File SKIP_SPECIES.TXT lists species and minerals omitted from the calculations due to given T, P, option switches, or suppression in CHIMRUN, or are suppressed in the SOLTHERM database. It also lists minerals for which density is not specified in SOLTHERM. This is an extended P(to 5 kB), T(to 600 C) run (CON_FLAG = 1). methanol,aq is suppressed in SOLTHERM data file. methanol,aq is suppressed in SOLTHERM data file. CuCl4-3 is suppressed in SOLTHERM data file. H2BO3- is suppressed in SOLTHERM data file. UO2CO3,aq is suppressed in SOLTHERM data file. UO2SO4,aq is suppressed in SOLTHERM data file. UO2Cl2,aq is suppressed in SOLTHERM data file. UO2F2,aq is suppressed in SOLTHERM data file. PO4-3 is suppressed in SOLTHERM data file. H2PO4- is suppressed in SOLTHERM data file. H3PO4 is suppressed in SOLTHERM data file. O2,gas is suppressed in THIS RUN. O2,gas is suppressed in THIS RUN. amesite is suppressed in SOLTHERM data file. antigorite is suppressed in SOLTHERM data file. goethite is suppressed in THIS RUN. goethite is suppressed in THIS RUN. riebeckite is suppressed in THIS RUN. riebeckite is suppressed in THIS RUN. sapphirine-Fe(221) is suppressed in SOLTHERM data file. sapphirine(221) is suppressed in SOLTHERM data file. talc-prl is suppressed in SOLTHERM data file. PrO1.833(s) is suppressed in SOLTHERM data file. niter-NH4 is suppressed in SOLTHERM data file. FMQ_HS-1 is suppressed in THIS RUN. kf-ab-equil is suppressed in THIS RUN. ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Species No. Charge Tot.moles Trial molality Gamma Mixing solution H+ 1 1. -0.13217E-01 0.11528E-08 0.9382 0.00000000E+00 H2O 2 0. 0.55498E+02 0.10000E+01 1.0000 0.00000000E+00 Cl- 3 -1. 0.13797E-03 0.13795E-03 0.9377 0.00000000E+00 SO4-- 4 -2. 0.47647E-04 0.25487E-04 0.8168 0.00000000E+00 HCO3- 5 -1. 0.13070E-04 0.11938E-04 0.9379 0.00000000E+00 HS- 6 -1. -0.22143E-04 0.55214E-13 0.9378 0.00000000E+00 Al+++ 7 3. 0.26053E-02 0.79797E-24 0.6478 0.00000000E+00 H4SiO4 8 0. 0.83198E-02 0.45863E-03 1.0000 0.00000000E+00 Ca++ 9 2. 0.93344E-03 0.60451E-07 0.8163 0.00000000E+00 Mg++ 10 2. 0.63413E-03 0.51746E-09 0.8160 0.00000000E+00 Fe++ 11 2. 0.56969E-03 0.30528E-11 0.8161 0.00000000E+00 K+ 12 1. 0.16964E-03 0.67004E-04 0.9379 0.00000000E+00 Na+ 13 1. 0.11630E-02 0.11558E-02 0.9377 0.00000000E+00 Mn++ 14 2. 0.13854E-04 0.41016E-09 0.8161 0.00000000E+00 HPO4-- 15 -2. 0.47281E-05 0.18198E-05 0.8168 0.00000000E+00 Chg. balance for total moles = 0.4566E-13 Max. difference allowed = 0.1380E-07 The following parameters were given: ERPC = 0.1000E-11 pH = 0.0000 PFLUID = 50.0000 SLIM = 0.200000E+01 TEMP = 100.0000 SINC = 0.4000E-01 TEMPC = 0.0000 TOTMIX = 0.799000E+00 ENTH = 0.0000 SENTH = 0.0000 DENTH = 0.0000 TOTWAT = 90.0000 SOLMIN = 0.0000E+00 RM = 0.0000 AQGRM = 1000.0103 SUPRNT = 0.1000E-19 VBOX-1 = 1.3196 RHOFRS = 0.0000 RHOROC = 2.5000 The following options were selected: CONFLG = 1 C = 3 IFRAC = 0 IPUNCH = 2 NLOOP = 400 ISTEP = 2 LIMSOL = 1 LOOC = 0 IENTH = 0 ITREF = 0 IDEAL = 0 IPSAT = 1 INCREM = 0 INCP = 0 MINSOL = 1 NEUT = 0 AWAT = 0 CHGF = 0 Of the derived species, only those with molality > 0.10E-19 will appear in the output Species No. Charge Log K(diss) Species No. Charge Log K(diss) HSiO3- 16 -1. 9.0298 MnO2-2 65 -2. 40.4638 Ca(HSiO3)+ 17 1. 7.6723 HMnO2- 66 -1. 29.1232 Mg(HSiO3)+ 18 1. 7.5773 MnO4- 67 -1. 83.3111 NaHSiO3,aq 19 0. 7.8210 MnO4-2 68 -2. 81.3005 AlO+ 20 1. 6.8663 MnCl+ 69 1. -0.7894 AlOH+2 21 2. 3.1691 MnSO4,aq 70 0. -2.4604 HAlO2,aq 22 0. 10.5671 NaCl,aq 71 0. 0.4796 AlO2- 23 -1. 16.2221 NaOH,aq 72 0. 12.3669 CH4,aq 24 0. 6.0126 O2,aq 73 0. 53.5502 C2H6,aq 25 0. 12.3733 OH- 74 -1. 12.2382 C3H8,aq 26 0. 17.3707 HO2- 75 -1. 50.8010 C4H10,aq 27 0. 22.3757 H2O2,aq 76 0. 40.0166 ethanol,aq 28 0. 15.3258 H3PO2,aq 77 0. 24.3066 CO,aq 29 0. 4.6892 H2PO2- 78 -1. 26.5366 CO2,aq 30 0. -6.3298 HPO3-2 79 -2. 11.9254 CO3-2 31 -2. 10.0588 H3PO3,aq 80 0. 3.5792 CaCO3,aq 32 0. 5.9605 H2PO3- 81 -1. 5.6232 Ca(HCO3)+ 33 1. -1.4070 H3PO4,aq 82 0. -9.8447 CaCl+ 34 1. -0.2091 H2PO4- 83 -1. -7.2659 CaCl2,aq 35 0. 0.4151 PO4-3 84 -3. 12.0884 CaOH+ 36 1. 10.1471 H4P2O7,aq 85 0. -17.8095 CaSO4,aq 37 0. -2.5018 H3P2O7- 86 -1. -15.9156 HCl,aq 38 0. 0.7370 H2P2O7-2 87 -2. -13.4262 HClO,aq 39 0. 32.4260 HP2O7-3 88 -3. -6.7266 ClO- 40 -1. 39.6530 P2O7-4 89 -4. 2.8952 HClO2,aq 41 0. 70.1812 H2S,aq 90 0. -6.4900 Fe+3 42 3. 8.3809 S2-2 91 -2. 1.2355 FeCl+ 43 1. -0.1994 S3-2 92 -2. -8.8031 FeCl2,aq 44 0. 4.3001 S3- 93 -1. -16.3389 FeCl+2 45 2. 6.5269 S4-2 94 -2. -18.6615 FeO,aq 46 0. 16.4104 S5-2 95 -2. -28.3439 FeOH+ 47 1. 7.4874 SO2,aq 96 0. -0.2309 HFeO2- 48 -1. 24.3908 SO3-2 97 -2. 10.3052 FeO+ 49 1. 11.4004 HSO3- 98 -1. 2.5086 FeOH+2 50 2. 9.1194 HSO4- 99 -1. -2.9839 FeO2- 51 -1. 24.0895 HSO5- 100 -1. 38.8366 HFeO2,aq 52 0. 15.9850 S2O3-2 101 -2. -4.5600 H2,aq 53 0. 9.4190 HS2O3- 102 -1. -6.8123 KCl,aq 54 0. 1.7417 H2S2O3,aq 103 0. -8.0173 KHSO4,aq 55 0. -0.4514 S2O4-2 104 -2. 10.5541 KOH,aq 56 0. 12.3695 HS2O4- 105 -1. 7.6551 KSO4- 57 -1. -1.1908 H2S2O4,aq 106 0. 6.6259 MgCO3,aq 58 0. 6.5614 S2O5-2 107 -2. 10.0741 Mg(HCO3)+ 59 1. -1.4164 S2O6-2 108 -2. 11.5521 MgCl+ 60 1. -0.1664 S2O8-2 109 -2. 42.0620 MgOH+ 61 1. 9.4041 S3O6-2 110 -2. 3.7866 Mn+3 62 3. 19.1453 S4O6-2 111 -2. -17.8657 MnO,aq 63 0. 17.9848 S5O6-2 112 -2. -14.1333 MnOH+ 64 1. 8.5194 113 0. 10.3111 For mixed gases (JSOLS=6), log K(hydrol) = log (K*P) Log K Trial Log K Trial Mineral No. hydrol Moles Mineral No. hydrol Moles H2O,gas 1 1.696 0.0000E+00 osumilite(2) 124 20.667 0.0000E+00 CO2,gas 2 -6.660 0.0000E+00 osumilite-Fe 125 14.390 0.0000E+00 CH4,gas 3 4.544 0.0000E+00 pargasite 126 65.092 0.0000E+00 H2,gas 4 8.000 0.0000E+00 periclase 127 16.138 0.0000E+00 H2S,gas 5 -6.230 0.0000E+00 periclase-Fe 128 11.627 0.0000E+00 S2,gas 6 -7.335 0.0000E+00 perovskite-Al 129 12.344 0.0000E+00 CO,gas 7 3.215 0.0000E+00 perovskite-Ca 130 23.807 0.0000E+00 SO3,gas 8 17.121 0.0000E+00 perovskite-Fe 131 21.143 0.0000E+00 SO2,gas 9 0.832 0.0000E+00 perovskite-Mg 132 23.119 0.0000E+00 HCl,gas 10 5.189 0.0000E+00 phase_A 133 80.189 0.0000E+00 acmite 11 7.710 0.0000E+00 phlogopite-Na 134 29.647 0.0000E+00 akermanite 12 36.442 0.0000E+00 piemontite(ordered) 135 33.776 0.0000E+00 akimotoite 13 16.591 0.0000E+00 prehnite 136 19.372 0.0000E+00 akimotoite-Fe 14 13.067 0.0000E+00 prehnite-Fe 137 22.498 0.0000E+00 albite-high 15 0.693 0.0000E+00 pumpellyite-Fe 138 46.269 0.0000E+00 albite 16 -0.384 0.0000E+00 pumpellyite-Mg 139 48.995 0.0000E+00 almandine 17 24.442 0.0000E+00 px-Mg-tschermaks 140 19.616 0.0000E+00 pyrope 18 37.248 0.0000E+00 px-Ca-tschermaks 141 18.610 0.0000E+00 spessartine 19 24.457 0.0000E+00 pyrite 142 -21.247 0.0000E+00 analcite 20 3.322 0.0000E+00 pyrrhotite 143 -4.260 0.0000E+00 andalusite 21 5.002 0.0000E+00 pyrrhotiteFe0.875 144 -6.017 0.0000E+00 andradite 22 39.009 0.0000E+00 pyroxmangite 145 7.399 0.0000E+00 grossular 23 32.731 0.0000E+00 pyrophyllite 146 -6.176 0.0000E+00 anhydrite 24 -5.317 0.0000E+00 quartz 147 -2.989 0.0000E+00 ankerite 25 -2.135 0.0000E+00 rankinite 148 40.713 0.0000E+00 annite 26 20.123 0.0000E+00 ringwoodite-Fe 149 15.456 0.0000E+00 phlogopite 27 27.065 0.0000E+00 ringwoodite-Mg 150 27.575 0.0000E+00 biotite-Mn 28 32.960 0.0000E+00 rhodochrosite 151 -0.976 0.0000E+00 anorthite 29 12.710 0.0000E+00 rhodonite 152 7.446 0.0000E+00 anthophyllite 30 51.852 0.0000E+00 sanidine 153 -1.275 0.0000E+00 anthophyllite-Fe 31 29.306 0.0000E+00 sapphirine(351) 154 78.899 0.0000E+00 apatite-OH 32 -18.153 0.9584E-06 siderite 155 -2.608 0.0000E+00 apatite-OH-zs 33 -12.736 0.0000E+00 sillimanite 156 5.262 0.0000E+00 apatite-Cl-zs 34 -16.674 0.0000E+00 sodalite 157 49.976 0.0000E+00 aragonite 35 0.967 0.0000E+00 spinel 158 20.870 0.0000E+00 brucite 36 12.569 0.0000E+00 spurrite 159 59.482 0.0000E+00 calcite 37 0.812 0.0000E+00 staurolite-Fe 160 73.598 0.0000E+00 carnegieite-low 38 9.023 0.0000E+00 staurolite-Mg 161 89.802 0.0000E+00 carnegieite-high 39 10.093 0.0000E+00 staurolite-Mn 162 83.909 0.0000E+00 carpholite-Mg 40 8.582 0.0000E+00 stilbite 163 -7.522 0.9286E-03 carpholite-Fe 41 6.713 0.0000E+00 stilpnomelane-Fe 164 13.017 0.0000E+00 celadonite 42 5.342 0.0000E+00 stilpnomelane-Mg 165 27.441 0.0000E+00 celadonite-Fe 43 3.877 0.0000E+00 stishovite 166 2.720 0.0000E+00 chrysotile 44 23.892 0.0000E+00 sudoite-Fe 167 18.296 0.0000E+00 chondrodite 45 56.475 0.0000E+00 sudoite 168 21.077 0.0000E+00 clinochlore 46 39.070 0.1268E-03 sulfur 169 -9.152 0.0000E+00 daphnite 47 28.965 0.7851E-04 sylvite 170 1.338 0.0000E+00 chlorite-Mn 48 46.869 0.2770E-05 talc 171 16.491 0.0000E+00 chlorite-Al-free 49 47.173 0.0000E+00 talc-Fe 172 13.448 0.0000E+00 chloritoid-Mg 50 13.198 0.0000E+00 talc-tschermaks 173 19.091 0.0000E+00 chloritoid-Fe 51 9.174 0.0000E+00 tephroite 174 18.086 0.0000E+00 chloritoid-Mn 52 11.401 0.0000E+00 tilleyite 175 41.377 0.0000E+00 clinohumite 53 97.128 0.0000E+00 titanite-CaSi 176 15.479 0.0000E+00 coesite 54 -2.376 0.0000E+00 topaz-H 177 4.618 0.0000E+00 cordierite-H 55 23.715 0.0000E+00 tridymite 178 -2.626 0.0000E+00 cordierite 56 24.049 0.0000E+00 tremolite 179 47.869 0.0000E+00 cordierite-Fe 57 20.450 0.0000E+00 ferroactinolite 180 38.452 0.0000E+00 cordierite-Mn 58 25.066 0.0000E+00 troilite-low 181 -4.411 0.0000E+00 corundum 59 8.383 0.0000E+00 tschermakite 182 48.210 0.0000E+00 corundum-MgSi 60 18.891 0.0000E+00 vesuvianite 183 223.471 0.0000E+00 cristobalite 61 -2.560 0.0000E+00 wadeite-Si 184 20.216 0.0000E+00 cummingtonite 62 52.099 0.0000E+00 wadsleyite-Fe 185 15.680 0.0000E+00 cymrite-K 63 1.685 0.0000E+00 wadsleyite-Mg 186 25.850 0.0000E+00 deerite 64 95.671 0.0000E+00 wairakite 187 3.950 0.0000E+00 diaspore 65 2.874 0.0000E+00 walstromite 188 11.509 0.0000E+00 diamond 66 -3.102 0.0000E+00 wollastonite 189 10.461 0.0000E+00 diopside 67 16.181 0.0000E+00 pseudo-wollastonite 190 11.000 0.0000E+00 hedenbergite 68 14.208 0.0000E+00 zoisite 191 22.849 0.0000E+00 dolomite,ordered 69 0.546 0.0000E+00 akaganeite 192 7.755 0.0000E+00 eastonite 70 28.489 0.0000E+00 beidellite-Ca 193 -1.646 0.0000E+00 enstatite 71 17.265 0.0000E+00 beidellite-H 194 -2.326 0.0000E+00 clinoenstatite-HiP 72 18.354 0.0000E+00 beidellite-K 195 -1.520 0.0000E+00 clinoenstatite 73 17.166 0.0000E+00 beidellite-Mg 196 -1.790 0.0000E+00 protoenstatite 74 17.824 0.0000E+00 beidellite-Na 197 -1.342 0.0000E+00 epidote 75 24.670 0.0000E+00 calcium 198 84.026 0.0000E+00 clinozoisite 76 22.806 0.0000E+00 chalcedony 199 -2.802 0.0000E+00 epidote-Fe 77 29.841 0.0000E+00 dawsonite 200 1.682 0.0000E+00 fayalite 78 14.046 0.0000E+00 montmorillonite-Ca 201 -2.291 0.0000E+00 ferrosilite 79 11.149 0.0000E+00 montmorillonite-K 202 -2.237 0.0000E+00 forsterite 80 21.016 0.0000E+00 montmorillonite-Mg 203 -2.480 0.0000E+00 gedrite 81 50.522 0.0000E+00 montmorillonite-Na 204 -2.038 0.0000E+00 gehlenite 82 36.628 0.0000E+00 nontronite-Ca 205 3.215 0.0000E+00 gibbsite 83 4.079 0.0000E+00 nontronite-H 206 2.533 0.0000E+00 glaucophane 84 22.975 0.0000E+00 nontronite-K 207 3.341 0.0000E+00 glaucophane-Fe 85 17.276 0.0000E+00 nontronite-Mg 208 3.075 0.0000E+00 graphite 86 -3.546 0.0000E+00 nontronite-Na 209 3.520 0.0000E+00 greenalite 87 16.140 0.0000E+00 sepiolite 210 24.118 0.0000E+00 grunerite 88 31.215 0.0000E+00 alite 211 57.999 0.0000E+00 halite 89 1.575 0.0000E+00 belite 212 30.433 0.0000E+00 hematite 90 12.566 0.8857E-04 ettringite 213 43.232 0.0000E+00 heulandite 91 -5.827 0.0000E+00 gypsum 214 -4.955 0.0000E+00 hercynite 92 17.279 0.0000E+00 hemicarboaluminate 215 70.954 0.0000E+00 hollandite 93 25.673 0.0000E+00 hydrogarnet 216 60.662 0.0000E+00 iron 94 19.086 0.0000E+00 hydrogarnet-Si 217 50.586 0.0000E+00 jadeite 95 4.215 0.0000E+00 jennite 218 24.367 0.0000E+00 julgoldite 96 70.427 0.0000E+00 monosulfoaluminate 219 53.400 0.0000E+00 kalsilite 97 7.584 0.0000E+00 monocarboaluminate 220 61.898 0.0000E+00 kaolinite 98 -1.333 0.0000E+00 portlandite 221 18.272 0.0000E+00 kyanite 99 4.876 0.0000E+00 stratlingite 222 36.502 0.0000E+00 larnite-bredigite 100 30.686 0.0000E+00 tricarboaluminate 223 70.370 0.0000E+00 laumontite 101 2.883 0.0000E+00 tobermorite 224 9.823 0.0000E+00 lawsonite 102 9.616 0.0000E+00 C4AH13 225 81.816 0.0000E+00 leucite 103 4.119 0.0000E+00 C2AH8 226 45.203 0.0000E+00 lime 104 25.998 0.0000E+00 C3A 227 86.953 0.0000E+00 lizardite 105 23.244 0.0000E+00 C4AF 228 117.416 0.0000E+00 magnesite 106 0.691 0.0000E+00 CAH10 229 28.335 0.0000E+00 magnetite 107 20.087 0.0000E+00 alabandite 230 -0.978 0.0000E+00 minnesotaite 108 10.388 0.0000E+00 alunite 231 -10.435 0.0000E+00 minnesotaite-Mg 109 20.602 0.0000E+00 artinite 232 15.121 0.0000E+00 magnesioferrite 110 26.212 0.0000E+00 boehmite 233 4.406 0.0000E+00 majorite 111 53.251 0.0000E+00 dolomite,disordered 234 1.247 0.0000E+00 manganosite 112 14.058 0.0000E+00 ferrous-oxide 235 9.812 0.0000E+00 margarite 113 17.324 0.0000E+00 huntite 236 3.770 0.0000E+00 meionite 114 44.874 0.0000E+00 hydromagnesite 237 19.995 0.0000E+00 merwinite 115 55.930 0.0000E+00 nesquehonite 238 4.723 0.0000E+00 microcline 116 -2.486 0.0000E+00 potassium-oxide 239 69.038 0.0000E+00 monticellite 117 24.339 0.0000E+00 silica-amorphous 240 -2.091 0.0000E+00 mullite-Al 118 363.148 0.0000E+00 sodium-oxide 241 55.169 0.0000E+00 mullite-Si 119 7.264 0.0000E+00 an20ab80 242 2.018 0.0000E+00 muscovite 120 2.582 0.1026E-03 an25ab75 243 2.646 0.0000E+00 paragonite 121 4.239 0.0000E+00 an30ab70 244 3.279 0.0000E+00 nepheline 122 8.339 0.0000E+00 tr.625ac.25prg.125 245 45.165 0.0000E+00 osumilite(1) 123 21.717 0.0000E+00 246 0.000 0.0000E+00 Initial composition of reactant (wt%): SiO2 62.56 MgO 3.200 Al2O3 16.62 CaO 6.450 FeO 3.530 Na2O 3.890 Fe2O3 1.770 K2O 1.000 MnO 0.1230 P2O5 0.4200E-01 Sum of wt% of reactants: 99.1850 Reactant consumed: 0.7990000 g log = -0.0975 Original solution: 1000.0103000 g Original solution / Rock added: 1251.58 (Water/Rock Ratio), log = 3.0975 The following minerals and/or gases with identical index are in solid solution: H2O,gas 6 CO2,gas 6 CH4,gas 6 H2,gas 6 H2S,gas 6 S2,gas 6 CO,gas 6 SO3,gas 6 SO2,gas 6 HCl,gas 6 almandine 16 pyrope 16 spessartine 16 andradite 8 grossular 8 annite 15 phlogopite 15 biotite-Mn 15 clinochlore 1 daphnite 1 chlorite-Mn 1 diopside 5 hedenbergite 5 epidote 3 clinozoisite 3 greenalite 18 iron 9 lizardite 18 magnetite 14 talc 7 talc-Fe 7 tremolite 2 ferroactinolite 2 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 8 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 0.7990000 Water: Moles liquid = 0.5550E+02 kg liquid = 0.9998E+00 Moles total = 0.5550E+02 kg total = 0.9998E+00 Activity = 1.0000 Stoichiometric ionic strength = .8543031E-03 Osmotic coef. = 0.9830 True ionic strength = .1251392E-02 Chg. balance for total moles = 0.4566E-13 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.11528E-08 -8.9383 0.10816E-08 -8.9659 0.93824E+00 -0.0277 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13795E-03 -3.8603 0.12936E-03 -3.8882 0.93775E+00 -0.0279 4 SO4-- 0.25487E-04 -4.5937 0.20818E-04 -4.6816 0.81681E+00 -0.0879 5 HCO3- 0.11938E-04 -4.9231 0.11197E-04 -4.9509 0.93786E+00 -0.0279 6 HS- 0.55214E-13 -13.2580 0.51777E-13 -13.2859 0.93776E+00 -0.0279 7 Al+++ 0.79797E-24 -24.0980 0.51697E-24 -24.2865 0.64785E+00 -0.1885 8 H4SiO4 0.45863E-03 -3.3385 0.45863E-03 -3.3385 0.10000E+01 0.0000 9 Ca++ 0.60451E-07 -7.2186 0.49346E-07 -7.3067 0.81630E+00 -0.0882 10 Mg++ 0.51746E-09 -9.2861 0.42224E-09 -9.3744 0.81597E+00 -0.0883 11 Fe++ 0.30528E-11 -11.5153 0.24912E-11 -11.6036 0.81605E+00 -0.0883 12 K+ 0.67004E-04 -4.1739 0.62842E-04 -4.2017 0.93789E+00 -0.0279 13 Na+ 0.11558E-02 -2.9371 0.10838E-02 -2.9650 0.93773E+00 -0.0279 14 Mn++ 0.41016E-09 -9.3870 0.33473E-09 -9.4753 0.81611E+00 -0.0883 15 HPO4-- 0.18198E-05 -5.7400 0.14865E-05 -5.8278 0.81682E+00 -0.0879 16 HSiO3- 0.42223E-03 -3.3745 0.39594E-03 -3.4024 0.93775E+00 -0.0279 17 Ca(HSiO3)+ 0.47442E-09 -9.3238 0.44496E-09 -9.3517 0.93790E+00 -0.0278 18 Mg(HSiO3)+ 0.50520E-11 -11.2965 0.47383E-11 -11.3244 0.93790E+00 -0.0278 19 NaHSiO3,aq 0.69405E-05 -5.1586 0.69405E-05 -5.1586 0.10000E+01 0.0000 20 AlO+ 0.64100E-13 -13.1931 0.60120E-13 -13.2210 0.93790E+00 -0.0278 21 AlOH+2 0.39671E-18 -18.4015 0.32378E-18 -18.4897 0.81618E+00 -0.0882 22 HAlO2,aq 0.11070E-07 -7.9559 0.11070E-07 -7.9559 0.10000E+01 0.0000 23 AlO2- 0.24163E-04 -4.6168 0.22655E-04 -4.6448 0.93760E+00 -0.0280 24 CH4,aq 0.27058E-19 -19.5677 0.27051E-19 -19.5678 0.99974E+00 -0.0001 29 CO,aq 0.30502E-18 -18.5157 0.30502E-18 -18.5157 0.10000E+01 0.0000 30 CO2,aq 0.25883E-07 -7.5870 0.25876E-07 -7.5871 0.99974E+00 -0.0001 31 CO3-2 0.11072E-05 -5.9558 0.90421E-06 -6.0437 0.81666E+00 -0.0880 32 CaCO3,aq 0.55948E-09 -9.2522 0.55948E-09 -9.2522 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.15037E-10 -10.8228 0.14103E-10 -10.8507 0.93790E+00 -0.0278 34 CaCl+ 0.11015E-10 -10.9580 0.10331E-10 -10.9859 0.93790E+00 -0.0278 35 CaCl2,aq 0.31749E-15 -15.4983 0.31749E-15 -15.4983 0.10000E+01 0.0000 36 CaOH+ 0.34669E-08 -8.4601 0.32516E-08 -8.4879 0.93790E+00 -0.0278 37 CaSO4,aq 0.32621E-09 -9.4865 0.32621E-09 -9.4865 0.10000E+01 0.0000 38 HCl,aq 0.25639E-13 -13.5911 0.25639E-13 -13.5911 0.10000E+01 0.0000 43 FeCl+ 0.54387E-15 -15.2645 0.51010E-15 -15.2923 0.93790E+00 -0.0278 46 FeO,aq 0.82768E-10 -10.0821 0.82768E-10 -10.0821 0.10000E+01 0.0000 47 FeOH+ 0.79940E-10 -10.0972 0.74976E-10 -10.1251 0.93790E+00 -0.0278 48 HFeO2- 0.85384E-09 -9.0686 0.80069E-09 -9.0965 0.93775E+00 -0.0279 49 FeO+ 0.88022E-14 -14.0554 0.82556E-14 -14.0833 0.93790E+00 -0.0278 51 FeO2- 0.15399E-08 -8.8125 0.14440E-08 -8.8404 0.93775E+00 -0.0279 52 HFeO2,aq 0.19864E-09 -9.7019 0.19864E-09 -9.7019 0.10000E+01 0.0000 53 H2,aq 0.46936E-09 -9.3285 0.46924E-09 -9.3286 0.99974E+00 -0.0001 54 KCl,aq 0.14734E-09 -9.8317 0.14734E-09 -9.8317 0.10000E+01 0.0000 55 KHSO4,aq 0.40007E-17 -17.3979 0.40007E-17 -17.3979 0.10000E+01 0.0000 56 KOH,aq 0.24813E-07 -7.6053 0.24813E-07 -7.6053 0.10000E+01 0.0000 57 KSO4- 0.21648E-07 -7.6646 0.20301E-07 -7.6925 0.93775E+00 -0.0279 58 MgCO3,aq 0.11999E-11 -11.9208 0.11999E-11 -11.9208 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.13147E-12 -12.8812 0.12331E-12 -12.9090 0.93790E+00 -0.0278 60 MgCl+ 0.85420E-13 -13.0684 0.80115E-13 -13.0963 0.93790E+00 -0.0278 61 MgOH+ 0.16415E-09 -9.7848 0.15396E-09 -9.8126 0.93790E+00 -0.0278 63 MnO,aq 0.29633E-09 -9.5282 0.29633E-09 -9.5282 0.10000E+01 0.0000 64 MnOH+ 0.99781E-09 -9.0010 0.93584E-09 -9.0288 0.93790E+00 -0.0278 65 MnO2-2 0.10294E-13 -13.9874 0.84066E-14 -14.0754 0.81666E+00 -0.0880 66 HMnO2- 0.21243E-11 -11.6728 0.19920E-11 -11.7007 0.93775E+00 -0.0279 69 MnCl+ 0.28430E-12 -12.5462 0.26665E-12 -12.5741 0.93790E+00 -0.0278 70 MnSO4,aq 0.20117E-11 -11.6964 0.20117E-11 -11.6964 0.10000E+01 0.0000 71 NaCl,aq 0.46464E-07 -7.3329 0.46464E-07 -7.3329 0.10000E+01 0.0000 72 NaOH,aq 0.43053E-06 -6.3660 0.43053E-06 -6.3660 0.10000E+01 0.0000 74 OH- 0.56975E-03 -3.2443 0.53419E-03 -3.2723 0.93760E+00 -0.0280 79 HPO3-2 0.26617E-17 -17.5748 0.21737E-17 -17.6628 0.81666E+00 -0.0880 82 H3PO4,aq 0.12162E-13 -13.9150 0.12162E-13 -13.9150 0.10000E+01 0.0000 83 H2PO4- 0.31625E-07 -7.5000 0.29659E-07 -7.5278 0.93782E+00 -0.0279 84 PO4-3 0.17234E-08 -8.7636 0.11213E-08 -8.9503 0.65064E+00 -0.1867 87 H2P2O7-2 0.84457E-16 -16.0734 0.68972E-16 -16.1613 0.81666E+00 -0.0880 88 HP2O7-3 0.19654E-13 -13.7066 0.12733E-13 -13.8951 0.64788E+00 -0.1885 89 P2O7-4 0.59867E-14 -14.2228 0.28125E-14 -14.5509 0.46979E+00 -0.3281 90 H2S,aq 0.17312E-15 -15.7616 0.17308E-15 -15.7618 0.99974E+00 -0.0001 97 SO3-2 0.15524E-14 -14.8090 0.12694E-14 -14.8964 0.81770E+00 -0.0874 98 HSO3- 0.91672E-16 -16.0378 0.85965E-16 -16.0657 0.93775E+00 -0.0279 99 HSO4- 0.23134E-10 -10.6357 0.21699E-10 -10.6636 0.93798E+00 -0.0278 Charge balance for all species = 0.4567E-13 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.1152780E-08 -.1097119E-02 -.1105693E+01 0.0000 2 H2O 0.1000000E+01 0.5550844E+02 0.9998775E+06 0.0000 3 Cl- 0.1379495E-03 0.1379962E-03 0.4891773E+01 5.0777 4 SO4-- 0.2548654E-04 0.2550864E-04 0.2450097E+01 13.2503 5 HCO3- 0.1193842E-04 0.1307208E-04 0.7975232E+00 4.0150 6 HS- 0.5521367E-13 -.9992274E-10 -.3304236E-05 -4.3199 7 Al+++ 0.7979712E-24 0.2417420E-04 0.6521755E+00 2.6113 8 H4SiO4 0.4586319E-03 0.8877995E-03 0.8532064E+02 -3.3385 9 Ca++ 0.6045137E-07 0.6530443E-07 0.2616947E-02 10.6251 10 Mg++ 0.5174625E-09 0.6880812E-09 0.1672656E-04 8.5574 11 Fe++ 0.3052806E-11 0.2758157E-08 0.1540157E-03 6.3283 12 K+ 0.6700430E-04 0.6705090E-04 0.2621500E+01 4.7642 13 Na+ 0.1155779E-02 0.1163196E-02 0.2673834E+02 6.0009 14 Mn++ 0.4101571E-09 0.1708720E-08 0.9386202E-04 8.4566 15 HPO4-- 0.1819830E-05 0.1853178E-05 0.1778442E+00 12.1040 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.1321721E-01 -.1096944E-02 -.1212027E-01 0.0000000E+00 2 H2O 0.5549823E+02 0.5549959E+02 -.1359000E-02 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.4764748E-04 0.2550457E-04 0.2214291E-04 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.2214301E-04 -.9990682E-10 -.2214291E-04 0.0000000E+00 7 Al+++ 0.2605333E-02 0.2417035E-04 0.2581162E-02 0.0000000E+00 8 H4SiO4 0.8319814E-02 0.8876580E-03 0.7432156E-02 0.0000000E+00 9 Ca++ 0.9334350E-03 0.6529402E-07 0.9333697E-03 0.0000000E+00 10 Mg++ 0.6341270E-03 0.6879715E-09 0.6341263E-03 0.0000000E+00 11 Fe++ 0.5696939E-03 0.2757717E-08 0.5696911E-03 0.0000000E+00 12 K+ 0.1696391E-03 0.6704022E-04 0.1025988E-03 0.0000000E+00 13 Na+ 0.1163011E-02 0.1163011E-02 0.0000000E+00 0.0000000E+00 14 Mn++ 0.1385354E-04 0.1708447E-08 0.1385183E-04 0.0000000E+00 15 HPO4-- 0.4728144E-05 0.1852883E-05 0.2875261E-05 0.0000000E+00 Chg. balance for solid moles: -.1748E-17 Mass of aqueous solution: 0.999964E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 0.7990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) apatite-OH 0.9584E-06 -6.018 0.4814E-03 -3.317 0.5743E-01 0.1530E-03 clinochlore 0.1268E-03 -3.897 0.7049E-01 -1.152 8.409 0.2681E-01 daphnite 0.7851E-04 -4.105 0.5602E-01 -1.252 6.682 0.1697E-01 chlorite-Mn 0.2770E-05 -5.557 0.1964E-02 -2.707 0.2343 0.6259E-03 hematite 0.8857E-04 -4.053 0.1414E-01 -1.849 1.687 0.2681E-02 muscovite 0.1026E-03 -3.989 0.4087E-01 -1.389 4.875 0.1445E-01 stilbite 0.9286E-03 -3.032 0.6544 -0.184 78.06 0.3052 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.6094E+00 0.6094E+00 1.0000 -0.215 daphnite 0.3773E+00 0.3773E+00 1.0000 -0.423 chlorite-Mn 0.1331E-01 0.1331E-01 1.0000 -1.876 hematite 0.1000E+01 0.1000E+01 1.0000 0.000 muscovite 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 0.838354 g Volume = 0.366917 cm3 Porosity: 72.1948% V(tot) - V(min): 0.95268E+00 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.7990000 g log = -0.0975 Original solution: 1000.0103000 g Original solution / Rock added: 1251.58 (Water/Rock Ratio), log = 3.0975 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0203 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.1000E+01 0.9860 0.1006E+01 0.1020E+01 CO2,gas 0.2694E-05 1.0071 0.2768E-05 0.2749E-05 CH4,gas 0.3854E-16 1.0125 0.3982E-16 0.3932E-16 H2,gas 0.6035E-06 1.0005 0.6161E-06 0.6157E-06 H2S,gas 0.4682E-14 0.9960 0.4758E-14 0.4777E-14 S2,gas 0.2194E-35 1.0000 0.2239E-35 0.2239E-35 CO,gas 0.4455E-15 1.0000 0.4545E-15 0.4545E-15 SO3,gas 0.9025E-38 1.0000 0.9208E-38 0.9208E-38 SO2,gas 0.2163E-21 1.0000 0.2207E-21 0.2207E-21 HCl,gas 0.4434E-16 1.0000 0.4524E-16 0.4524E-16 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 32 apatite-OH -18.15 -18.15 0.00 0.000 0.00000E+00 46 clinochlore 39.07 39.07 0.00 0.000 0.24265E-10 47 daphnite 28.97 28.97 0.00 0.000 0.24265E-10 48 chlorite-Mn 46.87 46.87 0.00 0.000 -0.12132E-10 90 hematite 12.57 12.57 0.00 0.000 0.30331E-11 120 muscovite 2.58 2.58 0.00 0.000 -0.18198E-10 163 stilbite -7.52 -7.52 0.00 0.000 -0.90992E-11 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -13.92 -7.26 -2.419 0.12391E+05 -5.558 3 CH4,gas 4.54 -13.56 -18.10 -4.525 0.30903E+05 -16.400 4 H2,gas 8.00 0.09 -7.91 -4.520 0.13505E+05 -6.210 5 H2S,gas -6.23 -22.25 -16.02 -8.011 0.27356E+05 -14.323 6 S2,gas -7.34 -44.68 -37.35 -5.746 0.63772E+05 -35.650 7 CO,gas 3.21 -13.83 -17.04 -5.244 0.29098E+05 -15.342 8 SO3,gas 17.12 -22.61 -39.73 -9.934 0.67846E+05 -38.036 9 SO2,gas 0.83 -22.52 -23.36 -6.228 0.39878E+05 -21.656 10 HCl,gas 5.19 -12.85 -18.04 -9.022 0.30809E+05 -16.344 11 acmite 7.71 5.61 -2.10 -0.218 0.35905E+04 15 albite-high 0.69 -1.40 -2.10 -0.161 0.35797E+04 16 albite -0.38 -1.40 -1.02 -0.078 0.17409E+04 19 spessartine 24.46 20.58 -3.88 -0.194 0.66261E+04 20 analcite 3.32 1.94 -1.39 -0.154 0.23678E+04 21 andalusite 5.00 1.88 -3.12 -0.312 0.53230E+04 22 andradite 39.01 34.43 -4.58 -0.238 0.78250E+04 26 annite 20.12 16.34 -3.78 -0.210 0.64519E+04 27 phlogopite 27.06 23.03 -4.03 -0.224 0.68852E+04 29 anorthite 12.71 9.17 -3.54 -0.272 0.60439E+04 35 aragonite 0.97 -3.29 -4.26 -1.419 0.72708E+04 36 brucite 12.57 8.56 -4.01 -0.802 0.68489E+04 37 calcite 0.81 -3.29 -4.10 -1.368 0.70066E+04 38 carnegieite-low 9.02 5.27 -3.75 -0.536 0.64024E+04 39 carnegieite-high 10.09 5.27 -4.82 -0.689 0.82294E+04 40 carpholite-Mg 8.58 7.10 -1.48 -0.099 0.25256E+04 41 carpholite-Fe 6.71 4.87 -1.84 -0.123 0.31398E+04 42 celadonite 5.34 2.58 -2.76 -0.163 0.47175E+04 43 celadonite-Fe 3.88 0.35 -3.53 -0.207 0.60221E+04 44 chrysotile 23.89 19.00 -4.90 -0.408 0.83618E+04 50 chloritoid-Mg 13.20 10.44 -2.76 -0.184 0.47062E+04 51 chloritoid-Fe 9.17 8.21 -0.96 -0.064 0.16414E+04 52 chloritoid-Mn 11.40 10.34 -1.06 -0.071 0.18107E+04 54 coesite -2.38 -3.34 -0.96 -0.321 0.16434E+04 59 corundum 8.38 5.22 -3.16 -0.287 0.53966E+04 61 cristobalite -2.56 -3.34 -0.78 -0.259 0.13288E+04 63 cymrite-K 1.69 -2.64 -4.33 -0.360 0.73857E+04 65 diaspore 2.87 2.61 -0.26 -0.044 0.44807E+03 67 diopside 16.18 12.51 -3.68 -0.368 0.62764E+04 68 hedenbergite 14.21 10.28 -3.93 -0.393 0.67136E+04 75 epidote 24.67 22.74 -1.93 -0.094 0.32947E+04 76 clinozoisite 22.81 19.07 -3.74 -0.170 0.63817E+04 77 epidote-Fe 29.84 26.41 -3.43 -0.178 0.58544E+04 78 fayalite 14.05 9.32 -4.73 -0.675 0.80724E+04 83 gibbsite 4.08 2.61 -1.47 -0.210 0.25066E+04 87 greenalite 16.14 12.31 -3.83 -0.319 0.65425E+04 91 heulandite -5.83 -7.52 -1.69 -0.077 0.28938E+04 95 jadeite 4.22 1.94 -2.28 -0.228 0.38933E+04 97 kalsilite 7.58 4.04 -3.55 -0.507 0.60564E+04 98 kaolinite -1.33 -1.45 -0.12 -0.011 0.20787E+03 99 kyanite 4.88 1.88 -2.99 -0.299 0.51089E+04 101 laumontite 2.88 2.49 -0.39 -0.026 0.66567E+03 102 lawsonite 9.62 9.17 -0.45 -0.030 0.76059E+03 103 leucite 4.12 0.70 -3.42 -0.342 0.58403E+04 105 lizardite 23.24 19.00 -4.25 -0.354 0.72544E+04 107 magnetite 20.09 18.89 -1.19 -0.097 0.20369E+04 108 minnesotaite 10.39 5.63 -4.76 -0.280 0.81231E+04 113 margarite 17.32 14.39 -2.93 -0.117 0.50036E+04 116 microcline -2.49 -2.64 -0.15 -0.012 0.26233E+03 121 paragonite 4.24 3.82 -0.42 -0.025 0.71765E+03 122 nepheline 8.34 5.27 -3.07 -0.438 0.52348E+04 136 prehnite 19.37 16.46 -2.91 -0.171 0.49767E+04 137 prehnite-Fe 22.50 20.13 -2.37 -0.142 0.40447E+04 138 pumpellyite-Fe 46.27 41.85 -4.42 -0.098 0.75392E+04 139 pumpellyite-Mg 48.99 44.08 -4.91 -0.109 0.83866E+04 145 pyroxmangite 7.40 5.12 -2.28 -0.456 0.38941E+04 146 pyrophyllite -6.18 -8.13 -1.96 -0.122 0.33394E+04 147 quartz -2.99 -3.34 -0.35 -0.116 0.59608E+03 151 rhodochrosite -0.98 -5.46 -4.48 -1.495 0.76562E+04 152 rhodonite 7.45 5.12 -2.33 -0.466 0.39744E+04 153 sanidine -1.28 -2.64 -1.36 -0.105 0.23301E+04 155 siderite -2.61 -7.59 -4.98 -1.660 0.85039E+04 156 sillimanite 5.26 1.88 -3.38 -0.338 0.57670E+04 164 stilpnomelane-Fe 13.02 12.54 -0.48 -0.014 0.81807E+03 165 stilpnomelane-Mg 27.44 23.68 -3.76 -0.112 0.64164E+04 168 sudoite 21.08 17.54 -3.53 -0.114 0.60324E+04 171 talc 16.49 12.32 -4.17 -0.245 0.71251E+04 174 tephroite 18.09 13.57 -4.51 -0.644 0.77027E+04 177 topaz-H 4.62 1.88 -2.73 -0.249 0.46690E+04 178 tridymite -2.63 -3.34 -0.71 -0.237 0.12161E+04 187 wairakite 3.95 2.49 -1.46 -0.086 0.24876E+04 188 walstromite 11.51 7.29 -4.22 -0.845 0.72100E+04 189 wollastonite 10.46 7.29 -3.17 -0.635 0.54205E+04 190 pseudo-wollastonite 11.00 7.29 -3.71 -0.743 0.63403E+04 191 zoisite 22.85 19.07 -3.78 -0.172 0.64558E+04 192 akaganeite 7.75 6.28 -1.47 -0.318 0.25125E+04 193 beidellite-Ca -1.65 -4.41 -2.77 -0.171 0.47287E+04 194 beidellite-H -2.33 -6.17 -3.84 -0.245 0.65600E+04 195 beidellite-K -1.52 -4.60 -3.08 -0.188 0.52517E+04 196 beidellite-Mg -1.79 -4.76 -2.97 -0.184 0.50650E+04 197 beidellite-Na -1.34 -4.19 -2.85 -0.174 0.48588E+04 199 chalcedony -2.80 -3.34 -0.54 -0.179 0.91538E+03 201 montmorillonite-Ca -2.29 -4.42 -2.13 -0.131 0.36292E+04 202 montmorillonite-K -2.24 -4.60 -2.36 -0.145 0.40304E+04 203 montmorillonite-Mg -2.48 -4.76 -2.28 -0.141 0.38888E+04 204 montmorillonite-Na -2.04 -4.19 -2.15 -0.132 0.36732E+04 205 nontronite-Ca 3.21 2.93 -0.29 -0.019 0.48819E+03 206 nontronite-H 2.53 1.18 -1.36 -0.091 0.23174E+04 207 nontronite-K 3.34 2.75 -0.59 -0.038 0.10126E+04 208 nontronite-Mg 3.07 2.59 -0.49 -0.032 0.83182E+03 209 nontronite-Na 3.52 3.16 -0.36 -0.023 0.62139E+03 224 tobermorite 9.82 5.51 -4.31 -1.176 0.73607E+04 233 boehmite 4.41 2.61 -1.80 -0.299 0.30650E+04 235 ferrous-oxide 9.81 6.33 -3.48 -0.871 0.59476E+04 240 silica-amorphous -2.09 -3.34 -1.25 -0.416 0.21296E+04 242 an20ab80 2.02 0.71 -1.31 -0.100 0.22306E+04 243 an25ab75 2.65 1.24 -1.41 -0.108 0.24000E+04 244 an30ab70 3.28 1.77 -1.51 -0.116 0.25791E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 0.0400000 g Current total amount of reactant added: 0.7990000 g New total amount of reactant added: 0.8390000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.4566E-13 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 7 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 0.8390000 Water: Moles liquid = 0.5550E+02 kg liquid = 0.9998E+00 Moles total = 0.5550E+02 kg total = 0.9998E+00 Activity = 1.0000 Stoichiometric ionic strength = .8800455E-03 Osmotic coef. = 0.9827 True ionic strength = .1304062E-02 Chg. balance for total moles = 0.4566E-13 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.11113E-08 -8.9542 0.10417E-08 -8.9822 0.93740E+00 -0.0281 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13795E-03 -3.8603 0.12924E-03 -3.8886 0.93688E+00 -0.0283 4 SO4-- 0.25486E-04 -4.5937 0.20742E-04 -4.6832 0.81385E+00 -0.0895 5 HCO3- 0.11898E-04 -4.9245 0.11149E-04 -4.9528 0.93701E+00 -0.0283 6 HS- 0.55028E-13 -13.2594 0.51555E-13 -13.2877 0.93689E+00 -0.0283 7 Al+++ 0.68096E-24 -24.1669 0.43754E-24 -24.3590 0.64254E+00 -0.1921 8 H4SiO4 0.47186E-03 -3.3262 0.47186E-03 -3.3262 0.10000E+01 0.0000 9 Ca++ 0.51407E-07 -7.2890 0.41810E-07 -7.3787 0.81332E+00 -0.0897 10 Mg++ 0.48403E-09 -9.3151 0.39351E-09 -9.4050 0.81298E+00 -0.0899 11 Fe++ 0.28556E-11 -11.5443 0.23217E-11 -11.6342 0.81306E+00 -0.0899 12 K+ 0.69782E-04 -4.1563 0.65388E-04 -4.1845 0.93703E+00 -0.0282 13 Na+ 0.12052E-02 -2.9189 0.11291E-02 -2.9473 0.93687E+00 -0.0283 14 Mn++ 0.38366E-09 -9.4161 0.31196E-09 -9.5059 0.81312E+00 -0.0898 15 HPO4-- 0.22900E-05 -5.6402 0.18637E-05 -5.7296 0.81386E+00 -0.0895 16 HSiO3- 0.45144E-03 -3.3454 0.42294E-03 -3.3737 0.93688E+00 -0.0283 17 Ca(HSiO3)+ 0.42977E-09 -9.3668 0.40271E-09 -9.3950 0.93705E+00 -0.0282 18 Mg(HSiO3)+ 0.50339E-11 -11.2981 0.47170E-11 -11.3263 0.93705E+00 -0.0282 19 NaHSiO3,aq 0.77236E-05 -5.1122 0.77236E-05 -5.1122 0.10000E+01 0.0000 20 AlO+ 0.58536E-13 -13.2326 0.54851E-13 -13.2608 0.93705E+00 -0.0282 21 AlOH+2 0.34988E-18 -18.4561 0.28452E-18 -18.5459 0.81319E+00 -0.0898 22 HAlO2,aq 0.10486E-07 -7.9794 0.10486E-07 -7.9794 0.10000E+01 0.0000 23 AlO2- 0.23786E-04 -4.6237 0.22281E-04 -4.6521 0.93673E+00 -0.0284 24 CH4,aq 0.26925E-19 -19.5698 0.26918E-19 -19.5700 0.99973E+00 -0.0001 29 CO,aq 0.29523E-18 -18.5298 0.29523E-18 -18.5298 0.10000E+01 0.0000 30 CO2,aq 0.24823E-07 -7.6051 0.24816E-07 -7.6053 0.99973E+00 -0.0001 31 CO3-2 0.11488E-05 -5.9398 0.93477E-06 -6.0293 0.81369E+00 -0.0895 32 CaCO3,aq 0.49005E-09 -9.3098 0.49005E-09 -9.3098 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.12697E-10 -10.8963 0.11898E-10 -10.9245 0.93705E+00 -0.0282 34 CaCl+ 0.93321E-11 -11.0300 0.87447E-11 -11.0583 0.93705E+00 -0.0282 35 CaCl2,aq 0.26851E-15 -15.5710 0.26851E-15 -15.5710 0.10000E+01 0.0000 36 CaOH+ 0.30526E-08 -8.5153 0.28604E-08 -8.5436 0.93705E+00 -0.0282 37 CaSO4,aq 0.27538E-09 -9.5601 0.27538E-09 -9.5601 0.10000E+01 0.0000 38 HCl,aq 0.24671E-13 -13.6078 0.24671E-13 -13.6078 0.10000E+01 0.0000 43 FeCl+ 0.50686E-15 -15.2951 0.47495E-15 -15.3233 0.93705E+00 -0.0282 46 FeO,aq 0.83150E-10 -10.0801 0.83150E-10 -10.0801 0.10000E+01 0.0000 47 FeOH+ 0.77421E-10 -10.1111 0.72547E-10 -10.1394 0.93705E+00 -0.0282 48 HFeO2- 0.89142E-09 -9.0499 0.83516E-09 -9.0782 0.93688E+00 -0.0283 49 FeO+ 0.84857E-14 -14.0713 0.79514E-14 -14.0996 0.93705E+00 -0.0282 51 FeO2- 0.16003E-08 -8.7958 0.14993E-08 -8.8241 0.93688E+00 -0.0283 52 HFeO2,aq 0.19864E-09 -9.7019 0.19864E-09 -9.7019 0.10000E+01 0.0000 53 H2,aq 0.47372E-09 -9.3245 0.47359E-09 -9.3246 0.99973E+00 -0.0001 54 KCl,aq 0.15317E-09 -9.8148 0.15317E-09 -9.8148 0.10000E+01 0.0000 55 KHSO4,aq 0.39947E-17 -17.3985 0.39947E-17 -17.3985 0.10000E+01 0.0000 56 KOH,aq 0.26806E-07 -7.5718 0.26806E-07 -7.5718 0.10000E+01 0.0000 57 KSO4- 0.22464E-07 -7.6485 0.21046E-07 -7.6768 0.93688E+00 -0.0283 58 MgCO3,aq 0.11561E-11 -11.9370 0.11561E-11 -11.9370 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.12211E-12 -12.9132 0.11443E-12 -12.9415 0.93705E+00 -0.0282 60 MgCl+ 0.79607E-13 -13.0991 0.74595E-13 -13.1273 0.93705E+00 -0.0282 61 MgOH+ 0.15898E-09 -9.7987 0.14897E-09 -9.8269 0.93705E+00 -0.0282 63 MnO,aq 0.29770E-09 -9.5262 0.29770E-09 -9.5262 0.10000E+01 0.0000 64 MnOH+ 0.96638E-09 -9.0149 0.90554E-09 -9.0431 0.93705E+00 -0.0282 65 MnO2-2 0.11189E-13 -13.9512 0.91041E-14 -14.0408 0.81369E+00 -0.0895 66 HMnO2- 0.22178E-11 -11.6541 0.20778E-11 -11.6824 0.93688E+00 -0.0283 69 MnCl+ 0.26496E-12 -12.5768 0.24828E-12 -12.6051 0.93705E+00 -0.0282 70 MnSO4,aq 0.18680E-11 -11.7286 0.18680E-11 -11.7286 0.10000E+01 0.0000 71 NaCl,aq 0.48361E-07 -7.3155 0.48361E-07 -7.3155 0.10000E+01 0.0000 72 NaOH,aq 0.46568E-06 -6.3319 0.46568E-06 -6.3319 0.10000E+01 0.0000 74 OH- 0.59209E-03 -3.2276 0.55463E-03 -3.2560 0.93673E+00 -0.0284 79 HPO3-2 0.33804E-17 -17.4710 0.27506E-17 -17.5606 0.81369E+00 -0.0895 82 H3PO4,aq 0.14146E-13 -13.8494 0.14146E-13 -13.8494 0.10000E+01 0.0000 83 H2PO4- 0.38225E-07 -7.4176 0.35816E-07 -7.4459 0.93696E+00 -0.0283 84 PO4-3 0.22616E-08 -8.6456 0.14597E-08 -8.8357 0.64542E+00 -0.1902 87 H2P2O7-2 0.12361E-15 -15.9079 0.10058E-15 -15.9975 0.81369E+00 -0.0895 88 HP2O7-3 0.30003E-13 -13.5228 0.19279E-13 -13.7149 0.64257E+00 -0.1921 89 P2O7-4 0.95489E-14 -14.0200 0.44212E-14 -14.3545 0.46301E+00 -0.3344 90 H2S,aq 0.16603E-15 -15.7798 0.16599E-15 -15.7799 0.99973E+00 -0.0001 97 SO3-2 0.15667E-14 -14.8050 0.12765E-14 -14.8940 0.81477E+00 -0.0890 98 HSO3- 0.88870E-16 -16.0512 0.83260E-16 -16.0796 0.93688E+00 -0.0283 99 HSO4- 0.22220E-10 -10.6532 0.20823E-10 -10.6814 0.93713E+00 -0.0282 Charge balance for all species = 0.4567E-13 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.1111306E-08 -.1148019E-02 -.1156985E+01 0.0000 2 H2O 0.1000000E+01 0.5550843E+02 0.9998721E+06 0.0000 3 Cl- 0.1379487E-03 0.1379972E-03 0.4891785E+01 5.0936 4 SO4-- 0.2548597E-04 0.2550884E-04 0.2450104E+01 13.2813 5 HCO3- 0.1189805E-04 0.1307218E-04 0.7975251E+00 4.0295 6 HS- 0.5502796E-13 -.1063816E-09 -.3517798E-05 -4.3055 7 Al+++ 0.6809562E-24 0.2379688E-04 0.6419927E+00 2.5877 8 H4SiO4 0.4718585E-03 0.9310184E-03 0.8947367E+02 -3.3262 9 Ca++ 0.5140651E-07 0.5567629E-07 0.2231106E-02 10.5858 10 Mg++ 0.4840304E-09 0.6494003E-09 0.1578618E-04 8.5594 11 Fe++ 0.2855560E-11 0.2853784E-08 0.1593547E-03 6.3303 12 K+ 0.6978234E-04 0.6983176E-04 0.2730209E+01 4.7977 13 Na+ 0.1205185E-02 0.1213423E-02 0.2789276E+02 6.0350 14 Mn++ 0.3836589E-09 0.1652099E-08 0.9075130E-04 8.4586 15 HPO4-- 0.2289998E-05 0.2330485E-05 0.2236488E+00 12.2349 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.1387955E-01 -.1147827E-02 -.1273173E-01 0.0000000E+00 2 H2O 0.5549773E+02 0.5549916E+02 -.1426951E-02 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.4875602E-04 0.2550458E-04 0.2325144E-04 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.2325155E-04 -.1063638E-09 -.2325144E-04 0.0000000E+00 7 Al+++ 0.2735762E-02 0.2379290E-04 0.2711969E-02 0.0000000E+00 8 H4SiO4 0.8736325E-02 0.9308629E-03 0.7805462E-02 0.0000000E+00 9 Ca++ 0.9794407E-03 0.5566699E-07 0.9793851E-03 0.0000000E+00 10 Mg++ 0.6658730E-03 0.6492919E-09 0.6658724E-03 0.0000000E+00 11 Fe++ 0.5982142E-03 0.2853307E-08 0.5982114E-03 0.0000000E+00 12 K+ 0.1781316E-03 0.6982010E-04 0.1083115E-03 0.0000000E+00 13 Na+ 0.1213220E-02 0.1213220E-02 0.0000000E+00 0.0000000E+00 14 Mn++ 0.1454708E-04 0.1651823E-08 0.1454543E-04 0.0000000E+00 15 HPO4-- 0.4964847E-05 0.2330096E-05 0.2634751E-05 0.0000000E+00 Chg. balance for solid moles: 0.4074E-18 Mass of aqueous solution: 0.999962E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 0.8390000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) apatite-OH 0.8783E-06 -6.056 0.4412E-03 -3.355 0.5011E-01 0.1402E-03 clinochlore 0.1332E-03 -3.876 0.7402E-01 -1.131 8.407 0.2816E-01 daphnite 0.8244E-04 -4.084 0.5882E-01 -1.230 6.681 0.1782E-01 chlorite-Mn 0.2909E-05 -5.536 0.2062E-02 -2.686 0.2343 0.6573E-03 hematite 0.9301E-04 -4.031 0.1485E-01 -1.828 1.687 0.2815E-02 muscovite 0.1083E-03 -3.965 0.4314E-01 -1.365 4.900 0.1526E-01 stilbite 0.9750E-03 -3.011 0.6871 -0.163 78.04 0.3205 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.6094E+00 0.6094E+00 1.0000 -0.215 daphnite 0.3773E+00 0.3773E+00 1.0000 -0.423 chlorite-Mn 0.1331E-01 0.1331E-01 1.0000 -1.876 hematite 0.1000E+01 0.1000E+01 1.0000 0.000 muscovite 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 0.880440 g Volume = 0.385323 cm3 Porosity: 71.1498% V(tot) - V(min): 0.95028E+00 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.8390000 g log = -0.0762 Original solution: 1000.0103000 g Original solution / Rock added: 1191.91 (Water/Rock Ratio), log = 3.0762 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0203 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.1000E+01 0.9860 0.1006E+01 0.1020E+01 CO2,gas 0.2584E-05 1.0071 0.2655E-05 0.2636E-05 CH4,gas 0.3835E-16 1.0125 0.3962E-16 0.3913E-16 H2,gas 0.6091E-06 1.0005 0.6218E-06 0.6214E-06 H2S,gas 0.4490E-14 0.9960 0.4563E-14 0.4581E-14 S2,gas 0.1981E-35 1.0000 0.2022E-35 0.2022E-35 CO,gas 0.4312E-15 1.0000 0.4400E-15 0.4400E-15 SO3,gas 0.8341E-38 1.0000 0.8511E-38 0.8511E-38 SO2,gas 0.2018E-21 1.0000 0.2059E-21 0.2059E-21 HCl,gas 0.4267E-16 1.0000 0.4353E-16 0.4353E-16 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 32 apatite-OH -18.15 -18.15 0.00 0.000 0.60662E-11 46 clinochlore 39.07 39.07 0.00 0.000 0.36397E-10 47 daphnite 28.97 28.97 0.00 0.000 0.60662E-10 48 chlorite-Mn 46.87 46.87 0.00 0.000 0.36397E-10 90 hematite 12.57 12.57 0.00 0.000 -0.30331E-11 120 muscovite 2.58 2.58 0.00 0.000 0.60662E-11 163 stilbite -7.52 -7.52 0.00 0.000 0.39430E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -13.94 -7.27 -2.425 0.12422E+05 -5.576 3 CH4,gas 4.54 -13.56 -18.10 -4.525 0.30907E+05 -16.402 4 H2,gas 8.00 0.09 -7.91 -4.517 0.13498E+05 -6.206 5 H2S,gas -6.23 -22.27 -16.04 -8.020 0.27387E+05 -14.341 6 S2,gas -7.34 -44.73 -37.39 -5.753 0.63848E+05 -35.694 7 CO,gas 3.21 -13.84 -17.06 -5.248 0.29122E+05 -15.357 8 SO3,gas 17.12 -22.65 -39.77 -9.942 0.67904E+05 -38.070 9 SO2,gas 0.83 -22.55 -23.39 -6.236 0.39930E+05 -21.686 10 HCl,gas 5.19 -12.87 -18.06 -9.030 0.30837E+05 -16.361 11 acmite 7.71 5.67 -2.04 -0.212 0.34901E+04 15 albite-high 0.69 -1.36 -2.05 -0.158 0.34984E+04 16 albite -0.38 -1.36 -0.97 -0.075 0.16596E+04 19 spessartine 24.46 20.57 -3.88 -0.194 0.66329E+04 20 analcite 3.32 1.97 -1.35 -0.150 0.23077E+04 21 andalusite 5.00 1.85 -3.15 -0.315 0.53823E+04 22 andradite 39.01 34.34 -4.66 -0.242 0.79634E+04 26 annite 20.12 16.40 -3.73 -0.207 0.63613E+04 27 phlogopite 27.06 23.09 -3.98 -0.221 0.67946E+04 29 anorthite 12.71 9.11 -3.60 -0.277 0.61493E+04 35 aragonite 0.97 -3.35 -4.32 -1.439 0.73691E+04 36 brucite 12.57 8.56 -4.01 -0.802 0.68455E+04 37 calcite 0.81 -3.35 -4.16 -1.387 0.71049E+04 38 carnegieite-low 9.02 5.30 -3.73 -0.532 0.63633E+04 39 carnegieite-high 10.09 5.30 -4.80 -0.685 0.81903E+04 40 carpholite-Mg 8.58 7.08 -1.50 -0.100 0.25604E+04 41 carpholite-Fe 6.71 4.85 -1.86 -0.124 0.31746E+04 42 celadonite 5.34 2.64 -2.70 -0.159 0.46126E+04 43 celadonite-Fe 3.88 0.41 -3.47 -0.204 0.59172E+04 44 chrysotile 23.89 19.03 -4.87 -0.406 0.83093E+04 50 chloritoid-Mg 13.20 10.41 -2.79 -0.186 0.47621E+04 51 chloritoid-Fe 9.17 8.18 -0.99 -0.066 0.16972E+04 52 chloritoid-Mn 11.40 10.31 -1.09 -0.073 0.18666E+04 54 coesite -2.38 -3.33 -0.95 -0.317 0.16223E+04 59 corundum 8.38 5.18 -3.21 -0.292 0.54769E+04 61 cristobalite -2.56 -3.33 -0.77 -0.255 0.13077E+04 63 cymrite-K 1.69 -2.59 -4.28 -0.357 0.73054E+04 65 diaspore 2.87 2.59 -0.29 -0.048 0.48824E+03 67 diopside 16.18 12.49 -3.69 -0.369 0.62981E+04 68 hedenbergite 14.21 10.26 -3.94 -0.394 0.67353E+04 75 epidote 24.67 22.65 -2.02 -0.098 0.34463E+04 76 clinozoisite 22.81 18.96 -3.85 -0.175 0.65735E+04 77 epidote-Fe 29.84 26.35 -3.49 -0.182 0.59657E+04 78 fayalite 14.05 9.33 -4.71 -0.673 0.80444E+04 83 gibbsite 4.08 2.59 -1.49 -0.213 0.25468E+04 87 greenalite 16.14 12.34 -3.80 -0.317 0.64901E+04 91 heulandite -5.83 -7.52 -1.69 -0.077 0.28938E+04 95 jadeite 4.22 1.97 -2.24 -0.224 0.38332E+04 97 kalsilite 7.58 4.06 -3.52 -0.504 0.60182E+04 98 kaolinite -1.33 -1.48 -0.14 -0.013 0.24606E+03 99 kyanite 4.88 1.85 -3.03 -0.303 0.51682E+04 101 laumontite 2.88 2.46 -0.43 -0.028 0.72892E+03 102 lawsonite 9.62 9.11 -0.51 -0.034 0.86600E+03 103 leucite 4.12 0.73 -3.39 -0.339 0.57811E+04 105 lizardite 23.24 19.03 -4.22 -0.351 0.72020E+04 107 magnetite 20.09 18.90 -1.19 -0.097 0.20334E+04 108 minnesotaite 10.39 5.69 -4.70 -0.277 0.80285E+04 113 margarite 17.32 14.28 -3.04 -0.122 0.51894E+04 116 microcline -2.49 -2.59 -0.11 -0.008 0.18198E+03 121 paragonite 4.24 3.82 -0.42 -0.025 0.71674E+03 122 nepheline 8.34 5.30 -3.04 -0.435 0.51957E+04 136 prehnite 19.37 16.37 -3.00 -0.177 0.51283E+04 137 prehnite-Fe 22.50 20.06 -2.43 -0.146 0.41561E+04 138 pumpellyite-Fe 46.27 41.65 -4.61 -0.103 0.78790E+04 145 pyroxmangite 7.40 5.13 -2.27 -0.453 0.38696E+04 146 pyrophyllite -6.18 -8.13 -1.95 -0.122 0.33355E+04 147 quartz -2.99 -3.33 -0.34 -0.112 0.57500E+03 151 rhodochrosite -0.98 -5.48 -4.50 -1.500 0.76838E+04 152 rhodonite 7.45 5.13 -2.31 -0.463 0.39499E+04 153 sanidine -1.28 -2.59 -1.32 -0.101 0.22497E+04 155 siderite -2.61 -7.60 -5.00 -1.666 0.85315E+04 156 sillimanite 5.26 1.85 -3.41 -0.341 0.58263E+04 164 stilpnomelane-Fe 13.02 12.62 -0.40 -0.012 0.68402E+03 165 stilpnomelane-Mg 27.44 23.76 -3.68 -0.110 0.62824E+04 168 sudoite 21.08 17.49 -3.59 -0.116 0.61231E+04 171 talc 16.49 12.37 -4.12 -0.242 0.70305E+04 174 tephroite 18.09 13.59 -4.49 -0.642 0.76748E+04 177 topaz-H 4.62 1.85 -2.77 -0.252 0.47283E+04 178 tridymite -2.63 -3.33 -0.70 -0.233 0.11950E+04 187 wairakite 3.95 2.46 -1.49 -0.088 0.25509E+04 188 walstromite 11.51 7.26 -4.25 -0.850 0.72562E+04 189 wollastonite 10.46 7.26 -3.20 -0.640 0.54666E+04 190 pseudo-wollastonite 11.00 7.26 -3.74 -0.748 0.63864E+04 191 zoisite 22.85 18.96 -3.89 -0.177 0.66475E+04 192 akaganeite 7.75 6.28 -1.47 -0.318 0.25125E+04 193 beidellite-Ca -1.65 -4.43 -2.79 -0.172 0.47560E+04 194 beidellite-H -2.33 -6.18 -3.85 -0.246 0.65762E+04 195 beidellite-K -1.52 -4.59 -3.07 -0.188 0.52491E+04 196 beidellite-Mg -1.79 -4.77 -2.98 -0.184 0.50807E+04 197 beidellite-Na -1.34 -4.19 -2.84 -0.174 0.48558E+04 199 chalcedony -2.80 -3.33 -0.52 -0.175 0.89429E+03 201 montmorillonite-Ca -2.29 -4.41 -2.12 -0.131 0.36219E+04 202 montmorillonite-K -2.24 -4.58 -2.34 -0.143 0.39931E+04 203 montmorillonite-Mg -2.48 -4.75 -2.27 -0.140 0.38698E+04 204 montmorillonite-Na -2.04 -4.17 -2.13 -0.130 0.36356E+04 205 nontronite-Ca 3.21 2.96 -0.25 -0.017 0.43517E+03 206 nontronite-H 2.53 1.21 -1.32 -0.088 0.22533E+04 207 nontronite-K 3.34 2.80 -0.54 -0.035 0.92957E+03 208 nontronite-Mg 3.07 2.63 -0.45 -0.029 0.76714E+03 209 nontronite-Na 3.52 3.20 -0.32 -0.020 0.53807E+03 224 tobermorite 9.82 5.49 -4.33 -1.182 0.73956E+04 233 boehmite 4.41 2.59 -1.82 -0.303 0.31052E+04 235 ferrous-oxide 9.81 6.33 -3.48 -0.870 0.59442E+04 240 silica-amorphous -2.09 -3.33 -1.23 -0.412 0.21085E+04 242 an20ab80 2.02 0.74 -1.28 -0.099 0.21867E+04 243 an25ab75 2.65 1.26 -1.39 -0.107 0.23655E+04 244 an30ab70 3.28 1.78 -1.50 -0.115 0.25538E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 0.0400000 g Current total amount of reactant added: 0.8390000 g New total amount of reactant added: 0.8790000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.4566E-13 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 7 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 0.8790000 Water: Moles liquid = 0.5550E+02 kg liquid = 0.9998E+00 Moles total = 0.5550E+02 kg total = 0.9998E+00 Activity = 1.0000 Stoichiometric ionic strength = .9061114E-03 Osmotic coef. = 0.9825 True ionic strength = .1356847E-02 Chg. balance for total moles = 0.4566E-13 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.10732E-08 -8.9693 0.10051E-08 -8.9978 0.93657E+00 -0.0285 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13795E-03 -3.8603 0.12912E-03 -3.8890 0.93604E+00 -0.0287 4 SO4-- 0.25485E-04 -4.5937 0.20667E-04 -4.6847 0.81095E+00 -0.0910 5 HCO3- 0.11858E-04 -4.9260 0.11101E-04 -4.9546 0.93616E+00 -0.0286 6 HS- 0.55005E-13 -13.2596 0.51488E-13 -13.2883 0.93605E+00 -0.0287 7 Al+++ 0.58581E-24 -24.2322 0.37338E-24 -24.4278 0.63738E+00 -0.1956 8 H4SiO4 0.48442E-03 -3.3148 0.48442E-03 -3.3148 0.10000E+01 0.0000 9 Ca++ 0.44281E-07 -7.3538 0.35885E-07 -7.4451 0.81040E+00 -0.0913 10 Mg++ 0.45440E-09 -9.3426 0.36809E-09 -9.4340 0.81005E+00 -0.0915 11 Fe++ 0.26808E-11 -11.5717 0.21718E-11 -11.6632 0.81014E+00 -0.0914 12 K+ 0.72644E-04 -4.1388 0.68009E-04 -4.1674 0.93619E+00 -0.0286 13 Na+ 0.12546E-02 -2.9015 0.11743E-02 -2.9302 0.93603E+00 -0.0287 14 Mn++ 0.36018E-09 -9.4435 0.29181E-09 -9.5349 0.81020E+00 -0.0914 15 HPO4-- 0.28267E-05 -5.5487 0.22924E-05 -5.6397 0.81096E+00 -0.0910 16 HSiO3- 0.48076E-03 -3.3181 0.45001E-03 -3.3468 0.93604E+00 -0.0287 17 Ca(HSiO3)+ 0.39282E-09 -9.4058 0.36776E-09 -9.4344 0.93621E+00 -0.0286 18 Mg(HSiO3)+ 0.50146E-11 -11.2998 0.46947E-11 -11.3284 0.93621E+00 -0.0286 19 NaHSiO3,aq 0.85468E-05 -5.0682 0.85468E-05 -5.0682 0.10000E+01 0.0000 20 AlO+ 0.53704E-13 -13.2700 0.50278E-13 -13.2986 0.93621E+00 -0.0286 21 AlOH+2 0.31056E-18 -18.5078 0.25164E-18 -18.5992 0.81027E+00 -0.0914 22 HAlO2,aq 0.99616E-08 -8.0017 0.99616E-08 -8.0017 0.10000E+01 0.0000 23 AlO2- 0.23441E-04 -4.6300 0.21938E-04 -4.6588 0.93588E+00 -0.0288 24 CH4,aq 0.26872E-19 -19.5707 0.26864E-19 -19.5708 0.99972E+00 -0.0001 29 CO,aq 0.28636E-18 -18.5431 0.28636E-18 -18.5431 0.10000E+01 0.0000 30 CO2,aq 0.23849E-07 -7.6225 0.23843E-07 -7.6226 0.99972E+00 -0.0001 31 CO3-2 0.11898E-05 -5.9245 0.96469E-06 -6.0156 0.81079E+00 -0.0911 32 CaCO3,aq 0.43407E-09 -9.3624 0.43407E-09 -9.3624 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.10862E-10 -10.9641 0.10169E-10 -10.9927 0.93621E+00 -0.0286 34 CaCl+ 0.80096E-11 -11.0964 0.74987E-11 -11.1250 0.93621E+00 -0.0286 35 CaCl2,aq 0.23004E-15 -15.6382 0.23004E-15 -15.6382 0.10000E+01 0.0000 36 CaOH+ 0.27178E-08 -8.5658 0.25444E-08 -8.5944 0.93621E+00 -0.0286 37 CaSO4,aq 0.23551E-09 -9.6280 0.23551E-09 -9.6280 0.10000E+01 0.0000 38 HCl,aq 0.23783E-13 -13.6237 0.23783E-13 -13.6237 0.10000E+01 0.0000 43 FeCl+ 0.47412E-15 -15.3241 0.44387E-15 -15.3527 0.93621E+00 -0.0286 46 FeO,aq 0.83547E-10 -10.0781 0.83547E-10 -10.0781 0.10000E+01 0.0000 47 FeOH+ 0.75125E-10 -10.1242 0.70332E-10 -10.1528 0.93621E+00 -0.0286 48 HFeO2- 0.92912E-09 -9.0319 0.86969E-09 -9.0606 0.93604E+00 -0.0287 49 FeO+ 0.81949E-14 -14.0865 0.76721E-14 -14.1151 0.93621E+00 -0.0286 51 FeO2- 0.16600E-08 -8.7799 0.15539E-08 -8.8086 0.93604E+00 -0.0287 52 HFeO2,aq 0.19864E-09 -9.7019 0.19864E-09 -9.7019 0.10000E+01 0.0000 53 H2,aq 0.47825E-09 -9.3203 0.47811E-09 -9.3205 0.99972E+00 -0.0001 54 KCl,aq 0.15916E-09 -9.7982 0.15916E-09 -9.7982 0.10000E+01 0.0000 55 KHSO4,aq 0.39945E-17 -17.3985 0.39945E-17 -17.3985 0.10000E+01 0.0000 56 KOH,aq 0.28895E-07 -7.5392 0.28895E-07 -7.5392 0.10000E+01 0.0000 57 KSO4- 0.23301E-07 -7.6326 0.21811E-07 -7.6613 0.93604E+00 -0.0287 58 MgCO3,aq 0.11160E-11 -11.9523 0.11160E-11 -11.9523 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.11384E-12 -12.9437 0.10658E-12 -12.9723 0.93621E+00 -0.0286 60 MgCl+ 0.74464E-13 -13.1281 0.69714E-13 -13.1567 0.93621E+00 -0.0286 61 MgOH+ 0.15426E-09 -9.8117 0.14442E-09 -9.8404 0.93621E+00 -0.0286 63 MnO,aq 0.29912E-09 -9.5242 0.29912E-09 -9.5242 0.10000E+01 0.0000 64 MnOH+ 0.93772E-09 -9.0279 0.87790E-09 -9.0566 0.93621E+00 -0.0286 65 MnO2-2 0.12119E-13 -13.9165 0.98257E-14 -14.0076 0.81079E+00 -0.0911 66 HMnO2- 0.23116E-11 -11.6361 0.21637E-11 -11.6648 0.93604E+00 -0.0287 69 MnCl+ 0.24784E-12 -12.6058 0.23203E-12 -12.6344 0.93621E+00 -0.0286 70 MnSO4,aq 0.17411E-11 -11.7592 0.17411E-11 -11.7592 0.10000E+01 0.0000 71 NaCl,aq 0.50250E-07 -7.2989 0.50250E-07 -7.2989 0.10000E+01 0.0000 72 NaOH,aq 0.50195E-06 -6.2993 0.50195E-06 -6.2993 0.10000E+01 0.0000 74 OH- 0.61420E-03 -3.2117 0.57482E-03 -3.2405 0.93588E+00 -0.0288 79 HPO3-2 0.42126E-17 -17.3755 0.34155E-17 -17.4665 0.81079E+00 -0.0911 82 H3PO4,aq 0.16198E-13 -13.7905 0.16198E-13 -13.7905 0.10000E+01 0.0000 83 H2PO4- 0.45406E-07 -7.3429 0.42505E-07 -7.3716 0.93612E+00 -0.0287 84 PO4-3 0.29058E-08 -8.5367 0.18608E-08 -8.7303 0.64035E+00 -0.1936 87 H2P2O7-2 0.17472E-15 -15.7577 0.14166E-15 -15.8487 0.81079E+00 -0.0911 88 HP2O7-3 0.44150E-13 -13.3551 0.28142E-13 -13.5506 0.63741E+00 -0.1956 89 P2O7-4 0.14653E-13 -13.8341 0.66887E-14 -14.1747 0.45646E+00 -0.3406 90 H2S,aq 0.15999E-15 -15.7959 0.15995E-15 -15.7960 0.99972E+00 -0.0001 97 SO3-2 0.15816E-14 -14.8009 0.12841E-14 -14.8914 0.81190E+00 -0.0905 98 HSO3- 0.86335E-16 -16.0638 0.80813E-16 -16.0925 0.93604E+00 -0.0287 99 HSO4- 0.21382E-10 -10.6699 0.20020E-10 -10.6985 0.93629E+00 -0.0286 Charge balance for all species = 0.4567E-13 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.1073213E-08 -.1198969E-02 -.1208327E+01 0.0000 2 H2O 0.1000000E+01 0.5550842E+02 0.9998667E+06 0.0000 3 Cl- 0.1379479E-03 0.1379983E-03 0.4891797E+01 5.1088 4 SO4-- 0.2548537E-04 0.2550904E-04 0.2450110E+01 13.3108 5 HCO3- 0.1185818E-04 0.1307228E-04 0.7975271E+00 4.0431 6 HS- 0.5500542E-13 -.1127190E-09 -.3727344E-05 -4.2905 7 Al+++ 0.5858096E-24 0.2345125E-04 0.6326650E+00 2.5655 8 H4SiO4 0.4844160E-03 0.9737198E-03 0.9357690E+02 -3.3148 9 Ca++ 0.4428054E-07 0.4807962E-07 0.1926676E-02 10.5505 10 Mg++ 0.4544032E-09 0.6149848E-09 0.1494950E-04 8.5615 11 Fe++ 0.2680763E-11 0.2949164E-08 0.1646799E-03 6.3324 12 K+ 0.7264420E-04 0.7269656E-04 0.2842199E+01 4.8303 13 Na+ 0.1254552E-02 0.1263651E-02 0.2904718E+02 6.0676 14 Mn++ 0.3601761E-09 0.1601332E-08 0.8796215E-04 8.4607 15 HPO4-- 0.2826707E-05 0.2875019E-05 0.2759044E+00 12.3558 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.1454190E-01 -.1198760E-02 -.1334314E-01 0.0000000E+00 2 H2O 0.5549723E+02 0.5549873E+02 -.1495253E-02 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.4986456E-04 0.2550458E-04 0.2435997E-04 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.2436009E-04 -.1126993E-09 -.2435997E-04 0.0000000E+00 7 Al+++ 0.2866192E-02 0.2344715E-04 0.2842745E-02 0.0000000E+00 8 H4SiO4 0.9152836E-02 0.9735497E-03 0.8179287E-02 0.0000000E+00 9 Ca++ 0.1025446E-02 0.4807122E-07 0.1025398E-02 0.0000000E+00 10 Mg++ 0.6976190E-03 0.6148774E-09 0.6976184E-03 0.0000000E+00 11 Fe++ 0.6267346E-03 0.2948649E-08 0.6267316E-03 0.0000000E+00 12 K+ 0.1866242E-03 0.7268386E-04 0.1139403E-03 0.0000000E+00 13 Na+ 0.1263430E-02 0.1263430E-02 0.0000000E+00 0.0000000E+00 14 Mn++ 0.1524063E-04 0.1601052E-08 0.1523902E-04 0.0000000E+00 15 HPO4-- 0.5201550E-05 0.2874517E-05 0.2327033E-05 0.0000000E+00 Chg. balance for solid moles: -.4117E-18 Mass of aqueous solution: 0.999960E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 0.8790000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) apatite-OH 0.7757E-06 -6.110 0.3896E-03 -3.409 0.4223E-01 0.1238E-03 clinochlore 0.1395E-03 -3.855 0.7755E-01 -1.110 8.406 0.2950E-01 daphnite 0.8637E-04 -4.064 0.6163E-01 -1.210 6.680 0.1867E-01 chlorite-Mn 0.3048E-05 -5.516 0.2161E-02 -2.665 0.2342 0.6886E-03 hematite 0.9744E-04 -4.011 0.1556E-01 -1.808 1.687 0.2949E-02 muscovite 0.1139E-03 -3.943 0.4538E-01 -1.343 4.919 0.1605E-01 stilbite 0.1022E-02 -2.991 0.7199 -0.143 78.03 0.3358 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.6094E+00 0.6094E+00 1.0000 -0.215 daphnite 0.3773E+00 0.3773E+00 1.0000 -0.423 chlorite-Mn 0.1331E-01 0.1331E-01 1.0000 -1.876 hematite 0.1000E+01 0.1000E+01 1.0000 0.000 muscovite 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 0.922558 g Volume = 0.403750 cm3 Porosity: 70.1280% V(tot) - V(min): 0.94785E+00 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.8790000 g log = -0.0560 Original solution: 1000.0103000 g Original solution / Rock added: 1137.67 (Water/Rock Ratio), log = 3.0560 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0203 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.1000E+01 0.9860 0.1006E+01 0.1020E+01 CO2,gas 0.2483E-05 1.0071 0.2551E-05 0.2533E-05 CH4,gas 0.3828E-16 1.0125 0.3954E-16 0.3905E-16 H2,gas 0.6149E-06 1.0005 0.6277E-06 0.6274E-06 H2S,gas 0.4327E-14 0.9960 0.4397E-14 0.4414E-14 S2,gas 0.1805E-35 1.0000 0.1842E-35 0.1842E-35 CO,gas 0.4182E-15 1.0000 0.4267E-15 0.4267E-15 SO3,gas 0.7738E-38 1.0000 0.7895E-38 0.7895E-38 SO2,gas 0.1890E-21 1.0000 0.1928E-21 0.1928E-21 HCl,gas 0.4113E-16 1.0000 0.4197E-16 0.4197E-16 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 32 apatite-OH -18.15 -18.15 0.00 0.000 -0.60662E-11 46 clinochlore 39.07 39.07 0.00 0.000 -0.12132E-10 47 daphnite 28.97 28.97 0.00 0.000 0.00000E+00 48 chlorite-Mn 46.87 46.87 0.00 0.000 -0.12132E-10 90 hematite 12.57 12.57 0.00 0.000 -0.30331E-11 120 muscovite 2.58 2.58 0.00 0.000 0.30331E-10 163 stilbite -7.52 -7.52 0.00 0.000 0.15165E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -13.95 -7.29 -2.431 0.12451E+05 -5.593 3 CH4,gas 4.54 -13.56 -18.10 -4.525 0.30909E+05 -16.403 4 H2,gas 8.00 0.10 -7.90 -4.515 0.13491E+05 -6.202 5 H2S,gas -6.23 -22.29 -16.06 -8.028 0.27415E+05 -14.357 6 S2,gas -7.34 -44.77 -37.43 -5.759 0.63917E+05 -35.735 7 CO,gas 3.21 -13.85 -17.07 -5.252 0.29145E+05 -15.370 8 SO3,gas 17.12 -22.68 -39.80 -9.950 0.67960E+05 -38.103 9 SO2,gas 0.83 -22.58 -23.41 -6.244 0.39979E+05 -21.715 10 HCl,gas 5.19 -12.89 -18.08 -9.038 0.30864E+05 -16.377 11 acmite 7.71 5.72 -1.99 -0.207 0.33955E+04 15 albite-high 0.69 -1.31 -2.00 -0.154 0.34224E+04 16 albite -0.38 -1.31 -0.93 -0.071 0.15836E+04 19 spessartine 24.46 20.57 -3.89 -0.194 0.66399E+04 20 analcite 3.32 2.00 -1.32 -0.146 0.22511E+04 21 andalusite 5.00 1.82 -3.19 -0.319 0.54389E+04 22 andradite 39.01 34.27 -4.74 -0.246 0.80858E+04 26 annite 20.12 16.45 -3.67 -0.204 0.62747E+04 27 phlogopite 27.06 23.14 -3.93 -0.218 0.67080E+04 29 anorthite 12.71 9.05 -3.66 -0.281 0.62467E+04 35 aragonite 0.97 -3.40 -4.37 -1.456 0.74590E+04 36 brucite 12.57 8.56 -4.01 -0.801 0.68420E+04 37 calcite 0.81 -3.40 -4.21 -1.405 0.71948E+04 38 carnegieite-low 9.02 5.32 -3.71 -0.529 0.63263E+04 39 carnegieite-high 10.09 5.32 -4.78 -0.682 0.81533E+04 40 carpholite-Mg 8.58 7.06 -1.52 -0.101 0.25940E+04 41 carpholite-Fe 6.71 4.83 -1.88 -0.125 0.32081E+04 42 celadonite 5.34 2.70 -2.64 -0.155 0.45135E+04 43 celadonite-Fe 3.88 0.47 -3.41 -0.200 0.58182E+04 44 chrysotile 23.89 19.05 -4.84 -0.403 0.82598E+04 50 chloritoid-Mg 13.20 10.38 -2.82 -0.188 0.48151E+04 51 chloritoid-Fe 9.17 8.15 -1.03 -0.068 0.17503E+04 52 chloritoid-Mn 11.40 10.28 -1.12 -0.075 0.19196E+04 54 coesite -2.38 -3.31 -0.94 -0.313 0.16028E+04 59 corundum 8.38 5.13 -3.25 -0.296 0.55530E+04 61 cristobalite -2.56 -3.31 -0.75 -0.251 0.12882E+04 63 cymrite-K 1.69 -2.55 -4.23 -0.353 0.72293E+04 65 diaspore 2.87 2.57 -0.31 -0.051 0.52627E+03 67 diopside 16.18 12.48 -3.70 -0.370 0.63159E+04 68 hedenbergite 14.21 10.25 -3.96 -0.396 0.67531E+04 75 epidote 24.67 22.57 -2.10 -0.102 0.35845E+04 76 clinozoisite 22.81 18.85 -3.95 -0.180 0.67497E+04 77 epidote-Fe 29.84 26.29 -3.55 -0.185 0.60659E+04 78 fayalite 14.05 9.35 -4.70 -0.671 0.80179E+04 83 gibbsite 4.08 2.57 -1.51 -0.216 0.25848E+04 87 greenalite 16.14 12.37 -3.77 -0.314 0.64405E+04 91 heulandite -5.83 -7.52 -1.69 -0.077 0.28938E+04 95 jadeite 4.22 2.00 -2.21 -0.221 0.37766E+04 97 kalsilite 7.58 4.08 -3.50 -0.500 0.59811E+04 98 kaolinite -1.33 -1.50 -0.17 -0.015 0.28316E+03 99 kyanite 4.88 1.82 -3.06 -0.306 0.52248E+04 101 laumontite 2.88 2.42 -0.46 -0.031 0.78735E+03 102 lawsonite 9.62 9.05 -0.56 -0.038 0.96338E+03 103 leucite 4.12 0.77 -3.35 -0.335 0.57245E+04 105 lizardite 23.24 19.05 -4.19 -0.349 0.71524E+04 107 magnetite 20.09 18.90 -1.19 -0.097 0.20299E+04 108 minnesotaite 10.39 5.74 -4.65 -0.274 0.79400E+04 113 margarite 17.32 14.18 -3.14 -0.126 0.53628E+04 116 microcline -2.49 -2.55 -0.06 -0.005 0.10592E+03 121 paragonite 4.24 3.82 -0.42 -0.025 0.71678E+03 122 nepheline 8.34 5.32 -3.02 -0.432 0.51586E+04 136 prehnite 19.37 16.29 -3.08 -0.181 0.52664E+04 137 prehnite-Fe 22.50 20.01 -2.49 -0.150 0.42562E+04 138 pumpellyite-Fe 46.27 41.47 -4.80 -0.107 0.81899E+04 145 pyroxmangite 7.40 5.15 -2.25 -0.451 0.38466E+04 146 pyrophyllite -6.18 -8.13 -1.95 -0.122 0.33336E+04 147 quartz -2.99 -3.31 -0.33 -0.108 0.55552E+03 151 rhodochrosite -0.98 -5.49 -4.52 -1.505 0.77100E+04 152 rhodonite 7.45 5.15 -2.30 -0.460 0.39269E+04 153 sanidine -1.28 -2.55 -1.27 -0.098 0.21737E+04 156 sillimanite 5.26 1.82 -3.45 -0.345 0.58828E+04 164 stilpnomelane-Fe 13.02 12.69 -0.33 -0.010 0.55880E+03 165 stilpnomelane-Mg 27.44 23.84 -3.61 -0.108 0.61572E+04 168 sudoite 21.08 17.44 -3.64 -0.117 0.62097E+04 171 talc 16.49 12.43 -4.07 -0.239 0.69421E+04 174 tephroite 18.09 13.61 -4.48 -0.640 0.76482E+04 177 topaz-H 4.62 1.82 -2.80 -0.255 0.47849E+04 178 tridymite -2.63 -3.31 -0.69 -0.229 0.11755E+04 187 wairakite 3.95 2.42 -1.53 -0.090 0.26093E+04 188 walstromite 11.51 7.24 -4.27 -0.855 0.72970E+04 189 wollastonite 10.46 7.24 -3.23 -0.645 0.55074E+04 190 pseudo-wollastonite 11.00 7.24 -3.76 -0.753 0.64272E+04 191 zoisite 22.85 18.85 -4.00 -0.182 0.68237E+04 192 akaganeite 7.75 6.28 -1.47 -0.318 0.25125E+04 193 beidellite-Ca -1.65 -4.45 -2.80 -0.173 0.47831E+04 194 beidellite-H -2.33 -6.19 -3.86 -0.246 0.65933E+04 195 beidellite-K -1.52 -4.59 -3.07 -0.188 0.52478E+04 196 beidellite-Mg -1.79 -4.78 -2.99 -0.185 0.50972E+04 197 beidellite-Na -1.34 -4.19 -2.84 -0.174 0.48546E+04 199 chalcedony -2.80 -3.31 -0.51 -0.171 0.87482E+03 201 montmorillonite-Ca -2.29 -4.41 -2.12 -0.131 0.36163E+04 202 montmorillonite-K -2.24 -4.56 -2.32 -0.142 0.39592E+04 203 montmorillonite-Mg -2.48 -4.74 -2.26 -0.140 0.38537E+04 204 montmorillonite-Na -2.04 -4.15 -2.11 -0.129 0.36017E+04 205 nontronite-Ca 3.21 2.99 -0.23 -0.015 0.38618E+03 206 nontronite-H 2.53 1.25 -1.29 -0.086 0.21944E+04 207 nontronite-K 3.34 2.84 -0.50 -0.032 0.85228E+03 208 nontronite-Mg 3.07 2.66 -0.41 -0.027 0.70763E+03 209 nontronite-Na 3.52 3.25 -0.27 -0.017 0.46079E+03 224 tobermorite 9.82 5.47 -4.35 -1.187 0.74263E+04 233 boehmite 4.41 2.57 -1.84 -0.307 0.31432E+04 235 ferrous-oxide 9.81 6.33 -3.48 -0.870 0.59407E+04 240 silica-amorphous -2.09 -3.31 -1.22 -0.408 0.20890E+04 242 an20ab80 2.02 0.76 -1.26 -0.097 0.21454E+04 243 an25ab75 2.65 1.28 -1.37 -0.105 0.23328E+04 244 an30ab70 3.28 1.80 -1.48 -0.114 0.25298E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 0.0400000 g Current total amount of reactant added: 0.8790000 g New total amount of reactant added: 0.9190000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.4566E-13 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 7 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 0.9190000 Water: Moles liquid = 0.5550E+02 kg liquid = 0.9998E+00 Moles total = 0.5550E+02 kg total = 0.9998E+00 Activity = 1.0000 Stoichiometric ionic strength = .9324849E-03 Osmotic coef. = 0.9823 True ionic strength = .1409745E-02 Chg. balance for total moles = 0.4566E-13 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.10381E-08 -8.9838 0.97137E-09 -9.0126 0.93576E+00 -0.0288 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13795E-03 -3.8603 0.12901E-03 -3.8894 0.93521E+00 -0.0291 4 SO4-- 0.25485E-04 -4.5937 0.20595E-04 -4.6862 0.80812E+00 -0.0925 5 HCO3- 0.11819E-04 -4.9274 0.11055E-04 -4.9565 0.93534E+00 -0.0290 6 HS- 0.55126E-13 -13.2586 0.51555E-13 -13.2877 0.93522E+00 -0.0291 7 Al+++ 0.50763E-24 -24.2945 0.32100E-24 -24.4935 0.63236E+00 -0.1990 8 H4SiO4 0.49633E-03 -3.3042 0.49633E-03 -3.3042 0.10000E+01 0.0000 9 Ca++ 0.38585E-07 -7.4136 0.31160E-07 -7.5064 0.80756E+00 -0.0928 10 Mg++ 0.42797E-09 -9.3686 0.34546E-09 -9.4616 0.80720E+00 -0.0930 11 Fe++ 0.25248E-11 -11.5978 0.20382E-11 -11.6907 0.80728E+00 -0.0930 12 K+ 0.75589E-04 -4.1215 0.70703E-04 -4.1506 0.93537E+00 -0.0290 13 Na+ 0.13039E-02 -2.8848 0.12194E-02 -2.9139 0.93520E+00 -0.0291 14 Mn++ 0.33922E-09 -9.4695 0.27387E-09 -9.5625 0.80735E+00 -0.0929 15 HPO4-- 0.34293E-05 -5.4648 0.27714E-05 -5.5573 0.80814E+00 -0.0925 16 HSiO3- 0.51016E-03 -3.2923 0.47711E-03 -3.3214 0.93521E+00 -0.0291 17 Ca(HSiO3)+ 0.36195E-09 -9.4413 0.33857E-09 -9.4704 0.93539E+00 -0.0290 18 Mg(HSiO3)+ 0.49940E-11 -11.3015 0.46713E-11 -11.3306 0.93539E+00 -0.0290 19 NaHSiO3,aq 0.94094E-05 -5.0264 0.94094E-05 -5.0264 0.10000E+01 0.0000 20 AlO+ 0.49479E-13 -13.3056 0.46282E-13 -13.3346 0.93539E+00 -0.0290 21 AlOH+2 0.27725E-18 -18.5571 0.22386E-18 -18.6500 0.80742E+00 -0.0929 22 HAlO2,aq 0.94886E-08 -8.0228 0.94886E-08 -8.0228 0.10000E+01 0.0000 23 AlO2- 0.23125E-04 -4.6359 0.21623E-04 -4.6651 0.93504E+00 -0.0292 24 CH4,aq 0.26889E-19 -19.5704 0.26881E-19 -19.5706 0.99971E+00 -0.0001 29 CO,aq 0.27828E-18 -18.5555 0.27828E-18 -18.5555 0.10000E+01 0.0000 30 CO2,aq 0.22951E-07 -7.6392 0.22945E-07 -7.6393 0.99971E+00 -0.0001 31 CO3-2 0.12303E-05 -5.9100 0.99403E-06 -6.0026 0.80796E+00 -0.0926 32 CaCO3,aq 0.38838E-09 -9.4107 0.38838E-09 -9.4107 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.94000E-11 -11.0269 0.87926E-11 -11.0559 0.93539E+00 -0.0290 34 CaCl+ 0.69549E-11 -11.1577 0.65055E-11 -11.1867 0.93539E+00 -0.0290 35 CaCl2,aq 0.19939E-15 -15.7003 0.19939E-15 -15.7003 0.10000E+01 0.0000 36 CaOH+ 0.24441E-08 -8.6119 0.22862E-08 -8.6409 0.93539E+00 -0.0290 37 CaSO4,aq 0.20378E-09 -9.6908 0.20378E-09 -9.6908 0.10000E+01 0.0000 38 HCl,aq 0.22964E-13 -13.6390 0.22964E-13 -13.6390 0.10000E+01 0.0000 43 FeCl+ 0.44496E-15 -15.3517 0.41621E-15 -15.3807 0.93539E+00 -0.0290 46 FeO,aq 0.83955E-10 -10.0760 0.83955E-10 -10.0760 0.10000E+01 0.0000 47 FeOH+ 0.73020E-10 -10.1366 0.68302E-10 -10.1656 0.93539E+00 -0.0290 48 HFeO2- 0.96697E-09 -9.0146 0.90432E-09 -9.0437 0.93521E+00 -0.0291 49 FeO+ 0.79266E-14 -14.1009 0.74144E-14 -14.1299 0.93539E+00 -0.0290 51 FeO2- 0.17193E-08 -8.7647 0.16079E-08 -8.7937 0.93521E+00 -0.0291 52 HFeO2,aq 0.19864E-09 -9.7019 0.19864E-09 -9.7019 0.10000E+01 0.0000 53 H2,aq 0.48294E-09 -9.3161 0.48280E-09 -9.3162 0.99971E+00 -0.0001 54 KCl,aq 0.16532E-09 -9.7817 0.16532E-09 -9.7817 0.10000E+01 0.0000 55 KHSO4,aq 0.39991E-17 -17.3980 0.39991E-17 -17.3980 0.10000E+01 0.0000 56 KOH,aq 0.31084E-07 -7.5075 0.31084E-07 -7.5075 0.10000E+01 0.0000 57 KSO4- 0.24161E-07 -7.6169 0.22595E-07 -7.6460 0.93521E+00 -0.0291 58 MgCO3,aq 0.10793E-11 -11.9669 0.10793E-11 -11.9669 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.10649E-12 -12.9727 0.99607E-13 -13.0017 0.93539E+00 -0.0290 60 MgCl+ 0.69884E-13 -13.1556 0.65369E-13 -13.1846 0.93539E+00 -0.0290 61 MgOH+ 0.14994E-09 -9.8241 0.14025E-09 -9.8531 0.93539E+00 -0.0290 63 MnO,aq 0.30059E-09 -9.5220 0.30059E-09 -9.5220 0.10000E+01 0.0000 64 MnOH+ 0.91146E-09 -9.0403 0.85256E-09 -9.0693 0.93539E+00 -0.0290 65 MnO2-2 0.13085E-13 -13.8832 0.10572E-13 -13.9758 0.80796E+00 -0.0926 66 HMnO2- 0.24058E-11 -11.6187 0.22499E-11 -11.6478 0.93521E+00 -0.0291 69 MnCl+ 0.23260E-12 -12.6334 0.21757E-12 -12.6624 0.93539E+00 -0.0290 70 MnSO4,aq 0.16283E-11 -11.7883 0.16283E-11 -11.7883 0.10000E+01 0.0000 71 NaCl,aq 0.52134E-07 -7.2829 0.52134E-07 -7.2829 0.10000E+01 0.0000 72 NaOH,aq 0.53935E-06 -6.2681 0.53935E-06 -6.2681 0.10000E+01 0.0000 74 OH- 0.63612E-03 -3.1965 0.59480E-03 -3.2256 0.93504E+00 -0.0292 79 HPO3-2 0.51608E-17 -17.2873 0.41697E-17 -17.3799 0.80796E+00 -0.0926 82 H3PO4,aq 0.18289E-13 -13.7378 0.18289E-13 -13.7378 0.10000E+01 0.0000 83 H2PO4- 0.53096E-07 -7.2749 0.49661E-07 -7.3040 0.93530E+00 -0.0291 84 PO4-3 0.36634E-08 -8.4361 0.23278E-08 -8.6331 0.63541E+00 -0.1969 87 H2P2O7-2 0.23934E-15 -15.6210 0.19337E-15 -15.7136 0.80796E+00 -0.0926 88 HP2O7-3 0.62856E-13 -13.2017 0.39750E-13 -13.4007 0.63239E+00 -0.1990 89 P2O7-4 0.21718E-13 -13.6632 0.97760E-14 -14.0098 0.45013E+00 -0.3467 90 H2S,aq 0.15482E-15 -15.8102 0.15478E-15 -15.8103 0.99971E+00 -0.0001 97 SO3-2 0.15970E-14 -14.7967 0.12921E-14 -14.8887 0.80910E+00 -0.0920 98 HSO3- 0.84030E-16 -16.0756 0.78586E-16 -16.1047 0.93521E+00 -0.0291 99 HSO4- 0.20609E-10 -10.6859 0.19279E-10 -10.7149 0.93547E+00 -0.0290 Charge balance for all species = 0.4567E-13 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.1038057E-08 -.1249959E-02 -.1259708E+01 0.0000 2 H2O 0.1000000E+01 0.5550841E+02 0.9998614E+06 0.0000 3 Cl- 0.1379470E-03 0.1379993E-03 0.4891809E+01 5.1232 4 SO4-- 0.2548473E-04 0.2550924E-04 0.2450117E+01 13.3390 5 HCO3- 0.1181873E-04 0.1307238E-04 0.7975291E+00 4.0562 6 HS- 0.5512625E-13 -.1189497E-09 -.3933356E-05 -4.2751 7 Al+++ 0.5076254E-24 0.2313447E-04 0.6241158E+00 2.5444 8 H4SiO4 0.4963346E-03 0.1015904E-02 0.9763039E+02 -3.3042 9 Ca++ 0.3858536E-07 0.4199994E-07 0.1683039E-02 10.5188 10 Mg++ 0.4279704E-09 0.5841607E-09 0.1420014E-04 8.5636 11 Fe++ 0.2524813E-11 0.3044388E-08 0.1699962E-03 6.3345 12 K+ 0.7558852E-04 0.7564393E-04 0.2957417E+01 4.8621 13 Na+ 0.1303879E-02 0.1313879E-02 0.3020162E+02 6.0988 14 Mn++ 0.3392247E-09 0.1555546E-08 0.8544666E-04 8.4628 15 HPO4-- 0.3429331E-05 0.3486091E-05 0.3345449E+00 12.4679 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.1520424E-01 -.1249731E-02 -.1395450E-01 0.0000000E+00 2 H2O 0.5549673E+02 0.5549829E+02 -.1563906E-02 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.5097309E-04 0.2550459E-04 0.2546850E-04 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.2546862E-04 -.1189280E-09 -.2546850E-04 0.0000000E+00 7 Al+++ 0.2996622E-02 0.2313026E-04 0.2973491E-02 0.0000000E+00 8 H4SiO4 0.9569348E-02 0.1015719E-02 0.8553629E-02 0.0000000E+00 9 Ca++ 0.1071452E-02 0.4199229E-07 0.1071410E-02 0.0000000E+00 10 Mg++ 0.7293651E-03 0.5840542E-09 0.7293645E-03 0.0000000E+00 11 Fe++ 0.6552549E-03 0.3043833E-08 0.6552519E-03 0.0000000E+00 12 K+ 0.1951168E-03 0.7563014E-04 0.1194866E-03 0.0000000E+00 13 Na+ 0.1313640E-02 0.1313640E-02 0.0000000E+00 0.0000000E+00 14 Mn++ 0.1593417E-04 0.1555262E-08 0.1593261E-04 0.0000000E+00 15 HPO4-- 0.5438253E-05 0.3485455E-05 0.1952797E-05 0.0000000E+00 Chg. balance for solid moles: -.4989E-18 Mass of aqueous solution: 0.999957E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 0.9190000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) apatite-OH 0.6509E-06 -6.186 0.3270E-03 -3.485 0.3389E-01 0.1039E-03 clinochlore 0.1459E-03 -3.836 0.8108E-01 -1.091 8.405 0.3084E-01 daphnite 0.9030E-04 -4.044 0.6443E-01 -1.191 6.679 0.1952E-01 chlorite-Mn 0.3187E-05 -5.497 0.2259E-02 -2.646 0.2342 0.7199E-03 hematite 0.1019E-03 -3.992 0.1627E-01 -1.789 1.686 0.3084E-02 muscovite 0.1195E-03 -3.923 0.4759E-01 -1.322 4.933 0.1683E-01 stilbite 0.1068E-02 -2.971 0.7528 -0.123 78.03 0.3511 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.6094E+00 0.6094E+00 1.0000 -0.215 daphnite 0.3773E+00 0.3773E+00 1.0000 -0.423 chlorite-Mn 0.1331E-01 0.1331E-01 1.0000 -1.876 hematite 0.1000E+01 0.1000E+01 1.0000 0.000 muscovite 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 0.964710 g Volume = 0.422198 cm3 Porosity: 69.1285% V(tot) - V(min): 0.94540E+00 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.9190000 g log = -0.0367 Original solution: 1000.0103000 g Original solution / Rock added: 1088.15 (Water/Rock Ratio), log = 3.0367 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0203 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.1000E+01 0.9860 0.1006E+01 0.1020E+01 CO2,gas 0.2389E-05 1.0071 0.2455E-05 0.2438E-05 CH4,gas 0.3830E-16 1.0125 0.3957E-16 0.3908E-16 H2,gas 0.6209E-06 1.0005 0.6339E-06 0.6335E-06 H2S,gas 0.4187E-14 0.9960 0.4255E-14 0.4272E-14 S2,gas 0.1658E-35 1.0000 0.1691E-35 0.1691E-35 CO,gas 0.4064E-15 1.0000 0.4147E-15 0.4147E-15 SO3,gas 0.7201E-38 1.0000 0.7348E-38 0.7348E-38 SO2,gas 0.1776E-21 1.0000 0.1812E-21 0.1812E-21 HCl,gas 0.3971E-16 1.0000 0.4052E-16 0.4052E-16 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 32 apatite-OH -18.15 -18.15 0.00 0.000 0.12132E-10 46 clinochlore 39.07 39.07 0.00 0.000 0.24265E-10 47 daphnite 28.97 28.97 0.00 0.000 0.18198E-10 48 chlorite-Mn 46.87 46.87 0.00 0.000 0.24265E-10 90 hematite 12.57 12.57 0.00 0.000 -0.30331E-11 120 muscovite 2.58 2.58 0.00 0.000 -0.18198E-10 163 stilbite -7.52 -7.52 0.00 0.000 -0.90992E-11 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -13.97 -7.31 -2.436 0.12480E+05 -5.610 3 CH4,gas 4.54 -13.56 -18.10 -4.525 0.30908E+05 -16.403 4 H2,gas 8.00 0.10 -7.90 -4.513 0.13484E+05 -6.198 5 H2S,gas -6.23 -22.30 -16.07 -8.035 0.27439E+05 -14.371 6 S2,gas -7.34 -44.81 -37.47 -5.765 0.63980E+05 -35.772 7 CO,gas 3.21 -13.87 -17.08 -5.256 0.29166E+05 -15.382 8 SO3,gas 17.12 -22.71 -39.83 -9.958 0.68013E+05 -38.134 9 SO2,gas 0.83 -22.61 -23.44 -6.251 0.40025E+05 -21.742 10 HCl,gas 5.19 -12.90 -18.09 -9.046 0.30890E+05 -16.392 11 acmite 7.71 5.77 -1.94 -0.201 0.33062E+04 15 albite-high 0.69 -1.27 -1.96 -0.151 0.33511E+04 16 albite -0.38 -1.27 -0.89 -0.068 0.15123E+04 19 spessartine 24.46 20.56 -3.89 -0.195 0.66472E+04 20 analcite 3.32 2.03 -1.29 -0.143 0.21979E+04 21 andalusite 5.00 1.78 -3.22 -0.322 0.54930E+04 22 andradite 39.01 34.21 -4.80 -0.249 0.81938E+04 26 annite 20.12 16.50 -3.63 -0.201 0.61917E+04 27 phlogopite 27.06 23.18 -3.88 -0.216 0.66250E+04 29 anorthite 12.71 9.00 -3.71 -0.285 0.63368E+04 35 aragonite 0.97 -3.45 -4.42 -1.472 0.75415E+04 36 brucite 12.57 8.56 -4.00 -0.801 0.68383E+04 37 calcite 0.81 -3.45 -4.26 -1.421 0.72773E+04 38 carnegieite-low 9.02 5.34 -3.68 -0.526 0.62910E+04 39 carnegieite-high 10.09 5.34 -4.75 -0.679 0.81180E+04 40 carpholite-Mg 8.58 7.04 -1.54 -0.103 0.26265E+04 41 carpholite-Fe 6.71 4.81 -1.90 -0.127 0.32406E+04 42 celadonite 5.34 2.75 -2.59 -0.152 0.44198E+04 43 celadonite-Fe 3.88 0.52 -3.35 -0.197 0.57244E+04 44 chrysotile 23.89 19.08 -4.81 -0.401 0.82129E+04 50 chloritoid-Mg 13.20 10.35 -2.85 -0.190 0.48656E+04 51 chloritoid-Fe 9.17 8.12 -1.05 -0.070 0.18008E+04 52 chloritoid-Mn 11.40 10.25 -1.15 -0.077 0.19701E+04 54 coesite -2.38 -3.30 -0.93 -0.309 0.15848E+04 59 corundum 8.38 5.09 -3.29 -0.299 0.56251E+04 61 cristobalite -2.56 -3.30 -0.74 -0.248 0.12702E+04 63 cymrite-K 1.69 -2.51 -4.19 -0.349 0.71572E+04 65 diaspore 2.87 2.54 -0.33 -0.055 0.56235E+03 67 diopside 16.18 12.47 -3.71 -0.371 0.63302E+04 68 hedenbergite 14.21 10.24 -3.96 -0.396 0.67674E+04 75 epidote 24.67 22.50 -2.17 -0.105 0.37106E+04 76 clinozoisite 22.81 18.76 -4.05 -0.184 0.69119E+04 77 epidote-Fe 29.84 26.24 -3.61 -0.187 0.61559E+04 78 fayalite 14.05 9.36 -4.68 -0.669 0.79927E+04 83 gibbsite 4.08 2.54 -1.53 -0.219 0.26209E+04 87 greenalite 16.14 12.39 -3.74 -0.312 0.63936E+04 91 heulandite -5.83 -7.52 -1.69 -0.077 0.28938E+04 95 jadeite 4.22 2.03 -2.18 -0.218 0.37234E+04 97 kalsilite 7.58 4.10 -3.48 -0.497 0.59450E+04 98 kaolinite -1.33 -1.52 -0.19 -0.017 0.31926E+03 99 kyanite 4.88 1.78 -3.09 -0.309 0.52789E+04 101 laumontite 2.88 2.39 -0.49 -0.033 0.84142E+03 102 lawsonite 9.62 9.00 -0.62 -0.041 0.10535E+04 103 leucite 4.12 0.80 -3.32 -0.332 0.56704E+04 105 lizardite 23.24 19.08 -4.16 -0.347 0.71055E+04 107 magnetite 20.09 18.90 -1.19 -0.097 0.20263E+04 108 minnesotaite 10.39 5.79 -4.60 -0.271 0.78570E+04 113 margarite 17.32 14.09 -3.24 -0.129 0.55251E+04 116 microcline -2.49 -2.51 -0.02 -0.002 0.33772E+02 121 paragonite 4.24 3.82 -0.42 -0.025 0.71765E+03 122 nepheline 8.34 5.34 -3.00 -0.429 0.51234E+04 136 prehnite 19.37 16.21 -3.16 -0.186 0.53926E+04 137 prehnite-Fe 22.50 19.95 -2.55 -0.153 0.43463E+04 138 pumpellyite-Fe 46.27 41.31 -4.96 -0.110 0.84746E+04 145 pyroxmangite 7.40 5.16 -2.24 -0.448 0.38250E+04 146 pyrophyllite -6.18 -8.13 -1.95 -0.122 0.33337E+04 147 quartz -2.99 -3.30 -0.31 -0.105 0.53750E+03 151 rhodochrosite -0.98 -5.51 -4.53 -1.510 0.77348E+04 152 rhodonite 7.45 5.16 -2.29 -0.457 0.39052E+04 153 sanidine -1.28 -2.51 -1.23 -0.095 0.21015E+04 156 sillimanite 5.26 1.78 -3.48 -0.348 0.59370E+04 164 stilpnomelane-Fe 13.02 12.76 -0.26 -0.008 0.44161E+03 165 stilpnomelane-Mg 27.44 23.90 -3.54 -0.106 0.60400E+04 168 sudoite 21.08 17.39 -3.69 -0.119 0.62927E+04 171 talc 16.49 12.47 -4.02 -0.236 0.68591E+04 174 tephroite 18.09 13.62 -4.46 -0.638 0.76230E+04 177 topaz-H 4.62 1.78 -2.83 -0.258 0.48390E+04 178 tridymite -2.63 -3.30 -0.68 -0.226 0.11575E+04 187 wairakite 3.95 2.39 -1.56 -0.092 0.26634E+04 188 walstromite 11.51 7.21 -4.29 -0.859 0.73330E+04 189 wollastonite 10.46 7.21 -3.25 -0.649 0.55434E+04 190 pseudo-wollastonite 11.00 7.21 -3.79 -0.757 0.64632E+04 191 zoisite 22.85 18.76 -4.09 -0.186 0.69859E+04 192 akaganeite 7.75 6.28 -1.47 -0.318 0.25125E+04 193 beidellite-Ca -1.65 -4.46 -2.82 -0.174 0.48099E+04 194 beidellite-H -2.33 -6.20 -3.87 -0.247 0.66112E+04 195 beidellite-K -1.52 -4.59 -3.07 -0.188 0.52478E+04 196 beidellite-Mg -1.79 -4.79 -3.00 -0.185 0.51145E+04 197 beidellite-Na -1.34 -4.19 -2.84 -0.174 0.48549E+04 199 chalcedony -2.80 -3.30 -0.50 -0.167 0.85679E+03 201 montmorillonite-Ca -2.29 -4.41 -2.12 -0.131 0.36122E+04 202 montmorillonite-K -2.24 -4.54 -2.30 -0.141 0.39283E+04 203 montmorillonite-Mg -2.48 -4.73 -2.25 -0.139 0.38400E+04 204 montmorillonite-Na -2.04 -4.13 -2.09 -0.128 0.35711E+04 205 nontronite-Ca 3.21 3.01 -0.20 -0.013 0.34085E+03 206 nontronite-H 2.53 1.28 -1.25 -0.084 0.21401E+04 207 nontronite-K 3.34 2.88 -0.46 -0.029 0.78016E+03 208 nontronite-Mg 3.07 2.69 -0.38 -0.025 0.65279E+03 209 nontronite-Na 3.52 3.29 -0.23 -0.015 0.38896E+03 224 tobermorite 9.82 5.46 -4.37 -1.191 0.74533E+04 233 boehmite 4.41 2.54 -1.86 -0.310 0.31793E+04 235 ferrous-oxide 9.81 6.33 -3.48 -0.869 0.59371E+04 240 silica-amorphous -2.09 -3.30 -1.21 -0.404 0.20710E+04 242 an20ab80 2.02 0.78 -1.23 -0.095 0.21064E+04 243 an25ab75 2.65 1.30 -1.35 -0.104 0.23019E+04 244 an30ab70 3.28 1.81 -1.47 -0.113 0.25070E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 0.0400000 g Current total amount of reactant added: 0.9190000 g New total amount of reactant added: 0.9590000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.4566E-13 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 7 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 0.9590000 Water: Moles liquid = 0.5550E+02 kg liquid = 0.9998E+00 Moles total = 0.5550E+02 kg total = 0.9998E+00 Activity = 1.0000 Stoichiometric ionic strength = .9591489E-03 Osmotic coef. = 0.9820 True ionic strength = .1462752E-02 Chg. balance for total moles = 0.4566E-13 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.10055E-08 -8.9976 0.94009E-09 -9.0268 0.93497E+00 -0.0292 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13795E-03 -3.8603 0.12890E-03 -3.8898 0.93440E+00 -0.0295 4 SO4-- 0.25484E-04 -4.5937 0.20524E-04 -4.6877 0.80536E+00 -0.0940 5 HCO3- 0.11780E-04 -4.9289 0.11009E-04 -4.9583 0.93453E+00 -0.0294 6 HS- 0.55373E-13 -13.2567 0.51741E-13 -13.2862 0.93441E+00 -0.0295 7 Al+++ 0.44277E-24 -24.3538 0.27783E-24 -24.5562 0.62747E+00 -0.2024 8 H4SiO4 0.50765E-03 -3.2944 0.50765E-03 -3.2944 0.10000E+01 0.0000 9 Ca++ 0.33973E-07 -7.4689 0.27341E-07 -7.5632 0.80477E+00 -0.0943 10 Mg++ 0.40424E-09 -9.3934 0.32517E-09 -9.4879 0.80440E+00 -0.0945 11 Fe++ 0.23848E-11 -11.6225 0.19186E-11 -11.7170 0.80449E+00 -0.0945 12 K+ 0.78613E-04 -4.1045 0.73468E-04 -4.1339 0.93456E+00 -0.0294 13 Na+ 0.13532E-02 -2.8686 0.12644E-02 -2.8981 0.93439E+00 -0.0295 14 Mn++ 0.32042E-09 -9.4943 0.25779E-09 -9.5887 0.80456E+00 -0.0944 15 HPO4-- 0.40962E-05 -5.3876 0.32990E-05 -5.4816 0.80537E+00 -0.0940 16 HSiO3- 0.53962E-03 -3.2679 0.50422E-03 -3.2974 0.93440E+00 -0.0295 17 Ca(HSiO3)+ 0.33593E-09 -9.4738 0.31395E-09 -9.5031 0.93458E+00 -0.0294 18 Mg(HSiO3)+ 0.49723E-11 -11.3034 0.46470E-11 -11.3328 0.93458E+00 -0.0294 19 NaHSiO3,aq 0.10311E-04 -4.9867 0.10311E-04 -4.9867 0.10000E+01 0.0000 20 AlO+ 0.45761E-13 -13.3395 0.42768E-13 -13.3689 0.93458E+00 -0.0294 21 AlOH+2 0.24881E-18 -18.6041 0.20020E-18 -18.6985 0.80463E+00 -0.0944 22 HAlO2,aq 0.90599E-08 -8.0429 0.90599E-08 -8.0429 0.10000E+01 0.0000 23 AlO2- 0.22835E-04 -4.6414 0.21333E-04 -4.6709 0.93423E+00 -0.0295 24 CH4,aq 0.26966E-19 -19.5692 0.26958E-19 -19.5693 0.99970E+00 -0.0001 29 CO,aq 0.27088E-18 -18.5672 0.27088E-18 -18.5672 0.10000E+01 0.0000 30 CO2,aq 0.22120E-07 -7.6552 0.22113E-07 -7.6553 0.99970E+00 -0.0001 31 CO3-2 0.12703E-05 -5.8961 0.10228E-05 -5.9902 0.80518E+00 -0.0941 32 CaCO3,aq 0.35065E-09 -9.4551 0.35065E-09 -9.4551 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.82206E-11 -11.0851 0.76828E-11 -11.1145 0.93458E+00 -0.0294 34 CaCl+ 0.61023E-11 -11.2145 0.57031E-11 -11.2439 0.93458E+00 -0.0294 35 CaCl2,aq 0.17465E-15 -15.7578 0.17465E-15 -15.7578 0.10000E+01 0.0000 36 CaOH+ 0.22178E-08 -8.6541 0.20727E-08 -8.6835 0.93458E+00 -0.0294 37 CaSO4,aq 0.17819E-09 -9.7491 0.17819E-09 -9.7491 0.10000E+01 0.0000 38 HCl,aq 0.22205E-13 -13.6536 0.22205E-13 -13.6536 0.10000E+01 0.0000 43 FeCl+ 0.41883E-15 -15.3780 0.39143E-15 -15.4073 0.93458E+00 -0.0294 46 FeO,aq 0.84374E-10 -10.0738 0.84374E-10 -10.0738 0.10000E+01 0.0000 47 FeOH+ 0.71082E-10 -10.1482 0.66432E-10 -10.1776 0.93458E+00 -0.0294 48 HFeO2- 0.10050E-08 -8.9978 0.93907E-09 -9.0273 0.93440E+00 -0.0295 49 FeO+ 0.76779E-14 -14.1148 0.71756E-14 -14.1441 0.93458E+00 -0.0294 51 FeO2- 0.17780E-08 -8.7501 0.16614E-08 -8.7795 0.93440E+00 -0.0295 52 HFeO2,aq 0.19864E-09 -9.7019 0.19864E-09 -9.7019 0.10000E+01 0.0000 53 H2,aq 0.48777E-09 -9.3118 0.48762E-09 -9.3119 0.99970E+00 -0.0001 54 KCl,aq 0.17163E-09 -9.7654 0.17163E-09 -9.7654 0.10000E+01 0.0000 55 KHSO4,aq 0.40078E-17 -17.3971 0.40078E-17 -17.3971 0.10000E+01 0.0000 56 KOH,aq 0.33375E-07 -7.4766 0.33375E-07 -7.4766 0.10000E+01 0.0000 57 KSO4- 0.25041E-07 -7.6013 0.23398E-07 -7.6308 0.93440E+00 -0.0295 58 MgCO3,aq 0.10453E-11 -11.9807 0.10453E-11 -11.9807 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.99904E-13 -13.0004 0.93369E-13 -13.0298 0.93458E+00 -0.0294 60 MgCl+ 0.65780E-13 -13.1819 0.61477E-13 -13.2113 0.93458E+00 -0.0294 61 MgOH+ 0.14596E-09 -9.8358 0.13641E-09 -9.8651 0.93458E+00 -0.0294 63 MnO,aq 0.30209E-09 -9.5199 0.30209E-09 -9.5199 0.10000E+01 0.0000 64 MnOH+ 0.88727E-09 -9.0519 0.82922E-09 -9.0813 0.93458E+00 -0.0294 65 MnO2-2 0.14089E-13 -13.8511 0.11344E-13 -13.9452 0.80518E+00 -0.0941 66 HMnO2- 0.25004E-11 -11.6020 0.23364E-11 -11.6315 0.93440E+00 -0.0295 69 MnCl+ 0.21894E-12 -12.6597 0.20462E-12 -12.6890 0.93458E+00 -0.0294 70 MnSO4,aq 0.15274E-11 -11.8160 0.15274E-11 -11.8160 0.10000E+01 0.0000 71 NaCl,aq 0.54010E-07 -7.2675 0.54010E-07 -7.2675 0.10000E+01 0.0000 72 NaOH,aq 0.57786E-06 -6.2382 0.57786E-06 -6.2382 0.10000E+01 0.0000 74 OH- 0.65787E-03 -3.1819 0.61460E-03 -3.2114 0.93423E+00 -0.0295 79 HPO3-2 0.62261E-17 -17.2058 0.50132E-17 -17.2999 0.80518E+00 -0.0941 81 H2PO3- 0.10114E-19 -19.9951 0.94506E-20 -20.0245 0.93440E+00 -0.0295 82 H3PO4,aq 0.20391E-13 -13.6906 0.20391E-13 -13.6906 0.10000E+01 0.0000 83 H2PO4- 0.61222E-07 -7.2131 0.57211E-07 -7.2425 0.93449E+00 -0.0294 84 PO4-3 0.45403E-08 -8.3429 0.28632E-08 -8.5432 0.63061E+00 -0.2002 87 H2P2O7-2 0.31874E-15 -15.4966 0.25665E-15 -15.5907 0.80518E+00 -0.0941 88 HP2O7-3 0.86871E-13 -13.0611 0.54512E-13 -13.2635 0.62751E+00 -0.2024 89 P2O7-4 0.31199E-13 -13.5059 0.13853E-13 -13.8585 0.44401E+00 -0.3526 90 H2S,aq 0.15038E-15 -15.8228 0.15033E-15 -15.8230 0.99970E+00 -0.0001 97 SO3-2 0.16128E-14 -14.7924 0.13005E-14 -14.8859 0.80637E+00 -0.0935 98 HSO3- 0.81925E-16 -16.0866 0.76550E-16 -16.1161 0.93440E+00 -0.0295 99 HSO4- 0.19894E-10 -10.7013 0.18594E-10 -10.7306 0.93467E+00 -0.0293 Charge balance for all species = 0.4568E-13 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.1005475E-08 -.1300981E-02 -.1311121E+01 0.0000 2 H2O 0.1000000E+01 0.5550840E+02 0.9998561E+06 0.0000 3 Cl- 0.1379462E-03 0.1380004E-03 0.4891821E+01 5.1371 4 SO4-- 0.2548407E-04 0.2550944E-04 0.2450124E+01 13.3659 5 HCO3- 0.1177969E-04 0.1307248E-04 0.7975311E+00 4.0686 6 HS- 0.5537271E-13 -.1250868E-09 -.4136272E-05 -4.2593 7 Al+++ 0.4427697E-24 0.2284393E-04 0.6162743E+00 2.5243 8 H4SiO4 0.5076474E-03 0.1057580E-02 0.1016350E+03 -3.2944 9 Ca++ 0.3397311E-07 0.3707002E-07 0.1485478E-02 10.4905 10 Mg++ 0.4042445E-09 0.5563883E-09 0.1352496E-04 8.5658 11 Fe++ 0.2384832E-11 0.3139525E-08 0.1753077E-03 6.3366 12 K+ 0.7861278E-04 0.7867136E-04 0.3075763E+01 4.8929 13 Na+ 0.1353166E-02 0.1364109E-02 0.3135606E+02 6.1287 14 Mn++ 0.3204187E-09 0.1514033E-08 0.8316592E-04 8.4649 15 HPO4-- 0.4096250E-05 0.4162013E-05 0.3994081E+00 12.5720 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.1586658E-01 -.1300734E-02 -.1456584E-01 0.0000000E+00 2 H2O 0.5549623E+02 0.5549786E+02 -.1632902E-02 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.5208163E-04 0.2550460E-04 0.2657703E-04 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.2657716E-04 -.1250630E-09 -.2657703E-04 0.0000000E+00 7 Al+++ 0.3127051E-02 0.2283959E-04 0.3104212E-02 0.0000000E+00 8 H4SiO4 0.9985859E-02 0.1057379E-02 0.8928480E-02 0.0000000E+00 9 Ca++ 0.1117458E-02 0.3706298E-07 0.1117421E-02 0.0000000E+00 10 Mg++ 0.7611111E-03 0.5562826E-09 0.7611106E-03 0.0000000E+00 11 Fe++ 0.6837752E-03 0.3138929E-08 0.6837721E-03 0.0000000E+00 12 K+ 0.2036093E-03 0.7865642E-04 0.1249529E-03 0.0000000E+00 13 Na+ 0.1363850E-02 0.1363850E-02 0.0000000E+00 0.0000000E+00 14 Mn++ 0.1662771E-04 0.1513745E-08 0.1662620E-04 0.0000000E+00 15 HPO4-- 0.5674956E-05 0.4161222E-05 0.1513734E-05 0.0000000E+00 Chg. balance for solid moles: 0.2724E-17 Mass of aqueous solution: 0.999955E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 0.9590000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) apatite-OH 0.5046E-06 -6.297 0.2535E-03 -3.596 0.2517E-01 0.8054E-04 clinochlore 0.1522E-03 -3.818 0.8461E-01 -1.073 8.403 0.3218E-01 daphnite 0.9423E-04 -4.026 0.6723E-01 -1.172 6.677 0.2037E-01 chlorite-Mn 0.3325E-05 -5.478 0.2357E-02 -2.628 0.2341 0.7513E-03 hematite 0.1063E-03 -3.973 0.1698E-01 -1.770 1.686 0.3218E-02 muscovite 0.1250E-03 -3.903 0.4977E-01 -1.303 4.943 0.1760E-01 stilbite 0.1115E-02 -2.953 0.7857 -0.105 78.03 0.3665 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.6094E+00 0.6094E+00 1.0000 -0.215 daphnite 0.3773E+00 0.3773E+00 1.0000 -0.423 chlorite-Mn 0.1331E-01 0.1331E-01 1.0000 -1.876 hematite 0.1000E+01 0.1000E+01 1.0000 0.000 muscovite 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 1.006894 g Volume = 0.440666 cm3 Porosity: 68.1507% V(tot) - V(min): 0.94293E+00 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.9590000 g log = -0.0182 Original solution: 1000.0103000 g Original solution / Rock added: 1042.76 (Water/Rock Ratio), log = 3.0182 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0203 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.1000E+01 0.9860 0.1006E+01 0.1020E+01 CO2,gas 0.2302E-05 1.0071 0.2366E-05 0.2349E-05 CH4,gas 0.3841E-16 1.0125 0.3968E-16 0.3919E-16 H2,gas 0.6271E-06 1.0005 0.6402E-06 0.6398E-06 H2S,gas 0.4066E-14 0.9960 0.4132E-14 0.4149E-14 S2,gas 0.1533E-35 1.0000 0.1564E-35 0.1564E-35 CO,gas 0.3956E-15 1.0000 0.4037E-15 0.4037E-15 SO3,gas 0.6722E-38 1.0000 0.6858E-38 0.6858E-38 SO2,gas 0.1674E-21 1.0000 0.1708E-21 0.1708E-21 HCl,gas 0.3840E-16 1.0000 0.3918E-16 0.3918E-16 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 32 apatite-OH -18.15 -18.15 0.00 0.000 0.60662E-11 46 clinochlore 39.07 39.07 0.00 0.000 0.12132E-10 47 daphnite 28.97 28.97 0.00 0.000 0.00000E+00 48 chlorite-Mn 46.87 46.87 0.00 0.000 0.24265E-10 90 hematite 12.57 12.57 0.00 0.000 0.90992E-11 120 muscovite 2.58 2.58 0.00 0.000 -0.18198E-10 163 stilbite -7.52 -7.52 0.00 0.000 -0.90992E-11 116 microcline -2.49 -2.47 0.02 0.002 -0.34805E+02 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -13.99 -7.32 -2.442 0.12507E+05 -5.626 3 CH4,gas 4.54 -13.56 -18.10 -4.525 0.30906E+05 -16.401 4 H2,gas 8.00 0.11 -7.89 -4.510 0.13477E+05 -6.194 5 H2S,gas -6.23 -22.31 -16.08 -8.041 0.27461E+05 -14.384 6 S2,gas -7.34 -44.84 -37.50 -5.770 0.64038E+05 -35.806 7 CO,gas 3.21 -13.88 -17.09 -5.259 0.29186E+05 -15.394 8 SO3,gas 17.12 -22.74 -39.86 -9.966 0.68065E+05 -38.164 9 SO2,gas 0.83 -22.63 -23.47 -6.258 0.40068E+05 -21.767 10 HCl,gas 5.19 -12.92 -18.11 -9.053 0.30915E+05 -16.407 11 acmite 7.71 5.82 -1.89 -0.196 0.32216E+04 15 albite-high 0.69 -1.23 -1.92 -0.148 0.32841E+04 16 albite -0.38 -1.23 -0.85 -0.065 0.14453E+04 19 spessartine 24.46 20.56 -3.90 -0.195 0.66545E+04 20 analcite 3.32 2.06 -1.26 -0.140 0.21476E+04 21 andalusite 5.00 1.75 -3.25 -0.325 0.55449E+04 22 andradite 39.01 34.15 -4.85 -0.252 0.82889E+04 26 annite 20.12 16.54 -3.58 -0.199 0.61120E+04 27 phlogopite 27.06 23.23 -3.83 -0.213 0.65454E+04 29 anorthite 12.71 8.95 -3.76 -0.289 0.64204E+04 35 aragonite 0.97 -3.49 -4.46 -1.487 0.76173E+04 36 brucite 12.57 8.57 -4.00 -0.801 0.68346E+04 37 calcite 0.81 -3.49 -4.31 -1.435 0.73531E+04 38 carnegieite-low 9.02 5.36 -3.66 -0.524 0.62575E+04 39 carnegieite-high 10.09 5.36 -4.73 -0.676 0.80845E+04 40 carpholite-Mg 8.58 7.03 -1.56 -0.104 0.26579E+04 41 carpholite-Fe 6.71 4.80 -1.92 -0.128 0.32721E+04 42 celadonite 5.34 2.81 -2.54 -0.149 0.43308E+04 43 celadonite-Fe 3.88 0.58 -3.30 -0.194 0.56354E+04 44 chrysotile 23.89 19.11 -4.78 -0.399 0.81684E+04 50 chloritoid-Mg 13.20 10.32 -2.88 -0.192 0.49138E+04 51 chloritoid-Fe 9.17 8.09 -1.08 -0.072 0.18490E+04 52 chloritoid-Mn 11.40 10.22 -1.18 -0.079 0.20183E+04 54 coesite -2.38 -3.29 -0.92 -0.306 0.15681E+04 59 corundum 8.38 5.05 -3.33 -0.303 0.56937E+04 61 cristobalite -2.56 -3.29 -0.73 -0.245 0.12535E+04 63 cymrite-K 1.69 -2.47 -4.15 -0.346 0.70886E+04 65 diaspore 2.87 2.52 -0.35 -0.058 0.59664E+03 67 diopside 16.18 12.47 -3.71 -0.371 0.63415E+04 68 hedenbergite 14.21 10.24 -3.97 -0.397 0.67787E+04 75 epidote 24.67 22.43 -2.24 -0.109 0.38259E+04 76 clinozoisite 22.81 18.67 -4.14 -0.188 0.70614E+04 77 epidote-Fe 29.84 26.19 -3.65 -0.190 0.62369E+04 78 fayalite 14.05 9.38 -4.67 -0.667 0.79686E+04 83 gibbsite 4.08 2.52 -1.56 -0.222 0.26552E+04 87 greenalite 16.14 12.42 -3.72 -0.310 0.63492E+04 91 heulandite -5.83 -7.52 -1.69 -0.077 0.28938E+04 95 jadeite 4.22 2.06 -2.15 -0.215 0.36731E+04 97 kalsilite 7.58 4.12 -3.46 -0.494 0.59098E+04 98 kaolinite -1.33 -1.54 -0.21 -0.019 0.35441E+03 99 kyanite 4.88 1.75 -3.12 -0.312 0.53308E+04 101 laumontite 2.88 2.36 -0.52 -0.035 0.89156E+03 102 lawsonite 9.62 8.95 -0.67 -0.044 0.11371E+04 103 leucite 4.12 0.83 -3.29 -0.329 0.56185E+04 105 lizardite 23.24 19.11 -4.14 -0.345 0.70610E+04 107 magnetite 20.09 18.90 -1.18 -0.097 0.20226E+04 108 minnesotaite 10.39 5.83 -4.56 -0.268 0.77791E+04 113 margarite 17.32 14.00 -3.32 -0.133 0.56772E+04 121 paragonite 4.24 3.82 -0.42 -0.025 0.71923E+03 122 nepheline 8.34 5.36 -2.98 -0.426 0.50898E+04 136 prehnite 19.37 16.15 -3.23 -0.190 0.55078E+04 137 prehnite-Fe 22.50 19.90 -2.59 -0.156 0.44273E+04 145 pyroxmangite 7.40 5.17 -2.23 -0.446 0.38046E+04 146 pyrophyllite -6.18 -8.13 -1.95 -0.122 0.33354E+04 147 quartz -2.99 -3.29 -0.31 -0.102 0.52078E+03 151 rhodochrosite -0.98 -5.52 -4.54 -1.515 0.77585E+04 152 rhodonite 7.45 5.17 -2.28 -0.455 0.38848E+04 153 sanidine -1.28 -2.47 -1.19 -0.092 0.20329E+04 156 sillimanite 5.26 1.75 -3.51 -0.351 0.59888E+04 164 stilpnomelane-Fe 13.02 12.82 -0.19 -0.006 0.33168E+03 165 stilpnomelane-Mg 27.44 23.97 -3.47 -0.104 0.59300E+04 168 sudoite 21.08 17.35 -3.73 -0.120 0.63723E+04 171 talc 16.49 12.52 -3.97 -0.234 0.67812E+04 174 tephroite 18.09 13.64 -4.45 -0.636 0.75989E+04 177 topaz-H 4.62 1.75 -2.86 -0.260 0.48909E+04 178 tridymite -2.63 -3.29 -0.67 -0.223 0.11408E+04 187 wairakite 3.95 2.36 -1.59 -0.093 0.27135E+04 188 walstromite 11.51 7.20 -4.31 -0.863 0.73647E+04 189 wollastonite 10.46 7.20 -3.27 -0.653 0.55751E+04 190 pseudo-wollastonite 11.00 7.20 -3.80 -0.761 0.64949E+04 191 zoisite 22.85 18.67 -4.18 -0.190 0.71355E+04 192 akaganeite 7.75 6.28 -1.47 -0.318 0.25125E+04 193 beidellite-Ca -1.65 -4.48 -2.83 -0.175 0.48364E+04 194 beidellite-H -2.33 -6.21 -3.88 -0.248 0.66298E+04 195 beidellite-K -1.52 -4.59 -3.07 -0.188 0.52490E+04 196 beidellite-Mg -1.79 -4.80 -3.01 -0.186 0.51325E+04 197 beidellite-Na -1.34 -4.19 -2.84 -0.174 0.48566E+04 199 chalcedony -2.80 -3.29 -0.49 -0.164 0.84008E+03 201 montmorillonite-Ca -2.29 -4.40 -2.11 -0.131 0.36094E+04 202 montmorillonite-K -2.24 -4.52 -2.28 -0.140 0.39001E+04 203 montmorillonite-Mg -2.48 -4.72 -2.24 -0.139 0.38286E+04 204 montmorillonite-Na -2.04 -4.11 -2.08 -0.127 0.35434E+04 205 nontronite-Ca 3.21 3.04 -0.18 -0.011 0.29882E+03 206 nontronite-H 2.53 1.31 -1.22 -0.082 0.20901E+04 207 nontronite-K 3.34 2.92 -0.42 -0.027 0.71274E+03 208 nontronite-Mg 3.07 2.72 -0.35 -0.023 0.60216E+03 209 nontronite-Na 3.52 3.33 -0.19 -0.012 0.32206E+03 224 tobermorite 9.82 5.44 -4.38 -1.195 0.74769E+04 233 boehmite 4.41 2.52 -1.88 -0.314 0.32136E+04 235 ferrous-oxide 9.81 6.34 -3.47 -0.869 0.59334E+04 240 silica-amorphous -2.09 -3.29 -1.20 -0.401 0.20543E+04 242 an20ab80 2.02 0.81 -1.21 -0.093 0.20695E+04 243 an25ab75 2.65 1.31 -1.33 -0.102 0.22725E+04 244 an30ab70 3.28 1.82 -1.46 -0.112 0.24851E+04 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 6 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 0.9590000 Water: Moles liquid = 0.5550E+02 kg liquid = 0.9998E+00 Moles total = 0.5550E+02 kg total = 0.9998E+00 Activity = 1.0000 Stoichiometric ionic strength = .9597790E-03 Osmotic coef. = 0.9820 True ionic strength = .1459323E-02 Chg. balance for total moles = 0.4566E-13 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.10044E-08 -8.9981 0.93910E-09 -9.0273 0.93502E+00 -0.0292 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13795E-03 -3.8603 0.12890E-03 -3.8897 0.93445E+00 -0.0294 4 SO4-- 0.25485E-04 -4.5937 0.20529E-04 -4.6876 0.80554E+00 -0.0939 5 HCO3- 0.11779E-04 -4.9289 0.11008E-04 -4.9583 0.93459E+00 -0.0294 6 HS- 0.53605E-13 -13.2708 0.50092E-13 -13.3002 0.93446E+00 -0.0294 7 Al+++ 0.45164E-24 -24.3452 0.28353E-24 -24.5474 0.62779E+00 -0.2022 8 H4SiO4 0.50307E-03 -3.2984 0.50307E-03 -3.2984 0.10000E+01 0.0000 9 Ca++ 0.34458E-07 -7.4627 0.27737E-07 -7.5569 0.80495E+00 -0.0942 10 Mg++ 0.40172E-09 -9.3961 0.32321E-09 -9.4905 0.80458E+00 -0.0944 11 Fe++ 0.23699E-11 -11.6253 0.19070E-11 -11.7196 0.80467E+00 -0.0944 12 K+ 0.75205E-04 -4.1238 0.70287E-04 -4.1531 0.93461E+00 -0.0294 13 Na+ 0.13532E-02 -2.8686 0.12645E-02 -2.8981 0.93444E+00 -0.0294 14 Mn++ 0.31842E-09 -9.4970 0.25624E-09 -9.5914 0.80473E+00 -0.0943 15 HPO4-- 0.39926E-05 -5.3987 0.32162E-05 -5.4927 0.80555E+00 -0.0939 16 HSiO3- 0.53528E-03 -3.2714 0.50020E-03 -3.3009 0.93445E+00 -0.0294 17 Ca(HSiO3)+ 0.33806E-09 -9.4710 0.31597E-09 -9.5004 0.93463E+00 -0.0294 18 Mg(HSiO3)+ 0.49026E-11 -11.3096 0.45821E-11 -11.3389 0.93463E+00 -0.0294 19 NaHSiO3,aq 0.10230E-04 -4.9901 0.10230E-04 -4.9901 0.10000E+01 0.0000 20 AlO+ 0.46796E-13 -13.3298 0.43737E-13 -13.3591 0.93463E+00 -0.0294 21 AlOH+2 0.25412E-18 -18.5950 0.20452E-18 -18.6893 0.80481E+00 -0.0943 22 HAlO2,aq 0.92750E-08 -8.0327 0.92750E-08 -8.0327 0.10000E+01 0.0000 23 AlO2- 0.23400E-04 -4.6308 0.21862E-04 -4.6603 0.93428E+00 -0.0295 24 CH4,aq 0.26100E-19 -19.5834 0.26092E-19 -19.5835 0.99970E+00 -0.0001 29 CO,aq 0.26846E-18 -18.5711 0.26846E-18 -18.5711 0.10000E+01 0.0000 30 CO2,aq 0.22096E-07 -7.6557 0.22090E-07 -7.6558 0.99970E+00 -0.0001 31 CO3-2 0.12713E-05 -5.8957 0.10239E-05 -5.9898 0.80536E+00 -0.0940 32 CaCO3,aq 0.35610E-09 -9.4484 0.35610E-09 -9.4484 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.83392E-11 -11.0789 0.77941E-11 -11.1082 0.93463E+00 -0.0294 34 CaCl+ 0.61909E-11 -11.2082 0.57862E-11 -11.2376 0.93463E+00 -0.0294 35 CaCl2,aq 0.17720E-15 -15.7515 0.17720E-15 -15.7515 0.10000E+01 0.0000 36 CaOH+ 0.22522E-08 -8.6474 0.21050E-08 -8.6767 0.93463E+00 -0.0294 37 CaSO4,aq 0.18082E-09 -9.7428 0.18082E-09 -9.7428 0.10000E+01 0.0000 38 HCl,aq 0.22183E-13 -13.6540 0.22183E-13 -13.6540 0.10000E+01 0.0000 43 FeCl+ 0.41631E-15 -15.3806 0.38909E-15 -15.4099 0.93463E+00 -0.0294 46 FeO,aq 0.84041E-10 -10.0755 0.84041E-10 -10.0755 0.10000E+01 0.0000 47 FeOH+ 0.70724E-10 -10.1504 0.66100E-10 -10.1798 0.93463E+00 -0.0294 48 HFeO2- 0.10020E-08 -8.9991 0.93635E-09 -9.0286 0.93445E+00 -0.0294 49 FeO+ 0.76694E-14 -14.1152 0.71681E-14 -14.1446 0.93463E+00 -0.0294 51 FeO2- 0.17798E-08 -8.7496 0.16631E-08 -8.7791 0.93445E+00 -0.0294 52 HFeO2,aq 0.19864E-09 -9.7019 0.19864E-09 -9.7019 0.10000E+01 0.0000 53 H2,aq 0.48393E-09 -9.3152 0.48379E-09 -9.3153 0.99970E+00 -0.0001 54 KCl,aq 0.16421E-09 -9.7846 0.16421E-09 -9.7846 0.10000E+01 0.0000 55 KHSO4,aq 0.38313E-17 -17.4167 0.38313E-17 -17.4167 0.10000E+01 0.0000 56 KOH,aq 0.31963E-07 -7.4954 0.31963E-07 -7.4954 0.10000E+01 0.0000 57 KSO4- 0.23962E-07 -7.6205 0.22391E-07 -7.6499 0.93445E+00 -0.0294 58 MgCO3,aq 0.10401E-11 -11.9829 0.10401E-11 -11.9829 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.99294E-13 -13.0031 0.92803E-13 -13.0324 0.93463E+00 -0.0294 60 MgCl+ 0.65384E-13 -13.1845 0.61110E-13 -13.2139 0.93463E+00 -0.0294 61 MgOH+ 0.14522E-09 -9.8380 0.13573E-09 -9.8673 0.93463E+00 -0.0294 63 MnO,aq 0.30090E-09 -9.5216 0.30090E-09 -9.5216 0.10000E+01 0.0000 64 MnOH+ 0.88280E-09 -9.0541 0.82509E-09 -9.0835 0.93463E+00 -0.0294 65 MnO2-2 0.14059E-13 -13.8520 0.11323E-13 -13.9460 0.80536E+00 -0.0940 66 HMnO2- 0.24930E-11 -11.6033 0.23296E-11 -11.6327 0.93445E+00 -0.0294 69 MnCl+ 0.21763E-12 -12.6623 0.20340E-12 -12.6917 0.93463E+00 -0.0294 70 MnSO4,aq 0.15186E-11 -11.8185 0.15186E-11 -11.8185 0.10000E+01 0.0000 71 NaCl,aq 0.54019E-07 -7.2675 0.54019E-07 -7.2675 0.10000E+01 0.0000 72 NaOH,aq 0.57853E-06 -6.2377 0.57853E-06 -6.2377 0.10000E+01 0.0000 74 OH- 0.65852E-03 -3.1814 0.61524E-03 -3.2110 0.93428E+00 -0.0295 79 HPO3-2 0.60208E-17 -17.2203 0.48489E-17 -17.3144 0.80536E+00 -0.0940 82 H3PO4,aq 0.19838E-13 -13.7025 0.19838E-13 -13.7025 0.10000E+01 0.0000 83 H2PO4- 0.59621E-07 -7.2246 0.55718E-07 -7.2540 0.93454E+00 -0.0294 84 PO4-3 0.44289E-08 -8.3537 0.27943E-08 -8.5537 0.63091E+00 -0.2000 87 H2P2O7-2 0.30225E-15 -15.5196 0.24342E-15 -15.6136 0.80536E+00 -0.0940 88 HP2O7-3 0.82440E-13 -13.0839 0.51757E-13 -13.2860 0.62782E+00 -0.2022 89 P2O7-4 0.29628E-13 -13.5283 0.13166E-13 -13.8805 0.44440E+00 -0.3522 90 H2S,aq 0.14543E-15 -15.8373 0.14539E-15 -15.8375 0.99970E+00 -0.0001 97 SO3-2 0.16002E-14 -14.7958 0.12906E-14 -14.8892 0.80654E+00 -0.0934 98 HSO3- 0.81212E-16 -16.0904 0.75888E-16 -16.1198 0.93445E+00 -0.0294 99 HSO4- 0.19877E-10 -10.7016 0.18580E-10 -10.7310 0.93472E+00 -0.0293 Charge balance for all species = 0.4564E-13 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.1004368E-08 -.1299479E-02 -.1309608E+01 0.0000 2 H2O 0.1000000E+01 0.5550841E+02 0.9998571E+06 0.0000 3 Cl- 0.1379462E-03 0.1380004E-03 0.4891824E+01 5.1376 4 SO4-- 0.2548514E-04 0.2550943E-04 0.2450125E+01 13.3669 5 HCO3- 0.1177870E-04 0.1307248E-04 0.7975316E+00 4.0690 6 HS- 0.5360537E-13 -.1262685E-09 -.4175352E-05 -4.2729 7 Al+++ 0.4516364E-24 0.2340955E-04 0.6315340E+00 2.5345 8 H4SiO4 0.5030676E-03 0.1048581E-02 0.1007704E+03 -3.2984 9 Ca++ 0.3445849E-07 0.3760025E-07 0.1506726E-02 10.4976 10 Mg++ 0.4017190E-09 0.5530512E-09 0.1344385E-04 8.5641 11 Fe++ 0.2369934E-11 0.3137616E-08 0.1752013E-03 6.3349 12 K+ 0.7520487E-04 0.7526096E-04 0.2942431E+01 4.8742 13 Na+ 0.1353246E-02 0.1364108E-02 0.3135608E+02 6.1292 14 Mn++ 0.3184171E-09 0.1506352E-08 0.8274408E-04 8.4632 15 HPO4-- 0.3992602E-05 0.4056652E-05 0.3892975E+00 12.5619 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.1586658E-01 -.1299232E-02 -.1456734E-01 0.0000000E+00 2 H2O 0.5549623E+02 0.5549788E+02 -.1653223E-02 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.5208163E-04 0.2550460E-04 0.2657703E-04 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.2657716E-04 -.1262445E-09 -.2657703E-04 0.0000000E+00 7 Al+++ 0.3127051E-02 0.2340511E-04 0.3103646E-02 0.0000000E+00 8 H4SiO4 0.9985859E-02 0.1048383E-02 0.8937476E-02 0.0000000E+00 9 Ca++ 0.1117458E-02 0.3759311E-07 0.1117420E-02 0.0000000E+00 10 Mg++ 0.7611111E-03 0.5529463E-09 0.7611106E-03 0.0000000E+00 11 Fe++ 0.6837752E-03 0.3137020E-08 0.6837721E-03 0.0000000E+00 12 K+ 0.2036093E-03 0.7524668E-04 0.1283627E-03 0.0000000E+00 13 Na+ 0.1363850E-02 0.1363850E-02 0.0000000E+00 0.0000000E+00 14 Mn++ 0.1662771E-04 0.1506066E-08 0.1662621E-04 0.0000000E+00 15 HPO4-- 0.5674956E-05 0.4055882E-05 0.1619074E-05 0.0000000E+00 Chg. balance for solid moles: -.9656E-19 Mass of aqueous solution: 0.999954E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 0.9590000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) apatite-OH 0.5397E-06 -6.268 0.2711E-03 -3.567 0.2691E-01 0.8614E-04 clinochlore 0.1522E-03 -3.818 0.8461E-01 -1.073 8.398 0.3218E-01 daphnite 0.9423E-04 -4.026 0.6723E-01 -1.172 6.673 0.2037E-01 chlorite-Mn 0.3325E-05 -5.478 0.2357E-02 -2.628 0.2340 0.7513E-03 hematite 0.1063E-03 -3.973 0.1698E-01 -1.770 1.685 0.3218E-02 muscovite 0.1231E-03 -3.910 0.4905E-01 -1.309 4.868 0.1734E-01 stilbite 0.1115E-02 -2.953 0.7856 -0.105 77.97 0.3664 microcline 0.5221E-05 -5.282 0.1453E-02 -2.838 0.1442 0.5677E-03 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.6094E+00 0.6094E+00 1.0000 -0.215 daphnite 0.3773E+00 0.3773E+00 1.0000 -0.423 chlorite-Mn 0.1331E-01 0.1331E-01 1.0000 -1.876 hematite 0.1000E+01 0.1000E+01 1.0000 0.000 muscovite 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 1.007519 g Volume = 0.440927 cm3 Porosity: 68.1319% V(tot) - V(min): 0.94267E+00 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.9590000 g log = -0.0182 Original solution: 1000.0103000 g Original solution / Rock added: 1042.76 (Water/Rock Ratio), log = 3.0182 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0203 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.1000E+01 0.9860 0.1006E+01 0.1020E+01 CO2,gas 0.2300E-05 1.0071 0.2363E-05 0.2347E-05 CH4,gas 0.3718E-16 1.0125 0.3841E-16 0.3793E-16 H2,gas 0.6222E-06 1.0005 0.6352E-06 0.6348E-06 H2S,gas 0.3933E-14 0.9960 0.3997E-14 0.4013E-14 S2,gas 0.1457E-35 1.0000 0.1486E-35 0.1486E-35 CO,gas 0.3921E-15 1.0000 0.4001E-15 0.4001E-15 SO3,gas 0.6709E-38 1.0000 0.6846E-38 0.6846E-38 SO2,gas 0.1658E-21 1.0000 0.1692E-21 0.1692E-21 HCl,gas 0.3836E-16 1.0000 0.3914E-16 0.3914E-16 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 32 apatite-OH -18.15 -18.15 0.00 0.000 -0.60662E-11 46 clinochlore 39.07 39.07 0.00 0.000 -0.24265E-10 47 daphnite 28.97 28.97 0.00 0.000 -0.24265E-10 48 chlorite-Mn 46.87 46.87 0.00 0.000 -0.24265E-10 90 hematite 12.57 12.57 0.00 0.000 -0.30331E-11 116 microcline -2.49 -2.49 0.00 0.000 0.15165E-11 120 muscovite 2.58 2.58 0.00 0.000 -0.18198E-10 163 stilbite -7.52 -7.52 0.00 0.000 0.15165E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -13.99 -7.33 -2.442 0.12508E+05 -5.626 3 CH4,gas 4.54 -13.57 -18.11 -4.529 0.30930E+05 -16.416 4 H2,gas 8.00 0.10 -7.90 -4.512 0.13482E+05 -6.197 5 H2S,gas -6.23 -22.33 -16.10 -8.049 0.27486E+05 -14.398 6 S2,gas -7.34 -44.86 -37.53 -5.773 0.64076E+05 -35.828 7 CO,gas 3.21 -13.88 -17.10 -5.261 0.29192E+05 -15.398 8 SO3,gas 17.12 -22.74 -39.86 -9.966 0.68066E+05 -38.165 9 SO2,gas 0.83 -22.64 -23.47 -6.259 0.40076E+05 -21.772 10 HCl,gas 5.19 -12.92 -18.11 -9.053 0.30916E+05 -16.407 11 acmite 7.71 5.82 -1.89 -0.197 0.32342E+04 15 albite-high 0.69 -1.23 -1.92 -0.148 0.32860E+04 16 albite -0.38 -1.23 -0.85 -0.065 0.14472E+04 19 spessartine 24.46 20.56 -3.89 -0.195 0.66487E+04 20 analcite 3.32 2.07 -1.25 -0.139 0.21428E+04 21 andalusite 5.00 1.77 -3.23 -0.323 0.55168E+04 22 andradite 39.01 34.16 -4.84 -0.252 0.82723E+04 26 annite 20.12 16.52 -3.61 -0.200 0.61556E+04 27 phlogopite 27.06 23.21 -3.86 -0.214 0.65890E+04 29 anorthite 12.71 8.97 -3.74 -0.288 0.63868E+04 35 aragonite 0.97 -3.49 -4.45 -1.485 0.76059E+04 36 brucite 12.57 8.56 -4.00 -0.801 0.68376E+04 37 calcite 0.81 -3.49 -4.30 -1.433 0.73416E+04 38 carnegieite-low 9.02 5.37 -3.66 -0.523 0.62459E+04 39 carnegieite-high 10.09 5.37 -4.73 -0.675 0.80729E+04 40 carpholite-Mg 8.58 7.04 -1.55 -0.103 0.26395E+04 41 carpholite-Fe 6.71 4.81 -1.91 -0.127 0.32536E+04 42 celadonite 5.34 2.78 -2.56 -0.151 0.43752E+04 43 celadonite-Fe 3.88 0.55 -3.33 -0.196 0.56798E+04 44 chrysotile 23.89 19.10 -4.80 -0.400 0.81907E+04 50 chloritoid-Mg 13.20 10.33 -2.86 -0.191 0.48886E+04 51 chloritoid-Fe 9.17 8.11 -1.07 -0.071 0.18238E+04 52 chloritoid-Mn 11.40 10.23 -1.17 -0.078 0.19931E+04 54 coesite -2.38 -3.30 -0.92 -0.307 0.15748E+04 59 corundum 8.38 5.07 -3.31 -0.301 0.56589E+04 61 cristobalite -2.56 -3.30 -0.74 -0.246 0.12602E+04 63 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71234E+04 65 diaspore 2.87 2.53 -0.34 -0.057 0.57923E+03 67 diopside 16.18 12.46 -3.72 -0.372 0.63457E+04 68 hedenbergite 14.21 10.24 -3.97 -0.397 0.67829E+04 75 epidote 24.67 22.45 -2.22 -0.108 0.37867E+04 76 clinozoisite 22.81 18.70 -4.10 -0.186 0.70049E+04 77 epidote-Fe 29.84 26.20 -3.64 -0.189 0.62152E+04 78 fayalite 14.05 9.37 -4.67 -0.668 0.79812E+04 83 gibbsite 4.08 2.53 -1.54 -0.221 0.26378E+04 87 greenalite 16.14 12.41 -3.73 -0.311 0.63714E+04 91 heulandite -5.83 -7.52 -1.69 -0.077 0.28938E+04 95 jadeite 4.22 2.07 -2.15 -0.215 0.36682E+04 97 kalsilite 7.58 4.11 -3.47 -0.496 0.59312E+04 98 kaolinite -1.33 -1.53 -0.20 -0.018 0.33305E+03 99 kyanite 4.88 1.77 -3.11 -0.311 0.53027E+04 101 laumontite 2.88 2.37 -0.51 -0.034 0.87140E+03 102 lawsonite 9.62 8.97 -0.65 -0.043 0.11035E+04 103 leucite 4.12 0.81 -3.31 -0.331 0.56466E+04 105 lizardite 23.24 19.10 -4.15 -0.346 0.70833E+04 107 magnetite 20.09 18.90 -1.19 -0.097 0.20255E+04 108 minnesotaite 10.39 5.81 -4.58 -0.269 0.78148E+04 113 margarite 17.32 14.04 -3.28 -0.131 0.56088E+04 121 paragonite 4.24 3.84 -0.40 -0.024 0.68632E+03 122 nepheline 8.34 5.37 -2.97 -0.425 0.50783E+04 136 prehnite 19.37 16.17 -3.20 -0.188 0.54687E+04 137 prehnite-Fe 22.50 19.92 -2.58 -0.155 0.44055E+04 145 pyroxmangite 7.40 5.16 -2.23 -0.447 0.38142E+04 146 pyrophyllite -6.18 -8.12 -1.95 -0.122 0.33275E+04 147 quartz -2.99 -3.30 -0.31 -0.103 0.52750E+03 151 rhodochrosite -0.98 -5.52 -4.55 -1.515 0.77622E+04 152 rhodonite 7.45 5.16 -2.28 -0.456 0.38945E+04 153 sanidine -1.28 -2.49 -1.21 -0.093 0.20677E+04 156 sillimanite 5.26 1.77 -3.49 -0.349 0.59607E+04 164 stilpnomelane-Fe 13.02 12.79 -0.22 -0.007 0.38131E+03 165 stilpnomelane-Mg 27.44 23.94 -3.50 -0.105 0.59797E+04 168 sudoite 21.08 17.37 -3.71 -0.120 0.63287E+04 171 talc 16.49 12.50 -3.99 -0.235 0.68169E+04 174 tephroite 18.09 13.63 -4.46 -0.637 0.76114E+04 177 topaz-H 4.62 1.77 -2.85 -0.259 0.48628E+04 178 tridymite -2.63 -3.30 -0.67 -0.224 0.11475E+04 187 wairakite 3.95 2.37 -1.58 -0.093 0.26934E+04 188 walstromite 11.51 7.20 -4.31 -0.862 0.73591E+04 189 wollastonite 10.46 7.20 -3.26 -0.652 0.55696E+04 190 pseudo-wollastonite 11.00 7.20 -3.80 -0.760 0.64894E+04 191 zoisite 22.85 18.70 -4.15 -0.188 0.70789E+04 192 akaganeite 7.75 6.28 -1.47 -0.318 0.25125E+04 193 beidellite-Ca -1.65 -4.47 -2.82 -0.175 0.48185E+04 194 beidellite-H -2.33 -6.20 -3.87 -0.247 0.66139E+04 195 beidellite-K -1.52 -4.59 -3.07 -0.188 0.52437E+04 196 beidellite-Mg -1.79 -4.79 -3.00 -0.185 0.51171E+04 197 beidellite-Na -1.34 -4.18 -2.83 -0.174 0.48404E+04 199 chalcedony -2.80 -3.30 -0.50 -0.165 0.84680E+03 201 montmorillonite-Ca -2.29 -4.40 -2.11 -0.131 0.36061E+04 202 montmorillonite-K -2.24 -4.53 -2.29 -0.140 0.39094E+04 203 montmorillonite-Mg -2.48 -4.72 -2.24 -0.139 0.38279E+04 204 montmorillonite-Na -2.04 -4.11 -2.07 -0.127 0.35419E+04 205 nontronite-Ca 3.21 3.03 -0.18 -0.012 0.31572E+03 206 nontronite-H 2.53 1.30 -1.24 -0.083 0.21090E+04 207 nontronite-K 3.34 2.91 -0.43 -0.028 0.74224E+03 208 nontronite-Mg 3.07 2.71 -0.36 -0.024 0.62156E+03 209 nontronite-Na 3.52 3.32 -0.20 -0.013 0.34070E+03 224 tobermorite 9.82 5.45 -4.38 -1.194 0.74734E+04 233 boehmite 4.41 2.53 -1.87 -0.312 0.31962E+04 235 ferrous-oxide 9.81 6.33 -3.48 -0.869 0.59363E+04 240 silica-amorphous -2.09 -3.30 -1.21 -0.402 0.20610E+04 242 an20ab80 2.02 0.81 -1.21 -0.093 0.20643E+04 243 an25ab75 2.65 1.32 -1.33 -0.102 0.22655E+04 244 an30ab70 3.28 1.83 -1.45 -0.112 0.24764E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 0.0400000 g Current total amount of reactant added: 0.9590000 g New total amount of reactant added: 0.9990000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.4567E-13 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 6 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 0.9990000 Water: Moles liquid = 0.5550E+02 kg liquid = 0.9998E+00 Moles total = 0.5550E+02 kg total = 0.9998E+00 Activity = 1.0000 Stoichiometric ionic strength = .9879111E-03 Osmotic coef. = 0.9818 True ionic strength = .1505893E-02 Chg. balance for total moles = 0.4567E-13 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.97197E-09 -9.0123 0.90815E-09 -9.0418 0.93434E+00 -0.0295 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13795E-03 -3.8603 0.12881E-03 -3.8901 0.93375E+00 -0.0298 4 SO4-- 0.25486E-04 -4.5937 0.20470E-04 -4.6889 0.80315E+00 -0.0952 5 HCO3- 0.11738E-04 -4.9304 0.10962E-04 -4.9601 0.93389E+00 -0.0297 6 HS- 0.50628E-13 -13.2956 0.47274E-13 -13.3254 0.93376E+00 -0.0298 7 Al+++ 0.41118E-24 -24.3860 0.25641E-24 -24.5911 0.62359E+00 -0.2051 8 H4SiO4 0.50532E-03 -3.2964 0.50532E-03 -3.2964 0.10000E+01 0.0000 9 Ca++ 0.31324E-07 -7.5041 0.25139E-07 -7.5996 0.80255E+00 -0.0955 10 Mg++ 0.37579E-09 -9.4251 0.30145E-09 -9.5208 0.80217E+00 -0.0957 11 Fe++ 0.22170E-11 -11.6542 0.17786E-11 -11.7499 0.80226E+00 -0.0957 12 K+ 0.71810E-04 -4.1438 0.67064E-04 -4.1735 0.93392E+00 -0.0297 13 Na+ 0.14027E-02 -2.8530 0.13097E-02 -2.8828 0.93374E+00 -0.0298 14 Mn++ 0.29786E-09 -9.5260 0.23899E-09 -9.6216 0.80233E+00 -0.0956 15 HPO4-- 0.45115E-05 -5.3457 0.36235E-05 -5.4409 0.80317E+00 -0.0952 16 HSiO3- 0.55643E-03 -3.2546 0.51956E-03 -3.2844 0.93375E+00 -0.0298 17 Ca(HSiO3)+ 0.31850E-09 -9.4969 0.29746E-09 -9.5266 0.93394E+00 -0.0297 18 Mg(HSiO3)+ 0.47530E-11 -11.3230 0.44390E-11 -11.3527 0.93394E+00 -0.0297 19 NaHSiO3,aq 0.11006E-04 -4.9584 0.11006E-04 -4.9584 0.10000E+01 0.0000 20 AlO+ 0.45287E-13 -13.3440 0.42296E-13 -13.3737 0.93394E+00 -0.0297 21 AlOH+2 0.23836E-18 -18.6228 0.19126E-18 -18.7184 0.80241E+00 -0.0956 22 HAlO2,aq 0.92750E-08 -8.0327 0.92750E-08 -8.0327 0.10000E+01 0.0000 23 AlO2- 0.24216E-04 -4.6159 0.22608E-04 -4.6457 0.93357E+00 -0.0299 24 CH4,aq 0.24599E-19 -19.6091 0.24592E-19 -19.6092 0.99969E+00 -0.0001 29 CO,aq 0.25713E-18 -18.5898 0.25713E-18 -18.5898 0.10000E+01 0.0000 30 CO2,aq 0.21278E-07 -7.6721 0.21272E-07 -7.6722 0.99969E+00 -0.0001 31 CO3-2 0.13130E-05 -5.8817 0.10543E-05 -5.9770 0.80298E+00 -0.0953 32 CaCO3,aq 0.33234E-09 -9.4784 0.33234E-09 -9.4784 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.75319E-11 -11.1231 0.70343E-11 -11.1528 0.93394E+00 -0.0297 34 CaCl+ 0.56109E-11 -11.2510 0.52402E-11 -11.2806 0.93394E+00 -0.0297 35 CaCl2,aq 0.16036E-15 -15.7949 0.16036E-15 -15.7949 0.10000E+01 0.0000 36 CaOH+ 0.21124E-08 -8.6752 0.19729E-08 -8.7049 0.93394E+00 -0.0297 37 CaSO4,aq 0.16341E-09 -9.7867 0.16341E-09 -9.7867 0.10000E+01 0.0000 38 HCl,aq 0.21435E-13 -13.6689 0.21435E-13 -13.6689 0.10000E+01 0.0000 43 FeCl+ 0.38827E-15 -15.4109 0.36262E-15 -15.4406 0.93394E+00 -0.0297 46 FeO,aq 0.83816E-10 -10.0767 0.83816E-10 -10.0767 0.10000E+01 0.0000 47 FeOH+ 0.68260E-10 -10.1658 0.63750E-10 -10.1955 0.93394E+00 -0.0297 48 HFeO2- 0.10342E-08 -8.9854 0.96567E-09 -9.0152 0.93375E+00 -0.0298 49 FeO+ 0.74221E-14 -14.1295 0.69318E-14 -14.1592 0.93394E+00 -0.0297 51 FeO2- 0.18418E-08 -8.7347 0.17198E-08 -8.7645 0.93375E+00 -0.0298 52 HFeO2,aq 0.19864E-09 -9.7019 0.19864E-09 -9.7019 0.10000E+01 0.0000 53 H2,aq 0.48134E-09 -9.3175 0.48120E-09 -9.3177 0.99969E+00 -0.0001 54 KCl,aq 0.15656E-09 -9.8053 0.15656E-09 -9.8053 0.10000E+01 0.0000 55 KHSO4,aq 0.35249E-17 -17.4529 0.35249E-17 -17.4529 0.10000E+01 0.0000 56 KOH,aq 0.31537E-07 -7.5012 0.31537E-07 -7.5012 0.10000E+01 0.0000 57 KSO4- 0.22814E-07 -7.6418 0.21302E-07 -7.6716 0.93375E+00 -0.0298 58 MgCO3,aq 0.99891E-12 -12.0005 0.99891E-12 -12.0005 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.92286E-13 -13.0349 0.86190E-13 -13.0645 0.93394E+00 -0.0297 60 MgCl+ 0.60980E-13 -13.2148 0.56951E-13 -13.2445 0.93394E+00 -0.0297 61 MgOH+ 0.14017E-09 -9.8534 0.13091E-09 -9.8830 0.93394E+00 -0.0297 63 MnO,aq 0.30009E-09 -9.5227 0.30009E-09 -9.5227 0.10000E+01 0.0000 64 MnOH+ 0.85205E-09 -9.0695 0.79576E-09 -9.0992 0.93394E+00 -0.0297 65 MnO2-2 0.15039E-13 -13.8228 0.12076E-13 -13.9181 0.80298E+00 -0.0953 66 HMnO2- 0.25730E-11 -11.5896 0.24026E-11 -11.6193 0.93375E+00 -0.0298 69 MnCl+ 0.20297E-12 -12.6926 0.18956E-12 -12.7223 0.93394E+00 -0.0297 70 MnSO4,aq 0.14123E-11 -11.8501 0.14123E-11 -11.8501 0.10000E+01 0.0000 71 NaCl,aq 0.55907E-07 -7.2525 0.55907E-07 -7.2525 0.10000E+01 0.0000 72 NaOH,aq 0.61963E-06 -6.2079 0.61963E-06 -6.2079 0.10000E+01 0.0000 74 OH- 0.68148E-03 -3.1665 0.63621E-03 -3.1964 0.93357E+00 -0.0299 79 HPO3-2 0.67669E-17 -17.1696 0.54337E-17 -17.2649 0.80298E+00 -0.0953 81 H2PO3- 0.10597E-19 -19.9748 0.98954E-20 -20.0046 0.93375E+00 -0.0298 82 H3PO4,aq 0.20901E-13 -13.6798 0.20901E-13 -13.6798 0.10000E+01 0.0000 83 H2PO4- 0.65005E-07 -7.1871 0.60704E-07 -7.2168 0.93384E+00 -0.0297 84 PO4-3 0.51937E-08 -8.2845 0.32554E-08 -8.4874 0.62679E+00 -0.2029 87 H2P2O7-2 0.35984E-15 -15.4439 0.28894E-15 -15.5392 0.80298E+00 -0.0953 88 HP2O7-3 0.10187E-12 -12.9920 0.63530E-13 -13.1970 0.62363E+00 -0.2051 89 P2O7-4 0.38053E-13 -13.4196 0.16712E-13 -13.7770 0.43917E+00 -0.3574 90 H2S,aq 0.13273E-15 -15.8770 0.13269E-15 -15.8772 0.99969E+00 -0.0001 97 SO3-2 0.15917E-14 -14.7982 0.12800E-14 -14.8928 0.80419E+00 -0.0946 98 HSO3- 0.77946E-16 -16.1082 0.72782E-16 -16.1380 0.93375E+00 -0.0298 99 HSO4- 0.19180E-10 -10.7171 0.17915E-10 -10.7468 0.93403E+00 -0.0296 Charge balance for all species = 0.4647E-13 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.9719730E-09 -.1347701E-02 -.1358202E+01 0.0000 2 H2O 0.1000000E+01 0.5550841E+02 0.9998537E+06 0.0000 3 Cl- 0.1379453E-03 0.1380013E-03 0.4891842E+01 5.1518 4 SO4-- 0.2548649E-04 0.2550963E-04 0.2450135E+01 13.3948 5 HCO3- 0.1173794E-04 0.1307257E-04 0.7975345E+00 4.0817 6 HS- 0.5062774E-13 -.1346738E-09 -.4453276E-05 -4.2835 7 Al+++ 0.4111780E-24 0.2422543E-04 0.6535423E+00 2.5345 8 H4SiO4 0.5053234E-03 0.1072757E-02 0.1030933E+03 -3.2964 9 Ca++ 0.3132405E-07 0.3426386E-07 0.1373025E-02 10.4840 10 Mg++ 0.3757898E-09 0.5218609E-09 0.1268562E-04 8.5629 11 Fe++ 0.2216958E-11 0.3228970E-08 0.1803018E-03 6.3338 12 K+ 0.7180988E-04 0.7186439E-04 0.2809628E+01 4.8683 13 Na+ 0.1402656E-02 0.1414338E-02 0.3251056E+02 6.1590 14 Mn++ 0.2978650E-09 0.1454208E-08 0.7987951E-04 8.4621 15 HPO4-- 0.4511509E-05 0.4581708E-05 0.4396831E+00 12.6428 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.1652892E-01 -.1347436E-02 -.1518148E-01 0.0000000E+00 2 H2O 0.5549573E+02 0.5549749E+02 -.1761146E-02 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.5319017E-04 0.2550460E-04 0.2768556E-04 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.2768570E-04 -.1346473E-09 -.2768556E-04 0.0000000E+00 7 Al+++ 0.3257481E-02 0.2422066E-04 0.3233260E-02 0.0000000E+00 8 H4SiO4 0.1040237E-01 0.1072546E-02 0.9329824E-02 0.0000000E+00 9 Ca++ 0.1163464E-02 0.3425712E-07 0.1163429E-02 0.0000000E+00 10 Mg++ 0.7928571E-03 0.5217582E-09 0.7928566E-03 0.0000000E+00 11 Fe++ 0.7122956E-03 0.3228334E-08 0.7122924E-03 0.0000000E+00 12 K+ 0.2121019E-03 0.7185024E-04 0.1402517E-03 0.0000000E+00 13 Na+ 0.1414059E-02 0.1414059E-02 0.0000000E+00 0.0000000E+00 14 Mn++ 0.1732126E-04 0.1453921E-08 0.1731980E-04 0.0000000E+00 15 HPO4-- 0.5911659E-05 0.4580806E-05 0.1330853E-05 0.0000000E+00 Chg. balance for solid moles: -.1689E-17 Mass of aqueous solution: 0.999950E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 0.9990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) apatite-OH 0.4436E-06 -6.353 0.2228E-03 -3.652 0.2120E-01 0.7081E-04 clinochlore 0.1586E-03 -3.800 0.8814E-01 -1.055 8.387 0.3353E-01 daphnite 0.9816E-04 -4.008 0.7004E-01 -1.155 6.665 0.2122E-01 chlorite-Mn 0.3464E-05 -5.460 0.2456E-02 -2.610 0.2337 0.7826E-03 hematite 0.1107E-03 -3.956 0.1769E-01 -1.752 1.683 0.3352E-02 microcline 0.1516E-04 -4.819 0.4218E-02 -2.375 0.4014 0.1648E-02 muscovite 0.1251E-03 -3.903 0.4983E-01 -1.303 4.741 0.1762E-01 stilbite 0.1161E-02 -2.935 0.8183 -0.087 77.87 0.3817 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.6094E+00 0.6094E+00 1.0000 -0.215 daphnite 0.3773E+00 0.3773E+00 1.0000 -0.423 chlorite-Mn 0.1331E-01 0.1331E-01 1.0000 -1.876 hematite 0.1000E+01 0.1000E+01 1.0000 0.000 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 muscovite 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 1.050916 g Volume = 0.459905 cm3 Porosity: 67.1402% V(tot) - V(min): 0.93969E+00 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.9990000 g log = -0.0004 Original solution: 1000.0103000 g Original solution / Rock added: 1001.01 (Water/Rock Ratio), log = 3.0004 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0203 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.1000E+01 0.9860 0.1006E+01 0.1020E+01 CO2,gas 0.2215E-05 1.0071 0.2276E-05 0.2260E-05 CH4,gas 0.3504E-16 1.0125 0.3620E-16 0.3575E-16 H2,gas 0.6189E-06 1.0005 0.6318E-06 0.6314E-06 H2S,gas 0.3589E-14 0.9960 0.3647E-14 0.3662E-14 S2,gas 0.1226E-35 1.0000 0.1251E-35 0.1251E-35 CO,gas 0.3756E-15 1.0000 0.3832E-15 0.3832E-15 SO3,gas 0.6256E-38 1.0000 0.6383E-38 0.6383E-38 SO2,gas 0.1538E-21 1.0000 0.1569E-21 0.1569E-21 HCl,gas 0.3707E-16 1.0000 0.3782E-16 0.3782E-16 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 32 apatite-OH -18.15 -18.15 0.00 0.000 -0.12132E-10 46 clinochlore 39.07 39.07 0.00 0.000 -0.24265E-10 47 daphnite 28.97 28.97 0.00 0.000 0.60662E-11 48 chlorite-Mn 46.87 46.87 0.00 0.000 0.24265E-10 90 hematite 12.57 12.57 0.00 0.000 -0.90992E-11 116 microcline -2.49 -2.49 0.00 0.000 -0.10616E-10 120 muscovite 2.58 2.58 0.00 0.000 -0.18198E-10 163 stilbite -7.52 -7.52 0.00 0.000 -0.33364E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -14.00 -7.34 -2.447 0.12536E+05 -5.643 3 CH4,gas 4.54 -13.60 -18.14 -4.535 0.30974E+05 -16.441 4 H2,gas 8.00 0.10 -7.90 -4.513 0.13486E+05 -6.199 5 H2S,gas -6.23 -22.37 -16.14 -8.068 0.27553E+05 -14.438 6 S2,gas -7.34 -44.94 -37.60 -5.785 0.64204E+05 -35.903 7 CO,gas 3.21 -13.90 -17.12 -5.266 0.29224E+05 -15.417 8 SO3,gas 17.12 -22.77 -39.89 -9.973 0.68118E+05 -38.195 9 SO2,gas 0.83 -22.67 -23.50 -6.268 0.40131E+05 -21.804 10 HCl,gas 5.19 -12.93 -18.12 -9.061 0.30941E+05 -16.422 11 acmite 7.71 5.85 -1.86 -0.193 0.31767E+04 15 albite-high 0.69 -1.20 -1.89 -0.145 0.32252E+04 16 albite -0.38 -1.20 -0.81 -0.062 0.13864E+04 19 spessartine 24.46 20.57 -3.89 -0.195 0.66447E+04 20 analcite 3.32 2.10 -1.22 -0.136 0.20852E+04 21 andalusite 5.00 1.77 -3.23 -0.323 0.55135E+04 22 andradite 39.01 34.13 -4.88 -0.253 0.83320E+04 26 annite 20.12 16.51 -3.61 -0.200 0.61616E+04 27 phlogopite 27.06 23.20 -3.86 -0.215 0.65949E+04 29 anorthite 12.71 8.96 -3.75 -0.288 0.64034E+04 35 aragonite 0.97 -3.52 -4.48 -1.495 0.76571E+04 36 brucite 12.57 8.56 -4.01 -0.801 0.68396E+04 37 calcite 0.81 -3.52 -4.33 -1.443 0.73928E+04 38 carnegieite-low 9.02 5.40 -3.63 -0.518 0.61917E+04 39 carnegieite-high 10.09 5.40 -4.70 -0.671 0.80187E+04 40 carpholite-Mg 8.58 7.04 -1.54 -0.103 0.26348E+04 41 carpholite-Fe 6.71 4.81 -1.90 -0.127 0.32490E+04 42 celadonite 5.34 2.78 -2.56 -0.151 0.43739E+04 43 celadonite-Fe 3.88 0.55 -3.33 -0.196 0.56785E+04 44 chrysotile 23.89 19.10 -4.80 -0.400 0.81900E+04 50 chloritoid-Mg 13.20 10.34 -2.86 -0.191 0.48873E+04 51 chloritoid-Fe 9.17 8.11 -1.07 -0.071 0.18225E+04 52 chloritoid-Mn 11.40 10.23 -1.17 -0.078 0.19918E+04 54 coesite -2.38 -3.30 -0.92 -0.307 0.15715E+04 59 corundum 8.38 5.07 -3.31 -0.301 0.56589E+04 61 cristobalite -2.56 -3.30 -0.74 -0.245 0.12569E+04 63 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71234E+04 65 diaspore 2.87 2.53 -0.34 -0.057 0.57923E+03 67 diopside 16.18 12.45 -3.73 -0.373 0.63642E+04 68 hedenbergite 14.21 10.22 -3.98 -0.398 0.68014E+04 75 epidote 24.67 22.43 -2.24 -0.109 0.38232E+04 76 clinozoisite 22.81 18.68 -4.12 -0.187 0.70414E+04 77 epidote-Fe 29.84 26.18 -3.66 -0.190 0.62517E+04 78 fayalite 14.05 9.37 -4.67 -0.668 0.79818E+04 83 gibbsite 4.08 2.53 -1.54 -0.221 0.26378E+04 87 greenalite 16.14 12.41 -3.73 -0.311 0.63707E+04 91 heulandite -5.83 -7.52 -1.69 -0.077 0.28938E+04 95 jadeite 4.22 2.10 -2.11 -0.211 0.36107E+04 97 kalsilite 7.58 4.11 -3.48 -0.497 0.59378E+04 98 kaolinite -1.33 -1.52 -0.19 -0.017 0.32641E+03 99 kyanite 4.88 1.77 -3.10 -0.310 0.52994E+04 101 laumontite 2.88 2.37 -0.52 -0.034 0.88135E+03 102 lawsonite 9.62 8.96 -0.66 -0.044 0.11201E+04 103 leucite 4.12 0.81 -3.31 -0.331 0.56499E+04 105 lizardite 23.24 19.10 -4.15 -0.346 0.70826E+04 107 magnetite 20.09 18.90 -1.19 -0.097 0.20275E+04 108 minnesotaite 10.39 5.82 -4.57 -0.269 0.78075E+04 113 margarite 17.32 14.03 -3.29 -0.132 0.56254E+04 121 paragonite 4.24 3.87 -0.37 -0.022 0.62547E+03 122 nepheline 8.34 5.40 -2.94 -0.420 0.50241E+04 136 prehnite 19.37 16.15 -3.22 -0.190 0.55052E+04 137 prehnite-Fe 22.50 19.90 -2.60 -0.156 0.44420E+04 145 pyroxmangite 7.40 5.17 -2.23 -0.447 0.38129E+04 146 pyrophyllite -6.18 -8.12 -1.94 -0.121 0.33142E+04 147 quartz -2.99 -3.30 -0.31 -0.102 0.52419E+03 151 rhodochrosite -0.98 -5.54 -4.56 -1.521 0.77922E+04 152 rhodonite 7.45 5.17 -2.28 -0.456 0.38931E+04 153 sanidine -1.28 -2.49 -1.21 -0.093 0.20677E+04 156 sillimanite 5.26 1.77 -3.49 -0.349 0.59574E+04 164 stilpnomelane-Fe 13.02 12.80 -0.22 -0.006 0.36970E+03 165 stilpnomelane-Mg 27.44 23.95 -3.50 -0.104 0.59681E+04 168 sudoite 21.08 17.37 -3.70 -0.119 0.63228E+04 171 talc 16.49 12.50 -3.99 -0.235 0.68096E+04 174 tephroite 18.09 13.63 -4.46 -0.637 0.76121E+04 177 topaz-H 4.62 1.77 -2.85 -0.259 0.48595E+04 178 tridymite -2.63 -3.30 -0.67 -0.223 0.11442E+04 187 wairakite 3.95 2.37 -1.58 -0.093 0.27033E+04 188 walstromite 11.51 7.19 -4.32 -0.864 0.73790E+04 189 wollastonite 10.46 7.19 -3.27 -0.655 0.55895E+04 190 pseudo-wollastonite 11.00 7.19 -3.81 -0.762 0.65093E+04 191 zoisite 22.85 18.68 -4.17 -0.189 0.71154E+04 192 akaganeite 7.75 6.28 -1.47 -0.318 0.25125E+04 193 beidellite-Ca -1.65 -4.46 -2.82 -0.174 0.48102E+04 194 beidellite-H -2.33 -6.19 -3.87 -0.247 0.66017E+04 195 beidellite-K -1.52 -4.59 -3.07 -0.188 0.52348E+04 196 beidellite-Mg -1.79 -4.78 -2.99 -0.185 0.51052E+04 197 beidellite-Na -1.34 -4.16 -2.82 -0.173 0.48115E+04 199 chalcedony -2.80 -3.30 -0.49 -0.165 0.84348E+03 201 montmorillonite-Ca -2.29 -4.40 -2.11 -0.130 0.35974E+04 202 montmorillonite-K -2.24 -4.52 -2.28 -0.140 0.39001E+04 203 montmorillonite-Mg -2.48 -4.71 -2.23 -0.138 0.38156E+04 204 montmorillonite-Na -2.04 -4.09 -2.06 -0.126 0.35125E+04 205 nontronite-Ca 3.21 3.03 -0.18 -0.012 0.30738E+03 206 nontronite-H 2.53 1.30 -1.23 -0.082 0.20969E+04 207 nontronite-K 3.34 2.91 -0.43 -0.028 0.73335E+03 208 nontronite-Mg 3.07 2.72 -0.36 -0.023 0.60972E+03 209 nontronite-Na 3.52 3.34 -0.18 -0.012 0.31173E+03 224 tobermorite 9.82 5.44 -4.39 -1.197 0.74895E+04 233 boehmite 4.41 2.53 -1.87 -0.312 0.31962E+04 235 ferrous-oxide 9.81 6.33 -3.48 -0.869 0.59383E+04 240 silica-amorphous -2.09 -3.30 -1.21 -0.402 0.20577E+04 242 an20ab80 2.02 0.84 -1.18 -0.091 0.20189E+04 243 an25ab75 2.65 1.34 -1.30 -0.100 0.22240E+04 244 an30ab70 3.28 1.85 -1.43 -0.110 0.24388E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 0.0400000 g Current total amount of reactant added: 0.9990000 g New total amount of reactant added: 1.0390000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.4567E-13 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 6 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 1.0390000 Water: Moles liquid = 0.5550E+02 kg liquid = 0.9998E+00 Moles total = 0.5550E+02 kg total = 0.9998E+00 Activity = 1.0000 Stoichiometric ionic strength = .1016269E-02 Osmotic coef. = 0.9815 True ionic strength = .1552731E-02 Chg. balance for total moles = 0.4567E-13 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.94170E-09 -9.0261 0.87922E-09 -9.0559 0.93366E+00 -0.0298 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13794E-03 -3.8603 0.12871E-03 -3.8904 0.93306E+00 -0.0301 4 SO4-- 0.25488E-04 -4.5937 0.20411E-04 -4.6901 0.80081E+00 -0.0965 5 HCO3- 0.11697E-04 -4.9319 0.10916E-04 -4.9619 0.93320E+00 -0.0300 6 HS- 0.47887E-13 -13.3198 0.44682E-13 -13.3499 0.93307E+00 -0.0301 7 Al+++ 0.37561E-24 -24.4253 0.23268E-24 -24.6332 0.61948E+00 -0.2080 8 H4SiO4 0.50755E-03 -3.2945 0.50755E-03 -3.2945 0.10000E+01 0.0000 9 Ca++ 0.28553E-07 -7.5444 0.22848E-07 -7.6412 0.80019E+00 -0.0968 10 Mg++ 0.35234E-09 -9.4530 0.28181E-09 -9.5501 0.79980E+00 -0.0970 11 Fe++ 0.20786E-11 -11.6822 0.16627E-11 -11.7792 0.79989E+00 -0.0970 12 K+ 0.68660E-04 -4.1633 0.64076E-04 -4.1933 0.93323E+00 -0.0300 13 Na+ 0.14520E-02 -2.8380 0.13548E-02 -2.8681 0.93304E+00 -0.0301 14 Mn++ 0.27928E-09 -9.5540 0.22342E-09 -9.6509 0.79996E+00 -0.0969 15 HPO4-- 0.50820E-05 -5.2940 0.40697E-05 -5.3904 0.80082E+00 -0.0965 16 HSiO3- 0.57770E-03 -3.2383 0.53903E-03 -3.2684 0.93306E+00 -0.0301 17 Ca(HSiO3)+ 0.30053E-09 -9.5221 0.28047E-09 -9.5521 0.93325E+00 -0.0300 18 Mg(HSiO3)+ 0.46131E-11 -11.3360 0.43052E-11 -11.3660 0.93325E+00 -0.0300 19 NaHSiO3,aq 0.11811E-04 -4.9277 0.11811E-04 -4.9277 0.10000E+01 0.0000 20 AlO+ 0.43877E-13 -13.3578 0.40948E-13 -13.3878 0.93325E+00 -0.0300 21 AlOH+2 0.22408E-18 -18.6496 0.17927E-18 -18.7465 0.80005E+00 -0.0969 22 HAlO2,aq 0.92750E-08 -8.0327 0.92750E-08 -8.0327 0.10000E+01 0.0000 23 AlO2- 0.25032E-04 -4.6015 0.23351E-04 -4.6317 0.93288E+00 -0.0302 24 CH4,aq 0.23220E-19 -19.6341 0.23213E-19 -19.6343 0.99969E+00 -0.0001 29 CO,aq 0.24659E-18 -18.6080 0.24659E-18 -18.6080 0.10000E+01 0.0000 30 CO2,aq 0.20514E-07 -7.6879 0.20508E-07 -7.6881 0.99969E+00 -0.0001 31 CO3-2 0.13545E-05 -5.8682 0.10844E-05 -5.9648 0.80063E+00 -0.0966 32 CaCO3,aq 0.31068E-09 -9.5077 0.31068E-09 -9.5077 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.68216E-11 -11.1661 0.63663E-11 -11.1961 0.93325E+00 -0.0300 34 CaCl+ 0.50994E-11 -11.2925 0.47590E-11 -11.3225 0.93325E+00 -0.0300 35 CaCl2,aq 0.14552E-15 -15.8371 0.14552E-15 -15.8371 0.10000E+01 0.0000 36 CaOH+ 0.19845E-08 -8.7024 0.18520E-08 -8.7324 0.93325E+00 -0.0300 37 CaSO4,aq 0.14808E-09 -9.8295 0.14808E-09 -9.8295 0.10000E+01 0.0000 38 HCl,aq 0.20737E-13 -13.6833 0.20737E-13 -13.6833 0.10000E+01 0.0000 43 FeCl+ 0.36296E-15 -15.4401 0.33873E-15 -15.4701 0.93325E+00 -0.0300 46 FeO,aq 0.83594E-10 -10.0778 0.83594E-10 -10.0778 0.10000E+01 0.0000 47 FeOH+ 0.65960E-10 -10.1807 0.61557E-10 -10.2107 0.93325E+00 -0.0300 48 HFeO2- 0.10662E-08 -8.9722 0.99481E-09 -9.0023 0.93306E+00 -0.0301 49 FeO+ 0.71910E-14 -14.1432 0.67110E-14 -14.1732 0.93325E+00 -0.0300 51 FeO2- 0.19038E-08 -8.7204 0.17764E-08 -8.7505 0.93306E+00 -0.0301 52 HFeO2,aq 0.19864E-09 -9.7019 0.19864E-09 -9.7019 0.10000E+01 0.0000 53 H2,aq 0.47881E-09 -9.3198 0.47866E-09 -9.3200 0.99969E+00 -0.0001 54 KCl,aq 0.14947E-09 -9.8254 0.14947E-09 -9.8254 0.10000E+01 0.0000 55 KHSO4,aq 0.32512E-17 -17.4880 0.32512E-17 -17.4880 0.10000E+01 0.0000 56 KOH,aq 0.31123E-07 -7.5069 0.31123E-07 -7.5069 0.10000E+01 0.0000 57 KSO4- 0.21750E-07 -7.6625 0.20294E-07 -7.6926 0.93306E+00 -0.0301 58 MgCO3,aq 0.96049E-12 -12.0175 0.96049E-12 -12.0175 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.85974E-13 -13.0656 0.80236E-13 -13.0956 0.93325E+00 -0.0300 60 MgCl+ 0.57006E-13 -13.2441 0.53201E-13 -13.2741 0.93325E+00 -0.0300 61 MgOH+ 0.13544E-09 -9.8682 0.12640E-09 -9.8982 0.93325E+00 -0.0300 63 MnO,aq 0.29930E-09 -9.5239 0.29930E-09 -9.5239 0.10000E+01 0.0000 64 MnOH+ 0.82334E-09 -9.0844 0.76838E-09 -9.1144 0.93325E+00 -0.0300 65 MnO2-2 0.16049E-13 -13.7946 0.12849E-13 -13.8911 0.80063E+00 -0.0966 66 HMnO2- 0.26527E-11 -11.5763 0.24751E-11 -11.6064 0.93306E+00 -0.0301 69 MnCl+ 0.18974E-12 -12.7218 0.17708E-12 -12.7518 0.93325E+00 -0.0300 70 MnSO4,aq 0.13165E-11 -11.8806 0.13165E-11 -11.8806 0.10000E+01 0.0000 71 NaCl,aq 0.57789E-07 -7.2382 0.57789E-07 -7.2382 0.10000E+01 0.0000 72 NaOH,aq 0.66205E-06 -6.1791 0.66205E-06 -6.1791 0.10000E+01 0.0000 74 OH- 0.70442E-03 -3.1522 0.65714E-03 -3.1823 0.93288E+00 -0.0302 79 HPO3-2 0.75824E-17 -17.1202 0.60707E-17 -17.2168 0.80063E+00 -0.0966 81 H2PO3- 0.11471E-19 -19.9404 0.10703E-19 -19.9705 0.93306E+00 -0.0301 82 H3PO4,aq 0.22003E-13 -13.6575 0.22003E-13 -13.6575 0.10000E+01 0.0000 83 H2PO4- 0.70737E-07 -7.1504 0.66008E-07 -7.1804 0.93315E+00 -0.0300 84 PO4-3 0.60644E-08 -8.2172 0.37766E-08 -8.4229 0.62275E+00 -0.2057 87 H2P2O7-2 0.42672E-15 -15.3699 0.34164E-15 -15.4664 0.80063E+00 -0.0966 88 HP2O7-3 0.12524E-12 -12.9023 0.77589E-13 -13.1102 0.61951E+00 -0.2079 89 P2O7-4 0.48568E-13 -13.3136 0.21082E-13 -13.6761 0.43407E+00 -0.3624 90 H2S,aq 0.12145E-15 -15.9156 0.12142E-15 -15.9157 0.99969E+00 -0.0001 97 SO3-2 0.15833E-14 -14.8004 0.12696E-14 -14.8963 0.80187E+00 -0.0959 98 HSO3- 0.74905E-16 -16.1255 0.69891E-16 -16.1556 0.93306E+00 -0.0301 99 HSO4- 0.18530E-10 -10.7321 0.17295E-10 -10.7621 0.93334E+00 -0.0300 Charge balance for all species = 0.4646E-13 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.9416958E-09 -.1396065E-02 -.1406938E+01 0.0000 2 H2O 0.1000000E+01 0.5550842E+02 0.9998503E+06 0.0000 3 Cl- 0.1379444E-03 0.1380023E-03 0.4891860E+01 5.1655 4 SO4-- 0.2548775E-04 0.2550982E-04 0.2450145E+01 13.4217 5 HCO3- 0.1169734E-04 0.1307267E-04 0.7975375E+00 4.0940 6 HS- 0.4788707E-13 -.1430606E-09 -.4730589E-05 -4.2940 7 Al+++ 0.3756066E-24 0.2504079E-04 0.6755364E+00 2.5345 8 H4SiO4 0.5075548E-03 0.1097066E-02 0.1054290E+03 -3.2945 9 Ca++ 0.2855275E-07 0.3130844E-07 0.1254591E-02 10.4706 10 Mg++ 0.3523447E-09 0.4935041E-09 0.1199627E-04 8.5618 11 Fe++ 0.2078638E-11 0.3320307E-08 0.1854013E-03 6.3326 12 K+ 0.6866029E-04 0.6871331E-04 0.2686424E+01 4.8626 13 Na+ 0.1452037E-02 0.1464568E-02 0.3366506E+02 6.1878 14 Mn++ 0.2792815E-09 0.1406099E-08 0.7723665E-04 8.4609 15 HPO4-- 0.5081974E-05 0.5158776E-05 0.4950597E+00 12.7214 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.1719126E-01 -.1395780E-02 -.1579548E-01 0.0000000E+00 2 H2O 0.5549523E+02 0.5549709E+02 -.1868216E-02 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.5429870E-04 0.2550461E-04 0.2879409E-04 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.2879423E-04 -.1430314E-09 -.2879409E-04 0.0000000E+00 7 Al+++ 0.3387911E-02 0.2503568E-04 0.3362875E-02 0.0000000E+00 8 H4SiO4 0.1081888E-01 0.1096842E-02 0.9722040E-02 0.0000000E+00 9 Ca++ 0.1209469E-02 0.3130206E-07 0.1209438E-02 0.0000000E+00 10 Mg++ 0.8246032E-03 0.4934034E-09 0.8246027E-03 0.0000000E+00 11 Fe++ 0.7408159E-03 0.3319630E-08 0.7408126E-03 0.0000000E+00 12 K+ 0.2205945E-03 0.6869929E-04 0.1518952E-03 0.0000000E+00 13 Na+ 0.1464269E-02 0.1464269E-02 0.0000000E+00 0.0000000E+00 14 Mn++ 0.1801480E-04 0.1405812E-08 0.1801340E-04 0.0000000E+00 15 HPO4-- 0.6148362E-05 0.5157724E-05 0.9906380E-06 0.0000000E+00 Chg. balance for solid moles: -.1859E-17 Mass of aqueous solution: 0.999946E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 1.0390000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) apatite-OH 0.3302E-06 -6.481 0.1659E-03 -3.780 0.1516E-01 0.5271E-04 clinochlore 0.1649E-03 -3.783 0.9167E-01 -1.038 8.377 0.3487E-01 daphnite 0.1021E-03 -3.991 0.7284E-01 -1.138 6.657 0.2207E-01 chlorite-Mn 0.3603E-05 -5.443 0.2554E-02 -2.593 0.2334 0.8140E-03 hematite 0.1152E-03 -3.939 0.1839E-01 -1.735 1.681 0.3486E-02 microcline 0.2481E-04 -4.605 0.6905E-02 -2.161 0.6310 0.2697E-02 muscovite 0.1271E-03 -3.896 0.5062E-01 -1.296 4.626 0.1790E-01 stilbite 0.1208E-02 -2.918 0.8512 -0.070 77.78 0.3970 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.6094E+00 0.6094E+00 1.0000 -0.215 daphnite 0.3773E+00 0.3773E+00 1.0000 -0.423 chlorite-Mn 0.1331E-01 0.1331E-01 1.0000 -1.876 hematite 0.1000E+01 0.1000E+01 1.0000 0.000 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 muscovite 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 1.094302 g Volume = 0.478884 cm3 Porosity: 66.1710% V(tot) - V(min): 0.93672E+00 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 1.0390000 g log = 0.0166 Original solution: 1000.0103000 g Original solution / Rock added: 962.47 (Water/Rock Ratio), log = 2.9834 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0203 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.1000E+01 0.9860 0.1006E+01 0.1020E+01 CO2,gas 0.2135E-05 1.0071 0.2194E-05 0.2179E-05 CH4,gas 0.3307E-16 1.0125 0.3417E-16 0.3374E-16 H2,gas 0.6156E-06 1.0005 0.6284E-06 0.6281E-06 H2S,gas 0.3284E-14 0.9960 0.3338E-14 0.3351E-14 S2,gas 0.1038E-35 1.0000 0.1059E-35 0.1059E-35 CO,gas 0.3602E-15 1.0000 0.3675E-15 0.3675E-15 SO3,gas 0.5847E-38 1.0000 0.5966E-38 0.5966E-38 SO2,gas 0.1430E-21 1.0000 0.1459E-21 0.1459E-21 HCl,gas 0.3586E-16 1.0000 0.3659E-16 0.3659E-16 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 32 apatite-OH -18.15 -18.15 0.00 0.000 0.00000E+00 46 clinochlore 39.07 39.07 0.00 0.000 -0.36397E-10 47 daphnite 28.97 28.97 0.00 0.000 -0.36397E-10 48 chlorite-Mn 46.87 46.87 0.00 0.000 -0.36397E-10 90 hematite 12.57 12.57 0.00 0.000 0.90992E-11 116 microcline -2.49 -2.49 0.00 0.000 -0.10616E-10 120 muscovite 2.58 2.58 0.00 0.000 0.60662E-11 163 stilbite -7.52 -7.52 0.00 0.000 -0.90992E-11 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -14.02 -7.36 -2.453 0.12563E+05 -5.659 3 CH4,gas 4.54 -13.62 -18.17 -4.541 0.31017E+05 -16.466 4 H2,gas 8.00 0.10 -7.90 -4.515 0.13490E+05 -6.202 5 H2S,gas -6.23 -22.41 -16.18 -8.088 0.27619E+05 -14.477 6 S2,gas -7.34 -45.01 -37.67 -5.796 0.64328E+05 -35.975 7 CO,gas 3.21 -13.92 -17.13 -5.272 0.29255E+05 -15.435 8 SO3,gas 17.12 -22.80 -39.92 -9.981 0.68168E+05 -38.224 9 SO2,gas 0.83 -22.70 -23.54 -6.276 0.40185E+05 -21.836 10 HCl,gas 5.19 -12.95 -18.14 -9.068 0.30966E+05 -16.437 11 acmite 7.71 5.88 -1.83 -0.190 0.31210E+04 15 albite-high 0.69 -1.16 -1.85 -0.143 0.31663E+04 16 albite -0.38 -1.16 -0.78 -0.060 0.13275E+04 19 spessartine 24.46 20.57 -3.89 -0.194 0.66407E+04 20 analcite 3.32 2.13 -1.19 -0.132 0.20296E+04 21 andalusite 5.00 1.77 -3.23 -0.323 0.55102E+04 22 andradite 39.01 34.09 -4.91 -0.255 0.83908E+04 26 annite 20.12 16.51 -3.61 -0.201 0.61675E+04 27 phlogopite 27.06 23.20 -3.87 -0.215 0.66008E+04 29 anorthite 12.71 8.95 -3.76 -0.289 0.64197E+04 35 aragonite 0.97 -3.55 -4.51 -1.505 0.77070E+04 36 brucite 12.57 8.56 -4.01 -0.801 0.68415E+04 37 calcite 0.81 -3.55 -4.36 -1.453 0.74428E+04 38 carnegieite-low 9.02 5.43 -3.60 -0.514 0.61393E+04 39 carnegieite-high 10.09 5.43 -4.67 -0.667 0.79663E+04 40 carpholite-Mg 8.58 7.04 -1.54 -0.103 0.26303E+04 41 carpholite-Fe 6.71 4.81 -1.90 -0.127 0.32444E+04 42 celadonite 5.34 2.78 -2.56 -0.151 0.43726E+04 43 celadonite-Fe 3.88 0.55 -3.32 -0.196 0.56772E+04 44 chrysotile 23.89 19.10 -4.80 -0.400 0.81893E+04 50 chloritoid-Mg 13.20 10.34 -2.86 -0.191 0.48860E+04 51 chloritoid-Fe 9.17 8.11 -1.07 -0.071 0.18212E+04 52 chloritoid-Mn 11.40 10.24 -1.17 -0.078 0.19905E+04 54 coesite -2.38 -3.29 -0.92 -0.306 0.15682E+04 59 corundum 8.38 5.07 -3.31 -0.301 0.56589E+04 61 cristobalite -2.56 -3.29 -0.73 -0.245 0.12536E+04 63 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71234E+04 65 diaspore 2.87 2.53 -0.34 -0.057 0.57923E+03 67 diopside 16.18 12.44 -3.74 -0.374 0.63825E+04 68 hedenbergite 14.21 10.21 -3.99 -0.399 0.68197E+04 75 epidote 24.67 22.41 -2.26 -0.110 0.38592E+04 76 clinozoisite 22.81 18.66 -4.14 -0.188 0.70773E+04 77 epidote-Fe 29.84 26.16 -3.68 -0.191 0.62876E+04 78 fayalite 14.05 9.37 -4.68 -0.668 0.79825E+04 83 gibbsite 4.08 2.53 -1.54 -0.221 0.26378E+04 87 greenalite 16.14 12.41 -3.73 -0.311 0.63701E+04 91 heulandite -5.83 -7.52 -1.69 -0.077 0.28938E+04 95 jadeite 4.22 2.13 -2.08 -0.208 0.35551E+04 97 kalsilite 7.58 4.10 -3.48 -0.497 0.59443E+04 98 kaolinite -1.33 -1.52 -0.19 -0.017 0.31988E+03 99 kyanite 4.88 1.77 -3.10 -0.310 0.52961E+04 101 laumontite 2.88 2.36 -0.52 -0.035 0.89115E+03 102 lawsonite 9.62 8.95 -0.67 -0.044 0.11364E+04 103 leucite 4.12 0.81 -3.31 -0.331 0.56532E+04 105 lizardite 23.24 19.10 -4.15 -0.346 0.70820E+04 107 magnetite 20.09 18.90 -1.19 -0.097 0.20295E+04 108 minnesotaite 10.39 5.82 -4.57 -0.269 0.78003E+04 113 margarite 17.32 14.02 -3.30 -0.132 0.56418E+04 121 paragonite 4.24 3.91 -0.33 -0.020 0.56656E+03 122 nepheline 8.34 5.43 -2.91 -0.416 0.49717E+04 136 prehnite 19.37 16.13 -3.25 -0.191 0.55411E+04 137 prehnite-Fe 22.50 19.88 -2.62 -0.158 0.44780E+04 145 pyroxmangite 7.40 5.17 -2.23 -0.446 0.38116E+04 146 pyrophyllite -6.18 -8.11 -1.93 -0.121 0.33011E+04 147 quartz -2.99 -3.29 -0.31 -0.102 0.52092E+03 151 rhodochrosite -0.98 -5.56 -4.58 -1.527 0.78213E+04 152 rhodonite 7.45 5.17 -2.28 -0.456 0.38918E+04 153 sanidine -1.28 -2.49 -1.21 -0.093 0.20677E+04 156 sillimanite 5.26 1.77 -3.49 -0.349 0.59542E+04 164 stilpnomelane-Fe 13.02 12.81 -0.21 -0.006 0.35826E+03 165 stilpnomelane-Mg 27.44 23.95 -3.49 -0.104 0.59566E+04 168 sudoite 21.08 17.38 -3.70 -0.119 0.63169E+04 171 talc 16.49 12.51 -3.98 -0.234 0.68024E+04 174 tephroite 18.09 13.63 -4.46 -0.637 0.76127E+04 177 topaz-H 4.62 1.77 -2.84 -0.259 0.48562E+04 178 tridymite -2.63 -3.29 -0.67 -0.223 0.11409E+04 187 wairakite 3.95 2.36 -1.59 -0.093 0.27131E+04 188 walstromite 11.51 7.18 -4.33 -0.867 0.73987E+04 189 wollastonite 10.46 7.18 -3.29 -0.657 0.56091E+04 190 pseudo-wollastonite 11.00 7.18 -3.82 -0.765 0.65289E+04 191 zoisite 22.85 18.66 -4.19 -0.190 0.71514E+04 192 akaganeite 7.75 6.28 -1.47 -0.318 0.25125E+04 193 beidellite-Ca -1.65 -4.46 -2.81 -0.174 0.48020E+04 194 beidellite-H -2.33 -6.19 -3.86 -0.246 0.65897E+04 195 beidellite-K -1.52 -4.58 -3.06 -0.187 0.52260E+04 196 beidellite-Mg -1.79 -4.77 -2.98 -0.185 0.50936E+04 197 beidellite-Na -1.34 -4.14 -2.80 -0.172 0.47833E+04 199 chalcedony -2.80 -3.29 -0.49 -0.164 0.84022E+03 201 montmorillonite-Ca -2.29 -4.39 -2.10 -0.130 0.35887E+04 202 montmorillonite-K -2.24 -4.52 -2.28 -0.140 0.38909E+04 203 montmorillonite-Mg -2.48 -4.71 -2.23 -0.138 0.38035E+04 204 montmorillonite-Na -2.04 -4.08 -2.04 -0.125 0.34839E+04 205 nontronite-Ca 3.21 3.04 -0.18 -0.011 0.29916E+03 206 nontronite-H 2.53 1.31 -1.22 -0.082 0.20849E+04 207 nontronite-K 3.34 2.92 -0.42 -0.027 0.72459E+03 208 nontronite-Mg 3.07 2.72 -0.35 -0.023 0.59805E+03 209 nontronite-Na 3.52 3.35 -0.17 -0.011 0.28353E+03 224 tobermorite 9.82 5.43 -4.40 -1.199 0.75052E+04 233 boehmite 4.41 2.53 -1.87 -0.312 0.31962E+04 235 ferrous-oxide 9.81 6.33 -3.48 -0.870 0.59402E+04 240 silica-amorphous -2.09 -3.29 -1.20 -0.401 0.20544E+04 242 an20ab80 2.02 0.86 -1.16 -0.089 0.19751E+04 243 an25ab75 2.65 1.37 -1.28 -0.098 0.21839E+04 244 an30ab70 3.28 1.87 -1.41 -0.108 0.24024E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 0.0400000 g Current total amount of reactant added: 1.0390000 g New total amount of reactant added: 1.0790000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.4567E-13 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 6 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 1.0790000 Water: Moles liquid = 0.5550E+02 kg liquid = 0.9998E+00 Moles total = 0.5549E+02 kg total = 0.9998E+00 Activity = 1.0000 Stoichiometric ionic strength = .1044847E-02 Osmotic coef. = 0.9813 True ionic strength = .1599823E-02 Chg. balance for total moles = 0.4567E-13 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.91332E-09 -9.0394 0.85212E-09 -9.0695 0.93299E+00 -0.0301 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13794E-03 -3.8603 0.12861E-03 -3.8907 0.93237E+00 -0.0304 4 SO4-- 0.25489E-04 -4.5936 0.20353E-04 -4.6914 0.79850E+00 -0.0977 5 HCO3- 0.11657E-04 -4.9334 0.10870E-04 -4.9638 0.93252E+00 -0.0303 6 HS- 0.45369E-13 -13.3432 0.42302E-13 -13.3736 0.93239E+00 -0.0304 7 Al+++ 0.34418E-24 -24.4632 0.21182E-24 -24.6740 0.61543E+00 -0.2108 8 H4SiO4 0.50974E-03 -3.2927 0.50974E-03 -3.2927 0.10000E+01 0.0000 9 Ca++ 0.26102E-07 -7.5833 0.20826E-07 -7.6814 0.79786E+00 -0.0981 10 Mg++ 0.33108E-09 -9.4801 0.26402E-09 -9.5784 0.79746E+00 -0.0983 11 Fe++ 0.19532E-11 -11.7093 0.15578E-11 -11.8075 0.79756E+00 -0.0982 12 K+ 0.65741E-04 -4.1822 0.61307E-04 -4.2125 0.93255E+00 -0.0303 13 Na+ 0.15014E-02 -2.8235 0.13998E-02 -2.8539 0.93236E+00 -0.0304 14 Mn++ 0.26242E-09 -9.5810 0.20932E-09 -9.6792 0.79763E+00 -0.0982 15 HPO4-- 0.57045E-05 -5.2438 0.45551E-05 -5.3415 0.79851E+00 -0.0977 16 HSiO3- 0.59907E-03 -3.2225 0.55856E-03 -3.2529 0.93237E+00 -0.0304 17 Ca(HSiO3)+ 0.28407E-09 -9.5466 0.26492E-09 -9.5769 0.93257E+00 -0.0303 18 Mg(HSiO3)+ 0.44819E-11 -11.3485 0.41797E-11 -11.3789 0.93257E+00 -0.0303 19 NaHSiO3,aq 0.12646E-04 -4.8980 0.12646E-04 -4.8980 0.10000E+01 0.0000 20 AlO+ 0.42556E-13 -13.3710 0.39686E-13 -13.4014 0.93257E+00 -0.0303 21 AlOH+2 0.21109E-18 -18.6755 0.16839E-18 -18.7737 0.79771E+00 -0.0982 22 HAlO2,aq 0.92750E-08 -8.0327 0.92750E-08 -8.0327 0.10000E+01 0.0000 23 AlO2- 0.25847E-04 -4.5876 0.24094E-04 -4.6181 0.93219E+00 -0.0305 24 CH4,aq 0.21954E-19 -19.6585 0.21947E-19 -19.6586 0.99968E+00 -0.0001 29 CO,aq 0.23677E-18 -18.6257 0.23677E-18 -18.6257 0.10000E+01 0.0000 30 CO2,aq 0.19799E-07 -7.7034 0.19793E-07 -7.7035 0.99968E+00 -0.0001 31 CO3-2 0.13958E-05 -5.8552 0.11143E-05 -5.9530 0.79831E+00 -0.0978 32 CaCO3,aq 0.29097E-09 -9.5362 0.29097E-09 -9.5362 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.61966E-11 -11.2078 0.57787E-11 -11.2382 0.93257E+00 -0.0303 34 CaCl+ 0.46481E-11 -11.3327 0.43347E-11 -11.3630 0.93257E+00 -0.0303 35 CaCl2,aq 0.13245E-15 -15.8779 0.13245E-15 -15.8779 0.10000E+01 0.0000 36 CaOH+ 0.18678E-08 -8.7287 0.17418E-08 -8.7590 0.93257E+00 -0.0303 37 CaSO4,aq 0.13460E-09 -9.8710 0.13460E-09 -9.8710 0.10000E+01 0.0000 38 HCl,aq 0.20083E-13 -13.6972 0.20083E-13 -13.6972 0.10000E+01 0.0000 43 FeCl+ 0.34005E-15 -15.4685 0.31712E-15 -15.4988 0.93257E+00 -0.0303 46 FeO,aq 0.83380E-10 -10.0789 0.83380E-10 -10.0789 0.10000E+01 0.0000 47 FeOH+ 0.63809E-10 -10.1951 0.59506E-10 -10.2254 0.93257E+00 -0.0303 48 HFeO2- 0.10981E-08 -8.9594 0.10238E-08 -8.9898 0.93237E+00 -0.0304 49 FeO+ 0.69744E-14 -14.1565 0.65042E-14 -14.1868 0.93257E+00 -0.0303 51 FeO2- 0.19658E-08 -8.7065 0.18329E-08 -8.7369 0.93237E+00 -0.0304 52 HFeO2,aq 0.19864E-09 -9.7019 0.19864E-09 -9.7019 0.10000E+01 0.0000 53 H2,aq 0.47636E-09 -9.3221 0.47620E-09 -9.3222 0.99968E+00 -0.0001 54 KCl,aq 0.14291E-09 -9.8449 0.14291E-09 -9.8449 0.10000E+01 0.0000 55 KHSO4,aq 0.30062E-17 -17.5220 0.30062E-17 -17.5220 0.10000E+01 0.0000 56 KOH,aq 0.30725E-07 -7.5125 0.30725E-07 -7.5125 0.10000E+01 0.0000 57 KSO4- 0.20767E-07 -7.6826 0.19362E-07 -7.7130 0.93237E+00 -0.0304 58 MgCO3,aq 0.92461E-12 -12.0340 0.92461E-12 -12.0340 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.80270E-13 -13.0954 0.74857E-13 -13.1258 0.93257E+00 -0.0303 60 MgCl+ 0.53408E-13 -13.2724 0.49806E-13 -13.3027 0.93257E+00 -0.0303 61 MgOH+ 0.13103E-09 -9.8826 0.12219E-09 -9.9130 0.93257E+00 -0.0303 63 MnO,aq 0.29853E-09 -9.5250 0.29853E-09 -9.5250 0.10000E+01 0.0000 64 MnOH+ 0.79650E-09 -9.0988 0.74279E-09 -9.1291 0.93257E+00 -0.0303 65 MnO2-2 0.17092E-13 -13.7672 0.13644E-13 -13.8650 0.79831E+00 -0.0978 66 HMnO2- 0.27320E-11 -11.5635 0.25472E-11 -11.5939 0.93237E+00 -0.0304 69 MnCl+ 0.17777E-12 -12.7502 0.16578E-12 -12.7805 0.93257E+00 -0.0303 70 MnSO4,aq 0.12299E-11 -11.9101 0.12299E-11 -11.9101 0.10000E+01 0.0000 71 NaCl,aq 0.59665E-07 -7.2243 0.59665E-07 -7.2243 0.10000E+01 0.0000 72 NaOH,aq 0.70581E-06 -6.1513 0.70581E-06 -6.1513 0.10000E+01 0.0000 74 OH- 0.72737E-03 -3.1382 0.67804E-03 -3.1687 0.93219E+00 -0.0305 79 HPO3-2 0.84676E-17 -17.0722 0.67597E-17 -17.1701 0.79831E+00 -0.0978 81 H2PO3- 0.12389E-19 -19.9070 0.11551E-19 -19.9374 0.93237E+00 -0.0304 82 H3PO4,aq 0.23132E-13 -13.6358 0.23132E-13 -13.6358 0.10000E+01 0.0000 83 H2PO4- 0.76788E-07 -7.1147 0.71603E-07 -7.1451 0.93247E+00 -0.0304 84 PO4-3 0.70484E-08 -8.1519 0.43614E-08 -8.3604 0.61878E+00 -0.2085 87 H2P2O7-2 0.50357E-15 -15.2979 0.40201E-15 -15.3958 0.79831E+00 -0.0978 88 HP2O7-3 0.15306E-12 -12.8152 0.94201E-13 -13.0259 0.61547E+00 -0.2108 89 P2O7-4 0.61550E-13 -13.2108 0.26410E-13 -13.5782 0.42908E+00 -0.3675 90 H2S,aq 0.11144E-15 -15.9530 0.11141E-15 -15.9531 0.99968E+00 -0.0001 97 SO3-2 0.15752E-14 -14.8027 0.12595E-14 -14.8998 0.79958E+00 -0.0971 98 HSO3- 0.72071E-16 -16.1422 0.67197E-16 -16.1726 0.93237E+00 -0.0304 99 HSO4- 0.17920E-10 -10.7467 0.16714E-10 -10.7769 0.93267E+00 -0.0303 Charge balance for all species = 0.4644E-13 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.9133223E-09 -.1444554E-02 -.1455800E+01 0.0000 2 H2O 0.1000000E+01 0.5550842E+02 0.9998469E+06 0.0000 3 Cl- 0.1379435E-03 0.1380033E-03 0.4891879E+01 5.1788 4 SO4-- 0.2548894E-04 0.2551001E-04 0.2450155E+01 13.4476 5 HCO3- 0.1165690E-04 0.1307276E-04 0.7975404E+00 4.1057 6 HS- 0.4536924E-13 -.1514253E-09 -.5007166E-05 -4.3041 7 Al+++ 0.3441803E-24 0.2585596E-04 0.6975251E+00 2.5345 8 H4SiO4 0.5097366E-03 0.1121456E-02 0.1077726E+03 -3.2927 9 Ca++ 0.2610235E-07 0.2869062E-07 0.1149686E-02 10.4576 10 Mg++ 0.3310761E-09 0.4676421E-09 0.1136756E-04 8.5606 11 Fe++ 0.1953158E-11 0.3411690E-08 0.1905033E-03 6.3315 12 K+ 0.6574097E-04 0.6579261E-04 0.2572227E+01 4.8570 13 Na+ 0.1501387E-02 0.1514799E-02 0.3481956E+02 6.2156 14 Mn++ 0.2624231E-09 0.1361609E-08 0.7479254E-04 8.4598 15 HPO4-- 0.5704476E-05 0.5788313E-05 0.5554710E+00 12.7975 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.1785360E-01 -.1444249E-02 -.1640935E-01 0.0000000E+00 2 H2O 0.5549472E+02 0.5549670E+02 -.1974531E-02 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.5540724E-04 0.2550462E-04 0.2990262E-04 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.2990277E-04 -.1513933E-09 -.2990262E-04 0.0000000E+00 7 Al+++ 0.3518340E-02 0.2585050E-04 0.3492490E-02 0.0000000E+00 8 H4SiO4 0.1123539E-01 0.1121220E-02 0.1011417E-01 0.0000000E+00 9 Ca++ 0.1255475E-02 0.2868457E-07 0.1255446E-02 0.0000000E+00 10 Mg++ 0.8563492E-03 0.4675433E-09 0.8563487E-03 0.0000000E+00 11 Fe++ 0.7693363E-03 0.3410969E-08 0.7693329E-03 0.0000000E+00 12 K+ 0.2290870E-03 0.6577872E-04 0.1633083E-03 0.0000000E+00 13 Na+ 0.1514479E-02 0.1514479E-02 0.0000000E+00 0.0000000E+00 14 Mn++ 0.1870835E-04 0.1361321E-08 0.1870698E-04 0.0000000E+00 15 HPO4-- 0.6385065E-05 0.5787091E-05 0.5979738E-06 0.0000000E+00 Chg. balance for solid moles: 0.9891E-18 Mass of aqueous solution: 0.999943E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 1.0790000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) apatite-OH 0.1993E-06 -6.700 0.1001E-03 -3.999 0.8801E-02 0.3182E-04 clinochlore 0.1713E-03 -3.766 0.9520E-01 -1.021 8.368 0.3621E-01 daphnite 0.1060E-03 -3.975 0.7565E-01 -1.121 6.649 0.2292E-01 chlorite-Mn 0.3741E-05 -5.427 0.2653E-02 -2.576 0.2332 0.8453E-03 hematite 0.1196E-03 -3.922 0.1910E-01 -1.719 1.679 0.3621E-02 microcline 0.3420E-04 -4.466 0.9519E-02 -2.021 0.8367 0.3719E-02 muscovite 0.1291E-03 -3.889 0.5142E-01 -1.289 4.520 0.1818E-01 stilbite 0.1254E-02 -2.902 0.8840 -0.054 77.71 0.4123 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.6094E+00 0.6094E+00 1.0000 -0.215 daphnite 0.3773E+00 0.3773E+00 1.0000 -0.423 chlorite-Mn 0.1331E-01 0.1331E-01 1.0000 -1.876 hematite 0.1000E+01 0.1000E+01 1.0000 0.000 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 muscovite 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 1.137679 g Volume = 0.497864 cm3 Porosity: 65.2232% V(tot) - V(min): 0.93374E+00 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 1.0790000 g log = 0.0330 Original solution: 1000.0103000 g Original solution / Rock added: 926.79 (Water/Rock Ratio), log = 2.9670 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0203 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.1000E+01 0.9860 0.1006E+01 0.1020E+01 CO2,gas 0.2061E-05 1.0071 0.2118E-05 0.2103E-05 CH4,gas 0.3127E-16 1.0125 0.3230E-16 0.3190E-16 H2,gas 0.6124E-06 1.0005 0.6252E-06 0.6249E-06 H2S,gas 0.3013E-14 0.9960 0.3062E-14 0.3075E-14 S2,gas 0.8827E-36 1.0000 0.9007E-36 0.9007E-36 CO,gas 0.3458E-15 1.0000 0.3528E-15 0.3528E-15 SO3,gas 0.5477E-38 1.0000 0.5588E-38 0.5588E-38 SO2,gas 0.1332E-21 1.0000 0.1359E-21 0.1359E-21 HCl,gas 0.3473E-16 1.0000 0.3544E-16 0.3544E-16 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 32 apatite-OH -18.15 -18.15 0.00 0.000 0.00000E+00 46 clinochlore 39.07 39.07 0.00 0.000 0.00000E+00 47 daphnite 28.97 28.97 0.00 0.000 0.18198E-10 48 chlorite-Mn 46.87 46.87 0.00 0.000 0.36397E-10 90 hematite 12.57 12.57 0.00 0.000 -0.30331E-11 116 microcline -2.49 -2.49 0.00 0.000 0.15165E-11 120 muscovite 2.58 2.58 0.00 0.000 0.30331E-10 163 stilbite -7.52 -7.52 0.00 0.000 -0.90992E-11 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -14.03 -7.37 -2.458 0.12589E+05 -5.674 3 CH4,gas 4.54 -13.65 -18.19 -4.547 0.31058E+05 -16.491 4 H2,gas 8.00 0.10 -7.90 -4.516 0.13494E+05 -6.204 5 H2S,gas -6.23 -22.44 -16.21 -8.106 0.27683E+05 -14.514 6 S2,gas -7.34 -45.08 -37.74 -5.807 0.64448E+05 -36.045 7 CO,gas 3.21 -13.94 -17.15 -5.277 0.29286E+05 -15.452 8 SO3,gas 17.12 -22.83 -39.95 -9.988 0.68216E+05 -38.253 9 SO2,gas 0.83 -22.73 -23.57 -6.284 0.40238E+05 -21.867 10 HCl,gas 5.19 -12.96 -18.15 -9.075 0.30990E+05 -16.451 11 acmite 7.71 5.91 -1.80 -0.187 0.30672E+04 15 albite-high 0.69 -1.13 -1.82 -0.140 0.31093E+04 16 albite -0.38 -1.13 -0.74 -0.057 0.12705E+04 19 spessartine 24.46 20.57 -3.89 -0.194 0.66369E+04 20 analcite 3.32 2.16 -1.16 -0.129 0.19758E+04 21 andalusite 5.00 1.78 -3.23 -0.323 0.55070E+04 22 andradite 39.01 34.06 -4.95 -0.257 0.84481E+04 26 annite 20.12 16.51 -3.62 -0.201 0.61732E+04 27 phlogopite 27.06 23.20 -3.87 -0.215 0.66065E+04 29 anorthite 12.71 8.94 -3.77 -0.290 0.64356E+04 35 aragonite 0.97 -3.58 -4.54 -1.514 0.77556E+04 36 brucite 12.57 8.56 -4.01 -0.802 0.68434E+04 37 calcite 0.81 -3.58 -4.39 -1.462 0.74914E+04 38 carnegieite-low 9.02 5.46 -3.57 -0.509 0.60887E+04 39 carnegieite-high 10.09 5.46 -4.64 -0.662 0.79157E+04 40 carpholite-Mg 8.58 7.04 -1.54 -0.103 0.26258E+04 41 carpholite-Fe 6.71 4.82 -1.90 -0.127 0.32400E+04 42 celadonite 5.34 2.78 -2.56 -0.151 0.43713E+04 43 celadonite-Fe 3.88 0.55 -3.32 -0.196 0.56759E+04 44 chrysotile 23.89 19.10 -4.80 -0.400 0.81887E+04 50 chloritoid-Mg 13.20 10.34 -2.86 -0.191 0.48847E+04 51 chloritoid-Fe 9.17 8.11 -1.07 -0.071 0.18199E+04 52 chloritoid-Mn 11.40 10.24 -1.17 -0.078 0.19892E+04 54 coesite -2.38 -3.29 -0.92 -0.306 0.15651E+04 59 corundum 8.38 5.07 -3.31 -0.301 0.56589E+04 61 cristobalite -2.56 -3.29 -0.73 -0.244 0.12504E+04 63 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71234E+04 65 diaspore 2.87 2.53 -0.34 -0.057 0.57923E+03 67 diopside 16.18 12.43 -3.75 -0.375 0.64003E+04 68 hedenbergite 14.21 10.20 -4.00 -0.400 0.68376E+04 75 epidote 24.67 22.39 -2.28 -0.111 0.38942E+04 76 clinozoisite 22.81 18.64 -4.17 -0.189 0.71123E+04 77 epidote-Fe 29.84 26.14 -3.70 -0.192 0.63226E+04 78 fayalite 14.05 9.37 -4.68 -0.668 0.79831E+04 83 gibbsite 4.08 2.53 -1.54 -0.221 0.26378E+04 87 greenalite 16.14 12.41 -3.73 -0.311 0.63694E+04 91 heulandite -5.83 -7.52 -1.69 -0.077 0.28938E+04 95 jadeite 4.22 2.16 -2.05 -0.205 0.35013E+04 97 kalsilite 7.58 4.10 -3.49 -0.498 0.59507E+04 98 kaolinite -1.33 -1.52 -0.18 -0.017 0.31352E+03 99 kyanite 4.88 1.78 -3.10 -0.310 0.52929E+04 101 laumontite 2.88 2.36 -0.53 -0.035 0.90069E+03 102 lawsonite 9.62 8.94 -0.67 -0.045 0.11523E+04 103 leucite 4.12 0.81 -3.31 -0.331 0.56563E+04 105 lizardite 23.24 19.10 -4.15 -0.346 0.70813E+04 107 magnetite 20.09 18.90 -1.19 -0.097 0.20314E+04 108 minnesotaite 10.39 5.82 -4.56 -0.268 0.77933E+04 113 margarite 17.32 14.01 -3.31 -0.133 0.56577E+04 121 paragonite 4.24 3.94 -0.30 -0.018 0.50956E+03 122 nepheline 8.34 5.46 -2.88 -0.412 0.49211E+04 136 prehnite 19.37 16.11 -3.27 -0.192 0.55761E+04 137 prehnite-Fe 22.50 19.85 -2.64 -0.159 0.45130E+04 145 pyroxmangite 7.40 5.17 -2.23 -0.446 0.38103E+04 146 pyrophyllite -6.18 -8.10 -1.93 -0.120 0.32884E+04 147 quartz -2.99 -3.29 -0.30 -0.101 0.51774E+03 151 rhodochrosite -0.98 -5.57 -4.60 -1.532 0.78495E+04 152 rhodonite 7.45 5.17 -2.28 -0.456 0.38905E+04 153 sanidine -1.28 -2.49 -1.21 -0.093 0.20677E+04 156 sillimanite 5.26 1.78 -3.49 -0.349 0.59510E+04 164 stilpnomelane-Fe 13.02 12.81 -0.20 -0.006 0.34713E+03 165 stilpnomelane-Mg 27.44 23.96 -3.48 -0.104 0.59455E+04 168 sudoite 21.08 17.38 -3.70 -0.119 0.63112E+04 171 talc 16.49 12.51 -3.98 -0.234 0.67954E+04 174 tephroite 18.09 13.63 -4.46 -0.637 0.76134E+04 177 topaz-H 4.62 1.78 -2.84 -0.258 0.48530E+04 178 tridymite -2.63 -3.29 -0.67 -0.222 0.11377E+04 187 wairakite 3.95 2.36 -1.59 -0.094 0.27227E+04 188 walstromite 11.51 7.16 -4.34 -0.869 0.74177E+04 189 wollastonite 10.46 7.16 -3.30 -0.659 0.56282E+04 190 pseudo-wollastonite 11.00 7.16 -3.83 -0.767 0.65480E+04 191 zoisite 22.85 18.64 -4.21 -0.191 0.71864E+04 192 akaganeite 7.75 6.28 -1.47 -0.318 0.25125E+04 193 beidellite-Ca -1.65 -4.45 -2.81 -0.174 0.47940E+04 194 beidellite-H -2.33 -6.18 -3.85 -0.246 0.65781E+04 195 beidellite-K -1.52 -4.58 -3.06 -0.187 0.52175E+04 196 beidellite-Mg -1.79 -4.77 -2.98 -0.184 0.50822E+04 197 beidellite-Na -1.34 -4.13 -2.79 -0.171 0.47559E+04 199 chalcedony -2.80 -3.29 -0.49 -0.163 0.83704E+03 201 montmorillonite-Ca -2.29 -4.39 -2.10 -0.130 0.35803E+04 202 montmorillonite-K -2.24 -4.51 -2.27 -0.139 0.38820E+04 203 montmorillonite-Mg -2.48 -4.70 -2.22 -0.137 0.37917E+04 204 montmorillonite-Na -2.04 -4.06 -2.02 -0.124 0.34561E+04 205 nontronite-Ca 3.21 3.04 -0.17 -0.011 0.29116E+03 206 nontronite-H 2.53 1.32 -1.21 -0.081 0.20732E+04 207 nontronite-K 3.34 2.92 -0.42 -0.027 0.71607E+03 208 nontronite-Mg 3.07 2.73 -0.34 -0.022 0.58669E+03 209 nontronite-Na 3.52 3.37 -0.15 -0.010 0.25620E+03 224 tobermorite 9.82 5.42 -4.40 -1.202 0.75206E+04 233 boehmite 4.41 2.53 -1.87 -0.312 0.31962E+04 235 ferrous-oxide 9.81 6.33 -3.48 -0.870 0.59422E+04 240 silica-amorphous -2.09 -3.29 -1.20 -0.400 0.20512E+04 242 an20ab80 2.02 0.89 -1.13 -0.087 0.19326E+04 243 an25ab75 2.65 1.39 -1.26 -0.097 0.21452E+04 244 an30ab70 3.28 1.89 -1.39 -0.107 0.23673E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 0.0400000 g Current total amount of reactant added: 1.0790000 g New total amount of reactant added: 1.1190000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.4567E-13 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 6 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 1.1190000 Water: Moles liquid = 0.5550E+02 kg liquid = 0.9998E+00 Moles total = 0.5549E+02 kg total = 0.9997E+00 Activity = 1.0000 Stoichiometric ionic strength = .1073638E-02 Osmotic coef. = 0.9811 True ionic strength = .1647152E-02 Chg. balance for total moles = 0.4567E-13 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.88667E-09 -9.0522 0.82667E-09 -9.0827 0.93233E+00 -0.0304 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13794E-03 -3.8603 0.12852E-03 -3.8910 0.93170E+00 -0.0307 4 SO4-- 0.25490E-04 -4.5936 0.20296E-04 -4.6926 0.79622E+00 -0.0990 5 HCO3- 0.11617E-04 -4.9349 0.10825E-04 -4.9656 0.93185E+00 -0.0307 6 HS- 0.43059E-13 -13.3659 0.40119E-13 -13.3967 0.93171E+00 -0.0307 7 Al+++ 0.31629E-24 -24.4999 0.19340E-24 -24.7135 0.61146E+00 -0.2136 8 H4SiO4 0.51185E-03 -3.2909 0.51185E-03 -3.2909 0.10000E+01 0.0000 9 Ca++ 0.23934E-07 -7.6210 0.19041E-07 -7.7203 0.79557E+00 -0.0993 10 Mg++ 0.31172E-09 -9.5062 0.24787E-09 -9.6058 0.79516E+00 -0.0995 11 Fe++ 0.18390E-11 -11.7354 0.14625E-11 -11.8349 0.79525E+00 -0.0995 12 K+ 0.63037E-04 -4.2004 0.58742E-04 -4.2310 0.93188E+00 -0.0306 13 Na+ 0.15507E-02 -2.8095 0.14448E-02 -2.8402 0.93168E+00 -0.0307 14 Mn++ 0.24708E-09 -9.6072 0.19651E-09 -9.7066 0.79533E+00 -0.0995 15 HPO4-- 0.63789E-05 -5.1953 0.50790E-05 -5.2942 0.79623E+00 -0.0990 16 HSiO3- 0.62053E-03 -3.2072 0.57814E-03 -3.2380 0.93170E+00 -0.0307 17 Ca(HSiO3)+ 0.26903E-09 -9.5702 0.25071E-09 -9.6008 0.93190E+00 -0.0306 18 Mg(HSiO3)+ 0.43583E-11 -11.3607 0.40615E-11 -11.3913 0.93190E+00 -0.0306 19 NaHSiO3,aq 0.13510E-04 -4.8694 0.13510E-04 -4.8694 0.10000E+01 0.0000 20 AlO+ 0.41314E-13 -13.3839 0.38501E-13 -13.4145 0.93190E+00 -0.0306 21 AlOH+2 0.19924E-18 -18.7006 0.15848E-18 -18.8000 0.79541E+00 -0.0994 22 HAlO2,aq 0.92750E-08 -8.0327 0.92750E-08 -8.0327 0.10000E+01 0.0000 23 AlO2- 0.26662E-04 -4.5741 0.24836E-04 -4.6049 0.93151E+00 -0.0308 24 CH4,aq 0.20792E-19 -19.6821 0.20786E-19 -19.6822 0.99967E+00 -0.0001 29 CO,aq 0.22761E-18 -18.6428 0.22761E-18 -18.6428 0.10000E+01 0.0000 30 CO2,aq 0.19128E-07 -7.7183 0.19121E-07 -7.7185 0.99967E+00 -0.0001 31 CO3-2 0.14368E-05 -5.8426 0.11438E-05 -5.9417 0.79602E+00 -0.0991 32 CaCO3,aq 0.27308E-09 -9.5637 0.27308E-09 -9.5637 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.56460E-11 -11.2483 0.52615E-11 -11.2789 0.93190E+00 -0.0306 34 CaCl+ 0.42498E-11 -11.3716 0.39604E-11 -11.4023 0.93190E+00 -0.0306 35 CaCl2,aq 0.12093E-15 -15.9175 0.12093E-15 -15.9175 0.10000E+01 0.0000 36 CaOH+ 0.17616E-08 -8.7541 0.16416E-08 -8.7847 0.93190E+00 -0.0306 37 CaSO4,aq 0.12272E-09 -9.9111 0.12272E-09 -9.9111 0.10000E+01 0.0000 38 HCl,aq 0.19469E-13 -13.7107 0.19469E-13 -13.7107 0.10000E+01 0.0000 43 FeCl+ 0.31924E-15 -15.4959 0.29750E-15 -15.5265 0.93190E+00 -0.0306 46 FeO,aq 0.83173E-10 -10.0800 0.83173E-10 -10.0800 0.10000E+01 0.0000 47 FeOH+ 0.61794E-10 -10.2091 0.57586E-10 -10.2397 0.93190E+00 -0.0306 48 HFeO2- 0.11299E-08 -8.9470 0.10527E-08 -8.9777 0.93170E+00 -0.0307 49 FeO+ 0.67710E-14 -14.1693 0.63099E-14 -14.2000 0.93190E+00 -0.0306 51 FeO2- 0.20278E-08 -8.6930 0.18893E-08 -8.7237 0.93170E+00 -0.0307 52 HFeO2,aq 0.19864E-09 -9.7019 0.19864E-09 -9.7019 0.10000E+01 0.0000 53 H2,aq 0.47400E-09 -9.3242 0.47385E-09 -9.3244 0.99967E+00 -0.0001 54 KCl,aq 0.13683E-09 -9.8638 0.13683E-09 -9.8638 0.10000E+01 0.0000 55 KHSO4,aq 0.27866E-17 -17.5549 0.27866E-17 -17.5549 0.10000E+01 0.0000 56 KOH,aq 0.30346E-07 -7.5179 0.30346E-07 -7.5179 0.10000E+01 0.0000 57 KSO4- 0.19856E-07 -7.7021 0.18500E-07 -7.7328 0.93170E+00 -0.0307 58 MgCO3,aq 0.89103E-12 -12.0501 0.89103E-12 -12.0501 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.75098E-13 -13.1244 0.69984E-13 -13.1550 0.93190E+00 -0.0306 60 MgCl+ 0.50139E-13 -13.2998 0.46725E-13 -13.3305 0.93190E+00 -0.0306 61 MgOH+ 0.12689E-09 -9.8966 0.11825E-09 -9.9272 0.93190E+00 -0.0306 63 MnO,aq 0.29779E-09 -9.5261 0.29779E-09 -9.5261 0.10000E+01 0.0000 64 MnOH+ 0.77135E-09 -9.1127 0.71882E-09 -9.1434 0.93190E+00 -0.0306 65 MnO2-2 0.18168E-13 -13.7407 0.14462E-13 -13.8398 0.79602E+00 -0.0991 66 HMnO2- 0.28112E-11 -11.5511 0.26192E-11 -11.5818 0.93170E+00 -0.0307 69 MnCl+ 0.16689E-12 -12.7776 0.15552E-12 -12.8082 0.93190E+00 -0.0306 70 MnSO4,aq 0.11514E-11 -11.9388 0.11514E-11 -11.9388 0.10000E+01 0.0000 71 NaCl,aq 0.61536E-07 -7.2109 0.61536E-07 -7.2109 0.10000E+01 0.0000 72 NaOH,aq 0.75090E-06 -6.1244 0.75090E-06 -6.1244 0.10000E+01 0.0000 74 OH- 0.75031E-03 -3.1248 0.69892E-03 -3.1556 0.93151E+00 -0.0308 79 HPO3-2 0.94219E-17 -17.0259 0.75000E-17 -17.1249 0.79602E+00 -0.0991 81 H2PO3- 0.13344E-19 -19.8747 0.12433E-19 -19.9054 0.93170E+00 -0.0307 82 H3PO4,aq 0.24276E-13 -13.6148 0.24276E-13 -13.6148 0.10000E+01 0.0000 83 H2PO4- 0.83124E-07 -7.0803 0.77454E-07 -7.1110 0.93180E+00 -0.0307 84 PO4-3 0.81525E-08 -8.0887 0.50128E-08 -8.2999 0.61488E+00 -0.2112 87 H2P2O7-2 0.59093E-15 -15.2285 0.47040E-15 -15.3275 0.79602E+00 -0.0991 88 HP2O7-3 0.18581E-12 -12.7309 0.11362E-12 -12.9445 0.61150E+00 -0.2136 89 P2O7-4 0.77403E-13 -13.1112 0.32835E-13 -13.4837 0.42420E+00 -0.3724 90 H2S,aq 0.10253E-15 -15.9891 0.10250E-15 -15.9893 0.99967E+00 -0.0001 97 SO3-2 0.15674E-14 -14.8048 0.12497E-14 -14.9032 0.79733E+00 -0.0984 98 HSO3- 0.69427E-16 -16.1585 0.64685E-16 -16.1892 0.93170E+00 -0.0307 99 HSO4- 0.17349E-10 -10.7607 0.16169E-10 -10.7913 0.93200E+00 -0.0306 Charge balance for all species = 0.4641E-13 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.8866675E-09 -.1493156E-02 -.1504775E+01 0.0000 2 H2O 0.1000000E+01 0.5550842E+02 0.9998435E+06 0.0000 3 Cl- 0.1379426E-03 0.1380043E-03 0.4891897E+01 5.1916 4 SO4-- 0.2549004E-04 0.2551020E-04 0.2450165E+01 13.4727 5 HCO3- 0.1161660E-04 0.1307285E-04 0.7975434E+00 4.1171 6 HS- 0.4305912E-13 -.1597654E-09 -.5282929E-05 -4.3140 7 Al+++ 0.3162914E-24 0.2667123E-04 0.7195166E+00 2.5345 8 H4SiO4 0.5118482E-03 0.1145884E-02 0.1101198E+03 -3.2909 9 Ca++ 0.2393444E-07 0.2637075E-07 0.1056720E-02 10.4450 10 Mg++ 0.3117223E-09 0.4439853E-09 0.1079247E-04 8.5596 11 Fe++ 0.1838976E-11 0.3503174E-08 0.1956110E-03 6.3304 12 K+ 0.6303656E-04 0.6308689E-04 0.2466436E+01 4.8516 13 Na+ 0.1550708E-02 0.1565030E-02 0.3597407E+02 6.2425 14 Mn++ 0.2470823E-09 0.1320373E-08 0.7252723E-04 8.4587 15 HPO4-- 0.6378867E-05 0.6470144E-05 0.6209002E+00 12.8711 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.1851594E-01 -.1492830E-02 -.1702311E-01 0.0000000E+00 2 H2O 0.5549422E+02 0.5549630E+02 -.2080181E-02 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.5651577E-04 0.2550463E-04 0.3101114E-04 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.3101130E-04 -.1597305E-09 -.3101114E-04 0.0000000E+00 7 Al+++ 0.3648770E-02 0.2666541E-04 0.3622104E-02 0.0000000E+00 8 H4SiO4 0.1165190E-01 0.1145634E-02 0.1050627E-01 0.0000000E+00 9 Ca++ 0.1301481E-02 0.2636499E-07 0.1301454E-02 0.0000000E+00 10 Mg++ 0.8880952E-03 0.4438884E-09 0.8880948E-03 0.0000000E+00 11 Fe++ 0.7978566E-03 0.3502409E-08 0.7978531E-03 0.0000000E+00 12 K+ 0.2375796E-03 0.6307312E-04 0.1745065E-03 0.0000000E+00 13 Na+ 0.1564689E-02 0.1564689E-02 0.0000000E+00 0.0000000E+00 14 Mn++ 0.1940189E-04 0.1320085E-08 0.1940057E-04 0.0000000E+00 15 HPO4-- 0.6621768E-05 0.6468732E-05 0.1530364E-06 0.0000000E+00 Chg. balance for solid moles: -.3980E-18 Mass of aqueous solution: 0.999939E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 1.1190000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) apatite-OH 0.5101E-07 -7.292 0.2562E-04 -4.591 0.2170E-02 0.8142E-05 clinochlore 0.1776E-03 -3.751 0.9873E-01 -1.006 8.359 0.3755E-01 daphnite 0.1100E-03 -3.959 0.7845E-01 -1.105 6.643 0.2377E-01 chlorite-Mn 0.3880E-05 -5.411 0.2751E-02 -2.561 0.2329 0.8766E-03 hematite 0.1240E-03 -3.906 0.1981E-01 -1.703 1.677 0.3755E-02 microcline 0.4336E-04 -4.363 0.1207E-01 -1.918 1.022 0.4714E-02 muscovite 0.1311E-03 -3.882 0.5224E-01 -1.282 4.423 0.1847E-01 stilbite 0.1301E-02 -2.886 0.9170 -0.038 77.64 0.4277 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.6094E+00 0.6094E+00 1.0000 -0.215 daphnite 0.3773E+00 0.3773E+00 1.0000 -0.423 chlorite-Mn 0.1331E-01 0.1331E-01 1.0000 -1.876 hematite 0.1000E+01 0.1000E+01 1.0000 0.000 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 muscovite 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 1.181052 g Volume = 0.516848 cm3 Porosity: 64.2962% V(tot) - V(min): 0.93075E+00 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 1.1190000 g log = 0.0488 Original solution: 1000.0103000 g Original solution / Rock added: 893.66 (Water/Rock Ratio), log = 2.9512 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0203 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.1000E+01 0.9860 0.1006E+01 0.1020E+01 CO2,gas 0.1991E-05 1.0071 0.2046E-05 0.2031E-05 CH4,gas 0.2962E-16 1.0125 0.3059E-16 0.3022E-16 H2,gas 0.6094E-06 1.0005 0.6221E-06 0.6218E-06 H2S,gas 0.2773E-14 0.9960 0.2818E-14 0.2829E-14 S2,gas 0.7547E-36 1.0000 0.7700E-36 0.7700E-36 CO,gas 0.3324E-15 1.0000 0.3392E-15 0.3392E-15 SO3,gas 0.5140E-38 1.0000 0.5244E-38 0.5244E-38 SO2,gas 0.1244E-21 1.0000 0.1269E-21 0.1269E-21 HCl,gas 0.3367E-16 1.0000 0.3435E-16 0.3435E-16 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 32 apatite-OH -18.15 -18.15 0.00 0.000 0.12132E-10 46 clinochlore 39.07 39.07 0.00 0.000 0.48529E-10 47 daphnite 28.97 28.97 0.00 0.000 0.30331E-10 48 chlorite-Mn 46.87 46.87 0.00 0.000 0.72794E-10 90 hematite 12.57 12.57 0.00 0.000 -0.90992E-11 116 microcline -2.49 -2.49 0.00 0.000 0.13649E-10 120 muscovite 2.58 2.58 0.00 0.000 0.60662E-11 163 stilbite -7.52 -7.52 0.00 0.000 0.15165E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -14.05 -7.39 -2.463 0.12615E+05 -5.689 3 CH4,gas 4.54 -13.67 -18.21 -4.553 0.31099E+05 -16.514 4 H2,gas 8.00 0.09 -7.91 -4.517 0.13498E+05 -6.206 5 H2S,gas -6.23 -22.48 -16.25 -8.125 0.27745E+05 -14.550 6 S2,gas -7.34 -45.15 -37.81 -5.817 0.64564E+05 -36.113 7 CO,gas 3.21 -13.95 -17.17 -5.283 0.29315E+05 -15.470 8 SO3,gas 17.12 -22.86 -39.98 -9.995 0.68264E+05 -38.280 9 SO2,gas 0.83 -22.76 -23.60 -6.292 0.40289E+05 -21.896 10 HCl,gas 5.19 -12.97 -18.16 -9.082 0.31013E+05 -16.464 11 acmite 7.71 5.94 -1.77 -0.183 0.30152E+04 15 albite-high 0.69 -1.10 -1.79 -0.138 0.30542E+04 16 albite -0.38 -1.10 -0.71 -0.055 0.12153E+04 19 spessartine 24.46 20.57 -3.88 -0.194 0.66332E+04 20 analcite 3.32 2.20 -1.13 -0.125 0.19237E+04 21 andalusite 5.00 1.78 -3.22 -0.322 0.55040E+04 22 andradite 39.01 34.03 -4.98 -0.259 0.85033E+04 26 annite 20.12 16.50 -3.62 -0.201 0.61787E+04 27 phlogopite 27.06 23.19 -3.87 -0.215 0.66120E+04 29 anorthite 12.71 8.93 -3.78 -0.291 0.64510E+04 35 aragonite 0.97 -3.60 -4.57 -1.523 0.78027E+04 36 brucite 12.57 8.56 -4.01 -0.802 0.68453E+04 37 calcite 0.81 -3.60 -4.41 -1.472 0.75385E+04 38 carnegieite-low 9.02 5.49 -3.54 -0.505 0.60397E+04 39 carnegieite-high 10.09 5.49 -4.61 -0.658 0.78667E+04 40 carpholite-Mg 8.58 7.05 -1.54 -0.102 0.26215E+04 41 carpholite-Fe 6.71 4.82 -1.90 -0.126 0.32357E+04 42 celadonite 5.34 2.78 -2.56 -0.151 0.43701E+04 43 celadonite-Fe 3.88 0.55 -3.32 -0.195 0.56747E+04 44 chrysotile 23.89 19.10 -4.80 -0.400 0.81881E+04 50 chloritoid-Mg 13.20 10.34 -2.86 -0.191 0.48835E+04 51 chloritoid-Fe 9.17 8.11 -1.07 -0.071 0.18187E+04 52 chloritoid-Mn 11.40 10.24 -1.16 -0.078 0.19880E+04 54 coesite -2.38 -3.29 -0.91 -0.305 0.15620E+04 59 corundum 8.38 5.07 -3.31 -0.301 0.56589E+04 61 cristobalite -2.56 -3.29 -0.73 -0.244 0.12473E+04 63 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71234E+04 65 diaspore 2.87 2.53 -0.34 -0.057 0.57923E+03 67 diopside 16.18 12.42 -3.76 -0.376 0.64175E+04 68 hedenbergite 14.21 10.19 -4.01 -0.401 0.68547E+04 75 epidote 24.67 22.37 -2.30 -0.112 0.39279E+04 76 clinozoisite 22.81 18.62 -4.19 -0.190 0.71460E+04 77 epidote-Fe 29.84 26.12 -3.72 -0.193 0.63563E+04 78 fayalite 14.05 9.37 -4.68 -0.668 0.79837E+04 83 gibbsite 4.08 2.53 -1.54 -0.221 0.26378E+04 87 greenalite 16.14 12.41 -3.73 -0.311 0.63688E+04 91 heulandite -5.83 -7.52 -1.69 -0.077 0.28938E+04 95 jadeite 4.22 2.20 -2.02 -0.202 0.34492E+04 97 kalsilite 7.58 4.10 -3.49 -0.498 0.59568E+04 98 kaolinite -1.33 -1.51 -0.18 -0.016 0.30739E+03 99 kyanite 4.88 1.78 -3.10 -0.310 0.52899E+04 101 laumontite 2.88 2.35 -0.53 -0.036 0.90989E+03 102 lawsonite 9.62 8.93 -0.68 -0.046 0.11676E+04 103 leucite 4.12 0.80 -3.31 -0.331 0.56594E+04 105 lizardite 23.24 19.10 -4.15 -0.346 0.70807E+04 107 magnetite 20.09 18.90 -1.19 -0.097 0.20332E+04 108 minnesotaite 10.39 5.83 -4.56 -0.268 0.77866E+04 113 margarite 17.32 14.00 -3.32 -0.133 0.56730E+04 121 paragonite 4.24 3.97 -0.27 -0.016 0.45445E+03 122 nepheline 8.34 5.49 -2.85 -0.408 0.48721E+04 136 prehnite 19.37 16.09 -3.29 -0.193 0.56098E+04 137 prehnite-Fe 22.50 19.84 -2.66 -0.160 0.45467E+04 145 pyroxmangite 7.40 5.17 -2.23 -0.446 0.38091E+04 146 pyrophyllite -6.18 -8.09 -1.92 -0.120 0.32761E+04 147 quartz -2.99 -3.29 -0.30 -0.100 0.51467E+03 151 rhodochrosite -0.98 -5.59 -4.61 -1.538 0.78769E+04 152 rhodonite 7.45 5.17 -2.28 -0.456 0.38893E+04 153 sanidine -1.28 -2.49 -1.21 -0.093 0.20677E+04 156 sillimanite 5.26 1.78 -3.48 -0.348 0.59479E+04 164 stilpnomelane-Fe 13.02 12.82 -0.20 -0.006 0.33640E+03 165 stilpnomelane-Mg 27.44 23.97 -3.48 -0.104 0.59348E+04 168 sudoite 21.08 17.38 -3.69 -0.119 0.63056E+04 171 talc 16.49 12.52 -3.98 -0.234 0.67886E+04 174 tephroite 18.09 13.63 -4.46 -0.637 0.76140E+04 177 topaz-H 4.62 1.78 -2.84 -0.258 0.48499E+04 178 tridymite -2.63 -3.29 -0.66 -0.222 0.11347E+04 187 wairakite 3.95 2.35 -1.60 -0.094 0.27319E+04 188 walstromite 11.51 7.15 -4.36 -0.871 0.74361E+04 189 wollastonite 10.46 7.15 -3.31 -0.661 0.56466E+04 190 pseudo-wollastonite 11.00 7.15 -3.85 -0.769 0.65664E+04 191 zoisite 22.85 18.62 -4.23 -0.192 0.72201E+04 192 akaganeite 7.75 6.28 -1.47 -0.318 0.25125E+04 193 beidellite-Ca -1.65 -4.45 -2.80 -0.173 0.47862E+04 194 beidellite-H -2.33 -6.17 -3.85 -0.245 0.65668E+04 195 beidellite-K -1.52 -4.57 -3.05 -0.187 0.52093E+04 196 beidellite-Mg -1.79 -4.76 -2.97 -0.184 0.50713E+04 197 beidellite-Na -1.34 -4.11 -2.77 -0.170 0.47295E+04 199 chalcedony -2.80 -3.29 -0.49 -0.163 0.83397E+03 201 montmorillonite-Ca -2.29 -4.38 -2.09 -0.129 0.35722E+04 202 montmorillonite-K -2.24 -4.51 -2.27 -0.139 0.38734E+04 203 montmorillonite-Mg -2.48 -4.69 -2.21 -0.137 0.37804E+04 204 montmorillonite-Na -2.04 -4.05 -2.01 -0.123 0.34293E+04 205 nontronite-Ca 3.21 3.05 -0.17 -0.011 0.28345E+03 206 nontronite-H 2.53 1.33 -1.21 -0.081 0.20619E+04 207 nontronite-K 3.34 2.93 -0.41 -0.027 0.70785E+03 208 nontronite-Mg 3.07 2.74 -0.34 -0.022 0.57574E+03 209 nontronite-Na 3.52 3.39 -0.13 -0.009 0.22979E+03 224 tobermorite 9.82 5.41 -4.41 -1.204 0.75354E+04 233 boehmite 4.41 2.53 -1.87 -0.312 0.31962E+04 235 ferrous-oxide 9.81 6.33 -3.48 -0.870 0.59440E+04 240 silica-amorphous -2.09 -3.29 -1.20 -0.400 0.20481E+04 242 an20ab80 2.02 0.91 -1.11 -0.085 0.18916E+04 243 an25ab75 2.65 1.41 -1.23 -0.095 0.21077E+04 244 an30ab70 3.28 1.91 -1.37 -0.105 0.23333E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 0.0400000 g Current total amount of reactant added: 1.1190000 g New total amount of reactant added: 1.1590000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.4568E-13 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 6 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 1.1590000 Water: Moles liquid = 0.5550E+02 kg liquid = 0.9998E+00 Moles total = 0.5549E+02 kg total = 0.9997E+00 Activity = 1.0000 Stoichiometric ionic strength = .1102635E-02 Osmotic coef. = 0.9808 True ionic strength = .1694705E-02 Chg. balance for total moles = 0.4568E-13 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.86157E-09 -9.0647 0.80271E-09 -9.0954 0.93168E+00 -0.0307 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13794E-03 -3.8603 0.12843E-03 -3.8913 0.93103E+00 -0.0310 4 SO4-- 0.25491E-04 -4.5936 0.20239E-04 -4.6938 0.79397E+00 -0.1002 5 HCO3- 0.11576E-04 -4.9364 0.10780E-04 -4.9674 0.93119E+00 -0.0310 6 HS- 0.40941E-13 -13.3878 0.38118E-13 -13.4189 0.93105E+00 -0.0310 7 Al+++ 0.29144E-24 -24.5355 0.17707E-24 -24.7519 0.60756E+00 -0.2164 8 H4SiO4 0.51387E-03 -3.2891 0.51387E-03 -3.2891 0.10000E+01 0.0000 9 Ca++ 0.22014E-07 -7.6573 0.17464E-07 -7.7579 0.79330E+00 -0.1006 10 Mg++ 0.29406E-09 -9.5316 0.23315E-09 -9.6324 0.79288E+00 -0.1008 11 Fe++ 0.17348E-11 -11.7608 0.13756E-11 -11.8615 0.79298E+00 -0.1007 12 K+ 0.60532E-04 -4.2180 0.56368E-04 -4.2490 0.93122E+00 -0.0309 13 Na+ 0.16000E-02 -2.7959 0.14896E-02 -2.8269 0.93102E+00 -0.0310 14 Mn++ 0.23308E-09 -9.6325 0.18485E-09 -9.7332 0.79306E+00 -0.1007 15 HPO4-- 0.71044E-05 -5.1485 0.56408E-05 -5.2487 0.79398E+00 -0.1002 16 HSiO3- 0.64204E-03 -3.1924 0.59776E-03 -3.2235 0.93103E+00 -0.0310 17 Ca(HSiO3)+ 0.25530E-09 -9.5930 0.23774E-09 -9.6239 0.93124E+00 -0.0309 18 Mg(HSiO3)+ 0.42417E-11 -11.3725 0.39501E-11 -11.4034 0.93124E+00 -0.0309 19 NaHSiO3,aq 0.14402E-04 -4.8416 0.14402E-04 -4.8416 0.10000E+01 0.0000 20 AlO+ 0.40145E-13 -13.3964 0.37385E-13 -13.4273 0.93124E+00 -0.0309 21 AlOH+2 0.18840E-18 -18.7249 0.14943E-18 -18.8256 0.79315E+00 -0.1006 22 HAlO2,aq 0.92750E-08 -8.0327 0.92750E-08 -8.0327 0.10000E+01 0.0000 23 AlO2- 0.27478E-04 -4.5610 0.25577E-04 -4.5921 0.93083E+00 -0.0311 24 CH4,aq 0.19728E-19 -19.7049 0.19722E-19 -19.7051 0.99966E+00 -0.0001 29 CO,aq 0.21905E-18 -18.6595 0.21905E-18 -18.6595 0.10000E+01 0.0000 30 CO2,aq 0.18496E-07 -7.7329 0.18490E-07 -7.7331 0.99966E+00 -0.0001 31 CO3-2 0.14777E-05 -5.8304 0.11730E-05 -5.9307 0.79377E+00 -0.1003 32 CaCO3,aq 0.25686E-09 -9.5903 0.25686E-09 -9.5903 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.51604E-11 -11.2873 0.48055E-11 -11.3183 0.93124E+00 -0.0309 34 CaCl+ 0.38977E-11 -11.4092 0.36297E-11 -11.4401 0.93124E+00 -0.0309 35 CaCl2,aq 0.11075E-15 -15.9557 0.11075E-15 -15.9557 0.10000E+01 0.0000 36 CaOH+ 0.16651E-08 -8.7786 0.15506E-08 -8.8095 0.93124E+00 -0.0309 37 CaSO4,aq 0.11224E-09 -9.9499 0.11224E-09 -9.9499 0.10000E+01 0.0000 38 HCl,aq 0.18891E-13 -13.7237 0.18891E-13 -13.7237 0.10000E+01 0.0000 43 FeCl+ 0.30029E-15 -15.5225 0.27964E-15 -15.5534 0.93124E+00 -0.0309 46 FeO,aq 0.82976E-10 -10.0810 0.82976E-10 -10.0810 0.10000E+01 0.0000 47 FeOH+ 0.59903E-10 -10.2225 0.55784E-10 -10.2535 0.93124E+00 -0.0309 48 HFeO2- 0.11617E-08 -8.9349 0.10816E-08 -8.9659 0.93103E+00 -0.0310 49 FeO+ 0.65794E-14 -14.1818 0.61270E-14 -14.2128 0.93124E+00 -0.0309 51 FeO2- 0.20899E-08 -8.6799 0.19457E-08 -8.7109 0.93103E+00 -0.0310 52 HFeO2,aq 0.19864E-09 -9.7019 0.19864E-09 -9.7019 0.10000E+01 0.0000 53 H2,aq 0.47177E-09 -9.3263 0.47160E-09 -9.3264 0.99966E+00 -0.0001 54 KCl,aq 0.13121E-09 -9.8820 0.13121E-09 -9.8820 0.10000E+01 0.0000 55 KHSO4,aq 0.25892E-17 -17.5868 0.25892E-17 -17.5868 0.10000E+01 0.0000 56 KOH,aq 0.29989E-07 -7.5230 0.29989E-07 -7.5230 0.10000E+01 0.0000 57 KSO4- 0.19014E-07 -7.7209 0.17703E-07 -7.7520 0.93103E+00 -0.0310 58 MgCO3,aq 0.85957E-12 -12.0657 0.85957E-12 -12.0657 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.70396E-13 -13.1524 0.65556E-13 -13.1834 0.93124E+00 -0.0309 60 MgCl+ 0.47163E-13 -13.3264 0.43920E-13 -13.3573 0.93124E+00 -0.0309 61 MgOH+ 0.12301E-09 -9.9101 0.11455E-09 -9.9410 0.93124E+00 -0.0309 63 MnO,aq 0.29709E-09 -9.5271 0.29709E-09 -9.5271 0.10000E+01 0.0000 64 MnOH+ 0.74775E-09 -9.1262 0.69634E-09 -9.1572 0.93124E+00 -0.0309 65 MnO2-2 0.19277E-13 -13.7150 0.15302E-13 -13.8153 0.79377E+00 -0.1003 66 HMnO2- 0.28903E-11 -11.5391 0.26910E-11 -11.5701 0.93103E+00 -0.0310 69 MnCl+ 0.15698E-12 -12.8042 0.14619E-12 -12.8351 0.93124E+00 -0.0309 70 MnSO4,aq 0.10800E-11 -11.9666 0.10800E-11 -11.9666 0.10000E+01 0.0000 71 NaCl,aq 0.63400E-07 -7.1979 0.63400E-07 -7.1979 0.10000E+01 0.0000 72 NaOH,aq 0.79732E-06 -6.0984 0.79732E-06 -6.0984 0.10000E+01 0.0000 74 OH- 0.77326E-03 -3.1117 0.71978E-03 -3.1428 0.93083E+00 -0.0311 79 HPO3-2 0.10444E-16 -16.9811 0.82901E-17 -17.0814 0.79377E+00 -0.1003 81 H2PO3- 0.14333E-19 -19.8437 0.13344E-19 -19.8747 0.93103E+00 -0.0310 82 H3PO4,aq 0.25420E-13 -13.5948 0.25420E-13 -13.5948 0.10000E+01 0.0000 83 H2PO4- 0.89706E-07 -7.0472 0.83528E-07 -7.0782 0.93113E+00 -0.0310 84 PO4-3 0.93830E-08 -8.0277 0.57334E-08 -8.2416 0.61104E+00 -0.2139 87 H2P2O7-2 0.68919E-15 -15.1617 0.54706E-15 -15.2620 0.79377E+00 -0.1003 88 HP2O7-3 0.22397E-12 -12.6498 0.13608E-12 -12.8662 0.60760E+00 -0.2164 89 P2O7-4 0.96557E-13 -13.0152 0.40500E-13 -13.3925 0.41944E+00 -0.3773 90 H2S,aq 0.94598E-16 -16.0241 0.94566E-16 -16.0243 0.99966E+00 -0.0001 97 SO3-2 0.15600E-14 -14.8069 0.12403E-14 -14.9065 0.79511E+00 -0.0996 98 HSO3- 0.66958E-16 -16.1742 0.62339E-16 -16.2052 0.93103E+00 -0.0310 99 HSO4- 0.16811E-10 -10.7744 0.15657E-10 -10.8053 0.93134E+00 -0.0309 Charge balance for all species = 0.4640E-13 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.8615706E-09 -.1541857E-02 -.1553850E+01 0.0000 2 H2O 0.1000000E+01 0.5550842E+02 0.9998400E+06 0.0000 3 Cl- 0.1379418E-03 0.1380053E-03 0.4891915E+01 5.2041 4 SO4-- 0.2549108E-04 0.2551039E-04 0.2450175E+01 13.4971 5 HCO3- 0.1157644E-04 0.1307295E-04 0.7975463E+00 4.1281 6 HS- 0.4094110E-13 -.1680797E-09 -.5557838E-05 -4.3234 7 Al+++ 0.2914390E-24 0.2748688E-04 0.7415178E+00 2.5345 8 H4SiO4 0.5138738E-03 0.1170312E-02 0.1124669E+03 -3.2891 9 Ca++ 0.2201442E-07 0.2431294E-07 0.9742572E-03 10.4330 10 Mg++ 0.2940598E-09 0.4222852E-09 0.1026495E-04 8.5585 11 Fe++ 0.1734772E-11 0.3594809E-08 0.2007270E-03 6.3294 12 K+ 0.6053164E-04 0.6058077E-04 0.2368448E+01 4.8465 13 Na+ 0.1600000E-02 0.1615263E-02 0.3712859E+02 6.2685 14 Mn++ 0.2330820E-09 0.1282073E-08 0.7042322E-04 8.4577 15 HPO4-- 0.7104428E-05 0.7203517E-05 0.6912751E+00 12.9422 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.1917828E-01 -.1541510E-02 -.1763677E-01 0.0000000E+00 2 H2O 0.5549372E+02 0.5549591E+02 -.2185251E-02 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.5762431E-04 0.2550464E-04 0.3211967E-04 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.3211984E-04 -.1680418E-09 -.3211967E-04 0.0000000E+00 7 Al+++ 0.3779200E-02 0.2748068E-04 0.3751719E-02 0.0000000E+00 8 H4SiO4 0.1206842E-01 0.1170048E-02 0.1089837E-01 0.0000000E+00 9 Ca++ 0.1347486E-02 0.2430746E-07 0.1347462E-02 0.0000000E+00 10 Mg++ 0.9198413E-03 0.4221900E-09 0.9198408E-03 0.0000000E+00 11 Fe++ 0.8263770E-03 0.3593999E-08 0.8263734E-03 0.0000000E+00 12 K+ 0.2460722E-03 0.6056711E-04 0.1855051E-03 0.0000000E+00 13 Na+ 0.1614898E-02 0.1614898E-02 0.0000000E+00 0.0000000E+00 14 Mn++ 0.2009543E-04 0.1281784E-08 0.2009415E-04 0.0000000E+00 15 HPO4-- 0.6858471E-05 0.7201893E-05 -.3434213E-06 0.0000000E+00 Chg. balance for solid moles: 0.1092E-17 Mass of aqueous solution: 0.999935E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 1.1590000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) apatite-OH -.1145E-06 1.000 -.5750E-04 1.000 -.4696E-02 -.1827E-04 clinochlore 0.1840E-03 -3.735 0.1023 -0.990 8.351 0.3890E-01 daphnite 0.1139E-03 -3.944 0.8126E-01 -1.090 6.636 0.2462E-01 chlorite-Mn 0.4019E-05 -5.396 0.2849E-02 -2.545 0.2327 0.9080E-03 hematite 0.1285E-03 -3.891 0.2052E-01 -1.688 1.676 0.3889E-02 microcline 0.5230E-04 -4.281 0.1456E-01 -1.837 1.189 0.5687E-02 muscovite 0.1332E-03 -3.875 0.5306E-01 -1.275 4.333 0.1876E-01 stilbite 0.1348E-02 -2.870 0.9500 -0.022 77.59 0.4431 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.6094E+00 0.6094E+00 1.0000 -0.215 daphnite 0.3773E+00 0.3773E+00 1.0000 -0.423 chlorite-Mn 0.1331E-01 0.1331E-01 1.0000 -1.876 hematite 0.1000E+01 0.1000E+01 1.0000 0.000 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 muscovite 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 1.224422 g Volume = 0.535835 cm3 Porosity: 63.3892% V(tot) - V(min): 0.92776E+00 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 1.1590000 g log = 0.0641 Original solution: 1000.0103000 g Original solution / Rock added: 862.82 (Water/Rock Ratio), log = 2.9359 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0203 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.1000E+01 0.9860 0.1006E+01 0.1020E+01 CO2,gas 0.1925E-05 1.0071 0.1978E-05 0.1964E-05 CH4,gas 0.2810E-16 1.0125 0.2903E-16 0.2867E-16 H2,gas 0.6065E-06 1.0005 0.6192E-06 0.6188E-06 H2S,gas 0.2558E-14 0.9960 0.2600E-14 0.2610E-14 S2,gas 0.6485E-36 1.0000 0.6617E-36 0.6617E-36 CO,gas 0.3199E-15 1.0000 0.3264E-15 0.3264E-15 SO3,gas 0.4833E-38 1.0000 0.4931E-38 0.4931E-38 SO2,gas 0.1164E-21 1.0000 0.1188E-21 0.1188E-21 HCl,gas 0.3267E-16 1.0000 0.3333E-16 0.3333E-16 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 46 clinochlore 39.07 39.07 0.00 0.000 0.00000E+00 47 daphnite 28.97 28.97 0.00 0.000 0.00000E+00 48 chlorite-Mn 46.87 46.87 0.00 0.000 -0.12132E-10 90 hematite 12.57 12.57 0.00 0.000 -0.30331E-11 116 microcline -2.49 -2.49 0.00 0.000 0.15165E-11 120 muscovite 2.58 2.58 0.00 0.000 0.60662E-11 163 stilbite -7.52 -7.52 0.00 0.000 -0.90992E-11 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -14.06 -7.40 -2.468 0.12640E+05 -5.704 3 CH4,gas 4.54 -13.69 -18.24 -4.559 0.31138E+05 -16.537 4 H2,gas 8.00 0.09 -7.91 -4.518 0.13501E+05 -6.208 5 H2S,gas -6.23 -22.51 -16.28 -8.142 0.27805E+05 -14.585 6 S2,gas -7.34 -45.21 -37.88 -5.827 0.64676E+05 -36.179 7 CO,gas 3.21 -13.97 -17.19 -5.288 0.29343E+05 -15.486 8 SO3,gas 17.12 -22.88 -40.01 -10.002 0.68309E+05 -38.307 9 SO2,gas 0.83 -22.79 -23.62 -6.300 0.40338E+05 -21.925 10 HCl,gas 5.19 -12.99 -18.18 -9.088 0.31035E+05 -16.477 11 acmite 7.71 5.97 -1.74 -0.180 0.29648E+04 15 albite-high 0.69 -1.06 -1.76 -0.135 0.30009E+04 16 albite -0.38 -1.06 -0.68 -0.052 0.11621E+04 19 spessartine 24.46 20.57 -3.88 -0.194 0.66297E+04 20 analcite 3.32 2.22 -1.10 -0.122 0.18734E+04 21 andalusite 5.00 1.78 -3.22 -0.322 0.55010E+04 26 annite 20.12 16.50 -3.62 -0.201 0.61840E+04 27 phlogopite 27.06 23.19 -3.88 -0.215 0.66173E+04 29 anorthite 12.71 8.92 -3.79 -0.291 0.64656E+04 32 apatite-OH -18.15 -18.15 0.00 0.000 -0.60662E-11 35 aragonite 0.97 -3.63 -4.60 -1.532 0.78481E+04 36 brucite 12.57 8.56 -4.01 -0.802 0.68470E+04 37 calcite 0.81 -3.63 -4.44 -1.481 0.75839E+04 38 carnegieite-low 9.02 5.51 -3.51 -0.501 0.59923E+04 39 carnegieite-high 10.09 5.51 -4.58 -0.654 0.78193E+04 40 carpholite-Mg 8.58 7.05 -1.53 -0.102 0.26174E+04 41 carpholite-Fe 6.71 4.82 -1.89 -0.126 0.32316E+04 42 celadonite 5.34 2.78 -2.56 -0.151 0.43689E+04 43 celadonite-Fe 3.88 0.55 -3.32 -0.195 0.56735E+04 44 chrysotile 23.89 19.10 -4.80 -0.400 0.81875E+04 50 chloritoid-Mg 13.20 10.34 -2.86 -0.191 0.48823E+04 51 chloritoid-Fe 9.17 8.11 -1.06 -0.071 0.18175E+04 52 chloritoid-Mn 11.40 10.24 -1.16 -0.078 0.19868E+04 54 coesite -2.38 -3.29 -0.91 -0.304 0.15591E+04 59 corundum 8.38 5.07 -3.31 -0.301 0.56589E+04 61 cristobalite -2.56 -3.29 -0.73 -0.243 0.12444E+04 63 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71234E+04 65 diaspore 2.87 2.53 -0.34 -0.057 0.57923E+03 67 diopside 16.18 12.41 -3.77 -0.377 0.64339E+04 68 hedenbergite 14.21 10.18 -4.02 -0.402 0.68711E+04 75 epidote 24.67 22.35 -2.32 -0.112 0.39601E+04 76 clinozoisite 22.81 18.60 -4.20 -0.191 0.71782E+04 77 epidote-Fe 29.84 26.10 -3.74 -0.194 0.63886E+04 78 fayalite 14.05 9.37 -4.68 -0.668 0.79843E+04 83 gibbsite 4.08 2.53 -1.54 -0.221 0.26378E+04 87 greenalite 16.14 12.41 -3.73 -0.311 0.63682E+04 91 heulandite -5.83 -7.52 -1.69 -0.077 0.28938E+04 95 jadeite 4.22 2.22 -1.99 -0.199 0.33989E+04 97 kalsilite 7.58 4.09 -3.49 -0.499 0.59627E+04 98 kaolinite -1.33 -1.51 -0.18 -0.016 0.30153E+03 99 kyanite 4.88 1.78 -3.10 -0.310 0.52869E+04 101 laumontite 2.88 2.35 -0.54 -0.036 0.91868E+03 102 lawsonite 9.62 8.92 -0.69 -0.046 0.11823E+04 103 leucite 4.12 0.80 -3.32 -0.332 0.56623E+04 105 lizardite 23.24 19.10 -4.15 -0.346 0.70801E+04 107 magnetite 20.09 18.90 -1.19 -0.097 0.20350E+04 108 minnesotaite 10.39 5.83 -4.56 -0.268 0.77801E+04 113 margarite 17.32 13.99 -3.33 -0.133 0.56876E+04 121 paragonite 4.24 4.00 -0.23 -0.014 0.40118E+03 122 nepheline 8.34 5.51 -2.83 -0.404 0.48247E+04 136 prehnite 19.37 16.07 -3.30 -0.194 0.56421E+04 137 prehnite-Fe 22.50 19.82 -2.68 -0.161 0.45789E+04 145 pyroxmangite 7.40 5.17 -2.23 -0.446 0.38079E+04 146 pyrophyllite -6.18 -8.09 -1.91 -0.119 0.32644E+04 147 quartz -2.99 -3.29 -0.30 -0.100 0.51174E+03 151 rhodochrosite -0.98 -5.61 -4.63 -1.543 0.79036E+04 152 rhodonite 7.45 5.17 -2.28 -0.455 0.38881E+04 153 sanidine -1.28 -2.49 -1.21 -0.093 0.20677E+04 156 sillimanite 5.26 1.78 -3.48 -0.348 0.59450E+04 164 stilpnomelane-Fe 13.02 12.83 -0.19 -0.006 0.32615E+03 165 stilpnomelane-Mg 27.44 23.97 -3.47 -0.104 0.59245E+04 168 sudoite 21.08 17.39 -3.69 -0.119 0.63004E+04 171 talc 16.49 12.52 -3.97 -0.234 0.67822E+04 174 tephroite 18.09 13.63 -4.46 -0.637 0.76145E+04 177 topaz-H 4.62 1.78 -2.84 -0.258 0.48470E+04 178 tridymite -2.63 -3.29 -0.66 -0.221 0.11317E+04 187 wairakite 3.95 2.35 -1.61 -0.094 0.27406E+04 188 walstromite 11.51 7.14 -4.37 -0.873 0.74537E+04 189 wollastonite 10.46 7.14 -3.32 -0.663 0.56641E+04 190 pseudo-wollastonite 11.00 7.14 -3.86 -0.771 0.65840E+04 191 zoisite 22.85 18.60 -4.25 -0.193 0.72523E+04 192 akaganeite 7.75 6.28 -1.47 -0.318 0.25125E+04 193 beidellite-Ca -1.65 -4.44 -2.80 -0.173 0.47789E+04 194 beidellite-H -2.33 -6.17 -3.84 -0.245 0.65561E+04 195 beidellite-K -1.52 -4.57 -3.05 -0.187 0.52015E+04 196 beidellite-Mg -1.79 -4.75 -2.96 -0.183 0.50608E+04 197 beidellite-Na -1.34 -4.10 -2.76 -0.169 0.47041E+04 199 chalcedony -2.80 -3.29 -0.49 -0.162 0.83104E+03 201 montmorillonite-Ca -2.29 -4.38 -2.09 -0.129 0.35644E+04 202 montmorillonite-K -2.24 -4.50 -2.26 -0.139 0.38651E+04 203 montmorillonite-Mg -2.48 -4.69 -2.21 -0.137 0.37695E+04 204 montmorillonite-Na -2.04 -4.03 -1.99 -0.122 0.34035E+04 205 nontronite-Ca 3.21 3.05 -0.16 -0.010 0.27608E+03 206 nontronite-H 2.53 1.33 -1.20 -0.081 0.20512E+04 207 nontronite-K 3.34 2.93 -0.41 -0.026 0.70000E+03 208 nontronite-Mg 3.07 2.74 -0.33 -0.021 0.56528E+03 209 nontronite-Na 3.52 3.40 -0.12 -0.008 0.20437E+03 224 tobermorite 9.82 5.40 -4.42 -1.206 0.75496E+04 233 boehmite 4.41 2.53 -1.87 -0.312 0.31962E+04 235 ferrous-oxide 9.81 6.33 -3.48 -0.871 0.59458E+04 240 silica-amorphous -2.09 -3.29 -1.20 -0.399 0.20452E+04 242 an20ab80 2.02 0.93 -1.08 -0.083 0.18519E+04 243 an25ab75 2.65 1.43 -1.21 -0.093 0.20714E+04 244 an30ab70 3.28 1.93 -1.35 -0.104 0.23004E+04 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 6 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 1.1590000 Water: Moles liquid = 0.5550E+02 kg liquid = 0.9998E+00 Moles total = 0.5549E+02 kg total = 0.9997E+00 Activity = 1.0000 Stoichiometric ionic strength = .1101578E-02 Osmotic coef. = 0.9808 True ionic strength = .1693882E-02 Chg. balance for total moles = 0.4568E-13 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.86254E-09 -9.0642 0.80362E-09 -9.0949 0.93169E+00 -0.0307 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13794E-03 -3.8603 0.12843E-03 -3.8913 0.93104E+00 -0.0310 4 SO4-- 0.25491E-04 -4.5936 0.20240E-04 -4.6938 0.79401E+00 -0.1002 5 HCO3- 0.11578E-04 -4.9364 0.10781E-04 -4.9673 0.93120E+00 -0.0310 6 HS- 0.40424E-13 -13.3934 0.37637E-13 -13.4244 0.93106E+00 -0.0310 7 Al+++ 0.29240E-24 -24.5340 0.17767E-24 -24.7504 0.60763E+00 -0.2164 8 H4SiO4 0.51536E-03 -3.2879 0.51536E-03 -3.2879 0.10000E+01 0.0000 9 Ca++ 0.21621E-07 -7.6651 0.17153E-07 -7.7657 0.79334E+00 -0.1005 10 Mg++ 0.29420E-09 -9.5314 0.23328E-09 -9.6321 0.79292E+00 -0.1008 11 Fe++ 0.17356E-11 -11.7605 0.13764E-11 -11.8613 0.79302E+00 -0.1007 12 K+ 0.60076E-04 -4.2213 0.55944E-04 -4.2522 0.93123E+00 -0.0309 13 Na+ 0.16000E-02 -2.7959 0.14896E-02 -2.8269 0.93103E+00 -0.0310 14 Mn++ 0.23320E-09 -9.6323 0.18495E-09 -9.7330 0.79310E+00 -0.1007 15 HPO4-- 0.67656E-05 -5.1697 0.53720E-05 -5.2699 0.79402E+00 -0.1002 16 HSiO3- 0.64316E-03 -3.1917 0.59881E-03 -3.2227 0.93104E+00 -0.0310 17 Ca(HSiO3)+ 0.25118E-09 -9.6000 0.23392E-09 -9.6309 0.93125E+00 -0.0309 18 Mg(HSiO3)+ 0.42514E-11 -11.3715 0.39591E-11 -11.4024 0.93125E+00 -0.0309 19 NaHSiO3,aq 0.14427E-04 -4.8408 0.14427E-04 -4.8408 0.10000E+01 0.0000 20 AlO+ 0.40191E-13 -13.3959 0.37427E-13 -13.4268 0.93125E+00 -0.0309 21 AlOH+2 0.18882E-18 -18.7240 0.14977E-18 -18.8246 0.79319E+00 -0.1006 22 HAlO2,aq 0.92750E-08 -8.0327 0.92750E-08 -8.0327 0.10000E+01 0.0000 23 AlO2- 0.27446E-04 -4.5615 0.25548E-04 -4.5926 0.93085E+00 -0.0311 24 CH4,aq 0.19481E-19 -19.7104 0.19474E-19 -19.7105 0.99966E+00 -0.0001 29 CO,aq 0.21857E-18 -18.6604 0.21857E-18 -18.6604 0.10000E+01 0.0000 30 CO2,aq 0.18520E-07 -7.7324 0.18513E-07 -7.7325 0.99966E+00 -0.0001 31 CO3-2 0.14762E-05 -5.8309 0.11718E-05 -5.9311 0.79381E+00 -0.1003 32 CaCO3,aq 0.25203E-09 -9.5985 0.25203E-09 -9.5985 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.50691E-11 -11.2951 0.47206E-11 -11.3260 0.93125E+00 -0.0309 34 CaCl+ 0.38282E-11 -11.4170 0.35650E-11 -11.4479 0.93125E+00 -0.0309 35 CaCl2,aq 0.10878E-15 -15.9635 0.10878E-15 -15.9635 0.10000E+01 0.0000 36 CaOH+ 0.16335E-08 -8.7869 0.15212E-08 -8.8178 0.93125E+00 -0.0309 37 CaSO4,aq 0.11024E-09 -9.9576 0.11024E-09 -9.9576 0.10000E+01 0.0000 38 HCl,aq 0.18913E-13 -13.7232 0.18913E-13 -13.7232 0.10000E+01 0.0000 43 FeCl+ 0.30045E-15 -15.5222 0.27979E-15 -15.5532 0.93125E+00 -0.0309 46 FeO,aq 0.82832E-10 -10.0818 0.82832E-10 -10.0818 0.10000E+01 0.0000 47 FeOH+ 0.59867E-10 -10.2228 0.55751E-10 -10.2537 0.93125E+00 -0.0309 48 HFeO2- 0.11583E-08 -8.9362 0.10785E-08 -8.9672 0.93104E+00 -0.0310 49 FeO+ 0.65868E-14 -14.1813 0.61340E-14 -14.2123 0.93125E+00 -0.0309 51 FeO2- 0.20875E-08 -8.6804 0.19435E-08 -8.7114 0.93104E+00 -0.0310 52 HFeO2,aq 0.19864E-09 -9.7019 0.19864E-09 -9.7019 0.10000E+01 0.0000 53 H2,aq 0.47013E-09 -9.3278 0.46997E-09 -9.3279 0.99966E+00 -0.0001 54 KCl,aq 0.13022E-09 -9.8853 0.13022E-09 -9.8853 0.10000E+01 0.0000 55 KHSO4,aq 0.25728E-17 -17.5896 0.25728E-17 -17.5896 0.10000E+01 0.0000 56 KOH,aq 0.29730E-07 -7.5268 0.29730E-07 -7.5268 0.10000E+01 0.0000 57 KSO4- 0.18872E-07 -7.7242 0.17571E-07 -7.7552 0.93104E+00 -0.0310 58 MgCO3,aq 0.85917E-12 -12.0659 0.85917E-12 -12.0659 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.70443E-13 -13.1522 0.65600E-13 -13.1831 0.93125E+00 -0.0309 60 MgCl+ 0.47188E-13 -13.3262 0.43944E-13 -13.3571 0.93125E+00 -0.0309 61 MgOH+ 0.12293E-09 -9.9103 0.11448E-09 -9.9413 0.93125E+00 -0.0309 63 MnO,aq 0.29658E-09 -9.5279 0.29658E-09 -9.5279 0.10000E+01 0.0000 64 MnOH+ 0.74730E-09 -9.1265 0.69592E-09 -9.1574 0.93125E+00 -0.0309 65 MnO2-2 0.19199E-13 -13.7167 0.15241E-13 -13.8170 0.79381E+00 -0.1003 66 HMnO2- 0.28820E-11 -11.5403 0.26833E-11 -11.5713 0.93104E+00 -0.0310 69 MnCl+ 0.15707E-12 -12.8039 0.14627E-12 -12.8349 0.93125E+00 -0.0309 70 MnSO4,aq 0.10807E-11 -11.9663 0.10807E-11 -11.9663 0.10000E+01 0.0000 71 NaCl,aq 0.63401E-07 -7.1979 0.63401E-07 -7.1979 0.10000E+01 0.0000 72 NaOH,aq 0.79641E-06 -6.0989 0.79641E-06 -6.0989 0.10000E+01 0.0000 74 OH- 0.77237E-03 -3.1122 0.71896E-03 -3.1433 0.93085E+00 -0.0311 79 HPO3-2 0.99114E-17 -17.0039 0.78677E-17 -17.1041 0.79381E+00 -0.1003 81 H2PO3- 0.13618E-19 -19.8659 0.12679E-19 -19.8969 0.93104E+00 -0.0310 82 H3PO4,aq 0.24264E-13 -13.6150 0.24264E-13 -13.6150 0.10000E+01 0.0000 83 H2PO4- 0.85527E-07 -7.0679 0.79638E-07 -7.0989 0.93114E+00 -0.0310 84 PO4-3 0.89247E-08 -8.0494 0.54540E-08 -8.2633 0.61111E+00 -0.2139 87 H2P2O7-2 0.62646E-15 -15.2031 0.49729E-15 -15.3034 0.79381E+00 -0.1003 88 HP2O7-3 0.20334E-12 -12.6918 0.12356E-12 -12.9081 0.60767E+00 -0.2163 89 P2O7-4 0.87557E-13 -13.0577 0.36732E-13 -13.4350 0.41952E+00 -0.3772 90 H2S,aq 0.93511E-16 -16.0291 0.93479E-16 -16.0293 0.99966E+00 -0.0001 97 SO3-2 0.15546E-14 -14.8084 0.12361E-14 -14.9079 0.79515E+00 -0.0996 98 HSO3- 0.66804E-16 -16.1752 0.62197E-16 -16.2062 0.93104E+00 -0.0310 99 HSO4- 0.16831E-10 -10.7739 0.15675E-10 -10.8048 0.93135E+00 -0.0309 Charge balance for all species = 0.4569E-13 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.8625387E-09 -.1541993E-02 -.1553986E+01 0.0000 2 H2O 0.1000000E+01 0.5550842E+02 0.9998398E+06 0.0000 3 Cl- 0.1379418E-03 0.1380053E-03 0.4891914E+01 5.2036 4 SO4-- 0.2549122E-04 0.2551039E-04 0.2450174E+01 13.4961 5 HCO3- 0.1157796E-04 0.1307295E-04 0.7975462E+00 4.1276 6 HS- 0.4042402E-13 -.1681895E-09 -.5561468E-05 -4.3294 7 Al+++ 0.2924009E-24 0.2745537E-04 0.7406677E+00 2.5345 8 H4SiO4 0.5153627E-03 0.1172948E-02 0.1127203E+03 -3.2879 9 Ca++ 0.2162103E-07 0.2387691E-07 0.9567846E-03 10.4242 10 Mg++ 0.2942024E-09 0.4223618E-09 0.1026681E-04 8.5578 11 Fe++ 0.1735614E-11 0.3588889E-08 0.2003964E-03 6.3286 12 K+ 0.6007594E-04 0.6012467E-04 0.2350616E+01 4.8427 13 Na+ 0.1599976E-02 0.1615263E-02 0.3712858E+02 6.2680 14 Mn++ 0.2331950E-09 0.1281205E-08 0.7037552E-04 8.4569 15 HPO4-- 0.6765566E-05 0.6860018E-05 0.6583116E+00 12.9200 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.1917828E-01 -.1541645E-02 -.1763663E-01 0.0000000E+00 2 H2O 0.5549372E+02 0.5549591E+02 -.2183806E-02 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.5762431E-04 0.2550464E-04 0.3211967E-04 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.3211984E-04 -.1681516E-09 -.3211967E-04 0.0000000E+00 7 Al+++ 0.3779200E-02 0.2744918E-04 0.3751750E-02 0.0000000E+00 8 H4SiO4 0.1206842E-01 0.1172684E-02 0.1089573E-01 0.0000000E+00 9 Ca++ 0.1347486E-02 0.2387152E-07 0.1347463E-02 0.0000000E+00 10 Mg++ 0.9198413E-03 0.4222665E-09 0.9198408E-03 0.0000000E+00 11 Fe++ 0.8263770E-03 0.3588080E-08 0.8263734E-03 0.0000000E+00 12 K+ 0.2460722E-03 0.6011112E-04 0.1859611E-03 0.0000000E+00 13 Na+ 0.1614898E-02 0.1614898E-02 0.0000000E+00 0.0000000E+00 14 Mn++ 0.2009543E-04 0.1280916E-08 0.2009415E-04 0.0000000E+00 15 HPO4-- 0.6858471E-05 0.6858471E-05 0.0000000E+00 0.0000000E+00 Chg. balance for solid moles: 0.3890E-17 Mass of aqueous solution: 0.999936E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 1.1590000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) clinochlore 0.1840E-03 -3.735 0.1023 -0.990 8.352 0.3890E-01 daphnite 0.1139E-03 -3.944 0.8126E-01 -1.090 6.637 0.2462E-01 chlorite-Mn 0.4019E-05 -5.396 0.2849E-02 -2.545 0.2327 0.9080E-03 hematite 0.1285E-03 -3.891 0.2052E-01 -1.688 1.676 0.3889E-02 microcline 0.5240E-04 -4.281 0.1458E-01 -1.836 1.191 0.5697E-02 muscovite 0.1336E-03 -3.874 0.5320E-01 -1.274 4.345 0.1881E-01 stilbite 0.1347E-02 -2.870 0.9496 -0.022 77.56 0.4429 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity clinochlore 0.6094E+00 0.6094E+00 1.0000 -0.215 daphnite 0.3773E+00 0.3773E+00 1.0000 -0.423 chlorite-Mn 0.1331E-01 0.1331E-01 1.0000 -1.876 hematite 0.1000E+01 0.1000E+01 1.0000 0.000 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 muscovite 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 1.224247 g Volume = 0.535727 cm3 Porosity: 63.3966% V(tot) - V(min): 0.92787E+00 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 1.1590000 g log = 0.0641 Original solution: 1000.0103000 g Original solution / Rock added: 862.82 (Water/Rock Ratio), log = 2.9359 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0203 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.1000E+01 0.9860 0.1006E+01 0.1020E+01 CO2,gas 0.1928E-05 1.0071 0.1981E-05 0.1967E-05 CH4,gas 0.2775E-16 1.0125 0.2867E-16 0.2831E-16 H2,gas 0.6044E-06 1.0005 0.6170E-06 0.6167E-06 H2S,gas 0.2529E-14 0.9960 0.2570E-14 0.2580E-14 S2,gas 0.6381E-36 1.0000 0.6510E-36 0.6510E-36 CO,gas 0.3192E-15 1.0000 0.3257E-15 0.3257E-15 SO3,gas 0.4844E-38 1.0000 0.4942E-38 0.4942E-38 SO2,gas 0.1163E-21 1.0000 0.1186E-21 0.1186E-21 HCl,gas 0.3271E-16 1.0000 0.3337E-16 0.3337E-16 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 46 clinochlore 39.07 39.07 0.00 0.000 -0.12132E-10 47 daphnite 28.97 28.97 0.00 0.000 -0.48529E-10 48 chlorite-Mn 46.87 46.87 0.00 0.000 -0.24265E-10 90 hematite 12.57 12.57 0.00 0.000 0.15165E-10 116 microcline -2.49 -2.49 0.00 0.000 0.15165E-11 120 muscovite 2.58 2.58 0.00 0.000 0.60662E-11 163 stilbite -7.52 -7.52 0.00 0.000 -0.90992E-11 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -14.06 -7.40 -2.467 0.12639E+05 -5.703 3 CH4,gas 4.54 -13.70 -18.24 -4.560 0.31147E+05 -16.543 4 H2,gas 8.00 0.09 -7.91 -4.519 0.13504E+05 -6.210 5 H2S,gas -6.23 -22.52 -16.29 -8.145 0.27813E+05 -14.590 6 S2,gas -7.34 -45.22 -37.89 -5.829 0.64688E+05 -36.186 7 CO,gas 3.21 -13.97 -17.19 -5.288 0.29345E+05 -15.487 8 SO3,gas 17.12 -22.88 -40.01 -10.001 0.68308E+05 -38.306 9 SO2,gas 0.83 -22.79 -23.62 -6.300 0.40339E+05 -21.926 10 HCl,gas 5.19 -12.99 -18.18 -9.088 0.31034E+05 -16.477 11 acmite 7.71 5.98 -1.73 -0.180 0.29614E+04 15 albite-high 0.69 -1.06 -1.75 -0.135 0.29953E+04 16 albite -0.38 -1.06 -0.68 -0.052 0.11565E+04 19 spessartine 24.46 20.58 -3.88 -0.194 0.66271E+04 20 analcite 3.32 2.23 -1.10 -0.122 0.18699E+04 21 andalusite 5.00 1.78 -3.22 -0.322 0.54989E+04 26 annite 20.12 16.50 -3.62 -0.201 0.61879E+04 27 phlogopite 27.06 23.19 -3.88 -0.215 0.66212E+04 29 anorthite 12.71 8.92 -3.79 -0.292 0.64763E+04 32 apatite-OH -18.15 -18.26 -0.10 -0.008 0.17866E+03 35 aragonite 0.97 -3.64 -4.60 -1.535 0.78622E+04 36 brucite 12.57 8.56 -4.01 -0.802 0.68483E+04 37 calcite 0.81 -3.64 -4.45 -1.483 0.75979E+04 38 carnegieite-low 9.02 5.51 -3.51 -0.501 0.59910E+04 39 carnegieite-high 10.09 5.51 -4.58 -0.654 0.78180E+04 40 carpholite-Mg 8.58 7.05 -1.53 -0.102 0.26144E+04 41 carpholite-Fe 6.71 4.82 -1.89 -0.126 0.32286E+04 42 celadonite 5.34 2.78 -2.56 -0.150 0.43681E+04 43 celadonite-Fe 3.88 0.55 -3.32 -0.195 0.56727E+04 44 chrysotile 23.89 19.10 -4.79 -0.400 0.81871E+04 50 chloritoid-Mg 13.20 10.34 -2.86 -0.191 0.48815E+04 51 chloritoid-Fe 9.17 8.11 -1.06 -0.071 0.18167E+04 52 chloritoid-Mn 11.40 10.24 -1.16 -0.078 0.19859E+04 54 coesite -2.38 -3.29 -0.91 -0.304 0.15569E+04 59 corundum 8.38 5.07 -3.31 -0.301 0.56589E+04 61 cristobalite -2.56 -3.29 -0.73 -0.243 0.12423E+04 63 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71234E+04 65 diaspore 2.87 2.53 -0.34 -0.057 0.57923E+03 67 diopside 16.18 12.41 -3.78 -0.378 0.64459E+04 68 hedenbergite 14.21 10.18 -4.03 -0.403 0.68831E+04 75 epidote 24.67 22.34 -2.33 -0.113 0.39837E+04 76 clinozoisite 22.81 18.59 -4.22 -0.192 0.72018E+04 77 epidote-Fe 29.84 26.09 -3.76 -0.195 0.64122E+04 78 fayalite 14.05 9.37 -4.68 -0.668 0.79847E+04 83 gibbsite 4.08 2.53 -1.54 -0.221 0.26378E+04 87 greenalite 16.14 12.41 -3.73 -0.311 0.63678E+04 91 heulandite -5.83 -7.52 -1.69 -0.077 0.28938E+04 95 jadeite 4.22 2.23 -1.99 -0.199 0.33954E+04 97 kalsilite 7.58 4.09 -3.49 -0.499 0.59670E+04 98 kaolinite -1.33 -1.51 -0.17 -0.016 0.29724E+03 99 kyanite 4.88 1.78 -3.10 -0.310 0.52848E+04 101 laumontite 2.88 2.34 -0.54 -0.036 0.92511E+03 102 lawsonite 9.62 8.92 -0.70 -0.047 0.11930E+04 103 leucite 4.12 0.80 -3.32 -0.332 0.56645E+04 105 lizardite 23.24 19.10 -4.15 -0.346 0.70797E+04 107 magnetite 20.09 18.89 -1.19 -0.097 0.20363E+04 108 minnesotaite 10.39 5.83 -4.55 -0.268 0.77754E+04 113 margarite 17.32 13.99 -3.34 -0.133 0.56984E+04 121 paragonite 4.24 4.01 -0.23 -0.014 0.39559E+03 122 nepheline 8.34 5.51 -2.82 -0.404 0.48234E+04 136 prehnite 19.37 16.05 -3.32 -0.195 0.56657E+04 137 prehnite-Fe 22.50 19.80 -2.70 -0.162 0.46025E+04 145 pyroxmangite 7.40 5.17 -2.23 -0.446 0.38070E+04 146 pyrophyllite -6.18 -8.08 -1.91 -0.119 0.32559E+04 147 quartz -2.99 -3.29 -0.30 -0.099 0.50960E+03 151 rhodochrosite -0.98 -5.61 -4.63 -1.543 0.79039E+04 152 rhodonite 7.45 5.17 -2.28 -0.455 0.38873E+04 153 sanidine -1.28 -2.49 -1.21 -0.093 0.20677E+04 156 sillimanite 5.26 1.78 -3.48 -0.348 0.59428E+04 164 stilpnomelane-Fe 13.02 12.83 -0.19 -0.006 0.31864E+03 165 stilpnomelane-Mg 27.44 23.98 -3.47 -0.103 0.59170E+04 168 sudoite 21.08 17.39 -3.69 -0.119 0.62965E+04 171 talc 16.49 12.52 -3.97 -0.233 0.67775E+04 174 tephroite 18.09 13.63 -4.46 -0.637 0.76150E+04 177 topaz-H 4.62 1.78 -2.84 -0.258 0.48449E+04 178 tridymite -2.63 -3.29 -0.66 -0.221 0.11296E+04 187 wairakite 3.95 2.34 -1.61 -0.095 0.27471E+04 188 walstromite 11.51 7.14 -4.37 -0.875 0.74666E+04 189 wollastonite 10.46 7.14 -3.32 -0.665 0.56770E+04 190 pseudo-wollastonite 11.00 7.14 -3.86 -0.773 0.65968E+04 191 zoisite 22.85 18.59 -4.26 -0.194 0.72759E+04 192 akaganeite 7.75 6.28 -1.47 -0.318 0.25125E+04 193 beidellite-Ca -1.65 -4.44 -2.80 -0.173 0.47735E+04 194 beidellite-H -2.33 -6.16 -3.84 -0.245 0.65482E+04 195 beidellite-K -1.52 -4.56 -3.04 -0.186 0.51957E+04 196 beidellite-Mg -1.79 -4.75 -2.96 -0.183 0.50532E+04 197 beidellite-Na -1.34 -4.09 -2.75 -0.168 0.46965E+04 199 chalcedony -2.80 -3.29 -0.49 -0.162 0.82890E+03 201 montmorillonite-Ca -2.29 -4.37 -2.08 -0.129 0.35587E+04 202 montmorillonite-K -2.24 -4.50 -2.26 -0.138 0.38591E+04 203 montmorillonite-Mg -2.48 -4.68 -2.20 -0.136 0.37616E+04 204 montmorillonite-Na -2.04 -4.03 -1.99 -0.122 0.33956E+04 205 nontronite-Ca 3.21 3.06 -0.16 -0.010 0.27069E+03 206 nontronite-H 2.53 1.34 -1.20 -0.080 0.20433E+04 207 nontronite-K 3.34 2.93 -0.41 -0.026 0.69425E+03 208 nontronite-Mg 3.07 2.75 -0.33 -0.021 0.55762E+03 209 nontronite-Na 3.52 3.40 -0.12 -0.007 0.19677E+03 224 tobermorite 9.82 5.40 -4.43 -1.208 0.75599E+04 233 boehmite 4.41 2.53 -1.87 -0.312 0.31962E+04 235 ferrous-oxide 9.81 6.33 -3.48 -0.871 0.59470E+04 240 silica-amorphous -2.09 -3.29 -1.20 -0.399 0.20431E+04 242 an20ab80 2.02 0.93 -1.08 -0.083 0.18496E+04 243 an25ab75 2.65 1.43 -1.21 -0.093 0.20699E+04 244 an30ab70 3.28 1.93 -1.35 -0.104 0.22997E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 0.0400000 g Current total amount of reactant added: 1.1590000 g New total amount of reactant added: 1.1990000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.4568E-13 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 6 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 1.1990000 Water: Moles liquid = 0.5550E+02 kg liquid = 0.9998E+00 Moles total = 0.5549E+02 kg total = 0.9997E+00 Activity = 1.0000 Stoichiometric ionic strength = .1129102E-02 Osmotic coef. = 0.9806 True ionic strength = .1740375E-02 Chg. balance for total moles = 0.4568E-13 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.84033E-09 -9.0755 0.78241E-09 -9.1066 0.93107E+00 -0.0310 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13794E-03 -3.8603 0.12834E-03 -3.8916 0.93040E+00 -0.0313 4 SO4-- 0.25492E-04 -4.5936 0.20186E-04 -4.6949 0.79185E+00 -0.1014 5 HCO3- 0.11540E-04 -4.9378 0.10739E-04 -4.9690 0.93056E+00 -0.0313 6 HS- 0.37733E-13 -13.4233 0.35107E-13 -13.4546 0.93042E+00 -0.0313 7 Al+++ 0.27152E-24 -24.5662 0.16397E-24 -24.7852 0.60390E+00 -0.2190 8 H4SiO4 0.51969E-03 -3.2843 0.51969E-03 -3.2843 0.10000E+01 0.0000 9 Ca++ 0.19382E-07 -7.7126 0.15334E-07 -7.8143 0.79117E+00 -0.1017 10 Mg++ 0.27824E-09 -9.5556 0.22002E-09 -9.6575 0.79074E+00 -0.1020 11 Fe++ 0.16415E-11 -11.7848 0.12981E-11 -11.8867 0.79084E+00 -0.1019 12 K+ 0.57079E-04 -4.2435 0.53117E-04 -4.2748 0.93059E+00 -0.0312 13 Na+ 0.16492E-02 -2.7827 0.15344E-02 -2.8141 0.93038E+00 -0.0313 14 Mn++ 0.22055E-09 -9.6565 0.17443E-09 -9.7584 0.79092E+00 -0.1019 15 HPO4-- 0.70013E-05 -5.1548 0.55441E-05 -5.2562 0.79186E+00 -0.1014 16 HSiO3- 0.66661E-03 -3.1761 0.62021E-03 -3.2075 0.93040E+00 -0.0313 17 Ca(HSiO3)+ 0.23274E-09 -9.6331 0.21659E-09 -9.6644 0.93061E+00 -0.0312 18 Mg(HSiO3)+ 0.41559E-11 -11.3813 0.38675E-11 -11.4126 0.93061E+00 -0.0312 19 NaHSiO3,aq 0.15392E-04 -4.8127 0.15392E-04 -4.8127 0.10000E+01 0.0000 20 AlO+ 0.39156E-13 -13.4072 0.36439E-13 -13.4384 0.93061E+00 -0.0312 21 AlOH+2 0.17947E-18 -18.7460 0.14196E-18 -18.8478 0.79101E+00 -0.1018 22 HAlO2,aq 0.92750E-08 -8.0327 0.92750E-08 -8.0327 0.10000E+01 0.0000 23 AlO2- 0.28210E-04 -4.5496 0.26241E-04 -4.5810 0.93020E+00 -0.0314 24 CH4,aq 0.18149E-19 -19.7412 0.18143E-19 -19.7413 0.99965E+00 -0.0002 29 CO,aq 0.20985E-18 -18.6781 0.20985E-18 -18.6781 0.10000E+01 0.0000 30 CO2,aq 0.17960E-07 -7.7457 0.17954E-07 -7.7458 0.99965E+00 -0.0002 31 CO3-2 0.15144E-05 -5.8198 0.11989E-05 -5.9212 0.79165E+00 -0.1015 32 CaCO3,aq 0.23052E-09 -9.6373 0.23052E-09 -9.6373 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.45170E-11 -11.3452 0.42035E-11 -11.3764 0.93061E+00 -0.0312 34 CaCl+ 0.34223E-11 -11.4657 0.31849E-11 -11.4969 0.93061E+00 -0.0312 35 CaCl2,aq 0.97109E-16 -16.0127 0.97109E-16 -16.0127 0.10000E+01 0.0000 36 CaOH+ 0.15010E-08 -8.8236 0.13968E-08 -8.8549 0.93061E+00 -0.0312 37 CaSO4,aq 0.98294E-10 -10.0075 0.98294E-10 -10.0075 0.10000E+01 0.0000 38 HCl,aq 0.18401E-13 -13.7352 0.18401E-13 -13.7352 0.10000E+01 0.0000 43 FeCl+ 0.28337E-15 -15.5477 0.26371E-15 -15.5789 0.93061E+00 -0.0312 46 FeO,aq 0.82417E-10 -10.0840 0.82417E-10 -10.0840 0.10000E+01 0.0000 47 FeOH+ 0.58034E-10 -10.2363 0.54007E-10 -10.2675 0.93061E+00 -0.0312 48 HFeO2- 0.11846E-08 -8.9264 0.11022E-08 -8.9578 0.93040E+00 -0.0313 49 FeO+ 0.64173E-14 -14.1926 0.59720E-14 -14.2239 0.93061E+00 -0.0312 51 FeO2- 0.21455E-08 -8.6685 0.19962E-08 -8.6998 0.93040E+00 -0.0313 52 HFeO2,aq 0.19864E-09 -9.7019 0.19864E-09 -9.7019 0.10000E+01 0.0000 53 H2,aq 0.46544E-09 -9.3321 0.46528E-09 -9.3323 0.99965E+00 -0.0002 54 KCl,aq 0.12355E-09 -9.9081 0.12355E-09 -9.9081 0.10000E+01 0.0000 55 KHSO4,aq 0.23720E-17 -17.6249 0.23720E-17 -17.6249 0.10000E+01 0.0000 56 KOH,aq 0.28993E-07 -7.5377 0.28993E-07 -7.5377 0.10000E+01 0.0000 57 KSO4- 0.17883E-07 -7.7476 0.16638E-07 -7.7789 0.93040E+00 -0.0313 58 MgCO3,aq 0.82904E-12 -12.0814 0.82904E-12 -12.0814 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.66224E-13 -13.1790 0.61628E-13 -13.2102 0.93061E+00 -0.0312 60 MgCl+ 0.44505E-13 -13.3516 0.41417E-13 -13.3828 0.93061E+00 -0.0312 61 MgOH+ 0.11917E-09 -9.9238 0.11090E-09 -9.9551 0.93061E+00 -0.0312 63 MnO,aq 0.29509E-09 -9.5300 0.29509E-09 -9.5300 0.10000E+01 0.0000 64 MnOH+ 0.72442E-09 -9.1400 0.67416E-09 -9.1712 0.93061E+00 -0.0312 65 MnO2-2 0.20208E-13 -13.6945 0.15998E-13 -13.7959 0.79165E+00 -0.1015 66 HMnO2- 0.29474E-11 -11.5306 0.27422E-11 -11.5619 0.93040E+00 -0.0313 69 MnCl+ 0.14814E-12 -12.8293 0.13786E-12 -12.8606 0.93061E+00 -0.0312 70 MnSO4,aq 0.10165E-11 -11.9929 0.10165E-11 -11.9929 0.10000E+01 0.0000 71 NaCl,aq 0.65261E-07 -7.1853 0.65261E-07 -7.1853 0.10000E+01 0.0000 72 NaOH,aq 0.84259E-06 -6.0744 0.84259E-06 -6.0744 0.10000E+01 0.0000 74 OH- 0.79387E-03 -3.1003 0.73846E-03 -3.1317 0.93020E+00 -0.0314 79 HPO3-2 0.10154E-16 -16.9933 0.80387E-17 -17.0948 0.79165E+00 -0.1015 81 H2PO3- 0.13556E-19 -19.8679 0.12612E-19 -19.8992 0.93040E+00 -0.0313 82 H3PO4,aq 0.23737E-13 -13.6246 0.23737E-13 -13.6246 0.10000E+01 0.0000 83 H2PO4- 0.85996E-07 -7.0655 0.80019E-07 -7.0968 0.93050E+00 -0.0313 84 PO4-3 0.95175E-08 -8.0215 0.57813E-08 -8.2380 0.60744E+00 -0.2165 87 H2P2O7-2 0.63421E-15 -15.1978 0.50207E-15 -15.2992 0.79165E+00 -0.1015 88 HP2O7-3 0.21216E-12 -12.6733 0.12813E-12 -12.8923 0.60393E+00 -0.2190 89 P2O7-4 0.94276E-13 -13.0256 0.39123E-13 -13.4076 0.41498E+00 -0.3820 90 H2S,aq 0.84923E-16 -16.0710 0.84893E-16 -16.0711 0.99965E+00 -0.0002 97 SO3-2 0.15391E-14 -14.8127 0.12205E-14 -14.9135 0.79302E+00 -0.1007 98 HSO3- 0.64263E-16 -16.1920 0.59790E-16 -16.2234 0.93040E+00 -0.0313 99 HSO4- 0.16354E-10 -10.7864 0.15221E-10 -10.8176 0.93072E+00 -0.0312 Charge balance for all species = 0.4600E-13 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.8403345E-09 -.1591039E-02 -.1603408E+01 0.0000 2 H2O 0.1000000E+01 0.5550842E+02 0.9998360E+06 0.0000 3 Cl- 0.1379409E-03 0.1380063E-03 0.4891930E+01 5.2149 4 SO4-- 0.2549241E-04 0.2551058E-04 0.2450183E+01 13.5182 5 HCO3- 0.1154043E-04 0.1307304E-04 0.7975489E+00 4.1375 6 HS- 0.3773270E-13 -.1766251E-09 -.5840383E-05 -4.3480 7 Al+++ 0.2715191E-24 0.2821914E-04 0.7612693E+00 2.5345 8 H4SiO4 0.5196925E-03 0.1201691E-02 0.1154820E+03 -3.2843 9 Ca++ 0.1938192E-07 0.2145236E-07 0.8596259E-03 10.3988 10 Mg++ 0.2782446E-09 0.4025085E-09 0.9784174E-05 8.5556 11 Fe++ 0.1641467E-11 0.3670892E-08 0.2049745E-03 6.3265 12 K+ 0.5707938E-04 0.5712638E-04 0.2233388E+01 4.8318 13 Na+ 0.1649196E-02 0.1665496E-02 0.3828310E+02 6.2925 14 Mn++ 0.2205459E-09 0.1244194E-08 0.6834226E-04 8.4548 15 HPO4-- 0.7001312E-05 0.7096825E-05 0.6810339E+00 12.9570 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.1984062E-01 -.1590669E-02 -.1824995E-01 0.0000000E+00 2 H2O 0.5549322E+02 0.5549551E+02 -.2285769E-02 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.5873285E-04 0.2550465E-04 0.3322820E-04 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.3322838E-04 -.1765840E-09 -.3322820E-04 0.0000000E+00 7 Al+++ 0.3909629E-02 0.2821258E-04 0.3881417E-02 0.0000000E+00 8 H4SiO4 0.1248493E-01 0.1201412E-02 0.1128352E-01 0.0000000E+00 9 Ca++ 0.1393492E-02 0.2144737E-07 0.1393471E-02 0.0000000E+00 10 Mg++ 0.9515873E-03 0.4024149E-09 0.9515869E-03 0.0000000E+00 11 Fe++ 0.8548973E-03 0.3670038E-08 0.8548936E-03 0.0000000E+00 12 K+ 0.2545648E-03 0.5711309E-04 0.1974517E-03 0.0000000E+00 13 Na+ 0.1665108E-02 0.1665108E-02 0.0000000E+00 0.0000000E+00 14 Mn++ 0.2078898E-04 0.1243905E-08 0.2078773E-04 0.0000000E+00 15 HPO4-- 0.7095174E-05 0.7095174E-05 0.0000000E+00 0.0000000E+00 Chg. balance for solid moles: -.1498E-17 Mass of aqueous solution: 0.999932E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 1.1990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) clinochlore 0.1903E-03 -3.721 0.1058 -0.976 8.347 0.4024E-01 daphnite 0.1178E-03 -3.929 0.8406E-01 -1.075 6.633 0.2547E-01 chlorite-Mn 0.4158E-05 -5.381 0.2948E-02 -2.531 0.2326 0.9393E-03 hematite 0.1329E-03 -3.876 0.2123E-01 -1.673 1.675 0.4023E-02 microcline 0.6123E-04 -4.213 0.1704E-01 -1.768 1.345 0.6657E-02 muscovite 0.1362E-03 -3.866 0.5426E-01 -1.266 4.281 0.1919E-01 stilbite 0.1393E-02 -2.856 0.9820 -0.008 77.49 0.4580 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity clinochlore 0.6094E+00 0.6094E+00 1.0000 -0.215 daphnite 0.3773E+00 0.3773E+00 1.0000 -0.423 chlorite-Mn 0.1331E-01 0.1331E-01 1.0000 -1.876 hematite 0.1000E+01 0.1000E+01 1.0000 0.000 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 muscovite 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 1.267327 g Volume = 0.554542 cm3 Porosity: 62.5208% V(tot) - V(min): 0.92506E+00 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 1.1990000 g log = 0.0788 Original solution: 1000.0103000 g Original solution / Rock added: 834.04 (Water/Rock Ratio), log = 2.9212 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0203 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.1000E+01 0.9860 0.1006E+01 0.1020E+01 CO2,gas 0.1869E-05 1.0071 0.1921E-05 0.1907E-05 CH4,gas 0.2585E-16 1.0125 0.2670E-16 0.2637E-16 H2,gas 0.5984E-06 1.0005 0.6109E-06 0.6105E-06 H2S,gas 0.2296E-14 0.9960 0.2334E-14 0.2343E-14 S2,gas 0.5369E-36 1.0000 0.5478E-36 0.5478E-36 CO,gas 0.3065E-15 1.0000 0.3127E-15 0.3127E-15 SO3,gas 0.4579E-38 1.0000 0.4672E-38 0.4672E-38 SO2,gas 0.1088E-21 1.0000 0.1110E-21 0.1110E-21 HCl,gas 0.3182E-16 1.0000 0.3247E-16 0.3247E-16 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 46 clinochlore 39.07 39.07 0.00 0.000 -0.24265E-10 47 daphnite 28.97 28.97 0.00 0.000 0.12132E-10 48 chlorite-Mn 46.87 46.87 0.00 0.000 0.12132E-10 90 hematite 12.57 12.57 0.00 0.000 0.30331E-11 116 microcline -2.49 -2.49 0.00 0.000 0.13649E-10 120 muscovite 2.58 2.58 0.00 0.000 0.60662E-11 163 stilbite -7.52 -7.52 0.00 0.000 0.15165E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -14.08 -7.42 -2.472 0.12662E+05 -5.717 3 CH4,gas 4.54 -13.73 -18.27 -4.568 0.31200E+05 -16.573 4 H2,gas 8.00 0.09 -7.91 -4.522 0.13511E+05 -6.214 5 H2S,gas -6.23 -22.56 -16.33 -8.165 0.27885E+05 -14.632 6 S2,gas -7.34 -45.30 -37.96 -5.840 0.64816E+05 -36.261 7 CO,gas 3.21 -13.99 -17.20 -5.293 0.29375E+05 -15.505 8 SO3,gas 17.12 -22.91 -40.03 -10.007 0.68349E+05 -38.330 9 SO2,gas 0.83 -22.82 -23.65 -6.308 0.40388E+05 -21.955 10 HCl,gas 5.19 -13.00 -18.19 -9.094 0.31055E+05 -16.489 11 acmite 7.71 6.01 -1.70 -0.177 0.29072E+04 15 albite-high 0.69 -1.03 -1.72 -0.132 0.29349E+04 16 albite -0.38 -1.03 -0.64 -0.049 0.10961E+04 19 spessartine 24.46 20.58 -3.88 -0.194 0.66197E+04 20 analcite 3.32 2.26 -1.06 -0.118 0.18157E+04 21 andalusite 5.00 1.78 -3.22 -0.322 0.54927E+04 26 annite 20.12 16.49 -3.63 -0.202 0.61990E+04 27 phlogopite 27.06 23.18 -3.88 -0.216 0.66324E+04 29 anorthite 12.71 8.90 -3.81 -0.293 0.65073E+04 32 apatite-OH -18.15 -18.41 -0.26 -0.020 0.44468E+03 35 aragonite 0.97 -3.68 -4.64 -1.548 0.79283E+04 36 brucite 12.57 8.56 -4.01 -0.803 0.68520E+04 37 calcite 0.81 -3.68 -4.49 -1.496 0.76641E+04 38 carnegieite-low 9.02 5.54 -3.48 -0.497 0.59430E+04 39 carnegieite-high 10.09 5.54 -4.55 -0.650 0.77700E+04 40 carpholite-Mg 8.58 7.06 -1.53 -0.102 0.26057E+04 41 carpholite-Fe 6.71 4.83 -1.89 -0.126 0.32199E+04 42 celadonite 5.34 2.78 -2.56 -0.150 0.43656E+04 43 celadonite-Fe 3.88 0.56 -3.32 -0.195 0.56702E+04 44 chrysotile 23.89 19.10 -4.79 -0.400 0.81858E+04 50 chloritoid-Mg 13.20 10.34 -2.86 -0.190 0.48790E+04 51 chloritoid-Fe 9.17 8.11 -1.06 -0.071 0.18142E+04 52 chloritoid-Mn 11.40 10.24 -1.16 -0.077 0.19835E+04 54 coesite -2.38 -3.28 -0.91 -0.303 0.15507E+04 59 corundum 8.38 5.07 -3.31 -0.301 0.56589E+04 61 cristobalite -2.56 -3.28 -0.72 -0.241 0.12361E+04 63 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71234E+04 65 diaspore 2.87 2.53 -0.34 -0.057 0.57923E+03 67 diopside 16.18 12.39 -3.80 -0.380 0.64807E+04 68 hedenbergite 14.21 10.16 -4.05 -0.405 0.69179E+04 75 epidote 24.67 22.30 -2.37 -0.115 0.40519E+04 76 clinozoisite 22.81 18.55 -4.26 -0.194 0.72701E+04 77 epidote-Fe 29.84 26.05 -3.80 -0.197 0.64804E+04 78 fayalite 14.05 9.37 -4.68 -0.668 0.79860E+04 83 gibbsite 4.08 2.53 -1.54 -0.221 0.26378E+04 87 greenalite 16.14 12.41 -3.73 -0.311 0.63666E+04 91 heulandite -5.83 -7.52 -1.69 -0.077 0.28938E+04 95 jadeite 4.22 2.26 -1.96 -0.196 0.33412E+04 97 kalsilite 7.58 4.08 -3.50 -0.500 0.59794E+04 98 kaolinite -1.33 -1.50 -0.17 -0.015 0.28483E+03 99 kyanite 4.88 1.78 -3.09 -0.309 0.52786E+04 101 laumontite 2.88 2.33 -0.55 -0.037 0.94373E+03 102 lawsonite 9.62 8.90 -0.72 -0.048 0.12240E+04 103 leucite 4.12 0.80 -3.32 -0.332 0.56707E+04 105 lizardite 23.24 19.10 -4.15 -0.345 0.70785E+04 107 magnetite 20.09 18.89 -1.19 -0.098 0.20400E+04 108 minnesotaite 10.39 5.84 -4.55 -0.267 0.77618E+04 113 margarite 17.32 13.97 -3.36 -0.134 0.57294E+04 121 paragonite 4.24 4.04 -0.20 -0.012 0.33518E+03 122 nepheline 8.34 5.54 -2.80 -0.400 0.47754E+04 136 prehnite 19.37 16.01 -3.36 -0.198 0.57339E+04 137 prehnite-Fe 22.50 19.76 -2.74 -0.165 0.46707E+04 145 pyroxmangite 7.40 5.17 -2.23 -0.446 0.38045E+04 146 pyrophyllite -6.18 -8.07 -1.89 -0.118 0.32310E+04 147 quartz -2.99 -3.28 -0.29 -0.098 0.50339E+03 151 rhodochrosite -0.98 -5.62 -4.64 -1.548 0.79304E+04 152 rhodonite 7.45 5.17 -2.28 -0.455 0.38848E+04 153 sanidine -1.28 -2.49 -1.21 -0.093 0.20677E+04 156 sillimanite 5.26 1.78 -3.48 -0.348 0.59366E+04 164 stilpnomelane-Fe 13.02 12.84 -0.17 -0.005 0.29693E+03 165 stilpnomelane-Mg 27.44 23.99 -3.45 -0.103 0.58953E+04 168 sudoite 21.08 17.40 -3.68 -0.119 0.62853E+04 171 talc 16.49 12.53 -3.96 -0.233 0.67638E+04 174 tephroite 18.09 13.63 -4.46 -0.637 0.76162E+04 177 topaz-H 4.62 1.78 -2.83 -0.258 0.48387E+04 178 tridymite -2.63 -3.28 -0.66 -0.219 0.11234E+04 187 wairakite 3.95 2.33 -1.62 -0.095 0.27657E+04 188 walstromite 11.51 7.11 -4.39 -0.879 0.75038E+04 189 wollastonite 10.46 7.11 -3.35 -0.669 0.57142E+04 190 pseudo-wollastonite 11.00 7.11 -3.89 -0.777 0.66341E+04 191 zoisite 22.85 18.55 -4.30 -0.196 0.73441E+04 192 akaganeite 7.75 6.28 -1.47 -0.318 0.25125E+04 193 beidellite-Ca -1.65 -4.43 -2.79 -0.172 0.47579E+04 194 beidellite-H -2.33 -6.15 -3.82 -0.244 0.65254E+04 195 beidellite-K -1.52 -4.55 -3.03 -0.186 0.51791E+04 196 beidellite-Mg -1.79 -4.74 -2.95 -0.182 0.50310E+04 197 beidellite-Na -1.34 -4.07 -2.73 -0.167 0.46600E+04 199 chalcedony -2.80 -3.28 -0.48 -0.161 0.82269E+03 201 montmorillonite-Ca -2.29 -4.37 -2.07 -0.128 0.35423E+04 202 montmorillonite-K -2.24 -4.49 -2.25 -0.138 0.38416E+04 203 montmorillonite-Mg -2.48 -4.67 -2.19 -0.135 0.37386E+04 204 montmorillonite-Na -2.04 -4.00 -1.97 -0.120 0.33582E+04 205 nontronite-Ca 3.21 3.07 -0.15 -0.010 0.25509E+03 206 nontronite-H 2.53 1.35 -1.18 -0.079 0.20205E+04 207 nontronite-K 3.34 2.94 -0.40 -0.025 0.67763E+03 208 nontronite-Mg 3.07 2.76 -0.31 -0.020 0.53547E+03 209 nontronite-Na 3.52 3.43 -0.09 -0.006 0.16021E+03 224 tobermorite 9.82 5.38 -4.45 -1.213 0.75899E+04 233 boehmite 4.41 2.53 -1.87 -0.312 0.31962E+04 235 ferrous-oxide 9.81 6.33 -3.49 -0.871 0.59508E+04 240 silica-amorphous -2.09 -3.28 -1.19 -0.398 0.20369E+04 242 an20ab80 2.02 0.96 -1.06 -0.081 0.18075E+04 243 an25ab75 2.65 1.46 -1.19 -0.092 0.20323E+04 244 an30ab70 3.28 1.95 -1.33 -0.102 0.22667E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 0.0400000 g Current total amount of reactant added: 1.1990000 g New total amount of reactant added: 1.2390000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.4568E-13 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 6 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 1.2390000 Water: Moles liquid = 0.5549E+02 kg liquid = 0.9998E+00 Moles total = 0.5549E+02 kg total = 0.9997E+00 Activity = 1.0000 Stoichiometric ionic strength = .1156680E-02 Osmotic coef. = 0.9804 True ionic strength = .1787000E-02 Chg. balance for total moles = 0.4568E-13 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.81948E-09 -9.0865 0.76248E-09 -9.1178 0.93045E+00 -0.0313 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13794E-03 -3.8603 0.12825E-03 -3.8919 0.92977E+00 -0.0316 4 SO4-- 0.25494E-04 -4.5936 0.20133E-04 -4.6961 0.78972E+00 -0.1025 5 HCO3- 0.11503E-04 -4.9392 0.10697E-04 -4.9707 0.92993E+00 -0.0316 6 HS- 0.35221E-13 -13.4532 0.32748E-13 -13.4848 0.92978E+00 -0.0316 7 Al+++ 0.25283E-24 -24.5972 0.15176E-24 -24.8188 0.60023E+00 -0.2217 8 H4SiO4 0.52416E-03 -3.2805 0.52416E-03 -3.2805 0.10000E+01 0.0000 9 Ca++ 0.17383E-07 -7.7599 0.13716E-07 -7.8628 0.78903E+00 -0.1029 10 Mg++ 0.26362E-09 -9.5790 0.20788E-09 -9.6822 0.78859E+00 -0.1032 11 Fe++ 0.15552E-11 -11.8082 0.12265E-11 -11.9113 0.78869E+00 -0.1031 12 K+ 0.54251E-04 -4.2656 0.50451E-04 -4.2971 0.92996E+00 -0.0315 13 Na+ 0.16984E-02 -2.7700 0.15791E-02 -2.8016 0.92975E+00 -0.0316 14 Mn++ 0.20895E-09 -9.6800 0.16481E-09 -9.7830 0.78877E+00 -0.1030 15 HPO4-- 0.72371E-05 -5.1404 0.57154E-05 -5.2430 0.78973E+00 -0.1025 16 HSiO3- 0.69038E-03 -3.1609 0.64189E-03 -3.1925 0.92977E+00 -0.0316 17 Ca(HSiO3)+ 0.21559E-09 -9.6664 0.20050E-09 -9.6979 0.92998E+00 -0.0315 18 Mg(HSiO3)+ 0.40667E-11 -11.3908 0.37820E-11 -11.4223 0.92998E+00 -0.0315 19 NaHSiO3,aq 0.16393E-04 -4.7853 0.16393E-04 -4.7853 0.10000E+01 0.0000 20 AlO+ 0.38185E-13 -13.4181 0.35511E-13 -13.4496 0.92998E+00 -0.0315 21 AlOH+2 0.17091E-18 -18.7672 0.13483E-18 -18.8702 0.78886E+00 -0.1030 22 HAlO2,aq 0.92750E-08 -8.0327 0.92750E-08 -8.0327 0.10000E+01 0.0000 23 AlO2- 0.28967E-04 -4.5381 0.26926E-04 -4.5698 0.92956E+00 -0.0317 24 CH4,aq 0.16908E-19 -19.7719 0.16902E-19 -19.7721 0.99964E+00 -0.0002 29 CO,aq 0.20162E-18 -18.6955 0.20162E-18 -18.6955 0.10000E+01 0.0000 30 CO2,aq 0.17435E-07 -7.7586 0.17429E-07 -7.7587 0.99964E+00 -0.0002 31 CO3-2 0.15521E-05 -5.8091 0.12254E-05 -5.9117 0.78952E+00 -0.1026 32 CaCO3,aq 0.21075E-09 -9.6762 0.21075E-09 -9.6762 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.40271E-11 -11.3950 0.37452E-11 -11.4265 0.92998E+00 -0.0315 34 CaCl+ 0.30610E-11 -11.5141 0.28467E-11 -11.5457 0.92998E+00 -0.0315 35 CaCl2,aq 0.86738E-16 -16.0618 0.86738E-16 -16.0618 0.10000E+01 0.0000 36 CaOH+ 0.13785E-08 -8.8606 0.12820E-08 -8.8921 0.92998E+00 -0.0315 37 CaSO4,aq 0.87685E-10 -10.0571 0.87685E-10 -10.0571 0.10000E+01 0.0000 38 HCl,aq 0.17920E-13 -13.7467 0.17920E-13 -13.7467 0.10000E+01 0.0000 43 FeCl+ 0.26774E-15 -15.5723 0.24899E-15 -15.6038 0.92998E+00 -0.0315 46 FeO,aq 0.81995E-10 -10.0862 0.81995E-10 -10.0862 0.10000E+01 0.0000 47 FeOH+ 0.56304E-10 -10.2495 0.52362E-10 -10.2810 0.92998E+00 -0.0315 48 HFeO2- 0.12102E-08 -8.9172 0.11252E-08 -8.9488 0.92977E+00 -0.0316 49 FeO+ 0.62581E-14 -14.2036 0.58200E-14 -14.2351 0.92998E+00 -0.0315 51 FeO2- 0.22031E-08 -8.6570 0.20484E-08 -8.6886 0.92977E+00 -0.0316 52 HFeO2,aq 0.19864E-09 -9.7019 0.19864E-09 -9.7019 0.10000E+01 0.0000 53 H2,aq 0.46068E-09 -9.3366 0.46052E-09 -9.3368 0.99964E+00 -0.0002 54 KCl,aq 0.11727E-09 -9.9308 0.11727E-09 -9.9308 0.10000E+01 0.0000 55 KHSO4,aq 0.21897E-17 -17.6596 0.21897E-17 -17.6596 0.10000E+01 0.0000 56 KOH,aq 0.28257E-07 -7.5489 0.28257E-07 -7.5489 0.10000E+01 0.0000 57 KSO4- 0.16952E-07 -7.7708 0.15762E-07 -7.8024 0.92977E+00 -0.0316 58 MgCO3,aq 0.80066E-12 -12.0966 0.80066E-12 -12.0966 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.62370E-13 -13.2050 0.58003E-13 -13.2365 0.92998E+00 -0.0315 60 MgCl+ 0.42050E-13 -13.3762 0.39106E-13 -13.4078 0.92998E+00 -0.0315 61 MgOH+ 0.11562E-09 -9.9370 0.10752E-09 -9.9685 0.92998E+00 -0.0315 63 MnO,aq 0.29358E-09 -9.5323 0.29358E-09 -9.5323 0.10000E+01 0.0000 64 MnOH+ 0.70283E-09 -9.1531 0.65362E-09 -9.1847 0.92998E+00 -0.0315 65 MnO2-2 0.21226E-13 -13.6731 0.16758E-13 -13.7758 0.78952E+00 -0.1026 66 HMnO2- 0.30109E-11 -11.5213 0.27995E-11 -11.5529 0.92977E+00 -0.0316 69 MnCl+ 0.13996E-12 -12.8540 0.13016E-12 -12.8855 0.92998E+00 -0.0315 70 MnSO4,aq 0.95793E-12 -12.0187 0.95793E-12 -12.0187 0.10000E+01 0.0000 71 NaCl,aq 0.67115E-07 -7.1732 0.67115E-07 -7.1732 0.10000E+01 0.0000 72 NaOH,aq 0.88978E-06 -6.0507 0.88978E-06 -6.0507 0.10000E+01 0.0000 74 OH- 0.81517E-03 -3.0888 0.75775E-03 -3.1205 0.92956E+00 -0.0317 79 HPO3-2 0.10389E-16 -16.9834 0.82022E-17 -17.0861 0.78952E+00 -0.1026 81 H2PO3- 0.13489E-19 -19.8700 0.12541E-19 -19.9017 0.92977E+00 -0.0316 82 H3PO4,aq 0.23240E-13 -13.6338 0.23240E-13 -13.6338 0.10000E+01 0.0000 83 H2PO4- 0.86454E-07 -7.0632 0.80391E-07 -7.0948 0.92987E+00 -0.0316 84 PO4-3 0.10128E-07 -7.9945 0.61157E-08 -8.2136 0.60384E+00 -0.2191 87 H2P2O7-2 0.64184E-15 -15.1926 0.50674E-15 -15.2952 0.78952E+00 -0.1026 88 HP2O7-3 0.22107E-12 -12.6555 0.13270E-12 -12.8771 0.60027E+00 -0.2217 89 P2O7-4 0.10127E-12 -12.9945 0.41578E-13 -13.3811 0.41055E+00 -0.3866 90 H2S,aq 0.77199E-16 -16.1124 0.77172E-16 -16.1125 0.99964E+00 -0.0002 97 SO3-2 0.15233E-14 -14.8172 0.12048E-14 -14.9191 0.79091E+00 -0.1019 98 HSO3- 0.61864E-16 -16.2086 0.57519E-16 -16.2402 0.92977E+00 -0.0316 99 HSO4- 0.15906E-10 -10.7984 0.14794E-10 -10.8299 0.93009E+00 -0.0315 Charge balance for all species = 0.4598E-13 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.8194789E-09 -.1640234E-02 -.1652979E+01 0.0000 2 H2O 0.1000000E+01 0.5550842E+02 0.9998322E+06 0.0000 3 Cl- 0.1379400E-03 0.1380073E-03 0.4891947E+01 5.2258 4 SO4-- 0.2549353E-04 0.2551077E-04 0.2450192E+01 13.5394 5 HCO3- 0.1150336E-04 0.1307314E-04 0.7975516E+00 4.1470 6 HS- 0.3522096E-13 -.1850127E-09 -.6117709E-05 -4.3670 7 Al+++ 0.2528346E-24 0.2897620E-04 0.7816894E+00 2.5345 8 H4SiO4 0.5241644E-03 0.1230941E-02 0.1182924E+03 -3.2805 9 Ca++ 0.1738284E-07 0.1928246E-07 0.7726723E-03 10.3728 10 Mg++ 0.2636159E-09 0.3842039E-09 0.9339190E-05 8.5534 11 Fe++ 0.1555162E-11 0.3751767E-08 0.2094896E-03 6.3242 12 K+ 0.5425093E-04 0.5429625E-04 0.2122734E+01 4.8206 13 Na+ 0.1698379E-02 0.1715729E-02 0.3943762E+02 6.3162 14 Mn++ 0.2089502E-09 0.1209494E-08 0.6643596E-04 8.4525 15 HPO4-- 0.7237054E-05 0.7333636E-05 0.7037564E+00 12.9926 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.2050296E-01 -.1639841E-02 -.1886312E-01 0.0000000E+00 2 H2O 0.5549272E+02 0.5549511E+02 -.2386707E-02 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.5984138E-04 0.2550465E-04 0.3433673E-04 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.3433691E-04 -.1849683E-09 -.3433673E-04 0.0000000E+00 7 Al+++ 0.4040059E-02 0.2896925E-04 0.4011090E-02 0.0000000E+00 8 H4SiO4 0.1290144E-01 0.1230646E-02 0.1167079E-01 0.0000000E+00 9 Ca++ 0.1439498E-02 0.1927784E-07 0.1439479E-02 0.0000000E+00 10 Mg++ 0.9833333E-03 0.3841118E-09 0.9833329E-03 0.0000000E+00 11 Fe++ 0.8834176E-03 0.3750867E-08 0.8834139E-03 0.0000000E+00 12 K+ 0.2630573E-03 0.5428323E-04 0.2087741E-03 0.0000000E+00 13 Na+ 0.1715318E-02 0.1715318E-02 0.0000000E+00 0.0000000E+00 14 Mn++ 0.2148252E-04 0.1209204E-08 0.2148131E-04 0.0000000E+00 15 HPO4-- 0.7331877E-05 0.7331877E-05 0.0000000E+00 0.0000000E+00 Chg. balance for solid moles: -.1105E-17 Mass of aqueous solution: 0.999929E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 1.2390000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) clinochlore 0.1967E-03 -3.706 0.1093 -0.961 8.342 0.4158E-01 daphnite 0.1217E-03 -3.915 0.8687E-01 -1.061 6.629 0.2632E-01 chlorite-Mn 0.4296E-05 -5.367 0.3046E-02 -2.516 0.2324 0.9707E-03 hematite 0.1373E-03 -3.862 0.2193E-01 -1.659 1.674 0.4157E-02 microcline 0.6980E-04 -4.156 0.1943E-01 -1.712 1.483 0.7589E-02 muscovite 0.1390E-03 -3.857 0.5535E-01 -1.257 4.224 0.1957E-01 stilbite 0.1439E-02 -2.842 1.014 0.006 77.42 0.4731 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity clinochlore 0.6094E+00 0.6094E+00 1.0000 -0.215 daphnite 0.3773E+00 0.3773E+00 1.0000 -0.423 chlorite-Mn 0.1331E-01 0.1331E-01 1.0000 -1.876 hematite 0.1000E+01 0.1000E+01 1.0000 0.000 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 muscovite 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 1.310371 g Volume = 0.573342 cm3 Porosity: 61.6648% V(tot) - V(min): 0.92226E+00 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 1.2390000 g log = 0.0931 Original solution: 1000.0103000 g Original solution / Rock added: 807.11 (Water/Rock Ratio), log = 2.9069 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0203 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.1000E+01 0.9860 0.1006E+01 0.1020E+01 CO2,gas 0.1815E-05 1.0071 0.1865E-05 0.1852E-05 CH4,gas 0.2408E-16 1.0125 0.2488E-16 0.2457E-16 H2,gas 0.5923E-06 1.0005 0.6046E-06 0.6043E-06 H2S,gas 0.2087E-14 0.9960 0.2121E-14 0.2130E-14 S2,gas 0.4529E-36 1.0000 0.4621E-36 0.4621E-36 CO,gas 0.2945E-15 1.0000 0.3005E-15 0.3005E-15 SO3,gas 0.4338E-38 1.0000 0.4426E-38 0.4426E-38 SO2,gas 0.1020E-21 1.0000 0.1041E-21 0.1041E-21 HCl,gas 0.3099E-16 1.0000 0.3162E-16 0.3162E-16 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 46 clinochlore 39.07 39.07 0.00 0.000 0.12132E-10 47 daphnite 28.97 28.97 0.00 0.000 -0.60662E-11 48 chlorite-Mn 46.87 46.87 0.00 0.000 0.24265E-10 90 hematite 12.57 12.57 0.00 0.000 0.30331E-11 116 microcline -2.49 -2.49 0.00 0.000 0.13649E-10 120 muscovite 2.58 2.58 0.00 0.000 0.30331E-10 163 stilbite -7.52 -7.52 0.00 0.000 0.15165E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -14.09 -7.43 -2.476 0.12684E+05 -5.729 3 CH4,gas 4.54 -13.76 -18.30 -4.576 0.31252E+05 -16.604 4 H2,gas 8.00 0.08 -7.92 -4.524 0.13519E+05 -6.219 5 H2S,gas -6.23 -22.60 -16.37 -8.186 0.27955E+05 -14.673 6 S2,gas -7.34 -45.37 -38.03 -5.851 0.64942E+05 -36.335 7 CO,gas 3.21 -14.01 -17.22 -5.299 0.29405E+05 -15.522 8 SO3,gas 17.12 -22.93 -40.05 -10.013 0.68389E+05 -38.354 9 SO2,gas 0.83 -22.85 -23.68 -6.315 0.40436E+05 -21.983 10 HCl,gas 5.19 -13.01 -18.20 -9.100 0.31074E+05 -16.500 11 acmite 7.71 6.04 -1.67 -0.174 0.28541E+04 15 albite-high 0.69 -0.99 -1.68 -0.130 0.28754E+04 16 albite -0.38 -0.99 -0.61 -0.047 0.10366E+04 19 spessartine 24.46 20.58 -3.87 -0.194 0.66120E+04 20 analcite 3.32 2.29 -1.03 -0.115 0.17626E+04 21 andalusite 5.00 1.79 -3.21 -0.321 0.54863E+04 26 annite 20.12 16.49 -3.64 -0.202 0.62105E+04 27 phlogopite 27.06 23.17 -3.89 -0.216 0.66438E+04 29 anorthite 12.71 8.88 -3.83 -0.295 0.65391E+04 32 apatite-OH -18.15 -18.57 -0.42 -0.032 0.71414E+03 35 aragonite 0.97 -3.72 -4.68 -1.561 0.79948E+04 36 brucite 12.57 8.55 -4.02 -0.803 0.68559E+04 37 calcite 0.81 -3.72 -4.53 -1.509 0.77306E+04 38 carnegieite-low 9.02 5.57 -3.45 -0.493 0.58962E+04 39 carnegieite-high 10.09 5.57 -4.52 -0.646 0.77232E+04 40 carpholite-Mg 8.58 7.06 -1.52 -0.101 0.25968E+04 41 carpholite-Fe 6.71 4.83 -1.88 -0.125 0.32110E+04 42 celadonite 5.34 2.79 -2.56 -0.150 0.43631E+04 43 celadonite-Fe 3.88 0.56 -3.32 -0.195 0.56677E+04 44 chrysotile 23.89 19.10 -4.79 -0.399 0.81846E+04 50 chloritoid-Mg 13.20 10.34 -2.86 -0.190 0.48765E+04 51 chloritoid-Fe 9.17 8.11 -1.06 -0.071 0.18116E+04 52 chloritoid-Mn 11.40 10.24 -1.16 -0.077 0.19809E+04 54 coesite -2.38 -3.28 -0.90 -0.301 0.15444E+04 59 corundum 8.38 5.07 -3.31 -0.301 0.56589E+04 61 cristobalite -2.56 -3.28 -0.72 -0.240 0.12297E+04 63 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71234E+04 65 diaspore 2.87 2.53 -0.34 -0.057 0.57923E+03 67 diopside 16.18 12.37 -3.82 -0.382 0.65162E+04 68 hedenbergite 14.21 10.14 -4.07 -0.407 0.69535E+04 75 epidote 24.67 22.26 -2.41 -0.117 0.41218E+04 76 clinozoisite 22.81 18.51 -4.30 -0.195 0.73400E+04 77 epidote-Fe 29.84 26.00 -3.84 -0.199 0.65503E+04 78 fayalite 14.05 9.37 -4.68 -0.668 0.79872E+04 83 gibbsite 4.08 2.53 -1.54 -0.221 0.26378E+04 87 greenalite 16.14 12.41 -3.73 -0.311 0.63653E+04 91 heulandite -5.83 -7.52 -1.69 -0.077 0.28938E+04 95 jadeite 4.22 2.29 -1.93 -0.193 0.32881E+04 97 kalsilite 7.58 4.07 -3.51 -0.501 0.59921E+04 98 kaolinite -1.33 -1.49 -0.16 -0.014 0.27212E+03 99 kyanite 4.88 1.79 -3.09 -0.309 0.52722E+04 101 laumontite 2.88 2.32 -0.56 -0.038 0.96279E+03 102 lawsonite 9.62 8.88 -0.74 -0.049 0.12558E+04 103 leucite 4.12 0.79 -3.32 -0.332 0.56770E+04 105 lizardite 23.24 19.10 -4.14 -0.345 0.70772E+04 107 magnetite 20.09 18.89 -1.20 -0.098 0.20438E+04 108 minnesotaite 10.39 5.85 -4.54 -0.267 0.77478E+04 113 margarite 17.32 13.95 -3.37 -0.135 0.57611E+04 121 paragonite 4.24 4.08 -0.16 -0.009 0.27571E+03 122 nepheline 8.34 5.57 -2.77 -0.396 0.47286E+04 134 phlogopite-Na 29.65 24.67 -4.98 -0.277 0.84992E+04 136 prehnite 19.37 15.97 -3.40 -0.200 0.58038E+04 137 prehnite-Fe 22.50 19.72 -2.78 -0.167 0.47406E+04 145 pyroxmangite 7.40 5.17 -2.23 -0.445 0.38020E+04 146 pyrophyllite -6.18 -8.05 -1.88 -0.117 0.32056E+04 147 quartz -2.99 -3.28 -0.29 -0.097 0.49704E+03 151 rhodochrosite -0.98 -5.64 -4.66 -1.553 0.79562E+04 152 rhodonite 7.45 5.17 -2.27 -0.455 0.38822E+04 153 sanidine -1.28 -2.49 -1.21 -0.093 0.20677E+04 156 sillimanite 5.26 1.79 -3.47 -0.347 0.59303E+04 164 stilpnomelane-Fe 13.02 12.86 -0.16 -0.005 0.27469E+03 165 stilpnomelane-Mg 27.44 24.00 -3.44 -0.103 0.58731E+04 168 sudoite 21.08 17.40 -3.67 -0.119 0.62739E+04 171 talc 16.49 12.54 -3.95 -0.233 0.67498E+04 174 tephroite 18.09 13.62 -4.46 -0.637 0.76175E+04 177 topaz-H 4.62 1.79 -2.83 -0.257 0.48323E+04 178 tridymite -2.63 -3.28 -0.65 -0.218 0.11170E+04 187 wairakite 3.95 2.32 -1.63 -0.096 0.27847E+04 188 walstromite 11.51 7.09 -4.42 -0.883 0.75419E+04 189 wollastonite 10.46 7.09 -3.37 -0.674 0.57524E+04 190 pseudo-wollastonite 11.00 7.09 -3.91 -0.782 0.66722E+04 191 zoisite 22.85 18.51 -4.34 -0.197 0.74140E+04 192 akaganeite 7.75 6.28 -1.47 -0.318 0.25125E+04 193 beidellite-Ca -1.65 -4.42 -2.78 -0.172 0.47419E+04 194 beidellite-H -2.33 -6.13 -3.81 -0.243 0.65021E+04 195 beidellite-K -1.52 -4.54 -3.02 -0.185 0.51621E+04 196 beidellite-Mg -1.79 -4.72 -2.93 -0.181 0.50083E+04 197 beidellite-Na -1.34 -4.05 -2.71 -0.166 0.46233E+04 199 chalcedony -2.80 -3.28 -0.48 -0.159 0.81634E+03 201 montmorillonite-Ca -2.29 -4.36 -2.06 -0.128 0.35255E+04 202 montmorillonite-K -2.24 -4.48 -2.24 -0.137 0.38238E+04 203 montmorillonite-Mg -2.48 -4.66 -2.18 -0.135 0.37151E+04 204 montmorillonite-Na -2.04 -3.98 -1.94 -0.119 0.33208E+04 205 nontronite-Ca 3.21 3.07 -0.14 -0.009 0.23911E+03 206 nontronite-H 2.53 1.36 -1.17 -0.078 0.19972E+04 207 nontronite-K 3.34 2.95 -0.39 -0.025 0.66060E+03 208 nontronite-Mg 3.07 2.77 -0.30 -0.019 0.51278E+03 209 nontronite-Na 3.52 3.45 -0.07 -0.005 0.12356E+03 224 tobermorite 9.82 5.36 -4.46 -1.218 0.76206E+04 233 boehmite 4.41 2.53 -1.87 -0.312 0.31962E+04 235 ferrous-oxide 9.81 6.32 -3.49 -0.872 0.59546E+04 240 silica-amorphous -2.09 -3.28 -1.19 -0.396 0.20305E+04 242 an20ab80 2.02 0.98 -1.03 -0.080 0.17663E+04 243 an25ab75 2.65 1.48 -1.17 -0.090 0.19956E+04 244 an30ab70 3.28 1.97 -1.31 -0.101 0.22346E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 0.0400000 g Current total amount of reactant added: 1.2390000 g New total amount of reactant added: 1.2790000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.4568E-13 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 6 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 1.2790000 Water: Moles liquid = 0.5549E+02 kg liquid = 0.9998E+00 Moles total = 0.5549E+02 kg total = 0.9997E+00 Activity = 1.0000 Stoichiometric ionic strength = .1184310E-02 Osmotic coef. = 0.9802 True ionic strength = .1833747E-02 Chg. balance for total moles = 0.4568E-13 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.79985E-09 -9.0970 0.74374E-09 -9.1286 0.92984E+00 -0.0316 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13794E-03 -3.8603 0.12816E-03 -3.8922 0.92914E+00 -0.0319 4 SO4-- 0.25495E-04 -4.5936 0.20080E-04 -4.6972 0.78763E+00 -0.1037 5 HCO3- 0.11467E-04 -4.9406 0.10656E-04 -4.9724 0.92931E+00 -0.0318 6 HS- 0.32880E-13 -13.4831 0.30551E-13 -13.5150 0.92916E+00 -0.0319 7 Al+++ 0.23606E-24 -24.6270 0.14084E-24 -24.8513 0.59663E+00 -0.2243 8 H4SiO4 0.52876E-03 -3.2767 0.52876E-03 -3.2767 0.10000E+01 0.0000 9 Ca++ 0.15599E-07 -7.8069 0.12275E-07 -7.9110 0.78692E+00 -0.1041 10 Mg++ 0.25017E-09 -9.6018 0.19675E-09 -9.7061 0.78647E+00 -0.1043 11 Fe++ 0.14759E-11 -11.8310 0.11609E-11 -11.9352 0.78657E+00 -0.1043 12 K+ 0.51583E-04 -4.2875 0.47938E-04 -4.3193 0.92934E+00 -0.0318 13 Na+ 0.17475E-02 -2.7576 0.16237E-02 -2.7895 0.92912E+00 -0.0319 14 Mn++ 0.19829E-09 -9.7027 0.15599E-09 -9.8069 0.78666E+00 -0.1042 15 HPO4-- 0.74728E-05 -5.1265 0.58859E-05 -5.2302 0.78764E+00 -0.1037 16 HSiO3- 0.71448E-03 -3.1460 0.66385E-03 -3.1779 0.92914E+00 -0.0319 17 Ca(HSiO3)+ 0.19969E-09 -9.6996 0.18558E-09 -9.7315 0.92936E+00 -0.0318 18 Mg(HSiO3)+ 0.39833E-11 -11.3998 0.37019E-11 -11.4316 0.92936E+00 -0.0318 19 NaHSiO3,aq 0.17433E-04 -4.7586 0.17433E-04 -4.7586 0.10000E+01 0.0000 20 AlO+ 0.37271E-13 -13.4286 0.34638E-13 -13.4604 0.92936E+00 -0.0318 21 AlOH+2 0.16305E-18 -18.7877 0.12828E-18 -18.8918 0.78675E+00 -0.1042 22 HAlO2,aq 0.92750E-08 -8.0327 0.92750E-08 -8.0327 0.10000E+01 0.0000 23 AlO2- 0.29717E-04 -4.5270 0.27605E-04 -4.5590 0.92893E+00 -0.0320 24 CH4,aq 0.15754E-19 -19.8026 0.15749E-19 -19.8028 0.99963E+00 -0.0002 29 CO,aq 0.19387E-18 -18.7125 0.19387E-18 -18.7125 0.10000E+01 0.0000 30 CO2,aq 0.16941E-07 -7.7711 0.16935E-07 -7.7712 0.99963E+00 -0.0002 31 CO3-2 0.15893E-05 -5.7988 0.12515E-05 -5.9026 0.78742E+00 -0.1038 32 CaCO3,aq 0.19263E-09 -9.7153 0.19263E-09 -9.7153 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.35928E-11 -11.4446 0.33390E-11 -11.4764 0.92936E+00 -0.0318 34 CaCl+ 0.27395E-11 -11.5623 0.25460E-11 -11.5941 0.92936E+00 -0.0318 35 CaCl2,aq 0.77524E-16 -16.1106 0.77524E-16 -16.1106 0.10000E+01 0.0000 36 CaOH+ 0.12657E-08 -8.8977 0.11763E-08 -8.9295 0.92936E+00 -0.0318 37 CaSO4,aq 0.78272E-10 -10.1064 0.78272E-10 -10.1064 0.10000E+01 0.0000 38 HCl,aq 0.17467E-13 -13.7578 0.17467E-13 -13.7578 0.10000E+01 0.0000 43 FeCl+ 0.25340E-15 -15.5962 0.23550E-15 -15.6280 0.92936E+00 -0.0318 46 FeO,aq 0.81566E-10 -10.0885 0.81566E-10 -10.0885 0.10000E+01 0.0000 47 FeOH+ 0.54669E-10 -10.2623 0.50808E-10 -10.2941 0.92936E+00 -0.0318 48 HFeO2- 0.12350E-08 -8.9083 0.11475E-08 -8.9402 0.92914E+00 -0.0319 49 FeO+ 0.61083E-14 -14.2141 0.56769E-14 -14.2459 0.92936E+00 -0.0318 51 FeO2- 0.22602E-08 -8.6459 0.21000E-08 -8.6778 0.92914E+00 -0.0319 52 HFeO2,aq 0.19864E-09 -9.7019 0.19864E-09 -9.7019 0.10000E+01 0.0000 53 H2,aq 0.45588E-09 -9.3411 0.45571E-09 -9.3413 0.99963E+00 -0.0002 54 KCl,aq 0.11135E-09 -9.9533 0.11135E-09 -9.9533 0.10000E+01 0.0000 55 KHSO4,aq 0.20242E-17 -17.6938 0.20242E-17 -17.6938 0.10000E+01 0.0000 56 KOH,aq 0.27526E-07 -7.5603 0.27526E-07 -7.5603 0.10000E+01 0.0000 57 KSO4- 0.16076E-07 -7.7938 0.14937E-07 -7.8257 0.92914E+00 -0.0319 58 MgCO3,aq 0.77390E-12 -12.1113 0.77390E-12 -12.1113 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.58842E-13 -13.2303 0.54686E-13 -13.2621 0.92936E+00 -0.0318 60 MgCl+ 0.39798E-13 -13.4001 0.36987E-13 -13.4320 0.92936E+00 -0.0318 61 MgOH+ 0.11226E-09 -9.9498 0.10433E-09 -9.9816 0.92936E+00 -0.0318 63 MnO,aq 0.29205E-09 -9.5345 0.29205E-09 -9.5345 0.10000E+01 0.0000 64 MnOH+ 0.68243E-09 -9.1659 0.63422E-09 -9.1978 0.92936E+00 -0.0318 65 MnO2-2 0.22253E-13 -13.6526 0.17522E-13 -13.7564 0.78742E+00 -0.1038 66 HMnO2- 0.30728E-11 -11.5125 0.28550E-11 -11.5444 0.92914E+00 -0.0319 69 MnCl+ 0.13247E-12 -12.8779 0.12311E-12 -12.9097 0.92936E+00 -0.0318 70 MnSO4,aq 0.90427E-12 -12.0437 0.90427E-12 -12.0437 0.10000E+01 0.0000 71 NaCl,aq 0.68964E-07 -7.1614 0.68964E-07 -7.1614 0.10000E+01 0.0000 72 NaOH,aq 0.93797E-06 -6.0278 0.93797E-06 -6.0278 0.10000E+01 0.0000 74 OH- 0.83629E-03 -3.0776 0.77685E-03 -3.1097 0.92893E+00 -0.0320 79 HPO3-2 0.10616E-16 -16.9741 0.83589E-17 -17.0779 0.78742E+00 -0.1038 81 H2PO3- 0.13417E-19 -19.8723 0.12467E-19 -19.9043 0.92914E+00 -0.0319 82 H3PO4,aq 0.22770E-13 -13.6426 0.22770E-13 -13.6426 0.10000E+01 0.0000 83 H2PO4- 0.86902E-07 -7.0610 0.80754E-07 -7.0928 0.92925E+00 -0.0319 84 PO4-3 0.10756E-07 -7.9684 0.64569E-08 -8.1900 0.60031E+00 -0.2216 87 H2P2O7-2 0.64937E-15 -15.1875 0.51132E-15 -15.2913 0.78742E+00 -0.1038 88 HP2O7-3 0.23008E-12 -12.6381 0.13728E-12 -12.8624 0.59667E+00 -0.2243 89 P2O7-4 0.10855E-12 -12.9644 0.44096E-13 -13.3556 0.40621E+00 -0.3912 90 H2S,aq 0.70250E-16 -16.1534 0.70225E-16 -16.1535 0.99963E+00 -0.0002 97 SO3-2 0.15075E-14 -14.8218 0.11891E-14 -14.9248 0.78885E+00 -0.1030 98 HSO3- 0.59598E-16 -16.2248 0.55375E-16 -16.2567 0.92914E+00 -0.0319 99 HSO4- 0.15485E-10 -10.8101 0.14393E-10 -10.8419 0.92947E+00 -0.0318 Charge balance for all species = 0.4598E-13 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.7998544E-09 -.1689571E-02 -.1702693E+01 0.0000 2 H2O 0.1000000E+01 0.5550841E+02 0.9998283E+06 0.0000 3 Cl- 0.1379392E-03 0.1380083E-03 0.4891963E+01 5.2363 4 SO4-- 0.2549460E-04 0.2551096E-04 0.2450201E+01 13.5599 5 HCO3- 0.1146674E-04 0.1307323E-04 0.7975543E+00 4.1562 6 HS- 0.3288029E-13 -.1933472E-09 -.6393276E-05 -4.3864 7 Al+++ 0.2360557E-24 0.2972656E-04 0.8019288E+00 2.5345 8 H4SiO4 0.5287634E-03 0.1260673E-02 0.1211492E+03 -3.2767 9 Ca++ 0.1559924E-07 0.1734186E-07 0.6949072E-03 10.3462 10 Mg++ 0.2501732E-09 0.3672880E-09 0.8927965E-05 8.5511 11 Fe++ 0.1475855E-11 0.3831532E-08 0.2139427E-03 6.3219 12 K+ 0.5158273E-04 0.5162644E-04 0.2018349E+01 4.8093 13 Na+ 0.1747524E-02 0.1765964E-02 0.4059215E+02 6.3391 14 Mn++ 0.1982947E-09 0.1176899E-08 0.6464533E-04 8.4503 15 HPO4-- 0.7472792E-05 0.7570450E-05 0.7264789E+00 13.0270 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.2116530E-01 -.1689154E-02 -.1947615E-01 0.0000000E+00 2 H2O 0.5549222E+02 0.5549470E+02 -.2486669E-02 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.6094992E-04 0.2550466E-04 0.3544526E-04 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.3544545E-04 -.1932994E-09 -.3544526E-04 0.0000000E+00 7 Al+++ 0.4170489E-02 0.2971921E-04 0.4140769E-02 0.0000000E+00 8 H4SiO4 0.1331795E-01 0.1260362E-02 0.1205759E-01 0.0000000E+00 9 Ca++ 0.1485504E-02 0.1733758E-07 0.1485486E-02 0.0000000E+00 10 Mg++ 0.1015079E-02 0.3671972E-09 0.1015079E-02 0.0000000E+00 11 Fe++ 0.9119380E-03 0.3830586E-08 0.9119342E-03 0.0000000E+00 12 K+ 0.2715499E-03 0.5161369E-04 0.2199362E-03 0.0000000E+00 13 Na+ 0.1765528E-02 0.1765528E-02 0.0000000E+00 0.0000000E+00 14 Mn++ 0.2217606E-04 0.1176608E-08 0.2217489E-04 0.0000000E+00 15 HPO4-- 0.7568580E-05 0.7568580E-05 0.0000000E+00 0.0000000E+00 Chg. balance for solid moles: -.8132E-19 Mass of aqueous solution: 0.999925E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 1.2790000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) clinochlore 0.2030E-03 -3.692 0.1128 -0.948 8.338 0.4292E-01 daphnite 0.1257E-03 -3.901 0.8967E-01 -1.047 6.626 0.2717E-01 chlorite-Mn 0.4435E-05 -5.353 0.3144E-02 -2.502 0.2323 0.1002E-02 hematite 0.1418E-03 -3.848 0.2264E-01 -1.645 1.673 0.4292E-02 microcline 0.7813E-04 -4.107 0.2175E-01 -1.663 1.607 0.8495E-02 muscovite 0.1418E-03 -3.848 0.5648E-01 -1.248 4.173 0.1997E-01 stilbite 0.1485E-02 -2.828 1.047 0.020 77.35 0.4883 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity clinochlore 0.6094E+00 0.6094E+00 1.0000 -0.215 daphnite 0.3773E+00 0.3773E+00 1.0000 -0.423 chlorite-Mn 0.1331E-01 0.1331E-01 1.0000 -1.876 hematite 0.1000E+01 0.1000E+01 1.0000 0.000 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 muscovite 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 1.353380 g Volume = 0.592126 cm3 Porosity: 60.8278% V(tot) - V(min): 0.91947E+00 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 1.2790000 g log = 0.1069 Original solution: 1000.0103000 g Original solution / Rock added: 781.87 (Water/Rock Ratio), log = 2.8931 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0203 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.1000E+01 0.9860 0.1006E+01 0.1020E+01 CO2,gas 0.1763E-05 1.0071 0.1812E-05 0.1799E-05 CH4,gas 0.2244E-16 1.0125 0.2318E-16 0.2289E-16 H2,gas 0.5861E-06 1.0005 0.5983E-06 0.5980E-06 H2S,gas 0.1900E-14 0.9960 0.1930E-14 0.1938E-14 S2,gas 0.3830E-36 1.0000 0.3908E-36 0.3908E-36 CO,gas 0.2832E-15 1.0000 0.2889E-15 0.2889E-15 SO3,gas 0.4116E-38 1.0000 0.4200E-38 0.4200E-38 SO2,gas 0.9581E-22 1.0000 0.9776E-22 0.9776E-22 HCl,gas 0.3021E-16 1.0000 0.3082E-16 0.3082E-16 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 46 clinochlore 39.07 39.07 0.00 0.000 -0.24265E-10 47 daphnite 28.97 28.97 0.00 0.000 0.12132E-10 48 chlorite-Mn 46.87 46.87 0.00 0.000 0.12132E-10 90 hematite 12.57 12.57 0.00 0.000 -0.30331E-11 116 microcline -2.49 -2.49 0.00 0.000 -0.10616E-10 120 muscovite 2.58 2.58 0.00 0.000 0.60662E-11 163 stilbite -7.52 -7.52 0.00 0.000 0.15165E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -14.10 -7.44 -2.480 0.12705E+05 -5.742 3 CH4,gas 4.54 -13.79 -18.33 -4.583 0.31305E+05 -16.635 4 H2,gas 8.00 0.08 -7.92 -4.527 0.13527E+05 -6.223 5 H2S,gas -6.23 -22.64 -16.41 -8.207 0.28025E+05 -14.714 6 S2,gas -7.34 -45.44 -38.11 -5.863 0.65067E+05 -36.408 7 CO,gas 3.21 -14.02 -17.24 -5.304 0.29434E+05 -15.539 8 SO3,gas 17.12 -22.95 -40.08 -10.019 0.68428E+05 -38.377 9 SO2,gas 0.83 -22.88 -23.71 -6.322 0.40482E+05 -22.010 10 HCl,gas 5.19 -13.02 -18.21 -9.105 0.31093E+05 -16.511 11 acmite 7.71 6.07 -1.64 -0.170 0.28020E+04 15 albite-high 0.69 -0.96 -1.65 -0.127 0.28169E+04 16 albite -0.38 -0.96 -0.57 -0.044 0.97806E+03 19 spessartine 24.46 20.59 -3.87 -0.193 0.66043E+04 20 analcite 3.32 2.32 -1.00 -0.111 0.17105E+04 21 andalusite 5.00 1.79 -3.21 -0.321 0.54799E+04 26 annite 20.12 16.48 -3.64 -0.202 0.62221E+04 27 phlogopite 27.06 23.17 -3.90 -0.217 0.66554E+04 29 anorthite 12.71 8.86 -3.85 -0.296 0.65715E+04 32 apatite-OH -18.15 -18.73 -0.58 -0.044 0.98623E+03 35 aragonite 0.97 -3.75 -4.72 -1.574 0.80615E+04 36 brucite 12.57 8.55 -4.02 -0.803 0.68597E+04 37 calcite 0.81 -3.75 -4.57 -1.522 0.77973E+04 38 carnegieite-low 9.02 5.60 -3.43 -0.489 0.58506E+04 39 carnegieite-high 10.09 5.60 -4.50 -0.642 0.76776E+04 40 carpholite-Mg 8.58 7.07 -1.52 -0.101 0.25878E+04 41 carpholite-Fe 6.71 4.84 -1.88 -0.125 0.32019E+04 42 celadonite 5.34 2.79 -2.55 -0.150 0.43605E+04 43 celadonite-Fe 3.88 0.56 -3.32 -0.195 0.56651E+04 44 chrysotile 23.89 19.10 -4.79 -0.399 0.81833E+04 50 chloritoid-Mg 13.20 10.34 -2.85 -0.190 0.48739E+04 51 chloritoid-Fe 9.17 8.11 -1.06 -0.071 0.18090E+04 52 chloritoid-Mn 11.40 10.24 -1.16 -0.077 0.19783E+04 54 coesite -2.38 -3.28 -0.90 -0.300 0.15379E+04 59 corundum 8.38 5.07 -3.31 -0.301 0.56589E+04 61 cristobalite -2.56 -3.28 -0.72 -0.239 0.12232E+04 63 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71234E+04 65 diaspore 2.87 2.53 -0.34 -0.057 0.57923E+03 67 diopside 16.18 12.34 -3.84 -0.384 0.65525E+04 68 hedenbergite 14.21 10.11 -4.09 -0.409 0.69897E+04 75 epidote 24.67 22.21 -2.46 -0.119 0.41931E+04 76 clinozoisite 22.81 18.47 -4.34 -0.197 0.74112E+04 77 epidote-Fe 29.84 25.96 -3.88 -0.201 0.66216E+04 78 fayalite 14.05 9.37 -4.68 -0.668 0.79885E+04 83 gibbsite 4.08 2.53 -1.54 -0.221 0.26378E+04 87 greenalite 16.14 12.41 -3.73 -0.311 0.63640E+04 91 heulandite -5.83 -7.52 -1.69 -0.077 0.28938E+04 95 jadeite 4.22 2.32 -1.90 -0.190 0.32360E+04 97 kalsilite 7.58 4.07 -3.52 -0.502 0.60051E+04 98 kaolinite -1.33 -1.48 -0.15 -0.014 0.25917E+03 99 kyanite 4.88 1.79 -3.08 -0.308 0.52658E+04 101 laumontite 2.88 2.31 -0.58 -0.038 0.98222E+03 102 lawsonite 9.62 8.86 -0.75 -0.050 0.12882E+04 103 leucite 4.12 0.79 -3.33 -0.333 0.56835E+04 105 lizardite 23.24 19.10 -4.14 -0.345 0.70759E+04 107 magnetite 20.09 18.89 -1.20 -0.098 0.20477E+04 108 minnesotaite 10.39 5.86 -4.53 -0.266 0.77335E+04 113 margarite 17.32 13.93 -3.39 -0.136 0.57935E+04 121 paragonite 4.24 4.11 -0.13 -0.007 0.21716E+03 122 nepheline 8.34 5.60 -2.74 -0.392 0.46830E+04 134 phlogopite-Na 29.65 24.70 -4.95 -0.275 0.84523E+04 136 prehnite 19.37 15.93 -3.44 -0.202 0.58750E+04 137 prehnite-Fe 22.50 19.68 -2.82 -0.170 0.48119E+04 145 pyroxmangite 7.40 5.17 -2.23 -0.445 0.37994E+04 146 pyrophyllite -6.18 -8.04 -1.86 -0.116 0.31797E+04 147 quartz -2.99 -3.28 -0.29 -0.096 0.49056E+03 151 rhodochrosite -0.98 -5.65 -4.67 -1.558 0.79814E+04 152 rhodonite 7.45 5.17 -2.27 -0.454 0.38797E+04 153 sanidine -1.28 -2.49 -1.21 -0.093 0.20677E+04 156 sillimanite 5.26 1.79 -3.47 -0.347 0.59238E+04 164 stilpnomelane-Fe 13.02 12.87 -0.15 -0.004 0.25202E+03 165 stilpnomelane-Mg 27.44 24.02 -3.43 -0.102 0.58504E+04 168 sudoite 21.08 17.41 -3.67 -0.118 0.62622E+04 171 talc 16.49 12.55 -3.94 -0.232 0.67356E+04 174 tephroite 18.09 13.62 -4.46 -0.637 0.76188E+04 177 topaz-H 4.62 1.79 -2.83 -0.257 0.48258E+04 178 tridymite -2.63 -3.28 -0.65 -0.217 0.11105E+04 187 wairakite 3.95 2.31 -1.64 -0.097 0.28042E+04 188 walstromite 11.51 7.07 -4.44 -0.888 0.75808E+04 189 wollastonite 10.46 7.07 -3.39 -0.678 0.57912E+04 190 pseudo-wollastonite 11.00 7.07 -3.93 -0.786 0.67111E+04 191 zoisite 22.85 18.47 -4.38 -0.199 0.74853E+04 192 akaganeite 7.75 6.28 -1.47 -0.318 0.25125E+04 193 beidellite-Ca -1.65 -4.41 -2.77 -0.171 0.47256E+04 194 beidellite-H -2.33 -6.12 -3.79 -0.242 0.64783E+04 195 beidellite-K -1.52 -4.53 -3.01 -0.185 0.51447E+04 196 beidellite-Mg -1.79 -4.71 -2.92 -0.181 0.49852E+04 197 beidellite-Na -1.34 -4.03 -2.69 -0.164 0.45866E+04 199 chalcedony -2.80 -3.28 -0.47 -0.158 0.80986E+03 201 montmorillonite-Ca -2.29 -4.35 -2.05 -0.127 0.35084E+04 202 montmorillonite-K -2.24 -4.47 -2.23 -0.136 0.38056E+04 203 montmorillonite-Mg -2.48 -4.64 -2.16 -0.134 0.36911E+04 204 montmorillonite-Na -2.04 -3.96 -1.92 -0.118 0.32832E+04 205 nontronite-Ca 3.21 3.08 -0.13 -0.008 0.22281E+03 206 nontronite-H 2.53 1.38 -1.16 -0.077 0.19735E+04 207 nontronite-K 3.34 2.96 -0.38 -0.024 0.64324E+03 208 nontronite-Mg 3.07 2.79 -0.29 -0.019 0.48965E+03 209 nontronite-Na 3.52 3.47 -0.05 -0.003 0.86874E+02 224 tobermorite 9.82 5.34 -4.48 -1.223 0.76519E+04 233 boehmite 4.41 2.53 -1.87 -0.312 0.31962E+04 235 ferrous-oxide 9.81 6.32 -3.49 -0.872 0.59585E+04 240 silica-amorphous -2.09 -3.28 -1.19 -0.395 0.20240E+04 242 an20ab80 2.02 1.01 -1.01 -0.078 0.17259E+04 243 an25ab75 2.65 1.50 -1.15 -0.088 0.19598E+04 244 an30ab70 3.28 1.99 -1.29 -0.099 0.22034E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 0.0400000 g Current total amount of reactant added: 1.2790000 g New total amount of reactant added: 1.3190000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.4568E-13 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 6 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 1.3190000 Water: Moles liquid = 0.5549E+02 kg liquid = 0.9997E+00 Moles total = 0.5549E+02 kg total = 0.9997E+00 Activity = 1.0000 Stoichiometric ionic strength = .1211987E-02 Osmotic coef. = 0.9800 True ionic strength = .1880608E-02 Chg. balance for total moles = 0.4568E-13 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.78136E-09 -9.1072 0.72607E-09 -9.1390 0.92924E+00 -0.0319 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13794E-03 -3.8603 0.12808E-03 -3.8925 0.92852E+00 -0.0322 4 SO4-- 0.25496E-04 -4.5935 0.20028E-04 -4.6984 0.78556E+00 -0.1048 5 HCO3- 0.11431E-04 -4.9419 0.10615E-04 -4.9741 0.92869E+00 -0.0321 6 HS- 0.30702E-13 -13.5128 0.28508E-13 -13.5450 0.92854E+00 -0.0322 7 Al+++ 0.22094E-24 -24.6557 0.13104E-24 -24.8826 0.59309E+00 -0.2269 8 H4SiO4 0.53348E-03 -3.2729 0.53348E-03 -3.2729 0.10000E+01 0.0000 9 Ca++ 0.14009E-07 -7.8536 0.10994E-07 -7.9588 0.78484E+00 -0.1052 10 Mg++ 0.23779E-09 -9.6238 0.18652E-09 -9.7293 0.78438E+00 -0.1055 11 Fe++ 0.14028E-11 -11.8530 0.11005E-11 -11.9584 0.78449E+00 -0.1054 12 K+ 0.49067E-04 -4.3092 0.45570E-04 -4.3413 0.92872E+00 -0.0321 13 Na+ 0.17966E-02 -2.7455 0.16682E-02 -2.7778 0.92850E+00 -0.0322 14 Mn++ 0.18848E-09 -9.7247 0.14788E-09 -9.8301 0.78457E+00 -0.1054 15 HPO4-- 0.77085E-05 -5.1130 0.60556E-05 -5.2178 0.78557E+00 -0.1048 16 HSiO3- 0.73888E-03 -3.1314 0.68606E-03 -3.1636 0.92852E+00 -0.0322 17 Ca(HSiO3)+ 0.18496E-09 -9.7329 0.17178E-09 -9.7650 0.92875E+00 -0.0321 18 Mg(HSiO3)+ 0.39050E-11 -11.4084 0.36268E-11 -11.4405 0.92875E+00 -0.0321 19 NaHSiO3,aq 0.18510E-04 -4.7326 0.18510E-04 -4.7326 0.10000E+01 0.0000 20 AlO+ 0.36410E-13 -13.4388 0.33815E-13 -13.4709 0.92875E+00 -0.0321 21 AlOH+2 0.15580E-18 -18.8074 0.12225E-18 -18.9127 0.78467E+00 -0.1053 22 HAlO2,aq 0.92750E-08 -8.0327 0.92750E-08 -8.0327 0.10000E+01 0.0000 23 AlO2- 0.30461E-04 -4.5163 0.28277E-04 -4.5486 0.92830E+00 -0.0323 24 CH4,aq 0.14683E-19 -19.8332 0.14677E-19 -19.8334 0.99962E+00 -0.0002 29 CO,aq 0.18654E-18 -18.7292 0.18654E-18 -18.7292 0.10000E+01 0.0000 30 CO2,aq 0.16475E-07 -7.7832 0.16469E-07 -7.7833 0.99962E+00 -0.0002 31 CO3-2 0.16261E-05 -5.7889 0.12770E-05 -5.8938 0.78535E+00 -0.1049 32 CaCO3,aq 0.17605E-09 -9.7544 0.17605E-09 -9.7544 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.32077E-11 -11.4938 0.29792E-11 -11.5259 0.92875E+00 -0.0321 34 CaCl+ 0.24537E-11 -11.6102 0.22788E-11 -11.6423 0.92875E+00 -0.0321 35 CaCl2,aq 0.69342E-16 -16.1590 0.69342E-16 -16.1590 0.10000E+01 0.0000 36 CaOH+ 0.11620E-08 -8.9348 0.10792E-08 -8.9669 0.92875E+00 -0.0321 37 CaSO4,aq 0.69924E-10 -10.1554 0.69924E-10 -10.1554 0.10000E+01 0.0000 38 HCl,aq 0.17041E-13 -13.7685 0.17041E-13 -13.7685 0.10000E+01 0.0000 43 FeCl+ 0.24021E-15 -15.6194 0.22310E-15 -15.6515 0.92875E+00 -0.0321 46 FeO,aq 0.81133E-10 -10.0908 0.81133E-10 -10.0908 0.10000E+01 0.0000 47 FeOH+ 0.53122E-10 -10.2747 0.49337E-10 -10.3068 0.92875E+00 -0.0321 48 HFeO2- 0.12592E-08 -8.8999 0.11692E-08 -8.9321 0.92852E+00 -0.0322 49 FeO+ 0.59671E-14 -14.2242 0.55420E-14 -14.2563 0.92875E+00 -0.0321 51 FeO2- 0.23167E-08 -8.6351 0.21511E-08 -8.6673 0.92852E+00 -0.0322 52 HFeO2,aq 0.19864E-09 -9.7019 0.19864E-09 -9.7019 0.10000E+01 0.0000 53 H2,aq 0.45106E-09 -9.3458 0.45089E-09 -9.3459 0.99962E+00 -0.0002 54 KCl,aq 0.10578E-09 -9.9756 0.10578E-09 -9.9756 0.10000E+01 0.0000 55 KHSO4,aq 0.18736E-17 -17.7273 0.18736E-17 -17.7273 0.10000E+01 0.0000 56 KOH,aq 0.26803E-07 -7.5718 0.26803E-07 -7.5718 0.10000E+01 0.0000 57 KSO4- 0.15253E-07 -7.8166 0.14163E-07 -7.8489 0.92852E+00 -0.0322 58 MgCO3,aq 0.74863E-12 -12.1257 0.74863E-12 -12.1257 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.55606E-13 -13.2549 0.51644E-13 -13.2870 0.92875E+00 -0.0321 60 MgCl+ 0.37727E-13 -13.4233 0.35039E-13 -13.4554 0.92875E+00 -0.0321 61 MgOH+ 0.10908E-09 -9.9622 0.10131E-09 -9.9943 0.92875E+00 -0.0321 63 MnO,aq 0.29050E-09 -9.5369 0.29050E-09 -9.5369 0.10000E+01 0.0000 64 MnOH+ 0.66312E-09 -9.1784 0.61587E-09 -9.2105 0.92875E+00 -0.0321 65 MnO2-2 0.23286E-13 -13.6329 0.18288E-13 -13.7378 0.78535E+00 -0.1049 66 HMnO2- 0.31330E-11 -11.5040 0.29090E-11 -11.5363 0.92852E+00 -0.0322 69 MnCl+ 0.12558E-12 -12.9011 0.11663E-12 -12.9332 0.92875E+00 -0.0321 70 MnSO4,aq 0.85502E-12 -12.0680 0.85502E-12 -12.0680 0.10000E+01 0.0000 71 NaCl,aq 0.70807E-07 -7.1499 0.70807E-07 -7.1499 0.10000E+01 0.0000 72 NaOH,aq 0.98714E-06 -6.0056 0.98714E-06 -6.0056 0.10000E+01 0.0000 74 OH- 0.85722E-03 -3.0669 0.79576E-03 -3.0992 0.92830E+00 -0.0323 79 HPO3-2 0.10835E-16 -16.9652 0.85089E-17 -17.0701 0.78535E+00 -0.1049 81 H2PO3- 0.13342E-19 -19.8748 0.12389E-19 -19.9070 0.92852E+00 -0.0322 82 H3PO4,aq 0.22327E-13 -13.6512 0.22327E-13 -13.6512 0.10000E+01 0.0000 83 H2PO4- 0.87342E-07 -7.0588 0.81109E-07 -7.0909 0.92863E+00 -0.0322 84 PO4-3 0.11401E-07 -7.9430 0.68048E-08 -8.1672 0.59684E+00 -0.2241 87 H2P2O7-2 0.65682E-15 -15.1826 0.51583E-15 -15.2875 0.78535E+00 -0.1049 88 HP2O7-3 0.23917E-12 -12.6213 0.14186E-12 -12.8481 0.59313E+00 -0.2268 89 P2O7-4 0.11612E-12 -12.9351 0.46676E-13 -13.3309 0.40197E+00 -0.3958 90 H2S,aq 0.63995E-16 -16.1939 0.63971E-16 -16.1940 0.99962E+00 -0.0002 97 SO3-2 0.14915E-14 -14.8264 0.11735E-14 -14.9305 0.78681E+00 -0.1041 98 HSO3- 0.57456E-16 -16.2407 0.53349E-16 -16.2729 0.92852E+00 -0.0322 99 HSO4- 0.15088E-10 -10.8214 0.14014E-10 -10.8534 0.92886E+00 -0.0321 Charge balance for all species = 0.4595E-13 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.7813559E-09 -.1739042E-02 -.1752541E+01 0.0000 2 H2O 0.1000000E+01 0.5550841E+02 0.9998243E+06 0.0000 3 Cl- 0.1379383E-03 0.1380093E-03 0.4891979E+01 5.2465 4 SO4-- 0.2549562E-04 0.2551116E-04 0.2450210E+01 13.5797 5 HCO3- 0.1143057E-04 0.1307332E-04 0.7975569E+00 4.1650 6 HS- 0.3070185E-13 -.2016242E-09 -.6666940E-05 -4.4060 7 Al+++ 0.2209358E-24 0.3047028E-04 0.8219888E+00 2.5345 8 H4SiO4 0.5334752E-03 0.1290865E-02 0.1240502E+03 -3.2729 9 Ca++ 0.1400863E-07 0.1560723E-07 0.6253961E-03 10.3192 10 Mg++ 0.2377921E-09 0.3516209E-09 0.8547100E-05 8.5488 11 Fe++ 0.1402810E-11 0.3910211E-08 0.2183350E-03 6.3196 12 K+ 0.4906696E-04 0.4910913E-04 0.1919926E+01 4.7977 13 Na+ 0.1796631E-02 0.1816199E-02 0.4174669E+02 6.3613 14 Mn++ 0.1884805E-09 0.1146229E-08 0.6296040E-04 8.4479 15 HPO4-- 0.7708524E-05 0.7807268E-05 0.7492016E+00 13.0602 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.2182764E-01 -.1738600E-02 -.2008904E-01 0.0000000E+00 2 H2O 0.5549172E+02 0.5549430E+02 -.2585702E-02 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.6205846E-04 0.2550467E-04 0.3655378E-04 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.3655399E-04 -.2015730E-09 -.3655378E-04 0.0000000E+00 7 Al+++ 0.4300918E-02 0.3046253E-04 0.4270456E-02 0.0000000E+00 8 H4SiO4 0.1373446E-01 0.1290537E-02 0.1244392E-01 0.0000000E+00 9 Ca++ 0.1531509E-02 0.1560326E-07 0.1531494E-02 0.0000000E+00 10 Mg++ 0.1046825E-02 0.3515315E-09 0.1046825E-02 0.0000000E+00 11 Fe++ 0.9404583E-03 0.3909217E-08 0.9404544E-03 0.0000000E+00 12 K+ 0.2800425E-03 0.4909664E-04 0.2309458E-03 0.0000000E+00 13 Na+ 0.1815737E-02 0.1815737E-02 0.0000000E+00 0.0000000E+00 14 Mn++ 0.2286961E-04 0.1145937E-08 0.2286846E-04 0.0000000E+00 15 HPO4-- 0.7805284E-05 0.7805284E-05 0.0000000E+00 0.0000000E+00 Chg. balance for solid moles: -.2114E-17 Mass of aqueous solution: 0.999922E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 1.3190000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) clinochlore 0.2094E-03 -3.679 0.1164 -0.934 8.334 0.4426E-01 daphnite 0.1296E-03 -3.887 0.9247E-01 -1.034 6.623 0.2802E-01 chlorite-Mn 0.4574E-05 -5.340 0.3243E-02 -2.489 0.2322 0.1033E-02 hematite 0.1462E-03 -3.835 0.2335E-01 -1.632 1.672 0.4426E-02 microcline 0.8623E-04 -4.064 0.2400E-01 -1.620 1.719 0.9375E-02 muscovite 0.1447E-03 -3.839 0.5764E-01 -1.239 4.128 0.2038E-01 stilbite 0.1531E-02 -2.815 1.079 0.033 77.29 0.5034 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity clinochlore 0.6094E+00 0.6094E+00 1.0000 -0.215 daphnite 0.3773E+00 0.3773E+00 1.0000 -0.423 chlorite-Mn 0.1331E-01 0.1331E-01 1.0000 -1.876 hematite 0.1000E+01 0.1000E+01 1.0000 0.000 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 muscovite 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 1.396356 g Volume = 0.610897 cm3 Porosity: 60.0094% V(tot) - V(min): 0.91670E+00 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 1.3190000 g log = 0.1202 Original solution: 1000.0103000 g Original solution / Rock added: 758.16 (Water/Rock Ratio), log = 2.8798 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0203 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.1000E+01 0.9860 0.1006E+01 0.1020E+01 CO2,gas 0.1715E-05 1.0071 0.1762E-05 0.1750E-05 CH4,gas 0.2091E-16 1.0125 0.2160E-16 0.2134E-16 H2,gas 0.5799E-06 1.0005 0.5920E-06 0.5916E-06 H2S,gas 0.1730E-14 0.9960 0.1759E-14 0.1766E-14 S2,gas 0.3247E-36 1.0000 0.3313E-36 0.3313E-36 CO,gas 0.2725E-15 1.0000 0.2780E-15 0.2780E-15 SO3,gas 0.3913E-38 1.0000 0.3992E-38 0.3992E-38 SO2,gas 0.9011E-22 1.0000 0.9194E-22 0.9194E-22 HCl,gas 0.2947E-16 1.0000 0.3007E-16 0.3007E-16 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 46 clinochlore 39.07 39.07 0.00 0.000 -0.12132E-10 47 daphnite 28.97 28.97 0.00 0.000 -0.48529E-10 48 chlorite-Mn 46.87 46.87 0.00 0.000 -0.24265E-10 90 hematite 12.57 12.57 0.00 0.000 -0.15165E-10 116 microcline -2.49 -2.49 0.00 0.000 -0.22748E-10 120 muscovite 2.58 2.58 0.00 0.000 0.30331E-10 163 stilbite -7.52 -7.52 0.00 0.000 -0.33364E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -14.11 -7.45 -2.484 0.12726E+05 -5.754 3 CH4,gas 4.54 -13.82 -18.36 -4.591 0.31357E+05 -16.665 4 H2,gas 8.00 0.07 -7.93 -4.530 0.13535E+05 -6.228 5 H2S,gas -6.23 -22.68 -16.45 -8.227 0.28094E+05 -14.755 6 S2,gas -7.34 -45.51 -38.18 -5.874 0.65189E+05 -36.480 7 CO,gas 3.21 -14.04 -17.25 -5.309 0.29462E+05 -15.556 8 SO3,gas 17.12 -22.98 -40.10 -10.024 0.68466E+05 -38.399 9 SO2,gas 0.83 -22.90 -23.74 -6.329 0.40528E+05 -22.036 10 HCl,gas 5.19 -13.03 -18.22 -9.110 0.31112E+05 -16.522 11 acmite 7.71 6.10 -1.61 -0.167 0.27510E+04 15 albite-high 0.69 -0.92 -1.62 -0.124 0.27592E+04 16 albite -0.38 -0.92 -0.54 -0.041 0.92043E+03 19 spessartine 24.46 20.59 -3.86 -0.193 0.65964E+04 20 analcite 3.32 2.35 -0.97 -0.108 0.16595E+04 21 andalusite 5.00 1.80 -3.21 -0.321 0.54733E+04 26 annite 20.12 16.47 -3.65 -0.203 0.62340E+04 27 phlogopite 27.06 23.16 -3.90 -0.217 0.66673E+04 29 anorthite 12.71 8.84 -3.87 -0.298 0.66044E+04 32 apatite-OH -18.15 -18.89 -0.74 -0.057 0.12602E+04 35 aragonite 0.97 -3.79 -4.76 -1.587 0.81282E+04 36 brucite 12.57 8.55 -4.02 -0.804 0.68637E+04 37 calcite 0.81 -3.79 -4.61 -1.535 0.78640E+04 38 carnegieite-low 9.02 5.62 -3.40 -0.486 0.58062E+04 39 carnegieite-high 10.09 5.62 -4.47 -0.639 0.76332E+04 40 carpholite-Mg 8.58 7.07 -1.51 -0.101 0.25786E+04 41 carpholite-Fe 6.71 4.84 -1.87 -0.125 0.31927E+04 42 celadonite 5.34 2.79 -2.55 -0.150 0.43578E+04 43 celadonite-Fe 3.88 0.56 -3.32 -0.195 0.56624E+04 44 chrysotile 23.89 19.10 -4.79 -0.399 0.81819E+04 50 chloritoid-Mg 13.20 10.34 -2.85 -0.190 0.48712E+04 51 chloritoid-Fe 9.17 8.12 -1.06 -0.071 0.18064E+04 52 chloritoid-Mn 11.40 10.24 -1.16 -0.077 0.19757E+04 54 coesite -2.38 -3.27 -0.90 -0.299 0.15313E+04 59 corundum 8.38 5.07 -3.31 -0.301 0.56589E+04 61 cristobalite -2.56 -3.27 -0.71 -0.238 0.12167E+04 63 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71234E+04 65 diaspore 2.87 2.53 -0.34 -0.057 0.57923E+03 67 diopside 16.18 12.32 -3.86 -0.386 0.65894E+04 68 hedenbergite 14.21 10.09 -4.12 -0.412 0.70266E+04 75 epidote 24.67 22.17 -2.50 -0.121 0.42655E+04 76 clinozoisite 22.81 18.42 -4.38 -0.199 0.74836E+04 77 epidote-Fe 29.84 25.92 -3.92 -0.204 0.66939E+04 78 fayalite 14.05 9.37 -4.68 -0.668 0.79899E+04 83 gibbsite 4.08 2.53 -1.54 -0.221 0.26378E+04 87 greenalite 16.14 12.41 -3.73 -0.311 0.63627E+04 91 heulandite -5.83 -7.52 -1.69 -0.077 0.28938E+04 95 jadeite 4.22 2.35 -1.87 -0.187 0.31850E+04 97 kalsilite 7.58 4.06 -3.52 -0.504 0.60182E+04 98 kaolinite -1.33 -1.48 -0.14 -0.013 0.24601E+03 99 kyanite 4.88 1.80 -3.08 -0.308 0.52592E+04 101 laumontite 2.88 2.30 -0.59 -0.039 0.10020E+04 102 lawsonite 9.62 8.84 -0.77 -0.052 0.13211E+04 103 leucite 4.12 0.79 -3.33 -0.333 0.56901E+04 105 lizardite 23.24 19.10 -4.14 -0.345 0.70746E+04 107 magnetite 20.09 18.89 -1.20 -0.098 0.20517E+04 108 minnesotaite 10.39 5.87 -4.52 -0.266 0.77191E+04 113 margarite 17.32 13.91 -3.41 -0.136 0.58264E+04 121 paragonite 4.24 4.15 -0.09 -0.005 0.15953E+03 122 nepheline 8.34 5.62 -2.72 -0.388 0.46385E+04 134 phlogopite-Na 29.65 24.72 -4.92 -0.274 0.84065E+04 136 prehnite 19.37 15.89 -3.48 -0.205 0.59474E+04 137 prehnite-Fe 22.50 19.64 -2.86 -0.172 0.48843E+04 145 pyroxmangite 7.40 5.18 -2.22 -0.445 0.37968E+04 146 pyrophyllite -6.18 -8.02 -1.85 -0.115 0.31534E+04 147 quartz -2.99 -3.27 -0.28 -0.094 0.48398E+03 151 rhodochrosite -0.98 -5.67 -4.69 -1.563 0.80060E+04 152 rhodonite 7.45 5.18 -2.27 -0.454 0.38770E+04 153 sanidine -1.28 -2.49 -1.21 -0.093 0.20677E+04 156 sillimanite 5.26 1.80 -3.47 -0.347 0.59172E+04 164 stilpnomelane-Fe 13.02 12.88 -0.13 -0.004 0.22899E+03 165 stilpnomelane-Mg 27.44 24.03 -3.41 -0.102 0.58274E+04 168 sudoite 21.08 17.42 -3.66 -0.118 0.62504E+04 171 talc 16.49 12.55 -3.94 -0.232 0.67211E+04 174 tephroite 18.09 13.62 -4.46 -0.638 0.76201E+04 177 topaz-H 4.62 1.80 -2.82 -0.257 0.48193E+04 178 tridymite -2.63 -3.27 -0.65 -0.216 0.11040E+04 187 wairakite 3.95 2.30 -1.65 -0.097 0.28239E+04 188 walstromite 11.51 7.05 -4.46 -0.893 0.76203E+04 189 wollastonite 10.46 7.05 -3.41 -0.683 0.58307E+04 190 pseudo-wollastonite 11.00 7.05 -3.95 -0.791 0.67505E+04 191 zoisite 22.85 18.42 -4.43 -0.201 0.75577E+04 192 akaganeite 7.75 6.28 -1.47 -0.318 0.25125E+04 193 beidellite-Ca -1.65 -4.40 -2.76 -0.171 0.47091E+04 194 beidellite-H -2.33 -6.11 -3.78 -0.241 0.64542E+04 195 beidellite-K -1.52 -4.52 -3.00 -0.184 0.51271E+04 196 beidellite-Mg -1.79 -4.70 -2.91 -0.180 0.49617E+04 197 beidellite-Na -1.34 -4.01 -2.66 -0.163 0.45500E+04 199 chalcedony -2.80 -3.27 -0.47 -0.157 0.80328E+03 201 montmorillonite-Ca -2.29 -4.34 -2.04 -0.126 0.34909E+04 202 montmorillonite-K -2.24 -4.45 -2.22 -0.136 0.37871E+04 203 montmorillonite-Mg -2.48 -4.63 -2.15 -0.133 0.36667E+04 204 montmorillonite-Na -2.04 -3.94 -1.90 -0.116 0.32457E+04 205 nontronite-Ca 3.21 3.09 -0.12 -0.008 0.20627E+03 206 nontronite-H 2.53 1.39 -1.14 -0.077 0.19493E+04 207 nontronite-K 3.34 2.97 -0.37 -0.024 0.62561E+03 208 nontronite-Mg 3.07 2.80 -0.27 -0.018 0.46615E+03 209 nontronite-Na 3.52 3.49 -0.03 -0.002 0.50227E+02 224 tobermorite 9.82 5.32 -4.50 -1.228 0.76837E+04 233 boehmite 4.41 2.53 -1.87 -0.312 0.31962E+04 235 ferrous-oxide 9.81 6.32 -3.49 -0.873 0.59624E+04 240 silica-amorphous -2.09 -3.27 -1.18 -0.394 0.20175E+04 242 an20ab80 2.02 1.03 -0.99 -0.076 0.16864E+04 243 an25ab75 2.65 1.52 -1.13 -0.087 0.19248E+04 244 an30ab70 3.28 2.01 -1.27 -0.098 0.21729E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 0.0400000 g Current total amount of reactant added: 1.3190000 g New total amount of reactant added: 1.3590000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.4569E-13 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 6 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 1.3590000 Water: Moles liquid = 0.5549E+02 kg liquid = 0.9997E+00 Moles total = 0.5549E+02 kg total = 0.9997E+00 Activity = 1.0000 Stoichiometric ionic strength = .1239707E-02 Osmotic coef. = 0.9797 True ionic strength = .1927576E-02 Chg. balance for total moles = 0.4569E-13 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.76389E-09 -9.1170 0.70938E-09 -9.1491 0.92864E+00 -0.0322 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13794E-03 -3.8603 0.12799E-03 -3.8928 0.92791E+00 -0.0325 4 SO4-- 0.25497E-04 -4.5935 0.19977E-04 -4.6995 0.78353E+00 -0.1059 5 HCO3- 0.11395E-04 -4.9433 0.10575E-04 -4.9757 0.92808E+00 -0.0324 6 HS- 0.28677E-13 -13.5425 0.26610E-13 -13.5750 0.92793E+00 -0.0325 7 Al+++ 0.20727E-24 -24.6835 0.12221E-24 -24.9129 0.58962E+00 -0.2294 8 H4SiO4 0.53829E-03 -3.2690 0.53829E-03 -3.2690 0.10000E+01 0.0000 9 Ca++ 0.12591E-07 -7.9000 0.98557E-08 -8.0063 0.78279E+00 -0.1064 10 Mg++ 0.22636E-09 -9.6452 0.17709E-09 -9.7518 0.78232E+00 -0.1066 11 Fe++ 0.13354E-11 -11.8744 0.10448E-11 -11.9809 0.78243E+00 -0.1066 12 K+ 0.46696E-04 -4.3307 0.43339E-04 -4.3631 0.92812E+00 -0.0324 13 Na+ 0.18457E-02 -2.7338 0.17126E-02 -2.7663 0.92789E+00 -0.0325 14 Mn++ 0.17942E-09 -9.7461 0.14040E-09 -9.8526 0.78251E+00 -0.1065 15 HPO4-- 0.79443E-05 -5.0999 0.62246E-05 -5.2059 0.78354E+00 -0.1059 16 HSiO3- 0.76358E-03 -3.1171 0.70853E-03 -3.1496 0.92791E+00 -0.0325 17 Ca(HSiO3)+ 0.17134E-09 -9.7661 0.15903E-09 -9.7985 0.92814E+00 -0.0324 18 Mg(HSiO3)+ 0.38315E-11 -11.4166 0.35562E-11 -11.4490 0.92814E+00 -0.0324 19 NaHSiO3,aq 0.19626E-04 -4.7072 0.19626E-04 -4.7072 0.10000E+01 0.0000 20 AlO+ 0.35596E-13 -13.4486 0.33038E-13 -13.4810 0.92814E+00 -0.0324 21 AlOH+2 0.14912E-18 -18.8265 0.11670E-18 -18.9329 0.78261E+00 -0.1065 22 HAlO2,aq 0.92750E-08 -8.0327 0.92750E-08 -8.0327 0.10000E+01 0.0000 23 AlO2- 0.31198E-04 -4.5059 0.28942E-04 -4.5385 0.92769E+00 -0.0326 24 CH4,aq 0.13689E-19 -19.8636 0.13683E-19 -19.8638 0.99962E+00 -0.0002 29 CO,aq 0.17962E-18 -18.7456 0.17962E-18 -18.7456 0.10000E+01 0.0000 30 CO2,aq 0.16036E-07 -7.7949 0.16030E-07 -7.7951 0.99962E+00 -0.0002 31 CO3-2 0.16624E-05 -5.7793 0.13021E-05 -5.8853 0.78331E+00 -0.1061 32 CaCO3,aq 0.16092E-09 -9.7934 0.16092E-09 -9.7934 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.28665E-11 -11.5426 0.26605E-11 -11.5750 0.92814E+00 -0.0324 34 CaCl+ 0.21995E-11 -11.6577 0.20414E-11 -11.6901 0.92814E+00 -0.0324 35 CaCl2,aq 0.62077E-16 -16.2071 0.62077E-16 -16.2071 0.10000E+01 0.0000 36 CaOH+ 0.10668E-08 -8.9719 0.99017E-09 -9.0043 0.92814E+00 -0.0324 37 CaSO4,aq 0.62521E-10 -10.2040 0.62521E-10 -10.2040 0.10000E+01 0.0000 38 HCl,aq 0.16638E-13 -13.7789 0.16638E-13 -13.7789 0.10000E+01 0.0000 43 FeCl+ 0.22807E-15 -15.6419 0.21168E-15 -15.6743 0.92814E+00 -0.0324 46 FeO,aq 0.80697E-10 -10.0931 0.80697E-10 -10.0931 0.10000E+01 0.0000 47 FeOH+ 0.51656E-10 -10.2869 0.47944E-10 -10.3193 0.92814E+00 -0.0324 48 HFeO2- 0.12827E-08 -8.8919 0.11903E-08 -8.9244 0.92791E+00 -0.0325 49 FeO+ 0.58338E-14 -14.2340 0.54146E-14 -14.2664 0.92814E+00 -0.0324 51 FeO2- 0.23728E-08 -8.6247 0.22017E-08 -8.6572 0.92791E+00 -0.0325 52 HFeO2,aq 0.19864E-09 -9.7019 0.19864E-09 -9.7019 0.10000E+01 0.0000 53 H2,aq 0.44623E-09 -9.3504 0.44606E-09 -9.3506 0.99962E+00 -0.0002 54 KCl,aq 0.10054E-09 -9.9977 0.10054E-09 -9.9977 0.10000E+01 0.0000 55 KHSO4,aq 0.17365E-17 -17.7603 0.17365E-17 -17.7603 0.10000E+01 0.0000 56 KOH,aq 0.26091E-07 -7.5835 0.26091E-07 -7.5835 0.10000E+01 0.0000 57 KSO4- 0.14479E-07 -7.8393 0.13435E-07 -7.8718 0.92791E+00 -0.0325 58 MgCO3,aq 0.72475E-12 -12.1398 0.72475E-12 -12.1398 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.52629E-13 -13.2788 0.48847E-13 -13.3112 0.92814E+00 -0.0324 60 MgCl+ 0.35819E-13 -13.4459 0.33246E-13 -13.4783 0.92814E+00 -0.0324 61 MgOH+ 0.10607E-09 -9.9744 0.98450E-10 -10.0068 0.92814E+00 -0.0324 63 MnO,aq 0.28894E-09 -9.5392 0.28894E-09 -9.5392 0.10000E+01 0.0000 64 MnOH+ 0.64482E-09 -9.1906 0.59848E-09 -9.2229 0.92814E+00 -0.0324 65 MnO2-2 0.24327E-13 -13.6139 0.19055E-13 -13.7200 0.78331E+00 -0.1061 66 HMnO2- 0.31915E-11 -11.4960 0.29614E-11 -11.5285 0.92791E+00 -0.0325 69 MnCl+ 0.11923E-12 -12.9236 0.11066E-12 -12.9560 0.92814E+00 -0.0324 70 MnSO4,aq 0.80972E-12 -12.0917 0.80972E-12 -12.0917 0.10000E+01 0.0000 71 NaCl,aq 0.72644E-07 -7.1388 0.72644E-07 -7.1388 0.10000E+01 0.0000 72 NaOH,aq 0.10373E-05 -5.9841 0.10373E-05 -5.9841 0.10000E+01 0.0000 74 OH- 0.87796E-03 -3.0565 0.81448E-03 -3.0891 0.92769E+00 -0.0326 79 HPO3-2 0.11046E-16 -16.9568 0.86526E-17 -17.0629 0.78331E+00 -0.1061 81 H2PO3- 0.13265E-19 -19.8773 0.12309E-19 -19.9098 0.92791E+00 -0.0325 82 H3PO4,aq 0.21908E-13 -13.6594 0.21908E-13 -13.6594 0.10000E+01 0.0000 83 H2PO4- 0.87774E-07 -7.0566 0.81456E-07 -7.0891 0.92802E+00 -0.0324 84 PO4-3 0.12064E-07 -7.9185 0.71592E-08 -8.1451 0.59343E+00 -0.2266 87 H2P2O7-2 0.66419E-15 -15.1777 0.52026E-15 -15.2838 0.78331E+00 -0.1061 88 HP2O7-3 0.24835E-12 -12.6049 0.14644E-12 -12.8343 0.58966E+00 -0.2294 89 P2O7-4 0.12397E-12 -12.9067 0.49318E-13 -13.3070 0.39783E+00 -0.4003 90 H2S,aq 0.58362E-16 -16.2339 0.58340E-16 -16.2340 0.99962E+00 -0.0002 97 SO3-2 0.14755E-14 -14.8311 0.11580E-14 -14.9363 0.78480E+00 -0.1052 98 HSO3- 0.55429E-16 -16.2563 0.51433E-16 -16.2888 0.92791E+00 -0.0325 99 HSO4- 0.14713E-10 -10.8323 0.13657E-10 -10.8646 0.92826E+00 -0.0323 Charge balance for all species = 0.4594E-13 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.7638894E-09 -.1788639E-02 -.1802515E+01 0.0000 2 H2O 0.1000000E+01 0.5550841E+02 0.9998203E+06 0.0000 3 Cl- 0.1379375E-03 0.1380103E-03 0.4891995E+01 5.2563 4 SO4-- 0.2549658E-04 0.2551135E-04 0.2450219E+01 13.5988 5 HCO3- 0.1139484E-04 0.1307342E-04 0.7975595E+00 4.1734 6 HS- 0.2867657E-13 -.2098401E-09 -.6938580E-05 -4.4258 7 Al+++ 0.2072664E-24 0.3120743E-04 0.8418715E+00 2.5345 8 H4SiO4 0.5382865E-03 0.1321494E-02 0.1269930E+03 -3.2690 9 Ca++ 0.1259055E-07 0.1405723E-07 0.5632841E-03 10.2919 10 Mg++ 0.2263637E-09 0.3370802E-09 0.8193617E-05 8.5464 11 Fe++ 0.1335386E-11 0.3987830E-08 0.2226682E-03 6.3173 12 K+ 0.4669590E-04 0.4673657E-04 0.1827164E+01 4.7860 13 Na+ 0.1845699E-02 0.1866435E-02 0.4290123E+02 6.3828 14 Mn++ 0.1794216E-09 0.1117321E-08 0.6137231E-04 8.4456 15 HPO4-- 0.7944250E-05 0.8044089E-05 0.7719244E+00 13.0924 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.2248998E-01 -.1788171E-02 -.2070181E-01 0.0000000E+00 2 H2O 0.5549121E+02 0.5549390E+02 -.2683851E-02 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.6316699E-04 0.2550468E-04 0.3766231E-04 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.3766252E-04 -.2097852E-09 -.3766231E-04 0.0000000E+00 7 Al+++ 0.4431348E-02 0.3119927E-04 0.4400149E-02 0.0000000E+00 8 H4SiO4 0.1415097E-01 0.1321148E-02 0.1282982E-01 0.0000000E+00 9 Ca++ 0.1577515E-02 0.1405356E-07 0.1577501E-02 0.0000000E+00 10 Mg++ 0.1078571E-02 0.3369921E-09 0.1078571E-02 0.0000000E+00 11 Fe++ 0.9689787E-03 0.3986787E-08 0.9689747E-03 0.0000000E+00 12 K+ 0.2885350E-03 0.4672436E-04 0.2418107E-03 0.0000000E+00 13 Na+ 0.1865947E-02 0.1865947E-02 0.0000000E+00 0.0000000E+00 14 Mn++ 0.2356315E-04 0.1117029E-08 0.2356203E-04 0.0000000E+00 15 HPO4-- 0.8041987E-05 0.8041987E-05 0.0000000E+00 0.0000000E+00 Chg. balance for solid moles: 0.1294E-17 Mass of aqueous solution: 0.999919E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 1.3590000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) clinochlore 0.2157E-03 -3.666 0.1199 -0.921 8.330 0.4561E-01 daphnite 0.1335E-03 -3.874 0.9528E-01 -1.021 6.620 0.2887E-01 chlorite-Mn 0.4712E-05 -5.327 0.3341E-02 -2.476 0.2321 0.1065E-02 hematite 0.1506E-03 -3.822 0.2406E-01 -1.619 1.672 0.4560E-02 microcline 0.9410E-04 -4.026 0.2619E-01 -1.582 1.820 0.1023E-01 muscovite 0.1477E-03 -3.831 0.5883E-01 -1.230 4.088 0.2080E-01 stilbite 0.1578E-02 -2.802 1.112 0.046 77.24 0.5185 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity clinochlore 0.6094E+00 0.6094E+00 1.0000 -0.215 daphnite 0.3773E+00 0.3773E+00 1.0000 -0.423 chlorite-Mn 0.1331E-01 0.1331E-01 1.0000 -1.876 hematite 0.1000E+01 0.1000E+01 1.0000 0.000 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 muscovite 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 1.439301 g Volume = 0.629654 cm3 Porosity: 59.2087% V(tot) - V(min): 0.91395E+00 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 1.3590000 g log = 0.1332 Original solution: 1000.0103000 g Original solution / Rock added: 735.84 (Water/Rock Ratio), log = 2.8668 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0203 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.1000E+01 0.9860 0.1006E+01 0.1020E+01 CO2,gas 0.1669E-05 1.0071 0.1715E-05 0.1703E-05 CH4,gas 0.1950E-16 1.0125 0.2014E-16 0.1989E-16 H2,gas 0.5737E-06 1.0005 0.5856E-06 0.5853E-06 H2S,gas 0.1578E-14 0.9960 0.1604E-14 0.1610E-14 S2,gas 0.2759E-36 1.0000 0.2815E-36 0.2815E-36 CO,gas 0.2623E-15 1.0000 0.2677E-15 0.2677E-15 SO3,gas 0.3725E-38 1.0000 0.3801E-38 0.3801E-38 SO2,gas 0.8488E-22 1.0000 0.8660E-22 0.8660E-22 HCl,gas 0.2877E-16 1.0000 0.2936E-16 0.2936E-16 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 46 clinochlore 39.07 39.07 0.00 0.000 0.24265E-10 47 daphnite 28.97 28.97 0.00 0.000 0.24265E-10 48 chlorite-Mn 46.87 46.87 0.00 0.000 0.00000E+00 90 hematite 12.57 12.57 0.00 0.000 -0.30331E-11 116 microcline -2.49 -2.49 0.00 0.000 0.15165E-11 120 muscovite 2.58 2.58 0.00 0.000 0.60662E-11 163 stilbite -7.52 -7.52 0.00 0.000 0.15165E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -14.12 -7.46 -2.488 0.12746E+05 -5.766 3 CH4,gas 4.54 -13.85 -18.39 -4.599 0.31409E+05 -16.696 4 H2,gas 8.00 0.07 -7.93 -4.532 0.13543E+05 -6.232 5 H2S,gas -6.23 -22.72 -16.49 -8.247 0.28163E+05 -14.795 6 S2,gas -7.34 -45.58 -38.25 -5.885 0.65310E+05 -36.551 7 CO,gas 3.21 -14.06 -17.27 -5.314 0.29490E+05 -15.572 8 SO3,gas 17.12 -23.00 -40.12 -10.030 0.68502E+05 -38.420 9 SO2,gas 0.83 -22.93 -23.76 -6.336 0.40572E+05 -22.062 10 HCl,gas 5.19 -13.04 -18.23 -9.116 0.31129E+05 -16.532 11 acmite 7.71 6.13 -1.58 -0.164 0.27009E+04 15 albite-high 0.69 -0.89 -1.58 -0.122 0.27025E+04 16 albite -0.38 -0.89 -0.51 -0.039 0.86373E+03 19 spessartine 24.46 20.60 -3.86 -0.193 0.65884E+04 20 analcite 3.32 2.38 -0.94 -0.105 0.16094E+04 21 andalusite 5.00 1.80 -3.20 -0.320 0.54666E+04 26 annite 20.12 16.47 -3.66 -0.203 0.62459E+04 27 phlogopite 27.06 23.15 -3.91 -0.217 0.66793E+04 29 anorthite 12.71 8.82 -3.89 -0.299 0.66377E+04 32 apatite-OH -18.15 -19.05 -0.90 -0.069 0.15354E+04 35 aragonite 0.97 -3.83 -4.80 -1.600 0.81949E+04 36 brucite 12.57 8.55 -4.02 -0.804 0.68677E+04 37 calcite 0.81 -3.83 -4.64 -1.548 0.79306E+04 38 carnegieite-low 9.02 5.65 -3.38 -0.482 0.57628E+04 39 carnegieite-high 10.09 5.65 -4.45 -0.635 0.75898E+04 40 carpholite-Mg 8.58 7.08 -1.50 -0.100 0.25692E+04 41 carpholite-Fe 6.71 4.85 -1.86 -0.124 0.31834E+04 42 celadonite 5.34 2.79 -2.55 -0.150 0.43552E+04 43 celadonite-Fe 3.88 0.56 -3.31 -0.195 0.56598E+04 44 chrysotile 23.89 19.10 -4.79 -0.399 0.81806E+04 50 chloritoid-Mg 13.20 10.35 -2.85 -0.190 0.48686E+04 51 chloritoid-Fe 9.17 8.12 -1.06 -0.070 0.18038E+04 52 chloritoid-Mn 11.40 10.25 -1.16 -0.077 0.19730E+04 54 coesite -2.38 -3.27 -0.89 -0.298 0.15246E+04 59 corundum 8.38 5.07 -3.31 -0.301 0.56589E+04 61 cristobalite -2.56 -3.27 -0.71 -0.236 0.12100E+04 63 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71234E+04 65 diaspore 2.87 2.53 -0.34 -0.057 0.57923E+03 67 diopside 16.18 12.30 -3.88 -0.388 0.66266E+04 68 hedenbergite 14.21 10.07 -4.14 -0.414 0.70639E+04 75 epidote 24.67 22.13 -2.54 -0.123 0.43387E+04 76 clinozoisite 22.81 18.38 -4.43 -0.201 0.75568E+04 77 epidote-Fe 29.84 25.88 -3.96 -0.206 0.67672E+04 78 fayalite 14.05 9.37 -4.68 -0.669 0.79912E+04 83 gibbsite 4.08 2.53 -1.54 -0.221 0.26378E+04 87 greenalite 16.14 12.41 -3.73 -0.310 0.63614E+04 91 heulandite -5.83 -7.52 -1.69 -0.077 0.28938E+04 95 jadeite 4.22 2.38 -1.84 -0.184 0.31349E+04 97 kalsilite 7.58 4.05 -3.53 -0.505 0.60315E+04 98 kaolinite -1.33 -1.47 -0.14 -0.012 0.23269E+03 99 kyanite 4.88 1.80 -3.08 -0.308 0.52525E+04 101 laumontite 2.88 2.28 -0.60 -0.040 0.10219E+04 102 lawsonite 9.62 8.82 -0.79 -0.053 0.13544E+04 103 leucite 4.12 0.78 -3.34 -0.334 0.56968E+04 105 lizardite 23.24 19.10 -4.14 -0.345 0.70732E+04 107 magnetite 20.09 18.88 -1.20 -0.098 0.20557E+04 108 minnesotaite 10.39 5.88 -4.51 -0.265 0.77044E+04 113 margarite 17.32 13.89 -3.43 -0.137 0.58597E+04 121 paragonite 4.24 4.18 -0.06 -0.004 0.10283E+03 122 nepheline 8.34 5.65 -2.69 -0.384 0.45951E+04 134 phlogopite-Na 29.65 24.75 -4.90 -0.272 0.83618E+04 136 prehnite 19.37 15.85 -3.53 -0.207 0.60206E+04 137 prehnite-Fe 22.50 19.59 -2.90 -0.175 0.49575E+04 145 pyroxmangite 7.40 5.18 -2.22 -0.444 0.37941E+04 146 pyrophyllite -6.18 -8.01 -1.83 -0.114 0.31268E+04 147 quartz -2.99 -3.27 -0.28 -0.093 0.47733E+03 151 rhodochrosite -0.98 -5.68 -4.70 -1.568 0.80301E+04 152 rhodonite 7.45 5.18 -2.27 -0.454 0.38744E+04 153 sanidine -1.28 -2.49 -1.21 -0.093 0.20677E+04 156 sillimanite 5.26 1.80 -3.46 -0.346 0.59106E+04 164 stilpnomelane-Fe 13.02 12.90 -0.12 -0.004 0.20569E+03 165 stilpnomelane-Mg 27.44 24.04 -3.40 -0.101 0.58041E+04 168 sudoite 21.08 17.42 -3.65 -0.118 0.62384E+04 171 talc 16.49 12.56 -3.93 -0.231 0.67065E+04 174 tephroite 18.09 13.62 -4.46 -0.638 0.76214E+04 177 topaz-H 4.62 1.80 -2.82 -0.256 0.48126E+04 178 tridymite -2.63 -3.27 -0.64 -0.214 0.10973E+04 187 wairakite 3.95 2.28 -1.67 -0.098 0.28439E+04 188 walstromite 11.51 7.02 -4.49 -0.897 0.76602E+04 189 wollastonite 10.46 7.02 -3.44 -0.688 0.58706E+04 190 pseudo-wollastonite 11.00 7.02 -3.98 -0.795 0.67905E+04 191 zoisite 22.85 18.38 -4.47 -0.203 0.76309E+04 192 akaganeite 7.75 6.28 -1.47 -0.318 0.25125E+04 193 beidellite-Ca -1.65 -4.39 -2.75 -0.170 0.46923E+04 194 beidellite-H -2.33 -6.09 -3.77 -0.240 0.64297E+04 195 beidellite-K -1.52 -4.51 -2.99 -0.183 0.51092E+04 196 beidellite-Mg -1.79 -4.68 -2.89 -0.179 0.49379E+04 197 beidellite-Na -1.34 -3.99 -2.64 -0.162 0.45134E+04 199 chalcedony -2.80 -3.27 -0.47 -0.156 0.79662E+03 201 montmorillonite-Ca -2.29 -4.32 -2.03 -0.126 0.34733E+04 202 montmorillonite-K -2.24 -4.44 -2.21 -0.135 0.37683E+04 203 montmorillonite-Mg -2.48 -4.61 -2.13 -0.132 0.36421E+04 204 montmorillonite-Na -2.04 -3.92 -1.88 -0.115 0.32083E+04 205 nontronite-Ca 3.21 3.10 -0.11 -0.007 0.18952E+03 206 nontronite-H 2.53 1.41 -1.13 -0.076 0.19249E+04 207 nontronite-K 3.34 2.98 -0.36 -0.023 0.60776E+03 208 nontronite-Mg 3.07 2.82 -0.26 -0.017 0.44238E+03 209 nontronite-Na 3.52 3.51 -0.01 -0.001 0.13672E+02 224 tobermorite 9.82 5.30 -4.52 -1.233 0.77158E+04 233 boehmite 4.41 2.53 -1.87 -0.312 0.31962E+04 235 ferrous-oxide 9.81 6.32 -3.49 -0.874 0.59664E+04 240 silica-amorphous -2.09 -3.27 -1.18 -0.393 0.20108E+04 242 an20ab80 2.02 1.05 -0.96 -0.074 0.16477E+04 243 an25ab75 2.65 1.54 -1.11 -0.085 0.18906E+04 244 an30ab70 3.28 2.02 -1.26 -0.097 0.21432E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 0.0400000 g Current total amount of reactant added: 1.3590000 g New total amount of reactant added: 1.3990000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.4569E-13 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 6 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 1.3990000 Water: Moles liquid = 0.5549E+02 kg liquid = 0.9997E+00 Moles total = 0.5549E+02 kg total = 0.9997E+00 Activity = 1.0000 Stoichiometric ionic strength = .1267468E-02 Osmotic coef. = 0.9795 True ionic strength = .1974643E-02 Chg. balance for total moles = 0.4569E-13 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.74737E-09 -9.1265 0.69360E-09 -9.1589 0.92806E+00 -0.0324 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13794E-03 -3.8603 0.12791E-03 -3.8931 0.92731E+00 -0.0328 4 SO4-- 0.25497E-04 -4.5935 0.19927E-04 -4.7006 0.78152E+00 -0.1071 5 HCO3- 0.11360E-04 -4.9446 0.10536E-04 -4.9773 0.92748E+00 -0.0327 6 HS- 0.26795E-13 -13.5719 0.24848E-13 -13.6047 0.92732E+00 -0.0328 7 Al+++ 0.19487E-24 -24.7103 0.11423E-24 -24.9422 0.58620E+00 -0.2320 8 H4SiO4 0.54318E-03 -3.2651 0.54318E-03 -3.2651 0.10000E+01 0.0000 9 Ca++ 0.11326E-07 -7.9459 0.88432E-08 -8.0534 0.78076E+00 -0.1075 10 Mg++ 0.21579E-09 -9.6660 0.16838E-09 -9.7737 0.78029E+00 -0.1077 11 Fe++ 0.12730E-11 -11.8952 0.99347E-12 -12.0028 0.78040E+00 -0.1077 12 K+ 0.44462E-04 -4.3520 0.41239E-04 -4.3847 0.92752E+00 -0.0327 13 Na+ 0.18947E-02 -2.7225 0.17570E-02 -2.7552 0.92729E+00 -0.0328 14 Mn++ 0.17104E-09 -9.7669 0.13350E-09 -9.8745 0.78049E+00 -0.1076 15 HPO4-- 0.81800E-05 -5.0872 0.63929E-05 -5.1943 0.78153E+00 -0.1071 16 HSiO3- 0.78857E-03 -3.1032 0.73125E-03 -3.1359 0.92731E+00 -0.0328 17 Ca(HSiO3)+ 0.15877E-09 -9.7992 0.14727E-09 -9.8319 0.92754E+00 -0.0327 18 Mg(HSiO3)+ 0.37623E-11 -11.4245 0.34897E-11 -11.4572 0.92754E+00 -0.0327 19 NaHSiO3,aq 0.20779E-04 -4.6824 0.20779E-04 -4.6824 0.10000E+01 0.0000 20 AlO+ 0.34827E-13 -13.4581 0.32303E-13 -13.4908 0.92754E+00 -0.0327 21 AlOH+2 0.14293E-18 -18.8449 0.11157E-18 -18.9525 0.78059E+00 -0.1076 22 HAlO2,aq 0.92750E-08 -8.0327 0.92750E-08 -8.0327 0.10000E+01 0.0000 23 AlO2- 0.31929E-04 -4.4958 0.29601E-04 -4.5287 0.92708E+00 -0.0329 24 CH4,aq 0.12767E-19 -19.8939 0.12762E-19 -19.8941 0.99961E+00 -0.0002 29 CO,aq 0.17308E-18 -18.7618 0.17308E-18 -18.7618 0.10000E+01 0.0000 30 CO2,aq 0.15621E-07 -7.8063 0.15615E-07 -7.8065 0.99961E+00 -0.0002 31 CO3-2 0.16982E-05 -5.7700 0.13268E-05 -5.8772 0.78130E+00 -0.1072 32 CaCO3,aq 0.14712E-09 -9.8323 0.14712E-09 -9.8323 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.25641E-11 -11.5911 0.23783E-11 -11.6237 0.92754E+00 -0.0327 34 CaCl+ 0.19735E-11 -11.7048 0.18305E-11 -11.7374 0.92754E+00 -0.0327 35 CaCl2,aq 0.55627E-16 -16.2547 0.55627E-16 -16.2547 0.10000E+01 0.0000 36 CaOH+ 0.97965E-09 -9.0089 0.90867E-09 -9.0416 0.92754E+00 -0.0327 37 CaSO4,aq 0.55957E-10 -10.2521 0.55957E-10 -10.2521 0.10000E+01 0.0000 38 HCl,aq 0.16257E-13 -13.7890 0.16257E-13 -13.7890 0.10000E+01 0.0000 43 FeCl+ 0.21685E-15 -15.6638 0.20114E-15 -15.6965 0.92754E+00 -0.0327 46 FeO,aq 0.80260E-10 -10.0955 0.80260E-10 -10.0955 0.10000E+01 0.0000 47 FeOH+ 0.50266E-10 -10.2987 0.46624E-10 -10.3314 0.92754E+00 -0.0327 48 HFeO2- 0.13057E-08 -8.8842 0.12107E-08 -8.9169 0.92731E+00 -0.0328 49 FeO+ 0.57077E-14 -14.2435 0.52942E-14 -14.2762 0.92754E+00 -0.0327 51 FeO2- 0.24283E-08 -8.6147 0.22518E-08 -8.6475 0.92731E+00 -0.0328 52 HFeO2,aq 0.19864E-09 -9.7019 0.19864E-09 -9.7019 0.10000E+01 0.0000 53 H2,aq 0.44141E-09 -9.3552 0.44123E-09 -9.3553 0.99961E+00 -0.0002 54 KCl,aq 0.95603E-10 -10.0195 0.95603E-10 -10.0195 0.10000E+01 0.0000 55 KHSO4,aq 0.16115E-17 -17.7928 0.16115E-17 -17.7928 0.10000E+01 0.0000 56 KOH,aq 0.25391E-07 -7.5953 0.25391E-07 -7.5953 0.10000E+01 0.0000 57 KSO4- 0.13751E-07 -7.8617 0.12752E-07 -7.8944 0.92731E+00 -0.0328 58 MgCO3,aq 0.70215E-12 -12.1536 0.70215E-12 -12.1536 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.49886E-13 -13.3020 0.46272E-13 -13.3347 0.92754E+00 -0.0327 60 MgCl+ 0.34058E-13 -13.4678 0.31590E-13 -13.5005 0.92754E+00 -0.0327 61 MgOH+ 0.10322E-09 -9.9862 0.95738E-10 -10.0189 0.92754E+00 -0.0327 63 MnO,aq 0.28737E-09 -9.5416 0.28737E-09 -9.5416 0.10000E+01 0.0000 64 MnOH+ 0.62747E-09 -9.2024 0.58200E-09 -9.2351 0.92754E+00 -0.0327 65 MnO2-2 0.25373E-13 -13.5956 0.19824E-13 -13.7028 0.78130E+00 -0.1072 66 HMnO2- 0.32486E-11 -11.4883 0.30124E-11 -11.5211 0.92731E+00 -0.0328 69 MnCl+ 0.11336E-12 -12.9455 0.10515E-12 -12.9782 0.92754E+00 -0.0327 70 MnSO4,aq 0.76796E-12 -12.1147 0.76796E-12 -12.1147 0.10000E+01 0.0000 71 NaCl,aq 0.74477E-07 -7.1280 0.74477E-07 -7.1280 0.10000E+01 0.0000 72 NaOH,aq 0.10883E-05 -5.9632 0.10883E-05 -5.9632 0.10000E+01 0.0000 74 OH- 0.89853E-03 -3.0465 0.83301E-03 -3.0794 0.92708E+00 -0.0329 79 HPO3-2 0.11251E-16 -16.9488 0.87905E-17 -17.0560 0.78130E+00 -0.1072 81 H2PO3- 0.13185E-19 -19.8799 0.12227E-19 -19.9127 0.92731E+00 -0.0328 82 H3PO4,aq 0.21510E-13 -13.6674 0.21510E-13 -13.6674 0.10000E+01 0.0000 83 H2PO4- 0.88199E-07 -7.0545 0.81798E-07 -7.0873 0.92742E+00 -0.0327 84 PO4-3 0.12744E-07 -7.8947 0.75201E-08 -8.1238 0.59007E+00 -0.2291 87 H2P2O7-2 0.67149E-15 -15.1730 0.52463E-15 -15.2801 0.78130E+00 -0.1072 88 HP2O7-3 0.25763E-12 -12.5890 0.15103E-12 -12.8209 0.58624E+00 -0.2319 89 P2O7-4 0.13211E-12 -12.8791 0.52020E-13 -13.2838 0.39377E+00 -0.4048 90 H2S,aq 0.53287E-16 -16.2734 0.53266E-16 -16.2736 0.99961E+00 -0.0002 97 SO3-2 0.14596E-14 -14.8358 0.11426E-14 -14.9421 0.78281E+00 -0.1063 98 HSO3- 0.53509E-16 -16.2716 0.49619E-16 -16.3043 0.92731E+00 -0.0328 99 HSO4- 0.14358E-10 -10.8429 0.13320E-10 -10.8755 0.92766E+00 -0.0326 Charge balance for all species = 0.4594E-13 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.7473709E-09 -.1838354E-02 -.1852609E+01 0.0000 2 H2O 0.1000000E+01 0.5550840E+02 0.9998163E+06 0.0000 3 Cl- 0.1379367E-03 0.1380113E-03 0.4892011E+01 5.2658 4 SO4-- 0.2549750E-04 0.2551154E-04 0.2450228E+01 13.6172 5 HCO3- 0.1135955E-04 0.1307351E-04 0.7975621E+00 4.1816 6 HS- 0.2679538E-13 -.2179918E-09 -.7208096E-05 -4.4458 7 Al+++ 0.1948696E-24 0.3193811E-04 0.8615792E+00 2.5345 8 H4SiO4 0.5431844E-03 0.1352535E-02 0.1299755E+03 -3.2651 9 Ca++ 0.1132641E-07 0.1267245E-07 0.5077928E-03 10.2644 10 Mg++ 0.2157929E-09 0.3235581E-09 0.7864896E-05 8.5441 11 Fe++ 0.1273022E-11 0.4064417E-08 0.2269437E-03 6.3149 12 K+ 0.4446195E-04 0.4450119E-04 0.1739765E+01 4.7742 13 Na+ 0.1894729E-02 0.1916672E-02 0.4405578E+02 6.4037 14 Mn++ 0.1710423E-09 0.1090033E-08 0.5987319E-04 8.4432 15 HPO4-- 0.8179970E-05 0.8280914E-05 0.7946474E+00 13.1235 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.2315232E-01 -.1837860E-02 -.2131446E-01 0.0000000E+00 2 H2O 0.5549071E+02 0.5549349E+02 -.2781163E-02 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.6427553E-04 0.2550469E-04 0.3877084E-04 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.3877106E-04 -.2179332E-09 -.3877084E-04 0.0000000E+00 7 Al+++ 0.4561778E-02 0.3192953E-04 0.4529848E-02 0.0000000E+00 8 H4SiO4 0.1456748E-01 0.1352172E-02 0.1321531E-01 0.0000000E+00 9 Ca++ 0.1623521E-02 0.1266905E-07 0.1623508E-02 0.0000000E+00 10 Mg++ 0.1110317E-02 0.3234712E-09 0.1110317E-02 0.0000000E+00 11 Fe++ 0.9974990E-03 0.4063326E-08 0.9974950E-03 0.0000000E+00 12 K+ 0.2970276E-03 0.4448923E-04 0.2525384E-03 0.0000000E+00 13 Na+ 0.1916157E-02 0.1916157E-02 0.0000000E+00 0.0000000E+00 14 Mn++ 0.2425670E-04 0.1089740E-08 0.2425561E-04 0.0000000E+00 15 HPO4-- 0.8278690E-05 0.8278690E-05 0.0000000E+00 0.0000000E+00 Chg. balance for solid moles: -.4737E-17 Mass of aqueous solution: 0.999916E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 1.3990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) clinochlore 0.2221E-03 -3.654 0.1234 -0.909 8.327 0.4695E-01 daphnite 0.1375E-03 -3.862 0.9808E-01 -1.008 6.617 0.2972E-01 chlorite-Mn 0.4851E-05 -5.314 0.3439E-02 -2.464 0.2320 0.1096E-02 hematite 0.1551E-03 -3.809 0.2477E-01 -1.606 1.671 0.4694E-02 microcline 0.1018E-03 -3.992 0.2833E-01 -1.548 1.911 0.1107E-01 muscovite 0.1508E-03 -3.822 0.6005E-01 -1.221 4.051 0.2123E-01 stilbite 0.1624E-02 -2.790 1.144 0.058 77.19 0.5336 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity clinochlore 0.6094E+00 0.6094E+00 1.0000 -0.215 daphnite 0.3773E+00 0.3773E+00 1.0000 -0.423 chlorite-Mn 0.1331E-01 0.1331E-01 1.0000 -1.876 hematite 0.1000E+01 0.1000E+01 1.0000 0.000 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 muscovite 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 1.482216 g Volume = 0.648399 cm3 Porosity: 58.4253% V(tot) - V(min): 0.91120E+00 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 1.3990000 g log = 0.1458 Original solution: 1000.0103000 g Original solution / Rock added: 714.80 (Water/Rock Ratio), log = 2.8542 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0203 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.1000E+01 0.9860 0.1006E+01 0.1020E+01 CO2,gas 0.1626E-05 1.0071 0.1671E-05 0.1659E-05 CH4,gas 0.1818E-16 1.0125 0.1878E-16 0.1855E-16 H2,gas 0.5675E-06 1.0005 0.5793E-06 0.5790E-06 H2S,gas 0.1441E-14 0.9960 0.1464E-14 0.1470E-14 S2,gas 0.2350E-36 1.0000 0.2398E-36 0.2398E-36 CO,gas 0.2528E-15 1.0000 0.2579E-15 0.2579E-15 SO3,gas 0.3553E-38 1.0000 0.3625E-38 0.3625E-38 SO2,gas 0.8006E-22 1.0000 0.8169E-22 0.8169E-22 HCl,gas 0.2812E-16 1.0000 0.2869E-16 0.2869E-16 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 46 clinochlore 39.07 39.07 0.00 0.000 -0.36397E-10 47 daphnite 28.97 28.97 0.00 0.000 -0.30331E-10 48 chlorite-Mn 46.87 46.87 0.00 0.000 0.00000E+00 90 hematite 12.57 12.57 0.00 0.000 0.30331E-11 116 microcline -2.49 -2.49 0.00 0.000 0.13649E-10 120 muscovite 2.58 2.58 0.00 0.000 0.60662E-11 163 stilbite -7.52 -7.52 0.00 0.000 -0.90992E-11 209 nontronite-Na 3.52 3.53 0.01 0.001 -0.22741E+02 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -14.14 -7.48 -2.492 0.12765E+05 -5.777 3 CH4,gas 4.54 -13.88 -18.43 -4.606 0.31460E+05 -16.726 4 H2,gas 8.00 0.06 -7.94 -4.535 0.13551E+05 -6.237 5 H2S,gas -6.23 -22.76 -16.53 -8.267 0.28230E+05 -14.834 6 S2,gas -7.34 -45.65 -38.32 -5.895 0.65429E+05 -36.620 7 CO,gas 3.21 -14.07 -17.29 -5.319 0.29518E+05 -15.589 8 SO3,gas 17.12 -23.02 -40.14 -10.035 0.68537E+05 -38.441 9 SO2,gas 0.83 -22.95 -23.79 -6.343 0.40615E+05 -22.088 10 HCl,gas 5.19 -13.05 -18.24 -9.121 0.31147E+05 -16.542 11 acmite 7.71 6.16 -1.55 -0.161 0.26518E+04 15 albite-high 0.69 -0.86 -1.55 -0.119 0.26467E+04 16 albite -0.38 -0.86 -0.47 -0.036 0.80794E+03 19 spessartine 24.46 20.60 -3.85 -0.193 0.65803E+04 20 analcite 3.32 2.41 -0.91 -0.102 0.15604E+04 21 andalusite 5.00 1.80 -3.20 -0.320 0.54599E+04 26 annite 20.12 16.46 -3.67 -0.204 0.62580E+04 27 phlogopite 27.06 23.15 -3.92 -0.218 0.66914E+04 29 anorthite 12.71 8.80 -3.91 -0.301 0.66713E+04 32 apatite-OH -18.15 -19.21 -1.06 -0.082 0.18113E+04 35 aragonite 0.97 -3.87 -4.84 -1.613 0.82614E+04 36 brucite 12.57 8.54 -4.02 -0.805 0.68717E+04 37 calcite 0.81 -3.87 -4.68 -1.561 0.79971E+04 38 carnegieite-low 9.02 5.67 -3.35 -0.479 0.57204E+04 39 carnegieite-high 10.09 5.67 -4.42 -0.631 0.75474E+04 40 carpholite-Mg 8.58 7.08 -1.50 -0.100 0.25598E+04 41 carpholite-Fe 6.71 4.85 -1.86 -0.124 0.31740E+04 42 celadonite 5.34 2.79 -2.55 -0.150 0.43525E+04 43 celadonite-Fe 3.88 0.56 -3.31 -0.195 0.56571E+04 44 chrysotile 23.89 19.10 -4.79 -0.399 0.81793E+04 50 chloritoid-Mg 13.20 10.35 -2.85 -0.190 0.48659E+04 51 chloritoid-Fe 9.17 8.12 -1.05 -0.070 0.18011E+04 52 chloritoid-Mn 11.40 10.25 -1.15 -0.077 0.19703E+04 54 coesite -2.38 -3.27 -0.89 -0.296 0.15179E+04 59 corundum 8.38 5.07 -3.31 -0.301 0.56589E+04 61 cristobalite -2.56 -3.27 -0.70 -0.235 0.12033E+04 63 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71234E+04 65 diaspore 2.87 2.53 -0.34 -0.057 0.57923E+03 67 diopside 16.18 12.28 -3.90 -0.390 0.66643E+04 68 hedenbergite 14.21 10.05 -4.16 -0.416 0.71015E+04 75 epidote 24.67 22.09 -2.58 -0.125 0.44126E+04 76 clinozoisite 22.81 18.34 -4.47 -0.203 0.76307E+04 77 epidote-Fe 29.84 25.83 -4.01 -0.208 0.68410E+04 78 fayalite 14.05 9.36 -4.68 -0.669 0.79925E+04 83 gibbsite 4.08 2.53 -1.54 -0.221 0.26378E+04 87 greenalite 16.14 12.41 -3.72 -0.310 0.63600E+04 91 heulandite -5.83 -7.52 -1.69 -0.077 0.28938E+04 95 jadeite 4.22 2.41 -1.81 -0.181 0.30859E+04 97 kalsilite 7.58 4.04 -3.54 -0.506 0.60450E+04 98 kaolinite -1.33 -1.46 -0.13 -0.012 0.21926E+03 99 kyanite 4.88 1.80 -3.07 -0.307 0.52458E+04 101 laumontite 2.88 2.27 -0.61 -0.041 0.10421E+04 102 lawsonite 9.62 8.80 -0.81 -0.054 0.13879E+04 103 leucite 4.12 0.78 -3.34 -0.334 0.57035E+04 105 lizardite 23.24 19.10 -4.14 -0.345 0.70719E+04 107 magnetite 20.09 18.88 -1.21 -0.098 0.20597E+04 108 minnesotaite 10.39 5.88 -4.50 -0.265 0.76896E+04 113 margarite 17.32 13.87 -3.45 -0.138 0.58933E+04 121 paragonite 4.24 4.21 -0.03 -0.002 0.47038E+02 122 nepheline 8.34 5.67 -2.67 -0.381 0.45528E+04 134 phlogopite-Na 29.65 24.78 -4.87 -0.271 0.83181E+04 136 prehnite 19.37 15.80 -3.57 -0.210 0.60945E+04 137 prehnite-Fe 22.50 19.55 -2.95 -0.177 0.50314E+04 145 pyroxmangite 7.40 5.18 -2.22 -0.444 0.37914E+04 146 pyrophyllite -6.18 -7.99 -1.82 -0.113 0.30999E+04 147 quartz -2.99 -3.27 -0.28 -0.092 0.47061E+03 151 rhodochrosite -0.98 -5.69 -4.72 -1.572 0.80536E+04 152 rhodonite 7.45 5.18 -2.27 -0.453 0.38717E+04 153 sanidine -1.28 -2.49 -1.21 -0.093 0.20677E+04 156 sillimanite 5.26 1.80 -3.46 -0.346 0.59038E+04 164 stilpnomelane-Fe 13.02 12.91 -0.11 -0.003 0.18218E+03 165 stilpnomelane-Mg 27.44 24.06 -3.39 -0.101 0.57805E+04 168 sudoite 21.08 17.43 -3.65 -0.118 0.62263E+04 171 talc 16.49 12.57 -3.92 -0.231 0.66917E+04 174 tephroite 18.09 13.62 -4.46 -0.638 0.76227E+04 177 topaz-H 4.62 1.80 -2.81 -0.256 0.48059E+04 178 tridymite -2.63 -3.27 -0.64 -0.213 0.10906E+04 187 wairakite 3.95 2.27 -1.68 -0.099 0.28640E+04 188 walstromite 11.51 7.00 -4.51 -0.902 0.77005E+04 189 wollastonite 10.46 7.00 -3.46 -0.692 0.59109E+04 190 pseudo-wollastonite 11.00 7.00 -4.00 -0.800 0.68308E+04 191 zoisite 22.85 18.34 -4.51 -0.205 0.77048E+04 192 akaganeite 7.75 6.28 -1.47 -0.318 0.25125E+04 193 beidellite-Ca -1.65 -4.38 -2.74 -0.169 0.46754E+04 194 beidellite-H -2.33 -6.08 -3.75 -0.239 0.64051E+04 195 beidellite-K -1.52 -4.50 -2.98 -0.183 0.50912E+04 196 beidellite-Mg -1.79 -4.67 -2.88 -0.178 0.49139E+04 197 beidellite-Na -1.34 -3.96 -2.62 -0.161 0.44770E+04 199 chalcedony -2.80 -3.27 -0.46 -0.154 0.78991E+03 201 montmorillonite-Ca -2.29 -4.31 -2.02 -0.125 0.34555E+04 202 montmorillonite-K -2.24 -4.43 -2.20 -0.134 0.37495E+04 203 montmorillonite-Mg -2.48 -4.60 -2.12 -0.131 0.36172E+04 204 montmorillonite-Na -2.04 -3.89 -1.86 -0.114 0.31710E+04 205 nontronite-Ca 3.21 3.11 -0.10 -0.007 0.17263E+03 206 nontronite-H 2.53 1.42 -1.11 -0.075 0.19002E+04 207 nontronite-K 3.34 3.00 -0.35 -0.022 0.58976E+03 208 nontronite-Mg 3.07 2.83 -0.25 -0.016 0.41839E+03 224 tobermorite 9.82 5.29 -4.54 -1.238 0.77483E+04 233 boehmite 4.41 2.53 -1.87 -0.312 0.31962E+04 235 ferrous-oxide 9.81 6.31 -3.50 -0.874 0.59704E+04 240 silica-amorphous -2.09 -3.27 -1.17 -0.391 0.20041E+04 242 an20ab80 2.02 1.08 -0.94 -0.073 0.16098E+04 243 an25ab75 2.65 1.56 -1.09 -0.084 0.18572E+04 244 an30ab70 3.28 2.04 -1.24 -0.095 0.21142E+04 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 6 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 1.3990000 Water: Moles liquid = 0.5549E+02 kg liquid = 0.9997E+00 Moles total = 0.5549E+02 kg total = 0.9997E+00 Activity = 1.0000 Stoichiometric ionic strength = .1268026E-02 Osmotic coef. = 0.9795 True ionic strength = .1974714E-02 Chg. balance for total moles = 0.4569E-13 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.74439E-09 -9.1282 0.69083E-09 -9.1606 0.92805E+00 -0.0324 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13794E-03 -3.8603 0.12791E-03 -3.8931 0.92730E+00 -0.0328 4 SO4-- 0.25497E-04 -4.5935 0.19926E-04 -4.7006 0.78152E+00 -0.1071 5 HCO3- 0.11354E-04 -4.9449 0.10530E-04 -4.9776 0.92748E+00 -0.0327 6 HS- 0.27822E-13 -13.5556 0.25800E-13 -13.5884 0.92732E+00 -0.0328 7 Al+++ 0.19255E-24 -24.7155 0.11287E-24 -24.9474 0.58620E+00 -0.2320 8 H4SiO4 0.53849E-03 -3.2688 0.53849E-03 -3.2688 0.10000E+01 0.0000 9 Ca++ 0.11939E-07 -7.9230 0.93218E-08 -8.0305 0.78076E+00 -0.1075 10 Mg++ 0.21519E-09 -9.6672 0.16791E-09 -9.7749 0.78028E+00 -0.1077 11 Fe++ 0.12695E-11 -11.8964 0.99069E-12 -12.0041 0.78040E+00 -0.1077 12 K+ 0.45452E-04 -4.3425 0.42157E-04 -4.3751 0.92752E+00 -0.0327 13 Na+ 0.18938E-02 -2.7227 0.17561E-02 -2.7555 0.92729E+00 -0.0328 14 Mn++ 0.17056E-09 -9.7681 0.13312E-09 -9.8757 0.78048E+00 -0.1076 15 HPO4-- 0.81803E-05 -5.0872 0.63931E-05 -5.1943 0.78153E+00 -0.1071 16 HSiO3- 0.78490E-03 -3.1052 0.72784E-03 -3.1380 0.92730E+00 -0.0328 17 Ca(HSiO3)+ 0.16658E-09 -9.7784 0.15451E-09 -9.8110 0.92754E+00 -0.0327 18 Mg(HSiO3)+ 0.37343E-11 -11.4278 0.34637E-11 -11.4605 0.92754E+00 -0.0327 19 NaHSiO3,aq 0.20672E-04 -4.6846 0.20672E-04 -4.6846 0.10000E+01 0.0000 20 AlO+ 0.34688E-13 -13.4598 0.32174E-13 -13.4925 0.92754E+00 -0.0327 21 AlOH+2 0.14179E-18 -18.8484 0.11068E-18 -18.9559 0.78059E+00 -0.1076 22 HAlO2,aq 0.92750E-08 -8.0327 0.92750E-08 -8.0327 0.10000E+01 0.0000 23 AlO2- 0.32057E-04 -4.4941 0.29719E-04 -4.5270 0.92708E+00 -0.0329 24 CH4,aq 0.13249E-19 -19.8778 0.13244E-19 -19.8780 0.99961E+00 -0.0002 29 CO,aq 0.17410E-18 -18.7592 0.17410E-18 -18.7592 0.10000E+01 0.0000 30 CO2,aq 0.15550E-07 -7.8083 0.15544E-07 -7.8084 0.99961E+00 -0.0002 31 CO3-2 0.17041E-05 -5.7685 0.13314E-05 -5.8757 0.78129E+00 -0.1072 32 CaCO3,aq 0.15562E-09 -9.8079 0.15562E-09 -9.8079 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.27014E-11 -11.5684 0.25057E-11 -11.6011 0.92754E+00 -0.0327 34 CaCl+ 0.20803E-11 -11.6819 0.19296E-11 -11.7145 0.92754E+00 -0.0327 35 CaCl2,aq 0.58637E-16 -16.2318 0.58637E-16 -16.2318 0.10000E+01 0.0000 36 CaOH+ 0.10368E-08 -8.9843 0.96168E-09 -9.0170 0.92754E+00 -0.0327 37 CaSO4,aq 0.58984E-10 -10.2293 0.58984E-10 -10.2293 0.10000E+01 0.0000 38 HCl,aq 0.16192E-13 -13.7907 0.16192E-13 -13.7907 0.10000E+01 0.0000 43 FeCl+ 0.21624E-15 -15.6651 0.20057E-15 -15.6977 0.92754E+00 -0.0327 46 FeO,aq 0.80679E-10 -10.0932 0.80679E-10 -10.0932 0.10000E+01 0.0000 47 FeOH+ 0.50326E-10 -10.2982 0.46680E-10 -10.3309 0.92754E+00 -0.0327 48 HFeO2- 0.13177E-08 -8.8802 0.12219E-08 -8.9130 0.92730E+00 -0.0328 49 FeO+ 0.56850E-14 -14.2453 0.52730E-14 -14.2779 0.92754E+00 -0.0327 51 FeO2- 0.24381E-08 -8.6130 0.22608E-08 -8.6457 0.92730E+00 -0.0328 52 HFeO2,aq 0.19864E-09 -9.7019 0.19864E-09 -9.7019 0.10000E+01 0.0000 53 H2,aq 0.44603E-09 -9.3506 0.44585E-09 -9.3508 0.99961E+00 -0.0002 54 KCl,aq 0.97731E-10 -10.0100 0.97731E-10 -10.0100 0.10000E+01 0.0000 55 KHSO4,aq 0.16408E-17 -17.7849 0.16408E-17 -17.7849 0.10000E+01 0.0000 56 KOH,aq 0.26061E-07 -7.5840 0.26061E-07 -7.5840 0.10000E+01 0.0000 57 KSO4- 0.14057E-07 -7.8521 0.13035E-07 -7.8849 0.92730E+00 -0.0328 58 MgCO3,aq 0.70263E-12 -12.1533 0.70263E-12 -12.1533 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.49721E-13 -13.3035 0.46118E-13 -13.3361 0.92754E+00 -0.0327 60 MgCl+ 0.33962E-13 -13.4690 0.31502E-13 -13.5017 0.92754E+00 -0.0327 61 MgOH+ 0.10334E-09 -9.9857 0.95853E-10 -10.0184 0.92754E+00 -0.0327 63 MnO,aq 0.28887E-09 -9.5393 0.28887E-09 -9.5393 0.10000E+01 0.0000 64 MnOH+ 0.62822E-09 -9.2019 0.58270E-09 -9.2346 0.92754E+00 -0.0327 65 MnO2-2 0.25711E-13 -13.5899 0.20088E-13 -13.6971 0.78129E+00 -0.1072 66 HMnO2- 0.32786E-11 -11.4843 0.30403E-11 -11.5171 0.92730E+00 -0.0328 69 MnCl+ 0.11305E-12 -12.9467 0.10486E-12 -12.9794 0.92754E+00 -0.0327 70 MnSO4,aq 0.76580E-12 -12.1159 0.76580E-12 -12.1159 0.10000E+01 0.0000 71 NaCl,aq 0.74440E-07 -7.1282 0.74440E-07 -7.1282 0.10000E+01 0.0000 72 NaOH,aq 0.10922E-05 -5.9617 0.10922E-05 -5.9617 0.10000E+01 0.0000 74 OH- 0.90213E-03 -3.0447 0.83635E-03 -3.0776 0.92708E+00 -0.0329 79 HPO3-2 0.11369E-16 -16.9443 0.88827E-17 -17.0515 0.78129E+00 -0.1072 81 H2PO3- 0.13270E-19 -19.8771 0.12305E-19 -19.9099 0.92730E+00 -0.0328 82 H3PO4,aq 0.21339E-13 -13.6708 0.21339E-13 -13.6708 0.10000E+01 0.0000 83 H2PO4- 0.87850E-07 -7.0563 0.81474E-07 -7.0890 0.92742E+00 -0.0327 84 PO4-3 0.12796E-07 -7.8929 0.75505E-08 -8.1220 0.59007E+00 -0.2291 87 H2P2O7-2 0.66618E-15 -15.1764 0.52048E-15 -15.2836 0.78129E+00 -0.1072 88 HP2O7-3 0.25662E-12 -12.5907 0.15044E-12 -12.8226 0.58624E+00 -0.2319 89 P2O7-4 0.13212E-12 -12.8790 0.52024E-13 -13.2838 0.39377E+00 -0.4048 90 H2S,aq 0.55108E-16 -16.2588 0.55086E-16 -16.2590 0.99961E+00 -0.0002 97 SO3-2 0.14748E-14 -14.8313 0.11545E-14 -14.9376 0.78281E+00 -0.1063 98 HSO3- 0.53852E-16 -16.2688 0.49937E-16 -16.3016 0.92730E+00 -0.0328 99 HSO4- 0.14301E-10 -10.8446 0.13266E-10 -10.8772 0.92766E+00 -0.0326 Charge balance for all species = 0.4570E-13 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.7443867E-09 -.1838701E-02 -.1852960E+01 0.0000 2 H2O 0.1000000E+01 0.5550841E+02 0.9998171E+06 0.0000 3 Cl- 0.1379367E-03 0.1380112E-03 0.4892014E+01 5.2675 4 SO4-- 0.2549719E-04 0.2551154E-04 0.2450229E+01 13.6207 5 HCO3- 0.1135368E-04 0.1307351E-04 0.7975625E+00 4.1831 6 HS- 0.2782228E-13 -.2180538E-09 -.7210152E-05 -4.4277 7 Al+++ 0.1925458E-24 0.3206616E-04 0.8650343E+00 2.5345 8 H4SiO4 0.5384944E-03 0.1344065E-02 0.1291616E+03 -3.2688 9 Ca++ 0.1193935E-07 0.1336213E-07 0.5354291E-03 10.2908 10 Mg++ 0.2151902E-09 0.3230519E-09 0.7852595E-05 8.5463 11 Fe++ 0.1269466E-11 0.4086707E-08 0.2281884E-03 6.3172 12 K+ 0.4545161E-04 0.4549182E-04 0.1778495E+01 4.7855 13 Na+ 0.1893803E-02 0.1915642E-02 0.4403214E+02 6.4052 14 Mn++ 0.1705646E-09 0.1091837E-08 0.5997232E-04 8.4455 15 HPO4-- 0.8180267E-05 0.8280913E-05 0.7946478E+00 13.1270 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.2315232E-01 -.1838207E-02 -.2131412E-01 0.0000000E+00 2 H2O 0.5549071E+02 0.5549351E+02 -.2795241E-02 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.6427553E-04 0.2550469E-04 0.3877084E-04 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.3877106E-04 -.2179953E-09 -.3877084E-04 0.0000000E+00 7 Al+++ 0.4561778E-02 0.3205755E-04 0.4529720E-02 0.0000000E+00 8 H4SiO4 0.1456748E-01 0.1343704E-02 0.1322378E-01 0.0000000E+00 9 Ca++ 0.1623521E-02 0.1335854E-07 0.1623507E-02 0.0000000E+00 10 Mg++ 0.1110317E-02 0.3229651E-09 0.1110317E-02 0.0000000E+00 11 Fe++ 0.9974990E-03 0.4085610E-08 0.9974949E-03 0.0000000E+00 12 K+ 0.2970276E-03 0.4547961E-04 0.2515480E-03 0.0000000E+00 13 Na+ 0.1916157E-02 0.1915128E-02 0.1029007E-05 0.0000000E+00 14 Mn++ 0.2425670E-04 0.1091544E-08 0.2425560E-04 0.0000000E+00 15 HPO4-- 0.8278690E-05 0.8278690E-05 0.0000000E+00 0.0000000E+00 Chg. balance for solid moles: -.4669E-17 Mass of aqueous solution: 0.999915E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 1.3990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) clinochlore 0.2221E-03 -3.654 0.1234 -0.909 8.324 0.4695E-01 daphnite 0.1375E-03 -3.862 0.9808E-01 -1.008 6.615 0.2972E-01 chlorite-Mn 0.4851E-05 -5.314 0.3439E-02 -2.464 0.2320 0.1096E-02 hematite 0.1520E-03 -3.818 0.2427E-01 -1.615 1.637 0.4600E-02 microcline 0.1009E-03 -3.996 0.2807E-01 -1.552 1.893 0.1097E-01 muscovite 0.1507E-03 -3.822 0.6002E-01 -1.222 4.048 0.2122E-01 stilbite 0.1624E-02 -2.790 1.144 0.058 77.16 0.5336 nontronite-Na 0.3118E-05 -5.506 0.1326E-02 -2.877 0.8943E-01 0.4119E-03 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity clinochlore 0.6094E+00 0.6094E+00 1.0000 -0.215 daphnite 0.3773E+00 0.3773E+00 1.0000 -0.423 chlorite-Mn 0.1331E-01 0.1331E-01 1.0000 -1.876 hematite 0.1000E+01 0.1000E+01 1.0000 0.000 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 muscovite 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 nontronite-Na 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 1.482758 g Volume = 0.648606 cm3 Porosity: 58.4120% V(tot) - V(min): 0.91099E+00 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 1.3990000 g log = 0.1458 Original solution: 1000.0103000 g Original solution / Rock added: 714.80 (Water/Rock Ratio), log = 2.8542 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0203 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.1000E+01 0.9860 0.1006E+01 0.1020E+01 CO2,gas 0.1619E-05 1.0071 0.1663E-05 0.1651E-05 CH4,gas 0.1887E-16 1.0125 0.1949E-16 0.1925E-16 H2,gas 0.5734E-06 1.0005 0.5853E-06 0.5850E-06 H2S,gas 0.1490E-14 0.9960 0.1514E-14 0.1520E-14 S2,gas 0.2462E-36 1.0000 0.2512E-36 0.2512E-36 CO,gas 0.2543E-15 1.0000 0.2594E-15 0.2594E-15 SO3,gas 0.3524E-38 1.0000 0.3596E-38 0.3596E-38 SO2,gas 0.8026E-22 1.0000 0.8188E-22 0.8188E-22 HCl,gas 0.2800E-16 1.0000 0.2857E-16 0.2857E-16 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 46 clinochlore 39.07 39.07 0.00 0.000 -0.24265E-10 47 daphnite 28.97 28.97 0.00 0.000 -0.42463E-10 48 chlorite-Mn 46.87 46.87 0.00 0.000 -0.48529E-10 90 hematite 12.57 12.57 0.00 0.000 0.90992E-11 116 microcline -2.49 -2.49 0.00 0.000 0.15165E-11 120 muscovite 2.58 2.58 0.00 0.000 -0.18198E-10 163 stilbite -7.52 -7.52 0.00 0.000 -0.90992E-11 209 nontronite-Na 3.52 3.52 0.00 0.000 -0.30331E-11 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -14.14 -7.48 -2.493 0.12769E+05 -5.779 3 CH4,gas 4.54 -13.87 -18.41 -4.602 0.31433E+05 -16.710 4 H2,gas 8.00 0.07 -7.93 -4.532 0.13543E+05 -6.233 5 H2S,gas -6.23 -22.75 -16.52 -8.259 0.28205E+05 -14.820 6 S2,gas -7.34 -45.63 -38.30 -5.892 0.65394E+05 -36.600 7 CO,gas 3.21 -14.07 -17.28 -5.318 0.29514E+05 -15.586 8 SO3,gas 17.12 -23.02 -40.14 -10.036 0.68543E+05 -38.444 9 SO2,gas 0.83 -22.95 -23.79 -6.343 0.40614E+05 -22.087 10 HCl,gas 5.19 -13.05 -18.24 -9.122 0.31149E+05 -16.544 11 acmite 7.71 6.15 -1.56 -0.162 0.26621E+04 15 albite-high 0.69 -0.87 -1.56 -0.120 0.26634E+04 16 albite -0.38 -0.87 -0.48 -0.037 0.82462E+03 19 spessartine 24.46 20.60 -3.86 -0.193 0.65880E+04 20 analcite 3.32 2.40 -0.92 -0.102 0.15706E+04 21 andalusite 5.00 1.80 -3.20 -0.320 0.54663E+04 26 annite 20.12 16.47 -3.66 -0.203 0.62465E+04 27 phlogopite 27.06 23.15 -3.91 -0.217 0.66798E+04 29 anorthite 12.71 8.82 -3.89 -0.299 0.66391E+04 32 apatite-OH -18.15 -19.09 -0.94 -0.072 0.16039E+04 35 aragonite 0.97 -3.85 -4.81 -1.605 0.82197E+04 36 brucite 12.57 8.55 -4.02 -0.804 0.68679E+04 37 calcite 0.81 -3.85 -4.66 -1.553 0.79555E+04 38 carnegieite-low 9.02 5.67 -3.35 -0.479 0.57243E+04 39 carnegieite-high 10.09 5.67 -4.42 -0.632 0.75513E+04 40 carpholite-Mg 8.58 7.08 -1.50 -0.100 0.25688E+04 41 carpholite-Fe 6.71 4.85 -1.86 -0.124 0.31830E+04 42 celadonite 5.34 2.79 -2.55 -0.150 0.43551E+04 43 celadonite-Fe 3.88 0.56 -3.31 -0.195 0.56597E+04 44 chrysotile 23.89 19.10 -4.79 -0.399 0.81806E+04 50 chloritoid-Mg 13.20 10.35 -2.85 -0.190 0.48685E+04 51 chloritoid-Fe 9.17 8.12 -1.06 -0.070 0.18036E+04 52 chloritoid-Mn 11.40 10.25 -1.16 -0.077 0.19729E+04 54 coesite -2.38 -3.27 -0.89 -0.298 0.15244E+04 59 corundum 8.38 5.07 -3.31 -0.301 0.56589E+04 61 cristobalite -2.56 -3.27 -0.71 -0.236 0.12097E+04 63 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71234E+04 65 diaspore 2.87 2.53 -0.34 -0.057 0.57923E+03 67 diopside 16.18 12.30 -3.88 -0.388 0.66283E+04 68 hedenbergite 14.21 10.07 -4.14 -0.414 0.70655E+04 75 epidote 24.67 22.13 -2.54 -0.123 0.43418E+04 76 clinozoisite 22.81 18.38 -4.43 -0.201 0.75600E+04 77 epidote-Fe 29.84 25.88 -3.97 -0.206 0.67703E+04 78 fayalite 14.05 9.37 -4.68 -0.669 0.79912E+04 83 gibbsite 4.08 2.53 -1.54 -0.221 0.26378E+04 87 greenalite 16.14 12.41 -3.73 -0.310 0.63613E+04 91 heulandite -5.83 -7.52 -1.69 -0.077 0.28938E+04 95 jadeite 4.22 2.40 -1.81 -0.181 0.30961E+04 97 kalsilite 7.58 4.05 -3.53 -0.505 0.60321E+04 98 kaolinite -1.33 -1.47 -0.14 -0.012 0.23212E+03 99 kyanite 4.88 1.80 -3.08 -0.308 0.52522E+04 101 laumontite 2.88 2.28 -0.60 -0.040 0.10228E+04 102 lawsonite 9.62 8.82 -0.79 -0.053 0.13558E+04 103 leucite 4.12 0.78 -3.34 -0.334 0.56970E+04 105 lizardite 23.24 19.10 -4.14 -0.345 0.70732E+04 107 magnetite 20.09 18.88 -1.20 -0.098 0.20558E+04 108 minnesotaite 10.39 5.88 -4.51 -0.265 0.77038E+04 113 margarite 17.32 13.89 -3.43 -0.137 0.58611E+04 121 paragonite 4.24 4.20 -0.04 -0.002 0.63726E+02 122 nepheline 8.34 5.67 -2.67 -0.381 0.45566E+04 134 phlogopite-Na 29.65 24.77 -4.87 -0.271 0.83232E+04 136 prehnite 19.37 15.84 -3.53 -0.208 0.60238E+04 137 prehnite-Fe 22.50 19.59 -2.91 -0.175 0.49606E+04 145 pyroxmangite 7.40 5.18 -2.22 -0.444 0.37940E+04 146 pyrophyllite -6.18 -8.01 -1.83 -0.114 0.31256E+04 147 quartz -2.99 -3.27 -0.28 -0.093 0.47704E+03 151 rhodochrosite -0.98 -5.69 -4.72 -1.572 0.80530E+04 152 rhodonite 7.45 5.18 -2.27 -0.454 0.38742E+04 153 sanidine -1.28 -2.49 -1.21 -0.093 0.20677E+04 156 sillimanite 5.26 1.80 -3.46 -0.346 0.59103E+04 164 stilpnomelane-Fe 13.02 12.90 -0.12 -0.004 0.20469E+03 165 stilpnomelane-Mg 27.44 24.04 -3.40 -0.101 0.58031E+04 168 sudoite 21.08 17.42 -3.65 -0.118 0.62379E+04 171 talc 16.49 12.56 -3.93 -0.231 0.67058E+04 174 tephroite 18.09 13.62 -4.46 -0.638 0.76215E+04 177 topaz-H 4.62 1.80 -2.82 -0.256 0.48123E+04 178 tridymite -2.63 -3.27 -0.64 -0.214 0.10970E+04 187 wairakite 3.95 2.28 -1.67 -0.098 0.28447E+04 188 walstromite 11.51 7.02 -4.49 -0.897 0.76619E+04 189 wollastonite 10.46 7.02 -3.44 -0.688 0.58724E+04 190 pseudo-wollastonite 11.00 7.02 -3.98 -0.796 0.67922E+04 191 zoisite 22.85 18.38 -4.47 -0.203 0.76340E+04 192 akaganeite 7.75 6.28 -1.47 -0.318 0.25125E+04 193 beidellite-Ca -1.65 -4.39 -2.75 -0.170 0.46916E+04 194 beidellite-H -2.33 -6.09 -3.77 -0.240 0.64287E+04 195 beidellite-K -1.52 -4.51 -2.99 -0.183 0.51085E+04 196 beidellite-Mg -1.79 -4.68 -2.89 -0.179 0.49369E+04 197 beidellite-Na -1.34 -3.98 -2.64 -0.161 0.44997E+04 199 chalcedony -2.80 -3.27 -0.47 -0.155 0.79634E+03 201 montmorillonite-Ca -2.29 -4.32 -2.03 -0.126 0.34726E+04 202 montmorillonite-K -2.24 -4.44 -2.21 -0.135 0.37675E+04 203 montmorillonite-Mg -2.48 -4.61 -2.13 -0.132 0.36410E+04 204 montmorillonite-Na -2.04 -3.91 -1.87 -0.115 0.31946E+04 205 nontronite-Ca 3.21 3.10 -0.11 -0.007 0.18880E+03 206 nontronite-H 2.53 1.41 -1.13 -0.076 0.19238E+04 207 nontronite-K 3.34 2.99 -0.36 -0.023 0.60700E+03 208 nontronite-Mg 3.07 2.82 -0.26 -0.017 0.44136E+03 224 tobermorite 9.82 5.30 -4.52 -1.233 0.77172E+04 233 boehmite 4.41 2.53 -1.87 -0.312 0.31962E+04 235 ferrous-oxide 9.81 6.32 -3.49 -0.874 0.59666E+04 240 silica-amorphous -2.09 -3.27 -1.18 -0.392 0.20105E+04 242 an20ab80 2.02 1.07 -0.95 -0.073 0.16167E+04 243 an25ab75 2.65 1.56 -1.09 -0.084 0.18617E+04 244 an30ab70 3.28 2.04 -1.24 -0.095 0.21163E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 0.0400000 g Current total amount of reactant added: 1.3990000 g New total amount of reactant added: 1.4390000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.4569E-13 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 6 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 1.4390000 Water: Moles liquid = 0.5549E+02 kg liquid = 0.9997E+00 Moles total = 0.5549E+02 kg total = 0.9997E+00 Activity = 1.0000 Stoichiometric ionic strength = .1296703E-02 Osmotic coef. = 0.9793 True ionic strength = .2021914E-02 Chg. balance for total moles = 0.4569E-13 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.72419E-09 -9.1401 0.67167E-09 -9.1728 0.92747E+00 -0.0327 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13794E-03 -3.8603 0.12783E-03 -3.8934 0.92671E+00 -0.0331 4 SO4-- 0.25498E-04 -4.5935 0.19876E-04 -4.7017 0.77954E+00 -0.1082 5 HCO3- 0.11309E-04 -4.9466 0.10482E-04 -4.9795 0.92689E+00 -0.0330 6 HS- 0.27616E-13 -13.5588 0.25592E-13 -13.5919 0.92673E+00 -0.0330 7 Al+++ 0.17799E-24 -24.7496 0.10374E-24 -24.9841 0.58284E+00 -0.2345 8 H4SiO4 0.53597E-03 -3.2709 0.53597E-03 -3.2709 0.10000E+01 0.0000 9 Ca++ 0.11694E-07 -7.9321 0.91066E-08 -8.0406 0.77877E+00 -0.1086 10 Mg++ 0.20452E-09 -9.6893 0.15917E-09 -9.7981 0.77828E+00 -0.1089 11 Fe++ 0.12065E-11 -11.9185 0.93914E-12 -12.0273 0.77840E+00 -0.1088 12 K+ 0.44847E-04 -4.3483 0.41570E-04 -4.3812 0.92693E+00 -0.0330 13 Na+ 0.19413E-02 -2.7119 0.17990E-02 -2.7450 0.92669E+00 -0.0331 14 Mn++ 0.16211E-09 -9.7902 0.12620E-09 -9.8990 0.77848E+00 -0.1088 15 HPO4-- 0.84164E-05 -5.0749 0.65610E-05 -5.1830 0.77955E+00 -0.1082 16 HSiO3- 0.80402E-03 -3.0947 0.74509E-03 -3.1278 0.92671E+00 -0.0331 17 Ca(HSiO3)+ 0.16670E-09 -9.7781 0.15453E-09 -9.8110 0.92695E+00 -0.0329 18 Mg(HSiO3)+ 0.36262E-11 -11.4405 0.33614E-11 -11.4735 0.92695E+00 -0.0329 19 NaHSiO3,aq 0.21680E-04 -4.6639 0.21680E-04 -4.6639 0.10000E+01 0.0000 20 AlO+ 0.33747E-13 -13.4718 0.31282E-13 -13.5047 0.92695E+00 -0.0329 21 AlOH+2 0.13438E-18 -18.8717 0.10462E-18 -18.9804 0.77859E+00 -0.1087 22 HAlO2,aq 0.92750E-08 -8.0327 0.92750E-08 -8.0327 0.10000E+01 0.0000 23 AlO2- 0.32993E-04 -4.4816 0.30567E-04 -4.5147 0.92648E+00 -0.0332 24 CH4,aq 0.13116E-19 -19.8822 0.13111E-19 -19.8824 0.99960E+00 -0.0002 29 CO,aq 0.16945E-18 -18.7710 0.16945E-18 -18.7710 0.10000E+01 0.0000 30 CO2,aq 0.15050E-07 -7.8225 0.15044E-07 -7.8226 0.99960E+00 -0.0002 31 CO3-2 0.17492E-05 -5.7572 0.13632E-05 -5.8655 0.77931E+00 -0.1083 32 CaCO3,aq 0.15565E-09 -9.8078 0.15565E-09 -9.8078 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.26287E-11 -11.5803 0.24367E-11 -11.6132 0.92695E+00 -0.0329 34 CaCl+ 0.20323E-11 -11.6920 0.18838E-11 -11.7250 0.92695E+00 -0.0329 35 CaCl2,aq 0.57209E-16 -16.2425 0.57209E-16 -16.2425 0.10000E+01 0.0000 36 CaOH+ 0.10424E-08 -8.9820 0.96628E-09 -9.0149 0.92695E+00 -0.0329 37 CaSO4,aq 0.57477E-10 -10.2405 0.57477E-10 -10.2405 0.10000E+01 0.0000 38 HCl,aq 0.15733E-13 -13.8032 0.15733E-13 -13.8032 0.10000E+01 0.0000 43 FeCl+ 0.20499E-15 -15.6883 0.19001E-15 -15.7212 0.92695E+00 -0.0329 46 FeO,aq 0.80906E-10 -10.0920 0.80906E-10 -10.0920 0.10000E+01 0.0000 47 FeOH+ 0.49100E-10 -10.3089 0.45513E-10 -10.3419 0.92695E+00 -0.0329 48 HFeO2- 0.13600E-08 -8.8665 0.12603E-08 -8.8995 0.92671E+00 -0.0331 49 FeO+ 0.55308E-14 -14.2572 0.51268E-14 -14.2902 0.92695E+00 -0.0329 51 FeO2- 0.25092E-08 -8.6005 0.23253E-08 -8.6335 0.92671E+00 -0.0331 52 HFeO2,aq 0.19864E-09 -9.7019 0.19864E-09 -9.7019 0.10000E+01 0.0000 53 H2,aq 0.44855E-09 -9.3482 0.44837E-09 -9.3484 0.99960E+00 -0.0002 54 KCl,aq 0.96307E-10 -10.0163 0.96307E-10 -10.0163 0.10000E+01 0.0000 55 KHSO4,aq 0.15691E-17 -17.8043 0.15691E-17 -17.8043 0.10000E+01 0.0000 56 KOH,aq 0.26431E-07 -7.5779 0.26431E-07 -7.5779 0.10000E+01 0.0000 57 KSO4- 0.13836E-07 -7.8590 0.12821E-07 -7.8921 0.92671E+00 -0.0331 58 MgCO3,aq 0.68195E-12 -12.1662 0.68195E-12 -12.1662 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.46949E-13 -13.3284 0.43520E-13 -13.3613 0.92695E+00 -0.0329 60 MgCl+ 0.32195E-13 -13.4922 0.29843E-13 -13.5252 0.92695E+00 -0.0329 61 MgOH+ 0.10082E-09 -9.9964 0.93458E-10 -10.0294 0.92695E+00 -0.0329 63 MnO,aq 0.28969E-09 -9.5381 0.28969E-09 -9.5381 0.10000E+01 0.0000 64 MnOH+ 0.61291E-09 -9.2126 0.56814E-09 -9.2455 0.92695E+00 -0.0329 65 MnO2-2 0.27345E-13 -13.5631 0.21310E-13 -13.6714 0.77931E+00 -0.1083 66 HMnO2- 0.33838E-11 -11.4706 0.31358E-11 -11.5036 0.92671E+00 -0.0331 69 MnCl+ 0.10716E-12 -12.9700 0.99335E-13 -13.0029 0.92695E+00 -0.0329 70 MnSO4,aq 0.72413E-12 -12.1402 0.72413E-12 -12.1402 0.10000E+01 0.0000 71 NaCl,aq 0.76209E-07 -7.1180 0.76209E-07 -7.1180 0.10000E+01 0.0000 72 NaOH,aq 0.11508E-05 -5.9390 0.11508E-05 -5.9390 0.10000E+01 0.0000 74 OH- 0.92847E-03 -3.0322 0.86020E-03 -3.0654 0.92648E+00 -0.0332 79 HPO3-2 0.11764E-16 -16.9295 0.91676E-17 -17.0377 0.77931E+00 -0.1083 81 H2PO3- 0.13324E-19 -19.8754 0.12348E-19 -19.9084 0.92671E+00 -0.0331 82 H3PO4,aq 0.20702E-13 -13.6840 0.20702E-13 -13.6840 0.10000E+01 0.0000 83 H2PO4- 0.87713E-07 -7.0569 0.81295E-07 -7.0899 0.92683E+00 -0.0330 84 PO4-3 0.13582E-07 -7.8670 0.79698E-08 -8.0986 0.58677E+00 -0.2315 87 H2P2O7-2 0.66495E-15 -15.1772 0.51820E-15 -15.2855 0.77931E+00 -0.1083 88 HP2O7-3 0.26429E-12 -12.5779 0.15405E-12 -12.8123 0.58288E+00 -0.2344 89 P2O7-4 0.14057E-12 -12.8521 0.54792E-13 -13.2613 0.38980E+00 -0.4092 90 H2S,aq 0.53148E-16 -16.2745 0.53127E-16 -16.2747 0.99960E+00 -0.0002 97 SO3-2 0.14831E-14 -14.8288 0.11581E-14 -14.9363 0.78086E+00 -0.1074 98 HSO3- 0.52556E-16 -16.2794 0.48704E-16 -16.3124 0.92671E+00 -0.0331 99 HSO4- 0.13878E-10 -10.8577 0.12866E-10 -10.8906 0.92707E+00 -0.0329 Charge balance for all species = 0.4604E-13 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.7241942E-09 -.1889017E-02 -.1903660E+01 0.0000 2 H2O 0.1000000E+01 0.5550842E+02 0.9998143E+06 0.0000 3 Cl- 0.1379359E-03 0.1380122E-03 0.4892034E+01 5.2795 4 SO4-- 0.2549759E-04 0.2551173E-04 0.2450240E+01 13.6440 5 HCO3- 0.1130920E-04 0.1307360E-04 0.7975658E+00 4.1933 6 HS- 0.2761586E-13 -.2263178E-09 -.7483388E-05 -4.4190 7 Al+++ 0.1779852E-24 0.3300204E-04 0.8902784E+00 2.5345 8 H4SiO4 0.5359696E-03 0.1361670E-02 0.1308530E+03 -3.2709 9 Ca++ 0.1169360E-07 0.1312053E-07 0.5257463E-03 10.3050 10 Mg++ 0.2045189E-09 0.3097290E-09 0.7528728E-05 8.5476 11 Fe++ 0.1206509E-11 0.4199102E-08 0.2344635E-03 6.3184 12 K+ 0.4484709E-04 0.4488746E-04 0.1754862E+01 4.7916 13 Na+ 0.1941324E-02 0.1964230E-02 0.4514884E+02 6.4279 14 Mn++ 0.1621057E-09 0.1068947E-08 0.5871485E-04 8.4467 15 HPO4-- 0.8416443E-05 0.8517740E-05 0.8173716E+00 13.1627 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.2381466E-01 -.1888496E-02 -.2192617E-01 0.0000000E+00 2 H2O 0.5549021E+02 0.5549313E+02 -.2914842E-02 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.6538407E-04 0.2550470E-04 0.3987937E-04 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.3987960E-04 -.2262555E-09 -.3987937E-04 0.0000000E+00 7 Al+++ 0.4692207E-02 0.3299295E-04 0.4659214E-02 0.0000000E+00 8 H4SiO4 0.1498399E-01 0.1361295E-02 0.1362270E-01 0.0000000E+00 9 Ca++ 0.1669526E-02 0.1311691E-07 0.1669513E-02 0.0000000E+00 10 Mg++ 0.1142063E-02 0.3096437E-09 0.1142063E-02 0.0000000E+00 11 Fe++ 0.1026019E-02 0.4197945E-08 0.1026015E-02 0.0000000E+00 12 K+ 0.3055202E-03 0.4487509E-04 0.2606451E-03 0.0000000E+00 13 Na+ 0.1966367E-02 0.1963689E-02 0.2677465E-05 0.0000000E+00 14 Mn++ 0.2495024E-04 0.1068652E-08 0.2494917E-04 0.0000000E+00 15 HPO4-- 0.8515393E-05 0.8515393E-05 0.0000000E+00 0.0000000E+00 Chg. balance for solid moles: -.1098E-17 Mass of aqueous solution: 0.999911E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 1.4390000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) clinochlore 0.2284E-03 -3.641 0.1270 -0.896 8.317 0.4829E-01 daphnite 0.1414E-03 -3.850 0.1009 -0.996 6.609 0.3057E-01 chlorite-Mn 0.4990E-05 -5.302 0.3538E-02 -2.451 0.2317 0.1127E-02 hematite 0.1514E-03 -3.820 0.2418E-01 -1.617 1.584 0.4583E-02 microcline 0.1070E-03 -3.971 0.2979E-01 -1.526 1.951 0.1163E-01 muscovite 0.1536E-03 -3.814 0.6119E-01 -1.213 4.009 0.2164E-01 stilbite 0.1670E-02 -2.777 1.177 0.071 77.07 0.5488 nontronite-Na 0.8114E-05 -5.091 0.3450E-02 -2.462 0.2260 0.1072E-02 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity clinochlore 0.6094E+00 0.6094E+00 1.0000 -0.215 daphnite 0.3773E+00 0.3773E+00 1.0000 -0.423 chlorite-Mn 0.1331E-01 0.1331E-01 1.0000 -1.876 hematite 0.1000E+01 0.1000E+01 1.0000 0.000 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 muscovite 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 nontronite-Na 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 1.526532 g Volume = 0.667678 cm3 Porosity: 57.6239% V(tot) - V(min): 0.90792E+00 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 1.4390000 g log = 0.1581 Original solution: 1000.0103000 g Original solution / Rock added: 694.93 (Water/Rock Ratio), log = 2.8419 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0203 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.1000E+01 0.9860 0.1006E+01 0.1020E+01 CO2,gas 0.1566E-05 1.0071 0.1610E-05 0.1598E-05 CH4,gas 0.1868E-16 1.0125 0.1930E-16 0.1906E-16 H2,gas 0.5766E-06 1.0005 0.5887E-06 0.5883E-06 H2S,gas 0.1437E-14 0.9960 0.1460E-14 0.1466E-14 S2,gas 0.2264E-36 1.0000 0.2310E-36 0.2310E-36 CO,gas 0.2475E-15 1.0000 0.2525E-15 0.2525E-15 SO3,gas 0.3323E-38 1.0000 0.3390E-38 0.3390E-38 SO2,gas 0.7610E-22 1.0000 0.7765E-22 0.7765E-22 HCl,gas 0.2721E-16 1.0000 0.2776E-16 0.2776E-16 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 46 clinochlore 39.07 39.07 0.00 0.000 0.36397E-10 47 daphnite 28.97 28.97 0.00 0.000 0.30331E-10 48 chlorite-Mn 46.87 46.87 0.00 0.000 0.48529E-10 90 hematite 12.57 12.57 0.00 0.000 0.30331E-11 116 microcline -2.49 -2.49 0.00 0.000 0.15165E-11 120 muscovite 2.58 2.58 0.00 0.000 0.60662E-11 163 stilbite -7.52 -7.52 0.00 0.000 0.15165E-10 209 nontronite-Na 3.52 3.52 0.00 0.000 -0.10616E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -14.15 -7.49 -2.497 0.12793E+05 -5.793 3 CH4,gas 4.54 -13.87 -18.41 -4.603 0.31440E+05 -16.714 4 H2,gas 8.00 0.07 -7.93 -4.531 0.13539E+05 -6.230 5 H2S,gas -6.23 -22.76 -16.53 -8.267 0.28232E+05 -14.836 6 S2,gas -7.34 -45.67 -38.34 -5.898 0.65456E+05 -36.636 7 CO,gas 3.21 -14.08 -17.30 -5.322 0.29534E+05 -15.598 8 SO3,gas 17.12 -23.05 -40.17 -10.042 0.68587E+05 -38.470 9 SO2,gas 0.83 -22.98 -23.81 -6.349 0.40653E+05 -22.110 10 HCl,gas 5.19 -13.07 -18.26 -9.128 0.31171E+05 -16.557 11 acmite 7.71 6.17 -1.54 -0.160 0.26303E+04 15 albite-high 0.69 -0.85 -1.54 -0.119 0.26351E+04 16 albite -0.38 -0.85 -0.47 -0.036 0.79632E+03 19 spessartine 24.46 20.60 -3.86 -0.193 0.65922E+04 20 analcite 3.32 2.42 -0.90 -0.100 0.15388E+04 21 andalusite 5.00 1.80 -3.20 -0.320 0.54698E+04 26 annite 20.12 16.47 -3.65 -0.203 0.62402E+04 27 phlogopite 27.06 23.16 -3.91 -0.217 0.66735E+04 29 anorthite 12.71 8.83 -3.88 -0.298 0.66217E+04 32 apatite-OH -18.15 -19.06 -0.91 -0.070 0.15494E+04 35 aragonite 0.97 -3.85 -4.81 -1.605 0.82195E+04 36 brucite 12.57 8.55 -4.02 -0.804 0.68658E+04 37 calcite 0.81 -3.85 -4.66 -1.553 0.79553E+04 38 carnegieite-low 9.02 5.69 -3.33 -0.476 0.56890E+04 39 carnegieite-high 10.09 5.69 -4.40 -0.629 0.75160E+04 40 carpholite-Mg 8.58 7.07 -1.51 -0.100 0.25737E+04 41 carpholite-Fe 6.71 4.85 -1.87 -0.124 0.31879E+04 42 celadonite 5.34 2.79 -2.55 -0.150 0.43564E+04 43 celadonite-Fe 3.88 0.56 -3.32 -0.195 0.56611E+04 44 chrysotile 23.89 19.10 -4.79 -0.399 0.81813E+04 50 chloritoid-Mg 13.20 10.35 -2.85 -0.190 0.48698E+04 51 chloritoid-Fe 9.17 8.12 -1.06 -0.070 0.18050E+04 52 chloritoid-Mn 11.40 10.24 -1.16 -0.077 0.19743E+04 54 coesite -2.38 -3.27 -0.89 -0.298 0.15278E+04 59 corundum 8.38 5.07 -3.31 -0.301 0.56589E+04 61 cristobalite -2.56 -3.27 -0.71 -0.237 0.12132E+04 63 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71234E+04 65 diaspore 2.87 2.53 -0.34 -0.057 0.57923E+03 67 diopside 16.18 12.31 -3.87 -0.387 0.66087E+04 68 hedenbergite 14.21 10.08 -4.13 -0.413 0.70460E+04 75 epidote 24.67 22.15 -2.52 -0.122 0.43035E+04 76 clinozoisite 22.81 18.40 -4.41 -0.200 0.75217E+04 77 epidote-Fe 29.84 25.90 -3.94 -0.205 0.67320E+04 78 fayalite 14.05 9.37 -4.68 -0.669 0.79906E+04 83 gibbsite 4.08 2.53 -1.54 -0.221 0.26378E+04 87 greenalite 16.14 12.41 -3.73 -0.310 0.63620E+04 91 heulandite -5.83 -7.52 -1.69 -0.077 0.28938E+04 95 jadeite 4.22 2.42 -1.79 -0.179 0.30643E+04 97 kalsilite 7.58 4.06 -3.53 -0.504 0.60251E+04 98 kaolinite -1.33 -1.47 -0.14 -0.013 0.23909E+03 99 kyanite 4.88 1.80 -3.08 -0.308 0.52557E+04 101 laumontite 2.88 2.29 -0.59 -0.040 0.10123E+04 102 lawsonite 9.62 8.83 -0.78 -0.052 0.13384E+04 103 leucite 4.12 0.78 -3.33 -0.333 0.56936E+04 105 lizardite 23.24 19.10 -4.14 -0.345 0.70739E+04 107 magnetite 20.09 18.88 -1.20 -0.098 0.20537E+04 108 minnesotaite 10.39 5.87 -4.52 -0.266 0.77114E+04 113 margarite 17.32 13.90 -3.42 -0.137 0.58437E+04 121 paragonite 4.24 4.22 -0.02 -0.001 0.35423E+02 122 nepheline 8.34 5.69 -2.65 -0.378 0.45213E+04 134 phlogopite-Na 29.65 24.79 -4.85 -0.270 0.82887E+04 136 prehnite 19.37 15.87 -3.51 -0.206 0.59855E+04 137 prehnite-Fe 22.50 19.62 -2.88 -0.173 0.49223E+04 145 pyroxmangite 7.40 5.18 -2.22 -0.445 0.37954E+04 146 pyrophyllite -6.18 -8.01 -1.84 -0.115 0.31396E+04 147 quartz -2.99 -3.27 -0.28 -0.094 0.48053E+03 151 rhodochrosite -0.98 -5.71 -4.73 -1.576 0.80752E+04 152 rhodonite 7.45 5.18 -2.27 -0.454 0.38756E+04 153 sanidine -1.28 -2.49 -1.21 -0.093 0.20677E+04 156 sillimanite 5.26 1.80 -3.46 -0.346 0.59138E+04 164 stilpnomelane-Fe 13.02 12.89 -0.13 -0.004 0.21688E+03 165 stilpnomelane-Mg 27.44 24.04 -3.41 -0.102 0.58153E+04 168 sudoite 21.08 17.42 -3.66 -0.118 0.62442E+04 171 talc 16.49 12.56 -3.93 -0.231 0.67135E+04 174 tephroite 18.09 13.62 -4.46 -0.638 0.76208E+04 177 topaz-H 4.62 1.80 -2.82 -0.256 0.48158E+04 178 tridymite -2.63 -3.27 -0.64 -0.215 0.11005E+04 187 wairakite 3.95 2.29 -1.66 -0.098 0.28343E+04 188 walstromite 11.51 7.03 -4.48 -0.895 0.76410E+04 189 wollastonite 10.46 7.03 -3.43 -0.685 0.58514E+04 190 pseudo-wollastonite 11.00 7.03 -3.97 -0.793 0.67713E+04 191 zoisite 22.85 18.40 -4.45 -0.202 0.75957E+04 192 akaganeite 7.75 6.28 -1.47 -0.318 0.25125E+04 193 beidellite-Ca -1.65 -4.40 -2.75 -0.170 0.47004E+04 194 beidellite-H -2.33 -6.10 -3.77 -0.241 0.64415E+04 195 beidellite-K -1.52 -4.52 -3.00 -0.184 0.51178E+04 196 beidellite-Mg -1.79 -4.69 -2.90 -0.179 0.49493E+04 197 beidellite-Na -1.34 -3.98 -2.64 -0.161 0.44997E+04 199 chalcedony -2.80 -3.27 -0.47 -0.156 0.79982E+03 201 montmorillonite-Ca -2.29 -4.33 -2.04 -0.126 0.34818E+04 202 montmorillonite-K -2.24 -4.45 -2.21 -0.135 0.37773E+04 203 montmorillonite-Mg -2.48 -4.62 -2.14 -0.132 0.36539E+04 204 montmorillonite-Na -2.04 -3.91 -1.87 -0.115 0.31950E+04 205 nontronite-Ca 3.21 3.10 -0.12 -0.008 0.19757E+03 206 nontronite-H 2.53 1.40 -1.13 -0.076 0.19366E+04 207 nontronite-K 3.34 2.98 -0.36 -0.023 0.61634E+03 208 nontronite-Mg 3.07 2.81 -0.27 -0.017 0.45380E+03 224 tobermorite 9.82 5.31 -4.51 -1.231 0.77004E+04 233 boehmite 4.41 2.53 -1.87 -0.312 0.31962E+04 235 ferrous-oxide 9.81 6.32 -3.49 -0.873 0.59645E+04 240 silica-amorphous -2.09 -3.27 -1.18 -0.393 0.20140E+04 242 an20ab80 2.02 1.09 -0.93 -0.072 0.15905E+04 243 an25ab75 2.65 1.57 -1.08 -0.083 0.18361E+04 244 an30ab70 3.28 2.05 -1.22 -0.094 0.20912E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 0.0400000 g Current total amount of reactant added: 1.4390000 g New total amount of reactant added: 1.4790000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.4569E-13 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 6 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 1.4790000 Water: Moles liquid = 0.5549E+02 kg liquid = 0.9997E+00 Moles total = 0.5549E+02 kg total = 0.9997E+00 Activity = 1.0000 Stoichiometric ionic strength = .1325400E-02 Osmotic coef. = 0.9791 True ionic strength = .2069113E-02 Chg. balance for total moles = 0.4569E-13 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.70507E-09 -9.1518 0.65353E-09 -9.1847 0.92690E+00 -0.0330 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13794E-03 -3.8603 0.12774E-03 -3.8937 0.92612E+00 -0.0333 4 SO4-- 0.25498E-04 -4.5935 0.19827E-04 -4.7027 0.77759E+00 -0.1093 5 HCO3- 0.11265E-04 -4.9483 0.10435E-04 -4.9815 0.92631E+00 -0.0332 6 HS- 0.27416E-13 -13.5620 0.25391E-13 -13.5953 0.92614E+00 -0.0333 7 Al+++ 0.16488E-24 -24.7828 0.95555E-25 -25.0197 0.57954E+00 -0.2369 8 H4SiO4 0.53352E-03 -3.2728 0.53352E-03 -3.2728 0.10000E+01 0.0000 9 Ca++ 0.11460E-07 -7.9408 0.89020E-08 -8.0505 0.77680E+00 -0.1097 10 Mg++ 0.19465E-09 -9.7108 0.15110E-09 -9.8207 0.77631E+00 -0.1100 11 Fe++ 0.11483E-11 -11.9400 0.89154E-12 -12.0499 0.77642E+00 -0.1099 12 K+ 0.44267E-04 -4.3539 0.41006E-04 -4.3871 0.92634E+00 -0.0332 13 Na+ 0.19888E-02 -2.7014 0.18419E-02 -2.7347 0.92610E+00 -0.0333 14 Mn++ 0.15428E-09 -9.8117 0.11980E-09 -9.9215 0.77651E+00 -0.1099 15 HPO4-- 0.86526E-05 -5.0629 0.67283E-05 -5.1721 0.77760E+00 -0.1092 16 HSiO3- 0.82309E-03 -3.0846 0.76228E-03 -3.1179 0.92612E+00 -0.0333 17 Ca(HSiO3)+ 0.16682E-09 -9.7777 0.15454E-09 -9.8110 0.92637E+00 -0.0332 18 Mg(HSiO3)+ 0.35241E-11 -11.4530 0.32646E-11 -11.4862 0.92637E+00 -0.0332 19 NaHSiO3,aq 0.22708E-04 -4.6438 0.22708E-04 -4.6438 0.10000E+01 0.0000 20 AlO+ 0.32856E-13 -13.4834 0.30437E-13 -13.5166 0.92637E+00 -0.0332 21 AlOH+2 0.12754E-18 -18.8944 0.99047E-19 -19.0042 0.77662E+00 -0.1098 22 HAlO2,aq 0.92750E-08 -8.0327 0.92750E-08 -8.0327 0.10000E+01 0.0000 23 AlO2- 0.33930E-04 -4.4694 0.31416E-04 -4.5029 0.92588E+00 -0.0334 24 CH4,aq 0.12986E-19 -19.8865 0.12981E-19 -19.8867 0.99959E+00 -0.0002 29 CO,aq 0.16503E-18 -18.7824 0.16503E-18 -18.7824 0.10000E+01 0.0000 30 CO2,aq 0.14577E-07 -7.8363 0.14571E-07 -7.8365 0.99959E+00 -0.0002 31 CO3-2 0.17941E-05 -5.7462 0.13946E-05 -5.8555 0.77735E+00 -0.1094 32 CaCO3,aq 0.15567E-09 -9.8078 0.15567E-09 -9.8078 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.25596E-11 -11.5918 0.23711E-11 -11.6250 0.92637E+00 -0.0332 34 CaCl+ 0.19866E-11 -11.7019 0.18403E-11 -11.7351 0.92637E+00 -0.0332 35 CaCl2,aq 0.55852E-16 -16.2530 0.55852E-16 -16.2530 0.10000E+01 0.0000 36 CaOH+ 0.10480E-08 -8.9797 0.97080E-09 -9.0129 0.92637E+00 -0.0332 37 CaSO4,aq 0.56047E-10 -10.2514 0.56047E-10 -10.2514 0.10000E+01 0.0000 38 HCl,aq 0.15298E-13 -13.8154 0.15298E-13 -13.8154 0.10000E+01 0.0000 43 FeCl+ 0.19459E-15 -15.7109 0.18027E-15 -15.7441 0.92637E+00 -0.0332 46 FeO,aq 0.81129E-10 -10.0908 0.81129E-10 -10.0908 0.10000E+01 0.0000 47 FeOH+ 0.47935E-10 -10.3193 0.44406E-10 -10.3526 0.92637E+00 -0.0332 48 HFeO2- 0.14025E-08 -8.8531 0.12989E-08 -8.8864 0.92612E+00 -0.0333 49 FeO+ 0.53848E-14 -14.2688 0.49883E-14 -14.3020 0.92637E+00 -0.0332 51 FeO2- 0.25805E-08 -8.5883 0.23899E-08 -8.6216 0.92612E+00 -0.0333 52 HFeO2,aq 0.19864E-09 -9.7019 0.19864E-09 -9.7019 0.10000E+01 0.0000 53 H2,aq 0.45103E-09 -9.3458 0.45084E-09 -9.3460 0.99959E+00 -0.0002 54 KCl,aq 0.94941E-10 -10.0225 0.94941E-10 -10.0225 0.10000E+01 0.0000 55 KHSO4,aq 0.15023E-17 -17.8232 0.15023E-17 -17.8232 0.10000E+01 0.0000 56 KOH,aq 0.26796E-07 -7.5719 0.26796E-07 -7.5719 0.10000E+01 0.0000 57 KSO4- 0.13623E-07 -7.8657 0.12616E-07 -7.8991 0.92612E+00 -0.0333 58 MgCO3,aq 0.66233E-12 -12.1789 0.66233E-12 -12.1789 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.44395E-13 -13.3527 0.41126E-13 -13.3859 0.92637E+00 -0.0332 60 MgCl+ 0.30563E-13 -13.5148 0.28312E-13 -13.5480 0.92637E+00 -0.0332 61 MgOH+ 0.98431E-10 -10.0069 0.91184E-10 -10.0401 0.92637E+00 -0.0332 63 MnO,aq 0.29048E-09 -9.5369 0.29048E-09 -9.5369 0.10000E+01 0.0000 64 MnOH+ 0.59838E-09 -9.2230 0.55432E-09 -9.2562 0.92637E+00 -0.0332 65 MnO2-2 0.29037E-13 -13.5371 0.22572E-13 -13.6464 0.77735E+00 -0.1094 66 HMnO2- 0.34896E-11 -11.4572 0.32318E-11 -11.4906 0.92612E+00 -0.0333 69 MnCl+ 0.10173E-12 -12.9926 0.94239E-13 -13.0258 0.92637E+00 -0.0332 70 MnSO4,aq 0.68572E-12 -12.1639 0.68572E-12 -12.1639 0.10000E+01 0.0000 71 NaCl,aq 0.77974E-07 -7.1080 0.77974E-07 -7.1080 0.10000E+01 0.0000 72 NaOH,aq 0.12109E-05 -5.9169 0.12109E-05 -5.9169 0.10000E+01 0.0000 74 OH- 0.95485E-03 -3.0201 0.88408E-03 -3.0535 0.92588E+00 -0.0334 79 HPO3-2 0.12161E-16 -16.9150 0.94531E-17 -17.0244 0.77735E+00 -0.1094 81 H2PO3- 0.13377E-19 -19.8737 0.12388E-19 -19.9070 0.92612E+00 -0.0333 82 H3PO4,aq 0.20098E-13 -13.6968 0.20098E-13 -13.6968 0.10000E+01 0.0000 83 H2PO4- 0.87574E-07 -7.0576 0.81115E-07 -7.0909 0.92624E+00 -0.0333 84 PO4-3 0.14395E-07 -7.8418 0.83999E-08 -8.0757 0.58354E+00 -0.2339 87 H2P2O7-2 0.66367E-15 -15.1780 0.51591E-15 -15.2874 0.77735E+00 -0.1094 88 HP2O7-3 0.27197E-12 -12.5655 0.15763E-12 -12.8024 0.57958E+00 -0.2369 89 P2O7-4 0.14931E-12 -12.8259 0.57621E-13 -13.2394 0.38592E+00 -0.4135 90 H2S,aq 0.51306E-16 -16.2898 0.51285E-16 -16.2900 0.99959E+00 -0.0002 97 SO3-2 0.14913E-14 -14.8264 0.11616E-14 -14.9349 0.77893E+00 -0.1085 98 HSO3- 0.51323E-16 -16.2897 0.47531E-16 -16.3230 0.92612E+00 -0.0333 99 HSO4- 0.13478E-10 -10.8704 0.12487E-10 -10.9035 0.92649E+00 -0.0332 Charge balance for all species = 0.4602E-13 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.7050671E-09 -.1939361E-02 -.1954389E+01 0.0000 2 H2O 0.1000000E+01 0.5550843E+02 0.9998115E+06 0.0000 3 Cl- 0.1379351E-03 0.1380132E-03 0.4892054E+01 5.2911 4 SO4-- 0.2549799E-04 0.2551191E-04 0.2450251E+01 13.6667 5 HCO3- 0.1126488E-04 0.1307369E-04 0.7975690E+00 4.2032 6 HS- 0.2741609E-13 -.2346119E-09 -.7757614E-05 -4.4106 7 Al+++ 0.1648804E-24 0.3393974E-04 0.9155715E+00 2.5345 8 H4SiO4 0.5335212E-03 0.1379319E-02 0.1325487E+03 -3.2728 9 Ca++ 0.1145985E-07 0.1289089E-07 0.5165433E-03 10.3190 10 Mg++ 0.1946451E-09 0.2973376E-09 0.7227502E-05 8.5487 11 Fe++ 0.1148257E-11 0.4311896E-08 0.2407608E-03 6.3196 12 K+ 0.4426706E-04 0.4430757E-04 0.1732187E+01 4.7976 13 Na+ 0.1988820E-02 0.2012816E-02 0.4626548E+02 6.4500 14 Mn++ 0.1542789E-09 0.1047443E-08 0.5753353E-04 8.4479 15 HPO4-- 0.8652600E-05 0.8754569E-05 0.8400956E+00 13.1974 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.2447700E-01 -.1938813E-02 -.2253819E-01 0.0000000E+00 2 H2O 0.5548971E+02 0.5549274E+02 -.3034351E-02 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.6649260E-04 0.2550470E-04 0.4098790E-04 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.4098813E-04 -.2345456E-09 -.4098790E-04 0.0000000E+00 7 Al+++ 0.4822637E-02 0.3393015E-04 0.4788707E-02 0.0000000E+00 8 H4SiO4 0.1540051E-01 0.1378930E-02 0.1402158E-01 0.0000000E+00 9 Ca++ 0.1715532E-02 0.1288725E-07 0.1715519E-02 0.0000000E+00 10 Mg++ 0.1173810E-02 0.2972536E-09 0.1173809E-02 0.0000000E+00 11 Fe++ 0.1054540E-02 0.4310678E-08 0.1054535E-02 0.0000000E+00 12 K+ 0.3140127E-03 0.4429506E-04 0.2697177E-03 0.0000000E+00 13 Na+ 0.2016576E-02 0.2012248E-02 0.4328547E-05 0.0000000E+00 14 Mn++ 0.2564378E-04 0.1047147E-08 0.2564274E-04 0.0000000E+00 15 HPO4-- 0.8752096E-05 0.8752096E-05 0.0000000E+00 0.0000000E+00 Chg. balance for solid moles: 0.2900E-17 Mass of aqueous solution: 0.999907E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 1.4790000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) clinochlore 0.2348E-03 -3.629 0.1305 -0.884 8.310 0.4963E-01 daphnite 0.1453E-03 -3.838 0.1037 -0.984 6.603 0.3142E-01 chlorite-Mn 0.5129E-05 -5.290 0.3636E-02 -2.439 0.2315 0.1159E-02 hematite 0.1508E-03 -3.821 0.2409E-01 -1.618 1.534 0.4566E-02 microcline 0.1131E-03 -3.946 0.3149E-01 -1.502 2.005 0.1230E-01 muscovite 0.1566E-03 -3.805 0.6237E-01 -1.205 3.972 0.2206E-01 stilbite 0.1716E-02 -2.766 1.209 0.082 76.99 0.5639 nontronite-Na 0.1312E-04 -4.882 0.5578E-02 -2.254 0.3552 0.1733E-02 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity clinochlore 0.6094E+00 0.6094E+00 1.0000 -0.215 daphnite 0.3773E+00 0.3773E+00 1.0000 -0.423 chlorite-Mn 0.1331E-01 0.1331E-01 1.0000 -1.876 hematite 0.1000E+01 0.1000E+01 1.0000 0.000 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 muscovite 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 nontronite-Na 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 1.570302 g Volume = 0.686749 cm3 Porosity: 56.8517% V(tot) - V(min): 0.90485E+00 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 1.4790000 g log = 0.1700 Original solution: 1000.0103000 g Original solution / Rock added: 676.14 (Water/Rock Ratio), log = 2.8300 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0203 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.1000E+01 0.9860 0.1006E+01 0.1020E+01 CO2,gas 0.1517E-05 1.0071 0.1559E-05 0.1548E-05 CH4,gas 0.1849E-16 1.0125 0.1911E-16 0.1887E-16 H2,gas 0.5798E-06 1.0005 0.5919E-06 0.5916E-06 H2S,gas 0.1387E-14 0.9960 0.1410E-14 0.1415E-14 S2,gas 0.2087E-36 1.0000 0.2129E-36 0.2129E-36 CO,gas 0.2410E-15 1.0000 0.2459E-15 0.2459E-15 SO3,gas 0.3138E-38 1.0000 0.3202E-38 0.3202E-38 SO2,gas 0.7226E-22 1.0000 0.7373E-22 0.7373E-22 HCl,gas 0.2646E-16 1.0000 0.2699E-16 0.2699E-16 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 46 clinochlore 39.07 39.07 0.00 0.000 0.36397E-10 47 daphnite 28.97 28.97 0.00 0.000 0.36397E-10 48 chlorite-Mn 46.87 46.87 0.00 0.000 0.24265E-10 90 hematite 12.57 12.57 0.00 0.000 0.90992E-11 116 microcline -2.49 -2.49 0.00 0.000 0.15165E-11 120 muscovite 2.58 2.58 0.00 0.000 0.30331E-10 163 stilbite -7.52 -7.52 0.00 0.000 0.15165E-10 209 nontronite-Na 3.52 3.52 0.00 0.000 -0.60662E-11 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -14.17 -7.51 -2.502 0.12817E+05 -5.807 3 CH4,gas 4.54 -13.87 -18.42 -4.604 0.31448E+05 -16.719 4 H2,gas 8.00 0.07 -7.93 -4.530 0.13535E+05 -6.228 5 H2S,gas -6.23 -22.78 -16.55 -8.275 0.28258E+05 -14.851 6 S2,gas -7.34 -45.71 -38.37 -5.903 0.65517E+05 -36.672 7 CO,gas 3.21 -14.09 -17.31 -5.326 0.29553E+05 -15.609 8 SO3,gas 17.12 -23.07 -40.19 -10.048 0.68629E+05 -38.495 9 SO2,gas 0.83 -23.00 -23.83 -6.355 0.40691E+05 -22.132 10 HCl,gas 5.19 -13.08 -18.27 -9.134 0.31192E+05 -16.569 11 acmite 7.71 6.19 -1.52 -0.158 0.25993E+04 15 albite-high 0.69 -0.83 -1.53 -0.117 0.26076E+04 16 albite -0.38 -0.83 -0.45 -0.035 0.76875E+03 19 spessartine 24.46 20.59 -3.86 -0.193 0.65963E+04 20 analcite 3.32 2.44 -0.88 -0.098 0.15079E+04 21 andalusite 5.00 1.80 -3.21 -0.321 0.54732E+04 26 annite 20.12 16.47 -3.65 -0.203 0.62341E+04 27 phlogopite 27.06 23.16 -3.90 -0.217 0.66674E+04 29 anorthite 12.71 8.84 -3.87 -0.298 0.66047E+04 32 apatite-OH -18.15 -19.03 -0.88 -0.067 0.14964E+04 35 aragonite 0.97 -3.85 -4.81 -1.605 0.82195E+04 36 brucite 12.57 8.55 -4.02 -0.804 0.68637E+04 37 calcite 0.81 -3.85 -4.66 -1.553 0.79552E+04 38 carnegieite-low 9.02 5.71 -3.31 -0.473 0.56546E+04 39 carnegieite-high 10.09 5.71 -4.38 -0.626 0.74816E+04 40 carpholite-Mg 8.58 7.07 -1.51 -0.101 0.25785E+04 41 carpholite-Fe 6.71 4.84 -1.87 -0.125 0.31926E+04 42 celadonite 5.34 2.79 -2.55 -0.150 0.43578E+04 43 celadonite-Fe 3.88 0.56 -3.32 -0.195 0.56624E+04 44 chrysotile 23.89 19.10 -4.79 -0.399 0.81819E+04 50 chloritoid-Mg 13.20 10.34 -2.85 -0.190 0.48712E+04 51 chloritoid-Fe 9.17 8.12 -1.06 -0.071 0.18064E+04 52 chloritoid-Mn 11.40 10.24 -1.16 -0.077 0.19757E+04 54 coesite -2.38 -3.27 -0.90 -0.299 0.15312E+04 59 corundum 8.38 5.07 -3.31 -0.301 0.56589E+04 61 cristobalite -2.56 -3.27 -0.71 -0.238 0.12166E+04 63 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71234E+04 65 diaspore 2.87 2.53 -0.34 -0.057 0.57923E+03 67 diopside 16.18 12.32 -3.86 -0.386 0.65897E+04 68 hedenbergite 14.21 10.09 -4.12 -0.412 0.70269E+04 75 epidote 24.67 22.17 -2.50 -0.121 0.42662E+04 76 clinozoisite 22.81 18.42 -4.38 -0.199 0.74843E+04 77 epidote-Fe 29.84 25.92 -3.92 -0.204 0.66946E+04 78 fayalite 14.05 9.37 -4.68 -0.668 0.79899E+04 83 gibbsite 4.08 2.53 -1.54 -0.221 0.26378E+04 87 greenalite 16.14 12.41 -3.73 -0.311 0.63627E+04 91 heulandite -5.83 -7.52 -1.69 -0.077 0.28938E+04 95 jadeite 4.22 2.44 -1.78 -0.178 0.30334E+04 97 kalsilite 7.58 4.06 -3.52 -0.504 0.60183E+04 98 kaolinite -1.33 -1.48 -0.14 -0.013 0.24588E+03 99 kyanite 4.88 1.80 -3.08 -0.308 0.52591E+04 101 laumontite 2.88 2.30 -0.59 -0.039 0.10021E+04 102 lawsonite 9.62 8.84 -0.77 -0.052 0.13214E+04 103 leucite 4.12 0.79 -3.33 -0.333 0.56902E+04 105 lizardite 23.24 19.10 -4.14 -0.345 0.70746E+04 107 magnetite 20.09 18.89 -1.20 -0.098 0.20517E+04 108 minnesotaite 10.39 5.87 -4.52 -0.266 0.77189E+04 113 margarite 17.32 13.91 -3.41 -0.136 0.58267E+04 121 paragonite 4.24 4.23 0.00 0.000 0.78497E+01 122 nepheline 8.34 5.71 -2.63 -0.375 0.44870E+04 134 phlogopite-Na 29.65 24.81 -4.83 -0.269 0.82550E+04 136 prehnite 19.37 15.89 -3.48 -0.205 0.59481E+04 137 prehnite-Fe 22.50 19.64 -2.86 -0.172 0.48850E+04 145 pyroxmangite 7.40 5.18 -2.22 -0.445 0.37967E+04 146 pyrophyllite -6.18 -8.02 -1.85 -0.115 0.31531E+04 147 quartz -2.99 -3.27 -0.28 -0.094 0.48392E+03 151 rhodochrosite -0.98 -5.72 -4.74 -1.581 0.80968E+04 152 rhodonite 7.45 5.18 -2.27 -0.454 0.38770E+04 153 sanidine -1.28 -2.49 -1.21 -0.093 0.20677E+04 156 sillimanite 5.26 1.80 -3.47 -0.347 0.59172E+04 164 stilpnomelane-Fe 13.02 12.88 -0.13 -0.004 0.22877E+03 165 stilpnomelane-Mg 27.44 24.03 -3.41 -0.102 0.58271E+04 168 sudoite 21.08 17.42 -3.66 -0.118 0.62503E+04 171 talc 16.49 12.55 -3.94 -0.232 0.67210E+04 174 tephroite 18.09 13.62 -4.46 -0.638 0.76201E+04 177 topaz-H 4.62 1.80 -2.82 -0.257 0.48192E+04 178 tridymite -2.63 -3.27 -0.65 -0.216 0.11039E+04 187 wairakite 3.95 2.30 -1.65 -0.097 0.28241E+04 188 walstromite 11.51 7.05 -4.46 -0.893 0.76206E+04 189 wollastonite 10.46 7.05 -3.42 -0.683 0.58311E+04 190 pseudo-wollastonite 11.00 7.05 -3.95 -0.791 0.67509E+04 191 zoisite 22.85 18.42 -4.43 -0.201 0.75584E+04 192 akaganeite 7.75 6.28 -1.47 -0.318 0.25125E+04 193 beidellite-Ca -1.65 -4.40 -2.76 -0.171 0.47089E+04 194 beidellite-H -2.33 -6.11 -3.78 -0.241 0.64539E+04 195 beidellite-K -1.52 -4.52 -3.00 -0.184 0.51269E+04 196 beidellite-Mg -1.79 -4.70 -2.91 -0.180 0.49615E+04 197 beidellite-Na -1.34 -3.98 -2.64 -0.161 0.44997E+04 199 chalcedony -2.80 -3.27 -0.47 -0.157 0.80322E+03 201 montmorillonite-Ca -2.29 -4.34 -2.04 -0.126 0.34908E+04 202 montmorillonite-K -2.24 -4.45 -2.22 -0.136 0.37869E+04 203 montmorillonite-Mg -2.48 -4.63 -2.15 -0.133 0.36665E+04 204 montmorillonite-Na -2.04 -3.91 -1.87 -0.115 0.31955E+04 205 nontronite-Ca 3.21 3.09 -0.12 -0.008 0.20611E+03 206 nontronite-H 2.53 1.39 -1.14 -0.077 0.19491E+04 207 nontronite-K 3.34 2.97 -0.37 -0.024 0.62544E+03 208 nontronite-Mg 3.07 2.80 -0.27 -0.018 0.46592E+03 224 tobermorite 9.82 5.32 -4.50 -1.228 0.76840E+04 233 boehmite 4.41 2.53 -1.87 -0.312 0.31962E+04 235 ferrous-oxide 9.81 6.32 -3.49 -0.873 0.59624E+04 240 silica-amorphous -2.09 -3.27 -1.18 -0.394 0.20174E+04 242 an20ab80 2.02 1.10 -0.92 -0.071 0.15651E+04 243 an25ab75 2.65 1.58 -1.06 -0.082 0.18112E+04 244 an30ab70 3.28 2.07 -1.21 -0.093 0.20668E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 0.0400000 g Current total amount of reactant added: 1.4790000 g New total amount of reactant added: 1.5190000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.4570E-13 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 6 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 1.5190000 Water: Moles liquid = 0.5549E+02 kg liquid = 0.9997E+00 Moles total = 0.5549E+02 kg total = 0.9997E+00 Activity = 1.0000 Stoichiometric ionic strength = .1354115E-02 Osmotic coef. = 0.9789 True ionic strength = .2116310E-02 Chg. balance for total moles = 0.4570E-13 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.68692E-09 -9.1631 0.63632E-09 -9.1963 0.92634E+00 -0.0332 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13793E-03 -3.8603 0.12766E-03 -3.8939 0.92554E+00 -0.0336 4 SO4-- 0.25498E-04 -4.5935 0.19778E-04 -4.7038 0.77567E+00 -0.1103 5 HCO3- 0.11221E-04 -4.9500 0.10387E-04 -4.9835 0.92573E+00 -0.0335 6 HS- 0.27223E-13 -13.5651 0.25196E-13 -13.5987 0.92556E+00 -0.0336 7 Al+++ 0.15305E-24 -24.8152 0.88205E-25 -25.0545 0.57630E+00 -0.2393 8 H4SiO4 0.53115E-03 -3.2748 0.53115E-03 -3.2748 0.10000E+01 0.0000 9 Ca++ 0.11237E-07 -7.9493 0.87073E-08 -8.0601 0.77487E+00 -0.1108 10 Mg++ 0.18549E-09 -9.7317 0.14364E-09 -9.8427 0.77436E+00 -0.1111 11 Fe++ 0.10943E-11 -11.9609 0.84748E-12 -12.0719 0.77448E+00 -0.1110 12 K+ 0.43710E-04 -4.3594 0.40465E-04 -4.3929 0.92576E+00 -0.0335 13 Na+ 0.20363E-02 -2.6912 0.18846E-02 -2.7248 0.92552E+00 -0.0336 14 Mn++ 0.14702E-09 -9.8326 0.11388E-09 -9.9436 0.77457E+00 -0.1109 15 HPO4-- 0.88887E-05 -5.0512 0.68948E-05 -5.1615 0.77568E+00 -0.1103 16 HSiO3- 0.84211E-03 -3.0746 0.77940E-03 -3.1082 0.92554E+00 -0.0336 17 Ca(HSiO3)+ 0.16694E-09 -9.7774 0.15455E-09 -9.8109 0.92579E+00 -0.0335 18 Mg(HSiO3)+ 0.34273E-11 -11.4650 0.31730E-11 -11.4985 0.92579E+00 -0.0335 19 NaHSiO3,aq 0.23757E-04 -4.6242 0.23757E-04 -4.6242 0.10000E+01 0.0000 20 AlO+ 0.32011E-13 -13.4947 0.29636E-13 -13.5282 0.92579E+00 -0.0335 21 AlOH+2 0.12121E-18 -18.9165 0.93901E-19 -19.0273 0.77468E+00 -0.1109 22 HAlO2,aq 0.92750E-08 -8.0327 0.92750E-08 -8.0327 0.10000E+01 0.0000 23 AlO2- 0.34870E-04 -4.4575 0.32265E-04 -4.4913 0.92530E+00 -0.0337 24 CH4,aq 0.12859E-19 -19.8908 0.12854E-19 -19.8910 0.99958E+00 -0.0002 29 CO,aq 0.16081E-18 -18.7937 0.16081E-18 -18.7937 0.10000E+01 0.0000 30 CO2,aq 0.14129E-07 -7.8499 0.14123E-07 -7.8501 0.99958E+00 -0.0002 31 CO3-2 0.18388E-05 -5.7355 0.14258E-05 -5.8459 0.77543E+00 -0.1105 32 CaCO3,aq 0.15567E-09 -9.8078 0.15567E-09 -9.8078 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.24938E-11 -11.6031 0.23087E-11 -11.6366 0.92579E+00 -0.0335 34 CaCl+ 0.19431E-11 -11.7115 0.17989E-11 -11.7450 0.92579E+00 -0.0335 35 CaCl2,aq 0.54562E-16 -16.2631 0.54562E-16 -16.2631 0.10000E+01 0.0000 36 CaOH+ 0.10534E-08 -8.9774 0.97524E-09 -9.0109 0.92579E+00 -0.0335 37 CaSO4,aq 0.54687E-10 -10.2621 0.54687E-10 -10.2621 0.10000E+01 0.0000 38 HCl,aq 0.14886E-13 -13.8272 0.14886E-13 -13.8272 0.10000E+01 0.0000 43 FeCl+ 0.18498E-15 -15.7329 0.17125E-15 -15.7664 0.92579E+00 -0.0335 46 FeO,aq 0.81347E-10 -10.0897 0.81347E-10 -10.0897 0.10000E+01 0.0000 47 FeOH+ 0.46828E-10 -10.3295 0.43353E-10 -10.3630 0.92579E+00 -0.0335 48 HFeO2- 0.14452E-08 -8.8401 0.13376E-08 -8.8737 0.92554E+00 -0.0336 49 FeO+ 0.52463E-14 -14.2801 0.48570E-14 -14.3136 0.92579E+00 -0.0335 51 FeO2- 0.26520E-08 -8.5764 0.24545E-08 -8.6100 0.92554E+00 -0.0336 52 HFeO2,aq 0.19864E-09 -9.7019 0.19864E-09 -9.7019 0.10000E+01 0.0000 53 H2,aq 0.45345E-09 -9.3435 0.45326E-09 -9.3436 0.99958E+00 -0.0002 54 KCl,aq 0.93628E-10 -10.0286 0.93628E-10 -10.0286 0.10000E+01 0.0000 55 KHSO4,aq 0.14399E-17 -17.8417 0.14399E-17 -17.8417 0.10000E+01 0.0000 56 KOH,aq 0.27157E-07 -7.5661 0.27157E-07 -7.5661 0.10000E+01 0.0000 57 KSO4- 0.13418E-07 -7.8723 0.12419E-07 -7.9059 0.92554E+00 -0.0336 58 MgCO3,aq 0.64369E-12 -12.1913 0.64369E-12 -12.1913 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.42035E-13 -13.3764 0.38916E-13 -13.4099 0.92579E+00 -0.0335 60 MgCl+ 0.29052E-13 -13.5368 0.26896E-13 -13.5703 0.92579E+00 -0.0335 61 MgOH+ 0.96157E-10 -10.0170 0.89021E-10 -10.0505 0.92579E+00 -0.0335 63 MnO,aq 0.29126E-09 -9.5357 0.29126E-09 -9.5357 0.10000E+01 0.0000 64 MnOH+ 0.58455E-09 -9.2332 0.54117E-09 -9.2667 0.92579E+00 -0.0335 65 MnO2-2 0.30786E-13 -13.5116 0.23873E-13 -13.6221 0.77543E+00 -0.1105 66 HMnO2- 0.35958E-11 -11.4442 0.33280E-11 -11.4778 0.92554E+00 -0.0336 69 MnCl+ 0.96702E-13 -13.0146 0.89526E-13 -13.0481 0.92579E+00 -0.0335 70 MnSO4,aq 0.65023E-12 -12.1869 0.65023E-12 -12.1869 0.10000E+01 0.0000 71 NaCl,aq 0.79735E-07 -7.0984 0.79735E-07 -7.0984 0.10000E+01 0.0000 72 NaOH,aq 0.12725E-05 -5.8953 0.12725E-05 -5.8953 0.10000E+01 0.0000 74 OH- 0.98129E-03 -3.0082 0.90799E-03 -3.0419 0.92530E+00 -0.0337 79 HPO3-2 0.12560E-16 -16.9010 0.97391E-17 -17.0115 0.77543E+00 -0.1105 81 H2PO3- 0.13427E-19 -19.8720 0.12427E-19 -19.9056 0.92554E+00 -0.0336 82 H3PO4,aq 0.19525E-13 -13.7094 0.19525E-13 -13.7094 0.10000E+01 0.0000 83 H2PO4- 0.87434E-07 -7.0583 0.80935E-07 -7.0919 0.92566E+00 -0.0335 84 PO4-3 0.15233E-07 -7.8172 0.88405E-08 -8.0535 0.58036E+00 -0.2363 87 H2P2O7-2 0.66237E-15 -15.1789 0.51362E-15 -15.2894 0.77543E+00 -0.1105 88 HP2O7-3 0.27964E-12 -12.5534 0.16117E-12 -12.7927 0.57635E+00 -0.2393 89 P2O7-4 0.15835E-12 -12.8004 0.60509E-13 -13.2182 0.38212E+00 -0.4178 90 H2S,aq 0.49572E-16 -16.3048 0.49551E-16 -16.3049 0.99958E+00 -0.0002 97 SO3-2 0.14992E-14 -14.8241 0.11650E-14 -14.9337 0.77704E+00 -0.1096 98 HSO3- 0.50148E-16 -16.2997 0.46414E-16 -16.3333 0.92554E+00 -0.0336 99 HSO4- 0.13099E-10 -10.8828 0.12129E-10 -10.9162 0.92592E+00 -0.0334 Charge balance for all species = 0.4602E-13 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.6869244E-09 -.1989731E-02 -.2005144E+01 0.0000 2 H2O 0.1000000E+01 0.5550844E+02 0.9998087E+06 0.0000 3 Cl- 0.1379343E-03 0.1380141E-03 0.4892074E+01 5.3024 4 SO4-- 0.2549837E-04 0.2551210E-04 0.2450262E+01 13.6888 5 HCO3- 0.1122072E-04 0.1307379E-04 0.7975723E+00 4.2128 6 HS- 0.2722258E-13 -.2429347E-09 -.8032790E-05 -4.4023 7 Al+++ 0.1530532E-24 0.3487918E-04 0.9409115E+00 2.5345 8 H4SiO4 0.5311452E-03 0.1397010E-02 0.1342484E+03 -3.2748 9 Ca++ 0.1123720E-07 0.1267235E-07 0.5077849E-03 10.3325 10 Mg++ 0.1854909E-09 0.2857896E-09 0.6946781E-05 8.5499 11 Fe++ 0.1094251E-11 0.4425074E-08 0.2470796E-03 6.3208 12 K+ 0.4370993E-04 0.4375060E-04 0.1710407E+01 4.8034 13 Na+ 0.2036291E-02 0.2061401E-02 0.4738207E+02 6.4715 14 Mn++ 0.1470226E-09 0.1027208E-08 0.5642190E-04 8.4491 15 HPO4-- 0.8888735E-05 0.8991403E-05 0.8628198E+00 13.2312 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.2513934E-01 -.1989155E-02 -.2315019E-01 0.0000000E+00 2 H2O 0.5548921E+02 0.5549236E+02 -.3153773E-02 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.6760114E-04 0.2550471E-04 0.4209643E-04 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.4209667E-04 -.2428643E-09 -.4209643E-04 0.0000000E+00 7 Al+++ 0.4953067E-02 0.3486908E-04 0.4918197E-02 0.0000000E+00 8 H4SiO4 0.1581702E-01 0.1396606E-02 0.1442041E-01 0.0000000E+00 9 Ca++ 0.1761538E-02 0.1266868E-07 0.1761525E-02 0.0000000E+00 10 Mg++ 0.1205556E-02 0.2857069E-09 0.1205555E-02 0.0000000E+00 11 Fe++ 0.1083060E-02 0.4423793E-08 0.1083056E-02 0.0000000E+00 12 K+ 0.3225053E-03 0.4373793E-04 0.2787674E-03 0.0000000E+00 13 Na+ 0.2066786E-02 0.2060804E-02 0.5982131E-05 0.0000000E+00 14 Mn++ 0.2633733E-04 0.1026911E-08 0.2633630E-04 0.0000000E+00 15 HPO4-- 0.8988799E-05 0.8988799E-05 0.0000000E+00 0.0000000E+00 Chg. balance for solid moles: -.7860E-18 Mass of aqueous solution: 0.999903E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 1.5190000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) clinochlore 0.2411E-03 -3.618 0.1340 -0.873 8.303 0.5098E-01 daphnite 0.1493E-03 -3.826 0.1065 -0.973 6.598 0.3227E-01 chlorite-Mn 0.5267E-05 -5.278 0.3734E-02 -2.428 0.2314 0.1190E-02 hematite 0.1503E-03 -3.823 0.2400E-01 -1.620 1.487 0.4548E-02 microcline 0.1192E-03 -3.924 0.3318E-01 -1.479 2.056 0.1296E-01 muscovite 0.1596E-03 -3.797 0.6356E-01 -1.197 3.938 0.2247E-01 stilbite 0.1762E-02 -2.754 1.241 0.094 76.91 0.5790 nontronite-Na 0.1813E-04 -4.742 0.7709E-02 -2.113 0.4776 0.2395E-02 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity clinochlore 0.6094E+00 0.6094E+00 1.0000 -0.215 daphnite 0.3773E+00 0.3773E+00 1.0000 -0.423 chlorite-Mn 0.1331E-01 0.1331E-01 1.0000 -1.876 hematite 0.1000E+01 0.1000E+01 1.0000 0.000 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 muscovite 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 nontronite-Na 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 1.614069 g Volume = 0.705818 cm3 Porosity: 56.0949% V(tot) - V(min): 0.90178E+00 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 1.5190000 g log = 0.1816 Original solution: 1000.0103000 g Original solution / Rock added: 658.33 (Water/Rock Ratio), log = 2.8184 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0203 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.1000E+01 0.9860 0.1006E+01 0.1020E+01 CO2,gas 0.1471E-05 1.0071 0.1511E-05 0.1500E-05 CH4,gas 0.1831E-16 1.0125 0.1892E-16 0.1869E-16 H2,gas 0.5829E-06 1.0005 0.5951E-06 0.5948E-06 H2S,gas 0.1340E-14 0.9960 0.1362E-14 0.1368E-14 S2,gas 0.1928E-36 1.0000 0.1967E-36 0.1967E-36 CO,gas 0.2349E-15 1.0000 0.2396E-15 0.2396E-15 SO3,gas 0.2968E-38 1.0000 0.3028E-38 0.3028E-38 SO2,gas 0.6871E-22 1.0000 0.7010E-22 0.7010E-22 HCl,gas 0.2574E-16 1.0000 0.2627E-16 0.2627E-16 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 46 clinochlore 39.07 39.07 0.00 0.000 0.12132E-10 47 daphnite 28.97 28.97 0.00 0.000 0.00000E+00 48 chlorite-Mn 46.87 46.87 0.00 0.000 -0.12132E-10 90 hematite 12.57 12.57 0.00 0.000 -0.90992E-11 116 microcline -2.49 -2.49 0.00 0.000 -0.10616E-10 120 muscovite 2.58 2.58 0.00 0.000 0.60662E-11 163 stilbite -7.52 -7.52 0.00 0.000 0.15165E-10 209 nontronite-Na 3.52 3.52 0.00 0.000 -0.15165E-11 121 paragonite 4.24 4.25 0.01 0.001 -0.19031E+02 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -14.18 -7.52 -2.507 0.12840E+05 -5.821 3 CH4,gas 4.54 -13.88 -18.42 -4.606 0.31455E+05 -16.723 4 H2,gas 8.00 0.08 -7.92 -4.528 0.13531E+05 -6.225 5 H2S,gas -6.23 -22.79 -16.56 -8.282 0.28284E+05 -14.866 6 S2,gas -7.34 -45.74 -38.41 -5.908 0.65576E+05 -36.706 7 CO,gas 3.21 -14.10 -17.32 -5.329 0.29572E+05 -15.620 8 SO3,gas 17.12 -23.10 -40.22 -10.054 0.68671E+05 -38.519 9 SO2,gas 0.83 -23.02 -23.85 -6.361 0.40729E+05 -22.154 10 HCl,gas 5.19 -13.09 -18.28 -9.140 0.31212E+05 -16.581 11 acmite 7.71 6.21 -1.50 -0.156 0.25691E+04 15 albite-high 0.69 -0.82 -1.51 -0.116 0.25807E+04 16 albite -0.38 -0.82 -0.43 -0.033 0.74187E+03 19 spessartine 24.46 20.59 -3.87 -0.193 0.66002E+04 20 analcite 3.32 2.46 -0.87 -0.096 0.14777E+04 21 andalusite 5.00 1.79 -3.21 -0.321 0.54765E+04 26 annite 20.12 16.48 -3.65 -0.203 0.62281E+04 27 phlogopite 27.06 23.16 -3.90 -0.217 0.66614E+04 29 anorthite 12.71 8.85 -3.86 -0.297 0.65882E+04 32 apatite-OH -18.15 -19.00 -0.85 -0.065 0.14449E+04 35 aragonite 0.97 -3.85 -4.81 -1.605 0.82194E+04 36 brucite 12.57 8.55 -4.02 -0.804 0.68617E+04 37 calcite 0.81 -3.85 -4.66 -1.553 0.79552E+04 38 carnegieite-low 9.02 5.73 -3.29 -0.470 0.56211E+04 39 carnegieite-high 10.09 5.73 -4.36 -0.623 0.74481E+04 40 carpholite-Mg 8.58 7.07 -1.51 -0.101 0.25831E+04 41 carpholite-Fe 6.71 4.84 -1.87 -0.125 0.31973E+04 42 celadonite 5.34 2.79 -2.55 -0.150 0.43591E+04 43 celadonite-Fe 3.88 0.56 -3.32 -0.195 0.56637E+04 44 chrysotile 23.89 19.10 -4.79 -0.399 0.81826E+04 50 chloritoid-Mg 13.20 10.34 -2.85 -0.190 0.48725E+04 51 chloritoid-Fe 9.17 8.11 -1.06 -0.071 0.18077E+04 52 chloritoid-Mn 11.40 10.24 -1.16 -0.077 0.19770E+04 54 coesite -2.38 -3.27 -0.90 -0.300 0.15345E+04 59 corundum 8.38 5.07 -3.31 -0.301 0.56589E+04 61 cristobalite -2.56 -3.27 -0.71 -0.238 0.12199E+04 63 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71234E+04 65 diaspore 2.87 2.53 -0.34 -0.057 0.57923E+03 67 diopside 16.18 12.33 -3.85 -0.385 0.65712E+04 68 hedenbergite 14.21 10.10 -4.10 -0.410 0.70084E+04 75 epidote 24.67 22.19 -2.48 -0.120 0.42297E+04 76 clinozoisite 22.81 18.44 -4.36 -0.198 0.74479E+04 77 epidote-Fe 29.84 25.94 -3.90 -0.203 0.66582E+04 78 fayalite 14.05 9.37 -4.68 -0.668 0.79892E+04 83 gibbsite 4.08 2.53 -1.54 -0.221 0.26378E+04 87 greenalite 16.14 12.41 -3.73 -0.311 0.63633E+04 91 heulandite -5.83 -7.52 -1.69 -0.077 0.28938E+04 95 jadeite 4.22 2.46 -1.76 -0.176 0.30032E+04 97 kalsilite 7.58 4.06 -3.52 -0.503 0.60117E+04 98 kaolinite -1.33 -1.48 -0.15 -0.013 0.25250E+03 99 kyanite 4.88 1.79 -3.08 -0.308 0.52624E+04 101 laumontite 2.88 2.30 -0.58 -0.039 0.99222E+03 102 lawsonite 9.62 8.85 -0.76 -0.051 0.13048E+04 103 leucite 4.12 0.79 -3.33 -0.333 0.56869E+04 105 lizardite 23.24 19.10 -4.14 -0.345 0.70752E+04 107 magnetite 20.09 18.89 -1.20 -0.098 0.20497E+04 108 minnesotaite 10.39 5.86 -4.52 -0.266 0.77262E+04 113 margarite 17.32 13.92 -3.40 -0.136 0.58102E+04 122 nepheline 8.34 5.73 -2.61 -0.373 0.44535E+04 134 phlogopite-Na 29.65 24.83 -4.82 -0.268 0.82221E+04 136 prehnite 19.37 15.91 -3.46 -0.204 0.59117E+04 137 prehnite-Fe 22.50 19.66 -2.84 -0.171 0.48486E+04 145 pyroxmangite 7.40 5.17 -2.22 -0.445 0.37981E+04 146 pyrophyllite -6.18 -8.03 -1.85 -0.116 0.31664E+04 147 quartz -2.99 -3.27 -0.29 -0.095 0.48723E+03 151 rhodochrosite -0.98 -5.73 -4.75 -1.585 0.81180E+04 152 rhodonite 7.45 5.17 -2.27 -0.454 0.38783E+04 153 sanidine -1.28 -2.49 -1.21 -0.093 0.20677E+04 156 sillimanite 5.26 1.79 -3.47 -0.347 0.59205E+04 164 stilpnomelane-Fe 13.02 12.88 -0.14 -0.004 0.24035E+03 165 stilpnomelane-Mg 27.44 24.02 -3.42 -0.102 0.58387E+04 168 sudoite 21.08 17.41 -3.66 -0.118 0.62562E+04 171 talc 16.49 12.55 -3.94 -0.232 0.67283E+04 174 tephroite 18.09 13.62 -4.46 -0.637 0.76194E+04 177 topaz-H 4.62 1.79 -2.82 -0.257 0.48225E+04 178 tridymite -2.63 -3.27 -0.65 -0.216 0.11072E+04 187 wairakite 3.95 2.30 -1.65 -0.097 0.28142E+04 188 walstromite 11.51 7.06 -4.45 -0.890 0.76008E+04 189 wollastonite 10.46 7.06 -3.40 -0.681 0.58112E+04 190 pseudo-wollastonite 11.00 7.06 -3.94 -0.788 0.67310E+04 191 zoisite 22.85 18.44 -4.41 -0.200 0.75220E+04 192 akaganeite 7.75 6.28 -1.47 -0.318 0.25125E+04 193 beidellite-Ca -1.65 -4.41 -2.76 -0.171 0.47172E+04 194 beidellite-H -2.33 -6.11 -3.79 -0.242 0.64661E+04 195 beidellite-K -1.52 -4.53 -3.01 -0.184 0.51358E+04 196 beidellite-Mg -1.79 -4.70 -2.91 -0.180 0.49733E+04 197 beidellite-Na -1.34 -3.98 -2.64 -0.161 0.44997E+04 199 chalcedony -2.80 -3.27 -0.47 -0.157 0.80653E+03 201 montmorillonite-Ca -2.29 -4.34 -2.05 -0.127 0.34995E+04 202 montmorillonite-K -2.24 -4.46 -2.22 -0.136 0.37962E+04 203 montmorillonite-Mg -2.48 -4.63 -2.15 -0.133 0.36788E+04 204 montmorillonite-Na -2.04 -3.91 -1.87 -0.115 0.31959E+04 205 nontronite-Ca 3.21 3.09 -0.13 -0.008 0.21443E+03 206 nontronite-H 2.53 1.38 -1.15 -0.077 0.19612E+04 207 nontronite-K 3.34 2.97 -0.37 -0.024 0.63431E+03 208 nontronite-Mg 3.07 2.79 -0.28 -0.018 0.47774E+03 224 tobermorite 9.82 5.33 -4.49 -1.225 0.76680E+04 233 boehmite 4.41 2.53 -1.87 -0.312 0.31962E+04 235 ferrous-oxide 9.81 6.32 -3.49 -0.873 0.59605E+04 240 silica-amorphous -2.09 -3.27 -1.18 -0.394 0.20207E+04 242 an20ab80 2.02 1.12 -0.90 -0.069 0.15403E+04 243 an25ab75 2.65 1.60 -1.05 -0.080 0.17869E+04 244 an30ab70 3.28 2.08 -1.20 -0.092 0.20430E+04 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 8 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 1.5190000 Water: Moles liquid = 0.5549E+02 kg liquid = 0.9997E+00 Moles total = 0.5549E+02 kg total = 0.9997E+00 Activity = 1.0000 Stoichiometric ionic strength = .1334127E-02 Osmotic coef. = 0.9791 True ionic strength = .2083127E-02 Chg. balance for total moles = 0.4570E-13 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.69978E-09 -9.1550 0.64851E-09 -9.1881 0.92673E+00 -0.0330 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13794E-03 -3.8603 0.12772E-03 -3.8937 0.92595E+00 -0.0334 4 SO4-- 0.25498E-04 -4.5935 0.19812E-04 -4.7031 0.77701E+00 -0.1096 5 HCO3- 0.11252E-04 -4.9488 0.10421E-04 -4.9821 0.92613E+00 -0.0333 6 HS- 0.27362E-13 -13.5629 0.25336E-13 -13.5963 0.92597E+00 -0.0334 7 Al+++ 0.16138E-24 -24.7921 0.93371E-25 -25.0298 0.57857E+00 -0.2376 8 H4SiO4 0.53283E-03 -3.2734 0.53283E-03 -3.2734 0.10000E+01 0.0000 9 Ca++ 0.11396E-07 -7.9432 0.88462E-08 -8.0532 0.77622E+00 -0.1100 10 Mg++ 0.19196E-09 -9.7168 0.14891E-09 -9.8271 0.77573E+00 -0.1103 11 Fe++ 0.11324E-11 -11.9460 0.87859E-12 -12.0562 0.77585E+00 -0.1102 12 K+ 0.44108E-04 -4.3555 0.40851E-04 -4.3888 0.92617E+00 -0.0333 13 Na+ 0.20027E-02 -2.6984 0.18544E-02 -2.7318 0.92593E+00 -0.0334 14 Mn++ 0.15215E-09 -9.8177 0.11806E-09 -9.9279 0.77594E+00 -0.1102 15 HPO4-- 0.88873E-05 -5.0512 0.69057E-05 -5.1608 0.77703E+00 -0.1096 16 HSiO3- 0.82853E-03 -3.0817 0.76718E-03 -3.1151 0.92595E+00 -0.0334 17 Ca(HSiO3)+ 0.16687E-09 -9.7776 0.15456E-09 -9.8109 0.92620E+00 -0.0333 18 Mg(HSiO3)+ 0.34958E-11 -11.4565 0.32378E-11 -11.4897 0.92620E+00 -0.0333 19 NaHSiO3,aq 0.23009E-04 -4.6381 0.23009E-04 -4.6381 0.10000E+01 0.0000 20 AlO+ 0.32610E-13 -13.4866 0.30203E-13 -13.5199 0.92620E+00 -0.0333 21 AlOH+2 0.12568E-18 -18.9007 0.97532E-19 -19.0109 0.77604E+00 -0.1101 22 HAlO2,aq 0.92750E-08 -8.0327 0.92750E-08 -8.0327 0.10000E+01 0.0000 23 AlO2- 0.34199E-04 -4.4660 0.31659E-04 -4.4995 0.92571E+00 -0.0335 24 CH4,aq 0.12950E-19 -19.8877 0.12945E-19 -19.8879 0.99959E+00 -0.0002 29 CO,aq 0.16380E-18 -18.7857 0.16380E-18 -18.7857 0.10000E+01 0.0000 30 CO2,aq 0.14447E-07 -7.8402 0.14441E-07 -7.8404 0.99959E+00 -0.0002 31 CO3-2 0.18069E-05 -5.7431 0.14036E-05 -5.8528 0.77678E+00 -0.1097 32 CaCO3,aq 0.15569E-09 -9.8077 0.15569E-09 -9.8077 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.25407E-11 -11.5950 0.23532E-11 -11.6283 0.92620E+00 -0.0333 34 CaCl+ 0.19741E-11 -11.7046 0.18284E-11 -11.7379 0.92620E+00 -0.0333 35 CaCl2,aq 0.55482E-16 -16.2558 0.55482E-16 -16.2558 0.10000E+01 0.0000 36 CaOH+ 0.10496E-08 -8.9790 0.97217E-09 -9.0123 0.92620E+00 -0.0333 37 CaSO4,aq 0.55655E-10 -10.2545 0.55655E-10 -10.2545 0.10000E+01 0.0000 38 HCl,aq 0.15178E-13 -13.8188 0.15178E-13 -13.8188 0.10000E+01 0.0000 43 FeCl+ 0.19177E-15 -15.7172 0.17762E-15 -15.7505 0.92620E+00 -0.0333 46 FeO,aq 0.81192E-10 -10.0905 0.81192E-10 -10.0905 0.10000E+01 0.0000 47 FeOH+ 0.47613E-10 -10.3223 0.44099E-10 -10.3556 0.92620E+00 -0.0333 48 HFeO2- 0.14147E-08 -8.8493 0.13100E-08 -8.8827 0.92595E+00 -0.0334 49 FeO+ 0.53445E-14 -14.2721 0.49500E-14 -14.3054 0.92620E+00 -0.0333 51 FeO2- 0.26010E-08 -8.5849 0.24084E-08 -8.6183 0.92595E+00 -0.0334 52 HFeO2,aq 0.19864E-09 -9.7019 0.19864E-09 -9.7019 0.10000E+01 0.0000 53 H2,aq 0.45173E-09 -9.3451 0.45155E-09 -9.3453 0.99959E+00 -0.0002 54 KCl,aq 0.94564E-10 -10.0243 0.94564E-10 -10.0243 0.10000E+01 0.0000 55 KHSO4,aq 0.14840E-17 -17.8286 0.14840E-17 -17.8286 0.10000E+01 0.0000 56 KOH,aq 0.26901E-07 -7.5702 0.26901E-07 -7.5702 0.10000E+01 0.0000 57 KSO4- 0.13564E-07 -7.8676 0.12559E-07 -7.9010 0.92595E+00 -0.0334 58 MgCO3,aq 0.65690E-12 -12.1825 0.65690E-12 -12.1825 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.43701E-13 -13.3595 0.40475E-13 -13.3928 0.92620E+00 -0.0333 60 MgCl+ 0.30119E-13 -13.5212 0.27896E-13 -13.5545 0.92620E+00 -0.0333 61 MgOH+ 0.97770E-10 -10.0098 0.90554E-10 -10.0431 0.92620E+00 -0.0333 63 MnO,aq 0.29071E-09 -9.5365 0.29071E-09 -9.5365 0.10000E+01 0.0000 64 MnOH+ 0.59436E-09 -9.2260 0.55049E-09 -9.2592 0.92620E+00 -0.0333 65 MnO2-2 0.29532E-13 -13.5297 0.22940E-13 -13.6394 0.77678E+00 -0.1097 66 HMnO2- 0.35200E-11 -11.4535 0.32593E-11 -11.4869 0.92595E+00 -0.0334 69 MnCl+ 0.10025E-12 -12.9989 0.92854E-13 -13.0322 0.92620E+00 -0.0333 70 MnSO4,aq 0.67527E-12 -12.1705 0.67527E-12 -12.1705 0.10000E+01 0.0000 71 NaCl,aq 0.78491E-07 -7.1052 0.78491E-07 -7.1052 0.10000E+01 0.0000 72 NaOH,aq 0.12286E-05 -5.9106 0.12286E-05 -5.9106 0.10000E+01 0.0000 74 OH- 0.96242E-03 -3.0166 0.89092E-03 -3.0502 0.92571E+00 -0.0335 79 HPO3-2 0.12510E-16 -16.9027 0.97175E-17 -17.0124 0.77678E+00 -0.1097 81 H2PO3- 0.13648E-19 -19.8649 0.12637E-19 -19.8984 0.92595E+00 -0.0334 82 H3PO4,aq 0.20312E-13 -13.6922 0.20312E-13 -13.6922 0.10000E+01 0.0000 83 H2PO4- 0.89210E-07 -7.0496 0.82614E-07 -7.0829 0.92607E+00 -0.0334 84 PO4-3 0.14913E-07 -7.8264 0.86880E-08 -8.0611 0.58259E+00 -0.2346 87 H2P2O7-2 0.68894E-15 -15.1618 0.53516E-15 -15.2715 0.77678E+00 -0.1097 88 HP2O7-3 0.28477E-12 -12.5455 0.16478E-12 -12.7831 0.57862E+00 -0.2376 89 P2O7-4 0.15775E-12 -12.8020 0.60699E-13 -13.2168 0.38478E+00 -0.4148 90 H2S,aq 0.50802E-16 -16.2941 0.50781E-16 -16.2943 0.99959E+00 -0.0002 97 SO3-2 0.14936E-14 -14.8258 0.11626E-14 -14.9346 0.77837E+00 -0.1088 98 HSO3- 0.50981E-16 -16.2926 0.47206E-16 -16.3260 0.92595E+00 -0.0334 99 HSO4- 0.13367E-10 -10.8740 0.12382E-10 -10.9072 0.92632E+00 -0.0332 Charge balance for all species = 0.4616E-13 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.6997820E-09 -.1953778E-02 -.1968916E+01 0.0000 2 H2O 0.1000000E+01 0.5550843E+02 0.9998107E+06 0.0000 3 Cl- 0.1379354E-03 0.1380140E-03 0.4892079E+01 5.2943 4 SO4-- 0.2549820E-04 0.2551207E-04 0.2450263E+01 13.6731 5 HCO3- 0.1125224E-04 0.1307377E-04 0.7975731E+00 4.2060 6 HS- 0.2736155E-13 -.2369912E-09 -.7836282E-05 -4.4082 7 Al+++ 0.1613817E-24 0.3420867E-04 0.9228255E+00 2.5345 8 H4SiO4 0.5328263E-03 0.1384368E-02 0.1330337E+03 -3.2734 9 Ca++ 0.1139648E-07 0.1282886E-07 0.5140570E-03 10.3229 10 Mg++ 0.1919616E-09 0.2939583E-09 0.7145353E-05 8.5491 11 Fe++ 0.1132426E-11 0.4344290E-08 0.2425694E-03 6.3200 12 K+ 0.4410754E-04 0.4414810E-04 0.1725950E+01 4.7993 13 Na+ 0.2002745E-02 0.2027061E-02 0.4659286E+02 6.4563 14 Mn++ 0.1521519E-09 0.1041545E-08 0.5720950E-04 8.4483 15 HPO4-- 0.8887269E-05 0.8991392E-05 0.8628206E+00 13.2154 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.2513934E-01 -.1953214E-02 -.2318613E-01 0.0000000E+00 2 H2O 0.5548921E+02 0.5549242E+02 -.3210973E-02 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.6760114E-04 0.2550471E-04 0.4209643E-04 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.4209667E-04 -.2369229E-09 -.4209643E-04 0.0000000E+00 7 Al+++ 0.4953067E-02 0.3419880E-04 0.4918868E-02 0.0000000E+00 8 H4SiO4 0.1581702E-01 0.1383968E-02 0.1443305E-01 0.0000000E+00 9 Ca++ 0.1761538E-02 0.1282516E-07 0.1761525E-02 0.0000000E+00 10 Mg++ 0.1205556E-02 0.2938735E-09 0.1205555E-02 0.0000000E+00 11 Fe++ 0.1083060E-02 0.4343037E-08 0.1083056E-02 0.0000000E+00 12 K+ 0.3225053E-03 0.4413537E-04 0.2783699E-03 0.0000000E+00 13 Na+ 0.2066786E-02 0.2026476E-02 0.4030973E-04 0.0000000E+00 14 Mn++ 0.2633733E-04 0.1041244E-08 0.2633629E-04 0.0000000E+00 15 HPO4-- 0.8988799E-05 0.8988799E-05 0.0000000E+00 0.0000000E+00 Chg. balance for solid moles: 0.3253E-18 Mass of aqueous solution: 0.999902E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 1.5190000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) clinochlore 0.2411E-03 -3.618 0.1340 -0.873 8.298 0.5098E-01 daphnite 0.1493E-03 -3.826 0.1065 -0.973 6.594 0.3227E-01 chlorite-Mn 0.5267E-05 -5.278 0.3734E-02 -2.428 0.2312 0.1190E-02 hematite 0.1835E-03 -3.736 0.2931E-01 -1.533 1.815 0.5555E-02 microcline 0.1807E-03 -3.743 0.5031E-01 -1.298 3.115 0.1965E-01 muscovite 0.9763E-04 -4.010 0.3889E-01 -1.410 2.408 0.1375E-01 stilbite 0.1762E-02 -2.754 1.241 0.094 76.87 0.5790 nontronite-Na -.1514E-04 1.000 -.6438E-02 1.000 -.3986 -.2000E-02 paragonite 0.4531E-04 -4.344 0.1732E-01 -1.762 1.072 0.5985E-02 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity clinochlore 0.6094E+00 0.6094E+00 1.0000 -0.215 daphnite 0.3773E+00 0.3773E+00 1.0000 -0.423 chlorite-Mn 0.1331E-01 0.1331E-01 1.0000 -1.876 hematite 0.1000E+01 0.1000E+01 1.0000 0.000 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 muscovite 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 nontronite-Na 0.1000E+01 0.1000E+01 1.0000 0.000 paragonite 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 1.615010 g Volume = 0.706383 cm3 Porosity: 56.0598% V(tot) - V(min): 0.90122E+00 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 1.5190000 g log = 0.1816 Original solution: 1000.0103000 g Original solution / Rock added: 658.33 (Water/Rock Ratio), log = 2.8184 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0203 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.1000E+01 0.9860 0.1006E+01 0.1020E+01 CO2,gas 0.1504E-05 1.0071 0.1545E-05 0.1534E-05 CH4,gas 0.1844E-16 1.0125 0.1905E-16 0.1882E-16 H2,gas 0.5807E-06 1.0005 0.5928E-06 0.5925E-06 H2S,gas 0.1374E-14 0.9960 0.1396E-14 0.1401E-14 S2,gas 0.2040E-36 1.0000 0.2081E-36 0.2081E-36 CO,gas 0.2392E-15 1.0000 0.2441E-15 0.2441E-15 SO3,gas 0.3088E-38 1.0000 0.3151E-38 0.3151E-38 SO2,gas 0.7122E-22 1.0000 0.7266E-22 0.7266E-22 HCl,gas 0.2625E-16 1.0000 0.2678E-16 0.2678E-16 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 46 clinochlore 39.07 39.07 0.00 0.000 -0.12132E-10 47 daphnite 28.97 28.97 0.00 0.000 0.60662E-11 48 chlorite-Mn 46.87 46.87 0.00 0.000 0.00000E+00 90 hematite 12.57 12.57 0.00 0.000 0.15165E-10 116 microcline -2.49 -2.49 0.00 0.000 0.15165E-11 120 muscovite 2.58 2.58 0.00 0.000 0.60662E-11 121 paragonite 4.24 4.24 0.00 0.000 -0.10616E-10 163 stilbite -7.52 -7.52 0.00 0.000 -0.90992E-11 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -14.17 -7.51 -2.503 0.12823E+05 -5.811 3 CH4,gas 4.54 -13.88 -18.42 -4.605 0.31450E+05 -16.720 4 H2,gas 8.00 0.07 -7.93 -4.529 0.13533E+05 -6.227 5 H2S,gas -6.23 -22.78 -16.55 -8.277 0.28266E+05 -14.855 6 S2,gas -7.34 -45.72 -38.38 -5.905 0.65534E+05 -36.682 7 CO,gas 3.21 -14.10 -17.31 -5.327 0.29559E+05 -15.612 8 SO3,gas 17.12 -23.08 -40.20 -10.050 0.68641E+05 -38.502 9 SO2,gas 0.83 -23.01 -23.84 -6.357 0.40702E+05 -22.139 10 HCl,gas 5.19 -13.08 -18.27 -9.136 0.31197E+05 -16.572 11 acmite 7.71 6.19 -1.52 -0.158 0.25905E+04 15 albite-high 0.69 -0.83 -1.52 -0.117 0.25997E+04 16 albite -0.38 -0.83 -0.45 -0.034 0.76090E+03 19 spessartine 24.46 20.59 -3.86 -0.193 0.65974E+04 20 analcite 3.32 2.44 -0.88 -0.098 0.14991E+04 21 andalusite 5.00 1.80 -3.21 -0.321 0.54742E+04 26 annite 20.12 16.47 -3.65 -0.203 0.62323E+04 27 phlogopite 27.06 23.16 -3.90 -0.217 0.66657E+04 29 anorthite 12.71 8.85 -3.87 -0.297 0.65999E+04 32 apatite-OH -18.15 -19.00 -0.84 -0.065 0.14390E+04 35 aragonite 0.97 -3.85 -4.81 -1.605 0.82194E+04 36 brucite 12.57 8.55 -4.02 -0.804 0.68631E+04 37 calcite 0.81 -3.85 -4.66 -1.553 0.79552E+04 38 carnegieite-low 9.02 5.72 -3.31 -0.472 0.56448E+04 39 carnegieite-high 10.09 5.72 -4.38 -0.625 0.74718E+04 40 carpholite-Mg 8.58 7.07 -1.51 -0.101 0.25798E+04 41 carpholite-Fe 6.71 4.84 -1.87 -0.125 0.31940E+04 42 celadonite 5.34 2.79 -2.55 -0.150 0.43582E+04 43 celadonite-Fe 3.88 0.56 -3.32 -0.195 0.56628E+04 44 chrysotile 23.89 19.10 -4.79 -0.399 0.81821E+04 50 chloritoid-Mg 13.20 10.34 -2.85 -0.190 0.48716E+04 51 chloritoid-Fe 9.17 8.12 -1.06 -0.071 0.18068E+04 52 chloritoid-Mn 11.40 10.24 -1.16 -0.077 0.19760E+04 54 coesite -2.38 -3.27 -0.90 -0.299 0.15322E+04 59 corundum 8.38 5.07 -3.31 -0.301 0.56589E+04 61 cristobalite -2.56 -3.27 -0.71 -0.238 0.12176E+04 63 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71234E+04 65 diaspore 2.87 2.53 -0.34 -0.057 0.57923E+03 67 diopside 16.18 12.33 -3.86 -0.386 0.65843E+04 68 hedenbergite 14.21 10.10 -4.11 -0.411 0.70215E+04 75 epidote 24.67 22.18 -2.49 -0.121 0.42555E+04 76 clinozoisite 22.81 18.43 -4.38 -0.199 0.74737E+04 77 epidote-Fe 29.84 25.93 -3.91 -0.203 0.66840E+04 78 fayalite 14.05 9.37 -4.68 -0.668 0.79897E+04 83 gibbsite 4.08 2.53 -1.54 -0.221 0.26378E+04 87 greenalite 16.14 12.41 -3.73 -0.311 0.63629E+04 91 heulandite -5.83 -7.52 -1.69 -0.077 0.28938E+04 95 jadeite 4.22 2.44 -1.77 -0.177 0.30245E+04 97 kalsilite 7.58 4.06 -3.52 -0.503 0.60164E+04 98 kaolinite -1.33 -1.48 -0.15 -0.013 0.24781E+03 99 kyanite 4.88 1.80 -3.08 -0.308 0.52601E+04 101 laumontite 2.88 2.30 -0.59 -0.039 0.99925E+03 102 lawsonite 9.62 8.85 -0.77 -0.051 0.13166E+04 103 leucite 4.12 0.79 -3.33 -0.333 0.56892E+04 105 lizardite 23.24 19.10 -4.14 -0.345 0.70748E+04 107 magnetite 20.09 18.89 -1.20 -0.098 0.20511E+04 108 minnesotaite 10.39 5.87 -4.52 -0.266 0.77210E+04 113 margarite 17.32 13.91 -3.41 -0.136 0.58219E+04 122 nepheline 8.34 5.72 -2.62 -0.375 0.44772E+04 134 phlogopite-Na 29.65 24.82 -4.83 -0.268 0.82454E+04 136 prehnite 19.37 15.89 -3.48 -0.205 0.59375E+04 137 prehnite-Fe 22.50 19.64 -2.85 -0.172 0.48743E+04 145 pyroxmangite 7.40 5.17 -2.22 -0.445 0.37971E+04 146 pyrophyllite -6.18 -8.02 -1.85 -0.116 0.31570E+04 147 quartz -2.99 -3.27 -0.28 -0.095 0.48489E+03 151 rhodochrosite -0.98 -5.72 -4.75 -1.582 0.81029E+04 152 rhodonite 7.45 5.17 -2.27 -0.454 0.38774E+04 153 sanidine -1.28 -2.49 -1.21 -0.093 0.20677E+04 156 sillimanite 5.26 1.80 -3.47 -0.347 0.59181E+04 164 stilpnomelane-Fe 13.02 12.88 -0.14 -0.004 0.23215E+03 165 stilpnomelane-Mg 27.44 24.03 -3.41 -0.102 0.58305E+04 168 sudoite 21.08 17.42 -3.66 -0.118 0.62520E+04 171 talc 16.49 12.55 -3.94 -0.232 0.67231E+04 174 tephroite 18.09 13.62 -4.46 -0.638 0.76199E+04 177 topaz-H 4.62 1.80 -2.82 -0.257 0.48202E+04 178 tridymite -2.63 -3.27 -0.65 -0.216 0.11049E+04 187 wairakite 3.95 2.30 -1.65 -0.097 0.28212E+04 188 walstromite 11.51 7.05 -4.46 -0.892 0.76148E+04 189 wollastonite 10.46 7.05 -3.41 -0.682 0.58253E+04 190 pseudo-wollastonite 11.00 7.05 -3.95 -0.790 0.67451E+04 191 zoisite 22.85 18.43 -4.42 -0.201 0.75477E+04 192 akaganeite 7.75 6.28 -1.47 -0.318 0.25125E+04 193 beidellite-Ca -1.65 -4.40 -2.76 -0.171 0.47113E+04 194 beidellite-H -2.33 -6.11 -3.78 -0.241 0.64575E+04 195 beidellite-K -1.52 -4.52 -3.00 -0.184 0.51295E+04 196 beidellite-Mg -1.79 -4.70 -2.91 -0.180 0.49649E+04 197 beidellite-Na -1.34 -3.98 -2.64 -0.161 0.44997E+04 199 chalcedony -2.80 -3.27 -0.47 -0.157 0.80418E+03 201 montmorillonite-Ca -2.29 -4.34 -2.05 -0.127 0.34933E+04 202 montmorillonite-K -2.24 -4.46 -2.22 -0.136 0.37896E+04 203 montmorillonite-Mg -2.48 -4.63 -2.15 -0.133 0.36701E+04 204 montmorillonite-Na -2.04 -3.91 -1.87 -0.115 0.31956E+04 205 nontronite-Ca 3.21 3.09 -0.12 -0.008 0.20854E+03 206 nontronite-H 2.53 1.39 -1.14 -0.077 0.19526E+04 207 nontronite-K 3.34 2.97 -0.37 -0.024 0.62803E+03 208 nontronite-Mg 3.07 2.80 -0.27 -0.018 0.46938E+03 209 nontronite-Na 3.52 3.52 0.00 0.000 0.83410E-11 224 tobermorite 9.82 5.33 -4.50 -1.227 0.76793E+04 233 boehmite 4.41 2.53 -1.87 -0.312 0.31962E+04 235 ferrous-oxide 9.81 6.32 -3.49 -0.873 0.59619E+04 240 silica-amorphous -2.09 -3.27 -1.18 -0.394 0.20184E+04 242 an20ab80 2.02 1.11 -0.91 -0.070 0.15578E+04 243 an25ab75 2.65 1.59 -1.06 -0.081 0.18041E+04 244 an30ab70 3.28 2.07 -1.21 -0.093 0.20599E+04 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 6 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 1.5190000 Water: Moles liquid = 0.5549E+02 kg liquid = 0.9997E+00 Moles total = 0.5549E+02 kg total = 0.9997E+00 Activity = 1.0000 Stoichiometric ionic strength = .1342604E-02 Osmotic coef. = 0.9790 True ionic strength = .2096775E-02 Chg. balance for total moles = 0.4570E-13 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.69316E-09 -9.1592 0.64226E-09 -9.1923 0.92657E+00 -0.0331 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13793E-03 -3.8603 0.12770E-03 -3.8938 0.92578E+00 -0.0335 4 SO4-- 0.25498E-04 -4.5935 0.19798E-04 -4.7034 0.77646E+00 -0.1099 5 HCO3- 0.11236E-04 -4.9494 0.10405E-04 -4.9828 0.92597E+00 -0.0334 6 HS- 0.27792E-13 -13.5561 0.25730E-13 -13.5896 0.92580E+00 -0.0335 7 Al+++ 0.15701E-24 -24.8041 0.90696E-25 -25.0424 0.57764E+00 -0.2383 8 H4SiO4 0.52997E-03 -3.2758 0.52997E-03 -3.2758 0.10000E+01 0.0000 9 Ca++ 0.11615E-07 -7.9350 0.90095E-08 -8.0453 0.77566E+00 -0.1103 10 Mg++ 0.18902E-09 -9.7235 0.14652E-09 -9.8341 0.77516E+00 -0.1106 11 Fe++ 0.11151E-11 -11.9527 0.86451E-12 -12.0632 0.77528E+00 -0.1105 12 K+ 0.44401E-04 -4.3526 0.41116E-04 -4.3860 0.92600E+00 -0.0334 13 Na+ 0.20161E-02 -2.6955 0.18664E-02 -2.7290 0.92576E+00 -0.0335 14 Mn++ 0.14982E-09 -9.8244 0.11617E-09 -9.9349 0.77537E+00 -0.1105 15 HPO4-- 0.88880E-05 -5.0512 0.69013E-05 -5.1611 0.77647E+00 -0.1099 16 HSiO3- 0.83226E-03 -3.0797 0.77049E-03 -3.1132 0.92578E+00 -0.0335 17 Ca(HSiO3)+ 0.17072E-09 -9.7677 0.15809E-09 -9.8011 0.92603E+00 -0.0334 18 Mg(HSiO3)+ 0.34553E-11 -11.4615 0.31997E-11 -11.4949 0.92603E+00 -0.0334 19 NaHSiO3,aq 0.23258E-04 -4.6334 0.23258E-04 -4.6334 0.10000E+01 0.0000 20 AlO+ 0.32302E-13 -13.4908 0.29912E-13 -13.5242 0.92603E+00 -0.0334 21 AlOH+2 0.12336E-18 -18.9088 0.95661E-19 -19.0193 0.77548E+00 -0.1104 22 HAlO2,aq 0.92750E-08 -8.0327 0.92750E-08 -8.0327 0.10000E+01 0.0000 23 AlO2- 0.34539E-04 -4.4617 0.31967E-04 -4.4953 0.92554E+00 -0.0336 24 CH4,aq 0.13140E-19 -19.8814 0.13135E-19 -19.8816 0.99958E+00 -0.0002 29 CO,aq 0.16302E-18 -18.7878 0.16302E-18 -18.7878 0.10000E+01 0.0000 30 CO2,aq 0.14285E-07 -7.8451 0.14279E-07 -7.8453 0.99958E+00 -0.0002 31 CO3-2 0.18229E-05 -5.7392 0.14150E-05 -5.8492 0.77622E+00 -0.1100 32 CaCO3,aq 0.15985E-09 -9.7963 0.15985E-09 -9.7963 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.25839E-11 -11.5877 0.23928E-11 -11.6211 0.92603E+00 -0.0334 34 CaCl+ 0.20106E-11 -11.6967 0.18619E-11 -11.7301 0.92603E+00 -0.0334 35 CaCl2,aq 0.56485E-16 -16.2481 0.56485E-16 -16.2481 0.10000E+01 0.0000 36 CaOH+ 0.10796E-08 -8.9667 0.99976E-09 -9.0001 0.92603E+00 -0.0334 37 CaSO4,aq 0.56642E-10 -10.2469 0.56642E-10 -10.2469 0.10000E+01 0.0000 38 HCl,aq 0.15029E-13 -13.8231 0.15029E-13 -13.8231 0.10000E+01 0.0000 43 FeCl+ 0.18870E-15 -15.7242 0.17474E-15 -15.7576 0.92603E+00 -0.0334 46 FeO,aq 0.81455E-10 -10.0891 0.81455E-10 -10.0891 0.10000E+01 0.0000 47 FeOH+ 0.47315E-10 -10.3250 0.43815E-10 -10.3584 0.92603E+00 -0.0334 48 HFeO2- 0.14334E-08 -8.8436 0.13270E-08 -8.8771 0.92578E+00 -0.0335 49 FeO+ 0.52939E-14 -14.2762 0.49023E-14 -14.3096 0.92603E+00 -0.0334 51 FeO2- 0.26268E-08 -8.5806 0.24318E-08 -8.6141 0.92578E+00 -0.0335 52 HFeO2,aq 0.19864E-09 -9.7019 0.19864E-09 -9.7019 0.10000E+01 0.0000 53 H2,aq 0.45466E-09 -9.3423 0.45447E-09 -9.3425 0.99958E+00 -0.0002 54 KCl,aq 0.95158E-10 -10.0216 0.95158E-10 -10.0216 0.10000E+01 0.0000 55 KHSO4,aq 0.14782E-17 -17.8303 0.14782E-17 -17.8303 0.10000E+01 0.0000 56 KOH,aq 0.27339E-07 -7.5632 0.27339E-07 -7.5632 0.10000E+01 0.0000 57 KSO4- 0.13644E-07 -7.8651 0.12632E-07 -7.8985 0.92578E+00 -0.0335 58 MgCO3,aq 0.65164E-12 -12.1860 0.65164E-12 -12.1860 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.42940E-13 -13.3671 0.39764E-13 -13.4005 0.92603E+00 -0.0334 60 MgCl+ 0.29636E-13 -13.5282 0.27444E-13 -13.5616 0.92603E+00 -0.0334 61 MgOH+ 0.97158E-10 -10.0125 0.89971E-10 -10.0459 0.92603E+00 -0.0334 63 MnO,aq 0.29165E-09 -9.5351 0.29165E-09 -9.5351 0.10000E+01 0.0000 64 MnOH+ 0.59064E-09 -9.2287 0.54695E-09 -9.2621 0.92603E+00 -0.0334 65 MnO2-2 0.30229E-13 -13.5196 0.23465E-13 -13.6296 0.77622E+00 -0.1100 66 HMnO2- 0.35664E-11 -11.4478 0.33017E-11 -11.4813 0.92578E+00 -0.0335 69 MnCl+ 0.98646E-13 -13.0059 0.91350E-13 -13.0393 0.92603E+00 -0.0334 70 MnSO4,aq 0.66397E-12 -12.1778 0.66397E-12 -12.1778 0.10000E+01 0.0000 71 NaCl,aq 0.78985E-07 -7.1025 0.78985E-07 -7.1025 0.10000E+01 0.0000 72 NaOH,aq 0.12486E-05 -5.9036 0.12486E-05 -5.9036 0.10000E+01 0.0000 74 OH- 0.97197E-03 -3.0123 0.89960E-03 -3.0460 0.92554E+00 -0.0336 79 HPO3-2 0.12592E-16 -16.8999 0.97742E-17 -17.0099 0.77622E+00 -0.1100 81 H2PO3- 0.13598E-19 -19.8665 0.12588E-19 -19.9000 0.92578E+00 -0.0335 82 H3PO4,aq 0.19910E-13 -13.7009 0.19910E-13 -13.7009 0.10000E+01 0.0000 83 H2PO4- 0.88310E-07 -7.0540 0.81766E-07 -7.0874 0.92590E+00 -0.0334 84 PO4-3 0.15072E-07 -7.8218 0.87671E-08 -8.0571 0.58167E+00 -0.2353 87 H2P2O7-2 0.67536E-15 -15.1705 0.52423E-15 -15.2805 0.77622E+00 -0.1100 88 HP2O7-3 0.28213E-12 -12.5496 0.16298E-12 -12.7879 0.57768E+00 -0.2383 89 P2O7-4 0.15800E-12 -12.8013 0.60623E-13 -13.2174 0.38368E+00 -0.4160 90 H2S,aq 0.51094E-16 -16.2916 0.51073E-16 -16.2918 0.99958E+00 -0.0002 97 SO3-2 0.15032E-14 -14.8230 0.11693E-14 -14.9321 0.77782E+00 -0.1091 98 HSO3- 0.50789E-16 -16.2942 0.47020E-16 -16.3277 0.92578E+00 -0.0335 99 HSO4- 0.13231E-10 -10.8784 0.12254E-10 -10.9117 0.92615E+00 -0.0333 Charge balance for all species = 0.4581E-13 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.6931576E-09 -.1968695E-02 -.1983948E+01 0.0000 2 H2O 0.1000000E+01 0.5550844E+02 0.9998103E+06 0.0000 3 Cl- 0.1379350E-03 0.1380140E-03 0.4892078E+01 5.2985 4 SO4-- 0.2549812E-04 0.2551208E-04 0.2450263E+01 13.6812 5 HCO3- 0.1123640E-04 0.1307378E-04 0.7975730E+00 4.2095 6 HS- 0.2779185E-13 -.2394835E-09 -.7918687E-05 -4.3973 7 Al+++ 0.1570131E-24 0.3454791E-04 0.9319766E+00 2.5345 8 H4SiO4 0.5299668E-03 0.1385484E-02 0.1331410E+03 -3.2758 9 Ca++ 0.1161523E-07 0.1308666E-07 0.5243869E-03 10.3393 10 Mg++ 0.1890239E-09 0.2903615E-09 0.7057922E-05 8.5505 11 Fe++ 0.1115095E-11 0.4388686E-08 0.2450482E-03 6.3214 12 K+ 0.4440118E-04 0.4444225E-04 0.1737449E+01 4.8063 13 Na+ 0.2016080E-02 0.2040666E-02 0.4690556E+02 6.4633 14 Mn++ 0.1498232E-09 0.1036470E-08 0.5693073E-04 8.4497 15 HPO4-- 0.8888013E-05 0.8991396E-05 0.8628205E+00 13.2235 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.2513934E-01 -.1968127E-02 -.2317122E-01 0.0000000E+00 2 H2O 0.5548921E+02 0.5549240E+02 -.3194284E-02 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.6760114E-04 0.2550471E-04 0.4209643E-04 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.4209667E-04 -.2394143E-09 -.4209643E-04 0.0000000E+00 7 Al+++ 0.4953067E-02 0.3453794E-04 0.4918529E-02 0.0000000E+00 8 H4SiO4 0.1581702E-01 0.1385084E-02 0.1443193E-01 0.0000000E+00 9 Ca++ 0.1761538E-02 0.1308288E-07 0.1761525E-02 0.0000000E+00 10 Mg++ 0.1205556E-02 0.2902777E-09 0.1205555E-02 0.0000000E+00 11 Fe++ 0.1083060E-02 0.4387418E-08 0.1083056E-02 0.0000000E+00 12 K+ 0.3225053E-03 0.4442942E-04 0.2780759E-03 0.0000000E+00 13 Na+ 0.2066786E-02 0.2040077E-02 0.2670912E-04 0.0000000E+00 14 Mn++ 0.2633733E-04 0.1036171E-08 0.2633629E-04 0.0000000E+00 15 HPO4-- 0.8988799E-05 0.8988799E-05 0.0000000E+00 0.0000000E+00 Chg. balance for solid moles: 0.4743E-19 Mass of aqueous solution: 0.999902E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 1.5190000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) clinochlore 0.2411E-03 -3.618 0.1340 -0.873 8.299 0.5098E-01 daphnite 0.1493E-03 -3.826 0.1065 -0.973 6.595 0.3227E-01 chlorite-Mn 0.5267E-05 -5.278 0.3734E-02 -2.428 0.2312 0.1190E-02 hematite 0.1684E-03 -3.774 0.2689E-01 -1.570 1.665 0.5097E-02 microcline 0.1551E-03 -3.809 0.4316E-01 -1.365 2.673 0.1686E-01 muscovite 0.1230E-03 -3.910 0.4899E-01 -1.310 3.034 0.1732E-01 paragonite 0.2671E-04 -4.573 0.1021E-01 -1.991 0.6321 0.3529E-02 stilbite 0.1762E-02 -2.754 1.241 0.094 76.87 0.5790 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity clinochlore 0.6094E+00 0.6094E+00 1.0000 -0.215 daphnite 0.3773E+00 0.3773E+00 1.0000 -0.423 chlorite-Mn 0.1331E-01 0.1331E-01 1.0000 -1.876 hematite 0.1000E+01 0.1000E+01 1.0000 0.000 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 muscovite 0.1000E+01 0.1000E+01 1.0000 0.000 paragonite 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 1.614885 g Volume = 0.706251 cm3 Porosity: 56.0680% V(tot) - V(min): 0.90135E+00 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 1.5190000 g log = 0.1816 Original solution: 1000.0103000 g Original solution / Rock added: 658.33 (Water/Rock Ratio), log = 2.8184 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0203 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.1000E+01 0.9860 0.1006E+01 0.1020E+01 CO2,gas 0.1487E-05 1.0071 0.1528E-05 0.1517E-05 CH4,gas 0.1871E-16 1.0125 0.1933E-16 0.1909E-16 H2,gas 0.5845E-06 1.0005 0.5967E-06 0.5963E-06 H2S,gas 0.1382E-14 0.9960 0.1404E-14 0.1410E-14 S2,gas 0.2037E-36 1.0000 0.2078E-36 0.2078E-36 CO,gas 0.2381E-15 1.0000 0.2429E-15 0.2429E-15 SO3,gas 0.3026E-38 1.0000 0.3088E-38 0.3088E-38 SO2,gas 0.7025E-22 1.0000 0.7168E-22 0.7168E-22 HCl,gas 0.2599E-16 1.0000 0.2652E-16 0.2652E-16 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 46 clinochlore 39.07 39.07 0.00 0.000 -0.36397E-10 47 daphnite 28.97 28.97 0.00 0.000 -0.90992E-10 48 chlorite-Mn 46.87 46.87 0.00 0.000 -0.48529E-10 90 hematite 12.57 12.57 0.00 0.000 -0.90992E-11 116 microcline -2.49 -2.49 0.00 0.000 -0.10616E-10 120 muscovite 2.58 2.58 0.00 0.000 0.60662E-11 121 paragonite 4.24 4.24 0.00 0.000 -0.10616E-10 163 stilbite -7.52 -7.52 0.00 0.000 -0.57629E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -14.18 -7.51 -2.505 0.12832E+05 -5.816 3 CH4,gas 4.54 -13.87 -18.41 -4.603 0.31439E+05 -16.714 4 H2,gas 8.00 0.08 -7.92 -4.528 0.13529E+05 -6.224 5 H2S,gas -6.23 -22.78 -16.55 -8.276 0.28261E+05 -14.853 6 S2,gas -7.34 -45.72 -38.38 -5.905 0.65535E+05 -36.682 7 CO,gas 3.21 -14.10 -17.31 -5.327 0.29562E+05 -15.615 8 SO3,gas 17.12 -23.09 -40.21 -10.052 0.68656E+05 -38.510 9 SO2,gas 0.83 -23.01 -23.84 -6.358 0.40712E+05 -22.145 10 HCl,gas 5.19 -13.09 -18.28 -9.138 0.31205E+05 -16.576 11 acmite 7.71 6.19 -1.51 -0.157 0.25865E+04 15 albite-high 0.69 -0.83 -1.52 -0.117 0.25997E+04 16 albite -0.38 -0.83 -0.45 -0.034 0.76090E+03 19 spessartine 24.46 20.59 -3.87 -0.193 0.66022E+04 20 analcite 3.32 2.45 -0.88 -0.097 0.14951E+04 21 andalusite 5.00 1.79 -3.21 -0.321 0.54782E+04 26 annite 20.12 16.48 -3.65 -0.203 0.62252E+04 27 phlogopite 27.06 23.16 -3.90 -0.217 0.66585E+04 29 anorthite 12.71 8.86 -3.85 -0.296 0.65799E+04 32 apatite-OH -18.15 -18.94 -0.79 -0.061 0.13439E+04 35 aragonite 0.97 -3.84 -4.80 -1.601 0.81998E+04 36 brucite 12.57 8.55 -4.02 -0.804 0.68608E+04 37 calcite 0.81 -3.84 -4.65 -1.549 0.79356E+04 38 carnegieite-low 9.02 5.72 -3.30 -0.472 0.56369E+04 39 carnegieite-high 10.09 5.72 -4.37 -0.624 0.74639E+04 40 carpholite-Mg 8.58 7.07 -1.51 -0.101 0.25854E+04 41 carpholite-Fe 6.71 4.84 -1.87 -0.125 0.31996E+04 42 celadonite 5.34 2.79 -2.55 -0.150 0.43598E+04 43 celadonite-Fe 3.88 0.56 -3.32 -0.195 0.56644E+04 44 chrysotile 23.89 19.10 -4.79 -0.399 0.81829E+04 50 chloritoid-Mg 13.20 10.34 -2.85 -0.190 0.48732E+04 51 chloritoid-Fe 9.17 8.11 -1.06 -0.071 0.18084E+04 52 chloritoid-Mn 11.40 10.24 -1.16 -0.077 0.19776E+04 54 coesite -2.38 -3.28 -0.90 -0.300 0.15362E+04 59 corundum 8.38 5.07 -3.31 -0.301 0.56589E+04 61 cristobalite -2.56 -3.28 -0.72 -0.238 0.12215E+04 63 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71234E+04 65 diaspore 2.87 2.53 -0.34 -0.057 0.57923E+03 67 diopside 16.18 12.34 -3.84 -0.384 0.65620E+04 68 hedenbergite 14.21 10.11 -4.10 -0.410 0.69992E+04 75 epidote 24.67 22.20 -2.47 -0.120 0.42116E+04 76 clinozoisite 22.81 18.45 -4.35 -0.198 0.74298E+04 77 epidote-Fe 29.84 25.95 -3.89 -0.202 0.66401E+04 78 fayalite 14.05 9.37 -4.68 -0.668 0.79889E+04 83 gibbsite 4.08 2.53 -1.54 -0.221 0.26378E+04 87 greenalite 16.14 12.41 -3.73 -0.311 0.63637E+04 91 heulandite -5.83 -7.52 -1.69 -0.077 0.28938E+04 95 jadeite 4.22 2.45 -1.77 -0.177 0.30206E+04 97 kalsilite 7.58 4.07 -3.52 -0.503 0.60084E+04 98 kaolinite -1.33 -1.48 -0.15 -0.014 0.25579E+03 99 kyanite 4.88 1.79 -3.08 -0.308 0.52641E+04 101 laumontite 2.88 2.31 -0.58 -0.039 0.98728E+03 102 lawsonite 9.62 8.86 -0.76 -0.051 0.12966E+04 103 leucite 4.12 0.79 -3.33 -0.333 0.56852E+04 105 lizardite 23.24 19.10 -4.14 -0.345 0.70756E+04 107 magnetite 20.09 18.89 -1.20 -0.098 0.20487E+04 108 minnesotaite 10.39 5.86 -4.53 -0.266 0.77298E+04 113 margarite 17.32 13.93 -3.40 -0.136 0.58020E+04 122 nepheline 8.34 5.72 -2.62 -0.374 0.44692E+04 134 phlogopite-Na 29.65 24.82 -4.82 -0.268 0.82382E+04 136 prehnite 19.37 15.92 -3.45 -0.203 0.58936E+04 137 prehnite-Fe 22.50 19.67 -2.83 -0.170 0.48304E+04 145 pyroxmangite 7.40 5.17 -2.22 -0.445 0.37987E+04 146 pyrophyllite -6.18 -8.03 -1.86 -0.116 0.31730E+04 147 quartz -2.99 -3.28 -0.29 -0.095 0.48888E+03 151 rhodochrosite -0.98 -5.73 -4.75 -1.583 0.81089E+04 152 rhodonite 7.45 5.17 -2.27 -0.454 0.38790E+04 153 sanidine -1.28 -2.49 -1.21 -0.093 0.20677E+04 156 sillimanite 5.26 1.79 -3.47 -0.347 0.59221E+04 164 stilpnomelane-Fe 13.02 12.87 -0.14 -0.004 0.24612E+03 165 stilpnomelane-Mg 27.44 24.02 -3.42 -0.102 0.58445E+04 168 sudoite 21.08 17.41 -3.67 -0.118 0.62592E+04 171 talc 16.49 12.55 -3.94 -0.232 0.67319E+04 174 tephroite 18.09 13.62 -4.46 -0.637 0.76191E+04 177 topaz-H 4.62 1.79 -2.83 -0.257 0.48242E+04 178 tridymite -2.63 -3.28 -0.65 -0.216 0.11089E+04 187 wairakite 3.95 2.31 -1.65 -0.097 0.28092E+04 188 walstromite 11.51 7.06 -4.45 -0.889 0.75909E+04 189 wollastonite 10.46 7.06 -3.40 -0.680 0.58013E+04 190 pseudo-wollastonite 11.00 7.06 -3.94 -0.787 0.67212E+04 191 zoisite 22.85 18.45 -4.39 -0.200 0.75038E+04 192 akaganeite 7.75 6.28 -1.47 -0.318 0.25125E+04 193 beidellite-Ca -1.65 -4.41 -2.77 -0.171 0.47214E+04 194 beidellite-H -2.33 -6.12 -3.79 -0.242 0.64721E+04 195 beidellite-K -1.52 -4.53 -3.01 -0.184 0.51402E+04 196 beidellite-Mg -1.79 -4.71 -2.92 -0.180 0.49792E+04 197 beidellite-Na -1.34 -3.98 -2.64 -0.162 0.45104E+04 199 chalcedony -2.80 -3.28 -0.47 -0.158 0.80817E+03 201 montmorillonite-Ca -2.29 -4.34 -2.05 -0.127 0.35039E+04 202 montmorillonite-K -2.24 -4.46 -2.23 -0.136 0.38008E+04 203 montmorillonite-Mg -2.48 -4.64 -2.16 -0.134 0.36849E+04 204 montmorillonite-Na -2.04 -3.92 -1.88 -0.115 0.32068E+04 205 nontronite-Ca 3.21 3.09 -0.13 -0.008 0.21857E+03 206 nontronite-H 2.53 1.38 -1.15 -0.077 0.19673E+04 207 nontronite-K 3.34 2.97 -0.37 -0.024 0.63872E+03 208 nontronite-Mg 3.07 2.79 -0.28 -0.018 0.48363E+03 209 nontronite-Na 3.52 3.51 -0.01 0.000 0.10694E+02 224 tobermorite 9.82 5.34 -4.49 -1.224 0.76600E+04 233 boehmite 4.41 2.53 -1.87 -0.312 0.31962E+04 235 ferrous-oxide 9.81 6.32 -3.49 -0.873 0.59595E+04 240 silica-amorphous -2.09 -3.28 -1.18 -0.395 0.20224E+04 242 an20ab80 2.02 1.11 -0.91 -0.070 0.15539E+04 243 an25ab75 2.65 1.59 -1.05 -0.081 0.17991E+04 244 an30ab70 3.28 2.08 -1.20 -0.093 0.20539E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 0.0400000 g Current total amount of reactant added: 1.5190000 g New total amount of reactant added: 1.5590000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.4570E-13 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 6 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 1.5590000 Water: Moles liquid = 0.5549E+02 kg liquid = 0.9997E+00 Moles total = 0.5549E+02 kg total = 0.9996E+00 Activity = 1.0000 Stoichiometric ionic strength = .1366636E-02 Osmotic coef. = 0.9788 True ionic strength = .2134992E-02 Chg. balance for total moles = 0.4570E-13 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.67553E-09 -9.1704 0.62562E-09 -9.2037 0.92611E+00 -0.0333 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13793E-03 -3.8603 0.12763E-03 -3.8940 0.92531E+00 -0.0337 4 SO4-- 0.25498E-04 -4.5935 0.19759E-04 -4.7042 0.77491E+00 -0.1107 5 HCO3- 0.11193E-04 -4.9511 0.10359E-04 -4.9847 0.92550E+00 -0.0336 6 HS- 0.29003E-13 -13.5376 0.26837E-13 -13.5713 0.92533E+00 -0.0337 7 Al+++ 0.14578E-24 -24.8363 0.83829E-25 -25.0766 0.57504E+00 -0.2403 8 H4SiO4 0.52225E-03 -3.2821 0.52225E-03 -3.2821 0.10000E+01 0.0000 9 Ca++ 0.12237E-07 -7.9123 0.94727E-08 -8.0235 0.77411E+00 -0.1112 10 Mg++ 0.18131E-09 -9.7416 0.14026E-09 -9.8531 0.77360E+00 -0.1115 11 Fe++ 0.10696E-11 -11.9708 0.82755E-12 -12.0822 0.77372E+00 -0.1114 12 K+ 0.45218E-04 -4.3447 0.41851E-04 -4.3783 0.92554E+00 -0.0336 13 Na+ 0.20532E-02 -2.6876 0.18998E-02 -2.7213 0.92529E+00 -0.0337 14 Mn++ 0.14371E-09 -9.8425 0.11120E-09 -9.9539 0.77382E+00 -0.1114 15 HPO4-- 0.91241E-05 -5.0398 0.70706E-05 -5.1505 0.77493E+00 -0.1107 16 HSiO3- 0.84238E-03 -3.0745 0.77947E-03 -3.1082 0.92531E+00 -0.0337 17 Ca(HSiO3)+ 0.18168E-09 -9.7407 0.16815E-09 -9.7743 0.92557E+00 -0.0336 18 Mg(HSiO3)+ 0.33478E-11 -11.4752 0.30986E-11 -11.5088 0.92557E+00 -0.0336 19 NaHSiO3,aq 0.23950E-04 -4.6207 0.23950E-04 -4.6207 0.10000E+01 0.0000 20 AlO+ 0.31480E-13 -13.5020 0.29137E-13 -13.5356 0.92557E+00 -0.0336 21 AlOH+2 0.11728E-18 -18.9308 0.90769E-19 -19.0421 0.77392E+00 -0.1113 22 HAlO2,aq 0.92750E-08 -8.0327 0.92750E-08 -8.0327 0.10000E+01 0.0000 23 AlO2- 0.35475E-04 -4.4501 0.32817E-04 -4.4839 0.92507E+00 -0.0338 24 CH4,aq 0.13673E-19 -19.8641 0.13667E-19 -19.8643 0.99958E+00 -0.0002 29 CO,aq 0.16091E-18 -18.7934 0.16091E-18 -18.7934 0.10000E+01 0.0000 30 CO2,aq 0.13854E-07 -7.8584 0.13848E-07 -7.8586 0.99958E+00 -0.0002 31 CO3-2 0.18669E-05 -5.7289 0.14463E-05 -5.8397 0.77468E+00 -0.1109 32 CaCO3,aq 0.17179E-09 -9.7650 0.17179E-09 -9.7650 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.27063E-11 -11.5676 0.25048E-11 -11.6012 0.92557E+00 -0.0336 34 CaCl+ 0.21139E-11 -11.6749 0.19566E-11 -11.7085 0.92557E+00 -0.0336 35 CaCl2,aq 0.59329E-16 -16.2267 0.59329E-16 -16.2267 0.10000E+01 0.0000 36 CaOH+ 0.11659E-08 -8.9333 0.10791E-08 -8.9669 0.92557E+00 -0.0336 37 CaSO4,aq 0.59435E-10 -10.2260 0.59435E-10 -10.2260 0.10000E+01 0.0000 38 HCl,aq 0.14632E-13 -13.8347 0.14632E-13 -13.8347 0.10000E+01 0.0000 43 FeCl+ 0.18063E-15 -15.7432 0.16718E-15 -15.7768 0.92557E+00 -0.0336 46 FeO,aq 0.82175E-10 -10.0853 0.82175E-10 -10.0853 0.10000E+01 0.0000 47 FeOH+ 0.46520E-10 -10.3324 0.43058E-10 -10.3660 0.92557E+00 -0.0336 48 HFeO2- 0.14853E-08 -8.8282 0.13743E-08 -8.8619 0.92531E+00 -0.0337 49 FeO+ 0.51593E-14 -14.2874 0.47753E-14 -14.3210 0.92557E+00 -0.0336 51 FeO2- 0.26980E-08 -8.5690 0.24965E-08 -8.6027 0.92531E+00 -0.0337 52 HFeO2,aq 0.19864E-09 -9.7019 0.19864E-09 -9.7019 0.10000E+01 0.0000 53 H2,aq 0.46273E-09 -9.3347 0.46254E-09 -9.3349 0.99958E+00 -0.0002 54 KCl,aq 0.96812E-10 -10.0141 0.96812E-10 -10.0141 0.10000E+01 0.0000 55 KHSO4,aq 0.14627E-17 -17.8348 0.14627E-17 -17.8348 0.10000E+01 0.0000 56 KOH,aq 0.28568E-07 -7.5441 0.28568E-07 -7.5441 0.10000E+01 0.0000 57 KSO4- 0.13868E-07 -7.8580 0.12832E-07 -7.8917 0.92531E+00 -0.0337 58 MgCO3,aq 0.63756E-12 -12.1955 0.63756E-12 -12.1955 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.40945E-13 -13.3878 0.37897E-13 -13.4214 0.92557E+00 -0.0336 60 MgCl+ 0.28369E-13 -13.5472 0.26257E-13 -13.5808 0.92557E+00 -0.0336 61 MgOH+ 0.95525E-10 -10.0199 0.88415E-10 -10.0535 0.92557E+00 -0.0336 63 MnO,aq 0.29423E-09 -9.5313 0.29423E-09 -9.5313 0.10000E+01 0.0000 64 MnOH+ 0.58071E-09 -9.2360 0.53749E-09 -9.2696 0.92557E+00 -0.0336 65 MnO2-2 0.32204E-13 -13.4921 0.24948E-13 -13.6030 0.77468E+00 -0.1109 66 HMnO2- 0.36954E-11 -11.4323 0.34194E-11 -11.4660 0.92531E+00 -0.0337 69 MnCl+ 0.94428E-13 -13.0249 0.87400E-13 -13.0585 0.92557E+00 -0.0336 70 MnSO4,aq 0.63432E-12 -12.1977 0.63432E-12 -12.1977 0.10000E+01 0.0000 71 NaCl,aq 0.80357E-07 -7.0950 0.80357E-07 -7.0950 0.10000E+01 0.0000 72 NaOH,aq 0.13047E-05 -5.8845 0.13047E-05 -5.8845 0.10000E+01 0.0000 74 OH- 0.99833E-03 -3.0007 0.92352E-03 -3.0346 0.92507E+00 -0.0338 79 HPO3-2 0.13156E-16 -16.8809 0.10192E-16 -16.9918 0.77468E+00 -0.1109 81 H2PO3- 0.13818E-19 -19.8595 0.12786E-19 -19.8933 0.92531E+00 -0.0337 82 H3PO4,aq 0.19355E-13 -13.7132 0.19355E-13 -13.7132 0.10000E+01 0.0000 83 H2PO4- 0.88176E-07 -7.0546 0.81601E-07 -7.0883 0.92544E+00 -0.0337 84 PO4-3 0.15922E-07 -7.7980 0.92209E-08 -8.0352 0.57912E+00 -0.2372 87 H2P2O7-2 0.67398E-15 -15.1714 0.52212E-15 -15.2822 0.77468E+00 -0.1109 88 HP2O7-3 0.28977E-12 -12.5379 0.16664E-12 -12.7782 0.57509E+00 -0.2403 89 P2O7-4 0.16717E-12 -12.7768 0.63633E-13 -13.1963 0.38065E+00 -0.4195 90 H2S,aq 0.51913E-16 -16.2847 0.51891E-16 -16.2849 0.99958E+00 -0.0002 97 SO3-2 0.15299E-14 -14.8153 0.11876E-14 -14.9253 0.77630E+00 -0.1100 98 HSO3- 0.50277E-16 -16.2986 0.46522E-16 -16.3323 0.92531E+00 -0.0337 99 HSO4- 0.12869E-10 -10.8904 0.11913E-10 -10.9240 0.92569E+00 -0.0335 Charge balance for all species = 0.4750E-13 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.6755328E-09 -.2009716E-02 -.2025283E+01 0.0000 2 H2O 0.1000000E+01 0.5550845E+02 0.9998091E+06 0.0000 3 Cl- 0.1379345E-03 0.1380150E-03 0.4892103E+01 5.3096 4 SO4-- 0.2549807E-04 0.2551225E-04 0.2450276E+01 13.7031 5 HCO3- 0.1119289E-04 0.1307386E-04 0.7975770E+00 4.2190 6 HS- 0.2900255E-13 -.2463660E-09 -.8146249E-05 -4.3676 7 Al+++ 0.1457798E-24 0.3548447E-04 0.9572400E+00 2.5345 8 H4SiO4 0.5222536E-03 0.1388586E-02 0.1334388E+03 -3.2821 9 Ca++ 0.1223694E-07 0.1382056E-07 0.5537937E-03 10.3839 10 Mg++ 0.1813076E-09 0.2808875E-09 0.6827623E-05 8.5543 11 Fe++ 0.1069572E-11 0.4511651E-08 0.2519137E-03 6.3252 12 K+ 0.4521840E-04 0.4526093E-04 0.1769452E+01 4.8254 13 Na+ 0.2053196E-02 0.2078532E-02 0.4777584E+02 6.4824 14 Mn++ 0.1437067E-09 0.1023103E-08 0.5619640E-04 8.4535 15 HPO4-- 0.9124129E-05 0.9228228E-05 0.8855457E+00 13.2568 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.2580169E-01 -.2009122E-02 -.2379256E-01 0.0000000E+00 2 H2O 0.5548871E+02 0.5549206E+02 -.3347887E-02 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.6870967E-04 0.2550472E-04 0.4320496E-04 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.4320520E-04 -.2462932E-09 -.4320496E-04 0.0000000E+00 7 Al+++ 0.5083496E-02 0.3547399E-04 0.5048022E-02 0.0000000E+00 8 H4SiO4 0.1623353E-01 0.1388176E-02 0.1484535E-01 0.0000000E+00 9 Ca++ 0.1807543E-02 0.1381647E-07 0.1807530E-02 0.0000000E+00 10 Mg++ 0.1237302E-02 0.2808045E-09 0.1237301E-02 0.0000000E+00 11 Fe++ 0.1111580E-02 0.4510318E-08 0.1111576E-02 0.0000000E+00 12 K+ 0.3309979E-03 0.4524756E-04 0.2857503E-03 0.0000000E+00 13 Na+ 0.2116996E-02 0.2077918E-02 0.3907803E-04 0.0000000E+00 14 Mn++ 0.2703087E-04 0.1022800E-08 0.2702985E-04 0.0000000E+00 15 HPO4-- 0.9225502E-05 0.9225502E-05 0.0000000E+00 0.0000000E+00 Chg. balance for solid moles: -.2412E-17 Mass of aqueous solution: 0.999897E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 1.5590000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) clinochlore 0.2475E-03 -3.606 0.1375 -0.862 8.288 0.5232E-01 daphnite 0.1532E-03 -3.815 0.1093 -0.961 6.586 0.3312E-01 chlorite-Mn 0.5406E-05 -5.267 0.3833E-02 -2.416 0.2309 0.1221E-02 hematite 0.1728E-03 -3.762 0.2760E-01 -1.559 1.663 0.5231E-02 microcline 0.1768E-03 -3.752 0.4921E-01 -1.308 2.965 0.1922E-01 muscovite 0.1089E-03 -3.963 0.4339E-01 -1.363 2.614 0.1534E-01 paragonite 0.3908E-04 -4.408 0.1494E-01 -1.826 0.8999 0.5163E-02 stilbite 0.1808E-02 -2.743 1.274 0.105 76.75 0.5941 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity clinochlore 0.6094E+00 0.6094E+00 1.0000 -0.215 daphnite 0.3773E+00 0.3773E+00 1.0000 -0.423 chlorite-Mn 0.1331E-01 0.1331E-01 1.0000 -1.876 hematite 0.1000E+01 0.1000E+01 1.0000 0.000 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 muscovite 0.1000E+01 0.1000E+01 1.0000 0.000 paragonite 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 1.659621 g Volume = 0.725747 cm3 Porosity: 55.3001% V(tot) - V(min): 0.89785E+00 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 1.5590000 g log = 0.1928 Original solution: 1000.0103000 g Original solution / Rock added: 641.44 (Water/Rock Ratio), log = 2.8072 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0203 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.1000E+01 0.9860 0.1006E+01 0.1020E+01 CO2,gas 0.1442E-05 1.0071 0.1482E-05 0.1471E-05 CH4,gas 0.1947E-16 1.0125 0.2012E-16 0.1987E-16 H2,gas 0.5949E-06 1.0005 0.6073E-06 0.6069E-06 H2S,gas 0.1404E-14 0.9960 0.1426E-14 0.1432E-14 S2,gas 0.2030E-36 1.0000 0.2071E-36 0.2071E-36 CO,gas 0.2350E-15 1.0000 0.2398E-15 0.2398E-15 SO3,gas 0.2866E-38 1.0000 0.2924E-38 0.2924E-38 SO2,gas 0.6771E-22 1.0000 0.6908E-22 0.6908E-22 HCl,gas 0.2531E-16 1.0000 0.2582E-16 0.2582E-16 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 46 clinochlore 39.07 39.07 0.00 0.000 0.00000E+00 47 daphnite 28.97 28.97 0.00 0.000 -0.36397E-10 48 chlorite-Mn 46.87 46.87 0.00 0.000 -0.24265E-10 90 hematite 12.57 12.57 0.00 0.000 0.90992E-11 116 microcline -2.49 -2.49 0.00 0.000 -0.10616E-10 120 muscovite 2.58 2.58 0.00 0.000 0.60662E-11 121 paragonite 4.24 4.24 0.00 0.000 -0.10616E-10 163 stilbite -7.52 -7.52 0.00 0.000 0.15165E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -14.19 -7.53 -2.509 0.12854E+05 -5.829 3 CH4,gas 4.54 -13.85 -18.40 -4.599 0.31410E+05 -16.696 4 H2,gas 8.00 0.08 -7.92 -4.523 0.13516E+05 -6.217 5 H2S,gas -6.23 -22.77 -16.54 -8.272 0.28250E+05 -14.846 6 S2,gas -7.34 -45.72 -38.38 -5.905 0.65538E+05 -36.684 7 CO,gas 3.21 -14.10 -17.32 -5.329 0.29572E+05 -15.620 8 SO3,gas 17.12 -23.11 -40.23 -10.058 0.68697E+05 -38.534 9 SO2,gas 0.83 -23.03 -23.86 -6.363 0.40740E+05 -22.161 10 HCl,gas 5.19 -13.10 -18.29 -9.144 0.31225E+05 -16.588 11 acmite 7.71 6.20 -1.51 -0.157 0.25757E+04 15 albite-high 0.69 -0.83 -1.52 -0.117 0.25997E+04 16 albite -0.38 -0.83 -0.45 -0.034 0.76090E+03 19 spessartine 24.46 20.58 -3.87 -0.194 0.66152E+04 20 analcite 3.32 2.45 -0.87 -0.097 0.14842E+04 21 andalusite 5.00 1.79 -3.21 -0.321 0.54890E+04 26 annite 20.12 16.49 -3.63 -0.202 0.62056E+04 27 phlogopite 27.06 23.18 -3.89 -0.216 0.66389E+04 29 anorthite 12.71 8.89 -3.82 -0.294 0.65256E+04 32 apatite-OH -18.15 -18.75 -0.60 -0.046 0.10262E+04 35 aragonite 0.97 -3.80 -4.77 -1.590 0.81464E+04 36 brucite 12.57 8.55 -4.01 -0.803 0.68542E+04 37 calcite 0.81 -3.80 -4.62 -1.539 0.78822E+04 38 carnegieite-low 9.02 5.73 -3.29 -0.470 0.56151E+04 39 carnegieite-high 10.09 5.73 -4.36 -0.623 0.74421E+04 40 carpholite-Mg 8.58 7.06 -1.52 -0.102 0.26006E+04 41 carpholite-Fe 6.71 4.83 -1.88 -0.126 0.32148E+04 42 celadonite 5.34 2.79 -2.56 -0.150 0.43641E+04 43 celadonite-Fe 3.88 0.56 -3.32 -0.195 0.56687E+04 44 chrysotile 23.89 19.10 -4.79 -0.399 0.81851E+04 50 chloritoid-Mg 13.20 10.34 -2.86 -0.190 0.48775E+04 51 chloritoid-Fe 9.17 8.11 -1.06 -0.071 0.18127E+04 52 chloritoid-Mn 11.40 10.24 -1.16 -0.077 0.19820E+04 54 coesite -2.38 -3.28 -0.91 -0.302 0.15471E+04 59 corundum 8.38 5.07 -3.31 -0.301 0.56589E+04 61 cristobalite -2.56 -3.28 -0.72 -0.241 0.12324E+04 63 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71234E+04 65 diaspore 2.87 2.53 -0.34 -0.057 0.57923E+03 67 diopside 16.18 12.37 -3.81 -0.381 0.65011E+04 68 hedenbergite 14.21 10.14 -4.06 -0.406 0.69383E+04 75 epidote 24.67 22.27 -2.40 -0.116 0.40920E+04 76 clinozoisite 22.81 18.52 -4.28 -0.195 0.73102E+04 77 epidote-Fe 29.84 26.02 -3.82 -0.198 0.65205E+04 78 fayalite 14.05 9.37 -4.68 -0.668 0.79867E+04 83 gibbsite 4.08 2.53 -1.54 -0.221 0.26378E+04 87 greenalite 16.14 12.41 -3.73 -0.311 0.63658E+04 91 heulandite -5.83 -7.52 -1.69 -0.077 0.28938E+04 95 jadeite 4.22 2.45 -1.76 -0.176 0.30097E+04 97 kalsilite 7.58 4.08 -3.51 -0.501 0.59867E+04 98 kaolinite -1.33 -1.50 -0.16 -0.015 0.27754E+03 99 kyanite 4.88 1.79 -3.09 -0.309 0.52749E+04 101 laumontite 2.88 2.32 -0.56 -0.037 0.95466E+03 102 lawsonite 9.62 8.89 -0.73 -0.049 0.12422E+04 103 leucite 4.12 0.80 -3.32 -0.332 0.56743E+04 105 lizardite 23.24 19.10 -4.15 -0.345 0.70777E+04 107 magnetite 20.09 18.89 -1.20 -0.098 0.20422E+04 108 minnesotaite 10.39 5.85 -4.54 -0.267 0.77537E+04 113 margarite 17.32 13.96 -3.37 -0.135 0.57476E+04 122 nepheline 8.34 5.73 -2.60 -0.372 0.44475E+04 134 phlogopite-Na 29.65 24.83 -4.81 -0.267 0.82186E+04 136 prehnite 19.37 15.99 -3.38 -0.199 0.57740E+04 137 prehnite-Fe 22.50 19.74 -2.76 -0.166 0.47108E+04 145 pyroxmangite 7.40 5.17 -2.23 -0.445 0.38031E+04 146 pyrophyllite -6.18 -8.06 -1.88 -0.118 0.32165E+04 147 quartz -2.99 -3.28 -0.29 -0.098 0.49975E+03 151 rhodochrosite -0.98 -5.73 -4.76 -1.586 0.81251E+04 152 rhodonite 7.45 5.17 -2.27 -0.455 0.38833E+04 153 sanidine -1.28 -2.49 -1.21 -0.093 0.20677E+04 156 sillimanite 5.26 1.79 -3.47 -0.347 0.59330E+04 164 stilpnomelane-Fe 13.02 12.85 -0.17 -0.005 0.28417E+03 165 stilpnomelane-Mg 27.44 24.00 -3.45 -0.103 0.58825E+04 168 sudoite 21.08 17.40 -3.68 -0.119 0.62788E+04 171 talc 16.49 12.53 -3.96 -0.233 0.67558E+04 174 tephroite 18.09 13.62 -4.46 -0.637 0.76169E+04 177 topaz-H 4.62 1.79 -2.83 -0.257 0.48350E+04 178 tridymite -2.63 -3.28 -0.66 -0.219 0.11197E+04 187 wairakite 3.95 2.32 -1.63 -0.096 0.27766E+04 188 walstromite 11.51 7.10 -4.41 -0.881 0.75257E+04 189 wollastonite 10.46 7.10 -3.36 -0.672 0.57361E+04 190 pseudo-wollastonite 11.00 7.10 -3.90 -0.780 0.66559E+04 191 zoisite 22.85 18.52 -4.32 -0.197 0.73842E+04 192 akaganeite 7.75 6.28 -1.47 -0.318 0.25125E+04 193 beidellite-Ca -1.65 -4.43 -2.78 -0.172 0.47487E+04 194 beidellite-H -2.33 -6.14 -3.81 -0.243 0.65120E+04 195 beidellite-K -1.52 -4.55 -3.03 -0.185 0.51693E+04 196 beidellite-Mg -1.79 -4.73 -2.94 -0.182 0.50180E+04 197 beidellite-Na -1.34 -4.00 -2.66 -0.163 0.45396E+04 199 chalcedony -2.80 -3.28 -0.48 -0.160 0.81905E+03 201 montmorillonite-Ca -2.29 -4.36 -2.07 -0.128 0.35327E+04 202 montmorillonite-K -2.24 -4.48 -2.24 -0.137 0.38314E+04 203 montmorillonite-Mg -2.48 -4.66 -2.18 -0.135 0.37251E+04 204 montmorillonite-Na -2.04 -3.93 -1.90 -0.116 0.32374E+04 205 nontronite-Ca 3.21 3.07 -0.14 -0.009 0.24592E+03 206 nontronite-H 2.53 1.36 -1.18 -0.079 0.20072E+04 207 nontronite-K 3.34 2.95 -0.39 -0.025 0.66786E+03 208 nontronite-Mg 3.07 2.77 -0.31 -0.020 0.52245E+03 209 nontronite-Na 3.52 3.50 -0.02 -0.001 0.39831E+02 224 tobermorite 9.82 5.37 -4.46 -1.216 0.76075E+04 233 boehmite 4.41 2.53 -1.87 -0.312 0.31962E+04 235 ferrous-oxide 9.81 6.33 -3.49 -0.872 0.59529E+04 240 silica-amorphous -2.09 -3.28 -1.19 -0.397 0.20332E+04 242 an20ab80 2.02 1.11 -0.90 -0.070 0.15430E+04 243 an25ab75 2.65 1.60 -1.05 -0.080 0.17855E+04 244 an30ab70 3.28 2.09 -1.19 -0.092 0.20376E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 0.0400000 g Current total amount of reactant added: 1.5590000 g New total amount of reactant added: 1.5990000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.4570E-13 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 6 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 1.5990000 Water: Moles liquid = 0.5549E+02 kg liquid = 0.9997E+00 Moles total = 0.5549E+02 kg total = 0.9996E+00 Activity = 1.0000 Stoichiometric ionic strength = .1390718E-02 Osmotic coef. = 0.9786 True ionic strength = .2173255E-02 Chg. balance for total moles = 0.4570E-13 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.65871E-09 -9.1813 0.60975E-09 -9.2148 0.92567E+00 -0.0335 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13793E-03 -3.8603 0.12757E-03 -3.8943 0.92485E+00 -0.0339 4 SO4-- 0.25498E-04 -4.5935 0.19720E-04 -4.7051 0.77339E+00 -0.1116 5 HCO3- 0.11149E-04 -4.9527 0.10314E-04 -4.9866 0.92504E+00 -0.0338 6 HS- 0.30242E-13 -13.5194 0.27970E-13 -13.5533 0.92487E+00 -0.0339 7 Al+++ 0.13557E-24 -24.8678 0.77610E-25 -25.1101 0.57248E+00 -0.2422 8 H4SiO4 0.51480E-03 -3.2884 0.51480E-03 -3.2884 0.10000E+01 0.0000 9 Ca++ 0.12880E-07 -7.8901 0.99509E-08 -8.0021 0.77257E+00 -0.1121 10 Mg++ 0.17406E-09 -9.7593 0.13439E-09 -9.8716 0.77206E+00 -0.1124 11 Fe++ 0.10268E-11 -11.9885 0.79291E-12 -12.1008 0.77218E+00 -0.1123 12 K+ 0.46037E-04 -4.3369 0.42588E-04 -4.3707 0.92508E+00 -0.0338 13 Na+ 0.20904E-02 -2.6798 0.19332E-02 -2.7137 0.92483E+00 -0.0339 14 Mn++ 0.13797E-09 -9.8602 0.10655E-09 -9.9725 0.77227E+00 -0.1122 15 HPO4-- 0.93602E-05 -5.0287 0.72393E-05 -5.1403 0.77341E+00 -0.1116 16 HSiO3- 0.85240E-03 -3.0694 0.78834E-03 -3.1033 0.92485E+00 -0.0339 17 Ca(HSiO3)+ 0.19312E-09 -9.7142 0.17865E-09 -9.7480 0.92511E+00 -0.0338 18 Mg(HSiO3)+ 0.32457E-11 -11.4887 0.30027E-11 -11.5225 0.92511E+00 -0.0338 19 NaHSiO3,aq 0.24649E-04 -4.6082 0.24649E-04 -4.6082 0.10000E+01 0.0000 20 AlO+ 0.30697E-13 -13.5129 0.28398E-13 -13.5467 0.92511E+00 -0.0338 21 AlOH+2 0.11163E-18 -18.9522 0.86222E-19 -19.0644 0.77238E+00 -0.1122 22 HAlO2,aq 0.92750E-08 -8.0327 0.92750E-08 -8.0327 0.10000E+01 0.0000 23 AlO2- 0.36417E-04 -4.4387 0.33671E-04 -4.4727 0.92460E+00 -0.0340 24 CH4,aq 0.14216E-19 -19.8472 0.14210E-19 -19.8474 0.99957E+00 -0.0002 29 CO,aq 0.15885E-18 -18.7990 0.15885E-18 -18.7990 0.10000E+01 0.0000 30 CO2,aq 0.13443E-07 -7.8715 0.13438E-07 -7.8717 0.99957E+00 -0.0002 31 CO3-2 0.19109E-05 -5.7188 0.14774E-05 -5.8305 0.77315E+00 -0.1117 32 CaCO3,aq 0.18434E-09 -9.7344 0.18434E-09 -9.7344 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.28318E-11 -11.5479 0.26198E-11 -11.5817 0.92511E+00 -0.0338 34 CaCl+ 0.22206E-11 -11.6535 0.20543E-11 -11.6873 0.92511E+00 -0.0338 35 CaCl2,aq 0.62261E-16 -16.2058 0.62261E-16 -16.2058 0.10000E+01 0.0000 36 CaOH+ 0.12573E-08 -8.9006 0.11631E-08 -8.9344 0.92511E+00 -0.0338 37 CaSO4,aq 0.62313E-10 -10.2054 0.62313E-10 -10.2054 0.10000E+01 0.0000 38 HCl,aq 0.14254E-13 -13.8461 0.14254E-13 -13.8461 0.10000E+01 0.0000 43 FeCl+ 0.17306E-15 -15.7618 0.16010E-15 -15.7956 0.92511E+00 -0.0338 46 FeO,aq 0.82887E-10 -10.0815 0.82887E-10 -10.0815 0.10000E+01 0.0000 47 FeOH+ 0.45755E-10 -10.3396 0.42329E-10 -10.3734 0.92511E+00 -0.0338 48 HFeO2- 0.15379E-08 -8.8131 0.14223E-08 -8.8470 0.92485E+00 -0.0339 49 FeO+ 0.50309E-14 -14.2984 0.46542E-14 -14.3322 0.92511E+00 -0.0338 51 FeO2- 0.27696E-08 -8.5576 0.25615E-08 -8.5915 0.92485E+00 -0.0339 52 HFeO2,aq 0.19864E-09 -9.7019 0.19864E-09 -9.7019 0.10000E+01 0.0000 53 H2,aq 0.47079E-09 -9.3272 0.47059E-09 -9.3274 0.99957E+00 -0.0002 54 KCl,aq 0.98465E-10 -10.0067 0.98465E-10 -10.0067 0.10000E+01 0.0000 55 KHSO4,aq 0.14478E-17 -17.8393 0.14478E-17 -17.8393 0.10000E+01 0.0000 56 KOH,aq 0.29827E-07 -7.5254 0.29827E-07 -7.5254 0.10000E+01 0.0000 57 KSO4- 0.14091E-07 -7.8511 0.13032E-07 -7.8850 0.92485E+00 -0.0339 58 MgCO3,aq 0.62403E-12 -12.2048 0.62403E-12 -12.2048 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.39078E-13 -13.4081 0.36152E-13 -13.4419 0.92511E+00 -0.0338 60 MgCl+ 0.27181E-13 -13.5657 0.25145E-13 -13.5995 0.92511E+00 -0.0338 61 MgOH+ 0.93955E-10 -10.0271 0.86919E-10 -10.0609 0.92511E+00 -0.0338 63 MnO,aq 0.29678E-09 -9.5276 0.29678E-09 -9.5276 0.10000E+01 0.0000 64 MnOH+ 0.57117E-09 -9.2432 0.52839E-09 -9.2770 0.92511E+00 -0.0338 65 MnO2-2 0.34264E-13 -13.4652 0.26491E-13 -13.5769 0.77315E+00 -0.1117 66 HMnO2- 0.38264E-11 -11.4172 0.35388E-11 -11.4511 0.92485E+00 -0.0339 69 MnCl+ 0.90474E-13 -13.0435 0.83699E-13 -13.0773 0.92511E+00 -0.0338 70 MnSO4,aq 0.60657E-12 -12.2171 0.60657E-12 -12.2171 0.10000E+01 0.0000 71 NaCl,aq 0.81730E-07 -7.0876 0.81730E-07 -7.0876 0.10000E+01 0.0000 72 NaOH,aq 0.13622E-05 -5.8658 0.13622E-05 -5.8658 0.10000E+01 0.0000 74 OH- 0.10248E-02 -2.9893 0.94756E-03 -3.0234 0.92460E+00 -0.0340 79 HPO3-2 0.13731E-16 -16.8623 0.10616E-16 -16.9740 0.77315E+00 -0.1117 81 H2PO3- 0.14036E-19 -19.8528 0.12981E-19 -19.8867 0.92485E+00 -0.0339 82 H3PO4,aq 0.18824E-13 -13.7253 0.18824E-13 -13.7253 0.10000E+01 0.0000 83 H2PO4- 0.88033E-07 -7.0554 0.81429E-07 -7.0892 0.92497E+00 -0.0339 84 PO4-3 0.16799E-07 -7.7747 0.96867E-08 -8.0138 0.57661E+00 -0.2391 87 H2P2O7-2 0.67246E-15 -15.1723 0.51991E-15 -15.2841 0.77315E+00 -0.1117 88 HP2O7-3 0.29738E-12 -12.5267 0.17026E-12 -12.7689 0.57252E+00 -0.2422 89 P2O7-4 0.17663E-12 -12.7529 0.66705E-13 -13.1758 0.37766E+00 -0.4229 90 H2S,aq 0.52732E-16 -16.2779 0.52709E-16 -16.2781 0.99957E+00 -0.0002 97 SO3-2 0.15565E-14 -14.8079 0.12059E-14 -14.9187 0.77479E+00 -0.1108 98 HSO3- 0.49781E-16 -16.3029 0.46040E-16 -16.3369 0.92485E+00 -0.0339 99 HSO4- 0.12524E-10 -10.9022 0.11588E-10 -10.9360 0.92523E+00 -0.0337 Charge balance for all species = 0.4746E-13 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.6587149E-09 -.2050805E-02 -.2066688E+01 0.0000 2 H2O 0.1000000E+01 0.5550847E+02 0.9998078E+06 0.0000 3 Cl- 0.1379340E-03 0.1380159E-03 0.4892127E+01 5.3206 4 SO4-- 0.2549801E-04 0.2551243E-04 0.2450289E+01 13.7246 5 HCO3- 0.1114939E-04 0.1307395E-04 0.7975810E+00 4.2283 6 HS- 0.3024183E-13 -.2533023E-09 -.8375588E-05 -4.3385 7 Al+++ 0.1355680E-24 0.3642625E-04 0.9826443E+00 2.5345 8 H4SiO4 0.5147986E-03 0.1391845E-02 0.1337518E+03 -3.2884 9 Ca++ 0.1288028E-07 0.1458236E-07 0.5843185E-03 10.4276 10 Mg++ 0.1740647E-09 0.2719558E-09 0.6610506E-05 8.5581 11 Fe++ 0.1026842E-11 0.4635801E-08 0.2588454E-03 6.3289 12 K+ 0.4603658E-04 0.4608060E-04 0.1801494E+01 4.8441 13 Na+ 0.2090356E-02 0.2116449E-02 0.4864731E+02 6.5011 14 Mn++ 0.1379655E-09 0.1010467E-08 0.5550229E-04 8.4572 15 HPO4-- 0.9360230E-05 0.9465064E-05 0.9082712E+00 13.2894 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.2646403E-01 -.2050186E-02 -.2441384E-01 0.0000000E+00 2 H2O 0.5548821E+02 0.5549171E+02 -.3501185E-02 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.6981821E-04 0.2550472E-04 0.4431349E-04 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.4431374E-04 -.2532258E-09 -.4431349E-04 0.0000000E+00 7 Al+++ 0.5213926E-02 0.3641525E-04 0.5177511E-02 0.0000000E+00 8 H4SiO4 0.1665004E-01 0.1391425E-02 0.1525862E-01 0.0000000E+00 9 Ca++ 0.1853549E-02 0.1457796E-07 0.1853535E-02 0.0000000E+00 10 Mg++ 0.1269048E-02 0.2718736E-09 0.1269047E-02 0.0000000E+00 11 Fe++ 0.1140101E-02 0.4634401E-08 0.1140096E-02 0.0000000E+00 12 K+ 0.3394904E-03 0.4606668E-04 0.2934238E-03 0.0000000E+00 13 Na+ 0.2167206E-02 0.2115810E-02 0.5139549E-04 0.0000000E+00 14 Mn++ 0.2772441E-04 0.1010162E-08 0.2772340E-04 0.0000000E+00 15 HPO4-- 0.9462205E-05 0.9462205E-05 0.0000000E+00 0.0000000E+00 Chg. balance for solid moles: -.4161E-17 Mass of aqueous solution: 0.999892E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 1.5990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) clinochlore 0.2538E-03 -3.595 0.1411 -0.851 8.277 0.5366E-01 daphnite 0.1571E-03 -3.804 0.1121 -0.950 6.578 0.3397E-01 chlorite-Mn 0.5545E-05 -5.256 0.3931E-02 -2.405 0.2306 0.1253E-02 hematite 0.1773E-03 -3.751 0.2831E-01 -1.548 1.661 0.5365E-02 microcline 0.1985E-03 -3.702 0.5524E-01 -1.258 3.241 0.2158E-01 muscovite 0.9494E-04 -4.023 0.3782E-01 -1.422 2.219 0.1337E-01 paragonite 0.5140E-04 -4.289 0.1964E-01 -1.707 1.153 0.6790E-02 stilbite 0.1854E-02 -2.732 1.306 0.116 76.64 0.6092 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity clinochlore 0.6094E+00 0.6094E+00 1.0000 -0.215 daphnite 0.3773E+00 0.3773E+00 1.0000 -0.423 chlorite-Mn 0.1331E-01 0.1331E-01 1.0000 -1.876 hematite 0.1000E+01 0.1000E+01 1.0000 0.000 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 muscovite 0.1000E+01 0.1000E+01 1.0000 0.000 paragonite 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 1.704347 g Volume = 0.745238 cm3 Porosity: 54.5475% V(tot) - V(min): 0.89436E+00 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 1.5990000 g log = 0.2038 Original solution: 1000.0103000 g Original solution / Rock added: 625.40 (Water/Rock Ratio), log = 2.7962 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0203 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.1000E+01 0.9860 0.1006E+01 0.1020E+01 CO2,gas 0.1399E-05 1.0071 0.1438E-05 0.1428E-05 CH4,gas 0.2025E-16 1.0125 0.2092E-16 0.2066E-16 H2,gas 0.6052E-06 1.0005 0.6178E-06 0.6175E-06 H2S,gas 0.1426E-14 0.9960 0.1449E-14 0.1455E-14 S2,gas 0.2023E-36 1.0000 0.2064E-36 0.2064E-36 CO,gas 0.2320E-15 1.0000 0.2367E-15 0.2367E-15 SO3,gas 0.2717E-38 1.0000 0.2772E-38 0.2772E-38 SO2,gas 0.6531E-22 1.0000 0.6663E-22 0.6663E-22 HCl,gas 0.2465E-16 1.0000 0.2515E-16 0.2515E-16 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 46 clinochlore 39.07 39.07 0.00 0.000 0.36397E-10 47 daphnite 28.97 28.97 0.00 0.000 0.42463E-10 48 chlorite-Mn 46.87 46.87 0.00 0.000 0.00000E+00 90 hematite 12.57 12.57 0.00 0.000 0.27298E-10 116 microcline -2.49 -2.49 0.00 0.000 0.15165E-11 120 muscovite 2.58 2.58 0.00 0.000 0.60662E-11 121 paragonite 4.24 4.24 0.00 0.000 0.13649E-10 163 stilbite -7.52 -7.52 0.00 0.000 0.15165E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -14.20 -7.54 -2.514 0.12877E+05 -5.842 3 CH4,gas 4.54 -13.83 -18.38 -4.595 0.31381E+05 -16.680 4 H2,gas 8.00 0.09 -7.91 -4.519 0.13503E+05 -6.209 5 H2S,gas -6.23 -22.77 -16.54 -8.269 0.28238E+05 -14.839 6 S2,gas -7.34 -45.72 -38.38 -5.905 0.65540E+05 -36.685 7 CO,gas 3.21 -14.11 -17.32 -5.331 0.29582E+05 -15.626 8 SO3,gas 17.12 -23.13 -40.26 -10.064 0.68736E+05 -38.557 9 SO2,gas 0.83 -23.04 -23.88 -6.367 0.40766E+05 -22.176 10 HCl,gas 5.19 -13.11 -18.30 -9.149 0.31244E+05 -16.599 11 acmite 7.71 6.21 -1.50 -0.156 0.25650E+04 15 albite-high 0.69 -0.83 -1.52 -0.117 0.25997E+04 16 albite -0.38 -0.83 -0.45 -0.034 0.76090E+03 19 spessartine 24.46 20.58 -3.88 -0.194 0.66280E+04 20 analcite 3.32 2.46 -0.86 -0.096 0.14735E+04 21 andalusite 5.00 1.78 -3.22 -0.322 0.54997E+04 26 annite 20.12 16.50 -3.62 -0.201 0.61864E+04 27 phlogopite 27.06 23.19 -3.88 -0.215 0.66197E+04 29 anorthite 12.71 8.92 -3.79 -0.292 0.64723E+04 32 apatite-OH -18.15 -18.57 -0.42 -0.032 0.71494E+03 35 aragonite 0.97 -3.77 -4.74 -1.580 0.80941E+04 36 brucite 12.57 8.56 -4.01 -0.802 0.68478E+04 37 calcite 0.81 -3.77 -4.59 -1.529 0.78299E+04 38 carnegieite-low 9.02 5.75 -3.28 -0.468 0.55938E+04 39 carnegieite-high 10.09 5.75 -4.35 -0.621 0.74208E+04 40 carpholite-Mg 8.58 7.05 -1.53 -0.102 0.26156E+04 41 carpholite-Fe 6.71 4.82 -1.89 -0.126 0.32297E+04 42 celadonite 5.34 2.78 -2.56 -0.150 0.43684E+04 43 celadonite-Fe 3.88 0.55 -3.32 -0.195 0.56730E+04 44 chrysotile 23.89 19.10 -4.79 -0.400 0.81872E+04 50 chloritoid-Mg 13.20 10.34 -2.86 -0.191 0.48818E+04 51 chloritoid-Fe 9.17 8.11 -1.06 -0.071 0.18170E+04 52 chloritoid-Mn 11.40 10.24 -1.16 -0.078 0.19863E+04 54 coesite -2.38 -3.29 -0.91 -0.304 0.15577E+04 59 corundum 8.38 5.07 -3.31 -0.301 0.56589E+04 61 cristobalite -2.56 -3.29 -0.73 -0.243 0.12431E+04 63 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71234E+04 65 diaspore 2.87 2.53 -0.34 -0.057 0.57923E+03 67 diopside 16.18 12.41 -3.77 -0.377 0.64414E+04 68 hedenbergite 14.21 10.18 -4.03 -0.403 0.68786E+04 75 epidote 24.67 22.34 -2.33 -0.113 0.39748E+04 76 clinozoisite 22.81 18.59 -4.21 -0.191 0.71929E+04 77 epidote-Fe 29.84 26.09 -3.75 -0.195 0.64032E+04 78 fayalite 14.05 9.37 -4.68 -0.668 0.79846E+04 83 gibbsite 4.08 2.53 -1.54 -0.221 0.26378E+04 87 greenalite 16.14 12.41 -3.73 -0.311 0.63680E+04 91 heulandite -5.83 -7.52 -1.69 -0.077 0.28938E+04 95 jadeite 4.22 2.46 -1.76 -0.176 0.29990E+04 97 kalsilite 7.58 4.09 -3.49 -0.499 0.59654E+04 98 kaolinite -1.33 -1.51 -0.18 -0.016 0.29886E+03 99 kyanite 4.88 1.78 -3.10 -0.310 0.52856E+04 101 laumontite 2.88 2.34 -0.54 -0.036 0.92268E+03 102 lawsonite 9.62 8.92 -0.70 -0.046 0.11889E+04 103 leucite 4.12 0.80 -3.32 -0.332 0.56637E+04 105 lizardite 23.24 19.10 -4.15 -0.346 0.70799E+04 107 magnetite 20.09 18.90 -1.19 -0.097 0.20358E+04 108 minnesotaite 10.39 5.83 -4.55 -0.268 0.77772E+04 113 margarite 17.32 13.99 -3.33 -0.133 0.56943E+04 122 nepheline 8.34 5.75 -2.59 -0.370 0.44262E+04 134 phlogopite-Na 29.65 24.84 -4.80 -0.267 0.81994E+04 136 prehnite 19.37 16.06 -3.31 -0.195 0.56567E+04 137 prehnite-Fe 22.50 19.81 -2.69 -0.162 0.45936E+04 145 pyroxmangite 7.40 5.17 -2.23 -0.446 0.38073E+04 146 pyrophyllite -6.18 -8.08 -1.91 -0.119 0.32591E+04 147 quartz -2.99 -3.29 -0.30 -0.100 0.51041E+03 151 rhodochrosite -0.98 -5.74 -4.77 -1.589 0.81410E+04 152 rhodonite 7.45 5.17 -2.28 -0.455 0.38876E+04 153 sanidine -1.28 -2.49 -1.21 -0.093 0.20677E+04 156 sillimanite 5.26 1.78 -3.48 -0.348 0.59436E+04 164 stilpnomelane-Fe 13.02 12.83 -0.19 -0.006 0.32148E+03 165 stilpnomelane-Mg 27.44 23.97 -3.47 -0.103 0.59199E+04 168 sudoite 21.08 17.39 -3.69 -0.119 0.62980E+04 171 talc 16.49 12.52 -3.97 -0.234 0.67793E+04 174 tephroite 18.09 13.63 -4.46 -0.637 0.76148E+04 177 topaz-H 4.62 1.78 -2.84 -0.258 0.48457E+04 178 tridymite -2.63 -3.29 -0.66 -0.221 0.11304E+04 187 wairakite 3.95 2.34 -1.61 -0.095 0.27446E+04 188 walstromite 11.51 7.14 -4.37 -0.874 0.74617E+04 189 wollastonite 10.46 7.14 -3.32 -0.664 0.56721E+04 190 pseudo-wollastonite 11.00 7.14 -3.86 -0.772 0.65920E+04 191 zoisite 22.85 18.59 -4.26 -0.193 0.72670E+04 192 akaganeite 7.75 6.28 -1.47 -0.318 0.25125E+04 193 beidellite-Ca -1.65 -4.44 -2.80 -0.173 0.47755E+04 194 beidellite-H -2.33 -6.16 -3.84 -0.245 0.65512E+04 195 beidellite-K -1.52 -4.56 -3.04 -0.186 0.51979E+04 196 beidellite-Mg -1.79 -4.75 -2.96 -0.183 0.50561E+04 197 beidellite-Na -1.34 -4.02 -2.68 -0.164 0.45682E+04 199 chalcedony -2.80 -3.29 -0.49 -0.162 0.82971E+03 201 montmorillonite-Ca -2.29 -4.38 -2.09 -0.129 0.35609E+04 202 montmorillonite-K -2.24 -4.50 -2.26 -0.138 0.38614E+04 203 montmorillonite-Mg -2.48 -4.68 -2.20 -0.136 0.37646E+04 204 montmorillonite-Na -2.04 -3.95 -1.91 -0.117 0.32674E+04 205 nontronite-Ca 3.21 3.05 -0.16 -0.010 0.27273E+03 206 nontronite-H 2.53 1.33 -1.20 -0.080 0.20463E+04 207 nontronite-K 3.34 2.93 -0.41 -0.026 0.69643E+03 208 nontronite-Mg 3.07 2.75 -0.33 -0.021 0.56052E+03 209 nontronite-Na 3.52 3.48 -0.04 -0.003 0.68404E+02 224 tobermorite 9.82 5.40 -4.43 -1.207 0.75560E+04 233 boehmite 4.41 2.53 -1.87 -0.312 0.31962E+04 235 ferrous-oxide 9.81 6.33 -3.48 -0.871 0.59466E+04 240 silica-amorphous -2.09 -3.29 -1.20 -0.399 0.20439E+04 242 an20ab80 2.02 1.12 -0.90 -0.069 0.15323E+04 243 an25ab75 2.65 1.61 -1.04 -0.080 0.17722E+04 244 an30ab70 3.28 2.10 -1.18 -0.091 0.20216E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 0.0400000 g Current total amount of reactant added: 1.5990000 g New total amount of reactant added: 1.6390000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.4570E-13 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 6 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 1.6390000 Water: Moles liquid = 0.5549E+02 kg liquid = 0.9997E+00 Moles total = 0.5549E+02 kg total = 0.9996E+00 Activity = 1.0000 Stoichiometric ionic strength = .1414848E-02 Osmotic coef. = 0.9785 True ionic strength = .2211559E-02 Chg. balance for total moles = 0.4570E-13 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.64265E-09 -9.1920 0.59460E-09 -9.2258 0.92522E+00 -0.0338 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13793E-03 -3.8603 0.12750E-03 -3.8945 0.92439E+00 -0.0341 4 SO4-- 0.25498E-04 -4.5935 0.19681E-04 -4.7059 0.77188E+00 -0.1125 5 HCO3- 0.11106E-04 -4.9544 0.10268E-04 -4.9885 0.92459E+00 -0.0341 6 HS- 0.31510E-13 -13.5016 0.29128E-13 -13.5357 0.92441E+00 -0.0341 7 Al+++ 0.12627E-24 -24.8987 0.71966E-25 -25.1429 0.56995E+00 -0.2442 8 H4SiO4 0.50759E-03 -3.2945 0.50759E-03 -3.2945 0.10000E+01 0.0000 9 Ca++ 0.13546E-07 -7.8682 0.10444E-07 -7.9811 0.77105E+00 -0.1129 10 Mg++ 0.16726E-09 -9.7766 0.12888E-09 -9.8898 0.77053E+00 -0.1132 11 Fe++ 0.98668E-12 -12.0058 0.76039E-12 -12.1190 0.77065E+00 -0.1131 12 K+ 0.46856E-04 -4.3292 0.43324E-04 -4.3633 0.92462E+00 -0.0340 13 Na+ 0.21276E-02 -2.6721 0.19667E-02 -2.7063 0.92437E+00 -0.0342 14 Mn++ 0.13257E-09 -9.8776 0.10218E-09 -9.9906 0.77075E+00 -0.1131 15 HPO4-- 0.95963E-05 -5.0179 0.74074E-05 -5.1303 0.77190E+00 -0.1124 16 HSiO3- 0.86231E-03 -3.0643 0.79711E-03 -3.0985 0.92439E+00 -0.0341 17 Ca(HSiO3)+ 0.20505E-09 -9.6881 0.18960E-09 -9.7222 0.92465E+00 -0.0340 18 Mg(HSiO3)+ 0.31488E-11 -11.5019 0.29116E-11 -11.5359 0.92465E+00 -0.0340 19 NaHSiO3,aq 0.25354E-04 -4.5959 0.25354E-04 -4.5959 0.10000E+01 0.0000 20 AlO+ 0.29949E-13 -13.5236 0.27692E-13 -13.5576 0.92465E+00 -0.0340 21 AlOH+2 0.10636E-18 -18.9732 0.81989E-19 -19.0862 0.77086E+00 -0.1130 22 HAlO2,aq 0.92750E-08 -8.0327 0.92750E-08 -8.0327 0.10000E+01 0.0000 23 AlO2- 0.37364E-04 -4.4275 0.34529E-04 -4.4618 0.92414E+00 -0.0343 24 CH4,aq 0.14769E-19 -19.8307 0.14762E-19 -19.8309 0.99956E+00 -0.0002 29 CO,aq 0.15686E-18 -18.8045 0.15686E-18 -18.8045 0.10000E+01 0.0000 30 CO2,aq 0.13052E-07 -7.8843 0.13046E-07 -7.8845 0.99956E+00 -0.0002 31 CO3-2 0.19548E-05 -5.7089 0.15084E-05 -5.8215 0.77164E+00 -0.1126 32 CaCO3,aq 0.19754E-09 -9.7043 0.19754E-09 -9.7043 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.29607E-11 -11.5286 0.27376E-11 -11.5626 0.92465E+00 -0.0340 34 CaCl+ 0.23307E-11 -11.6325 0.21551E-11 -11.6665 0.92465E+00 -0.0340 35 CaCl2,aq 0.65283E-16 -16.1852 0.65283E-16 -16.1852 0.10000E+01 0.0000 36 CaOH+ 0.13539E-08 -8.8684 0.12519E-08 -8.9024 0.92465E+00 -0.0340 37 CaSO4,aq 0.65274E-10 -10.1853 0.65274E-10 -10.1853 0.10000E+01 0.0000 38 HCl,aq 0.13892E-13 -13.8572 0.13892E-13 -13.8572 0.10000E+01 0.0000 43 FeCl+ 0.16597E-15 -15.7800 0.15346E-15 -15.8140 0.92465E+00 -0.0340 46 FeO,aq 0.83591E-10 -10.0778 0.83591E-10 -10.0778 0.10000E+01 0.0000 47 FeOH+ 0.45020E-10 -10.3466 0.41628E-10 -10.3806 0.92465E+00 -0.0340 48 HFeO2- 0.15913E-08 -8.7983 0.14710E-08 -8.8324 0.92439E+00 -0.0341 49 FeO+ 0.49083E-14 -14.3091 0.45385E-14 -14.3431 0.92465E+00 -0.0340 51 FeO2- 0.28416E-08 -8.5464 0.26267E-08 -8.5806 0.92439E+00 -0.0341 52 HFeO2,aq 0.19864E-09 -9.7019 0.19864E-09 -9.7019 0.10000E+01 0.0000 53 H2,aq 0.47883E-09 -9.3198 0.47862E-09 -9.3200 0.99956E+00 -0.0002 54 KCl,aq 0.10012E-09 -9.9995 0.10012E-09 -9.9995 0.10000E+01 0.0000 55 KHSO4,aq 0.14335E-17 -17.8436 0.14335E-17 -17.8436 0.10000E+01 0.0000 56 KOH,aq 0.31117E-07 -7.5070 0.31117E-07 -7.5070 0.10000E+01 0.0000 57 KSO4- 0.14314E-07 -7.8442 0.13231E-07 -7.8784 0.92439E+00 -0.0341 58 MgCO3,aq 0.61100E-12 -12.2140 0.61100E-12 -12.2140 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.37330E-13 -13.4279 0.34517E-13 -13.4620 0.92465E+00 -0.0340 60 MgCl+ 0.26066E-13 -13.5839 0.24102E-13 -13.6179 0.92465E+00 -0.0340 61 MgOH+ 0.92444E-10 -10.0341 0.85479E-10 -10.0681 0.92465E+00 -0.0340 63 MnO,aq 0.29930E-09 -9.5239 0.29930E-09 -9.5239 0.10000E+01 0.0000 64 MnOH+ 0.56198E-09 -9.2503 0.51964E-09 -9.2843 0.92465E+00 -0.0340 65 MnO2-2 0.36410E-13 -13.4388 0.28095E-13 -13.5514 0.77164E+00 -0.1126 66 HMnO2- 0.39592E-11 -11.4024 0.36599E-11 -11.4365 0.92439E+00 -0.0341 69 MnCl+ 0.86764E-13 -13.0617 0.80226E-13 -13.0957 0.92465E+00 -0.0340 70 MnSO4,aq 0.58056E-12 -12.2362 0.58056E-12 -12.2362 0.10000E+01 0.0000 71 NaCl,aq 0.83101E-07 -7.0804 0.83101E-07 -7.0804 0.10000E+01 0.0000 72 NaOH,aq 0.14211E-05 -5.8474 0.14211E-05 -5.8474 0.10000E+01 0.0000 74 OH- 0.10515E-02 -2.9782 0.97171E-03 -3.0125 0.92414E+00 -0.0343 79 HPO3-2 0.14318E-16 -16.8441 0.11048E-16 -16.9567 0.77164E+00 -0.1126 81 H2PO3- 0.14251E-19 -19.8462 0.13173E-19 -19.8803 0.92439E+00 -0.0341 82 H3PO4,aq 0.18316E-13 -13.7372 0.18316E-13 -13.7372 0.10000E+01 0.0000 83 H2PO4- 0.87882E-07 -7.0561 0.81249E-07 -7.0902 0.92452E+00 -0.0341 84 PO4-3 0.17704E-07 -7.7519 0.10164E-07 -7.9929 0.57413E+00 -0.2410 87 H2P2O7-2 0.67080E-15 -15.1734 0.51762E-15 -15.2860 0.77164E+00 -0.1126 88 HP2O7-3 0.30496E-12 -12.5158 0.17382E-12 -12.7599 0.57000E+00 -0.2441 89 P2O7-4 0.18637E-12 -12.7296 0.69839E-13 -13.1559 0.37473E+00 -0.4263 90 H2S,aq 0.53551E-16 -16.2712 0.53527E-16 -16.2714 0.99956E+00 -0.0002 97 SO3-2 0.15830E-14 -14.8005 0.12241E-14 -14.9122 0.77330E+00 -0.1117 98 HSO3- 0.49300E-16 -16.3072 0.45572E-16 -16.3413 0.92439E+00 -0.0341 99 HSO4- 0.12195E-10 -10.9138 0.11278E-10 -10.9478 0.92478E+00 -0.0340 Charge balance for all species = 0.4742E-13 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.6426533E-09 -.2091959E-02 -.2108157E+01 0.0000 2 H2O 0.1000000E+01 0.5550849E+02 0.9998066E+06 0.0000 3 Cl- 0.1379336E-03 0.1380168E-03 0.4892152E+01 5.3313 4 SO4-- 0.2549795E-04 0.2551260E-04 0.2450302E+01 13.7456 5 HCO3- 0.1110593E-04 0.1307403E-04 0.7975850E+00 4.2373 6 HS- 0.3150970E-13 -.2602907E-09 -.8606650E-05 -4.3099 7 Al+++ 0.1262670E-24 0.3737307E-04 0.1008184E+01 2.5345 8 H4SiO4 0.5075891E-03 0.1395251E-02 0.1340789E+03 -3.2945 9 Ca++ 0.1354556E-07 0.1537260E-07 0.6159827E-03 10.4704 10 Mg++ 0.1672579E-09 0.2635250E-09 0.6405568E-05 8.5617 11 Fe++ 0.9866843E-12 0.4761111E-08 0.2658418E-03 6.3326 12 K+ 0.4685565E-04 0.4690118E-04 0.1833571E+01 4.8625 13 Na+ 0.2127557E-02 0.2154415E-02 0.4951989E+02 6.5195 14 Mn++ 0.1325699E-09 0.9985142E-09 0.5484565E-04 8.4609 15 HPO4-- 0.9596315E-05 0.9701902E-05 0.9309968E+00 13.3212 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.2712637E-01 -.2091313E-02 -.2503505E-01 0.0000000E+00 2 H2O 0.5548770E+02 0.5549136E+02 -.3654200E-02 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.7092675E-04 0.2550473E-04 0.4542202E-04 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.4542228E-04 -.2602103E-09 -.4542202E-04 0.0000000E+00 7 Al+++ 0.5344356E-02 0.3736154E-04 0.5306994E-02 0.0000000E+00 8 H4SiO4 0.1706655E-01 0.1394820E-02 0.1567173E-01 0.0000000E+00 9 Ca++ 0.1899555E-02 0.1536786E-07 0.1899540E-02 0.0000000E+00 10 Mg++ 0.1300794E-02 0.2634437E-09 0.1300793E-02 0.0000000E+00 11 Fe++ 0.1168621E-02 0.4759641E-08 0.1168616E-02 0.0000000E+00 12 K+ 0.3479830E-03 0.4688671E-04 0.3010963E-03 0.0000000E+00 13 Na+ 0.2217415E-02 0.2153750E-02 0.6366501E-04 0.0000000E+00 14 Mn++ 0.2841796E-04 0.9982061E-09 0.2841696E-04 0.0000000E+00 15 HPO4-- 0.9698908E-05 0.9698908E-05 0.0000000E+00 0.0000000E+00 Chg. balance for solid moles: -.5218E-18 Mass of aqueous solution: 0.999887E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 1.6390000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) clinochlore 0.2602E-03 -3.585 0.1446 -0.840 8.268 0.5500E-01 daphnite 0.1610E-03 -3.793 0.1149 -0.940 6.570 0.3482E-01 chlorite-Mn 0.5683E-05 -5.245 0.4029E-02 -2.395 0.2304 0.1284E-02 hematite 0.1817E-03 -3.741 0.2902E-01 -1.537 1.659 0.5500E-02 microcline 0.2201E-03 -3.657 0.6126E-01 -1.213 3.502 0.2393E-01 muscovite 0.8102E-04 -4.091 0.3227E-01 -1.491 1.845 0.1141E-01 paragonite 0.6367E-04 -4.196 0.2433E-01 -1.614 1.391 0.8411E-02 stilbite 0.1900E-02 -2.721 1.339 0.127 76.53 0.6244 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity clinochlore 0.6094E+00 0.6094E+00 1.0000 -0.215 daphnite 0.3773E+00 0.3773E+00 1.0000 -0.423 chlorite-Mn 0.1331E-01 0.1331E-01 1.0000 -1.876 hematite 0.1000E+01 0.1000E+01 1.0000 0.000 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 muscovite 0.1000E+01 0.1000E+01 1.0000 0.000 paragonite 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 1.749062 g Volume = 0.764726 cm3 Porosity: 53.8098% V(tot) - V(min): 0.89087E+00 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 1.6390000 g log = 0.2146 Original solution: 1000.0103000 g Original solution / Rock added: 610.13 (Water/Rock Ratio), log = 2.7854 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0203 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.1000E+01 0.9860 0.1006E+01 0.1020E+01 CO2,gas 0.1358E-05 1.0071 0.1396E-05 0.1386E-05 CH4,gas 0.2103E-16 1.0125 0.2173E-16 0.2146E-16 H2,gas 0.6155E-06 1.0005 0.6284E-06 0.6280E-06 H2S,gas 0.1448E-14 0.9960 0.1471E-14 0.1477E-14 S2,gas 0.2017E-36 1.0000 0.2058E-36 0.2058E-36 CO,gas 0.2291E-15 1.0000 0.2337E-15 0.2337E-15 SO3,gas 0.2579E-38 1.0000 0.2631E-38 0.2631E-38 SO2,gas 0.6304E-22 1.0000 0.6432E-22 0.6432E-22 HCl,gas 0.2403E-16 1.0000 0.2451E-16 0.2451E-16 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 46 clinochlore 39.07 39.07 0.00 0.000 -0.24265E-10 47 daphnite 28.97 28.97 0.00 0.000 -0.30331E-10 48 chlorite-Mn 46.87 46.87 0.00 0.000 -0.24265E-10 90 hematite 12.57 12.57 0.00 0.000 -0.90992E-11 116 microcline -2.49 -2.49 0.00 0.000 -0.10616E-10 120 muscovite 2.58 2.58 0.00 0.000 -0.42463E-10 121 paragonite 4.24 4.24 0.00 0.000 -0.10616E-10 163 stilbite -7.52 -7.52 0.00 0.000 -0.90992E-11 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -14.21 -7.55 -2.518 0.12899E+05 -5.855 3 CH4,gas 4.54 -13.82 -18.36 -4.590 0.31353E+05 -16.663 4 H2,gas 8.00 0.10 -7.90 -4.515 0.13490E+05 -6.202 5 H2S,gas -6.23 -22.76 -16.53 -8.266 0.28227E+05 -14.832 6 S2,gas -7.34 -45.72 -38.39 -5.905 0.65542E+05 -36.687 7 CO,gas 3.21 -14.12 -17.33 -5.332 0.29591E+05 -15.631 8 SO3,gas 17.12 -23.16 -40.28 -10.070 0.68775E+05 -38.580 9 SO2,gas 0.83 -23.06 -23.89 -6.371 0.40793E+05 -22.192 10 HCl,gas 5.19 -13.12 -18.31 -9.155 0.31263E+05 -16.611 11 acmite 7.71 6.21 -1.50 -0.155 0.25545E+04 15 albite-high 0.69 -0.83 -1.52 -0.117 0.25997E+04 16 albite -0.38 -0.83 -0.45 -0.034 0.76090E+03 19 spessartine 24.46 20.57 -3.89 -0.194 0.66406E+04 20 analcite 3.32 2.46 -0.86 -0.095 0.14631E+04 21 andalusite 5.00 1.77 -3.23 -0.323 0.55102E+04 22 andradite 39.01 34.09 -4.91 -0.255 0.83917E+04 26 annite 20.12 16.51 -3.61 -0.201 0.61676E+04 27 phlogopite 27.06 23.20 -3.87 -0.215 0.66009E+04 29 anorthite 12.71 8.95 -3.76 -0.289 0.64200E+04 32 apatite-OH -18.15 -18.39 -0.24 -0.018 0.40980E+03 35 aragonite 0.97 -3.74 -4.71 -1.570 0.80428E+04 36 brucite 12.57 8.56 -4.01 -0.801 0.68416E+04 37 calcite 0.81 -3.74 -4.56 -1.519 0.77786E+04 38 carnegieite-low 9.02 5.76 -3.26 -0.466 0.55729E+04 39 carnegieite-high 10.09 5.76 -4.33 -0.619 0.73999E+04 40 carpholite-Mg 8.58 7.04 -1.54 -0.103 0.26302E+04 41 carpholite-Fe 6.71 4.81 -1.90 -0.127 0.32444E+04 42 celadonite 5.34 2.78 -2.56 -0.151 0.43726E+04 43 celadonite-Fe 3.88 0.55 -3.32 -0.196 0.56772E+04 44 chrysotile 23.89 19.10 -4.80 -0.400 0.81893E+04 50 chloritoid-Mg 13.20 10.34 -2.86 -0.191 0.48860E+04 51 chloritoid-Fe 9.17 8.11 -1.07 -0.071 0.18212E+04 52 chloritoid-Mn 11.40 10.24 -1.17 -0.078 0.19904E+04 54 coesite -2.38 -3.29 -0.92 -0.306 0.15682E+04 59 corundum 8.38 5.07 -3.31 -0.301 0.56589E+04 61 cristobalite -2.56 -3.29 -0.73 -0.245 0.12535E+04 63 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71234E+04 65 diaspore 2.87 2.53 -0.34 -0.057 0.57923E+03 67 diopside 16.18 12.44 -3.74 -0.374 0.63828E+04 68 hedenbergite 14.21 10.21 -3.99 -0.399 0.68200E+04 75 epidote 24.67 22.41 -2.26 -0.110 0.38597E+04 76 clinozoisite 22.81 18.66 -4.15 -0.188 0.70779E+04 77 epidote-Fe 29.84 26.16 -3.68 -0.191 0.62882E+04 78 fayalite 14.05 9.37 -4.68 -0.668 0.79825E+04 83 gibbsite 4.08 2.53 -1.54 -0.221 0.26378E+04 87 greenalite 16.14 12.41 -3.73 -0.311 0.63701E+04 91 heulandite -5.83 -7.52 -1.69 -0.077 0.28938E+04 95 jadeite 4.22 2.46 -1.75 -0.175 0.29886E+04 97 kalsilite 7.58 4.10 -3.48 -0.497 0.59444E+04 98 kaolinite -1.33 -1.52 -0.19 -0.017 0.31978E+03 99 kyanite 4.88 1.77 -3.10 -0.310 0.52961E+04 101 laumontite 2.88 2.36 -0.52 -0.035 0.89130E+03 102 lawsonite 9.62 8.95 -0.67 -0.044 0.11366E+04 103 leucite 4.12 0.81 -3.31 -0.331 0.56532E+04 105 lizardite 23.24 19.10 -4.15 -0.346 0.70819E+04 107 magnetite 20.09 18.90 -1.19 -0.097 0.20295E+04 108 minnesotaite 10.39 5.82 -4.57 -0.269 0.78002E+04 113 margarite 17.32 14.02 -3.30 -0.132 0.56420E+04 122 nepheline 8.34 5.76 -2.58 -0.369 0.44052E+04 134 phlogopite-Na 29.65 24.86 -4.79 -0.266 0.81806E+04 136 prehnite 19.37 16.13 -3.25 -0.191 0.55417E+04 137 prehnite-Fe 22.50 19.87 -2.62 -0.158 0.44785E+04 145 pyroxmangite 7.40 5.17 -2.23 -0.446 0.38115E+04 146 pyrophyllite -6.18 -8.11 -1.93 -0.121 0.33009E+04 147 quartz -2.99 -3.29 -0.31 -0.102 0.52087E+03 151 rhodochrosite -0.98 -5.75 -4.78 -1.592 0.81567E+04 152 rhodonite 7.45 5.17 -2.28 -0.456 0.38918E+04 153 sanidine -1.28 -2.49 -1.21 -0.093 0.20677E+04 156 sillimanite 5.26 1.77 -3.49 -0.349 0.59541E+04 164 stilpnomelane-Fe 13.02 12.81 -0.21 -0.006 0.35809E+03 165 stilpnomelane-Mg 27.44 23.95 -3.49 -0.104 0.59565E+04 168 sudoite 21.08 17.38 -3.70 -0.119 0.63168E+04 171 talc 16.49 12.51 -3.98 -0.234 0.68023E+04 174 tephroite 18.09 13.63 -4.46 -0.637 0.76127E+04 177 topaz-H 4.62 1.77 -2.84 -0.259 0.48561E+04 178 tridymite -2.63 -3.29 -0.67 -0.223 0.11408E+04 187 wairakite 3.95 2.36 -1.59 -0.093 0.27133E+04 188 walstromite 11.51 7.18 -4.33 -0.867 0.73990E+04 189 wollastonite 10.46 7.18 -3.29 -0.657 0.56094E+04 190 pseudo-wollastonite 11.00 7.18 -3.82 -0.765 0.65292E+04 191 zoisite 22.85 18.66 -4.19 -0.190 0.71519E+04 192 akaganeite 7.75 6.28 -1.47 -0.318 0.25125E+04 193 beidellite-Ca -1.65 -4.46 -2.81 -0.174 0.48018E+04 194 beidellite-H -2.33 -6.19 -3.86 -0.246 0.65895E+04 195 beidellite-K -1.52 -4.58 -3.06 -0.187 0.52259E+04 196 beidellite-Mg -1.79 -4.77 -2.98 -0.185 0.50934E+04 197 beidellite-Na -1.34 -4.03 -2.69 -0.165 0.45962E+04 199 chalcedony -2.80 -3.29 -0.49 -0.164 0.84017E+03 201 montmorillonite-Ca -2.29 -4.39 -2.10 -0.130 0.35886E+04 202 montmorillonite-K -2.24 -4.52 -2.28 -0.140 0.38908E+04 203 montmorillonite-Mg -2.48 -4.71 -2.23 -0.138 0.38033E+04 204 montmorillonite-Na -2.04 -3.97 -1.93 -0.118 0.32968E+04 205 nontronite-Ca 3.21 3.04 -0.18 -0.011 0.29903E+03 206 nontronite-H 2.53 1.31 -1.22 -0.082 0.20847E+04 207 nontronite-K 3.34 2.92 -0.42 -0.027 0.72446E+03 208 nontronite-Mg 3.07 2.72 -0.35 -0.023 0.59787E+03 209 nontronite-Na 3.52 3.46 -0.06 -0.004 0.96432E+02 224 tobermorite 9.82 5.43 -4.40 -1.199 0.75055E+04 233 boehmite 4.41 2.53 -1.87 -0.312 0.31962E+04 235 ferrous-oxide 9.81 6.33 -3.48 -0.870 0.59403E+04 240 silica-amorphous -2.09 -3.29 -1.20 -0.401 0.20543E+04 242 an20ab80 2.02 1.13 -0.89 -0.069 0.15219E+04 243 an25ab75 2.65 1.62 -1.03 -0.079 0.17591E+04 244 an30ab70 3.28 2.10 -1.17 -0.090 0.20059E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 0.0400000 g Current total amount of reactant added: 1.6390000 g New total amount of reactant added: 1.6790000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.4570E-13 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 6 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 1.6790000 Water: Moles liquid = 0.5549E+02 kg liquid = 0.9997E+00 Moles total = 0.5549E+02 kg total = 0.9996E+00 Activity = 1.0000 Stoichiometric ionic strength = .1439023E-02 Osmotic coef. = 0.9783 True ionic strength = .2249902E-02 Chg. balance for total moles = 0.4570E-13 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.62730E-09 -9.2025 0.58011E-09 -9.2365 0.92478E+00 -0.0340 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13793E-03 -3.8603 0.12744E-03 -3.8947 0.92394E+00 -0.0344 4 SO4-- 0.25498E-04 -4.5935 0.19643E-04 -4.7068 0.77039E+00 -0.1133 5 HCO3- 0.11063E-04 -4.9561 0.10223E-04 -4.9904 0.92414E+00 -0.0343 6 HS- 0.32806E-13 -13.4840 0.30311E-13 -13.5184 0.92396E+00 -0.0343 7 Al+++ 0.11778E-24 -24.9289 0.66835E-25 -25.1750 0.56745E+00 -0.2461 8 H4SiO4 0.50061E-03 -3.3005 0.50061E-03 -3.3005 0.10000E+01 0.0000 9 Ca++ 0.14233E-07 -7.8467 0.10953E-07 -7.9605 0.76955E+00 -0.1138 10 Mg++ 0.16085E-09 -9.7936 0.12370E-09 -9.9076 0.76902E+00 -0.1141 11 Fe++ 0.94890E-12 -12.0228 0.72984E-12 -12.1368 0.76914E+00 -0.1140 12 K+ 0.47676E-04 -4.3217 0.44061E-04 -4.3560 0.92417E+00 -0.0342 13 Na+ 0.21648E-02 -2.6646 0.20001E-02 -2.6990 0.92392E+00 -0.0344 14 Mn++ 0.12749E-09 -9.8945 0.98073E-10 -10.0085 0.76924E+00 -0.1139 15 HPO4-- 0.98324E-05 -5.0073 0.75749E-05 -5.1206 0.77040E+00 -0.1133 16 HSiO3- 0.87211E-03 -3.0594 0.80578E-03 -3.0938 0.92394E+00 -0.0344 17 Ca(HSiO3)+ 0.21748E-09 -9.6626 0.20099E-09 -9.6968 0.92420E+00 -0.0342 18 Mg(HSiO3)+ 0.30567E-11 -11.5148 0.28250E-11 -11.5490 0.92420E+00 -0.0342 19 NaHSiO3,aq 0.26066E-04 -4.5839 0.26066E-04 -4.5839 0.10000E+01 0.0000 20 AlO+ 0.29234E-13 -13.5341 0.27018E-13 -13.5683 0.92420E+00 -0.0342 21 AlOH+2 0.10144E-18 -18.9938 0.78044E-19 -19.1077 0.76935E+00 -0.1139 22 HAlO2,aq 0.92750E-08 -8.0327 0.92750E-08 -8.0327 0.10000E+01 0.0000 23 AlO2- 0.38315E-04 -4.4166 0.35391E-04 -4.4511 0.92368E+00 -0.0345 24 CH4,aq 0.15331E-19 -19.8144 0.15324E-19 -19.8146 0.99955E+00 -0.0002 29 CO,aq 0.15492E-18 -18.8099 0.15492E-18 -18.8099 0.10000E+01 0.0000 30 CO2,aq 0.12678E-07 -7.8969 0.12672E-07 -7.8971 0.99955E+00 -0.0002 31 CO3-2 0.19987E-05 -5.6992 0.15393E-05 -5.8127 0.77014E+00 -0.1134 32 CaCO3,aq 0.21140E-09 -9.6749 0.21140E-09 -9.6749 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.30927E-11 -11.5097 0.28583E-11 -11.5439 0.92420E+00 -0.0342 34 CaCl+ 0.24442E-11 -11.6119 0.22590E-11 -11.6461 0.92420E+00 -0.0342 35 CaCl2,aq 0.68395E-16 -16.1650 0.68395E-16 -16.1650 0.10000E+01 0.0000 36 CaOH+ 0.14560E-08 -8.8368 0.13456E-08 -8.8711 0.92420E+00 -0.0342 37 CaSO4,aq 0.68321E-10 -10.1654 0.68321E-10 -10.1654 0.10000E+01 0.0000 38 HCl,aq 0.13547E-13 -13.8681 0.13547E-13 -13.8681 0.10000E+01 0.0000 43 FeCl+ 0.15930E-15 -15.7978 0.14722E-15 -15.8320 0.92420E+00 -0.0342 46 FeO,aq 0.84288E-10 -10.0742 0.84288E-10 -10.0742 0.10000E+01 0.0000 47 FeOH+ 0.44311E-10 -10.3535 0.40952E-10 -10.3877 0.92420E+00 -0.0342 48 HFeO2- 0.16454E-08 -8.7837 0.15202E-08 -8.8181 0.92394E+00 -0.0344 49 FeO+ 0.47911E-14 -14.3196 0.44280E-14 -14.3538 0.92420E+00 -0.0342 51 FeO2- 0.29140E-08 -8.5355 0.26923E-08 -8.5699 0.92394E+00 -0.0344 52 HFeO2,aq 0.19864E-09 -9.7019 0.19864E-09 -9.7019 0.10000E+01 0.0000 53 H2,aq 0.48685E-09 -9.3126 0.48663E-09 -9.3128 0.99955E+00 -0.0002 54 KCl,aq 0.10177E-09 -9.9924 0.10177E-09 -9.9924 0.10000E+01 0.0000 55 KHSO4,aq 0.14196E-17 -17.8478 0.14196E-17 -17.8478 0.10000E+01 0.0000 56 KOH,aq 0.32436E-07 -7.4890 0.32436E-07 -7.4890 0.10000E+01 0.0000 57 KSO4- 0.14536E-07 -7.8376 0.13430E-07 -7.8719 0.92394E+00 -0.0344 58 MgCO3,aq 0.59844E-12 -12.2230 0.59844E-12 -12.2230 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.35690E-13 -13.4475 0.32985E-13 -13.4817 0.92420E+00 -0.0342 60 MgCl+ 0.25019E-13 -13.6017 0.23122E-13 -13.6360 0.92420E+00 -0.0342 61 MgOH+ 0.90989E-10 -10.0410 0.84092E-10 -10.0752 0.92420E+00 -0.0342 63 MnO,aq 0.30180E-09 -9.5203 0.30180E-09 -9.5203 0.10000E+01 0.0000 64 MnOH+ 0.55314E-09 -9.2572 0.51121E-09 -9.2914 0.92420E+00 -0.0342 65 MnO2-2 0.38645E-13 -13.4129 0.29762E-13 -13.5263 0.77014E+00 -0.1134 66 HMnO2- 0.40939E-11 -11.3879 0.37825E-11 -11.4222 0.92394E+00 -0.0344 69 MnCl+ 0.83277E-13 -13.0795 0.76965E-13 -13.1137 0.92420E+00 -0.0342 70 MnSO4,aq 0.55616E-12 -12.2548 0.55616E-12 -12.2548 0.10000E+01 0.0000 71 NaCl,aq 0.84472E-07 -7.0733 0.84472E-07 -7.0733 0.10000E+01 0.0000 72 NaOH,aq 0.14813E-05 -5.8294 0.14813E-05 -5.8294 0.10000E+01 0.0000 74 OH- 0.10783E-02 -2.9673 0.99597E-03 -3.0018 0.92368E+00 -0.0345 79 HPO3-2 0.14916E-16 -16.8263 0.11487E-16 -16.9398 0.77014E+00 -0.1134 81 H2PO3- 0.14464E-19 -19.8397 0.13363E-19 -19.8741 0.92394E+00 -0.0344 82 H3PO4,aq 0.17829E-13 -13.7489 0.17829E-13 -13.7489 0.10000E+01 0.0000 83 H2PO4- 0.87724E-07 -7.0569 0.81063E-07 -7.0912 0.92407E+00 -0.0343 84 PO4-3 0.18635E-07 -7.7297 0.10654E-07 -7.9725 0.57168E+00 -0.2428 87 H2P2O7-2 0.66904E-15 -15.1746 0.51525E-15 -15.2880 0.77014E+00 -0.1134 88 HP2O7-3 0.31251E-12 -12.5051 0.17735E-12 -12.7512 0.56750E+00 -0.2460 89 P2O7-4 0.19641E-12 -12.7068 0.73034E-13 -13.1365 0.37184E+00 -0.4296 90 H2S,aq 0.54370E-16 -16.2646 0.54346E-16 -16.2648 0.99955E+00 -0.0002 97 SO3-2 0.16094E-14 -14.7933 0.12422E-14 -14.9058 0.77183E+00 -0.1125 98 HSO3- 0.48834E-16 -16.3113 0.45120E-16 -16.3456 0.92394E+00 -0.0344 99 HSO4- 0.11881E-10 -10.9252 0.10982E-10 -10.9593 0.92433E+00 -0.0342 Charge balance for all species = 0.4737E-13 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.6273013E-09 -.2133173E-02 -.2149687E+01 0.0000 2 H2O 0.1000000E+01 0.5550851E+02 0.9998053E+06 0.0000 3 Cl- 0.1379331E-03 0.1380177E-03 0.4892177E+01 5.3418 4 SO4-- 0.2549790E-04 0.2551278E-04 0.2450315E+01 13.7662 5 HCO3- 0.1106251E-04 0.1307412E-04 0.7975891E+00 4.2461 6 HS- 0.3280617E-13 -.2673295E-09 -.8839379E-05 -4.2819 7 Al+++ 0.1177801E-24 0.3832475E-04 0.1033855E+01 2.5345 8 H4SiO4 0.5006132E-03 0.1398794E-02 0.1344191E+03 -3.3005 9 Ca++ 0.1423308E-07 0.1619181E-07 0.6488073E-03 10.5125 10 Mg++ 0.1608533E-09 0.2555579E-09 0.6211900E-05 8.5653 11 Fe++ 0.9488999E-12 0.4887554E-08 0.2729014E-03 6.3362 12 K+ 0.4767554E-04 0.4772262E-04 0.1865682E+01 4.8805 13 Na+ 0.2164795E-02 0.2192426E-02 0.5039351E+02 6.5375 14 Mn++ 0.1274931E-09 0.9871971E-09 0.5422394E-04 8.4645 15 HPO4-- 0.9832383E-05 0.9938744E-05 0.9537227E+00 13.3523 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.2778871E-01 -.2132501E-02 -.2565621E-01 0.0000000E+00 2 H2O 0.5548720E+02 0.5549101E+02 -.3806952E-02 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.7203528E-04 0.2550474E-04 0.4653055E-04 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.4653081E-04 -.2672452E-09 -.4653055E-04 0.0000000E+00 7 Al+++ 0.5474785E-02 0.3831267E-04 0.5436472E-02 0.0000000E+00 8 H4SiO4 0.1748306E-01 0.1398353E-02 0.1608471E-01 0.0000000E+00 9 Ca++ 0.1945561E-02 0.1618670E-07 0.1945544E-02 0.0000000E+00 10 Mg++ 0.1332540E-02 0.2554774E-09 0.1332539E-02 0.0000000E+00 11 Fe++ 0.1197141E-02 0.4886013E-08 0.1197137E-02 0.0000000E+00 12 K+ 0.3564756E-03 0.4770757E-04 0.3087680E-03 0.0000000E+00 13 Na+ 0.2267625E-02 0.2191735E-02 0.7588987E-04 0.0000000E+00 14 Mn++ 0.2911150E-04 0.9868859E-09 0.2911052E-04 0.0000000E+00 15 HPO4-- 0.9935611E-05 0.9935611E-05 0.0000000E+00 0.0000000E+00 Chg. balance for solid moles: 0.5218E-18 Mass of aqueous solution: 0.999882E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 1.6790000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) clinochlore 0.2665E-03 -3.574 0.1481 -0.829 8.258 0.5635E-01 daphnite 0.1650E-03 -3.783 0.1177 -0.929 6.562 0.3567E-01 chlorite-Mn 0.5822E-05 -5.235 0.4128E-02 -2.384 0.2301 0.1315E-02 hematite 0.1861E-03 -3.730 0.2972E-01 -1.527 1.657 0.5634E-02 microcline 0.2416E-03 -3.617 0.6725E-01 -1.172 3.749 0.2627E-01 muscovite 0.6716E-04 -4.173 0.2675E-01 -1.573 1.491 0.9460E-02 paragonite 0.7589E-04 -4.120 0.2901E-01 -1.538 1.617 0.1003E-01 stilbite 0.1946E-02 -2.711 1.371 0.137 76.43 0.6395 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity clinochlore 0.6094E+00 0.6094E+00 1.0000 -0.215 daphnite 0.3773E+00 0.3773E+00 1.0000 -0.423 chlorite-Mn 0.1331E-01 0.1331E-01 1.0000 -1.876 hematite 0.1000E+01 0.1000E+01 1.0000 0.000 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 muscovite 0.1000E+01 0.1000E+01 1.0000 0.000 paragonite 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 1.793768 g Volume = 0.784209 cm3 Porosity: 53.0863% V(tot) - V(min): 0.88739E+00 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 1.6790000 g log = 0.2251 Original solution: 1000.0103000 g Original solution / Rock added: 595.60 (Water/Rock Ratio), log = 2.7750 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0203 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.1000E+01 0.9860 0.1006E+01 0.1020E+01 CO2,gas 0.1319E-05 1.0071 0.1356E-05 0.1346E-05 CH4,gas 0.2183E-16 1.0125 0.2256E-16 0.2228E-16 H2,gas 0.6258E-06 1.0005 0.6389E-06 0.6385E-06 H2S,gas 0.1470E-14 0.9960 0.1494E-14 0.1500E-14 S2,gas 0.2012E-36 1.0000 0.2052E-36 0.2052E-36 CO,gas 0.2263E-15 1.0000 0.2309E-15 0.2309E-15 SO3,gas 0.2450E-38 1.0000 0.2499E-38 0.2499E-38 SO2,gas 0.6089E-22 1.0000 0.6213E-22 0.6213E-22 HCl,gas 0.2343E-16 1.0000 0.2390E-16 0.2390E-16 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 46 clinochlore 39.07 39.07 0.00 0.000 0.00000E+00 47 daphnite 28.97 28.97 0.00 0.000 -0.12132E-10 48 chlorite-Mn 46.87 46.87 0.00 0.000 -0.12132E-10 90 hematite 12.57 12.57 0.00 0.000 0.30331E-11 116 microcline -2.49 -2.49 0.00 0.000 0.15165E-11 120 muscovite 2.58 2.58 0.00 0.000 0.30331E-10 121 paragonite 4.24 4.24 0.00 0.000 0.13649E-10 163 stilbite -7.52 -7.52 0.00 0.000 -0.90992E-11 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -14.23 -7.57 -2.522 0.12920E+05 -5.868 3 CH4,gas 4.54 -13.80 -18.35 -4.586 0.31325E+05 -16.647 4 H2,gas 8.00 0.11 -7.89 -4.511 0.13478E+05 -6.195 5 H2S,gas -6.23 -22.75 -16.52 -8.262 0.28215E+05 -14.826 6 S2,gas -7.34 -45.72 -38.39 -5.906 0.65544E+05 -36.688 7 CO,gas 3.21 -14.12 -17.34 -5.334 0.29600E+05 -15.637 8 SO3,gas 17.12 -23.18 -40.30 -10.075 0.68813E+05 -38.602 9 SO2,gas 0.83 -23.07 -23.91 -6.375 0.40818E+05 -22.207 10 HCl,gas 5.19 -13.13 -18.32 -9.160 0.31282E+05 -16.622 11 acmite 7.71 6.22 -1.49 -0.155 0.25443E+04 15 albite-high 0.69 -0.83 -1.52 -0.117 0.25997E+04 16 albite -0.38 -0.83 -0.45 -0.034 0.76090E+03 19 spessartine 24.46 20.56 -3.90 -0.195 0.66529E+04 20 analcite 3.32 2.47 -0.85 -0.095 0.14528E+04 21 andalusite 5.00 1.77 -3.23 -0.323 0.55204E+04 22 andradite 39.01 34.20 -4.81 -0.250 0.82070E+04 26 annite 20.12 16.52 -3.60 -0.200 0.61491E+04 27 phlogopite 27.06 23.21 -3.86 -0.214 0.65824E+04 29 anorthite 12.71 8.98 -3.73 -0.287 0.63687E+04 32 apatite-OH -18.15 -18.22 -0.06 -0.005 0.11058E+03 35 aragonite 0.97 -3.71 -4.68 -1.560 0.79925E+04 36 brucite 12.57 8.57 -4.00 -0.801 0.68354E+04 37 calcite 0.81 -3.71 -4.53 -1.509 0.77283E+04 38 carnegieite-low 9.02 5.77 -3.25 -0.465 0.55524E+04 39 carnegieite-high 10.09 5.77 -4.32 -0.617 0.73793E+04 40 carpholite-Mg 8.58 7.03 -1.55 -0.103 0.26446E+04 41 carpholite-Fe 6.71 4.80 -1.91 -0.127 0.32587E+04 42 celadonite 5.34 2.78 -2.56 -0.151 0.43767E+04 43 celadonite-Fe 3.88 0.55 -3.33 -0.196 0.56813E+04 44 chrysotile 23.89 19.10 -4.80 -0.400 0.81914E+04 50 chloritoid-Mg 13.20 10.33 -2.86 -0.191 0.48901E+04 51 chloritoid-Fe 9.17 8.10 -1.07 -0.071 0.18253E+04 52 chloritoid-Mn 11.40 10.23 -1.17 -0.078 0.19945E+04 54 coesite -2.38 -3.30 -0.92 -0.308 0.15784E+04 59 corundum 8.38 5.07 -3.31 -0.301 0.56589E+04 61 cristobalite -2.56 -3.30 -0.74 -0.247 0.12638E+04 63 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71234E+04 65 diaspore 2.87 2.53 -0.34 -0.057 0.57923E+03 67 diopside 16.18 12.48 -3.70 -0.370 0.63253E+04 68 hedenbergite 14.21 10.25 -3.96 -0.396 0.67626E+04 75 epidote 24.67 22.48 -2.19 -0.106 0.37468E+04 76 clinozoisite 22.81 18.73 -4.08 -0.185 0.69650E+04 77 epidote-Fe 29.84 26.22 -3.62 -0.188 0.61753E+04 78 fayalite 14.05 9.37 -4.67 -0.668 0.79804E+04 83 gibbsite 4.08 2.53 -1.54 -0.221 0.26378E+04 87 greenalite 16.14 12.41 -3.73 -0.311 0.63721E+04 91 heulandite -5.83 -7.52 -1.69 -0.077 0.28938E+04 95 jadeite 4.22 2.47 -1.74 -0.174 0.29783E+04 97 kalsilite 7.58 4.11 -3.47 -0.496 0.59239E+04 98 kaolinite -1.33 -1.53 -0.20 -0.018 0.34030E+03 99 kyanite 4.88 1.77 -3.11 -0.311 0.53063E+04 101 laumontite 2.88 2.38 -0.50 -0.034 0.86052E+03 102 lawsonite 9.62 8.98 -0.64 -0.042 0.10853E+04 103 leucite 4.12 0.81 -3.30 -0.330 0.56430E+04 105 lizardite 23.24 19.10 -4.15 -0.346 0.70840E+04 107 magnetite 20.09 18.90 -1.19 -0.097 0.20234E+04 108 minnesotaite 10.39 5.81 -4.58 -0.269 0.78228E+04 113 margarite 17.32 14.05 -3.27 -0.131 0.55907E+04 122 nepheline 8.34 5.77 -2.57 -0.367 0.43847E+04 134 phlogopite-Na 29.65 24.87 -4.78 -0.266 0.81621E+04 136 prehnite 19.37 16.19 -3.18 -0.187 0.54288E+04 137 prehnite-Fe 22.50 19.94 -2.56 -0.154 0.43656E+04 145 pyroxmangite 7.40 5.16 -2.23 -0.447 0.38156E+04 146 pyrophyllite -6.18 -8.13 -1.96 -0.122 0.33420E+04 147 quartz -2.99 -3.30 -0.31 -0.104 0.53113E+03 151 rhodochrosite -0.98 -5.76 -4.79 -1.595 0.81721E+04 152 rhodonite 7.45 5.16 -2.28 -0.456 0.38959E+04 153 sanidine -1.28 -2.49 -1.21 -0.093 0.20677E+04 156 sillimanite 5.26 1.77 -3.49 -0.349 0.59644E+04 164 stilpnomelane-Fe 13.02 12.79 -0.23 -0.007 0.39400E+03 165 stilpnomelane-Mg 27.44 23.93 -3.51 -0.105 0.59924E+04 168 sudoite 21.08 17.37 -3.71 -0.120 0.63353E+04 171 talc 16.49 12.49 -4.00 -0.235 0.68248E+04 174 tephroite 18.09 13.63 -4.46 -0.637 0.76106E+04 177 topaz-H 4.62 1.77 -2.85 -0.259 0.48664E+04 178 tridymite -2.63 -3.30 -0.67 -0.225 0.11511E+04 187 wairakite 3.95 2.38 -1.57 -0.092 0.26825E+04 188 walstromite 11.51 7.21 -4.30 -0.859 0.73374E+04 189 wollastonite 10.46 7.21 -3.25 -0.650 0.55478E+04 190 pseudo-wollastonite 11.00 7.21 -3.79 -0.758 0.64676E+04 191 zoisite 22.85 18.73 -4.12 -0.187 0.70390E+04 192 akaganeite 7.75 6.28 -1.47 -0.318 0.25125E+04 193 beidellite-Ca -1.65 -4.47 -2.83 -0.175 0.48276E+04 194 beidellite-H -2.33 -6.21 -3.88 -0.248 0.66272E+04 195 beidellite-K -1.52 -4.60 -3.08 -0.188 0.52534E+04 196 beidellite-Mg -1.79 -4.79 -3.00 -0.186 0.51300E+04 197 beidellite-Na -1.34 -4.05 -2.71 -0.166 0.46237E+04 199 chalcedony -2.80 -3.30 -0.50 -0.166 0.85043E+03 201 montmorillonite-Ca -2.29 -4.41 -2.12 -0.131 0.36157E+04 202 montmorillonite-K -2.24 -4.53 -2.30 -0.141 0.39196E+04 203 montmorillonite-Mg -2.48 -4.73 -2.25 -0.139 0.38413E+04 204 montmorillonite-Na -2.04 -3.99 -1.95 -0.119 0.33256E+04 205 nontronite-Ca 3.21 3.02 -0.19 -0.012 0.32484E+03 206 nontronite-H 2.53 1.29 -1.24 -0.083 0.21223E+04 207 nontronite-K 3.34 2.90 -0.44 -0.028 0.75196E+03 208 nontronite-Mg 3.07 2.70 -0.37 -0.024 0.63451E+03 209 nontronite-Na 3.52 3.45 -0.07 -0.005 0.12393E+03 224 tobermorite 9.82 5.46 -4.37 -1.191 0.74559E+04 233 boehmite 4.41 2.53 -1.87 -0.312 0.31962E+04 235 ferrous-oxide 9.81 6.34 -3.48 -0.869 0.59341E+04 240 silica-amorphous -2.09 -3.30 -1.21 -0.403 0.20646E+04 242 an20ab80 2.02 1.13 -0.89 -0.068 0.15116E+04 243 an25ab75 2.65 1.62 -1.02 -0.079 0.17463E+04 244 an30ab70 3.28 2.11 -1.17 -0.090 0.19905E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 0.0400000 g Current total amount of reactant added: 1.6790000 g New total amount of reactant added: 1.7190000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.4571E-13 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 6 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 1.7190000 Water: Moles liquid = 0.5549E+02 kg liquid = 0.9997E+00 Moles total = 0.5549E+02 kg total = 0.9996E+00 Activity = 1.0000 Stoichiometric ionic strength = .1463240E-02 Osmotic coef. = 0.9781 True ionic strength = .2288280E-02 Chg. balance for total moles = 0.4571E-13 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.61262E-09 -9.2128 0.56627E-09 -9.2470 0.92434E+00 -0.0342 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13793E-03 -3.8603 0.12738E-03 -3.8949 0.92349E+00 -0.0346 4 SO4-- 0.25498E-04 -4.5935 0.19606E-04 -4.7076 0.76891E+00 -0.1141 5 HCO3- 0.11019E-04 -4.9579 0.10178E-04 -4.9923 0.92369E+00 -0.0345 6 HS- 0.34131E-13 -13.4668 0.31520E-13 -13.5014 0.92351E+00 -0.0346 7 Al+++ 0.11002E-24 -24.9585 0.62161E-25 -25.2065 0.56499E+00 -0.2480 8 H4SiO4 0.49386E-03 -3.3064 0.49386E-03 -3.3064 0.10000E+01 0.0000 9 Ca++ 0.14943E-07 -7.8256 0.11477E-07 -7.9402 0.76806E+00 -0.1146 10 Mg++ 0.15482E-09 -9.8102 0.11883E-09 -9.9251 0.76752E+00 -0.1149 11 Fe++ 0.91331E-12 -12.0394 0.70110E-12 -12.1542 0.76765E+00 -0.1148 12 K+ 0.48496E-04 -4.3143 0.44797E-04 -4.3487 0.92373E+00 -0.0345 13 Na+ 0.22021E-02 -2.6572 0.20335E-02 -2.6917 0.92347E+00 -0.0346 14 Mn++ 0.12271E-09 -9.9111 0.94211E-10 -10.0259 0.76775E+00 -0.1148 15 HPO4-- 0.10068E-04 -4.9970 0.77419E-05 -5.1112 0.76893E+00 -0.1141 16 HSiO3- 0.88182E-03 -3.0546 0.81435E-03 -3.0892 0.92349E+00 -0.0346 17 Ca(HSiO3)+ 0.23042E-09 -9.6375 0.21285E-09 -9.6719 0.92376E+00 -0.0344 18 Mg(HSiO3)+ 0.29690E-11 -11.5274 0.27426E-11 -11.5618 0.92376E+00 -0.0344 19 NaHSiO3,aq 0.26784E-04 -4.5721 0.26784E-04 -4.5721 0.10000E+01 0.0000 20 AlO+ 0.28550E-13 -13.5444 0.26373E-13 -13.5788 0.92376E+00 -0.0344 21 AlOH+2 0.96844E-19 -19.0139 0.74363E-19 -19.1286 0.76786E+00 -0.1147 22 HAlO2,aq 0.92750E-08 -8.0327 0.92750E-08 -8.0327 0.10000E+01 0.0000 23 AlO2- 0.39272E-04 -4.4059 0.36257E-04 -4.4406 0.92323E+00 -0.0347 24 CH4,aq 0.15903E-19 -19.7985 0.15896E-19 -19.7987 0.99955E+00 -0.0002 29 CO,aq 0.15303E-18 -18.8152 0.15303E-18 -18.8152 0.10000E+01 0.0000 30 CO2,aq 0.12321E-07 -7.9094 0.12315E-07 -7.9095 0.99955E+00 -0.0002 31 CO3-2 0.20425E-05 -5.6898 0.15700E-05 -5.8041 0.76866E+00 -0.1143 32 CaCO3,aq 0.22594E-09 -9.6460 0.22594E-09 -9.6460 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.32280E-11 -11.4911 0.29819E-11 -11.5255 0.92376E+00 -0.0344 34 CaCl+ 0.25612E-11 -11.5916 0.23659E-11 -11.6260 0.92376E+00 -0.0344 35 CaCl2,aq 0.71598E-16 -16.1451 0.71598E-16 -16.1451 0.10000E+01 0.0000 36 CaOH+ 0.15637E-08 -8.8058 0.14445E-08 -8.8403 0.92376E+00 -0.0344 37 CaSO4,aq 0.71453E-10 -10.1460 0.71453E-10 -10.1460 0.10000E+01 0.0000 38 HCl,aq 0.13218E-13 -13.8788 0.13218E-13 -13.8788 0.10000E+01 0.0000 43 FeCl+ 0.15302E-15 -15.8152 0.14136E-15 -15.8497 0.92376E+00 -0.0344 46 FeO,aq 0.84978E-10 -10.0707 0.84978E-10 -10.0707 0.10000E+01 0.0000 47 FeOH+ 0.43628E-10 -10.3602 0.40302E-10 -10.3947 0.92376E+00 -0.0344 48 HFeO2- 0.17003E-08 -8.7695 0.15702E-08 -8.8041 0.92349E+00 -0.0346 49 FeO+ 0.46790E-14 -14.3298 0.43222E-14 -14.3643 0.92376E+00 -0.0344 51 FeO2- 0.29867E-08 -8.5248 0.27582E-08 -8.5594 0.92349E+00 -0.0346 52 HFeO2,aq 0.19864E-09 -9.7019 0.19864E-09 -9.7019 0.10000E+01 0.0000 53 H2,aq 0.49486E-09 -9.3055 0.49463E-09 -9.3057 0.99955E+00 -0.0002 54 KCl,aq 0.10342E-09 -9.9854 0.10342E-09 -9.9854 0.10000E+01 0.0000 55 KHSO4,aq 0.14062E-17 -17.8520 0.14062E-17 -17.8520 0.10000E+01 0.0000 56 KOH,aq 0.33784E-07 -7.4713 0.33784E-07 -7.4713 0.10000E+01 0.0000 57 KSO4- 0.14758E-07 -7.8310 0.13629E-07 -7.8655 0.92349E+00 -0.0346 58 MgCO3,aq 0.58635E-12 -12.2318 0.58635E-12 -12.2318 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.34150E-13 -13.4666 0.31546E-13 -13.5011 0.92376E+00 -0.0344 60 MgCl+ 0.24033E-13 -13.6192 0.22201E-13 -13.6536 0.92376E+00 -0.0344 61 MgOH+ 0.89587E-10 -10.0478 0.82756E-10 -10.0822 0.92376E+00 -0.0344 63 MnO,aq 0.30427E-09 -9.5167 0.30427E-09 -9.5167 0.10000E+01 0.0000 64 MnOH+ 0.54461E-09 -9.2639 0.50309E-09 -9.2984 0.92376E+00 -0.0344 65 MnO2-2 0.40969E-13 -13.3875 0.31491E-13 -13.5018 0.76866E+00 -0.1143 66 HMnO2- 0.42304E-11 -11.3736 0.39067E-11 -11.4082 0.92349E+00 -0.0346 69 MnCl+ 0.79997E-13 -13.0969 0.73898E-13 -13.1314 0.92376E+00 -0.0344 70 MnSO4,aq 0.53323E-12 -12.2731 0.53323E-12 -12.2731 0.10000E+01 0.0000 71 NaCl,aq 0.85843E-07 -7.0663 0.85843E-07 -7.0663 0.10000E+01 0.0000 72 NaOH,aq 0.15429E-05 -5.8117 0.15429E-05 -5.8117 0.10000E+01 0.0000 74 OH- 0.11052E-02 -2.9566 0.10203E-02 -2.9913 0.92323E+00 -0.0347 79 HPO3-2 0.15525E-16 -16.8090 0.11934E-16 -16.9232 0.76866E+00 -0.1143 81 H2PO3- 0.14674E-19 -19.8335 0.13551E-19 -19.8680 0.92349E+00 -0.0346 82 H3PO4,aq 0.17362E-13 -13.7604 0.17362E-13 -13.7604 0.10000E+01 0.0000 83 H2PO4- 0.87560E-07 -7.0577 0.80872E-07 -7.0922 0.92362E+00 -0.0345 84 PO4-3 0.19595E-07 -7.7079 0.11155E-07 -7.9525 0.56927E+00 -0.2447 87 H2P2O7-2 0.66717E-15 -15.1758 0.51283E-15 -15.2900 0.76866E+00 -0.1143 88 HP2O7-3 0.32004E-12 -12.4948 0.18083E-12 -12.7427 0.56504E+00 -0.2479 89 P2O7-4 0.20675E-12 -12.6846 0.76290E-13 -13.1175 0.36900E+00 -0.4330 90 H2S,aq 0.55189E-16 -16.2581 0.55164E-16 -16.2583 0.99955E+00 -0.0002 97 SO3-2 0.16358E-14 -14.7863 0.12602E-14 -14.8996 0.77037E+00 -0.1133 98 HSO3- 0.48382E-16 -16.3153 0.44680E-16 -16.3499 0.92349E+00 -0.0346 99 HSO4- 0.11581E-10 -10.9363 0.10699E-10 -10.9707 0.92389E+00 -0.0344 Charge balance for all species = 0.4733E-13 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.6126156E-09 -.2174445E-02 -.2191274E+01 0.0000 2 H2O 0.1000000E+01 0.5550853E+02 0.9998041E+06 0.0000 3 Cl- 0.1379327E-03 0.1380186E-03 0.4892201E+01 5.3521 4 SO4-- 0.2549784E-04 0.2551296E-04 0.2450328E+01 13.7863 5 HCO3- 0.1101915E-04 0.1307421E-04 0.7975931E+00 4.2547 6 HS- 0.3413123E-13 -.2744173E-09 -.9073727E-05 -4.2544 7 Al+++ 0.1100222E-24 0.3928112E-04 0.1059653E+01 2.5345 8 H4SiO4 0.4938599E-03 0.1402464E-02 0.1347716E+03 -3.3064 9 Ca++ 0.1494317E-07 0.1704050E-07 0.6828136E-03 10.5538 10 Mg++ 0.1548202E-09 0.2480204E-09 0.6028673E-05 8.5689 11 Fe++ 0.9133075E-12 0.5015107E-08 0.2800231E-03 6.3397 12 K+ 0.4849619E-04 0.4854483E-04 0.1897823E+01 4.8982 13 Na+ 0.2202067E-02 0.2230480E-02 0.5126809E+02 6.5552 14 Mn++ 0.1227109E-09 0.9764738E-09 0.5363486E-04 8.4681 15 HPO4-- 0.1006843E-04 0.1017559E-04 0.9764488E+00 13.3828 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.2845105E-01 -.2173745E-02 -.2627730E-01 0.0000000E+00 2 H2O 0.5548670E+02 0.5549066E+02 -.3959458E-02 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.7314382E-04 0.2550474E-04 0.4763908E-04 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.4763935E-04 -.2743290E-09 -.4763908E-04 0.0000000E+00 7 Al+++ 0.5605215E-02 0.3926847E-04 0.5565946E-02 0.0000000E+00 8 H4SiO4 0.1789957E-01 0.1402013E-02 0.1649756E-01 0.0000000E+00 9 Ca++ 0.1991566E-02 0.1703502E-07 0.1991549E-02 0.0000000E+00 10 Mg++ 0.1364286E-02 0.2479405E-09 0.1364285E-02 0.0000000E+00 11 Fe++ 0.1225662E-02 0.5013493E-08 0.1225657E-02 0.0000000E+00 12 K+ 0.3649682E-03 0.4852921E-04 0.3164389E-03 0.0000000E+00 13 Na+ 0.2317835E-02 0.2229762E-02 0.8807308E-04 0.0000000E+00 14 Mn++ 0.2980505E-04 0.9761595E-09 0.2980407E-04 0.0000000E+00 15 HPO4-- 0.1017231E-04 0.1017231E-04 0.0000000E+00 0.0000000E+00 Chg. balance for solid moles: 0.1416E-17 Mass of aqueous solution: 0.999877E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 1.7190000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) clinochlore 0.2729E-03 -3.564 0.1517 -0.819 8.249 0.5769E-01 daphnite 0.1689E-03 -3.772 0.1205 -0.919 6.555 0.3652E-01 chlorite-Mn 0.5961E-05 -5.225 0.4226E-02 -2.374 0.2299 0.1347E-02 hematite 0.1906E-03 -3.720 0.3043E-01 -1.517 1.655 0.5768E-02 microcline 0.2631E-03 -3.580 0.7322E-01 -1.135 3.983 0.2860E-01 muscovite 0.5337E-04 -4.273 0.2126E-01 -1.672 1.156 0.7517E-02 paragonite 0.8807E-04 -4.055 0.3366E-01 -1.473 1.831 0.1164E-01 stilbite 0.1992E-02 -2.701 1.403 0.147 76.34 0.6546 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity clinochlore 0.6094E+00 0.6094E+00 1.0000 -0.215 daphnite 0.3773E+00 0.3773E+00 1.0000 -0.423 chlorite-Mn 0.1331E-01 0.1331E-01 1.0000 -1.876 hematite 0.1000E+01 0.1000E+01 1.0000 0.000 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 muscovite 0.1000E+01 0.1000E+01 1.0000 0.000 paragonite 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 1.838464 g Volume = 0.803689 cm3 Porosity: 52.3768% V(tot) - V(min): 0.88391E+00 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 1.7190000 g log = 0.2353 Original solution: 1000.0103000 g Original solution / Rock added: 581.74 (Water/Rock Ratio), log = 2.7647 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0203 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.1000E+01 0.9860 0.1006E+01 0.1020E+01 CO2,gas 0.1282E-05 1.0071 0.1318E-05 0.1308E-05 CH4,gas 0.2265E-16 1.0125 0.2340E-16 0.2311E-16 H2,gas 0.6361E-06 1.0005 0.6494E-06 0.6490E-06 H2S,gas 0.1492E-14 0.9960 0.1516E-14 0.1522E-14 S2,gas 0.2006E-36 1.0000 0.2047E-36 0.2047E-36 CO,gas 0.2235E-15 1.0000 0.2280E-15 0.2280E-15 SO3,gas 0.2330E-38 1.0000 0.2377E-38 0.2377E-38 SO2,gas 0.5886E-22 1.0000 0.6005E-22 0.6005E-22 HCl,gas 0.2286E-16 1.0000 0.2332E-16 0.2332E-16 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 46 clinochlore 39.07 39.07 0.00 0.000 0.12132E-10 47 daphnite 28.97 28.97 0.00 0.000 0.00000E+00 48 chlorite-Mn 46.87 46.87 0.00 0.000 0.00000E+00 90 hematite 12.57 12.57 0.00 0.000 0.30331E-11 116 microcline -2.49 -2.49 0.00 0.000 0.15165E-11 120 muscovite 2.58 2.58 0.00 0.000 -0.18198E-10 121 paragonite 4.24 4.24 0.00 0.000 -0.10616E-10 163 stilbite -7.52 -7.52 0.00 0.000 0.15165E-10 32 apatite-OH -18.15 -18.05 0.11 0.008 -0.18293E+03 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -14.24 -7.58 -2.526 0.12941E+05 -5.880 3 CH4,gas 4.54 -13.79 -18.33 -4.582 0.31298E+05 -16.631 4 H2,gas 8.00 0.11 -7.89 -4.507 0.13466E+05 -6.187 5 H2S,gas -6.23 -22.75 -16.52 -8.259 0.28204E+05 -14.819 6 S2,gas -7.34 -45.72 -38.39 -5.906 0.65546E+05 -36.689 7 CO,gas 3.21 -14.13 -17.34 -5.336 0.29609E+05 -15.642 8 SO3,gas 17.12 -23.20 -40.32 -10.081 0.68850E+05 -38.624 9 SO2,gas 0.83 -23.09 -23.92 -6.379 0.40843E+05 -22.221 10 HCl,gas 5.19 -13.14 -18.33 -9.166 0.31300E+05 -16.632 11 acmite 7.71 6.23 -1.48 -0.154 0.25342E+04 15 albite-high 0.69 -0.83 -1.52 -0.117 0.25997E+04 16 albite -0.38 -0.83 -0.45 -0.034 0.76090E+03 19 spessartine 24.46 20.55 -3.90 -0.195 0.66650E+04 20 analcite 3.32 2.48 -0.84 -0.094 0.14427E+04 21 andalusite 5.00 1.76 -3.24 -0.324 0.55305E+04 22 andradite 39.01 34.31 -4.70 -0.244 0.80257E+04 26 annite 20.12 16.53 -3.59 -0.199 0.61310E+04 27 phlogopite 27.06 23.22 -3.84 -0.214 0.65643E+04 29 anorthite 12.71 9.01 -3.70 -0.285 0.63183E+04 35 aragonite 0.97 -3.69 -4.65 -1.551 0.79432E+04 36 brucite 12.57 8.57 -4.00 -0.800 0.68294E+04 37 calcite 0.81 -3.69 -4.50 -1.499 0.76790E+04 38 carnegieite-low 9.02 5.78 -3.24 -0.463 0.55322E+04 39 carnegieite-high 10.09 5.78 -4.31 -0.616 0.73592E+04 40 carpholite-Mg 8.58 7.03 -1.56 -0.104 0.26587E+04 41 carpholite-Fe 6.71 4.80 -1.92 -0.128 0.32728E+04 42 celadonite 5.34 2.78 -2.57 -0.151 0.43807E+04 43 celadonite-Fe 3.88 0.55 -3.33 -0.196 0.56853E+04 44 chrysotile 23.89 19.09 -4.80 -0.400 0.81934E+04 50 chloritoid-Mg 13.20 10.33 -2.87 -0.191 0.48941E+04 51 chloritoid-Fe 9.17 8.10 -1.07 -0.071 0.18293E+04 52 chloritoid-Mn 11.40 10.23 -1.17 -0.078 0.19986E+04 54 coesite -2.38 -3.31 -0.93 -0.310 0.15885E+04 59 corundum 8.38 5.07 -3.31 -0.301 0.56589E+04 61 cristobalite -2.56 -3.31 -0.75 -0.249 0.12739E+04 63 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71234E+04 65 diaspore 2.87 2.53 -0.34 -0.057 0.57923E+03 67 diopside 16.18 12.51 -3.67 -0.367 0.62689E+04 68 hedenbergite 14.21 10.28 -3.93 -0.393 0.67062E+04 75 epidote 24.67 22.54 -2.13 -0.103 0.36361E+04 76 clinozoisite 22.81 18.79 -4.01 -0.182 0.68542E+04 77 epidote-Fe 29.84 26.29 -3.55 -0.185 0.60645E+04 78 fayalite 14.05 9.37 -4.67 -0.668 0.79784E+04 83 gibbsite 4.08 2.53 -1.54 -0.221 0.26378E+04 87 greenalite 16.14 12.41 -3.73 -0.311 0.63741E+04 91 heulandite -5.83 -7.52 -1.69 -0.077 0.28938E+04 95 jadeite 4.22 2.48 -1.74 -0.174 0.29682E+04 97 kalsilite 7.58 4.13 -3.46 -0.494 0.59038E+04 98 kaolinite -1.33 -1.54 -0.21 -0.019 0.36044E+03 99 kyanite 4.88 1.76 -3.11 -0.311 0.53164E+04 101 laumontite 2.88 2.40 -0.49 -0.032 0.83030E+03 102 lawsonite 9.62 9.01 -0.61 -0.040 0.10350E+04 103 leucite 4.12 0.82 -3.30 -0.330 0.56329E+04 105 lizardite 23.24 19.09 -4.15 -0.346 0.70860E+04 107 magnetite 20.09 18.91 -1.18 -0.096 0.20173E+04 108 minnesotaite 10.39 5.79 -4.59 -0.270 0.78449E+04 113 margarite 17.32 14.08 -3.24 -0.130 0.55403E+04 122 nepheline 8.34 5.78 -2.56 -0.365 0.43646E+04 134 phlogopite-Na 29.65 24.88 -4.77 -0.265 0.81440E+04 136 prehnite 19.37 16.26 -3.11 -0.183 0.53180E+04 137 prehnite-Fe 22.50 20.01 -2.49 -0.150 0.42549E+04 138 pumpellyite-Fe 46.27 41.39 -4.88 -0.108 0.83334E+04 145 pyroxmangite 7.40 5.16 -2.24 -0.447 0.38196E+04 146 pyrophyllite -6.18 -8.16 -1.98 -0.124 0.33823E+04 147 quartz -2.99 -3.31 -0.32 -0.106 0.54120E+03 151 rhodochrosite -0.98 -5.77 -4.79 -1.598 0.81872E+04 152 rhodonite 7.45 5.16 -2.28 -0.457 0.38999E+04 153 sanidine -1.28 -2.49 -1.21 -0.093 0.20677E+04 156 sillimanite 5.26 1.76 -3.50 -0.350 0.59744E+04 164 stilpnomelane-Fe 13.02 12.77 -0.25 -0.008 0.42925E+03 165 stilpnomelane-Mg 27.44 23.91 -3.53 -0.105 0.60276E+04 168 sudoite 21.08 17.36 -3.72 -0.120 0.63534E+04 171 talc 16.49 12.48 -4.01 -0.236 0.68470E+04 174 tephroite 18.09 13.63 -4.46 -0.637 0.76086E+04 177 topaz-H 4.62 1.76 -2.86 -0.260 0.48765E+04 178 tridymite -2.63 -3.31 -0.68 -0.227 0.11612E+04 187 wairakite 3.95 2.40 -1.55 -0.091 0.26523E+04 188 walstromite 11.51 7.25 -4.26 -0.852 0.72770E+04 189 wollastonite 10.46 7.25 -3.21 -0.643 0.54874E+04 190 pseudo-wollastonite 11.00 7.25 -3.75 -0.750 0.64072E+04 191 zoisite 22.85 18.79 -4.06 -0.184 0.69283E+04 192 akaganeite 7.75 6.28 -1.47 -0.318 0.25125E+04 193 beidellite-Ca -1.65 -4.49 -2.84 -0.176 0.48530E+04 194 beidellite-H -2.33 -6.23 -3.90 -0.249 0.66642E+04 195 beidellite-K -1.52 -4.61 -3.09 -0.189 0.52804E+04 196 beidellite-Mg -1.79 -4.82 -3.03 -0.187 0.51660E+04 197 beidellite-Na -1.34 -4.07 -2.72 -0.167 0.46507E+04 199 chalcedony -2.80 -3.31 -0.50 -0.168 0.86050E+03 201 montmorillonite-Ca -2.29 -4.42 -2.13 -0.132 0.36424E+04 202 montmorillonite-K -2.24 -4.55 -2.31 -0.142 0.39480E+04 203 montmorillonite-Mg -2.48 -4.75 -2.27 -0.141 0.38786E+04 204 montmorillonite-Na -2.04 -4.00 -1.96 -0.120 0.33540E+04 205 nontronite-Ca 3.21 3.01 -0.21 -0.013 0.35017E+03 206 nontronite-H 2.53 1.27 -1.26 -0.085 0.21593E+04 207 nontronite-K 3.34 2.88 -0.46 -0.029 0.77895E+03 208 nontronite-Mg 3.07 2.68 -0.39 -0.025 0.67048E+03 209 nontronite-Na 3.52 3.43 -0.09 -0.006 0.15093E+03 224 tobermorite 9.82 5.48 -4.34 -1.184 0.74072E+04 233 boehmite 4.41 2.53 -1.87 -0.312 0.31962E+04 235 ferrous-oxide 9.81 6.34 -3.47 -0.868 0.59281E+04 240 silica-amorphous -2.09 -3.31 -1.22 -0.405 0.20747E+04 242 an20ab80 2.02 1.14 -0.88 -0.068 0.15015E+04 243 an25ab75 2.65 1.63 -1.02 -0.078 0.17337E+04 244 an30ab70 3.28 2.12 -1.16 -0.089 0.19754E+04 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 6 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 1.7190000 Water: Moles liquid = 0.5549E+02 kg liquid = 0.9997E+00 Moles total = 0.5549E+02 kg total = 0.9996E+00 Activity = 1.0000 Stoichiometric ionic strength = .1460147E-02 Osmotic coef. = 0.9782 True ionic strength = .2284713E-02 Chg. balance for total moles = 0.4571E-13 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.61316E-09 -9.2124 0.56679E-09 -9.2466 0.92438E+00 -0.0341 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13793E-03 -3.8603 0.12738E-03 -3.8949 0.92353E+00 -0.0346 4 SO4-- 0.25498E-04 -4.5935 0.19609E-04 -4.7075 0.76905E+00 -0.1140 5 HCO3- 0.11021E-04 -4.9578 0.10180E-04 -4.9922 0.92373E+00 -0.0345 6 HS- 0.34051E-13 -13.4679 0.31448E-13 -13.5024 0.92355E+00 -0.0345 7 Al+++ 0.11028E-24 -24.9575 0.62334E-25 -25.2053 0.56522E+00 -0.2478 8 H4SiO4 0.49421E-03 -3.3061 0.49421E-03 -3.3061 0.10000E+01 0.0000 9 Ca++ 0.14894E-07 -7.8270 0.11441E-07 -7.9415 0.76820E+00 -0.1145 10 Mg++ 0.15501E-09 -9.8096 0.11900E-09 -9.9245 0.76766E+00 -0.1148 11 Fe++ 0.91444E-12 -12.0388 0.70210E-12 -12.1536 0.76779E+00 -0.1148 12 K+ 0.48435E-04 -4.3148 0.44743E-04 -4.3493 0.92377E+00 -0.0344 13 Na+ 0.21993E-02 -2.6577 0.20311E-02 -2.6923 0.92351E+00 -0.0346 14 Mn++ 0.12286E-09 -9.9106 0.94345E-10 -10.0253 0.76788E+00 -0.1147 15 HPO4-- 0.93321E-05 -5.0300 0.71769E-05 -5.1441 0.76906E+00 -0.1140 16 HSiO3- 0.88159E-03 -3.0547 0.81417E-03 -3.0893 0.92353E+00 -0.0346 17 Ca(HSiO3)+ 0.22964E-09 -9.6389 0.21214E-09 -9.6734 0.92380E+00 -0.0344 18 Mg(HSiO3)+ 0.29724E-11 -11.5269 0.27459E-11 -11.5613 0.92380E+00 -0.0344 19 NaHSiO3,aq 0.26745E-04 -4.5727 0.26745E-04 -4.5727 0.10000E+01 0.0000 20 AlO+ 0.28575E-13 -13.5440 0.26397E-13 -13.5784 0.92380E+00 -0.0344 21 AlOH+2 0.97006E-19 -19.0132 0.74500E-19 -19.1278 0.76800E+00 -0.1146 22 HAlO2,aq 0.92750E-08 -8.0327 0.92750E-08 -8.0327 0.10000E+01 0.0000 23 AlO2- 0.39234E-04 -4.4063 0.36223E-04 -4.4410 0.92327E+00 -0.0347 24 CH4,aq 0.15867E-19 -19.7995 0.15859E-19 -19.7997 0.99955E+00 -0.0002 29 CO,aq 0.15307E-18 -18.8151 0.15307E-18 -18.8151 0.10000E+01 0.0000 30 CO2,aq 0.12335E-07 -7.9089 0.12329E-07 -7.9091 0.99955E+00 -0.0002 31 CO3-2 0.20407E-05 -5.6902 0.15689E-05 -5.8044 0.76879E+00 -0.1142 32 CaCO3,aq 0.22507E-09 -9.6477 0.22507E-09 -9.6477 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.32185E-11 -11.4924 0.29732E-11 -11.5268 0.92380E+00 -0.0344 34 CaCl+ 0.25532E-11 -11.5929 0.23586E-11 -11.6273 0.92380E+00 -0.0344 35 CaCl2,aq 0.71381E-16 -16.1464 0.71381E-16 -16.1464 0.10000E+01 0.0000 36 CaOH+ 0.15573E-08 -8.8076 0.14387E-08 -8.8420 0.92380E+00 -0.0344 37 CaSO4,aq 0.71243E-10 -10.1473 0.71243E-10 -10.1473 0.10000E+01 0.0000 38 HCl,aq 0.13230E-13 -13.8784 0.13230E-13 -13.8784 0.10000E+01 0.0000 43 FeCl+ 0.15324E-15 -15.8146 0.14156E-15 -15.8491 0.92380E+00 -0.0344 46 FeO,aq 0.84941E-10 -10.0709 0.84941E-10 -10.0709 0.10000E+01 0.0000 47 FeOH+ 0.43648E-10 -10.3600 0.40322E-10 -10.3945 0.92380E+00 -0.0344 48 HFeO2- 0.16979E-08 -8.7701 0.15680E-08 -8.8046 0.92353E+00 -0.0346 49 FeO+ 0.46831E-14 -14.3295 0.43262E-14 -14.3639 0.92380E+00 -0.0344 51 FeO2- 0.29838E-08 -8.5252 0.27556E-08 -8.5598 0.92353E+00 -0.0346 52 HFeO2,aq 0.19864E-09 -9.7019 0.19864E-09 -9.7019 0.10000E+01 0.0000 53 H2,aq 0.49443E-09 -9.3059 0.49421E-09 -9.3061 0.99955E+00 -0.0002 54 KCl,aq 0.10330E-09 -9.9859 0.10330E-09 -9.9859 0.10000E+01 0.0000 55 KHSO4,aq 0.14060E-17 -17.8520 0.14060E-17 -17.8520 0.10000E+01 0.0000 56 KOH,aq 0.33712E-07 -7.4722 0.33712E-07 -7.4722 0.10000E+01 0.0000 57 KSO4- 0.14742E-07 -7.8314 0.13615E-07 -7.8660 0.92353E+00 -0.0346 58 MgCO3,aq 0.58676E-12 -12.2315 0.58676E-12 -12.2315 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.34204E-13 -13.4659 0.31598E-13 -13.5003 0.92380E+00 -0.0344 60 MgCl+ 0.24068E-13 -13.6186 0.22234E-13 -13.6530 0.92380E+00 -0.0344 61 MgOH+ 0.89627E-10 -10.0476 0.82798E-10 -10.0820 0.92380E+00 -0.0344 63 MnO,aq 0.30414E-09 -9.5169 0.30414E-09 -9.5169 0.10000E+01 0.0000 64 MnOH+ 0.54486E-09 -9.2637 0.50334E-09 -9.2981 0.92380E+00 -0.0344 65 MnO2-2 0.40868E-13 -13.3886 0.31419E-13 -13.5028 0.76879E+00 -0.1142 66 HMnO2- 0.42245E-11 -11.3742 0.39015E-11 -11.4088 0.92353E+00 -0.0346 69 MnCl+ 0.80111E-13 -13.0963 0.74007E-13 -13.1307 0.92380E+00 -0.0344 70 MnSO4,aq 0.53408E-12 -12.2724 0.53408E-12 -12.2724 0.10000E+01 0.0000 71 NaCl,aq 0.85743E-07 -7.0668 0.85743E-07 -7.0668 0.10000E+01 0.0000 72 NaOH,aq 0.15396E-05 -5.8126 0.15396E-05 -5.8126 0.10000E+01 0.0000 74 OH- 0.11041E-02 -2.9570 0.10194E-02 -2.9917 0.92327E+00 -0.0347 79 HPO3-2 0.14378E-16 -16.8423 0.11053E-16 -16.9565 0.76879E+00 -0.1142 81 H2PO3- 0.13603E-19 -19.8664 0.12563E-19 -19.9009 0.92353E+00 -0.0346 82 H3PO4,aq 0.16125E-13 -13.7925 0.16125E-13 -13.7925 0.10000E+01 0.0000 83 H2PO4- 0.81242E-07 -7.0902 0.75040E-07 -7.1247 0.92366E+00 -0.0345 84 PO4-3 0.18141E-07 -7.7413 0.10331E-07 -7.9858 0.56949E+00 -0.2445 87 H2P2O7-2 0.57432E-15 -15.2408 0.44153E-15 -15.3550 0.76879E+00 -0.1142 88 HP2O7-3 0.27518E-12 -12.5604 0.15555E-12 -12.8081 0.56527E+00 -0.2477 89 P2O7-4 0.17755E-12 -12.7507 0.65562E-13 -13.1833 0.36926E+00 -0.4327 90 H2S,aq 0.55113E-16 -16.2587 0.55088E-16 -16.2589 0.99955E+00 -0.0002 97 SO3-2 0.16344E-14 -14.7866 0.12593E-14 -14.8999 0.77050E+00 -0.1132 98 HSO3- 0.48392E-16 -16.3152 0.44691E-16 -16.3498 0.92353E+00 -0.0346 99 HSO4- 0.11593E-10 -10.9358 0.10711E-10 -10.9702 0.92393E+00 -0.0344 Charge balance for all species = 0.4246E-13 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.6131561E-09 -.2172953E-02 -.2189771E+01 0.0000 2 H2O 0.1000000E+01 0.5550853E+02 0.9998042E+06 0.0000 3 Cl- 0.1379327E-03 0.1380186E-03 0.4892201E+01 5.3517 4 SO4-- 0.2549785E-04 0.2551295E-04 0.2450328E+01 13.7856 5 HCO3- 0.1102096E-04 0.1307421E-04 0.7975930E+00 4.2543 6 HS- 0.3405080E-13 -.2741610E-09 -.9065252E-05 -4.2558 7 Al+++ 0.1102838E-24 0.3924300E-04 0.1058625E+01 2.5345 8 H4SiO4 0.4942117E-03 0.1402550E-02 0.1347799E+03 -3.3061 9 Ca++ 0.1489376E-07 0.1698281E-07 0.6805020E-03 10.5516 10 Mg++ 0.1550129E-09 0.2482577E-09 0.6034442E-05 8.5687 11 Fe++ 0.9144444E-12 0.5009819E-08 0.2797278E-03 6.3396 12 K+ 0.4843536E-04 0.4848391E-04 0.1895442E+01 4.8973 13 Na+ 0.2199304E-02 0.2227675E-02 0.5120364E+02 6.5543 14 Mn++ 0.1228636E-09 0.9767387E-09 0.5364942E-04 8.4679 15 HPO4-- 0.9332066E-05 0.9431450E-05 0.9050414E+00 13.3491 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.2845105E-01 -.2172254E-02 -.2627879E-01 0.0000000E+00 2 H2O 0.5548670E+02 0.5549067E+02 -.3967641E-02 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.7314382E-04 0.2550474E-04 0.4763908E-04 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.4763935E-04 -.2740728E-09 -.4763908E-04 0.0000000E+00 7 Al+++ 0.5605215E-02 0.3923037E-04 0.5565984E-02 0.0000000E+00 8 H4SiO4 0.1789957E-01 0.1402099E-02 0.1649748E-01 0.0000000E+00 9 Ca++ 0.1991566E-02 0.1697735E-07 0.1991549E-02 0.0000000E+00 10 Mg++ 0.1364286E-02 0.2481778E-09 0.1364285E-02 0.0000000E+00 11 Fe++ 0.1225662E-02 0.5008208E-08 0.1225657E-02 0.0000000E+00 12 K+ 0.3649682E-03 0.4846832E-04 0.3164998E-03 0.0000000E+00 13 Na+ 0.2317835E-02 0.2226958E-02 0.9087639E-04 0.0000000E+00 14 Mn++ 0.2980505E-04 0.9764245E-09 0.2980407E-04 0.0000000E+00 15 HPO4-- 0.1017231E-04 0.9428416E-05 0.7438983E-06 0.0000000E+00 Chg. balance for solid moles: 0.4037E-17 Mass of aqueous solution: 0.999877E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 1.7190000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) clinochlore 0.2729E-03 -3.564 0.1517 -0.819 8.249 0.5769E-01 daphnite 0.1689E-03 -3.772 0.1205 -0.919 6.555 0.3652E-01 chlorite-Mn 0.5961E-05 -5.225 0.4226E-02 -2.374 0.2299 0.1347E-02 hematite 0.1906E-03 -3.720 0.3043E-01 -1.517 1.655 0.5768E-02 microcline 0.2661E-03 -3.575 0.7407E-01 -1.130 4.029 0.2893E-01 muscovite 0.5039E-04 -4.298 0.2007E-01 -1.697 1.092 0.7097E-02 paragonite 0.9088E-04 -4.042 0.3473E-01 -1.459 1.889 0.1201E-01 stilbite 0.1990E-02 -2.701 1.403 0.147 76.29 0.6542 apatite-OH 0.2480E-06 -6.606 0.1246E-03 -3.905 0.6775E-02 0.3958E-04 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity clinochlore 0.6094E+00 0.6094E+00 1.0000 -0.215 daphnite 0.3773E+00 0.3773E+00 1.0000 -0.423 chlorite-Mn 0.1331E-01 0.1331E-01 1.0000 -1.876 hematite 0.1000E+01 0.1000E+01 1.0000 0.000 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 muscovite 0.1000E+01 0.1000E+01 1.0000 0.000 paragonite 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 1.838447 g Volume = 0.803602 cm3 Porosity: 52.3819% V(tot) - V(min): 0.88400E+00 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 1.7190000 g log = 0.2353 Original solution: 1000.0103000 g Original solution / Rock added: 581.74 (Water/Rock Ratio), log = 2.7647 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0203 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.1000E+01 0.9860 0.1006E+01 0.1020E+01 CO2,gas 0.1284E-05 1.0071 0.1319E-05 0.1310E-05 CH4,gas 0.2260E-16 1.0125 0.2334E-16 0.2306E-16 H2,gas 0.6356E-06 1.0005 0.6488E-06 0.6485E-06 H2S,gas 0.1490E-14 0.9960 0.1514E-14 0.1520E-14 S2,gas 0.2004E-36 1.0000 0.2045E-36 0.2045E-36 CO,gas 0.2236E-15 1.0000 0.2281E-15 0.2281E-15 SO3,gas 0.2334E-38 1.0000 0.2382E-38 0.2382E-38 SO2,gas 0.5893E-22 1.0000 0.6012E-22 0.6012E-22 HCl,gas 0.2288E-16 1.0000 0.2335E-16 0.2335E-16 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 32 apatite-OH -18.15 -18.15 0.00 0.000 0.60662E-11 46 clinochlore 39.07 39.07 0.00 0.000 0.36397E-10 47 daphnite 28.97 28.97 0.00 0.000 0.60662E-11 48 chlorite-Mn 46.87 46.87 0.00 0.000 0.24265E-10 90 hematite 12.57 12.57 0.00 0.000 -0.15165E-10 116 microcline -2.49 -2.49 0.00 0.000 0.13649E-10 120 muscovite 2.58 2.58 0.00 0.000 0.60662E-11 121 paragonite 4.24 4.24 0.00 0.000 -0.10616E-10 163 stilbite -7.52 -7.52 0.00 0.000 -0.90992E-11 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -14.24 -7.58 -2.526 0.12940E+05 -5.880 3 CH4,gas 4.54 -13.79 -18.33 -4.583 0.31299E+05 -16.632 4 H2,gas 8.00 0.11 -7.89 -4.507 0.13467E+05 -6.188 5 H2S,gas -6.23 -22.75 -16.52 -8.259 0.28205E+05 -14.820 6 S2,gas -7.34 -45.72 -38.39 -5.906 0.65547E+05 -36.689 7 CO,gas 3.21 -14.13 -17.34 -5.336 0.29609E+05 -15.642 8 SO3,gas 17.12 -23.20 -40.32 -10.081 0.68849E+05 -38.623 9 SO2,gas 0.83 -23.09 -23.92 -6.379 0.40843E+05 -22.221 10 HCl,gas 5.19 -13.14 -18.33 -9.165 0.31299E+05 -16.632 11 acmite 7.71 6.23 -1.48 -0.154 0.25347E+04 15 albite-high 0.69 -0.83 -1.52 -0.117 0.25997E+04 16 albite -0.38 -0.83 -0.45 -0.034 0.76090E+03 19 spessartine 24.46 20.55 -3.90 -0.195 0.66643E+04 20 analcite 3.32 2.48 -0.85 -0.094 0.14433E+04 21 andalusite 5.00 1.76 -3.24 -0.324 0.55300E+04 22 andradite 39.01 34.30 -4.71 -0.244 0.80353E+04 26 annite 20.12 16.53 -3.59 -0.200 0.61319E+04 27 phlogopite 27.06 23.22 -3.85 -0.214 0.65652E+04 29 anorthite 12.71 9.01 -3.70 -0.285 0.63209E+04 35 aragonite 0.97 -3.69 -4.65 -1.551 0.79461E+04 36 brucite 12.57 8.57 -4.00 -0.800 0.68297E+04 37 calcite 0.81 -3.69 -4.50 -1.500 0.76818E+04 38 carnegieite-low 9.02 5.78 -3.24 -0.463 0.55333E+04 39 carnegieite-high 10.09 5.78 -4.31 -0.616 0.73603E+04 40 carpholite-Mg 8.58 7.03 -1.56 -0.104 0.26579E+04 41 carpholite-Fe 6.71 4.80 -1.92 -0.128 0.32721E+04 42 celadonite 5.34 2.78 -2.57 -0.151 0.43805E+04 43 celadonite-Fe 3.88 0.55 -3.33 -0.196 0.56851E+04 44 chrysotile 23.89 19.09 -4.80 -0.400 0.81933E+04 50 chloritoid-Mg 13.20 10.33 -2.87 -0.191 0.48939E+04 51 chloritoid-Fe 9.17 8.10 -1.07 -0.071 0.18291E+04 52 chloritoid-Mn 11.40 10.23 -1.17 -0.078 0.19984E+04 54 coesite -2.38 -3.31 -0.93 -0.310 0.15880E+04 59 corundum 8.38 5.07 -3.31 -0.301 0.56589E+04 61 cristobalite -2.56 -3.31 -0.75 -0.249 0.12733E+04 63 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71234E+04 65 diaspore 2.87 2.53 -0.34 -0.057 0.57923E+03 67 diopside 16.18 12.51 -3.67 -0.367 0.62719E+04 68 hedenbergite 14.21 10.28 -3.93 -0.393 0.67091E+04 75 epidote 24.67 22.54 -2.13 -0.103 0.36419E+04 76 clinozoisite 22.81 18.79 -4.02 -0.183 0.68600E+04 77 epidote-Fe 29.84 26.29 -3.56 -0.185 0.60703E+04 78 fayalite 14.05 9.37 -4.67 -0.668 0.79785E+04 83 gibbsite 4.08 2.53 -1.54 -0.221 0.26378E+04 87 greenalite 16.14 12.41 -3.73 -0.311 0.63740E+04 91 heulandite -5.83 -7.52 -1.69 -0.077 0.28938E+04 95 jadeite 4.22 2.48 -1.74 -0.174 0.29688E+04 97 kalsilite 7.58 4.13 -3.46 -0.494 0.59048E+04 98 kaolinite -1.33 -1.54 -0.21 -0.019 0.35939E+03 99 kyanite 4.88 1.76 -3.11 -0.311 0.53159E+04 101 laumontite 2.88 2.40 -0.49 -0.032 0.83189E+03 102 lawsonite 9.62 9.01 -0.61 -0.041 0.10376E+04 103 leucite 4.12 0.82 -3.30 -0.330 0.56334E+04 105 lizardite 23.24 19.09 -4.15 -0.346 0.70859E+04 107 magnetite 20.09 18.91 -1.18 -0.096 0.20176E+04 108 minnesotaite 10.39 5.79 -4.59 -0.270 0.78438E+04 113 margarite 17.32 14.08 -3.25 -0.130 0.55430E+04 122 nepheline 8.34 5.78 -2.56 -0.365 0.43656E+04 134 phlogopite-Na 29.65 24.88 -4.77 -0.265 0.81450E+04 136 prehnite 19.37 16.25 -3.12 -0.183 0.53238E+04 137 prehnite-Fe 22.50 20.00 -2.50 -0.150 0.42607E+04 138 pumpellyite-Fe 46.27 41.38 -4.89 -0.109 0.83454E+04 145 pyroxmangite 7.40 5.16 -2.24 -0.447 0.38194E+04 146 pyrophyllite -6.18 -8.16 -1.98 -0.124 0.33802E+04 147 quartz -2.99 -3.31 -0.32 -0.106 0.54067E+03 151 rhodochrosite -0.98 -5.77 -4.79 -1.598 0.81867E+04 152 rhodonite 7.45 5.16 -2.28 -0.457 0.38997E+04 153 sanidine -1.28 -2.49 -1.21 -0.093 0.20677E+04 156 sillimanite 5.26 1.76 -3.50 -0.350 0.59739E+04 164 stilpnomelane-Fe 13.02 12.77 -0.25 -0.007 0.42741E+03 165 stilpnomelane-Mg 27.44 23.91 -3.53 -0.105 0.60258E+04 168 sudoite 21.08 17.36 -3.72 -0.120 0.63524E+04 171 talc 16.49 12.48 -4.01 -0.236 0.68458E+04 174 tephroite 18.09 13.63 -4.46 -0.637 0.76087E+04 177 topaz-H 4.62 1.76 -2.86 -0.260 0.48759E+04 178 tridymite -2.63 -3.31 -0.68 -0.227 0.11607E+04 187 wairakite 3.95 2.40 -1.55 -0.091 0.26538E+04 188 walstromite 11.51 7.25 -4.26 -0.853 0.72801E+04 189 wollastonite 10.46 7.25 -3.22 -0.643 0.54906E+04 190 pseudo-wollastonite 11.00 7.25 -3.75 -0.751 0.64104E+04 191 zoisite 22.85 18.79 -4.06 -0.185 0.69341E+04 192 akaganeite 7.75 6.28 -1.47 -0.318 0.25125E+04 193 beidellite-Ca -1.65 -4.49 -2.84 -0.176 0.48516E+04 194 beidellite-H -2.33 -6.23 -3.90 -0.249 0.66622E+04 195 beidellite-K -1.52 -4.61 -3.09 -0.189 0.52790E+04 196 beidellite-Mg -1.79 -4.81 -3.02 -0.187 0.51641E+04 197 beidellite-Na -1.34 -4.07 -2.72 -0.167 0.46493E+04 199 chalcedony -2.80 -3.31 -0.50 -0.168 0.85997E+03 201 montmorillonite-Ca -2.29 -4.42 -2.13 -0.132 0.36410E+04 202 montmorillonite-K -2.24 -4.55 -2.31 -0.142 0.39465E+04 203 montmorillonite-Mg -2.48 -4.75 -2.27 -0.140 0.38767E+04 204 montmorillonite-Na -2.04 -4.00 -1.96 -0.120 0.33525E+04 205 nontronite-Ca 3.21 3.01 -0.20 -0.013 0.34884E+03 206 nontronite-H 2.53 1.27 -1.26 -0.085 0.21574E+04 207 nontronite-K 3.34 2.89 -0.46 -0.029 0.77754E+03 208 nontronite-Mg 3.07 2.68 -0.39 -0.025 0.66859E+03 209 nontronite-Na 3.52 3.43 -0.09 -0.006 0.14951E+03 224 tobermorite 9.82 5.48 -4.34 -1.184 0.74098E+04 233 boehmite 4.41 2.53 -1.87 -0.312 0.31962E+04 235 ferrous-oxide 9.81 6.34 -3.47 -0.868 0.59284E+04 240 silica-amorphous -2.09 -3.31 -1.21 -0.405 0.20741E+04 242 an20ab80 2.02 1.14 -0.88 -0.068 0.15021E+04 243 an25ab75 2.65 1.63 -1.02 -0.078 0.17343E+04 244 an30ab70 3.28 2.12 -1.16 -0.089 0.19762E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 0.0400000 g Current total amount of reactant added: 1.7190000 g New total amount of reactant added: 1.7590000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.4571E-13 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 7 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 1.7590000 Water: Moles liquid = 0.5549E+02 kg liquid = 0.9997E+00 Moles total = 0.5549E+02 kg total = 0.9996E+00 Activity = 1.0000 Stoichiometric ionic strength = .1479780E-02 Osmotic coef. = 0.9780 True ionic strength = .2317791E-02 Chg. balance for total moles = 0.4571E-13 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.59985E-09 -9.2220 0.55426E-09 -9.2563 0.92401E+00 -0.0343 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13793E-03 -3.8603 0.12733E-03 -3.8951 0.92314E+00 -0.0347 4 SO4-- 0.25498E-04 -4.5935 0.19577E-04 -4.7083 0.76779E+00 -0.1148 5 HCO3- 0.10980E-04 -4.9594 0.10139E-04 -4.9940 0.92335E+00 -0.0346 6 HS- 0.35280E-13 -13.4525 0.32569E-13 -13.4872 0.92316E+00 -0.0347 7 Al+++ 0.10352E-24 -24.9850 0.58292E-25 -25.2344 0.56312E+00 -0.2494 8 H4SiO4 0.48817E-03 -3.3114 0.48817E-03 -3.3114 0.10000E+01 0.0000 9 Ca++ 0.15549E-07 -7.8083 0.11925E-07 -7.9235 0.76692E+00 -0.1152 10 Mg++ 0.14958E-09 -9.8251 0.11464E-09 -9.9407 0.76638E+00 -0.1156 11 Fe++ 0.88242E-12 -12.0543 0.67638E-12 -12.1698 0.76651E+00 -0.1155 12 K+ 0.49166E-04 -4.3083 0.45399E-04 -4.3430 0.92339E+00 -0.0346 13 Na+ 0.22325E-02 -2.6512 0.20608E-02 -2.6860 0.92312E+00 -0.0347 14 Mn++ 0.11856E-09 -9.9261 0.90889E-10 -10.0415 0.76661E+00 -0.1154 15 HPO4-- 0.84679E-05 -5.0722 0.65017E-05 -5.1870 0.76780E+00 -0.1148 16 HSiO3- 0.89087E-03 -3.0502 0.82240E-03 -3.0849 0.92314E+00 -0.0347 17 Ca(HSiO3)+ 0.24187E-09 -9.6164 0.22334E-09 -9.6510 0.92342E+00 -0.0346 18 Mg(HSiO3)+ 0.28937E-11 -11.5386 0.26721E-11 -11.5732 0.92342E+00 -0.0346 19 NaHSiO3,aq 0.27412E-04 -4.5621 0.27412E-04 -4.5621 0.10000E+01 0.0000 20 AlO+ 0.27955E-13 -13.5535 0.25814E-13 -13.5881 0.92342E+00 -0.0346 21 AlOH+2 0.92920E-19 -19.0319 0.71244E-19 -19.1473 0.76672E+00 -0.1154 22 HAlO2,aq 0.92750E-08 -8.0327 0.92750E-08 -8.0327 0.10000E+01 0.0000 23 AlO2- 0.40137E-04 -4.3965 0.37042E-04 -4.4313 0.92288E+00 -0.0349 24 CH4,aq 0.16392E-19 -19.7854 0.16385E-19 -19.7856 0.99954E+00 -0.0002 29 CO,aq 0.15129E-18 -18.8202 0.15129E-18 -18.8202 0.10000E+01 0.0000 30 CO2,aq 0.12013E-07 -7.9203 0.12008E-07 -7.9205 0.99954E+00 -0.0002 31 CO3-2 0.20817E-05 -5.6816 0.15978E-05 -5.7965 0.76753E+00 -0.1149 32 CaCO3,aq 0.23891E-09 -9.6218 0.23891E-09 -9.6218 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.33422E-11 -11.4760 0.30862E-11 -11.5106 0.92342E+00 -0.0346 34 CaCl+ 0.26611E-11 -11.5749 0.24573E-11 -11.6095 0.92342E+00 -0.0346 35 CaCl2,aq 0.74336E-16 -16.1288 0.74336E-16 -16.1288 0.10000E+01 0.0000 36 CaOH+ 0.16605E-08 -8.7798 0.15334E-08 -8.8144 0.92342E+00 -0.0346 37 CaSO4,aq 0.74133E-10 -10.1300 0.74133E-10 -10.1300 0.10000E+01 0.0000 38 HCl,aq 0.12933E-13 -13.8883 0.12933E-13 -13.8883 0.10000E+01 0.0000 43 FeCl+ 0.14763E-15 -15.8308 0.13632E-15 -15.8654 0.92342E+00 -0.0346 46 FeO,aq 0.85571E-10 -10.0677 0.85571E-10 -10.0677 0.10000E+01 0.0000 47 FeOH+ 0.43017E-10 -10.3664 0.39723E-10 -10.4010 0.92342E+00 -0.0346 48 HFeO2- 0.17498E-08 -8.7570 0.16154E-08 -8.7917 0.92314E+00 -0.0347 49 FeO+ 0.45815E-14 -14.3390 0.42306E-14 -14.3736 0.92342E+00 -0.0346 51 FeO2- 0.30525E-08 -8.5153 0.28179E-08 -8.5501 0.92314E+00 -0.0347 52 HFeO2,aq 0.19864E-09 -9.7019 0.19864E-09 -9.7019 0.10000E+01 0.0000 53 H2,aq 0.50179E-09 -9.2995 0.50156E-09 -9.2997 0.99954E+00 -0.0002 54 KCl,aq 0.10477E-09 -9.9798 0.10477E-09 -9.9798 0.10000E+01 0.0000 55 KHSO4,aq 0.13928E-17 -17.8561 0.13928E-17 -17.8561 0.10000E+01 0.0000 56 KOH,aq 0.34980E-07 -7.4562 0.34980E-07 -7.4562 0.10000E+01 0.0000 57 KSO4- 0.14940E-07 -7.8257 0.13792E-07 -7.8604 0.92314E+00 -0.0347 58 MgCO3,aq 0.57568E-12 -12.2398 0.57568E-12 -12.2398 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.32830E-13 -13.4837 0.30316E-13 -13.5183 0.92342E+00 -0.0346 60 MgCl+ 0.23186E-13 -13.6348 0.21410E-13 -13.6694 0.92342E+00 -0.0346 61 MgOH+ 0.88332E-10 -10.0539 0.81568E-10 -10.0885 0.92342E+00 -0.0346 63 MnO,aq 0.30639E-09 -9.5137 0.30639E-09 -9.5137 0.10000E+01 0.0000 64 MnOH+ 0.53699E-09 -9.2700 0.49586E-09 -9.3046 0.92342E+00 -0.0346 65 MnO2-2 0.43124E-13 -13.3653 0.33099E-13 -13.4802 0.76753E+00 -0.1149 66 HMnO2- 0.43538E-11 -11.3611 0.40192E-11 -11.3959 0.92314E+00 -0.0347 69 MnCl+ 0.77177E-13 -13.1125 0.71266E-13 -13.1471 0.92342E+00 -0.0346 70 MnSO4,aq 0.51368E-12 -12.2893 0.51368E-12 -12.2893 0.10000E+01 0.0000 71 NaCl,aq 0.86963E-07 -7.0607 0.86963E-07 -7.0607 0.10000E+01 0.0000 72 NaOH,aq 0.15975E-05 -5.7966 0.15975E-05 -5.7966 0.10000E+01 0.0000 74 OH- 0.11295E-02 -2.9471 0.10424E-02 -2.9820 0.92288E+00 -0.0349 79 HPO3-2 0.13240E-16 -16.8781 0.10162E-16 -16.9930 0.76753E+00 -0.1149 81 H2PO3- 0.12235E-19 -19.9124 0.11295E-19 -19.9471 0.92314E+00 -0.0347 82 H3PO4,aq 0.13970E-13 -13.8548 0.13970E-13 -13.8548 0.10000E+01 0.0000 83 H2PO4- 0.72002E-07 -7.1427 0.66478E-07 -7.1773 0.92328E+00 -0.0347 84 PO4-3 0.16867E-07 -7.7730 0.95707E-08 -8.0191 0.56744E+00 -0.2461 87 H2P2O7-2 0.45147E-15 -15.3454 0.34652E-15 -15.4603 0.76753E+00 -0.1149 88 HP2O7-3 0.22166E-12 -12.6543 0.12483E-12 -12.9037 0.56317E+00 -0.2494 89 P2O7-4 0.14667E-12 -12.8337 0.53806E-13 -13.2692 0.36685E+00 -0.4355 90 H2S,aq 0.55818E-16 -16.2532 0.55792E-16 -16.2534 0.99954E+00 -0.0002 97 SO3-2 0.16587E-14 -14.7802 0.12760E-14 -14.8942 0.76926E+00 -0.1139 98 HSO3- 0.47967E-16 -16.3191 0.44281E-16 -16.3538 0.92314E+00 -0.0347 99 HSO4- 0.11323E-10 -10.9461 0.10457E-10 -10.9806 0.92355E+00 -0.0345 Charge balance for all species = 0.4567E-13 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.5998479E-09 -.2212043E-02 -.2229160E+01 0.0000 2 H2O 0.1000000E+01 0.5550854E+02 0.9998031E+06 0.0000 3 Cl- 0.1379324E-03 0.1380195E-03 0.4892226E+01 5.3612 4 SO4-- 0.2549781E-04 0.2551312E-04 0.2450341E+01 13.8043 5 HCO3- 0.1098036E-04 0.1307429E-04 0.7975970E+00 4.2623 6 HS- 0.3528019E-13 -.2809089E-09 -.9288361E-05 -4.2309 7 Al+++ 0.1035166E-24 0.4014653E-04 0.1082997E+01 2.5345 8 H4SiO4 0.4881699E-03 0.1406448E-02 0.1351543E+03 -3.3114 9 Ca++ 0.1554913E-07 0.1777058E-07 0.7120668E-03 10.5890 10 Mg++ 0.1495840E-09 0.2414416E-09 0.5868755E-05 8.5719 11 Fe++ 0.8824165E-12 0.5130451E-08 0.2864630E-03 6.3428 12 K+ 0.4916572E-04 0.4921574E-04 0.1924049E+01 4.9133 13 Na+ 0.2232476E-02 0.2261572E-02 0.5198270E+02 6.5703 14 Mn++ 0.1185603E-09 0.9669245E-09 0.5311028E-04 8.4711 15 HPO4-- 0.8467948E-05 0.8556817E-05 0.8211106E+00 13.3256 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.2911339E-01 -.2211317E-02 -.2690207E-01 0.0000000E+00 2 H2O 0.5548620E+02 0.5549033E+02 -.4132178E-02 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.7425236E-04 0.2550475E-04 0.4874761E-04 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.4874789E-04 -.2808167E-09 -.4874761E-04 0.0000000E+00 7 Al+++ 0.5735644E-02 0.4013336E-04 0.5695511E-02 0.0000000E+00 8 H4SiO4 0.1831609E-01 0.1405986E-02 0.1691010E-01 0.0000000E+00 9 Ca++ 0.2037572E-02 0.1776475E-07 0.2037554E-02 0.0000000E+00 10 Mg++ 0.1396032E-02 0.2413624E-09 0.1396032E-02 0.0000000E+00 11 Fe++ 0.1254182E-02 0.5128768E-08 0.1254177E-02 0.0000000E+00 12 K+ 0.3734607E-03 0.4919960E-04 0.3242611E-03 0.0000000E+00 13 Na+ 0.2368045E-02 0.2260830E-02 0.1072142E-03 0.0000000E+00 14 Mn++ 0.3049859E-04 0.9666073E-09 0.3049762E-04 0.0000000E+00 15 HPO4-- 0.1040902E-04 0.8554010E-05 0.1855007E-05 0.0000000E+00 Chg. balance for solid moles: 0.3365E-17 Mass of aqueous solution: 0.999872E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 1.7590000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) apatite-OH 0.6183E-06 -6.209 0.3106E-03 -3.508 0.1649E-01 0.9870E-04 clinochlore 0.2792E-03 -3.554 0.1552 -0.809 8.241 0.5903E-01 daphnite 0.1728E-03 -3.762 0.1233 -0.909 6.549 0.3737E-01 chlorite-Mn 0.6100E-05 -5.215 0.4324E-02 -2.364 0.2296 0.1378E-02 hematite 0.1950E-03 -3.710 0.3114E-01 -1.507 1.654 0.5902E-02 microcline 0.2921E-03 -3.535 0.8129E-01 -1.090 4.317 0.3176E-01 muscovite 0.3220E-04 -4.492 0.1282E-01 -1.892 0.6810 0.4535E-02 paragonite 0.1072E-03 -3.970 0.4098E-01 -1.387 2.176 0.1416E-01 stilbite 0.2034E-02 -2.692 1.434 0.156 76.14 0.6687 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.6094E+00 0.6094E+00 1.0000 -0.215 daphnite 0.3773E+00 0.3773E+00 1.0000 -0.423 chlorite-Mn 0.1331E-01 0.1331E-01 1.0000 -1.876 hematite 0.1000E+01 0.1000E+01 1.0000 0.000 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 muscovite 0.1000E+01 0.1000E+01 1.0000 0.000 paragonite 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 1.883110 g Volume = 0.822950 cm3 Porosity: 51.6935% V(tot) - V(min): 0.88065E+00 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 1.7590000 g log = 0.2453 Original solution: 1000.0103000 g Original solution / Rock added: 568.51 (Water/Rock Ratio), log = 2.7547 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0203 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.1000E+01 0.9860 0.1006E+01 0.1020E+01 CO2,gas 0.1250E-05 1.0071 0.1285E-05 0.1276E-05 CH4,gas 0.2334E-16 1.0125 0.2412E-16 0.2382E-16 H2,gas 0.6450E-06 1.0005 0.6585E-06 0.6581E-06 H2S,gas 0.1509E-14 0.9960 0.1534E-14 0.1540E-14 S2,gas 0.1996E-36 1.0000 0.2036E-36 0.2036E-36 CO,gas 0.2210E-15 1.0000 0.2255E-15 0.2255E-15 SO3,gas 0.2229E-38 1.0000 0.2274E-38 0.2274E-38 SO2,gas 0.5710E-22 1.0000 0.5826E-22 0.5826E-22 HCl,gas 0.2237E-16 1.0000 0.2282E-16 0.2282E-16 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 32 apatite-OH -18.15 -18.15 0.00 0.000 0.12132E-10 46 clinochlore 39.07 39.07 0.00 0.000 0.24265E-10 47 daphnite 28.97 28.97 0.00 0.000 0.18198E-10 48 chlorite-Mn 46.87 46.87 0.00 0.000 0.24265E-10 90 hematite 12.57 12.57 0.00 0.000 -0.90992E-11 116 microcline -2.49 -2.49 0.00 0.000 0.15165E-11 120 muscovite 2.58 2.58 0.00 0.000 0.30331E-10 121 paragonite 4.24 4.24 0.00 0.000 0.13649E-10 163 stilbite -7.52 -7.52 0.00 0.000 0.15165E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -14.25 -7.59 -2.530 0.12960E+05 -5.891 3 CH4,gas 4.54 -13.77 -18.32 -4.579 0.31275E+05 -16.618 4 H2,gas 8.00 0.12 -7.88 -4.503 0.13456E+05 -6.181 5 H2S,gas -6.23 -22.74 -16.51 -8.257 0.28196E+05 -14.814 6 S2,gas -7.34 -45.73 -38.39 -5.906 0.65550E+05 -36.691 7 CO,gas 3.21 -14.13 -17.35 -5.337 0.29618E+05 -15.647 8 SO3,gas 17.12 -23.22 -40.34 -10.086 0.68883E+05 -38.643 9 SO2,gas 0.83 -23.10 -23.93 -6.382 0.40866E+05 -22.235 10 HCl,gas 5.19 -13.15 -18.34 -9.170 0.31316E+05 -16.642 11 acmite 7.71 6.23 -1.48 -0.154 0.25256E+04 15 albite-high 0.69 -0.83 -1.52 -0.117 0.25997E+04 16 albite -0.38 -0.83 -0.45 -0.034 0.76090E+03 19 spessartine 24.46 20.55 -3.91 -0.195 0.66753E+04 20 analcite 3.32 2.48 -0.84 -0.093 0.14342E+04 21 andalusite 5.00 1.76 -3.24 -0.324 0.55391E+04 22 andradite 39.01 34.40 -4.61 -0.239 0.78711E+04 26 annite 20.12 16.54 -3.58 -0.199 0.61155E+04 27 phlogopite 27.06 23.23 -3.84 -0.213 0.65488E+04 29 anorthite 12.71 9.04 -3.68 -0.283 0.62753E+04 35 aragonite 0.97 -3.66 -4.63 -1.543 0.79018E+04 36 brucite 12.57 8.57 -4.00 -0.799 0.68242E+04 37 calcite 0.81 -3.66 -4.47 -1.491 0.76376E+04 38 carnegieite-low 9.02 5.79 -3.23 -0.461 0.55150E+04 39 carnegieite-high 10.09 5.79 -4.30 -0.614 0.73420E+04 40 carpholite-Mg 8.58 7.02 -1.56 -0.104 0.26707E+04 41 carpholite-Fe 6.71 4.79 -1.92 -0.128 0.32849E+04 42 celadonite 5.34 2.77 -2.57 -0.151 0.43842E+04 43 celadonite-Fe 3.88 0.54 -3.33 -0.196 0.56888E+04 44 chrysotile 23.89 19.09 -4.80 -0.400 0.81951E+04 50 chloritoid-Mg 13.20 10.33 -2.87 -0.191 0.48976E+04 51 chloritoid-Fe 9.17 8.10 -1.07 -0.072 0.18327E+04 52 chloritoid-Mn 11.40 10.23 -1.17 -0.078 0.20020E+04 54 coesite -2.38 -3.31 -0.94 -0.312 0.15971E+04 59 corundum 8.38 5.07 -3.31 -0.301 0.56589E+04 61 cristobalite -2.56 -3.31 -0.75 -0.250 0.12825E+04 63 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71234E+04 65 diaspore 2.87 2.53 -0.34 -0.057 0.57923E+03 67 diopside 16.18 12.54 -3.64 -0.364 0.62208E+04 68 hedenbergite 14.21 10.31 -3.90 -0.390 0.66580E+04 75 epidote 24.67 22.60 -2.07 -0.101 0.35415E+04 76 clinozoisite 22.81 18.85 -3.96 -0.180 0.67597E+04 77 epidote-Fe 29.84 26.34 -3.50 -0.182 0.59700E+04 78 fayalite 14.05 9.37 -4.67 -0.667 0.79767E+04 83 gibbsite 4.08 2.53 -1.54 -0.221 0.26378E+04 87 greenalite 16.14 12.41 -3.73 -0.311 0.63758E+04 91 heulandite -5.83 -7.52 -1.69 -0.077 0.28938E+04 95 jadeite 4.22 2.48 -1.73 -0.173 0.29596E+04 97 kalsilite 7.58 4.14 -3.45 -0.493 0.58866E+04 98 kaolinite -1.33 -1.55 -0.22 -0.020 0.37763E+03 99 kyanite 4.88 1.76 -3.12 -0.312 0.53250E+04 101 laumontite 2.88 2.41 -0.47 -0.031 0.80452E+03 102 lawsonite 9.62 9.04 -0.58 -0.039 0.99201E+03 103 leucite 4.12 0.82 -3.29 -0.329 0.56243E+04 105 lizardite 23.24 19.09 -4.15 -0.346 0.70877E+04 107 magnetite 20.09 18.91 -1.18 -0.096 0.20122E+04 108 minnesotaite 10.39 5.78 -4.61 -0.271 0.78638E+04 113 margarite 17.32 14.10 -3.22 -0.129 0.54974E+04 122 nepheline 8.34 5.79 -2.55 -0.364 0.43474E+04 134 phlogopite-Na 29.65 24.89 -4.76 -0.264 0.81285E+04 136 prehnite 19.37 16.31 -3.06 -0.180 0.52235E+04 137 prehnite-Fe 22.50 20.06 -2.44 -0.147 0.41603E+04 138 pumpellyite-Fe 46.27 41.50 -4.77 -0.106 0.81392E+04 145 pyroxmangite 7.40 5.16 -2.24 -0.448 0.38231E+04 146 pyrophyllite -6.18 -8.18 -2.00 -0.125 0.34166E+04 147 quartz -2.99 -3.31 -0.32 -0.107 0.54980E+03 151 rhodochrosite -0.98 -5.78 -4.80 -1.601 0.82008E+04 152 rhodonite 7.45 5.16 -2.29 -0.457 0.39033E+04 153 sanidine -1.28 -2.49 -1.21 -0.093 0.20677E+04 156 sillimanite 5.26 1.76 -3.50 -0.350 0.59830E+04 164 stilpnomelane-Fe 13.02 12.75 -0.27 -0.008 0.45933E+03 165 stilpnomelane-Mg 27.44 23.89 -3.55 -0.106 0.60577E+04 168 sudoite 21.08 17.35 -3.73 -0.120 0.63689E+04 171 talc 16.49 12.47 -4.02 -0.237 0.68659E+04 174 tephroite 18.09 13.63 -4.46 -0.636 0.76069E+04 177 topaz-H 4.62 1.76 -2.86 -0.260 0.48851E+04 178 tridymite -2.63 -3.31 -0.69 -0.228 0.11698E+04 187 wairakite 3.95 2.41 -1.54 -0.090 0.26265E+04 188 walstromite 11.51 7.28 -4.23 -0.846 0.72254E+04 189 wollastonite 10.46 7.28 -3.18 -0.637 0.54358E+04 190 pseudo-wollastonite 11.00 7.28 -3.72 -0.744 0.63557E+04 191 zoisite 22.85 18.85 -4.00 -0.182 0.68337E+04 192 akaganeite 7.75 6.28 -1.47 -0.318 0.25125E+04 193 beidellite-Ca -1.65 -4.50 -2.85 -0.177 0.48746E+04 194 beidellite-H -2.33 -6.25 -3.92 -0.250 0.66957E+04 195 beidellite-K -1.52 -4.63 -3.11 -0.190 0.53034E+04 196 beidellite-Mg -1.79 -4.83 -3.04 -0.188 0.51967E+04 197 beidellite-Na -1.34 -4.08 -2.74 -0.168 0.46737E+04 199 chalcedony -2.80 -3.31 -0.51 -0.170 0.86909E+03 201 montmorillonite-Ca -2.29 -4.44 -2.15 -0.133 0.36651E+04 202 montmorillonite-K -2.24 -4.56 -2.33 -0.142 0.39721E+04 203 montmorillonite-Mg -2.48 -4.77 -2.29 -0.142 0.39104E+04 204 montmorillonite-Na -2.04 -4.02 -1.98 -0.121 0.33781E+04 205 nontronite-Ca 3.21 3.00 -0.22 -0.014 0.37178E+03 206 nontronite-H 2.53 1.25 -1.28 -0.086 0.21908E+04 207 nontronite-K 3.34 2.87 -0.47 -0.030 0.80198E+03 208 nontronite-Mg 3.07 2.66 -0.41 -0.027 0.70117E+03 209 nontronite-Na 3.52 3.42 -0.10 -0.007 0.17396E+03 224 tobermorite 9.82 5.51 -4.31 -1.177 0.73657E+04 233 boehmite 4.41 2.53 -1.87 -0.312 0.31962E+04 235 ferrous-oxide 9.81 6.34 -3.47 -0.867 0.59229E+04 240 silica-amorphous -2.09 -3.31 -1.22 -0.407 0.20833E+04 242 an20ab80 2.02 1.14 -0.87 -0.067 0.14929E+04 243 an25ab75 2.65 1.64 -1.01 -0.078 0.17229E+04 244 an30ab70 3.28 2.13 -1.15 -0.088 0.19625E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 0.0400000 g Current total amount of reactant added: 1.7590000 g New total amount of reactant added: 1.7990000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.4572E-13 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 7 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 1.7990000 Water: Moles liquid = 0.5549E+02 kg liquid = 0.9997E+00 Moles total = 0.5549E+02 kg total = 0.9996E+00 Activity = 1.0000 Stoichiometric ionic strength = .1499812E-02 Osmotic coef. = 0.9779 True ionic strength = .2351313E-02 Chg. balance for total moles = 0.4572E-13 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.58701E-09 -9.2314 0.54218E-09 -9.2659 0.92363E+00 -0.0345 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13793E-03 -3.8603 0.12728E-03 -3.8952 0.92276E+00 -0.0349 4 SO4-- 0.25498E-04 -4.5935 0.19545E-04 -4.7090 0.76652E+00 -0.1155 5 HCO3- 0.10940E-04 -4.9610 0.10097E-04 -4.9958 0.92297E+00 -0.0348 6 HS- 0.36543E-13 -13.4372 0.33721E-13 -13.4721 0.92278E+00 -0.0349 7 Al+++ 0.97255E-25 -25.0121 0.54562E-25 -25.2631 0.56102E+00 -0.2510 8 H4SiO4 0.48226E-03 -3.3167 0.48226E-03 -3.3167 0.10000E+01 0.0000 9 Ca++ 0.16229E-07 -7.7897 0.12426E-07 -7.9057 0.76565E+00 -0.1160 10 Mg++ 0.14442E-09 -9.8404 0.11050E-09 -9.9566 0.76510E+00 -0.1163 11 Fe++ 0.85197E-12 -12.0696 0.65196E-12 -12.1858 0.76523E+00 -0.1162 12 K+ 0.49904E-04 -4.3019 0.46061E-04 -4.3367 0.92300E+00 -0.0348 13 Na+ 0.22660E-02 -2.6447 0.20909E-02 -2.6797 0.92274E+00 -0.0349 14 Mn++ 0.11447E-09 -9.9413 0.87607E-10 -10.0575 0.76533E+00 -0.1162 15 HPO4-- 0.76904E-05 -5.1141 0.58950E-05 -5.2295 0.76654E+00 -0.1155 16 HSiO3- 0.90008E-03 -3.0457 0.83055E-03 -3.0806 0.92276E+00 -0.0349 17 Ca(HSiO3)+ 0.25463E-09 -9.5941 0.23503E-09 -9.6289 0.92303E+00 -0.0348 18 Mg(HSiO3)+ 0.28180E-11 -11.5501 0.26011E-11 -11.5848 0.92303E+00 -0.0348 19 NaHSiO3,aq 0.28087E-04 -4.5515 0.28087E-04 -4.5515 0.10000E+01 0.0000 20 AlO+ 0.27357E-13 -13.5629 0.25251E-13 -13.5977 0.92303E+00 -0.0348 21 AlOH+2 0.89060E-19 -19.0503 0.68171E-19 -19.1664 0.76545E+00 -0.1161 22 HAlO2,aq 0.92750E-08 -8.0327 0.92750E-08 -8.0327 0.10000E+01 0.0000 23 AlO2- 0.41049E-04 -4.3867 0.37868E-04 -4.4217 0.92249E+00 -0.0350 24 CH4,aq 0.16930E-19 -19.7713 0.16922E-19 -19.7715 0.99954E+00 -0.0002 29 CO,aq 0.14955E-18 -18.8252 0.14955E-18 -18.8252 0.10000E+01 0.0000 30 CO2,aq 0.11703E-07 -7.9317 0.11697E-07 -7.9319 0.99954E+00 -0.0002 31 CO3-2 0.21228E-05 -5.6731 0.16266E-05 -5.7887 0.76626E+00 -0.1156 32 CaCO3,aq 0.25344E-09 -9.5961 0.25344E-09 -9.5961 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.34696E-11 -11.4597 0.32026E-11 -11.4945 0.92303E+00 -0.0348 34 CaCl+ 0.27728E-11 -11.5571 0.25594E-11 -11.5919 0.92303E+00 -0.0348 35 CaCl2,aq 0.77393E-16 -16.1113 0.77393E-16 -16.1113 0.10000E+01 0.0000 36 CaOH+ 0.17696E-08 -8.7521 0.16334E-08 -8.7869 0.92303E+00 -0.0348 37 CaSO4,aq 0.77119E-10 -10.1128 0.77119E-10 -10.1128 0.10000E+01 0.0000 38 HCl,aq 0.12645E-13 -13.8981 0.12645E-13 -13.8981 0.10000E+01 0.0000 43 FeCl+ 0.14229E-15 -15.8468 0.13134E-15 -15.8816 0.92303E+00 -0.0348 46 FeO,aq 0.86198E-10 -10.0645 0.86198E-10 -10.0645 0.10000E+01 0.0000 47 FeOH+ 0.42405E-10 -10.3726 0.39142E-10 -10.4074 0.92303E+00 -0.0348 48 HFeO2- 0.18027E-08 -8.7441 0.16635E-08 -8.7790 0.92276E+00 -0.0349 49 FeO+ 0.44835E-14 -14.3484 0.41384E-14 -14.3832 0.92303E+00 -0.0348 51 FeO2- 0.31218E-08 -8.5056 0.28807E-08 -8.5405 0.92276E+00 -0.0349 52 HFeO2,aq 0.19864E-09 -9.7019 0.19864E-09 -9.7019 0.10000E+01 0.0000 53 H2,aq 0.50918E-09 -9.2931 0.50894E-09 -9.2933 0.99954E+00 -0.0002 54 KCl,aq 0.10625E-09 -9.9737 0.10625E-09 -9.9737 0.10000E+01 0.0000 55 KHSO4,aq 0.13800E-17 -17.8601 0.13800E-17 -17.8601 0.10000E+01 0.0000 56 KOH,aq 0.36281E-07 -7.4403 0.36281E-07 -7.4403 0.10000E+01 0.0000 57 KSO4- 0.15139E-07 -7.8199 0.13970E-07 -7.8548 0.92276E+00 -0.0349 58 MgCO3,aq 0.56491E-12 -12.2480 0.56491E-12 -12.2480 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.31527E-13 -13.5013 0.29100E-13 -13.5361 0.92303E+00 -0.0348 60 MgCl+ 0.22348E-13 -13.6508 0.20628E-13 -13.6855 0.92303E+00 -0.0348 61 MgOH+ 0.87076E-10 -10.0601 0.80374E-10 -10.0949 0.92303E+00 -0.0348 63 MnO,aq 0.30864E-09 -9.5106 0.30864E-09 -9.5106 0.10000E+01 0.0000 64 MnOH+ 0.52935E-09 -9.2763 0.48861E-09 -9.3110 0.92303E+00 -0.0348 65 MnO2-2 0.45473E-13 -13.3422 0.34844E-13 -13.4579 0.76626E+00 -0.1156 66 HMnO2- 0.44854E-11 -11.3482 0.41389E-11 -11.3831 0.92276E+00 -0.0349 69 MnCl+ 0.74389E-13 -13.1285 0.68664E-13 -13.1633 0.92303E+00 -0.0348 70 MnSO4,aq 0.49431E-12 -12.3060 0.49431E-12 -12.3060 0.10000E+01 0.0000 71 NaCl,aq 0.88195E-07 -7.0546 0.88195E-07 -7.0546 0.10000E+01 0.0000 72 NaOH,aq 0.16569E-05 -5.7807 0.16569E-05 -5.7807 0.10000E+01 0.0000 74 OH- 0.11552E-02 -2.9373 0.10657E-02 -2.9724 0.92249E+00 -0.0350 79 HPO3-2 0.12202E-16 -16.9136 0.93496E-17 -17.0292 0.76626E+00 -0.1156 81 H2PO3- 0.11016E-19 -19.9580 0.10165E-19 -19.9929 0.92276E+00 -0.0349 82 H3PO4,aq 0.12120E-13 -13.9165 0.12120E-13 -13.9165 0.10000E+01 0.0000 83 H2PO4- 0.63886E-07 -7.1946 0.58960E-07 -7.2294 0.92289E+00 -0.0348 84 PO4-3 0.15690E-07 -7.8044 0.88710E-08 -8.0520 0.56538E+00 -0.2477 87 H2P2O7-2 0.35572E-15 -15.4489 0.27257E-15 -15.5645 0.76626E+00 -0.1156 88 HP2O7-3 0.17892E-12 -12.7473 0.10038E-12 -12.9983 0.56107E+00 -0.2510 89 P2O7-4 0.12137E-12 -12.9159 0.44232E-13 -13.3543 0.36444E+00 -0.4384 90 H2S,aq 0.56532E-16 -16.2477 0.56505E-16 -16.2479 0.99954E+00 -0.0002 97 SO3-2 0.16831E-14 -14.7739 0.12926E-14 -14.8885 0.76801E+00 -0.1146 98 HSO3- 0.47554E-16 -16.3228 0.43880E-16 -16.3577 0.92276E+00 -0.0349 99 HSO4- 0.11062E-10 -10.9562 0.10212E-10 -10.9909 0.92317E+00 -0.0347 Charge balance for all species = 0.4571E-13 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.5870082E-09 -.2251351E-02 -.2268769E+01 0.0000 2 H2O 0.1000000E+01 0.5550856E+02 0.9998020E+06 0.0000 3 Cl- 0.1379320E-03 0.1380203E-03 0.4892250E+01 5.3706 4 SO4-- 0.2549778E-04 0.2551329E-04 0.2450354E+01 13.8227 5 HCO3- 0.1093961E-04 0.1307437E-04 0.7976010E+00 4.2700 6 HS- 0.3654305E-13 -.2877283E-09 -.9513834E-05 -4.2062 7 Al+++ 0.9725531E-25 0.4105848E-04 0.1107596E+01 2.5345 8 H4SiO4 0.4822619E-03 0.1410427E-02 0.1355364E+03 -3.3167 9 Ca++ 0.1622925E-07 0.1859026E-07 0.7449106E-03 10.6260 10 Mg++ 0.1444235E-09 0.2349364E-09 0.5710623E-05 8.5751 11 Fe++ 0.8519722E-12 0.5252653E-08 0.2932858E-03 6.3459 12 K+ 0.4990378E-04 0.4995531E-04 0.1952959E+01 4.9292 13 Na+ 0.2265998E-02 0.2295831E-02 0.5277006E+02 6.5862 14 Mn++ 0.1144698E-09 0.9575566E-09 0.5259565E-04 8.4743 15 HPO4-- 0.7690375E-05 0.7769952E-05 0.7456020E+00 13.3022 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.2977573E-01 -.2250598E-02 -.2752513E-01 0.0000000E+00 2 H2O 0.5548570E+02 0.5548999E+02 -.4295576E-02 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.7536089E-04 0.2550476E-04 0.4985613E-04 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.4985642E-04 -.2876320E-09 -.4985613E-04 0.0000000E+00 7 Al+++ 0.5866074E-02 0.4104475E-04 0.5825029E-02 0.0000000E+00 8 H4SiO4 0.1873260E-01 0.1409955E-02 0.1732264E-01 0.0000000E+00 9 Ca++ 0.2083578E-02 0.1858405E-07 0.2083559E-02 0.0000000E+00 10 Mg++ 0.1427778E-02 0.2348578E-09 0.1427778E-02 0.0000000E+00 11 Fe++ 0.1282702E-02 0.5250896E-08 0.1282697E-02 0.0000000E+00 12 K+ 0.3819533E-03 0.4993860E-04 0.3320147E-03 0.0000000E+00 13 Na+ 0.2418254E-02 0.2295063E-02 0.1231915E-03 0.0000000E+00 14 Mn++ 0.3119213E-04 0.9572363E-09 0.3119118E-04 0.0000000E+00 15 HPO4-- 0.1064572E-04 0.7767353E-05 0.2878368E-05 0.0000000E+00 Chg. balance for solid moles: -.1491E-18 Mass of aqueous solution: 0.999867E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 1.7990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) apatite-OH 0.9595E-06 -6.018 0.4820E-03 -3.317 0.2500E-01 0.1531E-03 clinochlore 0.2856E-03 -3.544 0.1587 -0.799 8.233 0.6037E-01 daphnite 0.1768E-03 -3.753 0.1261 -0.899 6.543 0.3822E-01 chlorite-Mn 0.6238E-05 -5.205 0.4423E-02 -2.354 0.2294 0.1409E-02 hematite 0.1994E-03 -3.700 0.3185E-01 -1.497 1.652 0.6036E-02 microcline 0.3176E-03 -3.498 0.8841E-01 -1.054 4.586 0.3453E-01 muscovite 0.1439E-04 -4.842 0.5734E-02 -2.242 0.2974 0.2027E-02 paragonite 0.1232E-03 -3.909 0.4708E-01 -1.327 2.442 0.1628E-01 stilbite 0.2079E-02 -2.682 1.465 0.166 75.99 0.6833 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.6094E+00 0.6094E+00 1.0000 -0.215 daphnite 0.3773E+00 0.3773E+00 1.0000 -0.423 chlorite-Mn 0.1331E-01 0.1331E-01 1.0000 -1.876 hematite 0.1000E+01 0.1000E+01 1.0000 0.000 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 muscovite 0.1000E+01 0.1000E+01 1.0000 0.000 paragonite 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 1.927769 g Volume = 0.842305 cm3 Porosity: 51.0174% V(tot) - V(min): 0.87730E+00 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 1.7990000 g log = 0.2550 Original solution: 1000.0103000 g Original solution / Rock added: 555.87 (Water/Rock Ratio), log = 2.7450 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0203 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.1000E+01 0.9860 0.1006E+01 0.1020E+01 CO2,gas 0.1218E-05 1.0071 0.1251E-05 0.1243E-05 CH4,gas 0.2411E-16 1.0125 0.2491E-16 0.2460E-16 H2,gas 0.6545E-06 1.0005 0.6682E-06 0.6678E-06 H2S,gas 0.1528E-14 0.9960 0.1553E-14 0.1559E-14 S2,gas 0.1988E-36 1.0000 0.2028E-36 0.2028E-36 CO,gas 0.2184E-15 1.0000 0.2229E-15 0.2229E-15 SO3,gas 0.2129E-38 1.0000 0.2172E-38 0.2172E-38 SO2,gas 0.5535E-22 1.0000 0.5647E-22 0.5647E-22 HCl,gas 0.2187E-16 1.0000 0.2231E-16 0.2231E-16 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 32 apatite-OH -18.15 -18.15 0.00 0.000 0.60662E-11 46 clinochlore 39.07 39.07 0.00 0.000 0.00000E+00 47 daphnite 28.97 28.97 0.00 0.000 0.00000E+00 48 chlorite-Mn 46.87 46.87 0.00 0.000 0.00000E+00 90 hematite 12.57 12.57 0.00 0.000 -0.90992E-11 116 microcline -2.49 -2.49 0.00 0.000 0.15165E-11 120 muscovite 2.58 2.58 0.00 0.000 -0.18198E-10 121 paragonite 4.24 4.24 0.00 0.000 -0.10616E-10 163 stilbite -7.52 -7.52 0.00 0.000 0.15165E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -14.26 -7.60 -2.534 0.12979E+05 -5.903 3 CH4,gas 4.54 -13.76 -18.30 -4.576 0.31251E+05 -16.604 4 H2,gas 8.00 0.13 -7.87 -4.499 0.13445E+05 -6.175 5 H2S,gas -6.23 -22.74 -16.51 -8.254 0.28186E+05 -14.809 6 S2,gas -7.34 -45.73 -38.39 -5.906 0.65553E+05 -36.693 7 CO,gas 3.21 -14.14 -17.35 -5.339 0.29626E+05 -15.652 8 SO3,gas 17.12 -23.24 -40.36 -10.091 0.68917E+05 -38.663 9 SO2,gas 0.83 -23.12 -23.95 -6.386 0.40889E+05 -22.248 10 HCl,gas 5.19 -13.16 -18.35 -9.175 0.31333E+05 -16.651 11 acmite 7.71 6.24 -1.47 -0.153 0.25166E+04 15 albite-high 0.69 -0.83 -1.52 -0.117 0.25997E+04 16 albite -0.38 -0.83 -0.45 -0.034 0.76090E+03 19 spessartine 24.46 20.54 -3.92 -0.196 0.66861E+04 20 analcite 3.32 2.49 -0.83 -0.093 0.14251E+04 21 andalusite 5.00 1.75 -3.25 -0.325 0.55481E+04 22 andradite 39.01 34.49 -4.51 -0.235 0.77085E+04 26 annite 20.12 16.55 -3.57 -0.198 0.60993E+04 27 phlogopite 27.06 23.24 -3.83 -0.213 0.65326E+04 29 anorthite 12.71 9.06 -3.65 -0.281 0.62302E+04 35 aragonite 0.97 -3.64 -4.60 -1.534 0.78580E+04 36 brucite 12.57 8.58 -3.99 -0.799 0.68188E+04 37 calcite 0.81 -3.64 -4.45 -1.482 0.75938E+04 38 carnegieite-low 9.02 5.80 -3.22 -0.460 0.54970E+04 39 carnegieite-high 10.09 5.80 -4.29 -0.613 0.73240E+04 40 carpholite-Mg 8.58 7.01 -1.57 -0.105 0.26833E+04 41 carpholite-Fe 6.71 4.78 -1.93 -0.129 0.32975E+04 42 celadonite 5.34 2.77 -2.57 -0.151 0.43878E+04 43 celadonite-Fe 3.88 0.54 -3.33 -0.196 0.56924E+04 44 chrysotile 23.89 19.09 -4.80 -0.400 0.81969E+04 50 chloritoid-Mg 13.20 10.33 -2.87 -0.191 0.49012E+04 51 chloritoid-Fe 9.17 8.10 -1.08 -0.072 0.18364E+04 52 chloritoid-Mn 11.40 10.23 -1.17 -0.078 0.20056E+04 54 coesite -2.38 -3.32 -0.94 -0.314 0.16061E+04 59 corundum 8.38 5.07 -3.31 -0.301 0.56589E+04 61 cristobalite -2.56 -3.32 -0.76 -0.252 0.12915E+04 63 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71234E+04 65 diaspore 2.87 2.53 -0.34 -0.057 0.57923E+03 67 diopside 16.18 12.57 -3.61 -0.361 0.61703E+04 68 hedenbergite 14.21 10.34 -3.87 -0.387 0.66075E+04 75 epidote 24.67 22.65 -2.02 -0.098 0.34422E+04 76 clinozoisite 22.81 18.91 -3.90 -0.177 0.66604E+04 77 epidote-Fe 29.84 26.40 -3.44 -0.179 0.58707E+04 78 fayalite 14.05 9.38 -4.67 -0.667 0.79749E+04 83 gibbsite 4.08 2.53 -1.54 -0.221 0.26378E+04 87 greenalite 16.14 12.40 -3.74 -0.311 0.63777E+04 91 heulandite -5.83 -7.52 -1.69 -0.077 0.28938E+04 95 jadeite 4.22 2.49 -1.73 -0.173 0.29506E+04 97 kalsilite 7.58 4.15 -3.44 -0.491 0.58685E+04 98 kaolinite -1.33 -1.56 -0.23 -0.021 0.39569E+03 99 kyanite 4.88 1.75 -3.12 -0.312 0.53340E+04 101 laumontite 2.88 2.43 -0.46 -0.030 0.77743E+03 102 lawsonite 9.62 9.06 -0.55 -0.037 0.94686E+03 103 leucite 4.12 0.83 -3.29 -0.329 0.56153E+04 105 lizardite 23.24 19.09 -4.15 -0.346 0.70895E+04 107 magnetite 20.09 18.91 -1.18 -0.096 0.20068E+04 108 minnesotaite 10.39 5.77 -4.62 -0.272 0.78837E+04 113 margarite 17.32 14.13 -3.19 -0.128 0.54522E+04 122 nepheline 8.34 5.80 -2.54 -0.362 0.43293E+04 134 phlogopite-Na 29.65 24.90 -4.75 -0.264 0.81123E+04 136 prehnite 19.37 16.37 -3.00 -0.177 0.51242E+04 137 prehnite-Fe 22.50 20.12 -2.38 -0.143 0.40610E+04 138 pumpellyite-Fe 46.27 41.62 -4.65 -0.103 0.79352E+04 145 pyroxmangite 7.40 5.16 -2.24 -0.448 0.38267E+04 146 pyrophyllite -6.18 -8.20 -2.02 -0.126 0.34528E+04 147 quartz -2.99 -3.32 -0.33 -0.109 0.55883E+03 151 rhodochrosite -0.98 -5.79 -4.81 -1.604 0.82148E+04 152 rhodonite 7.45 5.16 -2.29 -0.458 0.39069E+04 153 sanidine -1.28 -2.49 -1.21 -0.093 0.20677E+04 156 sillimanite 5.26 1.75 -3.51 -0.351 0.59921E+04 164 stilpnomelane-Fe 13.02 12.73 -0.29 -0.009 0.49093E+03 165 stilpnomelane-Mg 27.44 23.88 -3.57 -0.106 0.60893E+04 168 sudoite 21.08 17.34 -3.74 -0.121 0.63851E+04 171 talc 16.49 12.46 -4.03 -0.237 0.68858E+04 174 tephroite 18.09 13.63 -4.45 -0.636 0.76051E+04 177 topaz-H 4.62 1.75 -2.87 -0.261 0.48941E+04 178 tridymite -2.63 -3.32 -0.69 -0.230 0.11788E+04 187 wairakite 3.95 2.43 -1.52 -0.090 0.25994E+04 188 walstromite 11.51 7.31 -4.20 -0.840 0.71712E+04 189 wollastonite 10.46 7.31 -3.15 -0.630 0.53817E+04 190 pseudo-wollastonite 11.00 7.31 -3.69 -0.738 0.63015E+04 191 zoisite 22.85 18.91 -3.94 -0.179 0.67344E+04 192 akaganeite 7.75 6.28 -1.47 -0.318 0.25125E+04 193 beidellite-Ca -1.65 -4.51 -2.87 -0.177 0.48973E+04 194 beidellite-H -2.33 -6.27 -3.94 -0.251 0.67288E+04 195 beidellite-K -1.52 -4.64 -3.12 -0.191 0.53276E+04 196 beidellite-Mg -1.79 -4.85 -3.06 -0.189 0.52289E+04 197 beidellite-Na -1.34 -4.09 -2.75 -0.168 0.46979E+04 199 chalcedony -2.80 -3.32 -0.51 -0.171 0.87812E+03 201 montmorillonite-Ca -2.29 -4.45 -2.16 -0.134 0.36890E+04 202 montmorillonite-K -2.24 -4.58 -2.34 -0.143 0.39975E+04 203 montmorillonite-Mg -2.48 -4.79 -2.31 -0.143 0.39439E+04 204 montmorillonite-Na -2.04 -4.03 -1.99 -0.122 0.34035E+04 205 nontronite-Ca 3.21 2.98 -0.23 -0.015 0.39449E+03 206 nontronite-H 2.53 1.23 -1.30 -0.087 0.22240E+04 207 nontronite-K 3.34 2.86 -0.48 -0.031 0.82618E+03 208 nontronite-Mg 3.07 2.65 -0.43 -0.028 0.73341E+03 209 nontronite-Na 3.52 3.40 -0.12 -0.007 0.19815E+03 224 tobermorite 9.82 5.53 -4.29 -1.170 0.73221E+04 233 boehmite 4.41 2.53 -1.87 -0.312 0.31962E+04 235 ferrous-oxide 9.81 6.35 -3.47 -0.866 0.59175E+04 240 silica-amorphous -2.09 -3.32 -1.23 -0.408 0.20923E+04 242 an20ab80 2.02 1.15 -0.87 -0.067 0.14839E+04 243 an25ab75 2.65 1.64 -1.00 -0.077 0.17116E+04 244 an30ab70 3.28 2.14 -1.14 -0.088 0.19490E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 0.0400000 g Current total amount of reactant added: 1.7990000 g New total amount of reactant added: 1.8390000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.4572E-13 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 7 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 1.8390000 Water: Moles liquid = 0.5549E+02 kg liquid = 0.9997E+00 Moles total = 0.5549E+02 kg total = 0.9996E+00 Activity = 1.0000 Stoichiometric ionic strength = .1520202E-02 Osmotic coef. = 0.9778 True ionic strength = .2385236E-02 Chg. balance for total moles = 0.4572E-13 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.57462E-09 -9.2406 0.53052E-09 -9.2753 0.92326E+00 -0.0347 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13793E-03 -3.8603 0.12722E-03 -3.8954 0.92237E+00 -0.0351 4 SO4-- 0.25498E-04 -4.5935 0.19512E-04 -4.7097 0.76525E+00 -0.1162 5 HCO3- 0.10899E-04 -4.9626 0.10055E-04 -4.9976 0.92258E+00 -0.0350 6 HS- 0.37839E-13 -13.4221 0.34902E-13 -13.4571 0.92239E+00 -0.0351 7 Al+++ 0.91458E-25 -25.0388 0.51118E-25 -25.2914 0.55892E+00 -0.2527 8 H4SiO4 0.47649E-03 -3.3219 0.47649E-03 -3.3219 0.10000E+01 0.0000 9 Ca++ 0.16934E-07 -7.7712 0.12944E-07 -7.8879 0.76437E+00 -0.1167 10 Mg++ 0.13952E-09 -9.8554 0.10657E-09 -9.9724 0.76382E+00 -0.1170 11 Fe++ 0.82302E-12 -12.0846 0.62875E-12 -12.2015 0.76395E+00 -0.1169 12 K+ 0.50649E-04 -4.2954 0.46730E-04 -4.3304 0.92262E+00 -0.0350 13 Na+ 0.22998E-02 -2.6383 0.21212E-02 -2.6734 0.92235E+00 -0.0351 14 Mn++ 0.11058E-09 -9.9563 0.84489E-10 -10.0732 0.76405E+00 -0.1169 15 HPO4-- 0.69906E-05 -5.1555 0.53497E-05 -5.2717 0.76527E+00 -0.1162 16 HSiO3- 0.90922E-03 -3.0413 0.83864E-03 -3.0764 0.92237E+00 -0.0351 17 Ca(HSiO3)+ 0.26794E-09 -9.5720 0.24722E-09 -9.6069 0.92265E+00 -0.0350 18 Mg(HSiO3)+ 0.27453E-11 -11.5614 0.25329E-11 -11.5964 0.92265E+00 -0.0350 19 NaHSiO3,aq 0.28772E-04 -4.5410 0.28772E-04 -4.5410 0.10000E+01 0.0000 20 AlO+ 0.26780E-13 -13.5722 0.24708E-13 -13.6072 0.92265E+00 -0.0350 21 AlOH+2 0.85415E-19 -19.0685 0.65271E-19 -19.1853 0.76417E+00 -0.1168 22 HAlO2,aq 0.92750E-08 -8.0327 0.92750E-08 -8.0327 0.10000E+01 0.0000 23 AlO2- 0.41969E-04 -4.3771 0.38700E-04 -4.4123 0.92210E+00 -0.0352 24 CH4,aq 0.17479E-19 -19.7575 0.17471E-19 -19.7577 0.99953E+00 -0.0002 29 CO,aq 0.14785E-18 -18.8302 0.14785E-18 -18.8302 0.10000E+01 0.0000 30 CO2,aq 0.11404E-07 -7.9430 0.11398E-07 -7.9432 0.99953E+00 -0.0002 31 CO3-2 0.21640E-05 -5.6647 0.16555E-05 -5.7811 0.76499E+00 -0.1163 32 CaCO3,aq 0.26869E-09 -9.5708 0.26869E-09 -9.5708 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.36008E-11 -11.4436 0.33223E-11 -11.4786 0.92265E+00 -0.0350 34 CaCl+ 0.28884E-11 -11.5393 0.26650E-11 -11.5743 0.92265E+00 -0.0350 35 CaCl2,aq 0.80552E-16 -16.0939 0.80552E-16 -16.0939 0.10000E+01 0.0000 36 CaOH+ 0.18847E-08 -8.7248 0.17389E-08 -8.7597 0.92265E+00 -0.0350 37 CaSO4,aq 0.80201E-10 -10.0958 0.80201E-10 -10.0958 0.10000E+01 0.0000 38 HCl,aq 0.12368E-13 -13.9077 0.12368E-13 -13.9077 0.10000E+01 0.0000 43 FeCl+ 0.13723E-15 -15.8626 0.12661E-15 -15.8975 0.92265E+00 -0.0350 46 FeO,aq 0.86823E-10 -10.0614 0.86823E-10 -10.0614 0.10000E+01 0.0000 47 FeOH+ 0.41812E-10 -10.3787 0.38578E-10 -10.4137 0.92265E+00 -0.0350 48 HFeO2- 0.18565E-08 -8.7313 0.17124E-08 -8.7664 0.92237E+00 -0.0351 49 FeO+ 0.43889E-14 -14.3576 0.40494E-14 -14.3926 0.92265E+00 -0.0350 51 FeO2- 0.31918E-08 -8.4960 0.29440E-08 -8.5311 0.92237E+00 -0.0351 52 HFeO2,aq 0.19864E-09 -9.7019 0.19864E-09 -9.7019 0.10000E+01 0.0000 53 H2,aq 0.51659E-09 -9.2869 0.51635E-09 -9.2871 0.99953E+00 -0.0002 54 KCl,aq 0.10775E-09 -9.9676 0.10775E-09 -9.9676 0.10000E+01 0.0000 55 KHSO4,aq 0.13677E-17 -17.8640 0.13677E-17 -17.8640 0.10000E+01 0.0000 56 KOH,aq 0.37616E-07 -7.4246 0.37616E-07 -7.4246 0.10000E+01 0.0000 57 KSO4- 0.15340E-07 -7.8142 0.14149E-07 -7.8493 0.92237E+00 -0.0351 58 MgCO3,aq 0.55447E-12 -12.2561 0.55447E-12 -12.2561 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.30291E-13 -13.5187 0.27948E-13 -13.5536 0.92265E+00 -0.0350 60 MgCl+ 0.21553E-13 -13.6665 0.19886E-13 -13.7015 0.92265E+00 -0.0350 61 MgOH+ 0.85858E-10 -10.0662 0.79216E-10 -10.1012 0.92265E+00 -0.0350 63 MnO,aq 0.31088E-09 -9.5074 0.31088E-09 -9.5074 0.10000E+01 0.0000 64 MnOH+ 0.52194E-09 -9.2824 0.48157E-09 -9.3173 0.92265E+00 -0.0350 65 MnO2-2 0.47918E-13 -13.3195 0.36656E-13 -13.4358 0.76499E+00 -0.1163 66 HMnO2- 0.46191E-11 -11.3354 0.42605E-11 -11.3705 0.92237E+00 -0.0351 69 MnCl+ 0.71741E-13 -13.1442 0.66191E-13 -13.1792 0.92265E+00 -0.0350 70 MnSO4,aq 0.47593E-12 -12.3225 0.47593E-12 -12.3225 0.10000E+01 0.0000 71 NaCl,aq 0.89437E-07 -7.0485 0.89437E-07 -7.0485 0.10000E+01 0.0000 72 NaOH,aq 0.17179E-05 -5.7650 0.17179E-05 -5.7650 0.10000E+01 0.0000 74 OH- 0.11811E-02 -2.9277 0.10891E-02 -2.9629 0.92210E+00 -0.0352 79 HPO3-2 0.11253E-16 -16.9487 0.86083E-17 -17.0651 0.76499E+00 -0.1163 82 H3PO4,aq 0.10531E-13 -13.9775 0.10531E-13 -13.9775 0.10000E+01 0.0000 83 H2PO4- 0.56754E-07 -7.2460 0.52355E-07 -7.2810 0.92251E+00 -0.0350 84 PO4-3 0.14605E-07 -7.8355 0.82273E-08 -8.0847 0.56332E+00 -0.2492 87 H2P2O7-2 0.28096E-15 -15.5514 0.21493E-15 -15.6677 0.76499E+00 -0.1163 88 HP2O7-3 0.14472E-12 -12.8395 0.80895E-13 -13.0921 0.55897E+00 -0.2526 89 P2O7-4 0.10062E-12 -12.9973 0.36427E-13 -13.4386 0.36203E+00 -0.4413 90 H2S,aq 0.57254E-16 -16.2422 0.57227E-16 -16.2424 0.99953E+00 -0.0002 97 SO3-2 0.17075E-14 -14.7676 0.13093E-14 -14.8830 0.76676E+00 -0.1153 98 HSO3- 0.47150E-16 -16.3265 0.43490E-16 -16.3616 0.92237E+00 -0.0351 99 HSO4- 0.10811E-10 -10.9661 0.99760E-11 -11.0010 0.92279E+00 -0.0349 Charge balance for all species = 0.4570E-13 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.5746207E-09 -.2290858E-02 -.2308579E+01 0.0000 2 H2O 0.1000000E+01 0.5550858E+02 0.9998009E+06 0.0000 3 Cl- 0.1379317E-03 0.1380212E-03 0.4892274E+01 5.3799 4 SO4-- 0.2549774E-04 0.2551346E-04 0.2450367E+01 13.8409 5 HCO3- 0.1089875E-04 0.1307446E-04 0.7976050E+00 4.2777 6 HS- 0.3783892E-13 -.2946156E-09 -.9741549E-05 -4.1819 7 Al+++ 0.9145825E-25 0.4197832E-04 0.1132408E+01 2.5345 8 H4SiO4 0.4764875E-03 0.1414484E-02 0.1359261E+03 -3.3219 9 Ca++ 0.1693419E-07 0.1944217E-07 0.7790453E-03 10.6627 10 Mg++ 0.1395168E-09 0.2287259E-09 0.5559657E-05 8.5782 11 Fe++ 0.8230249E-12 0.5376356E-08 0.3001925E-03 6.3491 12 K+ 0.5064878E-04 0.5070184E-04 0.1982141E+01 4.9449 13 Na+ 0.2299836E-02 0.2330415E-02 0.5356491E+02 6.6019 14 Mn++ 0.1105804E-09 0.9486144E-09 0.5210441E-04 8.4774 15 HPO4-- 0.6990564E-05 0.7061923E-05 0.6776589E+00 13.2789 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.3043807E-01 -.2290077E-02 -.2814799E-01 0.0000000E+00 2 H2O 0.5548520E+02 0.5548966E+02 -.4457940E-02 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.7646943E-04 0.2550476E-04 0.5096466E-04 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.5096496E-04 -.2945151E-09 -.5096466E-04 0.0000000E+00 7 Al+++ 0.5996504E-02 0.4196401E-04 0.5954540E-02 0.0000000E+00 8 H4SiO4 0.1914911E-01 0.1414002E-02 0.1773511E-01 0.0000000E+00 9 Ca++ 0.2129583E-02 0.1943554E-07 0.2129564E-02 0.0000000E+00 10 Mg++ 0.1459524E-02 0.2286480E-09 0.1459524E-02 0.0000000E+00 11 Fe++ 0.1311223E-02 0.5374523E-08 0.1311217E-02 0.0000000E+00 12 K+ 0.3904459E-03 0.5068456E-04 0.3397613E-03 0.0000000E+00 13 Na+ 0.2468464E-02 0.2329621E-02 0.1388433E-03 0.0000000E+00 14 Mn++ 0.3188568E-04 0.9482910E-09 0.3188473E-04 0.0000000E+00 15 HPO4-- 0.1088242E-04 0.7059516E-05 0.3822908E-05 0.0000000E+00 Chg. balance for solid moles: -.2099E-17 Mass of aqueous solution: 0.999862E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 1.8390000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) apatite-OH 0.1274E-05 -5.895 0.6401E-03 -3.194 0.3245E-01 0.2034E-03 clinochlore 0.2919E-03 -3.535 0.1622 -0.790 8.226 0.6172E-01 daphnite 0.1807E-03 -3.743 0.1289 -0.890 6.537 0.3907E-01 chlorite-Mn 0.6377E-05 -5.195 0.4521E-02 -2.345 0.2292 0.1441E-02 hematite 0.2039E-03 -3.691 0.3256E-01 -1.487 1.651 0.6171E-02 microcline 0.3428E-03 -3.465 0.9542E-01 -1.020 4.838 0.3727E-01 muscovite -.3050E-05 1.000 -.1215E-02 1.000 -.6159E-01 -.4295E-03 paragonite 0.1388E-03 -3.857 0.5307E-01 -1.275 2.690 0.1834E-01 stilbite 0.2123E-02 -2.673 1.496 0.175 75.86 0.6979 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.6094E+00 0.6094E+00 1.0000 -0.215 daphnite 0.3773E+00 0.3773E+00 1.0000 -0.423 chlorite-Mn 0.1331E-01 0.1331E-01 1.0000 -1.876 hematite 0.1000E+01 0.1000E+01 1.0000 0.000 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 muscovite 0.1000E+01 0.1000E+01 1.0000 0.000 paragonite 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 1.972423 g Volume = 0.861667 cm3 Porosity: 50.3534% V(tot) - V(min): 0.87393E+00 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 1.8390000 g log = 0.2646 Original solution: 1000.0103000 g Original solution / Rock added: 543.78 (Water/Rock Ratio), log = 2.7354 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0203 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.1000E+01 0.9860 0.1006E+01 0.1020E+01 CO2,gas 0.1187E-05 1.0071 0.1219E-05 0.1211E-05 CH4,gas 0.2489E-16 1.0125 0.2572E-16 0.2540E-16 H2,gas 0.6641E-06 1.0005 0.6779E-06 0.6775E-06 H2S,gas 0.1548E-14 0.9960 0.1573E-14 0.1579E-14 S2,gas 0.1981E-36 1.0000 0.2021E-36 0.2021E-36 CO,gas 0.2159E-15 1.0000 0.2203E-15 0.2203E-15 SO3,gas 0.2035E-38 1.0000 0.2076E-38 0.2076E-38 SO2,gas 0.5367E-22 1.0000 0.5476E-22 0.5476E-22 HCl,gas 0.2139E-16 1.0000 0.2182E-16 0.2182E-16 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 32 apatite-OH -18.15 -18.15 0.00 0.000 0.60662E-11 46 clinochlore 39.07 39.07 0.00 0.000 0.00000E+00 47 daphnite 28.97 28.97 0.00 0.000 0.12132E-10 48 chlorite-Mn 46.87 46.87 0.00 0.000 0.36397E-10 90 hematite 12.57 12.57 0.00 0.000 -0.90992E-11 116 microcline -2.49 -2.49 0.00 0.000 0.15165E-11 121 paragonite 4.24 4.24 0.00 0.000 -0.10616E-10 163 stilbite -7.52 -7.52 0.00 0.000 0.15165E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -14.27 -7.61 -2.538 0.12999E+05 -5.914 3 CH4,gas 4.54 -13.75 -18.29 -4.572 0.31228E+05 -16.590 4 H2,gas 8.00 0.13 -7.87 -4.496 0.13434E+05 -6.169 5 H2S,gas -6.23 -22.73 -16.50 -8.251 0.28177E+05 -14.803 6 S2,gas -7.34 -45.73 -38.39 -5.907 0.65556E+05 -36.694 7 CO,gas 3.21 -14.14 -17.36 -5.340 0.29635E+05 -15.657 8 SO3,gas 17.12 -23.26 -40.38 -10.095 0.68951E+05 -38.683 9 SO2,gas 0.83 -23.13 -23.96 -6.389 0.40912E+05 -22.262 10 HCl,gas 5.19 -13.17 -18.36 -9.180 0.31349E+05 -16.661 11 acmite 7.71 6.24 -1.47 -0.153 0.25076E+04 15 albite-high 0.69 -0.83 -1.52 -0.117 0.25997E+04 16 albite -0.38 -0.83 -0.45 -0.034 0.76090E+03 19 spessartine 24.46 20.54 -3.92 -0.196 0.66968E+04 20 analcite 3.32 2.49 -0.83 -0.092 0.14162E+04 21 andalusite 5.00 1.75 -3.25 -0.325 0.55571E+04 22 andradite 39.01 34.59 -4.42 -0.230 0.75478E+04 26 annite 20.12 16.56 -3.56 -0.198 0.60832E+04 27 phlogopite 27.06 23.25 -3.82 -0.212 0.65165E+04 29 anorthite 12.71 9.09 -3.62 -0.279 0.61855E+04 35 aragonite 0.97 -3.61 -4.58 -1.526 0.78147E+04 36 brucite 12.57 8.58 -3.99 -0.798 0.68134E+04 37 calcite 0.81 -3.61 -4.42 -1.474 0.75505E+04 38 carnegieite-low 9.02 5.81 -3.21 -0.458 0.54791E+04 39 carnegieite-high 10.09 5.81 -4.28 -0.611 0.73061E+04 40 carpholite-Mg 8.58 7.00 -1.58 -0.105 0.26958E+04 41 carpholite-Fe 6.71 4.77 -1.94 -0.129 0.33100E+04 42 celadonite 5.34 2.77 -2.57 -0.151 0.43913E+04 43 celadonite-Fe 3.88 0.54 -3.34 -0.196 0.56959E+04 44 chrysotile 23.89 19.09 -4.80 -0.400 0.81987E+04 50 chloritoid-Mg 13.20 10.33 -2.87 -0.192 0.49047E+04 51 chloritoid-Fe 9.17 8.10 -1.08 -0.072 0.18399E+04 52 chloritoid-Mn 11.40 10.22 -1.18 -0.078 0.20092E+04 54 coesite -2.38 -3.32 -0.95 -0.315 0.16151E+04 59 corundum 8.38 5.07 -3.31 -0.301 0.56589E+04 61 cristobalite -2.56 -3.32 -0.76 -0.254 0.13004E+04 63 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71234E+04 65 diaspore 2.87 2.53 -0.34 -0.057 0.57923E+03 67 diopside 16.18 12.60 -3.58 -0.358 0.61202E+04 68 hedenbergite 14.21 10.37 -3.84 -0.384 0.65574E+04 75 epidote 24.67 22.71 -1.96 -0.095 0.33439E+04 76 clinozoisite 22.81 18.96 -3.84 -0.175 0.65621E+04 77 epidote-Fe 29.84 26.46 -3.38 -0.176 0.57724E+04 78 fayalite 14.05 9.38 -4.67 -0.667 0.79731E+04 83 gibbsite 4.08 2.53 -1.54 -0.221 0.26378E+04 87 greenalite 16.14 12.40 -3.74 -0.311 0.63794E+04 91 heulandite -5.83 -7.52 -1.69 -0.077 0.28938E+04 95 jadeite 4.22 2.49 -1.72 -0.172 0.29417E+04 97 kalsilite 7.58 4.16 -3.43 -0.490 0.58507E+04 98 kaolinite -1.33 -1.57 -0.24 -0.022 0.41356E+03 99 kyanite 4.88 1.75 -3.13 -0.313 0.53430E+04 101 laumontite 2.88 2.44 -0.44 -0.029 0.75064E+03 102 lawsonite 9.62 9.09 -0.53 -0.035 0.90220E+03 103 leucite 4.12 0.84 -3.28 -0.328 0.56063E+04 105 lizardite 23.24 19.09 -4.15 -0.346 0.70913E+04 107 magnetite 20.09 18.92 -1.17 -0.096 0.20014E+04 108 minnesotaite 10.39 5.76 -4.63 -0.272 0.79034E+04 113 margarite 17.32 14.16 -3.17 -0.127 0.54076E+04 120 muscovite 2.58 2.58 0.00 0.000 -0.18198E-10 122 nepheline 8.34 5.81 -2.53 -0.361 0.43115E+04 134 phlogopite-Na 29.65 24.91 -4.74 -0.263 0.80962E+04 136 prehnite 19.37 16.43 -2.94 -0.173 0.50259E+04 137 prehnite-Fe 22.50 20.18 -2.32 -0.140 0.39628E+04 138 pumpellyite-Fe 46.27 41.74 -4.53 -0.101 0.77333E+04 145 pyroxmangite 7.40 5.16 -2.24 -0.449 0.38303E+04 146 pyrophyllite -6.18 -8.22 -2.04 -0.128 0.34885E+04 147 quartz -2.99 -3.32 -0.33 -0.111 0.56776E+03 151 rhodochrosite -0.98 -5.80 -4.82 -1.606 0.82287E+04 152 rhodonite 7.45 5.16 -2.29 -0.458 0.39105E+04 153 sanidine -1.28 -2.49 -1.21 -0.093 0.20677E+04 156 sillimanite 5.26 1.75 -3.51 -0.351 0.60010E+04 164 stilpnomelane-Fe 13.02 12.71 -0.31 -0.009 0.52220E+03 165 stilpnomelane-Mg 27.44 23.86 -3.58 -0.107 0.61206E+04 168 sudoite 21.08 17.33 -3.75 -0.121 0.64012E+04 171 talc 16.49 12.45 -4.04 -0.238 0.69054E+04 174 tephroite 18.09 13.63 -4.45 -0.636 0.76033E+04 177 topaz-H 4.62 1.75 -2.87 -0.261 0.49030E+04 178 tridymite -2.63 -3.32 -0.70 -0.232 0.11877E+04 187 wairakite 3.95 2.44 -1.51 -0.089 0.25726E+04 188 walstromite 11.51 7.34 -4.17 -0.834 0.71176E+04 189 wollastonite 10.46 7.34 -3.12 -0.624 0.53281E+04 190 pseudo-wollastonite 11.00 7.34 -3.66 -0.732 0.62479E+04 191 zoisite 22.85 18.96 -3.89 -0.177 0.66362E+04 192 akaganeite 7.75 6.28 -1.47 -0.318 0.25125E+04 193 beidellite-Ca -1.65 -4.53 -2.88 -0.178 0.49198E+04 194 beidellite-H -2.33 -6.29 -3.96 -0.253 0.67616E+04 195 beidellite-K -1.52 -4.65 -3.13 -0.192 0.53516E+04 196 beidellite-Mg -1.79 -4.87 -3.08 -0.191 0.52608E+04 197 beidellite-Na -1.34 -4.11 -2.77 -0.169 0.47218E+04 199 chalcedony -2.80 -3.32 -0.52 -0.173 0.88706E+03 201 montmorillonite-Ca -2.29 -4.47 -2.17 -0.135 0.37127E+04 202 montmorillonite-K -2.24 -4.59 -2.36 -0.144 0.40226E+04 203 montmorillonite-Mg -2.48 -4.81 -2.33 -0.144 0.39770E+04 204 montmorillonite-Na -2.04 -4.05 -2.01 -0.123 0.34286E+04 205 nontronite-Ca 3.21 2.97 -0.24 -0.016 0.41696E+03 206 nontronite-H 2.53 1.21 -1.32 -0.089 0.22568E+04 207 nontronite-K 3.34 2.84 -0.50 -0.032 0.85012E+03 208 nontronite-Mg 3.07 2.63 -0.45 -0.029 0.76531E+03 209 nontronite-Na 3.52 3.39 -0.13 -0.008 0.22209E+03 224 tobermorite 9.82 5.56 -4.26 -1.163 0.72790E+04 233 boehmite 4.41 2.53 -1.87 -0.312 0.31962E+04 235 ferrous-oxide 9.81 6.35 -3.46 -0.866 0.59121E+04 240 silica-amorphous -2.09 -3.32 -1.23 -0.410 0.21012E+04 242 an20ab80 2.02 1.15 -0.86 -0.066 0.14750E+04 243 an25ab75 2.65 1.65 -1.00 -0.077 0.17005E+04 244 an30ab70 3.28 2.15 -1.13 -0.087 0.19356E+04 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 6 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 1.8390000 Water: Moles liquid = 0.5549E+02 kg liquid = 0.9997E+00 Moles total = 0.5549E+02 kg total = 0.9996E+00 Activity = 1.0000 Stoichiometric ionic strength = .1520837E-02 Osmotic coef. = 0.9778 True ionic strength = .2387299E-02 Chg. balance for total moles = 0.4572E-13 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.57496E-09 -9.2404 0.53082E-09 -9.2751 0.92323E+00 -0.0347 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13793E-03 -3.8603 0.12722E-03 -3.8954 0.92234E+00 -0.0351 4 SO4-- 0.25498E-04 -4.5935 0.19510E-04 -4.7097 0.76518E+00 -0.1162 5 HCO3- 0.10900E-04 -4.9626 0.10056E-04 -4.9976 0.92256E+00 -0.0350 6 HS- 0.37684E-13 -13.4238 0.34758E-13 -13.4589 0.92237E+00 -0.0351 7 Al+++ 0.91340E-25 -25.0393 0.51040E-25 -25.2921 0.55879E+00 -0.2528 8 H4SiO4 0.47797E-03 -3.3206 0.47797E-03 -3.3206 0.10000E+01 0.0000 9 Ca++ 0.16697E-07 -7.7774 0.12762E-07 -7.8941 0.76429E+00 -0.1167 10 Mg++ 0.13961E-09 -9.8551 0.10662E-09 -9.9721 0.76374E+00 -0.1171 11 Fe++ 0.82357E-12 -12.0843 0.62910E-12 -12.2013 0.76387E+00 -0.1170 12 K+ 0.50370E-04 -4.2978 0.46471E-04 -4.3328 0.92260E+00 -0.0350 13 Na+ 0.23020E-02 -2.6379 0.21232E-02 -2.6730 0.92232E+00 -0.0351 14 Mn++ 0.11065E-09 -9.9560 0.84536E-10 -10.0730 0.76397E+00 -0.1169 15 HPO4-- 0.71640E-05 -5.1448 0.54819E-05 -5.2611 0.76519E+00 -0.1162 16 HSiO3- 0.91156E-03 -3.0402 0.84078E-03 -3.0753 0.92234E+00 -0.0351 17 Ca(HSiO3)+ 0.26485E-09 -9.5770 0.24435E-09 -9.6120 0.92263E+00 -0.0350 18 Mg(HSiO3)+ 0.27539E-11 -11.5601 0.25408E-11 -11.5950 0.92263E+00 -0.0350 19 NaHSiO3,aq 0.28872E-04 -4.5395 0.28872E-04 -4.5395 0.10000E+01 0.0000 20 AlO+ 0.26709E-13 -13.5733 0.24643E-13 -13.6083 0.92263E+00 -0.0350 21 AlOH+2 0.85245E-19 -19.0693 0.65134E-19 -19.1862 0.76409E+00 -0.1169 22 HAlO2,aq 0.92451E-08 -8.0341 0.92451E-08 -8.0341 0.10000E+01 0.0000 23 AlO2- 0.41811E-04 -4.3787 0.38553E-04 -4.4139 0.92208E+00 -0.0352 24 CH4,aq 0.17410E-19 -19.7592 0.17402E-19 -19.7594 0.99953E+00 -0.0002 29 CO,aq 0.14777E-18 -18.8304 0.14777E-18 -18.8304 0.10000E+01 0.0000 30 CO2,aq 0.11411E-07 -7.9427 0.11405E-07 -7.9429 0.99953E+00 -0.0002 31 CO3-2 0.21631E-05 -5.6649 0.16546E-05 -5.7813 0.76491E+00 -0.1164 32 CaCO3,aq 0.26477E-09 -9.5771 0.26477E-09 -9.5771 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.35503E-11 -11.4497 0.32756E-11 -11.4847 0.92263E+00 -0.0350 34 CaCl+ 0.28477E-11 -11.5455 0.26274E-11 -11.5805 0.92263E+00 -0.0350 35 CaCl2,aq 0.79412E-16 -16.1001 0.79412E-16 -16.1001 0.10000E+01 0.0000 36 CaOH+ 0.18571E-08 -8.7312 0.17134E-08 -8.7661 0.92263E+00 -0.0350 37 CaSO4,aq 0.79064E-10 -10.1020 0.79064E-10 -10.1020 0.10000E+01 0.0000 38 HCl,aq 0.12375E-13 -13.9075 0.12375E-13 -13.9075 0.10000E+01 0.0000 43 FeCl+ 0.13730E-15 -15.8623 0.12668E-15 -15.8973 0.92263E+00 -0.0350 46 FeO,aq 0.86773E-10 -10.0616 0.86773E-10 -10.0616 0.10000E+01 0.0000 47 FeOH+ 0.41813E-10 -10.3787 0.38578E-10 -10.4137 0.92263E+00 -0.0350 48 HFeO2- 0.18544E-08 -8.7318 0.17104E-08 -8.7669 0.92234E+00 -0.0351 49 FeO+ 0.43915E-14 -14.3574 0.40517E-14 -14.3924 0.92263E+00 -0.0350 51 FeO2- 0.31900E-08 -8.4962 0.29423E-08 -8.5313 0.92234E+00 -0.0351 52 HFeO2,aq 0.19864E-09 -9.7019 0.19864E-09 -9.7019 0.10000E+01 0.0000 53 H2,aq 0.51600E-09 -9.2874 0.51576E-09 -9.2876 0.99953E+00 -0.0002 54 KCl,aq 0.10715E-09 -9.9700 0.10715E-09 -9.9700 0.10000E+01 0.0000 55 KHSO4,aq 0.13608E-17 -17.8662 0.13608E-17 -17.8662 0.10000E+01 0.0000 56 KOH,aq 0.37387E-07 -7.4273 0.37387E-07 -7.4273 0.10000E+01 0.0000 57 KSO4- 0.15254E-07 -7.8166 0.14069E-07 -7.8517 0.92234E+00 -0.0351 58 MgCO3,aq 0.55449E-12 -12.2561 0.55449E-12 -12.2561 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.30310E-13 -13.5184 0.27965E-13 -13.5534 0.92263E+00 -0.0350 60 MgCl+ 0.21565E-13 -13.6663 0.19896E-13 -13.7012 0.92263E+00 -0.0350 61 MgOH+ 0.85859E-10 -10.0662 0.79216E-10 -10.1012 0.92263E+00 -0.0350 63 MnO,aq 0.31070E-09 -9.5077 0.31070E-09 -9.5077 0.10000E+01 0.0000 64 MnOH+ 0.52195E-09 -9.2824 0.48157E-09 -9.3173 0.92263E+00 -0.0350 65 MnO2-2 0.47840E-13 -13.3202 0.36594E-13 -13.4366 0.76491E+00 -0.1164 66 HMnO2- 0.46140E-11 -11.3359 0.42557E-11 -11.3710 0.92234E+00 -0.0351 69 MnCl+ 0.71781E-13 -13.1440 0.66227E-13 -13.1790 0.92263E+00 -0.0350 70 MnSO4,aq 0.47615E-12 -12.3223 0.47615E-12 -12.3223 0.10000E+01 0.0000 71 NaCl,aq 0.89516E-07 -7.0481 0.89516E-07 -7.0481 0.10000E+01 0.0000 72 NaOH,aq 0.17185E-05 -5.7648 0.17185E-05 -5.7648 0.10000E+01 0.0000 74 OH- 0.11804E-02 -2.9280 0.10884E-02 -2.9632 0.92208E+00 -0.0352 79 HPO3-2 0.11519E-16 -16.9386 0.88108E-17 -17.0550 0.76491E+00 -0.1164 81 H2PO3- 0.10168E-19 -19.9927 0.93788E-20 -20.0279 0.92234E+00 -0.0351 82 H3PO4,aq 0.10803E-13 -13.9665 0.10803E-13 -13.9665 0.10000E+01 0.0000 83 H2PO4- 0.58190E-07 -7.2351 0.53680E-07 -7.2702 0.92248E+00 -0.0350 84 PO4-3 0.14961E-07 -7.8250 0.84258E-08 -8.0744 0.56319E+00 -0.2493 87 H2P2O7-2 0.29538E-15 -15.5296 0.22594E-15 -15.6460 0.76491E+00 -0.1164 88 HP2O7-3 0.15208E-12 -12.8179 0.84990E-13 -13.0706 0.55884E+00 -0.2527 89 P2O7-4 0.10569E-12 -12.9759 0.38250E-13 -13.4174 0.36189E+00 -0.4414 90 H2S,aq 0.57050E-16 -16.2437 0.57023E-16 -16.2439 0.99953E+00 -0.0002 97 SO3-2 0.17056E-14 -14.7681 0.13076E-14 -14.8835 0.76669E+00 -0.1154 98 HSO3- 0.47119E-16 -16.3268 0.43460E-16 -16.3619 0.92234E+00 -0.0351 99 HSO4- 0.10816E-10 -10.9659 0.99807E-11 -11.0008 0.92276E+00 -0.0349 Charge balance for all species = 0.4573E-13 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.5749613E-09 -.2292023E-02 -.2309753E+01 0.0000 2 H2O 0.1000000E+01 0.5550858E+02 0.9998005E+06 0.0000 3 Cl- 0.1379316E-03 0.1380212E-03 0.4892273E+01 5.3796 4 SO4-- 0.2549783E-04 0.2551347E-04 0.2450366E+01 13.8404 5 HCO3- 0.1089963E-04 0.1307446E-04 0.7976048E+00 4.2775 6 HS- 0.3768371E-13 -.2945480E-09 -.9739312E-05 -4.1839 7 Al+++ 0.9133965E-25 0.4182034E-04 0.1128146E+01 2.5331 8 H4SiO4 0.4779726E-03 0.1418408E-02 0.1363032E+03 -3.3206 9 Ca++ 0.1669725E-07 0.1916942E-07 0.7681159E-03 10.6560 10 Mg++ 0.1396091E-09 0.2288284E-09 0.5562146E-05 8.5780 11 Fe++ 0.8235695E-12 0.5372502E-08 0.2999772E-03 6.3488 12 K+ 0.5037024E-04 0.5042299E-04 0.1971239E+01 4.9422 13 Na+ 0.2302005E-02 0.2332685E-02 0.5361706E+02 6.6020 14 Mn++ 0.1106536E-09 0.9485127E-09 0.5209880E-04 8.4771 15 HPO4-- 0.7164022E-05 0.7237174E-05 0.6944756E+00 13.2890 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.3043807E-01 -.2291242E-02 -.2814683E-01 0.0000000E+00 2 H2O 0.5548520E+02 0.5548965E+02 -.4447791E-02 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.7646943E-04 0.2550476E-04 0.5096466E-04 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.5096496E-04 -.2944475E-09 -.5096466E-04 0.0000000E+00 7 Al+++ 0.5996504E-02 0.4180608E-04 0.5954698E-02 0.0000000E+00 8 H4SiO4 0.1914911E-01 0.1417925E-02 0.1773118E-01 0.0000000E+00 9 Ca++ 0.2129583E-02 0.1916288E-07 0.2129564E-02 0.0000000E+00 10 Mg++ 0.1459524E-02 0.2287504E-09 0.1459524E-02 0.0000000E+00 11 Fe++ 0.1311223E-02 0.5370670E-08 0.1311217E-02 0.0000000E+00 12 K+ 0.3904459E-03 0.5040580E-04 0.3400401E-03 0.0000000E+00 13 Na+ 0.2468464E-02 0.2331889E-02 0.1365750E-03 0.0000000E+00 14 Mn++ 0.3188568E-04 0.9481892E-09 0.3188473E-04 0.0000000E+00 15 HPO4-- 0.1088242E-04 0.7234706E-05 0.3647718E-05 0.0000000E+00 Chg. balance for solid moles: -.5167E-18 Mass of aqueous solution: 0.999862E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 1.8390000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) apatite-OH 0.1216E-05 -5.915 0.6108E-03 -3.214 0.3097E-01 0.1941E-03 clinochlore 0.2919E-03 -3.535 0.1622 -0.790 8.227 0.6172E-01 daphnite 0.1807E-03 -3.743 0.1289 -0.890 6.538 0.3907E-01 chlorite-Mn 0.6377E-05 -5.195 0.4521E-02 -2.345 0.2292 0.1441E-02 hematite 0.2039E-03 -3.691 0.3256E-01 -1.487 1.651 0.6171E-02 microcline 0.3400E-03 -3.468 0.9465E-01 -1.024 4.799 0.3697E-01 paragonite 0.1366E-03 -3.865 0.5220E-01 -1.282 2.647 0.1804E-01 stilbite 0.2123E-02 -2.673 1.496 0.175 75.88 0.6980 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.6094E+00 0.6094E+00 1.0000 -0.215 daphnite 0.3773E+00 0.3773E+00 1.0000 -0.423 chlorite-Mn 0.1331E-01 0.1331E-01 1.0000 -1.876 hematite 0.1000E+01 0.1000E+01 1.0000 0.000 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 paragonite 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 1.972177 g Volume = 0.861582 cm3 Porosity: 50.3583% V(tot) - V(min): 0.87402E+00 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 1.8390000 g log = 0.2646 Original solution: 1000.0103000 g Original solution / Rock added: 543.78 (Water/Rock Ratio), log = 2.7354 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0203 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.1000E+01 0.9860 0.1006E+01 0.1020E+01 CO2,gas 0.1188E-05 1.0071 0.1220E-05 0.1212E-05 CH4,gas 0.2479E-16 1.0125 0.2561E-16 0.2530E-16 H2,gas 0.6633E-06 1.0005 0.6771E-06 0.6768E-06 H2S,gas 0.1542E-14 0.9960 0.1568E-14 0.1574E-14 S2,gas 0.1972E-36 1.0000 0.2012E-36 0.2012E-36 CO,gas 0.2158E-15 1.0000 0.2202E-15 0.2202E-15 SO3,gas 0.2037E-38 1.0000 0.2079E-38 0.2079E-38 SO2,gas 0.5367E-22 1.0000 0.5476E-22 0.5476E-22 HCl,gas 0.2140E-16 1.0000 0.2184E-16 0.2184E-16 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 32 apatite-OH -18.15 -18.15 0.00 0.000 -0.60662E-11 46 clinochlore 39.07 39.07 0.00 0.000 -0.12132E-10 47 daphnite 28.97 28.97 0.00 0.000 0.60662E-11 48 chlorite-Mn 46.87 46.87 0.00 0.000 -0.12132E-10 90 hematite 12.57 12.57 0.00 0.000 0.30331E-11 116 microcline -2.49 -2.49 0.00 0.000 -0.10616E-10 121 paragonite 4.24 4.24 0.00 0.000 0.13649E-10 163 stilbite -7.52 -7.52 0.00 0.000 -0.90992E-11 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -14.27 -7.61 -2.538 0.12998E+05 -5.914 3 CH4,gas 4.54 -13.75 -18.29 -4.573 0.31231E+05 -16.592 4 H2,gas 8.00 0.13 -7.87 -4.496 0.13435E+05 -6.169 5 H2S,gas -6.23 -22.73 -16.50 -8.252 0.28180E+05 -14.805 6 S2,gas -7.34 -45.73 -38.40 -5.907 0.65559E+05 -36.696 7 CO,gas 3.21 -14.14 -17.36 -5.340 0.29635E+05 -15.657 8 SO3,gas 17.12 -23.26 -40.38 -10.095 0.68950E+05 -38.682 9 SO2,gas 0.83 -23.13 -23.96 -6.389 0.40912E+05 -22.262 10 HCl,gas 5.19 -13.17 -18.36 -9.180 0.31349E+05 -16.661 11 acmite 7.71 6.24 -1.47 -0.152 0.25028E+04 15 albite-high 0.69 -0.83 -1.52 -0.117 0.25949E+04 16 albite -0.38 -0.83 -0.44 -0.034 0.75611E+03 19 spessartine 24.46 20.54 -3.92 -0.196 0.66960E+04 20 analcite 3.32 2.49 -0.83 -0.092 0.14137E+04 21 andalusite 5.00 1.75 -3.26 -0.326 0.55595E+04 22 andradite 39.01 34.57 -4.44 -0.230 0.75749E+04 26 annite 20.12 16.56 -3.56 -0.198 0.60845E+04 27 phlogopite 27.06 23.25 -3.82 -0.212 0.65178E+04 29 anorthite 12.71 9.08 -3.63 -0.279 0.61971E+04 35 aragonite 0.97 -3.62 -4.58 -1.528 0.78256E+04 36 brucite 12.57 8.58 -3.99 -0.798 0.68139E+04 37 calcite 0.81 -3.62 -4.43 -1.476 0.75614E+04 38 carnegieite-low 9.02 5.81 -3.21 -0.458 0.54789E+04 39 carnegieite-high 10.09 5.81 -4.28 -0.611 0.73059E+04 40 carpholite-Mg 8.58 7.00 -1.58 -0.105 0.26964E+04 41 carpholite-Fe 6.71 4.77 -1.94 -0.129 0.33106E+04 42 celadonite 5.34 2.77 -2.57 -0.151 0.43895E+04 43 celadonite-Fe 3.88 0.54 -3.33 -0.196 0.56941E+04 44 chrysotile 23.89 19.09 -4.80 -0.400 0.81954E+04 50 chloritoid-Mg 13.20 10.32 -2.87 -0.192 0.49076E+04 51 chloritoid-Fe 9.17 8.09 -1.08 -0.072 0.18428E+04 52 chloritoid-Mn 11.40 10.22 -1.18 -0.079 0.20121E+04 54 coesite -2.38 -3.32 -0.94 -0.315 0.16128E+04 59 corundum 8.38 5.07 -3.32 -0.302 0.56637E+04 61 cristobalite -2.56 -3.32 -0.76 -0.253 0.12981E+04 63 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71234E+04 65 diaspore 2.87 2.53 -0.34 -0.057 0.58163E+03 67 diopside 16.18 12.59 -3.59 -0.359 0.61274E+04 68 hedenbergite 14.21 10.36 -3.84 -0.384 0.65646E+04 75 epidote 24.67 22.70 -1.97 -0.096 0.33645E+04 76 clinozoisite 22.81 18.95 -3.86 -0.175 0.65851E+04 77 epidote-Fe 29.84 26.45 -3.39 -0.176 0.57906E+04 78 fayalite 14.05 9.38 -4.67 -0.667 0.79717E+04 83 gibbsite 4.08 2.53 -1.55 -0.221 0.26402E+04 87 greenalite 16.14 12.41 -3.73 -0.311 0.63761E+04 91 heulandite -5.83 -7.52 -1.69 -0.077 0.28938E+04 95 jadeite 4.22 2.49 -1.72 -0.172 0.29392E+04 97 kalsilite 7.58 4.15 -3.43 -0.490 0.58553E+04 98 kaolinite -1.33 -1.58 -0.24 -0.022 0.41373E+03 99 kyanite 4.88 1.75 -3.13 -0.313 0.53454E+04 101 laumontite 2.88 2.44 -0.44 -0.030 0.75756E+03 102 lawsonite 9.62 9.08 -0.54 -0.036 0.91374E+03 103 leucite 4.12 0.83 -3.28 -0.328 0.56086E+04 105 lizardite 23.24 19.09 -4.15 -0.346 0.70880E+04 107 magnetite 20.09 18.92 -1.17 -0.096 0.20018E+04 108 minnesotaite 10.39 5.76 -4.62 -0.272 0.78954E+04 113 margarite 17.32 14.15 -3.18 -0.127 0.54239E+04 120 muscovite 2.58 2.58 0.00 0.000 0.47881E+01 122 nepheline 8.34 5.81 -2.52 -0.361 0.43113E+04 134 phlogopite-Na 29.65 24.91 -4.74 -0.263 0.80927E+04 136 prehnite 19.37 16.42 -2.96 -0.174 0.50465E+04 137 prehnite-Fe 22.50 20.17 -2.33 -0.140 0.39810E+04 138 pumpellyite-Fe 46.27 41.71 -4.55 -0.101 0.77773E+04 145 pyroxmangite 7.40 5.16 -2.24 -0.448 0.38284E+04 146 pyrophyllite -6.18 -8.22 -2.04 -0.128 0.34840E+04 147 quartz -2.99 -3.32 -0.33 -0.110 0.56545E+03 151 rhodochrosite -0.98 -5.80 -4.82 -1.606 0.82286E+04 152 rhodonite 7.45 5.16 -2.29 -0.458 0.39086E+04 153 sanidine -1.28 -2.49 -1.21 -0.093 0.20677E+04 156 sillimanite 5.26 1.75 -3.52 -0.352 0.60035E+04 164 stilpnomelane-Fe 13.02 12.72 -0.30 -0.009 0.51292E+03 165 stilpnomelane-Mg 27.44 23.86 -3.58 -0.107 0.61113E+04 168 sudoite 21.08 17.33 -3.75 -0.121 0.64047E+04 171 talc 16.49 12.45 -4.04 -0.238 0.68975E+04 174 tephroite 18.09 13.63 -4.45 -0.636 0.76018E+04 177 topaz-H 4.62 1.75 -2.87 -0.261 0.49055E+04 178 tridymite -2.63 -3.32 -0.69 -0.231 0.11854E+04 187 wairakite 3.95 2.44 -1.51 -0.089 0.25795E+04 188 walstromite 11.51 7.34 -4.17 -0.835 0.71267E+04 189 wollastonite 10.46 7.34 -3.13 -0.625 0.53371E+04 190 pseudo-wollastonite 11.00 7.34 -3.66 -0.733 0.62569E+04 191 zoisite 22.85 18.95 -3.90 -0.177 0.66591E+04 192 akaganeite 7.75 6.28 -1.47 -0.318 0.25125E+04 193 beidellite-Ca -1.65 -4.53 -2.88 -0.178 0.49187E+04 194 beidellite-H -2.33 -6.28 -3.96 -0.253 0.67587E+04 195 beidellite-K -1.52 -4.65 -3.13 -0.192 0.53502E+04 196 beidellite-Mg -1.79 -4.87 -3.08 -0.190 0.52580E+04 197 beidellite-Na -1.34 -4.11 -2.76 -0.169 0.47189E+04 199 chalcedony -2.80 -3.32 -0.52 -0.173 0.88475E+03 201 montmorillonite-Ca -2.29 -4.46 -2.17 -0.134 0.37095E+04 202 montmorillonite-K -2.24 -4.59 -2.35 -0.144 0.40190E+04 203 montmorillonite-Mg -2.48 -4.81 -2.33 -0.144 0.39719E+04 204 montmorillonite-Na -2.04 -4.04 -2.00 -0.123 0.34234E+04 205 nontronite-Ca 3.21 2.97 -0.24 -0.016 0.41115E+03 206 nontronite-H 2.53 1.22 -1.32 -0.088 0.22491E+04 207 nontronite-K 3.34 2.85 -0.49 -0.032 0.84393E+03 208 nontronite-Mg 3.07 2.63 -0.44 -0.029 0.75770E+03 209 nontronite-Na 3.52 3.39 -0.13 -0.008 0.21433E+03 224 tobermorite 9.82 5.56 -4.27 -1.164 0.72861E+04 233 boehmite 4.41 2.53 -1.87 -0.312 0.31985E+04 235 ferrous-oxide 9.81 6.35 -3.46 -0.866 0.59126E+04 240 silica-amorphous -2.09 -3.32 -1.23 -0.410 0.20989E+04 242 an20ab80 2.02 1.15 -0.86 -0.066 0.14735E+04 243 an25ab75 2.65 1.65 -1.00 -0.077 0.16998E+04 244 an30ab70 3.28 2.15 -1.13 -0.087 0.19357E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 0.0400000 g Current total amount of reactant added: 1.8390000 g New total amount of reactant added: 1.8790000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.4573E-13 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 6 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 1.8790000 Water: Moles liquid = 0.5549E+02 kg liquid = 0.9997E+00 Moles total = 0.5548E+02 kg total = 0.9996E+00 Activity = 1.0000 Stoichiometric ionic strength = .1544984E-02 Osmotic coef. = 0.9776 True ionic strength = .2433090E-02 Chg. balance for total moles = 0.4573E-13 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.56493E-09 -9.2480 0.52127E-09 -9.2829 0.92273E+00 -0.0349 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13793E-03 -3.8603 0.12715E-03 -3.8957 0.92183E+00 -0.0354 4 SO4-- 0.25498E-04 -4.5935 0.19468E-04 -4.7107 0.76348E+00 -0.1172 5 HCO3- 0.10864E-04 -4.9640 0.10017E-04 -4.9993 0.92204E+00 -0.0352 6 HS- 0.38110E-13 -13.4190 0.35132E-13 -13.4543 0.92185E+00 -0.0353 7 Al+++ 0.85376E-25 -25.0687 0.47468E-25 -25.3236 0.55599E+00 -0.2549 8 H4SiO4 0.48065E-03 -3.3182 0.48065E-03 -3.3182 0.10000E+01 0.0000 9 Ca++ 0.16091E-07 -7.7934 0.12270E-07 -7.9111 0.76259E+00 -0.1177 10 Mg++ 0.13546E-09 -9.8682 0.10322E-09 -9.9862 0.76202E+00 -0.1180 11 Fe++ 0.79908E-12 -12.0974 0.60903E-12 -12.2154 0.76216E+00 -0.1180 12 K+ 0.49557E-04 -4.3049 0.45696E-04 -4.3401 0.92208E+00 -0.0352 13 Na+ 0.23483E-02 -2.6293 0.21646E-02 -2.6646 0.92181E+00 -0.0354 14 Mn++ 0.10736E-09 -9.9691 0.81839E-10 -10.0870 0.76226E+00 -0.1179 15 HPO4-- 0.74819E-05 -5.1260 0.57124E-05 -5.2432 0.76350E+00 -0.1172 16 HSiO3- 0.93399E-03 -3.0297 0.86097E-03 -3.0650 0.92183E+00 -0.0354 17 Ca(HSiO3)+ 0.26092E-09 -9.5835 0.24060E-09 -9.6187 0.92211E+00 -0.0352 18 Mg(HSiO3)+ 0.27316E-11 -11.5636 0.25188E-11 -11.5988 0.92211E+00 -0.0352 19 NaHSiO3,aq 0.30143E-04 -4.5208 0.30143E-04 -4.5208 0.10000E+01 0.0000 20 AlO+ 0.25773E-13 -13.5888 0.23766E-13 -13.6241 0.92211E+00 -0.0352 21 AlOH+2 0.80913E-19 -19.0920 0.61687E-19 -19.2098 0.76238E+00 -0.1178 22 HAlO2,aq 0.90795E-08 -8.0419 0.90795E-08 -8.0419 0.10000E+01 0.0000 23 AlO2- 0.41838E-04 -4.3784 0.38556E-04 -4.4139 0.92155E+00 -0.0355 24 CH4,aq 0.17568E-19 -19.7553 0.17560E-19 -19.7555 0.99952E+00 -0.0002 29 CO,aq 0.14568E-18 -18.8366 0.14568E-18 -18.8366 0.10000E+01 0.0000 30 CO2,aq 0.11163E-07 -7.9522 0.11157E-07 -7.9524 0.99952E+00 -0.0002 31 CO3-2 0.21992E-05 -5.6577 0.16785E-05 -5.7751 0.76322E+00 -0.1174 32 CaCO3,aq 0.25825E-09 -9.5880 0.25825E-09 -9.5880 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.34025E-11 -11.4682 0.31375E-11 -11.5034 0.92211E+00 -0.0352 34 CaCl+ 0.27381E-11 -11.5625 0.25248E-11 -11.5978 0.92211E+00 -0.0352 35 CaCl2,aq 0.76270E-16 -16.1176 0.76270E-16 -16.1176 0.10000E+01 0.0000 36 CaOH+ 0.18193E-08 -8.7401 0.16776E-08 -8.7753 0.92211E+00 -0.0352 37 CaSO4,aq 0.75854E-10 -10.1200 0.75854E-10 -10.1200 0.10000E+01 0.0000 38 HCl,aq 0.12145E-13 -13.9156 0.12145E-13 -13.9156 0.10000E+01 0.0000 43 FeCl+ 0.13292E-15 -15.8764 0.12257E-15 -15.9116 0.92211E+00 -0.0352 46 FeO,aq 0.87111E-10 -10.0599 0.87111E-10 -10.0599 0.10000E+01 0.0000 47 FeOH+ 0.41243E-10 -10.3846 0.38031E-10 -10.4199 0.92211E+00 -0.0352 48 HFeO2- 0.18968E-08 -8.7220 0.17485E-08 -8.7573 0.92183E+00 -0.0354 49 FeO+ 0.43149E-14 -14.3650 0.39788E-14 -14.4002 0.92211E+00 -0.0352 51 FeO2- 0.32503E-08 -8.4881 0.29962E-08 -8.5234 0.92183E+00 -0.0354 52 HFeO2,aq 0.19864E-09 -9.7019 0.19864E-09 -9.7019 0.10000E+01 0.0000 53 H2,aq 0.52002E-09 -9.2840 0.51977E-09 -9.2842 0.99952E+00 -0.0002 54 KCl,aq 0.10530E-09 -9.9776 0.10530E-09 -9.9776 0.10000E+01 0.0000 55 KHSO4,aq 0.13111E-17 -17.8824 0.13111E-17 -17.8824 0.10000E+01 0.0000 56 KOH,aq 0.37437E-07 -7.4267 0.37437E-07 -7.4267 0.10000E+01 0.0000 57 KSO4- 0.14975E-07 -7.8246 0.13804E-07 -7.8600 0.92183E+00 -0.0354 58 MgCO3,aq 0.54454E-12 -12.2640 0.54454E-12 -12.2640 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.29247E-13 -13.5339 0.26969E-13 -13.5691 0.92211E+00 -0.0352 60 MgCl+ 0.20876E-13 -13.6803 0.19250E-13 -13.7156 0.92211E+00 -0.0352 61 MgOH+ 0.84689E-10 -10.0722 0.78093E-10 -10.1074 0.92211E+00 -0.0352 63 MnO,aq 0.31190E-09 -9.5060 0.31190E-09 -9.5060 0.10000E+01 0.0000 64 MnOH+ 0.51484E-09 -9.2883 0.47474E-09 -9.3235 0.92211E+00 -0.0352 65 MnO2-2 0.49913E-13 -13.3018 0.38094E-13 -13.4191 0.76322E+00 -0.1174 66 HMnO2- 0.47194E-11 -11.3261 0.43505E-11 -11.3615 0.92183E+00 -0.0354 69 MnCl+ 0.69490E-13 -13.1581 0.64077E-13 -13.1933 0.92211E+00 -0.0352 70 MnSO4,aq 0.45994E-12 -12.3373 0.45994E-12 -12.3373 0.10000E+01 0.0000 71 NaCl,aq 0.91212E-07 -7.0400 0.91212E-07 -7.0400 0.10000E+01 0.0000 72 NaOH,aq 0.17842E-05 -5.7486 0.17842E-05 -5.7486 0.10000E+01 0.0000 74 OH- 0.12027E-02 -2.9198 0.11084E-02 -2.9553 0.92155E+00 -0.0355 79 HPO3-2 0.12124E-16 -16.9164 0.92529E-17 -17.0337 0.76322E+00 -0.1174 81 H2PO3- 0.10492E-19 -19.9791 0.96722E-20 -20.0145 0.92183E+00 -0.0354 82 H3PO4,aq 0.10856E-13 -13.9643 0.10856E-13 -13.9643 0.10000E+01 0.0000 83 H2PO4- 0.59580E-07 -7.2249 0.54931E-07 -7.2602 0.92197E+00 -0.0353 84 PO4-3 0.15953E-07 -7.7971 0.89410E-08 -8.0486 0.56045E+00 -0.2515 87 H2P2O7-2 0.31000E-15 -15.5086 0.23660E-15 -15.6260 0.76322E+00 -0.1174 88 HP2O7-3 0.16299E-12 -12.7878 0.90630E-13 -13.0427 0.55605E+00 -0.2549 89 P2O7-4 0.11579E-12 -12.9363 0.41535E-13 -13.3816 0.35870E+00 -0.4453 90 H2S,aq 0.56627E-16 -16.2470 0.56600E-16 -16.2472 0.99952E+00 -0.0002 97 SO3-2 0.17188E-14 -14.7648 0.13149E-14 -14.8811 0.76502E+00 -0.1163 98 HSO3- 0.46556E-16 -16.3320 0.42917E-16 -16.3674 0.92183E+00 -0.0354 99 HSO4- 0.10604E-10 -10.9745 0.97797E-11 -11.0097 0.92225E+00 -0.0351 Charge balance for all species = 0.4616E-13 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.5649255E-09 -.2338233E-02 -.2356312E+01 0.0000 2 H2O 0.1000000E+01 0.5550857E+02 0.9997969E+06 0.0000 3 Cl- 0.1379309E-03 0.1380222E-03 0.4892291E+01 5.3872 4 SO4-- 0.2549829E-04 0.2551365E-04 0.2450376E+01 13.8552 5 HCO3- 0.1086392E-04 0.1307455E-04 0.7976076E+00 4.2837 6 HS- 0.3811040E-13 -.3010749E-09 -.9955091E-05 -4.1714 7 Al+++ 0.8537551E-25 0.4184704E-04 0.1128862E+01 2.5252 8 H4SiO4 0.4806495E-03 0.1444779E-02 0.1388368E+03 -3.3182 9 Ca++ 0.1609058E-07 0.1851109E-07 0.7417339E-03 10.6547 10 Mg++ 0.1354585E-09 0.2234741E-09 0.5431980E-05 8.5796 11 Fe++ 0.7990819E-12 0.5474894E-08 0.3056932E-03 6.3505 12 K+ 0.4955725E-04 0.4960977E-04 0.1939440E+01 4.9428 13 Na+ 0.2348253E-02 0.2380271E-02 0.5471064E+02 6.6183 14 Mn++ 0.1073633E-09 0.9394097E-09 0.5159862E-04 8.4788 15 HPO4-- 0.7481881E-05 0.7557415E-05 0.7252032E+00 13.3227 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.3110041E-01 -.2337419E-02 -.2876299E-01 0.0000000E+00 2 H2O 0.5548470E+02 0.5548925E+02 -.4552100E-02 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.7757797E-04 0.2550477E-04 0.5207319E-04 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.5207350E-04 -.3009701E-09 -.5207319E-04 0.0000000E+00 7 Al+++ 0.6126933E-02 0.4183247E-04 0.6085101E-02 0.0000000E+00 8 H4SiO4 0.1956562E-01 0.1444276E-02 0.1812134E-01 0.0000000E+00 9 Ca++ 0.2175589E-02 0.1850464E-07 0.2175571E-02 0.0000000E+00 10 Mg++ 0.1491270E-02 0.2233963E-09 0.1491270E-02 0.0000000E+00 11 Fe++ 0.1339743E-02 0.5472987E-08 0.1339738E-02 0.0000000E+00 12 K+ 0.3989384E-03 0.4959250E-04 0.3493459E-03 0.0000000E+00 13 Na+ 0.2518674E-02 0.2379442E-02 0.1392317E-03 0.0000000E+00 14 Mn++ 0.3257922E-04 0.9390827E-09 0.3257828E-04 0.0000000E+00 15 HPO4-- 0.1111913E-04 0.7554784E-05 0.3564343E-05 0.0000000E+00 Chg. balance for solid moles: 0.3193E-17 Mass of aqueous solution: 0.999859E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 1.8790000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) apatite-OH 0.1188E-05 -5.925 0.5968E-03 -3.224 0.2961E-01 0.1896E-03 clinochlore 0.2983E-03 -3.525 0.1658 -0.780 8.225 0.6306E-01 daphnite 0.1846E-03 -3.734 0.1317 -0.880 6.536 0.3992E-01 chlorite-Mn 0.6516E-05 -5.186 0.4619E-02 -2.335 0.2292 0.1472E-02 hematite 0.2083E-03 -3.681 0.3326E-01 -1.478 1.650 0.6305E-02 microcline 0.3493E-03 -3.457 0.9724E-01 -1.012 4.825 0.3798E-01 paragonite 0.1392E-03 -3.856 0.5321E-01 -1.274 2.640 0.1839E-01 stilbite 0.2170E-02 -2.664 1.529 0.184 75.86 0.7131 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.6094E+00 0.6094E+00 1.0000 -0.215 daphnite 0.3773E+00 0.3773E+00 1.0000 -0.423 chlorite-Mn 0.1331E-01 0.1331E-01 1.0000 -1.876 hematite 0.1000E+01 0.1000E+01 1.0000 0.000 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 paragonite 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 2.015428 g Volume = 0.880466 cm3 Porosity: 49.7336% V(tot) - V(min): 0.87113E+00 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 1.8790000 g log = 0.2739 Original solution: 1000.0103000 g Original solution / Rock added: 532.20 (Water/Rock Ratio), log = 2.7261 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0203 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.1000E+01 0.9860 0.1006E+01 0.1020E+01 CO2,gas 0.1162E-05 1.0071 0.1194E-05 0.1185E-05 CH4,gas 0.2502E-16 1.0125 0.2585E-16 0.2553E-16 H2,gas 0.6685E-06 1.0005 0.6824E-06 0.6820E-06 H2S,gas 0.1531E-14 0.9960 0.1556E-14 0.1562E-14 S2,gas 0.1912E-36 1.0000 0.1951E-36 0.1951E-36 CO,gas 0.2128E-15 1.0000 0.2171E-15 0.2171E-15 SO3,gas 0.1960E-38 1.0000 0.2000E-38 0.2000E-38 SO2,gas 0.5204E-22 1.0000 0.5310E-22 0.5310E-22 HCl,gas 0.2100E-16 1.0000 0.2143E-16 0.2143E-16 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 32 apatite-OH -18.15 -18.15 0.00 0.000 -0.60662E-11 46 clinochlore 39.07 39.07 0.00 0.000 0.12132E-10 47 daphnite 28.97 28.97 0.00 0.000 0.60662E-11 48 chlorite-Mn 46.87 46.87 0.00 0.000 0.24265E-10 90 hematite 12.57 12.57 0.00 0.000 -0.90992E-11 116 microcline -2.49 -2.49 0.00 0.000 0.15165E-11 121 paragonite 4.24 4.24 0.00 0.000 0.13649E-10 163 stilbite -7.52 -7.52 0.00 0.000 0.15165E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -14.28 -7.62 -2.541 0.13014E+05 -5.923 3 CH4,gas 4.54 -13.74 -18.29 -4.572 0.31224E+05 -16.588 4 H2,gas 8.00 0.13 -7.86 -4.494 0.13429E+05 -6.166 5 H2S,gas -6.23 -22.74 -16.51 -8.253 0.28185E+05 -14.808 6 S2,gas -7.34 -45.74 -38.41 -5.909 0.65582E+05 -36.710 7 CO,gas 3.21 -14.15 -17.36 -5.342 0.29646E+05 -15.663 8 SO3,gas 17.12 -23.28 -40.40 -10.099 0.68978E+05 -38.699 9 SO2,gas 0.83 -23.14 -23.97 -6.393 0.40935E+05 -22.275 10 HCl,gas 5.19 -13.18 -18.37 -9.184 0.31363E+05 -16.669 11 acmite 7.71 6.27 -1.44 -0.150 0.24667E+04 15 albite-high 0.69 -0.81 -1.50 -0.116 0.25681E+04 16 albite -0.38 -0.81 -0.43 -0.033 0.72930E+03 19 spessartine 24.46 20.53 -3.92 -0.196 0.67017E+04 20 analcite 3.32 2.51 -0.81 -0.091 0.13910E+04 21 andalusite 5.00 1.73 -3.27 -0.327 0.55822E+04 22 andradite 39.01 34.58 -4.43 -0.230 0.75690E+04 26 annite 20.12 16.57 -3.56 -0.198 0.60758E+04 27 phlogopite 27.06 23.25 -3.81 -0.212 0.65091E+04 29 anorthite 12.71 9.07 -3.64 -0.280 0.62178E+04 35 aragonite 0.97 -3.63 -4.59 -1.531 0.78441E+04 36 brucite 12.57 8.58 -3.99 -0.798 0.68110E+04 37 calcite 0.81 -3.63 -4.44 -1.480 0.75799E+04 38 carnegieite-low 9.02 5.83 -3.20 -0.457 0.54604E+04 39 carnegieite-high 10.09 5.83 -4.27 -0.610 0.72874E+04 40 carpholite-Mg 8.58 6.99 -1.59 -0.106 0.27121E+04 41 carpholite-Fe 6.71 4.76 -1.95 -0.130 0.33263E+04 42 celadonite 5.34 2.77 -2.57 -0.151 0.43824E+04 43 celadonite-Fe 3.88 0.55 -3.33 -0.196 0.56870E+04 44 chrysotile 23.89 19.10 -4.79 -0.399 0.81785E+04 50 chloritoid-Mg 13.20 10.31 -2.89 -0.192 0.49274E+04 51 chloritoid-Fe 9.17 8.08 -1.09 -0.073 0.18626E+04 52 chloritoid-Mn 11.40 10.21 -1.19 -0.079 0.20319E+04 54 coesite -2.38 -3.32 -0.94 -0.314 0.16086E+04 59 corundum 8.38 5.05 -3.33 -0.303 0.56905E+04 61 cristobalite -2.56 -3.32 -0.76 -0.253 0.12940E+04 63 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71234E+04 65 diaspore 2.87 2.53 -0.35 -0.058 0.59503E+03 67 diopside 16.18 12.60 -3.58 -0.358 0.61184E+04 68 hedenbergite 14.21 10.37 -3.84 -0.384 0.65556E+04 75 epidote 24.67 22.69 -1.98 -0.096 0.33833E+04 76 clinozoisite 22.81 18.93 -3.88 -0.176 0.66172E+04 77 epidote-Fe 29.84 26.45 -3.39 -0.176 0.57960E+04 78 fayalite 14.05 9.38 -4.66 -0.666 0.79618E+04 83 gibbsite 4.08 2.53 -1.55 -0.222 0.26536E+04 87 greenalite 16.14 12.42 -3.72 -0.310 0.63592E+04 91 heulandite -5.83 -7.52 -1.69 -0.077 0.28938E+04 95 jadeite 4.22 2.51 -1.71 -0.171 0.29165E+04 97 kalsilite 7.58 4.15 -3.43 -0.491 0.58636E+04 98 kaolinite -1.33 -1.59 -0.25 -0.023 0.43226E+03 99 kyanite 4.88 1.73 -3.14 -0.314 0.53681E+04 101 laumontite 2.88 2.43 -0.45 -0.030 0.76998E+03 102 lawsonite 9.62 9.07 -0.55 -0.036 0.93444E+03 103 leucite 4.12 0.83 -3.29 -0.329 0.56128E+04 105 lizardite 23.24 19.10 -4.14 -0.345 0.70711E+04 107 magnetite 20.09 18.92 -1.17 -0.096 0.19989E+04 108 minnesotaite 10.39 5.78 -4.61 -0.271 0.78702E+04 113 margarite 17.32 14.12 -3.20 -0.128 0.54714E+04 120 muscovite 2.58 2.56 -0.02 -0.001 0.31601E+02 122 nepheline 8.34 5.83 -2.51 -0.359 0.42928E+04 134 phlogopite-Na 29.65 24.93 -4.72 -0.262 0.80573E+04 136 prehnite 19.37 16.41 -2.97 -0.175 0.50652E+04 137 prehnite-Fe 22.50 20.16 -2.33 -0.140 0.39863E+04 138 pumpellyite-Fe 46.27 41.69 -4.58 -0.102 0.78253E+04 145 pyroxmangite 7.40 5.16 -2.24 -0.448 0.38214E+04 146 pyrophyllite -6.18 -8.22 -2.05 -0.128 0.34943E+04 147 quartz -2.99 -3.32 -0.33 -0.110 0.56131E+03 151 rhodochrosite -0.98 -5.80 -4.83 -1.609 0.82421E+04 152 rhodonite 7.45 5.16 -2.29 -0.457 0.39016E+04 153 sanidine -1.28 -2.49 -1.21 -0.093 0.20677E+04 156 sillimanite 5.26 1.73 -3.53 -0.353 0.60261E+04 164 stilpnomelane-Fe 13.02 12.73 -0.29 -0.009 0.49173E+03 165 stilpnomelane-Mg 27.44 23.87 -3.57 -0.106 0.60901E+04 168 sudoite 21.08 17.31 -3.77 -0.122 0.64402E+04 171 talc 16.49 12.47 -4.02 -0.237 0.68723E+04 174 tephroite 18.09 13.64 -4.45 -0.635 0.75919E+04 177 topaz-H 4.62 1.73 -2.89 -0.262 0.49282E+04 178 tridymite -2.63 -3.32 -0.69 -0.231 0.11813E+04 187 wairakite 3.95 2.43 -1.52 -0.089 0.25919E+04 188 walstromite 11.51 7.34 -4.17 -0.835 0.71247E+04 189 wollastonite 10.46 7.34 -3.12 -0.625 0.53351E+04 190 pseudo-wollastonite 11.00 7.34 -3.66 -0.733 0.62550E+04 191 zoisite 22.85 18.93 -3.92 -0.178 0.66913E+04 192 akaganeite 7.75 6.28 -1.47 -0.318 0.25125E+04 193 beidellite-Ca -1.65 -4.54 -2.89 -0.179 0.49351E+04 194 beidellite-H -2.33 -6.29 -3.97 -0.253 0.67748E+04 195 beidellite-K -1.52 -4.66 -3.14 -0.192 0.53659E+04 196 beidellite-Mg -1.79 -4.88 -3.09 -0.191 0.52736E+04 197 beidellite-Na -1.34 -4.11 -2.77 -0.169 0.47257E+04 199 chalcedony -2.80 -3.32 -0.52 -0.172 0.88061E+03 201 montmorillonite-Ca -2.29 -4.47 -2.18 -0.135 0.37147E+04 202 montmorillonite-K -2.24 -4.59 -2.36 -0.144 0.40236E+04 203 montmorillonite-Mg -2.48 -4.81 -2.33 -0.144 0.39763E+04 204 montmorillonite-Na -2.04 -4.04 -2.00 -0.123 0.34191E+04 205 nontronite-Ca 3.21 2.98 -0.23 -0.015 0.40074E+03 206 nontronite-H 2.53 1.22 -1.31 -0.088 0.22383E+04 207 nontronite-K 3.34 2.85 -0.49 -0.031 0.83284E+03 208 nontronite-Mg 3.07 2.64 -0.44 -0.028 0.74645E+03 209 nontronite-Na 3.52 3.41 -0.11 -0.007 0.19438E+03 224 tobermorite 9.82 5.56 -4.27 -1.164 0.72838E+04 233 boehmite 4.41 2.53 -1.88 -0.314 0.32120E+04 235 ferrous-oxide 9.81 6.35 -3.46 -0.865 0.59097E+04 240 silica-amorphous -2.09 -3.32 -1.23 -0.409 0.20948E+04 242 an20ab80 2.02 1.16 -0.85 -0.066 0.14561E+04 243 an25ab75 2.65 1.66 -0.99 -0.076 0.16848E+04 244 an30ab70 3.28 2.15 -1.13 -0.087 0.19231E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 0.0400000 g Current total amount of reactant added: 1.8790000 g New total amount of reactant added: 1.9190000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.4572E-13 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 6 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 1.9190000 Water: Moles liquid = 0.5549E+02 kg liquid = 0.9996E+00 Moles total = 0.5548E+02 kg total = 0.9996E+00 Activity = 1.0000 Stoichiometric ionic strength = .1569158E-02 Osmotic coef. = 0.9774 True ionic strength = .2478887E-02 Chg. balance for total moles = 0.4572E-13 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.55527E-09 -9.2555 0.51209E-09 -9.2907 0.92223E+00 -0.0352 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13793E-03 -3.8603 0.12708E-03 -3.8959 0.92131E+00 -0.0356 4 SO4-- 0.25499E-04 -4.5935 0.19425E-04 -4.7116 0.76181E+00 -0.1182 5 HCO3- 0.10828E-04 -4.9654 0.99788E-05 -5.0009 0.92153E+00 -0.0355 6 HS- 0.38534E-13 -13.4142 0.35503E-13 -13.4497 0.92134E+00 -0.0356 7 Al+++ 0.79920E-25 -25.0973 0.44215E-25 -25.3544 0.55324E+00 -0.2571 8 H4SiO4 0.48327E-03 -3.3158 0.48327E-03 -3.3158 0.10000E+01 0.0000 9 Ca++ 0.15520E-07 -7.8091 0.11809E-07 -7.9278 0.76091E+00 -0.1187 10 Mg++ 0.13152E-09 -9.8810 0.99998E-10 -10.0000 0.76033E+00 -0.1190 11 Fe++ 0.77584E-12 -12.1102 0.59000E-12 -12.2291 0.76047E+00 -0.1189 12 K+ 0.48777E-04 -4.3118 0.44951E-04 -4.3473 0.92157E+00 -0.0355 13 Na+ 0.23945E-02 -2.6208 0.22060E-02 -2.6564 0.92129E+00 -0.0356 14 Mn++ 0.10424E-09 -9.9820 0.79282E-10 -10.1008 0.76057E+00 -0.1189 15 HPO4-- 0.78053E-05 -5.1076 0.59463E-05 -5.2257 0.76183E+00 -0.1181 16 HSiO3- 0.95646E-03 -3.0193 0.88119E-03 -3.0549 0.92131E+00 -0.0356 17 Ca(HSiO3)+ 0.25715E-09 -9.5898 0.23699E-09 -9.6253 0.92161E+00 -0.0355 18 Mg(HSiO3)+ 0.27099E-11 -11.5670 0.24975E-11 -11.6025 0.92161E+00 -0.0355 19 NaHSiO3,aq 0.31440E-04 -4.5025 0.31440E-04 -4.5025 0.10000E+01 0.0000 20 AlO+ 0.24889E-13 -13.6040 0.22938E-13 -13.6394 0.92161E+00 -0.0355 21 AlOH+2 0.76890E-19 -19.1141 0.58489E-19 -19.2329 0.76069E+00 -0.1188 22 HAlO2,aq 0.89204E-08 -8.0496 0.89204E-08 -8.0496 0.10000E+01 0.0000 23 AlO2- 0.41865E-04 -4.3781 0.38559E-04 -4.4139 0.92104E+00 -0.0357 24 CH4,aq 0.17724E-19 -19.7514 0.17716E-19 -19.7516 0.99951E+00 -0.0002 29 CO,aq 0.14366E-18 -18.8427 0.14366E-18 -18.8427 0.10000E+01 0.0000 30 CO2,aq 0.10924E-07 -7.9616 0.10919E-07 -7.9618 0.99951E+00 -0.0002 31 CO3-2 0.22350E-05 -5.6507 0.17021E-05 -5.7690 0.76155E+00 -0.1183 32 CaCO3,aq 0.25204E-09 -9.5985 0.25204E-09 -9.5985 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.32640E-11 -11.4863 0.30081E-11 -11.5217 0.92161E+00 -0.0355 34 CaCl+ 0.26352E-11 -11.5792 0.24286E-11 -11.6146 0.92161E+00 -0.0355 35 CaCl2,aq 0.73322E-16 -16.1348 0.73322E-16 -16.1348 0.10000E+01 0.0000 36 CaOH+ 0.17834E-08 -8.7488 0.16436E-08 -8.7842 0.92161E+00 -0.0355 37 CaSO4,aq 0.72846E-10 -10.1376 0.72846E-10 -10.1376 0.10000E+01 0.0000 38 HCl,aq 0.11925E-13 -13.9236 0.11925E-13 -13.9236 0.10000E+01 0.0000 43 FeCl+ 0.12877E-15 -15.8902 0.11867E-15 -15.9256 0.92161E+00 -0.0355 46 FeO,aq 0.87443E-10 -10.0583 0.87443E-10 -10.0583 0.10000E+01 0.0000 47 FeOH+ 0.40694E-10 -10.3905 0.37503E-10 -10.4259 0.92161E+00 -0.0355 48 HFeO2- 0.19392E-08 -8.7124 0.17866E-08 -8.7480 0.92131E+00 -0.0356 49 FeO+ 0.42412E-14 -14.3725 0.39087E-14 -14.4080 0.92161E+00 -0.0355 51 FeO2- 0.33104E-08 -8.4801 0.30499E-08 -8.5157 0.92131E+00 -0.0356 52 HFeO2,aq 0.19864E-09 -9.7019 0.19864E-09 -9.7019 0.10000E+01 0.0000 53 H2,aq 0.52400E-09 -9.2807 0.52374E-09 -9.2809 0.99951E+00 -0.0002 54 KCl,aq 0.10353E-09 -9.9849 0.10353E-09 -9.9849 0.10000E+01 0.0000 55 KHSO4,aq 0.12643E-17 -17.8982 0.12643E-17 -17.8982 0.10000E+01 0.0000 56 KOH,aq 0.37487E-07 -7.4261 0.37487E-07 -7.4261 0.10000E+01 0.0000 57 KSO4- 0.14707E-07 -7.8325 0.13550E-07 -7.8681 0.92131E+00 -0.0356 58 MgCO3,aq 0.53494E-12 -12.2717 0.53494E-12 -12.2717 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.28241E-13 -13.5491 0.26027E-13 -13.5846 0.92161E+00 -0.0355 60 MgCl+ 0.20224E-13 -13.6941 0.18639E-13 -13.7296 0.92161E+00 -0.0355 61 MgOH+ 0.83561E-10 -10.0780 0.77010E-10 -10.1135 0.92161E+00 -0.0355 63 MnO,aq 0.31309E-09 -9.5043 0.31309E-09 -9.5043 0.10000E+01 0.0000 64 MnOH+ 0.50798E-09 -9.2942 0.46816E-09 -9.3296 0.92161E+00 -0.0355 65 MnO2-2 0.52030E-13 -13.2837 0.39623E-13 -13.4021 0.76155E+00 -0.1183 66 HMnO2- 0.48250E-11 -11.3165 0.44454E-11 -11.3521 0.92131E+00 -0.0356 69 MnCl+ 0.67318E-13 -13.1719 0.62041E-13 -13.2073 0.92161E+00 -0.0355 70 MnSO4,aq 0.44461E-12 -12.3520 0.44461E-12 -12.3520 0.10000E+01 0.0000 71 NaCl,aq 0.92903E-07 -7.0320 0.92903E-07 -7.0320 0.10000E+01 0.0000 72 NaOH,aq 0.18509E-05 -5.7326 0.18509E-05 -5.7326 0.10000E+01 0.0000 74 OH- 0.12250E-02 -2.9119 0.11283E-02 -2.9476 0.92104E+00 -0.0357 79 HPO3-2 0.12744E-16 -16.8947 0.97054E-17 -17.0130 0.76155E+00 -0.1183 81 H2PO3- 0.10818E-19 -19.9659 0.99665E-20 -20.0015 0.92131E+00 -0.0356 82 H3PO4,aq 0.10906E-13 -13.9623 0.10906E-13 -13.9623 0.10000E+01 0.0000 83 H2PO4- 0.60962E-07 -7.2149 0.56173E-07 -7.2505 0.92146E+00 -0.0355 84 PO4-3 0.16986E-07 -7.7699 0.94740E-08 -8.0235 0.55775E+00 -0.2536 87 H2P2O7-2 0.32489E-15 -15.4883 0.24742E-15 -15.6066 0.76155E+00 -0.1183 88 HP2O7-3 0.17436E-12 -12.7585 0.96474E-13 -13.0156 0.55329E+00 -0.2570 89 P2O7-4 0.12657E-12 -12.8977 0.45006E-13 -13.3467 0.35558E+00 -0.4491 90 H2S,aq 0.56217E-16 -16.2501 0.56189E-16 -16.2503 0.99951E+00 -0.0002 97 SO3-2 0.17319E-14 -14.7615 0.13221E-14 -14.8787 0.76337E+00 -0.1173 98 HSO3- 0.46011E-16 -16.3371 0.42391E-16 -16.3727 0.92131E+00 -0.0356 99 HSO4- 0.10400E-10 -10.9829 0.95866E-11 -11.0183 0.92175E+00 -0.0354 Charge balance for all species = 0.4617E-13 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.5552747E-09 -.2384462E-02 -.2402890E+01 0.0000 2 H2O 0.1000000E+01 0.5550857E+02 0.9997933E+06 0.0000 3 Cl- 0.1379302E-03 0.1380232E-03 0.4892308E+01 5.3947 4 SO4-- 0.2549874E-04 0.2551384E-04 0.2450385E+01 13.8697 5 HCO3- 0.1082847E-04 0.1307465E-04 0.7976105E+00 4.2897 6 HS- 0.3853396E-13 -.3075950E-09 -.1017064E-04 -4.1591 7 Al+++ 0.7992043E-25 0.4187418E-04 0.1129591E+01 2.5175 8 H4SiO4 0.4832737E-03 0.1471169E-02 0.1413723E+03 -3.3158 9 Ca++ 0.1552028E-07 0.1789158E-07 0.7169081E-03 10.6535 10 Mg++ 0.1315191E-09 0.2183733E-09 0.5307974E-05 8.5813 11 Fe++ 0.7758406E-12 0.5577216E-08 0.3114053E-03 6.3522 12 K+ 0.4877679E-04 0.4882909E-04 0.1908914E+01 4.9434 13 Na+ 0.2394469E-02 0.2427853E-02 0.5580412E+02 6.6343 14 Mn++ 0.1042405E-09 0.9307065E-09 0.5112040E-04 8.4805 15 HPO4-- 0.7805320E-05 0.7883269E-05 0.7564691E+00 13.3556 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.3176275E-01 -.2383615E-02 -.2937914E-01 0.0000000E+00 2 H2O 0.5548419E+02 0.5548885E+02 -.4656309E-02 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.7868650E-04 0.2550478E-04 0.5318172E-04 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.5318203E-04 -.3074857E-09 -.5318172E-04 0.0000000E+00 7 Al+++ 0.6257363E-02 0.4185930E-04 0.6215504E-02 0.0000000E+00 8 H4SiO4 0.1998213E-01 0.1470647E-02 0.1851148E-01 0.0000000E+00 9 Ca++ 0.2221595E-02 0.1788523E-07 0.2221577E-02 0.0000000E+00 10 Mg++ 0.1523016E-02 0.2182957E-09 0.1523016E-02 0.0000000E+00 11 Fe++ 0.1368263E-02 0.5575234E-08 0.1368258E-02 0.0000000E+00 12 K+ 0.4074310E-03 0.4881174E-04 0.3586193E-03 0.0000000E+00 13 Na+ 0.2568884E-02 0.2426991E-02 0.1418929E-03 0.0000000E+00 14 Mn++ 0.3327277E-04 0.9303759E-09 0.3327184E-04 0.0000000E+00 15 HPO4-- 0.1135583E-04 0.7880468E-05 0.3475362E-05 0.0000000E+00 Chg. balance for solid moles: 0.1714E-17 Mass of aqueous solution: 0.999855E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 1.9190000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) apatite-OH 0.1158E-05 -5.936 0.5819E-03 -3.235 0.2827E-01 0.1849E-03 clinochlore 0.3046E-03 -3.516 0.1693 -0.771 8.224 0.6440E-01 daphnite 0.1886E-03 -3.725 0.1345 -0.871 6.535 0.4077E-01 chlorite-Mn 0.6654E-05 -5.177 0.4718E-02 -2.326 0.2292 0.1503E-02 hematite 0.2127E-03 -3.672 0.3397E-01 -1.469 1.650 0.6439E-02 microcline 0.3586E-03 -3.445 0.9982E-01 -1.001 4.849 0.3899E-01 paragonite 0.1419E-03 -3.848 0.5423E-01 -1.266 2.634 0.1875E-01 stilbite 0.2216E-02 -2.654 1.562 0.194 75.85 0.7283 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.6094E+00 0.6094E+00 1.0000 -0.215 daphnite 0.3773E+00 0.3773E+00 1.0000 -0.423 chlorite-Mn 0.1331E-01 0.1331E-01 1.0000 -1.876 hematite 0.1000E+01 0.1000E+01 1.0000 0.000 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 paragonite 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 2.058677 g Volume = 0.899349 cm3 Porosity: 49.1203% V(tot) - V(min): 0.86825E+00 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 1.9190000 g log = 0.2831 Original solution: 1000.0103000 g Original solution / Rock added: 521.11 (Water/Rock Ratio), log = 2.7169 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0203 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.1000E+01 0.9860 0.1006E+01 0.1020E+01 CO2,gas 0.1137E-05 1.0071 0.1168E-05 0.1160E-05 CH4,gas 0.2524E-16 1.0125 0.2608E-16 0.2575E-16 H2,gas 0.6736E-06 1.0005 0.6876E-06 0.6872E-06 H2S,gas 0.1520E-14 0.9960 0.1545E-14 0.1551E-14 S2,gas 0.1856E-36 1.0000 0.1894E-36 0.1894E-36 CO,gas 0.2098E-15 1.0000 0.2141E-15 0.2141E-15 SO3,gas 0.1888E-38 1.0000 0.1926E-38 0.1926E-38 SO2,gas 0.5050E-22 1.0000 0.5153E-22 0.5153E-22 HCl,gas 0.2062E-16 1.0000 0.2104E-16 0.2104E-16 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 32 apatite-OH -18.15 -18.15 0.00 0.000 0.00000E+00 46 clinochlore 39.07 39.07 0.00 0.000 -0.12132E-10 47 daphnite 28.97 28.97 0.00 0.000 -0.18198E-10 48 chlorite-Mn 46.87 46.87 0.00 0.000 0.12132E-10 90 hematite 12.57 12.57 0.00 0.000 0.90992E-11 116 microcline -2.49 -2.49 0.00 0.000 0.15165E-11 121 paragonite 4.24 4.24 0.00 0.000 -0.34880E-10 163 stilbite -7.52 -7.52 0.00 0.000 -0.90992E-11 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -14.29 -7.63 -2.544 0.13030E+05 -5.932 3 CH4,gas 4.54 -13.74 -18.28 -4.571 0.31217E+05 -16.584 4 H2,gas 8.00 0.14 -7.86 -4.492 0.13424E+05 -6.163 5 H2S,gas -6.23 -22.74 -16.51 -8.255 0.28191E+05 -14.811 6 S2,gas -7.34 -45.76 -38.42 -5.911 0.65604E+05 -36.723 7 CO,gas 3.21 -14.15 -17.37 -5.344 0.29656E+05 -15.669 8 SO3,gas 17.12 -23.29 -40.41 -10.104 0.69006E+05 -38.715 9 SO2,gas 0.83 -23.15 -23.99 -6.397 0.40957E+05 -22.288 10 HCl,gas 5.19 -13.19 -18.38 -9.188 0.31376E+05 -16.677 11 acmite 7.71 6.29 -1.42 -0.148 0.24314E+04 15 albite-high 0.69 -0.80 -1.49 -0.115 0.25419E+04 16 albite -0.38 -0.80 -0.41 -0.032 0.70308E+03 19 spessartine 24.46 20.53 -3.93 -0.196 0.67074E+04 20 analcite 3.32 2.52 -0.80 -0.089 0.13689E+04 21 andalusite 5.00 1.72 -3.28 -0.328 0.56044E+04 22 andradite 39.01 34.58 -4.43 -0.230 0.75631E+04 26 annite 20.12 16.57 -3.55 -0.197 0.60674E+04 27 phlogopite 27.06 23.26 -3.81 -0.212 0.65007E+04 29 anorthite 12.71 9.06 -3.65 -0.281 0.62380E+04 35 aragonite 0.97 -3.64 -4.60 -1.535 0.78622E+04 36 brucite 12.57 8.58 -3.99 -0.797 0.68082E+04 37 calcite 0.81 -3.64 -4.45 -1.483 0.75979E+04 38 carnegieite-low 9.02 5.84 -3.19 -0.455 0.54423E+04 39 carnegieite-high 10.09 5.84 -4.26 -0.608 0.72692E+04 40 carpholite-Mg 8.58 6.98 -1.60 -0.106 0.27274E+04 41 carpholite-Fe 6.71 4.76 -1.96 -0.130 0.33416E+04 42 celadonite 5.34 2.78 -2.56 -0.151 0.43756E+04 43 celadonite-Fe 3.88 0.55 -3.33 -0.196 0.56802E+04 44 chrysotile 23.89 19.11 -4.78 -0.398 0.81619E+04 50 chloritoid-Mg 13.20 10.30 -2.90 -0.193 0.49468E+04 51 chloritoid-Fe 9.17 8.07 -1.10 -0.073 0.18820E+04 52 chloritoid-Mn 11.40 10.20 -1.20 -0.080 0.20512E+04 54 coesite -2.38 -3.32 -0.94 -0.313 0.16046E+04 59 corundum 8.38 5.04 -3.35 -0.304 0.57167E+04 61 cristobalite -2.56 -3.32 -0.76 -0.252 0.12899E+04 63 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71234E+04 65 diaspore 2.87 2.52 -0.36 -0.059 0.60814E+03 67 diopside 16.18 12.60 -3.58 -0.358 0.61096E+04 68 hedenbergite 14.21 10.37 -3.83 -0.383 0.65468E+04 75 epidote 24.67 22.68 -1.99 -0.097 0.34015E+04 76 clinozoisite 22.81 18.91 -3.89 -0.177 0.66485E+04 77 epidote-Fe 29.84 26.44 -3.40 -0.176 0.58010E+04 78 fayalite 14.05 9.39 -4.66 -0.665 0.79521E+04 83 gibbsite 4.08 2.52 -1.56 -0.223 0.26667E+04 87 greenalite 16.14 12.42 -3.71 -0.310 0.63426E+04 91 heulandite -5.83 -7.52 -1.69 -0.077 0.28938E+04 95 jadeite 4.22 2.52 -1.70 -0.170 0.28943E+04 97 kalsilite 7.58 4.15 -3.44 -0.491 0.58716E+04 98 kaolinite -1.33 -1.60 -0.26 -0.024 0.45040E+03 99 kyanite 4.88 1.72 -3.16 -0.316 0.53903E+04 101 laumontite 2.88 2.43 -0.46 -0.031 0.78210E+03 102 lawsonite 9.62 9.06 -0.56 -0.037 0.95463E+03 103 leucite 4.12 0.83 -3.29 -0.329 0.56168E+04 105 lizardite 23.24 19.11 -4.13 -0.344 0.70545E+04 107 magnetite 20.09 18.92 -1.17 -0.095 0.19961E+04 108 minnesotaite 10.39 5.79 -4.59 -0.270 0.78456E+04 113 margarite 17.32 14.09 -3.23 -0.129 0.55178E+04 120 muscovite 2.58 2.55 -0.03 -0.002 0.57821E+02 122 nepheline 8.34 5.84 -2.50 -0.358 0.42746E+04 134 phlogopite-Na 29.65 24.95 -4.70 -0.261 0.80226E+04 136 prehnite 19.37 16.39 -2.98 -0.175 0.50834E+04 137 prehnite-Fe 22.50 20.16 -2.34 -0.141 0.39914E+04 138 pumpellyite-Fe 46.27 41.66 -4.61 -0.102 0.78720E+04 145 pyroxmangite 7.40 5.16 -2.23 -0.447 0.38145E+04 146 pyrophyllite -6.18 -8.23 -2.05 -0.128 0.35044E+04 147 quartz -2.99 -3.32 -0.33 -0.109 0.55727E+03 151 rhodochrosite -0.98 -5.81 -4.83 -1.612 0.82552E+04 152 rhodonite 7.45 5.16 -2.28 -0.456 0.38948E+04 153 sanidine -1.28 -2.49 -1.21 -0.093 0.20677E+04 156 sillimanite 5.26 1.72 -3.54 -0.354 0.60483E+04 164 stilpnomelane-Fe 13.02 12.74 -0.28 -0.008 0.47104E+03 165 stilpnomelane-Mg 27.44 23.89 -3.55 -0.106 0.60694E+04 168 sudoite 21.08 17.29 -3.79 -0.122 0.64748E+04 171 talc 16.49 12.48 -4.01 -0.236 0.68477E+04 174 tephroite 18.09 13.65 -4.44 -0.634 0.75823E+04 177 topaz-H 4.62 1.72 -2.90 -0.264 0.49504E+04 178 tridymite -2.63 -3.32 -0.69 -0.230 0.11772E+04 187 wairakite 3.95 2.43 -1.53 -0.090 0.26041E+04 188 walstromite 11.51 7.34 -4.17 -0.834 0.71227E+04 189 wollastonite 10.46 7.34 -3.12 -0.625 0.53332E+04 190 pseudo-wollastonite 11.00 7.34 -3.66 -0.732 0.62530E+04 191 zoisite 22.85 18.91 -3.94 -0.179 0.67226E+04 192 akaganeite 7.75 6.28 -1.47 -0.318 0.25125E+04 193 beidellite-Ca -1.65 -4.55 -2.90 -0.179 0.49512E+04 194 beidellite-H -2.33 -6.30 -3.98 -0.254 0.67905E+04 195 beidellite-K -1.52 -4.67 -3.15 -0.193 0.53813E+04 196 beidellite-Mg -1.79 -4.89 -3.10 -0.192 0.52888E+04 197 beidellite-Na -1.34 -4.11 -2.77 -0.170 0.47325E+04 199 chalcedony -2.80 -3.32 -0.51 -0.171 0.87657E+03 201 montmorillonite-Ca -2.29 -4.47 -2.18 -0.135 0.37199E+04 202 montmorillonite-K -2.24 -4.60 -2.36 -0.144 0.40281E+04 203 montmorillonite-Mg -2.48 -4.81 -2.33 -0.144 0.39807E+04 204 montmorillonite-Na -2.04 -4.04 -2.00 -0.122 0.34150E+04 205 nontronite-Ca 3.21 2.99 -0.23 -0.015 0.39058E+03 206 nontronite-H 2.53 1.23 -1.30 -0.087 0.22278E+04 207 nontronite-K 3.34 2.86 -0.48 -0.031 0.82201E+03 208 nontronite-Mg 3.07 2.64 -0.43 -0.028 0.73549E+03 209 nontronite-Na 3.52 3.42 -0.10 -0.007 0.17491E+03 224 tobermorite 9.82 5.56 -4.26 -1.164 0.72815E+04 233 boehmite 4.41 2.52 -1.89 -0.315 0.32251E+04 235 ferrous-oxide 9.81 6.35 -3.46 -0.865 0.59069E+04 240 silica-amorphous -2.09 -3.32 -1.22 -0.408 0.20907E+04 242 an20ab80 2.02 1.17 -0.84 -0.065 0.14392E+04 243 an25ab75 2.65 1.67 -0.98 -0.075 0.16702E+04 244 an30ab70 3.28 2.16 -1.12 -0.086 0.19108E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 0.0400000 g Current total amount of reactant added: 1.9190000 g New total amount of reactant added: 1.9590000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.4573E-13 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 6 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 1.9590000 Water: Moles liquid = 0.5549E+02 kg liquid = 0.9996E+00 Moles total = 0.5548E+02 kg total = 0.9996E+00 Activity = 1.0000 Stoichiometric ionic strength = .1593359E-02 Osmotic coef. = 0.9773 True ionic strength = .2524688E-02 Chg. balance for total moles = 0.4573E-13 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.54599E-09 -9.2628 0.50326E-09 -9.2982 0.92174E+00 -0.0354 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13793E-03 -3.8603 0.12701E-03 -3.8962 0.92081E+00 -0.0358 4 SO4-- 0.25499E-04 -4.5935 0.19384E-04 -4.7126 0.76017E+00 -0.1191 5 HCO3- 0.10793E-04 -4.9668 0.99409E-05 -5.0026 0.92103E+00 -0.0357 6 HS- 0.38955E-13 -13.4094 0.35871E-13 -13.4453 0.92083E+00 -0.0358 7 Al+++ 0.74921E-25 -25.1254 0.41247E-25 -25.3846 0.55053E+00 -0.2592 8 H4SiO4 0.48585E-03 -3.3135 0.48585E-03 -3.3135 0.10000E+01 0.0000 9 Ca++ 0.14984E-07 -7.8244 0.11376E-07 -7.9440 0.75924E+00 -0.1196 10 Mg++ 0.12778E-09 -9.8936 0.96939E-10 -10.0135 0.75866E+00 -0.1200 11 Fe++ 0.75376E-12 -12.1228 0.57195E-12 -12.2426 0.75880E+00 -0.1199 12 K+ 0.48027E-04 -4.3185 0.44236E-04 -4.3542 0.92107E+00 -0.0357 13 Na+ 0.24407E-02 -2.6125 0.22473E-02 -2.6483 0.92078E+00 -0.0358 14 Mn++ 0.10127E-09 -9.9945 0.76857E-10 -10.1143 0.75891E+00 -0.1198 15 HPO4-- 0.81341E-05 -5.0897 0.61834E-05 -5.2088 0.76018E+00 -0.1191 16 HSiO3- 0.97897E-03 -3.0092 0.90144E-03 -3.0451 0.92081E+00 -0.0358 17 Ca(HSiO3)+ 0.25355E-09 -9.5959 0.23354E-09 -9.6316 0.92110E+00 -0.0357 18 Mg(HSiO3)+ 0.26888E-11 -11.5704 0.24767E-11 -11.6061 0.92110E+00 -0.0357 19 NaHSiO3,aq 0.32765E-04 -4.4846 0.32765E-04 -4.4846 0.10000E+01 0.0000 20 AlO+ 0.24053E-13 -13.6188 0.22156E-13 -13.6545 0.92110E+00 -0.0357 21 AlOH+2 0.73146E-19 -19.1358 0.55520E-19 -19.2555 0.75903E+00 -0.1197 22 HAlO2,aq 0.87674E-08 -8.0571 0.87674E-08 -8.0571 0.10000E+01 0.0000 23 AlO2- 0.41893E-04 -4.3779 0.38564E-04 -4.4138 0.92052E+00 -0.0360 24 CH4,aq 0.17879E-19 -19.7477 0.17870E-19 -19.7479 0.99951E+00 -0.0002 29 CO,aq 0.14170E-18 -18.8486 0.14170E-18 -18.8486 0.10000E+01 0.0000 30 CO2,aq 0.10695E-07 -7.9708 0.10690E-07 -7.9710 0.99951E+00 -0.0002 31 CO3-2 0.22705E-05 -5.6439 0.17254E-05 -5.7631 0.75989E+00 -0.1192 32 CaCO3,aq 0.24611E-09 -9.6089 0.24611E-09 -9.6089 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.31340E-11 -11.5039 0.28867E-11 -11.5396 0.92110E+00 -0.0357 34 CaCl+ 0.25385E-11 -11.5954 0.23382E-11 -11.6311 0.92110E+00 -0.0357 35 CaCl2,aq 0.70553E-16 -16.1515 0.70553E-16 -16.1515 0.10000E+01 0.0000 36 CaOH+ 0.17490E-08 -8.7572 0.16111E-08 -8.7929 0.92110E+00 -0.0357 37 CaSO4,aq 0.70023E-10 -10.1548 0.70023E-10 -10.1548 0.10000E+01 0.0000 38 HCl,aq 0.11712E-13 -13.9314 0.11712E-13 -13.9314 0.10000E+01 0.0000 43 FeCl+ 0.12483E-15 -15.9037 0.11498E-15 -15.9394 0.92110E+00 -0.0357 46 FeO,aq 0.87770E-10 -10.0567 0.87770E-10 -10.0567 0.10000E+01 0.0000 47 FeOH+ 0.40163E-10 -10.3962 0.36994E-10 -10.4319 0.92110E+00 -0.0357 48 HFeO2- 0.19817E-08 -8.7030 0.18248E-08 -8.7388 0.92081E+00 -0.0358 49 FeO+ 0.41703E-14 -14.3798 0.38413E-14 -14.4155 0.92110E+00 -0.0357 51 FeO2- 0.33704E-08 -8.4723 0.31035E-08 -8.5082 0.92081E+00 -0.0358 52 HFeO2,aq 0.19864E-09 -9.7019 0.19864E-09 -9.7019 0.10000E+01 0.0000 53 H2,aq 0.52793E-09 -9.2774 0.52767E-09 -9.2776 0.99951E+00 -0.0002 54 KCl,aq 0.10183E-09 -9.9921 0.10183E-09 -9.9921 0.10000E+01 0.0000 55 KHSO4,aq 0.12201E-17 -17.9136 0.12201E-17 -17.9136 0.10000E+01 0.0000 56 KOH,aq 0.37538E-07 -7.4255 0.37538E-07 -7.4255 0.10000E+01 0.0000 57 KSO4- 0.14450E-07 -7.8401 0.13306E-07 -7.8760 0.92081E+00 -0.0358 58 MgCO3,aq 0.52567E-12 -12.2793 0.52567E-12 -12.2793 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.27288E-13 -13.5640 0.25135E-13 -13.5997 0.92110E+00 -0.0357 60 MgCl+ 0.19605E-13 -13.7076 0.18058E-13 -13.7433 0.92110E+00 -0.0357 61 MgOH+ 0.82471E-10 -10.0837 0.75965E-10 -10.1194 0.92110E+00 -0.0357 63 MnO,aq 0.31426E-09 -9.5027 0.31426E-09 -9.5027 0.10000E+01 0.0000 64 MnOH+ 0.50136E-09 -9.2999 0.46180E-09 -9.3355 0.92110E+00 -0.0357 65 MnO2-2 0.54192E-13 -13.2661 0.41180E-13 -13.3853 0.75989E+00 -0.1192 66 HMnO2- 0.49308E-11 -11.3071 0.45403E-11 -11.3429 0.92081E+00 -0.0358 69 MnCl+ 0.65258E-13 -13.1854 0.60109E-13 -13.2211 0.92110E+00 -0.0357 70 MnSO4,aq 0.43008E-12 -12.3664 0.43008E-12 -12.3664 0.10000E+01 0.0000 71 NaCl,aq 0.94590E-07 -7.0242 0.94590E-07 -7.0242 0.10000E+01 0.0000 72 NaOH,aq 0.19186E-05 -5.7170 0.19186E-05 -5.7170 0.10000E+01 0.0000 74 OH- 0.12472E-02 -2.9041 0.11481E-02 -2.9400 0.92052E+00 -0.0360 79 HPO3-2 0.13381E-16 -16.8735 0.10168E-16 -16.9928 0.75989E+00 -0.1192 81 H2PO3- 0.11144E-19 -19.9530 0.10261E-19 -19.9888 0.92081E+00 -0.0358 82 H3PO4,aq 0.10953E-13 -13.9605 0.10953E-13 -13.9605 0.10000E+01 0.0000 83 H2PO4- 0.62333E-07 -7.2053 0.57405E-07 -7.2410 0.92095E+00 -0.0358 84 PO4-3 0.18059E-07 -7.7433 0.10025E-07 -7.9989 0.55510E+00 -0.2556 87 H2P2O7-2 0.34004E-15 -15.4685 0.25839E-15 -15.5877 0.75989E+00 -0.1192 88 HP2O7-3 0.18620E-12 -12.7300 0.10252E-12 -12.9892 0.55058E+00 -0.2592 89 P2O7-4 0.13806E-12 -12.8599 0.48667E-13 -13.3128 0.35252E+00 -0.4528 90 H2S,aq 0.55820E-16 -16.2532 0.55792E-16 -16.2534 0.99951E+00 -0.0002 97 SO3-2 0.17449E-14 -14.7582 0.13291E-14 -14.8764 0.76175E+00 -0.1182 98 HSO3- 0.45483E-16 -16.3421 0.41881E-16 -16.3780 0.92081E+00 -0.0358 99 HSO4- 0.10205E-10 -10.9912 0.94010E-11 -11.0268 0.92125E+00 -0.0356 Charge balance for all species = 0.4618E-13 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.5459862E-09 -.2430709E-02 -.2449485E+01 0.0000 2 H2O 0.1000000E+01 0.5550857E+02 0.9997897E+06 0.0000 3 Cl- 0.1379295E-03 0.1380242E-03 0.4892326E+01 5.4020 4 SO4-- 0.2549919E-04 0.2551403E-04 0.2450394E+01 13.8839 5 HCO3- 0.1079326E-04 0.1307474E-04 0.7976133E+00 4.2956 6 HS- 0.3895460E-13 -.3141083E-09 -.1038597E-04 -4.1471 7 Al+++ 0.7492140E-25 0.4190183E-04 0.1130332E+01 2.5100 8 H4SiO4 0.4858463E-03 0.1497577E-02 0.1439094E+03 -3.3135 9 Ca++ 0.1498356E-07 0.1730796E-07 0.6935202E-03 10.6524 10 Mg++ 0.1277759E-09 0.2135086E-09 0.5189710E-05 8.5829 11 Fe++ 0.7537571E-12 0.5679473E-08 0.3171137E-03 6.3538 12 K+ 0.4802706E-04 0.4807915E-04 0.1879589E+01 4.9440 13 Na+ 0.2440654E-02 0.2475432E-02 0.5689752E+02 6.6499 14 Mn++ 0.1012732E-09 0.9223782E-09 0.5066277E-04 8.4821 15 HPO4-- 0.8134133E-05 0.8214526E-05 0.7882534E+00 13.3877 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.3242509E-01 -.2429828E-02 -.2999526E-01 0.0000000E+00 2 H2O 0.5548369E+02 0.5548845E+02 -.4760423E-02 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.7979504E-04 0.2550478E-04 0.5429025E-04 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.5429057E-04 -.3139944E-09 -.5429025E-04 0.0000000E+00 7 Al+++ 0.6387793E-02 0.4188664E-04 0.6345906E-02 0.0000000E+00 8 H4SiO4 0.2039864E-01 0.1497034E-02 0.1890161E-01 0.0000000E+00 9 Ca++ 0.2267601E-02 0.1730169E-07 0.2267583E-02 0.0000000E+00 10 Mg++ 0.1554762E-02 0.2134312E-09 0.1554762E-02 0.0000000E+00 11 Fe++ 0.1396784E-02 0.5677415E-08 0.1396778E-02 0.0000000E+00 12 K+ 0.4159236E-03 0.4806172E-04 0.3678618E-03 0.0000000E+00 13 Na+ 0.2619093E-02 0.2474535E-02 0.1445582E-03 0.0000000E+00 14 Mn++ 0.3396631E-04 0.9220439E-09 0.3396539E-04 0.0000000E+00 15 HPO4-- 0.1159253E-04 0.8211549E-05 0.3380984E-05 0.0000000E+00 Chg. balance for solid moles: 0.1357E-17 Mass of aqueous solution: 0.999851E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 1.9590000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) apatite-OH 0.1127E-05 -5.948 0.5661E-03 -3.247 0.2693E-01 0.1799E-03 clinochlore 0.3110E-03 -3.507 0.1728 -0.762 8.223 0.6574E-01 daphnite 0.1925E-03 -3.716 0.1373 -0.862 6.534 0.4162E-01 chlorite-Mn 0.6793E-05 -5.168 0.4816E-02 -2.317 0.2291 0.1535E-02 hematite 0.2172E-03 -3.663 0.3468E-01 -1.460 1.650 0.6573E-02 microcline 0.3679E-03 -3.434 0.1024 -0.990 4.871 0.4000E-01 paragonite 0.1446E-03 -3.840 0.5525E-01 -1.258 2.629 0.1910E-01 stilbite 0.2262E-02 -2.646 1.594 0.202 75.84 0.7435 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.6094E+00 0.6094E+00 1.0000 -0.215 daphnite 0.3773E+00 0.3773E+00 1.0000 -0.423 chlorite-Mn 0.1331E-01 0.1331E-01 1.0000 -1.876 hematite 0.1000E+01 0.1000E+01 1.0000 0.000 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 paragonite 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 2.101925 g Volume = 0.918233 cm3 Porosity: 48.5180% V(tot) - V(min): 0.86537E+00 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 1.9590000 g log = 0.2920 Original solution: 1000.0103000 g Original solution / Rock added: 510.47 (Water/Rock Ratio), log = 2.7080 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0203 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.1000E+01 0.9860 0.1006E+01 0.1020E+01 CO2,gas 0.1113E-05 1.0071 0.1144E-05 0.1136E-05 CH4,gas 0.2546E-16 1.0125 0.2630E-16 0.2598E-16 H2,gas 0.6786E-06 1.0005 0.6928E-06 0.6924E-06 H2S,gas 0.1509E-14 0.9960 0.1534E-14 0.1540E-14 S2,gas 0.1803E-36 1.0000 0.1840E-36 0.1840E-36 CO,gas 0.2070E-15 1.0000 0.2112E-15 0.2112E-15 SO3,gas 0.1819E-38 1.0000 0.1856E-38 0.1856E-38 SO2,gas 0.4903E-22 1.0000 0.5003E-22 0.5003E-22 HCl,gas 0.2026E-16 1.0000 0.2067E-16 0.2067E-16 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 32 apatite-OH -18.15 -18.15 0.00 0.000 0.12132E-10 46 clinochlore 39.07 39.07 0.00 0.000 0.12132E-10 47 daphnite 28.97 28.97 0.00 0.000 0.18198E-10 48 chlorite-Mn 46.87 46.87 0.00 0.000 0.12132E-10 90 hematite 12.57 12.57 0.00 0.000 -0.90992E-11 116 microcline -2.49 -2.49 0.00 0.000 0.15165E-11 121 paragonite 4.24 4.24 0.00 0.000 0.13649E-10 163 stilbite -7.52 -7.52 0.00 0.000 0.15165E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -14.30 -7.64 -2.547 0.13046E+05 -5.942 3 CH4,gas 4.54 -13.74 -18.28 -4.570 0.31211E+05 -16.580 4 H2,gas 8.00 0.14 -7.86 -4.491 0.13418E+05 -6.159 5 H2S,gas -6.23 -22.74 -16.51 -8.257 0.28196E+05 -14.814 6 S2,gas -7.34 -45.77 -38.43 -5.913 0.65625E+05 -36.735 7 CO,gas 3.21 -14.16 -17.37 -5.346 0.29666E+05 -15.675 8 SO3,gas 17.12 -23.31 -40.43 -10.108 0.69034E+05 -38.731 9 SO2,gas 0.83 -23.17 -24.00 -6.400 0.40979E+05 -22.301 10 HCl,gas 5.19 -13.19 -18.38 -9.192 0.31390E+05 -16.685 11 acmite 7.71 6.31 -1.40 -0.146 0.23969E+04 15 albite-high 0.69 -0.78 -1.47 -0.113 0.25162E+04 16 albite -0.38 -0.78 -0.40 -0.031 0.67743E+03 19 spessartine 24.46 20.53 -3.93 -0.197 0.67129E+04 20 analcite 3.32 2.53 -0.79 -0.088 0.13471E+04 21 andalusite 5.00 1.71 -3.29 -0.329 0.56261E+04 22 andradite 39.01 34.58 -4.43 -0.230 0.75570E+04 26 annite 20.12 16.57 -3.55 -0.197 0.60591E+04 27 phlogopite 27.06 23.26 -3.80 -0.211 0.64924E+04 29 anorthite 12.71 9.05 -3.66 -0.282 0.62577E+04 35 aragonite 0.97 -3.65 -4.61 -1.538 0.78798E+04 36 brucite 12.57 8.58 -3.99 -0.797 0.68054E+04 37 calcite 0.81 -3.65 -4.46 -1.487 0.76156E+04 38 carnegieite-low 9.02 5.85 -3.18 -0.454 0.54245E+04 39 carnegieite-high 10.09 5.85 -4.25 -0.607 0.72515E+04 40 carpholite-Mg 8.58 6.98 -1.61 -0.107 0.27424E+04 41 carpholite-Fe 6.71 4.75 -1.97 -0.131 0.33566E+04 42 celadonite 5.34 2.78 -2.56 -0.151 0.43689E+04 43 celadonite-Fe 3.88 0.55 -3.32 -0.195 0.56735E+04 44 chrysotile 23.89 19.12 -4.77 -0.398 0.81457E+04 50 chloritoid-Mg 13.20 10.29 -2.91 -0.194 0.49657E+04 51 chloritoid-Fe 9.17 8.06 -1.11 -0.074 0.19009E+04 52 chloritoid-Mn 11.40 10.19 -1.21 -0.081 0.20702E+04 54 coesite -2.38 -3.31 -0.94 -0.312 0.16007E+04 59 corundum 8.38 5.02 -3.36 -0.306 0.57424E+04 61 cristobalite -2.56 -3.31 -0.75 -0.251 0.12860E+04 63 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71234E+04 65 diaspore 2.87 2.51 -0.36 -0.061 0.62097E+03 67 diopside 16.18 12.61 -3.57 -0.357 0.61008E+04 68 hedenbergite 14.21 10.38 -3.83 -0.383 0.65381E+04 75 epidote 24.67 22.67 -2.00 -0.097 0.34191E+04 76 clinozoisite 22.81 18.89 -3.91 -0.178 0.66790E+04 77 epidote-Fe 29.84 26.44 -3.40 -0.177 0.58059E+04 78 fayalite 14.05 9.39 -4.65 -0.665 0.79426E+04 83 gibbsite 4.08 2.51 -1.57 -0.224 0.26795E+04 87 greenalite 16.14 12.43 -3.71 -0.309 0.63265E+04 91 heulandite -5.83 -7.52 -1.69 -0.077 0.28938E+04 95 jadeite 4.22 2.53 -1.68 -0.168 0.28726E+04 97 kalsilite 7.58 4.14 -3.44 -0.492 0.58795E+04 98 kaolinite -1.33 -1.61 -0.27 -0.025 0.46818E+03 99 kyanite 4.88 1.71 -3.17 -0.317 0.54120E+04 101 laumontite 2.88 2.42 -0.46 -0.031 0.79391E+03 102 lawsonite 9.62 9.05 -0.57 -0.038 0.97432E+03 103 leucite 4.12 0.83 -3.29 -0.329 0.56208E+04 105 lizardite 23.24 19.12 -4.12 -0.344 0.70384E+04 107 magnetite 20.09 18.92 -1.17 -0.095 0.19934E+04 108 minnesotaite 10.39 5.81 -4.58 -0.269 0.78215E+04 113 margarite 17.32 14.07 -3.26 -0.130 0.55632E+04 120 muscovite 2.58 2.53 -0.05 -0.003 0.83471E+02 122 nepheline 8.34 5.85 -2.49 -0.356 0.42568E+04 134 phlogopite-Na 29.65 24.97 -4.68 -0.260 0.79886E+04 136 prehnite 19.37 16.38 -2.99 -0.176 0.51011E+04 137 prehnite-Fe 22.50 20.16 -2.34 -0.141 0.39962E+04 138 pumpellyite-Fe 46.27 41.63 -4.64 -0.103 0.79174E+04 145 pyroxmangite 7.40 5.17 -2.23 -0.446 0.38078E+04 146 pyrophyllite -6.18 -8.23 -2.06 -0.129 0.35143E+04 147 quartz -2.99 -3.31 -0.32 -0.108 0.55333E+03 151 rhodochrosite -0.98 -5.82 -4.84 -1.614 0.82682E+04 152 rhodonite 7.45 5.17 -2.28 -0.455 0.38880E+04 153 sanidine -1.28 -2.49 -1.21 -0.093 0.20677E+04 156 sillimanite 5.26 1.71 -3.55 -0.355 0.60700E+04 164 stilpnomelane-Fe 13.02 12.75 -0.26 -0.008 0.45085E+03 165 stilpnomelane-Mg 27.44 23.90 -3.54 -0.106 0.60492E+04 168 sudoite 21.08 17.27 -3.81 -0.123 0.65088E+04 171 talc 16.49 12.49 -4.00 -0.235 0.68236E+04 174 tephroite 18.09 13.65 -4.44 -0.634 0.75728E+04 177 topaz-H 4.62 1.71 -2.91 -0.265 0.49721E+04 178 tridymite -2.63 -3.31 -0.69 -0.229 0.11733E+04 187 wairakite 3.95 2.42 -1.53 -0.090 0.26159E+04 188 walstromite 11.51 7.34 -4.17 -0.834 0.71207E+04 189 wollastonite 10.46 7.34 -3.12 -0.624 0.53311E+04 190 pseudo-wollastonite 11.00 7.34 -3.66 -0.732 0.62510E+04 191 zoisite 22.85 18.89 -3.96 -0.180 0.67531E+04 192 akaganeite 7.75 6.28 -1.47 -0.318 0.25125E+04 193 beidellite-Ca -1.65 -4.55 -2.91 -0.180 0.49670E+04 194 beidellite-H -2.33 -6.31 -3.99 -0.254 0.68059E+04 195 beidellite-K -1.52 -4.68 -3.16 -0.194 0.53964E+04 196 beidellite-Mg -1.79 -4.90 -3.11 -0.192 0.53038E+04 197 beidellite-Na -1.34 -4.12 -2.78 -0.170 0.47391E+04 199 chalcedony -2.80 -3.31 -0.51 -0.170 0.87263E+03 201 montmorillonite-Ca -2.29 -4.47 -2.18 -0.135 0.37249E+04 202 montmorillonite-K -2.24 -4.60 -2.36 -0.145 0.40325E+04 203 montmorillonite-Mg -2.48 -4.81 -2.33 -0.144 0.39850E+04 204 montmorillonite-Na -2.04 -4.04 -2.00 -0.122 0.34109E+04 205 nontronite-Ca 3.21 2.99 -0.22 -0.014 0.38068E+03 206 nontronite-H 2.53 1.23 -1.30 -0.087 0.22176E+04 207 nontronite-K 3.34 2.87 -0.48 -0.031 0.81146E+03 208 nontronite-Mg 3.07 2.65 -0.42 -0.028 0.72482E+03 209 nontronite-Na 3.52 3.43 -0.09 -0.006 0.15589E+03 224 tobermorite 9.82 5.56 -4.26 -1.163 0.72791E+04 233 boehmite 4.41 2.51 -1.90 -0.316 0.32379E+04 235 ferrous-oxide 9.81 6.35 -3.46 -0.864 0.59041E+04 240 silica-amorphous -2.09 -3.31 -1.22 -0.407 0.20868E+04 242 an20ab80 2.02 1.18 -0.83 -0.064 0.14226E+04 243 an25ab75 2.65 1.68 -0.97 -0.075 0.16559E+04 244 an30ab70 3.28 2.17 -1.11 -0.086 0.18988E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 0.0400000 g Current total amount of reactant added: 1.9590000 g New total amount of reactant added: 1.9990000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.4574E-13 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 6 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 1.9990000 Water: Moles liquid = 0.5549E+02 kg liquid = 0.9996E+00 Moles total = 0.5548E+02 kg total = 0.9995E+00 Activity = 1.0000 Stoichiometric ionic strength = .1617587E-02 Osmotic coef. = 0.9771 True ionic strength = .2570493E-02 Chg. balance for total moles = 0.4574E-13 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.53704E-09 -9.2700 0.49475E-09 -9.3056 0.92125E+00 -0.0356 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13793E-03 -3.8603 0.12694E-03 -3.8964 0.92030E+00 -0.0361 4 SO4-- 0.25500E-04 -4.5935 0.19342E-04 -4.7135 0.75854E+00 -0.1200 5 HCO3- 0.10758E-04 -4.9683 0.99034E-05 -5.0042 0.92053E+00 -0.0360 6 HS- 0.39372E-13 -13.4048 0.36236E-13 -13.4409 0.92033E+00 -0.0361 7 Al+++ 0.70332E-25 -25.1528 0.38532E-25 -25.4142 0.54786E+00 -0.2613 8 H4SiO4 0.48837E-03 -3.3113 0.48837E-03 -3.3113 0.10000E+01 0.0000 9 Ca++ 0.14478E-07 -7.8393 0.10968E-07 -7.9599 0.75760E+00 -0.1206 10 Mg++ 0.12422E-09 -9.9058 0.94033E-10 -10.0267 0.75701E+00 -0.1209 11 Fe++ 0.73275E-12 -12.1350 0.55480E-12 -12.2559 0.75715E+00 -0.1208 12 K+ 0.47306E-04 -4.3251 0.43549E-04 -4.3610 0.92057E+00 -0.0359 13 Na+ 0.24868E-02 -2.6044 0.22886E-02 -2.6404 0.92028E+00 -0.0361 14 Mn++ 0.98451E-10 -10.0068 0.74553E-10 -10.1275 0.75726E+00 -0.1208 15 HPO4-- 0.84681E-05 -5.0722 0.64235E-05 -5.1922 0.75856E+00 -0.1200 16 HSiO3- 0.10015E-02 -2.9993 0.92170E-03 -3.0354 0.92030E+00 -0.0361 17 Ca(HSiO3)+ 0.25009E-09 -9.6019 0.23023E-09 -9.6378 0.92061E+00 -0.0359 18 Mg(HSiO3)+ 0.26683E-11 -11.5738 0.24564E-11 -11.6097 0.92061E+00 -0.0359 19 NaHSiO3,aq 0.34116E-04 -4.4670 0.34116E-04 -4.4670 0.10000E+01 0.0000 20 AlO+ 0.23262E-13 -13.6333 0.21416E-13 -13.6693 0.92061E+00 -0.0359 21 AlOH+2 0.69659E-19 -19.1570 0.52758E-19 -19.2777 0.75739E+00 -0.1207 22 HAlO2,aq 0.86203E-08 -8.0645 0.86203E-08 -8.0645 0.10000E+01 0.0000 23 AlO2- 0.41921E-04 -4.3776 0.38568E-04 -4.4138 0.92002E+00 -0.0362 24 CH4,aq 0.18031E-19 -19.7440 0.18022E-19 -19.7442 0.99950E+00 -0.0002 29 CO,aq 0.13980E-18 -18.8545 0.13980E-18 -18.8545 0.10000E+01 0.0000 30 CO2,aq 0.10475E-07 -7.9799 0.10469E-07 -7.9801 0.99950E+00 -0.0002 31 CO3-2 0.23058E-05 -5.6372 0.17484E-05 -5.7574 0.75826E+00 -0.1202 32 CaCO3,aq 0.24046E-09 -9.6190 0.24046E-09 -9.6190 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.30119E-11 -11.5212 0.27728E-11 -11.5571 0.92061E+00 -0.0359 34 CaCl+ 0.24475E-11 -11.6113 0.22532E-11 -11.6472 0.92061E+00 -0.0359 35 CaCl2,aq 0.67950E-16 -16.1678 0.67950E-16 -16.1678 0.10000E+01 0.0000 36 CaOH+ 0.17163E-08 -8.7654 0.15800E-08 -8.8013 0.92061E+00 -0.0359 37 CaSO4,aq 0.67370E-10 -10.1715 0.67370E-10 -10.1715 0.10000E+01 0.0000 38 HCl,aq 0.11508E-13 -13.9390 0.11508E-13 -13.9390 0.10000E+01 0.0000 43 FeCl+ 0.12108E-15 -15.9169 0.11147E-15 -15.9528 0.92061E+00 -0.0359 46 FeO,aq 0.88092E-10 -10.0551 0.88092E-10 -10.0551 0.10000E+01 0.0000 47 FeOH+ 0.39650E-10 -10.4018 0.36502E-10 -10.4377 0.92061E+00 -0.0359 48 HFeO2- 0.20243E-08 -8.6937 0.18630E-08 -8.7298 0.92030E+00 -0.0361 49 FeO+ 0.41020E-14 -14.3870 0.37764E-14 -14.4229 0.92061E+00 -0.0359 51 FeO2- 0.34302E-08 -8.4647 0.31568E-08 -8.5007 0.92030E+00 -0.0361 52 HFeO2,aq 0.19864E-09 -9.7019 0.19864E-09 -9.7019 0.10000E+01 0.0000 53 H2,aq 0.53182E-09 -9.2742 0.53155E-09 -9.2745 0.99950E+00 -0.0002 54 KCl,aq 0.10019E-09 -9.9992 0.10019E-09 -9.9992 0.10000E+01 0.0000 55 KHSO4,aq 0.11783E-17 -17.9287 0.11783E-17 -17.9287 0.10000E+01 0.0000 56 KOH,aq 0.37591E-07 -7.4249 0.37591E-07 -7.4249 0.10000E+01 0.0000 57 KSO4- 0.14203E-07 -7.8476 0.13071E-07 -7.8837 0.92030E+00 -0.0361 58 MgCO3,aq 0.51672E-12 -12.2867 0.51672E-12 -12.2867 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.26384E-13 -13.5787 0.24289E-13 -13.6146 0.92061E+00 -0.0359 60 MgCl+ 0.19017E-13 -13.7209 0.17507E-13 -13.7568 0.92061E+00 -0.0359 61 MgOH+ 0.81418E-10 -10.0893 0.74954E-10 -10.1252 0.92061E+00 -0.0359 63 MnO,aq 0.31542E-09 -9.5011 0.31542E-09 -9.5011 0.10000E+01 0.0000 64 MnOH+ 0.49496E-09 -9.3054 0.45566E-09 -9.3414 0.92061E+00 -0.0359 65 MnO2-2 0.56399E-13 -13.2487 0.42765E-13 -13.3689 0.75826E+00 -0.1202 66 HMnO2- 0.50368E-11 -11.2978 0.46354E-11 -11.3339 0.92030E+00 -0.0361 69 MnCl+ 0.63301E-13 -13.1986 0.58275E-13 -13.2345 0.92061E+00 -0.0359 70 MnSO4,aq 0.41630E-12 -12.3806 0.41630E-12 -12.3806 0.10000E+01 0.0000 71 NaCl,aq 0.96273E-07 -7.0165 0.96273E-07 -7.0165 0.10000E+01 0.0000 72 NaOH,aq 0.19874E-05 -5.7017 0.19874E-05 -5.7017 0.10000E+01 0.0000 74 OH- 0.12693E-02 -2.8964 0.11678E-02 -2.9326 0.92002E+00 -0.0362 79 HPO3-2 0.14033E-16 -16.8529 0.10640E-16 -16.9730 0.75826E+00 -0.1202 81 H2PO3- 0.11471E-19 -19.9404 0.10557E-19 -19.9765 0.92030E+00 -0.0361 82 H3PO4,aq 0.10997E-13 -13.9587 0.10997E-13 -13.9587 0.10000E+01 0.0000 83 H2PO4- 0.63693E-07 -7.1959 0.58626E-07 -7.2319 0.92045E+00 -0.0360 84 PO4-3 0.19174E-07 -7.7173 0.10593E-07 -7.9750 0.55248E+00 -0.2577 87 H2P2O7-2 0.35542E-15 -15.4493 0.26950E-15 -15.5694 0.75826E+00 -0.1202 88 HP2O7-3 0.19851E-12 -12.7022 0.10877E-12 -12.9635 0.54792E+00 -0.2613 89 P2O7-4 0.15027E-12 -12.8231 0.52520E-13 -13.2797 0.34951E+00 -0.4565 90 H2S,aq 0.55435E-16 -16.2562 0.55407E-16 -16.2564 0.99950E+00 -0.0002 97 SO3-2 0.17577E-14 -14.7551 0.13361E-14 -14.8742 0.76014E+00 -0.1191 98 HSO3- 0.44972E-16 -16.3471 0.41388E-16 -16.3831 0.92030E+00 -0.0361 99 HSO4- 0.10016E-10 -10.9993 0.92224E-11 -11.0352 0.92075E+00 -0.0359 Charge balance for all species = 0.4618E-13 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.5370393E-09 -.2476974E-02 -.2496098E+01 0.0000 2 H2O 0.1000000E+01 0.5550857E+02 0.9997861E+06 0.0000 3 Cl- 0.1379288E-03 0.1380252E-03 0.4892343E+01 5.4092 4 SO4-- 0.2549962E-04 0.2551422E-04 0.2450404E+01 13.8977 5 HCO3- 0.1075831E-04 0.1307483E-04 0.7976162E+00 4.3014 6 HS- 0.3937250E-13 -.3206150E-09 -.1060107E-04 -4.1352 7 Al+++ 0.7033186E-25 0.4193003E-04 0.1131089E+01 2.5027 8 H4SiO4 0.4883684E-03 0.1524000E-02 0.1464481E+03 -3.3113 9 Ca++ 0.1447786E-07 0.1675753E-07 0.6714623E-03 10.6514 10 Mg++ 0.1242154E-09 0.2088643E-09 0.5076804E-05 8.5845 11 Fe++ 0.7327512E-12 0.5781670E-08 0.3228187E-03 6.3554 12 K+ 0.4730637E-04 0.4735826E-04 0.1851400E+01 4.9446 13 Na+ 0.2486808E-02 0.2523008E-02 0.5799084E+02 6.6652 14 Mn++ 0.9845076E-10 0.9144017E-09 0.5022448E-04 8.4837 15 HPO4-- 0.8468114E-05 0.8550981E-05 0.8205362E+00 13.4190 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.3308743E-01 -.2476058E-02 -.3061137E-01 0.0000000E+00 2 H2O 0.5548319E+02 0.5548806E+02 -.4864449E-02 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.8090357E-04 0.2550479E-04 0.5539878E-04 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.5539910E-04 -.3204965E-09 -.5539878E-04 0.0000000E+00 7 Al+++ 0.6518222E-02 0.4191453E-04 0.6476308E-02 0.0000000E+00 8 H4SiO4 0.2081515E-01 0.1523437E-02 0.1929172E-01 0.0000000E+00 9 Ca++ 0.2313606E-02 0.1675134E-07 0.2313589E-02 0.0000000E+00 10 Mg++ 0.1586508E-02 0.2087871E-09 0.1586508E-02 0.0000000E+00 11 Fe++ 0.1425304E-02 0.5779533E-08 0.1425298E-02 0.0000000E+00 12 K+ 0.4244161E-03 0.4734076E-04 0.3770754E-03 0.0000000E+00 13 Na+ 0.2669303E-02 0.2522076E-02 0.1472273E-03 0.0000000E+00 14 Mn++ 0.3465985E-04 0.9140638E-09 0.3465894E-04 0.0000000E+00 15 HPO4-- 0.1182924E-04 0.8547821E-05 0.3281414E-05 0.0000000E+00 Chg. balance for solid moles: -.6404E-18 Mass of aqueous solution: 0.999848E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 1.9990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) apatite-OH 0.1094E-05 -5.961 0.5494E-03 -3.260 0.2561E-01 0.1746E-03 clinochlore 0.3173E-03 -3.499 0.1764 -0.754 8.222 0.6708E-01 daphnite 0.1964E-03 -3.707 0.1401 -0.853 6.533 0.4247E-01 chlorite-Mn 0.6932E-05 -5.159 0.4914E-02 -2.309 0.2291 0.1566E-02 hematite 0.2216E-03 -3.654 0.3539E-01 -1.451 1.650 0.6707E-02 microcline 0.3771E-03 -3.424 0.1050 -0.979 4.893 0.4100E-01 paragonite 0.1472E-03 -3.832 0.5627E-01 -1.250 2.623 0.1945E-01 stilbite 0.2308E-02 -2.637 1.627 0.211 75.83 0.7587 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.6094E+00 0.6094E+00 1.0000 -0.215 daphnite 0.3773E+00 0.3773E+00 1.0000 -0.423 chlorite-Mn 0.1331E-01 0.1331E-01 1.0000 -1.876 hematite 0.1000E+01 0.1000E+01 1.0000 0.000 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 paragonite 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 2.145171 g Volume = 0.937116 cm3 Porosity: 47.9264% V(tot) - V(min): 0.86248E+00 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 1.9990000 g log = 0.3008 Original solution: 1000.0103000 g Original solution / Rock added: 500.26 (Water/Rock Ratio), log = 2.6992 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0203 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.1000E+01 0.9860 0.1006E+01 0.1020E+01 CO2,gas 0.1090E-05 1.0071 0.1120E-05 0.1112E-05 CH4,gas 0.2568E-16 1.0125 0.2653E-16 0.2620E-16 H2,gas 0.6836E-06 1.0005 0.6979E-06 0.6975E-06 H2S,gas 0.1499E-14 0.9960 0.1523E-14 0.1529E-14 S2,gas 0.1752E-36 1.0000 0.1788E-36 0.1788E-36 CO,gas 0.2042E-15 1.0000 0.2083E-15 0.2083E-15 SO3,gas 0.1755E-38 1.0000 0.1790E-38 0.1790E-38 SO2,gas 0.4764E-22 1.0000 0.4860E-22 0.4860E-22 HCl,gas 0.1990E-16 1.0000 0.2031E-16 0.2031E-16 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 32 apatite-OH -18.15 -18.15 0.00 0.000 -0.12132E-10 46 clinochlore 39.07 39.07 0.00 0.000 0.00000E+00 47 daphnite 28.97 28.97 0.00 0.000 -0.18198E-10 48 chlorite-Mn 46.87 46.87 0.00 0.000 -0.12132E-10 90 hematite 12.57 12.57 0.00 0.000 -0.30331E-11 116 microcline -2.49 -2.49 0.00 0.000 -0.10616E-10 121 paragonite 4.24 4.24 0.00 0.000 0.13649E-10 163 stilbite -7.52 -7.52 0.00 0.000 -0.90992E-11 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -14.31 -7.65 -2.550 0.13062E+05 -5.951 3 CH4,gas 4.54 -13.73 -18.28 -4.569 0.31205E+05 -16.576 4 H2,gas 8.00 0.14 -7.86 -4.489 0.13413E+05 -6.156 5 H2S,gas -6.23 -22.75 -16.52 -8.258 0.28201E+05 -14.817 6 S2,gas -7.34 -45.78 -38.45 -5.915 0.65647E+05 -36.748 7 CO,gas 3.21 -14.17 -17.38 -5.348 0.29676E+05 -15.681 8 SO3,gas 17.12 -23.32 -40.45 -10.112 0.69061E+05 -38.747 9 SO2,gas 0.83 -23.18 -24.01 -6.403 0.41000E+05 -22.313 10 HCl,gas 5.19 -13.20 -18.39 -9.196 0.31403E+05 -16.692 11 acmite 7.71 6.33 -1.38 -0.144 0.23631E+04 15 albite-high 0.69 -0.77 -1.46 -0.112 0.24911E+04 16 albite -0.38 -0.77 -0.38 -0.029 0.65233E+03 19 spessartine 24.46 20.52 -3.93 -0.197 0.67183E+04 20 analcite 3.32 2.55 -0.78 -0.086 0.13259E+04 21 andalusite 5.00 1.69 -3.31 -0.331 0.56474E+04 22 andradite 39.01 34.59 -4.42 -0.230 0.75508E+04 26 annite 20.12 16.58 -3.54 -0.197 0.60509E+04 27 phlogopite 27.06 23.27 -3.80 -0.211 0.64842E+04 29 anorthite 12.71 9.03 -3.68 -0.283 0.62769E+04 35 aragonite 0.97 -3.66 -4.62 -1.542 0.78970E+04 36 brucite 12.57 8.58 -3.98 -0.797 0.68027E+04 37 calcite 0.81 -3.66 -4.47 -1.490 0.76328E+04 38 carnegieite-low 9.02 5.86 -3.17 -0.452 0.54071E+04 39 carnegieite-high 10.09 5.86 -4.24 -0.605 0.72340E+04 40 carpholite-Mg 8.58 6.97 -1.61 -0.108 0.27571E+04 41 carpholite-Fe 6.71 4.74 -1.97 -0.132 0.33713E+04 42 celadonite 5.34 2.79 -2.55 -0.150 0.43623E+04 43 celadonite-Fe 3.88 0.56 -3.32 -0.195 0.56669E+04 44 chrysotile 23.89 19.13 -4.76 -0.397 0.81299E+04 50 chloritoid-Mg 13.20 10.28 -2.92 -0.195 0.49843E+04 51 chloritoid-Fe 9.17 8.05 -1.12 -0.075 0.19195E+04 52 chloritoid-Mn 11.40 10.18 -1.22 -0.082 0.20887E+04 54 coesite -2.38 -3.31 -0.94 -0.312 0.15968E+04 59 corundum 8.38 5.01 -3.38 -0.307 0.57675E+04 61 cristobalite -2.56 -3.31 -0.75 -0.250 0.12822E+04 63 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71234E+04 65 diaspore 2.87 2.50 -0.37 -0.062 0.63352E+03 67 diopside 16.18 12.61 -3.57 -0.357 0.60922E+04 68 hedenbergite 14.21 10.38 -3.82 -0.382 0.65294E+04 75 epidote 24.67 22.66 -2.01 -0.098 0.34363E+04 76 clinozoisite 22.81 18.88 -3.93 -0.179 0.67087E+04 77 epidote-Fe 29.84 26.44 -3.40 -0.177 0.58105E+04 78 fayalite 14.05 9.40 -4.65 -0.664 0.79333E+04 83 gibbsite 4.08 2.50 -1.58 -0.225 0.26921E+04 87 greenalite 16.14 12.44 -3.70 -0.308 0.63106E+04 91 heulandite -5.83 -7.52 -1.69 -0.077 0.28938E+04 95 jadeite 4.22 2.55 -1.67 -0.167 0.28514E+04 97 kalsilite 7.58 4.14 -3.45 -0.493 0.58872E+04 98 kaolinite -1.33 -1.62 -0.28 -0.026 0.48560E+03 99 kyanite 4.88 1.69 -3.18 -0.318 0.54333E+04 101 laumontite 2.88 2.41 -0.47 -0.031 0.80543E+03 102 lawsonite 9.62 9.03 -0.58 -0.039 0.99351E+03 103 leucite 4.12 0.82 -3.29 -0.329 0.56246E+04 105 lizardite 23.24 19.13 -4.11 -0.343 0.70225E+04 107 magnetite 20.09 18.92 -1.17 -0.095 0.19906E+04 108 minnesotaite 10.39 5.82 -4.57 -0.269 0.77980E+04 113 margarite 17.32 14.04 -3.28 -0.131 0.56074E+04 120 muscovite 2.58 2.52 -0.06 -0.004 0.10857E+03 122 nepheline 8.34 5.86 -2.48 -0.355 0.42394E+04 134 phlogopite-Na 29.65 24.99 -4.66 -0.259 0.79554E+04 136 prehnite 19.37 16.37 -3.00 -0.176 0.51182E+04 137 prehnite-Fe 22.50 20.15 -2.34 -0.141 0.40008E+04 138 pumpellyite-Fe 46.27 41.61 -4.66 -0.104 0.79615E+04 145 pyroxmangite 7.40 5.17 -2.23 -0.445 0.38012E+04 146 pyrophyllite -6.18 -8.24 -2.06 -0.129 0.35240E+04 147 quartz -2.99 -3.31 -0.32 -0.107 0.54949E+03 151 rhodochrosite -0.98 -5.83 -4.85 -1.617 0.82809E+04 152 rhodonite 7.45 5.17 -2.27 -0.455 0.38815E+04 153 sanidine -1.28 -2.49 -1.21 -0.093 0.20677E+04 156 sillimanite 5.26 1.69 -3.57 -0.357 0.60913E+04 164 stilpnomelane-Fe 13.02 12.76 -0.25 -0.008 0.43113E+03 165 stilpnomelane-Mg 27.44 23.91 -3.53 -0.105 0.60295E+04 168 sudoite 21.08 17.25 -3.83 -0.124 0.65420E+04 171 talc 16.49 12.51 -3.98 -0.234 0.68001E+04 174 tephroite 18.09 13.66 -4.43 -0.633 0.75635E+04 177 topaz-H 4.62 1.69 -2.92 -0.266 0.49933E+04 178 tridymite -2.63 -3.31 -0.68 -0.228 0.11695E+04 187 wairakite 3.95 2.41 -1.54 -0.091 0.26274E+04 188 walstromite 11.51 7.34 -4.17 -0.834 0.71186E+04 189 wollastonite 10.46 7.34 -3.12 -0.624 0.53291E+04 190 pseudo-wollastonite 11.00 7.34 -3.66 -0.732 0.62489E+04 191 zoisite 22.85 18.88 -3.97 -0.181 0.67828E+04 192 akaganeite 7.75 6.28 -1.47 -0.318 0.25125E+04 193 beidellite-Ca -1.65 -4.56 -2.92 -0.181 0.49824E+04 194 beidellite-H -2.33 -6.32 -3.99 -0.255 0.68211E+04 195 beidellite-K -1.52 -4.69 -3.17 -0.194 0.54112E+04 196 beidellite-Mg -1.79 -4.90 -3.11 -0.193 0.53185E+04 197 beidellite-Na -1.34 -4.12 -2.78 -0.170 0.47456E+04 199 chalcedony -2.80 -3.31 -0.51 -0.170 0.86879E+03 201 montmorillonite-Ca -2.29 -4.48 -2.18 -0.135 0.37299E+04 202 montmorillonite-K -2.24 -4.60 -2.36 -0.145 0.40369E+04 203 montmorillonite-Mg -2.48 -4.82 -2.34 -0.145 0.39892E+04 204 montmorillonite-Na -2.04 -4.03 -2.00 -0.122 0.34070E+04 205 nontronite-Ca 3.21 3.00 -0.22 -0.014 0.37103E+03 206 nontronite-H 2.53 1.24 -1.29 -0.087 0.22076E+04 207 nontronite-K 3.34 2.87 -0.47 -0.030 0.80117E+03 208 nontronite-Mg 3.07 2.66 -0.42 -0.027 0.71442E+03 209 nontronite-Na 3.52 3.44 -0.08 -0.005 0.13732E+03 224 tobermorite 9.82 5.56 -4.26 -1.163 0.72767E+04 233 boehmite 4.41 2.50 -1.90 -0.317 0.32504E+04 235 ferrous-oxide 9.81 6.36 -3.46 -0.864 0.59014E+04 240 silica-amorphous -2.09 -3.31 -1.22 -0.407 0.20830E+04 242 an20ab80 2.02 1.19 -0.82 -0.063 0.14064E+04 243 an25ab75 2.65 1.68 -0.96 -0.074 0.16419E+04 244 an30ab70 3.28 2.17 -1.11 -0.085 0.18870E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 0.0400000 g Current total amount of reactant added: 1.9990000 g New total amount of reactant added: 2.0390000 g Mixing fraction reached given limit of 0.2000E+01 TOTMIX = 0.2039E+01 Execution stopped.