File SKIP_SPECIES.TXT lists species and minerals omitted from the calculations due to given T, P, option switches, or suppression in CHIMRUN, or are suppressed in the SOLTHERM database. It also lists minerals for which density is not specified in SOLTHERM. This is an extended P(to 5 kB), T(to 600 C) run (CON_FLAG = 1). methanol,aq is suppressed in SOLTHERM data file. methanol,aq is suppressed in SOLTHERM data file. CuCl4-3 is suppressed in SOLTHERM data file. H2BO3- is suppressed in SOLTHERM data file. UO2CO3,aq is suppressed in SOLTHERM data file. UO2SO4,aq is suppressed in SOLTHERM data file. UO2Cl2,aq is suppressed in SOLTHERM data file. UO2F2,aq is suppressed in SOLTHERM data file. PO4-3 is suppressed in SOLTHERM data file. H2PO4- is suppressed in SOLTHERM data file. H3PO4 is suppressed in SOLTHERM data file. O2,gas is suppressed in THIS RUN. O2,gas is suppressed in THIS RUN. amesite is suppressed in SOLTHERM data file. antigorite is suppressed in SOLTHERM data file. goethite is suppressed in THIS RUN. goethite is suppressed in THIS RUN. riebeckite is suppressed in THIS RUN. riebeckite is suppressed in THIS RUN. sapphirine-Fe(221) is suppressed in SOLTHERM data file. sapphirine(221) is suppressed in SOLTHERM data file. talc-prl is suppressed in SOLTHERM data file. PrO1.833(s) is suppressed in SOLTHERM data file. niter-NH4 is suppressed in SOLTHERM data file. FMQ_HS-1 is suppressed in THIS RUN. kf-ab-equil is suppressed in THIS RUN. ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Species No. Charge Tot.moles Trial molality Gamma Mixing solution H+ 1 1. -0.65938E-02 0.20087E-08 0.9473 0.00000000E+00 H2O 2 0. 0.55503E+02 0.10000E+01 1.0000 0.00000000E+00 Cl- 3 -1. 0.13797E-03 0.13796E-03 0.9470 0.00000000E+00 SO4-- 4 -2. 0.36562E-04 0.25479E-04 0.8491 0.00000000E+00 HCO3- 5 -1. 0.13070E-04 0.12387E-04 0.9471 0.00000000E+00 HS- 6 -1. -0.11058E-04 0.88634E-13 0.9470 0.00000000E+00 Al+++ 7 3. 0.13010E-02 0.56222E-23 0.7072 0.00000000E+00 H4SiO4 8 0. 0.41547E-02 0.37357E-03 1.0000 0.00000000E+00 Ca++ 9 2. 0.47338E-03 0.37919E-06 0.8487 0.00000000E+00 Mg++ 10 2. 0.31667E-03 0.15171E-08 0.8485 0.00000000E+00 Fe++ 11 2. 0.28449E-03 0.89508E-11 0.8486 0.00000000E+00 K+ 12 1. 0.84713E-04 0.76665E-04 0.9471 0.00000000E+00 Na+ 13 1. 0.66091E-03 0.65895E-03 0.9470 0.00000000E+00 Mn++ 14 2. 0.69181E-05 0.12022E-08 0.8486 0.00000000E+00 HPO4-- 15 -2. 0.23611E-05 0.16332E-06 0.8491 0.00000000E+00 Chg. balance for total moles = -.5880E-14 Max. difference allowed = 0.1380E-07 The following parameters were given: ERPC = 0.1000E-11 pH = 0.0000 PFLUID = 50.0000 SLIM = 0.800000E+00 TEMP = 100.0000 SINC = 0.2000E-01 TEMPC = 0.0000 TOTMIX = 0.399000E+00 ENTH = 0.0000 SENTH = 0.0000 DENTH = 0.0000 TOTWAT = 90.0000 SOLMIN = 0.0000E+00 RM = 0.0000 AQGRM = 1000.0103 SUPRNT = 0.1000E-19 VBOX-1 = 1.1596 RHOFRS = 0.0000 RHOROC = 2.5000 The following options were selected: CONFLG = 1 C = 3 IFRAC = 0 IPUNCH = 2 NLOOP = 400 ISTEP = 2 LIMSOL = 1 LOOC = 0 IENTH = 0 ITREF = 0 IDEAL = 0 IPSAT = 1 INCREM = 0 INCP = 0 MINSOL = 1 NEUT = 0 AWAT = 0 CHGF = 0 Of the derived species, only those with molality > 0.10E-19 will appear in the output Species No. Charge Log K(diss) Species No. Charge Log K(diss) HSiO3- 16 -1. 9.0298 MnO2-2 65 -2. 40.4638 Ca(HSiO3)+ 17 1. 7.6723 HMnO2- 66 -1. 29.1232 Mg(HSiO3)+ 18 1. 7.5773 MnO4- 67 -1. 83.3111 NaHSiO3,aq 19 0. 7.8210 MnO4-2 68 -2. 81.3005 AlO+ 20 1. 6.8663 MnCl+ 69 1. -0.7894 AlOH+2 21 2. 3.1691 MnSO4,aq 70 0. -2.4604 HAlO2,aq 22 0. 10.5671 NaCl,aq 71 0. 0.4796 AlO2- 23 -1. 16.2221 NaOH,aq 72 0. 12.3669 CH4,aq 24 0. 6.0126 O2,aq 73 0. 53.5502 C2H6,aq 25 0. 12.3733 OH- 74 -1. 12.2382 C3H8,aq 26 0. 17.3707 HO2- 75 -1. 50.8010 C4H10,aq 27 0. 22.3757 H2O2,aq 76 0. 40.0166 ethanol,aq 28 0. 15.3258 H3PO2,aq 77 0. 24.3066 CO,aq 29 0. 4.6892 H2PO2- 78 -1. 26.5366 CO2,aq 30 0. -6.3298 HPO3-2 79 -2. 11.9254 CO3-2 31 -2. 10.0588 H3PO3,aq 80 0. 3.5792 CaCO3,aq 32 0. 5.9605 H2PO3- 81 -1. 5.6232 Ca(HCO3)+ 33 1. -1.4070 H3PO4,aq 82 0. -9.8447 CaCl+ 34 1. -0.2091 H2PO4- 83 -1. -7.2659 CaCl2,aq 35 0. 0.4151 PO4-3 84 -3. 12.0884 CaOH+ 36 1. 10.1471 H4P2O7,aq 85 0. -17.8095 CaSO4,aq 37 0. -2.5018 H3P2O7- 86 -1. -15.9156 HCl,aq 38 0. 0.7370 H2P2O7-2 87 -2. -13.4262 HClO,aq 39 0. 32.4260 HP2O7-3 88 -3. -6.7266 ClO- 40 -1. 39.6530 P2O7-4 89 -4. 2.8952 HClO2,aq 41 0. 70.1812 H2S,aq 90 0. -6.4900 Fe+3 42 3. 8.3809 S2-2 91 -2. 1.2355 FeCl+ 43 1. -0.1994 S3-2 92 -2. -8.8031 FeCl2,aq 44 0. 4.3001 S3- 93 -1. -16.3389 FeCl+2 45 2. 6.5269 S4-2 94 -2. -18.6615 FeO,aq 46 0. 16.4104 S5-2 95 -2. -28.3439 FeOH+ 47 1. 7.4874 SO2,aq 96 0. -0.2309 HFeO2- 48 -1. 24.3908 SO3-2 97 -2. 10.3052 FeO+ 49 1. 11.4004 HSO3- 98 -1. 2.5086 FeOH+2 50 2. 9.1194 HSO4- 99 -1. -2.9839 FeO2- 51 -1. 24.0895 HSO5- 100 -1. 38.8366 HFeO2,aq 52 0. 15.9850 S2O3-2 101 -2. -4.5600 H2,aq 53 0. 9.4190 HS2O3- 102 -1. -6.8123 KCl,aq 54 0. 1.7417 H2S2O3,aq 103 0. -8.0173 KHSO4,aq 55 0. -0.4514 S2O4-2 104 -2. 10.5541 KOH,aq 56 0. 12.3695 HS2O4- 105 -1. 7.6551 KSO4- 57 -1. -1.1908 H2S2O4,aq 106 0. 6.6259 MgCO3,aq 58 0. 6.5614 S2O5-2 107 -2. 10.0741 Mg(HCO3)+ 59 1. -1.4164 S2O6-2 108 -2. 11.5521 MgCl+ 60 1. -0.1664 S2O8-2 109 -2. 42.0620 MgOH+ 61 1. 9.4041 S3O6-2 110 -2. 3.7866 Mn+3 62 3. 19.1453 S4O6-2 111 -2. -17.8657 MnO,aq 63 0. 17.9848 S5O6-2 112 -2. -14.1333 MnOH+ 64 1. 8.5194 113 0. 10.3111 For mixed gases (JSOLS=6), log K(hydrol) = log (K*P) Log K Trial Log K Trial Mineral No. hydrol Moles Mineral No. hydrol Moles H2O,gas 1 1.696 0.0000E+00 osumilite(2) 124 20.667 0.0000E+00 CO2,gas 2 -6.660 0.0000E+00 osumilite-Fe 125 14.390 0.0000E+00 CH4,gas 3 4.544 0.0000E+00 pargasite 126 65.092 0.0000E+00 H2,gas 4 8.000 0.0000E+00 periclase 127 16.138 0.0000E+00 H2S,gas 5 -6.230 0.0000E+00 periclase-Fe 128 11.627 0.0000E+00 S2,gas 6 -7.335 0.0000E+00 perovskite-Al 129 12.344 0.0000E+00 CO,gas 7 3.215 0.0000E+00 perovskite-Ca 130 23.807 0.0000E+00 SO3,gas 8 17.121 0.0000E+00 perovskite-Fe 131 21.143 0.0000E+00 SO2,gas 9 0.832 0.0000E+00 perovskite-Mg 132 23.119 0.0000E+00 HCl,gas 10 5.189 0.0000E+00 phase_A 133 80.189 0.0000E+00 acmite 11 7.710 0.0000E+00 phlogopite-Na 134 29.647 0.0000E+00 akermanite 12 36.442 0.0000E+00 piemontite(ordered) 135 33.776 0.0000E+00 akimotoite 13 16.591 0.0000E+00 prehnite 136 19.372 0.0000E+00 akimotoite-Fe 14 13.067 0.0000E+00 prehnite-Fe 137 22.498 0.0000E+00 albite-high 15 0.693 0.0000E+00 pumpellyite-Fe 138 46.269 0.0000E+00 albite 16 -0.384 0.0000E+00 pumpellyite-Mg 139 48.995 0.0000E+00 almandine 17 24.442 0.0000E+00 px-Mg-tschermaks 140 19.616 0.0000E+00 pyrope 18 37.248 0.0000E+00 px-Ca-tschermaks 141 18.610 0.0000E+00 spessartine 19 24.457 0.0000E+00 pyrite 142 -21.247 0.0000E+00 analcite 20 3.322 0.0000E+00 pyrrhotite 143 -4.260 0.0000E+00 andalusite 21 5.002 0.0000E+00 pyrrhotiteFe0.875 144 -6.017 0.0000E+00 andradite 22 39.009 0.0000E+00 pyroxmangite 145 7.399 0.0000E+00 grossular 23 32.731 0.0000E+00 pyrophyllite 146 -6.176 0.0000E+00 anhydrite 24 -5.317 0.0000E+00 quartz 147 -2.989 0.0000E+00 ankerite 25 -2.135 0.0000E+00 rankinite 148 40.713 0.0000E+00 annite 26 20.123 0.0000E+00 ringwoodite-Fe 149 15.456 0.0000E+00 phlogopite 27 27.065 0.0000E+00 ringwoodite-Mg 150 27.575 0.0000E+00 biotite-Mn 28 32.960 0.0000E+00 rhodochrosite 151 -0.976 0.0000E+00 anorthite 29 12.710 0.0000E+00 rhodonite 152 7.446 0.0000E+00 anthophyllite 30 51.852 0.0000E+00 sanidine 153 -1.275 0.0000E+00 anthophyllite-Fe 31 29.306 0.0000E+00 sapphirine(351) 154 78.899 0.0000E+00 apatite-OH 32 -18.153 0.7309E-06 siderite 155 -2.608 0.0000E+00 apatite-OH-zs 33 -12.736 0.0000E+00 sillimanite 156 5.262 0.0000E+00 apatite-Cl-zs 34 -16.674 0.0000E+00 sodalite 157 49.976 0.0000E+00 aragonite 35 0.967 0.0000E+00 spinel 158 20.870 0.0000E+00 brucite 36 12.569 0.0000E+00 spurrite 159 59.482 0.0000E+00 calcite 37 0.812 0.0000E+00 staurolite-Fe 160 73.598 0.0000E+00 carnegieite-low 38 9.023 0.0000E+00 staurolite-Mg 161 89.802 0.0000E+00 carnegieite-high 39 10.093 0.0000E+00 staurolite-Mn 162 83.909 0.0000E+00 carpholite-Mg 40 8.582 0.0000E+00 stilbite 163 -7.522 0.4400E-03 carpholite-Fe 41 6.713 0.0000E+00 stilpnomelane-Fe 164 13.017 0.0000E+00 celadonite 42 5.342 0.0000E+00 stilpnomelane-Mg 165 27.441 0.0000E+00 celadonite-Fe 43 3.877 0.0000E+00 stishovite 166 2.720 0.0000E+00 chrysotile 44 23.892 0.0000E+00 sudoite-Fe 167 18.296 0.0000E+00 chondrodite 45 56.475 0.0000E+00 sudoite 168 21.077 0.0000E+00 clinochlore 46 39.070 0.6333E-04 sulfur 169 -9.152 0.0000E+00 daphnite 47 28.965 0.3921E-04 sylvite 170 1.338 0.0000E+00 chlorite-Mn 48 46.869 0.1383E-05 talc 171 16.491 0.0000E+00 chlorite-Al-free 49 47.173 0.0000E+00 talc-Fe 172 13.448 0.0000E+00 chloritoid-Mg 50 13.198 0.0000E+00 talc-tschermaks 173 19.091 0.0000E+00 chloritoid-Fe 51 9.174 0.0000E+00 tephroite 174 18.086 0.0000E+00 chloritoid-Mn 52 11.401 0.0000E+00 tilleyite 175 41.377 0.0000E+00 clinohumite 53 97.128 0.0000E+00 titanite-CaSi 176 15.479 0.0000E+00 coesite 54 -2.376 0.0000E+00 topaz-H 177 4.618 0.0000E+00 cordierite-H 55 23.715 0.0000E+00 tridymite 178 -2.626 0.0000E+00 cordierite 56 24.049 0.0000E+00 tremolite 179 47.869 0.0000E+00 cordierite-Fe 57 20.450 0.0000E+00 ferroactinolite 180 38.452 0.0000E+00 cordierite-Mn 58 25.066 0.0000E+00 troilite-low 181 -4.411 0.0000E+00 corundum 59 8.383 0.0000E+00 tschermakite 182 48.210 0.0000E+00 corundum-MgSi 60 18.891 0.0000E+00 vesuvianite 183 223.471 0.0000E+00 cristobalite 61 -2.560 0.0000E+00 wadeite-Si 184 20.216 0.0000E+00 cummingtonite 62 52.099 0.0000E+00 wadsleyite-Fe 185 15.680 0.0000E+00 cymrite-K 63 1.685 0.0000E+00 wadsleyite-Mg 186 25.850 0.0000E+00 deerite 64 95.671 0.0000E+00 wairakite 187 3.950 0.0000E+00 diaspore 65 2.874 0.0000E+00 walstromite 188 11.509 0.0000E+00 diamond 66 -3.102 0.0000E+00 wollastonite 189 10.461 0.0000E+00 diopside 67 16.181 0.0000E+00 pseudo-wollastonite 190 11.000 0.0000E+00 hedenbergite 68 14.208 0.0000E+00 zoisite 191 22.849 0.0000E+00 dolomite,ordered 69 0.546 0.0000E+00 akaganeite 192 7.755 0.0000E+00 eastonite 70 28.489 0.0000E+00 beidellite-Ca 193 -1.646 0.0000E+00 enstatite 71 17.265 0.0000E+00 beidellite-H 194 -2.326 0.0000E+00 clinoenstatite-HiP 72 18.354 0.0000E+00 beidellite-K 195 -1.520 0.0000E+00 clinoenstatite 73 17.166 0.0000E+00 beidellite-Mg 196 -1.790 0.0000E+00 protoenstatite 74 17.824 0.0000E+00 beidellite-Na 197 -1.342 0.0000E+00 epidote 75 24.670 0.0000E+00 calcium 198 84.026 0.0000E+00 clinozoisite 76 22.806 0.0000E+00 chalcedony 199 -2.802 0.0000E+00 epidote-Fe 77 29.841 0.0000E+00 dawsonite 200 1.682 0.0000E+00 fayalite 78 14.046 0.0000E+00 montmorillonite-Ca 201 -2.291 0.0000E+00 ferrosilite 79 11.149 0.0000E+00 montmorillonite-K 202 -2.237 0.0000E+00 forsterite 80 21.016 0.0000E+00 montmorillonite-Mg 203 -2.480 0.0000E+00 gedrite 81 50.522 0.0000E+00 montmorillonite-Na 204 -2.038 0.0000E+00 gehlenite 82 36.628 0.0000E+00 nontronite-Ca 205 3.215 0.0000E+00 gibbsite 83 4.079 0.0000E+00 nontronite-H 206 2.533 0.0000E+00 glaucophane 84 22.975 0.0000E+00 nontronite-K 207 3.341 0.0000E+00 glaucophane-Fe 85 17.276 0.0000E+00 nontronite-Mg 208 3.075 0.0000E+00 graphite 86 -3.546 0.0000E+00 nontronite-Na 209 3.520 0.0000E+00 greenalite 87 16.140 0.0000E+00 sepiolite 210 24.118 0.0000E+00 grunerite 88 31.215 0.0000E+00 alite 211 57.999 0.0000E+00 halite 89 1.575 0.0000E+00 belite 212 30.433 0.0000E+00 hematite 90 12.566 0.4423E-04 ettringite 213 43.232 0.0000E+00 heulandite 91 -5.827 0.0000E+00 gypsum 214 -4.955 0.0000E+00 hercynite 92 17.279 0.0000E+00 hemicarboaluminate 215 70.954 0.0000E+00 hollandite 93 25.673 0.0000E+00 hydrogarnet 216 60.662 0.0000E+00 iron 94 19.086 0.0000E+00 hydrogarnet-Si 217 50.586 0.0000E+00 jadeite 95 4.215 0.0000E+00 jennite 218 24.367 0.0000E+00 julgoldite 96 70.427 0.0000E+00 monosulfoaluminate 219 53.400 0.0000E+00 kalsilite 97 7.584 0.0000E+00 monocarboaluminate 220 61.898 0.0000E+00 kaolinite 98 -1.333 0.5564E-04 portlandite 221 18.272 0.0000E+00 kyanite 99 4.876 0.0000E+00 stratlingite 222 36.502 0.0000E+00 larnite-bredigite 100 30.686 0.0000E+00 tricarboaluminate 223 70.370 0.0000E+00 laumontite 101 2.883 0.0000E+00 tobermorite 224 9.823 0.0000E+00 lawsonite 102 9.616 0.2932E-04 C4AH13 225 81.816 0.0000E+00 leucite 103 4.119 0.0000E+00 C2AH8 226 45.203 0.0000E+00 lime 104 25.998 0.0000E+00 C3A 227 86.953 0.0000E+00 lizardite 105 23.244 0.0000E+00 C4AF 228 117.416 0.0000E+00 magnesite 106 0.691 0.0000E+00 CAH10 229 28.335 0.0000E+00 magnetite 107 20.087 0.0000E+00 alabandite 230 -0.978 0.0000E+00 minnesotaite 108 10.388 0.0000E+00 alunite 231 -10.435 0.0000E+00 minnesotaite-Mg 109 20.602 0.0000E+00 artinite 232 15.121 0.0000E+00 magnesioferrite 110 26.212 0.0000E+00 boehmite 233 4.406 0.0000E+00 majorite 111 53.251 0.0000E+00 dolomite,disordered 234 1.247 0.0000E+00 manganosite 112 14.058 0.0000E+00 ferrous-oxide 235 9.812 0.0000E+00 margarite 113 17.324 0.0000E+00 huntite 236 3.770 0.0000E+00 meionite 114 44.874 0.0000E+00 hydromagnesite 237 19.995 0.0000E+00 merwinite 115 55.930 0.0000E+00 nesquehonite 238 4.723 0.0000E+00 microcline 116 -2.486 0.0000E+00 potassium-oxide 239 69.038 0.0000E+00 monticellite 117 24.339 0.0000E+00 silica-amorphous 240 -2.091 0.0000E+00 mullite-Al 118 363.148 0.0000E+00 sodium-oxide 241 55.169 0.0000E+00 mullite-Si 119 7.264 0.0000E+00 an20ab80 242 2.018 0.0000E+00 muscovite 120 2.582 0.8012E-05 an25ab75 243 2.646 0.0000E+00 paragonite 121 4.239 0.0000E+00 an30ab70 244 3.279 0.0000E+00 nepheline 122 8.339 0.0000E+00 tr.625ac.25prg.125 245 45.165 0.0000E+00 osumilite(1) 123 21.717 0.0000E+00 246 0.000 0.0000E+00 Initial composition of reactant (wt%): SiO2 62.56 MgO 3.200 Al2O3 16.62 CaO 6.450 FeO 3.530 Na2O 3.890 Fe2O3 1.770 K2O 1.000 MnO 0.1230 P2O5 0.4200E-01 Sum of wt% of reactants: 99.1850 Reactant consumed: 0.3990000 g log = -0.3990 Original solution: 1000.0103000 g Original solution / Rock added: 2506.29 (Water/Rock Ratio), log = 3.3990 The following minerals and/or gases with identical index are in solid solution: H2O,gas 6 CO2,gas 6 CH4,gas 6 H2,gas 6 H2S,gas 6 S2,gas 6 CO,gas 6 SO3,gas 6 SO2,gas 6 HCl,gas 6 almandine 16 pyrope 16 spessartine 16 andradite 8 grossular 8 annite 15 phlogopite 15 biotite-Mn 15 clinochlore 1 daphnite 1 chlorite-Mn 1 diopside 5 hedenbergite 5 epidote 3 clinozoisite 3 greenalite 18 iron 9 lizardite 18 magnetite 14 talc 7 talc-Fe 7 tremolite 2 ferroactinolite 2 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 7 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 0.3990000 Water: Moles liquid = 0.5550E+02 kg liquid = 0.9999E+00 Moles total = 0.5550E+02 kg total = 0.9999E+00 Activity = 1.0000 Stoichiometric ionic strength = .5830340E-03 Osmotic coef. = 0.9858 True ionic strength = .7630569E-03 Chg. balance for total moles = -.5880E-14 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.20087E-08 -8.6971 0.19028E-08 -8.7206 0.94729E+00 -0.0235 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13796E-03 -3.8603 0.13064E-03 -3.8839 0.94698E+00 -0.0237 4 SO4-- 0.25479E-04 -4.5938 0.21633E-04 -4.6649 0.84908E+00 -0.0711 5 HCO3- 0.12387E-04 -4.9070 0.11731E-04 -4.9307 0.94705E+00 -0.0236 6 HS- 0.88634E-13 -13.0524 0.83935E-13 -13.0761 0.94698E+00 -0.0237 7 Al+++ 0.56222E-23 -23.2501 0.39758E-23 -23.4006 0.70716E+00 -0.1505 8 H4SiO4 0.37357E-03 -3.4276 0.37357E-03 -3.4276 0.10000E+01 0.0000 9 Ca++ 0.37919E-06 -6.4211 0.32183E-06 -6.4924 0.84874E+00 -0.0712 10 Mg++ 0.15171E-08 -8.8190 0.12873E-08 -8.8903 0.84853E+00 -0.0713 11 Fe++ 0.89508E-11 -11.0481 0.75955E-11 -11.1194 0.84858E+00 -0.0713 12 K+ 0.76665E-04 -4.1154 0.72607E-04 -4.1390 0.94706E+00 -0.0236 13 Na+ 0.65895E-03 -3.1811 0.62401E-03 -3.2048 0.94697E+00 -0.0237 14 Mn++ 0.12022E-08 -8.9200 0.10202E-08 -8.9913 0.84862E+00 -0.0713 15 HPO4-- 0.16332E-06 -6.7870 0.13867E-06 -6.8580 0.84909E+00 -0.0710 16 HSiO3- 0.19358E-03 -3.7131 0.18332E-03 -3.7368 0.94698E+00 -0.0237 17 Ca(HSiO3)+ 0.14187E-08 -8.8481 0.13436E-08 -8.8717 0.94708E+00 -0.0236 18 Mg(HSiO3)+ 0.70624E-11 -11.1510 0.66886E-11 -11.1747 0.94708E+00 -0.0236 19 NaHSiO3,aq 0.18501E-05 -5.7328 0.18501E-05 -5.7328 0.10000E+01 0.0000 20 AlO+ 0.15773E-12 -12.8021 0.14939E-12 -12.8257 0.94708E+00 -0.0236 21 AlOH+2 0.16678E-17 -17.7779 0.14154E-17 -17.8491 0.84867E+00 -0.0713 22 HAlO2,aq 0.15635E-07 -7.8059 0.15635E-07 -7.8059 0.10000E+01 0.0000 23 AlO2- 0.19209E-04 -4.7165 0.18188E-04 -4.7402 0.94688E+00 -0.0237 24 CH4,aq 0.44220E-19 -19.3544 0.44212E-19 -19.3545 0.99982E+00 -0.0001 29 CO,aq 0.54558E-18 -18.2631 0.54558E-18 -18.2631 0.10000E+01 0.0000 30 CO2,aq 0.47705E-07 -7.3214 0.47696E-07 -7.3215 0.99982E+00 -0.0001 31 CO3-2 0.63428E-06 -6.1977 0.53849E-06 -6.2688 0.84898E+00 -0.0711 32 CaCO3,aq 0.21731E-08 -8.6629 0.21731E-08 -8.6629 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.10176E-09 -9.9924 0.96371E-10 -10.0161 0.94708E+00 -0.0236 34 CaCl+ 0.71845E-10 -10.1436 0.68043E-10 -10.1672 0.94708E+00 -0.0236 35 CaCl2,aq 0.21119E-14 -14.6753 0.21119E-14 -14.6753 0.10000E+01 0.0000 36 CaOH+ 0.12728E-07 -7.8952 0.12054E-07 -7.9189 0.94708E+00 -0.0236 37 CaSO4,aq 0.22109E-08 -8.6554 0.22109E-08 -8.6554 0.10000E+01 0.0000 38 HCl,aq 0.45553E-13 -13.3415 0.45553E-13 -13.3415 0.10000E+01 0.0000 43 FeCl+ 0.16584E-14 -14.7803 0.15707E-14 -14.8039 0.94708E+00 -0.0236 46 FeO,aq 0.81533E-10 -10.0887 0.81533E-10 -10.0887 0.10000E+01 0.0000 47 FeOH+ 0.13720E-09 -9.8627 0.12994E-09 -9.8863 0.94708E+00 -0.0236 48 HFeO2- 0.47344E-09 -9.3247 0.44833E-09 -9.3484 0.94698E+00 -0.0237 49 FeO+ 0.15336E-13 -13.8143 0.14524E-13 -13.8379 0.94708E+00 -0.0236 51 FeO2- 0.86677E-09 -9.0621 0.82081E-09 -9.0858 0.94698E+00 -0.0237 52 HFeO2,aq 0.19864E-09 -9.7019 0.19864E-09 -9.7019 0.10000E+01 0.0000 53 H2,aq 0.45543E-09 -9.3416 0.45534E-09 -9.3417 0.99982E+00 -0.0001 54 KCl,aq 0.17192E-09 -9.7647 0.17192E-09 -9.7647 0.10000E+01 0.0000 55 KHSO4,aq 0.84505E-17 -17.0731 0.84505E-17 -17.0731 0.10000E+01 0.0000 56 KOH,aq 0.16296E-07 -7.7879 0.16296E-07 -7.7879 0.10000E+01 0.0000 57 KSO4- 0.25739E-07 -7.5894 0.24374E-07 -7.6131 0.94698E+00 -0.0237 58 MgCO3,aq 0.21788E-11 -11.6618 0.21788E-11 -11.6618 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.41591E-12 -12.3810 0.39390E-12 -12.4046 0.94708E+00 -0.0236 60 MgCl+ 0.26047E-12 -12.5842 0.24668E-12 -12.6079 0.94708E+00 -0.0236 61 MgOH+ 0.28172E-09 -9.5502 0.26681E-09 -9.5738 0.94708E+00 -0.0236 63 MnO,aq 0.29181E-09 -9.5349 0.29181E-09 -9.5349 0.10000E+01 0.0000 64 MnOH+ 0.17119E-08 -8.7665 0.16213E-08 -8.7901 0.94708E+00 -0.0236 65 MnO2-2 0.31505E-14 -14.5016 0.26747E-14 -14.5727 0.84898E+00 -0.0711 66 HMnO2- 0.11775E-11 -11.9291 0.11150E-11 -11.9527 0.94698E+00 -0.0237 69 MnCl+ 0.86663E-12 -12.0622 0.82076E-12 -12.0858 0.94708E+00 -0.0236 70 MnSO4,aq 0.63717E-11 -11.1957 0.63717E-11 -11.1957 0.10000E+01 0.0000 71 NaCl,aq 0.27017E-07 -7.5684 0.27017E-07 -7.5684 0.10000E+01 0.0000 72 NaOH,aq 0.14090E-06 -6.8511 0.14090E-06 -6.8511 0.10000E+01 0.0000 74 OH- 0.32068E-03 -3.4939 0.30364E-03 -3.5176 0.94688E+00 -0.0237 79 HPO3-2 0.23177E-18 -18.6349 0.19677E-18 -18.7060 0.84898E+00 -0.0711 82 H3PO4,aq 0.35115E-14 -14.4545 0.35115E-14 -14.4545 0.10000E+01 0.0000 83 H2PO4- 0.51398E-08 -8.2891 0.48675E-08 -8.3127 0.94702E+00 -0.0236 84 PO4-3 0.83855E-10 -10.0765 0.59459E-10 -10.2258 0.70907E+00 -0.1493 87 H2P2O7-2 0.21882E-17 -17.6599 0.18577E-17 -17.7310 0.84898E+00 -0.0711 88 HP2O7-3 0.27567E-15 -15.5596 0.19495E-15 -15.7101 0.70718E+00 -0.1505 89 P2O7-4 0.44626E-16 -16.3504 0.24475E-16 -16.6113 0.54846E+00 -0.2609 90 H2S,aq 0.49370E-15 -15.3065 0.49361E-15 -15.3066 0.99982E+00 -0.0001 97 SO3-2 0.15066E-14 -14.8220 0.12801E-14 -14.8928 0.84966E+00 -0.0708 98 HSO3- 0.16105E-15 -15.7930 0.15251E-15 -15.8167 0.94698E+00 -0.0237 99 HSO4- 0.41885E-10 -10.3779 0.39671E-10 -10.4015 0.94712E+00 -0.0236 Charge balance for all species = -.5529E-14 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.2008691E-08 -.5937515E-03 -.5984170E+00 0.0000 2 H2O 0.1000000E+01 0.5550841E+02 0.9999190E+06 0.0000 3 Cl- 0.1379585E-03 0.1379858E-03 0.4891611E+01 4.8367 4 SO4-- 0.2547862E-04 0.2550664E-04 0.2450008E+01 12.7763 5 HCO3- 0.1238683E-04 0.1307110E-04 0.7974968E+00 3.7899 6 HS- 0.8863371E-13 -.1923284E-10 -.6360166E-06 -4.3555 7 Al+++ 0.5622216E-23 0.1922430E-04 0.5186580E+00 2.7612 8 H4SiO4 0.3735728E-03 0.5690075E-03 0.5468592E+02 -3.4276 9 Ca++ 0.3791879E-06 0.3978920E-06 0.1594541E-01 10.9488 10 Mg++ 0.1517147E-08 0.1808786E-08 0.4397162E-04 8.5509 11 Fe++ 0.8950845E-11 0.1766547E-08 0.9864831E-04 6.3218 12 K+ 0.7666543E-04 0.7670764E-04 0.2999177E+01 4.5816 13 Na+ 0.6589508E-03 0.6609688E-03 0.1519430E+02 5.5158 14 Mn++ 0.1202209E-08 0.3214340E-08 0.1765750E-03 8.4499 15 HPO4-- 0.1633153E-06 0.1685390E-06 0.1617488E-01 10.5832 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.6593808E-02 -.5937015E-03 -.6000106E-02 0.0000000E+00 2 H2O 0.5550325E+02 0.5550374E+02 -.4929927E-03 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.3656212E-04 0.2550449E-04 0.1105763E-04 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.1105765E-04 -.1923122E-10 -.1105763E-04 0.0000000E+00 7 Al+++ 0.1301036E-02 0.1922268E-04 0.1281813E-02 0.0000000E+00 8 H4SiO4 0.4154700E-02 0.5689596E-03 0.3585741E-02 0.0000000E+00 9 Ca++ 0.4733780E-03 0.3978585E-06 0.4729801E-03 0.0000000E+00 10 Mg++ 0.3166667E-03 0.1808634E-08 0.3166649E-03 0.0000000E+00 11 Fe++ 0.2844904E-03 0.1766399E-08 0.2844887E-03 0.0000000E+00 12 K+ 0.8471338E-04 0.7670118E-04 0.8012196E-05 0.0000000E+00 13 Na+ 0.6609132E-03 0.6609132E-03 0.0000000E+00 0.0000000E+00 14 Mn++ 0.6918100E-05 0.3214069E-08 0.6914886E-05 0.0000000E+00 15 HPO4-- 0.2361113E-05 0.1685248E-06 0.2192588E-05 0.0000000E+00 Chg. balance for solid moles: 0.4760E-18 Mass of aqueous solution: 0.999998E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 0.3990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) apatite-OH 0.7309E-06 -6.136 0.3671E-03 -3.435 0.8989E-01 0.1167E-03 clinochlore 0.6333E-04 -4.198 0.3520E-01 -1.453 8.619 0.1339E-01 daphnite 0.3921E-04 -4.407 0.2797E-01 -1.553 6.849 0.8477E-02 chlorite-Mn 0.1383E-05 -5.859 0.9805E-03 -3.009 0.2401 0.3125E-03 hematite 0.4423E-04 -4.354 0.7064E-02 -2.151 1.729 0.1339E-02 kaolinite 0.5564E-04 -4.255 0.1436E-01 -1.843 3.517 0.5527E-02 lawsonite 0.2932E-04 -4.533 0.9215E-02 -2.036 2.256 0.2972E-02 muscovite 0.8012E-05 -5.096 0.3191E-02 -2.496 0.7814 0.1128E-02 stilbite 0.4400E-03 -3.357 0.3101 -0.509 75.92 0.1446 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.6094E+00 0.6094E+00 1.0000 -0.215 daphnite 0.3773E+00 0.3773E+00 1.0000 -0.423 chlorite-Mn 0.1331E-01 0.1331E-01 1.0000 -1.876 hematite 0.1000E+01 0.1000E+01 1.0000 0.000 kaolinite 0.1000E+01 0.1000E+01 1.0000 0.000 lawsonite 0.1000E+01 0.1000E+01 1.0000 0.000 muscovite 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 0.408435 g Volume = 0.177887 cm3 Porosity: 84.6596% V(tot) - V(min): 0.98171E+00 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.3990000 g log = -0.3990 Original solution: 1000.0103000 g Original solution / Rock added: 2506.29 (Water/Rock Ratio), log = 3.3990 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0203 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.1000E+01 0.9860 0.1006E+01 0.1020E+01 CO2,gas 0.4966E-05 1.0071 0.5103E-05 0.5067E-05 CH4,gas 0.6299E-16 1.0125 0.6508E-16 0.6427E-16 H2,gas 0.5856E-06 1.0005 0.5978E-06 0.5975E-06 H2S,gas 0.1335E-13 0.9960 0.1357E-13 0.1362E-13 S2,gas 0.1895E-34 1.0000 0.1934E-34 0.1934E-34 CO,gas 0.7968E-15 1.0000 0.8130E-15 0.8130E-15 SO3,gas 0.2903E-37 1.0000 0.2962E-37 0.2962E-37 SO2,gas 0.6751E-21 1.0000 0.6888E-21 0.6888E-21 HCl,gas 0.7878E-16 1.0000 0.8038E-16 0.8038E-16 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 32 apatite-OH -18.15 -18.15 0.00 0.000 -0.12132E-10 46 clinochlore 39.07 39.07 0.00 0.000 -0.36397E-10 47 daphnite 28.97 28.97 0.00 0.000 -0.54595E-10 48 chlorite-Mn 46.87 46.87 0.00 0.000 -0.48529E-10 90 hematite 12.57 12.57 0.00 0.000 0.30331E-11 98 kaolinite -1.33 -1.33 0.00 0.000 -0.64453E-11 102 lawsonite 9.62 9.62 0.00 0.000 -0.24265E-10 120 muscovite 2.58 2.58 0.00 0.000 0.60662E-11 163 stilbite -7.52 -7.52 0.00 0.000 -0.90992E-11 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -13.65 -6.99 -2.330 0.11937E+05 -5.292 3 CH4,gas 4.54 -13.34 -17.89 -4.471 0.30539E+05 -16.187 4 H2,gas 8.00 0.08 -7.92 -4.527 0.13527E+05 -6.223 5 H2S,gas -6.23 -21.80 -15.57 -7.783 0.26579E+05 -13.867 6 S2,gas -7.34 -43.75 -36.41 -5.602 0.62173E+05 -34.714 7 CO,gas 3.21 -13.57 -16.79 -5.166 0.28667E+05 -15.090 8 SO3,gas 17.12 -22.11 -39.23 -9.807 0.66980E+05 -37.528 9 SO2,gas 0.83 -22.03 -22.86 -6.096 0.39034E+05 -21.162 10 HCl,gas 5.19 -12.60 -17.79 -8.897 0.30382E+05 -16.095 11 acmite 7.71 4.94 -2.77 -0.287 0.47230E+04 15 albite-high 0.69 -2.01 -2.70 -0.208 0.46083E+04 16 albite -0.38 -2.01 -1.62 -0.125 0.27695E+04 19 spessartine 24.46 20.59 -3.87 -0.193 0.66045E+04 20 analcite 3.32 1.42 -1.90 -0.211 0.32443E+04 21 andalusite 5.00 2.09 -2.91 -0.291 0.49631E+04 22 andradite 39.01 35.13 -3.88 -0.202 0.66231E+04 23 grossular 32.73 28.09 -4.65 -0.232 0.79317E+04 26 annite 20.12 16.03 -4.10 -0.228 0.69975E+04 27 phlogopite 27.06 22.71 -4.35 -0.242 0.74308E+04 29 anorthite 12.71 9.62 -3.09 -0.238 0.52833E+04 35 aragonite 0.97 -2.70 -3.67 -1.223 0.62646E+04 36 brucite 12.57 8.55 -4.02 -0.804 0.68600E+04 37 calcite 0.81 -2.70 -3.51 -1.171 0.60004E+04 38 carnegieite-low 9.02 4.85 -4.17 -0.596 0.71268E+04 40 carpholite-Mg 8.58 7.22 -1.36 -0.091 0.23289E+04 41 carpholite-Fe 6.71 4.99 -1.72 -0.115 0.29431E+04 42 celadonite 5.34 2.18 -3.16 -0.186 0.53928E+04 43 celadonite-Fe 3.88 -0.05 -3.92 -0.231 0.66974E+04 50 chloritoid-Mg 13.20 10.65 -2.55 -0.170 0.43574E+04 51 chloritoid-Fe 9.17 8.42 -0.76 -0.050 0.12926E+04 52 chloritoid-Mn 11.40 10.54 -0.86 -0.057 0.14621E+04 54 coesite -2.38 -3.43 -1.05 -0.351 0.17955E+04 59 corundum 8.38 5.52 -2.86 -0.260 0.48845E+04 61 cristobalite -2.56 -3.43 -0.87 -0.289 0.14809E+04 63 cymrite-K 1.69 -2.94 -4.63 -0.385 0.78978E+04 65 diaspore 2.87 2.76 -0.11 -0.019 0.19202E+03 67 diopside 16.18 12.64 -3.54 -0.354 0.60391E+04 68 hedenbergite 14.21 10.42 -3.79 -0.379 0.64763E+04 75 epidote 24.67 23.42 -1.25 -0.061 0.21335E+04 76 clinozoisite 22.81 19.90 -2.91 -0.132 0.49645E+04 77 epidote-Fe 29.84 26.94 -2.90 -0.151 0.49492E+04 78 fayalite 14.05 9.22 -4.83 -0.690 0.82468E+04 83 gibbsite 4.08 2.76 -1.32 -0.188 0.22506E+04 87 greenalite 16.14 12.11 -4.03 -0.336 0.68802E+04 91 heulandite -5.83 -7.52 -1.69 -0.077 0.28938E+04 95 jadeite 4.22 1.42 -2.79 -0.279 0.47698E+04 97 kalsilite 7.58 3.92 -3.67 -0.524 0.62642E+04 99 kyanite 4.88 2.09 -2.78 -0.278 0.47490E+04 101 laumontite 2.88 2.76 -0.12 -0.008 0.20932E+03 103 leucite 4.12 0.49 -3.63 -0.363 0.62003E+04 105 lizardite 23.24 18.80 -4.45 -0.371 0.75921E+04 107 magnetite 20.09 18.89 -1.20 -0.098 0.20480E+04 113 margarite 17.32 15.14 -2.19 -0.087 0.37309E+04 116 microcline -2.49 -2.94 -0.45 -0.035 0.77443E+03 121 paragonite 4.24 3.52 -0.72 -0.043 0.12341E+04 122 nepheline 8.34 4.85 -3.49 -0.499 0.59592E+04 136 prehnite 19.37 17.14 -2.23 -0.131 0.38155E+04 137 prehnite-Fe 22.50 20.66 -1.84 -0.111 0.31396E+04 138 pumpellyite-Fe 46.27 43.36 -2.91 -0.065 0.49719E+04 139 pumpellyite-Mg 48.99 45.59 -3.41 -0.076 0.58193E+04 145 pyroxmangite 7.40 5.02 -2.38 -0.475 0.40576E+04 146 pyrophyllite -6.18 -8.19 -2.01 -0.126 0.34358E+04 147 quartz -2.99 -3.43 -0.44 -0.146 0.74820E+03 151 rhodochrosite -0.98 -5.20 -4.23 -1.408 0.72142E+04 152 rhodonite 7.45 5.02 -2.42 -0.485 0.41379E+04 153 sanidine -1.28 -2.94 -1.66 -0.128 0.28422E+04 155 siderite -2.61 -7.33 -4.72 -1.574 0.80616E+04 156 sillimanite 5.26 2.09 -3.17 -0.317 0.54070E+04 164 stilpnomelane-Fe 13.02 12.00 -1.02 -0.030 0.17345E+04 165 stilpnomelane-Mg 27.44 23.15 -4.29 -0.128 0.73329E+04 167 sudoite-Fe 18.30 13.41 -4.89 -0.158 0.83505E+04 168 sudoite 21.08 17.86 -3.21 -0.104 0.54869E+04 171 talc 16.49 11.94 -4.55 -0.268 0.77670E+04 174 tephroite 18.09 13.47 -4.61 -0.659 0.78776E+04 177 topaz-H 4.62 2.09 -2.52 -0.229 0.43090E+04 178 tridymite -2.63 -3.43 -0.80 -0.267 0.13682E+04 187 wairakite 3.95 2.76 -1.19 -0.070 0.20313E+04 188 walstromite 11.51 7.52 -3.99 -0.798 0.68094E+04 189 wollastonite 10.46 7.52 -2.94 -0.588 0.50199E+04 190 pseudo-wollastonite 11.00 7.52 -3.48 -0.696 0.59397E+04 191 zoisite 22.85 19.90 -2.95 -0.134 0.50385E+04 192 akaganeite 7.75 6.28 -1.47 -0.318 0.25125E+04 193 beidellite-Ca -1.65 -4.34 -2.69 -0.167 0.45991E+04 194 beidellite-H -2.33 -6.15 -3.82 -0.244 0.65216E+04 195 beidellite-K -1.52 -4.63 -3.11 -0.191 0.53163E+04 196 beidellite-Mg -1.79 -4.73 -2.95 -0.182 0.50285E+04 197 beidellite-Na -1.34 -4.33 -2.98 -0.183 0.50938E+04 199 chalcedony -2.80 -3.43 -0.63 -0.208 0.10675E+04 201 montmorillonite-Ca -2.29 -4.47 -2.18 -0.135 0.37225E+04 202 montmorillonite-K -2.24 -4.77 -2.53 -0.155 0.43178E+04 203 montmorillonite-Mg -2.48 -4.87 -2.39 -0.148 0.40751E+04 204 montmorillonite-Na -2.04 -4.46 -2.42 -0.148 0.41311E+04 205 nontronite-Ca 3.21 2.70 -0.51 -0.033 0.87076E+03 206 nontronite-H 2.53 0.90 -1.63 -0.110 0.27912E+04 207 nontronite-K 3.34 2.41 -0.93 -0.060 0.15893E+04 208 nontronite-Mg 3.07 2.31 -0.77 -0.050 0.13074E+04 209 nontronite-Na 3.52 2.72 -0.80 -0.051 0.13685E+04 224 tobermorite 9.82 5.69 -4.13 -1.127 0.70524E+04 233 boehmite 4.41 2.76 -1.65 -0.274 0.28089E+04 235 ferrous-oxide 9.81 6.32 -3.49 -0.872 0.59588E+04 240 silica-amorphous -2.09 -3.43 -1.34 -0.445 0.22817E+04 242 an20ab80 2.02 0.32 -1.70 -0.131 0.29014E+04 243 an25ab75 2.65 0.90 -1.75 -0.134 0.29814E+04 244 an30ab70 3.28 1.48 -1.80 -0.138 0.30709E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 0.0200000 g Current total amount of reactant added: 0.3990000 g New total amount of reactant added: 0.4190000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.5879E-14 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 7 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 0.4190000 Water: Moles liquid = 0.5550E+02 kg liquid = 0.9999E+00 Moles total = 0.5550E+02 kg total = 0.9999E+00 Activity = 1.0000 Stoichiometric ionic strength = .5976311E-03 Osmotic coef. = 0.9856 True ionic strength = .7850144E-03 Chg. balance for total moles = -.5879E-14 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.19315E-08 -8.7141 0.18287E-08 -8.7378 0.94682E+00 -0.0237 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13796E-03 -3.8603 0.13058E-03 -3.8841 0.94650E+00 -0.0239 4 SO4-- 0.25480E-04 -4.5938 0.21591E-04 -4.6657 0.84739E+00 -0.0719 5 HCO3- 0.12364E-04 -4.9079 0.11703E-04 -4.9317 0.94658E+00 -0.0238 6 HS- 0.85060E-13 -13.0703 0.80510E-13 -13.0941 0.94651E+00 -0.0239 7 Al+++ 0.50134E-23 -23.2999 0.35293E-23 -23.4523 0.70398E+00 -0.1524 8 H4SiO4 0.37357E-03 -3.4276 0.37357E-03 -3.4276 0.10000E+01 0.0000 9 Ca++ 0.35094E-06 -6.4548 0.29726E-06 -6.5269 0.84704E+00 -0.0721 10 Mg++ 0.14041E-08 -8.8526 0.11891E-08 -8.9248 0.84683E+00 -0.0722 11 Fe++ 0.82842E-11 -11.0818 0.70157E-11 -11.1539 0.84688E+00 -0.0722 12 K+ 0.73718E-04 -4.1324 0.69781E-04 -4.1563 0.94659E+00 -0.0238 13 Na+ 0.68390E-03 -3.1650 0.64731E-03 -3.1889 0.94649E+00 -0.0239 14 Mn++ 0.11127E-08 -8.9536 0.94238E-09 -9.0258 0.84692E+00 -0.0722 15 HPO4-- 0.17717E-06 -6.7516 0.15013E-06 -6.8235 0.84739E+00 -0.0719 16 HSiO3- 0.20153E-03 -3.6957 0.19074E-03 -3.7195 0.94650E+00 -0.0239 17 Ca(HSiO3)+ 0.13641E-08 -8.8651 0.12913E-08 -8.8890 0.94660E+00 -0.0238 18 Mg(HSiO3)+ 0.67909E-11 -11.1681 0.64283E-11 -11.1919 0.94660E+00 -0.0238 19 NaHSiO3,aq 0.19970E-05 -5.6996 0.19970E-05 -5.6996 0.10000E+01 0.0000 20 AlO+ 0.15167E-12 -12.8191 0.14357E-12 -12.8429 0.94660E+00 -0.0238 21 AlOH+2 0.15436E-17 -17.8115 0.13074E-17 -17.8836 0.84696E+00 -0.0721 22 HAlO2,aq 0.15635E-07 -7.8059 0.15635E-07 -7.8059 0.10000E+01 0.0000 23 AlO2- 0.19997E-04 -4.6990 0.18925E-04 -4.7230 0.94640E+00 -0.0239 24 CH4,aq 0.42397E-19 -19.3727 0.42389E-19 -19.3727 0.99981E+00 -0.0001 29 CO,aq 0.52309E-18 -18.2814 0.52309E-18 -18.2814 0.10000E+01 0.0000 30 CO2,aq 0.45739E-07 -7.3397 0.45730E-07 -7.3398 0.99981E+00 -0.0001 31 CO3-2 0.65972E-06 -6.1806 0.55897E-06 -6.2526 0.84729E+00 -0.0720 32 CaCO3,aq 0.20835E-08 -8.6812 0.20835E-08 -8.6812 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.93812E-10 -10.0277 0.88802E-10 -10.0516 0.94660E+00 -0.0238 34 CaCl+ 0.66360E-10 -10.1781 0.62816E-10 -10.2019 0.94660E+00 -0.0238 35 CaCl2,aq 0.19487E-14 -14.7103 0.19487E-14 -14.7103 0.10000E+01 0.0000 36 CaOH+ 0.12239E-07 -7.9123 0.11585E-07 -7.9361 0.94660E+00 -0.0238 37 CaSO4,aq 0.20381E-08 -8.6908 0.20381E-08 -8.6908 0.10000E+01 0.0000 38 HCl,aq 0.43757E-13 -13.3589 0.43757E-13 -13.3589 0.10000E+01 0.0000 43 FeCl+ 0.15318E-14 -14.8148 0.14500E-14 -14.8386 0.94660E+00 -0.0238 46 FeO,aq 0.81533E-10 -10.0887 0.81533E-10 -10.0887 0.10000E+01 0.0000 47 FeOH+ 0.13192E-09 -9.8797 0.12488E-09 -9.9035 0.94660E+00 -0.0238 48 HFeO2- 0.49286E-09 -9.3073 0.46649E-09 -9.3312 0.94650E+00 -0.0239 49 FeO+ 0.14746E-13 -13.8313 0.13959E-13 -13.8552 0.94660E+00 -0.0238 51 FeO2- 0.90233E-09 -9.0446 0.85406E-09 -9.0685 0.94650E+00 -0.0239 52 HFeO2,aq 0.19864E-09 -9.7019 0.19864E-09 -9.7019 0.10000E+01 0.0000 53 H2,aq 0.45543E-09 -9.3416 0.45534E-09 -9.3417 0.99981E+00 -0.0001 54 KCl,aq 0.16514E-09 -9.7821 0.16514E-09 -9.7821 0.10000E+01 0.0000 55 KHSO4,aq 0.77902E-17 -17.1084 0.77902E-17 -17.1084 0.10000E+01 0.0000 56 KOH,aq 0.16296E-07 -7.7879 0.16296E-07 -7.7879 0.10000E+01 0.0000 57 KSO4- 0.24701E-07 -7.6073 0.23380E-07 -7.6312 0.94650E+00 -0.0239 58 MgCO3,aq 0.20890E-11 -11.6801 0.20890E-11 -11.6801 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.38344E-12 -12.4163 0.36296E-12 -12.4401 0.94660E+00 -0.0238 60 MgCl+ 0.24058E-12 -12.6187 0.22774E-12 -12.6426 0.94660E+00 -0.0238 61 MgOH+ 0.27089E-09 -9.5672 0.25643E-09 -9.5910 0.94660E+00 -0.0238 63 MnO,aq 0.29182E-09 -9.5349 0.29182E-09 -9.5349 0.10000E+01 0.0000 64 MnOH+ 0.16462E-08 -8.7835 0.15583E-08 -8.8074 0.94660E+00 -0.0238 65 MnO2-2 0.34179E-14 -14.4662 0.28959E-14 -14.5382 0.84729E+00 -0.0720 66 HMnO2- 0.12258E-11 -11.9116 0.11602E-11 -11.9355 0.94650E+00 -0.0239 69 MnCl+ 0.80050E-12 -12.0966 0.75775E-12 -12.1205 0.94660E+00 -0.0238 70 MnSO4,aq 0.58741E-11 -11.2311 0.58741E-11 -11.2311 0.10000E+01 0.0000 71 NaCl,aq 0.28011E-07 -7.5527 0.28011E-07 -7.5527 0.10000E+01 0.0000 72 NaOH,aq 0.15208E-06 -6.8179 0.15208E-06 -6.8179 0.10000E+01 0.0000 74 OH- 0.33383E-03 -3.4765 0.31594E-03 -3.5004 0.94640E+00 -0.0239 79 HPO3-2 0.25143E-18 -18.5996 0.21303E-18 -18.6716 0.84729E+00 -0.0720 82 H3PO4,aq 0.35115E-14 -14.4545 0.35115E-14 -14.4545 0.10000E+01 0.0000 83 H2PO4- 0.53507E-08 -8.2716 0.50647E-08 -8.2954 0.94655E+00 -0.0239 84 PO4-3 0.94882E-10 -10.0228 0.66980E-10 -10.1741 0.70593E+00 -0.1512 87 H2P2O7-2 0.23738E-17 -17.6246 0.20113E-17 -17.6965 0.84729E+00 -0.0720 88 HP2O7-3 0.31194E-15 -15.5059 0.21961E-15 -15.6584 0.70400E+00 -0.1524 89 P2O7-4 0.52726E-16 -16.2780 0.28688E-16 -16.5423 0.54411E+00 -0.2643 90 H2S,aq 0.45512E-15 -15.3419 0.45504E-15 -15.3420 0.99981E+00 -0.0001 97 SO3-2 0.15066E-14 -14.8220 0.12776E-14 -14.8936 0.84798E+00 -0.0716 98 HSO3- 0.15456E-15 -15.8109 0.14629E-15 -15.8348 0.94650E+00 -0.0239 99 HSO4- 0.40197E-10 -10.3958 0.38052E-10 -10.4196 0.94665E+00 -0.0238 Charge balance for all species = -.5880E-14 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.1931451E-08 -.6181894E-03 -.6230461E+00 0.0000 2 H2O 0.1000000E+01 0.5550842E+02 0.9999178E+06 0.0000 3 Cl- 0.1379581E-03 0.1379863E-03 0.4891622E+01 4.8537 4 SO4-- 0.2547992E-04 0.2550673E-04 0.2450014E+01 12.8100 5 HCO3- 0.1236351E-04 0.1307115E-04 0.7974986E+00 3.8061 6 HS- 0.8506029E-13 -.2368140E-10 -.7831262E-06 -4.3563 7 Al+++ 0.5013397E-23 0.2001247E-04 0.5399215E+00 2.7612 8 H4SiO4 0.3735728E-03 0.5770968E-03 0.5546329E+02 -3.4276 9 Ca++ 0.3509432E-06 0.3688276E-06 0.1478065E-01 10.9488 10 Mg++ 0.1404148E-08 0.1684542E-08 0.4095118E-04 8.5509 11 Fe++ 0.8284156E-11 0.1815592E-08 0.1013869E-03 6.3218 12 K+ 0.7371790E-04 0.7375906E-04 0.2883887E+01 4.5816 13 Na+ 0.6839013E-03 0.6860783E-03 0.1577149E+02 5.5490 14 Mn++ 0.1112711E-08 0.3058592E-08 0.1680190E-03 8.4499 15 HPO4-- 0.1771664E-06 0.1826119E-06 0.1752545E-01 10.6522 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.6924978E-02 -.6181352E-03 -.6306843E-02 0.0000000E+00 2 H2O 0.5550300E+02 0.5550355E+02 -.5487316E-03 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.3711639E-04 0.2550449E-04 0.1161189E-04 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.1161192E-04 -.2367932E-10 -.1161189E-04 0.0000000E+00 7 Al+++ 0.1366251E-02 0.2001071E-04 0.1346240E-02 0.0000000E+00 8 H4SiO4 0.4362956E-02 0.5770462E-03 0.3785910E-02 0.0000000E+00 9 Ca++ 0.4963808E-03 0.3687953E-06 0.4960120E-03 0.0000000E+00 10 Mg++ 0.3325397E-03 0.1684394E-08 0.3325380E-03 0.0000000E+00 11 Fe++ 0.2987506E-03 0.1815433E-08 0.2987488E-03 0.0000000E+00 12 K+ 0.8895966E-04 0.7375258E-04 0.1520708E-04 0.0000000E+00 13 Na+ 0.6860181E-03 0.6860181E-03 0.0000000E+00 0.0000000E+00 14 Mn++ 0.7264872E-05 0.3058323E-08 0.7261813E-05 0.0000000E+00 15 HPO4-- 0.2479465E-05 0.1825959E-06 0.2296869E-05 0.0000000E+00 Chg. balance for solid moles: -.5463E-18 Mass of aqueous solution: 0.999995E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 0.4190000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) apatite-OH 0.7656E-06 -6.116 0.3846E-03 -3.415 0.8932E-01 0.1222E-03 clinochlore 0.6651E-04 -4.177 0.3697E-01 -1.432 8.586 0.1406E-01 daphnite 0.4117E-04 -4.385 0.2938E-01 -1.532 6.823 0.8902E-02 chlorite-Mn 0.1452E-05 -5.838 0.1030E-02 -2.987 0.2392 0.3281E-03 hematite 0.4645E-04 -4.333 0.7418E-02 -2.130 1.723 0.1406E-02 kaolinite 0.4899E-04 -4.310 0.1265E-01 -1.898 2.938 0.4867E-02 lawsonite 0.2608E-04 -4.584 0.8194E-02 -2.086 1.903 0.2642E-02 muscovite 0.1521E-04 -4.818 0.6057E-02 -2.218 1.407 0.2142E-02 stilbite 0.4661E-03 -3.332 0.3285 -0.483 76.29 0.1532 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.6094E+00 0.6094E+00 1.0000 -0.215 daphnite 0.3773E+00 0.3773E+00 1.0000 -0.423 chlorite-Mn 0.1331E-01 0.1331E-01 1.0000 -1.876 hematite 0.1000E+01 0.1000E+01 1.0000 0.000 kaolinite 0.1000E+01 0.1000E+01 1.0000 0.000 lawsonite 0.1000E+01 0.1000E+01 1.0000 0.000 muscovite 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 0.430550 g Volume = 0.187677 cm3 Porosity: 83.9263% V(tot) - V(min): 0.97992E+00 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.4190000 g log = -0.3778 Original solution: 1000.0103000 g Original solution / Rock added: 2386.66 (Water/Rock Ratio), log = 3.3778 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0203 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.1000E+01 0.9860 0.1006E+01 0.1020E+01 CO2,gas 0.4762E-05 1.0071 0.4893E-05 0.4858E-05 CH4,gas 0.6040E-16 1.0125 0.6239E-16 0.6162E-16 H2,gas 0.5856E-06 1.0005 0.5978E-06 0.5975E-06 H2S,gas 0.1231E-13 0.9960 0.1251E-13 0.1256E-13 S2,gas 0.1611E-34 1.0000 0.1643E-34 0.1643E-34 CO,gas 0.7640E-15 1.0000 0.7795E-15 0.7795E-15 SO3,gas 0.2676E-37 1.0000 0.2730E-37 0.2730E-37 SO2,gas 0.6223E-21 1.0000 0.6350E-21 0.6350E-21 HCl,gas 0.7567E-16 1.0000 0.7721E-16 0.7721E-16 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 32 apatite-OH -18.15 -18.15 0.00 0.000 -0.60662E-11 46 clinochlore 39.07 39.07 0.00 0.000 0.12132E-10 47 daphnite 28.97 28.97 0.00 0.000 0.60662E-11 48 chlorite-Mn 46.87 46.87 0.00 0.000 0.00000E+00 90 hematite 12.57 12.57 0.00 0.000 0.21232E-10 98 kaolinite -1.33 -1.33 0.00 0.000 0.56870E-11 102 lawsonite 9.62 9.62 0.00 0.000 0.00000E+00 120 muscovite 2.58 2.58 0.00 0.000 -0.18198E-10 163 stilbite -7.52 -7.52 0.00 0.000 0.15165E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -13.67 -7.01 -2.336 0.11968E+05 -5.310 3 CH4,gas 4.54 -13.36 -17.90 -4.476 0.30570E+05 -16.205 4 H2,gas 8.00 0.08 -7.92 -4.527 0.13527E+05 -6.223 5 H2S,gas -6.23 -21.83 -15.60 -7.801 0.26640E+05 -13.903 6 S2,gas -7.34 -43.82 -36.48 -5.613 0.62294E+05 -34.784 7 CO,gas 3.21 -13.59 -16.81 -5.171 0.28698E+05 -15.108 8 SO3,gas 17.12 -22.14 -39.26 -9.816 0.67040E+05 -37.564 9 SO2,gas 0.83 -22.06 -22.90 -6.106 0.39095E+05 -21.197 10 HCl,gas 5.19 -12.62 -17.81 -8.906 0.30412E+05 -16.112 11 acmite 7.71 4.98 -2.73 -0.284 0.46664E+04 15 albite-high 0.69 -1.97 -2.67 -0.205 0.45517E+04 16 albite -0.38 -1.97 -1.59 -0.122 0.27128E+04 19 spessartine 24.46 20.59 -3.87 -0.193 0.66044E+04 20 analcite 3.32 1.45 -1.87 -0.207 0.31877E+04 21 andalusite 5.00 2.09 -2.91 -0.291 0.49631E+04 22 andradite 39.01 35.13 -3.88 -0.202 0.66231E+04 23 grossular 32.73 28.09 -4.65 -0.232 0.79317E+04 26 annite 20.12 16.03 -4.10 -0.228 0.69975E+04 27 phlogopite 27.06 22.71 -4.35 -0.242 0.74308E+04 29 anorthite 12.71 9.62 -3.09 -0.238 0.52833E+04 35 aragonite 0.97 -2.72 -3.69 -1.229 0.62958E+04 36 brucite 12.57 8.55 -4.02 -0.804 0.68600E+04 37 calcite 0.81 -2.72 -3.53 -1.177 0.60316E+04 38 carnegieite-low 9.02 4.88 -4.14 -0.592 0.70702E+04 40 carpholite-Mg 8.58 7.22 -1.36 -0.091 0.23289E+04 41 carpholite-Fe 6.71 4.99 -1.72 -0.115 0.29431E+04 42 celadonite 5.34 2.18 -3.16 -0.186 0.53928E+04 43 celadonite-Fe 3.88 -0.05 -3.92 -0.231 0.66974E+04 50 chloritoid-Mg 13.20 10.65 -2.55 -0.170 0.43574E+04 51 chloritoid-Fe 9.17 8.42 -0.76 -0.050 0.12926E+04 52 chloritoid-Mn 11.40 10.54 -0.86 -0.057 0.14621E+04 54 coesite -2.38 -3.43 -1.05 -0.351 0.17955E+04 59 corundum 8.38 5.52 -2.86 -0.260 0.48845E+04 61 cristobalite -2.56 -3.43 -0.87 -0.289 0.14809E+04 63 cymrite-K 1.69 -2.94 -4.63 -0.385 0.78978E+04 65 diaspore 2.87 2.76 -0.11 -0.019 0.19202E+03 67 diopside 16.18 12.64 -3.54 -0.354 0.60391E+04 68 hedenbergite 14.21 10.42 -3.79 -0.379 0.64763E+04 75 epidote 24.67 23.42 -1.25 -0.061 0.21335E+04 76 clinozoisite 22.81 19.90 -2.91 -0.132 0.49645E+04 77 epidote-Fe 29.84 26.94 -2.90 -0.151 0.49492E+04 78 fayalite 14.05 9.22 -4.83 -0.690 0.82468E+04 83 gibbsite 4.08 2.76 -1.32 -0.188 0.22506E+04 87 greenalite 16.14 12.11 -4.03 -0.336 0.68802E+04 91 heulandite -5.83 -7.52 -1.69 -0.077 0.28938E+04 95 jadeite 4.22 1.45 -2.76 -0.276 0.47132E+04 97 kalsilite 7.58 3.92 -3.67 -0.524 0.62642E+04 99 kyanite 4.88 2.09 -2.78 -0.278 0.47490E+04 101 laumontite 2.88 2.76 -0.12 -0.008 0.20932E+03 103 leucite 4.12 0.49 -3.63 -0.363 0.62003E+04 105 lizardite 23.24 18.80 -4.45 -0.371 0.75921E+04 107 magnetite 20.09 18.89 -1.20 -0.098 0.20480E+04 113 margarite 17.32 15.14 -2.19 -0.087 0.37309E+04 116 microcline -2.49 -2.94 -0.45 -0.035 0.77443E+03 121 paragonite 4.24 3.55 -0.69 -0.041 0.11775E+04 122 nepheline 8.34 4.88 -3.46 -0.494 0.59025E+04 136 prehnite 19.37 17.14 -2.23 -0.131 0.38155E+04 137 prehnite-Fe 22.50 20.66 -1.84 -0.111 0.31396E+04 138 pumpellyite-Fe 46.27 43.36 -2.91 -0.065 0.49719E+04 139 pumpellyite-Mg 48.99 45.59 -3.41 -0.076 0.58193E+04 145 pyroxmangite 7.40 5.02 -2.38 -0.475 0.40576E+04 146 pyrophyllite -6.18 -8.19 -2.01 -0.126 0.34358E+04 147 quartz -2.99 -3.43 -0.44 -0.146 0.74820E+03 151 rhodochrosite -0.98 -5.22 -4.24 -1.414 0.72453E+04 152 rhodonite 7.45 5.02 -2.42 -0.485 0.41379E+04 153 sanidine -1.28 -2.94 -1.66 -0.128 0.28422E+04 155 siderite -2.61 -7.35 -4.74 -1.580 0.80928E+04 156 sillimanite 5.26 2.09 -3.17 -0.317 0.54070E+04 164 stilpnomelane-Fe 13.02 12.00 -1.02 -0.030 0.17345E+04 165 stilpnomelane-Mg 27.44 23.15 -4.29 -0.128 0.73329E+04 167 sudoite-Fe 18.30 13.41 -4.89 -0.158 0.83505E+04 168 sudoite 21.08 17.86 -3.21 -0.104 0.54869E+04 171 talc 16.49 11.94 -4.55 -0.268 0.77670E+04 174 tephroite 18.09 13.47 -4.61 -0.659 0.78775E+04 177 topaz-H 4.62 2.09 -2.52 -0.229 0.43090E+04 178 tridymite -2.63 -3.43 -0.80 -0.267 0.13682E+04 187 wairakite 3.95 2.76 -1.19 -0.070 0.20313E+04 188 walstromite 11.51 7.52 -3.99 -0.798 0.68094E+04 189 wollastonite 10.46 7.52 -2.94 -0.588 0.50199E+04 190 pseudo-wollastonite 11.00 7.52 -3.48 -0.696 0.59397E+04 191 zoisite 22.85 19.90 -2.95 -0.134 0.50385E+04 192 akaganeite 7.75 6.28 -1.47 -0.318 0.25125E+04 193 beidellite-Ca -1.65 -4.34 -2.69 -0.167 0.45991E+04 194 beidellite-H -2.33 -6.15 -3.82 -0.244 0.65216E+04 195 beidellite-K -1.52 -4.63 -3.11 -0.191 0.53163E+04 196 beidellite-Mg -1.79 -4.73 -2.95 -0.182 0.50285E+04 197 beidellite-Na -1.34 -4.31 -2.97 -0.182 0.50751E+04 199 chalcedony -2.80 -3.43 -0.63 -0.208 0.10675E+04 201 montmorillonite-Ca -2.29 -4.47 -2.18 -0.135 0.37225E+04 202 montmorillonite-K -2.24 -4.77 -2.53 -0.155 0.43178E+04 203 montmorillonite-Mg -2.48 -4.87 -2.39 -0.148 0.40751E+04 204 montmorillonite-Na -2.04 -4.45 -2.41 -0.147 0.41124E+04 205 nontronite-Ca 3.21 2.70 -0.51 -0.033 0.87076E+03 206 nontronite-H 2.53 0.90 -1.63 -0.110 0.27912E+04 207 nontronite-K 3.34 2.41 -0.93 -0.060 0.15893E+04 208 nontronite-Mg 3.07 2.31 -0.77 -0.050 0.13074E+04 209 nontronite-Na 3.52 2.73 -0.79 -0.051 0.13498E+04 224 tobermorite 9.82 5.69 -4.13 -1.127 0.70524E+04 233 boehmite 4.41 2.76 -1.65 -0.274 0.28089E+04 235 ferrous-oxide 9.81 6.32 -3.49 -0.872 0.59588E+04 240 silica-amorphous -2.09 -3.43 -1.34 -0.445 0.22817E+04 242 an20ab80 2.02 0.35 -1.67 -0.129 0.28561E+04 243 an25ab75 2.65 0.92 -1.72 -0.132 0.29389E+04 244 an30ab70 3.28 1.50 -1.78 -0.137 0.30313E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 0.0200000 g Current total amount of reactant added: 0.4190000 g New total amount of reactant added: 0.4390000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.5880E-14 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 7 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 0.4390000 Water: Moles liquid = 0.5550E+02 kg liquid = 0.9999E+00 Moles total = 0.5550E+02 kg total = 0.9999E+00 Activity = 1.0000 Stoichiometric ionic strength = .6123672E-03 Osmotic coef. = 0.9854 True ionic strength = .8071740E-03 Chg. balance for total moles = -.5880E-14 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.18594E-08 -8.7306 0.17597E-08 -8.7546 0.94635E+00 -0.0239 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13796E-03 -3.8603 0.13051E-03 -3.8844 0.94603E+00 -0.0241 4 SO4-- 0.25481E-04 -4.5938 0.21550E-04 -4.6666 0.84571E+00 -0.0728 5 HCO3- 0.12340E-04 -4.9087 0.11675E-04 -4.9328 0.94610E+00 -0.0241 6 HS- 0.81730E-13 -13.0876 0.77320E-13 -13.1117 0.94603E+00 -0.0241 7 Al+++ 0.44866E-23 -23.3481 0.31444E-23 -23.5025 0.70083E+00 -0.1544 8 H4SiO4 0.37357E-03 -3.4276 0.37357E-03 -3.4276 0.10000E+01 0.0000 9 Ca++ 0.32559E-06 -6.4873 0.27524E-06 -6.5603 0.84536E+00 -0.0730 10 Mg++ 0.13027E-08 -8.8852 0.11010E-08 -8.9582 0.84514E+00 -0.0731 11 Fe++ 0.76856E-11 -11.1143 0.64958E-11 -11.1874 0.84519E+00 -0.0730 12 K+ 0.70969E-04 -4.1489 0.67145E-04 -4.1730 0.94612E+00 -0.0241 13 Na+ 0.70885E-03 -3.1494 0.67058E-03 -3.1735 0.94602E+00 -0.0241 14 Mn++ 0.10324E-08 -8.9862 0.87258E-09 -9.0592 0.84523E+00 -0.0730 15 HPO4-- 0.19173E-06 -6.7173 0.16215E-06 -6.7901 0.84572E+00 -0.0728 16 HSiO3- 0.20954E-03 -3.6787 0.19823E-03 -3.7028 0.94603E+00 -0.0241 17 Ca(HSiO3)+ 0.13133E-08 -8.8816 0.12425E-08 -8.9057 0.94613E+00 -0.0240 18 Mg(HSiO3)+ 0.65377E-11 -11.1846 0.61855E-11 -11.2086 0.94613E+00 -0.0240 19 NaHSiO3,aq 0.21499E-05 -5.6676 0.21499E-05 -5.6676 0.10000E+01 0.0000 20 AlO+ 0.14601E-12 -12.8356 0.13815E-12 -12.8597 0.94613E+00 -0.0240 21 AlOH+2 0.14320E-17 -17.8440 0.12105E-17 -17.9170 0.84528E+00 -0.0730 22 HAlO2,aq 0.15635E-07 -7.8059 0.15635E-07 -7.8059 0.10000E+01 0.0000 23 AlO2- 0.20792E-04 -4.6821 0.19668E-04 -4.7062 0.94593E+00 -0.0241 24 CH4,aq 0.40698E-19 -19.3904 0.40690E-19 -19.3905 0.99981E+00 -0.0001 29 CO,aq 0.50212E-18 -18.2992 0.50212E-18 -18.2992 0.10000E+01 0.0000 30 CO2,aq 0.43906E-07 -7.3575 0.43897E-07 -7.3576 0.99981E+00 -0.0001 31 CO3-2 0.68532E-06 -6.1641 0.57951E-06 -6.2369 0.84561E+00 -0.0728 32 CaCO3,aq 0.20000E-08 -8.6990 0.20000E-08 -8.6990 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.86694E-10 -10.0620 0.82024E-10 -10.0861 0.94613E+00 -0.0240 34 CaCl+ 0.61442E-10 -10.2115 0.58132E-10 -10.2356 0.94613E+00 -0.0240 35 CaCl2,aq 0.18025E-14 -14.7441 0.18025E-14 -14.7441 0.10000E+01 0.0000 36 CaOH+ 0.11782E-07 -7.9288 0.11147E-07 -7.9528 0.94613E+00 -0.0240 37 CaSO4,aq 0.18834E-08 -8.7250 0.18834E-08 -8.7250 0.10000E+01 0.0000 38 HCl,aq 0.42084E-13 -13.3759 0.42084E-13 -13.3759 0.10000E+01 0.0000 43 FeCl+ 0.14183E-14 -14.8482 0.13419E-14 -14.8723 0.94613E+00 -0.0240 46 FeO,aq 0.81533E-10 -10.0887 0.81533E-10 -10.0887 0.10000E+01 0.0000 47 FeOH+ 0.12700E-09 -9.8962 0.12016E-09 -9.9202 0.94613E+00 -0.0240 48 HFeO2- 0.51246E-09 -9.2903 0.48480E-09 -9.3144 0.94603E+00 -0.0241 49 FeO+ 0.14196E-13 -13.8478 0.13431E-13 -13.8719 0.94613E+00 -0.0240 51 FeO2- 0.93822E-09 -9.0277 0.88758E-09 -9.0518 0.94603E+00 -0.0241 52 HFeO2,aq 0.19864E-09 -9.7019 0.19864E-09 -9.7019 0.10000E+01 0.0000 53 H2,aq 0.45543E-09 -9.3416 0.45534E-09 -9.3417 0.99981E+00 -0.0001 54 KCl,aq 0.15883E-09 -9.7991 0.15883E-09 -9.7991 0.10000E+01 0.0000 55 KHSO4,aq 0.71990E-17 -17.1427 0.71990E-17 -17.1427 0.10000E+01 0.0000 56 KOH,aq 0.16296E-07 -7.7879 0.16296E-07 -7.7879 0.10000E+01 0.0000 57 KSO4- 0.23734E-07 -7.6246 0.22453E-07 -7.6487 0.94603E+00 -0.0241 58 MgCO3,aq 0.20053E-11 -11.6978 0.20053E-11 -11.6978 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.35434E-12 -12.4506 0.33526E-12 -12.4746 0.94613E+00 -0.0240 60 MgCl+ 0.22275E-12 -12.6522 0.21075E-12 -12.6762 0.94613E+00 -0.0240 61 MgOH+ 0.26079E-09 -9.5837 0.24674E-09 -9.6078 0.94613E+00 -0.0240 63 MnO,aq 0.29183E-09 -9.5349 0.29183E-09 -9.5349 0.10000E+01 0.0000 64 MnOH+ 0.15848E-08 -8.8000 0.14995E-08 -8.8241 0.94613E+00 -0.0240 65 MnO2-2 0.36989E-14 -14.4319 0.31278E-14 -14.5048 0.84561E+00 -0.0728 66 HMnO2- 0.12746E-11 -11.8946 0.12058E-11 -11.9187 0.94603E+00 -0.0241 69 MnCl+ 0.74120E-12 -12.1301 0.70127E-12 -12.1541 0.94613E+00 -0.0240 70 MnSO4,aq 0.54285E-11 -11.2653 0.54285E-11 -11.2653 0.10000E+01 0.0000 71 NaCl,aq 0.29004E-07 -7.5375 0.29004E-07 -7.5375 0.10000E+01 0.0000 72 NaOH,aq 0.16373E-06 -6.7859 0.16373E-06 -6.7859 0.10000E+01 0.0000 74 OH- 0.34711E-03 -3.4595 0.32834E-03 -3.4837 0.94593E+00 -0.0241 79 HPO3-2 0.27209E-18 -18.5653 0.23008E-18 -18.6381 0.84561E+00 -0.0728 82 H3PO4,aq 0.35115E-14 -14.4545 0.35115E-14 -14.4545 0.10000E+01 0.0000 83 H2PO4- 0.55634E-08 -8.2547 0.52634E-08 -8.2787 0.94608E+00 -0.0241 84 PO4-3 0.10697E-09 -9.9707 0.75180E-10 -10.1239 0.70283E+00 -0.1532 87 H2P2O7-2 0.25689E-17 -17.5903 0.21722E-17 -17.6631 0.84561E+00 -0.0728 88 HP2O7-3 0.35170E-15 -15.4538 0.24649E-15 -15.6082 0.70085E+00 -0.1544 89 P2O7-4 0.61992E-16 -16.2077 0.33464E-16 -16.4754 0.53981E+00 -0.2678 90 H2S,aq 0.42058E-15 -15.3761 0.42050E-15 -15.3762 0.99981E+00 -0.0001 97 SO3-2 0.15067E-14 -14.8220 0.12751E-14 -14.8944 0.84632E+00 -0.0725 98 HSO3- 0.14851E-15 -15.8283 0.14049E-15 -15.8524 0.94603E+00 -0.0241 99 HSO4- 0.38623E-10 -10.4132 0.36544E-10 -10.4372 0.94618E+00 -0.0240 Charge balance for all species = -.5877E-14 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.1859425E-08 -.6428524E-03 -.6479020E+00 0.0000 2 H2O 0.1000000E+01 0.5550843E+02 0.9999165E+06 0.0000 3 Cl- 0.1379576E-03 0.1379868E-03 0.4891633E+01 4.8702 4 SO4-- 0.2548114E-04 0.2550683E-04 0.2450020E+01 12.8426 5 HCO3- 0.1233988E-04 0.1307120E-04 0.7975004E+00 3.8218 6 HS- 0.8173034E-13 -.2816968E-10 -.9315491E-06 -4.3571 7 Al+++ 0.4486646E-23 0.2080773E-04 0.5613764E+00 2.7612 8 H4SiO4 0.3735728E-03 0.5852638E-03 0.5624811E+02 -3.4276 9 Ca++ 0.3255857E-06 0.3427127E-06 0.1373408E-01 10.9488 10 Mg++ 0.1302699E-08 0.1572609E-08 0.3823004E-04 8.5509 11 Fe++ 0.7685617E-11 0.1865556E-08 0.1041769E-03 6.3218 12 K+ 0.7096933E-04 0.7100951E-04 0.2776380E+01 4.5816 13 Na+ 0.7088453E-03 0.7111880E-03 0.1634869E+02 5.5810 14 Mn++ 0.1032354E-08 0.2916471E-08 0.1602115E-03 8.4499 15 HPO4-- 0.1917251E-06 0.1973955E-06 0.1894422E-01 10.7190 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.7256148E-02 -.6427936E-03 -.6613355E-02 0.0000000E+00 2 H2O 0.5550275E+02 0.5550335E+02 -.6041071E-03 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.3767066E-04 0.2550450E-04 0.1216616E-04 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.1216619E-04 -.2816711E-10 -.1216616E-04 0.0000000E+00 7 Al+++ 0.1431466E-02 0.2080583E-04 0.1410660E-02 0.0000000E+00 8 H4SiO4 0.4571212E-02 0.5852103E-03 0.3986001E-02 0.0000000E+00 9 Ca++ 0.5193837E-03 0.3426814E-06 0.5190410E-03 0.0000000E+00 10 Mg++ 0.3484127E-03 0.1572465E-08 0.3484111E-03 0.0000000E+00 11 Fe++ 0.3130108E-03 0.1865385E-08 0.3130089E-03 0.0000000E+00 12 K+ 0.9320594E-04 0.7100302E-04 0.2220292E-04 0.0000000E+00 13 Na+ 0.7111230E-03 0.7111230E-03 0.0000000E+00 0.0000000E+00 14 Mn++ 0.7611644E-05 0.2916204E-08 0.7608727E-05 0.0000000E+00 15 HPO4-- 0.2597816E-05 0.1973775E-06 0.2400439E-05 0.0000000E+00 Chg. balance for solid moles: -.1465E-18 Mass of aqueous solution: 0.999993E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 0.4390000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) apatite-OH 0.8001E-06 -6.097 0.4019E-03 -3.396 0.8879E-01 0.1277E-03 clinochlore 0.6968E-04 -4.157 0.3873E-01 -1.412 8.556 0.1473E-01 daphnite 0.4314E-04 -4.365 0.3078E-01 -1.512 6.799 0.9327E-02 chlorite-Mn 0.1522E-05 -5.818 0.1079E-02 -2.967 0.2383 0.3438E-03 hematite 0.4866E-04 -4.313 0.7772E-02 -2.109 1.717 0.1473E-02 kaolinite 0.4265E-04 -4.370 0.1101E-01 -1.958 2.432 0.4236E-02 lawsonite 0.2284E-04 -4.641 0.7177E-02 -2.144 1.586 0.2314E-02 muscovite 0.2220E-04 -4.654 0.8844E-02 -2.053 1.954 0.3127E-02 stilbite 0.4922E-03 -3.308 0.3469 -0.460 76.63 0.1618 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.6094E+00 0.6094E+00 1.0000 -0.215 daphnite 0.3773E+00 0.3773E+00 1.0000 -0.423 chlorite-Mn 0.1331E-01 0.1331E-01 1.0000 -1.876 hematite 0.1000E+01 0.1000E+01 1.0000 0.000 kaolinite 0.1000E+01 0.1000E+01 1.0000 0.000 lawsonite 0.1000E+01 0.1000E+01 1.0000 0.000 muscovite 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 0.452656 g Volume = 0.197465 cm3 Porosity: 83.2031% V(tot) - V(min): 0.97814E+00 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.4390000 g log = -0.3575 Original solution: 1000.0103000 g Original solution / Rock added: 2277.93 (Water/Rock Ratio), log = 3.3575 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0203 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.1000E+01 0.9860 0.1006E+01 0.1020E+01 CO2,gas 0.4571E-05 1.0071 0.4697E-05 0.4663E-05 CH4,gas 0.5798E-16 1.0125 0.5989E-16 0.5915E-16 H2,gas 0.5856E-06 1.0005 0.5978E-06 0.5975E-06 H2S,gas 0.1137E-13 0.9960 0.1156E-13 0.1161E-13 S2,gas 0.1375E-34 1.0000 0.1403E-34 0.1403E-34 CO,gas 0.7334E-15 1.0000 0.7483E-15 0.7483E-15 SO3,gas 0.2473E-37 1.0000 0.2523E-37 0.2523E-37 SO2,gas 0.5751E-21 1.0000 0.5868E-21 0.5868E-21 HCl,gas 0.7278E-16 1.0000 0.7426E-16 0.7426E-16 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 32 apatite-OH -18.15 -18.15 0.00 0.000 -0.12132E-10 46 clinochlore 39.07 39.07 0.00 0.000 -0.24265E-10 47 daphnite 28.97 28.97 0.00 0.000 -0.12132E-10 48 chlorite-Mn 46.87 46.87 0.00 0.000 -0.24265E-10 90 hematite 12.57 12.57 0.00 0.000 0.30331E-11 98 kaolinite -1.33 -1.33 0.00 0.000 0.56870E-11 102 lawsonite 9.62 9.62 0.00 0.000 -0.12132E-10 120 muscovite 2.58 2.58 0.00 0.000 -0.18198E-10 163 stilbite -7.52 -7.52 0.00 0.000 -0.90992E-11 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -13.69 -7.03 -2.342 0.11999E+05 -5.328 3 CH4,gas 4.54 -13.38 -17.92 -4.480 0.30601E+05 -16.223 4 H2,gas 8.00 0.08 -7.92 -4.527 0.13527E+05 -6.223 5 H2S,gas -6.23 -21.87 -15.64 -7.818 0.26698E+05 -13.937 6 S2,gas -7.34 -43.89 -36.55 -5.623 0.62411E+05 -34.853 7 CO,gas 3.21 -13.61 -16.82 -5.177 0.28728E+05 -15.126 8 SO3,gas 17.12 -22.18 -39.30 -9.824 0.67099E+05 -37.598 9 SO2,gas 0.83 -22.10 -22.93 -6.115 0.39153E+05 -21.232 10 HCl,gas 5.19 -12.64 -17.83 -8.914 0.30441E+05 -16.129 11 acmite 7.71 5.01 -2.70 -0.281 0.46116E+04 15 albite-high 0.69 -1.94 -2.63 -0.203 0.44969E+04 16 albite -0.38 -1.94 -1.56 -0.120 0.26581E+04 19 spessartine 24.46 20.59 -3.87 -0.193 0.66044E+04 20 analcite 3.32 1.49 -1.83 -0.204 0.31330E+04 21 andalusite 5.00 2.09 -2.91 -0.291 0.49631E+04 22 andradite 39.01 35.13 -3.88 -0.202 0.66231E+04 23 grossular 32.73 28.09 -4.65 -0.232 0.79317E+04 26 annite 20.12 16.03 -4.10 -0.228 0.69975E+04 27 phlogopite 27.06 22.71 -4.35 -0.242 0.74308E+04 29 anorthite 12.71 9.62 -3.09 -0.238 0.52833E+04 35 aragonite 0.97 -2.74 -3.70 -1.235 0.63262E+04 36 brucite 12.57 8.55 -4.02 -0.804 0.68600E+04 37 calcite 0.81 -2.74 -3.55 -1.183 0.60620E+04 38 carnegieite-low 9.02 4.91 -4.11 -0.587 0.70154E+04 40 carpholite-Mg 8.58 7.22 -1.36 -0.091 0.23289E+04 41 carpholite-Fe 6.71 4.99 -1.72 -0.115 0.29431E+04 42 celadonite 5.34 2.18 -3.16 -0.186 0.53928E+04 43 celadonite-Fe 3.88 -0.05 -3.92 -0.231 0.66974E+04 50 chloritoid-Mg 13.20 10.65 -2.55 -0.170 0.43574E+04 51 chloritoid-Fe 9.17 8.42 -0.76 -0.050 0.12926E+04 52 chloritoid-Mn 11.40 10.54 -0.86 -0.057 0.14621E+04 54 coesite -2.38 -3.43 -1.05 -0.351 0.17955E+04 59 corundum 8.38 5.52 -2.86 -0.260 0.48845E+04 61 cristobalite -2.56 -3.43 -0.87 -0.289 0.14809E+04 63 cymrite-K 1.69 -2.94 -4.63 -0.385 0.78978E+04 65 diaspore 2.87 2.76 -0.11 -0.019 0.19202E+03 67 diopside 16.18 12.64 -3.54 -0.354 0.60391E+04 68 hedenbergite 14.21 10.42 -3.79 -0.379 0.64763E+04 75 epidote 24.67 23.42 -1.25 -0.061 0.21335E+04 76 clinozoisite 22.81 19.90 -2.91 -0.132 0.49645E+04 77 epidote-Fe 29.84 26.94 -2.90 -0.151 0.49492E+04 78 fayalite 14.05 9.22 -4.83 -0.690 0.82468E+04 83 gibbsite 4.08 2.76 -1.32 -0.188 0.22506E+04 87 greenalite 16.14 12.11 -4.03 -0.336 0.68802E+04 91 heulandite -5.83 -7.52 -1.69 -0.077 0.28938E+04 95 jadeite 4.22 1.49 -2.73 -0.273 0.46584E+04 97 kalsilite 7.58 3.92 -3.67 -0.524 0.62642E+04 99 kyanite 4.88 2.09 -2.78 -0.278 0.47490E+04 101 laumontite 2.88 2.76 -0.12 -0.008 0.20932E+03 103 leucite 4.12 0.49 -3.63 -0.363 0.62003E+04 105 lizardite 23.24 18.80 -4.45 -0.371 0.75921E+04 107 magnetite 20.09 18.89 -1.20 -0.098 0.20480E+04 113 margarite 17.32 15.14 -2.19 -0.087 0.37309E+04 116 microcline -2.49 -2.94 -0.45 -0.035 0.77443E+03 121 paragonite 4.24 3.58 -0.66 -0.039 0.11228E+04 122 nepheline 8.34 4.91 -3.42 -0.489 0.58478E+04 136 prehnite 19.37 17.14 -2.23 -0.131 0.38155E+04 137 prehnite-Fe 22.50 20.66 -1.84 -0.111 0.31396E+04 138 pumpellyite-Fe 46.27 43.36 -2.91 -0.065 0.49719E+04 139 pumpellyite-Mg 48.99 45.59 -3.41 -0.076 0.58193E+04 145 pyroxmangite 7.40 5.02 -2.38 -0.475 0.40576E+04 146 pyrophyllite -6.18 -8.19 -2.01 -0.126 0.34358E+04 147 quartz -2.99 -3.43 -0.44 -0.146 0.74820E+03 151 rhodochrosite -0.98 -5.24 -4.26 -1.420 0.72756E+04 152 rhodonite 7.45 5.02 -2.42 -0.485 0.41378E+04 153 sanidine -1.28 -2.94 -1.66 -0.128 0.28422E+04 155 siderite -2.61 -7.37 -4.76 -1.586 0.81231E+04 156 sillimanite 5.26 2.09 -3.17 -0.317 0.54070E+04 164 stilpnomelane-Fe 13.02 12.00 -1.02 -0.030 0.17345E+04 165 stilpnomelane-Mg 27.44 23.15 -4.29 -0.128 0.73329E+04 167 sudoite-Fe 18.30 13.41 -4.89 -0.158 0.83505E+04 168 sudoite 21.08 17.86 -3.21 -0.104 0.54869E+04 171 talc 16.49 11.94 -4.55 -0.268 0.77670E+04 174 tephroite 18.09 13.47 -4.61 -0.659 0.78775E+04 177 topaz-H 4.62 2.09 -2.52 -0.229 0.43090E+04 178 tridymite -2.63 -3.43 -0.80 -0.267 0.13682E+04 187 wairakite 3.95 2.76 -1.19 -0.070 0.20313E+04 188 walstromite 11.51 7.52 -3.99 -0.798 0.68094E+04 189 wollastonite 10.46 7.52 -2.94 -0.588 0.50199E+04 190 pseudo-wollastonite 11.00 7.52 -3.48 -0.696 0.59397E+04 191 zoisite 22.85 19.90 -2.95 -0.134 0.50385E+04 192 akaganeite 7.75 6.28 -1.47 -0.318 0.25125E+04 193 beidellite-Ca -1.65 -4.34 -2.69 -0.167 0.45991E+04 194 beidellite-H -2.33 -6.15 -3.82 -0.244 0.65216E+04 195 beidellite-K -1.52 -4.63 -3.11 -0.191 0.53163E+04 196 beidellite-Mg -1.79 -4.73 -2.95 -0.182 0.50285E+04 197 beidellite-Na -1.34 -4.30 -2.96 -0.181 0.50571E+04 199 chalcedony -2.80 -3.43 -0.63 -0.208 0.10675E+04 201 montmorillonite-Ca -2.29 -4.47 -2.18 -0.135 0.37225E+04 202 montmorillonite-K -2.24 -4.77 -2.53 -0.155 0.43178E+04 203 montmorillonite-Mg -2.48 -4.87 -2.39 -0.148 0.40751E+04 204 montmorillonite-Na -2.04 -4.44 -2.40 -0.147 0.40943E+04 205 nontronite-Ca 3.21 2.70 -0.51 -0.033 0.87076E+03 206 nontronite-H 2.53 0.90 -1.63 -0.110 0.27912E+04 207 nontronite-K 3.34 2.41 -0.93 -0.060 0.15893E+04 208 nontronite-Mg 3.07 2.31 -0.77 -0.050 0.13074E+04 209 nontronite-Na 3.52 2.74 -0.78 -0.050 0.13318E+04 224 tobermorite 9.82 5.69 -4.13 -1.127 0.70524E+04 233 boehmite 4.41 2.76 -1.65 -0.274 0.28089E+04 235 ferrous-oxide 9.81 6.32 -3.49 -0.872 0.59588E+04 240 silica-amorphous -2.09 -3.43 -1.34 -0.445 0.22817E+04 242 an20ab80 2.02 0.37 -1.65 -0.127 0.28123E+04 243 an25ab75 2.65 0.95 -1.70 -0.131 0.28978E+04 244 an30ab70 3.28 1.53 -1.75 -0.135 0.29930E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 0.0200000 g Current total amount of reactant added: 0.4390000 g New total amount of reactant added: 0.4590000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.5878E-14 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 7 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 0.4590000 Water: Moles liquid = 0.5550E+02 kg liquid = 0.9999E+00 Moles total = 0.5550E+02 kg total = 0.9999E+00 Activity = 1.0000 Stoichiometric ionic strength = .6272298E-03 Osmotic coef. = 0.9853 True ionic strength = .8295173E-03 Chg. balance for total moles = -.5878E-14 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.17922E-08 -8.7466 0.16952E-08 -8.7708 0.94589E+00 -0.0242 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13796E-03 -3.8603 0.13045E-03 -3.8846 0.94555E+00 -0.0243 4 SO4-- 0.25482E-04 -4.5938 0.21508E-04 -4.6674 0.84405E+00 -0.0736 5 HCO3- 0.12316E-04 -4.9095 0.11646E-04 -4.9338 0.94564E+00 -0.0243 6 HS- 0.78623E-13 -13.1045 0.74343E-13 -13.1288 0.94556E+00 -0.0243 7 Al+++ 0.40291E-23 -23.3948 0.28112E-23 -23.5511 0.69772E+00 -0.1563 8 H4SiO4 0.37357E-03 -3.4276 0.37357E-03 -3.4276 0.10000E+01 0.0000 9 Ca++ 0.30276E-06 -6.5189 0.25543E-06 -6.5927 0.84369E+00 -0.0738 10 Mg++ 0.12114E-08 -8.9167 0.10217E-08 -8.9907 0.84346E+00 -0.0739 11 Fe++ 0.71468E-11 -11.1459 0.60284E-11 -11.2198 0.84351E+00 -0.0739 12 K+ 0.68402E-04 -4.1649 0.64685E-04 -4.1892 0.94565E+00 -0.0243 13 Na+ 0.73378E-03 -3.1344 0.69383E-03 -3.1587 0.94555E+00 -0.0243 14 Mn++ 0.96001E-09 -9.0177 0.80982E-09 -9.0916 0.84355E+00 -0.0739 15 HPO4-- 0.20700E-06 -6.6840 0.17472E-06 -6.7577 0.84405E+00 -0.0736 16 HSiO3- 0.21762E-03 -3.6623 0.20577E-03 -3.6866 0.94555E+00 -0.0243 17 Ca(HSiO3)+ 0.12658E-08 -8.8976 0.11970E-08 -8.9219 0.94566E+00 -0.0243 18 Mg(HSiO3)+ 0.63012E-11 -11.2006 0.59588E-11 -11.2248 0.94566E+00 -0.0243 19 NaHSiO3,aq 0.23091E-05 -5.6366 0.23091E-05 -5.6366 0.10000E+01 0.0000 20 AlO+ 0.14073E-12 -12.8516 0.13309E-12 -12.8759 0.94566E+00 -0.0243 21 AlOH+2 0.13317E-17 -17.8756 0.11234E-17 -17.9495 0.84360E+00 -0.0739 22 HAlO2,aq 0.15635E-07 -7.8059 0.15635E-07 -7.8059 0.10000E+01 0.0000 23 AlO2- 0.21594E-04 -4.6657 0.20416E-04 -4.6900 0.94545E+00 -0.0244 24 CH4,aq 0.39111E-19 -19.4077 0.39104E-19 -19.4078 0.99981E+00 -0.0001 29 CO,aq 0.48255E-18 -18.3165 0.48255E-18 -18.3165 0.10000E+01 0.0000 30 CO2,aq 0.42194E-07 -7.3747 0.42186E-07 -7.3748 0.99981E+00 -0.0001 31 CO3-2 0.71106E-06 -6.1481 0.60009E-06 -6.2218 0.84394E+00 -0.0737 32 CaCO3,aq 0.19220E-08 -8.7162 0.19220E-08 -8.7162 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.80300E-10 -10.0953 0.75937E-10 -10.1195 0.94566E+00 -0.0243 34 CaCl+ 0.57021E-10 -10.2440 0.53923E-10 -10.2682 0.94566E+00 -0.0243 35 CaCl2,aq 0.16711E-14 -14.7770 0.16711E-14 -14.7770 0.10000E+01 0.0000 36 CaOH+ 0.11356E-07 -7.9448 0.10739E-07 -7.9690 0.94566E+00 -0.0243 37 CaSO4,aq 0.17446E-08 -8.7583 0.17446E-08 -8.7583 0.10000E+01 0.0000 38 HCl,aq 0.40521E-13 -13.3923 0.40521E-13 -13.3923 0.10000E+01 0.0000 43 FeCl+ 0.13162E-14 -14.8807 0.12447E-14 -14.9049 0.94566E+00 -0.0243 46 FeO,aq 0.81533E-10 -10.0887 0.81533E-10 -10.0887 0.10000E+01 0.0000 47 FeOH+ 0.12241E-09 -9.9122 0.11576E-09 -9.9364 0.94566E+00 -0.0243 48 HFeO2- 0.53222E-09 -9.2739 0.50324E-09 -9.2982 0.94555E+00 -0.0243 49 FeO+ 0.13683E-13 -13.8638 0.12939E-13 -13.8881 0.94566E+00 -0.0243 51 FeO2- 0.97439E-09 -9.0113 0.92134E-09 -9.0356 0.94555E+00 -0.0243 52 HFeO2,aq 0.19864E-09 -9.7019 0.19864E-09 -9.7019 0.10000E+01 0.0000 53 H2,aq 0.45543E-09 -9.3416 0.45534E-09 -9.3417 0.99981E+00 -0.0001 54 KCl,aq 0.15293E-09 -9.8155 0.15293E-09 -9.8155 0.10000E+01 0.0000 55 KHSO4,aq 0.66682E-17 -17.1760 0.66682E-17 -17.1760 0.10000E+01 0.0000 56 KOH,aq 0.16296E-07 -7.7879 0.16296E-07 -7.7879 0.10000E+01 0.0000 57 KSO4- 0.22832E-07 -7.6415 0.21589E-07 -7.6658 0.94555E+00 -0.0243 58 MgCO3,aq 0.19271E-11 -11.7151 0.19271E-11 -11.7151 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.32821E-12 -12.4838 0.31038E-12 -12.5081 0.94566E+00 -0.0243 60 MgCl+ 0.20672E-12 -12.6846 0.19549E-12 -12.7089 0.94566E+00 -0.0243 61 MgOH+ 0.25136E-09 -9.5997 0.23770E-09 -9.6240 0.94566E+00 -0.0243 63 MnO,aq 0.29184E-09 -9.5349 0.29184E-09 -9.5349 0.10000E+01 0.0000 64 MnOH+ 0.15276E-08 -8.8160 0.14446E-08 -8.8403 0.94566E+00 -0.0243 65 MnO2-2 0.39936E-14 -14.3986 0.33704E-14 -14.4723 0.84394E+00 -0.0737 66 HMnO2- 0.13238E-11 -11.8782 0.12517E-11 -11.9025 0.94555E+00 -0.0243 69 MnCl+ 0.68789E-12 -12.1625 0.65051E-12 -12.1867 0.94566E+00 -0.0243 70 MnSO4,aq 0.50284E-11 -11.2986 0.50284E-11 -11.2986 0.10000E+01 0.0000 71 NaCl,aq 0.29994E-07 -7.5230 0.29994E-07 -7.5230 0.10000E+01 0.0000 72 NaOH,aq 0.17585E-06 -6.7549 0.17585E-06 -6.7549 0.10000E+01 0.0000 74 OH- 0.36049E-03 -3.4431 0.34083E-03 -3.4675 0.94545E+00 -0.0244 79 HPO3-2 0.29377E-18 -18.5320 0.24792E-18 -18.6057 0.84394E+00 -0.0737 82 H3PO4,aq 0.35115E-14 -14.4545 0.35115E-14 -14.4545 0.10000E+01 0.0000 83 H2PO4- 0.57779E-08 -8.2382 0.54636E-08 -8.2625 0.94561E+00 -0.0243 84 PO4-3 0.12017E-09 -9.9202 0.84090E-10 -10.0753 0.69976E+00 -0.1551 87 H2P2O7-2 0.27735E-17 -17.5570 0.23407E-17 -17.6307 0.84394E+00 -0.0737 88 HP2O7-3 0.39514E-15 -15.4032 0.27571E-15 -15.5596 0.69774E+00 -0.1563 89 P2O7-4 0.72545E-16 -16.1394 0.38854E-16 -16.4106 0.53558E+00 -0.2712 90 H2S,aq 0.38957E-15 -15.4094 0.38950E-15 -15.4095 0.99981E+00 -0.0001 97 SO3-2 0.15067E-14 -14.8220 0.12727E-14 -14.8953 0.84467E+00 -0.0733 98 HSO3- 0.14286E-15 -15.8451 0.13508E-15 -15.8694 0.94555E+00 -0.0243 99 HSO4- 0.37155E-10 -10.4300 0.35138E-10 -10.4542 0.94571E+00 -0.0242 Charge balance for all species = -.5874E-14 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.1792160E-08 -.6677205E-03 -.6729644E+00 0.0000 2 H2O 0.1000000E+01 0.5550843E+02 0.9999153E+06 0.0000 3 Cl- 0.1379571E-03 0.1379873E-03 0.4891644E+01 4.8862 4 SO4-- 0.2548228E-04 0.2550693E-04 0.2450026E+01 12.8742 5 HCO3- 0.1231598E-04 0.1307124E-04 0.7975022E+00 3.8370 6 HS- 0.7862265E-13 -.3269407E-10 -.1081166E-05 -4.3580 7 Al+++ 0.4029144E-23 0.2160945E-04 0.5830053E+00 2.7612 8 H4SiO4 0.3735728E-03 0.5935019E-03 0.5703977E+02 -3.4276 9 Ca++ 0.3027592E-06 0.3191849E-06 0.1279120E-01 10.9488 10 Mg++ 0.1211376E-08 0.1471497E-08 0.3577195E-04 8.5509 11 Fe++ 0.7146820E-11 0.1916354E-08 0.1070135E-03 6.3218 12 K+ 0.6840245E-04 0.6844173E-04 0.2675979E+01 4.5816 13 Na+ 0.7337829E-03 0.7362978E-03 0.1692589E+02 5.6120 14 Mn++ 0.9600116E-09 0.2786461E-08 0.1530694E-03 8.4500 15 HPO4-- 0.2069958E-06 0.2128939E-06 0.2043159E-01 10.7839 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.7587319E-02 -.6676570E-03 -.6919662E-02 0.0000000E+00 2 H2O 0.5550250E+02 0.5550316E+02 -.6591503E-03 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.3822492E-04 0.2550450E-04 0.1272042E-04 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.1272045E-04 -.3269096E-10 -.1272042E-04 0.0000000E+00 7 Al+++ 0.1496680E-02 0.2160739E-04 0.1475073E-02 0.0000000E+00 8 H4SiO4 0.4779467E-02 0.5934454E-03 0.4186022E-02 0.0000000E+00 9 Ca++ 0.5423865E-03 0.3191546E-06 0.5420674E-03 0.0000000E+00 10 Mg++ 0.3642857E-03 0.1471357E-08 0.3642842E-03 0.0000000E+00 11 Fe++ 0.3272709E-03 0.1916172E-08 0.3272690E-03 0.0000000E+00 12 K+ 0.9745223E-04 0.6843522E-04 0.2901701E-04 0.0000000E+00 13 Na+ 0.7362278E-03 0.7362278E-03 0.0000000E+00 0.0000000E+00 14 Mn++ 0.7958416E-05 0.2786196E-08 0.7955629E-05 0.0000000E+00 15 HPO4-- 0.2716168E-05 0.2128737E-06 0.2503294E-05 0.0000000E+00 Chg. balance for solid moles: 0.7344E-18 Mass of aqueous solution: 0.999991E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 0.4590000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) apatite-OH 0.8344E-06 -6.079 0.4192E-03 -3.378 0.8829E-01 0.1332E-03 clinochlore 0.7286E-04 -4.138 0.4050E-01 -1.393 8.530 0.1540E-01 daphnite 0.4510E-04 -4.346 0.3218E-01 -1.492 6.778 0.9752E-02 chlorite-Mn 0.1591E-05 -5.798 0.1128E-02 -2.948 0.2376 0.3595E-03 hematite 0.5088E-04 -4.293 0.8126E-02 -2.090 1.712 0.1540E-02 kaolinite 0.3657E-04 -4.437 0.9440E-02 -2.025 1.988 0.3632E-02 lawsonite 0.1962E-04 -4.707 0.6164E-02 -2.210 1.298 0.1988E-02 muscovite 0.2902E-04 -4.537 0.1156E-01 -1.937 2.434 0.4087E-02 stilbite 0.5183E-03 -3.285 0.3652 -0.437 76.93 0.1704 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.6094E+00 0.6094E+00 1.0000 -0.215 daphnite 0.3773E+00 0.3773E+00 1.0000 -0.423 chlorite-Mn 0.1331E-01 0.1331E-01 1.0000 -1.876 hematite 0.1000E+01 0.1000E+01 1.0000 0.000 kaolinite 0.1000E+01 0.1000E+01 1.0000 0.000 lawsonite 0.1000E+01 0.1000E+01 1.0000 0.000 muscovite 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 0.474753 g Volume = 0.207250 cm3 Porosity: 82.4898% V(tot) - V(min): 0.97635E+00 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.4590000 g log = -0.3382 Original solution: 1000.0103000 g Original solution / Rock added: 2178.67 (Water/Rock Ratio), log = 3.3382 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0203 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.1000E+01 0.9860 0.1006E+01 0.1020E+01 CO2,gas 0.4392E-05 1.0071 0.4513E-05 0.4482E-05 CH4,gas 0.5571E-16 1.0125 0.5756E-16 0.5685E-16 H2,gas 0.5856E-06 1.0005 0.5978E-06 0.5975E-06 H2S,gas 0.1054E-13 0.9960 0.1071E-13 0.1075E-13 S2,gas 0.1180E-34 1.0000 0.1204E-34 0.1204E-34 CO,gas 0.7048E-15 1.0000 0.7191E-15 0.7191E-15 SO3,gas 0.2290E-37 1.0000 0.2337E-37 0.2337E-37 SO2,gas 0.5327E-21 1.0000 0.5435E-21 0.5435E-21 HCl,gas 0.7008E-16 1.0000 0.7150E-16 0.7150E-16 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 32 apatite-OH -18.15 -18.15 0.00 0.000 -0.60662E-11 46 clinochlore 39.07 39.07 0.00 0.000 0.12132E-10 47 daphnite 28.97 28.97 0.00 0.000 0.00000E+00 48 chlorite-Mn 46.87 46.87 0.00 0.000 0.00000E+00 90 hematite 12.57 12.57 0.00 0.000 0.90992E-11 98 kaolinite -1.33 -1.33 0.00 0.000 -0.64453E-11 102 lawsonite 9.62 9.62 0.00 0.000 0.00000E+00 120 muscovite 2.58 2.58 0.00 0.000 -0.18198E-10 163 stilbite -7.52 -7.52 0.00 0.000 -0.90992E-11 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -13.70 -7.04 -2.348 0.12028E+05 -5.345 3 CH4,gas 4.54 -13.40 -17.94 -4.485 0.30630E+05 -16.240 4 H2,gas 8.00 0.08 -7.92 -4.527 0.13527E+05 -6.223 5 H2S,gas -6.23 -21.90 -15.67 -7.835 0.26755E+05 -13.970 6 S2,gas -7.34 -43.95 -36.62 -5.634 0.62525E+05 -34.919 7 CO,gas 3.21 -13.63 -16.84 -5.182 0.28758E+05 -15.143 8 SO3,gas 17.12 -22.21 -39.33 -9.833 0.67155E+05 -37.631 9 SO2,gas 0.83 -22.13 -22.96 -6.124 0.39210E+05 -21.265 10 HCl,gas 5.19 -12.66 -17.84 -8.922 0.30469E+05 -16.146 11 acmite 7.71 5.04 -2.67 -0.277 0.45587E+04 15 albite-high 0.69 -1.91 -2.60 -0.200 0.44440E+04 16 albite -0.38 -1.91 -1.53 -0.117 0.26052E+04 19 spessartine 24.46 20.59 -3.87 -0.193 0.66043E+04 20 analcite 3.32 1.52 -1.80 -0.200 0.30800E+04 21 andalusite 5.00 2.09 -2.91 -0.291 0.49631E+04 22 andradite 39.01 35.13 -3.88 -0.202 0.66231E+04 23 grossular 32.73 28.09 -4.65 -0.232 0.79317E+04 26 annite 20.12 16.03 -4.10 -0.228 0.69975E+04 27 phlogopite 27.06 22.71 -4.35 -0.242 0.74308E+04 29 anorthite 12.71 9.62 -3.09 -0.238 0.52833E+04 35 aragonite 0.97 -2.76 -3.72 -1.241 0.63557E+04 36 brucite 12.57 8.55 -4.02 -0.804 0.68600E+04 37 calcite 0.81 -2.76 -3.57 -1.189 0.60914E+04 38 carnegieite-low 9.02 4.95 -4.08 -0.583 0.69625E+04 40 carpholite-Mg 8.58 7.22 -1.36 -0.091 0.23289E+04 41 carpholite-Fe 6.71 4.99 -1.72 -0.115 0.29431E+04 42 celadonite 5.34 2.18 -3.16 -0.186 0.53928E+04 43 celadonite-Fe 3.88 -0.05 -3.92 -0.231 0.66974E+04 50 chloritoid-Mg 13.20 10.65 -2.55 -0.170 0.43574E+04 51 chloritoid-Fe 9.17 8.42 -0.76 -0.050 0.12926E+04 52 chloritoid-Mn 11.40 10.54 -0.86 -0.057 0.14620E+04 54 coesite -2.38 -3.43 -1.05 -0.351 0.17955E+04 59 corundum 8.38 5.52 -2.86 -0.260 0.48845E+04 61 cristobalite -2.56 -3.43 -0.87 -0.289 0.14809E+04 63 cymrite-K 1.69 -2.94 -4.63 -0.385 0.78978E+04 65 diaspore 2.87 2.76 -0.11 -0.019 0.19202E+03 67 diopside 16.18 12.64 -3.54 -0.354 0.60391E+04 68 hedenbergite 14.21 10.42 -3.79 -0.379 0.64763E+04 75 epidote 24.67 23.42 -1.25 -0.061 0.21335E+04 76 clinozoisite 22.81 19.90 -2.91 -0.132 0.49645E+04 77 epidote-Fe 29.84 26.94 -2.90 -0.151 0.49492E+04 78 fayalite 14.05 9.22 -4.83 -0.690 0.82468E+04 83 gibbsite 4.08 2.76 -1.32 -0.188 0.22506E+04 87 greenalite 16.14 12.11 -4.03 -0.336 0.68802E+04 91 heulandite -5.83 -7.52 -1.69 -0.077 0.28938E+04 95 jadeite 4.22 1.52 -2.70 -0.270 0.46055E+04 97 kalsilite 7.58 3.92 -3.67 -0.524 0.62642E+04 99 kyanite 4.88 2.09 -2.78 -0.278 0.47490E+04 101 laumontite 2.88 2.76 -0.12 -0.008 0.20932E+03 103 leucite 4.12 0.49 -3.63 -0.363 0.62003E+04 105 lizardite 23.24 18.80 -4.45 -0.371 0.75921E+04 107 magnetite 20.09 18.89 -1.20 -0.098 0.20480E+04 113 margarite 17.32 15.14 -2.19 -0.087 0.37309E+04 116 microcline -2.49 -2.94 -0.45 -0.035 0.77443E+03 121 paragonite 4.24 3.61 -0.63 -0.037 0.10698E+04 122 nepheline 8.34 4.95 -3.39 -0.485 0.57948E+04 136 prehnite 19.37 17.14 -2.23 -0.131 0.38155E+04 137 prehnite-Fe 22.50 20.66 -1.84 -0.111 0.31396E+04 138 pumpellyite-Fe 46.27 43.36 -2.91 -0.065 0.49719E+04 139 pumpellyite-Mg 48.99 45.59 -3.41 -0.076 0.58193E+04 145 pyroxmangite 7.40 5.02 -2.38 -0.475 0.40576E+04 146 pyrophyllite -6.18 -8.19 -2.01 -0.126 0.34358E+04 147 quartz -2.99 -3.43 -0.44 -0.146 0.74820E+03 151 rhodochrosite -0.98 -5.25 -4.28 -1.426 0.73051E+04 152 rhodonite 7.45 5.02 -2.42 -0.485 0.41378E+04 153 sanidine -1.28 -2.94 -1.66 -0.128 0.28422E+04 155 siderite -2.61 -7.38 -4.77 -1.592 0.81526E+04 156 sillimanite 5.26 2.09 -3.17 -0.317 0.54070E+04 164 stilpnomelane-Fe 13.02 12.00 -1.02 -0.030 0.17345E+04 165 stilpnomelane-Mg 27.44 23.15 -4.29 -0.128 0.73329E+04 167 sudoite-Fe 18.30 13.41 -4.89 -0.158 0.83505E+04 168 sudoite 21.08 17.86 -3.21 -0.104 0.54869E+04 171 talc 16.49 11.94 -4.55 -0.268 0.77670E+04 174 tephroite 18.09 13.47 -4.61 -0.659 0.78774E+04 177 topaz-H 4.62 2.09 -2.52 -0.229 0.43090E+04 178 tridymite -2.63 -3.43 -0.80 -0.267 0.13682E+04 187 wairakite 3.95 2.76 -1.19 -0.070 0.20313E+04 188 walstromite 11.51 7.52 -3.99 -0.798 0.68094E+04 189 wollastonite 10.46 7.52 -2.94 -0.588 0.50199E+04 190 pseudo-wollastonite 11.00 7.52 -3.48 -0.696 0.59397E+04 191 zoisite 22.85 19.90 -2.95 -0.134 0.50385E+04 192 akaganeite 7.75 6.28 -1.47 -0.318 0.25125E+04 193 beidellite-Ca -1.65 -4.34 -2.69 -0.167 0.45991E+04 194 beidellite-H -2.33 -6.15 -3.82 -0.244 0.65216E+04 195 beidellite-K -1.52 -4.63 -3.11 -0.191 0.53163E+04 196 beidellite-Mg -1.79 -4.73 -2.95 -0.182 0.50285E+04 197 beidellite-Na -1.34 -4.29 -2.95 -0.181 0.50396E+04 199 chalcedony -2.80 -3.43 -0.63 -0.208 0.10675E+04 201 montmorillonite-Ca -2.29 -4.47 -2.18 -0.135 0.37225E+04 202 montmorillonite-K -2.24 -4.77 -2.53 -0.155 0.43178E+04 203 montmorillonite-Mg -2.48 -4.87 -2.39 -0.148 0.40751E+04 204 montmorillonite-Na -2.04 -4.43 -2.39 -0.146 0.40769E+04 205 nontronite-Ca 3.21 2.70 -0.51 -0.033 0.87076E+03 206 nontronite-H 2.53 0.90 -1.63 -0.110 0.27912E+04 207 nontronite-K 3.34 2.41 -0.93 -0.060 0.15893E+04 208 nontronite-Mg 3.07 2.31 -0.77 -0.050 0.13074E+04 209 nontronite-Na 3.52 2.75 -0.77 -0.049 0.13143E+04 224 tobermorite 9.82 5.69 -4.13 -1.127 0.70524E+04 233 boehmite 4.41 2.76 -1.65 -0.274 0.28089E+04 235 ferrous-oxide 9.81 6.32 -3.49 -0.872 0.59588E+04 240 silica-amorphous -2.09 -3.43 -1.34 -0.445 0.22817E+04 242 an20ab80 2.02 0.40 -1.62 -0.125 0.27699E+04 243 an25ab75 2.65 0.97 -1.67 -0.129 0.28581E+04 244 an30ab70 3.28 1.55 -1.73 -0.133 0.29559E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 0.0200000 g Current total amount of reactant added: 0.4590000 g New total amount of reactant added: 0.4790000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.5880E-14 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 6 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 0.4790000 Water: Moles liquid = 0.5550E+02 kg liquid = 0.9999E+00 Moles total = 0.5550E+02 kg total = 0.9999E+00 Activity = 1.0000 Stoichiometric ionic strength = .6422081E-03 Osmotic coef. = 0.9851 True ionic strength = .8520278E-03 Chg. balance for total moles = -.5880E-14 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.17292E-08 -8.7621 0.16349E-08 -8.7865 0.94543E+00 -0.0244 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13796E-03 -3.8603 0.13038E-03 -3.8848 0.94509E+00 -0.0245 4 SO4-- 0.25483E-04 -4.5937 0.21467E-04 -4.6682 0.84240E+00 -0.0745 5 HCO3- 0.12292E-04 -4.9104 0.11618E-04 -4.9349 0.94517E+00 -0.0245 6 HS- 0.75718E-13 -13.1208 0.71561E-13 -13.1453 0.94510E+00 -0.0245 7 Al+++ 0.36303E-23 -23.4401 0.25218E-23 -23.5983 0.69465E+00 -0.1582 8 H4SiO4 0.37357E-03 -3.4276 0.37357E-03 -3.4276 0.10000E+01 0.0000 9 Ca++ 0.28216E-06 -6.5495 0.23758E-06 -6.6242 0.84203E+00 -0.0747 10 Mg++ 0.11290E-08 -8.9473 0.95035E-09 -9.0221 0.84180E+00 -0.0748 11 Fe++ 0.66605E-11 -11.1765 0.56072E-11 -11.2513 0.84185E+00 -0.0748 12 K+ 0.66002E-04 -4.1804 0.62384E-04 -4.2049 0.94519E+00 -0.0245 13 Na+ 0.75871E-03 -3.1199 0.71705E-03 -3.1445 0.94508E+00 -0.0245 14 Mn++ 0.89471E-09 -9.0483 0.75325E-09 -9.1231 0.84189E+00 -0.0747 15 HPO4-- 0.22298E-06 -6.6517 0.18784E-06 -6.7262 0.84241E+00 -0.0745 16 HSiO3- 0.22576E-03 -3.6464 0.21336E-03 -3.6709 0.94509E+00 -0.0245 17 Ca(HSiO3)+ 0.12214E-08 -8.9132 0.11544E-08 -8.9376 0.94520E+00 -0.0245 18 Mg(HSiO3)+ 0.60801E-11 -11.2161 0.57469E-11 -11.2406 0.94520E+00 -0.0245 19 NaHSiO3,aq 0.24744E-05 -5.6065 0.24744E-05 -5.6065 0.10000E+01 0.0000 20 AlO+ 0.13579E-12 -12.8671 0.12835E-12 -12.8916 0.94520E+00 -0.0245 21 AlOH+2 0.12410E-17 -17.9062 0.10449E-17 -17.9809 0.84194E+00 -0.0747 22 HAlO2,aq 0.15635E-07 -7.8059 0.15635E-07 -7.8059 0.10000E+01 0.0000 23 AlO2- 0.22401E-04 -4.6497 0.21169E-04 -4.6743 0.94498E+00 -0.0246 24 CH4,aq 0.37628E-19 -19.4245 0.37620E-19 -19.4246 0.99980E+00 -0.0001 29 CO,aq 0.46424E-18 -18.3333 0.46424E-18 -18.3333 0.10000E+01 0.0000 30 CO2,aq 0.40594E-07 -7.3915 0.40586E-07 -7.3916 0.99980E+00 -0.0001 31 CO3-2 0.73692E-06 -6.1326 0.62070E-06 -6.2071 0.84229E+00 -0.0745 32 CaCO3,aq 0.18491E-08 -8.7330 0.18491E-08 -8.7330 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.74543E-10 -10.1276 0.70458E-10 -10.1521 0.94520E+00 -0.0245 34 CaCl+ 0.53036E-10 -10.2754 0.50130E-10 -10.2999 0.94520E+00 -0.0245 35 CaCl2,aq 0.15528E-14 -14.8089 0.15528E-14 -14.8089 0.10000E+01 0.0000 36 CaOH+ 0.10957E-07 -7.9603 0.10357E-07 -7.9848 0.94520E+00 -0.0245 37 CaSO4,aq 0.16196E-08 -8.7906 0.16196E-08 -8.7906 0.10000E+01 0.0000 38 HCl,aq 0.39060E-13 -13.4083 0.39060E-13 -13.4083 0.10000E+01 0.0000 43 FeCl+ 0.12243E-14 -14.9121 0.11572E-14 -14.9366 0.94520E+00 -0.0245 46 FeO,aq 0.81533E-10 -10.0887 0.81533E-10 -10.0887 0.10000E+01 0.0000 47 FeOH+ 0.11811E-09 -9.9277 0.11164E-09 -9.9522 0.94520E+00 -0.0245 48 HFeO2- 0.55212E-09 -9.2580 0.52180E-09 -9.2825 0.94509E+00 -0.0245 49 FeO+ 0.13202E-13 -13.8793 0.12479E-13 -13.9038 0.94520E+00 -0.0245 51 FeO2- 0.10108E-08 -8.9953 0.95532E-09 -9.0199 0.94509E+00 -0.0245 52 HFeO2,aq 0.19864E-09 -9.7019 0.19864E-09 -9.7019 0.10000E+01 0.0000 53 H2,aq 0.45543E-09 -9.3416 0.45534E-09 -9.3417 0.99980E+00 -0.0001 54 KCl,aq 0.14742E-09 -9.8315 0.14742E-09 -9.8315 0.10000E+01 0.0000 55 KHSO4,aq 0.61904E-17 -17.2083 0.61904E-17 -17.2083 0.10000E+01 0.0000 56 KOH,aq 0.16296E-07 -7.7879 0.16296E-07 -7.7879 0.10000E+01 0.0000 57 KSO4- 0.21989E-07 -7.6578 0.20781E-07 -7.6823 0.94509E+00 -0.0245 58 MgCO3,aq 0.18540E-11 -11.7319 0.18540E-11 -11.7319 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.30468E-12 -12.5162 0.28798E-12 -12.5406 0.94520E+00 -0.0245 60 MgCl+ 0.19228E-12 -12.7161 0.18174E-12 -12.7405 0.94520E+00 -0.0245 61 MgOH+ 0.24254E-09 -9.6152 0.22924E-09 -9.6397 0.94520E+00 -0.0245 63 MnO,aq 0.29185E-09 -9.5348 0.29185E-09 -9.5348 0.10000E+01 0.0000 64 MnOH+ 0.14740E-08 -8.8315 0.13932E-08 -8.8560 0.94520E+00 -0.0245 65 MnO2-2 0.43022E-14 -14.3663 0.36237E-14 -14.4408 0.84229E+00 -0.0745 66 HMnO2- 0.13733E-11 -11.8622 0.12979E-11 -11.8867 0.94509E+00 -0.0245 69 MnCl+ 0.63984E-12 -12.1939 0.60477E-12 -12.2184 0.94520E+00 -0.0245 70 MnSO4,aq 0.46682E-11 -11.3308 0.46682E-11 -11.3308 0.10000E+01 0.0000 71 NaCl,aq 0.30983E-07 -7.5089 0.30983E-07 -7.5089 0.10000E+01 0.0000 72 NaOH,aq 0.18844E-06 -6.7248 0.18844E-06 -6.7248 0.10000E+01 0.0000 74 OH- 0.37398E-03 -3.4272 0.35340E-03 -3.4517 0.94498E+00 -0.0246 79 HPO3-2 0.31645E-18 -18.4997 0.26655E-18 -18.5742 0.84229E+00 -0.0745 82 H3PO4,aq 0.35115E-14 -14.4545 0.35115E-14 -14.4545 0.10000E+01 0.0000 83 H2PO4- 0.59940E-08 -8.2223 0.56652E-08 -8.2468 0.94514E+00 -0.0245 84 PO4-3 0.13455E-09 -9.8711 0.93742E-10 -10.0281 0.69673E+00 -0.1569 87 H2P2O7-2 0.29877E-17 -17.5247 0.25165E-17 -17.5992 0.84229E+00 -0.0745 88 HP2O7-3 0.44244E-15 -15.3541 0.30735E-15 -15.5124 0.69467E+00 -0.1582 89 P2O7-4 0.84513E-16 -16.0731 0.44911E-16 -16.3476 0.53141E+00 -0.2746 90 H2S,aq 0.36166E-15 -15.4417 0.36158E-15 -15.4418 0.99980E+00 -0.0001 97 SO3-2 0.15067E-14 -14.8220 0.12702E-14 -14.8961 0.84303E+00 -0.0742 98 HSO3- 0.13758E-15 -15.8614 0.13003E-15 -15.8860 0.94509E+00 -0.0245 99 HSO4- 0.35782E-10 -10.4463 0.33823E-10 -10.4708 0.94525E+00 -0.0245 Charge balance for all species = -.5759E-14 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.1729247E-08 -.6927756E-03 -.6982154E+00 0.0000 2 H2O 0.1000000E+01 0.5550844E+02 0.9999140E+06 0.0000 3 Cl- 0.1379566E-03 0.1379878E-03 0.4891655E+01 4.9017 4 SO4-- 0.2548334E-04 0.2550703E-04 0.2450032E+01 12.9048 5 HCO3- 0.1229185E-04 0.1307129E-04 0.7975040E+00 3.8516 6 HS- 0.7571807E-13 -.3725129E-10 -.1231867E-05 -4.3588 7 Al+++ 0.3630289E-23 0.2241703E-04 0.6047922E+00 2.7612 8 H4SiO4 0.3735728E-03 0.6018051E-03 0.5783770E+02 -3.4276 9 Ca++ 0.2821571E-06 0.2979321E-06 0.1193948E-01 10.9488 10 Mg++ 0.1128952E-08 0.1379918E-08 0.3354564E-04 8.5509 11 Fe++ 0.6660525E-11 0.1967912E-08 0.1098924E-03 6.3218 12 K+ 0.6600167E-04 0.6604010E-04 0.2582075E+01 4.5816 13 Na+ 0.7587141E-03 0.7614079E-03 0.1750309E+02 5.6421 14 Mn++ 0.8947137E-09 0.2667239E-08 0.1465200E-03 8.4500 15 HPO4-- 0.2229823E-06 0.2291109E-06 0.2198792E-01 10.8468 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.7918489E-02 -.6927072E-03 -.7225782E-02 0.0000000E+00 2 H2O 0.5550225E+02 0.5550296E+02 -.7138892E-03 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.3877919E-04 0.2550451E-04 0.1327469E-04 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.1327472E-04 -.3724761E-10 -.1327469E-04 0.0000000E+00 7 Al+++ 0.1561895E-02 0.2241481E-04 0.1539480E-02 0.0000000E+00 8 H4SiO4 0.4987723E-02 0.6017457E-03 0.4385977E-02 0.0000000E+00 9 Ca++ 0.5653894E-03 0.2979027E-06 0.5650915E-03 0.0000000E+00 10 Mg++ 0.3801587E-03 0.1379782E-08 0.3801574E-03 0.0000000E+00 11 Fe++ 0.3415311E-03 0.1967717E-08 0.3415291E-03 0.0000000E+00 12 K+ 0.1016985E-03 0.6603358E-04 0.3566494E-04 0.0000000E+00 13 Na+ 0.7613327E-03 0.7613327E-03 0.0000000E+00 0.0000000E+00 14 Mn++ 0.8305187E-05 0.2666976E-08 0.8302521E-05 0.0000000E+00 15 HPO4-- 0.2834519E-05 0.2290883E-06 0.2605431E-05 0.0000000E+00 Chg. balance for solid moles: 0.1474E-18 Mass of aqueous solution: 0.999988E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 0.4790000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) apatite-OH 0.8685E-06 -6.061 0.4363E-03 -3.360 0.8781E-01 0.1386E-03 clinochlore 0.7603E-04 -4.119 0.4226E-01 -1.374 8.506 0.1607E-01 daphnite 0.4707E-04 -4.327 0.3358E-01 -1.474 6.759 0.1018E-01 chlorite-Mn 0.1661E-05 -5.780 0.1177E-02 -2.929 0.2369 0.3752E-03 hematite 0.5310E-04 -4.275 0.8480E-02 -2.072 1.707 0.1607E-02 kaolinite 0.3074E-04 -4.512 0.7935E-02 -2.100 1.597 0.3053E-02 lawsonite 0.1640E-04 -4.785 0.5154E-02 -2.288 1.037 0.1662E-02 muscovite 0.3566E-04 -4.448 0.1421E-01 -1.848 2.859 0.5023E-02 stilbite 0.5443E-03 -3.264 0.3836 -0.416 77.21 0.1789 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.6094E+00 0.6094E+00 1.0000 -0.215 daphnite 0.3773E+00 0.3773E+00 1.0000 -0.423 chlorite-Mn 0.1331E-01 0.1331E-01 1.0000 -1.876 hematite 0.1000E+01 0.1000E+01 1.0000 0.000 kaolinite 0.1000E+01 0.1000E+01 1.0000 0.000 lawsonite 0.1000E+01 0.1000E+01 1.0000 0.000 muscovite 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 0.496843 g Volume = 0.217034 cm3 Porosity: 81.7863% V(tot) - V(min): 0.97457E+00 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.4790000 g log = -0.3197 Original solution: 1000.0103000 g Original solution / Rock added: 2087.70 (Water/Rock Ratio), log = 3.3197 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0203 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.1000E+01 0.9860 0.1006E+01 0.1020E+01 CO2,gas 0.4226E-05 1.0071 0.4342E-05 0.4312E-05 CH4,gas 0.5360E-16 1.0125 0.5537E-16 0.5469E-16 H2,gas 0.5856E-06 1.0005 0.5978E-06 0.5975E-06 H2S,gas 0.9781E-14 0.9960 0.9940E-14 0.9979E-14 S2,gas 0.1017E-34 1.0000 0.1038E-34 0.1038E-34 CO,gas 0.6780E-15 1.0000 0.6918E-15 0.6918E-15 SO3,gas 0.2126E-37 1.0000 0.2170E-37 0.2170E-37 SO2,gas 0.4945E-21 1.0000 0.5046E-21 0.5046E-21 HCl,gas 0.6755E-16 1.0000 0.6892E-16 0.6892E-16 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 32 apatite-OH -18.15 -18.15 0.00 0.000 0.00000E+00 46 clinochlore 39.07 39.07 0.00 0.000 -0.12132E-10 47 daphnite 28.97 28.97 0.00 0.000 -0.24265E-10 48 chlorite-Mn 46.87 46.87 0.00 0.000 -0.12132E-10 90 hematite 12.57 12.57 0.00 0.000 -0.30331E-11 98 kaolinite -1.33 -1.33 0.00 0.000 0.56870E-11 102 lawsonite 9.62 9.62 0.00 0.000 0.12132E-10 120 muscovite 2.58 2.58 0.00 0.000 -0.18198E-10 163 stilbite -7.52 -7.52 0.00 0.000 0.15165E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -13.72 -7.06 -2.354 0.12057E+05 -5.362 3 CH4,gas 4.54 -13.41 -17.96 -4.489 0.30659E+05 -16.257 4 H2,gas 8.00 0.08 -7.92 -4.527 0.13527E+05 -6.223 5 H2S,gas -6.23 -21.93 -15.70 -7.851 0.26810E+05 -14.003 6 S2,gas -7.34 -44.02 -36.68 -5.644 0.62635E+05 -34.984 7 CO,gas 3.21 -13.64 -16.86 -5.187 0.28786E+05 -15.160 8 SO3,gas 17.12 -22.24 -39.36 -9.841 0.67211E+05 -37.664 9 SO2,gas 0.83 -22.16 -23.00 -6.132 0.39265E+05 -21.297 10 HCl,gas 5.19 -12.67 -17.86 -8.930 0.30496E+05 -16.162 11 acmite 7.71 5.07 -2.64 -0.274 0.45074E+04 15 albite-high 0.69 -1.88 -2.57 -0.198 0.43927E+04 16 albite -0.38 -1.88 -1.50 -0.115 0.25539E+04 19 spessartine 24.46 20.59 -3.87 -0.193 0.66042E+04 20 analcite 3.32 1.55 -1.77 -0.197 0.30287E+04 21 andalusite 5.00 2.09 -2.91 -0.291 0.49631E+04 22 andradite 39.01 35.13 -3.88 -0.202 0.66231E+04 23 grossular 32.73 28.09 -4.65 -0.232 0.79317E+04 26 annite 20.12 16.03 -4.10 -0.228 0.69975E+04 27 phlogopite 27.06 22.71 -4.35 -0.242 0.74308E+04 29 anorthite 12.71 9.62 -3.09 -0.238 0.52833E+04 35 aragonite 0.97 -2.77 -3.74 -1.246 0.63843E+04 36 brucite 12.57 8.55 -4.02 -0.804 0.68600E+04 37 calcite 0.81 -2.77 -3.58 -1.195 0.61201E+04 38 carnegieite-low 9.02 4.98 -4.05 -0.578 0.69112E+04 40 carpholite-Mg 8.58 7.22 -1.36 -0.091 0.23289E+04 41 carpholite-Fe 6.71 4.99 -1.72 -0.115 0.29431E+04 42 celadonite 5.34 2.18 -3.16 -0.186 0.53928E+04 43 celadonite-Fe 3.88 -0.05 -3.92 -0.231 0.66974E+04 50 chloritoid-Mg 13.20 10.65 -2.55 -0.170 0.43574E+04 51 chloritoid-Fe 9.17 8.42 -0.76 -0.050 0.12926E+04 52 chloritoid-Mn 11.40 10.54 -0.86 -0.057 0.14620E+04 54 coesite -2.38 -3.43 -1.05 -0.351 0.17955E+04 59 corundum 8.38 5.52 -2.86 -0.260 0.48845E+04 61 cristobalite -2.56 -3.43 -0.87 -0.289 0.14809E+04 63 cymrite-K 1.69 -2.94 -4.63 -0.385 0.78978E+04 65 diaspore 2.87 2.76 -0.11 -0.019 0.19202E+03 67 diopside 16.18 12.64 -3.54 -0.354 0.60391E+04 68 hedenbergite 14.21 10.42 -3.79 -0.379 0.64763E+04 75 epidote 24.67 23.42 -1.25 -0.061 0.21335E+04 76 clinozoisite 22.81 19.90 -2.91 -0.132 0.49645E+04 77 epidote-Fe 29.84 26.94 -2.90 -0.151 0.49492E+04 78 fayalite 14.05 9.22 -4.83 -0.690 0.82468E+04 83 gibbsite 4.08 2.76 -1.32 -0.188 0.22506E+04 87 greenalite 16.14 12.11 -4.03 -0.336 0.68802E+04 91 heulandite -5.83 -7.52 -1.69 -0.077 0.28938E+04 95 jadeite 4.22 1.55 -2.67 -0.267 0.45542E+04 97 kalsilite 7.58 3.92 -3.67 -0.524 0.62642E+04 99 kyanite 4.88 2.09 -2.78 -0.278 0.47490E+04 101 laumontite 2.88 2.76 -0.12 -0.008 0.20932E+03 103 leucite 4.12 0.49 -3.63 -0.363 0.62003E+04 105 lizardite 23.24 18.80 -4.45 -0.371 0.75921E+04 107 magnetite 20.09 18.89 -1.20 -0.098 0.20480E+04 113 margarite 17.32 15.14 -2.19 -0.087 0.37309E+04 116 microcline -2.49 -2.94 -0.45 -0.035 0.77443E+03 121 paragonite 4.24 3.64 -0.60 -0.035 0.10186E+04 122 nepheline 8.34 4.98 -3.36 -0.481 0.57436E+04 136 prehnite 19.37 17.14 -2.23 -0.131 0.38155E+04 137 prehnite-Fe 22.50 20.66 -1.84 -0.111 0.31396E+04 138 pumpellyite-Fe 46.27 43.36 -2.91 -0.065 0.49719E+04 139 pumpellyite-Mg 48.99 45.59 -3.41 -0.076 0.58193E+04 145 pyroxmangite 7.40 5.02 -2.38 -0.475 0.40575E+04 146 pyrophyllite -6.18 -8.19 -2.01 -0.126 0.34358E+04 147 quartz -2.99 -3.43 -0.44 -0.146 0.74820E+03 151 rhodochrosite -0.98 -5.27 -4.30 -1.432 0.73338E+04 152 rhodonite 7.45 5.02 -2.42 -0.485 0.41378E+04 153 sanidine -1.28 -2.94 -1.66 -0.128 0.28422E+04 155 siderite -2.61 -7.40 -4.79 -1.597 0.81813E+04 156 sillimanite 5.26 2.09 -3.17 -0.317 0.54070E+04 164 stilpnomelane-Fe 13.02 12.00 -1.02 -0.030 0.17345E+04 165 stilpnomelane-Mg 27.44 23.15 -4.29 -0.128 0.73329E+04 167 sudoite-Fe 18.30 13.41 -4.89 -0.158 0.83505E+04 168 sudoite 21.08 17.86 -3.21 -0.104 0.54869E+04 171 talc 16.49 11.94 -4.55 -0.268 0.77670E+04 174 tephroite 18.09 13.47 -4.61 -0.659 0.78774E+04 177 topaz-H 4.62 2.09 -2.52 -0.229 0.43090E+04 178 tridymite -2.63 -3.43 -0.80 -0.267 0.13682E+04 187 wairakite 3.95 2.76 -1.19 -0.070 0.20313E+04 188 walstromite 11.51 7.52 -3.99 -0.798 0.68094E+04 189 wollastonite 10.46 7.52 -2.94 -0.588 0.50199E+04 190 pseudo-wollastonite 11.00 7.52 -3.48 -0.696 0.59397E+04 191 zoisite 22.85 19.90 -2.95 -0.134 0.50385E+04 192 akaganeite 7.75 6.28 -1.47 -0.318 0.25125E+04 193 beidellite-Ca -1.65 -4.34 -2.69 -0.167 0.45991E+04 194 beidellite-H -2.33 -6.15 -3.82 -0.244 0.65216E+04 195 beidellite-K -1.52 -4.63 -3.11 -0.191 0.53163E+04 196 beidellite-Mg -1.79 -4.73 -2.95 -0.182 0.50285E+04 197 beidellite-Na -1.34 -4.28 -2.94 -0.180 0.50227E+04 199 chalcedony -2.80 -3.43 -0.63 -0.208 0.10675E+04 201 montmorillonite-Ca -2.29 -4.47 -2.18 -0.135 0.37225E+04 202 montmorillonite-K -2.24 -4.77 -2.53 -0.155 0.43178E+04 203 montmorillonite-Mg -2.48 -4.87 -2.39 -0.148 0.40751E+04 204 montmorillonite-Na -2.04 -4.42 -2.38 -0.146 0.40599E+04 205 nontronite-Ca 3.21 2.70 -0.51 -0.033 0.87076E+03 206 nontronite-H 2.53 0.90 -1.63 -0.110 0.27912E+04 207 nontronite-K 3.34 2.41 -0.93 -0.060 0.15893E+04 208 nontronite-Mg 3.07 2.31 -0.77 -0.050 0.13074E+04 209 nontronite-Na 3.52 2.76 -0.76 -0.049 0.12974E+04 224 tobermorite 9.82 5.69 -4.13 -1.127 0.70524E+04 233 boehmite 4.41 2.76 -1.65 -0.274 0.28089E+04 235 ferrous-oxide 9.81 6.32 -3.49 -0.872 0.59588E+04 240 silica-amorphous -2.09 -3.43 -1.34 -0.445 0.22817E+04 242 an20ab80 2.02 0.42 -1.60 -0.123 0.27289E+04 243 an25ab75 2.65 0.99 -1.65 -0.127 0.28197E+04 244 an30ab70 3.28 1.57 -1.71 -0.132 0.29200E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 0.0200000 g Current total amount of reactant added: 0.4790000 g New total amount of reactant added: 0.4990000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.5880E-14 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 6 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 0.4990000 Water: Moles liquid = 0.5550E+02 kg liquid = 0.9999E+00 Moles total = 0.5550E+02 kg total = 0.9999E+00 Activity = 1.0000 Stoichiometric ionic strength = .6572920E-03 Osmotic coef. = 0.9849 True ionic strength = .8746906E-03 Chg. balance for total moles = -.5880E-14 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.16703E-08 -8.7772 0.15784E-08 -8.8018 0.94498E+00 -0.0246 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13796E-03 -3.8603 0.13032E-03 -3.8850 0.94463E+00 -0.0247 4 SO4-- 0.25484E-04 -4.5937 0.21426E-04 -4.6691 0.84077E+00 -0.0753 5 HCO3- 0.12268E-04 -4.9112 0.11589E-04 -4.9359 0.94471E+00 -0.0247 6 HS- 0.72999E-13 -13.1367 0.68958E-13 -13.1614 0.94463E+00 -0.0247 7 Al+++ 0.32813E-23 -23.4840 0.22694E-23 -23.6441 0.69161E+00 -0.1601 8 H4SiO4 0.37357E-03 -3.4276 0.37357E-03 -3.4276 0.10000E+01 0.0000 9 Ca++ 0.26351E-06 -6.5792 0.22145E-06 -6.6547 0.84039E+00 -0.0755 10 Mg++ 0.10544E-08 -8.9770 0.88583E-09 -9.0527 0.84015E+00 -0.0756 11 Fe++ 0.62205E-11 -11.2062 0.52265E-11 -11.2818 0.84021E+00 -0.0756 12 K+ 0.63753E-04 -4.1955 0.60229E-04 -4.2202 0.94473E+00 -0.0247 13 Na+ 0.78364E-03 -3.1059 0.74024E-03 -3.1306 0.94462E+00 -0.0247 14 Mn++ 0.83562E-09 -9.0780 0.70213E-09 -9.1536 0.84025E+00 -0.0756 15 HPO4-- 0.23969E-06 -6.6204 0.20152E-06 -6.6957 0.84077E+00 -0.0753 16 HSiO3- 0.23395E-03 -3.6309 0.22099E-03 -3.6556 0.94463E+00 -0.0247 17 Ca(HSiO3)+ 0.11797E-08 -8.9282 0.11145E-08 -8.9529 0.94474E+00 -0.0247 18 Mg(HSiO3)+ 0.58729E-11 -11.2311 0.55483E-11 -11.2558 0.94474E+00 -0.0247 19 NaHSiO3,aq 0.26458E-05 -5.5774 0.26458E-05 -5.5774 0.10000E+01 0.0000 20 AlO+ 0.13117E-12 -12.8822 0.12392E-12 -12.9069 0.94474E+00 -0.0247 21 AlOH+2 0.11590E-17 -17.9359 0.97395E-18 -18.0115 0.84030E+00 -0.0756 22 HAlO2,aq 0.15635E-07 -7.8059 0.15635E-07 -7.8059 0.10000E+01 0.0000 23 AlO2- 0.23214E-04 -4.6342 0.21926E-04 -4.6590 0.94452E+00 -0.0248 24 CH4,aq 0.36238E-19 -19.4408 0.36231E-19 -19.4409 0.99980E+00 -0.0001 29 CO,aq 0.44710E-18 -18.3496 0.44710E-18 -18.3496 0.10000E+01 0.0000 30 CO2,aq 0.39095E-07 -7.4079 0.39087E-07 -7.4080 0.99980E+00 -0.0001 31 CO3-2 0.76289E-06 -6.1175 0.64132E-06 -6.1929 0.84065E+00 -0.0754 32 CaCO3,aq 0.17808E-08 -8.7494 0.17808E-08 -8.7494 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.69344E-10 -10.1590 0.65512E-10 -10.1837 0.94474E+00 -0.0247 34 CaCl+ 0.49435E-10 -10.3060 0.46703E-10 -10.3307 0.94474E+00 -0.0247 35 CaCl2,aq 0.14460E-14 -14.8398 0.14460E-14 -14.8398 0.10000E+01 0.0000 36 CaOH+ 0.10584E-07 -7.9753 0.99992E-08 -8.0000 0.94474E+00 -0.0247 37 CaSO4,aq 0.15067E-08 -8.8220 0.15067E-08 -8.8220 0.10000E+01 0.0000 38 HCl,aq 0.37693E-13 -13.4237 0.37693E-13 -13.4237 0.10000E+01 0.0000 43 FeCl+ 0.11411E-14 -14.9427 0.10781E-14 -14.9674 0.94474E+00 -0.0247 46 FeO,aq 0.81533E-10 -10.0887 0.81533E-10 -10.0887 0.10000E+01 0.0000 47 FeOH+ 0.11409E-09 -9.9428 0.10778E-09 -9.9674 0.94474E+00 -0.0247 48 HFeO2- 0.57215E-09 -9.2425 0.54047E-09 -9.2672 0.94463E+00 -0.0247 49 FeO+ 0.12753E-13 -13.8944 0.12048E-13 -13.9191 0.94474E+00 -0.0247 51 FeO2- 0.10475E-08 -8.9798 0.98950E-09 -9.0046 0.94463E+00 -0.0247 52 HFeO2,aq 0.19864E-09 -9.7019 0.19864E-09 -9.7019 0.10000E+01 0.0000 53 H2,aq 0.45543E-09 -9.3416 0.45534E-09 -9.3417 0.99980E+00 -0.0001 54 KCl,aq 0.14225E-09 -9.8469 0.14225E-09 -9.8469 0.10000E+01 0.0000 55 KHSO4,aq 0.57592E-17 -17.2396 0.57592E-17 -17.2396 0.10000E+01 0.0000 56 KOH,aq 0.16296E-07 -7.7879 0.16296E-07 -7.7879 0.10000E+01 0.0000 57 KSO4- 0.21199E-07 -7.6737 0.20025E-07 -7.6984 0.94463E+00 -0.0247 58 MgCO3,aq 0.17855E-11 -11.7482 0.17855E-11 -11.7482 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.28343E-12 -12.5476 0.26777E-12 -12.5722 0.94474E+00 -0.0247 60 MgCl+ 0.17922E-12 -12.7466 0.16932E-12 -12.7713 0.94474E+00 -0.0247 61 MgOH+ 0.23427E-09 -9.6303 0.22133E-09 -9.6550 0.94474E+00 -0.0247 63 MnO,aq 0.29186E-09 -9.5348 0.29186E-09 -9.5348 0.10000E+01 0.0000 64 MnOH+ 0.14238E-08 -8.8465 0.13451E-08 -8.8712 0.94474E+00 -0.0247 65 MnO2-2 0.46246E-14 -14.3349 0.38877E-14 -14.4103 0.84065E+00 -0.0754 66 HMnO2- 0.14232E-11 -11.8467 0.13444E-11 -11.8715 0.94463E+00 -0.0247 69 MnCl+ 0.59641E-12 -12.2245 0.56345E-12 -12.2491 0.94474E+00 -0.0247 70 MnSO4,aq 0.43431E-11 -11.3622 0.43431E-11 -11.3622 0.10000E+01 0.0000 71 NaCl,aq 0.31969E-07 -7.4953 0.31969E-07 -7.4953 0.10000E+01 0.0000 72 NaOH,aq 0.20149E-06 -6.6957 0.20149E-06 -6.6957 0.10000E+01 0.0000 74 OH- 0.38755E-03 -3.4117 0.36605E-03 -3.4365 0.94452E+00 -0.0248 79 HPO3-2 0.34016E-18 -18.4683 0.28596E-18 -18.5437 0.84065E+00 -0.0754 82 H3PO4,aq 0.35115E-14 -14.4545 0.35115E-14 -14.4545 0.10000E+01 0.0000 83 H2PO4- 0.62115E-08 -8.2068 0.58679E-08 -8.2315 0.94468E+00 -0.0247 84 PO4-3 0.15016E-09 -9.8235 0.10417E-09 -9.9823 0.69373E+00 -0.1588 87 H2P2O7-2 0.32115E-17 -17.4933 0.26998E-17 -17.5687 0.84065E+00 -0.0754 88 HP2O7-3 0.49381E-15 -15.3064 0.34154E-15 -15.4666 0.69163E+00 -0.1601 89 P2O7-4 0.98030E-16 -16.0086 0.51692E-16 -16.2866 0.52731E+00 -0.2779 90 H2S,aq 0.33646E-15 -15.4731 0.33640E-15 -15.4732 0.99980E+00 -0.0001 97 SO3-2 0.15068E-14 -14.8220 0.12678E-14 -14.8969 0.84142E+00 -0.0750 98 HSO3- 0.13264E-15 -15.8773 0.12530E-15 -15.9021 0.94463E+00 -0.0247 99 HSO4- 0.34497E-10 -10.4622 0.32593E-10 -10.4869 0.94479E+00 -0.0247 Charge balance for all species = -.5758E-14 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.1670318E-08 -.7180016E-03 -.7236384E+00 0.0000 2 H2O 0.1000000E+01 0.5550845E+02 0.9999127E+06 0.0000 3 Cl- 0.1379561E-03 0.1379883E-03 0.4891666E+01 4.9168 4 SO4-- 0.2548434E-04 0.2550712E-04 0.2450038E+01 12.9345 5 HCO3- 0.1226751E-04 0.1307134E-04 0.7975058E+00 3.8658 6 HS- 0.7299930E-13 -.4183839E-10 -.1383557E-05 -4.3596 7 Al+++ 0.3281294E-23 0.2322994E-04 0.6267232E+00 2.7612 8 H4SiO4 0.3735728E-03 0.6101683E-03 0.5864137E+02 -3.4276 9 Ca++ 0.2635146E-06 0.2786848E-06 0.1116814E-01 10.9488 10 Mg++ 0.1054368E-08 0.1296760E-08 0.3152403E-04 8.5509 11 Fe++ 0.6220486E-11 0.2020159E-08 0.1128098E-03 6.3218 12 K+ 0.6375288E-04 0.6379052E-04 0.2494116E+01 4.5816 13 Na+ 0.7836388E-03 0.7865181E-03 0.1808029E+02 5.6712 14 Mn++ 0.8356229E-09 0.2557651E-08 0.1404998E-03 8.4500 15 HPO4-- 0.2396880E-06 0.2460496E-06 0.2361350E-01 10.9079 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.8249659E-02 -.7179281E-03 -.7531731E-02 0.0000000E+00 2 H2O 0.5550200E+02 0.5550276E+02 -.7683493E-03 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.3933346E-04 0.2550451E-04 0.1382895E-04 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.1382899E-04 -.4183410E-10 -.1382895E-04 0.0000000E+00 7 Al+++ 0.1627110E-02 0.2322757E-04 0.1603882E-02 0.0000000E+00 8 H4SiO4 0.5195979E-02 0.6101058E-03 0.4585873E-02 0.0000000E+00 9 Ca++ 0.5883922E-03 0.2786562E-06 0.5881136E-03 0.0000000E+00 10 Mg++ 0.3960317E-03 0.1296627E-08 0.3960304E-03 0.0000000E+00 11 Fe++ 0.3557913E-03 0.2019952E-08 0.3557893E-03 0.0000000E+00 12 K+ 0.1059448E-03 0.6378399E-04 0.4216081E-04 0.0000000E+00 13 Na+ 0.7864376E-03 0.7864376E-03 0.0000000E+00 0.0000000E+00 14 Mn++ 0.8651959E-05 0.2557389E-08 0.8649402E-05 0.0000000E+00 15 HPO4-- 0.2952871E-05 0.2460244E-06 0.2706846E-05 0.0000000E+00 Chg. balance for solid moles: -.1135E-17 Mass of aqueous solution: 0.999986E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 0.4990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) apatite-OH 0.9023E-06 -6.045 0.4532E-03 -3.344 0.8734E-01 0.1440E-03 clinochlore 0.7921E-04 -4.101 0.4403E-01 -1.356 8.484 0.1675E-01 daphnite 0.4903E-04 -4.310 0.3498E-01 -1.456 6.742 0.1060E-01 chlorite-Mn 0.1730E-05 -5.762 0.1226E-02 -2.911 0.2363 0.3908E-03 hematite 0.5532E-04 -4.257 0.8834E-02 -2.054 1.702 0.1674E-02 kaolinite 0.2513E-04 -4.600 0.6488E-02 -2.188 1.250 0.2496E-02 lawsonite 0.1320E-04 -4.880 0.4147E-02 -2.382 0.7992 0.1337E-02 muscovite 0.4216E-04 -4.375 0.1679E-01 -1.775 3.236 0.5938E-02 stilbite 0.5704E-03 -3.244 0.4020 -0.396 77.46 0.1875 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.6094E+00 0.6094E+00 1.0000 -0.215 daphnite 0.3773E+00 0.3773E+00 1.0000 -0.423 chlorite-Mn 0.1331E-01 0.1331E-01 1.0000 -1.876 hematite 0.1000E+01 0.1000E+01 1.0000 0.000 kaolinite 0.1000E+01 0.1000E+01 1.0000 0.000 lawsonite 0.1000E+01 0.1000E+01 1.0000 0.000 muscovite 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 0.518927 g Volume = 0.226817 cm3 Porosity: 81.0923% V(tot) - V(min): 0.97278E+00 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.4990000 g log = -0.3019 Original solution: 1000.0103000 g Original solution / Rock added: 2004.03 (Water/Rock Ratio), log = 3.3019 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0203 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.1000E+01 0.9860 0.1006E+01 0.1020E+01 CO2,gas 0.4070E-05 1.0071 0.4182E-05 0.4152E-05 CH4,gas 0.5162E-16 1.0125 0.5333E-16 0.5267E-16 H2,gas 0.5856E-06 1.0005 0.5978E-06 0.5975E-06 H2S,gas 0.9099E-14 0.9960 0.9247E-14 0.9284E-14 S2,gas 0.8803E-35 1.0000 0.8982E-35 0.8982E-35 CO,gas 0.6530E-15 1.0000 0.6663E-15 0.6663E-15 SO3,gas 0.1978E-37 1.0000 0.2018E-37 0.2018E-37 SO2,gas 0.4601E-21 1.0000 0.4694E-21 0.4694E-21 HCl,gas 0.6519E-16 1.0000 0.6651E-16 0.6651E-16 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 32 apatite-OH -18.15 -18.15 0.00 0.000 0.60662E-11 46 clinochlore 39.07 39.07 0.00 0.000 0.00000E+00 47 daphnite 28.97 28.97 0.00 0.000 0.36397E-10 48 chlorite-Mn 46.87 46.87 0.00 0.000 0.12132E-10 90 hematite 12.57 12.57 0.00 0.000 -0.30331E-11 98 kaolinite -1.33 -1.33 0.00 0.000 -0.64453E-11 102 lawsonite 9.62 9.62 0.00 0.000 0.00000E+00 120 muscovite 2.58 2.58 0.00 0.000 0.60662E-11 163 stilbite -7.52 -7.52 0.00 0.000 -0.90992E-11 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -13.74 -7.08 -2.359 0.12085E+05 -5.379 3 CH4,gas 4.54 -13.43 -17.97 -4.493 0.30687E+05 -16.273 4 H2,gas 8.00 0.08 -7.92 -4.527 0.13527E+05 -6.223 5 H2S,gas -6.23 -21.96 -15.73 -7.866 0.26864E+05 -14.034 6 S2,gas -7.34 -44.08 -36.75 -5.653 0.62742E+05 -35.047 7 CO,gas 3.21 -13.66 -16.88 -5.192 0.28814E+05 -15.176 8 SO3,gas 17.12 -22.27 -39.39 -9.848 0.67264E+05 -37.695 9 SO2,gas 0.83 -22.20 -23.03 -6.141 0.39319E+05 -21.328 10 HCl,gas 5.19 -12.69 -17.88 -8.938 0.30523E+05 -16.177 11 acmite 7.71 5.10 -2.61 -0.271 0.44577E+04 15 albite-high 0.69 -1.85 -2.54 -0.196 0.43430E+04 16 albite -0.38 -1.85 -1.47 -0.113 0.25042E+04 19 spessartine 24.46 20.59 -3.87 -0.193 0.66042E+04 20 analcite 3.32 1.58 -1.74 -0.194 0.29791E+04 21 andalusite 5.00 2.09 -2.91 -0.291 0.49631E+04 22 andradite 39.01 35.13 -3.88 -0.202 0.66231E+04 23 grossular 32.73 28.09 -4.65 -0.232 0.79317E+04 26 annite 20.12 16.03 -4.10 -0.228 0.69975E+04 27 phlogopite 27.06 22.71 -4.35 -0.242 0.74308E+04 29 anorthite 12.71 9.62 -3.09 -0.238 0.52833E+04 35 aragonite 0.97 -2.79 -3.76 -1.252 0.64122E+04 36 brucite 12.57 8.55 -4.02 -0.804 0.68600E+04 37 calcite 0.81 -2.79 -3.60 -1.200 0.61480E+04 38 carnegieite-low 9.02 5.00 -4.02 -0.574 0.68615E+04 40 carpholite-Mg 8.58 7.22 -1.36 -0.091 0.23289E+04 41 carpholite-Fe 6.71 4.99 -1.72 -0.115 0.29431E+04 42 celadonite 5.34 2.18 -3.16 -0.186 0.53928E+04 43 celadonite-Fe 3.88 -0.05 -3.92 -0.231 0.66974E+04 50 chloritoid-Mg 13.20 10.65 -2.55 -0.170 0.43574E+04 51 chloritoid-Fe 9.17 8.42 -0.76 -0.050 0.12926E+04 52 chloritoid-Mn 11.40 10.54 -0.86 -0.057 0.14620E+04 54 coesite -2.38 -3.43 -1.05 -0.351 0.17955E+04 59 corundum 8.38 5.52 -2.86 -0.260 0.48845E+04 61 cristobalite -2.56 -3.43 -0.87 -0.289 0.14809E+04 63 cymrite-K 1.69 -2.94 -4.63 -0.385 0.78978E+04 65 diaspore 2.87 2.76 -0.11 -0.019 0.19202E+03 67 diopside 16.18 12.64 -3.54 -0.354 0.60391E+04 68 hedenbergite 14.21 10.42 -3.79 -0.379 0.64763E+04 75 epidote 24.67 23.42 -1.25 -0.061 0.21335E+04 76 clinozoisite 22.81 19.90 -2.91 -0.132 0.49645E+04 77 epidote-Fe 29.84 26.94 -2.90 -0.151 0.49492E+04 78 fayalite 14.05 9.22 -4.83 -0.690 0.82468E+04 83 gibbsite 4.08 2.76 -1.32 -0.188 0.22506E+04 87 greenalite 16.14 12.11 -4.03 -0.336 0.68802E+04 91 heulandite -5.83 -7.52 -1.69 -0.077 0.28938E+04 95 jadeite 4.22 1.58 -2.64 -0.264 0.45045E+04 97 kalsilite 7.58 3.92 -3.67 -0.524 0.62642E+04 99 kyanite 4.88 2.09 -2.78 -0.278 0.47490E+04 101 laumontite 2.88 2.76 -0.12 -0.008 0.20932E+03 103 leucite 4.12 0.49 -3.63 -0.363 0.62003E+04 105 lizardite 23.24 18.80 -4.45 -0.371 0.75921E+04 107 magnetite 20.09 18.89 -1.20 -0.098 0.20480E+04 113 margarite 17.32 15.14 -2.19 -0.087 0.37309E+04 116 microcline -2.49 -2.94 -0.45 -0.035 0.77443E+03 121 paragonite 4.24 3.67 -0.57 -0.033 0.96888E+03 122 nepheline 8.34 5.00 -3.33 -0.476 0.56939E+04 136 prehnite 19.37 17.14 -2.23 -0.131 0.38155E+04 137 prehnite-Fe 22.50 20.66 -1.84 -0.111 0.31396E+04 138 pumpellyite-Fe 46.27 43.36 -2.91 -0.065 0.49719E+04 139 pumpellyite-Mg 48.99 45.59 -3.41 -0.076 0.58193E+04 145 pyroxmangite 7.40 5.02 -2.38 -0.475 0.40575E+04 146 pyrophyllite -6.18 -8.19 -2.01 -0.126 0.34358E+04 147 quartz -2.99 -3.43 -0.44 -0.146 0.74820E+03 151 rhodochrosite -0.98 -5.29 -4.31 -1.437 0.73616E+04 152 rhodonite 7.45 5.02 -2.42 -0.485 0.41378E+04 153 sanidine -1.28 -2.94 -1.66 -0.128 0.28422E+04 155 siderite -2.61 -7.42 -4.81 -1.603 0.82092E+04 156 sillimanite 5.26 2.09 -3.17 -0.317 0.54070E+04 164 stilpnomelane-Fe 13.02 12.00 -1.02 -0.030 0.17345E+04 165 stilpnomelane-Mg 27.44 23.15 -4.29 -0.128 0.73329E+04 167 sudoite-Fe 18.30 13.41 -4.89 -0.158 0.83505E+04 168 sudoite 21.08 17.86 -3.21 -0.104 0.54869E+04 171 talc 16.49 11.94 -4.55 -0.268 0.77670E+04 174 tephroite 18.09 13.47 -4.61 -0.659 0.78774E+04 177 topaz-H 4.62 2.09 -2.52 -0.229 0.43090E+04 178 tridymite -2.63 -3.43 -0.80 -0.267 0.13682E+04 187 wairakite 3.95 2.76 -1.19 -0.070 0.20313E+04 188 walstromite 11.51 7.52 -3.99 -0.798 0.68094E+04 189 wollastonite 10.46 7.52 -2.94 -0.588 0.50199E+04 190 pseudo-wollastonite 11.00 7.52 -3.48 -0.696 0.59397E+04 191 zoisite 22.85 19.90 -2.95 -0.134 0.50385E+04 192 akaganeite 7.75 6.28 -1.47 -0.318 0.25125E+04 193 beidellite-Ca -1.65 -4.34 -2.69 -0.167 0.45991E+04 194 beidellite-H -2.33 -6.15 -3.82 -0.244 0.65216E+04 195 beidellite-K -1.52 -4.63 -3.11 -0.191 0.53163E+04 196 beidellite-Mg -1.79 -4.73 -2.95 -0.182 0.50285E+04 197 beidellite-Na -1.34 -4.27 -2.93 -0.180 0.50063E+04 199 chalcedony -2.80 -3.43 -0.63 -0.208 0.10675E+04 201 montmorillonite-Ca -2.29 -4.47 -2.18 -0.135 0.37225E+04 202 montmorillonite-K -2.24 -4.77 -2.53 -0.155 0.43178E+04 203 montmorillonite-Mg -2.48 -4.87 -2.39 -0.148 0.40751E+04 204 montmorillonite-Na -2.04 -4.41 -2.37 -0.145 0.40436E+04 205 nontronite-Ca 3.21 2.70 -0.51 -0.033 0.87076E+03 206 nontronite-H 2.53 0.90 -1.63 -0.110 0.27912E+04 207 nontronite-K 3.34 2.41 -0.93 -0.060 0.15893E+04 208 nontronite-Mg 3.07 2.31 -0.77 -0.050 0.13074E+04 209 nontronite-Na 3.52 2.77 -0.75 -0.048 0.12810E+04 224 tobermorite 9.82 5.69 -4.13 -1.127 0.70524E+04 233 boehmite 4.41 2.76 -1.65 -0.274 0.28089E+04 235 ferrous-oxide 9.81 6.32 -3.49 -0.872 0.59588E+04 240 silica-amorphous -2.09 -3.43 -1.34 -0.445 0.22817E+04 242 an20ab80 2.02 0.44 -1.57 -0.121 0.26892E+04 243 an25ab75 2.65 1.02 -1.63 -0.125 0.27824E+04 244 an30ab70 3.28 1.59 -1.69 -0.130 0.28852E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 0.0200000 g Current total amount of reactant added: 0.4990000 g New total amount of reactant added: 0.5190000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.5878E-14 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 6 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 0.5190000 Water: Moles liquid = 0.5550E+02 kg liquid = 0.9999E+00 Moles total = 0.5550E+02 kg total = 0.9999E+00 Activity = 1.0000 Stoichiometric ionic strength = .6724726E-03 Osmotic coef. = 0.9848 True ionic strength = .8974924E-03 Chg. balance for total moles = -.5878E-14 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.16150E-08 -8.7918 0.15255E-08 -8.8166 0.94453E+00 -0.0248 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13796E-03 -3.8603 0.13025E-03 -3.8852 0.94417E+00 -0.0250 4 SO4-- 0.25485E-04 -4.5937 0.21386E-04 -4.6699 0.83915E+00 -0.0762 5 HCO3- 0.12243E-04 -4.9121 0.11560E-04 -4.9370 0.94425E+00 -0.0249 6 HS- 0.70451E-13 -13.1521 0.66518E-13 -13.1771 0.94417E+00 -0.0249 7 Al+++ 0.29748E-23 -23.5265 0.20485E-23 -23.6886 0.68861E+00 -0.1620 8 H4SiO4 0.37357E-03 -3.4276 0.37357E-03 -3.4276 0.10000E+01 0.0000 9 Ca++ 0.24660E-06 -6.6080 0.20684E-06 -6.6844 0.83876E+00 -0.0764 10 Mg++ 0.98671E-09 -9.0058 0.82737E-09 -9.0823 0.83852E+00 -0.0765 11 Fe++ 0.58213E-11 -11.2350 0.48816E-11 -11.3114 0.83858E+00 -0.0765 12 K+ 0.61643E-04 -4.2101 0.58208E-04 -4.2350 0.94427E+00 -0.0249 13 Na+ 0.80856E-03 -3.0923 0.76341E-03 -3.1172 0.94416E+00 -0.0250 14 Mn++ 0.78202E-09 -9.1068 0.65582E-09 -9.1832 0.83862E+00 -0.0764 15 HPO4-- 0.25712E-06 -6.5899 0.21576E-06 -6.6660 0.83916E+00 -0.0762 16 HSiO3- 0.24219E-03 -3.6158 0.22867E-03 -3.6408 0.94417E+00 -0.0250 17 Ca(HSiO3)+ 0.11407E-08 -8.9428 0.10771E-08 -8.9677 0.94428E+00 -0.0249 18 Mg(HSiO3)+ 0.56786E-11 -11.2458 0.53622E-11 -11.2707 0.94428E+00 -0.0249 19 NaHSiO3,aq 0.28234E-05 -5.5492 0.28234E-05 -5.5492 0.10000E+01 0.0000 20 AlO+ 0.12683E-12 -12.8968 0.11976E-12 -12.9217 0.94428E+00 -0.0249 21 AlOH+2 0.10847E-17 -17.9647 0.90968E-18 -18.0411 0.83867E+00 -0.0764 22 HAlO2,aq 0.15635E-07 -7.8059 0.15635E-07 -7.8059 0.10000E+01 0.0000 23 AlO2- 0.24032E-04 -4.6192 0.22688E-04 -4.6442 0.94406E+00 -0.0250 24 CH4,aq 0.34935E-19 -19.4567 0.34928E-19 -19.4568 0.99979E+00 -0.0001 29 CO,aq 0.43102E-18 -18.3655 0.43102E-18 -18.3655 0.10000E+01 0.0000 30 CO2,aq 0.37690E-07 -7.4238 0.37682E-07 -7.4239 0.99979E+00 -0.0001 31 CO3-2 0.78893E-06 -6.1030 0.66194E-06 -6.1792 0.83903E+00 -0.0762 32 CaCO3,aq 0.17168E-08 -8.7653 0.17168E-08 -8.7653 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.64639E-10 -10.1895 0.61037E-10 -10.2144 0.94428E+00 -0.0249 34 CaCl+ 0.46173E-10 -10.3356 0.43600E-10 -10.3605 0.94428E+00 -0.0249 35 CaCl2,aq 0.13492E-14 -14.8699 0.13492E-14 -14.8699 0.10000E+01 0.0000 36 CaOH+ 0.10234E-07 -7.9900 0.96637E-08 -8.0149 0.94428E+00 -0.0249 37 CaSO4,aq 0.14047E-08 -8.8524 0.14047E-08 -8.8524 0.10000E+01 0.0000 38 HCl,aq 0.36410E-13 -13.4388 0.36410E-13 -13.4388 0.10000E+01 0.0000 43 FeCl+ 0.10658E-14 -14.9723 0.10064E-14 -14.9972 0.94428E+00 -0.0249 46 FeO,aq 0.81533E-10 -10.0887 0.81533E-10 -10.0887 0.10000E+01 0.0000 47 FeOH+ 0.11031E-09 -9.9574 0.10417E-09 -9.9823 0.94428E+00 -0.0249 48 HFeO2- 0.59231E-09 -9.2275 0.55924E-09 -9.2524 0.94417E+00 -0.0250 49 FeO+ 0.12331E-13 -13.9090 0.11644E-13 -13.9339 0.94428E+00 -0.0249 51 FeO2- 0.10844E-08 -8.9648 0.10239E-08 -8.9898 0.94417E+00 -0.0250 52 HFeO2,aq 0.19864E-09 -9.7019 0.19864E-09 -9.7019 0.10000E+01 0.0000 53 H2,aq 0.45544E-09 -9.3416 0.45534E-09 -9.3417 0.99979E+00 -0.0001 54 KCl,aq 0.13741E-09 -9.8620 0.13741E-09 -9.8620 0.10000E+01 0.0000 55 KHSO4,aq 0.53690E-17 -17.2701 0.53690E-17 -17.2701 0.10000E+01 0.0000 56 KOH,aq 0.16296E-07 -7.7879 0.16296E-07 -7.7879 0.10000E+01 0.0000 57 KSO4- 0.20459E-07 -7.6891 0.19317E-07 -7.7141 0.94417E+00 -0.0250 58 MgCO3,aq 0.17213E-11 -11.7641 0.17213E-11 -11.7641 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.26420E-12 -12.5781 0.24948E-12 -12.6030 0.94428E+00 -0.0249 60 MgCl+ 0.16740E-12 -12.7763 0.15807E-12 -12.8012 0.94428E+00 -0.0249 61 MgOH+ 0.22652E-09 -9.6449 0.21390E-09 -9.6698 0.94428E+00 -0.0249 63 MnO,aq 0.29186E-09 -9.5348 0.29186E-09 -9.5348 0.10000E+01 0.0000 64 MnOH+ 0.13767E-08 -8.8612 0.13000E-08 -8.8861 0.94428E+00 -0.0249 65 MnO2-2 0.49610E-14 -14.3044 0.41625E-14 -14.3806 0.83903E+00 -0.0762 66 HMnO2- 0.14734E-11 -11.8317 0.13911E-11 -11.8566 0.94417E+00 -0.0250 69 MnCl+ 0.55706E-12 -12.2541 0.52602E-12 -12.2790 0.94428E+00 -0.0249 70 MnSO4,aq 0.40490E-11 -11.3927 0.40490E-11 -11.3927 0.10000E+01 0.0000 71 NaCl,aq 0.32953E-07 -7.4821 0.32953E-07 -7.4821 0.10000E+01 0.0000 72 NaOH,aq 0.21502E-06 -6.6675 0.21502E-06 -6.6675 0.10000E+01 0.0000 74 OH- 0.40120E-03 -3.3966 0.37876E-03 -3.4216 0.94406E+00 -0.0250 79 HPO3-2 0.36490E-18 -18.4378 0.30616E-18 -18.5140 0.83903E+00 -0.0762 82 H3PO4,aq 0.35115E-14 -14.4545 0.35115E-14 -14.4545 0.10000E+01 0.0000 83 H2PO4- 0.64303E-08 -8.1918 0.60716E-08 -8.2167 0.94422E+00 -0.0249 84 PO4-3 0.16706E-09 -9.7771 0.11540E-09 -9.9378 0.69077E+00 -0.1607 87 H2P2O7-2 0.34451E-17 -17.4628 0.28905E-17 -17.5390 0.83903E+00 -0.0762 88 HP2O7-3 0.54944E-15 -15.2601 0.37836E-15 -15.4221 0.68863E+00 -0.1620 89 P2O7-4 0.11324E-15 -15.9460 0.59254E-16 -16.2273 0.52327E+00 -0.2813 90 H2S,aq 0.31367E-15 -15.5035 0.31360E-15 -15.5036 0.99979E+00 -0.0001 97 SO3-2 0.15068E-14 -14.8219 0.12654E-14 -14.8978 0.83981E+00 -0.0758 98 HSO3- 0.12801E-15 -15.8928 0.12086E-15 -15.9177 0.94417E+00 -0.0250 99 HSO4- 0.33293E-10 -10.4777 0.31440E-10 -10.5025 0.94434E+00 -0.0249 Charge balance for all species = -.5764E-14 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.1615038E-08 -.7433839E-03 -.7492189E+00 0.0000 2 H2O 0.1000000E+01 0.5550845E+02 0.9999114E+06 0.0000 3 Cl- 0.1379557E-03 0.1379888E-03 0.4891677E+01 4.9314 4 SO4-- 0.2548527E-04 0.2550722E-04 0.2450044E+01 12.9633 5 HCO3- 0.1224298E-04 0.1307139E-04 0.7975076E+00 3.8796 6 HS- 0.7045071E-13 -.4645271E-10 -.1536146E-05 -4.3605 7 Al+++ 0.2974841E-23 0.2404773E-04 0.6487853E+00 2.7612 8 H4SiO4 0.3735728E-03 0.6185865E-03 0.5945034E+02 -3.4276 9 Ca++ 0.2466029E-06 0.2612098E-06 0.1046782E-01 10.9488 10 Mg++ 0.9867077E-09 0.1221059E-08 0.2968370E-04 8.5509 11 Fe++ 0.5821301E-11 0.2073036E-08 0.1157624E-03 6.3218 12 K+ 0.6164337E-04 0.6168026E-04 0.2411604E+01 4.5816 13 Na+ 0.8085572E-03 0.8116285E-03 0.1865750E+02 5.6994 14 Mn++ 0.7820153E-09 0.2456685E-08 0.1349532E-03 8.4500 15 HPO4-- 0.2571157E-06 0.2637131E-06 0.2530864E-01 10.9672 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.8580829E-02 -.7433050E-03 -.7837524E-02 0.0000000E+00 2 H2O 0.5550174E+02 0.5550257E+02 -.8225535E-03 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.3988773E-04 0.2550452E-04 0.1438321E-04 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.1438326E-04 -.4644778E-10 -.1438321E-04 0.0000000E+00 7 Al+++ 0.1692325E-02 0.2404518E-04 0.1668280E-02 0.0000000E+00 8 H4SiO4 0.5404234E-02 0.6185209E-03 0.4785713E-02 0.0000000E+00 9 Ca++ 0.6113951E-03 0.2611821E-06 0.6111339E-03 0.0000000E+00 10 Mg++ 0.4119048E-03 0.1220929E-08 0.4119035E-03 0.0000000E+00 11 Fe++ 0.3700515E-03 0.2072816E-08 0.3700494E-03 0.0000000E+00 12 K+ 0.1101911E-03 0.6167372E-04 0.4851736E-04 0.0000000E+00 13 Na+ 0.8115424E-03 0.8115424E-03 0.0000000E+00 0.0000000E+00 14 Mn++ 0.8998731E-05 0.2456424E-08 0.8996275E-05 0.0000000E+00 15 HPO4-- 0.3071222E-05 0.2636851E-06 0.2807537E-05 0.0000000E+00 Chg. balance for solid moles: 0.1320E-17 Mass of aqueous solution: 0.999984E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 0.5190000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) apatite-OH 0.9358E-06 -6.029 0.4701E-03 -3.328 0.8689E-01 0.1494E-03 clinochlore 0.8238E-04 -4.084 0.4579E-01 -1.339 8.464 0.1742E-01 daphnite 0.5100E-04 -4.292 0.3639E-01 -1.439 6.726 0.1103E-01 chlorite-Mn 0.1799E-05 -5.745 0.1276E-02 -2.894 0.2358 0.4065E-03 hematite 0.5753E-04 -4.240 0.9188E-02 -2.037 1.698 0.1741E-02 kaolinite 0.1973E-04 -4.705 0.5094E-02 -2.293 0.9416 0.1960E-02 lawsonite 0.1000E-04 -5.000 0.3143E-02 -2.503 0.5810 0.1014E-02 muscovite 0.4852E-04 -4.314 0.1932E-01 -1.714 3.572 0.6833E-02 stilbite 0.5965E-03 -3.224 0.4203 -0.376 77.69 0.1961 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.6094E+00 0.6094E+00 1.0000 -0.215 daphnite 0.3773E+00 0.3773E+00 1.0000 -0.423 chlorite-Mn 0.1331E-01 0.1331E-01 1.0000 -1.876 hematite 0.1000E+01 0.1000E+01 1.0000 0.000 kaolinite 0.1000E+01 0.1000E+01 1.0000 0.000 lawsonite 0.1000E+01 0.1000E+01 1.0000 0.000 muscovite 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 0.541004 g Volume = 0.236598 cm3 Porosity: 80.4076% V(tot) - V(min): 0.97100E+00 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.5190000 g log = -0.2848 Original solution: 1000.0103000 g Original solution / Rock added: 1926.80 (Water/Rock Ratio), log = 3.2848 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0203 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.1000E+01 0.9860 0.1006E+01 0.1020E+01 CO2,gas 0.3923E-05 1.0071 0.4032E-05 0.4003E-05 CH4,gas 0.4977E-16 1.0125 0.5141E-16 0.5078E-16 H2,gas 0.5856E-06 1.0005 0.5978E-06 0.5975E-06 H2S,gas 0.8483E-14 0.9960 0.8621E-14 0.8655E-14 S2,gas 0.7651E-35 1.0000 0.7806E-35 0.7806E-35 CO,gas 0.6295E-15 1.0000 0.6423E-15 0.6423E-15 SO3,gas 0.1844E-37 1.0000 0.1882E-37 0.1882E-37 SO2,gas 0.4289E-21 1.0000 0.4376E-21 0.4376E-21 HCl,gas 0.6297E-16 1.0000 0.6425E-16 0.6425E-16 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 32 apatite-OH -18.15 -18.15 0.00 0.000 0.60662E-11 46 clinochlore 39.07 39.07 0.00 0.000 0.12132E-10 47 daphnite 28.97 28.97 0.00 0.000 -0.12132E-10 48 chlorite-Mn 46.87 46.87 0.00 0.000 0.12132E-10 90 hematite 12.57 12.57 0.00 0.000 -0.30331E-11 98 kaolinite -1.33 -1.33 0.00 0.000 -0.64453E-11 102 lawsonite 9.62 9.62 0.00 0.000 0.00000E+00 120 muscovite 2.58 2.58 0.00 0.000 -0.42463E-10 163 stilbite -7.52 -7.52 0.00 0.000 -0.90992E-11 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -13.75 -7.09 -2.364 0.12112E+05 -5.395 3 CH4,gas 4.54 -13.44 -17.99 -4.497 0.30714E+05 -16.289 4 H2,gas 8.00 0.08 -7.92 -4.527 0.13527E+05 -6.223 5 H2S,gas -6.23 -21.99 -15.76 -7.882 0.26916E+05 -14.064 6 S2,gas -7.34 -44.14 -36.81 -5.663 0.62846E+05 -35.108 7 CO,gas 3.21 -13.68 -16.89 -5.197 0.28841E+05 -15.192 8 SO3,gas 17.12 -22.30 -39.42 -9.856 0.67316E+05 -37.725 9 SO2,gas 0.83 -22.23 -23.06 -6.149 0.39371E+05 -21.359 10 HCl,gas 5.19 -12.70 -17.89 -8.946 0.30549E+05 -16.192 11 acmite 7.71 5.13 -2.58 -0.268 0.44096E+04 15 albite-high 0.69 -1.82 -2.52 -0.193 0.42949E+04 16 albite -0.38 -1.82 -1.44 -0.111 0.24560E+04 19 spessartine 24.46 20.59 -3.87 -0.193 0.66041E+04 20 analcite 3.32 1.61 -1.72 -0.191 0.29309E+04 21 andalusite 5.00 2.09 -2.91 -0.291 0.49631E+04 22 andradite 39.01 35.13 -3.88 -0.202 0.66231E+04 23 grossular 32.73 28.09 -4.65 -0.232 0.79317E+04 26 annite 20.12 16.03 -4.10 -0.228 0.69975E+04 27 phlogopite 27.06 22.71 -4.35 -0.242 0.74308E+04 29 anorthite 12.71 9.62 -3.09 -0.238 0.52833E+04 35 aragonite 0.97 -2.80 -3.77 -1.257 0.64394E+04 36 brucite 12.57 8.55 -4.02 -0.804 0.68600E+04 37 calcite 0.81 -2.80 -3.62 -1.206 0.61752E+04 38 carnegieite-low 9.02 5.03 -3.99 -0.570 0.68134E+04 40 carpholite-Mg 8.58 7.22 -1.36 -0.091 0.23289E+04 41 carpholite-Fe 6.71 4.99 -1.72 -0.115 0.29431E+04 42 celadonite 5.34 2.18 -3.16 -0.186 0.53928E+04 43 celadonite-Fe 3.88 -0.05 -3.92 -0.231 0.66974E+04 50 chloritoid-Mg 13.20 10.65 -2.55 -0.170 0.43574E+04 51 chloritoid-Fe 9.17 8.42 -0.76 -0.050 0.12926E+04 52 chloritoid-Mn 11.40 10.54 -0.86 -0.057 0.14620E+04 54 coesite -2.38 -3.43 -1.05 -0.351 0.17955E+04 59 corundum 8.38 5.52 -2.86 -0.260 0.48845E+04 61 cristobalite -2.56 -3.43 -0.87 -0.289 0.14809E+04 63 cymrite-K 1.69 -2.94 -4.63 -0.385 0.78978E+04 65 diaspore 2.87 2.76 -0.11 -0.019 0.19202E+03 67 diopside 16.18 12.64 -3.54 -0.354 0.60391E+04 68 hedenbergite 14.21 10.42 -3.79 -0.379 0.64763E+04 75 epidote 24.67 23.42 -1.25 -0.061 0.21335E+04 76 clinozoisite 22.81 19.90 -2.91 -0.132 0.49645E+04 77 epidote-Fe 29.84 26.94 -2.90 -0.151 0.49492E+04 78 fayalite 14.05 9.22 -4.83 -0.690 0.82468E+04 83 gibbsite 4.08 2.76 -1.32 -0.188 0.22506E+04 87 greenalite 16.14 12.11 -4.03 -0.336 0.68802E+04 91 heulandite -5.83 -7.52 -1.69 -0.077 0.28938E+04 95 jadeite 4.22 1.61 -2.61 -0.261 0.44564E+04 97 kalsilite 7.58 3.92 -3.67 -0.524 0.62642E+04 99 kyanite 4.88 2.09 -2.78 -0.278 0.47490E+04 101 laumontite 2.88 2.76 -0.12 -0.008 0.20932E+03 103 leucite 4.12 0.49 -3.63 -0.363 0.62003E+04 105 lizardite 23.24 18.80 -4.45 -0.371 0.75921E+04 107 magnetite 20.09 18.89 -1.20 -0.098 0.20480E+04 113 margarite 17.32 15.14 -2.19 -0.087 0.37309E+04 116 microcline -2.49 -2.94 -0.45 -0.035 0.77443E+03 121 paragonite 4.24 3.70 -0.54 -0.032 0.92071E+03 122 nepheline 8.34 5.03 -3.31 -0.472 0.56457E+04 136 prehnite 19.37 17.14 -2.23 -0.131 0.38155E+04 137 prehnite-Fe 22.50 20.66 -1.84 -0.111 0.31396E+04 138 pumpellyite-Fe 46.27 43.36 -2.91 -0.065 0.49719E+04 139 pumpellyite-Mg 48.99 45.59 -3.41 -0.076 0.58193E+04 145 pyroxmangite 7.40 5.02 -2.38 -0.475 0.40575E+04 146 pyrophyllite -6.18 -8.19 -2.01 -0.126 0.34358E+04 147 quartz -2.99 -3.43 -0.44 -0.146 0.74820E+03 151 rhodochrosite -0.98 -5.30 -4.33 -1.442 0.73888E+04 152 rhodonite 7.45 5.02 -2.42 -0.485 0.41378E+04 153 sanidine -1.28 -2.94 -1.66 -0.128 0.28422E+04 155 siderite -2.61 -7.43 -4.82 -1.608 0.82364E+04 156 sillimanite 5.26 2.09 -3.17 -0.317 0.54070E+04 164 stilpnomelane-Fe 13.02 12.00 -1.02 -0.030 0.17346E+04 165 stilpnomelane-Mg 27.44 23.15 -4.29 -0.128 0.73329E+04 167 sudoite-Fe 18.30 13.41 -4.89 -0.158 0.83505E+04 168 sudoite 21.08 17.86 -3.21 -0.104 0.54869E+04 171 talc 16.49 11.94 -4.55 -0.268 0.77670E+04 174 tephroite 18.09 13.47 -4.61 -0.659 0.78773E+04 177 topaz-H 4.62 2.09 -2.52 -0.229 0.43090E+04 178 tridymite -2.63 -3.43 -0.80 -0.267 0.13682E+04 187 wairakite 3.95 2.76 -1.19 -0.070 0.20313E+04 188 walstromite 11.51 7.52 -3.99 -0.798 0.68094E+04 189 wollastonite 10.46 7.52 -2.94 -0.588 0.50199E+04 190 pseudo-wollastonite 11.00 7.52 -3.48 -0.696 0.59397E+04 191 zoisite 22.85 19.90 -2.95 -0.134 0.50385E+04 192 akaganeite 7.75 6.28 -1.47 -0.318 0.25125E+04 193 beidellite-Ca -1.65 -4.34 -2.69 -0.167 0.45991E+04 194 beidellite-H -2.33 -6.15 -3.82 -0.244 0.65216E+04 195 beidellite-K -1.52 -4.63 -3.11 -0.191 0.53163E+04 196 beidellite-Mg -1.79 -4.73 -2.95 -0.182 0.50285E+04 197 beidellite-Na -1.34 -4.26 -2.92 -0.179 0.49904E+04 199 chalcedony -2.80 -3.43 -0.63 -0.208 0.10675E+04 201 montmorillonite-Ca -2.29 -4.47 -2.18 -0.135 0.37225E+04 202 montmorillonite-K -2.24 -4.77 -2.53 -0.155 0.43178E+04 203 montmorillonite-Mg -2.48 -4.87 -2.39 -0.148 0.40751E+04 204 montmorillonite-Na -2.04 -4.40 -2.36 -0.144 0.40277E+04 205 nontronite-Ca 3.21 2.70 -0.51 -0.033 0.87076E+03 206 nontronite-H 2.53 0.90 -1.63 -0.110 0.27912E+04 207 nontronite-K 3.34 2.41 -0.93 -0.060 0.15893E+04 208 nontronite-Mg 3.07 2.31 -0.77 -0.050 0.13074E+04 209 nontronite-Na 3.52 2.78 -0.74 -0.048 0.12651E+04 224 tobermorite 9.82 5.69 -4.13 -1.127 0.70524E+04 233 boehmite 4.41 2.76 -1.65 -0.274 0.28089E+04 235 ferrous-oxide 9.81 6.32 -3.49 -0.872 0.59588E+04 240 silica-amorphous -2.09 -3.43 -1.34 -0.445 0.22817E+04 242 an20ab80 2.02 0.47 -1.55 -0.119 0.26507E+04 243 an25ab75 2.65 1.04 -1.61 -0.124 0.27463E+04 244 an30ab70 3.28 1.61 -1.67 -0.128 0.28515E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 0.0200000 g Current total amount of reactant added: 0.5190000 g New total amount of reactant added: 0.5390000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.5877E-14 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 6 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 0.5390000 Water: Moles liquid = 0.5550E+02 kg liquid = 0.9999E+00 Moles total = 0.5550E+02 kg total = 0.9999E+00 Activity = 1.0000 Stoichiometric ionic strength = .6877417E-03 Osmotic coef. = 0.9846 True ionic strength = .9204209E-03 Chg. balance for total moles = -.5877E-14 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.15631E-08 -8.8060 0.14757E-08 -8.8310 0.94408E+00 -0.0250 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13796E-03 -3.8603 0.13019E-03 -3.8854 0.94371E+00 -0.0252 4 SO4-- 0.25486E-04 -4.5937 0.21346E-04 -4.6707 0.83755E+00 -0.0770 5 HCO3- 0.12218E-04 -4.9130 0.11532E-04 -4.9381 0.94380E+00 -0.0251 6 HS- 0.68058E-13 -13.1671 0.64228E-13 -13.1923 0.94372E+00 -0.0252 7 Al+++ 0.27048E-23 -23.5679 0.18545E-23 -23.7318 0.68564E+00 -0.1639 8 H4SiO4 0.37357E-03 -3.4276 0.37357E-03 -3.4276 0.10000E+01 0.0000 9 Ca++ 0.23122E-06 -6.6360 0.19357E-06 -6.7132 0.83716E+00 -0.0772 10 Mg++ 0.92518E-09 -9.0338 0.77429E-09 -9.1111 0.83691E+00 -0.0773 11 Fe++ 0.54583E-11 -11.2629 0.45684E-11 -11.3402 0.83697E+00 -0.0773 12 K+ 0.59662E-04 -4.2243 0.56310E-04 -4.2494 0.94382E+00 -0.0251 13 Na+ 0.83347E-03 -3.0791 0.78655E-03 -3.1043 0.94370E+00 -0.0252 14 Mn++ 0.73326E-09 -9.1347 0.61375E-09 -9.2120 0.83701E+00 -0.0773 15 HPO4-- 0.27527E-06 -6.5602 0.23055E-06 -6.6372 0.83756E+00 -0.0770 16 HSiO3- 0.25047E-03 -3.6012 0.23638E-03 -3.6264 0.94371E+00 -0.0252 17 Ca(HSiO3)+ 0.11040E-08 -8.9570 0.10420E-08 -8.9821 0.94383E+00 -0.0251 18 Mg(HSiO3)+ 0.54960E-11 -11.2600 0.51873E-11 -11.2851 0.94383E+00 -0.0251 19 NaHSiO3,aq 0.30070E-05 -5.5219 0.30070E-05 -5.5219 0.10000E+01 0.0000 20 AlO+ 0.12275E-12 -12.9110 0.11585E-12 -12.9361 0.94383E+00 -0.0251 21 AlOH+2 0.10170E-17 -17.9927 0.85131E-18 -18.0699 0.83706E+00 -0.0772 22 HAlO2,aq 0.15635E-07 -7.8059 0.15635E-07 -7.8059 0.10000E+01 0.0000 23 AlO2- 0.24854E-04 -4.6046 0.23452E-04 -4.6298 0.94360E+00 -0.0252 24 CH4,aq 0.33712E-19 -19.4722 0.33705E-19 -19.4723 0.99979E+00 -0.0001 29 CO,aq 0.41593E-18 -18.3810 0.41593E-18 -18.3810 0.10000E+01 0.0000 30 CO2,aq 0.36370E-07 -7.4393 0.36362E-07 -7.4394 0.99979E+00 -0.0001 31 CO3-2 0.81505E-06 -6.0888 0.68255E-06 -6.1659 0.83743E+00 -0.0771 32 CaCO3,aq 0.16567E-08 -8.7808 0.16567E-08 -8.7808 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.60370E-10 -10.2192 0.56979E-10 -10.2443 0.94383E+00 -0.0251 34 CaCl+ 0.43210E-10 -10.3644 0.40783E-10 -10.3895 0.94383E+00 -0.0251 35 CaCl2,aq 0.12614E-14 -14.8991 0.12614E-14 -14.8991 0.10000E+01 0.0000 36 CaOH+ 0.99049E-08 -8.0042 0.93485E-08 -8.0293 0.94383E+00 -0.0251 37 CaSO4,aq 0.13121E-08 -8.8820 0.13121E-08 -8.8820 0.10000E+01 0.0000 38 HCl,aq 0.35205E-13 -13.4534 0.35205E-13 -13.4534 0.10000E+01 0.0000 43 FeCl+ 0.99743E-15 -15.0011 0.94141E-15 -15.0262 0.94383E+00 -0.0251 46 FeO,aq 0.81533E-10 -10.0887 0.81533E-10 -10.0887 0.10000E+01 0.0000 47 FeOH+ 0.10677E-09 -9.9716 0.10077E-09 -9.9967 0.94383E+00 -0.0251 48 HFeO2- 0.61257E-09 -9.2128 0.57809E-09 -9.2380 0.94371E+00 -0.0252 49 FeO+ 0.11934E-13 -13.9232 0.11264E-13 -13.9483 0.94383E+00 -0.0251 51 FeO2- 0.11215E-08 -8.9502 0.10584E-08 -8.9754 0.94371E+00 -0.0252 52 HFeO2,aq 0.19864E-09 -9.7019 0.19864E-09 -9.7019 0.10000E+01 0.0000 53 H2,aq 0.45544E-09 -9.3416 0.45534E-09 -9.3417 0.99979E+00 -0.0001 54 KCl,aq 0.13287E-09 -9.8766 0.13287E-09 -9.8766 0.10000E+01 0.0000 55 KHSO4,aq 0.50151E-17 -17.2997 0.50151E-17 -17.2997 0.10000E+01 0.0000 56 KOH,aq 0.16296E-07 -7.7879 0.16296E-07 -7.7879 0.10000E+01 0.0000 57 KSO4- 0.19764E-07 -7.7041 0.18652E-07 -7.7293 0.94371E+00 -0.0252 58 MgCO3,aq 0.16610E-11 -11.7796 0.16610E-11 -11.7796 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.24675E-12 -12.6077 0.23289E-12 -12.6329 0.94383E+00 -0.0251 60 MgCl+ 0.15665E-12 -12.8051 0.14785E-12 -12.8302 0.94383E+00 -0.0251 61 MgOH+ 0.21924E-09 -9.6591 0.20692E-09 -9.6842 0.94383E+00 -0.0251 63 MnO,aq 0.29187E-09 -9.5348 0.29187E-09 -9.5348 0.10000E+01 0.0000 64 MnOH+ 0.13325E-08 -8.8753 0.12576E-08 -8.9004 0.94383E+00 -0.0251 65 MnO2-2 0.53114E-14 -14.2748 0.44479E-14 -14.3518 0.83743E+00 -0.0771 66 HMnO2- 0.15238E-11 -11.8171 0.14380E-11 -11.8422 0.94371E+00 -0.0252 69 MnCl+ 0.52133E-12 -12.2829 0.49204E-12 -12.3080 0.94383E+00 -0.0251 70 MnSO4,aq 0.37822E-11 -11.4223 0.37822E-11 -11.4223 0.10000E+01 0.0000 71 NaCl,aq 0.33936E-07 -7.4693 0.33936E-07 -7.4693 0.10000E+01 0.0000 72 NaOH,aq 0.22900E-06 -6.6402 0.22900E-06 -6.6402 0.10000E+01 0.0000 74 OH- 0.41493E-03 -3.3820 0.39152E-03 -3.4072 0.94360E+00 -0.0252 79 HPO3-2 0.39066E-18 -18.4082 0.32715E-18 -18.4852 0.83743E+00 -0.0771 82 H3PO4,aq 0.35115E-14 -14.4545 0.35115E-14 -14.4545 0.10000E+01 0.0000 83 H2PO4- 0.66502E-08 -8.1772 0.62763E-08 -8.2023 0.94377E+00 -0.0251 84 PO4-3 0.18531E-09 -9.7321 0.12747E-09 -9.8946 0.68785E+00 -0.1625 87 H2P2O7-2 0.36883E-17 -17.4332 0.30887E-17 -17.5102 0.83743E+00 -0.0771 88 HP2O7-3 0.60953E-15 -15.2150 0.41793E-15 -15.3789 0.68566E+00 -0.1639 89 P2O7-4 0.13029E-15 -15.8851 0.67657E-16 -16.1697 0.51929E+00 -0.2846 90 H2S,aq 0.29300E-15 -15.5331 0.29293E-15 -15.5332 0.99979E+00 -0.0001 97 SO3-2 0.15068E-14 -14.8219 0.12631E-14 -14.8986 0.83823E+00 -0.0766 98 HSO3- 0.12366E-15 -15.9078 0.11670E-15 -15.9329 0.94371E+00 -0.0252 99 HSO4- 0.32162E-10 -10.4927 0.30357E-10 -10.5177 0.94389E+00 -0.0251 Charge balance for all species = -.5774E-14 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.1563107E-08 -.7689091E-03 -.7749434E+00 0.0000 2 H2O 0.1000000E+01 0.5550846E+02 0.9999101E+06 0.0000 3 Cl- 0.1379552E-03 0.1379893E-03 0.4891688E+01 4.9456 4 SO4-- 0.2548616E-04 0.2550732E-04 0.2450050E+01 12.9913 5 HCO3- 0.1221829E-04 0.1307143E-04 0.7975094E+00 3.8929 6 HS- 0.6805820E-13 -.5109185E-10 -.1689555E-05 -4.3613 7 Al+++ 0.2704821E-23 0.2486994E-04 0.6709670E+00 2.7612 8 H4SiO4 0.3735728E-03 0.6270555E-03 0.6026418E+02 -3.4276 9 Ca++ 0.2312239E-06 0.2453052E-06 0.9830440E-02 10.9488 10 Mg++ 0.9251796E-09 0.1151977E-08 0.2800430E-04 8.5509 11 Fe++ 0.5458292E-11 0.2126487E-08 0.1187470E-03 6.3218 12 K+ 0.5966163E-04 0.5969782E-04 0.2334091E+01 4.5816 13 Na+ 0.8334692E-03 0.8367391E-03 0.1923471E+02 5.7267 14 Mn++ 0.7332636E-09 0.2363453E-08 0.1298315E-03 8.4500 15 HPO4-- 0.2752683E-06 0.2821039E-06 0.2707357E-01 11.0248 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.8912000E-02 -.7688248E-03 -.8143175E-02 0.0000000E+00 2 H2O 0.5550149E+02 0.5550237E+02 -.8765225E-03 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.4044200E-04 0.2550452E-04 0.1493748E-04 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.1493753E-04 -.5108624E-10 -.1493748E-04 0.0000000E+00 7 Al+++ 0.1757540E-02 0.2486721E-04 0.1732673E-02 0.0000000E+00 8 H4SiO4 0.5612490E-02 0.6269867E-03 0.4985503E-02 0.0000000E+00 9 Ca++ 0.6343980E-03 0.2452782E-06 0.6341527E-03 0.0000000E+00 10 Mg++ 0.4277778E-03 0.1151851E-08 0.4277766E-03 0.0000000E+00 11 Fe++ 0.3843116E-03 0.2126253E-08 0.3843095E-03 0.0000000E+00 12 K+ 0.1144374E-03 0.5969127E-04 0.5474609E-04 0.0000000E+00 13 Na+ 0.8366473E-03 0.8366473E-03 0.0000000E+00 0.0000000E+00 14 Mn++ 0.9345503E-05 0.2363194E-08 0.9343140E-05 0.0000000E+00 15 HPO4-- 0.3189574E-05 0.2820729E-06 0.2907501E-05 0.0000000E+00 Chg. balance for solid moles: -.4083E-18 Mass of aqueous solution: 0.999982E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 0.5390000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) apatite-OH 0.9692E-06 -6.014 0.4868E-03 -3.313 0.8646E-01 0.1547E-03 clinochlore 0.8556E-04 -4.068 0.4755E-01 -1.323 8.445 0.1809E-01 daphnite 0.5296E-04 -4.276 0.3779E-01 -1.423 6.711 0.1145E-01 chlorite-Mn 0.1869E-05 -5.728 0.1325E-02 -2.878 0.2353 0.4222E-03 hematite 0.5975E-04 -4.224 0.9542E-02 -2.020 1.695 0.1809E-02 kaolinite 0.1452E-04 -4.838 0.3750E-02 -2.426 0.6659 0.1443E-02 lawsonite 0.6818E-05 -5.166 0.2142E-02 -2.669 0.3805 0.6909E-03 muscovite 0.5475E-04 -4.262 0.2181E-01 -1.661 3.873 0.7711E-02 stilbite 0.6225E-03 -3.206 0.4387 -0.358 77.91 0.2046 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.6094E+00 0.6094E+00 1.0000 -0.215 daphnite 0.3773E+00 0.3773E+00 1.0000 -0.423 chlorite-Mn 0.1331E-01 0.1331E-01 1.0000 -1.876 hematite 0.1000E+01 0.1000E+01 1.0000 0.000 kaolinite 0.1000E+01 0.1000E+01 1.0000 0.000 lawsonite 0.1000E+01 0.1000E+01 1.0000 0.000 muscovite 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 0.563075 g Volume = 0.246378 cm3 Porosity: 79.7320% V(tot) - V(min): 0.96922E+00 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.5390000 g log = -0.2684 Original solution: 1000.0103000 g Original solution / Rock added: 1855.31 (Water/Rock Ratio), log = 3.2684 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0203 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.1000E+01 0.9860 0.1006E+01 0.1020E+01 CO2,gas 0.3786E-05 1.0071 0.3890E-05 0.3863E-05 CH4,gas 0.4802E-16 1.0125 0.4961E-16 0.4900E-16 H2,gas 0.5856E-06 1.0005 0.5978E-06 0.5975E-06 H2S,gas 0.7924E-14 0.9960 0.8053E-14 0.8085E-14 S2,gas 0.6675E-35 1.0000 0.6811E-35 0.6811E-35 CO,gas 0.6075E-15 1.0000 0.6198E-15 0.6198E-15 SO3,gas 0.1723E-37 1.0000 0.1758E-37 0.1758E-37 SO2,gas 0.4006E-21 1.0000 0.4088E-21 0.4088E-21 HCl,gas 0.6088E-16 1.0000 0.6212E-16 0.6212E-16 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 32 apatite-OH -18.15 -18.15 0.00 0.000 0.00000E+00 46 clinochlore 39.07 39.07 0.00 0.000 -0.24265E-10 47 daphnite 28.97 28.97 0.00 0.000 -0.60662E-11 48 chlorite-Mn 46.87 46.87 0.00 0.000 0.00000E+00 90 hematite 12.57 12.57 0.00 0.000 0.30331E-11 98 kaolinite -1.33 -1.33 0.00 0.000 0.56870E-11 102 lawsonite 9.62 9.62 0.00 0.000 0.00000E+00 120 muscovite 2.58 2.58 0.00 0.000 0.30331E-10 163 stilbite -7.52 -7.52 0.00 0.000 -0.90992E-11 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -13.77 -7.11 -2.370 0.12138E+05 -5.410 3 CH4,gas 4.54 -13.46 -18.00 -4.501 0.30740E+05 -16.304 4 H2,gas 8.00 0.08 -7.92 -4.527 0.13527E+05 -6.223 5 H2S,gas -6.23 -22.02 -15.79 -7.897 0.26966E+05 -14.094 6 S2,gas -7.34 -44.20 -36.87 -5.672 0.62947E+05 -35.167 7 CO,gas 3.21 -13.69 -16.91 -5.202 0.28868E+05 -15.208 8 SO3,gas 17.12 -22.33 -39.45 -9.864 0.67367E+05 -37.755 9 SO2,gas 0.83 -22.26 -23.09 -6.157 0.39421E+05 -21.389 10 HCl,gas 5.19 -12.72 -17.91 -8.953 0.30574E+05 -16.207 11 acmite 7.71 5.15 -2.56 -0.265 0.43628E+04 15 albite-high 0.69 -1.79 -2.49 -0.191 0.42481E+04 16 albite -0.38 -1.79 -1.41 -0.109 0.24093E+04 19 spessartine 24.46 20.59 -3.87 -0.193 0.66041E+04 20 analcite 3.32 1.63 -1.69 -0.188 0.28842E+04 21 andalusite 5.00 2.09 -2.91 -0.291 0.49631E+04 22 andradite 39.01 35.13 -3.88 -0.202 0.66231E+04 23 grossular 32.73 28.09 -4.65 -0.232 0.79317E+04 26 annite 20.12 16.03 -4.10 -0.228 0.69975E+04 27 phlogopite 27.06 22.71 -4.35 -0.242 0.74308E+04 29 anorthite 12.71 9.62 -3.09 -0.238 0.52833E+04 35 aragonite 0.97 -2.82 -3.79 -1.262 0.64658E+04 36 brucite 12.57 8.55 -4.02 -0.804 0.68600E+04 37 calcite 0.81 -2.82 -3.63 -1.211 0.62016E+04 38 carnegieite-low 9.02 5.06 -3.96 -0.566 0.67666E+04 40 carpholite-Mg 8.58 7.22 -1.36 -0.091 0.23289E+04 41 carpholite-Fe 6.71 4.99 -1.72 -0.115 0.29431E+04 42 celadonite 5.34 2.18 -3.16 -0.186 0.53928E+04 43 celadonite-Fe 3.88 -0.05 -3.92 -0.231 0.66974E+04 50 chloritoid-Mg 13.20 10.65 -2.55 -0.170 0.43574E+04 51 chloritoid-Fe 9.17 8.42 -0.76 -0.050 0.12926E+04 52 chloritoid-Mn 11.40 10.54 -0.86 -0.057 0.14620E+04 54 coesite -2.38 -3.43 -1.05 -0.351 0.17955E+04 59 corundum 8.38 5.52 -2.86 -0.260 0.48845E+04 61 cristobalite -2.56 -3.43 -0.87 -0.289 0.14809E+04 63 cymrite-K 1.69 -2.94 -4.63 -0.385 0.78978E+04 65 diaspore 2.87 2.76 -0.11 -0.019 0.19202E+03 67 diopside 16.18 12.64 -3.54 -0.354 0.60391E+04 68 hedenbergite 14.21 10.42 -3.79 -0.379 0.64763E+04 75 epidote 24.67 23.42 -1.25 -0.061 0.21335E+04 76 clinozoisite 22.81 19.90 -2.91 -0.132 0.49645E+04 77 epidote-Fe 29.84 26.94 -2.90 -0.151 0.49492E+04 78 fayalite 14.05 9.22 -4.83 -0.690 0.82468E+04 83 gibbsite 4.08 2.76 -1.32 -0.188 0.22506E+04 87 greenalite 16.14 12.11 -4.03 -0.336 0.68802E+04 91 heulandite -5.83 -7.52 -1.69 -0.077 0.28938E+04 95 jadeite 4.22 1.63 -2.58 -0.258 0.44097E+04 97 kalsilite 7.58 3.92 -3.67 -0.524 0.62642E+04 99 kyanite 4.88 2.09 -2.78 -0.278 0.47490E+04 101 laumontite 2.88 2.76 -0.12 -0.008 0.20932E+03 103 leucite 4.12 0.49 -3.63 -0.363 0.62003E+04 105 lizardite 23.24 18.80 -4.45 -0.371 0.75921E+04 107 magnetite 20.09 18.89 -1.20 -0.098 0.20480E+04 113 margarite 17.32 15.14 -2.19 -0.087 0.37309E+04 116 microcline -2.49 -2.94 -0.45 -0.035 0.77443E+03 121 paragonite 4.24 3.73 -0.51 -0.030 0.87398E+03 122 nepheline 8.34 5.06 -3.28 -0.468 0.55990E+04 136 prehnite 19.37 17.14 -2.23 -0.131 0.38155E+04 137 prehnite-Fe 22.50 20.66 -1.84 -0.111 0.31396E+04 138 pumpellyite-Fe 46.27 43.36 -2.91 -0.065 0.49719E+04 139 pumpellyite-Mg 48.99 45.59 -3.41 -0.076 0.58193E+04 145 pyroxmangite 7.40 5.02 -2.38 -0.475 0.40575E+04 146 pyrophyllite -6.18 -8.19 -2.01 -0.126 0.34358E+04 147 quartz -2.99 -3.43 -0.44 -0.146 0.74820E+03 151 rhodochrosite -0.98 -5.32 -4.34 -1.448 0.74152E+04 152 rhodonite 7.45 5.02 -2.42 -0.485 0.41377E+04 153 sanidine -1.28 -2.94 -1.66 -0.128 0.28422E+04 155 siderite -2.61 -7.45 -4.84 -1.613 0.82628E+04 156 sillimanite 5.26 2.09 -3.17 -0.317 0.54070E+04 164 stilpnomelane-Fe 13.02 12.00 -1.02 -0.030 0.17346E+04 165 stilpnomelane-Mg 27.44 23.15 -4.29 -0.128 0.73329E+04 167 sudoite-Fe 18.30 13.41 -4.89 -0.158 0.83505E+04 168 sudoite 21.08 17.86 -3.21 -0.104 0.54869E+04 171 talc 16.49 11.94 -4.55 -0.268 0.77670E+04 174 tephroite 18.09 13.47 -4.61 -0.659 0.78773E+04 177 topaz-H 4.62 2.09 -2.52 -0.229 0.43090E+04 178 tridymite -2.63 -3.43 -0.80 -0.267 0.13682E+04 187 wairakite 3.95 2.76 -1.19 -0.070 0.20313E+04 188 walstromite 11.51 7.52 -3.99 -0.798 0.68094E+04 189 wollastonite 10.46 7.52 -2.94 -0.588 0.50199E+04 190 pseudo-wollastonite 11.00 7.52 -3.48 -0.696 0.59397E+04 191 zoisite 22.85 19.90 -2.95 -0.134 0.50385E+04 192 akaganeite 7.75 6.28 -1.47 -0.318 0.25125E+04 193 beidellite-Ca -1.65 -4.34 -2.69 -0.167 0.45991E+04 194 beidellite-H -2.33 -6.15 -3.82 -0.244 0.65216E+04 195 beidellite-K -1.52 -4.63 -3.11 -0.191 0.53163E+04 196 beidellite-Mg -1.79 -4.73 -2.95 -0.182 0.50285E+04 197 beidellite-Na -1.34 -4.26 -2.91 -0.178 0.49750E+04 199 chalcedony -2.80 -3.43 -0.63 -0.208 0.10675E+04 201 montmorillonite-Ca -2.29 -4.47 -2.18 -0.135 0.37225E+04 202 montmorillonite-K -2.24 -4.77 -2.53 -0.155 0.43178E+04 203 montmorillonite-Mg -2.48 -4.87 -2.39 -0.148 0.40751E+04 204 montmorillonite-Na -2.04 -4.39 -2.35 -0.144 0.40122E+04 205 nontronite-Ca 3.21 2.70 -0.51 -0.033 0.87076E+03 206 nontronite-H 2.53 0.90 -1.63 -0.110 0.27912E+04 207 nontronite-K 3.34 2.41 -0.93 -0.060 0.15893E+04 208 nontronite-Mg 3.07 2.31 -0.77 -0.050 0.13074E+04 209 nontronite-Na 3.52 2.79 -0.73 -0.047 0.12496E+04 224 tobermorite 9.82 5.69 -4.13 -1.127 0.70524E+04 233 boehmite 4.41 2.76 -1.65 -0.274 0.28089E+04 235 ferrous-oxide 9.81 6.32 -3.49 -0.872 0.59588E+04 240 silica-amorphous -2.09 -3.43 -1.34 -0.445 0.22817E+04 242 an20ab80 2.02 0.49 -1.53 -0.118 0.26133E+04 243 an25ab75 2.65 1.06 -1.59 -0.122 0.27112E+04 244 an30ab70 3.28 1.63 -1.65 -0.127 0.28188E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 0.0200000 g Current total amount of reactant added: 0.5390000 g New total amount of reactant added: 0.5590000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.5876E-14 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 6 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 0.5590000 Water: Moles liquid = 0.5550E+02 kg liquid = 0.9999E+00 Moles total = 0.5550E+02 kg total = 0.9999E+00 Activity = 1.0000 Stoichiometric ionic strength = .7030922E-03 Osmotic coef. = 0.9845 True ionic strength = .9434653E-03 Chg. balance for total moles = -.5876E-14 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.15143E-08 -8.8198 0.14289E-08 -8.8450 0.94364E+00 -0.0252 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13795E-03 -3.8603 0.13013E-03 -3.8856 0.94326E+00 -0.0254 4 SO4-- 0.25487E-04 -4.5937 0.21306E-04 -4.6715 0.83597E+00 -0.0778 5 HCO3- 0.12193E-04 -4.9139 0.11503E-04 -4.9392 0.94335E+00 -0.0253 6 HS- 0.65809E-13 -13.1817 0.62076E-13 -13.2071 0.94327E+00 -0.0254 7 Al+++ 0.24661E-23 -23.6080 0.16837E-23 -23.7737 0.68272E+00 -0.1658 8 H4SiO4 0.37357E-03 -3.4276 0.37357E-03 -3.4276 0.10000E+01 0.0000 9 Ca++ 0.21721E-06 -6.6631 0.18149E-06 -6.7411 0.83556E+00 -0.0780 10 Mg++ 0.86909E-09 -9.0609 0.72596E-09 -9.1391 0.83531E+00 -0.0782 11 Fe++ 0.51274E-11 -11.2901 0.42833E-11 -11.3682 0.83537E+00 -0.0781 12 K+ 0.57797E-04 -4.2381 0.54524E-04 -4.2634 0.94337E+00 -0.0253 13 Na+ 0.85837E-03 -3.0663 0.80966E-03 -3.0917 0.94325E+00 -0.0254 14 Mn++ 0.68882E-09 -9.1619 0.57545E-09 -9.2400 0.83542E+00 -0.0781 15 HPO4-- 0.29415E-06 -6.5314 0.24590E-06 -6.6092 0.83597E+00 -0.0778 16 HSiO3- 0.25880E-03 -3.5870 0.24412E-03 -3.6124 0.94326E+00 -0.0254 17 Ca(HSiO3)+ 0.10695E-08 -8.9708 0.10090E-08 -8.9961 0.94338E+00 -0.0253 18 Mg(HSiO3)+ 0.53243E-11 -11.2737 0.50228E-11 -11.2991 0.94338E+00 -0.0253 19 NaHSiO3,aq 0.31968E-05 -5.4953 0.31968E-05 -5.4953 0.10000E+01 0.0000 20 AlO+ 0.11891E-12 -12.9248 0.11218E-12 -12.9501 0.94338E+00 -0.0253 21 AlOH+2 0.95537E-18 -18.0198 0.79818E-18 -18.0979 0.83547E+00 -0.0781 22 HAlO2,aq 0.15635E-07 -7.8059 0.15635E-07 -7.8059 0.10000E+01 0.0000 23 AlO2- 0.25681E-04 -4.5904 0.24221E-04 -4.6158 0.94315E+00 -0.0254 24 CH4,aq 0.32561E-19 -19.4873 0.32554E-19 -19.4874 0.99978E+00 -0.0001 29 CO,aq 0.40173E-18 -18.3961 0.40173E-18 -18.3961 0.10000E+01 0.0000 30 CO2,aq 0.35128E-07 -7.4543 0.35121E-07 -7.4544 0.99978E+00 -0.0001 31 CO3-2 0.84123E-06 -6.0751 0.70314E-06 -6.1530 0.83585E+00 -0.0779 32 CaCO3,aq 0.16001E-08 -8.7959 0.16001E-08 -8.7959 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.56487E-10 -10.2481 0.53289E-10 -10.2734 0.94338E+00 -0.0253 34 CaCl+ 0.40513E-10 -10.3924 0.38219E-10 -10.4177 0.94338E+00 -0.0253 35 CaCl2,aq 0.11816E-14 -14.9275 0.11816E-14 -14.9275 0.10000E+01 0.0000 36 CaOH+ 0.95954E-08 -8.0179 0.90521E-08 -8.0433 0.94338E+00 -0.0253 37 CaSO4,aq 0.12279E-08 -8.9108 0.12279E-08 -8.9108 0.10000E+01 0.0000 38 HCl,aq 0.34073E-13 -13.4676 0.34073E-13 -13.4676 0.10000E+01 0.0000 43 FeCl+ 0.93517E-15 -15.0291 0.88222E-15 -15.0544 0.94338E+00 -0.0253 46 FeO,aq 0.81533E-10 -10.0887 0.81533E-10 -10.0887 0.10000E+01 0.0000 47 FeOH+ 0.10343E-09 -9.9854 0.97574E-10 -10.0107 0.94338E+00 -0.0253 48 HFeO2- 0.63293E-09 -9.1986 0.59702E-09 -9.2240 0.94326E+00 -0.0254 49 FeO+ 0.11561E-13 -13.9370 0.10907E-13 -13.9623 0.94338E+00 -0.0253 51 FeO2- 0.11588E-08 -8.9360 0.10930E-08 -8.9614 0.94326E+00 -0.0254 52 HFeO2,aq 0.19864E-09 -9.7019 0.19864E-09 -9.7019 0.10000E+01 0.0000 53 H2,aq 0.45544E-09 -9.3416 0.45534E-09 -9.3417 0.99978E+00 -0.0001 54 KCl,aq 0.12859E-09 -9.8908 0.12859E-09 -9.8908 0.10000E+01 0.0000 55 KHSO4,aq 0.46934E-17 -17.3285 0.46934E-17 -17.3285 0.10000E+01 0.0000 56 KOH,aq 0.16296E-07 -7.7879 0.16296E-07 -7.7879 0.10000E+01 0.0000 57 KSO4- 0.19111E-07 -7.7187 0.18027E-07 -7.7441 0.94326E+00 -0.0254 58 MgCO3,aq 0.16043E-11 -11.7947 0.16043E-11 -11.7947 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.23088E-12 -12.6366 0.21781E-12 -12.6619 0.94338E+00 -0.0253 60 MgCl+ 0.14688E-12 -12.8330 0.13856E-12 -12.8584 0.94338E+00 -0.0253 61 MgOH+ 0.21239E-09 -9.6729 0.20036E-09 -9.6982 0.94338E+00 -0.0253 63 MnO,aq 0.29187E-09 -9.5348 0.29187E-09 -9.5348 0.10000E+01 0.0000 64 MnOH+ 0.12909E-08 -8.8891 0.12178E-08 -8.9144 0.94338E+00 -0.0253 65 MnO2-2 0.56758E-14 -14.2460 0.47441E-14 -14.3238 0.83585E+00 -0.0779 66 HMnO2- 0.15745E-11 -11.8029 0.14852E-11 -11.8282 0.94326E+00 -0.0254 69 MnCl+ 0.48879E-12 -12.3109 0.46112E-12 -12.3362 0.94338E+00 -0.0253 70 MnSO4,aq 0.35396E-11 -11.4510 0.35396E-11 -11.4510 0.10000E+01 0.0000 71 NaCl,aq 0.34916E-07 -7.4570 0.34916E-07 -7.4570 0.10000E+01 0.0000 72 NaOH,aq 0.24345E-06 -6.6136 0.24345E-06 -6.6136 0.10000E+01 0.0000 74 OH- 0.42872E-03 -3.3678 0.40435E-03 -3.3932 0.94315E+00 -0.0254 79 HPO3-2 0.41746E-18 -18.3794 0.34893E-18 -18.4573 0.83585E+00 -0.0779 82 H3PO4,aq 0.35115E-14 -14.4545 0.35115E-14 -14.4545 0.10000E+01 0.0000 83 H2PO4- 0.68713E-08 -8.1630 0.64818E-08 -8.1883 0.94332E+00 -0.0253 84 PO4-3 0.20498E-09 -9.6883 0.14041E-09 -9.8526 0.68497E+00 -0.1643 87 H2P2O7-2 0.39413E-17 -17.4044 0.32943E-17 -17.4822 0.83585E+00 -0.0779 88 HP2O7-3 0.67427E-15 -15.1712 0.46035E-15 -15.3369 0.68274E+00 -0.1657 89 P2O7-4 0.14934E-15 -15.8258 0.76965E-16 -16.1137 0.51538E+00 -0.2879 90 H2S,aq 0.27420E-15 -15.5619 0.27414E-15 -15.5620 0.99978E+00 -0.0001 97 SO3-2 0.15068E-14 -14.8219 0.12607E-14 -14.8994 0.83666E+00 -0.0775 98 HSO3- 0.11958E-15 -15.9223 0.11279E-15 -15.9477 0.94326E+00 -0.0254 99 HSO4- 0.31099E-10 -10.5073 0.29340E-10 -10.5325 0.94344E+00 -0.0253 Charge balance for all species = -.5778E-14 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.1514251E-08 -.7945655E-03 -.8007999E+00 0.0000 2 H2O 0.1000000E+01 0.5550847E+02 0.9999088E+06 0.0000 3 Cl- 0.1379547E-03 0.1379898E-03 0.4891699E+01 4.9594 4 SO4-- 0.2548699E-04 0.2550742E-04 0.2450056E+01 13.0185 5 HCO3- 0.1219347E-04 0.1307148E-04 0.7975111E+00 3.9058 6 HS- 0.6580901E-13 -.5575365E-10 -.1843713E-05 -4.3621 7 Al+++ 0.2466116E-23 0.2569621E-04 0.6932579E+00 2.7612 8 H4SiO4 0.3735728E-03 0.6355714E-03 0.6108252E+02 -3.4276 9 Ca++ 0.2172055E-06 0.2307954E-06 0.9248959E-02 10.9488 10 Mg++ 0.8690947E-09 0.1088787E-08 0.2646813E-04 8.5509 11 Fe++ 0.5127399E-11 0.2180462E-08 0.1217609E-03 6.3218 12 K+ 0.5779728E-04 0.5783282E-04 0.2261169E+01 4.5816 13 Na+ 0.8583748E-03 0.8618499E-03 0.1981192E+02 5.7533 14 Mn++ 0.6888229E-09 0.2277177E-08 0.1250919E-03 8.4500 15 HPO4-- 0.2941482E-06 0.3012244E-06 0.2890853E-01 11.0807 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.9243170E-02 -.7944754E-03 -.8448695E-02 0.0000000E+00 2 H2O 0.5550124E+02 0.5550217E+02 -.9302751E-03 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.4099627E-04 0.2550453E-04 0.1549174E-04 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.1549180E-04 -.5574732E-10 -.1549174E-04 0.0000000E+00 7 Al+++ 0.1822755E-02 0.2569330E-04 0.1797061E-02 0.0000000E+00 8 H4SiO4 0.5820746E-02 0.6354993E-03 0.5185246E-02 0.0000000E+00 9 Ca++ 0.6574008E-03 0.2307692E-06 0.6571700E-03 0.0000000E+00 10 Mg++ 0.4436508E-03 0.1088664E-08 0.4436497E-03 0.0000000E+00 11 Fe++ 0.3985718E-03 0.2180215E-08 0.3985696E-03 0.0000000E+00 12 K+ 0.1186837E-03 0.5782626E-04 0.6085739E-04 0.0000000E+00 13 Na+ 0.8617522E-03 0.8617522E-03 0.0000000E+00 0.0000000E+00 14 Mn++ 0.9692275E-05 0.2276919E-08 0.9689998E-05 0.0000000E+00 15 HPO4-- 0.3307925E-05 0.3011903E-06 0.3006735E-05 0.0000000E+00 Chg. balance for solid moles: -.1191E-17 Mass of aqueous solution: 0.999980E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 0.5590000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) apatite-OH 0.1002E-05 -5.999 0.5034E-03 -3.298 0.8604E-01 0.1600E-03 clinochlore 0.8873E-04 -4.052 0.4932E-01 -1.307 8.429 0.1876E-01 daphnite 0.5493E-04 -4.260 0.3919E-01 -1.407 6.698 0.1188E-01 chlorite-Mn 0.1938E-05 -5.713 0.1374E-02 -2.862 0.2348 0.4379E-03 hematite 0.6197E-04 -4.208 0.9896E-02 -2.005 1.691 0.1876E-02 kaolinite 0.9491E-05 -5.023 0.2450E-02 -2.611 0.4187 0.9427E-03 lawsonite 0.3641E-05 -5.439 0.1144E-02 -2.942 0.1955 0.3689E-03 muscovite 0.6086E-04 -4.216 0.2424E-01 -1.615 4.143 0.8571E-02 stilbite 0.6485E-03 -3.188 0.4570 -0.340 78.10 0.2132 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.6094E+00 0.6094E+00 1.0000 -0.215 daphnite 0.3773E+00 0.3773E+00 1.0000 -0.423 chlorite-Mn 0.1331E-01 0.1331E-01 1.0000 -1.876 hematite 0.1000E+01 0.1000E+01 1.0000 0.000 kaolinite 0.1000E+01 0.1000E+01 1.0000 0.000 lawsonite 0.1000E+01 0.1000E+01 1.0000 0.000 muscovite 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 0.585141 g Volume = 0.256156 cm3 Porosity: 79.0654% V(tot) - V(min): 0.96744E+00 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.5590000 g log = -0.2526 Original solution: 1000.0103000 g Original solution / Rock added: 1788.93 (Water/Rock Ratio), log = 3.2526 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0203 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.1000E+01 0.9860 0.1006E+01 0.1020E+01 CO2,gas 0.3657E-05 1.0071 0.3758E-05 0.3731E-05 CH4,gas 0.4638E-16 1.0125 0.4792E-16 0.4732E-16 H2,gas 0.5856E-06 1.0005 0.5978E-06 0.5975E-06 H2S,gas 0.7415E-14 0.9960 0.7536E-14 0.7566E-14 S2,gas 0.5846E-35 1.0000 0.5965E-35 0.5965E-35 CO,gas 0.5867E-15 1.0000 0.5987E-15 0.5987E-15 SO3,gas 0.1612E-37 1.0000 0.1645E-37 0.1645E-37 SO2,gas 0.3749E-21 1.0000 0.3826E-21 0.3826E-21 HCl,gas 0.5893E-16 1.0000 0.6012E-16 0.6012E-16 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 32 apatite-OH -18.15 -18.15 0.00 0.000 0.00000E+00 46 clinochlore 39.07 39.07 0.00 0.000 -0.12132E-10 47 daphnite 28.97 28.97 0.00 0.000 -0.12132E-10 48 chlorite-Mn 46.87 46.87 0.00 0.000 0.00000E+00 90 hematite 12.57 12.57 0.00 0.000 0.90992E-11 98 kaolinite -1.33 -1.33 0.00 0.000 -0.64453E-11 102 lawsonite 9.62 9.62 0.00 0.000 -0.12132E-10 120 muscovite 2.58 2.58 0.00 0.000 -0.18198E-10 163 stilbite -7.52 -7.52 0.00 0.000 -0.33364E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -13.78 -7.12 -2.375 0.12164E+05 -5.425 3 CH4,gas 4.54 -13.47 -18.02 -4.505 0.30766E+05 -16.320 4 H2,gas 8.00 0.08 -7.92 -4.527 0.13527E+05 -6.223 5 H2S,gas -6.23 -22.05 -15.82 -7.911 0.27015E+05 -14.123 6 S2,gas -7.34 -44.26 -36.92 -5.681 0.63046E+05 -35.224 7 CO,gas 3.21 -13.71 -16.92 -5.207 0.28894E+05 -15.223 8 SO3,gas 17.12 -22.36 -39.48 -9.871 0.67416E+05 -37.784 9 SO2,gas 0.83 -22.28 -23.12 -6.164 0.39470E+05 -21.417 10 HCl,gas 5.19 -12.73 -17.92 -8.960 0.30598E+05 -16.221 11 acmite 7.71 5.18 -2.53 -0.263 0.43175E+04 15 albite-high 0.69 -1.77 -2.46 -0.189 0.42028E+04 16 albite -0.38 -1.77 -1.38 -0.106 0.23639E+04 19 spessartine 24.46 20.59 -3.87 -0.193 0.66040E+04 20 analcite 3.32 1.66 -1.66 -0.185 0.28388E+04 21 andalusite 5.00 2.09 -2.91 -0.291 0.49631E+04 22 andradite 39.01 35.13 -3.88 -0.202 0.66231E+04 23 grossular 32.73 28.09 -4.65 -0.232 0.79317E+04 26 annite 20.12 16.03 -4.10 -0.228 0.69975E+04 27 phlogopite 27.06 22.71 -4.35 -0.242 0.74308E+04 29 anorthite 12.71 9.62 -3.09 -0.238 0.52833E+04 35 aragonite 0.97 -2.84 -3.80 -1.267 0.64916E+04 36 brucite 12.57 8.55 -4.02 -0.804 0.68600E+04 37 calcite 0.81 -2.84 -3.65 -1.216 0.62274E+04 38 carnegieite-low 9.02 5.09 -3.94 -0.562 0.67213E+04 40 carpholite-Mg 8.58 7.22 -1.36 -0.091 0.23289E+04 41 carpholite-Fe 6.71 4.99 -1.72 -0.115 0.29431E+04 42 celadonite 5.34 2.18 -3.16 -0.186 0.53928E+04 43 celadonite-Fe 3.88 -0.05 -3.92 -0.231 0.66974E+04 50 chloritoid-Mg 13.20 10.65 -2.55 -0.170 0.43574E+04 51 chloritoid-Fe 9.17 8.42 -0.76 -0.050 0.12926E+04 52 chloritoid-Mn 11.40 10.54 -0.86 -0.057 0.14620E+04 54 coesite -2.38 -3.43 -1.05 -0.351 0.17955E+04 59 corundum 8.38 5.52 -2.86 -0.260 0.48845E+04 61 cristobalite -2.56 -3.43 -0.87 -0.289 0.14809E+04 63 cymrite-K 1.69 -2.94 -4.63 -0.385 0.78978E+04 65 diaspore 2.87 2.76 -0.11 -0.019 0.19202E+03 67 diopside 16.18 12.64 -3.54 -0.354 0.60391E+04 68 hedenbergite 14.21 10.42 -3.79 -0.379 0.64763E+04 75 epidote 24.67 23.42 -1.25 -0.061 0.21335E+04 76 clinozoisite 22.81 19.90 -2.91 -0.132 0.49645E+04 77 epidote-Fe 29.84 26.94 -2.90 -0.151 0.49492E+04 78 fayalite 14.05 9.22 -4.83 -0.690 0.82468E+04 83 gibbsite 4.08 2.76 -1.32 -0.188 0.22506E+04 87 greenalite 16.14 12.11 -4.03 -0.336 0.68802E+04 91 heulandite -5.83 -7.52 -1.69 -0.077 0.28938E+04 95 jadeite 4.22 1.66 -2.56 -0.256 0.43643E+04 97 kalsilite 7.58 3.92 -3.67 -0.524 0.62642E+04 99 kyanite 4.88 2.09 -2.78 -0.278 0.47490E+04 101 laumontite 2.88 2.76 -0.12 -0.008 0.20932E+03 103 leucite 4.12 0.49 -3.63 -0.363 0.62003E+04 105 lizardite 23.24 18.80 -4.45 -0.371 0.75921E+04 107 magnetite 20.09 18.89 -1.20 -0.098 0.20480E+04 113 margarite 17.32 15.14 -2.19 -0.087 0.37309E+04 116 microcline -2.49 -2.94 -0.45 -0.035 0.77443E+03 121 paragonite 4.24 3.75 -0.49 -0.029 0.82861E+03 122 nepheline 8.34 5.09 -3.25 -0.465 0.55536E+04 136 prehnite 19.37 17.14 -2.23 -0.131 0.38155E+04 137 prehnite-Fe 22.50 20.66 -1.84 -0.111 0.31396E+04 138 pumpellyite-Fe 46.27 43.36 -2.91 -0.065 0.49719E+04 139 pumpellyite-Mg 48.99 45.59 -3.41 -0.076 0.58193E+04 145 pyroxmangite 7.40 5.02 -2.38 -0.475 0.40575E+04 146 pyrophyllite -6.18 -8.19 -2.01 -0.126 0.34358E+04 147 quartz -2.99 -3.43 -0.44 -0.146 0.74820E+03 151 rhodochrosite -0.98 -5.33 -4.36 -1.453 0.74409E+04 152 rhodonite 7.45 5.02 -2.42 -0.485 0.41377E+04 153 sanidine -1.28 -2.94 -1.66 -0.128 0.28422E+04 155 siderite -2.61 -7.46 -4.85 -1.618 0.82886E+04 156 sillimanite 5.26 2.09 -3.17 -0.317 0.54070E+04 164 stilpnomelane-Fe 13.02 12.00 -1.02 -0.030 0.17346E+04 165 stilpnomelane-Mg 27.44 23.15 -4.29 -0.128 0.73329E+04 167 sudoite-Fe 18.30 13.41 -4.89 -0.158 0.83505E+04 168 sudoite 21.08 17.86 -3.21 -0.104 0.54869E+04 171 talc 16.49 11.94 -4.55 -0.268 0.77670E+04 174 tephroite 18.09 13.47 -4.61 -0.659 0.78773E+04 177 topaz-H 4.62 2.09 -2.52 -0.229 0.43090E+04 178 tridymite -2.63 -3.43 -0.80 -0.267 0.13682E+04 187 wairakite 3.95 2.76 -1.19 -0.070 0.20313E+04 188 walstromite 11.51 7.52 -3.99 -0.798 0.68094E+04 189 wollastonite 10.46 7.52 -2.94 -0.588 0.50199E+04 190 pseudo-wollastonite 11.00 7.52 -3.48 -0.696 0.59397E+04 191 zoisite 22.85 19.90 -2.95 -0.134 0.50385E+04 192 akaganeite 7.75 6.28 -1.47 -0.318 0.25125E+04 193 beidellite-Ca -1.65 -4.34 -2.69 -0.167 0.45991E+04 194 beidellite-H -2.33 -6.15 -3.82 -0.244 0.65216E+04 195 beidellite-K -1.52 -4.63 -3.11 -0.191 0.53163E+04 196 beidellite-Mg -1.79 -4.73 -2.95 -0.182 0.50285E+04 197 beidellite-Na -1.34 -4.25 -2.90 -0.178 0.49600E+04 199 chalcedony -2.80 -3.43 -0.63 -0.208 0.10675E+04 201 montmorillonite-Ca -2.29 -4.47 -2.18 -0.135 0.37225E+04 202 montmorillonite-K -2.24 -4.77 -2.53 -0.155 0.43178E+04 203 montmorillonite-Mg -2.48 -4.87 -2.39 -0.148 0.40751E+04 204 montmorillonite-Na -2.04 -4.38 -2.34 -0.143 0.39973E+04 205 nontronite-Ca 3.21 2.70 -0.51 -0.033 0.87076E+03 206 nontronite-H 2.53 0.90 -1.63 -0.110 0.27912E+04 207 nontronite-K 3.34 2.41 -0.93 -0.060 0.15893E+04 208 nontronite-Mg 3.07 2.31 -0.77 -0.050 0.13074E+04 209 nontronite-Na 3.52 2.80 -0.72 -0.046 0.12347E+04 224 tobermorite 9.82 5.69 -4.13 -1.127 0.70524E+04 233 boehmite 4.41 2.76 -1.65 -0.274 0.28089E+04 235 ferrous-oxide 9.81 6.32 -3.49 -0.872 0.59588E+04 240 silica-amorphous -2.09 -3.43 -1.34 -0.445 0.22817E+04 242 an20ab80 2.02 0.51 -1.51 -0.116 0.25770E+04 243 an25ab75 2.65 1.08 -1.57 -0.121 0.26772E+04 244 an30ab70 3.28 1.65 -1.63 -0.126 0.27870E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 0.0200000 g Current total amount of reactant added: 0.5590000 g New total amount of reactant added: 0.5790000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.5874E-14 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 6 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 0.5790000 Water: Moles liquid = 0.5550E+02 kg liquid = 0.9999E+00 Moles total = 0.5550E+02 kg total = 0.9999E+00 Activity = 1.0000 Stoichiometric ionic strength = .7185173E-03 Osmotic coef. = 0.9843 True ionic strength = .9666157E-03 Chg. balance for total moles = -.5874E-14 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.14682E-08 -8.8332 0.13848E-08 -8.8586 0.94320E+00 -0.0254 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13795E-03 -3.8603 0.13007E-03 -3.8858 0.94281E+00 -0.0256 4 SO4-- 0.25488E-04 -4.5937 0.21267E-04 -4.6723 0.83440E+00 -0.0786 5 HCO3- 0.12169E-04 -4.9148 0.11474E-04 -4.9403 0.94291E+00 -0.0255 6 HS- 0.63692E-13 -13.1959 0.60050E-13 -13.2215 0.94282E+00 -0.0256 7 Al+++ 0.22544E-23 -23.6470 0.15326E-23 -23.8146 0.67983E+00 -0.1676 8 H4SiO4 0.37357E-03 -3.4276 0.37357E-03 -3.4276 0.10000E+01 0.0000 9 Ca++ 0.20440E-06 -6.6895 0.17047E-06 -6.7684 0.83399E+00 -0.0788 10 Mg++ 0.81785E-09 -9.0873 0.68187E-09 -9.1663 0.83373E+00 -0.0790 11 Fe++ 0.48251E-11 -11.3165 0.40231E-11 -11.3954 0.83379E+00 -0.0789 12 K+ 0.56041E-04 -4.2515 0.52842E-04 -4.2770 0.94292E+00 -0.0255 13 Na+ 0.88327E-03 -3.0539 0.83275E-03 -3.0795 0.94280E+00 -0.0256 14 Mn++ 0.64822E-09 -9.1883 0.54051E-09 -9.2672 0.83384E+00 -0.0789 15 HPO4-- 0.31376E-06 -6.5034 0.26180E-06 -6.5820 0.83441E+00 -0.0786 16 HSiO3- 0.26716E-03 -3.5732 0.25189E-03 -3.5988 0.94281E+00 -0.0256 17 Ca(HSiO3)+ 0.10370E-08 -8.9842 0.97786E-09 -9.0097 0.94294E+00 -0.0255 18 Mg(HSiO3)+ 0.51625E-11 -11.2871 0.48679E-11 -11.3127 0.94294E+00 -0.0255 19 NaHSiO3,aq 0.33926E-05 -5.4695 0.33926E-05 -5.4695 0.10000E+01 0.0000 20 AlO+ 0.11530E-12 -12.9382 0.10872E-12 -12.9637 0.94294E+00 -0.0255 21 AlOH+2 0.89904E-18 -18.0462 0.74970E-18 -18.1251 0.83389E+00 -0.0789 22 HAlO2,aq 0.15635E-07 -7.8059 0.15635E-07 -7.8059 0.10000E+01 0.0000 23 AlO2- 0.26511E-04 -4.5766 0.24991E-04 -4.6022 0.94270E+00 -0.0256 24 CH4,aq 0.31477E-19 -19.5020 0.31470E-19 -19.5021 0.99978E+00 -0.0001 29 CO,aq 0.38836E-18 -18.4108 0.38836E-18 -18.4108 0.10000E+01 0.0000 30 CO2,aq 0.33959E-07 -7.4690 0.33952E-07 -7.4691 0.99978E+00 -0.0001 31 CO3-2 0.86744E-06 -6.0618 0.72369E-06 -6.1404 0.83428E+00 -0.0787 32 CaCO3,aq 0.15468E-08 -8.8106 0.15468E-08 -8.8106 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.52947E-10 -10.2762 0.49926E-10 -10.3017 0.94294E+00 -0.0255 34 CaCl+ 0.38052E-10 -10.4196 0.35881E-10 -10.4451 0.94294E+00 -0.0255 35 CaCl2,aq 0.11087E-14 -14.9552 0.11087E-14 -14.9552 0.10000E+01 0.0000 36 CaOH+ 0.93038E-08 -8.0313 0.87729E-08 -8.0569 0.94294E+00 -0.0255 37 CaSO4,aq 0.11512E-08 -8.9388 0.11512E-08 -8.9388 0.10000E+01 0.0000 38 HCl,aq 0.33006E-13 -13.4814 0.33006E-13 -13.4814 0.10000E+01 0.0000 43 FeCl+ 0.87837E-15 -15.0563 0.82824E-15 -15.0818 0.94294E+00 -0.0255 46 FeO,aq 0.81533E-10 -10.0887 0.81533E-10 -10.0887 0.10000E+01 0.0000 47 FeOH+ 0.10029E-09 -9.9988 0.94565E-10 -10.0243 0.94294E+00 -0.0255 48 HFeO2- 0.65339E-09 -9.1848 0.61602E-09 -9.2104 0.94281E+00 -0.0256 49 FeO+ 0.11210E-13 -13.9504 0.10570E-13 -13.9759 0.94294E+00 -0.0255 51 FeO2- 0.11962E-08 -8.9222 0.11278E-08 -8.9478 0.94281E+00 -0.0256 52 HFeO2,aq 0.19864E-09 -9.7019 0.19864E-09 -9.7019 0.10000E+01 0.0000 53 H2,aq 0.45544E-09 -9.3416 0.45534E-09 -9.3417 0.99978E+00 -0.0001 54 KCl,aq 0.12457E-09 -9.9046 0.12457E-09 -9.9046 0.10000E+01 0.0000 55 KHSO4,aq 0.44002E-17 -17.3565 0.44002E-17 -17.3565 0.10000E+01 0.0000 56 KOH,aq 0.16296E-07 -7.7879 0.16296E-07 -7.7879 0.10000E+01 0.0000 57 KSO4- 0.18496E-07 -7.7329 0.17439E-07 -7.7585 0.94281E+00 -0.0256 58 MgCO3,aq 0.15509E-11 -11.8094 0.15509E-11 -11.8094 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.21641E-12 -12.6647 0.20406E-12 -12.6902 0.94294E+00 -0.0255 60 MgCl+ 0.13795E-12 -12.8603 0.13008E-12 -12.8858 0.94294E+00 -0.0255 61 MgOH+ 0.20593E-09 -9.6863 0.19418E-09 -9.7118 0.94294E+00 -0.0255 63 MnO,aq 0.29188E-09 -9.5348 0.29188E-09 -9.5348 0.10000E+01 0.0000 64 MnOH+ 0.12517E-08 -8.9025 0.11802E-08 -8.9280 0.94294E+00 -0.0255 65 MnO2-2 0.60543E-14 -14.2179 0.50510E-14 -14.2966 0.83428E+00 -0.0787 66 HMnO2- 0.16254E-11 -11.7890 0.15324E-11 -11.8146 0.94281E+00 -0.0256 69 MnCl+ 0.45911E-12 -12.3381 0.43291E-12 -12.3636 0.94294E+00 -0.0255 70 MnSO4,aq 0.33185E-11 -11.4791 0.33185E-11 -11.4791 0.10000E+01 0.0000 71 NaCl,aq 0.35895E-07 -7.4450 0.35895E-07 -7.4450 0.10000E+01 0.0000 72 NaOH,aq 0.25836E-06 -6.5878 0.25836E-06 -6.5878 0.10000E+01 0.0000 74 OH- 0.44258E-03 -3.3540 0.41722E-03 -3.3796 0.94270E+00 -0.0256 79 HPO3-2 0.44529E-18 -18.3514 0.37149E-18 -18.4300 0.83428E+00 -0.0787 82 H3PO4,aq 0.35115E-14 -14.4545 0.35115E-14 -14.4545 0.10000E+01 0.0000 83 H2PO4- 0.70933E-08 -8.1492 0.66881E-08 -8.1747 0.94287E+00 -0.0255 84 PO4-3 0.22612E-09 -9.6457 0.15424E-09 -9.8118 0.68212E+00 -0.1661 87 H2P2O7-2 0.42040E-17 -17.3763 0.35073E-17 -17.4550 0.83428E+00 -0.0787 88 HP2O7-3 0.74387E-15 -15.1285 0.50572E-15 -15.2961 0.67985E+00 -0.1676 89 P2O7-4 0.17055E-15 -15.7682 0.87241E-16 -16.0593 0.51153E+00 -0.2911 90 H2S,aq 0.25707E-15 -15.5899 0.25701E-15 -15.5900 0.99978E+00 -0.0001 97 SO3-2 0.15069E-14 -14.8219 0.12584E-14 -14.9002 0.83511E+00 -0.0783 98 HSO3- 0.11573E-15 -15.9366 0.10911E-15 -15.9621 0.94281E+00 -0.0256 99 HSO4- 0.30098E-10 -10.5215 0.28383E-10 -10.5469 0.94300E+00 -0.0255 Charge balance for all species = -.5783E-14 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.1468226E-08 -.8203423E-03 -.8267777E+00 0.0000 2 H2O 0.1000000E+01 0.5550848E+02 0.9999074E+06 0.0000 3 Cl- 0.1379543E-03 0.1379903E-03 0.4891710E+01 4.9728 4 SO4-- 0.2548778E-04 0.2550752E-04 0.2450062E+01 13.0449 5 HCO3- 0.1216853E-04 0.1307153E-04 0.7975129E+00 3.9183 6 HS- 0.6369165E-13 -.6043615E-10 -.1998556E-05 -4.3629 7 Al+++ 0.2254418E-23 0.2652618E-04 0.7156485E+00 2.7612 8 H4SiO4 0.3735728E-03 0.6441306E-03 0.6190502E+02 -3.4276 9 Ca++ 0.2043979E-06 0.2175278E-06 0.8717256E-02 10.9488 10 Mg++ 0.8178540E-09 0.1030854E-08 0.2505975E-04 8.5509 11 Fe++ 0.4825086E-11 0.2234917E-08 0.1248016E-03 6.3218 12 K+ 0.5604093E-04 0.5607584E-04 0.2192471E+01 4.5816 13 Na+ 0.8832741E-03 0.8869609E-03 0.2038913E+02 5.7791 14 Mn++ 0.6482191E-09 0.2197170E-08 0.1206968E-03 8.4500 15 HPO4-- 0.3137575E-06 0.3210769E-06 0.3081373E-01 11.1352 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.9574340E-02 -.8202462E-03 -.8754094E-02 0.0000000E+00 2 H2O 0.5550099E+02 0.5550198E+02 -.9838282E-03 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.4155053E-04 0.2550453E-04 0.1604600E-04 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.1604606E-04 -.6042908E-10 -.1604600E-04 0.0000000E+00 7 Al+++ 0.1887969E-02 0.2652307E-04 0.1861446E-02 0.0000000E+00 8 H4SiO4 0.6029001E-02 0.6440551E-03 0.5384946E-02 0.0000000E+00 9 Ca++ 0.6804037E-03 0.2175023E-06 0.6801862E-03 0.0000000E+00 10 Mg++ 0.4595238E-03 0.1030733E-08 0.4595228E-03 0.0000000E+00 11 Fe++ 0.4128320E-03 0.2234655E-08 0.4128297E-03 0.0000000E+00 12 K+ 0.1229299E-03 0.5606928E-04 0.6686066E-04 0.0000000E+00 13 Na+ 0.8868571E-03 0.8868571E-03 0.0000000E+00 0.0000000E+00 14 Mn++ 0.1003905E-04 0.2196913E-08 0.1003685E-04 0.0000000E+00 15 HPO4-- 0.3426277E-05 0.3210393E-06 0.3105238E-05 0.0000000E+00 Chg. balance for solid moles: 0.5590E-19 Mass of aqueous solution: 0.999977E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 0.5790000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) apatite-OH 0.1035E-05 -5.985 0.5199E-03 -3.284 0.8563E-01 0.1652E-03 clinochlore 0.9190E-04 -4.037 0.5108E-01 -1.292 8.413 0.1943E-01 daphnite 0.5689E-04 -4.245 0.4059E-01 -1.392 6.685 0.1230E-01 chlorite-Mn 0.2007E-05 -5.697 0.1423E-02 -2.847 0.2344 0.4535E-03 hematite 0.6418E-04 -4.193 0.1025E-01 -1.989 1.688 0.1943E-02 kaolinite 0.4617E-05 -5.336 0.1192E-02 -2.924 0.1963 0.4586E-03 lawsonite 0.4716E-06 -6.326 0.1482E-03 -3.829 0.2441E-01 0.4779E-04 muscovite 0.6686E-04 -4.175 0.2663E-01 -1.575 4.386 0.9417E-02 stilbite 0.6745E-03 -3.171 0.4754 -0.323 78.29 0.2217 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.6094E+00 0.6094E+00 1.0000 -0.215 daphnite 0.3773E+00 0.3773E+00 1.0000 -0.423 chlorite-Mn 0.1331E-01 0.1331E-01 1.0000 -1.876 hematite 0.1000E+01 0.1000E+01 1.0000 0.000 kaolinite 0.1000E+01 0.1000E+01 1.0000 0.000 lawsonite 0.1000E+01 0.1000E+01 1.0000 0.000 muscovite 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 0.607203 g Volume = 0.265934 cm3 Porosity: 78.4075% V(tot) - V(min): 0.96567E+00 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.5790000 g log = -0.2373 Original solution: 1000.0103000 g Original solution / Rock added: 1727.13 (Water/Rock Ratio), log = 3.2373 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0203 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.1000E+01 0.9860 0.1006E+01 0.1020E+01 CO2,gas 0.3535E-05 1.0071 0.3632E-05 0.3607E-05 CH4,gas 0.4484E-16 1.0125 0.4632E-16 0.4575E-16 H2,gas 0.5856E-06 1.0005 0.5978E-06 0.5975E-06 H2S,gas 0.6952E-14 0.9960 0.7065E-14 0.7093E-14 S2,gas 0.5139E-35 1.0000 0.5243E-35 0.5243E-35 CO,gas 0.5672E-15 1.0000 0.5787E-15 0.5787E-15 SO3,gas 0.1511E-37 1.0000 0.1542E-37 0.1542E-37 SO2,gas 0.3515E-21 1.0000 0.3587E-21 0.3587E-21 HCl,gas 0.5708E-16 1.0000 0.5824E-16 0.5824E-16 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 32 apatite-OH -18.15 -18.15 0.00 0.000 0.00000E+00 46 clinochlore 39.07 39.07 0.00 0.000 0.24265E-10 47 daphnite 28.97 28.97 0.00 0.000 0.18198E-10 48 chlorite-Mn 46.87 46.87 0.00 0.000 0.36397E-10 90 hematite 12.57 12.57 0.00 0.000 0.90992E-11 98 kaolinite -1.33 -1.33 0.00 0.000 0.17819E-10 102 lawsonite 9.62 9.62 0.00 0.000 0.12132E-10 120 muscovite 2.58 2.58 0.00 0.000 0.60662E-11 163 stilbite -7.52 -7.52 0.00 0.000 0.15165E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -13.80 -7.14 -2.380 0.12189E+05 -5.440 3 CH4,gas 4.54 -13.49 -18.03 -4.508 0.30791E+05 -16.334 4 H2,gas 8.00 0.08 -7.92 -4.527 0.13527E+05 -6.223 5 H2S,gas -6.23 -22.08 -15.85 -7.925 0.27063E+05 -14.151 6 S2,gas -7.34 -44.31 -36.98 -5.689 0.63141E+05 -35.280 7 CO,gas 3.21 -13.72 -16.94 -5.211 0.28919E+05 -15.238 8 SO3,gas 17.12 -22.39 -39.51 -9.878 0.67464E+05 -37.812 9 SO2,gas 0.83 -22.31 -23.14 -6.172 0.39518E+05 -21.445 10 HCl,gas 5.19 -12.74 -17.93 -8.967 0.30621E+05 -16.235 11 acmite 7.71 5.21 -2.50 -0.260 0.42734E+04 15 albite-high 0.69 -1.74 -2.44 -0.187 0.41587E+04 16 albite -0.38 -1.74 -1.36 -0.105 0.23199E+04 19 spessartine 24.46 20.59 -3.87 -0.193 0.66040E+04 20 analcite 3.32 1.69 -1.64 -0.182 0.27947E+04 21 andalusite 5.00 2.09 -2.91 -0.291 0.49631E+04 22 andradite 39.01 35.13 -3.88 -0.202 0.66231E+04 23 grossular 32.73 28.09 -4.65 -0.232 0.79317E+04 26 annite 20.12 16.03 -4.10 -0.228 0.69975E+04 27 phlogopite 27.06 22.71 -4.35 -0.242 0.74308E+04 29 anorthite 12.71 9.62 -3.09 -0.238 0.52833E+04 35 aragonite 0.97 -2.85 -3.82 -1.272 0.65167E+04 36 brucite 12.57 8.55 -4.02 -0.804 0.68600E+04 37 calcite 0.81 -2.85 -3.66 -1.221 0.62525E+04 38 carnegieite-low 9.02 5.11 -3.91 -0.559 0.66772E+04 39 carnegieite-high 10.09 5.11 -4.98 -0.712 0.85042E+04 40 carpholite-Mg 8.58 7.22 -1.36 -0.091 0.23289E+04 41 carpholite-Fe 6.71 4.99 -1.72 -0.115 0.29431E+04 42 celadonite 5.34 2.18 -3.16 -0.186 0.53928E+04 43 celadonite-Fe 3.88 -0.05 -3.92 -0.231 0.66974E+04 50 chloritoid-Mg 13.20 10.65 -2.55 -0.170 0.43574E+04 51 chloritoid-Fe 9.17 8.42 -0.76 -0.050 0.12926E+04 52 chloritoid-Mn 11.40 10.54 -0.86 -0.057 0.14620E+04 54 coesite -2.38 -3.43 -1.05 -0.351 0.17955E+04 59 corundum 8.38 5.52 -2.86 -0.260 0.48845E+04 61 cristobalite -2.56 -3.43 -0.87 -0.289 0.14809E+04 63 cymrite-K 1.69 -2.94 -4.63 -0.385 0.78978E+04 65 diaspore 2.87 2.76 -0.11 -0.019 0.19202E+03 67 diopside 16.18 12.64 -3.54 -0.354 0.60391E+04 68 hedenbergite 14.21 10.42 -3.79 -0.379 0.64763E+04 75 epidote 24.67 23.42 -1.25 -0.061 0.21335E+04 76 clinozoisite 22.81 19.90 -2.91 -0.132 0.49645E+04 77 epidote-Fe 29.84 26.94 -2.90 -0.151 0.49492E+04 78 fayalite 14.05 9.22 -4.83 -0.690 0.82468E+04 83 gibbsite 4.08 2.76 -1.32 -0.188 0.22506E+04 87 greenalite 16.14 12.11 -4.03 -0.336 0.68802E+04 91 heulandite -5.83 -7.52 -1.69 -0.077 0.28938E+04 95 jadeite 4.22 1.69 -2.53 -0.253 0.43202E+04 97 kalsilite 7.58 3.92 -3.67 -0.524 0.62642E+04 99 kyanite 4.88 2.09 -2.78 -0.278 0.47490E+04 101 laumontite 2.88 2.76 -0.12 -0.008 0.20932E+03 103 leucite 4.12 0.49 -3.63 -0.363 0.62003E+04 105 lizardite 23.24 18.80 -4.45 -0.371 0.75921E+04 107 magnetite 20.09 18.89 -1.20 -0.098 0.20480E+04 113 margarite 17.32 15.14 -2.19 -0.087 0.37309E+04 116 microcline -2.49 -2.94 -0.45 -0.035 0.77443E+03 121 paragonite 4.24 3.78 -0.46 -0.027 0.78452E+03 122 nepheline 8.34 5.11 -3.23 -0.461 0.55095E+04 136 prehnite 19.37 17.14 -2.23 -0.131 0.38155E+04 137 prehnite-Fe 22.50 20.66 -1.84 -0.111 0.31396E+04 138 pumpellyite-Fe 46.27 43.36 -2.91 -0.065 0.49719E+04 139 pumpellyite-Mg 48.99 45.59 -3.41 -0.076 0.58193E+04 145 pyroxmangite 7.40 5.02 -2.38 -0.475 0.40575E+04 146 pyrophyllite -6.18 -8.19 -2.01 -0.126 0.34358E+04 147 quartz -2.99 -3.43 -0.44 -0.146 0.74820E+03 151 rhodochrosite -0.98 -5.35 -4.37 -1.458 0.74660E+04 152 rhodonite 7.45 5.02 -2.42 -0.485 0.41377E+04 153 sanidine -1.28 -2.94 -1.66 -0.128 0.28422E+04 155 siderite -2.61 -7.48 -4.87 -1.623 0.83137E+04 156 sillimanite 5.26 2.09 -3.17 -0.317 0.54070E+04 164 stilpnomelane-Fe 13.02 12.00 -1.02 -0.030 0.17346E+04 165 stilpnomelane-Mg 27.44 23.15 -4.29 -0.128 0.73329E+04 167 sudoite-Fe 18.30 13.41 -4.89 -0.158 0.83505E+04 168 sudoite 21.08 17.86 -3.21 -0.104 0.54869E+04 171 talc 16.49 11.94 -4.55 -0.268 0.77670E+04 174 tephroite 18.09 13.47 -4.61 -0.659 0.78773E+04 177 topaz-H 4.62 2.09 -2.52 -0.229 0.43090E+04 178 tridymite -2.63 -3.43 -0.80 -0.267 0.13682E+04 187 wairakite 3.95 2.76 -1.19 -0.070 0.20313E+04 188 walstromite 11.51 7.52 -3.99 -0.798 0.68094E+04 189 wollastonite 10.46 7.52 -2.94 -0.588 0.50199E+04 190 pseudo-wollastonite 11.00 7.52 -3.48 -0.696 0.59397E+04 191 zoisite 22.85 19.90 -2.95 -0.134 0.50385E+04 192 akaganeite 7.75 6.28 -1.47 -0.318 0.25125E+04 193 beidellite-Ca -1.65 -4.34 -2.69 -0.167 0.45991E+04 194 beidellite-H -2.33 -6.15 -3.82 -0.244 0.65216E+04 195 beidellite-K -1.52 -4.63 -3.11 -0.191 0.53163E+04 196 beidellite-Mg -1.79 -4.73 -2.95 -0.182 0.50285E+04 197 beidellite-Na -1.34 -4.24 -2.90 -0.177 0.49454E+04 199 chalcedony -2.80 -3.43 -0.63 -0.208 0.10675E+04 201 montmorillonite-Ca -2.29 -4.47 -2.18 -0.135 0.37225E+04 202 montmorillonite-K -2.24 -4.77 -2.53 -0.155 0.43178E+04 203 montmorillonite-Mg -2.48 -4.87 -2.39 -0.148 0.40751E+04 204 montmorillonite-Na -2.04 -4.37 -2.33 -0.143 0.39827E+04 205 nontronite-Ca 3.21 2.70 -0.51 -0.033 0.87076E+03 206 nontronite-H 2.53 0.90 -1.63 -0.110 0.27912E+04 207 nontronite-K 3.34 2.41 -0.93 -0.060 0.15893E+04 208 nontronite-Mg 3.07 2.31 -0.77 -0.050 0.13074E+04 209 nontronite-Na 3.52 2.81 -0.71 -0.046 0.12201E+04 224 tobermorite 9.82 5.69 -4.13 -1.127 0.70524E+04 233 boehmite 4.41 2.76 -1.65 -0.274 0.28089E+04 235 ferrous-oxide 9.81 6.32 -3.49 -0.872 0.59588E+04 240 silica-amorphous -2.09 -3.43 -1.34 -0.445 0.22817E+04 242 an20ab80 2.02 0.53 -1.49 -0.115 0.25417E+04 243 an25ab75 2.65 1.10 -1.55 -0.119 0.26441E+04 244 an30ab70 3.28 1.67 -1.61 -0.124 0.27562E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 0.0200000 g Current total amount of reactant added: 0.5790000 g New total amount of reactant added: 0.5990000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.5874E-14 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 6 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 0.5990000 Water: Moles liquid = 0.5550E+02 kg liquid = 0.9999E+00 Moles total = 0.5550E+02 kg total = 0.9999E+00 Activity = 1.0000 Stoichiometric ionic strength = .7340113E-03 Osmotic coef. = 0.9841 True ionic strength = .9898634E-03 Chg. balance for total moles = -.5874E-14 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.14248E-08 -8.8462 0.13433E-08 -8.8718 0.94277E+00 -0.0256 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13795E-03 -3.8603 0.13000E-03 -3.8860 0.94237E+00 -0.0258 4 SO4-- 0.25489E-04 -4.5937 0.21228E-04 -4.6731 0.83285E+00 -0.0794 5 HCO3- 0.12143E-04 -4.9157 0.11445E-04 -4.9414 0.94247E+00 -0.0257 6 HS- 0.61696E-13 -13.2097 0.58141E-13 -13.2355 0.94238E+00 -0.0258 7 Al+++ 0.20661E-23 -23.6849 0.13987E-23 -23.8543 0.67698E+00 -0.1694 8 H4SiO4 0.37357E-03 -3.4276 0.37357E-03 -3.4276 0.10000E+01 0.0000 9 Ca++ 0.19267E-06 -6.7152 0.16039E-06 -6.7948 0.83243E+00 -0.0797 10 Mg++ 0.77094E-09 -9.1130 0.64155E-09 -9.1928 0.83217E+00 -0.0798 11 Fe++ 0.45483E-11 -11.3422 0.37852E-11 -11.4219 0.83223E+00 -0.0798 12 K+ 0.54384E-04 -4.2645 0.51256E-04 -4.2903 0.94248E+00 -0.0257 13 Na+ 0.90817E-03 -3.0418 0.85582E-03 -3.0676 0.94236E+00 -0.0258 14 Mn++ 0.61104E-09 -9.2139 0.50855E-09 -9.2937 0.83228E+00 -0.0797 15 HPO4-- 0.33410E-06 -6.4761 0.27826E-06 -6.5556 0.83286E+00 -0.0794 16 HSiO3- 0.27556E-03 -3.5598 0.25968E-03 -3.5856 0.94237E+00 -0.0258 17 Ca(HSiO3)+ 0.10064E-08 -8.9972 0.94850E-09 -9.0230 0.94250E+00 -0.0257 18 Mg(HSiO3)+ 0.50098E-11 -11.3002 0.47217E-11 -11.3259 0.94250E+00 -0.0257 19 NaHSiO3,aq 0.35944E-05 -5.4444 0.35944E-05 -5.4444 0.10000E+01 0.0000 20 AlO+ 0.11189E-12 -12.9512 0.10546E-12 -12.9769 0.94250E+00 -0.0257 21 AlOH+2 0.84746E-18 -18.0719 0.70537E-18 -18.1516 0.83233E+00 -0.0797 22 HAlO2,aq 0.15635E-07 -7.8059 0.15635E-07 -7.8059 0.10000E+01 0.0000 23 AlO2- 0.27344E-04 -4.5631 0.25765E-04 -4.5890 0.94225E+00 -0.0258 24 CH4,aq 0.30455E-19 -19.5163 0.30449E-19 -19.5164 0.99977E+00 -0.0001 29 CO,aq 0.37575E-18 -18.4251 0.37575E-18 -18.4251 0.10000E+01 0.0000 30 CO2,aq 0.32857E-07 -7.4834 0.32849E-07 -7.4835 0.99977E+00 -0.0001 31 CO3-2 0.89369E-06 -6.0488 0.74420E-06 -6.1283 0.83273E+00 -0.0795 32 CaCO3,aq 0.14966E-08 -8.8249 0.14966E-08 -8.8249 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.49714E-10 -10.3035 0.46855E-10 -10.3292 0.94250E+00 -0.0257 34 CaCl+ 0.35802E-10 -10.4461 0.33743E-10 -10.4718 0.94250E+00 -0.0257 35 CaCl2,aq 0.10422E-14 -14.9821 0.10422E-14 -14.9821 0.10000E+01 0.0000 36 CaOH+ 0.90287E-08 -8.0444 0.85095E-08 -8.0701 0.94250E+00 -0.0257 37 CaSO4,aq 0.10811E-08 -8.9661 0.10811E-08 -8.9661 0.10000E+01 0.0000 38 HCl,aq 0.32000E-13 -13.4948 0.32000E-13 -13.4948 0.10000E+01 0.0000 43 FeCl+ 0.82642E-15 -15.0828 0.77890E-15 -15.1085 0.94250E+00 -0.0257 46 FeO,aq 0.81533E-10 -10.0887 0.81533E-10 -10.0887 0.10000E+01 0.0000 47 FeOH+ 0.97322E-10 -10.0118 0.91726E-10 -10.0375 0.94250E+00 -0.0257 48 HFeO2- 0.67392E-09 -9.1714 0.63508E-09 -9.1972 0.94237E+00 -0.0258 49 FeO+ 0.10879E-13 -13.9634 0.10253E-13 -13.9891 0.94250E+00 -0.0257 51 FeO2- 0.12338E-08 -8.9087 0.11627E-08 -8.9345 0.94237E+00 -0.0258 52 HFeO2,aq 0.19864E-09 -9.7019 0.19864E-09 -9.7019 0.10000E+01 0.0000 53 H2,aq 0.45544E-09 -9.3416 0.45534E-09 -9.3417 0.99977E+00 -0.0001 54 KCl,aq 0.12077E-09 -9.9180 0.12077E-09 -9.9180 0.10000E+01 0.0000 55 KHSO4,aq 0.41324E-17 -17.3838 0.41324E-17 -17.3838 0.10000E+01 0.0000 56 KOH,aq 0.16296E-07 -7.7879 0.16296E-07 -7.7879 0.10000E+01 0.0000 57 KSO4- 0.17917E-07 -7.7467 0.16884E-07 -7.7725 0.94237E+00 -0.0258 58 MgCO3,aq 0.15006E-11 -11.8237 0.15006E-11 -11.8237 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.20319E-12 -12.6921 0.19151E-12 -12.7178 0.94250E+00 -0.0257 60 MgCl+ 0.12980E-12 -12.8867 0.12233E-12 -12.9125 0.94250E+00 -0.0257 61 MgOH+ 0.19984E-09 -9.6993 0.18835E-09 -9.7250 0.94250E+00 -0.0257 63 MnO,aq 0.29188E-09 -9.5348 0.29188E-09 -9.5348 0.10000E+01 0.0000 64 MnOH+ 0.12147E-08 -8.9155 0.11448E-08 -8.9413 0.94250E+00 -0.0257 65 MnO2-2 0.64469E-14 -14.1906 0.53685E-14 -14.2701 0.83273E+00 -0.0795 66 HMnO2- 0.16765E-11 -11.7756 0.15799E-11 -11.8014 0.94237E+00 -0.0258 69 MnCl+ 0.43196E-12 -12.3646 0.40712E-12 -12.3903 0.94250E+00 -0.0257 70 MnSO4,aq 0.31166E-11 -11.5063 0.31166E-11 -11.5063 0.10000E+01 0.0000 71 NaCl,aq 0.36872E-07 -7.4333 0.36872E-07 -7.4333 0.10000E+01 0.0000 72 NaOH,aq 0.27374E-06 -6.5627 0.27374E-06 -6.5627 0.10000E+01 0.0000 74 OH- 0.45649E-03 -3.3406 0.43013E-03 -3.3664 0.94225E+00 -0.0258 79 HPO3-2 0.47416E-18 -18.3241 0.39484E-18 -18.4036 0.83273E+00 -0.0795 82 H3PO4,aq 0.35115E-14 -14.4545 0.35115E-14 -14.4545 0.10000E+01 0.0000 83 H2PO4- 0.73163E-08 -8.1357 0.68951E-08 -8.1615 0.94243E+00 -0.0258 84 PO4-3 0.24880E-09 -9.6042 0.16901E-09 -9.7721 0.67932E+00 -0.1679 87 H2P2O7-2 0.44766E-17 -17.3491 0.37278E-17 -17.4285 0.83273E+00 -0.0795 88 HP2O7-3 0.81852E-15 -15.0870 0.55414E-15 -15.2564 0.67700E+00 -0.1694 89 P2O7-4 0.19410E-15 -15.7120 0.98552E-16 -16.0063 0.50775E+00 -0.2944 90 H2S,aq 0.24143E-15 -15.6172 0.24137E-15 -15.6173 0.99977E+00 -0.0001 97 SO3-2 0.15069E-14 -14.8219 0.12561E-14 -14.9010 0.83358E+00 -0.0791 98 HSO3- 0.11210E-15 -15.9504 0.10564E-15 -15.9762 0.94237E+00 -0.0258 99 HSO4- 0.29155E-10 -10.5353 0.27480E-10 -10.5610 0.94256E+00 -0.0257 Charge balance for all species = -.5782E-14 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.1424808E-08 -.8462297E-03 -.8528670E+00 0.0000 2 H2O 0.1000000E+01 0.5550848E+02 0.9999061E+06 0.0000 3 Cl- 0.1379538E-03 0.1379908E-03 0.4891720E+01 4.9858 4 SO4-- 0.2548852E-04 0.2550762E-04 0.2450068E+01 13.0706 5 HCO3- 0.1214348E-04 0.1307158E-04 0.7975147E+00 3.9304 6 HS- 0.6169567E-13 -.6513760E-10 -.2154024E-05 -4.3637 7 Al+++ 0.2066093E-23 0.2735953E-04 0.7381304E+00 2.7612 8 H4SiO4 0.3735728E-03 0.6527299E-03 0.6273138E+02 -3.4276 9 Ca++ 0.1926706E-06 0.2053690E-06 0.8229990E-02 10.9488 10 Mg++ 0.7709352E-09 0.9776220E-09 0.2376567E-04 8.5509 11 Fe++ 0.4548271E-11 0.2289812E-08 0.1278668E-03 6.3218 12 K+ 0.5438407E-04 0.5441840E-04 0.2127664E+01 4.5816 13 Na+ 0.9081670E-03 0.9120721E-03 0.2096634E+02 5.8042 14 Mn++ 0.6110389E-09 0.2122828E-08 0.1166127E-03 8.4500 15 HPO4-- 0.3340982E-06 0.3416633E-06 0.3278936E-01 11.1881 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.9905511E-02 -.8461275E-03 -.9059383E-02 0.0000000E+00 2 H2O 0.5550074E+02 0.5550178E+02 -.1037197E-02 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.4210480E-04 0.2550454E-04 0.1660027E-04 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.1660033E-04 -.6512974E-10 -.1660027E-04 0.0000000E+00 7 Al+++ 0.1953184E-02 0.2735623E-04 0.1925828E-02 0.0000000E+00 8 H4SiO4 0.6237257E-02 0.6526511E-03 0.5584606E-02 0.0000000E+00 9 Ca++ 0.7034065E-03 0.2053442E-06 0.7032012E-03 0.0000000E+00 10 Mg++ 0.4753968E-03 0.9775039E-09 0.4753958E-03 0.0000000E+00 11 Fe++ 0.4270921E-03 0.2289535E-08 0.4270899E-03 0.0000000E+00 12 K+ 0.1271762E-03 0.5441183E-04 0.7276439E-04 0.0000000E+00 13 Na+ 0.9119619E-03 0.9119619E-03 0.0000000E+00 0.0000000E+00 14 Mn++ 0.1038582E-04 0.2122571E-08 0.1038370E-04 0.0000000E+00 15 HPO4-- 0.3544628E-05 0.3416220E-06 0.3203006E-05 0.0000000E+00 Chg. balance for solid moles: -.8174E-18 Mass of aqueous solution: 0.999975E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 0.5990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) apatite-OH 0.1068E-05 -5.972 0.5363E-03 -3.271 0.8523E-01 0.1704E-03 clinochlore 0.9508E-04 -4.022 0.5285E-01 -1.277 8.398 0.2010E-01 daphnite 0.5886E-04 -4.230 0.4200E-01 -1.377 6.674 0.1273E-01 chlorite-Mn 0.2077E-05 -5.683 0.1472E-02 -2.832 0.2340 0.4692E-03 hematite 0.6640E-04 -4.178 0.1060E-01 -1.975 1.685 0.2010E-02 kaolinite -.1089E-06 1.000 -.2811E-04 1.000 -.4466E-02 -.1081E-04 lawsonite -.2690E-05 1.000 -.8453E-03 1.000 -.1343 -.2726E-03 muscovite 0.7276E-04 -4.138 0.2898E-01 -1.538 4.606 0.1025E-01 stilbite 0.7006E-03 -3.155 0.4937 -0.307 78.46 0.2303 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.6094E+00 0.6094E+00 1.0000 -0.215 daphnite 0.3773E+00 0.3773E+00 1.0000 -0.423 chlorite-Mn 0.1331E-01 0.1331E-01 1.0000 -1.876 hematite 0.1000E+01 0.1000E+01 1.0000 0.000 kaolinite 0.1000E+01 0.1000E+01 1.0000 0.000 lawsonite 0.1000E+01 0.1000E+01 1.0000 0.000 muscovite 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 0.629259 g Volume = 0.275710 cm3 Porosity: 77.7582% V(tot) - V(min): 0.96389E+00 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.5990000 g log = -0.2226 Original solution: 1000.0103000 g Original solution / Rock added: 1669.47 (Water/Rock Ratio), log = 3.2226 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0203 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.1000E+01 0.9860 0.1006E+01 0.1020E+01 CO2,gas 0.3420E-05 1.0071 0.3515E-05 0.3490E-05 CH4,gas 0.4338E-16 1.0125 0.4482E-16 0.4426E-16 H2,gas 0.5856E-06 1.0005 0.5978E-06 0.5975E-06 H2S,gas 0.6529E-14 0.9960 0.6635E-14 0.6662E-14 S2,gas 0.4532E-35 1.0000 0.4624E-35 0.4624E-35 CO,gas 0.5488E-15 1.0000 0.5599E-15 0.5599E-15 SO3,gas 0.1419E-37 1.0000 0.1448E-37 0.1448E-37 SO2,gas 0.3301E-21 1.0000 0.3368E-21 0.3368E-21 HCl,gas 0.5534E-16 1.0000 0.5646E-16 0.5646E-16 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 32 apatite-OH -18.15 -18.15 0.00 0.000 0.60662E-11 46 clinochlore 39.07 39.07 0.00 0.000 0.48529E-10 47 daphnite 28.97 28.97 0.00 0.000 0.30331E-10 48 chlorite-Mn 46.87 46.87 0.00 0.000 0.36397E-10 90 hematite 12.57 12.57 0.00 0.000 -0.30331E-11 120 muscovite 2.58 2.58 0.00 0.000 -0.18198E-10 163 stilbite -7.52 -7.52 0.00 0.000 0.15165E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -13.81 -7.15 -2.384 0.12214E+05 -5.454 3 CH4,gas 4.54 -13.50 -18.05 -4.512 0.30816E+05 -16.349 4 H2,gas 8.00 0.08 -7.92 -4.527 0.13527E+05 -6.223 5 H2S,gas -6.23 -22.11 -15.88 -7.939 0.27110E+05 -14.178 6 S2,gas -7.34 -44.37 -37.03 -5.698 0.63234E+05 -35.335 7 CO,gas 3.21 -13.74 -16.95 -5.216 0.28943E+05 -15.252 8 SO3,gas 17.12 -22.42 -39.54 -9.885 0.67510E+05 -37.839 9 SO2,gas 0.83 -22.34 -23.17 -6.179 0.39565E+05 -21.473 10 HCl,gas 5.19 -12.76 -17.95 -8.974 0.30644E+05 -16.248 11 acmite 7.71 5.23 -2.48 -0.257 0.42305E+04 15 albite-high 0.69 -1.72 -2.41 -0.185 0.41158E+04 16 albite -0.38 -1.72 -1.33 -0.103 0.22770E+04 19 spessartine 24.46 20.59 -3.87 -0.193 0.66040E+04 20 analcite 3.32 1.71 -1.61 -0.179 0.27518E+04 21 andalusite 5.00 2.09 -2.91 -0.291 0.49631E+04 22 andradite 39.01 35.13 -3.88 -0.202 0.66231E+04 23 grossular 32.73 28.09 -4.65 -0.232 0.79317E+04 26 annite 20.12 16.03 -4.10 -0.228 0.69975E+04 27 phlogopite 27.06 22.71 -4.35 -0.242 0.74308E+04 29 anorthite 12.71 9.62 -3.09 -0.238 0.52833E+04 35 aragonite 0.97 -2.86 -3.83 -1.277 0.65412E+04 36 brucite 12.57 8.55 -4.02 -0.804 0.68600E+04 37 calcite 0.81 -2.86 -3.68 -1.225 0.62769E+04 38 carnegieite-low 9.02 5.14 -3.89 -0.555 0.66343E+04 39 carnegieite-high 10.09 5.14 -4.96 -0.708 0.84613E+04 40 carpholite-Mg 8.58 7.22 -1.36 -0.091 0.23289E+04 41 carpholite-Fe 6.71 4.99 -1.72 -0.115 0.29431E+04 42 celadonite 5.34 2.18 -3.16 -0.186 0.53928E+04 43 celadonite-Fe 3.88 -0.05 -3.92 -0.231 0.66974E+04 50 chloritoid-Mg 13.20 10.65 -2.55 -0.170 0.43574E+04 51 chloritoid-Fe 9.17 8.42 -0.76 -0.050 0.12926E+04 52 chloritoid-Mn 11.40 10.54 -0.86 -0.057 0.14619E+04 54 coesite -2.38 -3.43 -1.05 -0.351 0.17955E+04 59 corundum 8.38 5.52 -2.86 -0.260 0.48845E+04 61 cristobalite -2.56 -3.43 -0.87 -0.289 0.14809E+04 63 cymrite-K 1.69 -2.94 -4.63 -0.385 0.78978E+04 65 diaspore 2.87 2.76 -0.11 -0.019 0.19202E+03 67 diopside 16.18 12.64 -3.54 -0.354 0.60391E+04 68 hedenbergite 14.21 10.42 -3.79 -0.379 0.64763E+04 75 epidote 24.67 23.42 -1.25 -0.061 0.21335E+04 76 clinozoisite 22.81 19.90 -2.91 -0.132 0.49645E+04 77 epidote-Fe 29.84 26.94 -2.90 -0.151 0.49492E+04 78 fayalite 14.05 9.22 -4.83 -0.690 0.82468E+04 83 gibbsite 4.08 2.76 -1.32 -0.188 0.22506E+04 87 greenalite 16.14 12.11 -4.03 -0.336 0.68802E+04 91 heulandite -5.83 -7.52 -1.69 -0.077 0.28938E+04 95 jadeite 4.22 1.71 -2.51 -0.251 0.42773E+04 97 kalsilite 7.58 3.92 -3.67 -0.524 0.62642E+04 98 kaolinite -1.33 -1.33 0.00 0.000 0.56870E-11 99 kyanite 4.88 2.09 -2.78 -0.278 0.47490E+04 101 laumontite 2.88 2.76 -0.12 -0.008 0.20932E+03 102 lawsonite 9.62 9.62 0.00 0.000 0.12132E-10 103 leucite 4.12 0.49 -3.63 -0.363 0.62003E+04 105 lizardite 23.24 18.80 -4.45 -0.371 0.75921E+04 107 magnetite 20.09 18.89 -1.20 -0.098 0.20480E+04 113 margarite 17.32 15.14 -2.19 -0.087 0.37309E+04 116 microcline -2.49 -2.94 -0.45 -0.035 0.77443E+03 121 paragonite 4.24 3.81 -0.43 -0.026 0.74166E+03 122 nepheline 8.34 5.14 -3.20 -0.457 0.54667E+04 136 prehnite 19.37 17.14 -2.23 -0.131 0.38155E+04 137 prehnite-Fe 22.50 20.66 -1.84 -0.111 0.31396E+04 138 pumpellyite-Fe 46.27 43.36 -2.91 -0.065 0.49719E+04 139 pumpellyite-Mg 48.99 45.59 -3.41 -0.076 0.58193E+04 145 pyroxmangite 7.40 5.02 -2.38 -0.475 0.40574E+04 146 pyrophyllite -6.18 -8.19 -2.01 -0.126 0.34358E+04 147 quartz -2.99 -3.43 -0.44 -0.146 0.74820E+03 151 rhodochrosite -0.98 -5.36 -4.39 -1.462 0.74905E+04 152 rhodonite 7.45 5.02 -2.42 -0.485 0.41377E+04 153 sanidine -1.28 -2.94 -1.66 -0.128 0.28422E+04 155 siderite -2.61 -7.49 -4.88 -1.628 0.83381E+04 156 sillimanite 5.26 2.09 -3.17 -0.317 0.54070E+04 164 stilpnomelane-Fe 13.02 12.00 -1.02 -0.030 0.17346E+04 165 stilpnomelane-Mg 27.44 23.15 -4.29 -0.128 0.73329E+04 167 sudoite-Fe 18.30 13.41 -4.89 -0.158 0.83505E+04 168 sudoite 21.08 17.86 -3.21 -0.104 0.54869E+04 171 talc 16.49 11.94 -4.55 -0.268 0.77670E+04 174 tephroite 18.09 13.47 -4.61 -0.659 0.78772E+04 177 topaz-H 4.62 2.09 -2.52 -0.229 0.43090E+04 178 tridymite -2.63 -3.43 -0.80 -0.267 0.13682E+04 187 wairakite 3.95 2.76 -1.19 -0.070 0.20313E+04 188 walstromite 11.51 7.52 -3.99 -0.798 0.68094E+04 189 wollastonite 10.46 7.52 -2.94 -0.588 0.50199E+04 190 pseudo-wollastonite 11.00 7.52 -3.48 -0.696 0.59397E+04 191 zoisite 22.85 19.90 -2.95 -0.134 0.50385E+04 192 akaganeite 7.75 6.28 -1.47 -0.318 0.25125E+04 193 beidellite-Ca -1.65 -4.34 -2.69 -0.167 0.45991E+04 194 beidellite-H -2.33 -6.15 -3.82 -0.244 0.65216E+04 195 beidellite-K -1.52 -4.63 -3.11 -0.191 0.53163E+04 196 beidellite-Mg -1.79 -4.73 -2.95 -0.182 0.50285E+04 197 beidellite-Na -1.34 -4.23 -2.89 -0.177 0.49313E+04 199 chalcedony -2.80 -3.43 -0.63 -0.208 0.10675E+04 201 montmorillonite-Ca -2.29 -4.47 -2.18 -0.135 0.37225E+04 202 montmorillonite-K -2.24 -4.77 -2.53 -0.155 0.43178E+04 203 montmorillonite-Mg -2.48 -4.87 -2.39 -0.148 0.40751E+04 204 montmorillonite-Na -2.04 -4.36 -2.32 -0.142 0.39686E+04 205 nontronite-Ca 3.21 2.70 -0.51 -0.033 0.87076E+03 206 nontronite-H 2.53 0.90 -1.63 -0.110 0.27912E+04 207 nontronite-K 3.34 2.41 -0.93 -0.060 0.15893E+04 208 nontronite-Mg 3.07 2.31 -0.77 -0.050 0.13074E+04 209 nontronite-Na 3.52 2.81 -0.71 -0.045 0.12060E+04 224 tobermorite 9.82 5.69 -4.13 -1.127 0.70524E+04 233 boehmite 4.41 2.76 -1.65 -0.274 0.28089E+04 235 ferrous-oxide 9.81 6.32 -3.49 -0.872 0.59588E+04 240 silica-amorphous -2.09 -3.43 -1.34 -0.445 0.22817E+04 242 an20ab80 2.02 0.55 -1.47 -0.113 0.25074E+04 243 an25ab75 2.65 1.12 -1.53 -0.118 0.26120E+04 244 an30ab70 3.28 1.68 -1.60 -0.123 0.27262E+04 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 6 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 0.5990000 Water: Moles liquid = 0.5550E+02 kg liquid = 0.9999E+00 Moles total = 0.5550E+02 kg total = 0.9999E+00 Activity = 1.0000 Stoichiometric ionic strength = .7308781E-03 Osmotic coef. = 0.9842 True ionic strength = .9897398E-03 Chg. balance for total moles = -.5874E-14 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.14357E-08 -8.8429 0.13535E-08 -8.8685 0.94277E+00 -0.0256 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13795E-03 -3.8603 0.13000E-03 -3.8860 0.94237E+00 -0.0258 4 SO4-- 0.25489E-04 -4.5937 0.21228E-04 -4.6731 0.83286E+00 -0.0794 5 HCO3- 0.12150E-04 -4.9154 0.11451E-04 -4.9412 0.94247E+00 -0.0257 6 HS- 0.59478E-13 -13.2256 0.56051E-13 -13.2514 0.94238E+00 -0.0258 7 Al+++ 0.20748E-23 -23.6830 0.14046E-23 -23.8524 0.67699E+00 -0.1694 8 H4SiO4 0.38174E-03 -3.4182 0.38174E-03 -3.4182 0.10000E+01 0.0000 9 Ca++ 0.17452E-06 -6.7581 0.14528E-06 -6.8378 0.83244E+00 -0.0796 10 Mg++ 0.77844E-09 -9.1088 0.64780E-09 -9.1886 0.83217E+00 -0.0798 11 Fe++ 0.45926E-11 -11.3379 0.38221E-11 -11.4177 0.83224E+00 -0.0798 12 K+ 0.54306E-04 -4.2651 0.51183E-04 -4.2909 0.94249E+00 -0.0257 13 Na+ 0.90812E-03 -3.0419 0.85578E-03 -3.0676 0.94236E+00 -0.0258 14 Mn++ 0.61699E-09 -9.2097 0.51351E-09 -9.2894 0.83229E+00 -0.0797 15 HPO4-- 0.39799E-06 -6.4001 0.33147E-06 -6.4796 0.83287E+00 -0.0794 16 HSiO3- 0.27945E-03 -3.5537 0.26334E-03 -3.5795 0.94237E+00 -0.0258 17 Ca(HSiO3)+ 0.92445E-09 -9.0341 0.87130E-09 -9.0598 0.94250E+00 -0.0257 18 Mg(HSiO3)+ 0.51300E-11 -11.2899 0.48350E-11 -11.3156 0.94250E+00 -0.0257 19 NaHSiO3,aq 0.36449E-05 -5.4383 0.36449E-05 -5.4383 0.10000E+01 0.0000 20 AlO+ 0.11067E-12 -12.9560 0.10430E-12 -12.9817 0.94250E+00 -0.0257 21 AlOH+2 0.84459E-18 -18.0734 0.70299E-18 -18.1531 0.83234E+00 -0.0797 22 HAlO2,aq 0.15347E-07 -7.8140 0.15347E-07 -7.8140 0.10000E+01 0.0000 23 AlO2- 0.26636E-04 -4.5745 0.25098E-04 -4.6004 0.94225E+00 -0.0258 24 CH4,aq 0.29375E-19 -19.5320 0.29369E-19 -19.5321 0.99977E+00 -0.0001 29 CO,aq 0.37465E-18 -18.4264 0.37465E-18 -18.4264 0.10000E+01 0.0000 30 CO2,aq 0.33125E-07 -7.4798 0.33118E-07 -7.4799 0.99977E+00 -0.0001 31 CO3-2 0.88736E-06 -6.0519 0.73893E-06 -6.1314 0.83273E+00 -0.0795 32 CaCO3,aq 0.13461E-08 -8.8709 0.13461E-08 -8.8709 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.45055E-10 -10.3463 0.42464E-10 -10.3720 0.94250E+00 -0.0257 34 CaCl+ 0.32430E-10 -10.4891 0.30565E-10 -10.5148 0.94250E+00 -0.0257 35 CaCl2,aq 0.94404E-15 -15.0250 0.94404E-15 -15.0250 0.10000E+01 0.0000 36 CaOH+ 0.81164E-08 -8.0906 0.76497E-08 -8.1164 0.94250E+00 -0.0257 37 CaSO4,aq 0.97934E-09 -9.0091 0.97934E-09 -9.0091 0.10000E+01 0.0000 38 HCl,aq 0.32245E-13 -13.4915 0.32245E-13 -13.4915 0.10000E+01 0.0000 43 FeCl+ 0.83447E-15 -15.0786 0.78649E-15 -15.1043 0.94250E+00 -0.0257 46 FeO,aq 0.81083E-10 -10.0911 0.81083E-10 -10.0911 0.10000E+01 0.0000 47 FeOH+ 0.97525E-10 -10.0109 0.91918E-10 -10.0366 0.94250E+00 -0.0257 48 HFeO2- 0.66512E-09 -9.1771 0.62679E-09 -9.2029 0.94237E+00 -0.0258 49 FeO+ 0.10962E-13 -13.9601 0.10331E-13 -13.9858 0.94250E+00 -0.0257 51 FeO2- 0.12245E-08 -8.9121 0.11539E-08 -8.9378 0.94237E+00 -0.0258 52 HFeO2,aq 0.19864E-09 -9.7019 0.19864E-09 -9.7019 0.10000E+01 0.0000 53 H2,aq 0.45043E-09 -9.3464 0.45033E-09 -9.3465 0.99977E+00 -0.0001 54 KCl,aq 0.12060E-09 -9.9187 0.12060E-09 -9.9187 0.10000E+01 0.0000 55 KHSO4,aq 0.41581E-17 -17.3811 0.41581E-17 -17.3811 0.10000E+01 0.0000 56 KOH,aq 0.16149E-07 -7.7919 0.16149E-07 -7.7919 0.10000E+01 0.0000 57 KSO4- 0.17891E-07 -7.7474 0.16860E-07 -7.7731 0.94237E+00 -0.0258 58 MgCO3,aq 0.15045E-11 -11.8226 0.15045E-11 -11.8226 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.20528E-12 -12.6877 0.19348E-12 -12.7134 0.94250E+00 -0.0257 60 MgCl+ 0.13106E-12 -12.8825 0.12352E-12 -12.9082 0.94250E+00 -0.0257 61 MgOH+ 0.20026E-09 -9.6984 0.18875E-09 -9.7241 0.94250E+00 -0.0257 63 MnO,aq 0.29027E-09 -9.5372 0.29027E-09 -9.5372 0.10000E+01 0.0000 64 MnOH+ 0.12172E-08 -8.9146 0.11472E-08 -8.9404 0.94250E+00 -0.0257 65 MnO2-2 0.63144E-14 -14.1997 0.52582E-14 -14.2792 0.83273E+00 -0.0795 66 HMnO2- 0.16546E-11 -11.7813 0.15593E-11 -11.8071 0.94237E+00 -0.0258 69 MnCl+ 0.43617E-12 -12.3603 0.41109E-12 -12.3861 0.94250E+00 -0.0257 70 MnSO4,aq 0.31470E-11 -11.5021 0.31470E-11 -11.5021 0.10000E+01 0.0000 71 NaCl,aq 0.36870E-07 -7.4333 0.36870E-07 -7.4333 0.10000E+01 0.0000 72 NaOH,aq 0.27165E-06 -6.5660 0.27165E-06 -6.5660 0.10000E+01 0.0000 74 OH- 0.45302E-03 -3.3439 0.42686E-03 -3.3697 0.94225E+00 -0.0258 79 HPO3-2 0.55862E-18 -18.2529 0.46518E-18 -18.3324 0.83273E+00 -0.0795 82 H3PO4,aq 0.42473E-14 -14.3719 0.42473E-14 -14.3719 0.10000E+01 0.0000 83 H2PO4- 0.87821E-08 -8.0564 0.82766E-08 -8.0822 0.94243E+00 -0.0257 84 PO4-3 0.29412E-09 -9.5315 0.19981E-09 -9.6994 0.67933E+00 -0.1679 87 H2P2O7-2 0.64501E-17 -17.1904 0.53712E-17 -17.2699 0.83273E+00 -0.0795 88 HP2O7-3 0.11704E-14 -14.9317 0.79237E-15 -15.1011 0.67701E+00 -0.1694 89 P2O7-4 0.27543E-15 -15.5600 0.13985E-15 -15.8543 0.50777E+00 -0.2943 90 H2S,aq 0.23453E-15 -15.6298 0.23447E-15 -15.6299 0.99977E+00 -0.0001 97 SO3-2 0.14903E-14 -14.8267 0.12423E-14 -14.9058 0.83358E+00 -0.0791 98 HSO3- 0.11172E-15 -15.9519 0.10528E-15 -15.9776 0.94237E+00 -0.0258 99 HSO4- 0.29378E-10 -10.5320 0.27691E-10 -10.5577 0.94256E+00 -0.0257 Charge balance for all species = -.5874E-14 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.1435698E-08 -.8438580E-03 -.8504758E+00 0.0000 2 H2O 0.1000000E+01 0.5550847E+02 0.9999050E+06 0.0000 3 Cl- 0.1379538E-03 0.1379909E-03 0.4891716E+01 4.9825 4 SO4-- 0.2548865E-04 0.2550762E-04 0.2450065E+01 13.0640 5 HCO3- 0.1214970E-04 0.1307158E-04 0.7975139E+00 3.9274 6 HS- 0.5947768E-13 -.6522179E-10 -.2156806E-05 -4.3829 7 Al+++ 0.2074828E-23 0.2665143E-04 0.7190258E+00 2.7532 8 H4SiO4 0.3817382E-03 0.6648318E-03 0.6389439E+02 -3.4182 9 Ca++ 0.1745244E-06 0.1859682E-06 0.7452511E-02 10.8993 10 Mg++ 0.7784439E-09 0.9856750E-09 0.2396141E-04 8.5485 11 Fe++ 0.4592571E-11 0.2271442E-08 0.1268409E-03 6.3194 12 K+ 0.5430640E-04 0.5434056E-04 0.2124619E+01 4.5777 13 Na+ 0.9081187E-03 0.9120722E-03 0.2096633E+02 5.8009 14 Mn++ 0.6169899E-09 0.2129714E-08 0.1169909E-03 8.4476 15 HPO4-- 0.3979899E-06 0.4070662E-06 0.3906602E-01 11.2575 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.9905511E-02 -.8437560E-03 -.9061755E-02 0.0000000E+00 2 H2O 0.5550074E+02 0.5550177E+02 -.1024045E-02 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.4210480E-04 0.2550454E-04 0.1660027E-04 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.1660033E-04 -.6521391E-10 -.1660027E-04 0.0000000E+00 7 Al+++ 0.1953184E-02 0.2664821E-04 0.1926536E-02 0.0000000E+00 8 H4SiO4 0.6237257E-02 0.6647515E-03 0.5572506E-02 0.0000000E+00 9 Ca++ 0.7034065E-03 0.1859457E-06 0.7032206E-03 0.0000000E+00 10 Mg++ 0.4753968E-03 0.9855559E-09 0.4753958E-03 0.0000000E+00 11 Fe++ 0.4270921E-03 0.2271167E-08 0.4270899E-03 0.0000000E+00 12 K+ 0.1271762E-03 0.5433399E-04 0.7284223E-04 0.0000000E+00 13 Na+ 0.9119619E-03 0.9119619E-03 0.0000000E+00 0.0000000E+00 14 Mn++ 0.1038582E-04 0.2129457E-08 0.1038369E-04 0.0000000E+00 15 HPO4-- 0.3544628E-05 0.4070170E-06 0.3137611E-05 0.0000000E+00 Chg. balance for solid moles: -.4091E-18 Mass of aqueous solution: 0.999976E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 0.5990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) apatite-OH 0.1046E-05 -5.981 0.5254E-03 -3.280 0.8361E-01 0.1669E-03 clinochlore 0.9508E-04 -4.022 0.5285E-01 -1.277 8.411 0.2010E-01 daphnite 0.5886E-04 -4.230 0.4200E-01 -1.377 6.683 0.1273E-01 chlorite-Mn 0.2077E-05 -5.683 0.1472E-02 -2.832 0.2343 0.4692E-03 hematite 0.6640E-04 -4.178 0.1060E-01 -1.975 1.688 0.2010E-02 muscovite 0.7284E-04 -4.138 0.2901E-01 -1.537 4.617 0.1026E-01 stilbite 0.6980E-03 -3.156 0.4919 -0.308 78.28 0.2294 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.6094E+00 0.6094E+00 1.0000 -0.215 daphnite 0.3773E+00 0.3773E+00 1.0000 -0.423 chlorite-Mn 0.1331E-01 0.1331E-01 1.0000 -1.876 hematite 0.1000E+01 0.1000E+01 1.0000 0.000 muscovite 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 0.628347 g Volume = 0.275159 cm3 Porosity: 77.8026% V(tot) - V(min): 0.96444E+00 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.5990000 g log = -0.2226 Original solution: 1000.0103000 g Original solution / Rock added: 1669.47 (Water/Rock Ratio), log = 3.2226 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0203 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.1000E+01 0.9860 0.1006E+01 0.1020E+01 CO2,gas 0.3448E-05 1.0071 0.3543E-05 0.3518E-05 CH4,gas 0.4184E-16 1.0125 0.4323E-16 0.4269E-16 H2,gas 0.5792E-06 1.0005 0.5912E-06 0.5909E-06 H2S,gas 0.6342E-14 0.9960 0.6446E-14 0.6471E-14 S2,gas 0.4372E-35 1.0000 0.4461E-35 0.4461E-35 CO,gas 0.5472E-15 1.0000 0.5583E-15 0.5583E-15 SO3,gas 0.1441E-37 1.0000 0.1471E-37 0.1471E-37 SO2,gas 0.3315E-21 1.0000 0.3382E-21 0.3382E-21 HCl,gas 0.5576E-16 1.0000 0.5690E-16 0.5690E-16 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 32 apatite-OH -18.15 -18.15 0.00 0.000 -0.12132E-10 46 clinochlore 39.07 39.07 0.00 0.000 -0.12132E-10 47 daphnite 28.97 28.97 0.00 0.000 -0.42463E-10 48 chlorite-Mn 46.87 46.87 0.00 0.000 -0.48529E-10 90 hematite 12.57 12.57 0.00 0.000 0.30331E-11 120 muscovite 2.58 2.58 0.00 0.000 -0.42463E-10 163 stilbite -7.52 -7.52 0.00 0.000 -0.90992E-11 98 kaolinite -1.33 -1.33 0.00 0.000 -0.44706E+01 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -13.81 -7.15 -2.383 0.12208E+05 -5.451 3 CH4,gas 4.54 -13.52 -18.06 -4.516 0.30842E+05 -16.364 4 H2,gas 8.00 0.07 -7.93 -4.530 0.13535E+05 -6.228 5 H2S,gas -6.23 -22.12 -15.89 -7.945 0.27131E+05 -14.191 6 S2,gas -7.34 -44.38 -37.05 -5.700 0.63261E+05 -35.351 7 CO,gas 3.21 -13.74 -16.95 -5.216 0.28945E+05 -15.253 8 SO3,gas 17.12 -22.41 -39.53 -9.883 0.67499E+05 -37.833 9 SO2,gas 0.83 -22.34 -23.17 -6.179 0.39562E+05 -21.471 10 HCl,gas 5.19 -12.75 -17.94 -8.972 0.30639E+05 -16.245 11 acmite 7.71 5.25 -2.46 -0.256 0.42041E+04 15 albite-high 0.69 -1.70 -2.39 -0.184 0.40872E+04 16 albite -0.38 -1.70 -1.32 -0.101 0.22484E+04 19 spessartine 24.46 20.59 -3.86 -0.193 0.65958E+04 20 analcite 3.32 1.72 -1.60 -0.178 0.27393E+04 21 andalusite 5.00 2.09 -2.91 -0.291 0.49746E+04 22 andradite 39.01 35.01 -4.00 -0.208 0.68290E+04 23 grossular 32.73 27.95 -4.78 -0.239 0.81651E+04 26 annite 20.12 16.03 -4.09 -0.227 0.69822E+04 27 phlogopite 27.06 22.72 -4.34 -0.241 0.74155E+04 29 anorthite 12.71 9.57 -3.14 -0.242 0.53635E+04 35 aragonite 0.97 -2.91 -3.88 -1.292 0.66198E+04 36 brucite 12.57 8.55 -4.02 -0.804 0.68641E+04 37 calcite 0.81 -2.91 -3.72 -1.241 0.63556E+04 38 carnegieite-low 9.02 5.14 -3.89 -0.555 0.66378E+04 39 carnegieite-high 10.09 5.14 -4.96 -0.708 0.84648E+04 40 carpholite-Mg 8.58 7.22 -1.36 -0.091 0.23285E+04 41 carpholite-Fe 6.71 4.99 -1.72 -0.115 0.29427E+04 42 celadonite 5.34 2.21 -3.14 -0.184 0.53533E+04 43 celadonite-Fe 3.88 -0.02 -3.90 -0.229 0.66579E+04 50 chloritoid-Mg 13.20 10.64 -2.56 -0.171 0.43730E+04 51 chloritoid-Fe 9.17 8.41 -0.77 -0.051 0.13082E+04 52 chloritoid-Mn 11.40 10.54 -0.87 -0.058 0.14776E+04 54 coesite -2.38 -3.42 -1.04 -0.347 0.17795E+04 59 corundum 8.38 5.51 -2.88 -0.262 0.49121E+04 61 cristobalite -2.56 -3.42 -0.86 -0.286 0.14648E+04 63 cymrite-K 1.69 -2.92 -4.61 -0.384 0.78702E+04 65 diaspore 2.87 2.75 -0.12 -0.020 0.20582E+03 67 diopside 16.18 12.61 -3.57 -0.357 0.60958E+04 68 hedenbergite 14.21 10.38 -3.83 -0.383 0.65330E+04 75 epidote 24.67 23.33 -1.34 -0.065 0.22823E+04 76 clinozoisite 22.81 19.80 -3.00 -0.136 0.51271E+04 77 epidote-Fe 29.84 26.86 -2.98 -0.155 0.50842E+04 78 fayalite 14.05 9.22 -4.83 -0.689 0.82390E+04 83 gibbsite 4.08 2.75 -1.33 -0.189 0.22644E+04 87 greenalite 16.14 12.12 -4.02 -0.335 0.68604E+04 91 heulandite -5.83 -7.52 -1.69 -0.077 0.28938E+04 95 jadeite 4.22 1.72 -2.50 -0.250 0.42647E+04 97 kalsilite 7.58 3.91 -3.67 -0.524 0.62687E+04 99 kyanite 4.88 2.09 -2.79 -0.279 0.47605E+04 101 laumontite 2.88 2.73 -0.15 -0.010 0.25742E+03 102 lawsonite 9.62 9.57 -0.05 -0.003 0.80170E+02 103 leucite 4.12 0.49 -3.62 -0.362 0.61888E+04 105 lizardite 23.24 18.81 -4.43 -0.370 0.75723E+04 107 magnetite 20.09 18.89 -1.20 -0.098 0.20521E+04 113 margarite 17.32 15.08 -2.25 -0.090 0.38387E+04 116 microcline -2.49 -2.92 -0.44 -0.034 0.74684E+03 121 paragonite 4.24 3.81 -0.43 -0.026 0.74064E+03 122 nepheline 8.34 5.14 -3.20 -0.458 0.54701E+04 136 prehnite 19.37 17.05 -2.32 -0.137 0.39643E+04 137 prehnite-Fe 22.50 20.58 -1.92 -0.115 0.32745E+04 138 pumpellyite-Fe 46.27 43.17 -3.10 -0.069 0.52873E+04 139 pumpellyite-Mg 48.99 45.40 -3.59 -0.080 0.61348E+04 145 pyroxmangite 7.40 5.03 -2.37 -0.474 0.40455E+04 146 pyrophyllite -6.18 -8.17 -1.99 -0.124 0.33993E+04 147 quartz -2.99 -3.42 -0.43 -0.143 0.73216E+03 151 rhodochrosite -0.98 -5.36 -4.39 -1.462 0.74886E+04 152 rhodonite 7.45 5.03 -2.42 -0.483 0.41258E+04 153 sanidine -1.28 -2.92 -1.65 -0.127 0.28146E+04 155 siderite -2.61 -7.49 -4.88 -1.627 0.83362E+04 156 sillimanite 5.26 2.09 -3.17 -0.317 0.54186E+04 164 stilpnomelane-Fe 13.02 12.05 -0.97 -0.029 0.16577E+04 165 stilpnomelane-Mg 27.44 23.19 -4.25 -0.127 0.72561E+04 167 sudoite-Fe 18.30 13.40 -4.90 -0.158 0.83658E+04 168 sudoite 21.08 17.85 -3.22 -0.104 0.55022E+04 171 talc 16.49 11.97 -4.52 -0.266 0.77152E+04 174 tephroite 18.09 13.48 -4.61 -0.658 0.78694E+04 177 topaz-H 4.62 2.09 -2.53 -0.230 0.43206E+04 178 tridymite -2.63 -3.42 -0.79 -0.264 0.13521E+04 187 wairakite 3.95 2.73 -1.22 -0.072 0.20794E+04 188 walstromite 11.51 7.48 -4.03 -0.806 0.68780E+04 189 wollastonite 10.46 7.48 -2.98 -0.596 0.50885E+04 190 pseudo-wollastonite 11.00 7.48 -3.52 -0.704 0.60083E+04 191 zoisite 22.85 19.80 -3.05 -0.138 0.52011E+04 192 akaganeite 7.75 6.28 -1.47 -0.318 0.25125E+04 193 beidellite-Ca -1.65 -4.33 -2.69 -0.166 0.45864E+04 194 beidellite-H -2.33 -6.13 -3.80 -0.243 0.64949E+04 195 beidellite-K -1.52 -4.62 -3.10 -0.190 0.52918E+04 196 beidellite-Mg -1.79 -4.72 -2.93 -0.181 0.50025E+04 197 beidellite-Na -1.34 -4.22 -2.87 -0.176 0.49065E+04 199 chalcedony -2.80 -3.42 -0.62 -0.205 0.10515E+04 201 montmorillonite-Ca -2.29 -4.46 -2.17 -0.134 0.36968E+04 202 montmorillonite-K -2.24 -4.74 -2.51 -0.154 0.42803E+04 203 montmorillonite-Mg -2.48 -4.84 -2.36 -0.146 0.40361E+04 204 montmorillonite-Na -2.04 -4.34 -2.30 -0.141 0.39307E+04 205 nontronite-Ca 3.21 2.73 -0.49 -0.032 0.83044E+03 206 nontronite-H 2.53 0.93 -1.60 -0.107 0.27369E+04 207 nontronite-K 3.34 2.44 -0.90 -0.058 0.15372E+04 208 nontronite-Mg 3.07 2.34 -0.73 -0.048 0.12538E+04 209 nontronite-Na 3.52 2.84 -0.68 -0.043 0.11536E+04 224 tobermorite 9.82 5.66 -4.16 -1.136 0.71068E+04 233 boehmite 4.41 2.75 -1.65 -0.276 0.28227E+04 235 ferrous-oxide 9.81 6.32 -3.49 -0.873 0.59629E+04 240 silica-amorphous -2.09 -3.42 -1.33 -0.442 0.22656E+04 242 an20ab80 2.02 0.55 -1.46 -0.113 0.25006E+04 243 an25ab75 2.65 1.12 -1.53 -0.118 0.26106E+04 244 an30ab70 3.28 1.68 -1.60 -0.123 0.27302E+04 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 6 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 0.5990000 Water: Moles liquid = 0.5550E+02 kg liquid = 0.9999E+00 Moles total = 0.5550E+02 kg total = 0.9999E+00 Activity = 1.0000 Stoichiometric ionic strength = .7308769E-03 Osmotic coef. = 0.9842 True ionic strength = .9901863E-03 Chg. balance for total moles = -.5874E-14 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.14345E-08 -8.8433 0.13524E-08 -8.8689 0.94276E+00 -0.0256 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13795E-03 -3.8603 0.13000E-03 -3.8860 0.94236E+00 -0.0258 4 SO4-- 0.25488E-04 -4.5937 0.21228E-04 -4.6731 0.83283E+00 -0.0794 5 HCO3- 0.12149E-04 -4.9155 0.11450E-04 -4.9412 0.94246E+00 -0.0257 6 HS- 0.60038E-13 -13.2216 0.56578E-13 -13.2474 0.94237E+00 -0.0258 7 Al+++ 0.20644E-23 -23.6852 0.13975E-23 -23.8547 0.67694E+00 -0.1695 8 H4SiO4 0.38160E-03 -3.4184 0.38160E-03 -3.4184 0.10000E+01 0.0000 9 Ca++ 0.17561E-06 -6.7554 0.14618E-06 -6.8351 0.83241E+00 -0.0797 10 Mg++ 0.77819E-09 -9.1089 0.64757E-09 -9.1887 0.83214E+00 -0.0798 11 Fe++ 0.45911E-11 -11.3381 0.38207E-11 -11.4179 0.83221E+00 -0.0798 12 K+ 0.54755E-04 -4.2616 0.51606E-04 -4.2873 0.94248E+00 -0.0257 13 Na+ 0.90812E-03 -3.0419 0.85577E-03 -3.0676 0.94236E+00 -0.0258 14 Mn++ 0.61679E-09 -9.2099 0.51333E-09 -9.2896 0.83226E+00 -0.0797 15 HPO4-- 0.39349E-06 -6.4051 0.32771E-06 -6.4845 0.83284E+00 -0.0794 16 HSiO3- 0.27958E-03 -3.5535 0.26346E-03 -3.5793 0.94236E+00 -0.0258 17 Ca(HSiO3)+ 0.93063E-09 -9.0312 0.87711E-09 -9.0569 0.94249E+00 -0.0257 18 Mg(HSiO3)+ 0.51306E-11 -11.2898 0.48355E-11 -11.3156 0.94249E+00 -0.0257 19 NaHSiO3,aq 0.36466E-05 -5.4381 0.36466E-05 -5.4381 0.10000E+01 0.0000 20 AlO+ 0.11029E-12 -12.9575 0.10394E-12 -12.9832 0.94249E+00 -0.0257 21 AlOH+2 0.84100E-18 -18.0752 0.69998E-18 -18.1549 0.83231E+00 -0.0797 22 HAlO2,aq 0.15306E-07 -7.8151 0.15306E-07 -7.8151 0.10000E+01 0.0000 23 AlO2- 0.26587E-04 -4.5753 0.25052E-04 -4.6012 0.94224E+00 -0.0258 24 CH4,aq 0.29651E-19 -19.5280 0.29644E-19 -19.5281 0.99977E+00 -0.0001 29 CO,aq 0.37527E-18 -18.4257 0.37527E-18 -18.4257 0.10000E+01 0.0000 30 CO2,aq 0.33096E-07 -7.4802 0.33088E-07 -7.4803 0.99977E+00 -0.0001 31 CO3-2 0.88806E-06 -6.0516 0.73949E-06 -6.1311 0.83271E+00 -0.0795 32 CaCO3,aq 0.13555E-08 -8.8679 0.13555E-08 -8.8679 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.45332E-10 -10.3436 0.42725E-10 -10.3693 0.94249E+00 -0.0257 34 CaCl+ 0.32631E-10 -10.4864 0.30755E-10 -10.5121 0.94249E+00 -0.0257 35 CaCl2,aq 0.94988E-15 -15.0223 0.94988E-15 -15.0223 0.10000E+01 0.0000 36 CaOH+ 0.81735E-08 -8.0876 0.77035E-08 -8.1133 0.94249E+00 -0.0257 37 CaSO4,aq 0.98538E-09 -9.0064 0.98538E-09 -9.0064 0.10000E+01 0.0000 38 HCl,aq 0.32218E-13 -13.4919 0.32218E-13 -13.4919 0.10000E+01 0.0000 43 FeCl+ 0.83417E-15 -15.0787 0.78620E-15 -15.1045 0.94249E+00 -0.0257 46 FeO,aq 0.81187E-10 -10.0905 0.81187E-10 -10.0905 0.10000E+01 0.0000 47 FeOH+ 0.97571E-10 -10.0107 0.91960E-10 -10.0364 0.94249E+00 -0.0257 48 HFeO2- 0.66652E-09 -9.1762 0.62811E-09 -9.2020 0.94236E+00 -0.0258 49 FeO+ 0.10953E-13 -13.9605 0.10323E-13 -13.9862 0.94249E+00 -0.0257 51 FeO2- 0.12255E-08 -8.9117 0.11548E-08 -8.9375 0.94236E+00 -0.0258 52 HFeO2,aq 0.19864E-09 -9.7019 0.19864E-09 -9.7019 0.10000E+01 0.0000 53 H2,aq 0.45159E-09 -9.3453 0.45148E-09 -9.3454 0.99977E+00 -0.0001 54 KCl,aq 0.12159E-09 -9.9151 0.12159E-09 -9.9151 0.10000E+01 0.0000 55 KHSO4,aq 0.41889E-17 -17.3779 0.41889E-17 -17.3779 0.10000E+01 0.0000 56 KOH,aq 0.16296E-07 -7.7879 0.16296E-07 -7.7879 0.10000E+01 0.0000 57 KSO4- 0.18039E-07 -7.7438 0.16999E-07 -7.7696 0.94236E+00 -0.0258 58 MgCO3,aq 0.15051E-11 -11.8224 0.15051E-11 -11.8224 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.20519E-12 -12.6878 0.19339E-12 -12.7136 0.94249E+00 -0.0257 60 MgCl+ 0.13101E-12 -12.8827 0.12348E-12 -12.9084 0.94249E+00 -0.0257 61 MgOH+ 0.20035E-09 -9.6982 0.18883E-09 -9.7239 0.94249E+00 -0.0257 63 MnO,aq 0.29064E-09 -9.5366 0.29064E-09 -9.5366 0.10000E+01 0.0000 64 MnOH+ 0.12178E-08 -8.9144 0.11477E-08 -8.9402 0.94249E+00 -0.0257 65 MnO2-2 0.63330E-14 -14.1984 0.52736E-14 -14.2779 0.83271E+00 -0.0795 66 HMnO2- 0.16581E-11 -11.7804 0.15625E-11 -11.8062 0.94236E+00 -0.0258 69 MnCl+ 0.43602E-12 -12.3605 0.41094E-12 -12.3862 0.94249E+00 -0.0257 70 MnSO4,aq 0.31458E-11 -11.5023 0.31458E-11 -11.5023 0.10000E+01 0.0000 71 NaCl,aq 0.36869E-07 -7.4333 0.36869E-07 -7.4333 0.10000E+01 0.0000 72 NaOH,aq 0.27187E-06 -6.5656 0.27187E-06 -6.5656 0.10000E+01 0.0000 74 OH- 0.45340E-03 -3.3435 0.42721E-03 -3.3694 0.94224E+00 -0.0258 79 HPO3-2 0.55372E-18 -18.2567 0.46109E-18 -18.3362 0.83271E+00 -0.0795 82 H3PO4,aq 0.41922E-14 -14.3776 0.41922E-14 -14.3776 0.10000E+01 0.0000 83 H2PO4- 0.86755E-08 -8.0617 0.81760E-08 -8.0875 0.94243E+00 -0.0258 84 PO4-3 0.29105E-09 -9.5360 0.19770E-09 -9.7040 0.67928E+00 -0.1680 87 H2P2O7-2 0.62945E-17 -17.2010 0.52415E-17 -17.2805 0.83271E+00 -0.0795 88 HP2O7-3 0.11432E-14 -14.9419 0.77387E-15 -15.1113 0.67696E+00 -0.1694 89 P2O7-4 0.26925E-15 -15.5698 0.13670E-15 -15.8642 0.50770E+00 -0.2944 90 H2S,aq 0.23654E-15 -15.6261 0.23649E-15 -15.6262 0.99977E+00 -0.0001 97 SO3-2 0.14941E-14 -14.8256 0.12454E-14 -14.9047 0.83355E+00 -0.0791 98 HSO3- 0.11191E-15 -15.9511 0.10546E-15 -15.9769 0.94236E+00 -0.0258 99 HSO4- 0.29353E-10 -10.5323 0.27667E-10 -10.5580 0.94255E+00 -0.0257 Charge balance for all species = -.5873E-14 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.1434535E-08 -.8441728E-03 -.8507931E+00 0.0000 2 H2O 0.1000000E+01 0.5550847E+02 0.9999049E+06 0.0000 3 Cl- 0.1379538E-03 0.1379909E-03 0.4891716E+01 4.9828 4 SO4-- 0.2548850E-04 0.2550762E-04 0.2450065E+01 13.0647 5 HCO3- 0.1214902E-04 0.1307158E-04 0.7975139E+00 3.9277 6 HS- 0.6003755E-13 -.6505995E-10 -.2151454E-05 -4.3785 7 Al+++ 0.2064412E-23 0.2660277E-04 0.7177132E+00 2.7520 8 H4SiO4 0.3816011E-03 0.6648274E-03 0.6389396E+02 -3.4184 9 Ca++ 0.1756137E-06 0.1871367E-06 0.7499338E-02 10.9027 10 Mg++ 0.7781908E-09 0.9855165E-09 0.2395756E-04 8.5491 11 Fe++ 0.4591077E-11 0.2274006E-08 0.1269841E-03 6.3199 12 K+ 0.5475534E-04 0.5478979E-04 0.2142183E+01 4.5816 13 Na+ 0.9081168E-03 0.9120722E-03 0.2096633E+02 5.8012 14 Mn++ 0.6167892E-09 0.2130456E-08 0.1170316E-03 8.4482 15 HPO4-- 0.3934912E-06 0.4024578E-06 0.3862375E-01 11.2533 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.9905511E-02 -.8440708E-03 -.9061440E-02 0.0000000E+00 2 H2O 0.5550074E+02 0.5550176E+02 -.1023310E-02 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.4210480E-04 0.2550454E-04 0.1660027E-04 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.1660033E-04 -.6505208E-10 -.1660027E-04 0.0000000E+00 7 Al+++ 0.1953184E-02 0.2659956E-04 0.1926585E-02 0.0000000E+00 8 H4SiO4 0.6237257E-02 0.6647471E-03 0.5572510E-02 0.0000000E+00 9 Ca++ 0.7034065E-03 0.1871141E-06 0.7032194E-03 0.0000000E+00 10 Mg++ 0.4753968E-03 0.9853974E-09 0.4753958E-03 0.0000000E+00 11 Fe++ 0.4270921E-03 0.2273731E-08 0.4270899E-03 0.0000000E+00 12 K+ 0.1271762E-03 0.5478317E-04 0.7239305E-04 0.0000000E+00 13 Na+ 0.9119619E-03 0.9119619E-03 0.0000000E+00 0.0000000E+00 14 Mn++ 0.1038582E-04 0.2130198E-08 0.1038369E-04 0.0000000E+00 15 HPO4-- 0.3544628E-05 0.4024091E-06 0.3142219E-05 0.0000000E+00 Chg. balance for solid moles: -.8284E-18 Mass of aqueous solution: 0.999976E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 0.5990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) apatite-OH 0.1047E-05 -5.980 0.5261E-03 -3.279 0.8373E-01 0.1672E-03 clinochlore 0.9508E-04 -4.022 0.5285E-01 -1.277 8.411 0.2010E-01 daphnite 0.5886E-04 -4.230 0.4200E-01 -1.377 6.683 0.1273E-01 chlorite-Mn 0.2077E-05 -5.683 0.1472E-02 -2.832 0.2343 0.4692E-03 hematite 0.6640E-04 -4.178 0.1060E-01 -1.975 1.688 0.2010E-02 muscovite 0.7239E-04 -4.140 0.2883E-01 -1.540 4.589 0.1020E-01 stilbite 0.6980E-03 -3.156 0.4919 -0.308 78.28 0.2294 kaolinite 0.7069E-06 -6.151 0.1825E-03 -3.739 0.2905E-01 0.7022E-04 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.6094E+00 0.6094E+00 1.0000 -0.215 daphnite 0.3773E+00 0.3773E+00 1.0000 -0.423 chlorite-Mn 0.1331E-01 0.1331E-01 1.0000 -1.876 hematite 0.1000E+01 0.1000E+01 1.0000 0.000 muscovite 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 kaolinite 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 0.628346 g Volume = 0.275163 cm3 Porosity: 77.8023% V(tot) - V(min): 0.96444E+00 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.5990000 g log = -0.2226 Original solution: 1000.0103000 g Original solution / Rock added: 1669.47 (Water/Rock Ratio), log = 3.2226 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0203 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.1000E+01 0.9860 0.1006E+01 0.1020E+01 CO2,gas 0.3445E-05 1.0071 0.3540E-05 0.3515E-05 CH4,gas 0.4224E-16 1.0125 0.4363E-16 0.4309E-16 H2,gas 0.5806E-06 1.0005 0.5927E-06 0.5924E-06 H2S,gas 0.6397E-14 0.9960 0.6501E-14 0.6527E-14 S2,gas 0.4425E-35 1.0000 0.4515E-35 0.4515E-35 CO,gas 0.5481E-15 1.0000 0.5592E-15 0.5592E-15 SO3,gas 0.1439E-37 1.0000 0.1468E-37 0.1468E-37 SO2,gas 0.3318E-21 1.0000 0.3385E-21 0.3385E-21 HCl,gas 0.5572E-16 1.0000 0.5685E-16 0.5685E-16 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 32 apatite-OH -18.15 -18.15 0.00 0.000 0.60662E-11 46 clinochlore 39.07 39.07 0.00 0.000 0.00000E+00 47 daphnite 28.97 28.97 0.00 0.000 0.00000E+00 48 chlorite-Mn 46.87 46.87 0.00 0.000 -0.24265E-10 90 hematite 12.57 12.57 0.00 0.000 -0.15165E-10 98 kaolinite -1.33 -1.33 0.00 0.000 -0.18578E-10 120 muscovite 2.58 2.58 0.00 0.000 0.60662E-11 163 stilbite -7.52 -7.52 0.00 0.000 -0.90992E-11 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -13.81 -7.15 -2.383 0.12208E+05 -5.451 3 CH4,gas 4.54 -13.52 -18.06 -4.515 0.30835E+05 -16.360 4 H2,gas 8.00 0.07 -7.93 -4.529 0.13534E+05 -6.227 5 H2S,gas -6.23 -22.12 -15.89 -7.943 0.27125E+05 -14.187 6 S2,gas -7.34 -44.38 -37.04 -5.699 0.63252E+05 -35.345 7 CO,gas 3.21 -13.74 -16.95 -5.216 0.28944E+05 -15.252 8 SO3,gas 17.12 -22.41 -39.53 -9.883 0.67500E+05 -37.833 9 SO2,gas 0.83 -22.34 -23.17 -6.178 0.39561E+05 -21.470 10 HCl,gas 5.19 -12.75 -17.94 -8.972 0.30639E+05 -16.245 11 acmite 7.71 5.25 -2.46 -0.256 0.42041E+04 15 albite-high 0.69 -1.70 -2.39 -0.184 0.40894E+04 16 albite -0.38 -1.70 -1.32 -0.101 0.22505E+04 19 spessartine 24.46 20.59 -3.86 -0.193 0.65977E+04 20 analcite 3.32 1.72 -1.61 -0.178 0.27412E+04 21 andalusite 5.00 2.09 -2.92 -0.292 0.49788E+04 22 andradite 39.01 35.02 -3.99 -0.207 0.68124E+04 23 grossular 32.73 27.96 -4.77 -0.239 0.81525E+04 26 annite 20.12 16.04 -4.09 -0.227 0.69754E+04 27 phlogopite 27.06 22.73 -4.34 -0.241 0.74087E+04 29 anorthite 12.71 9.57 -3.14 -0.242 0.53622E+04 35 aragonite 0.97 -2.91 -3.87 -1.291 0.66146E+04 36 brucite 12.57 8.55 -4.02 -0.804 0.68632E+04 37 calcite 0.81 -2.91 -3.72 -1.240 0.63504E+04 38 carnegieite-low 9.02 5.13 -3.89 -0.555 0.66394E+04 39 carnegieite-high 10.09 5.13 -4.96 -0.708 0.84664E+04 40 carpholite-Mg 8.58 7.22 -1.37 -0.091 0.23321E+04 41 carpholite-Fe 6.71 4.99 -1.73 -0.115 0.29462E+04 42 celadonite 5.34 2.21 -3.13 -0.184 0.53487E+04 43 celadonite-Fe 3.88 -0.02 -3.90 -0.229 0.66533E+04 50 chloritoid-Mg 13.20 10.63 -2.56 -0.171 0.43763E+04 51 chloritoid-Fe 9.17 8.41 -0.77 -0.051 0.13115E+04 52 chloritoid-Mn 11.40 10.53 -0.87 -0.058 0.14809E+04 54 coesite -2.38 -3.42 -1.04 -0.347 0.17797E+04 59 corundum 8.38 5.50 -2.88 -0.262 0.49160E+04 61 cristobalite -2.56 -3.42 -0.86 -0.286 0.14651E+04 63 cymrite-K 1.69 -2.92 -4.61 -0.384 0.78663E+04 65 diaspore 2.87 2.75 -0.12 -0.020 0.20778E+03 67 diopside 16.18 12.61 -3.57 -0.357 0.60895E+04 68 hedenbergite 14.21 10.39 -3.82 -0.382 0.65268E+04 75 epidote 24.67 23.34 -1.33 -0.065 0.22755E+04 76 clinozoisite 22.81 19.81 -3.00 -0.136 0.51222E+04 77 epidote-Fe 29.84 26.87 -2.97 -0.154 0.50754E+04 78 fayalite 14.05 9.22 -4.82 -0.689 0.82373E+04 83 gibbsite 4.08 2.75 -1.33 -0.190 0.22663E+04 87 greenalite 16.14 12.12 -4.02 -0.335 0.68581E+04 91 heulandite -5.83 -7.52 -1.69 -0.077 0.28938E+04 95 jadeite 4.22 1.72 -2.50 -0.250 0.42667E+04 97 kalsilite 7.58 3.92 -3.67 -0.524 0.62642E+04 99 kyanite 4.88 2.09 -2.79 -0.279 0.47647E+04 101 laumontite 2.88 2.73 -0.15 -0.010 0.25662E+03 102 lawsonite 9.62 9.57 -0.05 -0.003 0.78838E+02 103 leucite 4.12 0.50 -3.62 -0.362 0.61846E+04 105 lizardite 23.24 18.81 -4.43 -0.369 0.75700E+04 107 magnetite 20.09 18.89 -1.20 -0.098 0.20512E+04 113 margarite 17.32 15.07 -2.25 -0.090 0.38413E+04 116 microcline -2.49 -2.92 -0.44 -0.033 0.74290E+03 121 paragonite 4.24 3.80 -0.44 -0.026 0.74675E+03 122 nepheline 8.34 5.13 -3.20 -0.458 0.54718E+04 136 prehnite 19.37 17.05 -2.32 -0.136 0.39574E+04 137 prehnite-Fe 22.50 20.59 -1.91 -0.115 0.32657E+04 138 pumpellyite-Fe 46.27 43.18 -3.09 -0.069 0.52746E+04 139 pumpellyite-Mg 48.99 45.41 -3.59 -0.080 0.61221E+04 145 pyroxmangite 7.40 5.03 -2.37 -0.474 0.40448E+04 146 pyrophyllite -6.18 -8.17 -1.99 -0.125 0.34043E+04 147 quartz -2.99 -3.42 -0.43 -0.143 0.73243E+03 151 rhodochrosite -0.98 -5.36 -4.39 -1.462 0.74883E+04 152 rhodonite 7.45 5.03 -2.42 -0.483 0.41251E+04 153 sanidine -1.28 -2.92 -1.65 -0.127 0.28106E+04 155 siderite -2.61 -7.49 -4.88 -1.627 0.83359E+04 156 sillimanite 5.26 2.09 -3.18 -0.318 0.54228E+04 164 stilpnomelane-Fe 13.02 12.05 -0.97 -0.029 0.16557E+04 165 stilpnomelane-Mg 27.44 23.19 -4.25 -0.127 0.72541E+04 167 sudoite-Fe 18.30 13.39 -4.90 -0.158 0.83726E+04 168 sudoite 21.08 17.85 -3.23 -0.104 0.55090E+04 171 talc 16.49 11.97 -4.52 -0.266 0.77134E+04 174 tephroite 18.09 13.48 -4.61 -0.658 0.78678E+04 177 topaz-H 4.62 2.09 -2.53 -0.230 0.43248E+04 178 tridymite -2.63 -3.42 -0.79 -0.264 0.13524E+04 187 wairakite 3.95 2.73 -1.22 -0.072 0.20786E+04 188 walstromite 11.51 7.48 -4.02 -0.805 0.68725E+04 189 wollastonite 10.46 7.48 -2.98 -0.595 0.50829E+04 190 pseudo-wollastonite 11.00 7.48 -3.52 -0.703 0.60028E+04 191 zoisite 22.85 19.81 -3.04 -0.138 0.51962E+04 192 akaganeite 7.75 6.28 -1.47 -0.318 0.25125E+04 193 beidellite-Ca -1.65 -4.33 -2.69 -0.166 0.45910E+04 194 beidellite-H -2.33 -6.13 -3.81 -0.243 0.65005E+04 195 beidellite-K -1.52 -4.62 -3.10 -0.190 0.52952E+04 196 beidellite-Mg -1.79 -4.72 -2.93 -0.181 0.50079E+04 197 beidellite-Na -1.34 -4.22 -2.88 -0.176 0.49118E+04 199 chalcedony -2.80 -3.42 -0.62 -0.205 0.10517E+04 201 montmorillonite-Ca -2.29 -4.46 -2.17 -0.134 0.36999E+04 202 montmorillonite-K -2.24 -4.74 -2.51 -0.154 0.42821E+04 203 montmorillonite-Mg -2.48 -4.85 -2.37 -0.146 0.40400E+04 204 montmorillonite-Na -2.04 -4.34 -2.30 -0.141 0.39346E+04 205 nontronite-Ca 3.21 2.73 -0.49 -0.032 0.83111E+03 206 nontronite-H 2.53 0.93 -1.60 -0.107 0.27385E+04 207 nontronite-K 3.34 2.44 -0.90 -0.058 0.15366E+04 208 nontronite-Mg 3.07 2.34 -0.74 -0.048 0.12553E+04 209 nontronite-Na 3.52 2.84 -0.68 -0.043 0.11550E+04 224 tobermorite 9.82 5.66 -4.16 -1.135 0.71023E+04 233 boehmite 4.41 2.75 -1.65 -0.276 0.28247E+04 235 ferrous-oxide 9.81 6.32 -3.49 -0.873 0.59619E+04 240 silica-amorphous -2.09 -3.42 -1.33 -0.442 0.22659E+04 242 an20ab80 2.02 0.55 -1.47 -0.113 0.25020E+04 243 an25ab75 2.65 1.12 -1.53 -0.118 0.26119E+04 244 an30ab70 3.28 1.68 -1.60 -0.123 0.27313E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 0.0200000 g Current total amount of reactant added: 0.5990000 g New total amount of reactant added: 0.6190000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.5872E-14 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 7 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 0.6190000 Water: Moles liquid = 0.5550E+02 kg liquid = 0.9999E+00 Moles total = 0.5550E+02 kg total = 0.9999E+00 Activity = 1.0000 Stoichiometric ionic strength = .7428282E-03 Osmotic coef. = 0.9840 True ionic strength = .1013905E-02 Chg. balance for total moles = -.5872E-14 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.14043E-08 -8.8526 0.13233E-08 -8.8784 0.94233E+00 -0.0258 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13795E-03 -3.8603 0.12994E-03 -3.8863 0.94192E+00 -0.0260 4 SO4-- 0.25489E-04 -4.5936 0.21188E-04 -4.6739 0.83127E+00 -0.0803 5 HCO3- 0.12131E-04 -4.9161 0.11427E-04 -4.9421 0.94202E+00 -0.0259 6 HS- 0.56463E-13 -13.2482 0.53184E-13 -13.2742 0.94193E+00 -0.0260 7 Al+++ 0.18961E-23 -23.7221 0.12781E-23 -23.8934 0.67408E+00 -0.1713 8 H4SiO4 0.39082E-03 -3.4080 0.39082E-03 -3.4080 0.10000E+01 0.0000 9 Ca++ 0.14948E-06 -6.8254 0.12420E-06 -6.9059 0.83084E+00 -0.0805 10 Mg++ 0.74285E-09 -9.1291 0.61699E-09 -9.2097 0.83057E+00 -0.0806 11 Fe++ 0.43826E-11 -11.3583 0.36403E-11 -11.4389 0.83064E+00 -0.0806 12 K+ 0.53600E-04 -4.2708 0.50493E-04 -4.2968 0.94203E+00 -0.0259 13 Na+ 0.93294E-03 -3.0301 0.87875E-03 -3.0561 0.94191E+00 -0.0260 14 Mn++ 0.58878E-09 -9.2300 0.48909E-09 -9.3106 0.83069E+00 -0.0806 15 HPO4-- 0.50247E-06 -6.2989 0.41769E-06 -6.3791 0.83128E+00 -0.0803 16 HSiO3- 0.29278E-03 -3.5335 0.27578E-03 -3.5594 0.94192E+00 -0.0260 17 Ca(HSiO3)+ 0.82800E-09 -9.0820 0.78001E-09 -9.1079 0.94205E+00 -0.0259 18 Mg(HSiO3)+ 0.51192E-11 -11.2908 0.48225E-11 -11.3167 0.94205E+00 -0.0259 19 NaHSiO3,aq 0.39195E-05 -5.4068 0.39195E-05 -5.4068 0.10000E+01 0.0000 20 AlO+ 0.10541E-12 -12.9771 0.99302E-13 -13.0030 0.94205E+00 -0.0259 21 AlOH+2 0.78761E-18 -18.1037 0.65431E-18 -18.1842 0.83074E+00 -0.0805 22 HAlO2,aq 0.14945E-07 -7.8255 0.14945E-07 -7.8255 0.10000E+01 0.0000 23 AlO2- 0.26545E-04 -4.5760 0.25000E-04 -4.6021 0.94180E+00 -0.0260 24 CH4,aq 0.27868E-19 -19.5549 0.27862E-19 -19.5550 0.99977E+00 -0.0001 29 CO,aq 0.36297E-18 -18.4401 0.36297E-18 -18.4401 0.10000E+01 0.0000 30 CO2,aq 0.32318E-07 -7.4906 0.32310E-07 -7.4907 0.99977E+00 -0.0001 31 CO3-2 0.90752E-06 -6.0421 0.75428E-06 -6.1225 0.83115E+00 -0.0803 32 CaCO3,aq 0.11746E-08 -8.9301 0.11746E-08 -8.9301 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.38455E-10 -10.4150 0.36227E-10 -10.4410 0.94205E+00 -0.0259 34 CaCl+ 0.27723E-10 -10.5572 0.26116E-10 -10.5831 0.94205E+00 -0.0259 35 CaCl2,aq 0.80624E-15 -15.0935 0.80624E-15 -15.0935 0.10000E+01 0.0000 36 CaOH+ 0.71005E-08 -8.1487 0.66890E-08 -8.1746 0.94205E+00 -0.0259 37 CaSO4,aq 0.83563E-09 -9.0780 0.83563E-09 -9.0780 0.10000E+01 0.0000 38 HCl,aq 0.31508E-13 -13.5016 0.31508E-13 -13.5016 0.10000E+01 0.0000 43 FeCl+ 0.79478E-15 -15.0998 0.74872E-15 -15.1257 0.94205E+00 -0.0259 46 FeO,aq 0.80800E-10 -10.0926 0.80800E-10 -10.0926 0.10000E+01 0.0000 47 FeOH+ 0.95057E-10 -10.0220 0.89548E-10 -10.0479 0.94205E+00 -0.0259 48 HFeO2- 0.67828E-09 -9.1686 0.63889E-09 -9.1946 0.94192E+00 -0.0260 49 FeO+ 0.10722E-13 -13.9697 0.10100E-13 -13.9957 0.94205E+00 -0.0259 51 FeO2- 0.12531E-08 -8.9020 0.11803E-08 -8.9280 0.94192E+00 -0.0260 52 HFeO2,aq 0.19864E-09 -9.7019 0.19864E-09 -9.7019 0.10000E+01 0.0000 53 H2,aq 0.44729E-09 -9.3494 0.44719E-09 -9.3495 0.99977E+00 -0.0001 54 KCl,aq 0.11891E-09 -9.9248 0.11891E-09 -9.9248 0.10000E+01 0.0000 55 KHSO4,aq 0.40028E-17 -17.3976 0.40028E-17 -17.3976 0.10000E+01 0.0000 56 KOH,aq 0.16296E-07 -7.7879 0.16296E-07 -7.7879 0.10000E+01 0.0000 57 KSO4- 0.17625E-07 -7.7539 0.16602E-07 -7.7798 0.94192E+00 -0.0260 58 MgCO3,aq 0.14627E-11 -11.8348 0.14627E-11 -11.8348 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.19521E-12 -12.7095 0.18390E-12 -12.7354 0.94205E+00 -0.0259 60 MgCl+ 0.12483E-12 -12.9037 0.11759E-12 -12.9296 0.94205E+00 -0.0259 61 MgOH+ 0.19519E-09 -9.7095 0.18388E-09 -9.7355 0.94205E+00 -0.0259 63 MnO,aq 0.28926E-09 -9.5387 0.28926E-09 -9.5387 0.10000E+01 0.0000 64 MnOH+ 0.11864E-08 -8.9258 0.11177E-08 -8.9517 0.94205E+00 -0.0259 65 MnO2-2 0.65961E-14 -14.1807 0.54823E-14 -14.2610 0.83115E+00 -0.0803 66 HMnO2- 0.16874E-11 -11.7728 0.15894E-11 -11.7988 0.94192E+00 -0.0260 69 MnCl+ 0.41543E-12 -12.3815 0.39136E-12 -12.4074 0.94205E+00 -0.0259 70 MnSO4,aq 0.29918E-11 -11.5241 0.29918E-11 -11.5241 0.10000E+01 0.0000 71 NaCl,aq 0.37841E-07 -7.4220 0.37841E-07 -7.4220 0.10000E+01 0.0000 72 NaOH,aq 0.28532E-06 -6.5447 0.28532E-06 -6.5447 0.10000E+01 0.0000 74 OH- 0.46361E-03 -3.3338 0.43663E-03 -3.3599 0.94180E+00 -0.0260 79 HPO3-2 0.70035E-18 -18.1547 0.58210E-18 -18.2350 0.83115E+00 -0.0803 82 H3PO4,aq 0.51153E-14 -14.2911 0.51153E-14 -14.2911 0.10000E+01 0.0000 83 H2PO4- 0.10824E-07 -7.9656 0.10196E-07 -7.9916 0.94198E+00 -0.0260 84 PO4-3 0.38071E-09 -9.4194 0.25754E-09 -9.5892 0.67646E+00 -0.1698 87 H2P2O7-2 0.98078E-17 -17.0084 0.81517E-17 -17.0888 0.83115E+00 -0.0803 88 HP2O7-3 0.18247E-14 -14.7388 0.12301E-14 -14.9101 0.67410E+00 -0.1713 89 P2O7-4 0.44069E-15 -15.3559 0.22207E-15 -15.6535 0.50391E+00 -0.2976 90 H2S,aq 0.21756E-15 -15.6624 0.21751E-15 -15.6625 0.99977E+00 -0.0001 97 SO3-2 0.14799E-14 -14.8298 0.12313E-14 -14.9096 0.83201E+00 -0.0799 98 HSO3- 0.10831E-15 -15.9653 0.10202E-15 -15.9913 0.94192E+00 -0.0260 99 HSO4- 0.28681E-10 -10.5424 0.27021E-10 -10.5683 0.94211E+00 -0.0259 Charge balance for all species = -.5873E-14 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.1404257E-08 -.8677205E-03 -.8745232E+00 0.0000 2 H2O 0.1000000E+01 0.5550847E+02 0.9999022E+06 0.0000 3 Cl- 0.1379534E-03 0.1379914E-03 0.4891722E+01 4.9921 4 SO4-- 0.2548916E-04 0.2550772E-04 0.2450069E+01 13.0828 5 HCO3- 0.1213057E-04 0.1307163E-04 0.7975149E+00 3.9363 6 HS- 0.5646326E-13 -.6958602E-10 -.2301120E-05 -4.3959 7 Al+++ 0.1896117E-23 0.2655965E-04 0.7165480E+00 2.7416 8 H4SiO4 0.3908240E-03 0.6875283E-03 0.6607548E+02 -3.4080 9 Ca++ 0.1494812E-06 0.1594861E-06 0.6391248E-02 10.8508 10 Mg++ 0.7428498E-09 0.9449436E-09 0.2297118E-04 8.5470 11 Fe++ 0.4382569E-11 0.2310255E-08 0.1290080E-03 6.3178 12 K+ 0.5360002E-04 0.5363406E-04 0.2096990E+01 4.5816 13 Na+ 0.9329410E-03 0.9371836E-03 0.2154352E+02 5.8222 14 Mn++ 0.5887835E-09 0.2069563E-08 0.1136863E-03 8.4461 15 HPO4-- 0.5024695E-06 0.5136744E-06 0.4929705E-01 11.3776 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.1023668E-01 -.8676124E-03 -.9369069E-02 0.0000000E+00 2 H2O 0.5550049E+02 0.5550155E+02 -.1060376E-02 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.4265907E-04 0.2550454E-04 0.1715453E-04 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.1715460E-04 -.6957735E-10 -.1715453E-04 0.0000000E+00 7 Al+++ 0.2018399E-02 0.2655634E-04 0.1991843E-02 0.0000000E+00 8 H4SiO4 0.6445513E-02 0.6874426E-03 0.5758070E-02 0.0000000E+00 9 Ca++ 0.7264094E-03 0.1594662E-06 0.7262499E-03 0.0000000E+00 10 Mg++ 0.4912698E-03 0.9448258E-09 0.4912689E-03 0.0000000E+00 11 Fe++ 0.4413523E-03 0.2309967E-08 0.4413500E-03 0.0000000E+00 12 K+ 0.1314225E-03 0.5362738E-04 0.7779513E-04 0.0000000E+00 13 Na+ 0.9370668E-03 0.9370668E-03 0.0000000E+00 0.0000000E+00 14 Mn++ 0.1073259E-04 0.2069305E-08 0.1073052E-04 0.0000000E+00 15 HPO4-- 0.3662980E-05 0.5136103E-06 0.3149370E-05 0.0000000E+00 Chg. balance for solid moles: 0.6209E-18 Mass of aqueous solution: 0.999975E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 0.6190000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) apatite-OH 0.1050E-05 -5.979 0.5273E-03 -3.278 0.8121E-01 0.1676E-03 clinochlore 0.9825E-04 -4.008 0.5461E-01 -1.263 8.411 0.2077E-01 daphnite 0.6082E-04 -4.216 0.4340E-01 -1.363 6.683 0.1315E-01 chlorite-Mn 0.2146E-05 -5.668 0.1522E-02 -2.818 0.2343 0.4849E-03 hematite 0.6862E-04 -4.164 0.1096E-01 -1.960 1.688 0.2077E-02 kaolinite -.2995E-05 1.000 -.7732E-03 1.000 -.1191 -.2975E-03 muscovite 0.7780E-04 -4.109 0.3099E-01 -1.509 4.772 0.1096E-01 stilbite 0.7210E-03 -3.142 0.5081 -0.294 78.25 0.2370 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.6094E+00 0.6094E+00 1.0000 -0.215 daphnite 0.3773E+00 0.3773E+00 1.0000 -0.423 chlorite-Mn 0.1331E-01 0.1331E-01 1.0000 -1.876 hematite 0.1000E+01 0.1000E+01 1.0000 0.000 kaolinite 0.1000E+01 0.1000E+01 1.0000 0.000 muscovite 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 0.649334 g Volume = 0.284302 cm3 Porosity: 77.2121% V(tot) - V(min): 0.96330E+00 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.6190000 g log = -0.2083 Original solution: 1000.0103000 g Original solution / Rock added: 1615.53 (Water/Rock Ratio), log = 3.2083 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0203 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.1000E+01 0.9860 0.1006E+01 0.1020E+01 CO2,gas 0.3364E-05 1.0071 0.3457E-05 0.3433E-05 CH4,gas 0.3970E-16 1.0125 0.4101E-16 0.4050E-16 H2,gas 0.5751E-06 1.0005 0.5871E-06 0.5868E-06 H2S,gas 0.5884E-14 0.9960 0.5979E-14 0.6003E-14 S2,gas 0.3816E-35 1.0000 0.3893E-35 0.3893E-35 CO,gas 0.5301E-15 1.0000 0.5409E-15 0.5409E-15 SO3,gas 0.1375E-37 1.0000 0.1403E-37 0.1403E-37 SO2,gas 0.3141E-21 1.0000 0.3204E-21 0.3204E-21 HCl,gas 0.5449E-16 1.0000 0.5560E-16 0.5560E-16 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 32 apatite-OH -18.15 -18.15 0.00 0.000 -0.12132E-10 46 clinochlore 39.07 39.07 0.00 0.000 -0.24265E-10 47 daphnite 28.97 28.97 0.00 0.000 -0.24265E-10 48 chlorite-Mn 46.87 46.87 0.00 0.000 -0.24265E-10 90 hematite 12.57 12.57 0.00 0.000 -0.21232E-10 120 muscovite 2.58 2.58 0.00 0.000 0.60662E-11 163 stilbite -7.52 -7.52 0.00 0.000 -0.90992E-11 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -13.82 -7.16 -2.387 0.12226E+05 -5.461 3 CH4,gas 4.54 -13.54 -18.09 -4.522 0.30881E+05 -16.387 4 H2,gas 8.00 0.07 -7.93 -4.532 0.13541E+05 -6.231 5 H2S,gas -6.23 -22.15 -15.92 -7.961 0.27187E+05 -14.223 6 S2,gas -7.34 -44.44 -37.11 -5.709 0.63362E+05 -35.410 7 CO,gas 3.21 -13.75 -16.97 -5.220 0.28969E+05 -15.267 8 SO3,gas 17.12 -22.43 -39.55 -9.888 0.67534E+05 -37.853 9 SO2,gas 0.83 -22.36 -23.19 -6.185 0.39602E+05 -21.494 10 HCl,gas 5.19 -12.76 -17.95 -8.977 0.30656E+05 -16.255 11 acmite 7.71 5.29 -2.42 -0.251 0.41328E+04 15 albite-high 0.69 -1.66 -2.35 -0.181 0.40181E+04 16 albite -0.38 -1.66 -1.28 -0.098 0.21793E+04 19 spessartine 24.46 20.60 -3.86 -0.193 0.65906E+04 20 analcite 3.32 1.75 -1.57 -0.175 0.26876E+04 21 andalusite 5.00 2.08 -2.93 -0.293 0.49965E+04 22 andradite 39.01 34.89 -4.11 -0.214 0.70249E+04 23 grossular 32.73 27.81 -4.92 -0.246 0.84004E+04 26 annite 20.12 16.05 -4.07 -0.226 0.69506E+04 27 phlogopite 27.06 22.74 -4.32 -0.240 0.73839E+04 29 anorthite 12.71 9.52 -3.19 -0.246 0.54507E+04 35 aragonite 0.97 -2.97 -3.94 -1.312 0.67208E+04 36 brucite 12.57 8.55 -4.02 -0.804 0.68667E+04 37 calcite 0.81 -2.97 -3.78 -1.260 0.64566E+04 38 carnegieite-low 9.02 5.16 -3.87 -0.552 0.66036E+04 39 carnegieite-high 10.09 5.16 -4.94 -0.705 0.84306E+04 40 carpholite-Mg 8.58 7.21 -1.37 -0.091 0.23356E+04 41 carpholite-Fe 6.71 4.99 -1.73 -0.115 0.29498E+04 42 celadonite 5.34 2.24 -3.10 -0.183 0.52991E+04 43 celadonite-Fe 3.88 0.01 -3.87 -0.228 0.66037E+04 50 chloritoid-Mg 13.20 10.62 -2.58 -0.172 0.43975E+04 51 chloritoid-Fe 9.17 8.39 -0.78 -0.052 0.13327E+04 52 chloritoid-Mn 11.40 10.52 -0.88 -0.059 0.15021E+04 54 coesite -2.38 -3.41 -1.03 -0.344 0.17620E+04 59 corundum 8.38 5.48 -2.90 -0.264 0.49514E+04 61 cristobalite -2.56 -3.41 -0.85 -0.283 0.14474E+04 63 cymrite-K 1.69 -2.90 -4.59 -0.382 0.78309E+04 65 diaspore 2.87 2.74 -0.13 -0.022 0.22549E+03 67 diopside 16.18 12.58 -3.60 -0.360 0.61462E+04 68 hedenbergite 14.21 10.35 -3.86 -0.386 0.65834E+04 75 epidote 24.67 23.24 -1.43 -0.069 0.24348E+04 76 clinozoisite 22.81 19.70 -3.10 -0.141 0.52992E+04 77 epidote-Fe 29.84 26.79 -3.06 -0.159 0.52170E+04 78 fayalite 14.05 9.23 -4.82 -0.688 0.82267E+04 83 gibbsite 4.08 2.74 -1.34 -0.191 0.22840E+04 87 greenalite 16.14 12.14 -4.00 -0.334 0.68333E+04 91 heulandite -5.83 -7.52 -1.69 -0.077 0.28938E+04 95 jadeite 4.22 1.75 -2.47 -0.247 0.42131E+04 97 kalsilite 7.58 3.92 -3.67 -0.524 0.62642E+04 98 kaolinite -1.33 -1.33 0.00 0.000 0.56870E-11 99 kyanite 4.88 2.08 -2.80 -0.280 0.47824E+04 101 laumontite 2.88 2.70 -0.18 -0.012 0.30975E+03 102 lawsonite 9.62 9.52 -0.10 -0.007 0.16738E+03 103 leucite 4.12 0.51 -3.61 -0.361 0.61668E+04 105 lizardite 23.24 18.82 -4.42 -0.368 0.75452E+04 107 magnetite 20.09 18.88 -1.20 -0.098 0.20547E+04 113 margarite 17.32 15.00 -2.32 -0.093 0.39653E+04 116 microcline -2.49 -2.90 -0.41 -0.032 0.70748E+03 121 paragonite 4.24 3.82 -0.42 -0.024 0.71094E+03 122 nepheline 8.34 5.16 -3.18 -0.455 0.54360E+04 136 prehnite 19.37 16.96 -2.41 -0.142 0.41168E+04 137 prehnite-Fe 22.50 20.50 -2.00 -0.120 0.34074E+04 138 pumpellyite-Fe 46.27 42.98 -3.29 -0.073 0.56146E+04 139 pumpellyite-Mg 48.99 45.21 -3.78 -0.084 0.64621E+04 145 pyroxmangite 7.40 5.04 -2.36 -0.472 0.40307E+04 146 pyrophyllite -6.18 -8.15 -1.97 -0.123 0.33689E+04 147 quartz -2.99 -3.41 -0.42 -0.140 0.71472E+03 151 rhodochrosite -0.98 -5.37 -4.40 -1.466 0.75095E+04 152 rhodonite 7.45 5.04 -2.41 -0.482 0.41109E+04 153 sanidine -1.28 -2.90 -1.63 -0.125 0.27752E+04 155 siderite -2.61 -7.50 -4.89 -1.631 0.83571E+04 156 sillimanite 5.26 2.08 -3.19 -0.319 0.54405E+04 164 stilpnomelane-Fe 13.02 12.10 -0.92 -0.027 0.15672E+04 165 stilpnomelane-Mg 27.44 23.24 -4.20 -0.125 0.71655E+04 167 sudoite-Fe 18.30 13.38 -4.92 -0.159 0.83974E+04 168 sudoite 21.08 17.84 -3.24 -0.105 0.55338E+04 171 talc 16.49 12.01 -4.48 -0.264 0.76532E+04 174 tephroite 18.09 13.48 -4.60 -0.657 0.78571E+04 177 topaz-H 4.62 2.08 -2.54 -0.231 0.43425E+04 178 tridymite -2.63 -3.41 -0.78 -0.261 0.13347E+04 187 wairakite 3.95 2.70 -1.25 -0.073 0.21317E+04 188 walstromite 11.51 7.44 -4.07 -0.813 0.69433E+04 189 wollastonite 10.46 7.44 -3.02 -0.604 0.51538E+04 190 pseudo-wollastonite 11.00 7.44 -3.56 -0.711 0.60736E+04 191 zoisite 22.85 19.70 -3.15 -0.143 0.53733E+04 192 akaganeite 7.75 6.28 -1.47 -0.318 0.25125E+04 193 beidellite-Ca -1.65 -4.33 -2.68 -0.166 0.45819E+04 194 beidellite-H -2.33 -6.12 -3.79 -0.242 0.64768E+04 195 beidellite-K -1.52 -4.61 -3.09 -0.189 0.52714E+04 196 beidellite-Mg -1.79 -4.71 -2.92 -0.181 0.49848E+04 197 beidellite-Na -1.34 -4.20 -2.86 -0.175 0.48763E+04 199 chalcedony -2.80 -3.41 -0.61 -0.202 0.10340E+04 201 montmorillonite-Ca -2.29 -4.44 -2.15 -0.133 0.36744E+04 202 montmorillonite-K -2.24 -4.72 -2.48 -0.152 0.42420E+04 203 montmorillonite-Mg -2.48 -4.82 -2.34 -0.145 0.40005E+04 204 montmorillonite-Na -2.04 -4.31 -2.27 -0.139 0.38826E+04 205 nontronite-Ca 3.21 2.75 -0.46 -0.030 0.78657E+03 206 nontronite-H 2.53 0.96 -1.57 -0.105 0.26794E+04 207 nontronite-K 3.34 2.48 -0.87 -0.056 0.14774E+04 208 nontronite-Mg 3.07 2.37 -0.70 -0.045 0.11967E+04 209 nontronite-Na 3.52 2.88 -0.63 -0.041 0.10840E+04 224 tobermorite 9.82 5.63 -4.19 -1.144 0.71583E+04 233 boehmite 4.41 2.74 -1.66 -0.277 0.28424E+04 235 ferrous-oxide 9.81 6.32 -3.49 -0.873 0.59655E+04 240 silica-amorphous -2.09 -3.41 -1.32 -0.439 0.22482E+04 242 an20ab80 2.02 0.58 -1.44 -0.111 0.24627E+04 243 an25ab75 2.65 1.13 -1.51 -0.116 0.25806E+04 244 an30ab70 3.28 1.69 -1.59 -0.122 0.27080E+04 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 6 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 0.6190000 Water: Moles liquid = 0.5550E+02 kg liquid = 0.9999E+00 Moles total = 0.5550E+02 kg total = 0.9999E+00 Activity = 1.0000 Stoichiometric ionic strength = .7428029E-03 Osmotic coef. = 0.9840 True ionic strength = .1015784E-02 Chg. balance for total moles = -.5872E-14 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.13996E-08 -8.8540 0.13188E-08 -8.8798 0.94229E+00 -0.0258 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13795E-03 -3.8603 0.12994E-03 -3.8863 0.94188E+00 -0.0260 4 SO4-- 0.25489E-04 -4.5937 0.21185E-04 -4.6740 0.83115E+00 -0.0803 5 HCO3- 0.12128E-04 -4.9162 0.11424E-04 -4.9422 0.94198E+00 -0.0260 6 HS- 0.58736E-13 -13.2311 0.55323E-13 -13.2571 0.94189E+00 -0.0260 7 Al+++ 0.18567E-23 -23.7313 0.12512E-23 -23.9027 0.67385E+00 -0.1714 8 H4SiO4 0.39026E-03 -3.4086 0.39026E-03 -3.4086 0.10000E+01 0.0000 9 Ca++ 0.15343E-06 -6.8141 0.12746E-06 -6.8946 0.83072E+00 -0.0805 10 Mg++ 0.74196E-09 -9.1296 0.61616E-09 -9.2103 0.83045E+00 -0.0807 11 Fe++ 0.43773E-11 -11.3588 0.36354E-11 -11.4394 0.83051E+00 -0.0807 12 K+ 0.55497E-04 -4.2557 0.52278E-04 -4.2817 0.94200E+00 -0.0259 13 Na+ 0.93293E-03 -3.0301 0.87871E-03 -3.0562 0.94187E+00 -0.0260 14 Mn++ 0.58808E-09 -9.2306 0.48843E-09 -9.3112 0.83056E+00 -0.0806 15 HPO4-- 0.47914E-06 -6.3195 0.39824E-06 -6.3999 0.83116E+00 -0.0803 16 HSiO3- 0.29336E-03 -3.5326 0.27631E-03 -3.5586 0.94188E+00 -0.0260 17 Ca(HSiO3)+ 0.85140E-09 -9.0699 0.80203E-09 -9.0958 0.94201E+00 -0.0259 18 Mg(HSiO3)+ 0.51222E-11 -11.2905 0.48252E-11 -11.3165 0.94201E+00 -0.0259 19 NaHSiO3,aq 0.39268E-05 -5.4060 0.39268E-05 -5.4060 0.10000E+01 0.0000 20 AlO+ 0.10389E-12 -12.9834 0.97861E-13 -13.0094 0.94201E+00 -0.0259 21 AlOH+2 0.77370E-18 -18.1114 0.64265E-18 -18.1920 0.83062E+00 -0.0806 22 HAlO2,aq 0.14777E-07 -7.8304 0.14777E-07 -7.8304 0.10000E+01 0.0000 23 AlO2- 0.26337E-04 -4.5794 0.24803E-04 -4.6055 0.94176E+00 -0.0261 24 CH4,aq 0.28986E-19 -19.5378 0.28980E-19 -19.5379 0.99977E+00 -0.0001 29 CO,aq 0.36556E-18 -18.4370 0.36556E-18 -18.4370 0.10000E+01 0.0000 30 CO2,aq 0.32201E-07 -7.4921 0.32193E-07 -7.4922 0.99977E+00 -0.0001 31 CO3-2 0.91047E-06 -6.0407 0.75662E-06 -6.1211 0.83102E+00 -0.0804 32 CaCO3,aq 0.12092E-08 -8.9175 0.12092E-08 -8.9175 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.39456E-10 -10.4039 0.37168E-10 -10.4298 0.94201E+00 -0.0259 34 CaCl+ 0.28451E-10 -10.5459 0.26801E-10 -10.5718 0.94201E+00 -0.0259 35 CaCl2,aq 0.82736E-15 -15.0823 0.82736E-15 -15.0823 0.10000E+01 0.0000 36 CaOH+ 0.73118E-08 -8.1360 0.68878E-08 -8.1619 0.94201E+00 -0.0259 37 CaSO4,aq 0.85743E-09 -9.0668 0.85743E-09 -9.0668 0.10000E+01 0.0000 38 HCl,aq 0.31402E-13 -13.5030 0.31402E-13 -13.5030 0.10000E+01 0.0000 43 FeCl+ 0.79371E-15 -15.1003 0.74768E-15 -15.1263 0.94201E+00 -0.0259 46 FeO,aq 0.81235E-10 -10.0903 0.81235E-10 -10.0903 0.10000E+01 0.0000 47 FeOH+ 0.95252E-10 -10.0211 0.89728E-10 -10.0471 0.94201E+00 -0.0259 48 HFeO2- 0.68426E-09 -9.1648 0.64449E-09 -9.1908 0.94188E+00 -0.0260 49 FeO+ 0.10686E-13 -13.9712 0.10066E-13 -13.9971 0.94201E+00 -0.0259 51 FeO2- 0.12573E-08 -8.9005 0.11843E-08 -8.9265 0.94188E+00 -0.0260 52 HFeO2,aq 0.19864E-09 -9.7019 0.19864E-09 -9.7019 0.10000E+01 0.0000 53 H2,aq 0.45212E-09 -9.3447 0.45202E-09 -9.3448 0.99977E+00 -0.0001 54 KCl,aq 0.12311E-09 -9.9097 0.12311E-09 -9.9097 0.10000E+01 0.0000 55 KHSO4,aq 0.41297E-17 -17.3841 0.41297E-17 -17.3841 0.10000E+01 0.0000 56 KOH,aq 0.16928E-07 -7.7714 0.16928E-07 -7.7714 0.10000E+01 0.0000 57 KSO4- 0.18246E-07 -7.7388 0.17186E-07 -7.7648 0.94188E+00 -0.0260 58 MgCO3,aq 0.14652E-11 -11.8341 0.14652E-11 -11.8341 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.19490E-12 -12.7102 0.18360E-12 -12.7361 0.94201E+00 -0.0259 60 MgCl+ 0.12466E-12 -12.9043 0.11743E-12 -12.9302 0.94201E+00 -0.0259 61 MgOH+ 0.19559E-09 -9.7086 0.18425E-09 -9.7346 0.94201E+00 -0.0259 63 MnO,aq 0.29082E-09 -9.5364 0.29082E-09 -9.5364 0.10000E+01 0.0000 64 MnOH+ 0.11888E-08 -8.9249 0.11199E-08 -8.9508 0.94201E+00 -0.0259 65 MnO2-2 0.66774E-14 -14.1754 0.55490E-14 -14.2558 0.83102E+00 -0.0804 66 HMnO2- 0.17022E-11 -11.7690 0.16033E-11 -11.7950 0.94188E+00 -0.0260 69 MnCl+ 0.41487E-12 -12.3821 0.39081E-12 -12.4080 0.94201E+00 -0.0259 70 MnSO4,aq 0.29872E-11 -11.5247 0.29872E-11 -11.5247 0.10000E+01 0.0000 71 NaCl,aq 0.37838E-07 -7.4221 0.37838E-07 -7.4221 0.10000E+01 0.0000 72 NaOH,aq 0.28627E-06 -6.5432 0.28627E-06 -6.5432 0.10000E+01 0.0000 74 OH- 0.46519E-03 -3.3324 0.43810E-03 -3.3584 0.94176E+00 -0.0261 79 HPO3-2 0.67505E-18 -18.1707 0.56098E-18 -18.2511 0.83102E+00 -0.0804 82 H3PO4,aq 0.48444E-14 -14.3148 0.48444E-14 -14.3148 0.10000E+01 0.0000 83 H2PO4- 0.10286E-07 -7.9878 0.96887E-08 -8.0137 0.94195E+00 -0.0260 84 PO4-3 0.36432E-09 -9.4385 0.24637E-09 -9.6084 0.67624E+00 -0.1699 87 H2P2O7-2 0.88571E-17 -17.0527 0.73604E-17 -17.1331 0.83102E+00 -0.0804 88 HP2O7-3 0.16537E-14 -14.7815 0.11144E-14 -14.9530 0.67388E+00 -0.1714 89 P2O7-4 0.40083E-15 -15.3970 0.20187E-15 -15.6949 0.50362E+00 -0.2979 90 H2S,aq 0.22555E-15 -15.6468 0.22550E-15 -15.6469 0.99977E+00 -0.0001 97 SO3-2 0.14959E-14 -14.8251 0.12444E-14 -14.9050 0.83189E+00 -0.0799 98 HSO3- 0.10910E-15 -15.9622 0.10276E-15 -15.9882 0.94188E+00 -0.0260 99 HSO4- 0.28581E-10 -10.5439 0.26925E-10 -10.5698 0.94208E+00 -0.0259 Charge balance for all species = -.5869E-14 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.1399597E-08 -.8690517E-03 -.8758647E+00 0.0000 2 H2O 0.1000000E+01 0.5550847E+02 0.9999022E+06 0.0000 3 Cl- 0.1379534E-03 0.1379914E-03 0.4891722E+01 4.9935 4 SO4-- 0.2548852E-04 0.2550772E-04 0.2450068E+01 13.0856 5 HCO3- 0.1212771E-04 0.1307163E-04 0.7975149E+00 3.9376 6 HS- 0.5873619E-13 -.6890941E-10 -.2278745E-05 -4.3773 7 Al+++ 0.1856711E-23 0.2635184E-04 0.7109413E+00 2.7367 8 H4SiO4 0.3902580E-03 0.6875408E-03 0.6607667E+02 -3.4086 9 Ca++ 0.1534302E-06 0.1637279E-06 0.6561233E-02 10.8650 10 Mg++ 0.7419567E-09 0.9444555E-09 0.2295931E-04 8.5493 11 Fe++ 0.4377300E-11 0.2321119E-08 0.1296146E-03 6.3202 12 K+ 0.5549699E-04 0.5553229E-04 0.2171207E+01 4.5981 13 Na+ 0.9329328E-03 0.9371837E-03 0.2154352E+02 5.8237 14 Mn++ 0.5880753E-09 0.2072852E-08 0.1138670E-03 8.4484 15 HPO4-- 0.4791384E-06 0.4897886E-06 0.4700474E-01 11.3598 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.1023668E-01 -.8689433E-03 -.9367738E-02 0.0000000E+00 2 H2O 0.5550049E+02 0.5550155E+02 -.1057241E-02 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.4265907E-04 0.2550454E-04 0.1715453E-04 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.1715460E-04 -.6890081E-10 -.1715453E-04 0.0000000E+00 7 Al+++ 0.2018399E-02 0.2634855E-04 0.1992051E-02 0.0000000E+00 8 H4SiO4 0.6445513E-02 0.6874550E-03 0.5758058E-02 0.0000000E+00 9 Ca++ 0.7264094E-03 0.1637075E-06 0.7262457E-03 0.0000000E+00 10 Mg++ 0.4912698E-03 0.9443377E-09 0.4912689E-03 0.0000000E+00 11 Fe++ 0.4413523E-03 0.2320829E-08 0.4413500E-03 0.0000000E+00 12 K+ 0.1314225E-03 0.5552536E-04 0.7589715E-04 0.0000000E+00 13 Na+ 0.9370668E-03 0.9370668E-03 0.0000000E+00 0.0000000E+00 14 Mn++ 0.1073259E-04 0.2072593E-08 0.1073052E-04 0.0000000E+00 15 HPO4-- 0.3662980E-05 0.4897275E-06 0.3173252E-05 0.0000000E+00 Chg. balance for solid moles: 0.8826E-18 Mass of aqueous solution: 0.999975E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 0.6190000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) apatite-OH 0.1058E-05 -5.976 0.5313E-03 -3.275 0.8183E-01 0.1688E-03 clinochlore 0.9825E-04 -4.008 0.5461E-01 -1.263 8.411 0.2077E-01 daphnite 0.6082E-04 -4.216 0.4340E-01 -1.363 6.684 0.1315E-01 chlorite-Mn 0.2146E-05 -5.668 0.1522E-02 -2.818 0.2343 0.4849E-03 hematite 0.6862E-04 -4.164 0.1096E-01 -1.960 1.688 0.2077E-02 muscovite 0.7590E-04 -4.120 0.3023E-01 -1.520 4.656 0.1069E-01 stilbite 0.7210E-03 -3.142 0.5081 -0.294 78.25 0.2370 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.6094E+00 0.6094E+00 1.0000 -0.215 daphnite 0.3773E+00 0.3773E+00 1.0000 -0.423 chlorite-Mn 0.1331E-01 0.1331E-01 1.0000 -1.876 hematite 0.1000E+01 0.1000E+01 1.0000 0.000 muscovite 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 0.649325 g Volume = 0.284319 cm3 Porosity: 77.2108% V(tot) - V(min): 0.96328E+00 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.6190000 g log = -0.2083 Original solution: 1000.0103000 g Original solution / Rock added: 1615.53 (Water/Rock Ratio), log = 3.2083 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0203 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.1000E+01 0.9860 0.1006E+01 0.1020E+01 CO2,gas 0.3352E-05 1.0071 0.3444E-05 0.3420E-05 CH4,gas 0.4129E-16 1.0125 0.4266E-16 0.4213E-16 H2,gas 0.5813E-06 1.0005 0.5934E-06 0.5931E-06 H2S,gas 0.6100E-14 0.9960 0.6199E-14 0.6223E-14 S2,gas 0.4014E-35 1.0000 0.4095E-35 0.4095E-35 CO,gas 0.5339E-15 1.0000 0.5448E-15 0.5448E-15 SO3,gas 0.1365E-37 1.0000 0.1393E-37 0.1393E-37 SO2,gas 0.3153E-21 1.0000 0.3217E-21 0.3217E-21 HCl,gas 0.5431E-16 1.0000 0.5541E-16 0.5541E-16 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 32 apatite-OH -18.15 -18.15 0.00 0.000 0.60662E-11 46 clinochlore 39.07 39.07 0.00 0.000 -0.12132E-10 47 daphnite 28.97 28.97 0.00 0.000 0.12132E-10 48 chlorite-Mn 46.87 46.87 0.00 0.000 0.12132E-10 90 hematite 12.57 12.57 0.00 0.000 -0.30331E-11 120 muscovite 2.58 2.58 0.00 0.000 0.60662E-11 163 stilbite -7.52 -7.52 0.00 0.000 -0.33364E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -13.82 -7.16 -2.387 0.12229E+05 -5.463 3 CH4,gas 4.54 -13.53 -18.07 -4.517 0.30852E+05 -16.370 4 H2,gas 8.00 0.07 -7.93 -4.529 0.13533E+05 -6.227 5 H2S,gas -6.23 -22.14 -15.91 -7.953 0.27160E+05 -14.208 6 S2,gas -7.34 -44.42 -37.09 -5.706 0.63324E+05 -35.388 7 CO,gas 3.21 -13.75 -16.96 -5.219 0.28963E+05 -15.264 8 SO3,gas 17.12 -22.43 -39.55 -9.889 0.67539E+05 -37.856 9 SO2,gas 0.83 -22.36 -23.19 -6.184 0.39599E+05 -21.493 10 HCl,gas 5.19 -12.77 -17.96 -8.978 0.30658E+05 -16.256 11 acmite 7.71 5.29 -2.42 -0.251 0.41325E+04 15 albite-high 0.69 -1.67 -2.36 -0.181 0.40272E+04 16 albite -0.38 -1.67 -1.28 -0.099 0.21884E+04 19 spessartine 24.46 20.59 -3.86 -0.193 0.65985E+04 20 analcite 3.32 1.74 -1.58 -0.175 0.26957E+04 21 andalusite 5.00 2.06 -2.94 -0.294 0.50143E+04 22 andradite 39.01 34.94 -4.07 -0.212 0.69555E+04 23 grossular 32.73 27.84 -4.89 -0.244 0.83477E+04 26 annite 20.12 16.07 -4.05 -0.225 0.69220E+04 27 phlogopite 27.06 22.76 -4.31 -0.239 0.73553E+04 29 anorthite 12.71 9.52 -3.19 -0.245 0.54453E+04 35 aragonite 0.97 -2.96 -3.92 -1.308 0.66993E+04 36 brucite 12.57 8.55 -4.02 -0.804 0.68628E+04 37 calcite 0.81 -2.96 -3.77 -1.256 0.64351E+04 38 carnegieite-low 9.02 5.15 -3.87 -0.553 0.66106E+04 39 carnegieite-high 10.09 5.15 -4.94 -0.706 0.84375E+04 40 carpholite-Mg 8.58 7.21 -1.38 -0.092 0.23505E+04 41 carpholite-Fe 6.71 4.98 -1.74 -0.116 0.29646E+04 42 celadonite 5.34 2.25 -3.09 -0.182 0.52795E+04 43 celadonite-Fe 3.88 0.02 -3.86 -0.227 0.65841E+04 50 chloritoid-Mg 13.20 10.61 -2.58 -0.172 0.44113E+04 51 chloritoid-Fe 9.17 8.39 -0.79 -0.053 0.13465E+04 52 chloritoid-Mn 11.40 10.51 -0.89 -0.059 0.15159E+04 54 coesite -2.38 -3.41 -1.03 -0.344 0.17631E+04 59 corundum 8.38 5.47 -2.91 -0.265 0.49681E+04 61 cristobalite -2.56 -3.41 -0.85 -0.283 0.14485E+04 63 cymrite-K 1.69 -2.89 -4.58 -0.381 0.78142E+04 65 diaspore 2.87 2.74 -0.14 -0.023 0.23384E+03 67 diopside 16.18 12.60 -3.58 -0.358 0.61202E+04 68 hedenbergite 14.21 10.37 -3.84 -0.384 0.65574E+04 75 epidote 24.67 23.26 -1.41 -0.068 0.24063E+04 76 clinozoisite 22.81 19.71 -3.09 -0.141 0.52791E+04 77 epidote-Fe 29.84 26.81 -3.03 -0.158 0.51802E+04 78 fayalite 14.05 9.23 -4.81 -0.688 0.82198E+04 83 gibbsite 4.08 2.74 -1.34 -0.192 0.22924E+04 87 greenalite 16.14 12.14 -4.00 -0.333 0.68235E+04 91 heulandite -5.83 -7.52 -1.69 -0.077 0.28938E+04 95 jadeite 4.22 1.74 -2.47 -0.247 0.42212E+04 97 kalsilite 7.58 3.93 -3.66 -0.523 0.62454E+04 98 kaolinite -1.33 -1.34 -0.01 -0.001 0.18837E+02 99 kyanite 4.88 2.06 -2.81 -0.281 0.48002E+04 101 laumontite 2.88 2.70 -0.18 -0.012 0.30652E+03 102 lawsonite 9.62 9.52 -0.09 -0.006 0.16201E+03 103 leucite 4.12 0.52 -3.60 -0.360 0.61491E+04 105 lizardite 23.24 18.83 -4.41 -0.368 0.75354E+04 107 magnetite 20.09 18.89 -1.20 -0.098 0.20507E+04 113 margarite 17.32 14.99 -2.33 -0.093 0.39766E+04 116 microcline -2.49 -2.89 -0.40 -0.031 0.69079E+03 121 paragonite 4.24 3.81 -0.43 -0.025 0.73673E+03 122 nepheline 8.34 5.15 -3.19 -0.455 0.54429E+04 136 prehnite 19.37 16.98 -2.39 -0.141 0.40883E+04 137 prehnite-Fe 22.50 20.52 -1.97 -0.119 0.33705E+04 138 pumpellyite-Fe 46.27 43.01 -3.26 -0.072 0.55620E+04 139 pumpellyite-Mg 48.99 45.24 -3.75 -0.083 0.64094E+04 145 pyroxmangite 7.40 5.04 -2.36 -0.472 0.40278E+04 146 pyrophyllite -6.18 -8.16 -1.99 -0.124 0.33898E+04 147 quartz -2.99 -3.41 -0.42 -0.140 0.71580E+03 151 rhodochrosite -0.98 -5.37 -4.40 -1.466 0.75082E+04 152 rhodonite 7.45 5.04 -2.41 -0.481 0.41080E+04 153 sanidine -1.28 -2.89 -1.62 -0.124 0.27585E+04 155 siderite -2.61 -7.50 -4.89 -1.631 0.83558E+04 156 sillimanite 5.26 2.06 -3.20 -0.320 0.54582E+04 164 stilpnomelane-Fe 13.02 12.10 -0.91 -0.027 0.15584E+04 165 stilpnomelane-Mg 27.44 23.25 -4.19 -0.125 0.71568E+04 167 sudoite-Fe 18.30 13.36 -4.93 -0.159 0.84260E+04 168 sudoite 21.08 17.82 -3.26 -0.105 0.55624E+04 171 talc 16.49 12.01 -4.48 -0.263 0.76456E+04 174 tephroite 18.09 13.49 -4.60 -0.657 0.78502E+04 177 topaz-H 4.62 2.06 -2.55 -0.232 0.43603E+04 178 tridymite -2.63 -3.41 -0.78 -0.261 0.13358E+04 187 wairakite 3.95 2.70 -1.25 -0.073 0.21285E+04 188 walstromite 11.51 7.46 -4.05 -0.811 0.69202E+04 189 wollastonite 10.46 7.46 -3.00 -0.601 0.51306E+04 190 pseudo-wollastonite 11.00 7.46 -3.54 -0.709 0.60505E+04 191 zoisite 22.85 19.71 -3.14 -0.143 0.53531E+04 192 akaganeite 7.75 6.28 -1.47 -0.318 0.25125E+04 193 beidellite-Ca -1.65 -4.34 -2.69 -0.167 0.46013E+04 194 beidellite-H -2.33 -6.13 -3.81 -0.243 0.65002E+04 195 beidellite-K -1.52 -4.62 -3.10 -0.190 0.52855E+04 196 beidellite-Mg -1.79 -4.72 -2.93 -0.181 0.50075E+04 197 beidellite-Na -1.34 -4.21 -2.87 -0.176 0.48989E+04 199 chalcedony -2.80 -3.41 -0.61 -0.202 0.10351E+04 201 montmorillonite-Ca -2.29 -4.45 -2.16 -0.134 0.36873E+04 202 montmorillonite-K -2.24 -4.73 -2.49 -0.152 0.42496E+04 203 montmorillonite-Mg -2.48 -4.83 -2.35 -0.146 0.40167E+04 204 montmorillonite-Na -2.04 -4.32 -2.28 -0.140 0.38988E+04 205 nontronite-Ca 3.21 2.75 -0.46 -0.030 0.78927E+03 206 nontronite-H 2.53 0.96 -1.57 -0.105 0.26861E+04 207 nontronite-K 3.34 2.48 -0.86 -0.055 0.14748E+04 208 nontronite-Mg 3.07 2.37 -0.70 -0.046 0.12028E+04 209 nontronite-Na 3.52 2.88 -0.64 -0.041 0.10899E+04 224 tobermorite 9.82 5.64 -4.18 -1.141 0.71392E+04 233 boehmite 4.41 2.74 -1.67 -0.278 0.28508E+04 235 ferrous-oxide 9.81 6.32 -3.49 -0.873 0.59615E+04 240 silica-amorphous -2.09 -3.41 -1.32 -0.439 0.22493E+04 242 an20ab80 2.02 0.57 -1.45 -0.111 0.24690E+04 243 an25ab75 2.65 1.13 -1.51 -0.117 0.25861E+04 244 an30ab70 3.28 1.69 -1.59 -0.122 0.27128E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 0.0200000 g Current total amount of reactant added: 0.6190000 g New total amount of reactant added: 0.6390000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.5871E-14 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 7 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 0.6390000 Water: Moles liquid = 0.5550E+02 kg liquid = 0.9999E+00 Moles total = 0.5550E+02 kg total = 0.9999E+00 Activity = 1.0000 Stoichiometric ionic strength = .7548239E-03 Osmotic coef. = 0.9839 True ionic strength = .1041855E-02 Chg. balance for total moles = -.5871E-14 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.13657E-08 -8.8646 0.12862E-08 -8.8907 0.94182E+00 -0.0260 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13795E-03 -3.8603 0.12987E-03 -3.8865 0.94140E+00 -0.0262 4 SO4-- 0.25488E-04 -4.5937 0.21142E-04 -4.6749 0.82947E+00 -0.0812 5 HCO3- 0.12106E-04 -4.9170 0.11398E-04 -4.9432 0.94150E+00 -0.0262 6 HS- 0.58077E-13 -13.2360 0.54675E-13 -13.2622 0.94141E+00 -0.0262 7 Al+++ 0.16684E-23 -23.7777 0.11191E-23 -23.9511 0.67077E+00 -0.1734 8 H4SiO4 0.39859E-03 -3.3995 0.39859E-03 -3.3995 0.10000E+01 0.0000 9 Ca++ 0.13567E-06 -6.8675 0.11248E-06 -6.9489 0.82903E+00 -0.0814 10 Mg++ 0.70854E-09 -9.1496 0.58720E-09 -9.2312 0.82875E+00 -0.0816 11 Fe++ 0.41801E-11 -11.3788 0.34646E-11 -11.4604 0.82882E+00 -0.0815 12 K+ 0.56703E-04 -4.2464 0.53387E-04 -4.2726 0.94152E+00 -0.0262 13 Na+ 0.95774E-03 -3.0188 0.90160E-03 -3.0450 0.94139E+00 -0.0262 14 Mn++ 0.56159E-09 -9.2506 0.46548E-09 -9.3321 0.82887E+00 -0.0815 15 HPO4-- 0.57194E-06 -6.2426 0.47441E-06 -6.3238 0.82948E+00 -0.0812 16 HSiO3- 0.30737E-03 -3.5123 0.28936E-03 -3.5386 0.94140E+00 -0.0262 17 Ca(HSiO3)+ 0.78723E-09 -9.1039 0.74120E-09 -9.1301 0.94153E+00 -0.0262 18 Mg(HSiO3)+ 0.51147E-11 -11.2912 0.48157E-11 -11.3173 0.94153E+00 -0.0262 19 NaHSiO3,aq 0.42195E-05 -5.3747 0.42195E-05 -5.3747 0.10000E+01 0.0000 20 AlO+ 0.97740E-13 -13.0099 0.92025E-13 -13.0361 0.94153E+00 -0.0262 21 AlOH+2 0.71103E-18 -18.1481 0.58939E-18 -18.2296 0.82893E+00 -0.0815 22 HAlO2,aq 0.14248E-07 -7.8462 0.14248E-07 -7.8462 0.10000E+01 0.0000 23 AlO2- 0.26051E-04 -4.5842 0.24521E-04 -4.6105 0.94127E+00 -0.0263 24 CH4,aq 0.28639E-19 -19.5430 0.28632E-19 -19.5431 0.99977E+00 -0.0001 29 CO,aq 0.35706E-18 -18.4473 0.35706E-18 -18.4473 0.10000E+01 0.0000 30 CO2,aq 0.31333E-07 -7.5040 0.31325E-07 -7.5041 0.99977E+00 -0.0001 31 CO3-2 0.93328E-06 -6.0300 0.77400E-06 -6.1113 0.82934E+00 -0.0813 32 CaCO3,aq 0.10916E-08 -8.9619 0.10916E-08 -8.9619 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.34756E-10 -10.4590 0.32724E-10 -10.4851 0.94153E+00 -0.0262 34 CaCl+ 0.25107E-10 -10.6002 0.23639E-10 -10.6264 0.94153E+00 -0.0262 35 CaCl2,aq 0.72937E-15 -15.1371 0.72937E-15 -15.1371 0.10000E+01 0.0000 36 CaOH+ 0.66193E-08 -8.1792 0.62323E-08 -8.2054 0.94153E+00 -0.0262 37 CaSO4,aq 0.75512E-09 -9.1220 0.75512E-09 -9.1220 0.10000E+01 0.0000 38 HCl,aq 0.30610E-13 -13.5141 0.30610E-13 -13.5141 0.10000E+01 0.0000 43 FeCl+ 0.75640E-15 -15.1212 0.71218E-15 -15.1474 0.94153E+00 -0.0262 46 FeO,aq 0.81390E-10 -10.0894 0.81390E-10 -10.0894 0.10000E+01 0.0000 47 FeOH+ 0.93123E-10 -10.0309 0.87678E-10 -10.0571 0.94153E+00 -0.0262 48 HFeO2- 0.70330E-09 -9.1529 0.66208E-09 -9.1791 0.94140E+00 -0.0262 49 FeO+ 0.10427E-13 -13.9818 0.98177E-14 -14.0080 0.94153E+00 -0.0262 51 FeO2- 0.12899E-08 -8.8895 0.12143E-08 -8.9157 0.94140E+00 -0.0262 52 HFeO2,aq 0.19864E-09 -9.7019 0.19864E-09 -9.7019 0.10000E+01 0.0000 53 H2,aq 0.45385E-09 -9.3431 0.45375E-09 -9.3432 0.99977E+00 -0.0001 54 KCl,aq 0.12566E-09 -9.9008 0.12566E-09 -9.9008 0.10000E+01 0.0000 55 KHSO4,aq 0.41047E-17 -17.3867 0.41047E-17 -17.3867 0.10000E+01 0.0000 56 KOH,aq 0.17725E-07 -7.7514 0.17725E-07 -7.7514 0.10000E+01 0.0000 57 KSO4- 0.18605E-07 -7.7304 0.17514E-07 -7.7566 0.94140E+00 -0.0262 58 MgCO3,aq 0.14285E-11 -11.8451 0.14285E-11 -11.8451 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.18541E-12 -12.7319 0.17457E-12 -12.7580 0.94153E+00 -0.0262 60 MgCl+ 0.11880E-12 -12.9252 0.11185E-12 -12.9514 0.94153E+00 -0.0262 61 MgOH+ 0.19122E-09 -9.7185 0.18004E-09 -9.7446 0.94153E+00 -0.0262 63 MnO,aq 0.29138E-09 -9.5355 0.29138E-09 -9.5355 0.10000E+01 0.0000 64 MnOH+ 0.11623E-08 -8.9347 0.10943E-08 -8.9609 0.94153E+00 -0.0262 65 MnO2-2 0.70478E-14 -14.1519 0.58450E-14 -14.2332 0.82934E+00 -0.0813 66 HMnO2- 0.17496E-11 -11.7571 0.16471E-11 -11.7833 0.94140E+00 -0.0262 69 MnCl+ 0.39537E-12 -12.4030 0.37226E-12 -12.4292 0.94153E+00 -0.0262 70 MnSO4,aq 0.28411E-11 -11.5465 0.28411E-11 -11.5465 0.10000E+01 0.0000 71 NaCl,aq 0.38804E-07 -7.4111 0.38804E-07 -7.4111 0.10000E+01 0.0000 72 NaOH,aq 0.30117E-06 -6.5212 0.30117E-06 -6.5212 0.10000E+01 0.0000 74 OH- 0.47722E-03 -3.3213 0.44920E-03 -3.3476 0.94127E+00 -0.0263 79 HPO3-2 0.80888E-18 -18.0921 0.67083E-18 -18.1734 0.82934E+00 -0.0813 82 H3PO4,aq 0.54893E-14 -14.2605 0.54893E-14 -14.2605 0.10000E+01 0.0000 83 H2PO4- 0.11956E-07 -7.9224 0.11257E-07 -7.9486 0.94146E+00 -0.0262 84 PO4-3 0.44701E-09 -9.3497 0.30093E-09 -9.5215 0.67320E+00 -0.1719 87 H2P2O7-2 0.11980E-16 -16.9215 0.99354E-17 -17.0028 0.82934E+00 -0.0813 88 HP2O7-3 0.22993E-14 -14.6384 0.15424E-14 -14.8118 0.67080E+00 -0.1734 89 P2O7-4 0.57346E-15 -15.2415 0.28647E-15 -15.5429 0.49955E+00 -0.3014 90 H2S,aq 0.21740E-15 -15.6627 0.21735E-15 -15.6628 0.99977E+00 -0.0001 97 SO3-2 0.15015E-14 -14.8235 0.12466E-14 -14.9043 0.83022E+00 -0.0808 98 HSO3- 0.10664E-15 -15.9721 0.10039E-15 -15.9983 0.94140E+00 -0.0262 99 HSO4- 0.27832E-10 -10.5555 0.26207E-10 -10.5816 0.94160E+00 -0.0261 Charge balance for all species = -.5875E-14 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.1365695E-08 -.8942825E-03 -.9012909E+00 0.0000 2 H2O 0.1000000E+01 0.5550847E+02 0.9998994E+06 0.0000 3 Cl- 0.1379530E-03 0.1379919E-03 0.4891727E+01 5.0042 4 SO4-- 0.2548836E-04 0.2550782E-04 0.2450072E+01 13.1065 5 HCO3- 0.1210594E-04 0.1307168E-04 0.7975158E+00 3.9475 6 HS- 0.5807727E-13 -.7254258E-10 -.2398883E-05 -4.3715 7 Al+++ 0.1668387E-23 0.2606510E-04 0.7032034E+00 2.7209 8 H4SiO4 0.3985921E-03 0.7101816E-03 0.6825241E+02 -3.3995 9 Ca++ 0.1356744E-06 0.1449875E-06 0.5810216E-02 10.8324 10 Mg++ 0.7085363E-09 0.9066035E-09 0.2203909E-04 8.5501 11 Fe++ 0.4180122E-11 0.2370506E-08 0.1323721E-03 6.3210 12 K+ 0.5670266E-04 0.5673911E-04 0.2218386E+01 4.6181 13 Na+ 0.9577360E-03 0.9622954E-03 0.2212072E+02 5.8457 14 Mn++ 0.5615904E-09 0.2020247E-08 0.1109770E-03 8.4493 15 HPO4-- 0.5719395E-06 0.5843429E-06 0.5607891E-01 11.4575 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.1056785E-01 -.8941675E-03 -.9673684E-02 0.0000000E+00 2 H2O 0.5550024E+02 0.5550133E+02 -.1090490E-02 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.4321334E-04 0.2550454E-04 0.1770880E-04 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.1770887E-04 -.7253325E-10 -.1770880E-04 0.0000000E+00 7 Al+++ 0.2083614E-02 0.2606174E-04 0.2057552E-02 0.0000000E+00 8 H4SiO4 0.6653768E-02 0.7100903E-03 0.5943678E-02 0.0000000E+00 9 Ca++ 0.7494122E-03 0.1449689E-06 0.7492672E-03 0.0000000E+00 10 Mg++ 0.5071429E-03 0.9064869E-09 0.5071420E-03 0.0000000E+00 11 Fe++ 0.4556125E-03 0.2370201E-08 0.4556101E-03 0.0000000E+00 12 K+ 0.1356688E-03 0.5673182E-04 0.7893697E-04 0.0000000E+00 13 Na+ 0.9621717E-03 0.9621717E-03 0.0000000E+00 0.0000000E+00 14 Mn++ 0.1107936E-04 0.2019987E-08 0.1107734E-04 0.0000000E+00 15 HPO4-- 0.3781331E-05 0.5842678E-06 0.3197064E-05 0.0000000E+00 Chg. balance for solid moles: 0.2338E-18 Mass of aqueous solution: 0.999974E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 0.6390000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) apatite-OH 0.1066E-05 -5.972 0.5353E-03 -3.271 0.7986E-01 0.1701E-03 clinochlore 0.1014E-03 -3.994 0.5638E-01 -1.249 8.411 0.2144E-01 daphnite 0.6279E-04 -4.202 0.4480E-01 -1.349 6.683 0.1358E-01 chlorite-Mn 0.2215E-05 -5.655 0.1571E-02 -2.804 0.2343 0.5005E-03 hematite 0.7084E-04 -4.150 0.1131E-01 -1.946 1.688 0.2144E-02 muscovite 0.7894E-04 -4.103 0.3144E-01 -1.502 4.691 0.1112E-01 stilbite 0.7439E-03 -3.128 0.5243 -0.280 78.21 0.2445 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.6094E+00 0.6094E+00 1.0000 -0.215 daphnite 0.3773E+00 0.3773E+00 1.0000 -0.423 chlorite-Mn 0.1331E-01 0.1331E-01 1.0000 -1.876 hematite 0.1000E+01 0.1000E+01 1.0000 0.000 muscovite 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 0.670305 g Volume = 0.293481 cm3 Porosity: 76.6262% V(tot) - V(min): 0.96212E+00 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.6390000 g log = -0.1945 Original solution: 1000.0103000 g Original solution / Rock added: 1564.96 (Water/Rock Ratio), log = 3.1945 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0203 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.1000E+01 0.9860 0.1006E+01 0.1020E+01 CO2,gas 0.3262E-05 1.0071 0.3351E-05 0.3328E-05 CH4,gas 0.4080E-16 1.0125 0.4214E-16 0.4162E-16 H2,gas 0.5835E-06 1.0005 0.5957E-06 0.5954E-06 H2S,gas 0.5879E-14 0.9960 0.5975E-14 0.5998E-14 S2,gas 0.3701E-35 1.0000 0.3776E-35 0.3776E-35 CO,gas 0.5215E-15 1.0000 0.5321E-15 0.5321E-15 SO3,gas 0.1296E-37 1.0000 0.1322E-37 0.1322E-37 SO2,gas 0.3004E-21 1.0000 0.3065E-21 0.3065E-21 HCl,gas 0.5294E-16 1.0000 0.5401E-16 0.5401E-16 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 32 apatite-OH -18.15 -18.15 0.00 0.000 -0.18198E-10 46 clinochlore 39.07 39.07 0.00 0.000 -0.36397E-10 47 daphnite 28.97 28.97 0.00 0.000 -0.36397E-10 48 chlorite-Mn 46.87 46.87 0.00 0.000 -0.24265E-10 90 hematite 12.57 12.57 0.00 0.000 -0.90992E-11 120 muscovite 2.58 2.58 0.00 0.000 0.60662E-11 163 stilbite -7.52 -7.52 0.00 0.000 -0.90992E-11 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -13.83 -7.17 -2.391 0.12249E+05 -5.475 3 CH4,gas 4.54 -13.53 -18.07 -4.519 0.30861E+05 -16.375 4 H2,gas 8.00 0.08 -7.92 -4.528 0.13530E+05 -6.225 5 H2S,gas -6.23 -22.15 -15.92 -7.961 0.27188E+05 -14.224 6 S2,gas -7.34 -44.46 -37.12 -5.711 0.63385E+05 -35.423 7 CO,gas 3.21 -13.76 -16.97 -5.222 0.28981E+05 -15.274 8 SO3,gas 17.12 -22.46 -39.58 -9.894 0.67578E+05 -37.879 9 SO2,gas 0.83 -22.38 -23.21 -6.190 0.39635E+05 -21.514 10 HCl,gas 5.19 -12.78 -17.97 -8.983 0.30677E+05 -16.268 11 acmite 7.71 5.33 -2.38 -0.247 0.40636E+04 15 albite-high 0.69 -1.63 -2.32 -0.179 0.39696E+04 16 albite -0.38 -1.63 -1.25 -0.096 0.21308E+04 19 spessartine 24.46 20.59 -3.87 -0.193 0.66013E+04 20 analcite 3.32 1.77 -1.55 -0.173 0.26537E+04 21 andalusite 5.00 2.04 -2.96 -0.296 0.50527E+04 22 andradite 39.01 34.87 -4.14 -0.215 0.70753E+04 23 grossular 32.73 27.74 -4.99 -0.250 0.85216E+04 26 annite 20.12 16.10 -4.02 -0.223 0.68636E+04 27 phlogopite 27.06 22.79 -4.27 -0.237 0.72970E+04 29 anorthite 12.71 9.48 -3.24 -0.249 0.55237E+04 35 aragonite 0.97 -3.00 -3.97 -1.323 0.67752E+04 36 brucite 12.57 8.55 -4.02 -0.804 0.68613E+04 37 calcite 0.81 -3.00 -3.81 -1.271 0.65110E+04 38 carnegieite-low 9.02 5.17 -3.86 -0.551 0.65843E+04 39 carnegieite-high 10.09 5.17 -4.93 -0.704 0.84113E+04 40 carpholite-Mg 8.58 7.19 -1.39 -0.093 0.23718E+04 41 carpholite-Fe 6.71 4.96 -1.75 -0.117 0.29859E+04 42 celadonite 5.34 2.29 -3.05 -0.179 0.52083E+04 43 celadonite-Fe 3.88 0.06 -3.81 -0.224 0.65129E+04 50 chloritoid-Mg 13.20 10.59 -2.61 -0.174 0.44483E+04 51 chloritoid-Fe 9.17 8.36 -0.81 -0.054 0.13835E+04 52 chloritoid-Mn 11.40 10.49 -0.91 -0.061 0.15529E+04 54 coesite -2.38 -3.40 -1.02 -0.341 0.17474E+04 59 corundum 8.38 5.44 -2.94 -0.267 0.50222E+04 61 cristobalite -2.56 -3.40 -0.84 -0.280 0.14328E+04 63 cymrite-K 1.69 -2.86 -4.54 -0.379 0.77601E+04 65 diaspore 2.87 2.72 -0.15 -0.025 0.26088E+03 67 diopside 16.18 12.58 -3.60 -0.360 0.61430E+04 68 hedenbergite 14.21 10.35 -3.85 -0.385 0.65802E+04 75 epidote 24.67 23.19 -1.48 -0.072 0.25246E+04 76 clinozoisite 22.81 19.63 -3.18 -0.144 0.54244E+04 77 epidote-Fe 29.84 26.75 -3.09 -0.160 0.52714E+04 78 fayalite 14.05 9.24 -4.80 -0.686 0.82013E+04 83 gibbsite 4.08 2.72 -1.36 -0.194 0.23194E+04 87 greenalite 16.14 12.16 -3.98 -0.331 0.67879E+04 91 heulandite -5.83 -7.52 -1.69 -0.077 0.28938E+04 95 jadeite 4.22 1.77 -2.45 -0.245 0.41792E+04 97 kalsilite 7.58 3.94 -3.64 -0.521 0.62226E+04 98 kaolinite -1.33 -1.36 -0.02 -0.002 0.41580E+02 99 kyanite 4.88 2.04 -2.83 -0.283 0.48386E+04 101 laumontite 2.88 2.68 -0.21 -0.014 0.35353E+03 102 lawsonite 9.62 9.48 -0.14 -0.009 0.24036E+03 103 leucite 4.12 0.54 -3.58 -0.358 0.61107E+04 105 lizardite 23.24 18.85 -4.39 -0.366 0.74998E+04 107 magnetite 20.09 18.89 -1.20 -0.098 0.20493E+04 113 margarite 17.32 14.92 -2.41 -0.096 0.41090E+04 116 microcline -2.49 -2.86 -0.37 -0.029 0.63671E+03 121 paragonite 4.24 3.81 -0.43 -0.025 0.73322E+03 122 nepheline 8.34 5.17 -3.17 -0.453 0.54166E+04 136 prehnite 19.37 16.91 -2.46 -0.145 0.42066E+04 137 prehnite-Fe 22.50 20.47 -2.03 -0.122 0.34618E+04 138 pumpellyite-Fe 46.27 42.86 -3.41 -0.076 0.58242E+04 139 pumpellyite-Mg 48.99 45.09 -3.91 -0.087 0.66716E+04 145 pyroxmangite 7.40 5.05 -2.35 -0.470 0.40107E+04 146 pyrophyllite -6.18 -8.16 -1.98 -0.124 0.33812E+04 147 quartz -2.99 -3.40 -0.41 -0.137 0.70013E+03 151 rhodochrosite -0.98 -5.38 -4.41 -1.469 0.75270E+04 152 rhodonite 7.45 5.05 -2.40 -0.479 0.40909E+04 153 sanidine -1.28 -2.86 -1.58 -0.122 0.27045E+04 155 siderite -2.61 -7.51 -4.90 -1.635 0.83747E+04 156 sillimanite 5.26 2.04 -3.22 -0.322 0.54967E+04 164 stilpnomelane-Fe 13.02 12.16 -0.86 -0.026 0.14630E+04 165 stilpnomelane-Mg 27.44 23.31 -4.14 -0.123 0.70614E+04 167 sudoite-Fe 18.30 13.33 -4.97 -0.160 0.84844E+04 168 sudoite 21.08 17.79 -3.29 -0.106 0.56207E+04 171 talc 16.49 12.05 -4.44 -0.261 0.75787E+04 174 tephroite 18.09 13.50 -4.59 -0.655 0.78317E+04 177 topaz-H 4.62 2.04 -2.58 -0.234 0.43987E+04 178 tridymite -2.63 -3.40 -0.77 -0.258 0.13201E+04 187 wairakite 3.95 2.68 -1.27 -0.075 0.21755E+04 188 walstromite 11.51 7.43 -4.08 -0.815 0.69601E+04 189 wollastonite 10.46 7.43 -3.03 -0.606 0.51706E+04 190 pseudo-wollastonite 11.00 7.43 -3.57 -0.713 0.60904E+04 191 zoisite 22.85 19.63 -3.22 -0.146 0.54985E+04 192 akaganeite 7.75 6.28 -1.47 -0.318 0.25125E+04 193 beidellite-Ca -1.65 -4.35 -2.70 -0.167 0.46160E+04 194 beidellite-H -2.33 -6.14 -3.81 -0.243 0.65057E+04 195 beidellite-K -1.52 -4.61 -3.09 -0.189 0.52797E+04 196 beidellite-Mg -1.79 -4.73 -2.94 -0.182 0.50128E+04 197 beidellite-Na -1.34 -4.21 -2.87 -0.175 0.48920E+04 199 chalcedony -2.80 -3.40 -0.60 -0.199 0.10194E+04 201 montmorillonite-Ca -2.29 -4.45 -2.15 -0.133 0.36785E+04 202 montmorillonite-K -2.24 -4.71 -2.47 -0.151 0.42204E+04 203 montmorillonite-Mg -2.48 -4.82 -2.34 -0.145 0.39985E+04 204 montmorillonite-Na -2.04 -4.30 -2.27 -0.139 0.38683E+04 205 nontronite-Ca 3.21 2.78 -0.44 -0.028 0.74986E+03 206 nontronite-H 2.53 0.99 -1.54 -0.104 0.26375E+04 207 nontronite-K 3.34 2.51 -0.83 -0.053 0.14150E+04 208 nontronite-Mg 3.07 2.40 -0.68 -0.044 0.11539E+04 209 nontronite-Na 3.52 2.92 -0.60 -0.039 0.10289E+04 224 tobermorite 9.82 5.62 -4.20 -1.146 0.71699E+04 233 boehmite 4.41 2.72 -1.69 -0.281 0.28778E+04 235 ferrous-oxide 9.81 6.32 -3.49 -0.873 0.59601E+04 240 silica-amorphous -2.09 -3.40 -1.31 -0.436 0.22336E+04 242 an20ab80 2.02 0.59 -1.43 -0.110 0.24385E+04 243 an25ab75 2.65 1.14 -1.50 -0.115 0.25625E+04 244 an30ab70 3.28 1.70 -1.58 -0.121 0.26960E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 0.0200000 g Current total amount of reactant added: 0.6390000 g New total amount of reactant added: 0.6590000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.5870E-14 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 7 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 0.6590000 Water: Moles liquid = 0.5550E+02 kg liquid = 0.9999E+00 Moles total = 0.5550E+02 kg total = 0.9999E+00 Activity = 1.0000 Stoichiometric ionic strength = .7669396E-03 Osmotic coef. = 0.9838 True ionic strength = .1067951E-02 Chg. balance for total moles = -.5870E-14 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.13338E-08 -8.8749 0.12556E-08 -8.9012 0.94135E+00 -0.0262 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13795E-03 -3.8603 0.12980E-03 -3.8867 0.94092E+00 -0.0264 4 SO4-- 0.25488E-04 -4.5937 0.21099E-04 -4.6757 0.82781E+00 -0.0821 5 HCO3- 0.12084E-04 -4.9178 0.11372E-04 -4.9442 0.94103E+00 -0.0264 6 HS- 0.57496E-13 -13.2404 0.54099E-13 -13.2668 0.94093E+00 -0.0264 7 Al+++ 0.15049E-23 -23.8225 0.10049E-23 -23.9979 0.66774E+00 -0.1754 8 H4SiO4 0.40674E-03 -3.3907 0.40674E-03 -3.3907 0.10000E+01 0.0000 9 Ca++ 0.12064E-06 -6.9185 0.99809E-07 -7.0008 0.82736E+00 -0.0823 10 Mg++ 0.67782E-09 -9.1689 0.56061E-09 -9.2513 0.82708E+00 -0.0825 11 Fe++ 0.39989E-11 -11.3981 0.33077E-11 -11.4805 0.82714E+00 -0.0824 12 K+ 0.57925E-04 -4.2371 0.54510E-04 -4.2635 0.94104E+00 -0.0264 13 Na+ 0.98253E-03 -3.0077 0.92447E-03 -3.0341 0.94091E+00 -0.0264 14 Mn++ 0.53725E-09 -9.2698 0.44441E-09 -9.3522 0.82719E+00 -0.0824 15 HPO4-- 0.67722E-06 -6.1693 0.56062E-06 -6.2513 0.82782E+00 -0.0821 16 HSiO3- 0.32148E-03 -3.4928 0.30249E-03 -3.5193 0.94092E+00 -0.0264 17 Ca(HSiO3)+ 0.73063E-09 -9.1363 0.68757E-09 -9.1627 0.94106E+00 -0.0264 18 Mg(HSiO3)+ 0.51072E-11 -11.2918 0.48062E-11 -11.3182 0.94106E+00 -0.0264 19 NaHSiO3,aq 0.45228E-05 -5.3446 0.45228E-05 -5.3446 0.10000E+01 0.0000 20 AlO+ 0.92153E-13 -13.0355 0.86721E-13 -13.0619 0.94106E+00 -0.0264 21 AlOH+2 0.65539E-18 -18.1835 0.54217E-18 -18.2659 0.82725E+00 -0.0824 22 HAlO2,aq 0.13755E-07 -7.8615 0.13755E-07 -7.8615 0.10000E+01 0.0000 23 AlO2- 0.25777E-04 -4.5888 0.24251E-04 -4.6153 0.94079E+00 -0.0265 24 CH4,aq 0.28330E-19 -19.5478 0.28323E-19 -19.5479 0.99976E+00 -0.0001 29 CO,aq 0.34911E-18 -18.4570 0.34911E-18 -18.4570 0.10000E+01 0.0000 30 CO2,aq 0.30516E-07 -7.5155 0.30508E-07 -7.5156 0.99976E+00 -0.0001 31 CO3-2 0.95582E-06 -6.0196 0.79110E-06 -6.1018 0.82767E+00 -0.0821 32 CaCO3,aq 0.99007E-09 -9.0043 0.99007E-09 -9.0043 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.30787E-10 -10.5116 0.28972E-10 -10.5380 0.94106E+00 -0.0264 34 CaCl+ 0.22279E-10 -10.6521 0.20966E-10 -10.6785 0.94106E+00 -0.0264 35 CaCl2,aq 0.64656E-15 -15.1894 0.64656E-15 -15.1894 0.10000E+01 0.0000 36 CaOH+ 0.60204E-08 -8.2204 0.56655E-08 -8.2468 0.94106E+00 -0.0264 37 CaSO4,aq 0.66872E-09 -9.1748 0.66872E-09 -9.1748 0.10000E+01 0.0000 38 HCl,aq 0.29864E-13 -13.5248 0.29864E-13 -13.5248 0.10000E+01 0.0000 43 FeCl+ 0.72214E-15 -15.1414 0.67958E-15 -15.1678 0.94106E+00 -0.0264 46 FeO,aq 0.81549E-10 -10.0886 0.81549E-10 -10.0886 0.10000E+01 0.0000 47 FeOH+ 0.91124E-10 -10.0404 0.85754E-10 -10.0667 0.94106E+00 -0.0264 48 HFeO2- 0.72225E-09 -9.1413 0.67958E-09 -9.1678 0.94092E+00 -0.0264 49 FeO+ 0.10184E-13 -13.9921 0.95835E-14 -14.0185 0.94106E+00 -0.0264 51 FeO2- 0.13221E-08 -8.8788 0.12440E-08 -8.9052 0.94092E+00 -0.0264 52 HFeO2,aq 0.19864E-09 -9.7019 0.19864E-09 -9.7019 0.10000E+01 0.0000 53 H2,aq 0.45563E-09 -9.3414 0.45552E-09 -9.3415 0.99976E+00 -0.0001 54 KCl,aq 0.12824E-09 -9.8920 0.12824E-09 -9.8920 0.10000E+01 0.0000 55 KHSO4,aq 0.40828E-17 -17.3890 0.40828E-17 -17.3890 0.10000E+01 0.0000 56 KOH,aq 0.18541E-07 -7.7319 0.18541E-07 -7.7319 0.10000E+01 0.0000 57 KSO4- 0.18968E-07 -7.7220 0.17847E-07 -7.7484 0.94092E+00 -0.0264 58 MgCO3,aq 0.13939E-11 -11.8558 0.13939E-11 -11.8558 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.17670E-12 -12.7528 0.16628E-12 -12.7792 0.94106E+00 -0.0264 60 MgCl+ 0.11342E-12 -12.9453 0.10673E-12 -12.9717 0.94106E+00 -0.0264 61 MgOH+ 0.18712E-09 -9.7279 0.17609E-09 -9.7543 0.94106E+00 -0.0264 63 MnO,aq 0.29195E-09 -9.5347 0.29195E-09 -9.5347 0.10000E+01 0.0000 64 MnOH+ 0.11374E-08 -8.9441 0.10703E-08 -8.9705 0.94106E+00 -0.0264 65 MnO2-2 0.74258E-14 -14.1293 0.61462E-14 -14.2114 0.82767E+00 -0.0821 66 HMnO2- 0.17968E-11 -11.7455 0.16906E-11 -11.7719 0.94092E+00 -0.0264 69 MnCl+ 0.37747E-12 -12.4231 0.35522E-12 -12.4495 0.94106E+00 -0.0264 70 MnSO4,aq 0.27070E-11 -11.5675 0.27070E-11 -11.5675 0.10000E+01 0.0000 71 NaCl,aq 0.39768E-07 -7.4005 0.39768E-07 -7.4005 0.10000E+01 0.0000 72 NaOH,aq 0.31635E-06 -6.4998 0.31635E-06 -6.4998 0.10000E+01 0.0000 74 OH- 0.48913E-03 -3.3106 0.46017E-03 -3.3371 0.94079E+00 -0.0265 79 HPO3-2 0.96151E-18 -18.0170 0.79582E-18 -18.0992 0.82767E+00 -0.0821 82 H3PO4,aq 0.61810E-14 -14.2089 0.61810E-14 -14.2089 0.10000E+01 0.0000 83 H2PO4- 0.13799E-07 -7.8602 0.12985E-07 -7.8866 0.94099E+00 -0.0264 84 PO4-3 0.54356E-09 -9.2648 0.36430E-09 -9.4385 0.67022E+00 -0.1738 87 H2P2O7-2 0.15973E-16 -16.7966 0.13220E-16 -16.8788 0.82767E+00 -0.0821 88 HP2O7-3 0.31485E-14 -14.5019 0.21025E-14 -14.6773 0.66777E+00 -0.1754 89 P2O7-4 0.80723E-15 -15.0930 0.40004E-15 -15.3979 0.49557E+00 -0.3049 90 H2S,aq 0.20998E-15 -15.6778 0.20993E-15 -15.6779 0.99976E+00 -0.0001 97 SO3-2 0.15073E-14 -14.8218 0.12490E-14 -14.9035 0.82858E+00 -0.0817 98 HSO3- 0.10435E-15 -15.9815 0.98185E-16 -16.0080 0.94092E+00 -0.0264 99 HSO4- 0.27127E-10 -10.5666 0.25530E-10 -10.5929 0.94113E+00 -0.0264 Charge balance for all species = -.5868E-14 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.1333779E-08 -.9195472E-03 -.9267511E+00 0.0000 2 H2O 0.1000000E+01 0.5550847E+02 0.9998966E+06 0.0000 3 Cl- 0.1379525E-03 0.1379925E-03 0.4891733E+01 5.0144 4 SO4-- 0.2548818E-04 0.2550792E-04 0.2450075E+01 13.1266 5 HCO3- 0.1208438E-04 0.1307173E-04 0.7975167E+00 3.9570 6 HS- 0.5749555E-13 -.7612358E-10 -.2517295E-05 -4.3656 7 Al+++ 0.1504910E-23 0.2579068E-04 0.6957981E+00 2.7056 8 H4SiO4 0.4067402E-03 0.7327437E-03 0.7042056E+02 -3.3907 9 Ca++ 0.1206362E-06 0.1290991E-06 0.5173490E-02 10.8015 10 Mg++ 0.6778226E-09 0.8717304E-09 0.2119128E-04 8.5510 11 Fe++ 0.3998914E-11 0.2419630E-08 0.1351149E-03 6.3219 12 K+ 0.5792460E-04 0.5796223E-04 0.2266201E+01 4.6376 13 Na+ 0.9825284E-03 0.9874073E-03 0.2269791E+02 5.8671 14 Mn++ 0.5372499E-09 0.1971442E-08 0.1082957E-03 8.4501 15 HPO4-- 0.6772217E-06 0.6915643E-06 0.6636868E-01 11.5510 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.1089902E-01 -.9194254E-03 -.9979596E-02 0.0000000E+00 2 H2O 0.5549999E+02 0.5550111E+02 -.1123797E-02 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.4376761E-04 0.2550455E-04 0.1826306E-04 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.1826314E-04 -.7611350E-10 -.1826306E-04 0.0000000E+00 7 Al+++ 0.2148829E-02 0.2578726E-04 0.2123041E-02 0.0000000E+00 8 H4SiO4 0.6862024E-02 0.7326467E-03 0.6129377E-02 0.0000000E+00 9 Ca++ 0.7724151E-03 0.1290820E-06 0.7722860E-03 0.0000000E+00 10 Mg++ 0.5230159E-03 0.8716149E-09 0.5230150E-03 0.0000000E+00 11 Fe++ 0.4698727E-03 0.2419310E-08 0.4698702E-03 0.0000000E+00 12 K+ 0.1399151E-03 0.5795456E-04 0.8196052E-04 0.0000000E+00 13 Na+ 0.9872766E-03 0.9872766E-03 0.0000000E+00 0.0000000E+00 14 Mn++ 0.1142613E-04 0.1971181E-08 0.1142416E-04 0.0000000E+00 15 HPO4-- 0.3899683E-05 0.6914727E-06 0.3208210E-05 0.0000000E+00 Chg. balance for solid moles: -.2243E-17 Mass of aqueous solution: 0.999973E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 0.6590000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) apatite-OH 0.1069E-05 -5.971 0.5372E-03 -3.270 0.7771E-01 0.1707E-03 clinochlore 0.1046E-03 -3.980 0.5814E-01 -1.236 8.411 0.2212E-01 daphnite 0.6475E-04 -4.189 0.4620E-01 -1.335 6.683 0.1400E-01 chlorite-Mn 0.2285E-05 -5.641 0.1620E-02 -2.791 0.2343 0.5162E-03 hematite 0.7305E-04 -4.136 0.1167E-01 -1.933 1.688 0.2211E-02 muscovite 0.8196E-04 -4.086 0.3265E-01 -1.486 4.722 0.1154E-01 stilbite 0.7669E-03 -3.115 0.5405 -0.267 78.18 0.2521 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.6094E+00 0.6094E+00 1.0000 -0.215 daphnite 0.3773E+00 0.3773E+00 1.0000 -0.423 chlorite-Mn 0.1331E-01 0.1331E-01 1.0000 -1.876 hematite 0.1000E+01 0.1000E+01 1.0000 0.000 muscovite 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 0.691290 g Volume = 0.302646 cm3 Porosity: 76.0489% V(tot) - V(min): 0.96095E+00 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.6590000 g log = -0.1811 Original solution: 1000.0103000 g Original solution / Rock added: 1517.47 (Water/Rock Ratio), log = 3.1811 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0203 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.1000E+01 0.9860 0.1006E+01 0.1020E+01 CO2,gas 0.3177E-05 1.0071 0.3264E-05 0.3241E-05 CH4,gas 0.4035E-16 1.0125 0.4169E-16 0.4117E-16 H2,gas 0.5858E-06 1.0005 0.5980E-06 0.5977E-06 H2S,gas 0.5679E-14 0.9960 0.5771E-14 0.5794E-14 S2,gas 0.3426E-35 1.0000 0.3495E-35 0.3495E-35 CO,gas 0.5099E-15 1.0000 0.5202E-15 0.5202E-15 SO3,gas 0.1233E-37 1.0000 0.1258E-37 0.1258E-37 SO2,gas 0.2868E-21 1.0000 0.2926E-21 0.2926E-21 HCl,gas 0.5165E-16 1.0000 0.5270E-16 0.5270E-16 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 32 apatite-OH -18.15 -18.15 0.00 0.000 0.60662E-11 46 clinochlore 39.07 39.07 0.00 0.000 0.36397E-10 47 daphnite 28.97 28.97 0.00 0.000 0.12132E-10 48 chlorite-Mn 46.87 46.87 0.00 0.000 0.24265E-10 90 hematite 12.57 12.57 0.00 0.000 -0.30331E-11 120 muscovite 2.58 2.58 0.00 0.000 -0.18198E-10 163 stilbite -7.52 -7.52 0.00 0.000 -0.90992E-11 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -13.85 -7.19 -2.395 0.12269E+05 -5.486 3 CH4,gas 4.54 -13.54 -18.08 -4.520 0.30869E+05 -16.380 4 H2,gas 8.00 0.08 -7.92 -4.527 0.13527E+05 -6.223 5 H2S,gas -6.23 -22.17 -15.94 -7.969 0.27213E+05 -14.239 6 S2,gas -7.34 -44.49 -37.16 -5.716 0.63442E+05 -35.457 7 CO,gas 3.21 -13.77 -16.98 -5.225 0.28998E+05 -15.284 8 SO3,gas 17.12 -22.48 -39.60 -9.900 0.67615E+05 -37.900 9 SO2,gas 0.83 -22.40 -23.23 -6.195 0.39669E+05 -21.534 10 HCl,gas 5.19 -12.79 -17.98 -8.989 0.30696E+05 -16.278 11 acmite 7.71 5.37 -2.34 -0.243 0.39971E+04 15 albite-high 0.69 -1.60 -2.29 -0.176 0.39143E+04 16 albite -0.38 -1.60 -1.22 -0.094 0.20754E+04 19 spessartine 24.46 20.59 -3.87 -0.193 0.66042E+04 20 analcite 3.32 1.79 -1.53 -0.170 0.26134E+04 21 andalusite 5.00 2.02 -2.98 -0.298 0.50899E+04 22 andradite 39.01 34.80 -4.21 -0.219 0.71887E+04 26 annite 20.12 16.14 -3.99 -0.221 0.68071E+04 27 phlogopite 27.06 22.82 -4.24 -0.236 0.72404E+04 29 anorthite 12.71 9.43 -3.28 -0.252 0.55987E+04 35 aragonite 0.97 -3.04 -4.01 -1.337 0.68476E+04 36 brucite 12.57 8.55 -4.02 -0.804 0.68599E+04 37 calcite 0.81 -3.04 -3.86 -1.285 0.65834E+04 38 carnegieite-low 9.02 5.18 -3.84 -0.549 0.65589E+04 39 carnegieite-high 10.09 5.18 -4.91 -0.702 0.83859E+04 40 carpholite-Mg 8.58 7.18 -1.40 -0.093 0.23926E+04 41 carpholite-Fe 6.71 4.95 -1.76 -0.117 0.30067E+04 42 celadonite 5.34 2.33 -3.01 -0.177 0.51397E+04 43 celadonite-Fe 3.88 0.10 -3.77 -0.222 0.64443E+04 50 chloritoid-Mg 13.20 10.57 -2.63 -0.175 0.44841E+04 51 chloritoid-Fe 9.17 8.34 -0.83 -0.055 0.14193E+04 52 chloritoid-Mn 11.40 10.47 -0.93 -0.062 0.15887E+04 54 coesite -2.38 -3.39 -1.01 -0.338 0.17324E+04 59 corundum 8.38 5.41 -2.97 -0.270 0.50744E+04 61 cristobalite -2.56 -3.39 -0.83 -0.277 0.14178E+04 63 cymrite-K 1.69 -2.83 -4.51 -0.376 0.77079E+04 65 diaspore 2.87 2.71 -0.17 -0.028 0.28700E+03 67 diopside 16.18 12.57 -3.61 -0.361 0.61644E+04 68 hedenbergite 14.21 10.34 -3.87 -0.387 0.66016E+04 75 epidote 24.67 23.13 -1.54 -0.075 0.26374E+04 76 clinozoisite 22.81 19.55 -3.26 -0.148 0.55633E+04 77 epidote-Fe 29.84 26.70 -3.14 -0.163 0.53581E+04 78 fayalite 14.05 9.25 -4.79 -0.685 0.81834E+04 83 gibbsite 4.08 2.71 -1.37 -0.196 0.23455E+04 87 greenalite 16.14 12.18 -3.96 -0.330 0.67536E+04 91 heulandite -5.83 -7.52 -1.69 -0.077 0.28938E+04 95 jadeite 4.22 1.79 -2.42 -0.242 0.41389E+04 97 kalsilite 7.58 3.95 -3.63 -0.519 0.62004E+04 98 kaolinite -1.33 -1.37 -0.04 -0.003 0.63807E+02 99 kyanite 4.88 2.02 -2.86 -0.286 0.48758E+04 101 laumontite 2.88 2.65 -0.23 -0.016 0.39855E+03 102 lawsonite 9.62 9.43 -0.18 -0.012 0.31539E+03 103 leucite 4.12 0.56 -3.56 -0.356 0.60734E+04 105 lizardite 23.24 18.87 -4.37 -0.364 0.74655E+04 107 magnetite 20.09 18.89 -1.20 -0.098 0.20479E+04 108 minnesotaite 10.39 5.40 -4.99 -0.293 0.85122E+04 113 margarite 17.32 14.84 -2.48 -0.099 0.42363E+04 116 microcline -2.49 -2.83 -0.34 -0.026 0.58447E+03 121 paragonite 4.24 3.81 -0.43 -0.025 0.73008E+03 122 nepheline 8.34 5.18 -3.16 -0.451 0.53913E+04 136 prehnite 19.37 16.84 -2.53 -0.149 0.43194E+04 137 prehnite-Fe 22.50 20.42 -2.08 -0.125 0.35485E+04 138 pumpellyite-Fe 46.27 42.71 -3.56 -0.079 0.60745E+04 139 pumpellyite-Mg 48.99 44.94 -4.05 -0.090 0.69219E+04 145 pyroxmangite 7.40 5.06 -2.34 -0.468 0.39942E+04 146 pyrophyllite -6.18 -8.15 -1.98 -0.123 0.33735E+04 147 quartz -2.99 -3.39 -0.40 -0.134 0.68512E+03 151 rhodochrosite -0.98 -5.40 -4.42 -1.473 0.75452E+04 152 rhodonite 7.45 5.06 -2.39 -0.477 0.40745E+04 153 sanidine -1.28 -2.83 -1.55 -0.119 0.26522E+04 155 siderite -2.61 -7.52 -4.92 -1.638 0.83928E+04 156 sillimanite 5.26 2.02 -3.24 -0.324 0.55339E+04 164 stilpnomelane-Fe 13.02 12.21 -0.80 -0.024 0.13713E+04 165 stilpnomelane-Mg 27.44 23.36 -4.08 -0.122 0.69697E+04 168 sudoite 21.08 17.75 -3.32 -0.107 0.56773E+04 171 talc 16.49 12.09 -4.40 -0.259 0.75143E+04 174 tephroite 18.09 13.51 -4.58 -0.654 0.78138E+04 177 topaz-H 4.62 2.02 -2.60 -0.236 0.44359E+04 178 tridymite -2.63 -3.39 -0.76 -0.255 0.13051E+04 187 wairakite 3.95 2.65 -1.30 -0.076 0.22205E+04 188 walstromite 11.51 7.41 -4.10 -0.820 0.69979E+04 189 wollastonite 10.46 7.41 -3.05 -0.610 0.52084E+04 190 pseudo-wollastonite 11.00 7.41 -3.59 -0.718 0.61282E+04 191 zoisite 22.85 19.55 -3.30 -0.150 0.56374E+04 192 akaganeite 7.75 6.28 -1.47 -0.318 0.25125E+04 193 beidellite-Ca -1.65 -4.36 -2.71 -0.168 0.46305E+04 194 beidellite-H -2.33 -6.14 -3.81 -0.243 0.65114E+04 195 beidellite-K -1.52 -4.61 -3.09 -0.189 0.52745E+04 196 beidellite-Mg -1.79 -4.73 -2.94 -0.182 0.50183E+04 197 beidellite-Na -1.34 -4.20 -2.86 -0.175 0.48857E+04 199 chalcedony -2.80 -3.39 -0.59 -0.196 0.10044E+04 201 montmorillonite-Ca -2.29 -4.44 -2.15 -0.133 0.36703E+04 202 montmorillonite-K -2.24 -4.69 -2.46 -0.150 0.41925E+04 203 montmorillonite-Mg -2.48 -4.81 -2.33 -0.144 0.39814E+04 204 montmorillonite-Na -2.04 -4.29 -2.25 -0.138 0.38394E+04 205 nontronite-Ca 3.21 2.80 -0.42 -0.027 0.71212E+03 206 nontronite-H 2.53 1.02 -1.52 -0.102 0.25910E+04 207 nontronite-K 3.34 2.55 -0.80 -0.051 0.13575E+04 208 nontronite-Mg 3.07 2.43 -0.65 -0.042 0.11073E+04 209 nontronite-Na 3.52 2.95 -0.57 -0.036 0.97043E+03 224 tobermorite 9.82 5.61 -4.22 -1.150 0.71988E+04 233 boehmite 4.41 2.71 -1.70 -0.283 0.29039E+04 235 ferrous-oxide 9.81 6.32 -3.49 -0.872 0.59586E+04 240 silica-amorphous -2.09 -3.39 -1.30 -0.433 0.22186E+04 242 an20ab80 2.02 0.61 -1.41 -0.109 0.24093E+04 243 an25ab75 2.65 1.16 -1.49 -0.114 0.25397E+04 244 an30ab70 3.28 1.71 -1.57 -0.121 0.26797E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 0.0200000 g Current total amount of reactant added: 0.6590000 g New total amount of reactant added: 0.6790000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.5867E-14 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 7 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 0.6790000 Water: Moles liquid = 0.5550E+02 kg liquid = 0.9999E+00 Moles total = 0.5550E+02 kg total = 0.9998E+00 Activity = 1.0000 Stoichiometric ionic strength = .7791489E-03 Osmotic coef. = 0.9837 True ionic strength = .1094074E-02 Chg. balance for total moles = -.5867E-14 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.13037E-08 -8.8848 0.12266E-08 -8.9113 0.94089E+00 -0.0265 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13795E-03 -3.8603 0.12974E-03 -3.8869 0.94045E+00 -0.0267 4 SO4-- 0.25488E-04 -4.5937 0.21057E-04 -4.6766 0.82617E+00 -0.0829 5 HCO3- 0.12063E-04 -4.9185 0.11346E-04 -4.9452 0.94056E+00 -0.0266 6 HS- 0.56986E-13 -13.2442 0.53593E-13 -13.2709 0.94046E+00 -0.0267 7 Al+++ 0.13623E-23 -23.8657 0.90560E-24 -24.0431 0.66476E+00 -0.1773 8 H4SiO4 0.41470E-03 -3.3823 0.41470E-03 -3.3823 0.10000E+01 0.0000 9 Ca++ 0.10783E-06 -6.9673 0.89033E-07 -7.0504 0.82571E+00 -0.0832 10 Mg++ 0.64951E-09 -9.1874 0.53612E-09 -9.2707 0.82542E+00 -0.0833 11 Fe++ 0.38319E-11 -11.4166 0.31632E-11 -11.4999 0.82549E+00 -0.0833 12 K+ 0.59164E-04 -4.2279 0.55648E-04 -4.2545 0.94058E+00 -0.0266 13 Na+ 0.10073E-02 -2.9968 0.94732E-03 -3.0235 0.94044E+00 -0.0267 14 Mn++ 0.51481E-09 -9.2884 0.42500E-09 -9.3716 0.82555E+00 -0.0833 15 HPO4-- 0.79576E-06 -6.0992 0.65744E-06 -6.1821 0.82618E+00 -0.0829 16 HSiO3- 0.33568E-03 -3.4741 0.31569E-03 -3.5007 0.94045E+00 -0.0267 17 Ca(HSiO3)+ 0.68052E-09 -9.1672 0.64009E-09 -9.1938 0.94059E+00 -0.0266 18 Mg(HSiO3)+ 0.50998E-11 -11.2924 0.47968E-11 -11.3190 0.94059E+00 -0.0266 19 NaHSiO3,aq 0.48368E-05 -5.3154 0.48368E-05 -5.3154 0.10000E+01 0.0000 20 AlO+ 0.87057E-13 -13.0602 0.81885E-13 -13.0868 0.94059E+00 -0.0266 21 AlOH+2 0.60577E-18 -18.2177 0.50013E-18 -18.3009 0.82561E+00 -0.0832 22 HAlO2,aq 0.13295E-07 -7.8763 0.13295E-07 -7.8763 0.10000E+01 0.0000 23 AlO2- 0.25515E-04 -4.5932 0.23992E-04 -4.6199 0.94032E+00 -0.0267 24 CH4,aq 0.28057E-19 -19.5520 0.28050E-19 -19.5521 0.99976E+00 -0.0001 29 CO,aq 0.34164E-18 -18.4664 0.34164E-18 -18.4664 0.10000E+01 0.0000 30 CO2,aq 0.29744E-07 -7.5266 0.29737E-07 -7.5267 0.99976E+00 -0.0001 31 CO3-2 0.97810E-06 -6.0096 0.80794E-06 -6.0926 0.82604E+00 -0.0830 32 CaCO3,aq 0.90196E-09 -9.0448 0.90196E-09 -9.0448 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.27414E-10 -10.5620 0.25785E-10 -10.5886 0.94059E+00 -0.0266 34 CaCl+ 0.19874E-10 -10.7017 0.18693E-10 -10.7283 0.94059E+00 -0.0266 35 CaCl2,aq 0.57617E-15 -15.2394 0.57617E-15 -15.2394 0.10000E+01 0.0000 36 CaOH+ 0.54998E-08 -8.2597 0.51731E-08 -8.2863 0.94059E+00 -0.0266 37 CaSO4,aq 0.59534E-09 -9.2252 0.59534E-09 -9.2252 0.10000E+01 0.0000 38 HCl,aq 0.29161E-13 -13.5352 0.29161E-13 -13.5352 0.10000E+01 0.0000 43 FeCl+ 0.69059E-15 -15.1608 0.64957E-15 -15.1874 0.94059E+00 -0.0266 46 FeO,aq 0.81711E-10 -10.0877 0.81711E-10 -10.0877 0.10000E+01 0.0000 47 FeOH+ 0.89245E-10 -10.0494 0.83943E-10 -10.0760 0.94059E+00 -0.0266 48 HFeO2- 0.74114E-09 -9.1301 0.69701E-09 -9.1568 0.94045E+00 -0.0267 49 FeO+ 0.99539E-14 -14.0020 0.93625E-14 -14.0286 0.94059E+00 -0.0266 51 FeO2- 0.13539E-08 -8.8684 0.12733E-08 -8.8951 0.94045E+00 -0.0267 52 HFeO2,aq 0.19864E-09 -9.7019 0.19864E-09 -9.7019 0.10000E+01 0.0000 53 H2,aq 0.45744E-09 -9.3397 0.45733E-09 -9.3398 0.99976E+00 -0.0001 54 KCl,aq 0.13085E-09 -9.8832 0.13085E-09 -9.8832 0.10000E+01 0.0000 55 KHSO4,aq 0.40639E-17 -17.3911 0.40639E-17 -17.3911 0.10000E+01 0.0000 56 KOH,aq 0.19375E-07 -7.7128 0.19375E-07 -7.7128 0.10000E+01 0.0000 57 KSO4- 0.19335E-07 -7.7137 0.18184E-07 -7.7403 0.94045E+00 -0.0267 58 MgCO3,aq 0.13614E-11 -11.8660 0.13614E-11 -11.8660 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.16868E-12 -12.7729 0.15866E-12 -12.7995 0.94059E+00 -0.0266 60 MgCl+ 0.10846E-12 -12.9647 0.10202E-12 -12.9913 0.94059E+00 -0.0266 61 MgOH+ 0.18326E-09 -9.7369 0.17237E-09 -9.7635 0.94059E+00 -0.0266 63 MnO,aq 0.29253E-09 -9.5338 0.29253E-09 -9.5338 0.10000E+01 0.0000 64 MnOH+ 0.11139E-08 -8.9532 0.10477E-08 -8.9798 0.94059E+00 -0.0266 65 MnO2-2 0.78115E-14 -14.1073 0.64526E-14 -14.1903 0.82604E+00 -0.0830 66 HMnO2- 0.18438E-11 -11.7343 0.17340E-11 -11.7609 0.94045E+00 -0.0267 69 MnCl+ 0.36098E-12 -12.4425 0.33954E-12 -12.4691 0.94059E+00 -0.0266 70 MnSO4,aq 0.25836E-11 -11.5878 0.25836E-11 -11.5878 0.10000E+01 0.0000 71 NaCl,aq 0.40730E-07 -7.3901 0.40730E-07 -7.3901 0.10000E+01 0.0000 72 NaOH,aq 0.33182E-06 -6.4791 0.33182E-06 -6.4791 0.10000E+01 0.0000 74 OH- 0.50093E-03 -3.3002 0.47104E-03 -3.3269 0.94032E+00 -0.0267 79 HPO3-2 0.11343E-17 -17.9453 0.93699E-18 -18.0283 0.82604E+00 -0.0830 82 H3PO4,aq 0.69181E-14 -14.1600 0.69181E-14 -14.1600 0.10000E+01 0.0000 83 H2PO4- 0.15817E-07 -7.8009 0.14876E-07 -7.8275 0.94052E+00 -0.0266 84 PO4-3 0.65535E-09 -9.1835 0.43731E-09 -9.3592 0.66729E+00 -0.1757 87 H2P2O7-2 0.21007E-16 -16.6776 0.17353E-16 -16.7606 0.82604E+00 -0.0830 88 HP2O7-3 0.42492E-14 -14.3717 0.28248E-14 -14.5490 0.66479E+00 -0.1773 89 P2O7-4 0.11190E-14 -14.9512 0.55016E-15 -15.2595 0.49167E+00 -0.3083 90 H2S,aq 0.20322E-15 -15.6920 0.20317E-15 -15.6921 0.99976E+00 -0.0001 97 SO3-2 0.15133E-14 -14.8201 0.12515E-14 -14.9026 0.82696E+00 -0.0825 98 HSO3- 0.10220E-15 -15.9906 0.96112E-16 -16.0172 0.94045E+00 -0.0267 99 HSO4- 0.26462E-10 -10.5774 0.24892E-10 -10.6039 0.94066E+00 -0.0266 Charge balance for all species = -.5874E-14 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.1303663E-08 -.9448427E-03 -.9522422E+00 0.0000 2 H2O 0.1000000E+01 0.5550846E+02 0.9998939E+06 0.0000 3 Cl- 0.1379521E-03 0.1379930E-03 0.4891738E+01 5.0244 4 SO4-- 0.2548799E-04 0.2550803E-04 0.2450078E+01 13.1460 5 HCO3- 0.1206301E-04 0.1307178E-04 0.7975176E+00 3.9661 6 HS- 0.5698610E-13 -.7965472E-10 -.2634057E-05 -4.3596 7 Al+++ 0.1362288E-23 0.2552808E-04 0.6887118E+00 2.6908 8 H4SiO4 0.4147025E-03 0.7552174E-03 0.7258021E+02 -3.3823 9 Ca++ 0.1078253E-06 0.1155502E-06 0.4630523E-02 10.7721 10 Mg++ 0.6495083E-09 0.8395035E-09 0.2040781E-04 8.5519 11 Fe++ 0.3831862E-11 0.2468517E-08 0.1378444E-03 6.3227 12 K+ 0.5916385E-04 0.5920269E-04 0.2314694E+01 4.6567 13 Na+ 0.1007310E-02 0.1012519E-02 0.2327511E+02 5.8878 14 Mn++ 0.5148105E-09 0.1926044E-08 0.1058016E-03 8.4510 15 HPO4-- 0.7957620E-06 0.8122345E-06 0.7794906E-01 11.6405 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.1123019E-01 -.9447139E-03 -.1028548E-01 0.0000000E+00 2 H2O 0.5549974E+02 0.5550090E+02 -.1157169E-02 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.4432187E-04 0.2550455E-04 0.1881733E-04 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.1881740E-04 -.7964386E-10 -.1881733E-04 0.0000000E+00 7 Al+++ 0.2214044E-02 0.2552460E-04 0.2188519E-02 0.0000000E+00 8 H4SiO4 0.7070280E-02 0.7551145E-03 0.6315165E-02 0.0000000E+00 9 Ca++ 0.7954179E-03 0.1155345E-06 0.7953024E-03 0.0000000E+00 10 Mg++ 0.5388889E-03 0.8393890E-09 0.5388880E-03 0.0000000E+00 11 Fe++ 0.4841328E-03 0.2468180E-08 0.4841304E-03 0.0000000E+00 12 K+ 0.1441614E-03 0.5919462E-04 0.8496674E-04 0.0000000E+00 13 Na+ 0.1012381E-02 0.1012381E-02 0.0000000E+00 0.0000000E+00 14 Mn++ 0.1177291E-04 0.1925782E-08 0.1177098E-04 0.0000000E+00 15 HPO4-- 0.4018035E-05 0.8121238E-06 0.3205911E-05 0.0000000E+00 Chg. balance for solid moles: -.2206E-17 Mass of aqueous solution: 0.999971E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 0.6790000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) apatite-OH 0.1069E-05 -5.971 0.5368E-03 -3.270 0.7536E-01 0.1706E-03 clinochlore 0.1078E-03 -3.967 0.5991E-01 -1.223 8.410 0.2279E-01 daphnite 0.6672E-04 -4.176 0.4760E-01 -1.322 6.683 0.1443E-01 chlorite-Mn 0.2354E-05 -5.628 0.1669E-02 -2.778 0.2343 0.5319E-03 hematite 0.7527E-04 -4.123 0.1202E-01 -1.920 1.688 0.2278E-02 muscovite 0.8497E-04 -4.071 0.3384E-01 -1.471 4.751 0.1197E-01 stilbite 0.7900E-03 -3.102 0.5567 -0.254 78.16 0.2597 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.6094E+00 0.6094E+00 1.0000 -0.215 daphnite 0.3773E+00 0.3773E+00 1.0000 -0.423 chlorite-Mn 0.1331E-01 0.1331E-01 1.0000 -1.876 hematite 0.1000E+01 0.1000E+01 1.0000 0.000 muscovite 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 0.712280 g Volume = 0.311815 cm3 Porosity: 75.4785% V(tot) - V(min): 0.95979E+00 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.6790000 g log = -0.1681 Original solution: 1000.0103000 g Original solution / Rock added: 1472.77 (Water/Rock Ratio), log = 3.1681 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0203 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.1000E+01 0.9860 0.1006E+01 0.1020E+01 CO2,gas 0.3096E-05 1.0071 0.3182E-05 0.3159E-05 CH4,gas 0.3997E-16 1.0125 0.4129E-16 0.4078E-16 H2,gas 0.5882E-06 1.0005 0.6004E-06 0.6001E-06 H2S,gas 0.5496E-14 0.9960 0.5585E-14 0.5607E-14 S2,gas 0.3183E-35 1.0000 0.3248E-35 0.3248E-35 CO,gas 0.4990E-15 1.0000 0.5091E-15 0.5091E-15 SO3,gas 0.1174E-37 1.0000 0.1198E-37 0.1198E-37 SO2,gas 0.2743E-21 1.0000 0.2798E-21 0.2798E-21 HCl,gas 0.5043E-16 1.0000 0.5146E-16 0.5146E-16 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 32 apatite-OH -18.15 -18.15 0.00 0.000 0.00000E+00 46 clinochlore 39.07 39.07 0.00 0.000 0.00000E+00 47 daphnite 28.97 28.97 0.00 0.000 -0.12132E-10 48 chlorite-Mn 46.87 46.87 0.00 0.000 -0.24265E-10 90 hematite 12.57 12.57 0.00 0.000 0.30331E-11 120 muscovite 2.58 2.58 0.00 0.000 0.60662E-11 163 stilbite -7.52 -7.52 0.00 0.000 -0.33364E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -13.86 -7.20 -2.399 0.12288E+05 -5.497 3 CH4,gas 4.54 -13.54 -18.08 -4.521 0.30876E+05 -16.384 4 H2,gas 8.00 0.08 -7.92 -4.526 0.13524E+05 -6.222 5 H2S,gas -6.23 -22.18 -15.95 -7.976 0.27238E+05 -14.253 6 S2,gas -7.34 -44.52 -37.19 -5.721 0.63496E+05 -35.488 7 CO,gas 3.21 -13.78 -16.99 -5.228 0.29014E+05 -15.293 8 SO3,gas 17.12 -22.50 -39.62 -9.905 0.67651E+05 -37.922 9 SO2,gas 0.83 -22.42 -23.25 -6.201 0.39702E+05 -21.553 10 HCl,gas 5.19 -12.80 -17.99 -8.994 0.30713E+05 -16.289 11 acmite 7.71 5.41 -2.30 -0.239 0.39329E+04 15 albite-high 0.69 -1.57 -2.26 -0.174 0.38610E+04 16 albite -0.38 -1.57 -1.18 -0.091 0.20222E+04 19 spessartine 24.46 20.59 -3.87 -0.193 0.66071E+04 20 analcite 3.32 1.81 -1.51 -0.168 0.25745E+04 21 andalusite 5.00 2.00 -3.00 -0.300 0.51261E+04 22 andradite 39.01 34.74 -4.27 -0.222 0.72959E+04 26 annite 20.12 16.17 -3.95 -0.220 0.67521E+04 27 phlogopite 27.06 22.86 -4.21 -0.234 0.71855E+04 29 anorthite 12.71 9.39 -3.32 -0.255 0.56706E+04 35 aragonite 0.97 -3.08 -4.05 -1.350 0.69167E+04 36 brucite 12.57 8.55 -4.02 -0.803 0.68584E+04 37 calcite 0.81 -3.08 -3.90 -1.299 0.66525E+04 38 carnegieite-low 9.02 5.20 -3.83 -0.547 0.65344E+04 39 carnegieite-high 10.09 5.20 -4.90 -0.700 0.83614E+04 40 carpholite-Mg 8.58 7.17 -1.41 -0.094 0.24129E+04 41 carpholite-Fe 6.71 4.94 -1.77 -0.118 0.30270E+04 42 celadonite 5.34 2.37 -2.97 -0.175 0.50733E+04 43 celadonite-Fe 3.88 0.14 -3.74 -0.220 0.63779E+04 50 chloritoid-Mg 13.20 10.55 -2.65 -0.176 0.45188E+04 51 chloritoid-Fe 9.17 8.32 -0.85 -0.057 0.14539E+04 52 chloritoid-Mn 11.40 10.45 -0.95 -0.063 0.16233E+04 54 coesite -2.38 -3.38 -1.01 -0.335 0.17181E+04 59 corundum 8.38 5.38 -3.00 -0.273 0.51249E+04 61 cristobalite -2.56 -3.38 -0.82 -0.274 0.14034E+04 63 cymrite-K 1.69 -2.80 -4.48 -0.374 0.76574E+04 65 diaspore 2.87 2.69 -0.18 -0.030 0.31225E+03 67 diopside 16.18 12.56 -3.62 -0.362 0.61843E+04 68 hedenbergite 14.21 10.33 -3.88 -0.388 0.66215E+04 75 epidote 24.67 23.06 -1.61 -0.078 0.27451E+04 76 clinozoisite 22.81 19.47 -3.34 -0.152 0.56962E+04 77 epidote-Fe 29.84 26.65 -3.19 -0.166 0.54405E+04 78 fayalite 14.05 9.26 -4.78 -0.683 0.81661E+04 83 gibbsite 4.08 2.69 -1.39 -0.198 0.23708E+04 87 greenalite 16.14 12.20 -3.94 -0.328 0.67204E+04 91 heulandite -5.83 -7.52 -1.69 -0.077 0.28938E+04 95 jadeite 4.22 1.81 -2.40 -0.240 0.41000E+04 97 kalsilite 7.58 3.97 -3.62 -0.517 0.61787E+04 98 kaolinite -1.33 -1.38 -0.05 -0.005 0.85559E+02 99 kyanite 4.88 2.00 -2.88 -0.288 0.49120E+04 101 laumontite 2.88 2.62 -0.26 -0.017 0.44168E+03 102 lawsonite 9.62 9.39 -0.23 -0.015 0.38727E+03 103 leucite 4.12 0.58 -3.54 -0.354 0.60373E+04 105 lizardite 23.24 18.89 -4.35 -0.363 0.74323E+04 107 magnetite 20.09 18.89 -1.20 -0.098 0.20464E+04 108 minnesotaite 10.39 5.44 -4.95 -0.291 0.84503E+04 113 margarite 17.32 14.77 -2.55 -0.102 0.43587E+04 116 microcline -2.49 -2.80 -0.31 -0.024 0.53397E+03 121 paragonite 4.24 3.81 -0.43 -0.025 0.72731E+03 122 nepheline 8.34 5.20 -3.14 -0.449 0.53668E+04 136 prehnite 19.37 16.78 -2.59 -0.153 0.44270E+04 137 prehnite-Fe 22.50 20.37 -2.13 -0.128 0.36309E+04 138 pumpellyite-Fe 46.27 42.57 -3.70 -0.082 0.63135E+04 139 pumpellyite-Mg 48.99 44.80 -4.19 -0.093 0.71610E+04 145 pyroxmangite 7.40 5.07 -2.33 -0.466 0.39783E+04 146 pyrophyllite -6.18 -8.15 -1.97 -0.123 0.33665E+04 147 quartz -2.99 -3.38 -0.39 -0.131 0.67074E+03 151 rhodochrosite -0.98 -5.41 -4.43 -1.476 0.75627E+04 152 rhodonite 7.45 5.07 -2.38 -0.475 0.40586E+04 153 sanidine -1.28 -2.80 -1.52 -0.117 0.26017E+04 155 siderite -2.61 -7.53 -4.93 -1.642 0.84103E+04 156 sillimanite 5.26 2.00 -3.26 -0.326 0.55700E+04 164 stilpnomelane-Fe 13.02 12.27 -0.75 -0.022 0.12831E+04 165 stilpnomelane-Mg 27.44 23.41 -4.03 -0.120 0.68815E+04 168 sudoite 21.08 17.72 -3.36 -0.108 0.57322E+04 171 talc 16.49 12.13 -4.36 -0.257 0.74524E+04 174 tephroite 18.09 13.52 -4.57 -0.652 0.77965E+04 177 topaz-H 4.62 2.00 -2.62 -0.238 0.44720E+04 178 tridymite -2.63 -3.38 -0.76 -0.252 0.12907E+04 187 wairakite 3.95 2.62 -1.33 -0.078 0.22636E+04 188 walstromite 11.51 7.39 -4.12 -0.824 0.70337E+04 189 wollastonite 10.46 7.39 -3.07 -0.614 0.52441E+04 190 pseudo-wollastonite 11.00 7.39 -3.61 -0.722 0.61639E+04 191 zoisite 22.85 19.47 -3.38 -0.154 0.57703E+04 192 akaganeite 7.75 6.28 -1.47 -0.318 0.25125E+04 193 beidellite-Ca -1.65 -4.37 -2.72 -0.168 0.46448E+04 194 beidellite-H -2.33 -6.14 -3.82 -0.244 0.65175E+04 195 beidellite-K -1.52 -4.61 -3.09 -0.189 0.52698E+04 196 beidellite-Mg -1.79 -4.73 -2.94 -0.182 0.50242E+04 197 beidellite-Na -1.34 -4.20 -2.86 -0.175 0.48801E+04 199 chalcedony -2.80 -3.38 -0.58 -0.193 0.99004E+03 201 montmorillonite-Ca -2.29 -4.44 -2.15 -0.133 0.36628E+04 202 montmorillonite-K -2.24 -4.68 -2.44 -0.149 0.41659E+04 203 montmorillonite-Mg -2.48 -4.80 -2.32 -0.144 0.39653E+04 204 montmorillonite-Na -2.04 -4.27 -2.23 -0.137 0.38119E+04 205 nontronite-Ca 3.21 2.82 -0.40 -0.026 0.67597E+03 206 nontronite-H 2.53 1.04 -1.49 -0.100 0.25466E+04 207 nontronite-K 3.34 2.58 -0.76 -0.049 0.13023E+04 208 nontronite-Mg 3.07 2.45 -0.62 -0.040 0.10626E+04 209 nontronite-Na 3.52 2.98 -0.54 -0.034 0.91432E+03 224 tobermorite 9.82 5.59 -4.23 -1.155 0.72262E+04 233 boehmite 4.41 2.69 -1.72 -0.286 0.29292E+04 235 ferrous-oxide 9.81 6.32 -3.49 -0.872 0.59571E+04 240 silica-amorphous -2.09 -3.38 -1.29 -0.430 0.22042E+04 242 an20ab80 2.02 0.62 -1.39 -0.107 0.23810E+04 243 an25ab75 2.65 1.17 -1.47 -0.113 0.25177E+04 244 an30ab70 3.28 1.72 -1.56 -0.120 0.26640E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 0.0200000 g Current total amount of reactant added: 0.6790000 g New total amount of reactant added: 0.6990000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.5867E-14 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 7 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 0.6990000 Water: Moles liquid = 0.5550E+02 kg liquid = 0.9999E+00 Moles total = 0.5550E+02 kg total = 0.9998E+00 Activity = 1.0000 Stoichiometric ionic strength = .7914506E-03 Osmotic coef. = 0.9836 True ionic strength = .1120223E-02 Chg. balance for total moles = -.5867E-14 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.12752E-08 -8.8944 0.11992E-08 -8.9211 0.94043E+00 -0.0267 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13795E-03 -3.8603 0.12967E-03 -3.8872 0.93999E+00 -0.0269 4 SO4-- 0.25488E-04 -4.5937 0.21016E-04 -4.6774 0.82456E+00 -0.0838 5 HCO3- 0.12042E-04 -4.9193 0.11320E-04 -4.9461 0.94009E+00 -0.0268 6 HS- 0.56544E-13 -13.2476 0.53152E-13 -13.2745 0.94000E+00 -0.0269 7 Al+++ 0.12373E-23 -23.9075 0.81887E-24 -24.0868 0.66183E+00 -0.1793 8 H4SiO4 0.42248E-03 -3.3742 0.42248E-03 -3.3742 0.10000E+01 0.0000 9 Ca++ 0.96851E-07 -7.0139 0.79814E-07 -7.0979 0.82409E+00 -0.0840 10 Mg++ 0.62333E-09 -9.2053 0.51350E-09 -9.2895 0.82380E+00 -0.0842 11 Fe++ 0.36774E-11 -11.4345 0.30297E-11 -11.5186 0.82387E+00 -0.0841 12 K+ 0.60421E-04 -4.2188 0.56803E-04 -4.2456 0.94011E+00 -0.0268 13 Na+ 0.10321E-02 -2.9863 0.97013E-03 -3.0132 0.93998E+00 -0.0269 14 Mn++ 0.49406E-09 -9.3062 0.40707E-09 -9.3903 0.82392E+00 -0.0841 15 HPO4-- 0.92827E-06 -6.0323 0.76543E-06 -6.1161 0.82457E+00 -0.0838 16 HSiO3- 0.34995E-03 -3.4560 0.32895E-03 -3.4829 0.93999E+00 -0.0269 17 Ca(HSiO3)+ 0.63600E-09 -9.1965 0.59793E-09 -9.2234 0.94013E+00 -0.0268 18 Mg(HSiO3)+ 0.50923E-11 -11.2931 0.47874E-11 -11.3199 0.94013E+00 -0.0268 19 NaHSiO3,aq 0.51614E-05 -5.2872 0.51614E-05 -5.2872 0.10000E+01 0.0000 20 AlO+ 0.82395E-13 -13.0841 0.77462E-13 -13.1109 0.94013E+00 -0.0268 21 AlOH+2 0.56137E-18 -18.2508 0.46256E-18 -18.3348 0.82398E+00 -0.0841 22 HAlO2,aq 0.12864E-07 -7.8906 0.12864E-07 -7.8906 0.10000E+01 0.0000 23 AlO2- 0.25264E-04 -4.5975 0.23744E-04 -4.6244 0.93985E+00 -0.0269 24 CH4,aq 0.27818E-19 -19.5557 0.27811E-19 -19.5558 0.99975E+00 -0.0001 29 CO,aq 0.33462E-18 -18.4754 0.33462E-18 -18.4754 0.10000E+01 0.0000 30 CO2,aq 0.29015E-07 -7.5374 0.29008E-07 -7.5375 0.99975E+00 -0.0001 31 CO3-2 0.10001E-05 -5.9999 0.82453E-06 -6.0838 0.82442E+00 -0.0839 32 CaCO3,aq 0.82518E-09 -9.0835 0.82518E-09 -9.0835 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.24532E-10 -10.6103 0.23064E-10 -10.6371 0.94013E+00 -0.0268 34 CaCl+ 0.17816E-10 -10.7492 0.16749E-10 -10.7760 0.94013E+00 -0.0268 35 CaCl2,aq 0.51600E-15 -15.2874 0.51600E-15 -15.2874 0.10000E+01 0.0000 36 CaOH+ 0.50454E-08 -8.2971 0.47433E-08 -8.3239 0.94013E+00 -0.0268 37 CaSO4,aq 0.53265E-09 -9.2736 0.53265E-09 -9.2736 0.10000E+01 0.0000 38 HCl,aq 0.28496E-13 -13.5452 0.28496E-13 -13.5452 0.10000E+01 0.0000 43 FeCl+ 0.66145E-15 -15.1795 0.62185E-15 -15.2063 0.94013E+00 -0.0268 46 FeO,aq 0.81877E-10 -10.0868 0.81877E-10 -10.0868 0.10000E+01 0.0000 47 FeOH+ 0.87473E-10 -10.0581 0.82236E-10 -10.0849 0.94013E+00 -0.0268 48 HFeO2- 0.75998E-09 -9.1192 0.71437E-09 -9.1461 0.93999E+00 -0.0269 49 FeO+ 0.97365E-14 -14.0116 0.91536E-14 -14.0384 0.94013E+00 -0.0268 51 FeO2- 0.13855E-08 -8.8584 0.13024E-08 -8.8853 0.93999E+00 -0.0269 52 HFeO2,aq 0.19864E-09 -9.7019 0.19864E-09 -9.7019 0.10000E+01 0.0000 53 H2,aq 0.45931E-09 -9.3379 0.45920E-09 -9.3380 0.99975E+00 -0.0001 54 KCl,aq 0.13350E-09 -9.8745 0.13350E-09 -9.8745 0.10000E+01 0.0000 55 KHSO4,aq 0.40477E-17 -17.3928 0.40477E-17 -17.3928 0.10000E+01 0.0000 56 KOH,aq 0.20228E-07 -7.6940 0.20228E-07 -7.6940 0.10000E+01 0.0000 57 KSO4- 0.19707E-07 -7.7054 0.18525E-07 -7.7323 0.93999E+00 -0.0269 58 MgCO3,aq 0.13307E-11 -11.8759 0.13307E-11 -11.8759 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.16128E-12 -12.7924 0.15162E-12 -12.8192 0.94013E+00 -0.0268 60 MgCl+ 0.10389E-12 -12.9834 0.97666E-13 -13.0103 0.94013E+00 -0.0268 61 MgOH+ 0.17962E-09 -9.7456 0.16887E-09 -9.7725 0.94013E+00 -0.0268 63 MnO,aq 0.29313E-09 -9.5329 0.29313E-09 -9.5329 0.10000E+01 0.0000 64 MnOH+ 0.10918E-08 -8.9619 0.10264E-08 -8.9887 0.94013E+00 -0.0268 65 MnO2-2 0.82050E-14 -14.0859 0.67644E-14 -14.1698 0.82442E+00 -0.0839 66 HMnO2- 0.18907E-11 -11.7234 0.17772E-11 -11.7503 0.93999E+00 -0.0269 69 MnCl+ 0.34575E-12 -12.4612 0.32505E-12 -12.4880 0.94013E+00 -0.0268 70 MnSO4,aq 0.24698E-11 -11.6073 0.24698E-11 -11.6073 0.10000E+01 0.0000 71 NaCl,aq 0.41690E-07 -7.3800 0.41690E-07 -7.3800 0.10000E+01 0.0000 72 NaOH,aq 0.34757E-06 -6.4590 0.34757E-06 -6.4590 0.10000E+01 0.0000 74 OH- 0.51262E-03 -3.2902 0.48179E-03 -3.3171 0.93985E+00 -0.0269 79 HPO3-2 0.13286E-17 -17.8766 0.10953E-17 -17.9605 0.82442E+00 -0.0839 82 H3PO4,aq 0.76989E-14 -14.1136 0.76989E-14 -14.1136 0.10000E+01 0.0000 83 H2PO4- 0.18013E-07 -7.7444 0.16933E-07 -7.7713 0.94006E+00 -0.0268 84 PO4-3 0.78380E-09 -9.1058 0.52076E-09 -9.2834 0.66440E+00 -0.1776 87 H2P2O7-2 0.27271E-16 -16.5643 0.22482E-16 -16.6482 0.82442E+00 -0.0839 88 HP2O7-3 0.56560E-14 -14.2475 0.37434E-14 -14.4267 0.66186E+00 -0.1792 89 P2O7-4 0.15286E-14 -14.8157 0.74573E-15 -15.1274 0.48785E+00 -0.3117 90 H2S,aq 0.19705E-15 -15.7054 0.19700E-15 -15.7055 0.99975E+00 -0.0001 97 SO3-2 0.15194E-14 -14.8183 0.12541E-14 -14.9017 0.82537E+00 -0.0834 98 HSO3- 0.10018E-15 -15.9992 0.94165E-16 -16.0261 0.93999E+00 -0.0269 99 HSO4- 0.25834E-10 -10.5878 0.24289E-10 -10.6146 0.94020E+00 -0.0268 Charge balance for all species = -.5871E-14 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.1275181E-08 -.9701662E-03 -.9777613E+00 0.0000 2 H2O 0.1000000E+01 0.5550846E+02 0.9998911E+06 0.0000 3 Cl- 0.1379517E-03 0.1379935E-03 0.4891744E+01 5.0339 4 SO4-- 0.2548778E-04 0.2550813E-04 0.2450081E+01 13.1648 5 HCO3- 0.1204183E-04 0.1307183E-04 0.7975185E+00 3.9750 6 HS- 0.5654437E-13 -.8313831E-10 -.2749246E-05 -4.3534 7 Al+++ 0.1237276E-23 0.2527682E-04 0.6819311E+00 2.6765 8 H4SiO4 0.4224795E-03 0.7775943E-03 0.7473053E+02 -3.3742 9 Ca++ 0.9685120E-07 0.1039328E-06 0.4164958E-02 10.7443 10 Mg++ 0.6233292E-09 0.8096365E-09 0.1968171E-04 8.5527 11 Fe++ 0.3677408E-11 0.2517190E-08 0.1405620E-03 6.3236 12 K+ 0.6042130E-04 0.6046137E-04 0.2363900E+01 4.6755 13 Na+ 0.1032081E-02 0.1037632E-02 0.2385231E+02 5.9079 14 Mn++ 0.4940629E-09 0.1883709E-08 0.1034758E-03 8.4519 15 HPO4-- 0.9282734E-06 0.9470700E-06 0.9088880E-01 11.7261 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.1156136E-01 -.9700302E-03 -.1059133E-01 0.0000000E+00 2 H2O 0.5549949E+02 0.5550068E+02 -.1190611E-02 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.4487614E-04 0.2550455E-04 0.1937159E-04 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.1937167E-04 -.8312665E-10 -.1937159E-04 0.0000000E+00 7 Al+++ 0.2279258E-02 0.2527327E-04 0.2253985E-02 0.0000000E+00 8 H4SiO4 0.7278535E-02 0.7774853E-03 0.6501050E-02 0.0000000E+00 9 Ca++ 0.8184208E-03 0.1039182E-06 0.8183169E-03 0.0000000E+00 10 Mg++ 0.5547619E-03 0.8095230E-09 0.5547611E-03 0.0000000E+00 11 Fe++ 0.4983930E-03 0.2516838E-08 0.4983905E-03 0.0000000E+00 12 K+ 0.1484076E-03 0.6045290E-04 0.8795474E-04 0.0000000E+00 13 Na+ 0.1037486E-02 0.1037486E-02 0.0000000E+00 0.0000000E+00 14 Mn++ 0.1211968E-04 0.1883445E-08 0.1211780E-04 0.0000000E+00 15 HPO4-- 0.4136386E-05 0.9469373E-06 0.3189449E-05 0.0000000E+00 Chg. balance for solid moles: -.1298E-17 Mass of aqueous solution: 0.999970E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 0.6990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) apatite-OH 0.1063E-05 -5.973 0.5340E-03 -3.272 0.7283E-01 0.1697E-03 clinochlore 0.1110E-03 -3.955 0.6167E-01 -1.210 8.410 0.2346E-01 daphnite 0.6868E-04 -4.163 0.4901E-01 -1.310 6.683 0.1485E-01 chlorite-Mn 0.2424E-05 -5.616 0.1718E-02 -2.765 0.2343 0.5476E-03 hematite 0.7749E-04 -4.111 0.1237E-01 -1.907 1.688 0.2345E-02 muscovite 0.8795E-04 -4.056 0.3503E-01 -1.456 4.778 0.1239E-01 stilbite 0.8130E-03 -3.090 0.5729 -0.242 78.13 0.2672 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.6094E+00 0.6094E+00 1.0000 -0.215 daphnite 0.3773E+00 0.3773E+00 1.0000 -0.423 chlorite-Mn 0.1331E-01 0.1331E-01 1.0000 -1.876 hematite 0.1000E+01 0.1000E+01 1.0000 0.000 muscovite 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 0.733275 g Volume = 0.320988 cm3 Porosity: 74.9150% V(tot) - V(min): 0.95861E+00 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.6990000 g log = -0.1555 Original solution: 1000.0103000 g Original solution / Rock added: 1430.63 (Water/Rock Ratio), log = 3.1555 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0203 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.1000E+01 0.9860 0.1006E+01 0.1020E+01 CO2,gas 0.3020E-05 1.0071 0.3104E-05 0.3082E-05 CH4,gas 0.3963E-16 1.0125 0.4094E-16 0.4043E-16 H2,gas 0.5906E-06 1.0005 0.6029E-06 0.6025E-06 H2S,gas 0.5329E-14 0.9960 0.5415E-14 0.5437E-14 S2,gas 0.2968E-35 1.0000 0.3029E-35 0.3029E-35 CO,gas 0.4887E-15 1.0000 0.4987E-15 0.4987E-15 SO3,gas 0.1120E-37 1.0000 0.1143E-37 0.1143E-37 SO2,gas 0.2627E-21 1.0000 0.2680E-21 0.2680E-21 HCl,gas 0.4928E-16 1.0000 0.5028E-16 0.5028E-16 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 32 apatite-OH -18.15 -18.15 0.00 0.000 0.12132E-10 46 clinochlore 39.07 39.07 0.00 0.000 0.24265E-10 47 daphnite 28.97 28.97 0.00 0.000 0.36397E-10 48 chlorite-Mn 46.87 46.87 0.00 0.000 0.24265E-10 90 hematite 12.57 12.57 0.00 0.000 0.30331E-11 120 muscovite 2.58 2.58 0.00 0.000 0.60662E-11 163 stilbite -7.52 -7.52 0.00 0.000 0.15165E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -13.87 -7.21 -2.402 0.12306E+05 -5.508 3 CH4,gas 4.54 -13.54 -18.09 -4.522 0.30883E+05 -16.388 4 H2,gas 8.00 0.08 -7.92 -4.525 0.13521E+05 -6.220 5 H2S,gas -6.23 -22.20 -15.97 -7.983 0.27260E+05 -14.266 6 S2,gas -7.34 -44.55 -37.22 -5.726 0.63548E+05 -35.519 7 CO,gas 3.21 -13.79 -17.00 -5.231 0.29029E+05 -15.302 8 SO3,gas 17.12 -22.52 -39.64 -9.910 0.67686E+05 -37.942 9 SO2,gas 0.83 -22.44 -23.27 -6.206 0.39734E+05 -21.572 10 HCl,gas 5.19 -12.81 -18.00 -8.999 0.30730E+05 -16.299 11 acmite 7.71 5.44 -2.27 -0.236 0.38710E+04 15 albite-high 0.69 -1.54 -2.23 -0.172 0.38097E+04 16 albite -0.38 -1.54 -1.15 -0.089 0.19709E+04 19 spessartine 24.46 20.59 -3.87 -0.194 0.66101E+04 20 analcite 3.32 1.84 -1.49 -0.165 0.25370E+04 21 andalusite 5.00 1.98 -3.02 -0.302 0.51612E+04 22 andradite 39.01 34.68 -4.33 -0.225 0.73973E+04 26 annite 20.12 16.20 -3.92 -0.218 0.66988E+04 27 phlogopite 27.06 22.89 -4.18 -0.232 0.71321E+04 29 anorthite 12.71 9.35 -3.36 -0.259 0.57395E+04 35 aragonite 0.97 -3.12 -4.09 -1.363 0.69827E+04 36 brucite 12.57 8.55 -4.02 -0.803 0.68569E+04 37 calcite 0.81 -3.12 -3.93 -1.312 0.67184E+04 38 carnegieite-low 9.02 5.21 -3.81 -0.545 0.65107E+04 39 carnegieite-high 10.09 5.21 -4.88 -0.698 0.83377E+04 40 carpholite-Mg 8.58 7.16 -1.42 -0.095 0.24327E+04 41 carpholite-Fe 6.71 4.93 -1.78 -0.119 0.30468E+04 42 celadonite 5.34 2.41 -2.93 -0.173 0.50091E+04 43 celadonite-Fe 3.88 0.18 -3.70 -0.218 0.63138E+04 44 chrysotile 23.89 18.91 -4.98 -0.415 0.85076E+04 50 chloritoid-Mg 13.20 10.53 -2.67 -0.178 0.45523E+04 51 chloritoid-Fe 9.17 8.30 -0.87 -0.058 0.14875E+04 52 chloritoid-Mn 11.40 10.43 -0.97 -0.065 0.16569E+04 54 coesite -2.38 -3.37 -1.00 -0.333 0.17043E+04 59 corundum 8.38 5.35 -3.03 -0.275 0.51738E+04 61 cristobalite -2.56 -3.37 -0.81 -0.271 0.13896E+04 63 cymrite-K 1.69 -2.77 -4.46 -0.371 0.76085E+04 65 diaspore 2.87 2.68 -0.20 -0.033 0.33668E+03 67 diopside 16.18 12.55 -3.63 -0.363 0.62028E+04 68 hedenbergite 14.21 10.32 -3.89 -0.389 0.66400E+04 75 epidote 24.67 23.00 -1.67 -0.081 0.28478E+04 76 clinozoisite 22.81 19.40 -3.41 -0.155 0.58234E+04 77 epidote-Fe 29.84 26.61 -3.23 -0.168 0.55188E+04 78 fayalite 14.05 9.27 -4.77 -0.682 0.81493E+04 83 gibbsite 4.08 2.68 -1.40 -0.200 0.23952E+04 87 greenalite 16.14 12.22 -3.92 -0.326 0.66883E+04 91 heulandite -5.83 -7.52 -1.69 -0.077 0.28938E+04 95 jadeite 4.22 1.84 -2.38 -0.238 0.40625E+04 97 kalsilite 7.58 3.98 -3.61 -0.515 0.61573E+04 98 kaolinite -1.33 -1.40 -0.06 -0.006 0.10687E+03 99 kyanite 4.88 1.98 -2.90 -0.290 0.49471E+04 101 laumontite 2.88 2.60 -0.28 -0.019 0.48301E+03 102 lawsonite 9.62 9.35 -0.27 -0.018 0.45616E+03 103 leucite 4.12 0.60 -3.52 -0.352 0.60022E+04 105 lizardite 23.24 18.91 -4.33 -0.361 0.74002E+04 107 magnetite 20.09 18.89 -1.20 -0.098 0.20449E+04 108 minnesotaite 10.39 5.47 -4.91 -0.289 0.83907E+04 113 margarite 17.32 14.70 -2.62 -0.105 0.44764E+04 116 microcline -2.49 -2.77 -0.28 -0.022 0.48510E+03 121 paragonite 4.24 3.81 -0.42 -0.025 0.72489E+03 122 nepheline 8.34 5.21 -3.13 -0.447 0.53430E+04 136 prehnite 19.37 16.72 -2.65 -0.156 0.45297E+04 137 prehnite-Fe 22.50 20.33 -2.17 -0.131 0.37091E+04 138 pumpellyite-Fe 46.27 42.44 -3.83 -0.085 0.65418E+04 139 pumpellyite-Mg 48.99 44.67 -4.33 -0.096 0.73893E+04 145 pyroxmangite 7.40 5.08 -2.32 -0.464 0.39631E+04 146 pyrophyllite -6.18 -8.14 -1.97 -0.123 0.33602E+04 147 quartz -2.99 -3.37 -0.38 -0.128 0.65697E+03 151 rhodochrosite -0.98 -5.42 -4.44 -1.480 0.75796E+04 152 rhodonite 7.45 5.08 -2.37 -0.474 0.40433E+04 153 sanidine -1.28 -2.77 -1.50 -0.115 0.25528E+04 155 siderite -2.61 -7.54 -4.94 -1.645 0.84272E+04 156 sillimanite 5.26 1.98 -3.28 -0.328 0.56051E+04 164 stilpnomelane-Fe 13.02 12.32 -0.70 -0.021 0.11982E+04 165 stilpnomelane-Mg 27.44 23.46 -3.98 -0.119 0.67966E+04 168 sudoite 21.08 17.69 -3.39 -0.109 0.57856E+04 171 talc 16.49 12.16 -4.33 -0.255 0.73927E+04 174 tephroite 18.09 13.53 -4.56 -0.651 0.77797E+04 177 topaz-H 4.62 1.98 -2.64 -0.240 0.45071E+04 178 tridymite -2.63 -3.37 -0.75 -0.249 0.12769E+04 187 wairakite 3.95 2.60 -1.35 -0.079 0.23050E+04 188 walstromite 11.51 7.37 -4.14 -0.828 0.70675E+04 189 wollastonite 10.46 7.37 -3.09 -0.618 0.52779E+04 190 pseudo-wollastonite 11.00 7.37 -3.63 -0.726 0.61977E+04 191 zoisite 22.85 19.40 -3.45 -0.157 0.58974E+04 192 akaganeite 7.75 6.28 -1.47 -0.318 0.25125E+04 193 beidellite-Ca -1.65 -4.37 -2.73 -0.169 0.46590E+04 194 beidellite-H -2.33 -6.15 -3.82 -0.244 0.65239E+04 195 beidellite-K -1.52 -4.60 -3.08 -0.189 0.52656E+04 196 beidellite-Mg -1.79 -4.74 -2.95 -0.182 0.50303E+04 197 beidellite-Na -1.34 -4.20 -2.86 -0.175 0.48751E+04 199 chalcedony -2.80 -3.37 -0.57 -0.191 0.97626E+03 201 montmorillonite-Ca -2.29 -4.43 -2.14 -0.132 0.36558E+04 202 montmorillonite-K -2.24 -4.66 -2.42 -0.148 0.41406E+04 203 montmorillonite-Mg -2.48 -4.79 -2.31 -0.143 0.39503E+04 204 montmorillonite-Na -2.04 -4.25 -2.22 -0.136 0.37858E+04 205 nontronite-Ca 3.21 2.84 -0.38 -0.024 0.64132E+03 206 nontronite-H 2.53 1.07 -1.47 -0.098 0.25041E+04 207 nontronite-K 3.34 2.61 -0.73 -0.047 0.12493E+04 208 nontronite-Mg 3.07 2.48 -0.60 -0.039 0.10198E+04 209 nontronite-Na 3.52 3.02 -0.50 -0.032 0.86047E+03 224 tobermorite 9.82 5.58 -4.25 -1.159 0.72521E+04 233 boehmite 4.41 2.68 -1.73 -0.288 0.29536E+04 235 ferrous-oxide 9.81 6.32 -3.49 -0.872 0.59556E+04 240 silica-amorphous -2.09 -3.37 -1.28 -0.428 0.21904E+04 242 an20ab80 2.02 0.64 -1.38 -0.106 0.23538E+04 243 an25ab75 2.65 1.18 -1.46 -0.112 0.24964E+04 244 an30ab70 3.28 1.73 -1.55 -0.119 0.26487E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 0.0200000 g Current total amount of reactant added: 0.6990000 g New total amount of reactant added: 0.7190000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.5865E-14 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 7 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 0.7190000 Water: Moles liquid = 0.5550E+02 kg liquid = 0.9999E+00 Moles total = 0.5550E+02 kg total = 0.9998E+00 Activity = 1.0000 Stoichiometric ionic strength = .8038435E-03 Osmotic coef. = 0.9834 True ionic strength = .1146400E-02 Chg. balance for total moles = -.5865E-14 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.12482E-08 -8.9037 0.11733E-08 -8.9306 0.93999E+00 -0.0269 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13795E-03 -3.8603 0.12961E-03 -3.8874 0.93953E+00 -0.0271 4 SO4-- 0.25488E-04 -4.5937 0.20975E-04 -4.6783 0.82297E+00 -0.0846 5 HCO3- 0.12021E-04 -4.9201 0.11295E-04 -4.9471 0.93964E+00 -0.0270 6 HS- 0.56166E-13 -13.2505 0.52770E-13 -13.2776 0.93954E+00 -0.0271 7 Al+++ 0.11272E-23 -23.9480 0.74278E-24 -24.1291 0.65895E+00 -0.1811 8 H4SiO4 0.43007E-03 -3.3665 0.43007E-03 -3.3665 0.10000E+01 0.0000 9 Ca++ 0.87401E-07 -7.0585 0.71887E-07 -7.1434 0.82249E+00 -0.0849 10 Mg++ 0.59906E-09 -9.2225 0.49254E-09 -9.3076 0.82219E+00 -0.0850 11 Fe++ 0.35342E-11 -11.4517 0.29060E-11 -11.5367 0.82226E+00 -0.0850 12 K+ 0.61698E-04 -4.2097 0.57975E-04 -4.2368 0.93966E+00 -0.0270 13 Na+ 0.10568E-02 -2.9760 0.99292E-03 -3.0031 0.93952E+00 -0.0271 14 Mn++ 0.47483E-09 -9.3235 0.39046E-09 -9.4084 0.82232E+00 -0.0850 15 HPO4-- 0.10754E-05 -5.9684 0.88503E-06 -6.0530 0.82298E+00 -0.0846 16 HSiO3- 0.36430E-03 -3.4385 0.34227E-03 -3.4656 0.93953E+00 -0.0271 17 Ca(HSiO3)+ 0.59631E-09 -9.2245 0.56034E-09 -9.2515 0.93967E+00 -0.0270 18 Mg(HSiO3)+ 0.50847E-11 -11.2937 0.47780E-11 -11.3208 0.93967E+00 -0.0270 19 NaHSiO3,aq 0.54965E-05 -5.2599 0.54965E-05 -5.2599 0.10000E+01 0.0000 20 AlO+ 0.78119E-13 -13.1072 0.73406E-13 -13.1343 0.93967E+00 -0.0270 21 AlOH+2 0.52148E-18 -18.2828 0.42885E-18 -18.3677 0.82238E+00 -0.0849 22 HAlO2,aq 0.12460E-07 -7.9045 0.12460E-07 -7.9045 0.10000E+01 0.0000 23 AlO2- 0.25024E-04 -4.6016 0.23507E-04 -4.6288 0.93939E+00 -0.0272 24 CH4,aq 0.27610E-19 -19.5589 0.27603E-19 -19.5590 0.99975E+00 -0.0001 29 CO,aq 0.32801E-18 -18.4841 0.32801E-18 -18.4841 0.10000E+01 0.0000 30 CO2,aq 0.28324E-07 -7.5478 0.28317E-07 -7.5479 0.99975E+00 -0.0001 31 CO3-2 0.10219E-05 -5.9906 0.84089E-06 -6.0753 0.82283E+00 -0.0847 32 CaCO3,aq 0.75796E-09 -9.1204 0.75796E-09 -9.1204 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.22057E-10 -10.6564 0.20727E-10 -10.6835 0.93967E+00 -0.0270 34 CaCl+ 0.16046E-10 -10.7946 0.15078E-10 -10.8217 0.93967E+00 -0.0270 35 CaCl2,aq 0.46429E-15 -15.3332 0.46429E-15 -15.3332 0.10000E+01 0.0000 36 CaOH+ 0.46470E-08 -8.3328 0.43667E-08 -8.3598 0.93967E+00 -0.0270 37 CaSO4,aq 0.47882E-09 -9.3198 0.47882E-09 -9.3198 0.10000E+01 0.0000 38 HCl,aq 0.27866E-13 -13.5549 0.27866E-13 -13.5549 0.10000E+01 0.0000 43 FeCl+ 0.63445E-15 -15.1976 0.59617E-15 -15.2246 0.93967E+00 -0.0270 46 FeO,aq 0.82047E-10 -10.0859 0.82047E-10 -10.0859 0.10000E+01 0.0000 47 FeOH+ 0.85800E-10 -10.0665 0.80624E-10 -10.0935 0.93967E+00 -0.0270 48 HFeO2- 0.77878E-09 -9.1086 0.73169E-09 -9.1357 0.93953E+00 -0.0271 49 FeO+ 0.95304E-14 -14.0209 0.89555E-14 -14.0479 0.93967E+00 -0.0270 51 FeO2- 0.14169E-08 -8.8487 0.13312E-08 -8.8758 0.93953E+00 -0.0271 52 HFeO2,aq 0.19864E-09 -9.7019 0.19864E-09 -9.7019 0.10000E+01 0.0000 53 H2,aq 0.46122E-09 -9.3361 0.46111E-09 -9.3362 0.99975E+00 -0.0001 54 KCl,aq 0.13619E-09 -9.8659 0.13619E-09 -9.8659 0.10000E+01 0.0000 55 KHSO4,aq 0.40340E-17 -17.3943 0.40340E-17 -17.3943 0.10000E+01 0.0000 56 KOH,aq 0.21102E-07 -7.6757 0.21102E-07 -7.6757 0.10000E+01 0.0000 57 KSO4- 0.20085E-07 -7.6971 0.18870E-07 -7.7242 0.93953E+00 -0.0271 58 MgCO3,aq 0.13017E-11 -11.8855 0.13017E-11 -11.8855 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.15442E-12 -12.8113 0.14511E-12 -12.8383 0.93967E+00 -0.0270 60 MgCl+ 0.99645E-13 -13.0015 0.93634E-13 -13.0286 0.93967E+00 -0.0270 61 MgOH+ 0.17618E-09 -9.7540 0.16556E-09 -9.7811 0.93967E+00 -0.0270 63 MnO,aq 0.29374E-09 -9.5320 0.29374E-09 -9.5320 0.10000E+01 0.0000 64 MnOH+ 0.10709E-08 -8.9702 0.10063E-08 -8.9973 0.93967E+00 -0.0270 65 MnO2-2 0.86064E-14 -14.0652 0.70816E-14 -14.1499 0.82283E+00 -0.0847 66 HMnO2- 0.19375E-11 -11.7128 0.18203E-11 -11.7399 0.93953E+00 -0.0271 69 MnCl+ 0.33164E-12 -12.4793 0.31163E-12 -12.5064 0.93967E+00 -0.0270 70 MnSO4,aq 0.23644E-11 -11.6263 0.23644E-11 -11.6263 0.10000E+01 0.0000 71 NaCl,aq 0.42649E-07 -7.3701 0.42649E-07 -7.3701 0.10000E+01 0.0000 72 NaOH,aq 0.36360E-06 -6.4394 0.36360E-06 -6.4394 0.10000E+01 0.0000 74 OH- 0.52422E-03 -3.2805 0.49244E-03 -3.3076 0.93939E+00 -0.0272 79 HPO3-2 0.15456E-17 -17.8109 0.12718E-17 -17.8956 0.82283E+00 -0.0847 82 H3PO4,aq 0.85208E-14 -14.0695 0.85208E-14 -14.0695 0.10000E+01 0.0000 83 H2PO4- 0.20387E-07 -7.6907 0.19155E-07 -7.7177 0.93960E+00 -0.0271 84 PO4-3 0.93028E-09 -9.0314 0.61544E-09 -9.2108 0.66156E+00 -0.1794 87 H2P2O7-2 0.34966E-16 -16.4564 0.28771E-16 -16.5410 0.82283E+00 -0.0847 88 HP2O7-3 0.74304E-14 -14.1290 0.48964E-14 -14.3101 0.65897E+00 -0.1811 89 P2O7-4 0.20595E-14 -14.6862 0.99698E-15 -15.0013 0.48410E+00 -0.3151 90 H2S,aq 0.19140E-15 -15.7181 0.19135E-15 -15.7182 0.99975E+00 -0.0001 97 SO3-2 0.15257E-14 -14.8165 0.12569E-14 -14.9007 0.82379E+00 -0.0842 98 HSO3- 0.98274E-16 -16.0076 0.92332E-16 -16.0346 0.93953E+00 -0.0271 99 HSO4- 0.25238E-10 -10.5979 0.23717E-10 -10.6249 0.93974E+00 -0.0270 Charge balance for all species = -.5864E-14 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.1248189E-08 -.9955150E-03 -.1003306E+01 0.0000 2 H2O 0.1000000E+01 0.5550846E+02 0.9998884E+06 0.0000 3 Cl- 0.1379513E-03 0.1379941E-03 0.4891750E+01 5.0432 4 SO4-- 0.2548755E-04 0.2550823E-04 0.2450084E+01 13.1829 5 HCO3- 0.1202083E-04 0.1307188E-04 0.7975195E+00 3.9835 6 HS- 0.5616613E-13 -.8657666E-10 -.2862939E-05 -4.3470 7 Al+++ 0.1127218E-23 0.2503640E-04 0.6754432E+00 2.6627 8 H4SiO4 0.4300722E-03 0.7998668E-03 0.7687082E+02 -3.3665 9 Ca++ 0.8740119E-07 0.9391940E-07 0.3763676E-02 10.7178 10 Mg++ 0.5990577E-09 0.7818820E-09 0.1900696E-04 8.5536 11 Fe++ 0.3534209E-11 0.2565675E-08 0.1432690E-03 6.3245 12 K+ 0.6169775E-04 0.6173907E-04 0.2413848E+01 4.6938 13 Na+ 0.1056841E-02 0.1062744E-02 0.2442951E+02 5.9275 14 Mn++ 0.4748267E-09 0.1844139E-08 0.1013019E-03 8.4528 15 HPO4-- 0.1075395E-05 0.1096712E-05 0.1052495E+00 11.8082 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.1189253E-01 -.9953716E-03 -.1089716E-01 0.0000000E+00 2 H2O 0.5549924E+02 0.5550046E+02 -.1224128E-02 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.4543041E-04 0.2550456E-04 0.1992585E-04 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.1992594E-04 -.8656419E-10 -.1992585E-04 0.0000000E+00 7 Al+++ 0.2344473E-02 0.2503279E-04 0.2319440E-02 0.0000000E+00 8 H4SiO4 0.7486791E-02 0.7997516E-03 0.6687039E-02 0.0000000E+00 9 Ca++ 0.8414236E-03 0.9390587E-07 0.8413297E-03 0.0000000E+00 10 Mg++ 0.5706349E-03 0.7817694E-09 0.5706341E-03 0.0000000E+00 11 Fe++ 0.5126532E-03 0.2565306E-08 0.5126506E-03 0.0000000E+00 12 K+ 0.1526539E-03 0.6173018E-04 0.9092375E-04 0.0000000E+00 13 Na+ 0.1062591E-02 0.1062591E-02 0.0000000E+00 0.0000000E+00 14 Mn++ 0.1246645E-04 0.1843874E-08 0.1246461E-04 0.0000000E+00 15 HPO4-- 0.4254738E-05 0.1096554E-05 0.3158183E-05 0.0000000E+00 Chg. balance for solid moles: 0.2151E-18 Mass of aqueous solution: 0.999969E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 0.7190000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) apatite-OH 0.1053E-05 -5.978 0.5288E-03 -3.277 0.7011E-01 0.1680E-03 clinochlore 0.1141E-03 -3.943 0.6344E-01 -1.198 8.410 0.2413E-01 daphnite 0.7065E-04 -4.151 0.5041E-01 -1.297 6.683 0.1528E-01 chlorite-Mn 0.2493E-05 -5.603 0.1767E-02 -2.753 0.2343 0.5632E-03 hematite 0.7970E-04 -4.099 0.1273E-01 -1.895 1.688 0.2413E-02 muscovite 0.9092E-04 -4.041 0.3622E-01 -1.441 4.801 0.1281E-01 stilbite 0.8361E-03 -3.078 0.5892 -0.230 78.11 0.2748 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.6094E+00 0.6094E+00 1.0000 -0.215 daphnite 0.3773E+00 0.3773E+00 1.0000 -0.423 chlorite-Mn 0.1331E-01 0.1331E-01 1.0000 -1.876 hematite 0.1000E+01 0.1000E+01 1.0000 0.000 muscovite 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 0.754277 g Volume = 0.330164 cm3 Porosity: 74.3582% V(tot) - V(min): 0.95744E+00 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.7190000 g log = -0.1433 Original solution: 1000.0103000 g Original solution / Rock added: 1390.83 (Water/Rock Ratio), log = 3.1433 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0203 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.1000E+01 0.9860 0.1006E+01 0.1020E+01 CO2,gas 0.2948E-05 1.0071 0.3030E-05 0.3008E-05 CH4,gas 0.3933E-16 1.0125 0.4063E-16 0.4013E-16 H2,gas 0.5930E-06 1.0005 0.6054E-06 0.6051E-06 H2S,gas 0.5176E-14 0.9960 0.5260E-14 0.5281E-14 S2,gas 0.2778E-35 1.0000 0.2834E-35 0.2834E-35 CO,gas 0.4791E-15 1.0000 0.4888E-15 0.4888E-15 SO3,gas 0.1070E-37 1.0000 0.1092E-37 0.1092E-37 SO2,gas 0.2520E-21 1.0000 0.2571E-21 0.2571E-21 HCl,gas 0.4819E-16 1.0000 0.4917E-16 0.4917E-16 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 32 apatite-OH -18.15 -18.15 0.00 0.000 0.00000E+00 46 clinochlore 39.07 39.07 0.00 0.000 -0.12132E-10 47 daphnite 28.97 28.97 0.00 0.000 -0.12132E-10 48 chlorite-Mn 46.87 46.87 0.00 0.000 0.12132E-10 90 hematite 12.57 12.57 0.00 0.000 -0.30331E-11 120 muscovite 2.58 2.58 0.00 0.000 0.60662E-11 163 stilbite -7.52 -7.52 0.00 0.000 -0.90992E-11 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -13.88 -7.22 -2.406 0.12324E+05 -5.519 3 CH4,gas 4.54 -13.55 -18.09 -4.523 0.30888E+05 -16.391 4 H2,gas 8.00 0.08 -7.92 -4.524 0.13518E+05 -6.218 5 H2S,gas -6.23 -22.21 -15.98 -7.989 0.27282E+05 -14.279 6 S2,gas -7.34 -44.58 -37.25 -5.730 0.63598E+05 -35.548 7 CO,gas 3.21 -13.79 -17.01 -5.234 0.29044E+05 -15.311 8 SO3,gas 17.12 -22.54 -39.66 -9.915 0.67720E+05 -37.962 9 SO2,gas 0.83 -22.46 -23.29 -6.210 0.39765E+05 -21.590 10 HCl,gas 5.19 -12.82 -18.01 -9.004 0.30747E+05 -16.308 11 acmite 7.71 5.48 -2.23 -0.232 0.38111E+04 15 albite-high 0.69 -1.51 -2.20 -0.169 0.37603E+04 16 albite -0.38 -1.51 -1.13 -0.087 0.19215E+04 19 spessartine 24.46 20.58 -3.87 -0.194 0.66132E+04 20 analcite 3.32 1.86 -1.46 -0.163 0.25008E+04 21 andalusite 5.00 1.96 -3.04 -0.304 0.51953E+04 22 andradite 39.01 34.62 -4.39 -0.228 0.74931E+04 26 annite 20.12 16.23 -3.89 -0.216 0.66468E+04 27 phlogopite 27.06 22.92 -4.15 -0.230 0.70801E+04 29 anorthite 12.71 9.31 -3.40 -0.262 0.58055E+04 35 aragonite 0.97 -3.16 -4.13 -1.375 0.70457E+04 36 brucite 12.57 8.55 -4.01 -0.803 0.68554E+04 37 calcite 0.81 -3.16 -3.97 -1.324 0.67815E+04 38 carnegieite-low 9.02 5.22 -3.80 -0.543 0.64877E+04 39 carnegieite-high 10.09 5.22 -4.87 -0.696 0.83147E+04 40 carpholite-Mg 8.58 7.15 -1.44 -0.096 0.24520E+04 41 carpholite-Fe 6.71 4.92 -1.80 -0.120 0.30662E+04 42 celadonite 5.34 2.44 -2.90 -0.170 0.49471E+04 43 celadonite-Fe 3.88 0.22 -3.66 -0.215 0.62517E+04 44 chrysotile 23.89 18.93 -4.96 -0.414 0.84766E+04 50 chloritoid-Mg 13.20 10.51 -2.69 -0.179 0.45849E+04 51 chloritoid-Fe 9.17 8.28 -0.89 -0.059 0.15201E+04 52 chloritoid-Mn 11.40 10.41 -0.99 -0.066 0.16895E+04 54 coesite -2.38 -3.37 -0.99 -0.330 0.16911E+04 59 corundum 8.38 5.33 -3.06 -0.278 0.52211E+04 61 cristobalite -2.56 -3.37 -0.81 -0.269 0.13764E+04 63 cymrite-K 1.69 -2.74 -4.43 -0.369 0.75612E+04 65 diaspore 2.87 2.66 -0.21 -0.035 0.36035E+03 67 diopside 16.18 12.54 -3.64 -0.364 0.62200E+04 68 hedenbergite 14.21 10.31 -3.90 -0.390 0.66572E+04 75 epidote 24.67 22.94 -1.73 -0.084 0.29457E+04 76 clinozoisite 22.81 19.32 -3.48 -0.158 0.59450E+04 77 epidote-Fe 29.84 26.57 -3.28 -0.170 0.55931E+04 78 fayalite 14.05 9.28 -4.76 -0.680 0.81330E+04 83 gibbsite 4.08 2.66 -1.42 -0.202 0.24189E+04 87 greenalite 16.14 12.24 -3.90 -0.325 0.66573E+04 91 heulandite -5.83 -7.52 -1.69 -0.077 0.28938E+04 95 jadeite 4.22 1.86 -2.36 -0.236 0.40263E+04 97 kalsilite 7.58 3.99 -3.59 -0.513 0.61364E+04 98 kaolinite -1.33 -1.41 -0.07 -0.007 0.12778E+03 99 kyanite 4.88 1.96 -2.92 -0.292 0.49812E+04 101 laumontite 2.88 2.58 -0.31 -0.020 0.52264E+03 102 lawsonite 9.62 9.31 -0.31 -0.020 0.52220E+03 103 leucite 4.12 0.62 -3.50 -0.350 0.59681E+04 105 lizardite 23.24 18.93 -4.32 -0.360 0.73692E+04 107 magnetite 20.09 18.89 -1.20 -0.098 0.20433E+04 108 minnesotaite 10.39 5.51 -4.88 -0.287 0.83332E+04 113 margarite 17.32 14.64 -2.69 -0.108 0.45898E+04 116 microcline -2.49 -2.74 -0.26 -0.020 0.43777E+03 121 paragonite 4.24 3.82 -0.42 -0.025 0.72281E+03 122 nepheline 8.34 5.22 -3.12 -0.445 0.53200E+04 136 prehnite 19.37 16.66 -2.71 -0.159 0.46277E+04 137 prehnite-Fe 22.50 20.28 -2.22 -0.133 0.37834E+04 138 pumpellyite-Fe 46.27 42.31 -3.96 -0.088 0.67599E+04 139 pumpellyite-Mg 48.99 44.54 -4.46 -0.099 0.76073E+04 145 pyroxmangite 7.40 5.09 -2.31 -0.462 0.39483E+04 146 pyrophyllite -6.18 -8.14 -1.96 -0.123 0.33547E+04 147 quartz -2.99 -3.37 -0.38 -0.126 0.64376E+03 151 rhodochrosite -0.98 -5.42 -4.45 -1.483 0.75959E+04 152 rhodonite 7.45 5.09 -2.36 -0.472 0.40286E+04 153 sanidine -1.28 -2.74 -1.47 -0.113 0.25055E+04 155 siderite -2.61 -7.55 -4.95 -1.648 0.84436E+04 156 sillimanite 5.26 1.96 -3.30 -0.330 0.56392E+04 164 stilpnomelane-Fe 13.02 12.36 -0.65 -0.020 0.11165E+04 165 stilpnomelane-Mg 27.44 23.51 -3.93 -0.117 0.67149E+04 168 sudoite 21.08 17.66 -3.42 -0.110 0.58376E+04 171 talc 16.49 12.20 -4.30 -0.253 0.73353E+04 174 tephroite 18.09 13.54 -4.55 -0.650 0.77634E+04 177 topaz-H 4.62 1.96 -2.66 -0.242 0.45413E+04 178 tridymite -2.63 -3.37 -0.74 -0.247 0.12637E+04 187 wairakite 3.95 2.58 -1.37 -0.081 0.23446E+04 188 walstromite 11.51 7.35 -4.16 -0.832 0.70994E+04 189 wollastonite 10.46 7.35 -3.11 -0.622 0.53098E+04 190 pseudo-wollastonite 11.00 7.35 -3.65 -0.730 0.62297E+04 191 zoisite 22.85 19.32 -3.53 -0.160 0.60190E+04 192 akaganeite 7.75 6.28 -1.47 -0.318 0.25125E+04 193 beidellite-Ca -1.65 -4.38 -2.74 -0.169 0.46731E+04 194 beidellite-H -2.33 -6.15 -3.82 -0.244 0.65305E+04 195 beidellite-K -1.52 -4.60 -3.08 -0.189 0.52619E+04 196 beidellite-Mg -1.79 -4.74 -2.95 -0.182 0.50367E+04 197 beidellite-Na -1.34 -4.19 -2.85 -0.175 0.48707E+04 199 chalcedony -2.80 -3.37 -0.56 -0.188 0.96306E+03 201 montmorillonite-Ca -2.29 -4.43 -2.14 -0.132 0.36494E+04 202 montmorillonite-K -2.24 -4.65 -2.41 -0.148 0.41164E+04 203 montmorillonite-Mg -2.48 -4.79 -2.31 -0.143 0.39362E+04 204 montmorillonite-Na -2.04 -4.24 -2.20 -0.135 0.37609E+04 205 nontronite-Ca 3.21 2.86 -0.36 -0.023 0.60810E+03 206 nontronite-H 2.53 1.09 -1.44 -0.097 0.24634E+04 207 nontronite-K 3.34 2.64 -0.70 -0.045 0.11983E+04 208 nontronite-Mg 3.07 2.50 -0.57 -0.037 0.97892E+03 209 nontronite-Na 3.52 3.05 -0.47 -0.030 0.80877E+03 224 tobermorite 9.82 5.56 -4.26 -1.163 0.72765E+04 233 boehmite 4.41 2.66 -1.74 -0.291 0.29773E+04 235 ferrous-oxide 9.81 6.32 -3.49 -0.872 0.59541E+04 240 silica-amorphous -2.09 -3.37 -1.28 -0.425 0.21772E+04 242 an20ab80 2.02 0.65 -1.36 -0.105 0.23274E+04 243 an25ab75 2.65 1.20 -1.45 -0.112 0.24759E+04 244 an30ab70 3.28 1.74 -1.54 -0.119 0.26340E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 0.0200000 g Current total amount of reactant added: 0.7190000 g New total amount of reactant added: 0.7390000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.5864E-14 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 7 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 0.7390000 Water: Moles liquid = 0.5550E+02 kg liquid = 0.9999E+00 Moles total = 0.5550E+02 kg total = 0.9998E+00 Activity = 1.0000 Stoichiometric ionic strength = .8163265E-03 Osmotic coef. = 0.9833 True ionic strength = .1172605E-02 Chg. balance for total moles = -.5864E-14 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.12226E-08 -8.9127 0.11486E-08 -8.9398 0.93954E+00 -0.0271 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13795E-03 -3.8603 0.12955E-03 -3.8876 0.93908E+00 -0.0273 4 SO4-- 0.25487E-04 -4.5937 0.20935E-04 -4.6791 0.82140E+00 -0.0854 5 HCO3- 0.12000E-04 -4.9208 0.11270E-04 -4.9481 0.93919E+00 -0.0272 6 HS- 0.55847E-13 -13.2530 0.52446E-13 -13.2803 0.93909E+00 -0.0273 7 Al+++ 0.10299E-23 -23.9872 0.67574E-24 -24.1702 0.65611E+00 -0.1830 8 H4SiO4 0.43748E-03 -3.3590 0.43748E-03 -3.3590 0.10000E+01 0.0000 9 Ca++ 0.79223E-07 -7.1011 0.65035E-07 -7.1869 0.82091E+00 -0.0857 10 Mg++ 0.57650E-09 -9.2392 0.47308E-09 -9.3251 0.82061E+00 -0.0859 11 Fe++ 0.34011E-11 -11.4684 0.27912E-11 -11.5542 0.82068E+00 -0.0858 12 K+ 0.62994E-04 -4.2007 0.59164E-04 -4.2279 0.93921E+00 -0.0272 13 Na+ 0.10816E-02 -2.9659 0.10157E-02 -2.9932 0.93907E+00 -0.0273 14 Mn++ 0.45695E-09 -9.3401 0.37503E-09 -9.4259 0.82074E+00 -0.0858 15 HPO4-- 0.12377E-05 -5.9074 0.10166E-05 -5.9928 0.82141E+00 -0.0854 16 HSiO3- 0.37870E-03 -3.4217 0.35563E-03 -3.4490 0.93908E+00 -0.0273 17 Ca(HSiO3)+ 0.56081E-09 -9.2512 0.52673E-09 -9.2784 0.93922E+00 -0.0272 18 Mg(HSiO3)+ 0.50769E-11 -11.2944 0.47683E-11 -11.3216 0.93922E+00 -0.0272 19 NaHSiO3,aq 0.58421E-05 -5.2334 0.58421E-05 -5.2334 0.10000E+01 0.0000 20 AlO+ 0.74185E-13 -13.1297 0.69677E-13 -13.1569 0.93922E+00 -0.0272 21 AlOH+2 0.48552E-18 -18.3138 0.39852E-18 -18.3996 0.82080E+00 -0.0858 22 HAlO2,aq 0.12080E-07 -7.9179 0.12080E-07 -7.9179 0.10000E+01 0.0000 23 AlO2- 0.24794E-04 -4.6056 0.23280E-04 -4.6330 0.93894E+00 -0.0274 24 CH4,aq 0.27432E-19 -19.5617 0.27425E-19 -19.5618 0.99975E+00 -0.0001 29 CO,aq 0.32178E-18 -18.4924 0.32178E-18 -18.4924 0.10000E+01 0.0000 30 CO2,aq 0.27669E-07 -7.5580 0.27662E-07 -7.5581 0.99975E+00 -0.0001 31 CO3-2 0.10435E-05 -5.9815 0.85702E-06 -6.0670 0.82126E+00 -0.0855 32 CaCO3,aq 0.69887E-09 -9.1556 0.69887E-09 -9.1556 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.19920E-10 -10.7007 0.18710E-10 -10.7279 0.93922E+00 -0.0272 34 CaCl+ 0.14517E-10 -10.8381 0.13634E-10 -10.8654 0.93922E+00 -0.0272 35 CaCl2,aq 0.41963E-15 -15.3771 0.41963E-15 -15.3771 0.10000E+01 0.0000 36 CaOH+ 0.42963E-08 -8.3669 0.40352E-08 -8.3941 0.93922E+00 -0.0272 37 CaSO4,aq 0.43235E-09 -9.3642 0.43235E-09 -9.3642 0.10000E+01 0.0000 38 HCl,aq 0.27267E-13 -13.5644 0.27267E-13 -13.5644 0.10000E+01 0.0000 43 FeCl+ 0.60937E-15 -15.2151 0.57234E-15 -15.2423 0.93922E+00 -0.0272 46 FeO,aq 0.82222E-10 -10.0850 0.82222E-10 -10.0850 0.10000E+01 0.0000 47 FeOH+ 0.84218E-10 -10.0746 0.79099E-10 -10.1018 0.93922E+00 -0.0272 48 HFeO2- 0.79756E-09 -9.0982 0.74896E-09 -9.1255 0.93908E+00 -0.0273 49 FeO+ 0.93348E-14 -14.0299 0.87675E-14 -14.0571 0.93922E+00 -0.0272 51 FeO2- 0.14479E-08 -8.8392 0.13597E-08 -8.8665 0.93908E+00 -0.0273 52 HFeO2,aq 0.19864E-09 -9.7019 0.19864E-09 -9.7019 0.10000E+01 0.0000 53 H2,aq 0.46318E-09 -9.3342 0.46307E-09 -9.3344 0.99975E+00 -0.0001 54 KCl,aq 0.13891E-09 -9.8573 0.13891E-09 -9.8573 0.10000E+01 0.0000 55 KHSO4,aq 0.40226E-17 -17.3955 0.40226E-17 -17.3955 0.10000E+01 0.0000 56 KOH,aq 0.21997E-07 -7.6576 0.21997E-07 -7.6576 0.10000E+01 0.0000 57 KSO4- 0.20467E-07 -7.6889 0.19220E-07 -7.7162 0.93908E+00 -0.0273 58 MgCO3,aq 0.12743E-11 -11.8947 0.12743E-11 -11.8947 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.14806E-12 -12.8295 0.13907E-12 -12.8568 0.93922E+00 -0.0272 60 MgCl+ 0.95707E-13 -13.0191 0.89890E-13 -13.0463 0.93922E+00 -0.0272 61 MgOH+ 0.17293E-09 -9.7621 0.16242E-09 -9.7894 0.93922E+00 -0.0272 63 MnO,aq 0.29437E-09 -9.5311 0.29437E-09 -9.5311 0.10000E+01 0.0000 64 MnOH+ 0.10512E-08 -8.9783 0.98729E-09 -9.0056 0.93922E+00 -0.0272 65 MnO2-2 0.90159E-14 -14.0450 0.74044E-14 -14.1305 0.82126E+00 -0.0855 66 HMnO2- 0.19842E-11 -11.7024 0.18633E-11 -11.7297 0.93908E+00 -0.0273 69 MnCl+ 0.31854E-12 -12.4968 0.29918E-12 -12.5241 0.93922E+00 -0.0272 70 MnSO4,aq 0.22666E-11 -11.6446 0.22666E-11 -11.6446 0.10000E+01 0.0000 71 NaCl,aq 0.43605E-07 -7.3605 0.43605E-07 -7.3605 0.10000E+01 0.0000 72 NaOH,aq 0.37991E-06 -6.4203 0.37991E-06 -6.4203 0.10000E+01 0.0000 74 OH- 0.53572E-03 -3.2711 0.50300E-03 -3.2984 0.93894E+00 -0.0274 79 HPO3-2 0.17864E-17 -17.7480 0.14671E-17 -17.8335 0.82126E+00 -0.0855 82 H3PO4,aq 0.93814E-14 -14.0277 0.93814E-14 -14.0277 0.10000E+01 0.0000 83 H2PO4- 0.22938E-07 -7.6394 0.21542E-07 -7.6667 0.93915E+00 -0.0273 84 PO4-3 0.10962E-08 -8.9601 0.72213E-09 -9.1414 0.65877E+00 -0.1813 87 H2P2O7-2 0.44307E-16 -16.3535 0.36387E-16 -16.4390 0.82126E+00 -0.0855 88 HP2O7-3 0.96404E-14 -14.0159 0.63254E-14 -14.1989 0.65614E+00 -0.1830 89 P2O7-4 0.27384E-14 -14.5625 0.13156E-14 -14.8809 0.48042E+00 -0.3184 90 H2S,aq 0.18623E-15 -15.7299 0.18618E-15 -15.7301 0.99975E+00 -0.0001 97 SO3-2 0.15321E-14 -14.8147 0.12598E-14 -14.8997 0.82224E+00 -0.0850 98 HSO3- 0.96481E-16 -16.0156 0.90603E-16 -16.0429 0.93908E+00 -0.0273 99 HSO4- 0.24672E-10 -10.6078 0.23175E-10 -10.6350 0.93930E+00 -0.0272 Charge balance for all species = -.5866E-14 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.1222560E-08 -.1020887E-02 -.1028873E+01 0.0000 2 H2O 0.1000000E+01 0.5550845E+02 0.9998856E+06 0.0000 3 Cl- 0.1379508E-03 0.1379946E-03 0.4891756E+01 5.0522 4 SO4-- 0.2548731E-04 0.2550833E-04 0.2450087E+01 13.2005 5 HCO3- 0.1200000E-04 0.1307193E-04 0.7975204E+00 3.9917 6 HS- 0.5584747E-13 -.8997205E-10 -.2975211E-05 -4.3405 7 Al+++ 0.1029926E-23 0.2480637E-04 0.6692355E+00 2.6492 8 H4SiO4 0.4374818E-03 0.8220285E-03 0.7900045E+02 -3.3590 9 Ca++ 0.7922299E-07 0.8524578E-07 0.3416085E-02 10.6928 10 Mg++ 0.5764964E-09 0.7560252E-09 0.1837836E-04 8.5546 11 Fe++ 0.3401100E-11 0.2613993E-08 0.1459668E-03 6.3254 12 K+ 0.6299381E-04 0.6303641E-04 0.2464564E+01 4.7119 13 Na+ 0.1081591E-02 0.1087857E-02 0.2500672E+02 5.9466 14 Mn++ 0.4569458E-09 0.1807072E-08 0.9926543E-04 8.4537 15 HPO4-- 0.1237686E-05 0.1261720E-05 0.1210846E+00 11.8868 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.1222370E-01 -.1020736E-02 -.1120297E-01 0.0000000E+00 2 H2O 0.5549899E+02 0.5550024E+02 -.1257722E-02 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.4598468E-04 0.2550456E-04 0.2048012E-04 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.2048021E-04 -.8995875E-10 -.2048012E-04 0.0000000E+00 7 Al+++ 0.2409688E-02 0.2480270E-04 0.2384885E-02 0.0000000E+00 8 H4SiO4 0.7695047E-02 0.8219070E-03 0.6873140E-02 0.0000000E+00 9 Ca++ 0.8644265E-03 0.8523318E-07 0.8643412E-03 0.0000000E+00 10 Mg++ 0.5865079E-03 0.7559134E-09 0.5865072E-03 0.0000000E+00 11 Fe++ 0.5269134E-03 0.2613607E-08 0.5269107E-03 0.0000000E+00 12 K+ 0.1569002E-03 0.6302709E-04 0.9387312E-04 0.0000000E+00 13 Na+ 0.1087696E-02 0.1087696E-02 0.0000000E+00 0.0000000E+00 14 Mn++ 0.1281322E-04 0.1806805E-08 0.1281142E-04 0.0000000E+00 15 HPO4-- 0.4373089E-05 0.1261534E-05 0.3111555E-05 0.0000000E+00 Chg. balance for solid moles: 0.7428E-18 Mass of aqueous solution: 0.999968E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 0.7390000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) apatite-OH 0.1037E-05 -5.984 0.5210E-03 -3.283 0.6720E-01 0.1656E-03 clinochlore 0.1173E-03 -3.931 0.6520E-01 -1.186 8.410 0.2480E-01 daphnite 0.7261E-04 -4.139 0.5181E-01 -1.286 6.683 0.1570E-01 chlorite-Mn 0.2562E-05 -5.591 0.1817E-02 -2.741 0.2343 0.5789E-03 hematite 0.8192E-04 -4.087 0.1308E-01 -1.883 1.687 0.2480E-02 muscovite 0.9387E-04 -4.027 0.3739E-01 -1.427 4.823 0.1322E-01 stilbite 0.8592E-03 -3.066 0.6055 -0.218 78.10 0.2824 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.6094E+00 0.6094E+00 1.0000 -0.215 daphnite 0.3773E+00 0.3773E+00 1.0000 -0.423 chlorite-Mn 0.1331E-01 0.1331E-01 1.0000 -1.876 hematite 0.1000E+01 0.1000E+01 1.0000 0.000 muscovite 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 0.775285 g Volume = 0.339345 cm3 Porosity: 73.8079% V(tot) - V(min): 0.95625E+00 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.7390000 g log = -0.1314 Original solution: 1000.0103000 g Original solution / Rock added: 1353.19 (Water/Rock Ratio), log = 3.1314 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0203 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.1000E+01 0.9860 0.1006E+01 0.1020E+01 CO2,gas 0.2880E-05 1.0071 0.2959E-05 0.2939E-05 CH4,gas 0.3908E-16 1.0125 0.4037E-16 0.3987E-16 H2,gas 0.5955E-06 1.0005 0.6080E-06 0.6076E-06 H2S,gas 0.5036E-14 0.9960 0.5118E-14 0.5138E-14 S2,gas 0.2607E-35 1.0000 0.2660E-35 0.2660E-35 CO,gas 0.4700E-15 1.0000 0.4795E-15 0.4795E-15 SO3,gas 0.1024E-37 1.0000 0.1044E-37 0.1044E-37 SO2,gas 0.2421E-21 1.0000 0.2470E-21 0.2470E-21 HCl,gas 0.4716E-16 1.0000 0.4811E-16 0.4811E-16 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 32 apatite-OH -18.15 -18.15 0.00 0.000 -0.60662E-11 46 clinochlore 39.07 39.07 0.00 0.000 -0.12132E-10 47 daphnite 28.97 28.97 0.00 0.000 -0.60662E-11 48 chlorite-Mn 46.87 46.87 0.00 0.000 -0.24265E-10 90 hematite 12.57 12.57 0.00 0.000 -0.90992E-11 120 muscovite 2.58 2.58 0.00 0.000 0.30331E-10 163 stilbite -7.52 -7.52 0.00 0.000 -0.90992E-11 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -13.89 -7.23 -2.409 0.12341E+05 -5.529 3 CH4,gas 4.54 -13.55 -18.09 -4.523 0.30893E+05 -16.394 4 H2,gas 8.00 0.08 -7.92 -4.523 0.13515E+05 -6.216 5 H2S,gas -6.23 -22.22 -15.99 -7.995 0.27302E+05 -14.291 6 S2,gas -7.34 -44.61 -37.27 -5.734 0.63644E+05 -35.575 7 CO,gas 3.21 -13.80 -17.02 -5.236 0.29058E+05 -15.319 8 SO3,gas 17.12 -22.56 -39.68 -9.920 0.67753E+05 -37.981 9 SO2,gas 0.83 -22.47 -23.31 -6.215 0.39795E+05 -21.607 10 HCl,gas 5.19 -12.83 -18.02 -9.008 0.30763E+05 -16.318 11 acmite 7.71 5.51 -2.20 -0.228 0.37532E+04 15 albite-high 0.69 -1.48 -2.17 -0.167 0.37127E+04 16 albite -0.38 -1.48 -1.10 -0.084 0.18739E+04 19 spessartine 24.46 20.58 -3.87 -0.194 0.66163E+04 20 analcite 3.32 1.88 -1.44 -0.160 0.24658E+04 21 andalusite 5.00 1.94 -3.06 -0.306 0.52285E+04 22 andradite 39.01 34.57 -4.44 -0.231 0.75835E+04 26 annite 20.12 16.26 -3.86 -0.215 0.65962E+04 27 phlogopite 27.06 22.95 -4.12 -0.229 0.70296E+04 29 anorthite 12.71 9.27 -3.44 -0.264 0.58689E+04 35 aragonite 0.97 -3.20 -4.16 -1.387 0.71059E+04 36 brucite 12.57 8.55 -4.01 -0.803 0.68538E+04 37 calcite 0.81 -3.20 -4.01 -1.336 0.68416E+04 38 carnegieite-low 9.02 5.24 -3.79 -0.541 0.64654E+04 39 carnegieite-high 10.09 5.24 -4.86 -0.694 0.82924E+04 40 carpholite-Mg 8.58 7.13 -1.45 -0.096 0.24710E+04 41 carpholite-Fe 6.71 4.91 -1.81 -0.120 0.30851E+04 42 celadonite 5.34 2.48 -2.86 -0.168 0.48870E+04 43 celadonite-Fe 3.88 0.25 -3.63 -0.213 0.61916E+04 44 chrysotile 23.89 18.95 -4.95 -0.412 0.84465E+04 50 chloritoid-Mg 13.20 10.49 -2.70 -0.180 0.46165E+04 51 chloritoid-Fe 9.17 8.26 -0.91 -0.061 0.15517E+04 52 chloritoid-Mn 11.40 10.39 -1.01 -0.067 0.17211E+04 54 coesite -2.38 -3.36 -0.98 -0.328 0.16784E+04 59 corundum 8.38 5.30 -3.08 -0.280 0.52670E+04 61 cristobalite -2.56 -3.36 -0.80 -0.266 0.13638E+04 63 cymrite-K 1.69 -2.72 -4.40 -0.367 0.75153E+04 65 diaspore 2.87 2.65 -0.22 -0.037 0.38328E+03 67 diopside 16.18 12.53 -3.65 -0.365 0.62359E+04 68 hedenbergite 14.21 10.30 -3.91 -0.391 0.66731E+04 75 epidote 24.67 22.89 -1.78 -0.086 0.30392E+04 76 clinozoisite 22.81 19.26 -3.55 -0.161 0.60614E+04 77 epidote-Fe 29.84 26.52 -3.32 -0.172 0.56636E+04 78 fayalite 14.05 9.29 -4.75 -0.679 0.81172E+04 83 gibbsite 4.08 2.65 -1.43 -0.204 0.24418E+04 87 greenalite 16.14 12.26 -3.88 -0.323 0.66273E+04 91 heulandite -5.83 -7.52 -1.69 -0.077 0.28938E+04 95 jadeite 4.22 1.88 -2.34 -0.234 0.39913E+04 97 kalsilite 7.58 4.00 -3.58 -0.512 0.61159E+04 98 kaolinite -1.33 -1.42 -0.09 -0.008 0.14831E+03 99 kyanite 4.88 1.94 -2.94 -0.294 0.50144E+04 101 laumontite 2.88 2.56 -0.33 -0.022 0.56064E+03 102 lawsonite 9.62 9.27 -0.34 -0.023 0.58553E+03 103 leucite 4.12 0.64 -3.48 -0.348 0.59349E+04 105 lizardite 23.24 18.95 -4.30 -0.358 0.73391E+04 107 magnetite 20.09 18.89 -1.20 -0.098 0.20418E+04 108 minnesotaite 10.39 5.54 -4.85 -0.285 0.82778E+04 113 margarite 17.32 14.57 -2.75 -0.110 0.46990E+04 116 microcline -2.49 -2.72 -0.23 -0.018 0.39191E+03 121 paragonite 4.24 3.82 -0.42 -0.025 0.72107E+03 122 nepheline 8.34 5.24 -3.10 -0.443 0.52978E+04 136 prehnite 19.37 16.61 -2.76 -0.163 0.47212E+04 137 prehnite-Fe 22.50 20.24 -2.26 -0.136 0.38540E+04 138 pumpellyite-Fe 46.27 42.19 -4.08 -0.091 0.69682E+04 139 pumpellyite-Mg 48.99 44.42 -4.58 -0.102 0.78157E+04 145 pyroxmangite 7.40 5.09 -2.30 -0.461 0.39341E+04 146 pyrophyllite -6.18 -8.14 -1.96 -0.123 0.33499E+04 147 quartz -2.99 -3.36 -0.37 -0.123 0.63109E+03 151 rhodochrosite -0.98 -5.43 -4.46 -1.486 0.76117E+04 152 rhodonite 7.45 5.09 -2.35 -0.470 0.40143E+04 153 sanidine -1.28 -2.72 -1.44 -0.111 0.24597E+04 155 siderite -2.61 -7.56 -4.95 -1.651 0.84594E+04 156 sillimanite 5.26 1.94 -3.32 -0.332 0.56724E+04 164 stilpnomelane-Fe 13.02 12.41 -0.61 -0.018 0.10378E+04 165 stilpnomelane-Mg 27.44 23.55 -3.89 -0.116 0.66362E+04 168 sudoite 21.08 17.63 -3.45 -0.111 0.58881E+04 171 talc 16.49 12.23 -4.26 -0.251 0.72799E+04 174 tephroite 18.09 13.55 -4.54 -0.648 0.77476E+04 177 topaz-H 4.62 1.94 -2.68 -0.244 0.45745E+04 178 tridymite -2.63 -3.36 -0.73 -0.244 0.12511E+04 187 wairakite 3.95 2.56 -1.40 -0.082 0.23826E+04 188 walstromite 11.51 7.33 -4.18 -0.835 0.71295E+04 189 wollastonite 10.46 7.33 -3.13 -0.625 0.53400E+04 190 pseudo-wollastonite 11.00 7.33 -3.67 -0.733 0.62598E+04 191 zoisite 22.85 19.26 -3.59 -0.163 0.61354E+04 192 akaganeite 7.75 6.28 -1.47 -0.318 0.25125E+04 193 beidellite-Ca -1.65 -4.39 -2.75 -0.170 0.46871E+04 194 beidellite-H -2.33 -6.15 -3.83 -0.244 0.65375E+04 195 beidellite-K -1.52 -4.60 -3.08 -0.189 0.52587E+04 196 beidellite-Mg -1.79 -4.74 -2.95 -0.183 0.50434E+04 197 beidellite-Na -1.34 -4.19 -2.85 -0.175 0.48669E+04 199 chalcedony -2.80 -3.36 -0.56 -0.186 0.95039E+03 201 montmorillonite-Ca -2.29 -4.42 -2.13 -0.132 0.36436E+04 202 montmorillonite-K -2.24 -4.63 -2.40 -0.147 0.40933E+04 203 montmorillonite-Mg -2.48 -4.78 -2.30 -0.142 0.39230E+04 204 montmorillonite-Na -2.04 -4.23 -2.19 -0.134 0.37373E+04 205 nontronite-Ca 3.21 2.88 -0.34 -0.022 0.57624E+03 206 nontronite-H 2.53 1.11 -1.42 -0.095 0.24245E+04 207 nontronite-K 3.34 2.67 -0.67 -0.043 0.11492E+04 208 nontronite-Mg 3.07 2.52 -0.55 -0.036 0.93974E+03 209 nontronite-Na 3.52 3.08 -0.44 -0.029 0.75911E+03 224 tobermorite 9.82 5.55 -4.28 -1.166 0.72995E+04 233 boehmite 4.41 2.65 -1.76 -0.293 0.30002E+04 235 ferrous-oxide 9.81 6.33 -3.49 -0.872 0.59525E+04 240 silica-amorphous -2.09 -3.36 -1.27 -0.423 0.21646E+04 242 an20ab80 2.02 0.67 -1.35 -0.104 0.23020E+04 243 an25ab75 2.65 1.21 -1.44 -0.111 0.24560E+04 244 an30ab70 3.28 1.75 -1.53 -0.118 0.26197E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 0.0200000 g Current total amount of reactant added: 0.7390000 g New total amount of reactant added: 0.7590000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.5863E-14 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 7 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 0.7590000 Water: Moles liquid = 0.5550E+02 kg liquid = 0.9998E+00 Moles total = 0.5550E+02 kg total = 0.9998E+00 Activity = 1.0000 Stoichiometric ionic strength = .8288984E-03 Osmotic coef. = 0.9832 True ionic strength = .1198839E-02 Chg. balance for total moles = -.5863E-14 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.11982E-08 -8.9215 0.11252E-08 -8.9488 0.93910E+00 -0.0273 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13795E-03 -3.8603 0.12948E-03 -3.8878 0.93863E+00 -0.0275 4 SO4-- 0.25487E-04 -4.5937 0.20896E-04 -4.6799 0.81985E+00 -0.0863 5 HCO3- 0.11979E-04 -4.9216 0.11245E-04 -4.9490 0.93874E+00 -0.0275 6 HS- 0.55585E-13 -13.2550 0.52174E-13 -13.2825 0.93864E+00 -0.0275 7 Al+++ 0.94359E-24 -24.0252 0.61646E-24 -24.2101 0.65331E+00 -0.1849 8 H4SiO4 0.44471E-03 -3.3519 0.44471E-03 -3.3519 0.10000E+01 0.0000 9 Ca++ 0.72112E-07 -7.1420 0.59085E-07 -7.2285 0.81936E+00 -0.0865 10 Mg++ 0.55547E-09 -9.2553 0.45496E-09 -9.3420 0.81904E+00 -0.0867 11 Fe++ 0.32771E-11 -11.4845 0.26843E-11 -11.5712 0.81912E+00 -0.0867 12 K+ 0.64310E-04 -4.1917 0.60372E-04 -4.2192 0.93876E+00 -0.0274 13 Na+ 0.11063E-02 -2.9561 0.10384E-02 -2.9836 0.93862E+00 -0.0275 14 Mn++ 0.44028E-09 -9.3563 0.36067E-09 -9.4429 0.81917E+00 -0.0866 15 HPO4-- 0.14156E-05 -5.8491 0.11606E-05 -5.9353 0.81986E+00 -0.0863 16 HSiO3- 0.39317E-03 -3.4054 0.36904E-03 -3.4329 0.93863E+00 -0.0275 17 Ca(HSiO3)+ 0.52896E-09 -9.2766 0.49657E-09 -9.3040 0.93878E+00 -0.0274 18 Mg(HSiO3)+ 0.50689E-11 -11.2951 0.47585E-11 -11.3225 0.93878E+00 -0.0274 19 NaHSiO3,aq 0.61980E-05 -5.2078 0.61980E-05 -5.2078 0.10000E+01 0.0000 20 AlO+ 0.70558E-13 -13.1515 0.66239E-13 -13.1789 0.93878E+00 -0.0274 21 AlOH+2 0.45301E-18 -18.3439 0.37113E-18 -18.4305 0.81924E+00 -0.0866 22 HAlO2,aq 0.11723E-07 -7.9309 0.11723E-07 -7.9309 0.10000E+01 0.0000 23 AlO2- 0.24575E-04 -4.6095 0.23063E-04 -4.6371 0.93848E+00 -0.0276 24 CH4,aq 0.27282E-19 -19.5641 0.27275E-19 -19.5642 0.99974E+00 -0.0001 29 CO,aq 0.31588E-18 -18.5005 0.31588E-18 -18.5005 0.10000E+01 0.0000 30 CO2,aq 0.27045E-07 -7.5679 0.27038E-07 -7.5680 0.99974E+00 -0.0001 31 CO3-2 0.10649E-05 -5.9727 0.87294E-06 -6.0590 0.81970E+00 -0.0863 32 CaCO3,aq 0.64673E-09 -9.1893 0.64673E-09 -9.1893 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.18067E-10 -10.7431 0.16961E-10 -10.7706 0.93878E+00 -0.0274 34 CaCl+ 0.13188E-10 -10.8798 0.12381E-10 -10.9072 0.93878E+00 -0.0274 35 CaCl2,aq 0.38087E-15 -15.4192 0.38087E-15 -15.4192 0.10000E+01 0.0000 36 CaOH+ 0.39864E-08 -8.3994 0.37424E-08 -8.4269 0.93878E+00 -0.0274 37 CaSO4,aq 0.39205E-09 -9.4067 0.39205E-09 -9.4067 0.10000E+01 0.0000 38 HCl,aq 0.26698E-13 -13.5735 0.26698E-13 -13.5735 0.10000E+01 0.0000 43 FeCl+ 0.58603E-15 -15.2321 0.55015E-15 -15.2595 0.93878E+00 -0.0274 46 FeO,aq 0.82400E-10 -10.0841 0.82400E-10 -10.0841 0.10000E+01 0.0000 47 FeOH+ 0.82718E-10 -10.0824 0.77654E-10 -10.1098 0.93878E+00 -0.0274 48 HFeO2- 0.81632E-09 -9.0881 0.76622E-09 -9.1156 0.93863E+00 -0.0275 49 FeO+ 0.91487E-14 -14.0386 0.85886E-14 -14.0661 0.93878E+00 -0.0274 51 FeO2- 0.14788E-08 -8.8301 0.13880E-08 -8.8576 0.93863E+00 -0.0275 52 HFeO2,aq 0.19864E-09 -9.7019 0.19864E-09 -9.7019 0.10000E+01 0.0000 53 H2,aq 0.46520E-09 -9.3324 0.46508E-09 -9.3325 0.99974E+00 -0.0001 54 KCl,aq 0.14168E-09 -9.8487 0.14168E-09 -9.8487 0.10000E+01 0.0000 55 KHSO4,aq 0.40134E-17 -17.3965 0.40134E-17 -17.3965 0.10000E+01 0.0000 56 KOH,aq 0.22913E-07 -7.6399 0.22913E-07 -7.6399 0.10000E+01 0.0000 57 KSO4- 0.20855E-07 -7.6808 0.19576E-07 -7.7083 0.93863E+00 -0.0275 58 MgCO3,aq 0.12482E-11 -11.9037 0.12482E-11 -11.9037 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.14215E-12 -12.8473 0.13345E-12 -12.8747 0.93878E+00 -0.0274 60 MgCl+ 0.92040E-13 -13.0360 0.86405E-13 -13.0635 0.93878E+00 -0.0274 61 MgOH+ 0.16985E-09 -9.7699 0.15946E-09 -9.7974 0.93878E+00 -0.0274 63 MnO,aq 0.29501E-09 -9.5302 0.29501E-09 -9.5302 0.10000E+01 0.0000 64 MnOH+ 0.10325E-08 -8.9861 0.96926E-09 -9.0136 0.93878E+00 -0.0274 65 MnO2-2 0.94335E-14 -14.0253 0.77327E-14 -14.1117 0.81970E+00 -0.0863 66 HMnO2- 0.20309E-11 -11.6923 0.19062E-11 -11.7198 0.93863E+00 -0.0275 69 MnCl+ 0.30634E-12 -12.5138 0.28758E-12 -12.5412 0.93878E+00 -0.0274 70 MnSO4,aq 0.21757E-11 -11.6624 0.21757E-11 -11.6624 0.10000E+01 0.0000 71 NaCl,aq 0.44560E-07 -7.3511 0.44560E-07 -7.3511 0.10000E+01 0.0000 72 NaOH,aq 0.39651E-06 -6.4017 0.39651E-06 -6.4017 0.10000E+01 0.0000 74 OH- 0.54714E-03 -3.2619 0.51348E-03 -3.2895 0.93848E+00 -0.0276 79 HPO3-2 0.20521E-17 -17.6878 0.16821E-17 -17.7741 0.81970E+00 -0.0863 82 H3PO4,aq 0.10277E-13 -13.9881 0.10277E-13 -13.9881 0.10000E+01 0.0000 83 H2PO4- 0.25664E-07 -7.5907 0.24091E-07 -7.6181 0.93870E+00 -0.0275 84 PO4-3 0.12828E-08 -8.8918 0.84156E-09 -9.0749 0.65602E+00 -0.1831 87 H2P2O7-2 0.55517E-16 -16.2556 0.45507E-16 -16.3419 0.81970E+00 -0.0863 88 HP2O7-3 0.12360E-13 -13.9080 0.80755E-14 -14.0928 0.65334E+00 -0.1849 89 P2O7-4 0.35958E-14 -14.4442 0.17145E-14 -14.7659 0.47681E+00 -0.3217 90 H2S,aq 0.18149E-15 -15.7412 0.18144E-15 -15.7413 0.99974E+00 -0.0001 97 SO3-2 0.15387E-14 -14.8128 0.12629E-14 -14.8986 0.82071E+00 -0.0858 98 HSO3- 0.94789E-16 -16.0232 0.88971E-16 -16.0508 0.93863E+00 -0.0275 99 HSO4- 0.24135E-10 -10.6174 0.22659E-10 -10.6448 0.93885E+00 -0.0274 Charge balance for all species = -.5864E-14 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.1198180E-08 -.1046279E-02 -.1054462E+01 0.0000 2 H2O 0.1000000E+01 0.5550845E+02 0.9998829E+06 0.0000 3 Cl- 0.1379504E-03 0.1379951E-03 0.4891761E+01 5.0610 4 SO4-- 0.2548707E-04 0.2550843E-04 0.2450091E+01 13.2176 5 HCO3- 0.1197932E-04 0.1307198E-04 0.7975213E+00 3.9997 6 HS- 0.5558475E-13 -.9332674E-10 -.3086136E-05 -4.3338 7 Al+++ 0.9435878E-24 0.2458628E-04 0.6632961E+00 2.6362 8 H4SiO4 0.4447102E-03 0.8440740E-03 0.8111890E+02 -3.3519 9 Ca++ 0.7211179E-07 0.7769721E-07 0.3113580E-02 10.6690 10 Mg++ 0.5554737E-09 0.7318787E-09 0.1779133E-04 8.5555 11 Fe++ 0.3277068E-11 0.2662167E-08 0.1486564E-03 6.3264 12 K+ 0.6431002E-04 0.6435393E-04 0.2516069E+01 4.7296 13 Na+ 0.1106331E-02 0.1112970E-02 0.2558392E+02 5.9651 14 Mn++ 0.4402839E-09 0.1772278E-08 0.9735387E-04 8.4546 15 HPO4-- 0.1415617E-05 0.1442564E-05 0.1384394E+00 11.9622 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.1255487E-01 -.1046121E-02 -.1150875E-01 0.0000000E+00 2 H2O 0.5549874E+02 0.5550003E+02 -.1291397E-02 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.4653895E-04 0.2550456E-04 0.2103438E-04 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.2103448E-04 -.9331259E-10 -.2103438E-04 0.0000000E+00 7 Al+++ 0.2474903E-02 0.2458255E-04 0.2450320E-02 0.0000000E+00 8 H4SiO4 0.7903302E-02 0.8439460E-03 0.7059356E-02 0.0000000E+00 9 Ca++ 0.8874293E-03 0.7768542E-07 0.8873516E-03 0.0000000E+00 10 Mg++ 0.6023810E-03 0.7317677E-09 0.6023802E-03 0.0000000E+00 11 Fe++ 0.5411735E-03 0.2661763E-08 0.5411709E-03 0.0000000E+00 12 K+ 0.1611465E-03 0.6434416E-04 0.9680233E-04 0.0000000E+00 13 Na+ 0.1112801E-02 0.1112801E-02 0.0000000E+00 0.0000000E+00 14 Mn++ 0.1315999E-04 0.1772009E-08 0.1315822E-04 0.0000000E+00 15 HPO4-- 0.4491441E-05 0.1442345E-05 0.3049096E-05 0.0000000E+00 Chg. balance for solid moles: -.7700E-18 Mass of aqueous solution: 0.999967E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 0.7590000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) apatite-OH 0.1016E-05 -5.993 0.5105E-03 -3.292 0.6411E-01 0.1622E-03 clinochlore 0.1205E-03 -3.919 0.6696E-01 -1.174 8.409 0.2547E-01 daphnite 0.7458E-04 -4.127 0.5321E-01 -1.274 6.683 0.1613E-01 chlorite-Mn 0.2632E-05 -5.580 0.1866E-02 -2.729 0.2343 0.5946E-03 hematite 0.8414E-04 -4.075 0.1344E-01 -1.872 1.687 0.2547E-02 muscovite 0.9680E-04 -4.014 0.3856E-01 -1.414 4.842 0.1363E-01 stilbite 0.8823E-03 -3.054 0.6218 -0.206 78.08 0.2900 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.6094E+00 0.6094E+00 1.0000 -0.215 daphnite 0.3773E+00 0.3773E+00 1.0000 -0.423 chlorite-Mn 0.1331E-01 0.1331E-01 1.0000 -1.876 hematite 0.1000E+01 0.1000E+01 1.0000 0.000 muscovite 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 0.796301 g Volume = 0.348531 cm3 Porosity: 73.2640% V(tot) - V(min): 0.95507E+00 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.7590000 g log = -0.1198 Original solution: 1000.0103000 g Original solution / Rock added: 1317.54 (Water/Rock Ratio), log = 3.1198 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0203 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.1000E+01 0.9860 0.1006E+01 0.1020E+01 CO2,gas 0.2815E-05 1.0071 0.2893E-05 0.2872E-05 CH4,gas 0.3886E-16 1.0125 0.4015E-16 0.3965E-16 H2,gas 0.5981E-06 1.0005 0.6106E-06 0.6103E-06 H2S,gas 0.4908E-14 0.9960 0.4988E-14 0.5008E-14 S2,gas 0.2455E-35 1.0000 0.2505E-35 0.2505E-35 CO,gas 0.4614E-15 1.0000 0.4707E-15 0.4707E-15 SO3,gas 0.9804E-38 1.0000 0.1000E-37 0.1000E-37 SO2,gas 0.2329E-21 1.0000 0.2376E-21 0.2376E-21 HCl,gas 0.4617E-16 1.0000 0.4711E-16 0.4711E-16 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 32 apatite-OH -18.15 -18.15 0.00 0.000 -0.60662E-11 46 clinochlore 39.07 39.07 0.00 0.000 0.00000E+00 47 daphnite 28.97 28.97 0.00 0.000 -0.60662E-11 48 chlorite-Mn 46.87 46.87 0.00 0.000 0.12132E-10 90 hematite 12.57 12.57 0.00 0.000 0.30331E-11 120 muscovite 2.58 2.58 0.00 0.000 0.60662E-11 163 stilbite -7.52 -7.52 0.00 0.000 -0.90992E-11 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -13.90 -7.24 -2.413 0.12358E+05 -5.539 3 CH4,gas 4.54 -13.55 -18.10 -4.524 0.30897E+05 -16.396 4 H2,gas 8.00 0.09 -7.91 -4.522 0.13512E+05 -6.214 5 H2S,gas -6.23 -22.23 -16.00 -8.001 0.27321E+05 -14.302 6 S2,gas -7.34 -44.64 -37.30 -5.738 0.63689E+05 -35.601 7 CO,gas 3.21 -13.81 -17.03 -5.239 0.29072E+05 -15.327 8 SO3,gas 17.12 -22.58 -39.70 -9.925 0.67785E+05 -38.000 9 SO2,gas 0.83 -22.49 -23.32 -6.219 0.39824E+05 -21.624 10 HCl,gas 5.19 -12.84 -18.03 -9.013 0.30779E+05 -16.327 11 acmite 7.71 5.54 -2.17 -0.225 0.36972E+04 15 albite-high 0.69 -1.45 -2.15 -0.165 0.36668E+04 16 albite -0.38 -1.45 -1.07 -0.082 0.18280E+04 19 spessartine 24.46 20.58 -3.88 -0.194 0.66195E+04 20 analcite 3.32 1.90 -1.42 -0.158 0.24321E+04 21 andalusite 5.00 1.92 -3.08 -0.308 0.52608E+04 22 andradite 39.01 34.52 -4.49 -0.233 0.76688E+04 26 annite 20.12 16.29 -3.83 -0.213 0.65469E+04 27 phlogopite 27.06 22.98 -4.09 -0.227 0.69803E+04 29 anorthite 12.71 9.24 -3.47 -0.267 0.59296E+04 35 aragonite 0.97 -3.23 -4.20 -1.398 0.71634E+04 36 brucite 12.57 8.56 -4.01 -0.803 0.68522E+04 37 calcite 0.81 -3.23 -4.04 -1.347 0.68991E+04 38 carnegieite-low 9.02 5.25 -3.77 -0.539 0.64438E+04 39 carnegieite-high 10.09 5.25 -4.84 -0.692 0.82708E+04 40 carpholite-Mg 8.58 7.12 -1.46 -0.097 0.24896E+04 41 carpholite-Fe 6.71 4.89 -1.82 -0.121 0.31037E+04 42 celadonite 5.34 2.51 -2.83 -0.166 0.48287E+04 43 celadonite-Fe 3.88 0.28 -3.59 -0.211 0.61333E+04 44 chrysotile 23.89 18.96 -4.93 -0.411 0.84174E+04 50 chloritoid-Mg 13.20 10.48 -2.72 -0.181 0.46473E+04 51 chloritoid-Fe 9.17 8.25 -0.93 -0.062 0.15825E+04 52 chloritoid-Mn 11.40 10.38 -1.03 -0.068 0.17518E+04 54 coesite -2.38 -3.35 -0.98 -0.325 0.16663E+04 59 corundum 8.38 5.27 -3.11 -0.283 0.53115E+04 61 cristobalite -2.56 -3.35 -0.79 -0.264 0.13516E+04 63 cymrite-K 1.69 -2.69 -4.38 -0.365 0.74708E+04 65 diaspore 2.87 2.64 -0.24 -0.040 0.40552E+03 67 diopside 16.18 12.52 -3.66 -0.366 0.62505E+04 68 hedenbergite 14.21 10.29 -3.92 -0.392 0.66878E+04 75 epidote 24.67 22.84 -1.83 -0.089 0.31284E+04 76 clinozoisite 22.81 19.19 -3.62 -0.164 0.61728E+04 77 epidote-Fe 29.84 26.48 -3.36 -0.174 0.57306E+04 78 fayalite 14.05 9.30 -4.74 -0.678 0.81018E+04 83 gibbsite 4.08 2.64 -1.44 -0.206 0.24641E+04 87 greenalite 16.14 12.28 -3.86 -0.322 0.65981E+04 91 heulandite -5.83 -7.52 -1.69 -0.077 0.28938E+04 95 jadeite 4.22 1.90 -2.32 -0.232 0.39576E+04 97 kalsilite 7.58 4.01 -3.57 -0.510 0.60957E+04 98 kaolinite -1.33 -1.43 -0.10 -0.009 0.16849E+03 99 kyanite 4.88 1.92 -2.96 -0.296 0.50467E+04 101 laumontite 2.88 2.53 -0.35 -0.023 0.59709E+03 102 lawsonite 9.62 9.24 -0.38 -0.025 0.64629E+03 103 leucite 4.12 0.66 -3.46 -0.346 0.59026E+04 105 lizardite 23.24 18.96 -4.28 -0.357 0.73100E+04 107 magnetite 20.09 18.89 -1.19 -0.098 0.20402E+04 108 minnesotaite 10.39 5.57 -4.82 -0.283 0.82244E+04 113 margarite 17.32 14.51 -2.81 -0.113 0.48042E+04 116 microcline -2.49 -2.69 -0.20 -0.016 0.34743E+03 121 paragonite 4.24 3.82 -0.42 -0.025 0.71963E+03 122 nepheline 8.34 5.25 -3.09 -0.441 0.52762E+04 136 prehnite 19.37 16.55 -2.82 -0.166 0.48103E+04 137 prehnite-Fe 22.50 20.20 -2.30 -0.138 0.39209E+04 138 pumpellyite-Fe 46.27 42.07 -4.20 -0.093 0.71672E+04 139 pumpellyite-Mg 48.99 44.30 -4.69 -0.104 0.80147E+04 145 pyroxmangite 7.40 5.10 -2.30 -0.459 0.39203E+04 146 pyrophyllite -6.18 -8.14 -1.96 -0.122 0.33458E+04 147 quartz -2.99 -3.35 -0.36 -0.121 0.61894E+03 151 rhodochrosite -0.98 -5.44 -4.47 -1.489 0.76270E+04 152 rhodonite 7.45 5.10 -2.34 -0.469 0.40005E+04 153 sanidine -1.28 -2.69 -1.41 -0.109 0.24152E+04 155 siderite -2.61 -7.57 -4.96 -1.654 0.84747E+04 156 sillimanite 5.26 1.92 -3.34 -0.334 0.57047E+04 164 stilpnomelane-Fe 13.02 12.45 -0.56 -0.017 0.96190E+03 165 stilpnomelane-Mg 27.44 23.60 -3.84 -0.115 0.65603E+04 168 sudoite 21.08 17.60 -3.48 -0.112 0.59374E+04 171 talc 16.49 12.26 -4.23 -0.249 0.72265E+04 174 tephroite 18.09 13.56 -4.53 -0.647 0.77322E+04 177 topaz-H 4.62 1.92 -2.70 -0.245 0.46068E+04 178 tridymite -2.63 -3.35 -0.73 -0.242 0.12389E+04 187 wairakite 3.95 2.53 -1.42 -0.083 0.24191E+04 188 walstromite 11.51 7.32 -4.19 -0.838 0.71580E+04 189 wollastonite 10.46 7.32 -3.14 -0.629 0.53684E+04 190 pseudo-wollastonite 11.00 7.32 -3.68 -0.737 0.62882E+04 191 zoisite 22.85 19.19 -3.66 -0.166 0.62469E+04 192 akaganeite 7.75 6.28 -1.47 -0.318 0.25125E+04 193 beidellite-Ca -1.65 -4.40 -2.75 -0.170 0.47010E+04 194 beidellite-H -2.33 -6.16 -3.83 -0.245 0.65447E+04 195 beidellite-K -1.52 -4.60 -3.08 -0.189 0.52560E+04 196 beidellite-Mg -1.79 -4.75 -2.96 -0.183 0.50503E+04 197 beidellite-Na -1.34 -4.19 -2.85 -0.174 0.48637E+04 199 chalcedony -2.80 -3.35 -0.55 -0.183 0.93824E+03 201 montmorillonite-Ca -2.29 -4.42 -2.13 -0.132 0.36383E+04 202 montmorillonite-K -2.24 -4.62 -2.38 -0.146 0.40714E+04 203 montmorillonite-Mg -2.48 -4.77 -2.29 -0.142 0.39108E+04 204 montmorillonite-Na -2.04 -4.21 -2.18 -0.133 0.37148E+04 205 nontronite-Ca 3.21 2.89 -0.32 -0.021 0.54568E+03 206 nontronite-H 2.53 1.13 -1.40 -0.094 0.23873E+04 207 nontronite-K 3.34 2.70 -0.65 -0.041 0.11019E+04 208 nontronite-Mg 3.07 2.55 -0.53 -0.034 0.90221E+03 209 nontronite-Na 3.52 3.10 -0.42 -0.027 0.71139E+03 224 tobermorite 9.82 5.54 -4.29 -1.170 0.73211E+04 233 boehmite 4.41 2.64 -1.77 -0.295 0.30224E+04 235 ferrous-oxide 9.81 6.33 -3.49 -0.871 0.59509E+04 240 silica-amorphous -2.09 -3.35 -1.26 -0.420 0.21524E+04 242 an20ab80 2.02 0.68 -1.33 -0.103 0.22774E+04 243 an25ab75 2.65 1.22 -1.43 -0.110 0.24368E+04 244 an30ab70 3.28 1.75 -1.53 -0.117 0.26057E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 0.0200000 g Current total amount of reactant added: 0.7590000 g New total amount of reactant added: 0.7790000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.5861E-14 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 6 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 0.7790000 Water: Moles liquid = 0.5550E+02 kg liquid = 0.9998E+00 Moles total = 0.5550E+02 kg total = 0.9998E+00 Activity = 1.0000 Stoichiometric ionic strength = .8415577E-03 Osmotic coef. = 0.9831 True ionic strength = .1225101E-02 Chg. balance for total moles = -.5861E-14 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.11750E-08 -8.9300 0.11029E-08 -8.9575 0.93867E+00 -0.0275 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13795E-03 -3.8603 0.12942E-03 -3.8880 0.93818E+00 -0.0277 4 SO4-- 0.25487E-04 -4.5937 0.20856E-04 -4.6808 0.81832E+00 -0.0871 5 HCO3- 0.11959E-04 -4.9223 0.11221E-04 -4.9500 0.93830E+00 -0.0277 6 HS- 0.55375E-13 -13.2567 0.51952E-13 -13.2844 0.93820E+00 -0.0277 7 Al+++ 0.86669E-24 -24.0621 0.56384E-24 -24.2488 0.65056E+00 -0.1867 8 H4SiO4 0.45176E-03 -3.3451 0.45176E-03 -3.3451 0.10000E+01 0.0000 9 Ca++ 0.65900E-07 -7.1811 0.53894E-07 -7.2685 0.81782E+00 -0.0873 10 Mg++ 0.53584E-09 -9.2710 0.43805E-09 -9.3585 0.81750E+00 -0.0875 11 Fe++ 0.31612E-11 -11.5001 0.25845E-11 -11.5876 0.81757E+00 -0.0875 12 K+ 0.65647E-04 -4.1828 0.61598E-04 -4.2104 0.93832E+00 -0.0276 13 Na+ 0.11311E-02 -2.9465 0.10611E-02 -2.9742 0.93817E+00 -0.0277 14 Mn++ 0.42472E-09 -9.3719 0.34727E-09 -9.4593 0.81763E+00 -0.0874 15 HPO4-- 0.16096E-05 -5.7933 0.13172E-05 -5.8804 0.81833E+00 -0.0871 16 HSiO3- 0.40767E-03 -3.3897 0.38247E-03 -3.4174 0.93818E+00 -0.0277 17 Ca(HSiO3)+ 0.50029E-09 -9.3008 0.46944E-09 -9.3284 0.93834E+00 -0.0276 18 Mg(HSiO3)+ 0.50606E-11 -11.2958 0.47485E-11 -11.3234 0.93834E+00 -0.0276 19 NaHSiO3,aq 0.65641E-05 -5.1828 0.65641E-05 -5.1828 0.10000E+01 0.0000 20 AlO+ 0.67206E-13 -13.1726 0.63062E-13 -13.2002 0.93834E+00 -0.0276 21 AlOH+2 0.42353E-18 -18.3731 0.34632E-18 -18.4605 0.81770E+00 -0.0874 22 HAlO2,aq 0.11387E-07 -7.9436 0.11387E-07 -7.9436 0.10000E+01 0.0000 23 AlO2- 0.24364E-04 -4.6132 0.22855E-04 -4.6410 0.93804E+00 -0.0278 24 CH4,aq 0.27158E-19 -19.5661 0.27151E-19 -19.5662 0.99974E+00 -0.0001 29 CO,aq 0.31031E-18 -18.5082 0.31031E-18 -18.5082 0.10000E+01 0.0000 30 CO2,aq 0.26450E-07 -7.5776 0.26443E-07 -7.5777 0.99974E+00 -0.0001 31 CO3-2 0.10862E-05 -5.9641 0.88867E-06 -6.0513 0.81817E+00 -0.0872 32 CaCO3,aq 0.60054E-09 -9.2215 0.60054E-09 -9.2215 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.16451E-10 -10.7838 0.15437E-10 -10.8114 0.93834E+00 -0.0276 34 CaCl+ 0.12030E-10 -10.9197 0.11288E-10 -10.9474 0.93834E+00 -0.0276 35 CaCl2,aq 0.34708E-15 -15.4596 0.34708E-15 -15.4596 0.10000E+01 0.0000 36 CaOH+ 0.37116E-08 -8.4304 0.34827E-08 -8.4581 0.93834E+00 -0.0276 37 CaSO4,aq 0.35694E-09 -9.4474 0.35694E-09 -9.4474 0.10000E+01 0.0000 38 HCl,aq 0.26156E-13 -13.5824 0.26156E-13 -13.5824 0.10000E+01 0.0000 43 FeCl+ 0.56425E-15 -15.2485 0.52945E-15 -15.2762 0.93834E+00 -0.0276 46 FeO,aq 0.82582E-10 -10.0831 0.82582E-10 -10.0831 0.10000E+01 0.0000 47 FeOH+ 0.81294E-10 -10.0899 0.76281E-10 -10.1176 0.93834E+00 -0.0276 48 HFeO2- 0.83508E-09 -9.0783 0.78345E-09 -9.1060 0.93818E+00 -0.0277 49 FeO+ 0.89714E-14 -14.0471 0.84182E-14 -14.0748 0.93834E+00 -0.0276 51 FeO2- 0.15094E-08 -8.8212 0.14161E-08 -8.8489 0.93818E+00 -0.0277 52 HFeO2,aq 0.19864E-09 -9.7019 0.19864E-09 -9.7019 0.10000E+01 0.0000 53 H2,aq 0.46726E-09 -9.3304 0.46713E-09 -9.3306 0.99974E+00 -0.0001 54 KCl,aq 0.14449E-09 -9.8402 0.14449E-09 -9.8402 0.10000E+01 0.0000 55 KHSO4,aq 0.40061E-17 -17.3973 0.40061E-17 -17.3973 0.10000E+01 0.0000 56 KOH,aq 0.23852E-07 -7.6225 0.23852E-07 -7.6225 0.10000E+01 0.0000 57 KSO4- 0.21249E-07 -7.6727 0.19936E-07 -7.7004 0.93818E+00 -0.0277 58 MgCO3,aq 0.12235E-11 -11.9124 0.12235E-11 -11.9124 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.13663E-12 -12.8645 0.12821E-12 -12.8921 0.93834E+00 -0.0276 60 MgCl+ 0.88619E-13 -13.0525 0.83155E-13 -13.0801 0.93834E+00 -0.0276 61 MgOH+ 0.16693E-09 -9.7775 0.15664E-09 -9.8051 0.93834E+00 -0.0276 63 MnO,aq 0.29566E-09 -9.5292 0.29566E-09 -9.5292 0.10000E+01 0.0000 64 MnOH+ 0.10147E-08 -8.9937 0.95213E-09 -9.0213 0.93834E+00 -0.0276 65 MnO2-2 0.98595E-14 -14.0061 0.80668E-14 -14.0933 0.81817E+00 -0.0872 66 HMnO2- 0.20776E-11 -11.6824 0.19491E-11 -11.7102 0.93818E+00 -0.0277 69 MnCl+ 0.29495E-12 -12.5303 0.27676E-12 -12.5579 0.93834E+00 -0.0276 70 MnSO4,aq 0.20909E-11 -11.6797 0.20909E-11 -11.6797 0.10000E+01 0.0000 71 NaCl,aq 0.45513E-07 -7.3419 0.45513E-07 -7.3419 0.10000E+01 0.0000 72 NaOH,aq 0.41338E-06 -6.3837 0.41338E-06 -6.3837 0.10000E+01 0.0000 74 OH- 0.55848E-03 -3.2530 0.52387E-03 -3.2808 0.93804E+00 -0.0278 79 HPO3-2 0.23436E-17 -17.6301 0.19175E-17 -17.7173 0.81817E+00 -0.0872 82 H3PO4,aq 0.11205E-13 -13.9506 0.11205E-13 -13.9506 0.10000E+01 0.0000 83 H2PO4- 0.28562E-07 -7.5442 0.26798E-07 -7.5719 0.93826E+00 -0.0277 84 PO4-3 0.14915E-08 -8.8264 0.97441E-09 -9.0113 0.65331E+00 -0.1849 87 H2P2O7-2 0.68823E-16 -16.1623 0.56309E-16 -16.2494 0.81817E+00 -0.0872 88 HP2O7-3 0.15670E-13 -13.8049 0.10195E-13 -13.9916 0.65059E+00 -0.1867 89 P2O7-4 0.46660E-14 -14.3311 0.22083E-14 -14.6559 0.47327E+00 -0.3249 90 H2S,aq 0.17713E-15 -15.7517 0.17708E-15 -15.7518 0.99974E+00 -0.0001 97 SO3-2 0.15455E-14 -14.8109 0.12661E-14 -14.8975 0.81919E+00 -0.0866 98 HSO3- 0.93188E-16 -16.0306 0.87427E-16 -16.0584 0.93818E+00 -0.0277 99 HSO4- 0.23623E-10 -10.6267 0.22168E-10 -10.6543 0.93841E+00 -0.0276 Charge balance for all species = -.5856E-14 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.1174950E-08 -.1071690E-02 -.1080069E+01 0.0000 2 H2O 0.1000000E+01 0.5550844E+02 0.9998802E+06 0.0000 3 Cl- 0.1379500E-03 0.1379956E-03 0.4891767E+01 5.0695 4 SO4-- 0.2548681E-04 0.2550853E-04 0.2450094E+01 13.2342 5 HCO3- 0.1195880E-04 0.1307203E-04 0.7975223E+00 4.0075 6 HS- 0.5537455E-13 -.9664293E-10 -.3195788E-05 -4.3269 7 Al+++ 0.8666915E-24 0.2437569E-04 0.6576131E+00 2.6236 8 H4SiO4 0.4517594E-03 0.8659988E-03 0.8322574E+02 -3.3451 9 Ca++ 0.6590036E-07 0.7109817E-07 0.2849127E-02 10.6465 10 Mg++ 0.5358396E-09 0.7092787E-09 0.1724190E-04 8.5565 11 Fe++ 0.3161229E-11 0.2710215E-08 0.1513391E-03 6.3273 12 K+ 0.6564675E-04 0.6569200E-04 0.2568377E+01 4.7470 13 Na+ 0.1131060E-02 0.1138083E-02 0.2616113E+02 5.9832 14 Mn++ 0.4247224E-09 0.1739554E-08 0.9555603E-04 8.4556 15 HPO4-- 0.1609568E-05 0.1639621E-05 0.1573501E+00 12.0346 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.1288604E-01 -.1071524E-02 -.1181452E-01 0.0000000E+00 2 H2O 0.5549849E+02 0.5549981E+02 -.1325156E-02 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.4709322E-04 0.2550457E-04 0.2158865E-04 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.2158875E-04 -.9662790E-10 -.2158865E-04 0.0000000E+00 7 Al+++ 0.2540118E-02 0.2437190E-04 0.2515746E-02 0.0000000E+00 8 H4SiO4 0.8111558E-02 0.8658641E-03 0.7245694E-02 0.0000000E+00 9 Ca++ 0.9104322E-03 0.7108711E-07 0.9103611E-03 0.0000000E+00 10 Mg++ 0.6182540E-03 0.7091684E-09 0.6182533E-03 0.0000000E+00 11 Fe++ 0.5554337E-03 0.2709794E-08 0.5554310E-03 0.0000000E+00 12 K+ 0.1653928E-03 0.6568178E-04 0.9971100E-04 0.0000000E+00 13 Na+ 0.1137906E-02 0.1137906E-02 0.0000000E+00 0.0000000E+00 14 Mn++ 0.1350677E-04 0.1739283E-08 0.1350503E-04 0.0000000E+00 15 HPO4-- 0.4609792E-05 0.1639366E-05 0.2970426E-05 0.0000000E+00 Chg. balance for solid moles: 0.2321E-18 Mass of aqueous solution: 0.999966E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 0.7790000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) apatite-OH 0.9901E-06 -6.004 0.4974E-03 -3.303 0.6085E-01 0.1580E-03 clinochlore 0.1237E-03 -3.908 0.6873E-01 -1.163 8.409 0.2614E-01 daphnite 0.7654E-04 -4.116 0.5462E-01 -1.263 6.682 0.1655E-01 chlorite-Mn 0.2701E-05 -5.568 0.1915E-02 -2.718 0.2343 0.6102E-03 hematite 0.8635E-04 -4.064 0.1379E-01 -1.860 1.687 0.2614E-02 muscovite 0.9971E-04 -4.001 0.3972E-01 -1.401 4.859 0.1404E-01 stilbite 0.9054E-03 -3.043 0.6381 -0.195 78.07 0.2976 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.6094E+00 0.6094E+00 1.0000 -0.215 daphnite 0.3773E+00 0.3773E+00 1.0000 -0.423 chlorite-Mn 0.1331E-01 0.1331E-01 1.0000 -1.876 hematite 0.1000E+01 0.1000E+01 1.0000 0.000 muscovite 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 0.817324 g Volume = 0.357722 cm3 Porosity: 72.7263% V(tot) - V(min): 0.95388E+00 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.7790000 g log = -0.1085 Original solution: 1000.0103000 g Original solution / Rock added: 1283.71 (Water/Rock Ratio), log = 3.1085 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0203 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.1000E+01 0.9860 0.1006E+01 0.1020E+01 CO2,gas 0.2753E-05 1.0071 0.2829E-05 0.2809E-05 CH4,gas 0.3868E-16 1.0125 0.3996E-16 0.3947E-16 H2,gas 0.6008E-06 1.0005 0.6133E-06 0.6130E-06 H2S,gas 0.4790E-14 0.9960 0.4868E-14 0.4887E-14 S2,gas 0.2318E-35 1.0000 0.2365E-35 0.2365E-35 CO,gas 0.4532E-15 1.0000 0.4624E-15 0.4624E-15 SO3,gas 0.9401E-38 1.0000 0.9592E-38 0.9592E-38 SO2,gas 0.2243E-21 1.0000 0.2289E-21 0.2289E-21 HCl,gas 0.4524E-16 1.0000 0.4615E-16 0.4615E-16 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 32 apatite-OH -18.15 -18.15 0.00 0.000 0.12132E-10 46 clinochlore 39.07 39.07 0.00 0.000 0.24265E-10 47 daphnite 28.97 28.97 0.00 0.000 0.36397E-10 48 chlorite-Mn 46.87 46.87 0.00 0.000 0.24265E-10 90 hematite 12.57 12.57 0.00 0.000 -0.90992E-11 120 muscovite 2.58 2.58 0.00 0.000 0.60662E-11 163 stilbite -7.52 -7.52 0.00 0.000 0.15165E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -13.91 -7.25 -2.416 0.12375E+05 -5.548 3 CH4,gas 4.54 -13.55 -18.10 -4.524 0.30901E+05 -16.398 4 H2,gas 8.00 0.09 -7.91 -4.521 0.13508E+05 -6.212 5 H2S,gas -6.23 -22.24 -16.01 -8.006 0.27339E+05 -14.313 6 S2,gas -7.34 -44.66 -37.33 -5.742 0.63732E+05 -35.626 7 CO,gas 3.21 -13.82 -17.03 -5.241 0.29085E+05 -15.335 8 SO3,gas 17.12 -22.60 -39.72 -9.929 0.67816E+05 -38.018 9 SO2,gas 0.83 -22.51 -23.34 -6.224 0.39851E+05 -21.640 10 HCl,gas 5.19 -12.85 -18.03 -9.017 0.30794E+05 -16.336 11 acmite 7.71 5.58 -2.13 -0.222 0.36430E+04 15 albite-high 0.69 -1.43 -2.12 -0.163 0.36225E+04 16 albite -0.38 -1.43 -1.04 -0.080 0.17837E+04 19 spessartine 24.46 20.58 -3.88 -0.194 0.66228E+04 20 analcite 3.32 1.92 -1.41 -0.156 0.23994E+04 21 andalusite 5.00 1.90 -3.10 -0.310 0.52923E+04 22 andradite 39.01 34.47 -4.54 -0.236 0.77492E+04 26 annite 20.12 16.32 -3.81 -0.211 0.64989E+04 27 phlogopite 27.06 23.00 -4.06 -0.226 0.69322E+04 29 anorthite 12.71 9.20 -3.51 -0.270 0.59879E+04 35 aragonite 0.97 -3.26 -4.23 -1.409 0.72183E+04 36 brucite 12.57 8.56 -4.01 -0.802 0.68506E+04 37 calcite 0.81 -3.26 -4.07 -1.358 0.69541E+04 38 carnegieite-low 9.02 5.26 -3.76 -0.537 0.64228E+04 39 carnegieite-high 10.09 5.26 -4.83 -0.690 0.82498E+04 40 carpholite-Mg 8.58 7.11 -1.47 -0.098 0.25078E+04 41 carpholite-Fe 6.71 4.88 -1.83 -0.122 0.31219E+04 42 celadonite 5.34 2.55 -2.79 -0.164 0.47723E+04 43 celadonite-Fe 3.88 0.32 -3.56 -0.209 0.60769E+04 44 chrysotile 23.89 18.98 -4.91 -0.409 0.83892E+04 50 chloritoid-Mg 13.20 10.46 -2.74 -0.183 0.46771E+04 51 chloritoid-Fe 9.17 8.23 -0.94 -0.063 0.16123E+04 52 chloritoid-Mn 11.40 10.36 -1.04 -0.070 0.17817E+04 54 coesite -2.38 -3.35 -0.97 -0.323 0.16546E+04 59 corundum 8.38 5.25 -3.14 -0.285 0.53546E+04 61 cristobalite -2.56 -3.35 -0.78 -0.262 0.13399E+04 63 cymrite-K 1.69 -2.66 -4.35 -0.363 0.74276E+04 65 diaspore 2.87 2.62 -0.25 -0.042 0.42710E+03 67 diopside 16.18 12.51 -3.67 -0.367 0.62640E+04 68 hedenbergite 14.21 10.28 -3.92 -0.392 0.67013E+04 75 epidote 24.67 22.79 -1.88 -0.091 0.32135E+04 76 clinozoisite 22.81 19.13 -3.68 -0.167 0.62795E+04 77 epidote-Fe 29.84 26.45 -3.39 -0.176 0.57941E+04 78 fayalite 14.05 9.31 -4.74 -0.677 0.80869E+04 83 gibbsite 4.08 2.62 -1.46 -0.208 0.24857E+04 87 greenalite 16.14 12.29 -3.85 -0.321 0.65699E+04 91 heulandite -5.83 -7.52 -1.69 -0.077 0.28938E+04 95 jadeite 4.22 1.92 -2.30 -0.230 0.39249E+04 97 kalsilite 7.58 4.03 -3.56 -0.508 0.60759E+04 98 kaolinite -1.33 -1.44 -0.11 -0.010 0.18833E+03 99 kyanite 4.88 1.90 -2.97 -0.297 0.50782E+04 101 laumontite 2.88 2.51 -0.37 -0.025 0.63208E+03 102 lawsonite 9.62 9.20 -0.41 -0.028 0.70461E+03 103 leucite 4.12 0.68 -3.44 -0.344 0.58711E+04 105 lizardite 23.24 18.98 -4.26 -0.355 0.72818E+04 107 magnetite 20.09 18.89 -1.19 -0.097 0.20385E+04 108 minnesotaite 10.39 5.60 -4.79 -0.282 0.81728E+04 113 margarite 17.32 14.45 -2.87 -0.115 0.49057E+04 116 microcline -2.49 -2.66 -0.18 -0.014 0.30426E+03 121 paragonite 4.24 3.82 -0.42 -0.025 0.71850E+03 122 nepheline 8.34 5.26 -3.08 -0.440 0.52552E+04 136 prehnite 19.37 16.50 -2.87 -0.169 0.48955E+04 137 prehnite-Fe 22.50 20.16 -2.33 -0.140 0.39844E+04 138 pumpellyite-Fe 46.27 41.96 -4.31 -0.096 0.73574E+04 139 pumpellyite-Mg 48.99 44.19 -4.81 -0.107 0.82049E+04 145 pyroxmangite 7.40 5.11 -2.29 -0.458 0.39070E+04 146 pyrophyllite -6.18 -8.13 -1.96 -0.122 0.33423E+04 147 quartz -2.99 -3.35 -0.36 -0.119 0.60728E+03 151 rhodochrosite -0.98 -5.45 -4.48 -1.492 0.76418E+04 152 rhodonite 7.45 5.11 -2.34 -0.467 0.39872E+04 153 sanidine -1.28 -2.66 -1.39 -0.107 0.23720E+04 155 siderite -2.61 -7.58 -4.97 -1.657 0.84895E+04 156 sillimanite 5.26 1.90 -3.36 -0.336 0.57363E+04 164 stilpnomelane-Fe 13.02 12.50 -0.52 -0.016 0.88870E+03 165 stilpnomelane-Mg 27.44 23.64 -3.80 -0.113 0.64871E+04 168 sudoite 21.08 17.57 -3.51 -0.113 0.59855E+04 171 talc 16.49 12.29 -4.20 -0.247 0.71749E+04 174 tephroite 18.09 13.57 -4.52 -0.646 0.77172E+04 177 topaz-H 4.62 1.90 -2.72 -0.247 0.46383E+04 178 tridymite -2.63 -3.35 -0.72 -0.240 0.12273E+04 187 wairakite 3.95 2.51 -1.44 -0.085 0.24540E+04 188 walstromite 11.51 7.30 -4.21 -0.842 0.71848E+04 189 wollastonite 10.46 7.30 -3.16 -0.632 0.53952E+04 190 pseudo-wollastonite 11.00 7.30 -3.70 -0.740 0.63150E+04 191 zoisite 22.85 19.13 -3.72 -0.169 0.63536E+04 192 akaganeite 7.75 6.28 -1.47 -0.318 0.25125E+04 193 beidellite-Ca -1.65 -4.41 -2.76 -0.171 0.47149E+04 194 beidellite-H -2.33 -6.16 -3.84 -0.245 0.65522E+04 195 beidellite-K -1.52 -4.60 -3.08 -0.188 0.52536E+04 196 beidellite-Mg -1.79 -4.75 -2.96 -0.183 0.50575E+04 197 beidellite-Na -1.34 -4.19 -2.85 -0.174 0.48610E+04 199 chalcedony -2.80 -3.35 -0.54 -0.181 0.92657E+03 201 montmorillonite-Ca -2.29 -4.42 -2.13 -0.132 0.36335E+04 202 montmorillonite-K -2.24 -4.61 -2.37 -0.145 0.40504E+04 203 montmorillonite-Mg -2.48 -4.76 -2.28 -0.141 0.38994E+04 204 montmorillonite-Na -2.04 -4.20 -2.16 -0.132 0.36935E+04 205 nontronite-Ca 3.21 2.91 -0.30 -0.020 0.51635E+03 206 nontronite-H 2.53 1.16 -1.38 -0.092 0.23516E+04 207 nontronite-K 3.34 2.72 -0.62 -0.040 0.10564E+04 208 nontronite-Mg 3.07 2.57 -0.51 -0.033 0.86626E+03 209 nontronite-Na 3.52 3.13 -0.39 -0.025 0.66551E+03 224 tobermorite 9.82 5.52 -4.30 -1.173 0.73415E+04 233 boehmite 4.41 2.62 -1.78 -0.297 0.30440E+04 235 ferrous-oxide 9.81 6.33 -3.48 -0.871 0.59493E+04 240 silica-amorphous -2.09 -3.35 -1.25 -0.418 0.21408E+04 242 an20ab80 2.02 0.70 -1.32 -0.102 0.22537E+04 243 an25ab75 2.65 1.23 -1.42 -0.109 0.24181E+04 244 an30ab70 3.28 1.76 -1.52 -0.117 0.25922E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 0.0200000 g Current total amount of reactant added: 0.7790000 g New total amount of reactant added: 0.7990000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.5860E-14 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 6 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 0.7990000 Water: Moles liquid = 0.5550E+02 kg liquid = 0.9998E+00 Moles total = 0.5550E+02 kg total = 0.9998E+00 Activity = 1.0000 Stoichiometric ionic strength = .8543031E-03 Osmotic coef. = 0.9830 True ionic strength = .1251392E-02 Chg. balance for total moles = -.5860E-14 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.11528E-08 -8.9383 0.10816E-08 -8.9659 0.93824E+00 -0.0277 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13795E-03 -3.8603 0.12936E-03 -3.8882 0.93775E+00 -0.0279 4 SO4-- 0.25487E-04 -4.5937 0.20818E-04 -4.6816 0.81681E+00 -0.0879 5 HCO3- 0.11938E-04 -4.9231 0.11197E-04 -4.9509 0.93786E+00 -0.0279 6 HS- 0.55214E-13 -13.2580 0.51777E-13 -13.2859 0.93776E+00 -0.0279 7 Al+++ 0.79797E-24 -24.0980 0.51697E-24 -24.2865 0.64785E+00 -0.1885 8 H4SiO4 0.45863E-03 -3.3385 0.45863E-03 -3.3385 0.10000E+01 0.0000 9 Ca++ 0.60451E-07 -7.2186 0.49346E-07 -7.3067 0.81630E+00 -0.0882 10 Mg++ 0.51746E-09 -9.2861 0.42224E-09 -9.3744 0.81597E+00 -0.0883 11 Fe++ 0.30528E-11 -11.5153 0.24912E-11 -11.6036 0.81605E+00 -0.0883 12 K+ 0.67004E-04 -4.1739 0.62842E-04 -4.2017 0.93789E+00 -0.0279 13 Na+ 0.11558E-02 -2.9371 0.10838E-02 -2.9650 0.93773E+00 -0.0279 14 Mn++ 0.41016E-09 -9.3870 0.33473E-09 -9.4753 0.81611E+00 -0.0883 15 HPO4-- 0.18198E-05 -5.7400 0.14865E-05 -5.8278 0.81682E+00 -0.0879 16 HSiO3- 0.42223E-03 -3.3745 0.39594E-03 -3.4024 0.93775E+00 -0.0279 17 Ca(HSiO3)+ 0.47442E-09 -9.3238 0.44496E-09 -9.3517 0.93790E+00 -0.0278 18 Mg(HSiO3)+ 0.50520E-11 -11.2965 0.47383E-11 -11.3244 0.93790E+00 -0.0278 19 NaHSiO3,aq 0.69405E-05 -5.1586 0.69405E-05 -5.1586 0.10000E+01 0.0000 20 AlO+ 0.64100E-13 -13.1931 0.60120E-13 -13.2210 0.93790E+00 -0.0278 21 AlOH+2 0.39671E-18 -18.4015 0.32378E-18 -18.4897 0.81618E+00 -0.0882 22 HAlO2,aq 0.11070E-07 -7.9559 0.11070E-07 -7.9559 0.10000E+01 0.0000 23 AlO2- 0.24163E-04 -4.6168 0.22655E-04 -4.6448 0.93760E+00 -0.0280 24 CH4,aq 0.27058E-19 -19.5677 0.27051E-19 -19.5678 0.99974E+00 -0.0001 29 CO,aq 0.30502E-18 -18.5157 0.30502E-18 -18.5157 0.10000E+01 0.0000 30 CO2,aq 0.25883E-07 -7.5870 0.25876E-07 -7.5871 0.99974E+00 -0.0001 31 CO3-2 0.11072E-05 -5.9558 0.90421E-06 -6.0437 0.81666E+00 -0.0880 32 CaCO3,aq 0.55948E-09 -9.2522 0.55948E-09 -9.2522 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.15037E-10 -10.8228 0.14103E-10 -10.8507 0.93790E+00 -0.0278 34 CaCl+ 0.11015E-10 -10.9580 0.10331E-10 -10.9859 0.93790E+00 -0.0278 35 CaCl2,aq 0.31749E-15 -15.4983 0.31749E-15 -15.4983 0.10000E+01 0.0000 36 CaOH+ 0.34669E-08 -8.4601 0.32516E-08 -8.4879 0.93790E+00 -0.0278 37 CaSO4,aq 0.32621E-09 -9.4865 0.32621E-09 -9.4865 0.10000E+01 0.0000 38 HCl,aq 0.25639E-13 -13.5911 0.25639E-13 -13.5911 0.10000E+01 0.0000 43 FeCl+ 0.54387E-15 -15.2645 0.51010E-15 -15.2923 0.93790E+00 -0.0278 46 FeO,aq 0.82768E-10 -10.0821 0.82768E-10 -10.0821 0.10000E+01 0.0000 47 FeOH+ 0.79940E-10 -10.0972 0.74976E-10 -10.1251 0.93790E+00 -0.0278 48 HFeO2- 0.85384E-09 -9.0686 0.80069E-09 -9.0965 0.93775E+00 -0.0279 49 FeO+ 0.88022E-14 -14.0554 0.82556E-14 -14.0833 0.93790E+00 -0.0278 51 FeO2- 0.15399E-08 -8.8125 0.14440E-08 -8.8404 0.93775E+00 -0.0279 52 HFeO2,aq 0.19864E-09 -9.7019 0.19864E-09 -9.7019 0.10000E+01 0.0000 53 H2,aq 0.46936E-09 -9.3285 0.46924E-09 -9.3286 0.99974E+00 -0.0001 54 KCl,aq 0.14734E-09 -9.8317 0.14734E-09 -9.8317 0.10000E+01 0.0000 55 KHSO4,aq 0.40007E-17 -17.3979 0.40007E-17 -17.3979 0.10000E+01 0.0000 56 KOH,aq 0.24813E-07 -7.6053 0.24813E-07 -7.6053 0.10000E+01 0.0000 57 KSO4- 0.21648E-07 -7.6646 0.20301E-07 -7.6925 0.93775E+00 -0.0279 58 MgCO3,aq 0.11999E-11 -11.9208 0.11999E-11 -11.9208 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.13147E-12 -12.8812 0.12331E-12 -12.9090 0.93790E+00 -0.0278 60 MgCl+ 0.85420E-13 -13.0684 0.80115E-13 -13.0963 0.93790E+00 -0.0278 61 MgOH+ 0.16415E-09 -9.7848 0.15396E-09 -9.8126 0.93790E+00 -0.0278 63 MnO,aq 0.29633E-09 -9.5282 0.29633E-09 -9.5282 0.10000E+01 0.0000 64 MnOH+ 0.99781E-09 -9.0010 0.93584E-09 -9.0288 0.93790E+00 -0.0278 65 MnO2-2 0.10294E-13 -13.9874 0.84066E-14 -14.0754 0.81666E+00 -0.0880 66 HMnO2- 0.21243E-11 -11.6728 0.19920E-11 -11.7007 0.93775E+00 -0.0279 69 MnCl+ 0.28430E-12 -12.5462 0.26665E-12 -12.5741 0.93790E+00 -0.0278 70 MnSO4,aq 0.20117E-11 -11.6964 0.20117E-11 -11.6964 0.10000E+01 0.0000 71 NaCl,aq 0.46464E-07 -7.3329 0.46464E-07 -7.3329 0.10000E+01 0.0000 72 NaOH,aq 0.43053E-06 -6.3660 0.43053E-06 -6.3660 0.10000E+01 0.0000 74 OH- 0.56975E-03 -3.2443 0.53419E-03 -3.2723 0.93760E+00 -0.0280 79 HPO3-2 0.26617E-17 -17.5748 0.21737E-17 -17.6628 0.81666E+00 -0.0880 82 H3PO4,aq 0.12162E-13 -13.9150 0.12162E-13 -13.9150 0.10000E+01 0.0000 83 H2PO4- 0.31625E-07 -7.5000 0.29659E-07 -7.5278 0.93782E+00 -0.0279 84 PO4-3 0.17234E-08 -8.7636 0.11213E-08 -8.9503 0.65064E+00 -0.1867 87 H2P2O7-2 0.84457E-16 -16.0734 0.68972E-16 -16.1613 0.81666E+00 -0.0880 88 HP2O7-3 0.19654E-13 -13.7066 0.12733E-13 -13.8951 0.64788E+00 -0.1885 89 P2O7-4 0.59867E-14 -14.2228 0.28125E-14 -14.5509 0.46979E+00 -0.3281 90 H2S,aq 0.17312E-15 -15.7616 0.17308E-15 -15.7618 0.99974E+00 -0.0001 97 SO3-2 0.15524E-14 -14.8090 0.12694E-14 -14.8964 0.81770E+00 -0.0874 98 HSO3- 0.91672E-16 -16.0378 0.85965E-16 -16.0657 0.93775E+00 -0.0279 99 HSO4- 0.23134E-10 -10.6357 0.21699E-10 -10.6636 0.93798E+00 -0.0278 Charge balance for all species = -.5865E-14 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.1152780E-08 -.1097119E-02 -.1105693E+01 0.0000 2 H2O 0.1000000E+01 0.5550844E+02 0.9998775E+06 0.0000 3 Cl- 0.1379495E-03 0.1379962E-03 0.4891773E+01 5.0777 4 SO4-- 0.2548654E-04 0.2550864E-04 0.2450097E+01 13.2503 5 HCO3- 0.1193842E-04 0.1307208E-04 0.7975232E+00 4.0150 6 HS- 0.5521367E-13 -.9992275E-10 -.3304236E-05 -4.3199 7 Al+++ 0.7979712E-24 0.2417420E-04 0.6521755E+00 2.6113 8 H4SiO4 0.4586319E-03 0.8877995E-03 0.8532064E+02 -3.3385 9 Ca++ 0.6045137E-07 0.6530443E-07 0.2616947E-02 10.6251 10 Mg++ 0.5174625E-09 0.6880812E-09 0.1672656E-04 8.5574 11 Fe++ 0.3052806E-11 0.2758157E-08 0.1540157E-03 6.3283 12 K+ 0.6700430E-04 0.6705090E-04 0.2621500E+01 4.7642 13 Na+ 0.1155779E-02 0.1163196E-02 0.2673834E+02 6.0009 14 Mn++ 0.4101571E-09 0.1708720E-08 0.9386202E-04 8.4566 15 HPO4-- 0.1819830E-05 0.1853178E-05 0.1778442E+00 12.1040 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.1321721E-01 -.1096944E-02 -.1212027E-01 0.0000000E+00 2 H2O 0.5549823E+02 0.5549959E+02 -.1359000E-02 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.4764748E-04 0.2550457E-04 0.2214291E-04 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.2214301E-04 -.9990682E-10 -.2214291E-04 0.0000000E+00 7 Al+++ 0.2605333E-02 0.2417035E-04 0.2581162E-02 0.0000000E+00 8 H4SiO4 0.8319814E-02 0.8876580E-03 0.7432156E-02 0.0000000E+00 9 Ca++ 0.9334350E-03 0.6529402E-07 0.9333697E-03 0.0000000E+00 10 Mg++ 0.6341270E-03 0.6879715E-09 0.6341263E-03 0.0000000E+00 11 Fe++ 0.5696939E-03 0.2757717E-08 0.5696911E-03 0.0000000E+00 12 K+ 0.1696391E-03 0.6704022E-04 0.1025988E-03 0.0000000E+00 13 Na+ 0.1163011E-02 0.1163011E-02 0.0000000E+00 0.0000000E+00 14 Mn++ 0.1385354E-04 0.1708447E-08 0.1385183E-04 0.0000000E+00 15 HPO4-- 0.4728144E-05 0.1852883E-05 0.2875261E-05 0.0000000E+00 Chg. balance for solid moles: -.2889E-17 Mass of aqueous solution: 0.999964E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 0.7990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) apatite-OH 0.9584E-06 -6.018 0.4814E-03 -3.317 0.5743E-01 0.1530E-03 clinochlore 0.1268E-03 -3.897 0.7049E-01 -1.152 8.409 0.2681E-01 daphnite 0.7851E-04 -4.105 0.5602E-01 -1.252 6.682 0.1697E-01 chlorite-Mn 0.2770E-05 -5.557 0.1964E-02 -2.707 0.2343 0.6259E-03 hematite 0.8857E-04 -4.053 0.1414E-01 -1.849 1.687 0.2681E-02 muscovite 0.1026E-03 -3.989 0.4087E-01 -1.389 4.875 0.1445E-01 stilbite 0.9286E-03 -3.032 0.6544 -0.184 78.06 0.3052 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.6094E+00 0.6094E+00 1.0000 -0.215 daphnite 0.3773E+00 0.3773E+00 1.0000 -0.423 chlorite-Mn 0.1331E-01 0.1331E-01 1.0000 -1.876 hematite 0.1000E+01 0.1000E+01 1.0000 0.000 muscovite 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 0.838354 g Volume = 0.366917 cm3 Porosity: 72.1948% V(tot) - V(min): 0.95268E+00 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.7990000 g log = -0.0975 Original solution: 1000.0103000 g Original solution / Rock added: 1251.58 (Water/Rock Ratio), log = 3.0975 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0203 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.1000E+01 0.9860 0.1006E+01 0.1020E+01 CO2,gas 0.2694E-05 1.0071 0.2768E-05 0.2749E-05 CH4,gas 0.3854E-16 1.0125 0.3982E-16 0.3932E-16 H2,gas 0.6035E-06 1.0005 0.6161E-06 0.6157E-06 H2S,gas 0.4682E-14 0.9960 0.4758E-14 0.4777E-14 S2,gas 0.2194E-35 1.0000 0.2239E-35 0.2239E-35 CO,gas 0.4455E-15 1.0000 0.4545E-15 0.4545E-15 SO3,gas 0.9025E-38 1.0000 0.9208E-38 0.9208E-38 SO2,gas 0.2163E-21 1.0000 0.2207E-21 0.2207E-21 HCl,gas 0.4434E-16 1.0000 0.4524E-16 0.4524E-16 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 32 apatite-OH -18.15 -18.15 0.00 0.000 0.60662E-11 46 clinochlore 39.07 39.07 0.00 0.000 0.00000E+00 47 daphnite 28.97 28.97 0.00 0.000 0.00000E+00 48 chlorite-Mn 46.87 46.87 0.00 0.000 0.00000E+00 90 hematite 12.57 12.57 0.00 0.000 0.30331E-11 120 muscovite 2.58 2.58 0.00 0.000 -0.18198E-10 163 stilbite -7.52 -7.52 0.00 0.000 -0.90992E-11 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -13.92 -7.26 -2.419 0.12391E+05 -5.558 3 CH4,gas 4.54 -13.56 -18.10 -4.525 0.30903E+05 -16.400 4 H2,gas 8.00 0.09 -7.91 -4.520 0.13505E+05 -6.210 5 H2S,gas -6.23 -22.25 -16.02 -8.011 0.27356E+05 -14.323 6 S2,gas -7.34 -44.68 -37.35 -5.746 0.63772E+05 -35.650 7 CO,gas 3.21 -13.83 -17.04 -5.244 0.29098E+05 -15.342 8 SO3,gas 17.12 -22.61 -39.73 -9.934 0.67846E+05 -38.036 9 SO2,gas 0.83 -22.52 -23.36 -6.228 0.39878E+05 -21.656 10 HCl,gas 5.19 -12.85 -18.04 -9.022 0.30809E+05 -16.344 11 acmite 7.71 5.61 -2.10 -0.218 0.35905E+04 15 albite-high 0.69 -1.40 -2.10 -0.161 0.35797E+04 16 albite -0.38 -1.40 -1.02 -0.078 0.17409E+04 19 spessartine 24.46 20.58 -3.88 -0.194 0.66261E+04 20 analcite 3.32 1.94 -1.39 -0.154 0.23678E+04 21 andalusite 5.00 1.88 -3.12 -0.312 0.53230E+04 22 andradite 39.01 34.43 -4.58 -0.238 0.78250E+04 26 annite 20.12 16.34 -3.78 -0.210 0.64519E+04 27 phlogopite 27.06 23.03 -4.03 -0.224 0.68852E+04 29 anorthite 12.71 9.17 -3.54 -0.272 0.60439E+04 35 aragonite 0.97 -3.29 -4.26 -1.419 0.72708E+04 36 brucite 12.57 8.56 -4.01 -0.802 0.68489E+04 37 calcite 0.81 -3.29 -4.10 -1.368 0.70066E+04 38 carnegieite-low 9.02 5.27 -3.75 -0.536 0.64024E+04 39 carnegieite-high 10.09 5.27 -4.82 -0.689 0.82294E+04 40 carpholite-Mg 8.58 7.10 -1.48 -0.099 0.25256E+04 41 carpholite-Fe 6.71 4.87 -1.84 -0.123 0.31398E+04 42 celadonite 5.34 2.58 -2.76 -0.163 0.47175E+04 43 celadonite-Fe 3.88 0.35 -3.53 -0.207 0.60221E+04 44 chrysotile 23.89 19.00 -4.90 -0.408 0.83618E+04 50 chloritoid-Mg 13.20 10.44 -2.76 -0.184 0.47062E+04 51 chloritoid-Fe 9.17 8.21 -0.96 -0.064 0.16414E+04 52 chloritoid-Mn 11.40 10.34 -1.06 -0.071 0.18107E+04 54 coesite -2.38 -3.34 -0.96 -0.321 0.16434E+04 59 corundum 8.38 5.22 -3.16 -0.287 0.53966E+04 61 cristobalite -2.56 -3.34 -0.78 -0.259 0.13288E+04 63 cymrite-K 1.69 -2.64 -4.33 -0.360 0.73857E+04 65 diaspore 2.87 2.61 -0.26 -0.044 0.44807E+03 67 diopside 16.18 12.51 -3.68 -0.368 0.62764E+04 68 hedenbergite 14.21 10.28 -3.93 -0.393 0.67136E+04 75 epidote 24.67 22.74 -1.93 -0.094 0.32947E+04 76 clinozoisite 22.81 19.07 -3.74 -0.170 0.63817E+04 77 epidote-Fe 29.84 26.41 -3.43 -0.178 0.58544E+04 78 fayalite 14.05 9.32 -4.73 -0.675 0.80724E+04 83 gibbsite 4.08 2.61 -1.47 -0.210 0.25066E+04 87 greenalite 16.14 12.31 -3.83 -0.319 0.65425E+04 91 heulandite -5.83 -7.52 -1.69 -0.077 0.28938E+04 95 jadeite 4.22 1.94 -2.28 -0.228 0.38933E+04 97 kalsilite 7.58 4.04 -3.55 -0.507 0.60564E+04 98 kaolinite -1.33 -1.45 -0.12 -0.011 0.20787E+03 99 kyanite 4.88 1.88 -2.99 -0.299 0.51089E+04 101 laumontite 2.88 2.49 -0.39 -0.026 0.66567E+03 102 lawsonite 9.62 9.17 -0.45 -0.030 0.76059E+03 103 leucite 4.12 0.70 -3.42 -0.342 0.58403E+04 105 lizardite 23.24 19.00 -4.25 -0.354 0.72544E+04 107 magnetite 20.09 18.89 -1.19 -0.097 0.20369E+04 108 minnesotaite 10.39 5.63 -4.76 -0.280 0.81231E+04 113 margarite 17.32 14.39 -2.93 -0.117 0.50036E+04 116 microcline -2.49 -2.64 -0.15 -0.012 0.26233E+03 121 paragonite 4.24 3.82 -0.42 -0.025 0.71765E+03 122 nepheline 8.34 5.27 -3.07 -0.438 0.52348E+04 136 prehnite 19.37 16.46 -2.91 -0.171 0.49767E+04 137 prehnite-Fe 22.50 20.13 -2.37 -0.142 0.40447E+04 138 pumpellyite-Fe 46.27 41.85 -4.42 -0.098 0.75392E+04 139 pumpellyite-Mg 48.99 44.08 -4.91 -0.109 0.83866E+04 145 pyroxmangite 7.40 5.12 -2.28 -0.456 0.38941E+04 146 pyrophyllite -6.18 -8.13 -1.96 -0.122 0.33394E+04 147 quartz -2.99 -3.34 -0.35 -0.116 0.59608E+03 151 rhodochrosite -0.98 -5.46 -4.48 -1.495 0.76562E+04 152 rhodonite 7.45 5.12 -2.33 -0.466 0.39744E+04 153 sanidine -1.28 -2.64 -1.36 -0.105 0.23301E+04 155 siderite -2.61 -7.59 -4.98 -1.660 0.85039E+04 156 sillimanite 5.26 1.88 -3.38 -0.338 0.57670E+04 164 stilpnomelane-Fe 13.02 12.54 -0.48 -0.014 0.81807E+03 165 stilpnomelane-Mg 27.44 23.68 -3.76 -0.112 0.64164E+04 168 sudoite 21.08 17.54 -3.53 -0.114 0.60324E+04 171 talc 16.49 12.32 -4.17 -0.245 0.71251E+04 174 tephroite 18.09 13.57 -4.51 -0.644 0.77027E+04 177 topaz-H 4.62 1.88 -2.73 -0.249 0.46690E+04 178 tridymite -2.63 -3.34 -0.71 -0.237 0.12161E+04 187 wairakite 3.95 2.49 -1.46 -0.086 0.24876E+04 188 walstromite 11.51 7.29 -4.22 -0.845 0.72100E+04 189 wollastonite 10.46 7.29 -3.17 -0.635 0.54205E+04 190 pseudo-wollastonite 11.00 7.29 -3.71 -0.743 0.63403E+04 191 zoisite 22.85 19.07 -3.78 -0.172 0.64558E+04 192 akaganeite 7.75 6.28 -1.47 -0.318 0.25125E+04 193 beidellite-Ca -1.65 -4.41 -2.77 -0.171 0.47287E+04 194 beidellite-H -2.33 -6.17 -3.84 -0.245 0.65600E+04 195 beidellite-K -1.52 -4.60 -3.08 -0.188 0.52517E+04 196 beidellite-Mg -1.79 -4.76 -2.97 -0.184 0.50650E+04 197 beidellite-Na -1.34 -4.19 -2.85 -0.174 0.48588E+04 199 chalcedony -2.80 -3.34 -0.54 -0.179 0.91538E+03 201 montmorillonite-Ca -2.29 -4.42 -2.13 -0.131 0.36292E+04 202 montmorillonite-K -2.24 -4.60 -2.36 -0.145 0.40304E+04 203 montmorillonite-Mg -2.48 -4.76 -2.28 -0.141 0.38888E+04 204 montmorillonite-Na -2.04 -4.19 -2.15 -0.132 0.36732E+04 205 nontronite-Ca 3.21 2.93 -0.29 -0.019 0.48819E+03 206 nontronite-H 2.53 1.18 -1.36 -0.091 0.23174E+04 207 nontronite-K 3.34 2.75 -0.59 -0.038 0.10126E+04 208 nontronite-Mg 3.07 2.59 -0.49 -0.032 0.83182E+03 209 nontronite-Na 3.52 3.16 -0.36 -0.023 0.62139E+03 224 tobermorite 9.82 5.51 -4.31 -1.176 0.73607E+04 233 boehmite 4.41 2.61 -1.80 -0.299 0.30650E+04 235 ferrous-oxide 9.81 6.33 -3.48 -0.871 0.59476E+04 240 silica-amorphous -2.09 -3.34 -1.25 -0.416 0.21296E+04 242 an20ab80 2.02 0.71 -1.31 -0.100 0.22306E+04 243 an25ab75 2.65 1.24 -1.41 -0.108 0.24000E+04 244 an30ab70 3.28 1.77 -1.51 -0.116 0.25791E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 0.0200000 g Current total amount of reactant added: 0.7990000 g New total amount of reactant added: 0.8190000 g Mixing fraction reached given limit of 0.8000E+00 TOTMIX = 0.8190E+00 Execution stopped.