File SKIP_SPECIES.TXT lists species and minerals omitted from the calculations due to given T, P, option switches, or suppression in CHIMRUN, or are suppressed in the SOLTHERM database. It also lists minerals for which density is not specified in SOLTHERM. This is an extended P(to 5 kB), T(to 600 C) run (CON_FLAG = 1). methanol,aq is suppressed in SOLTHERM data file. methanol,aq is suppressed in SOLTHERM data file. CuCl4-3 is suppressed in SOLTHERM data file. H2BO3- is suppressed in SOLTHERM data file. UO2CO3,aq is suppressed in SOLTHERM data file. UO2SO4,aq is suppressed in SOLTHERM data file. UO2Cl2,aq is suppressed in SOLTHERM data file. UO2F2,aq is suppressed in SOLTHERM data file. PO4-3 is suppressed in SOLTHERM data file. H2PO4- is suppressed in SOLTHERM data file. H3PO4 is suppressed in SOLTHERM data file. O2,gas is suppressed in THIS RUN. O2,gas is suppressed in THIS RUN. amesite is suppressed in SOLTHERM data file. antigorite is suppressed in SOLTHERM data file. goethite is suppressed in THIS RUN. goethite is suppressed in THIS RUN. riebeckite is suppressed in THIS RUN. riebeckite is suppressed in THIS RUN. sapphirine-Fe(221) is suppressed in SOLTHERM data file. sapphirine(221) is suppressed in SOLTHERM data file. talc-prl is suppressed in SOLTHERM data file. PrO1.833(s) is suppressed in SOLTHERM data file. niter-NH4 is suppressed in SOLTHERM data file. FMQ_HS-1 is suppressed in THIS RUN. kf-ab-equil is suppressed in THIS RUN. ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Species No. Charge Tot.moles Trial molality Gamma Mixing solution H+ 1 1. -0.33087E-01 0.53704E-09 0.9213 0.00000000E+00 H2O 2 0. 0.55483E+02 0.10000E+01 1.0000 0.00000000E+00 Cl- 3 -1. 0.13797E-03 0.13793E-03 0.9203 0.00000000E+00 SO4-- 4 -2. 0.80904E-04 0.25500E-04 0.7585 0.00000000E+00 HCO3- 5 -1. 0.13070E-04 0.10758E-04 0.9205 0.00000000E+00 HS- 6 -1. -0.55399E-04 0.39372E-13 0.9203 0.00000000E+00 Al+++ 7 3. 0.65182E-02 0.70332E-25 0.5479 0.00000000E+00 H4SiO4 8 0. 0.20815E-01 0.48837E-03 1.0000 0.00000000E+00 Ca++ 9 2. 0.23136E-02 0.14478E-07 0.7576 0.00000000E+00 Mg++ 10 2. 0.15865E-02 0.12422E-09 0.7570 0.00000000E+00 Fe++ 11 2. 0.14253E-02 0.73275E-12 0.7572 0.00000000E+00 K+ 12 1. 0.42442E-03 0.47306E-04 0.9206 0.00000000E+00 Na+ 13 1. 0.26693E-02 0.24868E-02 0.9203 0.00000000E+00 Mn++ 14 2. 0.34660E-04 0.98451E-10 0.7573 0.00000000E+00 HPO4-- 15 -2. 0.11829E-04 0.84681E-05 0.7586 0.00000000E+00 Chg. balance for total moles = 0.8100E-13 Max. difference allowed = 0.1380E-07 The following parameters were given: ERPC = 0.1000E-11 pH = 0.0000 PFLUID = 50.0000 SLIM = 0.400000E+01 TEMP = 100.0000 SINC = 0.1000E+00 TEMPC = 0.0000 TOTMIX = 0.199900E+01 ENTH = 0.0000 SENTH = 0.0000 DENTH = 0.0000 TOTWAT = 90.0000 SOLMIN = 0.0000E+00 RM = 0.0000 AQGRM = 1000.0103 SUPRNT = 0.1000E-19 VBOX-1 = 1.7996 RHOFRS = 0.0000 RHOROC = 2.5000 The following options were selected: CONFLG = 1 C = 3 IFRAC = 0 IPUNCH = 2 NLOOP = 400 ISTEP = 2 LIMSOL = 1 LOOC = 0 IENTH = 0 ITREF = 0 IDEAL = 0 IPSAT = 1 INCREM = 0 INCP = 0 MINSOL = 1 NEUT = 0 AWAT = 0 CHGF = 0 Of the derived species, only those with molality > 0.10E-19 will appear in the output Species No. Charge Log K(diss) Species No. Charge Log K(diss) HSiO3- 16 -1. 9.0298 MnO2-2 65 -2. 40.4638 Ca(HSiO3)+ 17 1. 7.6723 HMnO2- 66 -1. 29.1232 Mg(HSiO3)+ 18 1. 7.5773 MnO4- 67 -1. 83.3111 NaHSiO3,aq 19 0. 7.8210 MnO4-2 68 -2. 81.3005 AlO+ 20 1. 6.8663 MnCl+ 69 1. -0.7894 AlOH+2 21 2. 3.1691 MnSO4,aq 70 0. -2.4604 HAlO2,aq 22 0. 10.5671 NaCl,aq 71 0. 0.4796 AlO2- 23 -1. 16.2221 NaOH,aq 72 0. 12.3669 CH4,aq 24 0. 6.0126 O2,aq 73 0. 53.5502 C2H6,aq 25 0. 12.3733 OH- 74 -1. 12.2382 C3H8,aq 26 0. 17.3707 HO2- 75 -1. 50.8010 C4H10,aq 27 0. 22.3757 H2O2,aq 76 0. 40.0166 ethanol,aq 28 0. 15.3258 H3PO2,aq 77 0. 24.3066 CO,aq 29 0. 4.6892 H2PO2- 78 -1. 26.5366 CO2,aq 30 0. -6.3298 HPO3-2 79 -2. 11.9254 CO3-2 31 -2. 10.0588 H3PO3,aq 80 0. 3.5792 CaCO3,aq 32 0. 5.9605 H2PO3- 81 -1. 5.6232 Ca(HCO3)+ 33 1. -1.4070 H3PO4,aq 82 0. -9.8447 CaCl+ 34 1. -0.2091 H2PO4- 83 -1. -7.2659 CaCl2,aq 35 0. 0.4151 PO4-3 84 -3. 12.0884 CaOH+ 36 1. 10.1471 H4P2O7,aq 85 0. -17.8095 CaSO4,aq 37 0. -2.5018 H3P2O7- 86 -1. -15.9156 HCl,aq 38 0. 0.7370 H2P2O7-2 87 -2. -13.4262 HClO,aq 39 0. 32.4260 HP2O7-3 88 -3. -6.7266 ClO- 40 -1. 39.6530 P2O7-4 89 -4. 2.8952 HClO2,aq 41 0. 70.1812 H2S,aq 90 0. -6.4900 Fe+3 42 3. 8.3809 S2-2 91 -2. 1.2355 FeCl+ 43 1. -0.1994 S3-2 92 -2. -8.8031 FeCl2,aq 44 0. 4.3001 S3- 93 -1. -16.3389 FeCl+2 45 2. 6.5269 S4-2 94 -2. -18.6615 FeO,aq 46 0. 16.4104 S5-2 95 -2. -28.3439 FeOH+ 47 1. 7.4874 SO2,aq 96 0. -0.2309 HFeO2- 48 -1. 24.3908 SO3-2 97 -2. 10.3052 FeO+ 49 1. 11.4004 HSO3- 98 -1. 2.5086 FeOH+2 50 2. 9.1194 HSO4- 99 -1. -2.9839 FeO2- 51 -1. 24.0895 HSO5- 100 -1. 38.8366 HFeO2,aq 52 0. 15.9850 S2O3-2 101 -2. -4.5600 H2,aq 53 0. 9.4190 HS2O3- 102 -1. -6.8123 KCl,aq 54 0. 1.7417 H2S2O3,aq 103 0. -8.0173 KHSO4,aq 55 0. -0.4514 S2O4-2 104 -2. 10.5541 KOH,aq 56 0. 12.3695 HS2O4- 105 -1. 7.6551 KSO4- 57 -1. -1.1908 H2S2O4,aq 106 0. 6.6259 MgCO3,aq 58 0. 6.5614 S2O5-2 107 -2. 10.0741 Mg(HCO3)+ 59 1. -1.4164 S2O6-2 108 -2. 11.5521 MgCl+ 60 1. -0.1664 S2O8-2 109 -2. 42.0620 MgOH+ 61 1. 9.4041 S3O6-2 110 -2. 3.7866 Mn+3 62 3. 19.1453 S4O6-2 111 -2. -17.8657 MnO,aq 63 0. 17.9848 S5O6-2 112 -2. -14.1333 MnOH+ 64 1. 8.5194 113 0. 10.3111 For mixed gases (JSOLS=6), log K(hydrol) = log (K*P) Log K Trial Log K Trial Mineral No. hydrol Moles Mineral No. hydrol Moles H2O,gas 1 1.696 0.0000E+00 osumilite(2) 124 20.667 0.0000E+00 CO2,gas 2 -6.660 0.0000E+00 osumilite-Fe 125 14.390 0.0000E+00 CH4,gas 3 4.544 0.0000E+00 pargasite 126 65.092 0.0000E+00 H2,gas 4 8.000 0.0000E+00 periclase 127 16.138 0.0000E+00 H2S,gas 5 -6.230 0.0000E+00 periclase-Fe 128 11.627 0.0000E+00 S2,gas 6 -7.335 0.0000E+00 perovskite-Al 129 12.344 0.0000E+00 CO,gas 7 3.215 0.0000E+00 perovskite-Ca 130 23.807 0.0000E+00 SO3,gas 8 17.121 0.0000E+00 perovskite-Fe 131 21.143 0.0000E+00 SO2,gas 9 0.832 0.0000E+00 perovskite-Mg 132 23.119 0.0000E+00 HCl,gas 10 5.189 0.0000E+00 phase_A 133 80.189 0.0000E+00 acmite 11 7.710 0.0000E+00 phlogopite-Na 134 29.647 0.0000E+00 akermanite 12 36.442 0.0000E+00 piemontite(ordered) 135 33.776 0.0000E+00 akimotoite 13 16.591 0.0000E+00 prehnite 136 19.372 0.0000E+00 akimotoite-Fe 14 13.067 0.0000E+00 prehnite-Fe 137 22.498 0.0000E+00 albite-high 15 0.693 0.0000E+00 pumpellyite-Fe 138 46.269 0.0000E+00 albite 16 -0.384 0.0000E+00 pumpellyite-Mg 139 48.995 0.0000E+00 almandine 17 24.442 0.0000E+00 px-Mg-tschermaks 140 19.616 0.0000E+00 pyrope 18 37.248 0.0000E+00 px-Ca-tschermaks 141 18.610 0.0000E+00 spessartine 19 24.457 0.0000E+00 pyrite 142 -21.247 0.0000E+00 analcite 20 3.322 0.0000E+00 pyrrhotite 143 -4.260 0.0000E+00 andalusite 21 5.002 0.0000E+00 pyrrhotiteFe0.875 144 -6.017 0.0000E+00 andradite 22 39.009 0.0000E+00 pyroxmangite 145 7.399 0.0000E+00 grossular 23 32.731 0.0000E+00 pyrophyllite 146 -6.176 0.0000E+00 anhydrite 24 -5.317 0.0000E+00 quartz 147 -2.989 0.0000E+00 ankerite 25 -2.135 0.0000E+00 rankinite 148 40.713 0.0000E+00 annite 26 20.123 0.0000E+00 ringwoodite-Fe 149 15.456 0.0000E+00 phlogopite 27 27.065 0.0000E+00 ringwoodite-Mg 150 27.575 0.0000E+00 biotite-Mn 28 32.960 0.0000E+00 rhodochrosite 151 -0.976 0.0000E+00 anorthite 29 12.710 0.0000E+00 rhodonite 152 7.446 0.0000E+00 anthophyllite 30 51.852 0.0000E+00 sanidine 153 -1.275 0.0000E+00 anthophyllite-Fe 31 29.306 0.0000E+00 sapphirine(351) 154 78.899 0.0000E+00 apatite-OH 32 -18.153 0.1094E-05 siderite 155 -2.608 0.0000E+00 apatite-OH-zs 33 -12.736 0.0000E+00 sillimanite 156 5.262 0.0000E+00 apatite-Cl-zs 34 -16.674 0.0000E+00 sodalite 157 49.976 0.0000E+00 aragonite 35 0.967 0.0000E+00 spinel 158 20.870 0.0000E+00 brucite 36 12.569 0.0000E+00 spurrite 159 59.482 0.0000E+00 calcite 37 0.812 0.0000E+00 staurolite-Fe 160 73.598 0.0000E+00 carnegieite-low 38 9.023 0.0000E+00 staurolite-Mg 161 89.802 0.0000E+00 carnegieite-high 39 10.093 0.0000E+00 staurolite-Mn 162 83.909 0.0000E+00 carpholite-Mg 40 8.582 0.0000E+00 stilbite 163 -7.522 0.2308E-02 carpholite-Fe 41 6.713 0.0000E+00 stilpnomelane-Fe 164 13.017 0.0000E+00 celadonite 42 5.342 0.0000E+00 stilpnomelane-Mg 165 27.441 0.0000E+00 celadonite-Fe 43 3.877 0.0000E+00 stishovite 166 2.720 0.0000E+00 chrysotile 44 23.892 0.0000E+00 sudoite-Fe 167 18.296 0.0000E+00 chondrodite 45 56.475 0.0000E+00 sudoite 168 21.077 0.0000E+00 clinochlore 46 39.070 0.3173E-03 sulfur 169 -9.152 0.0000E+00 daphnite 47 28.965 0.1964E-03 sylvite 170 1.338 0.0000E+00 chlorite-Mn 48 46.869 0.6932E-05 talc 171 16.491 0.0000E+00 chlorite-Al-free 49 47.173 0.0000E+00 talc-Fe 172 13.448 0.0000E+00 chloritoid-Mg 50 13.198 0.0000E+00 talc-tschermaks 173 19.091 0.0000E+00 chloritoid-Fe 51 9.174 0.0000E+00 tephroite 174 18.086 0.0000E+00 chloritoid-Mn 52 11.401 0.0000E+00 tilleyite 175 41.377 0.0000E+00 clinohumite 53 97.128 0.0000E+00 titanite-CaSi 176 15.479 0.0000E+00 coesite 54 -2.376 0.0000E+00 topaz-H 177 4.618 0.0000E+00 cordierite-H 55 23.715 0.0000E+00 tridymite 178 -2.626 0.0000E+00 cordierite 56 24.049 0.0000E+00 tremolite 179 47.869 0.0000E+00 cordierite-Fe 57 20.450 0.0000E+00 ferroactinolite 180 38.452 0.0000E+00 cordierite-Mn 58 25.066 0.0000E+00 troilite-low 181 -4.411 0.0000E+00 corundum 59 8.383 0.0000E+00 tschermakite 182 48.210 0.0000E+00 corundum-MgSi 60 18.891 0.0000E+00 vesuvianite 183 223.471 0.0000E+00 cristobalite 61 -2.560 0.0000E+00 wadeite-Si 184 20.216 0.0000E+00 cummingtonite 62 52.099 0.0000E+00 wadsleyite-Fe 185 15.680 0.0000E+00 cymrite-K 63 1.685 0.0000E+00 wadsleyite-Mg 186 25.850 0.0000E+00 deerite 64 95.671 0.0000E+00 wairakite 187 3.950 0.0000E+00 diaspore 65 2.874 0.0000E+00 walstromite 188 11.509 0.0000E+00 diamond 66 -3.102 0.0000E+00 wollastonite 189 10.461 0.0000E+00 diopside 67 16.181 0.0000E+00 pseudo-wollastonite 190 11.000 0.0000E+00 hedenbergite 68 14.208 0.0000E+00 zoisite 191 22.849 0.0000E+00 dolomite,ordered 69 0.546 0.0000E+00 akaganeite 192 7.755 0.0000E+00 eastonite 70 28.489 0.0000E+00 beidellite-Ca 193 -1.646 0.0000E+00 enstatite 71 17.265 0.0000E+00 beidellite-H 194 -2.326 0.0000E+00 clinoenstatite-HiP 72 18.354 0.0000E+00 beidellite-K 195 -1.520 0.0000E+00 clinoenstatite 73 17.166 0.0000E+00 beidellite-Mg 196 -1.790 0.0000E+00 protoenstatite 74 17.824 0.0000E+00 beidellite-Na 197 -1.342 0.0000E+00 epidote 75 24.670 0.0000E+00 calcium 198 84.026 0.0000E+00 clinozoisite 76 22.806 0.0000E+00 chalcedony 199 -2.802 0.0000E+00 epidote-Fe 77 29.841 0.0000E+00 dawsonite 200 1.682 0.0000E+00 fayalite 78 14.046 0.0000E+00 montmorillonite-Ca 201 -2.291 0.0000E+00 ferrosilite 79 11.149 0.0000E+00 montmorillonite-K 202 -2.237 0.0000E+00 forsterite 80 21.016 0.0000E+00 montmorillonite-Mg 203 -2.480 0.0000E+00 gedrite 81 50.522 0.0000E+00 montmorillonite-Na 204 -2.038 0.0000E+00 gehlenite 82 36.628 0.0000E+00 nontronite-Ca 205 3.215 0.0000E+00 gibbsite 83 4.079 0.0000E+00 nontronite-H 206 2.533 0.0000E+00 glaucophane 84 22.975 0.0000E+00 nontronite-K 207 3.341 0.0000E+00 glaucophane-Fe 85 17.276 0.0000E+00 nontronite-Mg 208 3.075 0.0000E+00 graphite 86 -3.546 0.0000E+00 nontronite-Na 209 3.520 0.0000E+00 greenalite 87 16.140 0.0000E+00 sepiolite 210 24.118 0.0000E+00 grunerite 88 31.215 0.0000E+00 alite 211 57.999 0.0000E+00 halite 89 1.575 0.0000E+00 belite 212 30.433 0.0000E+00 hematite 90 12.566 0.2216E-03 ettringite 213 43.232 0.0000E+00 heulandite 91 -5.827 0.0000E+00 gypsum 214 -4.955 0.0000E+00 hercynite 92 17.279 0.0000E+00 hemicarboaluminate 215 70.954 0.0000E+00 hollandite 93 25.673 0.0000E+00 hydrogarnet 216 60.662 0.0000E+00 iron 94 19.086 0.0000E+00 hydrogarnet-Si 217 50.586 0.0000E+00 jadeite 95 4.215 0.0000E+00 jennite 218 24.367 0.0000E+00 julgoldite 96 70.427 0.0000E+00 monosulfoaluminate 219 53.400 0.0000E+00 kalsilite 97 7.584 0.0000E+00 monocarboaluminate 220 61.898 0.0000E+00 kaolinite 98 -1.333 0.0000E+00 portlandite 221 18.272 0.0000E+00 kyanite 99 4.876 0.0000E+00 stratlingite 222 36.502 0.0000E+00 larnite-bredigite 100 30.686 0.0000E+00 tricarboaluminate 223 70.370 0.0000E+00 laumontite 101 2.883 0.0000E+00 tobermorite 224 9.823 0.0000E+00 lawsonite 102 9.616 0.0000E+00 C4AH13 225 81.816 0.0000E+00 leucite 103 4.119 0.0000E+00 C2AH8 226 45.203 0.0000E+00 lime 104 25.998 0.0000E+00 C3A 227 86.953 0.0000E+00 lizardite 105 23.244 0.0000E+00 C4AF 228 117.416 0.0000E+00 magnesite 106 0.691 0.0000E+00 CAH10 229 28.335 0.0000E+00 magnetite 107 20.087 0.0000E+00 alabandite 230 -0.978 0.0000E+00 minnesotaite 108 10.388 0.0000E+00 alunite 231 -10.435 0.0000E+00 minnesotaite-Mg 109 20.602 0.0000E+00 artinite 232 15.121 0.0000E+00 magnesioferrite 110 26.212 0.0000E+00 boehmite 233 4.406 0.0000E+00 majorite 111 53.251 0.0000E+00 dolomite,disordered 234 1.247 0.0000E+00 manganosite 112 14.058 0.0000E+00 ferrous-oxide 235 9.812 0.0000E+00 margarite 113 17.324 0.0000E+00 huntite 236 3.770 0.0000E+00 meionite 114 44.874 0.0000E+00 hydromagnesite 237 19.995 0.0000E+00 merwinite 115 55.930 0.0000E+00 nesquehonite 238 4.723 0.0000E+00 microcline 116 -2.486 0.3771E-03 potassium-oxide 239 69.038 0.0000E+00 monticellite 117 24.339 0.0000E+00 silica-amorphous 240 -2.091 0.0000E+00 mullite-Al 118 363.148 0.0000E+00 sodium-oxide 241 55.169 0.0000E+00 mullite-Si 119 7.264 0.0000E+00 an20ab80 242 2.018 0.0000E+00 muscovite 120 2.582 0.0000E+00 an25ab75 243 2.646 0.0000E+00 paragonite 121 4.239 0.1472E-03 an30ab70 244 3.279 0.0000E+00 nepheline 122 8.339 0.0000E+00 tr.625ac.25prg.125 245 45.165 0.0000E+00 osumilite(1) 123 21.717 0.0000E+00 246 0.000 0.0000E+00 Initial composition of reactant (wt%): SiO2 62.56 MgO 3.200 Al2O3 16.62 CaO 6.450 FeO 3.530 Na2O 3.890 Fe2O3 1.770 K2O 1.000 MnO 0.1230 P2O5 0.4200E-01 Sum of wt% of reactants: 99.1850 Reactant consumed: 1.9990000 g log = 0.3008 Original solution: 1000.0103000 g Original solution / Rock added: 500.26 (Water/Rock Ratio), log = 2.6992 The following minerals and/or gases with identical index are in solid solution: H2O,gas 6 CO2,gas 6 CH4,gas 6 H2,gas 6 H2S,gas 6 S2,gas 6 CO,gas 6 SO3,gas 6 SO2,gas 6 HCl,gas 6 almandine 16 pyrope 16 spessartine 16 andradite 8 grossular 8 annite 15 phlogopite 15 biotite-Mn 15 clinochlore 1 daphnite 1 chlorite-Mn 1 diopside 5 hedenbergite 5 epidote 3 clinozoisite 3 greenalite 18 iron 9 lizardite 18 magnetite 14 talc 7 talc-Fe 7 tremolite 2 ferroactinolite 2 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 8 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 1.9990000 Water: Moles liquid = 0.5549E+02 kg liquid = 0.9996E+00 Moles total = 0.5548E+02 kg total = 0.9995E+00 Activity = 1.0000 Stoichiometric ionic strength = .1617587E-02 Osmotic coef. = 0.9771 True ionic strength = .2570493E-02 Chg. balance for total moles = 0.8100E-13 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.53704E-09 -9.2700 0.49475E-09 -9.3056 0.92125E+00 -0.0356 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13793E-03 -3.8603 0.12694E-03 -3.8964 0.92030E+00 -0.0361 4 SO4-- 0.25500E-04 -4.5935 0.19342E-04 -4.7135 0.75854E+00 -0.1200 5 HCO3- 0.10758E-04 -4.9683 0.99034E-05 -5.0042 0.92053E+00 -0.0360 6 HS- 0.39372E-13 -13.4048 0.36236E-13 -13.4409 0.92033E+00 -0.0361 7 Al+++ 0.70332E-25 -25.1528 0.38532E-25 -25.4142 0.54786E+00 -0.2613 8 H4SiO4 0.48837E-03 -3.3113 0.48837E-03 -3.3113 0.10000E+01 0.0000 9 Ca++ 0.14478E-07 -7.8393 0.10968E-07 -7.9599 0.75760E+00 -0.1206 10 Mg++ 0.12422E-09 -9.9058 0.94033E-10 -10.0267 0.75701E+00 -0.1209 11 Fe++ 0.73275E-12 -12.1350 0.55480E-12 -12.2559 0.75715E+00 -0.1208 12 K+ 0.47306E-04 -4.3251 0.43549E-04 -4.3610 0.92057E+00 -0.0359 13 Na+ 0.24868E-02 -2.6044 0.22886E-02 -2.6404 0.92028E+00 -0.0361 14 Mn++ 0.98451E-10 -10.0068 0.74553E-10 -10.1275 0.75726E+00 -0.1208 15 HPO4-- 0.84681E-05 -5.0722 0.64235E-05 -5.1922 0.75856E+00 -0.1200 16 HSiO3- 0.10015E-02 -2.9993 0.92170E-03 -3.0354 0.92030E+00 -0.0361 17 Ca(HSiO3)+ 0.25009E-09 -9.6019 0.23023E-09 -9.6378 0.92061E+00 -0.0359 18 Mg(HSiO3)+ 0.26683E-11 -11.5738 0.24564E-11 -11.6097 0.92061E+00 -0.0359 19 NaHSiO3,aq 0.34116E-04 -4.4670 0.34116E-04 -4.4670 0.10000E+01 0.0000 20 AlO+ 0.23262E-13 -13.6333 0.21416E-13 -13.6693 0.92061E+00 -0.0359 21 AlOH+2 0.69659E-19 -19.1570 0.52758E-19 -19.2777 0.75739E+00 -0.1207 22 HAlO2,aq 0.86203E-08 -8.0645 0.86203E-08 -8.0645 0.10000E+01 0.0000 23 AlO2- 0.41921E-04 -4.3776 0.38568E-04 -4.4138 0.92002E+00 -0.0362 24 CH4,aq 0.18031E-19 -19.7440 0.18022E-19 -19.7442 0.99950E+00 -0.0002 29 CO,aq 0.13980E-18 -18.8545 0.13980E-18 -18.8545 0.10000E+01 0.0000 30 CO2,aq 0.10475E-07 -7.9799 0.10469E-07 -7.9801 0.99950E+00 -0.0002 31 CO3-2 0.23058E-05 -5.6372 0.17484E-05 -5.7574 0.75826E+00 -0.1202 32 CaCO3,aq 0.24046E-09 -9.6190 0.24046E-09 -9.6190 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.30119E-11 -11.5212 0.27728E-11 -11.5571 0.92061E+00 -0.0359 34 CaCl+ 0.24475E-11 -11.6113 0.22532E-11 -11.6472 0.92061E+00 -0.0359 35 CaCl2,aq 0.67950E-16 -16.1678 0.67950E-16 -16.1678 0.10000E+01 0.0000 36 CaOH+ 0.17163E-08 -8.7654 0.15800E-08 -8.8013 0.92061E+00 -0.0359 37 CaSO4,aq 0.67370E-10 -10.1715 0.67370E-10 -10.1715 0.10000E+01 0.0000 38 HCl,aq 0.11508E-13 -13.9390 0.11508E-13 -13.9390 0.10000E+01 0.0000 43 FeCl+ 0.12108E-15 -15.9169 0.11147E-15 -15.9528 0.92061E+00 -0.0359 46 FeO,aq 0.88092E-10 -10.0551 0.88092E-10 -10.0551 0.10000E+01 0.0000 47 FeOH+ 0.39650E-10 -10.4018 0.36502E-10 -10.4377 0.92061E+00 -0.0359 48 HFeO2- 0.20243E-08 -8.6937 0.18630E-08 -8.7298 0.92030E+00 -0.0361 49 FeO+ 0.41020E-14 -14.3870 0.37764E-14 -14.4229 0.92061E+00 -0.0359 51 FeO2- 0.34302E-08 -8.4647 0.31568E-08 -8.5007 0.92030E+00 -0.0361 52 HFeO2,aq 0.19864E-09 -9.7019 0.19864E-09 -9.7019 0.10000E+01 0.0000 53 H2,aq 0.53182E-09 -9.2742 0.53155E-09 -9.2745 0.99950E+00 -0.0002 54 KCl,aq 0.10019E-09 -9.9992 0.10019E-09 -9.9992 0.10000E+01 0.0000 55 KHSO4,aq 0.11783E-17 -17.9287 0.11783E-17 -17.9287 0.10000E+01 0.0000 56 KOH,aq 0.37591E-07 -7.4249 0.37591E-07 -7.4249 0.10000E+01 0.0000 57 KSO4- 0.14203E-07 -7.8476 0.13071E-07 -7.8837 0.92030E+00 -0.0361 58 MgCO3,aq 0.51672E-12 -12.2867 0.51672E-12 -12.2867 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.26384E-13 -13.5787 0.24289E-13 -13.6146 0.92061E+00 -0.0359 60 MgCl+ 0.19017E-13 -13.7209 0.17507E-13 -13.7568 0.92061E+00 -0.0359 61 MgOH+ 0.81418E-10 -10.0893 0.74954E-10 -10.1252 0.92061E+00 -0.0359 63 MnO,aq 0.31542E-09 -9.5011 0.31542E-09 -9.5011 0.10000E+01 0.0000 64 MnOH+ 0.49496E-09 -9.3054 0.45566E-09 -9.3414 0.92061E+00 -0.0359 65 MnO2-2 0.56399E-13 -13.2487 0.42765E-13 -13.3689 0.75826E+00 -0.1202 66 HMnO2- 0.50368E-11 -11.2978 0.46354E-11 -11.3339 0.92030E+00 -0.0361 69 MnCl+ 0.63301E-13 -13.1986 0.58275E-13 -13.2345 0.92061E+00 -0.0359 70 MnSO4,aq 0.41630E-12 -12.3806 0.41630E-12 -12.3806 0.10000E+01 0.0000 71 NaCl,aq 0.96273E-07 -7.0165 0.96273E-07 -7.0165 0.10000E+01 0.0000 72 NaOH,aq 0.19874E-05 -5.7017 0.19874E-05 -5.7017 0.10000E+01 0.0000 74 OH- 0.12693E-02 -2.8964 0.11678E-02 -2.9326 0.92002E+00 -0.0362 79 HPO3-2 0.14033E-16 -16.8529 0.10640E-16 -16.9730 0.75826E+00 -0.1202 81 H2PO3- 0.11471E-19 -19.9404 0.10557E-19 -19.9765 0.92030E+00 -0.0361 82 H3PO4,aq 0.10997E-13 -13.9587 0.10997E-13 -13.9587 0.10000E+01 0.0000 83 H2PO4- 0.63693E-07 -7.1959 0.58626E-07 -7.2319 0.92045E+00 -0.0360 84 PO4-3 0.19174E-07 -7.7173 0.10593E-07 -7.9750 0.55248E+00 -0.2577 87 H2P2O7-2 0.35542E-15 -15.4493 0.26950E-15 -15.5694 0.75826E+00 -0.1202 88 HP2O7-3 0.19851E-12 -12.7022 0.10877E-12 -12.9635 0.54792E+00 -0.2613 89 P2O7-4 0.15027E-12 -12.8231 0.52520E-13 -13.2797 0.34951E+00 -0.4565 90 H2S,aq 0.55435E-16 -16.2562 0.55407E-16 -16.2564 0.99950E+00 -0.0002 97 SO3-2 0.17577E-14 -14.7551 0.13361E-14 -14.8742 0.76014E+00 -0.1191 98 HSO3- 0.44972E-16 -16.3471 0.41388E-16 -16.3831 0.92030E+00 -0.0361 99 HSO4- 0.10016E-10 -10.9993 0.92224E-11 -11.0352 0.92075E+00 -0.0359 Charge balance for all species = 0.8107E-13 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.5370393E-09 -.2476974E-02 -.2496098E+01 0.0000 2 H2O 0.1000000E+01 0.5550857E+02 0.9997861E+06 0.0000 3 Cl- 0.1379288E-03 0.1380252E-03 0.4892343E+01 5.4092 4 SO4-- 0.2549962E-04 0.2551422E-04 0.2450404E+01 13.8977 5 HCO3- 0.1075831E-04 0.1307483E-04 0.7976162E+00 4.3014 6 HS- 0.3937250E-13 -.3206150E-09 -.1060107E-04 -4.1352 7 Al+++ 0.7033186E-25 0.4193003E-04 0.1131089E+01 2.5027 8 H4SiO4 0.4883684E-03 0.1524000E-02 0.1464481E+03 -3.3113 9 Ca++ 0.1447786E-07 0.1675753E-07 0.6714623E-03 10.6514 10 Mg++ 0.1242154E-09 0.2088643E-09 0.5076804E-05 8.5845 11 Fe++ 0.7327512E-12 0.5781670E-08 0.3228187E-03 6.3554 12 K+ 0.4730637E-04 0.4735826E-04 0.1851400E+01 4.9446 13 Na+ 0.2486808E-02 0.2523008E-02 0.5799084E+02 6.6652 14 Mn++ 0.9845076E-10 0.9144017E-09 0.5022448E-04 8.4837 15 HPO4-- 0.8468114E-05 0.8550981E-05 0.8205362E+00 13.4190 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.3308743E-01 -.2476058E-02 -.3061137E-01 0.0000000E+00 2 H2O 0.5548319E+02 0.5548806E+02 -.4864449E-02 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.8090357E-04 0.2550479E-04 0.5539878E-04 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.5539910E-04 -.3204965E-09 -.5539878E-04 0.0000000E+00 7 Al+++ 0.6518222E-02 0.4191453E-04 0.6476308E-02 0.0000000E+00 8 H4SiO4 0.2081515E-01 0.1523437E-02 0.1929172E-01 0.0000000E+00 9 Ca++ 0.2313606E-02 0.1675134E-07 0.2313589E-02 0.0000000E+00 10 Mg++ 0.1586508E-02 0.2087871E-09 0.1586508E-02 0.0000000E+00 11 Fe++ 0.1425304E-02 0.5779533E-08 0.1425298E-02 0.0000000E+00 12 K+ 0.4244161E-03 0.4734076E-04 0.3770754E-03 0.0000000E+00 13 Na+ 0.2669303E-02 0.2522076E-02 0.1472273E-03 0.0000000E+00 14 Mn++ 0.3465985E-04 0.9140638E-09 0.3465894E-04 0.0000000E+00 15 HPO4-- 0.1182924E-04 0.8547821E-05 0.3281414E-05 0.0000000E+00 Chg. balance for solid moles: -.1354E-17 Mass of aqueous solution: 0.999848E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 1.9990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) apatite-OH 0.1094E-05 -5.961 0.5494E-03 -3.260 0.2561E-01 0.1746E-03 clinochlore 0.3173E-03 -3.499 0.1764 -0.754 8.222 0.6708E-01 daphnite 0.1964E-03 -3.707 0.1401 -0.853 6.533 0.4247E-01 chlorite-Mn 0.6932E-05 -5.159 0.4914E-02 -2.309 0.2291 0.1566E-02 hematite 0.2216E-03 -3.654 0.3539E-01 -1.451 1.650 0.6707E-02 microcline 0.3771E-03 -3.424 0.1050 -0.979 4.893 0.4100E-01 paragonite 0.1472E-03 -3.832 0.5627E-01 -1.250 2.623 0.1945E-01 stilbite 0.2308E-02 -2.637 1.627 0.211 75.83 0.7587 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.6094E+00 0.6094E+00 1.0000 -0.215 daphnite 0.3773E+00 0.3773E+00 1.0000 -0.423 chlorite-Mn 0.1331E-01 0.1331E-01 1.0000 -1.876 hematite 0.1000E+01 0.1000E+01 1.0000 0.000 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 paragonite 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 2.145171 g Volume = 0.937116 cm3 Porosity: 47.9264% V(tot) - V(min): 0.86248E+00 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 1.9990000 g log = 0.3008 Original solution: 1000.0103000 g Original solution / Rock added: 500.26 (Water/Rock Ratio), log = 2.6992 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0203 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.1000E+01 0.9860 0.1006E+01 0.1020E+01 CO2,gas 0.1090E-05 1.0071 0.1120E-05 0.1112E-05 CH4,gas 0.2568E-16 1.0125 0.2653E-16 0.2620E-16 H2,gas 0.6836E-06 1.0005 0.6979E-06 0.6975E-06 H2S,gas 0.1499E-14 0.9960 0.1523E-14 0.1529E-14 S2,gas 0.1752E-36 1.0000 0.1788E-36 0.1788E-36 CO,gas 0.2042E-15 1.0000 0.2083E-15 0.2083E-15 SO3,gas 0.1755E-38 1.0000 0.1790E-38 0.1790E-38 SO2,gas 0.4764E-22 1.0000 0.4860E-22 0.4860E-22 HCl,gas 0.1990E-16 1.0000 0.2031E-16 0.2031E-16 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 32 apatite-OH -18.15 -18.15 0.00 0.000 -0.12132E-10 46 clinochlore 39.07 39.07 0.00 0.000 0.00000E+00 47 daphnite 28.97 28.97 0.00 0.000 -0.12132E-10 48 chlorite-Mn 46.87 46.87 0.00 0.000 0.00000E+00 90 hematite 12.57 12.57 0.00 0.000 0.30331E-11 116 microcline -2.49 -2.49 0.00 0.000 0.15165E-11 121 paragonite 4.24 4.24 0.00 0.000 -0.10616E-10 163 stilbite -7.52 -7.52 0.00 0.000 -0.90992E-11 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -14.31 -7.65 -2.550 0.13062E+05 -5.951 3 CH4,gas 4.54 -13.73 -18.28 -4.569 0.31205E+05 -16.576 4 H2,gas 8.00 0.14 -7.86 -4.489 0.13413E+05 -6.156 5 H2S,gas -6.23 -22.75 -16.52 -8.258 0.28201E+05 -14.817 6 S2,gas -7.34 -45.78 -38.45 -5.915 0.65647E+05 -36.748 7 CO,gas 3.21 -14.17 -17.38 -5.348 0.29676E+05 -15.681 8 SO3,gas 17.12 -23.32 -40.45 -10.112 0.69061E+05 -38.747 9 SO2,gas 0.83 -23.18 -24.01 -6.403 0.41000E+05 -22.313 10 HCl,gas 5.19 -13.20 -18.39 -9.196 0.31403E+05 -16.692 11 acmite 7.71 6.33 -1.38 -0.144 0.23631E+04 15 albite-high 0.69 -0.77 -1.46 -0.112 0.24911E+04 16 albite -0.38 -0.77 -0.38 -0.029 0.65233E+03 19 spessartine 24.46 20.52 -3.93 -0.197 0.67183E+04 20 analcite 3.32 2.55 -0.78 -0.086 0.13259E+04 21 andalusite 5.00 1.69 -3.31 -0.331 0.56474E+04 22 andradite 39.01 34.59 -4.42 -0.230 0.75508E+04 26 annite 20.12 16.58 -3.54 -0.197 0.60509E+04 27 phlogopite 27.06 23.27 -3.80 -0.211 0.64842E+04 29 anorthite 12.71 9.03 -3.68 -0.283 0.62769E+04 35 aragonite 0.97 -3.66 -4.62 -1.542 0.78970E+04 36 brucite 12.57 8.58 -3.98 -0.797 0.68027E+04 37 calcite 0.81 -3.66 -4.47 -1.490 0.76328E+04 38 carnegieite-low 9.02 5.86 -3.17 -0.452 0.54071E+04 39 carnegieite-high 10.09 5.86 -4.24 -0.605 0.72340E+04 40 carpholite-Mg 8.58 6.97 -1.61 -0.108 0.27571E+04 41 carpholite-Fe 6.71 4.74 -1.97 -0.132 0.33713E+04 42 celadonite 5.34 2.79 -2.55 -0.150 0.43623E+04 43 celadonite-Fe 3.88 0.56 -3.32 -0.195 0.56669E+04 44 chrysotile 23.89 19.13 -4.76 -0.397 0.81299E+04 50 chloritoid-Mg 13.20 10.28 -2.92 -0.195 0.49843E+04 51 chloritoid-Fe 9.17 8.05 -1.12 -0.075 0.19195E+04 52 chloritoid-Mn 11.40 10.18 -1.22 -0.082 0.20887E+04 54 coesite -2.38 -3.31 -0.94 -0.312 0.15968E+04 59 corundum 8.38 5.01 -3.38 -0.307 0.57675E+04 61 cristobalite -2.56 -3.31 -0.75 -0.250 0.12822E+04 63 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71234E+04 65 diaspore 2.87 2.50 -0.37 -0.062 0.63352E+03 67 diopside 16.18 12.61 -3.57 -0.357 0.60922E+04 68 hedenbergite 14.21 10.38 -3.82 -0.382 0.65294E+04 75 epidote 24.67 22.66 -2.01 -0.098 0.34363E+04 76 clinozoisite 22.81 18.88 -3.93 -0.179 0.67087E+04 77 epidote-Fe 29.84 26.44 -3.40 -0.177 0.58105E+04 78 fayalite 14.05 9.40 -4.65 -0.664 0.79333E+04 83 gibbsite 4.08 2.50 -1.58 -0.225 0.26921E+04 87 greenalite 16.14 12.44 -3.70 -0.308 0.63106E+04 91 heulandite -5.83 -7.52 -1.69 -0.077 0.28938E+04 95 jadeite 4.22 2.55 -1.67 -0.167 0.28514E+04 97 kalsilite 7.58 4.14 -3.45 -0.493 0.58872E+04 98 kaolinite -1.33 -1.62 -0.28 -0.026 0.48560E+03 99 kyanite 4.88 1.69 -3.18 -0.318 0.54333E+04 101 laumontite 2.88 2.41 -0.47 -0.031 0.80543E+03 102 lawsonite 9.62 9.03 -0.58 -0.039 0.99351E+03 103 leucite 4.12 0.82 -3.29 -0.329 0.56246E+04 105 lizardite 23.24 19.13 -4.11 -0.343 0.70225E+04 107 magnetite 20.09 18.92 -1.17 -0.095 0.19906E+04 108 minnesotaite 10.39 5.82 -4.57 -0.269 0.77980E+04 113 margarite 17.32 14.04 -3.28 -0.131 0.56074E+04 120 muscovite 2.58 2.52 -0.06 -0.004 0.10857E+03 122 nepheline 8.34 5.86 -2.48 -0.355 0.42394E+04 134 phlogopite-Na 29.65 24.99 -4.66 -0.259 0.79554E+04 136 prehnite 19.37 16.37 -3.00 -0.176 0.51182E+04 137 prehnite-Fe 22.50 20.15 -2.34 -0.141 0.40008E+04 138 pumpellyite-Fe 46.27 41.61 -4.66 -0.104 0.79615E+04 145 pyroxmangite 7.40 5.17 -2.23 -0.445 0.38012E+04 146 pyrophyllite -6.18 -8.24 -2.06 -0.129 0.35240E+04 147 quartz -2.99 -3.31 -0.32 -0.107 0.54949E+03 151 rhodochrosite -0.98 -5.83 -4.85 -1.617 0.82809E+04 152 rhodonite 7.45 5.17 -2.27 -0.455 0.38815E+04 153 sanidine -1.28 -2.49 -1.21 -0.093 0.20677E+04 156 sillimanite 5.26 1.69 -3.57 -0.357 0.60913E+04 164 stilpnomelane-Fe 13.02 12.76 -0.25 -0.008 0.43113E+03 165 stilpnomelane-Mg 27.44 23.91 -3.53 -0.105 0.60295E+04 168 sudoite 21.08 17.25 -3.83 -0.124 0.65420E+04 171 talc 16.49 12.51 -3.98 -0.234 0.68001E+04 174 tephroite 18.09 13.66 -4.43 -0.633 0.75635E+04 177 topaz-H 4.62 1.69 -2.92 -0.266 0.49933E+04 178 tridymite -2.63 -3.31 -0.68 -0.228 0.11695E+04 187 wairakite 3.95 2.41 -1.54 -0.091 0.26274E+04 188 walstromite 11.51 7.34 -4.17 -0.834 0.71186E+04 189 wollastonite 10.46 7.34 -3.12 -0.624 0.53291E+04 190 pseudo-wollastonite 11.00 7.34 -3.66 -0.732 0.62489E+04 191 zoisite 22.85 18.88 -3.97 -0.181 0.67828E+04 192 akaganeite 7.75 6.28 -1.47 -0.318 0.25125E+04 193 beidellite-Ca -1.65 -4.56 -2.92 -0.181 0.49824E+04 194 beidellite-H -2.33 -6.32 -3.99 -0.255 0.68211E+04 195 beidellite-K -1.52 -4.69 -3.17 -0.194 0.54112E+04 196 beidellite-Mg -1.79 -4.90 -3.11 -0.193 0.53185E+04 197 beidellite-Na -1.34 -4.12 -2.78 -0.170 0.47456E+04 199 chalcedony -2.80 -3.31 -0.51 -0.170 0.86879E+03 201 montmorillonite-Ca -2.29 -4.48 -2.18 -0.135 0.37299E+04 202 montmorillonite-K -2.24 -4.60 -2.36 -0.145 0.40369E+04 203 montmorillonite-Mg -2.48 -4.82 -2.34 -0.145 0.39892E+04 204 montmorillonite-Na -2.04 -4.03 -2.00 -0.122 0.34070E+04 205 nontronite-Ca 3.21 3.00 -0.22 -0.014 0.37103E+03 206 nontronite-H 2.53 1.24 -1.29 -0.087 0.22076E+04 207 nontronite-K 3.34 2.87 -0.47 -0.030 0.80117E+03 208 nontronite-Mg 3.07 2.66 -0.42 -0.027 0.71442E+03 209 nontronite-Na 3.52 3.44 -0.08 -0.005 0.13732E+03 224 tobermorite 9.82 5.56 -4.26 -1.163 0.72767E+04 233 boehmite 4.41 2.50 -1.90 -0.317 0.32504E+04 235 ferrous-oxide 9.81 6.36 -3.46 -0.864 0.59014E+04 240 silica-amorphous -2.09 -3.31 -1.22 -0.407 0.20830E+04 242 an20ab80 2.02 1.19 -0.82 -0.063 0.14064E+04 243 an25ab75 2.65 1.68 -0.96 -0.074 0.16419E+04 244 an30ab70 3.28 2.17 -1.11 -0.085 0.18870E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 0.1000000 g Current total amount of reactant added: 1.9990000 g New total amount of reactant added: 2.0990000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.8100E-13 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 7 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 2.0990000 Water: Moles liquid = 0.5549E+02 kg liquid = 0.9996E+00 Moles total = 0.5548E+02 kg total = 0.9995E+00 Activity = 1.0000 Stoichiometric ionic strength = .1678262E-02 Osmotic coef. = 0.9767 True ionic strength = .2685010E-02 Chg. balance for total moles = 0.8100E-13 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.51604E-09 -9.2873 0.47479E-09 -9.3235 0.92006E+00 -0.0362 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13793E-03 -3.8604 0.12677E-03 -3.8970 0.91907E+00 -0.0366 4 SO4-- 0.25501E-04 -4.5934 0.19242E-04 -4.7158 0.75455E+00 -0.1223 5 HCO3- 0.10672E-04 -4.9718 0.98109E-05 -5.0083 0.91931E+00 -0.0365 6 HS- 0.40406E-13 -13.3936 0.37137E-13 -13.4302 0.91910E+00 -0.0366 7 Al+++ 0.60392E-25 -25.2190 0.32694E-25 -25.4855 0.54136E+00 -0.2665 8 H4SiO4 0.49446E-03 -3.3059 0.49446E-03 -3.3059 0.10000E+01 0.0000 9 Ca++ 0.13335E-07 -7.8750 0.10049E-07 -7.9979 0.75358E+00 -0.1229 10 Mg++ 0.11603E-09 -9.9354 0.87371E-10 -10.0586 0.75297E+00 -0.1232 11 Fe++ 0.68449E-12 -12.1646 0.51550E-12 -12.2878 0.75312E+00 -0.1231 12 K+ 0.45622E-04 -4.3408 0.41942E-04 -4.3773 0.91935E+00 -0.0365 13 Na+ 0.26021E-02 -2.5847 0.23914E-02 -2.6213 0.91905E+00 -0.0367 14 Mn++ 0.91966E-10 -10.0364 0.69271E-10 -10.1594 0.75323E+00 -0.1231 15 HPO4-- 0.93244E-05 -5.0304 0.70359E-05 -5.1527 0.75457E+00 -0.1223 16 HSiO3- 0.10580E-02 -2.9755 0.97242E-03 -3.0121 0.91907E+00 -0.0366 17 Ca(HSiO3)+ 0.24205E-09 -9.6161 0.22254E-09 -9.6526 0.91939E+00 -0.0365 18 Mg(HSiO3)+ 0.26191E-11 -11.5818 0.24080E-11 -11.6183 0.91939E+00 -0.0365 19 NaHSiO3,aq 0.37611E-04 -4.4247 0.37611E-04 -4.4247 0.10000E+01 0.0000 20 AlO+ 0.21461E-13 -13.6684 0.19731E-13 -13.7049 0.91939E+00 -0.0365 21 AlOH+2 0.61918E-19 -19.2082 0.46646E-19 -19.3312 0.75336E+00 -0.1230 22 HAlO2,aq 0.82758E-08 -8.0822 0.82758E-08 -8.0822 0.10000E+01 0.0000 23 AlO2- 0.41995E-04 -4.3768 0.38584E-04 -4.4136 0.91878E+00 -0.0368 24 CH4,aq 0.18403E-19 -19.7351 0.18394E-19 -19.7353 0.99948E+00 -0.0002 29 CO,aq 0.13528E-18 -18.8688 0.13528E-18 -18.8688 0.10000E+01 0.0000 30 CO2,aq 0.99584E-08 -8.0018 0.99533E-08 -8.0020 0.99948E+00 -0.0002 31 CO3-2 0.23929E-05 -5.6211 0.18049E-05 -5.7436 0.75427E+00 -0.1225 32 CaCO3,aq 0.22741E-09 -9.6432 0.22741E-09 -9.6432 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.27372E-11 -11.5627 0.25165E-11 -11.5992 0.91939E+00 -0.0365 34 CaCl+ 0.22422E-11 -11.6493 0.20615E-11 -11.6858 0.91939E+00 -0.0365 35 CaCl2,aq 0.62084E-16 -16.2070 0.62084E-16 -16.2070 0.10000E+01 0.0000 36 CaOH+ 0.16406E-08 -8.7850 0.15084E-08 -8.8215 0.91939E+00 -0.0365 37 CaSO4,aq 0.61399E-10 -10.2118 0.61399E-10 -10.2118 0.10000E+01 0.0000 38 HCl,aq 0.11029E-13 -13.9575 0.11029E-13 -13.9575 0.10000E+01 0.0000 43 FeCl+ 0.11250E-15 -15.9488 0.10343E-15 -15.9853 0.91939E+00 -0.0365 46 FeO,aq 0.88877E-10 -10.0512 0.88877E-10 -10.0512 0.10000E+01 0.0000 47 FeOH+ 0.38441E-10 -10.4152 0.35342E-10 -10.4517 0.91939E+00 -0.0365 48 HFeO2- 0.21311E-08 -8.6714 0.19586E-08 -8.7081 0.91907E+00 -0.0366 49 FeO+ 0.39418E-14 -14.4043 0.36240E-14 -14.4408 0.91939E+00 -0.0365 51 FeO2- 0.35792E-08 -8.4462 0.32895E-08 -8.4829 0.91907E+00 -0.0366 52 HFeO2,aq 0.19864E-09 -9.7019 0.19864E-09 -9.7019 0.10000E+01 0.0000 53 H2,aq 0.54135E-09 -9.2665 0.54107E-09 -9.2668 0.99948E+00 -0.0002 54 KCl,aq 0.96363E-10 -10.0161 0.96363E-10 -10.0161 0.10000E+01 0.0000 55 KHSO4,aq 0.10834E-17 -17.9652 0.10834E-17 -17.9652 0.10000E+01 0.0000 56 KOH,aq 0.37726E-07 -7.4234 0.37726E-07 -7.4234 0.10000E+01 0.0000 57 KSO4- 0.13626E-07 -7.8656 0.12523E-07 -7.9023 0.91907E+00 -0.0366 58 MgCO3,aq 0.49562E-12 -12.3048 0.49562E-12 -12.3048 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.24318E-13 -13.6141 0.22358E-13 -13.6506 0.91939E+00 -0.0365 60 MgCl+ 0.17669E-13 -13.7528 0.16245E-13 -13.7893 0.91939E+00 -0.0365 61 MgOH+ 0.78935E-10 -10.1027 0.72572E-10 -10.1392 0.91939E+00 -0.0365 63 MnO,aq 0.31823E-09 -9.4973 0.31823E-09 -9.4973 0.10000E+01 0.0000 64 MnOH+ 0.47986E-09 -9.3189 0.44118E-09 -9.3554 0.91939E+00 -0.0365 65 MnO2-2 0.62113E-13 -13.2068 0.46850E-13 -13.3293 0.75427E+00 -0.1225 66 HMnO2- 0.53024E-11 -11.2755 0.48733E-11 -11.3122 0.91907E+00 -0.0366 69 MnCl+ 0.58815E-13 -13.2305 0.54074E-13 -13.2670 0.91939E+00 -0.0365 70 MnSO4,aq 0.38479E-12 -12.4148 0.38479E-12 -12.4148 0.10000E+01 0.0000 71 NaCl,aq 0.10046E-06 -6.9980 0.10046E-06 -6.9980 0.10000E+01 0.0000 72 NaOH,aq 0.21641E-05 -5.6647 0.21641E-05 -5.6647 0.10000E+01 0.0000 74 OH- 0.13245E-02 -2.8780 0.12169E-02 -2.9147 0.91878E+00 -0.0368 79 HPO3-2 0.15729E-16 -16.8033 0.11864E-16 -16.9258 0.75427E+00 -0.1225 81 H2PO3- 0.12290E-19 -19.9105 0.11295E-19 -19.9471 0.91907E+00 -0.0366 82 H3PO4,aq 0.11093E-13 -13.9550 0.11093E-13 -13.9550 0.10000E+01 0.0000 83 H2PO4- 0.67040E-07 -7.1737 0.61625E-07 -7.2102 0.91923E+00 -0.0366 84 PO4-3 0.22140E-07 -7.6548 0.12091E-07 -7.9175 0.54611E+00 -0.2627 87 H2P2O7-2 0.39478E-15 -15.4036 0.29777E-15 -15.5261 0.75427E+00 -0.1225 88 HP2O7-3 0.23130E-12 -12.6358 0.12523E-12 -12.9023 0.54141E+00 -0.2665 89 P2O7-4 0.18411E-12 -12.7349 0.63011E-13 -13.2006 0.34223E+00 -0.4657 90 H2S,aq 0.54523E-16 -16.2634 0.54495E-16 -16.2636 0.99948E+00 -0.0002 97 SO3-2 0.17890E-14 -14.7474 0.13529E-14 -14.8687 0.75621E+00 -0.1214 98 HSO3- 0.43760E-16 -16.3589 0.40219E-16 -16.3956 0.91907E+00 -0.0366 99 HSO4- 0.95746E-11 -11.0189 0.88043E-11 -11.0553 0.91954E+00 -0.0364 Charge balance for all species = 0.8101E-13 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.5160439E-09 -.2592705E-02 -.2612700E+01 0.0000 2 H2O 0.1000000E+01 0.5550857E+02 0.9997771E+06 0.0000 3 Cl- 0.1379271E-03 0.1380276E-03 0.4892387E+01 5.4265 4 SO4-- 0.2550066E-04 0.2551469E-04 0.2450427E+01 13.9312 5 HCO3- 0.1067199E-04 0.1307506E-04 0.7976233E+00 4.3152 6 HS- 0.4040626E-13 -.3368536E-09 -.1113790E-04 -4.1067 7 Al+++ 0.6039224E-25 0.4200316E-04 0.1133052E+01 2.4850 8 H4SiO4 0.4944602E-03 0.1590120E-02 0.1528004E+03 -3.3059 9 Ca++ 0.1333460E-07 0.1551109E-07 0.6215129E-03 10.6491 10 Mg++ 0.1160343E-09 0.1981260E-09 0.4815750E-05 8.5884 11 Fe++ 0.6844856E-12 0.6036922E-08 0.3370677E-03 6.3592 12 K+ 0.4562166E-04 0.4567310E-04 0.1785506E+01 4.9462 13 Na+ 0.2602060E-02 0.2641936E-02 0.6072384E+02 6.7022 14 Mn++ 0.9196554E-10 0.8958664E-09 0.4920597E-04 8.4875 15 HPO4-- 0.9324360E-05 0.9413540E-05 0.9032977E+00 13.4943 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.3474328E-01 -.2591701E-02 -.3215158E-01 0.0000000E+00 2 H2O 0.5548194E+02 0.5548706E+02 -.5124159E-02 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.8367492E-04 0.2550481E-04 0.5817011E-04 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.5817045E-04 -.3367231E-09 -.5817011E-04 0.0000000E+00 7 Al+++ 0.6844297E-02 0.4198689E-04 0.6802310E-02 0.0000000E+00 8 H4SiO4 0.2185643E-01 0.1589504E-02 0.2026693E-01 0.0000000E+00 9 Ca++ 0.2428620E-02 0.1550509E-07 0.2428605E-02 0.0000000E+00 10 Mg++ 0.1665873E-02 0.1980493E-09 0.1665873E-02 0.0000000E+00 11 Fe++ 0.1496605E-02 0.6034584E-08 0.1496599E-02 0.0000000E+00 12 K+ 0.4456476E-03 0.4565541E-04 0.3999921E-03 0.0000000E+00 13 Na+ 0.2794827E-02 0.2640913E-02 0.1539144E-03 0.0000000E+00 14 Mn++ 0.3639371E-04 0.8955194E-09 0.3639282E-04 0.0000000E+00 15 HPO4-- 0.1242099E-04 0.9409893E-05 0.3011100E-05 0.0000000E+00 Chg. balance for solid moles: -.7979E-18 Mass of aqueous solution: 0.999839E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 2.0990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) apatite-OH 0.1004E-05 -5.998 0.5042E-03 -3.297 0.2238E-01 0.1602E-03 clinochlore 0.3332E-03 -3.477 0.1852 -0.732 8.219 0.7044E-01 daphnite 0.2062E-03 -3.686 0.1472 -0.832 6.531 0.4459E-01 chlorite-Mn 0.7279E-05 -5.138 0.5160E-02 -2.287 0.2290 0.1644E-02 hematite 0.2327E-03 -3.633 0.3716E-01 -1.430 1.649 0.7043E-02 microcline 0.4000E-03 -3.398 0.1113 -0.953 4.941 0.4349E-01 paragonite 0.1539E-03 -3.813 0.5883E-01 -1.230 2.611 0.2033E-01 stilbite 0.2424E-02 -2.616 1.708 0.232 75.80 0.7966 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.6094E+00 0.6094E+00 1.0000 -0.215 daphnite 0.3773E+00 0.3773E+00 1.0000 -0.423 chlorite-Mn 0.1331E-01 0.1331E-01 1.0000 -1.876 hematite 0.1000E+01 0.1000E+01 1.0000 0.000 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 paragonite 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 2.253281 g Volume = 0.984324 cm3 Porosity: 46.4925% V(tot) - V(min): 0.85528E+00 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 2.0990000 g log = 0.3220 Original solution: 1000.0103000 g Original solution / Rock added: 476.42 (Water/Rock Ratio), log = 2.6780 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0203 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.1000E+01 0.9860 0.1006E+01 0.1020E+01 CO2,gas 0.1036E-05 1.0071 0.1065E-05 0.1057E-05 CH4,gas 0.2621E-16 1.0125 0.2707E-16 0.2674E-16 H2,gas 0.6958E-06 1.0005 0.7104E-06 0.7100E-06 H2S,gas 0.1474E-14 0.9960 0.1498E-14 0.1504E-14 S2,gas 0.1636E-36 1.0000 0.1669E-36 0.1669E-36 CO,gas 0.1976E-15 1.0000 0.2016E-15 0.2016E-15 SO3,gas 0.1607E-38 1.0000 0.1640E-38 0.1640E-38 SO2,gas 0.4442E-22 1.0000 0.4532E-22 0.4532E-22 HCl,gas 0.1907E-16 1.0000 0.1946E-16 0.1946E-16 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 32 apatite-OH -18.15 -18.15 0.00 0.000 0.60662E-11 46 clinochlore 39.07 39.07 0.00 0.000 0.36397E-10 47 daphnite 28.97 28.97 0.00 0.000 0.48529E-10 48 chlorite-Mn 46.87 46.87 0.00 0.000 0.12132E-10 90 hematite 12.57 12.57 0.00 0.000 -0.30331E-11 116 microcline -2.49 -2.49 0.00 0.000 0.13649E-10 121 paragonite 4.24 4.24 0.00 0.000 0.13649E-10 163 stilbite -7.52 -7.52 0.00 0.000 0.15165E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -14.33 -7.67 -2.557 0.13099E+05 -5.973 3 CH4,gas 4.54 -13.72 -18.27 -4.567 0.31189E+05 -16.567 4 H2,gas 8.00 0.15 -7.85 -4.484 0.13399E+05 -6.149 5 H2S,gas -6.23 -22.75 -16.52 -8.262 0.28213E+05 -14.824 6 S2,gas -7.34 -45.81 -38.48 -5.919 0.65697E+05 -36.777 7 CO,gas 3.21 -14.18 -17.39 -5.352 0.29701E+05 -15.696 8 SO3,gas 17.12 -23.36 -40.48 -10.121 0.69126E+05 -38.785 9 SO2,gas 0.83 -23.21 -24.04 -6.411 0.41052E+05 -22.344 10 HCl,gas 5.19 -13.22 -18.41 -9.205 0.31434E+05 -16.711 11 acmite 7.71 6.37 -1.34 -0.139 0.22815E+04 15 albite-high 0.69 -0.73 -1.42 -0.110 0.24307E+04 16 albite -0.38 -0.73 -0.35 -0.027 0.59185E+03 19 spessartine 24.46 20.51 -3.94 -0.197 0.67315E+04 20 analcite 3.32 2.58 -0.75 -0.083 0.12746E+04 21 andalusite 5.00 1.66 -3.34 -0.334 0.56986E+04 22 andradite 39.01 34.60 -4.41 -0.229 0.75348E+04 26 annite 20.12 16.59 -3.53 -0.196 0.60312E+04 27 phlogopite 27.06 23.28 -3.79 -0.210 0.64645E+04 29 anorthite 12.71 9.01 -3.70 -0.285 0.63228E+04 35 aragonite 0.97 -3.68 -4.65 -1.550 0.79384E+04 36 brucite 12.57 8.59 -3.98 -0.796 0.67961E+04 37 calcite 0.81 -3.68 -4.49 -1.498 0.76742E+04 38 carnegieite-low 9.02 5.88 -3.14 -0.449 0.53650E+04 39 carnegieite-high 10.09 5.88 -4.21 -0.602 0.71920E+04 40 carpholite-Mg 8.58 6.95 -1.64 -0.109 0.27926E+04 41 carpholite-Fe 6.71 4.72 -2.00 -0.133 0.34068E+04 42 celadonite 5.34 2.80 -2.55 -0.150 0.43465E+04 43 celadonite-Fe 3.88 0.57 -3.31 -0.195 0.56512E+04 44 chrysotile 23.89 19.15 -4.74 -0.395 0.80918E+04 50 chloritoid-Mg 13.20 10.25 -2.95 -0.196 0.50290E+04 51 chloritoid-Fe 9.17 8.02 -1.15 -0.077 0.19642E+04 52 chloritoid-Mn 11.40 10.15 -1.25 -0.083 0.21334E+04 54 coesite -2.38 -3.31 -0.93 -0.310 0.15876E+04 59 corundum 8.38 4.97 -3.41 -0.310 0.58279E+04 61 cristobalite -2.56 -3.31 -0.75 -0.249 0.12730E+04 63 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71234E+04 65 diaspore 2.87 2.48 -0.39 -0.065 0.66376E+03 67 diopside 16.18 12.63 -3.56 -0.356 0.60711E+04 68 hedenbergite 14.21 10.40 -3.81 -0.381 0.65083E+04 75 epidote 24.67 22.63 -2.04 -0.099 0.34769E+04 76 clinozoisite 22.81 18.84 -3.97 -0.180 0.67796E+04 77 epidote-Fe 29.84 26.43 -3.41 -0.177 0.58209E+04 78 fayalite 14.05 9.41 -4.63 -0.662 0.79110E+04 83 gibbsite 4.08 2.48 -1.59 -0.228 0.27223E+04 87 greenalite 16.14 12.47 -3.67 -0.306 0.62725E+04 91 heulandite -5.83 -7.52 -1.69 -0.077 0.28938E+04 95 jadeite 4.22 2.58 -1.64 -0.164 0.28001E+04 97 kalsilite 7.58 4.13 -3.46 -0.494 0.59056E+04 98 kaolinite -1.33 -1.64 -0.31 -0.028 0.52769E+03 99 kyanite 4.88 1.66 -3.21 -0.321 0.54845E+04 101 laumontite 2.88 2.40 -0.49 -0.033 0.83300E+03 102 lawsonite 9.62 9.01 -0.61 -0.041 0.10395E+04 103 leucite 4.12 0.82 -3.30 -0.330 0.56338E+04 105 lizardite 23.24 19.15 -4.09 -0.341 0.69844E+04 107 magnetite 20.09 18.93 -1.16 -0.095 0.19841E+04 108 minnesotaite 10.39 5.85 -4.53 -0.267 0.77415E+04 113 margarite 17.32 13.98 -3.35 -0.134 0.57139E+04 120 muscovite 2.58 2.48 -0.10 -0.006 0.16905E+03 122 nepheline 8.34 5.88 -2.46 -0.351 0.41973E+04 134 phlogopite-Na 29.65 25.03 -4.61 -0.256 0.78752E+04 136 prehnite 19.37 16.35 -3.02 -0.178 0.51589E+04 137 prehnite-Fe 22.50 20.15 -2.35 -0.141 0.40112E+04 138 pumpellyite-Fe 46.27 41.55 -4.72 -0.105 0.80664E+04 145 pyroxmangite 7.40 5.18 -2.22 -0.443 0.37855E+04 146 pyrophyllite -6.18 -8.25 -2.08 -0.130 0.35477E+04 147 quartz -2.99 -3.31 -0.32 -0.105 0.54030E+03 151 rhodochrosite -0.98 -5.84 -4.87 -1.623 0.83118E+04 152 rhodonite 7.45 5.18 -2.26 -0.453 0.38657E+04 153 sanidine -1.28 -2.49 -1.21 -0.093 0.20677E+04 156 sillimanite 5.26 1.66 -3.60 -0.360 0.61426E+04 164 stilpnomelane-Fe 13.02 12.79 -0.22 -0.007 0.38384E+03 165 stilpnomelane-Mg 27.44 23.94 -3.50 -0.105 0.59822E+04 168 sudoite 21.08 17.20 -3.88 -0.125 0.66223E+04 171 talc 16.49 12.54 -3.95 -0.232 0.67436E+04 174 tephroite 18.09 13.67 -4.42 -0.631 0.75412E+04 177 topaz-H 4.62 1.66 -2.95 -0.269 0.50446E+04 178 tridymite -2.63 -3.31 -0.68 -0.227 0.11603E+04 187 wairakite 3.95 2.40 -1.55 -0.091 0.26550E+04 188 walstromite 11.51 7.34 -4.17 -0.833 0.71133E+04 189 wollastonite 10.46 7.34 -3.12 -0.624 0.53237E+04 190 pseudo-wollastonite 11.00 7.34 -3.66 -0.731 0.62436E+04 191 zoisite 22.85 18.84 -4.01 -0.182 0.68536E+04 192 akaganeite 7.75 6.28 -1.47 -0.318 0.25125E+04 193 beidellite-Ca -1.65 -4.59 -2.94 -0.182 0.50198E+04 194 beidellite-H -2.33 -6.34 -4.02 -0.256 0.68578E+04 195 beidellite-K -1.52 -4.71 -3.19 -0.195 0.54470E+04 196 beidellite-Mg -1.79 -4.93 -3.14 -0.194 0.53542E+04 197 beidellite-Na -1.34 -4.13 -2.79 -0.171 0.47615E+04 199 chalcedony -2.80 -3.31 -0.50 -0.168 0.85960E+03 201 montmorillonite-Ca -2.29 -4.48 -2.19 -0.136 0.37421E+04 202 montmorillonite-K -2.24 -4.61 -2.37 -0.145 0.40475E+04 203 montmorillonite-Mg -2.48 -4.82 -2.34 -0.145 0.39997E+04 204 montmorillonite-Na -2.04 -4.03 -1.99 -0.122 0.33977E+04 205 nontronite-Ca 3.21 3.01 -0.20 -0.013 0.34791E+03 206 nontronite-H 2.53 1.25 -1.28 -0.086 0.21839E+04 207 nontronite-K 3.34 2.89 -0.45 -0.029 0.77654E+03 208 nontronite-Mg 3.07 2.67 -0.40 -0.026 0.68958E+03 209 nontronite-Na 3.52 3.47 -0.05 -0.003 0.92727E+02 224 tobermorite 9.82 5.56 -4.26 -1.162 0.72708E+04 233 boehmite 4.41 2.48 -1.92 -0.320 0.32807E+04 235 ferrous-oxide 9.81 6.36 -3.45 -0.863 0.58948E+04 240 silica-amorphous -2.09 -3.31 -1.21 -0.405 0.20738E+04 242 an20ab80 2.02 1.22 -0.80 -0.062 0.13672E+04 243 an25ab75 2.65 1.70 -0.94 -0.072 0.16080E+04 244 an30ab70 3.28 2.19 -1.09 -0.084 0.18584E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 0.1000000 g Current total amount of reactant added: 2.0990000 g New total amount of reactant added: 2.1990000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.8100E-13 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 7 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 2.1990000 Water: Moles liquid = 0.5549E+02 kg liquid = 0.9996E+00 Moles total = 0.5548E+02 kg total = 0.9995E+00 Activity = 1.0000 Stoichiometric ionic strength = .1739081E-02 Osmotic coef. = 0.9764 True ionic strength = .2799519E-02 Chg. balance for total moles = 0.8100E-13 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.49680E-09 -9.3038 0.45651E-09 -9.3405 0.91890E+00 -0.0367 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13793E-03 -3.8604 0.12660E-03 -3.8976 0.91787E+00 -0.0372 4 SO4-- 0.25502E-04 -4.5934 0.19144E-04 -4.7180 0.75069E+00 -0.1245 5 HCO3- 0.10587E-04 -4.9752 0.97202E-05 -5.0123 0.91812E+00 -0.0371 6 HS- 0.41426E-13 -13.3827 0.38025E-13 -13.4199 0.91790E+00 -0.0372 7 Al+++ 0.52247E-25 -25.2819 0.27957E-25 -25.5535 0.53509E+00 -0.2716 8 H4SiO4 0.50026E-03 -3.3008 0.50026E-03 -3.3008 0.10000E+01 0.0000 9 Ca++ 0.12340E-07 -7.9087 0.92513E-08 -8.0338 0.74968E+00 -0.1251 10 Mg++ 0.10875E-09 -9.9636 0.81462E-10 -10.0890 0.74905E+00 -0.1255 11 Fe++ 0.64153E-12 -12.1928 0.48064E-12 -12.3182 0.74920E+00 -0.1254 12 K+ 0.44087E-04 -4.3557 0.40479E-04 -4.3928 0.91816E+00 -0.0371 13 Na+ 0.27171E-02 -2.5659 0.24939E-02 -2.6031 0.91785E+00 -0.0372 14 Mn++ 0.86194E-10 -10.0645 0.64587E-10 -10.1899 0.74932E+00 -0.1253 15 HPO4-- 0.10209E-04 -4.9910 0.76637E-05 -5.1156 0.75071E+00 -0.1245 16 HSiO3- 0.11148E-02 -2.9528 0.10232E-02 -2.9900 0.91787E+00 -0.0372 17 Ca(HSiO3)+ 0.23479E-09 -9.6293 0.21558E-09 -9.6664 0.91820E+00 -0.0371 18 Mg(HSiO3)+ 0.25729E-11 -11.5896 0.23624E-11 -11.6266 0.91820E+00 -0.0371 19 NaHSiO3,aq 0.41272E-04 -4.3843 0.41272E-04 -4.3843 0.10000E+01 0.0000 20 AlO+ 0.19876E-13 -13.7017 0.18250E-13 -13.7387 0.91820E+00 -0.0371 21 AlOH+2 0.55354E-19 -19.2569 0.41485E-19 -19.3821 0.74945E+00 -0.1253 22 HAlO2,aq 0.79614E-08 -8.0990 0.79614E-08 -8.0990 0.10000E+01 0.0000 23 AlO2- 0.42072E-04 -4.3760 0.38604E-04 -4.4134 0.91756E+00 -0.0374 24 CH4,aq 0.18765E-19 -19.7267 0.18755E-19 -19.7269 0.99946E+00 -0.0002 29 CO,aq 0.13108E-18 -18.8825 0.13108E-18 -18.8825 0.10000E+01 0.0000 30 CO2,aq 0.94868E-08 -8.0229 0.94817E-08 -8.0231 0.99946E+00 -0.0002 31 CO3-2 0.24785E-05 -5.6058 0.18598E-05 -5.7305 0.75039E+00 -0.1247 32 CaCO3,aq 0.21574E-09 -9.6661 0.21574E-09 -9.6661 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.24999E-11 -11.6021 0.22954E-11 -11.6391 0.91820E+00 -0.0371 34 CaCl+ 0.20642E-11 -11.6852 0.18954E-11 -11.7223 0.91820E+00 -0.0371 35 CaCl2,aq 0.57007E-16 -16.2441 0.57007E-16 -16.2441 0.10000E+01 0.0000 36 CaOH+ 0.15730E-08 -8.8033 0.14443E-08 -8.8403 0.91820E+00 -0.0371 37 CaSO4,aq 0.56239E-10 -10.2500 0.56239E-10 -10.2500 0.10000E+01 0.0000 38 HCl,aq 0.10590E-13 -13.9751 0.10590E-13 -13.9751 0.10000E+01 0.0000 43 FeCl+ 0.10489E-15 -15.9793 0.96312E-16 -16.0163 0.91820E+00 -0.0371 46 FeO,aq 0.89635E-10 -10.0475 0.89635E-10 -10.0475 0.10000E+01 0.0000 47 FeOH+ 0.37324E-10 -10.4280 0.34271E-10 -10.4651 0.91820E+00 -0.0371 48 HFeO2- 0.22382E-08 -8.6501 0.20544E-08 -8.6873 0.91787E+00 -0.0372 49 FeO+ 0.37949E-14 -14.4208 0.34845E-14 -14.4579 0.91820E+00 -0.0371 51 FeO2- 0.37274E-08 -8.4286 0.34213E-08 -8.4658 0.91787E+00 -0.0372 52 HFeO2,aq 0.19864E-09 -9.7019 0.19864E-09 -9.7019 0.10000E+01 0.0000 53 H2,aq 0.55064E-09 -9.2591 0.55034E-09 -9.2594 0.99946E+00 -0.0002 54 KCl,aq 0.92879E-10 -10.0321 0.92879E-10 -10.0321 0.10000E+01 0.0000 55 KHSO4,aq 0.10002E-17 -17.9999 0.10002E-17 -17.9999 0.10000E+01 0.0000 56 KOH,aq 0.37867E-07 -7.4217 0.37867E-07 -7.4217 0.10000E+01 0.0000 57 KSO4- 0.13101E-07 -7.8827 0.12025E-07 -7.9199 0.91787E+00 -0.0372 58 MgCO3,aq 0.47617E-12 -12.3222 0.47617E-12 -12.3222 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.22493E-13 -13.6479 0.20653E-13 -13.6850 0.91820E+00 -0.0371 60 MgCl+ 0.16474E-13 -13.7832 0.15126E-13 -13.8203 0.91820E+00 -0.0371 61 MgOH+ 0.76643E-10 -10.1155 0.70373E-10 -10.1526 0.91820E+00 -0.0371 63 MnO,aq 0.32095E-09 -9.4936 0.32095E-09 -9.4936 0.10000E+01 0.0000 64 MnOH+ 0.46593E-09 -9.3317 0.42781E-09 -9.3687 0.91820E+00 -0.0371 65 MnO2-2 0.68110E-13 -13.1668 0.51109E-13 -13.2915 0.75039E+00 -0.1247 66 HMnO2- 0.55690E-11 -11.2542 0.51117E-11 -11.2914 0.91787E+00 -0.0372 69 MnCl+ 0.54836E-13 -13.2609 0.50350E-13 -13.2980 0.91820E+00 -0.0371 70 MnSO4,aq 0.35695E-12 -12.4474 0.35695E-12 -12.4474 0.10000E+01 0.0000 71 NaCl,aq 0.10463E-06 -6.9803 0.10463E-06 -6.9803 0.10000E+01 0.0000 72 NaOH,aq 0.23472E-05 -5.6295 0.23472E-05 -5.6295 0.10000E+01 0.0000 74 OH- 0.13793E-02 -2.8603 0.12656E-02 -2.8977 0.91756E+00 -0.0374 79 HPO3-2 0.17516E-16 -16.7566 0.13143E-16 -16.8813 0.75039E+00 -0.1247 81 H2PO3- 0.13109E-19 -19.8824 0.12032E-19 -19.9197 0.91787E+00 -0.0372 82 H3PO4,aq 0.11170E-13 -13.9519 0.11170E-13 -13.9519 0.10000E+01 0.0000 83 H2PO4- 0.70301E-07 -7.1530 0.64539E-07 -7.1902 0.91803E+00 -0.0371 84 PO4-3 0.25366E-07 -7.5957 0.13697E-07 -7.8634 0.53997E+00 -0.2676 87 H2P2O7-2 0.43524E-15 -15.3613 0.32660E-15 -15.4860 0.75039E+00 -0.1247 88 HP2O7-3 0.26694E-12 -12.5736 0.14285E-12 -12.8451 0.53514E+00 -0.2715 89 P2O7-4 0.22296E-12 -12.6518 0.74756E-13 -13.1264 0.33528E+00 -0.4746 90 H2S,aq 0.53678E-16 -16.2702 0.53649E-16 -16.2704 0.99946E+00 -0.0002 97 SO3-2 0.18196E-14 -14.7400 0.13691E-14 -14.8636 0.75240E+00 -0.1236 98 HSO3- 0.42634E-16 -16.3702 0.39133E-16 -16.4075 0.91787E+00 -0.0372 99 HSO4- 0.91710E-11 -11.0376 0.84222E-11 -11.0746 0.91836E+00 -0.0370 Charge balance for all species = 0.8105E-13 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.4968039E-09 -.2708530E-02 -.2729393E+01 0.0000 2 H2O 0.1000000E+01 0.5550856E+02 0.9997681E+06 0.0000 3 Cl- 0.1379254E-03 0.1380301E-03 0.4892430E+01 5.4430 4 SO4-- 0.2550164E-04 0.2551516E-04 0.2450451E+01 13.9631 5 HCO3- 0.1058713E-04 0.1307530E-04 0.7976304E+00 4.3282 6 HS- 0.4142600E-13 -.3530535E-09 -.1167344E-04 -4.0794 7 Al+++ 0.5224748E-25 0.4208029E-04 0.1135122E+01 2.4681 8 H4SiO4 0.5002607E-03 0.1656313E-02 0.1591597E+03 -3.3008 9 Ca++ 0.1234023E-07 0.1442452E-07 0.5779698E-03 10.6473 10 Mg++ 0.1087532E-09 0.1884839E-09 0.4581343E-05 8.5921 11 Fe++ 0.6415297E-12 0.6291876E-08 0.3512998E-03 6.3629 12 K+ 0.4408702E-04 0.4413808E-04 0.1725481E+01 4.9478 13 Na+ 0.2717127E-02 0.2760851E-02 0.6345649E+02 6.7374 14 Mn++ 0.8619373E-10 0.8791168E-09 0.4828556E-04 8.4912 15 HPO4-- 0.1020860E-04 0.1030427E-04 0.9887605E+00 13.5655 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.3639914E-01 -.2707432E-02 -.3369170E-01 0.0000000E+00 2 H2O 0.5548068E+02 0.5548607E+02 -.5383418E-02 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.8644626E-04 0.2550482E-04 0.6094143E-04 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.6094179E-04 -.3529104E-09 -.6094143E-04 0.0000000E+00 7 Al+++ 0.7170371E-02 0.4206324E-04 0.7128308E-02 0.0000000E+00 8 H4SiO4 0.2289771E-01 0.1655642E-02 0.2124207E-01 0.0000000E+00 9 Ca++ 0.2543635E-02 0.1441867E-07 0.2543620E-02 0.0000000E+00 10 Mg++ 0.1745238E-02 0.1884076E-09 0.1745238E-02 0.0000000E+00 11 Fe++ 0.1567906E-02 0.6289327E-08 0.1567900E-02 0.0000000E+00 12 K+ 0.4668790E-03 0.4412020E-04 0.4227588E-03 0.0000000E+00 13 Na+ 0.2920352E-02 0.2759733E-02 0.1606191E-03 0.0000000E+00 14 Mn++ 0.3812757E-04 0.8787606E-09 0.3812669E-04 0.0000000E+00 15 HPO4-- 0.1301275E-04 0.1030009E-04 0.2712660E-05 0.0000000E+00 Chg. balance for solid moles: 0.4498E-17 Mass of aqueous solution: 0.999830E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 2.1990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) apatite-OH 0.9042E-06 -6.044 0.4542E-03 -3.343 0.1923E-01 0.1443E-03 clinochlore 0.3490E-03 -3.457 0.1940 -0.712 8.216 0.7380E-01 daphnite 0.2161E-03 -3.665 0.1542 -0.812 6.529 0.4672E-01 chlorite-Mn 0.7625E-05 -5.118 0.5406E-02 -2.267 0.2289 0.1723E-02 hematite 0.2438E-03 -3.613 0.3893E-01 -1.410 1.649 0.7379E-02 microcline 0.4228E-03 -3.374 0.1177 -0.929 4.983 0.4597E-01 paragonite 0.1606E-03 -3.794 0.6139E-01 -1.212 2.600 0.2122E-01 stilbite 0.2539E-02 -2.595 1.789 0.253 75.78 0.8346 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.6094E+00 0.6094E+00 1.0000 -0.215 daphnite 0.3773E+00 0.3773E+00 1.0000 -0.423 chlorite-Mn 0.1331E-01 0.1331E-01 1.0000 -1.876 hematite 0.1000E+01 0.1000E+01 1.0000 0.000 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 paragonite 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 2.361385 g Volume = 1.031532 cm3 Porosity: 45.1196% V(tot) - V(min): 0.84807E+00 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 2.1990000 g log = 0.3422 Original solution: 1000.0103000 g Original solution / Rock added: 454.76 (Water/Rock Ratio), log = 2.6578 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0203 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.1000E+01 0.9860 0.1006E+01 0.1020E+01 CO2,gas 0.9873E-06 1.0071 0.1014E-05 0.1007E-05 CH4,gas 0.2672E-16 1.0125 0.2761E-16 0.2726E-16 H2,gas 0.7078E-06 1.0005 0.7225E-06 0.7221E-06 H2S,gas 0.1451E-14 0.9960 0.1475E-14 0.1481E-14 S2,gas 0.1533E-36 1.0000 0.1564E-36 0.1564E-36 CO,gas 0.1915E-15 1.0000 0.1953E-15 0.1953E-15 SO3,gas 0.1478E-38 1.0000 0.1508E-38 0.1508E-38 SO2,gas 0.4156E-22 1.0000 0.4240E-22 0.4240E-22 HCl,gas 0.1832E-16 1.0000 0.1869E-16 0.1869E-16 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 32 apatite-OH -18.15 -18.15 0.00 0.000 0.00000E+00 46 clinochlore 39.07 39.07 0.00 0.000 0.00000E+00 47 daphnite 28.97 28.97 0.00 0.000 -0.42463E-10 48 chlorite-Mn 46.87 46.87 0.00 0.000 -0.36397E-10 90 hematite 12.57 12.57 0.00 0.000 0.15165E-10 116 microcline -2.49 -2.49 0.00 0.000 -0.10616E-10 121 paragonite 4.24 4.24 0.00 0.000 -0.10616E-10 163 stilbite -7.52 -7.52 0.00 0.000 0.15165E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -14.35 -7.69 -2.564 0.13135E+05 -5.994 3 CH4,gas 4.54 -13.71 -18.26 -4.564 0.31175E+05 -16.559 4 H2,gas 8.00 0.16 -7.84 -4.480 0.13387E+05 -6.141 5 H2S,gas -6.23 -22.76 -16.53 -8.265 0.28225E+05 -14.831 6 S2,gas -7.34 -45.84 -38.50 -5.924 0.65746E+05 -36.806 7 CO,gas 3.21 -14.19 -17.41 -5.356 0.29724E+05 -15.709 8 SO3,gas 17.12 -23.40 -40.52 -10.130 0.69188E+05 -38.821 9 SO2,gas 0.83 -23.24 -24.07 -6.419 0.41102E+05 -22.373 10 HCl,gas 5.19 -13.24 -18.43 -9.214 0.31464E+05 -16.728 11 acmite 7.71 6.42 -1.29 -0.134 0.22040E+04 15 albite-high 0.69 -0.70 -1.39 -0.107 0.23732E+04 16 albite -0.38 -0.70 -0.31 -0.024 0.53440E+03 19 spessartine 24.46 20.51 -3.95 -0.197 0.67441E+04 20 analcite 3.32 2.60 -0.72 -0.080 0.12258E+04 21 andalusite 5.00 1.64 -3.37 -0.337 0.57474E+04 22 andradite 39.01 34.61 -4.40 -0.229 0.75181E+04 26 annite 20.12 16.60 -3.52 -0.196 0.60123E+04 27 phlogopite 27.06 23.29 -3.77 -0.210 0.64456E+04 29 anorthite 12.71 8.98 -3.73 -0.287 0.63661E+04 35 aragonite 0.97 -3.71 -4.67 -1.557 0.79775E+04 36 brucite 12.57 8.59 -3.98 -0.795 0.67898E+04 37 calcite 0.81 -3.71 -4.52 -1.506 0.77132E+04 38 carnegieite-low 9.02 5.90 -3.12 -0.446 0.53248E+04 39 carnegieite-high 10.09 5.90 -4.19 -0.598 0.71518E+04 40 carpholite-Mg 8.58 6.93 -1.66 -0.110 0.28265E+04 41 carpholite-Fe 6.71 4.70 -2.02 -0.134 0.34407E+04 42 celadonite 5.34 2.80 -2.54 -0.149 0.43316E+04 43 celadonite-Fe 3.88 0.58 -3.30 -0.194 0.56362E+04 44 chrysotile 23.89 19.17 -4.72 -0.393 0.80556E+04 50 chloritoid-Mg 13.20 10.23 -2.97 -0.198 0.50715E+04 51 chloritoid-Fe 9.17 8.00 -1.18 -0.078 0.20067E+04 52 chloritoid-Mn 11.40 10.13 -1.27 -0.085 0.21759E+04 54 coesite -2.38 -3.30 -0.92 -0.308 0.15790E+04 59 corundum 8.38 4.94 -3.45 -0.313 0.58854E+04 61 cristobalite -2.56 -3.30 -0.74 -0.247 0.12643E+04 63 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71234E+04 65 diaspore 2.87 2.47 -0.41 -0.068 0.69248E+03 67 diopside 16.18 12.64 -3.54 -0.354 0.60506E+04 68 hedenbergite 14.21 10.41 -3.80 -0.380 0.64878E+04 75 epidote 24.67 22.61 -2.06 -0.100 0.35146E+04 76 clinozoisite 22.81 18.80 -4.01 -0.182 0.68460E+04 77 epidote-Fe 29.84 26.43 -3.41 -0.177 0.58298E+04 78 fayalite 14.05 9.43 -4.62 -0.660 0.78897E+04 83 gibbsite 4.08 2.47 -1.61 -0.230 0.27510E+04 87 greenalite 16.14 12.49 -3.65 -0.304 0.62363E+04 91 heulandite -5.83 -7.52 -1.69 -0.077 0.28938E+04 95 jadeite 4.22 2.60 -1.61 -0.161 0.27513E+04 97 kalsilite 7.58 4.12 -3.47 -0.496 0.59229E+04 98 kaolinite -1.33 -1.67 -0.33 -0.030 0.56784E+03 99 kyanite 4.88 1.64 -3.24 -0.324 0.55333E+04 101 laumontite 2.88 2.38 -0.50 -0.034 0.85895E+03 102 lawsonite 9.62 8.98 -0.63 -0.042 0.10827E+04 103 leucite 4.12 0.81 -3.30 -0.330 0.56424E+04 105 lizardite 23.24 19.17 -4.07 -0.339 0.69482E+04 107 magnetite 20.09 18.93 -1.16 -0.095 0.19778E+04 108 minnesotaite 10.39 5.89 -4.50 -0.265 0.76880E+04 113 margarite 17.32 13.92 -3.41 -0.136 0.58146E+04 120 muscovite 2.58 2.45 -0.13 -0.008 0.22650E+03 122 nepheline 8.34 5.90 -2.43 -0.348 0.41572E+04 134 phlogopite-Na 29.65 25.08 -4.57 -0.254 0.77988E+04 136 prehnite 19.37 16.33 -3.04 -0.179 0.51966E+04 137 prehnite-Fe 22.50 20.14 -2.35 -0.142 0.40202E+04 138 pumpellyite-Fe 46.27 41.49 -4.78 -0.106 0.81642E+04 145 pyroxmangite 7.40 5.19 -2.21 -0.442 0.37705E+04 146 pyrophyllite -6.18 -8.27 -2.09 -0.131 0.35706E+04 147 quartz -2.99 -3.30 -0.31 -0.104 0.53165E+03 151 rhodochrosite -0.98 -5.86 -4.89 -1.628 0.83415E+04 152 rhodonite 7.45 5.19 -2.26 -0.451 0.38508E+04 153 sanidine -1.28 -2.49 -1.21 -0.093 0.20677E+04 156 sillimanite 5.26 1.64 -3.63 -0.363 0.61914E+04 164 stilpnomelane-Fe 13.02 12.82 -0.20 -0.006 0.33921E+03 165 stilpnomelane-Mg 27.44 23.96 -3.48 -0.104 0.59376E+04 168 sudoite 21.08 17.15 -3.92 -0.127 0.66986E+04 171 talc 16.49 12.57 -3.92 -0.230 0.66901E+04 174 tephroite 18.09 13.68 -4.40 -0.629 0.75199E+04 177 topaz-H 4.62 1.64 -2.98 -0.271 0.50934E+04 178 tridymite -2.63 -3.30 -0.67 -0.225 0.11516E+04 187 wairakite 3.95 2.38 -1.57 -0.092 0.26809E+04 188 walstromite 11.51 7.35 -4.16 -0.833 0.71078E+04 189 wollastonite 10.46 7.35 -3.11 -0.623 0.53182E+04 190 pseudo-wollastonite 11.00 7.35 -3.65 -0.731 0.62380E+04 191 zoisite 22.85 18.80 -4.05 -0.184 0.69201E+04 192 akaganeite 7.75 6.28 -1.47 -0.318 0.25125E+04 193 beidellite-Ca -1.65 -4.61 -2.96 -0.183 0.50555E+04 194 beidellite-H -2.33 -6.36 -4.04 -0.258 0.68930E+04 195 beidellite-K -1.52 -4.73 -3.21 -0.197 0.54813E+04 196 beidellite-Mg -1.79 -4.95 -3.16 -0.195 0.53883E+04 197 beidellite-Na -1.34 -4.14 -2.80 -0.171 0.47768E+04 199 chalcedony -2.80 -3.30 -0.50 -0.166 0.85095E+03 201 montmorillonite-Ca -2.29 -4.49 -2.20 -0.136 0.37539E+04 202 montmorillonite-K -2.24 -4.61 -2.38 -0.146 0.40579E+04 203 montmorillonite-Mg -2.48 -4.83 -2.35 -0.145 0.40100E+04 204 montmorillonite-Na -2.04 -4.02 -1.98 -0.122 0.33892E+04 205 nontronite-Ca 3.21 3.02 -0.19 -0.012 0.32616E+03 206 nontronite-H 2.53 1.27 -1.27 -0.085 0.21616E+04 207 nontronite-K 3.34 2.90 -0.44 -0.028 0.75336E+03 208 nontronite-Mg 3.07 2.68 -0.39 -0.025 0.66628E+03 209 nontronite-Na 3.52 3.49 -0.03 -0.002 0.50589E+02 224 tobermorite 9.82 5.57 -4.25 -1.161 0.72647E+04 233 boehmite 4.41 2.47 -1.94 -0.323 0.33094E+04 235 ferrous-oxide 9.81 6.36 -3.45 -0.862 0.58885E+04 240 silica-amorphous -2.09 -3.30 -1.21 -0.403 0.20651E+04 242 an20ab80 2.02 1.24 -0.78 -0.060 0.13299E+04 243 an25ab75 2.65 1.72 -0.92 -0.071 0.15757E+04 244 an30ab70 3.28 2.21 -1.07 -0.082 0.18312E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 0.1000000 g Current total amount of reactant added: 2.1990000 g New total amount of reactant added: 2.2990000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.8100E-13 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 7 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 2.2990000 Water: Moles liquid = 0.5548E+02 kg liquid = 0.9996E+00 Moles total = 0.5548E+02 kg total = 0.9995E+00 Activity = 1.0000 Stoichiometric ionic strength = .1800030E-02 Osmotic coef. = 0.9760 True ionic strength = .2914004E-02 Chg. balance for total moles = 0.8100E-13 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.47910E-09 -9.3196 0.43970E-09 -9.3568 0.91776E+00 -0.0373 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13792E-03 -3.8604 0.12643E-03 -3.8981 0.91670E+00 -0.0378 4 SO4-- 0.25503E-04 -4.5934 0.19049E-04 -4.7201 0.74693E+00 -0.1267 5 HCO3- 0.10504E-04 -4.9787 0.96314E-05 -5.0163 0.91696E+00 -0.0377 6 HS- 0.42433E-13 -13.3723 0.38900E-13 -13.4101 0.91673E+00 -0.0378 7 Al+++ 0.45510E-25 -25.3419 0.24077E-25 -25.6184 0.52903E+00 -0.2765 8 H4SiO4 0.50579E-03 -3.2960 0.50579E-03 -3.2960 0.10000E+01 0.0000 9 Ca++ 0.11470E-07 -7.9404 0.85554E-08 -8.0678 0.74590E+00 -0.1273 10 Mg++ 0.10224E-09 -9.9904 0.76192E-10 -10.1181 0.74524E+00 -0.1277 11 Fe++ 0.60309E-12 -12.2196 0.44954E-12 -12.3472 0.74540E+00 -0.1276 12 K+ 0.42684E-04 -4.3697 0.39141E-04 -4.4074 0.91700E+00 -0.0376 13 Na+ 0.28320E-02 -2.5479 0.25960E-02 -2.5857 0.91668E+00 -0.0378 14 Mn++ 0.81029E-10 -10.0914 0.60408E-10 -10.2189 0.74552E+00 -0.1275 15 HPO4-- 0.11118E-04 -4.9540 0.83045E-05 -5.0807 0.74695E+00 -0.1267 16 HSiO3- 0.11717E-02 -2.9312 0.10741E-02 -2.9690 0.91670E+00 -0.0378 17 Ca(HSiO3)+ 0.22820E-09 -9.6417 0.20927E-09 -9.6793 0.91704E+00 -0.0376 18 Mg(HSiO3)+ 0.25293E-11 -11.5970 0.23194E-11 -11.6346 0.91704E+00 -0.0376 19 NaHSiO3,aq 0.45098E-04 -4.3458 0.45098E-04 -4.3458 0.10000E+01 0.0000 20 AlO+ 0.18474E-13 -13.7334 0.16942E-13 -13.7710 0.91704E+00 -0.0376 21 AlOH+2 0.49745E-19 -19.3032 0.37093E-19 -19.4307 0.74566E+00 -0.1275 22 HAlO2,aq 0.76732E-08 -8.1150 0.76732E-08 -8.1150 0.10000E+01 0.0000 23 AlO2- 0.42154E-04 -4.3752 0.38629E-04 -4.4131 0.91638E+00 -0.0379 24 CH4,aq 0.19116E-19 -19.7186 0.19106E-19 -19.7188 0.99944E+00 -0.0002 29 CO,aq 0.12716E-18 -18.8956 0.12716E-18 -18.8956 0.10000E+01 0.0000 30 CO2,aq 0.90541E-08 -8.0432 0.90491E-08 -8.0434 0.99944E+00 -0.0002 31 CO3-2 0.25626E-05 -5.5913 0.19133E-05 -5.7182 0.74662E+00 -0.1269 32 CaCO3,aq 0.20525E-09 -9.6877 0.20525E-09 -9.6877 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.22936E-11 -11.6395 0.21034E-11 -11.6771 0.91704E+00 -0.0376 34 CaCl+ 0.19089E-11 -11.7192 0.17505E-11 -11.7568 0.91704E+00 -0.0376 35 CaCl2,aq 0.52583E-16 -16.2792 0.52583E-16 -16.2792 0.10000E+01 0.0000 36 CaOH+ 0.15122E-08 -8.8204 0.13867E-08 -8.8580 0.91704E+00 -0.0376 37 CaSO4,aq 0.51750E-10 -10.2861 0.51750E-10 -10.2861 0.10000E+01 0.0000 38 HCl,aq 0.10187E-13 -13.9919 0.10187E-13 -13.9919 0.10000E+01 0.0000 43 FeCl+ 0.98104E-16 -16.0083 0.89965E-16 -16.0459 0.91704E+00 -0.0376 46 FeO,aq 0.90369E-10 -10.0440 0.90369E-10 -10.0440 0.10000E+01 0.0000 47 FeOH+ 0.36290E-10 -10.4402 0.33280E-10 -10.4778 0.91704E+00 -0.0376 48 HFeO2- 0.23458E-08 -8.6297 0.21504E-08 -8.6675 0.91670E+00 -0.0378 49 FeO+ 0.36598E-14 -14.4365 0.33562E-14 -14.4742 0.91704E+00 -0.0376 51 FeO2- 0.38748E-08 -8.4117 0.35521E-08 -8.4495 0.91670E+00 -0.0378 52 HFeO2,aq 0.19864E-09 -9.7019 0.19864E-09 -9.7019 0.10000E+01 0.0000 53 H2,aq 0.55970E-09 -9.2520 0.55939E-09 -9.2523 0.99944E+00 -0.0002 54 KCl,aq 0.89693E-10 -10.0472 0.89693E-10 -10.0472 0.10000E+01 0.0000 55 KHSO4,aq 0.92691E-18 -18.0330 0.92691E-18 -18.0330 0.10000E+01 0.0000 56 KOH,aq 0.38016E-07 -7.4200 0.38016E-07 -7.4200 0.10000E+01 0.0000 57 KSO4- 0.12621E-07 -7.8989 0.11570E-07 -7.9367 0.91670E+00 -0.0378 58 MgCO3,aq 0.45817E-12 -12.3390 0.45817E-12 -12.3390 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.20872E-13 -13.6804 0.19141E-13 -13.7180 0.91704E+00 -0.0376 60 MgCl+ 0.15408E-13 -13.8123 0.14130E-13 -13.8499 0.91704E+00 -0.0376 61 MgOH+ 0.74519E-10 -10.1277 0.68337E-10 -10.1653 0.91704E+00 -0.0376 63 MnO,aq 0.32357E-09 -9.4900 0.32357E-09 -9.4900 0.10000E+01 0.0000 64 MnOH+ 0.45302E-09 -9.3439 0.41544E-09 -9.3815 0.91704E+00 -0.0376 65 MnO2-2 0.74393E-13 -13.1285 0.55543E-13 -13.2554 0.74662E+00 -0.1269 66 HMnO2- 0.58368E-11 -11.2338 0.53506E-11 -11.2716 0.91670E+00 -0.0378 69 MnCl+ 0.51287E-13 -13.2900 0.47033E-13 -13.3276 0.91704E+00 -0.0376 70 MnSO4,aq 0.33220E-12 -12.4786 0.33220E-12 -12.4786 0.10000E+01 0.0000 71 NaCl,aq 0.10878E-06 -6.9635 0.10878E-06 -6.9635 0.10000E+01 0.0000 72 NaOH,aq 0.25367E-05 -5.5957 0.25367E-05 -5.5957 0.10000E+01 0.0000 74 OH- 0.14339E-02 -2.8435 0.13140E-02 -2.8814 0.91638E+00 -0.0379 79 HPO3-2 0.19390E-16 -16.7124 0.14477E-16 -16.8393 0.74662E+00 -0.1269 81 H2PO3- 0.13925E-19 -19.8562 0.12765E-19 -19.8940 0.91670E+00 -0.0378 82 H3PO4,aq 0.11229E-13 -13.9496 0.11229E-13 -13.9496 0.10000E+01 0.0000 83 H2PO4- 0.73468E-07 -7.1339 0.67360E-07 -7.1716 0.91687E+00 -0.0377 84 PO4-3 0.28855E-07 -7.5398 0.15410E-07 -7.8122 0.53404E+00 -0.2724 87 H2P2O7-2 0.47652E-15 -15.3219 0.35578E-15 -15.4488 0.74662E+00 -0.1269 88 HP2O7-3 0.30537E-12 -12.5152 0.16157E-12 -12.7916 0.52909E+00 -0.2765 89 P2O7-4 0.26711E-12 -12.5733 0.87782E-13 -13.0566 0.32863E+00 -0.4833 90 H2S,aq 0.52892E-16 -16.2766 0.52863E-16 -16.2768 0.99944E+00 -0.0002 97 SO3-2 0.18495E-14 -14.7330 0.13847E-14 -14.8586 0.74870E+00 -0.1257 98 HSO3- 0.41586E-16 -16.3811 0.38122E-16 -16.4188 0.91670E+00 -0.0378 99 HSO4- 0.88004E-11 -11.0555 0.80718E-11 -11.0930 0.91720E+00 -0.0375 Charge balance for all species = 0.8105E-13 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.4791008E-09 -.2824438E-02 -.2846169E+01 0.0000 2 H2O 0.1000000E+01 0.5550855E+02 0.9997591E+06 0.0000 3 Cl- 0.1379237E-03 0.1380326E-03 0.4892474E+01 5.4587 4 SO4-- 0.2550258E-04 0.2551563E-04 0.2450474E+01 13.9935 5 HCO3- 0.1050370E-04 0.1307553E-04 0.7976375E+00 4.3405 6 HS- 0.4243342E-13 -.3692166E-09 -.1220775E-04 -4.0532 7 Al+++ 0.4551048E-25 0.4216154E-04 0.1137304E+01 2.4521 8 H4SiO4 0.5057874E-03 0.1722566E-02 0.1655247E+03 -3.2960 9 Ca++ 0.1146993E-07 0.1347149E-07 0.5397786E-03 10.6459 10 Mg++ 0.1022375E-09 0.1797802E-09 0.4369750E-05 8.5956 11 Fe++ 0.6030894E-12 0.6546580E-08 0.3655176E-03 6.3665 12 K+ 0.4268390E-04 0.4273462E-04 0.1670601E+01 4.9495 13 Na+ 0.2832013E-02 0.2879756E-02 0.6618885E+02 6.7712 14 Mn++ 0.8102867E-10 0.8639169E-09 0.4745028E-04 8.4948 15 HPO4-- 0.1111794E-04 0.1122027E-04 0.1076647E+01 13.6330 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.3805499E-01 -.2823243E-02 -.3523174E-01 0.0000000E+00 2 H2O 0.5547943E+02 0.5548507E+02 -.5642285E-02 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.8921760E-04 0.2550484E-04 0.6371276E-04 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.6371313E-04 -.3690604E-09 -.6371276E-04 0.0000000E+00 7 Al+++ 0.7496445E-02 0.4214370E-04 0.7454301E-02 0.0000000E+00 8 H4SiO4 0.2393899E-01 0.1721837E-02 0.2221715E-01 0.0000000E+00 9 Ca++ 0.2658649E-02 0.1346579E-07 0.2658636E-02 0.0000000E+00 10 Mg++ 0.1824603E-02 0.1797042E-09 0.1824603E-02 0.0000000E+00 11 Fe++ 0.1639207E-02 0.6543810E-08 0.1639200E-02 0.0000000E+00 12 K+ 0.4881104E-03 0.4271655E-04 0.4453939E-03 0.0000000E+00 13 Na+ 0.3045876E-02 0.2878538E-02 0.1673383E-03 0.0000000E+00 14 Mn++ 0.3986143E-04 0.8635514E-09 0.3986057E-04 0.0000000E+00 15 HPO4-- 0.1360451E-04 0.1121552E-04 0.2388988E-05 0.0000000E+00 Chg. balance for solid moles: -.2101E-17 Mass of aqueous solution: 0.999821E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 2.2990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) apatite-OH 0.7963E-06 -6.099 0.4000E-03 -3.398 0.1620E-01 0.1271E-03 clinochlore 0.3649E-03 -3.438 0.2028 -0.693 8.214 0.7715E-01 daphnite 0.2259E-03 -3.646 0.1612 -0.793 6.527 0.4884E-01 chlorite-Mn 0.7972E-05 -5.098 0.5652E-02 -2.248 0.2289 0.1801E-02 hematite 0.2549E-03 -3.594 0.4070E-01 -1.390 1.648 0.7714E-02 microcline 0.4454E-03 -3.351 0.1240 -0.907 5.020 0.4843E-01 paragonite 0.1673E-03 -3.776 0.6396E-01 -1.194 2.590 0.2211E-01 stilbite 0.2655E-02 -2.576 1.871 0.272 75.76 0.8726 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.6094E+00 0.6094E+00 1.0000 -0.215 daphnite 0.3773E+00 0.3773E+00 1.0000 -0.423 chlorite-Mn 0.1331E-01 0.1331E-01 1.0000 -1.876 hematite 0.1000E+01 0.1000E+01 1.0000 0.000 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 paragonite 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 2.469482 g Volume = 1.078740 cm3 Porosity: 43.8039% V(tot) - V(min): 0.84086E+00 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 2.2990000 g log = 0.3615 Original solution: 1000.0103000 g Original solution / Rock added: 434.98 (Water/Rock Ratio), log = 2.6385 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0203 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.1000E+01 0.9860 0.1006E+01 0.1020E+01 CO2,gas 0.9422E-06 1.0071 0.9682E-06 0.9613E-06 CH4,gas 0.2722E-16 1.0125 0.2812E-16 0.2777E-16 H2,gas 0.7194E-06 1.0005 0.7344E-06 0.7340E-06 H2S,gas 0.1430E-14 0.9960 0.1453E-14 0.1459E-14 S2,gas 0.1440E-36 1.0000 0.1470E-36 0.1470E-36 CO,gas 0.1857E-15 1.0000 0.1895E-15 0.1895E-15 SO3,gas 0.1365E-38 1.0000 0.1392E-38 0.1392E-38 SO2,gas 0.3899E-22 1.0000 0.3979E-22 0.3979E-22 HCl,gas 0.1762E-16 1.0000 0.1798E-16 0.1798E-16 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 32 apatite-OH -18.15 -18.15 0.00 0.000 0.60662E-11 46 clinochlore 39.07 39.07 0.00 0.000 -0.12132E-10 47 daphnite 28.97 28.97 0.00 0.000 -0.12132E-10 48 chlorite-Mn 46.87 46.87 0.00 0.000 -0.12132E-10 90 hematite 12.57 12.57 0.00 0.000 0.30331E-11 116 microcline -2.49 -2.49 0.00 0.000 0.15165E-11 121 paragonite 4.24 4.24 0.00 0.000 0.13649E-10 163 stilbite -7.52 -7.52 0.00 0.000 0.15165E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -14.37 -7.71 -2.571 0.13170E+05 -6.014 3 CH4,gas 4.54 -13.71 -18.25 -4.562 0.31161E+05 -16.551 4 H2,gas 8.00 0.17 -7.83 -4.476 0.13375E+05 -6.134 5 H2S,gas -6.23 -22.77 -16.54 -8.268 0.28236E+05 -14.838 6 S2,gas -7.34 -45.87 -38.53 -5.928 0.65792E+05 -36.833 7 CO,gas 3.21 -14.21 -17.42 -5.360 0.29747E+05 -15.722 8 SO3,gas 17.12 -23.43 -40.56 -10.139 0.69247E+05 -38.856 9 SO2,gas 0.83 -23.27 -24.10 -6.426 0.41149E+05 -22.400 10 HCl,gas 5.19 -13.25 -18.44 -9.222 0.31493E+05 -16.745 11 acmite 7.71 6.46 -1.25 -0.130 0.21301E+04 15 albite-high 0.69 -0.66 -1.36 -0.104 0.23185E+04 16 albite -0.38 -0.66 -0.28 -0.022 0.47972E+03 19 spessartine 24.46 20.50 -3.96 -0.198 0.67562E+04 20 analcite 3.32 2.63 -0.69 -0.077 0.11793E+04 21 andalusite 5.00 1.61 -3.39 -0.339 0.57940E+04 22 andradite 39.01 34.62 -4.39 -0.228 0.75007E+04 26 annite 20.12 16.61 -3.51 -0.195 0.59941E+04 27 phlogopite 27.06 23.30 -3.76 -0.209 0.64274E+04 29 anorthite 12.71 8.96 -3.75 -0.289 0.64068E+04 35 aragonite 0.97 -3.73 -4.69 -1.565 0.80144E+04 36 brucite 12.57 8.60 -3.97 -0.795 0.67837E+04 37 calcite 0.81 -3.73 -4.54 -1.513 0.77502E+04 38 carnegieite-low 9.02 5.93 -3.10 -0.442 0.52864E+04 39 carnegieite-high 10.09 5.93 -4.17 -0.595 0.71134E+04 40 carpholite-Mg 8.58 6.91 -1.67 -0.112 0.28588E+04 41 carpholite-Fe 6.71 4.68 -2.03 -0.136 0.34730E+04 42 celadonite 5.34 2.81 -2.53 -0.149 0.43174E+04 43 celadonite-Fe 3.88 0.58 -3.29 -0.194 0.56220E+04 44 chrysotile 23.89 19.19 -4.70 -0.391 0.80211E+04 50 chloritoid-Mg 13.20 10.20 -2.99 -0.200 0.51120E+04 51 chloritoid-Fe 9.17 7.97 -1.20 -0.080 0.20472E+04 52 chloritoid-Mn 11.40 10.10 -1.30 -0.087 0.22164E+04 54 coesite -2.38 -3.30 -0.92 -0.307 0.15708E+04 59 corundum 8.38 4.90 -3.48 -0.316 0.59401E+04 61 cristobalite -2.56 -3.30 -0.74 -0.245 0.12562E+04 63 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71234E+04 65 diaspore 2.87 2.45 -0.42 -0.070 0.71982E+03 67 diopside 16.18 12.65 -3.53 -0.353 0.60306E+04 68 hedenbergite 14.21 10.42 -3.79 -0.379 0.64678E+04 75 epidote 24.67 22.59 -2.08 -0.101 0.35495E+04 76 clinozoisite 22.81 18.76 -4.05 -0.184 0.69083E+04 77 epidote-Fe 29.84 26.42 -3.42 -0.178 0.58374E+04 78 fayalite 14.05 9.44 -4.61 -0.658 0.78695E+04 83 gibbsite 4.08 2.45 -1.63 -0.232 0.27784E+04 87 greenalite 16.14 12.51 -3.63 -0.303 0.62019E+04 91 heulandite -5.83 -7.52 -1.69 -0.077 0.28938E+04 95 jadeite 4.22 2.63 -1.58 -0.158 0.27047E+04 97 kalsilite 7.58 4.11 -3.48 -0.497 0.59392E+04 98 kaolinite -1.33 -1.69 -0.36 -0.032 0.60623E+03 99 kyanite 4.88 1.61 -3.27 -0.327 0.55799E+04 101 laumontite 2.88 2.37 -0.52 -0.034 0.88339E+03 102 lawsonite 9.62 8.96 -0.66 -0.044 0.11235E+04 103 leucite 4.12 0.81 -3.31 -0.331 0.56506E+04 105 lizardite 23.24 19.19 -4.05 -0.337 0.69138E+04 107 magnetite 20.09 18.93 -1.15 -0.094 0.19717E+04 108 minnesotaite 10.39 5.92 -4.47 -0.263 0.76373E+04 113 margarite 17.32 13.86 -3.46 -0.138 0.59100E+04 120 muscovite 2.58 2.42 -0.16 -0.010 0.28118E+03 122 nepheline 8.34 5.93 -2.41 -0.345 0.41188E+04 134 phlogopite-Na 29.65 25.12 -4.52 -0.251 0.77260E+04 136 prehnite 19.37 16.31 -3.06 -0.180 0.52315E+04 137 prehnite-Fe 22.50 20.14 -2.36 -0.142 0.40277E+04 138 pumpellyite-Fe 46.27 41.43 -4.83 -0.107 0.82554E+04 145 pyroxmangite 7.40 5.20 -2.20 -0.440 0.37563E+04 146 pyrophyllite -6.18 -8.28 -2.10 -0.132 0.35927E+04 147 quartz -2.99 -3.30 -0.31 -0.102 0.52351E+03 151 rhodochrosite -0.98 -5.88 -4.90 -1.634 0.83701E+04 152 rhodonite 7.45 5.20 -2.25 -0.449 0.38366E+04 153 sanidine -1.28 -2.49 -1.21 -0.093 0.20677E+04 156 sillimanite 5.26 1.61 -3.65 -0.365 0.62379E+04 164 stilpnomelane-Fe 13.02 12.84 -0.17 -0.005 0.29702E+03 165 stilpnomelane-Mg 27.44 23.99 -3.45 -0.103 0.58954E+04 168 sudoite 21.08 17.11 -3.97 -0.128 0.67714E+04 171 talc 16.49 12.60 -3.89 -0.229 0.66394E+04 174 tephroite 18.09 13.69 -4.39 -0.627 0.74997E+04 177 topaz-H 4.62 1.61 -3.01 -0.274 0.51400E+04 178 tridymite -2.63 -3.30 -0.67 -0.223 0.11435E+04 187 wairakite 3.95 2.37 -1.58 -0.093 0.27054E+04 188 walstromite 11.51 7.35 -4.16 -0.832 0.71020E+04 189 wollastonite 10.46 7.35 -3.11 -0.622 0.53124E+04 190 pseudo-wollastonite 11.00 7.35 -3.65 -0.730 0.62322E+04 191 zoisite 22.85 18.76 -4.09 -0.186 0.69823E+04 192 akaganeite 7.75 6.28 -1.47 -0.318 0.25125E+04 193 beidellite-Ca -1.65 -4.63 -2.98 -0.184 0.50896E+04 194 beidellite-H -2.33 -6.38 -4.06 -0.259 0.69268E+04 195 beidellite-K -1.52 -4.75 -3.23 -0.198 0.55142E+04 196 beidellite-Mg -1.79 -4.96 -3.17 -0.196 0.54211E+04 197 beidellite-Na -1.34 -4.15 -2.81 -0.172 0.47916E+04 199 chalcedony -2.80 -3.30 -0.49 -0.165 0.84280E+03 201 montmorillonite-Ca -2.29 -4.50 -2.21 -0.136 0.37654E+04 202 montmorillonite-K -2.24 -4.62 -2.38 -0.146 0.40680E+04 203 montmorillonite-Mg -2.48 -4.83 -2.35 -0.146 0.40200E+04 204 montmorillonite-Na -2.04 -4.02 -1.98 -0.121 0.33812E+04 205 nontronite-Ca 3.21 3.04 -0.18 -0.012 0.30567E+03 206 nontronite-H 2.53 1.28 -1.25 -0.084 0.21407E+04 207 nontronite-K 3.34 2.91 -0.43 -0.027 0.73152E+03 208 nontronite-Mg 3.07 2.70 -0.38 -0.024 0.64440E+03 209 nontronite-Na 3.52 3.51 -0.01 0.000 0.10709E+02 224 tobermorite 9.82 5.57 -4.25 -1.160 0.72585E+04 233 boehmite 4.41 2.45 -1.95 -0.326 0.33367E+04 235 ferrous-oxide 9.81 6.37 -3.45 -0.861 0.58825E+04 240 silica-amorphous -2.09 -3.30 -1.20 -0.402 0.20570E+04 242 an20ab80 2.02 1.26 -0.76 -0.058 0.12943E+04 243 an25ab75 2.65 1.74 -0.90 -0.070 0.15449E+04 244 an30ab70 3.28 2.22 -1.06 -0.081 0.18051E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 0.1000000 g Current total amount of reactant added: 2.2990000 g New total amount of reactant added: 2.3990000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.8100E-13 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 7 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 2.3990000 Water: Moles liquid = 0.5548E+02 kg liquid = 0.9996E+00 Moles total = 0.5548E+02 kg total = 0.9995E+00 Activity = 1.0000 Stoichiometric ionic strength = .1861096E-02 Osmotic coef. = 0.9756 True ionic strength = .3028449E-02 Chg. balance for total moles = 0.8100E-13 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.46275E-09 -9.3347 0.42418E-09 -9.3724 0.91666E+00 -0.0378 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13792E-03 -3.8604 0.12628E-03 -3.8987 0.91556E+00 -0.0383 4 SO4-- 0.25503E-04 -4.5934 0.18956E-04 -4.7223 0.74328E+00 -0.1289 5 HCO3- 0.10422E-04 -4.9821 0.95444E-05 -5.0203 0.91582E+00 -0.0382 6 HS- 0.43430E-13 -13.3622 0.39764E-13 -13.4005 0.91559E+00 -0.0383 7 Al+++ 0.39890E-25 -25.3991 0.20870E-25 -25.6805 0.52318E+00 -0.2813 8 H4SiO4 0.51106E-03 -3.2915 0.51106E-03 -3.2915 0.10000E+01 0.0000 9 Ca++ 0.10704E-07 -7.9705 0.79444E-08 -8.0999 0.74221E+00 -0.1295 10 Mg++ 0.96378E-10 -10.0160 0.71468E-10 -10.1459 0.74154E+00 -0.1299 11 Fe++ 0.56852E-12 -12.2453 0.42167E-12 -12.3750 0.74170E+00 -0.1298 12 K+ 0.41396E-04 -4.3830 0.37914E-04 -4.4212 0.91587E+00 -0.0382 13 Na+ 0.29467E-02 -2.5307 0.26978E-02 -2.5690 0.91553E+00 -0.0383 14 Mn++ 0.76383E-10 -10.1170 0.56663E-10 -10.2467 0.74182E+00 -0.1297 15 HPO4-- 0.12050E-04 -4.9190 0.89565E-05 -5.0479 0.74330E+00 -0.1288 16 HSiO3- 0.12287E-02 -2.9105 0.11250E-02 -2.9489 0.91556E+00 -0.0383 17 Ca(HSiO3)+ 0.22222E-09 -9.6532 0.20354E-09 -9.6914 0.91591E+00 -0.0381 18 Mg(HSiO3)+ 0.24879E-11 -11.6042 0.22787E-11 -11.6423 0.91591E+00 -0.0381 19 NaHSiO3,aq 0.49087E-04 -4.3090 0.49087E-04 -4.3090 0.10000E+01 0.0000 20 AlO+ 0.17228E-13 -13.7638 0.15779E-13 -13.8019 0.91591E+00 -0.0381 21 AlOH+2 0.44919E-19 -19.3476 0.33328E-19 -19.4772 0.74196E+00 -0.1296 22 HAlO2,aq 0.74081E-08 -8.1303 0.74081E-08 -8.1303 0.10000E+01 0.0000 23 AlO2- 0.42239E-04 -4.3743 0.38659E-04 -4.4128 0.91523E+00 -0.0385 24 CH4,aq 0.19459E-19 -19.7109 0.19448E-19 -19.7111 0.99942E+00 -0.0003 29 CO,aq 0.12349E-18 -18.9084 0.12349E-18 -18.9084 0.10000E+01 0.0000 30 CO2,aq 0.86558E-08 -8.0627 0.86508E-08 -8.0629 0.99942E+00 -0.0003 31 CO3-2 0.26453E-05 -5.5775 0.19653E-05 -5.7066 0.74296E+00 -0.1290 32 CaCO3,aq 0.19578E-09 -9.7082 0.19578E-09 -9.7082 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.21132E-11 -11.6751 0.19355E-11 -11.7132 0.91591E+00 -0.0381 34 CaCl+ 0.17725E-11 -11.7514 0.16235E-11 -11.7896 0.91591E+00 -0.0381 35 CaCl2,aq 0.48705E-16 -16.3124 0.48705E-16 -16.3124 0.10000E+01 0.0000 36 CaOH+ 0.14573E-08 -8.8364 0.13348E-08 -8.8746 0.91591E+00 -0.0381 37 CaSO4,aq 0.47821E-10 -10.3204 0.47821E-10 -10.3204 0.10000E+01 0.0000 38 HCl,aq 0.98154E-14 -14.0081 0.98154E-14 -14.0081 0.10000E+01 0.0000 43 FeCl+ 0.92018E-16 -16.0361 0.84280E-16 -16.0743 0.91591E+00 -0.0381 46 FeO,aq 0.91081E-10 -10.0406 0.91081E-10 -10.0406 0.10000E+01 0.0000 47 FeOH+ 0.35329E-10 -10.4519 0.32358E-10 -10.4900 0.91591E+00 -0.0381 48 HFeO2- 0.24539E-08 -8.6102 0.22467E-08 -8.6485 0.91556E+00 -0.0383 49 FeO+ 0.35350E-14 -14.4516 0.32378E-14 -14.4898 0.91591E+00 -0.0381 51 FeO2- 0.40216E-08 -8.3956 0.36820E-08 -8.4339 0.91556E+00 -0.0383 52 HFeO2,aq 0.19864E-09 -9.7019 0.19864E-09 -9.7019 0.10000E+01 0.0000 53 H2,aq 0.56856E-09 -9.2452 0.56824E-09 -9.2455 0.99942E+00 -0.0003 54 KCl,aq 0.86771E-10 -10.0616 0.86771E-10 -10.0616 0.10000E+01 0.0000 55 KHSO4,aq 0.86196E-18 -18.0645 0.86196E-18 -18.0645 0.10000E+01 0.0000 56 KOH,aq 0.38171E-07 -7.4183 0.38171E-07 -7.4183 0.10000E+01 0.0000 57 KSO4- 0.12181E-07 -7.9143 0.11152E-07 -7.9526 0.91556E+00 -0.0383 58 MgCO3,aq 0.44145E-12 -12.3551 0.44145E-12 -12.3551 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.19425E-13 -13.7116 0.17791E-13 -13.7498 0.91591E+00 -0.0381 60 MgCl+ 0.14452E-13 -13.8401 0.13237E-13 -13.8782 0.91591E+00 -0.0381 61 MgOH+ 0.72545E-10 -10.1394 0.66445E-10 -10.1775 0.91591E+00 -0.0381 63 MnO,aq 0.32612E-09 -9.4866 0.32612E-09 -9.4866 0.10000E+01 0.0000 64 MnOH+ 0.44102E-09 -9.3555 0.40393E-09 -9.3937 0.91591E+00 -0.0381 65 MnO2-2 0.80962E-13 -13.0917 0.60151E-13 -13.2208 0.74296E+00 -0.1290 66 HMnO2- 0.61055E-11 -11.2143 0.55900E-11 -11.2526 0.91556E+00 -0.0383 69 MnCl+ 0.48106E-13 -13.3178 0.44061E-13 -13.3559 0.91591E+00 -0.0381 70 MnSO4,aq 0.31009E-12 -12.5085 0.31009E-12 -12.5085 0.10000E+01 0.0000 71 NaCl,aq 0.11290E-06 -6.9473 0.11290E-06 -6.9473 0.10000E+01 0.0000 72 NaOH,aq 0.27326E-05 -5.5634 0.27326E-05 -5.5634 0.10000E+01 0.0000 74 OH- 0.14882E-02 -2.8273 0.13621E-02 -2.8658 0.91523E+00 -0.0385 79 HPO3-2 0.21347E-16 -16.6707 0.15860E-16 -16.7997 0.74296E+00 -0.1290 81 H2PO3- 0.14735E-19 -19.8316 0.13491E-19 -19.8700 0.91556E+00 -0.0383 82 H3PO4,aq 0.11271E-13 -13.9480 0.11271E-13 -13.9480 0.10000E+01 0.0000 83 H2PO4- 0.76534E-07 -7.1161 0.70085E-07 -7.1544 0.91573E+00 -0.0382 84 PO4-3 0.32608E-07 -7.4867 0.17227E-07 -7.7638 0.52831E+00 -0.2771 87 H2P2O7-2 0.51839E-15 -15.2853 0.38514E-15 -15.4144 0.74296E+00 -0.1290 88 HP2O7-3 0.34649E-12 -12.4603 0.18130E-12 -12.7416 0.52324E+00 -0.2813 89 P2O7-4 0.31685E-12 -12.4992 0.10211E-12 -12.9910 0.32226E+00 -0.4918 90 H2S,aq 0.52160E-16 -16.2827 0.52130E-16 -16.2829 0.99942E+00 -0.0003 97 SO3-2 0.18786E-14 -14.7262 0.13998E-14 -14.8539 0.74510E+00 -0.1278 98 HSO3- 0.40605E-16 -16.3914 0.37176E-16 -16.4297 0.91556E+00 -0.0383 99 HSO4- 0.84590E-11 -11.0727 0.77491E-11 -11.1107 0.91608E+00 -0.0381 Charge balance for all species = 0.8105E-13 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.4627515E-09 -.2940421E-02 -.2963017E+01 0.0000 2 H2O 0.1000000E+01 0.5550855E+02 0.9997501E+06 0.0000 3 Cl- 0.1379220E-03 0.1380350E-03 0.4892517E+01 5.4738 4 SO4-- 0.2550348E-04 0.2551610E-04 0.2450497E+01 14.0226 5 HCO3- 0.1042164E-04 0.1307576E-04 0.7976446E+00 4.3522 6 HS- 0.4342986E-13 -.3853446E-09 -.1274089E-04 -4.0281 7 Al+++ 0.3988997E-25 0.4224684E-04 0.1139595E+01 2.4369 8 H4SiO4 0.5110569E-03 0.1788869E-02 0.1718944E+03 -3.2915 9 Ca++ 0.1070376E-07 0.1263080E-07 0.5060890E-03 10.6450 10 Mg++ 0.9637763E-10 0.1718858E-09 0.4177830E-05 8.5990 11 Fe++ 0.5685181E-12 0.6801072E-08 0.3797233E-03 6.3699 12 K+ 0.4139649E-04 0.4144693E-04 0.1620248E+01 4.9512 13 Na+ 0.2946720E-02 0.2998653E-02 0.6892098E+02 6.8035 14 Mn++ 0.7638348E-10 0.8500704E-09 0.4668935E-04 8.4982 15 HPO4-- 0.1204969E-04 0.1215883E-04 0.1166697E+01 13.6970 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.3971084E-01 -.2939124E-02 -.3677171E-01 0.0000000E+00 2 H2O 0.5547818E+02 0.5548408E+02 -.5900808E-02 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.9198894E-04 0.2550486E-04 0.6648408E-04 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.6648447E-04 -.3851747E-09 -.6648408E-04 0.0000000E+00 7 Al+++ 0.7822519E-02 0.4222821E-04 0.7780291E-02 0.0000000E+00 8 H4SiO4 0.2498027E-01 0.1788081E-02 0.2319219E-01 0.0000000E+00 9 Ca++ 0.2773663E-02 0.1262523E-07 0.2773651E-02 0.0000000E+00 10 Mg++ 0.1903968E-02 0.1718100E-09 0.1903968E-02 0.0000000E+00 11 Fe++ 0.1710508E-02 0.6798074E-08 0.1710501E-02 0.0000000E+00 12 K+ 0.5093418E-03 0.4142866E-04 0.4679132E-03 0.0000000E+00 13 Na+ 0.3171400E-02 0.2997331E-02 0.1740698E-03 0.0000000E+00 14 Mn++ 0.4159529E-04 0.8496956E-09 0.4159444E-04 0.0000000E+00 15 HPO4-- 0.1419627E-04 0.1215347E-04 0.2042795E-05 0.0000000E+00 Chg. balance for solid moles: 0.2560E-17 Mass of aqueous solution: 0.999812E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 2.3990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) apatite-OH 0.6809E-06 -6.167 0.3420E-03 -3.466 0.1327E-01 0.1087E-03 clinochlore 0.3808E-03 -3.419 0.2117 -0.674 8.211 0.8051E-01 daphnite 0.2357E-03 -3.628 0.1682 -0.774 6.525 0.5097E-01 chlorite-Mn 0.8319E-05 -5.080 0.5898E-02 -2.229 0.2288 0.1879E-02 hematite 0.2659E-03 -3.575 0.4247E-01 -1.372 1.648 0.8050E-02 microcline 0.4679E-03 -3.330 0.1302 -0.885 5.053 0.5087E-01 paragonite 0.1741E-03 -3.759 0.6653E-01 -1.177 2.581 0.2300E-01 stilbite 0.2770E-02 -2.557 1.952 0.291 75.74 0.9106 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.6094E+00 0.6094E+00 1.0000 -0.215 daphnite 0.3773E+00 0.3773E+00 1.0000 -0.423 chlorite-Mn 0.1331E-01 0.1331E-01 1.0000 -1.876 hematite 0.1000E+01 0.1000E+01 1.0000 0.000 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 paragonite 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 2.577575 g Volume = 1.125948 cm3 Porosity: 42.5419% V(tot) - V(min): 0.83365E+00 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 2.3990000 g log = 0.3800 Original solution: 1000.0103000 g Original solution / Rock added: 416.84 (Water/Rock Ratio), log = 2.6200 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0203 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.1000E+01 0.9860 0.1006E+01 0.1020E+01 CO2,gas 0.9007E-06 1.0071 0.9255E-06 0.9190E-06 CH4,gas 0.2771E-16 1.0125 0.2863E-16 0.2827E-16 H2,gas 0.7308E-06 1.0005 0.7460E-06 0.7456E-06 H2S,gas 0.1410E-14 0.9960 0.1433E-14 0.1439E-14 S2,gas 0.1357E-36 1.0000 0.1385E-36 0.1385E-36 CO,gas 0.1804E-15 1.0000 0.1840E-15 0.1840E-15 SO3,gas 0.1264E-38 1.0000 0.1290E-38 0.1290E-38 SO2,gas 0.3669E-22 1.0000 0.3743E-22 0.3743E-22 HCl,gas 0.1697E-16 1.0000 0.1732E-16 0.1732E-16 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 32 apatite-OH -18.15 -18.15 0.00 0.000 -0.60662E-11 46 clinochlore 39.07 39.07 0.00 0.000 -0.48529E-10 47 daphnite 28.97 28.97 0.00 0.000 -0.36397E-10 48 chlorite-Mn 46.87 46.87 0.00 0.000 -0.60662E-10 90 hematite 12.57 12.57 0.00 0.000 0.30331E-11 116 microcline -2.49 -2.49 0.00 0.000 -0.10616E-10 121 paragonite 4.24 4.24 0.00 0.000 0.13649E-10 163 stilbite -7.52 -7.52 0.00 0.000 -0.90992E-11 209 nontronite-Na 3.52 3.54 0.02 0.001 -0.27097E+02 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -14.39 -7.73 -2.578 0.13203E+05 -6.034 3 CH4,gas 4.54 -13.70 -18.24 -4.561 0.31148E+05 -16.543 4 H2,gas 8.00 0.17 -7.83 -4.472 0.13363E+05 -6.127 5 H2S,gas -6.23 -22.77 -16.54 -8.271 0.28246E+05 -14.844 6 S2,gas -7.34 -45.89 -38.56 -5.932 0.65836E+05 -36.859 7 CO,gas 3.21 -14.22 -17.43 -5.364 0.29768E+05 -15.735 8 SO3,gas 17.12 -23.47 -40.59 -10.147 0.69304E+05 -38.890 9 SO2,gas 0.83 -23.29 -24.13 -6.434 0.41194E+05 -22.427 10 HCl,gas 5.19 -13.27 -18.46 -9.230 0.31521E+05 -16.761 11 acmite 7.71 6.50 -1.21 -0.125 0.20596E+04 15 albite-high 0.69 -0.63 -1.33 -0.102 0.22664E+04 16 albite -0.38 -0.63 -0.25 -0.019 0.42757E+03 19 spessartine 24.46 20.49 -3.96 -0.198 0.67678E+04 20 analcite 3.32 2.66 -0.66 -0.074 0.11348E+04 21 andalusite 5.00 1.58 -3.42 -0.342 0.58384E+04 22 andradite 39.01 34.63 -4.38 -0.228 0.74826E+04 26 annite 20.12 16.62 -3.50 -0.194 0.59767E+04 27 phlogopite 27.06 23.31 -3.75 -0.209 0.64100E+04 29 anorthite 12.71 8.94 -3.77 -0.290 0.64452E+04 35 aragonite 0.97 -3.75 -4.71 -1.571 0.80495E+04 36 brucite 12.57 8.60 -3.97 -0.794 0.67779E+04 37 calcite 0.81 -3.75 -4.56 -1.520 0.77853E+04 38 carnegieite-low 9.02 5.95 -3.07 -0.439 0.52496E+04 39 carnegieite-high 10.09 5.95 -4.14 -0.592 0.70766E+04 40 carpholite-Mg 8.58 6.89 -1.69 -0.113 0.28898E+04 41 carpholite-Fe 6.71 4.66 -2.05 -0.137 0.35040E+04 42 celadonite 5.34 2.82 -2.52 -0.148 0.43039E+04 43 celadonite-Fe 3.88 0.59 -3.28 -0.193 0.56085E+04 44 chrysotile 23.89 19.21 -4.68 -0.390 0.79883E+04 50 chloritoid-Mg 13.20 10.18 -3.02 -0.201 0.51506E+04 51 chloritoid-Fe 9.17 7.95 -1.22 -0.081 0.20858E+04 52 chloritoid-Mn 11.40 10.08 -1.32 -0.088 0.22551E+04 54 coesite -2.38 -3.29 -0.92 -0.305 0.15631E+04 59 corundum 8.38 4.87 -3.51 -0.319 0.59922E+04 61 cristobalite -2.56 -3.29 -0.73 -0.244 0.12485E+04 63 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71234E+04 65 diaspore 2.87 2.44 -0.44 -0.073 0.74590E+03 67 diopside 16.18 12.66 -3.52 -0.352 0.60111E+04 68 hedenbergite 14.21 10.43 -3.78 -0.378 0.64483E+04 75 epidote 24.67 22.57 -2.10 -0.102 0.35819E+04 76 clinozoisite 22.81 18.73 -4.08 -0.185 0.69667E+04 77 epidote-Fe 29.84 26.42 -3.42 -0.178 0.58437E+04 78 fayalite 14.05 9.45 -4.60 -0.657 0.78502E+04 79 ferrosilite 11.15 6.16 -4.99 -0.499 0.85250E+04 83 gibbsite 4.08 2.44 -1.64 -0.235 0.28044E+04 87 greenalite 16.14 12.53 -3.61 -0.301 0.61691E+04 91 heulandite -5.83 -7.52 -1.69 -0.077 0.28938E+04 95 jadeite 4.22 2.66 -1.56 -0.156 0.26603E+04 97 kalsilite 7.58 4.10 -3.49 -0.498 0.59545E+04 98 kaolinite -1.33 -1.71 -0.38 -0.034 0.64301E+03 99 kyanite 4.88 1.58 -3.29 -0.329 0.56243E+04 101 laumontite 2.88 2.35 -0.53 -0.035 0.90645E+03 102 lawsonite 9.62 8.94 -0.68 -0.045 0.11619E+04 103 leucite 4.12 0.81 -3.31 -0.331 0.56583E+04 105 lizardite 23.24 19.21 -4.03 -0.336 0.68809E+04 107 magnetite 20.09 18.94 -1.15 -0.094 0.19659E+04 108 minnesotaite 10.39 5.94 -4.44 -0.261 0.75891E+04 113 margarite 17.32 13.81 -3.51 -0.141 0.60006E+04 120 muscovite 2.58 2.39 -0.20 -0.011 0.33333E+03 122 nepheline 8.34 5.95 -2.39 -0.342 0.40820E+04 134 phlogopite-Na 29.65 25.16 -4.48 -0.249 0.76564E+04 136 prehnite 19.37 16.29 -3.08 -0.181 0.52639E+04 137 prehnite-Fe 22.50 20.14 -2.36 -0.142 0.40341E+04 138 pumpellyite-Fe 46.27 41.38 -4.88 -0.109 0.83404E+04 145 pyroxmangite 7.40 5.21 -2.19 -0.438 0.37428E+04 146 pyrophyllite -6.18 -8.29 -2.12 -0.132 0.36141E+04 147 quartz -2.99 -3.29 -0.30 -0.101 0.51582E+03 151 rhodochrosite -0.98 -5.89 -4.92 -1.639 0.83977E+04 152 rhodonite 7.45 5.21 -2.24 -0.448 0.38231E+04 153 sanidine -1.28 -2.49 -1.21 -0.093 0.20677E+04 156 sillimanite 5.26 1.58 -3.68 -0.368 0.62824E+04 164 stilpnomelane-Fe 13.02 12.87 -0.15 -0.004 0.25709E+03 165 stilpnomelane-Mg 27.44 24.01 -3.43 -0.102 0.58555E+04 168 sudoite 21.08 17.07 -4.01 -0.129 0.68410E+04 171 talc 16.49 12.63 -3.86 -0.227 0.65912E+04 174 tephroite 18.09 13.70 -4.38 -0.626 0.74803E+04 177 topaz-H 4.62 1.58 -3.04 -0.276 0.51844E+04 178 tridymite -2.63 -3.29 -0.67 -0.222 0.11358E+04 187 wairakite 3.95 2.35 -1.60 -0.094 0.27284E+04 188 walstromite 11.51 7.35 -4.16 -0.831 0.70959E+04 189 wollastonite 10.46 7.35 -3.11 -0.622 0.53064E+04 190 pseudo-wollastonite 11.00 7.35 -3.65 -0.729 0.62262E+04 191 zoisite 22.85 18.73 -4.12 -0.187 0.70408E+04 192 akaganeite 7.75 6.28 -1.47 -0.318 0.25125E+04 193 beidellite-Ca -1.65 -4.65 -3.00 -0.186 0.51225E+04 194 beidellite-H -2.33 -6.40 -4.08 -0.260 0.69593E+04 195 beidellite-K -1.52 -4.77 -3.25 -0.199 0.55457E+04 196 beidellite-Mg -1.79 -4.98 -3.19 -0.198 0.54527E+04 197 beidellite-Na -1.34 -4.16 -2.81 -0.172 0.48060E+04 199 chalcedony -2.80 -3.29 -0.49 -0.163 0.83512E+03 201 montmorillonite-Ca -2.29 -4.50 -2.21 -0.137 0.37765E+04 202 montmorillonite-K -2.24 -4.62 -2.39 -0.146 0.40779E+04 203 montmorillonite-Mg -2.48 -4.84 -2.36 -0.146 0.40300E+04 204 montmorillonite-Na -2.04 -4.01 -1.98 -0.121 0.33739E+04 205 nontronite-Ca 3.21 3.05 -0.17 -0.011 0.28634E+03 206 nontronite-H 2.53 1.29 -1.24 -0.083 0.21211E+04 207 nontronite-K 3.34 2.92 -0.42 -0.027 0.71093E+03 208 nontronite-Mg 3.07 2.71 -0.37 -0.024 0.62384E+03 224 tobermorite 9.82 5.58 -4.25 -1.159 0.72522E+04 233 boehmite 4.41 2.44 -1.97 -0.328 0.33628E+04 235 ferrous-oxide 9.81 6.37 -3.44 -0.860 0.58766E+04 240 silica-amorphous -2.09 -3.29 -1.20 -0.400 0.20493E+04 242 an20ab80 2.02 1.28 -0.74 -0.057 0.12603E+04 243 an25ab75 2.65 1.76 -0.89 -0.068 0.15154E+04 244 an30ab70 3.28 2.24 -1.04 -0.080 0.17801E+04 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 6 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 2.3990000 Water: Moles liquid = 0.5548E+02 kg liquid = 0.9996E+00 Moles total = 0.5548E+02 kg total = 0.9995E+00 Activity = 1.0000 Stoichiometric ionic strength = .1860863E-02 Osmotic coef. = 0.9756 True ionic strength = .3025746E-02 Chg. balance for total moles = 0.8100E-13 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.46044E-09 -9.3368 0.42208E-09 -9.3746 0.91668E+00 -0.0378 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13792E-03 -3.8604 0.12628E-03 -3.8987 0.91559E+00 -0.0383 4 SO4-- 0.25503E-04 -4.5934 0.18958E-04 -4.7222 0.74336E+00 -0.1288 5 HCO3- 0.10411E-04 -4.9825 0.95352E-05 -5.0207 0.91585E+00 -0.0382 6 HS- 0.44196E-13 -13.3546 0.40466E-13 -13.3929 0.91561E+00 -0.0383 7 Al+++ 0.39676E-25 -25.4015 0.20763E-25 -25.6827 0.52332E+00 -0.2812 8 H4SiO4 0.50536E-03 -3.2964 0.50536E-03 -3.2964 0.10000E+01 0.0000 9 Ca++ 0.11239E-07 -7.9493 0.83425E-08 -8.0787 0.74230E+00 -0.1294 10 Mg++ 0.95678E-10 -10.0192 0.70957E-10 -10.1490 0.74162E+00 -0.1298 11 Fe++ 0.56439E-12 -12.2484 0.41866E-12 -12.3781 0.74179E+00 -0.1297 12 K+ 0.42182E-04 -4.3749 0.38635E-04 -4.4130 0.91590E+00 -0.0382 13 Na+ 0.29442E-02 -2.5310 0.26956E-02 -2.5693 0.91556E+00 -0.0383 14 Mn++ 0.75829E-10 -10.1202 0.56258E-10 -10.2498 0.74191E+00 -0.1297 15 HPO4-- 0.11032E-04 -4.9573 0.82009E-05 -5.0861 0.74338E+00 -0.1288 16 HSiO3- 0.12211E-02 -2.9133 0.11180E-02 -2.9516 0.91559E+00 -0.0383 17 Ca(HSiO3)+ 0.23190E-09 -9.6347 0.21241E-09 -9.6728 0.91593E+00 -0.0381 18 Mg(HSiO3)+ 0.24547E-11 -11.6100 0.22484E-11 -11.6481 0.91593E+00 -0.0381 19 NaHSiO3,aq 0.48742E-04 -4.3121 0.48742E-04 -4.3121 0.10000E+01 0.0000 20 AlO+ 0.17311E-13 -13.7617 0.15856E-13 -13.7998 0.91593E+00 -0.0381 21 AlOH+2 0.44908E-19 -19.3477 0.33324E-19 -19.4772 0.74205E+00 -0.1296 22 HAlO2,aq 0.74812E-08 -8.1260 0.74812E-08 -8.1260 0.10000E+01 0.0000 23 AlO2- 0.42868E-04 -4.3679 0.39235E-04 -4.4063 0.91526E+00 -0.0385 24 CH4,aq 0.19782E-19 -19.7037 0.19771E-19 -19.7040 0.99942E+00 -0.0003 29 CO,aq 0.12344E-18 -18.9085 0.12344E-18 -18.9085 0.10000E+01 0.0000 30 CO2,aq 0.86045E-08 -8.0653 0.85996E-08 -8.0655 0.99942E+00 -0.0003 31 CO3-2 0.26556E-05 -5.5758 0.19733E-05 -5.7048 0.74305E+00 -0.1290 32 CaCO3,aq 0.20641E-09 -9.6853 0.20641E-09 -9.6853 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.22169E-11 -11.6543 0.20305E-11 -11.6924 0.91593E+00 -0.0381 34 CaCl+ 0.18613E-11 -11.7302 0.17049E-11 -11.7683 0.91593E+00 -0.0381 35 CaCl2,aq 0.51148E-16 -16.2912 0.51148E-16 -16.2912 0.10000E+01 0.0000 36 CaOH+ 0.15380E-08 -8.8131 0.14087E-08 -8.8512 0.91593E+00 -0.0381 37 CaSO4,aq 0.50222E-10 -10.2991 0.50222E-10 -10.2991 0.10000E+01 0.0000 38 HCl,aq 0.97669E-14 -14.0102 0.97669E-14 -14.0102 0.10000E+01 0.0000 43 FeCl+ 0.91361E-16 -16.0392 0.83681E-16 -16.0774 0.91593E+00 -0.0381 46 FeO,aq 0.91336E-10 -10.0394 0.91336E-10 -10.0394 0.10000E+01 0.0000 47 FeOH+ 0.35251E-10 -10.4528 0.32287E-10 -10.4910 0.91593E+00 -0.0381 48 HFeO2- 0.24730E-08 -8.6068 0.22642E-08 -8.6451 0.91559E+00 -0.0383 49 FeO+ 0.35173E-14 -14.4538 0.32217E-14 -14.4919 0.91593E+00 -0.0381 51 FeO2- 0.40416E-08 -8.3935 0.37004E-08 -8.4318 0.91559E+00 -0.0383 52 HFeO2,aq 0.19864E-09 -9.7019 0.19864E-09 -9.7019 0.10000E+01 0.0000 53 H2,aq 0.57176E-09 -9.2428 0.57143E-09 -9.2430 0.99942E+00 -0.0003 54 KCl,aq 0.88424E-10 -10.0534 0.88424E-10 -10.0534 0.10000E+01 0.0000 55 KHSO4,aq 0.87407E-18 -18.0585 0.87407E-18 -18.0585 0.10000E+01 0.0000 56 KOH,aq 0.39091E-07 -7.4079 0.39091E-07 -7.4079 0.10000E+01 0.0000 57 KSO4- 0.12414E-07 -7.9061 0.11366E-07 -7.9444 0.91559E+00 -0.0383 58 MgCO3,aq 0.44007E-12 -12.3565 0.44007E-12 -12.3565 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.19267E-13 -13.7152 0.17647E-13 -13.7533 0.91593E+00 -0.0381 60 MgCl+ 0.14349E-13 -13.8432 0.13143E-13 -13.8813 0.91593E+00 -0.0381 61 MgOH+ 0.72385E-10 -10.1404 0.66300E-10 -10.1785 0.91593E+00 -0.0381 63 MnO,aq 0.32704E-09 -9.4854 0.32704E-09 -9.4854 0.10000E+01 0.0000 64 MnOH+ 0.44004E-09 -9.3565 0.40305E-09 -9.3946 0.91593E+00 -0.0381 65 MnO2-2 0.81992E-13 -13.0862 0.60924E-13 -13.2152 0.74305E+00 -0.1290 66 HMnO2- 0.61531E-11 -11.2109 0.56337E-11 -11.2492 0.91559E+00 -0.0383 69 MnCl+ 0.47763E-13 -13.3209 0.43747E-13 -13.3590 0.91593E+00 -0.0381 70 MnSO4,aq 0.30790E-12 -12.5116 0.30790E-12 -12.5116 0.10000E+01 0.0000 71 NaCl,aq 0.11281E-06 -6.9477 0.11281E-06 -6.9477 0.10000E+01 0.0000 72 NaOH,aq 0.27440E-05 -5.5616 0.27440E-05 -5.5616 0.10000E+01 0.0000 74 OH- 0.14956E-02 -2.8252 0.13689E-02 -2.8636 0.91526E+00 -0.0385 79 HPO3-2 0.19654E-16 -16.7065 0.14604E-16 -16.8355 0.74305E+00 -0.1290 81 H2PO3- 0.13500E-19 -19.8697 0.12361E-19 -19.9080 0.91559E+00 -0.0383 82 H3PO4,aq 0.10218E-13 -13.9906 0.10218E-13 -13.9906 0.10000E+01 0.0000 83 H2PO4- 0.69728E-07 -7.1566 0.63854E-07 -7.1948 0.91576E+00 -0.0382 84 PO4-3 0.29999E-07 -7.5229 0.15853E-07 -7.7999 0.52844E+00 -0.2770 87 H2P2O7-2 0.43026E-15 -15.3663 0.31970E-15 -15.4953 0.74305E+00 -0.1290 88 HP2O7-3 0.28898E-12 -12.5391 0.15125E-12 -12.8203 0.52338E+00 -0.2812 89 P2O7-4 0.26552E-12 -12.5759 0.85605E-13 -13.0675 0.32240E+00 -0.4916 90 H2S,aq 0.52818E-16 -16.2772 0.52787E-16 -16.2775 0.99942E+00 -0.0003 97 SO3-2 0.18892E-14 -14.7237 0.14078E-14 -14.8515 0.74518E+00 -0.1277 98 HSO3- 0.40633E-16 -16.3911 0.37203E-16 -16.4294 0.91559E+00 -0.0383 99 HSO4- 0.84176E-11 -11.0748 0.77114E-11 -11.1129 0.91610E+00 -0.0381 Charge balance for all species = 0.8073E-13 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.4604379E-09 -.2942343E-02 -.2964958E+01 0.0000 2 H2O 0.1000000E+01 0.5550856E+02 0.9997515E+06 0.0000 3 Cl- 0.1379221E-03 0.1380350E-03 0.4892522E+01 5.4759 4 SO4-- 0.2550324E-04 0.2551610E-04 0.2450500E+01 14.0270 5 HCO3- 0.1041132E-04 0.1307576E-04 0.7976453E+00 4.3539 6 HS- 0.4419602E-13 -.3870428E-09 -.1279705E-04 -4.0183 7 Al+++ 0.3967563E-25 0.4287579E-04 0.1156562E+01 2.4411 8 H4SiO4 0.5053573E-03 0.1775157E-02 0.1705770E+03 -3.2964 9 Ca++ 0.1123877E-07 0.1326934E-07 0.5316746E-03 10.6705 10 Mg++ 0.9567806E-10 0.1709910E-09 0.4156086E-05 8.6002 11 Fe++ 0.5643915E-12 0.6840323E-08 0.3819153E-03 6.3711 12 K+ 0.4218246E-04 0.4223406E-04 0.1651020E+01 4.9616 13 Na+ 0.2944246E-02 0.2995845E-02 0.6885652E+02 6.8053 14 Mn++ 0.7582906E-10 0.8495011E-09 0.4665814E-04 8.4994 15 HPO4-- 0.1103195E-04 0.1113167E-04 0.1068138E+01 13.6631 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.3971084E-01 -.2941046E-02 -.3676979E-01 0.0000000E+00 2 H2O 0.5547818E+02 0.5548411E+02 -.5933792E-02 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.9198894E-04 0.2550486E-04 0.6648408E-04 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.6648447E-04 -.3868723E-09 -.6648408E-04 0.0000000E+00 7 Al+++ 0.7822519E-02 0.4285690E-04 0.7779662E-02 0.0000000E+00 8 H4SiO4 0.2498027E-01 0.1774375E-02 0.2320589E-01 0.0000000E+00 9 Ca++ 0.2773663E-02 0.1326349E-07 0.2773650E-02 0.0000000E+00 10 Mg++ 0.1903968E-02 0.1709157E-09 0.1903968E-02 0.0000000E+00 11 Fe++ 0.1710508E-02 0.6837309E-08 0.1710501E-02 0.0000000E+00 12 K+ 0.5093418E-03 0.4221545E-04 0.4671264E-03 0.0000000E+00 13 Na+ 0.3171400E-02 0.2994525E-02 0.1768753E-03 0.0000000E+00 14 Mn++ 0.4159529E-04 0.8491269E-09 0.4159444E-04 0.0000000E+00 15 HPO4-- 0.1419627E-04 0.1112677E-04 0.3069496E-05 0.0000000E+00 Chg. balance for solid moles: -.1321E-18 Mass of aqueous solution: 0.999811E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 2.3990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) apatite-OH 0.1023E-05 -5.990 0.5140E-03 -3.289 0.1993E-01 0.1633E-03 clinochlore 0.3808E-03 -3.419 0.2117 -0.674 8.209 0.8051E-01 daphnite 0.2357E-03 -3.628 0.1682 -0.774 6.523 0.5097E-01 chlorite-Mn 0.8319E-05 -5.080 0.5898E-02 -2.229 0.2287 0.1879E-02 hematite 0.2586E-03 -3.587 0.4130E-01 -1.384 1.602 0.7828E-02 microcline 0.4671E-03 -3.331 0.1300 -0.886 5.043 0.5079E-01 paragonite 0.1745E-03 -3.758 0.6668E-01 -1.176 2.586 0.2305E-01 stilbite 0.2769E-02 -2.558 1.951 0.290 75.67 0.9100 nontronite-Na 0.7325E-05 -5.135 0.3115E-02 -2.507 0.1208 0.9678E-03 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.6094E+00 0.6094E+00 1.0000 -0.215 daphnite 0.3773E+00 0.3773E+00 1.0000 -0.423 chlorite-Mn 0.1331E-01 0.1331E-01 1.0000 -1.876 hematite 0.1000E+01 0.1000E+01 1.0000 0.000 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 paragonite 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 nontronite-Na 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 2.578415 g Volume = 1.126152 cm3 Porosity: 42.5315% V(tot) - V(min): 0.83345E+00 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 2.3990000 g log = 0.3800 Original solution: 1000.0103000 g Original solution / Rock added: 416.84 (Water/Rock Ratio), log = 2.6200 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0203 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.1000E+01 0.9860 0.1006E+01 0.1020E+01 CO2,gas 0.8954E-06 1.0071 0.9201E-06 0.9136E-06 CH4,gas 0.2817E-16 1.0125 0.2910E-16 0.2874E-16 H2,gas 0.7349E-06 1.0005 0.7502E-06 0.7498E-06 H2S,gas 0.1428E-14 0.9960 0.1451E-14 0.1457E-14 S2,gas 0.1376E-36 1.0000 0.1404E-36 0.1404E-36 CO,gas 0.1803E-15 1.0000 0.1840E-15 0.1840E-15 SO3,gas 0.1252E-38 1.0000 0.1277E-38 0.1277E-38 SO2,gas 0.3653E-22 1.0000 0.3727E-22 0.3727E-22 HCl,gas 0.1689E-16 1.0000 0.1723E-16 0.1723E-16 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 32 apatite-OH -18.15 -18.15 0.00 0.000 -0.60662E-11 46 clinochlore 39.07 39.07 0.00 0.000 -0.24265E-10 47 daphnite 28.97 28.97 0.00 0.000 -0.18198E-10 48 chlorite-Mn 46.87 46.87 0.00 0.000 -0.24265E-10 90 hematite 12.57 12.57 0.00 0.000 0.90992E-11 116 microcline -2.49 -2.49 0.00 0.000 0.15165E-11 121 paragonite 4.24 4.24 0.00 0.000 0.13649E-10 163 stilbite -7.52 -7.52 0.00 0.000 -0.90992E-11 209 nontronite-Na 3.52 3.52 0.00 0.000 0.14407E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -14.40 -7.74 -2.578 0.13208E+05 -6.036 3 CH4,gas 4.54 -13.69 -18.24 -4.559 0.31136E+05 -16.536 4 H2,gas 8.00 0.18 -7.82 -4.471 0.13359E+05 -6.125 5 H2S,gas -6.23 -22.77 -16.54 -8.269 0.28237E+05 -14.838 6 S2,gas -7.34 -45.89 -38.55 -5.931 0.65826E+05 -36.853 7 CO,gas 3.21 -14.22 -17.43 -5.364 0.29769E+05 -15.735 8 SO3,gas 17.12 -23.47 -40.59 -10.148 0.69311E+05 -38.894 9 SO2,gas 0.83 -23.30 -24.13 -6.434 0.41197E+05 -22.429 10 HCl,gas 5.19 -13.27 -18.46 -9.231 0.31524E+05 -16.764 11 acmite 7.71 6.50 -1.21 -0.126 0.20731E+04 15 albite-high 0.69 -0.64 -1.34 -0.103 0.22810E+04 16 albite -0.38 -0.64 -0.26 -0.020 0.44214E+03 19 spessartine 24.46 20.49 -3.97 -0.198 0.67720E+04 20 analcite 3.32 2.65 -0.67 -0.074 0.11411E+04 21 andalusite 5.00 1.59 -3.42 -0.342 0.58322E+04 22 andradite 39.01 34.69 -4.32 -0.224 0.73767E+04 26 annite 20.12 16.63 -3.50 -0.194 0.59704E+04 27 phlogopite 27.06 23.31 -3.75 -0.208 0.64038E+04 29 anorthite 12.71 8.96 -3.75 -0.288 0.64036E+04 35 aragonite 0.97 -3.72 -4.69 -1.564 0.80102E+04 36 brucite 12.57 8.60 -3.97 -0.794 0.67758E+04 37 calcite 0.81 -3.72 -4.54 -1.512 0.77460E+04 38 carnegieite-low 9.02 5.95 -3.07 -0.439 0.52476E+04 39 carnegieite-high 10.09 5.95 -4.14 -0.592 0.70746E+04 40 carpholite-Mg 8.58 6.89 -1.69 -0.113 0.28898E+04 41 carpholite-Fe 6.71 4.66 -2.05 -0.137 0.35039E+04 42 celadonite 5.34 2.82 -2.52 -0.148 0.43101E+04 43 celadonite-Fe 3.88 0.59 -3.29 -0.193 0.56147E+04 44 chrysotile 23.89 19.21 -4.68 -0.390 0.79987E+04 50 chloritoid-Mg 13.20 10.19 -3.01 -0.201 0.51423E+04 51 chloritoid-Fe 9.17 7.96 -1.22 -0.081 0.20775E+04 52 chloritoid-Mn 11.40 10.09 -1.32 -0.088 0.22467E+04 54 coesite -2.38 -3.30 -0.92 -0.307 0.15715E+04 59 corundum 8.38 4.88 -3.50 -0.318 0.59777E+04 61 cristobalite -2.56 -3.30 -0.74 -0.245 0.12568E+04 63 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71234E+04 65 diaspore 2.87 2.44 -0.43 -0.072 0.73861E+03 67 diopside 16.18 12.68 -3.50 -0.350 0.59820E+04 68 hedenbergite 14.21 10.45 -3.76 -0.376 0.64192E+04 75 epidote 24.67 22.62 -2.05 -0.100 0.35050E+04 76 clinozoisite 22.81 18.78 -4.03 -0.183 0.68825E+04 77 epidote-Fe 29.84 26.46 -3.38 -0.176 0.57741E+04 78 fayalite 14.05 9.45 -4.60 -0.657 0.78543E+04 83 gibbsite 4.08 2.44 -1.64 -0.234 0.27972E+04 87 greenalite 16.14 12.52 -3.62 -0.302 0.61795E+04 91 heulandite -5.83 -7.52 -1.69 -0.077 0.28938E+04 95 jadeite 4.22 2.65 -1.56 -0.156 0.26665E+04 97 kalsilite 7.58 4.11 -3.48 -0.497 0.59379E+04 98 kaolinite -1.33 -1.71 -0.38 -0.034 0.64507E+03 99 kyanite 4.88 1.59 -3.29 -0.329 0.56181E+04 101 laumontite 2.88 2.37 -0.52 -0.034 0.88150E+03 102 lawsonite 9.62 8.96 -0.66 -0.044 0.11203E+04 103 leucite 4.12 0.81 -3.31 -0.331 0.56499E+04 105 lizardite 23.24 19.21 -4.04 -0.336 0.68913E+04 107 magnetite 20.09 18.94 -1.15 -0.094 0.19638E+04 108 minnesotaite 10.39 5.93 -4.46 -0.262 0.76161E+04 113 margarite 17.32 13.84 -3.48 -0.139 0.59444E+04 120 muscovite 2.58 2.40 -0.19 -0.011 0.31876E+03 122 nepheline 8.34 5.95 -2.39 -0.341 0.40799E+04 134 phlogopite-Na 29.65 25.16 -4.49 -0.249 0.76647E+04 136 prehnite 19.37 16.33 -3.04 -0.179 0.51870E+04 137 prehnite-Fe 22.50 20.18 -2.32 -0.140 0.39644E+04 138 pumpellyite-Fe 46.27 41.48 -4.79 -0.106 0.81772E+04 145 pyroxmangite 7.40 5.20 -2.20 -0.439 0.37491E+04 146 pyrophyllite -6.18 -8.30 -2.13 -0.133 0.36328E+04 147 quartz -2.99 -3.30 -0.31 -0.102 0.52414E+03 151 rhodochrosite -0.98 -5.90 -4.92 -1.640 0.84000E+04 152 rhodonite 7.45 5.20 -2.24 -0.449 0.38293E+04 153 sanidine -1.28 -2.49 -1.21 -0.093 0.20677E+04 156 sillimanite 5.26 1.59 -3.68 -0.368 0.62761E+04 164 stilpnomelane-Fe 13.02 12.85 -0.17 -0.005 0.28984E+03 165 stilpnomelane-Mg 27.44 23.99 -3.45 -0.103 0.58882E+04 168 sudoite 21.08 17.08 -4.00 -0.129 0.68327E+04 171 talc 16.49 12.62 -3.88 -0.228 0.66182E+04 174 tephroite 18.09 13.70 -4.38 -0.626 0.74845E+04 177 topaz-H 4.62 1.59 -3.03 -0.276 0.51782E+04 178 tridymite -2.63 -3.30 -0.67 -0.223 0.11441E+04 187 wairakite 3.95 2.37 -1.58 -0.093 0.27035E+04 188 walstromite 11.51 7.37 -4.14 -0.827 0.70606E+04 189 wollastonite 10.46 7.37 -3.09 -0.617 0.52710E+04 190 pseudo-wollastonite 11.00 7.37 -3.63 -0.725 0.61909E+04 191 zoisite 22.85 18.78 -4.07 -0.185 0.69566E+04 192 akaganeite 7.75 6.28 -1.47 -0.318 0.25125E+04 193 beidellite-Ca -1.65 -4.65 -3.00 -0.186 0.51288E+04 194 beidellite-H -2.33 -6.41 -4.08 -0.261 0.69729E+04 195 beidellite-K -1.52 -4.77 -3.25 -0.199 0.55534E+04 196 beidellite-Mg -1.79 -4.99 -3.20 -0.198 0.54659E+04 197 beidellite-Na -1.34 -4.16 -2.82 -0.173 0.48185E+04 199 chalcedony -2.80 -3.30 -0.49 -0.165 0.84343E+03 201 montmorillonite-Ca -2.29 -4.51 -2.22 -0.137 0.37897E+04 202 montmorillonite-K -2.24 -4.63 -2.40 -0.147 0.40925E+04 203 montmorillonite-Mg -2.48 -4.85 -2.37 -0.147 0.40500E+04 204 montmorillonite-Na -2.04 -4.03 -1.99 -0.122 0.33933E+04 205 nontronite-Ca 3.21 3.03 -0.18 -0.012 0.30725E+03 206 nontronite-H 2.53 1.27 -1.26 -0.084 0.21493E+04 207 nontronite-K 3.34 2.91 -0.43 -0.028 0.73322E+03 208 nontronite-Mg 3.07 2.69 -0.38 -0.025 0.65161E+03 224 tobermorite 9.82 5.59 -4.23 -1.154 0.72242E+04 233 boehmite 4.41 2.44 -1.97 -0.328 0.33555E+04 235 ferrous-oxide 9.81 6.37 -3.44 -0.860 0.58746E+04 240 silica-amorphous -2.09 -3.30 -1.21 -0.402 0.20576E+04 242 an20ab80 2.02 1.28 -0.74 -0.057 0.12636E+04 243 an25ab75 2.65 1.76 -0.89 -0.068 0.15159E+04 244 an30ab70 3.28 2.24 -1.04 -0.080 0.17779E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 0.1000000 g Current total amount of reactant added: 2.3990000 g New total amount of reactant added: 2.4990000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.8099E-13 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 6 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 2.4990000 Water: Moles liquid = 0.5548E+02 kg liquid = 0.9995E+00 Moles total = 0.5548E+02 kg total = 0.9994E+00 Activity = 1.0000 Stoichiometric ionic strength = .1921642E-02 Osmotic coef. = 0.9753 True ionic strength = .3136427E-02 Chg. balance for total moles = 0.8099E-13 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.44241E-09 -9.3542 0.40508E-09 -9.3925 0.91564E+00 -0.0383 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13792E-03 -3.8604 0.12613E-03 -3.8992 0.91451E+00 -0.0388 4 SO4-- 0.25504E-04 -4.5934 0.18871E-04 -4.7242 0.73992E+00 -0.1308 5 HCO3- 0.10316E-04 -4.9865 0.94371E-05 -5.0252 0.91478E+00 -0.0387 6 HS- 0.46262E-13 -13.3348 0.42308E-13 -13.3736 0.91453E+00 -0.0388 7 Al+++ 0.34723E-25 -25.4594 0.17981E-25 -25.7452 0.51783E+00 -0.2858 8 H4SiO4 0.50280E-03 -3.2986 0.50280E-03 -3.2986 0.10000E+01 0.0000 9 Ca++ 0.11230E-07 -7.9496 0.82967E-08 -8.0811 0.73882E+00 -0.1315 10 Mg++ 0.89551E-10 -10.0479 0.66100E-10 -10.1798 0.73813E+00 -0.1319 11 Fe++ 0.52824E-12 -12.2772 0.39000E-12 -12.4089 0.73830E+00 -0.1318 12 K+ 0.42009E-04 -4.3767 0.38431E-04 -4.4153 0.91483E+00 -0.0387 13 Na+ 0.30554E-02 -2.5149 0.27941E-02 -2.5538 0.91448E+00 -0.0388 14 Mn++ 0.70972E-10 -10.1489 0.52407E-10 -10.2806 0.73842E+00 -0.1317 15 HPO4-- 0.10589E-04 -4.9751 0.78353E-05 -5.1059 0.73994E+00 -0.1308 16 HSiO3- 0.12673E-02 -2.8971 0.11590E-02 -2.9359 0.91451E+00 -0.0388 17 Ca(HSiO3)+ 0.23936E-09 -9.6209 0.21899E-09 -9.6596 0.91487E+00 -0.0386 18 Mg(HSiO3)+ 0.23733E-11 -11.6246 0.21713E-11 -11.6633 0.91487E+00 -0.0386 19 NaHSiO3,aq 0.52376E-04 -4.2809 0.52376E-04 -4.2809 0.10000E+01 0.0000 20 AlO+ 0.16294E-13 -13.7880 0.14907E-13 -13.8266 0.91487E+00 -0.0386 21 AlOH+2 0.40712E-19 -19.3903 0.30069E-19 -19.5219 0.73857E+00 -0.1316 22 HAlO2,aq 0.73288E-08 -8.1350 0.73288E-08 -8.1350 0.10000E+01 0.0000 23 AlO2- 0.43809E-04 -4.3584 0.40048E-04 -4.3974 0.91416E+00 -0.0390 24 CH4,aq 0.20565E-19 -19.6869 0.20553E-19 -19.6871 0.99941E+00 -0.0003 29 CO,aq 0.11993E-18 -18.9211 0.11993E-18 -18.9211 0.10000E+01 0.0000 30 CO2,aq 0.81733E-08 -8.0876 0.81684E-08 -8.0879 0.99941E+00 -0.0003 31 CO3-2 0.27513E-05 -5.5605 0.20349E-05 -5.6915 0.73959E+00 -0.1310 32 CaCO3,aq 0.21169E-09 -9.6743 0.21169E-09 -9.6743 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.21846E-11 -11.6606 0.19986E-11 -11.6993 0.91487E+00 -0.0386 34 CaCl+ 0.18511E-11 -11.7326 0.16935E-11 -11.7712 0.91487E+00 -0.0386 35 CaCl2,aq 0.50746E-16 -16.2946 0.50746E-16 -16.2946 0.10000E+01 0.0000 36 CaOH+ 0.15955E-08 -8.7971 0.14597E-08 -8.8357 0.91487E+00 -0.0386 37 CaSO4,aq 0.49716E-10 -10.3035 0.49716E-10 -10.3035 0.10000E+01 0.0000 38 HCl,aq 0.93625E-14 -14.0286 0.93625E-14 -14.0286 0.10000E+01 0.0000 43 FeCl+ 0.85106E-16 -16.0700 0.77860E-16 -16.1087 0.91487E+00 -0.0386 46 FeO,aq 0.92372E-10 -10.0345 0.92372E-10 -10.0345 0.10000E+01 0.0000 47 FeOH+ 0.34255E-10 -10.4653 0.31339E-10 -10.5039 0.91487E+00 -0.0386 48 HFeO2- 0.26090E-08 -8.5835 0.23859E-08 -8.6223 0.91451E+00 -0.0388 49 FeO+ 0.33797E-14 -14.4711 0.30920E-14 -14.5098 0.91487E+00 -0.0386 51 FeO2- 0.42161E-08 -8.3751 0.38556E-08 -8.4139 0.91451E+00 -0.0388 52 HFeO2,aq 0.19864E-09 -9.7019 0.19864E-09 -9.7019 0.10000E+01 0.0000 53 H2,aq 0.58481E-09 -9.2330 0.58446E-09 -9.2332 0.99941E+00 -0.0003 54 KCl,aq 0.87853E-10 -10.0562 0.87853E-10 -10.0562 0.10000E+01 0.0000 55 KHSO4,aq 0.83061E-18 -18.0806 0.83061E-18 -18.0806 0.10000E+01 0.0000 56 KOH,aq 0.40516E-07 -7.3924 0.40516E-07 -7.3924 0.10000E+01 0.0000 57 KSO4- 0.12306E-07 -7.9099 0.11254E-07 -7.9487 0.91451E+00 -0.0388 58 MgCO3,aq 0.42274E-12 -12.3739 0.42274E-12 -12.3739 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.17784E-13 -13.7500 0.16270E-13 -13.7886 0.91487E+00 -0.0386 60 MgCl+ 0.13366E-13 -13.8740 0.12229E-13 -13.9126 0.91487E+00 -0.0386 61 MgOH+ 0.70341E-10 -10.1528 0.64352E-10 -10.1914 0.91487E+00 -0.0386 63 MnO,aq 0.33075E-09 -9.4805 0.33075E-09 -9.4805 0.10000E+01 0.0000 64 MnOH+ 0.42762E-09 -9.3689 0.39121E-09 -9.4076 0.91487E+00 -0.0386 65 MnO2-2 0.90446E-13 -13.0436 0.66893E-13 -13.1746 0.73959E+00 -0.1310 66 HMnO2- 0.64916E-11 -11.1877 0.59366E-11 -11.2265 0.91451E+00 -0.0388 69 MnCl+ 0.44492E-13 -13.3517 0.40704E-13 -13.3904 0.91487E+00 -0.0386 70 MnSO4,aq 0.28551E-12 -12.5444 0.28551E-12 -12.5444 0.10000E+01 0.0000 71 NaCl,aq 0.11679E-06 -6.9326 0.11679E-06 -6.9326 0.10000E+01 0.0000 72 NaOH,aq 0.29636E-05 -5.5282 0.29636E-05 -5.5282 0.10000E+01 0.0000 74 OH- 0.15602E-02 -2.8068 0.14263E-02 -2.8458 0.91416E+00 -0.0390 79 HPO3-2 0.19296E-16 -16.7145 0.14271E-16 -16.8455 0.73959E+00 -0.1310 81 H2PO3- 0.12676E-19 -19.8970 0.11593E-19 -19.9358 0.91451E+00 -0.0388 82 H3PO4,aq 0.89922E-14 -14.0461 0.89922E-14 -14.0461 0.10000E+01 0.0000 83 H2PO4- 0.64012E-07 -7.1937 0.58551E-07 -7.2325 0.91468E+00 -0.0387 84 PO4-3 0.30171E-07 -7.5204 0.15781E-07 -7.8019 0.52307E+00 -0.2814 87 H2P2O7-2 0.36345E-15 -15.4396 0.26881E-15 -15.5706 0.73959E+00 -0.1310 88 HP2O7-3 0.25585E-12 -12.5920 0.13250E-12 -12.8778 0.51790E+00 -0.2858 89 P2O7-4 0.24691E-12 -12.6075 0.78142E-13 -13.1071 0.31648E+00 -0.4997 90 H2S,aq 0.53000E-16 -16.2757 0.52968E-16 -16.2760 0.99941E+00 -0.0003 97 SO3-2 0.19321E-14 -14.7140 0.14332E-14 -14.8437 0.74179E+00 -0.1297 98 HSO3- 0.39750E-16 -16.4007 0.36352E-16 -16.4395 0.91451E+00 -0.0388 99 HSO4- 0.80508E-11 -11.0942 0.73668E-11 -11.1327 0.91504E+00 -0.0386 Charge balance for all species = 0.9245E-13 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.4424059E-09 -.3060943E-02 -.3084447E+01 0.0000 2 H2O 0.1000000E+01 0.5550858E+02 0.9997445E+06 0.0000 3 Cl- 0.1379205E-03 0.1380374E-03 0.4892571E+01 5.4933 4 SO4-- 0.2550379E-04 0.2551656E-04 0.2450526E+01 14.0607 5 HCO3- 0.1031627E-04 0.1307599E-04 0.7976533E+00 4.3673 6 HS- 0.4626239E-13 -.4055911E-09 -.1341023E-04 -3.9811 7 Al+++ 0.3472311E-25 0.4381583E-04 0.1181910E+01 2.4322 8 H4SiO4 0.5028013E-03 0.1822517E-02 0.1751266E+03 -3.2986 9 Ca++ 0.1122958E-07 0.1332992E-07 0.5340980E-03 10.7038 10 Mg++ 0.8955070E-10 0.1627185E-09 0.3954986E-05 8.6051 11 Fe++ 0.5282433E-12 0.7150881E-08 0.3992517E-03 6.3760 12 K+ 0.4200905E-04 0.4206196E-04 0.1644280E+01 4.9771 13 Na+ 0.3055446E-02 0.3110903E-02 0.7150049E+02 6.8387 14 Mn++ 0.7097205E-10 0.8362496E-09 0.4592997E-04 8.5043 15 HPO4-- 0.1058915E-04 0.1068333E-04 0.1025109E+01 13.6790 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.4136669E-01 -.3059541E-02 -.3830715E-01 0.0000000E+00 2 H2O 0.5547692E+02 0.5548316E+02 -.6237561E-02 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.9476028E-04 0.2550488E-04 0.6925540E-04 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.6925581E-04 -.4054054E-09 -.6925540E-04 0.0000000E+00 7 Al+++ 0.8148593E-02 0.4379577E-04 0.8104798E-02 0.0000000E+00 8 H4SiO4 0.2602154E-01 0.1821683E-02 0.2419986E-01 0.0000000E+00 9 Ca++ 0.2888678E-02 0.1332382E-07 0.2888664E-02 0.0000000E+00 10 Mg++ 0.1983333E-02 0.1626440E-09 0.1983333E-02 0.0000000E+00 11 Fe++ 0.1781808E-02 0.7147606E-08 0.1781801E-02 0.0000000E+00 12 K+ 0.5305732E-03 0.4204270E-04 0.4885305E-03 0.0000000E+00 13 Na+ 0.3296925E-02 0.3109478E-02 0.1874464E-03 0.0000000E+00 14 Mn++ 0.4332915E-04 0.8358666E-09 0.4332832E-04 0.0000000E+00 15 HPO4-- 0.1478802E-04 0.1067844E-04 0.4109587E-05 0.0000000E+00 Chg. balance for solid moles: -.1540E-17 Mass of aqueous solution: 0.999801E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 2.4990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) apatite-OH 0.1370E-05 -5.863 0.6881E-03 -3.162 0.2560E-01 0.2187E-03 clinochlore 0.3967E-03 -3.402 0.2205 -0.657 8.203 0.8386E-01 daphnite 0.2456E-03 -3.610 0.1752 -0.756 6.519 0.5309E-01 chlorite-Mn 0.8666E-05 -5.062 0.6144E-02 -2.212 0.2286 0.1958E-02 hematite 0.2596E-03 -3.586 0.4146E-01 -1.382 1.543 0.7859E-02 microcline 0.4885E-03 -3.311 0.1360 -0.867 5.059 0.5312E-01 paragonite 0.1817E-03 -3.741 0.6945E-01 -1.158 2.584 0.2401E-01 stilbite 0.2882E-02 -2.540 2.031 0.308 75.56 0.9472 nontronite-Na 0.1738E-04 -4.760 0.7390E-02 -2.131 0.2750 0.2296E-02 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.6094E+00 0.6094E+00 1.0000 -0.215 daphnite 0.3773E+00 0.3773E+00 1.0000 -0.423 chlorite-Mn 0.1331E-01 0.1331E-01 1.0000 -1.876 hematite 0.1000E+01 0.1000E+01 1.0000 0.000 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 paragonite 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 nontronite-Na 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 2.687670 g Volume = 1.173646 cm3 Porosity: 41.3060% V(tot) - V(min): 0.82595E+00 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 2.4990000 g log = 0.3978 Original solution: 1000.0103000 g Original solution / Rock added: 400.16 (Water/Rock Ratio), log = 2.6022 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0203 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.1000E+01 0.9860 0.1006E+01 0.1020E+01 CO2,gas 0.8505E-06 1.0071 0.8739E-06 0.8678E-06 CH4,gas 0.2928E-16 1.0125 0.3025E-16 0.2988E-16 H2,gas 0.7517E-06 1.0005 0.7673E-06 0.7669E-06 H2S,gas 0.1433E-14 0.9960 0.1456E-14 0.1462E-14 S2,gas 0.1325E-36 1.0000 0.1352E-36 0.1352E-36 CO,gas 0.1752E-15 1.0000 0.1787E-15 0.1787E-15 SO3,gas 0.1148E-38 1.0000 0.1171E-38 0.1171E-38 SO2,gas 0.3426E-22 1.0000 0.3495E-22 0.3495E-22 HCl,gas 0.1619E-16 1.0000 0.1652E-16 0.1652E-16 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 32 apatite-OH -18.15 -18.15 0.00 0.000 0.12132E-10 46 clinochlore 39.07 39.07 0.00 0.000 0.12132E-10 47 daphnite 28.97 28.97 0.00 0.000 0.00000E+00 48 chlorite-Mn 46.87 46.87 0.00 0.000 -0.12132E-10 90 hematite 12.57 12.57 0.00 0.000 -0.15165E-10 116 microcline -2.49 -2.49 0.00 0.000 0.15165E-11 121 paragonite 4.24 4.24 0.00 0.000 -0.10616E-10 163 stilbite -7.52 -7.52 0.00 0.000 -0.90992E-11 209 nontronite-Na 3.52 3.52 0.00 0.000 -0.98575E-11 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -14.42 -7.76 -2.586 0.13246E+05 -6.059 3 CH4,gas 4.54 -13.67 -18.22 -4.555 0.31107E+05 -16.519 4 H2,gas 8.00 0.19 -7.81 -4.465 0.13342E+05 -6.115 5 H2S,gas -6.23 -22.77 -16.54 -8.268 0.28234E+05 -14.837 6 S2,gas -7.34 -45.90 -38.57 -5.934 0.65854E+05 -36.869 7 CO,gas 3.21 -14.23 -17.45 -5.368 0.29790E+05 -15.748 8 SO3,gas 17.12 -23.51 -40.63 -10.158 0.69375E+05 -38.932 9 SO2,gas 0.83 -23.32 -24.16 -6.441 0.41245E+05 -22.457 10 HCl,gas 5.19 -13.29 -18.48 -9.240 0.31556E+05 -16.782 11 acmite 7.71 6.52 -1.19 -0.123 0.20236E+04 15 albite-high 0.69 -0.62 -1.32 -0.101 0.22504E+04 16 albite -0.38 -0.62 -0.24 -0.019 0.41160E+03 19 spessartine 24.46 20.48 -3.98 -0.199 0.67887E+04 20 analcite 3.32 2.67 -0.65 -0.072 0.11068E+04 21 andalusite 5.00 1.57 -3.44 -0.344 0.58665E+04 22 andradite 39.01 34.78 -4.23 -0.220 0.72174E+04 26 annite 20.12 16.64 -3.48 -0.193 0.59453E+04 27 phlogopite 27.06 23.33 -3.74 -0.208 0.63787E+04 29 anorthite 12.71 8.97 -3.74 -0.288 0.63848E+04 35 aragonite 0.97 -3.71 -4.68 -1.560 0.79915E+04 36 brucite 12.57 8.61 -3.96 -0.793 0.67675E+04 37 calcite 0.81 -3.71 -4.53 -1.509 0.77273E+04 38 carnegieite-low 9.02 5.97 -3.05 -0.436 0.52095E+04 39 carnegieite-high 10.09 5.97 -4.12 -0.589 0.70365E+04 40 carpholite-Mg 8.58 6.87 -1.71 -0.114 0.29195E+04 41 carpholite-Fe 6.71 4.64 -2.07 -0.138 0.35336E+04 42 celadonite 5.34 2.82 -2.52 -0.148 0.43055E+04 43 celadonite-Fe 3.88 0.59 -3.29 -0.193 0.56101E+04 44 chrysotile 23.89 19.22 -4.67 -0.390 0.79812E+04 50 chloritoid-Mg 13.20 10.17 -3.03 -0.202 0.51682E+04 51 chloritoid-Fe 9.17 7.94 -1.23 -0.082 0.21034E+04 52 chloritoid-Mn 11.40 10.07 -1.33 -0.089 0.22727E+04 54 coesite -2.38 -3.30 -0.92 -0.308 0.15752E+04 59 corundum 8.38 4.86 -3.52 -0.320 0.60082E+04 61 cristobalite -2.56 -3.30 -0.74 -0.246 0.12606E+04 63 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71234E+04 65 diaspore 2.87 2.43 -0.44 -0.074 0.75388E+03 67 diopside 16.18 12.71 -3.47 -0.347 0.59243E+04 68 hedenbergite 14.21 10.48 -3.73 -0.373 0.63615E+04 75 epidote 24.67 22.66 -2.01 -0.097 0.34331E+04 76 clinozoisite 22.81 18.81 -4.00 -0.182 0.68259E+04 77 epidote-Fe 29.84 26.51 -3.33 -0.173 0.56869E+04 78 fayalite 14.05 9.45 -4.59 -0.656 0.78414E+04 79 ferrosilite 11.15 6.15 -4.99 -0.499 0.85283E+04 83 gibbsite 4.08 2.43 -1.65 -0.235 0.28124E+04 87 greenalite 16.14 12.53 -3.61 -0.301 0.61619E+04 91 heulandite -5.83 -7.52 -1.69 -0.077 0.28938E+04 95 jadeite 4.22 2.67 -1.54 -0.154 0.26322E+04 97 kalsilite 7.58 4.11 -3.47 -0.496 0.59304E+04 98 kaolinite -1.33 -1.73 -0.40 -0.036 0.68313E+03 99 kyanite 4.88 1.57 -3.31 -0.331 0.56524E+04 101 laumontite 2.88 2.37 -0.51 -0.034 0.87022E+03 102 lawsonite 9.62 8.97 -0.65 -0.043 0.11015E+04 103 leucite 4.12 0.81 -3.31 -0.331 0.56462E+04 105 lizardite 23.24 19.22 -4.03 -0.335 0.68738E+04 107 magnetite 20.09 18.94 -1.15 -0.093 0.19555E+04 108 minnesotaite 10.39 5.93 -4.45 -0.262 0.76061E+04 113 margarite 17.32 13.84 -3.49 -0.140 0.59562E+04 120 muscovite 2.58 2.38 -0.20 -0.012 0.34929E+03 122 nepheline 8.34 5.97 -2.37 -0.338 0.40419E+04 134 phlogopite-Na 29.65 25.19 -4.46 -0.248 0.76091E+04 136 prehnite 19.37 16.38 -3.00 -0.176 0.51151E+04 137 prehnite-Fe 22.50 20.23 -2.27 -0.137 0.38773E+04 138 pumpellyite-Fe 46.27 41.56 -4.71 -0.105 0.80403E+04 145 pyroxmangite 7.40 5.21 -2.19 -0.439 0.37445E+04 146 pyrophyllite -6.18 -8.33 -2.15 -0.135 0.36783E+04 147 quartz -2.99 -3.30 -0.31 -0.103 0.52790E+03 151 rhodochrosite -0.98 -5.91 -4.94 -1.646 0.84298E+04 152 rhodonite 7.45 5.21 -2.24 -0.448 0.38247E+04 153 sanidine -1.28 -2.49 -1.21 -0.093 0.20677E+04 156 sillimanite 5.26 1.57 -3.70 -0.370 0.63104E+04 164 stilpnomelane-Fe 13.02 12.84 -0.17 -0.005 0.29536E+03 165 stilpnomelane-Mg 27.44 23.99 -3.45 -0.103 0.58937E+04 168 sudoite 21.08 17.04 -4.03 -0.130 0.68883E+04 171 talc 16.49 12.62 -3.87 -0.228 0.66082E+04 174 tephroite 18.09 13.71 -4.38 -0.625 0.74715E+04 177 topaz-H 4.62 1.57 -3.05 -0.278 0.52125E+04 178 tridymite -2.63 -3.30 -0.67 -0.224 0.11479E+04 187 wairakite 3.95 2.37 -1.58 -0.093 0.26922E+04 188 walstromite 11.51 7.41 -4.10 -0.821 0.70075E+04 189 wollastonite 10.46 7.41 -3.06 -0.611 0.52179E+04 190 pseudo-wollastonite 11.00 7.41 -3.59 -0.719 0.61378E+04 191 zoisite 22.85 18.81 -4.04 -0.184 0.69000E+04 192 akaganeite 7.75 6.28 -1.47 -0.318 0.25125E+04 193 beidellite-Ca -1.65 -4.67 -3.03 -0.187 0.51688E+04 194 beidellite-H -2.33 -6.44 -4.11 -0.262 0.70223E+04 195 beidellite-K -1.52 -4.80 -3.28 -0.201 0.55940E+04 196 beidellite-Mg -1.79 -5.02 -3.23 -0.200 0.55139E+04 197 beidellite-Na -1.34 -4.18 -2.84 -0.174 0.48490E+04 199 chalcedony -2.80 -3.30 -0.50 -0.165 0.84719E+03 201 montmorillonite-Ca -2.29 -4.53 -2.24 -0.138 0.38181E+04 202 montmorillonite-K -2.24 -4.65 -2.41 -0.148 0.41215E+04 203 montmorillonite-Mg -2.48 -4.87 -2.39 -0.148 0.40864E+04 204 montmorillonite-Na -2.04 -4.04 -2.00 -0.122 0.34122E+04 205 nontronite-Ca 3.21 3.03 -0.19 -0.012 0.31671E+03 206 nontronite-H 2.53 1.26 -1.27 -0.085 0.21681E+04 207 nontronite-K 3.34 2.91 -0.44 -0.028 0.74329E+03 208 nontronite-Mg 3.07 2.68 -0.39 -0.025 0.66907E+03 224 tobermorite 9.82 5.62 -4.21 -1.147 0.71806E+04 233 boehmite 4.41 2.43 -1.97 -0.329 0.33708E+04 235 ferrous-oxide 9.81 6.38 -3.44 -0.859 0.58662E+04 240 silica-amorphous -2.09 -3.30 -1.21 -0.402 0.20614E+04 242 an20ab80 2.02 1.29 -0.72 -0.056 0.12354E+04 243 an25ab75 2.65 1.77 -0.87 -0.067 0.14883E+04 244 an30ab70 3.28 2.25 -1.03 -0.079 0.17509E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 0.1000000 g Current total amount of reactant added: 2.4990000 g New total amount of reactant added: 2.5990000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.8099E-13 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 6 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 2.5990000 Water: Moles liquid = 0.5548E+02 kg liquid = 0.9995E+00 Moles total = 0.5548E+02 kg total = 0.9994E+00 Activity = 1.0000 Stoichiometric ionic strength = .1982437E-02 Osmotic coef. = 0.9749 True ionic strength = .3247081E-02 Chg. balance for total moles = 0.8099E-13 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.42577E-09 -9.3708 0.38941E-09 -9.4096 0.91461E+00 -0.0388 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13792E-03 -3.8604 0.12598E-03 -3.8997 0.91345E+00 -0.0393 4 SO4-- 0.25504E-04 -4.5934 0.18785E-04 -4.7262 0.73656E+00 -0.1328 5 HCO3- 0.10222E-04 -4.9904 0.93406E-05 -5.0296 0.91373E+00 -0.0392 6 HS- 0.48340E-13 -13.3157 0.44157E-13 -13.3550 0.91348E+00 -0.0393 7 Al+++ 0.30557E-25 -25.5149 0.15661E-25 -25.8052 0.51252E+00 -0.2903 8 H4SiO4 0.50036E-03 -3.3007 0.50036E-03 -3.3007 0.10000E+01 0.0000 9 Ca++ 0.11223E-07 -7.9499 0.82538E-08 -8.0833 0.73543E+00 -0.1335 10 Mg++ 0.84047E-10 -10.0755 0.61752E-10 -10.2094 0.73473E+00 -0.1339 11 Fe++ 0.49578E-12 -12.3047 0.36434E-12 -12.4385 0.73489E+00 -0.1338 12 K+ 0.41846E-04 -4.3783 0.38238E-04 -4.4175 0.91378E+00 -0.0392 13 Na+ 0.31666E-02 -2.4994 0.28924E-02 -2.5387 0.91342E+00 -0.0393 14 Mn++ 0.66610E-10 -10.1765 0.48960E-10 -10.3102 0.73502E+00 -0.1337 15 HPO4-- 0.10180E-04 -4.9923 0.74983E-05 -5.1250 0.73658E+00 -0.1328 16 HSiO3- 0.13134E-02 -2.8816 0.11998E-02 -2.9209 0.91345E+00 -0.0393 17 Ca(HSiO3)+ 0.24679E-09 -9.6077 0.22552E-09 -9.6468 0.91382E+00 -0.0391 18 Mg(HSiO3)+ 0.22978E-11 -11.6387 0.20998E-11 -11.6778 0.91382E+00 -0.0391 19 NaHSiO3,aq 0.56126E-04 -4.2508 0.56126E-04 -4.2508 0.10000E+01 0.0000 20 AlO+ 0.15375E-13 -13.8132 0.14050E-13 -13.8523 0.91382E+00 -0.0391 21 AlOH+2 0.37057E-19 -19.4311 0.27243E-19 -19.5647 0.73517E+00 -0.1336 22 HAlO2,aq 0.71851E-08 -8.1436 0.71851E-08 -8.1436 0.10000E+01 0.0000 23 AlO2- 0.44730E-04 -4.3494 0.40843E-04 -4.3889 0.91310E+00 -0.0395 24 CH4,aq 0.21341E-19 -19.6708 0.21328E-19 -19.6711 0.99939E+00 -0.0003 29 CO,aq 0.11661E-18 -18.9332 0.11661E-18 -18.9332 0.10000E+01 0.0000 30 CO2,aq 0.77769E-08 -8.1092 0.77722E-08 -8.1095 0.99939E+00 -0.0003 31 CO3-2 0.28457E-05 -5.5458 0.20951E-05 -5.6788 0.73623E+00 -0.1330 32 CaCO3,aq 0.21683E-09 -9.6639 0.21683E-09 -9.6639 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.21535E-11 -11.6668 0.19679E-11 -11.7060 0.91382E+00 -0.0391 34 CaCl+ 0.18415E-11 -11.7348 0.16828E-11 -11.7740 0.91382E+00 -0.0391 35 CaCl2,aq 0.50366E-16 -16.2979 0.50366E-16 -16.2979 0.10000E+01 0.0000 36 CaOH+ 0.16531E-08 -8.7817 0.15106E-08 -8.8209 0.91382E+00 -0.0391 37 CaSO4,aq 0.49236E-10 -10.3077 0.49236E-10 -10.3077 0.10000E+01 0.0000 38 HCl,aq 0.89899E-14 -14.0462 0.89899E-14 -14.0462 0.10000E+01 0.0000 43 FeCl+ 0.79505E-16 -16.0996 0.72653E-16 -16.1387 0.91382E+00 -0.0391 46 FeO,aq 0.93380E-10 -10.0297 0.93380E-10 -10.0297 0.10000E+01 0.0000 47 FeOH+ 0.33328E-10 -10.4772 0.30455E-10 -10.5163 0.91382E+00 -0.0391 48 HFeO2- 0.27467E-08 -8.5612 0.25090E-08 -8.6005 0.91345E+00 -0.0393 49 FeO+ 0.32527E-14 -14.4878 0.29724E-14 -14.5269 0.91382E+00 -0.0391 51 FeO2- 0.43908E-08 -8.3575 0.40108E-08 -8.3968 0.91345E+00 -0.0393 52 HFeO2,aq 0.19864E-09 -9.7019 0.19864E-09 -9.7019 0.10000E+01 0.0000 53 H2,aq 0.59764E-09 -9.2236 0.59728E-09 -9.2238 0.99939E+00 -0.0003 54 KCl,aq 0.87310E-10 -10.0589 0.87310E-10 -10.0589 0.10000E+01 0.0000 55 KHSO4,aq 0.79089E-18 -18.1019 0.79089E-18 -18.1019 0.10000E+01 0.0000 56 KOH,aq 0.41935E-07 -7.3774 0.41935E-07 -7.3774 0.10000E+01 0.0000 57 KSO4- 0.12203E-07 -7.9135 0.11147E-07 -7.9529 0.91345E+00 -0.0393 58 MgCO3,aq 0.40662E-12 -12.3908 0.40662E-12 -12.3908 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.16463E-13 -13.7835 0.15045E-13 -13.8226 0.91382E+00 -0.0391 60 MgCl+ 0.12487E-13 -13.9035 0.11411E-13 -13.9427 0.91382E+00 -0.0391 61 MgOH+ 0.68435E-10 -10.1647 0.62538E-10 -10.2039 0.91382E+00 -0.0391 63 MnO,aq 0.33435E-09 -9.4758 0.33435E-09 -9.4758 0.10000E+01 0.0000 64 MnOH+ 0.41604E-09 -9.3809 0.38018E-09 -9.4200 0.91382E+00 -0.0391 65 MnO2-2 0.99390E-13 -13.0027 0.73173E-13 -13.1356 0.73623E+00 -0.1330 66 HMnO2- 0.68343E-11 -11.1653 0.62428E-11 -11.2046 0.91345E+00 -0.0393 69 MnCl+ 0.41564E-13 -13.3813 0.37982E-13 -13.4204 0.91382E+00 -0.0391 70 MnSO4,aq 0.26552E-12 -12.5759 0.26552E-12 -12.5759 0.10000E+01 0.0000 71 NaCl,aq 0.12076E-06 -6.9181 0.12076E-06 -6.9181 0.10000E+01 0.0000 72 NaOH,aq 0.31913E-05 -5.4960 0.31913E-05 -5.4960 0.10000E+01 0.0000 74 OH- 0.16249E-02 -2.7892 0.14837E-02 -2.8287 0.91310E+00 -0.0395 79 HPO3-2 0.18957E-16 -16.7222 0.13957E-16 -16.8552 0.73623E+00 -0.1330 81 H2PO3- 0.11931E-19 -19.9233 0.10899E-19 -19.9626 0.91345E+00 -0.0393 82 H3PO4,aq 0.79526E-14 -14.0995 0.79526E-14 -14.0995 0.10000E+01 0.0000 83 H2PO4- 0.58957E-07 -7.2295 0.53865E-07 -7.2687 0.91363E+00 -0.0392 84 PO4-3 0.30336E-07 -7.5180 0.15710E-07 -7.8038 0.51787E+00 -0.2858 87 H2P2O7-2 0.30901E-15 -15.5100 0.22750E-15 -15.6430 0.73623E+00 -0.1330 88 HP2O7-3 0.22758E-12 -12.6429 0.11665E-12 -12.9331 0.51258E+00 -0.2902 89 P2O7-4 0.23027E-12 -12.6378 0.71564E-13 -13.1453 0.31078E+00 -0.5075 90 H2S,aq 0.53178E-16 -16.2743 0.53145E-16 -16.2745 0.99939E+00 -0.0003 97 SO3-2 0.19744E-14 -14.7046 0.14580E-14 -14.8362 0.73848E+00 -0.1317 98 HSO3- 0.38919E-16 -16.4098 0.35550E-16 -16.4492 0.91345E+00 -0.0393 99 HSO4- 0.77133E-11 -11.1128 0.70499E-11 -11.1518 0.91400E+00 -0.0391 Charge balance for all species = 0.9187E-13 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.4257699E-09 -.3179483E-02 -.3203874E+01 0.0000 2 H2O 0.1000000E+01 0.5550860E+02 0.9997374E+06 0.0000 3 Cl- 0.1379189E-03 0.1380398E-03 0.4892620E+01 5.5099 4 SO4-- 0.2550434E-04 0.2551702E-04 0.2450553E+01 14.0930 5 HCO3- 0.1022250E-04 0.1307622E-04 0.7976613E+00 4.3800 6 HS- 0.4834008E-13 -.4242201E-09 -.1402607E-04 -3.9454 7 Al+++ 0.3055682E-25 0.4473735E-04 0.1206759E+01 2.4236 8 H4SiO4 0.5003560E-03 0.1869921E-02 0.1796803E+03 -3.3007 9 Ca++ 0.1122307E-07 0.1339297E-07 0.5366205E-03 10.7358 10 Mg++ 0.8404736E-10 0.1552161E-09 0.3772609E-05 8.6098 11 Fe++ 0.4957765E-12 0.7463381E-08 0.4166963E-03 6.3807 12 K+ 0.4184642E-04 0.4190064E-04 0.1637962E+01 4.9921 13 Na+ 0.3166577E-02 0.3226015E-02 0.7414566E+02 6.8708 14 Mn++ 0.6660968E-10 0.8242408E-09 0.4527007E-04 8.5090 15 HPO4-- 0.1017981E-04 0.1026910E-04 0.9853552E+00 13.6941 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.4302254E-01 -.3177972E-02 -.3984457E-01 0.0000000E+00 2 H2O 0.5547567E+02 0.5548221E+02 -.6540920E-02 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.9753162E-04 0.2550489E-04 0.7202673E-04 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.7202715E-04 -.4240184E-09 -.7202673E-04 0.0000000E+00 7 Al+++ 0.8474667E-02 0.4471608E-04 0.8429951E-02 0.0000000E+00 8 H4SiO4 0.2706282E-01 0.1869032E-02 0.2519379E-01 0.0000000E+00 9 Ca++ 0.3003692E-02 0.1338661E-07 0.3003678E-02 0.0000000E+00 10 Mg++ 0.2062698E-02 0.1551424E-09 0.2062698E-02 0.0000000E+00 11 Fe++ 0.1853109E-02 0.7459833E-08 0.1853102E-02 0.0000000E+00 12 K+ 0.5518047E-03 0.4188073E-04 0.5099239E-03 0.0000000E+00 13 Na+ 0.3422449E-02 0.3224481E-02 0.1979681E-03 0.0000000E+00 14 Mn++ 0.4506301E-04 0.8238490E-09 0.4506219E-04 0.0000000E+00 15 HPO4-- 0.1537978E-04 0.1026422E-04 0.5115563E-05 0.0000000E+00 Chg. balance for solid moles: 0.2548E-17 Mass of aqueous solution: 0.999791E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 2.5990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) apatite-OH 0.1705E-05 -5.768 0.8565E-03 -3.067 0.3062E-01 0.2722E-03 clinochlore 0.4125E-03 -3.385 0.2293 -0.640 8.198 0.8722E-01 daphnite 0.2554E-03 -3.593 0.1822 -0.739 6.515 0.5522E-01 chlorite-Mn 0.9012E-05 -5.045 0.6390E-02 -2.195 0.2284 0.2036E-02 hematite 0.2608E-03 -3.584 0.4165E-01 -1.380 1.489 0.7893E-02 microcline 0.5099E-03 -3.292 0.1419 -0.848 5.075 0.5544E-01 paragonite 0.1889E-03 -3.724 0.7222E-01 -1.141 2.582 0.2496E-01 stilbite 0.2995E-02 -2.524 2.111 0.324 75.47 0.9845 nontronite-Na 0.2734E-04 -4.563 0.1162E-01 -1.935 0.4156 0.3611E-02 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.6094E+00 0.6094E+00 1.0000 -0.215 daphnite 0.3773E+00 0.3773E+00 1.0000 -0.423 chlorite-Mn 0.1331E-01 0.1331E-01 1.0000 -1.876 hematite 0.1000E+01 0.1000E+01 1.0000 0.000 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 paragonite 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 nontronite-Na 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 2.796924 g Volume = 1.221143 cm3 Porosity: 40.1283% V(tot) - V(min): 0.81846E+00 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 2.5990000 g log = 0.4148 Original solution: 1000.0103000 g Original solution / Rock added: 384.77 (Water/Rock Ratio), log = 2.5852 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0203 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.1000E+01 0.9860 0.1006E+01 0.1020E+01 CO2,gas 0.8093E-06 1.0071 0.8315E-06 0.8257E-06 CH4,gas 0.3039E-16 1.0125 0.3139E-16 0.3100E-16 H2,gas 0.7681E-06 1.0005 0.7842E-06 0.7837E-06 H2S,gas 0.1438E-14 0.9960 0.1461E-14 0.1467E-14 S2,gas 0.1277E-36 1.0000 0.1303E-36 0.1303E-36 CO,gas 0.1703E-15 1.0000 0.1738E-15 0.1738E-15 SO3,gas 0.1056E-38 1.0000 0.1077E-38 0.1077E-38 SO2,gas 0.3221E-22 1.0000 0.3286E-22 0.3286E-22 HCl,gas 0.1555E-16 1.0000 0.1586E-16 0.1586E-16 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 32 apatite-OH -18.15 -18.15 0.00 0.000 0.00000E+00 46 clinochlore 39.07 39.07 0.00 0.000 -0.12132E-10 47 daphnite 28.97 28.97 0.00 0.000 -0.24265E-10 48 chlorite-Mn 46.87 46.87 0.00 0.000 0.00000E+00 90 hematite 12.57 12.57 0.00 0.000 -0.30331E-11 116 microcline -2.49 -2.49 0.00 0.000 0.15165E-11 121 paragonite 4.24 4.24 0.00 0.000 -0.10616E-10 163 stilbite -7.52 -7.52 0.00 0.000 0.15165E-10 209 nontronite-Na 3.52 3.52 0.00 0.000 -0.68244E-11 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -14.44 -7.78 -2.593 0.13283E+05 -6.080 3 CH4,gas 4.54 -13.66 -18.20 -4.551 0.31080E+05 -16.503 4 H2,gas 8.00 0.20 -7.80 -4.460 0.13326E+05 -6.106 5 H2S,gas -6.23 -22.76 -16.53 -8.267 0.28232E+05 -14.835 6 S2,gas -7.34 -45.92 -38.58 -5.936 0.65881E+05 -36.885 7 CO,gas 3.21 -14.24 -17.46 -5.372 0.29811E+05 -15.760 8 SO3,gas 17.12 -23.55 -40.67 -10.167 0.69437E+05 -38.968 9 SO2,gas 0.83 -23.35 -24.18 -6.449 0.41291E+05 -22.483 10 HCl,gas 5.19 -13.31 -18.50 -9.249 0.31586E+05 -16.800 11 acmite 7.71 6.55 -1.16 -0.120 0.19759E+04 15 albite-high 0.69 -0.61 -1.30 -0.100 0.22211E+04 16 albite -0.38 -0.61 -0.22 -0.017 0.38224E+03 19 spessartine 24.46 20.47 -3.99 -0.199 0.68048E+04 20 analcite 3.32 2.69 -0.63 -0.070 0.10738E+04 21 andalusite 5.00 1.55 -3.46 -0.346 0.58995E+04 22 andradite 39.01 34.87 -4.14 -0.215 0.70642E+04 26 annite 20.12 16.66 -3.47 -0.193 0.59212E+04 27 phlogopite 27.06 23.34 -3.72 -0.207 0.63545E+04 29 anorthite 12.71 8.98 -3.73 -0.287 0.63668E+04 35 aragonite 0.97 -3.70 -4.67 -1.557 0.79737E+04 36 brucite 12.57 8.61 -3.96 -0.792 0.67594E+04 37 calcite 0.81 -3.70 -4.52 -1.505 0.77095E+04 38 carnegieite-low 9.02 5.99 -3.03 -0.433 0.51729E+04 39 carnegieite-high 10.09 5.99 -4.10 -0.586 0.69999E+04 40 carpholite-Mg 8.58 6.86 -1.73 -0.115 0.29480E+04 41 carpholite-Fe 6.71 4.63 -2.09 -0.139 0.35622E+04 42 celadonite 5.34 2.82 -2.52 -0.148 0.43011E+04 43 celadonite-Fe 3.88 0.59 -3.28 -0.193 0.56057E+04 44 chrysotile 23.89 19.23 -4.66 -0.389 0.79643E+04 50 chloritoid-Mg 13.20 10.16 -3.04 -0.203 0.51932E+04 51 chloritoid-Fe 9.17 7.93 -1.25 -0.083 0.21284E+04 52 chloritoid-Mn 11.40 10.06 -1.35 -0.090 0.22976E+04 54 coesite -2.38 -3.30 -0.92 -0.308 0.15788E+04 59 corundum 8.38 4.85 -3.54 -0.321 0.60375E+04 61 cristobalite -2.56 -3.30 -0.74 -0.247 0.12642E+04 63 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71234E+04 65 diaspore 2.87 2.42 -0.45 -0.075 0.76856E+03 67 diopside 16.18 12.74 -3.44 -0.344 0.58688E+04 68 hedenbergite 14.21 10.52 -3.69 -0.369 0.63060E+04 75 epidote 24.67 22.70 -1.97 -0.096 0.33640E+04 76 clinozoisite 22.81 18.84 -3.97 -0.180 0.67715E+04 77 epidote-Fe 29.84 26.56 -3.28 -0.170 0.56031E+04 78 fayalite 14.05 9.46 -4.59 -0.655 0.78289E+04 79 ferrosilite 11.15 6.16 -4.99 -0.499 0.85195E+04 83 gibbsite 4.08 2.42 -1.66 -0.237 0.28271E+04 84 glaucophane 22.97 18.01 -4.96 -0.134 0.84729E+04 87 greenalite 16.14 12.54 -3.60 -0.300 0.61450E+04 91 heulandite -5.83 -7.52 -1.69 -0.077 0.28938E+04 95 jadeite 4.22 2.69 -1.52 -0.152 0.25993E+04 97 kalsilite 7.58 4.11 -3.47 -0.496 0.59232E+04 98 kaolinite -1.33 -1.75 -0.42 -0.038 0.71972E+03 99 kyanite 4.88 1.55 -3.33 -0.333 0.56854E+04 101 laumontite 2.88 2.38 -0.50 -0.034 0.85937E+03 102 lawsonite 9.62 8.98 -0.63 -0.042 0.10834E+04 103 leucite 4.12 0.81 -3.30 -0.330 0.56426E+04 105 lizardite 23.24 19.23 -4.02 -0.335 0.68569E+04 107 magnetite 20.09 18.95 -1.14 -0.093 0.19474E+04 108 minnesotaite 10.39 5.94 -4.45 -0.262 0.75964E+04 113 margarite 17.32 13.83 -3.49 -0.140 0.59674E+04 120 muscovite 2.58 2.36 -0.22 -0.013 0.37865E+03 122 nepheline 8.34 5.99 -2.35 -0.335 0.40053E+04 134 phlogopite-Na 29.65 25.22 -4.43 -0.246 0.75556E+04 136 prehnite 19.37 16.42 -2.96 -0.174 0.50460E+04 137 prehnite-Fe 22.50 20.28 -2.22 -0.134 0.37935E+04 138 pumpellyite-Fe 46.27 41.64 -4.63 -0.103 0.79087E+04 145 pyroxmangite 7.40 5.21 -2.19 -0.438 0.37400E+04 146 pyrophyllite -6.18 -8.36 -2.18 -0.136 0.37222E+04 147 quartz -2.99 -3.30 -0.31 -0.104 0.53151E+03 151 rhodochrosite -0.98 -5.93 -4.95 -1.651 0.84586E+04 152 rhodonite 7.45 5.21 -2.24 -0.447 0.38203E+04 153 sanidine -1.28 -2.49 -1.21 -0.093 0.20677E+04 156 sillimanite 5.26 1.55 -3.72 -0.372 0.63434E+04 164 stilpnomelane-Fe 13.02 12.84 -0.18 -0.005 0.30068E+03 165 stilpnomelane-Mg 27.44 23.99 -3.45 -0.103 0.58990E+04 168 sudoite 21.08 17.01 -4.07 -0.131 0.69418E+04 171 talc 16.49 12.63 -3.86 -0.227 0.65985E+04 174 tephroite 18.09 13.72 -4.37 -0.624 0.74591E+04 177 topaz-H 4.62 1.55 -3.07 -0.279 0.52454E+04 178 tridymite -2.63 -3.30 -0.67 -0.225 0.11515E+04 187 wairakite 3.95 2.38 -1.57 -0.092 0.26813E+04 188 walstromite 11.51 7.44 -4.07 -0.815 0.69564E+04 189 wollastonite 10.46 7.44 -3.03 -0.605 0.51669E+04 190 pseudo-wollastonite 11.00 7.44 -3.56 -0.713 0.60867E+04 191 zoisite 22.85 18.84 -4.01 -0.182 0.68455E+04 192 akaganeite 7.75 6.28 -1.47 -0.318 0.25125E+04 193 beidellite-Ca -1.65 -4.70 -3.05 -0.189 0.52073E+04 194 beidellite-H -2.33 -6.47 -4.14 -0.264 0.70697E+04 195 beidellite-K -1.52 -4.82 -3.30 -0.202 0.56331E+04 196 beidellite-Mg -1.79 -5.05 -3.26 -0.201 0.55600E+04 197 beidellite-Na -1.34 -4.20 -2.86 -0.175 0.48784E+04 199 chalcedony -2.80 -3.30 -0.50 -0.166 0.85081E+03 201 montmorillonite-Ca -2.29 -4.54 -2.25 -0.139 0.38454E+04 202 montmorillonite-K -2.24 -4.67 -2.43 -0.149 0.41494E+04 203 montmorillonite-Mg -2.48 -4.89 -2.41 -0.149 0.41214E+04 204 montmorillonite-Na -2.04 -4.05 -2.01 -0.123 0.34305E+04 205 nontronite-Ca 3.21 3.02 -0.19 -0.012 0.32580E+03 206 nontronite-H 2.53 1.25 -1.28 -0.086 0.21862E+04 207 nontronite-K 3.34 2.90 -0.44 -0.028 0.75298E+03 208 nontronite-Mg 3.07 2.67 -0.40 -0.026 0.68586E+03 224 tobermorite 9.82 5.64 -4.18 -1.141 0.71386E+04 233 boehmite 4.41 2.42 -1.98 -0.330 0.33855E+04 235 ferrous-oxide 9.81 6.38 -3.43 -0.858 0.58582E+04 240 silica-amorphous -2.09 -3.30 -1.21 -0.403 0.20650E+04 242 an20ab80 2.02 1.31 -0.71 -0.054 0.12083E+04 243 an25ab75 2.65 1.79 -0.86 -0.066 0.14618E+04 244 an30ab70 3.28 2.27 -1.01 -0.078 0.17249E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 0.1000000 g Current total amount of reactant added: 2.5990000 g New total amount of reactant added: 2.6990000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.8099E-13 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 6 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 2.6990000 Water: Moles liquid = 0.5548E+02 kg liquid = 0.9995E+00 Moles total = 0.5547E+02 kg total = 0.9994E+00 Activity = 1.0000 Stoichiometric ionic strength = .2043244E-02 Osmotic coef. = 0.9746 True ionic strength = .3357700E-02 Chg. balance for total moles = 0.8099E-13 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.41037E-09 -9.3868 0.37492E-09 -9.4261 0.91361E+00 -0.0392 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13792E-03 -3.8604 0.12584E-03 -3.9002 0.91241E+00 -0.0398 4 SO4-- 0.25505E-04 -4.5934 0.18702E-04 -4.7281 0.73328E+00 -0.1347 5 HCO3- 0.10130E-04 -4.9944 0.92457E-05 -5.0341 0.91270E+00 -0.0397 6 HS- 0.50428E-13 -13.2973 0.46013E-13 -13.3371 0.91244E+00 -0.0398 7 Al+++ 0.27028E-25 -25.5682 0.13713E-25 -25.8629 0.50736E+00 -0.2947 8 H4SiO4 0.49801E-03 -3.3028 0.49801E-03 -3.3028 0.10000E+01 0.0000 9 Ca++ 0.11219E-07 -7.9500 0.82137E-08 -8.0855 0.73213E+00 -0.1354 10 Mg++ 0.79083E-10 -10.1019 0.57842E-10 -10.2378 0.73140E+00 -0.1358 11 Fe++ 0.46649E-12 -12.3312 0.34127E-12 -12.4669 0.73158E+00 -0.1357 12 K+ 0.41693E-04 -4.3799 0.38056E-04 -4.4196 0.91275E+00 -0.0396 13 Na+ 0.32776E-02 -2.4844 0.29905E-02 -2.5243 0.91238E+00 -0.0398 14 Mn++ 0.62675E-10 -10.2029 0.45860E-10 -10.3386 0.73171E+00 -0.1357 15 HPO4-- 0.98004E-05 -5.0088 0.71867E-05 -5.1435 0.73331E+00 -0.1347 16 HSiO3- 0.13594E-02 -2.8667 0.12403E-02 -2.9065 0.91241E+00 -0.0398 17 Ca(HSiO3)+ 0.25417E-09 -9.5949 0.23201E-09 -9.6345 0.91279E+00 -0.0396 18 Mg(HSiO3)+ 0.22276E-11 -11.6522 0.20333E-11 -11.6918 0.91279E+00 -0.0396 19 NaHSiO3,aq 0.59989E-04 -4.2219 0.59989E-04 -4.2219 0.10000E+01 0.0000 20 AlO+ 0.14539E-13 -13.8375 0.13272E-13 -13.8771 0.91279E+00 -0.0396 21 AlOH+2 0.33854E-19 -19.4704 0.24776E-19 -19.6060 0.73186E+00 -0.1356 22 HAlO2,aq 0.70495E-08 -8.1518 0.70495E-08 -8.1518 0.10000E+01 0.0000 23 AlO2- 0.45634E-04 -4.3407 0.41621E-04 -4.3807 0.91205E+00 -0.0400 24 CH4,aq 0.22110E-19 -19.6554 0.22096E-19 -19.6557 0.99937E+00 -0.0003 29 CO,aq 0.11348E-18 -18.9451 0.11348E-18 -18.9451 0.10000E+01 0.0000 30 CO2,aq 0.74116E-08 -8.1301 0.74069E-08 -8.1304 0.99937E+00 -0.0003 31 CO3-2 0.29388E-05 -5.5318 0.21540E-05 -5.6668 0.73294E+00 -0.1349 32 CaCO3,aq 0.22184E-09 -9.6540 0.22184E-09 -9.6540 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.21237E-11 -11.6729 0.19385E-11 -11.7125 0.91279E+00 -0.0396 34 CaCl+ 0.18325E-11 -11.7370 0.16727E-11 -11.7766 0.91279E+00 -0.0396 35 CaCl2,aq 0.50007E-16 -16.3010 0.50007E-16 -16.3010 0.10000E+01 0.0000 36 CaOH+ 0.17105E-08 -8.7669 0.15614E-08 -8.8065 0.91279E+00 -0.0396 37 CaSO4,aq 0.48780E-10 -10.3118 0.48780E-10 -10.3118 0.10000E+01 0.0000 38 HCl,aq 0.86454E-14 -14.0632 0.86454E-14 -14.0632 0.10000E+01 0.0000 43 FeCl+ 0.74469E-16 -16.1280 0.67975E-16 -16.1677 0.91279E+00 -0.0396 46 FeO,aq 0.94360E-10 -10.0252 0.94360E-10 -10.0252 0.10000E+01 0.0000 47 FeOH+ 0.32460E-10 -10.4886 0.29630E-10 -10.5283 0.91279E+00 -0.0396 48 HFeO2- 0.28861E-08 -8.5397 0.26333E-08 -8.5795 0.91241E+00 -0.0398 49 FeO+ 0.31351E-14 -14.5037 0.28617E-14 -14.5434 0.91279E+00 -0.0396 51 FeO2- 0.45657E-08 -8.3405 0.41658E-08 -8.3803 0.91241E+00 -0.0398 52 HFeO2,aq 0.19864E-09 -9.7019 0.19864E-09 -9.7019 0.10000E+01 0.0000 53 H2,aq 0.61027E-09 -9.2145 0.60988E-09 -9.2148 0.99937E+00 -0.0003 54 KCl,aq 0.86794E-10 -10.0615 0.86794E-10 -10.0615 0.10000E+01 0.0000 55 KHSO4,aq 0.75447E-18 -18.1224 0.75447E-18 -18.1224 0.10000E+01 0.0000 56 KOH,aq 0.43348E-07 -7.3630 0.43348E-07 -7.3630 0.10000E+01 0.0000 57 KSO4- 0.12105E-07 -7.9171 0.11044E-07 -7.9569 0.91241E+00 -0.0398 58 MgCO3,aq 0.39158E-12 -12.4072 0.39158E-12 -12.4072 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.15281E-13 -13.8158 0.13949E-13 -13.8555 0.91279E+00 -0.0396 60 MgCl+ 0.11696E-13 -13.9320 0.10676E-13 -13.9716 0.91279E+00 -0.0396 61 MgOH+ 0.66655E-10 -10.1762 0.60842E-10 -10.2158 0.91279E+00 -0.0396 63 MnO,aq 0.33786E-09 -9.4713 0.33786E-09 -9.4713 0.10000E+01 0.0000 64 MnOH+ 0.40521E-09 -9.3923 0.36987E-09 -9.4319 0.91279E+00 -0.0396 65 MnO2-2 0.10883E-12 -12.9632 0.79768E-13 -13.0982 0.73294E+00 -0.1349 66 HMnO2- 0.71811E-11 -11.1438 0.65521E-11 -11.1836 0.91241E+00 -0.0398 69 MnCl+ 0.38932E-13 -13.4097 0.35537E-13 -13.4493 0.91279E+00 -0.0396 70 MnSO4,aq 0.24761E-12 -12.6062 0.24761E-12 -12.6062 0.10000E+01 0.0000 71 NaCl,aq 0.12471E-06 -6.9041 0.12471E-06 -6.9041 0.10000E+01 0.0000 72 NaOH,aq 0.34270E-05 -5.4651 0.34270E-05 -5.4651 0.10000E+01 0.0000 74 OH- 0.16897E-02 -2.7722 0.15410E-02 -2.8122 0.91205E+00 -0.0400 79 HPO3-2 0.18636E-16 -16.7297 0.13659E-16 -16.8646 0.73294E+00 -0.1349 81 H2PO3- 0.11255E-19 -19.9487 0.10269E-19 -19.9885 0.91241E+00 -0.0398 82 H3PO4,aq 0.70653E-14 -14.1509 0.70653E-14 -14.1509 0.10000E+01 0.0000 83 H2PO4- 0.54466E-07 -7.2639 0.49705E-07 -7.3036 0.91260E+00 -0.0397 84 PO4-3 0.30497E-07 -7.5157 0.15639E-07 -7.8058 0.51282E+00 -0.2900 87 H2P2O7-2 0.26431E-15 -15.5779 0.19372E-15 -15.7128 0.73294E+00 -0.1349 88 HP2O7-3 0.20332E-12 -12.6918 0.10317E-12 -12.9864 0.50743E+00 -0.2946 89 P2O7-4 0.21533E-12 -12.6669 0.65740E-13 -13.1822 0.30530E+00 -0.5153 90 H2S,aq 0.53351E-16 -16.2729 0.53317E-16 -16.2731 0.99937E+00 -0.0003 97 SO3-2 0.20159E-14 -14.6955 0.14822E-14 -14.8291 0.73526E+00 -0.1336 98 HSO3- 0.38135E-16 -16.4187 0.34795E-16 -16.4585 0.91241E+00 -0.0398 99 HSO4- 0.74016E-11 -11.1307 0.67575E-11 -11.1702 0.91298E+00 -0.0395 Charge balance for all species = 0.9141E-13 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.4103738E-09 -.3297968E-02 -.3323243E+01 0.0000 2 H2O 0.1000000E+01 0.5550862E+02 0.9997303E+06 0.0000 3 Cl- 0.1379174E-03 0.1380422E-03 0.4892669E+01 5.5259 4 SO4-- 0.2550488E-04 0.2551749E-04 0.2450579E+01 14.1240 5 HCO3- 0.1013001E-04 0.1307644E-04 0.7976694E+00 4.3920 6 HS- 0.5042840E-13 -.4429251E-09 -.1464441E-04 -3.9111 7 Al+++ 0.2702776E-25 0.4564140E-04 0.1231136E+01 2.4153 8 H4SiO4 0.4980129E-03 0.1917364E-02 0.1842378E+03 -3.3028 9 Ca++ 0.1121891E-07 0.1345817E-07 0.5392289E-03 10.7667 10 Mg++ 0.7908341E-10 0.1483843E-09 0.3606530E-05 8.6144 11 Fe++ 0.4664920E-12 0.7777752E-08 0.4342451E-03 6.3852 12 K+ 0.4169349E-04 0.4174903E-04 0.1632023E+01 5.0065 13 Na+ 0.3277634E-02 0.3341174E-02 0.7679188E+02 6.9018 14 Mn++ 0.6267490E-10 0.8133265E-09 0.4467029E-04 8.5135 15 HPO4-- 0.9800369E-05 0.9885333E-05 0.9485244E+00 13.7086 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.4467839E-01 -.3296343E-02 -.4138205E-01 0.0000000E+00 2 H2O 0.5547442E+02 0.5548126E+02 -.6843909E-02 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.1003030E-03 0.2550491E-04 0.7479805E-04 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.7479849E-04 -.4427069E-09 -.7479805E-04 0.0000000E+00 7 Al+++ 0.8800742E-02 0.4561891E-04 0.8755123E-02 0.0000000E+00 8 H4SiO4 0.2810410E-01 0.1916420E-02 0.2618768E-01 0.0000000E+00 9 Ca++ 0.3118706E-02 0.1345154E-07 0.3118693E-02 0.0000000E+00 10 Mg++ 0.2142063E-02 0.1483112E-09 0.2142063E-02 0.0000000E+00 11 Fe++ 0.1924410E-02 0.7773919E-08 0.1924402E-02 0.0000000E+00 12 K+ 0.5730361E-03 0.4172846E-04 0.5313076E-03 0.0000000E+00 13 Na+ 0.3547974E-02 0.3339528E-02 0.2084459E-03 0.0000000E+00 14 Mn++ 0.4679687E-04 0.8129257E-09 0.4679606E-04 0.0000000E+00 15 HPO4-- 0.1597154E-04 0.9880461E-05 0.6091078E-05 0.0000000E+00 Chg. balance for solid moles: 0.6915E-17 Mass of aqueous solution: 0.999781E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 2.6990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) apatite-OH 0.2030E-05 -5.692 0.1020E-02 -2.991 0.3509E-01 0.3241E-03 clinochlore 0.4284E-03 -3.368 0.2381 -0.623 8.194 0.9058E-01 daphnite 0.2652E-03 -3.576 0.1892 -0.723 6.511 0.5734E-01 chlorite-Mn 0.9359E-05 -5.029 0.6635E-02 -2.178 0.2283 0.2115E-02 hematite 0.2620E-03 -3.582 0.4184E-01 -1.378 1.440 0.7930E-02 microcline 0.5313E-03 -3.275 0.1479 -0.830 5.089 0.5777E-01 paragonite 0.1962E-03 -3.707 0.7498E-01 -1.125 2.580 0.2592E-01 stilbite 0.3109E-02 -2.507 2.191 0.341 75.38 1.022 nontronite-Na 0.3720E-04 -4.429 0.1582E-01 -1.801 0.5444 0.4915E-02 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.6094E+00 0.6094E+00 1.0000 -0.215 daphnite 0.3773E+00 0.3773E+00 1.0000 -0.423 chlorite-Mn 0.1331E-01 0.1331E-01 1.0000 -1.876 hematite 0.1000E+01 0.1000E+01 1.0000 0.000 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 paragonite 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 nontronite-Na 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 2.906177 g Volume = 1.268643 cm3 Porosity: 38.9958% V(tot) - V(min): 0.81096E+00 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 2.6990000 g log = 0.4312 Original solution: 1000.0103000 g Original solution / Rock added: 370.51 (Water/Rock Ratio), log = 2.5688 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0203 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.1000E+01 0.9860 0.1006E+01 0.1020E+01 CO2,gas 0.7712E-06 1.0071 0.7925E-06 0.7869E-06 CH4,gas 0.3148E-16 1.0125 0.3252E-16 0.3212E-16 H2,gas 0.7843E-06 1.0005 0.8007E-06 0.8003E-06 H2S,gas 0.1442E-14 0.9960 0.1466E-14 0.1471E-14 S2,gas 0.1233E-36 1.0000 0.1258E-36 0.1258E-36 CO,gas 0.1657E-15 1.0000 0.1691E-15 0.1691E-15 SO3,gas 0.9742E-39 1.0000 0.9940E-39 0.9940E-39 SO2,gas 0.3035E-22 1.0000 0.3096E-22 0.3096E-22 HCl,gas 0.1495E-16 1.0000 0.1526E-16 0.1526E-16 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 32 apatite-OH -18.15 -18.15 0.00 0.000 0.60662E-11 46 clinochlore 39.07 39.07 0.00 0.000 0.24265E-10 47 daphnite 28.97 28.97 0.00 0.000 0.30331E-10 48 chlorite-Mn 46.87 46.87 0.00 0.000 0.24265E-10 90 hematite 12.57 12.57 0.00 0.000 0.15165E-10 116 microcline -2.49 -2.49 0.00 0.000 0.15165E-11 121 paragonite 4.24 4.24 0.00 0.000 -0.10616E-10 163 stilbite -7.52 -7.52 0.00 0.000 -0.90992E-11 209 nontronite-Na 3.52 3.52 0.00 0.000 0.68244E-11 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -14.46 -7.80 -2.600 0.13318E+05 -6.101 3 CH4,gas 4.54 -13.64 -18.19 -4.547 0.31053E+05 -16.488 4 H2,gas 8.00 0.20 -7.80 -4.455 0.13311E+05 -6.097 5 H2S,gas -6.23 -22.76 -16.53 -8.266 0.28230E+05 -14.834 6 S2,gas -7.34 -45.93 -38.60 -5.938 0.65907E+05 -36.900 7 CO,gas 3.21 -14.26 -17.47 -5.376 0.29831E+05 -15.772 8 SO3,gas 17.12 -23.58 -40.70 -10.175 0.69497E+05 -39.003 9 SO2,gas 0.83 -23.38 -24.21 -6.455 0.41335E+05 -22.509 10 HCl,gas 5.19 -13.33 -18.52 -9.258 0.31615E+05 -16.817 11 acmite 7.71 6.58 -1.13 -0.117 0.19300E+04 15 albite-high 0.69 -0.59 -1.28 -0.099 0.21928E+04 16 albite -0.38 -0.59 -0.21 -0.016 0.35398E+03 19 spessartine 24.46 20.46 -3.99 -0.200 0.68203E+04 20 analcite 3.32 2.71 -0.61 -0.068 0.10420E+04 21 andalusite 5.00 1.53 -3.47 -0.347 0.59312E+04 22 andradite 39.01 34.96 -4.05 -0.210 0.69168E+04 26 annite 20.12 16.67 -3.45 -0.192 0.58980E+04 27 phlogopite 27.06 23.36 -3.71 -0.206 0.63313E+04 29 anorthite 12.71 8.99 -3.72 -0.286 0.63494E+04 35 aragonite 0.97 -3.69 -4.66 -1.553 0.79568E+04 36 brucite 12.57 8.61 -3.95 -0.791 0.67517E+04 37 calcite 0.81 -3.69 -4.51 -1.502 0.76926E+04 38 carnegieite-low 9.02 6.01 -3.01 -0.430 0.51377E+04 39 carnegieite-high 10.09 6.01 -4.08 -0.583 0.69647E+04 40 carpholite-Mg 8.58 6.84 -1.74 -0.116 0.29755E+04 41 carpholite-Fe 6.71 4.61 -2.10 -0.140 0.35897E+04 42 celadonite 5.34 2.83 -2.52 -0.148 0.42969E+04 43 celadonite-Fe 3.88 0.60 -3.28 -0.193 0.56015E+04 44 chrysotile 23.89 19.24 -4.65 -0.388 0.79480E+04 50 chloritoid-Mg 13.20 10.14 -3.06 -0.204 0.52172E+04 51 chloritoid-Fe 9.17 7.91 -1.26 -0.084 0.21524E+04 52 chloritoid-Mn 11.40 10.04 -1.36 -0.091 0.23216E+04 54 coesite -2.38 -3.30 -0.93 -0.309 0.15823E+04 59 corundum 8.38 4.83 -3.55 -0.323 0.60658E+04 61 cristobalite -2.56 -3.30 -0.74 -0.247 0.12677E+04 63 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71234E+04 65 diaspore 2.87 2.42 -0.46 -0.076 0.78269E+03 67 diopside 16.18 12.78 -3.41 -0.341 0.58154E+04 68 hedenbergite 14.21 10.55 -3.66 -0.366 0.62526E+04 75 epidote 24.67 22.74 -1.93 -0.094 0.32974E+04 76 clinozoisite 22.81 18.87 -3.94 -0.179 0.67190E+04 77 epidote-Fe 29.84 26.61 -3.23 -0.168 0.55224E+04 78 fayalite 14.05 9.47 -4.58 -0.654 0.78169E+04 79 ferrosilite 11.15 6.16 -4.98 -0.498 0.85110E+04 83 gibbsite 4.08 2.42 -1.66 -0.238 0.28412E+04 84 glaucophane 22.97 18.06 -4.92 -0.133 0.84001E+04 87 greenalite 16.14 12.55 -3.59 -0.299 0.61287E+04 91 heulandite -5.83 -7.52 -1.69 -0.077 0.28938E+04 95 jadeite 4.22 2.71 -1.50 -0.150 0.25675E+04 97 kalsilite 7.58 4.12 -3.46 -0.495 0.59162E+04 98 kaolinite -1.33 -1.77 -0.44 -0.040 0.75495E+03 99 kyanite 4.88 1.53 -3.35 -0.335 0.57171E+04 101 laumontite 2.88 2.39 -0.50 -0.033 0.84893E+03 102 lawsonite 9.62 8.99 -0.62 -0.042 0.10660E+04 103 leucite 4.12 0.82 -3.30 -0.330 0.56391E+04 105 lizardite 23.24 19.24 -4.01 -0.334 0.68406E+04 107 magnetite 20.09 18.95 -1.14 -0.093 0.19397E+04 108 minnesotaite 10.39 5.94 -4.44 -0.261 0.75871E+04 113 margarite 17.32 13.82 -3.50 -0.140 0.59783E+04 120 muscovite 2.58 2.34 -0.24 -0.014 0.40692E+03 122 nepheline 8.34 6.01 -2.33 -0.332 0.39701E+04 134 phlogopite-Na 29.65 25.25 -4.39 -0.244 0.75041E+04 136 prehnite 19.37 16.46 -2.92 -0.172 0.49794E+04 137 prehnite-Fe 22.50 20.32 -2.17 -0.131 0.37128E+04 138 pumpellyite-Fe 46.27 41.71 -4.56 -0.101 0.77820E+04 145 pyroxmangite 7.40 5.21 -2.19 -0.438 0.37358E+04 146 pyrophyllite -6.18 -8.38 -2.20 -0.138 0.37643E+04 147 quartz -2.99 -3.30 -0.31 -0.104 0.53499E+03 151 rhodochrosite -0.98 -5.95 -4.97 -1.657 0.84866E+04 152 rhodonite 7.45 5.21 -2.23 -0.447 0.38160E+04 153 sanidine -1.28 -2.49 -1.21 -0.093 0.20677E+04 156 sillimanite 5.26 1.53 -3.73 -0.373 0.63751E+04 164 stilpnomelane-Fe 13.02 12.84 -0.18 -0.005 0.30579E+03 165 stilpnomelane-Mg 27.44 23.98 -3.46 -0.103 0.59042E+04 168 sudoite 21.08 16.98 -4.10 -0.132 0.69933E+04 171 talc 16.49 12.63 -3.86 -0.227 0.65892E+04 174 tephroite 18.09 13.72 -4.36 -0.623 0.74471E+04 177 topaz-H 4.62 1.53 -3.09 -0.281 0.52772E+04 178 tridymite -2.63 -3.30 -0.68 -0.225 0.11550E+04 187 wairakite 3.95 2.39 -1.56 -0.092 0.26709E+04 188 walstromite 11.51 7.46 -4.05 -0.809 0.69073E+04 189 wollastonite 10.46 7.46 -3.00 -0.599 0.51177E+04 190 pseudo-wollastonite 11.00 7.46 -3.54 -0.707 0.60376E+04 191 zoisite 22.85 18.87 -3.98 -0.181 0.67931E+04 192 akaganeite 7.75 6.28 -1.47 -0.318 0.25125E+04 193 beidellite-Ca -1.65 -4.72 -3.07 -0.190 0.52443E+04 194 beidellite-H -2.33 -6.49 -4.17 -0.266 0.71154E+04 195 beidellite-K -1.52 -4.84 -3.32 -0.203 0.56707E+04 196 beidellite-Mg -1.79 -5.07 -3.28 -0.203 0.56045E+04 197 beidellite-Na -1.34 -4.22 -2.87 -0.176 0.49067E+04 199 chalcedony -2.80 -3.30 -0.50 -0.167 0.85429E+03 201 montmorillonite-Ca -2.29 -4.56 -2.27 -0.140 0.38717E+04 202 montmorillonite-K -2.24 -4.68 -2.45 -0.150 0.41763E+04 203 montmorillonite-Mg -2.48 -4.91 -2.43 -0.151 0.41551E+04 204 montmorillonite-Na -2.04 -4.06 -2.02 -0.124 0.34480E+04 205 nontronite-Ca 3.21 3.02 -0.20 -0.013 0.33455E+03 206 nontronite-H 2.53 1.24 -1.29 -0.087 0.22037E+04 207 nontronite-K 3.34 2.89 -0.45 -0.029 0.76231E+03 208 nontronite-Mg 3.07 2.66 -0.41 -0.027 0.70202E+03 224 tobermorite 9.82 5.67 -4.16 -1.134 0.70983E+04 233 boehmite 4.41 2.42 -1.99 -0.332 0.33996E+04 235 ferrous-oxide 9.81 6.39 -3.43 -0.857 0.58504E+04 240 silica-amorphous -2.09 -3.30 -1.21 -0.404 0.20685E+04 242 an20ab80 2.02 1.33 -0.69 -0.053 0.11822E+04 243 an25ab75 2.65 1.80 -0.84 -0.065 0.14362E+04 244 an30ab70 3.28 2.28 -1.00 -0.077 0.16999E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 0.1000000 g Current total amount of reactant added: 2.6990000 g New total amount of reactant added: 2.7990000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.8099E-13 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 6 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 2.7990000 Water: Moles liquid = 0.5548E+02 kg liquid = 0.9995E+00 Moles total = 0.5547E+02 kg total = 0.9994E+00 Activity = 1.0000 Stoichiometric ionic strength = .2104057E-02 Osmotic coef. = 0.9742 True ionic strength = .3468275E-02 Chg. balance for total moles = 0.8099E-13 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.39608E-09 -9.4022 0.36148E-09 -9.4419 0.91263E+00 -0.0397 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13792E-03 -3.8604 0.12570E-03 -3.9007 0.91140E+00 -0.0403 4 SO4-- 0.25505E-04 -4.5934 0.18621E-04 -4.7300 0.73009E+00 -0.1366 5 HCO3- 0.10039E-04 -4.9983 0.91523E-05 -5.0385 0.91169E+00 -0.0402 6 HS- 0.52527E-13 -13.2796 0.47874E-13 -13.3199 0.91143E+00 -0.0403 7 Al+++ 0.24019E-25 -25.6194 0.12066E-25 -25.9184 0.50235E+00 -0.2990 8 H4SiO4 0.49576E-03 -3.3047 0.49576E-03 -3.3047 0.10000E+01 0.0000 9 Ca++ 0.11217E-07 -7.9501 0.81760E-08 -8.0875 0.72890E+00 -0.1373 10 Mg++ 0.74588E-10 -10.1273 0.54312E-10 -10.2651 0.72816E+00 -0.1378 11 Fe++ 0.43997E-12 -12.3566 0.32045E-12 -12.4942 0.72833E+00 -0.1377 12 K+ 0.41549E-04 -4.3814 0.37882E-04 -4.4216 0.91175E+00 -0.0401 13 Na+ 0.33886E-02 -2.4700 0.30883E-02 -2.5103 0.91137E+00 -0.0403 14 Mn++ 0.59112E-10 -10.2283 0.43061E-10 -10.3659 0.72847E+00 -0.1376 15 HPO4-- 0.94478E-05 -5.0247 0.68979E-05 -5.1613 0.73011E+00 -0.1366 16 HSiO3- 0.14051E-02 -2.8523 0.12806E-02 -2.8926 0.91140E+00 -0.0403 17 Ca(HSiO3)+ 0.26152E-09 -9.5825 0.23845E-09 -9.6226 0.91179E+00 -0.0401 18 Mg(HSiO3)+ 0.21620E-11 -11.6651 0.19713E-11 -11.7053 0.91179E+00 -0.0401 19 NaHSiO3,aq 0.63965E-04 -4.1941 0.63965E-04 -4.1941 0.10000E+01 0.0000 20 AlO+ 0.13778E-13 -13.8608 0.12563E-13 -13.9009 0.91179E+00 -0.0401 21 AlOH+2 0.31034E-19 -19.5082 0.22612E-19 -19.6457 0.72863E+00 -0.1375 22 HAlO2,aq 0.69211E-08 -8.1598 0.69211E-08 -8.1598 0.10000E+01 0.0000 23 AlO2- 0.46522E-04 -4.3323 0.42383E-04 -4.3728 0.91102E+00 -0.0405 24 CH4,aq 0.22872E-19 -19.6407 0.22857E-19 -19.6410 0.99935E+00 -0.0003 29 CO,aq 0.11051E-18 -18.9566 0.11051E-18 -18.9566 0.10000E+01 0.0000 30 CO2,aq 0.70738E-08 -8.1503 0.70692E-08 -8.1506 0.99935E+00 -0.0003 31 CO3-2 0.30306E-05 -5.5185 0.22115E-05 -5.6553 0.72974E+00 -0.1368 32 CaCO3,aq 0.22672E-09 -9.6445 0.22672E-09 -9.6445 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.20949E-11 -11.6788 0.19101E-11 -11.7189 0.91179E+00 -0.0401 34 CaCl+ 0.18240E-11 -11.7390 0.16631E-11 -11.7791 0.91179E+00 -0.0401 35 CaCl2,aq 0.49665E-16 -16.3039 0.49665E-16 -16.3039 0.10000E+01 0.0000 36 CaOH+ 0.17679E-08 -8.7525 0.16120E-08 -8.7926 0.91179E+00 -0.0401 37 CaSO4,aq 0.48345E-10 -10.3156 0.48345E-10 -10.3156 0.10000E+01 0.0000 38 HCl,aq 0.83260E-14 -14.0796 0.83260E-14 -14.0796 0.10000E+01 0.0000 43 FeCl+ 0.69923E-16 -16.1554 0.63755E-16 -16.1955 0.91179E+00 -0.0401 46 FeO,aq 0.95314E-10 -10.0208 0.95314E-10 -10.0208 0.10000E+01 0.0000 47 FeOH+ 0.31648E-10 -10.4997 0.28856E-10 -10.5398 0.91179E+00 -0.0401 48 HFeO2- 0.30271E-08 -8.5190 0.27589E-08 -8.5593 0.91140E+00 -0.0403 49 FeO+ 0.30261E-14 -14.5191 0.27591E-14 -14.5592 0.91179E+00 -0.0401 51 FeO2- 0.47408E-08 -8.3242 0.43207E-08 -8.3644 0.91140E+00 -0.0403 52 HFeO2,aq 0.19864E-09 -9.7019 0.19864E-09 -9.7019 0.10000E+01 0.0000 53 H2,aq 0.62269E-09 -9.2057 0.62228E-09 -9.2060 0.99935E+00 -0.0003 54 KCl,aq 0.86302E-10 -10.0640 0.86302E-10 -10.0640 0.10000E+01 0.0000 55 KHSO4,aq 0.72096E-18 -18.1421 0.72096E-18 -18.1421 0.10000E+01 0.0000 56 KOH,aq 0.44755E-07 -7.3492 0.44755E-07 -7.3492 0.10000E+01 0.0000 57 KSO4- 0.12011E-07 -7.9204 0.10946E-07 -7.9607 0.91140E+00 -0.0403 58 MgCO3,aq 0.37751E-12 -12.4231 0.37751E-12 -12.4231 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.14220E-13 -13.8471 0.12965E-13 -13.8872 0.91179E+00 -0.0401 60 MgCl+ 0.10982E-13 -13.9593 0.10013E-13 -13.9994 0.91179E+00 -0.0401 61 MgOH+ 0.64986E-10 -10.1872 0.59254E-10 -10.2273 0.91179E+00 -0.0401 63 MnO,aq 0.34128E-09 -9.4669 0.34128E-09 -9.4669 0.10000E+01 0.0000 64 MnOH+ 0.39507E-09 -9.4033 0.36022E-09 -9.4434 0.91179E+00 -0.0401 65 MnO2-2 0.11878E-12 -12.9252 0.86680E-13 -13.0621 0.72974E+00 -0.1368 66 HMnO2- 0.75319E-11 -11.1231 0.68645E-11 -11.1634 0.91140E+00 -0.0403 69 MnCl+ 0.36555E-13 -13.4371 0.33330E-13 -13.4772 0.91179E+00 -0.0401 70 MnSO4,aq 0.23149E-12 -12.6355 0.23149E-12 -12.6355 0.10000E+01 0.0000 71 NaCl,aq 0.12864E-06 -6.8906 0.12864E-06 -6.8906 0.10000E+01 0.0000 72 NaOH,aq 0.36707E-05 -5.4353 0.36707E-05 -5.4353 0.10000E+01 0.0000 74 OH- 0.17545E-02 -2.7559 0.15984E-02 -2.7963 0.91102E+00 -0.0405 79 HPO3-2 0.18331E-16 -16.7368 0.13377E-16 -16.8737 0.72974E+00 -0.1368 81 H2PO3- 0.10639E-19 -19.9731 0.96964E-20 -20.0134 0.91140E+00 -0.0403 82 H3PO4,aq 0.63038E-14 -14.2004 0.63038E-14 -14.2004 0.10000E+01 0.0000 83 H2PO4- 0.50458E-07 -7.2971 0.45997E-07 -7.3373 0.91159E+00 -0.0402 84 PO4-3 0.30653E-07 -7.5135 0.15569E-07 -7.8077 0.50792E+00 -0.2942 87 H2P2O7-2 0.22734E-15 -15.6433 0.16590E-15 -15.7802 0.72974E+00 -0.1368 88 HP2O7-3 0.18239E-12 -12.7390 0.91639E-13 -13.0379 0.50242E+00 -0.2989 89 P2O7-4 0.20186E-12 -12.6949 0.60563E-13 -13.2178 0.30002E+00 -0.5229 90 H2S,aq 0.53520E-16 -16.2715 0.53485E-16 -16.2718 0.99935E+00 -0.0003 97 SO3-2 0.20568E-14 -14.6868 0.15058E-14 -14.8222 0.73211E+00 -0.1354 98 HSO3- 0.37394E-16 -16.4272 0.34081E-16 -16.4675 0.91140E+00 -0.0403 99 HSO4- 0.71130E-11 -11.1479 0.64869E-11 -11.1880 0.91198E+00 -0.0400 Charge balance for all species = 0.9097E-13 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.3960841E-09 -.3416401E-02 -.3442558E+01 0.0000 2 H2O 0.1000000E+01 0.5550863E+02 0.9997233E+06 0.0000 3 Cl- 0.1379159E-03 0.1380446E-03 0.4892719E+01 5.5412 4 SO4-- 0.2550542E-04 0.2551795E-04 0.2450605E+01 14.1538 5 HCO3- 0.1003880E-04 0.1307667E-04 0.7976774E+00 4.4034 6 HS- 0.5252674E-13 -.4617020E-09 -.1526511E-04 -3.8780 7 Al+++ 0.2401939E-25 0.4652896E-04 0.1255068E+01 2.4073 8 H4SiO4 0.4957644E-03 0.1964845E-02 0.1887987E+03 -3.3047 9 Ca++ 0.1121681E-07 0.1352523E-07 0.5419118E-03 10.7964 10 Mg++ 0.7458834E-10 0.1421393E-09 0.3454719E-05 8.6187 11 Fe++ 0.4399736E-12 0.8093926E-08 0.4518943E-03 6.3896 12 K+ 0.4154935E-04 0.4160620E-04 0.1626428E+01 5.0204 13 Na+ 0.3388613E-02 0.3456377E-02 0.7943905E+02 6.9316 14 Mn++ 0.5911180E-10 0.8033810E-09 0.4412373E-04 8.5179 15 HPO4-- 0.9447753E-05 0.9528865E-05 0.9143136E+00 13.7226 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.4633424E-01 -.3414658E-02 -.4291959E-01 0.0000000E+00 2 H2O 0.5547316E+02 0.5548031E+02 -.7146563E-02 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.1030743E-03 0.2550493E-04 0.7756937E-04 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.7756983E-04 -.4614664E-09 -.7756937E-04 0.0000000E+00 7 Al+++ 0.9126816E-02 0.4650521E-04 0.9080311E-02 0.0000000E+00 8 H4SiO4 0.2914538E-01 0.1963842E-02 0.2718154E-01 0.0000000E+00 9 Ca++ 0.3233720E-02 0.1351833E-07 0.3233707E-02 0.0000000E+00 10 Mg++ 0.2221429E-02 0.1420668E-09 0.2221428E-02 0.0000000E+00 11 Fe++ 0.1995711E-02 0.8089797E-08 0.1995703E-02 0.0000000E+00 12 K+ 0.5942675E-03 0.4158497E-04 0.5526825E-03 0.0000000E+00 13 Na+ 0.3673498E-02 0.3454613E-02 0.2188845E-03 0.0000000E+00 14 Mn++ 0.4853073E-04 0.8029711E-09 0.4852993E-04 0.0000000E+00 15 HPO4-- 0.1656330E-04 0.9524003E-05 0.7039294E-05 0.0000000E+00 Chg. balance for solid moles: 0.1220E-17 Mass of aqueous solution: 0.999771E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 2.7990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) apatite-OH 0.2346E-05 -5.630 0.1179E-02 -2.929 0.3909E-01 0.3745E-03 clinochlore 0.4443E-03 -3.352 0.2469 -0.607 8.189 0.9393E-01 daphnite 0.2750E-03 -3.561 0.1962 -0.707 6.508 0.5947E-01 chlorite-Mn 0.9706E-05 -5.013 0.6881E-02 -2.162 0.2282 0.2193E-02 hematite 0.2633E-03 -3.580 0.4205E-01 -1.376 1.394 0.7969E-02 microcline 0.5527E-03 -3.258 0.1538 -0.813 5.102 0.6009E-01 paragonite 0.2034E-03 -3.692 0.7773E-01 -1.109 2.578 0.2687E-01 stilbite 0.3222E-02 -2.492 2.271 0.356 75.30 1.059 nontronite-Na 0.4700E-04 -4.328 0.1999E-01 -1.699 0.6628 0.6209E-02 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.6094E+00 0.6094E+00 1.0000 -0.215 daphnite 0.3773E+00 0.3773E+00 1.0000 -0.423 chlorite-Mn 0.1331E-01 0.1331E-01 1.0000 -1.876 hematite 0.1000E+01 0.1000E+01 1.0000 0.000 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 paragonite 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 nontronite-Na 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 3.015429 g Volume = 1.316146 cm3 Porosity: 37.9059% V(tot) - V(min): 0.80345E+00 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 2.7990000 g log = 0.4470 Original solution: 1000.0103000 g Original solution / Rock added: 357.27 (Water/Rock Ratio), log = 2.5530 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0203 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.1000E+01 0.9860 0.1006E+01 0.1020E+01 CO2,gas 0.7361E-06 1.0071 0.7563E-06 0.7510E-06 CH4,gas 0.3257E-16 1.0125 0.3364E-16 0.3323E-16 H2,gas 0.8003E-06 1.0005 0.8170E-06 0.8165E-06 H2S,gas 0.1447E-14 0.9960 0.1470E-14 0.1476E-14 S2,gas 0.1191E-36 1.0000 0.1216E-36 0.1216E-36 CO,gas 0.1614E-15 1.0000 0.1647E-15 0.1647E-15 SO3,gas 0.9017E-39 1.0000 0.9200E-39 0.9200E-39 SO2,gas 0.2866E-22 1.0000 0.2924E-22 0.2924E-22 HCl,gas 0.1440E-16 1.0000 0.1469E-16 0.1469E-16 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 32 apatite-OH -18.15 -18.15 0.00 0.000 -0.12132E-10 46 clinochlore 39.07 39.07 0.00 0.000 -0.24265E-10 47 daphnite 28.97 28.97 0.00 0.000 -0.60662E-10 48 chlorite-Mn 46.87 46.87 0.00 0.000 -0.36397E-10 90 hematite 12.57 12.57 0.00 0.000 0.90992E-11 116 microcline -2.49 -2.49 0.00 0.000 0.15165E-11 121 paragonite 4.24 4.24 0.00 0.000 -0.34880E-10 163 stilbite -7.52 -7.52 0.00 0.000 -0.33364E-10 209 nontronite-Na 3.52 3.52 0.00 0.000 0.11374E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -14.48 -7.82 -2.607 0.13353E+05 -6.121 3 CH4,gas 4.54 -13.63 -18.17 -4.543 0.31028E+05 -16.473 4 H2,gas 8.00 0.21 -7.79 -4.450 0.13296E+05 -6.088 5 H2S,gas -6.23 -22.76 -16.53 -8.266 0.28227E+05 -14.833 6 S2,gas -7.34 -45.95 -38.61 -5.941 0.65933E+05 -36.915 7 CO,gas 3.21 -14.27 -17.48 -5.379 0.29851E+05 -15.783 8 SO3,gas 17.12 -23.61 -40.74 -10.184 0.69554E+05 -39.036 9 SO2,gas 0.83 -23.40 -24.23 -6.462 0.41377E+05 -22.534 10 HCl,gas 5.19 -13.34 -18.53 -9.266 0.31643E+05 -16.833 11 acmite 7.71 6.61 -1.10 -0.115 0.18858E+04 15 albite-high 0.69 -0.58 -1.27 -0.098 0.21655E+04 16 albite -0.38 -0.58 -0.19 -0.015 0.32673E+03 19 spessartine 24.46 20.45 -4.00 -0.200 0.68352E+04 20 analcite 3.32 2.73 -0.59 -0.066 0.10114E+04 21 andalusite 5.00 1.51 -3.49 -0.349 0.59618E+04 22 andradite 39.01 35.04 -3.97 -0.206 0.67746E+04 26 annite 20.12 16.68 -3.44 -0.191 0.58756E+04 27 phlogopite 27.06 23.37 -3.69 -0.205 0.63089E+04 29 anorthite 12.71 9.00 -3.71 -0.285 0.63326E+04 35 aragonite 0.97 -3.68 -4.65 -1.550 0.79407E+04 36 brucite 12.57 8.62 -3.95 -0.790 0.67442E+04 37 calcite 0.81 -3.68 -4.50 -1.499 0.76764E+04 38 carnegieite-low 9.02 6.03 -2.99 -0.427 0.51037E+04 39 carnegieite-high 10.09 6.03 -4.06 -0.580 0.69307E+04 40 carpholite-Mg 8.58 6.82 -1.76 -0.117 0.30020E+04 41 carpholite-Fe 6.71 4.59 -2.12 -0.141 0.36162E+04 42 celadonite 5.34 2.83 -2.51 -0.148 0.42927E+04 43 celadonite-Fe 3.88 0.60 -3.28 -0.193 0.55974E+04 44 chrysotile 23.89 19.25 -4.65 -0.387 0.79323E+04 50 chloritoid-Mg 13.20 10.13 -3.07 -0.205 0.52403E+04 51 chloritoid-Fe 9.17 7.90 -1.27 -0.085 0.21755E+04 52 chloritoid-Mn 11.40 10.03 -1.37 -0.092 0.23448E+04 54 coesite -2.38 -3.30 -0.93 -0.310 0.15857E+04 59 corundum 8.38 4.81 -3.57 -0.324 0.60931E+04 61 cristobalite -2.56 -3.30 -0.74 -0.248 0.12710E+04 63 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71234E+04 65 diaspore 2.87 2.41 -0.47 -0.078 0.79632E+03 67 diopside 16.18 12.81 -3.38 -0.338 0.57639E+04 68 hedenbergite 14.21 10.58 -3.63 -0.363 0.62011E+04 75 epidote 24.67 22.78 -1.89 -0.092 0.32333E+04 76 clinozoisite 22.81 18.90 -3.91 -0.178 0.66685E+04 77 epidote-Fe 29.84 26.65 -3.19 -0.166 0.54447E+04 78 fayalite 14.05 9.47 -4.57 -0.653 0.78053E+04 79 ferrosilite 11.15 6.17 -4.98 -0.498 0.85027E+04 83 gibbsite 4.08 2.41 -1.67 -0.239 0.28549E+04 84 glaucophane 22.97 18.10 -4.88 -0.132 0.83299E+04 87 greenalite 16.14 12.56 -3.58 -0.298 0.61131E+04 91 heulandite -5.83 -7.52 -1.69 -0.077 0.28938E+04 95 jadeite 4.22 2.73 -1.49 -0.149 0.25369E+04 97 kalsilite 7.58 4.12 -3.46 -0.494 0.59095E+04 98 kaolinite -1.33 -1.79 -0.46 -0.042 0.78891E+03 99 kyanite 4.88 1.51 -3.37 -0.337 0.57477E+04 101 laumontite 2.88 2.39 -0.49 -0.033 0.83886E+03 102 lawsonite 9.62 9.00 -0.61 -0.041 0.10492E+04 103 leucite 4.12 0.82 -3.30 -0.330 0.56357E+04 105 lizardite 23.24 19.25 -4.00 -0.333 0.68249E+04 107 magnetite 20.09 18.96 -1.13 -0.092 0.19322E+04 108 minnesotaite 10.39 5.95 -4.44 -0.261 0.75781E+04 113 margarite 17.32 13.82 -3.51 -0.140 0.59888E+04 120 muscovite 2.58 2.33 -0.25 -0.015 0.43417E+03 122 nepheline 8.34 6.03 -2.31 -0.329 0.39361E+04 134 phlogopite-Na 29.65 25.28 -4.37 -0.243 0.74545E+04 136 prehnite 19.37 16.49 -2.88 -0.169 0.49152E+04 137 prehnite-Fe 22.50 20.37 -2.13 -0.128 0.36350E+04 138 pumpellyite-Fe 46.27 41.78 -4.49 -0.100 0.76598E+04 139 pumpellyite-Mg 48.99 44.01 -4.98 -0.111 0.85073E+04 145 pyroxmangite 7.40 5.21 -2.19 -0.437 0.37317E+04 146 pyrophyllite -6.18 -8.40 -2.23 -0.139 0.38050E+04 147 quartz -2.99 -3.30 -0.32 -0.105 0.53835E+03 151 rhodochrosite -0.98 -5.96 -4.99 -1.662 0.85137E+04 152 rhodonite 7.45 5.21 -2.23 -0.446 0.38119E+04 153 sanidine -1.28 -2.49 -1.21 -0.093 0.20677E+04 156 sillimanite 5.26 1.51 -3.75 -0.375 0.64058E+04 164 stilpnomelane-Fe 13.02 12.83 -0.18 -0.005 0.31072E+03 165 stilpnomelane-Mg 27.44 23.98 -3.46 -0.103 0.59091E+04 168 sudoite 21.08 16.95 -4.12 -0.133 0.70429E+04 171 talc 16.49 12.64 -3.85 -0.227 0.65802E+04 174 tephroite 18.09 13.73 -4.35 -0.622 0.74355E+04 177 topaz-H 4.62 1.51 -3.11 -0.283 0.53078E+04 178 tridymite -2.63 -3.30 -0.68 -0.226 0.11583E+04 187 wairakite 3.95 2.39 -1.56 -0.092 0.26608E+04 188 walstromite 11.51 7.49 -4.02 -0.804 0.68599E+04 189 wollastonite 10.46 7.49 -2.97 -0.594 0.50703E+04 190 pseudo-wollastonite 11.00 7.49 -3.51 -0.702 0.59902E+04 191 zoisite 22.85 18.90 -3.95 -0.179 0.67426E+04 192 akaganeite 7.75 6.28 -1.47 -0.318 0.25125E+04 193 beidellite-Ca -1.65 -4.74 -3.09 -0.191 0.52800E+04 194 beidellite-H -2.33 -6.52 -4.19 -0.268 0.71595E+04 195 beidellite-K -1.52 -4.86 -3.34 -0.205 0.57069E+04 196 beidellite-Mg -1.79 -5.10 -3.31 -0.205 0.56473E+04 197 beidellite-Na -1.34 -4.23 -2.89 -0.177 0.49339E+04 199 chalcedony -2.80 -3.30 -0.50 -0.167 0.85765E+03 201 montmorillonite-Ca -2.29 -4.57 -2.28 -0.141 0.38971E+04 202 montmorillonite-K -2.24 -4.70 -2.46 -0.151 0.42022E+04 203 montmorillonite-Mg -2.48 -4.93 -2.45 -0.152 0.41876E+04 204 montmorillonite-Na -2.04 -4.07 -2.03 -0.124 0.34649E+04 205 nontronite-Ca 3.21 3.01 -0.20 -0.013 0.34299E+03 206 nontronite-H 2.53 1.23 -1.30 -0.087 0.22205E+04 207 nontronite-K 3.34 2.89 -0.45 -0.029 0.77130E+03 208 nontronite-Mg 3.07 2.65 -0.42 -0.027 0.71760E+03 224 tobermorite 9.82 5.69 -4.13 -1.128 0.70594E+04 233 boehmite 4.41 2.41 -2.00 -0.333 0.34132E+04 235 ferrous-oxide 9.81 6.39 -3.42 -0.855 0.58430E+04 240 silica-amorphous -2.09 -3.30 -1.21 -0.404 0.20718E+04 242 an20ab80 2.02 1.34 -0.68 -0.052 0.11570E+04 243 an25ab75 2.65 1.82 -0.83 -0.064 0.14116E+04 244 an30ab70 3.28 2.30 -0.98 -0.075 0.16758E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 0.1000000 g Current total amount of reactant added: 2.7990000 g New total amount of reactant added: 2.8990000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.8098E-13 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 6 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 2.8990000 Water: Moles liquid = 0.5548E+02 kg liquid = 0.9995E+00 Moles total = 0.5547E+02 kg total = 0.9993E+00 Activity = 1.0000 Stoichiometric ionic strength = .2164872E-02 Osmotic coef. = 0.9739 True ionic strength = .3578800E-02 Chg. balance for total moles = 0.8098E-13 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.38279E-09 -9.4170 0.34897E-09 -9.4572 0.91167E+00 -0.0402 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13791E-03 -3.8604 0.12556E-03 -3.9012 0.91040E+00 -0.0408 4 SO4-- 0.25506E-04 -4.5934 0.18542E-04 -4.7318 0.72696E+00 -0.1385 5 HCO3- 0.99488E-05 -5.0022 0.90605E-05 -5.0428 0.91071E+00 -0.0406 6 HS- 0.54635E-13 -13.2625 0.49741E-13 -13.3033 0.91043E+00 -0.0408 7 Al+++ 0.21440E-25 -25.6688 0.10666E-25 -25.9720 0.49749E+00 -0.3032 8 H4SiO4 0.49360E-03 -3.3066 0.49360E-03 -3.3066 0.10000E+01 0.0000 9 Ca++ 0.11217E-07 -7.9501 0.81404E-08 -8.0894 0.72575E+00 -0.1392 10 Mg++ 0.70503E-10 -10.1518 0.51114E-10 -10.2915 0.72498E+00 -0.1397 11 Fe++ 0.41587E-12 -12.3810 0.30158E-12 -12.5206 0.72517E+00 -0.1396 12 K+ 0.41413E-04 -4.3829 0.37718E-04 -4.4235 0.91076E+00 -0.0406 13 Na+ 0.34995E-02 -2.4560 0.31859E-02 -2.4968 0.91037E+00 -0.0408 14 Mn++ 0.55873E-10 -10.2528 0.40525E-10 -10.3923 0.72531E+00 -0.1395 15 HPO4-- 0.91193E-05 -5.0400 0.66296E-05 -5.1785 0.72699E+00 -0.1385 16 HSiO3- 0.14507E-02 -2.8384 0.13207E-02 -2.8792 0.91040E+00 -0.0408 17 Ca(HSiO3)+ 0.26882E-09 -9.5705 0.24485E-09 -9.6111 0.91081E+00 -0.0406 18 Mg(HSiO3)+ 0.21007E-11 -11.6776 0.19133E-11 -11.7182 0.91081E+00 -0.0406 19 NaHSiO3,aq 0.68053E-04 -4.1672 0.68053E-04 -4.1672 0.10000E+01 0.0000 20 AlO+ 0.13082E-13 -13.8833 0.11915E-13 -13.9239 0.91081E+00 -0.0406 21 AlOH+2 0.28539E-19 -19.5446 0.20704E-19 -19.6839 0.72547E+00 -0.1394 22 HAlO2,aq 0.67994E-08 -8.1675 0.67994E-08 -8.1675 0.10000E+01 0.0000 23 AlO2- 0.47394E-04 -4.3243 0.43130E-04 -4.3652 0.91002E+00 -0.0409 24 CH4,aq 0.23626E-19 -19.6266 0.23610E-19 -19.6269 0.99933E+00 -0.0003 29 CO,aq 0.10769E-18 -18.9678 0.10769E-18 -18.9678 0.10000E+01 0.0000 30 CO2,aq 0.67607E-08 -8.1700 0.67562E-08 -8.1703 0.99933E+00 -0.0003 31 CO3-2 0.31211E-05 -5.5057 0.22678E-05 -5.6444 0.72660E+00 -0.1387 32 CaCO3,aq 0.23148E-09 -9.6355 0.23148E-09 -9.6355 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.20671E-11 -11.6846 0.18827E-11 -11.7252 0.91081E+00 -0.0406 34 CaCl+ 0.18160E-11 -11.7409 0.16541E-11 -11.7814 0.91081E+00 -0.0406 35 CaCl2,aq 0.49340E-16 -16.3068 0.49340E-16 -16.3068 0.10000E+01 0.0000 36 CaOH+ 0.18253E-08 -8.7387 0.16625E-08 -8.7792 0.91081E+00 -0.0406 37 CaSO4,aq 0.47930E-10 -10.3194 0.47930E-10 -10.3194 0.10000E+01 0.0000 38 HCl,aq 0.80292E-14 -14.0953 0.80292E-14 -14.0953 0.10000E+01 0.0000 43 FeCl+ 0.65804E-16 -16.1817 0.59934E-16 -16.2223 0.91081E+00 -0.0406 46 FeO,aq 0.96245E-10 -10.0166 0.96245E-10 -10.0166 0.10000E+01 0.0000 47 FeOH+ 0.30885E-10 -10.5103 0.28130E-10 -10.5508 0.91081E+00 -0.0406 48 HFeO2- 0.31696E-08 -8.4990 0.28857E-08 -8.5398 0.91040E+00 -0.0408 49 FeO+ 0.29245E-14 -14.5339 0.26637E-14 -14.5745 0.91081E+00 -0.0406 51 FeO2- 0.49160E-08 -8.3084 0.44755E-08 -8.3492 0.91040E+00 -0.0408 52 HFeO2,aq 0.19864E-09 -9.7019 0.19864E-09 -9.7019 0.10000E+01 0.0000 53 H2,aq 0.63492E-09 -9.1973 0.63449E-09 -9.1976 0.99933E+00 -0.0003 54 KCl,aq 0.85831E-10 -10.0664 0.85831E-10 -10.0664 0.10000E+01 0.0000 55 KHSO4,aq 0.69004E-18 -18.1611 0.69004E-18 -18.1611 0.10000E+01 0.0000 56 KOH,aq 0.46157E-07 -7.3358 0.46157E-07 -7.3358 0.10000E+01 0.0000 57 KSO4- 0.11920E-07 -7.9237 0.10852E-07 -7.9645 0.91040E+00 -0.0408 58 MgCO3,aq 0.36431E-12 -12.4385 0.36431E-12 -12.4385 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.13262E-13 -13.8774 0.12079E-13 -13.9180 0.91081E+00 -0.0406 60 MgCl+ 0.10335E-13 -13.9857 0.94131E-14 -14.0263 0.91081E+00 -0.0406 61 MgOH+ 0.63419E-10 -10.1978 0.57763E-10 -10.2384 0.91081E+00 -0.0406 63 MnO,aq 0.34461E-09 -9.4627 0.34461E-09 -9.4627 0.10000E+01 0.0000 64 MnOH+ 0.38554E-09 -9.4139 0.35115E-09 -9.4545 0.91081E+00 -0.0406 65 MnO2-2 0.12925E-12 -12.8886 0.93911E-13 -13.0273 0.72660E+00 -0.1387 66 HMnO2- 0.78866E-11 -11.1031 0.71799E-11 -11.1439 0.91040E+00 -0.0408 69 MnCl+ 0.34402E-13 -13.4634 0.31333E-13 -13.5040 0.91081E+00 -0.0406 70 MnSO4,aq 0.21693E-12 -12.6637 0.21693E-12 -12.6637 0.10000E+01 0.0000 71 NaCl,aq 0.13256E-06 -6.8776 0.13256E-06 -6.8776 0.10000E+01 0.0000 72 NaOH,aq 0.39223E-05 -5.4065 0.39223E-05 -5.4065 0.10000E+01 0.0000 74 OH- 0.18193E-02 -2.7401 0.16556E-02 -2.7810 0.91002E+00 -0.0409 79 HPO3-2 0.18041E-16 -16.7437 0.13109E-16 -16.8824 0.72660E+00 -0.1387 81 H2PO3- 0.10076E-19 -19.9967 0.91734E-20 -20.0375 0.91040E+00 -0.0408 82 H3PO4,aq 0.56467E-14 -14.2482 0.56467E-14 -14.2482 0.10000E+01 0.0000 83 H2PO4- 0.46869E-07 -7.3291 0.42679E-07 -7.3698 0.91060E+00 -0.0407 84 PO4-3 0.30805E-07 -7.5114 0.15500E-07 -7.8097 0.50316E+00 -0.2983 87 H2P2O7-2 0.19656E-15 -15.7065 0.14282E-15 -15.8452 0.72660E+00 -0.1387 88 HP2O7-3 0.16424E-12 -12.7845 0.81720E-13 -13.0877 0.49756E+00 -0.3032 89 P2O7-4 0.18969E-12 -12.7220 0.55943E-13 -13.2523 0.29492E+00 -0.5303 90 H2S,aq 0.53684E-16 -16.2702 0.53648E-16 -16.2704 0.99933E+00 -0.0003 97 SO3-2 0.20970E-14 -14.6784 0.15288E-14 -14.8156 0.72904E+00 -0.1373 98 HSO3- 0.36692E-16 -16.4354 0.33405E-16 -16.4762 0.91040E+00 -0.0408 99 HSO4- 0.68451E-11 -11.1646 0.62359E-11 -11.2051 0.91100E+00 -0.0405 Charge balance for all species = 0.9065E-13 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.3827857E-09 -.3534784E-02 -.3561822E+01 0.0000 2 H2O 0.1000000E+01 0.5550865E+02 0.9997162E+06 0.0000 3 Cl- 0.1379144E-03 0.1380470E-03 0.4892768E+01 5.5560 4 SO4-- 0.2550596E-04 0.2551842E-04 0.2450632E+01 14.1826 5 HCO3- 0.9948845E-05 0.1307690E-04 0.7976854E+00 4.4144 6 HS- 0.5463452E-13 -.4805468E-09 -.1588805E-04 -3.8461 7 Al+++ 0.2143969E-25 0.4740090E-04 0.1278578E+01 2.3996 8 H4SiO4 0.4936036E-03 0.2012359E-02 0.1933628E+03 -3.3066 9 Ca++ 0.1121653E-07 0.1359392E-07 0.5446598E-03 10.8251 10 Mg++ 0.7050298E-10 0.1364108E-09 0.3315461E-05 8.6229 11 Fe++ 0.4158724E-12 0.8411842E-08 0.4696405E-03 6.3938 12 K+ 0.4141317E-04 0.4147134E-04 0.1621144E+01 5.0337 13 Na+ 0.3499511E-02 0.3571619E-02 0.8208709E+02 6.9604 14 Mn++ 0.5587347E-10 0.7942969E-09 0.4362448E-04 8.5221 15 HPO4-- 0.9119277E-05 0.9196952E-05 0.8824593E+00 13.7359 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.4799010E-01 -.3532919E-02 -.4445718E-01 0.0000000E+00 2 H2O 0.5547191E+02 0.5547936E+02 -.7448915E-02 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.1058456E-03 0.2550495E-04 0.8034069E-04 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.8034117E-04 -.4802932E-09 -.8034069E-04 0.0000000E+00 7 Al+++ 0.9452890E-02 0.4737588E-04 0.9405514E-02 0.0000000E+00 8 H4SiO4 0.3018666E-01 0.2011297E-02 0.2817536E-01 0.0000000E+00 9 Ca++ 0.3348735E-02 0.1358675E-07 0.3348721E-02 0.0000000E+00 10 Mg++ 0.2300794E-02 0.1363388E-09 0.2300794E-02 0.0000000E+00 11 Fe++ 0.2067012E-02 0.8407403E-08 0.2067004E-02 0.0000000E+00 12 K+ 0.6154989E-03 0.4144945E-04 0.5740495E-03 0.0000000E+00 13 Na+ 0.3799022E-02 0.3569734E-02 0.2292882E-03 0.0000000E+00 14 Mn++ 0.5026459E-04 0.7938777E-09 0.5026380E-04 0.0000000E+00 15 HPO4-- 0.1715505E-04 0.9192099E-05 0.7962956E-05 0.0000000E+00 Chg. balance for solid moles: -.8132E-18 Mass of aqueous solution: 0.999761E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 2.8990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) apatite-OH 0.2654E-05 -5.576 0.1333E-02 -2.875 0.4267E-01 0.4237E-03 clinochlore 0.4602E-03 -3.337 0.2558 -0.592 8.185 0.9729E-01 daphnite 0.2849E-03 -3.545 0.2032 -0.692 6.505 0.6159E-01 chlorite-Mn 0.1005E-04 -4.998 0.7127E-02 -2.147 0.2281 0.2271E-02 hematite 0.2646E-03 -3.577 0.4226E-01 -1.374 1.353 0.8011E-02 microcline 0.5740E-03 -3.241 0.1598 -0.796 5.114 0.6241E-01 paragonite 0.2106E-03 -3.677 0.8048E-01 -1.094 2.576 0.2782E-01 stilbite 0.3335E-02 -2.477 2.351 0.371 75.23 1.096 nontronite-Na 0.5672E-04 -4.246 0.2412E-01 -1.618 0.7719 0.7493E-02 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.6094E+00 0.6094E+00 1.0000 -0.215 daphnite 0.3773E+00 0.3773E+00 1.0000 -0.423 chlorite-Mn 0.1331E-01 0.1331E-01 1.0000 -1.876 hematite 0.1000E+01 0.1000E+01 1.0000 0.000 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 paragonite 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 nontronite-Na 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 3.124680 g Volume = 1.363652 cm3 Porosity: 36.8563% V(tot) - V(min): 0.79595E+00 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 2.8990000 g log = 0.4622 Original solution: 1000.0103000 g Original solution / Rock added: 344.95 (Water/Rock Ratio), log = 2.5378 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0203 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.1000E+01 0.9860 0.1006E+01 0.1020E+01 CO2,gas 0.7035E-06 1.0071 0.7228E-06 0.7177E-06 CH4,gas 0.3364E-16 1.0125 0.3475E-16 0.3432E-16 H2,gas 0.8160E-06 1.0005 0.8330E-06 0.8326E-06 H2S,gas 0.1451E-14 0.9960 0.1475E-14 0.1481E-14 S2,gas 0.1153E-36 1.0000 0.1176E-36 0.1176E-36 CO,gas 0.1573E-15 1.0000 0.1605E-15 0.1605E-15 SO3,gas 0.8368E-39 1.0000 0.8538E-39 0.8538E-39 SO2,gas 0.2712E-22 1.0000 0.2767E-22 0.2767E-22 HCl,gas 0.1389E-16 1.0000 0.1417E-16 0.1417E-16 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 32 apatite-OH -18.15 -18.15 0.00 0.000 -0.60662E-11 46 clinochlore 39.07 39.07 0.00 0.000 -0.12132E-10 47 daphnite 28.97 28.97 0.00 0.000 0.12132E-10 48 chlorite-Mn 46.87 46.87 0.00 0.000 0.12132E-10 90 hematite 12.57 12.57 0.00 0.000 -0.90992E-11 116 microcline -2.49 -2.49 0.00 0.000 0.15165E-11 121 paragonite 4.24 4.24 0.00 0.000 0.13649E-10 163 stilbite -7.52 -7.52 0.00 0.000 0.15165E-10 209 nontronite-Na 3.52 3.52 0.00 0.000 -0.24265E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -14.50 -7.84 -2.613 0.13386E+05 -6.141 3 CH4,gas 4.54 -13.61 -18.16 -4.539 0.31004E+05 -16.459 4 H2,gas 8.00 0.22 -7.78 -4.445 0.13281E+05 -6.079 5 H2S,gas -6.23 -22.76 -16.53 -8.265 0.28225E+05 -14.831 6 S2,gas -7.34 -45.96 -38.63 -5.943 0.65957E+05 -36.929 7 CO,gas 3.21 -14.28 -17.49 -5.383 0.29870E+05 -15.795 8 SO3,gas 17.12 -23.65 -40.77 -10.192 0.69610E+05 -39.069 9 SO2,gas 0.83 -23.42 -24.26 -6.469 0.41418E+05 -22.558 10 HCl,gas 5.19 -13.36 -18.55 -9.274 0.31670E+05 -16.849 11 acmite 7.71 6.63 -1.08 -0.112 0.18431E+04 15 albite-high 0.69 -0.56 -1.25 -0.096 0.21392E+04 16 albite -0.38 -0.56 -0.18 -0.014 0.30042E+03 19 spessartine 24.46 20.45 -4.01 -0.201 0.68496E+04 20 analcite 3.32 2.75 -0.58 -0.064 0.98188E+03 21 andalusite 5.00 1.49 -3.51 -0.351 0.59914E+04 22 andradite 39.01 35.12 -3.89 -0.202 0.66374E+04 26 annite 20.12 16.69 -3.43 -0.190 0.58540E+04 27 phlogopite 27.06 23.38 -3.68 -0.205 0.62873E+04 29 anorthite 12.71 9.01 -3.70 -0.285 0.63164E+04 35 aragonite 0.97 -3.67 -4.64 -1.547 0.79253E+04 36 brucite 12.57 8.62 -3.95 -0.789 0.67370E+04 37 calcite 0.81 -3.67 -4.49 -1.496 0.76610E+04 38 carnegieite-low 9.02 6.05 -2.97 -0.424 0.50710E+04 39 carnegieite-high 10.09 6.05 -4.04 -0.577 0.68980E+04 40 carpholite-Mg 8.58 6.81 -1.77 -0.118 0.30276E+04 41 carpholite-Fe 6.71 4.58 -2.13 -0.142 0.36417E+04 42 celadonite 5.34 2.83 -2.51 -0.148 0.42888E+04 43 celadonite-Fe 3.88 0.60 -3.28 -0.193 0.55934E+04 44 chrysotile 23.89 19.26 -4.64 -0.386 0.79172E+04 50 chloritoid-Mg 13.20 10.12 -3.08 -0.205 0.52627E+04 51 chloritoid-Fe 9.17 7.89 -1.29 -0.086 0.21978E+04 52 chloritoid-Mn 11.40 10.01 -1.39 -0.092 0.23671E+04 54 coesite -2.38 -3.31 -0.93 -0.310 0.15889E+04 59 corundum 8.38 4.80 -3.58 -0.326 0.61194E+04 61 cristobalite -2.56 -3.31 -0.75 -0.249 0.12743E+04 63 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71234E+04 65 diaspore 2.87 2.40 -0.47 -0.079 0.80947E+03 67 diopside 16.18 12.83 -3.35 -0.335 0.57142E+04 68 hedenbergite 14.21 10.61 -3.60 -0.360 0.61514E+04 75 epidote 24.67 22.81 -1.86 -0.090 0.31713E+04 76 clinozoisite 22.81 18.93 -3.88 -0.176 0.66197E+04 77 epidote-Fe 29.84 26.70 -3.14 -0.163 0.53696E+04 78 fayalite 14.05 9.48 -4.56 -0.652 0.77941E+04 79 ferrosilite 11.15 6.17 -4.98 -0.498 0.84948E+04 83 gibbsite 4.08 2.40 -1.68 -0.240 0.28680E+04 84 glaucophane 22.97 18.14 -4.84 -0.131 0.82622E+04 87 greenalite 16.14 12.57 -3.57 -0.298 0.60979E+04 91 heulandite -5.83 -7.52 -1.69 -0.077 0.28938E+04 95 jadeite 4.22 2.75 -1.47 -0.147 0.25074E+04 97 kalsilite 7.58 4.13 -3.46 -0.494 0.59030E+04 98 kaolinite -1.33 -1.81 -0.48 -0.044 0.82169E+03 99 kyanite 4.88 1.49 -3.38 -0.338 0.57773E+04 101 laumontite 2.88 2.40 -0.49 -0.032 0.82915E+03 102 lawsonite 9.62 9.01 -0.61 -0.040 0.10330E+04 103 leucite 4.12 0.82 -3.30 -0.330 0.56325E+04 105 lizardite 23.24 19.26 -3.99 -0.332 0.68098E+04 107 magnetite 20.09 18.96 -1.13 -0.092 0.19250E+04 108 minnesotaite 10.39 5.95 -4.43 -0.261 0.75695E+04 113 margarite 17.32 13.81 -3.51 -0.141 0.59989E+04 120 muscovite 2.58 2.31 -0.27 -0.016 0.46048E+03 122 nepheline 8.34 6.05 -2.29 -0.327 0.39033E+04 134 phlogopite-Na 29.65 25.31 -4.34 -0.241 0.74066E+04 136 prehnite 19.37 16.53 -2.84 -0.167 0.48533E+04 137 prehnite-Fe 22.50 20.41 -2.08 -0.125 0.35599E+04 138 pumpellyite-Fe 46.27 41.85 -4.42 -0.098 0.75419E+04 139 pumpellyite-Mg 48.99 44.08 -4.91 -0.109 0.83894E+04 145 pyroxmangite 7.40 5.22 -2.18 -0.437 0.37277E+04 146 pyrophyllite -6.18 -8.43 -2.25 -0.141 0.38443E+04 147 quartz -2.99 -3.31 -0.32 -0.106 0.54159E+03 152 rhodonite 7.45 5.22 -2.23 -0.446 0.38079E+04 153 sanidine -1.28 -2.49 -1.21 -0.093 0.20677E+04 156 sillimanite 5.26 1.49 -3.77 -0.377 0.64353E+04 164 stilpnomelane-Fe 13.02 12.83 -0.18 -0.006 0.31548E+03 165 stilpnomelane-Mg 27.44 23.98 -3.46 -0.103 0.59139E+04 168 sudoite 21.08 16.92 -4.15 -0.134 0.70909E+04 171 talc 16.49 12.64 -3.85 -0.226 0.65716E+04 174 tephroite 18.09 13.74 -4.35 -0.621 0.74243E+04 177 topaz-H 4.62 1.49 -3.13 -0.284 0.53373E+04 178 tridymite -2.63 -3.31 -0.68 -0.227 0.11616E+04 187 wairakite 3.95 2.40 -1.55 -0.091 0.26511E+04 188 walstromite 11.51 7.52 -3.99 -0.798 0.68142E+04 189 wollastonite 10.46 7.52 -2.94 -0.589 0.50246E+04 190 pseudo-wollastonite 11.00 7.52 -3.48 -0.696 0.59444E+04 191 zoisite 22.85 18.93 -3.92 -0.178 0.66938E+04 192 akaganeite 7.75 6.28 -1.47 -0.318 0.25125E+04 193 beidellite-Ca -1.65 -4.76 -3.11 -0.193 0.53144E+04 194 beidellite-H -2.33 -6.54 -4.22 -0.269 0.72020E+04 195 beidellite-K -1.52 -4.88 -3.36 -0.206 0.57419E+04 196 beidellite-Mg -1.79 -5.12 -3.33 -0.206 0.56886E+04 197 beidellite-Na -1.34 -4.25 -2.91 -0.178 0.49602E+04 199 chalcedony -2.80 -3.31 -0.50 -0.168 0.86089E+03 201 montmorillonite-Ca -2.29 -4.59 -2.30 -0.142 0.39215E+04 202 montmorillonite-K -2.24 -4.71 -2.48 -0.152 0.42272E+04 203 montmorillonite-Mg -2.48 -4.95 -2.47 -0.153 0.42190E+04 204 montmorillonite-Na -2.04 -4.08 -2.04 -0.125 0.34812E+04 205 nontronite-Ca 3.21 3.01 -0.21 -0.013 0.35114E+03 206 nontronite-H 2.53 1.22 -1.31 -0.088 0.22367E+04 207 nontronite-K 3.34 2.88 -0.46 -0.029 0.77998E+03 208 nontronite-Mg 3.07 2.65 -0.43 -0.028 0.73264E+03 224 tobermorite 9.82 5.71 -4.11 -1.122 0.70218E+04 233 boehmite 4.41 2.40 -2.01 -0.334 0.34264E+04 235 ferrous-oxide 9.81 6.39 -3.42 -0.854 0.58358E+04 240 silica-amorphous -2.09 -3.31 -1.22 -0.405 0.20751E+04 242 an20ab80 2.02 1.35 -0.66 -0.051 0.11328E+04 243 an25ab75 2.65 1.83 -0.81 -0.063 0.13878E+04 244 an30ab70 3.28 2.31 -0.97 -0.074 0.16525E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 0.1000000 g Current total amount of reactant added: 2.8990000 g New total amount of reactant added: 2.9990000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.8098E-13 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 6 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 2.9990000 Water: Moles liquid = 0.5548E+02 kg liquid = 0.9995E+00 Moles total = 0.5547E+02 kg total = 0.9993E+00 Activity = 1.0000 Stoichiometric ionic strength = .2225686E-02 Osmotic coef. = 0.9736 True ionic strength = .3689270E-02 Chg. balance for total moles = 0.8098E-13 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.37038E-09 -9.4314 0.33731E-09 -9.4720 0.91073E+00 -0.0406 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13791E-03 -3.8604 0.12542E-03 -3.9016 0.90943E+00 -0.0412 4 SO4-- 0.25506E-04 -4.5933 0.18464E-04 -4.7337 0.72391E+00 -0.1403 5 HCO3- 0.98601E-05 -5.0061 0.89701E-05 -5.0472 0.90974E+00 -0.0411 6 HS- 0.56751E-13 -13.2460 0.51613E-13 -13.2872 0.90946E+00 -0.0412 7 Al+++ 0.19215E-25 -25.7164 0.94685E-26 -26.0237 0.49276E+00 -0.3074 8 H4SiO4 0.49152E-03 -3.3085 0.49152E-03 -3.3085 0.10000E+01 0.0000 9 Ca++ 0.11218E-07 -7.9501 0.81068E-08 -8.0912 0.72267E+00 -0.1411 10 Mg++ 0.66777E-10 -10.1754 0.48206E-10 -10.3169 0.72188E+00 -0.1415 11 Fe++ 0.39389E-12 -12.4046 0.28442E-12 -12.5460 0.72207E+00 -0.1414 12 K+ 0.41284E-04 -4.3842 0.37560E-04 -4.4253 0.90980E+00 -0.0411 13 Na+ 0.36103E-02 -2.4425 0.32832E-02 -2.4837 0.90940E+00 -0.0412 14 Mn++ 0.52920E-10 -10.2764 0.38220E-10 -10.4177 0.72221E+00 -0.1413 15 HPO4-- 0.88126E-05 -5.0549 0.63797E-05 -5.1952 0.72393E+00 -0.1403 16 HSiO3- 0.14961E-02 -2.8250 0.13606E-02 -2.8663 0.90943E+00 -0.0412 17 Ca(HSiO3)+ 0.27609E-09 -9.5589 0.25120E-09 -9.6000 0.90984E+00 -0.0410 18 Mg(HSiO3)+ 0.20432E-11 -11.6897 0.18590E-11 -11.7307 0.90984E+00 -0.0410 19 NaHSiO3,aq 0.72251E-04 -4.1412 0.72251E-04 -4.1412 0.10000E+01 0.0000 20 AlO+ 0.12443E-13 -13.9051 0.11321E-13 -13.9461 0.90984E+00 -0.0410 21 AlOH+2 0.26323E-19 -19.5797 0.19015E-19 -19.7209 0.72238E+00 -0.1412 22 HAlO2,aq 0.66839E-08 -8.1750 0.66839E-08 -8.1750 0.10000E+01 0.0000 23 AlO2- 0.48251E-04 -4.3165 0.43862E-04 -4.3579 0.90903E+00 -0.0414 24 CH4,aq 0.24373E-19 -19.6131 0.24356E-19 -19.6134 0.99931E+00 -0.0003 29 CO,aq 0.10500E-18 -18.9788 0.10500E-18 -18.9788 0.10000E+01 0.0000 30 CO2,aq 0.64698E-08 -8.1891 0.64653E-08 -8.1894 0.99931E+00 -0.0003 31 CO3-2 0.32103E-05 -5.4935 0.23228E-05 -5.6340 0.72354E+00 -0.1405 32 CaCO3,aq 0.23611E-09 -9.6269 0.23611E-09 -9.6269 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.20402E-11 -11.6903 0.18562E-11 -11.7314 0.90984E+00 -0.0410 34 CaCl+ 0.18085E-11 -11.7427 0.16454E-11 -11.7837 0.90984E+00 -0.0410 35 CaCl2,aq 0.49030E-16 -16.3095 0.49030E-16 -16.3095 0.10000E+01 0.0000 36 CaOH+ 0.18826E-08 -8.7252 0.17128E-08 -8.7663 0.90984E+00 -0.0410 37 CaSO4,aq 0.47533E-10 -10.3230 0.47533E-10 -10.3230 0.10000E+01 0.0000 38 HCl,aq 0.77525E-14 -14.1106 0.77525E-14 -14.1106 0.10000E+01 0.0000 43 FeCl+ 0.62058E-16 -16.2072 0.56463E-16 -16.2482 0.90984E+00 -0.0410 46 FeO,aq 0.97152E-10 -10.0125 0.97152E-10 -10.0125 0.10000E+01 0.0000 47 FeOH+ 0.30166E-10 -10.5205 0.27447E-10 -10.5615 0.90984E+00 -0.0410 48 HFeO2- 0.33137E-08 -8.4797 0.30136E-08 -8.5209 0.90943E+00 -0.0412 49 FeO+ 0.28298E-14 -14.5482 0.25747E-14 -14.5893 0.90984E+00 -0.0410 51 FeO2- 0.50914E-08 -8.2932 0.46302E-08 -8.3344 0.90943E+00 -0.0412 52 HFeO2,aq 0.19864E-09 -9.7019 0.19864E-09 -9.7019 0.10000E+01 0.0000 53 H2,aq 0.64696E-09 -9.1891 0.64652E-09 -9.1894 0.99931E+00 -0.0003 54 KCl,aq 0.85381E-10 -10.0686 0.85381E-10 -10.0686 0.10000E+01 0.0000 55 KHSO4,aq 0.66143E-18 -18.1795 0.66143E-18 -18.1795 0.10000E+01 0.0000 56 KOH,aq 0.47553E-07 -7.3228 0.47553E-07 -7.3228 0.10000E+01 0.0000 57 KSO4- 0.11834E-07 -7.9269 0.10762E-07 -7.9681 0.90943E+00 -0.0412 58 MgCO3,aq 0.35192E-12 -12.4536 0.35192E-12 -12.4536 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.12396E-13 -13.9067 0.11279E-13 -13.9477 0.90984E+00 -0.0410 60 MgCl+ 0.97467E-14 -14.0111 0.88680E-14 -14.0522 0.90984E+00 -0.0410 61 MgOH+ 0.61944E-10 -10.2080 0.56359E-10 -10.2490 0.90984E+00 -0.0410 63 MnO,aq 0.34786E-09 -9.4586 0.34786E-09 -9.4586 0.10000E+01 0.0000 64 MnOH+ 0.37658E-09 -9.4241 0.34262E-09 -9.4652 0.90984E+00 -0.0410 65 MnO2-2 0.14023E-12 -12.8532 0.10146E-12 -12.9937 0.72354E+00 -0.1405 66 HMnO2- 0.82450E-11 -11.0838 0.74982E-11 -11.1250 0.90943E+00 -0.0412 69 MnCl+ 0.32444E-13 -13.4889 0.29519E-13 -13.5299 0.90984E+00 -0.0410 70 MnSO4,aq 0.20373E-12 -12.6909 0.20373E-12 -12.6909 0.10000E+01 0.0000 71 NaCl,aq 0.13647E-06 -6.8650 0.13647E-06 -6.8650 0.10000E+01 0.0000 72 NaOH,aq 0.41819E-05 -5.3786 0.41819E-05 -5.3786 0.10000E+01 0.0000 74 OH- 0.18843E-02 -2.7249 0.17129E-02 -2.7663 0.90903E+00 -0.0414 79 HPO3-2 0.17765E-16 -16.7504 0.12854E-16 -16.8910 0.72354E+00 -0.1405 82 H3PO4,aq 0.50769E-14 -14.2944 0.50769E-14 -14.2944 0.10000E+01 0.0000 83 H2PO4- 0.43642E-07 -7.3601 0.39698E-07 -7.4012 0.90963E+00 -0.0411 84 PO4-3 0.30953E-07 -7.5093 0.15431E-07 -7.8116 0.49853E+00 -0.3023 87 H2P2O7-2 0.17078E-15 -15.7676 0.12357E-15 -15.9081 0.72354E+00 -0.1405 88 HP2O7-3 0.14843E-12 -12.8285 0.73148E-13 -13.1358 0.49283E+00 -0.3073 89 P2O7-4 0.17864E-12 -12.7480 0.51806E-13 -13.2856 0.29001E+00 -0.5376 90 H2S,aq 0.53844E-16 -16.2689 0.53807E-16 -16.2692 0.99931E+00 -0.0003 97 SO3-2 0.21367E-14 -14.6703 0.15513E-14 -14.8093 0.72603E+00 -0.1390 98 HSO3- 0.36026E-16 -16.4434 0.32763E-16 -16.4846 0.90943E+00 -0.0412 99 HSO4- 0.65956E-11 -11.1807 0.60023E-11 -11.2217 0.91004E+00 -0.0409 Charge balance for all species = 0.9037E-13 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.3703788E-09 -.3653122E-02 -.3681037E+01 0.0000 2 H2O 0.1000000E+01 0.5550867E+02 0.9997091E+06 0.0000 3 Cl- 0.1379129E-03 0.1380494E-03 0.4892817E+01 5.5703 4 SO4-- 0.2550649E-04 0.2551888E-04 0.2450658E+01 14.2103 5 HCO3- 0.9860138E-05 0.1307713E-04 0.7976934E+00 4.4248 6 HS- 0.5675120E-13 -.4994559E-09 -.1651311E-04 -3.8153 7 Al+++ 0.1921538E-25 0.4825803E-04 0.1301688E+01 2.3922 8 H4SiO4 0.4915245E-03 0.2059905E-02 0.1979299E+03 -3.3085 9 Ca++ 0.1121787E-07 0.1366402E-07 0.5474645E-03 10.8528 10 Mg++ 0.6677736E-10 0.1311387E-09 0.3187301E-05 8.6270 11 Fe++ 0.3938935E-12 0.8731441E-08 0.4874803E-03 6.3979 12 K+ 0.4128427E-04 0.4134374E-04 0.1616144E+01 5.0467 13 Na+ 0.3610327E-02 0.3686896E-02 0.8473590E+02 6.9883 14 Mn++ 0.5292031E-10 0.7859818E-09 0.4316748E-04 8.5262 15 HPO4-- 0.8812601E-05 0.8887198E-05 0.8527317E+00 13.7487 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.4964595E-01 -.3651131E-02 -.4599482E-01 0.0000000E+00 2 H2O 0.5547066E+02 0.5547841E+02 -.7750990E-02 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.1086170E-03 0.2550497E-04 0.8311201E-04 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.8311251E-04 -.4991837E-09 -.8311201E-04 0.0000000E+00 7 Al+++ 0.9778964E-02 0.4823172E-04 0.9730732E-02 0.0000000E+00 8 H4SiO4 0.3122794E-01 0.2058782E-02 0.2916915E-01 0.0000000E+00 9 Ca++ 0.3463749E-02 0.1365657E-07 0.3463735E-02 0.0000000E+00 10 Mg++ 0.2380159E-02 0.1310672E-09 0.2380159E-02 0.0000000E+00 11 Fe++ 0.2138313E-02 0.8726681E-08 0.2138304E-02 0.0000000E+00 12 K+ 0.6367304E-03 0.4132120E-04 0.5954092E-03 0.0000000E+00 13 Na+ 0.3924547E-02 0.3684886E-02 0.2396604E-03 0.0000000E+00 14 Mn++ 0.5199845E-04 0.7855534E-09 0.5199766E-04 0.0000000E+00 15 HPO4-- 0.1774681E-04 0.8882353E-05 0.8864459E-05 0.0000000E+00 Chg. balance for solid moles: 0.8250E-17 Mass of aqueous solution: 0.999751E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 2.9990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) apatite-OH 0.2955E-05 -5.529 0.1484E-02 -2.828 0.4590E-01 0.4716E-03 clinochlore 0.4760E-03 -3.322 0.2646 -0.577 8.182 0.1006 daphnite 0.2947E-03 -3.531 0.2103 -0.677 6.502 0.6371E-01 chlorite-Mn 0.1040E-04 -4.983 0.7373E-02 -2.132 0.2280 0.2350E-02 hematite 0.2661E-03 -3.575 0.4249E-01 -1.372 1.314 0.8054E-02 microcline 0.5954E-03 -3.225 0.1657 -0.781 5.125 0.6474E-01 paragonite 0.2178E-03 -3.662 0.8323E-01 -1.080 2.574 0.2877E-01 stilbite 0.3449E-02 -2.462 2.431 0.386 75.16 1.134 nontronite-Na 0.6637E-04 -4.178 0.2823E-01 -1.549 0.8728 0.8768E-02 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.6094E+00 0.6094E+00 1.0000 -0.215 daphnite 0.3773E+00 0.3773E+00 1.0000 -0.423 chlorite-Mn 0.1331E-01 0.1331E-01 1.0000 -1.876 hematite 0.1000E+01 0.1000E+01 1.0000 0.000 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 paragonite 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 nontronite-Na 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 3.233931 g Volume = 1.411160 cm3 Porosity: 35.8447% V(tot) - V(min): 0.78844E+00 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 2.9990000 g log = 0.4770 Original solution: 1000.0103000 g Original solution / Rock added: 333.45 (Water/Rock Ratio), log = 2.5230 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0203 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.1000E+01 0.9860 0.1006E+01 0.1020E+01 CO2,gas 0.6732E-06 1.0071 0.6917E-06 0.6868E-06 CH4,gas 0.3470E-16 1.0125 0.3585E-16 0.3541E-16 H2,gas 0.8315E-06 1.0005 0.8488E-06 0.8483E-06 H2S,gas 0.1455E-14 0.9960 0.1479E-14 0.1485E-14 S2,gas 0.1117E-36 1.0000 0.1140E-36 0.1140E-36 CO,gas 0.1534E-15 1.0000 0.1565E-15 0.1565E-15 SO3,gas 0.7786E-39 1.0000 0.7944E-39 0.7944E-39 SO2,gas 0.2571E-22 1.0000 0.2623E-22 0.2623E-22 HCl,gas 0.1341E-16 1.0000 0.1368E-16 0.1368E-16 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 32 apatite-OH -18.15 -18.15 0.00 0.000 0.00000E+00 46 clinochlore 39.07 39.07 0.00 0.000 0.24265E-10 47 daphnite 28.97 28.97 0.00 0.000 0.24265E-10 48 chlorite-Mn 46.87 46.87 0.00 0.000 0.60662E-10 90 hematite 12.57 12.57 0.00 0.000 -0.30331E-11 116 microcline -2.49 -2.49 0.00 0.000 0.13649E-10 121 paragonite 4.24 4.24 0.00 0.000 0.13649E-10 163 stilbite -7.52 -7.52 0.00 0.000 0.15165E-10 209 nontronite-Na 3.52 3.52 0.00 0.000 -0.68244E-11 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -14.52 -7.86 -2.620 0.13419E+05 -6.160 3 CH4,gas 4.54 -13.60 -18.14 -4.536 0.30981E+05 -16.446 4 H2,gas 8.00 0.23 -7.77 -4.440 0.13267E+05 -6.071 5 H2S,gas -6.23 -22.76 -16.53 -8.264 0.28223E+05 -14.830 6 S2,gas -7.34 -45.98 -38.64 -5.945 0.65980E+05 -36.943 7 CO,gas 3.21 -14.29 -17.50 -5.386 0.29888E+05 -15.806 8 SO3,gas 17.12 -23.68 -40.80 -10.200 0.69663E+05 -39.100 9 SO2,gas 0.83 -23.45 -24.28 -6.475 0.41458E+05 -22.581 10 HCl,gas 5.19 -13.37 -18.56 -9.281 0.31696E+05 -16.864 11 acmite 7.71 6.65 -1.06 -0.110 0.18018E+04 15 albite-high 0.69 -0.54 -1.24 -0.095 0.21138E+04 16 albite -0.38 -0.54 -0.16 -0.012 0.27500E+03 19 spessartine 24.46 20.44 -4.02 -0.201 0.68635E+04 20 analcite 3.32 2.76 -0.56 -0.062 0.95333E+03 21 andalusite 5.00 1.48 -3.53 -0.353 0.60199E+04 22 andradite 39.01 35.20 -3.81 -0.198 0.65048E+04 26 annite 20.12 16.71 -3.42 -0.190 0.58331E+04 27 phlogopite 27.06 23.39 -3.67 -0.204 0.62664E+04 29 anorthite 12.71 9.02 -3.69 -0.284 0.63007E+04 35 aragonite 0.97 -3.67 -4.63 -1.544 0.79106E+04 36 brucite 12.57 8.63 -3.94 -0.788 0.67301E+04 37 calcite 0.81 -3.67 -4.48 -1.493 0.76463E+04 38 carnegieite-low 9.02 6.07 -2.95 -0.422 0.50393E+04 39 carnegieite-high 10.09 6.07 -4.02 -0.574 0.68663E+04 40 carpholite-Mg 8.58 6.79 -1.79 -0.119 0.30523E+04 41 carpholite-Fe 6.71 4.57 -2.15 -0.143 0.36665E+04 42 celadonite 5.34 2.83 -2.51 -0.148 0.42849E+04 43 celadonite-Fe 3.88 0.60 -3.27 -0.193 0.55896E+04 44 chrysotile 23.89 19.26 -4.63 -0.386 0.79026E+04 50 chloritoid-Mg 13.20 10.10 -3.09 -0.206 0.52842E+04 51 chloritoid-Fe 9.17 7.87 -1.30 -0.087 0.22194E+04 52 chloritoid-Mn 11.40 10.00 -1.40 -0.093 0.23887E+04 54 coesite -2.38 -3.31 -0.93 -0.311 0.15920E+04 59 corundum 8.38 4.78 -3.60 -0.327 0.61448E+04 61 cristobalite -2.56 -3.31 -0.75 -0.249 0.12774E+04 63 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71234E+04 65 diaspore 2.87 2.39 -0.48 -0.080 0.82218E+03 67 diopside 16.18 12.86 -3.32 -0.332 0.56662E+04 68 hedenbergite 14.21 10.63 -3.57 -0.357 0.61034E+04 75 epidote 24.67 22.85 -1.82 -0.088 0.31115E+04 76 clinozoisite 22.81 18.96 -3.85 -0.175 0.65726E+04 77 epidote-Fe 29.84 26.74 -3.10 -0.161 0.52970E+04 78 fayalite 14.05 9.49 -4.56 -0.651 0.77834E+04 79 ferrosilite 11.15 6.18 -4.97 -0.497 0.84871E+04 83 gibbsite 4.08 2.39 -1.69 -0.241 0.28807E+04 84 glaucophane 22.97 18.17 -4.80 -0.130 0.81967E+04 87 greenalite 16.14 12.58 -3.56 -0.297 0.60833E+04 91 heulandite -5.83 -7.52 -1.69 -0.077 0.28938E+04 95 jadeite 4.22 2.76 -1.45 -0.145 0.24788E+04 97 kalsilite 7.58 4.13 -3.45 -0.493 0.58967E+04 98 kaolinite -1.33 -1.83 -0.50 -0.045 0.85337E+03 99 kyanite 4.88 1.48 -3.40 -0.340 0.58058E+04 101 laumontite 2.88 2.40 -0.48 -0.032 0.81976E+03 102 lawsonite 9.62 9.02 -0.60 -0.040 0.10174E+04 103 leucite 4.12 0.82 -3.30 -0.330 0.56294E+04 105 lizardite 23.24 19.26 -3.98 -0.332 0.67952E+04 107 magnetite 20.09 18.96 -1.12 -0.092 0.19180E+04 108 minnesotaite 10.39 5.96 -4.43 -0.260 0.75611E+04 113 margarite 17.32 13.80 -3.52 -0.141 0.60087E+04 120 muscovite 2.58 2.30 -0.28 -0.017 0.48590E+03 122 nepheline 8.34 6.07 -2.27 -0.324 0.38716E+04 134 phlogopite-Na 29.65 25.34 -4.31 -0.239 0.73602E+04 136 prehnite 19.37 16.56 -2.81 -0.165 0.47934E+04 137 prehnite-Fe 22.50 20.46 -2.04 -0.123 0.34873E+04 138 pumpellyite-Fe 46.27 41.92 -4.35 -0.097 0.74280E+04 139 pumpellyite-Mg 48.99 44.15 -4.85 -0.108 0.82754E+04 145 pyroxmangite 7.40 5.22 -2.18 -0.436 0.37239E+04 146 pyrophyllite -6.18 -8.45 -2.27 -0.142 0.38822E+04 147 quartz -2.99 -3.31 -0.32 -0.106 0.54472E+03 152 rhodonite 7.45 5.22 -2.23 -0.446 0.38041E+04 153 sanidine -1.28 -2.49 -1.21 -0.093 0.20677E+04 156 sillimanite 5.26 1.48 -3.79 -0.379 0.64639E+04 164 stilpnomelane-Fe 13.02 12.83 -0.19 -0.006 0.32008E+03 165 stilpnomelane-Mg 27.44 23.98 -3.47 -0.103 0.59185E+04 168 sudoite 21.08 16.90 -4.18 -0.135 0.71372E+04 171 talc 16.49 12.65 -3.84 -0.226 0.65632E+04 174 tephroite 18.09 13.74 -4.34 -0.620 0.74135E+04 177 topaz-H 4.62 1.48 -3.14 -0.286 0.53659E+04 178 tridymite -2.63 -3.31 -0.68 -0.227 0.11647E+04 187 wairakite 3.95 2.40 -1.55 -0.091 0.26417E+04 188 walstromite 11.51 7.54 -3.96 -0.793 0.67700E+04 189 wollastonite 10.46 7.54 -2.92 -0.583 0.49804E+04 190 pseudo-wollastonite 11.00 7.54 -3.46 -0.691 0.59002E+04 191 zoisite 22.85 18.96 -3.89 -0.177 0.66466E+04 192 akaganeite 7.75 6.28 -1.47 -0.318 0.25125E+04 193 beidellite-Ca -1.65 -4.78 -3.13 -0.194 0.53477E+04 194 beidellite-H -2.33 -6.57 -4.24 -0.271 0.72431E+04 195 beidellite-K -1.52 -4.90 -3.38 -0.207 0.57757E+04 196 beidellite-Mg -1.79 -5.14 -3.36 -0.208 0.57286E+04 197 beidellite-Na -1.34 -4.26 -2.92 -0.179 0.49856E+04 199 chalcedony -2.80 -3.31 -0.51 -0.169 0.86402E+03 201 montmorillonite-Ca -2.29 -4.60 -2.31 -0.143 0.39452E+04 202 montmorillonite-K -2.24 -4.73 -2.49 -0.152 0.42513E+04 203 montmorillonite-Mg -2.48 -4.97 -2.49 -0.154 0.42493E+04 204 montmorillonite-Na -2.04 -4.09 -2.05 -0.125 0.34970E+04 205 nontronite-Ca 3.21 3.00 -0.21 -0.014 0.35901E+03 206 nontronite-H 2.53 1.21 -1.32 -0.088 0.22524E+04 207 nontronite-K 3.34 2.88 -0.46 -0.030 0.78837E+03 208 nontronite-Mg 3.07 2.64 -0.44 -0.028 0.74717E+03 224 tobermorite 9.82 5.73 -4.09 -1.116 0.69855E+04 233 boehmite 4.41 2.39 -2.01 -0.336 0.34391E+04 235 ferrous-oxide 9.81 6.40 -3.41 -0.853 0.58288E+04 240 silica-amorphous -2.09 -3.31 -1.22 -0.406 0.20782E+04 242 an20ab80 2.02 1.37 -0.65 -0.050 0.11093E+04 243 an25ab75 2.65 1.85 -0.80 -0.061 0.13648E+04 244 an30ab70 3.28 2.32 -0.95 -0.073 0.16300E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 0.1000000 g Current total amount of reactant added: 2.9990000 g New total amount of reactant added: 3.0990000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.8097E-13 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 6 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 3.0990000 Water: Moles liquid = 0.5548E+02 kg liquid = 0.9994E+00 Moles total = 0.5547E+02 kg total = 0.9993E+00 Activity = 1.0000 Stoichiometric ionic strength = .2286497E-02 Osmotic coef. = 0.9732 True ionic strength = .3799681E-02 Chg. balance for total moles = 0.8097E-13 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.35878E-09 -9.4452 0.32642E-09 -9.4862 0.90981E+00 -0.0411 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13791E-03 -3.8604 0.12529E-03 -3.9021 0.90847E+00 -0.0417 4 SO4-- 0.25507E-04 -4.5933 0.18389E-04 -4.7355 0.72092E+00 -0.1421 5 HCO3- 0.97727E-05 -5.0100 0.88813E-05 -5.0515 0.90879E+00 -0.0415 6 HS- 0.58876E-13 -13.2301 0.53489E-13 -13.2717 0.90850E+00 -0.0417 7 Al+++ 0.17288E-25 -25.7623 0.84390E-26 -26.0737 0.48815E+00 -0.3114 8 H4SiO4 0.48952E-03 -3.3102 0.48952E-03 -3.3102 0.10000E+01 0.0000 9 Ca++ 0.11221E-07 -7.9500 0.80750E-08 -8.0929 0.71965E+00 -0.1429 10 Mg++ 0.63369E-10 -10.1981 0.45553E-10 -10.3415 0.71885E+00 -0.1434 11 Fe++ 0.37379E-12 -12.4274 0.26877E-12 -12.5706 0.71904E+00 -0.1432 12 K+ 0.41162E-04 -4.3855 0.37410E-04 -4.4270 0.90885E+00 -0.0415 13 Na+ 0.37211E-02 -2.4293 0.33803E-02 -2.4710 0.90844E+00 -0.0417 14 Mn++ 0.50219E-10 -10.2991 0.36117E-10 -10.4423 0.71919E+00 -0.1432 15 HPO4-- 0.85257E-05 -5.0693 0.61466E-05 -5.2114 0.72095E+00 -0.1421 16 HSiO3- 0.15414E-02 -2.8121 0.14003E-02 -2.8538 0.90847E+00 -0.0417 17 Ca(HSiO3)+ 0.28333E-09 -9.5477 0.25751E-09 -9.5892 0.90889E+00 -0.0415 18 Mg(HSiO3)+ 0.19891E-11 -11.7013 0.18079E-11 -11.7428 0.90889E+00 -0.0415 19 NaHSiO3,aq 0.76559E-04 -4.1160 0.76559E-04 -4.1160 0.10000E+01 0.0000 20 AlO+ 0.11855E-13 -13.9261 0.10775E-13 -13.9676 0.90889E+00 -0.0415 21 AlOH+2 0.24346E-19 -19.6136 0.17513E-19 -19.7566 0.71936E+00 -0.1431 22 HAlO2,aq 0.65740E-08 -8.1822 0.65740E-08 -8.1822 0.10000E+01 0.0000 23 AlO2- 0.49095E-04 -4.3090 0.44581E-04 -4.3508 0.90807E+00 -0.0419 24 CH4,aq 0.25112E-19 -19.6001 0.25095E-19 -19.6004 0.99929E+00 -0.0003 29 CO,aq 0.10245E-18 -18.9895 0.10245E-18 -18.9895 0.10000E+01 0.0000 30 CO2,aq 0.61989E-08 -8.2077 0.61945E-08 -8.2080 0.99929E+00 -0.0003 31 CO3-2 0.32982E-05 -5.4817 0.23766E-05 -5.6241 0.72055E+00 -0.1423 32 CaCO3,aq 0.24063E-09 -9.6187 0.24063E-09 -9.6187 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.20141E-11 -11.6959 0.18306E-11 -11.7374 0.90889E+00 -0.0415 34 CaCl+ 0.18014E-11 -11.7444 0.16372E-11 -11.7859 0.90889E+00 -0.0415 35 CaCl2,aq 0.48734E-16 -16.3122 0.48734E-16 -16.3122 0.10000E+01 0.0000 36 CaOH+ 0.19398E-08 -8.7122 0.17631E-08 -8.7537 0.90889E+00 -0.0415 37 CaSO4,aq 0.47152E-10 -10.3265 0.47152E-10 -10.3265 0.10000E+01 0.0000 38 HCl,aq 0.74941E-14 -14.1253 0.74941E-14 -14.1253 0.10000E+01 0.0000 43 FeCl+ 0.58642E-16 -16.2318 0.53300E-16 -16.2733 0.90889E+00 -0.0415 46 FeO,aq 0.98039E-10 -10.0086 0.98039E-10 -10.0086 0.10000E+01 0.0000 47 FeOH+ 0.29489E-10 -10.5303 0.26802E-10 -10.5718 0.90889E+00 -0.0415 48 HFeO2- 0.34592E-08 -8.4610 0.31426E-08 -8.5027 0.90847E+00 -0.0417 49 FeO+ 0.27412E-14 -14.5621 0.24915E-14 -14.6035 0.90889E+00 -0.0415 51 FeO2- 0.52669E-08 -8.2784 0.47848E-08 -8.3201 0.90847E+00 -0.0417 52 HFeO2,aq 0.19864E-09 -9.7019 0.19864E-09 -9.7019 0.10000E+01 0.0000 53 H2,aq 0.65883E-09 -9.1812 0.65837E-09 -9.1815 0.99929E+00 -0.0003 54 KCl,aq 0.84949E-10 -10.0708 0.84949E-10 -10.0708 0.10000E+01 0.0000 55 KHSO4,aq 0.63488E-18 -18.1973 0.63488E-18 -18.1973 0.10000E+01 0.0000 56 KOH,aq 0.48944E-07 -7.3103 0.48944E-07 -7.3103 0.10000E+01 0.0000 57 KSO4- 0.11750E-07 -7.9299 0.10675E-07 -7.9716 0.90847E+00 -0.0417 58 MgCO3,aq 0.34025E-12 -12.4682 0.34025E-12 -12.4682 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.11610E-13 -13.9352 0.10552E-13 -13.9767 0.90889E+00 -0.0415 60 MgCl+ 0.92102E-14 -14.0357 0.83711E-14 -14.0772 0.90889E+00 -0.0415 61 MgOH+ 0.60553E-10 -10.2179 0.55036E-10 -10.2594 0.90889E+00 -0.0415 63 MnO,aq 0.35104E-09 -9.4546 0.35104E-09 -9.4546 0.10000E+01 0.0000 64 MnOH+ 0.36812E-09 -9.4340 0.33458E-09 -9.4755 0.90889E+00 -0.0415 65 MnO2-2 0.15175E-12 -12.8189 0.10934E-12 -12.9612 0.72055E+00 -0.1423 66 HMnO2- 0.86070E-11 -11.0651 0.78192E-11 -11.1068 0.90847E+00 -0.0417 69 MnCl+ 0.30658E-13 -13.5135 0.27865E-13 -13.5549 0.90889E+00 -0.0415 70 MnSO4,aq 0.19173E-12 -12.7173 0.19173E-12 -12.7173 0.10000E+01 0.0000 71 NaCl,aq 0.14035E-06 -6.8528 0.14035E-06 -6.8528 0.10000E+01 0.0000 72 NaOH,aq 0.44494E-05 -5.3517 0.44494E-05 -5.3517 0.10000E+01 0.0000 74 OH- 0.19492E-02 -2.7101 0.17700E-02 -2.7520 0.90807E+00 -0.0419 79 HPO3-2 0.17502E-16 -16.7569 0.12611E-16 -16.8993 0.72055E+00 -0.1423 82 H3PO4,aq 0.45804E-14 -14.3391 0.45804E-14 -14.3391 0.10000E+01 0.0000 83 H2PO4- 0.40731E-07 -7.3901 0.37012E-07 -7.4317 0.90868E+00 -0.0416 84 PO4-3 0.31098E-07 -7.5073 0.15364E-07 -7.8135 0.49403E+00 -0.3062 87 H2P2O7-2 0.14907E-15 -15.8266 0.10741E-15 -15.9690 0.72055E+00 -0.1423 88 HP2O7-3 0.13458E-12 -12.8710 0.65706E-13 -13.1824 0.48823E+00 -0.3114 89 P2O7-4 0.16858E-12 -12.7732 0.48088E-13 -13.3180 0.28526E+00 -0.5448 90 H2S,aq 0.54000E-16 -16.2676 0.53962E-16 -16.2679 0.99929E+00 -0.0003 97 SO3-2 0.21757E-14 -14.6624 0.15732E-14 -14.8032 0.72309E+00 -0.1408 98 HSO3- 0.35393E-16 -16.4511 0.32153E-16 -16.4928 0.90847E+00 -0.0417 99 HSO4- 0.63629E-11 -11.1963 0.57846E-11 -11.2377 0.90910E+00 -0.0414 Charge balance for all species = 0.9014E-13 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.3587768E-09 -.3771417E-02 -.3800208E+01 0.0000 2 H2O 0.1000000E+01 0.5550868E+02 0.9997020E+06 0.0000 3 Cl- 0.1379114E-03 0.1380518E-03 0.4892866E+01 5.5841 4 SO4-- 0.2550702E-04 0.2551934E-04 0.2450685E+01 14.2370 5 HCO3- 0.9772667E-05 0.1307736E-04 0.7977015E+00 4.4347 6 HS- 0.5887630E-13 -.5184262E-09 -.1714019E-04 -3.7855 7 Al+++ 0.1728764E-25 0.4910108E-04 0.1324419E+01 2.3850 8 H4SiO4 0.4895214E-03 0.2107481E-02 0.2024998E+03 -3.3102 9 Ca++ 0.1122064E-07 0.1373537E-07 0.5503190E-03 10.8796 10 Mg++ 0.6336901E-10 0.1262721E-09 0.3068994E-05 8.6310 11 Fe++ 0.3737864E-12 0.9052668E-08 0.5054109E-03 6.4018 12 K+ 0.4116201E-04 0.4122279E-04 0.1611404E+01 5.0592 13 Na+ 0.3721057E-02 0.3802206E-02 0.8738541E+02 7.0152 14 Mn++ 0.5021865E-10 0.7783563E-09 0.4274835E-04 8.5302 15 HPO4-- 0.8525674E-05 0.8597504E-05 0.8249293E+00 13.7611 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.5130180E-01 -.3769295E-02 -.4753250E-01 0.0000000E+00 2 H2O 0.5546940E+02 0.5547746E+02 -.8052811E-02 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.1113883E-03 0.2550499E-04 0.8588334E-04 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.8588385E-04 -.5181345E-09 -.8588334E-04 0.0000000E+00 7 Al+++ 0.1010504E-01 0.4907346E-04 0.1005596E-01 0.0000000E+00 8 H4SiO4 0.3226921E-01 0.2106295E-02 0.3016292E-01 0.0000000E+00 9 Ca++ 0.3578763E-02 0.1372764E-07 0.3578749E-02 0.0000000E+00 10 Mg++ 0.2459524E-02 0.1262010E-09 0.2459524E-02 0.0000000E+00 11 Fe++ 0.2209614E-02 0.9047575E-08 0.2209605E-02 0.0000000E+00 12 K+ 0.6579618E-03 0.4119960E-04 0.6167622E-03 0.0000000E+00 13 Na+ 0.4050071E-02 0.3800067E-02 0.2500044E-03 0.0000000E+00 14 Mn++ 0.5373231E-04 0.7779184E-09 0.5373153E-04 0.0000000E+00 15 HPO4-- 0.1833857E-04 0.8592667E-05 0.9745903E-05 0.0000000E+00 Chg. balance for solid moles: 0.7034E-17 Mass of aqueous solution: 0.999741E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 3.0990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) apatite-OH 0.3249E-05 -5.488 0.1632E-02 -2.787 0.4881E-01 0.5185E-03 clinochlore 0.4919E-03 -3.308 0.2734 -0.563 8.178 0.1040 daphnite 0.3045E-03 -3.516 0.2173 -0.663 6.499 0.6584E-01 chlorite-Mn 0.1075E-04 -4.969 0.7619E-02 -2.118 0.2279 0.2428E-02 hematite 0.2676E-03 -3.573 0.4273E-01 -1.369 1.278 0.8099E-02 microcline 0.6168E-03 -3.210 0.1717 -0.765 5.135 0.6706E-01 paragonite 0.2249E-03 -3.648 0.8597E-01 -1.066 2.571 0.2972E-01 stilbite 0.3563E-02 -2.448 2.511 0.400 75.10 1.171 nontronite-Na 0.7597E-04 -4.119 0.3231E-01 -1.491 0.9664 0.1004E-01 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.6094E+00 0.6094E+00 1.0000 -0.215 daphnite 0.3773E+00 0.3773E+00 1.0000 -0.423 chlorite-Mn 0.1331E-01 0.1331E-01 1.0000 -1.876 hematite 0.1000E+01 0.1000E+01 1.0000 0.000 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 paragonite 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 nontronite-Na 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 3.343181 g Volume = 1.458670 cm3 Porosity: 34.8692% V(tot) - V(min): 0.78093E+00 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 3.0990000 g log = 0.4912 Original solution: 1000.0103000 g Original solution / Rock added: 322.69 (Water/Rock Ratio), log = 2.5088 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0203 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.1000E+01 0.9860 0.1006E+01 0.1020E+01 CO2,gas 0.6450E-06 1.0071 0.6627E-06 0.6581E-06 CH4,gas 0.3576E-16 1.0125 0.3694E-16 0.3648E-16 H2,gas 0.8467E-06 1.0005 0.8644E-06 0.8639E-06 H2S,gas 0.1460E-14 0.9960 0.1483E-14 0.1489E-14 S2,gas 0.1084E-36 1.0000 0.1105E-36 0.1105E-36 CO,gas 0.1496E-15 1.0000 0.1527E-15 0.1527E-15 SO3,gas 0.7261E-39 1.0000 0.7408E-39 0.7408E-39 SO2,gas 0.2442E-22 1.0000 0.2491E-22 0.2491E-22 HCl,gas 0.1296E-16 1.0000 0.1322E-16 0.1322E-16 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 32 apatite-OH -18.15 -18.15 0.00 0.000 -0.60662E-11 46 clinochlore 39.07 39.07 0.00 0.000 -0.12132E-10 47 daphnite 28.97 28.97 0.00 0.000 -0.24265E-10 48 chlorite-Mn 46.87 46.87 0.00 0.000 -0.24265E-10 90 hematite 12.57 12.57 0.00 0.000 0.90992E-11 116 microcline -2.49 -2.49 0.00 0.000 -0.10616E-10 121 paragonite 4.24 4.24 0.00 0.000 -0.10616E-10 163 stilbite -7.52 -7.52 0.00 0.000 -0.90992E-11 209 nontronite-Na 3.52 3.52 0.00 0.000 -0.68244E-11 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -14.54 -7.88 -2.626 0.13451E+05 -6.179 3 CH4,gas 4.54 -13.59 -18.13 -4.533 0.30959E+05 -16.433 4 H2,gas 8.00 0.24 -7.76 -4.436 0.13254E+05 -6.063 5 H2S,gas -6.23 -22.76 -16.53 -8.264 0.28221E+05 -14.829 6 S2,gas -7.34 -45.99 -38.66 -5.947 0.66003E+05 -36.956 7 CO,gas 3.21 -14.30 -17.52 -5.389 0.29907E+05 -15.816 8 SO3,gas 17.12 -23.71 -40.83 -10.207 0.69715E+05 -39.130 9 SO2,gas 0.83 -23.47 -24.30 -6.481 0.41496E+05 -22.604 10 HCl,gas 5.19 -13.39 -18.58 -9.289 0.31721E+05 -16.879 11 acmite 7.71 6.68 -1.03 -0.107 0.17619E+04 15 albite-high 0.69 -0.53 -1.22 -0.094 0.20892E+04 16 albite -0.38 -0.53 -0.15 -0.011 0.25041E+03 19 spessartine 24.46 20.43 -4.03 -0.201 0.68770E+04 20 analcite 3.32 2.78 -0.54 -0.060 0.92571E+03 21 andalusite 5.00 1.46 -3.54 -0.354 0.60475E+04 22 andradite 39.01 35.27 -3.73 -0.194 0.63765E+04 26 annite 20.12 16.72 -3.40 -0.189 0.58129E+04 27 phlogopite 27.06 23.41 -3.66 -0.203 0.62462E+04 29 anorthite 12.71 9.03 -3.68 -0.283 0.62856E+04 35 aragonite 0.97 -3.66 -4.62 -1.542 0.78965E+04 36 brucite 12.57 8.63 -3.94 -0.788 0.67233E+04 37 calcite 0.81 -3.66 -4.47 -1.490 0.76323E+04 38 carnegieite-low 9.02 6.09 -2.93 -0.419 0.50086E+04 39 carnegieite-high 10.09 6.09 -4.00 -0.572 0.68356E+04 40 carpholite-Mg 8.58 6.78 -1.80 -0.120 0.30762E+04 41 carpholite-Fe 6.71 4.55 -2.16 -0.144 0.36904E+04 42 celadonite 5.34 2.83 -2.51 -0.147 0.42812E+04 43 celadonite-Fe 3.88 0.61 -3.27 -0.192 0.55858E+04 44 chrysotile 23.89 19.27 -4.62 -0.385 0.78884E+04 50 chloritoid-Mg 13.20 10.09 -3.11 -0.207 0.53051E+04 51 chloritoid-Fe 9.17 7.86 -1.31 -0.087 0.22403E+04 52 chloritoid-Mn 11.40 9.99 -1.41 -0.094 0.24096E+04 54 coesite -2.38 -3.31 -0.93 -0.311 0.15951E+04 59 corundum 8.38 4.77 -3.61 -0.328 0.61694E+04 61 cristobalite -2.56 -3.31 -0.75 -0.250 0.12804E+04 63 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71234E+04 65 diaspore 2.87 2.38 -0.49 -0.081 0.83448E+03 67 diopside 16.18 12.89 -3.29 -0.329 0.56197E+04 68 hedenbergite 14.21 10.66 -3.55 -0.355 0.60569E+04 75 epidote 24.67 22.88 -1.79 -0.087 0.30536E+04 76 clinozoisite 22.81 18.98 -3.82 -0.174 0.65270E+04 77 epidote-Fe 29.84 26.78 -3.06 -0.159 0.52268E+04 78 fayalite 14.05 9.49 -4.55 -0.650 0.77729E+04 79 ferrosilite 11.15 6.18 -4.97 -0.497 0.84797E+04 83 gibbsite 4.08 2.38 -1.69 -0.242 0.28930E+04 84 glaucophane 22.97 18.21 -4.76 -0.129 0.81334E+04 87 greenalite 16.14 12.59 -3.55 -0.296 0.60691E+04 91 heulandite -5.83 -7.52 -1.69 -0.077 0.28938E+04 95 jadeite 4.22 2.78 -1.44 -0.144 0.24512E+04 97 kalsilite 7.58 4.13 -3.45 -0.493 0.58907E+04 98 kaolinite -1.33 -1.85 -0.52 -0.047 0.88402E+03 99 kyanite 4.88 1.46 -3.42 -0.342 0.58334E+04 101 laumontite 2.88 2.41 -0.47 -0.032 0.81067E+03 102 lawsonite 9.62 9.03 -0.59 -0.039 0.10023E+04 103 leucite 4.12 0.82 -3.30 -0.330 0.56263E+04 105 lizardite 23.24 19.27 -3.97 -0.331 0.67810E+04 107 magnetite 20.09 18.97 -1.12 -0.091 0.19113E+04 108 minnesotaite 10.39 5.96 -4.42 -0.260 0.75530E+04 113 margarite 17.32 13.80 -3.52 -0.141 0.60181E+04 120 muscovite 2.58 2.28 -0.30 -0.018 0.51049E+03 122 nepheline 8.34 6.09 -2.25 -0.321 0.38410E+04 134 phlogopite-Na 29.65 25.36 -4.28 -0.238 0.73154E+04 136 prehnite 19.37 16.60 -2.77 -0.163 0.47355E+04 137 prehnite-Fe 22.50 20.50 -2.00 -0.120 0.34171E+04 138 pumpellyite-Fe 46.27 41.98 -4.29 -0.095 0.73177E+04 139 pumpellyite-Mg 48.99 44.21 -4.78 -0.106 0.81652E+04 145 pyroxmangite 7.40 5.22 -2.18 -0.436 0.37201E+04 146 pyrophyllite -6.18 -8.47 -2.30 -0.143 0.39189E+04 147 quartz -2.99 -3.31 -0.32 -0.107 0.54775E+03 152 rhodonite 7.45 5.22 -2.23 -0.445 0.38004E+04 153 sanidine -1.28 -2.49 -1.21 -0.093 0.20677E+04 156 sillimanite 5.26 1.46 -3.80 -0.380 0.64915E+04 164 stilpnomelane-Fe 13.02 12.83 -0.19 -0.006 0.32453E+03 165 stilpnomelane-Mg 27.44 23.97 -3.47 -0.104 0.59229E+04 168 sudoite 21.08 16.87 -4.21 -0.136 0.71820E+04 171 talc 16.49 12.65 -3.84 -0.226 0.65551E+04 174 tephroite 18.09 13.75 -4.34 -0.619 0.74031E+04 177 topaz-H 4.62 1.46 -3.16 -0.287 0.53935E+04 178 tridymite -2.63 -3.31 -0.68 -0.228 0.11677E+04 187 wairakite 3.95 2.41 -1.54 -0.091 0.26326E+04 188 walstromite 11.51 7.57 -3.94 -0.788 0.67272E+04 189 wollastonite 10.46 7.57 -2.89 -0.578 0.49376E+04 190 pseudo-wollastonite 11.00 7.57 -3.43 -0.686 0.58575E+04 191 zoisite 22.85 18.98 -3.87 -0.176 0.66010E+04 192 akaganeite 7.75 6.28 -1.47 -0.318 0.25125E+04 193 beidellite-Ca -1.65 -4.80 -3.15 -0.195 0.53799E+04 194 beidellite-H -2.33 -6.59 -4.27 -0.272 0.72829E+04 195 beidellite-K -1.52 -4.92 -3.40 -0.208 0.58084E+04 196 beidellite-Mg -1.79 -5.17 -3.38 -0.209 0.57673E+04 197 beidellite-Na -1.34 -4.28 -2.93 -0.180 0.50102E+04 199 chalcedony -2.80 -3.31 -0.51 -0.169 0.86704E+03 201 montmorillonite-Ca -2.29 -4.61 -2.32 -0.144 0.39680E+04 202 montmorillonite-K -2.24 -4.74 -2.50 -0.153 0.42747E+04 203 montmorillonite-Mg -2.48 -4.99 -2.51 -0.155 0.42786E+04 204 montmorillonite-Na -2.04 -4.09 -2.06 -0.126 0.35122E+04 205 nontronite-Ca 3.21 3.00 -0.21 -0.014 0.36663E+03 206 nontronite-H 2.53 1.20 -1.33 -0.089 0.22675E+04 207 nontronite-K 3.34 2.87 -0.47 -0.030 0.79649E+03 208 nontronite-Mg 3.07 2.63 -0.45 -0.029 0.76123E+03 224 tobermorite 9.82 5.75 -4.07 -1.111 0.69504E+04 233 boehmite 4.41 2.38 -2.02 -0.337 0.34514E+04 235 ferrous-oxide 9.81 6.40 -3.41 -0.852 0.58221E+04 240 silica-amorphous -2.09 -3.31 -1.22 -0.406 0.20812E+04 242 an20ab80 2.02 1.38 -0.64 -0.049 0.10866E+04 243 an25ab75 2.65 1.86 -0.79 -0.060 0.13426E+04 244 an30ab70 3.28 2.34 -0.94 -0.072 0.16082E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 0.1000000 g Current total amount of reactant added: 3.0990000 g New total amount of reactant added: 3.1990000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.8096E-13 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 6 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 3.1990000 Water: Moles liquid = 0.5548E+02 kg liquid = 0.9994E+00 Moles total = 0.5547E+02 kg total = 0.9993E+00 Activity = 1.0000 Stoichiometric ionic strength = .2347301E-02 Osmotic coef. = 0.9729 True ionic strength = .3910027E-02 Chg. balance for total moles = 0.8096E-13 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.34790E-09 -9.4585 0.31621E-09 -9.5000 0.90890E+00 -0.0415 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13791E-03 -3.8604 0.12516E-03 -3.9025 0.90753E+00 -0.0421 4 SO4-- 0.25508E-04 -4.5933 0.18314E-04 -4.7372 0.71800E+00 -0.1439 5 HCO3- 0.96864E-05 -5.0138 0.87939E-05 -5.0558 0.90786E+00 -0.0420 6 HS- 0.61009E-13 -13.2146 0.55370E-13 -13.2567 0.90756E+00 -0.0421 7 Al+++ 0.15609E-25 -25.8066 0.75496E-26 -26.1221 0.48367E+00 -0.3154 8 H4SiO4 0.48759E-03 -3.3119 0.48759E-03 -3.3119 0.10000E+01 0.0000 9 Ca++ 0.11225E-07 -7.9498 0.80448E-08 -8.0945 0.71670E+00 -0.1447 10 Mg++ 0.60242E-10 -10.2201 0.43126E-10 -10.3653 0.71589E+00 -0.1452 11 Fe++ 0.35534E-12 -12.4494 0.25445E-12 -12.5944 0.71608E+00 -0.1450 12 K+ 0.41046E-04 -4.3867 0.37266E-04 -4.4287 0.90792E+00 -0.0420 13 Na+ 0.38317E-02 -2.4166 0.34773E-02 -2.4588 0.90750E+00 -0.0422 14 Mn++ 0.47740E-10 -10.3211 0.34193E-10 -10.4661 0.71623E+00 -0.1449 15 HPO4-- 0.82567E-05 -5.0832 0.59285E-05 -5.2271 0.71803E+00 -0.1439 16 HSiO3- 0.15865E-02 -2.7996 0.14398E-02 -2.8417 0.90753E+00 -0.0421 17 Ca(HSiO3)+ 0.29053E-09 -9.5368 0.26379E-09 -9.5787 0.90797E+00 -0.0419 18 Mg(HSiO3)+ 0.19383E-11 -11.7126 0.17599E-11 -11.7545 0.90797E+00 -0.0419 19 NaHSiO3,aq 0.80975E-04 -4.0916 0.80975E-04 -4.0916 0.10000E+01 0.0000 20 AlO+ 0.11313E-13 -13.9464 0.10272E-13 -13.9883 0.90797E+00 -0.0419 21 AlOH+2 0.22576E-19 -19.6464 0.16173E-19 -19.7912 0.71640E+00 -0.1448 22 HAlO2,aq 0.64692E-08 -8.1891 0.64692E-08 -8.1891 0.10000E+01 0.0000 23 AlO2- 0.49924E-04 -4.3017 0.45287E-04 -4.3440 0.90712E+00 -0.0423 24 CH4,aq 0.25844E-19 -19.5876 0.25825E-19 -19.5880 0.99927E+00 -0.0003 29 CO,aq 0.10001E-18 -18.9999 0.10001E-18 -18.9999 0.10000E+01 0.0000 30 CO2,aq 0.59460E-08 -8.2258 0.59417E-08 -8.2261 0.99927E+00 -0.0003 31 CO3-2 0.33850E-05 -5.4704 0.24291E-05 -5.6146 0.71762E+00 -0.1441 32 CaCO3,aq 0.24503E-09 -9.6108 0.24503E-09 -9.6108 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.19889E-11 -11.7014 0.18058E-11 -11.7433 0.90797E+00 -0.0419 34 CaCl+ 0.17946E-11 -11.7460 0.16294E-11 -11.7880 0.90797E+00 -0.0419 35 CaCl2,aq 0.48450E-16 -16.3147 0.48450E-16 -16.3147 0.10000E+01 0.0000 36 CaOH+ 0.19970E-08 -8.6996 0.18132E-08 -8.7416 0.90797E+00 -0.0419 37 CaSO4,aq 0.46786E-10 -10.3299 0.46786E-10 -10.3299 0.10000E+01 0.0000 38 HCl,aq 0.72521E-14 -14.1395 0.72521E-14 -14.1395 0.10000E+01 0.0000 43 FeCl+ 0.55517E-16 -16.2556 0.50407E-16 -16.2975 0.90797E+00 -0.0419 46 FeO,aq 0.98905E-10 -10.0048 0.98905E-10 -10.0048 0.10000E+01 0.0000 47 FeOH+ 0.28849E-10 -10.5399 0.26193E-10 -10.5818 0.90797E+00 -0.0419 48 HFeO2- 0.36062E-08 -8.4430 0.32727E-08 -8.4851 0.90753E+00 -0.0421 49 FeO+ 0.26582E-14 -14.5754 0.24136E-14 -14.6173 0.90797E+00 -0.0419 51 FeO2- 0.54426E-08 -8.2642 0.49393E-08 -8.3063 0.90753E+00 -0.0421 52 HFeO2,aq 0.19864E-09 -9.7019 0.19864E-09 -9.7019 0.10000E+01 0.0000 53 H2,aq 0.67054E-09 -9.1736 0.67005E-09 -9.1739 0.99927E+00 -0.0003 54 KCl,aq 0.84534E-10 -10.0730 0.84534E-10 -10.0730 0.10000E+01 0.0000 55 KHSO4,aq 0.61019E-18 -18.2145 0.61019E-18 -18.2145 0.10000E+01 0.0000 56 KOH,aq 0.50330E-07 -7.2982 0.50330E-07 -7.2982 0.10000E+01 0.0000 57 KSO4- 0.11670E-07 -7.9329 0.10591E-07 -7.9751 0.90753E+00 -0.0421 58 MgCO3,aq 0.32925E-12 -12.4825 0.32925E-12 -12.4825 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.10895E-13 -13.9628 0.98918E-14 -14.0047 0.90797E+00 -0.0419 60 MgCl+ 0.87193E-14 -14.0595 0.79168E-14 -14.1014 0.90797E+00 -0.0419 61 MgOH+ 0.59238E-10 -10.2274 0.53786E-10 -10.2693 0.90797E+00 -0.0419 63 MnO,aq 0.35414E-09 -9.4508 0.35414E-09 -9.4508 0.10000E+01 0.0000 64 MnOH+ 0.36012E-09 -9.4435 0.32698E-09 -9.4855 0.90797E+00 -0.0419 65 MnO2-2 0.16380E-12 -12.7857 0.11754E-12 -12.9298 0.71762E+00 -0.1441 66 HMnO2- 0.89727E-11 -11.0471 0.81430E-11 -11.0892 0.90753E+00 -0.0421 69 MnCl+ 0.29024E-13 -13.5372 0.26353E-13 -13.5792 0.90797E+00 -0.0419 70 MnSO4,aq 0.18078E-12 -12.7428 0.18078E-12 -12.7428 0.10000E+01 0.0000 71 NaCl,aq 0.14423E-06 -6.8410 0.14423E-06 -6.8410 0.10000E+01 0.0000 72 NaOH,aq 0.47247E-05 -5.3256 0.47247E-05 -5.3256 0.10000E+01 0.0000 74 OH- 0.20143E-02 -2.6959 0.18272E-02 -2.7382 0.90712E+00 -0.0423 79 HPO3-2 0.17251E-16 -16.7632 0.12379E-16 -16.9073 0.71762E+00 -0.1441 82 H3PO4,aq 0.41459E-14 -14.3824 0.41459E-14 -14.3824 0.10000E+01 0.0000 83 H2PO4- 0.38097E-07 -7.4191 0.34582E-07 -7.4611 0.90774E+00 -0.0420 84 PO4-3 0.31241E-07 -7.5053 0.15297E-07 -7.8154 0.48965E+00 -0.3101 87 H2P2O7-2 0.13067E-15 -15.8838 0.93773E-16 -16.0279 0.71762E+00 -0.1441 88 HP2O7-3 0.12241E-12 -12.9122 0.59215E-13 -13.2276 0.48375E+00 -0.3154 89 P2O7-4 0.15939E-12 -12.7975 0.44737E-13 -13.3493 0.28067E+00 -0.5518 90 H2S,aq 0.54151E-16 -16.2664 0.54112E-16 -16.2667 0.99927E+00 -0.0003 97 SO3-2 0.22142E-14 -14.6548 0.15947E-14 -14.7973 0.72022E+00 -0.1425 98 HSO3- 0.34790E-16 -16.4585 0.31573E-16 -16.5007 0.90753E+00 -0.0421 99 HSO4- 0.61454E-11 -11.2115 0.55811E-11 -11.2533 0.90818E+00 -0.0418 Charge balance for all species = 0.8995E-13 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.3479037E-09 -.3889670E-02 -.3919335E+01 0.0000 2 H2O 0.1000000E+01 0.5550870E+02 0.9996949E+06 0.0000 3 Cl- 0.1379099E-03 0.1380543E-03 0.4892915E+01 5.5975 4 SO4-- 0.2550755E-04 0.2551981E-04 0.2450711E+01 14.2628 5 HCO3- 0.9686416E-05 0.1307759E-04 0.7977095E+00 4.4442 6 HS- 0.6100934E-13 -.5374544E-09 -.1776916E-04 -3.7567 7 Al+++ 0.1560890E-25 0.4993074E-04 0.1346787E+01 2.3780 8 H4SiO4 0.4875894E-03 0.2155085E-02 0.2070724E+03 -3.3119 9 Ca++ 0.1122470E-07 0.1380781E-07 0.5532171E-03 10.9056 10 Mg++ 0.6024168E-10 0.1217668E-09 0.2959475E-05 8.6348 11 Fe++ 0.3553372E-12 0.9375474E-08 0.5234293E-03 6.4057 12 K+ 0.4104584E-04 0.4110793E-04 0.1606902E+01 5.0713 13 Na+ 0.3831701E-02 0.3917545E-02 0.9003557E+02 7.0413 14 Mn++ 0.4773975E-10 0.7713510E-09 0.4236330E-04 8.5340 15 HPO4-- 0.8256687E-05 0.8326026E-05 0.7988751E+00 13.7730 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.5295765E-01 -.3887414E-02 -.4907024E-01 0.0000000E+00 2 H2O 0.5546815E+02 0.5547650E+02 -.8354400E-02 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.1141597E-03 0.2550501E-04 0.8865466E-04 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.8865520E-04 -.5371426E-09 -.8865466E-04 0.0000000E+00 7 Al+++ 0.1043111E-01 0.4990178E-04 0.1038121E-01 0.0000000E+00 8 H4SiO4 0.3331049E-01 0.2153835E-02 0.3115666E-01 0.0000000E+00 9 Ca++ 0.3693777E-02 0.1379980E-07 0.3693764E-02 0.0000000E+00 10 Mg++ 0.2538889E-02 0.1216962E-09 0.2538889E-02 0.0000000E+00 11 Fe++ 0.2280914E-02 0.9370036E-08 0.2280905E-02 0.0000000E+00 12 K+ 0.6791932E-03 0.4108408E-04 0.6381091E-03 0.0000000E+00 13 Na+ 0.4175595E-02 0.3915273E-02 0.2603228E-03 0.0000000E+00 14 Mn++ 0.5546617E-04 0.7709035E-09 0.5546540E-04 0.0000000E+00 15 HPO4-- 0.1893033E-04 0.8321196E-05 0.1060913E-04 0.0000000E+00 Chg. balance for solid moles: 0.1897E-17 Mass of aqueous solution: 0.999731E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 3.1990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) apatite-OH 0.3536E-05 -5.451 0.1776E-02 -2.750 0.5145E-01 0.5645E-03 clinochlore 0.5078E-03 -3.294 0.2822 -0.549 8.175 0.1074 daphnite 0.3143E-03 -3.503 0.2243 -0.649 6.496 0.6796E-01 chlorite-Mn 0.1109E-04 -4.955 0.7865E-02 -2.104 0.2278 0.2506E-02 hematite 0.2691E-03 -3.570 0.4298E-01 -1.367 1.245 0.8146E-02 microcline 0.6381E-03 -3.195 0.1776 -0.751 5.145 0.6938E-01 paragonite 0.2321E-03 -3.634 0.8871E-01 -1.052 2.569 0.3066E-01 stilbite 0.3676E-02 -2.435 2.591 0.413 75.04 1.208 nontronite-Na 0.8551E-04 -4.068 0.3637E-01 -1.439 1.053 0.1130E-01 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.6094E+00 0.6094E+00 1.0000 -0.215 daphnite 0.3773E+00 0.3773E+00 1.0000 -0.423 chlorite-Mn 0.1331E-01 0.1331E-01 1.0000 -1.876 hematite 0.1000E+01 0.1000E+01 1.0000 0.000 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 paragonite 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 nontronite-Na 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 3.452430 g Volume = 1.506182 cm3 Porosity: 33.9278% V(tot) - V(min): 0.77342E+00 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 3.1990000 g log = 0.5050 Original solution: 1000.0103000 g Original solution / Rock added: 312.60 (Water/Rock Ratio), log = 2.4950 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0203 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.1000E+01 0.9860 0.1006E+01 0.1020E+01 CO2,gas 0.6187E-06 1.0071 0.6357E-06 0.6312E-06 CH4,gas 0.3680E-16 1.0125 0.3801E-16 0.3754E-16 H2,gas 0.8617E-06 1.0005 0.8797E-06 0.8792E-06 H2S,gas 0.1464E-14 0.9960 0.1487E-14 0.1493E-14 S2,gas 0.1052E-36 1.0000 0.1073E-36 0.1073E-36 CO,gas 0.1461E-15 1.0000 0.1490E-15 0.1490E-15 SO3,gas 0.6786E-39 1.0000 0.6924E-39 0.6924E-39 SO2,gas 0.2323E-22 1.0000 0.2370E-22 0.2370E-22 HCl,gas 0.1254E-16 1.0000 0.1280E-16 0.1280E-16 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 32 apatite-OH -18.15 -18.15 0.00 0.000 -0.60662E-11 46 clinochlore 39.07 39.07 0.00 0.000 0.00000E+00 47 daphnite 28.97 28.97 0.00 0.000 -0.24265E-10 48 chlorite-Mn 46.87 46.87 0.00 0.000 -0.24265E-10 90 hematite 12.57 12.57 0.00 0.000 -0.90992E-11 116 microcline -2.49 -2.49 0.00 0.000 0.15165E-11 121 paragonite 4.24 4.24 0.00 0.000 0.13649E-10 163 stilbite -7.52 -7.52 0.00 0.000 0.15165E-10 209 nontronite-Na 3.52 3.52 0.00 0.000 -0.45496E-11 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -14.56 -7.90 -2.632 0.13482E+05 -6.197 3 CH4,gas 4.54 -13.58 -18.12 -4.530 0.30938E+05 -16.420 4 H2,gas 8.00 0.25 -7.75 -4.431 0.13241E+05 -6.056 5 H2S,gas -6.23 -22.76 -16.53 -8.263 0.28219E+05 -14.828 6 S2,gas -7.34 -46.00 -38.67 -5.949 0.66025E+05 -36.969 7 CO,gas 3.21 -14.31 -17.53 -5.393 0.29925E+05 -15.827 8 SO3,gas 17.12 -23.74 -40.86 -10.215 0.69765E+05 -39.160 9 SO2,gas 0.83 -23.49 -24.32 -6.486 0.41533E+05 -22.625 10 HCl,gas 5.19 -13.40 -18.59 -9.296 0.31745E+05 -16.893 11 acmite 7.71 6.70 -1.01 -0.105 0.17233E+04 15 albite-high 0.69 -0.52 -1.21 -0.093 0.20654E+04 16 albite -0.38 -0.52 -0.13 -0.010 0.22659E+03 19 spessartine 24.46 20.42 -4.04 -0.202 0.68900E+04 20 analcite 3.32 2.80 -0.53 -0.058 0.89896E+03 21 andalusite 5.00 1.44 -3.56 -0.356 0.60743E+04 22 andradite 39.01 35.35 -3.66 -0.190 0.62523E+04 26 annite 20.12 16.73 -3.39 -0.188 0.57933E+04 27 phlogopite 27.06 23.42 -3.65 -0.203 0.62267E+04 29 anorthite 12.71 9.04 -3.67 -0.283 0.62709E+04 35 aragonite 0.97 -3.65 -4.62 -1.539 0.78831E+04 36 brucite 12.57 8.63 -3.93 -0.787 0.67168E+04 37 calcite 0.81 -3.65 -4.46 -1.487 0.76188E+04 38 carnegieite-low 9.02 6.11 -2.92 -0.417 0.49790E+04 39 carnegieite-high 10.09 6.11 -3.99 -0.569 0.68059E+04 40 carpholite-Mg 8.58 6.77 -1.82 -0.121 0.30994E+04 41 carpholite-Fe 6.71 4.54 -2.17 -0.145 0.37135E+04 42 celadonite 5.34 2.84 -2.51 -0.147 0.42776E+04 43 celadonite-Fe 3.88 0.61 -3.27 -0.192 0.55823E+04 44 chrysotile 23.89 19.28 -4.61 -0.384 0.78747E+04 50 chloritoid-Mg 13.20 10.08 -3.12 -0.208 0.53254E+04 51 chloritoid-Fe 9.17 7.85 -1.32 -0.088 0.22605E+04 52 chloritoid-Mn 11.40 9.98 -1.42 -0.095 0.24298E+04 54 coesite -2.38 -3.31 -0.94 -0.312 0.15980E+04 59 corundum 8.38 4.76 -3.63 -0.330 0.61932E+04 61 cristobalite -2.56 -3.31 -0.75 -0.251 0.12833E+04 63 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71234E+04 65 diaspore 2.87 2.38 -0.50 -0.083 0.84639E+03 67 diopside 16.18 12.92 -3.26 -0.326 0.55747E+04 68 hedenbergite 14.21 10.69 -3.52 -0.352 0.60119E+04 75 epidote 24.67 22.91 -1.76 -0.085 0.29975E+04 76 clinozoisite 22.81 19.01 -3.80 -0.173 0.64828E+04 77 epidote-Fe 29.84 26.82 -3.02 -0.157 0.51588E+04 78 fayalite 14.05 9.50 -4.55 -0.649 0.77628E+04 79 ferrosilite 11.15 6.19 -4.96 -0.496 0.84725E+04 83 gibbsite 4.08 2.38 -1.70 -0.243 0.29049E+04 84 glaucophane 22.97 18.25 -4.73 -0.128 0.80720E+04 87 greenalite 16.14 12.59 -3.55 -0.296 0.60554E+04 91 heulandite -5.83 -7.52 -1.69 -0.077 0.28938E+04 95 jadeite 4.22 2.80 -1.42 -0.142 0.24245E+04 97 kalsilite 7.58 4.14 -3.45 -0.492 0.58848E+04 98 kaolinite -1.33 -1.87 -0.54 -0.049 0.91370E+03 99 kyanite 4.88 1.44 -3.43 -0.343 0.58602E+04 101 laumontite 2.88 2.41 -0.47 -0.031 0.80187E+03 102 lawsonite 9.62 9.04 -0.58 -0.039 0.98759E+03 103 leucite 4.12 0.83 -3.29 -0.329 0.56234E+04 105 lizardite 23.24 19.28 -3.96 -0.330 0.67673E+04 107 magnetite 20.09 18.97 -1.12 -0.091 0.19048E+04 108 minnesotaite 10.39 5.97 -4.42 -0.260 0.75452E+04 113 margarite 17.32 13.79 -3.53 -0.141 0.60273E+04 120 muscovite 2.58 2.27 -0.31 -0.018 0.53430E+03 122 nepheline 8.34 6.11 -2.23 -0.319 0.38113E+04 134 phlogopite-Na 29.65 25.39 -4.26 -0.237 0.72721E+04 136 prehnite 19.37 16.63 -2.74 -0.161 0.46795E+04 137 prehnite-Fe 22.50 20.54 -1.96 -0.118 0.33492E+04 138 pumpellyite-Fe 46.27 42.05 -4.22 -0.094 0.72110E+04 139 pumpellyite-Mg 48.99 44.28 -4.72 -0.105 0.80584E+04 145 pyroxmangite 7.40 5.22 -2.18 -0.435 0.37166E+04 146 pyrophyllite -6.18 -8.49 -2.32 -0.145 0.39545E+04 147 quartz -2.99 -3.31 -0.32 -0.108 0.55068E+03 152 rhodonite 7.45 5.22 -2.22 -0.445 0.37968E+04 153 sanidine -1.28 -2.49 -1.21 -0.093 0.20677E+04 156 sillimanite 5.26 1.44 -3.82 -0.382 0.65182E+04 164 stilpnomelane-Fe 13.02 12.82 -0.19 -0.006 0.32884E+03 165 stilpnomelane-Mg 27.44 23.97 -3.47 -0.104 0.59272E+04 168 sudoite 21.08 16.85 -4.23 -0.137 0.72253E+04 171 talc 16.49 12.66 -3.83 -0.226 0.65473E+04 174 tephroite 18.09 13.76 -4.33 -0.619 0.73930E+04 177 topaz-H 4.62 1.44 -3.17 -0.289 0.54203E+04 178 tridymite -2.63 -3.31 -0.69 -0.229 0.11707E+04 187 wairakite 3.95 2.41 -1.54 -0.090 0.26238E+04 188 walstromite 11.51 7.59 -3.92 -0.783 0.66858E+04 189 wollastonite 10.46 7.59 -2.87 -0.574 0.48962E+04 190 pseudo-wollastonite 11.00 7.59 -3.41 -0.681 0.58161E+04 191 zoisite 22.85 19.01 -3.84 -0.175 0.65569E+04 192 akaganeite 7.75 6.28 -1.47 -0.318 0.25125E+04 193 beidellite-Ca -1.65 -4.81 -3.17 -0.196 0.54111E+04 194 beidellite-H -2.33 -6.61 -4.29 -0.274 0.73214E+04 195 beidellite-K -1.52 -4.94 -3.42 -0.209 0.58401E+04 196 beidellite-Mg -1.79 -5.19 -3.40 -0.210 0.58047E+04 197 beidellite-Na -1.34 -4.29 -2.95 -0.181 0.50341E+04 199 chalcedony -2.80 -3.31 -0.51 -0.170 0.86998E+03 201 montmorillonite-Ca -2.29 -4.63 -2.34 -0.145 0.39902E+04 202 montmorillonite-K -2.24 -4.75 -2.52 -0.154 0.42973E+04 203 montmorillonite-Mg -2.48 -5.00 -2.52 -0.156 0.43070E+04 204 montmorillonite-Na -2.04 -4.10 -2.07 -0.126 0.35270E+04 205 nontronite-Ca 3.21 3.00 -0.22 -0.014 0.37400E+03 206 nontronite-H 2.53 1.20 -1.34 -0.090 0.22822E+04 207 nontronite-K 3.34 2.87 -0.47 -0.030 0.80435E+03 208 nontronite-Mg 3.07 2.62 -0.45 -0.029 0.77485E+03 224 tobermorite 9.82 5.77 -4.05 -1.105 0.69164E+04 233 boehmite 4.41 2.38 -2.03 -0.338 0.34633E+04 235 ferrous-oxide 9.81 6.41 -3.41 -0.851 0.58155E+04 240 silica-amorphous -2.09 -3.31 -1.22 -0.407 0.20842E+04 242 an20ab80 2.02 1.39 -0.62 -0.048 0.10646E+04 243 an25ab75 2.65 1.87 -0.77 -0.060 0.13211E+04 244 an30ab70 3.28 2.35 -0.93 -0.072 0.15872E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 0.1000000 g Current total amount of reactant added: 3.1990000 g New total amount of reactant added: 3.2990000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.8096E-13 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 6 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 3.2990000 Water: Moles liquid = 0.5548E+02 kg liquid = 0.9994E+00 Moles total = 0.5547E+02 kg total = 0.9993E+00 Activity = 1.0000 Stoichiometric ionic strength = .2408098E-02 Osmotic coef. = 0.9726 True ionic strength = .4020306E-02 Chg. balance for total moles = 0.8096E-13 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.33769E-09 -9.4715 0.30663E-09 -9.5134 0.90801E+00 -0.0419 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13791E-03 -3.8604 0.12503E-03 -3.9030 0.90661E+00 -0.0426 4 SO4-- 0.25508E-04 -4.5933 0.18242E-04 -4.7389 0.71514E+00 -0.1456 5 HCO3- 0.96014E-05 -5.0177 0.87079E-05 -5.0601 0.90694E+00 -0.0424 6 HS- 0.63150E-13 -13.1996 0.57254E-13 -13.2422 0.90664E+00 -0.0426 7 Al+++ 0.14140E-25 -25.8495 0.67776E-26 -26.1689 0.47931E+00 -0.3194 8 H4SiO4 0.48572E-03 -3.3136 0.48572E-03 -3.3136 0.10000E+01 0.0000 9 Ca++ 0.11230E-07 -7.9496 0.80161E-08 -8.0960 0.71382E+00 -0.1464 10 Mg++ 0.57364E-10 -10.2414 0.40900E-10 -10.3883 0.71298E+00 -0.1469 11 Fe++ 0.33836E-12 -12.4706 0.24131E-12 -12.6174 0.71318E+00 -0.1468 12 K+ 0.40935E-04 -4.3879 0.37128E-04 -4.4303 0.90700E+00 -0.0424 13 Na+ 0.39423E-02 -2.4043 0.35739E-02 -2.4469 0.90657E+00 -0.0426 14 Mn++ 0.45459E-10 -10.3424 0.32427E-10 -10.4891 0.71333E+00 -0.1467 15 HPO4-- 0.80040E-05 -5.0967 0.57242E-05 -5.2423 0.71517E+00 -0.1456 16 HSiO3- 0.16315E-02 -2.7874 0.14791E-02 -2.8300 0.90661E+00 -0.0426 17 Ca(HSiO3)+ 0.29769E-09 -9.5262 0.27002E-09 -9.5686 0.90705E+00 -0.0424 18 Mg(HSiO3)+ 0.18903E-11 -11.7235 0.17146E-11 -11.7658 0.90705E+00 -0.0424 19 NaHSiO3,aq 0.85499E-04 -4.0680 0.85499E-04 -4.0680 0.10000E+01 0.0000 20 AlO+ 0.10812E-13 -13.9661 0.98069E-14 -14.0085 0.90705E+00 -0.0424 21 AlOH+2 0.20985E-19 -19.6781 0.14973E-19 -19.8247 0.71351E+00 -0.1466 22 HAlO2,aq 0.63693E-08 -8.1959 0.63693E-08 -8.1959 0.10000E+01 0.0000 23 AlO2- 0.50741E-04 -4.2946 0.45981E-04 -4.3374 0.90618E+00 -0.0428 24 CH4,aq 0.26568E-19 -19.5756 0.26549E-19 -19.5760 0.99926E+00 -0.0003 29 CO,aq 0.97686E-19 -19.0102 0.97686E-19 -19.0102 0.10000E+01 0.0000 30 CO2,aq 0.57096E-08 -8.2434 0.57053E-08 -8.2437 0.99926E+00 -0.0003 31 CO3-2 0.34705E-05 -5.4596 0.24805E-05 -5.6055 0.71475E+00 -0.1458 32 CaCO3,aq 0.24932E-09 -9.6032 0.24932E-09 -9.6032 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.19644E-11 -11.7068 0.17818E-11 -11.7491 0.90705E+00 -0.0424 34 CaCl+ 0.17881E-11 -11.7476 0.16219E-11 -11.7900 0.90705E+00 -0.0424 35 CaCl2,aq 0.48178E-16 -16.3171 0.48178E-16 -16.3171 0.10000E+01 0.0000 36 CaOH+ 0.20541E-08 -8.6874 0.18632E-08 -8.7297 0.90705E+00 -0.0424 37 CaSO4,aq 0.46434E-10 -10.3332 0.46434E-10 -10.3332 0.10000E+01 0.0000 38 HCl,aq 0.70252E-14 -14.1533 0.70252E-14 -14.1533 0.10000E+01 0.0000 43 FeCl+ 0.52649E-16 -16.2786 0.47756E-16 -16.3210 0.90705E+00 -0.0424 46 FeO,aq 0.99752E-10 -10.0011 0.99752E-10 -10.0011 0.10000E+01 0.0000 47 FeOH+ 0.28242E-10 -10.5491 0.25617E-10 -10.5915 0.90705E+00 -0.0424 48 HFeO2- 0.37545E-08 -8.4254 0.34038E-08 -8.4680 0.90661E+00 -0.0426 49 FeO+ 0.25803E-14 -14.5883 0.23405E-14 -14.6307 0.90705E+00 -0.0424 51 FeO2- 0.56183E-08 -8.2504 0.50936E-08 -8.2930 0.90661E+00 -0.0426 52 HFeO2,aq 0.19864E-09 -9.7019 0.19864E-09 -9.7019 0.10000E+01 0.0000 53 H2,aq 0.68208E-09 -9.1662 0.68158E-09 -9.1665 0.99926E+00 -0.0003 54 KCl,aq 0.84135E-10 -10.0750 0.84135E-10 -10.0750 0.10000E+01 0.0000 55 KHSO4,aq 0.58718E-18 -18.2312 0.58718E-18 -18.2312 0.10000E+01 0.0000 56 KOH,aq 0.51711E-07 -7.2864 0.51711E-07 -7.2864 0.10000E+01 0.0000 57 KSO4- 0.11593E-07 -7.9358 0.10510E-07 -7.9784 0.90661E+00 -0.0426 58 MgCO3,aq 0.31886E-12 -12.4964 0.31886E-12 -12.4964 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.10241E-13 -13.9896 0.92894E-14 -14.0320 0.90705E+00 -0.0424 60 MgCl+ 0.82690E-14 -14.0825 0.75004E-14 -14.1249 0.90705E+00 -0.0424 61 MgOH+ 0.57993E-10 -10.2366 0.52603E-10 -10.2790 0.90705E+00 -0.0424 63 MnO,aq 0.35717E-09 -9.4471 0.35717E-09 -9.4471 0.10000E+01 0.0000 64 MnOH+ 0.35256E-09 -9.4528 0.31979E-09 -9.4951 0.90705E+00 -0.0424 65 MnO2-2 0.17639E-12 -12.7535 0.12607E-12 -12.8994 0.71475E+00 -0.1458 66 HMnO2- 0.93418E-11 -11.0296 0.84693E-11 -11.0722 0.90661E+00 -0.0426 69 MnCl+ 0.27525E-13 -13.5603 0.24966E-13 -13.6026 0.90705E+00 -0.0424 70 MnSO4,aq 0.17077E-12 -12.7676 0.17077E-12 -12.7676 0.10000E+01 0.0000 71 NaCl,aq 0.14809E-06 -6.8295 0.14809E-06 -6.8295 0.10000E+01 0.0000 72 NaOH,aq 0.50078E-05 -5.3004 0.50078E-05 -5.3004 0.10000E+01 0.0000 74 OH- 0.20794E-02 -2.6821 0.18843E-02 -2.7249 0.90618E+00 -0.0428 79 HPO3-2 0.17011E-16 -16.7693 0.12158E-16 -16.9151 0.71475E+00 -0.1458 82 H3PO4,aq 0.37641E-14 -14.4243 0.37641E-14 -14.4243 0.10000E+01 0.0000 83 H2PO4- 0.35706E-07 -7.4473 0.32379E-07 -7.4897 0.90682E+00 -0.0425 84 PO4-3 0.31380E-07 -7.5033 0.15231E-07 -7.8173 0.48538E+00 -0.3139 87 H2P2O7-2 0.11501E-15 -15.9393 0.82205E-16 -16.0851 0.71475E+00 -0.1458 88 HP2O7-3 0.11167E-12 -12.9521 0.53532E-13 -13.2714 0.47939E+00 -0.3193 89 P2O7-4 0.15098E-12 -12.8211 0.41707E-13 -13.3798 0.27623E+00 -0.5587 90 H2S,aq 0.54299E-16 -16.2652 0.54258E-16 -16.2655 0.99926E+00 -0.0003 97 SO3-2 0.22521E-14 -14.6474 0.16157E-14 -14.7916 0.71741E+00 -0.1442 98 HSO3- 0.34215E-16 -16.4658 0.31019E-16 -16.5084 0.90661E+00 -0.0426 99 HSO4- 0.59415E-11 -11.2261 0.53905E-11 -11.2684 0.90727E+00 -0.0423 Charge balance for all species = 0.8978E-13 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.3376929E-09 -.4007885E-02 -.4038421E+01 0.0000 2 H2O 0.1000000E+01 0.5550872E+02 0.9996878E+06 0.0000 3 Cl- 0.1379085E-03 0.1380567E-03 0.4892965E+01 5.6104 4 SO4-- 0.2550807E-04 0.2552028E-04 0.2450738E+01 14.2878 5 HCO3- 0.9601372E-05 0.1307781E-04 0.7977175E+00 4.4533 6 HS- 0.6314988E-13 -.5565377E-09 -.1839995E-04 -3.7288 7 Al+++ 0.1414041E-25 0.5074763E-04 0.1368811E+01 2.3712 8 H4SiO4 0.4857240E-03 0.2202715E-02 0.2116475E+03 -3.3136 9 Ca++ 0.1122990E-07 0.1388120E-07 0.5561535E-03 10.9307 10 Mg++ 0.5736423E-10 0.1175851E-09 0.2857819E-05 8.6385 11 Fe++ 0.3383621E-12 0.9699809E-08 0.5415328E-03 6.4094 12 K+ 0.4093529E-04 0.4099868E-04 0.1602620E+01 5.0831 13 Na+ 0.3942257E-02 0.4032911E-02 0.9268631E+02 7.0665 14 Mn++ 0.4545892E-10 0.7649056E-09 0.4200901E-04 8.5377 15 HPO4-- 0.8004046E-05 0.8071133E-05 0.7744126E+00 13.7845 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.5461350E-01 -.4005490E-02 -.5060801E-01 0.0000000E+00 2 H2O 0.5546690E+02 0.5547555E+02 -.8655775E-02 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.1169310E-03 0.2550503E-04 0.9142598E-04 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.9142654E-04 -.5562052E-09 -.9142598E-04 0.0000000E+00 7 Al+++ 0.1075719E-01 0.5071731E-04 0.1070647E-01 0.0000000E+00 8 H4SiO4 0.3435177E-01 0.2201399E-02 0.3215037E-01 0.0000000E+00 9 Ca++ 0.3808792E-02 0.1387290E-07 0.3808778E-02 0.0000000E+00 10 Mg++ 0.2618254E-02 0.1175149E-09 0.2618254E-02 0.0000000E+00 11 Fe++ 0.2352215E-02 0.9694013E-08 0.2352206E-02 0.0000000E+00 12 K+ 0.7004246E-03 0.4097418E-04 0.6594505E-03 0.0000000E+00 13 Na+ 0.4301120E-02 0.4030502E-02 0.2706180E-03 0.0000000E+00 14 Mn++ 0.5720003E-04 0.7644486E-09 0.5719926E-04 0.0000000E+00 15 HPO4-- 0.1952209E-04 0.8066310E-05 0.1145578E-04 0.0000000E+00 Chg. balance for solid moles: 0.1050E-17 Mass of aqueous solution: 0.999721E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 3.2990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) apatite-OH 0.3819E-05 -5.418 0.1918E-02 -2.717 0.5386E-01 0.6095E-03 clinochlore 0.5237E-03 -3.281 0.2911 -0.536 8.172 0.1107 daphnite 0.3242E-03 -3.489 0.2313 -0.636 6.494 0.7009E-01 chlorite-Mn 0.1144E-04 -4.942 0.8111E-02 -2.091 0.2277 0.2585E-02 hematite 0.2707E-03 -3.568 0.4323E-01 -1.364 1.214 0.8194E-02 microcline 0.6595E-03 -3.181 0.1836 -0.736 5.154 0.7170E-01 paragonite 0.2393E-03 -3.621 0.9145E-01 -1.039 2.568 0.3161E-01 stilbite 0.3790E-02 -2.421 2.671 0.427 74.98 1.246 nontronite-Na 0.9501E-04 -4.022 0.4040E-01 -1.394 1.134 0.1255E-01 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.6094E+00 0.6094E+00 1.0000 -0.215 daphnite 0.3773E+00 0.3773E+00 1.0000 -0.423 chlorite-Mn 0.1331E-01 0.1331E-01 1.0000 -1.876 hematite 0.1000E+01 0.1000E+01 1.0000 0.000 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 paragonite 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 nontronite-Na 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 3.561679 g Volume = 1.553696 cm3 Porosity: 33.0188% V(tot) - V(min): 0.76590E+00 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 3.2990000 g log = 0.5184 Original solution: 1000.0103000 g Original solution / Rock added: 303.13 (Water/Rock Ratio), log = 2.4816 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0203 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.1000E+01 0.9860 0.1006E+01 0.1020E+01 CO2,gas 0.5941E-06 1.0071 0.6104E-06 0.6061E-06 CH4,gas 0.3783E-16 1.0125 0.3908E-16 0.3859E-16 H2,gas 0.8766E-06 1.0005 0.8948E-06 0.8943E-06 H2S,gas 0.1468E-14 0.9960 0.1492E-14 0.1497E-14 S2,gas 0.1022E-36 1.0000 0.1043E-36 0.1043E-36 CO,gas 0.1427E-15 1.0000 0.1456E-15 0.1456E-15 SO3,gas 0.6356E-39 1.0000 0.6485E-39 0.6485E-39 SO2,gas 0.2213E-22 1.0000 0.2258E-22 0.2258E-22 HCl,gas 0.1215E-16 1.0000 0.1240E-16 0.1240E-16 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 32 apatite-OH -18.15 -18.15 0.00 0.000 0.12132E-10 46 clinochlore 39.07 39.07 0.00 0.000 -0.24265E-10 47 daphnite 28.97 28.97 0.00 0.000 0.00000E+00 48 chlorite-Mn 46.87 46.87 0.00 0.000 0.00000E+00 90 hematite 12.57 12.57 0.00 0.000 -0.90992E-11 116 microcline -2.49 -2.49 0.00 0.000 0.15165E-11 121 paragonite 4.24 4.24 0.00 0.000 0.13649E-10 163 stilbite -7.52 -7.52 0.00 0.000 -0.90992E-11 209 nontronite-Na 3.52 3.52 0.00 0.000 -0.15165E-11 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -14.57 -7.91 -2.638 0.13512E+05 -6.214 3 CH4,gas 4.54 -13.56 -18.11 -4.527 0.30917E+05 -16.408 4 H2,gas 8.00 0.25 -7.75 -4.427 0.13228E+05 -6.048 5 H2S,gas -6.23 -22.76 -16.53 -8.263 0.28217E+05 -14.826 6 S2,gas -7.34 -46.02 -38.68 -5.951 0.66046E+05 -36.982 7 CO,gas 3.21 -14.32 -17.54 -5.396 0.29942E+05 -15.837 8 SO3,gas 17.12 -23.77 -40.89 -10.222 0.69814E+05 -39.188 9 SO2,gas 0.83 -23.51 -24.35 -6.492 0.41569E+05 -22.646 10 HCl,gas 5.19 -13.42 -18.61 -9.303 0.31769E+05 -16.907 11 acmite 7.71 6.72 -0.99 -0.103 0.16858E+04 15 albite-high 0.69 -0.50 -1.20 -0.092 0.20423E+04 16 albite -0.38 -0.50 -0.12 -0.009 0.20351E+03 19 spessartine 24.46 20.41 -4.04 -0.202 0.69027E+04 20 analcite 3.32 2.81 -0.51 -0.057 0.87304E+03 21 andalusite 5.00 1.43 -3.57 -0.357 0.61002E+04 22 andradite 39.01 35.42 -3.59 -0.187 0.61319E+04 26 annite 20.12 16.74 -3.38 -0.188 0.57744E+04 27 phlogopite 27.06 23.43 -3.64 -0.202 0.62077E+04 29 anorthite 12.71 9.05 -3.66 -0.282 0.62567E+04 35 aragonite 0.97 -3.64 -4.61 -1.536 0.78702E+04 36 brucite 12.57 8.64 -3.93 -0.786 0.67105E+04 37 calcite 0.81 -3.64 -4.45 -1.485 0.76060E+04 38 carnegieite-low 9.02 6.12 -2.90 -0.414 0.49502E+04 39 carnegieite-high 10.09 6.12 -3.97 -0.567 0.67772E+04 40 carpholite-Mg 8.58 6.75 -1.83 -0.122 0.31218E+04 41 carpholite-Fe 6.71 4.52 -2.19 -0.146 0.37360E+04 42 celadonite 5.34 2.84 -2.50 -0.147 0.42742E+04 43 celadonite-Fe 3.88 0.61 -3.27 -0.192 0.55788E+04 44 chrysotile 23.89 19.29 -4.60 -0.384 0.78614E+04 50 chloritoid-Mg 13.20 10.07 -3.13 -0.209 0.53450E+04 51 chloritoid-Fe 9.17 7.84 -1.34 -0.089 0.22801E+04 52 chloritoid-Mn 11.40 9.97 -1.43 -0.096 0.24494E+04 54 coesite -2.38 -3.31 -0.94 -0.313 0.16008E+04 59 corundum 8.38 4.74 -3.64 -0.331 0.62163E+04 61 cristobalite -2.56 -3.31 -0.75 -0.251 0.12862E+04 63 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71234E+04 65 diaspore 2.87 2.37 -0.50 -0.084 0.85793E+03 67 diopside 16.18 12.94 -3.24 -0.324 0.55311E+04 68 hedenbergite 14.21 10.71 -3.50 -0.350 0.59683E+04 75 epidote 24.67 22.95 -1.72 -0.084 0.29432E+04 76 clinozoisite 22.81 19.03 -3.77 -0.171 0.64400E+04 77 epidote-Fe 29.84 26.86 -2.98 -0.155 0.50929E+04 78 fayalite 14.05 9.51 -4.54 -0.649 0.77530E+04 79 ferrosilite 11.15 6.19 -4.96 -0.496 0.84656E+04 83 gibbsite 4.08 2.37 -1.71 -0.244 0.29165E+04 84 glaucophane 22.97 18.28 -4.69 -0.127 0.80126E+04 87 greenalite 16.14 12.60 -3.54 -0.295 0.60422E+04 91 heulandite -5.83 -7.52 -1.69 -0.077 0.28938E+04 95 jadeite 4.22 2.81 -1.40 -0.140 0.23985E+04 97 kalsilite 7.58 4.14 -3.44 -0.492 0.58791E+04 98 kaolinite -1.33 -1.88 -0.55 -0.050 0.94247E+03 99 kyanite 4.88 1.43 -3.45 -0.345 0.58861E+04 101 laumontite 2.88 2.42 -0.46 -0.031 0.79335E+03 102 lawsonite 9.62 9.05 -0.57 -0.038 0.97338E+03 103 leucite 4.12 0.83 -3.29 -0.329 0.56206E+04 105 lizardite 23.24 19.29 -3.96 -0.330 0.67540E+04 107 magnetite 20.09 18.98 -1.11 -0.091 0.18985E+04 108 minnesotaite 10.39 5.97 -4.41 -0.260 0.75376E+04 113 margarite 17.32 13.79 -3.54 -0.141 0.60361E+04 120 muscovite 2.58 2.26 -0.33 -0.019 0.55739E+03 122 nepheline 8.34 6.12 -2.22 -0.316 0.37825E+04 134 phlogopite-Na 29.65 25.41 -4.23 -0.235 0.72300E+04 136 prehnite 19.37 16.66 -2.71 -0.159 0.46251E+04 137 prehnite-Fe 22.50 20.57 -1.92 -0.116 0.32833E+04 138 pumpellyite-Fe 46.27 42.11 -4.16 -0.093 0.71075E+04 139 pumpellyite-Mg 48.99 44.34 -4.66 -0.104 0.79549E+04 145 pyroxmangite 7.40 5.22 -2.17 -0.435 0.37131E+04 146 pyrophyllite -6.18 -8.51 -2.34 -0.146 0.39889E+04 147 quartz -2.99 -3.31 -0.32 -0.108 0.55352E+03 152 rhodonite 7.45 5.22 -2.22 -0.444 0.37933E+04 153 sanidine -1.28 -2.49 -1.21 -0.093 0.20677E+04 156 sillimanite 5.26 1.43 -3.83 -0.383 0.65441E+04 164 stilpnomelane-Fe 13.02 12.82 -0.20 -0.006 0.33302E+03 165 stilpnomelane-Mg 27.44 23.97 -3.47 -0.104 0.59314E+04 168 sudoite 21.08 16.82 -4.26 -0.137 0.72674E+04 171 talc 16.49 12.66 -3.83 -0.225 0.65397E+04 174 tephroite 18.09 13.76 -4.32 -0.618 0.73832E+04 177 topaz-H 4.62 1.43 -3.19 -0.290 0.54462E+04 178 tridymite -2.63 -3.31 -0.69 -0.229 0.11735E+04 187 wairakite 3.95 2.42 -1.53 -0.090 0.26153E+04 188 walstromite 11.51 7.62 -3.89 -0.778 0.66457E+04 189 wollastonite 10.46 7.62 -2.84 -0.569 0.48561E+04 190 pseudo-wollastonite 11.00 7.62 -3.38 -0.677 0.57759E+04 191 zoisite 22.85 19.03 -3.82 -0.173 0.65141E+04 192 akaganeite 7.75 6.28 -1.47 -0.318 0.25125E+04 193 beidellite-Ca -1.65 -4.83 -3.19 -0.197 0.54413E+04 194 beidellite-H -2.33 -6.64 -4.31 -0.275 0.73587E+04 195 beidellite-K -1.52 -4.96 -3.44 -0.211 0.58708E+04 196 beidellite-Mg -1.79 -5.21 -3.42 -0.212 0.58410E+04 197 beidellite-Na -1.34 -4.30 -2.96 -0.181 0.50571E+04 199 chalcedony -2.80 -3.31 -0.51 -0.170 0.87282E+03 201 montmorillonite-Ca -2.29 -4.64 -2.35 -0.145 0.40117E+04 202 montmorillonite-K -2.24 -4.77 -2.53 -0.155 0.43193E+04 203 montmorillonite-Mg -2.48 -5.02 -2.54 -0.157 0.43345E+04 204 montmorillonite-Na -2.04 -4.11 -2.07 -0.127 0.35413E+04 205 nontronite-Ca 3.21 2.99 -0.22 -0.014 0.38115E+03 206 nontronite-H 2.53 1.19 -1.34 -0.090 0.22965E+04 207 nontronite-K 3.34 2.87 -0.48 -0.031 0.81196E+03 208 nontronite-Mg 3.07 2.61 -0.46 -0.030 0.78804E+03 224 tobermorite 9.82 5.79 -4.03 -1.100 0.68834E+04 233 boehmite 4.41 2.37 -2.04 -0.339 0.34748E+04 235 ferrous-oxide 9.81 6.41 -3.40 -0.851 0.58092E+04 240 silica-amorphous -2.09 -3.31 -1.22 -0.407 0.20870E+04 242 an20ab80 2.02 1.41 -0.61 -0.047 0.10433E+04 243 an25ab75 2.65 1.88 -0.76 -0.059 0.13002E+04 244 an30ab70 3.28 2.36 -0.92 -0.071 0.15668E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 0.1000000 g Current total amount of reactant added: 3.2990000 g New total amount of reactant added: 3.3990000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.8096E-13 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 6 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 3.3990000 Water: Moles liquid = 0.5547E+02 kg liquid = 0.9994E+00 Moles total = 0.5547E+02 kg total = 0.9992E+00 Activity = 1.0000 Stoichiometric ionic strength = .2468885E-02 Osmotic coef. = 0.9723 True ionic strength = .4130515E-02 Chg. balance for total moles = 0.8096E-13 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.32809E-09 -9.4840 0.29762E-09 -9.5263 0.90714E+00 -0.0423 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13791E-03 -3.8604 0.12490E-03 -3.9034 0.90570E+00 -0.0430 4 SO4-- 0.25509E-04 -4.5933 0.18171E-04 -4.7406 0.71234E+00 -0.1473 5 HCO3- 0.95175E-05 -5.0215 0.86233E-05 -5.0643 0.90604E+00 -0.0429 6 HS- 0.65298E-13 -13.1851 0.59142E-13 -13.2281 0.90573E+00 -0.0430 7 Al+++ 0.12850E-25 -25.8911 0.61046E-26 -26.2143 0.47505E+00 -0.3233 8 H4SiO4 0.48392E-03 -3.3152 0.48392E-03 -3.3152 0.10000E+01 0.0000 9 Ca++ 0.11236E-07 -7.9494 0.79887E-08 -8.0975 0.71099E+00 -0.1481 10 Mg++ 0.54710E-10 -10.2619 0.38851E-10 -10.4106 0.71013E+00 -0.1487 11 Fe++ 0.32270E-12 -12.4912 0.22923E-12 -12.6397 0.71034E+00 -0.1485 12 K+ 0.40830E-04 -4.3890 0.36996E-04 -4.4318 0.90611E+00 -0.0428 13 Na+ 0.40527E-02 -2.3923 0.36704E-02 -2.4353 0.90567E+00 -0.0430 14 Mn++ 0.43355E-10 -10.3630 0.30803E-10 -10.5114 0.71049E+00 -0.1484 15 HPO4-- 0.77663E-05 -5.1098 0.55325E-05 -5.2571 0.71237E+00 -0.1473 16 HSiO3- 0.16763E-02 -2.7756 0.15182E-02 -2.8187 0.90570E+00 -0.0430 17 Ca(HSiO3)+ 0.30483E-09 -9.5159 0.27622E-09 -9.5587 0.90616E+00 -0.0428 18 Mg(HSiO3)+ 0.18449E-11 -11.7340 0.16718E-11 -11.7768 0.90616E+00 -0.0428 19 NaHSiO3,aq 0.90129E-04 -4.0451 0.90129E-04 -4.0451 0.10000E+01 0.0000 20 AlO+ 0.10347E-13 -13.9852 0.93760E-14 -14.0280 0.90616E+00 -0.0428 21 AlOH+2 0.19552E-19 -19.7088 0.13895E-19 -19.8571 0.71067E+00 -0.1483 22 HAlO2,aq 0.62739E-08 -8.2025 0.62739E-08 -8.2025 0.10000E+01 0.0000 23 AlO2- 0.51546E-04 -4.2878 0.46663E-04 -4.3310 0.90527E+00 -0.0432 24 CH4,aq 0.27285E-19 -19.5641 0.27264E-19 -19.5644 0.99924E+00 -0.0003 29 CO,aq 0.95460E-19 -19.0202 0.95460E-19 -19.0202 0.10000E+01 0.0000 30 CO2,aq 0.54881E-08 -8.2606 0.54839E-08 -8.2609 0.99924E+00 -0.0003 31 CO3-2 0.35548E-05 -5.4492 0.25308E-05 -5.5967 0.71194E+00 -0.1476 32 CaCO3,aq 0.25351E-09 -9.5960 0.25351E-09 -9.5960 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.19406E-11 -11.7121 0.17585E-11 -11.7549 0.90616E+00 -0.0428 34 CaCl+ 0.17820E-11 -11.7491 0.16148E-11 -11.7919 0.90616E+00 -0.0428 35 CaCl2,aq 0.47917E-16 -16.3195 0.47917E-16 -16.3195 0.10000E+01 0.0000 36 CaOH+ 0.21111E-08 -8.6755 0.19130E-08 -8.7183 0.90616E+00 -0.0428 37 CaSO4,aq 0.46096E-10 -10.3363 0.46096E-10 -10.3363 0.10000E+01 0.0000 38 HCl,aq 0.68118E-14 -14.1667 0.68118E-14 -14.1667 0.10000E+01 0.0000 43 FeCl+ 0.50011E-16 -16.3009 0.45318E-16 -16.3437 0.90616E+00 -0.0428 46 FeO,aq 0.10058E-09 -9.9975 0.10058E-09 -9.9975 0.10000E+01 0.0000 47 FeOH+ 0.27667E-10 -10.5580 0.25071E-10 -10.6008 0.90616E+00 -0.0428 48 HFeO2- 0.39042E-08 -8.4085 0.35360E-08 -8.4515 0.90570E+00 -0.0430 49 FeO+ 0.25069E-14 -14.6009 0.22717E-14 -14.6437 0.90616E+00 -0.0428 51 FeO2- 0.57942E-08 -8.2370 0.52478E-08 -8.2800 0.90570E+00 -0.0430 52 HFeO2,aq 0.19864E-09 -9.7019 0.19864E-09 -9.7019 0.10000E+01 0.0000 53 H2,aq 0.69348E-09 -9.1590 0.69295E-09 -9.1593 0.99924E+00 -0.0003 54 KCl,aq 0.83750E-10 -10.0770 0.83750E-10 -10.0770 0.10000E+01 0.0000 55 KHSO4,aq 0.56569E-18 -18.2474 0.56569E-18 -18.2474 0.10000E+01 0.0000 56 KOH,aq 0.53086E-07 -7.2750 0.53086E-07 -7.2750 0.10000E+01 0.0000 57 KSO4- 0.11518E-07 -7.9386 0.10432E-07 -7.9816 0.90570E+00 -0.0430 58 MgCO3,aq 0.30903E-12 -12.5100 0.30903E-12 -12.5100 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.96434E-14 -14.0158 0.87384E-14 -14.0586 0.90616E+00 -0.0428 60 MgCl+ 0.78547E-14 -14.1049 0.71176E-14 -14.1477 0.90616E+00 -0.0428 61 MgOH+ 0.56813E-10 -10.2456 0.51481E-10 -10.2884 0.90616E+00 -0.0428 63 MnO,aq 0.36014E-09 -9.4435 0.36014E-09 -9.4435 0.10000E+01 0.0000 64 MnOH+ 0.34538E-09 -9.4617 0.31297E-09 -9.5045 0.90616E+00 -0.0428 65 MnO2-2 0.18953E-12 -12.7223 0.13493E-12 -12.8699 0.71194E+00 -0.1476 66 HMnO2- 0.97142E-11 -11.0126 0.87982E-11 -11.0556 0.90570E+00 -0.0430 69 MnCl+ 0.26146E-13 -13.5826 0.23692E-13 -13.6254 0.90616E+00 -0.0428 70 MnSO4,aq 0.16159E-12 -12.7916 0.16159E-12 -12.7916 0.10000E+01 0.0000 71 NaCl,aq 0.15193E-06 -6.8184 0.15193E-06 -6.8184 0.10000E+01 0.0000 72 NaOH,aq 0.52987E-05 -5.2758 0.52987E-05 -5.2758 0.10000E+01 0.0000 74 OH- 0.21445E-02 -2.6687 0.19413E-02 -2.7119 0.90527E+00 -0.0432 79 HPO3-2 0.16781E-16 -16.7752 0.11947E-16 -16.9227 0.71194E+00 -0.1476 82 H3PO4,aq 0.34274E-14 -14.4650 0.34274E-14 -14.4650 0.10000E+01 0.0000 83 H2PO4- 0.33529E-07 -7.4746 0.30375E-07 -7.5175 0.90592E+00 -0.0429 84 PO4-3 0.31517E-07 -7.5015 0.15167E-07 -7.8191 0.48122E+00 -0.3177 87 H2P2O7-2 0.10161E-15 -15.9930 0.72343E-16 -16.1406 0.71194E+00 -0.1476 88 HP2O7-3 0.10215E-12 -12.9908 0.48536E-13 -13.3139 0.47513E+00 -0.3232 89 P2O7-4 0.14327E-12 -12.8439 0.38959E-13 -13.4094 0.27194E+00 -0.5655 90 H2S,aq 0.54442E-16 -16.2641 0.54400E-16 -16.2644 0.99924E+00 -0.0003 97 SO3-2 0.22896E-14 -14.6402 0.16362E-14 -14.7862 0.71465E+00 -0.1459 98 HSO3- 0.33665E-16 -16.4728 0.30491E-16 -16.5158 0.90570E+00 -0.0430 99 HSO4- 0.57501E-11 -11.2403 0.52117E-11 -11.2830 0.90638E+00 -0.0427 Charge balance for all species = 0.8968E-13 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.3280856E-09 -.4126063E-02 -.4157469E+01 0.0000 2 H2O 0.1000000E+01 0.5550874E+02 0.9996807E+06 0.0000 3 Cl- 0.1379071E-03 0.1380591E-03 0.4893014E+01 5.6229 4 SO4-- 0.2550859E-04 0.2552074E-04 0.2450764E+01 14.3121 5 HCO3- 0.9517519E-05 0.1307804E-04 0.7977256E+00 4.4620 6 HS- 0.6529754E-13 -.5756735E-09 -.1903247E-04 -3.7018 7 Al+++ 0.1285040E-25 0.5155232E-04 0.1390506E+01 2.3647 8 H4SiO4 0.4839210E-03 0.2250372E-02 0.2162249E+03 -3.3152 9 Ca++ 0.1123613E-07 0.1395543E-07 0.5591236E-03 10.9552 10 Mg++ 0.5470978E-10 0.1136940E-09 0.2763229E-05 8.6421 11 Fe++ 0.3227026E-12 0.1002563E-07 0.5597189E-03 6.4129 12 K+ 0.4082991E-04 0.4089460E-04 0.1598540E+01 5.0945 13 Na+ 0.4052724E-02 0.4148303E-02 0.9533758E+02 7.0911 14 Mn++ 0.4335487E-10 0.7589674E-09 0.4168257E-04 8.5413 15 HPO4-- 0.7766334E-05 0.7831381E-05 0.7514032E+00 13.7956 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.5626935E-01 -.4123526E-02 -.5214583E-01 0.0000000E+00 2 H2O 0.5546564E+02 0.5547460E+02 -.8956951E-02 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.1197023E-03 0.2550505E-04 0.9419730E-04 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.9419788E-04 -.5753194E-09 -.9419730E-04 0.0000000E+00 7 Al+++ 0.1108326E-01 0.5152062E-04 0.1103174E-01 0.0000000E+00 8 H4SiO4 0.3539305E-01 0.2248988E-02 0.3314406E-01 0.0000000E+00 9 Ca++ 0.3923806E-02 0.1394685E-07 0.3923792E-02 0.0000000E+00 10 Mg++ 0.2697619E-02 0.1136241E-09 0.2697619E-02 0.0000000E+00 11 Fe++ 0.2423516E-02 0.1001946E-07 0.2423506E-02 0.0000000E+00 12 K+ 0.7216561E-03 0.4086945E-04 0.6807866E-03 0.0000000E+00 13 Na+ 0.4426644E-02 0.4145752E-02 0.2808923E-03 0.0000000E+00 14 Mn++ 0.5893389E-04 0.7585007E-09 0.5893313E-04 0.0000000E+00 15 HPO4-- 0.2011384E-04 0.7826565E-05 0.1228728E-04 0.0000000E+00 Chg. balance for solid moles: -.3591E-18 Mass of aqueous solution: 0.999711E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 3.3990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) apatite-OH 0.4096E-05 -5.388 0.2057E-02 -2.687 0.5605E-01 0.6538E-03 clinochlore 0.5395E-03 -3.268 0.2999 -0.523 8.169 0.1141 daphnite 0.3340E-03 -3.476 0.2383 -0.623 6.492 0.7221E-01 chlorite-Mn 0.1179E-04 -4.929 0.8356E-02 -2.078 0.2276 0.2663E-02 hematite 0.2723E-03 -3.565 0.4349E-01 -1.362 1.185 0.8243E-02 microcline 0.6808E-03 -3.167 0.1895 -0.722 5.162 0.7402E-01 paragonite 0.2464E-03 -3.608 0.9418E-01 -1.026 2.566 0.3256E-01 stilbite 0.3903E-02 -2.409 2.751 0.439 74.93 1.283 nontronite-Na 0.1045E-03 -3.981 0.4442E-01 -1.352 1.210 0.1380E-01 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.6094E+00 0.6094E+00 1.0000 -0.215 daphnite 0.3773E+00 0.3773E+00 1.0000 -0.423 chlorite-Mn 0.1331E-01 0.1331E-01 1.0000 -1.876 hematite 0.1000E+01 0.1000E+01 1.0000 0.000 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 paragonite 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 nontronite-Na 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 3.670927 g Volume = 1.601211 cm3 Porosity: 32.1406% V(tot) - V(min): 0.75839E+00 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 3.3990000 g log = 0.5314 Original solution: 1000.0103000 g Original solution / Rock added: 294.21 (Water/Rock Ratio), log = 2.4687 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0203 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.1000E+01 0.9860 0.1006E+01 0.1020E+01 CO2,gas 0.5710E-06 1.0071 0.5867E-06 0.5826E-06 CH4,gas 0.3885E-16 1.0125 0.4013E-16 0.3963E-16 H2,gas 0.8912E-06 1.0005 0.9098E-06 0.9093E-06 H2S,gas 0.1472E-14 0.9960 0.1495E-14 0.1501E-14 S2,gas 0.9940E-37 1.0000 0.1014E-36 0.1014E-36 CO,gas 0.1394E-15 1.0000 0.1423E-15 0.1423E-15 SO3,gas 0.5965E-39 1.0000 0.6086E-39 0.6086E-39 SO2,gas 0.2111E-22 1.0000 0.2154E-22 0.2154E-22 HCl,gas 0.1178E-16 1.0000 0.1202E-16 0.1202E-16 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 32 apatite-OH -18.15 -18.15 0.00 0.000 -0.60662E-11 46 clinochlore 39.07 39.07 0.00 0.000 0.12132E-10 47 daphnite 28.97 28.97 0.00 0.000 0.60662E-11 48 chlorite-Mn 46.87 46.87 0.00 0.000 -0.24265E-10 90 hematite 12.57 12.57 0.00 0.000 -0.30331E-11 116 microcline -2.49 -2.49 0.00 0.000 0.15165E-11 121 paragonite 4.24 4.24 0.00 0.000 -0.10616E-10 163 stilbite -7.52 -7.52 0.00 0.000 -0.90992E-11 209 nontronite-Na 3.52 3.52 0.00 0.000 -0.12891E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -14.59 -7.93 -2.644 0.13541E+05 -6.232 3 CH4,gas 4.54 -13.55 -18.10 -4.524 0.30898E+05 -16.397 4 H2,gas 8.00 0.26 -7.74 -4.423 0.13216E+05 -6.041 5 H2S,gas -6.23 -22.75 -16.52 -8.262 0.28215E+05 -14.825 6 S2,gas -7.34 -46.03 -38.69 -5.953 0.66067E+05 -36.994 7 CO,gas 3.21 -14.33 -17.55 -5.399 0.29959E+05 -15.847 8 SO3,gas 17.12 -23.79 -40.91 -10.229 0.69861E+05 -39.216 9 SO2,gas 0.83 -23.53 -24.37 -6.498 0.41604E+05 -22.667 10 HCl,gas 5.19 -13.43 -18.62 -9.310 0.31792E+05 -16.920 11 acmite 7.71 6.74 -0.97 -0.100 0.16494E+04 15 albite-high 0.69 -0.49 -1.18 -0.091 0.20199E+04 16 albite -0.38 -0.49 -0.11 -0.008 0.18111E+03 19 spessartine 24.46 20.41 -4.05 -0.202 0.69149E+04 20 analcite 3.32 2.83 -0.50 -0.055 0.84788E+03 21 andalusite 5.00 1.41 -3.59 -0.359 0.61254E+04 22 andradite 39.01 35.49 -3.52 -0.183 0.60150E+04 26 annite 20.12 16.75 -3.37 -0.187 0.57560E+04 27 phlogopite 27.06 23.44 -3.62 -0.201 0.61893E+04 29 anorthite 12.71 9.05 -3.66 -0.281 0.62429E+04 35 aragonite 0.97 -3.64 -4.60 -1.534 0.78578E+04 36 brucite 12.57 8.64 -3.93 -0.785 0.67044E+04 37 calcite 0.81 -3.64 -4.45 -1.482 0.75936E+04 38 carnegieite-low 9.02 6.14 -2.88 -0.412 0.49223E+04 39 carnegieite-high 10.09 6.14 -3.95 -0.565 0.67493E+04 40 carpholite-Mg 8.58 6.74 -1.84 -0.123 0.31436E+04 41 carpholite-Fe 6.71 4.51 -2.20 -0.147 0.37578E+04 42 celadonite 5.34 2.84 -2.50 -0.147 0.42708E+04 43 celadonite-Fe 3.88 0.61 -3.27 -0.192 0.55754E+04 44 chrysotile 23.89 19.30 -4.60 -0.383 0.78485E+04 50 chloritoid-Mg 13.20 10.06 -3.14 -0.209 0.53640E+04 51 chloritoid-Fe 9.17 7.83 -1.35 -0.090 0.22992E+04 52 chloritoid-Mn 11.40 9.96 -1.45 -0.096 0.24684E+04 54 coesite -2.38 -3.32 -0.94 -0.313 0.16036E+04 59 corundum 8.38 4.73 -3.65 -0.332 0.62387E+04 61 cristobalite -2.56 -3.32 -0.75 -0.252 0.12889E+04 63 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71234E+04 65 diaspore 2.87 2.36 -0.51 -0.085 0.86913E+03 67 diopside 16.18 12.97 -3.21 -0.321 0.54888E+04 68 hedenbergite 14.21 10.74 -3.47 -0.347 0.59260E+04 75 epidote 24.67 22.98 -1.69 -0.082 0.28904E+04 76 clinozoisite 22.81 19.06 -3.75 -0.170 0.63985E+04 77 epidote-Fe 29.84 26.90 -2.95 -0.153 0.50290E+04 78 fayalite 14.05 9.51 -4.54 -0.648 0.77435E+04 79 ferrosilite 11.15 6.20 -4.95 -0.495 0.84588E+04 83 gibbsite 4.08 2.36 -1.71 -0.245 0.29277E+04 84 glaucophane 22.97 18.32 -4.66 -0.126 0.79549E+04 87 greenalite 16.14 12.61 -3.53 -0.294 0.60293E+04 91 heulandite -5.83 -7.52 -1.69 -0.077 0.28938E+04 95 jadeite 4.22 2.83 -1.39 -0.139 0.23734E+04 97 kalsilite 7.58 4.14 -3.44 -0.491 0.58736E+04 98 kaolinite -1.33 -1.90 -0.57 -0.052 0.97038E+03 99 kyanite 4.88 1.41 -3.46 -0.346 0.59113E+04 101 laumontite 2.88 2.42 -0.46 -0.031 0.78507E+03 102 lawsonite 9.62 9.05 -0.56 -0.037 0.95959E+03 103 leucite 4.12 0.83 -3.29 -0.329 0.56178E+04 105 lizardite 23.24 19.30 -3.95 -0.329 0.67412E+04 107 magnetite 20.09 18.98 -1.11 -0.090 0.18923E+04 108 minnesotaite 10.39 5.98 -4.41 -0.259 0.75302E+04 113 margarite 17.32 13.78 -3.54 -0.142 0.60447E+04 120 muscovite 2.58 2.24 -0.34 -0.020 0.57978E+03 122 nepheline 8.34 6.14 -2.20 -0.314 0.37546E+04 134 phlogopite-Na 29.65 25.44 -4.21 -0.234 0.71892E+04 136 prehnite 19.37 16.69 -2.68 -0.158 0.45724E+04 137 prehnite-Fe 22.50 20.61 -1.89 -0.113 0.32193E+04 138 pumpellyite-Fe 46.27 42.17 -4.10 -0.091 0.70071E+04 139 pumpellyite-Mg 48.99 44.39 -4.60 -0.102 0.78545E+04 145 pyroxmangite 7.40 5.23 -2.17 -0.435 0.37097E+04 146 pyrophyllite -6.18 -8.53 -2.36 -0.147 0.40224E+04 147 quartz -2.99 -3.32 -0.33 -0.109 0.55628E+03 152 rhodonite 7.45 5.23 -2.22 -0.444 0.37900E+04 153 sanidine -1.28 -2.49 -1.21 -0.093 0.20677E+04 156 sillimanite 5.26 1.41 -3.85 -0.385 0.65693E+04 164 stilpnomelane-Fe 13.02 12.82 -0.20 -0.006 0.33707E+03 165 stilpnomelane-Mg 27.44 23.97 -3.48 -0.104 0.59354E+04 168 sudoite 21.08 16.80 -4.28 -0.138 0.73082E+04 171 talc 16.49 12.67 -3.83 -0.225 0.65323E+04 174 tephroite 18.09 13.77 -4.32 -0.617 0.73737E+04 177 topaz-H 4.62 1.41 -3.20 -0.291 0.54713E+04 178 tridymite -2.63 -3.32 -0.69 -0.230 0.11763E+04 187 wairakite 3.95 2.42 -1.53 -0.090 0.26070E+04 188 walstromite 11.51 7.64 -3.87 -0.774 0.66067E+04 189 wollastonite 10.46 7.64 -2.82 -0.564 0.48171E+04 190 pseudo-wollastonite 11.00 7.64 -3.36 -0.672 0.57370E+04 191 zoisite 22.85 19.06 -3.79 -0.172 0.64725E+04 192 akaganeite 7.75 6.28 -1.47 -0.318 0.25125E+04 193 beidellite-Ca -1.65 -4.85 -3.20 -0.198 0.54707E+04 194 beidellite-H -2.33 -6.66 -4.33 -0.276 0.73949E+04 195 beidellite-K -1.52 -4.98 -3.46 -0.212 0.59006E+04 196 beidellite-Mg -1.79 -5.23 -3.44 -0.213 0.58762E+04 197 beidellite-Na -1.34 -4.32 -2.97 -0.182 0.50795E+04 199 chalcedony -2.80 -3.32 -0.51 -0.171 0.87558E+03 201 montmorillonite-Ca -2.29 -4.65 -2.36 -0.146 0.40325E+04 202 montmorillonite-K -2.24 -4.78 -2.54 -0.156 0.43405E+04 203 montmorillonite-Mg -2.48 -5.03 -2.55 -0.158 0.43612E+04 204 montmorillonite-Na -2.04 -4.12 -2.08 -0.128 0.35552E+04 205 nontronite-Ca 3.21 2.99 -0.23 -0.015 0.38809E+03 206 nontronite-H 2.53 1.18 -1.35 -0.091 0.23103E+04 207 nontronite-K 3.34 2.86 -0.48 -0.031 0.81935E+03 208 nontronite-Mg 3.07 2.61 -0.47 -0.030 0.80085E+03 224 tobermorite 9.82 5.81 -4.01 -1.095 0.68515E+04 233 boehmite 4.41 2.36 -2.04 -0.340 0.34860E+04 235 ferrous-oxide 9.81 6.41 -3.40 -0.850 0.58031E+04 240 silica-amorphous -2.09 -3.32 -1.22 -0.408 0.20898E+04 242 an20ab80 2.02 1.42 -0.60 -0.046 0.10226E+04 243 an25ab75 2.65 1.90 -0.75 -0.058 0.12800E+04 244 an30ab70 3.28 2.37 -0.91 -0.070 0.15469E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 0.1000000 g Current total amount of reactant added: 3.3990000 g New total amount of reactant added: 3.4990000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.8095E-13 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 6 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 3.4990000 Water: Moles liquid = 0.5547E+02 kg liquid = 0.9994E+00 Moles total = 0.5546E+02 kg total = 0.9992E+00 Activity = 1.0000 Stoichiometric ionic strength = .2529661E-02 Osmotic coef. = 0.9720 True ionic strength = .4240651E-02 Chg. balance for total moles = 0.8095E-13 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.31903E-09 -9.4962 0.28913E-09 -9.5389 0.90628E+00 -0.0427 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13791E-03 -3.8604 0.12478E-03 -3.9039 0.90481E+00 -0.0434 4 SO4-- 0.25509E-04 -4.5933 0.18101E-04 -4.7423 0.70959E+00 -0.1490 5 HCO3- 0.94348E-05 -5.0253 0.85400E-05 -5.0685 0.90516E+00 -0.0433 6 HS- 0.67452E-13 -13.1710 0.61033E-13 -13.2144 0.90484E+00 -0.0434 7 Al+++ 0.11713E-25 -25.9313 0.55156E-26 -26.2584 0.47091E+00 -0.3271 8 H4SiO4 0.48218E-03 -3.3168 0.48218E-03 -3.3168 0.10000E+01 0.0000 9 Ca++ 0.11243E-07 -7.9491 0.79627E-08 -8.0989 0.70821E+00 -0.1498 10 Mg++ 0.52255E-10 -10.2819 0.36962E-10 -10.4322 0.70735E+00 -0.1504 11 Fe++ 0.30822E-12 -12.5111 0.21808E-12 -12.6614 0.70755E+00 -0.1502 12 K+ 0.40729E-04 -4.3901 0.36869E-04 -4.4333 0.90522E+00 -0.0432 13 Na+ 0.41631E-02 -2.3806 0.37667E-02 -2.4240 0.90477E+00 -0.0435 14 Mn++ 0.41409E-10 -10.3829 0.29306E-10 -10.5330 0.70771E+00 -0.1501 15 HPO4-- 0.75423E-05 -5.1225 0.53522E-05 -5.2715 0.70962E+00 -0.1490 16 HSiO3- 0.17210E-02 -2.7642 0.15572E-02 -2.8077 0.90481E+00 -0.0434 17 Ca(HSiO3)+ 0.31193E-09 -9.5059 0.28238E-09 -9.5492 0.90528E+00 -0.0432 18 Mg(HSiO3)+ 0.18020E-11 -11.7442 0.16313E-11 -11.7875 0.90528E+00 -0.0432 19 NaHSiO3,aq 0.94865E-04 -4.0229 0.94865E-04 -4.0229 0.10000E+01 0.0000 20 AlO+ 0.99152E-14 -14.0037 0.89760E-14 -14.0469 0.90528E+00 -0.0432 21 AlOH+2 0.18255E-19 -19.7386 0.12923E-19 -19.8886 0.70789E+00 -0.1500 22 HAlO2,aq 0.61825E-08 -8.2088 0.61825E-08 -8.2088 0.10000E+01 0.0000 23 AlO2- 0.52339E-04 -4.2812 0.47334E-04 -4.3248 0.90437E+00 -0.0437 24 CH4,aq 0.27993E-19 -19.5529 0.27971E-19 -19.5533 0.99922E+00 -0.0003 29 CO,aq 0.93329E-19 -19.0300 0.93329E-19 -19.0300 0.10000E+01 0.0000 30 CO2,aq 0.52802E-08 -8.2774 0.52761E-08 -8.2777 0.99922E+00 -0.0003 31 CO3-2 0.36379E-05 -5.4392 0.25799E-05 -5.5884 0.70919E+00 -0.1492 32 CaCO3,aq 0.25759E-09 -9.5891 0.25759E-09 -9.5891 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.19174E-11 -11.7173 0.17358E-11 -11.7605 0.90528E+00 -0.0432 34 CaCl+ 0.17761E-11 -11.7505 0.16079E-11 -11.7937 0.90528E+00 -0.0432 35 CaCl2,aq 0.47666E-16 -16.3218 0.47666E-16 -16.3218 0.10000E+01 0.0000 36 CaOH+ 0.21681E-08 -8.6639 0.19628E-08 -8.7071 0.90528E+00 -0.0432 37 CaSO4,aq 0.45769E-10 -10.3394 0.45769E-10 -10.3394 0.10000E+01 0.0000 38 HCl,aq 0.66110E-14 -14.1797 0.66110E-14 -14.1797 0.10000E+01 0.0000 43 FeCl+ 0.47579E-16 -16.3226 0.43072E-16 -16.3658 0.90528E+00 -0.0432 46 FeO,aq 0.10139E-09 -9.9940 0.10139E-09 -9.9940 0.10000E+01 0.0000 47 FeOH+ 0.27121E-10 -10.5667 0.24552E-10 -10.6099 0.90528E+00 -0.0432 48 HFeO2- 0.40552E-08 -8.3920 0.36692E-08 -8.4354 0.90481E+00 -0.0434 49 FeO+ 0.24378E-14 -14.6130 0.22069E-14 -14.6562 0.90528E+00 -0.0432 51 FeO2- 0.59702E-08 -8.2240 0.54019E-08 -8.2675 0.90481E+00 -0.0434 52 HFeO2,aq 0.19864E-09 -9.7019 0.19864E-09 -9.7019 0.10000E+01 0.0000 53 H2,aq 0.70472E-09 -9.1520 0.70417E-09 -9.1523 0.99922E+00 -0.0003 54 KCl,aq 0.83380E-10 -10.0789 0.83380E-10 -10.0789 0.10000E+01 0.0000 55 KHSO4,aq 0.54556E-18 -18.2632 0.54556E-18 -18.2632 0.10000E+01 0.0000 56 KOH,aq 0.54457E-07 -7.2639 0.54457E-07 -7.2639 0.10000E+01 0.0000 57 KSO4- 0.11446E-07 -7.9414 0.10356E-07 -7.9848 0.90481E+00 -0.0434 58 MgCO3,aq 0.29972E-12 -12.5233 0.29972E-12 -12.5233 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.90948E-14 -14.0412 0.82333E-14 -14.0844 0.90528E+00 -0.0432 60 MgCl+ 0.74726E-14 -14.1265 0.67648E-14 -14.1697 0.90528E+00 -0.0432 61 MgOH+ 0.55692E-10 -10.2542 0.50416E-10 -10.2974 0.90528E+00 -0.0432 63 MnO,aq 0.36304E-09 -9.4400 0.36304E-09 -9.4400 0.10000E+01 0.0000 64 MnOH+ 0.33857E-09 -9.4704 0.30650E-09 -9.5136 0.90528E+00 -0.0432 65 MnO2-2 0.20323E-12 -12.6920 0.14413E-12 -12.8413 0.70919E+00 -0.1492 66 HMnO2- 0.10090E-10 -10.9961 0.91295E-11 -11.0396 0.90481E+00 -0.0434 69 MnCl+ 0.24874E-13 -13.6043 0.22518E-13 -13.6475 0.90528E+00 -0.0432 70 MnSO4,aq 0.15314E-12 -12.8149 0.15314E-12 -12.8149 0.10000E+01 0.0000 71 NaCl,aq 0.15576E-06 -6.8075 0.15576E-06 -6.8075 0.10000E+01 0.0000 72 NaOH,aq 0.55973E-05 -5.2520 0.55973E-05 -5.2520 0.10000E+01 0.0000 74 OH- 0.22096E-02 -2.6557 0.19983E-02 -2.6993 0.90437E+00 -0.0437 79 HPO3-2 0.16561E-16 -16.7809 0.11745E-16 -16.9301 0.70919E+00 -0.1492 82 H3PO4,aq 0.31292E-14 -14.5046 0.31292E-14 -14.5046 0.10000E+01 0.0000 83 H2PO4- 0.31542E-07 -7.5011 0.28547E-07 -7.5444 0.90504E+00 -0.0433 84 PO4-3 0.31652E-07 -7.4996 0.15103E-07 -7.8209 0.47717E+00 -0.3213 87 H2P2O7-2 0.90099E-16 -16.0453 0.63897E-16 -16.1945 0.70919E+00 -0.1492 88 HP2O7-3 0.93693E-13 -13.0283 0.44128E-13 -13.3553 0.47099E+00 -0.3270 89 P2O7-4 0.13616E-12 -12.8659 0.36462E-13 -13.4382 0.26778E+00 -0.5722 90 H2S,aq 0.54582E-16 -16.2630 0.54539E-16 -16.2633 0.99922E+00 -0.0003 97 SO3-2 0.23265E-14 -14.6333 0.16564E-14 -14.7808 0.71195E+00 -0.1475 98 HSO3- 0.33140E-16 -16.4796 0.29985E-16 -16.5231 0.90481E+00 -0.0434 99 HSO4- 0.55700E-11 -11.2541 0.50437E-11 -11.2973 0.90550E+00 -0.0431 Charge balance for all species = 0.8962E-13 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.3190299E-09 -.4244207E-02 -.4276480E+01 0.0000 2 H2O 0.1000000E+01 0.5550875E+02 0.9996736E+06 0.0000 3 Cl- 0.1379057E-03 0.1380615E-03 0.4893063E+01 5.6350 4 SO4-- 0.2550911E-04 0.2552121E-04 0.2450791E+01 14.3355 5 HCO3- 0.9434842E-05 0.1307827E-04 0.7977336E+00 4.4704 6 HS- 0.6745192E-13 -.5948592E-09 -.1966663E-04 -3.6755 7 Al+++ 0.1171268E-25 0.5234535E-04 0.1411885E+01 2.3583 8 H4SiO4 0.4821767E-03 0.2298053E-02 0.2208046E+03 -3.3168 9 Ca++ 0.1124329E-07 0.1403041E-07 0.5621233E-03 10.9789 10 Mg++ 0.5225505E-10 0.1100649E-09 0.2675007E-05 8.6456 11 Fe++ 0.3082214E-12 0.1035289E-07 0.5779853E-03 6.4164 12 K+ 0.4072932E-04 0.4079530E-04 0.1594646E+01 5.1056 13 Na+ 0.4163100E-02 0.4263718E-02 0.9798935E+02 7.1149 14 Mn++ 0.4140913E-10 0.7534899E-09 0.4138143E-04 8.5448 15 HPO4-- 0.7542293E-05 0.7605488E-05 0.7297238E+00 13.8063 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.5792521E-01 -.4241523E-02 -.5368368E-01 0.0000000E+00 2 H2O 0.5546439E+02 0.5547365E+02 -.9257944E-02 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.1224737E-03 0.2550506E-04 0.9696862E-04 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.9696922E-04 -.5944830E-09 -.9696862E-04 0.0000000E+00 7 Al+++ 0.1140933E-01 0.5231225E-04 0.1135702E-01 0.0000000E+00 8 H4SiO4 0.3643433E-01 0.2296599E-02 0.3413773E-01 0.0000000E+00 9 Ca++ 0.4038820E-02 0.1402153E-07 0.4038806E-02 0.0000000E+00 10 Mg++ 0.2776984E-02 0.1099953E-09 0.2776984E-02 0.0000000E+00 11 Fe++ 0.2494817E-02 0.1034634E-07 0.2494807E-02 0.0000000E+00 12 K+ 0.7428875E-03 0.4076950E-04 0.7021180E-03 0.0000000E+00 13 Na+ 0.4552168E-02 0.4261021E-02 0.2911473E-03 0.0000000E+00 14 Mn++ 0.6066775E-04 0.7530133E-09 0.6066699E-04 0.0000000E+00 15 HPO4-- 0.2070560E-04 0.7600677E-05 0.1310492E-04 0.0000000E+00 Chg. balance for solid moles: -.1254E-17 Mass of aqueous solution: 0.999701E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 3.4990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) apatite-OH 0.4368E-05 -5.360 0.2194E-02 -2.659 0.5805E-01 0.6973E-03 clinochlore 0.5554E-03 -3.255 0.3087 -0.510 8.166 0.1174 daphnite 0.3438E-03 -3.464 0.2453 -0.610 6.489 0.7434E-01 chlorite-Mn 0.1213E-04 -4.916 0.8602E-02 -2.065 0.2276 0.2741E-02 hematite 0.2740E-03 -3.562 0.4376E-01 -1.359 1.158 0.8294E-02 microcline 0.7021E-03 -3.154 0.1954 -0.709 5.170 0.7634E-01 paragonite 0.2536E-03 -3.596 0.9692E-01 -1.014 2.564 0.3350E-01 stilbite 0.4017E-02 -2.396 2.831 0.452 74.89 1.320 nontronite-Na 0.1139E-03 -3.944 0.4842E-01 -1.315 1.281 0.1504E-01 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.6094E+00 0.6094E+00 1.0000 -0.215 daphnite 0.3773E+00 0.3773E+00 1.0000 -0.423 chlorite-Mn 0.1331E-01 0.1331E-01 1.0000 -1.876 hematite 0.1000E+01 0.1000E+01 1.0000 0.000 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 paragonite 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 nontronite-Na 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 3.780175 g Volume = 1.648727 cm3 Porosity: 31.2916% V(tot) - V(min): 0.75087E+00 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 3.4990000 g log = 0.5439 Original solution: 1000.0103000 g Original solution / Rock added: 285.80 (Water/Rock Ratio), log = 2.4561 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0203 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.1000E+01 0.9860 0.1006E+01 0.1020E+01 CO2,gas 0.5494E-06 1.0071 0.5645E-06 0.5605E-06 CH4,gas 0.3985E-16 1.0125 0.4117E-16 0.4066E-16 H2,gas 0.9056E-06 1.0005 0.9245E-06 0.9240E-06 H2S,gas 0.1475E-14 0.9960 0.1499E-14 0.1505E-14 S2,gas 0.9675E-37 1.0000 0.9872E-37 0.9872E-37 CO,gas 0.1363E-15 1.0000 0.1391E-15 0.1391E-15 SO3,gas 0.5608E-39 1.0000 0.5721E-39 0.5721E-39 SO2,gas 0.2017E-22 1.0000 0.2058E-22 0.2058E-22 HCl,gas 0.1143E-16 1.0000 0.1167E-16 0.1167E-16 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 32 apatite-OH -18.15 -18.15 0.00 0.000 -0.60662E-11 46 clinochlore 39.07 39.07 0.00 0.000 0.36397E-10 47 daphnite 28.97 28.97 0.00 0.000 0.60662E-10 48 chlorite-Mn 46.87 46.87 0.00 0.000 0.24265E-10 90 hematite 12.57 12.57 0.00 0.000 0.90992E-11 116 microcline -2.49 -2.49 0.00 0.000 0.13649E-10 121 paragonite 4.24 4.24 0.00 0.000 0.13649E-10 163 stilbite -7.52 -7.52 0.00 0.000 0.15165E-10 209 nontronite-Na 3.52 3.52 0.00 0.000 0.45496E-11 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -14.61 -7.95 -2.649 0.13570E+05 -6.248 3 CH4,gas 4.54 -13.54 -18.08 -4.521 0.30879E+05 -16.385 4 H2,gas 8.00 0.27 -7.73 -4.419 0.13204E+05 -6.034 5 H2S,gas -6.23 -22.75 -16.52 -8.262 0.28213E+05 -14.824 6 S2,gas -7.34 -46.04 -38.70 -5.955 0.66087E+05 -37.006 7 CO,gas 3.21 -14.34 -17.56 -5.402 0.29976E+05 -15.857 8 SO3,gas 17.12 -23.82 -40.94 -10.235 0.69906E+05 -39.242 9 SO2,gas 0.83 -23.55 -24.39 -6.503 0.41638E+05 -22.687 10 HCl,gas 5.19 -13.44 -18.63 -9.316 0.31814E+05 -16.933 11 acmite 7.71 6.76 -0.95 -0.098 0.16142E+04 15 albite-high 0.69 -0.48 -1.17 -0.090 0.19982E+04 16 albite -0.38 -0.48 -0.09 -0.007 0.15937E+03 19 spessartine 24.46 20.40 -4.06 -0.203 0.69268E+04 20 analcite 3.32 2.84 -0.48 -0.054 0.82346E+03 21 andalusite 5.00 1.40 -3.60 -0.360 0.61498E+04 22 andradite 39.01 35.55 -3.46 -0.180 0.59016E+04 26 annite 20.12 16.76 -3.36 -0.187 0.57381E+04 27 phlogopite 27.06 23.45 -3.61 -0.201 0.61714E+04 29 anorthite 12.71 9.06 -3.65 -0.281 0.62295E+04 35 aragonite 0.97 -3.63 -4.60 -1.532 0.78460E+04 36 brucite 12.57 8.65 -3.92 -0.785 0.66984E+04 37 calcite 0.81 -3.63 -4.44 -1.480 0.75818E+04 38 carnegieite-low 9.02 6.16 -2.87 -0.410 0.48952E+04 39 carnegieite-high 10.09 6.16 -3.94 -0.562 0.67222E+04 40 carpholite-Mg 8.58 6.73 -1.85 -0.124 0.31648E+04 41 carpholite-Fe 6.71 4.50 -2.21 -0.148 0.37789E+04 42 celadonite 5.34 2.84 -2.50 -0.147 0.42675E+04 43 celadonite-Fe 3.88 0.61 -3.26 -0.192 0.55721E+04 44 chrysotile 23.89 19.30 -4.59 -0.382 0.78360E+04 50 chloritoid-Mg 13.20 10.05 -3.15 -0.210 0.53824E+04 51 chloritoid-Fe 9.17 7.82 -1.36 -0.090 0.23176E+04 52 chloritoid-Mn 11.40 9.94 -1.46 -0.097 0.24869E+04 54 coesite -2.38 -3.32 -0.94 -0.314 0.16063E+04 59 corundum 8.38 4.72 -3.67 -0.333 0.62604E+04 61 cristobalite -2.56 -3.32 -0.76 -0.252 0.12916E+04 63 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71234E+04 65 diaspore 2.87 2.36 -0.52 -0.086 0.88000E+03 67 diopside 16.18 12.99 -3.19 -0.319 0.54477E+04 68 hedenbergite 14.21 10.76 -3.45 -0.345 0.58849E+04 75 epidote 24.67 23.01 -1.66 -0.081 0.28392E+04 76 clinozoisite 22.81 19.08 -3.72 -0.169 0.63581E+04 77 epidote-Fe 29.84 26.93 -2.91 -0.151 0.49669E+04 78 fayalite 14.05 9.52 -4.53 -0.647 0.77343E+04 79 ferrosilite 11.15 6.20 -4.95 -0.495 0.84523E+04 83 gibbsite 4.08 2.36 -1.72 -0.246 0.29385E+04 84 glaucophane 22.97 18.35 -4.63 -0.125 0.78989E+04 87 greenalite 16.14 12.62 -3.52 -0.294 0.60168E+04 91 heulandite -5.83 -7.52 -1.69 -0.077 0.28938E+04 95 jadeite 4.22 2.84 -1.38 -0.138 0.23489E+04 97 kalsilite 7.58 4.15 -3.44 -0.491 0.58683E+04 98 kaolinite -1.33 -1.92 -0.58 -0.053 0.99748E+03 99 kyanite 4.88 1.40 -3.48 -0.348 0.59357E+04 101 laumontite 2.88 2.43 -0.46 -0.030 0.77704E+03 102 lawsonite 9.62 9.06 -0.55 -0.037 0.94620E+03 103 leucite 4.12 0.83 -3.29 -0.329 0.56151E+04 105 lizardite 23.24 19.30 -3.94 -0.328 0.67286E+04 107 magnetite 20.09 18.98 -1.10 -0.090 0.18864E+04 108 minnesotaite 10.39 5.98 -4.41 -0.259 0.75231E+04 113 margarite 17.32 13.78 -3.55 -0.142 0.60531E+04 120 muscovite 2.58 2.23 -0.35 -0.021 0.60153E+03 122 nepheline 8.34 6.16 -2.18 -0.312 0.37275E+04 134 phlogopite-Na 29.65 25.46 -4.19 -0.233 0.71496E+04 136 prehnite 19.37 16.72 -2.65 -0.156 0.45212E+04 137 prehnite-Fe 22.50 20.65 -1.85 -0.111 0.31573E+04 138 pumpellyite-Fe 46.27 42.22 -4.05 -0.090 0.69096E+04 139 pumpellyite-Mg 48.99 44.45 -4.54 -0.101 0.77570E+04 145 pyroxmangite 7.40 5.23 -2.17 -0.434 0.37064E+04 146 pyrophyllite -6.18 -8.55 -2.37 -0.148 0.40548E+04 147 quartz -2.99 -3.32 -0.33 -0.109 0.55896E+03 152 rhodonite 7.45 5.23 -2.22 -0.444 0.37867E+04 153 sanidine -1.28 -2.49 -1.21 -0.093 0.20677E+04 156 sillimanite 5.26 1.40 -3.86 -0.386 0.65937E+04 164 stilpnomelane-Fe 13.02 12.82 -0.20 -0.006 0.34101E+03 165 stilpnomelane-Mg 27.44 23.96 -3.48 -0.104 0.59394E+04 168 sudoite 21.08 16.77 -4.30 -0.139 0.73478E+04 171 talc 16.49 12.67 -3.82 -0.225 0.65251E+04 174 tephroite 18.09 13.77 -4.31 -0.616 0.73644E+04 177 topaz-H 4.62 1.40 -3.22 -0.293 0.54958E+04 178 tridymite -2.63 -3.32 -0.69 -0.230 0.11789E+04 187 wairakite 3.95 2.43 -1.52 -0.090 0.25990E+04 188 walstromite 11.51 7.66 -3.85 -0.769 0.65689E+04 189 wollastonite 10.46 7.66 -2.80 -0.560 0.47793E+04 190 pseudo-wollastonite 11.00 7.66 -3.34 -0.668 0.56992E+04 191 zoisite 22.85 19.08 -3.77 -0.171 0.64322E+04 192 akaganeite 7.75 6.28 -1.47 -0.318 0.25125E+04 193 beidellite-Ca -1.65 -4.87 -3.22 -0.199 0.54992E+04 194 beidellite-H -2.33 -6.68 -4.35 -0.278 0.74301E+04 195 beidellite-K -1.52 -4.99 -3.47 -0.213 0.59295E+04 196 beidellite-Mg -1.79 -5.25 -3.46 -0.214 0.59103E+04 197 beidellite-Na -1.34 -4.33 -2.99 -0.183 0.51013E+04 199 chalcedony -2.80 -3.32 -0.51 -0.171 0.87825E+03 201 montmorillonite-Ca -2.29 -4.66 -2.37 -0.147 0.40527E+04 202 montmorillonite-K -2.24 -4.79 -2.55 -0.156 0.43612E+04 203 montmorillonite-Mg -2.48 -5.05 -2.57 -0.159 0.43871E+04 204 montmorillonite-Na -2.04 -4.13 -2.09 -0.128 0.35687E+04 205 nontronite-Ca 3.21 2.98 -0.23 -0.015 0.39482E+03 206 nontronite-H 2.53 1.17 -1.36 -0.091 0.23237E+04 207 nontronite-K 3.34 2.86 -0.48 -0.031 0.82653E+03 208 nontronite-Mg 3.07 2.60 -0.48 -0.031 0.81328E+03 224 tobermorite 9.82 5.83 -3.99 -1.090 0.68204E+04 233 boehmite 4.41 2.36 -2.05 -0.341 0.34969E+04 235 ferrous-oxide 9.81 6.42 -3.40 -0.849 0.57971E+04 240 silica-amorphous -2.09 -3.32 -1.23 -0.408 0.20924E+04 242 an20ab80 2.02 1.43 -0.59 -0.045 0.10026E+04 243 an25ab75 2.65 1.91 -0.74 -0.057 0.12603E+04 244 an30ab70 3.28 2.38 -0.89 -0.069 0.15277E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 0.1000000 g Current total amount of reactant added: 3.4990000 g New total amount of reactant added: 3.5990000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.8094E-13 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 6 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 3.5990000 Water: Moles liquid = 0.5547E+02 kg liquid = 0.9994E+00 Moles total = 0.5546E+02 kg total = 0.9992E+00 Activity = 1.0000 Stoichiometric ionic strength = .2590426E-02 Osmotic coef. = 0.9717 True ionic strength = .4350712E-02 Chg. balance for total moles = 0.8094E-13 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.31048E-09 -9.5080 0.28112E-09 -9.5511 0.90543E+00 -0.0431 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13790E-03 -3.8604 0.12466E-03 -3.9043 0.90393E+00 -0.0439 4 SO4-- 0.25510E-04 -4.5933 0.18033E-04 -4.7439 0.70690E+00 -0.1506 5 HCO3- 0.93533E-05 -5.0290 0.84581E-05 -5.0727 0.90429E+00 -0.0437 6 HS- 0.69613E-13 -13.1573 0.62928E-13 -13.2012 0.90397E+00 -0.0438 7 Al+++ 0.10706E-25 -25.9704 0.49980E-26 -26.3012 0.46686E+00 -0.3308 8 H4SiO4 0.48049E-03 -3.3183 0.48049E-03 -3.3183 0.10000E+01 0.0000 9 Ca++ 0.11251E-07 -7.9488 0.79377E-08 -8.1003 0.70550E+00 -0.1515 10 Mg++ 0.49980E-10 -10.3012 0.35216E-10 -10.4533 0.70461E+00 -0.1521 11 Fe++ 0.29480E-12 -12.5305 0.20778E-12 -12.6824 0.70482E+00 -0.1519 12 K+ 0.40633E-04 -4.3911 0.36747E-04 -4.4348 0.90436E+00 -0.0437 13 Na+ 0.42734E-02 -2.3692 0.38627E-02 -2.4131 0.90390E+00 -0.0439 14 Mn++ 0.39606E-10 -10.4022 0.27921E-10 -10.5541 0.70498E+00 -0.1518 15 HPO4-- 0.73308E-05 -5.1348 0.51824E-05 -5.2855 0.70693E+00 -0.1506 16 HSiO3- 0.17656E-02 -2.7531 0.15959E-02 -2.7970 0.90393E+00 -0.0439 17 Ca(HSiO3)+ 0.31900E-09 -9.4962 0.28850E-09 -9.5398 0.90441E+00 -0.0436 18 Mg(HSiO3)+ 0.17613E-11 -11.7542 0.15929E-11 -11.7978 0.90441E+00 -0.0436 19 NaHSiO3,aq 0.99705E-04 -4.0013 0.99705E-04 -4.0013 0.10000E+01 0.0000 20 AlO+ 0.95132E-14 -14.0217 0.86038E-14 -14.0653 0.90441E+00 -0.0436 21 AlOH+2 0.17079E-19 -19.7675 0.12044E-19 -19.9192 0.70517E+00 -0.1517 22 HAlO2,aq 0.60951E-08 -8.2150 0.60951E-08 -8.2150 0.10000E+01 0.0000 23 AlO2- 0.53121E-04 -4.2747 0.47994E-04 -4.3188 0.90348E+00 -0.0441 24 CH4,aq 0.28694E-19 -19.5422 0.28671E-19 -19.5426 0.99920E+00 -0.0003 29 CO,aq 0.91287E-19 -19.0396 0.91287E-19 -19.0396 0.10000E+01 0.0000 30 CO2,aq 0.50847E-08 -8.2937 0.50807E-08 -8.2941 0.99920E+00 -0.0003 31 CO3-2 0.37198E-05 -5.4295 0.26280E-05 -5.5804 0.70649E+00 -0.1509 32 CaCO3,aq 0.26157E-09 -9.5824 0.26157E-09 -9.5824 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.18949E-11 -11.7224 0.17138E-11 -11.7660 0.90441E+00 -0.0436 34 CaCl+ 0.17705E-11 -11.7519 0.16013E-11 -11.7955 0.90441E+00 -0.0436 35 CaCl2,aq 0.47423E-16 -16.3240 0.47423E-16 -16.3240 0.10000E+01 0.0000 36 CaOH+ 0.22251E-08 -8.6527 0.20124E-08 -8.6963 0.90441E+00 -0.0436 37 CaSO4,aq 0.45454E-10 -10.3424 0.45454E-10 -10.3424 0.10000E+01 0.0000 38 HCl,aq 0.64215E-14 -14.1924 0.64215E-14 -14.1924 0.10000E+01 0.0000 43 FeCl+ 0.45330E-16 -16.3436 0.40997E-16 -16.3872 0.90441E+00 -0.0436 46 FeO,aq 0.10219E-09 -9.9906 0.10219E-09 -9.9906 0.10000E+01 0.0000 47 FeOH+ 0.26602E-10 -10.5751 0.24059E-10 -10.6187 0.90441E+00 -0.0436 48 HFeO2- 0.42075E-08 -8.3760 0.38033E-08 -8.4198 0.90393E+00 -0.0439 49 FeO+ 0.23725E-14 -14.6248 0.21457E-14 -14.6684 0.90441E+00 -0.0436 51 FeO2- 0.61463E-08 -8.2114 0.55558E-08 -8.2553 0.90393E+00 -0.0439 52 HFeO2,aq 0.19864E-09 -9.7019 0.19864E-09 -9.7019 0.10000E+01 0.0000 53 H2,aq 0.71582E-09 -9.1452 0.71525E-09 -9.1455 0.99920E+00 -0.0003 54 KCl,aq 0.83022E-10 -10.0808 0.83022E-10 -10.0808 0.10000E+01 0.0000 55 KHSO4,aq 0.52669E-18 -18.2784 0.52669E-18 -18.2784 0.10000E+01 0.0000 56 KOH,aq 0.55823E-07 -7.2532 0.55823E-07 -7.2532 0.10000E+01 0.0000 57 KSO4- 0.11376E-07 -7.9440 0.10283E-07 -7.9879 0.90393E+00 -0.0439 58 MgCO3,aq 0.29088E-12 -12.5363 0.29088E-12 -12.5363 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.85903E-14 -14.0660 0.77692E-14 -14.1096 0.90441E+00 -0.0436 60 MgCl+ 0.71195E-14 -14.1476 0.64389E-14 -14.1912 0.90441E+00 -0.0436 61 MgOH+ 0.54625E-10 -10.2626 0.49403E-10 -10.3062 0.90441E+00 -0.0436 63 MnO,aq 0.36589E-09 -9.4367 0.36589E-09 -9.4367 0.10000E+01 0.0000 64 MnOH+ 0.33208E-09 -9.4788 0.30034E-09 -9.5224 0.90441E+00 -0.0436 65 MnO2-2 0.21749E-12 -12.6626 0.15365E-12 -12.8135 0.70649E+00 -0.1509 66 HMnO2- 0.10469E-10 -10.9801 0.94633E-11 -11.0240 0.90393E+00 -0.0439 69 MnCl+ 0.23698E-13 -13.6253 0.21433E-13 -13.6689 0.90441E+00 -0.0436 70 MnSO4,aq 0.14536E-12 -12.8376 0.14536E-12 -12.8376 0.10000E+01 0.0000 71 NaCl,aq 0.15957E-06 -6.7970 0.15957E-06 -6.7970 0.10000E+01 0.0000 72 NaOH,aq 0.59036E-05 -5.2289 0.59036E-05 -5.2289 0.10000E+01 0.0000 74 OH- 0.22748E-02 -2.6431 0.20553E-02 -2.6871 0.90348E+00 -0.0441 79 HPO3-2 0.16350E-16 -16.7865 0.11551E-16 -16.9374 0.70649E+00 -0.1509 82 H3PO4,aq 0.28644E-14 -14.5430 0.28644E-14 -14.5430 0.10000E+01 0.0000 83 H2PO4- 0.29724E-07 -7.5269 0.26875E-07 -7.5706 0.90417E+00 -0.0438 84 PO4-3 0.31785E-07 -7.4978 0.15041E-07 -7.8227 0.47321E+00 -0.3249 87 H2P2O7-2 0.80162E-16 -16.0960 0.56634E-16 -16.2469 0.70649E+00 -0.1509 88 HP2O7-3 0.86148E-13 -13.0648 0.40226E-13 -13.3955 0.46694E+00 -0.3307 89 P2O7-4 0.12961E-12 -12.8874 0.34185E-13 -13.4662 0.26375E+00 -0.5788 90 H2S,aq 0.54717E-16 -16.2619 0.54673E-16 -16.2622 0.99920E+00 -0.0003 97 SO3-2 0.23630E-14 -14.6265 0.16761E-14 -14.7757 0.70931E+00 -0.1492 98 HSO3- 0.32637E-16 -16.4863 0.29501E-16 -16.5302 0.90393E+00 -0.0439 99 HSO4- 0.54004E-11 -11.2676 0.48854E-11 -11.3111 0.90464E+00 -0.0435 Charge balance for all species = 0.8957E-13 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.3104794E-09 -.4362318E-02 -.4395457E+01 0.0000 2 H2O 0.1000000E+01 0.5550877E+02 0.9996665E+06 0.0000 3 Cl- 0.1379043E-03 0.1380639E-03 0.4893112E+01 5.6468 4 SO4-- 0.2550963E-04 0.2552167E-04 0.2450817E+01 14.3583 5 HCO3- 0.9353324E-05 0.1307850E-04 0.7977416E+00 4.4784 6 HS- 0.6961267E-13 -.6140925E-09 -.2030235E-04 -3.6500 7 Al+++ 0.1070551E-25 0.5312722E-04 0.1432964E+01 2.3521 8 H4SiO4 0.4804876E-03 0.2345757E-02 0.2253866E+03 -3.3183 9 Ca++ 0.1125127E-07 0.1410604E-07 0.5651491E-03 11.0019 10 Mg++ 0.4997976E-10 0.1066727E-09 0.2592544E-05 8.6490 11 Fe++ 0.2947988E-12 0.1068156E-07 0.5963296E-03 6.4198 12 K+ 0.4063317E-04 0.4070045E-04 0.1590927E+01 5.1163 13 Na+ 0.4273386E-02 0.4379154E-02 0.1006416E+03 7.1380 14 Mn++ 0.3960564E-10 0.7484320E-09 0.4110335E-04 8.5482 15 HPO4-- 0.7330800E-05 0.7392308E-05 0.7092647E+00 13.8167 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.5958106E-01 -.4359483E-02 -.5522157E-01 0.0000000E+00 2 H2O 0.5546314E+02 0.5547269E+02 -.9558765E-02 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.1252450E-03 0.2550508E-04 0.9973994E-04 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.9974056E-04 -.6136934E-09 -.9973994E-04 0.0000000E+00 7 Al+++ 0.1173541E-01 0.5309269E-04 0.1168232E-01 0.0000000E+00 8 H4SiO4 0.3747561E-01 0.2344233E-02 0.3513137E-01 0.0000000E+00 9 Ca++ 0.4153834E-02 0.1409687E-07 0.4153820E-02 0.0000000E+00 10 Mg++ 0.2856349E-02 0.1066034E-09 0.2856349E-02 0.0000000E+00 11 Fe++ 0.2566118E-02 0.1067461E-07 0.2566107E-02 0.0000000E+00 12 K+ 0.7641189E-03 0.4067399E-04 0.7234449E-03 0.0000000E+00 13 Na+ 0.4677693E-02 0.4376308E-02 0.3013849E-03 0.0000000E+00 14 Mn++ 0.6240161E-04 0.7479455E-09 0.6240086E-04 0.0000000E+00 15 HPO4-- 0.2129736E-04 0.7387504E-05 0.1390985E-04 0.0000000E+00 Chg. balance for solid moles: 0.4682E-17 Mass of aqueous solution: 0.999691E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 3.5990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) apatite-OH 0.4637E-05 -5.334 0.2329E-02 -2.633 0.5988E-01 0.7401E-03 clinochlore 0.5713E-03 -3.243 0.3175 -0.498 8.164 0.1208 daphnite 0.3536E-03 -3.451 0.2523 -0.598 6.487 0.7646E-01 chlorite-Mn 0.1248E-04 -4.904 0.8848E-02 -2.053 0.2275 0.2820E-02 hematite 0.2757E-03 -3.560 0.4403E-01 -1.356 1.132 0.8346E-02 microcline 0.7234E-03 -3.141 0.2014 -0.696 5.177 0.7866E-01 paragonite 0.2607E-03 -3.584 0.9965E-01 -1.002 2.562 0.3444E-01 stilbite 0.4131E-02 -2.384 2.911 0.464 74.84 1.358 nontronite-Na 0.1232E-03 -3.909 0.5241E-01 -1.281 1.347 0.1628E-01 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.6094E+00 0.6094E+00 1.0000 -0.215 daphnite 0.3773E+00 0.3773E+00 1.0000 -0.423 chlorite-Mn 0.1331E-01 0.1331E-01 1.0000 -1.876 hematite 0.1000E+01 0.1000E+01 1.0000 0.000 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 paragonite 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 nontronite-Na 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 3.889422 g Volume = 1.696245 cm3 Porosity: 30.4704% V(tot) - V(min): 0.74336E+00 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 3.5990000 g log = 0.5562 Original solution: 1000.0103000 g Original solution / Rock added: 277.86 (Water/Rock Ratio), log = 2.4438 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0203 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.1000E+01 0.9860 0.1006E+01 0.1020E+01 CO2,gas 0.5290E-06 1.0071 0.5436E-06 0.5397E-06 CH4,gas 0.4085E-16 1.0125 0.4220E-16 0.4168E-16 H2,gas 0.9199E-06 1.0005 0.9390E-06 0.9385E-06 H2S,gas 0.1479E-14 0.9960 0.1503E-14 0.1509E-14 S2,gas 0.9424E-37 1.0000 0.9615E-37 0.9615E-37 CO,gas 0.1333E-15 1.0000 0.1360E-15 0.1360E-15 SO3,gas 0.5281E-39 1.0000 0.5388E-39 0.5388E-39 SO2,gas 0.1929E-22 1.0000 0.1969E-22 0.1969E-22 HCl,gas 0.1111E-16 1.0000 0.1133E-16 0.1133E-16 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 32 apatite-OH -18.15 -18.15 0.00 0.000 0.60662E-11 46 clinochlore 39.07 39.07 0.00 0.000 0.12132E-10 47 daphnite 28.97 28.97 0.00 0.000 0.24265E-10 48 chlorite-Mn 46.87 46.87 0.00 0.000 0.36397E-10 90 hematite 12.57 12.57 0.00 0.000 -0.30331E-11 116 microcline -2.49 -2.49 0.00 0.000 0.15165E-11 121 paragonite 4.24 4.24 0.00 0.000 0.13649E-10 163 stilbite -7.52 -7.52 0.00 0.000 0.15165E-10 209 nontronite-Na 3.52 3.52 0.00 0.000 0.98575E-11 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -14.62 -7.96 -2.655 0.13598E+05 -6.265 3 CH4,gas 4.54 -13.53 -18.07 -4.518 0.30860E+05 -16.375 4 H2,gas 8.00 0.27 -7.73 -4.415 0.13192E+05 -6.027 5 H2S,gas -6.23 -22.75 -16.52 -8.261 0.28211E+05 -14.823 6 S2,gas -7.34 -46.05 -38.72 -5.956 0.66107E+05 -37.017 7 CO,gas 3.21 -14.35 -17.57 -5.405 0.29992E+05 -15.866 8 SO3,gas 17.12 -23.85 -40.97 -10.242 0.69951E+05 -39.269 9 SO2,gas 0.83 -23.57 -24.40 -6.508 0.41671E+05 -22.706 10 HCl,gas 5.19 -13.46 -18.64 -9.322 0.31835E+05 -16.946 11 acmite 7.71 6.78 -0.93 -0.096 0.15798E+04 15 albite-high 0.69 -0.46 -1.16 -0.089 0.19770E+04 16 albite -0.38 -0.46 -0.08 -0.006 0.13823E+03 19 spessartine 24.46 20.39 -4.06 -0.203 0.69384E+04 20 analcite 3.32 2.85 -0.47 -0.052 0.79972E+03 21 andalusite 5.00 1.39 -3.62 -0.362 0.61735E+04 22 andradite 39.01 35.62 -3.39 -0.176 0.57914E+04 23 grossular 32.73 27.76 -4.98 -0.249 0.84970E+04 26 annite 20.12 16.77 -3.35 -0.186 0.57207E+04 27 phlogopite 27.06 23.46 -3.60 -0.200 0.61541E+04 29 anorthite 12.71 9.07 -3.64 -0.280 0.62165E+04 35 aragonite 0.97 -3.62 -4.59 -1.529 0.78346E+04 36 brucite 12.57 8.65 -3.92 -0.784 0.66926E+04 37 calcite 0.81 -3.62 -4.43 -1.478 0.75704E+04 38 carnegieite-low 9.02 6.17 -2.85 -0.407 0.48688E+04 39 carnegieite-high 10.09 6.17 -3.92 -0.560 0.66958E+04 40 carpholite-Mg 8.58 6.72 -1.87 -0.124 0.31853E+04 41 carpholite-Fe 6.71 4.49 -2.23 -0.148 0.37995E+04 42 celadonite 5.34 2.84 -2.50 -0.147 0.42643E+04 43 celadonite-Fe 3.88 0.62 -3.26 -0.192 0.55689E+04 44 chrysotile 23.89 19.31 -4.58 -0.382 0.78239E+04 50 chloritoid-Mg 13.20 10.03 -3.16 -0.211 0.54004E+04 51 chloritoid-Fe 9.17 7.81 -1.37 -0.091 0.23356E+04 52 chloritoid-Mn 11.40 9.93 -1.47 -0.098 0.25048E+04 54 coesite -2.38 -3.32 -0.94 -0.314 0.16089E+04 59 corundum 8.38 4.70 -3.68 -0.334 0.62816E+04 61 cristobalite -2.56 -3.32 -0.76 -0.253 0.12942E+04 63 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71234E+04 65 diaspore 2.87 2.35 -0.52 -0.087 0.89057E+03 67 diopside 16.18 13.01 -3.17 -0.317 0.54078E+04 68 hedenbergite 14.21 10.79 -3.42 -0.342 0.58450E+04 75 epidote 24.67 23.04 -1.63 -0.079 0.27895E+04 76 clinozoisite 22.81 19.11 -3.70 -0.168 0.63190E+04 77 epidote-Fe 29.84 26.97 -2.87 -0.149 0.49066E+04 78 fayalite 14.05 9.52 -4.52 -0.646 0.77253E+04 79 ferrosilite 11.15 6.20 -4.95 -0.495 0.84459E+04 83 gibbsite 4.08 2.35 -1.73 -0.247 0.29491E+04 84 glaucophane 22.97 18.38 -4.59 -0.124 0.78445E+04 87 greenalite 16.14 12.62 -3.52 -0.293 0.60046E+04 91 heulandite -5.83 -7.52 -1.69 -0.077 0.28938E+04 95 jadeite 4.22 2.85 -1.36 -0.136 0.23252E+04 97 kalsilite 7.58 4.15 -3.43 -0.491 0.58631E+04 98 kaolinite -1.33 -1.93 -0.60 -0.055 0.10238E+04 99 kyanite 4.88 1.39 -3.49 -0.349 0.59594E+04 101 laumontite 2.88 2.43 -0.45 -0.030 0.76923E+03 102 lawsonite 9.62 9.07 -0.55 -0.036 0.93319E+03 103 leucite 4.12 0.83 -3.29 -0.329 0.56125E+04 105 lizardite 23.24 19.31 -3.93 -0.328 0.67165E+04 107 magnetite 20.09 18.99 -1.10 -0.090 0.18806E+04 108 minnesotaite 10.39 5.99 -4.40 -0.259 0.75161E+04 110 magnesioferrite 26.21 21.22 -5.00 -0.408 0.85327E+04 113 margarite 17.32 13.77 -3.55 -0.142 0.60612E+04 120 muscovite 2.58 2.22 -0.36 -0.021 0.62266E+03 122 nepheline 8.34 6.17 -2.17 -0.310 0.37012E+04 134 phlogopite-Na 29.65 25.48 -4.16 -0.231 0.71111E+04 136 prehnite 19.37 16.75 -2.62 -0.154 0.44714E+04 137 prehnite-Fe 22.50 20.68 -1.81 -0.109 0.30970E+04 138 pumpellyite-Fe 46.27 42.28 -3.99 -0.089 0.68149E+04 139 pumpellyite-Mg 48.99 44.51 -4.49 -0.100 0.76623E+04 145 pyroxmangite 7.40 5.23 -2.17 -0.434 0.37032E+04 146 pyrophyllite -6.18 -8.57 -2.39 -0.150 0.40864E+04 147 quartz -2.99 -3.32 -0.33 -0.110 0.56156E+03 152 rhodonite 7.45 5.23 -2.22 -0.443 0.37835E+04 153 sanidine -1.28 -2.49 -1.21 -0.093 0.20677E+04 156 sillimanite 5.26 1.39 -3.88 -0.388 0.66175E+04 164 stilpnomelane-Fe 13.02 12.82 -0.20 -0.006 0.34483E+03 165 stilpnomelane-Mg 27.44 23.96 -3.48 -0.104 0.59432E+04 168 sudoite 21.08 16.75 -4.33 -0.140 0.73863E+04 171 talc 16.49 12.67 -3.82 -0.225 0.65182E+04 174 tephroite 18.09 13.78 -4.31 -0.615 0.73554E+04 177 topaz-H 4.62 1.39 -3.23 -0.294 0.55195E+04 178 tridymite -2.63 -3.32 -0.69 -0.231 0.11815E+04 187 wairakite 3.95 2.43 -1.52 -0.089 0.25912E+04 188 walstromite 11.51 7.68 -3.83 -0.765 0.65322E+04 189 wollastonite 10.46 7.68 -2.78 -0.556 0.47426E+04 190 pseudo-wollastonite 11.00 7.68 -3.32 -0.663 0.56624E+04 191 zoisite 22.85 19.11 -3.74 -0.170 0.63930E+04 192 akaganeite 7.75 6.28 -1.47 -0.318 0.25125E+04 193 beidellite-Ca -1.65 -4.88 -3.24 -0.200 0.55268E+04 194 beidellite-H -2.33 -6.70 -4.37 -0.279 0.74643E+04 195 beidellite-K -1.52 -5.01 -3.49 -0.214 0.59576E+04 196 beidellite-Mg -1.79 -5.27 -3.48 -0.215 0.59436E+04 197 beidellite-Na -1.34 -4.34 -3.00 -0.184 0.51224E+04 199 chalcedony -2.80 -3.32 -0.52 -0.172 0.88086E+03 201 montmorillonite-Ca -2.29 -4.68 -2.39 -0.148 0.40724E+04 202 montmorillonite-K -2.24 -4.80 -2.57 -0.157 0.43813E+04 203 montmorillonite-Mg -2.48 -5.06 -2.58 -0.160 0.44123E+04 204 montmorillonite-Na -2.04 -4.14 -2.10 -0.128 0.35818E+04 205 nontronite-Ca 3.21 2.98 -0.24 -0.015 0.40137E+03 206 nontronite-H 2.53 1.16 -1.37 -0.092 0.23367E+04 207 nontronite-K 3.34 2.85 -0.49 -0.031 0.83350E+03 208 nontronite-Mg 3.07 2.59 -0.48 -0.031 0.82536E+03 224 tobermorite 9.82 5.85 -3.98 -1.085 0.67902E+04 233 boehmite 4.41 2.35 -2.05 -0.342 0.35075E+04 235 ferrous-oxide 9.81 6.42 -3.39 -0.848 0.57913E+04 240 silica-amorphous -2.09 -3.32 -1.23 -0.409 0.20950E+04 242 an20ab80 2.02 1.44 -0.58 -0.044 0.98304E+03 243 an25ab75 2.65 1.92 -0.73 -0.056 0.12412E+04 244 an30ab70 3.28 2.40 -0.88 -0.068 0.15090E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 0.1000000 g Current total amount of reactant added: 3.5990000 g New total amount of reactant added: 3.6990000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.8095E-13 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 6 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 3.6990000 Water: Moles liquid = 0.5547E+02 kg liquid = 0.9993E+00 Moles total = 0.5546E+02 kg total = 0.9992E+00 Activity = 1.0000 Stoichiometric ionic strength = .2651177E-02 Osmotic coef. = 0.9714 True ionic strength = .4460696E-02 Chg. balance for total moles = 0.8095E-13 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.30239E-09 -9.5194 0.27355E-09 -9.5630 0.90460E+00 -0.0435 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13790E-03 -3.8604 0.12454E-03 -3.9047 0.90307E+00 -0.0443 4 SO4-- 0.25510E-04 -4.5933 0.17966E-04 -4.7456 0.70427E+00 -0.1523 5 HCO3- 0.92729E-05 -5.0328 0.83775E-05 -5.0769 0.90344E+00 -0.0441 6 HS- 0.71779E-13 -13.1440 0.64825E-13 -13.1883 0.90311E+00 -0.0443 7 Al+++ 0.98108E-26 -26.0083 0.45415E-26 -26.3428 0.46291E+00 -0.3345 8 H4SiO4 0.47885E-03 -3.3198 0.47885E-03 -3.3198 0.10000E+01 0.0000 9 Ca++ 0.11260E-07 -7.9485 0.79139E-08 -8.1016 0.70283E+00 -0.1531 10 Mg++ 0.47866E-10 -10.3200 0.33599E-10 -10.4737 0.70193E+00 -0.1537 11 Fe++ 0.28233E-12 -12.5492 0.19824E-12 -12.7028 0.70214E+00 -0.1536 12 K+ 0.40541E-04 -4.3921 0.36629E-04 -4.4362 0.90350E+00 -0.0441 13 Na+ 0.43836E-02 -2.3582 0.39585E-02 -2.4025 0.90303E+00 -0.0443 14 Mn++ 0.37930E-10 -10.4210 0.26639E-10 -10.5745 0.70231E+00 -0.1535 15 HPO4-- 0.71308E-05 -5.1469 0.50222E-05 -5.2991 0.70429E+00 -0.1522 16 HSiO3- 0.18100E-02 -2.7423 0.16345E-02 -2.7866 0.90307E+00 -0.0443 17 Ca(HSiO3)+ 0.32604E-09 -9.4867 0.29459E-09 -9.5308 0.90356E+00 -0.0440 18 Mg(HSiO3)+ 0.17226E-11 -11.7638 0.15565E-11 -11.8078 0.90356E+00 -0.0440 19 NaHSiO3,aq 0.10465E-03 -3.9803 0.10465E-03 -3.9803 0.10000E+01 0.0000 20 AlO+ 0.91382E-14 -14.0391 0.82569E-14 -14.0832 0.90356E+00 -0.0440 21 AlOH+2 0.16009E-19 -19.7956 0.11247E-19 -19.9490 0.70250E+00 -0.1534 22 HAlO2,aq 0.60112E-08 -8.2210 0.60112E-08 -8.2210 0.10000E+01 0.0000 23 AlO2- 0.53892E-04 -4.2685 0.48644E-04 -4.3130 0.90261E+00 -0.0445 24 CH4,aq 0.29387E-19 -19.5318 0.29363E-19 -19.5322 0.99918E+00 -0.0004 29 CO,aq 0.89328E-19 -19.0490 0.89328E-19 -19.0490 0.10000E+01 0.0000 30 CO2,aq 0.49007E-08 -8.3097 0.48967E-08 -8.3101 0.99918E+00 -0.0004 31 CO3-2 0.38006E-05 -5.4201 0.26750E-05 -5.5727 0.70384E+00 -0.1525 32 CaCO3,aq 0.26545E-09 -9.5760 0.26545E-09 -9.5760 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.18730E-11 -11.7275 0.16923E-11 -11.7715 0.90356E+00 -0.0440 34 CaCl+ 0.17652E-11 -11.7532 0.15950E-11 -11.7973 0.90356E+00 -0.0440 35 CaCl2,aq 0.47190E-16 -16.3262 0.47190E-16 -16.3262 0.10000E+01 0.0000 36 CaOH+ 0.22820E-08 -8.6417 0.20619E-08 -8.6857 0.90356E+00 -0.0440 37 CaSO4,aq 0.45149E-10 -10.3454 0.45149E-10 -10.3454 0.10000E+01 0.0000 38 HCl,aq 0.62425E-14 -14.2046 0.62425E-14 -14.2046 0.10000E+01 0.0000 43 FeCl+ 0.43247E-16 -16.3640 0.39076E-16 -16.4081 0.90356E+00 -0.0440 46 FeO,aq 0.10296E-09 -9.9873 0.10296E-09 -9.9873 0.10000E+01 0.0000 47 FeOH+ 0.26107E-10 -10.5832 0.23589E-10 -10.6273 0.90356E+00 -0.0440 48 HFeO2- 0.43611E-08 -8.3604 0.39384E-08 -8.4047 0.90307E+00 -0.0443 49 FeO+ 0.23108E-14 -14.6362 0.20879E-14 -14.6803 0.90356E+00 -0.0440 51 FeO2- 0.63225E-08 -8.1991 0.57096E-08 -8.2434 0.90307E+00 -0.0443 52 HFeO2,aq 0.19864E-09 -9.7019 0.19864E-09 -9.7019 0.10000E+01 0.0000 53 H2,aq 0.72678E-09 -9.1386 0.72619E-09 -9.1390 0.99918E+00 -0.0004 54 KCl,aq 0.82676E-10 -10.0826 0.82676E-10 -10.0826 0.10000E+01 0.0000 55 KHSO4,aq 0.50897E-18 -18.2933 0.50897E-18 -18.2933 0.10000E+01 0.0000 56 KOH,aq 0.57185E-07 -7.2427 0.57185E-07 -7.2427 0.10000E+01 0.0000 57 KSO4- 0.11308E-07 -7.9466 0.10212E-07 -7.9909 0.90307E+00 -0.0443 58 MgCO3,aq 0.28248E-12 -12.5490 0.28248E-12 -12.5490 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.81253E-14 -14.0902 0.73416E-14 -14.1342 0.90356E+00 -0.0440 60 MgCl+ 0.67923E-14 -14.1680 0.61372E-14 -14.2120 0.90356E+00 -0.0440 61 MgOH+ 0.53609E-10 -10.2708 0.48439E-10 -10.3148 0.90356E+00 -0.0440 63 MnO,aq 0.36868E-09 -9.4334 0.36868E-09 -9.4334 0.10000E+01 0.0000 64 MnOH+ 0.32591E-09 -9.4869 0.29448E-09 -9.5310 0.90356E+00 -0.0440 65 MnO2-2 0.23232E-12 -12.6339 0.16351E-12 -12.7864 0.70384E+00 -0.1525 66 HMnO2- 0.10851E-10 -10.9645 0.97993E-11 -11.0088 0.90307E+00 -0.0443 69 MnCl+ 0.22609E-13 -13.6457 0.20429E-13 -13.6898 0.90356E+00 -0.0440 70 MnSO4,aq 0.13816E-12 -12.8596 0.13816E-12 -12.8596 0.10000E+01 0.0000 71 NaCl,aq 0.16337E-06 -6.7868 0.16337E-06 -6.7868 0.10000E+01 0.0000 72 NaOH,aq 0.62175E-05 -5.2064 0.62175E-05 -5.2064 0.10000E+01 0.0000 74 OH- 0.23401E-02 -2.6308 0.21122E-02 -2.6753 0.90261E+00 -0.0445 79 HPO3-2 0.16148E-16 -16.7919 0.11365E-16 -16.9444 0.70384E+00 -0.1525 82 H3PO4,aq 0.26283E-14 -14.5803 0.26283E-14 -14.5803 0.10000E+01 0.0000 83 H2PO4- 0.28056E-07 -7.5520 0.25343E-07 -7.5961 0.90331E+00 -0.0442 84 PO4-3 0.31915E-07 -7.4960 0.14979E-07 -7.8245 0.46935E+00 -0.3285 87 H2P2O7-2 0.71550E-16 -16.1454 0.50360E-16 -16.2979 0.70384E+00 -0.1525 88 HP2O7-3 0.79398E-13 -13.1002 0.36761E-13 -13.4346 0.46299E+00 -0.3344 89 P2O7-4 0.12356E-12 -12.9081 0.32104E-13 -13.4934 0.25984E+00 -0.5853 90 H2S,aq 0.54849E-16 -16.2608 0.54804E-16 -16.2612 0.99918E+00 -0.0004 97 SO3-2 0.23990E-14 -14.6200 0.16954E-14 -14.7707 0.70671E+00 -0.1508 98 HSO3- 0.32154E-16 -16.4928 0.29038E-16 -16.5370 0.90307E+00 -0.0443 99 HSO4- 0.52403E-11 -11.2806 0.47362E-11 -11.3246 0.90380E+00 -0.0439 Charge balance for all species = 0.8952E-13 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.3023931E-09 -.4480397E-02 -.4514399E+01 0.0000 2 H2O 0.1000000E+01 0.5550879E+02 0.9996594E+06 0.0000 3 Cl- 0.1379029E-03 0.1380663E-03 0.4893162E+01 5.6583 4 SO4-- 0.2551015E-04 0.2552214E-04 0.2450844E+01 14.3804 5 HCO3- 0.9272950E-05 0.1307873E-04 0.7977496E+00 4.4861 6 HS- 0.7177946E-13 -.6333713E-09 -.2093956E-04 -3.6253 7 Al+++ 0.9810750E-26 0.5389838E-04 0.1453753E+01 2.3461 8 H4SiO4 0.4788507E-03 0.2393484E-02 0.2299706E+03 -3.3198 9 Ca++ 0.1126001E-07 0.1418224E-07 0.5681978E-03 11.0243 10 Mg++ 0.4786620E-10 0.1034954E-09 0.2515304E-05 8.6523 11 Fe++ 0.2823304E-12 0.1101158E-07 0.6147498E-03 6.4231 12 K+ 0.4054114E-04 0.4060971E-04 0.1587368E+01 5.1268 13 Na+ 0.4383580E-02 0.4494611E-02 0.1032942E+03 7.1605 14 Mn++ 0.3793035E-10 0.7437573E-09 0.4084631E-04 8.5515 15 HPO4-- 0.7130848E-05 0.7190820E-05 0.6899274E+00 13.8268 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.6123691E-01 -.4477407E-02 -.5675950E-01 0.0000000E+00 2 H2O 0.5546188E+02 0.5547174E+02 -.9859426E-02 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.1280164E-03 0.2550510E-04 0.1025113E-03 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.1025119E-03 -.6329486E-09 -.1025113E-03 0.0000000E+00 7 Al+++ 0.1206148E-01 0.5386240E-04 0.1200762E-01 0.0000000E+00 8 H4SiO4 0.3851688E-01 0.2391887E-02 0.3612500E-01 0.0000000E+00 9 Ca++ 0.4268849E-02 0.1417277E-07 0.4268835E-02 0.0000000E+00 10 Mg++ 0.2935714E-02 0.1034263E-09 0.2935714E-02 0.0000000E+00 11 Fe++ 0.2637419E-02 0.1100423E-07 0.2637408E-02 0.0000000E+00 12 K+ 0.7853503E-03 0.4058261E-04 0.7447677E-03 0.0000000E+00 13 Na+ 0.4803217E-02 0.4491611E-02 0.3116064E-03 0.0000000E+00 14 Mn++ 0.6413547E-04 0.7432609E-09 0.6413472E-04 0.0000000E+00 15 HPO4-- 0.2188912E-04 0.7186020E-05 0.1470310E-04 0.0000000E+00 Chg. balance for solid moles: 0.8809E-19 Mass of aqueous solution: 0.999681E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 3.6990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) apatite-OH 0.4901E-05 -5.310 0.2462E-02 -2.609 0.6157E-01 0.7823E-03 clinochlore 0.5871E-03 -3.231 0.3264 -0.486 8.162 0.1241 daphnite 0.3635E-03 -3.440 0.2593 -0.586 6.486 0.7859E-01 chlorite-Mn 0.1283E-04 -4.892 0.9094E-02 -2.041 0.2274 0.2898E-02 hematite 0.2775E-03 -3.557 0.4431E-01 -1.353 1.108 0.8399E-02 microcline 0.7448E-03 -3.128 0.2073 -0.683 5.184 0.8098E-01 paragonite 0.2679E-03 -3.572 0.1024 -0.990 2.560 0.3539E-01 stilbite 0.4244E-02 -2.372 2.991 0.476 74.80 1.395 nontronite-Na 0.1326E-03 -3.878 0.5637E-01 -1.249 1.410 0.1751E-01 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.6094E+00 0.6094E+00 1.0000 -0.215 daphnite 0.3773E+00 0.3773E+00 1.0000 -0.423 chlorite-Mn 0.1331E-01 0.1331E-01 1.0000 -1.876 hematite 0.1000E+01 0.1000E+01 1.0000 0.000 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 paragonite 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 nontronite-Na 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 3.998669 g Volume = 1.743763 cm3 Porosity: 29.6756% V(tot) - V(min): 0.73584E+00 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 3.6990000 g log = 0.5681 Original solution: 1000.0103000 g Original solution / Rock added: 270.35 (Water/Rock Ratio), log = 2.4319 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0203 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.1000E+01 0.9860 0.1006E+01 0.1020E+01 CO2,gas 0.5099E-06 1.0071 0.5239E-06 0.5202E-06 CH4,gas 0.4184E-16 1.0125 0.4322E-16 0.4269E-16 H2,gas 0.9339E-06 1.0005 0.9534E-06 0.9529E-06 H2S,gas 0.1482E-14 0.9960 0.1507E-14 0.1513E-14 S2,gas 0.9186E-37 1.0000 0.9373E-37 0.9373E-37 CO,gas 0.1305E-15 1.0000 0.1331E-15 0.1331E-15 SO3,gas 0.4982E-39 1.0000 0.5083E-39 0.5083E-39 SO2,gas 0.1848E-22 1.0000 0.1885E-22 0.1885E-22 HCl,gas 0.1080E-16 1.0000 0.1102E-16 0.1102E-16 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 32 apatite-OH -18.15 -18.15 0.00 0.000 0.00000E+00 46 clinochlore 39.07 39.07 0.00 0.000 0.00000E+00 47 daphnite 28.97 28.97 0.00 0.000 -0.60662E-11 48 chlorite-Mn 46.87 46.87 0.00 0.000 -0.36397E-10 90 hematite 12.57 12.57 0.00 0.000 0.30331E-11 116 microcline -2.49 -2.49 0.00 0.000 0.15165E-11 121 paragonite 4.24 4.24 0.00 0.000 -0.10616E-10 163 stilbite -7.52 -7.52 0.00 0.000 -0.90992E-11 209 nontronite-Na 3.52 3.52 0.00 0.000 0.27298E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -14.64 -7.98 -2.660 0.13625E+05 -6.281 3 CH4,gas 4.54 -13.52 -18.06 -4.516 0.30843E+05 -16.364 4 H2,gas 8.00 0.28 -7.72 -4.411 0.13181E+05 -6.021 5 H2S,gas -6.23 -22.75 -16.52 -8.260 0.28209E+05 -14.822 6 S2,gas -7.34 -46.06 -38.73 -5.958 0.66125E+05 -37.028 7 CO,gas 3.21 -14.36 -17.57 -5.408 0.30008E+05 -15.876 8 SO3,gas 17.12 -23.87 -40.99 -10.248 0.69994E+05 -39.294 9 SO2,gas 0.83 -23.59 -24.42 -6.513 0.41703E+05 -22.725 10 HCl,gas 5.19 -13.47 -18.66 -9.328 0.31856E+05 -16.958 11 acmite 7.71 6.80 -0.91 -0.094 0.15465E+04 15 albite-high 0.69 -0.45 -1.15 -0.088 0.19565E+04 16 albite -0.38 -0.45 -0.07 -0.005 0.11768E+03 19 spessartine 24.46 20.39 -4.07 -0.204 0.69497E+04 20 analcite 3.32 2.87 -0.45 -0.051 0.77664E+03 21 andalusite 5.00 1.37 -3.63 -0.363 0.61966E+04 22 andradite 39.01 35.68 -3.33 -0.173 0.56841E+04 23 grossular 32.73 27.81 -4.93 -0.246 0.84104E+04 26 annite 20.12 16.78 -3.34 -0.186 0.57038E+04 27 phlogopite 27.06 23.47 -3.59 -0.200 0.61372E+04 29 anorthite 12.71 9.08 -3.63 -0.279 0.62039E+04 35 aragonite 0.97 -3.62 -4.58 -1.527 0.78237E+04 36 brucite 12.57 8.65 -3.92 -0.783 0.66870E+04 37 calcite 0.81 -3.62 -4.43 -1.476 0.75595E+04 38 carnegieite-low 9.02 6.19 -2.84 -0.405 0.48432E+04 39 carnegieite-high 10.09 6.19 -3.91 -0.558 0.66702E+04 40 carpholite-Mg 8.58 6.70 -1.88 -0.125 0.32053E+04 41 carpholite-Fe 6.71 4.48 -2.24 -0.149 0.38194E+04 42 celadonite 5.34 2.85 -2.50 -0.147 0.42612E+04 43 celadonite-Fe 3.88 0.62 -3.26 -0.192 0.55658E+04 44 chrysotile 23.89 19.32 -4.58 -0.381 0.78120E+04 50 chloritoid-Mg 13.20 10.02 -3.17 -0.212 0.54178E+04 51 chloritoid-Fe 9.17 7.80 -1.38 -0.092 0.23530E+04 52 chloritoid-Mn 11.40 9.92 -1.48 -0.098 0.25223E+04 54 coesite -2.38 -3.32 -0.94 -0.315 0.16114E+04 59 corundum 8.38 4.69 -3.69 -0.336 0.63021E+04 61 cristobalite -2.56 -3.32 -0.76 -0.253 0.12968E+04 63 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71234E+04 65 diaspore 2.87 2.35 -0.53 -0.088 0.90084E+03 67 diopside 16.18 13.04 -3.14 -0.314 0.53689E+04 68 hedenbergite 14.21 10.81 -3.40 -0.340 0.58061E+04 75 epidote 24.67 23.06 -1.61 -0.078 0.27411E+04 76 clinozoisite 22.81 19.13 -3.68 -0.167 0.62808E+04 77 epidote-Fe 29.84 27.00 -2.84 -0.147 0.48479E+04 78 fayalite 14.05 9.53 -4.52 -0.646 0.77166E+04 79 ferrosilite 11.15 6.21 -4.94 -0.494 0.84397E+04 83 gibbsite 4.08 2.35 -1.73 -0.248 0.29594E+04 84 glaucophane 22.97 18.41 -4.56 -0.123 0.77915E+04 87 greenalite 16.14 12.63 -3.51 -0.292 0.59928E+04 91 heulandite -5.83 -7.52 -1.69 -0.077 0.28938E+04 95 jadeite 4.22 2.87 -1.35 -0.135 0.23021E+04 97 kalsilite 7.58 4.15 -3.43 -0.490 0.58580E+04 98 kaolinite -1.33 -1.95 -0.61 -0.056 0.10494E+04 99 kyanite 4.88 1.37 -3.50 -0.350 0.59825E+04 101 laumontite 2.88 2.44 -0.45 -0.030 0.76164E+03 102 lawsonite 9.62 9.08 -0.54 -0.036 0.92054E+03 103 leucite 4.12 0.83 -3.29 -0.329 0.56100E+04 105 lizardite 23.24 19.32 -3.93 -0.327 0.67047E+04 107 magnetite 20.09 18.99 -1.10 -0.090 0.18750E+04 108 minnesotaite 10.39 5.99 -4.40 -0.259 0.75094E+04 110 magnesioferrite 26.21 21.22 -4.99 -0.408 0.85270E+04 113 margarite 17.32 13.77 -3.55 -0.142 0.60691E+04 120 muscovite 2.58 2.21 -0.38 -0.022 0.64322E+03 122 nepheline 8.34 6.19 -2.15 -0.308 0.36756E+04 134 phlogopite-Na 29.65 25.50 -4.14 -0.230 0.70737E+04 136 prehnite 19.37 16.78 -2.59 -0.152 0.44230E+04 137 prehnite-Fe 22.50 20.72 -1.78 -0.107 0.30383E+04 138 pumpellyite-Fe 46.27 42.33 -3.94 -0.087 0.67227E+04 139 pumpellyite-Mg 48.99 44.56 -4.43 -0.099 0.75702E+04 145 pyroxmangite 7.40 5.23 -2.17 -0.433 0.37001E+04 146 pyrophyllite -6.18 -8.59 -2.41 -0.151 0.41170E+04 147 quartz -2.99 -3.32 -0.33 -0.110 0.56409E+03 152 rhodonite 7.45 5.23 -2.21 -0.443 0.37804E+04 153 sanidine -1.28 -2.49 -1.21 -0.093 0.20677E+04 156 sillimanite 5.26 1.37 -3.89 -0.389 0.66405E+04 164 stilpnomelane-Fe 13.02 12.81 -0.20 -0.006 0.34855E+03 165 stilpnomelane-Mg 27.44 23.96 -3.48 -0.104 0.59469E+04 168 sudoite 21.08 16.73 -4.35 -0.140 0.74237E+04 171 talc 16.49 12.68 -3.81 -0.224 0.65114E+04 174 tephroite 18.09 13.78 -4.30 -0.615 0.73467E+04 177 topaz-H 4.62 1.37 -3.25 -0.295 0.55426E+04 178 tridymite -2.63 -3.32 -0.69 -0.231 0.11841E+04 187 wairakite 3.95 2.44 -1.51 -0.089 0.25836E+04 188 walstromite 11.51 7.70 -3.80 -0.761 0.64964E+04 189 wollastonite 10.46 7.70 -2.76 -0.551 0.47069E+04 190 pseudo-wollastonite 11.00 7.70 -3.30 -0.659 0.56267E+04 191 zoisite 22.85 19.13 -3.72 -0.169 0.63549E+04 192 akaganeite 7.75 6.28 -1.47 -0.318 0.25125E+04 193 beidellite-Ca -1.65 -4.90 -3.25 -0.201 0.55537E+04 194 beidellite-H -2.33 -6.72 -4.39 -0.280 0.74975E+04 195 beidellite-K -1.52 -5.03 -3.51 -0.215 0.59850E+04 196 beidellite-Mg -1.79 -5.29 -3.50 -0.217 0.59759E+04 197 beidellite-Na -1.34 -4.35 -3.01 -0.184 0.51430E+04 199 chalcedony -2.80 -3.32 -0.52 -0.172 0.88339E+03 201 montmorillonite-Ca -2.29 -4.69 -2.40 -0.148 0.40915E+04 202 montmorillonite-K -2.24 -4.81 -2.58 -0.158 0.44008E+04 203 montmorillonite-Mg -2.48 -5.08 -2.60 -0.161 0.44368E+04 204 montmorillonite-Na -2.04 -4.14 -2.11 -0.129 0.35945E+04 205 nontronite-Ca 3.21 2.98 -0.24 -0.015 0.40773E+03 206 nontronite-H 2.53 1.16 -1.38 -0.092 0.23494E+04 207 nontronite-K 3.34 2.85 -0.49 -0.032 0.84029E+03 208 nontronite-Mg 3.07 2.58 -0.49 -0.032 0.83711E+03 224 tobermorite 9.82 5.86 -3.96 -1.080 0.67609E+04 233 boehmite 4.41 2.35 -2.06 -0.343 0.35178E+04 235 ferrous-oxide 9.81 6.42 -3.39 -0.847 0.57857E+04 240 silica-amorphous -2.09 -3.32 -1.23 -0.409 0.20976E+04 242 an20ab80 2.02 1.45 -0.56 -0.043 0.96407E+03 243 an25ab75 2.65 1.93 -0.72 -0.055 0.12226E+04 244 an30ab70 3.28 2.41 -0.87 -0.067 0.14908E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 0.1000000 g Current total amount of reactant added: 3.6990000 g New total amount of reactant added: 3.7990000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.8094E-13 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 6 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 3.7990000 Water: Moles liquid = 0.5547E+02 kg liquid = 0.9993E+00 Moles total = 0.5546E+02 kg total = 0.9991E+00 Activity = 1.0000 Stoichiometric ionic strength = .2711916E-02 Osmotic coef. = 0.9711 True ionic strength = .4570602E-02 Chg. balance for total moles = 0.8094E-13 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.29473E-09 -9.5306 0.26638E-09 -9.5745 0.90379E+00 -0.0439 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13790E-03 -3.8604 0.12442E-03 -3.9051 0.90222E+00 -0.0447 4 SO4-- 0.25511E-04 -4.5933 0.17900E-04 -4.7471 0.70168E+00 -0.1539 5 HCO3- 0.91937E-05 -5.0365 0.82982E-05 -5.0810 0.90260E+00 -0.0445 6 HS- 0.73952E-13 -13.1311 0.66724E-13 -13.1757 0.90226E+00 -0.0447 7 Al+++ 0.90132E-26 -26.0451 0.41375E-26 -26.3833 0.45905E+00 -0.3381 8 H4SiO4 0.47726E-03 -3.3212 0.47726E-03 -3.3212 0.10000E+01 0.0000 9 Ca++ 0.11269E-07 -7.9481 0.78910E-08 -8.1029 0.70022E+00 -0.1548 10 Mg++ 0.45899E-10 -10.3382 0.32097E-10 -10.4935 0.69930E+00 -0.1553 11 Fe++ 0.27072E-12 -12.5675 0.18938E-12 -12.7227 0.69952E+00 -0.1552 12 K+ 0.40453E-04 -4.3930 0.36515E-04 -4.4375 0.90267E+00 -0.0445 13 Na+ 0.44937E-02 -2.3474 0.40541E-02 -2.3921 0.90218E+00 -0.0447 14 Mn++ 0.36371E-10 -10.4392 0.25448E-10 -10.5943 0.69968E+00 -0.1551 15 HPO4-- 0.69415E-05 -5.1585 0.48709E-05 -5.3124 0.70170E+00 -0.1538 16 HSiO3- 0.18543E-02 -2.7318 0.16730E-02 -2.7765 0.90222E+00 -0.0447 17 Ca(HSiO3)+ 0.33304E-09 -9.4775 0.30065E-09 -9.5219 0.90272E+00 -0.0444 18 Mg(HSiO3)+ 0.16859E-11 -11.7732 0.15219E-11 -11.8176 0.90272E+00 -0.0444 19 NaHSiO3,aq 0.10970E-03 -3.9598 0.10970E-03 -3.9598 0.10000E+01 0.0000 20 AlO+ 0.87876E-14 -14.0561 0.79328E-14 -14.1006 0.90272E+00 -0.0444 21 AlOH+2 0.15034E-19 -19.8229 0.10522E-19 -19.9779 0.69988E+00 -0.1550 22 HAlO2,aq 0.59307E-08 -8.2269 0.59307E-08 -8.2269 0.10000E+01 0.0000 23 AlO2- 0.54653E-04 -4.2624 0.49284E-04 -4.3073 0.90175E+00 -0.0449 24 CH4,aq 0.30072E-19 -19.5218 0.30047E-19 -19.5222 0.99916E+00 -0.0004 29 CO,aq 0.87445E-19 -19.0583 0.87445E-19 -19.0583 0.10000E+01 0.0000 30 CO2,aq 0.47272E-08 -8.3254 0.47232E-08 -8.3258 0.99916E+00 -0.0004 31 CO3-2 0.38803E-05 -5.4111 0.27210E-05 -5.5653 0.70125E+00 -0.1541 32 CaCO3,aq 0.26923E-09 -9.5699 0.26923E-09 -9.5699 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.18516E-11 -11.7325 0.16715E-11 -11.7769 0.90272E+00 -0.0444 34 CaCl+ 0.17601E-11 -11.7545 0.15888E-11 -11.7989 0.90272E+00 -0.0444 35 CaCl2,aq 0.46964E-16 -16.3282 0.46964E-16 -16.3282 0.10000E+01 0.0000 36 CaOH+ 0.23388E-08 -8.6310 0.21113E-08 -8.6755 0.90272E+00 -0.0444 37 CaSO4,aq 0.44854E-10 -10.3482 0.44854E-10 -10.3482 0.10000E+01 0.0000 38 HCl,aq 0.60731E-14 -14.2166 0.60731E-14 -14.2166 0.10000E+01 0.0000 43 FeCl+ 0.41313E-16 -16.3839 0.37294E-16 -16.4284 0.90272E+00 -0.0444 46 FeO,aq 0.10373E-09 -9.9841 0.10373E-09 -9.9841 0.10000E+01 0.0000 47 FeOH+ 0.25635E-10 -10.5912 0.23142E-10 -10.6356 0.90272E+00 -0.0444 48 HFeO2- 0.45159E-08 -8.3453 0.40744E-08 -8.3899 0.90222E+00 -0.0447 49 FeO+ 0.22523E-14 -14.6474 0.20332E-14 -14.6918 0.90272E+00 -0.0444 51 FeO2- 0.64987E-08 -8.1872 0.58633E-08 -8.2319 0.90222E+00 -0.0447 52 HFeO2,aq 0.19864E-09 -9.7019 0.19864E-09 -9.7019 0.10000E+01 0.0000 53 H2,aq 0.73761E-09 -9.1322 0.73700E-09 -9.1325 0.99916E+00 -0.0004 54 KCl,aq 0.82341E-10 -10.0844 0.82341E-10 -10.0844 0.10000E+01 0.0000 55 KHSO4,aq 0.49228E-18 -18.3078 0.49228E-18 -18.3078 0.10000E+01 0.0000 56 KOH,aq 0.58542E-07 -7.2325 0.58542E-07 -7.2325 0.10000E+01 0.0000 57 KSO4- 0.11242E-07 -7.9492 0.10143E-07 -7.9938 0.90222E+00 -0.0447 58 MgCO3,aq 0.27449E-12 -12.5615 0.27449E-12 -12.5615 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.76957E-14 -14.1137 0.69471E-14 -14.1582 0.90272E+00 -0.0444 60 MgCl+ 0.64886E-14 -14.1879 0.58573E-14 -14.2323 0.90272E+00 -0.0444 61 MgOH+ 0.52640E-10 -10.2787 0.47519E-10 -10.3231 0.90272E+00 -0.0444 63 MnO,aq 0.37141E-09 -9.4301 0.37141E-09 -9.4301 0.10000E+01 0.0000 64 MnOH+ 0.32001E-09 -9.4948 0.28888E-09 -9.5393 0.90272E+00 -0.0444 65 MnO2-2 0.24772E-12 -12.6060 0.17371E-12 -12.7602 0.70125E+00 -0.1541 66 HMnO2- 0.11236E-10 -10.9494 0.10138E-10 -10.9941 0.90222E+00 -0.0447 69 MnCl+ 0.21598E-13 -13.6656 0.19497E-13 -13.7100 0.90272E+00 -0.0444 70 MnSO4,aq 0.13151E-12 -12.8811 0.13151E-12 -12.8811 0.10000E+01 0.0000 71 NaCl,aq 0.16716E-06 -6.7769 0.16716E-06 -6.7769 0.10000E+01 0.0000 72 NaOH,aq 0.65390E-05 -5.1845 0.65390E-05 -5.1845 0.10000E+01 0.0000 74 OH- 0.24053E-02 -2.6188 0.21690E-02 -2.6637 0.90175E+00 -0.0449 79 HPO3-2 0.15953E-16 -16.7972 0.11187E-16 -16.9513 0.70125E+00 -0.1541 82 H3PO4,aq 0.24173E-14 -14.6167 0.24173E-14 -14.6167 0.10000E+01 0.0000 83 H2PO4- 0.26522E-07 -7.5764 0.23935E-07 -7.6210 0.90247E+00 -0.0446 84 PO4-3 0.32044E-07 -7.4942 0.14919E-07 -7.8263 0.46558E+00 -0.3320 87 H2P2O7-2 0.64059E-16 -16.1934 0.44921E-16 -16.3475 0.70125E+00 -0.1541 88 HP2O7-3 0.73339E-13 -13.1347 0.33673E-13 -13.4727 0.45914E+00 -0.3381 89 P2O7-4 0.11795E-12 -12.9283 0.30199E-13 -13.5200 0.25604E+00 -0.5917 90 H2S,aq 0.54978E-16 -16.2598 0.54932E-16 -16.2602 0.99916E+00 -0.0004 97 SO3-2 0.24346E-14 -14.6136 0.17143E-14 -14.7659 0.70417E+00 -0.1523 98 HSO3- 0.31691E-16 -16.4991 0.28593E-16 -16.5437 0.90222E+00 -0.0447 99 HSO4- 0.50890E-11 -11.2934 0.45952E-11 -11.3377 0.90296E+00 -0.0443 Charge balance for all species = 0.8957E-13 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.2947340E-09 -.4598447E-02 -.4633310E+01 0.0000 2 H2O 0.1000000E+01 0.5550881E+02 0.9996523E+06 0.0000 3 Cl- 0.1379015E-03 0.1380687E-03 0.4893211E+01 5.6694 4 SO4-- 0.2551066E-04 0.2552260E-04 0.2450870E+01 14.4019 5 HCO3- 0.9193702E-05 0.1307896E-04 0.7977577E+00 4.4935 6 HS- 0.7395197E-13 -.6526935E-09 -.2157821E-04 -3.6012 7 Al+++ 0.9013199E-26 0.5465926E-04 0.1474265E+01 2.3403 8 H4SiO4 0.4772629E-03 0.2441234E-02 0.2345567E+03 -3.3212 9 Ca++ 0.1126943E-07 0.1425894E-07 0.5712667E-03 11.0461 10 Mg++ 0.4589884E-10 0.1005135E-09 0.2442815E-05 8.6555 11 Fe++ 0.2707244E-12 0.1134294E-07 0.6332438E-03 6.4263 12 K+ 0.4045296E-04 0.4052282E-04 0.1583960E+01 5.1370 13 Na+ 0.4493683E-02 0.4610086E-02 0.1059473E+03 7.1824 14 Mn++ 0.3637094E-10 0.7394335E-09 0.4060855E-04 8.5547 15 HPO4-- 0.6941537E-05 0.7000104E-05 0.6716241E+00 13.8366 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.6289276E-01 -.4595297E-02 -.5829746E-01 0.0000000E+00 2 H2O 0.5546063E+02 0.5547079E+02 -.1015994E-01 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.1307877E-03 0.2550512E-04 0.1052826E-03 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.1052832E-03 -.6522465E-09 -.1052826E-03 0.0000000E+00 7 Al+++ 0.1238756E-01 0.5462182E-04 0.1233294E-01 0.0000000E+00 8 H4SiO4 0.3955816E-01 0.2439562E-02 0.3711860E-01 0.0000000E+00 9 Ca++ 0.4383863E-02 0.1424918E-07 0.4383849E-02 0.0000000E+00 10 Mg++ 0.3015079E-02 0.1004447E-09 0.3015079E-02 0.0000000E+00 11 Fe++ 0.2708720E-02 0.1133517E-07 0.2708708E-02 0.0000000E+00 12 K+ 0.8065817E-03 0.4049507E-04 0.7660867E-03 0.0000000E+00 13 Na+ 0.4928742E-02 0.4606928E-02 0.3218133E-03 0.0000000E+00 14 Mn++ 0.6586933E-04 0.7389271E-09 0.6586859E-04 0.0000000E+00 15 HPO4-- 0.2248087E-04 0.6995309E-05 0.1548556E-04 0.0000000E+00 Chg. balance for solid moles: 0.3903E-17 Mass of aqueous solution: 0.999671E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 3.7990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) apatite-OH 0.5162E-05 -5.287 0.2593E-02 -2.586 0.6312E-01 0.8239E-03 clinochlore 0.6030E-03 -3.220 0.3352 -0.475 8.159 0.1275 daphnite 0.3733E-03 -3.428 0.2663 -0.575 6.484 0.8071E-01 chlorite-Mn 0.1317E-04 -4.880 0.9340E-02 -2.030 0.2274 0.2976E-02 hematite 0.2793E-03 -3.554 0.4460E-01 -1.351 1.086 0.8453E-02 microcline 0.7661E-03 -3.116 0.2132 -0.671 5.191 0.8329E-01 paragonite 0.2750E-03 -3.561 0.1051 -0.978 2.559 0.3633E-01 stilbite 0.4358E-02 -2.361 3.071 0.487 74.76 1.432 nontronite-Na 0.1419E-03 -3.848 0.6033E-01 -1.219 1.469 0.1874E-01 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.6094E+00 0.6094E+00 1.0000 -0.215 daphnite 0.3773E+00 0.3773E+00 1.0000 -0.423 chlorite-Mn 0.1331E-01 0.1331E-01 1.0000 -1.876 hematite 0.1000E+01 0.1000E+01 1.0000 0.000 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 paragonite 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 nontronite-Na 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 4.107915 g Volume = 1.791283 cm3 Porosity: 28.9061% V(tot) - V(min): 0.72832E+00 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 3.7990000 g log = 0.5797 Original solution: 1000.0103000 g Original solution / Rock added: 263.23 (Water/Rock Ratio), log = 2.4203 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0203 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.1000E+01 0.9860 0.1006E+01 0.1020E+01 CO2,gas 0.4918E-06 1.0071 0.5053E-06 0.5018E-06 CH4,gas 0.4281E-16 1.0125 0.4423E-16 0.4368E-16 H2,gas 0.9478E-06 1.0005 0.9676E-06 0.9671E-06 H2S,gas 0.1486E-14 0.9960 0.1510E-14 0.1516E-14 S2,gas 0.8960E-37 1.0000 0.9142E-37 0.9142E-37 CO,gas 0.1277E-15 1.0000 0.1303E-15 0.1303E-15 SO3,gas 0.4707E-39 1.0000 0.4802E-39 0.4802E-39 SO2,gas 0.1772E-22 1.0000 0.1808E-22 0.1808E-22 HCl,gas 0.1050E-16 1.0000 0.1072E-16 0.1072E-16 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 32 apatite-OH -18.15 -18.15 0.00 0.000 0.60662E-11 46 clinochlore 39.07 39.07 0.00 0.000 0.12132E-10 47 daphnite 28.97 28.97 0.00 0.000 0.48529E-10 48 chlorite-Mn 46.87 46.87 0.00 0.000 0.24265E-10 90 hematite 12.57 12.57 0.00 0.000 -0.30331E-11 116 microcline -2.49 -2.49 0.00 0.000 0.13649E-10 121 paragonite 4.24 4.24 0.00 0.000 -0.10616E-10 163 stilbite -7.52 -7.52 0.00 0.000 0.15165E-10 209 nontronite-Na 3.52 3.52 0.00 0.000 0.10616E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -14.66 -8.00 -2.665 0.13652E+05 -6.296 3 CH4,gas 4.54 -13.51 -18.05 -4.513 0.30825E+05 -16.354 4 H2,gas 8.00 0.29 -7.71 -4.408 0.13170E+05 -6.014 5 H2S,gas -6.23 -22.75 -16.52 -8.260 0.28207E+05 -14.821 6 S2,gas -7.34 -46.07 -38.74 -5.960 0.66144E+05 -37.039 7 CO,gas 3.21 -14.37 -17.58 -5.410 0.30024E+05 -15.885 8 SO3,gas 17.12 -23.90 -41.02 -10.254 0.70036E+05 -39.319 9 SO2,gas 0.83 -23.61 -24.44 -6.518 0.41734E+05 -22.743 10 HCl,gas 5.19 -13.48 -18.67 -9.334 0.31877E+05 -16.970 11 acmite 7.71 6.82 -0.89 -0.092 0.15140E+04 15 albite-high 0.69 -0.44 -1.13 -0.087 0.19365E+04 16 albite -0.38 -0.44 -0.06 -0.004 0.97679E+02 19 spessartine 24.46 20.38 -4.08 -0.204 0.69606E+04 20 analcite 3.32 2.88 -0.44 -0.049 0.75418E+03 21 andalusite 5.00 1.36 -3.64 -0.364 0.62191E+04 22 andradite 39.01 35.74 -3.27 -0.170 0.55798E+04 23 grossular 32.73 27.86 -4.88 -0.244 0.83260E+04 26 annite 20.12 16.79 -3.33 -0.185 0.56874E+04 27 phlogopite 27.06 23.48 -3.58 -0.199 0.61207E+04 29 anorthite 12.71 9.08 -3.63 -0.279 0.61916E+04 35 aragonite 0.97 -3.61 -4.58 -1.525 0.78132E+04 36 brucite 12.57 8.66 -3.91 -0.783 0.66815E+04 37 calcite 0.81 -3.61 -4.42 -1.474 0.75490E+04 38 carnegieite-low 9.02 6.20 -2.82 -0.403 0.48183E+04 39 carnegieite-high 10.09 6.20 -3.89 -0.556 0.66453E+04 40 carpholite-Mg 8.58 6.69 -1.89 -0.126 0.32247E+04 41 carpholite-Fe 6.71 4.46 -2.25 -0.150 0.38389E+04 42 celadonite 5.34 2.85 -2.49 -0.147 0.42582E+04 43 celadonite-Fe 3.88 0.62 -3.26 -0.192 0.55628E+04 44 chrysotile 23.89 19.32 -4.57 -0.381 0.78005E+04 50 chloritoid-Mg 13.20 10.01 -3.18 -0.212 0.54348E+04 51 chloritoid-Fe 9.17 7.79 -1.39 -0.093 0.23700E+04 52 chloritoid-Mn 11.40 9.91 -1.49 -0.099 0.25393E+04 54 coesite -2.38 -3.32 -0.95 -0.315 0.16139E+04 59 corundum 8.38 4.68 -3.70 -0.337 0.63221E+04 61 cristobalite -2.56 -3.32 -0.76 -0.254 0.12992E+04 63 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71234E+04 65 diaspore 2.87 2.34 -0.53 -0.089 0.91084E+03 67 diopside 16.18 13.06 -3.12 -0.312 0.53311E+04 68 hedenbergite 14.21 10.83 -3.38 -0.338 0.57683E+04 75 epidote 24.67 23.09 -1.58 -0.076 0.26940E+04 76 clinozoisite 22.81 19.15 -3.66 -0.166 0.62438E+04 77 epidote-Fe 29.84 27.03 -2.81 -0.146 0.47909E+04 78 fayalite 14.05 9.53 -4.51 -0.645 0.77081E+04 79 ferrosilite 11.15 6.21 -4.94 -0.494 0.84337E+04 83 gibbsite 4.08 2.34 -1.74 -0.248 0.29694E+04 84 glaucophane 22.97 18.44 -4.53 -0.123 0.77400E+04 87 greenalite 16.14 12.64 -3.50 -0.292 0.59813E+04 91 heulandite -5.83 -7.52 -1.69 -0.077 0.28938E+04 95 jadeite 4.22 2.88 -1.34 -0.134 0.22797E+04 97 kalsilite 7.58 4.16 -3.43 -0.490 0.58531E+04 98 kaolinite -1.33 -1.96 -0.63 -0.057 0.10744E+04 99 kyanite 4.88 1.36 -3.52 -0.352 0.60050E+04 101 laumontite 2.88 2.44 -0.44 -0.029 0.75425E+03 102 lawsonite 9.62 9.08 -0.53 -0.035 0.90823E+03 103 leucite 4.12 0.83 -3.28 -0.328 0.56075E+04 105 lizardite 23.24 19.32 -3.92 -0.327 0.66932E+04 107 magnetite 20.09 18.99 -1.09 -0.089 0.18695E+04 108 minnesotaite 10.39 5.99 -4.39 -0.258 0.75028E+04 110 magnesioferrite 26.21 21.22 -4.99 -0.407 0.85216E+04 113 margarite 17.32 13.76 -3.56 -0.142 0.60768E+04 120 muscovite 2.58 2.19 -0.39 -0.023 0.66322E+03 122 nepheline 8.34 6.20 -2.14 -0.305 0.36507E+04 134 phlogopite-Na 29.65 25.53 -4.12 -0.229 0.70372E+04 136 prehnite 19.37 16.81 -2.56 -0.151 0.43760E+04 137 prehnite-Fe 22.50 20.75 -1.75 -0.105 0.29812E+04 138 pumpellyite-Fe 46.27 42.38 -3.88 -0.086 0.66331E+04 139 pumpellyite-Mg 48.99 44.61 -4.38 -0.097 0.74805E+04 145 pyroxmangite 7.40 5.23 -2.17 -0.433 0.36971E+04 146 pyrophyllite -6.18 -8.60 -2.43 -0.152 0.41469E+04 147 quartz -2.99 -3.32 -0.33 -0.111 0.56655E+03 152 rhodonite 7.45 5.23 -2.21 -0.442 0.37774E+04 153 sanidine -1.28 -2.49 -1.21 -0.093 0.20677E+04 156 sillimanite 5.26 1.36 -3.90 -0.390 0.66630E+04 164 stilpnomelane-Fe 13.02 12.81 -0.21 -0.006 0.35217E+03 165 stilpnomelane-Mg 27.44 23.96 -3.48 -0.104 0.59505E+04 168 sudoite 21.08 16.71 -4.37 -0.141 0.74602E+04 171 talc 16.49 12.68 -3.81 -0.224 0.65048E+04 174 tephroite 18.09 13.79 -4.30 -0.614 0.73382E+04 177 topaz-H 4.62 1.36 -3.26 -0.296 0.55650E+04 178 tridymite -2.63 -3.32 -0.69 -0.232 0.11865E+04 187 wairakite 3.95 2.44 -1.51 -0.089 0.25762E+04 188 walstromite 11.51 7.72 -3.78 -0.757 0.64616E+04 189 wollastonite 10.46 7.72 -2.74 -0.547 0.46721E+04 190 pseudo-wollastonite 11.00 7.72 -3.27 -0.655 0.55919E+04 191 zoisite 22.85 19.15 -3.70 -0.168 0.63178E+04 192 akaganeite 7.75 6.28 -1.47 -0.318 0.25125E+04 193 beidellite-Ca -1.65 -4.91 -3.27 -0.202 0.55799E+04 194 beidellite-H -2.33 -6.74 -4.41 -0.281 0.75299E+04 195 beidellite-K -1.52 -5.04 -3.52 -0.216 0.60116E+04 196 beidellite-Mg -1.79 -5.31 -3.52 -0.218 0.60073E+04 197 beidellite-Na -1.34 -4.37 -3.02 -0.185 0.51630E+04 199 chalcedony -2.80 -3.32 -0.52 -0.173 0.88585E+03 201 montmorillonite-Ca -2.29 -4.70 -2.41 -0.149 0.41101E+04 202 montmorillonite-K -2.24 -4.83 -2.59 -0.159 0.44198E+04 203 montmorillonite-Mg -2.48 -5.09 -2.61 -0.162 0.44606E+04 204 montmorillonite-Na -2.04 -4.15 -2.11 -0.129 0.36070E+04 205 nontronite-Ca 3.21 2.97 -0.24 -0.016 0.41393E+03 206 nontronite-H 2.53 1.15 -1.38 -0.093 0.23618E+04 207 nontronite-K 3.34 2.84 -0.50 -0.032 0.84689E+03 208 nontronite-Mg 3.07 2.58 -0.50 -0.032 0.84855E+03 224 tobermorite 9.82 5.88 -3.94 -1.076 0.67323E+04 233 boehmite 4.41 2.34 -2.07 -0.344 0.35278E+04 235 ferrous-oxide 9.81 6.43 -3.39 -0.846 0.57802E+04 240 silica-amorphous -2.09 -3.32 -1.23 -0.410 0.21000E+04 242 an20ab80 2.02 1.46 -0.55 -0.043 0.94561E+03 243 an25ab75 2.65 1.94 -0.71 -0.054 0.12046E+04 244 an30ab70 3.28 2.42 -0.86 -0.066 0.14731E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 0.1000000 g Current total amount of reactant added: 3.7990000 g New total amount of reactant added: 3.8990000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.8093E-13 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 6 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 3.8990000 Water: Moles liquid = 0.5547E+02 kg liquid = 0.9993E+00 Moles total = 0.5546E+02 kg total = 0.9991E+00 Activity = 1.0000 Stoichiometric ionic strength = .2772640E-02 Osmotic coef. = 0.9708 True ionic strength = .4680428E-02 Chg. balance for total moles = 0.8093E-13 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.28747E-09 -9.5414 0.25958E-09 -9.5857 0.90299E+00 -0.0443 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13790E-03 -3.8604 0.12430E-03 -3.9055 0.90139E+00 -0.0451 4 SO4-- 0.25511E-04 -4.5933 0.17836E-04 -4.7487 0.69913E+00 -0.1554 5 HCO3- 0.91156E-05 -5.0402 0.82201E-05 -5.0851 0.90177E+00 -0.0449 6 HS- 0.76130E-13 -13.1184 0.68625E-13 -13.1635 0.90143E+00 -0.0451 7 Al+++ 0.83000E-26 -26.0809 0.37789E-26 -26.4226 0.45528E+00 -0.3417 8 H4SiO4 0.47572E-03 -3.3226 0.47572E-03 -3.3226 0.10000E+01 0.0000 9 Ca++ 0.11279E-07 -7.9477 0.78691E-08 -8.1041 0.69765E+00 -0.1564 10 Mg++ 0.44064E-10 -10.3559 0.30700E-10 -10.5129 0.69671E+00 -0.1569 11 Fe++ 0.25990E-12 -12.5852 0.18113E-12 -12.7420 0.69694E+00 -0.1568 12 K+ 0.40368E-04 -4.3940 0.36406E-04 -4.4388 0.90184E+00 -0.0449 13 Na+ 0.46037E-02 -2.3369 0.41495E-02 -2.3820 0.90135E+00 -0.0451 14 Mn++ 0.34917E-10 -10.4570 0.24341E-10 -10.6137 0.69711E+00 -0.1567 15 HPO4-- 0.67621E-05 -5.1699 0.47278E-05 -5.3253 0.69916E+00 -0.1554 16 HSiO3- 0.18984E-02 -2.7216 0.17112E-02 -2.7667 0.90139E+00 -0.0451 17 Ca(HSiO3)+ 0.34003E-09 -9.4685 0.30667E-09 -9.5133 0.90190E+00 -0.0448 18 Mg(HSiO3)+ 0.16509E-11 -11.7823 0.14890E-11 -11.8271 0.90190E+00 -0.0448 19 NaHSiO3,aq 0.11485E-03 -3.9399 0.11485E-03 -3.9399 0.10000E+01 0.0000 20 AlO+ 0.84594E-14 -14.0727 0.76295E-14 -14.1175 0.90190E+00 -0.0448 21 AlOH+2 0.14142E-19 -19.8495 0.98615E-20 -20.0061 0.69730E+00 -0.1566 22 HAlO2,aq 0.58533E-08 -8.2326 0.58533E-08 -8.2326 0.10000E+01 0.0000 23 AlO2- 0.55404E-04 -4.2565 0.49914E-04 -4.3018 0.90091E+00 -0.0453 24 CH4,aq 0.30749E-19 -19.5122 0.30723E-19 -19.5125 0.99914E+00 -0.0004 29 CO,aq 0.85636E-19 -19.0673 0.85636E-19 -19.0673 0.10000E+01 0.0000 30 CO2,aq 0.45633E-08 -8.3407 0.45594E-08 -8.3411 0.99914E+00 -0.0004 31 CO3-2 0.39588E-05 -5.4024 0.27660E-05 -5.5581 0.69870E+00 -0.1557 32 CaCO3,aq 0.27292E-09 -9.5640 0.27292E-09 -9.5640 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.18308E-11 -11.7374 0.16512E-11 -11.7822 0.90190E+00 -0.0448 34 CaCl+ 0.17551E-11 -11.7557 0.15829E-11 -11.8005 0.90190E+00 -0.0448 35 CaCl2,aq 0.46746E-16 -16.3303 0.46746E-16 -16.3303 0.10000E+01 0.0000 36 CaOH+ 0.23955E-08 -8.6206 0.21605E-08 -8.6654 0.90190E+00 -0.0448 37 CaSO4,aq 0.44568E-10 -10.3510 0.44568E-10 -10.3510 0.10000E+01 0.0000 38 HCl,aq 0.59126E-14 -14.2282 0.59126E-14 -14.2282 0.10000E+01 0.0000 43 FeCl+ 0.39514E-16 -16.4032 0.35638E-16 -16.4481 0.90190E+00 -0.0448 46 FeO,aq 0.10448E-09 -9.9810 0.10448E-09 -9.9810 0.10000E+01 0.0000 47 FeOH+ 0.25185E-10 -10.5989 0.22714E-10 -10.6437 0.90190E+00 -0.0448 48 HFeO2- 0.46720E-08 -8.3305 0.42112E-08 -8.3756 0.90139E+00 -0.0451 49 FeO+ 0.21969E-14 -14.6582 0.19814E-14 -14.7030 0.90190E+00 -0.0448 51 FeO2- 0.66751E-08 -8.1755 0.60168E-08 -8.2206 0.90139E+00 -0.0451 52 HFeO2,aq 0.19864E-09 -9.7019 0.19864E-09 -9.7019 0.10000E+01 0.0000 53 H2,aq 0.74832E-09 -9.1259 0.74768E-09 -9.1263 0.99914E+00 -0.0004 54 KCl,aq 0.82017E-10 -10.0861 0.82017E-10 -10.0861 0.10000E+01 0.0000 55 KHSO4,aq 0.47656E-18 -18.3219 0.47656E-18 -18.3219 0.10000E+01 0.0000 56 KOH,aq 0.59894E-07 -7.2226 0.59894E-07 -7.2226 0.10000E+01 0.0000 57 KSO4- 0.11178E-07 -7.9516 0.10076E-07 -7.9967 0.90139E+00 -0.0451 58 MgCO3,aq 0.26689E-12 -12.5737 0.26689E-12 -12.5737 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.72982E-14 -14.1368 0.65822E-14 -14.1816 0.90190E+00 -0.0448 60 MgCl+ 0.62060E-14 -14.2072 0.55972E-14 -14.2520 0.90190E+00 -0.0448 61 MgOH+ 0.51715E-10 -10.2864 0.46641E-10 -10.3312 0.90190E+00 -0.0448 63 MnO,aq 0.37409E-09 -9.4270 0.37409E-09 -9.4270 0.10000E+01 0.0000 64 MnOH+ 0.31439E-09 -9.5025 0.28355E-09 -9.5474 0.90190E+00 -0.0448 65 MnO2-2 0.26370E-12 -12.5789 0.18425E-12 -12.7346 0.69870E+00 -0.1557 66 HMnO2- 0.11625E-10 -10.9346 0.10478E-10 -10.9797 0.90139E+00 -0.0451 69 MnCl+ 0.20658E-13 -13.6849 0.18631E-13 -13.7298 0.90190E+00 -0.0448 70 MnSO4,aq 0.12533E-12 -12.9019 0.12533E-12 -12.9019 0.10000E+01 0.0000 71 NaCl,aq 0.17093E-06 -6.7672 0.17093E-06 -6.7672 0.10000E+01 0.0000 72 NaOH,aq 0.68682E-05 -5.1632 0.68682E-05 -5.1632 0.10000E+01 0.0000 74 OH- 0.24706E-02 -2.6072 0.22258E-02 -2.6525 0.90091E+00 -0.0453 79 HPO3-2 0.15766E-16 -16.8023 0.11016E-16 -16.9580 0.69870E+00 -0.1557 82 H3PO4,aq 0.22280E-14 -14.6521 0.22280E-14 -14.6521 0.10000E+01 0.0000 83 H2PO4- 0.25109E-07 -7.6002 0.22639E-07 -7.6451 0.90164E+00 -0.0450 84 PO4-3 0.32172E-07 -7.4925 0.14860E-07 -7.8280 0.46190E+00 -0.3355 87 H2P2O7-2 0.57518E-16 -16.2402 0.40188E-16 -16.3959 0.69870E+00 -0.1557 88 HP2O7-3 0.67887E-13 -13.1682 0.30914E-13 -13.5098 0.45537E+00 -0.3416 89 P2O7-4 0.11274E-12 -12.9479 0.28450E-13 -13.5459 0.25236E+00 -0.5980 90 H2S,aq 0.55103E-16 -16.2588 0.55056E-16 -16.2592 0.99914E+00 -0.0004 97 SO3-2 0.24697E-14 -14.6074 0.17329E-14 -14.7612 0.70167E+00 -0.1539 98 HSO3- 0.31246E-16 -16.5052 0.28165E-16 -16.5503 0.90139E+00 -0.0451 99 HSO4- 0.49458E-11 -11.3058 0.44618E-11 -11.3505 0.90214E+00 -0.0447 Charge balance for all species = 0.8951E-13 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.2874692E-09 -.4716468E-02 -.4752191E+01 0.0000 2 H2O 0.1000000E+01 0.5550883E+02 0.9996451E+06 0.0000 3 Cl- 0.1379001E-03 0.1380712E-03 0.4893260E+01 5.6802 4 SO4-- 0.2551117E-04 0.2552307E-04 0.2450897E+01 14.4227 5 HCO3- 0.9115565E-05 0.1307919E-04 0.7977657E+00 4.5006 6 HS- 0.7612990E-13 -.6720572E-09 -.2221821E-04 -3.5778 7 Al+++ 0.8300045E-26 0.5541027E-04 0.1494510E+01 2.3345 8 H4SiO4 0.4757217E-03 0.2489005E-02 0.2391448E+03 -3.3226 9 Ca++ 0.1127947E-07 0.1433609E-07 0.5743534E-03 11.0674 10 Mg++ 0.4406397E-10 0.9770986E-10 0.2374660E-05 8.6586 11 Fe++ 0.2599001E-12 0.1167559E-07 0.6518098E-03 6.4295 12 K+ 0.4036836E-04 0.4043951E-04 0.1580692E+01 5.1469 13 Na+ 0.4603694E-02 0.4725579E-02 0.1086007E+03 7.2037 14 Mn++ 0.3491656E-10 0.7354318E-09 0.4038848E-04 8.5578 15 HPO4-- 0.6762054E-05 0.6819335E-05 0.6542754E+00 13.8461 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.6454861E-01 -.4713155E-02 -.5983546E-01 0.0000000E+00 2 H2O 0.5545937E+02 0.5546983E+02 -.1046031E-01 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.1335591E-03 0.2550514E-04 0.1080539E-03 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.1080546E-03 -.6715851E-09 -.1080539E-03 0.0000000E+00 7 Al+++ 0.1271363E-01 0.5537135E-04 0.1265826E-01 0.0000000E+00 8 H4SiO4 0.4059944E-01 0.2487256E-02 0.3811218E-01 0.0000000E+00 9 Ca++ 0.4498877E-02 0.1432602E-07 0.4498863E-02 0.0000000E+00 10 Mg++ 0.3094444E-02 0.9764122E-10 0.3094444E-02 0.0000000E+00 11 Fe++ 0.2780021E-02 0.1166738E-07 0.2780009E-02 0.0000000E+00 12 K+ 0.8278132E-03 0.4041111E-04 0.7874021E-03 0.0000000E+00 13 Na+ 0.5054266E-02 0.4722259E-02 0.3320067E-03 0.0000000E+00 14 Mn++ 0.6760319E-04 0.7349152E-09 0.6760245E-04 0.0000000E+00 15 HPO4-- 0.2307263E-04 0.6814545E-05 0.1625809E-04 0.0000000E+00 Chg. balance for solid moles: 0.3063E-17 Mass of aqueous solution: 0.999660E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 3.8990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) apatite-OH 0.5419E-05 -5.266 0.2722E-02 -2.565 0.6455E-01 0.8650E-03 clinochlore 0.6189E-03 -3.208 0.3440 -0.463 8.157 0.1308 daphnite 0.3831E-03 -3.417 0.2734 -0.563 6.482 0.8284E-01 chlorite-Mn 0.1352E-04 -4.869 0.9586E-02 -2.018 0.2273 0.3055E-02 hematite 0.2811E-03 -3.551 0.4489E-01 -1.348 1.064 0.8508E-02 microcline 0.7874E-03 -3.104 0.2192 -0.659 5.197 0.8561E-01 paragonite 0.2821E-03 -3.550 0.1078 -0.967 2.557 0.3727E-01 stilbite 0.4472E-02 -2.350 3.151 0.498 74.73 1.470 nontronite-Na 0.1511E-03 -3.821 0.6427E-01 -1.192 1.524 0.1997E-01 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.6094E+00 0.6094E+00 1.0000 -0.215 daphnite 0.3773E+00 0.3773E+00 1.0000 -0.423 chlorite-Mn 0.1331E-01 0.1331E-01 1.0000 -1.876 hematite 0.1000E+01 0.1000E+01 1.0000 0.000 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 paragonite 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 nontronite-Na 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 4.217160 g Volume = 1.838804 cm3 Porosity: 28.1605% V(tot) - V(min): 0.72080E+00 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 3.8990000 g log = 0.5910 Original solution: 1000.0103000 g Original solution / Rock added: 256.48 (Water/Rock Ratio), log = 2.4091 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0203 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.1000E+01 0.9860 0.1006E+01 0.1020E+01 CO2,gas 0.4747E-06 1.0071 0.4878E-06 0.4844E-06 CH4,gas 0.4377E-16 1.0125 0.4522E-16 0.4466E-16 H2,gas 0.9616E-06 1.0005 0.9816E-06 0.9811E-06 H2S,gas 0.1489E-14 0.9960 0.1513E-14 0.1519E-14 S2,gas 0.8745E-37 1.0000 0.8923E-37 0.8923E-37 CO,gas 0.1251E-15 1.0000 0.1276E-15 0.1276E-15 SO3,gas 0.4454E-39 1.0000 0.4544E-39 0.4544E-39 SO2,gas 0.1701E-22 1.0000 0.1735E-22 0.1735E-22 HCl,gas 0.1023E-16 1.0000 0.1043E-16 0.1043E-16 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 32 apatite-OH -18.15 -18.15 0.00 0.000 0.18198E-10 46 clinochlore 39.07 39.07 0.00 0.000 0.36397E-10 47 daphnite 28.97 28.97 0.00 0.000 0.48529E-10 48 chlorite-Mn 46.87 46.87 0.00 0.000 0.12132E-10 90 hematite 12.57 12.57 0.00 0.000 -0.15165E-10 116 microcline -2.49 -2.49 0.00 0.000 0.25781E-10 121 paragonite 4.24 4.24 0.00 0.000 0.13649E-10 163 stilbite -7.52 -7.52 0.00 0.000 0.15165E-10 209 nontronite-Na 3.52 3.52 0.00 0.000 -0.15165E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -14.67 -8.01 -2.670 0.13678E+05 -6.312 3 CH4,gas 4.54 -13.50 -18.04 -4.511 0.30809E+05 -16.345 4 H2,gas 8.00 0.29 -7.71 -4.404 0.13160E+05 -6.008 5 H2S,gas -6.23 -22.75 -16.52 -8.260 0.28206E+05 -14.820 6 S2,gas -7.34 -46.08 -38.75 -5.961 0.66162E+05 -37.049 7 CO,gas 3.21 -14.38 -17.59 -5.413 0.30040E+05 -15.894 8 SO3,gas 17.12 -23.92 -41.04 -10.260 0.70077E+05 -39.343 9 SO2,gas 0.83 -23.63 -24.46 -6.523 0.41764E+05 -22.761 10 HCl,gas 5.19 -13.49 -18.68 -9.340 0.31897E+05 -16.982 11 acmite 7.71 6.84 -0.87 -0.090 0.14824E+04 15 albite-high 0.69 -0.43 -1.12 -0.086 0.19170E+04 16 albite -0.38 -0.43 -0.05 -0.004 0.78200E+02 19 spessartine 24.46 20.37 -4.08 -0.204 0.69713E+04 20 analcite 3.32 2.89 -0.43 -0.048 0.73230E+03 21 andalusite 5.00 1.35 -3.66 -0.366 0.62409E+04 22 andradite 39.01 35.80 -3.21 -0.167 0.54782E+04 23 grossular 32.73 27.90 -4.83 -0.241 0.82439E+04 26 annite 20.12 16.80 -3.32 -0.185 0.56714E+04 27 phlogopite 27.06 23.49 -3.58 -0.199 0.61047E+04 29 anorthite 12.71 9.09 -3.62 -0.278 0.61796E+04 35 aragonite 0.97 -3.60 -4.57 -1.523 0.78031E+04 36 brucite 12.57 8.66 -3.91 -0.782 0.66762E+04 37 calcite 0.81 -3.60 -4.42 -1.472 0.75389E+04 38 carnegieite-low 9.02 6.22 -2.81 -0.401 0.47940E+04 39 carnegieite-high 10.09 6.22 -3.88 -0.554 0.66210E+04 40 carpholite-Mg 8.58 6.68 -1.90 -0.127 0.32437E+04 41 carpholite-Fe 6.71 4.45 -2.26 -0.151 0.38578E+04 42 celadonite 5.34 2.85 -2.49 -0.147 0.42553E+04 43 celadonite-Fe 3.88 0.62 -3.26 -0.192 0.55599E+04 44 chrysotile 23.89 19.33 -4.56 -0.380 0.77893E+04 50 chloritoid-Mg 13.20 10.01 -3.19 -0.213 0.54514E+04 51 chloritoid-Fe 9.17 7.78 -1.40 -0.093 0.23866E+04 52 chloritoid-Mn 11.40 9.90 -1.50 -0.100 0.25558E+04 54 coesite -2.38 -3.32 -0.95 -0.316 0.16163E+04 59 corundum 8.38 4.67 -3.71 -0.338 0.63416E+04 61 cristobalite -2.56 -3.32 -0.76 -0.254 0.13016E+04 63 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71234E+04 65 diaspore 2.87 2.33 -0.54 -0.090 0.92058E+03 67 diopside 16.18 13.08 -3.10 -0.310 0.52943E+04 68 hedenbergite 14.21 10.85 -3.36 -0.336 0.57315E+04 75 epidote 24.67 23.12 -1.55 -0.075 0.26481E+04 76 clinozoisite 22.81 19.17 -3.64 -0.165 0.62076E+04 77 epidote-Fe 29.84 27.07 -2.77 -0.144 0.47352E+04 78 fayalite 14.05 9.54 -4.51 -0.644 0.76998E+04 79 ferrosilite 11.15 6.21 -4.94 -0.494 0.84278E+04 83 gibbsite 4.08 2.33 -1.74 -0.249 0.29791E+04 84 glaucophane 22.97 18.47 -4.50 -0.122 0.76899E+04 87 greenalite 16.14 12.64 -3.50 -0.291 0.59701E+04 91 heulandite -5.83 -7.52 -1.69 -0.077 0.28938E+04 95 jadeite 4.22 2.89 -1.32 -0.132 0.22578E+04 97 kalsilite 7.58 4.16 -3.43 -0.489 0.58483E+04 98 kaolinite -1.33 -1.98 -0.64 -0.058 0.10986E+04 99 kyanite 4.88 1.35 -3.53 -0.353 0.60268E+04 101 laumontite 2.88 2.45 -0.44 -0.029 0.74706E+03 102 lawsonite 9.62 9.09 -0.52 -0.035 0.89623E+03 103 leucite 4.12 0.84 -3.28 -0.328 0.56051E+04 105 lizardite 23.24 19.33 -3.91 -0.326 0.66819E+04 107 magnetite 20.09 19.00 -1.09 -0.089 0.18641E+04 108 minnesotaite 10.39 6.00 -4.39 -0.258 0.74964E+04 110 magnesioferrite 26.21 21.22 -4.99 -0.407 0.85162E+04 113 margarite 17.32 13.76 -3.56 -0.143 0.60843E+04 120 muscovite 2.58 2.18 -0.40 -0.024 0.68270E+03 122 nepheline 8.34 6.22 -2.12 -0.303 0.36264E+04 134 phlogopite-Na 29.65 25.55 -4.10 -0.228 0.70017E+04 136 prehnite 19.37 16.84 -2.54 -0.149 0.43301E+04 137 prehnite-Fe 22.50 20.78 -1.71 -0.103 0.29256E+04 138 pumpellyite-Fe 46.27 42.44 -3.83 -0.085 0.65457E+04 139 pumpellyite-Mg 48.99 44.66 -4.33 -0.096 0.73932E+04 145 pyroxmangite 7.40 5.24 -2.16 -0.433 0.36942E+04 146 pyrophyllite -6.18 -8.62 -2.45 -0.153 0.41760E+04 147 quartz -2.99 -3.32 -0.33 -0.111 0.56895E+03 152 rhodonite 7.45 5.24 -2.21 -0.442 0.37744E+04 153 sanidine -1.28 -2.49 -1.21 -0.093 0.20677E+04 156 sillimanite 5.26 1.35 -3.92 -0.392 0.66849E+04 164 stilpnomelane-Fe 13.02 12.81 -0.21 -0.006 0.35570E+03 165 stilpnomelane-Mg 27.44 23.95 -3.49 -0.104 0.59541E+04 168 sudoite 21.08 16.69 -4.39 -0.142 0.74957E+04 171 talc 16.49 12.69 -3.81 -0.224 0.64984E+04 174 tephroite 18.09 13.79 -4.29 -0.613 0.73300E+04 177 topaz-H 4.62 1.35 -3.27 -0.297 0.55869E+04 178 tridymite -2.63 -3.32 -0.70 -0.232 0.11889E+04 187 wairakite 3.95 2.45 -1.50 -0.089 0.25690E+04 188 walstromite 11.51 7.74 -3.76 -0.753 0.64278E+04 189 wollastonite 10.46 7.74 -2.72 -0.543 0.46382E+04 190 pseudo-wollastonite 11.00 7.74 -3.26 -0.651 0.55580E+04 191 zoisite 22.85 19.17 -3.68 -0.167 0.62817E+04 192 akaganeite 7.75 6.28 -1.47 -0.318 0.25125E+04 193 beidellite-Ca -1.65 -4.93 -3.28 -0.203 0.56055E+04 194 beidellite-H -2.33 -6.75 -4.43 -0.283 0.75613E+04 195 beidellite-K -1.52 -5.06 -3.54 -0.217 0.60375E+04 196 beidellite-Mg -1.79 -5.33 -3.54 -0.219 0.60379E+04 197 beidellite-Na -1.34 -4.38 -3.04 -0.186 0.51824E+04 199 chalcedony -2.80 -3.32 -0.52 -0.173 0.88825E+03 201 montmorillonite-Ca -2.29 -4.71 -2.42 -0.150 0.41282E+04 202 montmorillonite-K -2.24 -4.84 -2.60 -0.159 0.44383E+04 203 montmorillonite-Mg -2.48 -5.11 -2.63 -0.162 0.44838E+04 204 montmorillonite-Na -2.04 -4.16 -2.12 -0.130 0.36190E+04 205 nontronite-Ca 3.21 2.97 -0.25 -0.016 0.41996E+03 206 nontronite-H 2.53 1.14 -1.39 -0.093 0.23738E+04 207 nontronite-K 3.34 2.84 -0.50 -0.032 0.85332E+03 208 nontronite-Mg 3.07 2.57 -0.50 -0.033 0.85968E+03 224 tobermorite 9.82 5.90 -3.93 -1.071 0.67045E+04 233 boehmite 4.41 2.33 -2.07 -0.345 0.35375E+04 235 ferrous-oxide 9.81 6.43 -3.38 -0.846 0.57749E+04 240 silica-amorphous -2.09 -3.32 -1.23 -0.410 0.21024E+04 242 an20ab80 2.02 1.47 -0.54 -0.042 0.92763E+03 243 an25ab75 2.65 1.95 -0.70 -0.053 0.11870E+04 244 an30ab70 3.28 2.43 -0.85 -0.066 0.14559E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 0.1000000 g Current total amount of reactant added: 3.8990000 g New total amount of reactant added: 3.9990000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.8094E-13 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 6 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 3.9990000 Water: Moles liquid = 0.5547E+02 kg liquid = 0.9993E+00 Moles total = 0.5546E+02 kg total = 0.9991E+00 Activity = 1.0000 Stoichiometric ionic strength = .2833350E-02 Osmotic coef. = 0.9706 True ionic strength = .4790174E-02 Chg. balance for total moles = 0.8094E-13 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.28057E-09 -9.5520 0.25313E-09 -9.5967 0.90220E+00 -0.0447 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13790E-03 -3.8604 0.12419E-03 -3.9059 0.90056E+00 -0.0455 4 SO4-- 0.25512E-04 -4.5933 0.17772E-04 -4.7503 0.69664E+00 -0.1570 5 HCO3- 0.90385E-05 -5.0439 0.81433E-05 -5.0892 0.90096E+00 -0.0453 6 HS- 0.78313E-13 -13.1062 0.70529E-13 -13.1516 0.90060E+00 -0.0455 7 Al+++ 0.76604E-26 -26.1157 0.34595E-26 -26.4610 0.45160E+00 -0.3452 8 H4SiO4 0.47422E-03 -3.3240 0.47422E-03 -3.3240 0.10000E+01 0.0000 9 Ca++ 0.11290E-07 -7.9473 0.78480E-08 -8.1052 0.69513E+00 -0.1579 10 Mg++ 0.42350E-10 -10.3732 0.29398E-10 -10.5317 0.69418E+00 -0.1585 11 Fe++ 0.24979E-12 -12.6024 0.17345E-12 -12.7608 0.69440E+00 -0.1584 12 K+ 0.40287E-04 -4.3948 0.36300E-04 -4.4401 0.90103E+00 -0.0453 13 Na+ 0.47136E-02 -2.3266 0.42447E-02 -2.3721 0.90053E+00 -0.0455 14 Mn++ 0.33558E-10 -10.4742 0.23308E-10 -10.6325 0.69458E+00 -0.1583 15 HPO4-- 0.65917E-05 -5.1810 0.45922E-05 -5.3380 0.69667E+00 -0.1570 16 HSiO3- 0.19425E-02 -2.7116 0.17493E-02 -2.7571 0.90056E+00 -0.0455 17 Ca(HSiO3)+ 0.34698E-09 -9.4597 0.31266E-09 -9.5049 0.90108E+00 -0.0452 18 Mg(HSiO3)+ 0.16176E-11 -11.7911 0.14576E-11 -11.8364 0.90108E+00 -0.0452 19 NaHSiO3,aq 0.12010E-03 -3.9205 0.12010E-03 -3.9205 0.10000E+01 0.0000 20 AlO+ 0.81515E-14 -14.0888 0.73452E-14 -14.1340 0.90108E+00 -0.0452 21 AlOH+2 0.13325E-19 -19.8753 0.92581E-20 -20.0335 0.69478E+00 -0.1582 22 HAlO2,aq 0.57788E-08 -8.2382 0.57788E-08 -8.2382 0.10000E+01 0.0000 23 AlO2- 0.56146E-04 -4.2507 0.50536E-04 -4.2964 0.90007E+00 -0.0457 24 CH4,aq 0.31419E-19 -19.5028 0.31391E-19 -19.5032 0.99912E+00 -0.0004 29 CO,aq 0.83895E-19 -19.0763 0.83895E-19 -19.0763 0.10000E+01 0.0000 30 CO2,aq 0.44084E-08 -8.3557 0.44045E-08 -8.3561 0.99912E+00 -0.0004 31 CO3-2 0.40362E-05 -5.3940 0.28100E-05 -5.5513 0.69620E+00 -0.1573 32 CaCO3,aq 0.27652E-09 -9.5583 0.27652E-09 -9.5583 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.18104E-11 -11.7422 0.16313E-11 -11.7875 0.90108E+00 -0.0452 34 CaCl+ 0.17504E-11 -11.7569 0.15772E-11 -11.8021 0.90108E+00 -0.0452 35 CaCl2,aq 0.46535E-16 -16.3322 0.46535E-16 -16.3322 0.10000E+01 0.0000 36 CaOH+ 0.24522E-08 -8.6104 0.22097E-08 -8.6557 0.90108E+00 -0.0452 37 CaSO4,aq 0.44291E-10 -10.3537 0.44291E-10 -10.3537 0.10000E+01 0.0000 38 HCl,aq 0.57604E-14 -14.2396 0.57604E-14 -14.2396 0.10000E+01 0.0000 43 FeCl+ 0.37838E-16 -16.4221 0.34095E-16 -16.4673 0.90108E+00 -0.0452 46 FeO,aq 0.10521E-09 -9.9779 0.10521E-09 -9.9779 0.10000E+01 0.0000 47 FeOH+ 0.24754E-10 -10.6064 0.22305E-10 -10.6516 0.90108E+00 -0.0452 48 HFeO2- 0.48292E-08 -8.3161 0.43490E-08 -8.3616 0.90056E+00 -0.0455 49 FeO+ 0.21442E-14 -14.6687 0.19321E-14 -14.7140 0.90108E+00 -0.0452 51 FeO2- 0.68515E-08 -8.1642 0.61702E-08 -8.2097 0.90056E+00 -0.0455 52 HFeO2,aq 0.19864E-09 -9.7019 0.19864E-09 -9.7019 0.10000E+01 0.0000 53 H2,aq 0.75890E-09 -9.1198 0.75823E-09 -9.1202 0.99912E+00 -0.0004 54 KCl,aq 0.81703E-10 -10.0878 0.81703E-10 -10.0878 0.10000E+01 0.0000 55 KHSO4,aq 0.46172E-18 -18.3356 0.46172E-18 -18.3356 0.10000E+01 0.0000 56 KOH,aq 0.61242E-07 -7.2130 0.61242E-07 -7.2130 0.10000E+01 0.0000 57 KSO4- 0.11116E-07 -7.9540 0.10011E-07 -7.9995 0.90056E+00 -0.0455 58 MgCO3,aq 0.25963E-12 -12.5856 0.25963E-12 -12.5856 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.69296E-14 -14.1593 0.62442E-14 -14.2045 0.90108E+00 -0.0452 60 MgCl+ 0.59427E-14 -14.2260 0.53549E-14 -14.2713 0.90108E+00 -0.0452 61 MgOH+ 0.50830E-10 -10.2939 0.45802E-10 -10.3391 0.90108E+00 -0.0452 63 MnO,aq 0.37672E-09 -9.4240 0.37672E-09 -9.4240 0.10000E+01 0.0000 64 MnOH+ 0.30901E-09 -9.5100 0.27844E-09 -9.5553 0.90108E+00 -0.0452 65 MnO2-2 0.28027E-12 -12.5524 0.19513E-12 -12.7097 0.69620E+00 -0.1573 66 HMnO2- 0.12016E-10 -10.9202 0.10821E-10 -10.9657 0.90056E+00 -0.0455 69 MnCl+ 0.19781E-13 -13.7037 0.17825E-13 -13.7490 0.90108E+00 -0.0452 70 MnSO4,aq 0.11959E-12 -12.9223 0.11959E-12 -12.9223 0.10000E+01 0.0000 71 NaCl,aq 0.17470E-06 -6.7577 0.17470E-06 -6.7577 0.10000E+01 0.0000 72 NaOH,aq 0.72048E-05 -5.1424 0.72048E-05 -5.1424 0.10000E+01 0.0000 74 OH- 0.25359E-02 -2.5959 0.22825E-02 -2.6416 0.90007E+00 -0.0457 79 HPO3-2 0.15586E-16 -16.8073 0.10851E-16 -16.9645 0.69620E+00 -0.1573 82 H3PO4,aq 0.20579E-14 -14.6866 0.20579E-14 -14.6866 0.10000E+01 0.0000 83 H2PO4- 0.23804E-07 -7.6233 0.21443E-07 -7.6687 0.90082E+00 -0.0454 84 PO4-3 0.32297E-07 -7.4908 0.14802E-07 -7.8297 0.45830E+00 -0.3389 87 H2P2O7-2 0.51788E-16 -16.2858 0.36055E-16 -16.4430 0.69620E+00 -0.1573 88 HP2O7-3 0.62966E-13 -13.2009 0.28441E-13 -13.5461 0.45169E+00 -0.3452 89 P2O7-4 0.10789E-12 -12.9670 0.26842E-13 -13.5712 0.24878E+00 -0.6042 90 H2S,aq 0.55225E-16 -16.2579 0.55176E-16 -16.2582 0.99912E+00 -0.0004 97 SO3-2 0.25045E-14 -14.6013 0.17512E-14 -14.7567 0.69922E+00 -0.1554 98 HSO3- 0.30818E-16 -16.5112 0.27754E-16 -16.5567 0.90056E+00 -0.0455 99 HSO4- 0.48100E-11 -11.3179 0.43355E-11 -11.3630 0.90134E+00 -0.0451 Charge balance for all species = 0.8956E-13 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.2805688E-09 -.4834462E-02 -.4871043E+01 0.0000 2 H2O 0.1000000E+01 0.5550884E+02 0.9996380E+06 0.0000 3 Cl- 0.1378988E-03 0.1380736E-03 0.4893309E+01 5.6907 4 SO4-- 0.2551168E-04 0.2552354E-04 0.2450923E+01 14.4431 5 HCO3- 0.9038521E-05 0.1307942E-04 0.7977737E+00 4.5075 6 HS- 0.7831297E-13 -.6914605E-09 -.2285951E-04 -3.5550 7 Al+++ 0.7660443E-26 0.5615179E-04 0.1514498E+01 2.3290 8 H4SiO4 0.4742245E-03 0.2536797E-02 0.2437349E+03 -3.3240 9 Ca++ 0.1129006E-07 0.1441363E-07 0.5774555E-03 11.0881 10 Mg++ 0.4234951E-10 0.9506920E-10 0.2310466E-05 8.6616 11 Fe++ 0.2497861E-12 0.1200949E-07 0.6704457E-03 6.4325 12 K+ 0.4028712E-04 0.4035956E-04 0.1577555E+01 5.1566 13 Na+ 0.4713612E-02 0.4841088E-02 0.1112544E+03 7.2245 14 Mn++ 0.3355764E-10 0.7317262E-09 0.4018468E-04 8.5608 15 HPO4-- 0.6591667E-05 0.6647769E-05 0.6378099E+00 13.8553 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.6620446E-01 -.4830982E-02 -.6137348E-01 0.0000000E+00 2 H2O 0.5545812E+02 0.5546888E+02 -.1076055E-01 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.1363304E-03 0.2550516E-04 0.1108252E-03 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.1108259E-03 -.6909627E-09 -.1108252E-03 0.0000000E+00 7 Al+++ 0.1303971E-01 0.5611137E-04 0.1298359E-01 0.0000000E+00 8 H4SiO4 0.4164072E-01 0.2534970E-02 0.3910575E-01 0.0000000E+00 9 Ca++ 0.4613892E-02 0.1440326E-07 0.4613877E-02 0.0000000E+00 10 Mg++ 0.3173810E-02 0.9500076E-10 0.3173809E-02 0.0000000E+00 11 Fe++ 0.2851321E-02 0.1200085E-07 0.2851309E-02 0.0000000E+00 12 K+ 0.8490446E-03 0.4033050E-04 0.8087141E-03 0.0000000E+00 13 Na+ 0.5179790E-02 0.4837603E-02 0.3421876E-03 0.0000000E+00 14 Mn++ 0.6933705E-04 0.7311994E-09 0.6933631E-04 0.0000000E+00 15 HPO4-- 0.2366439E-04 0.6642983E-05 0.1702141E-04 0.0000000E+00 Chg. balance for solid moles: 0.4486E-17 Mass of aqueous solution: 0.999650E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 3.9990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) apatite-OH 0.5674E-05 -5.246 0.2850E-02 -2.545 0.6588E-01 0.9056E-03 clinochlore 0.6348E-03 -3.197 0.3528 -0.452 8.155 0.1342 daphnite 0.3929E-03 -3.406 0.2804 -0.552 6.480 0.8496E-01 chlorite-Mn 0.1387E-04 -4.858 0.9831E-02 -2.007 0.2272 0.3133E-02 hematite 0.2829E-03 -3.548 0.4519E-01 -1.345 1.044 0.8564E-02 microcline 0.8087E-03 -3.092 0.2251 -0.648 5.203 0.8793E-01 paragonite 0.2893E-03 -3.539 0.1106 -0.956 2.555 0.3822E-01 stilbite 0.4586E-02 -2.339 3.231 0.509 74.69 1.507 nontronite-Na 0.1604E-03 -3.795 0.6820E-01 -1.166 1.576 0.2119E-01 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.6094E+00 0.6094E+00 1.0000 -0.215 daphnite 0.3773E+00 0.3773E+00 1.0000 -0.423 chlorite-Mn 0.1331E-01 0.1331E-01 1.0000 -1.876 hematite 0.1000E+01 0.1000E+01 1.0000 0.000 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 paragonite 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 nontronite-Na 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 4.326405 g Volume = 1.886325 cm3 Porosity: 27.4379% V(tot) - V(min): 0.71328E+00 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 3.9990000 g log = 0.6020 Original solution: 1000.0103000 g Original solution / Rock added: 250.07 (Water/Rock Ratio), log = 2.3981 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0203 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.1000E+01 0.9860 0.1006E+01 0.1020E+01 CO2,gas 0.4586E-06 1.0071 0.4712E-06 0.4679E-06 CH4,gas 0.4473E-16 1.0125 0.4621E-16 0.4563E-16 H2,gas 0.9751E-06 1.0005 0.9955E-06 0.9949E-06 H2S,gas 0.1493E-14 0.9960 0.1517E-14 0.1523E-14 S2,gas 0.8541E-37 1.0000 0.8714E-37 0.8714E-37 CO,gas 0.1225E-15 1.0000 0.1250E-15 0.1250E-15 SO3,gas 0.4220E-39 1.0000 0.4306E-39 0.4306E-39 SO2,gas 0.1634E-22 1.0000 0.1668E-22 0.1668E-22 HCl,gas 0.9962E-17 1.0000 0.1016E-16 0.1016E-16 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 32 apatite-OH -18.15 -18.15 0.00 0.000 0.60662E-11 46 clinochlore 39.07 39.07 0.00 0.000 0.12132E-10 47 daphnite 28.97 28.97 0.00 0.000 0.60662E-11 48 chlorite-Mn 46.87 46.87 0.00 0.000 0.00000E+00 90 hematite 12.57 12.57 0.00 0.000 -0.21232E-10 116 microcline -2.49 -2.49 0.00 0.000 0.15165E-11 121 paragonite 4.24 4.24 0.00 0.000 -0.10616E-10 163 stilbite -7.52 -7.52 0.00 0.000 -0.90992E-11 209 nontronite-Na 3.52 3.52 0.00 0.000 0.14407E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -14.69 -8.03 -2.675 0.13704E+05 -6.327 3 CH4,gas 4.54 -13.49 -18.03 -4.509 0.30793E+05 -16.335 4 H2,gas 8.00 0.30 -7.70 -4.401 0.13149E+05 -6.002 5 H2S,gas -6.23 -22.75 -16.52 -8.259 0.28204E+05 -14.819 6 S2,gas -7.34 -46.09 -38.76 -5.963 0.66180E+05 -37.060 7 CO,gas 3.21 -14.39 -17.60 -5.416 0.30055E+05 -15.903 8 SO3,gas 17.12 -23.94 -41.06 -10.266 0.70117E+05 -39.366 9 SO2,gas 0.83 -23.64 -24.48 -6.527 0.41794E+05 -22.778 10 HCl,gas 5.19 -13.50 -18.69 -9.346 0.31916E+05 -16.993 11 acmite 7.71 6.86 -0.85 -0.088 0.14516E+04 15 albite-high 0.69 -0.42 -1.11 -0.086 0.18980E+04 16 albite -0.38 -0.42 -0.03 -0.003 0.59218E+02 19 spessartine 24.46 20.37 -4.09 -0.204 0.69817E+04 20 analcite 3.32 2.91 -0.42 -0.046 0.71098E+03 21 andalusite 5.00 1.33 -3.67 -0.367 0.62623E+04 22 andradite 39.01 35.86 -3.15 -0.164 0.53792E+04 23 grossular 32.73 27.95 -4.78 -0.239 0.81639E+04 26 annite 20.12 16.81 -3.31 -0.184 0.56558E+04 27 phlogopite 27.06 23.50 -3.57 -0.198 0.60891E+04 29 anorthite 12.71 9.10 -3.61 -0.278 0.61679E+04 35 aragonite 0.97 -3.60 -4.56 -1.521 0.77934E+04 36 brucite 12.57 8.66 -3.91 -0.781 0.66710E+04 37 calcite 0.81 -3.60 -4.41 -1.470 0.75292E+04 38 carnegieite-low 9.02 6.23 -2.79 -0.399 0.47704E+04 39 carnegieite-high 10.09 6.23 -3.86 -0.552 0.65974E+04 40 carpholite-Mg 8.58 6.67 -1.91 -0.127 0.32621E+04 41 carpholite-Fe 6.71 4.44 -2.27 -0.151 0.38763E+04 42 celadonite 5.34 2.85 -2.49 -0.146 0.42524E+04 43 celadonite-Fe 3.88 0.62 -3.25 -0.191 0.55570E+04 44 chrysotile 23.89 19.34 -4.56 -0.380 0.77784E+04 50 chloritoid-Mg 13.20 10.00 -3.20 -0.213 0.54675E+04 51 chloritoid-Fe 9.17 7.77 -1.41 -0.094 0.24027E+04 52 chloritoid-Mn 11.40 9.89 -1.51 -0.100 0.25719E+04 54 coesite -2.38 -3.32 -0.95 -0.316 0.16186E+04 59 corundum 8.38 4.66 -3.73 -0.339 0.63606E+04 61 cristobalite -2.56 -3.32 -0.76 -0.255 0.13040E+04 63 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71234E+04 65 diaspore 2.87 2.33 -0.54 -0.091 0.93007E+03 67 diopside 16.18 13.10 -3.08 -0.308 0.52585E+04 68 hedenbergite 14.21 10.87 -3.34 -0.334 0.56957E+04 75 epidote 24.67 23.15 -1.52 -0.074 0.26034E+04 76 clinozoisite 22.81 19.19 -3.61 -0.164 0.61724E+04 77 epidote-Fe 29.84 27.10 -2.74 -0.142 0.46811E+04 78 fayalite 14.05 9.54 -4.50 -0.644 0.76917E+04 79 ferrosilite 11.15 6.22 -4.93 -0.493 0.84221E+04 83 gibbsite 4.08 2.33 -1.75 -0.250 0.29886E+04 84 glaucophane 22.97 18.50 -4.48 -0.121 0.76410E+04 87 greenalite 16.14 12.65 -3.49 -0.291 0.59591E+04 91 heulandite -5.83 -7.52 -1.69 -0.077 0.28938E+04 95 jadeite 4.22 2.91 -1.31 -0.131 0.22365E+04 97 kalsilite 7.58 4.16 -3.42 -0.489 0.58436E+04 98 kaolinite -1.33 -1.99 -0.66 -0.060 0.11223E+04 99 kyanite 4.88 1.33 -3.54 -0.354 0.60482E+04 101 laumontite 2.88 2.45 -0.43 -0.029 0.74005E+03 102 lawsonite 9.62 9.10 -0.52 -0.035 0.88455E+03 103 leucite 4.12 0.84 -3.28 -0.328 0.56028E+04 105 lizardite 23.24 19.34 -3.91 -0.326 0.66710E+04 107 magnetite 20.09 19.00 -1.09 -0.089 0.18589E+04 108 minnesotaite 10.39 6.00 -4.39 -0.258 0.74901E+04 110 magnesioferrite 26.21 21.23 -4.98 -0.407 0.85110E+04 113 margarite 17.32 13.76 -3.57 -0.143 0.60916E+04 120 muscovite 2.58 2.17 -0.41 -0.024 0.70168E+03 122 nepheline 8.34 6.23 -2.11 -0.301 0.36027E+04 134 phlogopite-Na 29.65 25.57 -4.08 -0.227 0.69672E+04 136 prehnite 19.37 16.86 -2.51 -0.148 0.42854E+04 137 prehnite-Fe 22.50 20.82 -1.68 -0.101 0.28714E+04 138 pumpellyite-Fe 46.27 42.49 -3.78 -0.084 0.64606E+04 139 pumpellyite-Mg 48.99 44.71 -4.28 -0.095 0.73081E+04 145 pyroxmangite 7.40 5.24 -2.16 -0.432 0.36913E+04 146 pyrophyllite -6.18 -8.64 -2.46 -0.154 0.42043E+04 147 quartz -2.99 -3.32 -0.33 -0.112 0.57129E+03 152 rhodonite 7.45 5.24 -2.21 -0.442 0.37716E+04 153 sanidine -1.28 -2.49 -1.21 -0.093 0.20677E+04 156 sillimanite 5.26 1.33 -3.93 -0.393 0.67062E+04 164 stilpnomelane-Fe 13.02 12.81 -0.21 -0.006 0.35913E+03 165 stilpnomelane-Mg 27.44 23.95 -3.49 -0.104 0.59575E+04 168 sudoite 21.08 16.67 -4.41 -0.142 0.75302E+04 171 talc 16.49 12.69 -3.80 -0.224 0.64922E+04 174 tephroite 18.09 13.80 -4.29 -0.613 0.73219E+04 177 topaz-H 4.62 1.33 -3.28 -0.299 0.56082E+04 178 tridymite -2.63 -3.32 -0.70 -0.233 0.11913E+04 187 wairakite 3.95 2.45 -1.50 -0.088 0.25620E+04 188 walstromite 11.51 7.76 -3.75 -0.749 0.63948E+04 189 wollastonite 10.46 7.76 -2.70 -0.539 0.46052E+04 190 pseudo-wollastonite 11.00 7.76 -3.24 -0.647 0.55250E+04 191 zoisite 22.85 19.19 -3.66 -0.166 0.62465E+04 192 akaganeite 7.75 6.28 -1.47 -0.318 0.25125E+04 193 beidellite-Ca -1.65 -4.94 -3.30 -0.204 0.56303E+04 194 beidellite-H -2.33 -6.77 -4.45 -0.284 0.75920E+04 195 beidellite-K -1.52 -5.07 -3.55 -0.217 0.60627E+04 196 beidellite-Mg -1.79 -5.34 -3.55 -0.220 0.60677E+04 197 beidellite-Na -1.34 -4.39 -3.05 -0.187 0.52014E+04 199 chalcedony -2.80 -3.32 -0.52 -0.174 0.89059E+03 201 montmorillonite-Ca -2.29 -4.72 -2.43 -0.150 0.41458E+04 202 montmorillonite-K -2.24 -4.85 -2.61 -0.160 0.44564E+04 203 montmorillonite-Mg -2.48 -5.12 -2.64 -0.163 0.45065E+04 204 montmorillonite-Na -2.04 -4.16 -2.13 -0.130 0.36308E+04 205 nontronite-Ca 3.21 2.97 -0.25 -0.016 0.42584E+03 206 nontronite-H 2.53 1.14 -1.40 -0.094 0.23855E+04 207 nontronite-K 3.34 2.84 -0.50 -0.032 0.85958E+03 208 nontronite-Mg 3.07 2.56 -0.51 -0.033 0.87054E+03 224 tobermorite 9.82 5.91 -3.91 -1.067 0.66774E+04 233 boehmite 4.41 2.33 -2.08 -0.346 0.35470E+04 235 ferrous-oxide 9.81 6.43 -3.38 -0.845 0.57697E+04 240 silica-amorphous -2.09 -3.32 -1.23 -0.411 0.21048E+04 242 an20ab80 2.02 1.48 -0.53 -0.041 0.91010E+03 243 an25ab75 2.65 1.96 -0.69 -0.053 0.11698E+04 244 an30ab70 3.28 2.44 -0.84 -0.065 0.14391E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 0.1000000 g Current total amount of reactant added: 3.9990000 g New total amount of reactant added: 4.0990000 g Mixing fraction reached given limit of 0.4000E+01 TOTMIX = 0.4099E+01 Execution stopped.