File SKIP_SPECIES.TXT lists species and minerals omitted from the calculations due to given T, P, option switches, or suppression in CHIMRUN, or are suppressed in the SOLTHERM database. It also lists minerals for which density is not specified in SOLTHERM. This is an extended P(to 5 kB), T(to 600 C) run (CON_FLAG = 1). methanol,aq is suppressed in SOLTHERM data file. methanol,aq is suppressed in SOLTHERM data file. CuCl4-3 is suppressed in SOLTHERM data file. H2BO3- is suppressed in SOLTHERM data file. UO2CO3,aq is suppressed in SOLTHERM data file. UO2SO4,aq is suppressed in SOLTHERM data file. UO2Cl2,aq is suppressed in SOLTHERM data file. UO2F2,aq is suppressed in SOLTHERM data file. PO4-3 is suppressed in SOLTHERM data file. H2PO4- is suppressed in SOLTHERM data file. H3PO4 is suppressed in SOLTHERM data file. O2,gas is suppressed in THIS RUN. O2,gas is suppressed in THIS RUN. amesite is suppressed in SOLTHERM data file. antigorite is suppressed in SOLTHERM data file. goethite is suppressed in THIS RUN. goethite is suppressed in THIS RUN. riebeckite is suppressed in THIS RUN. riebeckite is suppressed in THIS RUN. sapphirine-Fe(221) is suppressed in SOLTHERM data file. sapphirine(221) is suppressed in SOLTHERM data file. talc-prl is suppressed in SOLTHERM data file. PrO1.833(s) is suppressed in SOLTHERM data file. niter-NH4 is suppressed in SOLTHERM data file. FMQ_HS-1 is suppressed in THIS RUN. kf-ab-equil is suppressed in THIS RUN. ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Species No. Charge Tot.moles Trial molality Gamma Mixing solution H+ 1 1. -0.33114E+00 0.14989E-09 0.8776 0.00000000E+00 H2O 2 0. 0.55258E+02 0.10000E+01 1.0000 0.00000000E+00 Cl- 3 -1. 0.13797E-03 0.13803E-03 0.8748 0.00000000E+00 SO4-- 4 -2. 0.57974E-03 0.25555E-04 0.6220 0.00000000E+00 HCO3- 5 -1. 0.13070E-04 0.67687E-05 0.8755 0.00000000E+00 HS- 6 -1. -0.55424E-03 0.14716E-11 0.8749 0.00000000E+00 Al+++ 7 3. 0.65212E-01 0.43449E-27 0.3489 0.00000000E+00 H4SiO4 8 0. 0.20825E+00 0.46958E-03 1.0000 0.00000000E+00 Ca++ 9 2. 0.23016E-01 0.37582E-07 0.6196 0.00000000E+00 Mg++ 10 2. 0.15872E-01 0.20737E-10 0.6181 0.00000000E+00 Fe++ 11 2. 0.14259E-01 0.11983E-12 0.6185 0.00000000E+00 K+ 12 1. 0.42461E-02 0.71060E-04 0.8756 0.00000000E+00 Na+ 13 1. 0.25264E-01 0.90091E-02 0.8748 0.00000000E+00 Mn++ 14 2. 0.34675E-03 0.16425E-10 0.6187 0.00000000E+00 HPO4-- 15 -2. 0.11835E-03 0.50344E-06 0.6220 0.00000000E+00 Chg. balance for total moles = 0.2990E-12 Max. difference allowed = 0.1380E-07 The following parameters were given: ERPC = 0.1000E-11 pH = 0.0000 PFLUID = 50.0000 SLIM = 0.400000E+02 TEMP = 100.0000 SINC = 0.1000E+01 TEMPC = 0.0000 TOTMIX = 0.199990E+02 ENTH = 0.0000 SENTH = 0.0000 DENTH = 0.0000 TOTWAT = 90.0000 SOLMIN = 0.0000E+00 RM = 0.0000 AQGRM = 1000.0103 SUPRNT = 0.1000E-19 VBOX-1 = 8.9996 RHOFRS = 0.0000 RHOROC = 2.5000 The following options were selected: CONFLG = 1 C = 3 IFRAC = 0 IPUNCH = 2 NLOOP = 400 ISTEP = 2 LIMSOL = 1 LOOC = 0 IENTH = 0 ITREF = 0 IDEAL = 0 IPSAT = 1 INCREM = 0 INCP = 0 MINSOL = 1 NEUT = 0 AWAT = 0 CHGF = 0 Of the derived species, only those with molality > 0.10E-19 will appear in the output Species No. Charge Log K(diss) Species No. Charge Log K(diss) HSiO3- 16 -1. 9.0298 MnO2-2 65 -2. 40.4638 Ca(HSiO3)+ 17 1. 7.6723 HMnO2- 66 -1. 29.1232 Mg(HSiO3)+ 18 1. 7.5773 MnO4- 67 -1. 83.3111 NaHSiO3,aq 19 0. 7.8210 MnO4-2 68 -2. 81.3005 AlO+ 20 1. 6.8663 MnCl+ 69 1. -0.7894 AlOH+2 21 2. 3.1691 MnSO4,aq 70 0. -2.4604 HAlO2,aq 22 0. 10.5671 NaCl,aq 71 0. 0.4796 AlO2- 23 -1. 16.2221 NaOH,aq 72 0. 12.3669 CH4,aq 24 0. 6.0126 O2,aq 73 0. 53.5502 C2H6,aq 25 0. 12.3733 OH- 74 -1. 12.2382 C3H8,aq 26 0. 17.3707 HO2- 75 -1. 50.8010 C4H10,aq 27 0. 22.3757 H2O2,aq 76 0. 40.0166 ethanol,aq 28 0. 15.3258 H3PO2,aq 77 0. 24.3066 CO,aq 29 0. 4.6892 H2PO2- 78 -1. 26.5366 CO2,aq 30 0. -6.3298 HPO3-2 79 -2. 11.9254 CO3-2 31 -2. 10.0588 H3PO3,aq 80 0. 3.5792 CaCO3,aq 32 0. 5.9605 H2PO3- 81 -1. 5.6232 Ca(HCO3)+ 33 1. -1.4070 H3PO4,aq 82 0. -9.8447 CaCl+ 34 1. -0.2091 H2PO4- 83 -1. -7.2659 CaCl2,aq 35 0. 0.4151 PO4-3 84 -3. 12.0884 CaOH+ 36 1. 10.1471 H4P2O7,aq 85 0. -17.8095 CaSO4,aq 37 0. -2.5018 H3P2O7- 86 -1. -15.9156 HCl,aq 38 0. 0.7370 H2P2O7-2 87 -2. -13.4262 HClO,aq 39 0. 32.4260 HP2O7-3 88 -3. -6.7266 ClO- 40 -1. 39.6530 P2O7-4 89 -4. 2.8952 HClO2,aq 41 0. 70.1812 H2S,aq 90 0. -6.4900 Fe+3 42 3. 8.3809 S2-2 91 -2. 1.2355 FeCl+ 43 1. -0.1994 S3-2 92 -2. -8.8031 FeCl2,aq 44 0. 4.3001 S3- 93 -1. -16.3389 FeCl+2 45 2. 6.5269 S4-2 94 -2. -18.6615 FeO,aq 46 0. 16.4104 S5-2 95 -2. -28.3439 FeOH+ 47 1. 7.4874 SO2,aq 96 0. -0.2309 HFeO2- 48 -1. 24.3908 SO3-2 97 -2. 10.3052 FeO+ 49 1. 11.4004 HSO3- 98 -1. 2.5086 FeOH+2 50 2. 9.1194 HSO4- 99 -1. -2.9839 FeO2- 51 -1. 24.0895 HSO5- 100 -1. 38.8366 HFeO2,aq 52 0. 15.9850 S2O3-2 101 -2. -4.5600 H2,aq 53 0. 9.4190 HS2O3- 102 -1. -6.8123 KCl,aq 54 0. 1.7417 H2S2O3,aq 103 0. -8.0173 KHSO4,aq 55 0. -0.4514 S2O4-2 104 -2. 10.5541 KOH,aq 56 0. 12.3695 HS2O4- 105 -1. 7.6551 KSO4- 57 -1. -1.1908 H2S2O4,aq 106 0. 6.6259 MgCO3,aq 58 0. 6.5614 S2O5-2 107 -2. 10.0741 Mg(HCO3)+ 59 1. -1.4164 S2O6-2 108 -2. 11.5521 MgCl+ 60 1. -0.1664 S2O8-2 109 -2. 42.0620 MgOH+ 61 1. 9.4041 S3O6-2 110 -2. 3.7866 Mn+3 62 3. 19.1453 S4O6-2 111 -2. -17.8657 MnO,aq 63 0. 17.9848 S5O6-2 112 -2. -14.1333 MnOH+ 64 1. 8.5194 113 0. 10.3111 For mixed gases (JSOLS=6), log K(hydrol) = log (K*P) Log K Trial Log K Trial Mineral No. hydrol Moles Mineral No. hydrol Moles H2O,gas 1 1.696 0.0000E+00 osumilite(2) 124 20.667 0.0000E+00 CO2,gas 2 -6.660 0.0000E+00 osumilite-Fe 125 14.390 0.0000E+00 CH4,gas 3 4.544 0.0000E+00 pargasite 126 65.092 0.0000E+00 H2,gas 4 8.000 0.0000E+00 periclase 127 16.138 0.0000E+00 H2S,gas 5 -6.230 0.0000E+00 periclase-Fe 128 11.627 0.0000E+00 S2,gas 6 -7.335 0.0000E+00 perovskite-Al 129 12.344 0.0000E+00 CO,gas 7 3.215 0.0000E+00 perovskite-Ca 130 23.807 0.0000E+00 SO3,gas 8 17.121 0.0000E+00 perovskite-Fe 131 21.143 0.0000E+00 SO2,gas 9 0.832 0.0000E+00 perovskite-Mg 132 23.119 0.0000E+00 HCl,gas 10 5.189 0.0000E+00 phase_A 133 80.189 0.0000E+00 acmite 11 7.710 0.0000E+00 phlogopite-Na 134 29.647 0.0000E+00 akermanite 12 36.442 0.0000E+00 piemontite(ordered) 135 33.776 0.0000E+00 akimotoite 13 16.591 0.0000E+00 prehnite 136 19.372 0.0000E+00 akimotoite-Fe 14 13.067 0.0000E+00 prehnite-Fe 137 22.498 0.0000E+00 albite-high 15 0.693 0.0000E+00 pumpellyite-Fe 138 46.269 0.0000E+00 albite 16 -0.384 0.1569E-01 pumpellyite-Mg 139 48.995 0.0000E+00 almandine 17 24.442 0.0000E+00 px-Mg-tschermaks 140 19.616 0.0000E+00 pyrope 18 37.248 0.0000E+00 px-Ca-tschermaks 141 18.610 0.0000E+00 spessartine 19 24.457 0.0000E+00 pyrite 142 -21.247 0.0000E+00 analcite 20 3.322 0.0000E+00 pyrrhotite 143 -4.260 0.0000E+00 andalusite 21 5.002 0.0000E+00 pyrrhotiteFe0.875 144 -6.017 0.0000E+00 andradite 22 39.009 0.1755E-02 pyroxmangite 145 7.399 0.0000E+00 grossular 23 32.731 0.8381E-04 pyrophyllite 146 -6.176 0.0000E+00 anhydrite 24 -5.317 0.0000E+00 quartz 147 -2.989 0.0000E+00 ankerite 25 -2.135 0.0000E+00 rankinite 148 40.713 0.0000E+00 annite 26 20.123 0.0000E+00 ringwoodite-Fe 149 15.456 0.0000E+00 phlogopite 27 27.065 0.0000E+00 ringwoodite-Mg 150 27.575 0.0000E+00 biotite-Mn 28 32.960 0.0000E+00 rhodochrosite 151 -0.976 0.0000E+00 anorthite 29 12.710 0.0000E+00 rhodonite 152 7.446 0.0000E+00 anthophyllite 30 51.852 0.0000E+00 sanidine 153 -1.275 0.0000E+00 anthophyllite-Fe 31 29.306 0.0000E+00 sapphirine(351) 154 78.899 0.0000E+00 apatite-OH 32 -18.153 0.3928E-04 siderite 155 -2.608 0.0000E+00 apatite-OH-zs 33 -12.736 0.0000E+00 sillimanite 156 5.262 0.0000E+00 apatite-Cl-zs 34 -16.674 0.0000E+00 sodalite 157 49.976 0.0000E+00 aragonite 35 0.967 0.0000E+00 spinel 158 20.870 0.0000E+00 brucite 36 12.569 0.0000E+00 spurrite 159 59.482 0.0000E+00 calcite 37 0.812 0.0000E+00 staurolite-Fe 160 73.598 0.0000E+00 carnegieite-low 38 9.023 0.0000E+00 staurolite-Mg 161 89.802 0.0000E+00 carnegieite-high 39 10.093 0.0000E+00 staurolite-Mn 162 83.909 0.0000E+00 carpholite-Mg 40 8.582 0.0000E+00 stilbite 163 -7.522 0.1730E-01 carpholite-Fe 41 6.713 0.0000E+00 stilpnomelane-Fe 164 13.017 0.3937E-04 celadonite 42 5.342 0.0000E+00 stilpnomelane-Mg 165 27.441 0.0000E+00 celadonite-Fe 43 3.877 0.0000E+00 stishovite 166 2.720 0.0000E+00 chrysotile 44 23.892 0.0000E+00 sudoite-Fe 167 18.296 0.0000E+00 chondrodite 45 56.475 0.0000E+00 sudoite 168 21.077 0.0000E+00 clinochlore 46 39.070 0.3174E-02 sulfur 169 -9.152 0.0000E+00 daphnite 47 28.965 0.1926E-02 sylvite 170 1.338 0.0000E+00 chlorite-Mn 48 46.869 0.6935E-04 talc 171 16.491 0.0000E+00 chlorite-Al-free 49 47.173 0.0000E+00 talc-Fe 172 13.448 0.0000E+00 chloritoid-Mg 50 13.198 0.0000E+00 talc-tschermaks 173 19.091 0.0000E+00 chloritoid-Fe 51 9.174 0.0000E+00 tephroite 174 18.086 0.0000E+00 chloritoid-Mn 52 11.401 0.0000E+00 tilleyite 175 41.377 0.0000E+00 clinohumite 53 97.128 0.0000E+00 titanite-CaSi 176 15.479 0.0000E+00 coesite 54 -2.376 0.0000E+00 topaz-H 177 4.618 0.0000E+00 cordierite-H 55 23.715 0.0000E+00 tridymite 178 -2.626 0.0000E+00 cordierite 56 24.049 0.0000E+00 tremolite 179 47.869 0.0000E+00 cordierite-Fe 57 20.450 0.0000E+00 ferroactinolite 180 38.452 0.0000E+00 cordierite-Mn 58 25.066 0.0000E+00 troilite-low 181 -4.411 0.0000E+00 corundum 59 8.383 0.0000E+00 tschermakite 182 48.210 0.0000E+00 corundum-MgSi 60 18.891 0.0000E+00 vesuvianite 183 223.471 0.0000E+00 cristobalite 61 -2.560 0.0000E+00 wadeite-Si 184 20.216 0.0000E+00 cummingtonite 62 52.099 0.0000E+00 wadsleyite-Fe 185 15.680 0.0000E+00 cymrite-K 63 1.685 0.0000E+00 wadsleyite-Mg 186 25.850 0.0000E+00 deerite 64 95.671 0.0000E+00 wairakite 187 3.950 0.0000E+00 diaspore 65 2.874 0.0000E+00 walstromite 188 11.509 0.0000E+00 diamond 66 -3.102 0.0000E+00 wollastonite 189 10.461 0.0000E+00 diopside 67 16.181 0.0000E+00 pseudo-wollastonite 190 11.000 0.0000E+00 hedenbergite 68 14.208 0.0000E+00 zoisite 191 22.849 0.0000E+00 dolomite,ordered 69 0.546 0.0000E+00 akaganeite 192 7.755 0.0000E+00 eastonite 70 28.489 0.0000E+00 beidellite-Ca 193 -1.646 0.0000E+00 enstatite 71 17.265 0.0000E+00 beidellite-H 194 -2.326 0.0000E+00 clinoenstatite-HiP 72 18.354 0.0000E+00 beidellite-K 195 -1.520 0.0000E+00 clinoenstatite 73 17.166 0.0000E+00 beidellite-Mg 196 -1.790 0.0000E+00 protoenstatite 74 17.824 0.0000E+00 beidellite-Na 197 -1.342 0.0000E+00 epidote 75 24.670 0.0000E+00 calcium 198 84.026 0.0000E+00 clinozoisite 76 22.806 0.0000E+00 chalcedony 199 -2.802 0.0000E+00 epidote-Fe 77 29.841 0.0000E+00 dawsonite 200 1.682 0.0000E+00 fayalite 78 14.046 0.0000E+00 montmorillonite-Ca 201 -2.291 0.0000E+00 ferrosilite 79 11.149 0.0000E+00 montmorillonite-K 202 -2.237 0.0000E+00 forsterite 80 21.016 0.0000E+00 montmorillonite-Mg 203 -2.480 0.0000E+00 gedrite 81 50.522 0.0000E+00 montmorillonite-Na 204 -2.038 0.0000E+00 gehlenite 82 36.628 0.0000E+00 nontronite-Ca 205 3.215 0.0000E+00 gibbsite 83 4.079 0.0000E+00 nontronite-H 206 2.533 0.0000E+00 glaucophane 84 22.975 0.0000E+00 nontronite-K 207 3.341 0.0000E+00 glaucophane-Fe 85 17.276 0.0000E+00 nontronite-Mg 208 3.075 0.0000E+00 graphite 86 -3.546 0.0000E+00 nontronite-Na 209 3.520 0.4236E-03 greenalite 87 16.140 0.0000E+00 sepiolite 210 24.118 0.0000E+00 grunerite 88 31.215 0.0000E+00 alite 211 57.999 0.0000E+00 halite 89 1.575 0.0000E+00 belite 212 30.433 0.0000E+00 hematite 90 12.566 0.3844E-04 ettringite 213 43.232 0.0000E+00 heulandite 91 -5.827 0.0000E+00 gypsum 214 -4.955 0.0000E+00 hercynite 92 17.279 0.0000E+00 hemicarboaluminate 215 70.954 0.0000E+00 hollandite 93 25.673 0.0000E+00 hydrogarnet 216 60.662 0.0000E+00 iron 94 19.086 0.0000E+00 hydrogarnet-Si 217 50.586 0.0000E+00 jadeite 95 4.215 0.0000E+00 jennite 218 24.367 0.0000E+00 julgoldite 96 70.427 0.0000E+00 monosulfoaluminate 219 53.400 0.0000E+00 kalsilite 97 7.584 0.0000E+00 monocarboaluminate 220 61.898 0.0000E+00 kaolinite 98 -1.333 0.0000E+00 portlandite 221 18.272 0.0000E+00 kyanite 99 4.876 0.0000E+00 stratlingite 222 36.502 0.0000E+00 larnite-bredigite 100 30.686 0.0000E+00 tricarboaluminate 223 70.370 0.0000E+00 laumontite 101 2.883 0.0000E+00 tobermorite 224 9.823 0.0000E+00 lawsonite 102 9.616 0.0000E+00 C4AH13 225 81.816 0.0000E+00 leucite 103 4.119 0.0000E+00 C2AH8 226 45.203 0.0000E+00 lime 104 25.998 0.0000E+00 C3A 227 86.953 0.0000E+00 lizardite 105 23.244 0.0000E+00 C4AF 228 117.416 0.0000E+00 magnesite 106 0.691 0.0000E+00 CAH10 229 28.335 0.0000E+00 magnetite 107 20.087 0.0000E+00 alabandite 230 -0.978 0.0000E+00 minnesotaite 108 10.388 0.0000E+00 alunite 231 -10.435 0.0000E+00 minnesotaite-Mg 109 20.602 0.0000E+00 artinite 232 15.121 0.0000E+00 magnesioferrite 110 26.212 0.0000E+00 boehmite 233 4.406 0.0000E+00 majorite 111 53.251 0.0000E+00 dolomite,disordered 234 1.247 0.0000E+00 manganosite 112 14.058 0.0000E+00 ferrous-oxide 235 9.812 0.0000E+00 margarite 113 17.324 0.0000E+00 huntite 236 3.770 0.0000E+00 meionite 114 44.874 0.0000E+00 hydromagnesite 237 19.995 0.0000E+00 merwinite 115 55.930 0.0000E+00 nesquehonite 238 4.723 0.0000E+00 microcline 116 -2.486 0.4155E-02 potassium-oxide 239 69.038 0.0000E+00 monticellite 117 24.339 0.0000E+00 silica-amorphous 240 -2.091 0.0000E+00 mullite-Al 118 363.148 0.0000E+00 sodium-oxide 241 55.169 0.0000E+00 mullite-Si 119 7.264 0.0000E+00 an20ab80 242 2.018 0.0000E+00 muscovite 120 2.582 0.0000E+00 an25ab75 243 2.646 0.0000E+00 paragonite 121 4.239 0.0000E+00 an30ab70 244 3.279 0.0000E+00 nepheline 122 8.339 0.0000E+00 tr.625ac.25prg.125 245 45.165 0.0000E+00 osumilite(1) 123 21.717 0.0000E+00 246 0.000 0.0000E+00 Initial composition of reactant (wt%): SiO2 62.56 MgO 3.200 Al2O3 16.62 CaO 6.450 FeO 3.530 Na2O 3.890 Fe2O3 1.770 K2O 1.000 MnO 0.1230 P2O5 0.4200E-01 Sum of wt% of reactants: 99.1850 Reactant consumed: 19.9990000 g log = 1.3010 Original solution: 1000.0103000 g Original solution / Rock added: 50.00 (Water/Rock Ratio), log = 1.6990 The following minerals and/or gases with identical index are in solid solution: H2O,gas 6 CO2,gas 6 CH4,gas 6 H2,gas 6 H2S,gas 6 S2,gas 6 CO,gas 6 SO3,gas 6 SO2,gas 6 HCl,gas 6 almandine 16 pyrope 16 spessartine 16 andradite 8 grossular 8 annite 15 phlogopite 15 biotite-Mn 15 clinochlore 1 daphnite 1 chlorite-Mn 1 diopside 5 hedenbergite 5 epidote 3 clinozoisite 3 greenalite 18 iron 9 lizardite 18 magnetite 14 talc 7 talc-Fe 7 tremolite 2 ferroactinolite 2 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 11 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 19.9990000 Water: Moles liquid = 0.5536E+02 kg liquid = 0.9973E+00 Moles total = 0.5526E+02 kg total = 0.9955E+00 Activity = 1.0000 Stoichiometric ionic strength = .5049956E-02 Osmotic coef. = 0.9622 True ionic strength = .9112649E-02 Chg. balance for total moles = 0.2990E-12 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.14989E-09 -9.8242 0.13154E-09 -9.8809 0.87760E+00 -0.0567 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13803E-03 -3.8600 0.12075E-03 -3.9181 0.87483E+00 -0.0581 4 SO4-- 0.25555E-04 -4.5925 0.15895E-04 -4.7987 0.62199E+00 -0.2062 5 HCO3- 0.67687E-05 -5.1695 0.59259E-05 -5.2272 0.87549E+00 -0.0577 6 HS- 0.14716E-11 -11.8322 0.12875E-11 -11.8903 0.87489E+00 -0.0580 7 Al+++ 0.43449E-27 -27.3620 0.15160E-27 -27.8193 0.34890E+00 -0.4573 8 H4SiO4 0.46958E-03 -3.3283 0.46958E-03 -3.3283 0.10000E+01 0.0000 9 Ca++ 0.37582E-07 -7.4250 0.23286E-07 -7.6329 0.61961E+00 -0.2079 10 Mg++ 0.20737E-10 -10.6833 0.12818E-10 -10.8922 0.61813E+00 -0.2089 11 Fe++ 0.11983E-12 -12.9214 0.74114E-13 -13.1301 0.61848E+00 -0.2087 12 K+ 0.71060E-04 -4.1484 0.62221E-04 -4.2061 0.87561E+00 -0.0577 13 Na+ 0.90091E-02 -2.0453 0.78807E-02 -2.1034 0.87475E+00 -0.0581 14 Mn++ 0.16425E-10 -10.7845 0.10163E-10 -10.9930 0.61875E+00 -0.2085 15 HPO4-- 0.50344E-06 -6.2981 0.31316E-06 -6.5042 0.62203E+00 -0.2062 16 HSiO3- 0.38102E-02 -2.4190 0.33333E-02 -2.4771 0.87483E+00 -0.0581 17 Ca(HSiO3)+ 0.20186E-08 -8.6950 0.17677E-08 -8.7526 0.87571E+00 -0.0576 18 Mg(HSiO3)+ 0.13829E-11 -11.8592 0.12110E-11 -11.9169 0.87571E+00 -0.0576 19 NaHSiO3,aq 0.42486E-03 -3.3718 0.42486E-03 -3.3718 0.10000E+01 0.0000 20 AlO+ 0.13611E-14 -14.8661 0.11919E-14 -14.9238 0.87571E+00 -0.0576 22 HAlO2,aq 0.18044E-08 -8.7437 0.18044E-08 -8.7437 0.10000E+01 0.0000 23 AlO2- 0.34743E-04 -4.4591 0.30365E-04 -4.5176 0.87399E+00 -0.0585 24 CH4,aq 0.46698E-18 -18.3307 0.46626E-18 -18.3314 0.99844E+00 -0.0007 29 CO,aq 0.79424E-19 -19.1000 0.79424E-19 -19.1000 0.10000E+01 0.0000 30 CO2,aq 0.16682E-08 -8.7777 0.16656E-08 -8.7784 0.99844E+00 -0.0007 31 CO3-2 0.63334E-05 -5.1984 0.39349E-05 -5.4051 0.62129E+00 -0.2067 32 CaCO3,aq 0.11489E-08 -8.9397 0.11489E-08 -8.9397 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.40223E-11 -11.3955 0.35224E-11 -11.4532 0.87571E+00 -0.0576 34 CaCl+ 0.51962E-11 -11.2843 0.45504E-11 -11.3420 0.87571E+00 -0.0576 35 CaCl2,aq 0.13054E-15 -15.8843 0.13054E-15 -15.8843 0.10000E+01 0.0000 36 CaOH+ 0.14407E-07 -7.8414 0.12616E-07 -7.8991 0.87571E+00 -0.0576 37 CaSO4,aq 0.11753E-09 -9.9298 0.11753E-09 -9.9298 0.10000E+01 0.0000 38 HCl,aq 0.29106E-14 -14.5360 0.29106E-14 -14.5360 0.10000E+01 0.0000 43 FeCl+ 0.16176E-16 -16.7911 0.14165E-16 -16.8488 0.87571E+00 -0.0576 46 FeO,aq 0.16647E-09 -9.7787 0.16647E-09 -9.7787 0.10000E+01 0.0000 47 FeOH+ 0.20943E-10 -10.6790 0.18340E-10 -10.7366 0.87571E+00 -0.0576 48 HFeO2- 0.15136E-07 -7.8200 0.13241E-07 -7.8781 0.87483E+00 -0.0581 49 FeO+ 0.11466E-14 -14.9406 0.10040E-14 -14.9982 0.87571E+00 -0.0576 51 FeO2- 0.13572E-07 -7.8673 0.11873E-07 -7.9254 0.87483E+00 -0.0581 52 HFeO2,aq 0.19864E-09 -9.7019 0.19864E-09 -9.7019 0.10000E+01 0.0000 53 H2,aq 0.19011E-08 -8.7210 0.18982E-08 -8.7217 0.99844E+00 -0.0007 54 KCl,aq 0.13617E-09 -9.8659 0.13617E-09 -9.8659 0.10000E+01 0.0000 55 KHSO4,aq 0.36783E-18 -18.4344 0.36783E-18 -18.4344 0.10000E+01 0.0000 56 KOH,aq 0.20200E-06 -6.6946 0.20200E-06 -6.6946 0.10000E+01 0.0000 57 KSO4- 0.17543E-07 -7.7559 0.15347E-07 -7.8140 0.87483E+00 -0.0581 58 MgCO3,aq 0.15853E-12 -12.7999 0.15853E-12 -12.7999 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.22624E-14 -14.6454 0.19812E-14 -14.7031 0.87571E+00 -0.0576 60 MgCl+ 0.25924E-14 -14.5863 0.22702E-14 -14.6439 0.87571E+00 -0.0576 61 MgOH+ 0.43884E-10 -10.3577 0.38429E-10 -10.4153 0.87571E+00 -0.0576 63 MnO,aq 0.60825E-09 -9.2159 0.60825E-09 -9.2159 0.10000E+01 0.0000 64 MnOH+ 0.26678E-09 -9.5738 0.23363E-09 -9.6315 0.87571E+00 -0.0576 65 MnO2-2 0.18777E-11 -11.7264 0.11666E-11 -11.9331 0.62129E+00 -0.2067 66 HMnO2- 0.38431E-10 -10.4153 0.33620E-10 -10.4734 0.87483E+00 -0.0581 69 MnCl+ 0.86295E-14 -14.0640 0.75569E-14 -14.1217 0.87571E+00 -0.0576 70 MnSO4,aq 0.46635E-13 -13.3313 0.46635E-13 -13.3313 0.10000E+01 0.0000 71 NaCl,aq 0.31536E-06 -6.5012 0.31536E-06 -6.5012 0.10000E+01 0.0000 72 NaOH,aq 0.25740E-04 -4.5894 0.25740E-04 -4.5894 0.10000E+01 0.0000 74 OH- 0.50256E-02 -2.2988 0.43923E-02 -2.3573 0.87399E+00 -0.0585 79 HPO3-2 0.29816E-17 -17.5256 0.18524E-17 -17.7323 0.62129E+00 -0.2067 82 H3PO4,aq 0.37898E-16 -16.4214 0.37898E-16 -16.4214 0.10000E+01 0.0000 83 H2PO4- 0.86820E-09 -9.0614 0.75990E-09 -9.1192 0.87526E+00 -0.0579 84 PO4-3 0.54256E-08 -8.2656 0.19424E-08 -8.7117 0.35800E+00 -0.4461 87 H2P2O7-2 0.72877E-19 -19.1374 0.45278E-19 -19.3441 0.62129E+00 -0.2067 88 HP2O7-3 0.19691E-15 -15.7057 0.68731E-16 -16.1628 0.34904E+00 -0.4571 89 P2O7-4 0.78872E-15 -15.1031 0.12482E-15 -15.9037 0.15826E+00 -0.8006 90 H2S,aq 0.52423E-15 -15.2805 0.52342E-15 -15.2812 0.99844E+00 -0.0007 97 SO3-2 0.62631E-14 -14.2032 0.39207E-14 -14.4066 0.62601E+00 -0.2034 98 HSO3- 0.36912E-16 -16.4328 0.32292E-16 -16.4909 0.87483E+00 -0.0581 99 HSO4- 0.22998E-11 -11.6383 0.20150E-11 -11.6957 0.87615E+00 -0.0574 Charge balance for all species = 0.2977E-12 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.1498887E-09 -.9432038E-02 -.9500413E+01 0.0000 2 H2O 0.1000000E+01 0.5550914E+02 0.9993284E+06 0.0000 3 Cl- 0.1380277E-03 0.1383432E-03 0.4901319E+01 5.9628 4 SO4-- 0.2555501E-04 0.2557392E-04 0.2454988E+01 14.9631 5 HCO3- 0.6768692E-05 0.1310495E-04 0.7990795E+00 4.6537 6 HS- 0.1471574E-11 -.1244604E-08 -.4113334E-04 -2.0093 7 Al+++ 0.4344938E-27 0.3474485E-04 0.9368256E+00 1.8235 8 H4SiO4 0.4695843E-03 0.4704696E-02 0.4518838E+03 -3.3283 9 Ca++ 0.3758181E-07 0.5528321E-07 0.2214122E-02 12.1290 10 Mg++ 0.2073704E-10 0.6616705E-10 0.1607551E-05 8.8697 11 Fe++ 0.1198315E-12 0.2909428E-07 0.1623715E-02 6.6318 12 K+ 0.7106021E-04 0.7127989E-04 0.2785276E+01 5.6749 13 Na+ 0.9009050E-02 0.9459967E-02 0.2173337E+03 7.7775 14 Mn++ 0.1642500E-10 0.9318246E-09 0.5115749E-04 8.7689 15 HPO4-- 0.5034397E-06 0.5097335E-06 0.4889018E-01 13.2576 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.3311407E+00 -.9406881E-02 -.3217338E+00 0.0000000E+00 2 H2O 0.5525755E+02 0.5536108E+02 -.1035283E+00 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.5797449E-03 0.2550571E-04 0.5542392E-03 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.5542405E-03 -.1241285E-08 -.5542392E-03 0.0000000E+00 7 Al+++ 0.6521157E-01 0.3465218E-04 0.6517692E-01 0.0000000E+00 8 H4SiO4 0.2082452E+00 0.4692148E-02 0.2035531E+00 0.0000000E+00 9 Ca++ 0.2301617E-01 0.5513575E-07 0.2301612E-01 0.0000000E+00 10 Mg++ 0.1587222E-01 0.6599057E-10 0.1587222E-01 0.0000000E+00 11 Fe++ 0.1425946E-01 0.2901668E-07 0.1425943E-01 0.0000000E+00 12 K+ 0.4246072E-02 0.7108977E-04 0.4174982E-02 0.0000000E+00 13 Na+ 0.2526369E-01 0.9434735E-02 0.1582895E-01 0.0000000E+00 14 Mn++ 0.3467546E-03 0.9293393E-09 0.3467537E-03 0.0000000E+00 15 HPO4-- 0.1183456E-03 0.5083739E-06 0.1178372E-03 0.0000000E+00 Chg. balance for solid moles: 0.3616E-16 Mass of aqueous solution: 0.998017E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 19.9990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 0.1569E-01 -1.804 4.114 0.614 18.85 1.579 andradite 0.1755E-02 -2.756 0.8918 -0.050 4.085 0.2317 grossular 0.8381E-04 -4.077 0.3775E-01 -1.423 0.1729 0.1050E-01 apatite-OH 0.3928E-04 -4.406 0.1973E-01 -1.705 0.9038E-01 0.6270E-02 clinochlore 0.3174E-02 -2.498 1.764 0.247 8.083 0.6711 daphnite 0.1926E-02 -2.715 1.374 0.138 6.294 0.4164 chlorite-Mn 0.6935E-04 -4.159 0.4917E-01 -1.308 0.2252 0.1567E-01 hematite 0.3844E-04 -4.415 0.6138E-02 -2.212 0.2812E-01 0.1163E-02 microcline 0.4155E-02 -2.381 1.157 0.063 5.298 0.4518 stilbite 0.1730E-01 -1.762 12.19 1.086 55.86 5.688 stilpnomelane-Fe 0.3937E-04 -4.405 0.4244E-01 -1.372 0.1944 0.1466E-01 nontronite-Na 0.4236E-03 -3.373 0.1802 -0.744 0.8252 0.5597E-01 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.9544E+00 0.9544E+00 1.0000 -0.020 grossular 0.4558E-01 0.4558E-01 1.0000 -1.341 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.6141E+00 0.6141E+00 1.0000 -0.212 daphnite 0.3725E+00 0.3725E+00 1.0000 -0.429 chlorite-Mn 0.1342E-01 0.1342E-01 1.0000 -1.872 hematite 0.1000E+01 0.1000E+01 1.0000 0.000 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 nontronite-Na 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 21.830470 g Volume = 9.142114 cm3 Porosity: -1.5836% V(tot) - V(min): -.14251E+00 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 19.9990000 g log = 1.3010 Original solution: 1000.0103000 g Original solution / Rock added: 50.00 (Water/Rock Ratio), log = 1.6990 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0203 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.1000E+01 0.9860 0.1006E+01 0.1020E+01 CO2,gas 0.1734E-06 1.0071 0.1782E-06 0.1769E-06 CH4,gas 0.6643E-15 1.0125 0.6863E-15 0.6778E-15 H2,gas 0.2441E-05 1.0005 0.2492E-05 0.2491E-05 H2S,gas 0.1416E-13 0.9960 0.1439E-13 0.1445E-13 S2,gas 0.1226E-35 1.0000 0.1251E-35 0.1251E-35 CO,gas 0.1160E-15 1.0000 0.1184E-15 0.1184E-15 SO3,gas 0.1019E-39 1.0000 0.1040E-39 0.1040E-39 SO2,gas 0.9882E-23 1.0000 0.1008E-22 0.1008E-22 HCl,gas 0.5034E-17 1.0000 0.5136E-17 0.5136E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 16 albite -0.38 -0.38 0.00 0.000 -0.94784E-12 22 andradite 39.01 39.01 0.00 0.000 0.24265E-10 23 grossular 32.73 32.73 0.00 0.000 0.12132E-10 32 apatite-OH -18.15 -18.15 0.00 0.000 0.60662E-11 46 clinochlore 39.07 39.07 0.00 0.000 -0.24265E-10 47 daphnite 28.97 28.97 0.00 0.000 -0.48529E-10 48 chlorite-Mn 46.87 46.87 0.00 0.000 0.12132E-10 90 hematite 12.57 12.57 0.00 0.000 -0.90992E-11 116 microcline -2.49 -2.49 0.00 0.000 -0.10616E-10 163 stilbite -7.52 -7.52 0.00 0.000 -0.90992E-11 164 stilpnomelane-Fe 13.02 13.02 0.00 0.000 -0.27298E-10 209 nontronite-Na 3.52 3.52 0.00 0.000 0.90992E-11 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -15.11 -8.45 -2.816 0.14425E+05 -6.749 3 CH4,gas 4.54 -12.32 -16.86 -4.216 0.28792E+05 -15.163 4 H2,gas 8.00 0.70 -7.30 -4.173 0.12469E+05 -5.603 5 H2S,gas -6.23 -21.77 -15.54 -7.770 0.26536E+05 -13.842 6 S2,gas -7.34 -44.94 -37.60 -5.785 0.64204E+05 -35.903 7 CO,gas 3.21 -14.41 -17.63 -5.423 0.30096E+05 -15.927 8 SO3,gas 17.12 -24.56 -41.68 -10.420 0.71171E+05 -39.983 9 SO2,gas 0.83 -23.86 -24.70 -6.585 0.42167E+05 -22.996 10 HCl,gas 5.19 -13.80 -18.99 -9.494 0.32422E+05 -17.289 11 acmite 7.71 7.40 -0.31 -0.032 0.52197E+03 15 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 19 spessartine 24.46 19.97 -4.49 -0.224 0.76641E+04 20 analcite 3.32 2.94 -0.38 -0.042 0.64447E+03 21 andalusite 5.00 0.32 -4.68 -0.468 0.79958E+04 26 annite 20.12 17.41 -2.71 -0.151 0.46351E+04 27 phlogopite 27.06 24.12 -2.94 -0.163 0.50234E+04 29 anorthite 12.71 9.12 -3.59 -0.276 0.61314E+04 35 aragonite 0.97 -2.98 -3.95 -1.315 0.67372E+04 36 brucite 12.57 8.87 -3.70 -0.740 0.63157E+04 37 calcite 0.81 -2.98 -3.79 -1.264 0.64730E+04 38 carnegieite-low 9.02 6.27 -2.75 -0.393 0.46966E+04 39 carnegieite-high 10.09 6.27 -3.82 -0.546 0.65236E+04 40 carpholite-Mg 8.58 5.86 -2.72 -0.181 0.46477E+04 41 carpholite-Fe 6.71 3.62 -3.09 -0.206 0.52769E+04 42 celadonite 5.34 3.05 -2.29 -0.135 0.39045E+04 43 celadonite-Fe 3.88 0.82 -3.06 -0.180 0.52241E+04 44 chrysotile 23.89 19.95 -3.94 -0.328 0.67272E+04 50 chloritoid-Mg 13.20 9.19 -4.01 -0.267 0.68458E+04 51 chloritoid-Fe 9.17 6.95 -2.22 -0.148 0.37960E+04 52 chloritoid-Mn 11.40 9.09 -2.31 -0.154 0.39502E+04 54 coesite -2.38 -3.33 -0.95 -0.317 0.16259E+04 59 corundum 8.38 3.65 -4.74 -0.431 0.80868E+04 61 cristobalite -2.56 -3.33 -0.77 -0.256 0.13113E+04 63 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71234E+04 65 diaspore 2.87 1.82 -1.05 -0.175 0.17932E+04 67 diopside 16.18 14.34 -1.84 -0.184 0.31405E+04 68 hedenbergite 14.21 12.10 -2.10 -0.210 0.35927E+04 75 epidote 24.67 24.20 -0.47 -0.023 0.79698E+03 76 clinozoisite 22.81 19.74 -3.06 -0.139 0.52291E+04 77 epidote-Fe 29.84 28.66 -1.18 -0.061 0.20115E+04 78 fayalite 14.05 9.94 -4.11 -0.587 0.70185E+04 79 ferrosilite 11.15 6.61 -4.54 -0.454 0.77562E+04 83 gibbsite 4.08 1.82 -2.26 -0.322 0.38517E+04 84 glaucophane 22.97 19.18 -3.79 -0.102 0.64714E+04 85 glaucophane-Fe 17.28 12.47 -4.80 -0.130 0.82041E+04 87 greenalite 16.14 13.24 -2.90 -0.242 0.49530E+04 91 heulandite -5.83 -7.52 -1.69 -0.077 0.28938E+04 95 jadeite 4.22 2.94 -1.27 -0.127 0.21700E+04 96 julgoldite 70.43 66.94 -3.48 -0.091 0.59503E+04 97 kalsilite 7.58 4.17 -3.41 -0.488 0.58290E+04 98 kaolinite -1.33 -3.01 -1.68 -0.152 0.28631E+04 99 kyanite 4.88 0.32 -4.56 -0.456 0.77817E+04 101 laumontite 2.88 2.46 -0.42 -0.028 0.71817E+03 102 lawsonite 9.62 9.12 -0.50 -0.033 0.84809E+03 103 leucite 4.12 0.84 -3.28 -0.328 0.55955E+04 105 lizardite 23.24 19.95 -3.29 -0.274 0.56199E+04 107 magnetite 20.09 19.20 -0.89 -0.073 0.15187E+04 108 minnesotaite 10.39 6.58 -3.81 -0.224 0.64986E+04 110 magnesioferrite 26.21 21.44 -4.78 -0.390 0.81558E+04 113 margarite 17.32 12.77 -4.56 -0.182 0.77814E+04 120 muscovite 2.58 1.16 -1.42 -0.084 0.24279E+04 121 paragonite 4.24 3.26 -0.98 -0.057 0.16670E+04 122 nepheline 8.34 6.27 -2.07 -0.295 0.35289E+04 128 periclase-Fe 11.63 6.63 -4.99 -1.249 0.85285E+04 134 phlogopite-Na 29.65 26.23 -3.42 -0.190 0.58422E+04 136 prehnite 19.37 17.92 -1.45 -0.085 0.24789E+04 137 prehnite-Fe 22.50 22.38 -0.12 -0.007 0.20183E+03 138 pumpellyite-Fe 46.27 44.30 -1.97 -0.044 0.33706E+04 139 pumpellyite-Mg 48.99 46.53 -2.46 -0.055 0.42031E+04 145 pyroxmangite 7.40 5.44 -1.96 -0.392 0.33434E+04 146 pyrophyllite -6.18 -9.67 -3.49 -0.218 0.59597E+04 147 quartz -2.99 -3.33 -0.34 -0.113 0.57858E+03 152 rhodonite 7.45 5.44 -2.01 -0.401 0.34236E+04 153 sanidine -1.28 -2.49 -1.21 -0.093 0.20677E+04 156 sillimanite 5.26 0.32 -4.94 -0.494 0.84397E+04 165 stilpnomelane-Mg 27.44 24.21 -3.23 -0.097 0.55233E+04 171 talc 16.49 13.30 -3.20 -0.188 0.54556E+04 174 tephroite 18.09 14.21 -3.88 -0.554 0.66187E+04 177 topaz-H 4.62 0.32 -4.30 -0.391 0.73418E+04 178 tridymite -2.63 -3.33 -0.70 -0.234 0.11986E+04 187 wairakite 3.95 2.46 -1.49 -0.088 0.25401E+04 188 walstromite 11.51 8.80 -2.71 -0.542 0.46248E+04 189 wollastonite 10.46 8.80 -1.66 -0.332 0.28352E+04 190 pseudo-wollastonite 11.00 8.80 -2.20 -0.440 0.37550E+04 191 zoisite 22.85 19.74 -3.11 -0.141 0.53032E+04 192 akaganeite 7.75 6.28 -1.47 -0.318 0.25125E+04 193 beidellite-Ca -1.65 -5.96 -4.32 -0.267 0.73749E+04 195 beidellite-K -1.52 -6.09 -4.57 -0.280 0.78085E+04 196 beidellite-Mg -1.79 -6.50 -4.71 -0.292 0.80470E+04 197 beidellite-Na -1.34 -5.40 -4.06 -0.248 0.69277E+04 199 chalcedony -2.80 -3.33 -0.53 -0.175 0.89788E+03 201 montmorillonite-Ca -2.29 -5.34 -3.05 -0.189 0.52059E+04 202 montmorillonite-K -2.24 -5.47 -3.23 -0.198 0.55177E+04 203 montmorillonite-Mg -2.48 -5.88 -3.40 -0.210 0.58012E+04 204 montmorillonite-Na -2.04 -4.77 -2.74 -0.168 0.46726E+04 205 nontronite-Ca 3.21 2.95 -0.26 -0.017 0.44418E+03 206 nontronite-H 2.53 0.95 -1.58 -0.106 0.26971E+04 207 nontronite-K 3.34 2.83 -0.51 -0.033 0.87912E+03 208 nontronite-Mg 3.07 2.42 -0.66 -0.043 0.11235E+04 224 tobermorite 9.82 6.78 -3.05 -0.832 0.52042E+04 233 boehmite 4.41 1.82 -2.58 -0.430 0.44101E+04 235 ferrous-oxide 9.81 6.63 -3.18 -0.795 0.54294E+04 240 silica-amorphous -2.09 -3.33 -1.24 -0.412 0.21121E+04 242 an20ab80 2.02 1.52 -0.50 -0.039 0.85544E+03 243 an25ab75 2.65 1.99 -0.65 -0.050 0.11163E+04 244 an30ab70 3.28 2.47 -0.81 -0.062 0.13867E+04 245 tr.625ac.25prg.125 45.16 40.56 -4.60 -0.124 0.78589E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 1.0000000 g Current total amount of reactant added: 19.9990000 g New total amount of reactant added: 20.9990000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.2990E-12 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 7 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 20.9990000 Water: Moles liquid = 0.5535E+02 kg liquid = 0.9972E+00 Moles total = 0.5525E+02 kg total = 0.9953E+00 Activity = 1.0000 Stoichiometric ionic strength = .5049974E-02 Osmotic coef. = 0.9622 True ionic strength = .9112663E-02 Chg. balance for total moles = 0.2990E-12 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.14989E-09 -9.8242 0.13154E-09 -9.8809 0.87760E+00 -0.0567 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13804E-03 -3.8600 0.12076E-03 -3.9181 0.87483E+00 -0.0581 4 SO4-- 0.25558E-04 -4.5925 0.15896E-04 -4.7987 0.62199E+00 -0.2062 5 HCO3- 0.67694E-05 -5.1695 0.59265E-05 -5.2272 0.87549E+00 -0.0577 6 HS- 0.14717E-11 -11.8322 0.12876E-11 -11.8902 0.87489E+00 -0.0580 7 Al+++ 0.43450E-27 -27.3620 0.15160E-27 -27.8193 0.34890E+00 -0.4573 8 H4SiO4 0.46958E-03 -3.3283 0.46958E-03 -3.3283 0.10000E+01 0.0000 9 Ca++ 0.37582E-07 -7.4250 0.23286E-07 -7.6329 0.61961E+00 -0.2079 10 Mg++ 0.20737E-10 -10.6833 0.12818E-10 -10.8922 0.61813E+00 -0.2089 11 Fe++ 0.11983E-12 -12.9214 0.74114E-13 -13.1301 0.61848E+00 -0.2087 12 K+ 0.71060E-04 -4.1484 0.62221E-04 -4.2061 0.87561E+00 -0.0577 13 Na+ 0.90091E-02 -2.0453 0.78807E-02 -2.1034 0.87475E+00 -0.0581 14 Mn++ 0.16425E-10 -10.7845 0.10163E-10 -10.9930 0.61875E+00 -0.2085 15 HPO4-- 0.50344E-06 -6.2981 0.31316E-06 -6.5042 0.62203E+00 -0.2062 16 HSiO3- 0.38102E-02 -2.4190 0.33333E-02 -2.4771 0.87483E+00 -0.0581 17 Ca(HSiO3)+ 0.20186E-08 -8.6950 0.17677E-08 -8.7526 0.87571E+00 -0.0576 18 Mg(HSiO3)+ 0.13829E-11 -11.8592 0.12110E-11 -11.9169 0.87571E+00 -0.0576 19 NaHSiO3,aq 0.42486E-03 -3.3718 0.42486E-03 -3.3718 0.10000E+01 0.0000 20 AlO+ 0.13611E-14 -14.8661 0.11919E-14 -14.9238 0.87571E+00 -0.0576 22 HAlO2,aq 0.18044E-08 -8.7437 0.18044E-08 -8.7437 0.10000E+01 0.0000 23 AlO2- 0.34743E-04 -4.4591 0.30365E-04 -4.5176 0.87399E+00 -0.0585 24 CH4,aq 0.46703E-18 -18.3307 0.46631E-18 -18.3313 0.99844E+00 -0.0007 29 CO,aq 0.79432E-19 -19.1000 0.79432E-19 -19.1000 0.10000E+01 0.0000 30 CO2,aq 0.16684E-08 -8.7777 0.16658E-08 -8.7784 0.99844E+00 -0.0007 31 CO3-2 0.63341E-05 -5.1983 0.39353E-05 -5.4050 0.62129E+00 -0.2067 32 CaCO3,aq 0.11490E-08 -8.9397 0.11490E-08 -8.9397 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.40228E-11 -11.3955 0.35228E-11 -11.4531 0.87571E+00 -0.0576 34 CaCl+ 0.51968E-11 -11.2843 0.45509E-11 -11.3419 0.87571E+00 -0.0576 35 CaCl2,aq 0.13057E-15 -15.8842 0.13057E-15 -15.8842 0.10000E+01 0.0000 36 CaOH+ 0.14407E-07 -7.8414 0.12616E-07 -7.8991 0.87571E+00 -0.0576 37 CaSO4,aq 0.11755E-09 -9.9298 0.11755E-09 -9.9298 0.10000E+01 0.0000 38 HCl,aq 0.29109E-14 -14.5360 0.29109E-14 -14.5360 0.10000E+01 0.0000 43 FeCl+ 0.16177E-16 -16.7911 0.14167E-16 -16.8487 0.87571E+00 -0.0576 46 FeO,aq 0.16647E-09 -9.7787 0.16647E-09 -9.7787 0.10000E+01 0.0000 47 FeOH+ 0.20943E-10 -10.6790 0.18340E-10 -10.7366 0.87571E+00 -0.0576 48 HFeO2- 0.15136E-07 -7.8200 0.13241E-07 -7.8781 0.87483E+00 -0.0581 49 FeO+ 0.11466E-14 -14.9406 0.10040E-14 -14.9982 0.87571E+00 -0.0576 51 FeO2- 0.13572E-07 -7.8673 0.11873E-07 -7.9254 0.87483E+00 -0.0581 52 HFeO2,aq 0.19864E-09 -9.7019 0.19864E-09 -9.7019 0.10000E+01 0.0000 53 H2,aq 0.19011E-08 -8.7210 0.18982E-08 -8.7217 0.99844E+00 -0.0007 54 KCl,aq 0.13618E-09 -9.8659 0.13618E-09 -9.8659 0.10000E+01 0.0000 55 KHSO4,aq 0.36786E-18 -18.4343 0.36786E-18 -18.4343 0.10000E+01 0.0000 56 KOH,aq 0.20200E-06 -6.6946 0.20200E-06 -6.6946 0.10000E+01 0.0000 57 KSO4- 0.17544E-07 -7.7559 0.15348E-07 -7.8139 0.87483E+00 -0.0581 58 MgCO3,aq 0.15854E-12 -12.7999 0.15854E-12 -12.7999 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.22627E-14 -14.6454 0.19814E-14 -14.7030 0.87571E+00 -0.0576 60 MgCl+ 0.25927E-14 -14.5862 0.22705E-14 -14.6439 0.87571E+00 -0.0576 61 MgOH+ 0.43884E-10 -10.3577 0.38429E-10 -10.4153 0.87571E+00 -0.0576 63 MnO,aq 0.60825E-09 -9.2159 0.60825E-09 -9.2159 0.10000E+01 0.0000 64 MnOH+ 0.26679E-09 -9.5738 0.23363E-09 -9.6315 0.87571E+00 -0.0576 65 MnO2-2 0.18777E-11 -11.7264 0.11666E-11 -11.9331 0.62129E+00 -0.2067 66 HMnO2- 0.38431E-10 -10.4153 0.33620E-10 -10.4734 0.87483E+00 -0.0581 69 MnCl+ 0.86304E-14 -14.0640 0.75577E-14 -14.1216 0.87571E+00 -0.0576 70 MnSO4,aq 0.46640E-13 -13.3312 0.46640E-13 -13.3312 0.10000E+01 0.0000 71 NaCl,aq 0.31539E-06 -6.5011 0.31539E-06 -6.5011 0.10000E+01 0.0000 72 NaOH,aq 0.25740E-04 -4.5894 0.25740E-04 -4.5894 0.10000E+01 0.0000 74 OH- 0.50256E-02 -2.2988 0.43923E-02 -2.3573 0.87399E+00 -0.0585 79 HPO3-2 0.29816E-17 -17.5256 0.18524E-17 -17.7323 0.62129E+00 -0.2067 82 H3PO4,aq 0.37898E-16 -16.4214 0.37898E-16 -16.4214 0.10000E+01 0.0000 83 H2PO4- 0.86820E-09 -9.0614 0.75990E-09 -9.1192 0.87526E+00 -0.0579 84 PO4-3 0.54256E-08 -8.2656 0.19423E-08 -8.7117 0.35800E+00 -0.4461 87 H2P2O7-2 0.72877E-19 -19.1374 0.45278E-19 -19.3441 0.62129E+00 -0.2067 88 HP2O7-3 0.19691E-15 -15.7057 0.68730E-16 -16.1629 0.34904E+00 -0.4571 89 P2O7-4 0.78872E-15 -15.1031 0.12482E-15 -15.9037 0.15826E+00 -0.8006 90 H2S,aq 0.52429E-15 -15.2804 0.52347E-15 -15.2811 0.99844E+00 -0.0007 97 SO3-2 0.62637E-14 -14.2032 0.39211E-14 -14.4066 0.62601E+00 -0.2034 98 HSO3- 0.36916E-16 -16.4328 0.32295E-16 -16.4909 0.87483E+00 -0.0581 99 HSO4- 0.23001E-11 -11.6383 0.20152E-11 -11.6957 0.87614E+00 -0.0574 Charge balance for all species = 0.2965E-12 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.1498889E-09 -.9432029E-02 -.9500403E+01 0.0000 2 H2O 0.1000000E+01 0.5550914E+02 0.9993284E+06 0.0000 3 Cl- 0.1380415E-03 0.1383571E-03 0.4901811E+01 5.9629 4 SO4-- 0.2555758E-04 0.2557649E-04 0.2455235E+01 14.9632 5 HCO3- 0.6769375E-05 0.1310627E-04 0.7991598E+00 4.6537 6 HS- 0.1471723E-11 -.1244602E-08 -.4113328E-04 -2.0093 7 Al+++ 0.4344956E-27 0.3474481E-04 0.9368245E+00 1.8235 8 H4SiO4 0.4695843E-03 0.4704692E-02 0.4518834E+03 -3.3283 9 Ca++ 0.3758191E-07 0.5528346E-07 0.2214132E-02 12.1290 10 Mg++ 0.2073710E-10 0.6616718E-10 0.1607554E-05 8.8697 11 Fe++ 0.1198318E-12 0.2909425E-07 0.1623713E-02 6.6318 12 K+ 0.7106030E-04 0.7127998E-04 0.2785279E+01 5.6749 13 Na+ 0.9009062E-02 0.9459978E-02 0.2173339E+03 7.7775 14 Mn++ 0.1642504E-10 0.9318251E-09 0.5115752E-04 8.7689 15 HPO4-- 0.5034387E-06 0.5097324E-06 0.4889008E-01 13.2576 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.3476992E+00 -.9405927E-02 -.3382933E+00 0.0000000E+00 2 H2O 0.5524502E+02 0.5535552E+02 -.1105030E+00 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.6074583E-03 0.2550571E-04 0.5819526E-03 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.5819539E-03 -.1241158E-08 -.5819526E-03 0.0000000E+00 7 Al+++ 0.6847231E-01 0.3464866E-04 0.6843766E-01 0.0000000E+00 8 H4SiO4 0.2186580E+00 0.4691672E-02 0.2139664E+00 0.0000000E+00 9 Ca++ 0.2416632E-01 0.5513047E-07 0.2416626E-01 0.0000000E+00 10 Mg++ 0.1666587E-01 0.6598407E-10 0.1666587E-01 0.0000000E+00 11 Fe++ 0.1497247E-01 0.2901373E-07 0.1497244E-01 0.0000000E+00 12 K+ 0.4458386E-02 0.7108272E-04 0.4387304E-02 0.0000000E+00 13 Na+ 0.2651893E-01 0.9433799E-02 0.1708513E-01 0.0000000E+00 14 Mn++ 0.3640932E-03 0.9292464E-09 0.3640922E-03 0.0000000E+00 15 HPO4-- 0.1242632E-03 0.5083218E-06 0.1237549E-03 0.0000000E+00 Chg. balance for solid moles: 0.5426E-16 Mass of aqueous solution: 0.997917E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 20.9990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 0.1691E-01 -1.772 4.433 0.647 19.34 1.702 andradite 0.1918E-02 -2.717 0.9746 -0.011 4.252 0.2532 grossular 0.9159E-04 -4.038 0.4126E-01 -1.385 0.1800 0.1148E-01 apatite-OH 0.4125E-04 -4.385 0.2072E-01 -1.684 0.9040E-01 0.6585E-02 clinochlore 0.3333E-02 -2.477 1.853 0.268 8.082 0.7047 daphnite 0.2022E-02 -2.694 1.443 0.159 6.294 0.4372 chlorite-Mn 0.7282E-04 -4.138 0.5163E-01 -1.287 0.2252 0.1645E-01 hematite -.1288E-03 1.000 -.2058E-01 1.000 -.8976E-01 -.3900E-02 microcline 0.4367E-02 -2.360 1.215 0.085 5.302 0.4748 stilbite 0.1793E-01 -1.746 12.64 1.102 55.13 5.894 stilpnomelane-Fe 0.4134E-04 -4.384 0.4456E-01 -1.351 0.1944 0.1539E-01 nontronite-Na 0.5389E-03 -3.268 0.2292 -0.640 0.9998 0.7119E-01 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.9544E+00 0.9544E+00 1.0000 -0.020 grossular 0.4558E-01 0.4558E-01 1.0000 -1.341 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.6141E+00 0.6141E+00 1.0000 -0.212 daphnite 0.3725E+00 0.3725E+00 1.0000 -0.429 chlorite-Mn 0.1342E-01 0.1342E-01 1.0000 -1.872 hematite 0.1000E+01 0.1000E+01 1.0000 0.000 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 nontronite-Na 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 22.922619 g Volume = 9.583106 cm3 Porosity: -1.9523% V(tot) - V(min): -.18351E+00 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 20.9990000 g log = 1.3222 Original solution: 1000.0103000 g Original solution / Rock added: 47.62 (Water/Rock Ratio), log = 1.6778 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0203 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.1000E+01 0.9860 0.1006E+01 0.1020E+01 CO2,gas 0.1734E-06 1.0071 0.1782E-06 0.1770E-06 CH4,gas 0.6644E-15 1.0125 0.6864E-15 0.6779E-15 H2,gas 0.2441E-05 1.0005 0.2492E-05 0.2491E-05 H2S,gas 0.1416E-13 0.9960 0.1439E-13 0.1445E-13 S2,gas 0.1227E-35 1.0000 0.1252E-35 0.1252E-35 CO,gas 0.1160E-15 1.0000 0.1184E-15 0.1184E-15 SO3,gas 0.1019E-39 1.0000 0.1040E-39 0.1040E-39 SO2,gas 0.9883E-23 1.0000 0.1008E-22 0.1008E-22 HCl,gas 0.5034E-17 1.0000 0.5136E-17 0.5136E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 16 albite -0.38 -0.38 0.00 0.000 -0.94784E-12 22 andradite 39.01 39.01 0.00 0.000 0.24265E-10 23 grossular 32.73 32.73 0.00 0.000 0.24265E-10 32 apatite-OH -18.15 -18.15 0.00 0.000 0.60662E-11 46 clinochlore 39.07 39.07 0.00 0.000 0.36397E-10 47 daphnite 28.97 28.97 0.00 0.000 -0.36397E-10 48 chlorite-Mn 46.87 46.87 0.00 0.000 0.12132E-10 116 microcline -2.49 -2.49 0.00 0.000 -0.10616E-10 163 stilbite -7.52 -7.52 0.00 0.000 -0.90992E-11 164 stilpnomelane-Fe 13.02 13.02 0.00 0.000 -0.27298E-10 209 nontronite-Na 3.52 3.52 0.00 0.000 0.10616E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -15.11 -8.45 -2.816 0.14425E+05 -6.749 3 CH4,gas 4.54 -12.32 -16.86 -4.216 0.28792E+05 -15.163 4 H2,gas 8.00 0.70 -7.30 -4.173 0.12469E+05 -5.603 5 H2S,gas -6.23 -21.77 -15.54 -7.770 0.26536E+05 -13.842 6 S2,gas -7.34 -44.94 -37.60 -5.785 0.64204E+05 -35.903 7 CO,gas 3.21 -14.41 -17.63 -5.423 0.30095E+05 -15.927 8 SO3,gas 17.12 -24.56 -41.68 -10.420 0.71171E+05 -39.983 9 SO2,gas 0.83 -23.86 -24.70 -6.585 0.42167E+05 -22.996 10 HCl,gas 5.19 -13.80 -18.99 -9.494 0.32422E+05 -17.289 11 acmite 7.71 7.40 -0.31 -0.032 0.52197E+03 15 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 19 spessartine 24.46 19.97 -4.49 -0.224 0.76641E+04 20 analcite 3.32 2.94 -0.38 -0.042 0.64447E+03 21 andalusite 5.00 0.32 -4.68 -0.468 0.79958E+04 26 annite 20.12 17.41 -2.71 -0.151 0.46351E+04 27 phlogopite 27.06 24.12 -2.94 -0.163 0.50234E+04 29 anorthite 12.71 9.12 -3.59 -0.276 0.61314E+04 35 aragonite 0.97 -2.98 -3.95 -1.315 0.67371E+04 36 brucite 12.57 8.87 -3.70 -0.740 0.63157E+04 37 calcite 0.81 -2.98 -3.79 -1.264 0.64729E+04 38 carnegieite-low 9.02 6.27 -2.75 -0.393 0.46966E+04 39 carnegieite-high 10.09 6.27 -3.82 -0.546 0.65236E+04 40 carpholite-Mg 8.58 5.86 -2.72 -0.181 0.46477E+04 41 carpholite-Fe 6.71 3.62 -3.09 -0.206 0.52769E+04 42 celadonite 5.34 3.05 -2.29 -0.135 0.39045E+04 43 celadonite-Fe 3.88 0.82 -3.06 -0.180 0.52241E+04 44 chrysotile 23.89 19.95 -3.94 -0.328 0.67272E+04 50 chloritoid-Mg 13.20 9.19 -4.01 -0.267 0.68458E+04 51 chloritoid-Fe 9.17 6.95 -2.22 -0.148 0.37960E+04 52 chloritoid-Mn 11.40 9.09 -2.31 -0.154 0.39502E+04 54 coesite -2.38 -3.33 -0.95 -0.317 0.16259E+04 59 corundum 8.38 3.65 -4.74 -0.431 0.80868E+04 61 cristobalite -2.56 -3.33 -0.77 -0.256 0.13113E+04 63 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71234E+04 65 diaspore 2.87 1.82 -1.05 -0.175 0.17932E+04 67 diopside 16.18 14.34 -1.84 -0.184 0.31405E+04 68 hedenbergite 14.21 12.10 -2.10 -0.210 0.35927E+04 75 epidote 24.67 24.20 -0.47 -0.023 0.79698E+03 76 clinozoisite 22.81 19.74 -3.06 -0.139 0.52291E+04 77 epidote-Fe 29.84 28.66 -1.18 -0.061 0.20115E+04 78 fayalite 14.05 9.94 -4.11 -0.587 0.70185E+04 79 ferrosilite 11.15 6.61 -4.54 -0.454 0.77562E+04 83 gibbsite 4.08 1.82 -2.26 -0.322 0.38517E+04 84 glaucophane 22.97 19.18 -3.79 -0.102 0.64714E+04 85 glaucophane-Fe 17.28 12.47 -4.80 -0.130 0.82041E+04 87 greenalite 16.14 13.24 -2.90 -0.242 0.49530E+04 90 hematite 12.57 12.57 0.00 0.000 0.15165E-10 91 heulandite -5.83 -7.52 -1.69 -0.077 0.28938E+04 95 jadeite 4.22 2.94 -1.27 -0.127 0.21700E+04 96 julgoldite 70.43 66.94 -3.48 -0.091 0.59503E+04 97 kalsilite 7.58 4.17 -3.41 -0.488 0.58290E+04 98 kaolinite -1.33 -3.01 -1.68 -0.152 0.28631E+04 99 kyanite 4.88 0.32 -4.56 -0.456 0.77817E+04 101 laumontite 2.88 2.46 -0.42 -0.028 0.71817E+03 102 lawsonite 9.62 9.12 -0.50 -0.033 0.84809E+03 103 leucite 4.12 0.84 -3.28 -0.328 0.55955E+04 105 lizardite 23.24 19.95 -3.29 -0.274 0.56199E+04 107 magnetite 20.09 19.20 -0.89 -0.073 0.15187E+04 108 minnesotaite 10.39 6.58 -3.81 -0.224 0.64986E+04 110 magnesioferrite 26.21 21.44 -4.78 -0.390 0.81558E+04 113 margarite 17.32 12.77 -4.56 -0.182 0.77814E+04 120 muscovite 2.58 1.16 -1.42 -0.084 0.24279E+04 121 paragonite 4.24 3.26 -0.98 -0.057 0.16670E+04 122 nepheline 8.34 6.27 -2.07 -0.295 0.35289E+04 128 periclase-Fe 11.63 6.63 -4.99 -1.249 0.85285E+04 134 phlogopite-Na 29.65 26.23 -3.42 -0.190 0.58422E+04 136 prehnite 19.37 17.92 -1.45 -0.085 0.24789E+04 137 prehnite-Fe 22.50 22.38 -0.12 -0.007 0.20183E+03 138 pumpellyite-Fe 46.27 44.30 -1.97 -0.044 0.33706E+04 139 pumpellyite-Mg 48.99 46.53 -2.46 -0.055 0.42031E+04 145 pyroxmangite 7.40 5.44 -1.96 -0.392 0.33434E+04 146 pyrophyllite -6.18 -9.67 -3.49 -0.218 0.59597E+04 147 quartz -2.99 -3.33 -0.34 -0.113 0.57858E+03 152 rhodonite 7.45 5.44 -2.01 -0.401 0.34236E+04 153 sanidine -1.28 -2.49 -1.21 -0.093 0.20677E+04 156 sillimanite 5.26 0.32 -4.94 -0.494 0.84397E+04 165 stilpnomelane-Mg 27.44 24.21 -3.23 -0.097 0.55233E+04 171 talc 16.49 13.30 -3.20 -0.188 0.54556E+04 174 tephroite 18.09 14.21 -3.88 -0.554 0.66187E+04 177 topaz-H 4.62 0.32 -4.30 -0.391 0.73418E+04 178 tridymite -2.63 -3.33 -0.70 -0.234 0.11986E+04 187 wairakite 3.95 2.46 -1.49 -0.088 0.25401E+04 188 walstromite 11.51 8.80 -2.71 -0.542 0.46248E+04 189 wollastonite 10.46 8.80 -1.66 -0.332 0.28352E+04 190 pseudo-wollastonite 11.00 8.80 -2.20 -0.440 0.37550E+04 191 zoisite 22.85 19.74 -3.11 -0.141 0.53032E+04 192 akaganeite 7.75 6.28 -1.47 -0.318 0.25125E+04 193 beidellite-Ca -1.65 -5.96 -4.32 -0.267 0.73749E+04 195 beidellite-K -1.52 -6.09 -4.57 -0.280 0.78085E+04 196 beidellite-Mg -1.79 -6.50 -4.71 -0.292 0.80470E+04 197 beidellite-Na -1.34 -5.40 -4.06 -0.248 0.69277E+04 199 chalcedony -2.80 -3.33 -0.53 -0.175 0.89788E+03 201 montmorillonite-Ca -2.29 -5.34 -3.05 -0.189 0.52059E+04 202 montmorillonite-K -2.24 -5.47 -3.23 -0.198 0.55177E+04 203 montmorillonite-Mg -2.48 -5.88 -3.40 -0.210 0.58012E+04 204 montmorillonite-Na -2.04 -4.77 -2.74 -0.168 0.46726E+04 205 nontronite-Ca 3.21 2.95 -0.26 -0.017 0.44418E+03 206 nontronite-H 2.53 0.95 -1.58 -0.106 0.26971E+04 207 nontronite-K 3.34 2.83 -0.51 -0.033 0.87912E+03 208 nontronite-Mg 3.07 2.42 -0.66 -0.043 0.11235E+04 224 tobermorite 9.82 6.78 -3.05 -0.832 0.52042E+04 233 boehmite 4.41 1.82 -2.58 -0.430 0.44101E+04 235 ferrous-oxide 9.81 6.63 -3.18 -0.795 0.54294E+04 240 silica-amorphous -2.09 -3.33 -1.24 -0.412 0.21121E+04 242 an20ab80 2.02 1.52 -0.50 -0.039 0.85544E+03 243 an25ab75 2.65 1.99 -0.65 -0.050 0.11163E+04 244 an30ab70 3.28 2.47 -0.81 -0.062 0.13867E+04 245 tr.625ac.25prg.125 45.16 40.56 -4.60 -0.124 0.78589E+04 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 9 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 20.9990000 Water: Moles liquid = 0.5535E+02 kg liquid = 0.9972E+00 Moles total = 0.5525E+02 kg total = 0.9953E+00 Activity = 1.0000 Stoichiometric ionic strength = .5075460E-02 Osmotic coef. = 0.9621 True ionic strength = .9168890E-02 Chg. balance for total moles = 0.2990E-12 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.14986E-09 -9.8243 0.13148E-09 -9.8811 0.87734E+00 -0.0568 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13804E-03 -3.8600 0.12072E-03 -3.9182 0.87455E+00 -0.0582 4 SO4-- 0.25558E-04 -4.5925 0.15877E-04 -4.7992 0.62123E+00 -0.2068 5 HCO3- 0.67649E-05 -5.1697 0.59208E-05 -5.2276 0.87522E+00 -0.0579 6 HS- 0.16482E-11 -11.7830 0.14416E-11 -11.8412 0.87462E+00 -0.0582 7 Al+++ 0.41553E-27 -27.3814 0.14457E-27 -27.8399 0.34793E+00 -0.4585 8 H4SiO4 0.47584E-03 -3.3225 0.47584E-03 -3.3225 0.10000E+01 0.0000 9 Ca++ 0.37572E-07 -7.4251 0.23251E-07 -7.6336 0.61884E+00 -0.2084 10 Mg++ 0.21133E-10 -10.6750 0.13047E-10 -10.8845 0.61735E+00 -0.2095 11 Fe++ 0.11946E-12 -12.9228 0.73793E-13 -13.1320 0.61771E+00 -0.2092 12 K+ 0.71500E-04 -4.1457 0.62587E-04 -4.2035 0.87534E+00 -0.0578 13 Na+ 0.90648E-02 -2.0426 0.79270E-02 -2.1009 0.87448E+00 -0.0583 14 Mn++ 0.16739E-10 -10.7763 0.10344E-10 -10.9853 0.61798E+00 -0.2090 15 HPO4-- 0.50501E-06 -6.2967 0.31375E-06 -6.5034 0.62127E+00 -0.2067 16 HSiO3- 0.38640E-02 -2.4130 0.33793E-02 -2.4712 0.87455E+00 -0.0582 17 Ca(HSiO3)+ 0.20440E-08 -8.6895 0.17894E-08 -8.7473 0.87544E+00 -0.0578 18 Mg(HSiO3)+ 0.14273E-11 -11.8455 0.12495E-11 -11.9032 0.87544E+00 -0.0578 19 NaHSiO3,aq 0.43325E-03 -3.3633 0.43325E-03 -3.3633 0.10000E+01 0.0000 20 AlO+ 0.12996E-14 -14.8862 0.11378E-14 -14.9440 0.87544E+00 -0.0578 22 HAlO2,aq 0.17233E-08 -8.7636 0.17233E-08 -8.7636 0.10000E+01 0.0000 23 AlO2- 0.33207E-04 -4.4788 0.29013E-04 -4.5374 0.87371E+00 -0.0586 24 CH4,aq 0.52301E-18 -18.2815 0.52219E-18 -18.2822 0.99844E+00 -0.0007 29 CO,aq 0.81623E-19 -19.0882 0.81623E-19 -19.0882 0.10000E+01 0.0000 30 CO2,aq 0.16660E-08 -8.7783 0.16634E-08 -8.7790 0.99844E+00 -0.0007 31 CO3-2 0.63387E-05 -5.1980 0.39333E-05 -5.4052 0.62053E+00 -0.2072 32 CaCO3,aq 0.11467E-08 -8.9405 0.11467E-08 -8.9405 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.40140E-11 -11.3964 0.35140E-11 -11.4542 0.87544E+00 -0.0578 34 CaCl+ 0.51889E-11 -11.2849 0.45425E-11 -11.3427 0.87544E+00 -0.0578 35 CaCl2,aq 0.13029E-15 -15.8851 0.13029E-15 -15.8851 0.10000E+01 0.0000 36 CaOH+ 0.14397E-07 -7.8417 0.12603E-07 -7.8995 0.87544E+00 -0.0578 37 CaSO4,aq 0.11723E-09 -9.9310 0.11723E-09 -9.9310 0.10000E+01 0.0000 38 HCl,aq 0.29086E-14 -14.5363 0.29086E-14 -14.5363 0.10000E+01 0.0000 43 FeCl+ 0.16107E-16 -16.7930 0.14101E-16 -16.8508 0.87544E+00 -0.0578 46 FeO,aq 0.16591E-09 -9.7801 0.16591E-09 -9.7801 0.10000E+01 0.0000 47 FeOH+ 0.20869E-10 -10.6805 0.18269E-10 -10.7383 0.87544E+00 -0.0578 48 HFeO2- 0.15096E-07 -7.8211 0.13203E-07 -7.8793 0.87455E+00 -0.0582 49 FeO+ 0.11262E-14 -14.9484 0.98595E-15 -15.0061 0.87544E+00 -0.0578 51 FeO2- 0.13344E-07 -7.8747 0.11670E-07 -7.9329 0.87455E+00 -0.0582 52 HFeO2,aq 0.19515E-09 -9.7096 0.19515E-09 -9.7096 0.10000E+01 0.0000 53 H2,aq 0.19564E-08 -8.7085 0.19534E-08 -8.7092 0.99844E+00 -0.0007 54 KCl,aq 0.13694E-09 -9.8635 0.13694E-09 -9.8635 0.10000E+01 0.0000 55 KHSO4,aq 0.36940E-18 -18.4325 0.36940E-18 -18.4325 0.10000E+01 0.0000 56 KOH,aq 0.20329E-06 -6.6919 0.20329E-06 -6.6919 0.10000E+01 0.0000 57 KSO4- 0.17632E-07 -7.7537 0.15420E-07 -7.8119 0.87455E+00 -0.0582 58 MgCO3,aq 0.16128E-12 -12.7924 0.16128E-12 -12.7924 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.23015E-14 -14.6380 0.20148E-14 -14.6958 0.87544E+00 -0.0578 60 MgCl+ 0.26389E-14 -14.5786 0.23102E-14 -14.6364 0.87544E+00 -0.0578 61 MgOH+ 0.44701E-10 -10.3497 0.39133E-10 -10.4075 0.87544E+00 -0.0578 63 MnO,aq 0.61967E-09 -9.2078 0.61967E-09 -9.2078 0.10000E+01 0.0000 64 MnOH+ 0.27175E-09 -9.5658 0.23790E-09 -9.6236 0.87544E+00 -0.0578 65 MnO2-2 0.19171E-11 -11.7173 0.11896E-11 -11.9246 0.62053E+00 -0.2072 66 HMnO2- 0.39183E-10 -10.4069 0.34268E-10 -10.4651 0.87455E+00 -0.0582 69 MnCl+ 0.87840E-14 -14.0563 0.76898E-14 -14.1141 0.87544E+00 -0.0578 70 MnSO4,aq 0.47413E-13 -13.3241 0.47413E-13 -13.3241 0.10000E+01 0.0000 71 NaCl,aq 0.31714E-06 -6.4987 0.31714E-06 -6.4987 0.10000E+01 0.0000 72 NaOH,aq 0.25904E-04 -4.5866 0.25904E-04 -4.5866 0.10000E+01 0.0000 74 OH- 0.50295E-02 -2.2985 0.43944E-02 -2.3571 0.87371E+00 -0.0586 79 HPO3-2 0.30778E-17 -17.5118 0.19099E-17 -17.7190 0.62053E+00 -0.2072 82 H3PO4,aq 0.37933E-16 -16.4210 0.37933E-16 -16.4210 0.10000E+01 0.0000 83 H2PO4- 0.86970E-09 -9.0606 0.76098E-09 -9.1186 0.87499E+00 -0.0580 84 PO4-3 0.54528E-08 -8.2634 0.19469E-08 -8.7106 0.35705E+00 -0.4473 87 H2P2O7-2 0.73173E-19 -19.1356 0.45406E-19 -19.3429 0.62053E+00 -0.2072 88 HP2O7-3 0.19811E-15 -15.7031 0.68957E-16 -16.1614 0.34807E+00 -0.4583 89 P2O7-4 0.79557E-15 -15.0993 0.12529E-15 -15.9021 0.15749E+00 -0.8028 90 H2S,aq 0.58671E-15 -15.2316 0.58579E-15 -15.2323 0.99844E+00 -0.0007 97 SO3-2 0.64457E-14 -14.1907 0.40302E-14 -14.3947 0.62526E+00 -0.2039 98 HSO3- 0.37937E-16 -16.4209 0.33178E-16 -16.4791 0.87455E+00 -0.0582 99 HSO4- 0.22969E-11 -11.6389 0.20118E-11 -11.6964 0.87588E+00 -0.0576 Charge balance for all species = 0.2978E-12 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.1498625E-09 -.9492193E-02 -.9560938E+01 0.0000 2 H2O 0.1000000E+01 0.5550908E+02 0.9993204E+06 0.0000 3 Cl- 0.1380407E-03 0.1383580E-03 0.4901809E+01 5.9629 4 SO4-- 0.2555766E-04 0.2557661E-04 0.2455230E+01 14.9630 5 HCO3- 0.6764862E-05 0.1310635E-04 0.7991595E+00 4.6535 6 HS- 0.1648230E-11 -.1201678E-08 -.3971437E-04 -1.9600 7 Al+++ 0.4155279E-27 0.3320881E-04 0.8954033E+00 1.8035 8 H4SiO4 0.4758359E-03 0.4773100E-02 0.4584509E+03 -3.3225 9 Ca++ 0.3757197E-07 0.5528578E-07 0.2214210E-02 12.1287 10 Mg++ 0.2113308E-10 0.6742722E-10 0.1638156E-05 8.8778 11 Fe++ 0.1194629E-12 0.2882286E-07 0.1608556E-02 6.6303 12 K+ 0.7149990E-04 0.7172096E-04 0.2802492E+01 5.6776 13 Na+ 0.9064842E-02 0.9524315E-02 0.2188105E+03 7.7802 14 Mn++ 0.1673860E-10 0.9493191E-09 0.5211759E-04 8.7770 15 HPO4-- 0.5050058E-06 0.5113283E-06 0.4904281E-01 13.2589 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.3476992E+00 -.9465864E-02 -.3382334E+00 0.0000000E+00 2 H2O 0.5524502E+02 0.5535510E+02 -.1100837E+00 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.6074583E-03 0.2550567E-04 0.5819527E-03 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.5819539E-03 -.1198344E-08 -.5819527E-03 0.0000000E+00 7 Al+++ 0.6847231E-01 0.3311670E-04 0.6843920E-01 0.0000000E+00 8 H4SiO4 0.2186580E+00 0.4759861E-02 0.2138982E+00 0.0000000E+00 9 Ca++ 0.2416632E-01 0.5513242E-07 0.2416626E-01 0.0000000E+00 10 Mg++ 0.1666587E-01 0.6724019E-10 0.1666587E-01 0.0000000E+00 11 Fe++ 0.1497247E-01 0.2874291E-07 0.1497244E-01 0.0000000E+00 12 K+ 0.4458386E-02 0.7152202E-04 0.4386864E-02 0.0000000E+00 13 Na+ 0.2651893E-01 0.9497896E-02 0.1702104E-01 0.0000000E+00 14 Mn++ 0.3640932E-03 0.9466859E-09 0.3640922E-03 0.0000000E+00 15 HPO4-- 0.1242632E-03 0.5099100E-06 0.1237533E-03 0.0000000E+00 Chg. balance for solid moles: 0.6288E-17 Mass of aqueous solution: 0.997917E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 20.9990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 0.1688E-01 -1.773 4.427 0.646 19.31 1.699 andradite 0.1905E-02 -2.720 0.9682 -0.014 4.224 0.2515 grossular 0.8845E-04 -4.053 0.3984E-01 -1.400 0.1738 0.1109E-01 apatite-OH 0.4125E-04 -4.385 0.2072E-01 -1.684 0.9040E-01 0.6584E-02 clinochlore 0.3333E-02 -2.477 1.853 0.268 8.082 0.7047 daphnite 0.1978E-02 -2.704 1.411 0.150 6.157 0.4277 chlorite-Mn 0.7282E-04 -4.138 0.5163E-01 -1.287 0.2252 0.1645E-01 microcline 0.4344E-02 -2.362 1.209 0.082 5.275 0.4723 stilbite 0.1798E-01 -1.745 12.67 1.103 55.28 5.910 stilpnomelane-Fe 0.8533E-04 -4.069 0.9198E-01 -1.036 0.4013 0.3177E-01 nontronite-Na 0.4227E-03 -3.374 0.1797 -0.745 0.7841 0.5584E-01 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.9556E+00 0.9556E+00 1.0000 -0.020 grossular 0.4437E-01 0.4437E-01 1.0000 -1.353 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.6191E+00 0.6191E+00 1.0000 -0.208 daphnite 0.3674E+00 0.3674E+00 1.0000 -0.435 chlorite-Mn 0.1352E-01 0.1352E-01 1.0000 -1.869 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 nontronite-Na 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 22.922230 g Volume = 9.586937 cm3 Porosity: -1.9930% V(tot) - V(min): -.18734E+00 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 20.9990000 g log = 1.3222 Original solution: 1000.0103000 g Original solution / Rock added: 47.62 (Water/Rock Ratio), log = 1.6778 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0203 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.1000E+01 0.9860 0.1006E+01 0.1020E+01 CO2,gas 0.1732E-06 1.0071 0.1780E-06 0.1767E-06 CH4,gas 0.7440E-15 1.0125 0.7686E-15 0.7591E-15 H2,gas 0.2512E-05 1.0005 0.2565E-05 0.2563E-05 H2S,gas 0.1585E-13 0.9960 0.1610E-13 0.1617E-13 S2,gas 0.1450E-35 1.0000 0.1480E-35 0.1480E-35 CO,gas 0.1192E-15 1.0000 0.1216E-15 0.1216E-15 SO3,gas 0.1017E-39 1.0000 0.1038E-39 0.1038E-39 SO2,gas 0.1015E-22 1.0000 0.1035E-22 0.1035E-22 HCl,gas 0.5030E-17 1.0000 0.5132E-17 0.5132E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 16 albite -0.38 -0.38 0.00 0.000 -0.94784E-12 22 andradite 39.01 39.01 0.00 0.000 0.00000E+00 23 grossular 32.73 32.73 0.00 0.000 0.00000E+00 32 apatite-OH -18.15 -18.15 0.00 0.000 0.00000E+00 46 clinochlore 39.07 39.07 0.00 0.000 -0.12132E-10 47 daphnite 28.97 28.97 0.00 0.000 0.12132E-10 48 chlorite-Mn 46.87 46.87 0.00 0.000 0.12132E-10 116 microcline -2.49 -2.49 0.00 0.000 0.13649E-10 163 stilbite -7.52 -7.52 0.00 0.000 -0.90992E-11 164 stilpnomelane-Fe 13.02 13.02 0.00 0.000 0.21232E-10 209 nontronite-Na 3.52 3.52 0.00 0.000 0.68244E-11 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -15.11 -8.45 -2.816 0.14426E+05 -6.750 3 CH4,gas 4.54 -12.27 -16.81 -4.203 0.28708E+05 -15.114 4 H2,gas 8.00 0.71 -7.29 -4.166 0.12447E+05 -5.591 5 H2S,gas -6.23 -21.72 -15.49 -7.746 0.26452E+05 -13.793 6 S2,gas -7.34 -44.86 -37.53 -5.774 0.64079E+05 -35.830 7 CO,gas 3.21 -14.40 -17.61 -5.420 0.30075E+05 -15.915 8 SO3,gas 17.12 -24.56 -41.68 -10.421 0.71172E+05 -39.984 9 SO2,gas 0.83 -23.85 -24.68 -6.582 0.42147E+05 -22.985 10 HCl,gas 5.19 -13.80 -18.99 -9.494 0.32423E+05 -17.290 11 acmite 7.71 7.41 -0.30 -0.031 0.51080E+03 15 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 19 spessartine 24.46 19.97 -4.49 -0.224 0.76615E+04 20 analcite 3.32 2.94 -0.38 -0.043 0.65428E+03 21 andalusite 5.00 0.28 -4.72 -0.472 0.80542E+04 26 annite 20.12 17.40 -2.72 -0.151 0.46426E+04 27 phlogopite 27.06 24.15 -2.92 -0.162 0.49820E+04 29 anorthite 12.71 9.09 -3.62 -0.278 0.61805E+04 35 aragonite 0.97 -2.98 -3.95 -1.316 0.67386E+04 36 brucite 12.57 8.88 -3.69 -0.738 0.63019E+04 37 calcite 0.81 -2.98 -3.79 -1.264 0.64744E+04 38 carnegieite-low 9.02 6.26 -2.76 -0.395 0.47162E+04 39 carnegieite-high 10.09 6.26 -3.83 -0.547 0.65432E+04 40 carpholite-Mg 8.58 5.84 -2.74 -0.183 0.46825E+04 41 carpholite-Fe 6.71 3.59 -3.12 -0.208 0.53280E+04 42 celadonite 5.34 3.07 -2.27 -0.134 0.38809E+04 43 celadonite-Fe 3.88 0.82 -3.06 -0.180 0.52168E+04 44 chrysotile 23.89 19.99 -3.90 -0.325 0.66662E+04 50 chloritoid-Mg 13.20 9.16 -4.04 -0.269 0.68904E+04 51 chloritoid-Fe 9.17 6.91 -2.26 -0.151 0.38569E+04 52 chloritoid-Mn 11.40 9.06 -2.34 -0.156 0.39948E+04 54 coesite -2.38 -3.32 -0.95 -0.315 0.16161E+04 59 corundum 8.38 3.61 -4.78 -0.434 0.81550E+04 61 cristobalite -2.56 -3.32 -0.76 -0.254 0.13014E+04 63 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71234E+04 65 diaspore 2.87 1.80 -1.07 -0.178 0.18273E+04 67 diopside 16.18 14.36 -1.82 -0.182 0.31075E+04 68 hedenbergite 14.21 12.11 -2.09 -0.209 0.35760E+04 75 epidote 24.67 24.17 -0.50 -0.024 0.84977E+03 76 clinozoisite 22.81 19.70 -3.11 -0.141 0.53029E+04 77 epidote-Fe 29.84 28.64 -1.20 -0.062 0.20433E+04 78 fayalite 14.05 9.94 -4.11 -0.587 0.70138E+04 79 ferrosilite 11.15 6.62 -4.53 -0.453 0.77416E+04 83 gibbsite 4.08 1.80 -2.28 -0.325 0.38859E+04 84 glaucophane 22.97 19.22 -3.75 -0.101 0.64104E+04 85 glaucophane-Fe 17.28 12.48 -4.80 -0.130 0.81920E+04 87 greenalite 16.14 13.25 -2.89 -0.241 0.49409E+04 90 hematite 12.57 12.55 -0.02 -0.002 0.26283E+02 91 heulandite -5.83 -7.52 -1.69 -0.077 0.28938E+04 95 jadeite 4.22 2.94 -1.28 -0.128 0.21798E+04 96 julgoldite 70.43 66.94 -3.49 -0.091 0.59507E+04 97 kalsilite 7.58 4.16 -3.43 -0.489 0.58486E+04 98 kaolinite -1.33 -3.04 -1.71 -0.155 0.29117E+04 99 kyanite 4.88 0.28 -4.59 -0.459 0.78401E+04 101 laumontite 2.88 2.45 -0.44 -0.029 0.74759E+03 102 lawsonite 9.62 9.09 -0.53 -0.035 0.89712E+03 103 leucite 4.12 0.84 -3.28 -0.328 0.56053E+04 105 lizardite 23.24 19.99 -3.26 -0.271 0.55589E+04 107 magnetite 20.09 19.18 -0.91 -0.074 0.15475E+04 108 minnesotaite 10.39 6.60 -3.79 -0.223 0.64669E+04 110 magnesioferrite 26.21 21.43 -4.78 -0.391 0.81683E+04 113 margarite 17.32 12.70 -4.63 -0.185 0.78986E+04 120 muscovite 2.58 1.12 -1.46 -0.086 0.24962E+04 121 paragonite 4.24 3.22 -1.02 -0.060 0.17353E+04 122 nepheline 8.34 6.26 -2.08 -0.297 0.35485E+04 128 periclase-Fe 11.63 6.63 -5.00 -1.249 0.85310E+04 134 phlogopite-Na 29.65 26.25 -3.40 -0.189 0.58008E+04 136 prehnite 19.37 17.90 -1.48 -0.087 0.25186E+04 137 prehnite-Fe 22.50 22.37 -0.13 -0.008 0.22050E+03 138 pumpellyite-Fe 46.27 44.23 -2.04 -0.045 0.34865E+04 139 pumpellyite-Mg 48.99 46.47 -2.52 -0.056 0.43027E+04 145 pyroxmangite 7.40 5.45 -1.94 -0.389 0.33198E+04 146 pyrophyllite -6.18 -9.68 -3.51 -0.219 0.59887E+04 147 quartz -2.99 -3.32 -0.33 -0.111 0.56877E+03 152 rhodonite 7.45 5.45 -1.99 -0.398 0.34000E+04 153 sanidine -1.28 -2.49 -1.21 -0.093 0.20677E+04 156 sillimanite 5.26 0.28 -4.98 -0.498 0.84982E+04 165 stilpnomelane-Mg 27.44 24.25 -3.19 -0.095 0.54418E+04 171 talc 16.49 13.34 -3.15 -0.185 0.53750E+04 174 tephroite 18.09 14.23 -3.85 -0.551 0.65813E+04 177 topaz-H 4.62 0.28 -4.33 -0.394 0.74002E+04 178 tridymite -2.63 -3.32 -0.70 -0.232 0.11887E+04 187 wairakite 3.95 2.45 -1.50 -0.089 0.25696E+04 188 walstromite 11.51 8.81 -2.70 -0.541 0.46154E+04 189 wollastonite 10.46 8.81 -1.65 -0.331 0.28258E+04 190 pseudo-wollastonite 11.00 8.81 -2.19 -0.439 0.37456E+04 191 zoisite 22.85 19.70 -3.15 -0.143 0.53769E+04 192 akaganeite 7.75 6.28 -1.48 -0.320 0.25257E+04 193 beidellite-Ca -1.65 -5.99 -4.34 -0.269 0.74185E+04 195 beidellite-K -1.52 -6.12 -4.60 -0.282 0.78505E+04 196 beidellite-Mg -1.79 -6.53 -4.74 -0.293 0.80882E+04 197 beidellite-Na -1.34 -5.42 -4.08 -0.250 0.69696E+04 199 chalcedony -2.80 -3.32 -0.52 -0.173 0.88807E+03 201 montmorillonite-Ca -2.29 -5.35 -3.06 -0.189 0.52192E+04 202 montmorillonite-K -2.24 -5.48 -3.24 -0.198 0.55293E+04 203 montmorillonite-Mg -2.48 -5.88 -3.40 -0.211 0.58121E+04 204 montmorillonite-Na -2.04 -4.78 -2.74 -0.168 0.46842E+04 205 nontronite-Ca 3.21 2.95 -0.26 -0.017 0.44579E+03 206 nontronite-H 2.53 0.95 -1.58 -0.106 0.26986E+04 207 nontronite-K 3.34 2.83 -0.51 -0.033 0.87912E+03 208 nontronite-Mg 3.07 2.42 -0.66 -0.043 0.11228E+04 224 tobermorite 9.82 6.78 -3.04 -0.830 0.51948E+04 233 boehmite 4.41 1.80 -2.60 -0.434 0.44442E+04 235 ferrous-oxide 9.81 6.63 -3.18 -0.795 0.54320E+04 240 silica-amorphous -2.09 -3.32 -1.23 -0.410 0.21022E+04 242 an20ab80 2.02 1.51 -0.51 -0.039 0.86524E+03 243 an25ab75 2.65 1.98 -0.66 -0.051 0.11285E+04 244 an30ab70 3.28 2.46 -0.82 -0.063 0.14014E+04 245 tr.625ac.25prg.125 45.16 40.63 -4.54 -0.122 0.77491E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 1.0000000 g Current total amount of reactant added: 20.9990000 g New total amount of reactant added: 21.9990000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.2990E-12 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 9 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 21.9990000 Water: Moles liquid = 0.5535E+02 kg liquid = 0.9971E+00 Moles total = 0.5523E+02 kg total = 0.9950E+00 Activity = 1.0000 Stoichiometric ionic strength = .5108209E-02 Osmotic coef. = 0.9620 True ionic strength = .9239852E-02 Chg. balance for total moles = 0.2990E-12 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.14984E-09 -9.8244 0.13141E-09 -9.8814 0.87701E+00 -0.0570 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13805E-03 -3.8600 0.12069E-03 -3.9183 0.87421E+00 -0.0584 4 SO4-- 0.25560E-04 -4.5924 0.15854E-04 -4.7999 0.62027E+00 -0.2074 5 HCO3- 0.67600E-05 -5.1701 0.59142E-05 -5.2281 0.87488E+00 -0.0581 6 HS- 0.18987E-11 -11.7216 0.16600E-11 -11.7799 0.87427E+00 -0.0584 7 Al+++ 0.39309E-27 -27.4055 0.13629E-27 -27.8655 0.34671E+00 -0.4600 8 H4SiO4 0.48375E-03 -3.3154 0.48375E-03 -3.3154 0.10000E+01 0.0000 9 Ca++ 0.37562E-07 -7.4252 0.23209E-07 -7.6343 0.61787E+00 -0.2091 10 Mg++ 0.21635E-10 -10.6649 0.13335E-10 -10.8750 0.61638E+00 -0.2102 11 Fe++ 0.11902E-12 -12.9244 0.73401E-13 -13.1343 0.61673E+00 -0.2099 12 K+ 0.72055E-04 -4.1423 0.63048E-04 -4.2003 0.87500E+00 -0.0580 13 Na+ 0.91352E-02 -2.0393 0.79854E-02 -2.0977 0.87413E+00 -0.0584 14 Mn++ 0.17136E-10 -10.7661 0.10573E-10 -10.9758 0.61700E+00 -0.2097 15 HPO4-- 0.50695E-06 -6.2950 0.31447E-06 -6.5024 0.62032E+00 -0.2074 16 HSiO3- 0.39320E-02 -2.4054 0.34374E-02 -2.4638 0.87421E+00 -0.0584 17 Ca(HSiO3)+ 0.20761E-08 -8.6827 0.18168E-08 -8.7407 0.87510E+00 -0.0579 18 Mg(HSiO3)+ 0.14846E-11 -11.8284 0.12991E-11 -11.8863 0.87510E+00 -0.0579 19 NaHSiO3,aq 0.44395E-03 -3.3527 0.44395E-03 -3.3527 0.10000E+01 0.0000 20 AlO+ 0.12270E-14 -14.9112 0.10737E-14 -14.9691 0.87510E+00 -0.0579 22 HAlO2,aq 0.16272E-08 -8.7886 0.16272E-08 -8.7886 0.10000E+01 0.0000 23 AlO2- 0.31384E-04 -4.5033 0.27410E-04 -4.5621 0.87336E+00 -0.0588 24 CH4,aq 0.60245E-18 -18.2201 0.60150E-18 -18.2208 0.99843E+00 -0.0007 29 CO,aq 0.84455E-19 -19.0734 0.84455E-19 -19.0734 0.10000E+01 0.0000 30 CO2,aq 0.16633E-08 -8.7790 0.16607E-08 -8.7797 0.99843E+00 -0.0007 31 CO3-2 0.63449E-05 -5.1976 0.39311E-05 -5.4055 0.61957E+00 -0.2079 32 CaCO3,aq 0.11440E-08 -8.9416 0.11440E-08 -8.9416 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.40038E-11 -11.3975 0.35038E-11 -11.4555 0.87510E+00 -0.0579 34 CaCl+ 0.51799E-11 -11.2857 0.45329E-11 -11.3436 0.87510E+00 -0.0579 35 CaCl2,aq 0.12997E-15 -15.8862 0.12997E-15 -15.8862 0.10000E+01 0.0000 36 CaOH+ 0.14384E-07 -7.8421 0.12587E-07 -7.9001 0.87510E+00 -0.0579 37 CaSO4,aq 0.11684E-09 -9.9324 0.11684E-09 -9.9324 0.10000E+01 0.0000 38 HCl,aq 0.29062E-14 -14.5367 0.29062E-14 -14.5367 0.10000E+01 0.0000 43 FeCl+ 0.16023E-16 -16.7953 0.14022E-16 -16.8532 0.87510E+00 -0.0579 46 FeO,aq 0.16520E-09 -9.7820 0.16520E-09 -9.7820 0.10000E+01 0.0000 47 FeOH+ 0.20777E-10 -10.6824 0.18182E-10 -10.7404 0.87510E+00 -0.0579 48 HFeO2- 0.15047E-07 -7.8226 0.13154E-07 -7.8809 0.87421E+00 -0.0584 49 FeO+ 0.11014E-14 -14.9580 0.96386E-15 -15.0160 0.87510E+00 -0.0579 51 FeO2- 0.13065E-07 -7.8839 0.11421E-07 -7.9423 0.87421E+00 -0.0584 52 HFeO2,aq 0.19089E-09 -9.7192 0.19089E-09 -9.7192 0.10000E+01 0.0000 53 H2,aq 0.20277E-08 -8.6930 0.20245E-08 -8.6937 0.99843E+00 -0.0007 54 KCl,aq 0.13791E-09 -9.8604 0.13791E-09 -9.8604 0.10000E+01 0.0000 55 KHSO4,aq 0.37139E-18 -18.4302 0.37139E-18 -18.4302 0.10000E+01 0.0000 56 KOH,aq 0.20490E-06 -6.6885 0.20490E-06 -6.6885 0.10000E+01 0.0000 57 KSO4- 0.17743E-07 -7.7510 0.15511E-07 -7.8094 0.87421E+00 -0.0584 58 MgCO3,aq 0.16476E-12 -12.7831 0.16476E-12 -12.7831 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.23507E-14 -14.6288 0.20571E-14 -14.6868 0.87510E+00 -0.0579 60 MgCl+ 0.26975E-14 -14.5690 0.23605E-14 -14.6270 0.87510E+00 -0.0579 61 MgOH+ 0.45732E-10 -10.3398 0.40020E-10 -10.3977 0.87510E+00 -0.0579 63 MnO,aq 0.63407E-09 -9.1979 0.63407E-09 -9.1979 0.10000E+01 0.0000 64 MnOH+ 0.27802E-09 -9.5559 0.24329E-09 -9.6139 0.87510E+00 -0.0579 65 MnO2-2 0.19668E-11 -11.7062 0.12186E-11 -11.9141 0.61957E+00 -0.2079 66 HMnO2- 0.40131E-10 -10.3965 0.35083E-10 -10.4549 0.87421E+00 -0.0584 69 MnCl+ 0.89791E-14 -14.0468 0.78575E-14 -14.1047 0.87510E+00 -0.0579 70 MnSO4,aq 0.48392E-13 -13.3152 0.48392E-13 -13.3152 0.10000E+01 0.0000 71 NaCl,aq 0.31938E-06 -6.4957 0.31938E-06 -6.4957 0.10000E+01 0.0000 72 NaOH,aq 0.26109E-04 -4.5832 0.26109E-04 -4.5832 0.10000E+01 0.0000 74 OH- 0.50343E-02 -2.2981 0.43968E-02 -2.3569 0.87336E+00 -0.0588 79 HPO3-2 0.32022E-17 -17.4945 0.19840E-17 -17.7025 0.61957E+00 -0.2079 82 H3PO4,aq 0.37980E-16 -16.4204 0.37980E-16 -16.4204 0.10000E+01 0.0000 83 H2PO4- 0.87158E-09 -9.0597 0.76232E-09 -9.1179 0.87464E+00 -0.0582 84 PO4-3 0.54867E-08 -8.2607 0.19525E-08 -8.7094 0.35586E+00 -0.4487 87 H2P2O7-2 0.73546E-19 -19.1334 0.45567E-19 -19.3414 0.61957E+00 -0.2079 88 HP2O7-3 0.19962E-15 -15.6998 0.69239E-16 -16.1596 0.34685E+00 -0.4599 89 P2O7-4 0.80418E-15 -15.0946 0.12587E-15 -15.9001 0.15653E+00 -0.8054 90 H2S,aq 0.67523E-15 -15.1706 0.67416E-15 -15.1712 0.99843E+00 -0.0007 97 SO3-2 0.66807E-14 -14.1752 0.41710E-14 -14.3798 0.62433E+00 -0.2046 98 HSO3- 0.39256E-16 -16.4061 0.34318E-16 -16.4645 0.87421E+00 -0.0584 99 HSO4- 0.22932E-11 -11.6396 0.20078E-11 -11.6973 0.87554E+00 -0.0577 Charge balance for all species = 0.2986E-12 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.1498370E-09 -.9568555E-02 -.9637770E+01 0.0000 2 H2O 0.1000000E+01 0.5550900E+02 0.9993103E+06 0.0000 3 Cl- 0.1380535E-03 0.1383730E-03 0.4902300E+01 5.9630 4 SO4-- 0.2556033E-04 0.2557934E-04 0.2455470E+01 14.9629 5 HCO3- 0.6760035E-05 0.1310778E-04 0.7992394E+00 4.6533 6 HS- 0.1898668E-11 -.1148130E-08 -.3794434E-04 -1.8985 7 Al+++ 0.3930854E-27 0.3138603E-04 0.8462487E+00 1.7786 8 H4SiO4 0.4837543E-03 0.4859705E-02 0.4667651E+03 -3.3154 9 Ca++ 0.3756225E-07 0.5529228E-07 0.2214451E-02 12.1284 10 Mg++ 0.2163462E-10 0.6902079E-10 0.1676857E-05 8.8877 11 Fe++ 0.1190159E-12 0.2848848E-07 0.1589881E-02 6.6285 12 K+ 0.7205469E-04 0.7227747E-04 0.2824213E+01 5.6810 13 Na+ 0.9135239E-02 0.9605615E-02 0.2206764E+03 7.7837 14 Mn++ 0.1713573E-10 0.9713786E-09 0.5332820E-04 8.7869 15 HPO4-- 0.5069537E-06 0.5133120E-06 0.4923264E-01 13.2603 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.3642577E+00 -.9540976E-02 -.3547168E+00 0.0000000E+00 2 H2O 0.5523248E+02 0.5534901E+02 -.1165229E+00 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.6351718E-03 0.2550561E-04 0.6096661E-03 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.6096673E-03 -.1144821E-08 -.6096661E-03 0.0000000E+00 7 Al+++ 0.7173305E-01 0.3129557E-04 0.7170176E-01 0.0000000E+00 8 H4SiO4 0.2290708E+00 0.4845698E-02 0.2242251E+00 0.0000000E+00 9 Ca++ 0.2531646E-01 0.5513291E-07 0.2531640E-01 0.0000000E+00 10 Mg++ 0.1745952E-01 0.6882185E-10 0.1745952E-01 0.0000000E+00 11 Fe++ 0.1568548E-01 0.2840637E-07 0.1568545E-01 0.0000000E+00 12 K+ 0.4670701E-02 0.7206915E-04 0.4598631E-02 0.0000000E+00 13 Na+ 0.2777418E-01 0.9577929E-02 0.1819625E-01 0.0000000E+00 14 Mn++ 0.3814318E-03 0.9685789E-09 0.3814308E-03 0.0000000E+00 15 HPO4-- 0.1301808E-03 0.5118325E-06 0.1296689E-03 0.0000000E+00 Chg. balance for solid moles: 0.2206E-16 Mass of aqueous solution: 0.997817E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 21.9990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 0.1807E-01 -1.743 4.738 0.676 19.73 1.819 andradite 0.2052E-02 -2.688 1.043 0.018 4.343 0.2709 grossular 0.9197E-04 -4.036 0.4143E-01 -1.383 0.1725 0.1153E-01 apatite-OH 0.4322E-04 -4.364 0.2171E-01 -1.663 0.9041E-01 0.6899E-02 clinochlore 0.3492E-02 -2.457 1.941 0.288 8.082 0.7383 daphnite 0.2017E-02 -2.695 1.439 0.158 5.992 0.4360 chlorite-Mn 0.7629E-04 -4.118 0.5408E-01 -1.267 0.2252 0.1724E-01 microcline 0.4526E-02 -2.344 1.260 0.100 5.246 0.4921 stilbite 0.1867E-01 -1.729 13.16 1.119 54.78 6.136 stilpnomelane-Fe 0.1450E-03 -3.839 0.1563 -0.806 0.6509 0.5399E-01 nontronite-Na 0.3865E-03 -3.413 0.1644 -0.784 0.6845 0.5106E-01 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.9571E+00 0.9571E+00 1.0000 -0.019 grossular 0.4290E-01 0.4290E-01 1.0000 -1.368 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.6252E+00 0.6252E+00 1.0000 -0.204 daphnite 0.3611E+00 0.3611E+00 1.0000 -0.442 chlorite-Mn 0.1366E-01 0.1366E-01 1.0000 -1.865 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 nontronite-Na 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 24.013973 g Volume = 10.032891 cm3 Porosity: -2.3806% V(tot) - V(min): -.23329E+00 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 21.9990000 g log = 1.3424 Original solution: 1000.0103000 g Original solution / Rock added: 45.46 (Water/Rock Ratio), log = 1.6576 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0203 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.1000E+01 0.9860 0.1006E+01 0.1020E+01 CO2,gas 0.1729E-06 1.0071 0.1777E-06 0.1764E-06 CH4,gas 0.8570E-15 1.0125 0.8854E-15 0.8744E-15 H2,gas 0.2604E-05 1.0005 0.2658E-05 0.2656E-05 H2S,gas 0.1824E-13 0.9960 0.1853E-13 0.1861E-13 S2,gas 0.1789E-35 1.0000 0.1825E-35 0.1825E-35 CO,gas 0.1234E-15 1.0000 0.1259E-15 0.1259E-15 SO3,gas 0.1015E-39 1.0000 0.1035E-39 0.1035E-39 SO2,gas 0.1049E-22 1.0000 0.1070E-22 0.1070E-22 HCl,gas 0.5026E-17 1.0000 0.5128E-17 0.5128E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 16 albite -0.38 -0.38 0.00 0.000 -0.94784E-12 22 andradite 39.01 39.01 0.00 0.000 0.00000E+00 23 grossular 32.73 32.73 0.00 0.000 0.12132E-10 32 apatite-OH -18.15 -18.15 0.00 0.000 -0.12132E-10 46 clinochlore 39.07 39.07 0.00 0.000 -0.24265E-10 47 daphnite 28.97 28.97 0.00 0.000 -0.42463E-10 48 chlorite-Mn 46.87 46.87 0.00 0.000 -0.24265E-10 116 microcline -2.49 -2.49 0.00 0.000 -0.10616E-10 163 stilbite -7.52 -7.52 0.00 0.000 -0.90992E-11 164 stilpnomelane-Fe 13.02 13.02 0.00 0.000 0.21232E-10 209 nontronite-Na 3.52 3.52 0.00 0.000 -0.75827E-11 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -15.11 -8.45 -2.816 0.14427E+05 -6.750 3 CH4,gas 4.54 -12.21 -16.75 -4.188 0.28603E+05 -15.053 4 H2,gas 8.00 0.73 -7.27 -4.157 0.12421E+05 -5.575 5 H2S,gas -6.23 -21.66 -15.43 -7.716 0.26348E+05 -13.732 6 S2,gas -7.34 -44.77 -37.44 -5.760 0.63924E+05 -35.739 7 CO,gas 3.21 -14.38 -17.60 -5.415 0.30050E+05 -15.900 8 SO3,gas 17.12 -24.56 -41.68 -10.421 0.71174E+05 -39.985 9 SO2,gas 0.83 -23.84 -24.67 -6.579 0.42122E+05 -22.970 10 HCl,gas 5.19 -13.80 -18.99 -9.495 0.32423E+05 -17.290 11 acmite 7.71 7.42 -0.29 -0.030 0.49687E+03 15 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 19 spessartine 24.46 19.97 -4.49 -0.224 0.76588E+04 20 analcite 3.32 2.93 -0.39 -0.043 0.66652E+03 21 andalusite 5.00 0.24 -4.76 -0.476 0.81271E+04 26 annite 20.12 17.40 -2.72 -0.151 0.46520E+04 27 phlogopite 27.06 24.18 -2.89 -0.160 0.49309E+04 29 anorthite 12.71 9.05 -3.66 -0.281 0.62417E+04 35 aragonite 0.97 -2.98 -3.95 -1.316 0.67404E+04 36 brucite 12.57 8.89 -3.68 -0.736 0.62849E+04 37 calcite 0.81 -2.98 -3.79 -1.264 0.64762E+04 38 carnegieite-low 9.02 6.25 -2.78 -0.397 0.47406E+04 39 carnegieite-high 10.09 6.25 -3.85 -0.549 0.65676E+04 40 carpholite-Mg 8.58 5.81 -2.77 -0.185 0.47262E+04 41 carpholite-Fe 6.71 3.55 -3.16 -0.211 0.53918E+04 42 celadonite 5.34 3.09 -2.26 -0.133 0.38516E+04 43 celadonite-Fe 3.88 0.83 -3.05 -0.179 0.52077E+04 44 chrysotile 23.89 20.03 -3.86 -0.322 0.65907E+04 50 chloritoid-Mg 13.20 9.13 -4.07 -0.271 0.69463E+04 51 chloritoid-Fe 9.17 6.87 -2.30 -0.154 0.39329E+04 52 chloritoid-Mn 11.40 9.03 -2.37 -0.158 0.40507E+04 54 coesite -2.38 -3.32 -0.94 -0.313 0.16039E+04 59 corundum 8.38 3.56 -4.83 -0.439 0.82402E+04 61 cristobalite -2.56 -3.32 -0.76 -0.252 0.12892E+04 63 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71234E+04 65 diaspore 2.87 1.78 -1.10 -0.183 0.18699E+04 67 diopside 16.18 14.39 -1.80 -0.180 0.30665E+04 68 hedenbergite 14.21 12.13 -2.08 -0.208 0.35552E+04 75 epidote 24.67 24.13 -0.54 -0.026 0.91567E+03 76 clinozoisite 22.81 19.65 -3.16 -0.144 0.53949E+04 77 epidote-Fe 29.84 28.62 -1.22 -0.063 0.20830E+04 78 fayalite 14.05 9.94 -4.10 -0.586 0.70078E+04 79 ferrosilite 11.15 6.63 -4.52 -0.452 0.77234E+04 83 gibbsite 4.08 1.78 -2.30 -0.329 0.39284E+04 84 glaucophane 22.97 19.26 -3.71 -0.100 0.63348E+04 85 glaucophane-Fe 17.28 12.49 -4.79 -0.129 0.81770E+04 87 greenalite 16.14 13.25 -2.88 -0.240 0.49259E+04 90 hematite 12.57 12.53 -0.03 -0.004 0.59082E+02 91 heulandite -5.83 -7.52 -1.69 -0.077 0.28938E+04 95 jadeite 4.22 2.93 -1.28 -0.128 0.21920E+04 96 julgoldite 70.43 66.94 -3.49 -0.091 0.59514E+04 97 kalsilite 7.58 4.14 -3.44 -0.491 0.58731E+04 98 kaolinite -1.33 -3.07 -1.74 -0.158 0.29724E+04 99 kyanite 4.88 0.24 -4.63 -0.463 0.79130E+04 101 laumontite 2.88 2.42 -0.46 -0.031 0.78431E+03 102 lawsonite 9.62 9.05 -0.56 -0.037 0.95832E+03 103 leucite 4.12 0.83 -3.29 -0.329 0.56176E+04 105 lizardite 23.24 20.03 -3.21 -0.268 0.54833E+04 107 magnetite 20.09 19.16 -0.93 -0.076 0.15834E+04 108 minnesotaite 10.39 6.62 -3.76 -0.221 0.64273E+04 110 magnesioferrite 26.21 21.42 -4.79 -0.391 0.81840E+04 113 margarite 17.32 12.61 -4.71 -0.188 0.80450E+04 120 muscovite 2.58 1.07 -1.51 -0.089 0.25813E+04 121 paragonite 4.24 3.17 -1.07 -0.063 0.18204E+04 122 nepheline 8.34 6.25 -2.09 -0.299 0.35730E+04 128 periclase-Fe 11.63 6.63 -5.00 -1.250 0.85342E+04 134 phlogopite-Na 29.65 26.28 -3.37 -0.187 0.57497E+04 136 prehnite 19.37 17.87 -1.50 -0.088 0.25681E+04 137 prehnite-Fe 22.50 22.36 -0.14 -0.009 0.24384E+03 138 pumpellyite-Fe 46.27 44.14 -2.13 -0.047 0.36312E+04 139 pumpellyite-Mg 48.99 46.40 -2.59 -0.058 0.44272E+04 145 pyroxmangite 7.40 5.47 -1.93 -0.385 0.32905E+04 146 pyrophyllite -6.18 -9.70 -3.53 -0.221 0.60249E+04 147 quartz -2.99 -3.32 -0.33 -0.109 0.55653E+03 152 rhodonite 7.45 5.47 -1.97 -0.395 0.33707E+04 153 sanidine -1.28 -2.49 -1.21 -0.093 0.20677E+04 165 stilpnomelane-Mg 27.44 24.31 -3.13 -0.093 0.53409E+04 171 talc 16.49 13.40 -3.09 -0.182 0.52749E+04 174 tephroite 18.09 14.26 -3.83 -0.547 0.65350E+04 177 topaz-H 4.62 0.24 -4.38 -0.398 0.74731E+04 178 tridymite -2.63 -3.32 -0.69 -0.230 0.11765E+04 187 wairakite 3.95 2.42 -1.53 -0.090 0.26063E+04 188 walstromite 11.51 8.81 -2.70 -0.539 0.46037E+04 189 wollastonite 10.46 8.81 -1.65 -0.330 0.28141E+04 190 pseudo-wollastonite 11.00 8.81 -2.19 -0.437 0.37339E+04 191 zoisite 22.85 19.65 -3.20 -0.146 0.54690E+04 192 akaganeite 7.75 6.27 -1.49 -0.322 0.25421E+04 193 beidellite-Ca -1.65 -6.02 -4.38 -0.271 0.74728E+04 195 beidellite-K -1.52 -6.15 -4.63 -0.283 0.79028E+04 196 beidellite-Mg -1.79 -6.56 -4.77 -0.295 0.81396E+04 197 beidellite-Na -1.34 -5.45 -4.11 -0.252 0.70219E+04 199 chalcedony -2.80 -3.32 -0.51 -0.171 0.87583E+03 201 montmorillonite-Ca -2.29 -5.36 -3.07 -0.190 0.52358E+04 202 montmorillonite-K -2.24 -5.48 -3.25 -0.199 0.55439E+04 203 montmorillonite-Mg -2.48 -5.89 -3.41 -0.211 0.58258E+04 204 montmorillonite-Na -2.04 -4.79 -2.75 -0.169 0.46988E+04 205 nontronite-Ca 3.21 2.95 -0.26 -0.017 0.44781E+03 206 nontronite-H 2.53 0.95 -1.58 -0.106 0.27006E+04 207 nontronite-K 3.34 2.83 -0.51 -0.033 0.87912E+03 208 nontronite-Mg 3.07 2.42 -0.66 -0.043 0.11219E+04 224 tobermorite 9.82 6.79 -3.04 -0.828 0.51830E+04 233 boehmite 4.41 1.78 -2.63 -0.438 0.44868E+04 235 ferrous-oxide 9.81 6.63 -3.18 -0.796 0.54351E+04 240 silica-amorphous -2.09 -3.32 -1.22 -0.408 0.20900E+04 242 an20ab80 2.02 1.50 -0.51 -0.040 0.87748E+03 243 an25ab75 2.65 1.98 -0.67 -0.052 0.11438E+04 244 an30ab70 3.28 2.45 -0.83 -0.064 0.14198E+04 245 tr.625ac.25prg.125 45.16 40.71 -4.46 -0.120 0.76128E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 1.0000000 g Current total amount of reactant added: 21.9990000 g New total amount of reactant added: 22.9990000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.2991E-12 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 9 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 22.9990000 Water: Moles liquid = 0.5534E+02 kg liquid = 0.9970E+00 Moles total = 0.5522E+02 kg total = 0.9948E+00 Activity = 1.0000 Stoichiometric ionic strength = .5140527E-02 Osmotic coef. = 0.9619 True ionic strength = .9308640E-02 Chg. balance for total moles = 0.2991E-12 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.14982E-09 -9.8244 0.13135E-09 -9.8816 0.87669E+00 -0.0572 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13807E-03 -3.8599 0.12065E-03 -3.9185 0.87387E+00 -0.0586 4 SO4-- 0.25563E-04 -4.5924 0.15832E-04 -4.8005 0.61935E+00 -0.2081 5 HCO3- 0.67556E-05 -5.1703 0.59081E-05 -5.2286 0.87455E+00 -0.0582 6 HS- 0.21741E-11 -11.6627 0.19001E-11 -11.7212 0.87394E+00 -0.0585 7 Al+++ 0.37280E-27 -27.4285 0.12882E-27 -27.8900 0.34554E+00 -0.4615 8 H4SiO4 0.49146E-03 -3.3085 0.49146E-03 -3.3085 0.10000E+01 0.0000 9 Ca++ 0.37556E-07 -7.4253 0.23170E-07 -7.6351 0.61694E+00 -0.2098 10 Mg++ 0.22123E-10 -10.6552 0.13615E-10 -10.8660 0.61544E+00 -0.2108 11 Fe++ 0.11860E-12 -12.9259 0.73034E-13 -13.1365 0.61580E+00 -0.2106 12 K+ 0.72592E-04 -4.1391 0.63495E-04 -4.1973 0.87467E+00 -0.0582 13 Na+ 0.92035E-02 -2.0360 0.80420E-02 -2.0946 0.87380E+00 -0.0586 14 Mn++ 0.17522E-10 -10.7564 0.10795E-10 -10.9668 0.61607E+00 -0.2104 15 HPO4-- 0.50881E-06 -6.2934 0.31516E-06 -6.5015 0.61940E+00 -0.2080 16 HSiO3- 0.39981E-02 -2.3982 0.34938E-02 -2.4567 0.87387E+00 -0.0586 17 Ca(HSiO3)+ 0.21075E-08 -8.6762 0.18435E-08 -8.7343 0.87477E+00 -0.0581 18 Mg(HSiO3)+ 0.15412E-11 -11.8121 0.13482E-11 -11.8702 0.87477E+00 -0.0581 19 NaHSiO3,aq 0.45443E-03 -3.3425 0.45443E-03 -3.3425 0.10000E+01 0.0000 20 AlO+ 0.11612E-14 -14.9351 0.10158E-14 -14.9932 0.87477E+00 -0.0581 22 HAlO2,aq 0.15402E-08 -8.8124 0.15402E-08 -8.8124 0.10000E+01 0.0000 23 AlO2- 0.29732E-04 -4.5268 0.25957E-04 -4.5858 0.87303E+00 -0.0590 24 CH4,aq 0.68983E-18 -18.1613 0.68874E-18 -18.1619 0.99842E+00 -0.0007 29 CO,aq 0.87265E-19 -19.0592 0.87265E-19 -19.0592 0.10000E+01 0.0000 30 CO2,aq 0.16608E-08 -8.7797 0.16581E-08 -8.7804 0.99842E+00 -0.0007 31 CO3-2 0.63508E-05 -5.1972 0.39289E-05 -5.4057 0.61865E+00 -0.2086 32 CaCO3,aq 0.11414E-08 -8.9425 0.11414E-08 -8.9425 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.39945E-11 -11.3985 0.34942E-11 -11.4566 0.87477E+00 -0.0581 34 CaCl+ 0.51716E-11 -11.2864 0.45240E-11 -11.3445 0.87477E+00 -0.0581 35 CaCl2,aq 0.12968E-15 -15.8871 0.12968E-15 -15.8871 0.10000E+01 0.0000 36 CaOH+ 0.14372E-07 -7.8425 0.12572E-07 -7.9006 0.87477E+00 -0.0581 37 CaSO4,aq 0.11649E-09 -9.9337 0.11649E-09 -9.9337 0.10000E+01 0.0000 38 HCl,aq 0.29039E-14 -14.5370 0.29039E-14 -14.5370 0.10000E+01 0.0000 43 FeCl+ 0.15944E-16 -16.7974 0.13948E-16 -16.8555 0.87477E+00 -0.0581 46 FeO,aq 0.16453E-09 -9.7837 0.16453E-09 -9.7837 0.10000E+01 0.0000 47 FeOH+ 0.20691E-10 -10.6842 0.18100E-10 -10.7423 0.87477E+00 -0.0581 48 HFeO2- 0.14999E-07 -7.8239 0.13107E-07 -7.8825 0.87387E+00 -0.0586 49 FeO+ 0.10782E-14 -14.9673 0.94321E-15 -15.0254 0.87477E+00 -0.0581 51 FeO2- 0.12802E-07 -7.8927 0.11187E-07 -7.9513 0.87387E+00 -0.0586 52 HFeO2,aq 0.18688E-09 -9.7284 0.18688E-09 -9.7284 0.10000E+01 0.0000 53 H2,aq 0.20983E-08 -8.6781 0.20950E-08 -8.6788 0.99842E+00 -0.0007 54 KCl,aq 0.13885E-09 -9.8575 0.13885E-09 -9.8575 0.10000E+01 0.0000 55 KHSO4,aq 0.37332E-18 -18.4279 0.37332E-18 -18.4279 0.10000E+01 0.0000 56 KOH,aq 0.20644E-06 -6.6852 0.20644E-06 -6.6852 0.10000E+01 0.0000 57 KSO4- 0.17851E-07 -7.7483 0.15599E-07 -7.8069 0.87387E+00 -0.0586 58 MgCO3,aq 0.16813E-12 -12.7744 0.16813E-12 -12.7744 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.23985E-14 -14.6201 0.20981E-14 -14.6782 0.87477E+00 -0.0581 60 MgCl+ 0.27544E-14 -14.5600 0.24094E-14 -14.6181 0.87477E+00 -0.0581 61 MgOH+ 0.46732E-10 -10.3304 0.40880E-10 -10.3885 0.87477E+00 -0.0581 63 MnO,aq 0.64800E-09 -9.1884 0.64800E-09 -9.1884 0.10000E+01 0.0000 64 MnOH+ 0.28410E-09 -9.5465 0.24852E-09 -9.6046 0.87477E+00 -0.0581 65 MnO2-2 0.20150E-11 -11.6957 0.12466E-11 -11.9043 0.61865E+00 -0.2086 66 HMnO2- 0.41048E-10 -10.3867 0.35871E-10 -10.4453 0.87387E+00 -0.0586 69 MnCl+ 0.91685E-14 -14.0377 0.80203E-14 -14.0958 0.87477E+00 -0.0581 70 MnSO4,aq 0.49340E-13 -13.3068 0.49340E-13 -13.3068 0.10000E+01 0.0000 71 NaCl,aq 0.32156E-06 -6.4927 0.32156E-06 -6.4927 0.10000E+01 0.0000 72 NaOH,aq 0.26306E-04 -4.5799 0.26306E-04 -4.5799 0.10000E+01 0.0000 74 OH- 0.50386E-02 -2.2977 0.43989E-02 -2.3567 0.87303E+00 -0.0590 79 HPO3-2 0.33259E-17 -17.4781 0.20576E-17 -17.6866 0.61865E+00 -0.2086 82 H3PO4,aq 0.38026E-16 -16.4199 0.38026E-16 -16.4199 0.10000E+01 0.0000 83 H2PO4- 0.87339E-09 -9.0588 0.76362E-09 -9.1171 0.87431E+00 -0.0583 84 PO4-3 0.55190E-08 -8.2581 0.19577E-08 -8.7083 0.35472E+00 -0.4501 87 H2P2O7-2 0.73907E-19 -19.1313 0.45722E-19 -19.3399 0.61865E+00 -0.2086 88 HP2O7-3 0.20107E-15 -15.6966 0.69508E-16 -16.1580 0.34568E+00 -0.4613 89 P2O7-4 0.81248E-15 -15.0902 0.12642E-15 -15.8982 0.15560E+00 -0.8080 90 H2S,aq 0.77254E-15 -15.1121 0.77131E-15 -15.1128 0.99842E+00 -0.0007 97 SO3-2 0.69139E-14 -14.1603 0.43103E-14 -14.3655 0.62343E+00 -0.2052 98 HSO3- 0.40564E-16 -16.3919 0.35447E-16 -16.4504 0.87387E+00 -0.0586 99 HSO4- 0.22898E-11 -11.6402 0.20041E-11 -11.6981 0.87522E+00 -0.0579 Charge balance for all species = 0.2988E-12 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.1498199E-09 -.9643034E-02 -.9712705E+01 0.0000 2 H2O 0.1000000E+01 0.5550892E+02 0.9993005E+06 0.0000 3 Cl- 0.1380663E-03 0.1383880E-03 0.4902791E+01 5.9631 4 SO4-- 0.2556300E-04 0.2558207E-04 0.2455711E+01 14.9627 5 HCO3- 0.6755568E-05 0.1310920E-04 0.7993195E+00 4.6530 6 HS- 0.2174130E-11 -.1096834E-08 -.3624878E-04 -1.8396 7 Al+++ 0.3727959E-27 0.2973335E-04 0.8016812E+00 1.7547 8 H4SiO4 0.4914615E-03 0.4943960E-02 0.4748536E+03 -3.3085 9 Ca++ 0.3755564E-07 0.5530202E-07 0.2214822E-02 12.1281 10 Mg++ 0.2212277E-10 0.7056933E-10 0.1714464E-05 8.8972 11 Fe++ 0.1186012E-12 0.2817268E-07 0.1572244E-02 6.6267 12 K+ 0.7259247E-04 0.7281691E-04 0.2845267E+01 5.6843 13 Na+ 0.9203478E-02 0.9684538E-02 0.2224877E+03 7.7869 14 Mn++ 0.1752225E-10 0.9927465E-09 0.5450082E-04 8.7964 15 HPO4-- 0.5088119E-06 0.5152043E-06 0.4941371E-01 13.2617 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.3808163E+00 -.9614196E-02 -.3712021E+00 0.0000000E+00 2 H2O 0.5521995E+02 0.5534292E+02 -.1229717E+00 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.6628852E-03 0.2550556E-04 0.6373796E-03 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.6373807E-03 -.1093554E-08 -.6373796E-03 0.0000000E+00 7 Al+++ 0.7499380E-01 0.2964443E-04 0.7496415E-01 0.0000000E+00 8 H4SiO4 0.2394836E+00 0.4929175E-02 0.2345544E+00 0.0000000E+00 9 Ca++ 0.2646660E-01 0.5513664E-07 0.2646655E-01 0.0000000E+00 10 Mg++ 0.1825317E-01 0.7035829E-10 0.1825317E-01 0.0000000E+00 11 Fe++ 0.1639848E-01 0.2808843E-07 0.1639846E-01 0.0000000E+00 12 K+ 0.4883015E-02 0.7259915E-04 0.4810416E-02 0.0000000E+00 13 Na+ 0.2902942E-01 0.9655576E-02 0.1937384E-01 0.0000000E+00 14 Mn++ 0.3987704E-03 0.9897776E-09 0.3987694E-03 0.0000000E+00 15 HPO4-- 0.1360983E-03 0.5136635E-06 0.1355847E-03 0.0000000E+00 Chg. balance for solid moles: -.1095E-16 Mass of aqueous solution: 0.997717E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 22.9990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 0.1926E-01 -1.715 5.050 0.703 20.11 1.939 andradite 0.2200E-02 -2.658 1.118 0.048 4.452 0.2904 grossular 0.9531E-04 -4.021 0.4293E-01 -1.367 0.1710 0.1195E-01 apatite-OH 0.4519E-04 -4.345 0.2270E-01 -1.644 0.9043E-01 0.7214E-02 clinochlore 0.3651E-02 -2.438 2.029 0.307 8.082 0.7718 daphnite 0.2055E-02 -2.687 1.466 0.166 5.839 0.4442 chlorite-Mn 0.7975E-04 -4.098 0.5654E-01 -1.248 0.2252 0.1802E-01 microcline 0.4708E-02 -2.327 1.310 0.117 5.219 0.5119 stilbite 0.1936E-01 -1.713 13.64 1.135 54.33 6.362 stilpnomelane-Fe 0.2053E-03 -3.688 0.2213 -0.655 0.8815 0.7644E-01 nontronite-Na 0.3499E-03 -3.456 0.1488 -0.827 0.5926 0.4622E-01 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.9585E+00 0.9585E+00 1.0000 -0.018 grossular 0.4153E-01 0.4153E-01 1.0000 -1.382 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.6311E+00 0.6311E+00 1.0000 -0.200 daphnite 0.3552E+00 0.3552E+00 1.0000 -0.450 chlorite-Mn 0.1379E-01 0.1379E-01 1.0000 -1.861 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 nontronite-Na 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 25.105820 g Volume = 10.478832 cm3 Porosity: -2.7377% V(tot) - V(min): -.27923E+00 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 22.9990000 g log = 1.3617 Original solution: 1000.0103000 g Original solution / Rock added: 43.48 (Water/Rock Ratio), log = 1.6383 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0203 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.1000E+01 0.9860 0.1006E+01 0.1020E+01 CO2,gas 0.1726E-06 1.0071 0.1774E-06 0.1762E-06 CH4,gas 0.9813E-15 1.0125 0.1014E-14 0.1001E-14 H2,gas 0.2694E-05 1.0005 0.2750E-05 0.2749E-05 H2S,gas 0.2086E-13 0.9960 0.2120E-13 0.2129E-13 S2,gas 0.2186E-35 1.0000 0.2231E-35 0.2231E-35 CO,gas 0.1275E-15 1.0000 0.1300E-15 0.1300E-15 SO3,gas 0.1012E-39 1.0000 0.1033E-39 0.1033E-39 SO2,gas 0.1083E-22 1.0000 0.1105E-22 0.1105E-22 HCl,gas 0.5022E-17 1.0000 0.5124E-17 0.5124E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 16 albite -0.38 -0.38 0.00 0.000 -0.94784E-12 22 andradite 39.01 39.01 0.00 0.000 -0.24265E-10 23 grossular 32.73 32.73 0.00 0.000 -0.12132E-10 32 apatite-OH -18.15 -18.15 0.00 0.000 0.00000E+00 46 clinochlore 39.07 39.07 0.00 0.000 0.12132E-10 47 daphnite 28.97 28.97 0.00 0.000 -0.12132E-10 48 chlorite-Mn 46.87 46.87 0.00 0.000 0.12132E-10 116 microcline -2.49 -2.49 0.00 0.000 0.15165E-11 163 stilbite -7.52 -7.52 0.00 0.000 -0.90992E-11 164 stilpnomelane-Fe 13.02 13.02 0.00 0.000 -0.75827E-10 209 nontronite-Na 3.52 3.52 0.00 0.000 0.15165E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -15.11 -8.45 -2.817 0.14428E+05 -6.751 3 CH4,gas 4.54 -12.15 -16.69 -4.173 0.28503E+05 -14.994 4 H2,gas 8.00 0.74 -7.26 -4.148 0.12396E+05 -5.561 5 H2S,gas -6.23 -21.60 -15.37 -7.686 0.26248E+05 -13.674 6 S2,gas -7.34 -44.69 -37.35 -5.746 0.63775E+05 -35.652 7 CO,gas 3.21 -14.37 -17.58 -5.411 0.30026E+05 -15.886 8 SO3,gas 17.12 -24.56 -41.68 -10.421 0.71176E+05 -39.986 9 SO2,gas 0.83 -23.82 -24.66 -6.575 0.42099E+05 -22.957 10 HCl,gas 5.19 -13.80 -18.99 -9.495 0.32424E+05 -17.290 11 acmite 7.71 7.43 -0.28 -0.029 0.48355E+03 15 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 19 spessartine 24.46 19.97 -4.48 -0.224 0.76568E+04 20 analcite 3.32 2.92 -0.40 -0.044 0.67824E+03 21 andalusite 5.00 0.20 -4.80 -0.480 0.81969E+04 26 annite 20.12 17.39 -2.73 -0.152 0.46611E+04 27 phlogopite 27.06 24.21 -2.86 -0.159 0.48826E+04 29 anorthite 12.71 9.02 -3.69 -0.284 0.63003E+04 35 aragonite 0.97 -2.98 -3.95 -1.316 0.67421E+04 36 brucite 12.57 8.90 -3.67 -0.734 0.62688E+04 37 calcite 0.81 -2.98 -3.79 -1.265 0.64779E+04 38 carnegieite-low 9.02 6.23 -2.79 -0.399 0.47641E+04 39 carnegieite-high 10.09 6.23 -3.86 -0.551 0.65911E+04 40 carpholite-Mg 8.58 5.79 -2.79 -0.186 0.47681E+04 41 carpholite-Fe 6.71 3.52 -3.19 -0.213 0.54529E+04 42 celadonite 5.34 3.10 -2.24 -0.132 0.38237E+04 43 celadonite-Fe 3.88 0.83 -3.04 -0.179 0.51990E+04 44 chrysotile 23.89 20.07 -3.82 -0.318 0.65189E+04 50 chloritoid-Mg 13.20 9.10 -4.10 -0.273 0.69999E+04 51 chloritoid-Fe 9.17 6.83 -2.35 -0.156 0.40057E+04 52 chloritoid-Mn 11.40 9.00 -2.40 -0.160 0.41044E+04 54 coesite -2.38 -3.31 -0.93 -0.311 0.15921E+04 59 corundum 8.38 3.51 -4.87 -0.443 0.83217E+04 61 cristobalite -2.56 -3.31 -0.75 -0.249 0.12775E+04 63 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71234E+04 65 diaspore 2.87 1.75 -1.12 -0.186 0.19106E+04 67 diopside 16.18 14.41 -1.77 -0.177 0.30275E+04 68 hedenbergite 14.21 12.14 -2.07 -0.207 0.35354E+04 75 epidote 24.67 24.10 -0.57 -0.028 0.97881E+03 76 clinozoisite 22.81 19.59 -3.21 -0.146 0.54831E+04 77 epidote-Fe 29.84 28.60 -1.24 -0.065 0.21211E+04 78 fayalite 14.05 9.94 -4.10 -0.586 0.70021E+04 79 ferrosilite 11.15 6.64 -4.51 -0.451 0.77060E+04 83 gibbsite 4.08 1.75 -2.32 -0.332 0.39692E+04 84 glaucophane 22.97 19.31 -3.67 -0.099 0.62630E+04 85 glaucophane-Fe 17.28 12.50 -4.78 -0.129 0.81626E+04 87 greenalite 16.14 13.26 -2.88 -0.240 0.49115E+04 90 hematite 12.57 12.51 -0.05 -0.006 0.90495E+02 91 heulandite -5.83 -7.52 -1.69 -0.077 0.28938E+04 95 jadeite 4.22 2.92 -1.29 -0.129 0.22037E+04 96 julgoldite 70.43 66.94 -3.49 -0.091 0.59521E+04 97 kalsilite 7.58 4.13 -3.45 -0.493 0.58966E+04 98 kaolinite -1.33 -3.11 -1.77 -0.161 0.30304E+04 99 kyanite 4.88 0.20 -4.68 -0.468 0.79828E+04 101 laumontite 2.88 2.40 -0.48 -0.032 0.81947E+03 102 lawsonite 9.62 9.02 -0.60 -0.040 0.10169E+04 103 leucite 4.12 0.82 -3.30 -0.330 0.56293E+04 105 lizardite 23.24 20.07 -3.17 -0.264 0.54115E+04 107 magnetite 20.09 19.14 -0.95 -0.077 0.16179E+04 108 minnesotaite 10.39 6.65 -3.74 -0.220 0.63895E+04 110 magnesioferrite 26.21 21.41 -4.80 -0.392 0.81993E+04 113 margarite 17.32 12.53 -4.79 -0.192 0.81851E+04 120 muscovite 2.58 1.02 -1.56 -0.092 0.26628E+04 121 paragonite 4.24 3.13 -1.11 -0.066 0.19019E+04 122 nepheline 8.34 6.23 -2.11 -0.301 0.35965E+04 128 periclase-Fe 11.63 6.63 -5.00 -1.250 0.85372E+04 134 phlogopite-Na 29.65 26.31 -3.34 -0.186 0.57014E+04 136 prehnite 19.37 17.84 -1.53 -0.090 0.26155E+04 137 prehnite-Fe 22.50 22.34 -0.16 -0.009 0.26622E+03 138 pumpellyite-Fe 46.27 44.06 -2.21 -0.049 0.37699E+04 139 pumpellyite-Mg 48.99 46.33 -2.66 -0.059 0.45467E+04 145 pyroxmangite 7.40 5.49 -1.91 -0.382 0.32626E+04 146 pyrophyllite -6.18 -9.72 -3.55 -0.222 0.60595E+04 147 quartz -2.99 -3.31 -0.32 -0.106 0.54481E+03 152 rhodonite 7.45 5.49 -1.96 -0.392 0.33429E+04 153 sanidine -1.28 -2.49 -1.21 -0.093 0.20677E+04 165 stilpnomelane-Mg 27.44 24.37 -3.07 -0.092 0.52453E+04 171 talc 16.49 13.46 -3.03 -0.178 0.51797E+04 174 tephroite 18.09 14.28 -3.80 -0.543 0.64910E+04 177 topaz-H 4.62 0.20 -4.42 -0.402 0.75429E+04 178 tridymite -2.63 -3.31 -0.68 -0.227 0.11648E+04 187 wairakite 3.95 2.40 -1.55 -0.091 0.26414E+04 188 walstromite 11.51 8.82 -2.69 -0.538 0.45925E+04 189 wollastonite 10.46 8.82 -1.64 -0.328 0.28029E+04 190 pseudo-wollastonite 11.00 8.82 -2.18 -0.436 0.37228E+04 191 zoisite 22.85 19.59 -3.25 -0.148 0.55572E+04 192 akaganeite 7.75 6.26 -1.50 -0.324 0.25578E+04 193 beidellite-Ca -1.65 -6.05 -4.41 -0.273 0.75248E+04 195 beidellite-K -1.52 -6.18 -4.66 -0.285 0.79529E+04 196 beidellite-Mg -1.79 -6.59 -4.80 -0.297 0.81889E+04 197 beidellite-Na -1.34 -5.48 -4.14 -0.254 0.70720E+04 199 chalcedony -2.80 -3.31 -0.51 -0.169 0.86411E+03 201 montmorillonite-Ca -2.29 -5.37 -3.08 -0.190 0.52517E+04 202 montmorillonite-K -2.24 -5.49 -3.26 -0.199 0.55579E+04 203 montmorillonite-Mg -2.48 -5.90 -3.42 -0.212 0.58390E+04 204 montmorillonite-Na -2.04 -4.80 -2.76 -0.169 0.47128E+04 205 nontronite-Ca 3.21 2.95 -0.26 -0.017 0.44975E+03 206 nontronite-H 2.53 0.95 -1.58 -0.106 0.27024E+04 207 nontronite-K 3.34 2.83 -0.51 -0.033 0.87912E+03 208 nontronite-Mg 3.07 2.42 -0.66 -0.043 0.11211E+04 224 tobermorite 9.82 6.79 -3.03 -0.826 0.51717E+04 233 boehmite 4.41 1.75 -2.65 -0.442 0.45275E+04 235 ferrous-oxide 9.81 6.63 -3.18 -0.796 0.54381E+04 240 silica-amorphous -2.09 -3.31 -1.22 -0.406 0.20783E+04 242 an20ab80 2.02 1.50 -0.52 -0.040 0.88920E+03 243 an25ab75 2.65 1.97 -0.68 -0.052 0.11585E+04 244 an30ab70 3.28 2.44 -0.84 -0.065 0.14374E+04 245 tr.625ac.25prg.125 45.16 40.78 -4.38 -0.118 0.74829E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 1.0000000 g Current total amount of reactant added: 22.9990000 g New total amount of reactant added: 23.9990000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.2991E-12 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 9 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 23.9990000 Water: Moles liquid = 0.5534E+02 kg liquid = 0.9969E+00 Moles total = 0.5521E+02 kg total = 0.9946E+00 Activity = 1.0000 Stoichiometric ionic strength = .5172392E-02 Osmotic coef. = 0.9618 True ionic strength = .9375393E-02 Chg. balance for total moles = 0.2991E-12 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.14981E-09 -9.8245 0.13129E-09 -9.8818 0.87639E+00 -0.0573 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13808E-03 -3.8599 0.12062E-03 -3.9186 0.87355E+00 -0.0587 4 SO4-- 0.25566E-04 -4.5923 0.15811E-04 -4.8010 0.61846E+00 -0.2087 5 HCO3- 0.67514E-05 -5.1706 0.59023E-05 -5.2290 0.87424E+00 -0.0584 6 HS- 0.24759E-11 -11.6063 0.21630E-11 -11.6649 0.87362E+00 -0.0587 7 Al+++ 0.35438E-27 -27.4505 0.12205E-27 -27.9135 0.34441E+00 -0.4629 8 H4SiO4 0.49897E-03 -3.3019 0.49897E-03 -3.3019 0.10000E+01 0.0000 9 Ca++ 0.37552E-07 -7.4254 0.23134E-07 -7.6358 0.61604E+00 -0.2104 10 Mg++ 0.22598E-10 -10.6459 0.13887E-10 -10.8574 0.61453E+00 -0.2115 11 Fe++ 0.11822E-12 -12.9273 0.72690E-13 -13.1385 0.61489E+00 -0.2112 12 K+ 0.73114E-04 -4.1360 0.63928E-04 -4.1943 0.87435E+00 -0.0583 13 Na+ 0.92697E-02 -2.0329 0.80969E-02 -2.0917 0.87348E+00 -0.0587 14 Mn++ 0.17899E-10 -10.7472 0.11011E-10 -10.9582 0.61517E+00 -0.2110 15 HPO4-- 0.51059E-06 -6.2919 0.31580E-06 -6.5006 0.61851E+00 -0.2087 16 HSiO3- 0.40623E-02 -2.3912 0.35486E-02 -2.4499 0.87355E+00 -0.0587 17 Ca(HSiO3)+ 0.21380E-08 -8.6700 0.18696E-08 -8.7283 0.87445E+00 -0.0583 18 Mg(HSiO3)+ 0.15973E-11 -11.7966 0.13968E-11 -11.8549 0.87445E+00 -0.0583 19 NaHSiO3,aq 0.46472E-03 -3.3328 0.46472E-03 -3.3328 0.10000E+01 0.0000 20 AlO+ 0.11016E-14 -14.9580 0.96326E-15 -15.0163 0.87445E+00 -0.0583 22 HAlO2,aq 0.14611E-08 -8.8353 0.14611E-08 -8.8353 0.10000E+01 0.0000 23 AlO2- 0.28228E-04 -4.5493 0.24634E-04 -4.6085 0.87270E+00 -0.0591 24 CH4,aq 0.78557E-18 -18.1048 0.78432E-18 -18.1055 0.99841E+00 -0.0007 29 CO,aq 0.90053E-19 -19.0455 0.90053E-19 -19.0455 0.10000E+01 0.0000 30 CO2,aq 0.16585E-08 -8.7803 0.16558E-08 -8.7810 0.99841E+00 -0.0007 31 CO3-2 0.63564E-05 -5.1968 0.39267E-05 -5.4060 0.61776E+00 -0.2092 32 CaCO3,aq 0.11390E-08 -8.9435 0.11390E-08 -8.9435 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.39858E-11 -11.3995 0.34854E-11 -11.4578 0.87445E+00 -0.0583 34 CaCl+ 0.51640E-11 -11.2870 0.45157E-11 -11.3453 0.87445E+00 -0.0583 35 CaCl2,aq 0.12940E-15 -15.8881 0.12940E-15 -15.8881 0.10000E+01 0.0000 36 CaOH+ 0.14361E-07 -7.8428 0.12558E-07 -7.9011 0.87445E+00 -0.0583 37 CaSO4,aq 0.11615E-09 -9.9350 0.11615E-09 -9.9350 0.10000E+01 0.0000 38 HCl,aq 0.29019E-14 -14.5373 0.29019E-14 -14.5373 0.10000E+01 0.0000 43 FeCl+ 0.15870E-16 -16.7994 0.13878E-16 -16.8577 0.87445E+00 -0.0583 46 FeO,aq 0.16389E-09 -9.7854 0.16389E-09 -9.7854 0.10000E+01 0.0000 47 FeOH+ 0.20609E-10 -10.6859 0.18022E-10 -10.7442 0.87445E+00 -0.0583 48 HFeO2- 0.14952E-07 -7.8253 0.13061E-07 -7.8840 0.87355E+00 -0.0587 49 FeO+ 0.10565E-14 -14.9761 0.92385E-15 -15.0344 0.87445E+00 -0.0583 51 FeO2- 0.12554E-07 -7.9012 0.10967E-07 -7.9599 0.87355E+00 -0.0587 52 HFeO2,aq 0.18313E-09 -9.7373 0.18313E-09 -9.7373 0.10000E+01 0.0000 53 H2,aq 0.21684E-08 -8.6639 0.21649E-08 -8.6646 0.99841E+00 -0.0007 54 KCl,aq 0.13975E-09 -9.8546 0.13975E-09 -9.8546 0.10000E+01 0.0000 55 KHSO4,aq 0.37522E-18 -18.4257 0.37522E-18 -18.4257 0.10000E+01 0.0000 56 KOH,aq 0.20794E-06 -6.6821 0.20794E-06 -6.6821 0.10000E+01 0.0000 57 KSO4- 0.17955E-07 -7.7458 0.15685E-07 -7.8045 0.87355E+00 -0.0587 58 MgCO3,aq 0.17139E-12 -12.7660 0.17139E-12 -12.7660 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.24449E-14 -14.6117 0.21380E-14 -14.6700 0.87445E+00 -0.0583 60 MgCl+ 0.28097E-14 -14.5513 0.24569E-14 -14.6096 0.87445E+00 -0.0583 61 MgOH+ 0.47703E-10 -10.3214 0.41715E-10 -10.3797 0.87445E+00 -0.0583 63 MnO,aq 0.66151E-09 -9.1795 0.66151E-09 -9.1795 0.10000E+01 0.0000 64 MnOH+ 0.29001E-09 -9.5376 0.25360E-09 -9.5959 0.87445E+00 -0.0583 65 MnO2-2 0.20616E-11 -11.6858 0.12736E-11 -11.8950 0.61776E+00 -0.2092 66 HMnO2- 0.41936E-10 -10.3774 0.36633E-10 -10.4361 0.87355E+00 -0.0587 69 MnCl+ 0.93526E-14 -14.0291 0.81784E-14 -14.0873 0.87445E+00 -0.0583 70 MnSO4,aq 0.50260E-13 -13.2988 0.50260E-13 -13.2988 0.10000E+01 0.0000 71 NaCl,aq 0.32366E-06 -6.4899 0.32366E-06 -6.4899 0.10000E+01 0.0000 72 NaOH,aq 0.26497E-04 -4.5768 0.26497E-04 -4.5768 0.10000E+01 0.0000 74 OH- 0.50426E-02 -2.2973 0.44007E-02 -2.3565 0.87270E+00 -0.0591 79 HPO3-2 0.34490E-17 -17.4623 0.21306E-17 -17.6715 0.61776E+00 -0.2092 82 H3PO4,aq 0.38073E-16 -16.4194 0.38073E-16 -16.4194 0.10000E+01 0.0000 83 H2PO4- 0.87514E-09 -9.0579 0.76487E-09 -9.1164 0.87400E+00 -0.0585 84 PO4-3 0.55498E-08 -8.2557 0.19625E-08 -8.7072 0.35361E+00 -0.4515 87 H2P2O7-2 0.74256E-19 -19.1293 0.45872E-19 -19.3385 0.61776E+00 -0.2092 88 HP2O7-3 0.20248E-15 -15.6936 0.69765E-16 -16.1564 0.34456E+00 -0.4627 89 P2O7-4 0.82050E-15 -15.0859 0.12694E-15 -15.8964 0.15471E+00 -0.8105 90 H2S,aq 0.87908E-15 -15.0560 0.87768E-15 -15.0567 0.99841E+00 -0.0007 97 SO3-2 0.71451E-14 -14.1460 0.44483E-14 -14.3518 0.62256E+00 -0.2058 98 HSO3- 0.41860E-16 -16.3782 0.36567E-16 -16.4369 0.87355E+00 -0.0587 99 HSO4- 0.22866E-11 -11.6408 0.20006E-11 -11.6988 0.87490E+00 -0.0580 Charge balance for all species = 0.2989E-12 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.1498101E-09 -.9715715E-02 -.9785831E+01 0.0000 2 H2O 0.1000000E+01 0.5550885E+02 0.9992910E+06 0.0000 3 Cl- 0.1380792E-03 0.1384031E-03 0.4903282E+01 5.9632 4 SO4-- 0.2556567E-04 0.2558479E-04 0.2455953E+01 14.9625 5 HCO3- 0.6751424E-05 0.1311063E-04 0.7993996E+00 4.6528 6 HS- 0.2475871E-11 -.1047586E-08 -.3462091E-04 -1.7832 7 Al+++ 0.3543757E-27 0.2822910E-04 0.7611168E+00 1.7318 8 H4SiO4 0.4989702E-03 0.5026006E-02 0.4827299E+03 -3.3019 9 Ca++ 0.3755177E-07 0.5531460E-07 0.2215308E-02 12.1278 10 Mg++ 0.2259840E-10 0.7207582E-10 0.1751050E-05 8.9061 11 Fe++ 0.1182154E-12 0.2787378E-07 0.1555550E-02 6.6250 12 K+ 0.7311435E-04 0.7334038E-04 0.2865698E+01 5.6875 13 Na+ 0.9269699E-02 0.9761235E-02 0.2242478E+03 7.7901 14 Mn++ 0.1789887E-10 0.1013469E-08 0.5563799E-04 8.8053 15 HPO4-- 0.5105873E-06 0.5170122E-06 0.4958671E-01 13.2629 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.3973748E+00 -.9685609E-02 -.3876892E+00 0.0000000E+00 2 H2O 0.5520741E+02 0.5533684E+02 -.1294293E+00 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.6905986E-03 0.2550551E-04 0.6650931E-03 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.6650941E-03 -.1044340E-08 -.6650931E-03 0.0000000E+00 7 Al+++ 0.7825454E-01 0.2814162E-04 0.7822640E-01 0.0000000E+00 8 H4SiO4 0.2498964E+00 0.5010431E-02 0.2448859E+00 0.0000000E+00 9 Ca++ 0.2761674E-01 0.5514320E-07 0.2761669E-01 0.0000000E+00 10 Mg++ 0.1904683E-01 0.7185247E-10 0.1904683E-01 0.0000000E+00 11 Fe++ 0.1711149E-01 0.2778741E-07 0.1711147E-01 0.0000000E+00 12 K+ 0.5095329E-02 0.7311312E-04 0.5022216E-02 0.0000000E+00 13 Na+ 0.3028466E-01 0.9730988E-02 0.2055367E-01 0.0000000E+00 14 Mn++ 0.4161090E-03 0.1010328E-08 0.4161080E-03 0.0000000E+00 15 HPO4-- 0.1420159E-03 0.5154102E-06 0.1415005E-03 0.0000000E+00 Chg. balance for solid moles: 0.5220E-16 Mass of aqueous solution: 0.997617E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 23.9990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 0.2045E-01 -1.689 5.363 0.729 20.47 2.059 andradite 0.2348E-02 -2.629 1.193 0.077 4.554 0.3100 grossular 0.9848E-04 -4.007 0.4436E-01 -1.353 0.1693 0.1234E-01 apatite-OH 0.4717E-04 -4.326 0.2369E-01 -1.625 0.9044E-01 0.7529E-02 clinochlore 0.3809E-02 -2.419 2.117 0.326 8.082 0.8054 daphnite 0.2092E-02 -2.679 1.493 0.174 5.698 0.4523 chlorite-Mn 0.8322E-04 -4.080 0.5900E-01 -1.229 0.2252 0.1880E-01 microcline 0.4889E-02 -2.311 1.361 0.134 5.194 0.5316 stilbite 0.2004E-01 -1.698 14.12 1.150 53.91 6.588 stilpnomelane-Fe 0.2662E-03 -3.575 0.2869 -0.542 1.095 0.9911E-01 nontronite-Na 0.3128E-03 -3.505 0.1330 -0.876 0.5077 0.4132E-01 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.9597E+00 0.9597E+00 1.0000 -0.018 grossular 0.4026E-01 0.4026E-01 1.0000 -1.395 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.6365E+00 0.6365E+00 1.0000 -0.196 daphnite 0.3496E+00 0.3496E+00 1.0000 -0.456 chlorite-Mn 0.1391E-01 0.1391E-01 1.0000 -1.857 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 nontronite-Na 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 26.197766 g Volume = 10.924762 cm3 Porosity: -3.0677% V(tot) - V(min): -.32516E+00 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 23.9990000 g log = 1.3802 Original solution: 1000.0103000 g Original solution / Rock added: 41.67 (Water/Rock Ratio), log = 1.6198 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0203 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.1000E+01 0.9860 0.1006E+01 0.1020E+01 CO2,gas 0.1724E-06 1.0071 0.1772E-06 0.1759E-06 CH4,gas 0.1118E-14 1.0125 0.1154E-14 0.1140E-14 H2,gas 0.2784E-05 1.0005 0.2842E-05 0.2841E-05 H2S,gas 0.2374E-13 0.9960 0.2413E-13 0.2422E-13 S2,gas 0.2651E-35 1.0000 0.2705E-35 0.2705E-35 CO,gas 0.1315E-15 1.0000 0.1342E-15 0.1342E-15 SO3,gas 0.1010E-39 1.0000 0.1031E-39 0.1031E-39 SO2,gas 0.1117E-22 1.0000 0.1140E-22 0.1140E-22 HCl,gas 0.5019E-17 1.0000 0.5121E-17 0.5121E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 16 albite -0.38 -0.38 0.00 0.000 0.11184E-10 22 andradite 39.01 39.01 0.00 0.000 0.12132E-10 23 grossular 32.73 32.73 0.00 0.000 0.00000E+00 32 apatite-OH -18.15 -18.15 0.00 0.000 0.00000E+00 46 clinochlore 39.07 39.07 0.00 0.000 0.36397E-10 47 daphnite 28.97 28.97 0.00 0.000 0.54595E-10 48 chlorite-Mn 46.87 46.87 0.00 0.000 0.12132E-10 116 microcline -2.49 -2.49 0.00 0.000 -0.10616E-10 163 stilbite -7.52 -7.52 0.00 0.000 0.15165E-10 164 stilpnomelane-Fe 13.02 13.02 0.00 0.000 0.21232E-10 209 nontronite-Na 3.52 3.52 0.00 0.000 -0.45496E-11 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -15.11 -8.45 -2.817 0.14429E+05 -6.752 3 CH4,gas 4.54 -12.09 -16.64 -4.159 0.28407E+05 -14.938 4 H2,gas 8.00 0.75 -7.25 -4.140 0.12371E+05 -5.546 5 H2S,gas -6.23 -21.55 -15.32 -7.658 0.26152E+05 -13.618 6 S2,gas -7.34 -44.60 -37.27 -5.733 0.63632E+05 -35.568 7 CO,gas 3.21 -14.36 -17.57 -5.407 0.30002E+05 -15.872 8 SO3,gas 17.12 -24.56 -41.69 -10.421 0.71178E+05 -39.987 9 SO2,gas 0.83 -23.81 -24.64 -6.571 0.42076E+05 -22.943 10 HCl,gas 5.19 -13.80 -18.99 -9.495 0.32424E+05 -17.291 11 acmite 7.71 7.43 -0.28 -0.029 0.47078E+03 15 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 19 spessartine 24.46 19.97 -4.48 -0.224 0.76553E+04 20 analcite 3.32 2.92 -0.40 -0.045 0.68948E+03 21 andalusite 5.00 0.16 -4.84 -0.484 0.82638E+04 26 annite 20.12 17.39 -2.73 -0.152 0.46698E+04 27 phlogopite 27.06 24.23 -2.83 -0.157 0.48367E+04 29 anorthite 12.71 8.99 -3.72 -0.286 0.63565E+04 35 aragonite 0.97 -2.98 -3.95 -1.316 0.67436E+04 36 brucite 12.57 8.91 -3.66 -0.732 0.62535E+04 37 calcite 0.81 -2.98 -3.79 -1.265 0.64794E+04 38 carnegieite-low 9.02 6.22 -2.80 -0.400 0.47866E+04 39 carnegieite-high 10.09 6.22 -3.87 -0.553 0.66136E+04 40 carpholite-Mg 8.58 5.77 -2.82 -0.188 0.48085E+04 41 carpholite-Fe 6.71 3.48 -3.23 -0.215 0.55114E+04 42 celadonite 5.34 3.12 -2.22 -0.131 0.37972E+04 43 celadonite-Fe 3.88 0.84 -3.04 -0.179 0.51906E+04 44 chrysotile 23.89 20.11 -3.78 -0.315 0.64505E+04 50 chloritoid-Mg 13.20 9.07 -4.13 -0.275 0.70516E+04 51 chloritoid-Fe 9.17 6.79 -2.39 -0.159 0.40755E+04 52 chloritoid-Mn 11.40 8.97 -2.43 -0.162 0.41560E+04 54 coesite -2.38 -3.30 -0.93 -0.309 0.15809E+04 59 corundum 8.38 3.46 -4.92 -0.447 0.83998E+04 61 cristobalite -2.56 -3.30 -0.74 -0.247 0.12662E+04 63 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71234E+04 65 diaspore 2.87 1.73 -1.14 -0.190 0.19497E+04 67 diopside 16.18 14.43 -1.75 -0.175 0.29903E+04 68 hedenbergite 14.21 12.15 -2.06 -0.206 0.35163E+04 75 epidote 24.67 24.06 -0.61 -0.030 0.10394E+04 76 clinozoisite 22.81 19.55 -3.26 -0.148 0.55677E+04 77 epidote-Fe 29.84 28.58 -1.26 -0.066 0.21577E+04 78 fayalite 14.05 9.95 -4.10 -0.585 0.69966E+04 79 ferrosilite 11.15 6.65 -4.50 -0.450 0.76893E+04 83 gibbsite 4.08 1.73 -2.35 -0.335 0.40083E+04 84 glaucophane 22.97 19.35 -3.63 -0.098 0.61946E+04 85 glaucophane-Fe 17.28 12.50 -4.77 -0.129 0.81488E+04 87 greenalite 16.14 13.27 -2.87 -0.239 0.48977E+04 90 hematite 12.57 12.50 -0.07 -0.009 0.12063E+03 91 heulandite -5.83 -7.52 -1.69 -0.077 0.28938E+04 95 jadeite 4.22 2.92 -1.30 -0.130 0.22150E+04 96 julgoldite 70.43 66.94 -3.49 -0.091 0.59528E+04 97 kalsilite 7.58 4.12 -3.47 -0.495 0.59190E+04 98 kaolinite -1.33 -3.14 -1.81 -0.164 0.30861E+04 99 kyanite 4.88 0.16 -4.71 -0.471 0.80497E+04 101 laumontite 2.88 2.38 -0.50 -0.033 0.85320E+03 102 lawsonite 9.62 8.99 -0.63 -0.042 0.10731E+04 103 leucite 4.12 0.82 -3.30 -0.330 0.56405E+04 105 lizardite 23.24 20.11 -3.13 -0.261 0.53431E+04 107 magnetite 20.09 19.12 -0.97 -0.079 0.16509E+04 108 minnesotaite 10.39 6.67 -3.72 -0.219 0.63532E+04 110 magnesioferrite 26.21 21.40 -4.81 -0.393 0.82142E+04 113 margarite 17.32 12.45 -4.87 -0.195 0.83195E+04 120 muscovite 2.58 0.98 -1.61 -0.094 0.27409E+04 121 paragonite 4.24 3.08 -1.16 -0.068 0.19800E+04 122 nepheline 8.34 6.22 -2.12 -0.303 0.36189E+04 134 phlogopite-Na 29.65 26.33 -3.31 -0.184 0.56555E+04 136 prehnite 19.37 17.81 -1.56 -0.092 0.26610E+04 137 prehnite-Fe 22.50 22.33 -0.17 -0.010 0.28773E+03 138 pumpellyite-Fe 46.27 43.98 -2.29 -0.051 0.39029E+04 139 pumpellyite-Mg 48.99 46.26 -2.73 -0.061 0.46615E+04 145 pyroxmangite 7.40 5.50 -1.90 -0.379 0.32361E+04 146 pyrophyllite -6.18 -9.74 -3.57 -0.223 0.60927E+04 147 quartz -2.99 -3.30 -0.31 -0.104 0.53357E+03 152 rhodonite 7.45 5.50 -1.94 -0.388 0.33164E+04 153 sanidine -1.28 -2.49 -1.21 -0.093 0.20677E+04 165 stilpnomelane-Mg 27.44 24.42 -3.02 -0.090 0.51543E+04 171 talc 16.49 13.51 -2.98 -0.175 0.50888E+04 174 tephroite 18.09 14.31 -3.78 -0.540 0.64492E+04 177 topaz-H 4.62 0.16 -4.46 -0.405 0.76098E+04 178 tridymite -2.63 -3.30 -0.68 -0.225 0.11535E+04 187 wairakite 3.95 2.38 -1.57 -0.092 0.26752E+04 188 walstromite 11.51 8.83 -2.68 -0.537 0.45818E+04 189 wollastonite 10.46 8.83 -1.64 -0.327 0.27922E+04 190 pseudo-wollastonite 11.00 8.83 -2.17 -0.435 0.37121E+04 191 zoisite 22.85 19.55 -3.30 -0.150 0.56418E+04 192 akaganeite 7.75 6.25 -1.51 -0.326 0.25728E+04 193 beidellite-Ca -1.65 -6.08 -4.44 -0.274 0.75747E+04 195 beidellite-K -1.52 -6.21 -4.69 -0.287 0.80009E+04 196 beidellite-Mg -1.79 -6.61 -4.82 -0.298 0.82362E+04 197 beidellite-Na -1.34 -5.51 -4.17 -0.255 0.71201E+04 199 chalcedony -2.80 -3.30 -0.50 -0.166 0.85287E+03 201 montmorillonite-Ca -2.29 -5.38 -3.08 -0.191 0.52671E+04 202 montmorillonite-K -2.24 -5.50 -3.26 -0.200 0.55714E+04 203 montmorillonite-Mg -2.48 -5.91 -3.43 -0.212 0.58517E+04 204 montmorillonite-Na -2.04 -4.81 -2.77 -0.170 0.47263E+04 205 nontronite-Ca 3.21 2.95 -0.26 -0.017 0.45160E+03 206 nontronite-H 2.53 0.95 -1.58 -0.106 0.27042E+04 207 nontronite-K 3.34 2.83 -0.51 -0.033 0.87912E+03 208 nontronite-Mg 3.07 2.42 -0.66 -0.043 0.11203E+04 224 tobermorite 9.82 6.80 -3.02 -0.825 0.51609E+04 233 boehmite 4.41 1.73 -2.67 -0.446 0.45666E+04 235 ferrous-oxide 9.81 6.62 -3.19 -0.797 0.54410E+04 240 silica-amorphous -2.09 -3.30 -1.21 -0.404 0.20670E+04 242 an20ab80 2.02 1.49 -0.53 -0.041 0.90045E+03 243 an25ab75 2.65 1.96 -0.69 -0.053 0.11725E+04 244 an30ab70 3.28 2.43 -0.85 -0.066 0.14542E+04 245 tr.625ac.25prg.125 45.16 40.85 -4.31 -0.116 0.73591E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 1.0000000 g Current total amount of reactant added: 23.9990000 g New total amount of reactant added: 24.9990000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.2992E-12 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 9 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 24.9990000 Water: Moles liquid = 0.5533E+02 kg liquid = 0.9968E+00 Moles total = 0.5519E+02 kg total = 0.9944E+00 Activity = 1.0000 Stoichiometric ionic strength = .5203789E-02 Osmotic coef. = 0.9617 True ionic strength = .9440238E-02 Chg. balance for total moles = 0.2992E-12 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.14981E-09 -9.8245 0.13125E-09 -9.8819 0.87609E+00 -0.0574 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13809E-03 -3.8598 0.12059E-03 -3.9187 0.87324E+00 -0.0589 4 SO4-- 0.25568E-04 -4.5923 0.15791E-04 -4.8016 0.61761E+00 -0.2093 5 HCO3- 0.67476E-05 -5.1709 0.58969E-05 -5.2294 0.87393E+00 -0.0585 6 HS- 0.28051E-11 -11.5520 0.24498E-11 -11.6109 0.87331E+00 -0.0588 7 Al+++ 0.33759E-27 -27.4716 0.11590E-27 -27.9359 0.34333E+00 -0.4643 8 H4SiO4 0.50629E-03 -3.2956 0.50629E-03 -3.2956 0.10000E+01 0.0000 9 Ca++ 0.37550E-07 -7.4254 0.23100E-07 -7.6364 0.61518E+00 -0.2110 10 Mg++ 0.23062E-10 -10.6371 0.14152E-10 -10.8492 0.61366E+00 -0.2121 11 Fe++ 0.11786E-12 -12.9286 0.72366E-13 -13.1405 0.61402E+00 -0.2118 12 K+ 0.73621E-04 -4.1330 0.64349E-04 -4.1915 0.87405E+00 -0.0585 13 Na+ 0.93340E-02 -2.0299 0.81502E-02 -2.0888 0.87317E+00 -0.0589 14 Mn++ 0.18266E-10 -10.7384 0.11221E-10 -10.9500 0.61429E+00 -0.2116 15 HPO4-- 0.51229E-06 -6.2905 0.31642E-06 -6.4997 0.61765E+00 -0.2093 16 HSiO3- 0.41249E-02 -2.3846 0.36020E-02 -2.4435 0.87324E+00 -0.0589 17 Ca(HSiO3)+ 0.21677E-08 -8.6640 0.18949E-08 -8.7224 0.87415E+00 -0.0584 18 Mg(HSiO3)+ 0.16528E-11 -11.7818 0.14448E-11 -11.8402 0.87415E+00 -0.0584 19 NaHSiO3,aq 0.47481E-03 -3.3235 0.47481E-03 -3.3235 0.10000E+01 0.0000 20 AlO+ 0.10472E-14 -14.9800 0.91539E-15 -15.0384 0.87415E+00 -0.0584 22 HAlO2,aq 0.13890E-08 -8.8573 0.13890E-08 -8.8573 0.10000E+01 0.0000 23 AlO2- 0.26854E-04 -4.5710 0.23427E-04 -4.6303 0.87238E+00 -0.0593 24 CH4,aq 0.89006E-18 -18.0506 0.88863E-18 -18.0513 0.99840E+00 -0.0007 29 CO,aq 0.92819E-19 -19.0324 0.92819E-19 -19.0324 0.10000E+01 0.0000 30 CO2,aq 0.16564E-08 -8.7808 0.16537E-08 -8.7815 0.99840E+00 -0.0007 31 CO3-2 0.63617E-05 -5.1964 0.39245E-05 -5.4062 0.61690E+00 -0.2098 32 CaCO3,aq 0.11367E-08 -8.9443 0.11367E-08 -8.9443 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.39777E-11 -11.4004 0.34771E-11 -11.4588 0.87415E+00 -0.0584 34 CaCl+ 0.51570E-11 -11.2876 0.45080E-11 -11.3460 0.87415E+00 -0.0584 35 CaCl2,aq 0.12915E-15 -15.8889 0.12915E-15 -15.8889 0.10000E+01 0.0000 36 CaOH+ 0.14350E-07 -7.8432 0.12544E-07 -7.9016 0.87415E+00 -0.0584 37 CaSO4,aq 0.11583E-09 -9.9362 0.11583E-09 -9.9362 0.10000E+01 0.0000 38 HCl,aq 0.29001E-14 -14.5376 0.29001E-14 -14.5376 0.10000E+01 0.0000 43 FeCl+ 0.15801E-16 -16.8013 0.13812E-16 -16.8597 0.87415E+00 -0.0584 46 FeO,aq 0.16328E-09 -9.7871 0.16328E-09 -9.7871 0.10000E+01 0.0000 47 FeOH+ 0.20532E-10 -10.6876 0.17948E-10 -10.7460 0.87415E+00 -0.0584 48 HFeO2- 0.14907E-07 -7.8266 0.13017E-07 -7.8855 0.87324E+00 -0.0589 49 FeO+ 0.10361E-14 -14.9846 0.90567E-15 -15.0430 0.87415E+00 -0.0584 51 FeO2- 0.12320E-07 -7.9094 0.10759E-07 -7.9682 0.87324E+00 -0.0589 52 HFeO2,aq 0.17959E-09 -9.7457 0.17959E-09 -9.7457 0.10000E+01 0.0000 53 H2,aq 0.22379E-08 -8.6502 0.22343E-08 -8.6509 0.99840E+00 -0.0007 54 KCl,aq 0.14064E-09 -9.8519 0.14064E-09 -9.8519 0.10000E+01 0.0000 55 KHSO4,aq 0.37707E-18 -18.4236 0.37707E-18 -18.4236 0.10000E+01 0.0000 56 KOH,aq 0.20938E-06 -6.6791 0.20938E-06 -6.6791 0.10000E+01 0.0000 57 KSO4- 0.18057E-07 -7.7434 0.15768E-07 -7.8022 0.87324E+00 -0.0589 58 MgCO3,aq 0.17456E-12 -12.7580 0.17456E-12 -12.7580 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.24901E-14 -14.6038 0.21767E-14 -14.6622 0.87415E+00 -0.0584 60 MgCl+ 0.28635E-14 -14.5431 0.25032E-14 -14.6015 0.87415E+00 -0.0584 61 MgOH+ 0.48648E-10 -10.3129 0.42525E-10 -10.3714 0.87415E+00 -0.0584 63 MnO,aq 0.67461E-09 -9.1709 0.67461E-09 -9.1709 0.10000E+01 0.0000 64 MnOH+ 0.29575E-09 -9.5291 0.25853E-09 -9.5875 0.87415E+00 -0.0584 65 MnO2-2 0.21069E-11 -11.6764 0.12997E-11 -11.8861 0.61690E+00 -0.2098 66 HMnO2- 0.42797E-10 -10.3686 0.37372E-10 -10.4274 0.87324E+00 -0.0589 69 MnCl+ 0.95319E-14 -14.0208 0.83323E-14 -14.0792 0.87415E+00 -0.0584 70 MnSO4,aq 0.51153E-13 -13.2911 0.51153E-13 -13.2911 0.10000E+01 0.0000 71 NaCl,aq 0.32571E-06 -6.4872 0.32571E-06 -6.4872 0.10000E+01 0.0000 72 NaOH,aq 0.26681E-04 -4.5738 0.26681E-04 -4.5738 0.10000E+01 0.0000 74 OH- 0.50462E-02 -2.2970 0.44023E-02 -2.3563 0.87238E+00 -0.0593 79 HPO3-2 0.35713E-17 -17.4472 0.22031E-17 -17.6570 0.61690E+00 -0.2098 82 H3PO4,aq 0.38119E-16 -16.4189 0.38119E-16 -16.4189 0.10000E+01 0.0000 83 H2PO4- 0.87683E-09 -9.0571 0.76608E-09 -9.1157 0.87369E+00 -0.0586 84 PO4-3 0.55793E-08 -8.2534 0.19670E-08 -8.7062 0.35255E+00 -0.4528 87 H2P2O7-2 0.74594E-19 -19.1273 0.46017E-19 -19.3371 0.61690E+00 -0.2098 88 HP2O7-3 0.20383E-15 -15.6907 0.70010E-16 -16.1548 0.34347E+00 -0.4641 89 P2O7-4 0.82825E-15 -15.0818 0.12744E-15 -15.8947 0.15386E+00 -0.8129 90 H2S,aq 0.99529E-15 -15.0021 0.99369E-15 -15.0027 0.99840E+00 -0.0007 97 SO3-2 0.73745E-14 -14.1323 0.45849E-14 -14.3387 0.62172E+00 -0.2064 98 HSO3- 0.43146E-16 -16.3651 0.37677E-16 -16.4239 0.87324E+00 -0.0589 99 HSO4- 0.22837E-11 -11.6414 0.19973E-11 -11.6996 0.87460E+00 -0.0582 Charge balance for all species = 0.2990E-12 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.1498069E-09 -.9786683E-02 -.9857232E+01 0.0000 2 H2O 0.1000000E+01 0.5550878E+02 0.9992817E+06 0.0000 3 Cl- 0.1380922E-03 0.1384181E-03 0.4903775E+01 5.9632 4 SO4-- 0.2556834E-04 0.2558752E-04 0.2456195E+01 14.9622 5 HCO3- 0.6747573E-05 0.1311205E-04 0.7994799E+00 4.6525 6 HS- 0.2805139E-11 -.1000205E-08 -.3305477E-04 -1.7290 7 Al+++ 0.3375877E-27 0.2685506E-04 0.7240640E+00 1.7098 8 H4SiO4 0.5062919E-03 0.5105972E-02 0.4904064E+03 -3.2956 9 Ca++ 0.3755033E-07 0.5532969E-07 0.2215894E-02 12.1274 10 Mg++ 0.2306230E-10 0.7354291E-10 0.1786678E-05 8.9147 11 Fe++ 0.1178558E-12 0.2759032E-07 0.1539718E-02 6.6234 12 K+ 0.7362130E-04 0.7384888E-04 0.2885544E+01 5.6905 13 Na+ 0.9334028E-02 0.9835843E-02 0.2259600E+03 7.7931 14 Mn++ 0.1826618E-10 0.1033587E-08 0.5674199E-04 8.8139 15 HPO4-- 0.5122860E-06 0.5187421E-06 0.4975223E-01 13.2641 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.4139333E+00 -.9755299E-02 -.4041780E+00 0.0000000E+00 2 H2O 0.5519488E+02 0.5533077E+02 -.1358954E+00 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.7183120E-03 0.2550547E-04 0.6928065E-03 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.6928075E-03 -.9969975E-09 -.6928065E-03 0.0000000E+00 7 Al+++ 0.8151528E-01 0.2676894E-04 0.8148851E-01 0.0000000E+00 8 H4SiO4 0.2603092E+00 0.5089598E-02 0.2552196E+00 0.0000000E+00 9 Ca++ 0.2876689E-01 0.5515226E-07 0.2876683E-01 0.0000000E+00 10 Mg++ 0.1984048E-01 0.7330707E-10 0.1984048E-01 0.0000000E+00 11 Fe++ 0.1782450E-01 0.2750184E-07 0.1782447E-01 0.0000000E+00 12 K+ 0.5307643E-02 0.7361206E-04 0.5234031E-02 0.0000000E+00 13 Na+ 0.3153991E-01 0.9804301E-02 0.2173561E-01 0.0000000E+00 14 Mn++ 0.4334476E-03 0.1030272E-08 0.4334465E-03 0.0000000E+00 15 HPO4-- 0.1479335E-03 0.5170786E-06 0.1474164E-03 0.0000000E+00 Chg. balance for solid moles: 0.6722E-16 Mass of aqueous solution: 0.997517E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 24.9990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 0.2164E-01 -1.665 5.676 0.754 20.80 2.179 andradite 0.2496E-02 -2.603 1.268 0.103 4.648 0.3295 grossular 0.1015E-03 -3.994 0.4572E-01 -1.340 0.1675 0.1272E-01 apatite-OH 0.4914E-04 -4.309 0.2468E-01 -1.608 0.9045E-01 0.7843E-02 clinochlore 0.3968E-02 -2.401 2.206 0.344 8.082 0.8389 daphnite 0.2129E-02 -2.672 1.519 0.182 5.566 0.4603 chlorite-Mn 0.8669E-04 -4.062 0.6146E-01 -1.211 0.2252 0.1959E-01 microcline 0.5070E-02 -2.295 1.411 0.150 5.171 0.5513 stilbite 0.2073E-01 -1.683 14.61 1.165 53.53 6.813 stilpnomelane-Fe 0.3276E-03 -3.485 0.3531 -0.452 1.294 0.1220 nontronite-Na 0.2752E-03 -3.560 0.1170 -0.932 0.4289 0.3636E-01 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.9609E+00 0.9609E+00 1.0000 -0.017 grossular 0.3908E-01 0.3908E-01 1.0000 -1.408 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.6417E+00 0.6417E+00 1.0000 -0.193 daphnite 0.3443E+00 0.3443E+00 1.0000 -0.463 chlorite-Mn 0.1402E-01 0.1402E-01 1.0000 -1.853 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 nontronite-Na 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 27.289806 g Volume = 11.370681 cm3 Porosity: -3.3736% V(tot) - V(min): -.37108E+00 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 24.9990000 g log = 1.3979 Original solution: 1000.0103000 g Original solution / Rock added: 40.00 (Water/Rock Ratio), log = 1.6021 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0203 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.1000E+01 0.9860 0.1006E+01 0.1020E+01 CO2,gas 0.1722E-06 1.0071 0.1769E-06 0.1757E-06 CH4,gas 0.1266E-14 1.0125 0.1308E-14 0.1292E-14 H2,gas 0.2873E-05 1.0005 0.2933E-05 0.2932E-05 H2S,gas 0.2688E-13 0.9960 0.2732E-13 0.2742E-13 S2,gas 0.3190E-35 1.0000 0.3255E-35 0.3255E-35 CO,gas 0.1356E-15 1.0000 0.1383E-15 0.1383E-15 SO3,gas 0.1008E-39 1.0000 0.1028E-39 0.1028E-39 SO2,gas 0.1150E-22 1.0000 0.1174E-22 0.1174E-22 HCl,gas 0.5016E-17 1.0000 0.5117E-17 0.5117E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 16 albite -0.38 -0.38 0.00 0.000 -0.94784E-12 22 andradite 39.01 39.01 0.00 0.000 0.12132E-10 23 grossular 32.73 32.73 0.00 0.000 -0.12132E-10 32 apatite-OH -18.15 -18.15 0.00 0.000 0.00000E+00 46 clinochlore 39.07 39.07 0.00 0.000 0.00000E+00 47 daphnite 28.97 28.97 0.00 0.000 -0.12132E-10 48 chlorite-Mn 46.87 46.87 0.00 0.000 -0.12132E-10 116 microcline -2.49 -2.49 0.00 0.000 0.15165E-11 163 stilbite -7.52 -7.52 0.00 0.000 -0.90992E-11 164 stilpnomelane-Fe 13.02 13.02 0.00 0.000 -0.27298E-10 209 nontronite-Na 3.52 3.52 0.00 0.000 0.60662E-11 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -15.11 -8.45 -2.817 0.14430E+05 -6.752 3 CH4,gas 4.54 -12.04 -16.58 -4.146 0.28314E+05 -14.883 4 H2,gas 8.00 0.77 -7.23 -4.132 0.12348E+05 -5.533 5 H2S,gas -6.23 -21.49 -15.26 -7.631 0.26060E+05 -13.564 6 S2,gas -7.34 -44.52 -37.19 -5.721 0.63495E+05 -35.487 7 CO,gas 3.21 -14.34 -17.56 -5.402 0.29980E+05 -15.859 8 SO3,gas 17.12 -24.57 -41.69 -10.422 0.71179E+05 -39.988 9 SO2,gas 0.83 -23.80 -24.63 -6.568 0.42054E+05 -22.930 10 HCl,gas 5.19 -13.80 -18.99 -9.495 0.32425E+05 -17.291 11 acmite 7.71 7.44 -0.27 -0.028 0.45852E+03 15 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 19 spessartine 24.46 19.97 -4.48 -0.224 0.76544E+04 20 analcite 3.32 2.91 -0.41 -0.046 0.70028E+03 21 andalusite 5.00 0.12 -4.88 -0.488 0.83281E+04 26 annite 20.12 17.38 -2.74 -0.152 0.46781E+04 27 phlogopite 27.06 24.26 -2.81 -0.156 0.47930E+04 29 anorthite 12.71 8.96 -3.75 -0.289 0.64105E+04 35 aragonite 0.97 -2.98 -3.95 -1.317 0.67451E+04 36 brucite 12.57 8.91 -3.65 -0.731 0.62389E+04 37 calcite 0.81 -2.98 -3.80 -1.265 0.64809E+04 38 carnegieite-low 9.02 6.21 -2.82 -0.402 0.48082E+04 39 carnegieite-high 10.09 6.21 -3.89 -0.555 0.66352E+04 40 carpholite-Mg 8.58 5.74 -2.84 -0.189 0.48474E+04 41 carpholite-Fe 6.71 3.45 -3.26 -0.217 0.55677E+04 42 celadonite 5.34 3.13 -2.21 -0.130 0.37719E+04 43 celadonite-Fe 3.88 0.84 -3.04 -0.179 0.51826E+04 44 chrysotile 23.89 20.15 -3.74 -0.312 0.63853E+04 50 chloritoid-Mg 13.20 9.04 -4.16 -0.277 0.71013E+04 51 chloritoid-Fe 9.17 6.75 -2.43 -0.162 0.41426E+04 52 chloritoid-Mn 11.40 8.94 -2.46 -0.164 0.42057E+04 54 coesite -2.38 -3.30 -0.92 -0.307 0.15701E+04 59 corundum 8.38 3.42 -4.96 -0.451 0.84749E+04 61 cristobalite -2.56 -3.30 -0.74 -0.245 0.12554E+04 63 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71234E+04 65 diaspore 2.87 1.71 -1.16 -0.194 0.19872E+04 67 diopside 16.18 14.45 -1.73 -0.173 0.29547E+04 68 hedenbergite 14.21 12.16 -2.05 -0.205 0.34980E+04 75 epidote 24.67 24.03 -0.64 -0.031 0.10976E+04 76 clinozoisite 22.81 19.50 -3.31 -0.150 0.56490E+04 77 epidote-Fe 29.84 28.56 -1.28 -0.067 0.21929E+04 78 fayalite 14.05 9.95 -4.09 -0.585 0.69914E+04 79 ferrosilite 11.15 6.66 -4.49 -0.449 0.76732E+04 83 gibbsite 4.08 1.71 -2.37 -0.338 0.40458E+04 84 glaucophane 22.97 19.39 -3.59 -0.097 0.61294E+04 85 glaucophane-Fe 17.28 12.51 -4.76 -0.129 0.81355E+04 87 greenalite 16.14 13.28 -2.86 -0.238 0.48844E+04 90 hematite 12.57 12.48 -0.09 -0.011 0.14958E+03 91 heulandite -5.83 -7.52 -1.69 -0.077 0.28938E+04 95 jadeite 4.22 2.91 -1.30 -0.130 0.22258E+04 96 julgoldite 70.43 66.94 -3.49 -0.091 0.59537E+04 97 kalsilite 7.58 4.10 -3.48 -0.497 0.59406E+04 98 kaolinite -1.33 -3.17 -1.84 -0.167 0.31396E+04 99 kyanite 4.88 0.12 -4.75 -0.475 0.81140E+04 101 laumontite 2.88 2.36 -0.52 -0.035 0.88561E+03 102 lawsonite 9.62 8.96 -0.66 -0.044 0.11272E+04 103 leucite 4.12 0.81 -3.31 -0.331 0.56513E+04 105 lizardite 23.24 20.15 -3.09 -0.258 0.52779E+04 107 magnetite 20.09 19.10 -0.99 -0.080 0.16826E+04 108 minnesotaite 10.39 6.69 -3.70 -0.218 0.63183E+04 110 magnesioferrite 26.21 21.39 -4.82 -0.393 0.82286E+04 113 margarite 17.32 12.38 -4.95 -0.198 0.84485E+04 120 muscovite 2.58 0.93 -1.65 -0.097 0.28160E+04 121 paragonite 4.24 3.04 -1.20 -0.071 0.20551E+04 122 nepheline 8.34 6.21 -2.13 -0.305 0.36405E+04 134 phlogopite-Na 29.65 26.36 -3.29 -0.183 0.56119E+04 136 prehnite 19.37 17.79 -1.58 -0.093 0.27048E+04 137 prehnite-Fe 22.50 22.32 -0.18 -0.011 0.30842E+03 138 pumpellyite-Fe 46.27 43.91 -2.36 -0.052 0.40307E+04 139 pumpellyite-Mg 48.99 46.20 -2.79 -0.062 0.47720E+04 145 pyroxmangite 7.40 5.52 -1.88 -0.376 0.32108E+04 146 pyrophyllite -6.18 -9.76 -3.59 -0.224 0.61245E+04 147 quartz -2.99 -3.30 -0.31 -0.102 0.52277E+03 152 rhodonite 7.45 5.52 -1.93 -0.385 0.32910E+04 153 sanidine -1.28 -2.49 -1.21 -0.093 0.20677E+04 165 stilpnomelane-Mg 27.44 24.47 -2.97 -0.089 0.50677E+04 171 talc 16.49 13.56 -2.93 -0.172 0.50020E+04 174 tephroite 18.09 14.33 -3.75 -0.536 0.64093E+04 177 topaz-H 4.62 0.12 -4.49 -0.409 0.76741E+04 178 tridymite -2.63 -3.30 -0.67 -0.223 0.11427E+04 187 wairakite 3.95 2.36 -1.59 -0.093 0.27076E+04 188 walstromite 11.51 8.83 -2.68 -0.535 0.45715E+04 189 wollastonite 10.46 8.83 -1.63 -0.326 0.27820E+04 190 pseudo-wollastonite 11.00 8.83 -2.17 -0.434 0.37018E+04 191 zoisite 22.85 19.50 -3.35 -0.152 0.57230E+04 192 akaganeite 7.75 6.24 -1.52 -0.328 0.25873E+04 193 beidellite-Ca -1.65 -6.11 -4.46 -0.276 0.76226E+04 195 beidellite-K -1.52 -6.23 -4.71 -0.289 0.80470E+04 196 beidellite-Mg -1.79 -6.64 -4.85 -0.300 0.82816E+04 197 beidellite-Na -1.34 -5.54 -4.20 -0.257 0.71662E+04 199 chalcedony -2.80 -3.30 -0.49 -0.164 0.84206E+03 201 montmorillonite-Ca -2.29 -5.38 -3.09 -0.191 0.52818E+04 202 montmorillonite-K -2.24 -5.51 -3.27 -0.200 0.55844E+04 203 montmorillonite-Mg -2.48 -5.91 -3.43 -0.212 0.58640E+04 204 montmorillonite-Na -2.04 -4.81 -2.78 -0.170 0.47393E+04 205 nontronite-Ca 3.21 2.95 -0.27 -0.017 0.45338E+03 206 nontronite-H 2.53 0.95 -1.58 -0.106 0.27059E+04 207 nontronite-K 3.34 2.83 -0.51 -0.033 0.87912E+03 208 nontronite-Mg 3.07 2.42 -0.66 -0.043 0.11196E+04 224 tobermorite 9.82 6.81 -3.02 -0.823 0.51506E+04 233 boehmite 4.41 1.71 -2.70 -0.449 0.46042E+04 235 ferrous-oxide 9.81 6.62 -3.19 -0.797 0.54438E+04 240 silica-amorphous -2.09 -3.30 -1.20 -0.401 0.20562E+04 242 an20ab80 2.02 1.48 -0.53 -0.041 0.91125E+03 243 an25ab75 2.65 1.95 -0.69 -0.053 0.11860E+04 244 an30ab70 3.28 2.42 -0.86 -0.066 0.14704E+04 245 tr.625ac.25prg.125 45.16 40.92 -4.24 -0.114 0.72406E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 1.0000000 g Current total amount of reactant added: 24.9990000 g New total amount of reactant added: 25.9990000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.2992E-12 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 9 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 25.9990000 Water: Moles liquid = 0.5532E+02 kg liquid = 0.9967E+00 Moles total = 0.5518E+02 kg total = 0.9941E+00 Activity = 1.0000 Stoichiometric ionic strength = .5234713E-02 Osmotic coef. = 0.9616 True ionic strength = .9503292E-02 Chg. balance for total moles = 0.2992E-12 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.14981E-09 -9.8245 0.13120E-09 -9.8821 0.87581E+00 -0.0576 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13811E-03 -3.8598 0.12056E-03 -3.9188 0.87294E+00 -0.0590 4 SO4-- 0.25571E-04 -4.5923 0.15772E-04 -4.8021 0.61678E+00 -0.2099 5 HCO3- 0.67440E-05 -5.1711 0.58918E-05 -5.2298 0.87363E+00 -0.0587 6 HS- 0.31632E-11 -11.4999 0.27615E-11 -11.5589 0.87301E+00 -0.0590 7 Al+++ 0.32223E-27 -27.4918 0.11029E-27 -27.9575 0.34228E+00 -0.4656 8 H4SiO4 0.51344E-03 -3.2895 0.51344E-03 -3.2895 0.10000E+01 0.0000 9 Ca++ 0.37551E-07 -7.4254 0.23069E-07 -7.6370 0.61434E+00 -0.2116 10 Mg++ 0.23515E-10 -10.6287 0.14410E-10 -10.8413 0.61281E+00 -0.2127 11 Fe++ 0.11752E-12 -12.9299 0.72060E-13 -13.1423 0.61318E+00 -0.2124 12 K+ 0.74114E-04 -4.1301 0.64757E-04 -4.1887 0.87375E+00 -0.0586 13 Na+ 0.93966E-02 -2.0270 0.82020E-02 -2.0861 0.87287E+00 -0.0591 14 Mn++ 0.18625E-10 -10.7299 0.11425E-10 -10.9421 0.61345E+00 -0.2122 15 HPO4-- 0.51391E-06 -6.2891 0.31700E-06 -6.4989 0.61683E+00 -0.2098 16 HSiO3- 0.41858E-02 -2.3782 0.36540E-02 -2.4372 0.87294E+00 -0.0590 17 Ca(HSiO3)+ 0.21968E-08 -8.6582 0.19197E-08 -8.7168 0.87385E+00 -0.0586 18 Mg(HSiO3)+ 0.17078E-11 -11.7676 0.14924E-11 -11.8261 0.87385E+00 -0.0586 19 NaHSiO3,aq 0.48472E-03 -3.3145 0.48472E-03 -3.3145 0.10000E+01 0.0000 20 AlO+ 0.99744E-15 -15.0011 0.87162E-15 -15.0597 0.87385E+00 -0.0586 22 HAlO2,aq 0.13230E-08 -8.8784 0.13230E-08 -8.8784 0.10000E+01 0.0000 23 AlO2- 0.25594E-04 -4.5919 0.22320E-04 -4.6513 0.87208E+00 -0.0594 24 CH4,aq 0.10037E-17 -17.9984 0.10021E-17 -17.9991 0.99839E+00 -0.0007 29 CO,aq 0.95565E-19 -19.0197 0.95565E-19 -19.0197 0.10000E+01 0.0000 30 CO2,aq 0.16544E-08 -8.7813 0.16518E-08 -8.7820 0.99839E+00 -0.0007 31 CO3-2 0.63667E-05 -5.1961 0.39223E-05 -5.4065 0.61607E+00 -0.2104 32 CaCO3,aq 0.11346E-08 -8.9452 0.11346E-08 -8.9452 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.39703E-11 -11.4012 0.34694E-11 -11.4597 0.87385E+00 -0.0586 34 CaCl+ 0.51505E-11 -11.2882 0.45008E-11 -11.3467 0.87385E+00 -0.0586 35 CaCl2,aq 0.12891E-15 -15.8897 0.12891E-15 -15.8897 0.10000E+01 0.0000 36 CaOH+ 0.14340E-07 -7.8435 0.12531E-07 -7.9020 0.87385E+00 -0.0586 37 CaSO4,aq 0.11554E-09 -9.9373 0.11554E-09 -9.9373 0.10000E+01 0.0000 38 HCl,aq 0.28985E-14 -14.5378 0.28985E-14 -14.5378 0.10000E+01 0.0000 43 FeCl+ 0.15736E-16 -16.8031 0.13751E-16 -16.8617 0.87385E+00 -0.0586 46 FeO,aq 0.16269E-09 -9.7886 0.16269E-09 -9.7886 0.10000E+01 0.0000 47 FeOH+ 0.20459E-10 -10.6891 0.17878E-10 -10.7477 0.87385E+00 -0.0586 48 HFeO2- 0.14862E-07 -7.8279 0.12974E-07 -7.8869 0.87294E+00 -0.0590 49 FeO+ 0.10168E-14 -14.9928 0.88855E-15 -15.0513 0.87385E+00 -0.0586 51 FeO2- 0.12099E-07 -7.9173 0.10562E-07 -7.9763 0.87294E+00 -0.0590 52 HFeO2,aq 0.17625E-09 -9.7539 0.17625E-09 -9.7539 0.10000E+01 0.0000 53 H2,aq 0.23068E-08 -8.6370 0.23031E-08 -8.6377 0.99839E+00 -0.0007 54 KCl,aq 0.14150E-09 -9.8493 0.14150E-09 -9.8493 0.10000E+01 0.0000 55 KHSO4,aq 0.37888E-18 -18.4215 0.37888E-18 -18.4215 0.10000E+01 0.0000 56 KOH,aq 0.21078E-06 -6.6762 0.21078E-06 -6.6762 0.10000E+01 0.0000 57 KSO4- 0.18155E-07 -7.7410 0.15849E-07 -7.8000 0.87294E+00 -0.0590 58 MgCO3,aq 0.17765E-12 -12.7504 0.17765E-12 -12.7504 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.25342E-14 -14.5962 0.22145E-14 -14.6547 0.87385E+00 -0.0586 60 MgCl+ 0.29160E-14 -14.5352 0.25482E-14 -14.5938 0.87385E+00 -0.0586 61 MgOH+ 0.49567E-10 -10.3048 0.43314E-10 -10.3634 0.87385E+00 -0.0586 63 MnO,aq 0.68733E-09 -9.1628 0.68733E-09 -9.1628 0.10000E+01 0.0000 64 MnOH+ 0.30133E-09 -9.5210 0.26332E-09 -9.5795 0.87385E+00 -0.0586 65 MnO2-2 0.21509E-11 -11.6674 0.13251E-11 -11.8778 0.61607E+00 -0.2104 66 HMnO2- 0.43633E-10 -10.3602 0.38089E-10 -10.4192 0.87294E+00 -0.0590 69 MnCl+ 0.97065E-14 -14.0129 0.84821E-14 -14.0715 0.87385E+00 -0.0586 70 MnSO4,aq 0.52022E-13 -13.2838 0.52022E-13 -13.2838 0.10000E+01 0.0000 71 NaCl,aq 0.32769E-06 -6.4845 0.32769E-06 -6.4845 0.10000E+01 0.0000 72 NaOH,aq 0.26859E-04 -4.5709 0.26859E-04 -4.5709 0.10000E+01 0.0000 74 OH- 0.50496E-02 -2.2967 0.44036E-02 -2.3562 0.87208E+00 -0.0594 79 HPO3-2 0.36930E-17 -17.4326 0.22751E-17 -17.6430 0.61607E+00 -0.2104 82 H3PO4,aq 0.38166E-16 -16.4183 0.38166E-16 -16.4183 0.10000E+01 0.0000 83 H2PO4- 0.87847E-09 -9.0563 0.76724E-09 -9.1151 0.87339E+00 -0.0588 84 PO4-3 0.56076E-08 -8.2512 0.19712E-08 -8.7053 0.35153E+00 -0.4540 87 H2P2O7-2 0.74923E-19 -19.1254 0.46157E-19 -19.3358 0.61607E+00 -0.2104 88 HP2O7-3 0.20514E-15 -15.6879 0.70245E-16 -16.1534 0.34242E+00 -0.4654 89 P2O7-4 0.83574E-15 -15.0779 0.12790E-15 -15.8931 0.15304E+00 -0.8152 90 H2S,aq 0.11216E-14 -14.9502 0.11198E-14 -14.9509 0.99839E+00 -0.0007 97 SO3-2 0.76021E-14 -14.1191 0.47202E-14 -14.3260 0.62091E+00 -0.2070 98 HSO3- 0.44421E-16 -16.3524 0.38777E-16 -16.4114 0.87294E+00 -0.0590 99 HSO4- 0.22809E-11 -11.6419 0.19942E-11 -11.7002 0.87431E+00 -0.0583 Charge balance for all species = 0.2988E-12 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.1498094E-09 -.9856015E-02 -.9926986E+01 0.0000 2 H2O 0.1000000E+01 0.5550871E+02 0.9992726E+06 0.0000 3 Cl- 0.1381052E-03 0.1384330E-03 0.4904267E+01 5.9632 4 SO4-- 0.2557102E-04 0.2559025E-04 0.2456437E+01 14.9620 5 HCO3- 0.6743989E-05 0.1311347E-04 0.7995602E+00 4.6523 6 HS- 0.3163181E-11 -.9545323E-09 -.3154514E-04 -1.6768 7 Al+++ 0.3222323E-27 0.2559580E-04 0.6901066E+00 1.6887 8 H4SiO4 0.5134369E-03 0.5183974E-02 0.4978943E+03 -3.2895 9 Ca++ 0.3755106E-07 0.5534699E-07 0.2216570E-02 12.1271 10 Mg++ 0.2351518E-10 0.7497302E-10 0.1821407E-05 8.9228 11 Fe++ 0.1175197E-12 0.2732098E-07 0.1524676E-02 6.6218 12 K+ 0.7411424E-04 0.7434331E-04 0.2904840E+01 5.6933 13 Na+ 0.9396579E-02 0.9908484E-02 0.2276270E+03 7.7960 14 Mn++ 0.1862477E-10 0.1053138E-08 0.5781487E-04 8.8220 15 HPO4-- 0.5139135E-06 0.5203996E-06 0.4991080E-01 13.2652 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.4304918E+00 -.9823345E-02 -.4206685E+00 0.0000000E+00 2 H2O 0.5518234E+02 0.5532471E+02 -.1423693E+00 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.7460254E-03 0.2550542E-04 0.7205200E-03 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.7205209E-03 -.9513683E-09 -.7205200E-03 0.0000000E+00 7 Al+++ 0.8477602E-01 0.2551096E-04 0.8475051E-01 0.0000000E+00 8 H4SiO4 0.2707219E+00 0.5166791E-02 0.2655552E+00 0.0000000E+00 9 Ca++ 0.2991703E-01 0.5516353E-07 0.2991697E-01 0.0000000E+00 10 Mg++ 0.2063413E-01 0.7472450E-10 0.2063413E-01 0.0000000E+00 11 Fe++ 0.1853751E-01 0.2723042E-07 0.1853748E-01 0.0000000E+00 12 K+ 0.5519958E-02 0.7409688E-04 0.5445861E-02 0.0000000E+00 13 Na+ 0.3279515E-01 0.9875640E-02 0.2291951E-01 0.0000000E+00 14 Mn++ 0.4507862E-03 0.1049647E-08 0.4507851E-03 0.0000000E+00 15 HPO4-- 0.1538511E-03 0.5186746E-06 0.1533324E-03 0.0000000E+00 Chg. balance for solid moles: -.4391E-17 Mass of aqueous solution: 0.997417E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 25.9990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 0.2284E-01 -1.641 5.989 0.777 21.10 2.299 andradite 0.2645E-02 -2.578 1.344 0.128 4.736 0.3492 grossular 0.1044E-03 -3.981 0.4702E-01 -1.328 0.1657 0.1308E-01 apatite-OH 0.5111E-04 -4.291 0.2567E-01 -1.591 0.9046E-01 0.8158E-02 clinochlore 0.4127E-02 -2.384 2.294 0.361 8.082 0.8725 daphnite 0.2165E-02 -2.665 1.545 0.189 5.443 0.4681 chlorite-Mn 0.9016E-04 -4.045 0.6392E-01 -1.194 0.2252 0.2037E-01 microcline 0.5251E-02 -2.280 1.462 0.165 5.150 0.5709 stilbite 0.2141E-01 -1.669 15.09 1.179 53.17 7.039 stilpnomelane-Fe 0.3895E-03 -3.409 0.4199 -0.377 1.479 0.1450 nontronite-Na 0.2373E-03 -3.625 0.1009 -0.996 0.3555 0.3135E-01 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.9620E+00 0.9620E+00 1.0000 -0.017 grossular 0.3797E-01 0.3797E-01 1.0000 -1.421 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.6466E+00 0.6466E+00 1.0000 -0.189 daphnite 0.3393E+00 0.3393E+00 1.0000 -0.469 chlorite-Mn 0.1413E-01 0.1413E-01 1.0000 -1.850 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 nontronite-Na 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 28.381935 g Volume = 11.816591 cm3 Porosity: -3.6579% V(tot) - V(min): -.41699E+00 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 25.9990000 g log = 1.4150 Original solution: 1000.0103000 g Original solution / Rock added: 38.46 (Water/Rock Ratio), log = 1.5850 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0203 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.1000E+01 0.9860 0.1006E+01 0.1020E+01 CO2,gas 0.1720E-06 1.0071 0.1767E-06 0.1755E-06 CH4,gas 0.1428E-14 1.0125 0.1475E-14 0.1457E-14 H2,gas 0.2962E-05 1.0005 0.3024E-05 0.3022E-05 H2S,gas 0.3029E-13 0.9960 0.3078E-13 0.3090E-13 S2,gas 0.3813E-35 1.0000 0.3890E-35 0.3890E-35 CO,gas 0.1396E-15 1.0000 0.1424E-15 0.1424E-15 SO3,gas 0.1006E-39 1.0000 0.1027E-39 0.1027E-39 SO2,gas 0.1184E-22 1.0000 0.1208E-22 0.1208E-22 HCl,gas 0.5013E-17 1.0000 0.5115E-17 0.5115E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 16 albite -0.38 -0.38 0.00 0.000 0.11184E-10 22 andradite 39.01 39.01 0.00 0.000 0.12132E-10 23 grossular 32.73 32.73 0.00 0.000 0.12132E-10 32 apatite-OH -18.15 -18.15 0.00 0.000 0.00000E+00 46 clinochlore 39.07 39.07 0.00 0.000 0.00000E+00 47 daphnite 28.97 28.97 0.00 0.000 -0.36397E-10 48 chlorite-Mn 46.87 46.87 0.00 0.000 0.24265E-10 116 microcline -2.49 -2.49 0.00 0.000 0.15165E-11 163 stilbite -7.52 -7.52 0.00 0.000 0.15165E-10 164 stilpnomelane-Fe 13.02 13.02 0.00 0.000 -0.27298E-10 209 nontronite-Na 3.52 3.52 0.00 0.000 0.23506E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -15.11 -8.45 -2.817 0.14431E+05 -6.753 3 CH4,gas 4.54 -11.99 -16.53 -4.133 0.28225E+05 -14.831 4 H2,gas 8.00 0.78 -7.22 -4.125 0.12325E+05 -5.519 5 H2S,gas -6.23 -21.44 -15.21 -7.605 0.25972E+05 -13.512 6 S2,gas -7.34 -44.44 -37.11 -5.709 0.63363E+05 -35.410 7 CO,gas 3.21 -14.33 -17.55 -5.399 0.29958E+05 -15.846 8 SO3,gas 17.12 -24.57 -41.69 -10.422 0.71180E+05 -39.989 9 SO2,gas 0.83 -23.78 -24.62 -6.565 0.42033E+05 -22.918 10 HCl,gas 5.19 -13.80 -18.99 -9.495 0.32425E+05 -17.291 11 acmite 7.71 7.45 -0.26 -0.027 0.44674E+03 15 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 19 spessartine 24.46 19.97 -4.48 -0.224 0.76538E+04 20 analcite 3.32 2.91 -0.42 -0.046 0.71068E+03 21 andalusite 5.00 0.09 -4.91 -0.491 0.83899E+04 26 annite 20.12 17.38 -2.74 -0.152 0.46861E+04 27 phlogopite 27.06 24.28 -2.78 -0.155 0.47515E+04 29 anorthite 12.71 8.93 -3.78 -0.291 0.64624E+04 35 aragonite 0.97 -2.98 -3.95 -1.317 0.67466E+04 36 brucite 12.57 8.92 -3.65 -0.729 0.62251E+04 37 calcite 0.81 -2.98 -3.80 -1.265 0.64823E+04 38 carnegieite-low 9.02 6.20 -2.83 -0.404 0.48290E+04 39 carnegieite-high 10.09 6.20 -3.90 -0.557 0.66560E+04 40 carpholite-Mg 8.58 5.72 -2.86 -0.191 0.48850E+04 41 carpholite-Fe 6.71 3.42 -3.29 -0.219 0.56218E+04 42 celadonite 5.34 3.15 -2.19 -0.129 0.37476E+04 43 celadonite-Fe 3.88 0.85 -3.03 -0.178 0.51749E+04 44 chrysotile 23.89 20.19 -3.70 -0.309 0.63229E+04 50 chloritoid-Mg 13.20 9.01 -4.19 -0.279 0.71492E+04 51 chloritoid-Fe 9.17 6.71 -2.46 -0.164 0.42071E+04 52 chloritoid-Mn 11.40 8.91 -2.49 -0.166 0.42537E+04 54 coesite -2.38 -3.29 -0.91 -0.304 0.15597E+04 61 cristobalite -2.56 -3.29 -0.73 -0.243 0.12450E+04 63 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71234E+04 65 diaspore 2.87 1.69 -1.18 -0.197 0.20233E+04 67 diopside 16.18 14.47 -1.71 -0.171 0.29206E+04 68 hedenbergite 14.21 12.17 -2.04 -0.204 0.34805E+04 75 epidote 24.67 23.99 -0.68 -0.033 0.11537E+04 76 clinozoisite 22.81 19.45 -3.35 -0.152 0.57272E+04 77 epidote-Fe 29.84 28.54 -1.30 -0.068 0.22267E+04 78 fayalite 14.05 9.95 -4.09 -0.585 0.69864E+04 79 ferrosilite 11.15 6.66 -4.48 -0.448 0.76578E+04 83 gibbsite 4.08 1.69 -2.39 -0.342 0.40819E+04 84 glaucophane 22.97 19.42 -3.55 -0.096 0.60670E+04 85 glaucophane-Fe 17.28 12.52 -4.76 -0.129 0.81228E+04 87 greenalite 16.14 13.29 -2.85 -0.238 0.48716E+04 90 hematite 12.57 12.46 -0.10 -0.013 0.17743E+03 91 heulandite -5.83 -7.52 -1.69 -0.077 0.28938E+04 95 jadeite 4.22 2.91 -1.31 -0.131 0.22362E+04 96 julgoldite 70.43 66.94 -3.49 -0.091 0.59545E+04 97 kalsilite 7.58 4.09 -3.49 -0.499 0.59614E+04 98 kaolinite -1.33 -3.20 -1.87 -0.170 0.31910E+04 99 kyanite 4.88 0.09 -4.79 -0.479 0.81758E+04 101 laumontite 2.88 2.35 -0.54 -0.036 0.91679E+03 102 lawsonite 9.62 8.93 -0.69 -0.046 0.11791E+04 103 leucite 4.12 0.80 -3.32 -0.332 0.56617E+04 105 lizardite 23.24 20.19 -3.05 -0.255 0.52155E+04 107 magnetite 20.09 19.08 -1.00 -0.082 0.17131E+04 108 minnesotaite 10.39 6.71 -3.68 -0.217 0.62848E+04 110 magnesioferrite 26.21 21.39 -4.83 -0.394 0.82426E+04 120 muscovite 2.58 0.89 -1.69 -0.100 0.28882E+04 121 paragonite 4.24 2.99 -1.25 -0.073 0.21273E+04 122 nepheline 8.34 6.20 -2.14 -0.306 0.36613E+04 134 phlogopite-Na 29.65 26.38 -3.26 -0.181 0.55703E+04 136 prehnite 19.37 17.76 -1.61 -0.095 0.27469E+04 137 prehnite-Fe 22.50 22.31 -0.19 -0.012 0.32835E+03 138 pumpellyite-Fe 46.27 43.84 -2.43 -0.054 0.41537E+04 139 pumpellyite-Mg 48.99 46.14 -2.86 -0.063 0.48785E+04 145 pyroxmangite 7.40 5.53 -1.87 -0.373 0.31865E+04 146 pyrophyllite -6.18 -9.78 -3.60 -0.225 0.61552E+04 147 quartz -2.99 -3.29 -0.30 -0.100 0.51237E+03 152 rhodonite 7.45 5.53 -1.91 -0.383 0.32668E+04 153 sanidine -1.28 -2.49 -1.21 -0.093 0.20677E+04 165 stilpnomelane-Mg 27.44 24.52 -2.92 -0.087 0.49850E+04 171 talc 16.49 13.61 -2.88 -0.169 0.49189E+04 174 tephroite 18.09 14.35 -3.73 -0.533 0.63712E+04 177 topaz-H 4.62 0.09 -4.53 -0.412 0.77359E+04 178 tridymite -2.63 -3.29 -0.66 -0.221 0.11324E+04 187 wairakite 3.95 2.35 -1.60 -0.094 0.27387E+04 188 walstromite 11.51 8.84 -2.67 -0.534 0.45617E+04 189 wollastonite 10.46 8.84 -1.62 -0.325 0.27721E+04 190 pseudo-wollastonite 11.00 8.84 -2.16 -0.432 0.36920E+04 191 zoisite 22.85 19.45 -3.40 -0.154 0.58013E+04 192 akaganeite 7.75 6.23 -1.52 -0.329 0.26012E+04 193 beidellite-Ca -1.65 -6.14 -4.49 -0.278 0.76687E+04 195 beidellite-K -1.52 -6.26 -4.74 -0.290 0.80914E+04 196 beidellite-Mg -1.79 -6.67 -4.88 -0.302 0.83253E+04 197 beidellite-Na -1.34 -5.57 -4.22 -0.259 0.72105E+04 199 chalcedony -2.80 -3.29 -0.49 -0.162 0.83167E+03 201 montmorillonite-Ca -2.29 -5.39 -3.10 -0.192 0.52961E+04 202 montmorillonite-K -2.24 -5.51 -3.28 -0.201 0.55969E+04 203 montmorillonite-Mg -2.48 -5.92 -3.44 -0.213 0.58759E+04 204 montmorillonite-Na -2.04 -4.82 -2.78 -0.170 0.47518E+04 205 nontronite-Ca 3.21 2.95 -0.27 -0.017 0.45510E+03 206 nontronite-H 2.53 0.95 -1.59 -0.106 0.27075E+04 207 nontronite-K 3.34 2.83 -0.51 -0.033 0.87912E+03 208 nontronite-Mg 3.07 2.42 -0.66 -0.043 0.11190E+04 224 tobermorite 9.82 6.81 -3.01 -0.821 0.51406E+04 233 boehmite 4.41 1.69 -2.72 -0.453 0.46403E+04 235 ferrous-oxide 9.81 6.62 -3.19 -0.797 0.54465E+04 240 silica-amorphous -2.09 -3.29 -1.20 -0.399 0.20459E+04 242 an20ab80 2.02 1.48 -0.54 -0.042 0.92164E+03 243 an25ab75 2.65 1.94 -0.70 -0.054 0.11990E+04 244 an30ab70 3.28 2.41 -0.87 -0.067 0.14860E+04 245 tr.625ac.25prg.125 45.16 40.99 -4.17 -0.112 0.71272E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 1.0000000 g Current total amount of reactant added: 25.9990000 g New total amount of reactant added: 26.9990000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.2992E-12 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 9 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 26.9990000 Water: Moles liquid = 0.5532E+02 kg liquid = 0.9966E+00 Moles total = 0.5517E+02 kg total = 0.9939E+00 Activity = 1.0000 Stoichiometric ionic strength = .5265161E-02 Osmotic coef. = 0.9615 True ionic strength = .9564657E-02 Chg. balance for total moles = 0.2992E-12 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.14982E-09 -9.8244 0.13117E-09 -9.8822 0.87553E+00 -0.0577 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13812E-03 -3.8597 0.12053E-03 -3.9189 0.87265E+00 -0.0592 4 SO4-- 0.25574E-04 -4.5922 0.15753E-04 -4.8026 0.61598E+00 -0.2104 5 HCO3- 0.67406E-05 -5.1713 0.58869E-05 -5.2301 0.87334E+00 -0.0588 6 HS- 0.35512E-11 -11.4496 0.30992E-11 -11.5087 0.87272E+00 -0.0591 7 Al+++ 0.30814E-27 -27.5113 0.10516E-27 -27.9782 0.34126E+00 -0.4669 8 H4SiO4 0.52041E-03 -3.2837 0.52041E-03 -3.2837 0.10000E+01 0.0000 9 Ca++ 0.37554E-07 -7.4253 0.23040E-07 -7.6375 0.61353E+00 -0.2122 10 Mg++ 0.23958E-10 -10.6206 0.14662E-10 -10.8338 0.61199E+00 -0.2133 11 Fe++ 0.11721E-12 -12.9311 0.71772E-13 -13.1440 0.61236E+00 -0.2130 12 K+ 0.74594E-04 -4.1273 0.65155E-04 -4.1861 0.87346E+00 -0.0588 13 Na+ 0.94575E-02 -2.0242 0.82523E-02 -2.0834 0.87257E+00 -0.0592 14 Mn++ 0.18975E-10 -10.7218 0.11625E-10 -10.9346 0.61264E+00 -0.2128 15 HPO4-- 0.51547E-06 -6.2878 0.31755E-06 -6.4982 0.61602E+00 -0.2104 16 HSiO3- 0.42452E-02 -2.3721 0.37046E-02 -2.4313 0.87265E+00 -0.0592 17 Ca(HSiO3)+ 0.22252E-08 -8.6526 0.19439E-08 -8.7113 0.87357E+00 -0.0587 18 Mg(HSiO3)+ 0.17623E-11 -11.7539 0.15395E-11 -11.8126 0.87357E+00 -0.0587 19 NaHSiO3,aq 0.49446E-03 -3.3059 0.49446E-03 -3.3059 0.10000E+01 0.0000 20 AlO+ 0.95182E-15 -15.0214 0.83147E-15 -15.0802 0.87357E+00 -0.0587 22 HAlO2,aq 0.12624E-08 -8.8988 0.12624E-08 -8.8988 0.10000E+01 0.0000 23 AlO2- 0.24437E-04 -4.6120 0.21304E-04 -4.6715 0.87178E+00 -0.0596 24 CH4,aq 0.11269E-17 -17.9481 0.11251E-17 -17.9488 0.99838E+00 -0.0007 29 CO,aq 0.98290E-19 -19.0075 0.98290E-19 -19.0075 0.10000E+01 0.0000 30 CO2,aq 0.16527E-08 -8.7818 0.16500E-08 -8.7825 0.99838E+00 -0.0007 31 CO3-2 0.63714E-05 -5.1958 0.39201E-05 -5.4067 0.61526E+00 -0.2109 32 CaCO3,aq 0.11325E-08 -8.9460 0.11325E-08 -8.9460 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.39633E-11 -11.4019 0.34622E-11 -11.4606 0.87357E+00 -0.0587 34 CaCl+ 0.51445E-11 -11.2887 0.44941E-11 -11.3474 0.87357E+00 -0.0587 35 CaCl2,aq 0.12869E-15 -15.8905 0.12869E-15 -15.8905 0.10000E+01 0.0000 36 CaOH+ 0.14330E-07 -7.8437 0.12519E-07 -7.9024 0.87357E+00 -0.0587 37 CaSO4,aq 0.11525E-09 -9.9383 0.11525E-09 -9.9383 0.10000E+01 0.0000 38 HCl,aq 0.28971E-14 -14.5380 0.28971E-14 -14.5380 0.10000E+01 0.0000 43 FeCl+ 0.15674E-16 -16.8048 0.13692E-16 -16.8635 0.87357E+00 -0.0587 46 FeO,aq 0.16213E-09 -9.7901 0.16213E-09 -9.7901 0.10000E+01 0.0000 47 FeOH+ 0.20389E-10 -10.6906 0.17811E-10 -10.7493 0.87357E+00 -0.0587 48 HFeO2- 0.14820E-07 -7.8292 0.12932E-07 -7.8883 0.87265E+00 -0.0592 49 FeO+ 0.99865E-15 -15.0006 0.87239E-15 -15.0593 0.87357E+00 -0.0587 51 FeO2- 0.11889E-07 -7.9248 0.10375E-07 -7.9840 0.87265E+00 -0.0592 52 HFeO2,aq 0.17309E-09 -9.7617 0.17309E-09 -9.7617 0.10000E+01 0.0000 53 H2,aq 0.23752E-08 -8.6243 0.23714E-08 -8.6250 0.99838E+00 -0.0007 54 KCl,aq 0.14233E-09 -9.8467 0.14233E-09 -9.8467 0.10000E+01 0.0000 55 KHSO4,aq 0.38065E-18 -18.4195 0.38065E-18 -18.4195 0.10000E+01 0.0000 56 KOH,aq 0.21213E-06 -6.6734 0.21213E-06 -6.6734 0.10000E+01 0.0000 57 KSO4- 0.18251E-07 -7.7387 0.15927E-07 -7.7979 0.87265E+00 -0.0592 58 MgCO3,aq 0.18065E-12 -12.7432 0.18065E-12 -12.7432 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.25771E-14 -14.5889 0.22513E-14 -14.6476 0.87357E+00 -0.0587 60 MgCl+ 0.29672E-14 -14.5277 0.25920E-14 -14.5864 0.87357E+00 -0.0587 61 MgOH+ 0.50462E-10 -10.2970 0.44082E-10 -10.3557 0.87357E+00 -0.0587 63 MnO,aq 0.69970E-09 -9.1551 0.69970E-09 -9.1551 0.10000E+01 0.0000 64 MnOH+ 0.30678E-09 -9.5132 0.26799E-09 -9.5719 0.87357E+00 -0.0587 65 MnO2-2 0.21936E-11 -11.6588 0.13496E-11 -11.8698 0.61526E+00 -0.2109 66 HMnO2- 0.44445E-10 -10.3522 0.38785E-10 -10.4113 0.87265E+00 -0.0592 69 MnCl+ 0.98768E-14 -14.0054 0.86281E-14 -14.0641 0.87357E+00 -0.0587 70 MnSO4,aq 0.52866E-13 -13.2768 0.52866E-13 -13.2768 0.10000E+01 0.0000 71 NaCl,aq 0.32963E-06 -6.4820 0.32963E-06 -6.4820 0.10000E+01 0.0000 72 NaOH,aq 0.27031E-04 -4.5681 0.27031E-04 -4.5681 0.10000E+01 0.0000 74 OH- 0.50526E-02 -2.2965 0.44048E-02 -2.3561 0.87178E+00 -0.0596 79 HPO3-2 0.38141E-17 -17.4186 0.23467E-17 -17.6296 0.61526E+00 -0.2109 82 H3PO4,aq 0.38212E-16 -16.4178 0.38212E-16 -16.4178 0.10000E+01 0.0000 83 H2PO4- 0.88005E-09 -9.0555 0.76837E-09 -9.1144 0.87310E+00 -0.0589 84 PO4-3 0.56347E-08 -8.2491 0.19752E-08 -8.7044 0.35054E+00 -0.4553 87 H2P2O7-2 0.75241E-19 -19.1235 0.46293E-19 -19.3345 0.61526E+00 -0.2109 88 HP2O7-3 0.20641E-15 -15.6853 0.70471E-16 -16.1520 0.34141E+00 -0.4667 89 P2O7-4 0.84301E-15 -15.0742 0.12835E-15 -15.8916 0.15225E+00 -0.8174 90 H2S,aq 0.12585E-14 -14.9002 0.12564E-14 -14.9009 0.99838E+00 -0.0007 97 SO3-2 0.78280E-14 -14.1063 0.48544E-14 -14.3139 0.62013E+00 -0.2075 98 HSO3- 0.45686E-16 -16.3402 0.39868E-16 -16.3994 0.87265E+00 -0.0592 99 HSO4- 0.22783E-11 -11.6424 0.19913E-11 -11.7009 0.87402E+00 -0.0585 Charge balance for all species = 0.2989E-12 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.1498169E-09 -.9923785E-02 -.9995168E+01 0.0000 2 H2O 0.1000000E+01 0.5550864E+02 0.9992637E+06 0.0000 3 Cl- 0.1381183E-03 0.1384480E-03 0.4904761E+01 5.9633 4 SO4-- 0.2557369E-04 0.2559297E-04 0.2456680E+01 14.9617 5 HCO3- 0.6740647E-05 0.1311489E-04 0.7996406E+00 4.6521 6 HS- 0.3551238E-11 -.9104281E-09 -.3008737E-04 -1.6266 7 Al+++ 0.3081405E-27 0.2443818E-04 0.6588902E+00 1.6683 8 H4SiO4 0.5204149E-03 0.5260121E-02 0.5052039E+03 -3.2837 9 Ca++ 0.3755372E-07 0.5536624E-07 0.2217324E-02 12.1268 10 Mg++ 0.2395767E-10 0.7636828E-10 0.1855290E-05 8.9305 11 Fe++ 0.1172051E-12 0.2706463E-07 0.1510358E-02 6.6203 12 K+ 0.7459397E-04 0.7482450E-04 0.2923619E+01 5.6961 13 Na+ 0.9457456E-02 0.9979271E-02 0.2292514E+03 7.7987 14 Mn++ 0.1897513E-10 0.1072157E-08 0.5885849E-04 8.8297 15 HPO4-- 0.5154748E-06 0.5219896E-06 0.5006291E-01 13.2661 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.4470503E+00 -.9889821E-02 -.4371605E+00 0.0000000E+00 2 H2O 0.5516981E+02 0.5531866E+02 -.1488506E+00 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.7737388E-03 0.2550538E-04 0.7482334E-03 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.7482343E-03 -.9073121E-09 -.7482334E-03 0.0000000E+00 7 Al+++ 0.8803676E-01 0.2435454E-04 0.8801241E-01 0.0000000E+00 8 H4SiO4 0.2811347E+00 0.5242118E-02 0.2758926E+00 0.0000000E+00 9 Ca++ 0.3106717E-01 0.5517675E-07 0.3106712E-01 0.0000000E+00 10 Mg++ 0.2142778E-01 0.7610691E-10 0.2142778E-01 0.0000000E+00 11 Fe++ 0.1925052E-01 0.2697200E-07 0.1925049E-01 0.0000000E+00 12 K+ 0.5732272E-02 0.7456841E-04 0.5657703E-02 0.0000000E+00 13 Na+ 0.3405039E-01 0.9945116E-02 0.2410528E-01 0.0000000E+00 14 Mn++ 0.4681248E-03 0.1068487E-08 0.4681237E-03 0.0000000E+00 15 HPO4-- 0.1597687E-03 0.5202030E-06 0.1592484E-03 0.0000000E+00 Chg. balance for solid moles: 0.9796E-16 Mass of aqueous solution: 0.997316E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 26.9990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 0.2404E-01 -1.619 6.304 0.800 21.39 2.420 andradite 0.2794E-02 -2.554 1.420 0.152 4.817 0.3689 grossular 0.1071E-03 -3.970 0.4826E-01 -1.316 0.1637 0.1343E-01 apatite-OH 0.5308E-04 -4.275 0.2666E-01 -1.574 0.9047E-01 0.8473E-02 clinochlore 0.4286E-02 -2.368 2.382 0.377 8.082 0.9061 daphnite 0.2201E-02 -2.657 1.570 0.196 5.328 0.4759 chlorite-Mn 0.9362E-04 -4.029 0.6638E-01 -1.178 0.2252 0.2115E-01 microcline 0.5432E-02 -2.265 1.512 0.180 5.129 0.5906 stilbite 0.2210E-01 -1.656 15.57 1.192 52.84 7.264 stilpnomelane-Fe 0.4519E-03 -3.345 0.4872 -0.312 1.653 0.1683 nontronite-Na 0.1990E-03 -3.701 0.8462E-01 -1.073 0.2871 0.2629E-01 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.9631E+00 0.9631E+00 1.0000 -0.016 grossular 0.3693E-01 0.3693E-01 1.0000 -1.433 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.6513E+00 0.6513E+00 1.0000 -0.186 daphnite 0.3345E+00 0.3345E+00 1.0000 -0.476 chlorite-Mn 0.1423E-01 0.1423E-01 1.0000 -1.847 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 nontronite-Na 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 29.474148 g Volume = 12.262491 cm3 Porosity: -3.9229% V(tot) - V(min): -.46289E+00 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 26.9990000 g log = 1.4313 Original solution: 1000.0103000 g Original solution / Rock added: 37.04 (Water/Rock Ratio), log = 1.5687 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0203 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.1000E+01 0.9860 0.1006E+01 0.1020E+01 CO2,gas 0.1718E-06 1.0071 0.1765E-06 0.1753E-06 CH4,gas 0.1603E-14 1.0125 0.1656E-14 0.1636E-14 H2,gas 0.3050E-05 1.0005 0.3113E-05 0.3112E-05 H2S,gas 0.3399E-13 0.9960 0.3454E-13 0.3468E-13 S2,gas 0.4528E-35 1.0000 0.4619E-35 0.4619E-35 CO,gas 0.1436E-15 1.0000 0.1465E-15 0.1465E-15 SO3,gas 0.1004E-39 1.0000 0.1025E-39 0.1025E-39 SO2,gas 0.1217E-22 1.0000 0.1241E-22 0.1241E-22 HCl,gas 0.5010E-17 1.0000 0.5112E-17 0.5112E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 16 albite -0.38 -0.38 0.00 0.000 0.11184E-10 22 andradite 39.01 39.01 0.00 0.000 -0.24265E-10 23 grossular 32.73 32.73 0.00 0.000 0.00000E+00 32 apatite-OH -18.15 -18.15 0.00 0.000 0.60662E-11 46 clinochlore 39.07 39.07 0.00 0.000 0.36397E-10 47 daphnite 28.97 28.97 0.00 0.000 -0.30331E-10 48 chlorite-Mn 46.87 46.87 0.00 0.000 0.36397E-10 116 microcline -2.49 -2.49 0.00 0.000 0.15165E-11 163 stilbite -7.52 -7.52 0.00 0.000 -0.90992E-11 164 stilpnomelane-Fe 13.02 13.02 0.00 0.000 -0.27298E-10 209 nontronite-Na 3.52 3.52 0.00 0.000 -0.83410E-11 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -15.11 -8.45 -2.817 0.14432E+05 -6.753 3 CH4,gas 4.54 -11.94 -16.48 -4.120 0.28139E+05 -14.781 4 H2,gas 8.00 0.79 -7.21 -4.118 0.12304E+05 -5.507 5 H2S,gas -6.23 -21.39 -15.16 -7.580 0.25886E+05 -13.462 6 S2,gas -7.34 -44.37 -37.03 -5.698 0.63235E+05 -35.335 7 CO,gas 3.21 -14.32 -17.53 -5.395 0.29937E+05 -15.834 8 SO3,gas 17.12 -24.57 -41.69 -10.422 0.71182E+05 -39.989 9 SO2,gas 0.83 -23.77 -24.61 -6.561 0.42013E+05 -22.906 10 HCl,gas 5.19 -13.80 -18.99 -9.495 0.32426E+05 -17.291 11 acmite 7.71 7.45 -0.25 -0.026 0.43539E+03 15 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 19 spessartine 24.46 19.97 -4.48 -0.224 0.76536E+04 20 analcite 3.32 2.90 -0.42 -0.047 0.72069E+03 21 andalusite 5.00 0.05 -4.95 -0.495 0.84494E+04 26 annite 20.12 17.37 -2.75 -0.153 0.46939E+04 27 phlogopite 27.06 24.31 -2.76 -0.153 0.47118E+04 29 anorthite 12.71 8.90 -3.81 -0.293 0.65125E+04 35 aragonite 0.97 -2.99 -3.95 -1.317 0.67479E+04 36 brucite 12.57 8.93 -3.64 -0.728 0.62119E+04 37 calcite 0.81 -2.99 -3.80 -1.266 0.64837E+04 38 carnegieite-low 9.02 6.18 -2.84 -0.406 0.48490E+04 39 carnegieite-high 10.09 6.18 -3.91 -0.559 0.66760E+04 40 carpholite-Mg 8.58 5.70 -2.88 -0.192 0.49213E+04 41 carpholite-Fe 6.71 3.39 -3.32 -0.222 0.56739E+04 42 celadonite 5.34 3.16 -2.18 -0.128 0.37244E+04 43 celadonite-Fe 3.88 0.85 -3.03 -0.178 0.51675E+04 44 chrysotile 23.89 20.22 -3.67 -0.306 0.62632E+04 50 chloritoid-Mg 13.20 8.98 -4.21 -0.281 0.71955E+04 51 chloritoid-Fe 9.17 6.67 -2.50 -0.167 0.42692E+04 52 chloritoid-Mn 11.40 8.88 -2.52 -0.168 0.43000E+04 54 coesite -2.38 -3.28 -0.91 -0.303 0.15497E+04 61 cristobalite -2.56 -3.28 -0.72 -0.241 0.12350E+04 63 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71234E+04 65 diaspore 2.87 1.67 -1.21 -0.201 0.20581E+04 67 diopside 16.18 14.49 -1.69 -0.169 0.28879E+04 68 hedenbergite 14.21 12.18 -2.03 -0.203 0.34636E+04 75 epidote 24.67 23.96 -0.71 -0.034 0.12076E+04 76 clinozoisite 22.81 19.41 -3.40 -0.154 0.58025E+04 77 epidote-Fe 29.84 28.52 -1.32 -0.069 0.22594E+04 78 fayalite 14.05 9.96 -4.09 -0.584 0.69815E+04 79 ferrosilite 11.15 6.67 -4.48 -0.448 0.76430E+04 83 gibbsite 4.08 1.67 -2.41 -0.344 0.41167E+04 84 glaucophane 22.97 19.46 -3.52 -0.095 0.60073E+04 85 glaucophane-Fe 17.28 12.53 -4.75 -0.128 0.81105E+04 87 greenalite 16.14 13.29 -2.85 -0.237 0.48594E+04 90 hematite 12.57 12.45 -0.12 -0.014 0.20426E+03 91 heulandite -5.83 -7.52 -1.69 -0.077 0.28938E+04 95 jadeite 4.22 2.90 -1.32 -0.132 0.22462E+04 96 julgoldite 70.43 66.94 -3.49 -0.091 0.59554E+04 97 kalsilite 7.58 4.08 -3.50 -0.500 0.59814E+04 98 kaolinite -1.33 -3.23 -1.90 -0.173 0.32405E+04 99 kyanite 4.88 0.05 -4.82 -0.482 0.82353E+04 101 laumontite 2.88 2.33 -0.55 -0.037 0.94682E+03 102 lawsonite 9.62 8.90 -0.72 -0.048 0.12292E+04 103 leucite 4.12 0.80 -3.32 -0.332 0.56717E+04 105 lizardite 23.24 20.22 -3.02 -0.252 0.51558E+04 107 magnetite 20.09 19.07 -1.02 -0.083 0.17426E+04 108 minnesotaite 10.39 6.73 -3.66 -0.215 0.62525E+04 110 magnesioferrite 26.21 21.38 -4.84 -0.395 0.82562E+04 120 muscovite 2.58 0.85 -1.73 -0.102 0.29578E+04 121 paragonite 4.24 2.95 -1.29 -0.076 0.21969E+04 122 nepheline 8.34 6.18 -2.16 -0.308 0.36813E+04 134 phlogopite-Na 29.65 26.41 -3.24 -0.180 0.55306E+04 136 prehnite 19.37 17.74 -1.63 -0.096 0.27875E+04 137 prehnite-Fe 22.50 22.29 -0.20 -0.012 0.34757E+03 138 pumpellyite-Fe 46.27 43.77 -2.50 -0.056 0.42722E+04 139 pumpellyite-Mg 48.99 46.08 -2.92 -0.065 0.49812E+04 145 pyroxmangite 7.40 5.55 -1.85 -0.371 0.31633E+04 146 pyrophyllite -6.18 -9.80 -3.62 -0.226 0.61847E+04 147 quartz -2.99 -3.28 -0.29 -0.098 0.50236E+03 152 rhodonite 7.45 5.55 -1.90 -0.380 0.32435E+04 153 sanidine -1.28 -2.49 -1.21 -0.093 0.20677E+04 165 stilpnomelane-Mg 27.44 24.57 -2.87 -0.086 0.49060E+04 171 talc 16.49 13.66 -2.83 -0.167 0.48391E+04 174 tephroite 18.09 14.38 -3.71 -0.530 0.63347E+04 177 topaz-H 4.62 0.05 -4.57 -0.415 0.77954E+04 178 tridymite -2.63 -3.28 -0.66 -0.219 0.11223E+04 187 wairakite 3.95 2.33 -1.62 -0.095 0.27688E+04 188 walstromite 11.51 8.84 -2.67 -0.533 0.45522E+04 189 wollastonite 10.46 8.84 -1.62 -0.324 0.27627E+04 190 pseudo-wollastonite 11.00 8.84 -2.16 -0.431 0.36825E+04 191 zoisite 22.85 19.41 -3.44 -0.156 0.58766E+04 192 akaganeite 7.75 6.22 -1.53 -0.331 0.26147E+04 193 beidellite-Ca -1.65 -6.16 -4.52 -0.279 0.77131E+04 195 beidellite-K -1.52 -6.28 -4.76 -0.292 0.81341E+04 196 beidellite-Mg -1.79 -6.69 -4.90 -0.303 0.83674E+04 197 beidellite-Na -1.34 -5.59 -4.25 -0.260 0.72533E+04 199 chalcedony -2.80 -3.28 -0.48 -0.160 0.82166E+03 201 montmorillonite-Ca -2.29 -5.40 -3.11 -0.192 0.53098E+04 202 montmorillonite-K -2.24 -5.52 -3.28 -0.201 0.56090E+04 203 montmorillonite-Mg -2.48 -5.93 -3.45 -0.213 0.58873E+04 204 montmorillonite-Na -2.04 -4.83 -2.79 -0.171 0.47639E+04 205 nontronite-Ca 3.21 2.95 -0.27 -0.017 0.45675E+03 206 nontronite-H 2.53 0.95 -1.59 -0.106 0.27091E+04 207 nontronite-K 3.34 2.83 -0.51 -0.033 0.87912E+03 208 nontronite-Mg 3.07 2.42 -0.65 -0.042 0.11183E+04 224 tobermorite 9.82 6.82 -3.01 -0.820 0.51311E+04 233 boehmite 4.41 1.67 -2.74 -0.456 0.46750E+04 235 ferrous-oxide 9.81 6.62 -3.19 -0.798 0.54491E+04 240 silica-amorphous -2.09 -3.28 -1.19 -0.397 0.20358E+04 242 an20ab80 2.02 1.47 -0.55 -0.042 0.93165E+03 243 an25ab75 2.65 1.94 -0.71 -0.055 0.12115E+04 244 an30ab70 3.28 2.40 -0.88 -0.068 0.15010E+04 245 tr.625ac.25prg.125 45.16 41.05 -4.11 -0.111 0.70184E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 1.0000000 g Current total amount of reactant added: 26.9990000 g New total amount of reactant added: 27.9990000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.2992E-12 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 9 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 27.9990000 Water: Moles liquid = 0.5531E+02 kg liquid = 0.9965E+00 Moles total = 0.5516E+02 kg total = 0.9937E+00 Activity = 1.0000 Stoichiometric ionic strength = .5295133E-02 Osmotic coef. = 0.9614 True ionic strength = .9624430E-02 Chg. balance for total moles = 0.2992E-12 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.14983E-09 -9.8244 0.13114E-09 -9.8823 0.87526E+00 -0.0579 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13813E-03 -3.8597 0.12050E-03 -3.9190 0.87237E+00 -0.0593 4 SO4-- 0.25576E-04 -4.5922 0.15735E-04 -4.8031 0.61520E+00 -0.2110 5 HCO3- 0.67375E-05 -5.1715 0.58823E-05 -5.2305 0.87307E+00 -0.0590 6 HS- 0.39705E-11 -11.4011 0.34641E-11 -11.4604 0.87244E+00 -0.0593 7 Al+++ 0.29517E-27 -27.5299 0.10044E-27 -27.9981 0.34028E+00 -0.4682 8 H4SiO4 0.52723E-03 -3.2780 0.52723E-03 -3.2780 0.10000E+01 0.0000 9 Ca++ 0.37558E-07 -7.4253 0.23013E-07 -7.6380 0.61274E+00 -0.2127 10 Mg++ 0.24390E-10 -10.6128 0.14907E-10 -10.8266 0.61120E+00 -0.2138 11 Fe++ 0.11691E-12 -12.9321 0.71498E-13 -13.1457 0.61157E+00 -0.2136 12 K+ 0.75061E-04 -4.1246 0.65542E-04 -4.1835 0.87319E+00 -0.0589 13 Na+ 0.95168E-02 -2.0215 0.83014E-02 -2.0808 0.87229E+00 -0.0593 14 Mn++ 0.19318E-10 -10.7140 0.11819E-10 -10.9274 0.61185E+00 -0.2134 15 HPO4-- 0.51697E-06 -6.2865 0.31807E-06 -6.4975 0.61525E+00 -0.2110 16 HSiO3- 0.43032E-02 -2.3662 0.37540E-02 -2.4255 0.87237E+00 -0.0593 17 Ca(HSiO3)+ 0.22529E-08 -8.6472 0.19675E-08 -8.7061 0.87329E+00 -0.0588 18 Mg(HSiO3)+ 0.18162E-11 -11.7408 0.15861E-11 -11.7997 0.87329E+00 -0.0588 19 NaHSiO3,aq 0.50403E-03 -3.2975 0.50403E-03 -3.2975 0.10000E+01 0.0000 20 AlO+ 0.90983E-15 -15.0410 0.79454E-15 -15.0999 0.87329E+00 -0.0588 22 HAlO2,aq 0.12066E-08 -8.9184 0.12066E-08 -8.9184 0.10000E+01 0.0000 23 AlO2- 0.23370E-04 -4.6313 0.20367E-04 -4.6911 0.87150E+00 -0.0597 24 CH4,aq 0.12600E-17 -17.8996 0.12580E-17 -17.9003 0.99837E+00 -0.0007 29 CO,aq 0.10100E-18 -18.9957 0.10100E-18 -18.9957 0.10000E+01 0.0000 30 CO2,aq 0.16510E-08 -8.7823 0.16483E-08 -8.7830 0.99837E+00 -0.0007 31 CO3-2 0.63760E-05 -5.1955 0.39179E-05 -5.4069 0.61448E+00 -0.2115 32 CaCO3,aq 0.11306E-08 -8.9467 0.11306E-08 -8.9467 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.39569E-11 -11.4026 0.34555E-11 -11.4615 0.87329E+00 -0.0588 34 CaCl+ 0.51390E-11 -11.2891 0.44878E-11 -11.3480 0.87329E+00 -0.0588 35 CaCl2,aq 0.12848E-15 -15.8912 0.12848E-15 -15.8912 0.10000E+01 0.0000 36 CaOH+ 0.14322E-07 -7.8440 0.12507E-07 -7.9029 0.87329E+00 -0.0588 37 CaSO4,aq 0.11498E-09 -9.9394 0.11498E-09 -9.9394 0.10000E+01 0.0000 38 HCl,aq 0.28957E-14 -14.5382 0.28957E-14 -14.5382 0.10000E+01 0.0000 43 FeCl+ 0.15616E-16 -16.8064 0.13637E-16 -16.8653 0.87329E+00 -0.0588 46 FeO,aq 0.16158E-09 -9.7916 0.16158E-09 -9.7916 0.10000E+01 0.0000 47 FeOH+ 0.20322E-10 -10.6920 0.17747E-10 -10.7509 0.87329E+00 -0.0588 48 HFeO2- 0.14778E-07 -7.8304 0.12892E-07 -7.8897 0.87237E+00 -0.0593 49 FeO+ 0.98147E-15 -15.0081 0.85711E-15 -15.0670 0.87329E+00 -0.0588 51 FeO2- 0.11690E-07 -7.9322 0.10198E-07 -7.9915 0.87237E+00 -0.0593 52 HFeO2,aq 0.17009E-09 -9.7693 0.17009E-09 -9.7693 0.10000E+01 0.0000 53 H2,aq 0.24431E-08 -8.6121 0.24391E-08 -8.6128 0.99837E+00 -0.0007 54 KCl,aq 0.14314E-09 -9.8442 0.14314E-09 -9.8442 0.10000E+01 0.0000 55 KHSO4,aq 0.38238E-18 -18.4175 0.38238E-18 -18.4175 0.10000E+01 0.0000 56 KOH,aq 0.21344E-06 -6.6707 0.21344E-06 -6.6707 0.10000E+01 0.0000 57 KSO4- 0.18344E-07 -7.7365 0.16003E-07 -7.7958 0.87237E+00 -0.0593 58 MgCO3,aq 0.18357E-12 -12.7362 0.18357E-12 -12.7362 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.26191E-14 -14.5819 0.22872E-14 -14.6407 0.87329E+00 -0.0588 60 MgCl+ 0.30171E-14 -14.5204 0.26348E-14 -14.5793 0.87329E+00 -0.0588 61 MgOH+ 0.51335E-10 -10.2896 0.44830E-10 -10.3484 0.87329E+00 -0.0588 63 MnO,aq 0.71174E-09 -9.1477 0.71174E-09 -9.1477 0.10000E+01 0.0000 64 MnOH+ 0.31208E-09 -9.5057 0.27254E-09 -9.5646 0.87329E+00 -0.0588 65 MnO2-2 0.22352E-11 -11.6507 0.13735E-11 -11.8622 0.61448E+00 -0.2115 66 HMnO2- 0.45234E-10 -10.3445 0.39461E-10 -10.4038 0.87237E+00 -0.0593 69 MnCl+ 0.10043E-13 -13.9981 0.87705E-14 -14.0570 0.87329E+00 -0.0588 70 MnSO4,aq 0.53689E-13 -13.2701 0.53689E-13 -13.2701 0.10000E+01 0.0000 71 NaCl,aq 0.33151E-06 -6.4795 0.33151E-06 -6.4795 0.10000E+01 0.0000 72 NaOH,aq 0.27197E-04 -4.5655 0.27197E-04 -4.5655 0.10000E+01 0.0000 74 OH- 0.50554E-02 -2.2962 0.44058E-02 -2.3560 0.87150E+00 -0.0597 79 HPO3-2 0.39345E-17 -17.4051 0.24177E-17 -17.6166 0.61448E+00 -0.2115 82 H3PO4,aq 0.38257E-16 -16.4173 0.38257E-16 -16.4173 0.10000E+01 0.0000 83 H2PO4- 0.88158E-09 -9.0547 0.76946E-09 -9.1138 0.87282E+00 -0.0591 84 PO4-3 0.56607E-08 -8.2471 0.19789E-08 -8.7036 0.34958E+00 -0.4565 87 H2P2O7-2 0.75550E-19 -19.1218 0.46424E-19 -19.3333 0.61448E+00 -0.2115 88 HP2O7-3 0.20764E-15 -15.6827 0.70687E-16 -16.1507 0.34043E+00 -0.4680 89 P2O7-4 0.85005E-15 -15.0706 0.12877E-15 -15.8902 0.15148E+00 -0.8196 90 H2S,aq 0.14063E-14 -14.8519 0.14040E-14 -14.8526 0.99837E+00 -0.0007 97 SO3-2 0.80522E-14 -14.0941 0.49873E-14 -14.3021 0.61937E+00 -0.2081 98 HSO3- 0.46941E-16 -16.3284 0.40950E-16 -16.3877 0.87237E+00 -0.0593 99 HSO4- 0.22759E-11 -11.6428 0.19886E-11 -11.7015 0.87375E+00 -0.0586 Charge balance for all species = 0.2991E-12 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.1498289E-09 -.9990063E-02 -.1006185E+02 0.0000 2 H2O 0.1000000E+01 0.5550857E+02 0.9992551E+06 0.0000 3 Cl- 0.1381313E-03 0.1384630E-03 0.4905254E+01 5.9633 4 SO4-- 0.2557636E-04 0.2559570E-04 0.2456923E+01 14.9614 5 HCO3- 0.6737529E-05 0.1311630E-04 0.7997211E+00 4.6518 6 HS- 0.3970545E-11 -.8677676E-09 -.2867733E-04 -1.5782 7 Al+++ 0.2951682E-27 0.2337093E-04 0.6301109E+00 1.6487 8 H4SiO4 0.5272344E-03 0.5334508E-02 0.5123446E+03 -3.2780 9 Ca++ 0.3755809E-07 0.5538723E-07 0.2218148E-02 12.1265 10 Mg++ 0.2439036E-10 0.7773071E-10 0.1888375E-05 8.9379 11 Fe++ 0.1169099E-12 0.2682023E-07 0.1496708E-02 6.6188 12 K+ 0.7506126E-04 0.7529318E-04 0.2941910E+01 5.6988 13 Na+ 0.9516752E-02 0.1004831E-01 0.2308357E+03 7.8014 14 Mn++ 0.1931773E-10 0.1090673E-08 0.5987454E-04 8.8371 15 HPO4-- 0.5169744E-06 0.5235167E-06 0.5020900E-01 13.2670 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.4636088E+00 -.9954795E-02 -.4536540E+00 0.0000000E+00 2 H2O 0.5515727E+02 0.5531261E+02 -.1553390E+00 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.8014522E-03 0.2550533E-04 0.7759469E-03 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.7759477E-03 -.8647041E-09 -.7759469E-03 0.0000000E+00 7 Al+++ 0.9129750E-01 0.2328843E-04 0.9127422E-01 0.0000000E+00 8 H4SiO4 0.2915475E+00 0.5315675E-02 0.2862318E+00 0.0000000E+00 9 Ca++ 0.3221732E-01 0.5519170E-07 0.3221726E-01 0.0000000E+00 10 Mg++ 0.2222143E-01 0.7745630E-10 0.2222143E-01 0.0000000E+00 11 Fe++ 0.1996353E-01 0.2672555E-07 0.1996350E-01 0.0000000E+00 12 K+ 0.5944586E-02 0.7502738E-04 0.5869559E-02 0.0000000E+00 13 Na+ 0.3530564E-01 0.1001283E-01 0.2529280E-01 0.0000000E+00 14 Mn++ 0.4854633E-03 0.1086823E-08 0.4854623E-03 0.0000000E+00 15 HPO4-- 0.1656862E-03 0.5216685E-06 0.1651646E-03 0.0000000E+00 Chg. balance for solid moles: 0.7579E-16 Mass of aqueous solution: 0.997216E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 27.9990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 0.2524E-01 -1.598 6.618 0.821 21.65 2.541 andradite 0.2943E-02 -2.531 1.496 0.175 4.894 0.3886 grossular 0.1098E-03 -3.959 0.4945E-01 -1.306 0.1618 0.1376E-01 apatite-OH 0.5505E-04 -4.259 0.2766E-01 -1.558 0.9048E-01 0.8788E-02 clinochlore 0.4444E-02 -2.352 2.470 0.393 8.082 0.9396 daphnite 0.2236E-02 -2.650 1.596 0.203 5.220 0.4835 chlorite-Mn 0.9709E-04 -4.013 0.6884E-01 -1.162 0.2252 0.2194E-01 microcline 0.5612E-02 -2.251 1.562 0.194 5.110 0.6102 stilbite 0.2278E-01 -1.642 16.06 1.206 52.53 7.488 stilpnomelane-Fe 0.5148E-03 -3.288 0.5549 -0.256 1.815 0.1917 nontronite-Na 0.1603E-03 -3.795 0.6818E-01 -1.166 0.2231 0.2118E-01 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.9640E+00 0.9640E+00 1.0000 -0.016 grossular 0.3596E-01 0.3596E-01 1.0000 -1.444 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.6557E+00 0.6557E+00 1.0000 -0.183 daphnite 0.3300E+00 0.3300E+00 1.0000 -0.482 chlorite-Mn 0.1433E-01 0.1433E-01 1.0000 -1.844 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 nontronite-Na 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 30.566442 g Volume = 12.708382 cm3 Porosity: -4.1705% V(tot) - V(min): -.50878E+00 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 27.9990000 g log = 1.4471 Original solution: 1000.0103000 g Original solution / Rock added: 35.72 (Water/Rock Ratio), log = 1.5529 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0203 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.1000E+01 0.9860 0.1006E+01 0.1020E+01 CO2,gas 0.1716E-06 1.0071 0.1764E-06 0.1751E-06 CH4,gas 0.1792E-14 1.0125 0.1852E-14 0.1829E-14 H2,gas 0.3137E-05 1.0005 0.3202E-05 0.3201E-05 H2S,gas 0.3798E-13 0.9960 0.3859E-13 0.3875E-13 S2,gas 0.5344E-35 1.0000 0.5452E-35 0.5452E-35 CO,gas 0.1475E-15 1.0000 0.1505E-15 0.1505E-15 SO3,gas 0.1003E-39 1.0000 0.1023E-39 0.1023E-39 SO2,gas 0.1249E-22 1.0000 0.1275E-22 0.1275E-22 HCl,gas 0.5008E-17 1.0000 0.5110E-17 0.5110E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 16 albite -0.38 -0.38 0.00 0.000 -0.94784E-12 22 andradite 39.01 39.01 0.00 0.000 0.12132E-10 23 grossular 32.73 32.73 0.00 0.000 0.12132E-10 32 apatite-OH -18.15 -18.15 0.00 0.000 -0.60662E-11 46 clinochlore 39.07 39.07 0.00 0.000 0.12132E-10 47 daphnite 28.97 28.97 0.00 0.000 -0.12132E-10 48 chlorite-Mn 46.87 46.87 0.00 0.000 0.24265E-10 116 microcline -2.49 -2.49 0.00 0.000 0.15165E-11 163 stilbite -7.52 -7.52 0.00 0.000 0.15165E-10 164 stilpnomelane-Fe 13.02 13.02 0.00 0.000 0.21232E-10 209 nontronite-Na 3.52 3.52 0.00 0.000 0.15924E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -15.11 -8.45 -2.818 0.14433E+05 -6.754 3 CH4,gas 4.54 -11.89 -16.43 -4.108 0.28056E+05 -14.732 4 H2,gas 8.00 0.81 -7.19 -4.111 0.12283E+05 -5.495 5 H2S,gas -6.23 -21.34 -15.11 -7.556 0.25804E+05 -13.413 6 S2,gas -7.34 -44.30 -36.96 -5.687 0.63112E+05 -35.263 7 CO,gas 3.21 -14.31 -17.52 -5.391 0.29917E+05 -15.822 8 SO3,gas 17.12 -24.57 -41.69 -10.422 0.71183E+05 -39.990 9 SO2,gas 0.83 -23.76 -24.59 -6.558 0.41993E+05 -22.895 10 HCl,gas 5.19 -13.80 -18.99 -9.495 0.32426E+05 -17.292 11 acmite 7.71 7.46 -0.25 -0.026 0.42446E+03 15 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 19 spessartine 24.46 19.97 -4.48 -0.224 0.76538E+04 20 analcite 3.32 2.89 -0.43 -0.048 0.73034E+03 21 andalusite 5.00 0.02 -4.98 -0.498 0.85068E+04 26 annite 20.12 17.37 -2.75 -0.153 0.47014E+04 27 phlogopite 27.06 24.33 -2.74 -0.152 0.46738E+04 29 anorthite 12.71 8.87 -3.84 -0.296 0.65608E+04 35 aragonite 0.97 -2.99 -3.95 -1.318 0.67492E+04 36 brucite 12.57 8.94 -3.63 -0.726 0.61992E+04 37 calcite 0.81 -2.99 -3.80 -1.266 0.64850E+04 38 carnegieite-low 9.02 6.17 -2.85 -0.407 0.48683E+04 39 carnegieite-high 10.09 6.17 -3.92 -0.560 0.66953E+04 40 carpholite-Mg 8.58 5.68 -2.90 -0.194 0.49563E+04 41 carpholite-Fe 6.71 3.36 -3.35 -0.223 0.57241E+04 42 celadonite 5.34 3.17 -2.17 -0.128 0.37021E+04 43 celadonite-Fe 3.88 0.85 -3.02 -0.178 0.51603E+04 44 chrysotile 23.89 20.26 -3.63 -0.303 0.62060E+04 50 chloritoid-Mg 13.20 8.96 -4.24 -0.283 0.72403E+04 51 chloritoid-Fe 9.17 6.64 -2.54 -0.169 0.43291E+04 52 chloritoid-Mn 11.40 8.86 -2.54 -0.170 0.43447E+04 54 coesite -2.38 -3.28 -0.90 -0.301 0.15400E+04 61 cristobalite -2.56 -3.28 -0.72 -0.239 0.12254E+04 63 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71234E+04 65 diaspore 2.87 1.65 -1.22 -0.204 0.20916E+04 67 diopside 16.18 14.51 -1.67 -0.167 0.28564E+04 68 hedenbergite 14.21 12.19 -2.02 -0.202 0.34473E+04 75 epidote 24.67 23.93 -0.74 -0.036 0.12597E+04 76 clinozoisite 22.81 19.37 -3.44 -0.156 0.58752E+04 77 epidote-Fe 29.84 28.50 -1.34 -0.070 0.22908E+04 78 fayalite 14.05 9.96 -4.09 -0.584 0.69769E+04 79 ferrosilite 11.15 6.68 -4.47 -0.447 0.76286E+04 83 gibbsite 4.08 1.65 -2.43 -0.347 0.41502E+04 84 glaucophane 22.97 19.49 -3.48 -0.094 0.59501E+04 85 glaucophane-Fe 17.28 12.53 -4.74 -0.128 0.80987E+04 87 greenalite 16.14 13.30 -2.84 -0.237 0.48475E+04 90 hematite 12.57 12.43 -0.13 -0.016 0.23013E+03 91 heulandite -5.83 -7.52 -1.69 -0.077 0.28938E+04 95 jadeite 4.22 2.89 -1.32 -0.132 0.22558E+04 96 julgoldite 70.43 66.94 -3.49 -0.091 0.59563E+04 97 kalsilite 7.58 4.07 -3.51 -0.502 0.60008E+04 98 kaolinite -1.33 -3.26 -1.93 -0.175 0.32883E+04 99 kyanite 4.88 0.02 -4.86 -0.486 0.82927E+04 101 laumontite 2.88 2.31 -0.57 -0.038 0.97578E+03 102 lawsonite 9.62 8.87 -0.75 -0.050 0.12774E+04 103 leucite 4.12 0.79 -3.33 -0.333 0.56814E+04 105 lizardite 23.24 20.26 -2.99 -0.249 0.50986E+04 107 magnetite 20.09 19.05 -1.04 -0.085 0.17709E+04 108 minnesotaite 10.39 6.74 -3.64 -0.214 0.62214E+04 110 magnesioferrite 26.21 21.37 -4.84 -0.395 0.82694E+04 120 muscovite 2.58 0.81 -1.77 -0.104 0.30248E+04 121 paragonite 4.24 2.91 -1.33 -0.078 0.22639E+04 122 nepheline 8.34 6.17 -2.17 -0.310 0.37007E+04 134 phlogopite-Na 29.65 26.43 -3.22 -0.179 0.54927E+04 136 prehnite 19.37 17.72 -1.66 -0.097 0.28266E+04 137 prehnite-Fe 22.50 22.28 -0.21 -0.013 0.36612E+03 138 pumpellyite-Fe 46.27 43.70 -2.57 -0.057 0.43865E+04 139 pumpellyite-Mg 48.99 46.02 -2.98 -0.066 0.50803E+04 145 pyroxmangite 7.40 5.56 -1.84 -0.368 0.31410E+04 146 pyrophyllite -6.18 -9.81 -3.64 -0.227 0.62131E+04 147 quartz -2.99 -3.28 -0.29 -0.096 0.49271E+03 152 rhodonite 7.45 5.56 -1.89 -0.377 0.32212E+04 153 sanidine -1.28 -2.49 -1.21 -0.093 0.20677E+04 165 stilpnomelane-Mg 27.44 24.61 -2.83 -0.084 0.48303E+04 171 talc 16.49 13.70 -2.79 -0.164 0.47626E+04 174 tephroite 18.09 14.40 -3.69 -0.527 0.62998E+04 177 topaz-H 4.62 0.02 -4.60 -0.418 0.78528E+04 178 tridymite -2.63 -3.28 -0.65 -0.217 0.11127E+04 187 wairakite 3.95 2.31 -1.64 -0.096 0.27977E+04 188 walstromite 11.51 8.85 -2.66 -0.532 0.45431E+04 189 wollastonite 10.46 8.85 -1.61 -0.323 0.27535E+04 190 pseudo-wollastonite 11.00 8.85 -2.15 -0.430 0.36734E+04 191 zoisite 22.85 19.37 -3.48 -0.158 0.59493E+04 192 akaganeite 7.75 6.22 -1.54 -0.333 0.26276E+04 193 beidellite-Ca -1.65 -6.19 -4.54 -0.281 0.77558E+04 195 beidellite-K -1.52 -6.31 -4.79 -0.293 0.81753E+04 196 beidellite-Mg -1.79 -6.71 -4.92 -0.305 0.84080E+04 197 beidellite-Na -1.34 -5.61 -4.27 -0.262 0.72944E+04 199 chalcedony -2.80 -3.28 -0.48 -0.159 0.81201E+03 201 montmorillonite-Ca -2.29 -5.41 -3.12 -0.193 0.53231E+04 202 montmorillonite-K -2.24 -5.53 -3.29 -0.202 0.56207E+04 203 montmorillonite-Mg -2.48 -5.93 -3.45 -0.214 0.58984E+04 204 montmorillonite-Na -2.04 -4.83 -2.80 -0.171 0.47756E+04 205 nontronite-Ca 3.21 2.95 -0.27 -0.017 0.45834E+03 206 nontronite-H 2.53 0.95 -1.59 -0.106 0.27106E+04 207 nontronite-K 3.34 2.83 -0.51 -0.033 0.87912E+03 208 nontronite-Mg 3.07 2.42 -0.65 -0.042 0.11178E+04 224 tobermorite 9.82 6.82 -3.00 -0.818 0.51218E+04 233 boehmite 4.41 1.65 -2.76 -0.460 0.47086E+04 235 ferrous-oxide 9.81 6.62 -3.19 -0.798 0.54515E+04 240 silica-amorphous -2.09 -3.28 -1.19 -0.396 0.20262E+04 242 an20ab80 2.02 1.47 -0.55 -0.042 0.94131E+03 243 an25ab75 2.65 1.93 -0.72 -0.055 0.12236E+04 244 an30ab70 3.28 2.39 -0.89 -0.068 0.15155E+04 245 tr.625ac.25prg.125 45.16 41.12 -4.05 -0.109 0.69139E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 1.0000000 g Current total amount of reactant added: 27.9990000 g New total amount of reactant added: 28.9990000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.2992E-12 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 9 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 28.9990000 Water: Moles liquid = 0.5531E+02 kg liquid = 0.9964E+00 Moles total = 0.5514E+02 kg total = 0.9935E+00 Activity = 1.0000 Stoichiometric ionic strength = .5324634E-02 Osmotic coef. = 0.9613 True ionic strength = .9682697E-02 Chg. balance for total moles = 0.2992E-12 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.14984E-09 -9.8244 0.13111E-09 -9.8823 0.87500E+00 -0.0580 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13814E-03 -3.8597 0.12047E-03 -3.9191 0.87209E+00 -0.0594 4 SO4-- 0.25579E-04 -4.5921 0.15717E-04 -4.8036 0.61445E+00 -0.2115 5 HCO3- 0.67346E-05 -5.1717 0.58779E-05 -5.2308 0.87279E+00 -0.0591 6 HS- 0.44223E-11 -11.3543 0.38570E-11 -11.4138 0.87216E+00 -0.0594 7 Al+++ 0.28319E-27 -27.5479 0.96096E-28 -28.0173 0.33933E+00 -0.4694 8 H4SiO4 0.53390E-03 -3.2725 0.53390E-03 -3.2725 0.10000E+01 0.0000 9 Ca++ 0.37564E-07 -7.4252 0.22988E-07 -7.6385 0.61198E+00 -0.2133 10 Mg++ 0.24814E-10 -10.6053 0.15147E-10 -10.8197 0.61043E+00 -0.2144 11 Fe++ 0.11663E-12 -12.9332 0.71239E-13 -13.1473 0.61080E+00 -0.2141 12 K+ 0.75517E-04 -4.1220 0.65920E-04 -4.1810 0.87292E+00 -0.0590 13 Na+ 0.95746E-02 -2.0189 0.83492E-02 -2.0784 0.87202E+00 -0.0595 14 Mn++ 0.19653E-10 -10.7066 0.12010E-10 -10.9205 0.61108E+00 -0.2139 15 HPO4-- 0.51842E-06 -6.2853 0.31856E-06 -6.4968 0.61449E+00 -0.2115 16 HSiO3- 0.43599E-02 -2.3605 0.38022E-02 -2.4200 0.87209E+00 -0.0594 17 Ca(HSiO3)+ 0.22801E-08 -8.6420 0.19906E-08 -8.7010 0.87302E+00 -0.0590 18 Mg(HSiO3)+ 0.18697E-11 -11.7282 0.16323E-11 -11.7872 0.87302E+00 -0.0590 19 NaHSiO3,aq 0.51344E-03 -3.2895 0.51344E-03 -3.2895 0.10000E+01 0.0000 20 AlO+ 0.87108E-15 -15.0599 0.76047E-15 -15.1189 0.87302E+00 -0.0590 22 HAlO2,aq 0.11551E-08 -8.9374 0.11551E-08 -8.9374 0.10000E+01 0.0000 23 AlO2- 0.22383E-04 -4.6501 0.19501E-04 -4.7100 0.87122E+00 -0.0599 24 CH4,aq 0.14035E-17 -17.8528 0.14012E-17 -17.8535 0.99836E+00 -0.0007 29 CO,aq 0.10368E-18 -18.9843 0.10368E-18 -18.9843 0.10000E+01 0.0000 30 CO2,aq 0.16495E-08 -8.7827 0.16468E-08 -8.7834 0.99836E+00 -0.0007 31 CO3-2 0.63803E-05 -5.1952 0.39158E-05 -5.4072 0.61372E+00 -0.2120 32 CaCO3,aq 0.11287E-08 -8.9474 0.11287E-08 -8.9474 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.39508E-11 -11.4033 0.34492E-11 -11.4623 0.87302E+00 -0.0590 34 CaCl+ 0.51338E-11 -11.2896 0.44819E-11 -11.3485 0.87302E+00 -0.0590 35 CaCl2,aq 0.12828E-15 -15.8918 0.12828E-15 -15.8918 0.10000E+01 0.0000 36 CaOH+ 0.14313E-07 -7.8443 0.12496E-07 -7.9032 0.87302E+00 -0.0590 37 CaSO4,aq 0.11473E-09 -9.9403 0.11473E-09 -9.9403 0.10000E+01 0.0000 38 HCl,aq 0.28946E-14 -14.5384 0.28946E-14 -14.5384 0.10000E+01 0.0000 43 FeCl+ 0.15561E-16 -16.8080 0.13585E-16 -16.8670 0.87302E+00 -0.0590 46 FeO,aq 0.16106E-09 -9.7930 0.16106E-09 -9.7930 0.10000E+01 0.0000 47 FeOH+ 0.20259E-10 -10.6934 0.17686E-10 -10.7524 0.87302E+00 -0.0590 48 HFeO2- 0.14738E-07 -7.8316 0.12853E-07 -7.8910 0.87209E+00 -0.0594 49 FeO+ 0.96519E-15 -15.0154 0.84263E-15 -15.0744 0.87302E+00 -0.0590 51 FeO2- 0.11501E-07 -7.9393 0.10030E-07 -7.9987 0.87209E+00 -0.0594 52 HFeO2,aq 0.16725E-09 -9.7766 0.16725E-09 -9.7766 0.10000E+01 0.0000 53 H2,aq 0.25105E-08 -8.6002 0.25063E-08 -8.6010 0.99836E+00 -0.0007 54 KCl,aq 0.14394E-09 -9.8418 0.14394E-09 -9.8418 0.10000E+01 0.0000 55 KHSO4,aq 0.38408E-18 -18.4156 0.38408E-18 -18.4156 0.10000E+01 0.0000 56 KOH,aq 0.21471E-06 -6.6682 0.21471E-06 -6.6682 0.10000E+01 0.0000 57 KSO4- 0.18435E-07 -7.7344 0.16077E-07 -7.7938 0.87209E+00 -0.0594 58 MgCO3,aq 0.18642E-12 -12.7295 0.18642E-12 -12.7295 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.26600E-14 -14.5751 0.23223E-14 -14.6341 0.87302E+00 -0.0590 60 MgCl+ 0.30659E-14 -14.5134 0.26766E-14 -14.5724 0.87302E+00 -0.0590 61 MgOH+ 0.52186E-10 -10.2824 0.45560E-10 -10.3414 0.87302E+00 -0.0590 63 MnO,aq 0.72346E-09 -9.1406 0.72346E-09 -9.1406 0.10000E+01 0.0000 64 MnOH+ 0.31726E-09 -9.4986 0.27697E-09 -9.5576 0.87302E+00 -0.0590 65 MnO2-2 0.22757E-11 -11.6429 0.13966E-11 -11.8549 0.61372E+00 -0.2120 66 HMnO2- 0.46003E-10 -10.3372 0.40118E-10 -10.3967 0.87209E+00 -0.0594 69 MnCl+ 0.10205E-13 -13.9912 0.89096E-14 -14.0501 0.87302E+00 -0.0590 70 MnSO4,aq 0.54491E-13 -13.2637 0.54491E-13 -13.2637 0.10000E+01 0.0000 71 NaCl,aq 0.33335E-06 -6.4771 0.33335E-06 -6.4771 0.10000E+01 0.0000 72 NaOH,aq 0.27359E-04 -4.5629 0.27359E-04 -4.5629 0.10000E+01 0.0000 74 OH- 0.50580E-02 -2.2960 0.44066E-02 -2.3559 0.87122E+00 -0.0599 79 HPO3-2 0.40542E-17 -17.3921 0.24882E-17 -17.6041 0.61372E+00 -0.2120 82 H3PO4,aq 0.38302E-16 -16.4168 0.38302E-16 -16.4168 0.10000E+01 0.0000 83 H2PO4- 0.88306E-09 -9.0540 0.77051E-09 -9.1132 0.87255E+00 -0.0592 84 PO4-3 0.56857E-08 -8.2452 0.19823E-08 -8.7028 0.34865E+00 -0.4576 87 H2P2O7-2 0.75851E-19 -19.1200 0.46552E-19 -19.3321 0.61372E+00 -0.2120 88 HP2O7-3 0.20883E-15 -15.6802 0.70894E-16 -16.1494 0.33948E+00 -0.4692 89 P2O7-4 0.85689E-15 -15.0671 0.12917E-15 -15.8888 0.15075E+00 -0.8218 90 H2S,aq 0.15655E-14 -14.8053 0.15630E-14 -14.8061 0.99836E+00 -0.0007 97 SO3-2 0.82747E-14 -14.0822 0.51190E-14 -14.2908 0.61863E+00 -0.2086 98 HSO3- 0.48187E-16 -16.3171 0.42024E-16 -16.3765 0.87209E+00 -0.0594 99 HSO4- 0.22736E-11 -11.6433 0.19860E-11 -11.7020 0.87348E+00 -0.0587 Charge balance for all species = 0.2989E-12 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.1498448E-09 -.1005491E-01 -.1012709E+02 0.0000 2 H2O 0.1000000E+01 0.5550851E+02 0.9992466E+06 0.0000 3 Cl- 0.1381445E-03 0.1384780E-03 0.4905749E+01 5.9632 4 SO4-- 0.2557904E-04 0.2559842E-04 0.2457167E+01 14.9611 5 HCO3- 0.6734614E-05 0.1311772E-04 0.7998017E+00 4.6516 6 HS- 0.4422331E-11 -.8264395E-09 -.2731135E-04 -1.5314 7 Al+++ 0.2831921E-27 0.2238436E-04 0.6035071E+00 1.6298 8 H4SiO4 0.5339035E-03 0.5407225E-02 0.5193248E+03 -3.2725 9 Ca++ 0.3756401E-07 0.5540975E-07 0.2219034E-02 12.1262 10 Mg++ 0.2481377E-10 0.7906207E-10 0.1920704E-05 8.9450 11 Fe++ 0.1166327E-12 0.2658688E-07 0.1483675E-02 6.6174 12 K+ 0.7551677E-04 0.7575006E-04 0.2959740E+01 5.7014 13 Na+ 0.9574556E-02 0.1011569E-01 0.2323818E+03 7.8040 14 Mn++ 0.1965297E-10 0.1108715E-08 0.6086457E-04 8.8442 15 HPO4-- 0.5184163E-06 0.5249851E-06 0.5034946E-01 13.2679 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.4801673E+00 -.1001833E-01 -.4701490E+00 0.0000000E+00 2 H2O 0.5514474E+02 0.5530657E+02 -.1618340E+00 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.8291656E-03 0.2550529E-04 0.8036603E-03 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.8036611E-03 -.8234330E-09 -.8036603E-03 0.0000000E+00 7 Al+++ 0.9455825E-01 0.2230292E-04 0.9453594E-01 0.0000000E+00 8 H4SiO4 0.3019603E+00 0.5387554E-02 0.2965727E+00 0.0000000E+00 9 Ca++ 0.3336746E-01 0.5520818E-07 0.3336740E-01 0.0000000E+00 10 Mg++ 0.2301508E-01 0.7877444E-10 0.2301508E-01 0.0000000E+00 11 Fe++ 0.2067654E-01 0.2649016E-07 0.2067651E-01 0.0000000E+00 12 K+ 0.6156900E-02 0.7547448E-04 0.6081426E-02 0.0000000E+00 13 Na+ 0.3656088E-01 0.1007889E-01 0.2648199E-01 0.0000000E+00 14 Mn++ 0.5028019E-03 0.1104682E-08 0.5028008E-03 0.0000000E+00 15 HPO4-- 0.1716038E-03 0.5230752E-06 0.1710807E-03 0.0000000E+00 Chg. balance for solid moles: -.2385E-16 Mass of aqueous solution: 0.997116E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 28.9990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 0.2644E-01 -1.578 6.934 0.841 21.90 2.662 andradite 0.3093E-02 -2.510 1.572 0.196 4.965 0.4084 grossular 0.1123E-03 -3.950 0.5059E-01 -1.296 0.1598 0.1408E-01 apatite-OH 0.5703E-04 -4.244 0.2865E-01 -1.543 0.9048E-01 0.9103E-02 clinochlore 0.4603E-02 -2.337 2.558 0.408 8.081 0.9732 daphnite 0.2271E-02 -2.644 1.621 0.210 5.119 0.4911 chlorite-Mn 0.1006E-03 -3.998 0.7129E-01 -1.147 0.2252 0.2272E-01 microcline 0.5792E-02 -2.237 1.612 0.207 5.093 0.6298 stilbite 0.2347E-01 -1.630 16.54 1.218 52.23 7.713 stilpnomelane-Fe 0.5781E-03 -3.238 0.6232 -0.205 1.968 0.2153 nontronite-Na 0.1213E-03 -3.916 0.5161E-01 -1.287 0.1630 0.1603E-01 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.9650E+00 0.9650E+00 1.0000 -0.015 grossular 0.3504E-01 0.3504E-01 1.0000 -1.455 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.6599E+00 0.6599E+00 1.0000 -0.180 daphnite 0.3256E+00 0.3256E+00 1.0000 -0.487 chlorite-Mn 0.1442E-01 0.1442E-01 1.0000 -1.841 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 nontronite-Na 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 31.658813 g Volume = 13.154266 cm3 Porosity: -4.4022% V(tot) - V(min): -.55467E+00 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 28.9990000 g log = 1.4624 Original solution: 1000.0103000 g Original solution / Rock added: 34.48 (Water/Rock Ratio), log = 1.5376 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0203 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.1000E+01 0.9860 0.1006E+01 0.1020E+01 CO2,gas 0.1715E-06 1.0071 0.1762E-06 0.1749E-06 CH4,gas 0.1996E-14 1.0125 0.2062E-14 0.2037E-14 H2,gas 0.3223E-05 1.0005 0.3291E-05 0.3289E-05 H2S,gas 0.4228E-13 0.9960 0.4296E-13 0.4314E-13 S2,gas 0.6272E-35 1.0000 0.6399E-35 0.6399E-35 CO,gas 0.1514E-15 1.0000 0.1545E-15 0.1545E-15 SO3,gas 0.1001E-39 1.0000 0.1022E-39 0.1022E-39 SO2,gas 0.1282E-22 1.0000 0.1308E-22 0.1308E-22 HCl,gas 0.5006E-17 1.0000 0.5108E-17 0.5108E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 16 albite -0.38 -0.38 0.00 0.000 -0.94784E-12 22 andradite 39.01 39.01 0.00 0.000 0.48529E-10 23 grossular 32.73 32.73 0.00 0.000 0.00000E+00 32 apatite-OH -18.15 -18.15 0.00 0.000 0.00000E+00 46 clinochlore 39.07 39.07 0.00 0.000 -0.12132E-10 47 daphnite 28.97 28.97 0.00 0.000 -0.54595E-10 48 chlorite-Mn 46.87 46.87 0.00 0.000 -0.12132E-10 116 microcline -2.49 -2.49 0.00 0.000 0.15165E-11 163 stilbite -7.52 -7.52 0.00 0.000 -0.90992E-11 164 stilpnomelane-Fe 13.02 13.02 0.00 0.000 -0.27298E-10 209 nontronite-Na 3.52 3.52 0.00 0.000 0.98575E-11 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -15.11 -8.45 -2.818 0.14433E+05 -6.754 3 CH4,gas 4.54 -11.84 -16.38 -4.096 0.27976E+05 -14.686 4 H2,gas 8.00 0.82 -7.18 -4.104 0.12263E+05 -5.483 5 H2S,gas -6.23 -21.30 -15.07 -7.533 0.25725E+05 -13.367 6 S2,gas -7.34 -44.23 -36.89 -5.676 0.62994E+05 -35.194 7 CO,gas 3.21 -14.30 -17.51 -5.388 0.29898E+05 -15.811 8 SO3,gas 17.12 -24.57 -41.69 -10.422 0.71184E+05 -39.991 9 SO2,gas 0.83 -23.75 -24.58 -6.555 0.41974E+05 -22.883 10 HCl,gas 5.19 -13.80 -18.99 -9.495 0.32426E+05 -17.292 11 acmite 7.71 7.47 -0.24 -0.025 0.41391E+03 15 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 19 spessartine 24.46 19.97 -4.48 -0.224 0.76542E+04 20 analcite 3.32 2.89 -0.43 -0.048 0.73966E+03 26 annite 20.12 17.37 -2.76 -0.153 0.47086E+04 27 phlogopite 27.06 24.35 -2.72 -0.151 0.46375E+04 29 anorthite 12.71 8.84 -3.87 -0.298 0.66074E+04 35 aragonite 0.97 -2.99 -3.95 -1.318 0.67504E+04 36 brucite 12.57 8.95 -3.62 -0.725 0.61871E+04 37 calcite 0.81 -2.99 -3.80 -1.266 0.64862E+04 38 carnegieite-low 9.02 6.16 -2.86 -0.409 0.48869E+04 39 carnegieite-high 10.09 6.16 -3.93 -0.562 0.67139E+04 40 carpholite-Mg 8.58 5.66 -2.92 -0.195 0.49903E+04 41 carpholite-Fe 6.71 3.33 -3.38 -0.225 0.57726E+04 42 celadonite 5.34 3.19 -2.16 -0.127 0.36806E+04 43 celadonite-Fe 3.88 0.86 -3.02 -0.178 0.51534E+04 44 chrysotile 23.89 20.29 -3.60 -0.300 0.61510E+04 50 chloritoid-Mg 13.20 8.93 -4.27 -0.284 0.72836E+04 51 chloritoid-Fe 9.17 6.60 -2.57 -0.171 0.43869E+04 52 chloritoid-Mn 11.40 8.83 -2.57 -0.171 0.43880E+04 54 coesite -2.38 -3.27 -0.90 -0.299 0.15307E+04 61 cristobalite -2.56 -3.27 -0.71 -0.237 0.12161E+04 63 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71234E+04 65 diaspore 2.87 1.63 -1.24 -0.207 0.21240E+04 67 diopside 16.18 14.53 -1.66 -0.166 0.28262E+04 68 hedenbergite 14.21 12.20 -2.01 -0.201 0.34316E+04 75 epidote 24.67 23.90 -0.77 -0.037 0.13100E+04 76 clinozoisite 22.81 19.32 -3.48 -0.158 0.59454E+04 77 epidote-Fe 29.84 28.48 -1.36 -0.071 0.23213E+04 78 fayalite 14.05 9.96 -4.08 -0.583 0.69724E+04 79 ferrosilite 11.15 6.69 -4.46 -0.446 0.76148E+04 83 gibbsite 4.08 1.63 -2.45 -0.350 0.41825E+04 84 glaucophane 22.97 19.52 -3.45 -0.093 0.58951E+04 85 glaucophane-Fe 17.28 12.54 -4.74 -0.128 0.80872E+04 87 greenalite 16.14 13.31 -2.83 -0.236 0.48361E+04 90 hematite 12.57 12.42 -0.15 -0.018 0.25511E+03 91 heulandite -5.83 -7.52 -1.69 -0.077 0.28938E+04 95 jadeite 4.22 2.89 -1.33 -0.133 0.22651E+04 96 julgoldite 70.43 66.94 -3.49 -0.091 0.59573E+04 97 kalsilite 7.58 4.06 -3.53 -0.504 0.60194E+04 98 kaolinite -1.33 -3.29 -1.95 -0.178 0.33344E+04 99 kyanite 4.88 -0.01 -4.89 -0.489 0.83481E+04 101 laumontite 2.88 2.30 -0.59 -0.039 0.10037E+04 102 lawsonite 9.62 8.84 -0.78 -0.052 0.13240E+04 103 leucite 4.12 0.79 -3.33 -0.333 0.56907E+04 105 lizardite 23.24 20.29 -2.95 -0.246 0.50436E+04 107 magnetite 20.09 19.03 -1.05 -0.086 0.17983E+04 108 minnesotaite 10.39 6.76 -3.63 -0.213 0.61913E+04 110 magnesioferrite 26.21 21.36 -4.85 -0.396 0.82823E+04 120 muscovite 2.58 0.77 -1.81 -0.106 0.30895E+04 121 paragonite 4.24 2.88 -1.36 -0.080 0.23286E+04 122 nepheline 8.34 6.16 -2.18 -0.311 0.37193E+04 134 phlogopite-Na 29.65 26.45 -3.20 -0.178 0.54563E+04 136 prehnite 19.37 17.69 -1.68 -0.099 0.28644E+04 137 prehnite-Fe 22.50 22.27 -0.22 -0.014 0.38406E+03 138 pumpellyite-Fe 46.27 43.64 -2.63 -0.059 0.44969E+04 139 pumpellyite-Mg 48.99 45.96 -3.03 -0.067 0.51762E+04 145 pyroxmangite 7.40 5.57 -1.83 -0.365 0.31195E+04 146 pyrophyllite -6.18 -9.83 -3.65 -0.228 0.62405E+04 147 quartz -2.99 -3.27 -0.28 -0.094 0.48339E+03 152 rhodonite 7.45 5.57 -1.87 -0.375 0.31998E+04 153 sanidine -1.28 -2.49 -1.21 -0.093 0.20677E+04 165 stilpnomelane-Mg 27.44 24.66 -2.79 -0.083 0.47577E+04 171 talc 16.49 13.74 -2.75 -0.162 0.46890E+04 174 tephroite 18.09 14.42 -3.67 -0.524 0.62662E+04 177 topaz-H 4.62 -0.01 -4.63 -0.421 0.79082E+04 178 tridymite -2.63 -3.27 -0.65 -0.215 0.11034E+04 187 wairakite 3.95 2.30 -1.65 -0.097 0.28257E+04 188 walstromite 11.51 8.85 -2.66 -0.531 0.45343E+04 189 wollastonite 10.46 8.85 -1.61 -0.321 0.27447E+04 190 pseudo-wollastonite 11.00 8.85 -2.15 -0.429 0.36646E+04 191 zoisite 22.85 19.32 -3.53 -0.160 0.60194E+04 192 akaganeite 7.75 6.21 -1.55 -0.334 0.26401E+04 193 beidellite-Ca -1.65 -6.21 -4.57 -0.282 0.77971E+04 195 beidellite-K -1.52 -6.33 -4.81 -0.295 0.82150E+04 196 beidellite-Mg -1.79 -6.74 -4.95 -0.306 0.84472E+04 197 beidellite-Na -1.34 -5.64 -4.30 -0.263 0.73342E+04 199 chalcedony -2.80 -3.27 -0.47 -0.157 0.80269E+03 201 montmorillonite-Ca -2.29 -5.42 -3.13 -0.193 0.53360E+04 202 montmorillonite-K -2.24 -5.54 -3.30 -0.202 0.56320E+04 203 montmorillonite-Mg -2.48 -5.94 -3.46 -0.214 0.59092E+04 204 montmorillonite-Na -2.04 -4.84 -2.80 -0.172 0.47869E+04 205 nontronite-Ca 3.21 2.95 -0.27 -0.017 0.45988E+03 206 nontronite-H 2.53 0.94 -1.59 -0.106 0.27120E+04 207 nontronite-K 3.34 2.83 -0.51 -0.033 0.87912E+03 208 nontronite-Mg 3.07 2.42 -0.65 -0.042 0.11172E+04 224 tobermorite 9.82 6.83 -2.99 -0.817 0.51130E+04 233 boehmite 4.41 1.63 -2.78 -0.463 0.47409E+04 235 ferrous-oxide 9.81 6.62 -3.19 -0.799 0.54540E+04 240 silica-amorphous -2.09 -3.27 -1.18 -0.394 0.20169E+04 242 an20ab80 2.02 1.46 -0.56 -0.043 0.95063E+03 243 an25ab75 2.65 1.92 -0.72 -0.056 0.12353E+04 244 an30ab70 3.28 2.38 -0.90 -0.069 0.15295E+04 245 tr.625ac.25prg.125 45.16 41.17 -3.99 -0.107 0.68134E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 1.0000000 g Current total amount of reactant added: 28.9990000 g New total amount of reactant added: 29.9990000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.2993E-12 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 9 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 29.9990000 Water: Moles liquid = 0.5530E+02 kg liquid = 0.9963E+00 Moles total = 0.5513E+02 kg total = 0.9932E+00 Activity = 1.0000 Stoichiometric ionic strength = .5353668E-02 Osmotic coef. = 0.9612 True ionic strength = .9739539E-02 Chg. balance for total moles = 0.2993E-12 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.14986E-09 -9.8243 0.13109E-09 -9.8824 0.87475E+00 -0.0581 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13816E-03 -3.8596 0.12045E-03 -3.9192 0.87183E+00 -0.0596 4 SO4-- 0.25582E-04 -4.5921 0.15700E-04 -4.8041 0.61371E+00 -0.2120 5 HCO3- 0.67319E-05 -5.1719 0.58738E-05 -5.2311 0.87253E+00 -0.0592 6 HS- 0.49078E-11 -11.3091 0.42791E-11 -11.3686 0.87190E+00 -0.0595 7 Al+++ 0.27211E-27 -27.5653 0.92084E-28 -28.0358 0.33841E+00 -0.4706 8 H4SiO4 0.54043E-03 -3.2673 0.54043E-03 -3.2673 0.10000E+01 0.0000 9 Ca++ 0.37571E-07 -7.4251 0.22965E-07 -7.6389 0.61123E+00 -0.2138 10 Mg++ 0.25228E-10 -10.5981 0.15381E-10 -10.8130 0.60968E+00 -0.2149 11 Fe++ 0.11637E-12 -12.9342 0.70993E-13 -13.1488 0.61005E+00 -0.2146 12 K+ 0.75961E-04 -4.1194 0.66288E-04 -4.1786 0.87265E+00 -0.0592 13 Na+ 0.96309E-02 -2.0163 0.83958E-02 -2.0759 0.87175E+00 -0.0596 14 Mn++ 0.19981E-10 -10.6994 0.12195E-10 -10.9138 0.61033E+00 -0.2144 15 HPO4-- 0.51980E-06 -6.2842 0.31904E-06 -6.4962 0.61376E+00 -0.2120 16 HSiO3- 0.44152E-02 -2.3550 0.38493E-02 -2.4146 0.87183E+00 -0.0596 17 Ca(HSiO3)+ 0.23067E-08 -8.6370 0.20132E-08 -8.6961 0.87276E+00 -0.0591 18 Mg(HSiO3)+ 0.19227E-11 -11.7161 0.16781E-11 -11.7752 0.87276E+00 -0.0591 19 NaHSiO3,aq 0.52270E-03 -3.2817 0.52270E-03 -3.2817 0.10000E+01 0.0000 20 AlO+ 0.83522E-15 -15.0782 0.72895E-15 -15.1373 0.87276E+00 -0.0591 22 HAlO2,aq 0.11074E-08 -8.9557 0.11074E-08 -8.9557 0.10000E+01 0.0000 23 AlO2- 0.21469E-04 -4.6682 0.18698E-04 -4.7282 0.87095E+00 -0.0600 24 CH4,aq 0.15577E-17 -17.8075 0.15551E-17 -17.8082 0.99835E+00 -0.0007 29 CO,aq 0.10635E-18 -18.9733 0.10635E-18 -18.9733 0.10000E+01 0.0000 30 CO2,aq 0.16481E-08 -8.7830 0.16453E-08 -8.7837 0.99835E+00 -0.0007 31 CO3-2 0.63845E-05 -5.1949 0.39136E-05 -5.4074 0.61299E+00 -0.2125 32 CaCO3,aq 0.11269E-08 -8.9481 0.11269E-08 -8.9481 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.39452E-11 -11.4039 0.34432E-11 -11.4630 0.87276E+00 -0.0591 34 CaCl+ 0.51291E-11 -11.2900 0.44764E-11 -11.3491 0.87276E+00 -0.0591 35 CaCl2,aq 0.12810E-15 -15.8925 0.12810E-15 -15.8925 0.10000E+01 0.0000 36 CaOH+ 0.14305E-07 -7.8445 0.12485E-07 -7.9036 0.87276E+00 -0.0591 37 CaSO4,aq 0.11449E-09 -9.9412 0.11449E-09 -9.9412 0.10000E+01 0.0000 38 HCl,aq 0.28935E-14 -14.5386 0.28935E-14 -14.5386 0.10000E+01 0.0000 43 FeCl+ 0.15508E-16 -16.8094 0.13535E-16 -16.8685 0.87276E+00 -0.0591 46 FeO,aq 0.16055E-09 -9.7944 0.16055E-09 -9.7944 0.10000E+01 0.0000 47 FeOH+ 0.20198E-10 -10.6947 0.17628E-10 -10.7538 0.87276E+00 -0.0591 48 HFeO2- 0.14698E-07 -7.8327 0.12814E-07 -7.8923 0.87183E+00 -0.0596 49 FeO+ 0.94974E-15 -15.0224 0.82889E-15 -15.0815 0.87276E+00 -0.0591 51 FeO2- 0.11320E-07 -7.9461 0.98692E-08 -8.0057 0.87183E+00 -0.0596 52 HFeO2,aq 0.16455E-09 -9.7837 0.16455E-09 -9.7837 0.10000E+01 0.0000 53 H2,aq 0.25773E-08 -8.5888 0.25731E-08 -8.5895 0.99835E+00 -0.0007 54 KCl,aq 0.14471E-09 -9.8395 0.14471E-09 -9.8395 0.10000E+01 0.0000 55 KHSO4,aq 0.38574E-18 -18.4137 0.38574E-18 -18.4137 0.10000E+01 0.0000 56 KOH,aq 0.21594E-06 -6.6657 0.21594E-06 -6.6657 0.10000E+01 0.0000 57 KSO4- 0.18523E-07 -7.7323 0.16149E-07 -7.7918 0.87183E+00 -0.0596 58 MgCO3,aq 0.18920E-12 -12.7231 0.18920E-12 -12.7231 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.27001E-14 -14.5686 0.23565E-14 -14.6277 0.87276E+00 -0.0591 60 MgCl+ 0.31136E-14 -14.5067 0.27174E-14 -14.5658 0.87276E+00 -0.0591 61 MgOH+ 0.53018E-10 -10.2756 0.46272E-10 -10.3347 0.87276E+00 -0.0591 63 MnO,aq 0.73488E-09 -9.1338 0.73488E-09 -9.1338 0.10000E+01 0.0000 64 MnOH+ 0.32231E-09 -9.4917 0.28130E-09 -9.5508 0.87276E+00 -0.0591 65 MnO2-2 0.23151E-11 -11.6354 0.14191E-11 -11.8480 0.61299E+00 -0.2125 66 HMnO2- 0.46751E-10 -10.3302 0.40758E-10 -10.3898 0.87183E+00 -0.0596 69 MnCl+ 0.10364E-13 -13.9845 0.90454E-14 -14.0436 0.87276E+00 -0.0591 70 MnSO4,aq 0.55274E-13 -13.2575 0.55274E-13 -13.2575 0.10000E+01 0.0000 71 NaCl,aq 0.33514E-06 -6.4748 0.33514E-06 -6.4748 0.10000E+01 0.0000 72 NaOH,aq 0.27516E-04 -4.5604 0.27516E-04 -4.5604 0.10000E+01 0.0000 74 OH- 0.50604E-02 -2.2958 0.44073E-02 -2.3558 0.87095E+00 -0.0600 79 HPO3-2 0.41733E-17 -17.3795 0.25582E-17 -17.5921 0.61299E+00 -0.2125 82 H3PO4,aq 0.38347E-16 -16.4163 0.38347E-16 -16.4163 0.10000E+01 0.0000 83 H2PO4- 0.88450E-09 -9.0533 0.77153E-09 -9.1126 0.87228E+00 -0.0593 84 PO4-3 0.57098E-08 -8.2434 0.19856E-08 -8.7021 0.34775E+00 -0.4587 87 H2P2O7-2 0.76143E-19 -19.1184 0.46675E-19 -19.3309 0.61299E+00 -0.2125 88 HP2O7-3 0.20999E-15 -15.6778 0.71093E-16 -16.1482 0.33856E+00 -0.4704 89 P2O7-4 0.86352E-15 -15.0637 0.12956E-15 -15.8875 0.15003E+00 -0.8238 90 H2S,aq 0.17366E-14 -14.7603 0.17337E-14 -14.7610 0.99835E+00 -0.0007 97 SO3-2 0.84956E-14 -14.0708 0.52496E-14 -14.2799 0.61791E+00 -0.2091 98 HSO3- 0.49424E-16 -16.3061 0.43089E-16 -16.3656 0.87183E+00 -0.0596 99 HSO4- 0.22715E-11 -11.6437 0.19835E-11 -11.7026 0.87322E+00 -0.0589 Charge balance for all species = 0.2990E-12 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.1498643E-09 -.1011840E-01 -.1019096E+02 0.0000 2 H2O 0.1000000E+01 0.5550844E+02 0.9992384E+06 0.0000 3 Cl- 0.1381576E-03 0.1384929E-03 0.4906243E+01 5.9632 4 SO4-- 0.2558171E-04 0.2560114E-04 0.2457411E+01 14.9607 5 HCO3- 0.6731887E-05 0.1311914E-04 0.7998824E+00 4.6513 6 HS- 0.4907817E-11 -.7863443E-09 -.2598614E-04 -1.4862 7 Al+++ 0.2721057E-27 0.2147005E-04 0.5788523E+00 1.6114 8 H4SiO4 0.5404296E-03 0.5478356E-02 0.5261526E+03 -3.2673 9 Ca++ 0.3757131E-07 0.5543365E-07 0.2219975E-02 12.1259 10 Mg++ 0.2522838E-10 0.8036401E-10 0.1952319E-05 8.9518 11 Fe++ 0.1163718E-12 0.2636376E-07 0.1471214E-02 6.6161 12 K+ 0.7596113E-04 0.7619574E-04 0.2977133E+01 5.7039 13 Na+ 0.9630945E-02 0.1018149E-01 0.2338920E+03 7.8065 14 Mn++ 0.1998125E-10 0.1126309E-08 0.6182998E-04 8.8510 15 HPO4-- 0.5198042E-06 0.5263985E-06 0.5048465E-01 13.2687 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.4967259E+00 -.1008050E-01 -.4866454E+00 0.0000000E+00 2 H2O 0.5513220E+02 0.5530054E+02 -.1683353E+00 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.8568790E-03 0.2550525E-04 0.8313738E-03 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.8313746E-03 -.7833991E-09 -.8313738E-03 0.0000000E+00 7 Al+++ 0.9781899E-01 0.2138964E-04 0.9779760E-01 0.0000000E+00 8 H4SiO4 0.3123731E+00 0.5457836E-02 0.3069152E+00 0.0000000E+00 9 Ca++ 0.3451760E-01 0.5522602E-07 0.3451755E-01 0.0000000E+00 10 Mg++ 0.2380873E-01 0.8006300E-10 0.2380873E-01 0.0000000E+00 11 Fe++ 0.2138954E-01 0.2626501E-07 0.2138952E-01 0.0000000E+00 12 K+ 0.6369214E-02 0.7591035E-04 0.6293304E-02 0.0000000E+00 13 Na+ 0.3781612E-01 0.1014336E-01 0.2767277E-01 0.0000000E+00 14 Mn++ 0.5201405E-03 0.1122091E-08 0.5201394E-03 0.0000000E+00 15 HPO4-- 0.1775214E-03 0.5244268E-06 0.1769970E-03 0.0000000E+00 Chg. balance for solid moles: 0.1117E-15 Mass of aqueous solution: 0.997015E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 29.9990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 0.2765E-01 -1.558 7.249 0.860 22.13 2.783 andradite 0.3243E-02 -2.489 1.648 0.217 5.033 0.4282 grossular 0.1148E-03 -3.940 0.5169E-01 -1.287 0.1578 0.1438E-01 apatite-OH 0.5900E-04 -4.229 0.2964E-01 -1.528 0.9049E-01 0.9417E-02 clinochlore 0.4762E-02 -2.322 2.647 0.423 8.081 1.007 daphnite 0.2306E-02 -2.637 1.645 0.216 5.024 0.4986 chlorite-Mn 0.1040E-03 -3.983 0.7375E-01 -1.132 0.2252 0.2350E-01 microcline 0.5972E-02 -2.224 1.662 0.221 5.076 0.6494 stilbite 0.2415E-01 -1.617 17.02 1.231 51.96 7.937 stilpnomelane-Fe 0.6418E-03 -3.193 0.6918 -0.160 2.112 0.2390 nontronite-Na 0.8206E-04 -4.086 0.3490E-01 -1.457 0.1066 0.1084E-01 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.9658E+00 0.9658E+00 1.0000 -0.015 grossular 0.3417E-01 0.3417E-01 1.0000 -1.466 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.6640E+00 0.6640E+00 1.0000 -0.178 daphnite 0.3215E+00 0.3215E+00 1.0000 -0.493 chlorite-Mn 0.1451E-01 0.1451E-01 1.0000 -1.838 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 nontronite-Na 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 32.751257 g Volume = 13.600142 cm3 Porosity: -4.6197% V(tot) - V(min): -.60054E+00 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 29.9990000 g log = 1.4771 Original solution: 1000.0103000 g Original solution / Rock added: 33.33 (Water/Rock Ratio), log = 1.5229 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0203 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.1000E+01 0.9860 0.1006E+01 0.1020E+01 CO2,gas 0.1713E-06 1.0071 0.1760E-06 0.1748E-06 CH4,gas 0.2216E-14 1.0125 0.2289E-14 0.2261E-14 H2,gas 0.3309E-05 1.0005 0.3378E-05 0.3376E-05 H2S,gas 0.4690E-13 0.9960 0.4766E-13 0.4785E-13 S2,gas 0.7323E-35 1.0000 0.7471E-35 0.7471E-35 CO,gas 0.1553E-15 1.0000 0.1585E-15 0.1585E-15 SO3,gas 0.9999E-40 1.0000 0.1020E-39 0.1020E-39 SO2,gas 0.1314E-22 1.0000 0.1341E-22 0.1341E-22 HCl,gas 0.5004E-17 1.0000 0.5106E-17 0.5106E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 16 albite -0.38 -0.38 0.00 0.000 -0.94784E-12 22 andradite 39.01 39.01 0.00 0.000 0.12132E-10 23 grossular 32.73 32.73 0.00 0.000 0.00000E+00 32 apatite-OH -18.15 -18.15 0.00 0.000 -0.60662E-11 46 clinochlore 39.07 39.07 0.00 0.000 -0.12132E-10 47 daphnite 28.97 28.97 0.00 0.000 -0.60662E-11 48 chlorite-Mn 46.87 46.87 0.00 0.000 0.00000E+00 116 microcline -2.49 -2.49 0.00 0.000 0.15165E-11 163 stilbite -7.52 -7.52 0.00 0.000 0.15165E-10 164 stilpnomelane-Fe 13.02 13.02 0.00 0.000 0.21232E-10 209 nontronite-Na 3.52 3.52 0.00 0.000 -0.53079E-11 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -15.11 -8.45 -2.818 0.14434E+05 -6.754 3 CH4,gas 4.54 -11.80 -16.34 -4.085 0.27899E+05 -14.640 4 H2,gas 8.00 0.83 -7.17 -4.097 0.12243E+05 -5.471 5 H2S,gas -6.23 -21.25 -15.02 -7.510 0.25648E+05 -13.322 6 S2,gas -7.34 -44.16 -36.83 -5.665 0.62879E+05 -35.127 7 CO,gas 3.21 -14.28 -17.50 -5.384 0.29879E+05 -15.800 8 SO3,gas 17.12 -24.57 -41.69 -10.423 0.71185E+05 -39.991 9 SO2,gas 0.83 -23.74 -24.57 -6.552 0.41955E+05 -22.873 10 HCl,gas 5.19 -13.80 -18.99 -9.495 0.32426E+05 -17.292 11 acmite 7.71 7.47 -0.24 -0.025 0.40371E+03 15 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 19 spessartine 24.46 19.97 -4.48 -0.224 0.76549E+04 20 analcite 3.32 2.88 -0.44 -0.049 0.74867E+03 26 annite 20.12 17.36 -2.76 -0.153 0.47156E+04 27 phlogopite 27.06 24.37 -2.70 -0.150 0.46027E+04 29 anorthite 12.71 8.81 -3.90 -0.300 0.66524E+04 35 aragonite 0.97 -2.99 -3.95 -1.318 0.67516E+04 36 brucite 12.57 8.95 -3.62 -0.723 0.61755E+04 37 calcite 0.81 -2.99 -3.80 -1.266 0.64873E+04 38 carnegieite-low 9.02 6.15 -2.87 -0.410 0.49050E+04 39 carnegieite-high 10.09 6.15 -3.94 -0.563 0.67320E+04 40 carpholite-Mg 8.58 5.64 -2.94 -0.196 0.50232E+04 41 carpholite-Fe 6.71 3.30 -3.41 -0.227 0.58195E+04 42 celadonite 5.34 3.20 -2.14 -0.126 0.36600E+04 43 celadonite-Fe 3.88 0.86 -3.01 -0.177 0.51467E+04 44 chrysotile 23.89 20.32 -3.57 -0.298 0.60981E+04 50 chloritoid-Mg 13.20 8.91 -4.29 -0.286 0.73255E+04 51 chloritoid-Fe 9.17 6.57 -2.60 -0.173 0.44428E+04 52 chloritoid-Mn 11.40 8.81 -2.59 -0.173 0.44299E+04 54 coesite -2.38 -3.27 -0.89 -0.297 0.15217E+04 61 cristobalite -2.56 -3.27 -0.71 -0.236 0.12071E+04 63 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71234E+04 65 diaspore 2.87 1.61 -1.26 -0.210 0.21553E+04 67 diopside 16.18 14.54 -1.64 -0.164 0.27971E+04 68 hedenbergite 14.21 12.21 -2.00 -0.200 0.34164E+04 75 epidote 24.67 23.87 -0.80 -0.039 0.13586E+04 76 clinozoisite 22.81 19.28 -3.52 -0.160 0.60132E+04 77 epidote-Fe 29.84 28.46 -1.38 -0.072 0.23507E+04 78 fayalite 14.05 9.96 -4.08 -0.583 0.69680E+04 79 ferrosilite 11.15 6.70 -4.45 -0.445 0.76015E+04 83 gibbsite 4.08 1.61 -2.47 -0.353 0.42138E+04 84 glaucophane 22.97 19.55 -3.42 -0.092 0.58422E+04 85 glaucophane-Fe 17.28 12.55 -4.73 -0.128 0.80762E+04 87 greenalite 16.14 13.31 -2.83 -0.235 0.48251E+04 90 hematite 12.57 12.40 -0.16 -0.020 0.27925E+03 91 heulandite -5.83 -7.52 -1.69 -0.077 0.28938E+04 95 jadeite 4.22 2.88 -1.33 -0.133 0.22742E+04 96 julgoldite 70.43 66.94 -3.49 -0.091 0.59583E+04 97 kalsilite 7.58 4.05 -3.54 -0.505 0.60374E+04 98 kaolinite -1.33 -3.31 -1.98 -0.180 0.33789E+04 99 kyanite 4.88 -0.04 -4.92 -0.492 0.84017E+04 101 laumontite 2.88 2.28 -0.60 -0.040 0.10308E+04 102 lawsonite 9.62 8.81 -0.80 -0.053 0.13691E+04 103 leucite 4.12 0.78 -3.34 -0.334 0.56997E+04 105 lizardite 23.24 20.32 -2.92 -0.244 0.49907E+04 107 magnetite 20.09 19.02 -1.07 -0.087 0.18248E+04 108 minnesotaite 10.39 6.78 -3.61 -0.212 0.61623E+04 110 magnesioferrite 26.21 21.35 -4.86 -0.397 0.82948E+04 120 muscovite 2.58 0.74 -1.85 -0.109 0.31521E+04 121 paragonite 4.24 2.84 -1.40 -0.082 0.23912E+04 122 nepheline 8.34 6.15 -2.19 -0.313 0.37373E+04 134 phlogopite-Na 29.65 26.47 -3.18 -0.176 0.54215E+04 136 prehnite 19.37 17.67 -1.70 -0.100 0.29010E+04 137 prehnite-Fe 22.50 22.26 -0.24 -0.014 0.40142E+03 138 pumpellyite-Fe 46.27 43.57 -2.70 -0.060 0.46036E+04 139 pumpellyite-Mg 48.99 45.91 -3.09 -0.069 0.52690E+04 145 pyroxmangite 7.40 5.58 -1.81 -0.363 0.30989E+04 146 pyrophyllite -6.18 -9.85 -3.67 -0.229 0.62671E+04 147 quartz -2.99 -3.27 -0.28 -0.093 0.47438E+03 152 rhodonite 7.45 5.58 -1.86 -0.372 0.31792E+04 153 sanidine -1.28 -2.49 -1.21 -0.093 0.20677E+04 165 stilpnomelane-Mg 27.44 24.70 -2.75 -0.082 0.46879E+04 171 talc 16.49 13.79 -2.70 -0.159 0.46181E+04 174 tephroite 18.09 14.43 -3.65 -0.522 0.62340E+04 177 topaz-H 4.62 -0.04 -4.66 -0.424 0.79617E+04 178 tridymite -2.63 -3.27 -0.64 -0.214 0.10944E+04 179 tremolite 47.87 42.87 -5.00 -0.135 0.85312E+04 187 wairakite 3.95 2.28 -1.67 -0.098 0.28527E+04 188 walstromite 11.51 8.86 -2.65 -0.530 0.45258E+04 189 wollastonite 10.46 8.86 -1.60 -0.321 0.27362E+04 190 pseudo-wollastonite 11.00 8.86 -2.14 -0.428 0.36561E+04 191 zoisite 22.85 19.28 -3.57 -0.162 0.60873E+04 192 akaganeite 7.75 6.20 -1.55 -0.336 0.26522E+04 193 beidellite-Ca -1.65 -6.24 -4.59 -0.284 0.78370E+04 195 beidellite-K -1.52 -6.35 -4.83 -0.296 0.82534E+04 196 beidellite-Mg -1.79 -6.76 -4.97 -0.307 0.84851E+04 197 beidellite-Na -1.34 -5.66 -4.32 -0.264 0.73726E+04 199 chalcedony -2.80 -3.27 -0.46 -0.155 0.79368E+03 201 montmorillonite-Ca -2.29 -5.42 -3.13 -0.194 0.53484E+04 202 montmorillonite-K -2.24 -5.54 -3.30 -0.202 0.56429E+04 203 montmorillonite-Mg -2.48 -5.95 -3.47 -0.214 0.59197E+04 204 montmorillonite-Na -2.04 -4.85 -2.81 -0.172 0.47978E+04 205 nontronite-Ca 3.21 2.94 -0.27 -0.018 0.46137E+03 206 nontronite-H 2.53 0.94 -1.59 -0.107 0.27134E+04 207 nontronite-K 3.34 2.83 -0.51 -0.033 0.87912E+03 208 nontronite-Mg 3.07 2.42 -0.65 -0.042 0.11167E+04 224 tobermorite 9.82 6.83 -2.99 -0.816 0.51044E+04 233 boehmite 4.41 1.61 -2.79 -0.466 0.47722E+04 235 ferrous-oxide 9.81 6.62 -3.20 -0.799 0.54563E+04 240 silica-amorphous -2.09 -3.27 -1.18 -0.392 0.20079E+04 242 an20ab80 2.02 1.46 -0.56 -0.043 0.95964E+03 243 an25ab75 2.65 1.92 -0.73 -0.056 0.12465E+04 244 an30ab70 3.28 2.38 -0.90 -0.070 0.15430E+04 245 tr.625ac.25prg.125 45.16 41.23 -3.93 -0.106 0.67166E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 1.0000000 g Current total amount of reactant added: 29.9990000 g New total amount of reactant added: 30.9990000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.2995E-12 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 9 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 30.9990000 Water: Moles liquid = 0.5529E+02 kg liquid = 0.9961E+00 Moles total = 0.5512E+02 kg total = 0.9930E+00 Activity = 1.0000 Stoichiometric ionic strength = .5382244E-02 Osmotic coef. = 0.9611 True ionic strength = .9795029E-02 Chg. balance for total moles = 0.2995E-12 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.14989E-09 -9.8242 0.13108E-09 -9.8825 0.87451E+00 -0.0582 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13817E-03 -3.8596 0.12043E-03 -3.9193 0.87157E+00 -0.0597 4 SO4-- 0.25584E-04 -4.5920 0.15683E-04 -4.8046 0.61300E+00 -0.2125 5 HCO3- 0.67293E-05 -5.1720 0.58698E-05 -5.2314 0.87228E+00 -0.0593 6 HS- 0.54282E-11 -11.2653 0.47314E-11 -11.3250 0.87164E+00 -0.0597 7 Al+++ 0.26182E-27 -27.5820 0.88368E-28 -28.0537 0.33752E+00 -0.4717 8 H4SiO4 0.54682E-03 -3.2622 0.54682E-03 -3.2622 0.10000E+01 0.0000 9 Ca++ 0.37580E-07 -7.4250 0.22943E-07 -7.6393 0.61051E+00 -0.2143 10 Mg++ 0.25635E-10 -10.5912 0.15610E-10 -10.8066 0.60896E+00 -0.2154 11 Fe++ 0.11613E-12 -12.9351 0.70759E-13 -13.1502 0.60933E+00 -0.2151 12 K+ 0.76395E-04 -4.1169 0.66647E-04 -4.1762 0.87240E+00 -0.0593 13 Na+ 0.96860E-02 -2.0139 0.84412E-02 -2.0736 0.87149E+00 -0.0597 14 Mn++ 0.20303E-10 -10.6924 0.12377E-10 -10.9074 0.60961E+00 -0.2149 15 HPO4-- 0.52114E-06 -6.2830 0.31949E-06 -6.4955 0.61305E+00 -0.2125 16 HSiO3- 0.44693E-02 -2.3498 0.38953E-02 -2.4095 0.87157E+00 -0.0597 17 Ca(HSiO3)+ 0.23327E-08 -8.6321 0.20353E-08 -8.6914 0.87250E+00 -0.0592 18 Mg(HSiO3)+ 0.19753E-11 -11.7044 0.17234E-11 -11.7636 0.87250E+00 -0.0592 19 NaHSiO3,aq 0.53181E-03 -3.2742 0.53181E-03 -3.2742 0.10000E+01 0.0000 20 AlO+ 0.80197E-15 -15.0958 0.69972E-15 -15.1551 0.87250E+00 -0.0592 22 HAlO2,aq 0.10631E-08 -8.9734 0.10631E-08 -8.9734 0.10000E+01 0.0000 23 AlO2- 0.20620E-04 -4.6857 0.17953E-04 -4.7459 0.87068E+00 -0.0601 24 CH4,aq 0.17230E-17 -17.7637 0.17202E-17 -17.7644 0.99834E+00 -0.0007 29 CO,aq 0.10900E-18 -18.9626 0.10900E-18 -18.9626 0.10000E+01 0.0000 30 CO2,aq 0.16468E-08 -8.7834 0.16440E-08 -8.7841 0.99834E+00 -0.0007 31 CO3-2 0.63884E-05 -5.1946 0.39115E-05 -5.4077 0.61228E+00 -0.2131 32 CaCO3,aq 0.11253E-08 -8.9487 0.11253E-08 -8.9487 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.39400E-11 -11.4045 0.34376E-11 -11.4637 0.87250E+00 -0.0592 34 CaCl+ 0.51247E-11 -11.2903 0.44713E-11 -11.3496 0.87250E+00 -0.0592 35 CaCl2,aq 0.12793E-15 -15.8930 0.12793E-15 -15.8930 0.10000E+01 0.0000 36 CaOH+ 0.14298E-07 -7.8447 0.12475E-07 -7.9040 0.87250E+00 -0.0592 37 CaSO4,aq 0.11426E-09 -9.9421 0.11426E-09 -9.9421 0.10000E+01 0.0000 38 HCl,aq 0.28925E-14 -14.5387 0.28925E-14 -14.5387 0.10000E+01 0.0000 43 FeCl+ 0.15459E-16 -16.8108 0.13488E-16 -16.8701 0.87250E+00 -0.0592 46 FeO,aq 0.16006E-09 -9.7957 0.16006E-09 -9.7957 0.10000E+01 0.0000 47 FeOH+ 0.20140E-10 -10.6959 0.17572E-10 -10.7552 0.87250E+00 -0.0592 48 HFeO2- 0.14660E-07 -7.8339 0.12777E-07 -7.8936 0.87157E+00 -0.0597 49 FeO+ 0.93505E-15 -15.0292 0.81583E-15 -15.0884 0.87250E+00 -0.0592 51 FeO2- 0.11148E-07 -7.9528 0.97162E-08 -8.0125 0.87157E+00 -0.0597 52 HFeO2,aq 0.16198E-09 -9.7905 0.16198E-09 -9.7905 0.10000E+01 0.0000 53 H2,aq 0.26437E-08 -8.5778 0.26393E-08 -8.5785 0.99834E+00 -0.0007 54 KCl,aq 0.14546E-09 -9.8372 0.14546E-09 -9.8372 0.10000E+01 0.0000 55 KHSO4,aq 0.38737E-18 -18.4119 0.38737E-18 -18.4119 0.10000E+01 0.0000 56 KOH,aq 0.21714E-06 -6.6633 0.21714E-06 -6.6633 0.10000E+01 0.0000 57 KSO4- 0.18610E-07 -7.7303 0.16220E-07 -7.7900 0.87157E+00 -0.0597 58 MgCO3,aq 0.19191E-12 -12.7169 0.19191E-12 -12.7169 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.27392E-14 -14.5624 0.23900E-14 -14.6216 0.87250E+00 -0.0592 60 MgCl+ 0.31603E-14 -14.5003 0.27573E-14 -14.5595 0.87250E+00 -0.0592 61 MgOH+ 0.53830E-10 -10.2690 0.46967E-10 -10.3282 0.87250E+00 -0.0592 63 MnO,aq 0.74602E-09 -9.1272 0.74602E-09 -9.1272 0.10000E+01 0.0000 64 MnOH+ 0.32725E-09 -9.4851 0.28553E-09 -9.5443 0.87250E+00 -0.0592 65 MnO2-2 0.23535E-11 -11.6283 0.14410E-11 -11.8413 0.61228E+00 -0.2131 66 HMnO2- 0.47480E-10 -10.3235 0.41382E-10 -10.3832 0.87157E+00 -0.0597 69 MnCl+ 0.10520E-13 -13.9780 0.91783E-14 -14.0372 0.87250E+00 -0.0592 70 MnSO4,aq 0.56038E-13 -13.2515 0.56038E-13 -13.2515 0.10000E+01 0.0000 71 NaCl,aq 0.33688E-06 -6.4725 0.33688E-06 -6.4725 0.10000E+01 0.0000 72 NaOH,aq 0.27669E-04 -4.5580 0.27669E-04 -4.5580 0.10000E+01 0.0000 74 OH- 0.50626E-02 -2.2956 0.44079E-02 -2.3558 0.87068E+00 -0.0601 79 HPO3-2 0.42918E-17 -17.3674 0.26278E-17 -17.5804 0.61228E+00 -0.2131 82 H3PO4,aq 0.38391E-16 -16.4158 0.38391E-16 -16.4158 0.10000E+01 0.0000 83 H2PO4- 0.88589E-09 -9.0526 0.77252E-09 -9.1121 0.87203E+00 -0.0595 84 PO4-3 0.57329E-08 -8.2416 0.19887E-08 -8.7014 0.34688E+00 -0.4598 87 H2P2O7-2 0.76427E-19 -19.1168 0.46795E-19 -19.3298 0.61228E+00 -0.2131 88 HP2O7-3 0.21111E-15 -15.6755 0.71285E-16 -16.1470 0.33767E+00 -0.4715 89 P2O7-4 0.86997E-15 -15.0605 0.12992E-15 -15.8863 0.14934E+00 -0.8258 90 H2S,aq 0.19199E-14 -14.7167 0.19167E-14 -14.7174 0.99834E+00 -0.0007 97 SO3-2 0.87150E-14 -14.0597 0.53790E-14 -14.2693 0.61722E+00 -0.2096 98 HSO3- 0.50651E-16 -16.2954 0.44146E-16 -16.3551 0.87157E+00 -0.0597 99 HSO4- 0.22694E-11 -11.6441 0.19811E-11 -11.7031 0.87297E+00 -0.0590 Charge balance for all species = 0.2993E-12 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.1498869E-09 -.1018058E-01 -.1025351E+02 0.0000 2 H2O 0.1000000E+01 0.5550838E+02 0.9992303E+06 0.0000 3 Cl- 0.1381708E-03 0.1385078E-03 0.4906738E+01 5.9632 4 SO4-- 0.2558439E-04 0.2560387E-04 0.2457655E+01 14.9604 5 HCO3- 0.6729334E-05 0.1312055E-04 0.7999631E+00 4.6511 6 HS- 0.5428217E-11 -.7473924E-09 -.2469873E-04 -1.4425 7 Al+++ 0.2618172E-27 0.2062073E-04 0.5559498E+00 1.5937 8 H4SiO4 0.5468194E-03 0.5547975E-02 0.5328353E+03 -3.2622 9 Ca++ 0.3757985E-07 0.5545875E-07 0.2220965E-02 12.1256 10 Mg++ 0.2563465E-10 0.8163803E-10 0.1983256E-05 8.9584 11 Fe++ 0.1161259E-12 0.2615013E-07 0.1459282E-02 6.6147 12 K+ 0.7639491E-04 0.7663081E-04 0.2994111E+01 5.7063 13 Na+ 0.9685992E-02 0.1024581E-01 0.2353678E+03 7.8089 14 Mn++ 0.2030291E-10 0.1143479E-08 0.6277207E-04 8.8576 15 HPO4-- 0.5211414E-06 0.5277602E-06 0.5061490E-01 13.2694 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.5132844E+00 -.1014135E-01 -.5031430E+00 0.0000000E+00 2 H2O 0.5511967E+02 0.5529451E+02 -.1748426E+00 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.8845924E-03 0.2550521E-04 0.8590872E-03 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.8590880E-03 -.7445127E-09 -.8590872E-03 0.0000000E+00 7 Al+++ 0.1010797E+00 0.2054127E-04 0.1010592E+00 0.0000000E+00 8 H4SiO4 0.3227859E+00 0.5526598E-02 0.3172593E+00 0.0000000E+00 9 Ca++ 0.3566774E-01 0.5524507E-07 0.3566769E-01 0.0000000E+00 10 Mg++ 0.2460238E-01 0.8132348E-10 0.2460238E-01 0.0000000E+00 11 Fe++ 0.2210255E-01 0.2604937E-07 0.2210253E-01 0.0000000E+00 12 K+ 0.6581529E-02 0.7633555E-04 0.6505193E-02 0.0000000E+00 13 Na+ 0.3907137E-01 0.1020633E-01 0.2886503E-01 0.0000000E+00 14 Mn++ 0.5374791E-03 0.1139073E-08 0.5374780E-03 0.0000000E+00 15 HPO4-- 0.1834390E-03 0.5257268E-06 0.1829132E-03 0.0000000E+00 Chg. balance for solid moles: -.1269E-16 Mass of aqueous solution: 0.996914E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 30.9990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 0.2885E-01 -1.540 7.565 0.879 22.35 2.904 andradite 0.3394E-02 -2.469 1.725 0.237 5.096 0.4481 grossular 0.1171E-03 -3.931 0.5275E-01 -1.278 0.1559 0.1468E-01 apatite-OH 0.6097E-04 -4.215 0.3063E-01 -1.514 0.9050E-01 0.9732E-02 clinochlore 0.4920E-02 -2.308 2.735 0.437 8.081 1.040 daphnite 0.2340E-02 -2.631 1.670 0.223 4.933 0.5060 chlorite-Mn 0.1075E-03 -3.969 0.7621E-01 -1.118 0.2252 0.2429E-01 microcline 0.6152E-02 -2.211 1.712 0.234 5.060 0.6689 stilbite 0.2483E-01 -1.605 17.50 1.243 51.70 8.161 stilpnomelane-Fe 0.7059E-03 -3.151 0.7609 -0.119 2.248 0.2628 nontronite-Na 0.4248E-04 -4.372 0.1807E-01 -1.743 0.5338E-01 0.5613E-02 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.9666E+00 0.9666E+00 1.0000 -0.015 grossular 0.3336E-01 0.3336E-01 1.0000 -1.477 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.6678E+00 0.6678E+00 1.0000 -0.175 daphnite 0.3176E+00 0.3176E+00 1.0000 -0.498 chlorite-Mn 0.1459E-01 0.1459E-01 1.0000 -1.836 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 nontronite-Na 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 33.843770 g Volume = 14.046010 cm3 Porosity: -4.8241% V(tot) - V(min): -.64641E+00 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 30.9990000 g log = 1.4913 Original solution: 1000.0103000 g Original solution / Rock added: 32.26 (Water/Rock Ratio), log = 1.5087 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0203 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.1000E+01 0.9860 0.1006E+01 0.1020E+01 CO2,gas 0.1712E-06 1.0071 0.1759E-06 0.1747E-06 CH4,gas 0.2451E-14 1.0125 0.2532E-14 0.2501E-14 H2,gas 0.3394E-05 1.0005 0.3465E-05 0.3463E-05 H2S,gas 0.5185E-13 0.9960 0.5269E-13 0.5290E-13 S2,gas 0.8506E-35 1.0000 0.8679E-35 0.8679E-35 CO,gas 0.1592E-15 1.0000 0.1624E-15 0.1624E-15 SO3,gas 0.9986E-40 1.0000 0.1019E-39 0.1019E-39 SO2,gas 0.1346E-22 1.0000 0.1373E-22 0.1373E-22 HCl,gas 0.5002E-17 1.0000 0.5104E-17 0.5104E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 16 albite -0.38 -0.38 0.00 0.000 -0.94784E-12 22 andradite 39.01 39.01 0.00 0.000 0.24265E-10 23 grossular 32.73 32.73 0.00 0.000 -0.36397E-10 32 apatite-OH -18.15 -18.15 0.00 0.000 0.00000E+00 46 clinochlore 39.07 39.07 0.00 0.000 -0.24265E-10 47 daphnite 28.97 28.97 0.00 0.000 -0.24265E-10 48 chlorite-Mn 46.87 46.87 0.00 0.000 0.00000E+00 116 microcline -2.49 -2.49 0.00 0.000 0.15165E-11 163 stilbite -7.52 -7.52 0.00 0.000 -0.90992E-11 164 stilpnomelane-Fe 13.02 13.02 0.00 0.000 -0.27298E-10 209 nontronite-Na 3.52 3.52 0.00 0.000 -0.68244E-11 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -15.11 -8.45 -2.818 0.14435E+05 -6.755 3 CH4,gas 4.54 -11.75 -16.30 -4.074 0.27824E+05 -14.597 4 H2,gas 8.00 0.84 -7.16 -4.091 0.12224E+05 -5.460 5 H2S,gas -6.23 -21.21 -14.98 -7.489 0.25573E+05 -13.278 6 S2,gas -7.34 -44.10 -36.76 -5.655 0.62768E+05 -35.062 7 CO,gas 3.21 -14.27 -17.49 -5.381 0.29861E+05 -15.789 8 SO3,gas 17.12 -24.57 -41.69 -10.423 0.71186E+05 -39.992 9 SO2,gas 0.83 -23.73 -24.56 -6.550 0.41937E+05 -22.862 10 HCl,gas 5.19 -13.80 -18.99 -9.496 0.32427E+05 -17.292 11 acmite 7.71 7.48 -0.23 -0.024 0.39386E+03 15 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 19 spessartine 24.46 19.97 -4.48 -0.224 0.76558E+04 20 analcite 3.32 2.88 -0.44 -0.049 0.75739E+03 26 annite 20.12 17.36 -2.77 -0.154 0.47224E+04 27 phlogopite 27.06 24.39 -2.68 -0.149 0.45692E+04 29 anorthite 12.71 8.79 -3.92 -0.302 0.66960E+04 35 aragonite 0.97 -2.99 -3.95 -1.318 0.67527E+04 36 brucite 12.57 8.96 -3.61 -0.722 0.61643E+04 37 calcite 0.81 -2.99 -3.80 -1.267 0.64884E+04 38 carnegieite-low 9.02 6.14 -2.88 -0.412 0.49224E+04 39 carnegieite-high 10.09 6.14 -3.95 -0.565 0.67494E+04 40 carpholite-Mg 8.58 5.62 -2.96 -0.197 0.50551E+04 41 carpholite-Fe 6.71 3.28 -3.43 -0.229 0.58648E+04 42 celadonite 5.34 3.21 -2.13 -0.125 0.36401E+04 43 celadonite-Fe 3.88 0.87 -3.01 -0.177 0.51403E+04 44 chrysotile 23.89 20.35 -3.54 -0.295 0.60472E+04 50 chloritoid-Mg 13.20 8.88 -4.31 -0.288 0.73661E+04 51 chloritoid-Fe 9.17 6.54 -2.63 -0.176 0.44968E+04 52 chloritoid-Mn 11.40 8.78 -2.62 -0.175 0.44706E+04 54 coesite -2.38 -3.26 -0.89 -0.295 0.15130E+04 61 cristobalite -2.56 -3.26 -0.70 -0.234 0.11983E+04 63 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71234E+04 65 diaspore 2.87 1.59 -1.28 -0.213 0.21855E+04 67 diopside 16.18 14.56 -1.62 -0.162 0.27690E+04 68 hedenbergite 14.21 12.22 -1.99 -0.199 0.34017E+04 75 epidote 24.67 23.85 -0.82 -0.040 0.14057E+04 76 clinozoisite 22.81 19.25 -3.56 -0.162 0.60788E+04 77 epidote-Fe 29.84 28.45 -1.39 -0.072 0.23792E+04 78 fayalite 14.05 9.97 -4.08 -0.583 0.69638E+04 79 ferrosilite 11.15 6.71 -4.44 -0.444 0.75885E+04 83 gibbsite 4.08 1.59 -2.49 -0.355 0.42441E+04 84 glaucophane 22.97 19.58 -3.39 -0.092 0.57913E+04 85 glaucophane-Fe 17.28 12.55 -4.72 -0.128 0.80656E+04 87 greenalite 16.14 13.32 -2.82 -0.235 0.48144E+04 90 hematite 12.57 12.39 -0.18 -0.021 0.30261E+03 91 heulandite -5.83 -7.52 -1.69 -0.077 0.28938E+04 95 jadeite 4.22 2.88 -1.34 -0.134 0.22829E+04 96 julgoldite 70.43 66.94 -3.49 -0.091 0.59592E+04 97 kalsilite 7.58 4.04 -3.55 -0.507 0.60549E+04 98 kaolinite -1.33 -3.34 -2.00 -0.182 0.34219E+04 99 kyanite 4.88 -0.07 -4.95 -0.495 0.84534E+04 101 laumontite 2.88 2.26 -0.62 -0.041 0.10569E+04 102 lawsonite 9.62 8.79 -0.83 -0.055 0.14127E+04 103 leucite 4.12 0.78 -3.34 -0.334 0.57084E+04 105 lizardite 23.24 20.35 -2.89 -0.241 0.49398E+04 107 magnetite 20.09 19.00 -1.08 -0.088 0.18504E+04 108 minnesotaite 10.39 6.80 -3.59 -0.211 0.61342E+04 110 magnesioferrite 26.21 21.35 -4.87 -0.397 0.83070E+04 120 muscovite 2.58 0.70 -1.88 -0.111 0.32126E+04 121 paragonite 4.24 2.80 -1.44 -0.084 0.24517E+04 122 nepheline 8.34 6.14 -2.20 -0.314 0.37547E+04 134 phlogopite-Na 29.65 26.49 -3.16 -0.175 0.53880E+04 136 prehnite 19.37 17.65 -1.72 -0.101 0.29364E+04 137 prehnite-Fe 22.50 22.25 -0.24 -0.015 0.41822E+03 138 pumpellyite-Fe 46.27 43.51 -2.76 -0.061 0.47069E+04 139 pumpellyite-Mg 48.99 45.86 -3.14 -0.070 0.53588E+04 145 pyroxmangite 7.40 5.60 -1.80 -0.361 0.30790E+04 146 pyrophyllite -6.18 -9.86 -3.69 -0.230 0.62927E+04 147 quartz -2.99 -3.26 -0.27 -0.091 0.46566E+03 152 rhodonite 7.45 5.60 -1.85 -0.370 0.31593E+04 153 sanidine -1.28 -2.49 -1.21 -0.093 0.20677E+04 165 stilpnomelane-Mg 27.44 24.74 -2.71 -0.081 0.46209E+04 171 talc 16.49 13.83 -2.66 -0.157 0.45497E+04 174 tephroite 18.09 14.45 -3.63 -0.519 0.62030E+04 177 topaz-H 4.62 -0.07 -4.69 -0.427 0.80135E+04 178 tridymite -2.63 -3.26 -0.64 -0.212 0.10856E+04 179 tremolite 47.87 42.95 -4.92 -0.133 0.84067E+04 187 wairakite 3.95 2.26 -1.69 -0.099 0.28789E+04 188 walstromite 11.51 8.86 -2.65 -0.529 0.45176E+04 189 wollastonite 10.46 8.86 -1.60 -0.320 0.27280E+04 190 pseudo-wollastonite 11.00 8.86 -2.14 -0.427 0.36479E+04 191 zoisite 22.85 19.25 -3.60 -0.164 0.61529E+04 192 akaganeite 7.75 6.19 -1.56 -0.337 0.26638E+04 193 beidellite-Ca -1.65 -6.26 -4.61 -0.285 0.78756E+04 195 beidellite-K -1.52 -6.38 -4.86 -0.297 0.82905E+04 196 beidellite-Mg -1.79 -6.78 -4.99 -0.309 0.85217E+04 197 beidellite-Na -1.34 -5.68 -4.34 -0.266 0.74097E+04 199 chalcedony -2.80 -3.26 -0.46 -0.153 0.78496E+03 201 montmorillonite-Ca -2.29 -5.43 -3.14 -0.194 0.53605E+04 202 montmorillonite-K -2.24 -5.55 -3.31 -0.203 0.56536E+04 203 montmorillonite-Mg -2.48 -5.95 -3.47 -0.215 0.59298E+04 204 montmorillonite-Na -2.04 -4.85 -2.82 -0.172 0.48085E+04 205 nontronite-Ca 3.21 2.94 -0.27 -0.018 0.46281E+03 206 nontronite-H 2.53 0.94 -1.59 -0.107 0.27148E+04 207 nontronite-K 3.34 2.83 -0.51 -0.033 0.87912E+03 208 nontronite-Mg 3.07 2.42 -0.65 -0.042 0.11162E+04 224 tobermorite 9.82 6.84 -2.98 -0.814 0.50961E+04 233 boehmite 4.41 1.59 -2.81 -0.469 0.48024E+04 235 ferrous-oxide 9.81 6.61 -3.20 -0.799 0.54585E+04 240 silica-amorphous -2.09 -3.26 -1.17 -0.390 0.19991E+04 242 an20ab80 2.02 1.45 -0.57 -0.044 0.96835E+03 243 an25ab75 2.65 1.91 -0.74 -0.057 0.12574E+04 244 an30ab70 3.28 2.37 -0.91 -0.070 0.15561E+04 245 tr.625ac.25prg.125 45.16 41.29 -3.88 -0.104 0.66233E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 1.0000000 g Current total amount of reactant added: 30.9990000 g New total amount of reactant added: 31.9990000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.2994E-12 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 9 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 31.9990000 Water: Moles liquid = 0.5529E+02 kg liquid = 0.9960E+00 Moles total = 0.5511E+02 kg total = 0.9928E+00 Activity = 1.0000 Stoichiometric ionic strength = .5410369E-02 Osmotic coef. = 0.9610 True ionic strength = .9849233E-02 Chg. balance for total moles = 0.2994E-12 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.14991E-09 -9.8242 0.13106E-09 -9.8825 0.87427E+00 -0.0584 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13818E-03 -3.8595 0.12040E-03 -3.9194 0.87132E+00 -0.0598 4 SO4-- 0.25587E-04 -4.5920 0.15667E-04 -4.8050 0.61231E+00 -0.2130 5 HCO3- 0.67269E-05 -5.1722 0.58661E-05 -5.2317 0.87203E+00 -0.0595 6 HS- 0.59847E-11 -11.2230 0.52150E-11 -11.2827 0.87139E+00 -0.0598 7 Al+++ 0.25225E-27 -27.5982 0.84919E-28 -28.0710 0.33665E+00 -0.4728 8 H4SiO4 0.55308E-03 -3.2572 0.55308E-03 -3.2572 0.10000E+01 0.0000 9 Ca++ 0.37590E-07 -7.4249 0.22923E-07 -7.6397 0.60981E+00 -0.2148 10 Mg++ 0.26033E-10 -10.5845 0.15835E-10 -10.8004 0.60825E+00 -0.2159 11 Fe++ 0.11589E-12 -12.9359 0.70536E-13 -13.1516 0.60863E+00 -0.2156 12 K+ 0.76819E-04 -4.1145 0.66997E-04 -4.1739 0.87215E+00 -0.0594 13 Na+ 0.97398E-02 -2.0115 0.84856E-02 -2.0713 0.87124E+00 -0.0599 14 Mn++ 0.20618E-10 -10.6857 0.12555E-10 -10.9012 0.60891E+00 -0.2154 15 HPO4-- 0.52243E-06 -6.2820 0.31992E-06 -6.4950 0.61236E+00 -0.2130 16 HSiO3- 0.45223E-02 -2.3446 0.39403E-02 -2.4045 0.87132E+00 -0.0598 17 Ca(HSiO3)+ 0.23583E-08 -8.6274 0.20570E-08 -8.6868 0.87225E+00 -0.0594 18 Mg(HSiO3)+ 0.20274E-11 -11.6931 0.17684E-11 -11.7524 0.87225E+00 -0.0594 19 NaHSiO3,aq 0.54079E-03 -3.2670 0.54079E-03 -3.2670 0.10000E+01 0.0000 20 AlO+ 0.77105E-15 -15.1129 0.67255E-15 -15.1723 0.87225E+00 -0.0594 22 HAlO2,aq 0.10219E-08 -8.9906 0.10219E-08 -8.9906 0.10000E+01 0.0000 23 AlO2- 0.19829E-04 -4.7027 0.17260E-04 -4.7630 0.87043E+00 -0.0603 24 CH4,aq 0.18999E-17 -17.7213 0.18967E-17 -17.7220 0.99833E+00 -0.0007 29 CO,aq 0.11163E-18 -18.9522 0.11163E-18 -18.9522 0.10000E+01 0.0000 30 CO2,aq 0.16455E-08 -8.7837 0.16428E-08 -8.7844 0.99833E+00 -0.0007 31 CO3-2 0.63923E-05 -5.1943 0.39094E-05 -5.4079 0.61158E+00 -0.2135 32 CaCO3,aq 0.11237E-08 -8.9494 0.11237E-08 -8.9494 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.39351E-11 -11.4050 0.34324E-11 -11.4644 0.87225E+00 -0.0594 34 CaCl+ 0.51206E-11 -11.2907 0.44664E-11 -11.3500 0.87225E+00 -0.0594 35 CaCl2,aq 0.12776E-15 -15.8936 0.12776E-15 -15.8936 0.10000E+01 0.0000 36 CaOH+ 0.14290E-07 -7.8450 0.12465E-07 -7.9043 0.87225E+00 -0.0594 37 CaSO4,aq 0.11404E-09 -9.9429 0.11404E-09 -9.9429 0.10000E+01 0.0000 38 HCl,aq 0.28917E-14 -14.5389 0.28917E-14 -14.5389 0.10000E+01 0.0000 43 FeCl+ 0.15411E-16 -16.8122 0.13442E-16 -16.8715 0.87225E+00 -0.0594 46 FeO,aq 0.15959E-09 -9.7970 0.15959E-09 -9.7970 0.10000E+01 0.0000 47 FeOH+ 0.20084E-10 -10.6971 0.17518E-10 -10.7565 0.87225E+00 -0.0594 48 HFeO2- 0.14622E-07 -7.8350 0.12741E-07 -7.8948 0.87132E+00 -0.0598 49 FeO+ 0.92106E-15 -15.0357 0.80340E-15 -15.0951 0.87225E+00 -0.0594 51 FeO2- 0.10984E-07 -7.9593 0.95702E-08 -8.0191 0.87132E+00 -0.0598 52 HFeO2,aq 0.15953E-09 -9.7972 0.15953E-09 -9.7972 0.10000E+01 0.0000 53 H2,aq 0.27096E-08 -8.5671 0.27051E-08 -8.5678 0.99833E+00 -0.0007 54 KCl,aq 0.14620E-09 -9.8351 0.14620E-09 -9.8351 0.10000E+01 0.0000 55 KHSO4,aq 0.38897E-18 -18.4101 0.38897E-18 -18.4101 0.10000E+01 0.0000 56 KOH,aq 0.21830E-06 -6.6609 0.21830E-06 -6.6609 0.10000E+01 0.0000 57 KSO4- 0.18694E-07 -7.7283 0.16288E-07 -7.7881 0.87132E+00 -0.0598 58 MgCO3,aq 0.19456E-12 -12.7109 0.19456E-12 -12.7109 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.27776E-14 -14.5563 0.24228E-14 -14.6157 0.87225E+00 -0.0594 60 MgCl+ 0.32059E-14 -14.4940 0.27964E-14 -14.5534 0.87225E+00 -0.0594 61 MgOH+ 0.54625E-10 -10.2626 0.47647E-10 -10.3220 0.87225E+00 -0.0594 63 MnO,aq 0.75689E-09 -9.1210 0.75689E-09 -9.1210 0.10000E+01 0.0000 64 MnOH+ 0.33208E-09 -9.4788 0.28966E-09 -9.5381 0.87225E+00 -0.0594 65 MnO2-2 0.23911E-11 -11.6214 0.14623E-11 -11.8350 0.61158E+00 -0.2135 66 HMnO2- 0.48191E-10 -10.3170 0.41989E-10 -10.3769 0.87132E+00 -0.0598 69 MnCl+ 0.10672E-13 -13.9718 0.93083E-14 -14.0311 0.87225E+00 -0.0594 70 MnSO4,aq 0.56785E-13 -13.2458 0.56785E-13 -13.2458 0.10000E+01 0.0000 71 NaCl,aq 0.33859E-06 -6.4703 0.33859E-06 -6.4703 0.10000E+01 0.0000 72 NaOH,aq 0.27817E-04 -4.5557 0.27817E-04 -4.5557 0.10000E+01 0.0000 74 OH- 0.50646E-02 -2.2955 0.44084E-02 -2.3557 0.87043E+00 -0.0603 79 HPO3-2 0.44097E-17 -17.3556 0.26969E-17 -17.5691 0.61158E+00 -0.2135 82 H3PO4,aq 0.38434E-16 -16.4153 0.38434E-16 -16.4153 0.10000E+01 0.0000 83 H2PO4- 0.88725E-09 -9.0520 0.77348E-09 -9.1115 0.87178E+00 -0.0596 84 PO4-3 0.57553E-08 -8.2399 0.19915E-08 -8.7008 0.34604E+00 -0.4609 87 H2P2O7-2 0.76704E-19 -19.1152 0.46911E-19 -19.3287 0.61158E+00 -0.2135 88 HP2O7-3 0.21220E-15 -15.6733 0.71469E-16 -16.1459 0.33680E+00 -0.4726 89 P2O7-4 0.87625E-15 -15.0574 0.13027E-15 -15.8852 0.14867E+00 -0.8278 90 H2S,aq 0.21160E-14 -14.6745 0.21124E-14 -14.6752 0.99833E+00 -0.0007 97 SO3-2 0.89328E-14 -14.0490 0.55074E-14 -14.2591 0.61654E+00 -0.2100 98 HSO3- 0.51870E-16 -16.2851 0.45195E-16 -16.3449 0.87132E+00 -0.0598 99 HSO4- 0.22675E-11 -11.6445 0.19789E-11 -11.7036 0.87272E+00 -0.0591 Charge balance for all species = 0.2994E-12 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.1499122E-09 -.1024150E-01 -.1031480E+02 0.0000 2 H2O 0.1000000E+01 0.5550832E+02 0.9992224E+06 0.0000 3 Cl- 0.1381840E-03 0.1385228E-03 0.4907234E+01 5.9632 4 SO4-- 0.2558706E-04 0.2560659E-04 0.2457899E+01 14.9600 5 HCO3- 0.6726940E-05 0.1312197E-04 0.8000439E+00 4.6509 6 HS- 0.5984737E-11 -.7095029E-09 -.2344646E-04 -1.4002 7 Al+++ 0.2522464E-27 0.1983000E-04 0.5346276E+00 1.5766 8 H4SiO4 0.5530793E-03 0.5616152E-02 0.5393795E+03 -3.2572 9 Ca++ 0.3758952E-07 0.5548494E-07 0.2221998E-02 12.1253 10 Mg++ 0.2603297E-10 0.8288552E-10 0.2013548E-05 8.9646 11 Fe++ 0.1158938E-12 0.2594533E-07 0.1447843E-02 6.6134 12 K+ 0.7681865E-04 0.7705580E-04 0.3010696E+01 5.7086 13 Na+ 0.9739766E-02 0.1030871E-01 0.2368111E+03 7.8112 14 Mn++ 0.2061829E-10 0.1160245E-08 0.6369202E-04 8.8638 15 HPO4-- 0.5224309E-06 0.5290735E-06 0.5074051E-01 13.2701 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.5298429E+00 -.1020094E-01 -.5196420E+00 0.0000000E+00 2 H2O 0.5510713E+02 0.5528849E+02 -.1813556E+00 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.9123058E-03 0.2550518E-04 0.8868007E-03 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.8868014E-03 -.7066930E-09 -.8868007E-03 0.0000000E+00 7 Al+++ 0.1043405E+00 0.1975147E-04 0.1043207E+00 0.0000000E+00 8 H4SiO4 0.3331986E+00 0.5593910E-02 0.3276047E+00 0.0000000E+00 9 Ca++ 0.3681789E-01 0.5526520E-07 0.3681783E-01 0.0000000E+00 10 Mg++ 0.2539603E-01 0.8255726E-10 0.2539603E-01 0.0000000E+00 11 Fe++ 0.2281556E-01 0.2584257E-07 0.2281554E-01 0.0000000E+00 12 K+ 0.6793843E-02 0.7675063E-04 0.6717092E-02 0.0000000E+00 13 Na+ 0.4032661E-01 0.1026788E-01 0.3005873E-01 0.0000000E+00 14 Mn++ 0.5548177E-03 0.1155650E-08 0.5548166E-03 0.0000000E+00 15 HPO4-- 0.1893565E-03 0.5269782E-06 0.1888296E-03 0.0000000E+00 Chg. balance for solid moles: 0.1251E-15 Mass of aqueous solution: 0.996814E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 31.9990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 0.3006E-01 -1.522 7.882 0.897 22.56 3.026 andradite 0.3545E-02 -2.450 1.801 0.256 5.156 0.4680 grossular 0.1194E-03 -3.923 0.5378E-01 -1.269 0.1539 0.1496E-01 apatite-OH 0.6294E-04 -4.201 0.3162E-01 -1.500 0.9050E-01 0.1005E-01 clinochlore 0.5079E-02 -2.294 2.823 0.451 8.081 1.074 daphnite 0.2374E-02 -2.625 1.694 0.229 4.848 0.5133 chlorite-Mn 0.1110E-03 -3.955 0.7867E-01 -1.104 0.2252 0.2507E-01 microcline 0.6332E-02 -2.198 1.762 0.246 5.045 0.6884 stilbite 0.2551E-01 -1.593 17.98 1.255 51.46 8.385 stilpnomelane-Fe 0.7704E-03 -3.113 0.8305 -0.081 2.377 0.2869 nontronite-Na 0.2634E-05 -5.579 0.1120E-02 -2.951 0.3207E-02 0.3480E-03 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.9674E+00 0.9674E+00 1.0000 -0.014 grossular 0.3258E-01 0.3258E-01 1.0000 -1.487 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.6715E+00 0.6715E+00 1.0000 -0.173 daphnite 0.3138E+00 0.3138E+00 1.0000 -0.503 chlorite-Mn 0.1467E-01 0.1467E-01 1.0000 -1.834 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 nontronite-Na 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 34.936351 g Volume = 14.491872 cm3 Porosity: -5.0166% V(tot) - V(min): -.69227E+00 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 31.9990000 g log = 1.5051 Original solution: 1000.0103000 g Original solution / Rock added: 31.25 (Water/Rock Ratio), log = 1.4949 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0203 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.1000E+01 0.9860 0.1006E+01 0.1020E+01 CO2,gas 0.1711E-06 1.0071 0.1758E-06 0.1745E-06 CH4,gas 0.2702E-14 1.0125 0.2792E-14 0.2757E-14 H2,gas 0.3479E-05 1.0005 0.3551E-05 0.3550E-05 H2S,gas 0.5714E-13 0.9960 0.5807E-13 0.5830E-13 S2,gas 0.9836E-35 1.0000 0.1004E-34 0.1004E-34 CO,gas 0.1630E-15 1.0000 0.1664E-15 0.1664E-15 SO3,gas 0.9973E-40 1.0000 0.1018E-39 0.1018E-39 SO2,gas 0.1378E-22 1.0000 0.1406E-22 0.1406E-22 HCl,gas 0.5001E-17 1.0000 0.5102E-17 0.5102E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 16 albite -0.38 -0.38 0.00 0.000 -0.94784E-12 22 andradite 39.01 39.01 0.00 0.000 0.12132E-10 23 grossular 32.73 32.73 0.00 0.000 0.00000E+00 32 apatite-OH -18.15 -18.15 0.00 0.000 0.00000E+00 46 clinochlore 39.07 39.07 0.00 0.000 0.12132E-10 47 daphnite 28.97 28.97 0.00 0.000 0.36397E-10 48 chlorite-Mn 46.87 46.87 0.00 0.000 0.48529E-10 116 microcline -2.49 -2.49 0.00 0.000 -0.10616E-10 163 stilbite -7.52 -7.52 0.00 0.000 -0.90992E-11 164 stilpnomelane-Fe 13.02 13.02 0.00 0.000 0.69761E-10 209 nontronite-Na 3.52 3.52 0.00 0.000 -0.83410E-11 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -15.11 -8.45 -2.818 0.14435E+05 -6.755 3 CH4,gas 4.54 -11.71 -16.25 -4.063 0.27752E+05 -14.554 4 H2,gas 8.00 0.85 -7.15 -4.085 0.12206E+05 -5.450 5 H2S,gas -6.23 -21.17 -14.94 -7.468 0.25501E+05 -13.236 6 S2,gas -7.34 -44.03 -36.70 -5.646 0.62660E+05 -34.998 7 CO,gas 3.21 -14.26 -17.48 -5.378 0.29843E+05 -15.779 8 SO3,gas 17.12 -24.57 -41.69 -10.423 0.71187E+05 -39.992 9 SO2,gas 0.83 -23.72 -24.55 -6.547 0.41920E+05 -22.852 10 HCl,gas 5.19 -13.80 -18.99 -9.496 0.32427E+05 -17.292 11 acmite 7.71 7.48 -0.23 -0.023 0.38432E+03 15 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 19 spessartine 24.46 19.97 -4.48 -0.224 0.76568E+04 20 analcite 3.32 2.87 -0.45 -0.050 0.76583E+03 26 annite 20.12 17.35 -2.77 -0.154 0.47289E+04 27 phlogopite 27.06 24.41 -2.66 -0.148 0.45370E+04 29 anorthite 12.71 8.76 -3.95 -0.304 0.67382E+04 35 aragonite 0.97 -2.99 -3.96 -1.318 0.67537E+04 36 brucite 12.57 8.96 -3.60 -0.721 0.61536E+04 37 calcite 0.81 -2.99 -3.80 -1.267 0.64895E+04 38 carnegieite-low 9.02 6.13 -2.89 -0.413 0.49393E+04 39 carnegieite-high 10.09 6.13 -3.96 -0.566 0.67663E+04 40 carpholite-Mg 8.58 5.60 -2.98 -0.199 0.50861E+04 41 carpholite-Fe 6.71 3.25 -3.46 -0.231 0.59087E+04 42 celadonite 5.34 3.22 -2.12 -0.125 0.36210E+04 43 celadonite-Fe 3.88 0.87 -3.01 -0.177 0.51340E+04 44 chrysotile 23.89 20.38 -3.51 -0.293 0.59981E+04 50 chloritoid-Mg 13.20 8.86 -4.34 -0.289 0.74055E+04 51 chloritoid-Fe 9.17 6.51 -2.66 -0.178 0.45491E+04 52 chloritoid-Mn 11.40 8.76 -2.64 -0.176 0.45100E+04 54 coesite -2.38 -3.26 -0.88 -0.294 0.15045E+04 61 cristobalite -2.56 -3.26 -0.70 -0.232 0.11899E+04 63 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71234E+04 65 diaspore 2.87 1.58 -1.30 -0.216 0.22148E+04 67 diopside 16.18 14.58 -1.61 -0.161 0.27419E+04 68 hedenbergite 14.21 12.22 -1.98 -0.198 0.33875E+04 75 epidote 24.67 23.82 -0.85 -0.041 0.14513E+04 76 clinozoisite 22.81 19.21 -3.60 -0.164 0.61424E+04 77 epidote-Fe 29.84 28.43 -1.41 -0.073 0.24068E+04 78 fayalite 14.05 9.97 -4.08 -0.582 0.69597E+04 79 ferrosilite 11.15 6.71 -4.44 -0.444 0.75760E+04 83 gibbsite 4.08 1.58 -2.50 -0.358 0.42734E+04 84 glaucophane 22.97 19.61 -3.36 -0.091 0.57423E+04 85 glaucophane-Fe 17.28 12.56 -4.72 -0.128 0.80552E+04 87 greenalite 16.14 13.33 -2.81 -0.234 0.48041E+04 90 hematite 12.57 12.38 -0.19 -0.023 0.32524E+03 91 heulandite -5.83 -7.52 -1.69 -0.077 0.28938E+04 95 jadeite 4.22 2.87 -1.34 -0.134 0.22913E+04 96 julgoldite 70.43 66.94 -3.49 -0.091 0.59602E+04 97 kalsilite 7.58 4.03 -3.56 -0.508 0.60717E+04 98 kaolinite -1.33 -3.36 -2.03 -0.184 0.34636E+04 99 kyanite 4.88 -0.10 -4.98 -0.498 0.85036E+04 101 laumontite 2.88 2.25 -0.63 -0.042 0.10822E+04 102 lawsonite 9.62 8.76 -0.85 -0.057 0.14549E+04 103 leucite 4.12 0.77 -3.35 -0.335 0.57169E+04 105 lizardite 23.24 20.38 -2.86 -0.239 0.48908E+04 107 magnetite 20.09 18.99 -1.10 -0.090 0.18752E+04 108 minnesotaite 10.39 6.81 -3.58 -0.210 0.61070E+04 110 magnesioferrite 26.21 21.34 -4.87 -0.398 0.83189E+04 120 muscovite 2.58 0.67 -1.92 -0.113 0.32712E+04 121 paragonite 4.24 2.77 -1.47 -0.086 0.25103E+04 122 nepheline 8.34 6.13 -2.21 -0.316 0.37716E+04 134 phlogopite-Na 29.65 26.51 -3.14 -0.174 0.53558E+04 136 prehnite 19.37 17.63 -1.74 -0.102 0.29706E+04 137 prehnite-Fe 22.50 22.24 -0.25 -0.015 0.43451E+03 138 pumpellyite-Fe 46.27 43.45 -2.82 -0.063 0.48069E+04 139 pumpellyite-Mg 48.99 45.81 -3.19 -0.071 0.54459E+04 145 pyroxmangite 7.40 5.61 -1.79 -0.358 0.30599E+04 146 pyrophyllite -6.18 -9.88 -3.70 -0.231 0.63175E+04 147 quartz -2.99 -3.26 -0.27 -0.089 0.45722E+03 152 rhodonite 7.45 5.61 -1.84 -0.368 0.31401E+04 153 sanidine -1.28 -2.49 -1.21 -0.093 0.20677E+04 165 stilpnomelane-Mg 27.44 24.77 -2.67 -0.080 0.45563E+04 171 talc 16.49 13.87 -2.63 -0.154 0.44838E+04 174 tephroite 18.09 14.47 -3.62 -0.516 0.61731E+04 177 topaz-H 4.62 -0.10 -4.72 -0.429 0.80637E+04 178 tridymite -2.63 -3.26 -0.63 -0.210 0.10772E+04 179 tremolite 47.87 43.02 -4.85 -0.131 0.82866E+04 187 wairakite 3.95 2.25 -1.70 -0.100 0.29042E+04 188 walstromite 11.51 8.87 -2.64 -0.528 0.45097E+04 189 wollastonite 10.46 8.87 -1.59 -0.319 0.27201E+04 190 pseudo-wollastonite 11.00 8.87 -2.13 -0.426 0.36399E+04 191 zoisite 22.85 19.21 -3.64 -0.165 0.62165E+04 192 akaganeite 7.75 6.19 -1.57 -0.339 0.26751E+04 193 beidellite-Ca -1.65 -6.28 -4.63 -0.287 0.79129E+04 195 beidellite-K -1.52 -6.40 -4.88 -0.299 0.83265E+04 197 beidellite-Na -1.34 -5.70 -4.36 -0.267 0.74457E+04 199 chalcedony -2.80 -3.26 -0.45 -0.152 0.77652E+03 201 montmorillonite-Ca -2.29 -5.44 -3.15 -0.195 0.53721E+04 202 montmorillonite-K -2.24 -5.55 -3.32 -0.203 0.56639E+04 203 montmorillonite-Mg -2.48 -5.96 -3.48 -0.215 0.59396E+04 204 montmorillonite-Na -2.04 -4.86 -2.82 -0.173 0.48188E+04 205 nontronite-Ca 3.21 2.94 -0.27 -0.018 0.46420E+03 206 nontronite-H 2.53 0.94 -1.59 -0.107 0.27161E+04 207 nontronite-K 3.34 2.83 -0.51 -0.033 0.87912E+03 208 nontronite-Mg 3.07 2.42 -0.65 -0.042 0.11158E+04 224 tobermorite 9.82 6.84 -2.98 -0.813 0.50881E+04 233 boehmite 4.41 1.58 -2.83 -0.472 0.48317E+04 235 ferrous-oxide 9.81 6.61 -3.20 -0.800 0.54607E+04 240 silica-amorphous -2.09 -3.26 -1.17 -0.389 0.19907E+04 242 an20ab80 2.02 1.45 -0.57 -0.044 0.97679E+03 243 an25ab75 2.65 1.90 -0.74 -0.057 0.12680E+04 244 an30ab70 3.28 2.36 -0.92 -0.071 0.15687E+04 245 tr.625ac.25prg.125 45.16 41.34 -3.83 -0.103 0.65332E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 1.0000000 g Current total amount of reactant added: 31.9990000 g New total amount of reactant added: 32.9990000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.2995E-12 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 9 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 32.9990000 Water: Moles liquid = 0.5528E+02 kg liquid = 0.9959E+00 Moles total = 0.5509E+02 kg total = 0.9925E+00 Activity = 1.0000 Stoichiometric ionic strength = .5438051E-02 Osmotic coef. = 0.9610 True ionic strength = .9902216E-02 Chg. balance for total moles = 0.2995E-12 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.14994E-09 -9.8241 0.13105E-09 -9.8826 0.87403E+00 -0.0585 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13820E-03 -3.8595 0.12038E-03 -3.9194 0.87107E+00 -0.0599 4 SO4-- 0.25590E-04 -4.5919 0.15652E-04 -4.8054 0.61164E+00 -0.2135 5 HCO3- 0.67247E-05 -5.1723 0.58625E-05 -5.2319 0.87178E+00 -0.0596 6 HS- 0.65786E-11 -11.1819 0.57309E-11 -11.2418 0.87114E+00 -0.0599 7 Al+++ 0.24332E-27 -27.6138 0.81711E-28 -28.0877 0.33581E+00 -0.4739 8 H4SiO4 0.55922E-03 -3.2524 0.55922E-03 -3.2524 0.10000E+01 0.0000 9 Ca++ 0.37600E-07 -7.4248 0.22904E-07 -7.6401 0.60913E+00 -0.2153 10 Mg++ 0.26424E-10 -10.5780 0.16054E-10 -10.7944 0.60757E+00 -0.2164 11 Fe++ 0.11567E-12 -12.9368 0.70323E-13 -13.1529 0.60794E+00 -0.2161 12 K+ 0.77233E-04 -4.1122 0.67340E-04 -4.1717 0.87191E+00 -0.0595 13 Na+ 0.97923E-02 -2.0091 0.85290E-02 -2.0691 0.87099E+00 -0.0600 14 Mn++ 0.20928E-10 -10.6793 0.12729E-10 -10.8952 0.60822E+00 -0.2159 15 HPO4-- 0.52368E-06 -6.2809 0.32033E-06 -6.4944 0.61169E+00 -0.2135 16 HSiO3- 0.45741E-02 -2.3397 0.39844E-02 -2.3996 0.87107E+00 -0.0599 17 Ca(HSiO3)+ 0.23833E-08 -8.6228 0.20782E-08 -8.6823 0.87201E+00 -0.0595 18 Mg(HSiO3)+ 0.20790E-11 -11.6821 0.18129E-11 -11.7416 0.87201E+00 -0.0595 19 NaHSiO3,aq 0.54963E-03 -3.2599 0.54963E-03 -3.2599 0.10000E+01 0.0000 20 AlO+ 0.74223E-15 -15.1295 0.64724E-15 -15.1889 0.87201E+00 -0.0595 22 HAlO2,aq 0.98354E-09 -9.0072 0.98354E-09 -9.0072 0.10000E+01 0.0000 23 AlO2- 0.19091E-04 -4.7192 0.16613E-04 -4.7796 0.87018E+00 -0.0604 24 CH4,aq 0.20886E-17 -17.6801 0.20851E-17 -17.6809 0.99833E+00 -0.0007 29 CO,aq 0.11425E-18 -18.9421 0.11425E-18 -18.9421 0.10000E+01 0.0000 30 CO2,aq 0.16444E-08 -8.7840 0.16417E-08 -8.7847 0.99833E+00 -0.0007 31 CO3-2 0.63959E-05 -5.1941 0.39073E-05 -5.4081 0.61091E+00 -0.2140 32 CaCO3,aq 0.11221E-08 -8.9500 0.11221E-08 -8.9500 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.39305E-11 -11.4056 0.34274E-11 -11.4650 0.87201E+00 -0.0595 34 CaCl+ 0.51168E-11 -11.2910 0.44619E-11 -11.3505 0.87201E+00 -0.0595 35 CaCl2,aq 0.12761E-15 -15.8941 0.12761E-15 -15.8941 0.10000E+01 0.0000 36 CaOH+ 0.14284E-07 -7.8452 0.12455E-07 -7.9046 0.87201E+00 -0.0595 37 CaSO4,aq 0.11383E-09 -9.9437 0.11383E-09 -9.9437 0.10000E+01 0.0000 38 HCl,aq 0.28909E-14 -14.5390 0.28909E-14 -14.5390 0.10000E+01 0.0000 43 FeCl+ 0.15366E-16 -16.8134 0.13399E-16 -16.8729 0.87201E+00 -0.0595 46 FeO,aq 0.15914E-09 -9.7982 0.15914E-09 -9.7982 0.10000E+01 0.0000 47 FeOH+ 0.20031E-10 -10.6983 0.17467E-10 -10.7578 0.87201E+00 -0.0595 48 HFeO2- 0.14586E-07 -7.8361 0.12705E-07 -7.8960 0.87107E+00 -0.0599 49 FeO+ 0.90772E-15 -15.0420 0.79154E-15 -15.1015 0.87201E+00 -0.0595 51 FeO2- 0.10826E-07 -7.9655 0.94305E-08 -8.0255 0.87107E+00 -0.0599 52 HFeO2,aq 0.15719E-09 -9.8036 0.15719E-09 -9.8036 0.10000E+01 0.0000 53 H2,aq 0.27750E-08 -8.5567 0.27704E-08 -8.5575 0.99833E+00 -0.0007 54 KCl,aq 0.14692E-09 -9.8329 0.14692E-09 -9.8329 0.10000E+01 0.0000 55 KHSO4,aq 0.39054E-18 -18.4083 0.39054E-18 -18.4083 0.10000E+01 0.0000 56 KOH,aq 0.21944E-06 -6.6587 0.21944E-06 -6.6587 0.10000E+01 0.0000 57 KSO4- 0.18776E-07 -7.7264 0.16355E-07 -7.7863 0.87107E+00 -0.0599 58 MgCO3,aq 0.19715E-12 -12.7052 0.19715E-12 -12.7052 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.28152E-14 -14.5505 0.24548E-14 -14.6100 0.87201E+00 -0.0595 60 MgCl+ 0.32507E-14 -14.4880 0.28346E-14 -14.5475 0.87201E+00 -0.0595 61 MgOH+ 0.55402E-10 -10.2565 0.48311E-10 -10.3160 0.87201E+00 -0.0595 63 MnO,aq 0.76751E-09 -9.1149 0.76751E-09 -9.1149 0.10000E+01 0.0000 64 MnOH+ 0.33681E-09 -9.4726 0.29370E-09 -9.5321 0.87201E+00 -0.0595 65 MnO2-2 0.24277E-11 -11.6148 0.14831E-11 -11.8288 0.61091E+00 -0.2140 66 HMnO2- 0.48884E-10 -10.3108 0.42582E-10 -10.3708 0.87107E+00 -0.0599 69 MnCl+ 0.10821E-13 -13.9658 0.94356E-14 -14.0252 0.87201E+00 -0.0595 70 MnSO4,aq 0.57515E-13 -13.2402 0.57515E-13 -13.2402 0.10000E+01 0.0000 71 NaCl,aq 0.34026E-06 -6.4682 0.34026E-06 -6.4682 0.10000E+01 0.0000 72 NaOH,aq 0.27962E-04 -4.5534 0.27962E-04 -4.5534 0.10000E+01 0.0000 74 OH- 0.50664E-02 -2.2953 0.44087E-02 -2.3557 0.87018E+00 -0.0604 79 HPO3-2 0.45269E-17 -17.3442 0.27655E-17 -17.5582 0.61091E+00 -0.2140 82 H3PO4,aq 0.38478E-16 -16.4148 0.38478E-16 -16.4148 0.10000E+01 0.0000 83 H2PO4- 0.88856E-09 -9.0513 0.77441E-09 -9.1110 0.87153E+00 -0.0597 84 PO4-3 0.57769E-08 -8.2383 0.19943E-08 -8.7002 0.34521E+00 -0.4619 87 H2P2O7-2 0.76973E-19 -19.1137 0.47024E-19 -19.3277 0.61091E+00 -0.2140 88 HP2O7-3 0.21326E-15 -15.6711 0.71647E-16 -16.1448 0.33596E+00 -0.4737 89 P2O7-4 0.88235E-15 -15.0544 0.13061E-15 -15.8840 0.14802E+00 -0.8297 90 H2S,aq 0.23251E-14 -14.6336 0.23212E-14 -14.6343 0.99833E+00 -0.0007 97 SO3-2 0.91490E-14 -14.0386 0.56347E-14 -14.2491 0.61588E+00 -0.2105 98 HSO3- 0.53079E-16 -16.2751 0.46236E-16 -16.3350 0.87107E+00 -0.0599 99 HSO4- 0.22657E-11 -11.6448 0.19768E-11 -11.7040 0.87248E+00 -0.0592 Charge balance for all species = 0.2994E-12 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.1499401E-09 -.1030123E-01 -.1037489E+02 0.0000 2 H2O 0.1000000E+01 0.5550826E+02 0.9992146E+06 0.0000 3 Cl- 0.1381973E-03 0.1385377E-03 0.4907730E+01 5.9631 4 SO4-- 0.2558974E-04 0.2560931E-04 0.2458144E+01 14.9597 5 HCO3- 0.6724695E-05 0.1312338E-04 0.8001248E+00 4.6506 6 HS- 0.6578574E-11 -.6726028E-09 -.2222689E-04 -1.3592 7 Al+++ 0.2433233E-27 0.1909229E-04 0.5147352E+00 1.5599 8 H4SiO4 0.5592150E-03 0.5682954E-02 0.5457915E+03 -3.2524 9 Ca++ 0.3760019E-07 0.5551210E-07 0.2223071E-02 12.1250 10 Mg++ 0.2642372E-10 0.8410777E-10 0.2043226E-05 8.9707 11 Fe++ 0.1156745E-12 0.2574875E-07 0.1436864E-02 6.6122 12 K+ 0.7723283E-04 0.7747120E-04 0.3026906E+01 5.7108 13 Na+ 0.9792326E-02 0.1037025E-01 0.2382233E+03 7.8135 14 Mn++ 0.2092766E-10 0.1176628E-08 0.6459095E-04 8.8699 15 HPO4-- 0.5236757E-06 0.5303411E-06 0.5086174E-01 13.2707 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.5464014E+00 -.1025932E-01 -.5361421E+00 0.0000000E+00 2 H2O 0.5509459E+02 0.5528247E+02 -.1878741E+00 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.9400193E-03 0.2550514E-04 0.9145141E-03 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.9145148E-03 -.6698668E-09 -.9145141E-03 0.0000000E+00 7 Al+++ 0.1076012E+00 0.1901463E-04 0.1075822E+00 0.0000000E+00 8 H4SiO4 0.3436114E+00 0.5659838E-02 0.3379516E+00 0.0000000E+00 9 Ca++ 0.3796803E-01 0.5528629E-07 0.3796797E-01 0.0000000E+00 10 Mg++ 0.2618968E-01 0.8376564E-10 0.2618968E-01 0.0000000E+00 11 Fe++ 0.2352857E-01 0.2564402E-07 0.2352854E-01 0.0000000E+00 12 K+ 0.7006157E-02 0.7715607E-04 0.6929001E-02 0.0000000E+00 13 Na+ 0.4158186E-01 0.1032807E-01 0.3125379E-01 0.0000000E+00 14 Mn++ 0.5721563E-03 0.1171842E-08 0.5721552E-03 0.0000000E+00 15 HPO4-- 0.1952741E-03 0.5281839E-06 0.1947459E-03 0.0000000E+00 Chg. balance for solid moles: 0.5486E-16 Mass of aqueous solution: 0.996713E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 32.9990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 0.3127E-01 -1.505 8.199 0.914 22.76 3.147 andradite 0.3696E-02 -2.432 1.878 0.274 5.212 0.4879 grossular 0.1216E-03 -3.915 0.5476E-01 -1.262 0.1520 0.1524E-01 apatite-OH 0.6492E-04 -4.188 0.3261E-01 -1.487 0.9051E-01 0.1036E-01 clinochlore 0.5238E-02 -2.281 2.911 0.464 8.081 1.107 daphnite 0.2407E-02 -2.618 1.718 0.235 4.767 0.5205 chlorite-Mn 0.1144E-03 -3.941 0.8113E-01 -1.091 0.2252 0.2585E-01 microcline 0.6511E-02 -2.186 1.812 0.258 5.030 0.7080 stilbite 0.2619E-01 -1.582 18.46 1.266 51.23 8.609 stilpnomelane-Fe 0.8352E-03 -3.078 0.9003 -0.046 2.499 0.3110 nontronite-Na -.3747E-04 1.000 -.1594E-01 1.000 -.4423E-01 -.4951E-02 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.9681E+00 0.9681E+00 1.0000 -0.014 grossular 0.3185E-01 0.3185E-01 1.0000 -1.497 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.6750E+00 0.6750E+00 1.0000 -0.171 daphnite 0.3102E+00 0.3102E+00 1.0000 -0.508 chlorite-Mn 0.1475E-01 0.1475E-01 1.0000 -1.831 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 nontronite-Na 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 36.028996 g Volume = 14.937728 cm3 Porosity: -5.1982% V(tot) - V(min): -.73813E+00 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 32.9990000 g log = 1.5185 Original solution: 1000.0103000 g Original solution / Rock added: 30.30 (Water/Rock Ratio), log = 1.4815 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0203 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.1000E+01 0.9860 0.1006E+01 0.1020E+01 CO2,gas 0.1709E-06 1.0071 0.1756E-06 0.1744E-06 CH4,gas 0.2971E-14 1.0125 0.3069E-14 0.3031E-14 H2,gas 0.3563E-05 1.0005 0.3637E-05 0.3635E-05 H2S,gas 0.6279E-13 0.9960 0.6381E-13 0.6406E-13 S2,gas 0.1132E-34 1.0000 0.1155E-34 0.1155E-34 CO,gas 0.1669E-15 1.0000 0.1703E-15 0.1703E-15 SO3,gas 0.9962E-40 1.0000 0.1016E-39 0.1016E-39 SO2,gas 0.1410E-22 1.0000 0.1438E-22 0.1438E-22 HCl,gas 0.5000E-17 1.0000 0.5101E-17 0.5101E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 16 albite -0.38 -0.38 0.00 0.000 -0.94784E-12 22 andradite 39.01 39.01 0.00 0.000 0.00000E+00 23 grossular 32.73 32.73 0.00 0.000 0.24265E-10 32 apatite-OH -18.15 -18.15 0.00 0.000 0.60662E-11 46 clinochlore 39.07 39.07 0.00 0.000 0.00000E+00 47 daphnite 28.97 28.97 0.00 0.000 -0.24265E-10 48 chlorite-Mn 46.87 46.87 0.00 0.000 0.12132E-10 116 microcline -2.49 -2.49 0.00 0.000 0.15165E-11 163 stilbite -7.52 -7.52 0.00 0.000 -0.90992E-11 164 stilpnomelane-Fe 13.02 13.02 0.00 0.000 0.69761E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -15.11 -8.45 -2.818 0.14436E+05 -6.755 3 CH4,gas 4.54 -11.67 -16.21 -4.053 0.27681E+05 -14.513 4 H2,gas 8.00 0.86 -7.14 -4.079 0.12188E+05 -5.439 5 H2S,gas -6.23 -21.12 -14.89 -7.447 0.25431E+05 -13.195 6 S2,gas -7.34 -43.97 -36.64 -5.636 0.62555E+05 -34.937 7 CO,gas 3.21 -14.25 -17.47 -5.375 0.29826E+05 -15.769 8 SO3,gas 17.12 -24.57 -41.69 -10.423 0.71188E+05 -39.993 9 SO2,gas 0.83 -23.71 -24.54 -6.544 0.41903E+05 -22.842 10 HCl,gas 5.19 -13.80 -18.99 -9.496 0.32427E+05 -17.292 11 acmite 7.71 7.49 -0.22 -0.023 0.37508E+03 15 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 19 spessartine 24.46 19.97 -4.49 -0.224 0.76581E+04 20 analcite 3.32 2.87 -0.45 -0.050 0.77401E+03 26 annite 20.12 17.35 -2.77 -0.154 0.47353E+04 27 phlogopite 27.06 24.43 -2.64 -0.147 0.45060E+04 29 anorthite 12.71 8.74 -3.97 -0.305 0.67791E+04 35 aragonite 0.97 -2.99 -3.96 -1.319 0.67547E+04 36 brucite 12.57 8.97 -3.60 -0.720 0.61433E+04 37 calcite 0.81 -2.99 -3.80 -1.267 0.64905E+04 38 carnegieite-low 9.02 6.12 -2.90 -0.415 0.49556E+04 39 carnegieite-high 10.09 6.12 -3.97 -0.567 0.67826E+04 40 carpholite-Mg 8.58 5.59 -3.00 -0.200 0.51162E+04 41 carpholite-Fe 6.71 3.23 -3.49 -0.232 0.59512E+04 42 celadonite 5.34 3.23 -2.11 -0.124 0.36025E+04 43 celadonite-Fe 3.88 0.87 -3.00 -0.177 0.51279E+04 44 chrysotile 23.89 20.41 -3.49 -0.290 0.59508E+04 50 chloritoid-Mg 13.20 8.84 -4.36 -0.291 0.74438E+04 51 chloritoid-Fe 9.17 6.48 -2.69 -0.180 0.45998E+04 52 chloritoid-Mn 11.40 8.74 -2.66 -0.178 0.45482E+04 54 coesite -2.38 -3.25 -0.88 -0.292 0.14964E+04 61 cristobalite -2.56 -3.25 -0.69 -0.231 0.11817E+04 63 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71234E+04 65 diaspore 2.87 1.56 -1.31 -0.219 0.22432E+04 67 diopside 16.18 14.59 -1.59 -0.159 0.27157E+04 68 hedenbergite 14.21 12.23 -1.98 -0.198 0.33738E+04 75 epidote 24.67 23.79 -0.88 -0.042 0.14955E+04 76 clinozoisite 22.81 19.17 -3.63 -0.165 0.62040E+04 77 epidote-Fe 29.84 28.42 -1.43 -0.074 0.24336E+04 78 fayalite 14.05 9.97 -4.07 -0.582 0.69558E+04 79 ferrosilite 11.15 6.72 -4.43 -0.443 0.75639E+04 83 gibbsite 4.08 1.56 -2.52 -0.360 0.43017E+04 84 glaucophane 22.97 19.64 -3.34 -0.090 0.56949E+04 85 glaucophane-Fe 17.28 12.56 -4.71 -0.127 0.80452E+04 87 greenalite 16.14 13.33 -2.81 -0.234 0.47941E+04 90 hematite 12.57 12.36 -0.20 -0.025 0.34716E+03 91 heulandite -5.83 -7.52 -1.69 -0.077 0.28938E+04 95 jadeite 4.22 2.87 -1.35 -0.135 0.22995E+04 96 julgoldite 70.43 66.94 -3.49 -0.091 0.59612E+04 97 kalsilite 7.58 4.02 -3.57 -0.509 0.60881E+04 98 kaolinite -1.33 -3.38 -2.05 -0.187 0.35041E+04 101 laumontite 2.88 2.24 -0.65 -0.043 0.11068E+04 102 lawsonite 9.62 8.74 -0.88 -0.058 0.14958E+04 103 leucite 4.12 0.77 -3.35 -0.335 0.57250E+04 105 lizardite 23.24 20.41 -2.84 -0.236 0.48434E+04 107 magnetite 20.09 18.98 -1.11 -0.091 0.18993E+04 108 minnesotaite 10.39 6.83 -3.56 -0.209 0.60806E+04 110 magnesioferrite 26.21 21.33 -4.88 -0.398 0.83305E+04 120 muscovite 2.58 0.63 -1.95 -0.115 0.33279E+04 121 paragonite 4.24 2.74 -1.50 -0.088 0.25670E+04 122 nepheline 8.34 6.12 -2.22 -0.317 0.37880E+04 134 phlogopite-Na 29.65 26.53 -3.12 -0.173 0.53248E+04 136 prehnite 19.37 17.61 -1.76 -0.103 0.30038E+04 137 prehnite-Fe 22.50 22.23 -0.26 -0.016 0.45031E+03 138 pumpellyite-Fe 46.27 43.40 -2.87 -0.064 0.49038E+04 139 pumpellyite-Mg 48.99 45.76 -3.24 -0.072 0.55304E+04 145 pyroxmangite 7.40 5.62 -1.78 -0.356 0.30414E+04 146 pyrophyllite -6.18 -9.89 -3.71 -0.232 0.63416E+04 147 quartz -2.99 -3.25 -0.26 -0.088 0.44904E+03 152 rhodonite 7.45 5.62 -1.83 -0.366 0.31216E+04 153 sanidine -1.28 -2.49 -1.21 -0.093 0.20677E+04 165 stilpnomelane-Mg 27.44 24.81 -2.63 -0.079 0.44940E+04 171 talc 16.49 13.90 -2.59 -0.152 0.44201E+04 174 tephroite 18.09 14.49 -3.60 -0.514 0.61442E+04 177 topaz-H 4.62 -0.13 -4.75 -0.432 0.81122E+04 178 tridymite -2.63 -3.25 -0.63 -0.209 0.10690E+04 179 tremolite 47.87 43.08 -4.79 -0.129 0.81705E+04 187 wairakite 3.95 2.24 -1.72 -0.101 0.29287E+04 188 walstromite 11.51 8.87 -2.64 -0.527 0.45020E+04 189 wollastonite 10.46 8.87 -1.59 -0.318 0.27124E+04 190 pseudo-wollastonite 11.00 8.87 -2.13 -0.425 0.36322E+04 191 zoisite 22.85 19.17 -3.68 -0.167 0.62781E+04 192 akaganeite 7.75 6.18 -1.57 -0.340 0.26861E+04 193 beidellite-Ca -1.65 -6.30 -4.66 -0.288 0.79491E+04 195 beidellite-K -1.52 -6.42 -4.90 -0.300 0.83613E+04 197 beidellite-Na -1.34 -5.72 -4.38 -0.268 0.74805E+04 199 chalcedony -2.80 -3.25 -0.45 -0.150 0.76834E+03 201 montmorillonite-Ca -2.29 -5.44 -3.15 -0.195 0.53835E+04 202 montmorillonite-K -2.24 -5.56 -3.32 -0.203 0.56739E+04 203 montmorillonite-Mg -2.48 -5.96 -3.48 -0.216 0.59492E+04 204 montmorillonite-Na -2.04 -4.87 -2.83 -0.173 0.48288E+04 205 nontronite-Ca 3.21 2.94 -0.27 -0.018 0.46555E+03 206 nontronite-H 2.53 0.94 -1.59 -0.107 0.27173E+04 207 nontronite-K 3.34 2.83 -0.51 -0.033 0.87912E+03 208 nontronite-Mg 3.07 2.42 -0.65 -0.042 0.11153E+04 209 nontronite-Na 3.52 3.52 0.00 0.000 0.53079E-11 224 tobermorite 9.82 6.85 -2.98 -0.812 0.50803E+04 233 boehmite 4.41 1.56 -2.85 -0.474 0.48601E+04 235 ferrous-oxide 9.81 6.61 -3.20 -0.800 0.54628E+04 240 silica-amorphous -2.09 -3.25 -1.16 -0.387 0.19825E+04 242 an20ab80 2.02 1.44 -0.58 -0.044 0.98497E+03 243 an25ab75 2.65 1.90 -0.75 -0.058 0.12782E+04 244 an30ab70 3.28 2.35 -0.93 -0.071 0.15810E+04 245 tr.625ac.25prg.125 45.16 41.39 -3.78 -0.102 0.64462E+04 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 8 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 32.9990000 Water: Moles liquid = 0.5528E+02 kg liquid = 0.9959E+00 Moles total = 0.5509E+02 kg total = 0.9925E+00 Activity = 1.0000 Stoichiometric ionic strength = .5532441E-02 Osmotic coef. = 0.9607 True ionic strength = .1007246E-01 Chg. balance for total moles = 0.2995E-12 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.14696E-09 -9.8328 0.12834E-09 -9.8916 0.87329E+00 -0.0588 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13819E-03 -3.8595 0.12027E-03 -3.9198 0.87029E+00 -0.0603 4 SO4-- 0.25590E-04 -4.5919 0.15597E-04 -4.8070 0.60950E+00 -0.2150 5 HCO3- 0.66476E-05 -5.1773 0.57901E-05 -5.2373 0.87101E+00 -0.0600 6 HS- 0.18125E-10 -10.7417 0.15775E-10 -10.8020 0.87036E+00 -0.0603 7 Al+++ 0.22815E-27 -27.6418 0.76006E-28 -28.1192 0.33314E+00 -0.4774 8 H4SiO4 0.55412E-03 -3.2564 0.55412E-03 -3.2564 0.10000E+01 0.0000 9 Ca++ 0.39335E-07 -7.4052 0.23875E-07 -7.6221 0.60697E+00 -0.2168 10 Mg++ 0.25609E-10 -10.5916 0.15503E-10 -10.8096 0.60538E+00 -0.2180 11 Fe++ 0.11300E-12 -12.9469 0.68449E-13 -13.1646 0.60576E+00 -0.2177 12 K+ 0.78564E-04 -4.1048 0.68440E-04 -4.1647 0.87114E+00 -0.0599 13 Na+ 0.99612E-02 -2.0017 0.86683E-02 -2.0621 0.87021E+00 -0.0604 14 Mn++ 0.20282E-10 -10.6929 0.12292E-10 -10.9104 0.60605E+00 -0.2175 15 HPO4-- 0.47688E-06 -6.3216 0.29068E-06 -6.5366 0.60955E+00 -0.2150 16 HSiO3- 0.46324E-02 -2.3342 0.40315E-02 -2.3945 0.87029E+00 -0.0603 17 Ca(HSiO3)+ 0.25160E-08 -8.5993 0.21920E-08 -8.6592 0.87124E+00 -0.0599 18 Mg(HSiO3)+ 0.20332E-11 -11.6918 0.17714E-11 -11.7517 0.87124E+00 -0.0599 19 NaHSiO3,aq 0.56521E-03 -3.2478 0.56521E-03 -3.2478 0.10000E+01 0.0000 20 AlO+ 0.72053E-15 -15.1423 0.62775E-15 -15.2022 0.87124E+00 -0.0599 22 HAlO2,aq 0.97409E-09 -9.0114 0.97409E-09 -9.0114 0.10000E+01 0.0000 23 AlO2- 0.19325E-04 -4.7139 0.16801E-04 -4.7747 0.86938E+00 -0.0608 24 CH4,aq 0.56984E-17 -17.2442 0.56887E-17 -17.2450 0.99830E+00 -0.0007 29 CO,aq 0.14321E-18 -18.8440 0.14321E-18 -18.8440 0.10000E+01 0.0000 30 CO2,aq 0.15906E-08 -8.7984 0.15879E-08 -8.7992 0.99830E+00 -0.0007 31 CO3-2 0.64732E-05 -5.1889 0.39406E-05 -5.4044 0.60876E+00 -0.2156 32 CaCO3,aq 0.11797E-08 -8.9282 0.11797E-08 -8.9282 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.40502E-11 -11.3925 0.35287E-11 -11.4524 0.87124E+00 -0.0599 34 CaCl+ 0.53336E-11 -11.2730 0.46468E-11 -11.3328 0.87124E+00 -0.0599 35 CaCl2,aq 0.13278E-15 -15.8769 0.13278E-15 -15.8769 0.10000E+01 0.0000 36 CaOH+ 0.15217E-07 -7.8177 0.13258E-07 -7.8775 0.87124E+00 -0.0599 37 CaSO4,aq 0.11825E-09 -9.9272 0.11825E-09 -9.9272 0.10000E+01 0.0000 38 HCl,aq 0.28285E-14 -14.5484 0.28285E-14 -14.5484 0.10000E+01 0.0000 43 FeCl+ 0.14956E-16 -16.8252 0.13030E-16 -16.8850 0.87124E+00 -0.0599 46 FeO,aq 0.16151E-09 -9.7918 0.16151E-09 -9.7918 0.10000E+01 0.0000 47 FeOH+ 0.19926E-10 -10.7006 0.17361E-10 -10.7604 0.87124E+00 -0.0599 48 HFeO2- 0.15130E-07 -7.8202 0.13167E-07 -7.8805 0.87029E+00 -0.0603 49 FeO+ 0.79321E-15 -15.1006 0.69108E-15 -15.1605 0.87124E+00 -0.0599 51 FeO2- 0.98646E-08 -8.0059 0.85850E-08 -8.0663 0.87029E+00 -0.0603 52 HFeO2,aq 0.14013E-09 -9.8535 0.14013E-09 -9.8535 0.10000E+01 0.0000 53 H2,aq 0.35964E-08 -8.4441 0.35903E-08 -8.4449 0.99830E+00 -0.0007 54 KCl,aq 0.14918E-09 -9.8263 0.14918E-09 -9.8263 0.10000E+01 0.0000 55 KHSO4,aq 0.38735E-18 -18.4119 0.38735E-18 -18.4119 0.10000E+01 0.0000 56 KOH,aq 0.22773E-06 -6.6426 0.22773E-06 -6.6426 0.10000E+01 0.0000 57 KSO4- 0.19033E-07 -7.7205 0.16564E-07 -7.7808 0.87029E+00 -0.0603 58 MgCO3,aq 0.19201E-12 -12.7167 0.19201E-12 -12.7167 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.26874E-14 -14.5707 0.23414E-14 -14.6305 0.87124E+00 -0.0599 60 MgCl+ 0.31390E-14 -14.5032 0.27348E-14 -14.5631 0.87124E+00 -0.0599 61 MgOH+ 0.54680E-10 -10.2622 0.47639E-10 -10.3220 0.87124E+00 -0.0599 63 MnO,aq 0.77282E-09 -9.1119 0.77282E-09 -9.1119 0.10000E+01 0.0000 64 MnOH+ 0.33242E-09 -9.4783 0.28961E-09 -9.5382 0.87124E+00 -0.0599 65 MnO2-2 0.25578E-11 -11.5921 0.15571E-11 -11.8077 0.60876E+00 -0.2156 66 HMnO2- 0.50308E-10 -10.2984 0.43782E-10 -10.3587 0.87029E+00 -0.0603 69 MnCl+ 0.10449E-13 -13.9809 0.91035E-14 -14.0408 0.87124E+00 -0.0599 70 MnSO4,aq 0.55348E-13 -13.2569 0.55348E-13 -13.2569 0.10000E+01 0.0000 71 NaCl,aq 0.34549E-06 -6.4616 0.34549E-06 -6.4616 0.10000E+01 0.0000 72 NaOH,aq 0.29019E-04 -4.5373 0.29019E-04 -4.5373 0.10000E+01 0.0000 74 OH- 0.51782E-02 -2.2858 0.45018E-02 -2.3466 0.86938E+00 -0.0608 79 HPO3-2 0.53425E-17 -17.2723 0.32523E-17 -17.4878 0.60876E+00 -0.2156 82 H3PO4,aq 0.33487E-16 -16.4751 0.33487E-16 -16.4751 0.10000E+01 0.0000 83 H2PO4- 0.79035E-09 -9.1022 0.68820E-09 -9.1623 0.87076E+00 -0.0601 84 PO4-3 0.53938E-08 -8.2681 0.18479E-08 -8.7333 0.34260E+00 -0.4652 87 H2P2O7-2 0.61004E-19 -19.2146 0.37137E-19 -19.4302 0.60876E+00 -0.2156 88 HP2O7-3 0.17336E-15 -15.7611 0.57779E-16 -16.2382 0.33329E+00 -0.4772 89 P2O7-4 0.73682E-15 -15.1326 0.10755E-15 -15.9684 0.14596E+00 -0.8358 90 H2S,aq 0.62680E-14 -14.2029 0.62574E-14 -14.2036 0.99830E+00 -0.0007 97 SO3-2 0.11856E-13 -13.9261 0.72768E-14 -14.1381 0.61379E+00 -0.2120 98 HSO3- 0.67190E-16 -16.1727 0.58475E-16 -16.2330 0.87029E+00 -0.0603 99 HSO4- 0.22130E-11 -11.6550 0.19291E-11 -11.7146 0.87172E+00 -0.0596 Charge balance for all species = 0.3005E-12 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.1469631E-09 -.1048889E-01 -.1056377E+02 0.0000 2 H2O 0.1000000E+01 0.5550830E+02 0.9992039E+06 0.0000 3 Cl- 0.1381936E-03 0.1385392E-03 0.4907728E+01 5.9718 4 SO4-- 0.2558975E-04 0.2560925E-04 0.2458111E+01 14.9763 5 HCO3- 0.6647587E-05 0.1312353E-04 0.8001244E+00 4.6543 6 HS- 0.1812504E-10 -.3333567E-09 -.1101601E-04 -0.9104 7 Al+++ 0.2281520E-27 0.1932578E-04 0.5210242E+00 1.5557 8 H4SiO4 0.5541230E-03 0.5751697E-02 0.5523873E+03 -3.2564 9 Ca++ 0.3933515E-07 0.5837594E-07 0.2337732E-02 12.1612 10 Mg++ 0.2560927E-10 0.8251984E-10 0.2004628E-05 8.9737 11 Fe++ 0.1129963E-12 0.2531583E-07 0.1412689E-02 6.6186 12 K+ 0.7856359E-04 0.7881051E-04 0.3079199E+01 5.7269 13 Na+ 0.9961206E-02 0.1055578E-01 0.2424823E+03 7.8296 14 Mn++ 0.2028229E-10 0.1178455E-08 0.6469048E-04 8.8729 15 HPO4-- 0.4768787E-06 0.4830628E-06 0.4632704E-01 13.2467 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.5464014E+00 -.1044611E-01 -.5359553E+00 0.0000000E+00 2 H2O 0.5509459E+02 0.5528190E+02 -.1873042E+00 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.9400193E-03 0.2550480E-04 0.9145144E-03 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.9145148E-03 -.3319971E-09 -.9145144E-03 0.0000000E+00 7 Al+++ 0.1076012E+00 0.1924696E-04 0.1075820E+00 0.0000000E+00 8 H4SiO4 0.3436114E+00 0.5728238E-02 0.3378832E+00 0.0000000E+00 9 Ca++ 0.3796803E-01 0.5813785E-07 0.3796797E-01 0.0000000E+00 10 Mg++ 0.2618968E-01 0.8218327E-10 0.2618968E-01 0.0000000E+00 11 Fe++ 0.2352857E-01 0.2521257E-07 0.2352855E-01 0.0000000E+00 12 K+ 0.7006157E-02 0.7848906E-04 0.6927668E-02 0.0000000E+00 13 Na+ 0.4158186E-01 0.1051272E-01 0.3106913E-01 0.0000000E+00 14 Mn++ 0.5721563E-03 0.1173648E-08 0.5721552E-03 0.0000000E+00 15 HPO4-- 0.1952741E-03 0.4810926E-06 0.1947930E-03 0.0000000E+00 Chg. balance for solid moles: -.1108E-15 Mass of aqueous solution: 0.996713E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 32.9990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 0.3107E-01 -1.508 8.147 0.911 22.61 3.127 andradite 0.3658E-02 -2.437 1.859 0.269 5.160 0.4830 grossular 0.1337E-03 -3.874 0.6022E-01 -1.220 0.1671 0.1676E-01 apatite-OH 0.6493E-04 -4.188 0.3262E-01 -1.487 0.9053E-01 0.1036E-01 clinochlore 0.5238E-02 -2.281 2.911 0.464 8.081 1.107 daphnite 0.2426E-02 -2.615 1.731 0.238 4.805 0.5246 chlorite-Mn 0.1144E-03 -3.941 0.8113E-01 -1.091 0.2252 0.2585E-01 microcline 0.6520E-02 -2.186 1.815 0.259 5.037 0.7089 stilbite 0.2627E-01 -1.581 18.51 1.267 51.38 8.634 stilpnomelane-Fe 0.8161E-03 -3.088 0.8798 -0.056 2.442 0.3039 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.9647E+00 0.9647E+00 1.0000 -0.016 grossular 0.3526E-01 0.3526E-01 1.0000 -1.453 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.6734E+00 0.6734E+00 1.0000 -0.172 daphnite 0.3119E+00 0.3119E+00 1.0000 -0.506 chlorite-Mn 0.1471E-01 0.1471E-01 1.0000 -1.832 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 36.028577 g Volume = 14.942313 cm3 Porosity: -5.2305% V(tot) - V(min): -.74271E+00 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 32.9990000 g log = 1.5185 Original solution: 1000.0103000 g Original solution / Rock added: 30.30 (Water/Rock Ratio), log = 1.4815 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0203 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.1000E+01 0.9860 0.1006E+01 0.1020E+01 CO2,gas 0.1653E-06 1.0071 0.1699E-06 0.1687E-06 CH4,gas 0.8105E-14 1.0125 0.8373E-14 0.8270E-14 H2,gas 0.4617E-05 1.0005 0.4714E-05 0.4711E-05 H2S,gas 0.1693E-12 0.9960 0.1720E-12 0.1727E-12 S2,gas 0.4899E-34 1.0000 0.4999E-34 0.4999E-34 CO,gas 0.2092E-15 1.0000 0.2134E-15 0.2134E-15 SO3,gas 0.9520E-40 1.0000 0.9714E-40 0.9714E-40 SO2,gas 0.1746E-22 1.0000 0.1781E-22 0.1781E-22 HCl,gas 0.4892E-17 1.0000 0.4991E-17 0.4991E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 16 albite -0.38 -0.38 0.00 0.000 -0.94784E-12 22 andradite 39.01 39.01 0.00 0.000 -0.12132E-10 23 grossular 32.73 32.73 0.00 0.000 0.00000E+00 32 apatite-OH -18.15 -18.15 0.00 0.000 -0.60662E-11 46 clinochlore 39.07 39.07 0.00 0.000 0.36397E-10 47 daphnite 28.97 28.97 0.00 0.000 -0.42463E-10 48 chlorite-Mn 46.87 46.87 0.00 0.000 -0.12132E-10 116 microcline -2.49 -2.49 0.00 0.000 0.15165E-11 163 stilbite -7.52 -7.52 0.00 0.000 -0.90992E-11 164 stilpnomelane-Fe 13.02 13.02 0.00 0.000 -0.27298E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -15.13 -8.47 -2.823 0.14460E+05 -6.770 3 CH4,gas 4.54 -11.23 -15.78 -3.944 0.26937E+05 -14.077 4 H2,gas 8.00 0.97 -7.03 -4.015 0.11996E+05 -5.327 5 H2S,gas -6.23 -20.69 -14.46 -7.232 0.24696E+05 -12.764 6 S2,gas -7.34 -43.34 -36.00 -5.538 0.61469E+05 -34.301 7 CO,gas 3.21 -14.15 -17.37 -5.345 0.29658E+05 -15.671 8 SO3,gas 17.12 -24.59 -41.71 -10.428 0.71221E+05 -40.013 9 SO2,gas 0.83 -23.62 -24.45 -6.520 0.41745E+05 -22.749 10 HCl,gas 5.19 -13.81 -19.00 -9.500 0.32443E+05 -17.302 11 acmite 7.71 7.45 -0.26 -0.027 0.44629E+03 15 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 19 spessartine 24.46 19.96 -4.50 -0.225 0.76774E+04 20 analcite 3.32 2.87 -0.45 -0.050 0.76723E+03 26 annite 20.12 17.37 -2.75 -0.153 0.47024E+04 27 phlogopite 27.06 24.43 -2.63 -0.146 0.44907E+04 29 anorthite 12.71 8.76 -3.95 -0.304 0.67452E+04 35 aragonite 0.97 -2.97 -3.93 -1.311 0.67176E+04 36 brucite 12.57 8.97 -3.59 -0.719 0.61381E+04 37 calcite 0.81 -2.97 -3.78 -1.260 0.64534E+04 38 carnegieite-low 9.02 6.13 -2.89 -0.413 0.49421E+04 39 carnegieite-high 10.09 6.13 -3.96 -0.566 0.67691E+04 40 carpholite-Mg 8.58 5.57 -3.01 -0.201 0.51390E+04 41 carpholite-Fe 6.71 3.22 -3.50 -0.233 0.59681E+04 42 celadonite 5.34 3.23 -2.11 -0.124 0.36041E+04 43 celadonite-Fe 3.88 0.88 -3.00 -0.177 0.51238E+04 44 chrysotile 23.89 20.41 -3.48 -0.290 0.59490E+04 50 chloritoid-Mg 13.20 8.83 -4.37 -0.291 0.74598E+04 51 chloritoid-Fe 9.17 6.47 -2.70 -0.180 0.46100E+04 52 chloritoid-Mn 11.40 8.73 -2.67 -0.178 0.45642E+04 54 coesite -2.38 -3.26 -0.88 -0.293 0.15031E+04 61 cristobalite -2.56 -3.26 -0.70 -0.232 0.11885E+04 63 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71234E+04 65 diaspore 2.87 1.56 -1.32 -0.220 0.22504E+04 67 diopside 16.18 14.62 -1.56 -0.156 0.26624E+04 68 hedenbergite 14.21 12.27 -1.94 -0.194 0.33146E+04 75 epidote 24.67 23.80 -0.87 -0.042 0.14917E+04 76 clinozoisite 22.81 19.22 -3.59 -0.163 0.61222E+04 77 epidote-Fe 29.84 28.37 -1.47 -0.076 0.25078E+04 78 fayalite 14.05 9.98 -4.06 -0.581 0.69406E+04 79 ferrosilite 11.15 6.72 -4.42 -0.442 0.75555E+04 83 gibbsite 4.08 1.56 -2.52 -0.361 0.43089E+04 84 glaucophane 22.97 19.64 -3.33 -0.090 0.56931E+04 85 glaucophane-Fe 17.28 12.58 -4.70 -0.127 0.80259E+04 87 greenalite 16.14 13.34 -2.80 -0.233 0.47748E+04 90 hematite 12.57 12.26 -0.30 -0.037 0.51747E+03 91 heulandite -5.83 -7.52 -1.69 -0.077 0.28938E+04 95 jadeite 4.22 2.87 -1.34 -0.134 0.22927E+04 96 julgoldite 70.43 66.87 -3.56 -0.092 0.60734E+04 97 kalsilite 7.58 4.03 -3.56 -0.508 0.60745E+04 98 kaolinite -1.33 -3.40 -2.07 -0.188 0.35319E+04 101 laumontite 2.88 2.25 -0.64 -0.042 0.10864E+04 102 lawsonite 9.62 8.76 -0.86 -0.057 0.14619E+04 103 leucite 4.12 0.77 -3.35 -0.335 0.57183E+04 105 lizardite 23.24 20.41 -2.84 -0.236 0.48416E+04 107 magnetite 20.09 18.88 -1.21 -0.098 0.20586E+04 108 minnesotaite 10.39 6.83 -3.56 -0.209 0.60748E+04 110 magnesioferrite 26.21 21.24 -4.98 -0.406 0.84957E+04 120 muscovite 2.58 0.62 -1.96 -0.115 0.33423E+04 121 paragonite 4.24 2.73 -1.51 -0.089 0.25814E+04 122 nepheline 8.34 6.13 -2.21 -0.316 0.37744E+04 134 phlogopite-Na 29.65 26.54 -3.11 -0.173 0.53095E+04 136 prehnite 19.37 17.66 -1.71 -0.100 0.29149E+04 137 prehnite-Fe 22.50 22.24 -0.26 -0.015 0.43936E+03 138 pumpellyite-Fe 46.27 43.50 -2.77 -0.061 0.47222E+04 139 pumpellyite-Mg 48.99 45.86 -3.14 -0.070 0.53546E+04 145 pyroxmangite 7.40 5.62 -1.78 -0.356 0.30430E+04 146 pyrophyllite -6.18 -9.91 -3.74 -0.234 0.63830E+04 147 quartz -2.99 -3.26 -0.27 -0.089 0.45583E+03 152 rhodonite 7.45 5.62 -1.83 -0.366 0.31233E+04 153 sanidine -1.28 -2.49 -1.21 -0.093 0.20677E+04 165 stilpnomelane-Mg 27.44 24.79 -2.65 -0.079 0.45233E+04 171 talc 16.49 13.90 -2.60 -0.153 0.44319E+04 174 tephroite 18.09 14.49 -3.60 -0.514 0.61408E+04 177 topaz-H 4.62 -0.14 -4.76 -0.433 0.81334E+04 178 tridymite -2.63 -3.26 -0.63 -0.210 0.10758E+04 179 tremolite 47.87 43.14 -4.73 -0.128 0.80755E+04 187 wairakite 3.95 2.25 -1.70 -0.100 0.29084E+04 188 walstromite 11.51 8.90 -2.60 -0.521 0.44470E+04 189 wollastonite 10.46 8.90 -1.56 -0.311 0.26574E+04 190 pseudo-wollastonite 11.00 8.90 -2.10 -0.419 0.35772E+04 191 zoisite 22.85 19.22 -3.63 -0.165 0.61963E+04 192 akaganeite 7.75 6.13 -1.62 -0.351 0.27713E+04 193 beidellite-Ca -1.65 -6.32 -4.67 -0.289 0.79805E+04 195 beidellite-K -1.52 -6.44 -4.92 -0.301 0.83939E+04 197 beidellite-Na -1.34 -5.74 -4.40 -0.269 0.75130E+04 199 chalcedony -2.80 -3.26 -0.45 -0.151 0.77512E+03 201 montmorillonite-Ca -2.29 -5.46 -3.17 -0.196 0.54107E+04 202 montmorillonite-K -2.24 -5.58 -3.34 -0.205 0.57022E+04 203 montmorillonite-Mg -2.48 -5.99 -3.51 -0.217 0.59858E+04 204 montmorillonite-Na -2.04 -4.88 -2.84 -0.174 0.48571E+04 205 nontronite-Ca 3.21 2.83 -0.38 -0.025 0.65292E+03 206 nontronite-H 2.53 0.83 -1.71 -0.114 0.29149E+04 207 nontronite-K 3.34 2.72 -0.63 -0.040 0.10676E+04 208 nontronite-Mg 3.07 2.31 -0.77 -0.050 0.13120E+04 209 nontronite-Na 3.52 3.41 -0.11 -0.007 0.18849E+03 224 tobermorite 9.82 6.87 -2.95 -0.805 0.50356E+04 233 boehmite 4.41 1.56 -2.85 -0.475 0.48673E+04 235 ferrous-oxide 9.81 6.62 -3.19 -0.798 0.54519E+04 240 silica-amorphous -2.09 -3.26 -1.17 -0.388 0.19893E+04 242 an20ab80 2.02 1.44 -0.57 -0.044 0.97819E+03 243 an25ab75 2.65 1.90 -0.74 -0.057 0.12697E+04 244 an30ab70 3.28 2.36 -0.92 -0.071 0.15708E+04 245 tr.625ac.25prg.125 45.16 41.45 -3.71 -0.100 0.63421E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 1.0000000 g Current total amount of reactant added: 32.9990000 g New total amount of reactant added: 33.9990000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.2995E-12 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 8 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 33.9990000 Water: Moles liquid = 0.5528E+02 kg liquid = 0.9958E+00 Moles total = 0.5508E+02 kg total = 0.9923E+00 Activity = 1.0000 Stoichiometric ionic strength = .5658956E-02 Osmotic coef. = 0.9603 True ionic strength = .1030302E-01 Chg. balance for total moles = 0.2995E-12 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.14403E-09 -9.8416 0.12563E-09 -9.9009 0.87230E+00 -0.0593 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13820E-03 -3.8595 0.12013E-03 -3.9203 0.86924E+00 -0.0609 4 SO4-- 0.25592E-04 -4.5919 0.15526E-04 -4.8089 0.60665E+00 -0.2171 5 HCO3- 0.65669E-05 -5.1826 0.57130E-05 -5.2431 0.86998E+00 -0.0605 6 HS- 0.55861E-10 -10.2529 0.48561E-10 -10.3137 0.86932E+00 -0.0608 7 Al+++ 0.20628E-27 -27.6855 0.67990E-28 -28.1676 0.32960E+00 -0.4820 8 H4SiO4 0.55498E-03 -3.2557 0.55498E-03 -3.2557 0.10000E+01 0.0000 9 Ca++ 0.41196E-07 -7.3851 0.24885E-07 -7.6041 0.60408E+00 -0.2189 10 Mg++ 0.25174E-10 -10.5990 0.15167E-10 -10.8191 0.60247E+00 -0.2201 11 Fe++ 0.11014E-12 -12.9581 0.66397E-13 -13.1778 0.60286E+00 -0.2198 12 K+ 0.80366E-04 -4.0949 0.69927E-04 -4.1554 0.87011E+00 -0.0604 13 Na+ 0.10190E-01 -1.9918 0.88567E-02 -2.0527 0.86916E+00 -0.0609 14 Mn++ 0.19937E-10 -10.7003 0.12025E-10 -10.9199 0.60315E+00 -0.2196 15 HPO4-- 0.43461E-06 -6.3619 0.26368E-06 -6.5789 0.60670E+00 -0.2170 16 HSiO3- 0.47453E-02 -2.3237 0.41248E-02 -2.3846 0.86924E+00 -0.0609 17 Ca(HSiO3)+ 0.26863E-08 -8.5708 0.23376E-08 -8.6312 0.87021E+00 -0.0604 18 Mg(HSiO3)+ 0.20375E-11 -11.6909 0.17731E-11 -11.7513 0.87021E+00 -0.0604 19 NaHSiO3,aq 0.59085E-03 -3.2285 0.59085E-03 -3.2285 0.10000E+01 0.0000 20 AlO+ 0.67342E-15 -15.1717 0.58602E-15 -15.2321 0.87021E+00 -0.0604 22 HAlO2,aq 0.92893E-09 -9.0320 0.92893E-09 -9.0320 0.10000E+01 0.0000 23 AlO2- 0.18849E-04 -4.7247 0.16367E-04 -4.7860 0.86832E+00 -0.0613 24 CH4,aq 0.17388E-16 -16.7598 0.17358E-16 -16.7605 0.99826E+00 -0.0008 29 CO,aq 0.18441E-18 -18.7342 0.18441E-18 -18.7342 0.10000E+01 0.0000 30 CO2,aq 0.15363E-08 -8.8135 0.15337E-08 -8.8143 0.99826E+00 -0.0008 31 CO3-2 0.65555E-05 -5.1834 0.39720E-05 -5.4010 0.60590E+00 -0.2176 32 CaCO3,aq 0.12394E-08 -8.9068 0.12394E-08 -8.9068 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.41703E-11 -11.3798 0.36291E-11 -11.4402 0.87021E+00 -0.0604 34 CaCl+ 0.55595E-11 -11.2550 0.48380E-11 -11.3153 0.87021E+00 -0.0604 35 CaCl2,aq 0.13808E-15 -15.8599 0.13808E-15 -15.8599 0.10000E+01 0.0000 36 CaOH+ 0.16222E-07 -7.7899 0.14117E-07 -7.8503 0.87021E+00 -0.0604 37 CaSO4,aq 0.12269E-09 -9.9112 0.12269E-09 -9.9112 0.10000E+01 0.0000 38 HCl,aq 0.27656E-14 -14.5582 0.27656E-14 -14.5582 0.10000E+01 0.0000 43 FeCl+ 0.14508E-16 -16.8384 0.12625E-16 -16.8988 0.87021E+00 -0.0604 46 FeO,aq 0.16350E-09 -9.7865 0.16350E-09 -9.7865 0.10000E+01 0.0000 47 FeOH+ 0.19769E-10 -10.7040 0.17203E-10 -10.7644 0.87021E+00 -0.0604 48 HFeO2- 0.15665E-07 -7.8051 0.13616E-07 -7.8659 0.86924E+00 -0.0609 49 FeO+ 0.68156E-15 -15.1665 0.59310E-15 -15.2269 0.87021E+00 -0.0604 51 FeO2- 0.88456E-08 -8.0533 0.76890E-08 -8.1141 0.86924E+00 -0.0609 52 HFeO2,aq 0.12286E-09 -9.9106 0.12286E-09 -9.9106 0.10000E+01 0.0000 53 H2,aq 0.47948E-08 -8.3192 0.47865E-08 -8.3200 0.99826E+00 -0.0008 54 KCl,aq 0.15225E-09 -9.8174 0.15225E-09 -9.8174 0.10000E+01 0.0000 55 KHSO4,aq 0.38564E-18 -18.4138 0.38564E-18 -18.4138 0.10000E+01 0.0000 56 KOH,aq 0.23770E-06 -6.6240 0.23770E-06 -6.6240 0.10000E+01 0.0000 57 KSO4- 0.19381E-07 -7.7126 0.16847E-07 -7.7735 0.86924E+00 -0.0609 58 MgCO3,aq 0.18934E-12 -12.7228 0.18934E-12 -12.7228 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.25971E-14 -14.5855 0.22600E-14 -14.6459 0.87021E+00 -0.0604 60 MgCl+ 0.30710E-14 -14.5127 0.26724E-14 -14.5731 0.87021E+00 -0.0604 61 MgOH+ 0.54709E-10 -10.2619 0.47609E-10 -10.3223 0.87021E+00 -0.0604 63 MnO,aq 0.78898E-09 -9.1029 0.78898E-09 -9.1029 0.10000E+01 0.0000 64 MnOH+ 0.33260E-09 -9.4781 0.28943E-09 -9.5385 0.87021E+00 -0.0604 65 MnO2-2 0.27380E-11 -11.5626 0.16589E-11 -11.7802 0.60590E+00 -0.2176 66 HMnO2- 0.52529E-10 -10.2796 0.45661E-10 -10.3405 0.86924E+00 -0.0609 69 MnCl+ 0.10222E-13 -13.9904 0.88956E-14 -14.0508 0.87021E+00 -0.0604 70 MnSO4,aq 0.53898E-13 -13.2684 0.53898E-13 -13.2684 0.10000E+01 0.0000 71 NaCl,aq 0.35260E-06 -6.4527 0.35260E-06 -6.4527 0.10000E+01 0.0000 72 NaOH,aq 0.30289E-04 -4.5187 0.30289E-04 -4.5187 0.10000E+01 0.0000 74 OH- 0.52963E-02 -2.2760 0.45989E-02 -2.3373 0.86832E+00 -0.0613 79 HPO3-2 0.64912E-17 -17.1877 0.39331E-17 -17.4053 0.60590E+00 -0.2176 82 H3PO4,aq 0.29107E-16 -16.5360 0.29107E-16 -16.5360 0.10000E+01 0.0000 83 H2PO4- 0.70263E-09 -9.1533 0.61109E-09 -9.2139 0.86972E+00 -0.0606 84 PO4-3 0.50491E-08 -8.2968 0.17124E-08 -8.7664 0.33914E+00 -0.4696 87 H2P2O7-2 0.48327E-19 -19.3158 0.29281E-19 -19.5334 0.60590E+00 -0.2176 88 HP2O7-3 0.14113E-15 -15.8504 0.46538E-16 -16.3322 0.32975E+00 -0.4818 89 P2O7-4 0.61771E-15 -15.2092 0.88494E-16 -16.0531 0.14326E+00 -0.8439 90 H2S,aq 0.18888E-13 -13.7238 0.18855E-13 -13.7246 0.99826E+00 -0.0008 97 SO3-2 0.15805E-13 -13.8012 0.96570E-14 -14.0152 0.61100E+00 -0.2140 98 HSO3- 0.87391E-16 -16.0585 0.75964E-16 -16.1194 0.86924E+00 -0.0609 99 HSO4- 0.21589E-11 -11.6658 0.18798E-11 -11.7259 0.87070E+00 -0.0601 Charge balance for all species = 0.3007E-12 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.1440256E-09 -.1074497E-01 -.1082147E+02 0.0000 2 H2O 0.1000000E+01 0.5550828E+02 0.9991848E+06 0.0000 3 Cl- 0.1382030E-03 0.1385558E-03 0.4908221E+01 5.9806 4 SO4-- 0.2559241E-04 0.2561184E-04 0.2458313E+01 14.9928 5 HCO3- 0.6566858E-05 0.1312509E-04 0.8002049E+00 4.6578 6 HS- 0.5586064E-10 0.1335295E-09 0.4412496E-05 -0.4128 7 Al+++ 0.2062839E-27 0.1885015E-04 0.5081916E+00 1.5351 8 H4SiO4 0.5549815E-03 0.5891087E-02 0.5657636E+03 -3.2557 9 Ca++ 0.4119553E-07 0.6147609E-07 0.2461835E-02 12.1977 10 Mg++ 0.2517391E-10 0.8211568E-10 0.1994772E-05 8.9827 11 Fe++ 0.1101381E-12 0.2481652E-07 0.1384801E-02 6.6239 12 K+ 0.8036572E-04 0.8062295E-04 0.3149954E+01 5.7455 13 Na+ 0.1018991E-01 0.1081140E-01 0.2483498E+03 7.8482 14 Mn++ 0.1993708E-10 0.1196847E-08 0.6569889E-04 8.8819 15 HPO4-- 0.4346052E-06 0.4403570E-06 0.4223064E-01 13.2229 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.5629599E+00 -.1069987E-01 -.5522601E+00 0.0000000E+00 2 H2O 0.5508206E+02 0.5527529E+02 -.1932297E+00 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.9677327E-03 0.2550434E-04 0.9422283E-03 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.9422282E-03 0.1329690E-09 -.9422283E-03 0.0000000E+00 7 Al+++ 0.1108620E+00 0.1877103E-04 0.1108432E+00 0.0000000E+00 8 H4SiO4 0.3540242E+00 0.5866360E-02 0.3481578E+00 0.0000000E+00 9 Ca++ 0.3911817E-01 0.6121806E-07 0.3911811E-01 0.0000000E+00 10 Mg++ 0.2698333E-01 0.8177100E-10 0.2698333E-01 0.0000000E+00 11 Fe++ 0.2424158E-01 0.2471236E-07 0.2424155E-01 0.0000000E+00 12 K+ 0.7218471E-02 0.8028455E-04 0.7138187E-02 0.0000000E+00 13 Na+ 0.4283710E-01 0.1076602E-01 0.3207107E-01 0.0000000E+00 14 Mn++ 0.5894949E-03 0.1191823E-08 0.5894937E-03 0.0000000E+00 15 HPO4-- 0.2011917E-03 0.4385086E-06 0.2007532E-03 0.0000000E+00 Chg. balance for solid moles: -.7589E-18 Mass of aqueous solution: 0.996613E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 33.9990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 0.3207E-01 -1.494 8.410 0.925 22.65 3.228 andradite 0.3769E-02 -2.424 1.915 0.282 5.160 0.4976 grossular 0.1498E-03 -3.824 0.6749E-01 -1.171 0.1818 0.1878E-01 apatite-OH 0.6692E-04 -4.174 0.3361E-01 -1.473 0.9055E-01 0.1068E-01 clinochlore 0.5397E-02 -2.268 3.000 0.477 8.081 1.141 daphnite 0.2479E-02 -2.606 1.769 0.248 4.765 0.5360 chlorite-Mn 0.1179E-03 -3.928 0.8359E-01 -1.078 0.2252 0.2664E-01 microcline 0.6707E-02 -2.173 1.867 0.271 5.029 0.7293 stilbite 0.2703E-01 -1.568 19.05 1.280 51.31 8.884 stilpnomelane-Fe 0.8619E-03 -3.065 0.9292 -0.032 2.503 0.3210 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.9618E+00 0.9618E+00 1.0000 -0.017 grossular 0.3823E-01 0.3823E-01 1.0000 -1.418 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.6751E+00 0.6751E+00 1.0000 -0.171 daphnite 0.3101E+00 0.3101E+00 1.0000 -0.508 chlorite-Mn 0.1475E-01 0.1475E-01 1.0000 -1.831 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 37.120664 g Volume = 15.392838 cm3 Porosity: -5.4333% V(tot) - V(min): -.79324E+00 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 33.9990000 g log = 1.5315 Original solution: 1000.0103000 g Original solution / Rock added: 29.41 (Water/Rock Ratio), log = 1.4685 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0203 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.1000E+01 0.9860 0.1006E+01 0.1020E+01 CO2,gas 0.1597E-06 1.0071 0.1641E-06 0.1629E-06 CH4,gas 0.2473E-13 1.0125 0.2555E-13 0.2523E-13 H2,gas 0.6156E-05 1.0005 0.6284E-05 0.6281E-05 H2S,gas 0.5100E-12 0.9960 0.5183E-12 0.5204E-12 S2,gas 0.2503E-33 1.0000 0.2554E-33 0.2554E-33 CO,gas 0.2693E-15 1.0000 0.2748E-15 0.2748E-15 SO3,gas 0.9081E-40 1.0000 0.9266E-40 0.9266E-40 SO2,gas 0.2220E-22 1.0000 0.2265E-22 0.2265E-22 HCl,gas 0.4783E-17 1.0000 0.4880E-17 0.4880E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 16 albite -0.38 -0.38 0.00 0.000 -0.94784E-12 22 andradite 39.01 39.01 0.00 0.000 -0.12132E-10 23 grossular 32.73 32.73 0.00 0.000 0.12132E-10 32 apatite-OH -18.15 -18.15 0.00 0.000 0.00000E+00 46 clinochlore 39.07 39.07 0.00 0.000 0.24265E-10 47 daphnite 28.97 28.97 0.00 0.000 -0.18198E-10 48 chlorite-Mn 46.87 46.87 0.00 0.000 -0.12132E-10 116 microcline -2.49 -2.49 0.00 0.000 0.15165E-11 163 stilbite -7.52 -7.52 0.00 0.000 -0.90992E-11 164 stilpnomelane-Fe 13.02 13.02 0.00 0.000 0.21232E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -15.14 -8.48 -2.828 0.14486E+05 -6.785 3 CH4,gas 4.54 -10.75 -15.29 -3.823 0.26110E+05 -13.593 4 H2,gas 8.00 1.10 -6.90 -3.943 0.11783E+05 -5.202 5 H2S,gas -6.23 -20.21 -13.98 -6.992 0.23878E+05 -12.285 6 S2,gas -7.34 -42.63 -35.29 -5.430 0.60260E+05 -33.593 7 CO,gas 3.21 -14.04 -17.26 -5.311 0.29471E+05 -15.561 8 SO3,gas 17.12 -24.61 -41.73 -10.433 0.71256E+05 -40.033 9 SO2,gas 0.83 -23.51 -24.34 -6.492 0.41566E+05 -22.645 10 HCl,gas 5.19 -13.82 -19.01 -9.505 0.32460E+05 -17.312 11 acmite 7.71 7.41 -0.30 -0.031 0.50979E+03 15 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 19 spessartine 24.46 19.95 -4.51 -0.225 0.76983E+04 20 analcite 3.32 2.87 -0.45 -0.050 0.76837E+03 26 annite 20.12 17.39 -2.74 -0.152 0.46752E+04 27 phlogopite 27.06 24.46 -2.60 -0.145 0.44446E+04 29 anorthite 12.71 8.76 -3.95 -0.304 0.67509E+04 35 aragonite 0.97 -2.95 -3.91 -1.304 0.66810E+04 36 brucite 12.57 8.98 -3.59 -0.717 0.61228E+04 37 calcite 0.81 -2.95 -3.76 -1.253 0.64168E+04 38 carnegieite-low 9.02 6.13 -2.90 -0.414 0.49444E+04 39 carnegieite-high 10.09 6.13 -3.97 -0.567 0.67714E+04 40 carpholite-Mg 8.58 5.54 -3.04 -0.203 0.51917E+04 41 carpholite-Fe 6.71 3.18 -3.53 -0.235 0.60272E+04 42 celadonite 5.34 3.24 -2.10 -0.124 0.35876E+04 43 celadonite-Fe 3.88 0.88 -2.99 -0.176 0.51135E+04 44 chrysotile 23.89 20.44 -3.46 -0.288 0.59007E+04 50 chloritoid-Mg 13.20 8.80 -4.40 -0.293 0.75137E+04 51 chloritoid-Fe 9.17 6.44 -2.74 -0.182 0.46702E+04 52 chloritoid-Mn 11.40 8.70 -2.70 -0.180 0.46181E+04 54 coesite -2.38 -3.26 -0.88 -0.293 0.15020E+04 61 cristobalite -2.56 -3.26 -0.70 -0.232 0.11873E+04 63 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71234E+04 65 diaspore 2.87 1.54 -1.34 -0.223 0.22856E+04 67 diopside 16.18 14.67 -1.51 -0.151 0.25824E+04 68 hedenbergite 14.21 12.31 -1.90 -0.190 0.32409E+04 75 epidote 24.67 23.77 -0.90 -0.043 0.15315E+04 76 clinozoisite 22.81 19.23 -3.57 -0.162 0.60997E+04 77 epidote-Fe 29.84 28.31 -1.53 -0.079 0.26099E+04 78 fayalite 14.05 9.99 -4.05 -0.579 0.69214E+04 79 ferrosilite 11.15 6.74 -4.41 -0.441 0.75351E+04 83 gibbsite 4.08 1.54 -2.54 -0.363 0.43441E+04 84 glaucophane 22.97 19.67 -3.31 -0.089 0.56448E+04 85 glaucophane-Fe 17.28 12.59 -4.68 -0.127 0.79964E+04 87 greenalite 16.14 13.36 -2.78 -0.232 0.47453E+04 90 hematite 12.57 12.15 -0.42 -0.051 0.71258E+03 91 heulandite -5.83 -7.52 -1.69 -0.077 0.28938E+04 95 jadeite 4.22 2.87 -1.34 -0.134 0.22939E+04 96 julgoldite 70.43 66.80 -3.62 -0.094 0.61891E+04 97 kalsilite 7.58 4.02 -3.56 -0.508 0.60768E+04 98 kaolinite -1.33 -3.44 -2.11 -0.192 0.36001E+04 101 laumontite 2.88 2.25 -0.64 -0.043 0.10899E+04 102 lawsonite 9.62 8.76 -0.86 -0.057 0.14676E+04 103 leucite 4.12 0.77 -3.35 -0.335 0.57194E+04 105 lizardite 23.24 20.44 -2.81 -0.234 0.47933E+04 107 magnetite 20.09 18.77 -1.31 -0.107 0.22446E+04 108 minnesotaite 10.39 6.85 -3.54 -0.208 0.60430E+04 120 muscovite 2.58 0.58 -2.00 -0.118 0.34127E+04 121 paragonite 4.24 2.69 -1.55 -0.091 0.26518E+04 122 nepheline 8.34 6.13 -2.21 -0.316 0.37767E+04 134 phlogopite-Na 29.65 26.56 -3.08 -0.171 0.52635E+04 136 prehnite 19.37 17.70 -1.67 -0.098 0.28571E+04 137 prehnite-Fe 22.50 22.24 -0.26 -0.016 0.44395E+03 138 pumpellyite-Fe 46.27 43.56 -2.71 -0.060 0.46327E+04 139 pumpellyite-Mg 48.99 45.91 -3.08 -0.068 0.52589E+04 145 pyroxmangite 7.40 5.63 -1.77 -0.355 0.30265E+04 146 pyrophyllite -6.18 -9.95 -3.78 -0.236 0.64488E+04 147 quartz -2.99 -3.26 -0.27 -0.089 0.45468E+03 152 rhodonite 7.45 5.63 -1.82 -0.364 0.31068E+04 153 sanidine -1.28 -2.49 -1.21 -0.093 0.20677E+04 165 stilpnomelane-Mg 27.44 24.81 -2.63 -0.079 0.44919E+04 171 talc 16.49 13.93 -2.57 -0.151 0.43812E+04 174 tephroite 18.09 14.51 -3.58 -0.511 0.61089E+04 177 topaz-H 4.62 -0.19 -4.80 -0.437 0.82026E+04 178 tridymite -2.63 -3.26 -0.63 -0.210 0.10747E+04 179 tremolite 47.87 43.26 -4.61 -0.124 0.78649E+04 187 wairakite 3.95 2.25 -1.71 -0.100 0.29118E+04 188 walstromite 11.51 8.94 -2.57 -0.513 0.43834E+04 189 wollastonite 10.46 8.94 -1.52 -0.304 0.25939E+04 190 pseudo-wollastonite 11.00 8.94 -2.06 -0.412 0.35137E+04 191 zoisite 22.85 19.23 -3.62 -0.164 0.61737E+04 192 akaganeite 7.75 6.07 -1.68 -0.363 0.28688E+04 193 beidellite-Ca -1.65 -6.36 -4.71 -0.292 0.80480E+04 195 beidellite-K -1.52 -6.48 -4.96 -0.303 0.84612E+04 197 beidellite-Na -1.34 -5.78 -4.44 -0.272 0.75803E+04 199 chalcedony -2.80 -3.26 -0.45 -0.151 0.77397E+03 201 montmorillonite-Ca -2.29 -5.48 -3.19 -0.197 0.54495E+04 202 montmorillonite-K -2.24 -5.60 -3.36 -0.206 0.57408E+04 203 montmorillonite-Mg -2.48 -6.01 -3.53 -0.219 0.60324E+04 204 montmorillonite-Na -2.04 -4.91 -2.87 -0.176 0.48957E+04 205 nontronite-Ca 3.21 2.72 -0.49 -0.032 0.84514E+03 206 nontronite-H 2.53 0.71 -1.83 -0.122 0.31174E+04 207 nontronite-K 3.34 2.60 -0.74 -0.047 0.12596E+04 208 nontronite-Mg 3.07 2.19 -0.89 -0.057 0.15120E+04 209 nontronite-Na 3.52 3.30 -0.22 -0.014 0.38052E+03 224 tobermorite 9.82 6.90 -2.92 -0.796 0.49825E+04 233 boehmite 4.41 1.54 -2.87 -0.479 0.49025E+04 235 ferrous-oxide 9.81 6.62 -3.19 -0.797 0.54428E+04 240 silica-amorphous -2.09 -3.26 -1.16 -0.388 0.19882E+04 242 an20ab80 2.02 1.44 -0.57 -0.044 0.97934E+03 243 an25ab75 2.65 1.90 -0.74 -0.057 0.12711E+04 244 an30ab70 3.28 2.36 -0.92 -0.071 0.15726E+04 245 tr.625ac.25prg.125 45.16 41.56 -3.60 -0.097 0.61508E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 1.0000000 g Current total amount of reactant added: 33.9990000 g New total amount of reactant added: 34.9990000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.2995E-12 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 8 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 34.9990000 Water: Moles liquid = 0.5527E+02 kg liquid = 0.9957E+00 Moles total = 0.5507E+02 kg total = 0.9921E+00 Activity = 1.0000 Stoichiometric ionic strength = .5783241E-02 Osmotic coef. = 0.9599 True ionic strength = .1052889E-01 Chg. balance for total moles = 0.2995E-12 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.14130E-09 -9.8499 0.12312E-09 -9.9097 0.87134E+00 -0.0598 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13821E-03 -3.8595 0.12000E-03 -3.9208 0.86823E+00 -0.0614 4 SO4-- 0.25595E-04 -4.5918 0.15457E-04 -4.8109 0.60391E+00 -0.2190 5 HCO3- 0.64901E-05 -5.1877 0.56398E-05 -5.2487 0.86898E+00 -0.0610 6 HS- 0.16341E-09 -9.7867 0.14189E-09 -9.8480 0.86831E+00 -0.0613 7 Al+++ 0.18726E-27 -27.7276 0.61086E-28 -28.2141 0.32621E+00 -0.4865 8 H4SiO4 0.55601E-03 -3.2549 0.55601E-03 -3.2549 0.10000E+01 0.0000 9 Ca++ 0.43045E-07 -7.3661 0.25883E-07 -7.5870 0.60130E+00 -0.2209 10 Mg++ 0.24781E-10 -10.6059 0.14861E-10 -10.8280 0.59967E+00 -0.2221 11 Fe++ 0.10749E-12 -12.9686 0.64502E-13 -13.1904 0.60006E+00 -0.2218 12 K+ 0.82131E-04 -4.0855 0.71381E-04 -4.1464 0.86911E+00 -0.0609 13 Na+ 0.10414E-01 -1.9824 0.90409E-02 -2.0438 0.86815E+00 -0.0614 14 Mn++ 0.19626E-10 -10.7072 0.11783E-10 -10.9288 0.60036E+00 -0.2216 15 HPO4-- 0.39800E-06 -6.4001 0.24038E-06 -6.6191 0.60396E+00 -0.2190 16 HSiO3- 0.48569E-02 -2.3136 0.42169E-02 -2.3750 0.86823E+00 -0.0614 17 Ca(HSiO3)+ 0.28597E-08 -8.5437 0.24857E-08 -8.6046 0.86922E+00 -0.0609 18 Mg(HSiO3)+ 0.20433E-11 -11.6897 0.17761E-11 -11.7505 0.86922E+00 -0.0609 19 NaHSiO3,aq 0.61661E-03 -3.2100 0.61661E-03 -3.2100 0.10000E+01 0.0000 20 AlO+ 0.63074E-15 -15.2001 0.54825E-15 -15.2610 0.86922E+00 -0.0609 22 HAlO2,aq 0.88683E-09 -9.0522 0.88683E-09 -9.0522 0.10000E+01 0.0000 23 AlO2- 0.18384E-04 -4.7356 0.15945E-04 -4.7974 0.86730E+00 -0.0618 24 CH4,aq 0.50379E-16 -16.2978 0.50289E-16 -16.2985 0.99822E+00 -0.0008 29 CO,aq 0.23468E-18 -18.6295 0.23468E-18 -18.6295 0.10000E+01 0.0000 30 CO2,aq 0.14863E-08 -8.8279 0.14837E-08 -8.8287 0.99822E+00 -0.0008 31 CO3-2 0.66338E-05 -5.1782 0.40012E-05 -5.3978 0.60315E+00 -0.2196 32 CaCO3,aq 0.12986E-08 -8.8865 0.12986E-08 -8.8865 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.42868E-11 -11.3679 0.37262E-11 -11.4287 0.86922E+00 -0.0609 34 CaCl+ 0.57828E-11 -11.2379 0.50265E-11 -11.2987 0.86922E+00 -0.0609 35 CaCl2,aq 0.14330E-15 -15.8437 0.14330E-15 -15.8437 0.10000E+01 0.0000 36 CaOH+ 0.17238E-07 -7.7635 0.14983E-07 -7.8244 0.86922E+00 -0.0609 37 CaSO4,aq 0.12704E-09 -9.8960 0.12704E-09 -9.8960 0.10000E+01 0.0000 38 HCl,aq 0.27073E-14 -14.5675 0.27073E-14 -14.5675 0.10000E+01 0.0000 43 FeCl+ 0.14095E-16 -16.8509 0.12252E-16 -16.9118 0.86922E+00 -0.0609 46 FeO,aq 0.16539E-09 -9.7815 0.16539E-09 -9.7815 0.10000E+01 0.0000 47 FeOH+ 0.19620E-10 -10.7073 0.17054E-10 -10.7682 0.86922E+00 -0.0609 48 HFeO2- 0.16189E-07 -7.7908 0.14055E-07 -7.8522 0.86823E+00 -0.0614 49 FeO+ 0.58974E-15 -15.2293 0.51261E-15 -15.2902 0.86922E+00 -0.0609 51 FeO2- 0.79702E-08 -8.0985 0.69200E-08 -8.1599 0.86823E+00 -0.0614 52 HFeO2,aq 0.10836E-09 -9.9651 0.10836E-09 -9.9651 0.10000E+01 0.0000 53 H2,aq 0.63079E-08 -8.2001 0.62966E-08 -8.2009 0.99822E+00 -0.0008 54 KCl,aq 0.15525E-09 -9.8090 0.15525E-09 -9.8090 0.10000E+01 0.0000 55 KHSO4,aq 0.38407E-18 -18.4156 0.38407E-18 -18.4156 0.10000E+01 0.0000 56 KOH,aq 0.24760E-06 -6.6062 0.24760E-06 -6.6062 0.10000E+01 0.0000 57 KSO4- 0.19720E-07 -7.7051 0.17121E-07 -7.7665 0.86823E+00 -0.0614 58 MgCO3,aq 0.18688E-12 -12.7284 0.18688E-12 -12.7284 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.25149E-14 -14.5995 0.21860E-14 -14.6603 0.86922E+00 -0.0609 60 MgCl+ 0.30092E-14 -14.5215 0.26157E-14 -14.5824 0.86922E+00 -0.0609 61 MgOH+ 0.54764E-10 -10.2615 0.47602E-10 -10.3224 0.86922E+00 -0.0609 63 MnO,aq 0.80500E-09 -9.0942 0.80500E-09 -9.0942 0.10000E+01 0.0000 64 MnOH+ 0.33293E-09 -9.4776 0.28939E-09 -9.5385 0.86922E+00 -0.0609 65 MnO2-2 0.29222E-11 -11.5343 0.17625E-11 -11.7539 0.60315E+00 -0.2196 66 HMnO2- 0.54755E-10 -10.2616 0.47540E-10 -10.3229 0.86823E+00 -0.0614 69 MnCl+ 0.10017E-13 -13.9993 0.87067E-14 -14.0601 0.86922E+00 -0.0609 70 MnSO4,aq 0.52578E-13 -13.2792 0.52578E-13 -13.2792 0.10000E+01 0.0000 71 NaCl,aq 0.35954E-06 -6.4443 0.35954E-06 -6.4443 0.10000E+01 0.0000 72 NaOH,aq 0.31551E-04 -4.5010 0.31551E-04 -4.5010 0.10000E+01 0.0000 74 OH- 0.54109E-02 -2.2667 0.46929E-02 -2.3286 0.86730E+00 -0.0618 79 HPO3-2 0.78203E-17 -17.1068 0.47168E-17 -17.3264 0.60315E+00 -0.2196 82 H3PO4,aq 0.25483E-16 -16.5937 0.25483E-16 -16.5937 0.10000E+01 0.0000 83 H2PO4- 0.62844E-09 -9.2017 0.54594E-09 -9.2629 0.86872E+00 -0.0611 84 PO4-3 0.47434E-08 -8.3239 0.15930E-08 -8.7978 0.33583E+00 -0.4739 87 H2P2O7-2 0.38747E-19 -19.4118 0.23370E-19 -19.6313 0.60315E+00 -0.2196 88 HP2O7-3 0.11614E-15 -15.9350 0.37903E-16 -16.4213 0.32637E+00 -0.4863 89 P2O7-4 0.52272E-15 -15.2817 0.73547E-16 -16.1334 0.14070E+00 -0.8517 90 H2S,aq 0.54086E-13 -13.2669 0.53990E-13 -13.2677 0.99822E+00 -0.0008 97 SO3-2 0.20791E-13 -13.6821 0.12648E-13 -13.8980 0.60832E+00 -0.2159 98 HSO3- 0.11229E-15 -15.9496 0.97497E-16 -16.0110 0.86823E+00 -0.0614 99 HSO4- 0.21087E-11 -11.6760 0.18340E-11 -11.7366 0.86971E+00 -0.0606 101 S2O3-2 0.16253E-19 -19.7891 0.98031E-20 -20.0086 0.60315E+00 -0.2196 Charge balance for all species = 0.3012E-12 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.1412955E-09 -.1099649E-01 -.1107458E+02 0.0000 2 H2O 0.1000000E+01 0.5550826E+02 0.9991660E+06 0.0000 3 Cl- 0.1382125E-03 0.1385722E-03 0.4908714E+01 5.9889 4 SO4-- 0.2559501E-04 0.2561429E-04 0.2458503E+01 15.0085 5 HCO3- 0.6490081E-05 0.1312665E-04 0.8002852E+00 4.6609 6 HS- 0.1634098E-09 0.7306194E-09 0.2414294E-04 0.0616 7 Al+++ 0.1872588E-27 0.1838527E-04 0.4956495E+00 1.5150 8 H4SiO4 0.5560119E-03 0.6029501E-02 0.5790458E+03 -3.2549 9 Ca++ 0.4304528E-07 0.6457818E-07 0.2586011E-02 12.2324 10 Mg++ 0.2478138E-10 0.8178139E-10 0.1986615E-05 8.9914 11 Fe++ 0.1074917E-12 0.2445228E-07 0.1364451E-02 6.6289 12 K+ 0.8213111E-04 0.8239859E-04 0.3219269E+01 5.7633 13 Na+ 0.1041396E-01 0.1106249E-01 0.2541128E+03 7.8659 14 Mn++ 0.1962580E-10 0.1215296E-08 0.6671038E-04 8.8906 15 HPO4-- 0.3980014E-06 0.4033732E-06 0.3868315E-01 13.2003 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.5795184E+00 -.1094903E-01 -.5685694E+00 0.0000000E+00 2 H2O 0.5506952E+02 0.5526870E+02 -.1991725E+00 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.9954461E-03 0.2550374E-04 0.9699423E-03 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.9699416E-03 0.7274662E-09 -.9699423E-03 0.0000000E+00 7 Al+++ 0.1141227E+00 0.1830592E-04 0.1141044E+00 0.0000000E+00 8 H4SiO4 0.3644370E+00 0.6003479E-02 0.3584335E+00 0.0000000E+00 9 Ca++ 0.4026831E-01 0.6429948E-07 0.4026825E-01 0.0000000E+00 10 Mg++ 0.2777698E-01 0.8142844E-10 0.2777698E-01 0.0000000E+00 11 Fe++ 0.2495459E-01 0.2434675E-07 0.2495456E-01 0.0000000E+00 12 K+ 0.7430786E-02 0.8204298E-04 0.7348743E-02 0.0000000E+00 13 Na+ 0.4409234E-01 0.1101474E-01 0.3307760E-01 0.0000000E+00 14 Mn++ 0.6068335E-03 0.1210051E-08 0.6068323E-03 0.0000000E+00 15 HPO4-- 0.2071093E-03 0.4016323E-06 0.2067076E-03 0.0000000E+00 Chg. balance for solid moles: -.3534E-16 Mass of aqueous solution: 0.996513E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 34.9990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 0.3308E-01 -1.480 8.674 0.938 22.70 3.330 andradite 0.3880E-02 -2.411 1.972 0.295 5.160 0.5122 grossular 0.1669E-03 -3.777 0.7520E-01 -1.124 0.1968 0.2092E-01 apatite-OH 0.6890E-04 -4.162 0.3461E-01 -1.461 0.9058E-01 0.1100E-01 clinochlore 0.5555E-02 -2.255 3.088 0.490 8.081 1.175 daphnite 0.2530E-02 -2.597 1.805 0.257 4.724 0.5470 chlorite-Mn 0.1214E-03 -3.916 0.8605E-01 -1.065 0.2252 0.2742E-01 microcline 0.6894E-02 -2.162 1.919 0.283 5.022 0.7496 stilbite 0.2778E-01 -1.556 19.58 1.292 51.24 9.132 stilpnomelane-Fe 0.9091E-03 -3.041 0.9800 -0.009 2.565 0.3385 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.9587E+00 0.9587E+00 1.0000 -0.018 grossular 0.4125E-01 0.4125E-01 1.0000 -1.385 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.6769E+00 0.6769E+00 1.0000 -0.169 daphnite 0.3083E+00 0.3083E+00 1.0000 -0.511 chlorite-Mn 0.1479E-01 0.1479E-01 1.0000 -1.830 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 38.212638 g Volume = 15.843123 cm3 Porosity: -5.6236% V(tot) - V(min): -.84352E+00 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 34.9990000 g log = 1.5441 Original solution: 1000.0103000 g Original solution / Rock added: 28.57 (Water/Rock Ratio), log = 1.4559 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0203 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.1000E+01 0.9860 0.1006E+01 0.1020E+01 CO2,gas 0.1545E-06 1.0071 0.1587E-06 0.1576E-06 CH4,gas 0.7165E-13 1.0125 0.7402E-13 0.7311E-13 H2,gas 0.8098E-05 1.0005 0.8267E-05 0.8262E-05 H2S,gas 0.1460E-11 0.9960 0.1484E-11 0.1490E-11 S2,gas 0.1186E-32 1.0000 0.1210E-32 0.1210E-32 CO,gas 0.3428E-15 1.0000 0.3497E-15 0.3497E-15 SO3,gas 0.8683E-40 1.0000 0.8859E-40 0.8859E-40 SO2,gas 0.2792E-22 1.0000 0.2849E-22 0.2849E-22 HCl,gas 0.4682E-17 1.0000 0.4777E-17 0.4777E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 16 albite -0.38 -0.38 0.00 0.000 -0.94784E-12 22 andradite 39.01 39.01 0.00 0.000 -0.12132E-10 23 grossular 32.73 32.73 0.00 0.000 -0.12132E-10 32 apatite-OH -18.15 -18.15 0.00 0.000 -0.60662E-11 46 clinochlore 39.07 39.07 0.00 0.000 0.00000E+00 47 daphnite 28.97 28.97 0.00 0.000 0.18198E-10 48 chlorite-Mn 46.87 46.87 0.00 0.000 0.48529E-10 116 microcline -2.49 -2.49 0.00 0.000 0.15165E-11 163 stilbite -7.52 -7.52 0.00 0.000 0.15165E-10 164 stilpnomelane-Fe 13.02 13.02 0.00 0.000 -0.27298E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -15.16 -8.50 -2.833 0.14511E+05 -6.799 3 CH4,gas 4.54 -10.29 -14.83 -3.707 0.25321E+05 -13.131 4 H2,gas 8.00 1.22 -6.78 -3.875 0.11579E+05 -5.083 5 H2S,gas -6.23 -19.76 -13.53 -6.764 0.23098E+05 -11.829 6 S2,gas -7.34 -41.95 -34.62 -5.326 0.59106E+05 -32.917 7 CO,gas 3.21 -13.94 -17.16 -5.279 0.29292E+05 -15.456 8 SO3,gas 17.12 -24.63 -41.75 -10.438 0.71290E+05 -40.053 9 SO2,gas 0.83 -23.41 -24.24 -6.465 0.41396E+05 -22.545 10 HCl,gas 5.19 -13.83 -19.02 -9.510 0.32476E+05 -17.321 11 acmite 7.71 7.38 -0.33 -0.035 0.56991E+03 15 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 19 spessartine 24.46 19.94 -4.52 -0.226 0.77183E+04 20 analcite 3.32 2.87 -0.45 -0.050 0.76975E+03 26 annite 20.12 17.40 -2.72 -0.151 0.46496E+04 27 phlogopite 27.06 24.49 -2.58 -0.143 0.43999E+04 29 anorthite 12.71 8.75 -3.96 -0.304 0.67578E+04 35 aragonite 0.97 -2.93 -3.89 -1.298 0.66464E+04 36 brucite 12.57 8.99 -3.58 -0.715 0.61079E+04 37 calcite 0.81 -2.93 -3.74 -1.246 0.63822E+04 38 carnegieite-low 9.02 6.13 -2.90 -0.414 0.49471E+04 39 carnegieite-high 10.09 6.13 -3.97 -0.567 0.67741E+04 40 carpholite-Mg 8.58 5.51 -3.07 -0.205 0.52429E+04 41 carpholite-Fe 6.71 3.15 -3.56 -0.238 0.60847E+04 42 celadonite 5.34 3.25 -2.09 -0.123 0.35714E+04 43 celadonite-Fe 3.88 0.89 -2.99 -0.176 0.51036E+04 44 chrysotile 23.89 20.46 -3.43 -0.286 0.58532E+04 50 chloritoid-Mg 13.20 8.77 -4.43 -0.295 0.75662E+04 51 chloritoid-Fe 9.17 6.40 -2.77 -0.185 0.47291E+04 52 chloritoid-Mn 11.40 8.67 -2.74 -0.182 0.46706E+04 54 coesite -2.38 -3.25 -0.88 -0.293 0.15006E+04 61 cristobalite -2.56 -3.25 -0.69 -0.232 0.11860E+04 63 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71234E+04 65 diaspore 2.87 1.51 -1.36 -0.226 0.23200E+04 67 diopside 16.18 14.71 -1.47 -0.147 0.25055E+04 68 hedenbergite 14.21 12.35 -1.86 -0.186 0.31704E+04 75 epidote 24.67 23.75 -0.92 -0.045 0.15710E+04 76 clinozoisite 22.81 19.24 -3.56 -0.162 0.60804E+04 77 epidote-Fe 29.84 28.25 -1.59 -0.082 0.27081E+04 78 fayalite 14.05 10.00 -4.04 -0.578 0.69029E+04 79 ferrosilite 11.15 6.75 -4.40 -0.440 0.75153E+04 83 gibbsite 4.08 1.51 -2.56 -0.366 0.43785E+04 84 glaucophane 22.97 19.70 -3.28 -0.089 0.55974E+04 85 glaucophane-Fe 17.28 12.61 -4.67 -0.126 0.79680E+04 87 greenalite 16.14 13.38 -2.76 -0.230 0.47169E+04 90 hematite 12.57 12.04 -0.53 -0.064 0.89887E+03 91 heulandite -5.83 -7.52 -1.69 -0.077 0.28938E+04 95 jadeite 4.22 2.87 -1.34 -0.134 0.22952E+04 96 julgoldite 70.43 66.74 -3.69 -0.096 0.62997E+04 97 kalsilite 7.58 4.02 -3.56 -0.509 0.60796E+04 98 kaolinite -1.33 -3.48 -2.15 -0.195 0.36661E+04 101 laumontite 2.88 2.24 -0.64 -0.043 0.10940E+04 102 lawsonite 9.62 8.75 -0.86 -0.058 0.14745E+04 103 leucite 4.12 0.77 -3.35 -0.335 0.57208E+04 105 lizardite 23.24 20.46 -2.78 -0.232 0.47458E+04 107 magnetite 20.09 18.67 -1.42 -0.116 0.24224E+04 108 minnesotaite 10.39 6.87 -3.52 -0.207 0.60119E+04 120 muscovite 2.58 0.54 -2.04 -0.120 0.34815E+04 121 paragonite 4.24 2.65 -1.59 -0.094 0.27206E+04 122 nepheline 8.34 6.13 -2.21 -0.316 0.37795E+04 128 periclase-Fe 11.63 6.63 -5.00 -1.249 0.85333E+04 134 phlogopite-Na 29.65 26.59 -3.06 -0.170 0.52187E+04 136 prehnite 19.37 17.73 -1.64 -0.097 0.28035E+04 137 prehnite-Fe 22.50 22.23 -0.26 -0.016 0.44903E+03 138 pumpellyite-Fe 46.27 43.60 -2.67 -0.059 0.45513E+04 139 pumpellyite-Mg 48.99 45.97 -3.03 -0.067 0.51711E+04 145 pyroxmangite 7.40 5.64 -1.76 -0.353 0.30103E+04 146 pyrophyllite -6.18 -9.99 -3.81 -0.238 0.65121E+04 147 quartz -2.99 -3.25 -0.27 -0.088 0.45330E+03 152 rhodonite 7.45 5.64 -1.81 -0.362 0.30905E+04 153 sanidine -1.28 -2.49 -1.21 -0.093 0.20677E+04 165 stilpnomelane-Mg 27.44 24.83 -2.61 -0.078 0.44601E+04 171 talc 16.49 13.95 -2.54 -0.149 0.43310E+04 174 tephroite 18.09 14.53 -3.56 -0.509 0.60778E+04 177 topaz-H 4.62 -0.22 -4.84 -0.440 0.82700E+04 178 tridymite -2.63 -3.25 -0.63 -0.210 0.10733E+04 179 tremolite 47.87 43.38 -4.49 -0.121 0.76611E+04 187 wairakite 3.95 2.24 -1.71 -0.100 0.29160E+04 188 walstromite 11.51 8.98 -2.53 -0.506 0.43229E+04 189 wollastonite 10.46 8.98 -1.48 -0.297 0.25333E+04 190 pseudo-wollastonite 11.00 8.98 -2.02 -0.404 0.34532E+04 191 zoisite 22.85 19.24 -3.60 -0.164 0.61544E+04 192 akaganeite 7.75 6.02 -1.73 -0.375 0.29620E+04 193 beidellite-Ca -1.65 -6.40 -4.75 -0.294 0.81134E+04 195 beidellite-K -1.52 -6.51 -4.99 -0.306 0.85263E+04 197 beidellite-Na -1.34 -5.82 -4.48 -0.274 0.76455E+04 199 chalcedony -2.80 -3.25 -0.45 -0.151 0.77260E+03 201 montmorillonite-Ca -2.29 -5.50 -3.21 -0.199 0.54868E+04 202 montmorillonite-K -2.24 -5.62 -3.38 -0.207 0.57779E+04 203 montmorillonite-Mg -2.48 -6.04 -3.56 -0.220 0.60769E+04 204 montmorillonite-Na -2.04 -4.93 -2.89 -0.177 0.49328E+04 205 nontronite-Ca 3.21 2.61 -0.60 -0.039 0.10280E+04 206 nontronite-H 2.53 0.59 -1.94 -0.130 0.33100E+04 207 nontronite-K 3.34 2.50 -0.84 -0.054 0.14422E+04 208 nontronite-Mg 3.07 2.08 -1.00 -0.065 0.17022E+04 209 nontronite-Na 3.52 3.19 -0.33 -0.021 0.56312E+03 224 tobermorite 9.82 6.93 -2.89 -0.788 0.49318E+04 233 boehmite 4.41 1.51 -2.89 -0.482 0.49369E+04 235 ferrous-oxide 9.81 6.63 -3.18 -0.796 0.54343E+04 240 silica-amorphous -2.09 -3.25 -1.16 -0.388 0.19868E+04 242 an20ab80 2.02 1.44 -0.57 -0.044 0.98071E+03 243 an25ab75 2.65 1.90 -0.75 -0.057 0.12729E+04 244 an30ab70 3.28 2.36 -0.92 -0.071 0.15746E+04 245 tr.625ac.25prg.125 45.16 41.67 -3.49 -0.094 0.59662E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 1.0000000 g Current total amount of reactant added: 34.9990000 g New total amount of reactant added: 35.9990000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.2996E-12 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 8 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 35.9990000 Water: Moles liquid = 0.5526E+02 kg liquid = 0.9956E+00 Moles total = 0.5506E+02 kg total = 0.9919E+00 Activity = 1.0000 Stoichiometric ionic strength = .5905347E-02 Osmotic coef. = 0.9596 True ionic strength = .1075019E-01 Chg. balance for total moles = 0.2996E-12 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.13875E-09 -9.8578 0.12077E-09 -9.9180 0.87042E+00 -0.0603 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13822E-03 -3.8594 0.11987E-03 -3.9213 0.86726E+00 -0.0619 4 SO4-- 0.25597E-04 -4.5918 0.15391E-04 -4.8127 0.60128E+00 -0.2209 5 HCO3- 0.64170E-05 -5.1927 0.55701E-05 -5.2541 0.86802E+00 -0.0615 6 HS- 0.45528E-09 -9.3417 0.39488E-09 -9.4035 0.86733E+00 -0.0618 7 Al+++ 0.17062E-27 -27.7680 0.55106E-28 -28.2588 0.32297E+00 -0.4908 8 H4SiO4 0.55720E-03 -3.2540 0.55720E-03 -3.2540 0.10000E+01 0.0000 9 Ca++ 0.44882E-07 -7.3479 0.26868E-07 -7.5708 0.59863E+00 -0.2228 10 Mg++ 0.24427E-10 -10.6121 0.14583E-10 -10.8362 0.59698E+00 -0.2240 11 Fe++ 0.10504E-12 -12.9787 0.62746E-13 -13.2024 0.59738E+00 -0.2238 12 K+ 0.83861E-04 -4.0764 0.72804E-04 -4.1378 0.86815E+00 -0.0614 13 Na+ 0.10633E-01 -1.9733 0.92211E-02 -2.0352 0.86717E+00 -0.0619 14 Mn++ 0.19345E-10 -10.7134 0.11562E-10 -10.9370 0.59767E+00 -0.2235 15 HPO4-- 0.36613E-06 -6.4364 0.22016E-06 -6.6573 0.60133E+00 -0.2209 16 HSiO3- 0.49673E-02 -2.3039 0.43079E-02 -2.3657 0.86726E+00 -0.0619 17 Ca(HSiO3)+ 0.30359E-08 -8.5177 0.26359E-08 -8.5791 0.86826E+00 -0.0613 18 Mg(HSiO3)+ 0.20506E-11 -11.6881 0.17805E-11 -11.7495 0.86826E+00 -0.0613 19 NaHSiO3,aq 0.64247E-03 -3.1921 0.64247E-03 -3.1921 0.10000E+01 0.0000 20 AlO+ 0.59194E-15 -15.2277 0.51396E-15 -15.2891 0.86826E+00 -0.0613 22 HAlO2,aq 0.84749E-09 -9.0719 0.84749E-09 -9.0719 0.10000E+01 0.0000 23 AlO2- 0.17930E-04 -4.7464 0.15533E-04 -4.8087 0.86631E+00 -0.0623 24 CH4,aq 0.13907E-15 -15.8568 0.13882E-15 -15.8576 0.99818E+00 -0.0008 29 CO,aq 0.29540E-18 -18.5296 0.29540E-18 -18.5296 0.10000E+01 0.0000 30 CO2,aq 0.14401E-08 -8.8416 0.14374E-08 -8.8424 0.99818E+00 -0.0008 31 CO3-2 0.67084E-05 -5.1734 0.40284E-05 -5.3949 0.60050E+00 -0.2215 32 CaCO3,aq 0.13571E-08 -8.8674 0.13571E-08 -8.8674 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.43997E-11 -11.3566 0.38201E-11 -11.4179 0.86826E+00 -0.0613 34 CaCl+ 0.60030E-11 -11.2216 0.52122E-11 -11.2830 0.86826E+00 -0.0613 35 CaCl2,aq 0.14844E-15 -15.8284 0.14844E-15 -15.8284 0.10000E+01 0.0000 36 CaOH+ 0.18261E-07 -7.7385 0.15855E-07 -7.7998 0.86826E+00 -0.0613 37 CaSO4,aq 0.13131E-09 -9.8817 0.13131E-09 -9.8817 0.10000E+01 0.0000 38 HCl,aq 0.26530E-14 -14.5763 0.26530E-14 -14.5763 0.10000E+01 0.0000 43 FeCl+ 0.13712E-16 -16.8629 0.11905E-16 -16.9243 0.86826E+00 -0.0613 46 FeO,aq 0.16719E-09 -9.7768 0.16719E-09 -9.7768 0.10000E+01 0.0000 47 FeOH+ 0.19477E-10 -10.7105 0.16911E-10 -10.7718 0.86826E+00 -0.0613 48 HFeO2- 0.16701E-07 -7.7773 0.14484E-07 -7.8391 0.86726E+00 -0.0619 49 FeO+ 0.51364E-15 -15.2893 0.44597E-15 -15.3507 0.86826E+00 -0.0613 51 FeO2- 0.72138E-08 -8.1418 0.62562E-08 -8.2037 0.86726E+00 -0.0619 52 HFeO2,aq 0.96099E-10 -10.0173 0.96099E-10 -10.0173 0.10000E+01 0.0000 53 H2,aq 0.81955E-08 -8.0864 0.81807E-08 -8.0872 0.99818E+00 -0.0008 54 KCl,aq 0.15818E-09 -9.8009 0.15818E-09 -9.8009 0.10000E+01 0.0000 55 KHSO4,aq 0.38263E-18 -18.4172 0.38263E-18 -18.4172 0.10000E+01 0.0000 56 KOH,aq 0.25743E-06 -6.5893 0.25743E-06 -6.5893 0.10000E+01 0.0000 57 KSO4- 0.20049E-07 -7.6979 0.17388E-07 -7.7598 0.86726E+00 -0.0619 58 MgCO3,aq 0.18463E-12 -12.7337 0.18463E-12 -12.7337 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.24401E-14 -14.6126 0.21186E-14 -14.6739 0.86826E+00 -0.0613 60 MgCl+ 0.29530E-14 -14.5297 0.25640E-14 -14.5911 0.86826E+00 -0.0613 61 MgOH+ 0.54843E-10 -10.2609 0.47618E-10 -10.3222 0.86826E+00 -0.0613 63 MnO,aq 0.82088E-09 -9.0857 0.82088E-09 -9.0857 0.10000E+01 0.0000 64 MnOH+ 0.33341E-09 -9.4770 0.28949E-09 -9.5384 0.86826E+00 -0.0613 65 MnO2-2 0.31102E-11 -11.5072 0.18677E-11 -11.7287 0.60050E+00 -0.2215 66 HMnO2- 0.56983E-10 -10.2443 0.49419E-10 -10.3061 0.86726E+00 -0.0619 69 MnCl+ 0.98298E-14 -14.0075 0.85348E-14 -14.0688 0.86826E+00 -0.0613 70 MnSO4,aq 0.51373E-13 -13.2893 0.51373E-13 -13.2893 0.10000E+01 0.0000 71 NaCl,aq 0.36632E-06 -6.4361 0.36632E-06 -6.4361 0.10000E+01 0.0000 72 NaOH,aq 0.32804E-04 -4.4841 0.32804E-04 -4.4841 0.10000E+01 0.0000 74 OH- 0.55222E-02 -2.2579 0.47839E-02 -2.3202 0.86631E+00 -0.0623 79 HPO3-2 0.93468E-17 -17.0293 0.56128E-17 -17.2508 0.60050E+00 -0.2215 82 H3PO4,aq 0.22460E-16 -16.6486 0.22460E-16 -16.6486 0.10000E+01 0.0000 83 H2PO4- 0.56527E-09 -9.2477 0.49051E-09 -9.3093 0.86775E+00 -0.0616 84 PO4-3 0.44709E-08 -8.3496 0.14873E-08 -8.8276 0.33267E+00 -0.4780 87 H2P2O7-2 0.31416E-19 -19.5028 0.18866E-19 -19.7243 0.60050E+00 -0.2215 88 HP2O7-3 0.96528E-16 -16.0153 0.31191E-16 -16.5060 0.32313E+00 -0.4906 89 P2O7-4 0.44622E-15 -15.3505 0.61697E-16 -16.2097 0.13827E+00 -0.8593 90 H2S,aq 0.14766E-12 -12.8307 0.14739E-12 -12.8315 0.99818E+00 -0.0008 97 SO3-2 0.27011E-13 -13.5685 0.16362E-13 -13.7862 0.60574E+00 -0.2177 98 HSO3- 0.14266E-15 -15.8457 0.12373E-15 -15.9075 0.86726E+00 -0.0619 99 HSO4- 0.20620E-11 -11.6857 0.17914E-11 -11.7468 0.86876E+00 -0.0611 101 S2O3-2 0.44377E-19 -19.3528 0.26648E-19 -19.5743 0.60050E+00 -0.2215 Charge balance for all species = 0.3014E-12 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.1387533E-09 -.1124355E-01 -.1132319E+02 0.0000 2 H2O 0.1000000E+01 0.5550823E+02 0.9991473E+06 0.0000 3 Cl- 0.1382222E-03 0.1385887E-03 0.4909207E+01 5.9968 4 SO4-- 0.2559742E-04 0.2561646E-04 0.2458667E+01 15.0233 5 HCO3- 0.6417017E-05 0.1312821E-04 0.8003655E+00 4.6639 6 HS- 0.4552763E-09 0.1590577E-08 0.5255883E-04 0.5145 7 Al+++ 0.1706237E-27 0.1793115E-04 0.4833979E+00 1.4953 8 H4SiO4 0.5572022E-03 0.6166959E-02 0.5922358E+03 -3.2540 9 Ca++ 0.4488205E-07 0.6767729E-07 0.2710065E-02 12.2653 10 Mg++ 0.2442734E-10 0.8151052E-10 0.1979999E-05 8.9999 11 Fe++ 0.1050358E-12 0.2419783E-07 0.1350228E-02 6.6336 12 K+ 0.8386074E-04 0.8413838E-04 0.3287182E+01 5.7802 13 Na+ 0.1063349E-01 0.1130913E-01 0.2597736E+03 7.8828 14 Mn++ 0.1934502E-10 0.1233790E-08 0.6772435E-04 8.8991 15 HPO4-- 0.3661296E-06 0.3711658E-06 0.3559384E-01 13.1788 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.5960770E+00 -.1119370E-01 -.5848833E+00 0.0000000E+00 2 H2O 0.5505699E+02 0.5526212E+02 -.2051322E+00 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.1023159E-02 0.2550289E-04 0.9976566E-03 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.9976550E-03 0.1583524E-08 -.9976566E-03 0.0000000E+00 7 Al+++ 0.1173834E+00 0.1785164E-04 0.1173656E+00 0.0000000E+00 8 H4SiO4 0.3748498E+00 0.6139616E-02 0.3687102E+00 0.0000000E+00 9 Ca++ 0.4141846E-01 0.6737723E-07 0.4141839E-01 0.0000000E+00 10 Mg++ 0.2857063E-01 0.8114912E-10 0.2857063E-01 0.0000000E+00 11 Fe++ 0.2566760E-01 0.2409054E-07 0.2566757E-01 0.0000000E+00 12 K+ 0.7643100E-02 0.8376533E-04 0.7559334E-02 0.0000000E+00 13 Na+ 0.4534759E-01 0.1125899E-01 0.3408860E-01 0.0000000E+00 14 Mn++ 0.6241721E-03 0.1228320E-08 0.6241709E-03 0.0000000E+00 15 HPO4-- 0.2130268E-03 0.3695201E-06 0.2126573E-03 0.0000000E+00 Chg. balance for solid moles: -.5735E-16 Mass of aqueous solution: 0.996413E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 35.9990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 0.3409E-01 -1.467 8.939 0.951 22.74 3.431 andradite 0.3991E-02 -2.399 2.028 0.307 5.160 0.5269 grossular 0.1850E-03 -3.733 0.8335E-01 -1.079 0.2121 0.2319E-01 apatite-OH 0.7089E-04 -4.149 0.3561E-01 -1.448 0.9059E-01 0.1131E-01 clinochlore 0.5714E-02 -2.243 3.176 0.502 8.081 1.208 daphnite 0.2580E-02 -2.588 1.841 0.265 4.683 0.5577 chlorite-Mn 0.1248E-03 -3.904 0.8850E-01 -1.053 0.2252 0.2820E-01 microcline 0.7081E-02 -2.150 1.971 0.295 5.014 0.7698 stilbite 0.2854E-01 -1.545 20.11 1.303 51.17 9.380 stilpnomelane-Fe 0.9577E-03 -3.019 1.032 0.014 2.627 0.3566 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.9557E+00 0.9557E+00 1.0000 -0.020 grossular 0.4431E-01 0.4431E-01 1.0000 -1.353 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.6788E+00 0.6788E+00 1.0000 -0.168 daphnite 0.3064E+00 0.3064E+00 1.0000 -0.514 chlorite-Mn 0.1483E-01 0.1483E-01 1.0000 -1.829 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 39.304501 g Volume = 16.293172 cm3 Porosity: -5.8026% V(tot) - V(min): -.89357E+00 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 35.9990000 g log = 1.5563 Original solution: 1000.0103000 g Original solution / Rock added: 27.78 (Water/Rock Ratio), log = 1.4437 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0203 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.1000E+01 0.9860 0.1006E+01 0.1020E+01 CO2,gas 0.1497E-06 1.0071 0.1538E-06 0.1527E-06 CH4,gas 0.1978E-12 1.0125 0.2043E-12 0.2018E-12 H2,gas 0.1052E-04 1.0005 0.1074E-04 0.1073E-04 H2S,gas 0.3987E-11 0.9960 0.4052E-11 0.4068E-11 S2,gas 0.5236E-32 1.0000 0.5342E-32 0.5342E-32 CO,gas 0.4314E-15 1.0000 0.4402E-15 0.4402E-15 SO3,gas 0.8319E-40 1.0000 0.8488E-40 0.8488E-40 SO2,gas 0.3476E-22 1.0000 0.3547E-22 0.3547E-22 HCl,gas 0.4588E-17 1.0000 0.4681E-17 0.4681E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 16 albite -0.38 -0.38 0.00 0.000 -0.13080E-10 22 andradite 39.01 39.01 0.00 0.000 0.00000E+00 23 grossular 32.73 32.73 0.00 0.000 0.12132E-10 32 apatite-OH -18.15 -18.15 0.00 0.000 0.00000E+00 46 clinochlore 39.07 39.07 0.00 0.000 -0.24265E-10 47 daphnite 28.97 28.97 0.00 0.000 -0.18198E-10 48 chlorite-Mn 46.87 46.87 0.00 0.000 -0.12132E-10 116 microcline -2.49 -2.49 0.00 0.000 -0.10616E-10 163 stilbite -7.52 -7.52 0.00 0.000 -0.90992E-11 164 stilpnomelane-Fe 13.02 13.02 0.00 0.000 -0.27298E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -15.17 -8.51 -2.837 0.14534E+05 -6.813 3 CH4,gas 4.54 -9.84 -14.39 -3.597 0.24568E+05 -12.690 4 H2,gas 8.00 1.33 -6.67 -3.810 0.11385E+05 -4.969 5 H2S,gas -6.23 -19.32 -13.09 -6.546 0.22353E+05 -11.392 6 S2,gas -7.34 -41.31 -33.97 -5.226 0.58005E+05 -32.272 7 CO,gas 3.21 -13.84 -17.06 -5.248 0.29121E+05 -15.356 8 SO3,gas 17.12 -24.65 -41.77 -10.443 0.71321E+05 -40.071 9 SO2,gas 0.83 -23.32 -24.15 -6.440 0.41234E+05 -22.450 10 HCl,gas 5.19 -13.84 -19.03 -9.514 0.32491E+05 -17.330 11 acmite 7.71 7.34 -0.37 -0.038 0.62688E+03 15 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 19 spessartine 24.46 19.93 -4.53 -0.227 0.77373E+04 20 analcite 3.32 2.87 -0.45 -0.050 0.77133E+03 26 annite 20.12 17.41 -2.71 -0.150 0.46255E+04 27 phlogopite 27.06 24.51 -2.55 -0.142 0.43565E+04 29 anorthite 12.71 8.75 -3.96 -0.305 0.67657E+04 35 aragonite 0.97 -2.91 -3.87 -1.291 0.66137E+04 36 brucite 12.57 9.00 -3.57 -0.714 0.60934E+04 37 calcite 0.81 -2.91 -3.72 -1.240 0.63495E+04 38 carnegieite-low 9.02 6.12 -2.90 -0.414 0.49503E+04 39 carnegieite-high 10.09 6.12 -3.97 -0.567 0.67773E+04 40 carpholite-Mg 8.58 5.48 -3.10 -0.207 0.52925E+04 41 carpholite-Fe 6.71 3.12 -3.60 -0.240 0.61408E+04 42 celadonite 5.34 3.26 -2.08 -0.122 0.35553E+04 43 celadonite-Fe 3.88 0.89 -2.98 -0.175 0.50940E+04 44 chrysotile 23.89 20.49 -3.40 -0.283 0.58066E+04 50 chloritoid-Mg 13.20 8.74 -4.46 -0.297 0.76174E+04 51 chloritoid-Fe 9.17 6.37 -2.80 -0.187 0.47867E+04 52 chloritoid-Mn 11.40 8.64 -2.77 -0.184 0.47218E+04 54 coesite -2.38 -3.25 -0.88 -0.293 0.14990E+04 61 cristobalite -2.56 -3.25 -0.69 -0.231 0.11844E+04 63 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71234E+04 65 diaspore 2.87 1.50 -1.38 -0.230 0.23536E+04 67 diopside 16.18 14.76 -1.42 -0.142 0.24317E+04 68 hedenbergite 14.21 12.39 -1.82 -0.182 0.31030E+04 75 epidote 24.67 23.73 -0.94 -0.046 0.16101E+04 76 clinozoisite 22.81 19.25 -3.55 -0.161 0.60642E+04 77 epidote-Fe 29.84 28.20 -1.64 -0.085 0.28027E+04 78 fayalite 14.05 10.01 -4.03 -0.576 0.68853E+04 79 ferrosilite 11.15 6.76 -4.39 -0.439 0.74961E+04 83 gibbsite 4.08 1.50 -2.58 -0.369 0.44121E+04 84 glaucophane 22.97 19.72 -3.25 -0.088 0.55507E+04 85 glaucophane-Fe 17.28 12.63 -4.65 -0.126 0.79408E+04 87 greenalite 16.14 13.39 -2.75 -0.229 0.46897E+04 90 hematite 12.57 11.94 -0.63 -0.076 0.10769E+04 91 heulandite -5.83 -7.52 -1.69 -0.077 0.28938E+04 95 jadeite 4.22 2.87 -1.35 -0.135 0.22968E+04 96 julgoldite 70.43 66.68 -3.75 -0.097 0.64055E+04 97 kalsilite 7.58 4.02 -3.56 -0.509 0.60827E+04 98 kaolinite -1.33 -3.52 -2.18 -0.199 0.37302E+04 101 laumontite 2.88 2.24 -0.64 -0.043 0.10988E+04 102 lawsonite 9.62 8.75 -0.87 -0.058 0.14824E+04 103 leucite 4.12 0.77 -3.35 -0.335 0.57224E+04 105 lizardite 23.24 20.49 -2.75 -0.229 0.46992E+04 107 magnetite 20.09 18.57 -1.52 -0.124 0.25924E+04 108 minnesotaite 10.39 6.88 -3.50 -0.206 0.59815E+04 120 muscovite 2.58 0.50 -2.08 -0.122 0.35487E+04 121 paragonite 4.24 2.61 -1.63 -0.096 0.27878E+04 122 nepheline 8.34 6.12 -2.22 -0.316 0.37826E+04 128 periclase-Fe 11.63 6.63 -4.99 -1.248 0.85253E+04 134 phlogopite-Na 29.65 26.62 -3.03 -0.168 0.51753E+04 136 prehnite 19.37 17.76 -1.61 -0.095 0.27536E+04 137 prehnite-Fe 22.50 22.23 -0.27 -0.016 0.45457E+03 138 pumpellyite-Fe 46.27 43.65 -2.62 -0.058 0.44772E+04 139 pumpellyite-Mg 48.99 46.01 -2.98 -0.066 0.50905E+04 145 pyroxmangite 7.40 5.65 -1.75 -0.351 0.29942E+04 146 pyrophyllite -6.18 -10.03 -3.85 -0.241 0.65731E+04 147 quartz -2.99 -3.25 -0.26 -0.088 0.45172E+03 152 rhodonite 7.45 5.65 -1.80 -0.360 0.30744E+04 153 sanidine -1.28 -2.49 -1.21 -0.093 0.20677E+04 165 stilpnomelane-Mg 27.44 24.85 -2.59 -0.077 0.44278E+04 171 talc 16.49 13.98 -2.51 -0.147 0.42812E+04 174 tephroite 18.09 14.54 -3.54 -0.506 0.60472E+04 177 topaz-H 4.62 -0.26 -4.88 -0.444 0.83357E+04 178 tridymite -2.63 -3.25 -0.63 -0.209 0.10717E+04 179 tremolite 47.87 43.50 -4.37 -0.118 0.74635E+04 187 wairakite 3.95 2.24 -1.71 -0.101 0.29207E+04 188 walstromite 11.51 9.01 -2.50 -0.500 0.42651E+04 189 wollastonite 10.46 9.01 -1.45 -0.290 0.24756E+04 190 pseudo-wollastonite 11.00 9.01 -1.99 -0.398 0.33954E+04 191 zoisite 22.85 19.25 -3.59 -0.163 0.61382E+04 192 akaganeite 7.75 5.97 -1.79 -0.386 0.30510E+04 193 beidellite-Ca -1.65 -6.43 -4.79 -0.296 0.81766E+04 197 beidellite-Na -1.34 -5.86 -4.51 -0.276 0.77085E+04 199 chalcedony -2.80 -3.25 -0.45 -0.151 0.77101E+03 201 montmorillonite-Ca -2.29 -5.53 -3.23 -0.200 0.55226E+04 202 montmorillonite-K -2.24 -5.64 -3.40 -0.208 0.58134E+04 203 montmorillonite-Mg -2.48 -6.06 -3.58 -0.222 0.61196E+04 204 montmorillonite-Na -2.04 -4.95 -2.91 -0.178 0.49683E+04 205 nontronite-Ca 3.21 2.51 -0.70 -0.046 0.12020E+04 206 nontronite-H 2.53 0.49 -2.05 -0.137 0.34933E+04 207 nontronite-K 3.34 2.39 -0.95 -0.061 0.16160E+04 208 nontronite-Mg 3.07 1.97 -1.10 -0.072 0.18831E+04 209 nontronite-Na 3.52 3.09 -0.43 -0.028 0.73692E+03 224 tobermorite 9.82 6.96 -2.86 -0.780 0.48835E+04 233 boehmite 4.41 1.50 -2.91 -0.485 0.49705E+04 235 ferrous-oxide 9.81 6.63 -3.18 -0.794 0.54262E+04 240 silica-amorphous -2.09 -3.25 -1.16 -0.388 0.19852E+04 242 an20ab80 2.02 1.44 -0.58 -0.044 0.98230E+03 243 an25ab75 2.65 1.90 -0.75 -0.057 0.12748E+04 244 an30ab70 3.28 2.36 -0.92 -0.071 0.15770E+04 245 tr.625ac.25prg.125 45.16 41.77 -3.39 -0.091 0.57880E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 1.0000000 g Current total amount of reactant added: 35.9990000 g New total amount of reactant added: 36.9990000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.2996E-12 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 8 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 36.9990000 Water: Moles liquid = 0.5526E+02 kg liquid = 0.9954E+00 Moles total = 0.5504E+02 kg total = 0.9916E+00 Activity = 1.0000 Stoichiometric ionic strength = .6025334E-02 Osmotic coef. = 0.9592 True ionic strength = .1096706E-01 Chg. balance for total moles = 0.2996E-12 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.13638E-09 -9.8652 0.11859E-09 -9.9260 0.86953E+00 -0.0607 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13823E-03 -3.8594 0.11975E-03 -3.9217 0.86632E+00 -0.0623 4 SO4-- 0.25599E-04 -4.5918 0.15327E-04 -4.8145 0.59874E+00 -0.2228 5 HCO3- 0.63474E-05 -5.1974 0.55038E-05 -5.2593 0.86709E+00 -0.0619 6 HS- 0.12119E-08 -8.9165 0.10500E-08 -8.9788 0.86639E+00 -0.0623 7 Al+++ 0.15601E-27 -27.8068 0.49902E-28 -28.3019 0.31987E+00 -0.4950 8 H4SiO4 0.55854E-03 -3.2529 0.55854E-03 -3.2529 0.10000E+01 0.0000 9 Ca++ 0.46704E-07 -7.3306 0.27838E-07 -7.5554 0.59606E+00 -0.2247 10 Mg++ 0.24108E-10 -10.6178 0.14329E-10 -10.8438 0.59439E+00 -0.2259 11 Fe++ 0.10275E-12 -12.9882 0.61115E-13 -13.2138 0.59479E+00 -0.2256 12 K+ 0.85556E-04 -4.0678 0.74196E-04 -4.1296 0.86722E+00 -0.0619 13 Na+ 0.10849E-01 -1.9646 0.93974E-02 -2.0270 0.86623E+00 -0.0624 14 Mn++ 0.19092E-10 -10.7192 0.11361E-10 -10.9446 0.59509E+00 -0.2254 15 HPO4-- 0.33823E-06 -6.4708 0.20253E-06 -6.6935 0.59879E+00 -0.2227 16 HSiO3- 0.50765E-02 -2.2944 0.43979E-02 -2.3568 0.86632E+00 -0.0623 17 Ca(HSiO3)+ 0.32146E-08 -8.4929 0.27882E-08 -8.5547 0.86734E+00 -0.0618 18 Mg(HSiO3)+ 0.20593E-11 -11.6863 0.17861E-11 -11.7481 0.86734E+00 -0.0618 19 NaHSiO3,aq 0.66843E-03 -3.1749 0.66843E-03 -3.1749 0.10000E+01 0.0000 20 AlO+ 0.55658E-15 -15.2545 0.48274E-15 -15.3163 0.86734E+00 -0.0618 22 HAlO2,aq 0.81068E-09 -9.0911 0.81068E-09 -9.0911 0.10000E+01 0.0000 23 AlO2- 0.17487E-04 -4.7573 0.15132E-04 -4.8201 0.86535E+00 -0.0628 24 CH4,aq 0.36693E-15 -15.4354 0.36625E-15 -15.4362 0.99815E+00 -0.0008 29 CO,aq 0.36804E-18 -18.4341 0.36804E-18 -18.4341 0.10000E+01 0.0000 30 CO2,aq 0.13972E-08 -8.8547 0.13946E-08 -8.8555 0.99815E+00 -0.0008 31 CO3-2 0.67795E-05 -5.1688 0.40538E-05 -5.3921 0.59796E+00 -0.2233 32 CaCO3,aq 0.14150E-08 -8.8492 0.14150E-08 -8.8492 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.45092E-11 -11.3459 0.39110E-11 -11.4077 0.86734E+00 -0.0618 34 CaCl+ 0.62202E-11 -11.2062 0.53950E-11 -11.2680 0.86734E+00 -0.0618 35 CaCl2,aq 0.15349E-15 -15.8139 0.15349E-15 -15.8139 0.10000E+01 0.0000 36 CaOH+ 0.19289E-07 -7.7147 0.16730E-07 -7.7765 0.86734E+00 -0.0618 37 CaSO4,aq 0.13549E-09 -9.8681 0.13549E-09 -9.8681 0.10000E+01 0.0000 38 HCl,aq 0.26023E-14 -14.5846 0.26023E-14 -14.5846 0.10000E+01 0.0000 43 FeCl+ 0.13356E-16 -16.8743 0.11584E-16 -16.9361 0.86734E+00 -0.0618 46 FeO,aq 0.16890E-09 -9.7724 0.16890E-09 -9.7724 0.10000E+01 0.0000 47 FeOH+ 0.19341E-10 -10.7135 0.16776E-10 -10.7753 0.86734E+00 -0.0618 48 HFeO2- 0.17202E-07 -7.7644 0.14902E-07 -7.8267 0.86632E+00 -0.0623 49 FeO+ 0.45010E-15 -15.3467 0.39039E-15 -15.4085 0.86734E+00 -0.0618 51 FeO2- 0.65568E-08 -8.1833 0.56803E-08 -8.2456 0.86632E+00 -0.0623 52 HFeO2,aq 0.85673E-10 -10.0672 0.85673E-10 -10.0672 0.10000E+01 0.0000 53 H2,aq 0.10525E-07 -7.9778 0.10505E-07 -7.9786 0.99815E+00 -0.0008 54 KCl,aq 0.16104E-09 -9.7931 0.16104E-09 -9.7931 0.10000E+01 0.0000 55 KHSO4,aq 0.38130E-18 -18.4187 0.38130E-18 -18.4187 0.10000E+01 0.0000 56 KOH,aq 0.26719E-06 -6.5732 0.26719E-06 -6.5732 0.10000E+01 0.0000 57 KSO4- 0.20370E-07 -7.6910 0.17647E-07 -7.7533 0.86632E+00 -0.0623 58 MgCO3,aq 0.18257E-12 -12.7386 0.18257E-12 -12.7386 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.23717E-14 -14.6249 0.20571E-14 -14.6868 0.86734E+00 -0.0618 60 MgCl+ 0.29019E-14 -14.5373 0.25169E-14 -14.5991 0.86734E+00 -0.0618 61 MgOH+ 0.54942E-10 -10.2601 0.47653E-10 -10.3219 0.86734E+00 -0.0618 63 MnO,aq 0.83664E-09 -9.0775 0.83664E-09 -9.0775 0.10000E+01 0.0000 64 MnOH+ 0.33401E-09 -9.4762 0.28970E-09 -9.5380 0.86734E+00 -0.0618 65 MnO2-2 0.33019E-11 -11.4812 0.19744E-11 -11.7046 0.59796E+00 -0.2233 66 HMnO2- 0.59211E-10 -10.2276 0.51296E-10 -10.2899 0.86632E+00 -0.0623 69 MnCl+ 0.96596E-14 -14.0150 0.83781E-14 -14.0769 0.86734E+00 -0.0618 70 MnSO4,aq 0.50272E-13 -13.2987 0.50272E-13 -13.2987 0.10000E+01 0.0000 71 NaCl,aq 0.37295E-06 -6.4284 0.37295E-06 -6.4284 0.10000E+01 0.0000 72 NaOH,aq 0.34047E-04 -4.4679 0.34047E-04 -4.4679 0.10000E+01 0.0000 74 OH- 0.56302E-02 -2.2495 0.48721E-02 -2.3123 0.86535E+00 -0.0628 79 HPO3-2 0.11088E-16 -16.9551 0.66303E-17 -17.1785 0.59796E+00 -0.2233 82 H3PO4,aq 0.19920E-16 -16.7007 0.19920E-16 -16.7007 0.10000E+01 0.0000 83 H2PO4- 0.51113E-09 -9.2915 0.44306E-09 -9.3535 0.86682E+00 -0.0621 84 PO4-3 0.42271E-08 -8.3740 0.13934E-08 -8.8559 0.32964E+00 -0.4820 87 H2P2O7-2 0.25741E-19 -19.5894 0.15392E-19 -19.8127 0.59796E+00 -0.2233 88 HP2O7-3 0.80983E-16 -16.0916 0.25916E-16 -16.5864 0.32003E+00 -0.4948 89 P2O7-4 0.38403E-15 -15.4156 0.52209E-16 -16.2823 0.13595E+00 -0.8666 90 H2S,aq 0.38555E-12 -12.4139 0.38483E-12 -12.4147 0.99815E+00 -0.0008 97 SO3-2 0.34685E-13 -13.4599 0.20924E-13 -13.6794 0.60326E+00 -0.2195 98 HSO3- 0.17934E-15 -15.7463 0.15536E-15 -15.8087 0.86632E+00 -0.0623 99 HSO4- 0.20184E-11 -11.6950 0.17517E-11 -11.7565 0.86785E+00 -0.0616 101 S2O3-2 0.11587E-18 -18.9360 0.69288E-19 -19.1593 0.59796E+00 -0.2233 Charge balance for all species = 0.3012E-12 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.1363816E-09 -.1148630E-01 -.1156745E+02 0.0000 2 H2O 0.1000000E+01 0.5550820E+02 0.9991289E+06 0.0000 3 Cl- 0.1382319E-03 0.1386050E-03 0.4909699E+01 6.0042 4 SO4-- 0.2559936E-04 0.2561807E-04 0.2458777E+01 15.0374 5 HCO3- 0.6347436E-05 0.1312976E-04 0.8004457E+00 4.6666 6 HS- 0.1211912E-08 0.3013169E-08 0.9956500E-04 0.9471 7 Al+++ 0.1560095E-27 0.1748780E-04 0.4714373E+00 1.4760 8 H4SiO4 0.5585409E-03 0.6303481E-02 0.6053356E+03 -3.2529 9 Ca++ 0.4670387E-07 0.7076913E-07 0.2833823E-02 12.2966 10 Mg++ 0.2410793E-10 0.8129725E-10 0.1974783E-05 9.0082 11 Fe++ 0.1027518E-12 0.2403291E-07 0.1341001E-02 6.6381 12 K+ 0.8555564E-04 0.8584337E-04 0.3353734E+01 5.7963 13 Na+ 0.1084861E-01 0.1155146E-01 0.2653352E+03 7.8990 14 Mn++ 0.1909170E-10 0.1252320E-08 0.6874021E-04 8.9073 15 HPO4-- 0.3382308E-06 0.3429691E-06 0.3288925E-01 13.1584 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.6126355E+00 -.1143402E-01 -.6012015E+00 0.0000000E+00 2 H2O 0.5504445E+02 0.5525556E+02 -.2111083E+00 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.1050873E-02 0.2550147E-04 0.1025371E-02 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.1025368E-02 0.2999454E-08 -.1025371E-02 0.0000000E+00 7 Al+++ 0.1206442E+00 0.1740820E-04 0.1206268E+00 0.0000000E+00 8 H4SiO4 0.3852626E+00 0.6274791E-02 0.3789878E+00 0.0000000E+00 9 Ca++ 0.4256860E-01 0.7044703E-07 0.4256853E-01 0.0000000E+00 10 Mg++ 0.2936429E-01 0.8092723E-10 0.2936429E-01 0.0000000E+00 11 Fe++ 0.2638060E-01 0.2392352E-07 0.2638058E-01 0.0000000E+00 12 K+ 0.7855414E-02 0.8545266E-04 0.7769961E-02 0.0000000E+00 13 Na+ 0.4660283E-01 0.1149888E-01 0.3510395E-01 0.0000000E+00 14 Mn++ 0.6415107E-03 0.1246620E-08 0.6415095E-03 0.0000000E+00 15 HPO4-- 0.2189444E-03 0.3414081E-06 0.2186030E-03 0.0000000E+00 Chg. balance for solid moles: -.1158E-15 Mass of aqueous solution: 0.996313E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 36.9990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 0.3510E-01 -1.455 9.205 0.964 22.79 3.534 andradite 0.4101E-02 -2.387 2.084 0.319 5.160 0.5415 grossular 0.2041E-03 -3.690 0.9191E-01 -1.037 0.2275 0.2557E-01 apatite-OH 0.7287E-04 -4.137 0.3660E-01 -1.436 0.9061E-01 0.1163E-01 clinochlore 0.5873E-02 -2.231 3.264 0.514 8.081 1.242 daphnite 0.2628E-02 -2.580 1.875 0.273 4.642 0.5682 chlorite-Mn 0.1283E-03 -3.892 0.9096E-01 -1.041 0.2252 0.2899E-01 microcline 0.7266E-02 -2.139 2.022 0.306 5.007 0.7900 stilbite 0.2929E-01 -1.533 20.64 1.315 51.09 9.627 stilpnomelane-Fe 0.1008E-02 -2.997 1.086 0.036 2.689 0.3752 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.9526E+00 0.9526E+00 1.0000 -0.021 grossular 0.4739E-01 0.4739E-01 1.0000 -1.324 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.6806E+00 0.6806E+00 1.0000 -0.167 daphnite 0.3045E+00 0.3045E+00 1.0000 -0.516 chlorite-Mn 0.1487E-01 0.1487E-01 1.0000 -1.828 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 40.396257 g Volume = 16.742993 cm3 Porosity: -5.9710% V(tot) - V(min): -.94339E+00 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 36.9990000 g log = 1.5682 Original solution: 1000.0103000 g Original solution / Rock added: 27.03 (Water/Rock Ratio), log = 1.4318 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0203 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.1000E+01 0.9860 0.1006E+01 0.1020E+01 CO2,gas 0.1452E-06 1.0071 0.1492E-06 0.1482E-06 CH4,gas 0.5218E-12 1.0125 0.5391E-12 0.5324E-12 H2,gas 0.1351E-04 1.0005 0.1379E-04 0.1378E-04 H2S,gas 0.1041E-10 0.9960 0.1058E-10 0.1062E-10 S2,gas 0.2164E-31 1.0000 0.2208E-31 0.2208E-31 CO,gas 0.5375E-15 1.0000 0.5485E-15 0.5485E-15 SO3,gas 0.7988E-40 1.0000 0.8150E-40 0.8150E-40 SO2,gas 0.4286E-22 1.0000 0.4373E-22 0.4373E-22 HCl,gas 0.4500E-17 1.0000 0.4592E-17 0.4592E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 16 albite -0.38 -0.38 0.00 0.000 -0.94784E-12 22 andradite 39.01 39.01 0.00 0.000 -0.12132E-10 23 grossular 32.73 32.73 0.00 0.000 0.12132E-10 32 apatite-OH -18.15 -18.15 0.00 0.000 0.12132E-10 46 clinochlore 39.07 39.07 0.00 0.000 0.00000E+00 47 daphnite 28.97 28.97 0.00 0.000 0.00000E+00 48 chlorite-Mn 46.87 46.87 0.00 0.000 0.12132E-10 116 microcline -2.49 -2.49 0.00 0.000 0.15165E-11 163 stilbite -7.52 -7.52 0.00 0.000 0.15165E-10 164 stilpnomelane-Fe 13.02 13.02 0.00 0.000 0.69761E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -15.19 -8.53 -2.842 0.14556E+05 -6.826 3 CH4,gas 4.54 -9.42 -13.97 -3.492 0.23849E+05 -12.268 4 H2,gas 8.00 1.44 -6.56 -3.748 0.11200E+05 -4.860 5 H2S,gas -6.23 -18.90 -12.67 -6.337 0.21641E+05 -10.976 6 S2,gas -7.34 -40.69 -33.35 -5.132 0.56953E+05 -31.656 7 CO,gas 3.21 -13.74 -16.96 -5.218 0.28958E+05 -15.261 8 SO3,gas 17.12 -24.67 -41.79 -10.447 0.71352E+05 -40.089 9 SO2,gas 0.83 -23.23 -24.06 -6.416 0.41079E+05 -22.359 10 HCl,gas 5.19 -13.85 -19.04 -9.518 0.32505E+05 -17.338 11 acmite 7.71 7.31 -0.40 -0.041 0.68089E+03 15 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 19 spessartine 24.46 19.92 -4.54 -0.227 0.77556E+04 20 analcite 3.32 2.87 -0.45 -0.050 0.77311E+03 26 annite 20.12 17.43 -2.70 -0.150 0.46028E+04 27 phlogopite 27.06 24.54 -2.53 -0.140 0.43142E+04 29 anorthite 12.71 8.74 -3.97 -0.305 0.67746E+04 35 aragonite 0.97 -2.89 -3.86 -1.285 0.65827E+04 36 brucite 12.57 9.01 -3.56 -0.712 0.60793E+04 37 calcite 0.81 -2.89 -3.70 -1.234 0.63185E+04 38 carnegieite-low 9.02 6.12 -2.90 -0.414 0.49538E+04 39 carnegieite-high 10.09 6.12 -3.97 -0.567 0.67808E+04 40 carpholite-Mg 8.58 5.45 -3.13 -0.209 0.53407E+04 41 carpholite-Fe 6.71 3.08 -3.63 -0.242 0.61955E+04 42 celadonite 5.34 3.27 -2.07 -0.122 0.35394E+04 43 celadonite-Fe 3.88 0.90 -2.98 -0.175 0.50847E+04 44 chrysotile 23.89 20.52 -3.37 -0.281 0.57607E+04 50 chloritoid-Mg 13.20 8.71 -4.49 -0.299 0.76674E+04 51 chloritoid-Fe 9.17 6.34 -2.84 -0.189 0.48432E+04 52 chloritoid-Mn 11.40 8.61 -2.79 -0.186 0.47718E+04 54 coesite -2.38 -3.25 -0.88 -0.292 0.14973E+04 61 cristobalite -2.56 -3.25 -0.69 -0.231 0.11826E+04 63 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71234E+04 65 diaspore 2.87 1.48 -1.40 -0.233 0.23865E+04 67 diopside 16.18 14.80 -1.38 -0.138 0.23606E+04 68 hedenbergite 14.21 12.43 -1.78 -0.178 0.30385E+04 75 epidote 24.67 23.70 -0.97 -0.047 0.16490E+04 76 clinozoisite 22.81 19.26 -3.54 -0.161 0.60508E+04 77 epidote-Fe 29.84 28.15 -1.69 -0.088 0.28938E+04 78 fayalite 14.05 10.02 -4.02 -0.575 0.68684E+04 79 ferrosilite 11.15 6.77 -4.38 -0.438 0.74774E+04 83 gibbsite 4.08 1.48 -2.60 -0.372 0.44451E+04 84 glaucophane 22.97 19.75 -3.22 -0.087 0.55048E+04 85 glaucophane-Fe 17.28 12.64 -4.64 -0.125 0.79145E+04 87 greenalite 16.14 13.41 -2.73 -0.228 0.46634E+04 90 hematite 12.57 11.84 -0.73 -0.089 0.12472E+04 91 heulandite -5.83 -7.52 -1.69 -0.077 0.28938E+04 95 jadeite 4.22 2.87 -1.35 -0.135 0.22986E+04 96 julgoldite 70.43 66.62 -3.81 -0.099 0.65067E+04 97 kalsilite 7.58 4.02 -3.56 -0.509 0.60863E+04 98 kaolinite -1.33 -3.55 -2.22 -0.202 0.37925E+04 101 laumontite 2.88 2.24 -0.65 -0.043 0.11041E+04 102 lawsonite 9.62 8.74 -0.87 -0.058 0.14913E+04 103 leucite 4.12 0.77 -3.35 -0.335 0.57241E+04 105 lizardite 23.24 20.52 -2.73 -0.227 0.46533E+04 107 magnetite 20.09 18.47 -1.61 -0.132 0.27552E+04 108 minnesotaite 10.39 6.90 -3.49 -0.205 0.59517E+04 120 muscovite 2.58 0.47 -2.12 -0.125 0.36146E+04 121 paragonite 4.24 2.57 -1.67 -0.098 0.28537E+04 122 nepheline 8.34 6.12 -2.22 -0.317 0.37862E+04 128 periclase-Fe 11.63 6.64 -4.99 -1.247 0.85177E+04 134 phlogopite-Na 29.65 26.64 -3.01 -0.167 0.51330E+04 136 prehnite 19.37 17.79 -1.59 -0.093 0.27074E+04 137 prehnite-Fe 22.50 22.23 -0.27 -0.016 0.46052E+03 138 pumpellyite-Fe 46.27 43.69 -2.58 -0.057 0.44100E+04 139 pumpellyite-Mg 48.99 46.06 -2.94 -0.065 0.50168E+04 145 pyroxmangite 7.40 5.65 -1.74 -0.349 0.29783E+04 146 pyrophyllite -6.18 -10.06 -3.88 -0.243 0.66318E+04 147 quartz -2.99 -3.25 -0.26 -0.088 0.44994E+03 152 rhodonite 7.45 5.65 -1.79 -0.358 0.30586E+04 153 sanidine -1.28 -2.49 -1.21 -0.093 0.20677E+04 165 stilpnomelane-Mg 27.44 24.87 -2.57 -0.077 0.43951E+04 171 talc 16.49 14.01 -2.48 -0.146 0.42318E+04 174 tephroite 18.09 14.56 -3.52 -0.503 0.60172E+04 177 topaz-H 4.62 -0.30 -4.92 -0.447 0.83998E+04 178 tridymite -2.63 -3.25 -0.63 -0.209 0.10699E+04 179 tremolite 47.87 43.61 -4.26 -0.115 0.72720E+04 187 wairakite 3.95 2.24 -1.71 -0.101 0.29261E+04 188 walstromite 11.51 9.04 -2.47 -0.493 0.42100E+04 189 wollastonite 10.46 9.04 -1.42 -0.284 0.24204E+04 190 pseudo-wollastonite 11.00 9.04 -1.96 -0.391 0.33402E+04 191 zoisite 22.85 19.26 -3.59 -0.163 0.61249E+04 192 akaganeite 7.75 5.92 -1.84 -0.397 0.31362E+04 193 beidellite-Ca -1.65 -6.47 -4.82 -0.298 0.82380E+04 197 beidellite-Na -1.34 -5.89 -4.55 -0.279 0.77696E+04 199 chalcedony -2.80 -3.25 -0.45 -0.150 0.76923E+03 201 montmorillonite-Ca -2.29 -5.55 -3.25 -0.201 0.55570E+04 202 montmorillonite-K -2.24 -5.66 -3.42 -0.210 0.58475E+04 203 montmorillonite-Mg -2.48 -6.09 -3.61 -0.223 0.61605E+04 204 montmorillonite-Na -2.04 -4.97 -2.93 -0.179 0.50024E+04 205 nontronite-Ca 3.21 2.41 -0.80 -0.052 0.13679E+04 206 nontronite-H 2.53 0.38 -2.15 -0.144 0.36680E+04 207 nontronite-K 3.34 2.30 -1.04 -0.067 0.17816E+04 208 nontronite-Mg 3.07 1.87 -1.20 -0.078 0.20554E+04 209 nontronite-Na 3.52 2.99 -0.53 -0.034 0.90247E+03 224 tobermorite 9.82 6.99 -2.83 -0.773 0.48372E+04 233 boehmite 4.41 1.48 -2.93 -0.488 0.50034E+04 235 ferrous-oxide 9.81 6.64 -3.17 -0.793 0.54187E+04 240 silica-amorphous -2.09 -3.25 -1.16 -0.387 0.19834E+04 242 an20ab80 2.02 1.44 -0.58 -0.044 0.98408E+03 243 an25ab75 2.65 1.90 -0.75 -0.058 0.12771E+04 244 an30ab70 3.28 2.35 -0.93 -0.071 0.15797E+04 245 tr.625ac.25prg.125 45.16 41.88 -3.29 -0.089 0.56158E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 1.0000000 g Current total amount of reactant added: 36.9990000 g New total amount of reactant added: 37.9990000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.2996E-12 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 7 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 37.9990000 Water: Moles liquid = 0.5525E+02 kg liquid = 0.9953E+00 Moles total = 0.5503E+02 kg total = 0.9914E+00 Activity = 1.0000 Stoichiometric ionic strength = .6143261E-02 Osmotic coef. = 0.9589 True ionic strength = .1117962E-01 Chg. balance for total moles = 0.2996E-12 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.13416E-09 -9.8724 0.11654E-09 -9.9335 0.86867E+00 -0.0611 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13824E-03 -3.8594 0.11964E-03 -3.9221 0.86541E+00 -0.0628 4 SO4-- 0.25600E-04 -4.5918 0.15265E-04 -4.8163 0.59629E+00 -0.2245 5 HCO3- 0.62811E-05 -5.2020 0.54407E-05 -5.2643 0.86619E+00 -0.0624 6 HS- 0.30912E-08 -8.5099 0.26754E-08 -8.5726 0.86549E+00 -0.0627 7 Al+++ 0.14311E-27 -27.8443 0.45351E-28 -28.3434 0.31689E+00 -0.4991 8 H4SiO4 0.56002E-03 -3.2518 0.56002E-03 -3.2518 0.10000E+01 0.0000 9 Ca++ 0.48509E-07 -7.3142 0.28794E-07 -7.5407 0.59358E+00 -0.2265 10 Mg++ 0.23820E-10 -10.6231 0.14099E-10 -10.8508 0.59189E+00 -0.2278 11 Fe++ 0.10062E-12 -12.9973 0.59598E-13 -13.2248 0.59229E+00 -0.2275 12 K+ 0.87217E-04 -4.0594 0.75558E-04 -4.1217 0.86633E+00 -0.0623 13 Na+ 0.11059E-01 -1.9563 0.95700E-02 -2.0191 0.86532E+00 -0.0628 14 Mn++ 0.18863E-10 -10.7244 0.11178E-10 -10.9516 0.59260E+00 -0.2272 15 HPO4-- 0.31369E-06 -6.5035 0.18706E-06 -6.7280 0.59634E+00 -0.2245 16 HSiO3- 0.51846E-02 -2.2853 0.44868E-02 -2.3481 0.86541E+00 -0.0628 17 Ca(HSiO3)+ 0.33957E-08 -8.4691 0.29422E-08 -8.5313 0.86644E+00 -0.0623 18 Mg(HSiO3)+ 0.20692E-11 -11.6842 0.17929E-11 -11.7465 0.86644E+00 -0.0623 19 NaHSiO3,aq 0.69447E-03 -3.1583 0.69447E-03 -3.1583 0.10000E+01 0.0000 20 AlO+ 0.52425E-15 -15.2805 0.45423E-15 -15.3427 0.86644E+00 -0.0623 22 HAlO2,aq 0.77618E-09 -9.1100 0.77618E-09 -9.1100 0.10000E+01 0.0000 23 AlO2- 0.17054E-04 -4.7682 0.14742E-04 -4.8314 0.86443E+00 -0.0633 24 CH4,aq 0.92801E-15 -15.0324 0.92625E-15 -15.0333 0.99811E+00 -0.0008 29 CO,aq 0.45417E-18 -18.3428 0.45417E-18 -18.3428 0.10000E+01 0.0000 30 CO2,aq 0.13574E-08 -8.8673 0.13549E-08 -8.8681 0.99811E+00 -0.0008 31 CO3-2 0.68474E-05 -5.1645 0.40776E-05 -5.3896 0.59550E+00 -0.2251 32 CaCO3,aq 0.14722E-08 -8.8320 0.14722E-08 -8.8320 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.46153E-11 -11.3358 0.39989E-11 -11.3981 0.86644E+00 -0.0623 34 CaCl+ 0.64340E-11 -11.1915 0.55747E-11 -11.2538 0.86644E+00 -0.0623 35 CaCl2,aq 0.15845E-15 -15.8001 0.15845E-15 -15.8001 0.10000E+01 0.0000 36 CaOH+ 0.20322E-07 -7.6920 0.17608E-07 -7.7543 0.86644E+00 -0.0623 37 CaSO4,aq 0.13958E-09 -9.8552 0.13958E-09 -9.8552 0.10000E+01 0.0000 38 HCl,aq 0.25550E-14 -14.5926 0.25550E-14 -14.5926 0.10000E+01 0.0000 43 FeCl+ 0.13025E-16 -16.8852 0.11286E-16 -16.9475 0.86644E+00 -0.0623 46 FeO,aq 0.17053E-09 -9.7682 0.17053E-09 -9.7682 0.10000E+01 0.0000 47 FeOH+ 0.19212E-10 -10.7164 0.16646E-10 -10.7787 0.86644E+00 -0.0623 48 HFeO2- 0.17691E-07 -7.7522 0.15310E-07 -7.8150 0.86541E+00 -0.0628 49 FeO+ 0.39669E-15 -15.4016 0.34371E-15 -15.4638 0.86644E+00 -0.0623 51 FeO2- 0.59832E-08 -8.2231 0.51779E-08 -8.2858 0.86541E+00 -0.0628 52 HFeO2,aq 0.76751E-10 -10.1149 0.76751E-10 -10.1149 0.10000E+01 0.0000 53 H2,aq 0.13369E-07 -7.8739 0.13344E-07 -7.8747 0.99811E+00 -0.0008 54 KCl,aq 0.16383E-09 -9.7856 0.16383E-09 -9.7856 0.10000E+01 0.0000 55 KHSO4,aq 0.38007E-18 -18.4201 0.38007E-18 -18.4201 0.10000E+01 0.0000 56 KOH,aq 0.27687E-06 -6.5577 0.27687E-06 -6.5577 0.10000E+01 0.0000 57 KSO4- 0.20682E-07 -7.6844 0.17898E-07 -7.7472 0.86541E+00 -0.0628 58 MgCO3,aq 0.18068E-12 -12.7431 0.18068E-12 -12.7431 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.23091E-14 -14.6366 0.20007E-14 -14.6988 0.86644E+00 -0.0623 60 MgCl+ 0.28553E-14 -14.5443 0.24740E-14 -14.6066 0.86644E+00 -0.0623 61 MgOH+ 0.55061E-10 -10.2592 0.47708E-10 -10.3214 0.86644E+00 -0.0623 63 MnO,aq 0.85228E-09 -9.0694 0.85228E-09 -9.0694 0.10000E+01 0.0000 64 MnOH+ 0.33474E-09 -9.4753 0.29003E-09 -9.5376 0.86644E+00 -0.0623 65 MnO2-2 0.34969E-11 -11.4563 0.20824E-11 -11.6814 0.59550E+00 -0.2251 66 HMnO2- 0.61440E-10 -10.2116 0.53170E-10 -10.2743 0.86541E+00 -0.0628 69 MnCl+ 0.95045E-14 -14.0221 0.82351E-14 -14.0843 0.86644E+00 -0.0623 70 MnSO4,aq 0.49261E-13 -13.3075 0.49261E-13 -13.3075 0.10000E+01 0.0000 71 NaCl,aq 0.37942E-06 -6.4209 0.37942E-06 -6.4209 0.10000E+01 0.0000 72 NaOH,aq 0.35280E-04 -4.4525 0.35280E-04 -4.4525 0.10000E+01 0.0000 74 OH- 0.57350E-02 -2.2415 0.49575E-02 -2.3047 0.86443E+00 -0.0633 79 HPO3-2 0.13063E-16 -16.8840 0.77789E-17 -17.1091 0.59550E+00 -0.2251 82 H3PO4,aq 0.17770E-16 -16.7503 0.17770E-16 -16.7503 0.10000E+01 0.0000 83 H2PO4- 0.46445E-09 -9.3331 0.40218E-09 -9.3956 0.86592E+00 -0.0625 84 PO4-3 0.40082E-08 -8.3971 0.13096E-08 -8.8829 0.32673E+00 -0.4858 87 H2P2O7-2 0.21297E-19 -19.6717 0.12682E-19 -19.8968 0.59550E+00 -0.2251 88 HP2O7-3 0.68535E-16 -16.1641 0.21729E-16 -16.6630 0.31705E+00 -0.4989 89 P2O7-4 0.33302E-15 -15.4775 0.44541E-16 -16.3512 0.13375E+00 -0.8737 90 H2S,aq 0.96549E-12 -12.0153 0.96367E-12 -12.0161 0.99811E+00 -0.0008 91 S2-2 0.19959E-19 -19.6999 0.11886E-19 -19.9250 0.59550E+00 -0.2251 97 SO3-2 0.44053E-13 -13.3560 0.26470E-13 -13.5772 0.60087E+00 -0.2212 98 HSO3- 0.22320E-15 -15.6513 0.19316E-15 -15.7141 0.86541E+00 -0.0628 99 HSO4- 0.19776E-11 -11.7039 0.17145E-11 -11.7659 0.86696E+00 -0.0620 101 S2O3-2 0.29018E-18 -18.5373 0.17280E-18 -18.7625 0.59550E+00 -0.2251 Charge balance for all species = 0.3079E-12 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.1341649E-09 -.1172484E-01 -.1180747E+02 0.0000 2 H2O 0.1000000E+01 0.5550818E+02 0.9991106E+06 0.0000 3 Cl- 0.1382418E-03 0.1386214E-03 0.4910190E+01 6.0114 4 SO4-- 0.2560019E-04 0.2561843E-04 0.2458767E+01 15.0507 5 HCO3- 0.6281123E-05 0.1313131E-04 0.8005259E+00 4.6692 6 HS- 0.3091210E-08 0.5676977E-08 0.1875827E-03 1.3609 7 Al+++ 0.1431134E-27 0.1705524E-04 0.4597684E+00 1.4571 8 H4SiO4 0.5600170E-03 0.6439087E-02 0.6183472E+03 -3.2518 9 Ca++ 0.4850908E-07 0.7384991E-07 0.2957135E-02 12.3263 10 Mg++ 0.2381974E-10 0.8113628E-10 0.1970838E-05 9.0162 11 Fe++ 0.1006230E-12 0.2394117E-07 0.1335858E-02 6.6422 12 K+ 0.8721689E-04 0.8751461E-04 0.3418965E+01 5.8118 13 Na+ 0.1105946E-01 0.1178959E-01 0.2708003E+03 7.9144 14 Mn++ 0.1886311E-10 0.1270874E-08 0.6975740E-04 8.9154 15 HPO4-- 0.3136872E-06 0.3181598E-06 0.3050961E-01 13.1390 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.6291940E+00 -.1167010E-01 -.6175239E+00 0.0000000E+00 2 H2O 0.5503192E+02 0.5524902E+02 -.2171003E+00 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.1078586E-02 0.2549882E-04 0.1053087E-02 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.1053082E-02 0.5650472E-08 -.1053087E-02 0.0000000E+00 7 Al+++ 0.1239049E+00 0.1697562E-04 0.1238879E+00 0.0000000E+00 8 H4SiO4 0.3956753E+00 0.6409024E-02 0.3892663E+00 0.0000000E+00 9 Ca++ 0.4371874E-01 0.7350512E-07 0.4371867E-01 0.0000000E+00 10 Mg++ 0.3015794E-01 0.8075747E-10 0.3015794E-01 0.0000000E+00 11 Fe++ 0.2709361E-01 0.2382940E-07 0.2709359E-01 0.0000000E+00 12 K+ 0.8067728E-02 0.8710602E-04 0.7980622E-02 0.0000000E+00 13 Na+ 0.4785807E-01 0.1173455E-01 0.3612353E-01 0.0000000E+00 14 Mn++ 0.6588493E-03 0.1264940E-08 0.6588480E-03 0.0000000E+00 15 HPO4-- 0.2248620E-03 0.3166744E-06 0.2245453E-03 0.0000000E+00 Chg. balance for solid moles: 0.6928E-16 Mass of aqueous solution: 0.996214E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 37.9990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 0.3612E-01 -1.442 9.472 0.976 22.83 3.636 andradite 0.4212E-02 -2.375 2.141 0.331 5.160 0.5562 grossular 0.2240E-03 -3.650 0.1009 -0.996 0.2432 0.2807E-01 apatite-OH 0.7485E-04 -4.126 0.3760E-01 -1.425 0.9062E-01 0.1195E-01 clinochlore 0.6032E-02 -2.220 3.353 0.525 8.081 1.275 daphnite 0.2675E-02 -2.573 1.909 0.281 4.601 0.5784 chlorite-Mn 0.1318E-03 -3.880 0.9342E-01 -1.030 0.2252 0.2977E-01 microcline 0.7451E-02 -2.128 2.074 0.317 4.999 0.8102 stilbite 0.3004E-01 -1.522 21.17 1.326 51.02 9.872 stilpnomelane-Fe 0.1059E-02 -2.975 1.141 0.057 2.751 0.3942 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.9495E+00 0.9495E+00 1.0000 -0.022 grossular 0.5049E-01 0.5049E-01 1.0000 -1.297 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.6824E+00 0.6824E+00 1.0000 -0.166 daphnite 0.3027E+00 0.3027E+00 1.0000 -0.519 chlorite-Mn 0.1491E-01 0.1491E-01 1.0000 -1.827 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 41.487911 g Volume = 17.192593 cm3 Porosity: -6.1297% V(tot) - V(min): -.99299E+00 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 37.9990000 g log = 1.5798 Original solution: 1000.0103000 g Original solution / Rock added: 26.32 (Water/Rock Ratio), log = 1.4202 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0203 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.1000E+01 0.9860 0.1006E+01 0.1020E+01 CO2,gas 0.1411E-06 1.0071 0.1450E-06 0.1439E-06 CH4,gas 0.1320E-11 1.0125 0.1363E-11 0.1347E-11 H2,gas 0.1716E-04 1.0005 0.1752E-04 0.1751E-04 H2S,gas 0.2607E-10 0.9960 0.2649E-10 0.2660E-10 S2,gas 0.8412E-31 1.0000 0.8583E-31 0.8583E-31 CO,gas 0.6633E-15 1.0000 0.6768E-15 0.6768E-15 SO3,gas 0.7684E-40 1.0000 0.7840E-40 0.7840E-40 SO2,gas 0.5237E-22 1.0000 0.5343E-22 0.5343E-22 HCl,gas 0.4419E-17 1.0000 0.4508E-17 0.4508E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 16 albite -0.38 -0.38 0.00 0.000 -0.94784E-12 22 andradite 39.01 39.01 0.00 0.000 -0.24265E-10 23 grossular 32.73 32.73 0.00 0.000 -0.24265E-10 32 apatite-OH -18.15 -18.15 0.00 0.000 -0.60662E-11 46 clinochlore 39.07 39.07 0.00 0.000 -0.12132E-10 47 daphnite 28.97 28.97 0.00 0.000 -0.60662E-11 48 chlorite-Mn 46.87 46.87 0.00 0.000 0.00000E+00 116 microcline -2.49 -2.49 0.00 0.000 0.15165E-11 163 stilbite -7.52 -7.52 0.00 0.000 -0.90992E-11 164 stilpnomelane-Fe 13.02 13.02 0.00 0.000 -0.27298E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -15.20 -8.54 -2.846 0.14578E+05 -6.839 3 CH4,gas 4.54 -9.02 -13.56 -3.391 0.23161E+05 -11.865 4 H2,gas 8.00 1.54 -6.46 -3.689 0.11023E+05 -4.756 5 H2S,gas -6.23 -18.51 -12.28 -6.138 0.20961E+05 -10.577 6 S2,gas -7.34 -40.10 -32.77 -5.041 0.55946E+05 -31.066 7 CO,gas 3.21 -13.65 -16.87 -5.190 0.28803E+05 -15.170 8 SO3,gas 17.12 -24.68 -41.80 -10.451 0.71380E+05 -40.106 9 SO2,gas 0.83 -23.14 -23.97 -6.392 0.40930E+05 -22.272 10 HCl,gas 5.19 -13.86 -19.04 -9.522 0.32519E+05 -17.346 11 acmite 7.71 7.28 -0.43 -0.045 0.73215E+03 15 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 19 spessartine 24.46 19.90 -4.55 -0.228 0.77730E+04 20 analcite 3.32 2.87 -0.45 -0.050 0.77507E+03 26 annite 20.12 17.44 -2.68 -0.149 0.45814E+04 27 phlogopite 27.06 24.56 -2.50 -0.139 0.42730E+04 29 anorthite 12.71 8.74 -3.97 -0.306 0.67844E+04 35 aragonite 0.97 -2.87 -3.84 -1.279 0.65534E+04 36 brucite 12.57 9.02 -3.55 -0.710 0.60656E+04 37 calcite 0.81 -2.87 -3.68 -1.228 0.62892E+04 38 carnegieite-low 9.02 6.12 -2.90 -0.415 0.49578E+04 39 carnegieite-high 10.09 6.12 -3.97 -0.568 0.67848E+04 40 carpholite-Mg 8.58 5.43 -3.16 -0.210 0.53875E+04 41 carpholite-Fe 6.71 3.05 -3.66 -0.244 0.62489E+04 42 celadonite 5.34 3.28 -2.06 -0.121 0.35237E+04 43 celadonite-Fe 3.88 0.90 -2.97 -0.175 0.50756E+04 44 chrysotile 23.89 20.54 -3.35 -0.279 0.57156E+04 50 chloritoid-Mg 13.20 8.68 -4.52 -0.301 0.77162E+04 51 chloritoid-Fe 9.17 6.30 -2.87 -0.191 0.48987E+04 52 chloritoid-Mn 11.40 8.58 -2.82 -0.188 0.48206E+04 54 coesite -2.38 -3.25 -0.88 -0.292 0.14953E+04 61 cristobalite -2.56 -3.25 -0.69 -0.230 0.11806E+04 63 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71234E+04 65 diaspore 2.87 1.46 -1.42 -0.236 0.24188E+04 67 diopside 16.18 14.84 -1.34 -0.134 0.22922E+04 68 hedenbergite 14.21 12.46 -1.74 -0.174 0.29767E+04 75 epidote 24.67 23.68 -0.99 -0.048 0.16876E+04 76 clinozoisite 22.81 19.27 -3.54 -0.161 0.60401E+04 77 epidote-Fe 29.84 28.09 -1.75 -0.091 0.29817E+04 78 fayalite 14.05 10.03 -4.01 -0.573 0.68521E+04 79 ferrosilite 11.15 6.78 -4.37 -0.437 0.74592E+04 83 gibbsite 4.08 1.46 -2.62 -0.375 0.44773E+04 84 glaucophane 22.97 19.78 -3.20 -0.086 0.54597E+04 85 glaucophane-Fe 17.28 12.66 -4.62 -0.125 0.78892E+04 87 greenalite 16.14 13.42 -2.72 -0.226 0.46381E+04 90 hematite 12.57 11.74 -0.83 -0.100 0.14103E+04 91 heulandite -5.83 -7.52 -1.69 -0.077 0.28938E+04 95 jadeite 4.22 2.87 -1.35 -0.135 0.23006E+04 96 julgoldite 70.43 66.56 -3.87 -0.100 0.66037E+04 97 kalsilite 7.58 4.02 -3.57 -0.510 0.60902E+04 98 kaolinite -1.33 -3.59 -2.26 -0.205 0.38531E+04 101 laumontite 2.88 2.23 -0.65 -0.043 0.11100E+04 102 lawsonite 9.62 8.74 -0.88 -0.059 0.15011E+04 103 leucite 4.12 0.77 -3.35 -0.335 0.57261E+04 105 lizardite 23.24 20.54 -2.70 -0.225 0.46082E+04 107 magnetite 20.09 18.38 -1.70 -0.139 0.29111E+04 108 minnesotaite 10.39 6.92 -3.47 -0.204 0.59225E+04 120 muscovite 2.58 0.43 -2.15 -0.127 0.36791E+04 121 paragonite 4.24 2.53 -1.71 -0.101 0.29182E+04 122 nepheline 8.34 6.12 -2.22 -0.317 0.37901E+04 128 periclase-Fe 11.63 6.64 -4.98 -1.246 0.85106E+04 134 phlogopite-Na 29.65 26.66 -2.98 -0.166 0.50918E+04 136 prehnite 19.37 17.81 -1.56 -0.092 0.26644E+04 137 prehnite-Fe 22.50 22.22 -0.27 -0.016 0.46685E+03 138 pumpellyite-Fe 46.27 43.72 -2.55 -0.057 0.43492E+04 139 pumpellyite-Mg 48.99 46.10 -2.90 -0.064 0.49494E+04 145 pyroxmangite 7.40 5.66 -1.74 -0.347 0.29626E+04 146 pyrophyllite -6.18 -10.09 -3.92 -0.245 0.66885E+04 147 quartz -2.99 -3.25 -0.26 -0.087 0.44798E+03 152 rhodonite 7.45 5.66 -1.78 -0.356 0.30429E+04 153 sanidine -1.28 -2.49 -1.21 -0.093 0.20677E+04 165 stilpnomelane-Mg 27.44 24.89 -2.55 -0.076 0.43621E+04 171 talc 16.49 14.04 -2.45 -0.144 0.41828E+04 174 tephroite 18.09 14.58 -3.51 -0.501 0.59878E+04 177 topaz-H 4.62 -0.34 -4.96 -0.451 0.84623E+04 178 tridymite -2.63 -3.25 -0.63 -0.208 0.10680E+04 179 tremolite 47.87 43.72 -4.15 -0.112 0.70861E+04 187 wairakite 3.95 2.23 -1.72 -0.101 0.29319E+04 188 walstromite 11.51 9.07 -2.43 -0.487 0.41572E+04 189 wollastonite 10.46 9.07 -1.39 -0.277 0.23676E+04 190 pseudo-wollastonite 11.00 9.07 -1.93 -0.385 0.32875E+04 191 zoisite 22.85 19.27 -3.58 -0.163 0.61142E+04 192 akaganeite 7.75 5.87 -1.88 -0.407 0.32177E+04 193 beidellite-Ca -1.65 -6.51 -4.86 -0.301 0.82976E+04 197 beidellite-Na -1.34 -5.93 -4.59 -0.281 0.78288E+04 199 chalcedony -2.80 -3.25 -0.45 -0.150 0.76728E+03 201 montmorillonite-Ca -2.29 -5.56 -3.27 -0.203 0.55901E+04 202 montmorillonite-K -2.24 -5.68 -3.44 -0.211 0.58803E+04 203 montmorillonite-Mg -2.48 -6.11 -3.63 -0.225 0.61997E+04 204 montmorillonite-Na -2.04 -4.99 -2.95 -0.181 0.50352E+04 205 nontronite-Ca 3.21 2.32 -0.89 -0.058 0.15261E+04 206 nontronite-H 2.53 0.29 -2.25 -0.151 0.38346E+04 207 nontronite-K 3.34 2.20 -1.14 -0.073 0.19395E+04 208 nontronite-Mg 3.07 1.77 -1.30 -0.084 0.22197E+04 209 nontronite-Na 3.52 2.90 -0.62 -0.040 0.10603E+04 224 tobermorite 9.82 7.02 -2.81 -0.766 0.47929E+04 233 boehmite 4.41 1.46 -2.95 -0.492 0.50357E+04 235 ferrous-oxide 9.81 6.64 -3.17 -0.792 0.54116E+04 240 silica-amorphous -2.09 -3.25 -1.16 -0.387 0.19815E+04 242 an20ab80 2.02 1.44 -0.58 -0.044 0.98604E+03 243 an25ab75 2.65 1.90 -0.75 -0.058 0.12795E+04 244 an30ab70 3.28 2.35 -0.93 -0.071 0.15826E+04 245 tr.625ac.25prg.125 45.16 41.97 -3.19 -0.086 0.54491E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 1.0000000 g Current total amount of reactant added: 37.9990000 g New total amount of reactant added: 38.9990000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.2995E-12 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 7 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 38.9990000 Water: Moles liquid = 0.5524E+02 kg liquid = 0.9952E+00 Moles total = 0.5502E+02 kg total = 0.9912E+00 Activity = 1.0000 Stoichiometric ionic strength = .6259183E-02 Osmotic coef. = 0.9586 True ionic strength = .1138802E-01 Chg. balance for total moles = 0.2995E-12 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.13209E-09 -9.8791 0.11463E-09 -9.9407 0.86783E+00 -0.0616 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13825E-03 -3.8593 0.11952E-03 -3.9226 0.86453E+00 -0.0632 4 SO4-- 0.25598E-04 -4.5918 0.15204E-04 -4.8181 0.59393E+00 -0.2263 5 HCO3- 0.62179E-05 -5.2064 0.53805E-05 -5.2692 0.86532E+00 -0.0628 6 HS- 0.75750E-08 -8.1206 0.65494E-08 -8.1838 0.86461E+00 -0.0632 7 Al+++ 0.13169E-27 -27.8805 0.41354E-28 -28.3835 0.31403E+00 -0.5030 8 H4SiO4 0.56162E-03 -3.2506 0.56162E-03 -3.2506 0.10000E+01 0.0000 9 Ca++ 0.50296E-07 -7.2985 0.29734E-07 -7.5267 0.59119E+00 -0.2283 10 Mg++ 0.23560E-10 -10.6278 0.13888E-10 -10.8574 0.58948E+00 -0.2295 11 Fe++ 0.98635E-13 -13.0060 0.58183E-13 -13.2352 0.58988E+00 -0.2292 12 K+ 0.88845E-04 -4.0514 0.76892E-04 -4.1141 0.86546E+00 -0.0628 13 Na+ 0.11266E-01 -1.9482 0.97389E-02 -2.0115 0.86444E+00 -0.0633 14 Mn++ 0.18657E-10 -10.7292 0.11011E-10 -10.9582 0.59019E+00 -0.2290 15 HPO4-- 0.29199E-06 -6.5346 0.17344E-06 -6.7609 0.59398E+00 -0.2262 16 HSiO3- 0.52916E-02 -2.2764 0.45747E-02 -2.3396 0.86453E+00 -0.0632 17 Ca(HSiO3)+ 0.35789E-08 -8.4462 0.30978E-08 -8.5089 0.86558E+00 -0.0627 18 Mg(HSiO3)+ 0.20803E-11 -11.6819 0.18007E-11 -11.7446 0.86558E+00 -0.0627 19 NaHSiO3,aq 0.72058E-03 -3.1423 0.72058E-03 -3.1423 0.10000E+01 0.0000 20 AlO+ 0.49462E-15 -15.3057 0.42814E-15 -15.3684 0.86558E+00 -0.0627 22 HAlO2,aq 0.74379E-09 -9.1285 0.74379E-09 -9.1285 0.10000E+01 0.0000 23 AlO2- 0.16633E-04 -4.7790 0.14363E-04 -4.8428 0.86353E+00 -0.0637 24 CH4,aq 0.22558E-14 -14.6467 0.22515E-14 -14.6475 0.99808E+00 -0.0008 29 CO,aq 0.55544E-18 -18.2554 0.55544E-18 -18.2554 0.10000E+01 0.0000 30 CO2,aq 0.13204E-08 -8.8793 0.13179E-08 -8.8801 0.99808E+00 -0.0008 31 CO3-2 0.69121E-05 -5.1604 0.40998E-05 -5.3872 0.59313E+00 -0.2269 32 CaCO3,aq 0.15285E-08 -8.8157 0.15285E-08 -8.8157 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.47180E-11 -11.3262 0.40838E-11 -11.3889 0.86558E+00 -0.0627 34 CaCl+ 0.66445E-11 -11.1775 0.57514E-11 -11.2402 0.86558E+00 -0.0627 35 CaCl2,aq 0.16331E-15 -15.7870 0.16331E-15 -15.7870 0.10000E+01 0.0000 36 CaOH+ 0.21358E-07 -7.6704 0.18487E-07 -7.7331 0.86558E+00 -0.0627 37 CaSO4,aq 0.14355E-09 -9.8430 0.14355E-09 -9.8430 0.10000E+01 0.0000 38 HCl,aq 0.25107E-14 -14.6002 0.25107E-14 -14.6002 0.10000E+01 0.0000 43 FeCl+ 0.12717E-16 -16.8956 0.11007E-16 -16.9583 0.86558E+00 -0.0627 46 FeO,aq 0.17209E-09 -9.7642 0.17209E-09 -9.7642 0.10000E+01 0.0000 47 FeOH+ 0.19088E-10 -10.7192 0.16522E-10 -10.7819 0.86558E+00 -0.0627 48 HFeO2- 0.18169E-07 -7.7407 0.15708E-07 -7.8039 0.86453E+00 -0.0632 49 FeO+ 0.35149E-15 -15.4541 0.30424E-15 -15.5168 0.86558E+00 -0.0627 51 FeO2- 0.54800E-08 -8.2612 0.47376E-08 -8.3244 0.86453E+00 -0.0632 52 HFeO2,aq 0.69072E-10 -10.1607 0.69072E-10 -10.1607 0.10000E+01 0.0000 53 H2,aq 0.16810E-07 -7.7744 0.16777E-07 -7.7753 0.99808E+00 -0.0008 54 KCl,aq 0.16657E-09 -9.7784 0.16657E-09 -9.7784 0.10000E+01 0.0000 55 KHSO4,aq 0.37889E-18 -18.4215 0.37889E-18 -18.4215 0.10000E+01 0.0000 56 KOH,aq 0.28646E-06 -6.5429 0.28646E-06 -6.5429 0.10000E+01 0.0000 57 KSO4- 0.20983E-07 -7.6781 0.18141E-07 -7.7413 0.86453E+00 -0.0632 58 MgCO3,aq 0.17895E-12 -12.7473 0.17895E-12 -12.7473 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.22517E-14 -14.6475 0.19490E-14 -14.7102 0.86558E+00 -0.0627 60 MgCl+ 0.28128E-14 -14.5509 0.24347E-14 -14.6136 0.86558E+00 -0.0627 61 MgOH+ 0.55199E-10 -10.2581 0.47779E-10 -10.3208 0.86558E+00 -0.0627 63 MnO,aq 0.86779E-09 -9.0616 0.86779E-09 -9.0616 0.10000E+01 0.0000 64 MnOH+ 0.33557E-09 -9.4742 0.29046E-09 -9.5369 0.86558E+00 -0.0627 65 MnO2-2 0.36951E-11 -11.4324 0.21917E-11 -11.6592 0.59313E+00 -0.2269 66 HMnO2- 0.63667E-10 -10.1961 0.55042E-10 -10.2593 0.86453E+00 -0.0632 69 MnCl+ 0.93629E-14 -14.0286 0.81043E-14 -14.0913 0.86558E+00 -0.0627 70 MnSO4,aq 0.48330E-13 -13.3158 0.48330E-13 -13.3158 0.10000E+01 0.0000 71 NaCl,aq 0.38576E-06 -6.4137 0.38576E-06 -6.4137 0.10000E+01 0.0000 72 NaOH,aq 0.36502E-04 -4.4377 0.36502E-04 -4.4377 0.10000E+01 0.0000 74 OH- 0.58368E-02 -2.2338 0.50403E-02 -2.2975 0.86353E+00 -0.0637 79 HPO3-2 0.15288E-16 -16.8156 0.90680E-17 -17.0425 0.59313E+00 -0.2269 82 H3PO4,aq 0.15940E-16 -16.7975 0.15940E-16 -16.7975 0.10000E+01 0.0000 83 H2PO4- 0.42398E-09 -9.3727 0.36676E-09 -9.4356 0.86504E+00 -0.0630 84 PO4-3 0.38108E-08 -8.4190 0.12344E-08 -8.9085 0.32394E+00 -0.4895 87 H2P2O7-2 0.17782E-19 -19.7500 0.10547E-19 -19.9769 0.59313E+00 -0.2269 88 HP2O7-3 0.58473E-16 -16.2330 0.18372E-16 -16.7358 0.31420E+00 -0.5028 89 P2O7-4 0.29083E-15 -15.5364 0.38288E-16 -16.4169 0.13165E+00 -0.8806 90 H2S,aq 0.23248E-11 -11.6336 0.23203E-11 -11.6345 0.99808E+00 -0.0008 91 S2-2 0.95513E-19 -19.0199 0.56651E-19 -19.2468 0.59313E+00 -0.2269 97 SO3-2 0.55378E-13 -13.2567 0.33147E-13 -13.4796 0.59856E+00 -0.2229 98 HSO3- 0.27519E-15 -15.5604 0.23791E-15 -15.6236 0.86453E+00 -0.0632 99 HSO4- 0.19392E-11 -11.7124 0.16796E-11 -11.7748 0.86610E+00 -0.0624 101 S2O3-2 0.69866E-18 -18.1557 0.41440E-18 -18.3826 0.59313E+00 -0.2269 Charge balance for all species = 0.3026E-12 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.1320896E-09 -.1195930E-01 -.1204337E+02 0.0000 2 H2O 0.1000000E+01 0.5550814E+02 0.9990925E+06 0.0000 3 Cl- 0.1382518E-03 0.1386377E-03 0.4910681E+01 6.0181 4 SO4-- 0.2559841E-04 0.2561603E-04 0.2458494E+01 15.0633 5 HCO3- 0.6217881E-05 0.1313285E-04 0.8006059E+00 4.6715 6 HS- 0.7574968E-08 0.1108606E-07 0.3663070E-03 1.7569 7 Al+++ 0.1316861E-27 0.1663351E-04 0.4483915E+00 1.4386 8 H4SiO4 0.5616200E-03 0.6573793E-02 0.6312719E+03 -3.2506 9 Ca++ 0.5029620E-07 0.7691617E-07 0.3079861E-02 12.3546 10 Mg++ 0.2355976E-10 0.8102290E-10 0.1968049E-05 9.0240 11 Fe++ 0.9863499E-13 0.2390939E-07 0.1334061E-02 6.6462 12 K+ 0.8884548E-04 0.8915309E-04 0.3482915E+01 5.8266 13 Na+ 0.1126618E-01 0.1202365E-01 0.2761715E+03 7.9292 14 Mn++ 0.1865688E-10 0.1289442E-08 0.7077535E-04 8.9232 15 HPO4-- 0.2919937E-06 0.2962284E-06 0.2840602E-01 13.1205 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.6457525E+00 -.1190206E-01 -.6338504E+00 0.0000000E+00 2 H2O 0.5501938E+02 0.5524249E+02 -.2231078E+00 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.1106300E-02 0.2549344E-04 0.1080806E-02 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.1080795E-02 0.1103301E-07 -.1080806E-02 0.0000000E+00 7 Al+++ 0.1271657E+00 0.1655390E-04 0.1271491E+00 0.0000000E+00 8 H4SiO4 0.4060881E+00 0.6542331E-02 0.3995458E+00 0.0000000E+00 9 Ca++ 0.4486888E-01 0.7654806E-07 0.4486881E-01 0.0000000E+00 10 Mg++ 0.3095159E-01 0.8063513E-10 0.3095159E-01 0.0000000E+00 11 Fe++ 0.2780662E-01 0.2379496E-07 0.2780660E-01 0.0000000E+00 12 K+ 0.8280042E-02 0.8872641E-04 0.8191316E-02 0.0000000E+00 13 Na+ 0.4911332E-01 0.1196610E-01 0.3714721E-01 0.0000000E+00 14 Mn++ 0.6761879E-03 0.1283271E-08 0.6761866E-03 0.0000000E+00 15 HPO4-- 0.2307796E-03 0.2948107E-06 0.2304848E-03 0.0000000E+00 Chg. balance for solid moles: 0.5443E-16 Mass of aqueous solution: 0.996114E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 38.9990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 0.3715E-01 -1.430 9.741 0.989 22.88 3.739 andradite 0.4323E-02 -2.364 2.197 0.342 5.160 0.5708 grossular 0.2448E-03 -3.611 0.1103 -0.958 0.2589 0.3068E-01 apatite-OH 0.7683E-04 -4.114 0.3859E-01 -1.413 0.9064E-01 0.1226E-01 clinochlore 0.6190E-02 -2.208 3.441 0.537 8.081 1.309 daphnite 0.2721E-02 -2.565 1.941 0.288 4.560 0.5883 chlorite-Mn 0.1352E-03 -3.869 0.9588E-01 -1.018 0.2252 0.3055E-01 microcline 0.7636E-02 -2.117 2.125 0.327 4.991 0.8302 stilbite 0.3078E-01 -1.512 21.69 1.336 50.94 10.12 stilpnomelane-Fe 0.1111E-02 -2.954 1.198 0.078 2.813 0.4137 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.9464E+00 0.9464E+00 1.0000 -0.024 grossular 0.5358E-01 0.5358E-01 1.0000 -1.271 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.6843E+00 0.6843E+00 1.0000 -0.165 daphnite 0.3008E+00 0.3008E+00 1.0000 -0.522 chlorite-Mn 0.1495E-01 0.1495E-01 1.0000 -1.825 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 42.579467 g Volume = 17.641980 cm3 Porosity: -6.2795% V(tot) - V(min): -.10424E+01 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 38.9990000 g log = 1.5911 Original solution: 1000.0103000 g Original solution / Rock added: 25.64 (Water/Rock Ratio), log = 1.4090 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0203 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.1000E+01 0.9860 0.1006E+01 0.1020E+01 CO2,gas 0.1372E-06 1.0071 0.1410E-06 0.1400E-06 CH4,gas 0.3208E-11 1.0125 0.3314E-11 0.3273E-11 H2,gas 0.2158E-04 1.0005 0.2203E-04 0.2201E-04 H2S,gas 0.6276E-10 0.9960 0.6378E-10 0.6404E-10 S2,gas 0.3085E-30 1.0000 0.3148E-30 0.3148E-30 CO,gas 0.8112E-15 1.0000 0.8277E-15 0.8277E-15 SO3,gas 0.7403E-40 1.0000 0.7554E-40 0.7554E-40 SO2,gas 0.6344E-22 1.0000 0.6473E-22 0.6473E-22 HCl,gas 0.4342E-17 1.0000 0.4430E-17 0.4430E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 16 albite -0.38 -0.38 0.00 0.000 -0.94784E-12 22 andradite 39.01 39.01 0.00 0.000 0.12132E-10 23 grossular 32.73 32.73 0.00 0.000 0.12132E-10 32 apatite-OH -18.15 -18.15 0.00 0.000 -0.12132E-10 46 clinochlore 39.07 39.07 0.00 0.000 -0.36397E-10 47 daphnite 28.97 28.97 0.00 0.000 0.00000E+00 48 chlorite-Mn 46.87 46.87 0.00 0.000 -0.48529E-10 116 microcline -2.49 -2.49 0.00 0.000 -0.10616E-10 163 stilbite -7.52 -7.52 0.00 0.000 -0.33364E-10 164 stilpnomelane-Fe 13.02 13.02 0.00 0.000 -0.27298E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -15.21 -8.55 -2.850 0.14598E+05 -6.851 3 CH4,gas 4.54 -8.63 -13.18 -3.295 0.22502E+05 -11.480 4 H2,gas 8.00 1.64 -6.36 -3.632 0.10853E+05 -4.657 5 H2S,gas -6.23 -18.12 -11.89 -5.947 0.20309E+05 -10.195 6 S2,gas -7.34 -39.54 -32.20 -4.954 0.54982E+05 -30.502 7 CO,gas 3.21 -13.57 -16.78 -5.163 0.28653E+05 -15.082 8 SO3,gas 17.12 -24.70 -41.82 -10.455 0.71408E+05 -40.122 9 SO2,gas 0.83 -23.06 -23.89 -6.370 0.40788E+05 -22.189 10 HCl,gas 5.19 -13.86 -19.05 -9.526 0.32532E+05 -17.354 11 acmite 7.71 7.25 -0.46 -0.048 0.78083E+03 15 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 19 spessartine 24.46 19.90 -4.56 -0.228 0.77897E+04 20 analcite 3.32 2.87 -0.46 -0.051 0.77719E+03 26 annite 20.12 17.45 -2.67 -0.148 0.45612E+04 27 phlogopite 27.06 24.59 -2.48 -0.138 0.42328E+04 29 anorthite 12.71 8.73 -3.98 -0.306 0.67950E+04 35 aragonite 0.97 -2.86 -3.82 -1.274 0.65255E+04 36 brucite 12.57 9.02 -3.54 -0.709 0.60522E+04 37 calcite 0.81 -2.86 -3.67 -1.222 0.62613E+04 38 carnegieite-low 9.02 6.12 -2.91 -0.415 0.49620E+04 39 carnegieite-high 10.09 6.12 -3.98 -0.568 0.67890E+04 40 carpholite-Mg 8.58 5.40 -3.18 -0.212 0.54331E+04 41 carpholite-Fe 6.71 3.02 -3.69 -0.246 0.63012E+04 42 celadonite 5.34 3.29 -2.05 -0.121 0.35082E+04 43 celadonite-Fe 3.88 0.91 -2.97 -0.175 0.50667E+04 44 chrysotile 23.89 20.57 -3.32 -0.277 0.56712E+04 50 chloritoid-Mg 13.20 8.65 -4.55 -0.303 0.77639E+04 51 chloritoid-Fe 9.17 6.27 -2.90 -0.193 0.49530E+04 52 chloritoid-Mn 11.40 8.55 -2.85 -0.190 0.48684E+04 54 coesite -2.38 -3.25 -0.87 -0.291 0.14932E+04 61 cristobalite -2.56 -3.25 -0.69 -0.230 0.11785E+04 63 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71234E+04 65 diaspore 2.87 1.44 -1.44 -0.239 0.24504E+04 67 diopside 16.18 14.88 -1.30 -0.130 0.22262E+04 68 hedenbergite 14.21 12.50 -1.71 -0.171 0.29173E+04 75 epidote 24.67 23.66 -1.01 -0.049 0.17259E+04 76 clinozoisite 22.81 19.27 -3.53 -0.161 0.60318E+04 77 epidote-Fe 29.84 28.04 -1.80 -0.093 0.30665E+04 78 fayalite 14.05 10.04 -4.00 -0.572 0.68366E+04 79 ferrosilite 11.15 6.79 -4.36 -0.436 0.74415E+04 83 gibbsite 4.08 1.44 -2.64 -0.377 0.45089E+04 84 glaucophane 22.97 19.80 -3.17 -0.086 0.54154E+04 85 glaucophane-Fe 17.28 12.67 -4.61 -0.124 0.78648E+04 87 greenalite 16.14 13.44 -2.70 -0.225 0.46137E+04 90 hematite 12.57 11.65 -0.92 -0.111 0.15667E+04 91 heulandite -5.83 -7.52 -1.69 -0.077 0.28938E+04 95 jadeite 4.22 2.87 -1.35 -0.135 0.23027E+04 96 julgoldite 70.43 66.50 -3.92 -0.102 0.66967E+04 97 kalsilite 7.58 4.01 -3.57 -0.510 0.60945E+04 98 kaolinite -1.33 -3.62 -2.29 -0.208 0.39121E+04 101 laumontite 2.88 2.23 -0.65 -0.044 0.11163E+04 102 lawsonite 9.62 8.73 -0.89 -0.059 0.15117E+04 103 leucite 4.12 0.76 -3.35 -0.335 0.57282E+04 105 lizardite 23.24 20.57 -2.67 -0.223 0.45639E+04 107 magnetite 20.09 18.29 -1.79 -0.146 0.30608E+04 108 minnesotaite 10.39 6.94 -3.45 -0.203 0.58938E+04 120 muscovite 2.58 0.39 -2.19 -0.129 0.37423E+04 121 paragonite 4.24 2.49 -1.75 -0.103 0.29814E+04 122 nepheline 8.34 6.12 -2.22 -0.317 0.37944E+04 128 periclase-Fe 11.63 6.65 -4.98 -1.245 0.85039E+04 134 phlogopite-Na 29.65 26.69 -2.96 -0.164 0.50516E+04 136 prehnite 19.37 17.83 -1.54 -0.090 0.26245E+04 137 prehnite-Fe 22.50 22.22 -0.28 -0.017 0.47351E+03 138 pumpellyite-Fe 46.27 43.75 -2.51 -0.056 0.42943E+04 139 pumpellyite-Mg 48.99 46.13 -2.86 -0.064 0.48878E+04 145 pyroxmangite 7.40 5.67 -1.73 -0.345 0.29471E+04 146 pyrophyllite -6.18 -10.13 -3.95 -0.247 0.67432E+04 147 quartz -2.99 -3.25 -0.26 -0.087 0.44586E+03 152 rhodonite 7.45 5.67 -1.77 -0.355 0.30274E+04 153 sanidine -1.28 -2.49 -1.21 -0.093 0.20677E+04 165 stilpnomelane-Mg 27.44 24.91 -2.54 -0.076 0.43289E+04 171 talc 16.49 14.07 -2.42 -0.142 0.41342E+04 174 tephroite 18.09 14.60 -3.49 -0.499 0.59589E+04 177 topaz-H 4.62 -0.37 -4.99 -0.454 0.85234E+04 178 tridymite -2.63 -3.25 -0.62 -0.208 0.10658E+04 179 tremolite 47.87 43.82 -4.04 -0.109 0.69055E+04 187 wairakite 3.95 2.23 -1.72 -0.101 0.29383E+04 188 walstromite 11.51 9.10 -2.41 -0.481 0.41067E+04 189 wollastonite 10.46 9.10 -1.36 -0.271 0.23171E+04 190 pseudo-wollastonite 11.00 9.10 -1.90 -0.379 0.32370E+04 191 zoisite 22.85 19.27 -3.58 -0.163 0.61059E+04 192 akaganeite 7.75 5.82 -1.93 -0.417 0.32959E+04 193 beidellite-Ca -1.65 -6.54 -4.89 -0.303 0.83555E+04 197 beidellite-Na -1.34 -5.96 -4.62 -0.283 0.78864E+04 199 chalcedony -2.80 -3.25 -0.45 -0.149 0.76516E+03 201 montmorillonite-Ca -2.29 -5.58 -3.29 -0.204 0.56220E+04 202 montmorillonite-K -2.24 -5.70 -3.46 -0.212 0.59119E+04 203 montmorillonite-Mg -2.48 -6.13 -3.65 -0.226 0.62374E+04 204 montmorillonite-Na -2.04 -5.01 -2.97 -0.182 0.50668E+04 205 nontronite-Ca 3.21 2.23 -0.98 -0.064 0.16771E+04 206 nontronite-H 2.53 0.19 -2.34 -0.157 0.39936E+04 207 nontronite-K 3.34 2.12 -1.22 -0.079 0.20901E+04 208 nontronite-Mg 3.07 1.68 -1.39 -0.090 0.23765E+04 209 nontronite-Na 3.52 2.81 -0.71 -0.046 0.12110E+04 224 tobermorite 9.82 7.04 -2.78 -0.759 0.47505E+04 233 boehmite 4.41 1.44 -2.97 -0.495 0.50673E+04 235 ferrous-oxide 9.81 6.65 -3.17 -0.791 0.54048E+04 240 silica-amorphous -2.09 -3.25 -1.16 -0.386 0.19793E+04 242 an20ab80 2.02 1.44 -0.58 -0.045 0.98816E+03 243 an25ab75 2.65 1.89 -0.75 -0.058 0.12822E+04 244 an30ab70 3.28 2.35 -0.93 -0.071 0.15858E+04 245 tr.625ac.25prg.125 45.16 42.07 -3.10 -0.083 0.52877E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 1.0000000 g Current total amount of reactant added: 38.9990000 g New total amount of reactant added: 39.9990000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.2998E-12 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 7 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 39.9990000 Water: Moles liquid = 0.5524E+02 kg liquid = 0.9951E+00 Moles total = 0.5501E+02 kg total = 0.9910E+00 Activity = 1.0000 Stoichiometric ionic strength = .6373139E-02 Osmotic coef. = 0.9583 True ionic strength = .1159234E-01 Chg. balance for total moles = 0.2998E-12 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.13014E-09 -9.8856 0.11284E-09 -9.9475 0.86703E+00 -0.0620 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13826E-03 -3.8593 0.11941E-03 -3.9229 0.86367E+00 -0.0637 4 SO4-- 0.25591E-04 -4.5919 0.15141E-04 -4.8199 0.59165E+00 -0.2279 5 HCO3- 0.61575E-05 -5.2106 0.53231E-05 -5.2738 0.86448E+00 -0.0632 6 HS- 0.17873E-07 -7.7478 0.15438E-07 -7.8114 0.86375E+00 -0.0636 7 Al+++ 0.12152E-27 -27.9153 0.37828E-28 -28.4222 0.31129E+00 -0.5068 8 H4SiO4 0.56334E-03 -3.2492 0.56334E-03 -3.2492 0.10000E+01 0.0000 9 Ca++ 0.52064E-07 -7.2835 0.30659E-07 -7.5134 0.58888E+00 -0.2300 10 Mg++ 0.23325E-10 -10.6322 0.13695E-10 -10.8634 0.58715E+00 -0.2313 11 Fe++ 0.96775E-13 -13.0142 0.56861E-13 -13.2452 0.58756E+00 -0.2309 12 K+ 0.90442E-04 -4.0436 0.78198E-04 -4.1068 0.86462E+00 -0.0632 13 Na+ 0.11469E-01 -1.9405 0.99043E-02 -2.0042 0.86358E+00 -0.0637 14 Mn++ 0.18471E-10 -10.7335 0.10859E-10 -10.9642 0.58787E+00 -0.2307 15 HPO4-- 0.27274E-06 -6.5643 0.16138E-06 -6.7922 0.59170E+00 -0.2279 16 HSiO3- 0.53975E-02 -2.2678 0.46617E-02 -2.3315 0.86367E+00 -0.0637 17 Ca(HSiO3)+ 0.37640E-08 -8.4243 0.32549E-08 -8.4875 0.86474E+00 -0.0631 18 Mg(HSiO3)+ 0.20925E-11 -11.6793 0.18095E-11 -11.7424 0.86474E+00 -0.0631 19 NaHSiO3,aq 0.74675E-03 -3.1268 0.74675E-03 -3.1268 0.10000E+01 0.0000 20 AlO+ 0.46741E-15 -15.3303 0.40419E-15 -15.3934 0.86474E+00 -0.0631 22 HAlO2,aq 0.71335E-09 -9.1467 0.71335E-09 -9.1467 0.10000E+01 0.0000 23 AlO2- 0.16222E-04 -4.7899 0.13994E-04 -4.8541 0.86267E+00 -0.0642 24 CH4,aq 0.52825E-14 -14.2772 0.52722E-14 -14.2780 0.99804E+00 -0.0009 29 CO,aq 0.67358E-18 -18.1716 0.67358E-18 -18.1716 0.10000E+01 0.0000 30 CO2,aq 0.12860E-08 -8.8908 0.12834E-08 -8.8916 0.99804E+00 -0.0009 31 CO3-2 0.69740E-05 -5.1565 0.41205E-05 -5.3850 0.59084E+00 -0.2285 32 CaCO3,aq 0.15840E-08 -8.8002 0.15840E-08 -8.8002 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.48175E-11 -11.3172 0.41659E-11 -11.3803 0.86474E+00 -0.0631 34 CaCl+ 0.68515E-11 -11.1642 0.59248E-11 -11.2273 0.86474E+00 -0.0631 35 CaCl2,aq 0.16809E-15 -15.7745 0.16809E-15 -15.7745 0.10000E+01 0.0000 36 CaOH+ 0.22394E-07 -7.6499 0.19365E-07 -7.7130 0.86474E+00 -0.0631 37 CaSO4,aq 0.14741E-09 -9.8315 0.14741E-09 -9.8315 0.10000E+01 0.0000 38 HCl,aq 0.24691E-14 -14.6075 0.24691E-14 -14.6075 0.10000E+01 0.0000 43 FeCl+ 0.12428E-16 -16.9056 0.10747E-16 -16.9687 0.86474E+00 -0.0631 46 FeO,aq 0.17357E-09 -9.7605 0.17357E-09 -9.7605 0.10000E+01 0.0000 47 FeOH+ 0.18969E-10 -10.7220 0.16403E-10 -10.7851 0.86474E+00 -0.0631 48 HFeO2- 0.18635E-07 -7.7297 0.16094E-07 -7.7933 0.86367E+00 -0.0637 49 FeO+ 0.31302E-15 -15.5044 0.27068E-15 -15.5675 0.86474E+00 -0.0631 51 FeO2- 0.50368E-08 -8.2978 0.43501E-08 -8.3615 0.86367E+00 -0.0637 52 HFeO2,aq 0.62430E-10 -10.2046 0.62430E-10 -10.2046 0.10000E+01 0.0000 53 H2,aq 0.20933E-07 -7.6792 0.20892E-07 -7.6800 0.99804E+00 -0.0009 54 KCl,aq 0.16924E-09 -9.7715 0.16924E-09 -9.7715 0.10000E+01 0.0000 55 KHSO4,aq 0.37773E-18 -18.4228 0.37773E-18 -18.4228 0.10000E+01 0.0000 56 KOH,aq 0.29596E-06 -6.5288 0.29596E-06 -6.5288 0.10000E+01 0.0000 57 KSO4- 0.21272E-07 -7.6722 0.18372E-07 -7.7358 0.86367E+00 -0.0637 58 MgCO3,aq 0.17736E-12 -12.7511 0.17736E-12 -12.7511 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.21989E-14 -14.6578 0.19015E-14 -14.7209 0.86474E+00 -0.0631 60 MgCl+ 0.27739E-14 -14.5569 0.23987E-14 -14.6200 0.86474E+00 -0.0631 61 MgOH+ 0.55353E-10 -10.2569 0.47866E-10 -10.3200 0.86474E+00 -0.0631 63 MnO,aq 0.88319E-09 -9.0539 0.88319E-09 -9.0539 0.10000E+01 0.0000 64 MnOH+ 0.33651E-09 -9.4730 0.29099E-09 -9.5361 0.86474E+00 -0.0631 65 MnO2-2 0.38962E-11 -11.4094 0.23020E-11 -11.6379 0.59084E+00 -0.2285 66 HMnO2- 0.65892E-10 -10.1812 0.56909E-10 -10.2448 0.86367E+00 -0.0637 69 MnCl+ 0.92336E-14 -14.0346 0.79847E-14 -14.0977 0.86474E+00 -0.0631 70 MnSO4,aq 0.47463E-13 -13.3236 0.47463E-13 -13.3236 0.10000E+01 0.0000 71 NaCl,aq 0.39195E-06 -6.4068 0.39195E-06 -6.4068 0.10000E+01 0.0000 72 NaOH,aq 0.37712E-04 -4.4235 0.37712E-04 -4.4235 0.10000E+01 0.0000 74 OH- 0.59355E-02 -2.2265 0.51204E-02 -2.2907 0.86267E+00 -0.0642 79 HPO3-2 0.17783E-16 -16.7500 0.10507E-16 -16.9785 0.59084E+00 -0.2285 82 H3PO4,aq 0.14371E-16 -16.8425 0.14371E-16 -16.8425 0.10000E+01 0.0000 83 H2PO4- 0.38871E-09 -9.4104 0.33592E-09 -9.4738 0.86420E+00 -0.0634 84 PO4-3 0.36323E-08 -8.4398 0.11669E-08 -8.9330 0.32125E+00 -0.4932 87 H2P2O7-2 0.14975E-19 -19.8246 0.88479E-20 -20.0532 0.59084E+00 -0.2285 88 HP2O7-3 0.50271E-16 -16.2987 0.15657E-16 -16.8053 0.31145E+00 -0.5066 89 P2O7-4 0.25568E-15 -15.5923 0.33149E-16 -16.4795 0.12965E+00 -0.8872 90 H2S,aq 0.53943E-11 -11.2681 0.53838E-11 -11.2689 0.99804E+00 -0.0009 91 S2-2 0.42781E-18 -18.3687 0.25277E-18 -18.5973 0.59084E+00 -0.2285 97 SO3-2 0.68931E-13 -13.1616 0.41106E-13 -13.3861 0.59633E+00 -0.2245 98 HSO3- 0.33625E-15 -15.4733 0.29041E-15 -15.5370 0.86367E+00 -0.0637 99 HSO4- 0.19028E-11 -11.7206 0.16465E-11 -11.7834 0.86527E+00 -0.0628 101 S2O3-2 0.16206E-17 -17.7903 0.95753E-18 -18.0188 0.59084E+00 -0.2285 Charge balance for all species = 0.2986E-12 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.1301435E-09 -.1218977E-01 -.1227525E+02 0.0000 2 H2O 0.1000000E+01 0.5550811E+02 0.9990745E+06 0.0000 3 Cl- 0.1382618E-03 0.1386539E-03 0.4911172E+01 6.0246 4 SO4-- 0.2559082E-04 0.2560765E-04 0.2457647E+01 15.0752 5 HCO3- 0.6157531E-05 0.1313439E-04 0.8006860E+00 4.6737 6 HS- 0.1787288E-07 0.2247413E-07 0.7425802E-03 2.1361 7 Al+++ 0.1215215E-27 0.1622259E-04 0.4373068E+00 1.4204 8 H4SiO4 0.5633406E-03 0.6707599E-02 0.6441099E+03 -3.2492 9 Ca++ 0.5206373E-07 0.7996440E-07 0.3201862E-02 12.3816 10 Mg++ 0.2332537E-10 0.8095290E-10 0.1966315E-05 9.0317 11 Fe++ 0.9677518E-13 0.2392673E-07 0.1335006E-02 6.6499 12 K+ 0.9044221E-04 0.9075960E-04 0.3545614E+01 5.8407 13 Na+ 0.1146886E-01 0.1225371E-01 0.2814510E+03 7.9434 14 Mn++ 0.1847093E-10 0.1308013E-08 0.7179346E-04 8.9309 15 HPO4-- 0.2727367E-06 0.2767577E-06 0.2653847E-01 13.1029 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.6623110E+00 -.1213001E-01 -.6501810E+00 0.0000000E+00 2 H2O 0.5500685E+02 0.5523598E+02 -.2291304E+00 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.1134013E-02 0.2548211E-04 0.1108531E-02 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.1108509E-02 0.2236395E-07 -.1108531E-02 0.0000000E+00 7 Al+++ 0.1304264E+00 0.1614306E-04 0.1304103E+00 0.0000000E+00 8 H4SiO4 0.4165009E+00 0.6674714E-02 0.4098262E+00 0.0000000E+00 9 Ca++ 0.4601903E-01 0.7957237E-07 0.4601895E-01 0.0000000E+00 10 Mg++ 0.3174524E-01 0.8055602E-10 0.3174524E-01 0.0000000E+00 11 Fe++ 0.2851963E-01 0.2380942E-07 0.2851961E-01 0.0000000E+00 12 K+ 0.8492357E-02 0.9031464E-04 0.8402042E-02 0.0000000E+00 13 Na+ 0.5036856E-01 0.1219364E-01 0.3817492E-01 0.0000000E+00 14 Mn++ 0.6935265E-03 0.1301600E-08 0.6935252E-03 0.0000000E+00 15 HPO4-- 0.2366971E-03 0.2754009E-06 0.2364217E-03 0.0000000E+00 Chg. balance for solid moles: 0.3914E-16 Mass of aqueous solution: 0.996014E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 39.9990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 0.3817E-01 -1.418 10.01 1.000 22.92 3.843 andradite 0.4434E-02 -2.353 2.253 0.353 5.160 0.5854 grossular 0.2664E-03 -3.574 0.1200 -0.921 0.2748 0.3339E-01 apatite-OH 0.7881E-04 -4.103 0.3959E-01 -1.402 0.9065E-01 0.1258E-01 clinochlore 0.6349E-02 -2.197 3.529 0.548 8.081 1.342 daphnite 0.2766E-02 -2.558 1.973 0.295 4.519 0.5980 chlorite-Mn 0.1387E-03 -3.858 0.9834E-01 -1.007 0.2252 0.3134E-01 microcline 0.7820E-02 -2.107 2.177 0.338 4.984 0.8502 stilbite 0.3152E-01 -1.501 22.22 1.347 50.87 10.36 stilpnomelane-Fe 0.1165E-02 -2.934 1.255 0.099 2.875 0.4336 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.9433E+00 0.9433E+00 1.0000 -0.025 grossular 0.5667E-01 0.5667E-01 1.0000 -1.247 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.6861E+00 0.6861E+00 1.0000 -0.164 daphnite 0.2989E+00 0.2989E+00 1.0000 -0.524 chlorite-Mn 0.1499E-01 0.1499E-01 1.0000 -1.824 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 43.670928 g Volume = 18.091159 cm3 Porosity: -6.4211% V(tot) - V(min): -.10916E+01 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 39.9990000 g log = 1.6020 Original solution: 1000.0103000 g Original solution / Rock added: 25.00 (Water/Rock Ratio), log = 1.3980 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0203 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.1000E+01 0.9860 0.1006E+01 0.1020E+01 CO2,gas 0.1336E-06 1.0071 0.1373E-06 0.1363E-06 CH4,gas 0.7512E-11 1.0125 0.7760E-11 0.7664E-11 H2,gas 0.2687E-04 1.0005 0.2743E-04 0.2741E-04 H2S,gas 0.1456E-09 0.9960 0.1480E-09 0.1486E-09 S2,gas 0.1071E-29 1.0000 0.1093E-29 0.1093E-29 CO,gas 0.9838E-15 1.0000 0.1004E-14 0.1004E-14 SO3,gas 0.7144E-40 1.0000 0.7289E-40 0.7289E-40 SO2,gas 0.7623E-22 1.0000 0.7778E-22 0.7778E-22 HCl,gas 0.4270E-17 1.0000 0.4357E-17 0.4357E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 16 albite -0.38 -0.38 0.00 0.000 -0.94784E-12 22 andradite 39.01 39.01 0.00 0.000 0.12132E-10 23 grossular 32.73 32.73 0.00 0.000 -0.12132E-10 32 apatite-OH -18.15 -18.15 0.00 0.000 0.00000E+00 46 clinochlore 39.07 39.07 0.00 0.000 0.12132E-10 47 daphnite 28.97 28.97 0.00 0.000 0.00000E+00 48 chlorite-Mn 46.87 46.87 0.00 0.000 0.00000E+00 116 microcline -2.49 -2.49 0.00 0.000 0.15165E-11 163 stilbite -7.52 -7.52 0.00 0.000 -0.90992E-11 164 stilpnomelane-Fe 13.02 13.02 0.00 0.000 -0.27298E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -15.22 -8.56 -2.854 0.14618E+05 -6.862 3 CH4,gas 4.54 -8.27 -12.81 -3.202 0.21871E+05 -11.110 4 H2,gas 8.00 1.74 -6.26 -3.578 0.10690E+05 -4.562 5 H2S,gas -6.23 -17.76 -11.53 -5.764 0.19685E+05 -9.830 6 S2,gas -7.34 -39.00 -31.66 -4.871 0.54059E+05 -29.961 7 CO,gas 3.21 -13.48 -16.70 -5.138 0.28510E+05 -14.998 8 SO3,gas 17.12 -24.71 -41.84 -10.459 0.71434E+05 -40.137 9 SO2,gas 0.83 -22.98 -23.81 -6.349 0.40652E+05 -22.109 10 HCl,gas 5.19 -13.87 -19.06 -9.530 0.32544E+05 -17.361 11 acmite 7.71 7.23 -0.48 -0.050 0.82709E+03 15 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 19 spessartine 24.46 19.89 -4.57 -0.229 0.78058E+04 20 analcite 3.32 2.87 -0.46 -0.051 0.77946E+03 26 annite 20.12 17.46 -2.66 -0.148 0.45422E+04 27 phlogopite 27.06 24.61 -2.46 -0.136 0.41937E+04 29 anorthite 12.71 8.72 -3.99 -0.307 0.68064E+04 35 aragonite 0.97 -2.84 -3.81 -1.269 0.64991E+04 36 brucite 12.57 9.03 -3.54 -0.707 0.60392E+04 37 calcite 0.81 -2.84 -3.65 -1.217 0.62349E+04 38 carnegieite-low 9.02 6.11 -2.91 -0.416 0.49665E+04 39 carnegieite-high 10.09 6.11 -3.98 -0.568 0.67935E+04 40 carpholite-Mg 8.58 5.37 -3.21 -0.214 0.54775E+04 41 carpholite-Fe 6.71 2.99 -3.72 -0.248 0.63523E+04 42 celadonite 5.34 3.30 -2.05 -0.120 0.34929E+04 43 celadonite-Fe 3.88 0.91 -2.96 -0.174 0.50581E+04 44 chrysotile 23.89 20.60 -3.30 -0.275 0.56276E+04 50 chloritoid-Mg 13.20 8.62 -4.57 -0.305 0.78106E+04 51 chloritoid-Fe 9.17 6.24 -2.93 -0.195 0.50064E+04 52 chloritoid-Mn 11.40 8.52 -2.88 -0.192 0.49150E+04 54 coesite -2.38 -3.25 -0.87 -0.291 0.14909E+04 61 cristobalite -2.56 -3.25 -0.69 -0.230 0.11763E+04 63 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71234E+04 65 diaspore 2.87 1.42 -1.45 -0.242 0.24814E+04 67 diopside 16.18 14.91 -1.27 -0.127 0.21625E+04 68 hedenbergite 14.21 12.53 -1.68 -0.168 0.28603E+04 75 epidote 24.67 23.64 -1.03 -0.050 0.17638E+04 76 clinozoisite 22.81 19.28 -3.53 -0.160 0.60258E+04 77 epidote-Fe 29.84 28.00 -1.84 -0.096 0.31484E+04 78 fayalite 14.05 10.05 -4.00 -0.571 0.68216E+04 79 ferrosilite 11.15 6.80 -4.35 -0.435 0.74243E+04 83 gibbsite 4.08 1.42 -2.66 -0.380 0.45399E+04 84 glaucophane 22.97 19.83 -3.15 -0.085 0.53717E+04 85 glaucophane-Fe 17.28 12.68 -4.59 -0.124 0.78412E+04 87 greenalite 16.14 13.45 -2.69 -0.224 0.45901E+04 90 hematite 12.57 11.56 -1.01 -0.122 0.17166E+04 91 heulandite -5.83 -7.52 -1.69 -0.077 0.28938E+04 95 jadeite 4.22 2.87 -1.35 -0.135 0.23049E+04 96 julgoldite 70.43 66.45 -3.97 -0.103 0.67859E+04 97 kalsilite 7.58 4.01 -3.57 -0.510 0.60990E+04 98 kaolinite -1.33 -3.66 -2.32 -0.211 0.39695E+04 101 laumontite 2.88 2.23 -0.66 -0.044 0.11231E+04 102 lawsonite 9.62 8.72 -0.89 -0.059 0.15230E+04 103 leucite 4.12 0.76 -3.36 -0.336 0.57305E+04 105 lizardite 23.24 20.60 -2.65 -0.221 0.45202E+04 107 magnetite 20.09 18.21 -1.88 -0.153 0.32044E+04 108 minnesotaite 10.39 6.95 -3.44 -0.202 0.58657E+04 120 muscovite 2.58 0.35 -2.23 -0.131 0.38043E+04 121 paragonite 4.24 2.46 -1.78 -0.105 0.30434E+04 122 nepheline 8.34 6.11 -2.22 -0.318 0.37989E+04 128 periclase-Fe 11.63 6.65 -4.98 -1.244 0.84975E+04 134 phlogopite-Na 29.65 26.71 -2.94 -0.163 0.50125E+04 136 prehnite 19.37 17.86 -1.52 -0.089 0.25874E+04 137 prehnite-Fe 22.50 22.22 -0.28 -0.017 0.48047E+03 138 pumpellyite-Fe 46.27 43.78 -2.49 -0.055 0.42449E+04 139 pumpellyite-Mg 48.99 46.17 -2.83 -0.063 0.48317E+04 145 pyroxmangite 7.40 5.68 -1.72 -0.343 0.29318E+04 146 pyrophyllite -6.18 -10.16 -3.98 -0.249 0.67961E+04 147 quartz -2.99 -3.25 -0.26 -0.087 0.44359E+03 152 rhodonite 7.45 5.68 -1.76 -0.353 0.30121E+04 153 sanidine -1.28 -2.49 -1.21 -0.093 0.20677E+04 165 stilpnomelane-Mg 27.44 24.93 -2.52 -0.075 0.42954E+04 171 talc 16.49 14.10 -2.39 -0.141 0.40860E+04 174 tephroite 18.09 14.61 -3.47 -0.496 0.59306E+04 178 tridymite -2.63 -3.25 -0.62 -0.208 0.10636E+04 179 tremolite 47.87 43.93 -3.94 -0.107 0.67299E+04 187 wairakite 3.95 2.23 -1.72 -0.101 0.29451E+04 188 walstromite 11.51 9.13 -2.38 -0.475 0.40583E+04 189 wollastonite 10.46 9.13 -1.33 -0.266 0.22688E+04 190 pseudo-wollastonite 11.00 9.13 -1.87 -0.373 0.31886E+04 191 zoisite 22.85 19.28 -3.57 -0.162 0.60998E+04 192 akaganeite 7.75 5.78 -1.97 -0.427 0.33708E+04 193 beidellite-Ca -1.65 -6.57 -4.93 -0.305 0.84118E+04 197 beidellite-Na -1.34 -5.99 -4.65 -0.285 0.79423E+04 199 chalcedony -2.80 -3.25 -0.45 -0.149 0.76289E+03 201 montmorillonite-Ca -2.29 -5.60 -3.31 -0.205 0.56528E+04 202 montmorillonite-K -2.24 -5.72 -3.48 -0.213 0.59423E+04 203 montmorillonite-Mg -2.48 -6.15 -3.67 -0.227 0.62736E+04 204 montmorillonite-Na -2.04 -5.02 -2.99 -0.183 0.50972E+04 205 nontronite-Ca 3.21 2.15 -1.07 -0.069 0.18213E+04 206 nontronite-H 2.53 0.10 -2.43 -0.163 0.41454E+04 207 nontronite-K 3.34 2.03 -1.31 -0.084 0.22340E+04 208 nontronite-Mg 3.07 1.60 -1.48 -0.096 0.25262E+04 209 nontronite-Na 3.52 2.73 -0.79 -0.051 0.13549E+04 224 tobermorite 9.82 7.06 -2.76 -0.753 0.47098E+04 233 boehmite 4.41 1.42 -2.99 -0.498 0.50983E+04 235 ferrous-oxide 9.81 6.65 -3.16 -0.790 0.53985E+04 240 silica-amorphous -2.09 -3.25 -1.16 -0.386 0.19771E+04 242 an20ab80 2.02 1.44 -0.58 -0.045 0.99042E+03 243 an25ab75 2.65 1.89 -0.75 -0.058 0.12850E+04 244 an30ab70 3.28 2.35 -0.93 -0.072 0.15892E+04 245 tr.625ac.25prg.125 45.16 42.16 -3.01 -0.081 0.51313E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 1.0000000 g Current total amount of reactant added: 39.9990000 g New total amount of reactant added: 40.9990000 g Mixing fraction reached given limit of 0.4000E+02 TOTMIX = 0.4100E+02 Execution stopped.