File SKIP_SPECIES.TXT lists species and minerals omitted from the calculations due to given T, P, option switches, or suppression in CHIMRUN, or are suppressed in the SOLTHERM database. It also lists minerals for which density is not specified in SOLTHERM. This is an extended P(to 5 kB), T(to 600 C) run (CON_FLAG = 1). methanol,aq is suppressed in SOLTHERM data file. methanol,aq is suppressed in SOLTHERM data file. CuCl4-3 is suppressed in SOLTHERM data file. H2BO3- is suppressed in SOLTHERM data file. UO2CO3,aq is suppressed in SOLTHERM data file. UO2SO4,aq is suppressed in SOLTHERM data file. UO2Cl2,aq is suppressed in SOLTHERM data file. UO2F2,aq is suppressed in SOLTHERM data file. PO4-3 is suppressed in SOLTHERM data file. H2PO4- is suppressed in SOLTHERM data file. H3PO4 is suppressed in SOLTHERM data file. O2,gas is suppressed in THIS RUN. O2,gas is suppressed in THIS RUN. amesite is suppressed in SOLTHERM data file. antigorite is suppressed in SOLTHERM data file. goethite is suppressed in THIS RUN. goethite is suppressed in THIS RUN. riebeckite is suppressed in THIS RUN. riebeckite is suppressed in THIS RUN. sapphirine-Fe(221) is suppressed in SOLTHERM data file. sapphirine(221) is suppressed in SOLTHERM data file. talc-prl is suppressed in SOLTHERM data file. PrO1.833(s) is suppressed in SOLTHERM data file. niter-NH4 is suppressed in SOLTHERM data file. FMQ_HS-1 is suppressed in THIS RUN. kf-ab-equil is suppressed in THIS RUN. ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Species No. Charge Tot.moles Trial molality Gamma Mixing solution H+ 1 1. -0.13244E+00 0.15408E-09 0.8827 0.00000000E+00 H2O 2 0. 0.55408E+02 0.10000E+01 1.0000 0.00000000E+00 Cl- 3 -1. 0.13797E-03 0.13788E-03 0.8802 0.00000000E+00 SO4-- 4 -2. 0.24718E-03 0.25523E-04 0.6370 0.00000000E+00 HCO3- 5 -1. 0.13070E-04 0.69271E-05 0.8808 0.00000000E+00 HS- 6 -1. -0.22168E-03 0.35318E-12 0.8802 0.00000000E+00 Al+++ 7 3. 0.26083E-01 0.10498E-26 0.3683 0.00000000E+00 H4SiO4 8 0. 0.83292E-01 0.37357E-03 1.0000 0.00000000E+00 Ca++ 9 2. 0.92145E-02 0.36514E-07 0.6348 0.00000000E+00 Mg++ 10 2. 0.63484E-02 0.17626E-10 0.6334 0.00000000E+00 Fe++ 11 2. 0.57034E-02 0.10394E-12 0.6337 0.00000000E+00 K+ 12 1. 0.16983E-02 0.62855E-04 0.8809 0.00000000E+00 Na+ 13 1. 0.10201E-01 0.79680E-02 0.8801 0.00000000E+00 Mn++ 14 2. 0.13869E-03 0.13963E-10 0.6340 0.00000000E+00 HPO4-- 15 -2. 0.47335E-04 0.51798E-06 0.6370 0.00000000E+00 Chg. balance for total moles = 0.6642E-13 Max. difference allowed = 0.1380E-07 The following parameters were given: ERPC = 0.1000E-11 pH = 0.0000 PFLUID = 50.0000 SLIM = 0.200000E+02 TEMP = 100.0000 SINC = 0.4000E+00 TEMPC = 0.0000 TOTMIX = 0.799900E+01 ENTH = 0.0000 SENTH = 0.0000 DENTH = 0.0000 TOTWAT = 90.0000 SOLMIN = 0.0000E+00 RM = 0.0000 AQGRM = 1000.0103 SUPRNT = 0.1000E-19 VBOX-1 = 4.1996 RHOFRS = 0.0000 RHOROC = 2.5000 The following options were selected: CONFLG = 1 C = 3 IFRAC = 0 IPUNCH = 2 NLOOP = 400 ISTEP = 2 LIMSOL = 1 LOOC = 0 IENTH = 0 ITREF = 0 IDEAL = 0 IPSAT = 1 INCREM = 0 INCP = 0 MINSOL = 1 NEUT = 0 AWAT = 0 CHGF = 0 Of the derived species, only those with molality > 0.10E-19 will appear in the output Species No. Charge Log K(diss) Species No. Charge Log K(diss) HSiO3- 16 -1. 9.0298 MnO2-2 65 -2. 40.4638 Ca(HSiO3)+ 17 1. 7.6723 HMnO2- 66 -1. 29.1232 Mg(HSiO3)+ 18 1. 7.5773 MnO4- 67 -1. 83.3111 NaHSiO3,aq 19 0. 7.8210 MnO4-2 68 -2. 81.3005 AlO+ 20 1. 6.8663 MnCl+ 69 1. -0.7894 AlOH+2 21 2. 3.1691 MnSO4,aq 70 0. -2.4604 HAlO2,aq 22 0. 10.5671 NaCl,aq 71 0. 0.4796 AlO2- 23 -1. 16.2221 NaOH,aq 72 0. 12.3669 CH4,aq 24 0. 6.0126 O2,aq 73 0. 53.5502 C2H6,aq 25 0. 12.3733 OH- 74 -1. 12.2382 C3H8,aq 26 0. 17.3707 HO2- 75 -1. 50.8010 C4H10,aq 27 0. 22.3757 H2O2,aq 76 0. 40.0166 ethanol,aq 28 0. 15.3258 H3PO2,aq 77 0. 24.3066 CO,aq 29 0. 4.6892 H2PO2- 78 -1. 26.5366 CO2,aq 30 0. -6.3298 HPO3-2 79 -2. 11.9254 CO3-2 31 -2. 10.0588 H3PO3,aq 80 0. 3.5792 CaCO3,aq 32 0. 5.9605 H2PO3- 81 -1. 5.6232 Ca(HCO3)+ 33 1. -1.4070 H3PO4,aq 82 0. -9.8447 CaCl+ 34 1. -0.2091 H2PO4- 83 -1. -7.2659 CaCl2,aq 35 0. 0.4151 PO4-3 84 -3. 12.0884 CaOH+ 36 1. 10.1471 H4P2O7,aq 85 0. -17.8095 CaSO4,aq 37 0. -2.5018 H3P2O7- 86 -1. -15.9156 HCl,aq 38 0. 0.7370 H2P2O7-2 87 -2. -13.4262 HClO,aq 39 0. 32.4260 HP2O7-3 88 -3. -6.7266 ClO- 40 -1. 39.6530 P2O7-4 89 -4. 2.8952 HClO2,aq 41 0. 70.1812 H2S,aq 90 0. -6.4900 Fe+3 42 3. 8.3809 S2-2 91 -2. 1.2355 FeCl+ 43 1. -0.1994 S3-2 92 -2. -8.8031 FeCl2,aq 44 0. 4.3001 S3- 93 -1. -16.3389 FeCl+2 45 2. 6.5269 S4-2 94 -2. -18.6615 FeO,aq 46 0. 16.4104 S5-2 95 -2. -28.3439 FeOH+ 47 1. 7.4874 SO2,aq 96 0. -0.2309 HFeO2- 48 -1. 24.3908 SO3-2 97 -2. 10.3052 FeO+ 49 1. 11.4004 HSO3- 98 -1. 2.5086 FeOH+2 50 2. 9.1194 HSO4- 99 -1. -2.9839 FeO2- 51 -1. 24.0895 HSO5- 100 -1. 38.8366 HFeO2,aq 52 0. 15.9850 S2O3-2 101 -2. -4.5600 H2,aq 53 0. 9.4190 HS2O3- 102 -1. -6.8123 KCl,aq 54 0. 1.7417 H2S2O3,aq 103 0. -8.0173 KHSO4,aq 55 0. -0.4514 S2O4-2 104 -2. 10.5541 KOH,aq 56 0. 12.3695 HS2O4- 105 -1. 7.6551 KSO4- 57 -1. -1.1908 H2S2O4,aq 106 0. 6.6259 MgCO3,aq 58 0. 6.5614 S2O5-2 107 -2. 10.0741 Mg(HCO3)+ 59 1. -1.4164 S2O6-2 108 -2. 11.5521 MgCl+ 60 1. -0.1664 S2O8-2 109 -2. 42.0620 MgOH+ 61 1. 9.4041 S3O6-2 110 -2. 3.7866 Mn+3 62 3. 19.1453 S4O6-2 111 -2. -17.8657 MnO,aq 63 0. 17.9848 S5O6-2 112 -2. -14.1333 MnOH+ 64 1. 8.5194 113 0. 10.3111 For mixed gases (JSOLS=6), log K(hydrol) = log (K*P) Log K Trial Log K Trial Mineral No. hydrol Moles Mineral No. hydrol Moles H2O,gas 1 1.696 0.0000E+00 osumilite(2) 124 20.667 0.0000E+00 CO2,gas 2 -6.660 0.0000E+00 osumilite-Fe 125 14.390 0.0000E+00 CH4,gas 3 4.544 0.0000E+00 pargasite 126 65.092 0.0000E+00 H2,gas 4 8.000 0.0000E+00 periclase 127 16.138 0.0000E+00 H2S,gas 5 -6.230 0.0000E+00 periclase-Fe 128 11.627 0.0000E+00 S2,gas 6 -7.335 0.0000E+00 perovskite-Al 129 12.344 0.0000E+00 CO,gas 7 3.215 0.0000E+00 perovskite-Ca 130 23.807 0.0000E+00 SO3,gas 8 17.121 0.0000E+00 perovskite-Fe 131 21.143 0.0000E+00 SO2,gas 9 0.832 0.0000E+00 perovskite-Mg 132 23.119 0.0000E+00 HCl,gas 10 5.189 0.0000E+00 phase_A 133 80.189 0.0000E+00 acmite 11 7.710 0.0000E+00 phlogopite-Na 134 29.647 0.0000E+00 akermanite 12 36.442 0.0000E+00 piemontite(ordered) 135 33.776 0.0000E+00 akimotoite 13 16.591 0.0000E+00 prehnite 136 19.372 0.0000E+00 akimotoite-Fe 14 13.067 0.0000E+00 prehnite-Fe 137 22.498 0.0000E+00 albite-high 15 0.693 0.0000E+00 pumpellyite-Fe 138 46.269 0.0000E+00 albite 16 -0.384 0.1931E-02 pumpellyite-Mg 139 48.995 0.0000E+00 almandine 17 24.442 0.0000E+00 px-Mg-tschermaks 140 19.616 0.0000E+00 pyrope 18 37.248 0.0000E+00 px-Ca-tschermaks 141 18.610 0.0000E+00 spessartine 19 24.457 0.0000E+00 pyrite 142 -21.247 0.0000E+00 analcite 20 3.322 0.0000E+00 pyrrhotite 143 -4.260 0.0000E+00 andalusite 21 5.002 0.0000E+00 pyrrhotiteFe0.875 144 -6.017 0.0000E+00 andradite 22 39.009 0.0000E+00 pyroxmangite 145 7.399 0.0000E+00 grossular 23 32.731 0.0000E+00 pyrophyllite 146 -6.176 0.0000E+00 anhydrite 24 -5.317 0.0000E+00 quartz 147 -2.989 0.0000E+00 ankerite 25 -2.135 0.0000E+00 rankinite 148 40.713 0.0000E+00 annite 26 20.123 0.0000E+00 ringwoodite-Fe 149 15.456 0.0000E+00 phlogopite 27 27.065 0.0000E+00 ringwoodite-Mg 150 27.575 0.0000E+00 biotite-Mn 28 32.960 0.0000E+00 rhodochrosite 151 -0.976 0.0000E+00 anorthite 29 12.710 0.0000E+00 rhodonite 152 7.446 0.0000E+00 anthophyllite 30 51.852 0.0000E+00 sanidine 153 -1.275 0.0000E+00 anthophyllite-Fe 31 29.306 0.0000E+00 sapphirine(351) 154 78.899 0.0000E+00 apatite-OH 32 -18.153 0.1560E-04 siderite 155 -2.608 0.0000E+00 apatite-OH-zs 33 -12.736 0.0000E+00 sillimanite 156 5.262 0.0000E+00 apatite-Cl-zs 34 -16.674 0.0000E+00 sodalite 157 49.976 0.0000E+00 aragonite 35 0.967 0.0000E+00 spinel 158 20.870 0.0000E+00 brucite 36 12.569 0.0000E+00 spurrite 159 59.482 0.0000E+00 calcite 37 0.812 0.0000E+00 staurolite-Fe 160 73.598 0.0000E+00 carnegieite-low 38 9.023 0.0000E+00 staurolite-Mg 161 89.802 0.0000E+00 carnegieite-high 39 10.093 0.0000E+00 staurolite-Mn 162 83.909 0.0000E+00 carpholite-Mg 40 8.582 0.0000E+00 stilbite 163 -7.522 0.8899E-02 carpholite-Fe 41 6.713 0.0000E+00 stilpnomelane-Fe 164 13.017 0.0000E+00 celadonite 42 5.342 0.0000E+00 stilpnomelane-Mg 165 27.441 0.0000E+00 celadonite-Fe 43 3.877 0.0000E+00 stishovite 166 2.720 0.0000E+00 chrysotile 44 23.892 0.0000E+00 sudoite-Fe 167 18.296 0.0000E+00 chondrodite 45 56.475 0.0000E+00 sudoite 168 21.077 0.0000E+00 clinochlore 46 39.070 0.1270E-02 sulfur 169 -9.152 0.0000E+00 daphnite 47 28.965 0.7860E-03 sylvite 170 1.338 0.0000E+00 chlorite-Mn 48 46.869 0.2774E-04 talc 171 16.491 0.0000E+00 chlorite-Al-free 49 47.173 0.0000E+00 talc-Fe 172 13.448 0.0000E+00 chloritoid-Mg 50 13.198 0.0000E+00 talc-tschermaks 173 19.091 0.0000E+00 chloritoid-Fe 51 9.174 0.0000E+00 tephroite 174 18.086 0.0000E+00 chloritoid-Mn 52 11.401 0.0000E+00 tilleyite 175 41.377 0.0000E+00 clinohumite 53 97.128 0.0000E+00 titanite-CaSi 176 15.479 0.0000E+00 coesite 54 -2.376 0.0000E+00 topaz-H 177 4.618 0.0000E+00 cordierite-H 55 23.715 0.0000E+00 tridymite 178 -2.626 0.0000E+00 cordierite 56 24.049 0.0000E+00 tremolite 179 47.869 0.0000E+00 cordierite-Fe 57 20.450 0.0000E+00 ferroactinolite 180 38.452 0.0000E+00 cordierite-Mn 58 25.066 0.0000E+00 troilite-low 181 -4.411 0.0000E+00 corundum 59 8.383 0.0000E+00 tschermakite 182 48.210 0.0000E+00 corundum-MgSi 60 18.891 0.0000E+00 vesuvianite 183 223.471 0.0000E+00 cristobalite 61 -2.560 0.0000E+00 wadeite-Si 184 20.216 0.0000E+00 cummingtonite 62 52.099 0.0000E+00 wadsleyite-Fe 185 15.680 0.0000E+00 cymrite-K 63 1.685 0.0000E+00 wadsleyite-Mg 186 25.850 0.0000E+00 deerite 64 95.671 0.0000E+00 wairakite 187 3.950 0.0000E+00 diaspore 65 2.874 0.0000E+00 walstromite 188 11.509 0.0000E+00 diamond 66 -3.102 0.0000E+00 wollastonite 189 10.461 0.0000E+00 diopside 67 16.181 0.0000E+00 pseudo-wollastonite 190 11.000 0.0000E+00 hedenbergite 68 14.208 0.0000E+00 zoisite 191 22.849 0.0000E+00 dolomite,ordered 69 0.546 0.0000E+00 akaganeite 192 7.755 0.0000E+00 eastonite 70 28.489 0.0000E+00 beidellite-Ca 193 -1.646 0.0000E+00 enstatite 71 17.265 0.0000E+00 beidellite-H 194 -2.326 0.0000E+00 clinoenstatite-HiP 72 18.354 0.0000E+00 beidellite-K 195 -1.520 0.0000E+00 clinoenstatite 73 17.166 0.0000E+00 beidellite-Mg 196 -1.790 0.0000E+00 protoenstatite 74 17.824 0.0000E+00 beidellite-Na 197 -1.342 0.0000E+00 epidote 75 24.670 0.0000E+00 calcium 198 84.026 0.0000E+00 clinozoisite 76 22.806 0.0000E+00 chalcedony 199 -2.802 0.0000E+00 epidote-Fe 77 29.841 0.0000E+00 dawsonite 200 1.682 0.0000E+00 fayalite 78 14.046 0.0000E+00 montmorillonite-Ca 201 -2.291 0.0000E+00 ferrosilite 79 11.149 0.0000E+00 montmorillonite-K 202 -2.237 0.0000E+00 forsterite 80 21.016 0.0000E+00 montmorillonite-Mg 203 -2.480 0.0000E+00 gedrite 81 50.522 0.0000E+00 montmorillonite-Na 204 -2.038 0.0000E+00 gehlenite 82 36.628 0.0000E+00 nontronite-Ca 205 3.215 0.0000E+00 gibbsite 83 4.079 0.0000E+00 nontronite-H 206 2.533 0.0000E+00 glaucophane 84 22.975 0.0000E+00 nontronite-K 207 3.341 0.0000E+00 glaucophane-Fe 85 17.276 0.0000E+00 nontronite-Mg 208 3.075 0.0000E+00 graphite 86 -3.546 0.0000E+00 nontronite-Na 209 3.520 0.0000E+00 greenalite 87 16.140 0.0000E+00 sepiolite 210 24.118 0.0000E+00 grunerite 88 31.215 0.0000E+00 alite 211 57.999 0.0000E+00 halite 89 1.575 0.0000E+00 belite 212 30.433 0.0000E+00 hematite 90 12.566 0.8867E-03 ettringite 213 43.232 0.0000E+00 heulandite 91 -5.827 0.0000E+00 gypsum 214 -4.955 0.0000E+00 hercynite 92 17.279 0.0000E+00 hemicarboaluminate 215 70.954 0.0000E+00 hollandite 93 25.673 0.0000E+00 hydrogarnet 216 60.662 0.0000E+00 iron 94 19.086 0.0000E+00 hydrogarnet-Si 217 50.586 0.0000E+00 jadeite 95 4.215 0.0000E+00 jennite 218 24.367 0.0000E+00 julgoldite 96 70.427 0.0000E+00 monosulfoaluminate 219 53.400 0.0000E+00 kalsilite 97 7.584 0.0000E+00 monocarboaluminate 220 61.898 0.0000E+00 kaolinite 98 -1.333 0.0000E+00 portlandite 221 18.272 0.0000E+00 kyanite 99 4.876 0.0000E+00 stratlingite 222 36.502 0.0000E+00 larnite-bredigite 100 30.686 0.0000E+00 tricarboaluminate 223 70.370 0.0000E+00 laumontite 101 2.883 0.0000E+00 tobermorite 224 9.823 0.0000E+00 lawsonite 102 9.616 0.2370E-03 C4AH13 225 81.816 0.0000E+00 leucite 103 4.119 0.0000E+00 C2AH8 226 45.203 0.0000E+00 lime 104 25.998 0.0000E+00 C3A 227 86.953 0.0000E+00 lizardite 105 23.244 0.0000E+00 C4AF 228 117.416 0.0000E+00 magnesite 106 0.691 0.0000E+00 CAH10 229 28.335 0.0000E+00 magnetite 107 20.087 0.0000E+00 alabandite 230 -0.978 0.0000E+00 minnesotaite 108 10.388 0.0000E+00 alunite 231 -10.435 0.0000E+00 minnesotaite-Mg 109 20.602 0.0000E+00 artinite 232 15.121 0.0000E+00 magnesioferrite 110 26.212 0.0000E+00 boehmite 233 4.406 0.0000E+00 majorite 111 53.251 0.0000E+00 dolomite,disordered 234 1.247 0.0000E+00 manganosite 112 14.058 0.0000E+00 ferrous-oxide 235 9.812 0.0000E+00 margarite 113 17.324 0.0000E+00 huntite 236 3.770 0.0000E+00 meionite 114 44.874 0.0000E+00 hydromagnesite 237 19.995 0.0000E+00 merwinite 115 55.930 0.0000E+00 nesquehonite 238 4.723 0.0000E+00 microcline 116 -2.486 0.1635E-02 potassium-oxide 239 69.038 0.0000E+00 monticellite 117 24.339 0.0000E+00 silica-amorphous 240 -2.091 0.0000E+00 mullite-Al 118 363.148 0.0000E+00 sodium-oxide 241 55.169 0.0000E+00 mullite-Si 119 7.264 0.0000E+00 an20ab80 242 2.018 0.0000E+00 muscovite 120 2.582 0.0000E+00 an25ab75 243 2.646 0.0000E+00 paragonite 121 4.239 0.0000E+00 an30ab70 244 3.279 0.0000E+00 nepheline 122 8.339 0.0000E+00 tr.625ac.25prg.125 245 45.165 0.0000E+00 osumilite(1) 123 21.717 0.0000E+00 246 0.000 0.0000E+00 Initial composition of reactant (wt%): SiO2 62.56 MgO 3.200 Al2O3 16.62 CaO 6.450 FeO 3.530 Na2O 3.890 Fe2O3 1.770 K2O 1.000 MnO 0.1230 P2O5 0.4200E-01 Sum of wt% of reactants: 99.1850 Reactant consumed: 7.9990000 g log = 0.9030 Original solution: 1000.0103000 g Original solution / Rock added: 125.02 (Water/Rock Ratio), log = 2.0970 The following minerals and/or gases with identical index are in solid solution: H2O,gas 6 CO2,gas 6 CH4,gas 6 H2,gas 6 H2S,gas 6 S2,gas 6 CO,gas 6 SO3,gas 6 SO2,gas 6 HCl,gas 6 almandine 16 pyrope 16 spessartine 16 andradite 8 grossular 8 annite 15 phlogopite 15 biotite-Mn 15 clinochlore 1 daphnite 1 chlorite-Mn 1 diopside 5 hedenbergite 5 epidote 3 clinozoisite 3 greenalite 18 iron 9 lizardite 18 magnetite 14 talc 7 talc-Fe 7 tremolite 2 ferroactinolite 2 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 9 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 7.9990000 Water: Moles liquid = 0.5543E+02 kg liquid = 0.9986E+00 Moles total = 0.5541E+02 kg total = 0.9982E+00 Activity = 1.0000 Stoichiometric ionic strength = .4646764E-02 Osmotic coef. = 0.9635 True ionic strength = .8063170E-02 Chg. balance for total moles = 0.6642E-13 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.15408E-09 -9.8123 0.13601E-09 -9.8664 0.88269E+00 -0.0542 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13788E-03 -3.8605 0.12136E-03 -3.9159 0.88017E+00 -0.0554 4 SO4-- 0.25523E-04 -4.5931 0.16257E-04 -4.7890 0.63695E+00 -0.1959 5 HCO3- 0.69271E-05 -5.1595 0.61012E-05 -5.2146 0.88078E+00 -0.0551 6 HS- 0.35318E-12 -12.4520 0.31088E-12 -12.5074 0.88023E+00 -0.0554 7 Al+++ 0.10498E-26 -26.9789 0.38667E-27 -27.4127 0.36833E+00 -0.4338 8 H4SiO4 0.37357E-03 -3.4276 0.37357E-03 -3.4276 0.10000E+01 0.0000 9 Ca++ 0.36514E-07 -7.4375 0.23178E-07 -7.6349 0.63476E+00 -0.1974 10 Mg++ 0.17626E-10 -10.7538 0.11165E-10 -10.9522 0.63339E+00 -0.1983 11 Fe++ 0.10394E-12 -12.9832 0.65872E-13 -13.1813 0.63372E+00 -0.1981 12 K+ 0.62855E-04 -4.2017 0.55368E-04 -4.2567 0.88088E+00 -0.0551 13 Na+ 0.79680E-02 -2.0987 0.70127E-02 -2.1541 0.88011E+00 -0.0555 14 Mn++ 0.13963E-10 -10.8550 0.88519E-11 -11.0530 0.63397E+00 -0.1979 15 HPO4-- 0.51798E-06 -6.2857 0.32995E-06 -6.4815 0.63699E+00 -0.1959 16 HSiO3- 0.29139E-02 -2.5355 0.25648E-02 -2.5910 0.88017E+00 -0.0554 17 Ca(HSiO3)+ 0.15367E-08 -8.8134 0.13538E-08 -8.8684 0.88097E+00 -0.0550 18 Mg(HSiO3)+ 0.92121E-12 -12.0356 0.81156E-12 -12.0907 0.88097E+00 -0.0550 19 NaHSiO3,aq 0.29090E-03 -3.5363 0.29090E-03 -3.5363 0.10000E+01 0.0000 20 AlO+ 0.32281E-14 -14.4911 0.28439E-14 -14.5461 0.88097E+00 -0.0550 22 HAlO2,aq 0.41642E-08 -8.3805 0.41642E-08 -8.3805 0.10000E+01 0.0000 23 AlO2- 0.77068E-04 -4.1131 0.67775E-04 -4.1689 0.87942E+00 -0.0558 24 CH4,aq 0.11350E-18 -18.9450 0.11333E-18 -18.9456 0.99857E+00 -0.0006 29 CO,aq 0.58444E-19 -19.2333 0.58444E-19 -19.2333 0.10000E+01 0.0000 30 CO2,aq 0.17756E-08 -8.7506 0.17731E-08 -8.7513 0.99857E+00 -0.0006 31 CO3-2 0.61579E-05 -5.2106 0.39183E-05 -5.4069 0.63631E+00 -0.1963 32 CaCO3,aq 0.11388E-08 -8.9436 0.11388E-08 -8.9436 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.40974E-11 -11.3875 0.36097E-11 -11.4425 0.88097E+00 -0.0550 34 CaCl+ 0.51671E-11 -11.2868 0.45521E-11 -11.3418 0.88097E+00 -0.0550 35 CaCl2,aq 0.13125E-15 -15.8819 0.13125E-15 -15.8819 0.10000E+01 0.0000 36 CaOH+ 0.13787E-07 -7.8605 0.12146E-07 -7.9156 0.88097E+00 -0.0550 37 CaSO4,aq 0.11965E-09 -9.9221 0.11965E-09 -9.9221 0.10000E+01 0.0000 38 HCl,aq 0.30246E-14 -14.5193 0.30246E-14 -14.5193 0.10000E+01 0.0000 43 FeCl+ 0.14363E-16 -16.8428 0.12653E-16 -16.8978 0.88097E+00 -0.0550 46 FeO,aq 0.13841E-09 -9.8588 0.13841E-09 -9.8588 0.10000E+01 0.0000 47 FeOH+ 0.17896E-10 -10.7473 0.15766E-10 -10.8023 0.88097E+00 -0.0550 48 HFeO2- 0.12097E-07 -7.9173 0.10648E-07 -7.9727 0.88017E+00 -0.0554 49 FeO+ 0.11784E-14 -14.9287 0.10381E-14 -14.9838 0.88097E+00 -0.0550 51 FeO2- 0.13047E-07 -7.8845 0.11484E-07 -7.9399 0.88017E+00 -0.0554 52 HFeO2,aq 0.19864E-09 -9.7019 0.19864E-09 -9.7019 0.10000E+01 0.0000 53 H2,aq 0.13140E-08 -8.8814 0.13121E-08 -8.8820 0.99857E+00 -0.0006 54 KCl,aq 0.12178E-09 -9.9144 0.12178E-09 -9.9144 0.10000E+01 0.0000 55 KHSO4,aq 0.34613E-18 -18.4608 0.34613E-18 -18.4608 0.10000E+01 0.0000 56 KOH,aq 0.17385E-06 -6.7598 0.17385E-06 -6.7598 0.10000E+01 0.0000 57 KSO4- 0.15869E-07 -7.7994 0.13968E-07 -7.8549 0.88017E+00 -0.0554 58 MgCO3,aq 0.13749E-12 -12.8617 0.13749E-12 -12.8617 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.20167E-14 -14.6954 0.17767E-14 -14.7504 0.88097E+00 -0.0550 60 MgCl+ 0.22558E-14 -14.6467 0.19873E-14 -14.7017 0.88097E+00 -0.0550 61 MgOH+ 0.36747E-10 -10.4348 0.32373E-10 -10.4898 0.88097E+00 -0.0550 63 MnO,aq 0.49558E-09 -9.3049 0.49558E-09 -9.3049 0.10000E+01 0.0000 64 MnOH+ 0.22340E-09 -9.6509 0.19681E-09 -9.7060 0.88097E+00 -0.0550 65 MnO2-2 0.13974E-11 -11.8547 0.88915E-12 -12.0510 0.63631E+00 -0.1963 66 HMnO2- 0.30100E-10 -10.5214 0.26494E-10 -10.5769 0.88017E+00 -0.0554 69 MnCl+ 0.75089E-14 -14.1244 0.66152E-14 -14.1795 0.88097E+00 -0.0550 70 MnSO4,aq 0.41545E-13 -13.3815 0.41545E-13 -13.3815 0.10000E+01 0.0000 71 NaCl,aq 0.28204E-06 -6.5497 0.28204E-06 -6.5497 0.10000E+01 0.0000 72 NaOH,aq 0.22153E-04 -4.6546 0.22153E-04 -4.6546 0.10000E+01 0.0000 74 OH- 0.48307E-02 -2.3160 0.42482E-02 -2.3718 0.87942E+00 -0.0558 79 HPO3-2 0.21204E-17 -17.6736 0.13492E-17 -17.8699 0.63631E+00 -0.1963 82 H3PO4,aq 0.42686E-16 -16.3697 0.42686E-16 -16.3697 0.10000E+01 0.0000 83 H2PO4- 0.94011E-09 -9.0268 0.82783E-09 -9.0821 0.88057E+00 -0.0552 84 PO4-3 0.52508E-08 -8.2798 0.19794E-08 -8.7035 0.37697E+00 -0.4237 87 H2P2O7-2 0.84447E-19 -19.0734 0.53734E-19 -19.2697 0.63631E+00 -0.1963 88 HP2O7-3 0.21411E-15 -15.6694 0.78890E-16 -16.1030 0.36846E+00 -0.4336 89 P2O7-4 0.79638E-15 -15.0989 0.13857E-15 -15.8583 0.17400E+00 -0.7594 90 H2S,aq 0.13086E-15 -15.8832 0.13068E-15 -15.8838 0.99857E+00 -0.0006 97 SO3-2 0.43269E-14 -14.3638 0.27721E-14 -14.5572 0.64066E+00 -0.1934 98 HSO3- 0.26819E-16 -16.5716 0.23606E-16 -16.6270 0.88017E+00 -0.0554 99 HSO4- 0.24176E-11 -11.6166 0.21308E-11 -11.6715 0.88137E+00 -0.0548 Charge balance for all species = 0.6650E-13 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.1540810E-09 -.8372347E-02 -.8434026E+01 0.0000 2 H2O 0.1000000E+01 0.5551005E+02 0.9994617E+06 0.0000 3 Cl- 0.1378809E-03 0.1381630E-03 0.4895509E+01 5.9505 4 SO4-- 0.2552339E-04 0.2554071E-04 0.2452086E+01 14.9439 5 HCO3- 0.6927060E-05 0.1308789E-04 0.7981323E+00 4.6519 6 HS- 0.3531815E-12 -.1326859E-08 -.4385693E-04 -2.6410 7 Al+++ 0.1049811E-26 0.7707242E-04 0.2078347E+01 2.1867 8 H4SiO4 0.3735728E-03 0.3578391E-02 0.3437429E+03 -3.4276 9 Ca++ 0.3651433E-07 0.5310547E-07 0.2127151E-02 12.0980 10 Mg++ 0.1762649E-10 0.5543674E-10 0.1347012E-05 8.7807 11 Fe++ 0.1039449E-12 0.2549958E-07 0.1423265E-02 6.5516 12 K+ 0.6285473E-04 0.6304458E-04 0.2463768E+01 5.6097 13 Na+ 0.7967974E-02 0.8281306E-02 0.1902773E+03 7.7123 14 Mn++ 0.1396261E-10 0.7644905E-09 0.4197570E-04 8.6799 15 HPO4-- 0.5179838E-06 0.5241747E-06 0.5028116E-01 13.2513 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.1324385E+00 -.8360904E-02 -.1240776E+00 0.0000000E+00 2 H2O 0.5540798E+02 0.5543418E+02 -.2619927E-01 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.2471840E-03 0.2550580E-04 0.2216782E-03 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.2216796E-03 -.1325045E-08 -.2216782E-03 0.0000000E+00 7 Al+++ 0.2608267E-01 0.7696708E-04 0.2600571E-01 0.0000000E+00 8 H4SiO4 0.8329185E-01 0.3573500E-02 0.7971835E-01 0.0000000E+00 9 Ca++ 0.9214462E-02 0.5303288E-07 0.9214409E-02 0.0000000E+00 10 Mg++ 0.6348413E-02 0.5536097E-10 0.6348413E-02 0.0000000E+00 11 Fe++ 0.5703356E-02 0.2546472E-07 0.5703330E-02 0.0000000E+00 12 K+ 0.1698301E-02 0.6295841E-04 0.1635343E-02 0.0000000E+00 13 Na+ 0.1020076E-01 0.8269987E-02 0.1930778E-02 0.0000000E+00 14 Mn++ 0.1386914E-03 0.7634456E-09 0.1386907E-03 0.0000000E+00 15 HPO4-- 0.4733470E-04 0.5234582E-06 0.4681124E-04 0.0000000E+00 Chg. balance for solid moles: 0.7576E-17 Mass of aqueous solution: 0.999201E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 7.9990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 0.1931E-02 -2.714 0.5063 -0.296 5.791 0.1944 apatite-OH 0.1560E-04 -4.807 0.7838E-02 -2.106 0.8965E-01 0.2491E-02 clinochlore 0.1270E-02 -2.896 0.7057 -0.151 8.072 0.2684 daphnite 0.7860E-03 -3.105 0.5608 -0.251 6.414 0.1699 chlorite-Mn 0.2774E-04 -4.557 0.1967E-01 -1.706 0.2249 0.6267E-02 hematite 0.8867E-03 -3.052 0.1416 -0.849 1.620 0.2684E-01 lawsonite 0.2370E-03 -3.625 0.7447E-01 -1.128 0.8518 0.2402E-01 microcline 0.1635E-02 -2.786 0.4552 -0.342 5.206 0.1778 stilbite 0.8899E-02 -2.051 6.272 0.797 71.73 2.925 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.6094E+00 0.6094E+00 1.0000 -0.215 daphnite 0.3773E+00 0.3773E+00 1.0000 -0.423 chlorite-Mn 0.1331E-01 0.1331E-01 1.0000 -1.876 hematite 0.1000E+01 0.1000E+01 1.0000 0.000 lawsonite 0.1000E+01 0.1000E+01 1.0000 0.000 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 8.743172 g Volume = 3.795331 cm3 Porosity: 9.6264% V(tot) - V(min): 0.40427E+00 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 7.9990000 g log = 0.9030 Original solution: 1000.0103000 g Original solution / Rock added: 125.02 (Water/Rock Ratio), log = 2.0970 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0203 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.1000E+01 0.9860 0.1006E+01 0.1020E+01 CO2,gas 0.1846E-06 1.0071 0.1897E-06 0.1884E-06 CH4,gas 0.1615E-15 1.0125 0.1668E-15 0.1648E-15 H2,gas 0.1688E-05 1.0005 0.1723E-05 0.1722E-05 H2S,gas 0.3535E-14 0.9960 0.3592E-14 0.3607E-14 S2,gas 0.1600E-36 1.0000 0.1632E-36 0.1632E-36 CO,gas 0.8536E-16 1.0000 0.8709E-16 0.8709E-16 SO3,gas 0.1114E-39 1.0000 0.1137E-39 0.1137E-39 SO2,gas 0.7469E-23 1.0000 0.7620E-23 0.7620E-23 HCl,gas 0.5231E-17 1.0000 0.5337E-17 0.5337E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 16 albite -0.38 -0.38 0.00 0.000 -0.94784E-12 32 apatite-OH -18.15 -18.15 0.00 0.000 -0.60662E-11 46 clinochlore 39.07 39.07 0.00 0.000 0.00000E+00 47 daphnite 28.97 28.97 0.00 0.000 0.18198E-10 48 chlorite-Mn 46.87 46.87 0.00 0.000 0.12132E-10 90 hematite 12.57 12.57 0.00 0.000 0.30331E-11 102 lawsonite 9.62 9.62 0.00 0.000 0.12132E-10 116 microcline -2.49 -2.49 0.00 0.000 -0.10616E-10 163 stilbite -7.52 -7.52 0.00 0.000 -0.90992E-11 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -15.08 -8.42 -2.807 0.14378E+05 -6.722 3 CH4,gas 4.54 -12.93 -17.48 -4.369 0.29841E+05 -15.778 4 H2,gas 8.00 0.54 -7.46 -4.264 0.12742E+05 -5.764 5 H2S,gas -6.23 -22.37 -16.14 -8.072 0.27565E+05 -14.445 6 S2,gas -7.34 -45.82 -38.49 -5.921 0.65714E+05 -36.787 7 CO,gas 3.21 -14.54 -17.76 -5.464 0.30323E+05 -16.060 8 SO3,gas 17.12 -24.52 -41.64 -10.411 0.71105E+05 -39.944 9 SO2,gas 0.83 -23.98 -24.82 -6.618 0.42374E+05 -23.118 10 HCl,gas 5.19 -13.78 -18.97 -9.486 0.32394E+05 -17.273 11 acmite 7.71 7.14 -0.57 -0.059 0.97248E+03 15 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 19 spessartine 24.46 20.13 -4.33 -0.216 0.73884E+04 20 analcite 3.32 3.04 -0.28 -0.031 0.47485E+03 21 andalusite 5.00 0.95 -4.06 -0.406 0.69252E+04 22 andradite 39.01 38.58 -0.43 -0.022 0.73686E+03 23 grossular 32.73 30.38 -2.35 -0.117 0.40075E+04 26 annite 20.12 17.17 -2.96 -0.164 0.50458E+04 27 phlogopite 27.06 23.86 -3.21 -0.178 0.54791E+04 29 anorthite 12.71 9.62 -3.09 -0.238 0.52833E+04 35 aragonite 0.97 -2.98 -3.95 -1.317 0.67438E+04 36 brucite 12.57 8.78 -3.79 -0.758 0.64676E+04 37 calcite 0.81 -2.98 -3.79 -1.265 0.64796E+04 38 carnegieite-low 9.02 6.47 -2.55 -0.365 0.43573E+04 39 carnegieite-high 10.09 6.47 -3.62 -0.517 0.61843E+04 40 carpholite-Mg 8.58 6.30 -2.28 -0.152 0.38986E+04 41 carpholite-Fe 6.71 4.07 -2.64 -0.176 0.45127E+04 42 celadonite 5.34 2.87 -2.47 -0.146 0.42260E+04 43 celadonite-Fe 3.88 0.64 -3.24 -0.191 0.55306E+04 44 chrysotile 23.89 19.49 -4.41 -0.367 0.75222E+04 50 chloritoid-Mg 13.20 9.73 -3.47 -0.231 0.59270E+04 51 chloritoid-Fe 9.17 7.50 -1.68 -0.112 0.28622E+04 52 chloritoid-Mn 11.40 9.63 -1.78 -0.118 0.30315E+04 54 coesite -2.38 -3.43 -1.05 -0.351 0.17955E+04 59 corundum 8.38 4.37 -4.01 -0.365 0.68466E+04 61 cristobalite -2.56 -3.43 -0.87 -0.289 0.14809E+04 63 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71234E+04 65 diaspore 2.87 2.19 -0.69 -0.115 0.11731E+04 67 diopside 16.18 14.02 -2.16 -0.216 0.36846E+04 68 hedenbergite 14.21 11.79 -2.41 -0.241 0.41218E+04 75 epidote 24.67 24.57 -0.10 -0.005 0.17145E+03 76 clinozoisite 22.81 20.47 -2.33 -0.106 0.39834E+04 77 epidote-Fe 29.84 28.67 -1.17 -0.061 0.20061E+04 78 fayalite 14.05 9.68 -4.37 -0.624 0.74620E+04 79 ferrosilite 11.15 6.25 -4.90 -0.490 0.83692E+04 83 gibbsite 4.08 2.19 -1.89 -0.270 0.32316E+04 84 glaucophane 22.97 18.72 -4.26 -0.115 0.72663E+04 87 greenalite 16.14 12.80 -3.34 -0.278 0.57029E+04 91 heulandite -5.83 -7.52 -1.69 -0.077 0.28938E+04 95 jadeite 4.22 3.04 -1.17 -0.117 0.20003E+04 96 julgoldite 70.43 66.06 -4.37 -0.113 0.74536E+04 97 kalsilite 7.58 4.37 -3.22 -0.459 0.54898E+04 98 kaolinite -1.33 -2.48 -1.15 -0.104 0.19621E+04 99 kyanite 4.88 0.95 -3.93 -0.393 0.67111E+04 101 laumontite 2.88 2.76 -0.12 -0.008 0.20932E+03 103 leucite 4.12 0.94 -3.18 -0.318 0.54259E+04 105 lizardite 23.24 19.49 -3.76 -0.313 0.64148E+04 107 magnetite 20.09 19.12 -0.97 -0.079 0.16556E+04 108 minnesotaite 10.39 5.94 -4.44 -0.261 0.75877E+04 110 magnesioferrite 26.21 21.35 -4.87 -0.397 0.83077E+04 113 margarite 17.32 13.99 -3.33 -0.133 0.56930E+04 120 muscovite 2.58 1.89 -0.70 -0.041 0.11877E+04 121 paragonite 4.24 3.99 -0.25 -0.015 0.42677E+03 122 nepheline 8.34 6.47 -1.87 -0.267 0.31897E+04 134 phlogopite-Na 29.65 25.96 -3.69 -0.205 0.62979E+04 136 prehnite 19.37 18.29 -1.09 -0.064 0.18534E+04 137 prehnite-Fe 22.50 22.38 -0.12 -0.007 0.19643E+03 138 pumpellyite-Fe 46.27 45.31 -0.96 -0.021 0.16363E+04 139 pumpellyite-Mg 48.99 47.54 -1.45 -0.032 0.24838E+04 145 pyroxmangite 7.40 5.25 -2.15 -0.429 0.36649E+04 146 pyrophyllite -6.18 -9.34 -3.16 -0.198 0.53979E+04 147 quartz -2.99 -3.43 -0.44 -0.146 0.74820E+03 152 rhodonite 7.45 5.25 -2.19 -0.439 0.37451E+04 153 sanidine -1.28 -2.49 -1.21 -0.093 0.20677E+04 156 sillimanite 5.26 0.95 -4.32 -0.432 0.73691E+04 164 stilpnomelane-Fe 13.02 12.52 -0.50 -0.015 0.85682E+03 165 stilpnomelane-Mg 27.44 23.66 -3.78 -0.113 0.64552E+04 171 talc 16.49 12.63 -3.86 -0.227 0.65898E+04 174 tephroite 18.09 13.93 -4.15 -0.593 0.70921E+04 177 topaz-H 4.62 0.95 -3.67 -0.334 0.62711E+04 178 tridymite -2.63 -3.43 -0.80 -0.267 0.13682E+04 187 wairakite 3.95 2.76 -1.19 -0.070 0.20313E+04 188 walstromite 11.51 8.67 -2.84 -0.568 0.48473E+04 189 wollastonite 10.46 8.67 -1.79 -0.358 0.30578E+04 190 pseudo-wollastonite 11.00 8.67 -2.33 -0.466 0.39776E+04 191 zoisite 22.85 20.47 -2.38 -0.108 0.40575E+04 192 akaganeite 7.75 6.28 -1.47 -0.318 0.25125E+04 193 beidellite-Ca -1.65 -5.49 -3.84 -0.238 0.65612E+04 195 beidellite-K -1.52 -5.63 -4.11 -0.252 0.70228E+04 196 beidellite-Mg -1.79 -6.04 -4.25 -0.263 0.72496E+04 197 beidellite-Na -1.34 -4.94 -3.60 -0.220 0.61420E+04 199 chalcedony -2.80 -3.43 -0.63 -0.208 0.10675E+04 201 montmorillonite-Ca -2.29 -5.16 -2.87 -0.178 0.49077E+04 202 montmorillonite-K -2.24 -5.31 -3.07 -0.188 0.52474E+04 203 montmorillonite-Mg -2.48 -5.71 -3.23 -0.200 0.55192E+04 204 montmorillonite-Na -2.04 -4.62 -2.58 -0.158 0.44023E+04 205 nontronite-Ca 3.21 2.70 -0.51 -0.033 0.87076E+03 206 nontronite-H 2.53 0.71 -1.82 -0.122 0.31149E+04 207 nontronite-K 3.34 2.56 -0.78 -0.050 0.13337E+04 208 nontronite-Mg 3.07 2.16 -0.92 -0.060 0.15664E+04 209 nontronite-Na 3.52 3.25 -0.27 -0.017 0.45458E+03 224 tobermorite 9.82 6.65 -3.17 -0.866 0.54179E+04 233 boehmite 4.41 2.19 -2.22 -0.370 0.37900E+04 235 ferrous-oxide 9.81 6.55 -3.26 -0.815 0.55663E+04 240 silica-amorphous -2.09 -3.43 -1.34 -0.445 0.22817E+04 242 an20ab80 2.02 1.62 -0.40 -0.031 0.68582E+03 243 an25ab75 2.65 2.12 -0.53 -0.041 0.90424E+03 244 an30ab70 3.28 2.62 -0.66 -0.051 0.11323E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 0.4000000 g Current total amount of reactant added: 7.9990000 g New total amount of reactant added: 8.3990000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.6640E-13 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 7 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 8.3990000 Water: Moles liquid = 0.5543E+02 kg liquid = 0.9986E+00 Moles total = 0.5540E+02 kg total = 0.9981E+00 Activity = 1.0000 Stoichiometric ionic strength = .4833237E-02 Osmotic coef. = 0.9629 True ionic strength = .8435425E-02 Chg. balance for total moles = 0.6640E-13 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.14760E-09 -9.8309 0.13001E-09 -9.8860 0.88083E+00 -0.0551 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13788E-03 -3.8605 0.12109E-03 -3.9169 0.87823E+00 -0.0564 4 SO4-- 0.25525E-04 -4.5930 0.16118E-04 -4.7927 0.63147E+00 -0.1996 5 HCO3- 0.67592E-05 -5.1701 0.59403E-05 -5.2262 0.87885E+00 -0.0561 6 HS- 0.44481E-12 -12.3518 0.39067E-12 -12.4082 0.87829E+00 -0.0564 7 Al+++ 0.85632E-27 -27.0674 0.30925E-27 -27.5097 0.36114E+00 -0.4423 8 H4SiO4 0.37357E-03 -3.4276 0.37357E-03 -3.4276 0.10000E+01 0.0000 9 Ca++ 0.40151E-07 -7.3963 0.25264E-07 -7.5975 0.62922E+00 -0.2012 10 Mg++ 0.16833E-10 -10.7738 0.10568E-10 -10.9760 0.62780E+00 -0.2022 11 Fe++ 0.99266E-13 -13.0032 0.62353E-13 -13.2051 0.62814E+00 -0.2019 12 K+ 0.65765E-04 -4.1820 0.57805E-04 -4.2380 0.87896E+00 -0.0560 13 Na+ 0.83372E-02 -2.0790 0.73214E-02 -2.1354 0.87816E+00 -0.0564 14 Mn++ 0.13334E-10 -10.8750 0.83790E-11 -11.0768 0.62840E+00 -0.2018 15 HPO4-- 0.42618E-06 -6.3704 0.26914E-06 -6.5700 0.63151E+00 -0.1996 16 HSiO3- 0.30551E-02 -2.5150 0.26830E-02 -2.5714 0.87823E+00 -0.0564 17 Ca(HSiO3)+ 0.17561E-08 -8.7555 0.15437E-08 -8.8114 0.87906E+00 -0.0560 18 Mg(HSiO3)+ 0.91420E-12 -12.0390 0.80363E-12 -12.0949 0.87906E+00 -0.0560 19 NaHSiO3,aq 0.31771E-03 -3.4980 0.31771E-03 -3.4980 0.10000E+01 0.0000 20 AlO+ 0.28315E-14 -14.5480 0.24891E-14 -14.6040 0.87906E+00 -0.0560 22 HAlO2,aq 0.38128E-08 -8.4188 0.38128E-08 -8.4188 0.10000E+01 0.0000 23 AlO2- 0.73985E-04 -4.1309 0.64917E-04 -4.1876 0.87744E+00 -0.0568 24 CH4,aq 0.14007E-18 -18.8537 0.13986E-18 -18.8543 0.99851E+00 -0.0006 29 CO,aq 0.58370E-19 -19.2338 0.58370E-19 -19.2338 0.10000E+01 0.0000 30 CO2,aq 0.16527E-08 -8.7818 0.16502E-08 -8.7825 0.99851E+00 -0.0006 31 CO3-2 0.63267E-05 -5.1988 0.39910E-05 -5.3989 0.63081E+00 -0.2001 32 CaCO3,aq 0.12642E-08 -8.8982 0.12642E-08 -8.8982 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.43579E-11 -11.3607 0.38308E-11 -11.4167 0.87906E+00 -0.0560 34 CaCl+ 0.56318E-11 -11.2494 0.49507E-11 -11.3053 0.87906E+00 -0.0560 35 CaCl2,aq 0.14242E-15 -15.8464 0.14242E-15 -15.8464 0.10000E+01 0.0000 36 CaOH+ 0.15755E-07 -7.8026 0.13849E-07 -7.8586 0.87906E+00 -0.0560 37 CaSO4,aq 0.12930E-09 -9.8884 0.12930E-09 -9.8884 0.10000E+01 0.0000 38 HCl,aq 0.28848E-14 -14.5399 0.28848E-14 -14.5399 0.10000E+01 0.0000 43 FeCl+ 0.13595E-16 -16.8666 0.11951E-16 -16.9226 0.87906E+00 -0.0560 46 FeO,aq 0.14337E-09 -9.8435 0.14337E-09 -9.8435 0.10000E+01 0.0000 47 FeOH+ 0.17760E-10 -10.7506 0.15612E-10 -10.8066 0.87906E+00 -0.0560 48 HFeO2- 0.13139E-07 -7.8815 0.11539E-07 -7.9378 0.87823E+00 -0.0564 49 FeO+ 0.11289E-14 -14.9474 0.99235E-15 -15.0033 0.87906E+00 -0.0560 51 FeO2- 0.13679E-07 -7.8639 0.12013E-07 -7.9203 0.87823E+00 -0.0564 52 HFeO2,aq 0.19864E-09 -9.7019 0.19864E-09 -9.7019 0.10000E+01 0.0000 53 H2,aq 0.14101E-08 -8.8507 0.14080E-08 -8.8514 0.99851E+00 -0.0006 54 KCl,aq 0.12686E-09 -9.8967 0.12686E-09 -9.8967 0.10000E+01 0.0000 55 KHSO4,aq 0.34248E-18 -18.4654 0.34248E-18 -18.4654 0.10000E+01 0.0000 56 KOH,aq 0.18988E-06 -6.7215 0.18988E-06 -6.7215 0.10000E+01 0.0000 57 KSO4- 0.16462E-07 -7.7835 0.14458E-07 -7.8399 0.87823E+00 -0.0564 58 MgCO3,aq 0.13256E-12 -12.8776 0.13256E-12 -12.8776 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.18627E-14 -14.7299 0.16374E-14 -14.7858 0.87906E+00 -0.0560 60 MgCl+ 0.21352E-14 -14.6706 0.18770E-14 -14.7265 0.87906E+00 -0.0560 61 MgOH+ 0.36468E-10 -10.4381 0.32057E-10 -10.4941 0.87906E+00 -0.0560 63 MnO,aq 0.51337E-09 -9.2896 0.51337E-09 -9.2896 0.10000E+01 0.0000 64 MnOH+ 0.22170E-09 -9.6542 0.19489E-09 -9.7102 0.87906E+00 -0.0560 65 MnO2-2 0.15979E-11 -11.7964 0.10080E-11 -11.9965 0.63081E+00 -0.2001 66 HMnO2- 0.32691E-10 -10.4856 0.28710E-10 -10.5420 0.87823E+00 -0.0564 69 MnCl+ 0.71074E-14 -14.1483 0.62478E-14 -14.2043 0.87906E+00 -0.0560 70 MnSO4,aq 0.38989E-13 -13.4091 0.38989E-13 -13.4091 0.10000E+01 0.0000 71 NaCl,aq 0.29380E-06 -6.5319 0.29380E-06 -6.5319 0.10000E+01 0.0000 72 NaOH,aq 0.24195E-04 -4.6163 0.24195E-04 -4.6163 0.10000E+01 0.0000 74 OH- 0.50648E-02 -2.2954 0.44441E-02 -2.3522 0.87744E+00 -0.0568 79 HPO3-2 0.18721E-17 -17.7277 0.11810E-17 -17.9278 0.63081E+00 -0.2001 82 H3PO4,aq 0.31816E-16 -16.4973 0.31816E-16 -16.4973 0.10000E+01 0.0000 83 H2PO4- 0.73464E-09 -9.1339 0.64548E-09 -9.1901 0.87863E+00 -0.0562 84 PO4-3 0.45655E-08 -8.3405 0.16890E-08 -8.7724 0.36995E+00 -0.4319 87 H2P2O7-2 0.51790E-19 -19.2858 0.32669E-19 -19.4859 0.63081E+00 -0.2001 88 HP2O7-3 0.13888E-15 -15.8573 0.50176E-16 -16.2995 0.36128E+00 -0.4422 89 P2O7-4 0.54846E-15 -15.2609 0.92199E-16 -16.0353 0.16811E+00 -0.7744 90 H2S,aq 0.15721E-15 -15.8035 0.15698E-15 -15.8042 0.99851E+00 -0.0006 97 SO3-2 0.46422E-14 -14.3333 0.29492E-14 -14.5303 0.63529E+00 -0.1970 98 HSO3- 0.27336E-16 -16.5633 0.24007E-16 -16.6197 0.87823E+00 -0.0564 99 HSO4- 0.22962E-11 -11.6390 0.20195E-11 -11.6948 0.87947E+00 -0.0558 Charge balance for all species = 0.6708E-13 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.1475986E-09 -.8764331E-02 -.8828667E+01 0.0000 2 H2O 0.1000000E+01 0.5551011E+02 0.9994368E+06 0.0000 3 Cl- 0.1378784E-03 0.1381724E-03 0.4895712E+01 5.9691 4 SO4-- 0.2552451E-04 0.2554248E-04 0.2452193E+01 14.9794 5 HCO3- 0.6759152E-05 0.1308877E-04 0.7981654E+00 4.6598 6 HS- 0.4448090E-12 -.1381731E-08 -.4566942E-04 -2.5222 7 Al+++ 0.8563160E-27 0.7398834E-04 0.1995129E+01 2.1484 8 H4SiO4 0.3735728E-03 0.3746337E-02 0.3598665E+03 -3.4276 9 Ca++ 0.4015116E-07 0.5906541E-07 0.2365816E-02 12.1745 10 Mg++ 0.1683345E-10 0.5435185E-10 0.1320616E-05 8.7960 11 Fe++ 0.9926624E-13 0.2717754E-07 0.1516882E-02 6.5669 12 K+ 0.6576527E-04 0.6597174E-04 0.2578093E+01 5.6480 13 Na+ 0.8337230E-02 0.8679428E-02 0.1994197E+03 7.7506 14 Mn++ 0.1333393E-10 0.7827398E-09 0.4297659E-04 8.6952 15 HPO4-- 0.4261797E-06 0.4314798E-06 0.4138838E-01 13.2020 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.1390619E+00 -.8751761E-02 -.1303102E+00 0.0000000E+00 2 H2O 0.5540297E+02 0.5543050E+02 -.2753307E-01 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.2582694E-03 0.2550585E-04 0.2327635E-03 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.2327649E-03 -.1379749E-08 -.2327635E-03 0.0000000E+00 7 Al+++ 0.2738697E-01 0.7388222E-04 0.2731309E-01 0.0000000E+00 8 H4SiO4 0.8745696E-01 0.3740963E-02 0.8371600E-01 0.0000000E+00 9 Ca++ 0.9674519E-02 0.5898070E-07 0.9674460E-02 0.0000000E+00 10 Mg++ 0.6665873E-02 0.5427389E-10 0.6665873E-02 0.0000000E+00 11 Fe++ 0.5988559E-02 0.2713856E-07 0.5988532E-02 0.0000000E+00 12 K+ 0.1783227E-02 0.6587712E-04 0.1717350E-02 0.0000000E+00 13 Na+ 0.1070286E-01 0.8666979E-02 0.2035883E-02 0.0000000E+00 14 Mn++ 0.1456269E-03 0.7816171E-09 0.1456261E-03 0.0000000E+00 15 HPO4-- 0.4970173E-04 0.4308610E-06 0.4927087E-04 0.0000000E+00 Chg. balance for solid moles: 0.9893E-17 Mass of aqueous solution: 0.999160E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 8.3990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 0.2036E-02 -2.691 0.5338 -0.273 5.814 0.2049 apatite-OH 0.1642E-04 -4.785 0.8250E-02 -2.084 0.8985E-01 0.2622E-02 clinochlore 0.1333E-02 -2.875 0.7410 -0.130 8.071 0.2819 daphnite 0.8253E-03 -3.083 0.5888 -0.230 6.414 0.1784 chlorite-Mn 0.2913E-04 -4.536 0.2065E-01 -1.685 0.2249 0.6580E-02 hematite 0.9311E-03 -3.031 0.1487 -0.828 1.619 0.2818E-01 lawsonite 0.2506E-03 -3.601 0.7874E-01 -1.104 0.8576 0.2539E-01 microcline 0.1717E-02 -2.765 0.4780 -0.321 5.206 0.1867 stilbite 0.9342E-02 -2.030 6.583 0.818 71.70 3.071 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.6094E+00 0.6094E+00 1.0000 -0.215 daphnite 0.3773E+00 0.3773E+00 1.0000 -0.423 chlorite-Mn 0.1331E-01 0.1331E-01 1.0000 -1.876 hematite 0.1000E+01 0.1000E+01 1.0000 0.000 lawsonite 0.1000E+01 0.1000E+01 1.0000 0.000 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 9.181385 g Volume = 3.985317 cm3 Porosity: 8.5853% V(tot) - V(min): 0.37428E+00 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 8.3990000 g log = 0.9242 Original solution: 1000.0103000 g Original solution / Rock added: 119.06 (Water/Rock Ratio), log = 2.0758 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0203 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.1000E+01 0.9860 0.1006E+01 0.1020E+01 CO2,gas 0.1718E-06 1.0071 0.1766E-06 0.1753E-06 CH4,gas 0.1993E-15 1.0125 0.2059E-15 0.2033E-15 H2,gas 0.1811E-05 1.0005 0.1849E-05 0.1848E-05 H2S,gas 0.4246E-14 0.9960 0.4315E-14 0.4332E-14 S2,gas 0.2005E-36 1.0000 0.2045E-36 0.2045E-36 CO,gas 0.8525E-16 1.0000 0.8698E-16 0.8698E-16 SO3,gas 0.1010E-39 1.0000 0.1030E-39 0.1030E-39 SO2,gas 0.7261E-23 1.0000 0.7408E-23 0.7408E-23 HCl,gas 0.4989E-17 1.0000 0.5090E-17 0.5090E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 16 albite -0.38 -0.38 0.00 0.000 0.11184E-10 32 apatite-OH -18.15 -18.15 0.00 0.000 0.12132E-10 46 clinochlore 39.07 39.07 0.00 0.000 0.12132E-10 47 daphnite 28.97 28.97 0.00 0.000 0.30331E-10 48 chlorite-Mn 46.87 46.87 0.00 0.000 0.12132E-10 90 hematite 12.57 12.57 0.00 0.000 0.90992E-11 102 lawsonite 9.62 9.62 0.00 0.000 0.12132E-10 116 microcline -2.49 -2.49 0.00 0.000 0.13649E-10 163 stilbite -7.52 -7.52 0.00 0.000 0.15165E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -15.11 -8.45 -2.817 0.14432E+05 -6.753 3 CH4,gas 4.54 -12.84 -17.39 -4.346 0.29685E+05 -15.686 4 H2,gas 8.00 0.57 -7.43 -4.247 0.12690E+05 -5.733 5 H2S,gas -6.23 -22.29 -16.06 -8.032 0.27429E+05 -14.365 6 S2,gas -7.34 -45.72 -38.39 -5.906 0.65547E+05 -36.689 7 CO,gas 3.21 -14.54 -17.76 -5.464 0.30324E+05 -16.061 8 SO3,gas 17.12 -24.56 -41.69 -10.422 0.71178E+05 -39.987 9 SO2,gas 0.83 -24.00 -24.83 -6.621 0.42395E+05 -23.130 10 HCl,gas 5.19 -13.80 -18.99 -9.496 0.32429E+05 -17.293 11 acmite 7.71 7.18 -0.53 -0.055 0.90710E+03 15 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 19 spessartine 24.46 20.10 -4.36 -0.218 0.74407E+04 20 analcite 3.32 3.04 -0.28 -0.031 0.47485E+03 21 andalusite 5.00 0.87 -4.13 -0.413 0.70559E+04 22 andradite 39.01 38.81 -0.20 -0.010 0.34458E+03 23 grossular 32.73 30.54 -2.19 -0.110 0.37460E+04 26 annite 20.12 17.21 -2.91 -0.162 0.49673E+04 27 phlogopite 27.06 23.90 -3.16 -0.176 0.54007E+04 29 anorthite 12.71 9.62 -3.09 -0.238 0.52833E+04 35 aragonite 0.97 -2.94 -3.90 -1.301 0.66663E+04 36 brucite 12.57 8.80 -3.77 -0.755 0.64415E+04 37 calcite 0.81 -2.94 -3.75 -1.250 0.64021E+04 38 carnegieite-low 9.02 6.47 -2.55 -0.365 0.43573E+04 39 carnegieite-high 10.09 6.47 -3.62 -0.517 0.61843E+04 40 carpholite-Mg 8.58 6.24 -2.34 -0.156 0.40032E+04 41 carpholite-Fe 6.71 4.01 -2.70 -0.180 0.46174E+04 42 celadonite 5.34 2.88 -2.46 -0.145 0.41998E+04 43 celadonite-Fe 3.88 0.65 -3.22 -0.190 0.55044E+04 44 chrysotile 23.89 19.53 -4.36 -0.363 0.74437E+04 50 chloritoid-Mg 13.20 9.67 -3.53 -0.236 0.60317E+04 51 chloritoid-Fe 9.17 7.44 -1.74 -0.116 0.29668E+04 52 chloritoid-Mn 11.40 9.56 -1.84 -0.122 0.31361E+04 54 coesite -2.38 -3.43 -1.05 -0.351 0.17955E+04 59 corundum 8.38 4.30 -4.09 -0.371 0.69773E+04 61 cristobalite -2.56 -3.43 -0.87 -0.289 0.14809E+04 63 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71234E+04 65 diaspore 2.87 2.15 -0.73 -0.121 0.12384E+04 67 diopside 16.18 14.12 -2.07 -0.207 0.35277E+04 68 hedenbergite 14.21 11.89 -2.32 -0.232 0.39649E+04 75 epidote 24.67 24.65 -0.02 -0.001 0.40692E+02 76 clinozoisite 22.81 20.51 -2.29 -0.104 0.39181E+04 77 epidote-Fe 29.84 28.78 -1.06 -0.055 0.18099E+04 78 fayalite 14.05 9.71 -4.34 -0.620 0.74096E+04 79 ferrosilite 11.15 6.28 -4.87 -0.487 0.83169E+04 83 gibbsite 4.08 2.15 -1.93 -0.276 0.32970E+04 84 glaucophane 22.97 18.77 -4.21 -0.114 0.71879E+04 87 greenalite 16.14 12.85 -3.29 -0.275 0.56245E+04 91 heulandite -5.83 -7.52 -1.69 -0.077 0.28938E+04 95 jadeite 4.22 3.04 -1.17 -0.117 0.20003E+04 96 julgoldite 70.43 66.40 -4.03 -0.105 0.68782E+04 97 kalsilite 7.58 4.37 -3.22 -0.459 0.54898E+04 98 kaolinite -1.33 -2.56 -1.23 -0.111 0.20929E+04 99 kyanite 4.88 0.87 -4.01 -0.401 0.68418E+04 101 laumontite 2.88 2.76 -0.12 -0.008 0.20932E+03 103 leucite 4.12 0.94 -3.18 -0.318 0.54259E+04 105 lizardite 23.24 19.53 -3.71 -0.309 0.63364E+04 107 magnetite 20.09 19.13 -0.95 -0.078 0.16294E+04 108 minnesotaite 10.39 5.99 -4.40 -0.259 0.75093E+04 110 magnesioferrite 26.21 21.36 -4.85 -0.396 0.82815E+04 113 margarite 17.32 13.91 -3.41 -0.136 0.58238E+04 120 muscovite 2.58 1.81 -0.77 -0.045 0.13184E+04 121 paragonite 4.24 3.91 -0.33 -0.019 0.55753E+03 122 nepheline 8.34 6.47 -1.87 -0.267 0.31897E+04 134 phlogopite-Na 29.65 26.00 -3.64 -0.202 0.62195E+04 136 prehnite 19.37 18.36 -1.01 -0.059 0.17226E+04 137 prehnite-Fe 22.50 22.50 0.00 0.000 0.28606E+00 138 pumpellyite-Fe 46.27 45.44 -0.83 -0.018 0.14140E+04 139 pumpellyite-Mg 48.99 47.67 -1.32 -0.029 0.22615E+04 145 pyroxmangite 7.40 5.27 -2.13 -0.426 0.36387E+04 146 pyrophyllite -6.18 -9.41 -3.24 -0.202 0.55287E+04 147 quartz -2.99 -3.43 -0.44 -0.146 0.74820E+03 152 rhodonite 7.45 5.27 -2.18 -0.436 0.37190E+04 153 sanidine -1.28 -2.49 -1.21 -0.093 0.20677E+04 156 sillimanite 5.26 0.87 -4.39 -0.439 0.74999E+04 164 stilpnomelane-Fe 13.02 12.53 -0.48 -0.014 0.82413E+03 165 stilpnomelane-Mg 27.44 23.68 -3.76 -0.112 0.64225E+04 171 talc 16.49 12.68 -3.81 -0.224 0.65113E+04 174 tephroite 18.09 13.96 -4.12 -0.589 0.70398E+04 177 topaz-H 4.62 0.87 -3.75 -0.341 0.64019E+04 178 tridymite -2.63 -3.43 -0.80 -0.267 0.13682E+04 187 wairakite 3.95 2.76 -1.19 -0.070 0.20313E+04 188 walstromite 11.51 8.75 -2.76 -0.552 0.47166E+04 189 wollastonite 10.46 8.75 -1.71 -0.343 0.29270E+04 190 pseudo-wollastonite 11.00 8.75 -2.25 -0.451 0.38468E+04 191 zoisite 22.85 20.51 -2.34 -0.106 0.39921E+04 192 akaganeite 7.75 6.28 -1.47 -0.318 0.25125E+04 193 beidellite-Ca -1.65 -5.56 -3.92 -0.242 0.66920E+04 195 beidellite-K -1.52 -5.71 -4.19 -0.257 0.71536E+04 196 beidellite-Mg -1.79 -6.12 -4.33 -0.268 0.73976E+04 197 beidellite-Na -1.34 -5.02 -3.67 -0.225 0.62727E+04 199 chalcedony -2.80 -3.43 -0.63 -0.208 0.10675E+04 201 montmorillonite-Ca -2.29 -5.21 -2.92 -0.181 0.49866E+04 202 montmorillonite-K -2.24 -5.36 -3.12 -0.191 0.53264E+04 203 montmorillonite-Mg -2.48 -5.77 -3.29 -0.203 0.56155E+04 204 montmorillonite-Na -2.04 -4.66 -2.62 -0.161 0.44813E+04 205 nontronite-Ca 3.21 2.70 -0.51 -0.033 0.87076E+03 206 nontronite-H 2.53 0.70 -1.84 -0.123 0.31365E+04 207 nontronite-K 3.34 2.56 -0.78 -0.050 0.13337E+04 208 nontronite-Mg 3.07 2.15 -0.93 -0.060 0.15837E+04 209 nontronite-Na 3.52 3.25 -0.27 -0.017 0.45458E+03 224 tobermorite 9.82 6.71 -3.11 -0.848 0.53090E+04 233 boehmite 4.41 2.15 -2.26 -0.376 0.38554E+04 235 ferrous-oxide 9.81 6.57 -3.24 -0.811 0.55402E+04 240 silica-amorphous -2.09 -3.43 -1.34 -0.445 0.22817E+04 242 an20ab80 2.02 1.62 -0.40 -0.031 0.68582E+03 243 an25ab75 2.65 2.12 -0.53 -0.041 0.90424E+03 244 an30ab70 3.28 2.62 -0.66 -0.051 0.11323E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 0.4000000 g Current total amount of reactant added: 8.3990000 g New total amount of reactant added: 8.7990000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.6640E-13 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 7 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 8.7990000 Water: Moles liquid = 0.5542E+02 kg liquid = 0.9985E+00 Moles total = 0.5540E+02 kg total = 0.9980E+00 Activity = 1.0000 Stoichiometric ionic strength = .5021109E-02 Osmotic coef. = 0.9623 True ionic strength = .8806970E-02 Chg. balance for total moles = 0.6640E-13 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.14169E-09 -9.8487 0.12455E-09 -9.9047 0.87904E+00 -0.0560 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13788E-03 -3.8605 0.12083E-03 -3.9178 0.87634E+00 -0.0573 4 SO4-- 0.25526E-04 -4.5930 0.15984E-04 -4.7963 0.62619E+00 -0.2033 5 HCO3- 0.65987E-05 -5.1805 0.57870E-05 -5.2375 0.87699E+00 -0.0570 6 HS- 0.55409E-12 -12.2564 0.48561E-12 -12.3137 0.87641E+00 -0.0573 7 Al+++ 0.70564E-27 -27.1514 0.25001E-27 -27.6020 0.35430E+00 -0.4506 8 H4SiO4 0.37357E-03 -3.4276 0.37357E-03 -3.4276 0.10000E+01 0.0000 9 Ca++ 0.43964E-07 -7.3569 0.27428E-07 -7.5618 0.62387E+00 -0.2049 10 Mg++ 0.16116E-10 -10.7927 0.10031E-10 -10.9987 0.62242E+00 -0.2059 11 Fe++ 0.95032E-13 -13.0221 0.59183E-13 -13.2278 0.62277E+00 -0.2057 12 K+ 0.68670E-04 -4.1632 0.60231E-04 -4.2202 0.87710E+00 -0.0569 13 Na+ 0.87058E-02 -2.0602 0.76286E-02 -2.1176 0.87627E+00 -0.0574 14 Mn++ 0.12765E-10 -10.8940 0.79530E-11 -11.0995 0.62303E+00 -0.2055 15 HPO4-- 0.35392E-06 -6.4511 0.22164E-06 -6.6544 0.62624E+00 -0.2033 16 HSiO3- 0.31958E-02 -2.4954 0.28006E-02 -2.5527 0.87634E+00 -0.0573 17 Ca(HSiO3)+ 0.19943E-08 -8.7002 0.17494E-08 -8.7571 0.87720E+00 -0.0569 18 Mg(HSiO3)+ 0.90766E-12 -12.0421 0.79620E-12 -12.0990 0.87720E+00 -0.0569 19 NaHSiO3,aq 0.34555E-03 -3.4615 0.34555E-03 -3.4615 0.10000E+01 0.0000 20 AlO+ 0.24994E-14 -14.6022 0.21925E-14 -14.6591 0.87720E+00 -0.0569 22 HAlO2,aq 0.35056E-08 -8.4552 0.35056E-08 -8.4552 0.10000E+01 0.0000 23 AlO2- 0.71161E-04 -4.1478 0.62303E-04 -4.2055 0.87553E+00 -0.0577 24 CH4,aq 0.17105E-18 -18.7669 0.17078E-18 -18.7676 0.99845E+00 -0.0007 29 CO,aq 0.58263E-19 -19.2346 0.58263E-19 -19.2346 0.10000E+01 0.0000 30 CO2,aq 0.15425E-08 -8.8118 0.15401E-08 -8.8124 0.99845E+00 -0.0007 31 CO3-2 0.64880E-05 -5.1879 0.40583E-05 -5.3917 0.62552E+00 -0.2038 32 CaCO3,aq 0.13957E-08 -8.8552 0.13957E-08 -8.8552 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.46189E-11 -11.3355 0.40517E-11 -11.3924 0.87720E+00 -0.0569 34 CaCl+ 0.61140E-11 -11.2137 0.53632E-11 -11.2706 0.87720E+00 -0.0569 35 CaCl2,aq 0.15395E-15 -15.8126 0.15395E-15 -15.8126 0.10000E+01 0.0000 36 CaOH+ 0.17892E-07 -7.7473 0.15695E-07 -7.8042 0.87720E+00 -0.0569 37 CaSO4,aq 0.13922E-09 -9.8563 0.13922E-09 -9.8563 0.10000E+01 0.0000 38 HCl,aq 0.27577E-14 -14.5595 0.27577E-14 -14.5595 0.10000E+01 0.0000 43 FeCl+ 0.12903E-16 -16.8893 0.11319E-16 -16.9462 0.87720E+00 -0.0569 46 FeO,aq 0.14827E-09 -9.8289 0.14827E-09 -9.8289 0.10000E+01 0.0000 47 FeOH+ 0.17632E-10 -10.7537 0.15467E-10 -10.8106 0.87720E+00 -0.0569 48 HFeO2- 0.14214E-07 -7.8473 0.12456E-07 -7.9046 0.87634E+00 -0.0573 49 FeO+ 0.10838E-14 -14.9651 0.95069E-15 -15.0220 0.87720E+00 -0.0569 51 FeO2- 0.14309E-07 -7.8444 0.12540E-07 -7.9017 0.87634E+00 -0.0573 52 HFeO2,aq 0.19864E-09 -9.7019 0.19864E-09 -9.7019 0.10000E+01 0.0000 53 H2,aq 0.15082E-08 -8.8215 0.15059E-08 -8.8222 0.99845E+00 -0.0007 54 KCl,aq 0.13190E-09 -9.8798 0.13190E-09 -9.8798 0.10000E+01 0.0000 55 KHSO4,aq 0.33903E-18 -18.4698 0.33903E-18 -18.4698 0.10000E+01 0.0000 56 KOH,aq 0.20652E-06 -6.6850 0.20652E-06 -6.6850 0.10000E+01 0.0000 57 KSO4- 0.17047E-07 -7.7683 0.14939E-07 -7.8257 0.87634E+00 -0.0573 58 MgCO3,aq 0.12794E-12 -12.8930 0.12794E-12 -12.8930 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.17260E-14 -14.7630 0.15141E-14 -14.8199 0.87720E+00 -0.0569 60 MgCl+ 0.20265E-14 -14.6932 0.17777E-14 -14.7501 0.87720E+00 -0.0569 61 MgOH+ 0.36207E-10 -10.4412 0.31761E-10 -10.4981 0.87720E+00 -0.0569 63 MnO,aq 0.53091E-09 -9.2750 0.53091E-09 -9.2750 0.10000E+01 0.0000 64 MnOH+ 0.22011E-09 -9.6574 0.19308E-09 -9.7143 0.87720E+00 -0.0569 65 MnO2-2 0.18158E-11 -11.7409 0.11358E-11 -11.9447 0.62552E+00 -0.2038 66 HMnO2- 0.35366E-10 -10.4514 0.30992E-10 -10.5087 0.87634E+00 -0.0573 69 MnCl+ 0.67457E-14 -14.1710 0.59173E-14 -14.2279 0.87720E+00 -0.0569 70 MnSO4,aq 0.36699E-13 -13.4354 0.36699E-13 -13.4354 0.10000E+01 0.0000 71 NaCl,aq 0.30547E-06 -6.5150 0.30547E-06 -6.5150 0.10000E+01 0.0000 72 NaOH,aq 0.26315E-04 -4.5798 0.26315E-04 -4.5798 0.10000E+01 0.0000 74 OH- 0.52983E-02 -2.2759 0.46388E-02 -2.3336 0.87553E+00 -0.0577 79 HPO3-2 0.16628E-17 -17.7792 0.10401E-17 -17.9829 0.62552E+00 -0.2038 82 H3PO4,aq 0.24047E-16 -16.6189 0.24047E-16 -16.6189 0.10000E+01 0.0000 83 H2PO4- 0.58082E-09 -9.2360 0.50924E-09 -9.2931 0.87676E+00 -0.0571 84 PO4-3 0.39966E-08 -8.3983 0.14519E-08 -8.8381 0.36327E+00 -0.4398 87 H2P2O7-2 0.32507E-19 -19.4880 0.20334E-19 -19.6918 0.62552E+00 -0.2038 88 HP2O7-3 0.91971E-16 -16.0364 0.32598E-16 -16.4868 0.35444E+00 -0.4505 89 P2O7-4 0.38460E-15 -15.4150 0.62525E-16 -16.2039 0.16257E+00 -0.7890 90 H2S,aq 0.18722E-15 -15.7276 0.18693E-15 -15.7283 0.99845E+00 -0.0007 97 SO3-2 0.49640E-14 -14.3042 0.31279E-14 -14.5047 0.63013E+00 -0.2006 98 HSO3- 0.27835E-16 -16.5554 0.24393E-16 -16.6127 0.87634E+00 -0.0573 99 HSO4- 0.21861E-11 -11.6603 0.19186E-11 -11.7170 0.87762E+00 -0.0567 Charge balance for all species = 0.6740E-13 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.1416906E-09 -.9157435E-02 -.9224416E+01 0.0000 2 H2O 0.1000000E+01 0.5551018E+02 0.9994118E+06 0.0000 3 Cl- 0.1378761E-03 0.1381817E-03 0.4895915E+01 5.9868 4 SO4-- 0.2552564E-04 0.2554426E-04 0.2452300E+01 15.0130 5 HCO3- 0.6598718E-05 0.1308966E-04 0.7981985E+00 4.6671 6 HS- 0.5540893E-12 -.1435872E-08 -.4745768E-04 -2.4091 7 Al+++ 0.7056384E-27 0.7116406E-04 0.1918921E+01 2.1119 8 H4SiO4 0.3735728E-03 0.3914920E-02 0.3760506E+03 -3.4276 9 Ca++ 0.4396442E-07 0.6539618E-07 0.2619321E-02 12.2475 10 Mg++ 0.1611573E-10 0.5336189E-10 0.1296529E-05 8.8106 11 Fe++ 0.9503198E-13 0.2888738E-07 0.1612272E-02 6.5815 12 K+ 0.6866997E-04 0.6889366E-04 0.2692208E+01 5.6845 13 Na+ 0.8705768E-02 0.9077934E-02 0.2085704E+03 7.7871 14 Mn++ 0.1276497E-10 0.8010153E-09 0.4397887E-04 8.7098 15 HPO4-- 0.3539161E-06 0.3584935E-06 0.3438649E-01 13.1549 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.1456853E+00 -.9143683E-02 -.1365417E+00 0.0000000E+00 2 H2O 0.5539795E+02 0.5542682E+02 -.2886582E-01 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.2693548E-03 0.2550590E-04 0.2438489E-03 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.2438503E-03 -.1433716E-08 -.2438489E-03 0.0000000E+00 7 Al+++ 0.2869127E-01 0.7105719E-04 0.2862021E-01 0.0000000E+00 8 H4SiO4 0.9162208E-01 0.3909041E-02 0.8771304E-01 0.0000000E+00 9 Ca++ 0.1013458E-01 0.6529797E-07 0.1013451E-01 0.0000000E+00 10 Mg++ 0.6983333E-02 0.5328176E-10 0.6983333E-02 0.0000000E+00 11 Fe++ 0.6273763E-02 0.2884400E-07 0.6273734E-02 0.0000000E+00 12 K+ 0.1868153E-02 0.6879021E-04 0.1799363E-02 0.0000000E+00 13 Na+ 0.1120496E-01 0.9064302E-02 0.2140658E-02 0.0000000E+00 14 Mn++ 0.1525623E-03 0.7998124E-09 0.1525615E-03 0.0000000E+00 15 HPO4-- 0.5206876E-04 0.3579552E-06 0.5171080E-04 0.0000000E+00 Chg. balance for solid moles: 0.2168E-17 Mass of aqueous solution: 0.999118E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 8.7990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 0.2141E-02 -2.669 0.5613 -0.251 5.835 0.2155 apatite-OH 0.1724E-04 -4.764 0.8658E-02 -2.063 0.9001E-01 0.2751E-02 clinochlore 0.1397E-02 -2.855 0.7763 -0.110 8.070 0.2953 daphnite 0.8646E-03 -3.063 0.6169 -0.210 6.413 0.1869 chlorite-Mn 0.3051E-04 -4.516 0.2163E-01 -1.665 0.2249 0.6894E-02 hematite 0.9754E-03 -3.011 0.1558 -0.808 1.619 0.2952E-01 lawsonite 0.2641E-03 -3.578 0.8300E-01 -1.081 0.8628 0.2676E-01 microcline 0.1799E-02 -2.745 0.5008 -0.300 5.206 0.1956 stilbite 0.9784E-02 -2.009 6.895 0.839 71.68 3.216 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.6094E+00 0.6094E+00 1.0000 -0.215 daphnite 0.3773E+00 0.3773E+00 1.0000 -0.423 chlorite-Mn 0.1331E-01 0.1331E-01 1.0000 -1.876 hematite 0.1000E+01 0.1000E+01 1.0000 0.000 lawsonite 0.1000E+01 0.1000E+01 1.0000 0.000 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 9.619543 g Volume = 4.175285 cm3 Porosity: 7.6183% V(tot) - V(min): 0.34431E+00 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 8.7990000 g log = 0.9444 Original solution: 1000.0103000 g Original solution / Rock added: 113.65 (Water/Rock Ratio), log = 2.0556 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0203 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.1000E+01 0.9860 0.1006E+01 0.1020E+01 CO2,gas 0.1604E-06 1.0071 0.1648E-06 0.1636E-06 CH4,gas 0.2433E-15 1.0125 0.2514E-15 0.2483E-15 H2,gas 0.1937E-05 1.0005 0.1977E-05 0.1976E-05 H2S,gas 0.5056E-14 0.9960 0.5139E-14 0.5159E-14 S2,gas 0.2485E-36 1.0000 0.2536E-36 0.2536E-36 CO,gas 0.8510E-16 1.0000 0.8682E-16 0.8682E-16 SO3,gas 0.9189E-40 1.0000 0.9376E-40 0.9376E-40 SO2,gas 0.7068E-23 1.0000 0.7211E-23 0.7211E-23 HCl,gas 0.4769E-17 1.0000 0.4866E-17 0.4866E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 16 albite -0.38 -0.38 0.00 0.000 -0.13080E-10 32 apatite-OH -18.15 -18.15 0.00 0.000 0.60662E-11 46 clinochlore 39.07 39.07 0.00 0.000 -0.12132E-10 47 daphnite 28.97 28.97 0.00 0.000 0.12132E-10 48 chlorite-Mn 46.87 46.87 0.00 0.000 -0.24265E-10 90 hematite 12.57 12.57 0.00 0.000 -0.30331E-11 102 lawsonite 9.62 9.62 0.00 0.000 0.12132E-10 116 microcline -2.49 -2.49 0.00 0.000 -0.10616E-10 163 stilbite -7.52 -7.52 0.00 0.000 -0.90992E-11 137 prehnite-Fe 22.50 22.61 0.11 0.007 -0.18656E+03 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -15.14 -8.48 -2.827 0.14483E+05 -6.783 3 CH4,gas 4.54 -12.75 -17.30 -4.325 0.29537E+05 -15.600 4 H2,gas 8.00 0.60 -7.40 -4.230 0.12640E+05 -5.704 5 H2S,gas -6.23 -22.22 -15.99 -7.994 0.27299E+05 -14.289 6 S2,gas -7.34 -45.63 -38.29 -5.892 0.65387E+05 -36.596 7 CO,gas 3.21 -14.55 -17.76 -5.465 0.30325E+05 -16.061 8 SO3,gas 17.12 -24.61 -41.73 -10.432 0.71248E+05 -40.028 9 SO2,gas 0.83 -24.01 -24.84 -6.624 0.42415E+05 -23.142 10 HCl,gas 5.19 -13.82 -19.01 -9.506 0.32462E+05 -17.313 11 acmite 7.71 7.21 -0.49 -0.051 0.84482E+03 15 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 19 spessartine 24.46 20.07 -4.39 -0.219 0.74905E+04 20 analcite 3.32 3.04 -0.28 -0.031 0.47485E+03 21 andalusite 5.00 0.80 -4.21 -0.421 0.71805E+04 22 andradite 39.01 39.03 0.02 0.001 -0.29122E+02 23 grossular 32.73 30.68 -2.05 -0.102 0.34969E+04 26 annite 20.12 17.26 -2.87 -0.159 0.48926E+04 27 phlogopite 27.06 23.95 -3.12 -0.173 0.53259E+04 29 anorthite 12.71 9.62 -3.09 -0.238 0.52833E+04 35 aragonite 0.97 -2.89 -3.86 -1.287 0.65929E+04 36 brucite 12.57 8.81 -3.76 -0.752 0.64166E+04 37 calcite 0.81 -2.89 -3.71 -1.235 0.63287E+04 38 carnegieite-low 9.02 6.47 -2.55 -0.365 0.43573E+04 39 carnegieite-high 10.09 6.47 -3.62 -0.517 0.61843E+04 40 carpholite-Mg 8.58 6.18 -2.40 -0.160 0.41029E+04 41 carpholite-Fe 6.71 3.95 -2.76 -0.184 0.47170E+04 42 celadonite 5.34 2.90 -2.45 -0.144 0.41749E+04 43 celadonite-Fe 3.88 0.67 -3.21 -0.189 0.54795E+04 44 chrysotile 23.89 19.58 -4.32 -0.360 0.73690E+04 50 chloritoid-Mg 13.20 9.61 -3.59 -0.239 0.61313E+04 51 chloritoid-Fe 9.17 7.38 -1.80 -0.120 0.30665E+04 52 chloritoid-Mn 11.40 9.51 -1.90 -0.126 0.32357E+04 54 coesite -2.38 -3.43 -1.05 -0.351 0.17955E+04 59 corundum 8.38 4.22 -4.16 -0.378 0.71019E+04 61 cristobalite -2.56 -3.43 -0.87 -0.289 0.14809E+04 63 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71234E+04 65 diaspore 2.87 2.11 -0.76 -0.127 0.13007E+04 67 diopside 16.18 14.20 -1.98 -0.198 0.33782E+04 68 hedenbergite 14.21 11.97 -2.23 -0.223 0.38154E+04 75 epidote 24.67 24.72 0.05 0.002 -0.83875E+02 76 clinozoisite 22.81 20.55 -2.26 -0.103 0.38558E+04 77 epidote-Fe 29.84 28.89 -0.95 -0.049 0.16231E+04 78 fayalite 14.05 9.74 -4.31 -0.616 0.73598E+04 79 ferrosilite 11.15 6.31 -4.84 -0.484 0.82671E+04 83 gibbsite 4.08 2.11 -1.97 -0.281 0.33593E+04 84 glaucophane 22.97 18.81 -4.17 -0.113 0.71131E+04 87 greenalite 16.14 12.89 -3.25 -0.271 0.55497E+04 91 heulandite -5.83 -7.52 -1.69 -0.077 0.28938E+04 95 jadeite 4.22 3.04 -1.17 -0.117 0.20003E+04 96 julgoldite 70.43 66.72 -3.71 -0.096 0.63301E+04 97 kalsilite 7.58 4.37 -3.22 -0.459 0.54898E+04 98 kaolinite -1.33 -2.63 -1.30 -0.118 0.22174E+04 99 kyanite 4.88 0.80 -4.08 -0.408 0.69664E+04 101 laumontite 2.88 2.76 -0.12 -0.008 0.20932E+03 103 leucite 4.12 0.94 -3.18 -0.318 0.54259E+04 105 lizardite 23.24 19.58 -3.67 -0.306 0.62616E+04 107 magnetite 20.09 19.15 -0.94 -0.077 0.16045E+04 108 minnesotaite 10.39 6.03 -4.35 -0.256 0.74345E+04 110 magnesioferrite 26.21 21.38 -4.84 -0.395 0.82566E+04 113 margarite 17.32 13.84 -3.48 -0.139 0.59484E+04 120 muscovite 2.58 1.74 -0.85 -0.050 0.14430E+04 121 paragonite 4.24 3.84 -0.40 -0.023 0.68209E+03 122 nepheline 8.34 6.47 -1.87 -0.267 0.31897E+04 134 phlogopite-Na 29.65 26.05 -3.60 -0.200 0.61447E+04 136 prehnite 19.37 18.44 -0.94 -0.055 0.15981E+04 138 pumpellyite-Fe 46.27 45.57 -0.70 -0.016 0.12023E+04 139 pumpellyite-Mg 48.99 47.79 -1.20 -0.027 0.20497E+04 145 pyroxmangite 7.40 5.28 -2.12 -0.423 0.36138E+04 146 pyrophyllite -6.18 -9.49 -3.31 -0.207 0.56532E+04 147 quartz -2.99 -3.43 -0.44 -0.146 0.74820E+03 152 rhodonite 7.45 5.28 -2.16 -0.433 0.36941E+04 153 sanidine -1.28 -2.49 -1.21 -0.093 0.20677E+04 156 sillimanite 5.26 0.80 -4.47 -0.447 0.76244E+04 164 stilpnomelane-Fe 13.02 12.55 -0.46 -0.014 0.79299E+03 165 stilpnomelane-Mg 27.44 23.70 -3.74 -0.112 0.63914E+04 171 talc 16.49 12.72 -3.77 -0.222 0.64366E+04 174 tephroite 18.09 13.99 -4.09 -0.585 0.69900E+04 177 topaz-H 4.62 0.80 -3.82 -0.347 0.65265E+04 178 tridymite -2.63 -3.43 -0.80 -0.267 0.13682E+04 187 wairakite 3.95 2.76 -1.19 -0.070 0.20313E+04 188 walstromite 11.51 8.82 -2.69 -0.538 0.45920E+04 189 wollastonite 10.46 8.82 -1.64 -0.328 0.28024E+04 190 pseudo-wollastonite 11.00 8.82 -2.18 -0.436 0.37223E+04 191 zoisite 22.85 20.55 -2.30 -0.105 0.39298E+04 192 akaganeite 7.75 6.28 -1.47 -0.318 0.25125E+04 193 beidellite-Ca -1.65 -5.64 -3.99 -0.247 0.68166E+04 195 beidellite-K -1.52 -5.78 -4.26 -0.261 0.72781E+04 196 beidellite-Mg -1.79 -6.20 -4.42 -0.273 0.75387E+04 197 beidellite-Na -1.34 -5.09 -3.75 -0.229 0.63973E+04 199 chalcedony -2.80 -3.43 -0.63 -0.208 0.10675E+04 201 montmorillonite-Ca -2.29 -5.26 -2.96 -0.183 0.50619E+04 202 montmorillonite-K -2.24 -5.40 -3.16 -0.194 0.54016E+04 203 montmorillonite-Mg -2.48 -5.82 -3.34 -0.207 0.57072E+04 204 montmorillonite-Na -2.04 -4.71 -2.67 -0.163 0.45565E+04 205 nontronite-Ca 3.21 2.70 -0.51 -0.033 0.87076E+03 206 nontronite-H 2.53 0.68 -1.85 -0.124 0.31571E+04 207 nontronite-K 3.34 2.56 -0.78 -0.050 0.13337E+04 208 nontronite-Mg 3.07 2.14 -0.94 -0.061 0.16001E+04 209 nontronite-Na 3.52 3.25 -0.27 -0.017 0.45458E+03 224 tobermorite 9.82 6.77 -3.05 -0.832 0.52052E+04 233 boehmite 4.41 2.11 -2.29 -0.382 0.39176E+04 235 ferrous-oxide 9.81 6.58 -3.23 -0.808 0.55153E+04 240 silica-amorphous -2.09 -3.43 -1.34 -0.445 0.22817E+04 242 an20ab80 2.02 1.62 -0.40 -0.031 0.68582E+03 243 an25ab75 2.65 2.12 -0.53 -0.041 0.90424E+03 244 an30ab70 3.28 2.62 -0.66 -0.051 0.11323E+04 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 10 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 8.7990000 Water: Moles liquid = 0.5543E+02 kg liquid = 0.9985E+00 Moles total = 0.5540E+02 kg total = 0.9980E+00 Activity = 1.0000 Stoichiometric ionic strength = .4833524E-02 Osmotic coef. = 0.9629 True ionic strength = .8435987E-02 Chg. balance for total moles = 0.6640E-13 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.14759E-09 -9.8309 0.13000E-09 -9.8861 0.88083E+00 -0.0551 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13788E-03 -3.8605 0.12109E-03 -3.9169 0.87822E+00 -0.0564 4 SO4-- 0.25526E-04 -4.5930 0.16118E-04 -4.7927 0.63146E+00 -0.1997 5 HCO3- 0.67592E-05 -5.1701 0.59403E-05 -5.2262 0.87885E+00 -0.0561 6 HS- 0.44498E-12 -12.3517 0.39082E-12 -12.4080 0.87829E+00 -0.0564 7 Al+++ 0.85606E-27 -27.0675 0.30915E-27 -27.5098 0.36113E+00 -0.4423 8 H4SiO4 0.37357E-03 -3.4276 0.37357E-03 -3.4276 0.10000E+01 0.0000 9 Ca++ 0.40157E-07 -7.3962 0.25267E-07 -7.5974 0.62921E+00 -0.2012 10 Mg++ 0.16832E-10 -10.7739 0.10567E-10 -10.9760 0.62779E+00 -0.2022 11 Fe++ 0.99260E-13 -13.0032 0.62348E-13 -13.2052 0.62813E+00 -0.2019 12 K+ 0.65770E-04 -4.1820 0.57809E-04 -4.2380 0.87896E+00 -0.0560 13 Na+ 0.83378E-02 -2.0789 0.73219E-02 -2.1354 0.87816E+00 -0.0564 14 Mn++ 0.13333E-10 -10.8751 0.83783E-11 -11.0768 0.62839E+00 -0.2018 15 HPO4-- 0.42606E-06 -6.3705 0.26906E-06 -6.5702 0.63151E+00 -0.1996 16 HSiO3- 0.30553E-02 -2.5150 0.26832E-02 -2.5713 0.87822E+00 -0.0564 17 Ca(HSiO3)+ 0.17564E-08 -8.7554 0.15440E-08 -8.8114 0.87905E+00 -0.0560 18 Mg(HSiO3)+ 0.91419E-12 -12.0390 0.80362E-12 -12.0949 0.87905E+00 -0.0560 19 NaHSiO3,aq 0.31775E-03 -3.4979 0.31775E-03 -3.4979 0.10000E+01 0.0000 20 AlO+ 0.28310E-14 -14.5481 0.24886E-14 -14.6040 0.87905E+00 -0.0560 22 HAlO2,aq 0.38123E-08 -8.4188 0.38123E-08 -8.4188 0.10000E+01 0.0000 23 AlO2- 0.73980E-04 -4.1309 0.64913E-04 -4.1877 0.87744E+00 -0.0568 24 CH4,aq 0.14012E-18 -18.8535 0.13991E-18 -18.8541 0.99851E+00 -0.0006 29 CO,aq 0.58372E-19 -19.2338 0.58372E-19 -19.2338 0.10000E+01 0.0000 30 CO2,aq 0.16526E-08 -8.7818 0.16501E-08 -8.7825 0.99851E+00 -0.0006 31 CO3-2 0.63272E-05 -5.1988 0.39912E-05 -5.3989 0.63080E+00 -0.2001 32 CaCO3,aq 0.12645E-08 -8.8981 0.12645E-08 -8.8981 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.43584E-11 -11.3607 0.38313E-11 -11.4167 0.87905E+00 -0.0560 34 CaCl+ 0.56327E-11 -11.2493 0.49515E-11 -11.3053 0.87905E+00 -0.0560 35 CaCl2,aq 0.14245E-15 -15.8463 0.14245E-15 -15.8463 0.10000E+01 0.0000 36 CaOH+ 0.15758E-07 -7.8025 0.13852E-07 -7.8585 0.87905E+00 -0.0560 37 CaSO4,aq 0.12932E-09 -9.8883 0.12932E-09 -9.8883 0.10000E+01 0.0000 38 HCl,aq 0.28847E-14 -14.5399 0.28847E-14 -14.5399 0.10000E+01 0.0000 43 FeCl+ 0.13594E-16 -16.8666 0.11950E-16 -16.9226 0.87905E+00 -0.0560 46 FeO,aq 0.14338E-09 -9.8435 0.14338E-09 -9.8435 0.10000E+01 0.0000 47 FeOH+ 0.17759E-10 -10.7506 0.15611E-10 -10.8066 0.87905E+00 -0.0560 48 HFeO2- 0.13140E-07 -7.8814 0.11540E-07 -7.9378 0.87822E+00 -0.0564 49 FeO+ 0.11288E-14 -14.9474 0.99229E-15 -15.0034 0.87905E+00 -0.0560 51 FeO2- 0.13680E-07 -7.8639 0.12014E-07 -7.9203 0.87822E+00 -0.0564 52 HFeO2,aq 0.19864E-09 -9.7019 0.19864E-09 -9.7019 0.10000E+01 0.0000 53 H2,aq 0.14103E-08 -8.8507 0.14082E-08 -8.8513 0.99851E+00 -0.0006 54 KCl,aq 0.12687E-09 -9.8966 0.12687E-09 -9.8966 0.10000E+01 0.0000 55 KHSO4,aq 0.34249E-18 -18.4654 0.34249E-18 -18.4654 0.10000E+01 0.0000 56 KOH,aq 0.18990E-06 -6.7215 0.18990E-06 -6.7215 0.10000E+01 0.0000 57 KSO4- 0.16464E-07 -7.7835 0.14459E-07 -7.8399 0.87822E+00 -0.0564 58 MgCO3,aq 0.13256E-12 -12.8776 0.13256E-12 -12.8776 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.18626E-14 -14.7299 0.16373E-14 -14.7859 0.87905E+00 -0.0560 60 MgCl+ 0.21351E-14 -14.6706 0.18769E-14 -14.7266 0.87905E+00 -0.0560 61 MgOH+ 0.36467E-10 -10.4381 0.32057E-10 -10.4941 0.87905E+00 -0.0560 63 MnO,aq 0.51340E-09 -9.2895 0.51340E-09 -9.2895 0.10000E+01 0.0000 64 MnOH+ 0.22170E-09 -9.6542 0.19488E-09 -9.7102 0.87905E+00 -0.0560 65 MnO2-2 0.15982E-11 -11.7964 0.10082E-11 -11.9965 0.63080E+00 -0.2001 66 HMnO2- 0.32695E-10 -10.4855 0.28714E-10 -10.5419 0.87822E+00 -0.0564 69 MnCl+ 0.71072E-14 -14.1483 0.62476E-14 -14.2043 0.87905E+00 -0.0560 70 MnSO4,aq 0.38987E-13 -13.4091 0.38987E-13 -13.4091 0.10000E+01 0.0000 71 NaCl,aq 0.29383E-06 -6.5319 0.29383E-06 -6.5319 0.10000E+01 0.0000 72 NaOH,aq 0.24198E-04 -4.6162 0.24198E-04 -4.6162 0.10000E+01 0.0000 74 OH- 0.50652E-02 -2.2954 0.44444E-02 -2.3522 0.87744E+00 -0.0568 79 HPO3-2 0.18718E-17 -17.7277 0.11807E-17 -17.9278 0.63080E+00 -0.2001 82 H3PO4,aq 0.31803E-16 -16.4975 0.31803E-16 -16.4975 0.10000E+01 0.0000 83 H2PO4- 0.73438E-09 -9.1341 0.64525E-09 -9.1903 0.87863E+00 -0.0562 84 PO4-3 0.45645E-08 -8.3406 0.16886E-08 -8.7725 0.36994E+00 -0.4319 87 H2P2O7-2 0.51753E-19 -19.2861 0.32646E-19 -19.4862 0.63080E+00 -0.2001 88 HP2O7-3 0.13880E-15 -15.8576 0.50142E-16 -16.2998 0.36127E+00 -0.4422 89 P2O7-4 0.54816E-15 -15.2611 0.92144E-16 -16.0355 0.16810E+00 -0.7744 90 H2S,aq 0.15726E-15 -15.8034 0.15702E-15 -15.8040 0.99851E+00 -0.0006 97 SO3-2 0.46429E-14 -14.3332 0.29496E-14 -14.5302 0.63529E+00 -0.1970 98 HSO3- 0.27338E-16 -16.5632 0.24008E-16 -16.6196 0.87822E+00 -0.0564 99 HSO4- 0.22962E-11 -11.6390 0.20194E-11 -11.6948 0.87946E+00 -0.0558 Charge balance for all species = 0.6753E-13 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.1475895E-09 -.8764914E-02 -.8829254E+01 0.0000 2 H2O 0.1000000E+01 0.5551011E+02 0.9994367E+06 0.0000 3 Cl- 0.1378840E-03 0.1381779E-03 0.4895910E+01 5.9692 4 SO4-- 0.2552554E-04 0.2554352E-04 0.2452292E+01 14.9794 5 HCO3- 0.6759181E-05 0.1308930E-04 0.7981977E+00 4.6599 6 HS- 0.4449771E-12 -.1381811E-08 -.4567208E-04 -2.5220 7 Al+++ 0.8560635E-27 0.7398390E-04 0.1995010E+01 2.1483 8 H4SiO4 0.3735728E-03 0.3746587E-02 0.3598906E+03 -3.4276 9 Ca++ 0.4015678E-07 0.5907471E-07 0.2366189E-02 12.1747 10 Mg++ 0.1683234E-10 0.5435034E-10 0.1320580E-05 8.7961 11 Fe++ 0.9925972E-13 0.2718006E-07 0.1517022E-02 6.5669 12 K+ 0.6576966E-04 0.6597615E-04 0.2578265E+01 5.6480 13 Na+ 0.8337786E-02 0.8680028E-02 0.1994334E+03 7.7507 14 Mn++ 0.1333306E-10 0.7827674E-09 0.4297810E-04 8.6953 15 HPO4-- 0.4260581E-06 0.4313570E-06 0.4137660E-01 13.2020 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.1456853E+00 -.8751989E-02 -.1369333E+00 0.0000000E+00 2 H2O 0.5539795E+02 0.5542826E+02 -.3030659E-01 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.2693548E-03 0.2550585E-04 0.2438489E-03 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.2438503E-03 -.1379773E-08 -.2438489E-03 0.0000000E+00 7 Al+++ 0.2869127E-01 0.7387480E-04 0.2861739E-01 0.0000000E+00 8 H4SiO4 0.9162208E-01 0.3741062E-02 0.8788102E-01 0.0000000E+00 9 Ca++ 0.1013458E-01 0.5898760E-07 0.1013452E-01 0.0000000E+00 10 Mg++ 0.6983333E-02 0.5427020E-10 0.6983333E-02 0.0000000E+00 11 Fe++ 0.6273763E-02 0.2713998E-07 0.6273735E-02 0.0000000E+00 12 K+ 0.1868153E-02 0.6587886E-04 0.1802274E-02 0.0000000E+00 13 Na+ 0.1120496E-01 0.8667228E-02 0.2537732E-02 0.0000000E+00 14 Mn++ 0.1525623E-03 0.7816131E-09 0.1525615E-03 0.0000000E+00 15 HPO4-- 0.5206876E-04 0.4307209E-06 0.5163804E-04 0.0000000E+00 Chg. balance for solid moles: -.9595E-17 Mass of aqueous solution: 0.999119E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 8.7990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 0.2538E-02 -2.596 0.6654 -0.177 6.918 0.2554 apatite-OH 0.1721E-04 -4.764 0.8646E-02 -2.063 0.8989E-01 0.2747E-02 clinochlore 0.1397E-02 -2.855 0.7763 -0.110 8.071 0.2953 daphnite 0.8646E-03 -3.063 0.6169 -0.210 6.414 0.1869 chlorite-Mn 0.3051E-04 -4.516 0.2163E-01 -1.665 0.2249 0.6894E-02 hematite 0.9082E-03 -3.042 0.1450 -0.839 1.508 0.2749E-01 lawsonite 0.1751E-03 -3.757 0.5503E-01 -1.259 0.5721 0.1775E-01 microcline 0.1802E-02 -2.744 0.5016 -0.300 5.215 0.1960 stilbite 0.9605E-02 -2.018 6.769 0.830 70.37 3.157 prehnite-Fe 0.1344E-03 -3.872 0.5928E-01 -1.227 0.6163 0.1989E-01 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.6094E+00 0.6094E+00 1.0000 -0.215 daphnite 0.3773E+00 0.3773E+00 1.0000 -0.423 chlorite-Mn 0.1331E-01 0.1331E-01 1.0000 -1.876 hematite 0.1000E+01 0.1000E+01 1.0000 0.000 lawsonite 0.1000E+01 0.1000E+01 1.0000 0.000 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 prehnite-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 9.618497 g Volume = 4.165376 cm3 Porosity: 7.8375% V(tot) - V(min): 0.35422E+00 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 8.7990000 g log = 0.9444 Original solution: 1000.0103000 g Original solution / Rock added: 113.65 (Water/Rock Ratio), log = 2.0556 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0203 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.1000E+01 0.9860 0.1006E+01 0.1020E+01 CO2,gas 0.1718E-06 1.0071 0.1765E-06 0.1753E-06 CH4,gas 0.1993E-15 1.0125 0.2059E-15 0.2034E-15 H2,gas 0.1811E-05 1.0005 0.1849E-05 0.1848E-05 H2S,gas 0.4247E-14 0.9960 0.4316E-14 0.4334E-14 S2,gas 0.2005E-36 1.0000 0.2046E-36 0.2046E-36 CO,gas 0.8526E-16 1.0000 0.8699E-16 0.8699E-16 SO3,gas 0.1009E-39 1.0000 0.1030E-39 0.1030E-39 SO2,gas 0.7261E-23 1.0000 0.7408E-23 0.7408E-23 HCl,gas 0.4989E-17 1.0000 0.5090E-17 0.5090E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 16 albite -0.38 -0.38 0.00 0.000 -0.94784E-12 32 apatite-OH -18.15 -18.15 0.00 0.000 -0.12132E-10 46 clinochlore 39.07 39.07 0.00 0.000 -0.24265E-10 47 daphnite 28.97 28.97 0.00 0.000 -0.18198E-10 48 chlorite-Mn 46.87 46.87 0.00 0.000 -0.24265E-10 90 hematite 12.57 12.57 0.00 0.000 0.30331E-11 102 lawsonite 9.62 9.62 0.00 0.000 -0.12132E-10 116 microcline -2.49 -2.49 0.00 0.000 0.15165E-11 137 prehnite-Fe 22.50 22.50 0.00 0.000 0.00000E+00 163 stilbite -7.52 -7.52 0.00 0.000 -0.90992E-11 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -15.11 -8.45 -2.817 0.14432E+05 -6.753 3 CH4,gas 4.54 -12.84 -17.39 -4.346 0.29685E+05 -15.686 4 H2,gas 8.00 0.57 -7.43 -4.247 0.12690E+05 -5.733 5 H2S,gas -6.23 -22.29 -16.06 -8.032 0.27429E+05 -14.365 6 S2,gas -7.34 -45.72 -38.39 -5.906 0.65547E+05 -36.689 7 CO,gas 3.21 -14.54 -17.76 -5.464 0.30324E+05 -16.061 8 SO3,gas 17.12 -24.56 -41.69 -10.422 0.71178E+05 -39.987 9 SO2,gas 0.83 -24.00 -24.83 -6.621 0.42395E+05 -23.130 10 HCl,gas 5.19 -13.80 -18.99 -9.496 0.32429E+05 -17.293 11 acmite 7.71 7.18 -0.53 -0.055 0.90700E+03 15 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 19 spessartine 24.46 20.10 -4.36 -0.218 0.74408E+04 20 analcite 3.32 3.04 -0.28 -0.031 0.47485E+03 21 andalusite 5.00 0.87 -4.13 -0.413 0.70561E+04 22 andradite 39.01 38.81 -0.20 -0.010 0.34401E+03 23 grossular 32.73 30.54 -2.19 -0.110 0.37456E+04 26 annite 20.12 17.21 -2.91 -0.162 0.49672E+04 27 phlogopite 27.06 23.90 -3.16 -0.176 0.54005E+04 29 anorthite 12.71 9.62 -3.09 -0.238 0.52833E+04 35 aragonite 0.97 -2.94 -3.90 -1.301 0.66662E+04 36 brucite 12.57 8.80 -3.77 -0.754 0.64414E+04 37 calcite 0.81 -2.94 -3.75 -1.250 0.64019E+04 38 carnegieite-low 9.02 6.47 -2.55 -0.365 0.43573E+04 39 carnegieite-high 10.09 6.47 -3.62 -0.517 0.61843E+04 40 carpholite-Mg 8.58 6.24 -2.34 -0.156 0.40034E+04 41 carpholite-Fe 6.71 4.01 -2.70 -0.180 0.46175E+04 42 celadonite 5.34 2.88 -2.46 -0.145 0.41998E+04 43 celadonite-Fe 3.88 0.65 -3.22 -0.190 0.55044E+04 44 chrysotile 23.89 19.53 -4.36 -0.363 0.74436E+04 50 chloritoid-Mg 13.20 9.67 -3.53 -0.236 0.60318E+04 51 chloritoid-Fe 9.17 7.44 -1.74 -0.116 0.29670E+04 52 chloritoid-Mn 11.40 9.56 -1.84 -0.122 0.31362E+04 54 coesite -2.38 -3.43 -1.05 -0.351 0.17955E+04 59 corundum 8.38 4.30 -4.09 -0.371 0.69775E+04 61 cristobalite -2.56 -3.43 -0.87 -0.289 0.14809E+04 63 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71234E+04 65 diaspore 2.87 2.15 -0.73 -0.121 0.12385E+04 67 diopside 16.18 14.12 -2.07 -0.207 0.35274E+04 68 hedenbergite 14.21 11.89 -2.32 -0.232 0.39647E+04 75 epidote 24.67 24.65 -0.02 -0.001 0.40501E+02 76 clinozoisite 22.81 20.51 -2.29 -0.104 0.39180E+04 77 epidote-Fe 29.84 28.78 -1.06 -0.055 0.18097E+04 78 fayalite 14.05 9.71 -4.34 -0.620 0.74096E+04 79 ferrosilite 11.15 6.28 -4.87 -0.487 0.83168E+04 83 gibbsite 4.08 2.15 -1.93 -0.276 0.32971E+04 84 glaucophane 22.97 18.77 -4.21 -0.114 0.71878E+04 87 greenalite 16.14 12.85 -3.29 -0.274 0.56244E+04 91 heulandite -5.83 -7.52 -1.69 -0.077 0.28938E+04 95 jadeite 4.22 3.04 -1.17 -0.117 0.20003E+04 96 julgoldite 70.43 66.40 -4.03 -0.105 0.68774E+04 97 kalsilite 7.58 4.37 -3.22 -0.459 0.54898E+04 98 kaolinite -1.33 -2.56 -1.23 -0.111 0.20930E+04 99 kyanite 4.88 0.87 -4.01 -0.401 0.68420E+04 101 laumontite 2.88 2.76 -0.12 -0.008 0.20932E+03 103 leucite 4.12 0.94 -3.18 -0.318 0.54259E+04 105 lizardite 23.24 19.53 -3.71 -0.309 0.63362E+04 107 magnetite 20.09 19.13 -0.95 -0.078 0.16294E+04 108 minnesotaite 10.39 5.99 -4.40 -0.259 0.75092E+04 110 magnesioferrite 26.21 21.36 -4.85 -0.396 0.82815E+04 113 margarite 17.32 13.91 -3.41 -0.136 0.58240E+04 120 muscovite 2.58 1.81 -0.77 -0.045 0.13186E+04 121 paragonite 4.24 3.91 -0.33 -0.019 0.55772E+03 122 nepheline 8.34 6.47 -1.87 -0.267 0.31897E+04 134 phlogopite-Na 29.65 26.00 -3.64 -0.202 0.62194E+04 136 prehnite 19.37 18.36 -1.01 -0.059 0.17225E+04 138 pumpellyite-Fe 46.27 45.44 -0.83 -0.018 0.14137E+04 139 pumpellyite-Mg 48.99 47.67 -1.32 -0.029 0.22612E+04 145 pyroxmangite 7.40 5.27 -2.13 -0.426 0.36387E+04 146 pyrophyllite -6.18 -9.41 -3.24 -0.202 0.55289E+04 147 quartz -2.99 -3.43 -0.44 -0.146 0.74820E+03 152 rhodonite 7.45 5.27 -2.18 -0.436 0.37189E+04 153 sanidine -1.28 -2.49 -1.21 -0.093 0.20677E+04 156 sillimanite 5.26 0.87 -4.39 -0.439 0.75000E+04 164 stilpnomelane-Fe 13.02 12.53 -0.48 -0.014 0.82408E+03 165 stilpnomelane-Mg 27.44 23.68 -3.76 -0.112 0.64225E+04 171 talc 16.49 12.68 -3.81 -0.224 0.65112E+04 174 tephroite 18.09 13.96 -4.12 -0.589 0.70397E+04 177 topaz-H 4.62 0.87 -3.75 -0.341 0.64021E+04 178 tridymite -2.63 -3.43 -0.80 -0.267 0.13682E+04 187 wairakite 3.95 2.76 -1.19 -0.070 0.20313E+04 188 walstromite 11.51 8.75 -2.76 -0.552 0.47164E+04 189 wollastonite 10.46 8.75 -1.71 -0.343 0.29268E+04 190 pseudo-wollastonite 11.00 8.75 -2.25 -0.451 0.38466E+04 191 zoisite 22.85 20.51 -2.34 -0.106 0.39920E+04 192 akaganeite 7.75 6.28 -1.47 -0.318 0.25125E+04 193 beidellite-Ca -1.65 -5.56 -3.92 -0.242 0.66922E+04 195 beidellite-K -1.52 -5.71 -4.19 -0.257 0.71538E+04 196 beidellite-Mg -1.79 -6.12 -4.33 -0.268 0.73979E+04 197 beidellite-Na -1.34 -5.02 -3.67 -0.225 0.62729E+04 199 chalcedony -2.80 -3.43 -0.63 -0.208 0.10675E+04 201 montmorillonite-Ca -2.29 -5.21 -2.92 -0.181 0.49868E+04 202 montmorillonite-K -2.24 -5.36 -3.12 -0.191 0.53265E+04 203 montmorillonite-Mg -2.48 -5.77 -3.29 -0.203 0.56156E+04 204 montmorillonite-Na -2.04 -4.66 -2.62 -0.161 0.44814E+04 205 nontronite-Ca 3.21 2.70 -0.51 -0.033 0.87076E+03 206 nontronite-H 2.53 0.70 -1.84 -0.123 0.31365E+04 207 nontronite-K 3.34 2.56 -0.78 -0.050 0.13337E+04 208 nontronite-Mg 3.07 2.15 -0.93 -0.060 0.15837E+04 209 nontronite-Na 3.52 3.25 -0.27 -0.017 0.45458E+03 224 tobermorite 9.82 6.71 -3.11 -0.848 0.53089E+04 233 boehmite 4.41 2.15 -2.26 -0.376 0.38555E+04 235 ferrous-oxide 9.81 6.57 -3.24 -0.811 0.55402E+04 240 silica-amorphous -2.09 -3.43 -1.34 -0.445 0.22817E+04 242 an20ab80 2.02 1.62 -0.40 -0.031 0.68582E+03 243 an25ab75 2.65 2.12 -0.53 -0.041 0.90424E+03 244 an30ab70 3.28 2.62 -0.66 -0.051 0.11323E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 0.4000000 g Current total amount of reactant added: 8.7990000 g New total amount of reactant added: 9.1990000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.6640E-13 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 7 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 9.1990000 Water: Moles liquid = 0.5542E+02 kg liquid = 0.9985E+00 Moles total = 0.5539E+02 kg total = 0.9979E+00 Activity = 1.0000 Stoichiometric ionic strength = .4833531E-02 Osmotic coef. = 0.9629 True ionic strength = .8435993E-02 Chg. balance for total moles = 0.6640E-13 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.14759E-09 -9.8309 0.13000E-09 -9.8861 0.88083E+00 -0.0551 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13789E-03 -3.8605 0.12110E-03 -3.9169 0.87822E+00 -0.0564 4 SO4-- 0.25527E-04 -4.5930 0.16119E-04 -4.7927 0.63146E+00 -0.1997 5 HCO3- 0.67595E-05 -5.1701 0.59406E-05 -5.2262 0.87885E+00 -0.0561 6 HS- 0.44500E-12 -12.3516 0.39083E-12 -12.4080 0.87829E+00 -0.0564 7 Al+++ 0.85607E-27 -27.0675 0.30915E-27 -27.5098 0.36113E+00 -0.4423 8 H4SiO4 0.37357E-03 -3.4276 0.37357E-03 -3.4276 0.10000E+01 0.0000 9 Ca++ 0.40157E-07 -7.3962 0.25267E-07 -7.5974 0.62921E+00 -0.2012 10 Mg++ 0.16832E-10 -10.7739 0.10567E-10 -10.9760 0.62779E+00 -0.2022 11 Fe++ 0.99260E-13 -13.0032 0.62348E-13 -13.2052 0.62813E+00 -0.2019 12 K+ 0.65770E-04 -4.1820 0.57809E-04 -4.2380 0.87896E+00 -0.0560 13 Na+ 0.83378E-02 -2.0789 0.73219E-02 -2.1354 0.87816E+00 -0.0564 14 Mn++ 0.13333E-10 -10.8751 0.83783E-11 -11.0768 0.62839E+00 -0.2018 15 HPO4-- 0.42606E-06 -6.3705 0.26906E-06 -6.5702 0.63151E+00 -0.1996 16 HSiO3- 0.30553E-02 -2.5150 0.26832E-02 -2.5713 0.87822E+00 -0.0564 17 Ca(HSiO3)+ 0.17564E-08 -8.7554 0.15440E-08 -8.8114 0.87905E+00 -0.0560 18 Mg(HSiO3)+ 0.91419E-12 -12.0390 0.80362E-12 -12.0949 0.87905E+00 -0.0560 19 NaHSiO3,aq 0.31775E-03 -3.4979 0.31775E-03 -3.4979 0.10000E+01 0.0000 20 AlO+ 0.28310E-14 -14.5481 0.24886E-14 -14.6040 0.87905E+00 -0.0560 22 HAlO2,aq 0.38123E-08 -8.4188 0.38123E-08 -8.4188 0.10000E+01 0.0000 23 AlO2- 0.73980E-04 -4.1309 0.64913E-04 -4.1877 0.87744E+00 -0.0568 24 CH4,aq 0.14013E-18 -18.8535 0.13992E-18 -18.8541 0.99851E+00 -0.0006 29 CO,aq 0.58375E-19 -19.2338 0.58375E-19 -19.2338 0.10000E+01 0.0000 30 CO2,aq 0.16526E-08 -8.7818 0.16502E-08 -8.7825 0.99851E+00 -0.0006 31 CO3-2 0.63275E-05 -5.1988 0.39914E-05 -5.3989 0.63080E+00 -0.2001 32 CaCO3,aq 0.12645E-08 -8.8981 0.12645E-08 -8.8981 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.43586E-11 -11.3607 0.38314E-11 -11.4166 0.87905E+00 -0.0560 34 CaCl+ 0.56330E-11 -11.2493 0.49517E-11 -11.3052 0.87905E+00 -0.0560 35 CaCl2,aq 0.14246E-15 -15.8463 0.14246E-15 -15.8463 0.10000E+01 0.0000 36 CaOH+ 0.15758E-07 -7.8025 0.13852E-07 -7.8585 0.87905E+00 -0.0560 37 CaSO4,aq 0.12933E-09 -9.8883 0.12933E-09 -9.8883 0.10000E+01 0.0000 38 HCl,aq 0.28848E-14 -14.5399 0.28848E-14 -14.5399 0.10000E+01 0.0000 43 FeCl+ 0.13595E-16 -16.8666 0.11951E-16 -16.9226 0.87905E+00 -0.0560 46 FeO,aq 0.14338E-09 -9.8435 0.14338E-09 -9.8435 0.10000E+01 0.0000 47 FeOH+ 0.17759E-10 -10.7506 0.15611E-10 -10.8066 0.87905E+00 -0.0560 48 HFeO2- 0.13140E-07 -7.8814 0.11540E-07 -7.9378 0.87822E+00 -0.0564 49 FeO+ 0.11288E-14 -14.9474 0.99229E-15 -15.0034 0.87905E+00 -0.0560 51 FeO2- 0.13680E-07 -7.8639 0.12014E-07 -7.9203 0.87822E+00 -0.0564 52 HFeO2,aq 0.19864E-09 -9.7019 0.19864E-09 -9.7019 0.10000E+01 0.0000 53 H2,aq 0.14103E-08 -8.8507 0.14082E-08 -8.8513 0.99851E+00 -0.0006 54 KCl,aq 0.12688E-09 -9.8966 0.12688E-09 -9.8966 0.10000E+01 0.0000 55 KHSO4,aq 0.34251E-18 -18.4653 0.34251E-18 -18.4653 0.10000E+01 0.0000 56 KOH,aq 0.18990E-06 -6.7215 0.18990E-06 -6.7215 0.10000E+01 0.0000 57 KSO4- 0.16465E-07 -7.7834 0.14460E-07 -7.8398 0.87822E+00 -0.0564 58 MgCO3,aq 0.13256E-12 -12.8776 0.13256E-12 -12.8776 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.18626E-14 -14.7299 0.16374E-14 -14.7859 0.87905E+00 -0.0560 60 MgCl+ 0.21352E-14 -14.6706 0.18770E-14 -14.7265 0.87905E+00 -0.0560 61 MgOH+ 0.36467E-10 -10.4381 0.32057E-10 -10.4941 0.87905E+00 -0.0560 63 MnO,aq 0.51340E-09 -9.2895 0.51340E-09 -9.2895 0.10000E+01 0.0000 64 MnOH+ 0.22170E-09 -9.6542 0.19488E-09 -9.7102 0.87905E+00 -0.0560 65 MnO2-2 0.15982E-11 -11.7964 0.10082E-11 -11.9965 0.63080E+00 -0.2001 66 HMnO2- 0.32695E-10 -10.4855 0.28714E-10 -10.5419 0.87822E+00 -0.0564 69 MnCl+ 0.71075E-14 -14.1483 0.62478E-14 -14.2043 0.87905E+00 -0.0560 70 MnSO4,aq 0.38988E-13 -13.4091 0.38988E-13 -13.4091 0.10000E+01 0.0000 71 NaCl,aq 0.29384E-06 -6.5319 0.29384E-06 -6.5319 0.10000E+01 0.0000 72 NaOH,aq 0.24198E-04 -4.6162 0.24198E-04 -4.6162 0.10000E+01 0.0000 74 OH- 0.50652E-02 -2.2954 0.44444E-02 -2.3522 0.87744E+00 -0.0568 79 HPO3-2 0.18718E-17 -17.7277 0.11807E-17 -17.9278 0.63080E+00 -0.2001 82 H3PO4,aq 0.31803E-16 -16.4975 0.31803E-16 -16.4975 0.10000E+01 0.0000 83 H2PO4- 0.73438E-09 -9.1341 0.64525E-09 -9.1903 0.87863E+00 -0.0562 84 PO4-3 0.45645E-08 -8.3406 0.16886E-08 -8.7725 0.36994E+00 -0.4319 87 H2P2O7-2 0.51753E-19 -19.2861 0.32646E-19 -19.4862 0.63080E+00 -0.2001 88 HP2O7-3 0.13880E-15 -15.8576 0.50142E-16 -16.2998 0.36127E+00 -0.4422 89 P2O7-4 0.54816E-15 -15.2611 0.92144E-16 -16.0355 0.16810E+00 -0.7744 90 H2S,aq 0.15727E-15 -15.8034 0.15703E-15 -15.8040 0.99851E+00 -0.0006 97 SO3-2 0.46431E-14 -14.3332 0.29497E-14 -14.5302 0.63529E+00 -0.1970 98 HSO3- 0.27339E-16 -16.5632 0.24009E-16 -16.6196 0.87822E+00 -0.0564 99 HSO4- 0.22963E-11 -11.6390 0.20195E-11 -11.6948 0.87946E+00 -0.0558 Charge balance for all species = 0.6519E-13 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.1475895E-09 -.8764910E-02 -.8829251E+01 0.0000 2 H2O 0.1000000E+01 0.5551011E+02 0.9994367E+06 0.0000 3 Cl- 0.1378895E-03 0.1381835E-03 0.4896107E+01 5.9692 4 SO4-- 0.2552657E-04 0.2554455E-04 0.2452391E+01 14.9794 5 HCO3- 0.6759455E-05 0.1308983E-04 0.7982299E+00 4.6599 6 HS- 0.4449956E-12 -.1381810E-08 -.4567205E-04 -2.5220 7 Al+++ 0.8560651E-27 0.7398386E-04 0.1995009E+01 2.1483 8 H4SiO4 0.3735728E-03 0.3746585E-02 0.3598904E+03 -3.4276 9 Ca++ 0.4015682E-07 0.5907483E-07 0.2366193E-02 12.1747 10 Mg++ 0.1683236E-10 0.5435039E-10 0.1320581E-05 8.7961 11 Fe++ 0.9925985E-13 0.2718005E-07 0.1517022E-02 6.5669 12 K+ 0.6576969E-04 0.6597619E-04 0.2578267E+01 5.6480 13 Na+ 0.8337791E-02 0.8680032E-02 0.1994335E+03 7.7507 14 Mn++ 0.1333308E-10 0.7827676E-09 0.4297812E-04 8.6953 15 HPO4-- 0.4260577E-06 0.4313566E-06 0.4137656E-01 13.2020 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.1523087E+00 -.8751632E-02 -.1435571E+00 0.0000000E+00 2 H2O 0.5539294E+02 0.5542602E+02 -.3308225E-01 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.2804401E-03 0.2550585E-04 0.2549343E-03 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.2549356E-03 -.1379717E-08 -.2549343E-03 0.0000000E+00 7 Al+++ 0.2999556E-01 0.7387178E-04 0.2992169E-01 0.0000000E+00 8 H4SiO4 0.9578719E-01 0.3740909E-02 0.9204628E-01 0.0000000E+00 9 Ca++ 0.1059463E-01 0.5898533E-07 0.1059457E-01 0.0000000E+00 10 Mg++ 0.7300794E-02 0.5426805E-10 0.7300794E-02 0.0000000E+00 11 Fe++ 0.6558966E-02 0.2713887E-07 0.6558939E-02 0.0000000E+00 12 K+ 0.1953079E-02 0.6587623E-04 0.1887202E-02 0.0000000E+00 13 Na+ 0.1170706E-01 0.8666882E-02 0.3040175E-02 0.0000000E+00 14 Mn++ 0.1594977E-03 0.7815817E-09 0.1594970E-03 0.0000000E+00 15 HPO4-- 0.5443579E-04 0.4307031E-06 0.5400508E-04 0.0000000E+00 Chg. balance for solid moles: -.2190E-16 Mass of aqueous solution: 0.999079E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 9.1990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 0.3040E-02 -2.517 0.7972 -0.098 7.928 0.3060 apatite-OH 0.1800E-04 -4.745 0.9043E-02 -2.044 0.8993E-01 0.2873E-02 clinochlore 0.1460E-02 -2.836 0.8116 -0.091 8.071 0.3087 daphnite 0.9039E-03 -3.044 0.6449 -0.190 6.414 0.1954 chlorite-Mn 0.3190E-04 -4.496 0.2262E-01 -1.646 0.2249 0.7207E-02 hematite 0.8853E-03 -3.053 0.1414 -0.850 1.406 0.2680E-01 lawsonite 0.9954E-04 -4.002 0.3128E-01 -1.505 0.3111 0.1009E-01 microcline 0.1887E-02 -2.724 0.5253 -0.280 5.224 0.2052 prehnite-Fe 0.2689E-03 -3.570 0.1187 -0.926 1.180 0.3980E-01 stilbite 0.9867E-02 -2.006 6.954 0.842 69.15 3.243 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.6094E+00 0.6094E+00 1.0000 -0.215 daphnite 0.3773E+00 0.3773E+00 1.0000 -0.423 chlorite-Mn 0.1331E-01 0.1331E-01 1.0000 -1.876 hematite 0.1000E+01 0.1000E+01 1.0000 0.000 lawsonite 0.1000E+01 0.1000E+01 1.0000 0.000 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 prehnite-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 10.055608 g Volume = 4.345421 cm3 Porosity: 7.1412% V(tot) - V(min): 0.33418E+00 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 9.1990000 g log = 0.9637 Original solution: 1000.0103000 g Original solution / Rock added: 108.71 (Water/Rock Ratio), log = 2.0363 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0203 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.1000E+01 0.9860 0.1006E+01 0.1020E+01 CO2,gas 0.1718E-06 1.0071 0.1766E-06 0.1753E-06 CH4,gas 0.1994E-15 1.0125 0.2059E-15 0.2034E-15 H2,gas 0.1811E-05 1.0005 0.1849E-05 0.1848E-05 H2S,gas 0.4248E-14 0.9960 0.4317E-14 0.4334E-14 S2,gas 0.2006E-36 1.0000 0.2046E-36 0.2046E-36 CO,gas 0.8526E-16 1.0000 0.8699E-16 0.8699E-16 SO3,gas 0.1010E-39 1.0000 0.1030E-39 0.1030E-39 SO2,gas 0.7261E-23 1.0000 0.7409E-23 0.7409E-23 HCl,gas 0.4989E-17 1.0000 0.5090E-17 0.5090E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 16 albite -0.38 -0.38 0.00 0.000 -0.94784E-12 32 apatite-OH -18.15 -18.15 0.00 0.000 0.00000E+00 46 clinochlore 39.07 39.07 0.00 0.000 -0.36397E-10 47 daphnite 28.97 28.97 0.00 0.000 -0.12132E-10 48 chlorite-Mn 46.87 46.87 0.00 0.000 -0.48529E-10 90 hematite 12.57 12.57 0.00 0.000 0.30331E-11 102 lawsonite 9.62 9.62 0.00 0.000 -0.12132E-10 116 microcline -2.49 -2.49 0.00 0.000 0.15165E-11 137 prehnite-Fe 22.50 22.50 0.00 0.000 -0.48529E-10 163 stilbite -7.52 -7.52 0.00 0.000 0.15165E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -15.11 -8.45 -2.817 0.14432E+05 -6.753 3 CH4,gas 4.54 -12.84 -17.39 -4.346 0.29685E+05 -15.686 4 H2,gas 8.00 0.57 -7.43 -4.247 0.12690E+05 -5.733 5 H2S,gas -6.23 -22.29 -16.06 -8.032 0.27429E+05 -14.365 6 S2,gas -7.34 -45.72 -38.39 -5.906 0.65546E+05 -36.689 7 CO,gas 3.21 -14.54 -17.76 -5.464 0.30324E+05 -16.061 8 SO3,gas 17.12 -24.56 -41.69 -10.422 0.71178E+05 -39.987 9 SO2,gas 0.83 -24.00 -24.83 -6.621 0.42395E+05 -23.130 10 HCl,gas 5.19 -13.80 -18.99 -9.496 0.32429E+05 -17.293 11 acmite 7.71 7.18 -0.53 -0.055 0.90700E+03 15 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 19 spessartine 24.46 20.10 -4.36 -0.218 0.74408E+04 20 analcite 3.32 3.04 -0.28 -0.031 0.47485E+03 21 andalusite 5.00 0.87 -4.13 -0.413 0.70561E+04 22 andradite 39.01 38.81 -0.20 -0.010 0.34401E+03 23 grossular 32.73 30.54 -2.19 -0.110 0.37456E+04 26 annite 20.12 17.21 -2.91 -0.162 0.49672E+04 27 phlogopite 27.06 23.90 -3.16 -0.176 0.54005E+04 29 anorthite 12.71 9.62 -3.09 -0.238 0.52833E+04 35 aragonite 0.97 -2.94 -3.90 -1.301 0.66661E+04 36 brucite 12.57 8.80 -3.77 -0.754 0.64414E+04 37 calcite 0.81 -2.94 -3.75 -1.250 0.64019E+04 38 carnegieite-low 9.02 6.47 -2.55 -0.365 0.43573E+04 39 carnegieite-high 10.09 6.47 -3.62 -0.517 0.61843E+04 40 carpholite-Mg 8.58 6.24 -2.34 -0.156 0.40034E+04 41 carpholite-Fe 6.71 4.01 -2.70 -0.180 0.46175E+04 42 celadonite 5.34 2.88 -2.46 -0.145 0.41998E+04 43 celadonite-Fe 3.88 0.65 -3.22 -0.190 0.55044E+04 44 chrysotile 23.89 19.53 -4.36 -0.363 0.74436E+04 50 chloritoid-Mg 13.20 9.67 -3.53 -0.236 0.60318E+04 51 chloritoid-Fe 9.17 7.44 -1.74 -0.116 0.29670E+04 52 chloritoid-Mn 11.40 9.56 -1.84 -0.122 0.31362E+04 54 coesite -2.38 -3.43 -1.05 -0.351 0.17955E+04 59 corundum 8.38 4.30 -4.09 -0.371 0.69775E+04 61 cristobalite -2.56 -3.43 -0.87 -0.289 0.14809E+04 63 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71234E+04 65 diaspore 2.87 2.15 -0.73 -0.121 0.12385E+04 67 diopside 16.18 14.12 -2.07 -0.207 0.35274E+04 68 hedenbergite 14.21 11.89 -2.32 -0.232 0.39647E+04 75 epidote 24.67 24.65 -0.02 -0.001 0.40501E+02 76 clinozoisite 22.81 20.51 -2.29 -0.104 0.39180E+04 77 epidote-Fe 29.84 28.78 -1.06 -0.055 0.18097E+04 78 fayalite 14.05 9.71 -4.34 -0.620 0.74096E+04 79 ferrosilite 11.15 6.28 -4.87 -0.487 0.83168E+04 83 gibbsite 4.08 2.15 -1.93 -0.276 0.32971E+04 84 glaucophane 22.97 18.77 -4.21 -0.114 0.71878E+04 87 greenalite 16.14 12.85 -3.29 -0.274 0.56244E+04 91 heulandite -5.83 -7.52 -1.69 -0.077 0.28938E+04 95 jadeite 4.22 3.04 -1.17 -0.117 0.20003E+04 96 julgoldite 70.43 66.40 -4.03 -0.105 0.68774E+04 97 kalsilite 7.58 4.37 -3.22 -0.459 0.54898E+04 98 kaolinite -1.33 -2.56 -1.23 -0.111 0.20930E+04 99 kyanite 4.88 0.87 -4.01 -0.401 0.68420E+04 101 laumontite 2.88 2.76 -0.12 -0.008 0.20932E+03 103 leucite 4.12 0.94 -3.18 -0.318 0.54259E+04 105 lizardite 23.24 19.53 -3.71 -0.309 0.63362E+04 107 magnetite 20.09 19.13 -0.95 -0.078 0.16294E+04 108 minnesotaite 10.39 5.99 -4.40 -0.259 0.75092E+04 110 magnesioferrite 26.21 21.36 -4.85 -0.396 0.82815E+04 113 margarite 17.32 13.91 -3.41 -0.136 0.58240E+04 120 muscovite 2.58 1.81 -0.77 -0.045 0.13186E+04 121 paragonite 4.24 3.91 -0.33 -0.019 0.55772E+03 122 nepheline 8.34 6.47 -1.87 -0.267 0.31897E+04 134 phlogopite-Na 29.65 26.00 -3.64 -0.202 0.62194E+04 136 prehnite 19.37 18.36 -1.01 -0.059 0.17225E+04 138 pumpellyite-Fe 46.27 45.44 -0.83 -0.018 0.14137E+04 139 pumpellyite-Mg 48.99 47.67 -1.32 -0.029 0.22612E+04 145 pyroxmangite 7.40 5.27 -2.13 -0.426 0.36387E+04 146 pyrophyllite -6.18 -9.41 -3.24 -0.202 0.55289E+04 147 quartz -2.99 -3.43 -0.44 -0.146 0.74820E+03 152 rhodonite 7.45 5.27 -2.18 -0.436 0.37189E+04 153 sanidine -1.28 -2.49 -1.21 -0.093 0.20677E+04 156 sillimanite 5.26 0.87 -4.39 -0.439 0.75000E+04 164 stilpnomelane-Fe 13.02 12.53 -0.48 -0.014 0.82408E+03 165 stilpnomelane-Mg 27.44 23.68 -3.76 -0.112 0.64225E+04 171 talc 16.49 12.68 -3.81 -0.224 0.65112E+04 174 tephroite 18.09 13.96 -4.12 -0.589 0.70397E+04 177 topaz-H 4.62 0.87 -3.75 -0.341 0.64021E+04 178 tridymite -2.63 -3.43 -0.80 -0.267 0.13682E+04 187 wairakite 3.95 2.76 -1.19 -0.070 0.20313E+04 188 walstromite 11.51 8.75 -2.76 -0.552 0.47164E+04 189 wollastonite 10.46 8.75 -1.71 -0.343 0.29268E+04 190 pseudo-wollastonite 11.00 8.75 -2.25 -0.451 0.38466E+04 191 zoisite 22.85 20.51 -2.34 -0.106 0.39920E+04 192 akaganeite 7.75 6.28 -1.47 -0.318 0.25125E+04 193 beidellite-Ca -1.65 -5.56 -3.92 -0.242 0.66922E+04 195 beidellite-K -1.52 -5.71 -4.19 -0.257 0.71538E+04 196 beidellite-Mg -1.79 -6.12 -4.33 -0.268 0.73979E+04 197 beidellite-Na -1.34 -5.02 -3.67 -0.225 0.62729E+04 199 chalcedony -2.80 -3.43 -0.63 -0.208 0.10675E+04 201 montmorillonite-Ca -2.29 -5.21 -2.92 -0.181 0.49868E+04 202 montmorillonite-K -2.24 -5.36 -3.12 -0.191 0.53265E+04 203 montmorillonite-Mg -2.48 -5.77 -3.29 -0.203 0.56156E+04 204 montmorillonite-Na -2.04 -4.66 -2.62 -0.161 0.44814E+04 205 nontronite-Ca 3.21 2.70 -0.51 -0.033 0.87076E+03 206 nontronite-H 2.53 0.70 -1.84 -0.123 0.31365E+04 207 nontronite-K 3.34 2.56 -0.78 -0.050 0.13337E+04 208 nontronite-Mg 3.07 2.15 -0.93 -0.060 0.15837E+04 209 nontronite-Na 3.52 3.25 -0.27 -0.017 0.45458E+03 224 tobermorite 9.82 6.71 -3.11 -0.848 0.53089E+04 233 boehmite 4.41 2.15 -2.26 -0.376 0.38555E+04 235 ferrous-oxide 9.81 6.57 -3.24 -0.811 0.55402E+04 240 silica-amorphous -2.09 -3.43 -1.34 -0.445 0.22817E+04 242 an20ab80 2.02 1.62 -0.40 -0.031 0.68582E+03 243 an25ab75 2.65 2.12 -0.53 -0.041 0.90424E+03 244 an30ab70 3.28 2.62 -0.66 -0.051 0.11323E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 0.4000000 g Current total amount of reactant added: 9.1990000 g New total amount of reactant added: 9.5990000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.6639E-13 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 7 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 9.5990000 Water: Moles liquid = 0.5542E+02 kg liquid = 0.9984E+00 Moles total = 0.5539E+02 kg total = 0.9978E+00 Activity = 1.0000 Stoichiometric ionic strength = .4833538E-02 Osmotic coef. = 0.9629 True ionic strength = .8435999E-02 Chg. balance for total moles = 0.6639E-13 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.14759E-09 -9.8309 0.13000E-09 -9.8861 0.88083E+00 -0.0551 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13790E-03 -3.8605 0.12110E-03 -3.9168 0.87822E+00 -0.0564 4 SO4-- 0.25528E-04 -4.5930 0.16120E-04 -4.7926 0.63146E+00 -0.1997 5 HCO3- 0.67597E-05 -5.1701 0.59408E-05 -5.2262 0.87885E+00 -0.0561 6 HS- 0.44501E-12 -12.3516 0.39085E-12 -12.4080 0.87829E+00 -0.0564 7 Al+++ 0.85607E-27 -27.0675 0.30915E-27 -27.5098 0.36113E+00 -0.4423 8 H4SiO4 0.37357E-03 -3.4276 0.37357E-03 -3.4276 0.10000E+01 0.0000 9 Ca++ 0.40157E-07 -7.3962 0.25267E-07 -7.5974 0.62921E+00 -0.2012 10 Mg++ 0.16832E-10 -10.7739 0.10567E-10 -10.9760 0.62779E+00 -0.2022 11 Fe++ 0.99260E-13 -13.0032 0.62348E-13 -13.2052 0.62813E+00 -0.2019 12 K+ 0.65770E-04 -4.1820 0.57809E-04 -4.2380 0.87896E+00 -0.0560 13 Na+ 0.83378E-02 -2.0789 0.73219E-02 -2.1354 0.87816E+00 -0.0564 14 Mn++ 0.13333E-10 -10.8751 0.83783E-11 -11.0768 0.62839E+00 -0.2018 15 HPO4-- 0.42606E-06 -6.3705 0.26906E-06 -6.5702 0.63151E+00 -0.1996 16 HSiO3- 0.30553E-02 -2.5150 0.26832E-02 -2.5713 0.87822E+00 -0.0564 17 Ca(HSiO3)+ 0.17564E-08 -8.7554 0.15440E-08 -8.8114 0.87905E+00 -0.0560 18 Mg(HSiO3)+ 0.91419E-12 -12.0390 0.80362E-12 -12.0949 0.87905E+00 -0.0560 19 NaHSiO3,aq 0.31775E-03 -3.4979 0.31775E-03 -3.4979 0.10000E+01 0.0000 20 AlO+ 0.28310E-14 -14.5481 0.24886E-14 -14.6040 0.87905E+00 -0.0560 22 HAlO2,aq 0.38123E-08 -8.4188 0.38123E-08 -8.4188 0.10000E+01 0.0000 23 AlO2- 0.73980E-04 -4.1309 0.64913E-04 -4.1877 0.87744E+00 -0.0568 24 CH4,aq 0.14013E-18 -18.8535 0.13992E-18 -18.8541 0.99851E+00 -0.0006 29 CO,aq 0.58377E-19 -19.2338 0.58377E-19 -19.2338 0.10000E+01 0.0000 30 CO2,aq 0.16527E-08 -8.7818 0.16502E-08 -8.7825 0.99851E+00 -0.0006 31 CO3-2 0.63277E-05 -5.1988 0.39915E-05 -5.3989 0.63080E+00 -0.2001 32 CaCO3,aq 0.12646E-08 -8.8980 0.12646E-08 -8.8980 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.43588E-11 -11.3606 0.38316E-11 -11.4166 0.87905E+00 -0.0560 34 CaCl+ 0.56332E-11 -11.2492 0.49519E-11 -11.3052 0.87905E+00 -0.0560 35 CaCl2,aq 0.14247E-15 -15.8463 0.14247E-15 -15.8463 0.10000E+01 0.0000 36 CaOH+ 0.15758E-07 -7.8025 0.13852E-07 -7.8585 0.87905E+00 -0.0560 37 CaSO4,aq 0.12934E-09 -9.8883 0.12934E-09 -9.8883 0.10000E+01 0.0000 38 HCl,aq 0.28849E-14 -14.5399 0.28849E-14 -14.5399 0.10000E+01 0.0000 43 FeCl+ 0.13596E-16 -16.8666 0.11951E-16 -16.9226 0.87905E+00 -0.0560 46 FeO,aq 0.14338E-09 -9.8435 0.14338E-09 -9.8435 0.10000E+01 0.0000 47 FeOH+ 0.17759E-10 -10.7506 0.15611E-10 -10.8066 0.87905E+00 -0.0560 48 HFeO2- 0.13140E-07 -7.8814 0.11540E-07 -7.9378 0.87822E+00 -0.0564 49 FeO+ 0.11288E-14 -14.9474 0.99229E-15 -15.0034 0.87905E+00 -0.0560 51 FeO2- 0.13680E-07 -7.8639 0.12014E-07 -7.9203 0.87822E+00 -0.0564 52 HFeO2,aq 0.19864E-09 -9.7019 0.19864E-09 -9.7019 0.10000E+01 0.0000 53 H2,aq 0.14103E-08 -8.8507 0.14082E-08 -8.8513 0.99851E+00 -0.0006 54 KCl,aq 0.12688E-09 -9.8966 0.12688E-09 -9.8966 0.10000E+01 0.0000 55 KHSO4,aq 0.34252E-18 -18.4653 0.34252E-18 -18.4653 0.10000E+01 0.0000 56 KOH,aq 0.18990E-06 -6.7215 0.18990E-06 -6.7215 0.10000E+01 0.0000 57 KSO4- 0.16465E-07 -7.7834 0.14460E-07 -7.8398 0.87822E+00 -0.0564 58 MgCO3,aq 0.13257E-12 -12.8776 0.13257E-12 -12.8776 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.18627E-14 -14.7299 0.16374E-14 -14.7858 0.87905E+00 -0.0560 60 MgCl+ 0.21353E-14 -14.6705 0.18770E-14 -14.7265 0.87905E+00 -0.0560 61 MgOH+ 0.36467E-10 -10.4381 0.32057E-10 -10.4941 0.87905E+00 -0.0560 63 MnO,aq 0.51340E-09 -9.2895 0.51340E-09 -9.2895 0.10000E+01 0.0000 64 MnOH+ 0.22170E-09 -9.6542 0.19488E-09 -9.7102 0.87905E+00 -0.0560 65 MnO2-2 0.15982E-11 -11.7964 0.10082E-11 -11.9965 0.63080E+00 -0.2001 66 HMnO2- 0.32695E-10 -10.4855 0.28714E-10 -10.5419 0.87822E+00 -0.0564 69 MnCl+ 0.71078E-14 -14.1483 0.62481E-14 -14.2043 0.87905E+00 -0.0560 70 MnSO4,aq 0.38990E-13 -13.4090 0.38990E-13 -13.4090 0.10000E+01 0.0000 71 NaCl,aq 0.29385E-06 -6.5319 0.29385E-06 -6.5319 0.10000E+01 0.0000 72 NaOH,aq 0.24198E-04 -4.6162 0.24198E-04 -4.6162 0.10000E+01 0.0000 74 OH- 0.50651E-02 -2.2954 0.44444E-02 -2.3522 0.87744E+00 -0.0568 79 HPO3-2 0.18718E-17 -17.7277 0.11807E-17 -17.9279 0.63080E+00 -0.2001 82 H3PO4,aq 0.31803E-16 -16.4975 0.31803E-16 -16.4975 0.10000E+01 0.0000 83 H2PO4- 0.73438E-09 -9.1341 0.64525E-09 -9.1903 0.87863E+00 -0.0562 84 PO4-3 0.45645E-08 -8.3406 0.16886E-08 -8.7725 0.36994E+00 -0.4319 87 H2P2O7-2 0.51753E-19 -19.2861 0.32646E-19 -19.4862 0.63080E+00 -0.2001 88 HP2O7-3 0.13880E-15 -15.8576 0.50142E-16 -16.2998 0.36127E+00 -0.4422 89 P2O7-4 0.54816E-15 -15.2611 0.92144E-16 -16.0355 0.16810E+00 -0.7744 90 H2S,aq 0.15727E-15 -15.8033 0.15704E-15 -15.8040 0.99851E+00 -0.0006 97 SO3-2 0.46432E-14 -14.3332 0.29498E-14 -14.5302 0.63529E+00 -0.1970 98 HSO3- 0.27340E-16 -16.5632 0.24010E-16 -16.6196 0.87822E+00 -0.0564 99 HSO4- 0.22963E-11 -11.6390 0.20196E-11 -11.6947 0.87946E+00 -0.0558 Charge balance for all species = 0.6527E-13 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.1475896E-09 -.8764907E-02 -.8829247E+01 0.0000 2 H2O 0.1000000E+01 0.5551011E+02 0.9994367E+06 0.0000 3 Cl- 0.1378951E-03 0.1381891E-03 0.4896305E+01 5.9692 4 SO4-- 0.2552760E-04 0.2554558E-04 0.2452490E+01 14.9795 5 HCO3- 0.6759729E-05 0.1309036E-04 0.7982621E+00 4.6599 6 HS- 0.4450141E-12 -.1381809E-08 -.4567202E-04 -2.5219 7 Al+++ 0.8560666E-27 0.7398383E-04 0.1995008E+01 2.1483 8 H4SiO4 0.3735728E-03 0.3746584E-02 0.3598903E+03 -3.4276 9 Ca++ 0.4015687E-07 0.5907494E-07 0.2366198E-02 12.1747 10 Mg++ 0.1683237E-10 0.5435043E-10 0.1320582E-05 8.7961 11 Fe++ 0.9925997E-13 0.2718004E-07 0.1517021E-02 6.5669 12 K+ 0.6576973E-04 0.6597622E-04 0.2578268E+01 5.6480 13 Na+ 0.8337796E-02 0.8680037E-02 0.1994337E+03 7.7507 14 Mn++ 0.1333309E-10 0.7827678E-09 0.4297813E-04 8.6953 15 HPO4-- 0.4260573E-06 0.4313562E-06 0.4137652E-01 13.2019 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.1589321E+00 -.8751275E-02 -.1501809E+00 0.0000000E+00 2 H2O 0.5538792E+02 0.5542378E+02 -.3585792E-01 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.2915255E-03 0.2550585E-04 0.2660196E-03 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.2660210E-03 -.1379660E-08 -.2660196E-03 0.0000000E+00 7 Al+++ 0.3129986E-01 0.7386876E-04 0.3122599E-01 0.0000000E+00 8 H4SiO4 0.9995230E-01 0.3740757E-02 0.9621155E-01 0.0000000E+00 9 Ca++ 0.1105469E-01 0.5898306E-07 0.1105463E-01 0.0000000E+00 10 Mg++ 0.7618254E-02 0.5426590E-10 0.7618254E-02 0.0000000E+00 11 Fe++ 0.6844169E-02 0.2713777E-07 0.6844142E-02 0.0000000E+00 12 K+ 0.2038004E-02 0.6587361E-04 0.1972131E-02 0.0000000E+00 13 Na+ 0.1220915E-01 0.8666537E-02 0.3542618E-02 0.0000000E+00 14 Mn++ 0.1664332E-03 0.7815504E-09 0.1664324E-03 0.0000000E+00 15 HPO4-- 0.5680282E-04 0.4306854E-06 0.5637213E-04 0.0000000E+00 Chg. balance for solid moles: 0.1372E-16 Mass of aqueous solution: 0.999039E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 9.5990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 0.3543E-02 -2.451 0.9289 -0.032 8.853 0.3566 apatite-OH 0.1879E-04 -4.726 0.9439E-02 -2.025 0.8996E-01 0.2999E-02 clinochlore 0.1524E-02 -2.817 0.8469 -0.072 8.071 0.3221 daphnite 0.9432E-03 -3.025 0.6730 -0.172 6.414 0.2039 chlorite-Mn 0.3329E-04 -4.478 0.2360E-01 -1.627 0.2249 0.7520E-02 hematite 0.8623E-03 -3.064 0.1377 -0.861 1.313 0.2610E-01 lawsonite 0.2396E-04 -4.621 0.7528E-02 -2.123 0.7174E-01 0.2428E-02 microcline 0.1972E-02 -2.705 0.5489 -0.260 5.231 0.2144 prehnite-Fe 0.4035E-03 -3.394 0.1780 -0.750 1.697 0.5972E-01 stilbite 0.1013E-01 -1.994 7.139 0.854 68.03 3.330 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.6094E+00 0.6094E+00 1.0000 -0.215 daphnite 0.3773E+00 0.3773E+00 1.0000 -0.423 chlorite-Mn 0.1331E-01 0.1331E-01 1.0000 -1.876 hematite 0.1000E+01 0.1000E+01 1.0000 0.000 lawsonite 0.1000E+01 0.1000E+01 1.0000 0.000 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 prehnite-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 10.492719 g Volume = 4.525466 cm3 Porosity: 6.4909% V(tot) - V(min): 0.31413E+00 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 9.5990000 g log = 0.9822 Original solution: 1000.0103000 g Original solution / Rock added: 104.18 (Water/Rock Ratio), log = 2.0178 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0203 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.1000E+01 0.9860 0.1006E+01 0.1020E+01 CO2,gas 0.1718E-06 1.0071 0.1766E-06 0.1753E-06 CH4,gas 0.1994E-15 1.0125 0.2060E-15 0.2034E-15 H2,gas 0.1811E-05 1.0005 0.1849E-05 0.1848E-05 H2S,gas 0.4248E-14 0.9960 0.4317E-14 0.4334E-14 S2,gas 0.2006E-36 1.0000 0.2047E-36 0.2047E-36 CO,gas 0.8526E-16 1.0000 0.8699E-16 0.8699E-16 SO3,gas 0.1010E-39 1.0000 0.1030E-39 0.1030E-39 SO2,gas 0.7262E-23 1.0000 0.7409E-23 0.7409E-23 HCl,gas 0.4989E-17 1.0000 0.5091E-17 0.5091E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 16 albite -0.38 -0.38 0.00 0.000 -0.94784E-12 32 apatite-OH -18.15 -18.15 0.00 0.000 0.60662E-11 46 clinochlore 39.07 39.07 0.00 0.000 -0.24265E-10 47 daphnite 28.97 28.97 0.00 0.000 0.00000E+00 48 chlorite-Mn 46.87 46.87 0.00 0.000 -0.12132E-10 90 hematite 12.57 12.57 0.00 0.000 0.30331E-11 102 lawsonite 9.62 9.62 0.00 0.000 -0.12132E-10 116 microcline -2.49 -2.49 0.00 0.000 0.15165E-11 137 prehnite-Fe 22.50 22.50 0.00 0.000 0.24265E-10 163 stilbite -7.52 -7.52 0.00 0.000 -0.90992E-11 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -15.11 -8.45 -2.817 0.14432E+05 -6.753 3 CH4,gas 4.54 -12.84 -17.39 -4.346 0.29685E+05 -15.686 4 H2,gas 8.00 0.57 -7.43 -4.247 0.12690E+05 -5.733 5 H2S,gas -6.23 -22.29 -16.06 -8.032 0.27429E+05 -14.365 6 S2,gas -7.34 -45.72 -38.39 -5.906 0.65546E+05 -36.689 7 CO,gas 3.21 -14.54 -17.76 -5.464 0.30324E+05 -16.061 8 SO3,gas 17.12 -24.56 -41.69 -10.422 0.71178E+05 -39.987 9 SO2,gas 0.83 -24.00 -24.83 -6.621 0.42395E+05 -23.130 10 HCl,gas 5.19 -13.80 -18.99 -9.496 0.32429E+05 -17.293 11 acmite 7.71 7.18 -0.53 -0.055 0.90700E+03 15 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 19 spessartine 24.46 20.10 -4.36 -0.218 0.74408E+04 20 analcite 3.32 3.04 -0.28 -0.031 0.47485E+03 21 andalusite 5.00 0.87 -4.13 -0.413 0.70561E+04 22 andradite 39.01 38.81 -0.20 -0.010 0.34401E+03 23 grossular 32.73 30.54 -2.19 -0.110 0.37456E+04 26 annite 20.12 17.21 -2.91 -0.162 0.49672E+04 27 phlogopite 27.06 23.90 -3.16 -0.176 0.54005E+04 29 anorthite 12.71 9.62 -3.09 -0.238 0.52833E+04 35 aragonite 0.97 -2.94 -3.90 -1.301 0.66661E+04 36 brucite 12.57 8.80 -3.77 -0.754 0.64414E+04 37 calcite 0.81 -2.94 -3.75 -1.250 0.64019E+04 38 carnegieite-low 9.02 6.47 -2.55 -0.365 0.43573E+04 39 carnegieite-high 10.09 6.47 -3.62 -0.517 0.61843E+04 40 carpholite-Mg 8.58 6.24 -2.34 -0.156 0.40034E+04 41 carpholite-Fe 6.71 4.01 -2.70 -0.180 0.46175E+04 42 celadonite 5.34 2.88 -2.46 -0.145 0.41998E+04 43 celadonite-Fe 3.88 0.65 -3.22 -0.190 0.55044E+04 44 chrysotile 23.89 19.53 -4.36 -0.363 0.74436E+04 50 chloritoid-Mg 13.20 9.67 -3.53 -0.236 0.60318E+04 51 chloritoid-Fe 9.17 7.44 -1.74 -0.116 0.29670E+04 52 chloritoid-Mn 11.40 9.56 -1.84 -0.122 0.31362E+04 54 coesite -2.38 -3.43 -1.05 -0.351 0.17955E+04 59 corundum 8.38 4.30 -4.09 -0.371 0.69775E+04 61 cristobalite -2.56 -3.43 -0.87 -0.289 0.14809E+04 63 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71234E+04 65 diaspore 2.87 2.15 -0.73 -0.121 0.12385E+04 67 diopside 16.18 14.12 -2.07 -0.207 0.35274E+04 68 hedenbergite 14.21 11.89 -2.32 -0.232 0.39647E+04 75 epidote 24.67 24.65 -0.02 -0.001 0.40501E+02 76 clinozoisite 22.81 20.51 -2.29 -0.104 0.39180E+04 77 epidote-Fe 29.84 28.78 -1.06 -0.055 0.18097E+04 78 fayalite 14.05 9.71 -4.34 -0.620 0.74096E+04 79 ferrosilite 11.15 6.28 -4.87 -0.487 0.83168E+04 83 gibbsite 4.08 2.15 -1.93 -0.276 0.32971E+04 84 glaucophane 22.97 18.77 -4.21 -0.114 0.71878E+04 87 greenalite 16.14 12.85 -3.29 -0.274 0.56244E+04 91 heulandite -5.83 -7.52 -1.69 -0.077 0.28938E+04 95 jadeite 4.22 3.04 -1.17 -0.117 0.20003E+04 96 julgoldite 70.43 66.40 -4.03 -0.105 0.68774E+04 97 kalsilite 7.58 4.37 -3.22 -0.459 0.54898E+04 98 kaolinite -1.33 -2.56 -1.23 -0.111 0.20930E+04 99 kyanite 4.88 0.87 -4.01 -0.401 0.68420E+04 101 laumontite 2.88 2.76 -0.12 -0.008 0.20932E+03 103 leucite 4.12 0.94 -3.18 -0.318 0.54259E+04 105 lizardite 23.24 19.53 -3.71 -0.309 0.63362E+04 107 magnetite 20.09 19.13 -0.95 -0.078 0.16294E+04 108 minnesotaite 10.39 5.99 -4.40 -0.259 0.75092E+04 110 magnesioferrite 26.21 21.36 -4.85 -0.396 0.82815E+04 113 margarite 17.32 13.91 -3.41 -0.136 0.58240E+04 120 muscovite 2.58 1.81 -0.77 -0.045 0.13186E+04 121 paragonite 4.24 3.91 -0.33 -0.019 0.55772E+03 122 nepheline 8.34 6.47 -1.87 -0.267 0.31897E+04 134 phlogopite-Na 29.65 26.00 -3.64 -0.202 0.62194E+04 136 prehnite 19.37 18.36 -1.01 -0.059 0.17225E+04 138 pumpellyite-Fe 46.27 45.44 -0.83 -0.018 0.14137E+04 139 pumpellyite-Mg 48.99 47.67 -1.32 -0.029 0.22612E+04 145 pyroxmangite 7.40 5.27 -2.13 -0.426 0.36387E+04 146 pyrophyllite -6.18 -9.41 -3.24 -0.202 0.55289E+04 147 quartz -2.99 -3.43 -0.44 -0.146 0.74820E+03 152 rhodonite 7.45 5.27 -2.18 -0.436 0.37189E+04 153 sanidine -1.28 -2.49 -1.21 -0.093 0.20677E+04 156 sillimanite 5.26 0.87 -4.39 -0.439 0.75000E+04 164 stilpnomelane-Fe 13.02 12.53 -0.48 -0.014 0.82408E+03 165 stilpnomelane-Mg 27.44 23.68 -3.76 -0.112 0.64225E+04 171 talc 16.49 12.68 -3.81 -0.224 0.65112E+04 174 tephroite 18.09 13.96 -4.12 -0.589 0.70397E+04 177 topaz-H 4.62 0.87 -3.75 -0.341 0.64021E+04 178 tridymite -2.63 -3.43 -0.80 -0.267 0.13682E+04 187 wairakite 3.95 2.76 -1.19 -0.070 0.20313E+04 188 walstromite 11.51 8.75 -2.76 -0.552 0.47164E+04 189 wollastonite 10.46 8.75 -1.71 -0.343 0.29268E+04 190 pseudo-wollastonite 11.00 8.75 -2.25 -0.451 0.38466E+04 191 zoisite 22.85 20.51 -2.34 -0.106 0.39920E+04 192 akaganeite 7.75 6.28 -1.47 -0.318 0.25125E+04 193 beidellite-Ca -1.65 -5.56 -3.92 -0.242 0.66922E+04 195 beidellite-K -1.52 -5.71 -4.19 -0.257 0.71538E+04 196 beidellite-Mg -1.79 -6.12 -4.33 -0.268 0.73979E+04 197 beidellite-Na -1.34 -5.02 -3.67 -0.225 0.62729E+04 199 chalcedony -2.80 -3.43 -0.63 -0.208 0.10675E+04 201 montmorillonite-Ca -2.29 -5.21 -2.92 -0.181 0.49868E+04 202 montmorillonite-K -2.24 -5.36 -3.12 -0.191 0.53265E+04 203 montmorillonite-Mg -2.48 -5.77 -3.29 -0.203 0.56156E+04 204 montmorillonite-Na -2.04 -4.66 -2.62 -0.161 0.44814E+04 205 nontronite-Ca 3.21 2.70 -0.51 -0.033 0.87076E+03 206 nontronite-H 2.53 0.70 -1.84 -0.123 0.31365E+04 207 nontronite-K 3.34 2.56 -0.78 -0.050 0.13337E+04 208 nontronite-Mg 3.07 2.15 -0.93 -0.060 0.15837E+04 209 nontronite-Na 3.52 3.25 -0.27 -0.017 0.45458E+03 224 tobermorite 9.82 6.71 -3.11 -0.848 0.53089E+04 233 boehmite 4.41 2.15 -2.26 -0.376 0.38555E+04 235 ferrous-oxide 9.81 6.57 -3.24 -0.811 0.55402E+04 240 silica-amorphous -2.09 -3.43 -1.34 -0.445 0.22817E+04 242 an20ab80 2.02 1.62 -0.40 -0.031 0.68582E+03 243 an25ab75 2.65 2.12 -0.53 -0.041 0.90424E+03 244 an30ab70 3.28 2.62 -0.66 -0.051 0.11323E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 0.4000000 g Current total amount of reactant added: 9.5990000 g New total amount of reactant added: 9.9990000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.6637E-13 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 7 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 9.9990000 Water: Moles liquid = 0.5542E+02 kg liquid = 0.9984E+00 Moles total = 0.5538E+02 kg total = 0.9977E+00 Activity = 1.0000 Stoichiometric ionic strength = .4833546E-02 Osmotic coef. = 0.9629 True ionic strength = .8436005E-02 Chg. balance for total moles = 0.6637E-13 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.14759E-09 -9.8309 0.13000E-09 -9.8861 0.88083E+00 -0.0551 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13790E-03 -3.8604 0.12111E-03 -3.9168 0.87822E+00 -0.0564 4 SO4-- 0.25529E-04 -4.5930 0.16120E-04 -4.7926 0.63146E+00 -0.1997 5 HCO3- 0.67600E-05 -5.1701 0.59410E-05 -5.2261 0.87885E+00 -0.0561 6 HS- 0.44503E-12 -12.3516 0.39087E-12 -12.4080 0.87829E+00 -0.0564 7 Al+++ 0.85607E-27 -27.0675 0.30915E-27 -27.5098 0.36113E+00 -0.4423 8 H4SiO4 0.37357E-03 -3.4276 0.37357E-03 -3.4276 0.10000E+01 0.0000 9 Ca++ 0.40157E-07 -7.3962 0.25267E-07 -7.5974 0.62921E+00 -0.2012 10 Mg++ 0.16832E-10 -10.7739 0.10567E-10 -10.9760 0.62779E+00 -0.2022 11 Fe++ 0.99260E-13 -13.0032 0.62348E-13 -13.2052 0.62813E+00 -0.2019 12 K+ 0.65770E-04 -4.1820 0.57809E-04 -4.2380 0.87896E+00 -0.0560 13 Na+ 0.83378E-02 -2.0789 0.73219E-02 -2.1354 0.87816E+00 -0.0564 14 Mn++ 0.13333E-10 -10.8751 0.83784E-11 -11.0768 0.62839E+00 -0.2018 15 HPO4-- 0.42606E-06 -6.3705 0.26906E-06 -6.5702 0.63151E+00 -0.1996 16 HSiO3- 0.30553E-02 -2.5150 0.26832E-02 -2.5713 0.87822E+00 -0.0564 17 Ca(HSiO3)+ 0.17564E-08 -8.7554 0.15440E-08 -8.8114 0.87905E+00 -0.0560 18 Mg(HSiO3)+ 0.91419E-12 -12.0390 0.80362E-12 -12.0949 0.87905E+00 -0.0560 19 NaHSiO3,aq 0.31775E-03 -3.4979 0.31775E-03 -3.4979 0.10000E+01 0.0000 20 AlO+ 0.28310E-14 -14.5481 0.24886E-14 -14.6040 0.87905E+00 -0.0560 22 HAlO2,aq 0.38123E-08 -8.4188 0.38123E-08 -8.4188 0.10000E+01 0.0000 23 AlO2- 0.73980E-04 -4.1309 0.64913E-04 -4.1877 0.87744E+00 -0.0568 24 CH4,aq 0.14014E-18 -18.8534 0.13993E-18 -18.8541 0.99851E+00 -0.0006 29 CO,aq 0.58380E-19 -19.2337 0.58380E-19 -19.2337 0.10000E+01 0.0000 30 CO2,aq 0.16528E-08 -8.7818 0.16503E-08 -8.7824 0.99851E+00 -0.0006 31 CO3-2 0.63280E-05 -5.1987 0.39917E-05 -5.3988 0.63080E+00 -0.2001 32 CaCO3,aq 0.12646E-08 -8.8980 0.12646E-08 -8.8980 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.43590E-11 -11.3606 0.38318E-11 -11.4166 0.87905E+00 -0.0560 34 CaCl+ 0.56334E-11 -11.2492 0.49521E-11 -11.3052 0.87905E+00 -0.0560 35 CaCl2,aq 0.14248E-15 -15.8462 0.14248E-15 -15.8462 0.10000E+01 0.0000 36 CaOH+ 0.15758E-07 -7.8025 0.13852E-07 -7.8585 0.87905E+00 -0.0560 37 CaSO4,aq 0.12934E-09 -9.8883 0.12934E-09 -9.8883 0.10000E+01 0.0000 38 HCl,aq 0.28851E-14 -14.5398 0.28851E-14 -14.5398 0.10000E+01 0.0000 43 FeCl+ 0.13596E-16 -16.8666 0.11952E-16 -16.9226 0.87905E+00 -0.0560 46 FeO,aq 0.14338E-09 -9.8435 0.14338E-09 -9.8435 0.10000E+01 0.0000 47 FeOH+ 0.17759E-10 -10.7506 0.15611E-10 -10.8066 0.87905E+00 -0.0560 48 HFeO2- 0.13140E-07 -7.8814 0.11540E-07 -7.9378 0.87822E+00 -0.0564 49 FeO+ 0.11288E-14 -14.9474 0.99229E-15 -15.0034 0.87905E+00 -0.0560 51 FeO2- 0.13680E-07 -7.8639 0.12014E-07 -7.9203 0.87822E+00 -0.0564 52 HFeO2,aq 0.19864E-09 -9.7019 0.19864E-09 -9.7019 0.10000E+01 0.0000 53 H2,aq 0.14103E-08 -8.8507 0.14082E-08 -8.8513 0.99851E+00 -0.0006 54 KCl,aq 0.12689E-09 -9.8966 0.12689E-09 -9.8966 0.10000E+01 0.0000 55 KHSO4,aq 0.34253E-18 -18.4653 0.34253E-18 -18.4653 0.10000E+01 0.0000 56 KOH,aq 0.18990E-06 -6.7215 0.18990E-06 -6.7215 0.10000E+01 0.0000 57 KSO4- 0.16466E-07 -7.7834 0.14461E-07 -7.8398 0.87822E+00 -0.0564 58 MgCO3,aq 0.13257E-12 -12.8775 0.13257E-12 -12.8775 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.18628E-14 -14.7298 0.16375E-14 -14.7858 0.87905E+00 -0.0560 60 MgCl+ 0.21354E-14 -14.6705 0.18771E-14 -14.7265 0.87905E+00 -0.0560 61 MgOH+ 0.36467E-10 -10.4381 0.32057E-10 -10.4941 0.87905E+00 -0.0560 63 MnO,aq 0.51340E-09 -9.2895 0.51340E-09 -9.2895 0.10000E+01 0.0000 64 MnOH+ 0.22170E-09 -9.6542 0.19488E-09 -9.7102 0.87905E+00 -0.0560 65 MnO2-2 0.15982E-11 -11.7964 0.10082E-11 -11.9965 0.63080E+00 -0.2001 66 HMnO2- 0.32695E-10 -10.4855 0.28714E-10 -10.5419 0.87822E+00 -0.0564 69 MnCl+ 0.71080E-14 -14.1482 0.62483E-14 -14.2042 0.87905E+00 -0.0560 70 MnSO4,aq 0.38991E-13 -13.4090 0.38991E-13 -13.4090 0.10000E+01 0.0000 71 NaCl,aq 0.29387E-06 -6.5318 0.29387E-06 -6.5318 0.10000E+01 0.0000 72 NaOH,aq 0.24198E-04 -4.6162 0.24198E-04 -4.6162 0.10000E+01 0.0000 74 OH- 0.50651E-02 -2.2954 0.44444E-02 -2.3522 0.87744E+00 -0.0568 79 HPO3-2 0.18718E-17 -17.7277 0.11807E-17 -17.9279 0.63080E+00 -0.2001 82 H3PO4,aq 0.31803E-16 -16.4975 0.31803E-16 -16.4975 0.10000E+01 0.0000 83 H2PO4- 0.73438E-09 -9.1341 0.64525E-09 -9.1903 0.87863E+00 -0.0562 84 PO4-3 0.45645E-08 -8.3406 0.16886E-08 -8.7725 0.36994E+00 -0.4319 87 H2P2O7-2 0.51753E-19 -19.2861 0.32646E-19 -19.4862 0.63080E+00 -0.2001 88 HP2O7-3 0.13880E-15 -15.8576 0.50142E-16 -16.2998 0.36127E+00 -0.4422 89 P2O7-4 0.54815E-15 -15.2611 0.92143E-16 -16.0355 0.16810E+00 -0.7744 90 H2S,aq 0.15728E-15 -15.8033 0.15704E-15 -15.8040 0.99851E+00 -0.0006 97 SO3-2 0.46434E-14 -14.3332 0.29499E-14 -14.5302 0.63529E+00 -0.1970 98 HSO3- 0.27341E-16 -16.5632 0.24011E-16 -16.6196 0.87822E+00 -0.0564 99 HSO4- 0.22964E-11 -11.6389 0.20196E-11 -11.6947 0.87946E+00 -0.0558 Charge balance for all species = 0.6532E-13 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.1475897E-09 -.8764903E-02 -.8829243E+01 0.0000 2 H2O 0.1000000E+01 0.5551011E+02 0.9994367E+06 0.0000 3 Cl- 0.1379007E-03 0.1381947E-03 0.4896503E+01 5.9692 4 SO4-- 0.2552863E-04 0.2554661E-04 0.2452589E+01 14.9795 5 HCO3- 0.6760004E-05 0.1309089E-04 0.7982944E+00 4.6599 6 HS- 0.4450326E-12 -.1381808E-08 -.4567199E-04 -2.5219 7 Al+++ 0.8560682E-27 0.7398379E-04 0.1995007E+01 2.1483 8 H4SiO4 0.3735728E-03 0.3746582E-02 0.3598901E+03 -3.4276 9 Ca++ 0.4015691E-07 0.5907505E-07 0.2366202E-02 12.1747 10 Mg++ 0.1683239E-10 0.5435047E-10 0.1320583E-05 8.7961 11 Fe++ 0.9926009E-13 0.2718003E-07 0.1517020E-02 6.5669 12 K+ 0.6576976E-04 0.6597626E-04 0.2578270E+01 5.6480 13 Na+ 0.8337800E-02 0.8680041E-02 0.1994338E+03 7.7507 14 Mn++ 0.1333311E-10 0.7827681E-09 0.4297814E-04 8.6953 15 HPO4-- 0.4260570E-06 0.4313559E-06 0.4137649E-01 13.2019 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.1655556E+00 -.8750918E-02 -.1568046E+00 0.0000000E+00 2 H2O 0.5538291E+02 0.5542154E+02 -.3863359E-01 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.3026108E-03 0.2550585E-04 0.2771050E-03 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.2771064E-03 -.1379604E-08 -.2771050E-03 0.0000000E+00 7 Al+++ 0.3260416E-01 0.7386574E-04 0.3253029E-01 0.0000000E+00 8 H4SiO4 0.1041174E+00 0.3740604E-02 0.1003768E+00 0.0000000E+00 9 Ca++ 0.1151475E-01 0.5898079E-07 0.1151469E-01 0.0000000E+00 10 Mg++ 0.7935714E-02 0.5426375E-10 0.7935714E-02 0.0000000E+00 11 Fe++ 0.7129373E-02 0.2713666E-07 0.7129346E-02 0.0000000E+00 12 K+ 0.2122930E-02 0.6587099E-04 0.2057059E-02 0.0000000E+00 13 Na+ 0.1271125E-01 0.8666191E-02 0.4045061E-02 0.0000000E+00 14 Mn++ 0.1733686E-03 0.7815191E-09 0.1733678E-03 0.0000000E+00 15 HPO4-- 0.5916985E-04 0.4306676E-06 0.5873918E-04 0.0000000E+00 Chg. balance for solid moles: 0.7129E-17 Mass of aqueous solution: 0.998998E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 9.9990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 0.4045E-02 -2.393 1.061 0.026 9.705 0.4072 apatite-OH 0.1958E-04 -4.708 0.9835E-02 -2.007 0.8999E-01 0.3125E-02 clinochlore 0.1587E-02 -2.799 0.8822 -0.054 8.071 0.3356 daphnite 0.9825E-03 -3.008 0.7010 -0.154 6.414 0.2124 chlorite-Mn 0.3467E-04 -4.460 0.2458E-01 -1.609 0.2249 0.7834E-02 hematite 0.8394E-03 -3.076 0.1341 -0.873 1.226 0.2541E-01 lawsonite -.5163E-04 1.000 -.1622E-01 1.000 -.1484 -.5232E-02 microcline 0.2057E-02 -2.687 0.5726 -0.242 5.239 0.2237 prehnite-Fe 0.5380E-03 -3.269 0.2374 -0.625 2.172 0.7964E-01 stilbite 0.1039E-01 -1.983 7.324 0.865 67.01 3.416 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.6094E+00 0.6094E+00 1.0000 -0.215 daphnite 0.3773E+00 0.3773E+00 1.0000 -0.423 chlorite-Mn 0.1331E-01 0.1331E-01 1.0000 -1.876 hematite 0.1000E+01 0.1000E+01 1.0000 0.000 lawsonite 0.1000E+01 0.1000E+01 1.0000 0.000 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 prehnite-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 10.929830 g Volume = 4.705511 cm3 Porosity: 5.8823% V(tot) - V(min): 0.29409E+00 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 9.9990000 g log = 1.0000 Original solution: 1000.0103000 g Original solution / Rock added: 100.01 (Water/Rock Ratio), log = 2.0000 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0203 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.1000E+01 0.9860 0.1006E+01 0.1020E+01 CO2,gas 0.1718E-06 1.0071 0.1766E-06 0.1753E-06 CH4,gas 0.1994E-15 1.0125 0.2060E-15 0.2034E-15 H2,gas 0.1811E-05 1.0005 0.1849E-05 0.1848E-05 H2S,gas 0.4248E-14 0.9960 0.4317E-14 0.4334E-14 S2,gas 0.2006E-36 1.0000 0.2047E-36 0.2047E-36 CO,gas 0.8527E-16 1.0000 0.8700E-16 0.8700E-16 SO3,gas 0.1010E-39 1.0000 0.1030E-39 0.1030E-39 SO2,gas 0.7262E-23 1.0000 0.7409E-23 0.7409E-23 HCl,gas 0.4989E-17 1.0000 0.5091E-17 0.5091E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 16 albite -0.38 -0.38 0.00 0.000 0.11184E-10 32 apatite-OH -18.15 -18.15 0.00 0.000 0.12132E-10 46 clinochlore 39.07 39.07 0.00 0.000 0.12132E-10 47 daphnite 28.97 28.97 0.00 0.000 -0.30331E-10 48 chlorite-Mn 46.87 46.87 0.00 0.000 0.48529E-10 90 hematite 12.57 12.57 0.00 0.000 0.90992E-11 116 microcline -2.49 -2.49 0.00 0.000 0.13649E-10 137 prehnite-Fe 22.50 22.50 0.00 0.000 0.24265E-10 163 stilbite -7.52 -7.52 0.00 0.000 0.15165E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -15.11 -8.45 -2.817 0.14432E+05 -6.753 3 CH4,gas 4.54 -12.84 -17.39 -4.346 0.29685E+05 -15.686 4 H2,gas 8.00 0.57 -7.43 -4.247 0.12690E+05 -5.733 5 H2S,gas -6.23 -22.29 -16.06 -8.032 0.27428E+05 -14.365 6 S2,gas -7.34 -45.72 -38.39 -5.906 0.65546E+05 -36.689 7 CO,gas 3.21 -14.54 -17.76 -5.464 0.30324E+05 -16.060 8 SO3,gas 17.12 -24.56 -41.69 -10.422 0.71178E+05 -39.987 9 SO2,gas 0.83 -24.00 -24.83 -6.621 0.42395E+05 -23.130 10 HCl,gas 5.19 -13.80 -18.99 -9.496 0.32429E+05 -17.293 11 acmite 7.71 7.18 -0.53 -0.055 0.90700E+03 15 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 19 spessartine 24.46 20.10 -4.36 -0.218 0.74408E+04 20 analcite 3.32 3.04 -0.28 -0.031 0.47485E+03 21 andalusite 5.00 0.87 -4.13 -0.413 0.70561E+04 22 andradite 39.01 38.81 -0.20 -0.010 0.34401E+03 23 grossular 32.73 30.54 -2.19 -0.110 0.37456E+04 26 annite 20.12 17.21 -2.91 -0.162 0.49672E+04 27 phlogopite 27.06 23.90 -3.16 -0.176 0.54005E+04 29 anorthite 12.71 9.62 -3.09 -0.238 0.52833E+04 35 aragonite 0.97 -2.94 -3.90 -1.301 0.66661E+04 36 brucite 12.57 8.80 -3.77 -0.754 0.64414E+04 37 calcite 0.81 -2.94 -3.75 -1.250 0.64018E+04 38 carnegieite-low 9.02 6.47 -2.55 -0.365 0.43573E+04 39 carnegieite-high 10.09 6.47 -3.62 -0.517 0.61843E+04 40 carpholite-Mg 8.58 6.24 -2.34 -0.156 0.40034E+04 41 carpholite-Fe 6.71 4.01 -2.70 -0.180 0.46175E+04 42 celadonite 5.34 2.88 -2.46 -0.145 0.41998E+04 43 celadonite-Fe 3.88 0.65 -3.22 -0.190 0.55044E+04 44 chrysotile 23.89 19.53 -4.36 -0.363 0.74436E+04 50 chloritoid-Mg 13.20 9.67 -3.53 -0.236 0.60318E+04 51 chloritoid-Fe 9.17 7.44 -1.74 -0.116 0.29670E+04 52 chloritoid-Mn 11.40 9.56 -1.84 -0.122 0.31362E+04 54 coesite -2.38 -3.43 -1.05 -0.351 0.17955E+04 59 corundum 8.38 4.30 -4.09 -0.371 0.69775E+04 61 cristobalite -2.56 -3.43 -0.87 -0.289 0.14809E+04 63 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71234E+04 65 diaspore 2.87 2.15 -0.73 -0.121 0.12385E+04 67 diopside 16.18 14.12 -2.07 -0.207 0.35274E+04 68 hedenbergite 14.21 11.89 -2.32 -0.232 0.39647E+04 75 epidote 24.67 24.65 -0.02 -0.001 0.40501E+02 76 clinozoisite 22.81 20.51 -2.29 -0.104 0.39180E+04 77 epidote-Fe 29.84 28.78 -1.06 -0.055 0.18097E+04 78 fayalite 14.05 9.71 -4.34 -0.620 0.74096E+04 79 ferrosilite 11.15 6.28 -4.87 -0.487 0.83168E+04 83 gibbsite 4.08 2.15 -1.93 -0.276 0.32971E+04 84 glaucophane 22.97 18.77 -4.21 -0.114 0.71878E+04 87 greenalite 16.14 12.85 -3.29 -0.274 0.56244E+04 91 heulandite -5.83 -7.52 -1.69 -0.077 0.28938E+04 95 jadeite 4.22 3.04 -1.17 -0.117 0.20003E+04 96 julgoldite 70.43 66.40 -4.03 -0.105 0.68774E+04 97 kalsilite 7.58 4.37 -3.22 -0.459 0.54898E+04 98 kaolinite -1.33 -2.56 -1.23 -0.111 0.20930E+04 99 kyanite 4.88 0.87 -4.01 -0.401 0.68420E+04 101 laumontite 2.88 2.76 -0.12 -0.008 0.20932E+03 102 lawsonite 9.62 9.62 0.00 0.000 0.12132E-10 103 leucite 4.12 0.94 -3.18 -0.318 0.54259E+04 105 lizardite 23.24 19.53 -3.71 -0.309 0.63362E+04 107 magnetite 20.09 19.13 -0.95 -0.078 0.16294E+04 108 minnesotaite 10.39 5.99 -4.40 -0.259 0.75092E+04 110 magnesioferrite 26.21 21.36 -4.85 -0.396 0.82815E+04 113 margarite 17.32 13.91 -3.41 -0.136 0.58240E+04 120 muscovite 2.58 1.81 -0.77 -0.045 0.13186E+04 121 paragonite 4.24 3.91 -0.33 -0.019 0.55772E+03 122 nepheline 8.34 6.47 -1.87 -0.267 0.31897E+04 134 phlogopite-Na 29.65 26.00 -3.64 -0.202 0.62194E+04 136 prehnite 19.37 18.36 -1.01 -0.059 0.17225E+04 138 pumpellyite-Fe 46.27 45.44 -0.83 -0.018 0.14137E+04 139 pumpellyite-Mg 48.99 47.67 -1.32 -0.029 0.22612E+04 145 pyroxmangite 7.40 5.27 -2.13 -0.426 0.36387E+04 146 pyrophyllite -6.18 -9.41 -3.24 -0.202 0.55289E+04 147 quartz -2.99 -3.43 -0.44 -0.146 0.74820E+03 152 rhodonite 7.45 5.27 -2.18 -0.436 0.37189E+04 153 sanidine -1.28 -2.49 -1.21 -0.093 0.20677E+04 156 sillimanite 5.26 0.87 -4.39 -0.439 0.75000E+04 164 stilpnomelane-Fe 13.02 12.53 -0.48 -0.014 0.82408E+03 165 stilpnomelane-Mg 27.44 23.68 -3.76 -0.112 0.64225E+04 171 talc 16.49 12.68 -3.81 -0.224 0.65112E+04 174 tephroite 18.09 13.96 -4.12 -0.589 0.70397E+04 177 topaz-H 4.62 0.87 -3.75 -0.341 0.64021E+04 178 tridymite -2.63 -3.43 -0.80 -0.267 0.13682E+04 187 wairakite 3.95 2.76 -1.19 -0.070 0.20313E+04 188 walstromite 11.51 8.75 -2.76 -0.552 0.47164E+04 189 wollastonite 10.46 8.75 -1.71 -0.343 0.29268E+04 190 pseudo-wollastonite 11.00 8.75 -2.25 -0.451 0.38466E+04 191 zoisite 22.85 20.51 -2.34 -0.106 0.39920E+04 192 akaganeite 7.75 6.28 -1.47 -0.318 0.25125E+04 193 beidellite-Ca -1.65 -5.56 -3.92 -0.242 0.66922E+04 195 beidellite-K -1.52 -5.71 -4.19 -0.257 0.71538E+04 196 beidellite-Mg -1.79 -6.12 -4.33 -0.268 0.73979E+04 197 beidellite-Na -1.34 -5.02 -3.67 -0.225 0.62729E+04 199 chalcedony -2.80 -3.43 -0.63 -0.208 0.10675E+04 201 montmorillonite-Ca -2.29 -5.21 -2.92 -0.181 0.49868E+04 202 montmorillonite-K -2.24 -5.36 -3.12 -0.191 0.53265E+04 203 montmorillonite-Mg -2.48 -5.77 -3.29 -0.203 0.56156E+04 204 montmorillonite-Na -2.04 -4.66 -2.62 -0.161 0.44814E+04 205 nontronite-Ca 3.21 2.70 -0.51 -0.033 0.87076E+03 206 nontronite-H 2.53 0.70 -1.84 -0.123 0.31365E+04 207 nontronite-K 3.34 2.56 -0.78 -0.050 0.13337E+04 208 nontronite-Mg 3.07 2.15 -0.93 -0.060 0.15837E+04 209 nontronite-Na 3.52 3.25 -0.27 -0.017 0.45458E+03 224 tobermorite 9.82 6.71 -3.11 -0.848 0.53089E+04 233 boehmite 4.41 2.15 -2.26 -0.376 0.38555E+04 235 ferrous-oxide 9.81 6.57 -3.24 -0.811 0.55402E+04 240 silica-amorphous -2.09 -3.43 -1.34 -0.445 0.22817E+04 242 an20ab80 2.02 1.62 -0.40 -0.031 0.68582E+03 243 an25ab75 2.65 2.12 -0.53 -0.041 0.90424E+03 244 an30ab70 3.28 2.62 -0.66 -0.051 0.11323E+04 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 8 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 9.9990000 Water: Moles liquid = 0.5542E+02 kg liquid = 0.9984E+00 Moles total = 0.5538E+02 kg total = 0.9977E+00 Activity = 1.0000 Stoichiometric ionic strength = .4874530E-02 Osmotic coef. = 0.9627 True ionic strength = .8565818E-02 Chg. balance for total moles = 0.6637E-13 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.14698E-09 -9.8328 0.12937E-09 -9.8882 0.88020E+00 -0.0554 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13790E-03 -3.8604 0.12101E-03 -3.9172 0.87756E+00 -0.0567 4 SO4-- 0.25529E-04 -4.5930 0.16073E-04 -4.7939 0.62960E+00 -0.2009 5 HCO3- 0.67369E-05 -5.1715 0.59163E-05 -5.2280 0.87819E+00 -0.0564 6 HS- 0.54094E-12 -12.2669 0.47474E-12 -12.3235 0.87762E+00 -0.0567 7 Al+++ 0.76319E-27 -27.1174 0.27376E-27 -27.5626 0.35871E+00 -0.4453 8 H4SiO4 0.38463E-03 -3.4150 0.38463E-03 -3.4150 0.10000E+01 0.0000 9 Ca++ 0.40276E-07 -7.3949 0.25266E-07 -7.5975 0.62732E+00 -0.2025 10 Mg++ 0.17148E-10 -10.7658 0.10733E-10 -10.9693 0.62589E+00 -0.2035 11 Fe++ 0.10112E-12 -12.9952 0.63324E-13 -13.1984 0.62623E+00 -0.2033 12 K+ 0.66785E-04 -4.1753 0.58657E-04 -4.2317 0.87830E+00 -0.0564 13 Na+ 0.84666E-02 -2.0723 0.74293E-02 -2.1290 0.87749E+00 -0.0568 14 Mn++ 0.13583E-10 -10.8670 0.85094E-11 -11.0701 0.62649E+00 -0.2031 15 HPO4-- 0.42457E-06 -6.3720 0.26733E-06 -6.5730 0.62964E+00 -0.2009 16 HSiO3- 0.31635E-02 -2.4998 0.27761E-02 -2.5566 0.87756E+00 -0.0567 17 Ca(HSiO3)+ 0.18185E-08 -8.7403 0.15974E-08 -8.7966 0.87840E+00 -0.0563 18 Mg(HSiO3)+ 0.96137E-12 -12.0171 0.84446E-12 -12.0734 0.87840E+00 -0.0563 19 NaHSiO3,aq 0.33358E-03 -3.4768 0.33358E-03 -3.4768 0.10000E+01 0.0000 20 AlO+ 0.25334E-14 -14.5963 0.22253E-14 -14.6526 0.87840E+00 -0.0563 22 HAlO2,aq 0.34256E-08 -8.4653 0.34256E-08 -8.4653 0.10000E+01 0.0000 23 AlO2- 0.66853E-04 -4.1749 0.58614E-04 -4.2320 0.87676E+00 -0.0571 24 CH4,aq 0.17000E-18 -18.7695 0.16975E-18 -18.7702 0.99850E+00 -0.0007 29 CO,aq 0.60853E-19 -19.2157 0.60853E-19 -19.2157 0.10000E+01 0.0000 30 CO2,aq 0.16379E-08 -8.7857 0.16354E-08 -8.7864 0.99850E+00 -0.0007 31 CO3-2 0.63512E-05 -5.1971 0.39945E-05 -5.3985 0.62893E+00 -0.2014 32 CaCO3,aq 0.12655E-08 -8.8977 0.12655E-08 -8.8977 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.43439E-11 -11.3621 0.38157E-11 -11.4184 0.87840E+00 -0.0563 34 CaCl+ 0.56331E-11 -11.2493 0.49481E-11 -11.3056 0.87840E+00 -0.0563 35 CaCl2,aq 0.14226E-15 -15.8469 0.14226E-15 -15.8469 0.10000E+01 0.0000 36 CaOH+ 0.15846E-07 -7.8001 0.13919E-07 -7.8564 0.87840E+00 -0.0563 37 CaSO4,aq 0.12895E-09 -9.8896 0.12895E-09 -9.8896 0.10000E+01 0.0000 38 HCl,aq 0.28688E-14 -14.5423 0.28688E-14 -14.5423 0.10000E+01 0.0000 43 FeCl+ 0.13808E-16 -16.8599 0.12129E-16 -16.9162 0.87840E+00 -0.0563 46 FeO,aq 0.14705E-09 -9.8325 0.14705E-09 -9.8325 0.10000E+01 0.0000 47 FeOH+ 0.18139E-10 -10.7414 0.15933E-10 -10.7977 0.87840E+00 -0.0563 48 HFeO2- 0.13553E-07 -7.8680 0.11893E-07 -7.9247 0.87756E+00 -0.0567 49 FeO+ 0.11242E-14 -14.9492 0.98746E-15 -15.0055 0.87840E+00 -0.0563 51 FeO2- 0.13757E-07 -7.8615 0.12073E-07 -7.9182 0.87756E+00 -0.0567 52 HFeO2,aq 0.19864E-09 -9.7019 0.19864E-09 -9.7019 0.10000E+01 0.0000 53 H2,aq 0.14834E-08 -8.8287 0.14812E-08 -8.8294 0.99850E+00 -0.0007 54 KCl,aq 0.12865E-09 -9.8906 0.12865E-09 -9.8906 0.10000E+01 0.0000 55 KHSO4,aq 0.34485E-18 -18.4624 0.34485E-18 -18.4624 0.10000E+01 0.0000 56 KOH,aq 0.19363E-06 -6.7130 0.19363E-06 -6.7130 0.10000E+01 0.0000 57 KSO4- 0.16671E-07 -7.7780 0.14630E-07 -7.8348 0.87756E+00 -0.0567 58 MgCO3,aq 0.13474E-12 -12.8705 0.13474E-12 -12.8705 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.18855E-14 -14.7246 0.16562E-14 -14.7809 0.87840E+00 -0.0563 60 MgCl+ 0.21687E-14 -14.6638 0.19050E-14 -14.7201 0.87840E+00 -0.0563 61 MgOH+ 0.37247E-10 -10.4289 0.32717E-10 -10.4852 0.87840E+00 -0.0563 63 MnO,aq 0.52654E-09 -9.2786 0.52654E-09 -9.2786 0.10000E+01 0.0000 64 MnOH+ 0.22644E-09 -9.6451 0.19890E-09 -9.7014 0.87840E+00 -0.0563 65 MnO2-2 0.16601E-11 -11.7799 0.10441E-11 -11.9813 0.62893E+00 -0.2014 66 HMnO2- 0.33722E-10 -10.4721 0.29593E-10 -10.5288 0.87756E+00 -0.0567 69 MnCl+ 0.72190E-14 -14.1415 0.63412E-14 -14.1978 0.87840E+00 -0.0563 70 MnSO4,aq 0.39484E-13 -13.4036 0.39484E-13 -13.4036 0.10000E+01 0.0000 71 NaCl,aq 0.29795E-06 -6.5259 0.29795E-06 -6.5259 0.10000E+01 0.0000 72 NaOH,aq 0.24674E-04 -4.6078 0.24674E-04 -4.6078 0.10000E+01 0.0000 74 OH- 0.50938E-02 -2.2930 0.44661E-02 -2.3501 0.87676E+00 -0.0571 79 HPO3-2 0.19620E-17 -17.7073 0.12340E-17 -17.9087 0.62893E+00 -0.2014 82 H3PO4,aq 0.31292E-16 -16.5046 0.31292E-16 -16.5046 0.10000E+01 0.0000 83 H2PO4- 0.72665E-09 -9.1387 0.63798E-09 -9.1952 0.87797E+00 -0.0565 84 PO4-3 0.45867E-08 -8.3385 0.16860E-08 -8.7732 0.36757E+00 -0.4347 87 H2P2O7-2 0.50744E-19 -19.2946 0.31914E-19 -19.4960 0.62893E+00 -0.2014 88 HP2O7-3 0.13727E-15 -15.8624 0.49259E-16 -16.3075 0.35884E+00 -0.4451 89 P2O7-4 0.54755E-15 -15.2616 0.90963E-16 -16.0411 0.16613E+00 -0.7796 90 H2S,aq 0.19010E-15 -15.7210 0.18982E-15 -15.7217 0.99850E+00 -0.0007 97 SO3-2 0.48839E-14 -14.3112 0.30937E-14 -14.5095 0.63346E+00 -0.1983 98 HSO3- 0.28556E-16 -16.5443 0.25059E-16 -16.6010 0.87756E+00 -0.0567 99 HSO4- 0.22802E-11 -11.6420 0.20039E-11 -11.6981 0.87881E+00 -0.0561 Charge balance for all species = 0.6278E-13 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.1469771E-09 -.8889626E-02 -.8954755E+01 0.0000 2 H2O 0.1000000E+01 0.5551001E+02 0.9994207E+06 0.0000 3 Cl- 0.1378979E-03 0.1381959E-03 0.4896478E+01 5.9710 4 SO4-- 0.2552866E-04 0.2554684E-04 0.2452576E+01 14.9824 5 HCO3- 0.6736860E-05 0.1309101E-04 0.7982904E+00 4.6602 6 HS- 0.5409385E-12 -.1373089E-08 -.4538317E-04 -2.4354 7 Al+++ 0.7631871E-27 0.6685605E-04 0.1802779E+01 2.1019 8 H4SiO4 0.3846299E-03 0.3881679E-02 0.3728621E+03 -3.4150 9 Ca++ 0.4027643E-07 0.5934547E-07 0.2377000E-02 12.1789 10 Mg++ 0.1714769E-10 0.5549455E-10 0.1348362E-05 8.8070 11 Fe++ 0.1011186E-12 0.2767399E-07 0.1544569E-02 6.5779 12 K+ 0.6678476E-04 0.6699519E-04 0.2618051E+01 5.6565 13 Na+ 0.8466576E-02 0.8825126E-02 0.2027644E+03 7.7591 14 Mn++ 0.1358269E-10 0.8019888E-09 0.4403284E-04 8.7062 15 HPO4-- 0.4245721E-06 0.4298855E-06 0.4123486E-01 13.2034 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.1655556E+00 -.8875361E-02 -.1566802E+00 0.0000000E+00 2 H2O 0.5538291E+02 0.5542093E+02 -.3802166E-01 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.3026108E-03 0.2550584E-04 0.2771050E-03 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.2771064E-03 -.1370886E-08 -.2771050E-03 0.0000000E+00 7 Al+++ 0.3260416E-01 0.6674877E-04 0.3253741E-01 0.0000000E+00 8 H4SiO4 0.1041174E+00 0.3875451E-02 0.1002420E+00 0.0000000E+00 9 Ca++ 0.1151475E-01 0.5925024E-07 0.1151469E-01 0.0000000E+00 10 Mg++ 0.7935714E-02 0.5540550E-10 0.7935714E-02 0.0000000E+00 11 Fe++ 0.7129373E-02 0.2762958E-07 0.7129345E-02 0.0000000E+00 12 K+ 0.2122930E-02 0.6688768E-04 0.2056042E-02 0.0000000E+00 13 Na+ 0.1271125E-01 0.8810964E-02 0.3900288E-02 0.0000000E+00 14 Mn++ 0.1733686E-03 0.8007019E-09 0.1733678E-03 0.0000000E+00 15 HPO4-- 0.5916985E-04 0.4291956E-06 0.5874065E-04 0.0000000E+00 Chg. balance for solid moles: -.2380E-16 Mass of aqueous solution: 0.999003E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 9.9990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 0.3900E-02 -2.409 1.023 0.010 9.362 0.3926 apatite-OH 0.1958E-04 -4.708 0.9836E-02 -2.007 0.9003E-01 0.3125E-02 clinochlore 0.1587E-02 -2.799 0.8822 -0.054 8.075 0.3356 daphnite 0.9825E-03 -3.008 0.7010 -0.154 6.417 0.2124 chlorite-Mn 0.3467E-04 -4.460 0.2458E-01 -1.609 0.2250 0.7834E-02 hematite 0.8649E-03 -3.063 0.1381 -0.860 1.264 0.2618E-01 microcline 0.2056E-02 -2.687 0.5723 -0.242 5.238 0.2235 prehnite-Fe 0.4870E-03 -3.312 0.2149 -0.668 1.967 0.7209E-01 stilbite 0.1044E-01 -1.981 7.359 0.867 67.36 3.432 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.6094E+00 0.6094E+00 1.0000 -0.215 daphnite 0.3773E+00 0.3773E+00 1.0000 -0.423 chlorite-Mn 0.1331E-01 0.1331E-01 1.0000 -1.876 hematite 0.1000E+01 0.1000E+01 1.0000 0.000 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 prehnite-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 10.924843 g Volume = 4.705823 cm3 Porosity: 5.8760% V(tot) - V(min): 0.29378E+00 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 9.9990000 g log = 1.0000 Original solution: 1000.0103000 g Original solution / Rock added: 100.01 (Water/Rock Ratio), log = 2.0000 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0203 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.1000E+01 0.9860 0.1006E+01 0.1020E+01 CO2,gas 0.1703E-06 1.0071 0.1750E-06 0.1737E-06 CH4,gas 0.2419E-15 1.0125 0.2499E-15 0.2468E-15 H2,gas 0.1905E-05 1.0005 0.1945E-05 0.1944E-05 H2S,gas 0.5134E-14 0.9960 0.5218E-14 0.5239E-14 S2,gas 0.2649E-36 1.0000 0.2702E-36 0.2702E-36 CO,gas 0.8888E-16 1.0000 0.9068E-16 0.9068E-16 SO3,gas 0.9969E-40 1.0000 0.1017E-39 0.1017E-39 SO2,gas 0.7542E-23 1.0000 0.7695E-23 0.7695E-23 HCl,gas 0.4961E-17 1.0000 0.5062E-17 0.5062E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 16 albite -0.38 -0.38 0.00 0.000 -0.94784E-12 32 apatite-OH -18.15 -18.15 0.00 0.000 0.60662E-11 46 clinochlore 39.07 39.07 0.00 0.000 0.24265E-10 47 daphnite 28.97 28.97 0.00 0.000 0.12132E-10 48 chlorite-Mn 46.87 46.87 0.00 0.000 0.12132E-10 90 hematite 12.57 12.57 0.00 0.000 -0.15165E-10 116 microcline -2.49 -2.49 0.00 0.000 0.15165E-11 137 prehnite-Fe 22.50 22.50 0.00 0.000 0.24265E-10 163 stilbite -7.52 -7.52 0.00 0.000 0.15165E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -15.12 -8.46 -2.819 0.14438E+05 -6.757 3 CH4,gas 4.54 -12.76 -17.30 -4.325 0.29541E+05 -15.602 4 H2,gas 8.00 0.59 -7.41 -4.234 0.12653E+05 -5.711 5 H2S,gas -6.23 -22.21 -15.98 -7.991 0.27288E+05 -14.283 6 S2,gas -7.34 -45.60 -38.27 -5.887 0.65340E+05 -36.568 7 CO,gas 3.21 -14.53 -17.74 -5.459 0.30293E+05 -16.042 8 SO3,gas 17.12 -24.57 -41.69 -10.423 0.71187E+05 -39.993 9 SO2,gas 0.83 -23.98 -24.81 -6.617 0.42367E+05 -23.114 10 HCl,gas 5.19 -13.81 -18.99 -9.497 0.32433E+05 -17.296 11 acmite 7.71 7.21 -0.50 -0.052 0.84932E+03 15 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 19 spessartine 24.46 20.08 -4.38 -0.219 0.74782E+04 20 analcite 3.32 3.03 -0.29 -0.032 0.49648E+03 21 andalusite 5.00 0.79 -4.21 -0.421 0.71931E+04 22 andradite 39.01 38.86 -0.15 -0.008 0.25749E+03 23 grossular 32.73 30.50 -2.24 -0.112 0.38177E+04 26 annite 20.12 17.25 -2.88 -0.160 0.49110E+04 27 phlogopite 27.06 23.93 -3.13 -0.174 0.53443E+04 29 anorthite 12.71 9.55 -3.16 -0.243 0.53915E+04 35 aragonite 0.97 -2.94 -3.90 -1.301 0.66656E+04 36 brucite 12.57 8.81 -3.76 -0.752 0.64227E+04 37 calcite 0.81 -2.94 -3.75 -1.250 0.64013E+04 38 carnegieite-low 9.02 6.45 -2.58 -0.368 0.44006E+04 39 carnegieite-high 10.09 6.45 -3.65 -0.521 0.62276E+04 40 carpholite-Mg 8.58 6.18 -2.40 -0.160 0.41000E+04 41 carpholite-Fe 6.71 3.95 -2.76 -0.184 0.47141E+04 42 celadonite 5.34 2.91 -2.44 -0.143 0.41594E+04 43 celadonite-Fe 3.88 0.68 -3.20 -0.188 0.54640E+04 44 chrysotile 23.89 19.59 -4.30 -0.358 0.73441E+04 50 chloritoid-Mg 13.20 9.60 -3.60 -0.240 0.61501E+04 51 chloritoid-Fe 9.17 7.37 -1.81 -0.120 0.30852E+04 52 chloritoid-Mn 11.40 9.50 -1.91 -0.127 0.32545E+04 54 coesite -2.38 -3.41 -1.04 -0.346 0.17739E+04 59 corundum 8.38 4.20 -4.18 -0.380 0.71361E+04 61 cristobalite -2.56 -3.41 -0.85 -0.285 0.14592E+04 63 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71234E+04 65 diaspore 2.87 2.10 -0.77 -0.129 0.13178E+04 67 diopside 16.18 14.16 -2.03 -0.203 0.34582E+04 68 hedenbergite 14.21 11.93 -2.28 -0.228 0.38954E+04 75 epidote 24.67 24.60 -0.07 -0.003 0.11981E+03 76 clinozoisite 22.81 20.42 -2.39 -0.109 0.40766E+04 77 epidote-Fe 29.84 28.78 -1.06 -0.055 0.18097E+04 78 fayalite 14.05 9.74 -4.30 -0.615 0.73505E+04 79 ferrosilite 11.15 6.33 -4.82 -0.482 0.82361E+04 83 gibbsite 4.08 2.10 -1.98 -0.282 0.33764E+04 84 glaucophane 22.97 18.82 -4.15 -0.112 0.70883E+04 87 greenalite 16.14 12.90 -3.24 -0.270 0.55249E+04 91 heulandite -5.83 -7.52 -1.69 -0.077 0.28938E+04 95 jadeite 4.22 3.03 -1.18 -0.118 0.20220E+04 96 julgoldite 70.43 66.51 -3.91 -0.102 0.66813E+04 97 kalsilite 7.58 4.34 -3.24 -0.463 0.55330E+04 98 kaolinite -1.33 -2.63 -1.29 -0.118 0.22084E+04 99 kyanite 4.88 0.79 -4.09 -0.409 0.69790E+04 101 laumontite 2.88 2.72 -0.16 -0.011 0.27421E+03 102 lawsonite 9.62 9.55 -0.06 -0.004 0.10815E+03 103 leucite 4.12 0.93 -3.19 -0.319 0.54475E+04 105 lizardite 23.24 19.59 -3.65 -0.304 0.62367E+04 107 magnetite 20.09 19.14 -0.94 -0.077 0.16107E+04 108 minnesotaite 10.39 6.07 -4.31 -0.254 0.73664E+04 110 magnesioferrite 26.21 21.37 -4.84 -0.395 0.82627E+04 113 margarite 17.32 13.76 -3.57 -0.143 0.60907E+04 120 muscovite 2.58 1.72 -0.87 -0.051 0.14772E+04 121 paragonite 4.24 3.82 -0.42 -0.025 0.71634E+03 122 nepheline 8.34 6.45 -1.89 -0.270 0.32329E+04 134 phlogopite-Na 29.65 26.04 -3.61 -0.201 0.61631E+04 136 prehnite 19.37 18.32 -1.06 -0.062 0.18018E+04 138 pumpellyite-Fe 46.27 45.31 -0.96 -0.021 0.16329E+04 139 pumpellyite-Mg 48.99 47.54 -1.45 -0.032 0.24803E+04 145 pyroxmangite 7.40 5.29 -2.11 -0.421 0.35983E+04 146 pyrophyllite -6.18 -9.46 -3.28 -0.205 0.56010E+04 147 quartz -2.99 -3.41 -0.43 -0.142 0.72657E+03 152 rhodonite 7.45 5.29 -2.15 -0.431 0.36786E+04 153 sanidine -1.28 -2.49 -1.21 -0.093 0.20677E+04 156 sillimanite 5.26 0.79 -4.47 -0.447 0.76370E+04 164 stilpnomelane-Fe 13.02 12.60 -0.42 -0.012 0.70872E+03 165 stilpnomelane-Mg 27.44 23.75 -3.69 -0.110 0.63071E+04 171 talc 16.49 12.76 -3.73 -0.219 0.63685E+04 174 tephroite 18.09 14.00 -4.09 -0.584 0.69806E+04 177 topaz-H 4.62 0.79 -3.83 -0.348 0.65391E+04 178 tridymite -2.63 -3.41 -0.79 -0.263 0.13465E+04 187 wairakite 3.95 2.72 -1.23 -0.072 0.20962E+04 188 walstromite 11.51 8.76 -2.75 -0.549 0.46875E+04 189 wollastonite 10.46 8.76 -1.70 -0.339 0.28980E+04 190 pseudo-wollastonite 11.00 8.76 -2.24 -0.447 0.38178E+04 191 zoisite 22.85 20.42 -2.43 -0.110 0.41506E+04 192 akaganeite 7.75 6.28 -1.47 -0.318 0.25125E+04 193 beidellite-Ca -1.65 -5.63 -3.98 -0.246 0.67964E+04 195 beidellite-K -1.52 -5.77 -4.25 -0.260 0.72544E+04 196 beidellite-Mg -1.79 -6.18 -4.39 -0.272 0.75002E+04 197 beidellite-Na -1.34 -5.07 -3.73 -0.229 0.63736E+04 199 chalcedony -2.80 -3.41 -0.61 -0.204 0.10459E+04 201 montmorillonite-Ca -2.29 -5.23 -2.94 -0.182 0.50253E+04 202 montmorillonite-K -2.24 -5.38 -3.14 -0.192 0.53615E+04 203 montmorillonite-Mg -2.48 -5.79 -3.31 -0.205 0.56523E+04 204 montmorillonite-Na -2.04 -4.68 -2.65 -0.162 0.45163E+04 205 nontronite-Ca 3.21 2.74 -0.48 -0.031 0.81636E+03 206 nontronite-H 2.53 0.73 -1.81 -0.121 0.30833E+04 207 nontronite-K 3.34 2.59 -0.75 -0.048 0.12757E+04 208 nontronite-Mg 3.07 2.18 -0.89 -0.058 0.15274E+04 209 nontronite-Na 3.52 3.29 -0.23 -0.015 0.39661E+03 224 tobermorite 9.82 6.73 -3.09 -0.844 0.52812E+04 233 boehmite 4.41 2.10 -2.30 -0.384 0.39348E+04 235 ferrous-oxide 9.81 6.58 -3.23 -0.808 0.55214E+04 240 silica-amorphous -2.09 -3.41 -1.32 -0.441 0.22600E+04 242 an20ab80 2.02 1.60 -0.41 -0.032 0.70745E+03 243 an25ab75 2.65 2.10 -0.55 -0.042 0.93128E+03 244 an30ab70 3.28 2.60 -0.68 -0.052 0.11647E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 0.4000000 g Current total amount of reactant added: 9.9990000 g New total amount of reactant added: 10.3990000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.6634E-13 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 8 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 10.3990000 Water: Moles liquid = 0.5542E+02 kg liquid = 0.9983E+00 Moles total = 0.5538E+02 kg total = 0.9977E+00 Activity = 1.0000 Stoichiometric ionic strength = .4942154E-02 Osmotic coef. = 0.9625 True ionic strength = .8757658E-02 Chg. balance for total moles = 0.6634E-13 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.14615E-09 -9.8352 0.12850E-09 -9.8911 0.87927E+00 -0.0559 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13790E-03 -3.8604 0.12088E-03 -3.9176 0.87659E+00 -0.0572 4 SO4-- 0.25530E-04 -4.5930 0.16004E-04 -4.7958 0.62688E+00 -0.2028 5 HCO3- 0.67047E-05 -5.1736 0.58816E-05 -5.2305 0.87723E+00 -0.0569 6 HS- 0.71541E-12 -12.1454 0.62717E-12 -12.2026 0.87665E+00 -0.0572 7 Al+++ 0.64817E-27 -27.1883 0.23023E-27 -27.6378 0.35519E+00 -0.4495 8 H4SiO4 0.40103E-03 -3.3968 0.40103E-03 -3.3968 0.10000E+01 0.0000 9 Ca++ 0.40474E-07 -7.3928 0.25279E-07 -7.5972 0.62457E+00 -0.2044 10 Mg++ 0.17620E-10 -10.7540 0.10980E-10 -10.9594 0.62312E+00 -0.2054 11 Fe++ 0.10390E-12 -12.9834 0.64781E-13 -13.1885 0.62347E+00 -0.2052 12 K+ 0.68285E-04 -4.1657 0.59909E-04 -4.2225 0.87735E+00 -0.0568 13 Na+ 0.86569E-02 -2.0626 0.75879E-02 -2.1199 0.87652E+00 -0.0572 14 Mn++ 0.13957E-10 -10.8552 0.87053E-11 -11.0602 0.62373E+00 -0.2050 15 HPO4-- 0.42226E-06 -6.3744 0.26473E-06 -6.5772 0.62693E+00 -0.2028 16 HSiO3- 0.33242E-02 -2.4783 0.29140E-02 -2.5355 0.87659E+00 -0.0572 17 Ca(HSiO3)+ 0.19119E-08 -8.7185 0.16775E-08 -8.7753 0.87744E+00 -0.0568 18 Mg(HSiO3)+ 0.10334E-11 -11.9857 0.90679E-12 -12.0425 0.87744E+00 -0.0568 19 NaHSiO3,aq 0.35761E-03 -3.4466 0.35761E-03 -3.4466 0.10000E+01 0.0000 20 AlO+ 0.21616E-14 -14.6652 0.18967E-14 -14.7220 0.87744E+00 -0.0568 22 HAlO2,aq 0.29394E-08 -8.5317 0.29394E-08 -8.5317 0.10000E+01 0.0000 23 AlO2- 0.57816E-04 -4.2380 0.50634E-04 -4.2956 0.87578E+00 -0.0576 24 CH4,aq 0.22423E-18 -18.6493 0.22389E-18 -18.6500 0.99848E+00 -0.0007 29 CO,aq 0.64601E-19 -19.1898 0.64601E-19 -19.1898 0.10000E+01 0.0000 30 CO2,aq 0.16174E-08 -8.7912 0.16150E-08 -8.7918 0.99848E+00 -0.0007 31 CO3-2 0.63841E-05 -5.1949 0.39978E-05 -5.3982 0.62621E+00 -0.2033 32 CaCO3,aq 0.12672E-08 -8.8972 0.12672E-08 -8.8972 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.43253E-11 -11.3640 0.37952E-11 -11.4208 0.87744E+00 -0.0568 34 CaCl+ 0.56358E-11 -11.2490 0.49451E-11 -11.3058 0.87744E+00 -0.0568 35 CaCl2,aq 0.14202E-15 -15.8477 0.14202E-15 -15.8477 0.10000E+01 0.0000 36 CaOH+ 0.15978E-07 -7.7965 0.14020E-07 -7.8533 0.87744E+00 -0.0568 37 CaSO4,aq 0.12847E-09 -9.8912 0.12847E-09 -9.8912 0.10000E+01 0.0000 38 HCl,aq 0.28465E-14 -14.5457 0.28465E-14 -14.5457 0.10000E+01 0.0000 43 FeCl+ 0.14126E-16 -16.8500 0.12395E-16 -16.9068 0.87744E+00 -0.0568 46 FeO,aq 0.15247E-09 -9.8168 0.15247E-09 -9.8168 0.10000E+01 0.0000 47 FeOH+ 0.18702E-10 -10.7281 0.16410E-10 -10.7849 0.87744E+00 -0.0568 48 HFeO2- 0.14162E-07 -7.8489 0.12415E-07 -7.9061 0.87659E+00 -0.0572 49 FeO+ 0.11179E-14 -14.9516 0.98085E-15 -15.0084 0.87744E+00 -0.0568 51 FeO2- 0.13865E-07 -7.8581 0.12154E-07 -7.9153 0.87659E+00 -0.0572 52 HFeO2,aq 0.19864E-09 -9.7019 0.19864E-09 -9.7019 0.10000E+01 0.0000 53 H2,aq 0.15948E-08 -8.7973 0.15924E-08 -8.7980 0.99848E+00 -0.0007 54 KCl,aq 0.13125E-09 -9.8819 0.13125E-09 -9.8819 0.10000E+01 0.0000 55 KHSO4,aq 0.34836E-18 -18.4580 0.34836E-18 -18.4580 0.10000E+01 0.0000 56 KOH,aq 0.19910E-06 -6.7009 0.19910E-06 -6.7009 0.10000E+01 0.0000 57 KSO4- 0.16973E-07 -7.7702 0.14878E-07 -7.8274 0.87659E+00 -0.0572 58 MgCO3,aq 0.13796E-12 -12.8603 0.13796E-12 -12.8603 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.19196E-14 -14.7168 0.16844E-14 -14.7736 0.87744E+00 -0.0568 60 MgCl+ 0.22186E-14 -14.6539 0.19467E-14 -14.7107 0.87744E+00 -0.0568 61 MgOH+ 0.38402E-10 -10.4156 0.33696E-10 -10.4724 0.87744E+00 -0.0568 63 MnO,aq 0.54594E-09 -9.2629 0.54594E-09 -9.2629 0.10000E+01 0.0000 64 MnOH+ 0.23346E-09 -9.6318 0.20485E-09 -9.6886 0.87744E+00 -0.0568 65 MnO2-2 0.17521E-11 -11.7564 0.10972E-11 -11.9597 0.62621E+00 -0.2033 66 HMnO2- 0.35238E-10 -10.4530 0.30890E-10 -10.5102 0.87659E+00 -0.0572 69 MnCl+ 0.73851E-14 -14.1316 0.64800E-14 -14.1884 0.87744E+00 -0.0568 70 MnSO4,aq 0.40221E-13 -13.3955 0.40221E-13 -13.3955 0.10000E+01 0.0000 71 NaCl,aq 0.30397E-06 -6.5172 0.30397E-06 -6.5172 0.10000E+01 0.0000 72 NaOH,aq 0.25370E-04 -4.5957 0.25370E-04 -4.5957 0.10000E+01 0.0000 74 OH- 0.51339E-02 -2.2896 0.44962E-02 -2.3472 0.87578E+00 -0.0576 79 HPO3-2 0.20978E-17 -17.6782 0.13137E-17 -17.8815 0.62621E+00 -0.2033 82 H3PO4,aq 0.30574E-16 -16.5146 0.30574E-16 -16.5146 0.10000E+01 0.0000 83 H2PO4- 0.71556E-09 -9.1454 0.62755E-09 -9.2024 0.87701E+00 -0.0570 84 PO4-3 0.46158E-08 -8.3358 0.16808E-08 -8.7745 0.36414E+00 -0.4387 87 H2P2O7-2 0.49312E-19 -19.3070 0.30880E-19 -19.5103 0.62621E+00 -0.2033 88 HP2O7-3 0.13504E-15 -15.8696 0.47982E-16 -16.3189 0.35533E+00 -0.4494 89 P2O7-4 0.54629E-15 -15.2626 0.89203E-16 -16.0496 0.16329E+00 -0.7870 90 H2S,aq 0.24946E-15 -15.6030 0.24908E-15 -15.6037 0.99848E+00 -0.0007 97 SO3-2 0.52500E-14 -14.2798 0.33117E-14 -14.4800 0.63080E+00 -0.2001 98 HSO3- 0.30397E-16 -16.5172 0.26646E-16 -16.5744 0.87659E+00 -0.0572 99 HSO4- 0.22577E-11 -11.6463 0.19820E-11 -11.7029 0.87786E+00 -0.0566 Charge balance for all species = 0.6063E-13 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.1461475E-09 -.9079060E-02 -.9145386E+01 0.0000 2 H2O 0.1000000E+01 0.5550984E+02 0.9993968E+06 0.0000 3 Cl- 0.1378993E-03 0.1382034E-03 0.4896639E+01 5.9734 4 SO4-- 0.2552973E-04 0.2554819E-04 0.2452655E+01 14.9864 5 HCO3- 0.6704672E-05 0.1309171E-04 0.7983166E+00 4.6606 6 HS- 0.7154100E-12 -.1358574E-08 -.4490247E-04 -2.3115 7 Al+++ 0.6481687E-27 0.5781863E-04 0.1559051E+01 2.0354 8 H4SiO4 0.4010262E-03 0.4082854E-02 0.3921780E+03 -3.3968 9 Ca++ 0.4047362E-07 0.5976911E-07 0.2393918E-02 12.1849 10 Mg++ 0.1762036E-10 0.5719835E-10 0.1389731E-05 8.8228 11 Fe++ 0.1039049E-12 0.2839755E-07 0.1584919E-02 6.5936 12 K+ 0.6828469E-04 0.6850089E-04 0.2676835E+01 5.6686 13 Na+ 0.8656884E-02 0.9040171E-02 0.2077009E+03 7.7712 14 Mn++ 0.1395683E-10 0.8303975E-09 0.4559165E-04 8.7220 15 HPO4-- 0.4222638E-06 0.4275952E-06 0.4101432E-01 13.2050 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.1721790E+00 -.9064004E-02 -.1631150E+00 0.0000000E+00 2 H2O 0.5537789E+02 0.5541779E+02 -.3989279E-01 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.3136962E-03 0.2550583E-04 0.2881904E-03 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.2881917E-03 -.1356321E-08 -.2881904E-03 0.0000000E+00 7 Al+++ 0.3390845E-01 0.5772275E-04 0.3385073E-01 0.0000000E+00 8 H4SiO4 0.1082825E+00 0.4076083E-02 0.1042064E+00 0.0000000E+00 9 Ca++ 0.1197480E-01 0.5966999E-07 0.1197474E-01 0.0000000E+00 10 Mg++ 0.8253175E-02 0.5710349E-10 0.8253175E-02 0.0000000E+00 11 Fe++ 0.7414576E-02 0.2835045E-07 0.7414548E-02 0.0000000E+00 12 K+ 0.2207856E-02 0.6838729E-04 0.2139468E-02 0.0000000E+00 13 Na+ 0.1321335E-01 0.9025179E-02 0.4188171E-02 0.0000000E+00 14 Mn++ 0.1803041E-03 0.8290203E-09 0.1803032E-03 0.0000000E+00 15 HPO4-- 0.6153688E-04 0.4268861E-06 0.6110999E-04 0.0000000E+00 Chg. balance for solid moles: -.9568E-17 Mass of aqueous solution: 0.998971E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 10.3990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 0.4188E-02 -2.378 1.098 0.041 9.672 0.4216 apatite-OH 0.2037E-04 -4.691 0.1023E-01 -1.990 0.9012E-01 0.3251E-02 clinochlore 0.1651E-02 -2.782 0.9175 -0.037 8.080 0.3490 daphnite 0.1022E-02 -2.991 0.7291 -0.137 6.421 0.2209 chlorite-Mn 0.3606E-04 -4.443 0.2557E-01 -1.592 0.2252 0.8147E-02 hematite 0.8795E-03 -3.056 0.1405 -0.852 1.237 0.2662E-01 microcline 0.2139E-02 -2.670 0.5955 -0.225 5.245 0.2326 prehnite-Fe 0.5466E-03 -3.262 0.2412 -0.618 2.124 0.8090E-01 stilbite 0.1078E-01 -1.967 7.597 0.881 66.91 3.543 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.6094E+00 0.6094E+00 1.0000 -0.215 daphnite 0.3773E+00 0.3773E+00 1.0000 -0.423 chlorite-Mn 0.1331E-01 0.1331E-01 1.0000 -1.876 hematite 0.1000E+01 0.1000E+01 1.0000 0.000 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 prehnite-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 11.354395 g Volume = 4.886275 cm3 Porosity: 5.2974% V(tot) - V(min): 0.27332E+00 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 10.3990000 g log = 1.0170 Original solution: 1000.0103000 g Original solution / Rock added: 96.16 (Water/Rock Ratio), log = 1.9830 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0203 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.1000E+01 0.9860 0.1006E+01 0.1020E+01 CO2,gas 0.1682E-06 1.0071 0.1728E-06 0.1716E-06 CH4,gas 0.3190E-15 1.0125 0.3295E-15 0.3255E-15 H2,gas 0.2048E-05 1.0005 0.2091E-05 0.2089E-05 H2S,gas 0.6738E-14 0.9960 0.6847E-14 0.6874E-14 S2,gas 0.3946E-36 1.0000 0.4027E-36 0.4027E-36 CO,gas 0.9435E-16 1.0000 0.9627E-16 0.9627E-16 SO3,gas 0.9794E-40 1.0000 0.9993E-40 0.9993E-40 SO2,gas 0.7966E-23 1.0000 0.8127E-23 0.8127E-23 HCl,gas 0.4923E-17 1.0000 0.5023E-17 0.5023E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 16 albite -0.38 -0.38 0.00 0.000 0.11184E-10 32 apatite-OH -18.15 -18.15 0.00 0.000 -0.60662E-11 46 clinochlore 39.07 39.07 0.00 0.000 0.00000E+00 47 daphnite 28.97 28.97 0.00 0.000 0.00000E+00 48 chlorite-Mn 46.87 46.87 0.00 0.000 0.24265E-10 90 hematite 12.57 12.57 0.00 0.000 0.90992E-11 116 microcline -2.49 -2.49 0.00 0.000 0.15165E-11 137 prehnite-Fe 22.50 22.50 0.00 0.000 0.00000E+00 163 stilbite -7.52 -7.52 0.00 0.000 -0.90992E-11 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -15.12 -8.46 -2.820 0.14448E+05 -6.762 3 CH4,gas 4.54 -12.64 -17.18 -4.295 0.29336E+05 -15.482 4 H2,gas 8.00 0.62 -7.38 -4.216 0.12599E+05 -5.680 5 H2S,gas -6.23 -22.09 -15.86 -7.932 0.27086E+05 -14.164 6 S2,gas -7.34 -45.43 -38.09 -5.861 0.65045E+05 -36.395 7 CO,gas 3.21 -14.50 -17.72 -5.451 0.30249E+05 -16.017 8 SO3,gas 17.12 -24.58 -41.70 -10.425 0.71200E+05 -40.000 9 SO2,gas 0.83 -23.96 -24.79 -6.610 0.42327E+05 -23.090 10 HCl,gas 5.19 -13.81 -19.00 -9.499 0.32439E+05 -17.299 11 acmite 7.71 7.26 -0.45 -0.047 0.76677E+03 15 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 19 spessartine 24.46 20.05 -4.41 -0.221 0.75319E+04 20 analcite 3.32 3.01 -0.31 -0.034 0.52744E+03 21 andalusite 5.00 0.67 -4.33 -0.433 0.73891E+04 22 andradite 39.01 38.93 -0.08 -0.004 0.13366E+03 23 grossular 32.73 30.44 -2.30 -0.115 0.39209E+04 26 annite 20.12 17.29 -2.83 -0.157 0.48305E+04 27 phlogopite 27.06 23.98 -3.08 -0.171 0.52638E+04 29 anorthite 12.71 9.46 -3.25 -0.250 0.55463E+04 35 aragonite 0.97 -2.94 -3.90 -1.301 0.66646E+04 36 brucite 12.57 8.82 -3.75 -0.749 0.63959E+04 37 calcite 0.81 -2.94 -3.75 -1.249 0.64004E+04 38 carnegieite-low 9.02 6.41 -2.61 -0.373 0.44625E+04 39 carnegieite-high 10.09 6.41 -3.68 -0.526 0.62895E+04 40 carpholite-Mg 8.58 6.10 -2.48 -0.165 0.42382E+04 41 carpholite-Fe 6.71 3.87 -2.84 -0.189 0.48524E+04 42 celadonite 5.34 2.94 -2.40 -0.141 0.41016E+04 43 celadonite-Fe 3.88 0.71 -3.17 -0.186 0.54062E+04 44 chrysotile 23.89 19.67 -4.22 -0.351 0.72017E+04 50 chloritoid-Mg 13.20 9.50 -3.70 -0.247 0.63193E+04 51 chloritoid-Fe 9.17 7.27 -1.91 -0.127 0.32545E+04 52 chloritoid-Mn 11.40 9.40 -2.01 -0.134 0.34237E+04 54 coesite -2.38 -3.40 -1.02 -0.340 0.17429E+04 59 corundum 8.38 4.07 -4.31 -0.392 0.73631E+04 61 cristobalite -2.56 -3.40 -0.84 -0.279 0.14283E+04 63 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71234E+04 65 diaspore 2.87 2.04 -0.84 -0.140 0.14314E+04 67 diopside 16.18 14.21 -1.97 -0.197 0.33592E+04 68 hedenbergite 14.21 11.98 -2.22 -0.222 0.37964E+04 75 epidote 24.67 24.53 -0.14 -0.007 0.23332E+03 76 clinozoisite 22.81 20.29 -2.52 -0.115 0.43036E+04 77 epidote-Fe 29.84 28.78 -1.06 -0.055 0.18097E+04 78 fayalite 14.05 9.79 -4.26 -0.608 0.72658E+04 79 ferrosilite 11.15 6.39 -4.76 -0.476 0.81205E+04 83 gibbsite 4.08 2.04 -2.04 -0.292 0.34899E+04 84 glaucophane 22.97 18.91 -4.07 -0.110 0.69459E+04 87 greenalite 16.14 12.99 -3.15 -0.263 0.53825E+04 91 heulandite -5.83 -7.52 -1.69 -0.077 0.28938E+04 95 jadeite 4.22 3.01 -1.20 -0.120 0.20529E+04 96 julgoldite 70.43 66.68 -3.75 -0.097 0.64006E+04 97 kalsilite 7.58 4.31 -3.28 -0.468 0.55950E+04 98 kaolinite -1.33 -2.72 -1.39 -0.126 0.23735E+04 99 kyanite 4.88 0.67 -4.20 -0.420 0.71750E+04 101 laumontite 2.88 2.67 -0.21 -0.014 0.36708E+03 102 lawsonite 9.62 9.46 -0.15 -0.010 0.26293E+03 103 leucite 4.12 0.91 -3.21 -0.321 0.54785E+04 105 lizardite 23.24 19.67 -3.57 -0.297 0.60944E+04 107 magnetite 20.09 19.16 -0.93 -0.076 0.15838E+04 108 minnesotaite 10.39 6.19 -4.19 -0.247 0.71621E+04 110 magnesioferrite 26.21 21.39 -4.82 -0.394 0.82359E+04 113 margarite 17.32 13.53 -3.79 -0.152 0.64725E+04 120 muscovite 2.58 1.58 -1.00 -0.059 0.17042E+04 121 paragonite 4.24 3.69 -0.55 -0.032 0.94335E+03 122 nepheline 8.34 6.41 -1.93 -0.276 0.32949E+04 134 phlogopite-Na 29.65 26.08 -3.56 -0.198 0.60826E+04 136 prehnite 19.37 18.25 -1.12 -0.066 0.19153E+04 138 pumpellyite-Fe 46.27 45.13 -1.14 -0.025 0.19466E+04 139 pumpellyite-Mg 48.99 47.36 -1.64 -0.036 0.27940E+04 145 pyroxmangite 7.40 5.33 -2.07 -0.415 0.35405E+04 146 pyrophyllite -6.18 -9.52 -3.34 -0.209 0.57041E+04 147 quartz -2.99 -3.40 -0.41 -0.136 0.69561E+03 152 rhodonite 7.45 5.33 -2.12 -0.424 0.36208E+04 153 sanidine -1.28 -2.49 -1.21 -0.093 0.20677E+04 156 sillimanite 5.26 0.67 -4.59 -0.459 0.78331E+04 164 stilpnomelane-Fe 13.02 12.70 -0.32 -0.010 0.54363E+03 165 stilpnomelane-Mg 27.44 23.84 -3.60 -0.107 0.61420E+04 171 talc 16.49 12.88 -3.61 -0.212 0.61642E+04 174 tephroite 18.09 14.05 -4.04 -0.577 0.68960E+04 177 topaz-H 4.62 0.67 -3.94 -0.359 0.67351E+04 178 tridymite -2.63 -3.40 -0.77 -0.257 0.13156E+04 187 wairakite 3.95 2.67 -1.28 -0.075 0.21890E+04 188 walstromite 11.51 8.79 -2.72 -0.544 0.46463E+04 189 wollastonite 10.46 8.79 -1.67 -0.335 0.28567E+04 190 pseudo-wollastonite 11.00 8.79 -2.21 -0.442 0.37765E+04 191 zoisite 22.85 20.29 -2.56 -0.117 0.43776E+04 192 akaganeite 7.75 6.28 -1.47 -0.318 0.25125E+04 193 beidellite-Ca -1.65 -5.71 -4.07 -0.252 0.69456E+04 195 beidellite-K -1.52 -5.85 -4.33 -0.265 0.73985E+04 196 beidellite-Mg -1.79 -6.27 -4.48 -0.277 0.76466E+04 197 beidellite-Na -1.34 -5.16 -3.82 -0.234 0.65176E+04 199 chalcedony -2.80 -3.40 -0.59 -0.198 0.10149E+04 201 montmorillonite-Ca -2.29 -5.27 -2.98 -0.184 0.50805E+04 202 montmorillonite-K -2.24 -5.41 -3.17 -0.194 0.54115E+04 203 montmorillonite-Mg -2.48 -5.82 -3.34 -0.207 0.57047E+04 204 montmorillonite-Na -2.04 -4.71 -2.67 -0.164 0.45664E+04 205 nontronite-Ca 3.21 2.78 -0.43 -0.028 0.73851E+03 206 nontronite-H 2.53 0.77 -1.76 -0.118 0.30072E+04 207 nontronite-K 3.34 2.64 -0.70 -0.045 0.11928E+04 208 nontronite-Mg 3.07 2.23 -0.85 -0.055 0.14468E+04 209 nontronite-Na 3.52 3.34 -0.18 -0.012 0.31364E+03 224 tobermorite 9.82 6.75 -3.07 -0.838 0.52417E+04 233 boehmite 4.41 2.04 -2.37 -0.395 0.40483E+04 235 ferrous-oxide 9.81 6.59 -3.22 -0.804 0.54946E+04 240 silica-amorphous -2.09 -3.40 -1.31 -0.435 0.22291E+04 242 an20ab80 2.02 1.59 -0.43 -0.033 0.73840E+03 243 an25ab75 2.65 2.08 -0.57 -0.044 0.96998E+03 244 an30ab70 3.28 2.57 -0.71 -0.055 0.12112E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 0.4000000 g Current total amount of reactant added: 10.3990000 g New total amount of reactant added: 10.7990000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.6634E-13 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 8 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 10.7990000 Water: Moles liquid = 0.5541E+02 kg liquid = 0.9983E+00 Moles total = 0.5537E+02 kg total = 0.9976E+00 Activity = 1.0000 Stoichiometric ionic strength = .5017405E-02 Osmotic coef. = 0.9623 True ionic strength = .8951048E-02 Chg. balance for total moles = 0.6634E-13 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.14539E-09 -9.8375 0.12771E-09 -9.8938 0.87836E+00 -0.0563 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13790E-03 -3.8604 0.12075E-03 -3.9181 0.87562E+00 -0.0577 4 SO4-- 0.25531E-04 -4.5929 0.15936E-04 -4.7976 0.62420E+00 -0.2047 5 HCO3- 0.66741E-05 -5.1756 0.58484E-05 -5.2330 0.87628E+00 -0.0574 6 HS- 0.93893E-12 -12.0274 0.82221E-12 -12.0850 0.87569E+00 -0.0577 7 Al+++ 0.55364E-27 -27.2568 0.19473E-27 -27.7106 0.35173E+00 -0.4538 8 H4SiO4 0.41763E-03 -3.3792 0.41763E-03 -3.3792 0.10000E+01 0.0000 9 Ca++ 0.40694E-07 -7.3905 0.25306E-07 -7.5968 0.62185E+00 -0.2063 10 Mg++ 0.18105E-10 -10.7422 0.11232E-10 -10.9496 0.62038E+00 -0.2073 11 Fe++ 0.10676E-12 -12.9716 0.66269E-13 -13.1787 0.62073E+00 -0.2071 12 K+ 0.69797E-04 -4.1562 0.61169E-04 -4.2135 0.87639E+00 -0.0573 13 Na+ 0.88487E-02 -2.0531 0.77475E-02 -2.1108 0.87555E+00 -0.0577 14 Mn++ 0.14340E-10 -10.8434 0.89052E-11 -11.0504 0.62100E+00 -0.2069 15 HPO4-- 0.41983E-06 -6.3769 0.26207E-06 -6.5816 0.62424E+00 -0.2046 16 HSiO3- 0.34873E-02 -2.4575 0.30536E-02 -2.5152 0.87562E+00 -0.0577 17 Ca(HSiO3)+ 0.20078E-08 -8.6973 0.17598E-08 -8.7545 0.87649E+00 -0.0573 18 Mg(HSiO3)+ 0.11090E-11 -11.9551 0.97205E-12 -12.0123 0.87649E+00 -0.0573 19 NaHSiO3,aq 0.38263E-03 -3.4172 0.38263E-03 -3.4172 0.10000E+01 0.0000 20 AlO+ 0.18533E-14 -14.7321 0.16244E-14 -14.7893 0.87649E+00 -0.0573 22 HAlO2,aq 0.25331E-08 -8.5963 0.25331E-08 -8.5963 0.10000E+01 0.0000 23 AlO2- 0.50192E-04 -4.2994 0.43908E-04 -4.3575 0.87480E+00 -0.0581 24 CH4,aq 0.29356E-18 -18.5323 0.29310E-18 -18.5330 0.99845E+00 -0.0007 29 CO,aq 0.68488E-19 -19.1644 0.68488E-19 -19.1644 0.10000E+01 0.0000 30 CO2,aq 0.15984E-08 -8.7963 0.15959E-08 -8.7970 0.99845E+00 -0.0007 31 CO3-2 0.64154E-05 -5.1928 0.40001E-05 -5.3979 0.62351E+00 -0.2052 32 CaCO3,aq 0.12692E-08 -8.8965 0.12692E-08 -8.8965 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.43101E-11 -11.3655 0.37778E-11 -11.4228 0.87649E+00 -0.0573 34 CaCl+ 0.56418E-11 -11.2486 0.49450E-11 -11.3058 0.87649E+00 -0.0573 35 CaCl2,aq 0.14186E-15 -15.8481 0.14186E-15 -15.8481 0.10000E+01 0.0000 36 CaOH+ 0.16112E-07 -7.7928 0.14122E-07 -7.8501 0.87649E+00 -0.0573 37 CaSO4,aq 0.12806E-09 -9.8926 0.12806E-09 -9.8926 0.10000E+01 0.0000 38 HCl,aq 0.28257E-14 -14.5489 0.28257E-14 -14.5489 0.10000E+01 0.0000 43 FeCl+ 0.14450E-16 -16.8401 0.12666E-16 -16.8974 0.87649E+00 -0.0573 46 FeO,aq 0.15793E-09 -9.8015 0.15793E-09 -9.8015 0.10000E+01 0.0000 47 FeOH+ 0.19272E-10 -10.7151 0.16891E-10 -10.7723 0.87649E+00 -0.0573 48 HFeO2- 0.14777E-07 -7.8304 0.12939E-07 -7.8881 0.87562E+00 -0.0577 49 FeO+ 0.11121E-14 -14.9538 0.97476E-15 -15.0111 0.87649E+00 -0.0573 51 FeO2- 0.13967E-07 -7.8549 0.12230E-07 -7.9126 0.87562E+00 -0.0577 52 HFeO2,aq 0.19864E-09 -9.7019 0.19864E-09 -9.7019 0.10000E+01 0.0000 53 H2,aq 0.17110E-08 -8.7667 0.17084E-08 -8.7674 0.99845E+00 -0.0007 54 KCl,aq 0.13387E-09 -9.8733 0.13387E-09 -9.8733 0.10000E+01 0.0000 55 KHSO4,aq 0.35198E-18 -18.4535 0.35198E-18 -18.4535 0.10000E+01 0.0000 56 KOH,aq 0.20455E-06 -6.6892 0.20455E-06 -6.6892 0.10000E+01 0.0000 57 KSO4- 0.17275E-07 -7.7626 0.15127E-07 -7.8203 0.87562E+00 -0.0577 58 MgCO3,aq 0.14121E-12 -12.8501 0.14121E-12 -12.8501 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.19548E-14 -14.7089 0.17133E-14 -14.7662 0.87649E+00 -0.0573 60 MgCl+ 0.22695E-14 -14.6441 0.19892E-14 -14.7013 0.87649E+00 -0.0573 61 MgOH+ 0.39572E-10 -10.4026 0.34685E-10 -10.4599 0.87649E+00 -0.0573 63 MnO,aq 0.56548E-09 -9.2476 0.56548E-09 -9.2476 0.10000E+01 0.0000 64 MnOH+ 0.24057E-09 -9.6188 0.21086E-09 -9.6760 0.87649E+00 -0.0573 65 MnO2-2 0.18455E-11 -11.7339 0.11507E-11 -11.9390 0.62351E+00 -0.2052 66 HMnO2- 0.36768E-10 -10.4345 0.32195E-10 -10.4922 0.87562E+00 -0.0577 69 MnCl+ 0.75546E-14 -14.1218 0.66216E-14 -14.1790 0.87649E+00 -0.0573 70 MnSO4,aq 0.40970E-13 -13.3875 0.40970E-13 -13.3875 0.10000E+01 0.0000 71 NaCl,aq 0.31003E-06 -6.5086 0.31003E-06 -6.5086 0.10000E+01 0.0000 72 NaOH,aq 0.26065E-04 -4.5839 0.26065E-04 -4.5839 0.10000E+01 0.0000 74 OH- 0.51718E-02 -2.2864 0.45243E-02 -2.3445 0.87480E+00 -0.0581 79 HPO3-2 0.22377E-17 -17.6502 0.13952E-17 -17.8554 0.62351E+00 -0.2052 82 H3PO4,aq 0.29893E-16 -16.5244 0.29893E-16 -16.5244 0.10000E+01 0.0000 83 H2PO4- 0.70476E-09 -9.1520 0.61740E-09 -9.2094 0.87605E+00 -0.0575 84 PO4-3 0.46411E-08 -8.3334 0.16743E-08 -8.7762 0.36076E+00 -0.4428 87 H2P2O7-2 0.47936E-19 -19.3193 0.29889E-19 -19.5245 0.62351E+00 -0.2052 88 HP2O7-3 0.13281E-15 -15.8768 0.46733E-16 -16.3304 0.35187E+00 -0.4536 89 P2O7-4 0.54464E-15 -15.2639 0.87422E-16 -16.0584 0.16051E+00 -0.7945 90 H2S,aq 0.32502E-15 -15.4881 0.32452E-15 -15.4888 0.99845E+00 -0.0007 97 SO3-2 0.56320E-14 -14.2493 0.35379E-14 -14.4513 0.62817E+00 -0.2019 98 HSO3- 0.32307E-16 -16.4907 0.28289E-16 -16.5484 0.87562E+00 -0.0577 99 HSO4- 0.22366E-11 -11.6504 0.19613E-11 -11.7075 0.87692E+00 -0.0570 Charge balance for all species = 0.6153E-13 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.1453917E-09 -.9275267E-02 -.9342826E+01 0.0000 2 H2O 0.1000000E+01 0.5550968E+02 0.9993725E+06 0.0000 3 Cl- 0.1379007E-03 0.1382108E-03 0.4896799E+01 5.9757 4 SO4-- 0.2553081E-04 0.2554956E-04 0.2452733E+01 14.9900 5 HCO3- 0.6674111E-05 0.1309242E-04 0.7983426E+00 4.6608 6 HS- 0.9389279E-12 -.1342047E-08 -.4435528E-04 -2.1912 7 Al+++ 0.5536373E-27 0.5019482E-04 0.1353450E+01 1.9708 8 H4SiO4 0.4176291E-03 0.4287566E-02 0.4118328E+03 -3.3792 9 Ca++ 0.4069403E-07 0.6022150E-07 0.2411986E-02 12.1908 10 Mg++ 0.1810459E-10 0.5893152E-10 0.1431811E-05 8.8380 11 Fe++ 0.1067592E-12 0.2912027E-07 0.1625221E-02 6.6089 12 K+ 0.6979671E-04 0.7001867E-04 0.2736088E+01 5.6803 13 Na+ 0.8848731E-02 0.9257734E-02 0.2126949E+03 7.7830 14 Mn++ 0.1434013E-10 0.8590532E-09 0.4716394E-04 8.7372 15 HPO4-- 0.4198276E-06 0.4251735E-06 0.4078116E-01 13.2060 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.1788024E+00 -.9259386E-02 -.1695430E+00 0.0000000E+00 2 H2O 0.5537288E+02 0.5541464E+02 -.4175556E-01 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.3247816E-03 0.2550581E-04 0.2992758E-03 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.2992771E-03 -.1339749E-08 -.2992758E-03 0.0000000E+00 7 Al+++ 0.3521275E-01 0.5010887E-04 0.3516264E-01 0.0000000E+00 8 H4SiO4 0.1124476E+00 0.4280224E-02 0.1081674E+00 0.0000000E+00 9 Ca++ 0.1243486E-01 0.6011838E-07 0.1243480E-01 0.0000000E+00 10 Mg++ 0.8570635E-02 0.5883062E-10 0.8570635E-02 0.0000000E+00 11 Fe++ 0.7699780E-02 0.2907041E-07 0.7699751E-02 0.0000000E+00 12 K+ 0.2292781E-02 0.6989879E-04 0.2222883E-02 0.0000000E+00 13 Na+ 0.1371545E-01 0.9241883E-02 0.4473564E-02 0.0000000E+00 14 Mn++ 0.1872395E-03 0.8575824E-09 0.1872386E-03 0.0000000E+00 15 HPO4-- 0.6390391E-04 0.4244455E-06 0.6347946E-04 0.0000000E+00 Chg. balance for solid moles: 0.1946E-16 Mass of aqueous solution: 0.998938E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 10.7990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 0.4474E-02 -2.349 1.173 0.069 9.955 0.4503 apatite-OH 0.2116E-04 -4.674 0.1063E-01 -1.974 0.9020E-01 0.3378E-02 clinochlore 0.1714E-02 -2.766 0.9528 -0.021 8.085 0.3624 daphnite 0.1061E-02 -2.974 0.7571 -0.121 6.425 0.2294 chlorite-Mn 0.3745E-04 -4.427 0.2655E-01 -1.576 0.2253 0.8461E-02 hematite 0.8942E-03 -3.049 0.1428 -0.845 1.212 0.2707E-01 microcline 0.2223E-02 -2.653 0.6187 -0.209 5.251 0.2417 prehnite-Fe 0.6057E-03 -3.218 0.2673 -0.573 2.268 0.8966E-01 stilbite 0.1112E-01 -1.954 7.835 0.894 66.49 3.654 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.6094E+00 0.6094E+00 1.0000 -0.215 daphnite 0.3773E+00 0.3773E+00 1.0000 -0.423 chlorite-Mn 0.1331E-01 0.1331E-01 1.0000 -1.876 hematite 0.1000E+01 0.1000E+01 1.0000 0.000 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 prehnite-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 11.783670 g Volume = 5.066666 cm3 Porosity: 4.7548% V(tot) - V(min): 0.25293E+00 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 10.7990000 g log = 1.0334 Original solution: 1000.0103000 g Original solution / Rock added: 92.60 (Water/Rock Ratio), log = 1.9666 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0203 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.1000E+01 0.9860 0.1006E+01 0.1020E+01 CO2,gas 0.1662E-06 1.0071 0.1707E-06 0.1695E-06 CH4,gas 0.4176E-15 1.0125 0.4314E-15 0.4261E-15 H2,gas 0.2197E-05 1.0005 0.2243E-05 0.2242E-05 H2S,gas 0.8778E-14 0.9960 0.8921E-14 0.8956E-14 S2,gas 0.5820E-36 1.0000 0.5938E-36 0.5938E-36 CO,gas 0.1000E-15 1.0000 0.1021E-15 0.1021E-15 SO3,gas 0.9631E-40 1.0000 0.9827E-40 0.9827E-40 SO2,gas 0.8404E-23 1.0000 0.8575E-23 0.8575E-23 HCl,gas 0.4887E-17 1.0000 0.4986E-17 0.4986E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 16 albite -0.38 -0.38 0.00 0.000 0.11184E-10 32 apatite-OH -18.15 -18.15 0.00 0.000 0.60662E-11 46 clinochlore 39.07 39.07 0.00 0.000 0.48529E-10 47 daphnite 28.97 28.97 0.00 0.000 0.60662E-10 48 chlorite-Mn 46.87 46.87 0.00 0.000 0.48529E-10 90 hematite 12.57 12.57 0.00 0.000 -0.30331E-11 116 microcline -2.49 -2.49 0.00 0.000 0.15165E-11 137 prehnite-Fe 22.50 22.50 0.00 0.000 0.00000E+00 163 stilbite -7.52 -7.52 0.00 0.000 -0.90992E-11 22 andradite 39.01 39.00 -0.01 0.000 0.13332E+02 23 grossular 32.73 30.38 -2.36 -0.118 0.40212E+04 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -15.13 -8.47 -2.822 0.14457E+05 -6.768 3 CH4,gas 4.54 -12.52 -17.06 -4.266 0.29136E+05 -15.365 4 H2,gas 8.00 0.65 -7.35 -4.199 0.12547E+05 -5.649 5 H2S,gas -6.23 -21.98 -15.75 -7.874 0.26890E+05 -14.050 6 S2,gas -7.34 -45.26 -37.93 -5.835 0.64756E+05 -36.226 7 CO,gas 3.21 -14.48 -17.69 -5.443 0.30205E+05 -15.991 8 SO3,gas 17.12 -24.59 -41.71 -10.427 0.71213E+05 -40.008 9 SO2,gas 0.83 -23.93 -24.77 -6.604 0.42287E+05 -23.067 10 HCl,gas 5.19 -13.81 -19.00 -9.501 0.32444E+05 -17.302 11 acmite 7.71 7.31 -0.40 -0.042 0.68655E+03 15 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 19 spessartine 24.46 20.02 -4.44 -0.222 0.75840E+04 20 analcite 3.32 3.00 -0.33 -0.036 0.55752E+03 21 andalusite 5.00 0.56 -4.44 -0.444 0.75797E+04 26 annite 20.12 17.34 -2.78 -0.155 0.47523E+04 27 phlogopite 27.06 24.03 -3.04 -0.169 0.51856E+04 29 anorthite 12.71 9.37 -3.34 -0.257 0.56967E+04 35 aragonite 0.97 -2.94 -3.90 -1.301 0.66634E+04 36 brucite 12.57 8.84 -3.73 -0.746 0.63698E+04 37 calcite 0.81 -2.94 -3.75 -1.249 0.63992E+04 38 carnegieite-low 9.02 6.37 -2.65 -0.378 0.45227E+04 39 carnegieite-high 10.09 6.37 -3.72 -0.531 0.63497E+04 40 carpholite-Mg 8.58 6.02 -2.56 -0.171 0.43726E+04 41 carpholite-Fe 6.71 3.79 -2.92 -0.195 0.49868E+04 42 celadonite 5.34 2.97 -2.37 -0.139 0.40455E+04 43 celadonite-Fe 3.88 0.74 -3.13 -0.184 0.53501E+04 44 chrysotile 23.89 19.76 -4.14 -0.345 0.70634E+04 50 chloritoid-Mg 13.20 9.40 -3.80 -0.253 0.64837E+04 51 chloritoid-Fe 9.17 7.17 -2.00 -0.133 0.34189E+04 52 chloritoid-Mn 11.40 9.30 -2.10 -0.140 0.35882E+04 54 coesite -2.38 -3.38 -1.00 -0.334 0.17128E+04 59 corundum 8.38 3.94 -4.44 -0.404 0.75837E+04 61 cristobalite -2.56 -3.38 -0.82 -0.273 0.13982E+04 63 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71234E+04 65 diaspore 2.87 1.97 -0.90 -0.150 0.15417E+04 67 diopside 16.18 14.27 -1.91 -0.191 0.32629E+04 68 hedenbergite 14.21 12.04 -2.17 -0.217 0.37001E+04 75 epidote 24.67 24.47 -0.20 -0.010 0.34362E+03 76 clinozoisite 22.81 20.16 -2.65 -0.120 0.45242E+04 77 epidote-Fe 29.84 28.78 -1.06 -0.055 0.18097E+04 78 fayalite 14.05 9.84 -4.21 -0.601 0.71836E+04 79 ferrosilite 11.15 6.46 -4.69 -0.469 0.80082E+04 83 gibbsite 4.08 1.97 -2.11 -0.301 0.36002E+04 84 glaucophane 22.97 18.99 -3.99 -0.108 0.68075E+04 85 glaucophane-Fe 17.28 12.30 -4.98 -0.134 0.84952E+04 87 greenalite 16.14 13.07 -3.07 -0.256 0.52441E+04 91 heulandite -5.83 -7.52 -1.69 -0.077 0.28938E+04 95 jadeite 4.22 3.00 -1.22 -0.122 0.20830E+04 96 julgoldite 70.43 66.84 -3.59 -0.093 0.61279E+04 97 kalsilite 7.58 4.27 -3.31 -0.473 0.56551E+04 98 kaolinite -1.33 -2.82 -1.48 -0.135 0.25339E+04 99 kyanite 4.88 0.56 -4.31 -0.431 0.73656E+04 101 laumontite 2.88 2.62 -0.27 -0.018 0.45732E+03 102 lawsonite 9.62 9.37 -0.24 -0.016 0.41334E+03 103 leucite 4.12 0.89 -3.23 -0.323 0.55086E+04 105 lizardite 23.24 19.76 -3.49 -0.291 0.59560E+04 107 magnetite 20.09 19.18 -0.91 -0.074 0.15578E+04 108 minnesotaite 10.39 6.31 -4.08 -0.240 0.69635E+04 110 magnesioferrite 26.21 21.40 -4.81 -0.393 0.82098E+04 113 margarite 17.32 13.32 -4.01 -0.160 0.68436E+04 120 muscovite 2.58 1.46 -1.13 -0.066 0.19248E+04 121 paragonite 4.24 3.56 -0.68 -0.040 0.11640E+04 122 nepheline 8.34 6.37 -1.96 -0.281 0.33550E+04 134 phlogopite-Na 29.65 26.13 -3.52 -0.195 0.60044E+04 136 prehnite 19.37 18.19 -1.19 -0.070 0.20256E+04 138 pumpellyite-Fe 46.27 44.95 -1.32 -0.029 0.22514E+04 139 pumpellyite-Mg 48.99 47.18 -1.81 -0.040 0.30989E+04 145 pyroxmangite 7.40 5.36 -2.04 -0.408 0.34844E+04 146 pyrophyllite -6.18 -9.58 -3.40 -0.212 0.58044E+04 147 quartz -2.99 -3.38 -0.39 -0.130 0.66553E+03 152 rhodonite 7.45 5.36 -2.09 -0.418 0.35646E+04 153 sanidine -1.28 -2.49 -1.21 -0.093 0.20677E+04 156 sillimanite 5.26 0.56 -4.70 -0.470 0.80236E+04 164 stilpnomelane-Fe 13.02 12.79 -0.22 -0.007 0.38319E+03 165 stilpnomelane-Mg 27.44 23.94 -3.50 -0.105 0.59816E+04 171 talc 16.49 13.00 -3.49 -0.206 0.59656E+04 174 tephroite 18.09 14.10 -3.99 -0.570 0.68138E+04 177 topaz-H 4.62 0.56 -4.06 -0.369 0.69257E+04 178 tridymite -2.63 -3.38 -0.75 -0.251 0.12855E+04 187 wairakite 3.95 2.62 -1.33 -0.079 0.22793E+04 188 walstromite 11.51 8.81 -2.70 -0.540 0.46061E+04 189 wollastonite 10.46 8.81 -1.65 -0.330 0.28166E+04 190 pseudo-wollastonite 11.00 8.81 -2.19 -0.438 0.37364E+04 191 zoisite 22.85 20.16 -2.69 -0.122 0.45982E+04 192 akaganeite 7.75 6.28 -1.47 -0.318 0.25125E+04 193 beidellite-Ca -1.65 -5.80 -4.15 -0.257 0.70905E+04 195 beidellite-K -1.52 -5.94 -4.41 -0.270 0.75384E+04 196 beidellite-Mg -1.79 -6.35 -4.56 -0.282 0.77889E+04 197 beidellite-Na -1.34 -5.24 -3.90 -0.239 0.66576E+04 199 chalcedony -2.80 -3.38 -0.58 -0.192 0.98483E+03 201 montmorillonite-Ca -2.29 -5.30 -3.01 -0.186 0.51341E+04 202 montmorillonite-K -2.24 -5.43 -3.20 -0.196 0.54602E+04 203 montmorillonite-Mg -2.48 -5.85 -3.37 -0.209 0.57557E+04 204 montmorillonite-Na -2.04 -4.74 -2.70 -0.166 0.46151E+04 205 nontronite-Ca 3.21 2.83 -0.39 -0.025 0.66285E+03 206 nontronite-H 2.53 0.81 -1.72 -0.115 0.29332E+04 207 nontronite-K 3.34 2.69 -0.65 -0.042 0.11121E+04 208 nontronite-Mg 3.07 2.27 -0.80 -0.052 0.13685E+04 209 nontronite-Na 3.52 3.38 -0.14 -0.009 0.23302E+03 224 tobermorite 9.82 6.78 -3.05 -0.831 0.52032E+04 233 boehmite 4.41 1.97 -2.44 -0.406 0.41586E+04 235 ferrous-oxide 9.81 6.61 -3.20 -0.801 0.54685E+04 240 silica-amorphous -2.09 -3.38 -1.29 -0.429 0.21990E+04 242 an20ab80 2.02 1.57 -0.45 -0.035 0.76849E+03 243 an25ab75 2.65 2.06 -0.59 -0.045 0.10076E+04 244 an30ab70 3.28 2.54 -0.74 -0.057 0.12563E+04 245 tr.625ac.25prg.125 45.16 40.20 -4.96 -0.134 0.84710E+04 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 10 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 10.7990000 Water: Moles liquid = 0.5541E+02 kg liquid = 0.9983E+00 Moles total = 0.5537E+02 kg total = 0.9976E+00 Activity = 1.0000 Stoichiometric ionic strength = .4957599E-02 Osmotic coef. = 0.9625 True ionic strength = .8798745E-02 Chg. balance for total moles = 0.6634E-13 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.14598E-09 -9.8357 0.12833E-09 -9.8917 0.87908E+00 -0.0560 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13790E-03 -3.8604 0.12086E-03 -3.9177 0.87638E+00 -0.0573 4 SO4-- 0.25531E-04 -4.5929 0.15990E-04 -4.7961 0.62631E+00 -0.2032 5 HCO3- 0.66983E-05 -5.1740 0.58746E-05 -5.2310 0.87703E+00 -0.0570 6 HS- 0.75858E-12 -12.1200 0.66486E-12 -12.1773 0.87645E+00 -0.0573 7 Al+++ 0.62647E-27 -27.2031 0.22205E-27 -27.6535 0.35445E+00 -0.4504 8 H4SiO4 0.40455E-03 -3.3930 0.40455E-03 -3.3930 0.10000E+01 0.0000 9 Ca++ 0.40519E-07 -7.3923 0.25283E-07 -7.5972 0.62399E+00 -0.2048 10 Mg++ 0.17723E-10 -10.7515 0.11033E-10 -10.9573 0.62254E+00 -0.2058 11 Fe++ 0.10451E-12 -12.9809 0.65096E-13 -13.1864 0.62288E+00 -0.2056 12 K+ 0.68606E-04 -4.1636 0.60177E-04 -4.2206 0.87714E+00 -0.0569 13 Na+ 0.86976E-02 -2.0606 0.76218E-02 -2.1179 0.87631E+00 -0.0573 14 Mn++ 0.14038E-10 -10.8527 0.87476E-11 -11.0581 0.62315E+00 -0.2054 15 HPO4-- 0.42175E-06 -6.3749 0.26417E-06 -6.5781 0.62635E+00 -0.2032 16 HSiO3- 0.33588E-02 -2.4738 0.29436E-02 -2.5311 0.87638E+00 -0.0573 17 Ca(HSiO3)+ 0.19321E-08 -8.7140 0.16949E-08 -8.7709 0.87724E+00 -0.0569 18 Mg(HSiO3)+ 0.10493E-11 -11.9791 0.92045E-12 -12.0360 0.87724E+00 -0.0569 19 NaHSiO3,aq 0.36286E-03 -3.4403 0.36286E-03 -3.4403 0.10000E+01 0.0000 20 AlO+ 0.20911E-14 -14.6796 0.18344E-14 -14.7365 0.87724E+00 -0.0569 22 HAlO2,aq 0.28467E-08 -8.5457 0.28467E-08 -8.5457 0.10000E+01 0.0000 23 AlO2- 0.56082E-04 -4.2512 0.49104E-04 -4.3089 0.87557E+00 -0.0577 24 CH4,aq 0.23763E-18 -18.6241 0.23727E-18 -18.6248 0.99847E+00 -0.0007 29 CO,aq 0.65420E-19 -19.1843 0.65420E-19 -19.1843 0.10000E+01 0.0000 30 CO2,aq 0.16133E-08 -8.7923 0.16108E-08 -8.7929 0.99847E+00 -0.0007 31 CO3-2 0.63912E-05 -5.1944 0.39985E-05 -5.3981 0.62563E+00 -0.2037 32 CaCO3,aq 0.12676E-08 -8.8970 0.12676E-08 -8.8970 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.43219E-11 -11.3643 0.37913E-11 -11.4212 0.87724E+00 -0.0569 34 CaCl+ 0.56370E-11 -11.2490 0.49450E-11 -11.3058 0.87724E+00 -0.0569 35 CaCl2,aq 0.14199E-15 -15.8478 0.14199E-15 -15.8478 0.10000E+01 0.0000 36 CaOH+ 0.16007E-07 -7.7957 0.14042E-07 -7.8526 0.87724E+00 -0.0569 37 CaSO4,aq 0.12838E-09 -9.8915 0.12838E-09 -9.8915 0.10000E+01 0.0000 38 HCl,aq 0.28420E-14 -14.5464 0.28420E-14 -14.5464 0.10000E+01 0.0000 43 FeCl+ 0.14195E-16 -16.8479 0.12453E-16 -16.9047 0.87724E+00 -0.0569 46 FeO,aq 0.15363E-09 -9.8135 0.15363E-09 -9.8135 0.10000E+01 0.0000 47 FeOH+ 0.18823E-10 -10.7253 0.16512E-10 -10.7822 0.87724E+00 -0.0569 48 HFeO2- 0.14293E-07 -7.8449 0.12526E-07 -7.9022 0.87638E+00 -0.0573 49 FeO+ 0.11166E-14 -14.9521 0.97952E-15 -15.0090 0.87724E+00 -0.0569 51 FeO2- 0.13887E-07 -7.8574 0.12171E-07 -7.9147 0.87638E+00 -0.0573 52 HFeO2,aq 0.19864E-09 -9.7019 0.19864E-09 -9.7019 0.10000E+01 0.0000 53 H2,aq 0.16191E-08 -8.7907 0.16167E-08 -8.7914 0.99847E+00 -0.0007 54 KCl,aq 0.13181E-09 -9.8800 0.13181E-09 -9.8800 0.10000E+01 0.0000 55 KHSO4,aq 0.34913E-18 -18.4570 0.34913E-18 -18.4570 0.10000E+01 0.0000 56 KOH,aq 0.20026E-06 -6.6984 0.20026E-06 -6.6984 0.10000E+01 0.0000 57 KSO4- 0.17038E-07 -7.7686 0.14932E-07 -7.8259 0.87638E+00 -0.0573 58 MgCO3,aq 0.13865E-12 -12.8581 0.13865E-12 -12.8581 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.19271E-14 -14.7151 0.16905E-14 -14.7720 0.87724E+00 -0.0569 60 MgCl+ 0.22295E-14 -14.6518 0.19558E-14 -14.7087 0.87724E+00 -0.0569 61 MgOH+ 0.38651E-10 -10.4128 0.33906E-10 -10.4697 0.87724E+00 -0.0569 63 MnO,aq 0.55009E-09 -9.2596 0.55009E-09 -9.2596 0.10000E+01 0.0000 64 MnOH+ 0.23497E-09 -9.6290 0.20612E-09 -9.6859 0.87724E+00 -0.0569 65 MnO2-2 0.17719E-11 -11.7516 0.11086E-11 -11.9552 0.62563E+00 -0.2037 66 HMnO2- 0.35563E-10 -10.4490 0.31167E-10 -10.5063 0.87638E+00 -0.0573 69 MnCl+ 0.74212E-14 -14.1295 0.65102E-14 -14.1864 0.87724E+00 -0.0569 70 MnSO4,aq 0.40381E-13 -13.3938 0.40381E-13 -13.3938 0.10000E+01 0.0000 71 NaCl,aq 0.30527E-06 -6.5153 0.30527E-06 -6.5153 0.10000E+01 0.0000 72 NaOH,aq 0.25518E-04 -4.5931 0.25518E-04 -4.5931 0.10000E+01 0.0000 74 OH- 0.51421E-02 -2.2889 0.45023E-02 -2.3466 0.87557E+00 -0.0577 79 HPO3-2 0.21273E-17 -17.6722 0.13309E-17 -17.8759 0.62563E+00 -0.2037 82 H3PO4,aq 0.30426E-16 -16.5168 0.30426E-16 -16.5168 0.10000E+01 0.0000 83 H2PO4- 0.71323E-09 -9.1468 0.62537E-09 -9.2039 0.87680E+00 -0.0571 84 PO4-3 0.46215E-08 -8.3352 0.16795E-08 -8.7748 0.36342E+00 -0.4396 87 H2P2O7-2 0.49014E-19 -19.3097 0.30665E-19 -19.5134 0.62563E+00 -0.2037 88 HP2O7-3 0.13456E-15 -15.8711 0.47714E-16 -16.3214 0.35459E+00 -0.4503 89 P2O7-4 0.54597E-15 -15.2628 0.88824E-16 -16.0515 0.16269E+00 -0.7886 90 H2S,aq 0.26409E-15 -15.5782 0.26369E-15 -15.5789 0.99847E+00 -0.0007 97 SO3-2 0.53302E-14 -14.2733 0.33593E-14 -14.4738 0.63024E+00 -0.2005 98 HSO3- 0.30799E-16 -16.5115 0.26992E-16 -16.5688 0.87638E+00 -0.0573 99 HSO4- 0.22532E-11 -11.6472 0.19775E-11 -11.7039 0.87766E+00 -0.0567 Charge balance for all species = 0.6858E-13 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.1459806E-09 -.9120329E-02 -.9186915E+01 0.0000 2 H2O 0.1000000E+01 0.5550981E+02 0.9993917E+06 0.0000 3 Cl- 0.1379041E-03 0.1382095E-03 0.4896836E+01 5.9739 4 SO4-- 0.2553081E-04 0.2554933E-04 0.2452753E+01 14.9872 5 HCO3- 0.6698252E-05 0.1309230E-04 0.7983486E+00 4.6607 6 HS- 0.7585828E-12 -.1355219E-08 -.4479139E-04 -2.2856 7 Al+++ 0.6264673E-27 0.5608489E-04 0.1512295E+01 2.0215 8 H4SiO4 0.4045468E-03 0.4126177E-02 0.3963377E+03 -3.3930 9 Ca++ 0.4051877E-07 0.5986330E-07 0.2397680E-02 12.1862 10 Mg++ 0.1772260E-10 0.5756526E-10 0.1398639E-05 8.8260 11 Fe++ 0.1045076E-12 0.2855159E-07 0.1593510E-02 6.5969 12 K+ 0.6860592E-04 0.6882335E-04 0.2689424E+01 5.6711 13 Na+ 0.8697642E-02 0.9086326E-02 0.2087603E+03 7.7737 14 Mn++ 0.1403777E-10 0.8364832E-09 0.4592557E-04 8.7252 15 HPO4-- 0.4217543E-06 0.4270890E-06 0.4096558E-01 13.2052 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.1788024E+00 -.9104798E-02 -.1696976E+00 0.0000000E+00 2 H2O 0.5537288E+02 0.5541528E+02 -.4239740E-01 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.3247816E-03 0.2550582E-04 0.2992757E-03 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.2992771E-03 -.1352911E-08 -.2992757E-03 0.0000000E+00 7 Al+++ 0.3521275E-01 0.5598938E-04 0.3515676E-01 0.0000000E+00 8 H4SiO4 0.1124476E+00 0.4119151E-02 0.1083285E+00 0.0000000E+00 9 Ca++ 0.1243486E-01 0.5976135E-07 0.1243480E-01 0.0000000E+00 10 Mg++ 0.8570635E-02 0.5746723E-10 0.8570635E-02 0.0000000E+00 11 Fe++ 0.7699780E-02 0.2850297E-07 0.7699751E-02 0.0000000E+00 12 K+ 0.2292781E-02 0.6870615E-04 0.2224075E-02 0.0000000E+00 13 Na+ 0.1371545E-01 0.9070852E-02 0.4644595E-02 0.0000000E+00 14 Mn++ 0.1872395E-03 0.8350587E-09 0.1872387E-03 0.0000000E+00 15 HPO4-- 0.6390391E-04 0.4263617E-06 0.6347755E-04 0.0000000E+00 Chg. balance for solid moles: 0.3198E-17 Mass of aqueous solution: 0.998931E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 10.7990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 0.4645E-02 -2.333 1.218 0.086 10.33 0.4675 apatite-OH 0.2116E-04 -4.675 0.1063E-01 -1.974 0.9014E-01 0.3377E-02 clinochlore 0.1714E-02 -2.766 0.9528 -0.021 8.080 0.3624 daphnite 0.1061E-02 -2.974 0.7571 -0.121 6.421 0.2294 chlorite-Mn 0.3745E-04 -4.427 0.2655E-01 -1.576 0.2252 0.8461E-02 hematite 0.8685E-03 -3.061 0.1387 -0.858 1.176 0.2629E-01 microcline 0.2224E-02 -2.653 0.6190 -0.208 5.250 0.2418 prehnite-Fe 0.4984E-03 -3.302 0.2199 -0.658 1.865 0.7378E-01 stilbite 0.1108E-01 -1.956 7.806 0.892 66.20 3.641 andradite 0.7935E-04 -4.100 0.4032E-01 -1.394 0.3420 0.1048E-01 grossular 0.5978E-05 -5.223 0.2693E-02 -2.570 0.2284E-01 0.7493E-03 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.6094E+00 0.6094E+00 1.0000 -0.215 daphnite 0.3773E+00 0.3773E+00 1.0000 -0.423 chlorite-Mn 0.1331E-01 0.1331E-01 1.0000 -1.876 hematite 0.1000E+01 0.1000E+01 1.0000 0.000 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 prehnite-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.9299E+00 0.9299E+00 1.0000 -0.032 grossular 0.7007E-01 0.7007E-01 1.0000 -1.154 Solid products produced: Mass = 11.791254 g Volume = 5.064975 cm3 Porosity: 4.7865% V(tot) - V(min): 0.25462E+00 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 10.7990000 g log = 1.0334 Original solution: 1000.0103000 g Original solution / Rock added: 92.60 (Water/Rock Ratio), log = 1.9666 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0203 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.1000E+01 0.9860 0.1006E+01 0.1020E+01 CO2,gas 0.1677E-06 1.0071 0.1723E-06 0.1711E-06 CH4,gas 0.3381E-15 1.0125 0.3492E-15 0.3449E-15 H2,gas 0.2079E-05 1.0005 0.2123E-05 0.2121E-05 H2S,gas 0.7133E-14 0.9960 0.7249E-14 0.7278E-14 S2,gas 0.4291E-36 1.0000 0.4378E-36 0.4378E-36 CO,gas 0.9555E-16 1.0000 0.9749E-16 0.9749E-16 SO3,gas 0.9758E-40 1.0000 0.9957E-40 0.9957E-40 SO2,gas 0.8058E-23 1.0000 0.8222E-23 0.8222E-23 HCl,gas 0.4915E-17 1.0000 0.5015E-17 0.5015E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 16 albite -0.38 -0.38 0.00 0.000 -0.94784E-12 22 andradite 39.01 39.01 0.00 0.000 0.00000E+00 23 grossular 32.73 32.73 0.00 0.000 -0.36397E-10 32 apatite-OH -18.15 -18.15 0.00 0.000 0.60662E-11 46 clinochlore 39.07 39.07 0.00 0.000 0.12132E-10 47 daphnite 28.97 28.97 0.00 0.000 0.18198E-10 48 chlorite-Mn 46.87 46.87 0.00 0.000 0.00000E+00 90 hematite 12.57 12.57 0.00 0.000 0.30331E-11 116 microcline -2.49 -2.49 0.00 0.000 0.15165E-11 137 prehnite-Fe 22.50 22.50 0.00 0.000 0.00000E+00 163 stilbite -7.52 -7.52 0.00 0.000 -0.90992E-11 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -15.12 -8.46 -2.821 0.14450E+05 -6.764 3 CH4,gas 4.54 -12.61 -17.16 -4.289 0.29293E+05 -15.457 4 H2,gas 8.00 0.63 -7.37 -4.213 0.12588E+05 -5.673 5 H2S,gas -6.23 -22.07 -15.84 -7.919 0.27044E+05 -14.140 6 S2,gas -7.34 -45.39 -38.06 -5.855 0.64982E+05 -36.359 7 CO,gas 3.21 -14.50 -17.71 -5.449 0.30239E+05 -16.011 8 SO3,gas 17.12 -24.58 -41.70 -10.425 0.71203E+05 -40.002 9 SO2,gas 0.83 -23.95 -24.78 -6.609 0.42318E+05 -23.085 10 HCl,gas 5.19 -13.81 -19.00 -9.499 0.32440E+05 -17.300 11 acmite 7.71 7.27 -0.44 -0.046 0.74949E+03 15 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 19 spessartine 24.46 20.04 -4.42 -0.221 0.75431E+04 20 analcite 3.32 3.01 -0.31 -0.035 0.53392E+03 21 andalusite 5.00 0.65 -4.35 -0.435 0.74302E+04 26 annite 20.12 17.30 -2.82 -0.157 0.48136E+04 27 phlogopite 27.06 23.99 -3.07 -0.171 0.52470E+04 29 anorthite 12.71 9.44 -3.27 -0.251 0.55787E+04 35 aragonite 0.97 -2.94 -3.90 -1.301 0.66643E+04 36 brucite 12.57 8.83 -3.74 -0.749 0.63902E+04 37 calcite 0.81 -2.94 -3.75 -1.249 0.64001E+04 38 carnegieite-low 9.02 6.40 -2.62 -0.374 0.44755E+04 39 carnegieite-high 10.09 6.40 -3.69 -0.527 0.63025E+04 40 carpholite-Mg 8.58 6.08 -2.50 -0.167 0.42672E+04 41 carpholite-Fe 6.71 3.85 -2.86 -0.191 0.48813E+04 42 celadonite 5.34 2.95 -2.40 -0.141 0.40895E+04 43 celadonite-Fe 3.88 0.72 -3.16 -0.186 0.53941E+04 44 chrysotile 23.89 19.69 -4.20 -0.350 0.71719E+04 50 chloritoid-Mg 13.20 9.48 -3.72 -0.248 0.63547E+04 51 chloritoid-Fe 9.17 7.25 -1.93 -0.128 0.32899E+04 52 chloritoid-Mn 11.40 9.38 -2.03 -0.135 0.34591E+04 54 coesite -2.38 -3.39 -1.02 -0.339 0.17364E+04 59 corundum 8.38 4.04 -4.34 -0.395 0.74107E+04 61 cristobalite -2.56 -3.39 -0.83 -0.278 0.14218E+04 63 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71234E+04 65 diaspore 2.87 2.02 -0.85 -0.142 0.14551E+04 67 diopside 16.18 14.23 -1.96 -0.196 0.33384E+04 68 hedenbergite 14.21 12.00 -2.21 -0.221 0.37756E+04 75 epidote 24.67 24.52 -0.15 -0.007 0.25708E+03 76 clinozoisite 22.81 20.26 -2.55 -0.116 0.43511E+04 77 epidote-Fe 29.84 28.78 -1.06 -0.055 0.18097E+04 78 fayalite 14.05 9.80 -4.24 -0.606 0.72481E+04 79 ferrosilite 11.15 6.41 -4.74 -0.474 0.80963E+04 83 gibbsite 4.08 2.02 -2.06 -0.294 0.35137E+04 84 glaucophane 22.97 18.92 -4.05 -0.109 0.69160E+04 87 greenalite 16.14 13.00 -3.13 -0.261 0.53527E+04 91 heulandite -5.83 -7.52 -1.69 -0.077 0.28938E+04 95 jadeite 4.22 3.01 -1.21 -0.121 0.20594E+04 96 julgoldite 70.43 66.71 -3.71 -0.096 0.63418E+04 97 kalsilite 7.58 4.30 -3.28 -0.469 0.56079E+04 98 kaolinite -1.33 -2.74 -1.41 -0.128 0.24081E+04 99 kyanite 4.88 0.65 -4.23 -0.423 0.72161E+04 101 laumontite 2.88 2.66 -0.23 -0.015 0.38652E+03 102 lawsonite 9.62 9.44 -0.17 -0.012 0.29534E+03 103 leucite 4.12 0.91 -3.21 -0.321 0.54850E+04 105 lizardite 23.24 19.69 -3.55 -0.296 0.60645E+04 107 magnetite 20.09 19.16 -0.92 -0.075 0.15782E+04 108 minnesotaite 10.39 6.22 -4.17 -0.245 0.71193E+04 110 magnesioferrite 26.21 21.39 -4.82 -0.393 0.82303E+04 113 margarite 17.32 13.49 -3.84 -0.154 0.65525E+04 120 muscovite 2.58 1.56 -1.03 -0.060 0.17518E+04 121 paragonite 4.24 3.66 -0.58 -0.034 0.99088E+03 122 nepheline 8.34 6.40 -1.94 -0.277 0.33078E+04 134 phlogopite-Na 29.65 26.09 -3.55 -0.197 0.60658E+04 136 prehnite 19.37 18.24 -1.14 -0.067 0.19390E+04 138 pumpellyite-Fe 46.27 45.09 -1.18 -0.026 0.20123E+04 139 pumpellyite-Mg 48.99 47.32 -1.67 -0.037 0.28597E+04 145 pyroxmangite 7.40 5.33 -2.07 -0.413 0.35284E+04 146 pyrophyllite -6.18 -9.53 -3.35 -0.210 0.57258E+04 147 quartz -2.99 -3.39 -0.40 -0.135 0.68913E+03 152 rhodonite 7.45 5.33 -2.11 -0.423 0.36087E+04 153 sanidine -1.28 -2.49 -1.21 -0.093 0.20677E+04 156 sillimanite 5.26 0.65 -4.61 -0.461 0.78741E+04 164 stilpnomelane-Fe 13.02 12.72 -0.30 -0.009 0.50906E+03 165 stilpnomelane-Mg 27.44 23.86 -3.58 -0.107 0.61074E+04 171 talc 16.49 12.91 -3.59 -0.211 0.61214E+04 174 tephroite 18.09 14.06 -4.03 -0.575 0.68783E+04 177 topaz-H 4.62 0.65 -3.97 -0.361 0.67762E+04 178 tridymite -2.63 -3.39 -0.77 -0.256 0.13091E+04 187 wairakite 3.95 2.66 -1.29 -0.076 0.22085E+04 188 walstromite 11.51 8.79 -2.72 -0.543 0.46376E+04 189 wollastonite 10.46 8.79 -1.67 -0.334 0.28480E+04 190 pseudo-wollastonite 11.00 8.79 -2.21 -0.441 0.37679E+04 191 zoisite 22.85 20.26 -2.59 -0.118 0.44252E+04 192 akaganeite 7.75 6.28 -1.47 -0.318 0.25125E+04 193 beidellite-Ca -1.65 -5.73 -4.09 -0.253 0.69768E+04 195 beidellite-K -1.52 -5.87 -4.35 -0.266 0.74286E+04 196 beidellite-Mg -1.79 -6.29 -4.50 -0.278 0.76773E+04 197 beidellite-Na -1.34 -5.18 -3.83 -0.235 0.65478E+04 199 chalcedony -2.80 -3.39 -0.59 -0.197 0.10084E+04 201 montmorillonite-Ca -2.29 -5.27 -2.98 -0.184 0.50920E+04 202 montmorillonite-K -2.24 -5.41 -3.18 -0.194 0.54220E+04 203 montmorillonite-Mg -2.48 -5.83 -3.35 -0.207 0.57157E+04 204 montmorillonite-Na -2.04 -4.72 -2.68 -0.164 0.45769E+04 205 nontronite-Ca 3.21 2.79 -0.42 -0.027 0.72221E+03 206 nontronite-H 2.53 0.78 -1.75 -0.117 0.29912E+04 207 nontronite-K 3.34 2.65 -0.69 -0.044 0.11754E+04 208 nontronite-Mg 3.07 2.24 -0.84 -0.054 0.14300E+04 209 nontronite-Na 3.52 3.35 -0.17 -0.011 0.29627E+03 224 tobermorite 9.82 6.76 -3.06 -0.836 0.52334E+04 233 boehmite 4.41 2.02 -2.38 -0.397 0.40720E+04 235 ferrous-oxide 9.81 6.60 -3.21 -0.804 0.54890E+04 240 silica-amorphous -2.09 -3.39 -1.30 -0.434 0.22226E+04 242 an20ab80 2.02 1.58 -0.44 -0.034 0.74489E+03 243 an25ab75 2.65 2.07 -0.57 -0.044 0.97808E+03 244 an30ab70 3.28 2.56 -0.72 -0.055 0.12209E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 0.4000000 g Current total amount of reactant added: 10.7990000 g New total amount of reactant added: 11.1990000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.6632E-13 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 7 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 11.1990000 Water: Moles liquid = 0.5541E+02 kg liquid = 0.9983E+00 Moles total = 0.5537E+02 kg total = 0.9975E+00 Activity = 1.0000 Stoichiometric ionic strength = .4957607E-02 Osmotic coef. = 0.9625 True ionic strength = .8798751E-02 Chg. balance for total moles = 0.6632E-13 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.14598E-09 -9.8357 0.12833E-09 -9.8917 0.87908E+00 -0.0560 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13791E-03 -3.8604 0.12086E-03 -3.9177 0.87638E+00 -0.0573 4 SO4-- 0.25532E-04 -4.5929 0.15991E-04 -4.7961 0.62631E+00 -0.2032 5 HCO3- 0.66985E-05 -5.1740 0.58748E-05 -5.2310 0.87703E+00 -0.0570 6 HS- 0.75862E-12 -12.1200 0.66489E-12 -12.1773 0.87645E+00 -0.0573 7 Al+++ 0.62647E-27 -27.2031 0.22205E-27 -27.6535 0.35445E+00 -0.4504 8 H4SiO4 0.40455E-03 -3.3930 0.40455E-03 -3.3930 0.10000E+01 0.0000 9 Ca++ 0.40519E-07 -7.3923 0.25283E-07 -7.5972 0.62399E+00 -0.2048 10 Mg++ 0.17723E-10 -10.7515 0.11033E-10 -10.9573 0.62254E+00 -0.2058 11 Fe++ 0.10451E-12 -12.9809 0.65096E-13 -13.1864 0.62288E+00 -0.2056 12 K+ 0.68606E-04 -4.1636 0.60177E-04 -4.2206 0.87714E+00 -0.0569 13 Na+ 0.86976E-02 -2.0606 0.76218E-02 -2.1179 0.87631E+00 -0.0573 14 Mn++ 0.14038E-10 -10.8527 0.87476E-11 -11.0581 0.62315E+00 -0.2054 15 HPO4-- 0.42175E-06 -6.3749 0.26417E-06 -6.5781 0.62635E+00 -0.2032 16 HSiO3- 0.33588E-02 -2.4738 0.29436E-02 -2.5311 0.87638E+00 -0.0573 17 Ca(HSiO3)+ 0.19321E-08 -8.7140 0.16949E-08 -8.7709 0.87724E+00 -0.0569 18 Mg(HSiO3)+ 0.10493E-11 -11.9791 0.92045E-12 -12.0360 0.87724E+00 -0.0569 19 NaHSiO3,aq 0.36286E-03 -3.4403 0.36286E-03 -3.4403 0.10000E+01 0.0000 20 AlO+ 0.20911E-14 -14.6796 0.18344E-14 -14.7365 0.87724E+00 -0.0569 22 HAlO2,aq 0.28467E-08 -8.5457 0.28467E-08 -8.5457 0.10000E+01 0.0000 23 AlO2- 0.56082E-04 -4.2512 0.49104E-04 -4.3089 0.87557E+00 -0.0577 24 CH4,aq 0.23764E-18 -18.6241 0.23728E-18 -18.6247 0.99847E+00 -0.0007 29 CO,aq 0.65423E-19 -19.1843 0.65423E-19 -19.1843 0.10000E+01 0.0000 30 CO2,aq 0.16134E-08 -8.7923 0.16109E-08 -8.7929 0.99847E+00 -0.0007 31 CO3-2 0.63914E-05 -5.1944 0.39987E-05 -5.3981 0.62563E+00 -0.2037 32 CaCO3,aq 0.12677E-08 -8.8970 0.12677E-08 -8.8970 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.43221E-11 -11.3643 0.37915E-11 -11.4212 0.87724E+00 -0.0569 34 CaCl+ 0.56372E-11 -11.2489 0.49452E-11 -11.3058 0.87724E+00 -0.0569 35 CaCl2,aq 0.14200E-15 -15.8477 0.14200E-15 -15.8477 0.10000E+01 0.0000 36 CaOH+ 0.16007E-07 -7.7957 0.14042E-07 -7.8526 0.87724E+00 -0.0569 37 CaSO4,aq 0.12838E-09 -9.8915 0.12838E-09 -9.8915 0.10000E+01 0.0000 38 HCl,aq 0.28421E-14 -14.5464 0.28421E-14 -14.5464 0.10000E+01 0.0000 43 FeCl+ 0.14196E-16 -16.8478 0.12453E-16 -16.9047 0.87724E+00 -0.0569 46 FeO,aq 0.15363E-09 -9.8135 0.15363E-09 -9.8135 0.10000E+01 0.0000 47 FeOH+ 0.18823E-10 -10.7253 0.16512E-10 -10.7822 0.87724E+00 -0.0569 48 HFeO2- 0.14293E-07 -7.8449 0.12526E-07 -7.9022 0.87638E+00 -0.0573 49 FeO+ 0.11166E-14 -14.9521 0.97952E-15 -15.0090 0.87724E+00 -0.0569 51 FeO2- 0.13887E-07 -7.8574 0.12171E-07 -7.9147 0.87638E+00 -0.0573 52 HFeO2,aq 0.19864E-09 -9.7019 0.19864E-09 -9.7019 0.10000E+01 0.0000 53 H2,aq 0.16191E-08 -8.7907 0.16167E-08 -8.7914 0.99847E+00 -0.0007 54 KCl,aq 0.13182E-09 -9.8800 0.13182E-09 -9.8800 0.10000E+01 0.0000 55 KHSO4,aq 0.34915E-18 -18.4570 0.34915E-18 -18.4570 0.10000E+01 0.0000 56 KOH,aq 0.20026E-06 -6.6984 0.20026E-06 -6.6984 0.10000E+01 0.0000 57 KSO4- 0.17039E-07 -7.7686 0.14932E-07 -7.8259 0.87638E+00 -0.0573 58 MgCO3,aq 0.13866E-12 -12.8581 0.13866E-12 -12.8581 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.19272E-14 -14.7151 0.16906E-14 -14.7720 0.87724E+00 -0.0569 60 MgCl+ 0.22296E-14 -14.6518 0.19559E-14 -14.7087 0.87724E+00 -0.0569 61 MgOH+ 0.38651E-10 -10.4128 0.33906E-10 -10.4697 0.87724E+00 -0.0569 63 MnO,aq 0.55009E-09 -9.2596 0.55009E-09 -9.2596 0.10000E+01 0.0000 64 MnOH+ 0.23497E-09 -9.6290 0.20612E-09 -9.6859 0.87724E+00 -0.0569 65 MnO2-2 0.17719E-11 -11.7516 0.11086E-11 -11.9552 0.62563E+00 -0.2037 66 HMnO2- 0.35563E-10 -10.4490 0.31167E-10 -10.5063 0.87638E+00 -0.0573 69 MnCl+ 0.74215E-14 -14.1295 0.65105E-14 -14.1864 0.87724E+00 -0.0569 70 MnSO4,aq 0.40383E-13 -13.3938 0.40383E-13 -13.3938 0.10000E+01 0.0000 71 NaCl,aq 0.30528E-06 -6.5153 0.30528E-06 -6.5153 0.10000E+01 0.0000 72 NaOH,aq 0.25518E-04 -4.5931 0.25518E-04 -4.5931 0.10000E+01 0.0000 74 OH- 0.51421E-02 -2.2889 0.45023E-02 -2.3466 0.87557E+00 -0.0577 79 HPO3-2 0.21273E-17 -17.6722 0.13309E-17 -17.8759 0.62563E+00 -0.2037 82 H3PO4,aq 0.30426E-16 -16.5168 0.30426E-16 -16.5168 0.10000E+01 0.0000 83 H2PO4- 0.71323E-09 -9.1468 0.62537E-09 -9.2039 0.87680E+00 -0.0571 84 PO4-3 0.46215E-08 -8.3352 0.16795E-08 -8.7748 0.36342E+00 -0.4396 87 H2P2O7-2 0.49014E-19 -19.3097 0.30665E-19 -19.5134 0.62563E+00 -0.2037 88 HP2O7-3 0.13456E-15 -15.8711 0.47714E-16 -16.3214 0.35459E+00 -0.4503 89 P2O7-4 0.54597E-15 -15.2628 0.88824E-16 -16.0515 0.16269E+00 -0.7886 90 H2S,aq 0.26411E-15 -15.5782 0.26370E-15 -15.5789 0.99847E+00 -0.0007 97 SO3-2 0.53304E-14 -14.2732 0.33594E-14 -14.4737 0.63024E+00 -0.2005 98 HSO3- 0.30800E-16 -16.5114 0.26993E-16 -16.5688 0.87638E+00 -0.0573 99 HSO4- 0.22533E-11 -11.6472 0.19776E-11 -11.7039 0.87766E+00 -0.0567 Charge balance for all species = 0.6517E-13 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.1459807E-09 -.9120325E-02 -.9186911E+01 0.0000 2 H2O 0.1000000E+01 0.5550981E+02 0.9993917E+06 0.0000 3 Cl- 0.1379100E-03 0.1382154E-03 0.4897042E+01 5.9740 4 SO4-- 0.2553188E-04 0.2555041E-04 0.2452857E+01 14.9872 5 HCO3- 0.6698536E-05 0.1309285E-04 0.7983823E+00 4.6607 6 HS- 0.7586155E-12 -.1355218E-08 -.4479136E-04 -2.2856 7 Al+++ 0.6264684E-27 0.5608487E-04 0.1512294E+01 2.0215 8 H4SiO4 0.4045468E-03 0.4126176E-02 0.3963375E+03 -3.3930 9 Ca++ 0.4051881E-07 0.5986341E-07 0.2397684E-02 12.1862 10 Mg++ 0.1772262E-10 0.5756531E-10 0.1398640E-05 8.8260 11 Fe++ 0.1045077E-12 0.2855158E-07 0.1593509E-02 6.5969 12 K+ 0.6860596E-04 0.6882339E-04 0.2689426E+01 5.6711 13 Na+ 0.8697646E-02 0.9086331E-02 0.2087605E+03 7.7737 14 Mn++ 0.1403779E-10 0.8364834E-09 0.4592558E-04 8.7252 15 HPO4-- 0.4217539E-06 0.4270886E-06 0.4096554E-01 13.2052 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.1854258E+00 -.9104410E-02 -.1763214E+00 0.0000000E+00 2 H2O 0.5536787E+02 0.5541294E+02 -.4507490E-01 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.3358669E-03 0.2550582E-04 0.3103611E-03 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.3103625E-03 -.1352853E-08 -.3103611E-03 0.0000000E+00 7 Al+++ 0.3651705E-01 0.5598699E-04 0.3646106E-01 0.0000000E+00 8 H4SiO4 0.1166128E+00 0.4118975E-02 0.1124938E+00 0.0000000E+00 9 Ca++ 0.1289492E-01 0.5975895E-07 0.1289486E-01 0.0000000E+00 10 Mg++ 0.8888095E-02 0.5746485E-10 0.8888095E-02 0.0000000E+00 11 Fe++ 0.7984983E-02 0.2850176E-07 0.7984955E-02 0.0000000E+00 12 K+ 0.2377707E-02 0.6870329E-04 0.2309004E-02 0.0000000E+00 13 Na+ 0.1421754E-01 0.9070475E-02 0.5147070E-02 0.0000000E+00 14 Mn++ 0.1941749E-03 0.8350237E-09 0.1941741E-03 0.0000000E+00 15 HPO4-- 0.6627094E-04 0.4263433E-06 0.6584460E-04 0.0000000E+00 Chg. balance for solid moles: 0.1686E-16 Mass of aqueous solution: 0.998888E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 11.1990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 0.5147E-02 -2.288 1.350 0.130 11.04 0.5181 andradite 0.1802E-03 -3.744 0.9156E-01 -1.038 0.7486 0.2379E-01 grossular 0.1357E-04 -4.867 0.6115E-02 -2.214 0.5000E-01 0.1701E-02 apatite-OH 0.2195E-04 -4.659 0.1103E-01 -1.958 0.9015E-01 0.3503E-02 clinochlore 0.1778E-02 -2.750 0.9881 -0.005 8.079 0.3758 daphnite 0.1100E-02 -2.958 0.7852 -0.105 6.420 0.2379 chlorite-Mn 0.3883E-04 -4.411 0.2753E-01 -1.560 0.2251 0.8774E-02 hematite 0.8507E-03 -3.070 0.1359 -0.867 1.111 0.2575E-01 microcline 0.2309E-02 -2.637 0.6427 -0.192 5.255 0.2511 prehnite-Fe 0.4212E-03 -3.375 0.1859 -0.731 1.520 0.6235E-01 stilbite 0.1136E-01 -1.945 8.007 0.903 65.47 3.734 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.9299E+00 0.9299E+00 1.0000 -0.032 grossular 0.7007E-01 0.7007E-01 1.0000 -1.154 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.6094E+00 0.6094E+00 1.0000 -0.215 daphnite 0.3773E+00 0.3773E+00 1.0000 -0.423 chlorite-Mn 0.1331E-01 0.1331E-01 1.0000 -1.876 hematite 0.1000E+01 0.1000E+01 1.0000 0.000 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 prehnite-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 12.230138 g Volume = 5.243211 cm3 Porosity: 4.3140% V(tot) - V(min): 0.23639E+00 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 11.1990000 g log = 1.0492 Original solution: 1000.0103000 g Original solution / Rock added: 89.29 (Water/Rock Ratio), log = 1.9508 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0203 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.1000E+01 0.9860 0.1006E+01 0.1020E+01 CO2,gas 0.1677E-06 1.0071 0.1724E-06 0.1711E-06 CH4,gas 0.3381E-15 1.0125 0.3493E-15 0.3449E-15 H2,gas 0.2079E-05 1.0005 0.2123E-05 0.2121E-05 H2S,gas 0.7133E-14 0.9960 0.7249E-14 0.7278E-14 S2,gas 0.4291E-36 1.0000 0.4378E-36 0.4378E-36 CO,gas 0.9555E-16 1.0000 0.9749E-16 0.9749E-16 SO3,gas 0.9759E-40 1.0000 0.9957E-40 0.9957E-40 SO2,gas 0.8058E-23 1.0000 0.8222E-23 0.8222E-23 HCl,gas 0.4915E-17 1.0000 0.5015E-17 0.5015E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 16 albite -0.38 -0.38 0.00 0.000 -0.94784E-12 22 andradite 39.01 39.01 0.00 0.000 0.00000E+00 23 grossular 32.73 32.73 0.00 0.000 0.12132E-10 32 apatite-OH -18.15 -18.15 0.00 0.000 0.60662E-11 46 clinochlore 39.07 39.07 0.00 0.000 0.36397E-10 47 daphnite 28.97 28.97 0.00 0.000 0.12132E-10 48 chlorite-Mn 46.87 46.87 0.00 0.000 0.24265E-10 90 hematite 12.57 12.57 0.00 0.000 0.90992E-11 116 microcline -2.49 -2.49 0.00 0.000 0.13649E-10 137 prehnite-Fe 22.50 22.50 0.00 0.000 0.00000E+00 163 stilbite -7.52 -7.52 0.00 0.000 0.15165E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -15.12 -8.46 -2.821 0.14450E+05 -6.764 3 CH4,gas 4.54 -12.61 -17.16 -4.289 0.29293E+05 -15.457 4 H2,gas 8.00 0.63 -7.37 -4.213 0.12588E+05 -5.673 5 H2S,gas -6.23 -22.07 -15.84 -7.919 0.27044E+05 -14.140 6 S2,gas -7.34 -45.39 -38.06 -5.855 0.64982E+05 -36.359 7 CO,gas 3.21 -14.50 -17.71 -5.449 0.30239E+05 -16.011 8 SO3,gas 17.12 -24.58 -41.70 -10.425 0.71203E+05 -40.002 9 SO2,gas 0.83 -23.95 -24.78 -6.609 0.42318E+05 -23.085 10 HCl,gas 5.19 -13.81 -19.00 -9.499 0.32440E+05 -17.300 11 acmite 7.71 7.27 -0.44 -0.046 0.74949E+03 15 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 19 spessartine 24.46 20.04 -4.42 -0.221 0.75431E+04 20 analcite 3.32 3.01 -0.31 -0.035 0.53392E+03 21 andalusite 5.00 0.65 -4.35 -0.435 0.74302E+04 26 annite 20.12 17.30 -2.82 -0.157 0.48136E+04 27 phlogopite 27.06 23.99 -3.07 -0.171 0.52470E+04 29 anorthite 12.71 9.44 -3.27 -0.251 0.55787E+04 35 aragonite 0.97 -2.94 -3.90 -1.301 0.66643E+04 36 brucite 12.57 8.83 -3.74 -0.749 0.63902E+04 37 calcite 0.81 -2.94 -3.75 -1.249 0.64001E+04 38 carnegieite-low 9.02 6.40 -2.62 -0.374 0.44755E+04 39 carnegieite-high 10.09 6.40 -3.69 -0.527 0.63025E+04 40 carpholite-Mg 8.58 6.08 -2.50 -0.167 0.42672E+04 41 carpholite-Fe 6.71 3.85 -2.86 -0.191 0.48813E+04 42 celadonite 5.34 2.95 -2.40 -0.141 0.40895E+04 43 celadonite-Fe 3.88 0.72 -3.16 -0.186 0.53941E+04 44 chrysotile 23.89 19.69 -4.20 -0.350 0.71719E+04 50 chloritoid-Mg 13.20 9.48 -3.72 -0.248 0.63547E+04 51 chloritoid-Fe 9.17 7.25 -1.93 -0.128 0.32899E+04 52 chloritoid-Mn 11.40 9.38 -2.03 -0.135 0.34591E+04 54 coesite -2.38 -3.39 -1.02 -0.339 0.17364E+04 59 corundum 8.38 4.04 -4.34 -0.395 0.74107E+04 61 cristobalite -2.56 -3.39 -0.83 -0.278 0.14218E+04 63 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71234E+04 65 diaspore 2.87 2.02 -0.85 -0.142 0.14551E+04 67 diopside 16.18 14.23 -1.96 -0.196 0.33384E+04 68 hedenbergite 14.21 12.00 -2.21 -0.221 0.37756E+04 75 epidote 24.67 24.52 -0.15 -0.007 0.25708E+03 76 clinozoisite 22.81 20.26 -2.55 -0.116 0.43511E+04 77 epidote-Fe 29.84 28.78 -1.06 -0.055 0.18097E+04 78 fayalite 14.05 9.80 -4.24 -0.606 0.72481E+04 79 ferrosilite 11.15 6.41 -4.74 -0.474 0.80963E+04 83 gibbsite 4.08 2.02 -2.06 -0.294 0.35137E+04 84 glaucophane 22.97 18.92 -4.05 -0.109 0.69160E+04 87 greenalite 16.14 13.00 -3.13 -0.261 0.53526E+04 91 heulandite -5.83 -7.52 -1.69 -0.077 0.28938E+04 95 jadeite 4.22 3.01 -1.21 -0.121 0.20594E+04 96 julgoldite 70.43 66.71 -3.71 -0.096 0.63418E+04 97 kalsilite 7.58 4.30 -3.28 -0.469 0.56079E+04 98 kaolinite -1.33 -2.74 -1.41 -0.128 0.24081E+04 99 kyanite 4.88 0.65 -4.23 -0.423 0.72161E+04 101 laumontite 2.88 2.66 -0.23 -0.015 0.38652E+03 102 lawsonite 9.62 9.44 -0.17 -0.012 0.29534E+03 103 leucite 4.12 0.91 -3.21 -0.321 0.54850E+04 105 lizardite 23.24 19.69 -3.55 -0.296 0.60645E+04 107 magnetite 20.09 19.16 -0.92 -0.075 0.15782E+04 108 minnesotaite 10.39 6.22 -4.17 -0.245 0.71193E+04 110 magnesioferrite 26.21 21.39 -4.82 -0.393 0.82303E+04 113 margarite 17.32 13.49 -3.84 -0.154 0.65525E+04 120 muscovite 2.58 1.56 -1.03 -0.060 0.17518E+04 121 paragonite 4.24 3.66 -0.58 -0.034 0.99088E+03 122 nepheline 8.34 6.40 -1.94 -0.277 0.33078E+04 134 phlogopite-Na 29.65 26.09 -3.55 -0.197 0.60658E+04 136 prehnite 19.37 18.24 -1.14 -0.067 0.19390E+04 138 pumpellyite-Fe 46.27 45.09 -1.18 -0.026 0.20123E+04 139 pumpellyite-Mg 48.99 47.32 -1.67 -0.037 0.28597E+04 145 pyroxmangite 7.40 5.33 -2.07 -0.413 0.35284E+04 146 pyrophyllite -6.18 -9.53 -3.35 -0.210 0.57258E+04 147 quartz -2.99 -3.39 -0.40 -0.135 0.68913E+03 152 rhodonite 7.45 5.33 -2.11 -0.423 0.36087E+04 153 sanidine -1.28 -2.49 -1.21 -0.093 0.20677E+04 156 sillimanite 5.26 0.65 -4.61 -0.461 0.78741E+04 164 stilpnomelane-Fe 13.02 12.72 -0.30 -0.009 0.50906E+03 165 stilpnomelane-Mg 27.44 23.86 -3.58 -0.107 0.61074E+04 171 talc 16.49 12.91 -3.59 -0.211 0.61214E+04 174 tephroite 18.09 14.06 -4.03 -0.575 0.68783E+04 177 topaz-H 4.62 0.65 -3.97 -0.361 0.67762E+04 178 tridymite -2.63 -3.39 -0.77 -0.256 0.13091E+04 187 wairakite 3.95 2.66 -1.29 -0.076 0.22085E+04 188 walstromite 11.51 8.79 -2.72 -0.543 0.46376E+04 189 wollastonite 10.46 8.79 -1.67 -0.334 0.28480E+04 190 pseudo-wollastonite 11.00 8.79 -2.21 -0.441 0.37679E+04 191 zoisite 22.85 20.26 -2.59 -0.118 0.44252E+04 192 akaganeite 7.75 6.28 -1.47 -0.318 0.25125E+04 193 beidellite-Ca -1.65 -5.73 -4.09 -0.253 0.69768E+04 195 beidellite-K -1.52 -5.87 -4.35 -0.266 0.74286E+04 196 beidellite-Mg -1.79 -6.29 -4.50 -0.278 0.76773E+04 197 beidellite-Na -1.34 -5.18 -3.83 -0.235 0.65478E+04 199 chalcedony -2.80 -3.39 -0.59 -0.197 0.10084E+04 201 montmorillonite-Ca -2.29 -5.27 -2.98 -0.184 0.50920E+04 202 montmorillonite-K -2.24 -5.41 -3.18 -0.194 0.54220E+04 203 montmorillonite-Mg -2.48 -5.83 -3.35 -0.207 0.57157E+04 204 montmorillonite-Na -2.04 -4.72 -2.68 -0.164 0.45769E+04 205 nontronite-Ca 3.21 2.79 -0.42 -0.027 0.72221E+03 206 nontronite-H 2.53 0.78 -1.75 -0.117 0.29912E+04 207 nontronite-K 3.34 2.65 -0.69 -0.044 0.11754E+04 208 nontronite-Mg 3.07 2.24 -0.84 -0.054 0.14300E+04 209 nontronite-Na 3.52 3.35 -0.17 -0.011 0.29627E+03 224 tobermorite 9.82 6.76 -3.06 -0.836 0.52334E+04 233 boehmite 4.41 2.02 -2.38 -0.397 0.40720E+04 235 ferrous-oxide 9.81 6.60 -3.21 -0.804 0.54890E+04 240 silica-amorphous -2.09 -3.39 -1.30 -0.434 0.22226E+04 242 an20ab80 2.02 1.58 -0.44 -0.034 0.74489E+03 243 an25ab75 2.65 2.07 -0.57 -0.044 0.97808E+03 244 an30ab70 3.28 2.56 -0.72 -0.055 0.12209E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 0.4000000 g Current total amount of reactant added: 11.1990000 g New total amount of reactant added: 11.5990000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.6630E-13 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 7 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 11.5990000 Water: Moles liquid = 0.5541E+02 kg liquid = 0.9982E+00 Moles total = 0.5536E+02 kg total = 0.9974E+00 Activity = 1.0000 Stoichiometric ionic strength = .4957614E-02 Osmotic coef. = 0.9625 True ionic strength = .8798757E-02 Chg. balance for total moles = 0.6630E-13 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.14598E-09 -9.8357 0.12833E-09 -9.8917 0.87908E+00 -0.0560 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13792E-03 -3.8604 0.12087E-03 -3.9177 0.87638E+00 -0.0573 4 SO4-- 0.25533E-04 -4.5929 0.15991E-04 -4.7961 0.62631E+00 -0.2032 5 HCO3- 0.66988E-05 -5.1740 0.58751E-05 -5.2310 0.87703E+00 -0.0570 6 HS- 0.75865E-12 -12.1200 0.66491E-12 -12.1772 0.87645E+00 -0.0573 7 Al+++ 0.62647E-27 -27.2031 0.22205E-27 -27.6535 0.35445E+00 -0.4504 8 H4SiO4 0.40455E-03 -3.3930 0.40455E-03 -3.3930 0.10000E+01 0.0000 9 Ca++ 0.40519E-07 -7.3923 0.25283E-07 -7.5972 0.62399E+00 -0.2048 10 Mg++ 0.17723E-10 -10.7515 0.11033E-10 -10.9573 0.62254E+00 -0.2058 11 Fe++ 0.10451E-12 -12.9809 0.65096E-13 -13.1864 0.62288E+00 -0.2056 12 K+ 0.68606E-04 -4.1636 0.60177E-04 -4.2206 0.87714E+00 -0.0569 13 Na+ 0.86977E-02 -2.0606 0.76218E-02 -2.1179 0.87631E+00 -0.0573 14 Mn++ 0.14038E-10 -10.8527 0.87476E-11 -11.0581 0.62315E+00 -0.2054 15 HPO4-- 0.42175E-06 -6.3749 0.26417E-06 -6.5781 0.62635E+00 -0.2032 16 HSiO3- 0.33588E-02 -2.4738 0.29436E-02 -2.5311 0.87638E+00 -0.0573 17 Ca(HSiO3)+ 0.19321E-08 -8.7140 0.16949E-08 -8.7709 0.87724E+00 -0.0569 18 Mg(HSiO3)+ 0.10493E-11 -11.9791 0.92045E-12 -12.0360 0.87724E+00 -0.0569 19 NaHSiO3,aq 0.36286E-03 -3.4403 0.36286E-03 -3.4403 0.10000E+01 0.0000 20 AlO+ 0.20911E-14 -14.6796 0.18344E-14 -14.7365 0.87724E+00 -0.0569 22 HAlO2,aq 0.28467E-08 -8.5457 0.28467E-08 -8.5457 0.10000E+01 0.0000 23 AlO2- 0.56082E-04 -4.2512 0.49104E-04 -4.3089 0.87557E+00 -0.0577 24 CH4,aq 0.23765E-18 -18.6241 0.23729E-18 -18.6247 0.99847E+00 -0.0007 29 CO,aq 0.65426E-19 -19.1843 0.65426E-19 -19.1843 0.10000E+01 0.0000 30 CO2,aq 0.16135E-08 -8.7922 0.16110E-08 -8.7929 0.99847E+00 -0.0007 31 CO3-2 0.63917E-05 -5.1944 0.39988E-05 -5.3981 0.62563E+00 -0.2037 32 CaCO3,aq 0.12677E-08 -8.8970 0.12677E-08 -8.8970 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.43223E-11 -11.3643 0.37917E-11 -11.4212 0.87724E+00 -0.0569 34 CaCl+ 0.56375E-11 -11.2489 0.49454E-11 -11.3058 0.87724E+00 -0.0569 35 CaCl2,aq 0.14201E-15 -15.8477 0.14201E-15 -15.8477 0.10000E+01 0.0000 36 CaOH+ 0.16007E-07 -7.7957 0.14042E-07 -7.8526 0.87724E+00 -0.0569 37 CaSO4,aq 0.12839E-09 -9.8915 0.12839E-09 -9.8915 0.10000E+01 0.0000 38 HCl,aq 0.28423E-14 -14.5463 0.28423E-14 -14.5463 0.10000E+01 0.0000 43 FeCl+ 0.14196E-16 -16.8478 0.12454E-16 -16.9047 0.87724E+00 -0.0569 46 FeO,aq 0.15363E-09 -9.8135 0.15363E-09 -9.8135 0.10000E+01 0.0000 47 FeOH+ 0.18823E-10 -10.7253 0.16512E-10 -10.7822 0.87724E+00 -0.0569 48 HFeO2- 0.14293E-07 -7.8449 0.12526E-07 -7.9022 0.87638E+00 -0.0573 49 FeO+ 0.11166E-14 -14.9521 0.97952E-15 -15.0090 0.87724E+00 -0.0569 51 FeO2- 0.13887E-07 -7.8574 0.12171E-07 -7.9147 0.87638E+00 -0.0573 52 HFeO2,aq 0.19864E-09 -9.7019 0.19864E-09 -9.7019 0.10000E+01 0.0000 53 H2,aq 0.16191E-08 -8.7907 0.16167E-08 -8.7914 0.99847E+00 -0.0007 54 KCl,aq 0.13183E-09 -9.8800 0.13183E-09 -9.8800 0.10000E+01 0.0000 55 KHSO4,aq 0.34916E-18 -18.4570 0.34916E-18 -18.4570 0.10000E+01 0.0000 56 KOH,aq 0.20026E-06 -6.6984 0.20026E-06 -6.6984 0.10000E+01 0.0000 57 KSO4- 0.17039E-07 -7.7685 0.14933E-07 -7.8259 0.87638E+00 -0.0573 58 MgCO3,aq 0.13866E-12 -12.8580 0.13866E-12 -12.8580 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.19273E-14 -14.7151 0.16907E-14 -14.7719 0.87724E+00 -0.0569 60 MgCl+ 0.22297E-14 -14.6518 0.19559E-14 -14.7086 0.87724E+00 -0.0569 61 MgOH+ 0.38651E-10 -10.4128 0.33906E-10 -10.4697 0.87724E+00 -0.0569 63 MnO,aq 0.55009E-09 -9.2596 0.55009E-09 -9.2596 0.10000E+01 0.0000 64 MnOH+ 0.23497E-09 -9.6290 0.20613E-09 -9.6859 0.87724E+00 -0.0569 65 MnO2-2 0.17719E-11 -11.7516 0.11086E-11 -11.9552 0.62563E+00 -0.2037 66 HMnO2- 0.35563E-10 -10.4490 0.31167E-10 -10.5063 0.87638E+00 -0.0573 69 MnCl+ 0.74219E-14 -14.1295 0.65107E-14 -14.1864 0.87724E+00 -0.0569 70 MnSO4,aq 0.40384E-13 -13.3938 0.40384E-13 -13.3938 0.10000E+01 0.0000 71 NaCl,aq 0.30530E-06 -6.5153 0.30530E-06 -6.5153 0.10000E+01 0.0000 72 NaOH,aq 0.25518E-04 -4.5931 0.25518E-04 -4.5931 0.10000E+01 0.0000 74 OH- 0.51421E-02 -2.2889 0.45023E-02 -2.3466 0.87557E+00 -0.0577 79 HPO3-2 0.21273E-17 -17.6722 0.13309E-17 -17.8759 0.62563E+00 -0.2037 82 H3PO4,aq 0.30426E-16 -16.5168 0.30426E-16 -16.5168 0.10000E+01 0.0000 83 H2PO4- 0.71323E-09 -9.1468 0.62536E-09 -9.2039 0.87680E+00 -0.0571 84 PO4-3 0.46215E-08 -8.3352 0.16795E-08 -8.7748 0.36342E+00 -0.4396 87 H2P2O7-2 0.49014E-19 -19.3097 0.30665E-19 -19.5134 0.62563E+00 -0.2037 88 HP2O7-3 0.13456E-15 -15.8711 0.47714E-16 -16.3214 0.35459E+00 -0.4503 89 P2O7-4 0.54597E-15 -15.2628 0.88824E-16 -16.0515 0.16269E+00 -0.7886 90 H2S,aq 0.26412E-15 -15.5782 0.26371E-15 -15.5789 0.99847E+00 -0.0007 97 SO3-2 0.53306E-14 -14.2732 0.33596E-14 -14.4737 0.63024E+00 -0.2005 98 HSO3- 0.30802E-16 -16.5114 0.26994E-16 -16.5687 0.87638E+00 -0.0573 99 HSO4- 0.22534E-11 -11.6472 0.19777E-11 -11.7038 0.87766E+00 -0.0567 Charge balance for all species = 0.6514E-13 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.1459808E-09 -.9120322E-02 -.9186907E+01 0.0000 2 H2O 0.1000000E+01 0.5550981E+02 0.9993917E+06 0.0000 3 Cl- 0.1379158E-03 0.1382212E-03 0.4897249E+01 5.9740 4 SO4-- 0.2553296E-04 0.2555149E-04 0.2452960E+01 14.9872 5 HCO3- 0.6698820E-05 0.1309340E-04 0.7984160E+00 4.6607 6 HS- 0.7586482E-12 -.1355217E-08 -.4479133E-04 -2.2856 7 Al+++ 0.6264696E-27 0.5608484E-04 0.1512293E+01 2.0215 8 H4SiO4 0.4045468E-03 0.4126174E-02 0.3963374E+03 -3.3930 9 Ca++ 0.4051886E-07 0.5986353E-07 0.2397689E-02 12.1862 10 Mg++ 0.1772264E-10 0.5756535E-10 0.1398641E-05 8.8260 11 Fe++ 0.1045078E-12 0.2855157E-07 0.1593508E-02 6.5969 12 K+ 0.6860600E-04 0.6882343E-04 0.2689427E+01 5.6711 13 Na+ 0.8697651E-02 0.9086335E-02 0.2087606E+03 7.7737 14 Mn++ 0.1403780E-10 0.8364836E-09 0.4592560E-04 8.7252 15 HPO4-- 0.4217535E-06 0.4270882E-06 0.4096551E-01 13.2052 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.1920492E+00 -.9104022E-02 -.1829452E+00 0.0000000E+00 2 H2O 0.5536285E+02 0.5541060E+02 -.4775241E-01 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.3469523E-03 0.2550582E-04 0.3214465E-03 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.3214478E-03 -.1352795E-08 -.3214465E-03 0.0000000E+00 7 Al+++ 0.3782134E-01 0.5598461E-04 0.3776536E-01 0.0000000E+00 8 H4SiO4 0.1207779E+00 0.4118800E-02 0.1166591E+00 0.0000000E+00 9 Ca++ 0.1335498E-01 0.5975655E-07 0.1335492E-01 0.0000000E+00 10 Mg++ 0.9205556E-02 0.5746247E-10 0.9205555E-02 0.0000000E+00 11 Fe++ 0.8270187E-02 0.2850054E-07 0.8270158E-02 0.0000000E+00 12 K+ 0.2462633E-02 0.6870043E-04 0.2393932E-02 0.0000000E+00 13 Na+ 0.1471964E-01 0.9070097E-02 0.5649545E-02 0.0000000E+00 14 Mn++ 0.2011104E-03 0.8349887E-09 0.2011095E-03 0.0000000E+00 15 HPO4-- 0.6863797E-04 0.4263250E-06 0.6821165E-04 0.0000000E+00 Chg. balance for solid moles: -.2968E-16 Mass of aqueous solution: 0.998846E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 11.5990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 0.5650E-02 -2.248 1.481 0.171 11.69 0.5687 andradite 0.2810E-03 -3.551 0.1428 -0.845 1.127 0.3710E-01 grossular 0.2117E-04 -4.674 0.9536E-02 -2.021 0.7527E-01 0.2653E-02 apatite-OH 0.2274E-04 -4.643 0.1142E-01 -1.942 0.9015E-01 0.3629E-02 clinochlore 0.1841E-02 -2.735 1.023 0.010 8.078 0.3893 daphnite 0.1140E-02 -2.943 0.8132 -0.090 6.419 0.2464 chlorite-Mn 0.4022E-04 -4.396 0.2852E-01 -1.545 0.2251 0.9087E-02 hematite 0.8328E-03 -3.079 0.1330 -0.876 1.050 0.2521E-01 microcline 0.2394E-02 -2.621 0.6663 -0.176 5.259 0.2603 prehnite-Fe 0.3440E-03 -3.463 0.1518 -0.819 1.198 0.5092E-01 stilbite 0.1165E-01 -1.934 8.208 0.914 64.79 3.828 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.9299E+00 0.9299E+00 1.0000 -0.032 grossular 0.7007E-01 0.7007E-01 1.0000 -1.154 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.6094E+00 0.6094E+00 1.0000 -0.215 daphnite 0.3773E+00 0.3773E+00 1.0000 -0.423 chlorite-Mn 0.1331E-01 0.1331E-01 1.0000 -1.876 hematite 0.1000E+01 0.1000E+01 1.0000 0.000 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 prehnite-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 12.669022 g Volume = 5.421446 cm3 Porosity: 3.8683% V(tot) - V(min): 0.21815E+00 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 11.5990000 g log = 1.0644 Original solution: 1000.0103000 g Original solution / Rock added: 86.22 (Water/Rock Ratio), log = 1.9356 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0203 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.1000E+01 0.9860 0.1006E+01 0.1020E+01 CO2,gas 0.1677E-06 1.0071 0.1724E-06 0.1711E-06 CH4,gas 0.3381E-15 1.0125 0.3493E-15 0.3450E-15 H2,gas 0.2079E-05 1.0005 0.2123E-05 0.2121E-05 H2S,gas 0.7133E-14 0.9960 0.7249E-14 0.7278E-14 S2,gas 0.4292E-36 1.0000 0.4379E-36 0.4379E-36 CO,gas 0.9556E-16 1.0000 0.9750E-16 0.9750E-16 SO3,gas 0.9759E-40 1.0000 0.9957E-40 0.9957E-40 SO2,gas 0.8059E-23 1.0000 0.8222E-23 0.8222E-23 HCl,gas 0.4915E-17 1.0000 0.5015E-17 0.5015E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 16 albite -0.38 -0.38 0.00 0.000 0.11184E-10 22 andradite 39.01 39.01 0.00 0.000 0.00000E+00 23 grossular 32.73 32.73 0.00 0.000 -0.12132E-10 32 apatite-OH -18.15 -18.15 0.00 0.000 0.12132E-10 46 clinochlore 39.07 39.07 0.00 0.000 0.48529E-10 47 daphnite 28.97 28.97 0.00 0.000 0.12132E-10 48 chlorite-Mn 46.87 46.87 0.00 0.000 0.48529E-10 90 hematite 12.57 12.57 0.00 0.000 -0.15165E-10 116 microcline -2.49 -2.49 0.00 0.000 0.13649E-10 137 prehnite-Fe 22.50 22.50 0.00 0.000 0.00000E+00 163 stilbite -7.52 -7.52 0.00 0.000 0.15165E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -15.12 -8.46 -2.821 0.14450E+05 -6.764 3 CH4,gas 4.54 -12.61 -17.16 -4.289 0.29293E+05 -15.457 4 H2,gas 8.00 0.63 -7.37 -4.213 0.12588E+05 -5.673 5 H2S,gas -6.23 -22.07 -15.84 -7.919 0.27044E+05 -14.140 6 S2,gas -7.34 -45.39 -38.06 -5.855 0.64982E+05 -36.359 7 CO,gas 3.21 -14.50 -17.71 -5.449 0.30239E+05 -16.011 8 SO3,gas 17.12 -24.58 -41.70 -10.425 0.71203E+05 -40.002 9 SO2,gas 0.83 -23.95 -24.78 -6.609 0.42318E+05 -23.085 10 HCl,gas 5.19 -13.81 -19.00 -9.499 0.32440E+05 -17.300 11 acmite 7.71 7.27 -0.44 -0.046 0.74949E+03 15 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 19 spessartine 24.46 20.04 -4.42 -0.221 0.75431E+04 20 analcite 3.32 3.01 -0.31 -0.035 0.53392E+03 21 andalusite 5.00 0.65 -4.35 -0.435 0.74302E+04 26 annite 20.12 17.30 -2.82 -0.157 0.48136E+04 27 phlogopite 27.06 23.99 -3.07 -0.171 0.52470E+04 29 anorthite 12.71 9.44 -3.27 -0.251 0.55787E+04 35 aragonite 0.97 -2.94 -3.90 -1.301 0.66643E+04 36 brucite 12.57 8.83 -3.74 -0.749 0.63902E+04 37 calcite 0.81 -2.94 -3.75 -1.249 0.64000E+04 38 carnegieite-low 9.02 6.40 -2.62 -0.374 0.44755E+04 39 carnegieite-high 10.09 6.40 -3.69 -0.527 0.63025E+04 40 carpholite-Mg 8.58 6.08 -2.50 -0.167 0.42672E+04 41 carpholite-Fe 6.71 3.85 -2.86 -0.191 0.48813E+04 42 celadonite 5.34 2.95 -2.40 -0.141 0.40895E+04 43 celadonite-Fe 3.88 0.72 -3.16 -0.186 0.53941E+04 44 chrysotile 23.89 19.69 -4.20 -0.350 0.71719E+04 50 chloritoid-Mg 13.20 9.48 -3.72 -0.248 0.63547E+04 51 chloritoid-Fe 9.17 7.25 -1.93 -0.128 0.32899E+04 52 chloritoid-Mn 11.40 9.38 -2.03 -0.135 0.34591E+04 54 coesite -2.38 -3.39 -1.02 -0.339 0.17364E+04 59 corundum 8.38 4.04 -4.34 -0.395 0.74107E+04 61 cristobalite -2.56 -3.39 -0.83 -0.278 0.14218E+04 63 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71234E+04 65 diaspore 2.87 2.02 -0.85 -0.142 0.14551E+04 67 diopside 16.18 14.23 -1.96 -0.196 0.33384E+04 68 hedenbergite 14.21 12.00 -2.21 -0.221 0.37756E+04 75 epidote 24.67 24.52 -0.15 -0.007 0.25708E+03 76 clinozoisite 22.81 20.26 -2.55 -0.116 0.43511E+04 77 epidote-Fe 29.84 28.78 -1.06 -0.055 0.18097E+04 78 fayalite 14.05 9.80 -4.24 -0.606 0.72481E+04 79 ferrosilite 11.15 6.41 -4.74 -0.474 0.80963E+04 83 gibbsite 4.08 2.02 -2.06 -0.294 0.35137E+04 84 glaucophane 22.97 18.92 -4.05 -0.109 0.69160E+04 87 greenalite 16.14 13.00 -3.13 -0.261 0.53526E+04 91 heulandite -5.83 -7.52 -1.69 -0.077 0.28938E+04 95 jadeite 4.22 3.01 -1.21 -0.121 0.20594E+04 96 julgoldite 70.43 66.71 -3.71 -0.096 0.63418E+04 97 kalsilite 7.58 4.30 -3.28 -0.469 0.56079E+04 98 kaolinite -1.33 -2.74 -1.41 -0.128 0.24081E+04 99 kyanite 4.88 0.65 -4.23 -0.423 0.72161E+04 101 laumontite 2.88 2.66 -0.23 -0.015 0.38652E+03 102 lawsonite 9.62 9.44 -0.17 -0.012 0.29534E+03 103 leucite 4.12 0.91 -3.21 -0.321 0.54850E+04 105 lizardite 23.24 19.69 -3.55 -0.296 0.60645E+04 107 magnetite 20.09 19.16 -0.92 -0.075 0.15782E+04 108 minnesotaite 10.39 6.22 -4.17 -0.245 0.71193E+04 110 magnesioferrite 26.21 21.39 -4.82 -0.393 0.82303E+04 113 margarite 17.32 13.49 -3.84 -0.154 0.65525E+04 120 muscovite 2.58 1.56 -1.03 -0.060 0.17518E+04 121 paragonite 4.24 3.66 -0.58 -0.034 0.99088E+03 122 nepheline 8.34 6.40 -1.94 -0.277 0.33078E+04 134 phlogopite-Na 29.65 26.09 -3.55 -0.197 0.60658E+04 136 prehnite 19.37 18.24 -1.14 -0.067 0.19390E+04 138 pumpellyite-Fe 46.27 45.09 -1.18 -0.026 0.20123E+04 139 pumpellyite-Mg 48.99 47.32 -1.67 -0.037 0.28597E+04 145 pyroxmangite 7.40 5.33 -2.07 -0.413 0.35284E+04 146 pyrophyllite -6.18 -9.53 -3.35 -0.210 0.57258E+04 147 quartz -2.99 -3.39 -0.40 -0.135 0.68913E+03 152 rhodonite 7.45 5.33 -2.11 -0.423 0.36087E+04 153 sanidine -1.28 -2.49 -1.21 -0.093 0.20677E+04 156 sillimanite 5.26 0.65 -4.61 -0.461 0.78741E+04 164 stilpnomelane-Fe 13.02 12.72 -0.30 -0.009 0.50906E+03 165 stilpnomelane-Mg 27.44 23.86 -3.58 -0.107 0.61074E+04 171 talc 16.49 12.91 -3.59 -0.211 0.61214E+04 174 tephroite 18.09 14.06 -4.03 -0.575 0.68783E+04 177 topaz-H 4.62 0.65 -3.97 -0.361 0.67762E+04 178 tridymite -2.63 -3.39 -0.77 -0.256 0.13091E+04 187 wairakite 3.95 2.66 -1.29 -0.076 0.22085E+04 188 walstromite 11.51 8.79 -2.72 -0.543 0.46376E+04 189 wollastonite 10.46 8.79 -1.67 -0.334 0.28480E+04 190 pseudo-wollastonite 11.00 8.79 -2.21 -0.441 0.37679E+04 191 zoisite 22.85 20.26 -2.59 -0.118 0.44252E+04 192 akaganeite 7.75 6.28 -1.47 -0.318 0.25125E+04 193 beidellite-Ca -1.65 -5.73 -4.09 -0.253 0.69768E+04 195 beidellite-K -1.52 -5.87 -4.35 -0.266 0.74286E+04 196 beidellite-Mg -1.79 -6.29 -4.50 -0.278 0.76773E+04 197 beidellite-Na -1.34 -5.18 -3.83 -0.235 0.65478E+04 199 chalcedony -2.80 -3.39 -0.59 -0.197 0.10084E+04 201 montmorillonite-Ca -2.29 -5.27 -2.98 -0.184 0.50920E+04 202 montmorillonite-K -2.24 -5.41 -3.18 -0.194 0.54220E+04 203 montmorillonite-Mg -2.48 -5.83 -3.35 -0.207 0.57157E+04 204 montmorillonite-Na -2.04 -4.72 -2.68 -0.164 0.45769E+04 205 nontronite-Ca 3.21 2.79 -0.42 -0.027 0.72221E+03 206 nontronite-H 2.53 0.78 -1.75 -0.117 0.29912E+04 207 nontronite-K 3.34 2.65 -0.69 -0.044 0.11754E+04 208 nontronite-Mg 3.07 2.24 -0.84 -0.054 0.14300E+04 209 nontronite-Na 3.52 3.35 -0.17 -0.011 0.29627E+03 224 tobermorite 9.82 6.76 -3.06 -0.836 0.52334E+04 233 boehmite 4.41 2.02 -2.38 -0.397 0.40720E+04 235 ferrous-oxide 9.81 6.60 -3.21 -0.804 0.54890E+04 240 silica-amorphous -2.09 -3.39 -1.30 -0.434 0.22226E+04 242 an20ab80 2.02 1.58 -0.44 -0.034 0.74489E+03 243 an25ab75 2.65 2.07 -0.57 -0.044 0.97808E+03 244 an30ab70 3.28 2.56 -0.72 -0.055 0.12209E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 0.4000000 g Current total amount of reactant added: 11.5990000 g New total amount of reactant added: 11.9990000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.6627E-13 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 7 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 11.9990000 Water: Moles liquid = 0.5541E+02 kg liquid = 0.9982E+00 Moles total = 0.5536E+02 kg total = 0.9973E+00 Activity = 1.0000 Stoichiometric ionic strength = .4957622E-02 Osmotic coef. = 0.9625 True ionic strength = .8798764E-02 Chg. balance for total moles = 0.6627E-13 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.14598E-09 -9.8357 0.12833E-09 -9.8917 0.87908E+00 -0.0560 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13792E-03 -3.8604 0.12087E-03 -3.9177 0.87638E+00 -0.0573 4 SO4-- 0.25534E-04 -4.5929 0.15992E-04 -4.7961 0.62631E+00 -0.2032 5 HCO3- 0.66991E-05 -5.1740 0.58753E-05 -5.2310 0.87703E+00 -0.0570 6 HS- 0.75868E-12 -12.1199 0.66494E-12 -12.1772 0.87645E+00 -0.0573 7 Al+++ 0.62647E-27 -27.2031 0.22205E-27 -27.6535 0.35445E+00 -0.4504 8 H4SiO4 0.40455E-03 -3.3930 0.40455E-03 -3.3930 0.10000E+01 0.0000 9 Ca++ 0.40519E-07 -7.3923 0.25283E-07 -7.5972 0.62399E+00 -0.2048 10 Mg++ 0.17723E-10 -10.7515 0.11033E-10 -10.9573 0.62254E+00 -0.2058 11 Fe++ 0.10451E-12 -12.9809 0.65096E-13 -13.1864 0.62288E+00 -0.2056 12 K+ 0.68606E-04 -4.1636 0.60177E-04 -4.2206 0.87714E+00 -0.0569 13 Na+ 0.86977E-02 -2.0606 0.76219E-02 -2.1179 0.87631E+00 -0.0573 14 Mn++ 0.14038E-10 -10.8527 0.87476E-11 -11.0581 0.62315E+00 -0.2054 15 HPO4-- 0.42175E-06 -6.3749 0.26417E-06 -6.5781 0.62635E+00 -0.2032 16 HSiO3- 0.33588E-02 -2.4738 0.29436E-02 -2.5311 0.87638E+00 -0.0573 17 Ca(HSiO3)+ 0.19321E-08 -8.7140 0.16949E-08 -8.7709 0.87724E+00 -0.0569 18 Mg(HSiO3)+ 0.10493E-11 -11.9791 0.92045E-12 -12.0360 0.87724E+00 -0.0569 19 NaHSiO3,aq 0.36286E-03 -3.4403 0.36286E-03 -3.4403 0.10000E+01 0.0000 20 AlO+ 0.20911E-14 -14.6796 0.18344E-14 -14.7365 0.87724E+00 -0.0569 22 HAlO2,aq 0.28467E-08 -8.5457 0.28467E-08 -8.5457 0.10000E+01 0.0000 23 AlO2- 0.56082E-04 -4.2512 0.49104E-04 -4.3089 0.87557E+00 -0.0577 24 CH4,aq 0.23766E-18 -18.6240 0.23730E-18 -18.6247 0.99847E+00 -0.0007 29 CO,aq 0.65428E-19 -19.1842 0.65428E-19 -19.1842 0.10000E+01 0.0000 30 CO2,aq 0.16135E-08 -8.7922 0.16111E-08 -8.7929 0.99847E+00 -0.0007 31 CO3-2 0.63920E-05 -5.1944 0.39990E-05 -5.3980 0.62563E+00 -0.2037 32 CaCO3,aq 0.12678E-08 -8.8970 0.12678E-08 -8.8970 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.43225E-11 -11.3643 0.37918E-11 -11.4212 0.87724E+00 -0.0569 34 CaCl+ 0.56377E-11 -11.2489 0.49456E-11 -11.3058 0.87724E+00 -0.0569 35 CaCl2,aq 0.14202E-15 -15.8476 0.14202E-15 -15.8476 0.10000E+01 0.0000 36 CaOH+ 0.16007E-07 -7.7957 0.14042E-07 -7.8526 0.87724E+00 -0.0569 37 CaSO4,aq 0.12840E-09 -9.8915 0.12840E-09 -9.8915 0.10000E+01 0.0000 38 HCl,aq 0.28424E-14 -14.5463 0.28424E-14 -14.5463 0.10000E+01 0.0000 43 FeCl+ 0.14197E-16 -16.8478 0.12454E-16 -16.9047 0.87724E+00 -0.0569 46 FeO,aq 0.15363E-09 -9.8135 0.15363E-09 -9.8135 0.10000E+01 0.0000 47 FeOH+ 0.18823E-10 -10.7253 0.16512E-10 -10.7822 0.87724E+00 -0.0569 48 HFeO2- 0.14293E-07 -7.8449 0.12526E-07 -7.9022 0.87638E+00 -0.0573 49 FeO+ 0.11166E-14 -14.9521 0.97952E-15 -15.0090 0.87724E+00 -0.0569 51 FeO2- 0.13887E-07 -7.8574 0.12171E-07 -7.9147 0.87638E+00 -0.0573 52 HFeO2,aq 0.19864E-09 -9.7019 0.19864E-09 -9.7019 0.10000E+01 0.0000 53 H2,aq 0.16191E-08 -8.7907 0.16167E-08 -8.7914 0.99847E+00 -0.0007 54 KCl,aq 0.13183E-09 -9.8800 0.13183E-09 -9.8800 0.10000E+01 0.0000 55 KHSO4,aq 0.34918E-18 -18.4570 0.34918E-18 -18.4570 0.10000E+01 0.0000 56 KOH,aq 0.20026E-06 -6.6984 0.20026E-06 -6.6984 0.10000E+01 0.0000 57 KSO4- 0.17040E-07 -7.7685 0.14934E-07 -7.8258 0.87638E+00 -0.0573 58 MgCO3,aq 0.13867E-12 -12.8580 0.13867E-12 -12.8580 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.19274E-14 -14.7150 0.16908E-14 -14.7719 0.87724E+00 -0.0569 60 MgCl+ 0.22298E-14 -14.6517 0.19560E-14 -14.7086 0.87724E+00 -0.0569 61 MgOH+ 0.38651E-10 -10.4128 0.33906E-10 -10.4697 0.87724E+00 -0.0569 63 MnO,aq 0.55009E-09 -9.2596 0.55009E-09 -9.2596 0.10000E+01 0.0000 64 MnOH+ 0.23497E-09 -9.6290 0.20613E-09 -9.6859 0.87724E+00 -0.0569 65 MnO2-2 0.17719E-11 -11.7516 0.11086E-11 -11.9552 0.62563E+00 -0.2037 66 HMnO2- 0.35563E-10 -10.4490 0.31167E-10 -10.5063 0.87638E+00 -0.0573 69 MnCl+ 0.74222E-14 -14.1295 0.65110E-14 -14.1864 0.87724E+00 -0.0569 70 MnSO4,aq 0.40386E-13 -13.3938 0.40386E-13 -13.3938 0.10000E+01 0.0000 71 NaCl,aq 0.30531E-06 -6.5153 0.30531E-06 -6.5153 0.10000E+01 0.0000 72 NaOH,aq 0.25518E-04 -4.5931 0.25518E-04 -4.5931 0.10000E+01 0.0000 74 OH- 0.51421E-02 -2.2889 0.45023E-02 -2.3466 0.87557E+00 -0.0577 79 HPO3-2 0.21273E-17 -17.6722 0.13309E-17 -17.8759 0.62563E+00 -0.2037 82 H3PO4,aq 0.30426E-16 -16.5168 0.30426E-16 -16.5168 0.10000E+01 0.0000 83 H2PO4- 0.71323E-09 -9.1468 0.62536E-09 -9.2039 0.87680E+00 -0.0571 84 PO4-3 0.46215E-08 -8.3352 0.16795E-08 -8.7748 0.36342E+00 -0.4396 87 H2P2O7-2 0.49014E-19 -19.3097 0.30665E-19 -19.5134 0.62563E+00 -0.2037 88 HP2O7-3 0.13456E-15 -15.8711 0.47714E-16 -16.3214 0.35459E+00 -0.4503 89 P2O7-4 0.54597E-15 -15.2628 0.88824E-16 -16.0515 0.16269E+00 -0.7886 90 H2S,aq 0.26413E-15 -15.5782 0.26373E-15 -15.5788 0.99847E+00 -0.0007 97 SO3-2 0.53309E-14 -14.2732 0.33597E-14 -14.4737 0.63024E+00 -0.2005 98 HSO3- 0.30803E-16 -16.5114 0.26995E-16 -16.5687 0.87638E+00 -0.0573 99 HSO4- 0.22535E-11 -11.6471 0.19778E-11 -11.7038 0.87766E+00 -0.0567 Charge balance for all species = 0.6510E-13 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.1459808E-09 -.9120318E-02 -.9186903E+01 0.0000 2 H2O 0.1000000E+01 0.5550981E+02 0.9993917E+06 0.0000 3 Cl- 0.1379216E-03 0.1382270E-03 0.4897455E+01 5.9740 4 SO4-- 0.2553404E-04 0.2555256E-04 0.2453064E+01 14.9873 5 HCO3- 0.6699104E-05 0.1309395E-04 0.7984496E+00 4.6607 6 HS- 0.7586809E-12 -.1355216E-08 -.4479130E-04 -2.2855 7 Al+++ 0.6264707E-27 0.5608481E-04 0.1512293E+01 2.0215 8 H4SiO4 0.4045468E-03 0.4126173E-02 0.3963372E+03 -3.3930 9 Ca++ 0.4051891E-07 0.5986365E-07 0.2397694E-02 12.1862 10 Mg++ 0.1772266E-10 0.5756540E-10 0.1398642E-05 8.8260 11 Fe++ 0.1045079E-12 0.2855156E-07 0.1593508E-02 6.5969 12 K+ 0.6860603E-04 0.6882346E-04 0.2689429E+01 5.6711 13 Na+ 0.8697656E-02 0.9086340E-02 0.2087607E+03 7.7737 14 Mn++ 0.1403782E-10 0.8364838E-09 0.4592561E-04 8.7252 15 HPO4-- 0.4217532E-06 0.4270879E-06 0.4096547E-01 13.2052 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.1986726E+00 -.9103634E-02 -.1895690E+00 0.0000000E+00 2 H2O 0.5535784E+02 0.5540827E+02 -.5042992E-01 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.3580377E-03 0.2550582E-04 0.3325318E-03 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.3325332E-03 -.1352737E-08 -.3325318E-03 0.0000000E+00 7 Al+++ 0.3912564E-01 0.5598222E-04 0.3906966E-01 0.0000000E+00 8 H4SiO4 0.1249430E+00 0.4118625E-02 0.1208244E+00 0.0000000E+00 9 Ca++ 0.1381503E-01 0.5975414E-07 0.1381497E-01 0.0000000E+00 10 Mg++ 0.9523016E-02 0.5746010E-10 0.9523016E-02 0.0000000E+00 11 Fe++ 0.8555390E-02 0.2849933E-07 0.8555362E-02 0.0000000E+00 12 K+ 0.2547558E-02 0.6869757E-04 0.2478861E-02 0.0000000E+00 13 Na+ 0.1522174E-01 0.9069719E-02 0.6152020E-02 0.0000000E+00 14 Mn++ 0.2080458E-03 0.8349537E-09 0.2080450E-03 0.0000000E+00 15 HPO4-- 0.7100500E-04 0.4263066E-06 0.7057870E-04 0.0000000E+00 Chg. balance for solid moles: 0.9162E-17 Mass of aqueous solution: 0.998804E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 11.9990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 0.6152E-02 -2.211 1.613 0.208 12.31 0.6193 andradite 0.3818E-03 -3.418 0.1940 -0.712 1.480 0.5041E-01 grossular 0.2877E-04 -4.541 0.1296E-01 -1.887 0.9886E-01 0.3606E-02 apatite-OH 0.2353E-04 -4.628 0.1182E-01 -1.927 0.9016E-01 0.3755E-02 clinochlore 0.1905E-02 -2.720 1.059 0.025 8.076 0.4027 daphnite 0.1179E-02 -2.928 0.8412 -0.075 6.418 0.2549 chlorite-Mn 0.4161E-04 -4.381 0.2950E-01 -1.530 0.2251 0.9401E-02 hematite 0.8149E-03 -3.089 0.1301 -0.886 0.9928 0.2467E-01 microcline 0.2479E-02 -2.606 0.6900 -0.161 5.264 0.2695 prehnite-Fe 0.2668E-03 -3.574 0.1177 -0.929 0.8982 0.3949E-01 stilbite 0.1193E-01 -1.923 8.409 0.925 64.15 3.922 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.9299E+00 0.9299E+00 1.0000 -0.032 grossular 0.7007E-01 0.7007E-01 1.0000 -1.154 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.6094E+00 0.6094E+00 1.0000 -0.215 daphnite 0.3773E+00 0.3773E+00 1.0000 -0.423 chlorite-Mn 0.1331E-01 0.1331E-01 1.0000 -1.876 hematite 0.1000E+01 0.1000E+01 1.0000 0.000 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 prehnite-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 13.107906 g Volume = 5.599682 cm3 Porosity: 3.4471% V(tot) - V(min): 0.19992E+00 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 11.9990000 g log = 1.0791 Original solution: 1000.0103000 g Original solution / Rock added: 83.34 (Water/Rock Ratio), log = 1.9209 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0203 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.1000E+01 0.9860 0.1006E+01 0.1020E+01 CO2,gas 0.1677E-06 1.0071 0.1724E-06 0.1712E-06 CH4,gas 0.3381E-15 1.0125 0.3493E-15 0.3450E-15 H2,gas 0.2079E-05 1.0005 0.2123E-05 0.2121E-05 H2S,gas 0.7134E-14 0.9960 0.7250E-14 0.7278E-14 S2,gas 0.4292E-36 1.0000 0.4379E-36 0.4379E-36 CO,gas 0.9556E-16 1.0000 0.9750E-16 0.9750E-16 SO3,gas 0.9760E-40 1.0000 0.9958E-40 0.9958E-40 SO2,gas 0.8059E-23 1.0000 0.8223E-23 0.8223E-23 HCl,gas 0.4916E-17 1.0000 0.5015E-17 0.5015E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 16 albite -0.38 -0.38 0.00 0.000 -0.94784E-12 22 andradite 39.01 39.01 0.00 0.000 0.00000E+00 23 grossular 32.73 32.73 0.00 0.000 0.12132E-10 32 apatite-OH -18.15 -18.15 0.00 0.000 -0.60662E-11 46 clinochlore 39.07 39.07 0.00 0.000 -0.12132E-10 47 daphnite 28.97 28.97 0.00 0.000 -0.36397E-10 48 chlorite-Mn 46.87 46.87 0.00 0.000 -0.12132E-10 90 hematite 12.57 12.57 0.00 0.000 0.30331E-11 116 microcline -2.49 -2.49 0.00 0.000 -0.22748E-10 137 prehnite-Fe 22.50 22.50 0.00 0.000 0.00000E+00 163 stilbite -7.52 -7.52 0.00 0.000 -0.90992E-11 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -15.12 -8.46 -2.821 0.14450E+05 -6.764 3 CH4,gas 4.54 -12.61 -17.16 -4.289 0.29293E+05 -15.457 4 H2,gas 8.00 0.63 -7.37 -4.213 0.12588E+05 -5.673 5 H2S,gas -6.23 -22.07 -15.84 -7.919 0.27044E+05 -14.140 6 S2,gas -7.34 -45.39 -38.06 -5.855 0.64982E+05 -36.359 7 CO,gas 3.21 -14.50 -17.71 -5.449 0.30239E+05 -16.011 8 SO3,gas 17.12 -24.58 -41.70 -10.425 0.71203E+05 -40.002 9 SO2,gas 0.83 -23.95 -24.78 -6.609 0.42318E+05 -23.085 10 HCl,gas 5.19 -13.81 -19.00 -9.499 0.32440E+05 -17.300 11 acmite 7.71 7.27 -0.44 -0.046 0.74949E+03 15 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 19 spessartine 24.46 20.04 -4.42 -0.221 0.75431E+04 20 analcite 3.32 3.01 -0.31 -0.035 0.53392E+03 21 andalusite 5.00 0.65 -4.35 -0.435 0.74302E+04 26 annite 20.12 17.30 -2.82 -0.157 0.48136E+04 27 phlogopite 27.06 23.99 -3.07 -0.171 0.52470E+04 29 anorthite 12.71 9.44 -3.27 -0.251 0.55787E+04 35 aragonite 0.97 -2.94 -3.90 -1.301 0.66642E+04 36 brucite 12.57 8.83 -3.74 -0.749 0.63902E+04 37 calcite 0.81 -2.94 -3.75 -1.249 0.64000E+04 38 carnegieite-low 9.02 6.40 -2.62 -0.374 0.44755E+04 39 carnegieite-high 10.09 6.40 -3.69 -0.527 0.63025E+04 40 carpholite-Mg 8.58 6.08 -2.50 -0.167 0.42672E+04 41 carpholite-Fe 6.71 3.85 -2.86 -0.191 0.48813E+04 42 celadonite 5.34 2.95 -2.40 -0.141 0.40895E+04 43 celadonite-Fe 3.88 0.72 -3.16 -0.186 0.53941E+04 44 chrysotile 23.89 19.69 -4.20 -0.350 0.71719E+04 50 chloritoid-Mg 13.20 9.48 -3.72 -0.248 0.63547E+04 51 chloritoid-Fe 9.17 7.25 -1.93 -0.128 0.32899E+04 52 chloritoid-Mn 11.40 9.38 -2.03 -0.135 0.34591E+04 54 coesite -2.38 -3.39 -1.02 -0.339 0.17364E+04 59 corundum 8.38 4.04 -4.34 -0.395 0.74107E+04 61 cristobalite -2.56 -3.39 -0.83 -0.278 0.14218E+04 63 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71234E+04 65 diaspore 2.87 2.02 -0.85 -0.142 0.14551E+04 67 diopside 16.18 14.23 -1.96 -0.196 0.33384E+04 68 hedenbergite 14.21 12.00 -2.21 -0.221 0.37756E+04 75 epidote 24.67 24.52 -0.15 -0.007 0.25708E+03 76 clinozoisite 22.81 20.26 -2.55 -0.116 0.43511E+04 77 epidote-Fe 29.84 28.78 -1.06 -0.055 0.18097E+04 78 fayalite 14.05 9.80 -4.24 -0.606 0.72481E+04 79 ferrosilite 11.15 6.41 -4.74 -0.474 0.80963E+04 83 gibbsite 4.08 2.02 -2.06 -0.294 0.35137E+04 84 glaucophane 22.97 18.92 -4.05 -0.109 0.69160E+04 87 greenalite 16.14 13.00 -3.13 -0.261 0.53526E+04 91 heulandite -5.83 -7.52 -1.69 -0.077 0.28938E+04 95 jadeite 4.22 3.01 -1.21 -0.121 0.20594E+04 96 julgoldite 70.43 66.71 -3.71 -0.096 0.63418E+04 97 kalsilite 7.58 4.30 -3.28 -0.469 0.56079E+04 98 kaolinite -1.33 -2.74 -1.41 -0.128 0.24081E+04 99 kyanite 4.88 0.65 -4.23 -0.423 0.72161E+04 101 laumontite 2.88 2.66 -0.23 -0.015 0.38652E+03 102 lawsonite 9.62 9.44 -0.17 -0.012 0.29534E+03 103 leucite 4.12 0.91 -3.21 -0.321 0.54850E+04 105 lizardite 23.24 19.69 -3.55 -0.296 0.60645E+04 107 magnetite 20.09 19.16 -0.92 -0.075 0.15782E+04 108 minnesotaite 10.39 6.22 -4.17 -0.245 0.71193E+04 110 magnesioferrite 26.21 21.39 -4.82 -0.393 0.82303E+04 113 margarite 17.32 13.49 -3.84 -0.154 0.65525E+04 120 muscovite 2.58 1.56 -1.03 -0.060 0.17518E+04 121 paragonite 4.24 3.66 -0.58 -0.034 0.99088E+03 122 nepheline 8.34 6.40 -1.94 -0.277 0.33078E+04 134 phlogopite-Na 29.65 26.09 -3.55 -0.197 0.60658E+04 136 prehnite 19.37 18.24 -1.14 -0.067 0.19390E+04 138 pumpellyite-Fe 46.27 45.09 -1.18 -0.026 0.20123E+04 139 pumpellyite-Mg 48.99 47.32 -1.67 -0.037 0.28597E+04 145 pyroxmangite 7.40 5.33 -2.07 -0.413 0.35284E+04 146 pyrophyllite -6.18 -9.53 -3.35 -0.210 0.57258E+04 147 quartz -2.99 -3.39 -0.40 -0.135 0.68913E+03 152 rhodonite 7.45 5.33 -2.11 -0.423 0.36087E+04 153 sanidine -1.28 -2.49 -1.21 -0.093 0.20677E+04 156 sillimanite 5.26 0.65 -4.61 -0.461 0.78741E+04 164 stilpnomelane-Fe 13.02 12.72 -0.30 -0.009 0.50906E+03 165 stilpnomelane-Mg 27.44 23.86 -3.58 -0.107 0.61074E+04 171 talc 16.49 12.91 -3.59 -0.211 0.61214E+04 174 tephroite 18.09 14.06 -4.03 -0.575 0.68783E+04 177 topaz-H 4.62 0.65 -3.97 -0.361 0.67762E+04 178 tridymite -2.63 -3.39 -0.77 -0.256 0.13091E+04 187 wairakite 3.95 2.66 -1.29 -0.076 0.22085E+04 188 walstromite 11.51 8.79 -2.72 -0.543 0.46376E+04 189 wollastonite 10.46 8.79 -1.67 -0.334 0.28480E+04 190 pseudo-wollastonite 11.00 8.79 -2.21 -0.441 0.37679E+04 191 zoisite 22.85 20.26 -2.59 -0.118 0.44252E+04 192 akaganeite 7.75 6.28 -1.47 -0.318 0.25125E+04 193 beidellite-Ca -1.65 -5.73 -4.09 -0.253 0.69768E+04 195 beidellite-K -1.52 -5.87 -4.35 -0.266 0.74286E+04 196 beidellite-Mg -1.79 -6.29 -4.50 -0.278 0.76773E+04 197 beidellite-Na -1.34 -5.18 -3.83 -0.235 0.65478E+04 199 chalcedony -2.80 -3.39 -0.59 -0.197 0.10084E+04 201 montmorillonite-Ca -2.29 -5.27 -2.98 -0.184 0.50920E+04 202 montmorillonite-K -2.24 -5.41 -3.18 -0.194 0.54220E+04 203 montmorillonite-Mg -2.48 -5.83 -3.35 -0.207 0.57157E+04 204 montmorillonite-Na -2.04 -4.72 -2.68 -0.164 0.45769E+04 205 nontronite-Ca 3.21 2.79 -0.42 -0.027 0.72221E+03 206 nontronite-H 2.53 0.78 -1.75 -0.117 0.29912E+04 207 nontronite-K 3.34 2.65 -0.69 -0.044 0.11754E+04 208 nontronite-Mg 3.07 2.24 -0.84 -0.054 0.14300E+04 209 nontronite-Na 3.52 3.35 -0.17 -0.011 0.29627E+03 224 tobermorite 9.82 6.76 -3.06 -0.836 0.52334E+04 233 boehmite 4.41 2.02 -2.38 -0.397 0.40720E+04 235 ferrous-oxide 9.81 6.60 -3.21 -0.804 0.54890E+04 240 silica-amorphous -2.09 -3.39 -1.30 -0.434 0.22226E+04 242 an20ab80 2.02 1.58 -0.44 -0.034 0.74489E+03 243 an25ab75 2.65 2.07 -0.57 -0.044 0.97808E+03 244 an30ab70 3.28 2.56 -0.72 -0.055 0.12209E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 0.4000000 g Current total amount of reactant added: 11.9990000 g New total amount of reactant added: 12.3990000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.6627E-13 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 7 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 12.3990000 Water: Moles liquid = 0.5540E+02 kg liquid = 0.9981E+00 Moles total = 0.5535E+02 kg total = 0.9972E+00 Activity = 1.0000 Stoichiometric ionic strength = .4957630E-02 Osmotic coef. = 0.9625 True ionic strength = .8798770E-02 Chg. balance for total moles = 0.6627E-13 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.14598E-09 -9.8357 0.12833E-09 -9.8917 0.87908E+00 -0.0560 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13793E-03 -3.8603 0.12088E-03 -3.9177 0.87638E+00 -0.0573 4 SO4-- 0.25535E-04 -4.5929 0.15993E-04 -4.7961 0.62631E+00 -0.2032 5 HCO3- 0.66994E-05 -5.1740 0.58756E-05 -5.2310 0.87703E+00 -0.0570 6 HS- 0.75871E-12 -12.1199 0.66497E-12 -12.1772 0.87645E+00 -0.0573 7 Al+++ 0.62647E-27 -27.2031 0.22205E-27 -27.6535 0.35445E+00 -0.4504 8 H4SiO4 0.40455E-03 -3.3930 0.40455E-03 -3.3930 0.10000E+01 0.0000 9 Ca++ 0.40519E-07 -7.3923 0.25283E-07 -7.5972 0.62399E+00 -0.2048 10 Mg++ 0.17723E-10 -10.7515 0.11033E-10 -10.9573 0.62254E+00 -0.2058 11 Fe++ 0.10451E-12 -12.9809 0.65096E-13 -13.1864 0.62288E+00 -0.2056 12 K+ 0.68606E-04 -4.1636 0.60177E-04 -4.2206 0.87714E+00 -0.0569 13 Na+ 0.86977E-02 -2.0606 0.76219E-02 -2.1179 0.87631E+00 -0.0573 14 Mn++ 0.14038E-10 -10.8527 0.87476E-11 -11.0581 0.62315E+00 -0.2054 15 HPO4-- 0.42175E-06 -6.3749 0.26417E-06 -6.5781 0.62635E+00 -0.2032 16 HSiO3- 0.33588E-02 -2.4738 0.29436E-02 -2.5311 0.87638E+00 -0.0573 17 Ca(HSiO3)+ 0.19321E-08 -8.7140 0.16949E-08 -8.7709 0.87724E+00 -0.0569 18 Mg(HSiO3)+ 0.10493E-11 -11.9791 0.92045E-12 -12.0360 0.87724E+00 -0.0569 19 NaHSiO3,aq 0.36286E-03 -3.4403 0.36286E-03 -3.4403 0.10000E+01 0.0000 20 AlO+ 0.20911E-14 -14.6796 0.18344E-14 -14.7365 0.87724E+00 -0.0569 22 HAlO2,aq 0.28467E-08 -8.5457 0.28467E-08 -8.5457 0.10000E+01 0.0000 23 AlO2- 0.56082E-04 -4.2512 0.49104E-04 -4.3089 0.87557E+00 -0.0577 24 CH4,aq 0.23767E-18 -18.6240 0.23731E-18 -18.6247 0.99847E+00 -0.0007 29 CO,aq 0.65431E-19 -19.1842 0.65431E-19 -19.1842 0.10000E+01 0.0000 30 CO2,aq 0.16136E-08 -8.7922 0.16111E-08 -8.7929 0.99847E+00 -0.0007 31 CO3-2 0.63922E-05 -5.1943 0.39992E-05 -5.3980 0.62563E+00 -0.2037 32 CaCO3,aq 0.12678E-08 -8.8969 0.12678E-08 -8.8969 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.43226E-11 -11.3643 0.37920E-11 -11.4211 0.87724E+00 -0.0569 34 CaCl+ 0.56380E-11 -11.2489 0.49458E-11 -11.3058 0.87724E+00 -0.0569 35 CaCl2,aq 0.14203E-15 -15.8476 0.14203E-15 -15.8476 0.10000E+01 0.0000 36 CaOH+ 0.16007E-07 -7.7957 0.14042E-07 -7.8526 0.87724E+00 -0.0569 37 CaSO4,aq 0.12840E-09 -9.8914 0.12840E-09 -9.8914 0.10000E+01 0.0000 38 HCl,aq 0.28425E-14 -14.5463 0.28425E-14 -14.5463 0.10000E+01 0.0000 43 FeCl+ 0.14198E-16 -16.8478 0.12455E-16 -16.9047 0.87724E+00 -0.0569 46 FeO,aq 0.15363E-09 -9.8135 0.15363E-09 -9.8135 0.10000E+01 0.0000 47 FeOH+ 0.18823E-10 -10.7253 0.16512E-10 -10.7822 0.87724E+00 -0.0569 48 HFeO2- 0.14293E-07 -7.8449 0.12526E-07 -7.9022 0.87638E+00 -0.0573 49 FeO+ 0.11166E-14 -14.9521 0.97952E-15 -15.0090 0.87724E+00 -0.0569 51 FeO2- 0.13887E-07 -7.8574 0.12171E-07 -7.9147 0.87638E+00 -0.0573 52 HFeO2,aq 0.19864E-09 -9.7019 0.19864E-09 -9.7019 0.10000E+01 0.0000 53 H2,aq 0.16191E-08 -8.7907 0.16167E-08 -8.7914 0.99847E+00 -0.0007 54 KCl,aq 0.13184E-09 -9.8800 0.13184E-09 -9.8800 0.10000E+01 0.0000 55 KHSO4,aq 0.34919E-18 -18.4569 0.34919E-18 -18.4569 0.10000E+01 0.0000 56 KOH,aq 0.20026E-06 -6.6984 0.20026E-06 -6.6984 0.10000E+01 0.0000 57 KSO4- 0.17041E-07 -7.7685 0.14934E-07 -7.8258 0.87638E+00 -0.0573 58 MgCO3,aq 0.13868E-12 -12.8580 0.13868E-12 -12.8580 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.19274E-14 -14.7150 0.16908E-14 -14.7719 0.87724E+00 -0.0569 60 MgCl+ 0.22298E-14 -14.6517 0.19561E-14 -14.7086 0.87724E+00 -0.0569 61 MgOH+ 0.38651E-10 -10.4128 0.33906E-10 -10.4697 0.87724E+00 -0.0569 63 MnO,aq 0.55009E-09 -9.2596 0.55009E-09 -9.2596 0.10000E+01 0.0000 64 MnOH+ 0.23497E-09 -9.6290 0.20613E-09 -9.6859 0.87724E+00 -0.0569 65 MnO2-2 0.17719E-11 -11.7516 0.11086E-11 -11.9552 0.62563E+00 -0.2037 66 HMnO2- 0.35563E-10 -10.4490 0.31167E-10 -10.5063 0.87638E+00 -0.0573 69 MnCl+ 0.74225E-14 -14.1294 0.65113E-14 -14.1863 0.87724E+00 -0.0569 70 MnSO4,aq 0.40388E-13 -13.3938 0.40388E-13 -13.3938 0.10000E+01 0.0000 71 NaCl,aq 0.30532E-06 -6.5152 0.30532E-06 -6.5152 0.10000E+01 0.0000 72 NaOH,aq 0.25518E-04 -4.5931 0.25518E-04 -4.5931 0.10000E+01 0.0000 74 OH- 0.51421E-02 -2.2889 0.45023E-02 -2.3466 0.87557E+00 -0.0577 79 HPO3-2 0.21273E-17 -17.6722 0.13309E-17 -17.8759 0.62563E+00 -0.2037 82 H3PO4,aq 0.30426E-16 -16.5168 0.30426E-16 -16.5168 0.10000E+01 0.0000 83 H2PO4- 0.71323E-09 -9.1468 0.62536E-09 -9.2039 0.87680E+00 -0.0571 84 PO4-3 0.46215E-08 -8.3352 0.16795E-08 -8.7748 0.36342E+00 -0.4396 87 H2P2O7-2 0.49014E-19 -19.3097 0.30665E-19 -19.5134 0.62563E+00 -0.2037 88 HP2O7-3 0.13456E-15 -15.8711 0.47714E-16 -16.3214 0.35459E+00 -0.4503 89 P2O7-4 0.54597E-15 -15.2628 0.88824E-16 -16.0515 0.16269E+00 -0.7886 90 H2S,aq 0.26414E-15 -15.5782 0.26374E-15 -15.5788 0.99847E+00 -0.0007 97 SO3-2 0.53311E-14 -14.2732 0.33599E-14 -14.4737 0.63024E+00 -0.2005 98 HSO3- 0.30804E-16 -16.5114 0.26996E-16 -16.5687 0.87638E+00 -0.0573 99 HSO4- 0.22536E-11 -11.6471 0.19779E-11 -11.7038 0.87766E+00 -0.0567 Charge balance for all species = 0.6516E-13 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.1459809E-09 -.9120314E-02 -.9186900E+01 0.0000 2 H2O 0.1000000E+01 0.5550981E+02 0.9993917E+06 0.0000 3 Cl- 0.1379274E-03 0.1382329E-03 0.4897662E+01 5.9740 4 SO4-- 0.2553511E-04 0.2555364E-04 0.2453167E+01 14.9873 5 HCO3- 0.6699387E-05 0.1309450E-04 0.7984833E+00 4.6607 6 HS- 0.7587136E-12 -.1355216E-08 -.4479127E-04 -2.2855 7 Al+++ 0.6264718E-27 0.5608479E-04 0.1512292E+01 2.0215 8 H4SiO4 0.4045468E-03 0.4126171E-02 0.3963371E+03 -3.3930 9 Ca++ 0.4051895E-07 0.5986376E-07 0.2397698E-02 12.1862 10 Mg++ 0.1772268E-10 0.5756544E-10 0.1398644E-05 8.8260 11 Fe++ 0.1045081E-12 0.2855154E-07 0.1593507E-02 6.5969 12 K+ 0.6860607E-04 0.6882350E-04 0.2689430E+01 5.6711 13 Na+ 0.8697661E-02 0.9086345E-02 0.2087608E+03 7.7737 14 Mn++ 0.1403784E-10 0.8364840E-09 0.4592562E-04 8.7252 15 HPO4-- 0.4217528E-06 0.4270875E-06 0.4096544E-01 13.2052 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.2052960E+00 -.9103247E-02 -.1961927E+00 0.0000000E+00 2 H2O 0.5535282E+02 0.5540593E+02 -.5310743E-01 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.3691230E-03 0.2550582E-04 0.3436172E-03 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.3436186E-03 -.1352680E-08 -.3436172E-03 0.0000000E+00 7 Al+++ 0.4042994E-01 0.5597983E-04 0.4037396E-01 0.0000000E+00 8 H4SiO4 0.1291081E+00 0.4118450E-02 0.1249896E+00 0.0000000E+00 9 Ca++ 0.1427509E-01 0.5975174E-07 0.1427503E-01 0.0000000E+00 10 Mg++ 0.9840476E-02 0.5745772E-10 0.9840476E-02 0.0000000E+00 11 Fe++ 0.8840594E-02 0.2849811E-07 0.8840565E-02 0.0000000E+00 12 K+ 0.2632484E-02 0.6869471E-04 0.2563789E-02 0.0000000E+00 13 Na+ 0.1572384E-01 0.9069341E-02 0.6654496E-02 0.0000000E+00 14 Mn++ 0.2149813E-03 0.8349187E-09 0.2149804E-03 0.0000000E+00 15 HPO4-- 0.7337203E-04 0.4262883E-06 0.7294574E-04 0.0000000E+00 Chg. balance for solid moles: 0.3524E-17 Mass of aqueous solution: 0.998762E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 12.3990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 0.6654E-02 -2.177 1.745 0.242 12.88 0.6698 andradite 0.4826E-03 -3.316 0.2453 -0.610 1.810 0.6372E-01 grossular 0.3636E-04 -4.439 0.1638E-01 -1.786 0.1209 0.4558E-02 apatite-OH 0.2432E-04 -4.614 0.1221E-01 -1.913 0.9016E-01 0.3881E-02 clinochlore 0.1968E-02 -2.706 1.094 0.039 8.075 0.4161 daphnite 0.1218E-02 -2.914 0.8693 -0.061 6.417 0.2634 chlorite-Mn 0.4300E-04 -4.367 0.3048E-01 -1.516 0.2250 0.9714E-02 hematite 0.7970E-03 -3.099 0.1273 -0.895 0.9396 0.2413E-01 microcline 0.2564E-02 -2.591 0.7136 -0.147 5.268 0.2788 prehnite-Fe 0.1896E-03 -3.722 0.8367E-01 -1.077 0.6176 0.2807E-01 stilbite 0.1222E-01 -1.913 8.610 0.935 63.56 4.016 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.9299E+00 0.9299E+00 1.0000 -0.032 grossular 0.7007E-01 0.7007E-01 1.0000 -1.154 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.6094E+00 0.6094E+00 1.0000 -0.215 daphnite 0.3773E+00 0.3773E+00 1.0000 -0.423 chlorite-Mn 0.1331E-01 0.1331E-01 1.0000 -1.876 hematite 0.1000E+01 0.1000E+01 1.0000 0.000 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 prehnite-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 13.546790 g Volume = 5.777917 cm3 Porosity: 3.0486% V(tot) - V(min): 0.18168E+00 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 12.3990000 g log = 1.0934 Original solution: 1000.0103000 g Original solution / Rock added: 80.65 (Water/Rock Ratio), log = 1.9066 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0203 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.1000E+01 0.9860 0.1006E+01 0.1020E+01 CO2,gas 0.1678E-06 1.0071 0.1724E-06 0.1712E-06 CH4,gas 0.3381E-15 1.0125 0.3493E-15 0.3450E-15 H2,gas 0.2079E-05 1.0005 0.2123E-05 0.2121E-05 H2S,gas 0.7134E-14 0.9960 0.7250E-14 0.7279E-14 S2,gas 0.4292E-36 1.0000 0.4380E-36 0.4380E-36 CO,gas 0.9557E-16 1.0000 0.9751E-16 0.9751E-16 SO3,gas 0.9760E-40 1.0000 0.9958E-40 0.9958E-40 SO2,gas 0.8059E-23 1.0000 0.8223E-23 0.8223E-23 HCl,gas 0.4916E-17 1.0000 0.5016E-17 0.5016E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 16 albite -0.38 -0.38 0.00 0.000 -0.94784E-12 22 andradite 39.01 39.01 0.00 0.000 0.00000E+00 23 grossular 32.73 32.73 0.00 0.000 0.00000E+00 32 apatite-OH -18.15 -18.15 0.00 0.000 -0.60662E-11 46 clinochlore 39.07 39.07 0.00 0.000 0.00000E+00 47 daphnite 28.97 28.97 0.00 0.000 0.00000E+00 48 chlorite-Mn 46.87 46.87 0.00 0.000 0.00000E+00 90 hematite 12.57 12.57 0.00 0.000 0.90992E-11 116 microcline -2.49 -2.49 0.00 0.000 -0.10616E-10 137 prehnite-Fe 22.50 22.50 0.00 0.000 -0.24265E-10 163 stilbite -7.52 -7.52 0.00 0.000 -0.90992E-11 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -15.12 -8.46 -2.821 0.14449E+05 -6.764 3 CH4,gas 4.54 -12.61 -17.16 -4.289 0.29293E+05 -15.457 4 H2,gas 8.00 0.63 -7.37 -4.213 0.12588E+05 -5.673 5 H2S,gas -6.23 -22.07 -15.84 -7.919 0.27044E+05 -14.140 6 S2,gas -7.34 -45.39 -38.06 -5.855 0.64982E+05 -36.359 7 CO,gas 3.21 -14.49 -17.71 -5.449 0.30239E+05 -16.011 8 SO3,gas 17.12 -24.58 -41.70 -10.425 0.71203E+05 -40.002 9 SO2,gas 0.83 -23.95 -24.78 -6.609 0.42318E+05 -23.085 10 HCl,gas 5.19 -13.81 -19.00 -9.499 0.32440E+05 -17.300 11 acmite 7.71 7.27 -0.44 -0.046 0.74949E+03 15 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 19 spessartine 24.46 20.04 -4.42 -0.221 0.75431E+04 20 analcite 3.32 3.01 -0.31 -0.035 0.53392E+03 21 andalusite 5.00 0.65 -4.35 -0.435 0.74302E+04 26 annite 20.12 17.30 -2.82 -0.157 0.48136E+04 27 phlogopite 27.06 23.99 -3.07 -0.171 0.52470E+04 29 anorthite 12.71 9.44 -3.27 -0.251 0.55787E+04 35 aragonite 0.97 -2.94 -3.90 -1.301 0.66642E+04 36 brucite 12.57 8.83 -3.74 -0.749 0.63902E+04 37 calcite 0.81 -2.94 -3.75 -1.249 0.64000E+04 38 carnegieite-low 9.02 6.40 -2.62 -0.374 0.44755E+04 39 carnegieite-high 10.09 6.40 -3.69 -0.527 0.63025E+04 40 carpholite-Mg 8.58 6.08 -2.50 -0.167 0.42672E+04 41 carpholite-Fe 6.71 3.85 -2.86 -0.191 0.48813E+04 42 celadonite 5.34 2.95 -2.40 -0.141 0.40895E+04 43 celadonite-Fe 3.88 0.72 -3.16 -0.186 0.53941E+04 44 chrysotile 23.89 19.69 -4.20 -0.350 0.71719E+04 50 chloritoid-Mg 13.20 9.48 -3.72 -0.248 0.63547E+04 51 chloritoid-Fe 9.17 7.25 -1.93 -0.128 0.32899E+04 52 chloritoid-Mn 11.40 9.38 -2.03 -0.135 0.34591E+04 54 coesite -2.38 -3.39 -1.02 -0.339 0.17364E+04 59 corundum 8.38 4.04 -4.34 -0.395 0.74107E+04 61 cristobalite -2.56 -3.39 -0.83 -0.278 0.14218E+04 63 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71234E+04 65 diaspore 2.87 2.02 -0.85 -0.142 0.14551E+04 67 diopside 16.18 14.23 -1.96 -0.196 0.33384E+04 68 hedenbergite 14.21 12.00 -2.21 -0.221 0.37756E+04 75 epidote 24.67 24.52 -0.15 -0.007 0.25708E+03 76 clinozoisite 22.81 20.26 -2.55 -0.116 0.43511E+04 77 epidote-Fe 29.84 28.78 -1.06 -0.055 0.18097E+04 78 fayalite 14.05 9.80 -4.24 -0.606 0.72481E+04 79 ferrosilite 11.15 6.41 -4.74 -0.474 0.80963E+04 83 gibbsite 4.08 2.02 -2.06 -0.294 0.35137E+04 84 glaucophane 22.97 18.92 -4.05 -0.109 0.69160E+04 87 greenalite 16.14 13.00 -3.13 -0.261 0.53526E+04 91 heulandite -5.83 -7.52 -1.69 -0.077 0.28938E+04 95 jadeite 4.22 3.01 -1.21 -0.121 0.20594E+04 96 julgoldite 70.43 66.71 -3.71 -0.096 0.63418E+04 97 kalsilite 7.58 4.30 -3.28 -0.469 0.56079E+04 98 kaolinite -1.33 -2.74 -1.41 -0.128 0.24081E+04 99 kyanite 4.88 0.65 -4.23 -0.423 0.72161E+04 101 laumontite 2.88 2.66 -0.23 -0.015 0.38652E+03 102 lawsonite 9.62 9.44 -0.17 -0.012 0.29534E+03 103 leucite 4.12 0.91 -3.21 -0.321 0.54850E+04 105 lizardite 23.24 19.69 -3.55 -0.296 0.60645E+04 107 magnetite 20.09 19.16 -0.92 -0.075 0.15782E+04 108 minnesotaite 10.39 6.22 -4.17 -0.245 0.71193E+04 110 magnesioferrite 26.21 21.39 -4.82 -0.393 0.82303E+04 113 margarite 17.32 13.49 -3.84 -0.154 0.65525E+04 120 muscovite 2.58 1.56 -1.03 -0.060 0.17518E+04 121 paragonite 4.24 3.66 -0.58 -0.034 0.99088E+03 122 nepheline 8.34 6.40 -1.94 -0.277 0.33078E+04 134 phlogopite-Na 29.65 26.09 -3.55 -0.197 0.60658E+04 136 prehnite 19.37 18.24 -1.14 -0.067 0.19390E+04 138 pumpellyite-Fe 46.27 45.09 -1.18 -0.026 0.20123E+04 139 pumpellyite-Mg 48.99 47.32 -1.67 -0.037 0.28597E+04 145 pyroxmangite 7.40 5.33 -2.07 -0.413 0.35284E+04 146 pyrophyllite -6.18 -9.53 -3.35 -0.210 0.57258E+04 147 quartz -2.99 -3.39 -0.40 -0.135 0.68913E+03 152 rhodonite 7.45 5.33 -2.11 -0.423 0.36087E+04 153 sanidine -1.28 -2.49 -1.21 -0.093 0.20677E+04 156 sillimanite 5.26 0.65 -4.61 -0.461 0.78741E+04 164 stilpnomelane-Fe 13.02 12.72 -0.30 -0.009 0.50906E+03 165 stilpnomelane-Mg 27.44 23.86 -3.58 -0.107 0.61074E+04 171 talc 16.49 12.91 -3.59 -0.211 0.61214E+04 174 tephroite 18.09 14.06 -4.03 -0.575 0.68783E+04 177 topaz-H 4.62 0.65 -3.97 -0.361 0.67762E+04 178 tridymite -2.63 -3.39 -0.77 -0.256 0.13091E+04 187 wairakite 3.95 2.66 -1.29 -0.076 0.22085E+04 188 walstromite 11.51 8.79 -2.72 -0.543 0.46376E+04 189 wollastonite 10.46 8.79 -1.67 -0.334 0.28480E+04 190 pseudo-wollastonite 11.00 8.79 -2.21 -0.441 0.37679E+04 191 zoisite 22.85 20.26 -2.59 -0.118 0.44252E+04 192 akaganeite 7.75 6.28 -1.47 -0.318 0.25125E+04 193 beidellite-Ca -1.65 -5.73 -4.09 -0.253 0.69768E+04 195 beidellite-K -1.52 -5.87 -4.35 -0.266 0.74286E+04 196 beidellite-Mg -1.79 -6.29 -4.50 -0.278 0.76773E+04 197 beidellite-Na -1.34 -5.18 -3.83 -0.235 0.65478E+04 199 chalcedony -2.80 -3.39 -0.59 -0.197 0.10084E+04 201 montmorillonite-Ca -2.29 -5.27 -2.98 -0.184 0.50920E+04 202 montmorillonite-K -2.24 -5.41 -3.18 -0.194 0.54220E+04 203 montmorillonite-Mg -2.48 -5.83 -3.35 -0.207 0.57157E+04 204 montmorillonite-Na -2.04 -4.72 -2.68 -0.164 0.45769E+04 205 nontronite-Ca 3.21 2.79 -0.42 -0.027 0.72221E+03 206 nontronite-H 2.53 0.78 -1.75 -0.117 0.29912E+04 207 nontronite-K 3.34 2.65 -0.69 -0.044 0.11754E+04 208 nontronite-Mg 3.07 2.24 -0.84 -0.054 0.14300E+04 209 nontronite-Na 3.52 3.35 -0.17 -0.011 0.29627E+03 224 tobermorite 9.82 6.76 -3.06 -0.836 0.52334E+04 233 boehmite 4.41 2.02 -2.38 -0.397 0.40720E+04 235 ferrous-oxide 9.81 6.60 -3.21 -0.804 0.54890E+04 240 silica-amorphous -2.09 -3.39 -1.30 -0.434 0.22226E+04 242 an20ab80 2.02 1.58 -0.44 -0.034 0.74489E+03 243 an25ab75 2.65 2.07 -0.57 -0.044 0.97808E+03 244 an30ab70 3.28 2.56 -0.72 -0.055 0.12209E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 0.4000000 g Current total amount of reactant added: 12.3990000 g New total amount of reactant added: 12.7990000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.6625E-13 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 7 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 12.7990000 Water: Moles liquid = 0.5540E+02 kg liquid = 0.9981E+00 Moles total = 0.5535E+02 kg total = 0.9971E+00 Activity = 1.0000 Stoichiometric ionic strength = .4957637E-02 Osmotic coef. = 0.9625 True ionic strength = .8798776E-02 Chg. balance for total moles = 0.6625E-13 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.14598E-09 -9.8357 0.12833E-09 -9.8917 0.87908E+00 -0.0560 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13793E-03 -3.8603 0.12088E-03 -3.9176 0.87638E+00 -0.0573 4 SO4-- 0.25536E-04 -4.5928 0.15994E-04 -4.7961 0.62631E+00 -0.2032 5 HCO3- 0.66997E-05 -5.1739 0.58758E-05 -5.2309 0.87703E+00 -0.0570 6 HS- 0.75875E-12 -12.1199 0.66500E-12 -12.1772 0.87645E+00 -0.0573 7 Al+++ 0.62647E-27 -27.2031 0.22205E-27 -27.6535 0.35445E+00 -0.4504 8 H4SiO4 0.40455E-03 -3.3930 0.40455E-03 -3.3930 0.10000E+01 0.0000 9 Ca++ 0.40519E-07 -7.3923 0.25283E-07 -7.5972 0.62399E+00 -0.2048 10 Mg++ 0.17723E-10 -10.7515 0.11033E-10 -10.9573 0.62254E+00 -0.2058 11 Fe++ 0.10451E-12 -12.9808 0.65096E-13 -13.1864 0.62288E+00 -0.2056 12 K+ 0.68606E-04 -4.1636 0.60177E-04 -4.2206 0.87714E+00 -0.0569 13 Na+ 0.86977E-02 -2.0606 0.76219E-02 -2.1179 0.87631E+00 -0.0573 14 Mn++ 0.14038E-10 -10.8527 0.87476E-11 -11.0581 0.62315E+00 -0.2054 15 HPO4-- 0.42175E-06 -6.3749 0.26417E-06 -6.5781 0.62635E+00 -0.2032 16 HSiO3- 0.33588E-02 -2.4738 0.29436E-02 -2.5311 0.87638E+00 -0.0573 17 Ca(HSiO3)+ 0.19321E-08 -8.7140 0.16949E-08 -8.7709 0.87724E+00 -0.0569 18 Mg(HSiO3)+ 0.10493E-11 -11.9791 0.92045E-12 -12.0360 0.87724E+00 -0.0569 19 NaHSiO3,aq 0.36286E-03 -3.4403 0.36286E-03 -3.4403 0.10000E+01 0.0000 20 AlO+ 0.20911E-14 -14.6796 0.18344E-14 -14.7365 0.87724E+00 -0.0569 22 HAlO2,aq 0.28467E-08 -8.5457 0.28467E-08 -8.5457 0.10000E+01 0.0000 23 AlO2- 0.56082E-04 -4.2512 0.49104E-04 -4.3089 0.87557E+00 -0.0577 24 CH4,aq 0.23768E-18 -18.6240 0.23732E-18 -18.6247 0.99847E+00 -0.0007 29 CO,aq 0.65434E-19 -19.1842 0.65434E-19 -19.1842 0.10000E+01 0.0000 30 CO2,aq 0.16137E-08 -8.7922 0.16112E-08 -8.7929 0.99847E+00 -0.0007 31 CO3-2 0.63925E-05 -5.1943 0.39993E-05 -5.3980 0.62563E+00 -0.2037 32 CaCO3,aq 0.12679E-08 -8.8969 0.12679E-08 -8.8969 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.43228E-11 -11.3642 0.37922E-11 -11.4211 0.87724E+00 -0.0569 34 CaCl+ 0.56382E-11 -11.2489 0.49461E-11 -11.3057 0.87724E+00 -0.0569 35 CaCl2,aq 0.14205E-15 -15.8476 0.14205E-15 -15.8476 0.10000E+01 0.0000 36 CaOH+ 0.16007E-07 -7.7957 0.14042E-07 -7.8526 0.87724E+00 -0.0569 37 CaSO4,aq 0.12841E-09 -9.8914 0.12841E-09 -9.8914 0.10000E+01 0.0000 38 HCl,aq 0.28426E-14 -14.5463 0.28426E-14 -14.5463 0.10000E+01 0.0000 43 FeCl+ 0.14198E-16 -16.8478 0.12455E-16 -16.9046 0.87724E+00 -0.0569 46 FeO,aq 0.15363E-09 -9.8135 0.15363E-09 -9.8135 0.10000E+01 0.0000 47 FeOH+ 0.18823E-10 -10.7253 0.16512E-10 -10.7822 0.87724E+00 -0.0569 48 HFeO2- 0.14293E-07 -7.8449 0.12526E-07 -7.9022 0.87638E+00 -0.0573 49 FeO+ 0.11166E-14 -14.9521 0.97952E-15 -15.0090 0.87724E+00 -0.0569 51 FeO2- 0.13887E-07 -7.8574 0.12171E-07 -7.9147 0.87638E+00 -0.0573 52 HFeO2,aq 0.19864E-09 -9.7019 0.19864E-09 -9.7019 0.10000E+01 0.0000 53 H2,aq 0.16191E-08 -8.7907 0.16167E-08 -8.7914 0.99847E+00 -0.0007 54 KCl,aq 0.13184E-09 -9.8799 0.13184E-09 -9.8799 0.10000E+01 0.0000 55 KHSO4,aq 0.34921E-18 -18.4569 0.34921E-18 -18.4569 0.10000E+01 0.0000 56 KOH,aq 0.20026E-06 -6.6984 0.20026E-06 -6.6984 0.10000E+01 0.0000 57 KSO4- 0.17042E-07 -7.7685 0.14935E-07 -7.8258 0.87638E+00 -0.0573 58 MgCO3,aq 0.13868E-12 -12.8580 0.13868E-12 -12.8580 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.19275E-14 -14.7150 0.16909E-14 -14.7719 0.87724E+00 -0.0569 60 MgCl+ 0.22299E-14 -14.6517 0.19562E-14 -14.7086 0.87724E+00 -0.0569 61 MgOH+ 0.38651E-10 -10.4128 0.33906E-10 -10.4697 0.87724E+00 -0.0569 63 MnO,aq 0.55009E-09 -9.2596 0.55009E-09 -9.2596 0.10000E+01 0.0000 64 MnOH+ 0.23497E-09 -9.6290 0.20613E-09 -9.6859 0.87724E+00 -0.0569 65 MnO2-2 0.17719E-11 -11.7516 0.11086E-11 -11.9552 0.62563E+00 -0.2037 66 HMnO2- 0.35563E-10 -10.4490 0.31167E-10 -10.5063 0.87638E+00 -0.0573 69 MnCl+ 0.74228E-14 -14.1294 0.65116E-14 -14.1863 0.87724E+00 -0.0569 70 MnSO4,aq 0.40390E-13 -13.3937 0.40390E-13 -13.3937 0.10000E+01 0.0000 71 NaCl,aq 0.30534E-06 -6.5152 0.30534E-06 -6.5152 0.10000E+01 0.0000 72 NaOH,aq 0.25518E-04 -4.5931 0.25518E-04 -4.5931 0.10000E+01 0.0000 74 OH- 0.51421E-02 -2.2889 0.45023E-02 -2.3466 0.87557E+00 -0.0577 79 HPO3-2 0.21273E-17 -17.6722 0.13309E-17 -17.8759 0.62563E+00 -0.2037 82 H3PO4,aq 0.30426E-16 -16.5168 0.30426E-16 -16.5168 0.10000E+01 0.0000 83 H2PO4- 0.71323E-09 -9.1468 0.62536E-09 -9.2039 0.87680E+00 -0.0571 84 PO4-3 0.46215E-08 -8.3352 0.16795E-08 -8.7748 0.36342E+00 -0.4396 87 H2P2O7-2 0.49014E-19 -19.3097 0.30665E-19 -19.5134 0.62563E+00 -0.2037 88 HP2O7-3 0.13456E-15 -15.8711 0.47713E-16 -16.3214 0.35459E+00 -0.4503 89 P2O7-4 0.54597E-15 -15.2628 0.88823E-16 -16.0515 0.16269E+00 -0.7886 90 H2S,aq 0.26415E-15 -15.5781 0.26375E-15 -15.5788 0.99847E+00 -0.0007 97 SO3-2 0.53313E-14 -14.2732 0.33600E-14 -14.4737 0.63024E+00 -0.2005 98 HSO3- 0.30806E-16 -16.5114 0.26998E-16 -16.5687 0.87638E+00 -0.0573 99 HSO4- 0.22537E-11 -11.6471 0.19780E-11 -11.7038 0.87766E+00 -0.0567 Charge balance for all species = 0.6512E-13 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.1459810E-09 -.9120310E-02 -.9186896E+01 0.0000 2 H2O 0.1000000E+01 0.5550981E+02 0.9993917E+06 0.0000 3 Cl- 0.1379332E-03 0.1382387E-03 0.4897868E+01 5.9740 4 SO4-- 0.2553619E-04 0.2555472E-04 0.2453271E+01 14.9873 5 HCO3- 0.6699671E-05 0.1309506E-04 0.7985170E+00 4.6607 6 HS- 0.7587462E-12 -.1355215E-08 -.4479124E-04 -2.2855 7 Al+++ 0.6264730E-27 0.5608476E-04 0.1512291E+01 2.0215 8 H4SiO4 0.4045468E-03 0.4126170E-02 0.3963369E+03 -3.3930 9 Ca++ 0.4051900E-07 0.5986388E-07 0.2397703E-02 12.1862 10 Mg++ 0.1772270E-10 0.5756549E-10 0.1398645E-05 8.8260 11 Fe++ 0.1045082E-12 0.2855153E-07 0.1593506E-02 6.5969 12 K+ 0.6860611E-04 0.6882354E-04 0.2689432E+01 5.6711 13 Na+ 0.8697665E-02 0.9086350E-02 0.2087609E+03 7.7737 14 Mn++ 0.1403786E-10 0.8364842E-09 0.4592563E-04 8.7252 15 HPO4-- 0.4217524E-06 0.4270871E-06 0.4096540E-01 13.2052 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.2119194E+00 -.9102859E-02 -.2028165E+00 0.0000000E+00 2 H2O 0.5534781E+02 0.5540359E+02 -.5578494E-01 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.3802084E-03 0.2550582E-04 0.3547026E-03 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.3547039E-03 -.1352622E-08 -.3547026E-03 0.0000000E+00 7 Al+++ 0.4173423E-01 0.5597745E-04 0.4167825E-01 0.0000000E+00 8 H4SiO4 0.1332732E+00 0.4118274E-02 0.1291549E+00 0.0000000E+00 9 Ca++ 0.1473515E-01 0.5974933E-07 0.1473509E-01 0.0000000E+00 10 Mg++ 0.1015794E-01 0.5745534E-10 0.1015794E-01 0.0000000E+00 11 Fe++ 0.9125797E-02 0.2849690E-07 0.9125768E-02 0.0000000E+00 12 K+ 0.2717410E-02 0.6869185E-04 0.2648718E-02 0.0000000E+00 13 Na+ 0.1622593E-01 0.9068963E-02 0.7156971E-02 0.0000000E+00 14 Mn++ 0.2219167E-03 0.8348837E-09 0.2219159E-03 0.0000000E+00 15 HPO4-- 0.7573906E-04 0.4262699E-06 0.7531279E-04 0.0000000E+00 Chg. balance for solid moles: 0.1518E-16 Mass of aqueous solution: 0.998720E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 12.7990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 0.7157E-02 -2.145 1.877 0.273 13.42 0.7204 andradite 0.5834E-03 -3.234 0.2965 -0.528 2.120 0.7703E-01 grossular 0.4396E-04 -4.357 0.1980E-01 -1.703 0.1416 0.5510E-02 apatite-OH 0.2510E-04 -4.600 0.1261E-01 -1.899 0.9017E-01 0.4007E-02 clinochlore 0.2032E-02 -2.692 1.129 0.053 8.074 0.4295 daphnite 0.1258E-02 -2.900 0.8973 -0.047 6.416 0.2719 chlorite-Mn 0.4438E-04 -4.353 0.3147E-01 -1.502 0.2250 0.1003E-01 hematite 0.7792E-03 -3.108 0.1244 -0.905 0.8897 0.2358E-01 microcline 0.2649E-02 -2.577 0.7372 -0.132 5.271 0.2880 prehnite-Fe 0.1124E-03 -3.949 0.4960E-01 -1.304 0.3547 0.1664E-01 stilbite 0.1250E-01 -1.903 8.811 0.945 63.00 4.110 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.9299E+00 0.9299E+00 1.0000 -0.032 grossular 0.7007E-01 0.7007E-01 1.0000 -1.154 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.6094E+00 0.6094E+00 1.0000 -0.215 daphnite 0.3773E+00 0.3773E+00 1.0000 -0.423 chlorite-Mn 0.1331E-01 0.1331E-01 1.0000 -1.876 hematite 0.1000E+01 0.1000E+01 1.0000 0.000 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 prehnite-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 13.985674 g Volume = 5.956153 cm3 Porosity: 2.6709% V(tot) - V(min): 0.16345E+00 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 12.7990000 g log = 1.1072 Original solution: 1000.0103000 g Original solution / Rock added: 78.13 (Water/Rock Ratio), log = 1.8928 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0203 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.1000E+01 0.9860 0.1006E+01 0.1020E+01 CO2,gas 0.1678E-06 1.0071 0.1724E-06 0.1712E-06 CH4,gas 0.3381E-15 1.0125 0.3493E-15 0.3450E-15 H2,gas 0.2079E-05 1.0005 0.2123E-05 0.2121E-05 H2S,gas 0.7134E-14 0.9960 0.7250E-14 0.7279E-14 S2,gas 0.4293E-36 1.0000 0.4380E-36 0.4380E-36 CO,gas 0.9557E-16 1.0000 0.9751E-16 0.9751E-16 SO3,gas 0.9761E-40 1.0000 0.9959E-40 0.9959E-40 SO2,gas 0.8060E-23 1.0000 0.8223E-23 0.8223E-23 HCl,gas 0.4916E-17 1.0000 0.5016E-17 0.5016E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 16 albite -0.38 -0.38 0.00 0.000 0.11184E-10 22 andradite 39.01 39.01 0.00 0.000 0.00000E+00 23 grossular 32.73 32.73 0.00 0.000 0.00000E+00 32 apatite-OH -18.15 -18.15 0.00 0.000 0.00000E+00 46 clinochlore 39.07 39.07 0.00 0.000 0.12132E-10 47 daphnite 28.97 28.97 0.00 0.000 0.36397E-10 48 chlorite-Mn 46.87 46.87 0.00 0.000 0.36397E-10 90 hematite 12.57 12.57 0.00 0.000 0.30331E-11 116 microcline -2.49 -2.49 0.00 0.000 0.13649E-10 137 prehnite-Fe 22.50 22.50 0.00 0.000 -0.24265E-10 163 stilbite -7.52 -7.52 0.00 0.000 0.15165E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -15.12 -8.46 -2.821 0.14449E+05 -6.764 3 CH4,gas 4.54 -12.61 -17.16 -4.289 0.29293E+05 -15.457 4 H2,gas 8.00 0.63 -7.37 -4.213 0.12588E+05 -5.673 5 H2S,gas -6.23 -22.07 -15.84 -7.919 0.27044E+05 -14.140 6 S2,gas -7.34 -45.39 -38.06 -5.855 0.64982E+05 -36.359 7 CO,gas 3.21 -14.49 -17.71 -5.449 0.30239E+05 -16.011 8 SO3,gas 17.12 -24.58 -41.70 -10.425 0.71203E+05 -40.002 9 SO2,gas 0.83 -23.95 -24.78 -6.609 0.42318E+05 -23.085 10 HCl,gas 5.19 -13.81 -19.00 -9.499 0.32440E+05 -17.300 11 acmite 7.71 7.27 -0.44 -0.046 0.74949E+03 15 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 19 spessartine 24.46 20.04 -4.42 -0.221 0.75431E+04 20 analcite 3.32 3.01 -0.31 -0.035 0.53392E+03 21 andalusite 5.00 0.65 -4.35 -0.435 0.74302E+04 26 annite 20.12 17.30 -2.82 -0.157 0.48136E+04 27 phlogopite 27.06 23.99 -3.07 -0.171 0.52470E+04 29 anorthite 12.71 9.44 -3.27 -0.251 0.55787E+04 35 aragonite 0.97 -2.94 -3.90 -1.301 0.66642E+04 36 brucite 12.57 8.83 -3.74 -0.749 0.63902E+04 37 calcite 0.81 -2.94 -3.75 -1.249 0.63999E+04 38 carnegieite-low 9.02 6.40 -2.62 -0.374 0.44755E+04 39 carnegieite-high 10.09 6.40 -3.69 -0.527 0.63025E+04 40 carpholite-Mg 8.58 6.08 -2.50 -0.167 0.42672E+04 41 carpholite-Fe 6.71 3.85 -2.86 -0.191 0.48813E+04 42 celadonite 5.34 2.95 -2.40 -0.141 0.40895E+04 43 celadonite-Fe 3.88 0.72 -3.16 -0.186 0.53941E+04 44 chrysotile 23.89 19.69 -4.20 -0.350 0.71719E+04 50 chloritoid-Mg 13.20 9.48 -3.72 -0.248 0.63547E+04 51 chloritoid-Fe 9.17 7.25 -1.93 -0.128 0.32899E+04 52 chloritoid-Mn 11.40 9.38 -2.03 -0.135 0.34591E+04 54 coesite -2.38 -3.39 -1.02 -0.339 0.17364E+04 59 corundum 8.38 4.04 -4.34 -0.395 0.74107E+04 61 cristobalite -2.56 -3.39 -0.83 -0.278 0.14218E+04 63 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71234E+04 65 diaspore 2.87 2.02 -0.85 -0.142 0.14551E+04 67 diopside 16.18 14.23 -1.96 -0.196 0.33384E+04 68 hedenbergite 14.21 12.00 -2.21 -0.221 0.37756E+04 75 epidote 24.67 24.52 -0.15 -0.007 0.25708E+03 76 clinozoisite 22.81 20.26 -2.55 -0.116 0.43511E+04 77 epidote-Fe 29.84 28.78 -1.06 -0.055 0.18097E+04 78 fayalite 14.05 9.80 -4.24 -0.606 0.72481E+04 79 ferrosilite 11.15 6.41 -4.74 -0.474 0.80963E+04 83 gibbsite 4.08 2.02 -2.06 -0.294 0.35137E+04 84 glaucophane 22.97 18.92 -4.05 -0.109 0.69160E+04 87 greenalite 16.14 13.00 -3.13 -0.261 0.53526E+04 91 heulandite -5.83 -7.52 -1.69 -0.077 0.28938E+04 95 jadeite 4.22 3.01 -1.21 -0.121 0.20594E+04 96 julgoldite 70.43 66.71 -3.71 -0.096 0.63418E+04 97 kalsilite 7.58 4.30 -3.28 -0.469 0.56079E+04 98 kaolinite -1.33 -2.74 -1.41 -0.128 0.24081E+04 99 kyanite 4.88 0.65 -4.23 -0.423 0.72161E+04 101 laumontite 2.88 2.66 -0.23 -0.015 0.38652E+03 102 lawsonite 9.62 9.44 -0.17 -0.012 0.29534E+03 103 leucite 4.12 0.91 -3.21 -0.321 0.54850E+04 105 lizardite 23.24 19.69 -3.55 -0.296 0.60645E+04 107 magnetite 20.09 19.16 -0.92 -0.075 0.15782E+04 108 minnesotaite 10.39 6.22 -4.17 -0.245 0.71193E+04 110 magnesioferrite 26.21 21.39 -4.82 -0.393 0.82303E+04 113 margarite 17.32 13.49 -3.84 -0.154 0.65525E+04 120 muscovite 2.58 1.56 -1.03 -0.060 0.17518E+04 121 paragonite 4.24 3.66 -0.58 -0.034 0.99088E+03 122 nepheline 8.34 6.40 -1.94 -0.277 0.33078E+04 134 phlogopite-Na 29.65 26.09 -3.55 -0.197 0.60658E+04 136 prehnite 19.37 18.24 -1.14 -0.067 0.19390E+04 138 pumpellyite-Fe 46.27 45.09 -1.18 -0.026 0.20123E+04 139 pumpellyite-Mg 48.99 47.32 -1.67 -0.037 0.28597E+04 145 pyroxmangite 7.40 5.33 -2.07 -0.413 0.35284E+04 146 pyrophyllite -6.18 -9.53 -3.35 -0.210 0.57258E+04 147 quartz -2.99 -3.39 -0.40 -0.135 0.68913E+03 152 rhodonite 7.45 5.33 -2.11 -0.423 0.36087E+04 153 sanidine -1.28 -2.49 -1.21 -0.093 0.20677E+04 156 sillimanite 5.26 0.65 -4.61 -0.461 0.78741E+04 164 stilpnomelane-Fe 13.02 12.72 -0.30 -0.009 0.50906E+03 165 stilpnomelane-Mg 27.44 23.86 -3.58 -0.107 0.61074E+04 171 talc 16.49 12.91 -3.59 -0.211 0.61214E+04 174 tephroite 18.09 14.06 -4.03 -0.575 0.68783E+04 177 topaz-H 4.62 0.65 -3.97 -0.361 0.67762E+04 178 tridymite -2.63 -3.39 -0.77 -0.256 0.13091E+04 187 wairakite 3.95 2.66 -1.29 -0.076 0.22085E+04 188 walstromite 11.51 8.79 -2.72 -0.543 0.46376E+04 189 wollastonite 10.46 8.79 -1.67 -0.334 0.28480E+04 190 pseudo-wollastonite 11.00 8.79 -2.21 -0.441 0.37679E+04 191 zoisite 22.85 20.26 -2.59 -0.118 0.44252E+04 192 akaganeite 7.75 6.28 -1.47 -0.318 0.25125E+04 193 beidellite-Ca -1.65 -5.73 -4.09 -0.253 0.69768E+04 195 beidellite-K -1.52 -5.87 -4.35 -0.266 0.74286E+04 196 beidellite-Mg -1.79 -6.29 -4.50 -0.278 0.76773E+04 197 beidellite-Na -1.34 -5.18 -3.83 -0.235 0.65478E+04 199 chalcedony -2.80 -3.39 -0.59 -0.197 0.10084E+04 201 montmorillonite-Ca -2.29 -5.27 -2.98 -0.184 0.50920E+04 202 montmorillonite-K -2.24 -5.41 -3.18 -0.194 0.54220E+04 203 montmorillonite-Mg -2.48 -5.83 -3.35 -0.207 0.57157E+04 204 montmorillonite-Na -2.04 -4.72 -2.68 -0.164 0.45769E+04 205 nontronite-Ca 3.21 2.79 -0.42 -0.027 0.72221E+03 206 nontronite-H 2.53 0.78 -1.75 -0.117 0.29912E+04 207 nontronite-K 3.34 2.65 -0.69 -0.044 0.11754E+04 208 nontronite-Mg 3.07 2.24 -0.84 -0.054 0.14300E+04 209 nontronite-Na 3.52 3.35 -0.17 -0.011 0.29627E+03 224 tobermorite 9.82 6.76 -3.06 -0.836 0.52334E+04 233 boehmite 4.41 2.02 -2.38 -0.397 0.40720E+04 235 ferrous-oxide 9.81 6.60 -3.21 -0.804 0.54890E+04 240 silica-amorphous -2.09 -3.39 -1.30 -0.434 0.22226E+04 242 an20ab80 2.02 1.58 -0.44 -0.034 0.74489E+03 243 an25ab75 2.65 2.07 -0.57 -0.044 0.97808E+03 244 an30ab70 3.28 2.56 -0.72 -0.055 0.12209E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 0.4000000 g Current total amount of reactant added: 12.7990000 g New total amount of reactant added: 13.1990000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.6626E-13 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 7 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 13.1990000 Water: Moles liquid = 0.5540E+02 kg liquid = 0.9980E+00 Moles total = 0.5534E+02 kg total = 0.9970E+00 Activity = 1.0000 Stoichiometric ionic strength = .4957645E-02 Osmotic coef. = 0.9625 True ionic strength = .8798782E-02 Chg. balance for total moles = 0.6626E-13 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.14598E-09 -9.8357 0.12833E-09 -9.8917 0.87908E+00 -0.0560 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13794E-03 -3.8603 0.12089E-03 -3.9176 0.87638E+00 -0.0573 4 SO4-- 0.25537E-04 -4.5928 0.15994E-04 -4.7960 0.62631E+00 -0.2032 5 HCO3- 0.67000E-05 -5.1739 0.58761E-05 -5.2309 0.87703E+00 -0.0570 6 HS- 0.75878E-12 -12.1199 0.66503E-12 -12.1772 0.87645E+00 -0.0573 7 Al+++ 0.62647E-27 -27.2031 0.22205E-27 -27.6535 0.35445E+00 -0.4504 8 H4SiO4 0.40455E-03 -3.3930 0.40455E-03 -3.3930 0.10000E+01 0.0000 9 Ca++ 0.40519E-07 -7.3923 0.25283E-07 -7.5972 0.62399E+00 -0.2048 10 Mg++ 0.17723E-10 -10.7515 0.11033E-10 -10.9573 0.62254E+00 -0.2058 11 Fe++ 0.10451E-12 -12.9808 0.65096E-13 -13.1864 0.62288E+00 -0.2056 12 K+ 0.68606E-04 -4.1636 0.60177E-04 -4.2206 0.87714E+00 -0.0569 13 Na+ 0.86977E-02 -2.0606 0.76219E-02 -2.1179 0.87631E+00 -0.0573 14 Mn++ 0.14038E-10 -10.8527 0.87476E-11 -11.0581 0.62314E+00 -0.2054 15 HPO4-- 0.42175E-06 -6.3749 0.26417E-06 -6.5781 0.62635E+00 -0.2032 16 HSiO3- 0.33588E-02 -2.4738 0.29436E-02 -2.5311 0.87638E+00 -0.0573 17 Ca(HSiO3)+ 0.19321E-08 -8.7140 0.16949E-08 -8.7709 0.87724E+00 -0.0569 18 Mg(HSiO3)+ 0.10493E-11 -11.9791 0.92045E-12 -12.0360 0.87724E+00 -0.0569 19 NaHSiO3,aq 0.36286E-03 -3.4403 0.36286E-03 -3.4403 0.10000E+01 0.0000 20 AlO+ 0.20911E-14 -14.6796 0.18344E-14 -14.7365 0.87724E+00 -0.0569 22 HAlO2,aq 0.28467E-08 -8.5457 0.28467E-08 -8.5457 0.10000E+01 0.0000 23 AlO2- 0.56082E-04 -4.2512 0.49104E-04 -4.3089 0.87557E+00 -0.0577 24 CH4,aq 0.23769E-18 -18.6240 0.23733E-18 -18.6246 0.99847E+00 -0.0007 29 CO,aq 0.65437E-19 -19.1842 0.65437E-19 -19.1842 0.10000E+01 0.0000 30 CO2,aq 0.16137E-08 -8.7922 0.16113E-08 -8.7928 0.99847E+00 -0.0007 31 CO3-2 0.63928E-05 -5.1943 0.39995E-05 -5.3980 0.62563E+00 -0.2037 32 CaCO3,aq 0.12679E-08 -8.8969 0.12679E-08 -8.8969 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.43230E-11 -11.3642 0.37923E-11 -11.4211 0.87724E+00 -0.0569 34 CaCl+ 0.56385E-11 -11.2488 0.49463E-11 -11.3057 0.87724E+00 -0.0569 35 CaCl2,aq 0.14206E-15 -15.8475 0.14206E-15 -15.8475 0.10000E+01 0.0000 36 CaOH+ 0.16007E-07 -7.7957 0.14042E-07 -7.8526 0.87724E+00 -0.0569 37 CaSO4,aq 0.12841E-09 -9.8914 0.12841E-09 -9.8914 0.10000E+01 0.0000 38 HCl,aq 0.28427E-14 -14.5463 0.28427E-14 -14.5463 0.10000E+01 0.0000 43 FeCl+ 0.14199E-16 -16.8477 0.12456E-16 -16.9046 0.87724E+00 -0.0569 46 FeO,aq 0.15363E-09 -9.8135 0.15363E-09 -9.8135 0.10000E+01 0.0000 47 FeOH+ 0.18823E-10 -10.7253 0.16512E-10 -10.7822 0.87724E+00 -0.0569 48 HFeO2- 0.14293E-07 -7.8449 0.12526E-07 -7.9022 0.87638E+00 -0.0573 49 FeO+ 0.11166E-14 -14.9521 0.97952E-15 -15.0090 0.87724E+00 -0.0569 51 FeO2- 0.13887E-07 -7.8574 0.12171E-07 -7.9147 0.87638E+00 -0.0573 52 HFeO2,aq 0.19864E-09 -9.7019 0.19864E-09 -9.7019 0.10000E+01 0.0000 53 H2,aq 0.16191E-08 -8.7907 0.16167E-08 -8.7914 0.99847E+00 -0.0007 54 KCl,aq 0.13185E-09 -9.8799 0.13185E-09 -9.8799 0.10000E+01 0.0000 55 KHSO4,aq 0.34922E-18 -18.4569 0.34922E-18 -18.4569 0.10000E+01 0.0000 56 KOH,aq 0.20026E-06 -6.6984 0.20026E-06 -6.6984 0.10000E+01 0.0000 57 KSO4- 0.17042E-07 -7.7685 0.14935E-07 -7.8258 0.87638E+00 -0.0573 58 MgCO3,aq 0.13869E-12 -12.8580 0.13869E-12 -12.8580 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.19276E-14 -14.7150 0.16910E-14 -14.7719 0.87724E+00 -0.0569 60 MgCl+ 0.22300E-14 -14.6517 0.19563E-14 -14.7086 0.87724E+00 -0.0569 61 MgOH+ 0.38651E-10 -10.4128 0.33906E-10 -10.4697 0.87724E+00 -0.0569 63 MnO,aq 0.55009E-09 -9.2596 0.55009E-09 -9.2596 0.10000E+01 0.0000 64 MnOH+ 0.23497E-09 -9.6290 0.20613E-09 -9.6859 0.87724E+00 -0.0569 65 MnO2-2 0.17719E-11 -11.7516 0.11086E-11 -11.9552 0.62563E+00 -0.2037 66 HMnO2- 0.35563E-10 -10.4490 0.31167E-10 -10.5063 0.87638E+00 -0.0573 69 MnCl+ 0.74231E-14 -14.1294 0.65119E-14 -14.1863 0.87724E+00 -0.0569 70 MnSO4,aq 0.40391E-13 -13.3937 0.40391E-13 -13.3937 0.10000E+01 0.0000 71 NaCl,aq 0.30535E-06 -6.5152 0.30535E-06 -6.5152 0.10000E+01 0.0000 72 NaOH,aq 0.25518E-04 -4.5931 0.25518E-04 -4.5931 0.10000E+01 0.0000 74 OH- 0.51421E-02 -2.2889 0.45023E-02 -2.3466 0.87557E+00 -0.0577 79 HPO3-2 0.21273E-17 -17.6722 0.13309E-17 -17.8759 0.62563E+00 -0.2037 82 H3PO4,aq 0.30426E-16 -16.5168 0.30426E-16 -16.5168 0.10000E+01 0.0000 83 H2PO4- 0.71323E-09 -9.1468 0.62536E-09 -9.2039 0.87680E+00 -0.0571 84 PO4-3 0.46215E-08 -8.3352 0.16795E-08 -8.7748 0.36342E+00 -0.4396 87 H2P2O7-2 0.49014E-19 -19.3097 0.30665E-19 -19.5134 0.62563E+00 -0.2037 88 HP2O7-3 0.13456E-15 -15.8711 0.47713E-16 -16.3214 0.35459E+00 -0.4503 89 P2O7-4 0.54596E-15 -15.2628 0.88823E-16 -16.0515 0.16269E+00 -0.7886 90 H2S,aq 0.26416E-15 -15.5781 0.26376E-15 -15.5788 0.99847E+00 -0.0007 97 SO3-2 0.53316E-14 -14.2731 0.33601E-14 -14.4736 0.63024E+00 -0.2005 98 HSO3- 0.30807E-16 -16.5114 0.26999E-16 -16.5687 0.87638E+00 -0.0573 99 HSO4- 0.22538E-11 -11.6471 0.19780E-11 -11.7038 0.87766E+00 -0.0567 Charge balance for all species = 0.6514E-13 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.1459811E-09 -.9120306E-02 -.9186892E+01 0.0000 2 H2O 0.1000000E+01 0.5550981E+02 0.9993917E+06 0.0000 3 Cl- 0.1379390E-03 0.1382445E-03 0.4898075E+01 5.9741 4 SO4-- 0.2553727E-04 0.2555580E-04 0.2453374E+01 14.9873 5 HCO3- 0.6699955E-05 0.1309561E-04 0.7985507E+00 4.6608 6 HS- 0.7587788E-12 -.1355214E-08 -.4479121E-04 -2.2855 7 Al+++ 0.6264741E-27 0.5608473E-04 0.1512291E+01 2.0215 8 H4SiO4 0.4045468E-03 0.4126168E-02 0.3963368E+03 -3.3930 9 Ca++ 0.4051905E-07 0.5986400E-07 0.2397708E-02 12.1862 10 Mg++ 0.1772272E-10 0.5756554E-10 0.1398646E-05 8.8260 11 Fe++ 0.1045083E-12 0.2855152E-07 0.1593505E-02 6.5969 12 K+ 0.6860614E-04 0.6882358E-04 0.2689433E+01 5.6711 13 Na+ 0.8697670E-02 0.9086354E-02 0.2087610E+03 7.7737 14 Mn++ 0.1403787E-10 0.8364844E-09 0.4592564E-04 8.7252 15 HPO4-- 0.4217520E-06 0.4270867E-06 0.4096536E-01 13.2052 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.2185428E+00 -.9102471E-02 -.2094403E+00 0.0000000E+00 2 H2O 0.5534280E+02 0.5540126E+02 -.5846244E-01 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.3912938E-03 0.2550582E-04 0.3657879E-03 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.3657893E-03 -.1352564E-08 -.3657879E-03 0.0000000E+00 7 Al+++ 0.4303853E-01 0.5597506E-04 0.4298255E-01 0.0000000E+00 8 H4SiO4 0.1374383E+00 0.4118099E-02 0.1333202E+00 0.0000000E+00 9 Ca++ 0.1519520E-01 0.5974693E-07 0.1519514E-01 0.0000000E+00 10 Mg++ 0.1047540E-01 0.5745297E-10 0.1047540E-01 0.0000000E+00 11 Fe++ 0.9411000E-02 0.2849568E-07 0.9410972E-02 0.0000000E+00 12 K+ 0.2802335E-02 0.6868899E-04 0.2733646E-02 0.0000000E+00 13 Na+ 0.1672803E-01 0.9068586E-02 0.7659446E-02 0.0000000E+00 14 Mn++ 0.2288521E-03 0.8348487E-09 0.2288513E-03 0.0000000E+00 15 HPO4-- 0.7810609E-04 0.4262516E-06 0.7767984E-04 0.0000000E+00 Chg. balance for solid moles: 0.1637E-16 Mass of aqueous solution: 0.998678E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 13.1990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 0.7659E-02 -2.116 2.008 0.303 13.92 0.7710 andradite 0.6843E-03 -3.165 0.3477 -0.459 2.411 0.9034E-01 grossular 0.5156E-04 -4.288 0.2322E-01 -1.634 0.1610 0.6462E-02 apatite-OH 0.2589E-04 -4.587 0.1301E-01 -1.886 0.9017E-01 0.4133E-02 clinochlore 0.2095E-02 -2.679 1.165 0.066 8.073 0.4429 daphnite 0.1297E-02 -2.887 0.9254 -0.034 6.415 0.2804 chlorite-Mn 0.4577E-04 -4.339 0.3245E-01 -1.489 0.2250 0.1034E-01 hematite 0.7613E-03 -3.118 0.1216 -0.915 0.8428 0.2304E-01 microcline 0.2734E-02 -2.563 0.7609 -0.119 5.275 0.2972 prehnite-Fe 0.3521E-04 -4.453 0.1554E-01 -1.809 0.1077 0.5212E-02 stilbite 0.1279E-01 -1.893 9.012 0.955 62.48 4.203 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.9299E+00 0.9299E+00 1.0000 -0.032 grossular 0.7007E-01 0.7007E-01 1.0000 -1.154 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.6094E+00 0.6094E+00 1.0000 -0.215 daphnite 0.3773E+00 0.3773E+00 1.0000 -0.423 chlorite-Mn 0.1331E-01 0.1331E-01 1.0000 -1.876 hematite 0.1000E+01 0.1000E+01 1.0000 0.000 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 prehnite-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 14.424558 g Volume = 6.134388 cm3 Porosity: 2.3124% V(tot) - V(min): 0.14521E+00 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 13.1990000 g log = 1.1205 Original solution: 1000.0103000 g Original solution / Rock added: 75.76 (Water/Rock Ratio), log = 1.8795 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0203 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.1000E+01 0.9860 0.1006E+01 0.1020E+01 CO2,gas 0.1678E-06 1.0071 0.1724E-06 0.1712E-06 CH4,gas 0.3381E-15 1.0125 0.3493E-15 0.3450E-15 H2,gas 0.2079E-05 1.0005 0.2123E-05 0.2121E-05 H2S,gas 0.7135E-14 0.9960 0.7251E-14 0.7279E-14 S2,gas 0.4293E-36 1.0000 0.4380E-36 0.4380E-36 CO,gas 0.9557E-16 1.0000 0.9751E-16 0.9751E-16 SO3,gas 0.9761E-40 1.0000 0.9959E-40 0.9959E-40 SO2,gas 0.8060E-23 1.0000 0.8224E-23 0.8224E-23 HCl,gas 0.4916E-17 1.0000 0.5016E-17 0.5016E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 16 albite -0.38 -0.38 0.00 0.000 -0.13080E-10 22 andradite 39.01 39.01 0.00 0.000 0.00000E+00 23 grossular 32.73 32.73 0.00 0.000 -0.12132E-10 32 apatite-OH -18.15 -18.15 0.00 0.000 -0.60662E-11 46 clinochlore 39.07 39.07 0.00 0.000 -0.36397E-10 47 daphnite 28.97 28.97 0.00 0.000 -0.18198E-10 48 chlorite-Mn 46.87 46.87 0.00 0.000 -0.60662E-10 90 hematite 12.57 12.57 0.00 0.000 0.30331E-11 116 microcline -2.49 -2.49 0.00 0.000 -0.10616E-10 137 prehnite-Fe 22.50 22.50 0.00 0.000 -0.24265E-10 163 stilbite -7.52 -7.52 0.00 0.000 -0.33364E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -15.12 -8.46 -2.821 0.14449E+05 -6.763 3 CH4,gas 4.54 -12.61 -17.16 -4.289 0.29293E+05 -15.457 4 H2,gas 8.00 0.63 -7.37 -4.213 0.12588E+05 -5.673 5 H2S,gas -6.23 -22.07 -15.84 -7.919 0.27044E+05 -14.140 6 S2,gas -7.34 -45.39 -38.06 -5.855 0.64982E+05 -36.358 7 CO,gas 3.21 -14.49 -17.71 -5.449 0.30239E+05 -16.011 8 SO3,gas 17.12 -24.58 -41.70 -10.425 0.71203E+05 -40.002 9 SO2,gas 0.83 -23.95 -24.78 -6.609 0.42318E+05 -23.085 10 HCl,gas 5.19 -13.81 -19.00 -9.499 0.32440E+05 -17.300 11 acmite 7.71 7.27 -0.44 -0.046 0.74949E+03 15 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 19 spessartine 24.46 20.04 -4.42 -0.221 0.75431E+04 20 analcite 3.32 3.01 -0.31 -0.035 0.53392E+03 21 andalusite 5.00 0.65 -4.35 -0.435 0.74302E+04 26 annite 20.12 17.30 -2.82 -0.157 0.48136E+04 27 phlogopite 27.06 23.99 -3.07 -0.171 0.52470E+04 29 anorthite 12.71 9.44 -3.27 -0.251 0.55787E+04 35 aragonite 0.97 -2.94 -3.90 -1.301 0.66641E+04 36 brucite 12.57 8.83 -3.74 -0.749 0.63902E+04 37 calcite 0.81 -2.94 -3.75 -1.249 0.63999E+04 38 carnegieite-low 9.02 6.40 -2.62 -0.374 0.44755E+04 39 carnegieite-high 10.09 6.40 -3.69 -0.527 0.63025E+04 40 carpholite-Mg 8.58 6.08 -2.50 -0.167 0.42672E+04 41 carpholite-Fe 6.71 3.85 -2.86 -0.191 0.48813E+04 42 celadonite 5.34 2.95 -2.40 -0.141 0.40895E+04 43 celadonite-Fe 3.88 0.72 -3.16 -0.186 0.53941E+04 44 chrysotile 23.89 19.69 -4.20 -0.350 0.71719E+04 50 chloritoid-Mg 13.20 9.48 -3.72 -0.248 0.63547E+04 51 chloritoid-Fe 9.17 7.25 -1.93 -0.128 0.32899E+04 52 chloritoid-Mn 11.40 9.38 -2.03 -0.135 0.34591E+04 54 coesite -2.38 -3.39 -1.02 -0.339 0.17364E+04 59 corundum 8.38 4.04 -4.34 -0.395 0.74107E+04 61 cristobalite -2.56 -3.39 -0.83 -0.278 0.14218E+04 63 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71234E+04 65 diaspore 2.87 2.02 -0.85 -0.142 0.14551E+04 67 diopside 16.18 14.23 -1.96 -0.196 0.33384E+04 68 hedenbergite 14.21 12.00 -2.21 -0.221 0.37756E+04 75 epidote 24.67 24.52 -0.15 -0.007 0.25708E+03 76 clinozoisite 22.81 20.26 -2.55 -0.116 0.43511E+04 77 epidote-Fe 29.84 28.78 -1.06 -0.055 0.18097E+04 78 fayalite 14.05 9.80 -4.24 -0.606 0.72481E+04 79 ferrosilite 11.15 6.41 -4.74 -0.474 0.80963E+04 83 gibbsite 4.08 2.02 -2.06 -0.294 0.35137E+04 84 glaucophane 22.97 18.92 -4.05 -0.109 0.69160E+04 87 greenalite 16.14 13.00 -3.13 -0.261 0.53526E+04 91 heulandite -5.83 -7.52 -1.69 -0.077 0.28938E+04 95 jadeite 4.22 3.01 -1.21 -0.121 0.20594E+04 96 julgoldite 70.43 66.71 -3.71 -0.096 0.63418E+04 97 kalsilite 7.58 4.30 -3.28 -0.469 0.56079E+04 98 kaolinite -1.33 -2.74 -1.41 -0.128 0.24081E+04 99 kyanite 4.88 0.65 -4.23 -0.423 0.72161E+04 101 laumontite 2.88 2.66 -0.23 -0.015 0.38652E+03 102 lawsonite 9.62 9.44 -0.17 -0.012 0.29534E+03 103 leucite 4.12 0.91 -3.21 -0.321 0.54850E+04 105 lizardite 23.24 19.69 -3.55 -0.296 0.60645E+04 107 magnetite 20.09 19.16 -0.92 -0.075 0.15782E+04 108 minnesotaite 10.39 6.22 -4.17 -0.245 0.71193E+04 110 magnesioferrite 26.21 21.39 -4.82 -0.393 0.82303E+04 113 margarite 17.32 13.49 -3.84 -0.154 0.65525E+04 120 muscovite 2.58 1.56 -1.03 -0.060 0.17518E+04 121 paragonite 4.24 3.66 -0.58 -0.034 0.99088E+03 122 nepheline 8.34 6.40 -1.94 -0.277 0.33078E+04 134 phlogopite-Na 29.65 26.09 -3.55 -0.197 0.60658E+04 136 prehnite 19.37 18.24 -1.14 -0.067 0.19390E+04 138 pumpellyite-Fe 46.27 45.09 -1.18 -0.026 0.20123E+04 139 pumpellyite-Mg 48.99 47.32 -1.67 -0.037 0.28597E+04 145 pyroxmangite 7.40 5.33 -2.07 -0.413 0.35284E+04 146 pyrophyllite -6.18 -9.53 -3.35 -0.210 0.57258E+04 147 quartz -2.99 -3.39 -0.40 -0.135 0.68913E+03 152 rhodonite 7.45 5.33 -2.11 -0.423 0.36087E+04 153 sanidine -1.28 -2.49 -1.21 -0.093 0.20677E+04 156 sillimanite 5.26 0.65 -4.61 -0.461 0.78741E+04 164 stilpnomelane-Fe 13.02 12.72 -0.30 -0.009 0.50906E+03 165 stilpnomelane-Mg 27.44 23.86 -3.58 -0.107 0.61074E+04 171 talc 16.49 12.91 -3.59 -0.211 0.61214E+04 174 tephroite 18.09 14.06 -4.03 -0.575 0.68783E+04 177 topaz-H 4.62 0.65 -3.97 -0.361 0.67762E+04 178 tridymite -2.63 -3.39 -0.77 -0.256 0.13091E+04 187 wairakite 3.95 2.66 -1.29 -0.076 0.22085E+04 188 walstromite 11.51 8.79 -2.72 -0.543 0.46376E+04 189 wollastonite 10.46 8.79 -1.67 -0.334 0.28480E+04 190 pseudo-wollastonite 11.00 8.79 -2.21 -0.441 0.37679E+04 191 zoisite 22.85 20.26 -2.59 -0.118 0.44252E+04 192 akaganeite 7.75 6.28 -1.47 -0.318 0.25125E+04 193 beidellite-Ca -1.65 -5.73 -4.09 -0.253 0.69768E+04 195 beidellite-K -1.52 -5.87 -4.35 -0.266 0.74286E+04 196 beidellite-Mg -1.79 -6.29 -4.50 -0.278 0.76773E+04 197 beidellite-Na -1.34 -5.18 -3.83 -0.235 0.65478E+04 199 chalcedony -2.80 -3.39 -0.59 -0.197 0.10084E+04 201 montmorillonite-Ca -2.29 -5.27 -2.98 -0.184 0.50920E+04 202 montmorillonite-K -2.24 -5.41 -3.18 -0.194 0.54220E+04 203 montmorillonite-Mg -2.48 -5.83 -3.35 -0.207 0.57157E+04 204 montmorillonite-Na -2.04 -4.72 -2.68 -0.164 0.45769E+04 205 nontronite-Ca 3.21 2.79 -0.42 -0.027 0.72221E+03 206 nontronite-H 2.53 0.78 -1.75 -0.117 0.29912E+04 207 nontronite-K 3.34 2.65 -0.69 -0.044 0.11754E+04 208 nontronite-Mg 3.07 2.24 -0.84 -0.054 0.14300E+04 209 nontronite-Na 3.52 3.35 -0.17 -0.011 0.29627E+03 224 tobermorite 9.82 6.76 -3.06 -0.836 0.52334E+04 233 boehmite 4.41 2.02 -2.38 -0.397 0.40720E+04 235 ferrous-oxide 9.81 6.60 -3.21 -0.804 0.54890E+04 240 silica-amorphous -2.09 -3.39 -1.30 -0.434 0.22226E+04 242 an20ab80 2.02 1.58 -0.44 -0.034 0.74489E+03 243 an25ab75 2.65 2.07 -0.57 -0.044 0.97808E+03 244 an30ab70 3.28 2.56 -0.72 -0.055 0.12209E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 0.4000000 g Current total amount of reactant added: 13.1990000 g New total amount of reactant added: 13.5990000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.6620E-13 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 7 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 13.5990000 Water: Moles liquid = 0.5540E+02 kg liquid = 0.9980E+00 Moles total = 0.5534E+02 kg total = 0.9969E+00 Activity = 1.0000 Stoichiometric ionic strength = .4957652E-02 Osmotic coef. = 0.9625 True ionic strength = .8798788E-02 Chg. balance for total moles = 0.6620E-13 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.14598E-09 -9.8357 0.12833E-09 -9.8917 0.87908E+00 -0.0560 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13794E-03 -3.8603 0.12089E-03 -3.9176 0.87638E+00 -0.0573 4 SO4-- 0.25538E-04 -4.5928 0.15995E-04 -4.7960 0.62631E+00 -0.2032 5 HCO3- 0.67002E-05 -5.1739 0.58763E-05 -5.2309 0.87703E+00 -0.0570 6 HS- 0.75881E-12 -12.1199 0.66506E-12 -12.1771 0.87645E+00 -0.0573 7 Al+++ 0.62648E-27 -27.2031 0.22205E-27 -27.6535 0.35445E+00 -0.4504 8 H4SiO4 0.40455E-03 -3.3930 0.40455E-03 -3.3930 0.10000E+01 0.0000 9 Ca++ 0.40519E-07 -7.3923 0.25283E-07 -7.5972 0.62399E+00 -0.2048 10 Mg++ 0.17723E-10 -10.7515 0.11033E-10 -10.9573 0.62254E+00 -0.2058 11 Fe++ 0.10451E-12 -12.9808 0.65096E-13 -13.1864 0.62288E+00 -0.2056 12 K+ 0.68606E-04 -4.1636 0.60177E-04 -4.2206 0.87714E+00 -0.0569 13 Na+ 0.86977E-02 -2.0606 0.76219E-02 -2.1179 0.87631E+00 -0.0573 14 Mn++ 0.14038E-10 -10.8527 0.87476E-11 -11.0581 0.62314E+00 -0.2054 15 HPO4-- 0.42175E-06 -6.3749 0.26417E-06 -6.5781 0.62635E+00 -0.2032 16 HSiO3- 0.33588E-02 -2.4738 0.29435E-02 -2.5311 0.87638E+00 -0.0573 17 Ca(HSiO3)+ 0.19321E-08 -8.7140 0.16949E-08 -8.7709 0.87724E+00 -0.0569 18 Mg(HSiO3)+ 0.10493E-11 -11.9791 0.92045E-12 -12.0360 0.87724E+00 -0.0569 19 NaHSiO3,aq 0.36286E-03 -3.4403 0.36286E-03 -3.4403 0.10000E+01 0.0000 20 AlO+ 0.20911E-14 -14.6796 0.18344E-14 -14.7365 0.87724E+00 -0.0569 22 HAlO2,aq 0.28467E-08 -8.5457 0.28467E-08 -8.5457 0.10000E+01 0.0000 23 AlO2- 0.56082E-04 -4.2512 0.49104E-04 -4.3089 0.87557E+00 -0.0577 24 CH4,aq 0.23770E-18 -18.6240 0.23734E-18 -18.6246 0.99847E+00 -0.0007 29 CO,aq 0.65440E-19 -19.1842 0.65440E-19 -19.1842 0.10000E+01 0.0000 30 CO2,aq 0.16138E-08 -8.7922 0.16113E-08 -8.7928 0.99847E+00 -0.0007 31 CO3-2 0.63930E-05 -5.1943 0.39997E-05 -5.3980 0.62563E+00 -0.2037 32 CaCO3,aq 0.12680E-08 -8.8969 0.12680E-08 -8.8969 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.43232E-11 -11.3642 0.37925E-11 -11.4211 0.87724E+00 -0.0569 34 CaCl+ 0.56387E-11 -11.2488 0.49465E-11 -11.3057 0.87724E+00 -0.0569 35 CaCl2,aq 0.14207E-15 -15.8475 0.14207E-15 -15.8475 0.10000E+01 0.0000 36 CaOH+ 0.16007E-07 -7.7957 0.14042E-07 -7.8526 0.87724E+00 -0.0569 37 CaSO4,aq 0.12842E-09 -9.8914 0.12842E-09 -9.8914 0.10000E+01 0.0000 38 HCl,aq 0.28429E-14 -14.5462 0.28429E-14 -14.5462 0.10000E+01 0.0000 43 FeCl+ 0.14200E-16 -16.8477 0.12456E-16 -16.9046 0.87724E+00 -0.0569 46 FeO,aq 0.15363E-09 -9.8135 0.15363E-09 -9.8135 0.10000E+01 0.0000 47 FeOH+ 0.18823E-10 -10.7253 0.16512E-10 -10.7822 0.87724E+00 -0.0569 48 HFeO2- 0.14293E-07 -7.8449 0.12526E-07 -7.9022 0.87638E+00 -0.0573 49 FeO+ 0.11166E-14 -14.9521 0.97952E-15 -15.0090 0.87724E+00 -0.0569 51 FeO2- 0.13887E-07 -7.8574 0.12171E-07 -7.9147 0.87638E+00 -0.0573 52 HFeO2,aq 0.19864E-09 -9.7019 0.19864E-09 -9.7019 0.10000E+01 0.0000 53 H2,aq 0.16191E-08 -8.7907 0.16167E-08 -8.7914 0.99847E+00 -0.0007 54 KCl,aq 0.13185E-09 -9.8799 0.13185E-09 -9.8799 0.10000E+01 0.0000 55 KHSO4,aq 0.34924E-18 -18.4569 0.34924E-18 -18.4569 0.10000E+01 0.0000 56 KOH,aq 0.20026E-06 -6.6984 0.20026E-06 -6.6984 0.10000E+01 0.0000 57 KSO4- 0.17043E-07 -7.7685 0.14936E-07 -7.8258 0.87638E+00 -0.0573 58 MgCO3,aq 0.13869E-12 -12.8579 0.13869E-12 -12.8579 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.19277E-14 -14.7150 0.16910E-14 -14.7718 0.87724E+00 -0.0569 60 MgCl+ 0.22301E-14 -14.6517 0.19564E-14 -14.7086 0.87724E+00 -0.0569 61 MgOH+ 0.38651E-10 -10.4128 0.33906E-10 -10.4697 0.87724E+00 -0.0569 63 MnO,aq 0.55009E-09 -9.2596 0.55009E-09 -9.2596 0.10000E+01 0.0000 64 MnOH+ 0.23497E-09 -9.6290 0.20613E-09 -9.6859 0.87724E+00 -0.0569 65 MnO2-2 0.17719E-11 -11.7516 0.11086E-11 -11.9552 0.62563E+00 -0.2037 66 HMnO2- 0.35563E-10 -10.4490 0.31167E-10 -10.5063 0.87638E+00 -0.0573 69 MnCl+ 0.74235E-14 -14.1294 0.65121E-14 -14.1863 0.87724E+00 -0.0569 70 MnSO4,aq 0.40393E-13 -13.3937 0.40393E-13 -13.3937 0.10000E+01 0.0000 71 NaCl,aq 0.30536E-06 -6.5152 0.30536E-06 -6.5152 0.10000E+01 0.0000 72 NaOH,aq 0.25518E-04 -4.5931 0.25518E-04 -4.5931 0.10000E+01 0.0000 74 OH- 0.51421E-02 -2.2889 0.45023E-02 -2.3466 0.87557E+00 -0.0577 79 HPO3-2 0.21273E-17 -17.6722 0.13309E-17 -17.8759 0.62563E+00 -0.2037 82 H3PO4,aq 0.30426E-16 -16.5168 0.30426E-16 -16.5168 0.10000E+01 0.0000 83 H2PO4- 0.71323E-09 -9.1468 0.62536E-09 -9.2039 0.87680E+00 -0.0571 84 PO4-3 0.46215E-08 -8.3352 0.16795E-08 -8.7748 0.36342E+00 -0.4396 87 H2P2O7-2 0.49014E-19 -19.3097 0.30665E-19 -19.5134 0.62563E+00 -0.2037 88 HP2O7-3 0.13456E-15 -15.8711 0.47713E-16 -16.3214 0.35459E+00 -0.4503 89 P2O7-4 0.54596E-15 -15.2628 0.88823E-16 -16.0515 0.16269E+00 -0.7886 90 H2S,aq 0.26418E-15 -15.5781 0.26377E-15 -15.5788 0.99847E+00 -0.0007 97 SO3-2 0.53318E-14 -14.2731 0.33603E-14 -14.4736 0.63024E+00 -0.2005 98 HSO3- 0.30808E-16 -16.5113 0.27000E-16 -16.5686 0.87638E+00 -0.0573 99 HSO4- 0.22539E-11 -11.6471 0.19781E-11 -11.7037 0.87766E+00 -0.0567 Charge balance for all species = 0.6506E-13 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.1459812E-09 -.9120302E-02 -.9186888E+01 0.0000 2 H2O 0.1000000E+01 0.5550981E+02 0.9993917E+06 0.0000 3 Cl- 0.1379449E-03 0.1382504E-03 0.4898282E+01 5.9741 4 SO4-- 0.2553835E-04 0.2555688E-04 0.2453477E+01 14.9873 5 HCO3- 0.6700239E-05 0.1309616E-04 0.7985843E+00 4.6608 6 HS- 0.7588114E-12 -.1355213E-08 -.4479118E-04 -2.2855 7 Al+++ 0.6264753E-27 0.5608471E-04 0.1512290E+01 2.0215 8 H4SiO4 0.4045468E-03 0.4126166E-02 0.3963366E+03 -3.3930 9 Ca++ 0.4051909E-07 0.5986411E-07 0.2397712E-02 12.1862 10 Mg++ 0.1772274E-10 0.5756558E-10 0.1398647E-05 8.8260 11 Fe++ 0.1045084E-12 0.2855151E-07 0.1593505E-02 6.5969 12 K+ 0.6860618E-04 0.6882362E-04 0.2689434E+01 5.6711 13 Na+ 0.8697675E-02 0.9086359E-02 0.2087611E+03 7.7737 14 Mn++ 0.1403789E-10 0.8364846E-09 0.4592565E-04 8.7252 15 HPO4-- 0.4217517E-06 0.4270864E-06 0.4096533E-01 13.2052 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.2251662E+00 -.9102083E-02 -.2160641E+00 0.0000000E+00 2 H2O 0.5533778E+02 0.5539892E+02 -.6113995E-01 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.4023791E-03 0.2550582E-04 0.3768733E-03 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.3768746E-03 -.1352506E-08 -.3768733E-03 0.0000000E+00 7 Al+++ 0.4434283E-01 0.5597267E-04 0.4428685E-01 0.0000000E+00 8 H4SiO4 0.1416034E+00 0.4117924E-02 0.1374855E+00 0.0000000E+00 9 Ca++ 0.1565526E-01 0.5974453E-07 0.1565520E-01 0.0000000E+00 10 Mg++ 0.1079286E-01 0.5745059E-10 0.1079286E-01 0.0000000E+00 11 Fe++ 0.9696204E-02 0.2849447E-07 0.9696175E-02 0.0000000E+00 12 K+ 0.2887261E-02 0.6868613E-04 0.2818575E-02 0.0000000E+00 13 Na+ 0.1723013E-01 0.9068208E-02 0.8161921E-02 0.0000000E+00 14 Mn++ 0.2357876E-03 0.8348136E-09 0.2357867E-03 0.0000000E+00 15 HPO4-- 0.8047312E-04 0.4262332E-06 0.8004689E-04 0.0000000E+00 Chg. balance for solid moles: -.3193E-16 Mass of aqueous solution: 0.998636E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 13.5990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 0.8162E-02 -2.088 2.140 0.330 14.40 0.8216 andradite 0.7851E-03 -3.105 0.3990 -0.399 2.684 0.1037 grossular 0.5915E-04 -4.228 0.2665E-01 -1.574 0.1793 0.7414E-02 apatite-OH 0.2668E-04 -4.574 0.1340E-01 -1.873 0.9017E-01 0.4259E-02 clinochlore 0.2159E-02 -2.666 1.200 0.079 8.072 0.4564 daphnite 0.1336E-02 -2.874 0.9534 -0.021 6.415 0.2889 chlorite-Mn 0.4716E-04 -4.326 0.3343E-01 -1.476 0.2249 0.1065E-01 hematite 0.7434E-03 -3.129 0.1187 -0.925 0.7987 0.2250E-01 microcline 0.2819E-02 -2.550 0.7845 -0.105 5.278 0.3065 prehnite-Fe -.4199E-04 1.000 -.1853E-01 1.000 -.1247 -.6215E-02 stilbite 0.1307E-01 -1.884 9.213 0.964 61.98 4.297 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.9299E+00 0.9299E+00 1.0000 -0.032 grossular 0.7007E-01 0.7007E-01 1.0000 -1.154 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.6094E+00 0.6094E+00 1.0000 -0.215 daphnite 0.3773E+00 0.3773E+00 1.0000 -0.423 chlorite-Mn 0.1331E-01 0.1331E-01 1.0000 -1.876 hematite 0.1000E+01 0.1000E+01 1.0000 0.000 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 prehnite-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 14.863442 g Volume = 6.312624 cm3 Porosity: 1.9718% V(tot) - V(min): 0.12698E+00 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 13.5990000 g log = 1.1335 Original solution: 1000.0103000 g Original solution / Rock added: 73.54 (Water/Rock Ratio), log = 1.8665 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0203 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.1000E+01 0.9860 0.1006E+01 0.1020E+01 CO2,gas 0.1678E-06 1.0071 0.1724E-06 0.1712E-06 CH4,gas 0.3382E-15 1.0125 0.3493E-15 0.3450E-15 H2,gas 0.2079E-05 1.0005 0.2123E-05 0.2121E-05 H2S,gas 0.7135E-14 0.9960 0.7251E-14 0.7280E-14 S2,gas 0.4294E-36 1.0000 0.4381E-36 0.4381E-36 CO,gas 0.9558E-16 1.0000 0.9752E-16 0.9752E-16 SO3,gas 0.9761E-40 1.0000 0.9960E-40 0.9960E-40 SO2,gas 0.8061E-23 1.0000 0.8224E-23 0.8224E-23 HCl,gas 0.4917E-17 1.0000 0.5016E-17 0.5016E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 16 albite -0.38 -0.38 0.00 0.000 -0.13080E-10 22 andradite 39.01 39.01 0.00 0.000 0.12132E-10 23 grossular 32.73 32.73 0.00 0.000 -0.12132E-10 32 apatite-OH -18.15 -18.15 0.00 0.000 -0.60662E-11 46 clinochlore 39.07 39.07 0.00 0.000 -0.48529E-10 47 daphnite 28.97 28.97 0.00 0.000 -0.24265E-10 48 chlorite-Mn 46.87 46.87 0.00 0.000 -0.48529E-10 90 hematite 12.57 12.57 0.00 0.000 -0.30331E-11 116 microcline -2.49 -2.49 0.00 0.000 -0.22748E-10 163 stilbite -7.52 -7.52 0.00 0.000 -0.33364E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -15.12 -8.46 -2.821 0.14449E+05 -6.763 3 CH4,gas 4.54 -12.61 -17.16 -4.289 0.29293E+05 -15.457 4 H2,gas 8.00 0.63 -7.37 -4.213 0.12588E+05 -5.673 5 H2S,gas -6.23 -22.07 -15.84 -7.919 0.27044E+05 -14.140 6 S2,gas -7.34 -45.39 -38.06 -5.855 0.64982E+05 -36.358 7 CO,gas 3.21 -14.49 -17.71 -5.449 0.30239E+05 -16.011 8 SO3,gas 17.12 -24.58 -41.70 -10.425 0.71203E+05 -40.002 9 SO2,gas 0.83 -23.95 -24.78 -6.609 0.42318E+05 -23.085 10 HCl,gas 5.19 -13.81 -19.00 -9.499 0.32440E+05 -17.300 11 acmite 7.71 7.27 -0.44 -0.046 0.74949E+03 15 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 19 spessartine 24.46 20.04 -4.42 -0.221 0.75431E+04 20 analcite 3.32 3.01 -0.31 -0.035 0.53392E+03 21 andalusite 5.00 0.65 -4.35 -0.435 0.74302E+04 26 annite 20.12 17.30 -2.82 -0.157 0.48136E+04 27 phlogopite 27.06 23.99 -3.07 -0.171 0.52470E+04 29 anorthite 12.71 9.44 -3.27 -0.251 0.55787E+04 35 aragonite 0.97 -2.94 -3.90 -1.301 0.66641E+04 36 brucite 12.57 8.83 -3.74 -0.749 0.63902E+04 37 calcite 0.81 -2.94 -3.75 -1.249 0.63999E+04 38 carnegieite-low 9.02 6.40 -2.62 -0.374 0.44755E+04 39 carnegieite-high 10.09 6.40 -3.69 -0.527 0.63025E+04 40 carpholite-Mg 8.58 6.08 -2.50 -0.167 0.42672E+04 41 carpholite-Fe 6.71 3.85 -2.86 -0.191 0.48813E+04 42 celadonite 5.34 2.95 -2.40 -0.141 0.40895E+04 43 celadonite-Fe 3.88 0.72 -3.16 -0.186 0.53941E+04 44 chrysotile 23.89 19.69 -4.20 -0.350 0.71719E+04 50 chloritoid-Mg 13.20 9.48 -3.72 -0.248 0.63547E+04 51 chloritoid-Fe 9.17 7.25 -1.93 -0.128 0.32899E+04 52 chloritoid-Mn 11.40 9.38 -2.03 -0.135 0.34591E+04 54 coesite -2.38 -3.39 -1.02 -0.339 0.17364E+04 59 corundum 8.38 4.04 -4.34 -0.395 0.74107E+04 61 cristobalite -2.56 -3.39 -0.83 -0.278 0.14218E+04 63 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71234E+04 65 diaspore 2.87 2.02 -0.85 -0.142 0.14551E+04 67 diopside 16.18 14.23 -1.96 -0.196 0.33384E+04 68 hedenbergite 14.21 12.00 -2.21 -0.221 0.37756E+04 75 epidote 24.67 24.52 -0.15 -0.007 0.25708E+03 76 clinozoisite 22.81 20.26 -2.55 -0.116 0.43511E+04 77 epidote-Fe 29.84 28.78 -1.06 -0.055 0.18097E+04 78 fayalite 14.05 9.80 -4.24 -0.606 0.72481E+04 79 ferrosilite 11.15 6.41 -4.74 -0.474 0.80963E+04 83 gibbsite 4.08 2.02 -2.06 -0.294 0.35137E+04 84 glaucophane 22.97 18.92 -4.05 -0.109 0.69160E+04 87 greenalite 16.14 13.00 -3.13 -0.261 0.53526E+04 91 heulandite -5.83 -7.52 -1.69 -0.077 0.28938E+04 95 jadeite 4.22 3.01 -1.21 -0.121 0.20594E+04 96 julgoldite 70.43 66.71 -3.71 -0.096 0.63418E+04 97 kalsilite 7.58 4.30 -3.28 -0.469 0.56079E+04 98 kaolinite -1.33 -2.74 -1.41 -0.128 0.24081E+04 99 kyanite 4.88 0.65 -4.23 -0.423 0.72161E+04 101 laumontite 2.88 2.66 -0.23 -0.015 0.38652E+03 102 lawsonite 9.62 9.44 -0.17 -0.012 0.29534E+03 103 leucite 4.12 0.91 -3.21 -0.321 0.54850E+04 105 lizardite 23.24 19.69 -3.55 -0.296 0.60645E+04 107 magnetite 20.09 19.16 -0.92 -0.075 0.15782E+04 108 minnesotaite 10.39 6.22 -4.17 -0.245 0.71193E+04 110 magnesioferrite 26.21 21.39 -4.82 -0.393 0.82303E+04 113 margarite 17.32 13.49 -3.84 -0.154 0.65525E+04 120 muscovite 2.58 1.56 -1.03 -0.060 0.17518E+04 121 paragonite 4.24 3.66 -0.58 -0.034 0.99088E+03 122 nepheline 8.34 6.40 -1.94 -0.277 0.33078E+04 134 phlogopite-Na 29.65 26.09 -3.55 -0.197 0.60658E+04 136 prehnite 19.37 18.24 -1.14 -0.067 0.19390E+04 137 prehnite-Fe 22.50 22.50 0.00 0.000 -0.24265E-10 138 pumpellyite-Fe 46.27 45.09 -1.18 -0.026 0.20123E+04 139 pumpellyite-Mg 48.99 47.32 -1.67 -0.037 0.28597E+04 145 pyroxmangite 7.40 5.33 -2.07 -0.413 0.35284E+04 146 pyrophyllite -6.18 -9.53 -3.35 -0.210 0.57258E+04 147 quartz -2.99 -3.39 -0.40 -0.135 0.68913E+03 152 rhodonite 7.45 5.33 -2.11 -0.423 0.36087E+04 153 sanidine -1.28 -2.49 -1.21 -0.093 0.20677E+04 156 sillimanite 5.26 0.65 -4.61 -0.461 0.78741E+04 164 stilpnomelane-Fe 13.02 12.72 -0.30 -0.009 0.50906E+03 165 stilpnomelane-Mg 27.44 23.86 -3.58 -0.107 0.61074E+04 171 talc 16.49 12.91 -3.59 -0.211 0.61214E+04 174 tephroite 18.09 14.06 -4.03 -0.575 0.68783E+04 177 topaz-H 4.62 0.65 -3.97 -0.361 0.67762E+04 178 tridymite -2.63 -3.39 -0.77 -0.256 0.13091E+04 187 wairakite 3.95 2.66 -1.29 -0.076 0.22085E+04 188 walstromite 11.51 8.79 -2.72 -0.543 0.46376E+04 189 wollastonite 10.46 8.79 -1.67 -0.334 0.28480E+04 190 pseudo-wollastonite 11.00 8.79 -2.21 -0.441 0.37679E+04 191 zoisite 22.85 20.26 -2.59 -0.118 0.44252E+04 192 akaganeite 7.75 6.28 -1.47 -0.318 0.25125E+04 193 beidellite-Ca -1.65 -5.73 -4.09 -0.253 0.69768E+04 195 beidellite-K -1.52 -5.87 -4.35 -0.266 0.74286E+04 196 beidellite-Mg -1.79 -6.29 -4.50 -0.278 0.76773E+04 197 beidellite-Na -1.34 -5.18 -3.83 -0.235 0.65478E+04 199 chalcedony -2.80 -3.39 -0.59 -0.197 0.10084E+04 201 montmorillonite-Ca -2.29 -5.27 -2.98 -0.184 0.50920E+04 202 montmorillonite-K -2.24 -5.41 -3.18 -0.194 0.54220E+04 203 montmorillonite-Mg -2.48 -5.83 -3.35 -0.207 0.57157E+04 204 montmorillonite-Na -2.04 -4.72 -2.68 -0.164 0.45769E+04 205 nontronite-Ca 3.21 2.79 -0.42 -0.027 0.72221E+03 206 nontronite-H 2.53 0.78 -1.75 -0.117 0.29912E+04 207 nontronite-K 3.34 2.65 -0.69 -0.044 0.11754E+04 208 nontronite-Mg 3.07 2.24 -0.84 -0.054 0.14300E+04 209 nontronite-Na 3.52 3.35 -0.17 -0.011 0.29627E+03 224 tobermorite 9.82 6.76 -3.06 -0.836 0.52334E+04 233 boehmite 4.41 2.02 -2.38 -0.397 0.40720E+04 235 ferrous-oxide 9.81 6.60 -3.21 -0.804 0.54890E+04 240 silica-amorphous -2.09 -3.39 -1.30 -0.434 0.22226E+04 242 an20ab80 2.02 1.58 -0.44 -0.034 0.74489E+03 243 an25ab75 2.65 2.07 -0.57 -0.044 0.97808E+03 244 an30ab70 3.28 2.56 -0.72 -0.055 0.12209E+04 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 9 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 13.5990000 Water: Moles liquid = 0.5540E+02 kg liquid = 0.9980E+00 Moles total = 0.5534E+02 kg total = 0.9969E+00 Activity = 1.0000 Stoichiometric ionic strength = .4963501E-02 Osmotic coef. = 0.9624 True ionic strength = .8826965E-02 Chg. balance for total moles = 0.6620E-13 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.14631E-09 -9.8347 0.12859E-09 -9.8908 0.87894E+00 -0.0560 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13794E-03 -3.8603 0.12087E-03 -3.9177 0.87624E+00 -0.0574 4 SO4-- 0.25538E-04 -4.5928 0.15985E-04 -4.7963 0.62591E+00 -0.2035 5 HCO3- 0.67055E-05 -5.1736 0.58800E-05 -5.2306 0.87689E+00 -0.0571 6 HS- 0.81490E-12 -12.0889 0.71410E-12 -12.1462 0.87630E+00 -0.0573 7 Al+++ 0.60496E-27 -27.2183 0.21412E-27 -27.6693 0.35394E+00 -0.4511 8 H4SiO4 0.41020E-03 -3.3870 0.41020E-03 -3.3870 0.10000E+01 0.0000 9 Ca++ 0.40231E-07 -7.3954 0.25088E-07 -7.6005 0.62359E+00 -0.2051 10 Mg++ 0.17964E-10 -10.7456 0.11176E-10 -10.9517 0.62214E+00 -0.2061 11 Fe++ 0.10593E-12 -12.9750 0.65939E-13 -13.1809 0.62248E+00 -0.2059 12 K+ 0.68827E-04 -4.1622 0.60361E-04 -4.2192 0.87700E+00 -0.0570 13 Na+ 0.87256E-02 -2.0592 0.76451E-02 -2.1166 0.87617E+00 -0.0574 14 Mn++ 0.14229E-10 -10.8468 0.88608E-11 -11.0525 0.62275E+00 -0.2057 15 HPO4-- 0.42870E-06 -6.3678 0.26835E-06 -6.5713 0.62596E+00 -0.2035 16 HSiO3- 0.33992E-02 -2.4686 0.29785E-02 -2.5260 0.87624E+00 -0.0574 17 Ca(HSiO3)+ 0.19402E-08 -8.7122 0.17017E-08 -8.7691 0.87710E+00 -0.0570 18 Mg(HSiO3)+ 0.10756E-11 -11.9683 0.94343E-12 -12.0253 0.87710E+00 -0.0570 19 NaHSiO3,aq 0.36829E-03 -3.4338 0.36829E-03 -3.4338 0.10000E+01 0.0000 20 AlO+ 0.20084E-14 -14.6972 0.17615E-14 -14.7541 0.87710E+00 -0.0570 22 HAlO2,aq 0.27280E-08 -8.5642 0.27280E-08 -8.5642 0.10000E+01 0.0000 23 AlO2- 0.53641E-04 -4.2705 0.46959E-04 -4.3283 0.87543E+00 -0.0578 24 CH4,aq 0.25555E-18 -18.5925 0.25516E-18 -18.5932 0.99847E+00 -0.0007 29 CO,aq 0.66770E-19 -19.1754 0.66770E-19 -19.1754 0.10000E+01 0.0000 30 CO2,aq 0.16182E-08 -8.7910 0.16157E-08 -8.7916 0.99847E+00 -0.0007 31 CO3-2 0.63878E-05 -5.1946 0.39939E-05 -5.3986 0.62523E+00 -0.2040 32 CaCO3,aq 0.12564E-08 -8.9009 0.12564E-08 -8.9009 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.42931E-11 -11.3672 0.37655E-11 -11.4242 0.87710E+00 -0.0570 34 CaCl+ 0.55950E-11 -11.2522 0.49074E-11 -11.3092 0.87710E+00 -0.0570 35 CaCl2,aq 0.14092E-15 -15.8510 0.14092E-15 -15.8510 0.10000E+01 0.0000 36 CaOH+ 0.15852E-07 -7.7999 0.13904E-07 -7.8569 0.87710E+00 -0.0570 37 CaSO4,aq 0.12734E-09 -9.8950 0.12734E-09 -9.8950 0.10000E+01 0.0000 38 HCl,aq 0.28483E-14 -14.5454 0.28483E-14 -14.5454 0.10000E+01 0.0000 43 FeCl+ 0.14383E-16 -16.8421 0.12615E-16 -16.8991 0.87710E+00 -0.0570 46 FeO,aq 0.15497E-09 -9.8097 0.15497E-09 -9.8097 0.10000E+01 0.0000 47 FeOH+ 0.19030E-10 -10.7206 0.16691E-10 -10.7775 0.87710E+00 -0.0570 48 HFeO2- 0.14390E-07 -7.8419 0.12609E-07 -7.8993 0.87624E+00 -0.0574 49 FeO+ 0.11191E-14 -14.9511 0.98155E-15 -15.0081 0.87710E+00 -0.0570 51 FeO2- 0.13861E-07 -7.8582 0.12145E-07 -7.9156 0.87624E+00 -0.0574 52 HFeO2,aq 0.19864E-09 -9.7019 0.19864E-09 -9.7019 0.10000E+01 0.0000 53 H2,aq 0.16476E-08 -8.7831 0.16451E-08 -8.7838 0.99847E+00 -0.0007 54 KCl,aq 0.13223E-09 -9.8787 0.13223E-09 -9.8787 0.10000E+01 0.0000 55 KHSO4,aq 0.35081E-18 -18.4549 0.35081E-18 -18.4549 0.10000E+01 0.0000 56 KOH,aq 0.20046E-06 -6.6980 0.20046E-06 -6.6980 0.10000E+01 0.0000 57 KSO4- 0.17087E-07 -7.7673 0.14972E-07 -7.8247 0.87624E+00 -0.0574 58 MgCO3,aq 0.14029E-12 -12.8530 0.14029E-12 -12.8530 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.19542E-14 -14.7090 0.17140E-14 -14.7660 0.87710E+00 -0.0570 60 MgCl+ 0.22590E-14 -14.6461 0.19814E-14 -14.7030 0.87710E+00 -0.0570 61 MgOH+ 0.39076E-10 -10.4081 0.34274E-10 -10.4650 0.87710E+00 -0.0570 63 MnO,aq 0.55491E-09 -9.2558 0.55491E-09 -9.2558 0.10000E+01 0.0000 64 MnOH+ 0.23756E-09 -9.6242 0.20836E-09 -9.6812 0.87710E+00 -0.0570 65 MnO2-2 0.17811E-11 -11.7493 0.11136E-11 -11.9533 0.62523E+00 -0.2040 66 HMnO2- 0.35806E-10 -10.4460 0.31375E-10 -10.5034 0.87624E+00 -0.0574 69 MnCl+ 0.75195E-14 -14.1238 0.65953E-14 -14.1808 0.87710E+00 -0.0570 70 MnSO4,aq 0.40890E-13 -13.3884 0.40890E-13 -13.3884 0.10000E+01 0.0000 71 NaCl,aq 0.30624E-06 -6.5139 0.30624E-06 -6.5139 0.10000E+01 0.0000 72 NaOH,aq 0.25543E-04 -4.5927 0.25543E-04 -4.5927 0.10000E+01 0.0000 74 OH- 0.51323E-02 -2.2897 0.44930E-02 -2.3475 0.87543E+00 -0.0578 79 HPO3-2 0.22004E-17 -17.6575 0.13758E-17 -17.8615 0.62523E+00 -0.2040 82 H3PO4,aq 0.31037E-16 -16.5081 0.31037E-16 -16.5081 0.10000E+01 0.0000 83 H2PO4- 0.72616E-09 -9.1390 0.63659E-09 -9.1961 0.87666E+00 -0.0572 84 PO4-3 0.46914E-08 -8.3287 0.17026E-08 -8.7689 0.36292E+00 -0.4402 87 H2P2O7-2 0.50822E-19 -19.2939 0.31776E-19 -19.4979 0.62523E+00 -0.2040 88 HP2O7-3 0.13935E-15 -15.8559 0.49340E-16 -16.3068 0.35408E+00 -0.4509 89 P2O7-4 0.56482E-15 -15.2481 0.91661E-16 -16.0378 0.16228E+00 -0.7897 90 H2S,aq 0.28425E-15 -15.5463 0.28381E-15 -15.5470 0.99847E+00 -0.0007 97 SO3-2 0.54254E-14 -14.2656 0.34172E-14 -14.4663 0.62985E+00 -0.2008 98 HSO3- 0.31400E-16 -16.5031 0.27514E-16 -16.5604 0.87624E+00 -0.0574 99 HSO4- 0.22575E-11 -11.6464 0.19810E-11 -11.7031 0.87753E+00 -0.0567 Charge balance for all species = 0.6551E-13 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.1463063E-09 -.9146594E-02 -.9213330E+01 0.0000 2 H2O 0.1000000E+01 0.5550975E+02 0.9993861E+06 0.0000 3 Cl- 0.1379442E-03 0.1382506E-03 0.4898266E+01 5.9731 4 SO4-- 0.2553834E-04 0.2555690E-04 0.2453469E+01 14.9853 5 HCO3- 0.6705489E-05 0.1309618E-04 0.7985819E+00 4.6602 6 HS- 0.8149009E-12 -.1344725E-08 -.4444434E-04 -2.2555 7 Al+++ 0.6049617E-27 0.5364360E-04 0.1446460E+01 2.0030 8 H4SiO4 0.4101979E-03 0.4177660E-02 0.4012810E+03 -3.3870 9 Ca++ 0.4023087E-07 0.5941682E-07 0.2379787E-02 12.1810 10 Mg++ 0.1796367E-10 0.5825985E-10 0.1415509E-05 8.8298 11 Fe++ 0.1059290E-12 0.2862409E-07 0.1597549E-02 6.6007 12 K+ 0.6882651E-04 0.6904419E-04 0.2698042E+01 5.6715 13 Na+ 0.8725631E-02 0.9119768E-02 0.2095277E+03 7.7742 14 Mn++ 0.1422869E-10 0.8443279E-09 0.4635606E-04 8.7290 15 HPO4-- 0.4287049E-06 0.4341224E-06 0.4164003E-01 13.2103 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.2251662E+00 -.9128309E-02 -.2160379E+00 0.0000000E+00 2 H2O 0.5533778E+02 0.5539878E+02 -.6099983E-01 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.4023791E-03 0.2550581E-04 0.3768733E-03 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.3768746E-03 -.1342037E-08 -.3768733E-03 0.0000000E+00 7 Al+++ 0.4434283E-01 0.5353636E-04 0.4428929E-01 0.0000000E+00 8 H4SiO4 0.1416034E+00 0.4169309E-02 0.1374341E+00 0.0000000E+00 9 Ca++ 0.1565526E-01 0.5929804E-07 0.1565520E-01 0.0000000E+00 10 Mg++ 0.1079286E-01 0.5814339E-10 0.1079286E-01 0.0000000E+00 11 Fe++ 0.9696204E-02 0.2856687E-07 0.9696175E-02 0.0000000E+00 12 K+ 0.2887261E-02 0.6890617E-04 0.2818355E-02 0.0000000E+00 13 Na+ 0.1723013E-01 0.9101538E-02 0.8128592E-02 0.0000000E+00 14 Mn++ 0.2357876E-03 0.8426400E-09 0.2357867E-03 0.0000000E+00 15 HPO4-- 0.8047312E-04 0.4332546E-06 0.8003987E-04 0.0000000E+00 Chg. balance for solid moles: -.1523E-16 Mass of aqueous solution: 0.998639E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 13.5990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 0.8129E-02 -2.090 2.131 0.329 14.34 0.8182 andradite 0.7609E-03 -3.119 0.3867 -0.413 2.602 0.1005 grossular 0.5494E-04 -4.260 0.2475E-01 -1.606 0.1665 0.6886E-02 apatite-OH 0.2668E-04 -4.574 0.1340E-01 -1.873 0.9019E-01 0.4259E-02 clinochlore 0.2159E-02 -2.666 1.200 0.079 8.074 0.4564 daphnite 0.1336E-02 -2.874 0.9534 -0.021 6.416 0.2889 chlorite-Mn 0.4716E-04 -4.326 0.3343E-01 -1.476 0.2250 0.1065E-01 hematite 0.7466E-03 -3.127 0.1192 -0.924 0.8023 0.2260E-01 microcline 0.2818E-02 -2.550 0.7845 -0.105 5.279 0.3064 stilbite 0.1307E-01 -1.884 9.214 0.964 62.00 4.297 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.9327E+00 0.9327E+00 1.0000 -0.030 grossular 0.6734E-01 0.6734E-01 1.0000 -1.172 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.6094E+00 0.6094E+00 1.0000 -0.215 daphnite 0.3773E+00 0.3773E+00 1.0000 -0.423 chlorite-Mn 0.1331E-01 0.1331E-01 1.0000 -1.876 hematite 0.1000E+01 0.1000E+01 1.0000 0.000 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 14.860343 g Volume = 6.312234 cm3 Porosity: 1.9779% V(tot) - V(min): 0.12737E+00 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 13.5990000 g log = 1.1335 Original solution: 1000.0103000 g Original solution / Rock added: 73.54 (Water/Rock Ratio), log = 1.8665 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0203 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.1000E+01 0.9860 0.1006E+01 0.1020E+01 CO2,gas 0.1682E-06 1.0071 0.1729E-06 0.1716E-06 CH4,gas 0.3636E-15 1.0125 0.3756E-15 0.3709E-15 H2,gas 0.2116E-05 1.0005 0.2160E-05 0.2159E-05 H2S,gas 0.7677E-14 0.9960 0.7802E-14 0.7833E-14 S2,gas 0.4800E-36 1.0000 0.4898E-36 0.4898E-36 CO,gas 0.9752E-16 1.0000 0.9950E-16 0.9950E-16 SO3,gas 0.9796E-40 1.0000 0.9995E-40 0.9995E-40 SO2,gas 0.8231E-23 1.0000 0.8398E-23 0.8398E-23 HCl,gas 0.4926E-17 1.0000 0.5026E-17 0.5026E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 16 albite -0.38 -0.38 0.00 0.000 0.11184E-10 22 andradite 39.01 39.01 0.00 0.000 0.24265E-10 23 grossular 32.73 32.73 0.00 0.000 0.00000E+00 32 apatite-OH -18.15 -18.15 0.00 0.000 0.00000E+00 46 clinochlore 39.07 39.07 0.00 0.000 0.12132E-10 47 daphnite 28.97 28.97 0.00 0.000 0.66728E-10 48 chlorite-Mn 46.87 46.87 0.00 0.000 0.12132E-10 90 hematite 12.57 12.57 0.00 0.000 0.30331E-11 116 microcline -2.49 -2.49 0.00 0.000 0.13649E-10 163 stilbite -7.52 -7.52 0.00 0.000 -0.90992E-11 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -15.12 -8.46 -2.820 0.14447E+05 -6.762 3 CH4,gas 4.54 -12.58 -17.12 -4.281 0.29239E+05 -15.425 4 H2,gas 8.00 0.64 -7.36 -4.208 0.12575E+05 -5.666 5 H2S,gas -6.23 -22.04 -15.81 -7.903 0.26990E+05 -14.108 6 S2,gas -7.34 -45.34 -38.01 -5.848 0.64899E+05 -36.310 7 CO,gas 3.21 -14.49 -17.70 -5.447 0.30224E+05 -16.002 8 SO3,gas 17.12 -24.58 -41.70 -10.425 0.71200E+05 -40.000 9 SO2,gas 0.83 -23.94 -24.77 -6.607 0.42302E+05 -23.076 10 HCl,gas 5.19 -13.81 -19.00 -9.499 0.32438E+05 -17.299 11 acmite 7.71 7.28 -0.43 -0.044 0.72819E+03 15 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 19 spessartine 24.46 20.03 -4.43 -0.221 0.75561E+04 20 analcite 3.32 3.00 -0.32 -0.035 0.54421E+03 21 andalusite 5.00 0.62 -4.38 -0.438 0.74831E+04 26 annite 20.12 17.32 -2.81 -0.156 0.47943E+04 27 phlogopite 27.06 24.00 -3.06 -0.170 0.52276E+04 29 anorthite 12.71 9.41 -3.30 -0.254 0.56301E+04 35 aragonite 0.97 -2.94 -3.91 -1.302 0.66709E+04 36 brucite 12.57 8.83 -3.74 -0.748 0.63838E+04 37 calcite 0.81 -2.94 -3.75 -1.251 0.64067E+04 38 carnegieite-low 9.02 6.39 -2.63 -0.376 0.44960E+04 39 carnegieite-high 10.09 6.39 -3.70 -0.529 0.63230E+04 40 carpholite-Mg 8.58 6.06 -2.52 -0.168 0.43033E+04 41 carpholite-Fe 6.71 3.83 -2.88 -0.192 0.49175E+04 42 celadonite 5.34 2.96 -2.39 -0.140 0.40728E+04 43 celadonite-Fe 3.88 0.73 -3.15 -0.185 0.53774E+04 44 chrysotile 23.89 19.72 -4.18 -0.348 0.71320E+04 50 chloritoid-Mg 13.20 9.45 -3.75 -0.250 0.64011E+04 51 chloritoid-Fe 9.17 7.22 -1.95 -0.130 0.33363E+04 52 chloritoid-Mn 11.40 9.35 -2.05 -0.137 0.35056E+04 54 coesite -2.38 -3.39 -1.01 -0.337 0.17262E+04 59 corundum 8.38 4.01 -4.38 -0.398 0.74738E+04 61 cristobalite -2.56 -3.39 -0.83 -0.276 0.14115E+04 63 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71234E+04 65 diaspore 2.87 2.00 -0.87 -0.145 0.14867E+04 67 diopside 16.18 14.24 -1.94 -0.194 0.33202E+04 68 hedenbergite 14.21 12.01 -2.20 -0.220 0.37574E+04 75 epidote 24.67 24.49 -0.18 -0.009 0.30707E+03 76 clinozoisite 22.81 20.21 -2.60 -0.118 0.44327E+04 77 epidote-Fe 29.84 28.77 -1.07 -0.056 0.18281E+04 78 fayalite 14.05 9.81 -4.23 -0.604 0.72249E+04 79 ferrosilite 11.15 6.43 -4.72 -0.472 0.80628E+04 83 gibbsite 4.08 2.00 -2.08 -0.297 0.35453E+04 84 glaucophane 22.97 18.95 -4.03 -0.109 0.68761E+04 87 greenalite 16.14 13.03 -3.11 -0.259 0.53127E+04 91 heulandite -5.83 -7.52 -1.69 -0.077 0.28938E+04 95 jadeite 4.22 3.00 -1.21 -0.121 0.20697E+04 96 julgoldite 70.43 66.74 -3.69 -0.096 0.63026E+04 97 kalsilite 7.58 4.29 -3.30 -0.471 0.56285E+04 98 kaolinite -1.33 -2.77 -1.44 -0.130 0.24507E+04 99 kyanite 4.88 0.62 -4.26 -0.426 0.72690E+04 101 laumontite 2.88 2.64 -0.24 -0.016 0.41738E+03 102 lawsonite 9.62 9.41 -0.20 -0.014 0.34677E+03 103 leucite 4.12 0.90 -3.22 -0.322 0.54952E+04 105 lizardite 23.24 19.72 -3.53 -0.294 0.60246E+04 107 magnetite 20.09 19.17 -0.92 -0.075 0.15718E+04 108 minnesotaite 10.39 6.25 -4.13 -0.243 0.70588E+04 110 magnesioferrite 26.21 21.40 -4.82 -0.393 0.82238E+04 113 margarite 17.32 13.42 -3.90 -0.156 0.66671E+04 120 muscovite 2.58 1.52 -1.06 -0.063 0.18149E+04 121 paragonite 4.24 3.62 -0.62 -0.036 0.10540E+04 122 nepheline 8.34 6.39 -1.95 -0.278 0.33284E+04 134 phlogopite-Na 29.65 26.11 -3.54 -0.197 0.60464E+04 136 prehnite 19.37 18.21 -1.16 -0.069 0.19890E+04 137 prehnite-Fe 22.50 22.49 -0.01 -0.001 0.18404E+02 138 pumpellyite-Fe 46.27 45.02 -1.25 -0.028 0.21374E+04 139 pumpellyite-Mg 48.99 47.25 -1.75 -0.039 0.29848E+04 145 pyroxmangite 7.40 5.34 -2.06 -0.411 0.35117E+04 146 pyrophyllite -6.18 -9.54 -3.37 -0.210 0.57478E+04 147 quartz -2.99 -3.39 -0.40 -0.133 0.67884E+03 152 rhodonite 7.45 5.34 -2.10 -0.421 0.35919E+04 153 sanidine -1.28 -2.49 -1.21 -0.093 0.20677E+04 156 sillimanite 5.26 0.62 -4.64 -0.464 0.79270E+04 164 stilpnomelane-Fe 13.02 12.75 -0.27 -0.008 0.45726E+03 165 stilpnomelane-Mg 27.44 23.89 -3.55 -0.106 0.60556E+04 171 talc 16.49 12.94 -3.55 -0.209 0.60608E+04 174 tephroite 18.09 14.07 -4.01 -0.574 0.68551E+04 177 topaz-H 4.62 0.62 -4.00 -0.364 0.68291E+04 178 tridymite -2.63 -3.39 -0.76 -0.254 0.12988E+04 187 wairakite 3.95 2.64 -1.31 -0.077 0.22393E+04 188 walstromite 11.51 8.79 -2.72 -0.543 0.46362E+04 189 wollastonite 10.46 8.79 -1.67 -0.333 0.28466E+04 190 pseudo-wollastonite 11.00 8.79 -2.21 -0.441 0.37664E+04 191 zoisite 22.85 20.21 -2.64 -0.120 0.45067E+04 192 akaganeite 7.75 6.28 -1.47 -0.318 0.25125E+04 193 beidellite-Ca -1.65 -5.75 -4.11 -0.254 0.70141E+04 195 beidellite-K -1.52 -5.89 -4.37 -0.268 0.74642E+04 196 beidellite-Mg -1.79 -6.31 -4.52 -0.279 0.77120E+04 197 beidellite-Na -1.34 -5.20 -3.86 -0.236 0.65834E+04 199 chalcedony -2.80 -3.39 -0.58 -0.195 0.99814E+03 201 montmorillonite-Ca -2.29 -5.28 -2.99 -0.185 0.51030E+04 202 montmorillonite-K -2.24 -5.42 -3.18 -0.195 0.54312E+04 203 montmorillonite-Mg -2.48 -5.83 -3.35 -0.207 0.57241E+04 204 montmorillonite-Na -2.04 -4.72 -2.69 -0.164 0.45861E+04 205 nontronite-Ca 3.21 2.81 -0.41 -0.026 0.69634E+03 206 nontronite-H 2.53 0.80 -1.74 -0.116 0.29639E+04 207 nontronite-K 3.34 2.67 -0.67 -0.043 0.11478E+04 208 nontronite-Mg 3.07 2.25 -0.82 -0.053 0.14016E+04 209 nontronite-Na 3.52 3.36 -0.16 -0.010 0.26871E+03 224 tobermorite 9.82 6.76 -3.06 -0.836 0.52305E+04 233 boehmite 4.41 2.00 -2.40 -0.401 0.41036E+04 235 ferrous-oxide 9.81 6.60 -3.21 -0.803 0.54825E+04 240 silica-amorphous -2.09 -3.39 -1.30 -0.432 0.22123E+04 242 an20ab80 2.02 1.58 -0.44 -0.034 0.75517E+03 243 an25ab75 2.65 2.07 -0.58 -0.045 0.99094E+03 244 an30ab70 3.28 2.56 -0.72 -0.056 0.12363E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 0.4000000 g Current total amount of reactant added: 13.5990000 g New total amount of reactant added: 13.9990000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.6621E-13 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 9 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 13.9990000 Water: Moles liquid = 0.5539E+02 kg liquid = 0.9980E+00 Moles total = 0.5533E+02 kg total = 0.9968E+00 Activity = 1.0000 Stoichiometric ionic strength = .4975667E-02 Osmotic coef. = 0.9624 True ionic strength = .8878639E-02 Chg. balance for total moles = 0.6621E-13 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.14692E-09 -9.8329 0.12910E-09 -9.8891 0.87870E+00 -0.0562 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13795E-03 -3.8603 0.12084E-03 -3.9178 0.87598E+00 -0.0575 4 SO4-- 0.25539E-04 -4.5928 0.15967E-04 -4.7968 0.62520E+00 -0.2040 5 HCO3- 0.67157E-05 -5.1729 0.58872E-05 -5.2301 0.87664E+00 -0.0572 6 HS- 0.92744E-12 -12.0327 0.81248E-12 -12.0902 0.87605E+00 -0.0575 7 Al+++ 0.56805E-27 -27.2456 0.20053E-27 -27.6978 0.35302E+00 -0.4522 8 H4SiO4 0.42066E-03 -3.3761 0.42066E-03 -3.3761 0.10000E+01 0.0000 9 Ca++ 0.39715E-07 -7.4010 0.24737E-07 -7.6067 0.62286E+00 -0.2056 10 Mg++ 0.18414E-10 -10.7349 0.11442E-10 -10.9415 0.62140E+00 -0.2066 11 Fe++ 0.10858E-12 -12.9642 0.67511E-13 -13.1706 0.62175E+00 -0.2064 12 K+ 0.69231E-04 -4.1597 0.60698E-04 -4.2168 0.87675E+00 -0.0571 13 Na+ 0.87769E-02 -2.0567 0.76878E-02 -2.1142 0.87591E+00 -0.0575 14 Mn++ 0.14585E-10 -10.8361 0.90721E-11 -11.0423 0.62201E+00 -0.2062 15 HPO4-- 0.44166E-06 -6.3549 0.27615E-06 -6.5589 0.62524E+00 -0.2040 16 HSiO3- 0.34734E-02 -2.4592 0.30426E-02 -2.5168 0.87598E+00 -0.0575 17 Ca(HSiO3)+ 0.19548E-08 -8.7089 0.17141E-08 -8.7660 0.87685E+00 -0.0571 18 Mg(HSiO3)+ 0.11253E-11 -11.9487 0.98673E-12 -12.0058 0.87685E+00 -0.0571 19 NaHSiO3,aq 0.37832E-03 -3.4221 0.37832E-03 -3.4221 0.10000E+01 0.0000 20 AlO+ 0.18668E-14 -14.7289 0.16369E-14 -14.7860 0.87685E+00 -0.0571 22 HAlO2,aq 0.25252E-08 -8.5977 0.25252E-08 -8.5977 0.10000E+01 0.0000 23 AlO2- 0.49475E-04 -4.3056 0.43299E-04 -4.3635 0.87517E+00 -0.0579 24 CH4,aq 0.29144E-18 -18.5354 0.29099E-18 -18.5361 0.99847E+00 -0.0007 29 CO,aq 0.69265E-19 -19.1595 0.69265E-19 -19.1595 0.10000E+01 0.0000 30 CO2,aq 0.16265E-08 -8.7888 0.16240E-08 -8.7894 0.99847E+00 -0.0007 31 CO3-2 0.63782E-05 -5.1953 0.39833E-05 -5.3998 0.62451E+00 -0.2045 32 CaCO3,aq 0.12355E-08 -8.9082 0.12355E-08 -8.9082 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.42396E-11 -11.3727 0.37174E-11 -11.4298 0.87685E+00 -0.0571 34 CaCl+ 0.55170E-11 -11.2583 0.48375E-11 -11.3154 0.87685E+00 -0.0571 35 CaCl2,aq 0.13888E-15 -15.8574 0.13888E-15 -15.8574 0.10000E+01 0.0000 36 CaOH+ 0.15575E-07 -7.8076 0.13657E-07 -7.8647 0.87685E+00 -0.0571 37 CaSO4,aq 0.12542E-09 -9.9016 0.12542E-09 -9.9016 0.10000E+01 0.0000 38 HCl,aq 0.28586E-14 -14.5438 0.28586E-14 -14.5438 0.10000E+01 0.0000 43 FeCl+ 0.14727E-16 -16.8319 0.12913E-16 -16.8890 0.87685E+00 -0.0571 46 FeO,aq 0.15744E-09 -9.8029 0.15744E-09 -9.8029 0.10000E+01 0.0000 47 FeOH+ 0.19414E-10 -10.7119 0.17023E-10 -10.7690 0.87685E+00 -0.0571 48 HFeO2- 0.14567E-07 -7.8366 0.12760E-07 -7.8941 0.87598E+00 -0.0575 49 FeO+ 0.11238E-14 -14.9493 0.98538E-15 -15.0064 0.87685E+00 -0.0571 51 FeO2- 0.13811E-07 -7.8598 0.12098E-07 -7.9173 0.87598E+00 -0.0575 52 HFeO2,aq 0.19864E-09 -9.7019 0.19864E-09 -9.7019 0.10000E+01 0.0000 53 H2,aq 0.17005E-08 -8.7694 0.16979E-08 -8.7701 0.99847E+00 -0.0007 54 KCl,aq 0.13294E-09 -9.8764 0.13294E-09 -9.8764 0.10000E+01 0.0000 55 KHSO4,aq 0.35375E-18 -18.4513 0.35375E-18 -18.4513 0.10000E+01 0.0000 56 KOH,aq 0.20079E-06 -6.6973 0.20079E-06 -6.6973 0.10000E+01 0.0000 57 KSO4- 0.17168E-07 -7.7653 0.15039E-07 -7.8228 0.87598E+00 -0.0575 58 MgCO3,aq 0.14325E-12 -12.8439 0.14325E-12 -12.8439 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.20038E-14 -14.6981 0.17570E-14 -14.7552 0.87685E+00 -0.0571 60 MgCl+ 0.23129E-14 -14.6358 0.20281E-14 -14.6929 0.87685E+00 -0.0571 61 MgOH+ 0.39864E-10 -10.3994 0.34955E-10 -10.4565 0.87685E+00 -0.0571 63 MnO,aq 0.56374E-09 -9.2489 0.56374E-09 -9.2489 0.10000E+01 0.0000 64 MnOH+ 0.24235E-09 -9.6156 0.21250E-09 -9.6726 0.87685E+00 -0.0571 65 MnO2-2 0.17975E-11 -11.7453 0.11226E-11 -11.9498 0.62451E+00 -0.2045 66 HMnO2- 0.36245E-10 -10.4408 0.31750E-10 -10.4983 0.87598E+00 -0.0575 69 MnCl+ 0.76990E-14 -14.1136 0.67508E-14 -14.1706 0.87685E+00 -0.0571 70 MnSO4,aq 0.41819E-13 -13.3786 0.41819E-13 -13.3786 0.10000E+01 0.0000 71 NaCl,aq 0.30787E-06 -6.5116 0.30787E-06 -6.5116 0.10000E+01 0.0000 72 NaOH,aq 0.25586E-04 -4.5920 0.25586E-04 -4.5920 0.10000E+01 0.0000 74 OH- 0.51139E-02 -2.2912 0.44755E-02 -2.3492 0.87517E+00 -0.0579 79 HPO3-2 0.23396E-17 -17.6309 0.14611E-17 -17.8353 0.62451E+00 -0.2045 82 H3PO4,aq 0.32188E-16 -16.4923 0.32188E-16 -16.4923 0.10000E+01 0.0000 83 H2PO4- 0.75038E-09 -9.1247 0.65764E-09 -9.1820 0.87641E+00 -0.0573 84 PO4-3 0.48209E-08 -8.3169 0.17453E-08 -8.7581 0.36202E+00 -0.4413 87 H2P2O7-2 0.54300E-19 -19.2652 0.33911E-19 -19.4697 0.62451E+00 -0.2045 88 HP2O7-3 0.14852E-15 -15.8282 0.52451E-16 -16.2802 0.35316E+00 -0.4520 89 P2O7-4 0.60085E-15 -15.2212 0.97063E-16 -16.0129 0.16154E+00 -0.7917 90 H2S,aq 0.32467E-15 -15.4886 0.32417E-15 -15.4892 0.99847E+00 -0.0007 97 SO3-2 0.55995E-14 -14.2519 0.35229E-14 -14.4531 0.62915E+00 -0.2012 98 HSO3- 0.32507E-16 -16.4880 0.28476E-16 -16.5455 0.87598E+00 -0.0575 99 HSO4- 0.22644E-11 -11.6450 0.19865E-11 -11.7019 0.87727E+00 -0.0569 Charge balance for all species = 0.6531E-13 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.1469176E-09 -.9195804E-02 -.9262821E+01 0.0000 2 H2O 0.1000000E+01 0.5550964E+02 0.9993757E+06 0.0000 3 Cl- 0.1379487E-03 0.1382567E-03 0.4898445E+01 5.9713 4 SO4-- 0.2553941E-04 0.2555803E-04 0.2453556E+01 14.9814 5 HCO3- 0.6715701E-05 0.1309677E-04 0.7986110E+00 4.6590 6 HS- 0.9274365E-12 -.1325180E-08 -.4379801E-04 -2.2011 7 Al+++ 0.5680452E-27 0.4947756E-04 0.1334115E+01 1.9694 8 H4SiO4 0.4206632E-03 0.4272364E-02 0.4103743E+03 -3.3761 9 Ca++ 0.3971525E-07 0.5861537E-07 0.2347667E-02 12.1715 10 Mg++ 0.1841371E-10 0.5955064E-10 0.1446858E-05 8.8367 11 Fe++ 0.1085825E-12 0.2875367E-07 0.1604767E-02 6.6075 12 K+ 0.6923057E-04 0.6944866E-04 0.2713825E+01 5.6723 13 Na+ 0.8776898E-02 0.9181109E-02 0.2109353E+03 7.7749 14 Mn++ 0.1458509E-10 0.8587600E-09 0.4714803E-04 8.7359 15 HPO4-- 0.4416631E-06 0.4472343E-06 0.4289733E-01 13.2193 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.2317896E+00 -.9177010E-02 -.2226126E+00 0.0000000E+00 2 H2O 0.5533277E+02 0.5539619E+02 -.6342046E-01 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.4134645E-03 0.2550579E-04 0.3879587E-03 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.3879600E-03 -.1322472E-08 -.3879587E-03 0.0000000E+00 7 Al+++ 0.4564712E-01 0.4937644E-04 0.4559775E-01 0.0000000E+00 8 H4SiO4 0.1457685E+00 0.4263633E-02 0.1415049E+00 0.0000000E+00 9 Ca++ 0.1611532E-01 0.5849557E-07 0.1611526E-01 0.0000000E+00 10 Mg++ 0.1111032E-01 0.5942893E-10 0.1111032E-01 0.0000000E+00 11 Fe++ 0.9981407E-02 0.2869490E-07 0.9981379E-02 0.0000000E+00 12 K+ 0.2972187E-02 0.6930672E-04 0.2902880E-02 0.0000000E+00 13 Na+ 0.1773223E-01 0.9162344E-02 0.8569882E-02 0.0000000E+00 14 Mn++ 0.2427230E-03 0.8570049E-09 0.2427221E-03 0.0000000E+00 15 HPO4-- 0.8284015E-04 0.4463203E-06 0.8239383E-04 0.0000000E+00 Chg. balance for solid moles: -.6559E-17 Mass of aqueous solution: 0.998602E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 13.9990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 0.8570E-02 -2.067 2.247 0.352 14.69 0.8626 andradite 0.8174E-03 -3.088 0.4154 -0.382 2.716 0.1079 grossular 0.5463E-04 -4.263 0.2461E-01 -1.609 0.1609 0.6848E-02 apatite-OH 0.2746E-04 -4.561 0.1380E-01 -1.860 0.9021E-01 0.4384E-02 clinochlore 0.2222E-02 -2.653 1.235 0.092 8.076 0.4698 daphnite 0.1376E-02 -2.862 0.9815 -0.008 6.418 0.2974 chlorite-Mn 0.4854E-04 -4.314 0.3442E-01 -1.463 0.2250 0.1097E-01 hematite 0.7344E-03 -3.134 0.1173 -0.931 0.7669 0.2223E-01 microcline 0.2903E-02 -2.537 0.8080 -0.093 5.283 0.3156 stilbite 0.1336E-01 -1.874 9.416 0.974 61.57 4.392 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.9374E+00 0.9374E+00 1.0000 -0.028 grossular 0.6265E-01 0.6265E-01 1.0000 -1.203 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.6094E+00 0.6094E+00 1.0000 -0.215 daphnite 0.3773E+00 0.3773E+00 1.0000 -0.423 chlorite-Mn 0.1331E-01 0.1331E-01 1.0000 -1.876 hematite 0.1000E+01 0.1000E+01 1.0000 0.000 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 15.293510 g Volume = 6.489742 cm3 Porosity: 1.6646% V(tot) - V(min): 0.10986E+00 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 13.9990000 g log = 1.1461 Original solution: 1000.0103000 g Original solution / Rock added: 71.43 (Water/Rock Ratio), log = 1.8539 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0203 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.1000E+01 0.9860 0.1006E+01 0.1020E+01 CO2,gas 0.1691E-06 1.0071 0.1737E-06 0.1725E-06 CH4,gas 0.4146E-15 1.0125 0.4283E-15 0.4230E-15 H2,gas 0.2184E-05 1.0005 0.2229E-05 0.2228E-05 H2S,gas 0.8769E-14 0.9960 0.8911E-14 0.8947E-14 S2,gas 0.5879E-36 1.0000 0.5999E-36 0.5999E-36 CO,gas 0.1012E-15 1.0000 0.1032E-15 0.1032E-15 SO3,gas 0.9861E-40 1.0000 0.1006E-39 0.1006E-39 SO2,gas 0.8552E-23 1.0000 0.8726E-23 0.8726E-23 HCl,gas 0.4944E-17 1.0000 0.5044E-17 0.5044E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 16 albite -0.38 -0.38 0.00 0.000 0.11184E-10 22 andradite 39.01 39.01 0.00 0.000 0.24265E-10 23 grossular 32.73 32.73 0.00 0.000 -0.24265E-10 32 apatite-OH -18.15 -18.15 0.00 0.000 0.60662E-11 46 clinochlore 39.07 39.07 0.00 0.000 -0.24265E-10 47 daphnite 28.97 28.97 0.00 0.000 0.18198E-10 48 chlorite-Mn 46.87 46.87 0.00 0.000 0.24265E-10 90 hematite 12.57 12.57 0.00 0.000 0.21232E-10 116 microcline -2.49 -2.49 0.00 0.000 -0.10616E-10 163 stilbite -7.52 -7.52 0.00 0.000 0.15165E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -15.12 -8.46 -2.820 0.14444E+05 -6.760 3 CH4,gas 4.54 -12.52 -17.07 -4.267 0.29142E+05 -15.368 4 H2,gas 8.00 0.65 -7.35 -4.200 0.12551E+05 -5.652 5 H2S,gas -6.23 -21.98 -15.75 -7.875 0.26891E+05 -14.050 6 S2,gas -7.34 -45.26 -37.92 -5.834 0.64749E+05 -36.222 7 CO,gas 3.21 -14.47 -17.69 -5.442 0.30197E+05 -15.986 8 SO3,gas 17.12 -24.57 -41.70 -10.424 0.71195E+05 -39.997 9 SO2,gas 0.83 -23.93 -24.76 -6.602 0.42274E+05 -23.059 10 HCl,gas 5.19 -13.81 -19.00 -9.498 0.32435E+05 -17.297 11 acmite 7.71 7.31 -0.40 -0.042 0.68959E+03 15 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 19 spessartine 24.46 20.02 -4.44 -0.222 0.75795E+04 20 analcite 3.32 2.99 -0.33 -0.037 0.56289E+03 21 andalusite 5.00 0.56 -4.44 -0.444 0.75790E+04 26 annite 20.12 17.34 -2.79 -0.155 0.47591E+04 27 phlogopite 27.06 24.02 -3.04 -0.169 0.51925E+04 29 anorthite 12.71 9.36 -3.35 -0.258 0.57235E+04 35 aragonite 0.97 -2.95 -3.91 -1.305 0.66833E+04 36 brucite 12.57 8.84 -3.73 -0.746 0.63721E+04 37 calcite 0.81 -2.95 -3.76 -1.253 0.64191E+04 38 carnegieite-low 9.02 6.37 -2.66 -0.379 0.45334E+04 39 carnegieite-high 10.09 6.37 -3.73 -0.532 0.63604E+04 40 carpholite-Mg 8.58 6.02 -2.56 -0.171 0.43688E+04 41 carpholite-Fe 6.71 3.79 -2.92 -0.195 0.49830E+04 42 celadonite 5.34 2.97 -2.37 -0.139 0.40424E+04 43 celadonite-Fe 3.88 0.74 -3.13 -0.184 0.53470E+04 44 chrysotile 23.89 19.76 -4.13 -0.345 0.70595E+04 50 chloritoid-Mg 13.20 9.40 -3.80 -0.253 0.64853E+04 51 chloritoid-Fe 9.17 7.17 -2.00 -0.134 0.34205E+04 52 chloritoid-Mn 11.40 9.30 -2.10 -0.140 0.35897E+04 54 coesite -2.38 -3.38 -1.00 -0.333 0.17075E+04 59 corundum 8.38 3.94 -4.44 -0.404 0.75884E+04 61 cristobalite -2.56 -3.38 -0.82 -0.272 0.13928E+04 63 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71234E+04 65 diaspore 2.87 1.97 -0.90 -0.151 0.15440E+04 67 diopside 16.18 14.26 -1.93 -0.193 0.32874E+04 68 hedenbergite 14.21 12.03 -2.18 -0.218 0.37246E+04 75 epidote 24.67 24.44 -0.23 -0.011 0.39800E+03 76 clinozoisite 22.81 20.12 -2.68 -0.122 0.45809E+04 77 epidote-Fe 29.84 28.75 -1.09 -0.057 0.18617E+04 78 fayalite 14.05 9.84 -4.21 -0.601 0.71828E+04 79 ferrosilite 11.15 6.46 -4.69 -0.469 0.80020E+04 83 gibbsite 4.08 1.97 -2.11 -0.301 0.36025E+04 84 glaucophane 22.97 18.99 -3.98 -0.108 0.68036E+04 85 glaucophane-Fe 17.28 12.30 -4.97 -0.134 0.84913E+04 87 greenalite 16.14 13.07 -3.07 -0.256 0.52402E+04 91 heulandite -5.83 -7.52 -1.69 -0.077 0.28938E+04 95 jadeite 4.22 2.99 -1.22 -0.122 0.20884E+04 96 julgoldite 70.43 66.78 -3.65 -0.095 0.62319E+04 97 kalsilite 7.58 4.27 -3.32 -0.474 0.56659E+04 98 kaolinite -1.33 -2.81 -1.48 -0.135 0.25279E+04 99 kyanite 4.88 0.56 -4.31 -0.431 0.73649E+04 101 laumontite 2.88 2.61 -0.28 -0.018 0.47343E+03 102 lawsonite 9.62 9.36 -0.26 -0.017 0.44018E+03 103 leucite 4.12 0.89 -3.23 -0.323 0.55139E+04 105 lizardite 23.24 19.76 -3.49 -0.290 0.59521E+04 107 magnetite 20.09 19.17 -0.91 -0.075 0.15601E+04 108 minnesotaite 10.39 6.32 -4.07 -0.239 0.69489E+04 110 magnesioferrite 26.21 21.40 -4.81 -0.393 0.82121E+04 113 margarite 17.32 13.30 -4.03 -0.161 0.68751E+04 120 muscovite 2.58 1.45 -1.13 -0.066 0.19295E+04 121 paragonite 4.24 3.56 -0.68 -0.040 0.11686E+04 122 nepheline 8.34 6.37 -1.97 -0.282 0.33658E+04 134 phlogopite-Na 29.65 26.13 -3.52 -0.196 0.60113E+04 136 prehnite 19.37 18.15 -1.22 -0.072 0.20800E+04 137 prehnite-Fe 22.50 22.47 -0.03 -0.002 0.52046E+02 138 pumpellyite-Fe 46.27 44.88 -1.38 -0.031 0.23648E+04 139 pumpellyite-Mg 48.99 47.11 -1.88 -0.042 0.32122E+04 145 pyroxmangite 7.40 5.36 -2.04 -0.408 0.34813E+04 146 pyrophyllite -6.18 -9.57 -3.39 -0.212 0.57876E+04 147 quartz -2.99 -3.38 -0.39 -0.129 0.66016E+03 152 rhodonite 7.45 5.36 -2.09 -0.417 0.35616E+04 153 sanidine -1.28 -2.49 -1.21 -0.093 0.20677E+04 156 sillimanite 5.26 0.56 -4.70 -0.470 0.80229E+04 164 stilpnomelane-Fe 13.02 12.80 -0.21 -0.006 0.36323E+03 165 stilpnomelane-Mg 27.44 23.95 -3.49 -0.104 0.59616E+04 171 talc 16.49 13.01 -3.49 -0.205 0.59510E+04 174 tephroite 18.09 14.10 -3.99 -0.570 0.68130E+04 177 topaz-H 4.62 0.56 -4.06 -0.369 0.69249E+04 178 tridymite -2.63 -3.38 -0.75 -0.250 0.12801E+04 187 wairakite 3.95 2.61 -1.34 -0.079 0.22954E+04 188 walstromite 11.51 8.80 -2.71 -0.543 0.46337E+04 189 wollastonite 10.46 8.80 -1.67 -0.333 0.28441E+04 190 pseudo-wollastonite 11.00 8.80 -2.20 -0.441 0.37639E+04 191 zoisite 22.85 20.12 -2.73 -0.124 0.46550E+04 192 akaganeite 7.75 6.28 -1.47 -0.318 0.25125E+04 193 beidellite-Ca -1.65 -5.79 -4.15 -0.257 0.70817E+04 195 beidellite-K -1.52 -5.93 -4.41 -0.270 0.75287E+04 196 beidellite-Mg -1.79 -6.34 -4.55 -0.282 0.77750E+04 197 beidellite-Na -1.34 -5.24 -3.89 -0.238 0.66479E+04 199 chalcedony -2.80 -3.38 -0.57 -0.191 0.97946E+03 201 montmorillonite-Ca -2.29 -5.29 -3.00 -0.186 0.51227E+04 202 montmorillonite-K -2.24 -5.43 -3.19 -0.195 0.54479E+04 203 montmorillonite-Mg -2.48 -5.84 -3.36 -0.208 0.57393E+04 204 montmorillonite-Na -2.04 -4.73 -2.70 -0.165 0.46028E+04 205 nontronite-Ca 3.21 2.83 -0.38 -0.025 0.64935E+03 206 nontronite-H 2.53 0.83 -1.71 -0.114 0.29142E+04 207 nontronite-K 3.34 2.70 -0.64 -0.041 0.10978E+04 208 nontronite-Mg 3.07 2.28 -0.79 -0.051 0.13500E+04 209 nontronite-Na 3.52 3.39 -0.13 -0.008 0.21864E+03 224 tobermorite 9.82 6.76 -3.06 -0.835 0.52253E+04 233 boehmite 4.41 1.97 -2.44 -0.406 0.41609E+04 235 ferrous-oxide 9.81 6.61 -3.20 -0.801 0.54708E+04 240 silica-amorphous -2.09 -3.38 -1.28 -0.428 0.21936E+04 242 an20ab80 2.02 1.56 -0.45 -0.035 0.77385E+03 243 an25ab75 2.65 2.05 -0.59 -0.046 0.10143E+04 244 an30ab70 3.28 2.54 -0.74 -0.057 0.12643E+04 245 tr.625ac.25prg.125 45.16 40.18 -4.98 -0.134 0.85090E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 0.4000000 g Current total amount of reactant added: 13.9990000 g New total amount of reactant added: 14.3990000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.6619E-13 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 9 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 14.3990000 Water: Moles liquid = 0.5539E+02 kg liquid = 0.9979E+00 Moles total = 0.5533E+02 kg total = 0.9967E+00 Activity = 1.0000 Stoichiometric ionic strength = .4989500E-02 Osmotic coef. = 0.9624 True ionic strength = .8930180E-02 Chg. balance for total moles = 0.6619E-13 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.14755E-09 -9.8311 0.12961E-09 -9.8874 0.87845E+00 -0.0563 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13795E-03 -3.8603 0.12081E-03 -3.9179 0.87573E+00 -0.0576 4 SO4-- 0.25540E-04 -4.5928 0.15950E-04 -4.7973 0.62448E+00 -0.2045 5 HCO3- 0.67262E-05 -5.1722 0.58948E-05 -5.2295 0.87638E+00 -0.0573 6 HS- 0.10532E-11 -11.9775 0.92238E-12 -12.0351 0.87579E+00 -0.0576 7 Al+++ 0.53422E-27 -27.2723 0.18810E-27 -27.7256 0.35210E+00 -0.4533 8 H4SiO4 0.43123E-03 -3.3653 0.43123E-03 -3.3653 0.10000E+01 0.0000 9 Ca++ 0.39217E-07 -7.4065 0.24399E-07 -7.6126 0.62214E+00 -0.2061 10 Mg++ 0.18873E-10 -10.7242 0.11714E-10 -10.9313 0.62067E+00 -0.2071 11 Fe++ 0.11129E-12 -12.9535 0.69114E-13 -13.1604 0.62102E+00 -0.2069 12 K+ 0.69634E-04 -4.1572 0.61034E-04 -4.2144 0.87650E+00 -0.0572 13 Na+ 0.88280E-02 -2.0541 0.77303E-02 -2.1118 0.87565E+00 -0.0577 14 Mn++ 0.14949E-10 -10.8254 0.92876E-11 -11.0321 0.62129E+00 -0.2067 15 HPO4-- 0.45485E-06 -6.3421 0.28407E-06 -6.5466 0.62453E+00 -0.2044 16 HSiO3- 0.35475E-02 -2.4501 0.31066E-02 -2.5077 0.87573E+00 -0.0576 17 Ca(HSiO3)+ 0.19692E-08 -8.7057 0.17262E-08 -8.7629 0.87659E+00 -0.0572 18 Mg(HSiO3)+ 0.11766E-11 -11.9294 0.10314E-11 -11.9866 0.87659E+00 -0.0572 19 NaHSiO3,aq 0.38841E-03 -3.4107 0.38841E-03 -3.4107 0.10000E+01 0.0000 20 AlO+ 0.17377E-14 -14.7600 0.15233E-14 -14.8172 0.87659E+00 -0.0572 22 HAlO2,aq 0.23405E-08 -8.6307 0.23405E-08 -8.6307 0.10000E+01 0.0000 23 AlO2- 0.45687E-04 -4.3402 0.39972E-04 -4.3982 0.87490E+00 -0.0580 24 CH4,aq 0.33165E-18 -18.4793 0.33114E-18 -18.4800 0.99846E+00 -0.0007 29 CO,aq 0.71823E-19 -19.1437 0.71823E-19 -19.1437 0.10000E+01 0.0000 30 CO2,aq 0.16351E-08 -8.7865 0.16326E-08 -8.7871 0.99846E+00 -0.0007 31 CO3-2 0.63683E-05 -5.1960 0.39725E-05 -5.4009 0.62380E+00 -0.2050 32 CaCO3,aq 0.12153E-08 -8.9153 0.12153E-08 -8.9153 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.41881E-11 -11.3780 0.36713E-11 -11.4352 0.87659E+00 -0.0572 34 CaCl+ 0.54417E-11 -11.2643 0.47701E-11 -11.3215 0.87659E+00 -0.0572 35 CaCl2,aq 0.13691E-15 -15.8636 0.13691E-15 -15.8636 0.10000E+01 0.0000 36 CaOH+ 0.15305E-07 -7.8152 0.13416E-07 -7.8724 0.87659E+00 -0.0572 37 CaSO4,aq 0.12357E-09 -9.9081 0.12357E-09 -9.9081 0.10000E+01 0.0000 38 HCl,aq 0.28693E-14 -14.5422 0.28693E-14 -14.5422 0.10000E+01 0.0000 43 FeCl+ 0.15077E-16 -16.8217 0.13216E-16 -16.8789 0.87659E+00 -0.0572 46 FeO,aq 0.15990E-09 -9.7962 0.15990E-09 -9.7962 0.10000E+01 0.0000 47 FeOH+ 0.19801E-10 -10.7033 0.17358E-10 -10.7605 0.87659E+00 -0.0572 48 HFeO2- 0.14740E-07 -7.8315 0.12908E-07 -7.8891 0.87573E+00 -0.0576 49 FeO+ 0.11286E-14 -14.9475 0.98931E-15 -15.0047 0.87659E+00 -0.0572 51 FeO2- 0.13760E-07 -7.8614 0.12050E-07 -7.9190 0.87573E+00 -0.0576 52 HFeO2,aq 0.19864E-09 -9.7019 0.19864E-09 -9.7019 0.10000E+01 0.0000 53 H2,aq 0.17540E-08 -8.7560 0.17513E-08 -8.7566 0.99846E+00 -0.0007 54 KCl,aq 0.13364E-09 -9.8741 0.13364E-09 -9.8741 0.10000E+01 0.0000 55 KHSO4,aq 0.35674E-18 -18.4477 0.35674E-18 -18.4477 0.10000E+01 0.0000 56 KOH,aq 0.20110E-06 -6.6966 0.20110E-06 -6.6966 0.10000E+01 0.0000 57 KSO4- 0.17249E-07 -7.7632 0.15106E-07 -7.8209 0.87573E+00 -0.0576 58 MgCO3,aq 0.14625E-12 -12.8349 0.14625E-12 -12.8349 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.20546E-14 -14.6873 0.18011E-14 -14.7445 0.87659E+00 -0.0572 60 MgCl+ 0.23679E-14 -14.6256 0.20757E-14 -14.6828 0.87659E+00 -0.0572 61 MgOH+ 0.40660E-10 -10.3908 0.35642E-10 -10.4480 0.87659E+00 -0.0572 63 MnO,aq 0.57254E-09 -9.2422 0.57254E-09 -9.2422 0.10000E+01 0.0000 64 MnOH+ 0.24719E-09 -9.6070 0.21668E-09 -9.6642 0.87659E+00 -0.0572 65 MnO2-2 0.18132E-11 -11.7416 0.11311E-11 -11.9465 0.62380E+00 -0.2050 66 HMnO2- 0.36675E-10 -10.4356 0.32118E-10 -10.4933 0.87573E+00 -0.0576 69 MnCl+ 0.78820E-14 -14.1034 0.69093E-14 -14.1606 0.87659E+00 -0.0572 70 MnSO4,aq 0.42765E-13 -13.3689 0.42765E-13 -13.3689 0.10000E+01 0.0000 71 NaCl,aq 0.30949E-06 -6.5093 0.30949E-06 -6.5093 0.10000E+01 0.0000 72 NaOH,aq 0.25625E-04 -4.5913 0.25625E-04 -4.5913 0.10000E+01 0.0000 74 OH- 0.50951E-02 -2.2928 0.44577E-02 -2.3509 0.87490E+00 -0.0580 79 HPO3-2 0.24853E-17 -17.6046 0.15503E-17 -17.8096 0.62380E+00 -0.2050 82 H3PO4,aq 0.33376E-16 -16.4766 0.33376E-16 -16.4766 0.10000E+01 0.0000 83 H2PO4- 0.77520E-09 -9.1106 0.67920E-09 -9.1680 0.87615E+00 -0.0574 84 PO4-3 0.49517E-08 -8.3052 0.17882E-08 -8.7476 0.36112E+00 -0.4423 87 H2P2O7-2 0.57985E-19 -19.2367 0.36171E-19 -19.4416 0.62380E+00 -0.2050 88 HP2O7-3 0.15820E-15 -15.8008 0.55724E-16 -16.2540 0.35224E+00 -0.4532 89 P2O7-4 0.63871E-15 -15.1947 0.10271E-15 -15.9884 0.16081E+00 -0.7937 90 H2S,aq 0.37006E-15 -15.4317 0.36949E-15 -15.4324 0.99846E+00 -0.0007 97 SO3-2 0.57758E-14 -14.2384 0.36298E-14 -14.4401 0.62845E+00 -0.2017 98 HSO3- 0.33637E-16 -16.4732 0.29457E-16 -16.5308 0.87573E+00 -0.0576 99 HSO4- 0.22716E-11 -11.6437 0.19922E-11 -11.7007 0.87702E+00 -0.0570 Charge balance for all species = 0.6517E-13 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.1475452E-09 -.9246080E-02 -.9313385E+01 0.0000 2 H2O 0.1000000E+01 0.5550953E+02 0.9993653E+06 0.0000 3 Cl- 0.1379533E-03 0.1382629E-03 0.4898623E+01 5.9695 4 SO4-- 0.2554047E-04 0.2555915E-04 0.2453644E+01 14.9775 5 HCO3- 0.6726240E-05 0.1309735E-04 0.7986401E+00 4.6578 6 HS- 0.1053195E-11 -.1305307E-08 -.4314082E-04 -2.1477 7 Al+++ 0.5342154E-27 0.4568976E-04 0.1231970E+01 1.9365 8 H4SiO4 0.4312299E-03 0.4367153E-02 0.4194755E+03 -3.3653 9 Ca++ 0.3921731E-07 0.5783986E-07 0.2316587E-02 12.1621 10 Mg++ 0.1887304E-10 0.6086036E-10 0.1478667E-05 8.8434 11 Fe++ 0.1112908E-12 0.2887860E-07 0.1611726E-02 6.6143 12 K+ 0.6963358E-04 0.6985206E-04 0.2729565E+01 5.6729 13 Na+ 0.8828033E-02 0.9242382E-02 0.2123412E+03 7.7756 14 Mn++ 0.1494884E-10 0.8732146E-09 0.4794122E-04 8.7426 15 HPO4-- 0.4548476E-06 0.4605744E-06 0.4417650E-01 13.2281 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.2384130E+00 -.9226769E-02 -.2291863E+00 0.0000000E+00 2 H2O 0.5532775E+02 0.5539359E+02 -.6584182E-01 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.4245498E-03 0.2550577E-04 0.3990441E-03 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.3990454E-03 -.1302581E-08 -.3990441E-03 0.0000000E+00 7 Al+++ 0.4695142E-01 0.4559434E-04 0.4690582E-01 0.0000000E+00 8 H4SiO4 0.1499337E+00 0.4358032E-02 0.1455756E+00 0.0000000E+00 9 Ca++ 0.1657538E-01 0.5771906E-07 0.1657532E-01 0.0000000E+00 10 Mg++ 0.1142778E-01 0.6073325E-10 0.1142778E-01 0.0000000E+00 11 Fe++ 0.1026661E-01 0.2881829E-07 0.1026658E-01 0.0000000E+00 12 K+ 0.3057113E-02 0.6970618E-04 0.2987406E-02 0.0000000E+00 13 Na+ 0.1823432E-01 0.9223079E-02 0.9011245E-02 0.0000000E+00 14 Mn++ 0.2496584E-03 0.8713909E-09 0.2496576E-03 0.0000000E+00 15 HPO4-- 0.8520719E-04 0.4596125E-06 0.8474757E-04 0.0000000E+00 Chg. balance for solid moles: 0.6993E-17 Mass of aqueous solution: 0.998566E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 14.3990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 0.9011E-02 -2.045 2.363 0.373 15.02 0.9071 andradite 0.8742E-03 -3.058 0.4442 -0.352 2.825 0.1154 grossular 0.5415E-04 -4.266 0.2439E-01 -1.613 0.1551 0.6787E-02 apatite-OH 0.2825E-04 -4.549 0.1419E-01 -1.848 0.9023E-01 0.4509E-02 clinochlore 0.2286E-02 -2.641 1.270 0.104 8.078 0.4832 daphnite 0.1415E-02 -2.849 1.010 0.004 6.419 0.3059 chlorite-Mn 0.4993E-04 -4.302 0.3540E-01 -1.451 0.2251 0.1128E-01 hematite 0.7220E-03 -3.141 0.1153 -0.938 0.7332 0.2185E-01 microcline 0.2987E-02 -2.525 0.8315 -0.080 5.287 0.3248 stilbite 0.1365E-01 -1.865 9.619 0.983 61.16 4.486 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.9417E+00 0.9417E+00 1.0000 -0.026 grossular 0.5833E-01 0.5833E-01 1.0000 -1.234 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.6094E+00 0.6094E+00 1.0000 -0.215 daphnite 0.3773E+00 0.3773E+00 1.0000 -0.423 chlorite-Mn 0.1331E-01 0.1331E-01 1.0000 -1.876 hematite 0.1000E+01 0.1000E+01 1.0000 0.000 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 15.726648 g Volume = 6.667240 cm3 Porosity: 1.3664% V(tot) - V(min): 0.92360E-01 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 14.3990000 g log = 1.1583 Original solution: 1000.0103000 g Original solution / Rock added: 69.45 (Water/Rock Ratio), log = 1.8417 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0203 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.1000E+01 0.9860 0.1006E+01 0.1020E+01 CO2,gas 0.1700E-06 1.0071 0.1747E-06 0.1734E-06 CH4,gas 0.4718E-15 1.0125 0.4874E-15 0.4814E-15 H2,gas 0.2252E-05 1.0005 0.2299E-05 0.2298E-05 H2S,gas 0.9995E-14 0.9960 0.1016E-13 0.1020E-13 S2,gas 0.7179E-36 1.0000 0.7325E-36 0.7325E-36 CO,gas 0.1049E-15 1.0000 0.1070E-15 0.1070E-15 SO3,gas 0.9929E-40 1.0000 0.1013E-39 0.1013E-39 SO2,gas 0.8882E-23 1.0000 0.9062E-23 0.9062E-23 HCl,gas 0.4962E-17 1.0000 0.5063E-17 0.5063E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 16 albite -0.38 -0.38 0.00 0.000 -0.13080E-10 22 andradite 39.01 39.01 0.00 0.000 -0.12132E-10 23 grossular 32.73 32.73 0.00 0.000 -0.24265E-10 32 apatite-OH -18.15 -18.15 0.00 0.000 0.60662E-11 46 clinochlore 39.07 39.07 0.00 0.000 -0.24265E-10 47 daphnite 28.97 28.97 0.00 0.000 0.24265E-10 48 chlorite-Mn 46.87 46.87 0.00 0.000 -0.24265E-10 90 hematite 12.57 12.57 0.00 0.000 0.30331E-11 116 microcline -2.49 -2.49 0.00 0.000 -0.10616E-10 163 stilbite -7.52 -7.52 0.00 0.000 -0.90992E-11 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -15.12 -8.46 -2.819 0.14440E+05 -6.758 3 CH4,gas 4.54 -12.47 -17.01 -4.253 0.29046E+05 -15.312 4 H2,gas 8.00 0.66 -7.34 -4.193 0.12528E+05 -5.638 5 H2S,gas -6.23 -21.92 -15.69 -7.846 0.26794E+05 -13.993 6 S2,gas -7.34 -45.17 -37.83 -5.821 0.64601E+05 -36.135 7 CO,gas 3.21 -14.45 -17.67 -5.437 0.30170E+05 -15.970 8 SO3,gas 17.12 -24.57 -41.69 -10.423 0.71190E+05 -39.994 9 SO2,gas 0.83 -23.91 -24.74 -6.598 0.42246E+05 -23.043 10 HCl,gas 5.19 -13.81 -18.99 -9.497 0.32433E+05 -17.296 11 acmite 7.71 7.33 -0.38 -0.040 0.65166E+03 15 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 19 spessartine 24.46 20.00 -4.45 -0.223 0.76025E+04 20 analcite 3.32 2.98 -0.34 -0.038 0.58129E+03 21 andalusite 5.00 0.51 -4.49 -0.449 0.76732E+04 26 annite 20.12 17.36 -2.77 -0.154 0.47247E+04 27 phlogopite 27.06 24.04 -3.02 -0.168 0.51580E+04 29 anorthite 12.71 9.30 -3.41 -0.262 0.58155E+04 35 aragonite 0.97 -2.95 -3.92 -1.307 0.66956E+04 36 brucite 12.57 8.84 -3.73 -0.745 0.63606E+04 37 calcite 0.81 -2.95 -3.77 -1.256 0.64313E+04 38 carnegieite-low 9.02 6.35 -2.68 -0.382 0.45702E+04 39 carnegieite-high 10.09 6.35 -3.75 -0.535 0.63972E+04 40 carpholite-Mg 8.58 5.99 -2.60 -0.173 0.44332E+04 41 carpholite-Fe 6.71 3.76 -2.96 -0.197 0.50473E+04 42 celadonite 5.34 2.99 -2.35 -0.138 0.40125E+04 43 celadonite-Fe 3.88 0.76 -3.11 -0.183 0.53171E+04 44 chrysotile 23.89 19.80 -4.09 -0.341 0.69882E+04 50 chloritoid-Mg 13.20 9.35 -3.85 -0.256 0.65681E+04 51 chloritoid-Fe 9.17 7.12 -2.05 -0.137 0.35033E+04 52 chloritoid-Mn 11.40 9.25 -2.15 -0.143 0.36725E+04 54 coesite -2.38 -3.37 -0.99 -0.330 0.16891E+04 59 corundum 8.38 3.87 -4.51 -0.410 0.77011E+04 61 cristobalite -2.56 -3.37 -0.80 -0.268 0.13744E+04 63 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71234E+04 65 diaspore 2.87 1.94 -0.94 -0.156 0.16003E+04 67 diopside 16.18 14.27 -1.91 -0.191 0.32552E+04 68 hedenbergite 14.21 12.05 -2.16 -0.216 0.36924E+04 75 epidote 24.67 24.38 -0.29 -0.014 0.48771E+03 76 clinozoisite 22.81 20.04 -2.77 -0.126 0.47269E+04 77 epidote-Fe 29.84 28.73 -1.11 -0.058 0.18951E+04 78 fayalite 14.05 9.86 -4.18 -0.597 0.71414E+04 79 ferrosilite 11.15 6.50 -4.65 -0.465 0.79423E+04 83 gibbsite 4.08 1.94 -2.14 -0.306 0.36589E+04 84 glaucophane 22.97 19.03 -3.94 -0.107 0.67323E+04 85 glaucophane-Fe 17.28 12.34 -4.93 -0.133 0.84201E+04 87 greenalite 16.14 13.11 -3.03 -0.252 0.51689E+04 91 heulandite -5.83 -7.52 -1.69 -0.077 0.28938E+04 95 jadeite 4.22 2.98 -1.23 -0.123 0.21068E+04 96 julgoldite 70.43 66.82 -3.61 -0.094 0.61630E+04 97 kalsilite 7.58 4.24 -3.34 -0.477 0.57027E+04 98 kaolinite -1.33 -2.86 -1.52 -0.139 0.26037E+04 99 kyanite 4.88 0.51 -4.37 -0.437 0.74591E+04 101 laumontite 2.88 2.57 -0.31 -0.021 0.52862E+03 102 lawsonite 9.62 9.30 -0.31 -0.021 0.53217E+03 103 leucite 4.12 0.88 -3.24 -0.324 0.55323E+04 105 lizardite 23.24 19.80 -3.44 -0.287 0.58808E+04 107 magnetite 20.09 19.18 -0.91 -0.074 0.15486E+04 108 minnesotaite 10.39 6.38 -4.01 -0.236 0.68409E+04 110 magnesioferrite 26.21 21.41 -4.80 -0.392 0.82006E+04 113 margarite 17.32 13.18 -4.15 -0.166 0.70797E+04 120 muscovite 2.58 1.39 -1.20 -0.070 0.20422E+04 121 paragonite 4.24 3.49 -0.75 -0.044 0.12813E+04 122 nepheline 8.34 6.35 -1.99 -0.285 0.34025E+04 134 phlogopite-Na 29.65 26.15 -3.50 -0.194 0.59768E+04 136 prehnite 19.37 18.10 -1.27 -0.075 0.21697E+04 137 prehnite-Fe 22.50 22.45 -0.05 -0.003 0.85434E+02 138 pumpellyite-Fe 46.27 44.75 -1.52 -0.034 0.25891E+04 139 pumpellyite-Mg 48.99 46.98 -2.01 -0.045 0.34365E+04 145 pyroxmangite 7.40 5.38 -2.02 -0.404 0.34514E+04 146 pyrophyllite -6.18 -9.59 -3.41 -0.213 0.58267E+04 147 quartz -2.99 -3.37 -0.38 -0.125 0.64176E+03 152 rhodonite 7.45 5.38 -2.07 -0.414 0.35317E+04 153 sanidine -1.28 -2.49 -1.21 -0.093 0.20677E+04 156 sillimanite 5.26 0.51 -4.75 -0.475 0.81172E+04 164 stilpnomelane-Fe 13.02 12.86 -0.16 -0.005 0.27068E+03 165 stilpnomelane-Mg 27.44 24.00 -3.44 -0.103 0.58690E+04 171 talc 16.49 13.07 -3.42 -0.201 0.58429E+04 174 tephroite 18.09 14.12 -3.97 -0.567 0.67716E+04 177 topaz-H 4.62 0.51 -4.11 -0.374 0.70192E+04 178 tridymite -2.63 -3.37 -0.74 -0.246 0.12617E+04 187 wairakite 3.95 2.57 -1.38 -0.081 0.23506E+04 188 walstromite 11.51 8.80 -2.71 -0.542 0.46314E+04 189 wollastonite 10.46 8.80 -1.66 -0.333 0.28418E+04 190 pseudo-wollastonite 11.00 8.80 -2.20 -0.441 0.37617E+04 191 zoisite 22.85 20.04 -2.81 -0.128 0.48010E+04 192 akaganeite 7.75 6.28 -1.47 -0.318 0.25125E+04 193 beidellite-Ca -1.65 -5.83 -4.19 -0.259 0.71481E+04 195 beidellite-K -1.52 -5.97 -4.45 -0.272 0.75921E+04 196 beidellite-Mg -1.79 -6.38 -4.59 -0.284 0.78369E+04 197 beidellite-Na -1.34 -5.27 -3.93 -0.241 0.67112E+04 199 chalcedony -2.80 -3.37 -0.56 -0.188 0.96106E+03 201 montmorillonite-Ca -2.29 -5.30 -3.01 -0.186 0.51420E+04 202 montmorillonite-K -2.24 -5.44 -3.20 -0.196 0.54642E+04 203 montmorillonite-Mg -2.48 -5.85 -3.37 -0.208 0.57540E+04 204 montmorillonite-Na -2.04 -4.74 -2.71 -0.166 0.46191E+04 205 nontronite-Ca 3.21 2.86 -0.35 -0.023 0.60308E+03 206 nontronite-H 2.53 0.85 -1.68 -0.112 0.28653E+04 207 nontronite-K 3.34 2.73 -0.61 -0.039 0.10485E+04 208 nontronite-Mg 3.07 2.31 -0.76 -0.049 0.12992E+04 209 nontronite-Na 3.52 3.42 -0.10 -0.006 0.16933E+03 224 tobermorite 9.82 6.77 -3.06 -0.834 0.52203E+04 233 boehmite 4.41 1.94 -2.47 -0.412 0.42172E+04 235 ferrous-oxide 9.81 6.61 -3.20 -0.799 0.54593E+04 240 silica-amorphous -2.09 -3.37 -1.27 -0.425 0.21752E+04 242 an20ab80 2.02 1.55 -0.46 -0.036 0.79225E+03 243 an25ab75 2.65 2.04 -0.61 -0.047 0.10373E+04 244 an30ab70 3.28 2.52 -0.76 -0.058 0.12919E+04 245 tr.625ac.25prg.125 45.16 40.27 -4.90 -0.132 0.83636E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 0.4000000 g Current total amount of reactant added: 14.3990000 g New total amount of reactant added: 14.7990000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.6618E-13 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 9 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 14.7990000 Water: Moles liquid = 0.5539E+02 kg liquid = 0.9979E+00 Moles total = 0.5532E+02 kg total = 0.9967E+00 Activity = 1.0000 Stoichiometric ionic strength = .5004846E-02 Osmotic coef. = 0.9623 True ionic strength = .8981636E-02 Chg. balance for total moles = 0.6618E-13 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.14819E-09 -9.8292 0.13014E-09 -9.8856 0.87821E+00 -0.0564 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13796E-03 -3.8603 0.12078E-03 -3.9180 0.87547E+00 -0.0578 4 SO4-- 0.25542E-04 -4.5928 0.15932E-04 -4.7977 0.62378E+00 -0.2050 5 HCO3- 0.67371E-05 -5.1715 0.59026E-05 -5.2290 0.87613E+00 -0.0574 6 HS- 0.11936E-11 -11.9232 0.10450E-11 -11.9809 0.87554E+00 -0.0577 7 Al+++ 0.50313E-27 -27.2983 0.17670E-27 -27.7528 0.35119E+00 -0.4545 8 H4SiO4 0.44190E-03 -3.3547 0.44190E-03 -3.3547 0.10000E+01 0.0000 9 Ca++ 0.38736E-07 -7.4119 0.24072E-07 -7.6185 0.62142E+00 -0.2066 10 Mg++ 0.19342E-10 -10.7135 0.11991E-10 -10.9211 0.61995E+00 -0.2076 11 Fe++ 0.11406E-12 -12.9429 0.70749E-13 -13.1503 0.62030E+00 -0.2074 12 K+ 0.70036E-04 -4.1547 0.61369E-04 -4.2121 0.87625E+00 -0.0574 13 Na+ 0.88791E-02 -2.0516 0.77727E-02 -2.1094 0.87540E+00 -0.0578 14 Mn++ 0.15320E-10 -10.8147 0.95072E-11 -11.0219 0.62057E+00 -0.2072 15 HPO4-- 0.46826E-06 -6.3295 0.29211E-06 -6.5345 0.62382E+00 -0.2049 16 HSiO3- 0.36216E-02 -2.4411 0.31706E-02 -2.4989 0.87547E+00 -0.0578 17 Ca(HSiO3)+ 0.19834E-08 -8.7026 0.17381E-08 -8.7599 0.87634E+00 -0.0573 18 Mg(HSiO3)+ 0.12296E-11 -11.9102 0.10775E-11 -11.9676 0.87634E+00 -0.0573 19 NaHSiO3,aq 0.39859E-03 -3.3995 0.39859E-03 -3.3995 0.10000E+01 0.0000 20 AlO+ 0.16196E-14 -14.7906 0.14193E-14 -14.8479 0.87634E+00 -0.0573 22 HAlO2,aq 0.21719E-08 -8.6632 0.21719E-08 -8.6632 0.10000E+01 0.0000 23 AlO2- 0.42237E-04 -4.3743 0.36943E-04 -4.4325 0.87465E+00 -0.0582 24 CH4,aq 0.37665E-18 -18.4241 0.37607E-18 -18.4247 0.99846E+00 -0.0007 29 CO,aq 0.74445E-19 -19.1282 0.74445E-19 -19.1282 0.10000E+01 0.0000 30 CO2,aq 0.16439E-08 -8.7841 0.16414E-08 -8.7848 0.99846E+00 -0.0007 31 CO3-2 0.63580E-05 -5.1967 0.39616E-05 -5.4021 0.62309E+00 -0.2055 32 CaCO3,aq 0.11957E-08 -8.9224 0.11957E-08 -8.9224 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.41386E-11 -11.3831 0.36268E-11 -11.4405 0.87634E+00 -0.0573 34 CaCl+ 0.53689E-11 -11.2701 0.47050E-11 -11.3274 0.87634E+00 -0.0573 35 CaCl2,aq 0.13501E-15 -15.8696 0.13501E-15 -15.8696 0.10000E+01 0.0000 36 CaOH+ 0.15043E-07 -7.8227 0.13182E-07 -7.8800 0.87634E+00 -0.0573 37 CaSO4,aq 0.12178E-09 -9.9144 0.12178E-09 -9.9144 0.10000E+01 0.0000 38 HCl,aq 0.28803E-14 -14.5406 0.28803E-14 -14.5406 0.10000E+01 0.0000 43 FeCl+ 0.15434E-16 -16.8115 0.13525E-16 -16.8689 0.87634E+00 -0.0573 46 FeO,aq 0.16235E-09 -9.7895 0.16235E-09 -9.7895 0.10000E+01 0.0000 47 FeOH+ 0.20193E-10 -10.6948 0.17696E-10 -10.7521 0.87634E+00 -0.0573 48 HFeO2- 0.14910E-07 -7.8265 0.13053E-07 -7.8843 0.87547E+00 -0.0578 49 FeO+ 0.11335E-14 -14.9456 0.99335E-15 -15.0029 0.87634E+00 -0.0573 51 FeO2- 0.13708E-07 -7.8630 0.12001E-07 -7.9208 0.87547E+00 -0.0578 52 HFeO2,aq 0.19864E-09 -9.7019 0.19864E-09 -9.7019 0.10000E+01 0.0000 53 H2,aq 0.18083E-08 -8.7427 0.18055E-08 -8.7434 0.99846E+00 -0.0007 54 KCl,aq 0.13434E-09 -9.8718 0.13434E-09 -9.8718 0.10000E+01 0.0000 55 KHSO4,aq 0.35976E-18 -18.4440 0.35976E-18 -18.4440 0.10000E+01 0.0000 56 KOH,aq 0.20138E-06 -6.6960 0.20138E-06 -6.6960 0.10000E+01 0.0000 57 KSO4- 0.17330E-07 -7.7612 0.15172E-07 -7.8190 0.87547E+00 -0.0578 58 MgCO3,aq 0.14930E-12 -12.8259 0.14930E-12 -12.8259 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.21066E-14 -14.6764 0.18461E-14 -14.7337 0.87634E+00 -0.0573 60 MgCl+ 0.24240E-14 -14.6155 0.21242E-14 -14.6728 0.87634E+00 -0.0573 61 MgOH+ 0.41464E-10 -10.3823 0.36337E-10 -10.4397 0.87634E+00 -0.0573 63 MnO,aq 0.58133E-09 -9.2356 0.58133E-09 -9.2356 0.10000E+01 0.0000 64 MnOH+ 0.25208E-09 -9.5985 0.22090E-09 -9.6558 0.87634E+00 -0.0573 65 MnO2-2 0.18282E-11 -11.7380 0.11391E-11 -11.9434 0.62309E+00 -0.2055 66 HMnO2- 0.37098E-10 -10.4307 0.32478E-10 -10.4884 0.87547E+00 -0.0578 69 MnCl+ 0.80687E-14 -14.0932 0.70709E-14 -14.1505 0.87634E+00 -0.0573 70 MnSO4,aq 0.43728E-13 -13.3592 0.43728E-13 -13.3592 0.10000E+01 0.0000 71 NaCl,aq 0.31111E-06 -6.5071 0.31111E-06 -6.5071 0.10000E+01 0.0000 72 NaOH,aq 0.25661E-04 -4.5907 0.25661E-04 -4.5907 0.10000E+01 0.0000 74 OH- 0.50759E-02 -2.2945 0.44396E-02 -2.3527 0.87465E+00 -0.0582 79 HPO3-2 0.26377E-17 -17.5788 0.16435E-17 -17.7842 0.62309E+00 -0.2055 82 H3PO4,aq 0.34601E-16 -16.4609 0.34601E-16 -16.4609 0.10000E+01 0.0000 83 H2PO4- 0.80064E-09 -9.0966 0.70128E-09 -9.1541 0.87590E+00 -0.0575 84 PO4-3 0.50837E-08 -8.2938 0.18313E-08 -8.7372 0.36024E+00 -0.4434 87 H2P2O7-2 0.61888E-19 -19.2084 0.38562E-19 -19.4138 0.62309E+00 -0.2055 88 HP2O7-3 0.16840E-15 -15.7737 0.59165E-16 -16.2279 0.35133E+00 -0.4543 89 P2O7-4 0.67846E-15 -15.1685 0.10861E-15 -15.9641 0.16008E+00 -0.7957 90 H2S,aq 0.42096E-15 -15.3758 0.42031E-15 -15.3764 0.99846E+00 -0.0007 97 SO3-2 0.59545E-14 -14.2252 0.37380E-14 -14.4274 0.62776E+00 -0.2022 98 HSO3- 0.34791E-16 -16.4585 0.30459E-16 -16.5163 0.87547E+00 -0.0578 99 HSO4- 0.22790E-11 -11.6423 0.19982E-11 -11.6994 0.87677E+00 -0.0571 Charge balance for all species = 0.6536E-13 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.1481880E-09 -.9297354E-02 -.9364954E+01 0.0000 2 H2O 0.1000000E+01 0.5550942E+02 0.9993549E+06 0.0000 3 Cl- 0.1379579E-03 0.1382691E-03 0.4898802E+01 5.9676 4 SO4-- 0.2554154E-04 0.2556028E-04 0.2453731E+01 14.9735 5 HCO3- 0.6737075E-05 0.1309794E-04 0.7986691E+00 4.6566 6 HS- 0.1193551E-11 -.1285113E-08 -.4247304E-04 -2.0953 7 Al+++ 0.5031336E-27 0.4223947E-04 0.1138928E+01 1.9040 8 H4SiO4 0.4419020E-03 0.4462075E-02 0.4285894E+03 -3.3547 9 Ca++ 0.3873618E-07 0.5708916E-07 0.2286500E-02 12.1527 10 Mg++ 0.1934186E-10 0.6218956E-10 0.1510949E-05 8.8500 11 Fe++ 0.1140551E-12 0.2899926E-07 0.1618447E-02 6.6209 12 K+ 0.7003592E-04 0.7025477E-04 0.2745278E+01 5.6735 13 Na+ 0.8879084E-02 0.9303641E-02 0.2137469E+03 7.7762 14 Mn++ 0.1532011E-10 0.8876999E-09 0.4873608E-04 8.7492 15 HPO4-- 0.4682589E-06 0.4741433E-06 0.4547759E-01 13.2367 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.2450364E+00 -.9277521E-02 -.2357589E+00 0.0000000E+00 2 H2O 0.5532274E+02 0.5539100E+02 -.6826364E-01 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.4356352E-03 0.2550575E-04 0.4101295E-03 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.4101307E-03 -.1282371E-08 -.4101295E-03 0.0000000E+00 7 Al+++ 0.4825572E-01 0.4214936E-04 0.4821357E-01 0.0000000E+00 8 H4SiO4 0.1540988E+00 0.4452556E-02 0.1496462E+00 0.0000000E+00 9 Ca++ 0.1703543E-01 0.5696737E-07 0.1703538E-01 0.0000000E+00 10 Mg++ 0.1174524E-01 0.6205689E-10 0.1174524E-01 0.0000000E+00 11 Fe++ 0.1055181E-01 0.2893740E-07 0.1055179E-01 0.0000000E+00 12 K+ 0.3142038E-02 0.7010490E-04 0.3071933E-02 0.0000000E+00 13 Na+ 0.1873642E-01 0.9283795E-02 0.9452627E-02 0.0000000E+00 14 Mn++ 0.2565939E-03 0.8858063E-09 0.2565930E-03 0.0000000E+00 15 HPO4-- 0.8757422E-04 0.4731318E-06 0.8710108E-04 0.0000000E+00 Chg. balance for solid moles: -.1339E-16 Mass of aqueous solution: 0.998530E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 14.7990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 0.9453E-02 -2.024 2.479 0.394 15.34 0.9515 andradite 0.9311E-03 -3.031 0.4731 -0.325 2.928 0.1229 grossular 0.5352E-04 -4.271 0.2411E-01 -1.618 0.1492 0.6708E-02 apatite-OH 0.2903E-04 -4.537 0.1458E-01 -1.836 0.9025E-01 0.4634E-02 clinochlore 0.2349E-02 -2.629 1.306 0.116 8.080 0.4966 daphnite 0.1454E-02 -2.837 1.038 0.016 6.421 0.3144 chlorite-Mn 0.5132E-04 -4.290 0.3638E-01 -1.439 0.2251 0.1159E-01 hematite 0.7095E-03 -3.149 0.1133 -0.946 0.7011 0.2147E-01 microcline 0.3072E-02 -2.513 0.8550 -0.068 5.291 0.3340 stilbite 0.1394E-01 -1.856 9.821 0.992 60.78 4.581 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.9456E+00 0.9456E+00 1.0000 -0.024 grossular 0.5436E-01 0.5436E-01 1.0000 -1.265 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.6094E+00 0.6094E+00 1.0000 -0.215 daphnite 0.3773E+00 0.3773E+00 1.0000 -0.423 chlorite-Mn 0.1331E-01 0.1331E-01 1.0000 -1.876 hematite 0.1000E+01 0.1000E+01 1.0000 0.000 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 16.159759 g Volume = 6.844727 cm3 Porosity: 1.0820% V(tot) - V(min): 0.74873E-01 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 14.7990000 g log = 1.1702 Original solution: 1000.0103000 g Original solution / Rock added: 67.57 (Water/Rock Ratio), log = 1.8298 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0203 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.1000E+01 0.9860 0.1006E+01 0.1020E+01 CO2,gas 0.1709E-06 1.0071 0.1756E-06 0.1744E-06 CH4,gas 0.5358E-15 1.0125 0.5536E-15 0.5467E-15 H2,gas 0.2322E-05 1.0005 0.2370E-05 0.2369E-05 H2S,gas 0.1137E-13 0.9960 0.1155E-13 0.1160E-13 S2,gas 0.8741E-36 1.0000 0.8919E-36 0.8919E-36 CO,gas 0.1087E-15 1.0000 0.1109E-15 0.1109E-15 SO3,gas 0.1000E-39 1.0000 0.1020E-39 0.1020E-39 SO2,gas 0.9222E-23 1.0000 0.9409E-23 0.9409E-23 HCl,gas 0.4981E-17 1.0000 0.5082E-17 0.5082E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 16 albite -0.38 -0.38 0.00 0.000 0.11184E-10 22 andradite 39.01 39.01 0.00 0.000 -0.12132E-10 23 grossular 32.73 32.73 0.00 0.000 0.00000E+00 32 apatite-OH -18.15 -18.15 0.00 0.000 0.12132E-10 46 clinochlore 39.07 39.07 0.00 0.000 0.24265E-10 47 daphnite 28.97 28.97 0.00 0.000 0.54595E-10 48 chlorite-Mn 46.87 46.87 0.00 0.000 0.24265E-10 90 hematite 12.57 12.57 0.00 0.000 -0.30331E-11 116 microcline -2.49 -2.49 0.00 0.000 0.15165E-11 163 stilbite -7.52 -7.52 0.00 0.000 0.15165E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -15.11 -8.45 -2.818 0.14436E+05 -6.755 3 CH4,gas 4.54 -12.41 -16.96 -4.239 0.28952E+05 -15.257 4 H2,gas 8.00 0.68 -7.32 -4.185 0.12506E+05 -5.625 5 H2S,gas -6.23 -21.87 -15.64 -7.818 0.26698E+05 -13.937 6 S2,gas -7.34 -45.08 -37.75 -5.807 0.64455E+05 -36.050 7 CO,gas 3.21 -14.44 -17.65 -5.432 0.30144E+05 -15.955 8 SO3,gas 17.12 -24.57 -41.69 -10.423 0.71185E+05 -39.991 9 SO2,gas 0.83 -23.89 -24.73 -6.593 0.42218E+05 -23.026 10 HCl,gas 5.19 -13.80 -18.99 -9.496 0.32430E+05 -17.294 11 acmite 7.71 7.35 -0.36 -0.037 0.61436E+03 15 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 19 spessartine 24.46 19.99 -4.47 -0.223 0.76250E+04 20 analcite 3.32 2.97 -0.35 -0.039 0.59941E+03 21 andalusite 5.00 0.45 -4.55 -0.455 0.77659E+04 26 annite 20.12 17.38 -2.75 -0.153 0.46908E+04 27 phlogopite 27.06 24.06 -3.00 -0.167 0.51241E+04 29 anorthite 12.71 9.25 -3.46 -0.266 0.59061E+04 35 aragonite 0.97 -2.96 -3.93 -1.309 0.67076E+04 36 brucite 12.57 8.85 -3.72 -0.744 0.63493E+04 37 calcite 0.81 -2.96 -3.77 -1.258 0.64434E+04 38 carnegieite-low 9.02 6.33 -2.70 -0.385 0.46064E+04 39 carnegieite-high 10.09 6.33 -3.77 -0.538 0.64334E+04 40 carpholite-Mg 8.58 5.95 -2.63 -0.176 0.44965E+04 41 carpholite-Fe 6.71 3.72 -2.99 -0.200 0.51106E+04 42 celadonite 5.34 3.01 -2.33 -0.137 0.39831E+04 43 celadonite-Fe 3.88 0.78 -3.10 -0.182 0.52877E+04 44 chrysotile 23.89 19.84 -4.05 -0.338 0.69181E+04 50 chloritoid-Mg 13.20 9.30 -3.89 -0.260 0.66495E+04 51 chloritoid-Fe 9.17 7.07 -2.10 -0.140 0.35847E+04 52 chloritoid-Mn 11.40 9.20 -2.20 -0.147 0.37539E+04 54 coesite -2.38 -3.35 -0.98 -0.326 0.16710E+04 59 corundum 8.38 3.81 -4.58 -0.416 0.78119E+04 61 cristobalite -2.56 -3.35 -0.79 -0.265 0.13563E+04 63 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71234E+04 65 diaspore 2.87 1.90 -0.97 -0.162 0.16557E+04 67 diopside 16.18 14.29 -1.89 -0.189 0.32237E+04 68 hedenbergite 14.21 12.06 -2.14 -0.214 0.36609E+04 75 epidote 24.67 24.33 -0.34 -0.016 0.57627E+03 76 clinozoisite 22.81 19.95 -2.85 -0.130 0.48709E+04 77 epidote-Fe 29.84 28.71 -1.13 -0.059 0.19282E+04 78 fayalite 14.05 9.89 -4.16 -0.594 0.71007E+04 79 ferrosilite 11.15 6.53 -4.62 -0.462 0.78834E+04 83 gibbsite 4.08 1.90 -2.18 -0.311 0.37143E+04 84 glaucophane 22.97 19.07 -3.90 -0.105 0.66622E+04 85 glaucophane-Fe 17.28 12.39 -4.89 -0.132 0.83499E+04 87 greenalite 16.14 13.15 -2.99 -0.249 0.50988E+04 91 heulandite -5.83 -7.52 -1.69 -0.077 0.28938E+04 95 jadeite 4.22 2.97 -1.24 -0.124 0.21249E+04 96 julgoldite 70.43 66.86 -3.57 -0.093 0.60958E+04 97 kalsilite 7.58 4.22 -3.36 -0.480 0.57389E+04 98 kaolinite -1.33 -2.90 -1.57 -0.143 0.26783E+04 99 kyanite 4.88 0.45 -4.42 -0.442 0.75518E+04 101 laumontite 2.88 2.54 -0.34 -0.023 0.58300E+03 102 lawsonite 9.62 9.25 -0.36 -0.024 0.62281E+03 103 leucite 4.12 0.87 -3.25 -0.325 0.55505E+04 105 lizardite 23.24 19.84 -3.40 -0.284 0.58107E+04 107 magnetite 20.09 19.19 -0.90 -0.073 0.15373E+04 108 minnesotaite 10.39 6.44 -3.94 -0.232 0.67345E+04 110 magnesioferrite 26.21 21.42 -4.80 -0.392 0.81893E+04 113 margarite 17.32 13.06 -4.26 -0.171 0.72812E+04 120 muscovite 2.58 1.32 -1.26 -0.074 0.21530E+04 121 paragonite 4.24 3.42 -0.82 -0.048 0.13921E+04 122 nepheline 8.34 6.33 -2.01 -0.288 0.34388E+04 134 phlogopite-Na 29.65 26.17 -3.48 -0.193 0.59429E+04 136 prehnite 19.37 18.05 -1.32 -0.078 0.22582E+04 137 prehnite-Fe 22.50 22.43 -0.07 -0.004 0.11857E+03 138 pumpellyite-Fe 46.27 44.62 -1.65 -0.037 0.28103E+04 139 pumpellyite-Mg 48.99 46.85 -2.14 -0.048 0.36578E+04 145 pyroxmangite 7.40 5.39 -2.00 -0.401 0.34220E+04 146 pyrophyllite -6.18 -9.61 -3.43 -0.215 0.58650E+04 147 quartz -2.99 -3.35 -0.37 -0.122 0.62364E+03 152 rhodonite 7.45 5.39 -2.05 -0.410 0.35022E+04 153 sanidine -1.28 -2.49 -1.21 -0.093 0.20677E+04 156 sillimanite 5.26 0.45 -4.81 -0.481 0.82099E+04 164 stilpnomelane-Fe 13.02 12.91 -0.11 -0.003 0.17952E+03 165 stilpnomelane-Mg 27.44 24.06 -3.38 -0.101 0.57779E+04 171 talc 16.49 13.13 -3.36 -0.198 0.57365E+04 174 tephroite 18.09 14.14 -3.94 -0.563 0.67309E+04 177 topaz-H 4.62 0.45 -4.17 -0.379 0.71119E+04 178 tridymite -2.63 -3.35 -0.73 -0.243 0.12436E+04 187 wairakite 3.95 2.54 -1.41 -0.083 0.24050E+04 188 walstromite 11.51 8.80 -2.71 -0.542 0.46293E+04 189 wollastonite 10.46 8.80 -1.66 -0.333 0.28398E+04 190 pseudo-wollastonite 11.00 8.80 -2.20 -0.440 0.37596E+04 191 zoisite 22.85 19.95 -2.90 -0.132 0.49450E+04 192 akaganeite 7.75 6.28 -1.47 -0.318 0.25125E+04 193 beidellite-Ca -1.65 -5.87 -4.22 -0.261 0.72133E+04 195 beidellite-K -1.52 -6.00 -4.48 -0.275 0.76543E+04 196 beidellite-Mg -1.79 -6.42 -4.63 -0.286 0.78976E+04 197 beidellite-Na -1.34 -5.31 -3.97 -0.243 0.67735E+04 199 chalcedony -2.80 -3.35 -0.55 -0.184 0.94293E+03 201 montmorillonite-Ca -2.29 -5.31 -3.02 -0.187 0.51610E+04 202 montmorillonite-K -2.24 -5.45 -3.21 -0.197 0.54802E+04 203 montmorillonite-Mg -2.48 -5.86 -3.38 -0.209 0.57685E+04 204 montmorillonite-Na -2.04 -4.75 -2.71 -0.166 0.46351E+04 205 nontronite-Ca 3.21 2.89 -0.33 -0.021 0.55749E+03 206 nontronite-H 2.53 0.88 -1.65 -0.111 0.28171E+04 207 nontronite-K 3.34 2.76 -0.59 -0.038 0.99987E+03 208 nontronite-Mg 3.07 2.34 -0.73 -0.047 0.12490E+04 209 nontronite-Na 3.52 3.45 -0.07 -0.005 0.12075E+03 224 tobermorite 9.82 6.77 -3.05 -0.833 0.52155E+04 233 boehmite 4.41 1.90 -2.50 -0.417 0.42727E+04 235 ferrous-oxide 9.81 6.62 -3.19 -0.798 0.54480E+04 240 silica-amorphous -2.09 -3.35 -1.26 -0.421 0.21571E+04 242 an20ab80 2.02 1.54 -0.47 -0.037 0.81038E+03 243 an25ab75 2.65 2.02 -0.62 -0.048 0.10599E+04 244 an30ab70 3.28 2.51 -0.77 -0.059 0.13191E+04 245 tr.625ac.25prg.125 45.16 40.35 -4.81 -0.130 0.82208E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 0.4000000 g Current total amount of reactant added: 14.7990000 g New total amount of reactant added: 15.1990000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.6622E-13 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 9 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 15.1990000 Water: Moles liquid = 0.5539E+02 kg liquid = 0.9978E+00 Moles total = 0.5532E+02 kg total = 0.9966E+00 Activity = 1.0000 Stoichiometric ionic strength = .5021569E-02 Osmotic coef. = 0.9623 True ionic strength = .9033050E-02 Chg. balance for total moles = 0.6622E-13 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.14885E-09 -9.8273 0.13068E-09 -9.8838 0.87797E+00 -0.0565 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13796E-03 -3.8602 0.12075E-03 -3.9181 0.87522E+00 -0.0579 4 SO4-- 0.25543E-04 -4.5927 0.15915E-04 -4.7982 0.62307E+00 -0.2055 5 HCO3- 0.67482E-05 -5.1708 0.59106E-05 -5.2284 0.87588E+00 -0.0576 6 HS- 0.13500E-11 -11.8697 0.11816E-11 -11.9275 0.87528E+00 -0.0579 7 Al+++ 0.47451E-27 -27.3238 0.16622E-27 -27.7793 0.35029E+00 -0.4556 8 H4SiO4 0.45268E-03 -3.3442 0.45268E-03 -3.3442 0.10000E+01 0.0000 9 Ca++ 0.38271E-07 -7.4171 0.23755E-07 -7.6242 0.62071E+00 -0.2071 10 Mg++ 0.19820E-10 -10.7029 0.12273E-10 -10.9110 0.61923E+00 -0.2081 11 Fe++ 0.11688E-12 -12.9323 0.72415E-13 -13.1402 0.61959E+00 -0.2079 12 K+ 0.70438E-04 -4.1522 0.61703E-04 -4.2097 0.87600E+00 -0.0575 13 Na+ 0.89301E-02 -2.0491 0.78151E-02 -2.1071 0.87514E+00 -0.0579 14 Mn++ 0.15699E-10 -10.8041 0.97311E-11 -11.0118 0.61985E+00 -0.2077 15 HPO4-- 0.48190E-06 -6.3170 0.30028E-06 -6.5225 0.62312E+00 -0.2054 16 HSiO3- 0.36956E-02 -2.4323 0.32345E-02 -2.4902 0.87522E+00 -0.0579 17 Ca(HSiO3)+ 0.19973E-08 -8.6995 0.17498E-08 -8.7570 0.87609E+00 -0.0575 18 Mg(HSiO3)+ 0.12843E-11 -11.8913 0.11251E-11 -11.9488 0.87609E+00 -0.0575 19 NaHSiO3,aq 0.40884E-03 -3.3885 0.40884E-03 -3.3885 0.10000E+01 0.0000 20 AlO+ 0.15114E-14 -14.8206 0.13241E-14 -14.8781 0.87609E+00 -0.0575 22 HAlO2,aq 0.20178E-08 -8.6951 0.20178E-08 -8.6951 0.10000E+01 0.0000 23 AlO2- 0.39089E-04 -4.4079 0.34179E-04 -4.4662 0.87439E+00 -0.0583 24 CH4,aq 0.42695E-18 -18.3696 0.42629E-18 -18.3703 0.99845E+00 -0.0007 29 CO,aq 0.77132E-19 -19.1128 0.77132E-19 -19.1128 0.10000E+01 0.0000 30 CO2,aq 0.16530E-08 -8.7817 0.16504E-08 -8.7824 0.99845E+00 -0.0007 31 CO3-2 0.63475E-05 -5.1974 0.39506E-05 -5.4033 0.62238E+00 -0.2059 32 CaCO3,aq 0.11767E-08 -8.9293 0.11767E-08 -8.9293 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.40909E-11 -11.3882 0.35840E-11 -11.4456 0.87609E+00 -0.0575 34 CaCl+ 0.52984E-11 -11.2759 0.46419E-11 -11.3333 0.87609E+00 -0.0575 35 CaCl2,aq 0.13316E-15 -15.8756 0.13316E-15 -15.8756 0.10000E+01 0.0000 36 CaOH+ 0.14788E-07 -7.8301 0.12955E-07 -7.8876 0.87609E+00 -0.0575 37 CaSO4,aq 0.12005E-09 -9.9206 0.12005E-09 -9.9206 0.10000E+01 0.0000 38 HCl,aq 0.28915E-14 -14.5389 0.28915E-14 -14.5389 0.10000E+01 0.0000 43 FeCl+ 0.15798E-16 -16.8014 0.13840E-16 -16.8589 0.87609E+00 -0.0575 46 FeO,aq 0.16480E-09 -9.7830 0.16480E-09 -9.7830 0.10000E+01 0.0000 47 FeOH+ 0.20589E-10 -10.6864 0.18038E-10 -10.7438 0.87609E+00 -0.0575 48 HFeO2- 0.15076E-07 -7.8217 0.13195E-07 -7.8796 0.87522E+00 -0.0579 49 FeO+ 0.11386E-14 -14.9436 0.99748E-15 -15.0011 0.87609E+00 -0.0575 51 FeO2- 0.13656E-07 -7.8647 0.11952E-07 -7.9226 0.87522E+00 -0.0579 52 HFeO2,aq 0.19864E-09 -9.7019 0.19864E-09 -9.7019 0.10000E+01 0.0000 53 H2,aq 0.18633E-08 -8.7297 0.18604E-08 -8.7304 0.99845E+00 -0.0007 54 KCl,aq 0.13503E-09 -9.8696 0.13503E-09 -9.8696 0.10000E+01 0.0000 55 KHSO4,aq 0.36284E-18 -18.4403 0.36284E-18 -18.4403 0.10000E+01 0.0000 56 KOH,aq 0.20164E-06 -6.6954 0.20164E-06 -6.6954 0.10000E+01 0.0000 57 KSO4- 0.17411E-07 -7.7592 0.15238E-07 -7.8171 0.87522E+00 -0.0579 58 MgCO3,aq 0.15239E-12 -12.8170 0.15239E-12 -12.8170 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.21597E-14 -14.6656 0.18921E-14 -14.7230 0.87609E+00 -0.0575 60 MgCl+ 0.24811E-14 -14.6054 0.21737E-14 -14.6628 0.87609E+00 -0.0575 61 MgOH+ 0.42277E-10 -10.3739 0.37039E-10 -10.4313 0.87609E+00 -0.0575 63 MnO,aq 0.59010E-09 -9.2291 0.59010E-09 -9.2291 0.10000E+01 0.0000 64 MnOH+ 0.25702E-09 -9.5900 0.22517E-09 -9.6475 0.87609E+00 -0.0575 65 MnO2-2 0.18425E-11 -11.7346 0.11467E-11 -11.9405 0.62238E+00 -0.2059 66 HMnO2- 0.37513E-10 -10.4258 0.32832E-10 -10.4837 0.87522E+00 -0.0579 69 MnCl+ 0.82589E-14 -14.0831 0.72356E-14 -14.1405 0.87609E+00 -0.0575 70 MnSO4,aq 0.44709E-13 -13.3496 0.44709E-13 -13.3496 0.10000E+01 0.0000 71 NaCl,aq 0.31273E-06 -6.5048 0.31273E-06 -6.5048 0.10000E+01 0.0000 72 NaOH,aq 0.25694E-04 -4.5902 0.25694E-04 -4.5902 0.10000E+01 0.0000 74 OH- 0.50564E-02 -2.2962 0.44212E-02 -2.3545 0.87439E+00 -0.0583 79 HPO3-2 0.27971E-17 -17.5533 0.17409E-17 -17.7592 0.62238E+00 -0.2059 82 H3PO4,aq 0.35865E-16 -16.4453 0.35865E-16 -16.4453 0.10000E+01 0.0000 83 H2PO4- 0.82669E-09 -9.0827 0.72389E-09 -9.1403 0.87565E+00 -0.0577 84 PO4-3 0.52170E-08 -8.2826 0.18747E-08 -8.7271 0.35935E+00 -0.4445 87 H2P2O7-2 0.66017E-19 -19.1803 0.41088E-19 -19.3863 0.62238E+00 -0.2059 88 HP2O7-3 0.17915E-15 -15.7468 0.62781E-16 -16.2022 0.35043E+00 -0.4554 89 P2O7-4 0.72017E-15 -15.1426 0.11477E-15 -15.9402 0.15936E+00 -0.7976 90 H2S,aq 0.47799E-15 -15.3206 0.47725E-15 -15.3213 0.99845E+00 -0.0007 97 SO3-2 0.61357E-14 -14.2121 0.38475E-14 -14.4148 0.62707E+00 -0.2027 98 HSO3- 0.35970E-16 -16.4441 0.31481E-16 -16.5019 0.87522E+00 -0.0579 99 HSO4- 0.22867E-11 -11.6408 0.20043E-11 -11.6980 0.87653E+00 -0.0572 Charge balance for all species = 0.6524E-13 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.1488451E-09 -.9349568E-02 -.9417468E+01 0.0000 2 H2O 0.1000000E+01 0.5550931E+02 0.9993445E+06 0.0000 3 Cl- 0.1379625E-03 0.1382753E-03 0.4898980E+01 5.9657 4 SO4-- 0.2554260E-04 0.2556140E-04 0.2453819E+01 14.9694 5 HCO3- 0.6748178E-05 0.1309853E-04 0.7986982E+00 4.6554 6 HS- 0.1350005E-11 -.1264606E-08 -.4179492E-04 -2.0437 7 Al+++ 0.4745080E-27 0.3909123E-04 0.1054031E+01 1.8720 8 H4SiO4 0.4526833E-03 0.4557171E-02 0.4377199E+03 -3.3442 9 Ca++ 0.3827107E-07 0.5636221E-07 0.2257366E-02 12.1433 10 Mg++ 0.1982035E-10 0.6353873E-10 0.1543715E-05 8.8565 11 Fe++ 0.1168763E-12 0.2911599E-07 0.1624948E-02 6.6274 12 K+ 0.7043793E-04 0.7065712E-04 0.2760977E+01 5.6741 13 Na+ 0.8930092E-02 0.9364935E-02 0.2151533E+03 7.7767 14 Mn++ 0.1569903E-10 0.9022231E-09 0.4953301E-04 8.7557 15 HPO4-- 0.4818974E-06 0.4879411E-06 0.4680062E-01 13.2451 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.2516598E+00 -.9329205E-02 -.2423306E+00 0.0000000E+00 2 H2O 0.5531772E+02 0.5538841E+02 -.7068569E-01 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.4467206E-03 0.2550573E-04 0.4212148E-03 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.4212161E-03 -.1261851E-08 -.4212148E-03 0.0000000E+00 7 Al+++ 0.4956001E-01 0.3900609E-04 0.4952101E-01 0.0000000E+00 8 H4SiO4 0.1582639E+00 0.4547246E-02 0.1537166E+00 0.0000000E+00 9 Ca++ 0.1749549E-01 0.5623946E-07 0.1749543E-01 0.0000000E+00 10 Mg++ 0.1206270E-01 0.6340035E-10 0.1206270E-01 0.0000000E+00 11 Fe++ 0.1083702E-01 0.2905258E-07 0.1083699E-01 0.0000000E+00 12 K+ 0.3226964E-02 0.7050323E-04 0.3156461E-02 0.0000000E+00 13 Na+ 0.1923852E-01 0.9344539E-02 0.9893980E-02 0.0000000E+00 14 Mn++ 0.2635293E-03 0.9002581E-09 0.2635284E-03 0.0000000E+00 15 HPO4-- 0.8994125E-04 0.4868784E-06 0.8945437E-04 0.0000000E+00 Chg. balance for solid moles: -.1667E-16 Mass of aqueous solution: 0.998493E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 15.1990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 0.9894E-02 -2.005 2.594 0.414 15.64 0.9959 andradite 0.9881E-03 -3.005 0.5021 -0.299 3.026 0.1305 grossular 0.5277E-04 -4.278 0.2377E-01 -1.624 0.1433 0.6614E-02 apatite-OH 0.2982E-04 -4.526 0.1498E-01 -1.825 0.9027E-01 0.4760E-02 clinochlore 0.2413E-02 -2.618 1.341 0.127 8.082 0.5101 daphnite 0.1493E-02 -2.826 1.066 0.028 6.422 0.3229 chlorite-Mn 0.5271E-04 -4.278 0.3737E-01 -1.428 0.2252 0.1191E-01 hematite 0.6968E-03 -3.157 0.1113 -0.954 0.6706 0.2109E-01 microcline 0.3156E-02 -2.501 0.8786 -0.056 5.295 0.3432 stilbite 0.1422E-01 -1.847 10.02 1.001 60.41 4.675 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.9493E+00 0.9493E+00 1.0000 -0.023 grossular 0.5070E-01 0.5070E-01 1.0000 -1.295 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.6094E+00 0.6094E+00 1.0000 -0.215 daphnite 0.3773E+00 0.3773E+00 1.0000 -0.423 chlorite-Mn 0.1331E-01 0.1331E-01 1.0000 -1.876 hematite 0.1000E+01 0.1000E+01 1.0000 0.000 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 16.592842 g Volume = 7.022204 cm3 Porosity: 0.8107% V(tot) - V(min): 0.57396E-01 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 15.1990000 g log = 1.1818 Original solution: 1000.0103000 g Original solution / Rock added: 65.79 (Water/Rock Ratio), log = 1.8182 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0203 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.1000E+01 0.9860 0.1006E+01 0.1020E+01 CO2,gas 0.1718E-06 1.0071 0.1766E-06 0.1753E-06 CH4,gas 0.6074E-15 1.0125 0.6275E-15 0.6197E-15 H2,gas 0.2393E-05 1.0005 0.2442E-05 0.2441E-05 H2S,gas 0.1291E-13 0.9960 0.1312E-13 0.1317E-13 S2,gas 0.1061E-35 1.0000 0.1083E-35 0.1083E-35 CO,gas 0.1127E-15 1.0000 0.1149E-15 0.1149E-15 SO3,gas 0.1007E-39 1.0000 0.1028E-39 0.1028E-39 SO2,gas 0.9571E-23 1.0000 0.9765E-23 0.9765E-23 HCl,gas 0.5001E-17 1.0000 0.5102E-17 0.5102E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 16 albite -0.38 -0.38 0.00 0.000 -0.94784E-12 22 andradite 39.01 39.01 0.00 0.000 0.12132E-10 23 grossular 32.73 32.73 0.00 0.000 0.00000E+00 32 apatite-OH -18.15 -18.15 0.00 0.000 0.12132E-10 46 clinochlore 39.07 39.07 0.00 0.000 -0.12132E-10 47 daphnite 28.97 28.97 0.00 0.000 0.36397E-10 48 chlorite-Mn 46.87 46.87 0.00 0.000 0.12132E-10 90 hematite 12.57 12.57 0.00 0.000 -0.90992E-11 116 microcline -2.49 -2.49 0.00 0.000 0.15165E-11 163 stilbite -7.52 -7.52 0.00 0.000 0.15165E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -15.11 -8.45 -2.817 0.14432E+05 -6.753 3 CH4,gas 4.54 -12.36 -16.90 -4.225 0.28859E+05 -15.202 4 H2,gas 8.00 0.69 -7.31 -4.178 0.12484E+05 -5.612 5 H2S,gas -6.23 -21.81 -15.58 -7.791 0.26604E+05 -13.882 6 S2,gas -7.34 -45.00 -37.66 -5.795 0.64311E+05 -35.965 7 CO,gas 3.21 -14.42 -17.64 -5.427 0.30117E+05 -15.940 8 SO3,gas 17.12 -24.57 -41.69 -10.422 0.71180E+05 -39.988 9 SO2,gas 0.83 -23.88 -24.71 -6.589 0.42190E+05 -23.010 10 HCl,gas 5.19 -13.80 -18.99 -9.496 0.32427E+05 -17.292 11 acmite 7.71 7.37 -0.34 -0.035 0.57766E+03 15 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 19 spessartine 24.46 19.98 -4.48 -0.224 0.76473E+04 20 analcite 3.32 2.96 -0.36 -0.040 0.61729E+03 21 andalusite 5.00 0.40 -4.60 -0.460 0.78572E+04 26 annite 20.12 17.40 -2.73 -0.152 0.46575E+04 27 phlogopite 27.06 24.08 -2.98 -0.166 0.50908E+04 29 anorthite 12.71 9.20 -3.51 -0.270 0.59955E+04 35 aragonite 0.97 -2.97 -3.94 -1.312 0.67195E+04 36 brucite 12.57 8.86 -3.71 -0.742 0.63382E+04 37 calcite 0.81 -2.97 -3.78 -1.260 0.64553E+04 38 carnegieite-low 9.02 6.30 -2.72 -0.388 0.46422E+04 39 carnegieite-high 10.09 6.30 -3.79 -0.541 0.64692E+04 40 carpholite-Mg 8.58 5.91 -2.67 -0.178 0.45588E+04 41 carpholite-Fe 6.71 3.68 -3.03 -0.202 0.51729E+04 42 celadonite 5.34 3.03 -2.32 -0.136 0.39541E+04 43 celadonite-Fe 3.88 0.80 -3.08 -0.181 0.52587E+04 44 chrysotile 23.89 19.88 -4.01 -0.334 0.68490E+04 50 chloritoid-Mg 13.20 9.26 -3.94 -0.263 0.67297E+04 51 chloritoid-Fe 9.17 7.03 -2.15 -0.143 0.36649E+04 52 chloritoid-Mn 11.40 9.16 -2.25 -0.150 0.38341E+04 54 coesite -2.38 -3.34 -0.97 -0.323 0.16531E+04 59 corundum 8.38 3.74 -4.64 -0.422 0.79211E+04 61 cristobalite -2.56 -3.34 -0.78 -0.261 0.13384E+04 63 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71234E+04 65 diaspore 2.87 1.87 -1.00 -0.167 0.17103E+04 67 diopside 16.18 14.31 -1.87 -0.187 0.31928E+04 68 hedenbergite 14.21 12.08 -2.13 -0.213 0.36300E+04 75 epidote 24.67 24.28 -0.39 -0.019 0.66373E+03 76 clinozoisite 22.81 19.87 -2.94 -0.133 0.50130E+04 77 epidote-Fe 29.84 28.69 -1.15 -0.060 0.19611E+04 78 fayalite 14.05 9.91 -4.14 -0.591 0.70606E+04 79 ferrosilite 11.15 6.57 -4.58 -0.458 0.78255E+04 83 gibbsite 4.08 1.87 -2.21 -0.315 0.37689E+04 84 glaucophane 22.97 19.11 -3.86 -0.104 0.65931E+04 85 glaucophane-Fe 17.28 12.43 -4.85 -0.131 0.82808E+04 87 greenalite 16.14 13.19 -2.95 -0.245 0.50297E+04 91 heulandite -5.83 -7.52 -1.69 -0.077 0.28938E+04 95 jadeite 4.22 2.96 -1.25 -0.125 0.21428E+04 96 julgoldite 70.43 66.90 -3.53 -0.092 0.60302E+04 97 kalsilite 7.58 4.20 -3.38 -0.483 0.57747E+04 98 kaolinite -1.33 -2.94 -1.61 -0.147 0.27517E+04 99 kyanite 4.88 0.40 -4.48 -0.448 0.76431E+04 101 laumontite 2.88 2.51 -0.37 -0.025 0.63663E+03 102 lawsonite 9.62 9.20 -0.42 -0.028 0.71218E+03 103 leucite 4.12 0.86 -3.26 -0.326 0.55683E+04 105 lizardite 23.24 19.88 -3.36 -0.280 0.57416E+04 107 magnetite 20.09 19.19 -0.89 -0.073 0.15262E+04 108 minnesotaite 10.39 6.51 -3.88 -0.228 0.66297E+04 110 magnesioferrite 26.21 21.42 -4.79 -0.391 0.81782E+04 113 margarite 17.32 12.94 -4.38 -0.175 0.74797E+04 120 muscovite 2.58 1.26 -1.32 -0.078 0.22622E+04 121 paragonite 4.24 3.36 -0.88 -0.052 0.15013E+04 122 nepheline 8.34 6.30 -2.03 -0.291 0.34746E+04 128 periclase-Fe 11.63 6.63 -5.00 -1.250 0.85360E+04 134 phlogopite-Na 29.65 26.19 -3.46 -0.192 0.59096E+04 136 prehnite 19.37 18.00 -1.37 -0.081 0.23457E+04 137 prehnite-Fe 22.50 22.41 -0.09 -0.005 0.15145E+03 138 pumpellyite-Fe 46.27 44.50 -1.77 -0.039 0.30287E+04 139 pumpellyite-Mg 48.99 46.72 -2.27 -0.050 0.38762E+04 145 pyroxmangite 7.40 5.41 -1.99 -0.397 0.33930E+04 146 pyrophyllite -6.18 -9.63 -3.46 -0.216 0.59027E+04 147 quartz -2.99 -3.34 -0.35 -0.118 0.60576E+03 152 rhodonite 7.45 5.41 -2.03 -0.407 0.34733E+04 153 sanidine -1.28 -2.49 -1.21 -0.093 0.20677E+04 156 sillimanite 5.26 0.40 -4.86 -0.486 0.83012E+04 164 stilpnomelane-Fe 13.02 12.96 -0.05 -0.002 0.89665E+02 165 stilpnomelane-Mg 27.44 24.11 -3.33 -0.099 0.56880E+04 171 talc 16.49 13.19 -3.30 -0.194 0.56317E+04 174 tephroite 18.09 14.17 -3.92 -0.560 0.66908E+04 177 topaz-H 4.62 0.40 -4.22 -0.384 0.72032E+04 178 tridymite -2.63 -3.34 -0.72 -0.239 0.12257E+04 187 wairakite 3.95 2.51 -1.44 -0.085 0.24586E+04 188 walstromite 11.51 8.80 -2.71 -0.542 0.46274E+04 189 wollastonite 10.46 8.80 -1.66 -0.332 0.28379E+04 190 pseudo-wollastonite 11.00 8.80 -2.20 -0.440 0.37577E+04 191 zoisite 22.85 19.87 -2.98 -0.135 0.50870E+04 192 akaganeite 7.75 6.28 -1.47 -0.318 0.25125E+04 193 beidellite-Ca -1.65 -5.91 -4.26 -0.264 0.72775E+04 195 beidellite-K -1.52 -6.04 -4.52 -0.277 0.77156E+04 196 beidellite-Mg -1.79 -6.45 -4.66 -0.288 0.79573E+04 197 beidellite-Na -1.34 -5.35 -4.00 -0.245 0.68348E+04 199 chalcedony -2.80 -3.34 -0.54 -0.181 0.92506E+03 201 montmorillonite-Ca -2.29 -5.32 -3.03 -0.188 0.51796E+04 202 montmorillonite-K -2.24 -5.46 -3.22 -0.197 0.54959E+04 203 montmorillonite-Mg -2.48 -5.87 -3.39 -0.210 0.57826E+04 204 montmorillonite-Na -2.04 -4.76 -2.72 -0.167 0.46507E+04 205 nontronite-Ca 3.21 2.91 -0.30 -0.019 0.51254E+03 206 nontronite-H 2.53 0.91 -1.62 -0.109 0.27695E+04 207 nontronite-K 3.34 2.78 -0.56 -0.036 0.95197E+03 208 nontronite-Mg 3.07 2.37 -0.70 -0.046 0.11996E+04 209 nontronite-Na 3.52 3.48 -0.04 -0.003 0.72846E+02 224 tobermorite 9.82 6.77 -3.05 -0.833 0.52110E+04 233 boehmite 4.41 1.87 -2.53 -0.422 0.43272E+04 235 ferrous-oxide 9.81 6.63 -3.18 -0.796 0.54369E+04 240 silica-amorphous -2.09 -3.34 -1.25 -0.418 0.21392E+04 242 an20ab80 2.02 1.53 -0.49 -0.037 0.82825E+03 243 an25ab75 2.65 2.01 -0.63 -0.049 0.10823E+04 244 an30ab70 3.28 2.49 -0.79 -0.061 0.13459E+04 245 tr.625ac.25prg.125 45.16 40.43 -4.73 -0.127 0.80804E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 0.4000000 g Current total amount of reactant added: 15.1990000 g New total amount of reactant added: 15.5990000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.6618E-13 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 9 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 15.5990000 Water: Moles liquid = 0.5538E+02 kg liquid = 0.9978E+00 Moles total = 0.5531E+02 kg total = 0.9965E+00 Activity = 1.0000 Stoichiometric ionic strength = .5039550E-02 Osmotic coef. = 0.9622 True ionic strength = .9084458E-02 Chg. balance for total moles = 0.6618E-13 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.14952E-09 -9.8253 0.13123E-09 -9.8820 0.87773E+00 -0.0566 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13797E-03 -3.8602 0.12072E-03 -3.9182 0.87496E+00 -0.0580 4 SO4-- 0.25544E-04 -4.5927 0.15898E-04 -4.7987 0.62237E+00 -0.2060 5 HCO3- 0.67595E-05 -5.1701 0.59188E-05 -5.2278 0.87563E+00 -0.0577 6 HS- 0.15242E-11 -11.8170 0.13337E-11 -11.8749 0.87503E+00 -0.0580 7 Al+++ 0.44809E-27 -27.3486 0.15656E-27 -27.8053 0.34939E+00 -0.4567 8 H4SiO4 0.46358E-03 -3.3339 0.46358E-03 -3.3339 0.10000E+01 0.0000 9 Ca++ 0.37821E-07 -7.4223 0.23449E-07 -7.6299 0.62000E+00 -0.2076 10 Mg++ 0.20309E-10 -10.6923 0.12561E-10 -10.9010 0.61852E+00 -0.2086 11 Fe++ 0.11976E-12 -12.9217 0.74113E-13 -13.1301 0.61887E+00 -0.2084 12 K+ 0.70840E-04 -4.1497 0.62038E-04 -4.2073 0.87575E+00 -0.0576 13 Na+ 0.89811E-02 -2.0467 0.78575E-02 -2.1047 0.87489E+00 -0.0580 14 Mn++ 0.16086E-10 -10.7936 0.99593E-11 -11.0018 0.61914E+00 -0.2082 15 HPO4-- 0.49576E-06 -6.3047 0.30857E-06 -6.5106 0.62242E+00 -0.2059 16 HSiO3- 0.37697E-02 -2.4237 0.32984E-02 -2.4817 0.87496E+00 -0.0580 17 Ca(HSiO3)+ 0.20111E-08 -8.6966 0.17614E-08 -8.7541 0.87584E+00 -0.0576 18 Mg(HSiO3)+ 0.13407E-11 -11.8727 0.11743E-11 -11.9302 0.87584E+00 -0.0576 19 NaHSiO3,aq 0.41917E-03 -3.3776 0.41917E-03 -3.3776 0.10000E+01 0.0000 20 AlO+ 0.14120E-14 -14.8502 0.12367E-14 -14.9077 0.87584E+00 -0.0576 22 HAlO2,aq 0.18767E-08 -8.7266 0.18767E-08 -8.7266 0.10000E+01 0.0000 23 AlO2- 0.36212E-04 -4.4411 0.31654E-04 -4.4996 0.87413E+00 -0.0584 24 CH4,aq 0.48310E-18 -18.3160 0.48235E-18 -18.3166 0.99845E+00 -0.0007 29 CO,aq 0.79888E-19 -19.0975 0.79888E-19 -19.0975 0.10000E+01 0.0000 30 CO2,aq 0.16623E-08 -8.7793 0.16597E-08 -8.7800 0.99845E+00 -0.0007 31 CO3-2 0.63368E-05 -5.1981 0.39394E-05 -5.4046 0.62168E+00 -0.2064 32 CaCO3,aq 0.11583E-08 -8.9362 0.11583E-08 -8.9362 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.40450E-11 -11.3931 0.35428E-11 -11.4507 0.87584E+00 -0.0576 34 CaCl+ 0.52303E-11 -11.2815 0.45810E-11 -11.3390 0.87584E+00 -0.0576 35 CaCl2,aq 0.13138E-15 -15.8815 0.13138E-15 -15.8815 0.10000E+01 0.0000 36 CaOH+ 0.14540E-07 -7.8374 0.12735E-07 -7.8950 0.87584E+00 -0.0576 37 CaSO4,aq 0.11838E-09 -9.9267 0.11838E-09 -9.9267 0.10000E+01 0.0000 38 HCl,aq 0.29030E-14 -14.5372 0.29030E-14 -14.5372 0.10000E+01 0.0000 43 FeCl+ 0.16169E-16 -16.7913 0.14161E-16 -16.8489 0.87584E+00 -0.0576 46 FeO,aq 0.16725E-09 -9.7766 0.16725E-09 -9.7766 0.10000E+01 0.0000 47 FeOH+ 0.20989E-10 -10.6780 0.18383E-10 -10.7356 0.87584E+00 -0.0576 48 HFeO2- 0.15240E-07 -7.8170 0.13335E-07 -7.8750 0.87496E+00 -0.0580 49 FeO+ 0.11437E-14 -14.9417 0.10017E-14 -14.9993 0.87584E+00 -0.0576 51 FeO2- 0.13602E-07 -7.8664 0.11901E-07 -7.9244 0.87496E+00 -0.0580 52 HFeO2,aq 0.19864E-09 -9.7019 0.19864E-09 -9.7019 0.10000E+01 0.0000 53 H2,aq 0.19190E-08 -8.7169 0.19160E-08 -8.7176 0.99845E+00 -0.0007 54 KCl,aq 0.13573E-09 -9.8673 0.13573E-09 -9.8673 0.10000E+01 0.0000 55 KHSO4,aq 0.36595E-18 -18.4366 0.36595E-18 -18.4366 0.10000E+01 0.0000 56 KOH,aq 0.20188E-06 -6.6949 0.20188E-06 -6.6949 0.10000E+01 0.0000 57 KSO4- 0.17491E-07 -7.7572 0.15304E-07 -7.8152 0.87496E+00 -0.0580 58 MgCO3,aq 0.15553E-12 -12.8082 0.15553E-12 -12.8082 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.22141E-14 -14.6548 0.19392E-14 -14.7124 0.87584E+00 -0.0576 60 MgCl+ 0.25394E-14 -14.5953 0.22241E-14 -14.6528 0.87584E+00 -0.0576 61 MgOH+ 0.43099E-10 -10.3655 0.37748E-10 -10.4231 0.87584E+00 -0.0576 63 MnO,aq 0.59886E-09 -9.2227 0.59886E-09 -9.2227 0.10000E+01 0.0000 64 MnOH+ 0.26201E-09 -9.5817 0.22948E-09 -9.6393 0.87584E+00 -0.0576 65 MnO2-2 0.18563E-11 -11.7314 0.11540E-11 -11.9378 0.62168E+00 -0.2064 66 HMnO2- 0.37920E-10 -10.4211 0.33179E-10 -10.4791 0.87496E+00 -0.0580 69 MnCl+ 0.84529E-14 -14.0730 0.74034E-14 -14.1306 0.87584E+00 -0.0576 70 MnSO4,aq 0.45708E-13 -13.3400 0.45708E-13 -13.3400 0.10000E+01 0.0000 71 NaCl,aq 0.31434E-06 -6.5026 0.31434E-06 -6.5026 0.10000E+01 0.0000 72 NaOH,aq 0.25725E-04 -4.5897 0.25725E-04 -4.5897 0.10000E+01 0.0000 74 OH- 0.50365E-02 -2.2979 0.44026E-02 -2.3563 0.87413E+00 -0.0584 79 HPO3-2 0.29637E-17 -17.5282 0.18425E-17 -17.7346 0.62168E+00 -0.2064 82 H3PO4,aq 0.37168E-16 -16.4298 0.37168E-16 -16.4298 0.10000E+01 0.0000 83 H2PO4- 0.85336E-09 -9.0689 0.74703E-09 -9.1267 0.87540E+00 -0.0578 84 PO4-3 0.53515E-08 -8.2715 0.19184E-08 -8.7171 0.35848E+00 -0.4455 87 H2P2O7-2 0.70385E-19 -19.1525 0.43757E-19 -19.3590 0.62168E+00 -0.2064 88 HP2O7-3 0.19047E-15 -15.7202 0.66577E-16 -16.1767 0.34953E+00 -0.4565 89 P2O7-4 0.76392E-15 -15.1170 0.12119E-15 -15.9165 0.15865E+00 -0.7996 90 H2S,aq 0.54179E-15 -15.2662 0.54095E-15 -15.2668 0.99845E+00 -0.0007 97 SO3-2 0.63193E-14 -14.1993 0.39583E-14 -14.4025 0.62638E+00 -0.2032 98 HSO3- 0.37173E-16 -16.4298 0.32525E-16 -16.4878 0.87496E+00 -0.0580 99 HSO4- 0.22945E-11 -11.6393 0.20106E-11 -11.6967 0.87628E+00 -0.0574 Charge balance for all species = 0.6542E-13 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.1495157E-09 -.9402670E-02 -.9470876E+01 0.0000 2 H2O 0.1000000E+01 0.5550920E+02 0.9993341E+06 0.0000 3 Cl- 0.1379670E-03 0.1382815E-03 0.4899158E+01 5.9637 4 SO4-- 0.2554367E-04 0.2556253E-04 0.2453906E+01 14.9652 5 HCO3- 0.6759526E-05 0.1309911E-04 0.7987272E+00 4.6542 6 HS- 0.1524195E-11 -.1243791E-08 -.4110665E-04 -1.9930 7 Al+++ 0.4480864E-27 0.3621405E-04 0.9764442E+00 1.8405 8 H4SiO4 0.4635769E-03 0.4652479E-02 0.4468705E+03 -3.3339 9 Ca++ 0.3782123E-07 0.5565804E-07 0.2229144E-02 12.1340 10 Mg++ 0.2030871E-10 0.6490839E-10 0.1576979E-05 8.8629 11 Fe++ 0.1197557E-12 0.2922908E-07 0.1631245E-02 6.6338 12 K+ 0.7083989E-04 0.7105940E-04 0.2776673E+01 5.6746 13 Na+ 0.8981095E-02 0.9426305E-02 0.2165613E+03 7.7772 14 Mn++ 0.1608576E-10 0.9167905E-09 0.5033235E-04 8.7621 15 HPO4-- 0.4957632E-06 0.5019681E-06 0.4814560E-01 13.2533 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.2582832E+00 -.9381771E-02 -.2489015E+00 0.0000000E+00 2 H2O 0.5531271E+02 0.5538582E+02 -.7310776E-01 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.4578059E-03 0.2550571E-04 0.4323002E-03 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.4323015E-03 -.1241026E-08 -.4323002E-03 0.0000000E+00 7 Al+++ 0.5086431E-01 0.3613356E-04 0.5082817E-01 0.0000000E+00 8 H4SiO4 0.1624290E+00 0.4642138E-02 0.1577869E+00 0.0000000E+00 9 Ca++ 0.1795555E-01 0.5553433E-07 0.1795549E-01 0.0000000E+00 10 Mg++ 0.1238016E-01 0.6476412E-10 0.1238016E-01 0.0000000E+00 11 Fe++ 0.1112222E-01 0.2916411E-07 0.1112219E-01 0.0000000E+00 12 K+ 0.3311890E-02 0.7090146E-04 0.3240988E-02 0.0000000E+00 13 Na+ 0.1974062E-01 0.9405354E-02 0.1033526E-01 0.0000000E+00 14 Mn++ 0.2704648E-03 0.9147528E-09 0.2704638E-03 0.0000000E+00 15 HPO4-- 0.9230828E-04 0.5008524E-06 0.9180743E-04 0.0000000E+00 Chg. balance for solid moles: 0.4472E-17 Mass of aqueous solution: 0.998457E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 15.5990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 0.1034E-01 -1.986 2.710 0.433 15.92 1.040 andradite 0.1045E-02 -2.981 0.5311 -0.275 3.120 0.1380 grossular 0.5192E-04 -4.285 0.2339E-01 -1.631 0.1374 0.6507E-02 apatite-OH 0.3060E-04 -4.514 0.1537E-01 -1.813 0.9029E-01 0.4885E-02 clinochlore 0.2476E-02 -2.606 1.376 0.139 8.083 0.5235 daphnite 0.1533E-02 -2.815 1.094 0.039 6.423 0.3314 chlorite-Mn 0.5409E-04 -4.267 0.3835E-01 -1.416 0.2252 0.1222E-01 hematite 0.6840E-03 -3.165 0.1092 -0.962 0.6416 0.2070E-01 microcline 0.3241E-02 -2.489 0.9021 -0.045 5.298 0.3524 stilbite 0.1451E-01 -1.838 10.23 1.010 60.06 4.770 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.9527E+00 0.9527E+00 1.0000 -0.021 grossular 0.4732E-01 0.4732E-01 1.0000 -1.325 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.6094E+00 0.6094E+00 1.0000 -0.215 daphnite 0.3773E+00 0.3773E+00 1.0000 -0.423 chlorite-Mn 0.1331E-01 0.1331E-01 1.0000 -1.876 hematite 0.1000E+01 0.1000E+01 1.0000 0.000 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 17.025896 g Volume = 7.199672 cm3 Porosity: 0.5515% V(tot) - V(min): 0.39928E-01 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 15.5990000 g log = 1.1931 Original solution: 1000.0103000 g Original solution / Rock added: 64.11 (Water/Rock Ratio), log = 1.8069 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0203 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.1000E+01 0.9860 0.1006E+01 0.1020E+01 CO2,gas 0.1728E-06 1.0071 0.1776E-06 0.1763E-06 CH4,gas 0.6872E-15 1.0125 0.7100E-15 0.7012E-15 H2,gas 0.2464E-05 1.0005 0.2516E-05 0.2514E-05 H2S,gas 0.1463E-13 0.9960 0.1487E-13 0.1493E-13 S2,gas 0.1286E-35 1.0000 0.1312E-35 0.1312E-35 CO,gas 0.1167E-15 1.0000 0.1190E-15 0.1190E-15 SO3,gas 0.1015E-39 1.0000 0.1035E-39 0.1035E-39 SO2,gas 0.9930E-23 1.0000 0.1013E-22 0.1013E-22 HCl,gas 0.5021E-17 1.0000 0.5122E-17 0.5122E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 16 albite -0.38 -0.38 0.00 0.000 0.11184E-10 22 andradite 39.01 39.01 0.00 0.000 -0.24265E-10 23 grossular 32.73 32.73 0.00 0.000 -0.12132E-10 32 apatite-OH -18.15 -18.15 0.00 0.000 0.12132E-10 46 clinochlore 39.07 39.07 0.00 0.000 0.48529E-10 47 daphnite 28.97 28.97 0.00 0.000 0.42463E-10 48 chlorite-Mn 46.87 46.87 0.00 0.000 0.12132E-10 90 hematite 12.57 12.57 0.00 0.000 -0.30331E-11 116 microcline -2.49 -2.49 0.00 0.000 0.15165E-11 163 stilbite -7.52 -7.52 0.00 0.000 0.15165E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -15.11 -8.45 -2.817 0.14427E+05 -6.751 3 CH4,gas 4.54 -12.30 -16.85 -4.212 0.28767E+05 -15.149 4 H2,gas 8.00 0.70 -7.30 -4.170 0.12462E+05 -5.599 5 H2S,gas -6.23 -21.76 -15.53 -7.763 0.26511E+05 -13.828 6 S2,gas -7.34 -44.92 -37.58 -5.782 0.64169E+05 -35.882 7 CO,gas 3.21 -14.41 -17.62 -5.423 0.30091E+05 -15.924 8 SO3,gas 17.12 -24.56 -41.68 -10.421 0.71174E+05 -39.985 9 SO2,gas 0.83 -23.86 -24.69 -6.585 0.42163E+05 -22.994 10 HCl,gas 5.19 -13.80 -18.99 -9.495 0.32424E+05 -17.291 11 acmite 7.71 7.39 -0.32 -0.033 0.54151E+03 15 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 19 spessartine 24.46 19.97 -4.49 -0.225 0.76691E+04 20 analcite 3.32 2.95 -0.37 -0.041 0.63492E+03 21 andalusite 5.00 0.35 -4.65 -0.465 0.79472E+04 26 annite 20.12 17.41 -2.71 -0.150 0.46247E+04 27 phlogopite 27.06 24.10 -2.96 -0.165 0.50580E+04 29 anorthite 12.71 9.15 -3.56 -0.274 0.60837E+04 35 aragonite 0.97 -2.98 -3.94 -1.314 0.67312E+04 36 brucite 12.57 8.86 -3.71 -0.741 0.63273E+04 37 calcite 0.81 -2.98 -3.79 -1.262 0.64670E+04 38 carnegieite-low 9.02 6.28 -2.74 -0.391 0.46775E+04 39 carnegieite-high 10.09 6.28 -3.81 -0.544 0.65045E+04 40 carpholite-Mg 8.58 5.88 -2.71 -0.180 0.46202E+04 41 carpholite-Fe 6.71 3.65 -3.07 -0.204 0.52343E+04 42 celadonite 5.34 3.04 -2.30 -0.135 0.39255E+04 43 celadonite-Fe 3.88 0.81 -3.06 -0.180 0.52302E+04 44 chrysotile 23.89 19.92 -3.97 -0.331 0.67809E+04 50 chloritoid-Mg 13.20 9.21 -3.99 -0.266 0.68087E+04 51 chloritoid-Fe 9.17 6.98 -2.19 -0.146 0.37439E+04 52 chloritoid-Mn 11.40 9.11 -2.29 -0.153 0.39131E+04 54 coesite -2.38 -3.33 -0.96 -0.319 0.16354E+04 59 corundum 8.38 3.68 -4.70 -0.427 0.80286E+04 61 cristobalite -2.56 -3.33 -0.77 -0.258 0.13208E+04 63 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71234E+04 65 diaspore 2.87 1.84 -1.03 -0.172 0.17641E+04 67 diopside 16.18 14.33 -1.85 -0.185 0.31625E+04 68 hedenbergite 14.21 12.10 -2.11 -0.211 0.35997E+04 75 epidote 24.67 24.23 -0.44 -0.021 0.75015E+03 76 clinozoisite 22.81 19.79 -3.02 -0.137 0.51532E+04 77 epidote-Fe 29.84 28.67 -1.17 -0.061 0.19937E+04 78 fayalite 14.05 9.93 -4.11 -0.587 0.70211E+04 79 ferrosilite 11.15 6.60 -4.55 -0.455 0.77683E+04 83 gibbsite 4.08 1.84 -2.24 -0.320 0.38226E+04 84 glaucophane 22.97 19.15 -3.82 -0.103 0.65251E+04 85 glaucophane-Fe 17.28 12.47 -4.81 -0.130 0.82128E+04 87 greenalite 16.14 13.23 -2.91 -0.242 0.49617E+04 91 heulandite -5.83 -7.52 -1.69 -0.077 0.28938E+04 95 jadeite 4.22 2.95 -1.27 -0.127 0.21604E+04 96 julgoldite 70.43 66.93 -3.49 -0.091 0.59661E+04 97 kalsilite 7.58 4.18 -3.40 -0.486 0.58099E+04 98 kaolinite -1.33 -2.99 -1.65 -0.150 0.28240E+04 99 kyanite 4.88 0.35 -4.53 -0.453 0.77331E+04 101 laumontite 2.88 2.48 -0.40 -0.027 0.68953E+03 102 lawsonite 9.62 9.15 -0.47 -0.031 0.80035E+03 103 leucite 4.12 0.85 -3.27 -0.327 0.55860E+04 105 lizardite 23.24 19.92 -3.32 -0.277 0.56736E+04 107 magnetite 20.09 19.20 -0.89 -0.072 0.15152E+04 108 minnesotaite 10.39 6.57 -3.82 -0.225 0.65263E+04 110 magnesioferrite 26.21 21.43 -4.78 -0.390 0.81673E+04 113 margarite 17.32 12.83 -4.50 -0.180 0.76754E+04 120 muscovite 2.58 1.19 -1.39 -0.082 0.23697E+04 121 paragonite 4.24 3.30 -0.94 -0.055 0.16088E+04 122 nepheline 8.34 6.28 -2.06 -0.294 0.35098E+04 128 periclase-Fe 11.63 6.63 -4.99 -1.248 0.85250E+04 134 phlogopite-Na 29.65 26.20 -3.44 -0.191 0.58768E+04 136 prehnite 19.37 17.95 -1.42 -0.084 0.24321E+04 137 prehnite-Fe 22.50 22.39 -0.11 -0.006 0.18408E+03 138 pumpellyite-Fe 46.27 44.37 -1.90 -0.042 0.32444E+04 139 pumpellyite-Mg 48.99 46.60 -2.40 -0.053 0.40918E+04 145 pyroxmangite 7.40 5.43 -1.97 -0.394 0.33644E+04 146 pyrophyllite -6.18 -9.65 -3.48 -0.217 0.59397E+04 147 quartz -2.99 -3.33 -0.34 -0.115 0.58813E+03 152 rhodonite 7.45 5.43 -2.02 -0.403 0.34447E+04 153 sanidine -1.28 -2.49 -1.21 -0.093 0.20677E+04 156 sillimanite 5.26 0.35 -4.91 -0.491 0.83911E+04 164 stilpnomelane-Fe 13.02 13.02 0.00 0.000 0.10578E+01 165 stilpnomelane-Mg 27.44 24.16 -3.28 -0.098 0.55994E+04 171 talc 16.49 13.25 -3.24 -0.190 0.55284E+04 174 tephroite 18.09 14.19 -3.90 -0.556 0.66513E+04 177 topaz-H 4.62 0.35 -4.27 -0.388 0.72931E+04 178 tridymite -2.63 -3.33 -0.71 -0.236 0.12081E+04 187 wairakite 3.95 2.48 -1.47 -0.087 0.25115E+04 188 walstromite 11.51 8.80 -2.71 -0.542 0.46257E+04 189 wollastonite 10.46 8.80 -1.66 -0.332 0.28361E+04 190 pseudo-wollastonite 11.00 8.80 -2.20 -0.440 0.37559E+04 191 zoisite 22.85 19.79 -3.06 -0.139 0.52272E+04 192 akaganeite 7.75 6.28 -1.47 -0.318 0.25125E+04 193 beidellite-Ca -1.65 -5.94 -4.30 -0.266 0.73407E+04 195 beidellite-K -1.52 -6.07 -4.55 -0.279 0.77759E+04 196 beidellite-Mg -1.79 -6.48 -4.69 -0.290 0.80161E+04 197 beidellite-Na -1.34 -5.38 -4.04 -0.247 0.68951E+04 199 chalcedony -2.80 -3.33 -0.53 -0.177 0.90743E+03 201 montmorillonite-Ca -2.29 -5.33 -3.04 -0.188 0.51979E+04 202 montmorillonite-K -2.24 -5.46 -3.23 -0.198 0.55112E+04 203 montmorillonite-Mg -2.48 -5.87 -3.39 -0.210 0.57965E+04 204 montmorillonite-Na -2.04 -4.77 -2.73 -0.167 0.46661E+04 205 nontronite-Ca 3.21 2.94 -0.27 -0.018 0.46819E+03 206 nontronite-H 2.53 0.94 -1.59 -0.107 0.27225E+04 207 nontronite-K 3.34 2.81 -0.53 -0.034 0.90471E+03 208 nontronite-Mg 3.07 2.40 -0.67 -0.044 0.11509E+04 209 nontronite-Na 3.52 3.50 -0.01 -0.001 0.25588E+02 224 tobermorite 9.82 6.77 -3.05 -0.832 0.52066E+04 233 boehmite 4.41 1.84 -2.57 -0.428 0.43810E+04 235 ferrous-oxide 9.81 6.63 -3.18 -0.794 0.54260E+04 240 silica-amorphous -2.09 -3.33 -1.24 -0.414 0.21216E+04 242 an20ab80 2.02 1.52 -0.50 -0.038 0.84589E+03 243 an25ab75 2.65 2.00 -0.65 -0.050 0.11043E+04 244 an30ab70 3.28 2.48 -0.80 -0.062 0.13724E+04 245 tr.625ac.25prg.125 45.16 40.51 -4.65 -0.125 0.79423E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 0.4000000 g Current total amount of reactant added: 15.5990000 g New total amount of reactant added: 15.9990000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.6621E-13 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 9 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 15.9990000 Water: Moles liquid = 0.5538E+02 kg liquid = 0.9977E+00 Moles total = 0.5531E+02 kg total = 0.9964E+00 Activity = 1.0000 Stoichiometric ionic strength = .5058685E-02 Osmotic coef. = 0.9621 True ionic strength = .9135893E-02 Chg. balance for total moles = 0.6621E-13 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.15020E-09 -9.8233 0.13180E-09 -9.8801 0.87749E+00 -0.0568 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13797E-03 -3.8602 0.12069E-03 -3.9183 0.87471E+00 -0.0581 4 SO4-- 0.25545E-04 -4.5927 0.15880E-04 -4.7991 0.62167E+00 -0.2064 5 HCO3- 0.67711E-05 -5.1693 0.59273E-05 -5.2271 0.87538E+00 -0.0578 6 HS- 0.17179E-11 -11.7650 0.15028E-11 -11.8231 0.87478E+00 -0.0581 7 Al+++ 0.42365E-27 -27.3730 0.14764E-27 -27.8308 0.34850E+00 -0.4578 8 H4SiO4 0.47459E-03 -3.3237 0.47459E-03 -3.3237 0.10000E+01 0.0000 9 Ca++ 0.37386E-07 -7.4273 0.23153E-07 -7.6354 0.61929E+00 -0.2081 10 Mg++ 0.20807E-10 -10.6818 0.12855E-10 -10.8909 0.61781E+00 -0.2091 11 Fe++ 0.12269E-12 -12.9112 0.75845E-13 -13.1201 0.61816E+00 -0.2089 12 K+ 0.71242E-04 -4.1473 0.62372E-04 -4.2050 0.87550E+00 -0.0577 13 Na+ 0.90321E-02 -2.0442 0.78999E-02 -2.1024 0.87464E+00 -0.0582 14 Mn++ 0.16480E-10 -10.7830 0.10192E-10 -10.9917 0.61843E+00 -0.2087 15 HPO4-- 0.50986E-06 -6.2926 0.31699E-06 -6.4990 0.62172E+00 -0.2064 16 HSiO3- 0.38438E-02 -2.4152 0.33623E-02 -2.4734 0.87471E+00 -0.0581 17 Ca(HSiO3)+ 0.20247E-08 -8.6936 0.17728E-08 -8.7513 0.87560E+00 -0.0577 18 Mg(HSiO3)+ 0.13990E-11 -11.8542 0.12250E-11 -11.9119 0.87560E+00 -0.0577 19 NaHSiO3,aq 0.42959E-03 -3.3669 0.42959E-03 -3.3669 0.10000E+01 0.0000 20 AlO+ 0.13206E-14 -14.8792 0.11563E-14 -14.9369 0.87560E+00 -0.0577 22 HAlO2,aq 0.17472E-08 -8.7577 0.17472E-08 -8.7577 0.10000E+01 0.0000 23 AlO2- 0.33579E-04 -4.4739 0.29344E-04 -4.5325 0.87388E+00 -0.0585 24 CH4,aq 0.54570E-18 -18.2630 0.54485E-18 -18.2637 0.99844E+00 -0.0007 29 CO,aq 0.82712E-19 -19.0824 0.82712E-19 -19.0824 0.10000E+01 0.0000 30 CO2,aq 0.16719E-08 -8.7768 0.16693E-08 -8.7775 0.99844E+00 -0.0007 31 CO3-2 0.63258E-05 -5.1989 0.39282E-05 -5.4058 0.62098E+00 -0.2069 32 CaCO3,aq 0.11404E-08 -8.9429 0.11404E-08 -8.9429 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.40007E-11 -11.3979 0.35030E-11 -11.4556 0.87560E+00 -0.0577 34 CaCl+ 0.51644E-11 -11.2870 0.45219E-11 -11.3447 0.87560E+00 -0.0577 35 CaCl2,aq 0.12965E-15 -15.8872 0.12965E-15 -15.8872 0.10000E+01 0.0000 36 CaOH+ 0.14299E-07 -7.8447 0.12520E-07 -7.9024 0.87560E+00 -0.0577 37 CaSO4,aq 0.11675E-09 -9.9327 0.11675E-09 -9.9327 0.10000E+01 0.0000 38 HCl,aq 0.29147E-14 -14.5354 0.29147E-14 -14.5354 0.10000E+01 0.0000 43 FeCl+ 0.16547E-16 -16.7813 0.14488E-16 -16.8390 0.87560E+00 -0.0577 46 FeO,aq 0.16970E-09 -9.7703 0.16970E-09 -9.7703 0.10000E+01 0.0000 47 FeOH+ 0.21393E-10 -10.6697 0.18732E-10 -10.7274 0.87560E+00 -0.0577 48 HFeO2- 0.15401E-07 -7.8124 0.13472E-07 -7.8706 0.87471E+00 -0.0581 49 FeO+ 0.11489E-14 -14.9397 0.10060E-14 -14.9974 0.87560E+00 -0.0577 51 FeO2- 0.13548E-07 -7.8681 0.11850E-07 -7.9263 0.87471E+00 -0.0581 52 HFeO2,aq 0.19864E-09 -9.7019 0.19864E-09 -9.7019 0.10000E+01 0.0000 53 H2,aq 0.19756E-08 -8.7043 0.19725E-08 -8.7050 0.99844E+00 -0.0007 54 KCl,aq 0.13643E-09 -9.8651 0.13643E-09 -9.8651 0.10000E+01 0.0000 55 KHSO4,aq 0.36910E-18 -18.4329 0.36910E-18 -18.4329 0.10000E+01 0.0000 56 KOH,aq 0.20210E-06 -6.6944 0.20210E-06 -6.6944 0.10000E+01 0.0000 57 KSO4- 0.17572E-07 -7.7552 0.15370E-07 -7.8133 0.87471E+00 -0.0581 58 MgCO3,aq 0.15871E-12 -12.7994 0.15871E-12 -12.7994 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.22697E-14 -14.6440 0.19874E-14 -14.7017 0.87560E+00 -0.0577 60 MgCl+ 0.25988E-14 -14.5852 0.22755E-14 -14.6429 0.87560E+00 -0.0577 61 MgOH+ 0.43929E-10 -10.3572 0.38464E-10 -10.4149 0.87560E+00 -0.0577 63 MnO,aq 0.60762E-09 -9.2164 0.60762E-09 -9.2164 0.10000E+01 0.0000 64 MnOH+ 0.26706E-09 -9.5734 0.23384E-09 -9.6311 0.87560E+00 -0.0577 65 MnO2-2 0.18694E-11 -11.7283 0.11609E-11 -11.9352 0.62098E+00 -0.2069 66 HMnO2- 0.38321E-10 -10.4166 0.33520E-10 -10.4747 0.87471E+00 -0.0581 69 MnCl+ 0.86506E-14 -14.0630 0.75744E-14 -14.1207 0.87560E+00 -0.0577 70 MnSO4,aq 0.46726E-13 -13.3304 0.46726E-13 -13.3304 0.10000E+01 0.0000 71 NaCl,aq 0.31596E-06 -6.5004 0.31596E-06 -6.5004 0.10000E+01 0.0000 72 NaOH,aq 0.25753E-04 -4.5892 0.25753E-04 -4.5892 0.10000E+01 0.0000 74 OH- 0.50165E-02 -2.2996 0.43838E-02 -2.3582 0.87388E+00 -0.0585 79 HPO3-2 0.31378E-17 -17.5034 0.19485E-17 -17.7103 0.62098E+00 -0.2069 82 H3PO4,aq 0.38511E-16 -16.4144 0.38511E-16 -16.4144 0.10000E+01 0.0000 83 H2PO4- 0.88065E-09 -9.0552 0.77070E-09 -9.1131 0.87515E+00 -0.0579 84 PO4-3 0.54873E-08 -8.2606 0.19623E-08 -8.7072 0.35761E+00 -0.4466 87 H2P2O7-2 0.75000E-19 -19.1249 0.46574E-19 -19.3319 0.62098E+00 -0.2069 88 HP2O7-3 0.20238E-15 -15.6938 0.70560E-16 -16.1514 0.34864E+00 -0.4576 89 P2O7-4 0.80977E-15 -15.0916 0.12790E-15 -15.8931 0.15794E+00 -0.8015 90 H2S,aq 0.61310E-15 -15.2125 0.61214E-15 -15.2131 0.99844E+00 -0.0007 97 SO3-2 0.65056E-14 -14.1867 0.40705E-14 -14.3903 0.62570E+00 -0.2036 98 HSO3- 0.38402E-16 -16.4156 0.33591E-16 -16.4738 0.87471E+00 -0.0581 99 HSO4- 0.23025E-11 -11.6378 0.20171E-11 -11.6953 0.87603E+00 -0.0575 Charge balance for all species = 0.6525E-13 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.1501990E-09 -.9456616E-02 -.9525132E+01 0.0000 2 H2O 0.1000000E+01 0.5550909E+02 0.9993236E+06 0.0000 3 Cl- 0.1379716E-03 0.1382877E-03 0.4899336E+01 5.9617 4 SO4-- 0.2554474E-04 0.2556365E-04 0.2453993E+01 14.9610 5 HCO3- 0.6771097E-05 0.1309970E-04 0.7987562E+00 4.6529 6 HS- 0.1717904E-11 -.1222674E-08 -.4040839E-04 -1.9430 7 Al+++ 0.4236492E-27 0.3358074E-04 0.9054342E+00 1.8095 8 H4SiO4 0.4745857E-03 0.4748028E-02 0.4560441E+03 -3.3237 9 Ca++ 0.3738601E-07 0.5497573E-07 0.2201799E-02 12.1248 10 Mg++ 0.2080711E-10 0.6629896E-10 0.1610749E-05 8.8692 11 Fe++ 0.1226943E-12 0.2933880E-07 0.1637355E-02 6.6401 12 K+ 0.7124206E-04 0.7146187E-04 0.2792376E+01 5.6751 13 Na+ 0.9032125E-02 0.9487787E-02 0.2179720E+03 7.7777 14 Mn++ 0.1648045E-10 0.9314077E-09 0.5113441E-04 8.7684 15 HPO4-- 0.5098561E-06 0.5162240E-06 0.4951252E-01 13.2612 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.2649066E+00 -.9435174E-02 -.2554715E+00 0.0000000E+00 2 H2O 0.5530770E+02 0.5538323E+02 -.7552969E-01 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.4688913E-03 0.2550569E-04 0.4433856E-03 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.4433868E-03 -.1219901E-08 -.4433856E-03 0.0000000E+00 7 Al+++ 0.5216861E-01 0.3350460E-04 0.5213510E-01 0.0000000E+00 8 H4SiO4 0.1665941E+00 0.4737263E-02 0.1618569E+00 0.0000000E+00 9 Ca++ 0.1841560E-01 0.5485107E-07 0.1841555E-01 0.0000000E+00 10 Mg++ 0.1269762E-01 0.6614863E-10 0.1269762E-01 0.0000000E+00 11 Fe++ 0.1140742E-01 0.2927228E-07 0.1140740E-01 0.0000000E+00 12 K+ 0.3396815E-02 0.7129983E-04 0.3325515E-02 0.0000000E+00 13 Na+ 0.2024271E-01 0.9466274E-02 0.1077644E-01 0.0000000E+00 14 Mn++ 0.2774002E-03 0.9292958E-09 0.2773993E-03 0.0000000E+00 15 HPO4-- 0.9467531E-04 0.5150535E-06 0.9416025E-04 0.0000000E+00 Chg. balance for solid moles: -.2355E-16 Mass of aqueous solution: 0.998421E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 15.9990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 0.1078E-01 -1.968 2.826 0.451 16.19 1.085 andradite 0.1102E-02 -2.958 0.5602 -0.252 3.209 0.1455 grossular 0.5098E-04 -4.293 0.2296E-01 -1.639 0.1315 0.6389E-02 apatite-OH 0.3139E-04 -4.503 0.1577E-01 -1.802 0.9030E-01 0.5010E-02 clinochlore 0.2540E-02 -2.595 1.412 0.150 8.085 0.5369 daphnite 0.1572E-02 -2.804 1.122 0.050 6.425 0.3399 chlorite-Mn 0.5548E-04 -4.256 0.3933E-01 -1.405 0.2253 0.1253E-01 hematite 0.6712E-03 -3.173 0.1072 -0.970 0.6139 0.2032E-01 microcline 0.3326E-02 -2.478 0.9256 -0.034 5.302 0.3616 stilbite 0.1480E-01 -1.830 10.43 1.018 59.73 4.864 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.9558E+00 0.9558E+00 1.0000 -0.020 grossular 0.4420E-01 0.4420E-01 1.0000 -1.355 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.6094E+00 0.6094E+00 1.0000 -0.215 daphnite 0.3773E+00 0.3773E+00 1.0000 -0.423 chlorite-Mn 0.1331E-01 0.1331E-01 1.0000 -1.876 hematite 0.1000E+01 0.1000E+01 1.0000 0.000 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 17.458923 g Volume = 7.377132 cm3 Porosity: 0.3036% V(tot) - V(min): 0.22468E-01 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 15.9990000 g log = 1.2041 Original solution: 1000.0103000 g Original solution / Rock added: 62.50 (Water/Rock Ratio), log = 1.7959 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0203 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.1000E+01 0.9860 0.1006E+01 0.1020E+01 CO2,gas 0.1738E-06 1.0071 0.1786E-06 0.1773E-06 CH4,gas 0.7763E-15 1.0125 0.8020E-15 0.7921E-15 H2,gas 0.2537E-05 1.0005 0.2590E-05 0.2588E-05 H2S,gas 0.1656E-13 0.9960 0.1683E-13 0.1689E-13 S2,gas 0.1553E-35 1.0000 0.1585E-35 0.1585E-35 CO,gas 0.1208E-15 1.0000 0.1233E-15 0.1233E-15 SO3,gas 0.1022E-39 1.0000 0.1043E-39 0.1043E-39 SO2,gas 0.1030E-22 1.0000 0.1051E-22 0.1051E-22 HCl,gas 0.5041E-17 1.0000 0.5143E-17 0.5143E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 16 albite -0.38 -0.38 0.00 0.000 -0.13080E-10 22 andradite 39.01 39.01 0.00 0.000 0.12132E-10 23 grossular 32.73 32.73 0.00 0.000 -0.12132E-10 32 apatite-OH -18.15 -18.15 0.00 0.000 0.00000E+00 46 clinochlore 39.07 39.07 0.00 0.000 -0.36397E-10 47 daphnite 28.97 28.97 0.00 0.000 0.00000E+00 48 chlorite-Mn 46.87 46.87 0.00 0.000 -0.24265E-10 90 hematite 12.57 12.57 0.00 0.000 0.30331E-11 116 microcline -2.49 -2.49 0.00 0.000 -0.10616E-10 163 stilbite -7.52 -7.52 0.00 0.000 -0.33364E-10 164 stilpnomelane-Fe 13.02 13.07 0.05 0.002 -0.86367E+02 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -15.11 -8.45 -2.816 0.14423E+05 -6.748 3 CH4,gas 4.54 -12.25 -16.79 -4.199 0.28677E+05 -15.096 4 H2,gas 8.00 0.71 -7.29 -4.163 0.12440E+05 -5.587 5 H2S,gas -6.23 -21.70 -15.47 -7.736 0.26420E+05 -13.774 6 S2,gas -7.34 -44.83 -37.50 -5.769 0.64028E+05 -35.800 7 CO,gas 3.21 -14.39 -17.61 -5.418 0.30065E+05 -15.909 8 SO3,gas 17.12 -24.56 -41.68 -10.420 0.71169E+05 -39.982 9 SO2,gas 0.83 -23.85 -24.68 -6.581 0.42136E+05 -22.978 10 HCl,gas 5.19 -13.80 -18.99 -9.494 0.32421E+05 -17.289 11 acmite 7.71 7.41 -0.30 -0.031 0.50590E+03 15 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 19 spessartine 24.46 19.95 -4.50 -0.225 0.76906E+04 20 analcite 3.32 2.94 -0.38 -0.042 0.65233E+03 21 andalusite 5.00 0.30 -4.71 -0.471 0.80358E+04 26 annite 20.12 17.43 -2.69 -0.149 0.45924E+04 27 phlogopite 27.06 24.12 -2.94 -0.164 0.50257E+04 29 anorthite 12.71 9.10 -3.61 -0.278 0.61707E+04 35 aragonite 0.97 -2.98 -3.95 -1.316 0.67428E+04 36 brucite 12.57 8.87 -3.70 -0.740 0.63165E+04 37 calcite 0.81 -2.98 -3.79 -1.265 0.64785E+04 38 carnegieite-low 9.02 6.26 -2.76 -0.394 0.47123E+04 39 carnegieite-high 10.09 6.26 -3.83 -0.547 0.65393E+04 40 carpholite-Mg 8.58 5.84 -2.74 -0.183 0.46806E+04 41 carpholite-Fe 6.71 3.61 -3.10 -0.207 0.52948E+04 42 celadonite 5.34 3.06 -2.28 -0.134 0.38974E+04 43 celadonite-Fe 3.88 0.83 -3.05 -0.179 0.52020E+04 44 chrysotile 23.89 19.96 -3.93 -0.328 0.67138E+04 50 chloritoid-Mg 13.20 9.16 -4.03 -0.269 0.68865E+04 51 chloritoid-Fe 9.17 6.94 -2.24 -0.149 0.38217E+04 52 chloritoid-Mn 11.40 9.06 -2.34 -0.156 0.39910E+04 54 coesite -2.38 -3.32 -0.95 -0.316 0.16180E+04 59 corundum 8.38 3.62 -4.76 -0.433 0.81347E+04 61 cristobalite -2.56 -3.32 -0.76 -0.254 0.13034E+04 63 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71234E+04 65 diaspore 2.87 1.81 -1.06 -0.177 0.18171E+04 67 diopside 16.18 14.35 -1.83 -0.183 0.31327E+04 68 hedenbergite 14.21 12.12 -2.09 -0.209 0.35699E+04 75 epidote 24.67 24.18 -0.49 -0.024 0.83555E+03 76 clinozoisite 22.81 19.71 -3.10 -0.141 0.52916E+04 77 epidote-Fe 29.84 28.65 -1.19 -0.062 0.20261E+04 78 fayalite 14.05 9.96 -4.09 -0.584 0.69822E+04 79 ferrosilite 11.15 6.63 -4.52 -0.452 0.77120E+04 83 gibbsite 4.08 1.81 -2.27 -0.324 0.38757E+04 84 glaucophane 22.97 19.19 -3.78 -0.102 0.64580E+04 85 glaucophane-Fe 17.28 12.51 -4.77 -0.129 0.81457E+04 87 greenalite 16.14 13.27 -2.87 -0.239 0.48946E+04 91 heulandite -5.83 -7.52 -1.69 -0.077 0.28938E+04 95 jadeite 4.22 2.94 -1.28 -0.128 0.21778E+04 96 julgoldite 70.43 66.97 -3.46 -0.090 0.59033E+04 97 kalsilite 7.58 4.16 -3.42 -0.489 0.58447E+04 98 kaolinite -1.33 -3.03 -1.70 -0.154 0.28953E+04 99 kyanite 4.88 0.30 -4.58 -0.458 0.78217E+04 101 laumontite 2.88 2.45 -0.43 -0.029 0.74174E+03 102 lawsonite 9.62 9.10 -0.52 -0.035 0.88737E+03 103 leucite 4.12 0.84 -3.28 -0.328 0.56034E+04 105 lizardite 23.24 19.96 -3.28 -0.274 0.56065E+04 107 magnetite 20.09 19.21 -0.88 -0.072 0.15045E+04 108 minnesotaite 10.39 6.63 -3.76 -0.221 0.64244E+04 110 magnesioferrite 26.21 21.44 -4.78 -0.390 0.81565E+04 113 margarite 17.32 12.72 -4.61 -0.184 0.78685E+04 120 muscovite 2.58 1.13 -1.45 -0.085 0.24758E+04 121 paragonite 4.24 3.24 -1.00 -0.059 0.17149E+04 122 nepheline 8.34 6.26 -2.08 -0.297 0.35446E+04 128 periclase-Fe 11.63 6.64 -4.99 -1.247 0.85143E+04 134 phlogopite-Na 29.65 26.22 -3.42 -0.190 0.58445E+04 136 prehnite 19.37 17.90 -1.47 -0.087 0.25175E+04 137 prehnite-Fe 22.50 22.37 -0.13 -0.008 0.21647E+03 138 pumpellyite-Fe 46.27 44.24 -2.02 -0.045 0.34574E+04 139 pumpellyite-Mg 48.99 46.47 -2.52 -0.056 0.43049E+04 145 pyroxmangite 7.40 5.44 -1.95 -0.391 0.33363E+04 146 pyrophyllite -6.18 -9.68 -3.50 -0.219 0.59761E+04 147 quartz -2.99 -3.32 -0.33 -0.111 0.57072E+03 152 rhodonite 7.45 5.44 -2.00 -0.400 0.34165E+04 153 sanidine -1.28 -2.49 -1.21 -0.093 0.20677E+04 156 sillimanite 5.26 0.30 -4.97 -0.497 0.84797E+04 165 stilpnomelane-Mg 27.44 24.21 -3.23 -0.096 0.55120E+04 171 talc 16.49 13.31 -3.18 -0.187 0.54265E+04 174 tephroite 18.09 14.21 -3.87 -0.553 0.66124E+04 177 topaz-H 4.62 0.30 -4.32 -0.393 0.73818E+04 178 tridymite -2.63 -3.32 -0.70 -0.232 0.11907E+04 187 wairakite 3.95 2.45 -1.50 -0.088 0.25637E+04 188 walstromite 11.51 8.80 -2.71 -0.542 0.46241E+04 189 wollastonite 10.46 8.80 -1.66 -0.332 0.28345E+04 190 pseudo-wollastonite 11.00 8.80 -2.20 -0.440 0.37543E+04 191 zoisite 22.85 19.71 -3.14 -0.143 0.53656E+04 192 akaganeite 7.75 6.28 -1.47 -0.318 0.25125E+04 193 beidellite-Ca -1.65 -5.98 -4.34 -0.268 0.74030E+04 195 beidellite-K -1.52 -6.11 -4.59 -0.281 0.78353E+04 196 beidellite-Mg -1.79 -6.52 -4.73 -0.293 0.80740E+04 197 beidellite-Na -1.34 -5.42 -4.07 -0.249 0.69545E+04 199 chalcedony -2.80 -3.32 -0.52 -0.174 0.89002E+03 201 montmorillonite-Ca -2.29 -5.35 -3.05 -0.189 0.52159E+04 202 montmorillonite-K -2.24 -5.47 -3.24 -0.198 0.55263E+04 203 montmorillonite-Mg -2.48 -5.88 -3.40 -0.211 0.58101E+04 204 montmorillonite-Na -2.04 -4.78 -2.74 -0.168 0.46812E+04 205 nontronite-Ca 3.21 2.97 -0.25 -0.016 0.42442E+03 206 nontronite-H 2.53 0.97 -1.57 -0.105 0.26761E+04 207 nontronite-K 3.34 2.84 -0.50 -0.032 0.85807E+03 208 nontronite-Mg 3.07 2.43 -0.65 -0.042 0.11027E+04 209 nontronite-Na 3.52 3.53 0.01 0.001 -0.21055E+02 224 tobermorite 9.82 6.78 -3.05 -0.831 0.52023E+04 233 boehmite 4.41 1.81 -2.60 -0.433 0.44340E+04 235 ferrous-oxide 9.81 6.64 -3.17 -0.793 0.54152E+04 240 silica-amorphous -2.09 -3.32 -1.23 -0.411 0.21042E+04 242 an20ab80 2.02 1.51 -0.51 -0.039 0.86329E+03 243 an25ab75 2.65 1.99 -0.66 -0.051 0.11261E+04 244 an30ab70 3.28 2.46 -0.82 -0.063 0.13985E+04 245 tr.625ac.25prg.125 45.16 40.59 -4.57 -0.123 0.78063E+04 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 9 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 15.9990000 Water: Moles liquid = 0.5538E+02 kg liquid = 0.9977E+00 Moles total = 0.5531E+02 kg total = 0.9964E+00 Activity = 1.0000 Stoichiometric ionic strength = .5045341E-02 Osmotic coef. = 0.9622 True ionic strength = .9100330E-02 Chg. balance for total moles = 0.6621E-13 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.14973E-09 -9.8247 0.13141E-09 -9.8814 0.87766E+00 -0.0567 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13797E-03 -3.8602 0.12071E-03 -3.9183 0.87489E+00 -0.0580 4 SO4-- 0.25545E-04 -4.5927 0.15893E-04 -4.7988 0.62215E+00 -0.2061 5 HCO3- 0.67633E-05 -5.1698 0.59216E-05 -5.2276 0.87555E+00 -0.0577 6 HS- 0.14954E-11 -11.8252 0.13084E-11 -11.8833 0.87495E+00 -0.0580 7 Al+++ 0.44034E-27 -27.3562 0.15373E-27 -27.8132 0.34912E+00 -0.4570 8 H4SiO4 0.46696E-03 -3.3307 0.46696E-03 -3.3307 0.10000E+01 0.0000 9 Ca++ 0.37685E-07 -7.4238 0.23357E-07 -7.6316 0.61978E+00 -0.2078 10 Mg++ 0.20548E-10 -10.6872 0.12705E-10 -10.8960 0.61830E+00 -0.2088 11 Fe++ 0.11981E-12 -12.9215 0.74122E-13 -13.1301 0.61865E+00 -0.2086 12 K+ 0.70964E-04 -4.1490 0.62141E-04 -4.2066 0.87567E+00 -0.0577 13 Na+ 0.89968E-02 -2.0459 0.78706E-02 -2.1040 0.87481E+00 -0.0581 14 Mn++ 0.16275E-10 -10.7885 0.10073E-10 -10.9968 0.61892E+00 -0.2084 15 HPO4-- 0.50009E-06 -6.3010 0.31115E-06 -6.5070 0.62220E+00 -0.2061 16 HSiO3- 0.37926E-02 -2.4211 0.33181E-02 -2.4791 0.87489E+00 -0.0580 17 Ca(HSiO3)+ 0.20153E-08 -8.6957 0.17650E-08 -8.7533 0.87577E+00 -0.0576 18 Mg(HSiO3)+ 0.13643E-11 -11.8651 0.11948E-11 -11.9227 0.87577E+00 -0.0576 19 NaHSiO3,aq 0.42238E-03 -3.3743 0.42238E-03 -3.3743 0.10000E+01 0.0000 20 AlO+ 0.13830E-14 -14.8592 0.12112E-14 -14.9168 0.87577E+00 -0.0576 22 HAlO2,aq 0.18355E-08 -8.7362 0.18355E-08 -8.7362 0.10000E+01 0.0000 23 AlO2- 0.35375E-04 -4.4513 0.30919E-04 -4.5098 0.87405E+00 -0.0585 24 CH4,aq 0.47430E-18 -18.3240 0.47356E-18 -18.3246 0.99845E+00 -0.0007 29 CO,aq 0.79628E-19 -19.0989 0.79628E-19 -19.0989 0.10000E+01 0.0000 30 CO2,aq 0.16653E-08 -8.7785 0.16627E-08 -8.7792 0.99845E+00 -0.0007 31 CO3-2 0.63336E-05 -5.1984 0.39361E-05 -5.4049 0.62146E+00 -0.2066 32 CaCO3,aq 0.11527E-08 -8.9383 0.11527E-08 -8.9383 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.40313E-11 -11.3946 0.35305E-11 -11.4522 0.87577E+00 -0.0576 34 CaCl+ 0.52099E-11 -11.2832 0.45627E-11 -11.3408 0.87577E+00 -0.0576 35 CaCl2,aq 0.13085E-15 -15.8832 0.13085E-15 -15.8832 0.10000E+01 0.0000 36 CaOH+ 0.14465E-07 -7.8397 0.12668E-07 -7.8973 0.87577E+00 -0.0576 37 CaSO4,aq 0.11787E-09 -9.9286 0.11787E-09 -9.9286 0.10000E+01 0.0000 38 HCl,aq 0.29067E-14 -14.5366 0.29067E-14 -14.5366 0.10000E+01 0.0000 43 FeCl+ 0.16171E-16 -16.7913 0.14162E-16 -16.8489 0.87577E+00 -0.0576 46 FeO,aq 0.16683E-09 -9.7777 0.16683E-09 -9.7777 0.10000E+01 0.0000 47 FeOH+ 0.20965E-10 -10.6785 0.18361E-10 -10.7361 0.87577E+00 -0.0576 48 HFeO2- 0.15183E-07 -7.8186 0.13284E-07 -7.8767 0.87489E+00 -0.0580 49 FeO+ 0.11453E-14 -14.9411 0.10030E-14 -14.9987 0.87577E+00 -0.0576 51 FeO2- 0.13585E-07 -7.8669 0.11886E-07 -7.9250 0.87489E+00 -0.0580 52 HFeO2,aq 0.19864E-09 -9.7019 0.19864E-09 -9.7019 0.10000E+01 0.0000 53 H2,aq 0.19094E-08 -8.7191 0.19064E-08 -8.7198 0.99845E+00 -0.0007 54 KCl,aq 0.13595E-09 -9.8666 0.13595E-09 -9.8666 0.10000E+01 0.0000 55 KHSO4,aq 0.36693E-18 -18.4354 0.36693E-18 -18.4354 0.10000E+01 0.0000 56 KOH,aq 0.20195E-06 -6.6948 0.20195E-06 -6.6948 0.10000E+01 0.0000 57 KSO4- 0.17517E-07 -7.7566 0.15325E-07 -7.8146 0.87489E+00 -0.0580 58 MgCO3,aq 0.15717E-12 -12.8036 0.15717E-12 -12.8036 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.22407E-14 -14.6496 0.19623E-14 -14.7072 0.87577E+00 -0.0576 60 MgCl+ 0.25685E-14 -14.5903 0.22494E-14 -14.6479 0.87577E+00 -0.0576 61 MgOH+ 0.43538E-10 -10.3611 0.38129E-10 -10.4187 0.87577E+00 -0.0576 63 MnO,aq 0.60412E-09 -9.2189 0.60412E-09 -9.2189 0.10000E+01 0.0000 64 MnOH+ 0.26468E-09 -9.5773 0.23180E-09 -9.6349 0.87577E+00 -0.0576 65 MnO2-2 0.18683E-11 -11.7286 0.11611E-11 -11.9351 0.62146E+00 -0.2066 66 HMnO2- 0.38206E-10 -10.4179 0.33426E-10 -10.4759 0.87489E+00 -0.0580 69 MnCl+ 0.85498E-14 -14.0680 0.74877E-14 -14.1257 0.87577E+00 -0.0576 70 MnSO4,aq 0.46217E-13 -13.3352 0.46217E-13 -13.3352 0.10000E+01 0.0000 71 NaCl,aq 0.31485E-06 -6.5019 0.31485E-06 -6.5019 0.10000E+01 0.0000 72 NaOH,aq 0.25734E-04 -4.5895 0.25734E-04 -4.5895 0.10000E+01 0.0000 74 OH- 0.50304E-02 -2.2984 0.43968E-02 -2.3569 0.87405E+00 -0.0585 79 HPO3-2 0.29746E-17 -17.5266 0.18486E-17 -17.7332 0.62146E+00 -0.2066 82 H3PO4,aq 0.37578E-16 -16.4251 0.37578E-16 -16.4251 0.10000E+01 0.0000 83 H2PO4- 0.86171E-09 -9.0646 0.75427E-09 -9.1225 0.87532E+00 -0.0578 84 PO4-3 0.53933E-08 -8.2681 0.19319E-08 -8.7140 0.35821E+00 -0.4459 87 H2P2O7-2 0.71782E-19 -19.1440 0.44610E-19 -19.3506 0.62146E+00 -0.2066 88 HP2O7-3 0.19408E-15 -15.7120 0.67785E-16 -16.1689 0.34926E+00 -0.4569 89 P2O7-4 0.77784E-15 -15.1091 0.12323E-15 -15.9093 0.15843E+00 -0.8002 90 H2S,aq 0.53221E-15 -15.2739 0.53139E-15 -15.2746 0.99845E+00 -0.0007 97 SO3-2 0.62877E-14 -14.2015 0.39372E-14 -14.4048 0.62617E+00 -0.2033 98 HSO3- 0.37027E-16 -16.4315 0.32394E-16 -16.4895 0.87489E+00 -0.0580 99 HSO4- 0.22970E-11 -11.6388 0.20126E-11 -11.6962 0.87620E+00 -0.0574 Charge balance for all species = 0.6788E-13 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.1497253E-09 -.9419227E-02 -.9487528E+01 0.0000 2 H2O 0.1000000E+01 0.5550916E+02 0.9993309E+06 0.0000 3 Cl- 0.1379724E-03 0.1382874E-03 0.4899352E+01 5.9631 4 SO4-- 0.2554473E-04 0.2556361E-04 0.2454003E+01 14.9640 5 HCO3- 0.6763267E-05 0.1309967E-04 0.7987589E+00 4.6538 6 HS- 0.1495407E-11 -.1244146E-08 -.4111826E-04 -2.0019 7 Al+++ 0.4403434E-27 0.3537656E-04 0.9538605E+00 1.8309 8 H4SiO4 0.4669618E-03 0.4681937E-02 0.4496987E+03 -3.3307 9 Ca++ 0.3768542E-07 0.5544526E-07 0.2220616E-02 12.1312 10 Mg++ 0.2054822E-10 0.6561235E-10 0.1594077E-05 8.8667 11 Fe++ 0.1198117E-12 0.2915493E-07 0.1627102E-02 6.6327 12 K+ 0.7096399E-04 0.7118359E-04 0.2781519E+01 5.6748 13 Na+ 0.8996842E-02 0.9445268E-02 0.2169964E+03 7.7774 14 Mn++ 0.1627544E-10 0.9252027E-09 0.5079405E-04 8.7659 15 HPO4-- 0.5000877E-06 0.5063427E-06 0.4856506E-01 13.2557 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.2649066E+00 -.9397894E-02 -.2555088E+00 0.0000000E+00 2 H2O 0.5530770E+02 0.5538344E+02 -.7574760E-01 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.4688913E-03 0.2550571E-04 0.4433856E-03 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.4433868E-03 -.1241328E-08 -.4433856E-03 0.0000000E+00 7 Al+++ 0.5216861E-01 0.3529644E-04 0.5213331E-01 0.0000000E+00 8 H4SiO4 0.1665941E+00 0.4671333E-02 0.1619228E+00 0.0000000E+00 9 Ca++ 0.1841560E-01 0.5531968E-07 0.1841555E-01 0.0000000E+00 10 Mg++ 0.1269762E-01 0.6546375E-10 0.1269762E-01 0.0000000E+00 11 Fe++ 0.1140742E-01 0.2908889E-07 0.1140740E-01 0.0000000E+00 12 K+ 0.3396815E-02 0.7102237E-04 0.3325793E-02 0.0000000E+00 13 Na+ 0.2024271E-01 0.9423876E-02 0.1081884E-01 0.0000000E+00 14 Mn++ 0.2774002E-03 0.9231073E-09 0.2773993E-03 0.0000000E+00 15 HPO4-- 0.9467531E-04 0.5051960E-06 0.9417011E-04 0.0000000E+00 Chg. balance for solid moles: -.4218E-16 Mass of aqueous solution: 0.998417E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 15.9990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 0.1082E-01 -1.966 2.837 0.453 16.25 1.089 andradite 0.1106E-02 -2.956 0.5623 -0.250 3.220 0.1461 grossular 0.5375E-04 -4.270 0.2421E-01 -1.616 0.1387 0.6737E-02 apatite-OH 0.3139E-04 -4.503 0.1577E-01 -1.802 0.9030E-01 0.5010E-02 clinochlore 0.2540E-02 -2.595 1.412 0.150 8.083 0.5369 daphnite 0.1554E-02 -2.808 1.109 0.045 6.352 0.3361 chlorite-Mn 0.5548E-04 -4.256 0.3933E-01 -1.405 0.2252 0.1253E-01 hematite 0.6671E-03 -3.176 0.1065 -0.973 0.6101 0.2019E-01 microcline 0.3317E-02 -2.479 0.9233 -0.035 5.287 0.3606 stilbite 0.1478E-01 -1.830 10.41 1.018 59.64 4.857 stilpnomelane-Fe 0.1760E-04 -4.755 0.1897E-01 -1.722 0.1086 0.6552E-02 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.9537E+00 0.9537E+00 1.0000 -0.021 grossular 0.4633E-01 0.4633E-01 1.0000 -1.334 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.6120E+00 0.6120E+00 1.0000 -0.213 daphnite 0.3746E+00 0.3746E+00 1.0000 -0.426 chlorite-Mn 0.1337E-01 0.1337E-01 1.0000 -1.874 hematite 0.1000E+01 0.1000E+01 1.0000 0.000 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 17.462234 g Volume = 7.377210 cm3 Porosity: 0.3026% V(tot) - V(min): 0.22390E-01 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 15.9990000 g log = 1.2041 Original solution: 1000.0103000 g Original solution / Rock added: 62.50 (Water/Rock Ratio), log = 1.7959 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0203 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.1000E+01 0.9860 0.1006E+01 0.1020E+01 CO2,gas 0.1731E-06 1.0071 0.1779E-06 0.1766E-06 CH4,gas 0.6747E-15 1.0125 0.6970E-15 0.6884E-15 H2,gas 0.2452E-05 1.0005 0.2503E-05 0.2502E-05 H2S,gas 0.1437E-13 0.9960 0.1461E-13 0.1467E-13 S2,gas 0.1253E-35 1.0000 0.1279E-35 0.1279E-35 CO,gas 0.1163E-15 1.0000 0.1187E-15 0.1187E-15 SO3,gas 0.1017E-39 1.0000 0.1038E-39 0.1038E-39 SO2,gas 0.9903E-23 1.0000 0.1010E-22 0.1010E-22 HCl,gas 0.5027E-17 1.0000 0.5129E-17 0.5129E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 16 albite -0.38 -0.38 0.00 0.000 -0.13080E-10 22 andradite 39.01 39.01 0.00 0.000 0.00000E+00 23 grossular 32.73 32.73 0.00 0.000 -0.36397E-10 32 apatite-OH -18.15 -18.15 0.00 0.000 0.60662E-11 46 clinochlore 39.07 39.07 0.00 0.000 0.00000E+00 47 daphnite 28.97 28.97 0.00 0.000 -0.30331E-10 48 chlorite-Mn 46.87 46.87 0.00 0.000 -0.12132E-10 90 hematite 12.57 12.57 0.00 0.000 0.30331E-11 116 microcline -2.49 -2.49 0.00 0.000 0.15165E-11 163 stilbite -7.52 -7.52 0.00 0.000 0.15165E-10 164 stilpnomelane-Fe 13.02 13.02 0.00 0.000 -0.27298E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -15.11 -8.45 -2.816 0.14426E+05 -6.750 3 CH4,gas 4.54 -12.31 -16.86 -4.214 0.28781E+05 -15.157 4 H2,gas 8.00 0.70 -7.30 -4.172 0.12465E+05 -5.602 5 H2S,gas -6.23 -21.76 -15.53 -7.767 0.26525E+05 -13.835 6 S2,gas -7.34 -44.93 -37.59 -5.783 0.64188E+05 -35.893 7 CO,gas 3.21 -14.41 -17.62 -5.423 0.30094E+05 -15.926 8 SO3,gas 17.12 -24.56 -41.68 -10.421 0.71172E+05 -39.984 9 SO2,gas 0.83 -23.86 -24.69 -6.585 0.42165E+05 -22.996 10 HCl,gas 5.19 -13.80 -18.99 -9.494 0.32423E+05 -17.290 11 acmite 7.71 7.40 -0.31 -0.032 0.53047E+03 15 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 19 spessartine 24.46 19.97 -4.49 -0.224 0.76664E+04 20 analcite 3.32 2.95 -0.38 -0.042 0.64032E+03 21 andalusite 5.00 0.33 -4.67 -0.467 0.79746E+04 26 annite 20.12 17.41 -2.71 -0.151 0.46303E+04 27 phlogopite 27.06 24.11 -2.95 -0.164 0.50386E+04 29 anorthite 12.71 9.13 -3.58 -0.275 0.61107E+04 35 aragonite 0.97 -2.98 -3.94 -1.315 0.67348E+04 36 brucite 12.57 8.87 -3.70 -0.740 0.63208E+04 37 calcite 0.81 -2.98 -3.79 -1.263 0.64705E+04 38 carnegieite-low 9.02 6.28 -2.75 -0.392 0.46883E+04 39 carnegieite-high 10.09 6.28 -3.82 -0.545 0.65152E+04 40 carpholite-Mg 8.58 5.87 -2.71 -0.181 0.46358E+04 41 carpholite-Fe 6.71 3.63 -3.08 -0.205 0.52583E+04 42 celadonite 5.34 3.05 -2.29 -0.135 0.39137E+04 43 celadonite-Fe 3.88 0.82 -3.06 -0.180 0.52266E+04 44 chrysotile 23.89 19.94 -3.95 -0.329 0.67507E+04 50 chloritoid-Mg 13.20 9.20 -4.00 -0.267 0.68297E+04 51 chloritoid-Fe 9.17 6.96 -2.21 -0.147 0.37732E+04 52 chloritoid-Mn 11.40 9.10 -2.30 -0.154 0.39341E+04 54 coesite -2.38 -3.33 -0.95 -0.318 0.16300E+04 59 corundum 8.38 3.66 -4.72 -0.429 0.80615E+04 61 cristobalite -2.56 -3.33 -0.77 -0.257 0.13154E+04 63 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71234E+04 65 diaspore 2.87 1.83 -1.04 -0.174 0.17805E+04 67 diopside 16.18 14.34 -1.84 -0.184 0.31501E+04 68 hedenbergite 14.21 12.10 -2.11 -0.211 0.35957E+04 75 epidote 24.67 24.22 -0.45 -0.022 0.77661E+03 76 clinozoisite 22.81 19.76 -3.04 -0.138 0.51961E+04 77 epidote-Fe 29.84 28.67 -1.17 -0.061 0.20038E+04 78 fayalite 14.05 9.93 -4.11 -0.587 0.70195E+04 79 ferrosilite 11.15 6.60 -4.55 -0.455 0.77613E+04 83 gibbsite 4.08 1.83 -2.25 -0.321 0.38391E+04 84 glaucophane 22.97 19.17 -3.80 -0.103 0.64948E+04 85 glaucophane-Fe 17.28 12.47 -4.81 -0.130 0.82076E+04 87 greenalite 16.14 13.24 -2.90 -0.242 0.49565E+04 91 heulandite -5.83 -7.52 -1.69 -0.077 0.28938E+04 95 jadeite 4.22 2.95 -1.27 -0.127 0.21658E+04 96 julgoldite 70.43 66.94 -3.49 -0.091 0.59570E+04 97 kalsilite 7.58 4.17 -3.41 -0.487 0.58207E+04 98 kaolinite -1.33 -3.00 -1.67 -0.152 0.28461E+04 99 kyanite 4.88 0.33 -4.55 -0.455 0.77605E+04 101 laumontite 2.88 2.47 -0.41 -0.028 0.70571E+03 102 lawsonite 9.62 9.13 -0.48 -0.032 0.82732E+03 103 leucite 4.12 0.84 -3.27 -0.327 0.55914E+04 105 lizardite 23.24 19.94 -3.31 -0.275 0.56433E+04 107 magnetite 20.09 19.20 -0.89 -0.073 0.15171E+04 108 minnesotaite 10.39 6.58 -3.81 -0.224 0.65104E+04 110 magnesioferrite 26.21 21.43 -4.78 -0.390 0.81608E+04 113 margarite 17.32 12.79 -4.53 -0.181 0.77353E+04 120 muscovite 2.58 1.18 -1.41 -0.083 0.24026E+04 121 paragonite 4.24 3.28 -0.96 -0.057 0.16417E+04 122 nepheline 8.34 6.28 -2.06 -0.295 0.35206E+04 128 periclase-Fe 11.63 6.63 -4.99 -1.248 0.85269E+04 134 phlogopite-Na 29.65 26.22 -3.43 -0.191 0.58574E+04 136 prehnite 19.37 17.93 -1.44 -0.085 0.24586E+04 137 prehnite-Fe 22.50 22.38 -0.11 -0.007 0.19410E+03 138 pumpellyite-Fe 46.27 44.33 -1.94 -0.043 0.33156E+04 139 pumpellyite-Mg 48.99 46.56 -2.43 -0.054 0.41547E+04 145 pyroxmangite 7.40 5.44 -1.96 -0.393 0.33526E+04 146 pyrophyllite -6.18 -9.66 -3.49 -0.218 0.59510E+04 147 quartz -2.99 -3.33 -0.34 -0.114 0.58273E+03 152 rhodonite 7.45 5.44 -2.01 -0.402 0.34328E+04 153 sanidine -1.28 -2.49 -1.21 -0.093 0.20677E+04 156 sillimanite 5.26 0.33 -4.93 -0.493 0.84186E+04 165 stilpnomelane-Mg 27.44 24.19 -3.25 -0.097 0.55566E+04 171 talc 16.49 13.28 -3.21 -0.189 0.54874E+04 174 tephroite 18.09 14.20 -3.88 -0.555 0.66329E+04 177 topaz-H 4.62 0.33 -4.29 -0.390 0.73206E+04 178 tridymite -2.63 -3.33 -0.70 -0.235 0.12027E+04 187 wairakite 3.95 2.47 -1.48 -0.087 0.25277E+04 188 walstromite 11.51 8.80 -2.71 -0.542 0.46252E+04 189 wollastonite 10.46 8.80 -1.66 -0.332 0.28356E+04 190 pseudo-wollastonite 11.00 8.80 -2.20 -0.440 0.37554E+04 191 zoisite 22.85 19.76 -3.09 -0.140 0.52701E+04 192 akaganeite 7.75 6.28 -1.47 -0.318 0.25125E+04 193 beidellite-Ca -1.65 -5.96 -4.31 -0.267 0.73600E+04 195 beidellite-K -1.52 -6.09 -4.56 -0.280 0.77943E+04 196 beidellite-Mg -1.79 -6.49 -4.70 -0.291 0.80336E+04 197 beidellite-Na -1.34 -5.39 -4.05 -0.248 0.69135E+04 199 chalcedony -2.80 -3.33 -0.53 -0.176 0.90203E+03 201 montmorillonite-Ca -2.29 -5.34 -3.05 -0.188 0.52025E+04 202 montmorillonite-K -2.24 -5.47 -3.23 -0.198 0.55149E+04 203 montmorillonite-Mg -2.48 -5.88 -3.40 -0.210 0.57992E+04 204 montmorillonite-Na -2.04 -4.77 -2.73 -0.167 0.46698E+04 205 nontronite-Ca 3.21 2.95 -0.27 -0.017 0.45462E+03 206 nontronite-H 2.53 0.95 -1.59 -0.106 0.27081E+04 207 nontronite-K 3.34 2.82 -0.52 -0.033 0.89025E+03 208 nontronite-Mg 3.07 2.41 -0.66 -0.043 0.11354E+04 209 nontronite-Na 3.52 3.51 -0.01 0.000 0.11130E+02 224 tobermorite 9.82 6.77 -3.05 -0.832 0.52052E+04 233 boehmite 4.41 1.83 -2.58 -0.429 0.43975E+04 235 ferrous-oxide 9.81 6.63 -3.18 -0.795 0.54278E+04 240 silica-amorphous -2.09 -3.33 -1.24 -0.413 0.21162E+04 242 an20ab80 2.02 1.52 -0.50 -0.038 0.85128E+03 243 an25ab75 2.65 1.99 -0.65 -0.050 0.11111E+04 244 an30ab70 3.28 2.47 -0.81 -0.062 0.13805E+04 245 tr.625ac.25prg.125 45.16 40.54 -4.62 -0.125 0.78952E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 0.4000000 g Current total amount of reactant added: 15.9990000 g New total amount of reactant added: 16.3990000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.6621E-13 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 9 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 16.3990000 Water: Moles liquid = 0.5538E+02 kg liquid = 0.9977E+00 Moles total = 0.5530E+02 kg total = 0.9963E+00 Activity = 1.0000 Stoichiometric ionic strength = .5050933E-02 Osmotic coef. = 0.9622 True ionic strength = .9115387E-02 Chg. balance for total moles = 0.6621E-13 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.14993E-09 -9.8241 0.13157E-09 -9.8808 0.87759E+00 -0.0567 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13798E-03 -3.8602 0.12070E-03 -3.9183 0.87481E+00 -0.0581 4 SO4-- 0.25546E-04 -4.5927 0.15888E-04 -4.7989 0.62195E+00 -0.2062 5 HCO3- 0.67668E-05 -5.1696 0.59242E-05 -5.2274 0.87548E+00 -0.0578 6 HS- 0.14655E-11 -11.8340 0.12822E-11 -11.8921 0.87488E+00 -0.0581 7 Al+++ 0.43317E-27 -27.3633 0.15111E-27 -27.8207 0.34885E+00 -0.4574 8 H4SiO4 0.47018E-03 -3.3277 0.47018E-03 -3.3277 0.10000E+01 0.0000 9 Ca++ 0.37558E-07 -7.4253 0.23270E-07 -7.6332 0.61957E+00 -0.2079 10 Mg++ 0.20780E-10 -10.6824 0.12844E-10 -10.8913 0.61809E+00 -0.2089 11 Fe++ 0.11983E-12 -12.9214 0.74111E-13 -13.1301 0.61844E+00 -0.2087 12 K+ 0.71082E-04 -4.1482 0.62239E-04 -4.2059 0.87560E+00 -0.0577 13 Na+ 0.90118E-02 -2.0452 0.78830E-02 -2.1033 0.87474E+00 -0.0581 14 Mn++ 0.16459E-10 -10.7836 0.10183E-10 -10.9921 0.61871E+00 -0.2085 15 HPO4-- 0.50421E-06 -6.2974 0.31362E-06 -6.5036 0.62200E+00 -0.2062 16 HSiO3- 0.38143E-02 -2.4186 0.33368E-02 -2.4767 0.87481E+00 -0.0581 17 Ca(HSiO3)+ 0.20193E-08 -8.6948 0.17683E-08 -8.7524 0.87569E+00 -0.0576 18 Mg(HSiO3)+ 0.13871E-11 -11.8579 0.12147E-11 -11.9155 0.87569E+00 -0.0576 19 NaHSiO3,aq 0.42543E-03 -3.3712 0.42543E-03 -3.3712 0.10000E+01 0.0000 20 AlO+ 0.13561E-14 -14.8677 0.11875E-14 -14.9254 0.87569E+00 -0.0576 22 HAlO2,aq 0.17975E-08 -8.7453 0.17975E-08 -8.7453 0.10000E+01 0.0000 23 AlO2- 0.34601E-04 -4.4609 0.30241E-04 -4.5194 0.87398E+00 -0.0585 24 CH4,aq 0.46513E-18 -18.3324 0.46440E-18 -18.3331 0.99844E+00 -0.0007 29 CO,aq 0.79341E-19 -19.1005 0.79341E-19 -19.1005 0.10000E+01 0.0000 30 CO2,aq 0.16681E-08 -8.7778 0.16655E-08 -8.7784 0.99844E+00 -0.0007 31 CO3-2 0.63306E-05 -5.1986 0.39329E-05 -5.4053 0.62126E+00 -0.2067 32 CaCO3,aq 0.11475E-08 -8.9402 0.11475E-08 -8.9402 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.40184E-11 -11.3959 0.35189E-11 -11.4536 0.87569E+00 -0.0576 34 CaCl+ 0.51907E-11 -11.2848 0.45455E-11 -11.3424 0.87569E+00 -0.0576 35 CaCl2,aq 0.13035E-15 -15.8849 0.13035E-15 -15.8849 0.10000E+01 0.0000 36 CaOH+ 0.14394E-07 -7.8418 0.12605E-07 -7.8995 0.87569E+00 -0.0576 37 CaSO4,aq 0.11740E-09 -9.9303 0.11740E-09 -9.9303 0.10000E+01 0.0000 38 HCl,aq 0.29102E-14 -14.5361 0.29102E-14 -14.5361 0.10000E+01 0.0000 43 FeCl+ 0.16169E-16 -16.7913 0.14159E-16 -16.8490 0.87569E+00 -0.0576 46 FeO,aq 0.16639E-09 -9.7789 0.16639E-09 -9.7789 0.10000E+01 0.0000 47 FeOH+ 0.20938E-10 -10.6791 0.18335E-10 -10.7367 0.87569E+00 -0.0576 48 HFeO2- 0.15125E-07 -7.8203 0.13232E-07 -7.8784 0.87481E+00 -0.0581 49 FeO+ 0.11468E-14 -14.9405 0.10043E-14 -14.9981 0.87569E+00 -0.0576 51 FeO2- 0.13569E-07 -7.8674 0.11871E-07 -7.9255 0.87481E+00 -0.0581 52 HFeO2,aq 0.19864E-09 -9.7019 0.19864E-09 -9.7019 0.10000E+01 0.0000 53 H2,aq 0.18993E-08 -8.7214 0.18963E-08 -8.7221 0.99844E+00 -0.0007 54 KCl,aq 0.13616E-09 -9.8660 0.13616E-09 -9.8660 0.10000E+01 0.0000 55 KHSO4,aq 0.36786E-18 -18.4343 0.36786E-18 -18.4343 0.10000E+01 0.0000 56 KOH,aq 0.20201E-06 -6.6946 0.20201E-06 -6.6946 0.10000E+01 0.0000 57 KSO4- 0.17541E-07 -7.7560 0.15345E-07 -7.8140 0.87481E+00 -0.0581 58 MgCO3,aq 0.15876E-12 -12.7993 0.15876E-12 -12.7993 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.22664E-14 -14.6447 0.19846E-14 -14.7023 0.87569E+00 -0.0576 60 MgCl+ 0.25967E-14 -14.5856 0.22739E-14 -14.6432 0.87569E+00 -0.0576 61 MgOH+ 0.43962E-10 -10.3569 0.38498E-10 -10.4146 0.87569E+00 -0.0576 63 MnO,aq 0.60919E-09 -9.2152 0.60919E-09 -9.2152 0.10000E+01 0.0000 64 MnOH+ 0.26726E-09 -9.5731 0.23404E-09 -9.6307 0.87569E+00 -0.0576 65 MnO2-2 0.18799E-11 -11.7259 0.11679E-11 -11.9326 0.62126E+00 -0.2067 66 HMnO2- 0.38482E-10 -10.4147 0.33664E-10 -10.4728 0.87481E+00 -0.0581 69 MnCl+ 0.86436E-14 -14.0633 0.75692E-14 -14.1210 0.87569E+00 -0.0576 70 MnSO4,aq 0.46709E-13 -13.3306 0.46709E-13 -13.3306 0.10000E+01 0.0000 71 NaCl,aq 0.31533E-06 -6.5012 0.31533E-06 -6.5012 0.10000E+01 0.0000 72 NaOH,aq 0.25742E-04 -4.5894 0.25742E-04 -4.5894 0.10000E+01 0.0000 74 OH- 0.50245E-02 -2.2989 0.43913E-02 -2.3574 0.87398E+00 -0.0585 79 HPO3-2 0.29832E-17 -17.5253 0.18533E-17 -17.7320 0.62126E+00 -0.2067 82 H3PO4,aq 0.37971E-16 -16.4206 0.37971E-16 -16.4206 0.10000E+01 0.0000 83 H2PO4- 0.86969E-09 -9.0606 0.76119E-09 -9.1185 0.87525E+00 -0.0579 84 PO4-3 0.54330E-08 -8.2650 0.19448E-08 -8.7111 0.35795E+00 -0.4462 87 H2P2O7-2 0.73129E-19 -19.1359 0.45432E-19 -19.3426 0.62126E+00 -0.2067 88 HP2O7-3 0.19756E-15 -15.7043 0.68948E-16 -16.1615 0.34900E+00 -0.4572 89 P2O7-4 0.79123E-15 -15.1017 0.12519E-15 -15.9024 0.15822E+00 -0.8007 90 H2S,aq 0.52220E-15 -15.2822 0.52138E-15 -15.2828 0.99844E+00 -0.0007 97 SO3-2 0.62547E-14 -14.2038 0.39152E-14 -14.4072 0.62597E+00 -0.2034 98 HSO3- 0.36870E-16 -16.4333 0.32254E-16 -16.4914 0.87481E+00 -0.0581 99 HSO4- 0.22994E-11 -11.6384 0.20146E-11 -11.6958 0.87613E+00 -0.0574 Charge balance for all species = 0.6582E-13 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.1499252E-09 -.9435001E-02 -.9503393E+01 0.0000 2 H2O 0.1000000E+01 0.5550913E+02 0.9993278E+06 0.0000 3 Cl- 0.1379777E-03 0.1382932E-03 0.4899547E+01 5.9626 4 SO4-- 0.2554578E-04 0.2556469E-04 0.2454101E+01 14.9627 5 HCO3- 0.6766849E-05 0.1310022E-04 0.7987906E+00 4.6535 6 HS- 0.1465543E-11 -.1244715E-08 -.4113698E-04 -2.0112 7 Al+++ 0.4331692E-27 0.3460308E-04 0.9330028E+00 1.8218 8 H4SiO4 0.4701821E-03 0.4709896E-02 0.4523831E+03 -3.3277 9 Ca++ 0.3755790E-07 0.5524537E-07 0.2212605E-02 12.1285 10 Mg++ 0.2077988E-10 0.6629292E-10 0.1610608E-05 8.8704 11 Fe++ 0.1198347E-12 0.2908064E-07 0.1622952E-02 6.6316 12 K+ 0.7108171E-04 0.7130140E-04 0.2786115E+01 5.6749 13 Na+ 0.9011779E-02 0.9463263E-02 0.2174093E+03 7.7775 14 Mn++ 0.1645891E-10 0.9333294E-09 0.5124008E-04 8.7696 15 HPO4-- 0.5042089E-06 0.5105116E-06 0.4896479E-01 13.2581 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.2715301E+00 -.9413235E-02 -.2621168E+00 0.0000000E+00 2 H2O 0.5530268E+02 0.5538107E+02 -.7839226E-01 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.4799767E-03 0.2550571E-04 0.4544710E-03 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.4544722E-03 -.1241844E-08 -.4544710E-03 0.0000000E+00 7 Al+++ 0.5347290E-01 0.3452326E-04 0.5343838E-01 0.0000000E+00 8 H4SiO4 0.1707592E+00 0.4699031E-02 0.1660602E+00 0.0000000E+00 9 Ca++ 0.1887566E-01 0.5511792E-07 0.1887561E-01 0.0000000E+00 10 Mg++ 0.1301508E-01 0.6613999E-10 0.1301508E-01 0.0000000E+00 11 Fe++ 0.1169263E-01 0.2901355E-07 0.1169260E-01 0.0000000E+00 12 K+ 0.3481741E-02 0.7113691E-04 0.3410604E-02 0.0000000E+00 13 Na+ 0.2074481E-01 0.9441431E-02 0.1130338E-01 0.0000000E+00 14 Mn++ 0.2843356E-03 0.9311762E-09 0.2843347E-03 0.0000000E+00 15 HPO4-- 0.9704234E-04 0.5093339E-06 0.9653300E-04 0.0000000E+00 Chg. balance for solid moles: -.1426E-16 Mass of aqueous solution: 0.998378E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 16.3990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 0.1130E-01 -1.947 2.964 0.472 16.56 1.138 andradite 0.1168E-02 -2.933 0.5935 -0.227 3.316 0.1542 grossular 0.5556E-04 -4.255 0.2503E-01 -1.602 0.1398 0.6964E-02 apatite-OH 0.3218E-04 -4.492 0.1616E-01 -1.791 0.9031E-01 0.5136E-02 clinochlore 0.2603E-02 -2.585 1.447 0.160 8.083 0.5503 daphnite 0.1576E-02 -2.802 1.124 0.051 6.282 0.3407 chlorite-Mn 0.5687E-04 -4.245 0.4032E-01 -1.395 0.2253 0.1285E-01 hematite 0.6500E-03 -3.187 0.1038 -0.984 0.5799 0.1967E-01 microcline 0.3393E-02 -2.469 0.9444 -0.025 5.276 0.3689 stilbite 0.1504E-01 -1.823 10.60 1.025 59.23 4.945 stilpnomelane-Fe 0.3550E-04 -4.450 0.3826E-01 -1.417 0.2138 0.1322E-01 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.9546E+00 0.9546E+00 1.0000 -0.020 grossular 0.4541E-01 0.4541E-01 1.0000 -1.343 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.6145E+00 0.6145E+00 1.0000 -0.211 daphnite 0.3720E+00 0.3720E+00 1.0000 -0.429 chlorite-Mn 0.1343E-01 0.1343E-01 1.0000 -1.872 hematite 0.1000E+01 0.1000E+01 1.0000 0.000 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 17.898650 g Volume = 7.554755 cm3 Porosity: 0.0641% V(tot) - V(min): 0.48450E-02 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 16.3990000 g log = 1.2148 Original solution: 1000.0103000 g Original solution / Rock added: 60.98 (Water/Rock Ratio), log = 1.7852 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0203 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.1000E+01 0.9860 0.1006E+01 0.1020E+01 CO2,gas 0.1734E-06 1.0071 0.1782E-06 0.1769E-06 CH4,gas 0.6617E-15 1.0125 0.6836E-15 0.6751E-15 H2,gas 0.2439E-05 1.0005 0.2490E-05 0.2488E-05 H2S,gas 0.1410E-13 0.9960 0.1433E-13 0.1439E-13 S2,gas 0.1219E-35 1.0000 0.1244E-35 0.1244E-35 CO,gas 0.1159E-15 1.0000 0.1182E-15 0.1182E-15 SO3,gas 0.1019E-39 1.0000 0.1040E-39 0.1040E-39 SO2,gas 0.9873E-23 1.0000 0.1007E-22 0.1007E-22 HCl,gas 0.5033E-17 1.0000 0.5135E-17 0.5135E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 16 albite -0.38 -0.38 0.00 0.000 -0.94784E-12 22 andradite 39.01 39.01 0.00 0.000 0.12132E-10 23 grossular 32.73 32.73 0.00 0.000 0.48529E-10 32 apatite-OH -18.15 -18.15 0.00 0.000 0.00000E+00 46 clinochlore 39.07 39.07 0.00 0.000 0.24265E-10 47 daphnite 28.97 28.97 0.00 0.000 -0.60662E-11 48 chlorite-Mn 46.87 46.87 0.00 0.000 0.36397E-10 90 hematite 12.57 12.57 0.00 0.000 0.30331E-11 116 microcline -2.49 -2.49 0.00 0.000 0.15165E-11 163 stilbite -7.52 -7.52 0.00 0.000 0.15165E-10 164 stilpnomelane-Fe 13.02 13.02 0.00 0.000 -0.27298E-10 209 nontronite-Na 3.52 3.52 0.00 0.000 -0.25283E+01 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -15.11 -8.45 -2.816 0.14425E+05 -6.749 3 CH4,gas 4.54 -12.32 -16.86 -4.216 0.28795E+05 -15.165 4 H2,gas 8.00 0.70 -7.30 -4.173 0.12469E+05 -5.604 5 H2S,gas -6.23 -21.77 -15.54 -7.771 0.26539E+05 -13.844 6 S2,gas -7.34 -44.94 -37.60 -5.785 0.64208E+05 -35.905 7 CO,gas 3.21 -14.41 -17.63 -5.423 0.30096E+05 -15.927 8 SO3,gas 17.12 -24.56 -41.68 -10.420 0.71171E+05 -39.983 9 SO2,gas 0.83 -23.86 -24.70 -6.586 0.42167E+05 -22.997 10 HCl,gas 5.19 -13.80 -18.99 -9.494 0.32422E+05 -17.289 11 acmite 7.71 7.41 -0.30 -0.032 0.52004E+03 15 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 19 spessartine 24.46 19.97 -4.49 -0.224 0.76635E+04 20 analcite 3.32 2.94 -0.38 -0.042 0.64541E+03 21 andalusite 5.00 0.32 -4.69 -0.469 0.80006E+04 26 annite 20.12 17.41 -2.72 -0.151 0.46362E+04 27 phlogopite 27.06 24.12 -2.94 -0.163 0.50200E+04 29 anorthite 12.71 9.12 -3.59 -0.276 0.61361E+04 35 aragonite 0.97 -2.98 -3.95 -1.315 0.67381E+04 36 brucite 12.57 8.87 -3.70 -0.740 0.63146E+04 37 calcite 0.81 -2.98 -3.79 -1.264 0.64739E+04 38 carnegieite-low 9.02 6.27 -2.75 -0.393 0.46984E+04 39 carnegieite-high 10.09 6.27 -3.82 -0.546 0.65254E+04 40 carpholite-Mg 8.58 5.86 -2.72 -0.182 0.46504E+04 41 carpholite-Fe 6.71 3.62 -3.09 -0.206 0.52811E+04 42 celadonite 5.34 3.06 -2.29 -0.134 0.39024E+04 43 celadonite-Fe 3.88 0.82 -3.06 -0.180 0.52235E+04 44 chrysotile 23.89 19.96 -3.94 -0.328 0.67219E+04 50 chloritoid-Mg 13.20 9.19 -4.01 -0.267 0.68494E+04 51 chloritoid-Fe 9.17 6.95 -2.23 -0.148 0.38011E+04 52 chloritoid-Mn 11.40 9.09 -2.32 -0.154 0.39539E+04 54 coesite -2.38 -3.33 -0.95 -0.317 0.16250E+04 59 corundum 8.38 3.64 -4.74 -0.431 0.80926E+04 61 cristobalite -2.56 -3.33 -0.77 -0.256 0.13103E+04 63 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71234E+04 65 diaspore 2.87 1.82 -1.05 -0.175 0.17961E+04 67 diopside 16.18 14.34 -1.84 -0.184 0.31383E+04 68 hedenbergite 14.21 12.10 -2.10 -0.210 0.35921E+04 75 epidote 24.67 24.20 -0.47 -0.023 0.80161E+03 76 clinozoisite 22.81 19.74 -3.07 -0.139 0.52366E+04 77 epidote-Fe 29.84 28.66 -1.18 -0.061 0.20132E+04 78 fayalite 14.05 9.94 -4.11 -0.587 0.70183E+04 79 ferrosilite 11.15 6.61 -4.54 -0.454 0.77550E+04 83 gibbsite 4.08 1.82 -2.26 -0.322 0.38546E+04 84 glaucophane 22.97 19.19 -3.79 -0.102 0.64660E+04 85 glaucophane-Fe 17.28 12.47 -4.80 -0.130 0.82033E+04 87 greenalite 16.14 13.24 -2.90 -0.242 0.49522E+04 91 heulandite -5.83 -7.52 -1.69 -0.077 0.28938E+04 95 jadeite 4.22 2.94 -1.27 -0.127 0.21709E+04 96 julgoldite 70.43 66.94 -3.48 -0.090 0.59488E+04 97 kalsilite 7.58 4.17 -3.41 -0.488 0.58309E+04 98 kaolinite -1.33 -3.01 -1.68 -0.153 0.28670E+04 99 kyanite 4.88 0.32 -4.56 -0.456 0.77865E+04 101 laumontite 2.88 2.46 -0.42 -0.028 0.72100E+03 102 lawsonite 9.62 9.12 -0.50 -0.033 0.85280E+03 103 leucite 4.12 0.84 -3.28 -0.328 0.55964E+04 105 lizardite 23.24 19.96 -3.29 -0.274 0.56145E+04 107 magnetite 20.09 19.20 -0.89 -0.073 0.15191E+04 108 minnesotaite 10.39 6.58 -3.80 -0.224 0.64959E+04 110 magnesioferrite 26.21 21.44 -4.78 -0.390 0.81546E+04 113 margarite 17.32 12.76 -4.56 -0.183 0.77918E+04 120 muscovite 2.58 1.16 -1.43 -0.084 0.24337E+04 121 paragonite 4.24 3.26 -0.98 -0.058 0.16728E+04 122 nepheline 8.34 6.27 -2.07 -0.295 0.35308E+04 128 periclase-Fe 11.63 6.63 -5.00 -1.249 0.85289E+04 134 phlogopite-Na 29.65 26.23 -3.42 -0.190 0.58388E+04 136 prehnite 19.37 17.92 -1.45 -0.086 0.24836E+04 137 prehnite-Fe 22.50 22.38 -0.12 -0.007 0.20358E+03 138 pumpellyite-Fe 46.27 44.29 -1.98 -0.044 0.33831E+04 139 pumpellyite-Mg 48.99 46.53 -2.47 -0.055 0.42140E+04 145 pyroxmangite 7.40 5.44 -1.96 -0.391 0.33413E+04 146 pyrophyllite -6.18 -9.67 -3.49 -0.218 0.59617E+04 147 quartz -2.99 -3.33 -0.34 -0.113 0.57764E+03 152 rhodonite 7.45 5.44 -2.00 -0.401 0.34215E+04 153 sanidine -1.28 -2.49 -1.21 -0.093 0.20677E+04 156 sillimanite 5.26 0.32 -4.95 -0.495 0.84445E+04 165 stilpnomelane-Mg 27.44 24.21 -3.23 -0.096 0.55158E+04 171 talc 16.49 13.30 -3.19 -0.188 0.54484E+04 174 tephroite 18.09 14.21 -3.87 -0.553 0.66154E+04 177 topaz-H 4.62 0.32 -4.30 -0.391 0.73466E+04 178 tridymite -2.63 -3.33 -0.70 -0.234 0.11976E+04 187 wairakite 3.95 2.46 -1.49 -0.088 0.25430E+04 188 walstromite 11.51 8.80 -2.71 -0.542 0.46247E+04 189 wollastonite 10.46 8.80 -1.66 -0.332 0.28351E+04 190 pseudo-wollastonite 11.00 8.80 -2.20 -0.440 0.37549E+04 191 zoisite 22.85 19.74 -3.11 -0.141 0.53107E+04 192 akaganeite 7.75 6.28 -1.47 -0.318 0.25125E+04 193 beidellite-Ca -1.65 -5.97 -4.32 -0.267 0.73783E+04 195 beidellite-K -1.52 -6.10 -4.58 -0.280 0.78117E+04 196 beidellite-Mg -1.79 -6.50 -4.71 -0.292 0.80500E+04 197 beidellite-Na -1.34 -5.40 -4.06 -0.249 0.69309E+04 199 chalcedony -2.80 -3.33 -0.53 -0.175 0.89693E+03 201 montmorillonite-Ca -2.29 -5.34 -3.05 -0.189 0.52067E+04 202 montmorillonite-K -2.24 -5.47 -3.23 -0.198 0.55183E+04 203 montmorillonite-Mg -2.48 -5.88 -3.40 -0.210 0.58017E+04 204 montmorillonite-Na -2.04 -4.77 -2.74 -0.168 0.46732E+04 205 nontronite-Ca 3.21 2.96 -0.26 -0.017 0.44180E+03 206 nontronite-H 2.53 0.95 -1.58 -0.106 0.26946E+04 207 nontronite-K 3.34 2.83 -0.51 -0.033 0.87659E+03 208 nontronite-Mg 3.07 2.42 -0.66 -0.043 0.11208E+04 224 tobermorite 9.82 6.78 -3.05 -0.832 0.52040E+04 233 boehmite 4.41 1.82 -2.58 -0.431 0.44130E+04 235 ferrous-oxide 9.81 6.63 -3.18 -0.795 0.54298E+04 240 silica-amorphous -2.09 -3.33 -1.24 -0.412 0.21111E+04 242 an20ab80 2.02 1.52 -0.50 -0.039 0.85638E+03 243 an25ab75 2.65 1.99 -0.65 -0.050 0.11174E+04 244 an30ab70 3.28 2.47 -0.81 -0.063 0.13881E+04 245 tr.625ac.25prg.125 45.16 40.57 -4.60 -0.124 0.78507E+04 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 8 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 16.3990000 Water: Moles liquid = 0.5538E+02 kg liquid = 0.9977E+00 Moles total = 0.5530E+02 kg total = 0.9963E+00 Activity = 1.0000 Stoichiometric ionic strength = .5049890E-02 Osmotic coef. = 0.9622 True ionic strength = .9112596E-02 Chg. balance for total moles = 0.6621E-13 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.14989E-09 -9.8242 0.13154E-09 -9.8809 0.87760E+00 -0.0567 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13798E-03 -3.8602 0.12071E-03 -3.9183 0.87483E+00 -0.0581 4 SO4-- 0.25546E-04 -4.5927 0.15889E-04 -4.7989 0.62199E+00 -0.2062 5 HCO3- 0.67662E-05 -5.1697 0.59238E-05 -5.2274 0.87549E+00 -0.0577 6 HS- 0.14710E-11 -11.8324 0.12870E-11 -11.8904 0.87489E+00 -0.0580 7 Al+++ 0.43449E-27 -27.3620 0.15159E-27 -27.8193 0.34890E+00 -0.4573 8 H4SiO4 0.46958E-03 -3.3283 0.46958E-03 -3.3283 0.10000E+01 0.0000 9 Ca++ 0.37581E-07 -7.4250 0.23286E-07 -7.6329 0.61961E+00 -0.2079 10 Mg++ 0.20737E-10 -10.6833 0.12818E-10 -10.8922 0.61813E+00 -0.2089 11 Fe++ 0.11983E-12 -12.9214 0.74113E-13 -13.1301 0.61848E+00 -0.2087 12 K+ 0.71060E-04 -4.1484 0.62221E-04 -4.2061 0.87561E+00 -0.0577 13 Na+ 0.90090E-02 -2.0453 0.78807E-02 -2.1034 0.87475E+00 -0.0581 14 Mn++ 0.16425E-10 -10.7845 0.10163E-10 -10.9930 0.61875E+00 -0.2085 15 HPO4-- 0.50344E-06 -6.2980 0.31316E-06 -6.5042 0.62203E+00 -0.2062 16 HSiO3- 0.38103E-02 -2.4190 0.33333E-02 -2.4771 0.87483E+00 -0.0581 17 Ca(HSiO3)+ 0.20186E-08 -8.6950 0.17677E-08 -8.7526 0.87571E+00 -0.0576 18 Mg(HSiO3)+ 0.13828E-11 -11.8592 0.12110E-11 -11.9169 0.87571E+00 -0.0576 19 NaHSiO3,aq 0.42486E-03 -3.3718 0.42486E-03 -3.3718 0.10000E+01 0.0000 20 AlO+ 0.13610E-14 -14.8661 0.11919E-14 -14.9238 0.87571E+00 -0.0576 22 HAlO2,aq 0.18044E-08 -8.7437 0.18044E-08 -8.7437 0.10000E+01 0.0000 23 AlO2- 0.34743E-04 -4.4591 0.30365E-04 -4.5176 0.87399E+00 -0.0585 24 CH4,aq 0.46681E-18 -18.3309 0.46609E-18 -18.3315 0.99844E+00 -0.0007 29 CO,aq 0.79395E-19 -19.1002 0.79395E-19 -19.1002 0.10000E+01 0.0000 30 CO2,aq 0.16676E-08 -8.7779 0.16650E-08 -8.7786 0.99844E+00 -0.0007 31 CO3-2 0.63312E-05 -5.1985 0.39335E-05 -5.4052 0.62129E+00 -0.2067 32 CaCO3,aq 0.11485E-08 -8.9399 0.11485E-08 -8.9399 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.40209E-11 -11.3957 0.35211E-11 -11.4533 0.87571E+00 -0.0576 34 CaCl+ 0.51943E-11 -11.2845 0.45487E-11 -11.3421 0.87571E+00 -0.0576 35 CaCl2,aq 0.13044E-15 -15.8846 0.13044E-15 -15.8846 0.10000E+01 0.0000 36 CaOH+ 0.14407E-07 -7.8414 0.12616E-07 -7.8991 0.87571E+00 -0.0576 37 CaSO4,aq 0.11749E-09 -9.9300 0.11749E-09 -9.9300 0.10000E+01 0.0000 38 HCl,aq 0.29096E-14 -14.5362 0.29096E-14 -14.5362 0.10000E+01 0.0000 43 FeCl+ 0.16170E-16 -16.7913 0.14160E-16 -16.8489 0.87571E+00 -0.0576 46 FeO,aq 0.16647E-09 -9.7787 0.16647E-09 -9.7787 0.10000E+01 0.0000 47 FeOH+ 0.20943E-10 -10.6790 0.18340E-10 -10.7366 0.87571E+00 -0.0576 48 HFeO2- 0.15136E-07 -7.8200 0.13241E-07 -7.8781 0.87483E+00 -0.0581 49 FeO+ 0.11466E-14 -14.9406 0.10040E-14 -14.9982 0.87571E+00 -0.0576 51 FeO2- 0.13572E-07 -7.8673 0.11873E-07 -7.9254 0.87483E+00 -0.0581 52 HFeO2,aq 0.19864E-09 -9.7019 0.19864E-09 -9.7019 0.10000E+01 0.0000 53 H2,aq 0.19011E-08 -8.7210 0.18982E-08 -8.7217 0.99844E+00 -0.0007 54 KCl,aq 0.13612E-09 -9.8661 0.13612E-09 -9.8661 0.10000E+01 0.0000 55 KHSO4,aq 0.36769E-18 -18.4345 0.36769E-18 -18.4345 0.10000E+01 0.0000 56 KOH,aq 0.20200E-06 -6.6946 0.20200E-06 -6.6946 0.10000E+01 0.0000 57 KSO4- 0.17536E-07 -7.7561 0.15341E-07 -7.8141 0.87483E+00 -0.0581 58 MgCO3,aq 0.15847E-12 -12.8001 0.15847E-12 -12.8001 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.22616E-14 -14.6456 0.19805E-14 -14.7032 0.87571E+00 -0.0576 60 MgCl+ 0.25915E-14 -14.5865 0.22694E-14 -14.6441 0.87571E+00 -0.0576 61 MgOH+ 0.43884E-10 -10.3577 0.38429E-10 -10.4153 0.87571E+00 -0.0576 63 MnO,aq 0.60825E-09 -9.2159 0.60825E-09 -9.2159 0.10000E+01 0.0000 64 MnOH+ 0.26678E-09 -9.5738 0.23362E-09 -9.6315 0.87571E+00 -0.0576 65 MnO2-2 0.18777E-11 -11.7264 0.11666E-11 -11.9331 0.62129E+00 -0.2067 66 HMnO2- 0.38431E-10 -10.4153 0.33620E-10 -10.4734 0.87483E+00 -0.0581 69 MnCl+ 0.86263E-14 -14.0642 0.75541E-14 -14.1218 0.87571E+00 -0.0576 70 MnSO4,aq 0.46618E-13 -13.3314 0.46618E-13 -13.3314 0.10000E+01 0.0000 71 NaCl,aq 0.31525E-06 -6.5014 0.31525E-06 -6.5014 0.10000E+01 0.0000 72 NaOH,aq 0.25740E-04 -4.5894 0.25740E-04 -4.5894 0.10000E+01 0.0000 74 OH- 0.50256E-02 -2.2988 0.43923E-02 -2.3573 0.87399E+00 -0.0585 79 HPO3-2 0.29816E-17 -17.5256 0.18524E-17 -17.7323 0.62129E+00 -0.2067 82 H3PO4,aq 0.37898E-16 -16.4214 0.37898E-16 -16.4214 0.10000E+01 0.0000 83 H2PO4- 0.86821E-09 -9.0614 0.75991E-09 -9.1192 0.87526E+00 -0.0579 84 PO4-3 0.54256E-08 -8.2655 0.19424E-08 -8.7117 0.35800E+00 -0.4461 87 H2P2O7-2 0.72878E-19 -19.1374 0.45279E-19 -19.3441 0.62129E+00 -0.2067 88 HP2O7-3 0.19691E-15 -15.7057 0.68732E-16 -16.1628 0.34904E+00 -0.4571 89 P2O7-4 0.78873E-15 -15.1031 0.12483E-15 -15.9037 0.15826E+00 -0.8006 90 H2S,aq 0.52404E-15 -15.2806 0.52322E-15 -15.2813 0.99844E+00 -0.0007 97 SO3-2 0.62608E-14 -14.2034 0.39193E-14 -14.4068 0.62601E+00 -0.2034 98 HSO3- 0.36899E-16 -16.4330 0.32280E-16 -16.4911 0.87483E+00 -0.0581 99 HSO4- 0.22990E-11 -11.6385 0.20142E-11 -11.6959 0.87615E+00 -0.0574 Charge balance for all species = 0.7071E-13 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.1498880E-09 -.9432071E-02 -.9500446E+01 0.0000 2 H2O 0.1000000E+01 0.5550914E+02 0.9993284E+06 0.0000 3 Cl- 0.1379778E-03 0.1382932E-03 0.4899547E+01 5.9627 4 SO4-- 0.2554578E-04 0.2556468E-04 0.2454101E+01 14.9630 5 HCO3- 0.6766234E-05 0.1310022E-04 0.7987907E+00 4.6535 6 HS- 0.1471037E-11 -.1244612E-08 -.4113358E-04 -2.0095 7 Al+++ 0.4344872E-27 0.3474498E-04 0.9368292E+00 1.8235 8 H4SiO4 0.4695843E-03 0.4704711E-02 0.4518852E+03 -3.3283 9 Ca++ 0.3758145E-07 0.5528230E-07 0.2214086E-02 12.1290 10 Mg++ 0.2073684E-10 0.6616659E-10 0.1607540E-05 8.8697 11 Fe++ 0.1198303E-12 0.2909439E-07 0.1623721E-02 6.6318 12 K+ 0.7105989E-04 0.7127956E-04 0.2785263E+01 5.6749 13 Na+ 0.9009010E-02 0.9459926E-02 0.2173328E+03 7.7775 14 Mn++ 0.1642483E-10 0.9318229E-09 0.5115740E-04 8.7689 15 HPO4-- 0.5034433E-06 0.5097372E-06 0.4889053E-01 13.2576 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.2715301E+00 -.9410315E-02 -.2621197E+00 0.0000000E+00 2 H2O 0.5530268E+02 0.5538110E+02 -.7841930E-01 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.4799767E-03 0.2550571E-04 0.4544710E-03 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.4544722E-03 -.1241741E-08 -.4544710E-03 0.0000000E+00 7 Al+++ 0.5347290E-01 0.3466484E-04 0.5343824E-01 0.0000000E+00 8 H4SiO4 0.1707592E+00 0.4693859E-02 0.1660654E+00 0.0000000E+00 9 Ca++ 0.1887566E-01 0.5515479E-07 0.1887561E-01 0.0000000E+00 10 Mg++ 0.1301508E-01 0.6601397E-10 0.1301508E-01 0.0000000E+00 11 Fe++ 0.1169263E-01 0.2902728E-07 0.1169260E-01 0.0000000E+00 12 K+ 0.3481741E-02 0.7111515E-04 0.3410626E-02 0.0000000E+00 13 Na+ 0.2074481E-01 0.9438107E-02 0.1130670E-01 0.0000000E+00 14 Mn++ 0.2843356E-03 0.9296736E-09 0.2843347E-03 0.0000000E+00 15 HPO4-- 0.9704234E-04 0.5085615E-06 0.9653378E-04 0.0000000E+00 Chg. balance for solid moles: 0.4017E-16 Mass of aqueous solution: 0.998378E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 16.3990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 0.1130E-01 -1.947 2.964 0.472 16.56 1.138 andradite 0.1169E-02 -2.932 0.5939 -0.226 3.318 0.1543 grossular 0.5581E-04 -4.253 0.2514E-01 -1.600 0.1405 0.6995E-02 apatite-OH 0.3218E-04 -4.492 0.1616E-01 -1.791 0.9031E-01 0.5136E-02 clinochlore 0.2603E-02 -2.585 1.447 0.160 8.083 0.5503 daphnite 0.1579E-02 -2.802 1.127 0.052 6.295 0.3414 chlorite-Mn 0.5687E-04 -4.245 0.4032E-01 -1.395 0.2253 0.1285E-01 hematite 0.6406E-03 -3.193 0.1023 -0.990 0.5716 0.1939E-01 microcline 0.3394E-02 -2.469 0.9448 -0.025 5.279 0.3691 stilbite 0.1504E-01 -1.823 10.60 1.025 59.22 4.944 stilpnomelane-Fe 0.3228E-04 -4.491 0.3480E-01 -1.458 0.1944 0.1202E-01 nontronite-Na 0.8637E-05 -5.064 0.3673E-02 -2.435 0.2052E-01 0.1141E-02 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.9544E+00 0.9544E+00 1.0000 -0.020 grossular 0.4558E-01 0.4558E-01 1.0000 -1.341 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.6141E+00 0.6141E+00 1.0000 -0.212 daphnite 0.3725E+00 0.3725E+00 1.0000 -0.429 chlorite-Mn 0.1342E-01 0.1342E-01 1.0000 -1.872 hematite 0.1000E+01 0.1000E+01 1.0000 0.000 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 nontronite-Na 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 17.898730 g Volume = 7.554540 cm3 Porosity: 0.0669% V(tot) - V(min): 0.50604E-02 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 16.3990000 g log = 1.2148 Original solution: 1000.0103000 g Original solution / Rock added: 60.98 (Water/Rock Ratio), log = 1.7852 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0203 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.1000E+01 0.9860 0.1006E+01 0.1020E+01 CO2,gas 0.1734E-06 1.0071 0.1781E-06 0.1769E-06 CH4,gas 0.6641E-15 1.0125 0.6860E-15 0.6776E-15 H2,gas 0.2441E-05 1.0005 0.2492E-05 0.2491E-05 H2S,gas 0.1415E-13 0.9960 0.1438E-13 0.1444E-13 S2,gas 0.1225E-35 1.0000 0.1250E-35 0.1250E-35 CO,gas 0.1160E-15 1.0000 0.1183E-15 0.1183E-15 SO3,gas 0.1019E-39 1.0000 0.1040E-39 0.1040E-39 SO2,gas 0.9878E-23 1.0000 0.1008E-22 0.1008E-22 HCl,gas 0.5032E-17 1.0000 0.5134E-17 0.5134E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 16 albite -0.38 -0.38 0.00 0.000 -0.13080E-10 22 andradite 39.01 39.01 0.00 0.000 -0.12132E-10 23 grossular 32.73 32.73 0.00 0.000 -0.24265E-10 32 apatite-OH -18.15 -18.15 0.00 0.000 -0.60662E-11 46 clinochlore 39.07 39.07 0.00 0.000 0.00000E+00 47 daphnite 28.97 28.97 0.00 0.000 0.00000E+00 48 chlorite-Mn 46.87 46.87 0.00 0.000 0.00000E+00 90 hematite 12.57 12.57 0.00 0.000 -0.30331E-11 116 microcline -2.49 -2.49 0.00 0.000 -0.10616E-10 163 stilbite -7.52 -7.52 0.00 0.000 -0.90992E-11 164 stilpnomelane-Fe 13.02 13.02 0.00 0.000 0.21232E-10 209 nontronite-Na 3.52 3.52 0.00 0.000 -0.12132E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -15.11 -8.45 -2.816 0.14425E+05 -6.749 3 CH4,gas 4.54 -12.32 -16.86 -4.216 0.28792E+05 -15.164 4 H2,gas 8.00 0.70 -7.30 -4.173 0.12469E+05 -5.603 5 H2S,gas -6.23 -21.77 -15.54 -7.771 0.26536E+05 -13.842 6 S2,gas -7.34 -44.94 -37.60 -5.785 0.64204E+05 -35.903 7 CO,gas 3.21 -14.41 -17.63 -5.423 0.30096E+05 -15.927 8 SO3,gas 17.12 -24.56 -41.68 -10.421 0.71171E+05 -39.983 9 SO2,gas 0.83 -23.86 -24.70 -6.585 0.42167E+05 -22.997 10 HCl,gas 5.19 -13.80 -18.99 -9.494 0.32422E+05 -17.290 11 acmite 7.71 7.40 -0.31 -0.032 0.52197E+03 15 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 19 spessartine 24.46 19.97 -4.49 -0.224 0.76641E+04 20 analcite 3.32 2.94 -0.38 -0.042 0.64447E+03 21 andalusite 5.00 0.32 -4.68 -0.468 0.79958E+04 26 annite 20.12 17.41 -2.71 -0.151 0.46351E+04 27 phlogopite 27.06 24.12 -2.94 -0.163 0.50234E+04 29 anorthite 12.71 9.12 -3.59 -0.276 0.61314E+04 35 aragonite 0.97 -2.98 -3.95 -1.315 0.67375E+04 36 brucite 12.57 8.87 -3.70 -0.740 0.63157E+04 37 calcite 0.81 -2.98 -3.79 -1.264 0.64733E+04 38 carnegieite-low 9.02 6.27 -2.75 -0.393 0.46966E+04 39 carnegieite-high 10.09 6.27 -3.82 -0.546 0.65236E+04 40 carpholite-Mg 8.58 5.86 -2.72 -0.181 0.46477E+04 41 carpholite-Fe 6.71 3.62 -3.09 -0.206 0.52769E+04 42 celadonite 5.34 3.05 -2.29 -0.135 0.39045E+04 43 celadonite-Fe 3.88 0.82 -3.06 -0.180 0.52241E+04 44 chrysotile 23.89 19.95 -3.94 -0.328 0.67272E+04 50 chloritoid-Mg 13.20 9.19 -4.01 -0.267 0.68458E+04 51 chloritoid-Fe 9.17 6.95 -2.22 -0.148 0.37960E+04 52 chloritoid-Mn 11.40 9.09 -2.31 -0.154 0.39502E+04 54 coesite -2.38 -3.33 -0.95 -0.317 0.16259E+04 59 corundum 8.38 3.65 -4.74 -0.431 0.80868E+04 61 cristobalite -2.56 -3.33 -0.77 -0.256 0.13113E+04 63 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71234E+04 65 diaspore 2.87 1.82 -1.05 -0.175 0.17932E+04 67 diopside 16.18 14.34 -1.84 -0.184 0.31405E+04 68 hedenbergite 14.21 12.10 -2.10 -0.210 0.35927E+04 75 epidote 24.67 24.20 -0.47 -0.023 0.79698E+03 76 clinozoisite 22.81 19.74 -3.06 -0.139 0.52291E+04 77 epidote-Fe 29.84 28.66 -1.18 -0.061 0.20115E+04 78 fayalite 14.05 9.94 -4.11 -0.587 0.70185E+04 79 ferrosilite 11.15 6.61 -4.54 -0.454 0.77562E+04 83 gibbsite 4.08 1.82 -2.26 -0.322 0.38517E+04 84 glaucophane 22.97 19.18 -3.79 -0.102 0.64714E+04 85 glaucophane-Fe 17.28 12.47 -4.80 -0.130 0.82041E+04 87 greenalite 16.14 13.24 -2.90 -0.242 0.49530E+04 91 heulandite -5.83 -7.52 -1.69 -0.077 0.28938E+04 95 jadeite 4.22 2.94 -1.27 -0.127 0.21700E+04 96 julgoldite 70.43 66.94 -3.48 -0.091 0.59503E+04 97 kalsilite 7.58 4.17 -3.41 -0.488 0.58290E+04 98 kaolinite -1.33 -3.01 -1.68 -0.152 0.28631E+04 99 kyanite 4.88 0.32 -4.56 -0.456 0.77817E+04 101 laumontite 2.88 2.46 -0.42 -0.028 0.71817E+03 102 lawsonite 9.62 9.12 -0.50 -0.033 0.84809E+03 103 leucite 4.12 0.84 -3.28 -0.328 0.55955E+04 105 lizardite 23.24 19.95 -3.29 -0.274 0.56199E+04 107 magnetite 20.09 19.20 -0.89 -0.073 0.15187E+04 108 minnesotaite 10.39 6.58 -3.81 -0.224 0.64986E+04 110 magnesioferrite 26.21 21.44 -4.78 -0.390 0.81558E+04 113 margarite 17.32 12.77 -4.56 -0.182 0.77814E+04 120 muscovite 2.58 1.16 -1.42 -0.084 0.24279E+04 121 paragonite 4.24 3.26 -0.98 -0.057 0.16670E+04 122 nepheline 8.34 6.27 -2.07 -0.295 0.35289E+04 128 periclase-Fe 11.63 6.63 -4.99 -1.249 0.85285E+04 134 phlogopite-Na 29.65 26.23 -3.42 -0.190 0.58422E+04 136 prehnite 19.37 17.92 -1.45 -0.085 0.24789E+04 137 prehnite-Fe 22.50 22.38 -0.12 -0.007 0.20183E+03 138 pumpellyite-Fe 46.27 44.30 -1.97 -0.044 0.33706E+04 139 pumpellyite-Mg 48.99 46.53 -2.46 -0.055 0.42031E+04 145 pyroxmangite 7.40 5.44 -1.96 -0.392 0.33434E+04 146 pyrophyllite -6.18 -9.67 -3.49 -0.218 0.59597E+04 147 quartz -2.99 -3.33 -0.34 -0.113 0.57858E+03 152 rhodonite 7.45 5.44 -2.01 -0.401 0.34236E+04 153 sanidine -1.28 -2.49 -1.21 -0.093 0.20677E+04 156 sillimanite 5.26 0.32 -4.94 -0.494 0.84397E+04 165 stilpnomelane-Mg 27.44 24.21 -3.23 -0.097 0.55233E+04 171 talc 16.49 13.30 -3.20 -0.188 0.54556E+04 174 tephroite 18.09 14.21 -3.88 -0.554 0.66187E+04 177 topaz-H 4.62 0.32 -4.30 -0.391 0.73418E+04 178 tridymite -2.63 -3.33 -0.70 -0.234 0.11986E+04 187 wairakite 3.95 2.46 -1.49 -0.088 0.25401E+04 188 walstromite 11.51 8.80 -2.71 -0.542 0.46248E+04 189 wollastonite 10.46 8.80 -1.66 -0.332 0.28352E+04 190 pseudo-wollastonite 11.00 8.80 -2.20 -0.440 0.37550E+04 191 zoisite 22.85 19.74 -3.11 -0.141 0.53032E+04 192 akaganeite 7.75 6.28 -1.47 -0.318 0.25125E+04 193 beidellite-Ca -1.65 -5.96 -4.32 -0.267 0.73749E+04 195 beidellite-K -1.52 -6.09 -4.57 -0.280 0.78085E+04 196 beidellite-Mg -1.79 -6.50 -4.71 -0.292 0.80470E+04 197 beidellite-Na -1.34 -5.40 -4.06 -0.248 0.69277E+04 199 chalcedony -2.80 -3.33 -0.53 -0.175 0.89788E+03 201 montmorillonite-Ca -2.29 -5.34 -3.05 -0.189 0.52059E+04 202 montmorillonite-K -2.24 -5.47 -3.23 -0.198 0.55177E+04 203 montmorillonite-Mg -2.48 -5.88 -3.40 -0.210 0.58012E+04 204 montmorillonite-Na -2.04 -4.77 -2.74 -0.168 0.46726E+04 205 nontronite-Ca 3.21 2.95 -0.26 -0.017 0.44418E+03 206 nontronite-H 2.53 0.95 -1.58 -0.106 0.26971E+04 207 nontronite-K 3.34 2.83 -0.51 -0.033 0.87912E+03 208 nontronite-Mg 3.07 2.42 -0.66 -0.043 0.11235E+04 224 tobermorite 9.82 6.78 -3.05 -0.832 0.52042E+04 233 boehmite 4.41 1.82 -2.58 -0.430 0.44101E+04 235 ferrous-oxide 9.81 6.63 -3.18 -0.795 0.54294E+04 240 silica-amorphous -2.09 -3.33 -1.24 -0.412 0.21121E+04 242 an20ab80 2.02 1.52 -0.50 -0.039 0.85544E+03 243 an25ab75 2.65 1.99 -0.65 -0.050 0.11163E+04 244 an30ab70 3.28 2.47 -0.81 -0.062 0.13867E+04 245 tr.625ac.25prg.125 45.16 40.56 -4.60 -0.124 0.78589E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 0.4000000 g Current total amount of reactant added: 16.3990000 g New total amount of reactant added: 16.7990000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.6625E-13 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 7 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 16.7990000 Water: Moles liquid = 0.5538E+02 kg liquid = 0.9977E+00 Moles total = 0.5530E+02 kg total = 0.9962E+00 Activity = 1.0000 Stoichiometric ionic strength = .5049898E-02 Osmotic coef. = 0.9622 True ionic strength = .9112602E-02 Chg. balance for total moles = 0.6625E-13 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.14989E-09 -9.8242 0.13154E-09 -9.8809 0.87760E+00 -0.0567 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13798E-03 -3.8602 0.12071E-03 -3.9183 0.87483E+00 -0.0581 4 SO4-- 0.25547E-04 -4.5927 0.15890E-04 -4.7989 0.62199E+00 -0.2062 5 HCO3- 0.67665E-05 -5.1696 0.59240E-05 -5.2274 0.87549E+00 -0.0577 6 HS- 0.14711E-11 -11.8324 0.12871E-11 -11.8904 0.87489E+00 -0.0580 7 Al+++ 0.43449E-27 -27.3620 0.15159E-27 -27.8193 0.34890E+00 -0.4573 8 H4SiO4 0.46958E-03 -3.3283 0.46958E-03 -3.3283 0.10000E+01 0.0000 9 Ca++ 0.37581E-07 -7.4250 0.23286E-07 -7.6329 0.61961E+00 -0.2079 10 Mg++ 0.20737E-10 -10.6833 0.12818E-10 -10.8922 0.61813E+00 -0.2089 11 Fe++ 0.11983E-12 -12.9214 0.74113E-13 -13.1301 0.61848E+00 -0.2087 12 K+ 0.71060E-04 -4.1484 0.62221E-04 -4.2061 0.87561E+00 -0.0577 13 Na+ 0.90090E-02 -2.0453 0.78807E-02 -2.1034 0.87475E+00 -0.0581 14 Mn++ 0.16425E-10 -10.7845 0.10163E-10 -10.9930 0.61875E+00 -0.2085 15 HPO4-- 0.50344E-06 -6.2980 0.31316E-06 -6.5042 0.62203E+00 -0.2062 16 HSiO3- 0.38103E-02 -2.4190 0.33333E-02 -2.4771 0.87483E+00 -0.0581 17 Ca(HSiO3)+ 0.20186E-08 -8.6950 0.17677E-08 -8.7526 0.87571E+00 -0.0576 18 Mg(HSiO3)+ 0.13828E-11 -11.8592 0.12110E-11 -11.9169 0.87571E+00 -0.0576 19 NaHSiO3,aq 0.42486E-03 -3.3718 0.42486E-03 -3.3718 0.10000E+01 0.0000 20 AlO+ 0.13610E-14 -14.8661 0.11919E-14 -14.9238 0.87571E+00 -0.0576 22 HAlO2,aq 0.18044E-08 -8.7437 0.18044E-08 -8.7437 0.10000E+01 0.0000 23 AlO2- 0.34743E-04 -4.4591 0.30365E-04 -4.5176 0.87399E+00 -0.0585 24 CH4,aq 0.46683E-18 -18.3308 0.46611E-18 -18.3315 0.99844E+00 -0.0007 29 CO,aq 0.79398E-19 -19.1002 0.79398E-19 -19.1002 0.10000E+01 0.0000 30 CO2,aq 0.16677E-08 -8.7779 0.16651E-08 -8.7786 0.99844E+00 -0.0007 31 CO3-2 0.63314E-05 -5.1985 0.39337E-05 -5.4052 0.62129E+00 -0.2067 32 CaCO3,aq 0.11486E-08 -8.9398 0.11486E-08 -8.9398 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.40210E-11 -11.3957 0.35212E-11 -11.4533 0.87571E+00 -0.0576 34 CaCl+ 0.51945E-11 -11.2845 0.45489E-11 -11.3421 0.87571E+00 -0.0576 35 CaCl2,aq 0.13046E-15 -15.8845 0.13046E-15 -15.8845 0.10000E+01 0.0000 36 CaOH+ 0.14407E-07 -7.8414 0.12616E-07 -7.8991 0.87571E+00 -0.0576 37 CaSO4,aq 0.11750E-09 -9.9300 0.11750E-09 -9.9300 0.10000E+01 0.0000 38 HCl,aq 0.29097E-14 -14.5362 0.29097E-14 -14.5362 0.10000E+01 0.0000 43 FeCl+ 0.16170E-16 -16.7913 0.14160E-16 -16.8489 0.87571E+00 -0.0576 46 FeO,aq 0.16647E-09 -9.7787 0.16647E-09 -9.7787 0.10000E+01 0.0000 47 FeOH+ 0.20943E-10 -10.6790 0.18340E-10 -10.7366 0.87571E+00 -0.0576 48 HFeO2- 0.15136E-07 -7.8200 0.13241E-07 -7.8781 0.87483E+00 -0.0581 49 FeO+ 0.11466E-14 -14.9406 0.10040E-14 -14.9982 0.87571E+00 -0.0576 51 FeO2- 0.13572E-07 -7.8673 0.11873E-07 -7.9254 0.87483E+00 -0.0581 52 HFeO2,aq 0.19864E-09 -9.7019 0.19864E-09 -9.7019 0.10000E+01 0.0000 53 H2,aq 0.19011E-08 -8.7210 0.18982E-08 -8.7217 0.99844E+00 -0.0007 54 KCl,aq 0.13613E-09 -9.8661 0.13613E-09 -9.8661 0.10000E+01 0.0000 55 KHSO4,aq 0.36771E-18 -18.4345 0.36771E-18 -18.4345 0.10000E+01 0.0000 56 KOH,aq 0.20200E-06 -6.6946 0.20200E-06 -6.6946 0.10000E+01 0.0000 57 KSO4- 0.17537E-07 -7.7560 0.15342E-07 -7.8141 0.87483E+00 -0.0581 58 MgCO3,aq 0.15847E-12 -12.8000 0.15847E-12 -12.8000 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.22617E-14 -14.6456 0.19806E-14 -14.7032 0.87571E+00 -0.0576 60 MgCl+ 0.25916E-14 -14.5864 0.22695E-14 -14.6441 0.87571E+00 -0.0576 61 MgOH+ 0.43884E-10 -10.3577 0.38429E-10 -10.4153 0.87571E+00 -0.0576 63 MnO,aq 0.60825E-09 -9.2159 0.60825E-09 -9.2159 0.10000E+01 0.0000 64 MnOH+ 0.26678E-09 -9.5738 0.23362E-09 -9.6315 0.87571E+00 -0.0576 65 MnO2-2 0.18777E-11 -11.7264 0.11666E-11 -11.9331 0.62129E+00 -0.2067 66 HMnO2- 0.38431E-10 -10.4153 0.33620E-10 -10.4734 0.87483E+00 -0.0581 69 MnCl+ 0.86266E-14 -14.0642 0.75544E-14 -14.1218 0.87571E+00 -0.0576 70 MnSO4,aq 0.46620E-13 -13.3314 0.46620E-13 -13.3314 0.10000E+01 0.0000 71 NaCl,aq 0.31526E-06 -6.5013 0.31526E-06 -6.5013 0.10000E+01 0.0000 72 NaOH,aq 0.25740E-04 -4.5894 0.25740E-04 -4.5894 0.10000E+01 0.0000 74 OH- 0.50256E-02 -2.2988 0.43923E-02 -2.3573 0.87399E+00 -0.0585 79 HPO3-2 0.29816E-17 -17.5256 0.18524E-17 -17.7323 0.62129E+00 -0.2067 82 H3PO4,aq 0.37898E-16 -16.4214 0.37898E-16 -16.4214 0.10000E+01 0.0000 83 H2PO4- 0.86821E-09 -9.0614 0.75991E-09 -9.1192 0.87526E+00 -0.0579 84 PO4-3 0.54256E-08 -8.2655 0.19424E-08 -8.7117 0.35800E+00 -0.4461 87 H2P2O7-2 0.72878E-19 -19.1374 0.45279E-19 -19.3441 0.62129E+00 -0.2067 88 HP2O7-3 0.19691E-15 -15.7057 0.68731E-16 -16.1628 0.34904E+00 -0.4571 89 P2O7-4 0.78873E-15 -15.1031 0.12483E-15 -15.9037 0.15826E+00 -0.8006 90 H2S,aq 0.52406E-15 -15.2806 0.52325E-15 -15.2813 0.99844E+00 -0.0007 97 SO3-2 0.62611E-14 -14.2034 0.39195E-14 -14.4068 0.62601E+00 -0.2034 98 HSO3- 0.36900E-16 -16.4330 0.32281E-16 -16.4910 0.87483E+00 -0.0581 99 HSO4- 0.22991E-11 -11.6384 0.20143E-11 -11.6959 0.87615E+00 -0.0574 Charge balance for all species = 0.6521E-13 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.1498881E-09 -.9432067E-02 -.9500442E+01 0.0000 2 H2O 0.1000000E+01 0.5550914E+02 0.9993284E+06 0.0000 3 Cl- 0.1379833E-03 0.1382987E-03 0.4899744E+01 5.9627 4 SO4-- 0.2554680E-04 0.2556570E-04 0.2454199E+01 14.9630 5 HCO3- 0.6766507E-05 0.1310074E-04 0.7988228E+00 4.6536 6 HS- 0.1471097E-11 -.1244611E-08 -.4113355E-04 -2.0095 7 Al+++ 0.4344879E-27 0.3474497E-04 0.9368288E+00 1.8235 8 H4SiO4 0.4695843E-03 0.4704709E-02 0.4518851E+03 -3.3283 9 Ca++ 0.3758149E-07 0.5528240E-07 0.2214090E-02 12.1290 10 Mg++ 0.2073687E-10 0.6616665E-10 0.1607541E-05 8.8697 11 Fe++ 0.1198304E-12 0.2909438E-07 0.1623720E-02 6.6318 12 K+ 0.7105992E-04 0.7127960E-04 0.2785265E+01 5.6749 13 Na+ 0.9009014E-02 0.9459931E-02 0.2173329E+03 7.7775 14 Mn++ 0.1642485E-10 0.9318231E-09 0.5115741E-04 8.7689 15 HPO4-- 0.5034429E-06 0.5097368E-06 0.4889049E-01 13.2576 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.2781535E+00 -.9409934E-02 -.2687435E+00 0.0000000E+00 2 H2O 0.5529767E+02 0.5537888E+02 -.8120919E-01 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.4910620E-03 0.2550571E-04 0.4655563E-03 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.4655576E-03 -.1241690E-08 -.4655563E-03 0.0000000E+00 7 Al+++ 0.5477720E-01 0.3466343E-04 0.5474253E-01 0.0000000E+00 8 H4SiO4 0.1749243E+00 0.4693669E-02 0.1702307E+00 0.0000000E+00 9 Ca++ 0.1933572E-01 0.5515268E-07 0.1933566E-01 0.0000000E+00 10 Mg++ 0.1333254E-01 0.6601138E-10 0.1333254E-01 0.0000000E+00 11 Fe++ 0.1197783E-01 0.2902611E-07 0.1197780E-01 0.0000000E+00 12 K+ 0.3566667E-02 0.7111233E-04 0.3495554E-02 0.0000000E+00 13 Na+ 0.2124691E-01 0.9437732E-02 0.1180918E-01 0.0000000E+00 14 Mn++ 0.2912711E-03 0.9296364E-09 0.2912701E-03 0.0000000E+00 15 HPO4-- 0.9940937E-04 0.5085406E-06 0.9890083E-04 0.0000000E+00 Chg. balance for solid moles: -.1157E-16 Mass of aqueous solution: 0.998338E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 16.7990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 0.1179E-01 -1.928 3.092 0.490 16.86 1.187 andradite 0.1234E-02 -2.909 0.6270 -0.203 3.419 0.1629 grossular 0.5892E-04 -4.230 0.2654E-01 -1.576 0.1448 0.7385E-02 apatite-OH 0.3297E-04 -4.482 0.1656E-01 -1.781 0.9032E-01 0.5262E-02 clinochlore 0.2667E-02 -2.574 1.482 0.171 8.083 0.5638 daphnite 0.1618E-02 -2.791 1.154 0.062 6.295 0.3497 chlorite-Mn 0.5825E-04 -4.235 0.4130E-01 -1.384 0.2252 0.1316E-01 hematite 0.5737E-03 -3.241 0.9162E-01 -1.038 0.4997 0.1737E-01 microcline 0.3479E-02 -2.459 0.9684 -0.014 5.281 0.3783 stilbite 0.1529E-01 -1.816 10.78 1.033 58.78 5.027 stilpnomelane-Fe 0.3307E-04 -4.481 0.3565E-01 -1.448 0.1944 0.1231E-01 nontronite-Na 0.5475E-04 -4.262 0.2328E-01 -1.633 0.1270 0.7233E-02 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.9544E+00 0.9544E+00 1.0000 -0.020 grossular 0.4558E-01 0.4558E-01 1.0000 -1.341 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.6141E+00 0.6141E+00 1.0000 -0.212 daphnite 0.3725E+00 0.3725E+00 1.0000 -0.429 chlorite-Mn 0.1342E-01 0.1342E-01 1.0000 -1.872 hematite 0.1000E+01 0.1000E+01 1.0000 0.000 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 nontronite-Na 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 18.335590 g Volume = 7.730937 cm3 Porosity: -0.1469% V(tot) - V(min): -.11337E-01 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 16.7990000 g log = 1.2253 Original solution: 1000.0103000 g Original solution / Rock added: 59.53 (Water/Rock Ratio), log = 1.7747 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0203 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.1000E+01 0.9860 0.1006E+01 0.1020E+01 CO2,gas 0.1734E-06 1.0071 0.1781E-06 0.1769E-06 CH4,gas 0.6641E-15 1.0125 0.6861E-15 0.6776E-15 H2,gas 0.2441E-05 1.0005 0.2492E-05 0.2491E-05 H2S,gas 0.1415E-13 0.9960 0.1438E-13 0.1444E-13 S2,gas 0.1226E-35 1.0000 0.1250E-35 0.1250E-35 CO,gas 0.1160E-15 1.0000 0.1183E-15 0.1183E-15 SO3,gas 0.1019E-39 1.0000 0.1040E-39 0.1040E-39 SO2,gas 0.9879E-23 1.0000 0.1008E-22 0.1008E-22 HCl,gas 0.5032E-17 1.0000 0.5134E-17 0.5134E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 16 albite -0.38 -0.38 0.00 0.000 -0.94784E-12 22 andradite 39.01 39.01 0.00 0.000 0.00000E+00 23 grossular 32.73 32.73 0.00 0.000 0.00000E+00 32 apatite-OH -18.15 -18.15 0.00 0.000 -0.60662E-11 46 clinochlore 39.07 39.07 0.00 0.000 -0.24265E-10 47 daphnite 28.97 28.97 0.00 0.000 0.00000E+00 48 chlorite-Mn 46.87 46.87 0.00 0.000 -0.12132E-10 90 hematite 12.57 12.57 0.00 0.000 -0.90992E-11 116 microcline -2.49 -2.49 0.00 0.000 0.15165E-11 163 stilbite -7.52 -7.52 0.00 0.000 -0.90992E-11 164 stilpnomelane-Fe 13.02 13.02 0.00 0.000 0.21232E-10 209 nontronite-Na 3.52 3.52 0.00 0.000 -0.90992E-11 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -15.11 -8.45 -2.816 0.14425E+05 -6.749 3 CH4,gas 4.54 -12.32 -16.86 -4.216 0.28792E+05 -15.164 4 H2,gas 8.00 0.70 -7.30 -4.173 0.12469E+05 -5.603 5 H2S,gas -6.23 -21.77 -15.54 -7.771 0.26536E+05 -13.842 6 S2,gas -7.34 -44.94 -37.60 -5.785 0.64204E+05 -35.903 7 CO,gas 3.21 -14.41 -17.63 -5.423 0.30096E+05 -15.927 8 SO3,gas 17.12 -24.56 -41.68 -10.421 0.71171E+05 -39.983 9 SO2,gas 0.83 -23.86 -24.70 -6.585 0.42167E+05 -22.997 10 HCl,gas 5.19 -13.80 -18.99 -9.494 0.32422E+05 -17.290 11 acmite 7.71 7.40 -0.31 -0.032 0.52197E+03 15 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 19 spessartine 24.46 19.97 -4.49 -0.224 0.76641E+04 20 analcite 3.32 2.94 -0.38 -0.042 0.64447E+03 21 andalusite 5.00 0.32 -4.68 -0.468 0.79958E+04 26 annite 20.12 17.41 -2.71 -0.151 0.46351E+04 27 phlogopite 27.06 24.12 -2.94 -0.163 0.50234E+04 29 anorthite 12.71 9.12 -3.59 -0.276 0.61314E+04 35 aragonite 0.97 -2.98 -3.95 -1.315 0.67375E+04 36 brucite 12.57 8.87 -3.70 -0.740 0.63157E+04 37 calcite 0.81 -2.98 -3.79 -1.264 0.64732E+04 38 carnegieite-low 9.02 6.27 -2.75 -0.393 0.46966E+04 39 carnegieite-high 10.09 6.27 -3.82 -0.546 0.65236E+04 40 carpholite-Mg 8.58 5.86 -2.72 -0.181 0.46477E+04 41 carpholite-Fe 6.71 3.62 -3.09 -0.206 0.52769E+04 42 celadonite 5.34 3.05 -2.29 -0.135 0.39045E+04 43 celadonite-Fe 3.88 0.82 -3.06 -0.180 0.52241E+04 44 chrysotile 23.89 19.95 -3.94 -0.328 0.67272E+04 50 chloritoid-Mg 13.20 9.19 -4.01 -0.267 0.68458E+04 51 chloritoid-Fe 9.17 6.95 -2.22 -0.148 0.37960E+04 52 chloritoid-Mn 11.40 9.09 -2.31 -0.154 0.39502E+04 54 coesite -2.38 -3.33 -0.95 -0.317 0.16259E+04 59 corundum 8.38 3.65 -4.74 -0.431 0.80868E+04 61 cristobalite -2.56 -3.33 -0.77 -0.256 0.13113E+04 63 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71234E+04 65 diaspore 2.87 1.82 -1.05 -0.175 0.17932E+04 67 diopside 16.18 14.34 -1.84 -0.184 0.31405E+04 68 hedenbergite 14.21 12.10 -2.10 -0.210 0.35927E+04 75 epidote 24.67 24.20 -0.47 -0.023 0.79698E+03 76 clinozoisite 22.81 19.74 -3.06 -0.139 0.52291E+04 77 epidote-Fe 29.84 28.66 -1.18 -0.061 0.20115E+04 78 fayalite 14.05 9.94 -4.11 -0.587 0.70185E+04 79 ferrosilite 11.15 6.61 -4.54 -0.454 0.77562E+04 83 gibbsite 4.08 1.82 -2.26 -0.322 0.38517E+04 84 glaucophane 22.97 19.18 -3.79 -0.102 0.64714E+04 85 glaucophane-Fe 17.28 12.47 -4.80 -0.130 0.82041E+04 87 greenalite 16.14 13.24 -2.90 -0.242 0.49530E+04 91 heulandite -5.83 -7.52 -1.69 -0.077 0.28938E+04 95 jadeite 4.22 2.94 -1.27 -0.127 0.21700E+04 96 julgoldite 70.43 66.94 -3.48 -0.091 0.59503E+04 97 kalsilite 7.58 4.17 -3.41 -0.488 0.58290E+04 98 kaolinite -1.33 -3.01 -1.68 -0.152 0.28631E+04 99 kyanite 4.88 0.32 -4.56 -0.456 0.77817E+04 101 laumontite 2.88 2.46 -0.42 -0.028 0.71817E+03 102 lawsonite 9.62 9.12 -0.50 -0.033 0.84809E+03 103 leucite 4.12 0.84 -3.28 -0.328 0.55955E+04 105 lizardite 23.24 19.95 -3.29 -0.274 0.56199E+04 107 magnetite 20.09 19.20 -0.89 -0.073 0.15187E+04 108 minnesotaite 10.39 6.58 -3.81 -0.224 0.64986E+04 110 magnesioferrite 26.21 21.44 -4.78 -0.390 0.81558E+04 113 margarite 17.32 12.77 -4.56 -0.182 0.77814E+04 120 muscovite 2.58 1.16 -1.42 -0.084 0.24279E+04 121 paragonite 4.24 3.26 -0.98 -0.057 0.16670E+04 122 nepheline 8.34 6.27 -2.07 -0.295 0.35289E+04 128 periclase-Fe 11.63 6.63 -4.99 -1.249 0.85285E+04 134 phlogopite-Na 29.65 26.23 -3.42 -0.190 0.58422E+04 136 prehnite 19.37 17.92 -1.45 -0.085 0.24789E+04 137 prehnite-Fe 22.50 22.38 -0.12 -0.007 0.20183E+03 138 pumpellyite-Fe 46.27 44.30 -1.97 -0.044 0.33706E+04 139 pumpellyite-Mg 48.99 46.53 -2.46 -0.055 0.42031E+04 145 pyroxmangite 7.40 5.44 -1.96 -0.392 0.33434E+04 146 pyrophyllite -6.18 -9.67 -3.49 -0.218 0.59597E+04 147 quartz -2.99 -3.33 -0.34 -0.113 0.57858E+03 152 rhodonite 7.45 5.44 -2.01 -0.401 0.34236E+04 153 sanidine -1.28 -2.49 -1.21 -0.093 0.20677E+04 156 sillimanite 5.26 0.32 -4.94 -0.494 0.84397E+04 165 stilpnomelane-Mg 27.44 24.21 -3.23 -0.097 0.55233E+04 171 talc 16.49 13.30 -3.20 -0.188 0.54556E+04 174 tephroite 18.09 14.21 -3.88 -0.554 0.66187E+04 177 topaz-H 4.62 0.32 -4.30 -0.391 0.73418E+04 178 tridymite -2.63 -3.33 -0.70 -0.234 0.11986E+04 187 wairakite 3.95 2.46 -1.49 -0.088 0.25401E+04 188 walstromite 11.51 8.80 -2.71 -0.542 0.46248E+04 189 wollastonite 10.46 8.80 -1.66 -0.332 0.28352E+04 190 pseudo-wollastonite 11.00 8.80 -2.20 -0.440 0.37550E+04 191 zoisite 22.85 19.74 -3.11 -0.141 0.53032E+04 192 akaganeite 7.75 6.28 -1.47 -0.318 0.25125E+04 193 beidellite-Ca -1.65 -5.96 -4.32 -0.267 0.73749E+04 195 beidellite-K -1.52 -6.09 -4.57 -0.280 0.78085E+04 196 beidellite-Mg -1.79 -6.50 -4.71 -0.292 0.80470E+04 197 beidellite-Na -1.34 -5.40 -4.06 -0.248 0.69277E+04 199 chalcedony -2.80 -3.33 -0.53 -0.175 0.89788E+03 201 montmorillonite-Ca -2.29 -5.34 -3.05 -0.189 0.52059E+04 202 montmorillonite-K -2.24 -5.47 -3.23 -0.198 0.55177E+04 203 montmorillonite-Mg -2.48 -5.88 -3.40 -0.210 0.58012E+04 204 montmorillonite-Na -2.04 -4.77 -2.74 -0.168 0.46726E+04 205 nontronite-Ca 3.21 2.95 -0.26 -0.017 0.44418E+03 206 nontronite-H 2.53 0.95 -1.58 -0.106 0.26971E+04 207 nontronite-K 3.34 2.83 -0.51 -0.033 0.87912E+03 208 nontronite-Mg 3.07 2.42 -0.66 -0.043 0.11235E+04 224 tobermorite 9.82 6.78 -3.05 -0.832 0.52042E+04 233 boehmite 4.41 1.82 -2.58 -0.430 0.44101E+04 235 ferrous-oxide 9.81 6.63 -3.18 -0.795 0.54294E+04 240 silica-amorphous -2.09 -3.33 -1.24 -0.412 0.21121E+04 242 an20ab80 2.02 1.52 -0.50 -0.039 0.85544E+03 243 an25ab75 2.65 1.99 -0.65 -0.050 0.11163E+04 244 an30ab70 3.28 2.47 -0.81 -0.062 0.13867E+04 245 tr.625ac.25prg.125 45.16 40.56 -4.60 -0.124 0.78589E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 0.4000000 g Current total amount of reactant added: 16.7990000 g New total amount of reactant added: 17.1990000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.6626E-13 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 7 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 17.1990000 Water: Moles liquid = 0.5538E+02 kg liquid = 0.9976E+00 Moles total = 0.5529E+02 kg total = 0.9961E+00 Activity = 1.0000 Stoichiometric ionic strength = .5049905E-02 Osmotic coef. = 0.9622 True ionic strength = .9112608E-02 Chg. balance for total moles = 0.6626E-13 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.14989E-09 -9.8242 0.13154E-09 -9.8809 0.87760E+00 -0.0567 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13799E-03 -3.8602 0.12072E-03 -3.9182 0.87483E+00 -0.0581 4 SO4-- 0.25548E-04 -4.5926 0.15890E-04 -4.7989 0.62199E+00 -0.2062 5 HCO3- 0.67668E-05 -5.1696 0.59243E-05 -5.2274 0.87549E+00 -0.0577 6 HS- 0.14712E-11 -11.8323 0.12871E-11 -11.8904 0.87489E+00 -0.0580 7 Al+++ 0.43449E-27 -27.3620 0.15159E-27 -27.8193 0.34890E+00 -0.4573 8 H4SiO4 0.46958E-03 -3.3283 0.46958E-03 -3.3283 0.10000E+01 0.0000 9 Ca++ 0.37582E-07 -7.4250 0.23286E-07 -7.6329 0.61961E+00 -0.2079 10 Mg++ 0.20737E-10 -10.6833 0.12818E-10 -10.8922 0.61813E+00 -0.2089 11 Fe++ 0.11983E-12 -12.9214 0.74113E-13 -13.1301 0.61848E+00 -0.2087 12 K+ 0.71060E-04 -4.1484 0.62221E-04 -4.2061 0.87561E+00 -0.0577 13 Na+ 0.90090E-02 -2.0453 0.78807E-02 -2.1034 0.87475E+00 -0.0581 14 Mn++ 0.16425E-10 -10.7845 0.10163E-10 -10.9930 0.61875E+00 -0.2085 15 HPO4-- 0.50344E-06 -6.2981 0.31316E-06 -6.5042 0.62203E+00 -0.2062 16 HSiO3- 0.38103E-02 -2.4190 0.33333E-02 -2.4771 0.87483E+00 -0.0581 17 Ca(HSiO3)+ 0.20186E-08 -8.6950 0.17677E-08 -8.7526 0.87571E+00 -0.0576 18 Mg(HSiO3)+ 0.13828E-11 -11.8592 0.12110E-11 -11.9169 0.87571E+00 -0.0576 19 NaHSiO3,aq 0.42486E-03 -3.3718 0.42486E-03 -3.3718 0.10000E+01 0.0000 20 AlO+ 0.13610E-14 -14.8661 0.11919E-14 -14.9238 0.87571E+00 -0.0576 22 HAlO2,aq 0.18044E-08 -8.7437 0.18044E-08 -8.7437 0.10000E+01 0.0000 23 AlO2- 0.34743E-04 -4.4591 0.30365E-04 -4.5176 0.87399E+00 -0.0585 24 CH4,aq 0.46685E-18 -18.3308 0.46613E-18 -18.3315 0.99844E+00 -0.0007 29 CO,aq 0.79401E-19 -19.1002 0.79401E-19 -19.1002 0.10000E+01 0.0000 30 CO2,aq 0.16678E-08 -8.7779 0.16652E-08 -8.7785 0.99844E+00 -0.0007 31 CO3-2 0.63317E-05 -5.1985 0.39338E-05 -5.4052 0.62129E+00 -0.2067 32 CaCO3,aq 0.11486E-08 -8.9398 0.11486E-08 -8.9398 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.40212E-11 -11.3956 0.35214E-11 -11.4533 0.87571E+00 -0.0576 34 CaCl+ 0.51947E-11 -11.2844 0.45491E-11 -11.3421 0.87571E+00 -0.0576 35 CaCl2,aq 0.13047E-15 -15.8845 0.13047E-15 -15.8845 0.10000E+01 0.0000 36 CaOH+ 0.14407E-07 -7.8414 0.12616E-07 -7.8991 0.87571E+00 -0.0576 37 CaSO4,aq 0.11750E-09 -9.9300 0.11750E-09 -9.9300 0.10000E+01 0.0000 38 HCl,aq 0.29098E-14 -14.5361 0.29098E-14 -14.5361 0.10000E+01 0.0000 43 FeCl+ 0.16171E-16 -16.7913 0.14161E-16 -16.8489 0.87571E+00 -0.0576 46 FeO,aq 0.16647E-09 -9.7787 0.16647E-09 -9.7787 0.10000E+01 0.0000 47 FeOH+ 0.20943E-10 -10.6790 0.18340E-10 -10.7366 0.87571E+00 -0.0576 48 HFeO2- 0.15136E-07 -7.8200 0.13241E-07 -7.8781 0.87483E+00 -0.0581 49 FeO+ 0.11466E-14 -14.9406 0.10040E-14 -14.9982 0.87571E+00 -0.0576 51 FeO2- 0.13572E-07 -7.8673 0.11873E-07 -7.9254 0.87483E+00 -0.0581 52 HFeO2,aq 0.19864E-09 -9.7019 0.19864E-09 -9.7019 0.10000E+01 0.0000 53 H2,aq 0.19011E-08 -8.7210 0.18982E-08 -8.7217 0.99844E+00 -0.0007 54 KCl,aq 0.13613E-09 -9.8660 0.13613E-09 -9.8660 0.10000E+01 0.0000 55 KHSO4,aq 0.36772E-18 -18.4345 0.36772E-18 -18.4345 0.10000E+01 0.0000 56 KOH,aq 0.20200E-06 -6.6946 0.20200E-06 -6.6946 0.10000E+01 0.0000 57 KSO4- 0.17538E-07 -7.7560 0.15342E-07 -7.8141 0.87483E+00 -0.0581 58 MgCO3,aq 0.15848E-12 -12.8000 0.15848E-12 -12.8000 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.22618E-14 -14.6455 0.19807E-14 -14.7032 0.87571E+00 -0.0576 60 MgCl+ 0.25917E-14 -14.5864 0.22696E-14 -14.6441 0.87571E+00 -0.0576 61 MgOH+ 0.43884E-10 -10.3577 0.38429E-10 -10.4153 0.87571E+00 -0.0576 63 MnO,aq 0.60825E-09 -9.2159 0.60825E-09 -9.2159 0.10000E+01 0.0000 64 MnOH+ 0.26678E-09 -9.5738 0.23362E-09 -9.6315 0.87571E+00 -0.0576 65 MnO2-2 0.18777E-11 -11.7264 0.11666E-11 -11.9331 0.62129E+00 -0.2067 66 HMnO2- 0.38431E-10 -10.4153 0.33620E-10 -10.4734 0.87483E+00 -0.0581 69 MnCl+ 0.86270E-14 -14.0641 0.75547E-14 -14.1218 0.87571E+00 -0.0576 70 MnSO4,aq 0.46622E-13 -13.3314 0.46622E-13 -13.3314 0.10000E+01 0.0000 71 NaCl,aq 0.31527E-06 -6.5013 0.31527E-06 -6.5013 0.10000E+01 0.0000 72 NaOH,aq 0.25740E-04 -4.5894 0.25740E-04 -4.5894 0.10000E+01 0.0000 74 OH- 0.50256E-02 -2.2988 0.43923E-02 -2.3573 0.87399E+00 -0.0585 79 HPO3-2 0.29816E-17 -17.5256 0.18524E-17 -17.7323 0.62129E+00 -0.2067 82 H3PO4,aq 0.37898E-16 -16.4214 0.37898E-16 -16.4214 0.10000E+01 0.0000 83 H2PO4- 0.86821E-09 -9.0614 0.75991E-09 -9.1192 0.87526E+00 -0.0579 84 PO4-3 0.54256E-08 -8.2655 0.19424E-08 -8.7117 0.35800E+00 -0.4461 87 H2P2O7-2 0.72878E-19 -19.1374 0.45279E-19 -19.3441 0.62129E+00 -0.2067 88 HP2O7-3 0.19691E-15 -15.7057 0.68731E-16 -16.1628 0.34904E+00 -0.4571 89 P2O7-4 0.78873E-15 -15.1031 0.12482E-15 -15.9037 0.15826E+00 -0.8006 90 H2S,aq 0.52408E-15 -15.2806 0.52327E-15 -15.2813 0.99844E+00 -0.0007 97 SO3-2 0.62613E-14 -14.2033 0.39196E-14 -14.4068 0.62601E+00 -0.2034 98 HSO3- 0.36902E-16 -16.4330 0.32283E-16 -16.4910 0.87483E+00 -0.0581 99 HSO4- 0.22992E-11 -11.6384 0.20144E-11 -11.6959 0.87615E+00 -0.0574 Charge balance for all species = 0.6509E-13 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.1498882E-09 -.9432063E-02 -.9500438E+01 0.0000 2 H2O 0.1000000E+01 0.5550914E+02 0.9993284E+06 0.0000 3 Cl- 0.1379889E-03 0.1383043E-03 0.4899941E+01 5.9627 4 SO4-- 0.2554783E-04 0.2556673E-04 0.2454298E+01 14.9630 5 HCO3- 0.6766780E-05 0.1310127E-04 0.7988548E+00 4.6536 6 HS- 0.1471157E-11 -.1244610E-08 -.4113353E-04 -2.0094 7 Al+++ 0.4344887E-27 0.3474495E-04 0.9368284E+00 1.8235 8 H4SiO4 0.4695843E-03 0.4704707E-02 0.4518849E+03 -3.3283 9 Ca++ 0.3758153E-07 0.5528250E-07 0.2214094E-02 12.1290 10 Mg++ 0.2073689E-10 0.6616669E-10 0.1607542E-05 8.8697 11 Fe++ 0.1198306E-12 0.2909437E-07 0.1623719E-02 6.6318 12 K+ 0.7105996E-04 0.7127964E-04 0.2785266E+01 5.6749 13 Na+ 0.9009019E-02 0.9459935E-02 0.2173330E+03 7.7775 14 Mn++ 0.1642487E-10 0.9318233E-09 0.5115742E-04 8.7689 15 HPO4-- 0.5034425E-06 0.5097364E-06 0.4889046E-01 13.2576 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.2847769E+00 -.9409552E-02 -.2753673E+00 0.0000000E+00 2 H2O 0.5529265E+02 0.5537665E+02 -.8399907E-01 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.5021474E-03 0.2550571E-04 0.4766417E-03 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.4766429E-03 -.1241639E-08 -.4766417E-03 0.0000000E+00 7 Al+++ 0.5608149E-01 0.3466203E-04 0.5604683E-01 0.0000000E+00 8 H4SiO4 0.1790895E+00 0.4693479E-02 0.1743960E+00 0.0000000E+00 9 Ca++ 0.1979577E-01 0.5515056E-07 0.1979572E-01 0.0000000E+00 10 Mg++ 0.1365000E-01 0.6600877E-10 0.1365000E-01 0.0000000E+00 11 Fe++ 0.1226303E-01 0.2902493E-07 0.1226301E-01 0.0000000E+00 12 K+ 0.3651592E-02 0.7110951E-04 0.3580483E-02 0.0000000E+00 13 Na+ 0.2174901E-01 0.9437357E-02 0.1231165E-01 0.0000000E+00 14 Mn++ 0.2982065E-03 0.9295993E-09 0.2982056E-03 0.0000000E+00 15 HPO4-- 0.1017764E-03 0.5085198E-06 0.1012679E-03 0.0000000E+00 Chg. balance for solid moles: -.1973E-16 Mass of aqueous solution: 0.998298E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 17.1990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 0.1228E-01 -1.911 3.220 0.508 17.15 1.236 andradite 0.1299E-02 -2.886 0.6601 -0.180 3.516 0.1715 grossular 0.6203E-04 -4.207 0.2794E-01 -1.554 0.1489 0.7775E-02 apatite-OH 0.3376E-04 -4.472 0.1696E-01 -1.771 0.9033E-01 0.5388E-02 clinochlore 0.2730E-02 -2.564 1.517 0.181 8.083 0.5772 daphnite 0.1656E-02 -2.781 1.182 0.072 6.295 0.3581 chlorite-Mn 0.5964E-04 -4.224 0.4228E-01 -1.374 0.2252 0.1347E-01 hematite 0.5068E-03 -3.295 0.8094E-01 -1.092 0.4312 0.1534E-01 microcline 0.3564E-02 -2.448 0.9919 -0.004 5.284 0.3875 stilbite 0.1554E-01 -1.808 10.95 1.040 58.35 5.109 stilpnomelane-Fe 0.3386E-04 -4.470 0.3650E-01 -1.438 0.1944 0.1261E-01 nontronite-Na 0.1009E-03 -3.996 0.4289E-01 -1.368 0.2285 0.1332E-01 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.9544E+00 0.9544E+00 1.0000 -0.020 grossular 0.4558E-01 0.4558E-01 1.0000 -1.341 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.6141E+00 0.6141E+00 1.0000 -0.212 daphnite 0.3725E+00 0.3725E+00 1.0000 -0.429 chlorite-Mn 0.1342E-01 0.1342E-01 1.0000 -1.872 hematite 0.1000E+01 0.1000E+01 1.0000 0.000 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 nontronite-Na 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 18.772450 g Volume = 7.907334 cm3 Porosity: -0.3520% V(tot) - V(min): -.27734E-01 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 17.1990000 g log = 1.2355 Original solution: 1000.0103000 g Original solution / Rock added: 58.14 (Water/Rock Ratio), log = 1.7645 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0203 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.1000E+01 0.9860 0.1006E+01 0.1020E+01 CO2,gas 0.1734E-06 1.0071 0.1782E-06 0.1769E-06 CH4,gas 0.6641E-15 1.0125 0.6861E-15 0.6776E-15 H2,gas 0.2441E-05 1.0005 0.2492E-05 0.2491E-05 H2S,gas 0.1415E-13 0.9960 0.1438E-13 0.1444E-13 S2,gas 0.1226E-35 1.0000 0.1251E-35 0.1251E-35 CO,gas 0.1160E-15 1.0000 0.1183E-15 0.1183E-15 SO3,gas 0.1019E-39 1.0000 0.1040E-39 0.1040E-39 SO2,gas 0.9879E-23 1.0000 0.1008E-22 0.1008E-22 HCl,gas 0.5032E-17 1.0000 0.5134E-17 0.5134E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 16 albite -0.38 -0.38 0.00 0.000 -0.94784E-12 22 andradite 39.01 39.01 0.00 0.000 0.00000E+00 23 grossular 32.73 32.73 0.00 0.000 0.24265E-10 32 apatite-OH -18.15 -18.15 0.00 0.000 0.60662E-11 46 clinochlore 39.07 39.07 0.00 0.000 0.12132E-10 47 daphnite 28.97 28.97 0.00 0.000 0.36397E-10 48 chlorite-Mn 46.87 46.87 0.00 0.000 0.36397E-10 90 hematite 12.57 12.57 0.00 0.000 0.30331E-11 116 microcline -2.49 -2.49 0.00 0.000 -0.10616E-10 163 stilbite -7.52 -7.52 0.00 0.000 0.15165E-10 164 stilpnomelane-Fe 13.02 13.02 0.00 0.000 0.21232E-10 209 nontronite-Na 3.52 3.52 0.00 0.000 -0.28056E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -15.11 -8.45 -2.816 0.14425E+05 -6.749 3 CH4,gas 4.54 -12.32 -16.86 -4.216 0.28792E+05 -15.164 4 H2,gas 8.00 0.70 -7.30 -4.173 0.12469E+05 -5.603 5 H2S,gas -6.23 -21.77 -15.54 -7.771 0.26536E+05 -13.842 6 S2,gas -7.34 -44.94 -37.60 -5.785 0.64204E+05 -35.903 7 CO,gas 3.21 -14.41 -17.63 -5.423 0.30096E+05 -15.927 8 SO3,gas 17.12 -24.56 -41.68 -10.421 0.71171E+05 -39.983 9 SO2,gas 0.83 -23.86 -24.70 -6.585 0.42167E+05 -22.997 10 HCl,gas 5.19 -13.80 -18.99 -9.494 0.32422E+05 -17.290 11 acmite 7.71 7.40 -0.31 -0.032 0.52197E+03 15 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 19 spessartine 24.46 19.97 -4.49 -0.224 0.76641E+04 20 analcite 3.32 2.94 -0.38 -0.042 0.64447E+03 21 andalusite 5.00 0.32 -4.68 -0.468 0.79958E+04 26 annite 20.12 17.41 -2.71 -0.151 0.46351E+04 27 phlogopite 27.06 24.12 -2.94 -0.163 0.50234E+04 29 anorthite 12.71 9.12 -3.59 -0.276 0.61314E+04 35 aragonite 0.97 -2.98 -3.95 -1.315 0.67374E+04 36 brucite 12.57 8.87 -3.70 -0.740 0.63157E+04 37 calcite 0.81 -2.98 -3.79 -1.264 0.64732E+04 38 carnegieite-low 9.02 6.27 -2.75 -0.393 0.46966E+04 39 carnegieite-high 10.09 6.27 -3.82 -0.546 0.65236E+04 40 carpholite-Mg 8.58 5.86 -2.72 -0.181 0.46477E+04 41 carpholite-Fe 6.71 3.62 -3.09 -0.206 0.52769E+04 42 celadonite 5.34 3.05 -2.29 -0.135 0.39045E+04 43 celadonite-Fe 3.88 0.82 -3.06 -0.180 0.52241E+04 44 chrysotile 23.89 19.95 -3.94 -0.328 0.67272E+04 50 chloritoid-Mg 13.20 9.19 -4.01 -0.267 0.68458E+04 51 chloritoid-Fe 9.17 6.95 -2.22 -0.148 0.37960E+04 52 chloritoid-Mn 11.40 9.09 -2.31 -0.154 0.39502E+04 54 coesite -2.38 -3.33 -0.95 -0.317 0.16259E+04 59 corundum 8.38 3.65 -4.74 -0.431 0.80868E+04 61 cristobalite -2.56 -3.33 -0.77 -0.256 0.13113E+04 63 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71234E+04 65 diaspore 2.87 1.82 -1.05 -0.175 0.17932E+04 67 diopside 16.18 14.34 -1.84 -0.184 0.31405E+04 68 hedenbergite 14.21 12.10 -2.10 -0.210 0.35927E+04 75 epidote 24.67 24.20 -0.47 -0.023 0.79698E+03 76 clinozoisite 22.81 19.74 -3.06 -0.139 0.52291E+04 77 epidote-Fe 29.84 28.66 -1.18 -0.061 0.20115E+04 78 fayalite 14.05 9.94 -4.11 -0.587 0.70185E+04 79 ferrosilite 11.15 6.61 -4.54 -0.454 0.77562E+04 83 gibbsite 4.08 1.82 -2.26 -0.322 0.38517E+04 84 glaucophane 22.97 19.18 -3.79 -0.102 0.64714E+04 85 glaucophane-Fe 17.28 12.47 -4.80 -0.130 0.82041E+04 87 greenalite 16.14 13.24 -2.90 -0.242 0.49530E+04 91 heulandite -5.83 -7.52 -1.69 -0.077 0.28938E+04 95 jadeite 4.22 2.94 -1.27 -0.127 0.21700E+04 96 julgoldite 70.43 66.94 -3.48 -0.091 0.59503E+04 97 kalsilite 7.58 4.17 -3.41 -0.488 0.58290E+04 98 kaolinite -1.33 -3.01 -1.68 -0.152 0.28631E+04 99 kyanite 4.88 0.32 -4.56 -0.456 0.77817E+04 101 laumontite 2.88 2.46 -0.42 -0.028 0.71817E+03 102 lawsonite 9.62 9.12 -0.50 -0.033 0.84809E+03 103 leucite 4.12 0.84 -3.28 -0.328 0.55955E+04 105 lizardite 23.24 19.95 -3.29 -0.274 0.56199E+04 107 magnetite 20.09 19.20 -0.89 -0.073 0.15187E+04 108 minnesotaite 10.39 6.58 -3.81 -0.224 0.64986E+04 110 magnesioferrite 26.21 21.44 -4.78 -0.390 0.81558E+04 113 margarite 17.32 12.77 -4.56 -0.182 0.77814E+04 120 muscovite 2.58 1.16 -1.42 -0.084 0.24279E+04 121 paragonite 4.24 3.26 -0.98 -0.057 0.16670E+04 122 nepheline 8.34 6.27 -2.07 -0.295 0.35289E+04 128 periclase-Fe 11.63 6.63 -4.99 -1.249 0.85285E+04 134 phlogopite-Na 29.65 26.23 -3.42 -0.190 0.58422E+04 136 prehnite 19.37 17.92 -1.45 -0.085 0.24789E+04 137 prehnite-Fe 22.50 22.38 -0.12 -0.007 0.20183E+03 138 pumpellyite-Fe 46.27 44.30 -1.97 -0.044 0.33706E+04 139 pumpellyite-Mg 48.99 46.53 -2.46 -0.055 0.42031E+04 145 pyroxmangite 7.40 5.44 -1.96 -0.392 0.33434E+04 146 pyrophyllite -6.18 -9.67 -3.49 -0.218 0.59597E+04 147 quartz -2.99 -3.33 -0.34 -0.113 0.57858E+03 152 rhodonite 7.45 5.44 -2.01 -0.401 0.34236E+04 153 sanidine -1.28 -2.49 -1.21 -0.093 0.20677E+04 156 sillimanite 5.26 0.32 -4.94 -0.494 0.84397E+04 165 stilpnomelane-Mg 27.44 24.21 -3.23 -0.097 0.55233E+04 171 talc 16.49 13.30 -3.20 -0.188 0.54556E+04 174 tephroite 18.09 14.21 -3.88 -0.554 0.66187E+04 177 topaz-H 4.62 0.32 -4.30 -0.391 0.73418E+04 178 tridymite -2.63 -3.33 -0.70 -0.234 0.11986E+04 187 wairakite 3.95 2.46 -1.49 -0.088 0.25401E+04 188 walstromite 11.51 8.80 -2.71 -0.542 0.46248E+04 189 wollastonite 10.46 8.80 -1.66 -0.332 0.28352E+04 190 pseudo-wollastonite 11.00 8.80 -2.20 -0.440 0.37550E+04 191 zoisite 22.85 19.74 -3.11 -0.141 0.53032E+04 192 akaganeite 7.75 6.28 -1.47 -0.318 0.25125E+04 193 beidellite-Ca -1.65 -5.96 -4.32 -0.267 0.73749E+04 195 beidellite-K -1.52 -6.09 -4.57 -0.280 0.78085E+04 196 beidellite-Mg -1.79 -6.50 -4.71 -0.292 0.80470E+04 197 beidellite-Na -1.34 -5.40 -4.06 -0.248 0.69277E+04 199 chalcedony -2.80 -3.33 -0.53 -0.175 0.89788E+03 201 montmorillonite-Ca -2.29 -5.34 -3.05 -0.189 0.52059E+04 202 montmorillonite-K -2.24 -5.47 -3.23 -0.198 0.55177E+04 203 montmorillonite-Mg -2.48 -5.88 -3.40 -0.210 0.58012E+04 204 montmorillonite-Na -2.04 -4.77 -2.74 -0.168 0.46726E+04 205 nontronite-Ca 3.21 2.95 -0.26 -0.017 0.44418E+03 206 nontronite-H 2.53 0.95 -1.58 -0.106 0.26971E+04 207 nontronite-K 3.34 2.83 -0.51 -0.033 0.87912E+03 208 nontronite-Mg 3.07 2.42 -0.66 -0.043 0.11235E+04 224 tobermorite 9.82 6.78 -3.05 -0.832 0.52042E+04 233 boehmite 4.41 1.82 -2.58 -0.430 0.44101E+04 235 ferrous-oxide 9.81 6.63 -3.18 -0.795 0.54294E+04 240 silica-amorphous -2.09 -3.33 -1.24 -0.412 0.21121E+04 242 an20ab80 2.02 1.52 -0.50 -0.039 0.85544E+03 243 an25ab75 2.65 1.99 -0.65 -0.050 0.11163E+04 244 an30ab70 3.28 2.47 -0.81 -0.062 0.13867E+04 245 tr.625ac.25prg.125 45.16 40.56 -4.60 -0.124 0.78589E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 0.4000000 g Current total amount of reactant added: 17.1990000 g New total amount of reactant added: 17.5990000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.6623E-13 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 7 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 17.5990000 Water: Moles liquid = 0.5537E+02 kg liquid = 0.9976E+00 Moles total = 0.5529E+02 kg total = 0.9960E+00 Activity = 1.0000 Stoichiometric ionic strength = .5049912E-02 Osmotic coef. = 0.9622 True ionic strength = .9112614E-02 Chg. balance for total moles = 0.6623E-13 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.14989E-09 -9.8242 0.13154E-09 -9.8809 0.87760E+00 -0.0567 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13799E-03 -3.8601 0.12072E-03 -3.9182 0.87483E+00 -0.0581 4 SO4-- 0.25549E-04 -4.5926 0.15891E-04 -4.7988 0.62199E+00 -0.2062 5 HCO3- 0.67671E-05 -5.1696 0.59245E-05 -5.2273 0.87549E+00 -0.0577 6 HS- 0.14712E-11 -11.8323 0.12872E-11 -11.8904 0.87489E+00 -0.0580 7 Al+++ 0.43449E-27 -27.3620 0.15159E-27 -27.8193 0.34890E+00 -0.4573 8 H4SiO4 0.46958E-03 -3.3283 0.46958E-03 -3.3283 0.10000E+01 0.0000 9 Ca++ 0.37582E-07 -7.4250 0.23286E-07 -7.6329 0.61961E+00 -0.2079 10 Mg++ 0.20737E-10 -10.6833 0.12818E-10 -10.8922 0.61813E+00 -0.2089 11 Fe++ 0.11983E-12 -12.9214 0.74113E-13 -13.1301 0.61848E+00 -0.2087 12 K+ 0.71060E-04 -4.1484 0.62221E-04 -4.2061 0.87561E+00 -0.0577 13 Na+ 0.90090E-02 -2.0453 0.78807E-02 -2.1034 0.87475E+00 -0.0581 14 Mn++ 0.16425E-10 -10.7845 0.10163E-10 -10.9930 0.61875E+00 -0.2085 15 HPO4-- 0.50344E-06 -6.2981 0.31316E-06 -6.5042 0.62203E+00 -0.2062 16 HSiO3- 0.38103E-02 -2.4190 0.33333E-02 -2.4771 0.87483E+00 -0.0581 17 Ca(HSiO3)+ 0.20186E-08 -8.6950 0.17677E-08 -8.7526 0.87571E+00 -0.0576 18 Mg(HSiO3)+ 0.13828E-11 -11.8592 0.12110E-11 -11.9169 0.87571E+00 -0.0576 19 NaHSiO3,aq 0.42486E-03 -3.3718 0.42486E-03 -3.3718 0.10000E+01 0.0000 20 AlO+ 0.13610E-14 -14.8661 0.11919E-14 -14.9238 0.87571E+00 -0.0576 22 HAlO2,aq 0.18044E-08 -8.7437 0.18044E-08 -8.7437 0.10000E+01 0.0000 23 AlO2- 0.34743E-04 -4.4591 0.30365E-04 -4.5176 0.87399E+00 -0.0585 24 CH4,aq 0.46687E-18 -18.3308 0.46614E-18 -18.3315 0.99844E+00 -0.0007 29 CO,aq 0.79404E-19 -19.1002 0.79404E-19 -19.1002 0.10000E+01 0.0000 30 CO2,aq 0.16678E-08 -8.7779 0.16652E-08 -8.7785 0.99844E+00 -0.0007 31 CO3-2 0.63319E-05 -5.1985 0.39340E-05 -5.4052 0.62129E+00 -0.2067 32 CaCO3,aq 0.11486E-08 -8.9398 0.11486E-08 -8.9398 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.40214E-11 -11.3956 0.35215E-11 -11.4533 0.87571E+00 -0.0576 34 CaCl+ 0.51950E-11 -11.2844 0.45493E-11 -11.3421 0.87571E+00 -0.0576 35 CaCl2,aq 0.13048E-15 -15.8845 0.13048E-15 -15.8845 0.10000E+01 0.0000 36 CaOH+ 0.14407E-07 -7.8414 0.12616E-07 -7.8991 0.87571E+00 -0.0576 37 CaSO4,aq 0.11750E-09 -9.9299 0.11750E-09 -9.9299 0.10000E+01 0.0000 38 HCl,aq 0.29099E-14 -14.5361 0.29099E-14 -14.5361 0.10000E+01 0.0000 43 FeCl+ 0.16172E-16 -16.7912 0.14162E-16 -16.8489 0.87571E+00 -0.0576 46 FeO,aq 0.16647E-09 -9.7787 0.16647E-09 -9.7787 0.10000E+01 0.0000 47 FeOH+ 0.20943E-10 -10.6790 0.18340E-10 -10.7366 0.87571E+00 -0.0576 48 HFeO2- 0.15136E-07 -7.8200 0.13241E-07 -7.8781 0.87483E+00 -0.0581 49 FeO+ 0.11466E-14 -14.9406 0.10040E-14 -14.9982 0.87571E+00 -0.0576 51 FeO2- 0.13572E-07 -7.8673 0.11873E-07 -7.9254 0.87483E+00 -0.0581 52 HFeO2,aq 0.19864E-09 -9.7019 0.19864E-09 -9.7019 0.10000E+01 0.0000 53 H2,aq 0.19011E-08 -8.7210 0.18982E-08 -8.7217 0.99844E+00 -0.0007 54 KCl,aq 0.13614E-09 -9.8660 0.13614E-09 -9.8660 0.10000E+01 0.0000 55 KHSO4,aq 0.36774E-18 -18.4345 0.36774E-18 -18.4345 0.10000E+01 0.0000 56 KOH,aq 0.20200E-06 -6.6946 0.20200E-06 -6.6946 0.10000E+01 0.0000 57 KSO4- 0.17538E-07 -7.7560 0.15343E-07 -7.8141 0.87483E+00 -0.0581 58 MgCO3,aq 0.15849E-12 -12.8000 0.15849E-12 -12.8000 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.22619E-14 -14.6455 0.19808E-14 -14.7032 0.87571E+00 -0.0576 60 MgCl+ 0.25918E-14 -14.5864 0.22697E-14 -14.6440 0.87571E+00 -0.0576 61 MgOH+ 0.43884E-10 -10.3577 0.38429E-10 -10.4153 0.87571E+00 -0.0576 63 MnO,aq 0.60825E-09 -9.2159 0.60825E-09 -9.2159 0.10000E+01 0.0000 64 MnOH+ 0.26678E-09 -9.5738 0.23362E-09 -9.6315 0.87571E+00 -0.0576 65 MnO2-2 0.18777E-11 -11.7264 0.11666E-11 -11.9331 0.62129E+00 -0.2067 66 HMnO2- 0.38431E-10 -10.4153 0.33620E-10 -10.4734 0.87483E+00 -0.0581 69 MnCl+ 0.86273E-14 -14.0641 0.75550E-14 -14.1218 0.87571E+00 -0.0576 70 MnSO4,aq 0.46624E-13 -13.3314 0.46624E-13 -13.3314 0.10000E+01 0.0000 71 NaCl,aq 0.31528E-06 -6.5013 0.31528E-06 -6.5013 0.10000E+01 0.0000 72 NaOH,aq 0.25740E-04 -4.5894 0.25740E-04 -4.5894 0.10000E+01 0.0000 74 OH- 0.50256E-02 -2.2988 0.43923E-02 -2.3573 0.87399E+00 -0.0585 79 HPO3-2 0.29816E-17 -17.5256 0.18524E-17 -17.7323 0.62129E+00 -0.2067 82 H3PO4,aq 0.37898E-16 -16.4214 0.37898E-16 -16.4214 0.10000E+01 0.0000 83 H2PO4- 0.86821E-09 -9.0614 0.75991E-09 -9.1192 0.87526E+00 -0.0579 84 PO4-3 0.54256E-08 -8.2656 0.19424E-08 -8.7117 0.35800E+00 -0.4461 87 H2P2O7-2 0.72878E-19 -19.1374 0.45278E-19 -19.3441 0.62129E+00 -0.2067 88 HP2O7-3 0.19691E-15 -15.7057 0.68731E-16 -16.1628 0.34904E+00 -0.4571 89 P2O7-4 0.78873E-15 -15.1031 0.12482E-15 -15.9037 0.15826E+00 -0.8006 90 H2S,aq 0.52410E-15 -15.2806 0.52329E-15 -15.2813 0.99844E+00 -0.0007 97 SO3-2 0.62616E-14 -14.2033 0.39198E-14 -14.4067 0.62601E+00 -0.2034 98 HSO3- 0.36903E-16 -16.4329 0.32284E-16 -16.4910 0.87483E+00 -0.0581 99 HSO4- 0.22993E-11 -11.6384 0.20145E-11 -11.6958 0.87615E+00 -0.0574 Charge balance for all species = 0.6517E-13 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.1498883E-09 -.9432060E-02 -.9500435E+01 0.0000 2 H2O 0.1000000E+01 0.5550914E+02 0.9993284E+06 0.0000 3 Cl- 0.1379944E-03 0.1383098E-03 0.4900138E+01 5.9627 4 SO4-- 0.2554885E-04 0.2556776E-04 0.2454396E+01 14.9630 5 HCO3- 0.6767053E-05 0.1310179E-04 0.7988869E+00 4.6536 6 HS- 0.1471216E-11 -.1244609E-08 -.4113350E-04 -2.0094 7 Al+++ 0.4344894E-27 0.3474494E-04 0.9368280E+00 1.8235 8 H4SiO4 0.4695843E-03 0.4704706E-02 0.4518848E+03 -3.3283 9 Ca++ 0.3758157E-07 0.5528260E-07 0.2214098E-02 12.1290 10 Mg++ 0.2073691E-10 0.6616674E-10 0.1607543E-05 8.8697 11 Fe++ 0.1198307E-12 0.2909435E-07 0.1623719E-02 6.6318 12 K+ 0.7106000E-04 0.7127967E-04 0.2785267E+01 5.6749 13 Na+ 0.9009023E-02 0.9459940E-02 0.2173331E+03 7.7775 14 Mn++ 0.1642489E-10 0.9318235E-09 0.5115743E-04 8.7689 15 HPO4-- 0.5034421E-06 0.5097360E-06 0.4889042E-01 13.2576 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.2914003E+00 -.9409170E-02 -.2819911E+00 0.0000000E+00 2 H2O 0.5528764E+02 0.5537443E+02 -.8678896E-01 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.5132328E-03 0.2550571E-04 0.4877270E-03 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.4877283E-03 -.1241589E-08 -.4877270E-03 0.0000000E+00 7 Al+++ 0.5738579E-01 0.3466062E-04 0.5735113E-01 0.0000000E+00 8 H4SiO4 0.1832546E+00 0.4693289E-02 0.1785613E+00 0.0000000E+00 9 Ca++ 0.2025583E-01 0.5514845E-07 0.2025578E-01 0.0000000E+00 10 Mg++ 0.1396746E-01 0.6600617E-10 0.1396746E-01 0.0000000E+00 11 Fe++ 0.1254824E-01 0.2902375E-07 0.1254821E-01 0.0000000E+00 12 K+ 0.3736518E-02 0.7110669E-04 0.3665411E-02 0.0000000E+00 13 Na+ 0.2225110E-01 0.9436983E-02 0.1281412E-01 0.0000000E+00 14 Mn++ 0.3051420E-03 0.9295621E-09 0.3051410E-03 0.0000000E+00 15 HPO4-- 0.1041434E-03 0.5084989E-06 0.1036349E-03 0.0000000E+00 Chg. balance for solid moles: 0.7763E-16 Mass of aqueous solution: 0.998257E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 17.5990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 0.1277E-01 -1.894 3.347 0.525 17.43 1.285 andradite 0.1364E-02 -2.865 0.6932 -0.159 3.609 0.1801 grossular 0.6515E-04 -4.186 0.2934E-01 -1.532 0.1528 0.8165E-02 apatite-OH 0.3454E-04 -4.462 0.1735E-01 -1.761 0.9033E-01 0.5514E-02 clinochlore 0.2793E-02 -2.554 1.553 0.191 8.083 0.5906 daphnite 0.1695E-02 -2.771 1.209 0.082 6.295 0.3664 chlorite-Mn 0.6103E-04 -4.214 0.4327E-01 -1.364 0.2252 0.1379E-01 hematite 0.4399E-03 -3.357 0.7025E-01 -1.153 0.3657 0.1332E-01 microcline 0.3648E-02 -2.438 1.015 0.007 5.286 0.3966 stilbite 0.1580E-01 -1.801 11.13 1.047 57.95 5.192 stilpnomelane-Fe 0.3465E-04 -4.460 0.3735E-01 -1.428 0.1944 0.1290E-01 nontronite-Na 0.1470E-03 -3.833 0.6250E-01 -1.204 0.3254 0.1942E-01 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.9544E+00 0.9544E+00 1.0000 -0.020 grossular 0.4558E-01 0.4558E-01 1.0000 -1.341 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.6141E+00 0.6141E+00 1.0000 -0.212 daphnite 0.3725E+00 0.3725E+00 1.0000 -0.429 chlorite-Mn 0.1342E-01 0.1342E-01 1.0000 -1.872 hematite 0.1000E+01 0.1000E+01 1.0000 0.000 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 nontronite-Na 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 19.209310 g Volume = 8.083731 cm3 Porosity: -0.5489% V(tot) - V(min): -.44131E-01 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 17.5990000 g log = 1.2455 Original solution: 1000.0103000 g Original solution / Rock added: 56.82 (Water/Rock Ratio), log = 1.7545 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0203 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.1000E+01 0.9860 0.1006E+01 0.1020E+01 CO2,gas 0.1734E-06 1.0071 0.1782E-06 0.1769E-06 CH4,gas 0.6642E-15 1.0125 0.6861E-15 0.6776E-15 H2,gas 0.2441E-05 1.0005 0.2492E-05 0.2491E-05 H2S,gas 0.1415E-13 0.9960 0.1438E-13 0.1444E-13 S2,gas 0.1226E-35 1.0000 0.1251E-35 0.1251E-35 CO,gas 0.1160E-15 1.0000 0.1183E-15 0.1183E-15 SO3,gas 0.1019E-39 1.0000 0.1040E-39 0.1040E-39 SO2,gas 0.9879E-23 1.0000 0.1008E-22 0.1008E-22 HCl,gas 0.5032E-17 1.0000 0.5135E-17 0.5135E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 16 albite -0.38 -0.38 0.00 0.000 -0.13080E-10 22 andradite 39.01 39.01 0.00 0.000 -0.12132E-10 23 grossular 32.73 32.73 0.00 0.000 -0.12132E-10 32 apatite-OH -18.15 -18.15 0.00 0.000 -0.12132E-10 46 clinochlore 39.07 39.07 0.00 0.000 -0.24265E-10 47 daphnite 28.97 28.97 0.00 0.000 -0.24265E-10 48 chlorite-Mn 46.87 46.87 0.00 0.000 -0.36397E-10 90 hematite 12.57 12.57 0.00 0.000 0.30331E-11 116 microcline -2.49 -2.49 0.00 0.000 -0.10616E-10 163 stilbite -7.52 -7.52 0.00 0.000 -0.90992E-11 164 stilpnomelane-Fe 13.02 13.02 0.00 0.000 0.21232E-10 209 nontronite-Na 3.52 3.52 0.00 0.000 0.37914E-11 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -15.11 -8.45 -2.816 0.14425E+05 -6.749 3 CH4,gas 4.54 -12.32 -16.86 -4.216 0.28792E+05 -15.164 4 H2,gas 8.00 0.70 -7.30 -4.173 0.12469E+05 -5.603 5 H2S,gas -6.23 -21.77 -15.54 -7.771 0.26536E+05 -13.842 6 S2,gas -7.34 -44.94 -37.60 -5.785 0.64204E+05 -35.903 7 CO,gas 3.21 -14.41 -17.63 -5.423 0.30096E+05 -15.927 8 SO3,gas 17.12 -24.56 -41.68 -10.421 0.71171E+05 -39.983 9 SO2,gas 0.83 -23.86 -24.70 -6.585 0.42167E+05 -22.997 10 HCl,gas 5.19 -13.80 -18.99 -9.494 0.32422E+05 -17.289 11 acmite 7.71 7.40 -0.31 -0.032 0.52197E+03 15 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 19 spessartine 24.46 19.97 -4.49 -0.224 0.76641E+04 20 analcite 3.32 2.94 -0.38 -0.042 0.64447E+03 21 andalusite 5.00 0.32 -4.68 -0.468 0.79958E+04 26 annite 20.12 17.41 -2.71 -0.151 0.46351E+04 27 phlogopite 27.06 24.12 -2.94 -0.163 0.50234E+04 29 anorthite 12.71 9.12 -3.59 -0.276 0.61314E+04 35 aragonite 0.97 -2.98 -3.95 -1.315 0.67374E+04 36 brucite 12.57 8.87 -3.70 -0.740 0.63157E+04 37 calcite 0.81 -2.98 -3.79 -1.264 0.64732E+04 38 carnegieite-low 9.02 6.27 -2.75 -0.393 0.46966E+04 39 carnegieite-high 10.09 6.27 -3.82 -0.546 0.65236E+04 40 carpholite-Mg 8.58 5.86 -2.72 -0.181 0.46477E+04 41 carpholite-Fe 6.71 3.62 -3.09 -0.206 0.52769E+04 42 celadonite 5.34 3.05 -2.29 -0.135 0.39045E+04 43 celadonite-Fe 3.88 0.82 -3.06 -0.180 0.52241E+04 44 chrysotile 23.89 19.95 -3.94 -0.328 0.67272E+04 50 chloritoid-Mg 13.20 9.19 -4.01 -0.267 0.68458E+04 51 chloritoid-Fe 9.17 6.95 -2.22 -0.148 0.37960E+04 52 chloritoid-Mn 11.40 9.09 -2.31 -0.154 0.39502E+04 54 coesite -2.38 -3.33 -0.95 -0.317 0.16259E+04 59 corundum 8.38 3.65 -4.74 -0.431 0.80868E+04 61 cristobalite -2.56 -3.33 -0.77 -0.256 0.13113E+04 63 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71234E+04 65 diaspore 2.87 1.82 -1.05 -0.175 0.17932E+04 67 diopside 16.18 14.34 -1.84 -0.184 0.31405E+04 68 hedenbergite 14.21 12.10 -2.10 -0.210 0.35927E+04 75 epidote 24.67 24.20 -0.47 -0.023 0.79698E+03 76 clinozoisite 22.81 19.74 -3.06 -0.139 0.52291E+04 77 epidote-Fe 29.84 28.66 -1.18 -0.061 0.20115E+04 78 fayalite 14.05 9.94 -4.11 -0.587 0.70185E+04 79 ferrosilite 11.15 6.61 -4.54 -0.454 0.77562E+04 83 gibbsite 4.08 1.82 -2.26 -0.322 0.38517E+04 84 glaucophane 22.97 19.18 -3.79 -0.102 0.64714E+04 85 glaucophane-Fe 17.28 12.47 -4.80 -0.130 0.82041E+04 87 greenalite 16.14 13.24 -2.90 -0.242 0.49530E+04 91 heulandite -5.83 -7.52 -1.69 -0.077 0.28938E+04 95 jadeite 4.22 2.94 -1.27 -0.127 0.21700E+04 96 julgoldite 70.43 66.94 -3.48 -0.091 0.59503E+04 97 kalsilite 7.58 4.17 -3.41 -0.488 0.58290E+04 98 kaolinite -1.33 -3.01 -1.68 -0.152 0.28631E+04 99 kyanite 4.88 0.32 -4.56 -0.456 0.77817E+04 101 laumontite 2.88 2.46 -0.42 -0.028 0.71817E+03 102 lawsonite 9.62 9.12 -0.50 -0.033 0.84809E+03 103 leucite 4.12 0.84 -3.28 -0.328 0.55955E+04 105 lizardite 23.24 19.95 -3.29 -0.274 0.56199E+04 107 magnetite 20.09 19.20 -0.89 -0.073 0.15187E+04 108 minnesotaite 10.39 6.58 -3.81 -0.224 0.64986E+04 110 magnesioferrite 26.21 21.44 -4.78 -0.390 0.81558E+04 113 margarite 17.32 12.77 -4.56 -0.182 0.77814E+04 120 muscovite 2.58 1.16 -1.42 -0.084 0.24279E+04 121 paragonite 4.24 3.26 -0.98 -0.057 0.16670E+04 122 nepheline 8.34 6.27 -2.07 -0.295 0.35289E+04 128 periclase-Fe 11.63 6.63 -4.99 -1.249 0.85285E+04 134 phlogopite-Na 29.65 26.23 -3.42 -0.190 0.58422E+04 136 prehnite 19.37 17.92 -1.45 -0.085 0.24789E+04 137 prehnite-Fe 22.50 22.38 -0.12 -0.007 0.20183E+03 138 pumpellyite-Fe 46.27 44.30 -1.97 -0.044 0.33706E+04 139 pumpellyite-Mg 48.99 46.53 -2.46 -0.055 0.42031E+04 145 pyroxmangite 7.40 5.44 -1.96 -0.392 0.33434E+04 146 pyrophyllite -6.18 -9.67 -3.49 -0.218 0.59597E+04 147 quartz -2.99 -3.33 -0.34 -0.113 0.57858E+03 152 rhodonite 7.45 5.44 -2.01 -0.401 0.34236E+04 153 sanidine -1.28 -2.49 -1.21 -0.093 0.20677E+04 156 sillimanite 5.26 0.32 -4.94 -0.494 0.84397E+04 165 stilpnomelane-Mg 27.44 24.21 -3.23 -0.097 0.55233E+04 171 talc 16.49 13.30 -3.20 -0.188 0.54556E+04 174 tephroite 18.09 14.21 -3.88 -0.554 0.66187E+04 177 topaz-H 4.62 0.32 -4.30 -0.391 0.73418E+04 178 tridymite -2.63 -3.33 -0.70 -0.234 0.11986E+04 187 wairakite 3.95 2.46 -1.49 -0.088 0.25401E+04 188 walstromite 11.51 8.80 -2.71 -0.542 0.46248E+04 189 wollastonite 10.46 8.80 -1.66 -0.332 0.28352E+04 190 pseudo-wollastonite 11.00 8.80 -2.20 -0.440 0.37550E+04 191 zoisite 22.85 19.74 -3.11 -0.141 0.53032E+04 192 akaganeite 7.75 6.28 -1.47 -0.318 0.25125E+04 193 beidellite-Ca -1.65 -5.96 -4.32 -0.267 0.73749E+04 195 beidellite-K -1.52 -6.09 -4.57 -0.280 0.78085E+04 196 beidellite-Mg -1.79 -6.50 -4.71 -0.292 0.80470E+04 197 beidellite-Na -1.34 -5.40 -4.06 -0.248 0.69277E+04 199 chalcedony -2.80 -3.33 -0.53 -0.175 0.89788E+03 201 montmorillonite-Ca -2.29 -5.34 -3.05 -0.189 0.52059E+04 202 montmorillonite-K -2.24 -5.47 -3.23 -0.198 0.55177E+04 203 montmorillonite-Mg -2.48 -5.88 -3.40 -0.210 0.58012E+04 204 montmorillonite-Na -2.04 -4.77 -2.74 -0.168 0.46726E+04 205 nontronite-Ca 3.21 2.95 -0.26 -0.017 0.44418E+03 206 nontronite-H 2.53 0.95 -1.58 -0.106 0.26971E+04 207 nontronite-K 3.34 2.83 -0.51 -0.033 0.87912E+03 208 nontronite-Mg 3.07 2.42 -0.66 -0.043 0.11235E+04 224 tobermorite 9.82 6.78 -3.05 -0.832 0.52042E+04 233 boehmite 4.41 1.82 -2.58 -0.430 0.44101E+04 235 ferrous-oxide 9.81 6.63 -3.18 -0.795 0.54294E+04 240 silica-amorphous -2.09 -3.33 -1.24 -0.412 0.21121E+04 242 an20ab80 2.02 1.52 -0.50 -0.039 0.85544E+03 243 an25ab75 2.65 1.99 -0.65 -0.050 0.11163E+04 244 an30ab70 3.28 2.47 -0.81 -0.062 0.13867E+04 245 tr.625ac.25prg.125 45.16 40.56 -4.60 -0.124 0.78589E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 0.4000000 g Current total amount of reactant added: 17.5990000 g New total amount of reactant added: 17.9990000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.6629E-13 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 7 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 17.9990000 Water: Moles liquid = 0.5537E+02 kg liquid = 0.9975E+00 Moles total = 0.5528E+02 kg total = 0.9959E+00 Activity = 1.0000 Stoichiometric ionic strength = .5049920E-02 Osmotic coef. = 0.9622 True ionic strength = .9112620E-02 Chg. balance for total moles = 0.6629E-13 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.14989E-09 -9.8242 0.13154E-09 -9.8809 0.87760E+00 -0.0567 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13800E-03 -3.8601 0.12073E-03 -3.9182 0.87483E+00 -0.0581 4 SO4-- 0.25550E-04 -4.5926 0.15892E-04 -4.7988 0.62199E+00 -0.2062 5 HCO3- 0.67673E-05 -5.1696 0.59248E-05 -5.2273 0.87549E+00 -0.0577 6 HS- 0.14713E-11 -11.8323 0.12872E-11 -11.8904 0.87489E+00 -0.0580 7 Al+++ 0.43449E-27 -27.3620 0.15159E-27 -27.8193 0.34890E+00 -0.4573 8 H4SiO4 0.46958E-03 -3.3283 0.46958E-03 -3.3283 0.10000E+01 0.0000 9 Ca++ 0.37582E-07 -7.4250 0.23286E-07 -7.6329 0.61961E+00 -0.2079 10 Mg++ 0.20737E-10 -10.6833 0.12818E-10 -10.8922 0.61813E+00 -0.2089 11 Fe++ 0.11983E-12 -12.9214 0.74113E-13 -13.1301 0.61848E+00 -0.2087 12 K+ 0.71060E-04 -4.1484 0.62221E-04 -4.2061 0.87561E+00 -0.0577 13 Na+ 0.90090E-02 -2.0453 0.78807E-02 -2.1034 0.87475E+00 -0.0581 14 Mn++ 0.16425E-10 -10.7845 0.10163E-10 -10.9930 0.61875E+00 -0.2085 15 HPO4-- 0.50344E-06 -6.2981 0.31316E-06 -6.5042 0.62203E+00 -0.2062 16 HSiO3- 0.38103E-02 -2.4190 0.33333E-02 -2.4771 0.87483E+00 -0.0581 17 Ca(HSiO3)+ 0.20186E-08 -8.6950 0.17677E-08 -8.7526 0.87571E+00 -0.0576 18 Mg(HSiO3)+ 0.13828E-11 -11.8592 0.12110E-11 -11.9169 0.87571E+00 -0.0576 19 NaHSiO3,aq 0.42486E-03 -3.3718 0.42486E-03 -3.3718 0.10000E+01 0.0000 20 AlO+ 0.13610E-14 -14.8661 0.11919E-14 -14.9238 0.87571E+00 -0.0576 22 HAlO2,aq 0.18044E-08 -8.7437 0.18044E-08 -8.7437 0.10000E+01 0.0000 23 AlO2- 0.34743E-04 -4.4591 0.30365E-04 -4.5176 0.87399E+00 -0.0585 24 CH4,aq 0.46689E-18 -18.3308 0.46616E-18 -18.3315 0.99844E+00 -0.0007 29 CO,aq 0.79407E-19 -19.1001 0.79407E-19 -19.1001 0.10000E+01 0.0000 30 CO2,aq 0.16679E-08 -8.7778 0.16653E-08 -8.7785 0.99844E+00 -0.0007 31 CO3-2 0.63322E-05 -5.1984 0.39341E-05 -5.4052 0.62129E+00 -0.2067 32 CaCO3,aq 0.11487E-08 -8.9398 0.11487E-08 -8.9398 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.40215E-11 -11.3956 0.35217E-11 -11.4533 0.87571E+00 -0.0576 34 CaCl+ 0.51952E-11 -11.2844 0.45495E-11 -11.3420 0.87571E+00 -0.0576 35 CaCl2,aq 0.13049E-15 -15.8844 0.13049E-15 -15.8844 0.10000E+01 0.0000 36 CaOH+ 0.14407E-07 -7.8414 0.12616E-07 -7.8991 0.87571E+00 -0.0576 37 CaSO4,aq 0.11751E-09 -9.9299 0.11751E-09 -9.9299 0.10000E+01 0.0000 38 HCl,aq 0.29100E-14 -14.5361 0.29100E-14 -14.5361 0.10000E+01 0.0000 43 FeCl+ 0.16172E-16 -16.7912 0.14162E-16 -16.8489 0.87571E+00 -0.0576 46 FeO,aq 0.16647E-09 -9.7787 0.16647E-09 -9.7787 0.10000E+01 0.0000 47 FeOH+ 0.20943E-10 -10.6790 0.18340E-10 -10.7366 0.87571E+00 -0.0576 48 HFeO2- 0.15136E-07 -7.8200 0.13241E-07 -7.8781 0.87483E+00 -0.0581 49 FeO+ 0.11466E-14 -14.9406 0.10040E-14 -14.9982 0.87571E+00 -0.0576 51 FeO2- 0.13572E-07 -7.8673 0.11873E-07 -7.9254 0.87483E+00 -0.0581 52 HFeO2,aq 0.19864E-09 -9.7019 0.19864E-09 -9.7019 0.10000E+01 0.0000 53 H2,aq 0.19011E-08 -8.7210 0.18982E-08 -8.7217 0.99844E+00 -0.0007 54 KCl,aq 0.13614E-09 -9.8660 0.13614E-09 -9.8660 0.10000E+01 0.0000 55 KHSO4,aq 0.36775E-18 -18.4344 0.36775E-18 -18.4344 0.10000E+01 0.0000 56 KOH,aq 0.20200E-06 -6.6946 0.20200E-06 -6.6946 0.10000E+01 0.0000 57 KSO4- 0.17539E-07 -7.7560 0.15344E-07 -7.8141 0.87483E+00 -0.0581 58 MgCO3,aq 0.15849E-12 -12.8000 0.15849E-12 -12.8000 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.22620E-14 -14.6455 0.19808E-14 -14.7032 0.87571E+00 -0.0576 60 MgCl+ 0.25919E-14 -14.5864 0.22698E-14 -14.6440 0.87571E+00 -0.0576 61 MgOH+ 0.43884E-10 -10.3577 0.38429E-10 -10.4153 0.87571E+00 -0.0576 63 MnO,aq 0.60825E-09 -9.2159 0.60825E-09 -9.2159 0.10000E+01 0.0000 64 MnOH+ 0.26678E-09 -9.5738 0.23362E-09 -9.6315 0.87571E+00 -0.0576 65 MnO2-2 0.18777E-11 -11.7264 0.11666E-11 -11.9331 0.62129E+00 -0.2067 66 HMnO2- 0.38431E-10 -10.4153 0.33620E-10 -10.4734 0.87483E+00 -0.0581 69 MnCl+ 0.86277E-14 -14.0641 0.75553E-14 -14.1217 0.87571E+00 -0.0576 70 MnSO4,aq 0.46625E-13 -13.3314 0.46625E-13 -13.3314 0.10000E+01 0.0000 71 NaCl,aq 0.31530E-06 -6.5013 0.31530E-06 -6.5013 0.10000E+01 0.0000 72 NaOH,aq 0.25740E-04 -4.5894 0.25740E-04 -4.5894 0.10000E+01 0.0000 74 OH- 0.50256E-02 -2.2988 0.43923E-02 -2.3573 0.87399E+00 -0.0585 79 HPO3-2 0.29816E-17 -17.5256 0.18524E-17 -17.7323 0.62129E+00 -0.2067 82 H3PO4,aq 0.37898E-16 -16.4214 0.37898E-16 -16.4214 0.10000E+01 0.0000 83 H2PO4- 0.86821E-09 -9.0614 0.75991E-09 -9.1192 0.87526E+00 -0.0579 84 PO4-3 0.54256E-08 -8.2656 0.19424E-08 -8.7117 0.35800E+00 -0.4461 87 H2P2O7-2 0.72878E-19 -19.1374 0.45278E-19 -19.3441 0.62129E+00 -0.2067 88 HP2O7-3 0.19691E-15 -15.7057 0.68731E-16 -16.1628 0.34904E+00 -0.4571 89 P2O7-4 0.78873E-15 -15.1031 0.12482E-15 -15.9037 0.15826E+00 -0.8006 90 H2S,aq 0.52413E-15 -15.2806 0.52331E-15 -15.2812 0.99844E+00 -0.0007 97 SO3-2 0.62618E-14 -14.2033 0.39200E-14 -14.4067 0.62601E+00 -0.2034 98 HSO3- 0.36905E-16 -16.4329 0.32285E-16 -16.4910 0.87483E+00 -0.0581 99 HSO4- 0.22994E-11 -11.6384 0.20146E-11 -11.6958 0.87615E+00 -0.0574 Charge balance for all species = 0.6525E-13 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.1498883E-09 -.9432056E-02 -.9500431E+01 0.0000 2 H2O 0.1000000E+01 0.5550914E+02 0.9993284E+06 0.0000 3 Cl- 0.1379999E-03 0.1383154E-03 0.4900334E+01 5.9627 4 SO4-- 0.2554988E-04 0.2556879E-04 0.2454495E+01 14.9630 5 HCO3- 0.6767326E-05 0.1310232E-04 0.7989190E+00 4.6536 6 HS- 0.1471276E-11 -.1244608E-08 -.4113348E-04 -2.0094 7 Al+++ 0.4344901E-27 0.3474492E-04 0.9368276E+00 1.8235 8 H4SiO4 0.4695843E-03 0.4704704E-02 0.4518846E+03 -3.3283 9 Ca++ 0.3758161E-07 0.5528270E-07 0.2214102E-02 12.1290 10 Mg++ 0.2073693E-10 0.6616680E-10 0.1607545E-05 8.8697 11 Fe++ 0.1198308E-12 0.2909434E-07 0.1623718E-02 6.6318 12 K+ 0.7106003E-04 0.7127971E-04 0.2785269E+01 5.6749 13 Na+ 0.9009028E-02 0.9459944E-02 0.2173332E+03 7.7775 14 Mn++ 0.1642490E-10 0.9318237E-09 0.5115744E-04 8.7689 15 HPO4-- 0.5034417E-06 0.5097355E-06 0.4889038E-01 13.2576 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.2980237E+00 -.9408789E-02 -.2886149E+00 0.0000000E+00 2 H2O 0.5528263E+02 0.5537220E+02 -.8957884E-01 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.5243181E-03 0.2550571E-04 0.4988124E-03 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.4988136E-03 -.1241538E-08 -.4988124E-03 0.0000000E+00 7 Al+++ 0.5869009E-01 0.3465921E-04 0.5865543E-01 0.0000000E+00 8 H4SiO4 0.1874197E+00 0.4693098E-02 0.1827266E+00 0.0000000E+00 9 Ca++ 0.2071589E-01 0.5514633E-07 0.2071583E-01 0.0000000E+00 10 Mg++ 0.1428492E-01 0.6600357E-10 0.1428492E-01 0.0000000E+00 11 Fe++ 0.1283344E-01 0.2902257E-07 0.1283341E-01 0.0000000E+00 12 K+ 0.3821444E-02 0.7110387E-04 0.3750340E-02 0.0000000E+00 13 Na+ 0.2275320E-01 0.9436608E-02 0.1331659E-01 0.0000000E+00 14 Mn++ 0.3120774E-03 0.9295250E-09 0.3120765E-03 0.0000000E+00 15 HPO4-- 0.1065105E-03 0.5084781E-06 0.1060020E-03 0.0000000E+00 Chg. balance for solid moles: 0.2542E-16 Mass of aqueous solution: 0.998217E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 17.9990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 0.1325E-01 -1.878 3.475 0.541 17.69 1.334 andradite 0.1429E-02 -2.845 0.7263 -0.139 3.697 0.1887 grossular 0.6826E-04 -4.166 0.3075E-01 -1.512 0.1565 0.8555E-02 apatite-OH 0.3533E-04 -4.452 0.1775E-01 -1.751 0.9034E-01 0.5640E-02 clinochlore 0.2857E-02 -2.544 1.588 0.201 8.083 0.6040 daphnite 0.1733E-02 -2.761 1.237 0.092 6.294 0.3747 chlorite-Mn 0.6242E-04 -4.205 0.4425E-01 -1.354 0.2252 0.1410E-01 hematite 0.3730E-03 -3.428 0.5957E-01 -1.225 0.3032 0.1129E-01 microcline 0.3733E-02 -2.428 1.039 0.017 5.288 0.4058 stilbite 0.1605E-01 -1.795 11.31 1.053 57.56 5.275 stilpnomelane-Fe 0.3543E-04 -4.451 0.3820E-01 -1.418 0.1944 0.1319E-01 nontronite-Na 0.1931E-03 -3.714 0.8211E-01 -1.086 0.4179 0.2551E-01 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.9544E+00 0.9544E+00 1.0000 -0.020 grossular 0.4558E-01 0.4558E-01 1.0000 -1.341 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.6141E+00 0.6141E+00 1.0000 -0.212 daphnite 0.3725E+00 0.3725E+00 1.0000 -0.429 chlorite-Mn 0.1342E-01 0.1342E-01 1.0000 -1.872 hematite 0.1000E+01 0.1000E+01 1.0000 0.000 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 nontronite-Na 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 19.646170 g Volume = 8.260128 cm3 Porosity: -0.7382% V(tot) - V(min): -.60528E-01 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 17.9990000 g log = 1.2552 Original solution: 1000.0103000 g Original solution / Rock added: 55.56 (Water/Rock Ratio), log = 1.7448 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0203 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.1000E+01 0.9860 0.1006E+01 0.1020E+01 CO2,gas 0.1734E-06 1.0071 0.1782E-06 0.1769E-06 CH4,gas 0.6642E-15 1.0125 0.6862E-15 0.6777E-15 H2,gas 0.2441E-05 1.0005 0.2492E-05 0.2491E-05 H2S,gas 0.1416E-13 0.9960 0.1439E-13 0.1444E-13 S2,gas 0.1226E-35 1.0000 0.1251E-35 0.1251E-35 CO,gas 0.1160E-15 1.0000 0.1183E-15 0.1183E-15 SO3,gas 0.1019E-39 1.0000 0.1040E-39 0.1040E-39 SO2,gas 0.9880E-23 1.0000 0.1008E-22 0.1008E-22 HCl,gas 0.5033E-17 1.0000 0.5135E-17 0.5135E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 16 albite -0.38 -0.38 0.00 0.000 -0.94784E-12 22 andradite 39.01 39.01 0.00 0.000 -0.12132E-10 23 grossular 32.73 32.73 0.00 0.000 0.00000E+00 32 apatite-OH -18.15 -18.15 0.00 0.000 0.00000E+00 46 clinochlore 39.07 39.07 0.00 0.000 -0.12132E-10 47 daphnite 28.97 28.97 0.00 0.000 0.60662E-11 48 chlorite-Mn 46.87 46.87 0.00 0.000 -0.36397E-10 90 hematite 12.57 12.57 0.00 0.000 -0.15165E-10 116 microcline -2.49 -2.49 0.00 0.000 -0.10616E-10 163 stilbite -7.52 -7.52 0.00 0.000 -0.90992E-11 164 stilpnomelane-Fe 13.02 13.02 0.00 0.000 -0.27298E-10 209 nontronite-Na 3.52 3.52 0.00 0.000 -0.83410E-11 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -15.11 -8.45 -2.816 0.14425E+05 -6.749 3 CH4,gas 4.54 -12.32 -16.86 -4.216 0.28792E+05 -15.164 4 H2,gas 8.00 0.70 -7.30 -4.173 0.12469E+05 -5.603 5 H2S,gas -6.23 -21.77 -15.54 -7.771 0.26536E+05 -13.842 6 S2,gas -7.34 -44.94 -37.60 -5.785 0.64204E+05 -35.903 7 CO,gas 3.21 -14.41 -17.63 -5.423 0.30096E+05 -15.927 8 SO3,gas 17.12 -24.56 -41.68 -10.421 0.71171E+05 -39.983 9 SO2,gas 0.83 -23.86 -24.70 -6.585 0.42167E+05 -22.997 10 HCl,gas 5.19 -13.80 -18.99 -9.494 0.32422E+05 -17.289 11 acmite 7.71 7.40 -0.31 -0.032 0.52197E+03 15 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 19 spessartine 24.46 19.97 -4.49 -0.224 0.76641E+04 20 analcite 3.32 2.94 -0.38 -0.042 0.64447E+03 21 andalusite 5.00 0.32 -4.68 -0.468 0.79958E+04 26 annite 20.12 17.41 -2.71 -0.151 0.46351E+04 27 phlogopite 27.06 24.12 -2.94 -0.163 0.50234E+04 29 anorthite 12.71 9.12 -3.59 -0.276 0.61314E+04 35 aragonite 0.97 -2.98 -3.95 -1.315 0.67374E+04 36 brucite 12.57 8.87 -3.70 -0.740 0.63157E+04 37 calcite 0.81 -2.98 -3.79 -1.264 0.64732E+04 38 carnegieite-low 9.02 6.27 -2.75 -0.393 0.46966E+04 39 carnegieite-high 10.09 6.27 -3.82 -0.546 0.65236E+04 40 carpholite-Mg 8.58 5.86 -2.72 -0.181 0.46477E+04 41 carpholite-Fe 6.71 3.62 -3.09 -0.206 0.52769E+04 42 celadonite 5.34 3.05 -2.29 -0.135 0.39045E+04 43 celadonite-Fe 3.88 0.82 -3.06 -0.180 0.52241E+04 44 chrysotile 23.89 19.95 -3.94 -0.328 0.67272E+04 50 chloritoid-Mg 13.20 9.19 -4.01 -0.267 0.68458E+04 51 chloritoid-Fe 9.17 6.95 -2.22 -0.148 0.37960E+04 52 chloritoid-Mn 11.40 9.09 -2.31 -0.154 0.39502E+04 54 coesite -2.38 -3.33 -0.95 -0.317 0.16259E+04 59 corundum 8.38 3.65 -4.74 -0.431 0.80868E+04 61 cristobalite -2.56 -3.33 -0.77 -0.256 0.13113E+04 63 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71234E+04 65 diaspore 2.87 1.82 -1.05 -0.175 0.17932E+04 67 diopside 16.18 14.34 -1.84 -0.184 0.31405E+04 68 hedenbergite 14.21 12.10 -2.10 -0.210 0.35927E+04 75 epidote 24.67 24.20 -0.47 -0.023 0.79698E+03 76 clinozoisite 22.81 19.74 -3.06 -0.139 0.52291E+04 77 epidote-Fe 29.84 28.66 -1.18 -0.061 0.20115E+04 78 fayalite 14.05 9.94 -4.11 -0.587 0.70185E+04 79 ferrosilite 11.15 6.61 -4.54 -0.454 0.77562E+04 83 gibbsite 4.08 1.82 -2.26 -0.322 0.38517E+04 84 glaucophane 22.97 19.18 -3.79 -0.102 0.64714E+04 85 glaucophane-Fe 17.28 12.47 -4.80 -0.130 0.82041E+04 87 greenalite 16.14 13.24 -2.90 -0.242 0.49530E+04 91 heulandite -5.83 -7.52 -1.69 -0.077 0.28938E+04 95 jadeite 4.22 2.94 -1.27 -0.127 0.21700E+04 96 julgoldite 70.43 66.94 -3.48 -0.091 0.59503E+04 97 kalsilite 7.58 4.17 -3.41 -0.488 0.58290E+04 98 kaolinite -1.33 -3.01 -1.68 -0.152 0.28631E+04 99 kyanite 4.88 0.32 -4.56 -0.456 0.77817E+04 101 laumontite 2.88 2.46 -0.42 -0.028 0.71817E+03 102 lawsonite 9.62 9.12 -0.50 -0.033 0.84809E+03 103 leucite 4.12 0.84 -3.28 -0.328 0.55955E+04 105 lizardite 23.24 19.95 -3.29 -0.274 0.56199E+04 107 magnetite 20.09 19.20 -0.89 -0.073 0.15187E+04 108 minnesotaite 10.39 6.58 -3.81 -0.224 0.64986E+04 110 magnesioferrite 26.21 21.44 -4.78 -0.390 0.81558E+04 113 margarite 17.32 12.77 -4.56 -0.182 0.77814E+04 120 muscovite 2.58 1.16 -1.42 -0.084 0.24279E+04 121 paragonite 4.24 3.26 -0.98 -0.057 0.16670E+04 122 nepheline 8.34 6.27 -2.07 -0.295 0.35289E+04 128 periclase-Fe 11.63 6.63 -4.99 -1.249 0.85285E+04 134 phlogopite-Na 29.65 26.23 -3.42 -0.190 0.58422E+04 136 prehnite 19.37 17.92 -1.45 -0.085 0.24789E+04 137 prehnite-Fe 22.50 22.38 -0.12 -0.007 0.20183E+03 138 pumpellyite-Fe 46.27 44.30 -1.97 -0.044 0.33706E+04 139 pumpellyite-Mg 48.99 46.53 -2.46 -0.055 0.42031E+04 145 pyroxmangite 7.40 5.44 -1.96 -0.392 0.33434E+04 146 pyrophyllite -6.18 -9.67 -3.49 -0.218 0.59597E+04 147 quartz -2.99 -3.33 -0.34 -0.113 0.57858E+03 152 rhodonite 7.45 5.44 -2.01 -0.401 0.34236E+04 153 sanidine -1.28 -2.49 -1.21 -0.093 0.20677E+04 156 sillimanite 5.26 0.32 -4.94 -0.494 0.84397E+04 165 stilpnomelane-Mg 27.44 24.21 -3.23 -0.097 0.55233E+04 171 talc 16.49 13.30 -3.20 -0.188 0.54556E+04 174 tephroite 18.09 14.21 -3.88 -0.554 0.66187E+04 177 topaz-H 4.62 0.32 -4.30 -0.391 0.73418E+04 178 tridymite -2.63 -3.33 -0.70 -0.234 0.11986E+04 187 wairakite 3.95 2.46 -1.49 -0.088 0.25401E+04 188 walstromite 11.51 8.80 -2.71 -0.542 0.46248E+04 189 wollastonite 10.46 8.80 -1.66 -0.332 0.28352E+04 190 pseudo-wollastonite 11.00 8.80 -2.20 -0.440 0.37550E+04 191 zoisite 22.85 19.74 -3.11 -0.141 0.53032E+04 192 akaganeite 7.75 6.28 -1.47 -0.318 0.25125E+04 193 beidellite-Ca -1.65 -5.96 -4.32 -0.267 0.73749E+04 195 beidellite-K -1.52 -6.09 -4.57 -0.280 0.78085E+04 196 beidellite-Mg -1.79 -6.50 -4.71 -0.292 0.80470E+04 197 beidellite-Na -1.34 -5.40 -4.06 -0.248 0.69277E+04 199 chalcedony -2.80 -3.33 -0.53 -0.175 0.89788E+03 201 montmorillonite-Ca -2.29 -5.34 -3.05 -0.189 0.52059E+04 202 montmorillonite-K -2.24 -5.47 -3.23 -0.198 0.55177E+04 203 montmorillonite-Mg -2.48 -5.88 -3.40 -0.210 0.58012E+04 204 montmorillonite-Na -2.04 -4.77 -2.74 -0.168 0.46726E+04 205 nontronite-Ca 3.21 2.95 -0.26 -0.017 0.44418E+03 206 nontronite-H 2.53 0.95 -1.58 -0.106 0.26971E+04 207 nontronite-K 3.34 2.83 -0.51 -0.033 0.87912E+03 208 nontronite-Mg 3.07 2.42 -0.66 -0.043 0.11235E+04 224 tobermorite 9.82 6.78 -3.05 -0.832 0.52042E+04 233 boehmite 4.41 1.82 -2.58 -0.430 0.44101E+04 235 ferrous-oxide 9.81 6.63 -3.18 -0.795 0.54294E+04 240 silica-amorphous -2.09 -3.33 -1.24 -0.412 0.21121E+04 242 an20ab80 2.02 1.52 -0.50 -0.039 0.85544E+03 243 an25ab75 2.65 1.99 -0.65 -0.050 0.11163E+04 244 an30ab70 3.28 2.47 -0.81 -0.062 0.13867E+04 245 tr.625ac.25prg.125 45.16 40.56 -4.60 -0.124 0.78589E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 0.4000000 g Current total amount of reactant added: 17.9990000 g New total amount of reactant added: 18.3990000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.6627E-13 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 7 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 18.3990000 Water: Moles liquid = 0.5537E+02 kg liquid = 0.9975E+00 Moles total = 0.5528E+02 kg total = 0.9958E+00 Activity = 1.0000 Stoichiometric ionic strength = .5049927E-02 Osmotic coef. = 0.9622 True ionic strength = .9112625E-02 Chg. balance for total moles = 0.6627E-13 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.14989E-09 -9.8242 0.13154E-09 -9.8809 0.87760E+00 -0.0567 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13801E-03 -3.8601 0.12073E-03 -3.9182 0.87483E+00 -0.0581 4 SO4-- 0.25551E-04 -4.5926 0.15892E-04 -4.7988 0.62199E+00 -0.2062 5 HCO3- 0.67676E-05 -5.1696 0.59250E-05 -5.2273 0.87549E+00 -0.0577 6 HS- 0.14713E-11 -11.8323 0.12873E-11 -11.8903 0.87489E+00 -0.0580 7 Al+++ 0.43449E-27 -27.3620 0.15159E-27 -27.8193 0.34890E+00 -0.4573 8 H4SiO4 0.46958E-03 -3.3283 0.46958E-03 -3.3283 0.10000E+01 0.0000 9 Ca++ 0.37582E-07 -7.4250 0.23286E-07 -7.6329 0.61961E+00 -0.2079 10 Mg++ 0.20737E-10 -10.6833 0.12818E-10 -10.8922 0.61813E+00 -0.2089 11 Fe++ 0.11983E-12 -12.9214 0.74113E-13 -13.1301 0.61848E+00 -0.2087 12 K+ 0.71060E-04 -4.1484 0.62221E-04 -4.2061 0.87561E+00 -0.0577 13 Na+ 0.90090E-02 -2.0453 0.78807E-02 -2.1034 0.87475E+00 -0.0581 14 Mn++ 0.16425E-10 -10.7845 0.10163E-10 -10.9930 0.61875E+00 -0.2085 15 HPO4-- 0.50344E-06 -6.2981 0.31316E-06 -6.5042 0.62203E+00 -0.2062 16 HSiO3- 0.38103E-02 -2.4190 0.33333E-02 -2.4771 0.87483E+00 -0.0581 17 Ca(HSiO3)+ 0.20186E-08 -8.6950 0.17677E-08 -8.7526 0.87571E+00 -0.0576 18 Mg(HSiO3)+ 0.13828E-11 -11.8592 0.12110E-11 -11.9169 0.87571E+00 -0.0576 19 NaHSiO3,aq 0.42486E-03 -3.3718 0.42486E-03 -3.3718 0.10000E+01 0.0000 20 AlO+ 0.13610E-14 -14.8661 0.11919E-14 -14.9238 0.87571E+00 -0.0576 22 HAlO2,aq 0.18044E-08 -8.7437 0.18044E-08 -8.7437 0.10000E+01 0.0000 23 AlO2- 0.34743E-04 -4.4591 0.30365E-04 -4.5176 0.87399E+00 -0.0585 24 CH4,aq 0.46691E-18 -18.3308 0.46618E-18 -18.3314 0.99844E+00 -0.0007 29 CO,aq 0.79411E-19 -19.1001 0.79411E-19 -19.1001 0.10000E+01 0.0000 30 CO2,aq 0.16680E-08 -8.7778 0.16654E-08 -8.7785 0.99844E+00 -0.0007 31 CO3-2 0.63324E-05 -5.1984 0.39343E-05 -5.4051 0.62129E+00 -0.2067 32 CaCO3,aq 0.11487E-08 -8.9398 0.11487E-08 -8.9398 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.40217E-11 -11.3956 0.35218E-11 -11.4532 0.87571E+00 -0.0576 34 CaCl+ 0.51954E-11 -11.2844 0.45496E-11 -11.3420 0.87571E+00 -0.0576 35 CaCl2,aq 0.13050E-15 -15.8844 0.13050E-15 -15.8844 0.10000E+01 0.0000 36 CaOH+ 0.14407E-07 -7.8414 0.12616E-07 -7.8991 0.87571E+00 -0.0576 37 CaSO4,aq 0.11751E-09 -9.9299 0.11751E-09 -9.9299 0.10000E+01 0.0000 38 HCl,aq 0.29102E-14 -14.5361 0.29102E-14 -14.5361 0.10000E+01 0.0000 43 FeCl+ 0.16173E-16 -16.7912 0.14163E-16 -16.8489 0.87571E+00 -0.0576 46 FeO,aq 0.16647E-09 -9.7787 0.16647E-09 -9.7787 0.10000E+01 0.0000 47 FeOH+ 0.20943E-10 -10.6790 0.18340E-10 -10.7366 0.87571E+00 -0.0576 48 HFeO2- 0.15136E-07 -7.8200 0.13241E-07 -7.8781 0.87483E+00 -0.0581 49 FeO+ 0.11466E-14 -14.9406 0.10040E-14 -14.9982 0.87571E+00 -0.0576 51 FeO2- 0.13572E-07 -7.8673 0.11873E-07 -7.9254 0.87483E+00 -0.0581 52 HFeO2,aq 0.19864E-09 -9.7019 0.19864E-09 -9.7019 0.10000E+01 0.0000 53 H2,aq 0.19011E-08 -8.7210 0.18982E-08 -8.7217 0.99844E+00 -0.0007 54 KCl,aq 0.13615E-09 -9.8660 0.13615E-09 -9.8660 0.10000E+01 0.0000 55 KHSO4,aq 0.36777E-18 -18.4344 0.36777E-18 -18.4344 0.10000E+01 0.0000 56 KOH,aq 0.20200E-06 -6.6946 0.20200E-06 -6.6946 0.10000E+01 0.0000 57 KSO4- 0.17540E-07 -7.7560 0.15344E-07 -7.8141 0.87483E+00 -0.0581 58 MgCO3,aq 0.15850E-12 -12.8000 0.15850E-12 -12.8000 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.22621E-14 -14.6455 0.19809E-14 -14.7031 0.87571E+00 -0.0576 60 MgCl+ 0.25920E-14 -14.5864 0.22698E-14 -14.6440 0.87571E+00 -0.0576 61 MgOH+ 0.43884E-10 -10.3577 0.38429E-10 -10.4153 0.87571E+00 -0.0576 63 MnO,aq 0.60825E-09 -9.2159 0.60825E-09 -9.2159 0.10000E+01 0.0000 64 MnOH+ 0.26678E-09 -9.5738 0.23363E-09 -9.6315 0.87571E+00 -0.0576 65 MnO2-2 0.18777E-11 -11.7264 0.11666E-11 -11.9331 0.62129E+00 -0.2067 66 HMnO2- 0.38431E-10 -10.4153 0.33620E-10 -10.4734 0.87483E+00 -0.0581 69 MnCl+ 0.86280E-14 -14.0641 0.75556E-14 -14.1217 0.87571E+00 -0.0576 70 MnSO4,aq 0.46627E-13 -13.3314 0.46627E-13 -13.3314 0.10000E+01 0.0000 71 NaCl,aq 0.31531E-06 -6.5013 0.31531E-06 -6.5013 0.10000E+01 0.0000 72 NaOH,aq 0.25740E-04 -4.5894 0.25740E-04 -4.5894 0.10000E+01 0.0000 74 OH- 0.50256E-02 -2.2988 0.43923E-02 -2.3573 0.87399E+00 -0.0585 79 HPO3-2 0.29816E-17 -17.5256 0.18524E-17 -17.7323 0.62129E+00 -0.2067 82 H3PO4,aq 0.37898E-16 -16.4214 0.37898E-16 -16.4214 0.10000E+01 0.0000 83 H2PO4- 0.86821E-09 -9.0614 0.75991E-09 -9.1192 0.87526E+00 -0.0579 84 PO4-3 0.54256E-08 -8.2656 0.19424E-08 -8.7117 0.35800E+00 -0.4461 87 H2P2O7-2 0.72878E-19 -19.1374 0.45278E-19 -19.3441 0.62129E+00 -0.2067 88 HP2O7-3 0.19691E-15 -15.7057 0.68731E-16 -16.1628 0.34904E+00 -0.4571 89 P2O7-4 0.78873E-15 -15.1031 0.12482E-15 -15.9037 0.15826E+00 -0.8006 90 H2S,aq 0.52415E-15 -15.2805 0.52333E-15 -15.2812 0.99844E+00 -0.0007 97 SO3-2 0.62621E-14 -14.2033 0.39201E-14 -14.4067 0.62601E+00 -0.2034 98 HSO3- 0.36906E-16 -16.4329 0.32287E-16 -16.4910 0.87483E+00 -0.0581 99 HSO4- 0.22995E-11 -11.6384 0.20147E-11 -11.6958 0.87615E+00 -0.0574 Charge balance for all species = 0.6521E-13 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.1498884E-09 -.9432053E-02 -.9500427E+01 0.0000 2 H2O 0.1000000E+01 0.5550914E+02 0.9993284E+06 0.0000 3 Cl- 0.1380055E-03 0.1383209E-03 0.4900531E+01 5.9628 4 SO4-- 0.2555091E-04 0.2556981E-04 0.2454594E+01 14.9631 5 HCO3- 0.6767599E-05 0.1310285E-04 0.7989511E+00 4.6536 6 HS- 0.1471336E-11 -.1244608E-08 -.4113345E-04 -2.0094 7 Al+++ 0.4344909E-27 0.3474491E-04 0.9368272E+00 1.8235 8 H4SiO4 0.4695843E-03 0.4704702E-02 0.4518844E+03 -3.3283 9 Ca++ 0.3758165E-07 0.5528280E-07 0.2214106E-02 12.1290 10 Mg++ 0.2073695E-10 0.6616685E-10 0.1607546E-05 8.8697 11 Fe++ 0.1198310E-12 0.2909433E-07 0.1623717E-02 6.6318 12 K+ 0.7106007E-04 0.7127974E-04 0.2785270E+01 5.6749 13 Na+ 0.9009032E-02 0.9459949E-02 0.2173333E+03 7.7775 14 Mn++ 0.1642492E-10 0.9318239E-09 0.5115745E-04 8.7689 15 HPO4-- 0.5034413E-06 0.5097351E-06 0.4889034E-01 13.2576 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.3046471E+00 -.9408407E-02 -.2952387E+00 0.0000000E+00 2 H2O 0.5527761E+02 0.5536998E+02 -.9236873E-01 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.5354035E-03 0.2550571E-04 0.5098978E-03 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.5098990E-03 -.1241487E-08 -.5098978E-03 0.0000000E+00 7 Al+++ 0.5999438E-01 0.3465780E-04 0.5995973E-01 0.0000000E+00 8 H4SiO4 0.1915848E+00 0.4692908E-02 0.1868919E+00 0.0000000E+00 9 Ca++ 0.2117595E-01 0.5514422E-07 0.2117589E-01 0.0000000E+00 10 Mg++ 0.1460238E-01 0.6600097E-10 0.1460238E-01 0.0000000E+00 11 Fe++ 0.1311865E-01 0.2902139E-07 0.1311862E-01 0.0000000E+00 12 K+ 0.3906369E-02 0.7110105E-04 0.3835268E-02 0.0000000E+00 13 Na+ 0.2325530E-01 0.9436234E-02 0.1381906E-01 0.0000000E+00 14 Mn++ 0.3190128E-03 0.9294879E-09 0.3190119E-03 0.0000000E+00 15 HPO4-- 0.1088775E-03 0.5084573E-06 0.1083690E-03 0.0000000E+00 Chg. balance for solid moles: -.7104E-16 Mass of aqueous solution: 0.998177E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 18.3990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 0.1374E-01 -1.862 3.603 0.557 17.94 1.383 andradite 0.1494E-02 -2.826 0.7594 -0.120 3.781 0.1973 grossular 0.7137E-04 -4.146 0.3215E-01 -1.493 0.1601 0.8945E-02 apatite-OH 0.3612E-04 -4.442 0.1815E-01 -1.741 0.9035E-01 0.5766E-02 clinochlore 0.2920E-02 -2.535 1.623 0.210 8.083 0.6175 daphnite 0.1772E-02 -2.752 1.264 0.102 6.294 0.3831 chlorite-Mn 0.6380E-04 -4.195 0.4523E-01 -1.345 0.2252 0.1441E-01 hematite 0.3061E-03 -3.514 0.4888E-01 -1.311 0.2434 0.9265E-02 microcline 0.3817E-02 -2.418 1.062 0.026 5.290 0.4150 stilbite 0.1630E-01 -1.788 11.49 1.060 57.19 5.357 stilpnomelane-Fe 0.3622E-04 -4.441 0.3905E-01 -1.408 0.1944 0.1349E-01 nontronite-Na 0.2392E-03 -3.621 0.1017 -0.993 0.5065 0.3160E-01 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.9544E+00 0.9544E+00 1.0000 -0.020 grossular 0.4558E-01 0.4558E-01 1.0000 -1.341 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.6141E+00 0.6141E+00 1.0000 -0.212 daphnite 0.3725E+00 0.3725E+00 1.0000 -0.429 chlorite-Mn 0.1342E-01 0.1342E-01 1.0000 -1.872 hematite 0.1000E+01 0.1000E+01 1.0000 0.000 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 nontronite-Na 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 20.083030 g Volume = 8.436525 cm3 Porosity: -0.9202% V(tot) - V(min): -.76925E-01 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 18.3990000 g log = 1.2648 Original solution: 1000.0103000 g Original solution / Rock added: 54.35 (Water/Rock Ratio), log = 1.7352 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0203 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.1000E+01 0.9860 0.1006E+01 0.1020E+01 CO2,gas 0.1734E-06 1.0071 0.1782E-06 0.1769E-06 CH4,gas 0.6642E-15 1.0125 0.6862E-15 0.6777E-15 H2,gas 0.2441E-05 1.0005 0.2492E-05 0.2491E-05 H2S,gas 0.1416E-13 0.9960 0.1439E-13 0.1444E-13 S2,gas 0.1226E-35 1.0000 0.1251E-35 0.1251E-35 CO,gas 0.1160E-15 1.0000 0.1183E-15 0.1183E-15 SO3,gas 0.1019E-39 1.0000 0.1040E-39 0.1040E-39 SO2,gas 0.9880E-23 1.0000 0.1008E-22 0.1008E-22 HCl,gas 0.5033E-17 1.0000 0.5135E-17 0.5135E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 16 albite -0.38 -0.38 0.00 0.000 -0.94784E-12 22 andradite 39.01 39.01 0.00 0.000 0.24265E-10 23 grossular 32.73 32.73 0.00 0.000 0.00000E+00 32 apatite-OH -18.15 -18.15 0.00 0.000 0.00000E+00 46 clinochlore 39.07 39.07 0.00 0.000 0.00000E+00 47 daphnite 28.97 28.97 0.00 0.000 -0.60662E-11 48 chlorite-Mn 46.87 46.87 0.00 0.000 0.00000E+00 90 hematite 12.57 12.57 0.00 0.000 0.30331E-11 116 microcline -2.49 -2.49 0.00 0.000 0.15165E-11 163 stilbite -7.52 -7.52 0.00 0.000 -0.90992E-11 164 stilpnomelane-Fe 13.02 13.02 0.00 0.000 -0.27298E-10 209 nontronite-Na 3.52 3.52 0.00 0.000 0.00000E+00 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -15.11 -8.45 -2.816 0.14425E+05 -6.749 3 CH4,gas 4.54 -12.32 -16.86 -4.216 0.28792E+05 -15.164 4 H2,gas 8.00 0.70 -7.30 -4.173 0.12469E+05 -5.603 5 H2S,gas -6.23 -21.77 -15.54 -7.771 0.26536E+05 -13.842 6 S2,gas -7.34 -44.94 -37.60 -5.785 0.64204E+05 -35.903 7 CO,gas 3.21 -14.41 -17.63 -5.423 0.30096E+05 -15.927 8 SO3,gas 17.12 -24.56 -41.68 -10.421 0.71171E+05 -39.983 9 SO2,gas 0.83 -23.86 -24.70 -6.585 0.42167E+05 -22.997 10 HCl,gas 5.19 -13.80 -18.99 -9.494 0.32422E+05 -17.289 11 acmite 7.71 7.40 -0.31 -0.032 0.52197E+03 15 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 19 spessartine 24.46 19.97 -4.49 -0.224 0.76641E+04 20 analcite 3.32 2.94 -0.38 -0.042 0.64447E+03 21 andalusite 5.00 0.32 -4.68 -0.468 0.79958E+04 26 annite 20.12 17.41 -2.71 -0.151 0.46351E+04 27 phlogopite 27.06 24.12 -2.94 -0.163 0.50234E+04 29 anorthite 12.71 9.12 -3.59 -0.276 0.61314E+04 35 aragonite 0.97 -2.98 -3.95 -1.315 0.67373E+04 36 brucite 12.57 8.87 -3.70 -0.740 0.63157E+04 37 calcite 0.81 -2.98 -3.79 -1.264 0.64731E+04 38 carnegieite-low 9.02 6.27 -2.75 -0.393 0.46966E+04 39 carnegieite-high 10.09 6.27 -3.82 -0.546 0.65236E+04 40 carpholite-Mg 8.58 5.86 -2.72 -0.181 0.46477E+04 41 carpholite-Fe 6.71 3.62 -3.09 -0.206 0.52769E+04 42 celadonite 5.34 3.05 -2.29 -0.135 0.39045E+04 43 celadonite-Fe 3.88 0.82 -3.06 -0.180 0.52241E+04 44 chrysotile 23.89 19.95 -3.94 -0.328 0.67272E+04 50 chloritoid-Mg 13.20 9.19 -4.01 -0.267 0.68458E+04 51 chloritoid-Fe 9.17 6.95 -2.22 -0.148 0.37960E+04 52 chloritoid-Mn 11.40 9.09 -2.31 -0.154 0.39502E+04 54 coesite -2.38 -3.33 -0.95 -0.317 0.16259E+04 59 corundum 8.38 3.65 -4.74 -0.431 0.80868E+04 61 cristobalite -2.56 -3.33 -0.77 -0.256 0.13113E+04 63 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71234E+04 65 diaspore 2.87 1.82 -1.05 -0.175 0.17932E+04 67 diopside 16.18 14.34 -1.84 -0.184 0.31405E+04 68 hedenbergite 14.21 12.10 -2.10 -0.210 0.35927E+04 75 epidote 24.67 24.20 -0.47 -0.023 0.79698E+03 76 clinozoisite 22.81 19.74 -3.06 -0.139 0.52291E+04 77 epidote-Fe 29.84 28.66 -1.18 -0.061 0.20115E+04 78 fayalite 14.05 9.94 -4.11 -0.587 0.70185E+04 79 ferrosilite 11.15 6.61 -4.54 -0.454 0.77562E+04 83 gibbsite 4.08 1.82 -2.26 -0.322 0.38517E+04 84 glaucophane 22.97 19.18 -3.79 -0.102 0.64714E+04 85 glaucophane-Fe 17.28 12.47 -4.80 -0.130 0.82041E+04 87 greenalite 16.14 13.24 -2.90 -0.242 0.49530E+04 91 heulandite -5.83 -7.52 -1.69 -0.077 0.28938E+04 95 jadeite 4.22 2.94 -1.27 -0.127 0.21700E+04 96 julgoldite 70.43 66.94 -3.48 -0.091 0.59503E+04 97 kalsilite 7.58 4.17 -3.41 -0.488 0.58290E+04 98 kaolinite -1.33 -3.01 -1.68 -0.152 0.28631E+04 99 kyanite 4.88 0.32 -4.56 -0.456 0.77817E+04 101 laumontite 2.88 2.46 -0.42 -0.028 0.71817E+03 102 lawsonite 9.62 9.12 -0.50 -0.033 0.84809E+03 103 leucite 4.12 0.84 -3.28 -0.328 0.55955E+04 105 lizardite 23.24 19.95 -3.29 -0.274 0.56199E+04 107 magnetite 20.09 19.20 -0.89 -0.073 0.15187E+04 108 minnesotaite 10.39 6.58 -3.81 -0.224 0.64986E+04 110 magnesioferrite 26.21 21.44 -4.78 -0.390 0.81558E+04 113 margarite 17.32 12.77 -4.56 -0.182 0.77814E+04 120 muscovite 2.58 1.16 -1.42 -0.084 0.24279E+04 121 paragonite 4.24 3.26 -0.98 -0.057 0.16670E+04 122 nepheline 8.34 6.27 -2.07 -0.295 0.35289E+04 128 periclase-Fe 11.63 6.63 -4.99 -1.249 0.85285E+04 134 phlogopite-Na 29.65 26.23 -3.42 -0.190 0.58422E+04 136 prehnite 19.37 17.92 -1.45 -0.085 0.24789E+04 137 prehnite-Fe 22.50 22.38 -0.12 -0.007 0.20183E+03 138 pumpellyite-Fe 46.27 44.30 -1.97 -0.044 0.33706E+04 139 pumpellyite-Mg 48.99 46.53 -2.46 -0.055 0.42031E+04 145 pyroxmangite 7.40 5.44 -1.96 -0.392 0.33434E+04 146 pyrophyllite -6.18 -9.67 -3.49 -0.218 0.59597E+04 147 quartz -2.99 -3.33 -0.34 -0.113 0.57858E+03 152 rhodonite 7.45 5.44 -2.01 -0.401 0.34236E+04 153 sanidine -1.28 -2.49 -1.21 -0.093 0.20677E+04 156 sillimanite 5.26 0.32 -4.94 -0.494 0.84397E+04 165 stilpnomelane-Mg 27.44 24.21 -3.23 -0.097 0.55233E+04 171 talc 16.49 13.30 -3.20 -0.188 0.54556E+04 174 tephroite 18.09 14.21 -3.88 -0.554 0.66187E+04 177 topaz-H 4.62 0.32 -4.30 -0.391 0.73418E+04 178 tridymite -2.63 -3.33 -0.70 -0.234 0.11986E+04 187 wairakite 3.95 2.46 -1.49 -0.088 0.25401E+04 188 walstromite 11.51 8.80 -2.71 -0.542 0.46248E+04 189 wollastonite 10.46 8.80 -1.66 -0.332 0.28352E+04 190 pseudo-wollastonite 11.00 8.80 -2.20 -0.440 0.37550E+04 191 zoisite 22.85 19.74 -3.11 -0.141 0.53032E+04 192 akaganeite 7.75 6.28 -1.47 -0.318 0.25125E+04 193 beidellite-Ca -1.65 -5.96 -4.32 -0.267 0.73749E+04 195 beidellite-K -1.52 -6.09 -4.57 -0.280 0.78085E+04 196 beidellite-Mg -1.79 -6.50 -4.71 -0.292 0.80470E+04 197 beidellite-Na -1.34 -5.40 -4.06 -0.248 0.69277E+04 199 chalcedony -2.80 -3.33 -0.53 -0.175 0.89788E+03 201 montmorillonite-Ca -2.29 -5.34 -3.05 -0.189 0.52059E+04 202 montmorillonite-K -2.24 -5.47 -3.23 -0.198 0.55177E+04 203 montmorillonite-Mg -2.48 -5.88 -3.40 -0.210 0.58012E+04 204 montmorillonite-Na -2.04 -4.77 -2.74 -0.168 0.46726E+04 205 nontronite-Ca 3.21 2.95 -0.26 -0.017 0.44418E+03 206 nontronite-H 2.53 0.95 -1.58 -0.106 0.26971E+04 207 nontronite-K 3.34 2.83 -0.51 -0.033 0.87912E+03 208 nontronite-Mg 3.07 2.42 -0.66 -0.043 0.11235E+04 224 tobermorite 9.82 6.78 -3.05 -0.832 0.52042E+04 233 boehmite 4.41 1.82 -2.58 -0.430 0.44101E+04 235 ferrous-oxide 9.81 6.63 -3.18 -0.795 0.54294E+04 240 silica-amorphous -2.09 -3.33 -1.24 -0.412 0.21121E+04 242 an20ab80 2.02 1.52 -0.50 -0.039 0.85544E+03 243 an25ab75 2.65 1.99 -0.65 -0.050 0.11163E+04 244 an30ab70 3.28 2.47 -0.81 -0.062 0.13867E+04 245 tr.625ac.25prg.125 45.16 40.56 -4.60 -0.124 0.78589E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 0.4000000 g Current total amount of reactant added: 18.3990000 g New total amount of reactant added: 18.7990000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.6634E-13 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 7 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 18.7990000 Water: Moles liquid = 0.5537E+02 kg liquid = 0.9975E+00 Moles total = 0.5527E+02 kg total = 0.9958E+00 Activity = 1.0000 Stoichiometric ionic strength = .5049934E-02 Osmotic coef. = 0.9622 True ionic strength = .9112631E-02 Chg. balance for total moles = 0.6634E-13 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.14989E-09 -9.8242 0.13154E-09 -9.8809 0.87760E+00 -0.0567 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13801E-03 -3.8601 0.12074E-03 -3.9182 0.87483E+00 -0.0581 4 SO4-- 0.25552E-04 -4.5926 0.15893E-04 -4.7988 0.62199E+00 -0.2062 5 HCO3- 0.67679E-05 -5.1695 0.59252E-05 -5.2273 0.87549E+00 -0.0577 6 HS- 0.14714E-11 -11.8323 0.12873E-11 -11.8903 0.87489E+00 -0.0580 7 Al+++ 0.43449E-27 -27.3620 0.15160E-27 -27.8193 0.34890E+00 -0.4573 8 H4SiO4 0.46958E-03 -3.3283 0.46958E-03 -3.3283 0.10000E+01 0.0000 9 Ca++ 0.37582E-07 -7.4250 0.23286E-07 -7.6329 0.61961E+00 -0.2079 10 Mg++ 0.20737E-10 -10.6833 0.12818E-10 -10.8922 0.61813E+00 -0.2089 11 Fe++ 0.11983E-12 -12.9214 0.74113E-13 -13.1301 0.61848E+00 -0.2087 12 K+ 0.71060E-04 -4.1484 0.62221E-04 -4.2061 0.87561E+00 -0.0577 13 Na+ 0.90090E-02 -2.0453 0.78807E-02 -2.1034 0.87475E+00 -0.0581 14 Mn++ 0.16425E-10 -10.7845 0.10163E-10 -10.9930 0.61875E+00 -0.2085 15 HPO4-- 0.50344E-06 -6.2981 0.31316E-06 -6.5042 0.62203E+00 -0.2062 16 HSiO3- 0.38103E-02 -2.4190 0.33333E-02 -2.4771 0.87483E+00 -0.0581 17 Ca(HSiO3)+ 0.20186E-08 -8.6950 0.17677E-08 -8.7526 0.87571E+00 -0.0576 18 Mg(HSiO3)+ 0.13828E-11 -11.8592 0.12110E-11 -11.9169 0.87571E+00 -0.0576 19 NaHSiO3,aq 0.42486E-03 -3.3718 0.42486E-03 -3.3718 0.10000E+01 0.0000 20 AlO+ 0.13610E-14 -14.8661 0.11919E-14 -14.9238 0.87571E+00 -0.0576 22 HAlO2,aq 0.18044E-08 -8.7437 0.18044E-08 -8.7437 0.10000E+01 0.0000 23 AlO2- 0.34743E-04 -4.4591 0.30365E-04 -4.5176 0.87399E+00 -0.0585 24 CH4,aq 0.46693E-18 -18.3308 0.46620E-18 -18.3314 0.99844E+00 -0.0007 29 CO,aq 0.79414E-19 -19.1001 0.79414E-19 -19.1001 0.10000E+01 0.0000 30 CO2,aq 0.16680E-08 -8.7778 0.16654E-08 -8.7785 0.99844E+00 -0.0007 31 CO3-2 0.63327E-05 -5.1984 0.39344E-05 -5.4051 0.62129E+00 -0.2067 32 CaCO3,aq 0.11488E-08 -8.9398 0.11488E-08 -8.9398 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.40218E-11 -11.3956 0.35220E-11 -11.4532 0.87571E+00 -0.0576 34 CaCl+ 0.51956E-11 -11.2844 0.45498E-11 -11.3420 0.87571E+00 -0.0576 35 CaCl2,aq 0.13051E-15 -15.8844 0.13051E-15 -15.8844 0.10000E+01 0.0000 36 CaOH+ 0.14407E-07 -7.8414 0.12616E-07 -7.8991 0.87571E+00 -0.0576 37 CaSO4,aq 0.11752E-09 -9.9299 0.11752E-09 -9.9299 0.10000E+01 0.0000 38 HCl,aq 0.29103E-14 -14.5361 0.29103E-14 -14.5361 0.10000E+01 0.0000 43 FeCl+ 0.16174E-16 -16.7912 0.14163E-16 -16.8488 0.87571E+00 -0.0576 46 FeO,aq 0.16647E-09 -9.7787 0.16647E-09 -9.7787 0.10000E+01 0.0000 47 FeOH+ 0.20943E-10 -10.6790 0.18340E-10 -10.7366 0.87571E+00 -0.0576 48 HFeO2- 0.15136E-07 -7.8200 0.13241E-07 -7.8781 0.87483E+00 -0.0581 49 FeO+ 0.11466E-14 -14.9406 0.10040E-14 -14.9982 0.87571E+00 -0.0576 51 FeO2- 0.13572E-07 -7.8673 0.11873E-07 -7.9254 0.87483E+00 -0.0581 52 HFeO2,aq 0.19864E-09 -9.7019 0.19864E-09 -9.7019 0.10000E+01 0.0000 53 H2,aq 0.19011E-08 -8.7210 0.18982E-08 -8.7217 0.99844E+00 -0.0007 54 KCl,aq 0.13615E-09 -9.8660 0.13615E-09 -9.8660 0.10000E+01 0.0000 55 KHSO4,aq 0.36778E-18 -18.4344 0.36778E-18 -18.4344 0.10000E+01 0.0000 56 KOH,aq 0.20200E-06 -6.6946 0.20200E-06 -6.6946 0.10000E+01 0.0000 57 KSO4- 0.17541E-07 -7.7560 0.15345E-07 -7.8140 0.87483E+00 -0.0581 58 MgCO3,aq 0.15851E-12 -12.8000 0.15851E-12 -12.8000 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.22622E-14 -14.6455 0.19810E-14 -14.7031 0.87571E+00 -0.0576 60 MgCl+ 0.25921E-14 -14.5863 0.22699E-14 -14.6440 0.87571E+00 -0.0576 61 MgOH+ 0.43884E-10 -10.3577 0.38429E-10 -10.4153 0.87571E+00 -0.0576 63 MnO,aq 0.60825E-09 -9.2159 0.60825E-09 -9.2159 0.10000E+01 0.0000 64 MnOH+ 0.26678E-09 -9.5738 0.23363E-09 -9.6315 0.87571E+00 -0.0576 65 MnO2-2 0.18777E-11 -11.7264 0.11666E-11 -11.9331 0.62129E+00 -0.2067 66 HMnO2- 0.38431E-10 -10.4153 0.33620E-10 -10.4734 0.87483E+00 -0.0581 69 MnCl+ 0.86284E-14 -14.0641 0.75560E-14 -14.1217 0.87571E+00 -0.0576 70 MnSO4,aq 0.46629E-13 -13.3313 0.46629E-13 -13.3313 0.10000E+01 0.0000 71 NaCl,aq 0.31532E-06 -6.5012 0.31532E-06 -6.5012 0.10000E+01 0.0000 72 NaOH,aq 0.25740E-04 -4.5894 0.25740E-04 -4.5894 0.10000E+01 0.0000 74 OH- 0.50256E-02 -2.2988 0.43923E-02 -2.3573 0.87399E+00 -0.0585 79 HPO3-2 0.29816E-17 -17.5256 0.18524E-17 -17.7323 0.62129E+00 -0.2067 82 H3PO4,aq 0.37898E-16 -16.4214 0.37898E-16 -16.4214 0.10000E+01 0.0000 83 H2PO4- 0.86821E-09 -9.0614 0.75990E-09 -9.1192 0.87526E+00 -0.0579 84 PO4-3 0.54256E-08 -8.2656 0.19424E-08 -8.7117 0.35800E+00 -0.4461 87 H2P2O7-2 0.72878E-19 -19.1374 0.45278E-19 -19.3441 0.62129E+00 -0.2067 88 HP2O7-3 0.19691E-15 -15.7057 0.68731E-16 -16.1628 0.34904E+00 -0.4571 89 P2O7-4 0.78873E-15 -15.1031 0.12482E-15 -15.9037 0.15826E+00 -0.8006 90 H2S,aq 0.52417E-15 -15.2805 0.52335E-15 -15.2812 0.99844E+00 -0.0007 97 SO3-2 0.62623E-14 -14.2033 0.39203E-14 -14.4067 0.62601E+00 -0.2034 98 HSO3- 0.36908E-16 -16.4329 0.32288E-16 -16.4910 0.87483E+00 -0.0581 99 HSO4- 0.22995E-11 -11.6384 0.20147E-11 -11.6958 0.87615E+00 -0.0574 Charge balance for all species = 0.6504E-13 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.1498885E-09 -.9432049E-02 -.9500424E+01 0.0000 2 H2O 0.1000000E+01 0.5550914E+02 0.9993284E+06 0.0000 3 Cl- 0.1380110E-03 0.1383265E-03 0.4900728E+01 5.9628 4 SO4-- 0.2555193E-04 0.2557084E-04 0.2454692E+01 14.9631 5 HCO3- 0.6767872E-05 0.1310337E-04 0.7989832E+00 4.6536 6 HS- 0.1471395E-11 -.1244607E-08 -.4113342E-04 -2.0094 7 Al+++ 0.4344916E-27 0.3474489E-04 0.9368268E+00 1.8235 8 H4SiO4 0.4695843E-03 0.4704701E-02 0.4518843E+03 -3.3283 9 Ca++ 0.3758169E-07 0.5528290E-07 0.2214110E-02 12.1290 10 Mg++ 0.2073698E-10 0.6616690E-10 0.1607547E-05 8.8697 11 Fe++ 0.1198311E-12 0.2909432E-07 0.1623717E-02 6.6318 12 K+ 0.7106010E-04 0.7127978E-04 0.2785272E+01 5.6749 13 Na+ 0.9009037E-02 0.9459953E-02 0.2173334E+03 7.7775 14 Mn++ 0.1642494E-10 0.9318240E-09 0.5115746E-04 8.7689 15 HPO4-- 0.5034409E-06 0.5097347E-06 0.4889030E-01 13.2576 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.3112705E+00 -.9408026E-02 -.3018625E+00 0.0000000E+00 2 H2O 0.5527260E+02 0.5536776E+02 -.9515861E-01 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.5464888E-03 0.2550571E-04 0.5209831E-03 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.5209844E-03 -.1241437E-08 -.5209831E-03 0.0000000E+00 7 Al+++ 0.6129868E-01 0.3465640E-04 0.6126403E-01 0.0000000E+00 8 H4SiO4 0.1957499E+00 0.4692718E-02 0.1910572E+00 0.0000000E+00 9 Ca++ 0.2163600E-01 0.5514210E-07 0.2163595E-01 0.0000000E+00 10 Mg++ 0.1491984E-01 0.6599837E-10 0.1491984E-01 0.0000000E+00 11 Fe++ 0.1340385E-01 0.2902021E-07 0.1340382E-01 0.0000000E+00 12 K+ 0.3991295E-02 0.7109823E-04 0.3920197E-02 0.0000000E+00 13 Na+ 0.2375740E-01 0.9435859E-02 0.1432154E-01 0.0000000E+00 14 Mn++ 0.3259483E-03 0.9294507E-09 0.3259473E-03 0.0000000E+00 15 HPO4-- 0.1112445E-03 0.5084364E-06 0.1107361E-03 0.0000000E+00 Chg. balance for solid moles: -.4380E-16 Mass of aqueous solution: 0.998137E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 18.7990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 0.1423E-01 -1.847 3.731 0.572 18.18 1.432 andradite 0.1559E-02 -2.807 0.7925 -0.101 3.862 0.2059 grossular 0.7448E-04 -4.128 0.3355E-01 -1.474 0.1635 0.9335E-02 apatite-OH 0.3691E-04 -4.433 0.1854E-01 -1.732 0.9036E-01 0.5892E-02 clinochlore 0.2984E-02 -2.525 1.659 0.220 8.083 0.6309 daphnite 0.1810E-02 -2.742 1.292 0.111 6.294 0.3914 chlorite-Mn 0.6519E-04 -4.186 0.4622E-01 -1.335 0.2252 0.1473E-01 hematite 0.2392E-03 -3.621 0.3820E-01 -1.418 0.1861 0.7240E-02 microcline 0.3902E-02 -2.409 1.086 0.036 5.292 0.4242 stilbite 0.1655E-01 -1.781 11.66 1.067 56.84 5.440 stilpnomelane-Fe 0.3701E-04 -4.432 0.3989E-01 -1.399 0.1944 0.1378E-01 nontronite-Na 0.2853E-03 -3.545 0.1213 -0.916 0.5913 0.3769E-01 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.9544E+00 0.9544E+00 1.0000 -0.020 grossular 0.4558E-01 0.4558E-01 1.0000 -1.341 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.6141E+00 0.6141E+00 1.0000 -0.212 daphnite 0.3725E+00 0.3725E+00 1.0000 -0.429 chlorite-Mn 0.1342E-01 0.1342E-01 1.0000 -1.872 hematite 0.1000E+01 0.1000E+01 1.0000 0.000 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 nontronite-Na 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 20.519890 g Volume = 8.612922 cm3 Porosity: -1.0954% V(tot) - V(min): -.93322E-01 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 18.7990000 g log = 1.2741 Original solution: 1000.0103000 g Original solution / Rock added: 53.19 (Water/Rock Ratio), log = 1.7259 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0203 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.1000E+01 0.9860 0.1006E+01 0.1020E+01 CO2,gas 0.1734E-06 1.0071 0.1782E-06 0.1769E-06 CH4,gas 0.6642E-15 1.0125 0.6862E-15 0.6777E-15 H2,gas 0.2441E-05 1.0005 0.2492E-05 0.2491E-05 H2S,gas 0.1416E-13 0.9960 0.1439E-13 0.1444E-13 S2,gas 0.1226E-35 1.0000 0.1251E-35 0.1251E-35 CO,gas 0.1160E-15 1.0000 0.1183E-15 0.1183E-15 SO3,gas 0.1019E-39 1.0000 0.1040E-39 0.1040E-39 SO2,gas 0.9881E-23 1.0000 0.1008E-22 0.1008E-22 HCl,gas 0.5033E-17 1.0000 0.5135E-17 0.5135E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 16 albite -0.38 -0.38 0.00 0.000 0.11184E-10 22 andradite 39.01 39.01 0.00 0.000 0.12132E-10 23 grossular 32.73 32.73 0.00 0.000 0.12132E-10 32 apatite-OH -18.15 -18.15 0.00 0.000 -0.60662E-11 46 clinochlore 39.07 39.07 0.00 0.000 -0.12132E-10 47 daphnite 28.97 28.97 0.00 0.000 -0.18198E-10 48 chlorite-Mn 46.87 46.87 0.00 0.000 0.00000E+00 90 hematite 12.57 12.57 0.00 0.000 -0.30331E-11 116 microcline -2.49 -2.49 0.00 0.000 0.15165E-11 163 stilbite -7.52 -7.52 0.00 0.000 0.15165E-10 164 stilpnomelane-Fe 13.02 13.02 0.00 0.000 -0.27298E-10 209 nontronite-Na 3.52 3.52 0.00 0.000 -0.98575E-11 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -15.11 -8.45 -2.816 0.14425E+05 -6.749 3 CH4,gas 4.54 -12.32 -16.86 -4.216 0.28792E+05 -15.164 4 H2,gas 8.00 0.70 -7.30 -4.173 0.12469E+05 -5.603 5 H2S,gas -6.23 -21.77 -15.54 -7.771 0.26536E+05 -13.842 6 S2,gas -7.34 -44.94 -37.60 -5.785 0.64204E+05 -35.903 7 CO,gas 3.21 -14.41 -17.63 -5.423 0.30096E+05 -15.927 8 SO3,gas 17.12 -24.56 -41.68 -10.421 0.71171E+05 -39.983 9 SO2,gas 0.83 -23.86 -24.70 -6.585 0.42167E+05 -22.996 10 HCl,gas 5.19 -13.80 -18.99 -9.494 0.32422E+05 -17.289 11 acmite 7.71 7.40 -0.31 -0.032 0.52197E+03 15 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 19 spessartine 24.46 19.97 -4.49 -0.224 0.76641E+04 20 analcite 3.32 2.94 -0.38 -0.042 0.64447E+03 21 andalusite 5.00 0.32 -4.68 -0.468 0.79958E+04 26 annite 20.12 17.41 -2.71 -0.151 0.46351E+04 27 phlogopite 27.06 24.12 -2.94 -0.163 0.50234E+04 29 anorthite 12.71 9.12 -3.59 -0.276 0.61314E+04 35 aragonite 0.97 -2.98 -3.95 -1.315 0.67373E+04 36 brucite 12.57 8.87 -3.70 -0.740 0.63157E+04 37 calcite 0.81 -2.98 -3.79 -1.264 0.64731E+04 38 carnegieite-low 9.02 6.27 -2.75 -0.393 0.46966E+04 39 carnegieite-high 10.09 6.27 -3.82 -0.546 0.65236E+04 40 carpholite-Mg 8.58 5.86 -2.72 -0.181 0.46477E+04 41 carpholite-Fe 6.71 3.62 -3.09 -0.206 0.52769E+04 42 celadonite 5.34 3.05 -2.29 -0.135 0.39045E+04 43 celadonite-Fe 3.88 0.82 -3.06 -0.180 0.52241E+04 44 chrysotile 23.89 19.95 -3.94 -0.328 0.67272E+04 50 chloritoid-Mg 13.20 9.19 -4.01 -0.267 0.68458E+04 51 chloritoid-Fe 9.17 6.95 -2.22 -0.148 0.37960E+04 52 chloritoid-Mn 11.40 9.09 -2.31 -0.154 0.39502E+04 54 coesite -2.38 -3.33 -0.95 -0.317 0.16259E+04 59 corundum 8.38 3.65 -4.74 -0.431 0.80868E+04 61 cristobalite -2.56 -3.33 -0.77 -0.256 0.13113E+04 63 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71234E+04 65 diaspore 2.87 1.82 -1.05 -0.175 0.17932E+04 67 diopside 16.18 14.34 -1.84 -0.184 0.31405E+04 68 hedenbergite 14.21 12.10 -2.10 -0.210 0.35927E+04 75 epidote 24.67 24.20 -0.47 -0.023 0.79698E+03 76 clinozoisite 22.81 19.74 -3.06 -0.139 0.52291E+04 77 epidote-Fe 29.84 28.66 -1.18 -0.061 0.20115E+04 78 fayalite 14.05 9.94 -4.11 -0.587 0.70185E+04 79 ferrosilite 11.15 6.61 -4.54 -0.454 0.77562E+04 83 gibbsite 4.08 1.82 -2.26 -0.322 0.38517E+04 84 glaucophane 22.97 19.18 -3.79 -0.102 0.64714E+04 85 glaucophane-Fe 17.28 12.47 -4.80 -0.130 0.82041E+04 87 greenalite 16.14 13.24 -2.90 -0.242 0.49530E+04 91 heulandite -5.83 -7.52 -1.69 -0.077 0.28938E+04 95 jadeite 4.22 2.94 -1.27 -0.127 0.21700E+04 96 julgoldite 70.43 66.94 -3.48 -0.091 0.59503E+04 97 kalsilite 7.58 4.17 -3.41 -0.488 0.58290E+04 98 kaolinite -1.33 -3.01 -1.68 -0.152 0.28631E+04 99 kyanite 4.88 0.32 -4.56 -0.456 0.77817E+04 101 laumontite 2.88 2.46 -0.42 -0.028 0.71817E+03 102 lawsonite 9.62 9.12 -0.50 -0.033 0.84809E+03 103 leucite 4.12 0.84 -3.28 -0.328 0.55955E+04 105 lizardite 23.24 19.95 -3.29 -0.274 0.56199E+04 107 magnetite 20.09 19.20 -0.89 -0.073 0.15187E+04 108 minnesotaite 10.39 6.58 -3.81 -0.224 0.64986E+04 110 magnesioferrite 26.21 21.44 -4.78 -0.390 0.81558E+04 113 margarite 17.32 12.77 -4.56 -0.182 0.77814E+04 120 muscovite 2.58 1.16 -1.42 -0.084 0.24279E+04 121 paragonite 4.24 3.26 -0.98 -0.057 0.16670E+04 122 nepheline 8.34 6.27 -2.07 -0.295 0.35289E+04 128 periclase-Fe 11.63 6.63 -4.99 -1.249 0.85285E+04 134 phlogopite-Na 29.65 26.23 -3.42 -0.190 0.58422E+04 136 prehnite 19.37 17.92 -1.45 -0.085 0.24789E+04 137 prehnite-Fe 22.50 22.38 -0.12 -0.007 0.20183E+03 138 pumpellyite-Fe 46.27 44.30 -1.97 -0.044 0.33706E+04 139 pumpellyite-Mg 48.99 46.53 -2.46 -0.055 0.42031E+04 145 pyroxmangite 7.40 5.44 -1.96 -0.392 0.33434E+04 146 pyrophyllite -6.18 -9.67 -3.49 -0.218 0.59597E+04 147 quartz -2.99 -3.33 -0.34 -0.113 0.57858E+03 152 rhodonite 7.45 5.44 -2.01 -0.401 0.34236E+04 153 sanidine -1.28 -2.49 -1.21 -0.093 0.20677E+04 156 sillimanite 5.26 0.32 -4.94 -0.494 0.84397E+04 165 stilpnomelane-Mg 27.44 24.21 -3.23 -0.097 0.55233E+04 171 talc 16.49 13.30 -3.20 -0.188 0.54556E+04 174 tephroite 18.09 14.21 -3.88 -0.554 0.66187E+04 177 topaz-H 4.62 0.32 -4.30 -0.391 0.73418E+04 178 tridymite -2.63 -3.33 -0.70 -0.234 0.11986E+04 187 wairakite 3.95 2.46 -1.49 -0.088 0.25401E+04 188 walstromite 11.51 8.80 -2.71 -0.542 0.46248E+04 189 wollastonite 10.46 8.80 -1.66 -0.332 0.28352E+04 190 pseudo-wollastonite 11.00 8.80 -2.20 -0.440 0.37550E+04 191 zoisite 22.85 19.74 -3.11 -0.141 0.53032E+04 192 akaganeite 7.75 6.28 -1.47 -0.318 0.25125E+04 193 beidellite-Ca -1.65 -5.96 -4.32 -0.267 0.73749E+04 195 beidellite-K -1.52 -6.09 -4.57 -0.280 0.78085E+04 196 beidellite-Mg -1.79 -6.50 -4.71 -0.292 0.80470E+04 197 beidellite-Na -1.34 -5.40 -4.06 -0.248 0.69277E+04 199 chalcedony -2.80 -3.33 -0.53 -0.175 0.89788E+03 201 montmorillonite-Ca -2.29 -5.34 -3.05 -0.189 0.52059E+04 202 montmorillonite-K -2.24 -5.47 -3.23 -0.198 0.55177E+04 203 montmorillonite-Mg -2.48 -5.88 -3.40 -0.210 0.58012E+04 204 montmorillonite-Na -2.04 -4.77 -2.74 -0.168 0.46726E+04 205 nontronite-Ca 3.21 2.95 -0.26 -0.017 0.44418E+03 206 nontronite-H 2.53 0.95 -1.58 -0.106 0.26971E+04 207 nontronite-K 3.34 2.83 -0.51 -0.033 0.87912E+03 208 nontronite-Mg 3.07 2.42 -0.66 -0.043 0.11235E+04 224 tobermorite 9.82 6.78 -3.05 -0.832 0.52042E+04 233 boehmite 4.41 1.82 -2.58 -0.430 0.44101E+04 235 ferrous-oxide 9.81 6.63 -3.18 -0.795 0.54294E+04 240 silica-amorphous -2.09 -3.33 -1.24 -0.412 0.21121E+04 242 an20ab80 2.02 1.52 -0.50 -0.039 0.85544E+03 243 an25ab75 2.65 1.99 -0.65 -0.050 0.11163E+04 244 an30ab70 3.28 2.47 -0.81 -0.062 0.13867E+04 245 tr.625ac.25prg.125 45.16 40.56 -4.60 -0.124 0.78589E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 0.4000000 g Current total amount of reactant added: 18.7990000 g New total amount of reactant added: 19.1990000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.6634E-13 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 7 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 19.1990000 Water: Moles liquid = 0.5536E+02 kg liquid = 0.9974E+00 Moles total = 0.5527E+02 kg total = 0.9957E+00 Activity = 1.0000 Stoichiometric ionic strength = .5049942E-02 Osmotic coef. = 0.9622 True ionic strength = .9112637E-02 Chg. balance for total moles = 0.6634E-13 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.14989E-09 -9.8242 0.13154E-09 -9.8809 0.87760E+00 -0.0567 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13802E-03 -3.8601 0.12074E-03 -3.9181 0.87483E+00 -0.0581 4 SO4-- 0.25553E-04 -4.5926 0.15894E-04 -4.7988 0.62199E+00 -0.2062 5 HCO3- 0.67681E-05 -5.1695 0.59255E-05 -5.2273 0.87549E+00 -0.0577 6 HS- 0.14715E-11 -11.8323 0.12874E-11 -11.8903 0.87489E+00 -0.0580 7 Al+++ 0.43449E-27 -27.3620 0.15160E-27 -27.8193 0.34890E+00 -0.4573 8 H4SiO4 0.46958E-03 -3.3283 0.46958E-03 -3.3283 0.10000E+01 0.0000 9 Ca++ 0.37582E-07 -7.4250 0.23286E-07 -7.6329 0.61961E+00 -0.2079 10 Mg++ 0.20737E-10 -10.6833 0.12818E-10 -10.8922 0.61813E+00 -0.2089 11 Fe++ 0.11983E-12 -12.9214 0.74113E-13 -13.1301 0.61848E+00 -0.2087 12 K+ 0.71060E-04 -4.1484 0.62221E-04 -4.2061 0.87561E+00 -0.0577 13 Na+ 0.90090E-02 -2.0453 0.78807E-02 -2.1034 0.87475E+00 -0.0581 14 Mn++ 0.16425E-10 -10.7845 0.10163E-10 -10.9930 0.61875E+00 -0.2085 15 HPO4-- 0.50344E-06 -6.2981 0.31316E-06 -6.5042 0.62203E+00 -0.2062 16 HSiO3- 0.38103E-02 -2.4190 0.33333E-02 -2.4771 0.87483E+00 -0.0581 17 Ca(HSiO3)+ 0.20186E-08 -8.6950 0.17677E-08 -8.7526 0.87571E+00 -0.0576 18 Mg(HSiO3)+ 0.13828E-11 -11.8592 0.12110E-11 -11.9169 0.87571E+00 -0.0576 19 NaHSiO3,aq 0.42486E-03 -3.3718 0.42486E-03 -3.3718 0.10000E+01 0.0000 20 AlO+ 0.13610E-14 -14.8661 0.11919E-14 -14.9238 0.87571E+00 -0.0576 22 HAlO2,aq 0.18044E-08 -8.7437 0.18044E-08 -8.7437 0.10000E+01 0.0000 23 AlO2- 0.34743E-04 -4.4591 0.30365E-04 -4.5176 0.87399E+00 -0.0585 24 CH4,aq 0.46695E-18 -18.3307 0.46622E-18 -18.3314 0.99844E+00 -0.0007 29 CO,aq 0.79417E-19 -19.1001 0.79417E-19 -19.1001 0.10000E+01 0.0000 30 CO2,aq 0.16681E-08 -8.7778 0.16655E-08 -8.7785 0.99844E+00 -0.0007 31 CO3-2 0.63329E-05 -5.1984 0.39346E-05 -5.4051 0.62129E+00 -0.2067 32 CaCO3,aq 0.11488E-08 -8.9397 0.11488E-08 -8.9397 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.40220E-11 -11.3956 0.35221E-11 -11.4532 0.87571E+00 -0.0576 34 CaCl+ 0.51958E-11 -11.2843 0.45500E-11 -11.3420 0.87571E+00 -0.0576 35 CaCl2,aq 0.13052E-15 -15.8843 0.13052E-15 -15.8843 0.10000E+01 0.0000 36 CaOH+ 0.14407E-07 -7.8414 0.12616E-07 -7.8991 0.87571E+00 -0.0576 37 CaSO4,aq 0.11752E-09 -9.9299 0.11752E-09 -9.9299 0.10000E+01 0.0000 38 HCl,aq 0.29104E-14 -14.5360 0.29104E-14 -14.5360 0.10000E+01 0.0000 43 FeCl+ 0.16174E-16 -16.7912 0.14164E-16 -16.8488 0.87571E+00 -0.0576 46 FeO,aq 0.16647E-09 -9.7787 0.16647E-09 -9.7787 0.10000E+01 0.0000 47 FeOH+ 0.20943E-10 -10.6790 0.18340E-10 -10.7366 0.87571E+00 -0.0576 48 HFeO2- 0.15136E-07 -7.8200 0.13241E-07 -7.8781 0.87483E+00 -0.0581 49 FeO+ 0.11466E-14 -14.9406 0.10040E-14 -14.9982 0.87571E+00 -0.0576 51 FeO2- 0.13572E-07 -7.8673 0.11873E-07 -7.9254 0.87483E+00 -0.0581 52 HFeO2,aq 0.19864E-09 -9.7019 0.19864E-09 -9.7019 0.10000E+01 0.0000 53 H2,aq 0.19011E-08 -8.7210 0.18982E-08 -8.7217 0.99844E+00 -0.0007 54 KCl,aq 0.13616E-09 -9.8660 0.13616E-09 -9.8660 0.10000E+01 0.0000 55 KHSO4,aq 0.36780E-18 -18.4344 0.36780E-18 -18.4344 0.10000E+01 0.0000 56 KOH,aq 0.20200E-06 -6.6946 0.20200E-06 -6.6946 0.10000E+01 0.0000 57 KSO4- 0.17541E-07 -7.7559 0.15346E-07 -7.8140 0.87483E+00 -0.0581 58 MgCO3,aq 0.15851E-12 -12.7999 0.15851E-12 -12.7999 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.22623E-14 -14.6455 0.19811E-14 -14.7031 0.87571E+00 -0.0576 60 MgCl+ 0.25922E-14 -14.5863 0.22700E-14 -14.6440 0.87571E+00 -0.0576 61 MgOH+ 0.43884E-10 -10.3577 0.38429E-10 -10.4153 0.87571E+00 -0.0576 63 MnO,aq 0.60825E-09 -9.2159 0.60825E-09 -9.2159 0.10000E+01 0.0000 64 MnOH+ 0.26678E-09 -9.5738 0.23363E-09 -9.6315 0.87571E+00 -0.0576 65 MnO2-2 0.18777E-11 -11.7264 0.11666E-11 -11.9331 0.62129E+00 -0.2067 66 HMnO2- 0.38431E-10 -10.4153 0.33620E-10 -10.4734 0.87483E+00 -0.0581 69 MnCl+ 0.86288E-14 -14.0641 0.75563E-14 -14.1217 0.87571E+00 -0.0576 70 MnSO4,aq 0.46631E-13 -13.3313 0.46631E-13 -13.3313 0.10000E+01 0.0000 71 NaCl,aq 0.31534E-06 -6.5012 0.31534E-06 -6.5012 0.10000E+01 0.0000 72 NaOH,aq 0.25740E-04 -4.5894 0.25740E-04 -4.5894 0.10000E+01 0.0000 74 OH- 0.50256E-02 -2.2988 0.43923E-02 -2.3573 0.87399E+00 -0.0585 79 HPO3-2 0.29816E-17 -17.5256 0.18524E-17 -17.7323 0.62129E+00 -0.2067 82 H3PO4,aq 0.37898E-16 -16.4214 0.37898E-16 -16.4214 0.10000E+01 0.0000 83 H2PO4- 0.86821E-09 -9.0614 0.75990E-09 -9.1192 0.87526E+00 -0.0579 84 PO4-3 0.54256E-08 -8.2656 0.19424E-08 -8.7117 0.35800E+00 -0.4461 87 H2P2O7-2 0.72878E-19 -19.1374 0.45278E-19 -19.3441 0.62129E+00 -0.2067 88 HP2O7-3 0.19691E-15 -15.7057 0.68731E-16 -16.1628 0.34904E+00 -0.4571 89 P2O7-4 0.78873E-15 -15.1031 0.12482E-15 -15.9037 0.15826E+00 -0.8006 90 H2S,aq 0.52419E-15 -15.2805 0.52337E-15 -15.2812 0.99844E+00 -0.0007 97 SO3-2 0.62626E-14 -14.2032 0.39204E-14 -14.4067 0.62601E+00 -0.2034 98 HSO3- 0.36909E-16 -16.4329 0.32289E-16 -16.4909 0.87483E+00 -0.0581 99 HSO4- 0.22996E-11 -11.6383 0.20148E-11 -11.6958 0.87615E+00 -0.0574 Charge balance for all species = 0.6517E-13 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.1498885E-09 -.9432045E-02 -.9500420E+01 0.0000 2 H2O 0.1000000E+01 0.5550914E+02 0.9993284E+06 0.0000 3 Cl- 0.1380166E-03 0.1383321E-03 0.4900925E+01 5.9628 4 SO4-- 0.2555296E-04 0.2557187E-04 0.2454791E+01 14.9631 5 HCO3- 0.6768146E-05 0.1310390E-04 0.7990153E+00 4.6537 6 HS- 0.1471455E-11 -.1244606E-08 -.4113340E-04 -2.0094 7 Al+++ 0.4344923E-27 0.3474488E-04 0.9368264E+00 1.8235 8 H4SiO4 0.4695843E-03 0.4704699E-02 0.4518841E+03 -3.3283 9 Ca++ 0.3758173E-07 0.5528300E-07 0.2214114E-02 12.1290 10 Mg++ 0.2073700E-10 0.6616695E-10 0.1607548E-05 8.8697 11 Fe++ 0.1198312E-12 0.2909430E-07 0.1623716E-02 6.6318 12 K+ 0.7106014E-04 0.7127982E-04 0.2785273E+01 5.6749 13 Na+ 0.9009041E-02 0.9459958E-02 0.2173335E+03 7.7775 14 Mn++ 0.1642496E-10 0.9318242E-09 0.5115747E-04 8.7689 15 HPO4-- 0.5034405E-06 0.5097343E-06 0.4889026E-01 13.2576 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.3178939E+00 -.9407644E-02 -.3084863E+00 0.0000000E+00 2 H2O 0.5526758E+02 0.5536553E+02 -.9794850E-01 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.5575742E-03 0.2550571E-04 0.5320685E-03 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.5320697E-03 -.1241386E-08 -.5320685E-03 0.0000000E+00 7 Al+++ 0.6260298E-01 0.3465499E-04 0.6256832E-01 0.0000000E+00 8 H4SiO4 0.1999150E+00 0.4692528E-02 0.1952225E+00 0.0000000E+00 9 Ca++ 0.2209606E-01 0.5513999E-07 0.2209600E-01 0.0000000E+00 10 Mg++ 0.1523730E-01 0.6599577E-10 0.1523730E-01 0.0000000E+00 11 Fe++ 0.1368905E-01 0.2901904E-07 0.1368902E-01 0.0000000E+00 12 K+ 0.4076221E-02 0.7109541E-04 0.4005125E-02 0.0000000E+00 13 Na+ 0.2425949E-01 0.9435485E-02 0.1482401E-01 0.0000000E+00 14 Mn++ 0.3328837E-03 0.9294136E-09 0.3328828E-03 0.0000000E+00 15 HPO4-- 0.1136116E-03 0.5084156E-06 0.1131031E-03 0.0000000E+00 Chg. balance for solid moles: 0.3217E-16 Mass of aqueous solution: 0.998097E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 19.1990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 0.1471E-01 -1.832 3.858 0.586 18.41 1.481 andradite 0.1625E-02 -2.789 0.8256 -0.083 3.939 0.2145 grossular 0.7759E-04 -4.110 0.3495E-01 -1.457 0.1668 0.9725E-02 apatite-OH 0.3770E-04 -4.424 0.1894E-01 -1.723 0.9037E-01 0.6018E-02 clinochlore 0.3047E-02 -2.516 1.694 0.229 8.083 0.6443 daphnite 0.1849E-02 -2.733 1.319 0.120 6.294 0.3997 chlorite-Mn 0.6658E-04 -4.177 0.4720E-01 -1.326 0.2252 0.1504E-01 hematite 0.1723E-03 -3.764 0.2751E-01 -1.561 0.1313 0.5214E-02 microcline 0.3986E-02 -2.399 1.110 0.045 5.294 0.4334 stilbite 0.1680E-01 -1.775 11.84 1.073 56.50 5.522 stilpnomelane-Fe 0.3780E-04 -4.423 0.4074E-01 -1.390 0.1944 0.1407E-01 nontronite-Na 0.3314E-03 -3.480 0.1409 -0.851 0.6725 0.4378E-01 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.9544E+00 0.9544E+00 1.0000 -0.020 grossular 0.4558E-01 0.4558E-01 1.0000 -1.341 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.6141E+00 0.6141E+00 1.0000 -0.212 daphnite 0.3725E+00 0.3725E+00 1.0000 -0.429 chlorite-Mn 0.1342E-01 0.1342E-01 1.0000 -1.872 hematite 0.1000E+01 0.1000E+01 1.0000 0.000 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 nontronite-Na 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 20.956750 g Volume = 8.789319 cm3 Porosity: -1.2641% V(tot) - V(min): -.10972E+00 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 19.1990000 g log = 1.2833 Original solution: 1000.0103000 g Original solution / Rock added: 52.09 (Water/Rock Ratio), log = 1.7167 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0203 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.1000E+01 0.9860 0.1006E+01 0.1020E+01 CO2,gas 0.1734E-06 1.0071 0.1782E-06 0.1769E-06 CH4,gas 0.6643E-15 1.0125 0.6862E-15 0.6778E-15 H2,gas 0.2441E-05 1.0005 0.2492E-05 0.2491E-05 H2S,gas 0.1416E-13 0.9960 0.1439E-13 0.1444E-13 S2,gas 0.1226E-35 1.0000 0.1251E-35 0.1251E-35 CO,gas 0.1160E-15 1.0000 0.1183E-15 0.1183E-15 SO3,gas 0.1019E-39 1.0000 0.1040E-39 0.1040E-39 SO2,gas 0.9881E-23 1.0000 0.1008E-22 0.1008E-22 HCl,gas 0.5033E-17 1.0000 0.5135E-17 0.5135E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 16 albite -0.38 -0.38 0.00 0.000 -0.94784E-12 22 andradite 39.01 39.01 0.00 0.000 0.00000E+00 23 grossular 32.73 32.73 0.00 0.000 0.12132E-10 32 apatite-OH -18.15 -18.15 0.00 0.000 -0.60662E-11 46 clinochlore 39.07 39.07 0.00 0.000 -0.36397E-10 47 daphnite 28.97 28.97 0.00 0.000 -0.18198E-10 48 chlorite-Mn 46.87 46.87 0.00 0.000 0.00000E+00 90 hematite 12.57 12.57 0.00 0.000 -0.30331E-11 116 microcline -2.49 -2.49 0.00 0.000 -0.10616E-10 163 stilbite -7.52 -7.52 0.00 0.000 -0.90992E-11 164 stilpnomelane-Fe 13.02 13.02 0.00 0.000 0.21232E-10 209 nontronite-Na 3.52 3.52 0.00 0.000 0.75827E-12 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -15.11 -8.45 -2.816 0.14425E+05 -6.749 3 CH4,gas 4.54 -12.32 -16.86 -4.216 0.28792E+05 -15.164 4 H2,gas 8.00 0.70 -7.30 -4.173 0.12469E+05 -5.603 5 H2S,gas -6.23 -21.77 -15.54 -7.770 0.26536E+05 -13.842 6 S2,gas -7.34 -44.94 -37.60 -5.785 0.64204E+05 -35.903 7 CO,gas 3.21 -14.41 -17.63 -5.423 0.30096E+05 -15.927 8 SO3,gas 17.12 -24.56 -41.68 -10.421 0.71171E+05 -39.983 9 SO2,gas 0.83 -23.86 -24.70 -6.585 0.42167E+05 -22.996 10 HCl,gas 5.19 -13.80 -18.99 -9.494 0.32422E+05 -17.289 11 acmite 7.71 7.40 -0.31 -0.032 0.52197E+03 15 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 19 spessartine 24.46 19.97 -4.49 -0.224 0.76641E+04 20 analcite 3.32 2.94 -0.38 -0.042 0.64447E+03 21 andalusite 5.00 0.32 -4.68 -0.468 0.79958E+04 26 annite 20.12 17.41 -2.71 -0.151 0.46351E+04 27 phlogopite 27.06 24.12 -2.94 -0.163 0.50234E+04 29 anorthite 12.71 9.12 -3.59 -0.276 0.61314E+04 35 aragonite 0.97 -2.98 -3.95 -1.315 0.67373E+04 36 brucite 12.57 8.87 -3.70 -0.740 0.63157E+04 37 calcite 0.81 -2.98 -3.79 -1.264 0.64731E+04 38 carnegieite-low 9.02 6.27 -2.75 -0.393 0.46966E+04 39 carnegieite-high 10.09 6.27 -3.82 -0.546 0.65236E+04 40 carpholite-Mg 8.58 5.86 -2.72 -0.181 0.46477E+04 41 carpholite-Fe 6.71 3.62 -3.09 -0.206 0.52769E+04 42 celadonite 5.34 3.05 -2.29 -0.135 0.39045E+04 43 celadonite-Fe 3.88 0.82 -3.06 -0.180 0.52241E+04 44 chrysotile 23.89 19.95 -3.94 -0.328 0.67272E+04 50 chloritoid-Mg 13.20 9.19 -4.01 -0.267 0.68458E+04 51 chloritoid-Fe 9.17 6.95 -2.22 -0.148 0.37960E+04 52 chloritoid-Mn 11.40 9.09 -2.31 -0.154 0.39502E+04 54 coesite -2.38 -3.33 -0.95 -0.317 0.16259E+04 59 corundum 8.38 3.65 -4.74 -0.431 0.80868E+04 61 cristobalite -2.56 -3.33 -0.77 -0.256 0.13113E+04 63 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71234E+04 65 diaspore 2.87 1.82 -1.05 -0.175 0.17932E+04 67 diopside 16.18 14.34 -1.84 -0.184 0.31405E+04 68 hedenbergite 14.21 12.10 -2.10 -0.210 0.35927E+04 75 epidote 24.67 24.20 -0.47 -0.023 0.79698E+03 76 clinozoisite 22.81 19.74 -3.06 -0.139 0.52291E+04 77 epidote-Fe 29.84 28.66 -1.18 -0.061 0.20115E+04 78 fayalite 14.05 9.94 -4.11 -0.587 0.70185E+04 79 ferrosilite 11.15 6.61 -4.54 -0.454 0.77562E+04 83 gibbsite 4.08 1.82 -2.26 -0.322 0.38517E+04 84 glaucophane 22.97 19.18 -3.79 -0.102 0.64714E+04 85 glaucophane-Fe 17.28 12.47 -4.80 -0.130 0.82041E+04 87 greenalite 16.14 13.24 -2.90 -0.242 0.49530E+04 91 heulandite -5.83 -7.52 -1.69 -0.077 0.28938E+04 95 jadeite 4.22 2.94 -1.27 -0.127 0.21700E+04 96 julgoldite 70.43 66.94 -3.48 -0.091 0.59503E+04 97 kalsilite 7.58 4.17 -3.41 -0.488 0.58290E+04 98 kaolinite -1.33 -3.01 -1.68 -0.152 0.28631E+04 99 kyanite 4.88 0.32 -4.56 -0.456 0.77817E+04 101 laumontite 2.88 2.46 -0.42 -0.028 0.71817E+03 102 lawsonite 9.62 9.12 -0.50 -0.033 0.84809E+03 103 leucite 4.12 0.84 -3.28 -0.328 0.55955E+04 105 lizardite 23.24 19.95 -3.29 -0.274 0.56199E+04 107 magnetite 20.09 19.20 -0.89 -0.073 0.15187E+04 108 minnesotaite 10.39 6.58 -3.81 -0.224 0.64986E+04 110 magnesioferrite 26.21 21.44 -4.78 -0.390 0.81558E+04 113 margarite 17.32 12.77 -4.56 -0.182 0.77814E+04 120 muscovite 2.58 1.16 -1.42 -0.084 0.24279E+04 121 paragonite 4.24 3.26 -0.98 -0.057 0.16670E+04 122 nepheline 8.34 6.27 -2.07 -0.295 0.35289E+04 128 periclase-Fe 11.63 6.63 -4.99 -1.249 0.85285E+04 134 phlogopite-Na 29.65 26.23 -3.42 -0.190 0.58422E+04 136 prehnite 19.37 17.92 -1.45 -0.085 0.24789E+04 137 prehnite-Fe 22.50 22.38 -0.12 -0.007 0.20183E+03 138 pumpellyite-Fe 46.27 44.30 -1.97 -0.044 0.33706E+04 139 pumpellyite-Mg 48.99 46.53 -2.46 -0.055 0.42031E+04 145 pyroxmangite 7.40 5.44 -1.96 -0.392 0.33434E+04 146 pyrophyllite -6.18 -9.67 -3.49 -0.218 0.59597E+04 147 quartz -2.99 -3.33 -0.34 -0.113 0.57858E+03 152 rhodonite 7.45 5.44 -2.01 -0.401 0.34236E+04 153 sanidine -1.28 -2.49 -1.21 -0.093 0.20677E+04 156 sillimanite 5.26 0.32 -4.94 -0.494 0.84397E+04 165 stilpnomelane-Mg 27.44 24.21 -3.23 -0.097 0.55233E+04 171 talc 16.49 13.30 -3.20 -0.188 0.54556E+04 174 tephroite 18.09 14.21 -3.88 -0.554 0.66187E+04 177 topaz-H 4.62 0.32 -4.30 -0.391 0.73418E+04 178 tridymite -2.63 -3.33 -0.70 -0.234 0.11986E+04 187 wairakite 3.95 2.46 -1.49 -0.088 0.25401E+04 188 walstromite 11.51 8.80 -2.71 -0.542 0.46248E+04 189 wollastonite 10.46 8.80 -1.66 -0.332 0.28352E+04 190 pseudo-wollastonite 11.00 8.80 -2.20 -0.440 0.37550E+04 191 zoisite 22.85 19.74 -3.11 -0.141 0.53032E+04 192 akaganeite 7.75 6.28 -1.47 -0.318 0.25125E+04 193 beidellite-Ca -1.65 -5.96 -4.32 -0.267 0.73749E+04 195 beidellite-K -1.52 -6.09 -4.57 -0.280 0.78085E+04 196 beidellite-Mg -1.79 -6.50 -4.71 -0.292 0.80470E+04 197 beidellite-Na -1.34 -5.40 -4.06 -0.248 0.69277E+04 199 chalcedony -2.80 -3.33 -0.53 -0.175 0.89788E+03 201 montmorillonite-Ca -2.29 -5.34 -3.05 -0.189 0.52059E+04 202 montmorillonite-K -2.24 -5.47 -3.23 -0.198 0.55177E+04 203 montmorillonite-Mg -2.48 -5.88 -3.40 -0.210 0.58012E+04 204 montmorillonite-Na -2.04 -4.77 -2.74 -0.168 0.46726E+04 205 nontronite-Ca 3.21 2.95 -0.26 -0.017 0.44418E+03 206 nontronite-H 2.53 0.95 -1.58 -0.106 0.26971E+04 207 nontronite-K 3.34 2.83 -0.51 -0.033 0.87912E+03 208 nontronite-Mg 3.07 2.42 -0.66 -0.043 0.11235E+04 224 tobermorite 9.82 6.78 -3.05 -0.832 0.52042E+04 233 boehmite 4.41 1.82 -2.58 -0.430 0.44101E+04 235 ferrous-oxide 9.81 6.63 -3.18 -0.795 0.54294E+04 240 silica-amorphous -2.09 -3.33 -1.24 -0.412 0.21121E+04 242 an20ab80 2.02 1.52 -0.50 -0.039 0.85544E+03 243 an25ab75 2.65 1.99 -0.65 -0.050 0.11163E+04 244 an30ab70 3.28 2.47 -0.81 -0.062 0.13867E+04 245 tr.625ac.25prg.125 45.16 40.56 -4.60 -0.124 0.78589E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 0.4000000 g Current total amount of reactant added: 19.1990000 g New total amount of reactant added: 19.5990000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.6631E-13 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 7 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 19.5990000 Water: Moles liquid = 0.5536E+02 kg liquid = 0.9974E+00 Moles total = 0.5526E+02 kg total = 0.9956E+00 Activity = 1.0000 Stoichiometric ionic strength = .5049949E-02 Osmotic coef. = 0.9622 True ionic strength = .9112643E-02 Chg. balance for total moles = 0.6631E-13 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.14989E-09 -9.8242 0.13154E-09 -9.8809 0.87760E+00 -0.0567 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13802E-03 -3.8601 0.12075E-03 -3.9181 0.87483E+00 -0.0581 4 SO4-- 0.25554E-04 -4.5925 0.15894E-04 -4.7988 0.62199E+00 -0.2062 5 HCO3- 0.67684E-05 -5.1695 0.59257E-05 -5.2273 0.87549E+00 -0.0577 6 HS- 0.14715E-11 -11.8322 0.12874E-11 -11.8903 0.87489E+00 -0.0580 7 Al+++ 0.43449E-27 -27.3620 0.15160E-27 -27.8193 0.34890E+00 -0.4573 8 H4SiO4 0.46958E-03 -3.3283 0.46958E-03 -3.3283 0.10000E+01 0.0000 9 Ca++ 0.37582E-07 -7.4250 0.23286E-07 -7.6329 0.61961E+00 -0.2079 10 Mg++ 0.20737E-10 -10.6833 0.12818E-10 -10.8922 0.61813E+00 -0.2089 11 Fe++ 0.11983E-12 -12.9214 0.74113E-13 -13.1301 0.61848E+00 -0.2087 12 K+ 0.71060E-04 -4.1484 0.62221E-04 -4.2061 0.87561E+00 -0.0577 13 Na+ 0.90090E-02 -2.0453 0.78807E-02 -2.1034 0.87475E+00 -0.0581 14 Mn++ 0.16425E-10 -10.7845 0.10163E-10 -10.9930 0.61875E+00 -0.2085 15 HPO4-- 0.50344E-06 -6.2981 0.31316E-06 -6.5042 0.62203E+00 -0.2062 16 HSiO3- 0.38103E-02 -2.4190 0.33333E-02 -2.4771 0.87483E+00 -0.0581 17 Ca(HSiO3)+ 0.20186E-08 -8.6950 0.17677E-08 -8.7526 0.87571E+00 -0.0576 18 Mg(HSiO3)+ 0.13829E-11 -11.8592 0.12110E-11 -11.9169 0.87571E+00 -0.0576 19 NaHSiO3,aq 0.42486E-03 -3.3718 0.42486E-03 -3.3718 0.10000E+01 0.0000 20 AlO+ 0.13611E-14 -14.8661 0.11919E-14 -14.9238 0.87571E+00 -0.0576 22 HAlO2,aq 0.18044E-08 -8.7437 0.18044E-08 -8.7437 0.10000E+01 0.0000 23 AlO2- 0.34743E-04 -4.4591 0.30365E-04 -4.5176 0.87399E+00 -0.0585 24 CH4,aq 0.46697E-18 -18.3307 0.46624E-18 -18.3314 0.99844E+00 -0.0007 29 CO,aq 0.79420E-19 -19.1001 0.79420E-19 -19.1001 0.10000E+01 0.0000 30 CO2,aq 0.16682E-08 -8.7778 0.16656E-08 -8.7784 0.99844E+00 -0.0007 31 CO3-2 0.63332E-05 -5.1984 0.39348E-05 -5.4051 0.62129E+00 -0.2067 32 CaCO3,aq 0.11489E-08 -8.9397 0.11489E-08 -8.9397 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.40222E-11 -11.3955 0.35223E-11 -11.4532 0.87571E+00 -0.0576 34 CaCl+ 0.51960E-11 -11.2843 0.45502E-11 -11.3420 0.87571E+00 -0.0576 35 CaCl2,aq 0.13053E-15 -15.8843 0.13053E-15 -15.8843 0.10000E+01 0.0000 36 CaOH+ 0.14407E-07 -7.8414 0.12616E-07 -7.8991 0.87571E+00 -0.0576 37 CaSO4,aq 0.11753E-09 -9.9299 0.11753E-09 -9.9299 0.10000E+01 0.0000 38 HCl,aq 0.29105E-14 -14.5360 0.29105E-14 -14.5360 0.10000E+01 0.0000 43 FeCl+ 0.16175E-16 -16.7912 0.14165E-16 -16.8488 0.87571E+00 -0.0576 46 FeO,aq 0.16647E-09 -9.7787 0.16647E-09 -9.7787 0.10000E+01 0.0000 47 FeOH+ 0.20943E-10 -10.6790 0.18340E-10 -10.7366 0.87571E+00 -0.0576 48 HFeO2- 0.15136E-07 -7.8200 0.13241E-07 -7.8781 0.87483E+00 -0.0581 49 FeO+ 0.11466E-14 -14.9406 0.10040E-14 -14.9982 0.87571E+00 -0.0576 51 FeO2- 0.13572E-07 -7.8673 0.11873E-07 -7.9254 0.87483E+00 -0.0581 52 HFeO2,aq 0.19864E-09 -9.7019 0.19864E-09 -9.7019 0.10000E+01 0.0000 53 H2,aq 0.19011E-08 -8.7210 0.18982E-08 -8.7217 0.99844E+00 -0.0007 54 KCl,aq 0.13617E-09 -9.8659 0.13617E-09 -9.8659 0.10000E+01 0.0000 55 KHSO4,aq 0.36781E-18 -18.4344 0.36781E-18 -18.4344 0.10000E+01 0.0000 56 KOH,aq 0.20200E-06 -6.6946 0.20200E-06 -6.6946 0.10000E+01 0.0000 57 KSO4- 0.17542E-07 -7.7559 0.15346E-07 -7.8140 0.87483E+00 -0.0581 58 MgCO3,aq 0.15852E-12 -12.7999 0.15852E-12 -12.7999 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.22624E-14 -14.6454 0.19812E-14 -14.7031 0.87571E+00 -0.0576 60 MgCl+ 0.25923E-14 -14.5863 0.22701E-14 -14.6440 0.87571E+00 -0.0576 61 MgOH+ 0.43884E-10 -10.3577 0.38429E-10 -10.4153 0.87571E+00 -0.0576 63 MnO,aq 0.60825E-09 -9.2159 0.60825E-09 -9.2159 0.10000E+01 0.0000 64 MnOH+ 0.26678E-09 -9.5738 0.23363E-09 -9.6315 0.87571E+00 -0.0576 65 MnO2-2 0.18777E-11 -11.7264 0.11666E-11 -11.9331 0.62129E+00 -0.2067 66 HMnO2- 0.38431E-10 -10.4153 0.33620E-10 -10.4734 0.87483E+00 -0.0581 69 MnCl+ 0.86291E-14 -14.0640 0.75566E-14 -14.1217 0.87571E+00 -0.0576 70 MnSO4,aq 0.46633E-13 -13.3313 0.46633E-13 -13.3313 0.10000E+01 0.0000 71 NaCl,aq 0.31535E-06 -6.5012 0.31535E-06 -6.5012 0.10000E+01 0.0000 72 NaOH,aq 0.25740E-04 -4.5894 0.25740E-04 -4.5894 0.10000E+01 0.0000 74 OH- 0.50256E-02 -2.2988 0.43923E-02 -2.3573 0.87399E+00 -0.0585 79 HPO3-2 0.29816E-17 -17.5256 0.18524E-17 -17.7323 0.62129E+00 -0.2067 82 H3PO4,aq 0.37898E-16 -16.4214 0.37898E-16 -16.4214 0.10000E+01 0.0000 83 H2PO4- 0.86821E-09 -9.0614 0.75990E-09 -9.1192 0.87526E+00 -0.0579 84 PO4-3 0.54256E-08 -8.2656 0.19424E-08 -8.7117 0.35800E+00 -0.4461 87 H2P2O7-2 0.72878E-19 -19.1374 0.45278E-19 -19.3441 0.62129E+00 -0.2067 88 HP2O7-3 0.19691E-15 -15.7057 0.68731E-16 -16.1628 0.34904E+00 -0.4571 89 P2O7-4 0.78872E-15 -15.1031 0.12482E-15 -15.9037 0.15826E+00 -0.8006 90 H2S,aq 0.52421E-15 -15.2805 0.52340E-15 -15.2812 0.99844E+00 -0.0007 97 SO3-2 0.62628E-14 -14.2032 0.39206E-14 -14.4066 0.62601E+00 -0.2034 98 HSO3- 0.36911E-16 -16.4328 0.32291E-16 -16.4909 0.87483E+00 -0.0581 99 HSO4- 0.22997E-11 -11.6383 0.20149E-11 -11.6957 0.87615E+00 -0.0574 Charge balance for all species = 0.6510E-13 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.1498886E-09 -.9432042E-02 -.9500416E+01 0.0000 2 H2O 0.1000000E+01 0.5550914E+02 0.9993284E+06 0.0000 3 Cl- 0.1380221E-03 0.1383376E-03 0.4901122E+01 5.9628 4 SO4-- 0.2555399E-04 0.2557289E-04 0.2454889E+01 14.9631 5 HCO3- 0.6768419E-05 0.1310443E-04 0.7990474E+00 4.6537 6 HS- 0.1471515E-11 -.1244605E-08 -.4113337E-04 -2.0093 7 Al+++ 0.4344931E-27 0.3474486E-04 0.9368260E+00 1.8235 8 H4SiO4 0.4695843E-03 0.4704698E-02 0.4518840E+03 -3.3283 9 Ca++ 0.3758177E-07 0.5528311E-07 0.2214118E-02 12.1290 10 Mg++ 0.2073702E-10 0.6616700E-10 0.1607550E-05 8.8697 11 Fe++ 0.1198313E-12 0.2909429E-07 0.1623715E-02 6.6318 12 K+ 0.7106017E-04 0.7127985E-04 0.2785275E+01 5.6749 13 Na+ 0.9009046E-02 0.9459962E-02 0.2173336E+03 7.7775 14 Mn++ 0.1642498E-10 0.9318244E-09 0.5115748E-04 8.7689 15 HPO4-- 0.5034401E-06 0.5097339E-06 0.4889022E-01 13.2576 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.3245173E+00 -.9407263E-02 -.3151100E+00 0.0000000E+00 2 H2O 0.5526257E+02 0.5536331E+02 -.1007384E+00 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.5686596E-03 0.2550571E-04 0.5431539E-03 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.5431551E-03 -.1241335E-08 -.5431539E-03 0.0000000E+00 7 Al+++ 0.6390727E-01 0.3465358E-04 0.6387262E-01 0.0000000E+00 8 H4SiO4 0.2040801E+00 0.4692338E-02 0.1993878E+00 0.0000000E+00 9 Ca++ 0.2255612E-01 0.5513787E-07 0.2255606E-01 0.0000000E+00 10 Mg++ 0.1555476E-01 0.6599317E-10 0.1555476E-01 0.0000000E+00 11 Fe++ 0.1397426E-01 0.2901786E-07 0.1397423E-01 0.0000000E+00 12 K+ 0.4161146E-02 0.7109259E-04 0.4090054E-02 0.0000000E+00 13 Na+ 0.2476159E-01 0.9435110E-02 0.1532648E-01 0.0000000E+00 14 Mn++ 0.3398191E-03 0.9293764E-09 0.3398182E-03 0.0000000E+00 15 HPO4-- 0.1159786E-03 0.5083948E-06 0.1154702E-03 0.0000000E+00 Chg. balance for solid moles: -.3383E-16 Mass of aqueous solution: 0.998057E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 19.5990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 0.1520E-01 -1.818 3.986 0.601 18.63 1.530 andradite 0.1690E-02 -2.772 0.8587 -0.066 4.014 0.2231 grossular 0.8070E-04 -4.093 0.3635E-01 -1.439 0.1699 0.1011E-01 apatite-OH 0.3849E-04 -4.415 0.1933E-01 -1.714 0.9037E-01 0.6144E-02 clinochlore 0.3111E-02 -2.507 1.729 0.238 8.083 0.6577 daphnite 0.1887E-02 -2.724 1.347 0.129 6.294 0.4080 chlorite-Mn 0.6796E-04 -4.168 0.4818E-01 -1.317 0.2252 0.1536E-01 hematite 0.1053E-03 -3.977 0.1682E-01 -1.774 0.7864E-01 0.3189E-02 microcline 0.4071E-02 -2.390 1.133 0.054 5.296 0.4426 stilbite 0.1705E-01 -1.768 12.02 1.080 56.17 5.605 stilpnomelane-Fe 0.3858E-04 -4.414 0.4159E-01 -1.381 0.1944 0.1437E-01 nontronite-Na 0.3775E-03 -3.423 0.1605 -0.794 0.7504 0.4987E-01 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.9544E+00 0.9544E+00 1.0000 -0.020 grossular 0.4558E-01 0.4558E-01 1.0000 -1.341 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.6141E+00 0.6141E+00 1.0000 -0.212 daphnite 0.3725E+00 0.3725E+00 1.0000 -0.429 chlorite-Mn 0.1342E-01 0.1342E-01 1.0000 -1.872 hematite 0.1000E+01 0.1000E+01 1.0000 0.000 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 nontronite-Na 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 21.393610 g Volume = 8.965716 cm3 Porosity: -1.4267% V(tot) - V(min): -.12612E+00 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 19.5990000 g log = 1.2922 Original solution: 1000.0103000 g Original solution / Rock added: 51.02 (Water/Rock Ratio), log = 1.7078 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0203 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.1000E+01 0.9860 0.1006E+01 0.1020E+01 CO2,gas 0.1734E-06 1.0071 0.1782E-06 0.1769E-06 CH4,gas 0.6643E-15 1.0125 0.6863E-15 0.6778E-15 H2,gas 0.2441E-05 1.0005 0.2492E-05 0.2491E-05 H2S,gas 0.1416E-13 0.9960 0.1439E-13 0.1445E-13 S2,gas 0.1226E-35 1.0000 0.1251E-35 0.1251E-35 CO,gas 0.1160E-15 1.0000 0.1184E-15 0.1184E-15 SO3,gas 0.1019E-39 1.0000 0.1040E-39 0.1040E-39 SO2,gas 0.9881E-23 1.0000 0.1008E-22 0.1008E-22 HCl,gas 0.5033E-17 1.0000 0.5136E-17 0.5136E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 16 albite -0.38 -0.38 0.00 0.000 -0.94784E-12 22 andradite 39.01 39.01 0.00 0.000 0.00000E+00 23 grossular 32.73 32.73 0.00 0.000 -0.12132E-10 32 apatite-OH -18.15 -18.15 0.00 0.000 -0.60662E-11 46 clinochlore 39.07 39.07 0.00 0.000 0.12132E-10 47 daphnite 28.97 28.97 0.00 0.000 -0.66728E-10 48 chlorite-Mn 46.87 46.87 0.00 0.000 -0.12132E-10 90 hematite 12.57 12.57 0.00 0.000 0.30331E-11 116 microcline -2.49 -2.49 0.00 0.000 0.13649E-10 163 stilbite -7.52 -7.52 0.00 0.000 -0.90992E-11 164 stilpnomelane-Fe 13.02 13.02 0.00 0.000 -0.27298E-10 209 nontronite-Na 3.52 3.52 0.00 0.000 -0.68244E-11 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -15.11 -8.45 -2.816 0.14425E+05 -6.749 3 CH4,gas 4.54 -12.32 -16.86 -4.216 0.28792E+05 -15.164 4 H2,gas 8.00 0.70 -7.30 -4.173 0.12469E+05 -5.603 5 H2S,gas -6.23 -21.77 -15.54 -7.770 0.26536E+05 -13.842 6 S2,gas -7.34 -44.94 -37.60 -5.785 0.64204E+05 -35.903 7 CO,gas 3.21 -14.41 -17.63 -5.423 0.30096E+05 -15.927 8 SO3,gas 17.12 -24.56 -41.68 -10.420 0.71171E+05 -39.983 9 SO2,gas 0.83 -23.86 -24.70 -6.585 0.42167E+05 -22.996 10 HCl,gas 5.19 -13.80 -18.99 -9.494 0.32422E+05 -17.289 11 acmite 7.71 7.40 -0.31 -0.032 0.52197E+03 15 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 19 spessartine 24.46 19.97 -4.49 -0.224 0.76641E+04 20 analcite 3.32 2.94 -0.38 -0.042 0.64447E+03 21 andalusite 5.00 0.32 -4.68 -0.468 0.79958E+04 26 annite 20.12 17.41 -2.71 -0.151 0.46351E+04 27 phlogopite 27.06 24.12 -2.94 -0.163 0.50234E+04 29 anorthite 12.71 9.12 -3.59 -0.276 0.61314E+04 35 aragonite 0.97 -2.98 -3.95 -1.315 0.67373E+04 36 brucite 12.57 8.87 -3.70 -0.740 0.63157E+04 37 calcite 0.81 -2.98 -3.79 -1.264 0.64730E+04 38 carnegieite-low 9.02 6.27 -2.75 -0.393 0.46966E+04 39 carnegieite-high 10.09 6.27 -3.82 -0.546 0.65236E+04 40 carpholite-Mg 8.58 5.86 -2.72 -0.181 0.46477E+04 41 carpholite-Fe 6.71 3.62 -3.09 -0.206 0.52769E+04 42 celadonite 5.34 3.05 -2.29 -0.135 0.39045E+04 43 celadonite-Fe 3.88 0.82 -3.06 -0.180 0.52241E+04 44 chrysotile 23.89 19.95 -3.94 -0.328 0.67272E+04 50 chloritoid-Mg 13.20 9.19 -4.01 -0.267 0.68458E+04 51 chloritoid-Fe 9.17 6.95 -2.22 -0.148 0.37960E+04 52 chloritoid-Mn 11.40 9.09 -2.31 -0.154 0.39502E+04 54 coesite -2.38 -3.33 -0.95 -0.317 0.16259E+04 59 corundum 8.38 3.65 -4.74 -0.431 0.80868E+04 61 cristobalite -2.56 -3.33 -0.77 -0.256 0.13113E+04 63 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71234E+04 65 diaspore 2.87 1.82 -1.05 -0.175 0.17932E+04 67 diopside 16.18 14.34 -1.84 -0.184 0.31405E+04 68 hedenbergite 14.21 12.10 -2.10 -0.210 0.35927E+04 75 epidote 24.67 24.20 -0.47 -0.023 0.79698E+03 76 clinozoisite 22.81 19.74 -3.06 -0.139 0.52291E+04 77 epidote-Fe 29.84 28.66 -1.18 -0.061 0.20115E+04 78 fayalite 14.05 9.94 -4.11 -0.587 0.70185E+04 79 ferrosilite 11.15 6.61 -4.54 -0.454 0.77562E+04 83 gibbsite 4.08 1.82 -2.26 -0.322 0.38517E+04 84 glaucophane 22.97 19.18 -3.79 -0.102 0.64714E+04 85 glaucophane-Fe 17.28 12.47 -4.80 -0.130 0.82041E+04 87 greenalite 16.14 13.24 -2.90 -0.242 0.49530E+04 91 heulandite -5.83 -7.52 -1.69 -0.077 0.28938E+04 95 jadeite 4.22 2.94 -1.27 -0.127 0.21700E+04 96 julgoldite 70.43 66.94 -3.48 -0.091 0.59503E+04 97 kalsilite 7.58 4.17 -3.41 -0.488 0.58290E+04 98 kaolinite -1.33 -3.01 -1.68 -0.152 0.28631E+04 99 kyanite 4.88 0.32 -4.56 -0.456 0.77817E+04 101 laumontite 2.88 2.46 -0.42 -0.028 0.71817E+03 102 lawsonite 9.62 9.12 -0.50 -0.033 0.84809E+03 103 leucite 4.12 0.84 -3.28 -0.328 0.55955E+04 105 lizardite 23.24 19.95 -3.29 -0.274 0.56199E+04 107 magnetite 20.09 19.20 -0.89 -0.073 0.15187E+04 108 minnesotaite 10.39 6.58 -3.81 -0.224 0.64986E+04 110 magnesioferrite 26.21 21.44 -4.78 -0.390 0.81558E+04 113 margarite 17.32 12.77 -4.56 -0.182 0.77814E+04 120 muscovite 2.58 1.16 -1.42 -0.084 0.24279E+04 121 paragonite 4.24 3.26 -0.98 -0.057 0.16670E+04 122 nepheline 8.34 6.27 -2.07 -0.295 0.35289E+04 128 periclase-Fe 11.63 6.63 -4.99 -1.249 0.85285E+04 134 phlogopite-Na 29.65 26.23 -3.42 -0.190 0.58422E+04 136 prehnite 19.37 17.92 -1.45 -0.085 0.24789E+04 137 prehnite-Fe 22.50 22.38 -0.12 -0.007 0.20183E+03 138 pumpellyite-Fe 46.27 44.30 -1.97 -0.044 0.33706E+04 139 pumpellyite-Mg 48.99 46.53 -2.46 -0.055 0.42031E+04 145 pyroxmangite 7.40 5.44 -1.96 -0.392 0.33434E+04 146 pyrophyllite -6.18 -9.67 -3.49 -0.218 0.59597E+04 147 quartz -2.99 -3.33 -0.34 -0.113 0.57858E+03 152 rhodonite 7.45 5.44 -2.01 -0.401 0.34236E+04 153 sanidine -1.28 -2.49 -1.21 -0.093 0.20677E+04 156 sillimanite 5.26 0.32 -4.94 -0.494 0.84397E+04 165 stilpnomelane-Mg 27.44 24.21 -3.23 -0.097 0.55233E+04 171 talc 16.49 13.30 -3.20 -0.188 0.54556E+04 174 tephroite 18.09 14.21 -3.88 -0.554 0.66187E+04 177 topaz-H 4.62 0.32 -4.30 -0.391 0.73418E+04 178 tridymite -2.63 -3.33 -0.70 -0.234 0.11986E+04 187 wairakite 3.95 2.46 -1.49 -0.088 0.25401E+04 188 walstromite 11.51 8.80 -2.71 -0.542 0.46248E+04 189 wollastonite 10.46 8.80 -1.66 -0.332 0.28352E+04 190 pseudo-wollastonite 11.00 8.80 -2.20 -0.440 0.37550E+04 191 zoisite 22.85 19.74 -3.11 -0.141 0.53032E+04 192 akaganeite 7.75 6.28 -1.47 -0.318 0.25125E+04 193 beidellite-Ca -1.65 -5.96 -4.32 -0.267 0.73749E+04 195 beidellite-K -1.52 -6.09 -4.57 -0.280 0.78085E+04 196 beidellite-Mg -1.79 -6.50 -4.71 -0.292 0.80470E+04 197 beidellite-Na -1.34 -5.40 -4.06 -0.248 0.69277E+04 199 chalcedony -2.80 -3.33 -0.53 -0.175 0.89788E+03 201 montmorillonite-Ca -2.29 -5.34 -3.05 -0.189 0.52059E+04 202 montmorillonite-K -2.24 -5.47 -3.23 -0.198 0.55177E+04 203 montmorillonite-Mg -2.48 -5.88 -3.40 -0.210 0.58012E+04 204 montmorillonite-Na -2.04 -4.77 -2.74 -0.168 0.46726E+04 205 nontronite-Ca 3.21 2.95 -0.26 -0.017 0.44418E+03 206 nontronite-H 2.53 0.95 -1.58 -0.106 0.26971E+04 207 nontronite-K 3.34 2.83 -0.51 -0.033 0.87912E+03 208 nontronite-Mg 3.07 2.42 -0.66 -0.043 0.11235E+04 224 tobermorite 9.82 6.78 -3.05 -0.832 0.52042E+04 233 boehmite 4.41 1.82 -2.58 -0.430 0.44101E+04 235 ferrous-oxide 9.81 6.63 -3.18 -0.795 0.54294E+04 240 silica-amorphous -2.09 -3.33 -1.24 -0.412 0.21121E+04 242 an20ab80 2.02 1.52 -0.50 -0.039 0.85544E+03 243 an25ab75 2.65 1.99 -0.65 -0.050 0.11163E+04 244 an30ab70 3.28 2.47 -0.81 -0.062 0.13867E+04 245 tr.625ac.25prg.125 45.16 40.56 -4.60 -0.124 0.78589E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 0.4000000 g Current total amount of reactant added: 19.5990000 g New total amount of reactant added: 19.9990000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.6638E-13 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 7 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 19.9990000 Water: Moles liquid = 0.5536E+02 kg liquid = 0.9973E+00 Moles total = 0.5526E+02 kg total = 0.9955E+00 Activity = 1.0000 Stoichiometric ionic strength = .5049956E-02 Osmotic coef. = 0.9622 True ionic strength = .9112649E-02 Chg. balance for total moles = 0.6638E-13 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.14989E-09 -9.8242 0.13154E-09 -9.8809 0.87760E+00 -0.0567 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13803E-03 -3.8600 0.12075E-03 -3.9181 0.87483E+00 -0.0581 4 SO4-- 0.25555E-04 -4.5925 0.15895E-04 -4.7987 0.62199E+00 -0.2062 5 HCO3- 0.67687E-05 -5.1695 0.59259E-05 -5.2272 0.87549E+00 -0.0577 6 HS- 0.14716E-11 -11.8322 0.12875E-11 -11.8903 0.87489E+00 -0.0580 7 Al+++ 0.43449E-27 -27.3620 0.15160E-27 -27.8193 0.34890E+00 -0.4573 8 H4SiO4 0.46958E-03 -3.3283 0.46958E-03 -3.3283 0.10000E+01 0.0000 9 Ca++ 0.37582E-07 -7.4250 0.23286E-07 -7.6329 0.61961E+00 -0.2079 10 Mg++ 0.20737E-10 -10.6833 0.12818E-10 -10.8922 0.61813E+00 -0.2089 11 Fe++ 0.11983E-12 -12.9214 0.74114E-13 -13.1301 0.61848E+00 -0.2087 12 K+ 0.71060E-04 -4.1484 0.62221E-04 -4.2061 0.87561E+00 -0.0577 13 Na+ 0.90091E-02 -2.0453 0.78807E-02 -2.1034 0.87475E+00 -0.0581 14 Mn++ 0.16425E-10 -10.7845 0.10163E-10 -10.9930 0.61875E+00 -0.2085 15 HPO4-- 0.50344E-06 -6.2981 0.31316E-06 -6.5042 0.62203E+00 -0.2062 16 HSiO3- 0.38102E-02 -2.4190 0.33333E-02 -2.4771 0.87483E+00 -0.0581 17 Ca(HSiO3)+ 0.20186E-08 -8.6950 0.17677E-08 -8.7526 0.87571E+00 -0.0576 18 Mg(HSiO3)+ 0.13829E-11 -11.8592 0.12110E-11 -11.9169 0.87571E+00 -0.0576 19 NaHSiO3,aq 0.42486E-03 -3.3718 0.42486E-03 -3.3718 0.10000E+01 0.0000 20 AlO+ 0.13611E-14 -14.8661 0.11919E-14 -14.9238 0.87571E+00 -0.0576 22 HAlO2,aq 0.18044E-08 -8.7437 0.18044E-08 -8.7437 0.10000E+01 0.0000 23 AlO2- 0.34743E-04 -4.4591 0.30365E-04 -4.5176 0.87399E+00 -0.0585 24 CH4,aq 0.46698E-18 -18.3307 0.46626E-18 -18.3314 0.99844E+00 -0.0007 29 CO,aq 0.79424E-19 -19.1000 0.79424E-19 -19.1000 0.10000E+01 0.0000 30 CO2,aq 0.16682E-08 -8.7777 0.16656E-08 -8.7784 0.99844E+00 -0.0007 31 CO3-2 0.63334E-05 -5.1984 0.39349E-05 -5.4051 0.62129E+00 -0.2067 32 CaCO3,aq 0.11489E-08 -8.9397 0.11489E-08 -8.9397 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.40223E-11 -11.3955 0.35224E-11 -11.4532 0.87571E+00 -0.0576 34 CaCl+ 0.51962E-11 -11.2843 0.45504E-11 -11.3420 0.87571E+00 -0.0576 35 CaCl2,aq 0.13054E-15 -15.8843 0.13054E-15 -15.8843 0.10000E+01 0.0000 36 CaOH+ 0.14407E-07 -7.8414 0.12616E-07 -7.8991 0.87571E+00 -0.0576 37 CaSO4,aq 0.11753E-09 -9.9298 0.11753E-09 -9.9298 0.10000E+01 0.0000 38 HCl,aq 0.29106E-14 -14.5360 0.29106E-14 -14.5360 0.10000E+01 0.0000 43 FeCl+ 0.16176E-16 -16.7911 0.14165E-16 -16.8488 0.87571E+00 -0.0576 46 FeO,aq 0.16647E-09 -9.7787 0.16647E-09 -9.7787 0.10000E+01 0.0000 47 FeOH+ 0.20943E-10 -10.6790 0.18340E-10 -10.7366 0.87571E+00 -0.0576 48 HFeO2- 0.15136E-07 -7.8200 0.13241E-07 -7.8781 0.87483E+00 -0.0581 49 FeO+ 0.11466E-14 -14.9406 0.10040E-14 -14.9982 0.87571E+00 -0.0576 51 FeO2- 0.13572E-07 -7.8673 0.11873E-07 -7.9254 0.87483E+00 -0.0581 52 HFeO2,aq 0.19864E-09 -9.7019 0.19864E-09 -9.7019 0.10000E+01 0.0000 53 H2,aq 0.19011E-08 -8.7210 0.18982E-08 -8.7217 0.99844E+00 -0.0007 54 KCl,aq 0.13617E-09 -9.8659 0.13617E-09 -9.8659 0.10000E+01 0.0000 55 KHSO4,aq 0.36783E-18 -18.4344 0.36783E-18 -18.4344 0.10000E+01 0.0000 56 KOH,aq 0.20200E-06 -6.6946 0.20200E-06 -6.6946 0.10000E+01 0.0000 57 KSO4- 0.17543E-07 -7.7559 0.15347E-07 -7.8140 0.87483E+00 -0.0581 58 MgCO3,aq 0.15853E-12 -12.7999 0.15853E-12 -12.7999 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.22624E-14 -14.6454 0.19812E-14 -14.7031 0.87571E+00 -0.0576 60 MgCl+ 0.25924E-14 -14.5863 0.22702E-14 -14.6439 0.87571E+00 -0.0576 61 MgOH+ 0.43884E-10 -10.3577 0.38429E-10 -10.4153 0.87571E+00 -0.0576 63 MnO,aq 0.60825E-09 -9.2159 0.60825E-09 -9.2159 0.10000E+01 0.0000 64 MnOH+ 0.26678E-09 -9.5738 0.23363E-09 -9.6315 0.87571E+00 -0.0576 65 MnO2-2 0.18777E-11 -11.7264 0.11666E-11 -11.9331 0.62129E+00 -0.2067 66 HMnO2- 0.38431E-10 -10.4153 0.33620E-10 -10.4734 0.87483E+00 -0.0581 69 MnCl+ 0.86295E-14 -14.0640 0.75569E-14 -14.1217 0.87571E+00 -0.0576 70 MnSO4,aq 0.46635E-13 -13.3313 0.46635E-13 -13.3313 0.10000E+01 0.0000 71 NaCl,aq 0.31536E-06 -6.5012 0.31536E-06 -6.5012 0.10000E+01 0.0000 72 NaOH,aq 0.25740E-04 -4.5894 0.25740E-04 -4.5894 0.10000E+01 0.0000 74 OH- 0.50256E-02 -2.2988 0.43923E-02 -2.3573 0.87399E+00 -0.0585 79 HPO3-2 0.29816E-17 -17.5256 0.18524E-17 -17.7323 0.62129E+00 -0.2067 82 H3PO4,aq 0.37898E-16 -16.4214 0.37898E-16 -16.4214 0.10000E+01 0.0000 83 H2PO4- 0.86820E-09 -9.0614 0.75990E-09 -9.1192 0.87526E+00 -0.0579 84 PO4-3 0.54256E-08 -8.2656 0.19424E-08 -8.7117 0.35800E+00 -0.4461 87 H2P2O7-2 0.72877E-19 -19.1374 0.45278E-19 -19.3441 0.62129E+00 -0.2067 88 HP2O7-3 0.19691E-15 -15.7057 0.68731E-16 -16.1628 0.34904E+00 -0.4571 89 P2O7-4 0.78872E-15 -15.1031 0.12482E-15 -15.9037 0.15826E+00 -0.8006 90 H2S,aq 0.52423E-15 -15.2805 0.52342E-15 -15.2812 0.99844E+00 -0.0007 97 SO3-2 0.62631E-14 -14.2032 0.39207E-14 -14.4066 0.62601E+00 -0.2034 98 HSO3- 0.36912E-16 -16.4328 0.32292E-16 -16.4909 0.87483E+00 -0.0581 99 HSO4- 0.22998E-11 -11.6383 0.20150E-11 -11.6957 0.87615E+00 -0.0574 Charge balance for all species = 0.6534E-13 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.1498887E-09 -.9432038E-02 -.9500413E+01 0.0000 2 H2O 0.1000000E+01 0.5550914E+02 0.9993284E+06 0.0000 3 Cl- 0.1380277E-03 0.1383432E-03 0.4901319E+01 5.9628 4 SO4-- 0.2555501E-04 0.2557392E-04 0.2454988E+01 14.9631 5 HCO3- 0.6768692E-05 0.1310495E-04 0.7990795E+00 4.6537 6 HS- 0.1471574E-11 -.1244604E-08 -.4113334E-04 -2.0093 7 Al+++ 0.4344938E-27 0.3474485E-04 0.9368256E+00 1.8235 8 H4SiO4 0.4695843E-03 0.4704696E-02 0.4518838E+03 -3.3283 9 Ca++ 0.3758181E-07 0.5528321E-07 0.2214122E-02 12.1290 10 Mg++ 0.2073704E-10 0.6616705E-10 0.1607551E-05 8.8697 11 Fe++ 0.1198315E-12 0.2909428E-07 0.1623715E-02 6.6318 12 K+ 0.7106021E-04 0.7127989E-04 0.2785276E+01 5.6749 13 Na+ 0.9009050E-02 0.9459967E-02 0.2173337E+03 7.7775 14 Mn++ 0.1642500E-10 0.9318246E-09 0.5115749E-04 8.7689 15 HPO4-- 0.5034397E-06 0.5097335E-06 0.4889018E-01 13.2576 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.3311407E+00 -.9406881E-02 -.3217338E+00 0.0000000E+00 2 H2O 0.5525755E+02 0.5536108E+02 -.1035283E+00 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.5797449E-03 0.2550571E-04 0.5542392E-03 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.5542405E-03 -.1241285E-08 -.5542392E-03 0.0000000E+00 7 Al+++ 0.6521157E-01 0.3465218E-04 0.6517692E-01 0.0000000E+00 8 H4SiO4 0.2082452E+00 0.4692148E-02 0.2035531E+00 0.0000000E+00 9 Ca++ 0.2301617E-01 0.5513575E-07 0.2301612E-01 0.0000000E+00 10 Mg++ 0.1587222E-01 0.6599057E-10 0.1587222E-01 0.0000000E+00 11 Fe++ 0.1425946E-01 0.2901668E-07 0.1425943E-01 0.0000000E+00 12 K+ 0.4246072E-02 0.7108977E-04 0.4174982E-02 0.0000000E+00 13 Na+ 0.2526369E-01 0.9434735E-02 0.1582895E-01 0.0000000E+00 14 Mn++ 0.3467546E-03 0.9293393E-09 0.3467537E-03 0.0000000E+00 15 HPO4-- 0.1183456E-03 0.5083739E-06 0.1178372E-03 0.0000000E+00 Chg. balance for solid moles: -.3095E-16 Mass of aqueous solution: 0.998017E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 19.9990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 0.1569E-01 -1.804 4.114 0.614 18.85 1.579 andradite 0.1755E-02 -2.756 0.8918 -0.050 4.085 0.2317 grossular 0.8381E-04 -4.077 0.3775E-01 -1.423 0.1729 0.1050E-01 apatite-OH 0.3928E-04 -4.406 0.1973E-01 -1.705 0.9038E-01 0.6270E-02 clinochlore 0.3174E-02 -2.498 1.764 0.247 8.083 0.6711 daphnite 0.1926E-02 -2.715 1.374 0.138 6.294 0.4164 chlorite-Mn 0.6935E-04 -4.159 0.4917E-01 -1.308 0.2252 0.1567E-01 hematite 0.3844E-04 -4.415 0.6138E-02 -2.212 0.2812E-01 0.1163E-02 microcline 0.4155E-02 -2.381 1.157 0.063 5.298 0.4518 stilbite 0.1730E-01 -1.762 12.19 1.086 55.86 5.688 stilpnomelane-Fe 0.3937E-04 -4.405 0.4244E-01 -1.372 0.1944 0.1466E-01 nontronite-Na 0.4236E-03 -3.373 0.1802 -0.744 0.8252 0.5597E-01 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.9544E+00 0.9544E+00 1.0000 -0.020 grossular 0.4558E-01 0.4558E-01 1.0000 -1.341 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.6141E+00 0.6141E+00 1.0000 -0.212 daphnite 0.3725E+00 0.3725E+00 1.0000 -0.429 chlorite-Mn 0.1342E-01 0.1342E-01 1.0000 -1.872 hematite 0.1000E+01 0.1000E+01 1.0000 0.000 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 nontronite-Na 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 21.830470 g Volume = 9.142114 cm3 Porosity: -1.5836% V(tot) - V(min): -.14251E+00 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 19.9990000 g log = 1.3010 Original solution: 1000.0103000 g Original solution / Rock added: 50.00 (Water/Rock Ratio), log = 1.6990 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0203 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.1000E+01 0.9860 0.1006E+01 0.1020E+01 CO2,gas 0.1734E-06 1.0071 0.1782E-06 0.1769E-06 CH4,gas 0.6643E-15 1.0125 0.6863E-15 0.6778E-15 H2,gas 0.2441E-05 1.0005 0.2492E-05 0.2491E-05 H2S,gas 0.1416E-13 0.9960 0.1439E-13 0.1445E-13 S2,gas 0.1226E-35 1.0000 0.1251E-35 0.1251E-35 CO,gas 0.1160E-15 1.0000 0.1184E-15 0.1184E-15 SO3,gas 0.1019E-39 1.0000 0.1040E-39 0.1040E-39 SO2,gas 0.9882E-23 1.0000 0.1008E-22 0.1008E-22 HCl,gas 0.5034E-17 1.0000 0.5136E-17 0.5136E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 16 albite -0.38 -0.38 0.00 0.000 -0.94784E-12 22 andradite 39.01 39.01 0.00 0.000 -0.24265E-10 23 grossular 32.73 32.73 0.00 0.000 0.24265E-10 32 apatite-OH -18.15 -18.15 0.00 0.000 0.60662E-11 46 clinochlore 39.07 39.07 0.00 0.000 0.12132E-10 47 daphnite 28.97 28.97 0.00 0.000 -0.24265E-10 48 chlorite-Mn 46.87 46.87 0.00 0.000 -0.12132E-10 90 hematite 12.57 12.57 0.00 0.000 -0.90992E-11 116 microcline -2.49 -2.49 0.00 0.000 0.13649E-10 163 stilbite -7.52 -7.52 0.00 0.000 -0.90992E-11 164 stilpnomelane-Fe 13.02 13.02 0.00 0.000 -0.27298E-10 209 nontronite-Na 3.52 3.52 0.00 0.000 0.15165E-11 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -15.11 -8.45 -2.816 0.14425E+05 -6.749 3 CH4,gas 4.54 -12.32 -16.86 -4.216 0.28792E+05 -15.163 4 H2,gas 8.00 0.70 -7.30 -4.173 0.12469E+05 -5.603 5 H2S,gas -6.23 -21.77 -15.54 -7.770 0.26536E+05 -13.842 6 S2,gas -7.34 -44.94 -37.60 -5.785 0.64204E+05 -35.903 7 CO,gas 3.21 -14.41 -17.63 -5.423 0.30096E+05 -15.927 8 SO3,gas 17.12 -24.56 -41.68 -10.420 0.71171E+05 -39.983 9 SO2,gas 0.83 -23.86 -24.70 -6.585 0.42167E+05 -22.996 10 HCl,gas 5.19 -13.80 -18.99 -9.494 0.32422E+05 -17.289 11 acmite 7.71 7.40 -0.31 -0.032 0.52197E+03 15 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 19 spessartine 24.46 19.97 -4.49 -0.224 0.76641E+04 20 analcite 3.32 2.94 -0.38 -0.042 0.64447E+03 21 andalusite 5.00 0.32 -4.68 -0.468 0.79958E+04 26 annite 20.12 17.41 -2.71 -0.151 0.46351E+04 27 phlogopite 27.06 24.12 -2.94 -0.163 0.50234E+04 29 anorthite 12.71 9.12 -3.59 -0.276 0.61314E+04 35 aragonite 0.97 -2.98 -3.95 -1.315 0.67372E+04 36 brucite 12.57 8.87 -3.70 -0.740 0.63157E+04 37 calcite 0.81 -2.98 -3.79 -1.264 0.64730E+04 38 carnegieite-low 9.02 6.27 -2.75 -0.393 0.46966E+04 39 carnegieite-high 10.09 6.27 -3.82 -0.546 0.65236E+04 40 carpholite-Mg 8.58 5.86 -2.72 -0.181 0.46477E+04 41 carpholite-Fe 6.71 3.62 -3.09 -0.206 0.52769E+04 42 celadonite 5.34 3.05 -2.29 -0.135 0.39045E+04 43 celadonite-Fe 3.88 0.82 -3.06 -0.180 0.52241E+04 44 chrysotile 23.89 19.95 -3.94 -0.328 0.67272E+04 50 chloritoid-Mg 13.20 9.19 -4.01 -0.267 0.68458E+04 51 chloritoid-Fe 9.17 6.95 -2.22 -0.148 0.37960E+04 52 chloritoid-Mn 11.40 9.09 -2.31 -0.154 0.39502E+04 54 coesite -2.38 -3.33 -0.95 -0.317 0.16259E+04 59 corundum 8.38 3.65 -4.74 -0.431 0.80868E+04 61 cristobalite -2.56 -3.33 -0.77 -0.256 0.13113E+04 63 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71234E+04 65 diaspore 2.87 1.82 -1.05 -0.175 0.17932E+04 67 diopside 16.18 14.34 -1.84 -0.184 0.31405E+04 68 hedenbergite 14.21 12.10 -2.10 -0.210 0.35927E+04 75 epidote 24.67 24.20 -0.47 -0.023 0.79698E+03 76 clinozoisite 22.81 19.74 -3.06 -0.139 0.52291E+04 77 epidote-Fe 29.84 28.66 -1.18 -0.061 0.20115E+04 78 fayalite 14.05 9.94 -4.11 -0.587 0.70185E+04 79 ferrosilite 11.15 6.61 -4.54 -0.454 0.77562E+04 83 gibbsite 4.08 1.82 -2.26 -0.322 0.38517E+04 84 glaucophane 22.97 19.18 -3.79 -0.102 0.64714E+04 85 glaucophane-Fe 17.28 12.47 -4.80 -0.130 0.82041E+04 87 greenalite 16.14 13.24 -2.90 -0.242 0.49530E+04 91 heulandite -5.83 -7.52 -1.69 -0.077 0.28938E+04 95 jadeite 4.22 2.94 -1.27 -0.127 0.21700E+04 96 julgoldite 70.43 66.94 -3.48 -0.091 0.59503E+04 97 kalsilite 7.58 4.17 -3.41 -0.488 0.58290E+04 98 kaolinite -1.33 -3.01 -1.68 -0.152 0.28631E+04 99 kyanite 4.88 0.32 -4.56 -0.456 0.77817E+04 101 laumontite 2.88 2.46 -0.42 -0.028 0.71817E+03 102 lawsonite 9.62 9.12 -0.50 -0.033 0.84809E+03 103 leucite 4.12 0.84 -3.28 -0.328 0.55955E+04 105 lizardite 23.24 19.95 -3.29 -0.274 0.56199E+04 107 magnetite 20.09 19.20 -0.89 -0.073 0.15187E+04 108 minnesotaite 10.39 6.58 -3.81 -0.224 0.64986E+04 110 magnesioferrite 26.21 21.44 -4.78 -0.390 0.81558E+04 113 margarite 17.32 12.77 -4.56 -0.182 0.77814E+04 120 muscovite 2.58 1.16 -1.42 -0.084 0.24279E+04 121 paragonite 4.24 3.26 -0.98 -0.057 0.16670E+04 122 nepheline 8.34 6.27 -2.07 -0.295 0.35289E+04 128 periclase-Fe 11.63 6.63 -4.99 -1.249 0.85285E+04 134 phlogopite-Na 29.65 26.23 -3.42 -0.190 0.58422E+04 136 prehnite 19.37 17.92 -1.45 -0.085 0.24789E+04 137 prehnite-Fe 22.50 22.38 -0.12 -0.007 0.20183E+03 138 pumpellyite-Fe 46.27 44.30 -1.97 -0.044 0.33706E+04 139 pumpellyite-Mg 48.99 46.53 -2.46 -0.055 0.42031E+04 145 pyroxmangite 7.40 5.44 -1.96 -0.392 0.33434E+04 146 pyrophyllite -6.18 -9.67 -3.49 -0.218 0.59597E+04 147 quartz -2.99 -3.33 -0.34 -0.113 0.57858E+03 152 rhodonite 7.45 5.44 -2.01 -0.401 0.34236E+04 153 sanidine -1.28 -2.49 -1.21 -0.093 0.20677E+04 156 sillimanite 5.26 0.32 -4.94 -0.494 0.84397E+04 165 stilpnomelane-Mg 27.44 24.21 -3.23 -0.097 0.55233E+04 171 talc 16.49 13.30 -3.20 -0.188 0.54556E+04 174 tephroite 18.09 14.21 -3.88 -0.554 0.66187E+04 177 topaz-H 4.62 0.32 -4.30 -0.391 0.73418E+04 178 tridymite -2.63 -3.33 -0.70 -0.234 0.11986E+04 187 wairakite 3.95 2.46 -1.49 -0.088 0.25401E+04 188 walstromite 11.51 8.80 -2.71 -0.542 0.46248E+04 189 wollastonite 10.46 8.80 -1.66 -0.332 0.28352E+04 190 pseudo-wollastonite 11.00 8.80 -2.20 -0.440 0.37550E+04 191 zoisite 22.85 19.74 -3.11 -0.141 0.53032E+04 192 akaganeite 7.75 6.28 -1.47 -0.318 0.25125E+04 193 beidellite-Ca -1.65 -5.96 -4.32 -0.267 0.73749E+04 195 beidellite-K -1.52 -6.09 -4.57 -0.280 0.78085E+04 196 beidellite-Mg -1.79 -6.50 -4.71 -0.292 0.80470E+04 197 beidellite-Na -1.34 -5.40 -4.06 -0.248 0.69277E+04 199 chalcedony -2.80 -3.33 -0.53 -0.175 0.89788E+03 201 montmorillonite-Ca -2.29 -5.34 -3.05 -0.189 0.52059E+04 202 montmorillonite-K -2.24 -5.47 -3.23 -0.198 0.55177E+04 203 montmorillonite-Mg -2.48 -5.88 -3.40 -0.210 0.58012E+04 204 montmorillonite-Na -2.04 -4.77 -2.74 -0.168 0.46726E+04 205 nontronite-Ca 3.21 2.95 -0.26 -0.017 0.44418E+03 206 nontronite-H 2.53 0.95 -1.58 -0.106 0.26971E+04 207 nontronite-K 3.34 2.83 -0.51 -0.033 0.87912E+03 208 nontronite-Mg 3.07 2.42 -0.66 -0.043 0.11235E+04 224 tobermorite 9.82 6.78 -3.05 -0.832 0.52042E+04 233 boehmite 4.41 1.82 -2.58 -0.430 0.44101E+04 235 ferrous-oxide 9.81 6.63 -3.18 -0.795 0.54294E+04 240 silica-amorphous -2.09 -3.33 -1.24 -0.412 0.21121E+04 242 an20ab80 2.02 1.52 -0.50 -0.039 0.85544E+03 243 an25ab75 2.65 1.99 -0.65 -0.050 0.11163E+04 244 an30ab70 3.28 2.47 -0.81 -0.062 0.13867E+04 245 tr.625ac.25prg.125 45.16 40.56 -4.60 -0.124 0.78589E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 0.4000000 g Current total amount of reactant added: 19.9990000 g New total amount of reactant added: 20.3990000 g Mixing fraction reached given limit of 0.2000E+02 TOTMIX = 0.2040E+02 Execution stopped.