File SKIP_SPECIES.TXT lists species and minerals omitted from the calculations due to given T, P, option switches, or suppression in CHIMRUN, or are suppressed in the SOLTHERM database. It also lists minerals for which density is not specified in SOLTHERM. This is an extended P(to 5 kB), T(to 600 C) run (CON_FLAG = 1). methanol,aq is suppressed in SOLTHERM data file. methanol,aq is suppressed in SOLTHERM data file. CuCl4-3 is suppressed in SOLTHERM data file. H2BO3- is suppressed in SOLTHERM data file. UO2CO3,aq is suppressed in SOLTHERM data file. UO2SO4,aq is suppressed in SOLTHERM data file. UO2Cl2,aq is suppressed in SOLTHERM data file. UO2F2,aq is suppressed in SOLTHERM data file. PO4-3 is suppressed in SOLTHERM data file. H2PO4- is suppressed in SOLTHERM data file. H3PO4 is suppressed in SOLTHERM data file. O2,gas is suppressed in THIS RUN. O2,gas is suppressed in THIS RUN. amesite is suppressed in SOLTHERM data file. antigorite is suppressed in SOLTHERM data file. goethite is suppressed in THIS RUN. goethite is suppressed in THIS RUN. riebeckite is suppressed in THIS RUN. riebeckite is suppressed in THIS RUN. sapphirine-Fe(221) is suppressed in SOLTHERM data file. sapphirine(221) is suppressed in SOLTHERM data file. talc-prl is suppressed in SOLTHERM data file. PrO1.833(s) is suppressed in SOLTHERM data file. niter-NH4 is suppressed in SOLTHERM data file. FMQ_HS-1 is suppressed in THIS RUN. kf-ab-equil is suppressed in THIS RUN. ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Species No. Charge Tot.moles Trial molality Gamma Mixing solution H+ 1 1. -0.66231E+00 0.13014E-09 0.8670 0.00000000E+00 H2O 2 0. 0.55007E+02 0.10000E+01 1.0000 0.00000000E+00 Cl- 3 -1. 0.13797E-03 0.13826E-03 0.8637 0.00000000E+00 SO4-- 4 -2. 0.11340E-02 0.25591E-04 0.5916 0.00000000E+00 HCO3- 5 -1. 0.13070E-04 0.61575E-05 0.8645 0.00000000E+00 HS- 6 -1. -0.11085E-02 0.17873E-07 0.8638 0.00000000E+00 Al+++ 7 3. 0.13043E+00 0.12152E-27 0.3113 0.00000000E+00 H4SiO4 8 0. 0.41650E+00 0.56334E-03 1.0000 0.00000000E+00 Ca++ 9 2. 0.46019E-01 0.52064E-07 0.5889 0.00000000E+00 Mg++ 10 2. 0.31745E-01 0.23325E-10 0.5871 0.00000000E+00 Fe++ 11 2. 0.28520E-01 0.96775E-13 0.5876 0.00000000E+00 K+ 12 1. 0.84924E-02 0.90442E-04 0.8646 0.00000000E+00 Na+ 13 1. 0.50369E-01 0.11469E-01 0.8636 0.00000000E+00 Mn++ 14 2. 0.69353E-03 0.18471E-10 0.5879 0.00000000E+00 HPO4-- 15 -2. 0.23670E-03 0.27274E-06 0.5917 0.00000000E+00 Chg. balance for total moles = -.1499E-12 Max. difference allowed = 0.1380E-07 The following parameters were given: ERPC = 0.1000E-11 pH = 0.0000 PFLUID = 50.0000 SLIM = 0.800000E+02 TEMP = 100.0000 SINC = 0.2000E+01 TEMPC = 0.0000 TOTMIX = 0.399990E+02 ENTH = 0.0000 SENTH = 0.0000 DENTH = 0.0000 TOTWAT = 90.0000 SOLMIN = 0.0000E+00 RM = 0.0000 AQGRM = 1000.0103 SUPRNT = 0.1000E-19 VBOX-1 = 16.9996 RHOFRS = 0.0000 RHOROC = 2.5000 The following options were selected: CONFLG = 1 C = 3 IFRAC = 0 IPUNCH = 2 NLOOP = 400 ISTEP = 2 LIMSOL = 1 LOOC = 0 IENTH = 0 ITREF = 0 IDEAL = 0 IPSAT = 1 INCREM = 0 INCP = 0 MINSOL = 1 NEUT = 0 AWAT = 0 CHGF = 0 Of the derived species, only those with molality > 0.10E-19 will appear in the output Species No. Charge Log K(diss) Species No. Charge Log K(diss) HSiO3- 16 -1. 9.0298 MnO2-2 65 -2. 40.4638 Ca(HSiO3)+ 17 1. 7.6723 HMnO2- 66 -1. 29.1232 Mg(HSiO3)+ 18 1. 7.5773 MnO4- 67 -1. 83.3111 NaHSiO3,aq 19 0. 7.8210 MnO4-2 68 -2. 81.3005 AlO+ 20 1. 6.8663 MnCl+ 69 1. -0.7894 AlOH+2 21 2. 3.1691 MnSO4,aq 70 0. -2.4604 HAlO2,aq 22 0. 10.5671 NaCl,aq 71 0. 0.4796 AlO2- 23 -1. 16.2221 NaOH,aq 72 0. 12.3669 CH4,aq 24 0. 6.0126 O2,aq 73 0. 53.5502 C2H6,aq 25 0. 12.3733 OH- 74 -1. 12.2382 C3H8,aq 26 0. 17.3707 HO2- 75 -1. 50.8010 C4H10,aq 27 0. 22.3757 H2O2,aq 76 0. 40.0166 ethanol,aq 28 0. 15.3258 H3PO2,aq 77 0. 24.3066 CO,aq 29 0. 4.6892 H2PO2- 78 -1. 26.5366 CO2,aq 30 0. -6.3298 HPO3-2 79 -2. 11.9254 CO3-2 31 -2. 10.0588 H3PO3,aq 80 0. 3.5792 CaCO3,aq 32 0. 5.9605 H2PO3- 81 -1. 5.6232 Ca(HCO3)+ 33 1. -1.4070 H3PO4,aq 82 0. -9.8447 CaCl+ 34 1. -0.2091 H2PO4- 83 -1. -7.2659 CaCl2,aq 35 0. 0.4151 PO4-3 84 -3. 12.0884 CaOH+ 36 1. 10.1471 H4P2O7,aq 85 0. -17.8095 CaSO4,aq 37 0. -2.5018 H3P2O7- 86 -1. -15.9156 HCl,aq 38 0. 0.7370 H2P2O7-2 87 -2. -13.4262 HClO,aq 39 0. 32.4260 HP2O7-3 88 -3. -6.7266 ClO- 40 -1. 39.6530 P2O7-4 89 -4. 2.8952 HClO2,aq 41 0. 70.1812 H2S,aq 90 0. -6.4900 Fe+3 42 3. 8.3809 S2-2 91 -2. 1.2355 FeCl+ 43 1. -0.1994 S3-2 92 -2. -8.8031 FeCl2,aq 44 0. 4.3001 S3- 93 -1. -16.3389 FeCl+2 45 2. 6.5269 S4-2 94 -2. -18.6615 FeO,aq 46 0. 16.4104 S5-2 95 -2. -28.3439 FeOH+ 47 1. 7.4874 SO2,aq 96 0. -0.2309 HFeO2- 48 -1. 24.3908 SO3-2 97 -2. 10.3052 FeO+ 49 1. 11.4004 HSO3- 98 -1. 2.5086 FeOH+2 50 2. 9.1194 HSO4- 99 -1. -2.9839 FeO2- 51 -1. 24.0895 HSO5- 100 -1. 38.8366 HFeO2,aq 52 0. 15.9850 S2O3-2 101 -2. -4.5600 H2,aq 53 0. 9.4190 HS2O3- 102 -1. -6.8123 KCl,aq 54 0. 1.7417 H2S2O3,aq 103 0. -8.0173 KHSO4,aq 55 0. -0.4514 S2O4-2 104 -2. 10.5541 KOH,aq 56 0. 12.3695 HS2O4- 105 -1. 7.6551 KSO4- 57 -1. -1.1908 H2S2O4,aq 106 0. 6.6259 MgCO3,aq 58 0. 6.5614 S2O5-2 107 -2. 10.0741 Mg(HCO3)+ 59 1. -1.4164 S2O6-2 108 -2. 11.5521 MgCl+ 60 1. -0.1664 S2O8-2 109 -2. 42.0620 MgOH+ 61 1. 9.4041 S3O6-2 110 -2. 3.7866 Mn+3 62 3. 19.1453 S4O6-2 111 -2. -17.8657 MnO,aq 63 0. 17.9848 S5O6-2 112 -2. -14.1333 MnOH+ 64 1. 8.5194 113 0. 10.3111 For mixed gases (JSOLS=6), log K(hydrol) = log (K*P) Log K Trial Log K Trial Mineral No. hydrol Moles Mineral No. hydrol Moles H2O,gas 1 1.696 0.0000E+00 osumilite(2) 124 20.667 0.0000E+00 CO2,gas 2 -6.660 0.0000E+00 osumilite-Fe 125 14.390 0.0000E+00 CH4,gas 3 4.544 0.0000E+00 pargasite 126 65.092 0.0000E+00 H2,gas 4 8.000 0.0000E+00 periclase 127 16.138 0.0000E+00 H2S,gas 5 -6.230 0.0000E+00 periclase-Fe 128 11.627 0.0000E+00 S2,gas 6 -7.335 0.0000E+00 perovskite-Al 129 12.344 0.0000E+00 CO,gas 7 3.215 0.0000E+00 perovskite-Ca 130 23.807 0.0000E+00 SO3,gas 8 17.121 0.0000E+00 perovskite-Fe 131 21.143 0.0000E+00 SO2,gas 9 0.832 0.0000E+00 perovskite-Mg 132 23.119 0.0000E+00 HCl,gas 10 5.189 0.0000E+00 phase_A 133 80.189 0.0000E+00 acmite 11 7.710 0.0000E+00 phlogopite-Na 134 29.647 0.0000E+00 akermanite 12 36.442 0.0000E+00 piemontite(ordered) 135 33.776 0.0000E+00 akimotoite 13 16.591 0.0000E+00 prehnite 136 19.372 0.0000E+00 akimotoite-Fe 14 13.067 0.0000E+00 prehnite-Fe 137 22.498 0.0000E+00 albite-high 15 0.693 0.0000E+00 pumpellyite-Fe 138 46.269 0.0000E+00 albite 16 -0.384 0.3817E-01 pumpellyite-Mg 139 48.995 0.0000E+00 almandine 17 24.442 0.0000E+00 px-Mg-tschermaks 140 19.616 0.0000E+00 pyrope 18 37.248 0.0000E+00 px-Ca-tschermaks 141 18.610 0.0000E+00 spessartine 19 24.457 0.0000E+00 pyrite 142 -21.247 0.0000E+00 analcite 20 3.322 0.0000E+00 pyrrhotite 143 -4.260 0.0000E+00 andalusite 21 5.002 0.0000E+00 pyrrhotiteFe0.875 144 -6.017 0.0000E+00 andradite 22 39.009 0.4434E-02 pyroxmangite 145 7.399 0.0000E+00 grossular 23 32.731 0.2664E-03 pyrophyllite 146 -6.176 0.0000E+00 anhydrite 24 -5.317 0.0000E+00 quartz 147 -2.989 0.0000E+00 ankerite 25 -2.135 0.0000E+00 rankinite 148 40.713 0.0000E+00 annite 26 20.123 0.0000E+00 ringwoodite-Fe 149 15.456 0.0000E+00 phlogopite 27 27.065 0.0000E+00 ringwoodite-Mg 150 27.575 0.0000E+00 biotite-Mn 28 32.960 0.0000E+00 rhodochrosite 151 -0.976 0.0000E+00 anorthite 29 12.710 0.0000E+00 rhodonite 152 7.446 0.0000E+00 anthophyllite 30 51.852 0.0000E+00 sanidine 153 -1.275 0.0000E+00 anthophyllite-Fe 31 29.306 0.0000E+00 sapphirine(351) 154 78.899 0.0000E+00 apatite-OH 32 -18.153 0.7881E-04 siderite 155 -2.608 0.0000E+00 apatite-OH-zs 33 -12.736 0.0000E+00 sillimanite 156 5.262 0.0000E+00 apatite-Cl-zs 34 -16.674 0.0000E+00 sodalite 157 49.976 0.0000E+00 aragonite 35 0.967 0.0000E+00 spinel 158 20.870 0.0000E+00 brucite 36 12.569 0.0000E+00 spurrite 159 59.482 0.0000E+00 calcite 37 0.812 0.0000E+00 staurolite-Fe 160 73.598 0.0000E+00 carnegieite-low 38 9.023 0.0000E+00 staurolite-Mg 161 89.802 0.0000E+00 carnegieite-high 39 10.093 0.0000E+00 staurolite-Mn 162 83.909 0.0000E+00 carpholite-Mg 40 8.582 0.0000E+00 stilbite 163 -7.522 0.3152E-01 carpholite-Fe 41 6.713 0.0000E+00 stilpnomelane-Fe 164 13.017 0.1165E-02 celadonite 42 5.342 0.0000E+00 stilpnomelane-Mg 165 27.441 0.0000E+00 celadonite-Fe 43 3.877 0.0000E+00 stishovite 166 2.720 0.0000E+00 chrysotile 44 23.892 0.0000E+00 sudoite-Fe 167 18.296 0.0000E+00 chondrodite 45 56.475 0.0000E+00 sudoite 168 21.077 0.0000E+00 clinochlore 46 39.070 0.6349E-02 sulfur 169 -9.152 0.0000E+00 daphnite 47 28.965 0.2766E-02 sylvite 170 1.338 0.0000E+00 chlorite-Mn 48 46.869 0.1387E-03 talc 171 16.491 0.0000E+00 chlorite-Al-free 49 47.173 0.0000E+00 talc-Fe 172 13.448 0.0000E+00 chloritoid-Mg 50 13.198 0.0000E+00 talc-tschermaks 173 19.091 0.0000E+00 chloritoid-Fe 51 9.174 0.0000E+00 tephroite 174 18.086 0.0000E+00 chloritoid-Mn 52 11.401 0.0000E+00 tilleyite 175 41.377 0.0000E+00 clinohumite 53 97.128 0.0000E+00 titanite-CaSi 176 15.479 0.0000E+00 coesite 54 -2.376 0.0000E+00 topaz-H 177 4.618 0.0000E+00 cordierite-H 55 23.715 0.0000E+00 tridymite 178 -2.626 0.0000E+00 cordierite 56 24.049 0.0000E+00 tremolite 179 47.869 0.0000E+00 cordierite-Fe 57 20.450 0.0000E+00 ferroactinolite 180 38.452 0.0000E+00 cordierite-Mn 58 25.066 0.0000E+00 troilite-low 181 -4.411 0.0000E+00 corundum 59 8.383 0.0000E+00 tschermakite 182 48.210 0.0000E+00 corundum-MgSi 60 18.891 0.0000E+00 vesuvianite 183 223.471 0.0000E+00 cristobalite 61 -2.560 0.0000E+00 wadeite-Si 184 20.216 0.0000E+00 cummingtonite 62 52.099 0.0000E+00 wadsleyite-Fe 185 15.680 0.0000E+00 cymrite-K 63 1.685 0.0000E+00 wadsleyite-Mg 186 25.850 0.0000E+00 deerite 64 95.671 0.0000E+00 wairakite 187 3.950 0.0000E+00 diaspore 65 2.874 0.0000E+00 walstromite 188 11.509 0.0000E+00 diamond 66 -3.102 0.0000E+00 wollastonite 189 10.461 0.0000E+00 diopside 67 16.181 0.0000E+00 pseudo-wollastonite 190 11.000 0.0000E+00 hedenbergite 68 14.208 0.0000E+00 zoisite 191 22.849 0.0000E+00 dolomite,ordered 69 0.546 0.0000E+00 akaganeite 192 7.755 0.0000E+00 eastonite 70 28.489 0.0000E+00 beidellite-Ca 193 -1.646 0.0000E+00 enstatite 71 17.265 0.0000E+00 beidellite-H 194 -2.326 0.0000E+00 clinoenstatite-HiP 72 18.354 0.0000E+00 beidellite-K 195 -1.520 0.0000E+00 clinoenstatite 73 17.166 0.0000E+00 beidellite-Mg 196 -1.790 0.0000E+00 protoenstatite 74 17.824 0.0000E+00 beidellite-Na 197 -1.342 0.0000E+00 epidote 75 24.670 0.0000E+00 calcium 198 84.026 0.0000E+00 clinozoisite 76 22.806 0.0000E+00 chalcedony 199 -2.802 0.0000E+00 epidote-Fe 77 29.841 0.0000E+00 dawsonite 200 1.682 0.0000E+00 fayalite 78 14.046 0.0000E+00 montmorillonite-Ca 201 -2.291 0.0000E+00 ferrosilite 79 11.149 0.0000E+00 montmorillonite-K 202 -2.237 0.0000E+00 forsterite 80 21.016 0.0000E+00 montmorillonite-Mg 203 -2.480 0.0000E+00 gedrite 81 50.522 0.0000E+00 montmorillonite-Na 204 -2.038 0.0000E+00 gehlenite 82 36.628 0.0000E+00 nontronite-Ca 205 3.215 0.0000E+00 gibbsite 83 4.079 0.0000E+00 nontronite-H 206 2.533 0.0000E+00 glaucophane 84 22.975 0.0000E+00 nontronite-K 207 3.341 0.0000E+00 glaucophane-Fe 85 17.276 0.0000E+00 nontronite-Mg 208 3.075 0.0000E+00 graphite 86 -3.546 0.0000E+00 nontronite-Na 209 3.520 0.0000E+00 greenalite 87 16.140 0.0000E+00 sepiolite 210 24.118 0.0000E+00 grunerite 88 31.215 0.0000E+00 alite 211 57.999 0.0000E+00 halite 89 1.575 0.0000E+00 belite 212 30.433 0.0000E+00 hematite 90 12.566 0.0000E+00 ettringite 213 43.232 0.0000E+00 heulandite 91 -5.827 0.0000E+00 gypsum 214 -4.955 0.0000E+00 hercynite 92 17.279 0.0000E+00 hemicarboaluminate 215 70.954 0.0000E+00 hollandite 93 25.673 0.0000E+00 hydrogarnet 216 60.662 0.0000E+00 iron 94 19.086 0.0000E+00 hydrogarnet-Si 217 50.586 0.0000E+00 jadeite 95 4.215 0.0000E+00 jennite 218 24.367 0.0000E+00 julgoldite 96 70.427 0.0000E+00 monosulfoaluminate 219 53.400 0.0000E+00 kalsilite 97 7.584 0.0000E+00 monocarboaluminate 220 61.898 0.0000E+00 kaolinite 98 -1.333 0.0000E+00 portlandite 221 18.272 0.0000E+00 kyanite 99 4.876 0.0000E+00 stratlingite 222 36.502 0.0000E+00 larnite-bredigite 100 30.686 0.0000E+00 tricarboaluminate 223 70.370 0.0000E+00 laumontite 101 2.883 0.0000E+00 tobermorite 224 9.823 0.0000E+00 lawsonite 102 9.616 0.0000E+00 C4AH13 225 81.816 0.0000E+00 leucite 103 4.119 0.0000E+00 C2AH8 226 45.203 0.0000E+00 lime 104 25.998 0.0000E+00 C3A 227 86.953 0.0000E+00 lizardite 105 23.244 0.0000E+00 C4AF 228 117.416 0.0000E+00 magnesite 106 0.691 0.0000E+00 CAH10 229 28.335 0.0000E+00 magnetite 107 20.087 0.0000E+00 alabandite 230 -0.978 0.0000E+00 minnesotaite 108 10.388 0.0000E+00 alunite 231 -10.435 0.0000E+00 minnesotaite-Mg 109 20.602 0.0000E+00 artinite 232 15.121 0.0000E+00 magnesioferrite 110 26.212 0.0000E+00 boehmite 233 4.406 0.0000E+00 majorite 111 53.251 0.0000E+00 dolomite,disordered 234 1.247 0.0000E+00 manganosite 112 14.058 0.0000E+00 ferrous-oxide 235 9.812 0.0000E+00 margarite 113 17.324 0.0000E+00 huntite 236 3.770 0.0000E+00 meionite 114 44.874 0.0000E+00 hydromagnesite 237 19.995 0.0000E+00 merwinite 115 55.930 0.0000E+00 nesquehonite 238 4.723 0.0000E+00 microcline 116 -2.486 0.7820E-02 potassium-oxide 239 69.038 0.0000E+00 monticellite 117 24.339 0.0000E+00 silica-amorphous 240 -2.091 0.0000E+00 mullite-Al 118 363.148 0.0000E+00 sodium-oxide 241 55.169 0.0000E+00 mullite-Si 119 7.264 0.0000E+00 an20ab80 242 2.018 0.0000E+00 muscovite 120 2.582 0.0000E+00 an25ab75 243 2.646 0.0000E+00 paragonite 121 4.239 0.0000E+00 an30ab70 244 3.279 0.0000E+00 nepheline 122 8.339 0.0000E+00 tr.625ac.25prg.125 245 45.165 0.0000E+00 osumilite(1) 123 21.717 0.0000E+00 246 0.000 0.0000E+00 Initial composition of reactant (wt%): SiO2 62.56 MgO 3.200 Al2O3 16.62 CaO 6.450 FeO 3.530 Na2O 3.890 Fe2O3 1.770 K2O 1.000 MnO 0.1230 P2O5 0.4200E-01 Sum of wt% of reactants: 99.1850 Reactant consumed: 39.9990000 g log = 1.6020 Original solution: 1000.0103000 g Original solution / Rock added: 25.00 (Water/Rock Ratio), log = 1.3980 The following minerals and/or gases with identical index are in solid solution: H2O,gas 6 CO2,gas 6 CH4,gas 6 H2,gas 6 H2S,gas 6 S2,gas 6 CO,gas 6 SO3,gas 6 SO2,gas 6 HCl,gas 6 almandine 16 pyrope 16 spessartine 16 andradite 8 grossular 8 annite 15 phlogopite 15 biotite-Mn 15 clinochlore 1 daphnite 1 chlorite-Mn 1 diopside 5 hedenbergite 5 epidote 3 clinozoisite 3 greenalite 18 iron 9 lizardite 18 magnetite 14 talc 7 talc-Fe 7 tremolite 2 ferroactinolite 2 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 10 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 39.9990000 Water: Moles liquid = 0.5524E+02 kg liquid = 0.9951E+00 Moles total = 0.5501E+02 kg total = 0.9910E+00 Activity = 1.0000 Stoichiometric ionic strength = .6373139E-02 Osmotic coef. = 0.9583 True ionic strength = .1159234E-01 Chg. balance for total moles = -.1499E-12 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.13014E-09 -9.8856 0.11284E-09 -9.9475 0.86703E+00 -0.0620 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13826E-03 -3.8593 0.11941E-03 -3.9229 0.86367E+00 -0.0637 4 SO4-- 0.25591E-04 -4.5919 0.15141E-04 -4.8199 0.59165E+00 -0.2279 5 HCO3- 0.61575E-05 -5.2106 0.53231E-05 -5.2738 0.86448E+00 -0.0632 6 HS- 0.17873E-07 -7.7478 0.15438E-07 -7.8114 0.86375E+00 -0.0636 7 Al+++ 0.12152E-27 -27.9153 0.37828E-28 -28.4222 0.31129E+00 -0.5068 8 H4SiO4 0.56334E-03 -3.2492 0.56334E-03 -3.2492 0.10000E+01 0.0000 9 Ca++ 0.52064E-07 -7.2835 0.30659E-07 -7.5134 0.58888E+00 -0.2300 10 Mg++ 0.23325E-10 -10.6322 0.13695E-10 -10.8634 0.58715E+00 -0.2313 11 Fe++ 0.96775E-13 -13.0142 0.56861E-13 -13.2452 0.58756E+00 -0.2309 12 K+ 0.90442E-04 -4.0436 0.78198E-04 -4.1068 0.86462E+00 -0.0632 13 Na+ 0.11469E-01 -1.9405 0.99043E-02 -2.0042 0.86358E+00 -0.0637 14 Mn++ 0.18471E-10 -10.7335 0.10859E-10 -10.9642 0.58787E+00 -0.2307 15 HPO4-- 0.27274E-06 -6.5643 0.16138E-06 -6.7922 0.59170E+00 -0.2279 16 HSiO3- 0.53975E-02 -2.2678 0.46617E-02 -2.3315 0.86367E+00 -0.0637 17 Ca(HSiO3)+ 0.37640E-08 -8.4243 0.32549E-08 -8.4875 0.86474E+00 -0.0631 18 Mg(HSiO3)+ 0.20925E-11 -11.6793 0.18095E-11 -11.7424 0.86474E+00 -0.0631 19 NaHSiO3,aq 0.74675E-03 -3.1268 0.74675E-03 -3.1268 0.10000E+01 0.0000 20 AlO+ 0.46741E-15 -15.3303 0.40419E-15 -15.3934 0.86474E+00 -0.0631 22 HAlO2,aq 0.71335E-09 -9.1467 0.71335E-09 -9.1467 0.10000E+01 0.0000 23 AlO2- 0.16222E-04 -4.7899 0.13994E-04 -4.8541 0.86267E+00 -0.0642 24 CH4,aq 0.52825E-14 -14.2772 0.52722E-14 -14.2780 0.99804E+00 -0.0009 29 CO,aq 0.67358E-18 -18.1716 0.67358E-18 -18.1716 0.10000E+01 0.0000 30 CO2,aq 0.12860E-08 -8.8908 0.12834E-08 -8.8916 0.99804E+00 -0.0009 31 CO3-2 0.69740E-05 -5.1565 0.41205E-05 -5.3850 0.59084E+00 -0.2285 32 CaCO3,aq 0.15840E-08 -8.8002 0.15840E-08 -8.8002 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.48175E-11 -11.3172 0.41659E-11 -11.3803 0.86474E+00 -0.0631 34 CaCl+ 0.68515E-11 -11.1642 0.59248E-11 -11.2273 0.86474E+00 -0.0631 35 CaCl2,aq 0.16809E-15 -15.7745 0.16809E-15 -15.7745 0.10000E+01 0.0000 36 CaOH+ 0.22394E-07 -7.6499 0.19365E-07 -7.7130 0.86474E+00 -0.0631 37 CaSO4,aq 0.14741E-09 -9.8315 0.14741E-09 -9.8315 0.10000E+01 0.0000 38 HCl,aq 0.24691E-14 -14.6075 0.24691E-14 -14.6075 0.10000E+01 0.0000 43 FeCl+ 0.12428E-16 -16.9056 0.10747E-16 -16.9687 0.86474E+00 -0.0631 46 FeO,aq 0.17357E-09 -9.7605 0.17357E-09 -9.7605 0.10000E+01 0.0000 47 FeOH+ 0.18969E-10 -10.7220 0.16403E-10 -10.7851 0.86474E+00 -0.0631 48 HFeO2- 0.18635E-07 -7.7297 0.16094E-07 -7.7933 0.86367E+00 -0.0637 49 FeO+ 0.31302E-15 -15.5044 0.27068E-15 -15.5675 0.86474E+00 -0.0631 51 FeO2- 0.50368E-08 -8.2978 0.43501E-08 -8.3615 0.86367E+00 -0.0637 52 HFeO2,aq 0.62430E-10 -10.2046 0.62430E-10 -10.2046 0.10000E+01 0.0000 53 H2,aq 0.20933E-07 -7.6792 0.20892E-07 -7.6800 0.99804E+00 -0.0009 54 KCl,aq 0.16924E-09 -9.7715 0.16924E-09 -9.7715 0.10000E+01 0.0000 55 KHSO4,aq 0.37773E-18 -18.4228 0.37773E-18 -18.4228 0.10000E+01 0.0000 56 KOH,aq 0.29596E-06 -6.5288 0.29596E-06 -6.5288 0.10000E+01 0.0000 57 KSO4- 0.21272E-07 -7.6722 0.18372E-07 -7.7358 0.86367E+00 -0.0637 58 MgCO3,aq 0.17736E-12 -12.7511 0.17736E-12 -12.7511 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.21989E-14 -14.6578 0.19015E-14 -14.7209 0.86474E+00 -0.0631 60 MgCl+ 0.27739E-14 -14.5569 0.23987E-14 -14.6200 0.86474E+00 -0.0631 61 MgOH+ 0.55353E-10 -10.2569 0.47866E-10 -10.3200 0.86474E+00 -0.0631 63 MnO,aq 0.88319E-09 -9.0539 0.88319E-09 -9.0539 0.10000E+01 0.0000 64 MnOH+ 0.33651E-09 -9.4730 0.29099E-09 -9.5361 0.86474E+00 -0.0631 65 MnO2-2 0.38962E-11 -11.4094 0.23020E-11 -11.6379 0.59084E+00 -0.2285 66 HMnO2- 0.65892E-10 -10.1812 0.56909E-10 -10.2448 0.86367E+00 -0.0637 69 MnCl+ 0.92336E-14 -14.0346 0.79847E-14 -14.0977 0.86474E+00 -0.0631 70 MnSO4,aq 0.47463E-13 -13.3236 0.47463E-13 -13.3236 0.10000E+01 0.0000 71 NaCl,aq 0.39195E-06 -6.4068 0.39195E-06 -6.4068 0.10000E+01 0.0000 72 NaOH,aq 0.37712E-04 -4.4235 0.37712E-04 -4.4235 0.10000E+01 0.0000 74 OH- 0.59355E-02 -2.2265 0.51204E-02 -2.2907 0.86267E+00 -0.0642 79 HPO3-2 0.17783E-16 -16.7500 0.10507E-16 -16.9785 0.59084E+00 -0.2285 82 H3PO4,aq 0.14371E-16 -16.8425 0.14371E-16 -16.8425 0.10000E+01 0.0000 83 H2PO4- 0.38871E-09 -9.4104 0.33592E-09 -9.4738 0.86420E+00 -0.0634 84 PO4-3 0.36323E-08 -8.4398 0.11669E-08 -8.9330 0.32125E+00 -0.4932 87 H2P2O7-2 0.14975E-19 -19.8246 0.88479E-20 -20.0532 0.59084E+00 -0.2285 88 HP2O7-3 0.50271E-16 -16.2987 0.15657E-16 -16.8053 0.31145E+00 -0.5066 89 P2O7-4 0.25568E-15 -15.5923 0.33149E-16 -16.4795 0.12965E+00 -0.8872 90 H2S,aq 0.53943E-11 -11.2681 0.53838E-11 -11.2689 0.99804E+00 -0.0009 91 S2-2 0.42781E-18 -18.3687 0.25277E-18 -18.5973 0.59084E+00 -0.2285 97 SO3-2 0.68931E-13 -13.1616 0.41106E-13 -13.3861 0.59633E+00 -0.2245 98 HSO3- 0.33625E-15 -15.4733 0.29041E-15 -15.5370 0.86367E+00 -0.0637 99 HSO4- 0.19028E-11 -11.7206 0.16465E-11 -11.7834 0.86527E+00 -0.0628 101 S2O3-2 0.16206E-17 -17.7903 0.95753E-18 -18.0188 0.59084E+00 -0.2285 Charge balance for all species = -.1498E-12 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.1301435E-09 -.1218977E-01 -.1227525E+02 0.0000 2 H2O 0.1000000E+01 0.5550811E+02 0.9990745E+06 0.0000 3 Cl- 0.1382618E-03 0.1386539E-03 0.4911172E+01 6.0246 4 SO4-- 0.2559082E-04 0.2560765E-04 0.2457647E+01 15.0752 5 HCO3- 0.6157531E-05 0.1313439E-04 0.8006860E+00 4.6737 6 HS- 0.1787288E-07 0.2247413E-07 0.7425802E-03 2.1361 7 Al+++ 0.1215215E-27 0.1622259E-04 0.4373068E+00 1.4204 8 H4SiO4 0.5633406E-03 0.6707599E-02 0.6441099E+03 -3.2492 9 Ca++ 0.5206373E-07 0.7996440E-07 0.3201862E-02 12.3816 10 Mg++ 0.2332537E-10 0.8095291E-10 0.1966315E-05 9.0317 11 Fe++ 0.9677518E-13 0.2392673E-07 0.1335006E-02 6.6499 12 K+ 0.9044221E-04 0.9075960E-04 0.3545614E+01 5.8407 13 Na+ 0.1146886E-01 0.1225371E-01 0.2814510E+03 7.9434 14 Mn++ 0.1847093E-10 0.1308013E-08 0.7179346E-04 8.9309 15 HPO4-- 0.2727367E-06 0.2767577E-06 0.2653847E-01 13.1029 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.6623110E+00 -.1213001E-01 -.6501810E+00 0.0000000E+00 2 H2O 0.5500685E+02 0.5523598E+02 -.2291304E+00 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.1134013E-02 0.2548211E-04 0.1108531E-02 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.1108509E-02 0.2236395E-07 -.1108531E-02 0.0000000E+00 7 Al+++ 0.1304264E+00 0.1614306E-04 0.1304103E+00 0.0000000E+00 8 H4SiO4 0.4165009E+00 0.6674714E-02 0.4098262E+00 0.0000000E+00 9 Ca++ 0.4601903E-01 0.7957237E-07 0.4601895E-01 0.0000000E+00 10 Mg++ 0.3174524E-01 0.8055603E-10 0.3174524E-01 0.0000000E+00 11 Fe++ 0.2851963E-01 0.2380942E-07 0.2851961E-01 0.0000000E+00 12 K+ 0.8492357E-02 0.9031464E-04 0.8402042E-02 0.0000000E+00 13 Na+ 0.5036856E-01 0.1219364E-01 0.3817492E-01 0.0000000E+00 14 Mn++ 0.6935265E-03 0.1301600E-08 0.6935252E-03 0.0000000E+00 15 HPO4-- 0.2366971E-03 0.2754009E-06 0.2364217E-03 0.0000000E+00 Chg. balance for solid moles: 0.1112E-15 Mass of aqueous solution: 0.996014E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 39.9990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 0.3817E-01 -1.418 10.01 1.000 22.92 3.843 andradite 0.4434E-02 -2.353 2.253 0.353 5.160 0.5854 grossular 0.2664E-03 -3.574 0.1200 -0.921 0.2748 0.3339E-01 apatite-OH 0.7881E-04 -4.103 0.3959E-01 -1.402 0.9065E-01 0.1258E-01 clinochlore 0.6349E-02 -2.197 3.529 0.548 8.081 1.342 daphnite 0.2766E-02 -2.558 1.973 0.295 4.519 0.5980 chlorite-Mn 0.1387E-03 -3.858 0.9834E-01 -1.007 0.2252 0.3134E-01 microcline 0.7820E-02 -2.107 2.177 0.338 4.984 0.8502 stilbite 0.3152E-01 -1.501 22.22 1.347 50.87 10.36 stilpnomelane-Fe 0.1165E-02 -2.934 1.255 0.099 2.875 0.4336 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.9433E+00 0.9433E+00 1.0000 -0.025 grossular 0.5667E-01 0.5667E-01 1.0000 -1.247 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.6861E+00 0.6861E+00 1.0000 -0.164 daphnite 0.2989E+00 0.2989E+00 1.0000 -0.524 chlorite-Mn 0.1499E-01 0.1499E-01 1.0000 -1.824 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 43.670928 g Volume = 18.091159 cm3 Porosity: -6.4211% V(tot) - V(min): -.10916E+01 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 39.9990000 g log = 1.6020 Original solution: 1000.0103000 g Original solution / Rock added: 25.00 (Water/Rock Ratio), log = 1.3980 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0203 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.1000E+01 0.9860 0.1006E+01 0.1020E+01 CO2,gas 0.1336E-06 1.0071 0.1373E-06 0.1363E-06 CH4,gas 0.7512E-11 1.0125 0.7760E-11 0.7664E-11 H2,gas 0.2687E-04 1.0005 0.2743E-04 0.2741E-04 H2S,gas 0.1456E-09 0.9960 0.1480E-09 0.1486E-09 S2,gas 0.1071E-29 1.0000 0.1093E-29 0.1093E-29 CO,gas 0.9838E-15 1.0000 0.1004E-14 0.1004E-14 SO3,gas 0.7144E-40 1.0000 0.7289E-40 0.7289E-40 SO2,gas 0.7623E-22 1.0000 0.7778E-22 0.7778E-22 HCl,gas 0.4270E-17 1.0000 0.4357E-17 0.4357E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 16 albite -0.38 -0.38 0.00 0.000 -0.13080E-10 22 andradite 39.01 39.01 0.00 0.000 0.00000E+00 23 grossular 32.73 32.73 0.00 0.000 -0.12132E-10 32 apatite-OH -18.15 -18.15 0.00 0.000 -0.12132E-10 46 clinochlore 39.07 39.07 0.00 0.000 -0.48529E-10 47 daphnite 28.97 28.97 0.00 0.000 -0.24265E-10 48 chlorite-Mn 46.87 46.87 0.00 0.000 -0.12132E-10 116 microcline -2.49 -2.49 0.00 0.000 -0.10616E-10 163 stilbite -7.52 -7.52 0.00 0.000 -0.90992E-11 164 stilpnomelane-Fe 13.02 13.02 0.00 0.000 -0.27298E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -15.22 -8.56 -2.854 0.14618E+05 -6.862 3 CH4,gas 4.54 -8.27 -12.81 -3.202 0.21871E+05 -11.110 4 H2,gas 8.00 1.74 -6.26 -3.578 0.10690E+05 -4.562 5 H2S,gas -6.23 -17.76 -11.53 -5.764 0.19685E+05 -9.830 6 S2,gas -7.34 -39.00 -31.66 -4.871 0.54059E+05 -29.961 7 CO,gas 3.21 -13.48 -16.70 -5.138 0.28510E+05 -14.998 8 SO3,gas 17.12 -24.71 -41.84 -10.459 0.71434E+05 -40.137 9 SO2,gas 0.83 -22.98 -23.81 -6.349 0.40652E+05 -22.109 10 HCl,gas 5.19 -13.87 -19.06 -9.530 0.32544E+05 -17.361 11 acmite 7.71 7.23 -0.48 -0.050 0.82709E+03 15 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 19 spessartine 24.46 19.89 -4.57 -0.229 0.78058E+04 20 analcite 3.32 2.87 -0.46 -0.051 0.77946E+03 26 annite 20.12 17.46 -2.66 -0.148 0.45422E+04 27 phlogopite 27.06 24.61 -2.46 -0.136 0.41937E+04 29 anorthite 12.71 8.72 -3.99 -0.307 0.68064E+04 35 aragonite 0.97 -2.84 -3.81 -1.269 0.64991E+04 36 brucite 12.57 9.03 -3.54 -0.707 0.60392E+04 37 calcite 0.81 -2.84 -3.65 -1.217 0.62349E+04 38 carnegieite-low 9.02 6.11 -2.91 -0.416 0.49665E+04 39 carnegieite-high 10.09 6.11 -3.98 -0.568 0.67935E+04 40 carpholite-Mg 8.58 5.37 -3.21 -0.214 0.54775E+04 41 carpholite-Fe 6.71 2.99 -3.72 -0.248 0.63523E+04 42 celadonite 5.34 3.30 -2.05 -0.120 0.34929E+04 43 celadonite-Fe 3.88 0.91 -2.96 -0.174 0.50581E+04 44 chrysotile 23.89 20.60 -3.30 -0.275 0.56276E+04 50 chloritoid-Mg 13.20 8.62 -4.57 -0.305 0.78106E+04 51 chloritoid-Fe 9.17 6.24 -2.93 -0.195 0.50064E+04 52 chloritoid-Mn 11.40 8.52 -2.88 -0.192 0.49150E+04 54 coesite -2.38 -3.25 -0.87 -0.291 0.14909E+04 61 cristobalite -2.56 -3.25 -0.69 -0.230 0.11763E+04 63 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71234E+04 65 diaspore 2.87 1.42 -1.45 -0.242 0.24814E+04 67 diopside 16.18 14.91 -1.27 -0.127 0.21625E+04 68 hedenbergite 14.21 12.53 -1.68 -0.168 0.28603E+04 75 epidote 24.67 23.64 -1.03 -0.050 0.17638E+04 76 clinozoisite 22.81 19.28 -3.53 -0.160 0.60258E+04 77 epidote-Fe 29.84 28.00 -1.84 -0.096 0.31484E+04 78 fayalite 14.05 10.05 -4.00 -0.571 0.68216E+04 79 ferrosilite 11.15 6.80 -4.35 -0.435 0.74243E+04 83 gibbsite 4.08 1.42 -2.66 -0.380 0.45399E+04 84 glaucophane 22.97 19.83 -3.15 -0.085 0.53717E+04 85 glaucophane-Fe 17.28 12.68 -4.59 -0.124 0.78412E+04 87 greenalite 16.14 13.45 -2.69 -0.224 0.45901E+04 90 hematite 12.57 11.56 -1.01 -0.122 0.17166E+04 91 heulandite -5.83 -7.52 -1.69 -0.077 0.28938E+04 95 jadeite 4.22 2.87 -1.35 -0.135 0.23049E+04 96 julgoldite 70.43 66.45 -3.97 -0.103 0.67859E+04 97 kalsilite 7.58 4.01 -3.57 -0.510 0.60990E+04 98 kaolinite -1.33 -3.66 -2.32 -0.211 0.39695E+04 101 laumontite 2.88 2.23 -0.66 -0.044 0.11231E+04 102 lawsonite 9.62 8.72 -0.89 -0.059 0.15230E+04 103 leucite 4.12 0.76 -3.36 -0.336 0.57305E+04 105 lizardite 23.24 20.60 -2.65 -0.221 0.45202E+04 107 magnetite 20.09 18.21 -1.88 -0.153 0.32044E+04 108 minnesotaite 10.39 6.95 -3.44 -0.202 0.58657E+04 120 muscovite 2.58 0.35 -2.23 -0.131 0.38043E+04 121 paragonite 4.24 2.46 -1.78 -0.105 0.30434E+04 122 nepheline 8.34 6.11 -2.22 -0.318 0.37989E+04 128 periclase-Fe 11.63 6.65 -4.98 -1.244 0.84975E+04 134 phlogopite-Na 29.65 26.71 -2.94 -0.163 0.50125E+04 136 prehnite 19.37 17.86 -1.52 -0.089 0.25874E+04 137 prehnite-Fe 22.50 22.22 -0.28 -0.017 0.48047E+03 138 pumpellyite-Fe 46.27 43.78 -2.49 -0.055 0.42449E+04 139 pumpellyite-Mg 48.99 46.17 -2.83 -0.063 0.48317E+04 145 pyroxmangite 7.40 5.68 -1.72 -0.343 0.29318E+04 146 pyrophyllite -6.18 -10.16 -3.98 -0.249 0.67961E+04 147 quartz -2.99 -3.25 -0.26 -0.087 0.44359E+03 152 rhodonite 7.45 5.68 -1.76 -0.353 0.30121E+04 153 sanidine -1.28 -2.49 -1.21 -0.093 0.20677E+04 165 stilpnomelane-Mg 27.44 24.93 -2.52 -0.075 0.42954E+04 171 talc 16.49 14.10 -2.39 -0.141 0.40860E+04 174 tephroite 18.09 14.61 -3.47 -0.496 0.59306E+04 178 tridymite -2.63 -3.25 -0.62 -0.208 0.10636E+04 179 tremolite 47.87 43.93 -3.94 -0.107 0.67299E+04 187 wairakite 3.95 2.23 -1.72 -0.101 0.29451E+04 188 walstromite 11.51 9.13 -2.38 -0.475 0.40583E+04 189 wollastonite 10.46 9.13 -1.33 -0.266 0.22688E+04 190 pseudo-wollastonite 11.00 9.13 -1.87 -0.373 0.31886E+04 191 zoisite 22.85 19.28 -3.57 -0.162 0.60998E+04 192 akaganeite 7.75 5.78 -1.97 -0.427 0.33708E+04 193 beidellite-Ca -1.65 -6.57 -4.93 -0.305 0.84118E+04 197 beidellite-Na -1.34 -5.99 -4.65 -0.285 0.79423E+04 199 chalcedony -2.80 -3.25 -0.45 -0.149 0.76289E+03 201 montmorillonite-Ca -2.29 -5.60 -3.31 -0.205 0.56528E+04 202 montmorillonite-K -2.24 -5.72 -3.48 -0.213 0.59423E+04 203 montmorillonite-Mg -2.48 -6.15 -3.67 -0.227 0.62736E+04 204 montmorillonite-Na -2.04 -5.02 -2.99 -0.183 0.50972E+04 205 nontronite-Ca 3.21 2.15 -1.07 -0.069 0.18213E+04 206 nontronite-H 2.53 0.10 -2.43 -0.163 0.41454E+04 207 nontronite-K 3.34 2.03 -1.31 -0.084 0.22340E+04 208 nontronite-Mg 3.07 1.60 -1.48 -0.096 0.25262E+04 209 nontronite-Na 3.52 2.73 -0.79 -0.051 0.13549E+04 224 tobermorite 9.82 7.06 -2.76 -0.753 0.47098E+04 233 boehmite 4.41 1.42 -2.99 -0.498 0.50983E+04 235 ferrous-oxide 9.81 6.65 -3.16 -0.790 0.53985E+04 240 silica-amorphous -2.09 -3.25 -1.16 -0.386 0.19771E+04 242 an20ab80 2.02 1.44 -0.58 -0.045 0.99042E+03 243 an25ab75 2.65 1.89 -0.75 -0.058 0.12850E+04 244 an30ab70 3.28 2.35 -0.93 -0.072 0.15892E+04 245 tr.625ac.25prg.125 45.16 42.16 -3.01 -0.081 0.51313E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 2.0000000 g Current total amount of reactant added: 39.9990000 g New total amount of reactant added: 41.9990000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.1498E-12 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 9 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 41.9990000 Water: Moles liquid = 0.5522E+02 kg liquid = 0.9949E+00 Moles total = 0.5498E+02 kg total = 0.9905E+00 Activity = 1.0000 Stoichiometric ionic strength = .6595095E-02 Osmotic coef. = 0.9577 True ionic strength = .1198879E-01 Chg. balance for total moles = -.1498E-12 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.12660E-09 -9.8976 0.10957E-09 -9.9603 0.86549E+00 -0.0627 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13828E-03 -3.8592 0.11921E-03 -3.9237 0.86205E+00 -0.0645 4 SO4-- 0.25525E-04 -4.5930 0.14991E-04 -4.8242 0.58732E+00 -0.2311 5 HCO3- 0.60450E-05 -5.2186 0.52161E-05 -5.2827 0.86288E+00 -0.0641 6 HS- 0.89336E-07 -7.0490 0.77019E-07 -7.1134 0.86213E+00 -0.0644 7 Al+++ 0.10433E-27 -27.9816 0.31937E-28 -28.4957 0.30612E+00 -0.5141 8 H4SiO4 0.56710E-03 -3.2463 0.56710E-03 -3.2463 0.10000E+01 0.0000 9 Ca++ 0.55532E-07 -7.2555 0.32458E-07 -7.4887 0.58449E+00 -0.2332 10 Mg++ 0.22925E-10 -10.6397 0.13359E-10 -10.8742 0.58273E+00 -0.2345 11 Fe++ 0.93399E-13 -13.0297 0.54465E-13 -13.2639 0.58315E+00 -0.2342 12 K+ 0.93541E-04 -4.0290 0.80727E-04 -4.0930 0.86302E+00 -0.0640 13 Na+ 0.11862E-01 -1.9258 0.10225E-01 -1.9904 0.86195E+00 -0.0645 14 Mn++ 0.18153E-10 -10.7410 0.10592E-10 -10.9750 0.58347E+00 -0.2340 15 HPO4-- 0.24025E-06 -6.6193 0.14111E-06 -6.8504 0.58738E+00 -0.2311 16 HSiO3- 0.56061E-02 -2.2513 0.48327E-02 -2.3158 0.86205E+00 -0.0645 17 Ca(HSiO3)+ 0.41387E-08 -8.3831 0.35722E-08 -8.4471 0.86314E+00 -0.0639 18 Mg(HSiO3)+ 0.21199E-11 -11.6737 0.18298E-11 -11.7376 0.86314E+00 -0.0639 19 NaHSiO3,aq 0.79918E-03 -3.0974 0.79918E-03 -3.0974 0.10000E+01 0.0000 20 AlO+ 0.41927E-15 -15.3775 0.36189E-15 -15.4414 0.86314E+00 -0.0639 22 HAlO2,aq 0.65774E-09 -9.1819 0.65774E-09 -9.1819 0.10000E+01 0.0000 23 AlO2- 0.15433E-04 -4.8116 0.13288E-04 -4.8766 0.86101E+00 -0.0650 24 CH4,aq 0.26084E-13 -13.5836 0.26031E-13 -13.5845 0.99797E+00 -0.0009 29 CO,aq 0.96734E-18 -18.0144 0.96734E-18 -18.0144 0.10000E+01 0.0000 30 CO2,aq 0.12237E-08 -8.9123 0.12212E-08 -8.9132 0.99797E+00 -0.0009 31 CO3-2 0.70896E-05 -5.1494 0.41580E-05 -5.3811 0.58650E+00 -0.2317 32 CaCO3,aq 0.16922E-08 -8.7715 0.16922E-08 -8.7715 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.50068E-11 -11.3004 0.43216E-11 -11.3644 0.86314E+00 -0.0639 34 CaCl+ 0.72543E-11 -11.1394 0.62615E-11 -11.2033 0.86314E+00 -0.0639 35 CaCl2,aq 0.17733E-15 -15.7512 0.17733E-15 -15.7512 0.10000E+01 0.0000 36 CaOH+ 0.24459E-07 -7.6116 0.21112E-07 -7.6755 0.86314E+00 -0.0639 37 CaSO4,aq 0.15451E-09 -9.8110 0.15451E-09 -9.8110 0.10000E+01 0.0000 38 HCl,aq 0.23935E-14 -14.6210 0.23935E-14 -14.6210 0.10000E+01 0.0000 43 FeCl+ 0.11906E-16 -16.9242 0.10277E-16 -16.9881 0.86314E+00 -0.0639 46 FeO,aq 0.17631E-09 -9.7537 0.17631E-09 -9.7537 0.10000E+01 0.0000 47 FeOH+ 0.18746E-10 -10.7271 0.16180E-10 -10.7910 0.86314E+00 -0.0639 48 HFeO2- 0.19531E-07 -7.7093 0.16836E-07 -7.7737 0.86205E+00 -0.0645 49 FeO+ 0.25180E-15 -15.5989 0.21734E-15 -15.6629 0.86314E+00 -0.0639 51 FeO2- 0.42969E-08 -8.3668 0.37042E-08 -8.4313 0.86205E+00 -0.0645 52 HFeO2,aq 0.51621E-10 -10.2872 0.51621E-10 -10.2872 0.10000E+01 0.0000 53 H2,aq 0.31596E-07 -7.5004 0.31532E-07 -7.5013 0.99797E+00 -0.0009 54 KCl,aq 0.17441E-09 -9.7584 0.17441E-09 -9.7584 0.10000E+01 0.0000 55 KHSO4,aq 0.37492E-18 -18.4261 0.37492E-18 -18.4261 0.10000E+01 0.0000 56 KOH,aq 0.31464E-06 -6.5022 0.31464E-06 -6.5022 0.10000E+01 0.0000 57 KSO4- 0.21785E-07 -7.6618 0.18779E-07 -7.7263 0.86205E+00 -0.0645 58 MgCO3,aq 0.17458E-12 -12.7580 0.17458E-12 -12.7580 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.21057E-14 -14.6766 0.18175E-14 -14.7405 0.86314E+00 -0.0639 60 MgCl+ 0.27061E-14 -14.5677 0.23357E-14 -14.6316 0.86314E+00 -0.0639 61 MgOH+ 0.55705E-10 -10.2541 0.48081E-10 -10.3180 0.86314E+00 -0.0639 63 MnO,aq 0.91362E-09 -9.0392 0.91362E-09 -9.0392 0.10000E+01 0.0000 64 MnOH+ 0.33865E-09 -9.4702 0.29230E-09 -9.5342 0.86314E+00 -0.0639 65 MnO2-2 0.43060E-11 -11.3659 0.25254E-11 -11.5977 0.58650E+00 -0.2317 66 HMnO2- 0.70326E-10 -10.1529 0.60624E-10 -10.2174 0.86205E+00 -0.0645 69 MnCl+ 0.90078E-14 -14.0454 0.77750E-14 -14.1093 0.86314E+00 -0.0639 70 MnSO4,aq 0.45840E-13 -13.3388 0.45840E-13 -13.3388 0.10000E+01 0.0000 71 NaCl,aq 0.40393E-06 -6.3937 0.40393E-06 -6.3937 0.10000E+01 0.0000 72 NaOH,aq 0.40092E-04 -4.3969 0.40092E-04 -4.3969 0.10000E+01 0.0000 74 OH- 0.61242E-02 -2.2130 0.52730E-02 -2.2779 0.86101E+00 -0.0650 79 HPO3-2 0.23643E-16 -16.6263 0.13866E-16 -16.8580 0.58650E+00 -0.2317 82 H3PO4,aq 0.11849E-16 -16.9263 0.11849E-16 -16.9263 0.10000E+01 0.0000 83 H2PO4- 0.33067E-09 -9.4806 0.28524E-09 -9.5448 0.86258E+00 -0.0642 84 PO4-3 0.33231E-08 -8.4785 0.10508E-08 -8.9785 0.31620E+00 -0.5000 87 H2P2O7-2 0.10877E-19 -19.9635 0.63794E-20 -20.1952 0.58650E+00 -0.2317 88 HP2O7-3 0.37956E-16 -16.4207 0.11625E-16 -16.9346 0.30629E+00 -0.5139 89 P2O7-4 0.20131E-15 -15.6961 0.25346E-16 -16.5961 0.12591E+00 -0.8999 90 H2S,aq 0.26135E-10 -10.5828 0.26082E-10 -10.5837 0.99797E+00 -0.0009 91 S2-2 0.71075E-17 -17.1483 0.41685E-17 -17.3800 0.58650E+00 -0.2317 97 SO3-2 0.10374E-12 -12.9840 0.61427E-13 -13.2116 0.59210E+00 -0.2276 98 HSO3- 0.48887E-15 -15.3108 0.42143E-15 -15.3753 0.86205E+00 -0.0645 99 HSO4- 0.18329E-11 -11.7369 0.15830E-11 -11.8005 0.86369E+00 -0.0636 101 S2O3-2 0.78314E-17 -17.1062 0.45931E-17 -17.3379 0.58650E+00 -0.2317 Charge balance for all species = -.1503E-12 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.1266009E-09 -.1263878E-01 -.1272696E+02 0.0000 2 H2O 0.1000000E+01 0.5550804E+02 0.9990392E+06 0.0000 3 Cl- 0.1382823E-03 0.1386864E-03 0.4912153E+01 6.0366 4 SO4-- 0.2552481E-04 0.2553940E-04 0.2451013E+01 15.0964 5 HCO3- 0.6044952E-05 0.1313746E-04 0.8008458E+00 4.6776 6 HS- 0.8933614E-07 0.9671772E-07 0.3195594E-02 2.8469 7 Al+++ 0.1043301E-27 0.1543328E-04 0.4160155E+00 1.3852 8 H4SiO4 0.5671015E-03 0.6972344E-02 0.6695098E+03 -3.2463 9 Ca++ 0.5553165E-07 0.8598850E-07 0.3442956E-02 12.4319 10 Mg++ 0.2292492E-10 0.8092938E-10 0.1965676E-05 9.0464 11 Fe++ 0.9339920E-13 0.2407452E-07 0.1343206E-02 6.6567 12 K+ 0.9354070E-04 0.9387730E-04 0.3667285E+01 5.8673 13 Na+ 0.1186219E-01 0.1270186E-01 0.2917345E+03 7.9699 14 Mn++ 0.1815319E-10 0.1345107E-08 0.7382693E-04 8.9456 15 HPO4-- 0.2402457E-06 0.2438995E-06 0.2338688E-01 13.0702 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.6954280E+00 -.1257387E-01 -.6828542E+00 0.0000000E+00 2 H2O 0.5498178E+02 0.5522300E+02 -.2412206E+00 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.1189440E-02 0.2540825E-04 0.1164032E-02 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.1163935E-02 0.9622105E-07 -.1164032E-02 0.0000000E+00 7 Al+++ 0.1369479E+00 0.1535403E-04 0.1369325E+00 0.0000000E+00 8 H4SiO4 0.4373265E+00 0.6936540E-02 0.4303899E+00 0.0000000E+00 9 Ca++ 0.4831931E-01 0.8554693E-07 0.4831923E-01 0.0000000E+00 10 Mg++ 0.3333254E-01 0.8051379E-10 0.3333254E-01 0.0000000E+00 11 Fe++ 0.2994565E-01 0.2395089E-07 0.2994562E-01 0.0000000E+00 12 K+ 0.8916985E-02 0.9339522E-04 0.8823590E-02 0.0000000E+00 13 Na+ 0.5287905E-01 0.1263664E-01 0.4024241E-01 0.0000000E+00 14 Mn++ 0.7282037E-03 0.1338200E-08 0.7282024E-03 0.0000000E+00 15 HPO4-- 0.2485323E-03 0.2426470E-06 0.2482897E-03 0.0000000E+00 Chg. balance for solid moles: 0.1908E-16 Mass of aqueous solution: 0.995816E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 41.9990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 0.4024E-01 -1.395 10.55 1.023 23.01 4.051 andradite 0.4656E-02 -2.332 2.366 0.374 5.160 0.6147 grossular 0.3119E-03 -3.506 0.1405 -0.852 0.3064 0.3909E-01 apatite-OH 0.8276E-04 -4.082 0.4157E-01 -1.381 0.9067E-01 0.1321E-01 clinochlore 0.6667E-02 -2.176 3.705 0.569 8.081 1.409 daphnite 0.2852E-02 -2.545 2.035 0.309 4.437 0.6166 chlorite-Mn 0.1456E-03 -3.837 0.1033 -0.986 0.2252 0.3290E-01 microcline 0.8186E-02 -2.087 2.279 0.358 4.969 0.8900 stilbite 0.3300E-01 -1.481 23.26 1.367 50.72 10.85 stilpnomelane-Fe 0.1275E-02 -2.894 1.374 0.138 2.997 0.4748 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.9372E+00 0.9372E+00 1.0000 -0.028 grossular 0.6279E-01 0.6279E-01 1.0000 -1.202 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.6898E+00 0.6898E+00 1.0000 -0.161 daphnite 0.2951E+00 0.2951E+00 1.0000 -0.530 chlorite-Mn 0.1507E-01 0.1507E-01 1.0000 -1.822 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 45.853591 g Volume = 18.988916 cm3 Porosity: -6.6817% V(tot) - V(min): -.11893E+01 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 41.9990000 g log = 1.6232 Original solution: 1000.0103000 g Original solution / Rock added: 23.81 (Water/Rock Ratio), log = 1.3768 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0203 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.1000E+01 0.9860 0.1006E+01 0.1020E+01 CO2,gas 0.1272E-06 1.0071 0.1307E-06 0.1297E-06 CH4,gas 0.3709E-10 1.0125 0.3832E-10 0.3784E-10 H2,gas 0.4055E-04 1.0005 0.4140E-04 0.4138E-04 H2S,gas 0.7055E-09 0.9960 0.7170E-09 0.7198E-09 S2,gas 0.1104E-28 1.0000 0.1126E-28 0.1126E-28 CO,gas 0.1413E-14 1.0000 0.1442E-14 0.1442E-14 SO3,gas 0.6670E-40 1.0000 0.6805E-40 0.6805E-40 SO2,gas 0.1074E-21 1.0000 0.1096E-21 0.1096E-21 HCl,gas 0.4139E-17 1.0000 0.4223E-17 0.4223E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 16 albite -0.38 -0.38 0.00 0.000 -0.94784E-12 22 andradite 39.01 39.01 0.00 0.000 0.24265E-10 23 grossular 32.73 32.73 0.00 0.000 -0.24265E-10 32 apatite-OH -18.15 -18.15 0.00 0.000 0.12132E-10 46 clinochlore 39.07 39.07 0.00 0.000 0.00000E+00 47 daphnite 28.97 28.97 0.00 0.000 0.18198E-10 48 chlorite-Mn 46.87 46.87 0.00 0.000 0.00000E+00 116 microcline -2.49 -2.49 0.00 0.000 -0.10616E-10 163 stilbite -7.52 -7.52 0.00 0.000 0.15165E-10 164 stilpnomelane-Fe 13.02 13.02 0.00 0.000 0.21232E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -15.24 -8.58 -2.861 0.14655E+05 -6.884 3 CH4,gas 4.54 -7.57 -12.12 -3.029 0.20687E+05 -10.417 4 H2,gas 8.00 1.92 -6.08 -3.475 0.10385E+05 -4.383 5 H2S,gas -6.23 -17.07 -10.84 -5.422 0.18515E+05 -9.144 6 S2,gas -7.34 -37.98 -30.65 -4.715 0.52330E+05 -28.948 7 CO,gas 3.21 -13.33 -16.54 -5.089 0.28242E+05 -14.841 8 SO3,gas 17.12 -24.74 -41.87 -10.467 0.71485E+05 -40.167 9 SO2,gas 0.83 -22.83 -23.66 -6.309 0.40397E+05 -21.960 10 HCl,gas 5.19 -13.88 -19.07 -9.537 0.32567E+05 -17.374 11 acmite 7.71 7.18 -0.53 -0.056 0.91282E+03 15 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 19 spessartine 24.46 19.87 -4.59 -0.229 0.78360E+04 20 analcite 3.32 2.86 -0.46 -0.051 0.78439E+03 26 annite 20.12 17.48 -2.64 -0.147 0.45072E+04 27 phlogopite 27.06 24.65 -2.41 -0.134 0.41184E+04 29 anorthite 12.71 8.71 -4.00 -0.308 0.68310E+04 35 aragonite 0.97 -2.81 -3.78 -1.259 0.64501E+04 36 brucite 12.57 9.05 -3.52 -0.704 0.60140E+04 37 calcite 0.81 -2.81 -3.62 -1.208 0.61859E+04 38 carnegieite-low 9.02 6.11 -2.91 -0.416 0.49764E+04 39 carnegieite-high 10.09 6.11 -3.98 -0.569 0.68034E+04 40 carpholite-Mg 8.58 5.32 -3.26 -0.217 0.55629E+04 41 carpholite-Fe 6.71 2.93 -3.78 -0.252 0.64512E+04 42 celadonite 5.34 3.31 -2.03 -0.119 0.34629E+04 43 celadonite-Fe 3.88 0.92 -2.95 -0.174 0.50415E+04 44 chrysotile 23.89 20.65 -3.25 -0.270 0.55424E+04 50 chloritoid-Mg 13.20 8.57 -4.63 -0.308 0.79009E+04 51 chloritoid-Fe 9.17 6.18 -2.99 -0.200 0.51102E+04 52 chloritoid-Mn 11.40 8.47 -2.93 -0.195 0.50054E+04 54 coesite -2.38 -3.25 -0.87 -0.290 0.14860E+04 61 cristobalite -2.56 -3.25 -0.69 -0.229 0.11713E+04 63 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71234E+04 65 diaspore 2.87 1.39 -1.49 -0.248 0.25416E+04 67 diopside 16.18 14.99 -1.20 -0.120 0.20417E+04 68 hedenbergite 14.21 12.60 -1.61 -0.161 0.27530E+04 75 epidote 24.67 23.59 -1.08 -0.052 0.18387E+04 76 clinozoisite 22.81 19.28 -3.53 -0.160 0.60199E+04 77 epidote-Fe 29.84 27.91 -1.94 -0.101 0.33041E+04 78 fayalite 14.05 10.07 -3.98 -0.568 0.67934E+04 79 ferrosilite 11.15 6.82 -4.33 -0.433 0.73911E+04 83 gibbsite 4.08 1.39 -2.69 -0.385 0.46001E+04 84 glaucophane 22.97 19.88 -3.10 -0.084 0.52865E+04 85 glaucophane-Fe 17.28 12.71 -4.57 -0.123 0.77964E+04 87 greenalite 16.14 13.48 -2.66 -0.222 0.45453E+04 90 hematite 12.57 11.40 -1.17 -0.142 0.19986E+04 91 heulandite -5.83 -7.52 -1.69 -0.077 0.28938E+04 95 jadeite 4.22 2.86 -1.35 -0.135 0.23099E+04 96 julgoldite 70.43 66.35 -4.07 -0.106 0.69536E+04 97 kalsilite 7.58 4.01 -3.58 -0.511 0.61089E+04 98 kaolinite -1.33 -3.72 -2.39 -0.217 0.40800E+04 101 laumontite 2.88 2.22 -0.67 -0.044 0.11379E+04 102 lawsonite 9.62 8.71 -0.91 -0.060 0.15477E+04 103 leucite 4.12 0.76 -3.36 -0.336 0.57354E+04 105 lizardite 23.24 20.65 -2.60 -0.216 0.44350E+04 107 magnetite 20.09 18.05 -2.03 -0.166 0.34747E+04 108 minnesotaite 10.39 6.98 -3.40 -0.200 0.58110E+04 120 muscovite 2.58 0.28 -2.30 -0.135 0.39247E+04 121 paragonite 4.24 2.39 -1.85 -0.109 0.31638E+04 122 nepheline 8.34 6.11 -2.23 -0.319 0.38088E+04 128 periclase-Fe 11.63 6.66 -4.97 -1.242 0.84859E+04 134 phlogopite-Na 29.65 26.76 -2.89 -0.161 0.49372E+04 136 prehnite 19.37 17.90 -1.48 -0.087 0.25213E+04 137 prehnite-Fe 22.50 22.21 -0.29 -0.017 0.49516E+03 138 pumpellyite-Fe 46.27 43.83 -2.44 -0.054 0.41612E+04 139 pumpellyite-Mg 48.99 46.22 -2.77 -0.062 0.47346E+04 145 pyroxmangite 7.40 5.70 -1.70 -0.340 0.29018E+04 146 pyrophyllite -6.18 -10.21 -4.04 -0.252 0.68968E+04 147 quartz -2.99 -3.25 -0.26 -0.086 0.43866E+03 152 rhodonite 7.45 5.70 -1.75 -0.349 0.29820E+04 153 sanidine -1.28 -2.49 -1.21 -0.093 0.20677E+04 165 stilpnomelane-Mg 27.44 24.97 -2.48 -0.074 0.42280E+04 171 talc 16.49 14.15 -2.34 -0.137 0.39909E+04 174 tephroite 18.09 14.64 -3.44 -0.492 0.58754E+04 178 tridymite -2.63 -3.25 -0.62 -0.207 0.10586E+04 179 tremolite 47.87 44.12 -3.74 -0.101 0.63932E+04 187 wairakite 3.95 2.22 -1.73 -0.102 0.29599E+04 188 walstromite 11.51 9.19 -2.32 -0.465 0.39676E+04 189 wollastonite 10.46 9.19 -1.28 -0.255 0.21780E+04 190 pseudo-wollastonite 11.00 9.19 -1.81 -0.363 0.30978E+04 191 zoisite 22.85 19.28 -3.57 -0.162 0.60939E+04 192 akaganeite 7.75 5.70 -2.06 -0.445 0.35118E+04 193 beidellite-Ca -1.65 -6.64 -4.99 -0.309 0.85197E+04 197 beidellite-Na -1.34 -6.06 -4.71 -0.289 0.80494E+04 199 chalcedony -2.80 -3.25 -0.44 -0.148 0.75795E+03 201 montmorillonite-Ca -2.29 -5.64 -3.34 -0.207 0.57111E+04 202 montmorillonite-K -2.24 -5.75 -3.51 -0.215 0.59998E+04 203 montmorillonite-Mg -2.48 -6.19 -3.71 -0.230 0.63420E+04 204 montmorillonite-Na -2.04 -5.06 -3.02 -0.185 0.51547E+04 205 nontronite-Ca 3.21 1.99 -1.22 -0.079 0.20909E+04 206 nontronite-H 2.53 -0.06 -2.59 -0.174 0.44291E+04 207 nontronite-K 3.34 1.87 -1.47 -0.094 0.25027E+04 208 nontronite-Mg 3.07 1.43 -1.64 -0.107 0.28058E+04 209 nontronite-Na 3.52 2.57 -0.95 -0.061 0.16236E+04 224 tobermorite 9.82 7.11 -2.71 -0.740 0.46334E+04 233 boehmite 4.41 1.39 -3.02 -0.504 0.51585E+04 235 ferrous-oxide 9.81 6.66 -3.15 -0.789 0.53868E+04 240 silica-amorphous -2.09 -3.25 -1.16 -0.385 0.19721E+04 242 an20ab80 2.02 1.43 -0.58 -0.045 0.99536E+03 243 an25ab75 2.65 1.89 -0.76 -0.058 0.12912E+04 244 an30ab70 3.28 2.34 -0.94 -0.072 0.15966E+04 245 tr.625ac.25prg.125 45.16 42.33 -2.83 -0.076 0.48327E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 2.0000000 g Current total amount of reactant added: 41.9990000 g New total amount of reactant added: 43.9990000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.1498E-12 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 9 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 43.9990000 Water: Moles liquid = 0.5521E+02 kg liquid = 0.9946E+00 Moles total = 0.5496E+02 kg total = 0.9901E+00 Activity = 1.0000 Stoichiometric ionic strength = .6807964E-02 Osmotic coef. = 0.9572 True ionic strength = .1236737E-01 Chg. balance for total moles = -.1498E-12 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.12348E-09 -9.9084 0.10670E-09 -9.9718 0.86406E+00 -0.0635 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13830E-03 -3.8592 0.11901E-03 -3.9244 0.86053E+00 -0.0652 4 SO4-- 0.25234E-04 -4.5980 0.14719E-04 -4.8321 0.58330E+00 -0.2341 5 HCO3- 0.59428E-05 -5.2260 0.51190E-05 -5.2908 0.86138E+00 -0.0648 6 HS- 0.38586E-06 -6.4136 0.33208E-06 -6.4788 0.86061E+00 -0.0652 7 Al+++ 0.90520E-28 -28.0433 0.27279E-28 -28.5642 0.30136E+00 -0.5209 8 H4SiO4 0.57125E-03 -3.2432 0.57125E-03 -3.2432 0.10000E+01 0.0000 9 Ca++ 0.58880E-07 -7.2300 0.34175E-07 -7.4663 0.58042E+00 -0.2363 10 Mg++ 0.22607E-10 -10.6458 0.13081E-10 -10.8834 0.57862E+00 -0.2376 11 Fe++ 0.90436E-13 -13.0437 0.52367E-13 -13.2809 0.57905E+00 -0.2373 12 K+ 0.96501E-04 -4.0155 0.83138E-04 -4.0802 0.86152E+00 -0.0647 13 Na+ 0.12238E-01 -1.9123 0.10530E-01 -1.9776 0.86043E+00 -0.0653 14 Mn++ 0.17900E-10 -10.7471 0.10371E-10 -10.9842 0.57937E+00 -0.2370 15 HPO4-- 0.21425E-06 -6.6691 0.12498E-06 -6.9031 0.58336E+00 -0.2341 16 HSiO3- 0.58095E-02 -2.2359 0.49992E-02 -2.3011 0.86053E+00 -0.0652 17 Ca(HSiO3)+ 0.45156E-08 -8.3453 0.38909E-08 -8.4100 0.86165E+00 -0.0647 18 Mg(HSiO3)+ 0.21510E-11 -11.6674 0.18534E-11 -11.7320 0.86165E+00 -0.0647 19 NaHSiO3,aq 0.85141E-03 -3.0699 0.85141E-03 -3.0699 0.10000E+01 0.0000 20 AlO+ 0.37833E-15 -15.4221 0.32599E-15 -15.4868 0.86165E+00 -0.0647 22 HAlO2,aq 0.60845E-09 -9.2158 0.60845E-09 -9.2158 0.10000E+01 0.0000 23 AlO2- 0.14687E-04 -4.8331 0.12623E-04 -4.8988 0.85947E+00 -0.0658 24 CH4,aq 0.11242E-12 -12.9492 0.11219E-12 -12.9501 0.99791E+00 -0.0009 29 CO,aq 0.13471E-17 -17.8706 0.13471E-17 -17.8706 0.10000E+01 0.0000 30 CO2,aq 0.11695E-08 -8.9320 0.11671E-08 -8.9329 0.99791E+00 -0.0009 31 CO3-2 0.71947E-05 -5.1430 0.41907E-05 -5.3777 0.58246E+00 -0.2347 32 CaCO3,aq 0.17958E-08 -8.7457 0.17958E-08 -8.7457 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.51827E-11 -11.2854 0.44656E-11 -11.3501 0.86165E+00 -0.0647 34 CaCl+ 0.76391E-11 -11.1170 0.65822E-11 -11.1816 0.86165E+00 -0.0647 35 CaCl2,aq 0.18611E-15 -15.7302 0.18611E-15 -15.7302 0.10000E+01 0.0000 36 CaOH+ 0.26493E-07 -7.5769 0.22828E-07 -7.6415 0.86165E+00 -0.0647 37 CaSO4,aq 0.15973E-09 -9.7966 0.15973E-09 -9.7966 0.10000E+01 0.0000 38 HCl,aq 0.23269E-14 -14.6332 0.23269E-14 -14.6332 0.10000E+01 0.0000 43 FeCl+ 0.11449E-16 -16.9412 0.98648E-17 -17.0059 0.86165E+00 -0.0647 46 FeO,aq 0.17878E-09 -9.7477 0.17878E-09 -9.7477 0.10000E+01 0.0000 47 FeOH+ 0.18541E-10 -10.7319 0.15976E-10 -10.7965 0.86165E+00 -0.0647 48 HFeO2- 0.20374E-07 -7.6909 0.17532E-07 -7.7562 0.86053E+00 -0.0652 49 FeO+ 0.20631E-15 -15.6855 0.17777E-15 -15.7501 0.86165E+00 -0.0647 51 FeO2- 0.37131E-08 -8.4303 0.31952E-08 -8.4955 0.86053E+00 -0.0652 52 HFeO2,aq 0.43360E-10 -10.3629 0.43360E-10 -10.3629 0.10000E+01 0.0000 53 H2,aq 0.46046E-07 -7.3368 0.45950E-07 -7.3377 0.99791E+00 -0.0009 54 KCl,aq 0.17933E-09 -9.7463 0.17933E-09 -9.7463 0.10000E+01 0.0000 55 KHSO4,aq 0.36916E-18 -18.4328 0.36916E-18 -18.4328 0.10000E+01 0.0000 56 KOH,aq 0.33276E-06 -6.4779 0.33276E-06 -6.4779 0.10000E+01 0.0000 57 KSO4- 0.22067E-07 -7.6563 0.18989E-07 -7.7215 0.86053E+00 -0.0652 58 MgCO3,aq 0.17229E-12 -12.7638 0.17229E-12 -12.7638 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.20269E-14 -14.6932 0.17465E-14 -14.7578 0.86165E+00 -0.0647 60 MgCl+ 0.26500E-14 -14.5767 0.22834E-14 -14.6414 0.86165E+00 -0.0647 61 MgOH+ 0.56111E-10 -10.2509 0.48348E-10 -10.3156 0.86165E+00 -0.0647 63 MnO,aq 0.94344E-09 -9.0253 0.94344E-09 -9.0253 0.10000E+01 0.0000 64 MnOH+ 0.34112E-09 -9.4671 0.29393E-09 -9.5318 0.86165E+00 -0.0647 65 MnO2-2 0.47219E-11 -11.3259 0.27503E-11 -11.5606 0.58246E+00 -0.2347 66 HMnO2- 0.74711E-10 -10.1266 0.64291E-10 -10.1919 0.86053E+00 -0.0652 69 MnCl+ 0.88212E-14 -14.0545 0.76007E-14 -14.1191 0.86165E+00 -0.0647 70 MnSO4,aq 0.44069E-13 -13.3559 0.44069E-13 -13.3559 0.10000E+01 0.0000 71 NaCl,aq 0.41532E-06 -6.3816 0.41532E-06 -6.3816 0.10000E+01 0.0000 72 NaOH,aq 0.42402E-04 -4.3726 0.42402E-04 -4.3726 0.10000E+01 0.0000 74 OH- 0.63005E-02 -2.2006 0.54151E-02 -2.2664 0.85947E+00 -0.0658 79 HPO3-2 0.30727E-16 -16.5125 0.17897E-16 -16.7472 0.58246E+00 -0.2347 82 H3PO4,aq 0.99512E-17 -17.0021 0.99512E-17 -17.0021 0.10000E+01 0.0000 83 H2PO4- 0.28569E-09 -9.5441 0.24600E-09 -9.6091 0.86108E+00 -0.0650 84 PO4-3 0.30677E-08 -8.5132 0.95573E-09 -9.0197 0.31155E+00 -0.5065 88 HP2O7-3 0.29450E-16 -16.5309 0.88802E-17 -17.0516 0.30153E+00 -0.5207 89 P2O7-4 0.16230E-15 -15.7897 0.19883E-16 -16.7015 0.12251E+00 -0.9118 90 H2S,aq 0.10973E-09 -9.9597 0.10951E-09 -9.9606 0.99791E+00 -0.0009 91 S2-2 0.91297E-16 -16.0395 0.53177E-16 -16.2743 0.58246E+00 -0.2347 97 SO3-2 0.14943E-12 -12.8256 0.87890E-13 -13.0561 0.58817E+00 -0.2305 98 HSO3- 0.68231E-15 -15.1660 0.58715E-15 -15.2313 0.86053E+00 -0.0652 99 HSO4- 0.17554E-11 -11.7556 0.15135E-11 -11.8200 0.86221E+00 -0.0644 101 S2O3-2 0.32506E-16 -16.4880 0.18934E-16 -16.7228 0.58246E+00 -0.2347 Charge balance for all species = -.1496E-12 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.1234834E-09 -.1307021E-01 -.1316097E+02 0.0000 2 H2O 0.1000000E+01 0.5550796E+02 0.9990048E+06 0.0000 3 Cl- 0.1383031E-03 0.1387186E-03 0.4913133E+01 6.0474 4 SO4-- 0.2523388E-04 0.2524506E-04 0.2422686E+01 15.1116 5 HCO3- 0.5942842E-05 0.1314052E-04 0.8010056E+00 4.6810 6 HS- 0.3858604E-06 0.3970123E-06 0.1311702E-01 3.4931 7 Al+++ 0.9052014E-28 0.1468793E-04 0.3959110E+00 1.3514 8 H4SiO4 0.5712503E-03 0.7232141E-02 0.6944334E+03 -3.2432 9 Ca++ 0.5888020E-07 0.9185730E-07 0.3677820E-02 12.4774 10 Mg++ 0.2260655E-10 0.8104586E-10 0.1968440E-05 9.0603 11 Fe++ 0.9043586E-13 0.2432739E-07 0.1357270E-02 6.6628 12 K+ 0.9650113E-04 0.9685614E-04 0.3783528E+01 5.8916 13 Na+ 0.1223801E-01 0.1313223E-01 0.3016092E+03 7.9943 14 Mn++ 0.1790049E-10 0.1381951E-08 0.7584663E-04 8.9595 15 HPO4-- 0.2142478E-06 0.2176012E-06 0.2086452E-01 13.0406 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.7285451E+00 -.1300007E-01 -.7155450E+00 0.0000000E+00 2 H2O 0.5495670E+02 0.5521008E+02 -.2533765E+00 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.1244867E-02 0.2510959E-04 0.1219757E-02 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.1219362E-02 0.3948818E-06 -.1219757E-02 0.0000000E+00 7 Al+++ 0.1434694E+00 0.1460911E-04 0.1434548E+00 0.0000000E+00 8 H4SiO4 0.4581520E+00 0.7193330E-02 0.4509587E+00 0.0000000E+00 9 Ca++ 0.5061960E-01 0.9136435E-07 0.5061951E-01 0.0000000E+00 10 Mg++ 0.3491984E-01 0.8061093E-10 0.3491984E-01 0.0000000E+00 11 Fe++ 0.3137167E-01 0.2419684E-07 0.3137164E-01 0.0000000E+00 12 K+ 0.9341614E-02 0.9633636E-04 0.9245277E-02 0.0000000E+00 13 Na+ 0.5538954E-01 0.1306176E-01 0.4232778E-01 0.0000000E+00 14 Mn++ 0.7628809E-03 0.1374535E-08 0.7628795E-03 0.0000000E+00 15 HPO4-- 0.2603675E-03 0.2164335E-06 0.2601510E-03 0.0000000E+00 Chg. balance for solid moles: 0.2786E-15 Mass of aqueous solution: 0.995617E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 43.9990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 0.4233E-01 -1.373 11.10 1.045 23.11 4.261 andradite 0.4879E-02 -2.312 2.479 0.394 5.162 0.6442 grossular 0.3600E-03 -3.444 0.1621 -0.790 0.3376 0.4512E-01 apatite-OH 0.8672E-04 -4.062 0.4356E-01 -1.361 0.9068E-01 0.1384E-01 clinochlore 0.6984E-02 -2.156 3.882 0.589 8.081 1.477 daphnite 0.2933E-02 -2.533 2.093 0.321 4.357 0.6343 chlorite-Mn 0.1526E-03 -3.817 0.1082 -0.966 0.2252 0.3447E-01 microcline 0.8551E-02 -2.068 2.380 0.377 4.955 0.9297 stilbite 0.3447E-01 -1.463 24.29 1.385 50.57 11.33 stilpnomelane-Fe 0.1389E-02 -2.857 1.498 0.175 3.118 0.5173 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.9313E+00 0.9313E+00 1.0000 -0.031 grossular 0.6871E-01 0.6871E-01 1.0000 -1.163 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.6935E+00 0.6935E+00 1.0000 -0.159 daphnite 0.2913E+00 0.2913E+00 1.0000 -0.536 chlorite-Mn 0.1515E-01 0.1515E-01 1.0000 -1.820 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 48.035969 g Volume = 19.885872 cm3 Porosity: -6.9156% V(tot) - V(min): -.12863E+01 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 43.9990000 g log = 1.6434 Original solution: 1000.0103000 g Original solution / Rock added: 22.73 (Water/Rock Ratio), log = 1.3566 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0204 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9999E+00 0.9860 0.1006E+01 0.1020E+01 CO2,gas 0.1215E-06 1.0071 0.1249E-06 0.1240E-06 CH4,gas 0.1598E-09 1.0125 0.1651E-09 0.1631E-09 H2,gas 0.5909E-04 1.0005 0.6033E-04 0.6029E-04 H2S,gas 0.2962E-08 0.9960 0.3010E-08 0.3022E-08 S2,gas 0.9160E-28 1.0000 0.9346E-28 0.9346E-28 CO,gas 0.1967E-14 1.0000 0.2008E-14 0.2008E-14 SO3,gas 0.6209E-40 1.0000 0.6336E-40 0.6336E-40 SO2,gas 0.1457E-21 1.0000 0.1487E-21 0.1487E-21 HCl,gas 0.4024E-17 1.0000 0.4106E-17 0.4106E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 16 albite -0.38 -0.38 0.00 0.000 -0.94784E-12 22 andradite 39.01 39.01 0.00 0.000 0.12132E-10 23 grossular 32.73 32.73 0.00 0.000 0.00000E+00 32 apatite-OH -18.15 -18.15 0.00 0.000 -0.12132E-10 46 clinochlore 39.07 39.07 0.00 0.000 0.24265E-10 47 daphnite 28.97 28.97 0.00 0.000 0.18198E-10 48 chlorite-Mn 46.87 46.87 0.00 0.000 0.24265E-10 116 microcline -2.49 -2.49 0.00 0.000 -0.10616E-10 163 stilbite -7.52 -7.52 0.00 0.000 -0.90992E-11 164 stilpnomelane-Fe 13.02 13.02 0.00 0.000 0.21232E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -15.26 -8.60 -2.868 0.14689E+05 -6.904 3 CH4,gas 4.54 -6.94 -11.48 -2.870 0.19604E+05 -9.782 4 H2,gas 8.00 2.08 -5.92 -3.382 0.10106E+05 -4.219 5 H2S,gas -6.23 -16.45 -10.22 -5.110 0.17451E+05 -8.521 6 S2,gas -7.34 -37.06 -29.73 -4.574 0.50760E+05 -28.029 7 CO,gas 3.21 -13.18 -16.40 -5.045 0.27996E+05 -14.697 8 SO3,gas 17.12 -24.78 -41.90 -10.474 0.71538E+05 -40.198 9 SO2,gas 0.83 -22.69 -23.53 -6.274 0.40171E+05 -21.828 10 HCl,gas 5.19 -13.90 -19.09 -9.543 0.32588E+05 -17.387 11 acmite 7.71 7.13 -0.58 -0.060 0.98978E+03 15 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 19 spessartine 24.46 19.85 -4.61 -0.230 0.78638E+04 20 analcite 3.32 2.86 -0.46 -0.051 0.78980E+03 26 annite 20.12 17.50 -2.62 -0.146 0.44763E+04 27 phlogopite 27.06 24.69 -2.37 -0.132 0.40469E+04 29 anorthite 12.71 8.69 -4.02 -0.309 0.68581E+04 35 aragonite 0.97 -2.79 -3.75 -1.251 0.64060E+04 36 brucite 12.57 9.06 -3.51 -0.702 0.59902E+04 37 calcite 0.81 -2.79 -3.60 -1.199 0.61418E+04 38 carnegieite-low 9.02 6.10 -2.92 -0.417 0.49872E+04 39 carnegieite-high 10.09 6.10 -3.99 -0.570 0.68142E+04 40 carpholite-Mg 8.58 5.28 -3.31 -0.220 0.56438E+04 41 carpholite-Fe 6.71 2.88 -3.83 -0.256 0.65456E+04 42 celadonite 5.34 3.33 -2.01 -0.118 0.34336E+04 43 celadonite-Fe 3.88 0.93 -2.94 -0.173 0.50258E+04 44 chrysotile 23.89 20.69 -3.20 -0.266 0.54601E+04 50 chloritoid-Mg 13.20 8.52 -4.68 -0.312 0.79872E+04 51 chloritoid-Fe 9.17 6.12 -3.05 -0.203 0.52100E+04 52 chloritoid-Mn 11.40 8.42 -2.98 -0.199 0.50916E+04 54 coesite -2.38 -3.24 -0.87 -0.289 0.14806E+04 61 cristobalite -2.56 -3.24 -0.68 -0.228 0.11659E+04 63 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71234E+04 65 diaspore 2.87 1.35 -1.52 -0.254 0.25993E+04 67 diopside 16.18 15.05 -1.13 -0.113 0.19294E+04 68 hedenbergite 14.21 12.65 -1.55 -0.155 0.26542E+04 75 epidote 24.67 23.55 -1.12 -0.054 0.19120E+04 76 clinozoisite 22.81 19.28 -3.53 -0.160 0.60216E+04 77 epidote-Fe 29.84 27.82 -2.02 -0.105 0.34490E+04 78 fayalite 14.05 10.08 -3.96 -0.566 0.67674E+04 79 ferrosilite 11.15 6.84 -4.31 -0.431 0.73597E+04 83 gibbsite 4.08 1.35 -2.73 -0.390 0.46579E+04 84 glaucophane 22.97 19.93 -3.05 -0.082 0.52042E+04 85 glaucophane-Fe 17.28 12.73 -4.54 -0.123 0.77547E+04 87 greenalite 16.14 13.50 -2.64 -0.220 0.45036E+04 90 hematite 12.57 11.24 -1.32 -0.160 0.22572E+04 91 heulandite -5.83 -7.52 -1.69 -0.077 0.28938E+04 95 jadeite 4.22 2.86 -1.36 -0.136 0.23153E+04 96 julgoldite 70.43 66.26 -4.16 -0.108 0.71072E+04 97 kalsilite 7.58 4.00 -3.58 -0.512 0.61197E+04 98 kaolinite -1.33 -3.78 -2.45 -0.223 0.41847E+04 101 laumontite 2.88 2.21 -0.68 -0.045 0.11542E+04 102 lawsonite 9.62 8.69 -0.92 -0.061 0.15747E+04 103 leucite 4.12 0.76 -3.36 -0.336 0.57408E+04 105 lizardite 23.24 20.69 -2.55 -0.212 0.43527E+04 107 magnetite 20.09 17.91 -2.18 -0.178 0.37230E+04 108 minnesotaite 10.39 7.02 -3.37 -0.198 0.57585E+04 120 muscovite 2.58 0.22 -2.37 -0.139 0.40402E+04 121 paragonite 4.24 2.32 -1.92 -0.113 0.32793E+04 122 nepheline 8.34 6.10 -2.24 -0.320 0.38196E+04 128 periclase-Fe 11.63 6.66 -4.96 -1.241 0.84756E+04 134 phlogopite-Na 29.65 26.80 -2.85 -0.158 0.48657E+04 136 prehnite 19.37 17.93 -1.44 -0.085 0.24653E+04 137 prehnite-Fe 22.50 22.20 -0.30 -0.018 0.51067E+03 138 pumpellyite-Fe 46.27 43.87 -2.40 -0.053 0.40965E+04 139 pumpellyite-Mg 48.99 46.27 -2.73 -0.061 0.46564E+04 144 pyrrhotiteFe0.875 -6.02 -10.88 -4.86 -1.788 0.83014E+04 145 pyroxmangite 7.40 5.72 -1.68 -0.336 0.28725E+04 146 pyrophyllite -6.18 -10.27 -4.09 -0.256 0.69906E+04 147 quartz -2.99 -3.24 -0.25 -0.085 0.43325E+03 152 rhodonite 7.45 5.72 -1.73 -0.346 0.29528E+04 153 sanidine -1.28 -2.49 -1.21 -0.093 0.20677E+04 165 stilpnomelane-Mg 27.44 25.00 -2.44 -0.073 0.41604E+04 171 talc 16.49 14.21 -2.28 -0.134 0.38978E+04 174 tephroite 18.09 14.68 -3.41 -0.487 0.58223E+04 178 tridymite -2.63 -3.24 -0.62 -0.206 0.10532E+04 179 tremolite 47.87 44.31 -3.56 -0.096 0.60755E+04 187 wairakite 3.95 2.21 -1.74 -0.103 0.29761E+04 188 walstromite 11.51 9.23 -2.27 -0.455 0.38845E+04 189 wollastonite 10.46 9.23 -1.23 -0.245 0.20949E+04 190 pseudo-wollastonite 11.00 9.23 -1.77 -0.353 0.30147E+04 191 zoisite 22.85 19.28 -3.57 -0.162 0.60956E+04 192 akaganeite 7.75 5.62 -2.13 -0.461 0.36411E+04 197 beidellite-Na -1.34 -6.12 -4.77 -0.292 0.81504E+04 199 chalcedony -2.80 -3.24 -0.44 -0.147 0.75255E+03 201 montmorillonite-Ca -2.29 -5.67 -3.38 -0.209 0.57653E+04 202 montmorillonite-K -2.24 -5.78 -3.55 -0.217 0.60530E+04 203 montmorillonite-Mg -2.48 -6.23 -3.75 -0.232 0.64050E+04 204 montmorillonite-Na -2.04 -5.09 -3.05 -0.187 0.52079E+04 205 nontronite-Ca 3.21 1.85 -1.37 -0.089 0.23359E+04 206 nontronite-H 2.53 -0.21 -2.74 -0.184 0.46870E+04 207 nontronite-K 3.34 1.73 -1.61 -0.103 0.27469E+04 208 nontronite-Mg 3.07 1.28 -1.79 -0.116 0.30597E+04 209 nontronite-Na 3.52 2.43 -1.09 -0.070 0.18678E+04 224 tobermorite 9.82 7.15 -2.67 -0.729 0.45633E+04 233 boehmite 4.41 1.35 -3.05 -0.509 0.52162E+04 235 ferrous-oxide 9.81 6.66 -3.15 -0.787 0.53765E+04 240 silica-amorphous -2.09 -3.24 -1.15 -0.384 0.19667E+04 242 an20ab80 2.02 1.43 -0.59 -0.045 0.10008E+04 243 an25ab75 2.65 1.89 -0.76 -0.058 0.12979E+04 244 an30ab70 3.28 2.34 -0.94 -0.072 0.16047E+04 245 tr.625ac.25prg.125 45.16 42.50 -2.67 -0.072 0.45527E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 2.0000000 g Current total amount of reactant added: 43.9990000 g New total amount of reactant added: 45.9990000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.1497E-12 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 9 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 45.9990000 Water: Moles liquid = 0.5520E+02 kg liquid = 0.9944E+00 Moles total = 0.5493E+02 kg total = 0.9896E+00 Activity = 1.0000 Stoichiometric ionic strength = .7007403E-02 Osmotic coef. = 0.9570 True ionic strength = .1272137E-01 Chg. balance for total moles = -.1497E-12 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.12079E-09 -9.9180 0.10421E-09 -9.9821 0.86274E+00 -0.0641 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13832E-03 -3.8591 0.11884E-03 -3.9250 0.85914E+00 -0.0659 4 SO4-- 0.24234E-04 -4.6156 0.14047E-04 -4.8524 0.57964E+00 -0.2368 5 HCO3- 0.58521E-05 -5.2327 0.50328E-05 -5.2982 0.86001E+00 -0.0655 6 HS- 0.13915E-05 -5.8565 0.11956E-05 -5.9224 0.85923E+00 -0.0659 7 Al+++ 0.79454E-28 -28.0999 0.23602E-28 -28.6270 0.29705E+00 -0.5272 8 H4SiO4 0.57577E-03 -3.2398 0.57577E-03 -3.2398 0.10000E+01 0.0000 9 Ca++ 0.62025E-07 -7.2074 0.35770E-07 -7.4465 0.57671E+00 -0.2390 10 Mg++ 0.22368E-10 -10.6504 0.12859E-10 -10.8908 0.57488E+00 -0.2404 11 Fe++ 0.87871E-13 -13.0562 0.50553E-13 -13.2963 0.57531E+00 -0.2401 12 K+ 0.99275E-04 -4.0032 0.85392E-04 -4.0686 0.86016E+00 -0.0654 13 Na+ 0.12590E-01 -1.9000 0.10815E-01 -1.9660 0.85904E+00 -0.0660 14 Mn++ 0.17711E-10 -10.7517 0.10196E-10 -10.9916 0.57564E+00 -0.2398 15 HPO4-- 0.19363E-06 -6.7130 0.11224E-06 -6.9498 0.57970E+00 -0.2368 16 HSiO3- 0.60049E-02 -2.2215 0.51591E-02 -2.2874 0.85914E+00 -0.0659 17 Ca(HSiO3)+ 0.48853E-08 -8.3111 0.42027E-08 -8.3765 0.86028E+00 -0.0654 18 Mg(HSiO3)+ 0.21856E-11 -11.6604 0.18803E-11 -11.7258 0.86028E+00 -0.0654 19 NaHSiO3,aq 0.90245E-03 -3.0446 0.90245E-03 -3.0446 0.10000E+01 0.0000 20 AlO+ 0.34370E-15 -15.4638 0.29568E-15 -15.5292 0.86028E+00 -0.0654 22 HAlO2,aq 0.56507E-09 -9.2479 0.56507E-09 -9.2479 0.10000E+01 0.0000 23 AlO2- 0.13989E-04 -4.8542 0.12003E-04 -4.9207 0.85806E+00 -0.0665 24 CH4,aq 0.41701E-12 -12.3799 0.41611E-12 -12.3808 0.99785E+00 -0.0009 29 CO,aq 0.18135E-17 -17.7415 0.18135E-17 -17.7415 0.10000E+01 0.0000 30 CO2,aq 0.11231E-08 -8.9496 0.11207E-08 -8.9505 0.99785E+00 -0.0009 31 CO3-2 0.72884E-05 -5.1374 0.42185E-05 -5.3748 0.57879E+00 -0.2375 32 CaCO3,aq 0.18921E-08 -8.7231 0.18921E-08 -8.7231 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.53417E-11 -11.2723 0.45954E-11 -11.3377 0.86028E+00 -0.0654 34 CaCl+ 0.79966E-11 -11.0971 0.68794E-11 -11.1625 0.86028E+00 -0.0654 35 CaCl2,aq 0.19423E-15 -15.7117 0.19423E-15 -15.7117 0.10000E+01 0.0000 36 CaOH+ 0.28437E-07 -7.5461 0.24464E-07 -7.6115 0.86028E+00 -0.0654 37 CaSO4,aq 0.15956E-09 -9.7971 0.15956E-09 -9.7971 0.10000E+01 0.0000 38 HCl,aq 0.22693E-14 -14.6441 0.22693E-14 -14.6441 0.10000E+01 0.0000 43 FeCl+ 0.11054E-16 -16.9565 0.95093E-17 -17.0219 0.86028E+00 -0.0654 46 FeO,aq 0.18093E-09 -9.7425 0.18093E-09 -9.7425 0.10000E+01 0.0000 47 FeOH+ 0.18356E-10 -10.7362 0.15791E-10 -10.8016 0.86028E+00 -0.0654 48 HFeO2- 0.21145E-07 -7.6748 0.18167E-07 -7.7407 0.85914E+00 -0.0659 49 FeO+ 0.17250E-15 -15.7632 0.14840E-15 -15.8286 0.86028E+00 -0.0654 51 FeO2- 0.32547E-08 -8.4875 0.27963E-08 -8.5534 0.85914E+00 -0.0659 52 HFeO2,aq 0.37061E-10 -10.4311 0.37061E-10 -10.4311 0.10000E+01 0.0000 53 H2,aq 0.64557E-07 -7.1901 0.64418E-07 -7.1910 0.99785E+00 -0.0009 54 KCl,aq 0.18392E-09 -9.7354 0.18392E-09 -9.7354 0.10000E+01 0.0000 55 KHSO4,aq 0.35342E-18 -18.4517 0.35342E-18 -18.4517 0.10000E+01 0.0000 56 KOH,aq 0.34995E-06 -6.4560 0.34995E-06 -6.4560 0.10000E+01 0.0000 57 KSO4- 0.21665E-07 -7.6642 0.18614E-07 -7.7302 0.85914E+00 -0.0659 58 MgCO3,aq 0.17049E-12 -12.7683 0.17049E-12 -12.7683 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.19622E-14 -14.7073 0.16880E-14 -14.7726 0.86028E+00 -0.0654 60 MgCl+ 0.26055E-14 -14.5841 0.22415E-14 -14.6495 0.86028E+00 -0.0654 61 MgOH+ 0.56568E-10 -10.2474 0.48665E-10 -10.3128 0.86028E+00 -0.0654 63 MnO,aq 0.97230E-09 -9.0122 0.97230E-09 -9.0122 0.10000E+01 0.0000 64 MnOH+ 0.34390E-09 -9.4636 0.29585E-09 -9.5289 0.86028E+00 -0.0654 65 MnO2-2 0.51339E-11 -11.2896 0.29714E-11 -11.5270 0.57879E+00 -0.2375 66 HMnO2- 0.78962E-10 -10.1026 0.67839E-10 -10.1685 0.85914E+00 -0.0659 69 MnCl+ 0.86729E-14 -14.0618 0.74612E-14 -14.1272 0.86028E+00 -0.0654 70 MnSO4,aq 0.41346E-13 -13.3836 0.41346E-13 -13.3836 0.10000E+01 0.0000 71 NaCl,aq 0.42595E-06 -6.3706 0.42595E-06 -6.3706 0.10000E+01 0.0000 72 NaOH,aq 0.44592E-04 -4.3507 0.44592E-04 -4.3507 0.10000E+01 0.0000 74 OH- 0.64616E-02 -2.1897 0.55444E-02 -2.2561 0.85806E+00 -0.0665 79 HPO3-2 0.38932E-16 -16.4097 0.22533E-16 -16.6472 0.57879E+00 -0.2375 82 H3PO4,aq 0.85250E-17 -17.0693 0.85250E-17 -17.0693 0.10000E+01 0.0000 83 H2PO4- 0.25099E-09 -9.6003 0.21577E-09 -9.6660 0.85970E+00 -0.0657 84 PO4-3 0.28594E-08 -8.5437 0.87882E-09 -9.0561 0.30734E+00 -0.5124 88 HP2O7-3 0.23534E-16 -16.6283 0.69952E-17 -17.1552 0.29723E+00 -0.5269 89 P2O7-4 0.13423E-15 -15.8722 0.16036E-16 -16.7949 0.11947E+00 -0.9227 90 H2S,aq 0.38591E-09 -9.4135 0.38508E-09 -9.4145 0.99785E+00 -0.0009 91 S2-2 0.84957E-15 -15.0708 0.49172E-15 -15.3083 0.57879E+00 -0.2375 97 SO3-2 0.20115E-12 -12.6965 0.11759E-12 -12.9296 0.58460E+00 -0.2331 98 HSO3- 0.89305E-15 -15.0491 0.76725E-15 -15.1151 0.85914E+00 -0.0659 99 HSO4- 0.16387E-11 -11.7855 0.14107E-11 -11.8506 0.86086E+00 -0.0651 101 S2O3-2 0.10978E-15 -15.9595 0.63542E-16 -16.1969 0.57879E+00 -0.2375 Charge balance for all species = -.1472E-12 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.1207870E-09 -.1347730E-01 -.1357047E+02 0.0000 2 H2O 0.1000000E+01 0.5550788E+02 0.9989718E+06 0.0000 3 Cl- 0.1383245E-03 0.1387506E-03 0.4914112E+01 6.0571 4 SO4-- 0.2423425E-04 0.2424035E-04 0.2326194E+01 15.1118 5 HCO3- 0.5852083E-05 0.1314355E-04 0.8011652E+00 4.6839 6 HS- 0.1391530E-05 0.1407644E-05 0.4650615E-01 4.0597 7 Al+++ 0.7945398E-28 0.1398934E-04 0.3770686E+00 1.3192 8 H4SiO4 0.5757671E-03 0.7483162E-02 0.7185140E+03 -3.2398 9 Ca++ 0.6202513E-07 0.9741239E-07 0.3900114E-02 12.5177 10 Mg++ 0.2236849E-10 0.8129750E-10 0.1974490E-05 9.0734 11 Fe++ 0.8787078E-13 0.2463622E-07 0.1374457E-02 6.6679 12 K+ 0.9927489E-04 0.9964668E-04 0.3892413E+01 5.9135 13 Na+ 0.1259015E-01 0.1353762E-01 0.3109099E+03 8.0161 14 Mn++ 0.1771144E-10 0.1418052E-08 0.7782553E-04 8.9726 15 HPO4-- 0.1936259E-06 0.1967363E-06 0.1886330E-01 13.0144 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.7616621E+00 -.1340188E-01 -.7482602E+00 0.0000000E+00 2 H2O 0.5493163E+02 0.5519725E+02 -.2656206E+00 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.1300294E-02 0.2410470E-04 0.1276189E-02 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.1274789E-02 0.1399767E-05 -.1276189E-02 0.0000000E+00 7 Al+++ 0.1499909E+00 0.1391105E-04 0.1499769E+00 0.0000000E+00 8 H4SiO4 0.4789776E+00 0.7441286E-02 0.4715363E+00 0.0000000E+00 9 Ca++ 0.5291988E-01 0.9686727E-07 0.5291979E-01 0.0000000E+00 10 Mg++ 0.3650714E-01 0.8084256E-10 0.3650714E-01 0.0000000E+00 11 Fe++ 0.3279768E-01 0.2449836E-07 0.3279766E-01 0.0000000E+00 12 K+ 0.9766242E-02 0.9908906E-04 0.9667153E-02 0.0000000E+00 13 Na+ 0.5790002E-01 0.1346186E-01 0.4443816E-01 0.0000000E+00 14 Mn++ 0.7975581E-03 0.1410117E-08 0.7975567E-03 0.0000000E+00 15 HPO4-- 0.2722026E-03 0.1956353E-06 0.2720070E-03 0.0000000E+00 Chg. balance for solid moles: -.1237E-15 Mass of aqueous solution: 0.995419E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 45.9990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 0.4444E-01 -1.352 11.65 1.066 23.20 4.473 andradite 0.5105E-02 -2.292 2.594 0.414 5.166 0.6740 grossular 0.4092E-03 -3.388 0.1843 -0.734 0.3671 0.5129E-01 apatite-OH 0.9067E-04 -4.043 0.4554E-01 -1.342 0.9069E-01 0.1447E-01 clinochlore 0.7301E-02 -2.137 4.058 0.608 8.081 1.544 daphnite 0.3012E-02 -2.521 2.149 0.332 4.279 0.6512 chlorite-Mn 0.1595E-03 -3.797 0.1131 -0.947 0.2252 0.3604E-01 microcline 0.8914E-02 -2.050 2.481 0.395 4.941 0.9692 stilbite 0.3592E-01 -1.445 25.32 1.403 50.41 11.81 stilpnomelane-Fe 0.1506E-02 -2.822 1.623 0.210 3.233 0.5608 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.9258E+00 0.9258E+00 1.0000 -0.033 grossular 0.7421E-01 0.7421E-01 1.0000 -1.130 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.6972E+00 0.6972E+00 1.0000 -0.157 daphnite 0.2876E+00 0.2876E+00 1.0000 -0.541 chlorite-Mn 0.1523E-01 0.1523E-01 1.0000 -1.817 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 50.218206 g Volume = 20.781942 cm3 Porosity: -7.1256% V(tot) - V(min): -.13823E+01 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 45.9990000 g log = 1.6627 Original solution: 1000.0103000 g Original solution / Rock added: 21.74 (Water/Rock Ratio), log = 1.3373 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0204 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9999E+00 0.9860 0.1006E+01 0.1020E+01 CO2,gas 0.1167E-06 1.0071 0.1199E-06 0.1191E-06 CH4,gas 0.5928E-09 1.0125 0.6125E-09 0.6049E-09 H2,gas 0.8284E-04 1.0005 0.8457E-04 0.8453E-04 H2S,gas 0.1042E-07 0.9960 0.1059E-07 0.1063E-07 S2,gas 0.5763E-27 1.0000 0.5880E-27 0.5880E-27 CO,gas 0.2648E-14 1.0000 0.2702E-14 0.2702E-14 SO3,gas 0.5653E-40 1.0000 0.5768E-40 0.5768E-40 SO2,gas 0.1860E-21 1.0000 0.1898E-21 0.1898E-21 HCl,gas 0.3924E-17 1.0000 0.4004E-17 0.4004E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 16 albite -0.38 -0.38 0.00 0.000 -0.94784E-12 22 andradite 39.01 39.01 0.00 0.000 0.00000E+00 23 grossular 32.73 32.73 0.00 0.000 -0.12132E-10 32 apatite-OH -18.15 -18.15 0.00 0.000 -0.12132E-10 46 clinochlore 39.07 39.07 0.00 0.000 0.12132E-10 47 daphnite 28.97 28.97 0.00 0.000 -0.48529E-10 48 chlorite-Mn 46.87 46.87 0.00 0.000 0.00000E+00 116 microcline -2.49 -2.49 0.00 0.000 0.15165E-11 163 stilbite -7.52 -7.52 0.00 0.000 -0.90992E-11 164 stilpnomelane-Fe 13.02 13.02 0.00 0.000 0.21232E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -15.28 -8.62 -2.873 0.14719E+05 -6.921 3 CH4,gas 4.54 -6.37 -10.91 -2.728 0.18632E+05 -9.213 4 H2,gas 8.00 2.23 -5.77 -3.298 0.98551E+04 -4.073 5 H2S,gas -6.23 -15.90 -9.67 -4.837 0.16519E+05 -7.975 6 S2,gas -7.34 -36.27 -28.93 -4.451 0.49396E+05 -27.231 7 CO,gas 3.21 -13.05 -16.27 -5.005 0.27776E+05 -14.568 8 SO3,gas 17.12 -24.82 -41.94 -10.484 0.71608E+05 -40.239 9 SO2,gas 0.83 -22.59 -23.42 -6.246 0.39990E+05 -21.722 10 HCl,gas 5.19 -13.91 -19.10 -9.548 0.32607E+05 -17.397 11 acmite 7.71 7.09 -0.62 -0.064 0.10572E+04 15 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 19 spessartine 24.46 19.84 -4.62 -0.231 0.78890E+04 20 analcite 3.32 2.86 -0.47 -0.052 0.79564E+03 26 annite 20.12 17.52 -2.61 -0.145 0.44498E+04 27 phlogopite 27.06 24.73 -2.33 -0.129 0.39799E+04 29 anorthite 12.71 8.68 -4.03 -0.310 0.68873E+04 35 aragonite 0.97 -2.76 -3.73 -1.243 0.63673E+04 36 brucite 12.57 9.07 -3.50 -0.699 0.59679E+04 37 calcite 0.81 -2.76 -3.57 -1.191 0.61031E+04 38 carnegieite-low 9.02 6.10 -2.93 -0.418 0.49989E+04 39 carnegieite-high 10.09 6.10 -4.00 -0.571 0.68259E+04 40 carpholite-Mg 8.58 5.23 -3.35 -0.223 0.57195E+04 41 carpholite-Fe 6.71 2.83 -3.89 -0.259 0.66347E+04 42 celadonite 5.34 3.35 -1.99 -0.117 0.34055E+04 43 celadonite-Fe 3.88 0.94 -2.93 -0.173 0.50111E+04 44 chrysotile 23.89 20.74 -3.15 -0.263 0.53814E+04 50 chloritoid-Mg 13.20 8.47 -4.73 -0.315 0.80687E+04 51 chloritoid-Fe 9.17 6.07 -3.11 -0.207 0.53050E+04 52 chloritoid-Mn 11.40 8.37 -3.03 -0.202 0.51732E+04 54 coesite -2.38 -3.24 -0.86 -0.288 0.14747E+04 61 cristobalite -2.56 -3.24 -0.68 -0.226 0.11601E+04 63 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71234E+04 65 diaspore 2.87 1.32 -1.55 -0.259 0.26542E+04 67 diopside 16.18 15.11 -1.07 -0.107 0.18265E+04 68 hedenbergite 14.21 12.71 -1.50 -0.150 0.25648E+04 75 epidote 24.67 23.51 -1.16 -0.056 0.19829E+04 76 clinozoisite 22.81 19.27 -3.53 -0.161 0.60310E+04 77 epidote-Fe 29.84 27.74 -2.10 -0.109 0.35814E+04 78 fayalite 14.05 10.10 -3.95 -0.564 0.67438E+04 79 ferrosilite 11.15 6.86 -4.29 -0.429 0.73303E+04 83 gibbsite 4.08 1.32 -2.76 -0.394 0.47127E+04 84 glaucophane 22.97 19.97 -3.00 -0.081 0.51255E+04 85 glaucophane-Fe 17.28 12.76 -4.52 -0.122 0.77164E+04 87 greenalite 16.14 13.52 -2.62 -0.218 0.44653E+04 90 hematite 12.57 11.11 -1.46 -0.177 0.24900E+04 91 heulandite -5.83 -7.52 -1.69 -0.077 0.28938E+04 95 jadeite 4.22 2.86 -1.36 -0.136 0.23211E+04 96 julgoldite 70.43 66.18 -4.24 -0.110 0.72447E+04 97 kalsilite 7.58 3.99 -3.59 -0.513 0.61314E+04 98 kaolinite -1.33 -3.84 -2.51 -0.228 0.42827E+04 101 laumontite 2.88 2.20 -0.69 -0.046 0.11717E+04 102 lawsonite 9.62 8.68 -0.94 -0.063 0.16039E+04 103 leucite 4.12 0.75 -3.37 -0.337 0.57467E+04 105 lizardite 23.24 20.74 -2.50 -0.209 0.42740E+04 107 magnetite 20.09 17.78 -2.31 -0.189 0.39470E+04 108 minnesotaite 10.39 7.04 -3.34 -0.197 0.57086E+04 120 muscovite 2.58 0.15 -2.43 -0.143 0.41499E+04 121 paragonite 4.24 2.25 -1.98 -0.117 0.33890E+04 122 nepheline 8.34 6.10 -2.24 -0.321 0.38313E+04 128 periclase-Fe 11.63 6.67 -4.96 -1.240 0.84667E+04 134 phlogopite-Na 29.65 26.84 -2.81 -0.156 0.47987E+04 136 prehnite 19.37 17.95 -1.42 -0.083 0.24198E+04 137 prehnite-Fe 22.50 22.19 -0.31 -0.019 0.52675E+03 138 pumpellyite-Fe 46.27 43.90 -2.37 -0.053 0.40516E+04 139 pumpellyite-Mg 48.99 46.30 -2.69 -0.060 0.45980E+04 143 pyrrhotite -4.26 -9.24 -4.98 -1.659 0.84968E+04 144 pyrrhotiteFe0.875 -6.02 -10.35 -4.33 -1.592 0.73923E+04 145 pyroxmangite 7.40 5.73 -1.67 -0.333 0.28444E+04 146 pyrophyllite -6.18 -10.32 -4.14 -0.259 0.70770E+04 147 quartz -2.99 -3.24 -0.25 -0.083 0.42741E+03 152 rhodonite 7.45 5.73 -1.71 -0.343 0.29246E+04 153 sanidine -1.28 -2.49 -1.21 -0.093 0.20677E+04 165 stilpnomelane-Mg 27.44 25.04 -2.40 -0.072 0.40930E+04 171 talc 16.49 14.26 -2.23 -0.131 0.38074E+04 174 tephroite 18.09 14.71 -3.38 -0.483 0.57718E+04 178 tridymite -2.63 -3.24 -0.61 -0.204 0.10474E+04 179 tremolite 47.87 44.48 -3.38 -0.091 0.57794E+04 181 troilite-low -4.41 -9.24 -4.83 -1.609 0.82396E+04 187 wairakite 3.95 2.20 -1.75 -0.103 0.29936E+04 188 walstromite 11.51 9.28 -2.23 -0.446 0.38098E+04 189 wollastonite 10.46 9.28 -1.18 -0.237 0.20202E+04 190 pseudo-wollastonite 11.00 9.28 -1.72 -0.344 0.29401E+04 191 zoisite 22.85 19.27 -3.58 -0.163 0.61050E+04 192 akaganeite 7.75 5.55 -2.20 -0.476 0.37575E+04 197 beidellite-Na -1.34 -6.17 -4.83 -0.296 0.82445E+04 199 chalcedony -2.80 -3.24 -0.44 -0.146 0.74671E+03 201 montmorillonite-Ca -2.29 -5.70 -3.41 -0.211 0.58148E+04 202 montmorillonite-K -2.24 -5.81 -3.57 -0.219 0.61016E+04 203 montmorillonite-Mg -2.48 -6.26 -3.78 -0.234 0.64622E+04 204 montmorillonite-Na -2.04 -5.12 -3.08 -0.189 0.52565E+04 205 nontronite-Ca 3.21 1.72 -1.50 -0.097 0.25540E+04 206 nontronite-H 2.53 -0.35 -2.88 -0.193 0.49164E+04 207 nontronite-K 3.34 1.60 -1.74 -0.111 0.29640E+04 208 nontronite-Mg 3.07 1.15 -1.92 -0.125 0.32855E+04 209 nontronite-Na 3.52 2.30 -1.22 -0.078 0.20849E+04 224 tobermorite 9.82 7.19 -2.64 -0.719 0.45001E+04 233 boehmite 4.41 1.32 -3.09 -0.515 0.52711E+04 235 ferrous-oxide 9.81 6.67 -3.14 -0.786 0.53677E+04 240 silica-amorphous -2.09 -3.24 -1.15 -0.383 0.19609E+04 242 an20ab80 2.02 1.43 -0.59 -0.045 0.10066E+04 243 an25ab75 2.65 1.88 -0.76 -0.059 0.13052E+04 244 an30ab70 3.28 2.33 -0.94 -0.073 0.16135E+04 245 tr.625ac.25prg.125 45.16 42.65 -2.51 -0.068 0.42936E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 2.0000000 g Current total amount of reactant added: 45.9990000 g New total amount of reactant added: 47.9990000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.1497E-12 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 9 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 47.9990000 Water: Moles liquid = 0.5519E+02 kg liquid = 0.9942E+00 Moles total = 0.5491E+02 kg total = 0.9892E+00 Activity = 1.0000 Stoichiometric ionic strength = .7186130E-02 Osmotic coef. = 0.9574 True ionic strength = .1303950E-01 Chg. balance for total moles = -.1497E-12 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.11854E-09 -9.9261 0.10213E-09 -9.9908 0.86159E+00 -0.0647 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13835E-03 -3.8590 0.11869E-03 -3.9256 0.85791E+00 -0.0666 4 SO4-- 0.21724E-04 -4.6631 0.12522E-04 -4.9023 0.57643E+00 -0.2393 5 HCO3- 0.57746E-05 -5.2385 0.49592E-05 -5.3046 0.85880E+00 -0.0661 6 HS- 0.39086E-05 -5.4080 0.33536E-05 -5.4745 0.85800E+00 -0.0665 7 Al+++ 0.70712E-28 -28.1505 0.20740E-28 -28.6832 0.29331E+00 -0.5327 8 H4SiO4 0.58063E-03 -3.2361 0.58063E-03 -3.2361 0.10000E+01 0.0000 9 Ca++ 0.64834E-07 -7.1882 0.37179E-07 -7.4297 0.57345E+00 -0.2415 10 Mg++ 0.22215E-10 -10.6534 0.12698E-10 -10.8963 0.57159E+00 -0.2429 11 Fe++ 0.85718E-13 -13.0669 0.49034E-13 -13.3095 0.57203E+00 -0.2426 12 K+ 0.10178E-03 -3.9923 0.87424E-04 -4.0584 0.85895E+00 -0.0660 13 Na+ 0.12908E-01 -1.8891 0.11073E-01 -1.9557 0.85781E+00 -0.0666 14 Mn++ 0.17589E-10 -10.7548 0.10068E-10 -10.9971 0.57237E+00 -0.2423 15 HPO4-- 0.17773E-06 -6.7502 0.10246E-06 -6.9894 0.57649E+00 -0.2392 16 HSiO3- 0.61876E-02 -2.2085 0.53084E-02 -2.2750 0.85791E+00 -0.0666 17 Ca(HSiO3)+ 0.52320E-08 -8.2813 0.44947E-08 -8.3473 0.85908E+00 -0.0660 18 Mg(HSiO3)+ 0.22238E-11 -11.6529 0.19104E-11 -11.7189 0.85908E+00 -0.0660 19 NaHSiO3,aq 0.95067E-03 -3.0220 0.95067E-03 -3.0220 0.10000E+01 0.0000 20 AlO+ 0.31487E-15 -15.5019 0.27050E-15 -15.5678 0.85908E+00 -0.0660 22 HAlO2,aq 0.52745E-09 -9.2778 0.52745E-09 -9.2778 0.10000E+01 0.0000 23 AlO2- 0.13342E-04 -4.8748 0.11432E-04 -4.9419 0.85681E+00 -0.0671 24 CH4,aq 0.12930E-11 -11.8884 0.12901E-11 -11.8894 0.99779E+00 -0.0010 29 CO,aq 0.23443E-17 -17.6300 0.23443E-17 -17.6300 0.10000E+01 0.0000 30 CO2,aq 0.10846E-08 -8.9647 0.10823E-08 -8.9657 0.99779E+00 -0.0010 31 CO3-2 0.73689E-05 -5.1326 0.42413E-05 -5.3725 0.57556E+00 -0.2399 32 CaCO3,aq 0.19772E-08 -8.7040 0.19772E-08 -8.7040 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.54784E-11 -11.2613 0.47064E-11 -11.3273 0.85908E+00 -0.0660 34 CaCl+ 0.83126E-11 -11.0803 0.71412E-11 -11.1462 0.85908E+00 -0.0660 35 CaCl2,aq 0.20137E-15 -15.6960 0.20137E-15 -15.6960 0.10000E+01 0.0000 36 CaOH+ 0.30200E-07 -7.5200 0.25944E-07 -7.5860 0.85908E+00 -0.0660 37 CaSO4,aq 0.14784E-09 -9.8302 0.14784E-09 -9.8302 0.10000E+01 0.0000 38 HCl,aq 0.22213E-14 -14.6534 0.22213E-14 -14.6534 0.10000E+01 0.0000 43 FeCl+ 0.10723E-16 -16.9697 0.92117E-17 -17.0357 0.85908E+00 -0.0660 46 FeO,aq 0.18270E-09 -9.7383 0.18270E-09 -9.7383 0.10000E+01 0.0000 47 FeOH+ 0.18191E-10 -10.7401 0.15628E-10 -10.8061 0.85908E+00 -0.0660 48 HFeO2- 0.21817E-07 -7.6612 0.18717E-07 -7.7278 0.85791E+00 -0.0666 49 FeO+ 0.14776E-15 -15.8304 0.12694E-15 -15.8964 0.85908E+00 -0.0660 51 FeO2- 0.29026E-08 -8.5372 0.24901E-08 -8.6038 0.85791E+00 -0.0666 52 HFeO2,aq 0.32346E-10 -10.4902 0.32346E-10 -10.4902 0.10000E+01 0.0000 53 H2,aq 0.86419E-07 -7.0634 0.86228E-07 -7.0644 0.99779E+00 -0.0010 54 KCl,aq 0.18806E-09 -9.7257 0.18806E-09 -9.7257 0.10000E+01 0.0000 55 KHSO4,aq 0.31613E-18 -18.5001 0.31613E-18 -18.5001 0.10000E+01 0.0000 56 KOH,aq 0.36556E-06 -6.4370 0.36556E-06 -6.4370 0.10000E+01 0.0000 57 KSO4- 0.19802E-07 -7.7033 0.16988E-07 -7.7699 0.85791E+00 -0.0666 58 MgCO3,aq 0.16926E-12 -12.7714 0.16926E-12 -12.7714 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.19119E-14 -14.7185 0.16425E-14 -14.7845 0.85908E+00 -0.0660 60 MgCl+ 0.25731E-14 -14.5895 0.22105E-14 -14.6555 0.85908E+00 -0.0660 61 MgOH+ 0.57074E-10 -10.2436 0.49031E-10 -10.3095 0.85908E+00 -0.0660 63 MnO,aq 0.99952E-09 -9.0002 0.99952E-09 -9.0002 0.10000E+01 0.0000 64 MnOH+ 0.34697E-09 -9.4597 0.29808E-09 -9.5257 0.85908E+00 -0.0660 65 MnO2-2 0.55252E-11 -11.2576 0.31801E-11 -11.4976 0.57556E+00 -0.2399 66 HMnO2- 0.82941E-10 -10.0812 0.71156E-10 -10.1478 0.85791E+00 -0.0666 69 MnCl+ 0.85652E-14 -14.0673 0.73582E-14 -14.1332 0.85908E+00 -0.0660 70 MnSO4,aq 0.36395E-13 -13.4390 0.36395E-13 -13.4390 0.10000E+01 0.0000 71 NaCl,aq 0.43554E-06 -6.3610 0.43554E-06 -6.3610 0.10000E+01 0.0000 72 NaOH,aq 0.46581E-04 -4.3318 0.46581E-04 -4.3318 0.10000E+01 0.0000 74 OH- 0.66026E-02 -2.1803 0.56571E-02 -2.2474 0.85681E+00 -0.0671 79 HPO3-2 0.47837E-16 -16.3202 0.27533E-16 -16.5601 0.57556E+00 -0.2399 82 H3PO4,aq 0.74749E-17 -17.1264 0.74749E-17 -17.1264 0.10000E+01 0.0000 83 H2PO4- 0.22486E-09 -9.6481 0.19304E-09 -9.7143 0.85849E+00 -0.0663 84 PO4-3 0.26954E-08 -8.5694 0.81852E-09 -9.0870 0.30367E+00 -0.5176 88 HP2O7-3 0.19465E-16 -16.7107 0.57127E-17 -17.2432 0.29348E+00 -0.5324 89 P2O7-4 0.11435E-15 -15.9418 0.13363E-16 -16.8741 0.11685E+00 -0.9324 90 H2S,aq 0.10609E-08 -8.9743 0.10586E-08 -8.9753 0.99779E+00 -0.0010 91 S2-2 0.50213E-14 -14.2992 0.28901E-14 -14.5391 0.57556E+00 -0.2399 97 SO3-2 0.24132E-12 -12.6174 0.14032E-12 -12.8529 0.58146E+00 -0.2355 98 HSO3- 0.10459E-14 -14.9805 0.89729E-15 -15.0471 0.85791E+00 -0.0666 99 HSO4- 0.14337E-11 -11.8435 0.12325E-11 -11.9092 0.85966E+00 -0.0657 101 S2O3-2 0.27054E-15 -15.5678 0.15571E-15 -15.8077 0.57556E+00 -0.2399 Charge balance for all species = -.1456E-12 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.1185394E-09 -.1384868E-01 -.1394401E+02 0.0000 2 H2O 0.1000000E+01 0.5550779E+02 0.9989411E+06 0.0000 3 Cl- 0.1383466E-03 0.1387823E-03 0.4915092E+01 6.0653 4 SO4-- 0.2172421E-04 0.2172292E-04 0.2084551E+01 15.0794 5 HCO3- 0.5774585E-05 0.1314656E-04 0.8013251E+00 4.6863 6 HS- 0.3908640E-05 0.3930940E-05 0.1298678E+00 4.5164 7 Al+++ 0.7071181E-28 0.1334289E-04 0.3596339E+00 1.2893 8 H4SiO4 0.5806332E-03 0.7718946E-02 0.7411319E+03 -3.2361 9 Ca++ 0.6483370E-07 0.1024043E-06 0.4099858E-02 12.5520 10 Mg++ 0.2221471E-10 0.8168602E-10 0.1983869E-05 9.0854 11 Fe++ 0.8571777E-13 0.2495282E-07 0.1392079E-02 6.6722 12 K+ 0.1017801E-03 0.1021656E-03 0.3990692E+01 5.9325 13 Na+ 0.1290821E-01 0.1390590E-01 0.3193587E+03 8.0351 14 Mn++ 0.1758920E-10 0.1452597E-08 0.7971914E-04 8.9846 15 HPO4-- 0.1777342E-06 0.1806545E-06 0.1732086E-01 12.9922 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.7947791E+00 -.1376804E-01 -.7810111E+00 0.0000000E+00 2 H2O 0.5490656E+02 0.5518455E+02 -.2779915E+00 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.1355720E-02 0.2159642E-04 0.1334124E-02 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.1330216E-02 0.3908049E-05 -.1334124E-02 0.0000000E+00 7 Al+++ 0.1565123E+00 0.1326520E-04 0.1564991E+00 0.0000000E+00 8 H4SiO4 0.4998032E+00 0.7673997E-02 0.4921292E+00 0.0000000E+00 9 Ca++ 0.5522017E-01 0.1018080E-06 0.5522007E-01 0.0000000E+00 10 Mg++ 0.3809444E-01 0.8121034E-10 0.3809444E-01 0.0000000E+00 11 Fe++ 0.3422370E-01 0.2480751E-07 0.3422367E-01 0.0000000E+00 12 K+ 0.1019087E-01 0.1015707E-03 0.1008930E-01 0.0000000E+00 13 Na+ 0.6041051E-01 0.1382492E-01 0.4658559E-01 0.0000000E+00 14 Mn++ 0.8322353E-03 0.1444139E-08 0.8322338E-03 0.0000000E+00 15 HPO4-- 0.2840378E-03 0.1796025E-06 0.2838582E-03 0.0000000E+00 Chg. balance for solid moles: 0.1023E-15 Mass of aqueous solution: 0.995220E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 47.9990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 0.4659E-01 -1.332 12.22 1.087 23.31 4.689 andradite 0.5336E-02 -2.273 2.712 0.433 5.175 0.7046 grossular 0.4575E-03 -3.340 0.2061 -0.686 0.3933 0.5734E-01 apatite-OH 0.9462E-04 -4.024 0.4753E-01 -1.323 0.9070E-01 0.1510E-01 clinochlore 0.7619E-02 -2.118 4.235 0.627 8.082 1.611 daphnite 0.3087E-02 -2.510 2.202 0.343 4.203 0.6674 chlorite-Mn 0.1664E-03 -3.779 0.1180 -0.928 0.2252 0.3761E-01 microcline 0.9278E-02 -2.033 2.582 0.412 4.928 1.009 stilbite 0.3736E-01 -1.428 26.33 1.420 50.25 12.28 stilpnomelane-Fe 0.1623E-02 -2.790 1.750 0.243 3.339 0.6045 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.9210E+00 0.9210E+00 1.0000 -0.036 grossular 0.7896E-01 0.7896E-01 1.0000 -1.103 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.7008E+00 0.7008E+00 1.0000 -0.154 daphnite 0.2839E+00 0.2839E+00 1.0000 -0.547 chlorite-Mn 0.1531E-01 0.1531E-01 1.0000 -1.815 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 52.400543 g Volume = 21.676978 cm3 Porosity: -7.3139% V(tot) - V(min): -.14774E+01 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 47.9990000 g log = 1.6812 Original solution: 1000.0103000 g Original solution / Rock added: 20.83 (Water/Rock Ratio), log = 1.3188 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0204 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9999E+00 0.9860 0.1006E+01 0.1020E+01 CO2,gas 0.1127E-06 1.0071 0.1158E-06 0.1150E-06 CH4,gas 0.1838E-08 1.0125 0.1899E-08 0.1875E-08 H2,gas 0.1109E-03 1.0005 0.1132E-03 0.1131E-03 H2S,gas 0.2863E-07 0.9960 0.2910E-07 0.2922E-07 S2,gas 0.2430E-26 1.0000 0.2480E-26 0.2480E-26 CO,gas 0.3424E-14 1.0000 0.3493E-14 0.3493E-14 SO3,gas 0.4840E-40 1.0000 0.4939E-40 0.4939E-40 SO2,gas 0.2132E-21 1.0000 0.2175E-21 0.2175E-21 HCl,gas 0.3841E-17 1.0000 0.3920E-17 0.3920E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 16 albite -0.38 -0.38 0.00 0.000 0.11184E-10 22 andradite 39.01 39.01 0.00 0.000 0.00000E+00 23 grossular 32.73 32.73 0.00 0.000 0.36397E-10 32 apatite-OH -18.15 -18.15 0.00 0.000 -0.12132E-10 46 clinochlore 39.07 39.07 0.00 0.000 0.00000E+00 47 daphnite 28.97 28.97 0.00 0.000 0.42463E-10 48 chlorite-Mn 46.87 46.87 0.00 0.000 -0.24265E-10 116 microcline -2.49 -2.49 0.00 0.000 0.15165E-11 163 stilbite -7.52 -7.52 0.00 0.000 -0.90992E-11 164 stilpnomelane-Fe 13.02 13.02 0.00 0.000 0.21232E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -15.30 -8.64 -2.878 0.14745E+05 -6.936 3 CH4,gas 4.54 -5.88 -10.42 -2.605 0.17793E+05 -8.721 4 H2,gas 8.00 2.35 -5.65 -3.226 0.96388E+04 -3.946 5 H2S,gas -6.23 -15.47 -9.24 -4.618 0.15769E+05 -7.536 6 S2,gas -7.34 -35.64 -28.30 -4.355 0.48329E+05 -26.606 7 CO,gas 3.21 -12.94 -16.16 -4.971 0.27585E+05 -14.457 8 SO3,gas 17.12 -24.88 -42.01 -10.501 0.71723E+05 -40.306 9 SO2,gas 0.83 -22.53 -23.36 -6.230 0.39889E+05 -21.662 10 HCl,gas 5.19 -13.92 -19.11 -9.553 0.32623E+05 -17.407 11 acmite 7.71 7.06 -0.65 -0.068 0.11132E+04 15 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 19 spessartine 24.46 19.82 -4.63 -0.232 0.79110E+04 20 analcite 3.32 2.85 -0.47 -0.052 0.80188E+03 26 annite 20.12 17.53 -2.59 -0.144 0.44281E+04 27 phlogopite 27.06 24.77 -2.29 -0.127 0.39184E+04 29 anorthite 12.71 8.66 -4.05 -0.312 0.69185E+04 35 aragonite 0.97 -2.74 -3.71 -1.237 0.63347E+04 36 brucite 12.57 9.09 -3.48 -0.697 0.59474E+04 37 calcite 0.81 -2.74 -3.56 -1.185 0.60705E+04 38 carnegieite-low 9.02 6.09 -2.93 -0.419 0.50114E+04 39 carnegieite-high 10.09 6.09 -4.00 -0.572 0.68384E+04 40 carpholite-Mg 8.58 5.19 -3.39 -0.226 0.57887E+04 41 carpholite-Fe 6.71 2.78 -3.93 -0.262 0.67172E+04 42 celadonite 5.34 3.36 -1.98 -0.116 0.33787E+04 43 celadonite-Fe 3.88 0.95 -2.93 -0.172 0.49977E+04 44 chrysotile 23.89 20.78 -3.11 -0.259 0.53075E+04 50 chloritoid-Mg 13.20 8.43 -4.77 -0.318 0.81442E+04 51 chloritoid-Fe 9.17 6.01 -3.16 -0.211 0.53937E+04 52 chloritoid-Mn 11.40 8.33 -3.07 -0.205 0.52486E+04 54 coesite -2.38 -3.24 -0.86 -0.287 0.14685E+04 61 cristobalite -2.56 -3.24 -0.68 -0.225 0.11538E+04 63 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71234E+04 65 diaspore 2.87 1.29 -1.58 -0.264 0.27053E+04 67 diopside 16.18 15.17 -1.02 -0.102 0.17351E+04 68 hedenbergite 14.21 12.75 -1.46 -0.146 0.24866E+04 75 epidote 24.67 23.47 -1.20 -0.058 0.20503E+04 76 clinozoisite 22.81 19.26 -3.54 -0.161 0.60485E+04 77 epidote-Fe 29.84 27.67 -2.17 -0.113 0.36986E+04 78 fayalite 14.05 10.11 -3.94 -0.562 0.67231E+04 79 ferrosilite 11.15 6.87 -4.28 -0.428 0.73034E+04 83 gibbsite 4.08 1.29 -2.79 -0.399 0.47638E+04 84 glaucophane 22.97 20.02 -2.96 -0.080 0.50516E+04 85 glaucophane-Fe 17.28 12.78 -4.50 -0.122 0.76823E+04 87 greenalite 16.14 13.54 -2.60 -0.216 0.44312E+04 90 hematite 12.57 10.99 -1.58 -0.191 0.26918E+04 91 heulandite -5.83 -7.52 -1.69 -0.077 0.28938E+04 95 jadeite 4.22 2.85 -1.36 -0.136 0.23274E+04 96 julgoldite 70.43 66.11 -4.31 -0.112 0.73625E+04 97 kalsilite 7.58 3.99 -3.60 -0.514 0.61438E+04 98 kaolinite -1.33 -3.89 -2.56 -0.233 0.43724E+04 101 laumontite 2.88 2.19 -0.70 -0.046 0.11904E+04 102 lawsonite 9.62 8.66 -0.96 -0.064 0.16351E+04 103 leucite 4.12 0.75 -3.37 -0.337 0.57529E+04 105 lizardite 23.24 20.78 -2.46 -0.205 0.42001E+04 107 magnetite 20.09 17.66 -2.43 -0.198 0.41415E+04 108 minnesotaite 10.39 7.07 -3.32 -0.195 0.56619E+04 120 muscovite 2.58 0.09 -2.49 -0.146 0.42521E+04 121 paragonite 4.24 2.19 -2.04 -0.120 0.34912E+04 122 nepheline 8.34 6.09 -2.25 -0.322 0.38437E+04 128 periclase-Fe 11.63 6.67 -4.95 -1.239 0.84595E+04 134 phlogopite-Na 29.65 26.87 -2.77 -0.154 0.47372E+04 136 prehnite 19.37 17.97 -1.40 -0.082 0.23863E+04 137 prehnite-Fe 22.50 22.18 -0.32 -0.019 0.54305E+03 138 pumpellyite-Fe 46.27 43.91 -2.36 -0.052 0.40284E+04 139 pumpellyite-Mg 48.99 46.32 -2.67 -0.059 0.45615E+04 143 pyrrhotite -4.26 -8.79 -4.53 -1.511 0.77397E+04 144 pyrrhotiteFe0.875 -6.02 -9.92 -3.90 -1.435 0.66629E+04 145 pyroxmangite 7.40 5.75 -1.65 -0.330 0.28176E+04 146 pyrophyllite -6.18 -10.37 -4.19 -0.262 0.71542E+04 147 quartz -2.99 -3.24 -0.25 -0.082 0.42117E+03 152 rhodonite 7.45 5.75 -1.70 -0.339 0.28979E+04 153 sanidine -1.28 -2.49 -1.21 -0.093 0.20677E+04 165 stilpnomelane-Mg 27.44 25.08 -2.36 -0.070 0.40267E+04 171 talc 16.49 14.31 -2.18 -0.128 0.37210E+04 174 tephroite 18.09 14.73 -3.35 -0.479 0.57246E+04 178 tridymite -2.63 -3.24 -0.61 -0.203 0.10411E+04 179 tremolite 47.87 44.64 -3.23 -0.087 0.55101E+04 181 troilite-low -4.41 -8.79 -4.38 -1.461 0.74825E+04 187 wairakite 3.95 2.19 -1.76 -0.104 0.30124E+04 188 walstromite 11.51 9.32 -2.19 -0.439 0.37451E+04 189 wollastonite 10.46 9.32 -1.15 -0.229 0.19555E+04 190 pseudo-wollastonite 11.00 9.32 -1.68 -0.337 0.28753E+04 191 zoisite 22.85 19.26 -3.59 -0.163 0.61226E+04 192 akaganeite 7.75 5.49 -2.26 -0.489 0.38585E+04 197 beidellite-Na -1.34 -6.22 -4.88 -0.299 0.83299E+04 199 chalcedony -2.80 -3.24 -0.43 -0.145 0.74047E+03 201 montmorillonite-Ca -2.29 -5.72 -3.43 -0.212 0.58587E+04 202 montmorillonite-K -2.24 -5.84 -3.60 -0.220 0.61445E+04 203 montmorillonite-Mg -2.48 -6.29 -3.81 -0.236 0.65124E+04 204 montmorillonite-Na -2.04 -5.14 -3.10 -0.190 0.52994E+04 205 nontronite-Ca 3.21 1.61 -1.60 -0.104 0.27401E+04 206 nontronite-H 2.53 -0.46 -2.99 -0.201 0.51122E+04 207 nontronite-K 3.34 1.50 -1.84 -0.118 0.31491E+04 208 nontronite-Mg 3.07 1.04 -2.04 -0.132 0.34779E+04 209 nontronite-Na 3.52 2.19 -1.33 -0.085 0.22700E+04 224 tobermorite 9.82 7.22 -2.60 -0.710 0.44452E+04 233 boehmite 4.41 1.29 -3.12 -0.519 0.53222E+04 235 ferrous-oxide 9.81 6.67 -3.14 -0.785 0.53605E+04 240 silica-amorphous -2.09 -3.24 -1.14 -0.382 0.19546E+04 242 an20ab80 2.02 1.42 -0.59 -0.046 0.10128E+04 243 an25ab75 2.65 1.88 -0.77 -0.059 0.13130E+04 244 an30ab70 3.28 2.33 -0.95 -0.073 0.16228E+04 245 tr.625ac.25prg.125 45.16 42.79 -2.38 -0.064 0.40601E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 2.0000000 g Current total amount of reactant added: 47.9990000 g New total amount of reactant added: 49.9990000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.1496E-12 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 9 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 49.9990000 Water: Moles liquid = 0.5517E+02 kg liquid = 0.9940E+00 Moles total = 0.5488E+02 kg total = 0.9887E+00 Activity = 1.0000 Stoichiometric ionic strength = .7342340E-02 Osmotic coef. = 0.9585 True ionic strength = .1331943E-01 Chg. balance for total moles = -.1496E-12 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.11670E-09 -9.9329 0.10043E-09 -9.9982 0.86058E+00 -0.0652 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13837E-03 -3.8590 0.11856E-03 -3.9261 0.85685E+00 -0.0671 4 SO4-- 0.17402E-04 -4.7594 0.99826E-05 -5.0008 0.57366E+00 -0.2413 5 HCO3- 0.57097E-05 -5.2434 0.48975E-05 -5.3100 0.85775E+00 -0.0666 6 HS- 0.82395E-05 -5.0841 0.70608E-05 -5.1511 0.85694E+00 -0.0670 7 Al+++ 0.63788E-28 -28.1953 0.18504E-28 -28.7327 0.29009E+00 -0.5375 8 H4SiO4 0.58575E-03 -3.2323 0.58575E-03 -3.2323 0.10000E+01 0.0000 9 Ca++ 0.67269E-07 -7.1722 0.38386E-07 -7.4158 0.57064E+00 -0.2436 10 Mg++ 0.22134E-10 -10.6549 0.12589E-10 -10.9000 0.56876E+00 -0.2451 11 Fe++ 0.83931E-13 -13.0761 0.47774E-13 -13.3208 0.56921E+00 -0.2447 12 K+ 0.10400E-03 -3.9830 0.89223E-04 -4.0495 0.85790E+00 -0.0666 13 Na+ 0.13190E-01 -1.8797 0.11301E-01 -1.9469 0.85675E+00 -0.0671 14 Mn++ 0.17525E-10 -10.7563 0.99812E-11 -11.0008 0.56955E+00 -0.2445 15 HPO4-- 0.16557E-06 -6.7810 0.94990E-07 -7.0223 0.57371E+00 -0.2413 16 HSiO3- 0.63561E-02 -2.1968 0.54462E-02 -2.2639 0.85685E+00 -0.0671 17 Ca(HSiO3)+ 0.55488E-08 -8.2558 0.47610E-08 -8.3223 0.85804E+00 -0.0665 18 Mg(HSiO3)+ 0.22647E-11 -11.6450 0.19432E-11 -11.7115 0.85804E+00 -0.0665 19 NaHSiO3,aq 0.99541E-03 -3.0020 0.99541E-03 -3.0020 0.10000E+01 0.0000 20 AlO+ 0.29091E-15 -15.5362 0.24961E-15 -15.6027 0.85804E+00 -0.0665 22 HAlO2,aq 0.49498E-09 -9.3054 0.49498E-09 -9.3054 0.10000E+01 0.0000 23 AlO2- 0.12750E-04 -4.8945 0.10910E-04 -4.9622 0.85573E+00 -0.0677 24 CH4,aq 0.33725E-11 -11.4721 0.33649E-11 -11.4730 0.99775E+00 -0.0010 29 CO,aq 0.29143E-17 -17.5355 0.29143E-17 -17.5355 0.10000E+01 0.0000 30 CO2,aq 0.10533E-08 -8.9774 0.10509E-08 -8.9784 0.99775E+00 -0.0010 31 CO3-2 0.74367E-05 -5.1286 0.42596E-05 -5.3706 0.57278E+00 -0.2420 32 CaCO3,aq 0.20502E-08 -8.6882 0.20502E-08 -8.6882 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.55927E-11 -11.2524 0.47988E-11 -11.3189 0.85804E+00 -0.0665 34 CaCl+ 0.85837E-11 -11.0663 0.73651E-11 -11.1328 0.85804E+00 -0.0665 35 CaCl2,aq 0.20746E-15 -15.6831 0.20746E-15 -15.6831 0.10000E+01 0.0000 36 CaOH+ 0.31749E-07 -7.4983 0.27241E-07 -7.5648 0.85804E+00 -0.0665 37 CaSO4,aq 0.12168E-09 -9.9148 0.12168E-09 -9.9148 0.10000E+01 0.0000 38 HCl,aq 0.21819E-14 -14.6612 0.21819E-14 -14.6612 0.10000E+01 0.0000 43 FeCl+ 0.10449E-16 -16.9809 0.89654E-17 -17.0474 0.85804E+00 -0.0665 46 FeO,aq 0.18410E-09 -9.7349 0.18410E-09 -9.7349 0.10000E+01 0.0000 47 FeOH+ 0.18047E-10 -10.7436 0.15485E-10 -10.8101 0.85804E+00 -0.0665 48 HFeO2- 0.22386E-07 -7.6500 0.19181E-07 -7.7171 0.85685E+00 -0.0671 49 FeO+ 0.12956E-15 -15.8875 0.11117E-15 -15.9540 0.85804E+00 -0.0665 51 FeO2- 0.26322E-08 -8.5797 0.22554E-08 -8.6468 0.85685E+00 -0.0671 52 HFeO2,aq 0.28808E-10 -10.5405 0.28808E-10 -10.5405 0.10000E+01 0.0000 53 H2,aq 0.11064E-06 -6.9561 0.11039E-06 -6.9571 0.99775E+00 -0.0010 54 KCl,aq 0.19173E-09 -9.7173 0.19173E-09 -9.7173 0.10000E+01 0.0000 55 KHSO4,aq 0.25290E-18 -18.5970 0.25290E-18 -18.5970 0.10000E+01 0.0000 56 KOH,aq 0.37941E-06 -6.4209 0.37941E-06 -6.4209 0.10000E+01 0.0000 57 KSO4- 0.16130E-07 -7.7924 0.13821E-07 -7.8595 0.85685E+00 -0.0671 58 MgCO3,aq 0.16854E-12 -12.7733 0.16854E-12 -12.7733 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.18742E-14 -14.7272 0.16081E-14 -14.7937 0.85804E+00 -0.0665 60 MgCl+ 0.25514E-14 -14.5932 0.21892E-14 -14.6597 0.85804E+00 -0.0665 61 MgOH+ 0.57615E-10 -10.2395 0.49436E-10 -10.3060 0.85804E+00 -0.0665 63 MnO,aq 0.10249E-08 -8.9893 0.10249E-08 -8.9893 0.10000E+01 0.0000 64 MnOH+ 0.35026E-09 -9.4556 0.30054E-09 -9.5221 0.85804E+00 -0.0665 65 MnO2-2 0.58880E-11 -11.2300 0.33725E-11 -11.4720 0.57278E+00 -0.2420 66 HMnO2- 0.86598E-10 -10.0625 0.74202E-10 -10.1296 0.85685E+00 -0.0671 69 MnCl+ 0.84929E-14 -14.0709 0.72872E-14 -14.1374 0.85804E+00 -0.0665 70 MnSO4,aq 0.28765E-13 -13.5411 0.28765E-13 -13.5411 0.10000E+01 0.0000 71 NaCl,aq 0.44402E-06 -6.3526 0.44402E-06 -6.3526 0.10000E+01 0.0000 72 NaOH,aq 0.48347E-04 -4.3156 0.48347E-04 -4.3156 0.10000E+01 0.0000 74 OH- 0.67232E-02 -2.1724 0.57532E-02 -2.2401 0.85573E+00 -0.0677 79 HPO3-2 0.57051E-16 -16.2437 0.32677E-16 -16.4858 0.57278E+00 -0.2420 82 H3PO4,aq 0.67003E-17 -17.1739 0.67003E-17 -17.1739 0.10000E+01 0.0000 83 H2PO4- 0.20524E-09 -9.6877 0.17598E-09 -9.7545 0.85743E+00 -0.0668 84 PO4-3 0.25679E-08 -8.5904 0.77173E-09 -9.1125 0.30053E+00 -0.5221 88 HP2O7-3 0.16633E-16 -16.7790 0.48280E-17 -17.3162 0.29027E+00 -0.5372 89 P2O7-4 0.10019E-15 -15.9992 0.11485E-16 -16.9399 0.11463E+00 -0.9407 90 H2S,aq 0.21965E-08 -8.6583 0.21915E-08 -8.6593 0.99775E+00 -0.0010 91 S2-2 0.17471E-13 -13.7577 0.10007E-13 -13.9997 0.57278E+00 -0.2420 97 SO3-2 0.24743E-12 -12.6065 0.14320E-12 -12.8441 0.57875E+00 -0.2375 98 HSO3- 0.10509E-14 -14.9785 0.90043E-15 -15.0456 0.85685E+00 -0.0671 99 HSO4- 0.11252E-11 -11.9488 0.96614E-12 -12.0150 0.85863E+00 -0.0662 101 S2O3-2 0.44867E-15 -15.3481 0.25699E-15 -15.5901 0.57278E+00 -0.2420 Charge balance for all species = -.1479E-12 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.1166957E-09 -.1418195E-01 -.1427919E+02 0.0000 2 H2O 0.1000000E+01 0.5550770E+02 0.9989132E+06 0.0000 3 Cl- 0.1383695E-03 0.1388137E-03 0.4916074E+01 6.0721 4 SO4-- 0.1740171E-04 0.1739064E-04 0.1668777E+01 14.9955 5 HCO3- 0.5709679E-05 0.1314953E-04 0.8014851E+00 4.6881 6 HS- 0.8239494E-05 0.8269021E-05 0.2731792E+00 4.8470 7 Al+++ 0.6378773E-28 0.1275009E-04 0.3436469E+00 1.2617 8 H4SiO4 0.5857533E-03 0.7937244E-02 0.7620716E+03 -3.2323 9 Ca++ 0.6726875E-07 0.1067522E-06 0.4273816E-02 12.5805 10 Mg++ 0.2213391E-10 0.8218660E-10 0.1995973E-05 9.0963 11 Fe++ 0.8393050E-13 0.2524878E-07 0.1408553E-02 6.6755 12 K+ 0.1040009E-03 0.1043967E-03 0.4077731E+01 5.9486 13 Na+ 0.1319018E-01 0.1423438E-01 0.3268940E+03 8.0513 14 Mn++ 0.1752480E-10 0.1485204E-08 0.8150645E-04 8.9955 15 HPO4-- 0.1655703E-06 0.1683434E-06 0.1614007E-01 12.9740 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.8278962E+00 -.1409618E-01 -.8138000E+00 0.0000000E+00 2 H2O 0.5488149E+02 0.5517199E+02 -.2904971E+00 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.1411147E-02 0.1728546E-04 0.1393862E-02 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.1385643E-02 0.8219010E-05 -.1393862E-02 0.0000000E+00 7 Al+++ 0.1630338E+00 0.1267298E-04 0.1630211E+00 0.0000000E+00 8 H4SiO4 0.5206287E+00 0.7889240E-02 0.5127395E+00 0.0000000E+00 9 Ca++ 0.5752045E-01 0.1061065E-06 0.5752035E-01 0.0000000E+00 10 Mg++ 0.3968175E-01 0.8168954E-10 0.3968175E-01 0.0000000E+00 11 Fe++ 0.3564972E-01 0.2509608E-07 0.3564969E-01 0.0000000E+00 12 K+ 0.1061550E-01 0.1037653E-03 0.1051173E-01 0.0000000E+00 13 Na+ 0.6292100E-01 0.1414829E-01 0.4877270E-01 0.0000000E+00 14 Mn++ 0.8669125E-03 0.1476221E-08 0.8669110E-03 0.0000000E+00 15 HPO4-- 0.2958729E-03 0.1673253E-06 0.2957056E-03 0.0000000E+00 Chg. balance for solid moles: -.4001E-16 Mass of aqueous solution: 0.995021E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 49.9990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 0.4877E-01 -1.312 12.79 1.107 23.43 4.909 andradite 0.5575E-02 -2.254 2.833 0.452 5.191 0.7361 grossular 0.5037E-03 -3.298 0.2269 -0.644 0.4157 0.6313E-01 apatite-OH 0.9857E-04 -4.006 0.4951E-01 -1.305 0.9071E-01 0.1573E-01 clinochlore 0.7936E-02 -2.100 4.411 0.645 8.082 1.678 daphnite 0.3160E-02 -2.500 2.255 0.353 4.131 0.6832 chlorite-Mn 0.1734E-03 -3.761 0.1229 -0.910 0.2252 0.3917E-01 microcline 0.9642E-02 -2.016 2.684 0.429 4.917 1.048 stilbite 0.3879E-01 -1.411 27.34 1.437 50.08 12.75 stilpnomelane-Fe 0.1740E-02 -2.759 1.875 0.273 3.436 0.6478 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.9171E+00 0.9171E+00 1.0000 -0.038 grossular 0.8285E-01 0.8285E-01 1.0000 -1.082 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.7042E+00 0.7042E+00 1.0000 -0.152 daphnite 0.2804E+00 0.2804E+00 1.0000 -0.552 chlorite-Mn 0.1538E-01 0.1538E-01 1.0000 -1.813 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 54.583131 g Volume = 22.571031 cm3 Porosity: -7.4831% V(tot) - V(min): -.15714E+01 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 49.9990000 g log = 1.6990 Original solution: 1000.0103000 g Original solution / Rock added: 20.00 (Water/Rock Ratio), log = 1.3010 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0204 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9999E+00 0.9860 0.1006E+01 0.1020E+01 CO2,gas 0.1094E-06 1.0071 0.1124E-06 0.1116E-06 CH4,gas 0.4794E-08 1.0125 0.4953E-08 0.4892E-08 H2,gas 0.1419E-03 1.0005 0.1449E-03 0.1448E-03 H2S,gas 0.5927E-07 0.9960 0.6024E-07 0.6048E-07 S2,gas 0.6356E-26 1.0000 0.6486E-26 0.6486E-26 CO,gas 0.4256E-14 1.0000 0.4343E-14 0.4343E-14 SO3,gas 0.3730E-40 1.0000 0.3807E-40 0.3807E-40 SO2,gas 0.2103E-21 1.0000 0.2146E-21 0.2146E-21 HCl,gas 0.3773E-17 1.0000 0.3850E-17 0.3850E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 16 albite -0.38 -0.38 0.00 0.000 -0.94784E-12 22 andradite 39.01 39.01 0.00 0.000 0.24265E-10 23 grossular 32.73 32.73 0.00 0.000 -0.12132E-10 32 apatite-OH -18.15 -18.15 0.00 0.000 0.60662E-11 46 clinochlore 39.07 39.07 0.00 0.000 0.24265E-10 47 daphnite 28.97 28.97 0.00 0.000 0.24265E-10 48 chlorite-Mn 46.87 46.87 0.00 0.000 0.12132E-10 116 microcline -2.49 -2.49 0.00 0.000 0.15165E-11 163 stilbite -7.52 -7.52 0.00 0.000 -0.90992E-11 164 stilpnomelane-Fe 13.02 13.02 0.00 0.000 -0.27298E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -15.31 -8.65 -2.883 0.14766E+05 -6.949 3 CH4,gas 4.54 -5.46 -10.00 -2.501 0.17082E+05 -8.305 4 H2,gas 8.00 2.46 -5.54 -3.164 0.94557E+04 -3.839 5 H2S,gas -6.23 -15.15 -8.92 -4.460 0.15229E+05 -7.220 6 S2,gas -7.34 -35.22 -27.89 -4.290 0.47616E+05 -26.188 7 CO,gas 3.21 -12.85 -16.06 -4.942 0.27424E+05 -14.362 8 SO3,gas 17.12 -25.00 -42.12 -10.530 0.71916E+05 -40.419 9 SO2,gas 0.83 -22.54 -23.37 -6.231 0.39899E+05 -21.668 10 HCl,gas 5.19 -13.92 -19.11 -9.557 0.32636E+05 -17.415 11 acmite 7.71 7.03 -0.68 -0.070 0.11585E+04 15 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 19 spessartine 24.46 19.81 -4.64 -0.232 0.79300E+04 20 analcite 3.32 2.85 -0.47 -0.053 0.80839E+03 26 annite 20.12 17.54 -2.58 -0.144 0.44111E+04 27 phlogopite 27.06 24.80 -2.26 -0.126 0.38627E+04 29 anorthite 12.71 8.64 -4.07 -0.313 0.69510E+04 35 aragonite 0.97 -2.73 -3.69 -1.231 0.63078E+04 36 brucite 12.57 9.10 -3.47 -0.694 0.59288E+04 37 calcite 0.81 -2.73 -3.54 -1.180 0.60436E+04 38 carnegieite-low 9.02 6.08 -2.94 -0.420 0.50244E+04 39 carnegieite-high 10.09 6.08 -4.01 -0.573 0.68514E+04 40 carpholite-Mg 8.58 5.16 -3.43 -0.228 0.58513E+04 41 carpholite-Fe 6.71 2.73 -3.98 -0.265 0.67927E+04 42 celadonite 5.34 3.38 -1.96 -0.116 0.33536E+04 43 celadonite-Fe 3.88 0.96 -2.92 -0.172 0.49855E+04 44 chrysotile 23.89 20.82 -3.07 -0.256 0.52387E+04 50 chloritoid-Mg 13.20 8.39 -4.81 -0.321 0.82133E+04 51 chloritoid-Fe 9.17 5.97 -3.21 -0.214 0.54758E+04 52 chloritoid-Mn 11.40 8.29 -3.11 -0.208 0.53178E+04 54 coesite -2.38 -3.23 -0.86 -0.285 0.14620E+04 61 cristobalite -2.56 -3.23 -0.67 -0.224 0.11473E+04 63 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71234E+04 65 diaspore 2.87 1.26 -1.61 -0.269 0.27524E+04 67 diopside 16.18 15.21 -0.97 -0.097 0.16548E+04 68 hedenbergite 14.21 12.79 -1.42 -0.142 0.24193E+04 75 epidote 24.67 23.43 -1.24 -0.060 0.21136E+04 76 clinozoisite 22.81 19.25 -3.56 -0.162 0.60730E+04 77 epidote-Fe 29.84 27.61 -2.23 -0.116 0.38007E+04 78 fayalite 14.05 10.12 -3.93 -0.561 0.67053E+04 79 ferrosilite 11.15 6.89 -4.26 -0.426 0.72790E+04 83 gibbsite 4.08 1.26 -2.82 -0.403 0.48109E+04 84 glaucophane 22.97 20.06 -2.92 -0.079 0.49828E+04 85 glaucophane-Fe 17.28 12.79 -4.48 -0.121 0.76523E+04 87 greenalite 16.14 13.56 -2.58 -0.215 0.44012E+04 90 hematite 12.57 10.89 -1.68 -0.203 0.28637E+04 91 heulandite -5.83 -7.52 -1.69 -0.077 0.28938E+04 95 jadeite 4.22 2.85 -1.37 -0.137 0.23339E+04 96 julgoldite 70.43 66.06 -4.37 -0.113 0.74610E+04 97 kalsilite 7.58 3.98 -3.61 -0.515 0.61569E+04 98 kaolinite -1.33 -3.94 -2.61 -0.237 0.44537E+04 101 laumontite 2.88 2.17 -0.71 -0.047 0.12099E+04 102 lawsonite 9.62 8.64 -0.98 -0.065 0.16677E+04 103 leucite 4.12 0.75 -3.37 -0.337 0.57594E+04 105 lizardite 23.24 20.82 -2.42 -0.202 0.41313E+04 107 magnetite 20.09 17.56 -2.52 -0.206 0.43077E+04 108 minnesotaite 10.39 7.10 -3.29 -0.194 0.56189E+04 120 muscovite 2.58 0.04 -2.55 -0.150 0.43463E+04 121 paragonite 4.24 2.14 -2.10 -0.124 0.35854E+04 122 nepheline 8.34 6.08 -2.26 -0.323 0.38568E+04 128 periclase-Fe 11.63 6.68 -4.95 -1.238 0.84538E+04 134 phlogopite-Na 29.65 26.91 -2.74 -0.152 0.46815E+04 136 prehnite 19.37 17.99 -1.38 -0.081 0.23637E+04 137 prehnite-Fe 22.50 22.17 -0.33 -0.020 0.55921E+03 138 pumpellyite-Fe 46.27 43.91 -2.36 -0.052 0.40246E+04 139 pumpellyite-Mg 48.99 46.33 -2.66 -0.059 0.45448E+04 142 pyrite -21.25 -26.09 -4.84 -1.138 0.82610E+04 143 pyrrhotite -4.26 -8.47 -4.21 -1.404 0.71944E+04 144 pyrrhotiteFe0.875 -6.02 -9.61 -3.60 -1.323 0.61411E+04 145 pyroxmangite 7.40 5.76 -1.64 -0.327 0.27925E+04 146 pyrophyllite -6.18 -10.41 -4.23 -0.264 0.72224E+04 147 quartz -2.99 -3.23 -0.24 -0.081 0.41466E+03 152 rhodonite 7.45 5.76 -1.68 -0.336 0.28728E+04 153 sanidine -1.28 -2.49 -1.21 -0.093 0.20677E+04 165 stilpnomelane-Mg 27.44 25.12 -2.32 -0.069 0.39621E+04 171 talc 16.49 14.36 -2.13 -0.125 0.36392E+04 174 tephroite 18.09 14.76 -3.33 -0.475 0.56809E+04 178 tridymite -2.63 -3.23 -0.61 -0.202 0.10346E+04 179 tremolite 47.87 44.78 -3.09 -0.083 0.52678E+04 181 troilite-low -4.41 -8.47 -4.06 -1.354 0.69372E+04 187 wairakite 3.95 2.17 -1.78 -0.104 0.30319E+04 188 walstromite 11.51 9.35 -2.16 -0.432 0.36899E+04 189 wollastonite 10.46 9.35 -1.11 -0.223 0.19003E+04 190 pseudo-wollastonite 11.00 9.35 -1.65 -0.330 0.28202E+04 191 zoisite 22.85 19.25 -3.60 -0.164 0.61471E+04 192 akaganeite 7.75 5.44 -2.31 -0.499 0.39444E+04 197 beidellite-Na -1.34 -6.27 -4.92 -0.302 0.84067E+04 199 chalcedony -2.80 -3.23 -0.43 -0.143 0.73396E+03 201 montmorillonite-Ca -2.29 -5.74 -3.45 -0.214 0.58972E+04 202 montmorillonite-K -2.24 -5.86 -3.62 -0.222 0.61819E+04 203 montmorillonite-Mg -2.48 -6.32 -3.84 -0.238 0.65559E+04 204 montmorillonite-Na -2.04 -5.16 -3.13 -0.191 0.53368E+04 205 nontronite-Ca 3.21 1.52 -1.70 -0.110 0.28956E+04 206 nontronite-H 2.53 -0.56 -3.09 -0.207 0.52757E+04 207 nontronite-K 3.34 1.41 -1.93 -0.124 0.33035E+04 208 nontronite-Mg 3.07 0.94 -2.13 -0.138 0.36383E+04 209 nontronite-Na 3.52 2.10 -1.42 -0.091 0.24244E+04 224 tobermorite 9.82 7.25 -2.58 -0.703 0.43981E+04 233 boehmite 4.41 1.26 -3.14 -0.524 0.53693E+04 235 ferrous-oxide 9.81 6.68 -3.14 -0.784 0.53548E+04 240 silica-amorphous -2.09 -3.23 -1.14 -0.380 0.19481E+04 242 an20ab80 2.02 1.42 -0.60 -0.046 0.10194E+04 243 an25ab75 2.65 1.87 -0.77 -0.060 0.13212E+04 244 an30ab70 3.28 2.32 -0.96 -0.074 0.16326E+04 245 tr.625ac.25prg.125 45.16 42.91 -2.26 -0.061 0.38521E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 2.0000000 g Current total amount of reactant added: 49.9990000 g New total amount of reactant added: 51.9990000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.1495E-12 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 8 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 51.9990000 Water: Moles liquid = 0.5516E+02 kg liquid = 0.9937E+00 Moles total = 0.5486E+02 kg total = 0.9883E+00 Activity = 1.0000 Stoichiometric ionic strength = .7485442E-02 Osmotic coef. = 0.9604 True ionic strength = .1357672E-01 Chg. balance for total moles = -.1495E-12 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.11510E-09 -9.9389 0.98946E-10 -10.0046 0.85968E+00 -0.0657 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13839E-03 -3.8589 0.11845E-03 -3.9265 0.85589E+00 -0.0676 4 SO4-- 0.12094E-04 -4.9174 0.69076E-05 -5.1607 0.57115E+00 -0.2432 5 HCO3- 0.56524E-05 -5.2478 0.48430E-05 -5.3149 0.85680E+00 -0.0671 6 HS- 0.13556E-04 -4.8679 0.11604E-04 -4.9354 0.85598E+00 -0.0675 7 Al+++ 0.58038E-28 -28.2363 0.16669E-28 -28.7781 0.28721E+00 -0.5418 8 H4SiO4 0.59097E-03 -3.2284 0.59097E-03 -3.2284 0.10000E+01 0.0000 9 Ca++ 0.69487E-07 -7.1581 0.39476E-07 -7.4037 0.56810E+00 -0.2456 10 Mg++ 0.22093E-10 -10.6557 0.12509E-10 -10.9028 0.56620E+00 -0.2470 11 Fe++ 0.82370E-13 -13.0842 0.46675E-13 -13.3309 0.56665E+00 -0.2467 12 K+ 0.10605E-03 -3.9745 0.90882E-04 -4.0415 0.85696E+00 -0.0670 13 Na+ 0.13451E-01 -1.8713 0.11511E-01 -1.9389 0.85578E+00 -0.0676 14 Mn++ 0.17492E-10 -10.7572 0.99179E-11 -11.0036 0.56699E+00 -0.2464 15 HPO4-- 0.15560E-06 -6.8080 0.88882E-07 -7.0512 0.57121E+00 -0.2432 16 HSiO3- 0.65160E-02 -2.1860 0.55769E-02 -2.2536 0.85589E+00 -0.0676 17 Ca(HSiO3)+ 0.58497E-08 -8.2329 0.50137E-08 -8.2998 0.85709E+00 -0.0670 18 Mg(HSiO3)+ 0.23069E-11 -11.6370 0.19772E-11 -11.7039 0.85709E+00 -0.0670 19 NaHSiO3,aq 0.10383E-02 -2.9837 0.10383E-02 -2.9837 0.10000E+01 0.0000 20 AlO+ 0.27025E-15 -15.5682 0.23163E-15 -15.6352 0.85709E+00 -0.0670 22 HAlO2,aq 0.46620E-09 -9.3314 0.46620E-09 -9.3314 0.10000E+01 0.0000 23 AlO2- 0.12202E-04 -4.9136 0.10430E-04 -4.9817 0.85475E+00 -0.0682 24 CH4,aq 0.79208E-11 -11.1012 0.79027E-11 -11.1022 0.99770E+00 -0.0010 29 CO,aq 0.35379E-17 -17.4512 0.35379E-17 -17.4512 0.10000E+01 0.0000 30 CO2,aq 0.10263E-08 -8.9887 0.10239E-08 -8.9897 0.99770E+00 -0.0010 31 CO3-2 0.74969E-05 -5.1251 0.42752E-05 -5.3690 0.57026E+00 -0.2439 32 CaCO3,aq 0.21162E-08 -8.6745 0.21162E-08 -8.6745 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.56938E-11 -11.2446 0.48801E-11 -11.3116 0.85709E+00 -0.0670 34 CaCl+ 0.88287E-11 -11.0541 0.75670E-11 -11.1211 0.85709E+00 -0.0670 35 CaCl2,aq 0.21294E-15 -15.6717 0.21294E-15 -15.6717 0.10000E+01 0.0000 36 CaOH+ 0.33175E-07 -7.4792 0.28434E-07 -7.5462 0.85709E+00 -0.0670 37 CaSO4,aq 0.86590E-10 -10.0625 0.86590E-10 -10.0625 0.10000E+01 0.0000 38 HCl,aq 0.21476E-14 -14.6680 0.21476E-14 -14.6680 0.10000E+01 0.0000 43 FeCl+ 0.10210E-16 -16.9910 0.87508E-17 -17.0580 0.85709E+00 -0.0670 46 FeO,aq 0.18529E-09 -9.7321 0.18529E-09 -9.7321 0.10000E+01 0.0000 47 FeOH+ 0.17915E-10 -10.7468 0.15355E-10 -10.8137 0.85709E+00 -0.0670 48 HFeO2- 0.22893E-07 -7.6403 0.19594E-07 -7.7079 0.85589E+00 -0.0676 49 FeO+ 0.11522E-15 -15.9385 0.98753E-16 -16.0054 0.85709E+00 -0.0670 51 FeO2- 0.24115E-08 -8.6177 0.20640E-08 -8.6853 0.85589E+00 -0.0676 52 HFeO2,aq 0.25974E-10 -10.5855 0.25974E-10 -10.5855 0.10000E+01 0.0000 53 H2,aq 0.13786E-06 -6.8605 0.13755E-06 -6.8615 0.99770E+00 -0.0010 54 KCl,aq 0.19511E-09 -9.7097 0.19511E-09 -9.7097 0.10000E+01 0.0000 55 KHSO4,aq 0.17563E-18 -18.7554 0.17563E-18 -18.7554 0.10000E+01 0.0000 56 KOH,aq 0.39225E-06 -6.4064 0.39225E-06 -6.4064 0.10000E+01 0.0000 57 KSO4- 0.11382E-07 -7.9438 0.97417E-08 -8.0114 0.85589E+00 -0.0676 58 MgCO3,aq 0.16808E-12 -12.7745 0.16808E-12 -12.7745 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.18436E-14 -14.7343 0.15801E-14 -14.8013 0.85709E+00 -0.0670 60 MgCl+ 0.25356E-14 -14.5959 0.21732E-14 -14.6629 0.85709E+00 -0.0670 61 MgOH+ 0.58170E-10 -10.2353 0.49857E-10 -10.3023 0.85709E+00 -0.0670 63 MnO,aq 0.10491E-08 -8.9792 0.10491E-08 -8.9792 0.10000E+01 0.0000 64 MnOH+ 0.35364E-09 -9.4514 0.30310E-09 -9.5184 0.85709E+00 -0.0670 65 MnO2-2 0.62362E-11 -11.2051 0.35563E-11 -11.4490 0.57026E+00 -0.2439 66 HMnO2- 0.90071E-10 -10.0454 0.77091E-10 -10.1130 0.85589E+00 -0.0676 69 MnCl+ 0.84403E-14 -14.0736 0.72341E-14 -14.1406 0.85709E+00 -0.0670 70 MnSO4,aq 0.19778E-13 -13.7038 0.19778E-13 -13.7038 0.10000E+01 0.0000 71 NaCl,aq 0.45185E-06 -6.3450 0.45185E-06 -6.3450 0.10000E+01 0.0000 72 NaOH,aq 0.49983E-04 -4.3012 0.49983E-04 -4.3012 0.10000E+01 0.0000 74 OH- 0.68316E-02 -2.1655 0.58393E-02 -2.2336 0.85475E+00 -0.0682 79 HPO3-2 0.66809E-16 -16.1752 0.38099E-16 -16.4191 0.57026E+00 -0.2439 82 H3PO4,aq 0.60860E-17 -17.2157 0.60860E-17 -17.2157 0.10000E+01 0.0000 83 H2PO4- 0.18942E-09 -9.7226 0.16223E-09 -9.7899 0.85648E+00 -0.0673 84 PO4-3 0.24618E-08 -8.6087 0.73291E-09 -9.1349 0.29771E+00 -0.5262 88 HP2O7-3 0.14492E-16 -16.8389 0.41648E-17 -17.3804 0.28739E+00 -0.5415 89 P2O7-4 0.89264E-16 -16.0493 0.10056E-16 -16.9976 0.11265E+00 -0.9483 90 H2S,aq 0.35567E-08 -8.4490 0.35485E-08 -8.4500 0.99770E+00 -0.0010 91 S2-2 0.38037E-13 -13.4198 0.21691E-13 -13.6637 0.57026E+00 -0.2439 97 SO3-2 0.21424E-12 -12.6691 0.12347E-12 -12.9084 0.57630E+00 -0.2394 98 HSO3- 0.89371E-15 -15.0488 0.76491E-15 -15.1164 0.85589E+00 -0.0676 99 HSO4- 0.76797E-12 -12.1147 0.65868E-12 -12.1813 0.85769E+00 -0.0667 101 S2O3-2 0.50491E-15 -15.2968 0.28793E-15 -15.5407 0.57026E+00 -0.2439 Charge balance for all species = -.1619E-12 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.1150964E-09 -.1449266E-01 -.1459167E+02 0.0000 2 H2O 0.1000000E+01 0.5550760E+02 0.9988868E+06 0.0000 3 Cl- 0.1383928E-03 0.1388449E-03 0.4917057E+01 6.0781 4 SO4-- 0.1209421E-04 0.1207151E-04 0.1158334E+01 14.8485 5 HCO3- 0.5652395E-05 0.1315248E-04 0.8016454E+00 4.6897 6 HS- 0.1355619E-04 0.1359391E-04 0.4490836E+00 5.0692 7 Al+++ 0.5803825E-28 0.1220262E-04 0.3288832E+00 1.2357 8 H4SiO4 0.5909704E-03 0.8145215E-02 0.7820200E+03 -3.2284 9 Ca++ 0.6948746E-07 0.1107294E-06 0.4432936E-02 12.6055 10 Mg++ 0.2209296E-10 0.8274273E-10 0.2009430E-05 9.1064 11 Fe++ 0.8236963E-13 0.2553380E-07 0.1424418E-02 6.6783 12 K+ 0.1060525E-03 0.1064563E-03 0.4158079E+01 5.9631 13 Na+ 0.1345066E-01 0.1453937E-01 0.3338897E+03 8.0657 14 Mn++ 0.1749199E-10 0.1516569E-08 0.8322566E-04 9.0056 15 HPO4-- 0.1556030E-06 0.1582543E-06 0.1517239E-01 12.9580 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.8610132E+00 -.1440177E-01 -.8466114E+00 0.0000000E+00 2 H2O 0.5485642E+02 0.5515950E+02 -.3030835E+00 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.1466574E-02 0.1199581E-04 0.1454578E-02 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.1441070E-02 0.1350866E-04 -.1454578E-02 0.0000000E+00 7 Al+++ 0.1695553E+00 0.1212610E-04 0.1695432E+00 0.0000000E+00 8 H4SiO4 0.5414543E+00 0.8094135E-02 0.5333602E+00 0.0000000E+00 9 Ca++ 0.5982074E-01 0.1100350E-06 0.5982063E-01 0.0000000E+00 10 Mg++ 0.4126905E-01 0.8222383E-10 0.4126905E-01 0.0000000E+00 11 Fe++ 0.3707573E-01 0.2537367E-07 0.3707571E-01 0.0000000E+00 12 K+ 0.1104013E-01 0.1057887E-03 0.1093434E-01 0.0000000E+00 13 Na+ 0.6543148E-01 0.1444819E-01 0.5098330E-01 0.0000000E+00 14 Mn++ 0.9015897E-03 0.1507058E-08 0.9015881E-03 0.0000000E+00 15 HPO4-- 0.3077081E-03 0.1572618E-06 0.3075508E-03 0.0000000E+00 Chg. balance for solid moles: 0.7102E-16 Mass of aqueous solution: 0.994822E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 51.9990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 0.5098E-01 -1.293 13.37 1.126 23.55 5.132 andradite 0.5818E-02 -2.235 2.957 0.471 5.209 0.7682 grossular 0.5491E-03 -3.260 0.2473 -0.607 0.4357 0.6882E-01 apatite-OH 0.1025E-03 -3.989 0.5150E-01 -1.288 0.9072E-01 0.1636E-01 clinochlore 0.8254E-02 -2.083 4.588 0.662 8.082 1.745 daphnite 0.3231E-02 -2.491 2.306 0.363 4.061 0.6986 chlorite-Mn 0.1803E-03 -3.744 0.1278 -0.893 0.2252 0.4074E-01 microcline 0.1001E-01 -2.000 2.785 0.445 4.906 1.088 stilbite 0.4021E-01 -1.396 28.33 1.452 49.91 13.22 stilpnomelane-Fe 0.1857E-02 -2.731 2.001 0.301 3.526 0.6913 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.9138E+00 0.9138E+00 1.0000 -0.039 grossular 0.8623E-01 0.8623E-01 1.0000 -1.064 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.7075E+00 0.7075E+00 1.0000 -0.150 daphnite 0.2770E+00 0.2770E+00 1.0000 -0.558 chlorite-Mn 0.1546E-01 0.1546E-01 1.0000 -1.811 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 56.765841 g Volume = 23.464463 cm3 Porosity: -7.6371% V(tot) - V(min): -.16649E+01 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 51.9990000 g log = 1.7160 Original solution: 1000.0103000 g Original solution / Rock added: 19.23 (Water/Rock Ratio), log = 1.2840 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0205 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9998E+00 0.9860 0.1006E+01 0.1020E+01 CO2,gas 0.1066E-06 1.0071 0.1095E-06 0.1088E-06 CH4,gas 0.1126E-07 1.0125 0.1163E-07 0.1149E-07 H2,gas 0.1769E-03 1.0005 0.1806E-03 0.1805E-03 H2S,gas 0.9597E-07 0.9960 0.9755E-07 0.9793E-07 S2,gas 0.1073E-25 1.0000 0.1095E-25 0.1095E-25 CO,gas 0.5166E-14 1.0000 0.5272E-14 0.5272E-14 SO3,gas 0.2506E-40 1.0000 0.2557E-40 0.2557E-40 SO2,gas 0.1760E-21 1.0000 0.1796E-21 0.1796E-21 HCl,gas 0.3714E-17 1.0000 0.3790E-17 0.3790E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 16 albite -0.38 -0.38 0.00 0.000 -0.94784E-12 22 andradite 39.01 39.01 0.00 0.000 -0.24265E-10 23 grossular 32.73 32.73 0.00 0.000 -0.12132E-10 32 apatite-OH -18.15 -18.15 0.00 0.000 0.60662E-11 46 clinochlore 39.07 39.07 0.00 0.000 0.12132E-10 47 daphnite 28.97 28.97 0.00 0.000 0.30331E-10 48 chlorite-Mn 46.87 46.87 0.00 0.000 0.12132E-10 116 microcline -2.49 -2.49 0.00 0.000 0.15165E-11 163 stilbite -7.52 -7.52 0.00 0.000 0.15165E-10 164 stilpnomelane-Fe 13.02 13.02 0.00 0.000 0.21232E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -15.32 -8.66 -2.886 0.14786E+05 -6.960 3 CH4,gas 4.54 -5.09 -9.63 -2.408 0.16449E+05 -7.934 4 H2,gas 8.00 2.56 -5.44 -3.110 0.92926E+04 -3.743 5 H2S,gas -6.23 -14.94 -8.71 -4.355 0.14872E+05 -7.011 6 S2,gas -7.34 -34.99 -27.66 -4.255 0.47228E+05 -25.960 7 CO,gas 3.21 -12.76 -15.98 -4.916 0.27280E+05 -14.278 8 SO3,gas 17.12 -25.17 -42.29 -10.573 0.72211E+05 -40.592 9 SO2,gas 0.83 -22.61 -23.44 -6.252 0.40031E+05 -21.746 10 HCl,gas 5.19 -13.93 -19.12 -9.560 0.32648E+05 -17.421 11 acmite 7.71 7.01 -0.70 -0.073 0.11975E+04 15 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 19 spessartine 24.46 19.80 -4.65 -0.233 0.79471E+04 20 analcite 3.32 2.84 -0.48 -0.053 0.81497E+03 26 annite 20.12 17.55 -2.58 -0.143 0.43968E+04 27 phlogopite 27.06 24.83 -2.23 -0.124 0.38107E+04 29 anorthite 12.71 8.62 -4.09 -0.315 0.69839E+04 35 aragonite 0.97 -2.71 -3.68 -1.227 0.62843E+04 36 brucite 12.57 9.11 -3.46 -0.692 0.59115E+04 37 calcite 0.81 -2.71 -3.53 -1.175 0.60201E+04 38 carnegieite-low 9.02 6.07 -2.95 -0.421 0.50375E+04 39 carnegieite-high 10.09 6.07 -4.02 -0.574 0.68645E+04 40 carpholite-Mg 8.58 5.12 -3.46 -0.231 0.59097E+04 41 carpholite-Fe 6.71 2.69 -4.02 -0.268 0.68636E+04 42 celadonite 5.34 3.39 -1.95 -0.115 0.33297E+04 43 celadonite-Fe 3.88 0.96 -2.91 -0.171 0.49741E+04 44 chrysotile 23.89 20.86 -3.03 -0.252 0.51736E+04 50 chloritoid-Mg 13.20 8.35 -4.85 -0.323 0.82783E+04 51 chloritoid-Fe 9.17 5.92 -3.25 -0.217 0.55532E+04 52 chloritoid-Mn 11.40 8.25 -3.15 -0.210 0.53827E+04 54 coesite -2.38 -3.23 -0.85 -0.284 0.14554E+04 61 cristobalite -2.56 -3.23 -0.67 -0.223 0.11408E+04 63 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71234E+04 65 diaspore 2.87 1.24 -1.64 -0.273 0.27968E+04 67 diopside 16.18 15.26 -0.93 -0.093 0.15816E+04 68 hedenbergite 14.21 12.83 -1.38 -0.138 0.23586E+04 75 epidote 24.67 23.40 -1.27 -0.062 0.21738E+04 76 clinozoisite 22.81 19.23 -3.57 -0.162 0.61009E+04 77 epidote-Fe 29.84 27.56 -2.28 -0.118 0.38934E+04 78 fayalite 14.05 10.13 -3.92 -0.560 0.66892E+04 79 ferrosilite 11.15 6.90 -4.25 -0.425 0.72563E+04 83 gibbsite 4.08 1.24 -2.84 -0.406 0.48553E+04 84 glaucophane 22.97 20.09 -2.88 -0.078 0.49177E+04 85 glaucophane-Fe 17.28 12.81 -4.47 -0.121 0.76248E+04 87 greenalite 16.14 13.58 -2.56 -0.213 0.43737E+04 90 hematite 12.57 10.80 -1.77 -0.214 0.30172E+04 91 heulandite -5.83 -7.52 -1.69 -0.077 0.28938E+04 95 jadeite 4.22 2.84 -1.37 -0.137 0.23405E+04 96 julgoldite 70.43 66.01 -4.42 -0.115 0.75480E+04 97 kalsilite 7.58 3.97 -3.61 -0.516 0.61700E+04 98 kaolinite -1.33 -3.99 -2.65 -0.241 0.45293E+04 101 laumontite 2.88 2.16 -0.72 -0.048 0.12297E+04 102 lawsonite 9.62 8.62 -1.00 -0.066 0.17006E+04 103 leucite 4.12 0.74 -3.38 -0.338 0.57660E+04 105 lizardite 23.24 20.86 -2.38 -0.198 0.40662E+04 107 magnetite 20.09 17.48 -2.61 -0.213 0.44565E+04 108 minnesotaite 10.39 7.12 -3.27 -0.192 0.55783E+04 120 muscovite 2.58 -0.02 -2.60 -0.153 0.44351E+04 121 paragonite 4.24 2.09 -2.15 -0.127 0.36742E+04 122 nepheline 8.34 6.07 -2.27 -0.324 0.38699E+04 128 periclase-Fe 11.63 6.68 -4.95 -1.237 0.84491E+04 134 phlogopite-Na 29.65 26.94 -2.71 -0.151 0.46296E+04 136 prehnite 19.37 18.00 -1.37 -0.081 0.23472E+04 137 prehnite-Fe 22.50 22.16 -0.34 -0.020 0.57509E+03 138 pumpellyite-Fe 46.27 43.91 -2.36 -0.052 0.40313E+04 139 pumpellyite-Mg 48.99 46.34 -2.66 -0.059 0.45389E+04 142 pyrite -21.25 -25.76 -4.51 -1.062 0.77045E+04 143 pyrrhotite -4.26 -8.26 -4.00 -1.334 0.68323E+04 144 pyrrhotiteFe0.875 -6.02 -9.41 -3.40 -1.249 0.57997E+04 145 pyroxmangite 7.40 5.78 -1.62 -0.324 0.27686E+04 146 pyrophyllite -6.18 -10.44 -4.27 -0.267 0.72849E+04 147 quartz -2.99 -3.23 -0.24 -0.080 0.40808E+03 152 rhodonite 7.45 5.78 -1.67 -0.334 0.28489E+04 153 sanidine -1.28 -2.49 -1.21 -0.093 0.20677E+04 165 stilpnomelane-Mg 27.44 25.16 -2.28 -0.068 0.38994E+04 171 talc 16.49 14.41 -2.09 -0.123 0.35610E+04 174 tephroite 18.09 14.78 -3.30 -0.472 0.56397E+04 178 tridymite -2.63 -3.23 -0.60 -0.201 0.10281E+04 179 tremolite 47.87 44.92 -2.95 -0.080 0.50430E+04 181 troilite-low -4.41 -8.26 -3.85 -1.284 0.65751E+04 187 wairakite 3.95 2.16 -1.79 -0.105 0.30516E+04 188 walstromite 11.51 9.38 -2.13 -0.426 0.36405E+04 189 wollastonite 10.46 9.38 -1.08 -0.217 0.18510E+04 190 pseudo-wollastonite 11.00 9.38 -1.62 -0.325 0.27708E+04 191 zoisite 22.85 19.23 -3.62 -0.164 0.61750E+04 192 akaganeite 7.75 5.40 -2.36 -0.509 0.40211E+04 197 beidellite-Na -1.34 -6.31 -4.97 -0.304 0.84779E+04 199 chalcedony -2.80 -3.23 -0.43 -0.142 0.72738E+03 201 montmorillonite-Ca -2.29 -5.77 -3.47 -0.215 0.59323E+04 202 montmorillonite-K -2.24 -5.88 -3.64 -0.223 0.62159E+04 203 montmorillonite-Mg -2.48 -6.34 -3.86 -0.239 0.65951E+04 204 montmorillonite-Na -2.04 -5.18 -3.15 -0.193 0.53708E+04 205 nontronite-Ca 3.21 1.44 -1.78 -0.115 0.30326E+04 206 nontronite-H 2.53 -0.64 -3.17 -0.213 0.54198E+04 207 nontronite-K 3.34 1.33 -2.01 -0.129 0.34394E+04 208 nontronite-Mg 3.07 0.86 -2.21 -0.144 0.37795E+04 209 nontronite-Na 3.52 2.02 -1.50 -0.096 0.25603E+04 224 tobermorite 9.82 7.27 -2.55 -0.696 0.43559E+04 230 alabandite -0.98 -5.93 -4.96 -1.652 0.84631E+04 233 boehmite 4.41 1.24 -3.17 -0.528 0.54137E+04 235 ferrous-oxide 9.81 6.68 -3.13 -0.783 0.53500E+04 240 silica-amorphous -2.09 -3.23 -1.14 -0.379 0.19416E+04 242 an20ab80 2.02 1.42 -0.60 -0.046 0.10259E+04 243 an25ab75 2.65 1.87 -0.78 -0.060 0.13294E+04 244 an30ab70 3.28 2.32 -0.96 -0.074 0.16424E+04 245 tr.625ac.25prg.125 45.16 43.02 -2.14 -0.058 0.36604E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 2.0000000 g Current total amount of reactant added: 51.9990000 g New total amount of reactant added: 53.9990000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.1494E-12 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 9 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 53.9990000 Water: Moles liquid = 0.5515E+02 kg liquid = 0.9935E+00 Moles total = 0.5483E+02 kg total = 0.9878E+00 Activity = 1.0000 Stoichiometric ionic strength = .7629177E-02 Osmotic coef. = 0.9626 True ionic strength = .1383349E-01 Chg. balance for total moles = -.1494E-12 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.11357E-09 -9.9447 0.97530E-10 -10.0109 0.85878E+00 -0.0661 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13842E-03 -3.8588 0.11834E-03 -3.9269 0.85494E+00 -0.0681 4 SO4-- 0.71354E-05 -5.1466 0.40579E-05 -5.3917 0.56870E+00 -0.2451 5 HCO3- 0.55968E-05 -5.2521 0.47901E-05 -5.3197 0.85587E+00 -0.0676 6 HS- 0.18524E-04 -4.7323 0.15839E-04 -4.8003 0.85503E+00 -0.0680 7 Al+++ 0.52933E-28 -28.2763 0.15054E-28 -28.8223 0.28439E+00 -0.5461 8 H4SiO4 0.59617E-03 -3.2246 0.59617E-03 -3.2246 0.10000E+01 0.0000 9 Ca++ 0.71722E-07 -7.1443 0.40567E-07 -7.3918 0.56561E+00 -0.2475 10 Mg++ 0.22058E-10 -10.6564 0.12434E-10 -10.9054 0.56368E+00 -0.2490 11 Fe++ 0.80887E-13 -13.0921 0.45632E-13 -13.3407 0.56414E+00 -0.2486 12 K+ 0.10810E-03 -3.9662 0.92534E-04 -4.0337 0.85602E+00 -0.0675 13 Na+ 0.13710E-01 -1.8630 0.11720E-01 -1.9311 0.85483E+00 -0.0681 14 Mn++ 0.17464E-10 -10.7579 0.98582E-11 -11.0062 0.56449E+00 -0.2483 15 HPO4-- 0.14649E-06 -6.8342 0.83319E-07 -7.0793 0.56876E+00 -0.2451 16 HSiO3- 0.66761E-02 -2.1755 0.57076E-02 -2.2435 0.85494E+00 -0.0681 17 Ca(HSiO3)+ 0.61589E-08 -8.2105 0.52730E-08 -8.2779 0.85616E+00 -0.0674 18 Mg(HSiO3)+ 0.23493E-11 -11.6291 0.20114E-11 -11.6965 0.85616E+00 -0.0674 19 NaHSiO3,aq 0.10819E-02 -2.9658 0.10819E-02 -2.9658 0.10000E+01 0.0000 20 AlO+ 0.25148E-15 -15.5995 0.21530E-15 -15.6669 0.85616E+00 -0.0674 22 HAlO2,aq 0.43963E-09 -9.3569 0.43963E-09 -9.3569 0.10000E+01 0.0000 23 AlO2- 0.11687E-04 -4.9323 0.99781E-05 -5.0010 0.85379E+00 -0.0686 24 CH4,aq 0.18205E-10 -10.7398 0.18162E-10 -10.7408 0.99766E+00 -0.0010 29 CO,aq 0.42740E-17 -17.3692 0.42740E-17 -17.3692 0.10000E+01 0.0000 30 CO2,aq 0.10006E-08 -8.9997 0.99826E-09 -9.0008 0.99766E+00 -0.0010 31 CO3-2 0.75554E-05 -5.1217 0.42899E-05 -5.3675 0.56780E+00 -0.2458 32 CaCO3,aq 0.21821E-08 -8.6611 0.21821E-08 -8.6611 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.57935E-11 -11.2371 0.49602E-11 -11.3045 0.85616E+00 -0.0674 34 CaCl+ 0.90740E-11 -11.0422 0.77688E-11 -11.1096 0.85616E+00 -0.0674 35 CaCl2,aq 0.21842E-15 -15.6607 0.21842E-15 -15.6607 0.10000E+01 0.0000 36 CaOH+ 0.34624E-07 -7.4606 0.29644E-07 -7.5281 0.85616E+00 -0.0674 37 CaSO4,aq 0.52272E-10 -10.2817 0.52272E-10 -10.2817 0.10000E+01 0.0000 38 HCl,aq 0.21149E-14 -14.6747 0.21149E-14 -14.6747 0.10000E+01 0.0000 43 FeCl+ 0.99833E-17 -17.0007 0.85473E-17 -17.0682 0.85616E+00 -0.0674 46 FeO,aq 0.18645E-09 -9.7294 0.18645E-09 -9.7294 0.10000E+01 0.0000 47 FeOH+ 0.17789E-10 -10.7499 0.15230E-10 -10.8173 0.85616E+00 -0.0674 48 HFeO2- 0.23396E-07 -7.6309 0.20002E-07 -7.6989 0.85494E+00 -0.0681 49 FeO+ 0.10278E-15 -15.9881 0.87992E-16 -16.0556 0.85616E+00 -0.0674 51 FeO2- 0.22140E-08 -8.6548 0.18928E-08 -8.7229 0.85494E+00 -0.0681 52 HFeO2,aq 0.23480E-10 -10.6293 0.23480E-10 -10.6293 0.10000E+01 0.0000 53 H2,aq 0.17083E-06 -6.7674 0.17043E-06 -6.7684 0.99766E+00 -0.0010 54 KCl,aq 0.19846E-09 -9.7023 0.19846E-09 -9.7023 0.10000E+01 0.0000 55 KHSO4,aq 0.10354E-18 -18.9849 0.10354E-18 -18.9849 0.10000E+01 0.0000 56 KOH,aq 0.40518E-06 -6.3924 0.40518E-06 -6.3924 0.10000E+01 0.0000 57 KSO4- 0.68153E-08 -8.1665 0.58267E-08 -8.2346 0.85494E+00 -0.0681 58 MgCO3,aq 0.16764E-12 -12.7756 0.16764E-12 -12.7756 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.18145E-14 -14.7413 0.15535E-14 -14.8087 0.85616E+00 -0.0674 60 MgCl+ 0.25207E-14 -14.5985 0.21581E-14 -14.6659 0.85616E+00 -0.0674 61 MgOH+ 0.58723E-10 -10.2312 0.50276E-10 -10.2986 0.85616E+00 -0.0674 63 MnO,aq 0.10733E-08 -8.9693 0.10733E-08 -8.9693 0.10000E+01 0.0000 64 MnOH+ 0.35700E-09 -9.4473 0.30565E-09 -9.5148 0.85616E+00 -0.0674 65 MnO2-2 0.65949E-11 -11.1808 0.37446E-11 -11.4266 0.56780E+00 -0.2458 66 HMnO2- 0.93588E-10 -10.0288 0.80012E-10 -10.0968 0.85494E+00 -0.0681 69 MnCl+ 0.83907E-14 -14.0762 0.71838E-14 -14.1436 0.85616E+00 -0.0674 70 MnSO4,aq 0.11549E-13 -13.9375 0.11549E-13 -13.9375 0.10000E+01 0.0000 71 NaCl,aq 0.45963E-06 -6.3376 0.45963E-06 -6.3376 0.10000E+01 0.0000 72 NaOH,aq 0.51630E-04 -4.2871 0.51630E-04 -4.2871 0.10000E+01 0.0000 74 OH- 0.69386E-02 -2.1587 0.59241E-02 -2.2274 0.85379E+00 -0.0686 79 HPO3-2 0.77938E-16 -16.1083 0.44253E-16 -16.3541 0.56780E+00 -0.2458 81 H2PO3- 0.10123E-19 -19.9947 0.86548E-20 -20.0627 0.85494E+00 -0.0681 82 H3PO4,aq 0.55430E-17 -17.2563 0.55430E-17 -17.2563 0.10000E+01 0.0000 83 H2PO4- 0.17522E-09 -9.7564 0.14990E-09 -9.8242 0.85554E+00 -0.0678 84 PO4-3 0.23631E-08 -8.6265 0.69700E-09 -9.1568 0.29496E+00 -0.5302 88 HP2O7-3 0.12676E-16 -16.8970 0.36073E-17 -17.4428 0.28458E+00 -0.5458 89 P2O7-4 0.79798E-16 -16.0980 0.88360E-17 -17.0537 0.11073E+00 -0.9557 90 H2S,aq 0.47855E-08 -8.3201 0.47743E-08 -8.3211 0.99766E+00 -0.0010 91 S2-2 0.57442E-13 -13.2408 0.32615E-13 -13.4866 0.56780E+00 -0.2458 97 SO3-2 0.15660E-12 -12.8052 0.89872E-13 -13.0464 0.57390E+00 -0.2412 98 HSO3- 0.64193E-15 -15.1925 0.54881E-15 -15.2606 0.85494E+00 -0.0681 99 HSO4- 0.44516E-12 -12.3515 0.38140E-12 -12.4186 0.85677E+00 -0.0671 101 S2O3-2 0.40080E-15 -15.3971 0.22757E-15 -15.6429 0.56780E+00 -0.2458 Charge balance for all species = -.1536E-12 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.1135679E-09 -.1480304E-01 -.1490381E+02 0.0000 2 H2O 0.1000000E+01 0.5550751E+02 0.9988604E+06 0.0000 3 Cl- 0.1384162E-03 0.1388761E-03 0.4918039E+01 6.0840 4 SO4-- 0.7135368E-05 0.7099789E-05 0.6812505E+00 14.6300 5 HCO3- 0.5596814E-05 0.1315544E-04 0.8018055E+00 4.6912 6 HS- 0.1852416E-04 0.1857140E-04 0.6135029E+00 5.2106 7 Al+++ 0.5293346E-28 0.1168725E-04 0.3149850E+00 1.2102 8 H4SiO4 0.5961685E-03 0.8354162E-02 0.8020611E+03 -3.2246 9 Ca++ 0.7172215E-07 0.1147544E-06 0.4593959E-02 12.6299 10 Mg++ 0.2205786E-10 0.8330235E-10 0.2022970E-05 9.1163 11 Fe++ 0.8088723E-13 0.2583794E-07 0.1441349E-02 6.6810 12 K+ 0.1080972E-03 0.1085094E-03 0.4238164E+01 5.9772 13 Na+ 0.1371029E-01 0.1484429E-01 0.3408836E+03 8.0798 14 Mn++ 0.1746382E-10 0.1547941E-08 0.8494520E-04 9.0155 15 HPO4-- 0.1464927E-06 0.1490310E-06 0.1428777E-01 12.9425 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.8941302E+00 -.1470691E-01 -.8794233E+00 0.0000000E+00 2 H2O 0.5483135E+02 0.5514703E+02 -.3156745E+00 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.1522001E-02 0.7053681E-05 0.1514947E-02 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.1496496E-02 0.1845079E-04 -.1514947E-02 0.0000000E+00 7 Al+++ 0.1760768E+00 0.1161135E-04 0.1760652E+00 0.0000000E+00 8 H4SiO4 0.5622799E+00 0.8299908E-02 0.5539800E+00 0.0000000E+00 9 Ca++ 0.6212102E-01 0.1140092E-06 0.6212091E-01 0.0000000E+00 10 Mg++ 0.4285635E-01 0.8276136E-10 0.4285635E-01 0.0000000E+00 11 Fe++ 0.3850175E-01 0.2567014E-07 0.3850173E-01 0.0000000E+00 12 K+ 0.1146476E-01 0.1078047E-03 0.1135695E-01 0.0000000E+00 13 Na+ 0.6794197E-01 0.1474788E-01 0.5319409E-01 0.0000000E+00 14 Mn++ 0.9362668E-03 0.1537888E-08 0.9362653E-03 0.0000000E+00 15 HPO4-- 0.3195432E-03 0.1480632E-06 0.3193952E-03 0.0000000E+00 Chg. balance for solid moles: 0.8825E-16 Mass of aqueous solution: 0.994624E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 53.9990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 0.5319E-01 -1.274 13.95 1.145 23.66 5.355 andradite 0.6060E-02 -2.218 3.079 0.488 5.224 0.8001 grossular 0.5966E-03 -3.224 0.2687 -0.571 0.4559 0.7477E-01 apatite-OH 0.1065E-03 -3.973 0.5348E-01 -1.272 0.9072E-01 0.1699E-01 clinochlore 0.8571E-02 -2.067 4.764 0.678 8.082 1.812 daphnite 0.3300E-02 -2.481 2.355 0.372 3.995 0.7136 chlorite-Mn 0.1873E-03 -3.728 0.1328 -0.877 0.2252 0.4231E-01 microcline 0.1037E-01 -1.984 2.886 0.460 4.896 1.127 stilbite 0.4162E-01 -1.381 29.33 1.467 49.76 13.68 stilpnomelane-Fe 0.1976E-02 -2.704 2.130 0.328 3.614 0.7358 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.9104E+00 0.9104E+00 1.0000 -0.041 grossular 0.8962E-01 0.8962E-01 1.0000 -1.048 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.7108E+00 0.7108E+00 1.0000 -0.148 daphnite 0.2737E+00 0.2737E+00 1.0000 -0.563 chlorite-Mn 0.1553E-01 0.1553E-01 1.0000 -1.809 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 58.948365 g Volume = 24.357701 cm3 Porosity: -7.7793% V(tot) - V(min): -.17581E+01 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 53.9990000 g log = 1.7324 Original solution: 1000.0103000 g Original solution / Rock added: 18.52 (Water/Rock Ratio), log = 1.2676 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0205 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9998E+00 0.9859 0.1006E+01 0.1020E+01 CO2,gas 0.1039E-06 1.0071 0.1068E-06 0.1061E-06 CH4,gas 0.2587E-07 1.0125 0.2673E-07 0.2640E-07 H2,gas 0.2191E-03 1.0005 0.2238E-03 0.2236E-03 H2S,gas 0.1291E-06 0.9960 0.1312E-06 0.1318E-06 S2,gas 0.1265E-25 1.0000 0.1291E-25 0.1291E-25 CO,gas 0.6241E-14 1.0000 0.6369E-14 0.6369E-14 SO3,gas 0.1430E-40 1.0000 0.1459E-40 0.1459E-40 SO2,gas 0.1245E-21 1.0000 0.1270E-21 0.1270E-21 HCl,gas 0.3657E-17 1.0000 0.3732E-17 0.3732E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 16 albite -0.38 -0.38 0.00 0.000 0.11184E-10 22 andradite 39.01 39.01 0.00 0.000 0.12132E-10 23 grossular 32.73 32.73 0.00 0.000 0.00000E+00 32 apatite-OH -18.15 -18.15 0.00 0.000 0.12132E-10 46 clinochlore 39.07 39.07 0.00 0.000 0.60662E-10 47 daphnite 28.97 28.97 0.00 0.000 -0.12132E-10 48 chlorite-Mn 46.87 46.87 0.00 0.000 0.72794E-10 116 microcline -2.49 -2.49 0.00 0.000 0.13649E-10 163 stilbite -7.52 -7.52 0.00 0.000 0.15165E-10 164 stilpnomelane-Fe 13.02 13.02 0.00 0.000 -0.27298E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -15.33 -8.67 -2.890 0.14804E+05 -6.971 3 CH4,gas 4.54 -4.73 -9.27 -2.318 0.15832E+05 -7.573 4 H2,gas 8.00 2.65 -5.35 -3.057 0.91336E+04 -3.650 5 H2S,gas -6.23 -14.81 -8.58 -4.290 0.14652E+05 -6.882 6 S2,gas -7.34 -34.92 -27.59 -4.244 0.47106E+05 -25.889 7 CO,gas 3.21 -12.68 -15.89 -4.891 0.27140E+05 -14.196 8 SO3,gas 17.12 -25.41 -42.53 -10.634 0.72627E+05 -40.836 9 SO2,gas 0.83 -22.76 -23.60 -6.292 0.40288E+05 -21.896 10 HCl,gas 5.19 -13.94 -19.13 -9.564 0.32659E+05 -17.428 11 acmite 7.71 6.99 -0.72 -0.075 0.12353E+04 15 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 19 spessartine 24.46 19.79 -4.66 -0.233 0.79640E+04 20 analcite 3.32 2.84 -0.48 -0.053 0.82146E+03 26 annite 20.12 17.56 -2.57 -0.143 0.43829E+04 27 phlogopite 27.06 24.86 -2.20 -0.122 0.37601E+04 29 anorthite 12.71 8.60 -4.11 -0.316 0.70164E+04 35 aragonite 0.97 -2.70 -3.67 -1.222 0.62615E+04 36 brucite 12.57 9.12 -3.45 -0.690 0.58946E+04 37 calcite 0.81 -2.70 -3.51 -1.171 0.59973E+04 38 carnegieite-low 9.02 6.07 -2.96 -0.423 0.50505E+04 39 carnegieite-high 10.09 6.07 -4.03 -0.575 0.68775E+04 40 carpholite-Mg 8.58 5.09 -3.49 -0.233 0.59669E+04 41 carpholite-Fe 6.71 2.65 -4.06 -0.271 0.69331E+04 42 celadonite 5.34 3.41 -1.94 -0.114 0.33064E+04 43 celadonite-Fe 3.88 0.97 -2.91 -0.171 0.49630E+04 44 chrysotile 23.89 20.90 -2.99 -0.249 0.51099E+04 50 chloritoid-Mg 13.20 8.31 -4.89 -0.326 0.83419E+04 51 chloritoid-Fe 9.17 5.88 -3.30 -0.220 0.56292E+04 52 chloritoid-Mn 11.40 8.21 -3.19 -0.213 0.54463E+04 54 coesite -2.38 -3.22 -0.85 -0.283 0.14489E+04 61 cristobalite -2.56 -3.22 -0.66 -0.221 0.11343E+04 63 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71234E+04 65 diaspore 2.87 1.21 -1.66 -0.277 0.28403E+04 67 diopside 16.18 15.30 -0.88 -0.088 0.15101E+04 68 hedenbergite 14.21 12.86 -1.35 -0.135 0.22994E+04 75 epidote 24.67 23.36 -1.31 -0.063 0.22331E+04 76 clinozoisite 22.81 19.22 -3.59 -0.163 0.61289E+04 77 epidote-Fe 29.84 27.51 -2.33 -0.121 0.39840E+04 78 fayalite 14.05 10.14 -3.91 -0.558 0.66734E+04 79 ferrosilite 11.15 6.91 -4.24 -0.424 0.72341E+04 83 gibbsite 4.08 1.21 -2.87 -0.410 0.48989E+04 84 glaucophane 22.97 20.13 -2.84 -0.077 0.48541E+04 85 glaucophane-Fe 17.28 12.83 -4.45 -0.120 0.75980E+04 87 greenalite 16.14 13.59 -2.55 -0.212 0.43469E+04 90 hematite 12.57 10.71 -1.85 -0.225 0.31670E+04 91 heulandite -5.83 -7.52 -1.69 -0.077 0.28938E+04 95 jadeite 4.22 2.84 -1.37 -0.137 0.23469E+04 96 julgoldite 70.43 65.96 -4.47 -0.116 0.76330E+04 97 kalsilite 7.58 3.96 -3.62 -0.517 0.61830E+04 98 kaolinite -1.33 -4.03 -2.70 -0.245 0.46034E+04 101 laumontite 2.88 2.15 -0.73 -0.049 0.12491E+04 102 lawsonite 9.62 8.60 -1.01 -0.068 0.17330E+04 103 leucite 4.12 0.74 -3.38 -0.338 0.57725E+04 105 lizardite 23.24 20.90 -2.34 -0.195 0.40026E+04 107 magnetite 20.09 17.39 -2.69 -0.220 0.46016E+04 108 minnesotaite 10.39 7.14 -3.24 -0.191 0.55384E+04 120 muscovite 2.58 -0.07 -2.65 -0.156 0.45222E+04 121 paragonite 4.24 2.04 -2.20 -0.130 0.37613E+04 122 nepheline 8.34 6.07 -2.27 -0.325 0.38829E+04 128 periclase-Fe 11.63 6.68 -4.95 -1.236 0.84445E+04 134 phlogopite-Na 29.65 26.97 -2.68 -0.149 0.45789E+04 136 prehnite 19.37 18.01 -1.37 -0.080 0.23316E+04 137 prehnite-Fe 22.50 22.15 -0.35 -0.021 0.59084E+03 138 pumpellyite-Fe 46.27 43.90 -2.37 -0.053 0.40390E+04 139 pumpellyite-Mg 48.99 46.34 -2.66 -0.059 0.45344E+04 142 pyrite -21.25 -25.59 -4.34 -1.022 0.74188E+04 143 pyrrhotite -4.26 -8.13 -3.87 -1.290 0.66076E+04 144 pyrrhotiteFe0.875 -6.02 -9.29 -3.28 -1.205 0.55954E+04 145 pyroxmangite 7.40 5.79 -1.61 -0.322 0.27453E+04 146 pyrophyllite -6.18 -10.48 -4.30 -0.269 0.73460E+04 147 quartz -2.99 -3.22 -0.24 -0.078 0.40159E+03 152 rhodonite 7.45 5.79 -1.65 -0.331 0.28255E+04 153 sanidine -1.28 -2.49 -1.21 -0.093 0.20677E+04 165 stilpnomelane-Mg 27.44 25.19 -2.25 -0.067 0.38380E+04 171 talc 16.49 14.45 -2.04 -0.120 0.34843E+04 174 tephroite 18.09 14.81 -3.28 -0.468 0.55995E+04 178 tridymite -2.63 -3.22 -0.60 -0.199 0.10216E+04 179 tremolite 47.87 45.04 -2.82 -0.076 0.48235E+04 181 troilite-low -4.41 -8.13 -3.72 -1.240 0.63504E+04 187 wairakite 3.95 2.15 -1.80 -0.106 0.30711E+04 188 walstromite 11.51 9.41 -2.10 -0.421 0.35925E+04 189 wollastonite 10.46 9.41 -1.06 -0.211 0.18029E+04 190 pseudo-wollastonite 11.00 9.41 -1.59 -0.319 0.27227E+04 191 zoisite 22.85 19.22 -3.63 -0.165 0.62029E+04 192 akaganeite 7.75 5.36 -2.40 -0.519 0.40960E+04 199 chalcedony -2.80 -3.22 -0.42 -0.141 0.72089E+03 201 montmorillonite-Ca -2.29 -5.79 -3.49 -0.216 0.59666E+04 202 montmorillonite-K -2.24 -5.90 -3.66 -0.224 0.62491E+04 203 montmorillonite-Mg -2.48 -6.36 -3.88 -0.240 0.66335E+04 204 montmorillonite-Na -2.04 -5.20 -3.16 -0.194 0.54040E+04 205 nontronite-Ca 3.21 1.36 -1.85 -0.120 0.31660E+04 206 nontronite-H 2.53 -0.72 -3.26 -0.218 0.55600E+04 207 nontronite-K 3.34 1.25 -2.09 -0.134 0.35718E+04 208 nontronite-Mg 3.07 0.78 -2.29 -0.149 0.39170E+04 209 nontronite-Na 3.52 1.94 -1.58 -0.101 0.26926E+04 224 tobermorite 9.82 7.30 -2.53 -0.689 0.43148E+04 230 alabandite -0.98 -5.80 -4.82 -1.606 0.82262E+04 233 boehmite 4.41 1.21 -3.20 -0.533 0.54572E+04 235 ferrous-oxide 9.81 6.68 -3.13 -0.783 0.53454E+04 240 silica-amorphous -2.09 -3.22 -1.13 -0.378 0.19351E+04 242 an20ab80 2.02 1.41 -0.60 -0.047 0.10324E+04 243 an25ab75 2.65 1.86 -0.78 -0.060 0.13375E+04 244 an30ab70 3.28 2.31 -0.97 -0.074 0.16522E+04 245 tr.625ac.25prg.125 45.16 43.13 -2.03 -0.055 0.34732E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 2.0000000 g Current total amount of reactant added: 53.9990000 g New total amount of reactant added: 55.9990000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.1493E-12 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 9 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 55.9990000 Water: Moles liquid = 0.5514E+02 kg liquid = 0.9933E+00 Moles total = 0.5481E+02 kg total = 0.9874E+00 Activity = 1.0000 Stoichiometric ionic strength = .7783601E-02 Osmotic coef. = 0.9644 True ionic strength = .1410565E-01 Chg. balance for total moles = -.1493E-12 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.11201E-09 -9.9508 0.96084E-10 -10.0173 0.85785E+00 -0.0666 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13844E-03 -3.8587 0.11822E-03 -3.9273 0.85395E+00 -0.0686 4 SO4-- 0.35586E-05 -5.4487 0.20147E-05 -5.6958 0.56614E+00 -0.2471 5 HCO3- 0.55392E-05 -5.2566 0.47354E-05 -5.3246 0.85489E+00 -0.0681 6 HS- 0.22109E-04 -4.6554 0.18882E-04 -4.7239 0.85404E+00 -0.0685 7 Al+++ 0.48192E-28 -28.3170 0.13565E-28 -28.8676 0.28148E+00 -0.5506 8 H4SiO4 0.60132E-03 -3.2209 0.60132E-03 -3.2209 0.10000E+01 0.0000 9 Ca++ 0.74142E-07 -7.1299 0.41743E-07 -7.3794 0.56301E+00 -0.2495 10 Mg++ 0.22010E-10 -10.6574 0.12349E-10 -10.9084 0.56107E+00 -0.2510 11 Fe++ 0.79396E-13 -13.1002 0.44583E-13 -13.3508 0.56153E+00 -0.2506 12 K+ 0.11025E-03 -3.9576 0.94270E-04 -4.0256 0.85505E+00 -0.0680 13 Na+ 0.13984E-01 -1.8544 0.11940E-01 -1.9230 0.85384E+00 -0.0686 14 Mn++ 0.17425E-10 -10.7588 0.97910E-11 -11.0092 0.56188E+00 -0.2504 15 HPO4-- 0.13754E-06 -6.8616 0.77876E-07 -7.1086 0.56620E+00 -0.2470 16 HSiO3- 0.68430E-02 -2.1648 0.58436E-02 -2.2333 0.85395E+00 -0.0686 17 Ca(HSiO3)+ 0.64958E-08 -8.1874 0.55552E-08 -8.2553 0.85519E+00 -0.0679 18 Mg(HSiO3)+ 0.23916E-11 -11.6213 0.20452E-11 -11.6893 0.85519E+00 -0.0679 19 NaHSiO3,aq 0.11285E-02 -2.9475 0.11285E-02 -2.9475 0.10000E+01 0.0000 20 AlO+ 0.23374E-15 -15.6313 0.19989E-15 -15.6992 0.85519E+00 -0.0679 22 HAlO2,aq 0.41431E-09 -9.3827 0.41431E-09 -9.3827 0.10000E+01 0.0000 23 AlO2- 0.11193E-04 -4.9511 0.95448E-05 -5.0202 0.85278E+00 -0.0692 24 CH4,aq 0.43215E-10 -10.3644 0.43112E-10 -10.3654 0.99761E+00 -0.0010 29 CO,aq 0.52009E-17 -17.2839 0.52009E-17 -17.2839 0.10000E+01 0.0000 30 CO2,aq 0.97454E-09 -9.0112 0.97222E-09 -9.0122 0.99761E+00 -0.0010 31 CO3-2 0.76160E-05 -5.1183 0.43047E-05 -5.3661 0.56523E+00 -0.2478 32 CaCO3,aq 0.22531E-08 -8.6472 0.22531E-08 -8.6472 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.59001E-11 -11.2291 0.50457E-11 -11.2971 0.85519E+00 -0.0679 34 CaCl+ 0.93385E-11 -11.0297 0.79861E-11 -11.0977 0.85519E+00 -0.0679 35 CaCl2,aq 0.22430E-15 -15.6492 0.22430E-15 -15.6492 0.10000E+01 0.0000 36 CaOH+ 0.36205E-07 -7.4412 0.30962E-07 -7.5092 0.85519E+00 -0.0679 37 CaSO4,aq 0.26705E-10 -10.5734 0.26705E-10 -10.5734 0.10000E+01 0.0000 38 HCl,aq 0.20815E-14 -14.6816 0.20815E-14 -14.6816 0.10000E+01 0.0000 43 FeCl+ 0.97552E-17 -17.0108 0.83425E-17 -17.0787 0.85519E+00 -0.0679 46 FeO,aq 0.18769E-09 -9.7266 0.18769E-09 -9.7266 0.10000E+01 0.0000 47 FeOH+ 0.17661E-10 -10.7530 0.15104E-10 -10.8209 0.85519E+00 -0.0679 48 HFeO2- 0.23934E-07 -7.6210 0.20438E-07 -7.6896 0.85395E+00 -0.0686 49 FeO+ 0.91286E-16 -16.0396 0.78067E-16 -16.1075 0.85519E+00 -0.0679 51 FeO2- 0.20262E-08 -8.6933 0.17303E-08 -8.7619 0.85395E+00 -0.0686 52 HFeO2,aq 0.21145E-10 -10.6748 0.21145E-10 -10.6748 0.10000E+01 0.0000 53 H2,aq 0.21346E-06 -6.6707 0.21295E-06 -6.6717 0.99761E+00 -0.0010 54 KCl,aq 0.20199E-09 -9.6947 0.20199E-09 -9.6947 0.10000E+01 0.0000 55 KHSO4,aq 0.51596E-19 -19.2874 0.51596E-19 -19.2874 0.10000E+01 0.0000 56 KOH,aq 0.41899E-06 -6.3778 0.41899E-06 -6.3778 0.10000E+01 0.0000 57 KSO4- 0.34512E-08 -8.4620 0.29471E-08 -8.5306 0.85395E+00 -0.0686 58 MgCO3,aq 0.16708E-12 -12.7771 0.16708E-12 -12.7771 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.17835E-14 -14.7487 0.15253E-14 -14.8167 0.85519E+00 -0.0679 60 MgCl+ 0.25039E-14 -14.6014 0.21413E-14 -14.6693 0.85519E+00 -0.0679 61 MgOH+ 0.59268E-10 -10.2272 0.50685E-10 -10.2951 0.85519E+00 -0.0679 63 MnO,aq 0.10983E-08 -8.9593 0.10983E-08 -8.9593 0.10000E+01 0.0000 64 MnOH+ 0.36031E-09 -9.4433 0.30813E-09 -9.5113 0.85519E+00 -0.0679 65 MnO2-2 0.69849E-11 -11.1558 0.39481E-11 -11.4036 0.56523E+00 -0.2478 66 HMnO2- 0.97323E-10 -10.0118 0.83109E-10 -10.0804 0.85395E+00 -0.0686 69 MnCl+ 0.83348E-14 -14.0791 0.71278E-14 -14.1470 0.85519E+00 -0.0679 70 MnSO4,aq 0.56946E-14 -14.2445 0.56946E-14 -14.2445 0.10000E+01 0.0000 71 NaCl,aq 0.46779E-06 -6.3300 0.46779E-06 -6.3300 0.10000E+01 0.0000 72 NaOH,aq 0.53390E-04 -4.2725 0.53390E-04 -4.2725 0.10000E+01 0.0000 74 OH- 0.70513E-02 -2.1517 0.60132E-02 -2.2209 0.85278E+00 -0.0692 79 HPO3-2 0.91434E-16 -16.0389 0.51681E-16 -16.2867 0.56523E+00 -0.2478 81 H2PO3- 0.11661E-19 -19.9333 0.99577E-20 -20.0018 0.85395E+00 -0.0686 82 H3PO4,aq 0.50284E-17 -17.2986 0.50284E-17 -17.2986 0.10000E+01 0.0000 83 H2PO4- 0.16153E-09 -9.7918 0.13803E-09 -9.8600 0.85456E+00 -0.0683 84 PO4-3 0.22639E-08 -8.6451 0.66128E-09 -9.1796 0.29210E+00 -0.5345 88 HP2O7-3 0.11023E-16 -16.9577 0.31047E-17 -17.5080 0.28167E+00 -0.5503 89 P2O7-4 0.70978E-16 -16.1489 0.77193E-17 -17.1124 0.10876E+00 -0.9635 90 H2S,aq 0.56207E-08 -8.2502 0.56073E-08 -8.2512 0.99761E+00 -0.0010 91 S2-2 0.65635E-13 -13.1829 0.37098E-13 -13.4306 0.56523E+00 -0.2478 97 SO3-2 0.97571E-13 -13.0107 0.55752E-13 -13.2537 0.57140E+00 -0.2431 98 HSO3- 0.39277E-15 -15.4059 0.33541E-15 -15.4744 0.85395E+00 -0.0686 99 HSO4- 0.21799E-12 -12.6616 0.18655E-12 -12.7292 0.85581E+00 -0.0676 101 S2O3-2 0.23477E-15 -15.6293 0.13270E-15 -15.8771 0.56523E+00 -0.2478 Charge balance for all species = -.1606E-12 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.1120058E-09 -.1512915E-01 -.1523174E+02 0.0000 2 H2O 0.1000000E+01 0.5550741E+02 0.9988325E+06 0.0000 3 Cl- 0.1384394E-03 0.1389074E-03 0.4919020E+01 6.0900 4 SO4-- 0.3558629E-05 0.3508955E-05 0.3366881E+00 14.3389 5 HCO3- 0.5539171E-05 0.1315840E-04 0.8019654E+00 4.6927 6 HS- 0.2210925E-04 0.2216802E-04 0.7322976E+00 5.2934 7 Al+++ 0.4819249E-28 0.1119298E-04 0.3016559E+00 1.1845 8 H4SiO4 0.6013178E-03 0.8572803E-02 0.8230307E+03 -3.2209 9 Ca++ 0.7414218E-07 0.1191385E-06 0.4769340E-02 12.6553 10 Mg++ 0.2200983E-10 0.8384103E-10 0.2035999E-05 9.1263 11 Fe++ 0.7939558E-13 0.2618645E-07 0.1460753E-02 6.6839 12 K+ 0.1102513E-03 0.1106739E-03 0.4322594E+01 5.9917 13 Na+ 0.1398381E-01 0.1516614E-01 0.3482655E+03 8.0944 14 Mn++ 0.1742540E-10 0.1580350E-08 0.8672144E-04 9.0255 15 HPO4-- 0.1375422E-06 0.1399676E-06 0.1341850E-01 12.9261 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.9272473E+00 -.1502751E-01 -.9122198E+00 0.0000000E+00 2 H2O 0.5480628E+02 0.5513449E+02 -.3282151E+00 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.1577428E-02 0.3485381E-05 0.1573942E-02 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.1551923E-02 0.2201909E-04 -.1573942E-02 0.0000000E+00 7 Al+++ 0.1825983E+00 0.1111778E-04 0.1825872E+00 0.0000000E+00 8 H4SiO4 0.5831054E+00 0.8515209E-02 0.5745902E+00 0.0000000E+00 9 Ca++ 0.6442131E-01 0.1183381E-06 0.6442119E-01 0.0000000E+00 10 Mg++ 0.4444365E-01 0.8327777E-10 0.4444365E-01 0.0000000E+00 11 Fe++ 0.3992777E-01 0.2601052E-07 0.3992774E-01 0.0000000E+00 12 K+ 0.1188938E-01 0.1099304E-03 0.1177945E-01 0.0000000E+00 13 Na+ 0.7045246E-01 0.1506425E-01 0.5538821E-01 0.0000000E+00 14 Mn++ 0.9709440E-03 0.1569733E-08 0.9709425E-03 0.0000000E+00 15 HPO4-- 0.3313784E-03 0.1390272E-06 0.3312393E-03 0.0000000E+00 Chg. balance for solid moles: 0.7145E-16 Mass of aqueous solution: 0.994425E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 55.9990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 0.5539E-01 -1.257 14.52 1.162 23.76 5.575 andradite 0.6296E-02 -2.201 3.199 0.505 5.234 0.8312 grossular 0.6486E-03 -3.188 0.2922 -0.534 0.4779 0.8129E-01 apatite-OH 0.1104E-03 -3.957 0.5546E-01 -1.256 0.9073E-01 0.1762E-01 clinochlore 0.8889E-02 -2.051 4.941 0.694 8.082 1.879 daphnite 0.3367E-02 -2.473 2.402 0.381 3.930 0.7280 chlorite-Mn 0.1942E-03 -3.712 0.1377 -0.861 0.2252 0.4387E-01 microcline 0.1073E-01 -1.969 2.986 0.475 4.885 1.167 stilbite 0.4304E-01 -1.366 30.33 1.482 49.61 14.15 stilpnomelane-Fe 0.2100E-02 -2.678 2.264 0.355 3.704 0.7821 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.9066E+00 0.9066E+00 1.0000 -0.043 grossular 0.9340E-01 0.9340E-01 1.0000 -1.030 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.7140E+00 0.7140E+00 1.0000 -0.146 daphnite 0.2704E+00 0.2704E+00 1.0000 -0.568 chlorite-Mn 0.1560E-01 0.1560E-01 1.0000 -1.807 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 61.130423 g Volume = 25.251003 cm3 Porosity: -7.9121% V(tot) - V(min): -.18514E+01 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 55.9990000 g log = 1.7482 Original solution: 1000.0103000 g Original solution / Rock added: 17.86 (Water/Rock Ratio), log = 1.2518 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0206 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9997E+00 0.9859 0.1006E+01 0.1020E+01 CO2,gas 0.1012E-06 1.0071 0.1040E-06 0.1033E-06 CH4,gas 0.6141E-07 1.0125 0.6346E-07 0.6267E-07 H2,gas 0.2738E-03 1.0005 0.2796E-03 0.2794E-03 H2S,gas 0.1516E-06 0.9960 0.1541E-06 0.1548E-06 S2,gas 0.1118E-25 1.0000 0.1141E-25 0.1141E-25 CO,gas 0.7594E-14 1.0000 0.7750E-14 0.7750E-14 SO3,gas 0.6891E-41 1.0000 0.7033E-41 0.7033E-41 SO2,gas 0.7495E-22 1.0000 0.7649E-22 0.7649E-22 HCl,gas 0.3599E-17 1.0000 0.3673E-17 0.3673E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 16 albite -0.38 -0.38 0.00 0.000 -0.94784E-12 22 andradite 39.01 39.01 0.00 0.000 -0.24265E-10 23 grossular 32.73 32.73 0.00 0.000 0.00000E+00 32 apatite-OH -18.15 -18.15 0.00 0.000 0.18198E-10 46 clinochlore 39.07 39.07 0.00 0.000 0.36397E-10 47 daphnite 28.97 28.97 0.00 0.000 -0.42463E-10 48 chlorite-Mn 46.87 46.87 0.00 0.000 0.48529E-10 116 microcline -2.49 -2.49 0.00 0.000 -0.10616E-10 163 stilbite -7.52 -7.52 0.00 0.000 -0.90992E-11 164 stilpnomelane-Fe 13.02 13.02 0.00 0.000 0.21232E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -15.34 -8.68 -2.894 0.14824E+05 -6.983 3 CH4,gas 4.54 -4.35 -8.90 -2.224 0.15191E+05 -7.198 4 H2,gas 8.00 2.75 -5.25 -3.001 0.89684E+04 -3.553 5 H2S,gas -6.23 -14.74 -8.51 -4.256 0.14532E+05 -6.812 6 S2,gas -7.34 -34.98 -27.64 -4.253 0.47197E+05 -25.943 7 CO,gas 3.21 -12.59 -15.81 -4.865 0.26995E+05 -14.111 8 SO3,gas 17.12 -25.73 -42.85 -10.713 0.73168E+05 -41.153 9 SO2,gas 0.83 -22.98 -23.82 -6.351 0.40664E+05 -22.116 10 HCl,gas 5.19 -13.94 -19.13 -9.567 0.32671E+05 -17.435 11 acmite 7.71 6.96 -0.75 -0.078 0.12754E+04 15 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 19 spessartine 24.46 19.78 -4.67 -0.234 0.79816E+04 20 analcite 3.32 2.84 -0.48 -0.054 0.82784E+03 26 annite 20.12 17.57 -2.56 -0.142 0.43682E+04 27 phlogopite 27.06 24.89 -2.17 -0.121 0.37088E+04 29 anorthite 12.71 8.58 -4.13 -0.318 0.70483E+04 35 aragonite 0.97 -2.69 -3.65 -1.218 0.62378E+04 36 brucite 12.57 9.13 -3.44 -0.688 0.58775E+04 37 calcite 0.81 -2.69 -3.50 -1.166 0.59736E+04 38 carnegieite-low 9.02 6.06 -2.97 -0.424 0.50633E+04 39 carnegieite-high 10.09 6.06 -4.04 -0.576 0.68903E+04 40 carpholite-Mg 8.58 5.05 -3.53 -0.235 0.60250E+04 41 carpholite-Fe 6.71 2.61 -4.10 -0.273 0.70034E+04 42 celadonite 5.34 3.42 -1.92 -0.113 0.32829E+04 43 celadonite-Fe 3.88 0.98 -2.90 -0.171 0.49518E+04 44 chrysotile 23.89 20.94 -2.96 -0.246 0.50459E+04 50 chloritoid-Mg 13.20 8.27 -4.92 -0.328 0.84064E+04 51 chloritoid-Fe 9.17 5.83 -3.34 -0.223 0.57059E+04 52 chloritoid-Mn 11.40 8.17 -3.23 -0.215 0.55109E+04 54 coesite -2.38 -3.22 -0.84 -0.282 0.14425E+04 61 cristobalite -2.56 -3.22 -0.66 -0.220 0.11279E+04 63 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71234E+04 65 diaspore 2.87 1.18 -1.69 -0.282 0.28843E+04 67 diopside 16.18 15.34 -0.84 -0.084 0.14369E+04 68 hedenbergite 14.21 12.90 -1.31 -0.131 0.22384E+04 75 epidote 24.67 23.33 -1.34 -0.065 0.22929E+04 76 clinozoisite 22.81 19.20 -3.60 -0.164 0.61550E+04 77 epidote-Fe 29.84 27.45 -2.39 -0.124 0.40775E+04 78 fayalite 14.05 10.15 -3.90 -0.557 0.66573E+04 79 ferrosilite 11.15 6.93 -4.22 -0.422 0.72115E+04 83 gibbsite 4.08 1.18 -2.89 -0.414 0.49429E+04 84 glaucophane 22.97 20.17 -2.81 -0.076 0.47900E+04 85 glaucophane-Fe 17.28 12.84 -4.43 -0.120 0.75705E+04 87 greenalite 16.14 13.61 -2.53 -0.211 0.43194E+04 90 hematite 12.57 10.62 -1.95 -0.236 0.33223E+04 91 heulandite -5.83 -7.52 -1.69 -0.077 0.28938E+04 95 jadeite 4.22 2.84 -1.38 -0.138 0.23533E+04 96 julgoldite 70.43 65.90 -4.52 -0.117 0.77222E+04 97 kalsilite 7.58 3.96 -3.63 -0.518 0.61958E+04 98 kaolinite -1.33 -4.07 -2.74 -0.249 0.46786E+04 101 laumontite 2.88 2.14 -0.74 -0.050 0.12683E+04 102 lawsonite 9.62 8.58 -1.03 -0.069 0.17649E+04 103 leucite 4.12 0.73 -3.38 -0.338 0.57789E+04 105 lizardite 23.24 20.94 -2.31 -0.192 0.39385E+04 107 magnetite 20.09 17.30 -2.78 -0.227 0.47521E+04 108 minnesotaite 10.39 7.17 -3.22 -0.189 0.54982E+04 120 muscovite 2.58 -0.12 -2.70 -0.159 0.46102E+04 121 paragonite 4.24 1.99 -2.25 -0.133 0.38493E+04 122 nepheline 8.34 6.06 -2.28 -0.326 0.38957E+04 128 periclase-Fe 11.63 6.68 -4.94 -1.236 0.84396E+04 134 phlogopite-Na 29.65 27.00 -2.65 -0.147 0.45276E+04 136 prehnite 19.37 18.02 -1.36 -0.080 0.23137E+04 137 prehnite-Fe 22.50 22.14 -0.36 -0.021 0.60667E+03 138 pumpellyite-Fe 46.27 43.90 -2.37 -0.053 0.40424E+04 139 pumpellyite-Mg 48.99 46.34 -2.65 -0.059 0.45256E+04 142 pyrite -21.25 -25.55 -4.30 -1.012 0.73406E+04 143 pyrrhotite -4.26 -8.06 -3.80 -1.266 0.64835E+04 144 pyrrhotiteFe0.875 -6.02 -9.23 -3.22 -1.183 0.54923E+04 145 pyroxmangite 7.40 5.80 -1.59 -0.319 0.27218E+04 146 pyrophyllite -6.18 -10.51 -4.34 -0.271 0.74085E+04 147 quartz -2.99 -3.22 -0.23 -0.077 0.39521E+03 152 rhodonite 7.45 5.80 -1.64 -0.328 0.28020E+04 153 sanidine -1.28 -2.49 -1.21 -0.093 0.20677E+04 165 stilpnomelane-Mg 27.44 25.23 -2.21 -0.066 0.37771E+04 171 talc 16.49 14.50 -2.00 -0.117 0.34075E+04 174 tephroite 18.09 14.83 -3.26 -0.465 0.55589E+04 178 tridymite -2.63 -3.22 -0.59 -0.198 0.10152E+04 179 tremolite 47.87 45.18 -2.69 -0.073 0.46003E+04 181 troilite-low -4.41 -8.06 -3.65 -1.215 0.62263E+04 187 wairakite 3.95 2.14 -1.81 -0.106 0.30902E+04 188 walstromite 11.51 9.43 -2.07 -0.415 0.35427E+04 189 wollastonite 10.46 9.43 -1.03 -0.205 0.17532E+04 190 pseudo-wollastonite 11.00 9.43 -1.57 -0.313 0.26730E+04 191 zoisite 22.85 19.20 -3.65 -0.166 0.62291E+04 192 akaganeite 7.75 5.31 -2.44 -0.529 0.41737E+04 199 chalcedony -2.80 -3.22 -0.42 -0.139 0.71451E+03 201 montmorillonite-Ca -2.29 -5.81 -3.51 -0.217 0.60018E+04 202 montmorillonite-K -2.24 -5.92 -3.68 -0.225 0.62832E+04 203 montmorillonite-Mg -2.48 -6.39 -3.91 -0.242 0.66730E+04 204 montmorillonite-Na -2.04 -5.22 -3.18 -0.195 0.54381E+04 205 nontronite-Ca 3.21 1.28 -1.94 -0.126 0.33053E+04 206 nontronite-H 2.53 -0.81 -3.34 -0.224 0.57065E+04 207 nontronite-K 3.34 1.17 -2.17 -0.139 0.37100E+04 208 nontronite-Mg 3.07 0.70 -2.38 -0.154 0.40606E+04 209 nontronite-Na 3.52 1.86 -1.66 -0.106 0.28309E+04 224 tobermorite 9.82 7.32 -2.50 -0.683 0.42723E+04 230 alabandite -0.98 -5.72 -4.74 -1.579 0.80898E+04 233 boehmite 4.41 1.18 -3.22 -0.537 0.55012E+04 235 ferrous-oxide 9.81 6.68 -3.13 -0.782 0.53405E+04 240 silica-amorphous -2.09 -3.22 -1.13 -0.377 0.19287E+04 242 an20ab80 2.02 1.41 -0.61 -0.047 0.10388E+04 243 an25ab75 2.65 1.86 -0.79 -0.061 0.13455E+04 244 an30ab70 3.28 2.31 -0.97 -0.075 0.16618E+04 245 tr.625ac.25prg.125 45.16 43.24 -1.92 -0.052 0.32824E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 2.0000000 g Current total amount of reactant added: 55.9990000 g New total amount of reactant added: 57.9990000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.1493E-12 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 10 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 57.9990000 Water: Moles liquid = 0.5512E+02 kg liquid = 0.9931E+00 Moles total = 0.5478E+02 kg total = 0.9869E+00 Activity = 1.0000 Stoichiometric ionic strength = .7950268E-02 Osmotic coef. = 0.9655 True ionic strength = .1439547E-01 Chg. balance for total moles = -.1493E-12 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.11041E-09 -9.9570 0.94605E-10 -10.0241 0.85687E+00 -0.0671 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13846E-03 -3.8587 0.11810E-03 -3.9278 0.85291E+00 -0.0691 4 SO4-- 0.15633E-05 -5.8059 0.88087E-06 -6.0551 0.56346E+00 -0.2491 5 HCO3- 0.54792E-05 -5.2613 0.46785E-05 -5.3299 0.85386E+00 -0.0686 6 HS- 0.24112E-04 -4.6178 0.20568E-04 -4.6868 0.85300E+00 -0.0690 7 Al+++ 0.43779E-28 -28.3587 0.12190E-28 -28.9140 0.27844E+00 -0.5553 8 H4SiO4 0.60646E-03 -3.2172 0.60646E-03 -3.2172 0.10000E+01 0.0000 9 Ca++ 0.76772E-07 -7.1148 0.43015E-07 -7.3664 0.56029E+00 -0.2516 10 Mg++ 0.21950E-10 -10.6586 0.12255E-10 -10.9117 0.55833E+00 -0.2531 11 Fe++ 0.77892E-13 -13.1085 0.43525E-13 -13.3613 0.55880E+00 -0.2527 12 K+ 0.11253E-03 -3.9487 0.96104E-04 -4.0173 0.85402E+00 -0.0685 13 Na+ 0.14273E-01 -1.8455 0.12172E-01 -1.9146 0.85280E+00 -0.0692 14 Mn++ 0.17378E-10 -10.7600 0.97168E-11 -11.0125 0.55915E+00 -0.2525 15 HPO4-- 0.12876E-06 -6.8902 0.72558E-07 -7.1393 0.56352E+00 -0.2491 16 HSiO3- 0.70180E-02 -2.1538 0.59857E-02 -2.2229 0.85291E+00 -0.0691 17 Ca(HSiO3)+ 0.68648E-08 -8.1634 0.58637E-08 -8.2318 0.85417E+00 -0.0685 18 Mg(HSiO3)+ 0.24341E-11 -11.6137 0.20791E-11 -11.6821 0.85417E+00 -0.0685 19 NaHSiO3,aq 0.11784E-02 -2.9287 0.11784E-02 -2.9287 0.10000E+01 0.0000 20 AlO+ 0.21693E-15 -15.6637 0.18529E-15 -15.7321 0.85417E+00 -0.0685 22 HAlO2,aq 0.39005E-09 -9.4089 0.39005E-09 -9.4089 0.10000E+01 0.0000 23 AlO2- 0.10715E-04 -4.9700 0.91266E-05 -5.0397 0.85172E+00 -0.0697 24 CH4,aq 0.10637E-09 -9.9732 0.10611E-09 -9.9742 0.99756E+00 -0.0011 29 CO,aq 0.63809E-17 -17.1951 0.63809E-17 -17.1951 0.10000E+01 0.0000 30 CO2,aq 0.94807E-09 -9.0232 0.94575E-09 -9.0242 0.99756E+00 -0.0011 31 CO3-2 0.76787E-05 -5.1147 0.43196E-05 -5.3646 0.56254E+00 -0.2498 32 CaCO3,aq 0.23298E-08 -8.6327 0.23298E-08 -8.6327 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.60141E-11 -11.2208 0.51370E-11 -11.2893 0.85417E+00 -0.0685 34 CaCl+ 0.96244E-11 -11.0166 0.82209E-11 -11.0851 0.85417E+00 -0.0685 35 CaCl2,aq 0.23065E-15 -15.6370 0.23065E-15 -15.6370 0.10000E+01 0.0000 36 CaOH+ 0.37938E-07 -7.4209 0.32405E-07 -7.4894 0.85417E+00 -0.0685 37 CaSO4,aq 0.12032E-10 -10.9197 0.12032E-10 -10.9197 0.10000E+01 0.0000 38 HCl,aq 0.20473E-14 -14.6888 0.20473E-14 -14.6888 0.10000E+01 0.0000 43 FeCl+ 0.95251E-17 -17.0211 0.81360E-17 -17.0896 0.85417E+00 -0.0685 46 FeO,aq 0.18901E-09 -9.7235 0.18901E-09 -9.7235 0.10000E+01 0.0000 47 FeOH+ 0.17533E-10 -10.7561 0.14976E-10 -10.8246 0.85417E+00 -0.0685 48 HFeO2- 0.24509E-07 -7.6107 0.20904E-07 -7.6798 0.85291E+00 -0.0691 49 FeO+ 0.80695E-16 -16.0932 0.68926E-16 -16.1616 0.85417E+00 -0.0685 51 FeO2- 0.18476E-08 -8.7334 0.15758E-08 -8.8025 0.85291E+00 -0.0691 52 HFeO2,aq 0.18961E-10 -10.7221 0.18961E-10 -10.7221 0.10000E+01 0.0000 53 H2,aq 0.26924E-06 -6.5699 0.26858E-06 -6.5709 0.99756E+00 -0.0011 54 KCl,aq 0.20570E-09 -9.6868 0.20570E-09 -9.6868 0.10000E+01 0.0000 55 KHSO4,aq 0.22644E-19 -19.6450 0.22644E-19 -19.6450 0.10000E+01 0.0000 56 KOH,aq 0.43383E-06 -6.3627 0.43383E-06 -6.3627 0.10000E+01 0.0000 57 KSO4- 0.15402E-08 -8.8124 0.13136E-08 -8.8815 0.85291E+00 -0.0691 58 MgCO3,aq 0.16638E-12 -12.7789 0.16638E-12 -12.7789 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.17509E-14 -14.7567 0.14955E-14 -14.8252 0.85417E+00 -0.0685 60 MgCl+ 0.24853E-14 -14.6046 0.21228E-14 -14.6731 0.85417E+00 -0.0685 61 MgOH+ 0.59810E-10 -10.2232 0.51088E-10 -10.2917 0.85417E+00 -0.0685 63 MnO,aq 0.11243E-08 -8.9491 0.11243E-08 -8.9491 0.10000E+01 0.0000 64 MnOH+ 0.36361E-09 -9.4394 0.31058E-09 -9.5078 0.85417E+00 -0.0685 65 MnO2-2 0.74112E-11 -11.1301 0.41691E-11 -11.3800 0.56254E+00 -0.2498 66 HMnO2- 0.10131E-09 -9.9943 0.86410E-10 -10.0634 0.85291E+00 -0.0691 69 MnCl+ 0.82728E-14 -14.0823 0.70663E-14 -14.1508 0.85417E+00 -0.0685 70 MnSO4,aq 0.24710E-14 -14.6071 0.24710E-14 -14.6071 0.10000E+01 0.0000 71 NaCl,aq 0.47639E-06 -6.3220 0.47639E-06 -6.3220 0.10000E+01 0.0000 72 NaOH,aq 0.55280E-04 -4.2574 0.55280E-04 -4.2574 0.10000E+01 0.0000 74 OH- 0.71705E-02 -2.1445 0.61073E-02 -2.2142 0.85172E+00 -0.0697 79 HPO3-2 0.10796E-15 -15.9667 0.60730E-16 -16.2166 0.56254E+00 -0.2498 81 H2PO3- 0.13508E-19 -19.8694 0.11521E-19 -19.9385 0.85291E+00 -0.0691 82 H3PO4,aq 0.45418E-17 -17.3428 0.45418E-17 -17.3428 0.10000E+01 0.0000 83 H2PO4- 0.14836E-09 -9.8287 0.12663E-09 -9.8975 0.85353E+00 -0.0688 84 PO4-3 0.21643E-08 -8.6647 0.62576E-09 -9.2036 0.28913E+00 -0.5389 88 HP2O7-3 0.95238E-17 -17.0212 0.26537E-17 -17.5762 0.27863E+00 -0.5550 89 P2O7-4 0.62791E-16 -16.2021 0.67011E-17 -17.1739 0.10672E+00 -0.9718 90 H2S,aq 0.60284E-08 -8.2198 0.60137E-08 -8.2209 0.99756E+00 -0.0011 91 S2-2 0.62040E-13 -13.2073 0.34900E-13 -13.4572 0.56254E+00 -0.2498 97 SO3-2 0.54052E-13 -13.2672 0.30744E-13 -13.5122 0.56878E+00 -0.2451 98 HSO3- 0.21352E-15 -15.6706 0.18211E-15 -15.7397 0.85291E+00 -0.0691 99 HSO4- 0.93953E-13 -13.0271 0.80311E-13 -13.0952 0.85480E+00 -0.0681 101 S2O3-2 0.11062E-15 -15.9562 0.62226E-16 -16.2060 0.56254E+00 -0.2498 Charge balance for all species = -.1517E-12 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.1104072E-09 -.1547332E-01 -.1557781E+02 0.0000 2 H2O 0.1000000E+01 0.5550730E+02 0.9988030E+06 0.0000 3 Cl- 0.1384623E-03 0.1389389E-03 0.4919998E+01 6.0963 4 SO4-- 0.1563339E-05 0.1497710E-05 0.1437029E+00 13.9931 5 HCO3- 0.5479248E-05 0.1316138E-04 0.8021249E+00 4.6942 6 HS- 0.2411187E-04 0.2418508E-04 0.7989070E+00 5.3373 7 Al+++ 0.4377944E-28 0.1071584E-04 0.2887889E+00 1.1583 8 H4SiO4 0.6064582E-03 0.8802860E-02 0.8450939E+03 -3.2172 9 Ca++ 0.7677239E-07 0.1239324E-06 0.4961112E-02 12.6818 10 Mg++ 0.2195024E-10 0.8436544E-10 0.2048677E-05 9.1365 11 Fe++ 0.7789162E-13 0.2658255E-07 0.1482807E-02 6.6869 12 K+ 0.1125309E-03 0.1129664E-03 0.4412011E+01 6.0068 13 Na+ 0.1427329E-01 0.1550745E-01 0.3560932E+03 8.1095 14 Mn++ 0.1737779E-10 0.1614048E-08 0.8856814E-04 9.0357 15 HPO4-- 0.1287589E-06 0.1310715E-06 0.1256530E-01 12.9089 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.9603643E+00 -.1536589E-01 -.9449984E+00 0.0000000E+00 2 H2O 0.5478121E+02 0.5512191E+02 -.3406972E+00 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.1632854E-02 0.1487311E-05 0.1631367E-02 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.1607350E-02 0.2401716E-04 -.1631367E-02 0.0000000E+00 7 Al+++ 0.1891198E+00 0.1064144E-04 0.1891091E+00 0.0000000E+00 8 H4SiO4 0.6039310E+00 0.8741740E-02 0.5951893E+00 0.0000000E+00 9 Ca++ 0.6672159E-01 0.1230719E-06 0.6672147E-01 0.0000000E+00 10 Mg++ 0.4603095E-01 0.8377968E-10 0.4603095E-01 0.0000000E+00 11 Fe++ 0.4135379E-01 0.2639798E-07 0.4135376E-01 0.0000000E+00 12 K+ 0.1231401E-01 0.1121821E-03 0.1220183E-01 0.0000000E+00 13 Na+ 0.7296295E-01 0.1539978E-01 0.5756317E-01 0.0000000E+00 14 Mn++ 0.1005621E-02 0.1602842E-08 0.1005620E-02 0.0000000E+00 15 HPO4-- 0.3432135E-03 0.1301615E-06 0.3430834E-03 0.0000000E+00 Chg. balance for solid moles: -.1160E-15 Mass of aqueous solution: 0.994228E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 57.9990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 0.5756E-01 -1.240 15.09 1.179 23.84 5.794 andradite 0.6525E-02 -2.185 3.316 0.521 5.238 0.8616 grossular 0.7058E-03 -3.151 0.3179 -0.498 0.5021 0.8846E-01 apatite-OH 0.1144E-03 -3.942 0.5745E-01 -1.241 0.9073E-01 0.1825E-01 clinochlore 0.9206E-02 -2.036 5.117 0.709 8.082 1.946 daphnite 0.3430E-02 -2.465 2.448 0.389 3.866 0.7417 chlorite-Mn 0.2011E-03 -3.697 0.1426 -0.846 0.2252 0.4544E-01 microcline 0.1109E-01 -1.955 3.086 0.489 4.874 1.205 stilbite 0.4446E-01 -1.352 31.33 1.496 49.48 14.61 stilpnomelane-Fe 0.2230E-02 -2.652 2.404 0.381 3.797 0.8304 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.9024E+00 0.9024E+00 1.0000 -0.045 grossular 0.9760E-01 0.9760E-01 1.0000 -1.011 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.7171E+00 0.7171E+00 1.0000 -0.144 daphnite 0.2672E+00 0.2672E+00 1.0000 -0.573 chlorite-Mn 0.1567E-01 0.1567E-01 1.0000 -1.805 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 63.311926 g Volume = 26.144373 cm3 Porosity: -8.0364% V(tot) - V(min): -.19448E+01 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 57.9990000 g log = 1.7634 Original solution: 1000.0103000 g Original solution / Rock added: 17.24 (Water/Rock Ratio), log = 1.2366 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0207 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9997E+00 0.9859 0.1006E+01 0.1020E+01 CO2,gas 0.9844E-07 1.0071 0.1012E-06 0.1005E-06 CH4,gas 0.1511E-06 1.0125 0.1562E-06 0.1543E-06 H2,gas 0.3453E-03 1.0005 0.3526E-03 0.3524E-03 H2S,gas 0.1626E-06 0.9960 0.1653E-06 0.1660E-06 S2,gas 0.8083E-26 1.0000 0.8250E-26 0.8250E-26 CO,gas 0.9316E-14 1.0000 0.9509E-14 0.9509E-14 SO3,gas 0.2921E-41 1.0000 0.2981E-41 0.2981E-41 SO2,gas 0.4007E-22 1.0000 0.4089E-22 0.4089E-22 HCl,gas 0.3539E-17 1.0000 0.3612E-17 0.3612E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 16 albite -0.38 -0.38 0.00 0.000 0.11184E-10 22 andradite 39.01 39.01 0.00 0.000 0.24265E-10 23 grossular 32.73 32.73 0.00 0.000 0.24265E-10 32 apatite-OH -18.15 -18.15 0.00 0.000 0.00000E+00 46 clinochlore 39.07 39.07 0.00 0.000 0.24265E-10 47 daphnite 28.97 28.97 0.00 0.000 0.48529E-10 48 chlorite-Mn 46.87 46.87 0.00 0.000 0.12132E-10 116 microcline -2.49 -2.49 0.00 0.000 0.13649E-10 163 stilbite -7.52 -7.52 0.00 0.000 0.15165E-10 164 stilpnomelane-Fe 13.02 13.02 0.00 0.000 0.21232E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -15.35 -8.69 -2.898 0.14845E+05 -6.995 3 CH4,gas 4.54 -3.96 -8.51 -2.126 0.14523E+05 -6.806 4 H2,gas 8.00 2.85 -5.15 -2.944 0.87963E+04 -3.453 5 H2S,gas -6.23 -14.71 -8.48 -4.240 0.14481E+05 -6.782 6 S2,gas -7.34 -35.12 -27.78 -4.274 0.47438E+05 -26.084 7 CO,gas 3.21 -12.51 -15.72 -4.837 0.26843E+05 -14.022 8 SO3,gas 17.12 -26.10 -43.22 -10.806 0.73805E+05 -41.526 9 SO2,gas 0.83 -23.26 -24.09 -6.423 0.41128E+05 -22.388 10 HCl,gas 5.19 -13.95 -19.14 -9.571 0.32683E+05 -17.442 11 acmite 7.71 6.94 -0.77 -0.080 0.13178E+04 15 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 19 spessartine 24.46 19.77 -4.69 -0.234 0.80000E+04 20 analcite 3.32 2.83 -0.49 -0.054 0.83415E+03 26 annite 20.12 17.57 -2.55 -0.142 0.43526E+04 27 phlogopite 27.06 24.92 -2.14 -0.119 0.36567E+04 29 anorthite 12.71 8.56 -4.15 -0.319 0.70798E+04 35 aragonite 0.97 -2.67 -3.64 -1.213 0.62130E+04 36 brucite 12.57 9.14 -3.43 -0.686 0.58602E+04 37 calcite 0.81 -2.67 -3.48 -1.161 0.59488E+04 38 carnegieite-low 9.02 6.05 -2.97 -0.425 0.50759E+04 39 carnegieite-high 10.09 6.05 -4.04 -0.578 0.69029E+04 40 carpholite-Mg 8.58 5.02 -3.56 -0.238 0.60845E+04 41 carpholite-Fe 6.71 2.57 -4.14 -0.276 0.70750E+04 42 celadonite 5.34 3.43 -1.91 -0.112 0.32592E+04 43 celadonite-Fe 3.88 0.98 -2.89 -0.170 0.49402E+04 44 chrysotile 23.89 20.98 -2.92 -0.243 0.49812E+04 50 chloritoid-Mg 13.20 8.24 -4.96 -0.331 0.84722E+04 51 chloritoid-Fe 9.17 5.79 -3.39 -0.226 0.57838E+04 52 chloritoid-Mn 11.40 8.14 -3.27 -0.218 0.55767E+04 54 coesite -2.38 -3.22 -0.84 -0.280 0.14362E+04 61 cristobalite -2.56 -3.22 -0.66 -0.219 0.11216E+04 63 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71234E+04 65 diaspore 2.87 1.16 -1.72 -0.286 0.29290E+04 67 diopside 16.18 15.38 -0.80 -0.080 0.13616E+04 68 hedenbergite 14.21 12.93 -1.27 -0.127 0.21752E+04 75 epidote 24.67 23.29 -1.38 -0.067 0.23537E+04 76 clinozoisite 22.81 19.19 -3.62 -0.165 0.61797E+04 77 epidote-Fe 29.84 27.40 -2.44 -0.127 0.41744E+04 78 fayalite 14.05 10.16 -3.89 -0.556 0.66405E+04 79 ferrosilite 11.15 6.94 -4.21 -0.421 0.71885E+04 83 gibbsite 4.08 1.16 -2.92 -0.417 0.49876E+04 84 glaucophane 22.97 20.21 -2.77 -0.075 0.47253E+04 85 glaucophane-Fe 17.28 12.86 -4.42 -0.119 0.75422E+04 87 greenalite 16.14 13.63 -2.51 -0.209 0.42911E+04 90 hematite 12.57 10.53 -2.04 -0.247 0.34840E+04 91 heulandite -5.83 -7.52 -1.69 -0.077 0.28938E+04 95 jadeite 4.22 2.83 -1.38 -0.138 0.23596E+04 96 julgoldite 70.43 65.85 -4.58 -0.119 0.78161E+04 97 kalsilite 7.58 3.95 -3.64 -0.519 0.62084E+04 98 kaolinite -1.33 -4.12 -2.79 -0.253 0.47555E+04 101 laumontite 2.88 2.13 -0.75 -0.050 0.12872E+04 102 lawsonite 9.62 8.56 -1.05 -0.070 0.17965E+04 103 leucite 4.12 0.73 -3.39 -0.339 0.57852E+04 105 lizardite 23.24 20.98 -2.27 -0.189 0.38738E+04 107 magnetite 20.09 17.21 -2.87 -0.235 0.49085E+04 108 minnesotaite 10.39 7.19 -3.20 -0.188 0.54573E+04 120 muscovite 2.58 -0.17 -2.75 -0.162 0.46996E+04 121 paragonite 4.24 1.93 -2.31 -0.136 0.39387E+04 122 nepheline 8.34 6.05 -2.29 -0.327 0.39083E+04 128 periclase-Fe 11.63 6.69 -4.94 -1.235 0.84343E+04 134 phlogopite-Na 29.65 27.03 -2.62 -0.146 0.44755E+04 136 prehnite 19.37 18.03 -1.34 -0.079 0.22937E+04 137 prehnite-Fe 22.50 22.13 -0.36 -0.022 0.62275E+03 138 pumpellyite-Fe 46.27 43.90 -2.37 -0.053 0.40418E+04 139 pumpellyite-Mg 48.99 46.35 -2.64 -0.059 0.45129E+04 142 pyrite -21.25 -25.58 -4.34 -1.020 0.74037E+04 143 pyrrhotite -4.26 -8.02 -3.76 -1.255 0.64264E+04 144 pyrrhotiteFe0.875 -6.02 -9.21 -3.20 -1.175 0.54572E+04 145 pyroxmangite 7.40 5.82 -1.58 -0.316 0.26981E+04 146 pyrophyllite -6.18 -10.55 -4.38 -0.274 0.74727E+04 147 quartz -2.99 -3.22 -0.23 -0.076 0.38890E+03 152 rhodonite 7.45 5.82 -1.63 -0.325 0.27784E+04 153 sanidine -1.28 -2.49 -1.21 -0.093 0.20677E+04 165 stilpnomelane-Mg 27.44 25.26 -2.18 -0.065 0.37163E+04 171 talc 16.49 14.54 -1.95 -0.115 0.33302E+04 174 tephroite 18.09 14.85 -3.23 -0.462 0.55179E+04 178 tridymite -2.63 -3.22 -0.59 -0.197 0.10089E+04 179 tremolite 47.87 45.31 -2.56 -0.069 0.43724E+04 181 troilite-low -4.41 -8.02 -3.61 -1.204 0.61692E+04 187 wairakite 3.95 2.13 -1.82 -0.107 0.31092E+04 188 walstromite 11.51 9.46 -2.04 -0.409 0.34911E+04 189 wollastonite 10.46 9.46 -1.00 -0.199 0.17016E+04 190 pseudo-wollastonite 11.00 9.46 -1.54 -0.307 0.26214E+04 191 zoisite 22.85 19.19 -3.66 -0.166 0.62538E+04 192 akaganeite 7.75 5.26 -2.49 -0.539 0.42545E+04 199 chalcedony -2.80 -3.22 -0.41 -0.138 0.70820E+03 201 montmorillonite-Ca -2.29 -5.83 -3.54 -0.219 0.60380E+04 202 montmorillonite-K -2.24 -5.94 -3.70 -0.227 0.63184E+04 203 montmorillonite-Mg -2.48 -6.41 -3.93 -0.243 0.67138E+04 204 montmorillonite-Na -2.04 -5.24 -3.21 -0.196 0.54733E+04 205 nontronite-Ca 3.21 1.19 -2.02 -0.131 0.34511E+04 206 nontronite-H 2.53 -0.90 -3.43 -0.230 0.58598E+04 207 nontronite-K 3.34 1.08 -2.26 -0.145 0.38548E+04 208 nontronite-Mg 3.07 0.61 -2.47 -0.160 0.42110E+04 209 nontronite-Na 3.52 1.78 -1.74 -0.112 0.29756E+04 224 tobermorite 9.82 7.35 -2.48 -0.676 0.42282E+04 230 alabandite -0.98 -5.68 -4.70 -1.566 0.80206E+04 233 boehmite 4.41 1.16 -3.25 -0.541 0.55460E+04 235 ferrous-oxide 9.81 6.69 -3.12 -0.781 0.53353E+04 240 silica-amorphous -2.09 -3.22 -1.13 -0.375 0.19224E+04 242 an20ab80 2.02 1.41 -0.61 -0.047 0.10451E+04 243 an25ab75 2.65 1.85 -0.79 -0.061 0.13534E+04 244 an30ab70 3.28 2.30 -0.98 -0.075 0.16712E+04 245 tr.625ac.25prg.125 45.16 43.36 -1.81 -0.049 0.30870E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 2.0000000 g Current total amount of reactant added: 57.9990000 g New total amount of reactant added: 59.9990000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.1492E-12 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 10 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 59.9990000 Water: Moles liquid = 0.5511E+02 kg liquid = 0.9928E+00 Moles total = 0.5476E+02 kg total = 0.9865E+00 Activity = 1.0000 Stoichiometric ionic strength = .8124078E-02 Osmotic coef. = 0.9658 True ionic strength = .1469476E-01 Chg. balance for total moles = -.1492E-12 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.10883E-09 -9.9633 0.93145E-10 -10.0308 0.85587E+00 -0.0676 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13848E-03 -3.8586 0.11797E-03 -3.9282 0.85185E+00 -0.0696 4 SO4-- 0.64955E-06 -6.1874 0.36423E-06 -6.4386 0.56074E+00 -0.2512 5 HCO3- 0.54191E-05 -5.2661 0.46216E-05 -5.3352 0.85282E+00 -0.0691 6 HS- 0.25032E-04 -4.6015 0.21326E-04 -4.6711 0.85195E+00 -0.0696 7 Al+++ 0.39768E-28 -28.4005 0.10952E-28 -28.9605 0.27538E+00 -0.5601 8 H4SiO4 0.61164E-03 -3.2135 0.61164E-03 -3.2135 0.10000E+01 0.0000 9 Ca++ 0.79525E-07 -7.0995 0.44338E-07 -7.3532 0.55754E+00 -0.2537 10 Mg++ 0.21891E-10 -10.6597 0.12162E-10 -10.9150 0.55555E+00 -0.2553 11 Fe++ 0.76422E-13 -13.1168 0.42493E-13 -13.3717 0.55602E+00 -0.2549 12 K+ 0.11488E-03 -3.9398 0.97987E-04 -4.0088 0.85298E+00 -0.0691 13 Na+ 0.14571E-01 -1.8365 0.12411E-01 -1.9062 0.85174E+00 -0.0697 14 Mn++ 0.17331E-10 -10.7612 0.96426E-11 -11.0158 0.55638E+00 -0.2546 15 HPO4-- 0.12049E-06 -6.9191 0.67570E-07 -7.1702 0.56080E+00 -0.2512 16 HSiO3- 0.71978E-02 -2.1428 0.61315E-02 -2.2124 0.85185E+00 -0.0696 17 Ca(HSiO3)+ 0.72571E-08 -8.1392 0.61913E-08 -8.2082 0.85313E+00 -0.0690 18 Mg(HSiO3)+ 0.24773E-11 -11.6060 0.21135E-11 -11.6750 0.85313E+00 -0.0690 19 NaHSiO3,aq 0.12307E-02 -2.9098 0.12307E-02 -2.9098 0.10000E+01 0.0000 20 AlO+ 0.20129E-15 -15.6962 0.17173E-15 -15.7652 0.85313E+00 -0.0690 22 HAlO2,aq 0.36716E-09 -9.4351 0.36716E-09 -9.4351 0.10000E+01 0.0000 23 AlO2- 0.10258E-04 -4.9890 0.87255E-05 -5.0592 0.85064E+00 -0.0703 24 CH4,aq 0.26351E-09 -9.5792 0.26285E-09 -9.5803 0.99751E+00 -0.0011 29 CO,aq 0.78400E-17 -17.1057 0.78400E-17 -17.1057 0.10000E+01 0.0000 30 CO2,aq 0.92212E-09 -9.0352 0.91982E-09 -9.0363 0.99751E+00 -0.0011 31 CO3-2 0.77416E-05 -5.1112 0.43338E-05 -5.3631 0.55981E+00 -0.2520 32 CaCO3,aq 0.24094E-08 -8.6181 0.24094E-08 -8.6181 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.61311E-11 -11.2125 0.52306E-11 -11.2815 0.85313E+00 -0.0690 34 CaCl+ 0.99219E-11 -11.0034 0.84646E-11 -11.0724 0.85313E+00 -0.0690 35 CaCl2,aq 0.23724E-15 -15.6248 0.23724E-15 -15.6248 0.10000E+01 0.0000 36 CaOH+ 0.39766E-07 -7.4005 0.33925E-07 -7.4695 0.85313E+00 -0.0690 37 CaSO4,aq 0.51281E-11 -11.2900 0.51281E-11 -11.2900 0.10000E+01 0.0000 38 HCl,aq 0.20135E-14 -14.6960 0.20135E-14 -14.6960 0.10000E+01 0.0000 43 FeCl+ 0.93004E-17 -17.0315 0.79344E-17 -17.1005 0.85313E+00 -0.0690 46 FeO,aq 0.19035E-09 -9.7204 0.19035E-09 -9.7204 0.10000E+01 0.0000 47 FeOH+ 0.17406E-10 -10.7593 0.14850E-10 -10.8283 0.85313E+00 -0.0690 48 HFeO2- 0.25102E-07 -7.6003 0.21383E-07 -7.6699 0.85185E+00 -0.0696 49 FeO+ 0.71276E-16 -16.1471 0.60807E-16 -16.2160 0.85313E+00 -0.0690 51 FeO2- 0.16835E-08 -8.7738 0.14341E-08 -8.8434 0.85185E+00 -0.0696 52 HFeO2,aq 0.16990E-10 -10.7698 0.16990E-10 -10.7698 0.10000E+01 0.0000 53 H2,aq 0.34014E-06 -6.4683 0.33930E-06 -6.4694 0.99751E+00 -0.0011 54 KCl,aq 0.20950E-09 -9.6788 0.20950E-09 -9.6788 0.10000E+01 0.0000 56 KOH,aq 0.44926E-06 -6.3475 0.44926E-06 -6.3475 0.10000E+01 0.0000 57 KSO4- 0.65014E-09 -9.1870 0.55382E-09 -9.2566 0.85185E+00 -0.0696 58 MgCO3,aq 0.16566E-12 -12.7808 0.16566E-12 -12.7808 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.17184E-14 -14.7649 0.14660E-14 -14.8339 0.85313E+00 -0.0690 60 MgCl+ 0.24666E-14 -14.6079 0.21043E-14 -14.6769 0.85313E+00 -0.0690 61 MgOH+ 0.60357E-10 -10.2193 0.51492E-10 -10.2883 0.85313E+00 -0.0690 63 MnO,aq 0.11510E-08 -8.9389 0.11510E-08 -8.9389 0.10000E+01 0.0000 64 MnOH+ 0.36693E-09 -9.4354 0.31304E-09 -9.5044 0.85313E+00 -0.0690 65 MnO2-2 0.78647E-11 -11.1043 0.44027E-11 -11.3563 0.55981E+00 -0.2520 66 HMnO2- 0.10547E-09 -9.9769 0.89845E-10 -10.0465 0.85185E+00 -0.0696 69 MnCl+ 0.82107E-14 -14.0856 0.70048E-14 -14.1546 0.85313E+00 -0.0690 70 MnSO4,aq 0.10139E-14 -14.9940 0.10139E-14 -14.9940 0.10000E+01 0.0000 71 NaCl,aq 0.48520E-06 -6.3141 0.48520E-06 -6.3141 0.10000E+01 0.0000 72 NaOH,aq 0.57247E-04 -4.2422 0.57247E-04 -4.2422 0.10000E+01 0.0000 74 OH- 0.72921E-02 -2.1371 0.62030E-02 -2.2074 0.85064E+00 -0.0703 79 HPO3-2 0.12762E-15 -15.8941 0.71445E-16 -16.1460 0.55981E+00 -0.2520 81 H2PO3- 0.15666E-19 -19.8051 0.13345E-19 -19.8747 0.85185E+00 -0.0696 82 H3PO4,aq 0.41001E-17 -17.3872 0.41001E-17 -17.3872 0.10000E+01 0.0000 83 H2PO4- 0.13619E-09 -9.8658 0.11610E-09 -9.9352 0.85248E+00 -0.0693 84 PO4-3 0.20685E-08 -8.6844 0.59187E-09 -9.2278 0.28614E+00 -0.5434 88 HP2O7-3 0.82221E-17 -17.0850 0.22658E-17 -17.6448 0.27558E+00 -0.5598 89 P2O7-4 0.55512E-16 -16.2556 0.58113E-17 -17.2357 0.10469E+00 -0.9801 90 H2S,aq 0.61546E-08 -8.2108 0.61393E-08 -8.2119 0.99751E+00 -0.0011 91 S2-2 0.53056E-13 -13.2753 0.29702E-13 -13.5272 0.55981E+00 -0.2520 97 SO3-2 0.28367E-13 -13.5472 0.16059E-13 -13.7943 0.56613E+00 -0.2471 98 HSO3- 0.10995E-15 -15.9588 0.93658E-16 -16.0285 0.85185E+00 -0.0696 99 HSO4- 0.38295E-13 -13.4169 0.32695E-13 -13.4855 0.85377E+00 -0.0687 101 S2O3-2 0.46921E-16 -16.3286 0.26267E-16 -16.5806 0.55981E+00 -0.2520 Charge balance for all species = -.1553E-12 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.1088303E-09 -.1582734E-01 -.1593377E+02 0.0000 2 H2O 0.1000000E+01 0.5550719E+02 0.9987725E+06 0.0000 3 Cl- 0.1384850E-03 0.1389704E-03 0.4920974E+01 6.1026 4 SO4-- 0.6495502E-06 0.5651190E-06 0.5422075E-01 13.6231 5 HCO3- 0.5419141E-05 0.1316437E-04 0.8022840E+00 4.6956 6 HS- 0.2503226E-04 0.2512350E-04 0.8298822E+00 5.3598 7 Al+++ 0.3976836E-28 0.1025792E-04 0.2764403E+00 1.1320 8 H4SiO4 0.6116419E-03 0.9040235E-02 0.8678577E+03 -3.2135 9 Ca++ 0.7952496E-07 0.1289785E-06 0.5162966E-02 12.7085 10 Mg++ 0.2189149E-10 0.8489577E-10 0.2061496E-05 9.1467 11 Fe++ 0.7642231E-13 0.2700990E-07 0.1506602E-02 6.6900 12 K+ 0.1148758E-03 0.1153259E-03 0.4504034E+01 6.0220 13 Na+ 0.1457108E-01 0.1585956E-01 0.3641683E+03 8.1246 14 Mn++ 0.1733085E-10 0.1648590E-08 0.9046097E-04 9.0459 15 HPO4-- 0.1204873E-06 0.1226920E-06 0.1176165E-01 12.8914 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.9934813E+00 -.1571388E-01 -.9777674E+00 0.0000000E+00 2 H2O 0.5475614E+02 0.5510929E+02 -.3531490E+00 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.1688281E-02 0.5610679E-06 0.1687720E-02 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.1662777E-02 0.2494340E-04 -.1687720E-02 0.0000000E+00 7 Al+++ 0.1956412E+00 0.1018439E-04 0.1956311E+00 0.0000000E+00 8 H4SiO4 0.6247566E+00 0.8975430E-02 0.6157811E+00 0.0000000E+00 9 Ca++ 0.6902188E-01 0.1280539E-06 0.6902175E-01 0.0000000E+00 10 Mg++ 0.4761825E-01 0.8428720E-10 0.4761825E-01 0.0000000E+00 11 Fe++ 0.4277980E-01 0.2681628E-07 0.4277978E-01 0.0000000E+00 12 K+ 0.1273864E-01 0.1144992E-03 0.1262414E-01 0.0000000E+00 13 Na+ 0.7547343E-01 0.1574587E-01 0.5972757E-01 0.0000000E+00 14 Mn++ 0.1040298E-02 0.1636772E-08 0.1040297E-02 0.0000000E+00 15 HPO4-- 0.3550487E-03 0.1218124E-06 0.3549269E-03 0.0000000E+00 Chg. balance for solid moles: -.9389E-16 Mass of aqueous solution: 0.994031E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 59.9990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 0.5973E-01 -1.224 15.66 1.195 23.91 6.012 andradite 0.6751E-02 -2.171 3.431 0.535 5.238 0.8913 grossular 0.7671E-03 -3.115 0.3455 -0.462 0.5276 0.9614E-01 apatite-OH 0.1183E-03 -3.927 0.5943E-01 -1.226 0.9074E-01 0.1888E-01 clinochlore 0.9524E-02 -2.021 5.294 0.724 8.083 2.014 daphnite 0.3491E-02 -2.457 2.491 0.396 3.803 0.7548 chlorite-Mn 0.2081E-03 -3.682 0.1475 -0.831 0.2252 0.4701E-01 microcline 0.1144E-01 -1.942 3.185 0.503 4.863 1.244 stilbite 0.4588E-01 -1.338 32.33 1.510 49.36 15.08 stilpnomelane-Fe 0.2364E-02 -2.626 2.549 0.406 3.892 0.8804 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8980E+00 0.8980E+00 1.0000 -0.047 grossular 0.1020E+00 0.1020E+00 1.0000 -0.991 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.7202E+00 0.7202E+00 1.0000 -0.143 daphnite 0.2640E+00 0.2640E+00 1.0000 -0.578 chlorite-Mn 0.1573E-01 0.1573E-01 1.0000 -1.803 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 65.492985 g Volume = 27.037657 cm3 Porosity: -8.1524% V(tot) - V(min): -.20381E+01 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 59.9990000 g log = 1.7781 Original solution: 1000.0103000 g Original solution / Rock added: 16.67 (Water/Rock Ratio), log = 1.2219 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0207 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9996E+00 0.9859 0.1006E+01 0.1020E+01 CO2,gas 0.9573E-07 1.0071 0.9841E-07 0.9772E-07 CH4,gas 0.3743E-06 1.0125 0.3869E-06 0.3821E-06 H2,gas 0.4362E-03 1.0005 0.4455E-03 0.4452E-03 H2S,gas 0.1660E-06 0.9960 0.1688E-06 0.1694E-06 S2,gas 0.5278E-26 1.0000 0.5388E-26 0.5388E-26 CO,gas 0.1145E-13 1.0000 0.1168E-13 0.1168E-13 SO3,gas 0.1171E-41 1.0000 0.1195E-41 0.1195E-41 SO2,gas 0.2029E-22 1.0000 0.2071E-22 0.2071E-22 HCl,gas 0.3481E-17 1.0000 0.3553E-17 0.3553E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 16 albite -0.38 -0.38 0.00 0.000 -0.94784E-12 22 andradite 39.01 39.01 0.00 0.000 0.00000E+00 23 grossular 32.73 32.73 0.00 0.000 0.48529E-10 32 apatite-OH -18.15 -18.15 0.00 0.000 -0.12132E-10 46 clinochlore 39.07 39.07 0.00 0.000 -0.24265E-10 47 daphnite 28.97 28.97 0.00 0.000 -0.30331E-10 48 chlorite-Mn 46.87 46.87 0.00 0.000 -0.48529E-10 116 microcline -2.49 -2.49 0.00 0.000 -0.10616E-10 163 stilbite -7.52 -7.52 0.00 0.000 -0.90992E-11 164 stilpnomelane-Fe 13.02 13.02 0.00 0.000 -0.27298E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -15.37 -8.71 -2.902 0.14865E+05 -7.007 3 CH4,gas 4.54 -3.57 -8.11 -2.028 0.13850E+05 -6.412 4 H2,gas 8.00 2.95 -5.05 -2.886 0.86230E+04 -3.351 5 H2S,gas -6.23 -14.70 -8.47 -4.236 0.14465E+05 -6.773 6 S2,gas -7.34 -35.30 -27.97 -4.303 0.47754E+05 -26.269 7 CO,gas 3.21 -12.42 -15.63 -4.810 0.26690E+05 -13.932 8 SO3,gas 17.12 -26.50 -43.62 -10.905 0.74483E+05 -41.923 9 SO2,gas 0.83 -23.55 -24.38 -6.502 0.41633E+05 -22.684 10 HCl,gas 5.19 -13.96 -19.15 -9.574 0.32695E+05 -17.449 11 acmite 7.71 6.91 -0.80 -0.083 0.13607E+04 15 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 19 spessartine 24.46 19.76 -4.70 -0.235 0.80186E+04 20 analcite 3.32 2.83 -0.49 -0.055 0.84046E+03 26 annite 20.12 17.58 -2.54 -0.141 0.43368E+04 27 phlogopite 27.06 24.95 -2.11 -0.117 0.36046E+04 29 anorthite 12.71 8.55 -4.16 -0.320 0.71114E+04 35 aragonite 0.97 -2.66 -3.62 -1.208 0.61881E+04 36 brucite 12.57 9.15 -3.42 -0.684 0.58428E+04 37 calcite 0.81 -2.66 -3.47 -1.156 0.59238E+04 38 carnegieite-low 9.02 6.04 -2.98 -0.426 0.50885E+04 39 carnegieite-high 10.09 6.04 -4.05 -0.579 0.69155E+04 40 carpholite-Mg 8.58 4.98 -3.60 -0.240 0.61442E+04 41 carpholite-Fe 6.71 2.53 -4.19 -0.279 0.71469E+04 42 celadonite 5.34 3.45 -1.89 -0.111 0.32355E+04 43 celadonite-Fe 3.88 0.99 -2.89 -0.170 0.49287E+04 44 chrysotile 23.89 21.01 -2.88 -0.240 0.49164E+04 51 chloritoid-Fe 9.17 5.74 -3.43 -0.229 0.58620E+04 52 chloritoid-Mn 11.40 8.10 -3.30 -0.220 0.56427E+04 54 coesite -2.38 -3.21 -0.84 -0.279 0.14299E+04 61 cristobalite -2.56 -3.21 -0.65 -0.218 0.11153E+04 63 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71234E+04 65 diaspore 2.87 1.13 -1.74 -0.290 0.29739E+04 67 diopside 16.18 15.43 -0.75 -0.075 0.12861E+04 68 hedenbergite 14.21 12.97 -1.24 -0.124 0.21118E+04 75 epidote 24.67 23.26 -1.41 -0.069 0.24149E+04 76 clinozoisite 22.81 19.17 -3.63 -0.165 0.62043E+04 77 epidote-Fe 29.84 27.34 -2.50 -0.130 0.42721E+04 78 fayalite 14.05 10.17 -3.88 -0.554 0.66237E+04 79 ferrosilite 11.15 6.95 -4.20 -0.420 0.71654E+04 83 gibbsite 4.08 1.13 -2.95 -0.421 0.50324E+04 84 glaucophane 22.97 20.25 -2.73 -0.074 0.46606E+04 85 glaucophane-Fe 17.28 12.88 -4.40 -0.119 0.75139E+04 87 greenalite 16.14 13.64 -2.50 -0.208 0.42627E+04 90 hematite 12.57 10.43 -2.14 -0.259 0.36468E+04 91 heulandite -5.83 -7.52 -1.69 -0.077 0.28938E+04 95 jadeite 4.22 2.83 -1.39 -0.139 0.23659E+04 96 julgoldite 70.43 65.79 -4.63 -0.120 0.79112E+04 97 kalsilite 7.58 3.94 -3.64 -0.520 0.62210E+04 98 kaolinite -1.33 -4.16 -2.83 -0.257 0.48325E+04 101 laumontite 2.88 2.12 -0.76 -0.051 0.13061E+04 102 lawsonite 9.62 8.55 -1.07 -0.071 0.18280E+04 103 leucite 4.12 0.73 -3.39 -0.339 0.57915E+04 105 lizardite 23.24 21.01 -2.23 -0.186 0.38090E+04 107 magnetite 20.09 17.12 -2.97 -0.242 0.50661E+04 108 minnesotaite 10.39 7.22 -3.17 -0.187 0.54163E+04 120 muscovite 2.58 -0.22 -2.80 -0.165 0.47893E+04 121 paragonite 4.24 1.88 -2.36 -0.139 0.40284E+04 122 nepheline 8.34 6.04 -2.30 -0.328 0.39209E+04 128 periclase-Fe 11.63 6.69 -4.94 -1.234 0.84291E+04 134 phlogopite-Na 29.65 27.06 -2.59 -0.144 0.44234E+04 136 prehnite 19.37 18.04 -1.33 -0.078 0.22734E+04 137 prehnite-Fe 22.50 22.12 -0.37 -0.023 0.63902E+03 138 pumpellyite-Fe 46.27 43.90 -2.37 -0.053 0.40409E+04 139 pumpellyite-Mg 48.99 46.36 -2.64 -0.059 0.44998E+04 142 pyrite -21.25 -25.66 -4.42 -1.039 0.75411E+04 143 pyrrhotite -4.26 -8.01 -3.75 -1.251 0.64058E+04 144 pyrrhotiteFe0.875 -6.02 -9.21 -3.20 -1.176 0.54588E+04 145 pyroxmangite 7.40 5.83 -1.57 -0.313 0.26744E+04 146 pyrophyllite -6.18 -10.59 -4.41 -0.276 0.75371E+04 147 quartz -2.99 -3.21 -0.22 -0.075 0.38259E+03 152 rhodonite 7.45 5.83 -1.61 -0.323 0.27547E+04 153 sanidine -1.28 -2.49 -1.21 -0.093 0.20677E+04 165 stilpnomelane-Mg 27.44 25.30 -2.14 -0.064 0.36557E+04 171 talc 16.49 14.59 -1.91 -0.112 0.32528E+04 174 tephroite 18.09 14.88 -3.21 -0.458 0.54768E+04 178 tridymite -2.63 -3.21 -0.59 -0.196 0.10026E+04 179 tremolite 47.87 45.44 -2.43 -0.066 0.41440E+04 181 troilite-low -4.41 -8.01 -3.60 -1.200 0.61486E+04 187 wairakite 3.95 2.12 -1.83 -0.108 0.31281E+04 188 walstromite 11.51 9.49 -2.01 -0.403 0.34393E+04 189 wollastonite 10.46 9.49 -0.97 -0.193 0.16497E+04 190 pseudo-wollastonite 11.00 9.49 -1.50 -0.301 0.25696E+04 191 zoisite 22.85 19.17 -3.68 -0.167 0.62783E+04 192 akaganeite 7.75 5.22 -2.54 -0.549 0.43359E+04 199 chalcedony -2.80 -3.21 -0.41 -0.137 0.70189E+03 201 montmorillonite-Ca -2.29 -5.85 -3.56 -0.220 0.60744E+04 202 montmorillonite-K -2.24 -5.96 -3.72 -0.228 0.63538E+04 203 montmorillonite-Mg -2.48 -6.44 -3.96 -0.245 0.67549E+04 204 montmorillonite-Na -2.04 -5.26 -3.23 -0.198 0.55087E+04 205 nontronite-Ca 3.21 1.11 -2.11 -0.137 0.35981E+04 206 nontronite-H 2.53 -0.99 -3.52 -0.236 0.60142E+04 207 nontronite-K 3.34 1.00 -2.34 -0.150 0.40007E+04 208 nontronite-Mg 3.07 0.52 -2.56 -0.166 0.43626E+04 209 nontronite-Na 3.52 1.69 -1.83 -0.117 0.31215E+04 224 tobermorite 9.82 7.37 -2.45 -0.669 0.41840E+04 230 alabandite -0.98 -5.66 -4.68 -1.559 0.79879E+04 233 boehmite 4.41 1.13 -3.27 -0.546 0.55908E+04 235 ferrous-oxide 9.81 6.69 -3.12 -0.780 0.53300E+04 240 silica-amorphous -2.09 -3.21 -1.12 -0.374 0.19161E+04 242 an20ab80 2.02 1.40 -0.62 -0.047 0.10514E+04 243 an25ab75 2.65 1.85 -0.80 -0.061 0.13613E+04 244 an30ab70 3.28 2.29 -0.98 -0.076 0.16807E+04 245 tr.625ac.25prg.125 45.16 43.47 -1.69 -0.046 0.28910E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 2.0000000 g Current total amount of reactant added: 59.9990000 g New total amount of reactant added: 61.9990000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.1494E-12 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 10 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 61.9990000 Water: Moles liquid = 0.5510E+02 kg liquid = 0.9926E+00 Moles total = 0.5473E+02 kg total = 0.9860E+00 Activity = 1.0000 Stoichiometric ionic strength = .8299776E-02 Osmotic coef. = 0.9658 True ionic strength = .1499521E-01 Chg. balance for total moles = -.1494E-12 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.10732E-09 -9.9693 0.91749E-10 -10.0374 0.85489E+00 -0.0681 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13851E-03 -3.8585 0.11784E-03 -3.9287 0.85080E+00 -0.0702 4 SO4-- 0.26952E-06 -6.5694 0.15041E-06 -6.8227 0.55806E+00 -0.2533 5 HCO3- 0.53607E-05 -5.2708 0.45662E-05 -5.3404 0.85179E+00 -0.0697 6 HS- 0.25419E-04 -4.5948 0.21629E-04 -4.6650 0.85090E+00 -0.0701 7 Al+++ 0.36196E-28 -28.4413 0.98592E-29 -29.0062 0.27239E+00 -0.5648 8 H4SiO4 0.61689E-03 -3.2098 0.61689E-03 -3.2098 0.10000E+01 0.0000 9 Ca++ 0.82310E-07 -7.0845 0.45667E-07 -7.3404 0.55482E+00 -0.2558 10 Mg++ 0.21843E-10 -10.6607 0.12075E-10 -10.9181 0.55281E+00 -0.2574 11 Fe++ 0.75026E-13 -13.1248 0.41511E-13 -13.3818 0.55329E+00 -0.2570 12 K+ 0.11723E-03 -3.9310 0.99871E-04 -4.0006 0.85195E+00 -0.0696 13 Na+ 0.14869E-01 -1.8277 0.12649E-01 -1.8979 0.85069E+00 -0.0702 14 Mn++ 0.17292E-10 -10.7622 0.95738E-11 -11.0189 0.55365E+00 -0.2568 15 HPO4-- 0.11295E-06 -6.9471 0.63042E-07 -7.2004 0.55813E+00 -0.2533 16 HSiO3- 0.73791E-02 -2.1320 0.62782E-02 -2.2022 0.85080E+00 -0.0702 17 Ca(HSiO3)+ 0.76627E-08 -8.1156 0.65294E-08 -8.1851 0.85210E+00 -0.0695 18 Mg(HSiO3)+ 0.25216E-11 -11.5983 0.21486E-11 -11.6678 0.85210E+00 -0.0695 19 NaHSiO3,aq 0.12844E-02 -2.8913 0.12844E-02 -2.8913 0.10000E+01 0.0000 20 AlO+ 0.18699E-15 -15.7282 0.15934E-15 -15.7977 0.85210E+00 -0.0695 22 HAlO2,aq 0.34585E-09 -9.4611 0.34585E-09 -9.4611 0.10000E+01 0.0000 23 AlO2- 0.98216E-05 -5.0078 0.83442E-05 -5.0786 0.84958E+00 -0.0708 24 CH4,aq 0.63944E-09 -9.1942 0.63781E-09 -9.1953 0.99746E+00 -0.0011 29 CO,aq 0.95877E-17 -17.0183 0.95877E-17 -17.0183 0.10000E+01 0.0000 30 CO2,aq 0.89746E-09 -9.0470 0.89518E-09 -9.0481 0.99746E+00 -0.0011 31 CO3-2 0.78027E-05 -5.1078 0.43470E-05 -5.3618 0.55712E+00 -0.2540 32 CaCO3,aq 0.24892E-08 -8.6039 0.24892E-08 -8.6039 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.62467E-11 -11.2044 0.53228E-11 -11.2739 0.85210E+00 -0.0695 34 CaCl+ 0.10221E-10 -10.9905 0.87090E-11 -11.0600 0.85210E+00 -0.0695 35 CaCl2,aq 0.24383E-15 -15.6129 0.24383E-15 -15.6129 0.10000E+01 0.0000 36 CaOH+ 0.41631E-07 -7.3806 0.35474E-07 -7.4501 0.85210E+00 -0.0695 37 CaSO4,aq 0.21812E-11 -11.6613 0.21812E-11 -11.6613 0.10000E+01 0.0000 38 HCl,aq 0.19812E-14 -14.7031 0.19812E-14 -14.7031 0.10000E+01 0.0000 43 FeCl+ 0.90868E-17 -17.0416 0.77428E-17 -17.1111 0.85210E+00 -0.0695 46 FeO,aq 0.19166E-09 -9.7175 0.19166E-09 -9.7175 0.10000E+01 0.0000 47 FeOH+ 0.17284E-10 -10.7624 0.14727E-10 -10.8319 0.85210E+00 -0.0695 48 HFeO2- 0.25689E-07 -7.5902 0.21857E-07 -7.6604 0.85080E+00 -0.0702 49 FeO+ 0.63136E-16 -16.1997 0.53798E-16 -16.2692 0.85210E+00 -0.0695 51 FeO2- 0.15370E-08 -8.8133 0.13077E-08 -8.8835 0.85080E+00 -0.0702 52 HFeO2,aq 0.15260E-10 -10.8165 0.15260E-10 -10.8165 0.10000E+01 0.0000 53 H2,aq 0.42744E-06 -6.3691 0.42635E-06 -6.3702 0.99746E+00 -0.0011 54 KCl,aq 0.21330E-09 -9.6710 0.21330E-09 -9.6710 0.10000E+01 0.0000 56 KOH,aq 0.46486E-06 -6.3327 0.46486E-06 -6.3327 0.10000E+01 0.0000 57 KSO4- 0.27397E-09 -9.5623 0.23310E-09 -9.6325 0.85080E+00 -0.0702 58 MgCO3,aq 0.16498E-12 -12.7826 0.16498E-12 -12.7826 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.16877E-14 -14.7727 0.14381E-14 -14.8422 0.85210E+00 -0.0695 60 MgCl+ 0.24494E-14 -14.6109 0.20871E-14 -14.6805 0.85210E+00 -0.0695 61 MgOH+ 0.60912E-10 -10.2153 0.51903E-10 -10.2848 0.85210E+00 -0.0695 63 MnO,aq 0.11778E-08 -8.9289 0.11778E-08 -8.9289 0.10000E+01 0.0000 64 MnOH+ 0.37030E-09 -9.4314 0.31554E-09 -9.5010 0.85210E+00 -0.0695 65 MnO2-2 0.83348E-11 -11.0791 0.46435E-11 -11.3332 0.55712E+00 -0.2540 66 HMnO2- 0.10971E-09 -9.9598 0.93337E-10 -10.0299 0.85080E+00 -0.0702 69 MnCl+ 0.81533E-14 -14.0887 0.69474E-14 -14.1582 0.85210E+00 -0.0695 70 MnSO4,aq 0.41571E-15 -15.3812 0.41571E-15 -15.3812 0.10000E+01 0.0000 71 NaCl,aq 0.49400E-06 -6.3063 0.49400E-06 -6.3063 0.10000E+01 0.0000 72 NaOH,aq 0.59235E-04 -4.2274 0.59235E-04 -4.2274 0.10000E+01 0.0000 74 OH- 0.74123E-02 -2.1300 0.62973E-02 -2.2008 0.84958E+00 -0.0708 79 HPO3-2 0.15035E-15 -15.8229 0.83762E-16 -16.0770 0.55712E+00 -0.2540 81 H2PO3- 0.18113E-19 -19.7420 0.15411E-19 -19.8122 0.85080E+00 -0.0702 82 H3PO4,aq 0.37116E-17 -17.4304 0.37116E-17 -17.4304 0.10000E+01 0.0000 83 H2PO4- 0.12532E-09 -9.9020 0.10670E-09 -9.9718 0.85144E+00 -0.0698 84 PO4-3 0.19795E-08 -8.7034 0.56061E-09 -9.2513 0.28320E+00 -0.5479 88 HP2O7-3 0.71274E-17 -17.1471 0.19428E-17 -17.7116 0.27258E+00 -0.5645 89 P2O7-4 0.49253E-16 -16.3076 0.50587E-17 -17.2960 0.10271E+00 -0.9884 90 H2S,aq 0.61487E-08 -8.2112 0.61330E-08 -8.2123 0.99746E+00 -0.0011 91 S2-2 0.43638E-13 -13.3601 0.24312E-13 -13.6142 0.55712E+00 -0.2540 97 SO3-2 0.14788E-13 -13.8301 0.83334E-14 -14.0792 0.56352E+00 -0.2491 98 HSO3- 0.56267E-16 -16.2497 0.47872E-16 -16.3199 0.85080E+00 -0.0702 99 HSO4- 0.15596E-13 -13.8070 0.13299E-13 -13.8762 0.85275E+00 -0.0692 101 S2O3-2 0.19450E-16 -16.7111 0.10836E-16 -16.9651 0.55712E+00 -0.2540 Charge balance for all species = -.1555E-12 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.1073230E-09 -.1618288E-01 -.1629122E+02 0.0000 2 H2O 0.1000000E+01 0.5550708E+02 0.9987416E+06 0.0000 3 Cl- 0.1385077E-03 0.1390019E-03 0.4921950E+01 6.1087 4 SO4-- 0.2695211E-06 0.1624914E-06 0.1558990E-01 13.2521 5 HCO3- 0.5360669E-05 0.1316736E-04 0.8024430E+00 4.6969 6 HS- 0.2541851E-04 0.2553196E-04 0.8433501E+00 5.3724 7 Al+++ 0.3619557E-28 0.9821963E-05 0.2646840E+00 1.1060 8 H4SiO4 0.6168922E-03 0.9280457E-02 0.8908932E+03 -3.2098 9 Ca++ 0.8230958E-07 0.1341112E-06 0.5368270E-02 12.7344 10 Mg++ 0.2184308E-10 0.8544553E-10 0.2074786E-05 9.1567 11 Fe++ 0.7502559E-13 0.2745074E-07 0.1531148E-02 6.6930 12 K+ 0.1172256E-03 0.1176910E-03 0.4596268E+01 6.0368 13 Na+ 0.1486950E-01 0.1621365E-01 0.3722882E+03 8.1395 14 Mn++ 0.1729209E-10 0.1683454E-08 0.9237138E-04 9.0559 15 HPO4-- 0.1129534E-06 0.1150582E-06 0.1102953E-01 12.8744 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.1026598E+01 -.1606322E-01 -.1010535E+01 0.0000000E+00 2 H2O 0.5473107E+02 0.5509667E+02 -.3655986E+00 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.1743708E-02 0.1612899E-06 0.1743547E-02 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.1718204E-02 0.2534318E-04 -.1743547E-02 0.0000000E+00 7 Al+++ 0.2021627E+00 0.9749340E-05 0.2021530E+00 0.0000000E+00 8 H4SiO4 0.6455821E+00 0.9211839E-02 0.6363703E+00 0.0000000E+00 9 Ca++ 0.7132217E-01 0.1331196E-06 0.7132203E-01 0.0000000E+00 10 Mg++ 0.4920556E-01 0.8481375E-10 0.4920556E-01 0.0000000E+00 11 Fe++ 0.4420582E-01 0.2724778E-07 0.4420579E-01 0.0000000E+00 12 K+ 0.1316327E-01 0.1168208E-03 0.1304645E-01 0.0000000E+00 13 Na+ 0.7798392E-01 0.1609377E-01 0.6189015E-01 0.0000000E+00 14 Mn++ 0.1074976E-02 0.1671007E-08 0.1074974E-02 0.0000000E+00 15 HPO4-- 0.3668838E-03 0.1142075E-06 0.3667696E-03 0.0000000E+00 Chg. balance for solid moles: -.9758E-18 Mass of aqueous solution: 0.993834E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 61.9990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 0.6189E-01 -1.208 16.23 1.210 23.98 6.230 andradite 0.6974E-02 -2.157 3.544 0.550 5.237 0.9208 grossular 0.8311E-03 -3.080 0.3743 -0.427 0.5532 0.1042 apatite-OH 0.1223E-03 -3.913 0.6141E-01 -1.212 0.9075E-01 0.1951E-01 clinochlore 0.9841E-02 -2.007 5.470 0.738 8.083 2.081 daphnite 0.3550E-02 -2.450 2.533 0.404 3.742 0.7675 chlorite-Mn 0.2150E-03 -3.668 0.1524 -0.817 0.2252 0.4857E-01 microcline 0.1180E-01 -1.928 3.283 0.516 4.851 1.282 stilbite 0.4730E-01 -1.325 33.33 1.523 49.25 15.55 stilpnomelane-Fe 0.2502E-02 -2.602 2.697 0.431 3.985 0.9316 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8935E+00 0.8935E+00 1.0000 -0.049 grossular 0.1065E+00 0.1065E+00 1.0000 -0.973 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.7233E+00 0.7233E+00 1.0000 -0.141 daphnite 0.2609E+00 0.2609E+00 1.0000 -0.584 chlorite-Mn 0.1580E-01 0.1580E-01 1.0000 -1.801 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 67.673748 g Volume = 27.930723 cm3 Porosity: -8.2603% V(tot) - V(min): -.21311E+01 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 61.9990000 g log = 1.7924 Original solution: 1000.0103000 g Original solution / Rock added: 16.13 (Water/Rock Ratio), log = 1.2076 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0209 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9995E+00 0.9859 0.1006E+01 0.1020E+01 CO2,gas 0.9316E-07 1.0071 0.9577E-07 0.9510E-07 CH4,gas 0.9082E-06 1.0125 0.9388E-06 0.9272E-06 H2,gas 0.5480E-03 1.0005 0.5598E-03 0.5594E-03 H2S,gas 0.1658E-06 0.9960 0.1686E-06 0.1693E-06 S2,gas 0.3336E-26 1.0000 0.3405E-26 0.3405E-26 CO,gas 0.1400E-13 1.0000 0.1429E-13 0.1429E-13 SO3,gas 0.4689E-42 1.0000 0.4787E-42 0.4787E-42 SO2,gas 0.1021E-22 1.0000 0.1043E-22 0.1043E-22 HCl,gas 0.3425E-17 1.0000 0.3496E-17 0.3496E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 16 albite -0.38 -0.38 0.00 0.000 -0.94784E-12 22 andradite 39.01 39.01 0.00 0.000 0.24265E-10 23 grossular 32.73 32.73 0.00 0.000 -0.36397E-10 32 apatite-OH -18.15 -18.15 0.00 0.000 -0.60662E-11 46 clinochlore 39.07 39.07 0.00 0.000 -0.48529E-10 47 daphnite 28.97 28.97 0.00 0.000 -0.12132E-10 48 chlorite-Mn 46.87 46.87 0.00 0.000 -0.36397E-10 116 microcline -2.49 -2.49 0.00 0.000 -0.10616E-10 163 stilbite -7.52 -7.52 0.00 0.000 -0.33364E-10 164 stilpnomelane-Fe 13.02 13.02 0.00 0.000 0.21232E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -15.38 -8.72 -2.906 0.14885E+05 -7.019 3 CH4,gas 4.54 -3.18 -7.73 -1.932 0.13193E+05 -6.027 4 H2,gas 8.00 3.05 -4.95 -2.829 0.84537E+04 -3.252 5 H2S,gas -6.23 -14.70 -8.47 -4.236 0.14466E+05 -6.773 6 S2,gas -7.34 -35.50 -28.17 -4.333 0.48094E+05 -26.468 7 CO,gas 3.21 -12.33 -15.54 -4.783 0.26541E+05 -13.845 8 SO3,gas 17.12 -26.90 -44.02 -11.005 0.75161E+05 -42.320 9 SO2,gas 0.83 -23.85 -24.68 -6.582 0.42142E+05 -22.982 10 HCl,gas 5.19 -13.97 -19.16 -9.578 0.32707E+05 -17.456 11 acmite 7.71 6.89 -0.82 -0.085 0.14023E+04 15 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 19 spessartine 24.46 19.75 -4.71 -0.235 0.80370E+04 20 analcite 3.32 2.83 -0.50 -0.055 0.84680E+03 26 annite 20.12 17.59 -2.53 -0.141 0.43216E+04 27 phlogopite 27.06 24.98 -2.08 -0.116 0.35533E+04 29 anorthite 12.71 8.53 -4.18 -0.322 0.71431E+04 35 aragonite 0.97 -2.64 -3.61 -1.203 0.61639E+04 36 brucite 12.57 9.16 -3.41 -0.682 0.58257E+04 37 calcite 0.81 -2.64 -3.46 -1.152 0.58997E+04 38 carnegieite-low 9.02 6.04 -2.99 -0.427 0.51012E+04 39 carnegieite-high 10.09 6.04 -4.06 -0.580 0.69282E+04 40 carpholite-Mg 8.58 4.95 -3.63 -0.242 0.62031E+04 41 carpholite-Fe 6.71 2.49 -4.23 -0.282 0.72178E+04 42 celadonite 5.34 3.46 -1.88 -0.111 0.32121E+04 43 celadonite-Fe 3.88 1.00 -2.88 -0.169 0.49173E+04 44 chrysotile 23.89 21.05 -2.84 -0.237 0.48525E+04 51 chloritoid-Fe 9.17 5.70 -3.48 -0.232 0.59392E+04 52 chloritoid-Mn 11.40 8.06 -3.34 -0.223 0.57079E+04 54 coesite -2.38 -3.21 -0.83 -0.278 0.14236E+04 61 cristobalite -2.56 -3.21 -0.65 -0.216 0.11089E+04 63 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71234E+04 65 diaspore 2.87 1.11 -1.77 -0.295 0.30182E+04 67 diopside 16.18 15.47 -0.71 -0.071 0.12121E+04 68 hedenbergite 14.21 13.01 -1.20 -0.120 0.20498E+04 75 epidote 24.67 23.22 -1.45 -0.070 0.24756E+04 76 clinozoisite 22.81 19.16 -3.65 -0.166 0.62297E+04 77 epidote-Fe 29.84 27.28 -2.56 -0.133 0.43681E+04 78 fayalite 14.05 10.18 -3.87 -0.553 0.66072E+04 79 ferrosilite 11.15 6.97 -4.18 -0.418 0.71426E+04 83 gibbsite 4.08 1.11 -2.97 -0.425 0.50768E+04 84 glaucophane 22.97 20.28 -2.69 -0.073 0.45966E+04 85 glaucophane-Fe 17.28 12.89 -4.38 -0.118 0.74860E+04 87 greenalite 16.14 13.66 -2.48 -0.207 0.42349E+04 90 hematite 12.57 10.34 -2.23 -0.270 0.38060E+04 91 heulandite -5.83 -7.52 -1.69 -0.077 0.28938E+04 95 jadeite 4.22 2.83 -1.39 -0.139 0.23723E+04 96 julgoldite 70.43 65.74 -4.69 -0.122 0.80044E+04 97 kalsilite 7.58 3.93 -3.65 -0.522 0.62337E+04 98 kaolinite -1.33 -4.21 -2.87 -0.261 0.49085E+04 101 laumontite 2.88 2.11 -0.78 -0.052 0.13252E+04 102 lawsonite 9.62 8.53 -1.09 -0.073 0.18597E+04 103 leucite 4.12 0.72 -3.40 -0.340 0.57978E+04 105 lizardite 23.24 21.05 -2.19 -0.183 0.37451E+04 107 magnetite 20.09 17.03 -3.06 -0.250 0.52203E+04 108 minnesotaite 10.39 7.24 -3.15 -0.185 0.53758E+04 120 muscovite 2.58 -0.27 -2.86 -0.168 0.48780E+04 121 paragonite 4.24 1.83 -2.41 -0.142 0.41171E+04 122 nepheline 8.34 6.04 -2.30 -0.329 0.39336E+04 128 periclase-Fe 11.63 6.69 -4.93 -1.233 0.84240E+04 134 phlogopite-Na 29.65 27.09 -2.56 -0.142 0.43721E+04 136 prehnite 19.37 18.05 -1.32 -0.078 0.22545E+04 137 prehnite-Fe 22.50 22.11 -0.38 -0.023 0.65537E+03 138 pumpellyite-Fe 46.27 43.90 -2.37 -0.053 0.40423E+04 139 pumpellyite-Mg 48.99 46.37 -2.63 -0.058 0.44892E+04 142 pyrite -21.25 -25.76 -4.51 -1.062 0.77069E+04 143 pyrrhotite -4.26 -8.01 -3.75 -1.250 0.64015E+04 144 pyrrhotiteFe0.875 -6.02 -9.22 -3.21 -1.180 0.54761E+04 145 pyroxmangite 7.40 5.85 -1.55 -0.311 0.26510E+04 146 pyrophyllite -6.18 -10.63 -4.45 -0.278 0.76004E+04 147 quartz -2.99 -3.21 -0.22 -0.073 0.37625E+03 152 rhodonite 7.45 5.85 -1.60 -0.320 0.27313E+04 153 sanidine -1.28 -2.49 -1.21 -0.093 0.20677E+04 165 stilpnomelane-Mg 27.44 25.34 -2.11 -0.063 0.35956E+04 171 talc 16.49 14.63 -1.86 -0.109 0.31762E+04 174 tephroite 18.09 14.90 -3.18 -0.455 0.54363E+04 178 tridymite -2.63 -3.21 -0.58 -0.194 0.99623E+03 179 tremolite 47.87 45.57 -2.30 -0.062 0.39192E+04 181 troilite-low -4.41 -8.01 -3.60 -1.199 0.61443E+04 187 wairakite 3.95 2.11 -1.84 -0.108 0.31471E+04 188 walstromite 11.51 9.52 -1.98 -0.397 0.33887E+04 189 wollastonite 10.46 9.52 -0.94 -0.187 0.15991E+04 190 pseudo-wollastonite 11.00 9.52 -1.48 -0.295 0.25189E+04 191 zoisite 22.85 19.16 -3.69 -0.168 0.63037E+04 192 akaganeite 7.75 5.17 -2.59 -0.559 0.44156E+04 199 chalcedony -2.80 -3.21 -0.41 -0.136 0.69555E+03 201 montmorillonite-Ca -2.29 -5.87 -3.58 -0.221 0.61101E+04 202 montmorillonite-K -2.24 -5.98 -3.74 -0.229 0.63885E+04 203 montmorillonite-Mg -2.48 -6.46 -3.98 -0.246 0.67951E+04 204 montmorillonite-Na -2.04 -5.28 -3.25 -0.199 0.55434E+04 205 nontronite-Ca 3.21 1.02 -2.19 -0.142 0.37414E+04 206 nontronite-H 2.53 -1.08 -3.61 -0.242 0.61648E+04 207 nontronite-K 3.34 0.91 -2.43 -0.156 0.41429E+04 208 nontronite-Mg 3.07 0.43 -2.64 -0.171 0.45104E+04 209 nontronite-Na 3.52 1.61 -1.91 -0.123 0.32638E+04 224 tobermorite 9.82 7.40 -2.43 -0.662 0.41408E+04 230 alabandite -0.98 -5.65 -4.67 -1.556 0.79715E+04 233 boehmite 4.41 1.11 -3.30 -0.550 0.56351E+04 235 ferrous-oxide 9.81 6.69 -3.12 -0.780 0.53250E+04 240 silica-amorphous -2.09 -3.21 -1.12 -0.373 0.19097E+04 242 an20ab80 2.02 1.40 -0.62 -0.048 0.10578E+04 243 an25ab75 2.65 1.84 -0.80 -0.062 0.13692E+04 244 an30ab70 3.28 2.29 -0.99 -0.076 0.16902E+04 245 tr.625ac.25prg.125 45.16 43.58 -1.58 -0.043 0.26985E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 2.0000000 g Current total amount of reactant added: 61.9990000 g New total amount of reactant added: 63.9990000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.1495E-12 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 10 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 63.9990000 Water: Moles liquid = 0.5509E+02 kg liquid = 0.9924E+00 Moles total = 0.5471E+02 kg total = 0.9855E+00 Activity = 1.0000 Stoichiometric ionic strength = .8474580E-02 Osmotic coef. = 0.9657 True ionic strength = .1529253E-01 Chg. balance for total moles = -.1495E-12 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.10590E-09 -9.9751 0.90434E-10 -10.0437 0.85393E+00 -0.0686 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13853E-03 -3.8585 0.11772E-03 -3.9291 0.84978E+00 -0.0707 4 SO4-- 0.11457E-06 -6.9409 0.63638E-07 -7.1963 0.55546E+00 -0.2553 5 HCO3- 0.53045E-05 -5.2754 0.45130E-05 -5.3455 0.85078E+00 -0.0702 6 HS- 0.25580E-04 -4.5921 0.21740E-04 -4.6627 0.84988E+00 -0.0706 7 Al+++ 0.33039E-28 -28.4810 0.89037E-29 -29.0504 0.26949E+00 -0.5695 8 H4SiO4 0.62221E-03 -3.2061 0.62221E-03 -3.2061 0.10000E+01 0.0000 9 Ca++ 0.85078E-07 -7.0702 0.46979E-07 -7.3281 0.55218E+00 -0.2579 10 Mg++ 0.21808E-10 -10.6614 0.11998E-10 -10.9209 0.55015E+00 -0.2595 11 Fe++ 0.73715E-13 -13.1324 0.40590E-13 -13.3916 0.55063E+00 -0.2591 12 K+ 0.11955E-03 -3.9225 0.10173E-03 -3.9926 0.85095E+00 -0.0701 13 Na+ 0.15165E-01 -1.8192 0.12885E-01 -1.8899 0.84966E+00 -0.0708 14 Mn++ 0.17264E-10 -10.7629 0.95126E-11 -11.0217 0.55100E+00 -0.2588 15 HPO4-- 0.10619E-06 -6.9739 0.58990E-07 -7.2292 0.55552E+00 -0.2553 16 HSiO3- 0.75600E-02 -2.1215 0.64244E-02 -2.1922 0.84978E+00 -0.0707 17 Ca(HSiO3)+ 0.80759E-08 -8.0928 0.68733E-08 -8.1628 0.85110E+00 -0.0700 18 Mg(HSiO3)+ 0.25668E-11 -11.5906 0.21846E-11 -11.6606 0.85110E+00 -0.0700 19 NaHSiO3,aq 0.13388E-02 -2.8733 0.13388E-02 -2.8733 0.10000E+01 0.0000 20 AlO+ 0.17402E-15 -15.7594 0.14811E-15 -15.8294 0.85110E+00 -0.0700 22 HAlO2,aq 0.32616E-09 -9.4866 0.32616E-09 -9.4866 0.10000E+01 0.0000 23 AlO2- 0.94086E-05 -5.0265 0.79835E-05 -5.0978 0.84854E+00 -0.0713 24 CH4,aq 0.15015E-08 -8.8235 0.14976E-08 -8.8246 0.99740E+00 -0.0011 29 CO,aq 0.11638E-16 -16.9341 0.11638E-16 -16.9341 0.10000E+01 0.0000 30 CO2,aq 0.87434E-09 -9.0583 0.87207E-09 -9.0594 0.99740E+00 -0.0011 31 CO3-2 0.78609E-05 -5.1045 0.43589E-05 -5.3606 0.55451E+00 -0.2561 32 CaCO3,aq 0.25677E-08 -8.5905 0.25677E-08 -8.5905 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.63587E-11 -11.1966 0.54119E-11 -11.2667 0.85110E+00 -0.0700 34 CaCl+ 0.10516E-10 -10.9782 0.89499E-11 -11.0482 0.85110E+00 -0.0700 35 CaCl2,aq 0.25031E-15 -15.6015 0.25031E-15 -15.6015 0.10000E+01 0.0000 36 CaOH+ 0.43501E-07 -7.3615 0.37023E-07 -7.4315 0.85110E+00 -0.0700 37 CaSO4,aq 0.94934E-12 -12.0226 0.94934E-12 -12.0226 0.10000E+01 0.0000 38 HCl,aq 0.19508E-14 -14.7098 0.19508E-14 -14.7098 0.10000E+01 0.0000 43 FeCl+ 0.88864E-17 -17.0513 0.75631E-17 -17.1213 0.85110E+00 -0.0700 46 FeO,aq 0.19289E-09 -9.7147 0.19289E-09 -9.7147 0.10000E+01 0.0000 47 FeOH+ 0.17166E-10 -10.7653 0.14610E-10 -10.8354 0.85110E+00 -0.0700 48 HFeO2- 0.26263E-07 -7.5807 0.22318E-07 -7.6514 0.84978E+00 -0.0707 49 FeO+ 0.56176E-16 -16.2504 0.47811E-16 -16.3205 0.85110E+00 -0.0700 51 FeO2- 0.14077E-08 -8.8515 0.11962E-08 -8.9222 0.84978E+00 -0.0707 52 HFeO2,aq 0.13759E-10 -10.8614 0.13759E-10 -10.8614 0.10000E+01 0.0000 53 H2,aq 0.53261E-06 -6.2736 0.53123E-06 -6.2747 0.99740E+00 -0.0011 54 KCl,aq 0.21705E-09 -9.6634 0.21705E-09 -9.6634 0.10000E+01 0.0000 56 KOH,aq 0.48040E-06 -6.3184 0.48040E-06 -6.3184 0.10000E+01 0.0000 57 KSO4- 0.11822E-09 -9.9273 0.10046E-09 -9.9980 0.84978E+00 -0.0707 58 MgCO3,aq 0.16437E-12 -12.7842 0.16437E-12 -12.7842 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.16594E-14 -14.7801 0.14123E-14 -14.8501 0.85110E+00 -0.0700 60 MgCl+ 0.24341E-14 -14.6137 0.20716E-14 -14.6837 0.85110E+00 -0.0700 61 MgOH+ 0.61475E-10 -10.2113 0.52321E-10 -10.2813 0.85110E+00 -0.0700 63 MnO,aq 0.12046E-08 -8.9192 0.12046E-08 -8.9192 0.10000E+01 0.0000 64 MnOH+ 0.37373E-09 -9.4274 0.31808E-09 -9.4975 0.85110E+00 -0.0700 65 MnO2-2 0.88151E-11 -11.0548 0.48881E-11 -11.3109 0.55451E+00 -0.2561 66 HMnO2- 0.11397E-09 -9.9432 0.96845E-10 -10.0139 0.84978E+00 -0.0707 69 MnCl+ 0.81023E-14 -14.0914 0.68958E-14 -14.1614 0.85110E+00 -0.0700 70 MnSO4,aq 0.17476E-15 -15.7576 0.17476E-15 -15.7576 0.10000E+01 0.0000 71 NaCl,aq 0.50267E-06 -6.2987 0.50267E-06 -6.2987 0.10000E+01 0.0000 72 NaOH,aq 0.61215E-04 -4.2131 0.61215E-04 -4.2131 0.10000E+01 0.0000 74 OH- 0.75293E-02 -2.1232 0.63889E-02 -2.1946 0.84854E+00 -0.0713 79 HPO3-2 0.17612E-15 -15.7542 0.97658E-16 -16.0103 0.55451E+00 -0.2561 81 H2PO3- 0.20841E-19 -19.6811 0.17710E-19 -19.7518 0.84978E+00 -0.0707 82 H3PO4,aq 0.33741E-17 -17.4718 0.33741E-17 -17.4718 0.10000E+01 0.0000 83 H2PO4- 0.11572E-09 -9.9366 0.98411E-10 -10.0070 0.85043E+00 -0.0704 84 PO4-3 0.18982E-08 -8.7217 0.53221E-09 -9.2739 0.28037E+00 -0.5523 88 HP2O7-3 0.62171E-17 -17.2064 0.16767E-17 -17.7755 0.26969E+00 -0.5691 89 P2O7-4 0.43936E-16 -16.3572 0.44292E-17 -17.3537 0.10081E+00 -0.9965 90 H2S,aq 0.60919E-08 -8.2152 0.60761E-08 -8.2164 0.99740E+00 -0.0011 91 S2-2 0.35550E-13 -13.4492 0.19713E-13 -13.7053 0.55451E+00 -0.2561 97 SO3-2 0.78312E-14 -14.1062 0.43931E-14 -14.3572 0.56098E+00 -0.2511 98 HSO3- 0.29272E-16 -16.5335 0.24875E-16 -16.6042 0.84978E+00 -0.0707 99 HSO4- 0.65115E-14 -14.1863 0.55462E-14 -14.2560 0.85176E+00 -0.0697 101 S2O3-2 0.81913E-17 -17.0866 0.45422E-17 -17.3427 0.55451E+00 -0.2561 Charge balance for all species = -.1516E-12 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.1059037E-09 -.1653560E-01 -.1664583E+02 0.0000 2 H2O 0.1000000E+01 0.5550696E+02 0.9987108E+06 0.0000 3 Cl- 0.1385306E-03 0.1390335E-03 0.4922924E+01 6.1145 4 SO4-- 0.1145674E-06 -.1979093E-07 -.1898746E-02 12.8911 5 HCO3- 0.5304541E-05 0.1317034E-04 0.8026019E+00 4.6981 6 HS- 0.2557950E-04 0.2572007E-04 0.8495392E+00 5.3809 7 Al+++ 0.3303884E-28 0.9408902E-05 0.2535455E+00 1.0806 8 H4SiO4 0.6222084E-03 0.9521057E-02 0.9139636E+03 -3.2061 9 Ca++ 0.8507808E-07 0.1392400E-06 0.5573406E-02 12.7592 10 Mg++ 0.2180840E-10 0.8601827E-10 0.2088633E-05 9.1664 11 Fe++ 0.7371462E-13 0.2789437E-07 0.1555848E-02 6.6958 12 K+ 0.1195491E-03 0.1200298E-03 0.4687474E+01 6.0511 13 Na+ 0.1516459E-01 0.1656510E-01 0.3803471E+03 8.1537 14 Mn++ 0.1726422E-10 0.1718339E-08 0.9428280E-04 9.0656 15 HPO4-- 0.1061879E-06 0.1082019E-06 0.1037198E-01 12.8581 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.1059715E+01 -.1640961E-01 -.1043306E+01 0.0000000E+00 2 H2O 0.5470600E+02 0.5508406E+02 -.3780607E+00 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.1799135E-02 -.1964015E-07 0.1799155E-02 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.1773630E-02 0.2552411E-04 -.1799155E-02 0.0000000E+00 7 Al+++ 0.2086842E+00 0.9337216E-05 0.2086749E+00 0.0000000E+00 8 H4SiO4 0.6664077E+00 0.9448516E-02 0.6569592E+00 0.0000000E+00 9 Ca++ 0.7362245E-01 0.1381791E-06 0.7362231E-01 0.0000000E+00 10 Mg++ 0.5079286E-01 0.8536290E-10 0.5079286E-01 0.0000000E+00 11 Fe++ 0.4563184E-01 0.2768184E-07 0.4563181E-01 0.0000000E+00 12 K+ 0.1358790E-01 0.1191153E-03 0.1346878E-01 0.0000000E+00 13 Na+ 0.8049441E-01 0.1643890E-01 0.6405551E-01 0.0000000E+00 14 Mn++ 0.1109653E-02 0.1705247E-08 0.1109651E-02 0.0000000E+00 15 HPO4-- 0.3787190E-03 0.1073775E-06 0.3786116E-03 0.0000000E+00 Chg. balance for solid moles: 0.7741E-16 Mass of aqueous solution: 0.993637E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 63.9990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 0.6406E-01 -1.193 16.80 1.225 24.05 6.448 andradite 0.7197E-02 -2.143 3.657 0.563 5.235 0.9502 grossular 0.8969E-03 -3.047 0.4040 -0.394 0.5784 0.1124 apatite-OH 0.1262E-03 -3.899 0.6339E-01 -1.198 0.9075E-01 0.2014E-01 clinochlore 0.1016E-01 -1.993 5.646 0.752 8.083 2.148 daphnite 0.3606E-02 -2.443 2.573 0.410 3.683 0.7796 chlorite-Mn 0.2219E-03 -3.654 0.1573 -0.803 0.2252 0.5014E-01 microcline 0.1215E-01 -1.916 3.381 0.529 4.840 1.321 stilbite 0.4871E-01 -1.312 34.33 1.536 49.14 16.01 stilpnomelane-Fe 0.2642E-02 -2.578 2.848 0.455 4.077 0.9838 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8892E+00 0.8892E+00 1.0000 -0.051 grossular 0.1108E+00 0.1108E+00 1.0000 -0.955 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.7263E+00 0.7263E+00 1.0000 -0.139 daphnite 0.2578E+00 0.2578E+00 1.0000 -0.589 chlorite-Mn 0.1587E-01 0.1587E-01 1.0000 -1.799 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 69.854306 g Volume = 28.823516 cm3 Porosity: -8.3607% V(tot) - V(min): -.22239E+01 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 63.9990000 g log = 1.8062 Original solution: 1000.0103000 g Original solution / Rock added: 15.63 (Water/Rock Ratio), log = 1.1938 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0210 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9993E+00 0.9859 0.1006E+01 0.1020E+01 CO2,gas 0.9074E-07 1.0071 0.9330E-07 0.9264E-07 CH4,gas 0.2132E-05 1.0125 0.2204E-05 0.2177E-05 H2,gas 0.6827E-03 1.0005 0.6974E-03 0.6971E-03 H2S,gas 0.1642E-06 0.9960 0.1670E-06 0.1677E-06 S2,gas 0.2109E-26 1.0000 0.2153E-26 0.2153E-26 CO,gas 0.1699E-13 1.0000 0.1734E-13 0.1734E-13 SO3,gas 0.1927E-42 1.0000 0.1968E-42 0.1968E-42 SO2,gas 0.5230E-23 1.0000 0.5340E-23 0.5340E-23 HCl,gas 0.3371E-17 1.0000 0.3442E-17 0.3442E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 16 albite -0.38 -0.38 0.00 0.000 0.11184E-10 22 andradite 39.01 39.01 0.00 0.000 -0.12132E-10 23 grossular 32.73 32.73 0.00 0.000 0.12132E-10 32 apatite-OH -18.15 -18.15 0.00 0.000 0.00000E+00 46 clinochlore 39.07 39.07 0.00 0.000 0.12132E-10 47 daphnite 28.97 28.97 0.00 0.000 -0.18198E-10 48 chlorite-Mn 46.87 46.87 0.00 0.000 -0.24265E-10 116 microcline -2.49 -2.49 0.00 0.000 0.13649E-10 163 stilbite -7.52 -7.52 0.00 0.000 0.15165E-10 164 stilpnomelane-Fe 13.02 13.02 0.00 0.000 0.21232E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -15.39 -8.73 -2.910 0.14905E+05 -7.030 3 CH4,gas 4.54 -2.81 -7.36 -1.839 0.12560E+05 -5.657 4 H2,gas 8.00 3.14 -4.86 -2.775 0.82906E+04 -3.156 5 H2S,gas -6.23 -14.71 -8.48 -4.238 0.14473E+05 -6.777 6 S2,gas -7.34 -35.70 -28.37 -4.364 0.48434E+05 -26.667 7 CO,gas 3.21 -12.24 -15.46 -4.757 0.26397E+05 -13.761 8 SO3,gas 17.12 -27.28 -44.40 -11.101 0.75820E+05 -42.706 9 SO2,gas 0.83 -24.14 -24.97 -6.659 0.42638E+05 -23.272 10 HCl,gas 5.19 -13.97 -19.16 -9.581 0.32719E+05 -17.463 11 acmite 7.71 6.87 -0.84 -0.088 0.14419E+04 15 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 19 spessartine 24.46 19.74 -4.72 -0.236 0.80549E+04 20 analcite 3.32 2.82 -0.50 -0.056 0.85316E+03 26 annite 20.12 17.60 -2.52 -0.140 0.43073E+04 27 phlogopite 27.06 25.01 -2.05 -0.114 0.35033E+04 29 anorthite 12.71 8.51 -4.20 -0.323 0.71749E+04 35 aragonite 0.97 -2.63 -3.60 -1.199 0.61409E+04 36 brucite 12.57 9.17 -3.40 -0.680 0.58090E+04 37 calcite 0.81 -2.63 -3.44 -1.147 0.58767E+04 38 carnegieite-low 9.02 6.03 -3.00 -0.428 0.51139E+04 39 carnegieite-high 10.09 6.03 -4.07 -0.581 0.69409E+04 40 carpholite-Mg 8.58 4.92 -3.67 -0.244 0.62607E+04 41 carpholite-Fe 6.71 2.44 -4.27 -0.285 0.72872E+04 42 celadonite 5.34 3.47 -1.87 -0.110 0.31891E+04 43 celadonite-Fe 3.88 1.00 -2.87 -0.169 0.49061E+04 44 chrysotile 23.89 21.09 -2.81 -0.234 0.47898E+04 49 chlorite-Al-free 47.17 42.17 -5.00 -0.208 0.85348E+04 51 chloritoid-Fe 9.17 5.65 -3.52 -0.235 0.60150E+04 52 chloritoid-Mn 11.40 8.02 -3.38 -0.225 0.57718E+04 54 coesite -2.38 -3.21 -0.83 -0.277 0.14172E+04 61 cristobalite -2.56 -3.21 -0.65 -0.215 0.11026E+04 63 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71234E+04 65 diaspore 2.87 1.08 -1.79 -0.299 0.30617E+04 67 diopside 16.18 15.51 -0.67 -0.067 0.11403E+04 68 hedenbergite 14.21 13.04 -1.17 -0.117 0.19899E+04 75 epidote 24.67 23.19 -1.48 -0.072 0.25354E+04 76 clinozoisite 22.81 19.14 -3.66 -0.167 0.62562E+04 77 epidote-Fe 29.84 27.23 -2.61 -0.136 0.44612E+04 78 fayalite 14.05 10.19 -3.86 -0.551 0.65913E+04 79 ferrosilite 11.15 6.98 -4.17 -0.417 0.71203E+04 83 gibbsite 4.08 1.08 -3.00 -0.428 0.51202E+04 84 glaucophane 22.97 20.32 -2.66 -0.072 0.45339E+04 85 glaucophane-Fe 17.28 12.91 -4.37 -0.118 0.74590E+04 87 greenalite 16.14 13.68 -2.46 -0.205 0.42079E+04 90 hematite 12.57 10.25 -2.32 -0.281 0.39596E+04 91 heulandite -5.83 -7.52 -1.69 -0.077 0.28938E+04 95 jadeite 4.22 2.82 -1.39 -0.139 0.23786E+04 96 julgoldite 70.43 65.69 -4.74 -0.123 0.80942E+04 97 kalsilite 7.58 3.93 -3.66 -0.523 0.62464E+04 98 kaolinite -1.33 -4.25 -2.92 -0.265 0.49827E+04 101 laumontite 2.88 2.10 -0.79 -0.052 0.13442E+04 102 lawsonite 9.62 8.51 -1.11 -0.074 0.18915E+04 103 leucite 4.12 0.72 -3.40 -0.340 0.58042E+04 105 lizardite 23.24 21.09 -2.16 -0.180 0.36824E+04 107 magnetite 20.09 16.94 -3.14 -0.257 0.53690E+04 108 minnesotaite 10.39 7.26 -3.13 -0.184 0.53360E+04 112 manganosite 14.06 9.07 -4.99 -1.248 0.85245E+04 120 muscovite 2.58 -0.33 -2.91 -0.171 0.49649E+04 121 paragonite 4.24 1.78 -2.46 -0.145 0.42040E+04 122 nepheline 8.34 6.03 -2.31 -0.330 0.39463E+04 128 periclase-Fe 11.63 6.70 -4.93 -1.233 0.84193E+04 134 phlogopite-Na 29.65 27.12 -2.53 -0.141 0.43222E+04 136 prehnite 19.37 18.06 -1.31 -0.077 0.22375E+04 137 prehnite-Fe 22.50 22.10 -0.39 -0.024 0.67172E+03 138 pumpellyite-Fe 46.27 43.90 -2.37 -0.053 0.40471E+04 139 pumpellyite-Mg 48.99 46.37 -2.62 -0.058 0.44821E+04 142 pyrite -21.25 -25.86 -4.61 -1.086 0.78791E+04 143 pyrrhotite -4.26 -8.01 -3.75 -1.250 0.64036E+04 144 pyrrhotiteFe0.875 -6.02 -9.24 -3.22 -1.184 0.54991E+04 145 pyroxmangite 7.40 5.86 -1.54 -0.308 0.26280E+04 146 pyrophyllite -6.18 -10.66 -4.49 -0.280 0.76619E+04 147 quartz -2.99 -3.21 -0.22 -0.072 0.36989E+03 152 rhodonite 7.45 5.86 -1.59 -0.317 0.27082E+04 153 sanidine -1.28 -2.49 -1.21 -0.093 0.20677E+04 165 stilpnomelane-Mg 27.44 25.37 -2.07 -0.062 0.35362E+04 171 talc 16.49 14.68 -1.82 -0.107 0.31008E+04 174 tephroite 18.09 14.93 -3.16 -0.452 0.53966E+04 178 tridymite -2.63 -3.21 -0.58 -0.193 0.98987E+03 179 tremolite 47.87 45.70 -2.17 -0.059 0.37003E+04 181 troilite-low -4.41 -8.01 -3.60 -1.200 0.61464E+04 187 wairakite 3.95 2.10 -1.85 -0.109 0.31662E+04 188 walstromite 11.51 9.55 -1.96 -0.391 0.33399E+04 189 wollastonite 10.46 9.55 -0.91 -0.182 0.15503E+04 190 pseudo-wollastonite 11.00 9.55 -1.45 -0.289 0.24702E+04 191 zoisite 22.85 19.14 -3.71 -0.169 0.63302E+04 192 akaganeite 7.75 5.12 -2.63 -0.569 0.44923E+04 199 chalcedony -2.80 -3.21 -0.40 -0.135 0.68919E+03 201 montmorillonite-Ca -2.29 -5.89 -3.60 -0.223 0.61448E+04 202 montmorillonite-K -2.24 -6.00 -3.76 -0.230 0.64221E+04 203 montmorillonite-Mg -2.48 -6.48 -4.00 -0.248 0.68340E+04 204 montmorillonite-Na -2.04 -5.30 -3.27 -0.200 0.55770E+04 205 nontronite-Ca 3.21 0.94 -2.27 -0.147 0.38789E+04 206 nontronite-H 2.53 -1.16 -3.70 -0.248 0.63094E+04 207 nontronite-K 3.34 0.83 -2.51 -0.161 0.42794E+04 208 nontronite-Mg 3.07 0.35 -2.72 -0.177 0.46522E+04 209 nontronite-Na 3.52 1.53 -1.99 -0.128 0.34003E+04 224 tobermorite 9.82 7.42 -2.40 -0.655 0.40991E+04 230 alabandite -0.98 -5.64 -4.66 -1.554 0.79618E+04 233 boehmite 4.41 1.08 -3.33 -0.554 0.56786E+04 235 ferrous-oxide 9.81 6.70 -3.12 -0.779 0.53202E+04 240 silica-amorphous -2.09 -3.21 -1.11 -0.372 0.19034E+04 242 an20ab80 2.02 1.39 -0.62 -0.048 0.10641E+04 243 an25ab75 2.65 1.84 -0.81 -0.062 0.13771E+04 244 an30ab70 3.28 2.28 -1.00 -0.077 0.16997E+04 245 tr.625ac.25prg.125 45.16 43.69 -1.47 -0.040 0.25113E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 2.0000000 g Current total amount of reactant added: 63.9990000 g New total amount of reactant added: 65.9990000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.1493E-12 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 9 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 65.9990000 Water: Moles liquid = 0.5507E+02 kg liquid = 0.9922E+00 Moles total = 0.5468E+02 kg total = 0.9851E+00 Activity = 1.0000 Stoichiometric ionic strength = .8647416E-02 Osmotic coef. = 0.9654 True ionic strength = .1558512E-01 Chg. balance for total moles = -.1493E-12 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.10457E-09 -9.9806 0.89200E-10 -10.0496 0.85299E+00 -0.0691 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13855E-03 -3.8584 0.11760E-03 -3.9296 0.84879E+00 -0.0712 4 SO4-- 0.50311E-07 -7.2983 0.27819E-07 -7.5557 0.55294E+00 -0.2573 5 HCO3- 0.52507E-05 -5.2798 0.44621E-05 -5.3505 0.84980E+00 -0.0707 6 HS- 0.25650E-04 -4.5909 0.21774E-04 -4.6621 0.84889E+00 -0.0711 7 Al+++ 0.30251E-28 -28.5193 0.80683E-29 -29.0932 0.26671E+00 -0.5740 8 H4SiO4 0.62758E-03 -3.2023 0.62758E-03 -3.2023 0.10000E+01 0.0000 9 Ca++ 0.87812E-07 -7.0564 0.48264E-07 -7.3164 0.54963E+00 -0.2599 10 Mg++ 0.21787E-10 -10.6618 0.11930E-10 -10.9234 0.54757E+00 -0.2616 11 Fe++ 0.72489E-13 -13.1397 0.39728E-13 -13.4009 0.54806E+00 -0.2612 12 K+ 0.12183E-03 -3.9142 0.10356E-03 -3.9848 0.84997E+00 -0.0706 13 Na+ 0.15455E-01 -1.8109 0.13116E-01 -1.8822 0.84867E+00 -0.0713 14 Mn++ 0.17247E-10 -10.7633 0.94590E-11 -11.0242 0.54843E+00 -0.2609 15 HPO4-- 0.10013E-06 -6.9994 0.55372E-07 -7.2567 0.55301E+00 -0.2573 16 HSiO3- 0.77398E-02 -2.1113 0.65695E-02 -2.1825 0.84879E+00 -0.0712 17 Ca(HSiO3)+ 0.84939E-08 -8.0709 0.72208E-08 -8.1414 0.85012E+00 -0.0705 18 Mg(HSiO3)+ 0.26129E-11 -11.5829 0.22213E-11 -11.6534 0.85012E+00 -0.0705 19 NaHSiO3,aq 0.13936E-02 -2.8559 0.13936E-02 -2.8559 0.10000E+01 0.0000 20 AlO+ 0.16227E-15 -15.7898 0.13795E-15 -15.8603 0.85012E+00 -0.0705 22 HAlO2,aq 0.30799E-09 -9.5115 0.30799E-09 -9.5115 0.10000E+01 0.0000 23 AlO2- 0.90180E-05 -5.0449 0.76431E-05 -5.1167 0.84753E+00 -0.0718 24 CH4,aq 0.34015E-08 -8.4683 0.33924E-08 -8.4695 0.99735E+00 -0.0012 29 CO,aq 0.14011E-16 -16.8535 0.14011E-16 -16.8535 0.10000E+01 0.0000 30 CO2,aq 0.85273E-09 -9.0692 0.85047E-09 -9.0703 0.99735E+00 -0.0012 31 CO3-2 0.79157E-05 -5.1015 0.43693E-05 -5.3596 0.55198E+00 -0.2581 32 CaCO3,aq 0.26442E-08 -8.5777 0.26442E-08 -8.5777 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.64664E-11 -11.1893 0.54972E-11 -11.2599 0.85012E+00 -0.0705 34 CaCl+ 0.10805E-10 -10.9664 0.91855E-11 -11.0369 0.85012E+00 -0.0705 35 CaCl2,aq 0.25664E-15 -15.5907 0.25664E-15 -15.5907 0.10000E+01 0.0000 36 CaOH+ 0.45360E-07 -7.3433 0.38562E-07 -7.4138 0.85012E+00 -0.0705 37 CaSO4,aq 0.42636E-12 -12.3702 0.42636E-12 -12.3702 0.10000E+01 0.0000 38 HCl,aq 0.19223E-14 -14.7162 0.19223E-14 -14.7162 0.10000E+01 0.0000 43 FeCl+ 0.86990E-17 -17.0605 0.73952E-17 -17.1310 0.85012E+00 -0.0705 46 FeO,aq 0.19406E-09 -9.7121 0.19406E-09 -9.7121 0.10000E+01 0.0000 47 FeOH+ 0.17054E-10 -10.7682 0.14498E-10 -10.8387 0.85012E+00 -0.0705 48 HFeO2- 0.26818E-07 -7.5716 0.22763E-07 -7.6428 0.84879E+00 -0.0712 49 FeO+ 0.50228E-16 -16.2991 0.42700E-16 -16.3696 0.85012E+00 -0.0705 51 FeO2- 0.12937E-08 -8.8882 0.10981E-08 -8.9594 0.84879E+00 -0.0712 52 HFeO2,aq 0.12458E-10 -10.9046 0.12458E-10 -10.9046 0.10000E+01 0.0000 53 H2,aq 0.65757E-06 -6.1821 0.65583E-06 -6.1832 0.99735E+00 -0.0012 54 KCl,aq 0.22073E-09 -9.6561 0.22073E-09 -9.6561 0.10000E+01 0.0000 56 KOH,aq 0.49579E-06 -6.3047 0.49579E-06 -6.3047 0.10000E+01 0.0000 57 KSO4- 0.52668E-10 -10.2785 0.44704E-10 -10.3497 0.84879E+00 -0.0712 58 MgCO3,aq 0.16383E-12 -12.7856 0.16383E-12 -12.7856 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.16333E-14 -14.7869 0.13885E-14 -14.8575 0.85012E+00 -0.0705 60 MgCl+ 0.24207E-14 -14.6161 0.20579E-14 -14.6866 0.85012E+00 -0.0705 61 MgOH+ 0.62045E-10 -10.2073 0.52745E-10 -10.2778 0.85012E+00 -0.0705 63 MnO,aq 0.12311E-08 -8.9097 0.12311E-08 -8.9097 0.10000E+01 0.0000 64 MnOH+ 0.37719E-09 -9.4234 0.32066E-09 -9.4940 0.85012E+00 -0.0705 65 MnO2-2 0.93029E-11 -11.0314 0.51350E-11 -11.2895 0.55198E+00 -0.2581 66 HMnO2- 0.11823E-09 -9.9273 0.10035E-09 -9.9985 0.84879E+00 -0.0712 69 MnCl+ 0.80578E-14 -14.0938 0.68501E-14 -14.1643 0.85012E+00 -0.0705 70 MnSO4,aq 0.75967E-16 -16.1194 0.75967E-16 -16.1194 0.10000E+01 0.0000 71 NaCl,aq 0.51118E-06 -6.2914 0.51118E-06 -6.2914 0.10000E+01 0.0000 72 NaOH,aq 0.63176E-04 -4.1994 0.63176E-04 -4.1994 0.10000E+01 0.0000 74 OH- 0.76425E-02 -2.1168 0.64773E-02 -2.1886 0.84753E+00 -0.0718 79 HPO3-2 0.20502E-15 -15.6882 0.11317E-15 -15.9463 0.55198E+00 -0.2581 81 H2PO3- 0.23849E-19 -19.6225 0.20243E-19 -19.6937 0.84879E+00 -0.0712 82 H3PO4,aq 0.30814E-17 -17.5113 0.30814E-17 -17.5113 0.10000E+01 0.0000 83 H2PO4- 0.10726E-09 -9.9695 0.91115E-10 -10.0404 0.84945E+00 -0.0709 84 PO4-3 0.18242E-08 -8.7389 0.50647E-09 -9.2954 0.27764E+00 -0.5565 88 HP2O7-3 0.54594E-17 -17.2629 0.14572E-17 -17.8365 0.26691E+00 -0.5736 89 P2O7-4 0.39418E-16 -16.4043 0.39026E-17 -17.4086 0.99004E-01 -1.0043 90 H2S,aq 0.60186E-08 -8.2205 0.60027E-08 -8.2217 0.99735E+00 -0.0012 91 S2-2 0.29019E-13 -13.5373 0.16018E-13 -13.7954 0.55198E+00 -0.2581 97 SO3-2 0.42449E-14 -14.3721 0.23709E-14 -14.6251 0.55852E+00 -0.2530 98 HSO3- 0.15600E-16 -16.8069 0.13241E-16 -16.8781 0.84879E+00 -0.0712 99 HSO4- 0.28109E-14 -14.5512 0.23915E-14 -14.6213 0.85079E+00 -0.0702 101 S2O3-2 0.35538E-17 -17.4493 0.19616E-17 -17.7074 0.55198E+00 -0.2581 Charge balance for all species = -.1597E-12 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.1045732E-09 -.1688390E-01 -.1699597E+02 0.0000 2 H2O 0.1000000E+01 0.5550684E+02 0.9986801E+06 0.0000 3 Cl- 0.1385535E-03 0.1390650E-03 0.4923898E+01 6.1201 4 SO4-- 0.5031147E-07 -.1172654E-06 -.1125014E-01 12.5436 5 HCO3- 0.5250709E-05 0.1317333E-04 0.8027607E+00 4.6992 6 HS- 0.2564972E-04 0.2582336E-04 0.8529266E+00 5.3876 7 Al+++ 0.3025139E-28 0.9018349E-05 0.2430141E+00 1.0557 8 H4SiO4 0.6275807E-03 0.9761009E-02 0.9369708E+03 -3.2023 9 Ca++ 0.8781156E-07 0.1443278E-06 0.5776894E-02 12.7829 10 Mg++ 0.2178749E-10 0.8661284E-10 0.2103010E-05 9.1759 11 Fe++ 0.7248855E-13 0.2833542E-07 0.1580403E-02 6.6984 12 K+ 0.1218348E-03 0.1223309E-03 0.4777202E+01 6.0648 13 Na+ 0.1545490E-01 0.1691220E-01 0.3883056E+03 8.1674 14 Mn++ 0.1724725E-10 0.1753108E-08 0.9618779E-04 9.0751 15 HPO4-- 0.1001287E-06 0.1020601E-06 0.9782969E-02 12.8426 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.1092832E+01 -.1675147E-01 -.1076081E+01 0.0000000E+00 2 H2O 0.5468093E+02 0.5507147E+02 -.3905406E+00 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.1854562E-02 -.1163456E-06 0.1854678E-02 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.1829057E-02 0.2562082E-04 -.1854678E-02 0.0000000E+00 7 Al+++ 0.2152057E+00 0.8947613E-05 0.2151967E+00 0.0000000E+00 8 H4SiO4 0.6872333E+00 0.9684447E-02 0.6775488E+00 0.0000000E+00 9 Ca++ 0.7592274E-01 0.1431957E-06 0.7592259E-01 0.0000000E+00 10 Mg++ 0.5238016E-01 0.8593348E-10 0.5238016E-01 0.0000000E+00 11 Fe++ 0.4705785E-01 0.2811317E-07 0.4705783E-01 0.0000000E+00 12 K+ 0.1401253E-01 0.1213714E-03 0.1389116E-01 0.0000000E+00 13 Na+ 0.8300490E-01 0.1677954E-01 0.6622535E-01 0.0000000E+00 14 Mn++ 0.1144330E-02 0.1739357E-08 0.1144328E-02 0.0000000E+00 15 HPO4-- 0.3905541E-03 0.1012596E-06 0.3904529E-03 0.0000000E+00 Chg. balance for solid moles: 0.1203E-15 Mass of aqueous solution: 0.993440E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 65.9990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 0.6623E-01 -1.179 17.37 1.240 24.11 6.666 andradite 0.7419E-02 -2.130 3.770 0.576 5.234 0.9795 grossular 0.9643E-03 -3.016 0.4344 -0.362 0.6030 0.1209 apatite-OH 0.1302E-03 -3.886 0.6538E-01 -1.185 0.9076E-01 0.2077E-01 clinochlore 0.1048E-01 -1.980 5.823 0.765 8.083 2.215 daphnite 0.3660E-02 -2.436 2.612 0.417 3.625 0.7914 chlorite-Mn 0.2289E-03 -3.640 0.1623 -0.790 0.2253 0.5171E-01 microcline 0.1250E-01 -1.903 3.479 0.541 4.830 1.359 stilbite 0.5012E-01 -1.300 35.32 1.548 49.04 16.48 stilpnomelane-Fe 0.2784E-02 -2.555 3.001 0.477 4.166 1.037 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8850E+00 0.8850E+00 1.0000 -0.053 grossular 0.1150E+00 0.1150E+00 1.0000 -0.939 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.7293E+00 0.7293E+00 1.0000 -0.137 daphnite 0.2548E+00 0.2548E+00 1.0000 -0.594 chlorite-Mn 0.1593E-01 0.1593E-01 1.0000 -1.798 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 72.034710 g Volume = 29.716028 cm3 Porosity: -8.4542% V(tot) - V(min): -.23164E+01 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 65.9990000 g log = 1.8195 Original solution: 1000.0103000 g Original solution / Rock added: 15.15 (Water/Rock Ratio), log = 1.1805 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0212 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9992E+00 0.9859 0.1006E+01 0.1020E+01 CO2,gas 0.8848E-07 1.0071 0.9099E-07 0.9035E-07 CH4,gas 0.4829E-05 1.0125 0.4993E-05 0.4932E-05 H2,gas 0.8427E-03 1.0005 0.8610E-03 0.8606E-03 H2S,gas 0.1622E-06 0.9960 0.1650E-06 0.1657E-06 S2,gas 0.1350E-26 1.0000 0.1379E-26 0.1379E-26 CO,gas 0.2045E-13 1.0000 0.2088E-13 0.2088E-13 SO3,gas 0.8196E-43 1.0000 0.8369E-43 0.8369E-43 SO2,gas 0.2745E-23 1.0000 0.2804E-23 0.2804E-23 HCl,gas 0.3322E-17 1.0000 0.3392E-17 0.3392E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 16 albite -0.38 -0.38 0.00 0.000 -0.94784E-12 22 andradite 39.01 39.01 0.00 0.000 0.24265E-10 23 grossular 32.73 32.73 0.00 0.000 -0.12132E-10 32 apatite-OH -18.15 -18.15 0.00 0.000 0.12132E-10 46 clinochlore 39.07 39.07 0.00 0.000 0.00000E+00 47 daphnite 28.97 28.97 0.00 0.000 -0.24265E-10 48 chlorite-Mn 46.87 46.87 0.00 0.000 0.12132E-10 116 microcline -2.49 -2.49 0.00 0.000 0.15165E-11 163 stilbite -7.52 -7.52 0.00 0.000 0.15165E-10 164 stilpnomelane-Fe 13.02 13.02 0.00 0.000 0.21232E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -15.40 -8.74 -2.913 0.14923E+05 -7.041 3 CH4,gas 4.54 -2.46 -7.00 -1.750 0.11953E+05 -5.302 4 H2,gas 8.00 3.24 -4.76 -2.722 0.81343E+04 -3.065 5 H2S,gas -6.23 -14.71 -8.48 -4.241 0.14482E+05 -6.782 6 S2,gas -7.34 -35.90 -28.56 -4.394 0.48765E+05 -26.861 7 CO,gas 3.21 -12.16 -15.38 -4.732 0.26260E+05 -13.680 8 SO3,gas 17.12 -27.65 -44.78 -11.194 0.76454E+05 -43.077 9 SO2,gas 0.83 -24.42 -25.25 -6.734 0.43116E+05 -23.552 10 HCl,gas 5.19 -13.98 -19.17 -9.584 0.32730E+05 -17.470 11 acmite 7.71 6.84 -0.87 -0.090 0.14795E+04 15 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 19 spessartine 24.46 19.73 -4.73 -0.236 0.80723E+04 20 analcite 3.32 2.82 -0.50 -0.056 0.85954E+03 26 annite 20.12 17.61 -2.51 -0.140 0.42939E+04 27 phlogopite 27.06 25.04 -2.02 -0.112 0.34548E+04 29 anorthite 12.71 8.49 -4.22 -0.325 0.72068E+04 35 aragonite 0.97 -2.62 -3.58 -1.195 0.61191E+04 36 brucite 12.57 9.18 -3.39 -0.679 0.57929E+04 37 calcite 0.81 -2.62 -3.43 -1.143 0.58549E+04 38 carnegieite-low 9.02 6.02 -3.00 -0.429 0.51267E+04 39 carnegieite-high 10.09 6.02 -4.07 -0.582 0.69537E+04 40 carpholite-Mg 8.58 4.88 -3.70 -0.247 0.63167E+04 41 carpholite-Fe 6.71 2.41 -4.31 -0.287 0.73550E+04 42 celadonite 5.34 3.49 -1.85 -0.109 0.31665E+04 43 celadonite-Fe 3.88 1.01 -2.87 -0.169 0.48953E+04 44 chrysotile 23.89 21.12 -2.77 -0.231 0.47285E+04 49 chlorite-Al-free 47.17 42.25 -4.93 -0.205 0.84122E+04 51 chloritoid-Fe 9.17 5.61 -3.57 -0.238 0.60892E+04 52 chloritoid-Mn 11.40 7.98 -3.42 -0.228 0.58343E+04 54 coesite -2.38 -3.20 -0.83 -0.275 0.14108E+04 61 cristobalite -2.56 -3.20 -0.64 -0.214 0.10962E+04 63 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71234E+04 65 diaspore 2.87 1.06 -1.82 -0.303 0.31042E+04 67 diopside 16.18 15.55 -0.63 -0.063 0.10709E+04 68 hedenbergite 14.21 13.08 -1.13 -0.113 0.19323E+04 75 epidote 24.67 23.15 -1.52 -0.074 0.25941E+04 76 clinozoisite 22.81 19.13 -3.68 -0.167 0.62838E+04 77 epidote-Fe 29.84 27.18 -2.67 -0.138 0.45511E+04 78 fayalite 14.05 10.19 -3.85 -0.550 0.65760E+04 79 ferrosilite 11.15 6.99 -4.16 -0.416 0.70986E+04 83 gibbsite 4.08 1.06 -3.02 -0.432 0.51628E+04 84 glaucophane 22.97 20.36 -2.62 -0.071 0.44726E+04 85 glaucophane-Fe 17.28 12.92 -4.35 -0.118 0.74328E+04 87 greenalite 16.14 13.69 -2.45 -0.204 0.41817E+04 90 hematite 12.57 10.16 -2.41 -0.292 0.41069E+04 91 heulandite -5.83 -7.52 -1.69 -0.077 0.28938E+04 95 jadeite 4.22 2.82 -1.40 -0.140 0.23850E+04 96 julgoldite 70.43 65.64 -4.79 -0.124 0.81801E+04 97 kalsilite 7.58 3.92 -3.67 -0.524 0.62592E+04 98 kaolinite -1.33 -4.29 -2.96 -0.269 0.50550E+04 101 laumontite 2.88 2.08 -0.80 -0.053 0.13634E+04 102 lawsonite 9.62 8.49 -1.13 -0.075 0.19234E+04 103 leucite 4.12 0.72 -3.40 -0.340 0.58106E+04 105 lizardite 23.24 21.12 -2.12 -0.177 0.36211E+04 107 magnetite 20.09 16.86 -3.23 -0.264 0.55119E+04 108 minnesotaite 10.39 7.29 -3.10 -0.182 0.52971E+04 112 manganosite 14.06 9.08 -4.98 -1.246 0.85083E+04 120 muscovite 2.58 -0.38 -2.96 -0.174 0.50499E+04 121 paragonite 4.24 1.73 -2.51 -0.148 0.42890E+04 122 nepheline 8.34 6.02 -2.32 -0.331 0.39591E+04 128 periclase-Fe 11.63 6.70 -4.93 -1.232 0.84148E+04 134 phlogopite-Na 29.65 27.14 -2.50 -0.139 0.42736E+04 136 prehnite 19.37 18.07 -1.30 -0.077 0.22227E+04 137 prehnite-Fe 22.50 22.09 -0.40 -0.024 0.68798E+03 138 pumpellyite-Fe 46.27 43.89 -2.38 -0.053 0.40553E+04 139 pumpellyite-Mg 48.99 46.37 -2.62 -0.058 0.44786E+04 142 pyrite -21.25 -25.96 -4.71 -1.109 0.80489E+04 143 pyrrhotite -4.26 -8.01 -3.75 -1.251 0.64082E+04 144 pyrrhotiteFe0.875 -6.02 -9.25 -3.23 -1.190 0.55235E+04 145 pyroxmangite 7.40 5.87 -1.53 -0.305 0.26054E+04 146 pyrophyllite -6.18 -10.70 -4.52 -0.283 0.77215E+04 147 quartz -2.99 -3.20 -0.21 -0.071 0.36351E+03 152 rhodonite 7.45 5.87 -1.57 -0.315 0.26857E+04 153 sanidine -1.28 -2.49 -1.21 -0.093 0.20677E+04 165 stilpnomelane-Mg 27.44 25.40 -2.04 -0.061 0.34776E+04 171 talc 16.49 14.72 -1.77 -0.104 0.30267E+04 174 tephroite 18.09 14.95 -3.14 -0.448 0.53579E+04 178 tridymite -2.63 -3.20 -0.58 -0.192 0.98349E+03 179 tremolite 47.87 45.83 -2.04 -0.055 0.34876E+04 181 troilite-low -4.41 -8.01 -3.60 -1.201 0.61510E+04 187 wairakite 3.95 2.08 -1.87 -0.110 0.31853E+04 188 walstromite 11.51 9.58 -1.93 -0.386 0.32931E+04 189 wollastonite 10.46 9.58 -0.88 -0.176 0.15036E+04 190 pseudo-wollastonite 11.00 9.58 -1.42 -0.284 0.24234E+04 191 zoisite 22.85 19.13 -3.72 -0.169 0.63579E+04 192 akaganeite 7.75 5.08 -2.67 -0.578 0.45660E+04 199 chalcedony -2.80 -3.20 -0.40 -0.133 0.68281E+03 201 montmorillonite-Ca -2.29 -5.91 -3.62 -0.224 0.61783E+04 202 montmorillonite-K -2.24 -6.02 -3.78 -0.231 0.64545E+04 203 montmorillonite-Mg -2.48 -6.50 -4.02 -0.249 0.68715E+04 204 montmorillonite-Na -2.04 -5.32 -3.29 -0.201 0.56094E+04 205 nontronite-Ca 3.21 0.87 -2.35 -0.152 0.40102E+04 206 nontronite-H 2.53 -1.24 -3.78 -0.253 0.64473E+04 207 nontronite-K 3.34 0.76 -2.58 -0.166 0.44096E+04 208 nontronite-Mg 3.07 0.27 -2.80 -0.182 0.47875E+04 209 nontronite-Na 3.52 1.45 -2.07 -0.133 0.35305E+04 224 tobermorite 9.82 7.45 -2.38 -0.649 0.40591E+04 230 alabandite -0.98 -5.64 -4.66 -1.553 0.79546E+04 233 boehmite 4.41 1.06 -3.35 -0.558 0.57211E+04 235 ferrous-oxide 9.81 6.70 -3.11 -0.778 0.53157E+04 240 silica-amorphous -2.09 -3.20 -1.11 -0.370 0.18970E+04 242 an20ab80 2.02 1.39 -0.63 -0.048 0.10705E+04 243 an25ab75 2.65 1.83 -0.81 -0.062 0.13851E+04 244 an30ab70 3.28 2.28 -1.00 -0.077 0.17093E+04 245 tr.625ac.25prg.125 45.16 43.80 -1.36 -0.037 0.23299E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 2.0000000 g Current total amount of reactant added: 65.9990000 g New total amount of reactant added: 67.9990000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.1492E-12 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 9 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 67.9990000 Water: Moles liquid = 0.5506E+02 kg liquid = 0.9919E+00 Moles total = 0.5466E+02 kg total = 0.9846E+00 Activity = 1.0000 Stoichiometric ionic strength = .8817967E-02 Osmotic coef. = 0.9652 True ionic strength = .1587259E-01 Chg. balance for total moles = -.1492E-12 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.10333E-09 -9.9858 0.88043E-10 -10.0553 0.85209E+00 -0.0695 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13858E-03 -3.8583 0.11749E-03 -3.9300 0.84783E+00 -0.0717 4 SO4-- 0.22855E-07 -7.6410 0.12582E-07 -7.9002 0.55051E+00 -0.2592 5 HCO3- 0.51987E-05 -5.2841 0.44129E-05 -5.3553 0.84886E+00 -0.0712 6 HS- 0.25683E-04 -4.5904 0.21777E-04 -4.6620 0.84793E+00 -0.0716 7 Al+++ 0.27784E-28 -28.5562 0.73359E-29 -29.1345 0.26403E+00 -0.5783 8 H4SiO4 0.63300E-03 -3.1986 0.63300E-03 -3.1986 0.10000E+01 0.0000 9 Ca++ 0.90504E-07 -7.0433 0.49520E-07 -7.3052 0.54716E+00 -0.2619 10 Mg++ 0.21779E-10 -10.6620 0.11871E-10 -10.9255 0.54508E+00 -0.2635 11 Fe++ 0.71342E-13 -13.1467 0.38922E-13 -13.4098 0.54558E+00 -0.2631 12 K+ 0.12408E-03 -3.9063 0.10535E-03 -3.9774 0.84903E+00 -0.0711 13 Na+ 0.15740E-01 -1.8030 0.13343E-01 -1.8747 0.84771E+00 -0.0718 14 Mn++ 0.17240E-10 -10.7635 0.94124E-11 -11.0263 0.54595E+00 -0.2628 15 HPO4-- 0.94690E-07 -7.0237 0.52134E-07 -7.2829 0.55058E+00 -0.2592 16 HSiO3- 0.79182E-02 -2.1014 0.67133E-02 -2.1731 0.84783E+00 -0.0717 17 Ca(HSiO3)+ 0.89157E-08 -8.0498 0.75710E-08 -8.1208 0.84918E+00 -0.0710 18 Mg(HSiO3)+ 0.26599E-11 -11.5751 0.22588E-11 -11.6461 0.84918E+00 -0.0710 19 NaHSiO3,aq 0.14487E-02 -2.8390 0.14487E-02 -2.8390 0.10000E+01 0.0000 20 AlO+ 0.15161E-15 -15.8193 0.12875E-15 -15.8903 0.84918E+00 -0.0710 22 HAlO2,aq 0.29122E-09 -9.5358 0.29122E-09 -9.5358 0.10000E+01 0.0000 23 AlO2- 0.86490E-05 -5.0630 0.73219E-05 -5.1354 0.84655E+00 -0.0723 24 CH4,aq 0.74395E-08 -8.1285 0.74194E-08 -8.1296 0.99730E+00 -0.0012 25 C2H6,aq 0.11760E-19 -19.9296 0.11729E-19 -19.9308 0.99730E+00 -0.0012 29 CO,aq 0.16733E-16 -16.7764 0.16733E-16 -16.7764 0.10000E+01 0.0000 30 CO2,aq 0.83244E-09 -9.0796 0.83019E-09 -9.0808 0.99730E+00 -0.0012 31 CO3-2 0.79666E-05 -5.0987 0.43780E-05 -5.3587 0.54954E+00 -0.2600 32 CaCO3,aq 0.27184E-08 -8.5657 0.27184E-08 -8.5657 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.65689E-11 -11.1825 0.55782E-11 -11.2535 0.84918E+00 -0.0710 34 CaCl+ 0.11088E-10 -10.9552 0.94155E-11 -11.0262 0.84918E+00 -0.0710 35 CaCl2,aq 0.26281E-15 -15.5804 0.26281E-15 -15.5804 0.10000E+01 0.0000 36 CaOH+ 0.47206E-07 -7.3260 0.40086E-07 -7.3970 0.84918E+00 -0.0710 37 CaSO4,aq 0.19785E-12 -12.7037 0.19785E-12 -12.7037 0.10000E+01 0.0000 38 HCl,aq 0.18955E-14 -14.7223 0.18955E-14 -14.7223 0.10000E+01 0.0000 43 FeCl+ 0.85238E-17 -17.0694 0.72382E-17 -17.1404 0.84918E+00 -0.0710 46 FeO,aq 0.19515E-09 -9.7096 0.19515E-09 -9.7096 0.10000E+01 0.0000 47 FeOH+ 0.16946E-10 -10.7709 0.14390E-10 -10.8419 0.84918E+00 -0.0710 48 HFeO2- 0.27355E-07 -7.5630 0.23192E-07 -7.6347 0.84783E+00 -0.0717 49 FeO+ 0.45124E-16 -16.3456 0.38318E-16 -16.4166 0.84918E+00 -0.0710 51 FeO2- 0.11931E-08 -8.9233 0.10115E-08 -8.9950 0.84783E+00 -0.0717 52 HFeO2,aq 0.11327E-10 -10.9459 0.11327E-10 -10.9459 0.10000E+01 0.0000 53 H2,aq 0.80454E-06 -6.0945 0.80237E-06 -6.0956 0.99730E+00 -0.0012 54 KCl,aq 0.22433E-09 -9.6491 0.22433E-09 -9.6491 0.10000E+01 0.0000 56 KOH,aq 0.51099E-06 -6.2916 0.51099E-06 -6.2916 0.10000E+01 0.0000 57 KSO4- 0.24260E-10 -10.6151 0.20568E-10 -10.6868 0.84783E+00 -0.0717 58 MgCO3,aq 0.16335E-12 -12.7869 0.16335E-12 -12.7869 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.16091E-14 -14.7934 0.13664E-14 -14.8644 0.84918E+00 -0.0710 60 MgCl+ 0.24091E-14 -14.6181 0.20458E-14 -14.6891 0.84918E+00 -0.0710 61 MgOH+ 0.62620E-10 -10.2033 0.53176E-10 -10.2743 0.84918E+00 -0.0710 63 MnO,aq 0.12575E-08 -8.9005 0.12575E-08 -8.9005 0.10000E+01 0.0000 64 MnOH+ 0.38069E-09 -9.4194 0.32327E-09 -9.4904 0.84918E+00 -0.0710 65 MnO2-2 0.97968E-11 -11.0089 0.53837E-11 -11.2689 0.54954E+00 -0.2600 66 HMnO2- 0.12248E-09 -9.9119 0.10385E-09 -9.9836 0.84783E+00 -0.0717 69 MnCl+ 0.80193E-14 -14.0959 0.68098E-14 -14.1669 0.84918E+00 -0.0710 70 MnSO4,aq 0.34189E-16 -16.4661 0.34189E-16 -16.4661 0.10000E+01 0.0000 71 NaCl,aq 0.51952E-06 -6.2844 0.51952E-06 -6.2844 0.10000E+01 0.0000 72 NaOH,aq 0.65113E-04 -4.1863 0.65113E-04 -4.1863 0.10000E+01 0.0000 74 OH- 0.77519E-02 -2.1106 0.65624E-02 -2.1829 0.84655E+00 -0.0723 79 HPO3-2 0.23721E-15 -15.6249 0.13036E-15 -15.8849 0.54954E+00 -0.2600 81 H2PO3- 0.27146E-19 -19.5663 0.23015E-19 -19.6380 0.84783E+00 -0.0717 82 H3PO4,aq 0.28264E-17 -17.5488 0.28264E-17 -17.5488 0.10000E+01 0.0000 83 H2PO4- 0.99793E-10 -10.0009 0.84674E-10 -10.0722 0.84849E+00 -0.0714 84 PO4-3 0.17567E-08 -8.7553 0.48313E-09 -9.3159 0.27502E+00 -0.5606 88 HP2O7-3 0.48252E-17 -17.3165 0.12750E-17 -17.8945 0.26424E+00 -0.5780 89 P2O7-4 0.35563E-16 -16.4490 0.34595E-17 -17.4610 0.97281E-01 -1.0120 90 H2S,aq 0.59419E-08 -8.2261 0.59258E-08 -8.2273 0.99730E+00 -0.0012 91 S2-2 0.23833E-13 -13.6228 0.13097E-13 -13.8828 0.54954E+00 -0.2600 97 SO3-2 0.23589E-14 -14.6273 0.13119E-14 -14.8821 0.55614E+00 -0.2548 98 HSO3- 0.85300E-17 -17.0691 0.72320E-17 -17.1407 0.84783E+00 -0.0717 99 HSO4- 0.12562E-14 -14.9010 0.10676E-14 -14.9716 0.84986E+00 -0.0707 101 S2O3-2 0.15938E-17 -17.7976 0.87584E-18 -18.0576 0.54954E+00 -0.2600 Charge balance for all species = -.1529E-12 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.1033261E-09 -.1722739E-01 -.1734124E+02 0.0000 2 H2O 0.1000000E+01 0.5550672E+02 0.9986496E+06 0.0000 3 Cl- 0.1385766E-03 0.1390964E-03 0.4924872E+01 6.1253 4 SO4-- 0.2285532E-07 -.1855439E-06 -.1780010E-01 12.2104 5 HCO3- 0.5198662E-05 0.1317631E-04 0.8029195E+00 4.7000 6 HS- 0.2568309E-04 0.2589746E-04 0.8553496E+00 5.3933 7 Al+++ 0.2778389E-28 0.8649327E-05 0.2330636E+00 1.0314 8 H4SiO4 0.6329980E-03 0.9999946E-02 0.9598795E+03 -3.1986 9 Ca++ 0.9050416E-07 0.1493617E-06 0.5978213E-02 12.8054 10 Mg++ 0.2177922E-10 0.8722656E-10 0.2117852E-05 9.1851 11 Fe++ 0.7134157E-13 0.2877129E-07 0.1604668E-02 6.7008 12 K+ 0.1240802E-03 0.1245915E-03 0.4865343E+01 6.0779 13 Na+ 0.1574010E-01 0.1725448E-01 0.3961531E+03 8.1806 14 Mn++ 0.1724030E-10 0.1787705E-08 0.9808322E-04 9.0843 15 HPO4-- 0.9469037E-07 0.9654684E-07 0.9254232E-02 12.8277 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.1125949E+01 -.1708840E-01 -.1108861E+01 0.0000000E+00 2 H2O 0.5465585E+02 0.5505889E+02 -.4030395E+00 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.1909989E-02 -.1840469E-06 0.1910173E-02 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.1884484E-02 0.2568852E-04 -.1910173E-02 0.0000000E+00 7 Al+++ 0.2217272E+00 0.8579545E-05 0.2217186E+00 0.0000000E+00 8 H4SiO4 0.7080588E+00 0.9919267E-02 0.6981396E+00 0.0000000E+00 9 Ca++ 0.7822302E-01 0.1481567E-06 0.7822287E-01 0.0000000E+00 10 Mg++ 0.5396746E-01 0.8652282E-10 0.5396746E-01 0.0000000E+00 11 Fe++ 0.4848387E-01 0.2853916E-07 0.4848384E-01 0.0000000E+00 12 K+ 0.1443715E-01 0.1235863E-03 0.1431357E-01 0.0000000E+00 13 Na+ 0.8551538E-01 0.1711527E-01 0.6840011E-01 0.0000000E+00 14 Mn++ 0.1179007E-02 0.1773282E-08 0.1179005E-02 0.0000000E+00 15 HPO4-- 0.4023893E-03 0.9576791E-07 0.4022935E-03 0.0000000E+00 Chg. balance for solid moles: 0.1199E-15 Mass of aqueous solution: 0.993244E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 67.9990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 0.6840E-01 -1.165 17.94 1.254 24.17 6.885 andradite 0.7641E-02 -2.117 3.883 0.589 5.232 1.009 grossular 0.1033E-02 -2.986 0.4653 -0.332 0.6269 0.1295 apatite-OH 0.1341E-03 -3.873 0.6736E-01 -1.172 0.9076E-01 0.2140E-01 clinochlore 0.1079E-01 -1.967 5.999 0.778 8.084 2.282 daphnite 0.3713E-02 -2.430 2.649 0.423 3.570 0.8028 chlorite-Mn 0.2358E-03 -3.627 0.1672 -0.777 0.2253 0.5327E-01 microcline 0.1285E-01 -1.891 3.577 0.553 4.819 1.397 stilbite 0.5153E-01 -1.288 36.32 1.560 48.93 16.94 stilpnomelane-Fe 0.2928E-02 -2.533 3.156 0.499 4.252 1.090 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8809E+00 0.8809E+00 1.0000 -0.055 grossular 0.1191E+00 0.1191E+00 1.0000 -0.924 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.7322E+00 0.7322E+00 1.0000 -0.135 daphnite 0.2519E+00 0.2519E+00 1.0000 -0.599 chlorite-Mn 0.1599E-01 0.1599E-01 1.0000 -1.796 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 74.214986 g Volume = 30.608270 cm3 Porosity: -8.5415% V(tot) - V(min): -.24087E+01 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 67.9990000 g log = 1.8325 Original solution: 1000.0103000 g Original solution / Rock added: 14.71 (Water/Rock Ratio), log = 1.1675 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0214 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9990E+00 0.9859 0.1006E+01 0.1020E+01 CO2,gas 0.8635E-07 1.0071 0.8882E-07 0.8820E-07 CH4,gas 0.1056E-04 1.0125 0.1092E-04 0.1079E-04 H2,gas 0.1031E-02 1.0005 0.1053E-02 0.1053E-02 H2S,gas 0.1601E-06 0.9960 0.1629E-06 0.1635E-06 S2,gas 0.8788E-27 1.0000 0.8976E-27 0.8976E-27 CO,gas 0.2441E-13 1.0000 0.2494E-13 0.2494E-13 SO3,gas 0.3611E-43 1.0000 0.3688E-43 0.3688E-43 SO2,gas 0.1480E-23 1.0000 0.1511E-23 0.1511E-23 HCl,gas 0.3275E-17 1.0000 0.3345E-17 0.3345E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 16 albite -0.38 -0.38 0.00 0.000 -0.94784E-12 22 andradite 39.01 39.01 0.00 0.000 0.00000E+00 23 grossular 32.73 32.73 0.00 0.000 0.00000E+00 32 apatite-OH -18.15 -18.15 0.00 0.000 0.00000E+00 46 clinochlore 39.07 39.07 0.00 0.000 0.00000E+00 47 daphnite 28.97 28.97 0.00 0.000 -0.30331E-10 48 chlorite-Mn 46.87 46.87 0.00 0.000 0.24265E-10 116 microcline -2.49 -2.49 0.00 0.000 0.15165E-11 163 stilbite -7.52 -7.52 0.00 0.000 0.39430E-10 164 stilpnomelane-Fe 13.02 13.02 0.00 0.000 -0.75827E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -15.41 -8.75 -2.917 0.14941E+05 -7.051 3 CH4,gas 4.54 -2.12 -6.66 -1.665 0.11373E+05 -4.962 4 H2,gas 8.00 3.32 -4.68 -2.672 0.79848E+04 -2.977 5 H2S,gas -6.23 -14.72 -8.49 -4.244 0.14491E+05 -6.788 6 S2,gas -7.34 -36.08 -28.75 -4.422 0.49083E+05 -27.047 7 CO,gas 3.21 -12.09 -15.30 -4.708 0.26128E+05 -13.603 8 SO3,gas 17.12 -28.01 -45.13 -11.283 0.77062E+05 -43.433 9 SO2,gas 0.83 -24.69 -25.52 -6.805 0.43574E+05 -23.821 10 HCl,gas 5.19 -13.99 -19.17 -9.587 0.32740E+05 -17.476 11 acmite 7.71 6.82 -0.89 -0.092 0.15149E+04 15 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 19 spessartine 24.46 19.72 -4.74 -0.237 0.80891E+04 20 analcite 3.32 2.81 -0.51 -0.056 0.86591E+03 26 annite 20.12 17.62 -2.51 -0.139 0.42814E+04 27 phlogopite 27.06 25.07 -2.00 -0.111 0.34077E+04 29 anorthite 12.71 8.47 -4.24 -0.326 0.72386E+04 35 aragonite 0.97 -2.61 -3.57 -1.191 0.60986E+04 36 brucite 12.57 9.19 -3.38 -0.677 0.57772E+04 37 calcite 0.81 -2.61 -3.42 -1.139 0.58344E+04 38 carnegieite-low 9.02 6.01 -3.01 -0.430 0.51394E+04 39 carnegieite-high 10.09 6.01 -4.08 -0.583 0.69664E+04 40 carpholite-Mg 8.58 4.85 -3.73 -0.249 0.63713E+04 41 carpholite-Fe 6.71 2.37 -4.35 -0.290 0.74212E+04 42 celadonite 5.34 3.50 -1.84 -0.108 0.31444E+04 43 celadonite-Fe 3.88 1.02 -2.86 -0.168 0.48847E+04 44 chrysotile 23.89 21.16 -2.73 -0.228 0.46686E+04 49 chlorite-Al-free 47.17 42.32 -4.86 -0.202 0.82925E+04 51 chloritoid-Fe 9.17 5.56 -3.61 -0.241 0.61617E+04 52 chloritoid-Mn 11.40 7.95 -3.45 -0.230 0.58953E+04 54 coesite -2.38 -3.20 -0.82 -0.274 0.14045E+04 61 cristobalite -2.56 -3.20 -0.64 -0.213 0.10898E+04 63 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71234E+04 65 diaspore 2.87 1.03 -1.84 -0.307 0.31457E+04 67 diopside 16.18 15.59 -0.59 -0.059 0.10041E+04 68 hedenbergite 14.21 13.11 -1.10 -0.110 0.18770E+04 75 epidote 24.67 23.12 -1.55 -0.075 0.26518E+04 76 clinozoisite 22.81 19.11 -3.70 -0.168 0.63124E+04 77 epidote-Fe 29.84 27.12 -2.72 -0.141 0.46379E+04 78 fayalite 14.05 10.20 -3.84 -0.549 0.65613E+04 79 ferrosilite 11.15 7.00 -4.15 -0.415 0.70775E+04 83 gibbsite 4.08 1.03 -3.05 -0.435 0.52043E+04 84 glaucophane 22.97 20.39 -2.58 -0.070 0.44128E+04 85 glaucophane-Fe 17.28 12.94 -4.34 -0.117 0.74076E+04 87 greenalite 16.14 13.71 -2.43 -0.203 0.41565E+04 90 hematite 12.57 10.08 -2.49 -0.302 0.42481E+04 91 heulandite -5.83 -7.52 -1.69 -0.077 0.28938E+04 95 jadeite 4.22 2.81 -1.40 -0.140 0.23914E+04 96 julgoldite 70.43 65.59 -4.84 -0.126 0.82622E+04 97 kalsilite 7.58 3.91 -3.67 -0.525 0.62719E+04 98 kaolinite -1.33 -4.33 -3.00 -0.273 0.51253E+04 101 laumontite 2.88 2.07 -0.81 -0.054 0.13825E+04 102 lawsonite 9.62 8.47 -1.15 -0.076 0.19553E+04 103 leucite 4.12 0.71 -3.41 -0.341 0.58169E+04 105 lizardite 23.24 21.16 -2.09 -0.174 0.35613E+04 107 magnetite 20.09 16.78 -3.31 -0.270 0.56489E+04 108 minnesotaite 10.39 7.31 -3.08 -0.181 0.52591E+04 112 manganosite 14.06 9.08 -4.97 -1.243 0.84926E+04 120 muscovite 2.58 -0.42 -3.01 -0.177 0.51330E+04 121 paragonite 4.24 1.68 -2.56 -0.151 0.43721E+04 122 nepheline 8.34 6.01 -2.33 -0.332 0.39718E+04 128 periclase-Fe 11.63 6.70 -4.93 -1.231 0.84106E+04 134 phlogopite-Na 29.65 27.17 -2.48 -0.138 0.42265E+04 136 prehnite 19.37 18.08 -1.29 -0.076 0.22097E+04 137 prehnite-Fe 22.50 22.09 -0.41 -0.025 0.70413E+03 138 pumpellyite-Fe 46.27 43.89 -2.38 -0.053 0.40668E+04 139 pumpellyite-Mg 48.99 46.37 -2.62 -0.058 0.44786E+04 142 pyrite -21.25 -26.06 -4.81 -1.132 0.82134E+04 143 pyrrhotite -4.26 -8.02 -3.76 -1.252 0.64136E+04 144 pyrrhotiteFe0.875 -6.02 -9.27 -3.25 -1.195 0.55480E+04 145 pyroxmangite 7.40 5.89 -1.51 -0.303 0.25833E+04 146 pyrophyllite -6.18 -10.73 -4.56 -0.285 0.77790E+04 147 quartz -2.99 -3.20 -0.21 -0.070 0.35714E+03 152 rhodonite 7.45 5.89 -1.56 -0.312 0.26636E+04 153 sanidine -1.28 -2.49 -1.21 -0.093 0.20677E+04 165 stilpnomelane-Mg 27.44 25.44 -2.00 -0.060 0.34199E+04 171 talc 16.49 14.76 -1.73 -0.102 0.29541E+04 174 tephroite 18.09 14.97 -3.12 -0.445 0.53201E+04 178 tridymite -2.63 -3.20 -0.57 -0.191 0.97712E+03 179 tremolite 47.87 45.95 -1.92 -0.052 0.32812E+04 180 ferroactinolite 38.45 33.53 -4.93 -0.133 0.84115E+04 181 troilite-low -4.41 -8.02 -3.61 -1.202 0.61564E+04 187 wairakite 3.95 2.07 -1.88 -0.110 0.32045E+04 188 walstromite 11.51 9.61 -1.90 -0.380 0.32483E+04 189 wollastonite 10.46 9.61 -0.85 -0.171 0.14588E+04 190 pseudo-wollastonite 11.00 9.61 -1.39 -0.279 0.23786E+04 191 zoisite 22.85 19.11 -3.74 -0.170 0.63865E+04 192 akaganeite 7.75 5.04 -2.72 -0.587 0.46366E+04 199 chalcedony -2.80 -3.20 -0.40 -0.132 0.67644E+03 201 montmorillonite-Ca -2.29 -5.93 -3.64 -0.225 0.62106E+04 202 montmorillonite-K -2.24 -6.04 -3.80 -0.233 0.64858E+04 203 montmorillonite-Mg -2.48 -6.53 -4.05 -0.250 0.69076E+04 204 montmorillonite-Na -2.04 -5.34 -3.30 -0.202 0.56407E+04 205 nontronite-Ca 3.21 0.79 -2.42 -0.157 0.41354E+04 206 nontronite-H 2.53 -1.32 -3.85 -0.258 0.65788E+04 207 nontronite-K 3.34 0.69 -2.66 -0.170 0.45338E+04 208 nontronite-Mg 3.07 0.20 -2.88 -0.187 0.49164E+04 209 nontronite-Na 3.52 1.38 -2.14 -0.137 0.36547E+04 224 tobermorite 9.82 7.47 -2.35 -0.642 0.40207E+04 230 alabandite -0.98 -5.63 -4.66 -1.552 0.79485E+04 233 boehmite 4.41 1.03 -3.37 -0.562 0.57626E+04 235 ferrous-oxide 9.81 6.70 -3.11 -0.778 0.53116E+04 240 silica-amorphous -2.09 -3.20 -1.11 -0.369 0.18906E+04 242 an20ab80 2.02 1.39 -0.63 -0.049 0.10769E+04 243 an25ab75 2.65 1.83 -0.82 -0.063 0.13931E+04 244 an30ab70 3.28 2.27 -1.01 -0.077 0.17189E+04 245 tr.625ac.25prg.125 45.16 43.90 -1.26 -0.034 0.21543E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 2.0000000 g Current total amount of reactant added: 67.9990000 g New total amount of reactant added: 69.9990000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.1492E-12 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 9 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 69.9990000 Water: Moles liquid = 0.5505E+02 kg liquid = 0.9917E+00 Moles total = 0.5463E+02 kg total = 0.9842E+00 Activity = 1.0000 Stoichiometric ionic strength = .8986198E-02 Osmotic coef. = 0.9649 True ionic strength = .1615498E-01 Chg. balance for total moles = -.1492E-12 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.10216E-09 -9.9907 0.86956E-10 -10.0607 0.85121E+00 -0.0700 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13860E-03 -3.8582 0.11738E-03 -3.9304 0.84690E+00 -0.0722 4 SO4-- 0.10728E-07 -7.9695 0.58807E-08 -8.2306 0.54816E+00 -0.2611 5 HCO3- 0.51474E-05 -5.2884 0.43647E-05 -5.3600 0.84794E+00 -0.0716 6 HS- 0.25701E-04 -4.5900 0.21769E-04 -4.6622 0.84700E+00 -0.0721 7 Al+++ 0.25592E-28 -28.5919 0.66914E-29 -29.1745 0.26146E+00 -0.5826 8 H4SiO4 0.63845E-03 -3.1949 0.63845E-03 -3.1949 0.10000E+01 0.0000 9 Ca++ 0.93155E-07 -7.0308 0.50749E-07 -7.2946 0.54478E+00 -0.2638 10 Mg++ 0.21782E-10 -10.6619 0.11821E-10 -10.9274 0.54268E+00 -0.2655 11 Fe++ 0.70267E-13 -13.1532 0.38167E-13 -13.4183 0.54318E+00 -0.2651 12 K+ 0.12629E-03 -3.8986 0.10710E-03 -3.9702 0.84811E+00 -0.0715 13 Na+ 0.16020E-01 -1.7953 0.13565E-01 -1.8676 0.84677E+00 -0.0722 14 Mn++ 0.17242E-10 -10.7634 0.93722E-11 -11.0282 0.54356E+00 -0.2648 15 HPO4-- 0.89791E-07 -7.0468 0.49226E-07 -7.3078 0.54823E+00 -0.2610 16 HSiO3- 0.80951E-02 -2.0918 0.68557E-02 -2.1639 0.84690E+00 -0.0722 17 Ca(HSiO3)+ 0.93408E-08 -8.0296 0.79234E-08 -8.1011 0.84826E+00 -0.0715 18 Mg(HSiO3)+ 0.27077E-11 -11.5674 0.22968E-11 -11.6389 0.84826E+00 -0.0715 19 NaHSiO3,aq 0.15042E-02 -2.8227 0.15042E-02 -2.8227 0.10000E+01 0.0000 20 AlO+ 0.14193E-15 -15.8479 0.12039E-15 -15.9194 0.84826E+00 -0.0715 22 HAlO2,aq 0.27572E-09 -9.5595 0.27572E-09 -9.5595 0.10000E+01 0.0000 23 AlO2- 0.83004E-05 -5.0809 0.70188E-05 -5.1537 0.84560E+00 -0.0728 24 CH4,aq 0.15738E-07 -7.8031 0.15695E-07 -7.8042 0.99725E+00 -0.0012 25 C2H6,aq 0.43383E-19 -19.3627 0.43264E-19 -19.3639 0.99725E+00 -0.0012 29 CO,aq 0.19829E-16 -16.7027 0.19829E-16 -16.7027 0.10000E+01 0.0000 30 CO2,aq 0.81322E-09 -9.0898 0.81098E-09 -9.0910 0.99725E+00 -0.0012 31 CO3-2 0.80125E-05 -5.0962 0.43843E-05 -5.3581 0.54718E+00 -0.2619 32 CaCO3,aq 0.27899E-08 -8.5544 0.27899E-08 -8.5544 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.66655E-11 -11.1762 0.56541E-11 -11.2476 0.84826E+00 -0.0715 34 CaCl+ 0.11364E-10 -10.9445 0.96401E-11 -11.0159 0.84826E+00 -0.0715 35 CaCl2,aq 0.26883E-15 -15.5705 0.26883E-15 -15.5705 0.10000E+01 0.0000 36 CaOH+ 0.49034E-07 -7.3095 0.41594E-07 -7.3810 0.84826E+00 -0.0715 37 CaSO4,aq 0.94768E-13 -13.0233 0.94768E-13 -13.0233 0.10000E+01 0.0000 38 HCl,aq 0.18704E-14 -14.7281 0.18704E-14 -14.7281 0.10000E+01 0.0000 43 FeCl+ 0.83597E-17 -17.0778 0.70912E-17 -17.1493 0.84826E+00 -0.0715 46 FeO,aq 0.19618E-09 -9.7073 0.19618E-09 -9.7073 0.10000E+01 0.0000 47 FeOH+ 0.16843E-10 -10.7736 0.14288E-10 -10.8450 0.84826E+00 -0.0715 48 HFeO2- 0.27873E-07 -7.5548 0.23606E-07 -7.6270 0.84690E+00 -0.0722 49 FeO+ 0.40721E-16 -16.3902 0.34542E-16 -16.4616 0.84826E+00 -0.0715 51 FeO2- 0.11038E-08 -8.9571 0.93477E-09 -9.0293 0.84690E+00 -0.0722 52 HFeO2,aq 0.10338E-10 -10.9856 0.10338E-10 -10.9856 0.10000E+01 0.0000 53 H2,aq 0.97601E-06 -6.0105 0.97333E-06 -6.0117 0.99725E+00 -0.0012 54 KCl,aq 0.22786E-09 -9.6423 0.22786E-09 -9.6423 0.10000E+01 0.0000 56 KOH,aq 0.52601E-06 -6.2790 0.52601E-06 -6.2790 0.10000E+01 0.0000 57 KSO4- 0.11541E-10 -10.9378 0.97737E-11 -11.0099 0.84690E+00 -0.0722 58 MgCO3,aq 0.16288E-12 -12.7881 0.16288E-12 -12.7881 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.15864E-14 -14.7996 0.13457E-14 -14.8710 0.84826E+00 -0.0715 60 MgCl+ 0.23992E-14 -14.6199 0.20351E-14 -14.6914 0.84826E+00 -0.0715 61 MgOH+ 0.63200E-10 -10.1993 0.53610E-10 -10.2708 0.84826E+00 -0.0715 63 MnO,aq 0.12836E-08 -8.8916 0.12836E-08 -8.8916 0.10000E+01 0.0000 64 MnOH+ 0.38421E-09 -9.4154 0.32592E-09 -9.4869 0.84826E+00 -0.0715 65 MnO2-2 0.10296E-10 -10.9873 0.56338E-11 -11.2492 0.54718E+00 -0.2619 66 HMnO2- 0.12673E-09 -9.8971 0.10733E-09 -9.9693 0.84690E+00 -0.0722 69 MnCl+ 0.79861E-14 -14.0977 0.67744E-14 -14.1691 0.84826E+00 -0.0715 70 MnSO4,aq 0.15911E-16 -16.7983 0.15911E-16 -16.7983 0.10000E+01 0.0000 71 NaCl,aq 0.52770E-06 -6.2776 0.52770E-06 -6.2776 0.10000E+01 0.0000 72 NaOH,aq 0.67027E-04 -4.1738 0.67027E-04 -4.1738 0.10000E+01 0.0000 74 OH- 0.78576E-02 -2.1047 0.66444E-02 -2.1775 0.84560E+00 -0.0728 79 HPO3-2 0.27288E-15 -15.5640 0.14931E-15 -15.8259 0.54718E+00 -0.2619 81 H2PO3- 0.30743E-19 -19.5123 0.26036E-19 -19.5844 0.84690E+00 -0.0722 82 H3PO4,aq 0.26033E-17 -17.5845 0.26033E-17 -17.5845 0.10000E+01 0.0000 83 H2PO4- 0.93164E-10 -10.0307 0.78964E-10 -10.1026 0.84757E+00 -0.0718 84 PO4-3 0.16949E-08 -8.7708 0.46188E-09 -9.3355 0.27250E+00 -0.5646 88 HP2O7-3 0.42904E-17 -17.3675 0.11227E-17 -17.9497 0.26167E+00 -0.5822 89 P2O7-4 0.32251E-16 -16.4915 0.30843E-17 -17.5108 0.95636E-01 -1.0194 90 H2S,aq 0.58665E-08 -8.2316 0.58503E-08 -8.2328 0.99725E+00 -0.0012 91 S2-2 0.19716E-13 -13.7052 0.10788E-13 -13.9671 0.54718E+00 -0.2619 97 SO3-2 0.13430E-14 -14.8719 0.74381E-15 -15.1285 0.55385E+00 -0.2566 98 HSO3- 0.47818E-17 -17.3204 0.40497E-17 -17.3926 0.84690E+00 -0.0722 99 HSO4- 0.58049E-15 -15.2362 0.49281E-15 -15.3073 0.84896E+00 -0.0711 101 S2O3-2 0.73859E-18 -18.1316 0.40414E-18 -18.3935 0.54718E+00 -0.2619 Charge balance for all species = -.1531E-12 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.1021553E-09 -.1756608E-01 -.1768168E+02 0.0000 2 H2O 0.1000000E+01 0.5550659E+02 0.9986194E+06 0.0000 3 Cl- 0.1385999E-03 0.1391278E-03 0.4925846E+01 6.1303 4 SO4-- 0.1072806E-07 -.2488624E-06 -.2387388E-01 11.8908 5 HCO3- 0.5147425E-05 0.1317928E-04 0.8030783E+00 4.7007 6 HS- 0.2570111E-04 0.2596658E-04 0.8576086E+00 5.3985 7 Al+++ 0.2559198E-28 0.8300668E-05 0.2236624E+00 1.0076 8 H4SiO4 0.6384499E-03 0.1023775E-01 0.9826787E+03 -3.1949 9 Ca++ 0.9315499E-07 0.1543378E-06 0.6177208E-02 12.8268 10 Mg++ 0.2178223E-10 0.8785666E-10 0.2133091E-05 9.1940 11 Fe++ 0.7026679E-13 0.2920056E-07 0.1628565E-02 6.7031 12 K+ 0.1262857E-03 0.1268120E-03 0.4951915E+01 6.0905 13 Na+ 0.1602023E-01 0.1759196E-01 0.4038901E+03 8.1931 14 Mn++ 0.1724228E-10 0.1822104E-08 0.9996773E-04 9.0932 15 HPO4-- 0.8979136E-07 0.9157946E-07 0.8777851E-02 12.8136 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.1159066E+01 -.1742043E-01 -.1141646E+01 0.0000000E+00 2 H2O 0.5463078E+02 0.5504634E+02 -.4155572E+00 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.1965415E-02 -.2467989E-06 0.1965662E-02 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.1939911E-02 0.2575127E-04 -.1965662E-02 0.0000000E+00 7 Al+++ 0.2282487E+00 0.8231840E-05 0.2282404E+00 0.0000000E+00 8 H4SiO4 0.7288844E+00 0.1015286E-01 0.7187315E+00 0.0000000E+00 9 Ca++ 0.8052331E-01 0.1530580E-06 0.8052315E-01 0.0000000E+00 10 Mg++ 0.5555476E-01 0.8712817E-10 0.5555476E-01 0.0000000E+00 11 Fe++ 0.4990989E-01 0.2895844E-07 0.4990986E-01 0.0000000E+00 12 K+ 0.1486178E-01 0.1257605E-03 0.1473602E-01 0.0000000E+00 13 Na+ 0.8802587E-01 0.1744609E-01 0.7057978E-01 0.0000000E+00 14 Mn++ 0.1213684E-02 0.1806995E-08 0.1213683E-02 0.0000000E+00 15 HPO4-- 0.4142244E-03 0.9082010E-07 0.4141336E-03 0.0000000E+00 Chg. balance for solid moles: 0.1959E-15 Mass of aqueous solution: 0.993047E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 69.9990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 0.7058E-01 -1.151 18.51 1.267 24.23 7.105 andradite 0.7863E-02 -2.104 3.996 0.602 5.230 1.038 grossular 0.1103E-02 -2.958 0.4966 -0.304 0.6501 0.1382 apatite-OH 0.1380E-03 -3.860 0.6934E-01 -1.159 0.9077E-01 0.2203E-01 clinochlore 0.1111E-01 -1.954 6.176 0.791 8.084 2.349 daphnite 0.3764E-02 -2.424 2.686 0.429 3.516 0.8138 chlorite-Mn 0.2427E-03 -3.615 0.1721 -0.764 0.2253 0.5484E-01 microcline 0.1320E-01 -1.879 3.674 0.565 4.809 1.435 stilbite 0.5294E-01 -1.276 37.31 1.572 48.83 17.40 stilpnomelane-Fe 0.3073E-02 -2.512 3.313 0.520 4.336 1.144 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8770E+00 0.8770E+00 1.0000 -0.057 grossular 0.1230E+00 0.1230E+00 1.0000 -0.910 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.7350E+00 0.7350E+00 1.0000 -0.134 daphnite 0.2490E+00 0.2490E+00 1.0000 -0.604 chlorite-Mn 0.1606E-01 0.1606E-01 1.0000 -1.794 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 76.395149 g Volume = 31.500257 cm3 Porosity: -8.6231% V(tot) - V(min): -.25007E+01 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 69.9990000 g log = 1.8451 Original solution: 1000.0103000 g Original solution / Rock added: 14.29 (Water/Rock Ratio), log = 1.1549 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0216 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9987E+00 0.9859 0.1006E+01 0.1020E+01 CO2,gas 0.8433E-07 1.0071 0.8677E-07 0.8615E-07 CH4,gas 0.2233E-04 1.0125 0.2310E-04 0.2282E-04 H2,gas 0.1250E-02 1.0005 0.1278E-02 0.1277E-02 H2S,gas 0.1580E-06 0.9960 0.1608E-06 0.1615E-06 S2,gas 0.5819E-27 1.0000 0.5945E-27 0.5945E-27 CO,gas 0.2892E-13 1.0000 0.2955E-13 0.2955E-13 SO3,gas 0.1646E-43 1.0000 0.1681E-43 0.1681E-43 SO2,gas 0.8182E-24 1.0000 0.8359E-24 0.8359E-24 HCl,gas 0.3230E-17 1.0000 0.3300E-17 0.3300E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 16 albite -0.38 -0.38 0.00 0.000 -0.13080E-10 22 andradite 39.01 39.01 0.00 0.000 0.12132E-10 23 grossular 32.73 32.73 0.00 0.000 0.12132E-10 32 apatite-OH -18.15 -18.15 0.00 0.000 -0.12132E-10 46 clinochlore 39.07 39.07 0.00 0.000 -0.36397E-10 47 daphnite 28.97 28.97 0.00 0.000 -0.48529E-10 48 chlorite-Mn 46.87 46.87 0.00 0.000 -0.24265E-10 116 microcline -2.49 -2.49 0.00 0.000 0.15165E-11 163 stilbite -7.52 -7.52 0.00 0.000 -0.33364E-10 164 stilpnomelane-Fe 13.02 13.02 0.00 0.000 -0.27298E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -15.42 -8.76 -2.920 0.14959E+05 -7.062 3 CH4,gas 4.54 -1.79 -6.34 -1.584 0.10817E+05 -4.636 4 H2,gas 8.00 3.41 -4.59 -2.624 0.78415E+04 -2.894 5 H2S,gas -6.23 -14.72 -8.49 -4.246 0.14501E+05 -6.794 6 S2,gas -7.34 -36.26 -28.92 -4.450 0.49388E+05 -27.226 7 CO,gas 3.21 -12.01 -15.23 -4.686 0.26002E+05 -13.529 8 SO3,gas 17.12 -28.35 -45.47 -11.368 0.77644E+05 -43.774 9 SO2,gas 0.83 -24.94 -25.78 -6.874 0.44013E+05 -24.078 10 HCl,gas 5.19 -13.99 -19.18 -9.590 0.32750E+05 -17.481 11 acmite 7.71 6.80 -0.91 -0.094 0.15485E+04 15 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 19 spessartine 24.46 19.71 -4.75 -0.237 0.81054E+04 20 analcite 3.32 2.81 -0.51 -0.057 0.87227E+03 26 annite 20.12 17.62 -2.50 -0.139 0.42697E+04 27 phlogopite 27.06 25.10 -1.97 -0.109 0.33619E+04 29 anorthite 12.71 8.45 -4.26 -0.328 0.72704E+04 35 aragonite 0.97 -2.59 -3.56 -1.187 0.60794E+04 36 brucite 12.57 9.19 -3.37 -0.675 0.57619E+04 37 calcite 0.81 -2.59 -3.41 -1.135 0.58151E+04 38 carnegieite-low 9.02 6.01 -3.02 -0.431 0.51522E+04 39 carnegieite-high 10.09 6.01 -4.09 -0.584 0.69792E+04 40 carpholite-Mg 8.58 4.82 -3.76 -0.251 0.64245E+04 41 carpholite-Fe 6.71 2.33 -4.38 -0.292 0.74857E+04 42 celadonite 5.34 3.51 -1.83 -0.108 0.31228E+04 43 celadonite-Fe 3.88 1.02 -2.85 -0.168 0.48745E+04 44 chrysotile 23.89 21.19 -2.70 -0.225 0.46102E+04 49 chlorite-Al-free 47.17 42.38 -4.79 -0.200 0.81755E+04 51 chloritoid-Fe 9.17 5.52 -3.65 -0.243 0.62326E+04 52 chloritoid-Mn 11.40 7.91 -3.49 -0.232 0.59548E+04 54 coesite -2.38 -3.19 -0.82 -0.273 0.13981E+04 61 cristobalite -2.56 -3.19 -0.63 -0.212 0.10835E+04 63 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71234E+04 65 diaspore 2.87 1.01 -1.87 -0.311 0.31863E+04 67 diopside 16.18 15.63 -0.55 -0.055 0.93951E+03 68 hedenbergite 14.21 13.14 -1.07 -0.107 0.18238E+04 75 epidote 24.67 23.08 -1.59 -0.077 0.27084E+04 76 clinozoisite 22.81 19.09 -3.71 -0.169 0.63418E+04 77 epidote-Fe 29.84 27.08 -2.77 -0.144 0.47216E+04 78 fayalite 14.05 10.21 -3.83 -0.548 0.65472E+04 79 ferrosilite 11.15 7.02 -4.13 -0.413 0.70570E+04 83 gibbsite 4.08 1.01 -3.07 -0.439 0.52448E+04 84 glaucophane 22.97 20.42 -2.55 -0.069 0.43543E+04 85 glaucophane-Fe 17.28 12.95 -4.32 -0.117 0.73831E+04 87 greenalite 16.14 13.72 -2.42 -0.202 0.41320E+04 90 hematite 12.57 10.00 -2.57 -0.311 0.43835E+04 91 heulandite -5.83 -7.52 -1.69 -0.077 0.28938E+04 95 jadeite 4.22 2.81 -1.40 -0.140 0.23978E+04 96 julgoldite 70.43 65.54 -4.88 -0.127 0.83407E+04 97 kalsilite 7.58 3.90 -3.68 -0.526 0.62846E+04 98 kaolinite -1.33 -4.37 -3.04 -0.277 0.51937E+04 101 laumontite 2.88 2.06 -0.82 -0.055 0.14016E+04 102 lawsonite 9.62 8.45 -1.16 -0.078 0.19871E+04 103 leucite 4.12 0.71 -3.41 -0.341 0.58233E+04 105 lizardite 23.24 21.19 -2.05 -0.171 0.35028E+04 107 magnetite 20.09 16.70 -3.39 -0.276 0.57805E+04 108 minnesotaite 10.39 7.33 -3.06 -0.180 0.52220E+04 112 manganosite 14.06 9.09 -4.96 -1.241 0.84774E+04 120 muscovite 2.58 -0.47 -3.05 -0.180 0.52141E+04 121 paragonite 4.24 1.63 -2.61 -0.153 0.44532E+04 122 nepheline 8.34 6.01 -2.33 -0.333 0.39845E+04 128 periclase-Fe 11.63 6.70 -4.92 -1.231 0.84067E+04 134 phlogopite-Na 29.65 27.20 -2.45 -0.136 0.41807E+04 136 prehnite 19.37 18.08 -1.29 -0.076 0.21986E+04 137 prehnite-Fe 22.50 22.08 -0.42 -0.025 0.72014E+03 138 pumpellyite-Fe 46.27 43.88 -2.39 -0.053 0.40812E+04 139 pumpellyite-Mg 48.99 46.37 -2.62 -0.058 0.44816E+04 142 pyrite -21.25 -26.15 -4.90 -1.154 0.83717E+04 143 pyrrhotite -4.26 -8.02 -3.76 -1.253 0.64192E+04 144 pyrrhotiteFe0.875 -6.02 -9.28 -3.26 -1.200 0.55718E+04 145 pyroxmangite 7.40 5.90 -1.50 -0.300 0.25617E+04 146 pyrophyllite -6.18 -10.76 -4.59 -0.287 0.78347E+04 147 quartz -2.99 -3.19 -0.21 -0.068 0.35078E+03 152 rhodonite 7.45 5.90 -1.55 -0.309 0.26420E+04 153 sanidine -1.28 -2.49 -1.21 -0.093 0.20677E+04 165 stilpnomelane-Mg 27.44 25.47 -1.97 -0.059 0.33632E+04 171 talc 16.49 14.80 -1.69 -0.099 0.28829E+04 174 tephroite 18.09 14.99 -3.09 -0.442 0.52832E+04 178 tridymite -2.63 -3.19 -0.57 -0.190 0.97076E+03 179 tremolite 47.87 46.06 -1.80 -0.049 0.30809E+04 180 ferroactinolite 38.45 33.61 -4.84 -0.131 0.82680E+04 181 troilite-low -4.41 -8.02 -3.61 -1.203 0.61620E+04 187 wairakite 3.95 2.06 -1.89 -0.111 0.32235E+04 188 walstromite 11.51 9.63 -1.88 -0.375 0.32054E+04 189 wollastonite 10.46 9.63 -0.83 -0.166 0.14158E+04 190 pseudo-wollastonite 11.00 9.63 -1.37 -0.274 0.23357E+04 191 zoisite 22.85 19.09 -3.76 -0.171 0.64159E+04 192 akaganeite 7.75 5.00 -2.76 -0.596 0.47043E+04 199 chalcedony -2.80 -3.19 -0.39 -0.131 0.67008E+03 201 montmorillonite-Ca -2.29 -5.95 -3.66 -0.226 0.62418E+04 202 montmorillonite-K -2.24 -6.05 -3.82 -0.234 0.65160E+04 203 montmorillonite-Mg -2.48 -6.55 -4.07 -0.252 0.69423E+04 204 montmorillonite-Na -2.04 -5.36 -3.32 -0.203 0.56709E+04 205 nontronite-Ca 3.21 0.72 -2.49 -0.162 0.42548E+04 206 nontronite-H 2.53 -1.39 -3.93 -0.263 0.67043E+04 207 nontronite-K 3.34 0.62 -2.72 -0.175 0.46522E+04 208 nontronite-Mg 3.07 0.12 -2.95 -0.191 0.50394E+04 209 nontronite-Na 3.52 1.31 -2.21 -0.142 0.37730E+04 224 tobermorite 9.82 7.49 -2.33 -0.637 0.39838E+04 230 alabandite -0.98 -5.63 -4.65 -1.551 0.79427E+04 233 boehmite 4.41 1.01 -3.40 -0.566 0.58032E+04 235 ferrous-oxide 9.81 6.70 -3.11 -0.777 0.53077E+04 240 silica-amorphous -2.09 -3.19 -1.10 -0.368 0.18843E+04 242 an20ab80 2.02 1.38 -0.63 -0.049 0.10832E+04 243 an25ab75 2.65 1.83 -0.82 -0.063 0.14010E+04 244 an30ab70 3.28 2.27 -1.01 -0.078 0.17284E+04 245 tr.625ac.25prg.125 45.16 44.00 -1.16 -0.031 0.19842E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 2.0000000 g Current total amount of reactant added: 69.9990000 g New total amount of reactant added: 71.9990000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.1492E-12 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 9 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 71.9990000 Water: Moles liquid = 0.5504E+02 kg liquid = 0.9915E+00 Moles total = 0.5461E+02 kg total = 0.9837E+00 Activity = 1.0000 Stoichiometric ionic strength = .9152159E-02 Osmotic coef. = 0.9647 True ionic strength = .1643244E-01 Chg. balance for total moles = -.1492E-12 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.10105E-09 -9.9954 0.85933E-10 -10.0658 0.85036E+00 -0.0704 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13862E-03 -3.8582 0.11727E-03 -3.9308 0.84599E+00 -0.0726 4 SO4-- 0.51935E-08 -8.2845 0.28351E-08 -8.5474 0.54589E+00 -0.2629 5 HCO3- 0.50953E-05 -5.2928 0.43160E-05 -5.3649 0.84705E+00 -0.0721 6 HS- 0.25713E-04 -4.5899 0.21755E-04 -4.6624 0.84610E+00 -0.0726 7 Al+++ 0.23638E-28 -28.6264 0.61219E-29 -29.2131 0.25899E+00 -0.5867 8 H4SiO4 0.64393E-03 -3.1912 0.64393E-03 -3.1912 0.10000E+01 0.0000 9 Ca++ 0.95765E-07 -7.0188 0.51950E-07 -7.2844 0.54247E+00 -0.2656 10 Mg++ 0.21795E-10 -10.6616 0.11777E-10 -10.9290 0.54035E+00 -0.2673 11 Fe++ 0.69258E-13 -13.1595 0.37458E-13 -13.4265 0.54086E+00 -0.2669 12 K+ 0.12845E-03 -3.8913 0.10883E-03 -3.9633 0.84722E+00 -0.0720 13 Na+ 0.16295E-01 -1.7879 0.13784E-01 -1.8606 0.84587E+00 -0.0727 14 Mn++ 0.17252E-10 -10.7632 0.93375E-11 -11.0298 0.54124E+00 -0.2666 15 HPO4-- 0.85360E-07 -7.0687 0.46603E-07 -7.3316 0.54595E+00 -0.2628 16 HSiO3- 0.82706E-02 -2.0825 0.69969E-02 -2.1551 0.84599E+00 -0.0726 17 Ca(HSiO3)+ 0.97689E-08 -8.0102 0.82779E-08 -8.0821 0.84738E+00 -0.0719 18 Mg(HSiO3)+ 0.27561E-11 -11.5597 0.23355E-11 -11.6316 0.84738E+00 -0.0719 19 NaHSiO3,aq 0.15598E-02 -2.8069 0.15598E-02 -2.8069 0.10000E+01 0.0000 20 AlO+ 0.13310E-15 -15.8758 0.11278E-15 -15.9478 0.84738E+00 -0.0719 22 HAlO2,aq 0.26138E-09 -9.5827 0.26138E-09 -9.5827 0.10000E+01 0.0000 23 AlO2- 0.79709E-05 -5.0985 0.67329E-05 -5.1718 0.84468E+00 -0.0733 24 CH4,aq 0.32262E-07 -7.4913 0.32171E-07 -7.4925 0.99720E+00 -0.0012 25 C2H6,aq 0.15148E-18 -18.8197 0.15105E-18 -18.8209 0.99720E+00 -0.0012 29 CO,aq 0.23320E-16 -16.6323 0.23320E-16 -16.6323 0.10000E+01 0.0000 30 CO2,aq 0.79472E-09 -9.0998 0.79249E-09 -9.1010 0.99720E+00 -0.0012 31 CO3-2 0.80510E-05 -5.0942 0.43870E-05 -5.3578 0.54490E+00 -0.2637 32 CaCO3,aq 0.28576E-08 -8.5440 0.28576E-08 -8.5440 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.67541E-11 -11.1704 0.57233E-11 -11.2424 0.84738E+00 -0.0719 34 CaCl+ 0.11635E-10 -10.9342 0.98593E-11 -11.0062 0.84738E+00 -0.0719 35 CaCl2,aq 0.27470E-15 -15.5611 0.27470E-15 -15.5611 0.10000E+01 0.0000 36 CaOH+ 0.50845E-07 -7.2938 0.43085E-07 -7.3657 0.84738E+00 -0.0719 37 CaSO4,aq 0.46769E-13 -13.3300 0.46769E-13 -13.3300 0.10000E+01 0.0000 38 HCl,aq 0.18467E-14 -14.7336 0.18467E-14 -14.7336 0.10000E+01 0.0000 43 FeCl+ 0.82056E-17 -17.0859 0.69532E-17 -17.1578 0.84738E+00 -0.0719 46 FeO,aq 0.19715E-09 -9.7052 0.19715E-09 -9.7052 0.10000E+01 0.0000 47 FeOH+ 0.16745E-10 -10.7761 0.14189E-10 -10.8480 0.84738E+00 -0.0719 48 HFeO2- 0.28375E-07 -7.5471 0.24005E-07 -7.6197 0.84599E+00 -0.0726 49 FeO+ 0.36903E-16 -16.4329 0.31270E-16 -16.5049 0.84738E+00 -0.0719 51 FeO2- 0.10242E-08 -8.9896 0.86649E-09 -9.0622 0.84599E+00 -0.0726 52 HFeO2,aq 0.94702E-11 -11.0236 0.94702E-11 -11.0236 0.10000E+01 0.0000 53 H2,aq 0.11747E-05 -5.9301 0.11714E-05 -5.9313 0.99720E+00 -0.0012 54 KCl,aq 0.23131E-09 -9.6358 0.23131E-09 -9.6358 0.10000E+01 0.0000 56 KOH,aq 0.54084E-06 -6.2669 0.54084E-06 -6.2669 0.10000E+01 0.0000 57 KSO4- 0.56593E-11 -11.2472 0.47877E-11 -11.3199 0.84599E+00 -0.0726 58 MgCO3,aq 0.16238E-12 -12.7895 0.16238E-12 -12.7895 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.15646E-14 -14.8056 0.13258E-14 -14.8775 0.84738E+00 -0.0719 60 MgCl+ 0.23907E-14 -14.6215 0.20258E-14 -14.6934 0.84738E+00 -0.0719 61 MgOH+ 0.63783E-10 -10.1953 0.54048E-10 -10.2672 0.84738E+00 -0.0719 63 MnO,aq 0.13095E-08 -8.8829 0.13095E-08 -8.8829 0.10000E+01 0.0000 64 MnOH+ 0.38776E-09 -9.4114 0.32858E-09 -9.4834 0.84738E+00 -0.0719 65 MnO2-2 0.10801E-10 -10.9666 0.58852E-11 -11.2302 0.54490E+00 -0.2637 66 HMnO2- 0.13097E-09 -9.8828 0.11080E-09 -9.9555 0.84599E+00 -0.0726 69 MnCl+ 0.79578E-14 -14.0992 0.67433E-14 -14.1711 0.84738E+00 -0.0719 70 MnSO4,aq 0.76424E-17 -17.1168 0.76424E-17 -17.1168 0.10000E+01 0.0000 71 NaCl,aq 0.53571E-06 -6.2711 0.53571E-06 -6.2711 0.10000E+01 0.0000 72 NaOH,aq 0.68916E-04 -4.1617 0.68916E-04 -4.1617 0.10000E+01 0.0000 74 OH- 0.79599E-02 -2.0991 0.67235E-02 -2.1724 0.84468E+00 -0.0733 79 HPO3-2 0.31220E-15 -15.5056 0.17012E-15 -15.7692 0.54490E+00 -0.2637 81 H2PO3- 0.34652E-19 -19.4603 0.29315E-19 -19.5329 0.84599E+00 -0.0726 82 H3PO4,aq 0.24069E-17 -17.6185 0.24069E-17 -17.6185 0.10000E+01 0.0000 83 H2PO4- 0.87254E-10 -10.0592 0.73876E-10 -10.1315 0.84668E+00 -0.0723 84 PO4-3 0.16383E-08 -8.7856 0.44247E-09 -9.3541 0.27008E+00 -0.5685 88 HP2O7-3 0.38364E-17 -17.4161 0.99437E-18 -18.0025 0.25920E+00 -0.5864 89 P2O7-4 0.29388E-16 -16.5318 0.27644E-17 -17.5584 0.94066E-01 -1.0266 90 H2S,aq 0.57941E-08 -8.2370 0.57779E-08 -8.2382 0.99720E+00 -0.0012 91 S2-2 0.16431E-13 -13.7843 0.89530E-14 -14.0480 0.54490E+00 -0.2637 97 SO3-2 0.78232E-15 -15.1066 0.43155E-15 -15.3650 0.55163E+00 -0.2584 98 HSO3- 0.27446E-17 -17.5615 0.23219E-17 -17.6341 0.84599E+00 -0.0726 99 HSO4- 0.27685E-15 -15.5578 0.23479E-15 -15.6293 0.84808E+00 -0.0716 101 S2O3-2 0.35314E-18 -18.4521 0.19242E-18 -18.7157 0.54490E+00 -0.2637 Charge balance for all species = -.1533E-12 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.1010542E-09 -.1790015E-01 -.1801745E+02 0.0000 2 H2O 0.1000000E+01 0.5550647E+02 0.9985893E+06 0.0000 3 Cl- 0.1386232E-03 0.1391592E-03 0.4926820E+01 6.1350 4 SO4-- 0.5193521E-08 -.3205976E-06 -.3075473E-01 11.5842 5 HCO3- 0.5095328E-05 0.1318225E-04 0.8032370E+00 4.7009 6 HS- 0.2571252E-04 0.2604411E-04 0.8601454E+00 5.4034 7 Al+++ 0.2363778E-28 0.7971182E-05 0.2147784E+00 0.9844 8 H4SiO4 0.6439272E-03 0.1047440E-01 0.1005365E+04 -3.1912 9 Ca++ 0.9576473E-07 0.1592548E-06 0.6373829E-02 12.8473 10 Mg++ 0.2179519E-10 0.8850048E-10 0.2148662E-05 9.2027 11 Fe++ 0.6925764E-13 0.2962243E-07 0.1652047E-02 6.7052 12 K+ 0.1284527E-03 0.1289938E-03 0.5036973E+01 6.1026 13 Na+ 0.1629549E-01 0.1792478E-01 0.4115199E+03 8.2052 14 Mn++ 0.1725216E-10 0.1856291E-08 0.1018405E-03 9.1019 15 HPO4-- 0.8536045E-07 0.8708600E-07 0.8346923E-02 12.8001 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.1192184E+01 -.1774772E-01 -.1174436E+01 0.0000000E+00 2 H2O 0.5460571E+02 0.5503381E+02 -.4280929E+00 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.2020842E-02 -.3178676E-06 0.2021160E-02 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.1995338E-02 0.2582234E-04 -.2021160E-02 0.0000000E+00 7 Al+++ 0.2347701E+00 0.7903304E-05 0.2347622E+00 0.0000000E+00 8 H4SiO4 0.7497100E+00 0.1038520E-01 0.7393248E+00 0.0000000E+00 9 Ca++ 0.8282359E-01 0.1578987E-06 0.8282343E-01 0.0000000E+00 10 Mg++ 0.5714206E-01 0.8774686E-10 0.5714206E-01 0.0000000E+00 11 Fe++ 0.5133591E-01 0.2937019E-07 0.5133588E-01 0.0000000E+00 12 K+ 0.1528641E-01 0.1278954E-03 0.1515852E-01 0.0000000E+00 13 Na+ 0.9053636E-01 0.1777214E-01 0.7276421E-01 0.0000000E+00 14 Mn++ 0.1248362E-02 0.1840484E-08 0.1248360E-02 0.0000000E+00 15 HPO4-- 0.4260596E-03 0.8634442E-07 0.4259733E-03 0.0000000E+00 Chg. balance for solid moles: -.1611E-15 Mass of aqueous solution: 0.992851E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 71.9990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 0.7276E-01 -1.138 19.08 1.281 24.28 7.324 andradite 0.8085E-02 -2.092 4.108 0.614 5.229 1.067 grossular 0.1173E-02 -2.931 0.5285 -0.277 0.6725 0.1470 apatite-OH 0.1420E-03 -3.848 0.7132E-01 -1.147 0.9077E-01 0.2266E-01 clinochlore 0.1143E-01 -1.942 6.352 0.803 8.084 2.416 daphnite 0.3814E-02 -2.419 2.721 0.435 3.463 0.8246 chlorite-Mn 0.2497E-03 -3.603 0.1770 -0.752 0.2253 0.5641E-01 microcline 0.1355E-01 -1.868 3.771 0.576 4.799 1.473 stilbite 0.5434E-01 -1.265 38.29 1.583 48.74 17.86 stilpnomelane-Fe 0.3220E-02 -2.492 3.471 0.540 4.417 1.199 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8733E+00 0.8733E+00 1.0000 -0.059 grossular 0.1267E+00 0.1267E+00 1.0000 -0.897 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.7377E+00 0.7377E+00 1.0000 -0.132 daphnite 0.2462E+00 0.2462E+00 1.0000 -0.609 chlorite-Mn 0.1612E-01 0.1612E-01 1.0000 -1.793 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 78.575214 g Volume = 32.392005 cm3 Porosity: -8.6995% V(tot) - V(min): -.25924E+01 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 71.9990000 g log = 1.8573 Original solution: 1000.0103000 g Original solution / Rock added: 13.89 (Water/Rock Ratio), log = 1.1427 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0219 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9984E+00 0.9859 0.1006E+01 0.1020E+01 CO2,gas 0.8239E-07 1.0071 0.8479E-07 0.8419E-07 CH4,gas 0.4577E-04 1.0125 0.4735E-04 0.4677E-04 H2,gas 0.1504E-02 1.0005 0.1538E-02 0.1537E-02 H2S,gas 0.1560E-06 0.9960 0.1588E-06 0.1595E-06 S2,gas 0.3918E-27 1.0000 0.4004E-27 0.4004E-27 CO,gas 0.3401E-13 1.0000 0.3475E-13 0.3475E-13 SO3,gas 0.7746E-44 1.0000 0.7916E-44 0.7916E-44 SO2,gas 0.4635E-24 1.0000 0.4736E-24 0.4736E-24 HCl,gas 0.3189E-17 1.0000 0.3259E-17 0.3259E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 16 albite -0.38 -0.38 0.00 0.000 -0.94784E-12 22 andradite 39.01 39.01 0.00 0.000 0.24265E-10 23 grossular 32.73 32.73 0.00 0.000 0.24265E-10 32 apatite-OH -18.15 -18.15 0.00 0.000 -0.12132E-10 46 clinochlore 39.07 39.07 0.00 0.000 -0.24265E-10 47 daphnite 28.97 28.97 0.00 0.000 -0.42463E-10 48 chlorite-Mn 46.87 46.87 0.00 0.000 -0.24265E-10 116 microcline -2.49 -2.49 0.00 0.000 -0.22748E-10 163 stilbite -7.52 -7.52 0.00 0.000 -0.90992E-11 164 stilpnomelane-Fe 13.02 13.02 0.00 0.000 -0.27298E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -15.43 -8.77 -2.924 0.14976E+05 -7.072 3 CH4,gas 4.54 -1.48 -6.02 -1.506 0.10285E+05 -4.325 4 H2,gas 8.00 3.49 -4.51 -2.578 0.77042E+04 -2.813 5 H2S,gas -6.23 -14.73 -8.50 -4.249 0.14510E+05 -6.799 6 S2,gas -7.34 -36.43 -29.10 -4.476 0.49681E+05 -27.398 7 CO,gas 3.21 -11.94 -15.16 -4.664 0.25882E+05 -13.459 8 SO3,gas 17.12 -28.68 -45.80 -11.450 0.78203E+05 -44.102 9 SO2,gas 0.83 -25.19 -26.02 -6.940 0.44435E+05 -24.325 10 HCl,gas 5.19 -14.00 -19.19 -9.593 0.32759E+05 -17.487 11 acmite 7.71 6.78 -0.93 -0.096 0.15802E+04 15 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 19 spessartine 24.46 19.70 -4.76 -0.238 0.81212E+04 20 analcite 3.32 2.81 -0.51 -0.057 0.87860E+03 26 annite 20.12 17.63 -2.49 -0.139 0.42588E+04 27 phlogopite 27.06 25.12 -1.94 -0.108 0.33175E+04 29 anorthite 12.71 8.43 -4.28 -0.329 0.73021E+04 35 aragonite 0.97 -2.58 -3.55 -1.183 0.60616E+04 36 brucite 12.57 9.20 -3.37 -0.673 0.57471E+04 37 calcite 0.81 -2.58 -3.40 -1.132 0.57973E+04 38 carnegieite-low 9.02 6.00 -3.02 -0.432 0.51648E+04 39 carnegieite-high 10.09 6.00 -4.09 -0.585 0.69918E+04 40 carpholite-Mg 8.58 4.79 -3.79 -0.253 0.64762E+04 41 carpholite-Fe 6.71 2.29 -4.42 -0.295 0.75486E+04 42 celadonite 5.34 3.53 -1.82 -0.107 0.31017E+04 43 celadonite-Fe 3.88 1.03 -2.85 -0.168 0.48645E+04 44 chrysotile 23.89 21.23 -2.67 -0.222 0.45531E+04 49 chlorite-Al-free 47.17 42.45 -4.72 -0.197 0.80613E+04 51 chloritoid-Fe 9.17 5.48 -3.69 -0.246 0.63018E+04 52 chloritoid-Mn 11.40 7.88 -3.52 -0.235 0.60129E+04 54 coesite -2.38 -3.19 -0.82 -0.272 0.13918E+04 61 cristobalite -2.56 -3.19 -0.63 -0.210 0.10771E+04 63 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71234E+04 65 diaspore 2.87 0.98 -1.89 -0.315 0.32259E+04 67 diopside 16.18 15.67 -0.51 -0.051 0.87713E+03 68 hedenbergite 14.21 13.17 -1.04 -0.104 0.17725E+04 75 epidote 24.67 23.05 -1.62 -0.078 0.27638E+04 76 clinozoisite 22.81 19.07 -3.73 -0.170 0.63719E+04 77 epidote-Fe 29.84 27.03 -2.81 -0.146 0.48024E+04 78 fayalite 14.05 10.22 -3.83 -0.547 0.65335E+04 79 ferrosilite 11.15 7.03 -4.12 -0.412 0.70370E+04 83 gibbsite 4.08 0.98 -3.09 -0.442 0.52844E+04 84 glaucophane 22.97 20.46 -2.52 -0.068 0.42972E+04 85 glaucophane-Fe 17.28 12.97 -4.31 -0.116 0.73595E+04 86 graphite -3.55 -8.46 -4.91 -1.403 0.83823E+04 87 greenalite 16.14 13.73 -2.41 -0.201 0.41084E+04 90 hematite 12.57 9.92 -2.64 -0.320 0.45136E+04 91 heulandite -5.83 -7.52 -1.69 -0.077 0.28938E+04 95 jadeite 4.22 2.81 -1.41 -0.141 0.24041E+04 96 julgoldite 70.43 65.50 -4.93 -0.128 0.84159E+04 97 kalsilite 7.58 3.90 -3.69 -0.527 0.62973E+04 98 kaolinite -1.33 -4.41 -3.08 -0.280 0.52603E+04 101 laumontite 2.88 2.05 -0.83 -0.055 0.14206E+04 102 lawsonite 9.62 8.43 -1.18 -0.079 0.20188E+04 103 leucite 4.12 0.70 -3.41 -0.341 0.58296E+04 105 lizardite 23.24 21.23 -2.02 -0.168 0.34457E+04 107 magnetite 20.09 16.63 -3.46 -0.282 0.59068E+04 108 minnesotaite 10.39 7.35 -3.04 -0.179 0.51857E+04 112 manganosite 14.06 9.10 -4.96 -1.239 0.84626E+04 120 muscovite 2.58 -0.52 -3.10 -0.182 0.52933E+04 121 paragonite 4.24 1.58 -2.65 -0.156 0.45324E+04 122 nepheline 8.34 6.00 -2.34 -0.334 0.39972E+04 128 periclase-Fe 11.63 6.71 -4.92 -1.230 0.84031E+04 134 phlogopite-Na 29.65 27.22 -2.42 -0.135 0.41363E+04 136 prehnite 19.37 18.09 -1.28 -0.075 0.21890E+04 137 prehnite-Fe 22.50 22.07 -0.43 -0.026 0.73598E+03 138 pumpellyite-Fe 46.27 43.87 -2.40 -0.053 0.40980E+04 139 pumpellyite-Mg 48.99 46.37 -2.63 -0.058 0.44873E+04 142 pyrite -21.25 -26.24 -4.99 -1.175 0.85239E+04 143 pyrrhotite -4.26 -8.02 -3.76 -1.254 0.64247E+04 144 pyrrhotiteFe0.875 -6.02 -9.29 -3.28 -1.205 0.55949E+04 145 pyroxmangite 7.40 5.91 -1.49 -0.298 0.25406E+04 146 pyrophyllite -6.18 -10.80 -4.62 -0.289 0.78886E+04 147 quartz -2.99 -3.19 -0.20 -0.067 0.34445E+03 152 rhodonite 7.45 5.91 -1.53 -0.307 0.26208E+04 153 sanidine -1.28 -2.49 -1.21 -0.093 0.20677E+04 165 stilpnomelane-Mg 27.44 25.50 -1.94 -0.058 0.33074E+04 171 talc 16.49 14.84 -1.65 -0.097 0.28132E+04 174 tephroite 18.09 15.01 -3.07 -0.439 0.52473E+04 178 tridymite -2.63 -3.19 -0.56 -0.188 0.96442E+03 179 tremolite 47.87 46.18 -1.69 -0.046 0.28864E+04 180 ferroactinolite 38.45 33.69 -4.76 -0.129 0.81293E+04 181 troilite-low -4.41 -8.02 -3.61 -1.204 0.61676E+04 187 wairakite 3.95 2.05 -1.90 -0.112 0.32425E+04 188 walstromite 11.51 9.66 -1.85 -0.371 0.31642E+04 189 wollastonite 10.46 9.66 -0.81 -0.161 0.13746E+04 190 pseudo-wollastonite 11.00 9.66 -1.34 -0.269 0.22944E+04 191 zoisite 22.85 19.07 -3.78 -0.172 0.64459E+04 192 akaganeite 7.75 4.96 -2.79 -0.604 0.47693E+04 199 chalcedony -2.80 -3.19 -0.39 -0.130 0.66374E+03 201 montmorillonite-Ca -2.29 -5.96 -3.67 -0.227 0.62720E+04 202 montmorillonite-K -2.24 -6.07 -3.83 -0.235 0.65451E+04 203 montmorillonite-Mg -2.48 -6.57 -4.09 -0.253 0.69758E+04 204 montmorillonite-Na -2.04 -5.38 -3.34 -0.204 0.57000E+04 205 nontronite-Ca 3.21 0.66 -2.56 -0.166 0.43689E+04 206 nontronite-H 2.53 -1.46 -4.00 -0.268 0.68242E+04 207 nontronite-K 3.34 0.55 -2.79 -0.179 0.47652E+04 208 nontronite-Mg 3.07 0.05 -3.02 -0.196 0.51568E+04 209 nontronite-Na 3.52 1.24 -2.28 -0.146 0.38861E+04 224 tobermorite 9.82 7.51 -2.31 -0.631 0.39484E+04 230 alabandite -0.98 -5.63 -4.65 -1.549 0.79372E+04 233 boehmite 4.41 0.98 -3.42 -0.570 0.58428E+04 235 ferrous-oxide 9.81 6.71 -3.11 -0.777 0.53040E+04 240 silica-amorphous -2.09 -3.19 -1.10 -0.367 0.18779E+04 242 an20ab80 2.02 1.38 -0.64 -0.049 0.10896E+04 243 an25ab75 2.65 1.82 -0.83 -0.063 0.14089E+04 244 an30ab70 3.28 2.26 -1.02 -0.078 0.17379E+04 245 tr.625ac.25prg.125 45.16 44.10 -1.07 -0.029 0.18194E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 2.0000000 g Current total amount of reactant added: 71.9990000 g New total amount of reactant added: 73.9990000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.1491E-12 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 9 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 73.9990000 Water: Moles liquid = 0.5502E+02 kg liquid = 0.9913E+00 Moles total = 0.5458E+02 kg total = 0.9833E+00 Activity = 1.0000 Stoichiometric ionic strength = .9315904E-02 Osmotic coef. = 0.9645 True ionic strength = .1670514E-01 Chg. balance for total moles = -.1491E-12 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.10002E-09 -9.9999 0.84968E-10 -10.0707 0.84954E+00 -0.0708 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13865E-03 -3.8581 0.11717E-03 -3.9312 0.84511E+00 -0.0731 4 SO4-- 0.25882E-08 -8.5870 0.14071E-08 -8.8517 0.54369E+00 -0.2647 5 HCO3- 0.50395E-05 -5.2976 0.42644E-05 -5.3701 0.84618E+00 -0.0725 6 HS- 0.25721E-04 -4.5897 0.21740E-04 -4.6627 0.84522E+00 -0.0730 7 Al+++ 0.21889E-28 -28.6598 0.56170E-29 -29.2505 0.25661E+00 -0.5907 8 H4SiO4 0.64942E-03 -3.1875 0.64942E-03 -3.1875 0.10000E+01 0.0000 9 Ca++ 0.98334E-07 -7.0073 0.53124E-07 -7.2747 0.54024E+00 -0.2674 10 Mg++ 0.21817E-10 -10.6612 0.11740E-10 -10.9303 0.53810E+00 -0.2691 11 Fe++ 0.68308E-13 -13.1655 0.36791E-13 -13.4343 0.53861E+00 -0.2687 12 K+ 0.13058E-03 -3.8841 0.11052E-03 -3.9566 0.84636E+00 -0.0724 13 Na+ 0.16566E-01 -1.7808 0.13998E-01 -1.8539 0.84498E+00 -0.0732 14 Mn++ 0.17269E-10 -10.7627 0.93079E-11 -11.0311 0.53900E+00 -0.2684 15 HPO4-- 0.81338E-07 -7.0897 0.44228E-07 -7.3543 0.54375E+00 -0.2646 16 HSiO3- 0.84447E-02 -2.0734 0.71367E-02 -2.1465 0.84511E+00 -0.0731 17 Ca(HSiO3)+ 0.10200E-07 -7.9914 0.86342E-08 -8.0638 0.84652E+00 -0.0724 18 Mg(HSiO3)+ 0.28051E-11 -11.5520 0.23746E-11 -11.6244 0.84652E+00 -0.0724 19 NaHSiO3,aq 0.16157E-02 -2.7916 0.16157E-02 -2.7916 0.10000E+01 0.0000 20 AlO+ 0.12504E-15 -15.9030 0.10585E-15 -15.9753 0.84652E+00 -0.0724 22 HAlO2,aq 0.24808E-09 -9.6054 0.24808E-09 -9.6054 0.10000E+01 0.0000 23 AlO2- 0.76595E-05 -5.1158 0.64630E-05 -5.1896 0.84379E+00 -0.0738 24 CH4,aq 0.64180E-07 -7.1926 0.63997E-07 -7.1938 0.99715E+00 -0.0012 25 C2H6,aq 0.50182E-18 -18.2995 0.50039E-18 -18.3007 0.99715E+00 -0.0012 29 CO,aq 0.27214E-16 -16.5652 0.27214E-16 -16.5652 0.10000E+01 0.0000 30 CO2,aq 0.77644E-09 -9.1099 0.77422E-09 -9.1111 0.99715E+00 -0.0012 31 CO3-2 0.80778E-05 -5.0927 0.43837E-05 -5.3582 0.54269E+00 -0.2655 32 CaCO3,aq 0.29201E-08 -8.5346 0.29201E-08 -8.5346 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.68311E-11 -11.1655 0.57827E-11 -11.2379 0.84652E+00 -0.0724 34 CaCl+ 0.11900E-10 -10.9245 0.10073E-10 -10.9968 0.84652E+00 -0.0724 35 CaCl2,aq 0.28042E-15 -15.5522 0.28042E-15 -15.5522 0.10000E+01 0.0000 36 CaOH+ 0.52638E-07 -7.2787 0.44559E-07 -7.3511 0.84652E+00 -0.0724 37 CaSO4,aq 0.23738E-13 -13.6246 0.23738E-13 -13.6246 0.10000E+01 0.0000 38 HCl,aq 0.18244E-14 -14.7389 0.18244E-14 -14.7389 0.10000E+01 0.0000 43 FeCl+ 0.80607E-17 -17.0936 0.68235E-17 -17.1660 0.84652E+00 -0.0724 46 FeO,aq 0.19806E-09 -9.7032 0.19806E-09 -9.7032 0.10000E+01 0.0000 47 FeOH+ 0.16650E-10 -10.7786 0.14095E-10 -10.8509 0.84652E+00 -0.0724 48 HFeO2- 0.28860E-07 -7.5397 0.24390E-07 -7.6128 0.84511E+00 -0.0731 49 FeO+ 0.33574E-16 -16.4740 0.28421E-16 -16.5464 0.84652E+00 -0.0724 51 FeO2- 0.95314E-09 -9.0208 0.80551E-09 -9.0939 0.84511E+00 -0.0731 52 HFeO2,aq 0.87048E-11 -11.0602 0.87048E-11 -11.0602 0.10000E+01 0.0000 53 H2,aq 0.14033E-05 -5.8529 0.13993E-05 -5.8541 0.99715E+00 -0.0012 54 KCl,aq 0.23471E-09 -9.6295 0.23471E-09 -9.6295 0.10000E+01 0.0000 56 KOH,aq 0.55548E-06 -6.2553 0.55548E-06 -6.2553 0.10000E+01 0.0000 57 KSO4- 0.28555E-11 -11.5443 0.24133E-11 -11.6174 0.84511E+00 -0.0731 58 MgCO3,aq 0.16175E-12 -12.7912 0.16175E-12 -12.7912 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.15425E-14 -14.8118 0.13058E-14 -14.8841 0.84652E+00 -0.0724 60 MgCl+ 0.23834E-14 -14.6228 0.20176E-14 -14.6952 0.84652E+00 -0.0724 61 MgOH+ 0.64368E-10 -10.1913 0.54488E-10 -10.2637 0.84652E+00 -0.0724 63 MnO,aq 0.13352E-08 -8.8745 0.13352E-08 -8.8745 0.10000E+01 0.0000 64 MnOH+ 0.39132E-09 -9.4075 0.33125E-09 -9.4798 0.84652E+00 -0.0724 65 MnO2-2 0.11310E-10 -10.9466 0.61375E-11 -11.2120 0.54269E+00 -0.2655 66 HMnO2- 0.13519E-09 -9.8691 0.11425E-09 -9.9421 0.84511E+00 -0.0731 69 MnCl+ 0.79337E-14 -14.1005 0.67160E-14 -14.1729 0.84652E+00 -0.0724 70 MnSO4,aq 0.37812E-17 -17.4224 0.37812E-17 -17.4224 0.10000E+01 0.0000 71 NaCl,aq 0.54356E-06 -6.2648 0.54356E-06 -6.2648 0.10000E+01 0.0000 72 NaOH,aq 0.70782E-04 -4.1501 0.70782E-04 -4.1501 0.10000E+01 0.0000 74 OH- 0.80588E-02 -2.0937 0.67999E-02 -2.1675 0.84379E+00 -0.0738 79 HPO3-2 0.35538E-15 -15.4493 0.19286E-15 -15.7148 0.54269E+00 -0.2655 81 H2PO3- 0.38883E-19 -19.4102 0.32860E-19 -19.4833 0.84511E+00 -0.0731 82 H3PO4,aq 0.22332E-17 -17.6511 0.22332E-17 -17.6511 0.10000E+01 0.0000 83 H2PO4- 0.81962E-10 -10.0864 0.69324E-10 -10.1591 0.84581E+00 -0.0727 84 PO4-3 0.15862E-08 -8.7997 0.42469E-09 -9.3719 0.26775E+00 -0.5723 88 HP2O7-3 0.34481E-17 -17.4624 0.88554E-18 -18.0528 0.25682E+00 -0.5904 89 P2O7-4 0.26898E-16 -16.5703 0.24898E-17 -17.6038 0.92565E-01 -1.0336 90 H2S,aq 0.57253E-08 -8.2422 0.57090E-08 -8.2434 0.99715E+00 -0.0012 91 S2-2 0.13791E-13 -13.8604 0.74842E-14 -14.1259 0.54269E+00 -0.2655 97 SO3-2 0.46565E-15 -15.3319 0.25587E-15 -15.5920 0.54948E+00 -0.2600 98 HSO3- 0.16107E-17 -17.7930 0.13612E-17 -17.8661 0.84511E+00 -0.0731 99 HSO4- 0.13600E-15 -15.8665 0.11522E-15 -15.9385 0.84723E+00 -0.0720 101 S2O3-2 0.17389E-18 -18.7597 0.94367E-19 -19.0252 0.54269E+00 -0.2655 Charge balance for all species = -.1545E-12 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.1000165E-09 -.1822976E-01 -.1834870E+02 0.0000 2 H2O 0.1000000E+01 0.5550634E+02 0.9985595E+06 0.0000 3 Cl- 0.1386467E-03 0.1391905E-03 0.4927793E+01 6.1396 4 SO4-- 0.2588156E-08 -.4122841E-06 -.3954907E-01 11.2898 5 HCO3- 0.5039536E-05 0.1318522E-04 0.8033958E+00 4.7006 6 HS- 0.2572099E-04 0.2614159E-04 0.8633410E+00 5.4080 7 Al+++ 0.2188943E-28 0.7659728E-05 0.2063808E+00 0.9617 8 H4SiO4 0.6494217E-03 0.1070986E-01 0.1027937E+04 -3.1875 9 Ca++ 0.9833422E-07 0.1641112E-06 0.6568014E-02 12.8668 10 Mg++ 0.2181697E-10 0.8915564E-10 0.2164509E-05 9.2111 11 Fe++ 0.6830828E-13 0.3003634E-07 0.1675085E-02 6.7072 12 K+ 0.1305825E-03 0.1311382E-03 0.5120568E+01 6.1142 13 Na+ 0.1656603E-01 0.1825311E-01 0.4190461E+03 8.2168 14 Mn++ 0.1726902E-10 0.1890256E-08 0.1037011E-03 9.1103 15 HPO4-- 0.8133772E-07 0.8300584E-07 0.7955633E-02 12.7872 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.1225301E+01 -.1807045E-01 -.1207230E+01 0.0000000E+00 2 H2O 0.5458064E+02 0.5502129E+02 -.4406460E+00 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.2076269E-02 -.4086813E-06 0.2076678E-02 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.2050765E-02 0.2591315E-04 -.2076678E-02 0.0000000E+00 7 Al+++ 0.2412916E+00 0.7592792E-05 0.2412840E+00 0.0000000E+00 8 H4SiO4 0.7705355E+00 0.1061627E-01 0.7599193E+00 0.0000000E+00 9 Ca++ 0.8512388E-01 0.1626771E-06 0.8512371E-01 0.0000000E+00 10 Mg++ 0.5872937E-01 0.8837654E-10 0.5872936E-01 0.0000000E+00 11 Fe++ 0.5276192E-01 0.2977386E-07 0.5276189E-01 0.0000000E+00 12 K+ 0.1571104E-01 0.1299923E-03 0.1558105E-01 0.0000000E+00 13 Na+ 0.9304684E-01 0.1809360E-01 0.7495325E-01 0.0000000E+00 14 Mn++ 0.1283039E-02 0.1873737E-08 0.1283037E-02 0.0000000E+00 15 HPO4-- 0.4378948E-03 0.8228049E-07 0.4378125E-03 0.0000000E+00 Chg. balance for solid moles: -.2913E-15 Mass of aqueous solution: 0.992655E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 73.9990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 0.7495E-01 -1.125 19.65 1.293 24.34 7.545 andradite 0.8307E-02 -2.081 4.221 0.625 5.227 1.097 grossular 0.1245E-02 -2.905 0.5607 -0.251 0.6943 0.1560 apatite-OH 0.1459E-03 -3.836 0.7331E-01 -1.135 0.9078E-01 0.2329E-01 clinochlore 0.1175E-01 -1.930 6.529 0.815 8.085 2.483 daphnite 0.3862E-02 -2.413 2.756 0.440 3.412 0.8351 chlorite-Mn 0.2566E-03 -3.591 0.1819 -0.740 0.2253 0.5798E-01 microcline 0.1390E-01 -1.857 3.868 0.588 4.790 1.511 stilbite 0.5574E-01 -1.254 39.28 1.594 48.64 18.32 stilpnomelane-Fe 0.3368E-02 -2.473 3.630 0.560 4.495 1.254 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8697E+00 0.8697E+00 1.0000 -0.061 grossular 0.1303E+00 0.1303E+00 1.0000 -0.885 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.7404E+00 0.7404E+00 1.0000 -0.131 daphnite 0.2434E+00 0.2434E+00 1.0000 -0.614 chlorite-Mn 0.1617E-01 0.1617E-01 1.0000 -1.791 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 80.755192 g Volume = 33.283530 cm3 Porosity: -8.7711% V(tot) - V(min): -.26839E+01 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 73.9990000 g log = 1.8692 Original solution: 1000.0103000 g Original solution / Rock added: 13.51 (Water/Rock Ratio), log = 1.1308 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0223 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9981E+00 0.9859 0.1006E+01 0.1020E+01 CO2,gas 0.8046E-07 1.0071 0.8283E-07 0.8225E-07 CH4,gas 0.9101E-04 1.0125 0.9420E-04 0.9303E-04 H2,gas 0.1796E-02 1.0005 0.1837E-02 0.1836E-02 H2S,gas 0.1541E-06 0.9960 0.1569E-06 0.1576E-06 S2,gas 0.2680E-27 1.0000 0.2739E-27 0.2739E-27 CO,gas 0.3967E-13 1.0000 0.4055E-13 0.4055E-13 SO3,gas 0.3758E-44 1.0000 0.3841E-44 0.3841E-44 SO2,gas 0.2686E-24 1.0000 0.2745E-24 0.2745E-24 HCl,gas 0.3149E-17 1.0000 0.3219E-17 0.3219E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 16 albite -0.38 -0.38 0.00 0.000 -0.13080E-10 22 andradite 39.01 39.01 0.00 0.000 0.00000E+00 23 grossular 32.73 32.73 0.00 0.000 -0.24265E-10 32 apatite-OH -18.15 -18.15 0.00 0.000 0.60662E-11 46 clinochlore 39.07 39.07 0.00 0.000 0.12132E-10 47 daphnite 28.97 28.97 0.00 0.000 0.18198E-10 48 chlorite-Mn 46.87 46.87 0.00 0.000 0.24265E-10 116 microcline -2.49 -2.49 0.00 0.000 -0.10616E-10 163 stilbite -7.52 -7.52 0.00 0.000 -0.90992E-11 164 stilpnomelane-Fe 13.02 13.02 0.00 0.000 0.21232E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -15.44 -8.78 -2.927 0.14993E+05 -7.082 3 CH4,gas 4.54 -1.18 -5.72 -1.431 0.97751E+04 -4.026 4 H2,gas 8.00 3.56 -4.43 -2.534 0.75724E+04 -2.736 5 H2S,gas -6.23 -14.73 -8.50 -4.252 0.14519E+05 -6.804 6 S2,gas -7.34 -36.60 -29.26 -4.502 0.49963E+05 -27.562 7 CO,gas 3.21 -11.88 -15.09 -4.643 0.25767E+05 -13.392 8 SO3,gas 17.12 -28.99 -46.11 -11.529 0.78739E+05 -44.416 9 SO2,gas 0.83 -25.43 -26.26 -7.003 0.44839E+05 -24.561 10 HCl,gas 5.19 -14.00 -19.19 -9.596 0.32769E+05 -17.492 11 acmite 7.71 6.77 -0.94 -0.098 0.16103E+04 15 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 19 spessartine 24.46 19.69 -4.77 -0.238 0.81365E+04 20 analcite 3.32 2.80 -0.52 -0.058 0.88491E+03 26 annite 20.12 17.64 -2.49 -0.138 0.42485E+04 27 phlogopite 27.06 25.15 -1.92 -0.107 0.32743E+04 29 anorthite 12.71 8.42 -4.30 -0.330 0.73336E+04 35 aragonite 0.97 -2.57 -3.54 -1.180 0.60455E+04 36 brucite 12.57 9.21 -3.36 -0.671 0.57327E+04 37 calcite 0.81 -2.57 -3.39 -1.129 0.57813E+04 38 carnegieite-low 9.02 5.99 -3.03 -0.433 0.51774E+04 39 carnegieite-high 10.09 5.99 -4.10 -0.586 0.70044E+04 40 carpholite-Mg 8.58 4.76 -3.82 -0.255 0.65267E+04 41 carpholite-Fe 6.71 2.26 -4.46 -0.297 0.76100E+04 42 celadonite 5.34 3.54 -1.80 -0.106 0.30810E+04 43 celadonite-Fe 3.88 1.03 -2.84 -0.167 0.48548E+04 44 chrysotile 23.89 21.26 -2.63 -0.219 0.44973E+04 49 chlorite-Al-free 47.17 42.52 -4.66 -0.194 0.79498E+04 51 chloritoid-Fe 9.17 5.44 -3.73 -0.249 0.63695E+04 52 chloritoid-Mn 11.40 7.85 -3.55 -0.237 0.60696E+04 54 coesite -2.38 -3.19 -0.81 -0.270 0.13855E+04 61 cristobalite -2.56 -3.19 -0.63 -0.209 0.10708E+04 63 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71234E+04 65 diaspore 2.87 0.96 -1.91 -0.319 0.32646E+04 67 diopside 16.18 15.70 -0.48 -0.048 0.81682E+03 68 hedenbergite 14.21 13.20 -1.01 -0.101 0.17232E+04 75 epidote 24.67 23.02 -1.65 -0.080 0.28182E+04 76 clinozoisite 22.81 19.06 -3.75 -0.170 0.64025E+04 77 epidote-Fe 29.84 26.98 -2.86 -0.148 0.48806E+04 78 fayalite 14.05 10.23 -3.82 -0.546 0.65204E+04 79 ferrosilite 11.15 7.04 -4.11 -0.411 0.70176E+04 83 gibbsite 4.08 0.96 -3.12 -0.445 0.53232E+04 84 glaucophane 22.97 20.49 -2.48 -0.067 0.42414E+04 85 glaucophane-Fe 17.28 12.98 -4.30 -0.116 0.73367E+04 86 graphite -3.55 -8.31 -4.76 -1.361 0.81359E+04 87 greenalite 16.14 13.75 -2.39 -0.199 0.40855E+04 90 hematite 12.57 9.85 -2.72 -0.329 0.46386E+04 91 heulandite -5.83 -7.52 -1.69 -0.077 0.28938E+04 95 jadeite 4.22 2.80 -1.41 -0.141 0.24104E+04 96 julgoldite 70.43 65.46 -4.97 -0.129 0.84879E+04 97 kalsilite 7.58 3.89 -3.70 -0.528 0.63099E+04 98 kaolinite -1.33 -4.45 -3.12 -0.284 0.53251E+04 101 laumontite 2.88 2.04 -0.84 -0.056 0.14395E+04 102 lawsonite 9.62 8.42 -1.20 -0.080 0.20503E+04 103 leucite 4.12 0.70 -3.42 -0.342 0.58359E+04 105 lizardite 23.24 21.26 -1.99 -0.165 0.33899E+04 107 magnetite 20.09 16.56 -3.53 -0.288 0.60284E+04 108 minnesotaite 10.39 7.37 -3.02 -0.177 0.51502E+04 112 manganosite 14.06 9.11 -4.95 -1.237 0.84482E+04 120 muscovite 2.58 -0.56 -3.15 -0.185 0.53708E+04 121 paragonite 4.24 1.54 -2.70 -0.159 0.46099E+04 122 nepheline 8.34 5.99 -2.35 -0.335 0.40098E+04 128 periclase-Fe 11.63 6.71 -4.92 -1.230 0.83997E+04 134 phlogopite-Na 29.65 27.25 -2.40 -0.133 0.40931E+04 136 prehnite 19.37 18.09 -1.28 -0.075 0.21809E+04 137 prehnite-Fe 22.50 22.06 -0.44 -0.026 0.75164E+03 138 pumpellyite-Fe 46.27 43.86 -2.41 -0.054 0.41171E+04 139 pumpellyite-Mg 48.99 46.36 -2.63 -0.059 0.44953E+04 143 pyrrhotite -4.26 -8.03 -3.77 -1.255 0.64302E+04 144 pyrrhotiteFe0.875 -6.02 -9.31 -3.29 -1.210 0.56172E+04 145 pyroxmangite 7.40 5.92 -1.48 -0.295 0.25199E+04 146 pyrophyllite -6.18 -10.83 -4.65 -0.291 0.79408E+04 147 quartz -2.99 -3.19 -0.20 -0.066 0.33814E+03 152 rhodonite 7.45 5.92 -1.52 -0.305 0.26002E+04 153 sanidine -1.28 -2.49 -1.21 -0.093 0.20677E+04 165 stilpnomelane-Mg 27.44 25.54 -1.90 -0.057 0.32525E+04 171 talc 16.49 14.88 -1.61 -0.095 0.27448E+04 174 tephroite 18.09 15.03 -3.05 -0.436 0.52122E+04 178 tridymite -2.63 -3.19 -0.56 -0.187 0.95812E+03 179 tremolite 47.87 46.29 -1.58 -0.043 0.26974E+04 180 ferroactinolite 38.45 33.77 -4.68 -0.127 0.79951E+04 181 troilite-low -4.41 -8.03 -3.62 -1.205 0.61730E+04 187 wairakite 3.95 2.04 -1.91 -0.112 0.32614E+04 188 walstromite 11.51 9.68 -1.83 -0.366 0.31245E+04 189 wollastonite 10.46 9.68 -0.78 -0.156 0.13350E+04 190 pseudo-wollastonite 11.00 9.68 -1.32 -0.264 0.22548E+04 191 zoisite 22.85 19.06 -3.79 -0.172 0.64765E+04 192 akaganeite 7.75 4.92 -2.83 -0.612 0.48318E+04 199 chalcedony -2.80 -3.19 -0.39 -0.128 0.65744E+03 201 montmorillonite-Ca -2.29 -5.98 -3.69 -0.228 0.63012E+04 202 montmorillonite-K -2.24 -6.09 -3.85 -0.236 0.65733E+04 203 montmorillonite-Mg -2.48 -6.58 -4.10 -0.254 0.70081E+04 204 montmorillonite-Na -2.04 -5.39 -3.35 -0.205 0.57282E+04 205 nontronite-Ca 3.21 0.59 -2.62 -0.170 0.44780E+04 206 nontronite-H 2.53 -1.53 -4.06 -0.272 0.69388E+04 207 nontronite-K 3.34 0.49 -2.85 -0.183 0.48733E+04 208 nontronite-Mg 3.07 -0.01 -3.09 -0.200 0.52690E+04 209 nontronite-Na 3.52 1.18 -2.34 -0.150 0.39942E+04 224 tobermorite 9.82 7.53 -2.29 -0.626 0.39144E+04 230 alabandite -0.98 -5.62 -4.65 -1.548 0.79317E+04 233 boehmite 4.41 0.96 -3.44 -0.574 0.58815E+04 235 ferrous-oxide 9.81 6.71 -3.10 -0.776 0.53006E+04 240 silica-amorphous -2.09 -3.19 -1.10 -0.365 0.18716E+04 242 an20ab80 2.02 1.38 -0.64 -0.049 0.10959E+04 243 an25ab75 2.65 1.82 -0.83 -0.064 0.14168E+04 244 an30ab70 3.28 2.26 -1.02 -0.079 0.17474E+04 245 tr.625ac.25prg.125 45.16 44.19 -0.97 -0.026 0.16595E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 2.0000000 g Current total amount of reactant added: 73.9990000 g New total amount of reactant added: 75.9990000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.1492E-12 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 9 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 75.9990000 Water: Moles liquid = 0.5501E+02 kg liquid = 0.9910E+00 Moles total = 0.5456E+02 kg total = 0.9828E+00 Activity = 1.0000 Stoichiometric ionic strength = .9477443E-02 Osmotic coef. = 0.9643 True ionic strength = .1697319E-01 Chg. balance for total moles = -.1492E-12 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.99037E-10 -10.0042 0.84057E-10 -10.0754 0.84874E+00 -0.0712 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13867E-03 -3.8580 0.11707E-03 -3.9315 0.84426E+00 -0.0735 4 SO4-- 0.13255E-08 -8.8776 0.71785E-09 -9.1440 0.54156E+00 -0.2664 5 HCO3- 0.49753E-05 -5.3032 0.42058E-05 -5.3761 0.84534E+00 -0.0730 6 HS- 0.25728E-04 -4.5896 0.21724E-04 -4.6631 0.84437E+00 -0.0735 7 Al+++ 0.20320E-28 -28.6921 0.51677E-29 -29.2867 0.25431E+00 -0.5946 8 H4SiO4 0.65493E-03 -3.1838 0.65493E-03 -3.1838 0.10000E+01 0.0000 9 Ca++ 0.10086E-06 -6.9963 0.54272E-07 -7.2654 0.53808E+00 -0.2692 10 Mg++ 0.21847E-10 -10.6606 0.11708E-10 -10.9315 0.53592E+00 -0.2709 11 Fe++ 0.67414E-13 -13.1713 0.36163E-13 -13.4417 0.53643E+00 -0.2705 12 K+ 0.13268E-03 -3.8772 0.11218E-03 -3.9501 0.84552E+00 -0.0729 13 Na+ 0.16832E-01 -1.7739 0.14208E-01 -1.8475 0.84413E+00 -0.0736 14 Mn++ 0.17292E-10 -10.7622 0.92828E-11 -11.0323 0.53682E+00 -0.2702 15 HPO4-- 0.77673E-07 -7.1097 0.42070E-07 -7.3760 0.54162E+00 -0.2663 16 HSiO3- 0.86173E-02 -2.0646 0.72752E-02 -2.1382 0.84426E+00 -0.0735 17 Ca(HSiO3)+ 0.10633E-07 -7.9733 0.89921E-08 -8.0461 0.84568E+00 -0.0728 18 Mg(HSiO3)+ 0.28547E-11 -11.5444 0.24141E-11 -11.6172 0.84568E+00 -0.0728 19 NaHSiO3,aq 0.16719E-02 -2.7768 0.16719E-02 -2.7768 0.10000E+01 0.0000 20 AlO+ 0.11766E-15 -15.9294 0.99502E-16 -16.0022 0.84568E+00 -0.0728 22 HAlO2,aq 0.23574E-09 -9.6276 0.23574E-09 -9.6276 0.10000E+01 0.0000 23 AlO2- 0.73650E-05 -5.1328 0.62081E-05 -5.2070 0.84292E+00 -0.0742 24 CH4,aq 0.12399E-06 -6.9066 0.12364E-06 -6.9079 0.99710E+00 -0.0013 25 C2H6,aq 0.15789E-17 -17.8016 0.15744E-17 -17.8029 0.99710E+00 -0.0013 29 CO,aq 0.31498E-16 -16.5017 0.31498E-16 -16.5017 0.10000E+01 0.0000 30 CO2,aq 0.75760E-09 -9.1206 0.75540E-09 -9.1218 0.99710E+00 -0.0013 31 CO3-2 0.80852E-05 -5.0923 0.43704E-05 -5.3595 0.54055E+00 -0.2672 32 CaCO3,aq 0.29741E-08 -8.5266 0.29741E-08 -8.5266 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.68898E-11 -11.1618 0.58266E-11 -11.2346 0.84568E+00 -0.0728 34 CaCl+ 0.12159E-10 -10.9151 0.10283E-10 -10.9879 0.84568E+00 -0.0728 35 CaCl2,aq 0.28600E-15 -15.5436 0.28600E-15 -15.5436 0.10000E+01 0.0000 36 CaOH+ 0.54413E-07 -7.2643 0.46016E-07 -7.3371 0.84568E+00 -0.0728 37 CaSO4,aq 0.12371E-13 -13.9076 0.12371E-13 -13.9076 0.10000E+01 0.0000 38 HCl,aq 0.18033E-14 -14.7439 0.18033E-14 -14.7439 0.10000E+01 0.0000 43 FeCl+ 0.79241E-17 -17.1010 0.67013E-17 -17.1738 0.84568E+00 -0.0728 46 FeO,aq 0.19892E-09 -9.7013 0.19892E-09 -9.7013 0.10000E+01 0.0000 47 FeOH+ 0.16560E-10 -10.7810 0.14004E-10 -10.8537 0.84568E+00 -0.0728 48 HFeO2- 0.29329E-07 -7.5327 0.24761E-07 -7.6062 0.84426E+00 -0.0735 49 FeO+ 0.30658E-16 -16.5135 0.25927E-16 -16.5863 0.84568E+00 -0.0728 51 FeO2- 0.88936E-09 -9.0509 0.75085E-09 -9.1244 0.84426E+00 -0.0735 52 HFeO2,aq 0.80271E-11 -11.0954 0.80271E-11 -11.0954 0.10000E+01 0.0000 53 H2,aq 0.16647E-05 -5.7787 0.16598E-05 -5.7799 0.99710E+00 -0.0013 54 KCl,aq 0.23803E-09 -9.6234 0.23803E-09 -9.6234 0.10000E+01 0.0000 56 KOH,aq 0.56994E-06 -6.2442 0.56994E-06 -6.2442 0.10000E+01 0.0000 57 KSO4- 0.14801E-11 -11.8297 0.12496E-11 -11.9032 0.84426E+00 -0.0735 58 MgCO3,aq 0.16082E-12 -12.7937 0.16082E-12 -12.7937 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.15187E-14 -14.8185 0.12844E-14 -14.8913 0.84568E+00 -0.0728 60 MgCl+ 0.23773E-14 -14.6239 0.20105E-14 -14.6967 0.84568E+00 -0.0728 61 MgOH+ 0.64954E-10 -10.1874 0.54930E-10 -10.2602 0.84568E+00 -0.0728 63 MnO,aq 0.13606E-08 -8.8663 0.13606E-08 -8.8663 0.10000E+01 0.0000 64 MnOH+ 0.39488E-09 -9.4035 0.33394E-09 -9.4763 0.84568E+00 -0.0728 65 MnO2-2 0.11823E-10 -10.9273 0.63907E-11 -11.1944 0.54055E+00 -0.2672 66 HMnO2- 0.13940E-09 -9.8557 0.11769E-09 -9.9293 0.84426E+00 -0.0735 69 MnCl+ 0.79134E-14 -14.1016 0.66922E-14 -14.1744 0.84568E+00 -0.0728 70 MnSO4,aq 0.19237E-17 -17.7159 0.19237E-17 -17.7159 0.10000E+01 0.0000 71 NaCl,aq 0.55126E-06 -6.2586 0.55126E-06 -6.2586 0.10000E+01 0.0000 72 NaOH,aq 0.72625E-04 -4.1389 0.72625E-04 -4.1389 0.10000E+01 0.0000 74 OH- 0.81545E-02 -2.0886 0.68736E-02 -2.1628 0.84292E+00 -0.0742 79 HPO3-2 0.40258E-15 -15.3952 0.21761E-15 -15.6623 0.54055E+00 -0.2672 81 H2PO3- 0.43447E-19 -19.3620 0.36680E-19 -19.4356 0.84426E+00 -0.0735 82 H3PO4,aq 0.20789E-17 -17.6822 0.20789E-17 -17.6822 0.10000E+01 0.0000 83 H2PO4- 0.77204E-10 -10.1124 0.65234E-10 -10.1855 0.84496E+00 -0.0732 84 PO4-3 0.15381E-08 -8.8130 0.40835E-09 -9.3890 0.26550E+00 -0.5759 88 HP2O7-3 0.31142E-17 -17.5067 0.79264E-18 -18.1009 0.25452E+00 -0.5943 89 P2O7-4 0.24721E-16 -16.6069 0.22528E-17 -17.6473 0.91128E-01 -1.0403 90 H2S,aq 0.56600E-08 -8.2472 0.56436E-08 -8.2484 0.99710E+00 -0.0013 91 S2-2 0.11655E-13 -13.9335 0.63001E-14 -14.2007 0.54055E+00 -0.2672 97 SO3-2 0.28286E-15 -15.5484 0.15484E-15 -15.8101 0.54740E+00 -0.2617 98 HSO3- 0.96524E-18 -18.0154 0.81491E-18 -18.0889 0.84426E+00 -0.0735 99 HSO4- 0.68704E-16 -16.1630 0.58151E-16 -16.2354 0.84640E+00 -0.0724 101 S2O3-2 0.88040E-19 -19.0553 0.47590E-19 -19.3225 0.54055E+00 -0.2672 Charge balance for all species = -.1565E-12 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.9903718E-10 -.1855498E-01 -.1867554E+02 0.0000 2 H2O 0.1000000E+01 0.5550621E+02 0.9985299E+06 0.0000 3 Cl- 0.1386703E-03 0.1392218E-03 0.4928767E+01 6.1439 4 SO4-- 0.1325542E-08 -.5387217E-06 -.5167641E-01 11.0069 5 HCO3- 0.4975292E-05 0.1318819E-04 0.8035545E+00 4.6993 6 HS- 0.2572811E-04 0.2627382E-04 0.8676841E+00 5.4124 7 Al+++ 0.2032036E-28 0.7365248E-05 0.1984410E+00 0.9396 8 H4SiO4 0.6549260E-03 0.1094407E-01 0.1050388E+04 -3.1838 9 Ca++ 0.1008637E-06 0.1689029E-06 0.6759604E-02 12.8854 10 Mg++ 0.2184657E-10 0.8982000E-10 0.2180579E-05 9.2193 11 Fe++ 0.6741368E-13 0.3044181E-07 0.1697651E-02 6.7091 12 K+ 0.1326760E-03 0.1332462E-03 0.5202735E+01 6.1253 13 Na+ 0.1683198E-01 0.1857700E-01 0.4264704E+03 8.2280 14 Mn++ 0.1729208E-10 0.1923983E-08 0.1055485E-03 9.1185 15 HPO4-- 0.7767349E-07 0.7928875E-07 0.7599164E-02 12.7748 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.1258418E+01 -.1838870E-01 -.1240029E+01 0.0000000E+00 2 H2O 0.5455557E+02 0.5500879E+02 -.4532162E+00 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.2131696E-02 -.5338939E-06 0.2132230E-02 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.2106191E-02 0.2603836E-04 -.2132230E-02 0.0000000E+00 7 Al+++ 0.2478131E+00 0.7299245E-05 0.2478058E+00 0.0000000E+00 8 H4SiO4 0.7913611E+00 0.1084600E-01 0.7805151E+00 0.0000000E+00 9 Ca++ 0.8742416E-01 0.1673893E-06 0.8742400E-01 0.0000000E+00 10 Mg++ 0.6031667E-01 0.8901508E-10 0.6031667E-01 0.0000000E+00 11 Fe++ 0.5418794E-01 0.3016901E-07 0.5418791E-01 0.0000000E+00 12 K+ 0.1613567E-01 0.1320521E-03 0.1600362E-01 0.0000000E+00 13 Na+ 0.9555733E-01 0.1841053E-01 0.7714681E-01 0.0000000E+00 14 Mn++ 0.1317716E-02 0.1906741E-08 0.1317714E-02 0.0000000E+00 15 HPO4-- 0.4497299E-03 0.7857821E-07 0.4496513E-03 0.0000000E+00 Chg. balance for solid moles: 0.6158E-16 Mass of aqueous solution: 0.992459E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 75.9990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 0.7715E-01 -1.113 20.23 1.306 24.39 7.766 andradite 0.8529E-02 -2.069 4.334 0.637 5.226 1.126 grossular 0.1317E-02 -2.880 0.5932 -0.227 0.7153 0.1651 apatite-OH 0.1499E-03 -3.824 0.7529E-01 -1.123 0.9078E-01 0.2392E-01 clinochlore 0.1206E-01 -1.919 6.705 0.826 8.085 2.550 daphnite 0.3909E-02 -2.408 2.789 0.446 3.363 0.8453 chlorite-Mn 0.2635E-03 -3.579 0.1868 -0.729 0.2253 0.5954E-01 microcline 0.1425E-01 -1.846 3.965 0.598 4.781 1.549 stilbite 0.5714E-01 -1.243 40.27 1.605 48.55 18.78 stilpnomelane-Fe 0.3517E-02 -2.454 3.791 0.579 4.571 1.309 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8662E+00 0.8662E+00 1.0000 -0.062 grossular 0.1338E+00 0.1338E+00 1.0000 -0.874 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.7430E+00 0.7430E+00 1.0000 -0.129 daphnite 0.2408E+00 0.2408E+00 1.0000 -0.618 chlorite-Mn 0.1623E-01 0.1623E-01 1.0000 -1.790 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 82.935094 g Volume = 34.174844 cm3 Porosity: -8.8385% V(tot) - V(min): -.27752E+01 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 75.9990000 g log = 1.8808 Original solution: 1000.0103000 g Original solution / Rock added: 13.16 (Water/Rock Ratio), log = 1.1192 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0227 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9977E+00 0.9859 0.1006E+01 0.1020E+01 CO2,gas 0.7847E-07 1.0071 0.8082E-07 0.8025E-07 CH4,gas 0.1757E-03 1.0126 0.1820E-03 0.1797E-03 H2,gas 0.2130E-02 1.0005 0.2179E-02 0.2178E-02 H2S,gas 0.1523E-06 0.9960 0.1551E-06 0.1558E-06 S2,gas 0.1860E-27 1.0000 0.1902E-27 0.1902E-27 CO,gas 0.4590E-13 1.0000 0.4694E-13 0.4694E-13 SO3,gas 0.1875E-44 1.0000 0.1918E-44 0.1918E-44 SO2,gas 0.1590E-24 1.0000 0.1626E-24 0.1626E-24 HCl,gas 0.3111E-17 1.0000 0.3182E-17 0.3182E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 16 albite -0.38 -0.38 0.00 0.000 -0.94784E-12 22 andradite 39.01 39.01 0.00 0.000 0.12132E-10 23 grossular 32.73 32.73 0.00 0.000 -0.12132E-10 32 apatite-OH -18.15 -18.15 0.00 0.000 0.18198E-10 46 clinochlore 39.07 39.07 0.00 0.000 0.12132E-10 47 daphnite 28.97 28.97 0.00 0.000 -0.24265E-10 48 chlorite-Mn 46.87 46.87 0.00 0.000 0.24265E-10 116 microcline -2.49 -2.49 0.00 0.000 0.15165E-11 163 stilbite -7.52 -7.52 0.00 0.000 0.15165E-10 164 stilpnomelane-Fe 13.02 13.02 0.00 0.000 -0.27298E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -15.45 -8.79 -2.930 0.15011E+05 -7.092 3 CH4,gas 4.54 -0.90 -5.44 -1.360 0.92868E+04 -3.740 4 H2,gas 8.00 3.64 -4.36 -2.492 0.74457E+04 -2.662 5 H2S,gas -6.23 -14.74 -8.51 -4.254 0.14528E+05 -6.809 6 S2,gas -7.34 -36.76 -29.42 -4.526 0.50233E+05 -27.721 7 CO,gas 3.21 -11.81 -15.03 -4.624 0.25659E+05 -13.328 8 SO3,gas 17.12 -29.29 -46.42 -11.604 0.79254E+05 -44.717 9 SO2,gas 0.83 -25.66 -26.49 -7.063 0.45227E+05 -24.789 10 HCl,gas 5.19 -14.01 -19.20 -9.598 0.32777E+05 -17.497 11 acmite 7.71 6.75 -0.96 -0.100 0.16388E+04 15 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 19 spessartine 24.46 19.68 -4.77 -0.239 0.81515E+04 20 analcite 3.32 2.80 -0.52 -0.058 0.89116E+03 26 annite 20.12 17.64 -2.48 -0.138 0.42389E+04 27 phlogopite 27.06 25.17 -1.89 -0.105 0.32324E+04 29 anorthite 12.71 8.40 -4.31 -0.332 0.73649E+04 35 aragonite 0.97 -2.57 -3.53 -1.178 0.60319E+04 36 brucite 12.57 9.22 -3.35 -0.670 0.57187E+04 37 calcite 0.81 -2.57 -3.38 -1.126 0.57677E+04 38 carnegieite-low 9.02 5.98 -3.04 -0.434 0.51899E+04 39 carnegieite-high 10.09 5.98 -4.11 -0.587 0.70169E+04 40 carpholite-Mg 8.58 4.73 -3.85 -0.257 0.65758E+04 41 carpholite-Fe 6.71 2.22 -4.49 -0.299 0.76699E+04 42 celadonite 5.34 3.55 -1.79 -0.105 0.30608E+04 43 celadonite-Fe 3.88 1.04 -2.84 -0.167 0.48453E+04 44 chrysotile 23.89 21.29 -2.60 -0.217 0.44428E+04 49 chlorite-Al-free 47.17 42.58 -4.59 -0.191 0.78408E+04 51 chloritoid-Fe 9.17 5.40 -3.77 -0.251 0.64357E+04 52 chloritoid-Mn 11.40 7.81 -3.59 -0.239 0.61250E+04 54 coesite -2.38 -3.18 -0.81 -0.269 0.13792E+04 61 cristobalite -2.56 -3.18 -0.62 -0.208 0.10646E+04 63 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71234E+04 65 diaspore 2.87 0.94 -1.93 -0.322 0.33024E+04 67 diopside 16.18 15.74 -0.44 -0.044 0.75846E+03 68 hedenbergite 14.21 13.23 -0.98 -0.098 0.16756E+04 75 epidote 24.67 22.99 -1.68 -0.082 0.28715E+04 76 clinozoisite 22.81 19.04 -3.77 -0.171 0.64335E+04 77 epidote-Fe 29.84 26.94 -2.90 -0.151 0.49561E+04 78 fayalite 14.05 10.23 -3.81 -0.544 0.65077E+04 79 ferrosilite 11.15 7.05 -4.10 -0.410 0.69986E+04 83 gibbsite 4.08 0.94 -3.14 -0.449 0.53610E+04 84 glaucophane 22.97 20.52 -2.45 -0.066 0.41870E+04 85 glaucophane-Fe 17.28 12.99 -4.28 -0.116 0.73145E+04 86 graphite -3.55 -8.17 -4.63 -1.322 0.79009E+04 87 greenalite 16.14 13.76 -2.38 -0.198 0.40634E+04 90 hematite 12.57 9.78 -2.79 -0.338 0.47588E+04 91 heulandite -5.83 -7.52 -1.69 -0.077 0.28938E+04 95 jadeite 4.22 2.80 -1.42 -0.142 0.24167E+04 97 kalsilite 7.58 3.88 -3.70 -0.529 0.63224E+04 98 kaolinite -1.33 -4.49 -3.16 -0.287 0.53882E+04 101 laumontite 2.88 2.03 -0.85 -0.057 0.14583E+04 102 lawsonite 9.62 8.40 -1.22 -0.081 0.20816E+04 103 leucite 4.12 0.70 -3.42 -0.342 0.58422E+04 105 lizardite 23.24 21.29 -1.95 -0.163 0.33355E+04 107 magnetite 20.09 16.49 -3.60 -0.294 0.61454E+04 108 minnesotaite 10.39 7.39 -3.00 -0.176 0.51156E+04 112 manganosite 14.06 9.12 -4.94 -1.235 0.84342E+04 120 muscovite 2.58 -0.61 -3.19 -0.188 0.54464E+04 121 paragonite 4.24 1.50 -2.74 -0.161 0.46855E+04 122 nepheline 8.34 5.98 -2.36 -0.337 0.40223E+04 128 periclase-Fe 11.63 6.71 -4.92 -1.229 0.83964E+04 134 phlogopite-Na 29.65 27.27 -2.37 -0.132 0.40512E+04 136 prehnite 19.37 18.10 -1.27 -0.075 0.21741E+04 137 prehnite-Fe 22.50 22.05 -0.45 -0.027 0.76710E+03 138 pumpellyite-Fe 46.27 43.85 -2.42 -0.054 0.41381E+04 139 pumpellyite-Mg 48.99 46.36 -2.64 -0.059 0.45056E+04 143 pyrrhotite -4.26 -8.03 -3.77 -1.256 0.64355E+04 144 pyrrhotiteFe0.875 -6.02 -9.32 -3.30 -1.215 0.56386E+04 145 pyroxmangite 7.40 5.93 -1.46 -0.293 0.24997E+04 146 pyrophyllite -6.18 -10.86 -4.68 -0.293 0.79914E+04 147 quartz -2.99 -3.18 -0.19 -0.065 0.33189E+03 152 rhodonite 7.45 5.93 -1.51 -0.302 0.25799E+04 153 sanidine -1.28 -2.49 -1.21 -0.093 0.20677E+04 165 stilpnomelane-Mg 27.44 25.57 -1.87 -0.056 0.31987E+04 171 talc 16.49 14.92 -1.57 -0.092 0.26778E+04 174 tephroite 18.09 15.05 -3.03 -0.433 0.51780E+04 178 tridymite -2.63 -3.18 -0.56 -0.186 0.95186E+03 179 tremolite 47.87 46.40 -1.47 -0.040 0.25137E+04 180 ferroactinolite 38.45 33.85 -4.61 -0.124 0.78653E+04 181 troilite-low -4.41 -8.03 -3.62 -1.206 0.61784E+04 187 wairakite 3.95 2.03 -1.92 -0.113 0.32802E+04 188 walstromite 11.51 9.70 -1.81 -0.362 0.30864E+04 189 wollastonite 10.46 9.70 -0.76 -0.152 0.12969E+04 190 pseudo-wollastonite 11.00 9.70 -1.30 -0.260 0.22167E+04 191 zoisite 22.85 19.04 -3.81 -0.173 0.65075E+04 192 akaganeite 7.75 4.89 -2.87 -0.619 0.48919E+04 199 chalcedony -2.80 -3.18 -0.38 -0.127 0.65118E+03 201 montmorillonite-Ca -2.29 -6.00 -3.71 -0.229 0.63295E+04 202 montmorillonite-K -2.24 -6.10 -3.87 -0.237 0.66005E+04 203 montmorillonite-Mg -2.48 -6.60 -4.12 -0.255 0.70394E+04 204 montmorillonite-Na -2.04 -5.41 -3.37 -0.206 0.57554E+04 205 nontronite-Ca 3.21 0.53 -2.68 -0.174 0.45825E+04 206 nontronite-H 2.53 -1.60 -4.13 -0.277 0.70485E+04 207 nontronite-K 3.34 0.43 -2.91 -0.187 0.49768E+04 208 nontronite-Mg 3.07 -0.07 -3.15 -0.204 0.53765E+04 209 nontronite-Na 3.52 1.12 -2.40 -0.154 0.40976E+04 224 tobermorite 9.82 7.55 -2.27 -0.620 0.38816E+04 230 alabandite -0.98 -5.62 -4.64 -1.547 0.79262E+04 233 boehmite 4.41 0.94 -3.47 -0.578 0.59194E+04 235 ferrous-oxide 9.81 6.71 -3.10 -0.776 0.52974E+04 240 silica-amorphous -2.09 -3.18 -1.09 -0.364 0.18654E+04 242 an20ab80 2.02 1.37 -0.65 -0.050 0.11021E+04 243 an25ab75 2.65 1.81 -0.83 -0.064 0.14246E+04 244 an30ab70 3.28 2.25 -1.03 -0.079 0.17567E+04 245 tr.625ac.25prg.125 45.16 44.28 -0.88 -0.024 0.15044E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 2.0000000 g Current total amount of reactant added: 75.9990000 g New total amount of reactant added: 77.9990000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.1490E-12 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 9 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 77.9990000 Water: Moles liquid = 0.5500E+02 kg liquid = 0.9908E+00 Moles total = 0.5453E+02 kg total = 0.9824E+00 Activity = 1.0000 Stoichiometric ionic strength = .9636713E-02 Osmotic coef. = 0.9642 True ionic strength = .1723656E-01 Chg. balance for total moles = -.1490E-12 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.98112E-10 -10.0083 0.83195E-10 -10.0799 0.84796E+00 -0.0716 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13869E-03 -3.8579 0.11698E-03 -3.9319 0.84343E+00 -0.0740 4 SO4-- 0.69683E-09 -9.1569 0.37593E-09 -9.4249 0.53949E+00 -0.2680 5 HCO3- 0.48949E-05 -5.3103 0.41338E-05 -5.3836 0.84453E+00 -0.0734 6 HS- 0.25735E-04 -4.5895 0.21708E-04 -4.6634 0.84354E+00 -0.0739 7 Al+++ 0.18908E-28 -28.7233 0.47668E-29 -29.3218 0.25210E+00 -0.5984 8 H4SiO4 0.66043E-03 -3.1802 0.66043E-03 -3.1802 0.10000E+01 0.0000 9 Ca++ 0.10335E-06 -6.9857 0.55395E-07 -7.2565 0.53598E+00 -0.2709 10 Mg++ 0.21883E-10 -10.6599 0.11681E-10 -10.9325 0.53380E+00 -0.2726 11 Fe++ 0.66570E-13 -13.1767 0.35570E-13 -13.4489 0.53432E+00 -0.2722 12 K+ 0.13473E-03 -3.8705 0.11381E-03 -3.9438 0.84471E+00 -0.0733 13 Na+ 0.17093E-01 -1.7672 0.14415E-01 -1.8412 0.84330E+00 -0.0740 14 Mn++ 0.17321E-10 -10.7614 0.92616E-11 -11.0333 0.53472E+00 -0.2719 15 HPO4-- 0.74327E-07 -7.1289 0.40104E-07 -7.3968 0.53956E+00 -0.2680 16 HSiO3- 0.87884E-02 -2.0561 0.74124E-02 -2.1300 0.84343E+00 -0.0740 17 Ca(HSiO3)+ 0.11068E-07 -7.9559 0.93511E-08 -8.0291 0.84487E+00 -0.0732 18 Mg(HSiO3)+ 0.29047E-11 -11.5369 0.24541E-11 -11.6101 0.84487E+00 -0.0732 19 NaHSiO3,aq 0.17281E-02 -2.7624 0.17281E-02 -2.7624 0.10000E+01 0.0000 20 AlO+ 0.11090E-15 -15.9551 0.93694E-16 -16.0283 0.84487E+00 -0.0732 22 HAlO2,aq 0.22428E-09 -9.6492 0.22428E-09 -9.6492 0.10000E+01 0.0000 23 AlO2- 0.70866E-05 -5.1496 0.59674E-05 -5.2242 0.84208E+00 -0.0746 24 CH4,aq 0.23256E-06 -6.6335 0.23188E-06 -6.6347 0.99705E+00 -0.0013 25 C2H6,aq 0.47134E-17 -17.3267 0.46995E-17 -17.3279 0.99705E+00 -0.0013 29 CO,aq 0.36106E-16 -16.4424 0.36106E-16 -16.4424 0.10000E+01 0.0000 30 CO2,aq 0.73704E-09 -9.1325 0.73486E-09 -9.1338 0.99705E+00 -0.0013 31 CO3-2 0.80600E-05 -5.0937 0.43401E-05 -5.3625 0.53847E+00 -0.2688 32 CaCO3,aq 0.30146E-08 -8.5208 0.30146E-08 -8.5208 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.69186E-11 -11.1600 0.58453E-11 -11.2332 0.84487E+00 -0.0732 34 CaCl+ 0.12412E-10 -10.9061 0.10487E-10 -10.9794 0.84487E+00 -0.0732 35 CaCl2,aq 0.29144E-15 -15.5354 0.29144E-15 -15.5354 0.10000E+01 0.0000 36 CaOH+ 0.56168E-07 -7.2505 0.47454E-07 -7.3237 0.84487E+00 -0.0732 37 CaSO4,aq 0.66128E-14 -14.1796 0.66128E-14 -14.1796 0.10000E+01 0.0000 38 HCl,aq 0.17834E-14 -14.7488 0.17834E-14 -14.7488 0.10000E+01 0.0000 43 FeCl+ 0.77953E-17 -17.1082 0.65860E-17 -17.1814 0.84487E+00 -0.0732 46 FeO,aq 0.19973E-09 -9.6996 0.19973E-09 -9.6996 0.10000E+01 0.0000 47 FeOH+ 0.16472E-10 -10.7832 0.13917E-10 -10.8565 0.84487E+00 -0.0732 48 HFeO2- 0.29783E-07 -7.5260 0.25120E-07 -7.6000 0.84343E+00 -0.0740 49 FeO+ 0.28094E-16 -16.5514 0.23736E-16 -16.6246 0.84487E+00 -0.0732 51 FeO2- 0.83197E-09 -9.0799 0.70171E-09 -9.1538 0.84343E+00 -0.0740 52 HFeO2,aq 0.74249E-11 -11.1293 0.74249E-11 -11.1293 0.10000E+01 0.0000 53 H2,aq 0.19616E-05 -5.7074 0.19559E-05 -5.7087 0.99705E+00 -0.0013 54 KCl,aq 0.24129E-09 -9.6175 0.24129E-09 -9.6175 0.10000E+01 0.0000 56 KOH,aq 0.58421E-06 -6.2334 0.58421E-06 -6.2334 0.10000E+01 0.0000 57 KSO4- 0.78716E-12 -12.1039 0.66392E-12 -12.1779 0.84343E+00 -0.0740 58 MgCO3,aq 0.15934E-12 -12.7977 0.15934E-12 -12.7977 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.14908E-14 -14.8266 0.12595E-14 -14.8998 0.84487E+00 -0.0732 60 MgCl+ 0.23723E-14 -14.6248 0.20043E-14 -14.6980 0.84487E+00 -0.0732 61 MgOH+ 0.65540E-10 -10.1835 0.55373E-10 -10.2567 0.84487E+00 -0.0732 63 MnO,aq 0.13858E-08 -8.8583 0.13858E-08 -8.8583 0.10000E+01 0.0000 64 MnOH+ 0.39844E-09 -9.3996 0.33663E-09 -9.4728 0.84487E+00 -0.0732 65 MnO2-2 0.12339E-10 -10.9087 0.66445E-11 -11.1775 0.53847E+00 -0.2688 66 HMnO2- 0.14359E-09 -9.8429 0.12111E-09 -9.9168 0.84343E+00 -0.0740 69 MnCl+ 0.78966E-14 -14.1026 0.66716E-14 -14.1758 0.84487E+00 -0.0732 70 MnSO4,aq 0.10052E-17 -17.9978 0.10052E-17 -17.9978 0.10000E+01 0.0000 71 NaCl,aq 0.55882E-06 -6.2527 0.55882E-06 -6.2527 0.10000E+01 0.0000 72 NaOH,aq 0.74443E-04 -4.1282 0.74443E-04 -4.1282 0.10000E+01 0.0000 74 OH- 0.82472E-02 -2.0837 0.69448E-02 -2.1583 0.84208E+00 -0.0746 79 HPO3-2 0.45394E-15 -15.3430 0.24444E-15 -15.6118 0.53847E+00 -0.2688 81 H2PO3- 0.48350E-19 -19.3156 0.40780E-19 -19.3896 0.84343E+00 -0.0740 82 H3PO4,aq 0.19414E-17 -17.7119 0.19414E-17 -17.7119 0.10000E+01 0.0000 83 H2PO4- 0.72913E-10 -10.1372 0.61548E-10 -10.2108 0.84414E+00 -0.0736 84 PO4-3 0.14936E-08 -8.8258 0.39330E-09 -9.4053 0.26333E+00 -0.5795 88 HP2O7-3 0.28255E-17 -17.5489 0.71291E-18 -18.1470 0.25231E+00 -0.5981 89 P2O7-4 0.22809E-16 -16.6419 0.20471E-17 -17.6889 0.89752E-01 -1.0470 90 H2S,aq 0.55982E-08 -8.2520 0.55817E-08 -8.2532 0.99705E+00 -0.0013 91 S2-2 0.99146E-14 -14.0037 0.53388E-14 -14.2726 0.53847E+00 -0.2688 97 SO3-2 0.17519E-15 -15.7565 0.95548E-16 -16.0198 0.54539E+00 -0.2633 98 HSO3- 0.59011E-18 -18.2291 0.49771E-18 -18.3030 0.84343E+00 -0.0740 99 HSO4- 0.35645E-16 -16.4480 0.30141E-16 -16.5208 0.84559E+00 -0.0728 101 S2O3-2 0.45775E-19 -19.3394 0.24649E-19 -19.6082 0.53847E+00 -0.2688 Charge balance for all species = -.1586E-12 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.9811193E-10 -.1887580E-01 -.1899793E+02 0.0000 2 H2O 0.1000000E+01 0.5550607E+02 0.9985005E+06 0.0000 3 Cl- 0.1386940E-03 0.1392531E-03 0.4929741E+01 6.1480 4 SO4-- 0.6968285E-09 -.7221671E-06 -.6927137E-01 10.7349 5 HCO3- 0.4894856E-05 0.1319115E-04 0.8037133E+00 4.6963 6 HS- 0.2573458E-04 0.2646304E-04 0.8739096E+00 5.4165 7 Al+++ 0.1890841E-28 0.7086791E-05 0.1909334E+00 0.9179 8 H4SiO4 0.6604328E-03 0.1117692E-01 0.1072707E+04 -3.1802 9 Ca++ 0.1033521E-06 0.1736217E-06 0.6948266E-02 12.9033 10 Mg++ 0.2188317E-10 0.9049148E-10 0.2196821E-05 9.2273 11 Fe++ 0.6656966E-13 0.3083832E-07 0.1719716E-02 6.7109 12 K+ 0.1347331E-03 0.1353176E-03 0.5283472E+01 6.1361 13 Na+ 0.1709331E-01 0.1889642E-01 0.4337915E+03 8.2387 14 Mn++ 0.1732068E-10 0.1957451E-08 0.1073817E-03 9.1265 15 HPO4-- 0.7432711E-07 0.7589358E-07 0.7273569E-02 12.7630 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.1291535E+01 -.1870244E-01 -.1272832E+01 0.0000000E+00 2 H2O 0.5453050E+02 0.5499630E+02 -.4658033E+00 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.2187123E-02 -.7155347E-06 0.2187838E-02 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.2161618E-02 0.2622000E-04 -.2187838E-02 0.0000000E+00 7 Al+++ 0.2543346E+00 0.7021706E-05 0.2543276E+00 0.0000000E+00 8 H4SiO4 0.8121867E+00 0.1107427E-01 0.8011124E+00 0.0000000E+00 9 Ca++ 0.8972445E-01 0.1720272E-06 0.8972428E-01 0.0000000E+00 10 Mg++ 0.6190397E-01 0.8966040E-10 0.6190397E-01 0.0000000E+00 11 Fe++ 0.5561396E-01 0.3055510E-07 0.5561393E-01 0.0000000E+00 12 K+ 0.1656030E-01 0.1340748E-03 0.1642622E-01 0.0000000E+00 13 Na+ 0.9806782E-01 0.1872288E-01 0.7934494E-01 0.0000000E+00 14 Mn++ 0.1352393E-02 0.1939474E-08 0.1352391E-02 0.0000000E+00 15 HPO4-- 0.4615651E-03 0.7519658E-07 0.4614899E-03 0.0000000E+00 Chg. balance for solid moles: -.3394E-16 Mass of aqueous solution: 0.992263E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 77.9990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 0.7934E-01 -1.100 20.81 1.318 24.44 7.987 andradite 0.8751E-02 -2.058 4.447 0.648 5.225 1.155 grossular 0.1390E-02 -2.857 0.6261 -0.203 0.7355 0.1742 apatite-OH 0.1538E-03 -3.813 0.7727E-01 -1.112 0.9079E-01 0.2455E-01 clinochlore 0.1238E-01 -1.907 6.882 0.838 8.085 2.618 daphnite 0.3955E-02 -2.403 2.822 0.451 3.316 0.8552 chlorite-Mn 0.2705E-03 -3.568 0.1918 -0.717 0.2253 0.6111E-01 microcline 0.1459E-01 -1.836 4.062 0.609 4.772 1.587 stilbite 0.5853E-01 -1.233 41.25 1.615 48.46 19.24 stilpnomelane-Fe 0.3667E-02 -2.436 3.953 0.597 4.644 1.365 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8630E+00 0.8630E+00 1.0000 -0.064 grossular 0.1370E+00 0.1370E+00 1.0000 -0.863 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.7455E+00 0.7455E+00 1.0000 -0.128 daphnite 0.2382E+00 0.2382E+00 1.0000 -0.623 chlorite-Mn 0.1629E-01 0.1629E-01 1.0000 -1.788 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 85.114936 g Volume = 35.065958 cm3 Porosity: -8.9018% V(tot) - V(min): -.28664E+01 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 77.9990000 g log = 1.8921 Original solution: 1000.0103000 g Original solution / Rock added: 12.82 (Water/Rock Ratio), log = 1.1079 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0232 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9972E+00 0.9859 0.1006E+01 0.1020E+01 CO2,gas 0.7629E-07 1.0071 0.7862E-07 0.7807E-07 CH4,gas 0.3294E-03 1.0126 0.3413E-03 0.3371E-03 H2,gas 0.2508E-02 1.0005 0.2568E-02 0.2566E-02 H2S,gas 0.1506E-06 0.9960 0.1534E-06 0.1540E-06 S2,gas 0.1310E-27 1.0000 0.1340E-27 0.1340E-27 CO,gas 0.5258E-13 1.0000 0.5380E-13 0.5380E-13 SO3,gas 0.9615E-45 1.0000 0.9838E-45 0.9838E-45 SO2,gas 0.9605E-25 1.0000 0.9828E-25 0.9828E-25 HCl,gas 0.3075E-17 1.0000 0.3147E-17 0.3147E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 16 albite -0.38 -0.38 0.00 0.000 -0.13080E-10 22 andradite 39.01 39.01 0.00 0.000 0.12132E-10 23 grossular 32.73 32.73 0.00 0.000 0.00000E+00 32 apatite-OH -18.15 -18.15 0.00 0.000 0.00000E+00 46 clinochlore 39.07 39.07 0.00 0.000 -0.24265E-10 47 daphnite 28.97 28.97 0.00 0.000 -0.42463E-10 48 chlorite-Mn 46.87 46.87 0.00 0.000 -0.48529E-10 116 microcline -2.49 -2.49 0.00 0.000 -0.22748E-10 163 stilbite -7.52 -7.52 0.00 0.000 -0.90992E-11 164 stilpnomelane-Fe 13.02 13.02 0.00 0.000 0.69761E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -15.46 -8.80 -2.934 0.15032E+05 -7.104 3 CH4,gas 4.54 -0.62 -5.17 -1.291 0.88205E+04 -3.467 4 H2,gas 8.00 3.71 -4.29 -2.451 0.73240E+04 -2.590 5 H2S,gas -6.23 -14.74 -8.51 -4.257 0.14536E+05 -6.814 6 S2,gas -7.34 -36.91 -29.57 -4.550 0.50493E+05 -27.873 7 CO,gas 3.21 -11.75 -14.97 -4.606 0.25558E+05 -13.269 8 SO3,gas 17.12 -29.58 -46.71 -11.677 0.79749E+05 -45.007 9 SO2,gas 0.83 -25.87 -26.71 -7.122 0.45601E+05 -25.008 10 HCl,gas 5.19 -14.01 -19.20 -9.601 0.32785E+05 -17.502 11 acmite 7.71 6.73 -0.98 -0.101 0.16659E+04 15 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 19 spessartine 24.46 19.67 -4.78 -0.239 0.81660E+04 20 analcite 3.32 2.80 -0.53 -0.058 0.89737E+03 26 annite 20.12 17.65 -2.48 -0.138 0.42298E+04 27 phlogopite 27.06 25.20 -1.87 -0.104 0.31916E+04 29 anorthite 12.71 8.38 -4.33 -0.333 0.73959E+04 35 aragonite 0.97 -2.56 -3.53 -1.176 0.60219E+04 36 brucite 12.57 9.23 -3.34 -0.668 0.57051E+04 37 calcite 0.81 -2.56 -3.37 -1.124 0.57577E+04 38 carnegieite-low 9.02 5.98 -3.05 -0.435 0.52024E+04 39 carnegieite-high 10.09 5.98 -4.12 -0.588 0.70294E+04 40 carpholite-Mg 8.58 4.70 -3.88 -0.259 0.66237E+04 41 carpholite-Fe 6.71 2.19 -4.53 -0.302 0.77284E+04 42 celadonite 5.34 3.56 -1.78 -0.105 0.30410E+04 43 celadonite-Fe 3.88 1.04 -2.83 -0.167 0.48361E+04 44 chrysotile 23.89 21.32 -2.57 -0.214 0.43896E+04 49 chlorite-Al-free 47.17 42.64 -4.53 -0.189 0.77345E+04 51 chloritoid-Fe 9.17 5.37 -3.81 -0.254 0.65004E+04 52 chloritoid-Mn 11.40 7.78 -3.62 -0.241 0.61791E+04 54 coesite -2.38 -3.18 -0.80 -0.268 0.13730E+04 61 cristobalite -2.56 -3.18 -0.62 -0.207 0.10583E+04 63 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71234E+04 65 diaspore 2.87 0.92 -1.96 -0.326 0.33394E+04 66 diamond -3.10 -8.04 -4.94 -1.412 0.84357E+04 67 diopside 16.18 15.77 -0.41 -0.041 0.70199E+03 68 hedenbergite 14.21 13.25 -0.95 -0.095 0.16297E+04 75 epidote 24.67 22.96 -1.71 -0.083 0.29237E+04 76 clinozoisite 22.81 19.02 -3.79 -0.172 0.64648E+04 77 epidote-Fe 29.84 26.90 -2.95 -0.153 0.50292E+04 78 fayalite 14.05 10.24 -3.80 -0.543 0.64955E+04 79 ferrosilite 11.15 7.06 -4.09 -0.409 0.69802E+04 83 gibbsite 4.08 0.92 -3.16 -0.452 0.53980E+04 84 glaucophane 22.97 20.55 -2.42 -0.065 0.41338E+04 85 glaucophane-Fe 17.28 13.00 -4.27 -0.115 0.72930E+04 86 graphite -3.55 -8.04 -4.50 -1.285 0.76779E+04 87 greenalite 16.14 13.77 -2.37 -0.197 0.40419E+04 90 hematite 12.57 9.71 -2.85 -0.346 0.48744E+04 91 heulandite -5.83 -7.52 -1.69 -0.077 0.28938E+04 95 jadeite 4.22 2.80 -1.42 -0.142 0.24229E+04 97 kalsilite 7.58 3.87 -3.71 -0.530 0.63348E+04 98 kaolinite -1.33 -4.52 -3.19 -0.290 0.54497E+04 101 laumontite 2.88 2.02 -0.86 -0.058 0.14769E+04 102 lawsonite 9.62 8.38 -1.24 -0.082 0.21126E+04 103 leucite 4.12 0.69 -3.43 -0.343 0.58484E+04 105 lizardite 23.24 21.32 -1.92 -0.160 0.32823E+04 107 magnetite 20.09 16.42 -3.67 -0.299 0.62580E+04 108 minnesotaite 10.39 7.41 -2.98 -0.175 0.50817E+04 112 manganosite 14.06 9.13 -4.93 -1.233 0.84206E+04 120 muscovite 2.58 -0.65 -3.23 -0.190 0.55203E+04 121 paragonite 4.24 1.45 -2.79 -0.164 0.47594E+04 122 nepheline 8.34 5.98 -2.36 -0.338 0.40347E+04 128 periclase-Fe 11.63 6.71 -4.92 -1.229 0.83934E+04 134 phlogopite-Na 29.65 27.30 -2.35 -0.130 0.40104E+04 136 prehnite 19.37 18.10 -1.27 -0.075 0.21684E+04 137 prehnite-Fe 22.50 22.04 -0.46 -0.028 0.78234E+03 138 pumpellyite-Fe 46.27 43.83 -2.44 -0.054 0.41608E+04 139 pumpellyite-Mg 48.99 46.35 -2.65 -0.059 0.45177E+04 143 pyrrhotite -4.26 -8.03 -3.77 -1.257 0.64407E+04 144 pyrrhotiteFe0.875 -6.02 -9.33 -3.31 -1.219 0.56592E+04 145 pyroxmangite 7.40 5.95 -1.45 -0.290 0.24799E+04 146 pyrophyllite -6.18 -10.88 -4.71 -0.294 0.80405E+04 147 quartz -2.99 -3.18 -0.19 -0.064 0.32568E+03 152 rhodonite 7.45 5.95 -1.50 -0.300 0.25601E+04 153 sanidine -1.28 -2.49 -1.21 -0.093 0.20677E+04 165 stilpnomelane-Mg 27.44 25.60 -1.84 -0.055 0.31458E+04 171 talc 16.49 14.96 -1.53 -0.090 0.26122E+04 174 tephroite 18.09 15.07 -3.01 -0.430 0.51446E+04 178 tridymite -2.63 -3.18 -0.55 -0.185 0.94565E+03 179 tremolite 47.87 46.50 -1.37 -0.037 0.23351E+04 180 ferroactinolite 38.45 33.92 -4.53 -0.123 0.77396E+04 181 troilite-low -4.41 -8.03 -3.62 -1.207 0.61835E+04 187 wairakite 3.95 2.02 -1.93 -0.114 0.32988E+04 188 walstromite 11.51 9.72 -1.79 -0.357 0.30498E+04 189 wollastonite 10.46 9.72 -0.74 -0.148 0.12602E+04 190 pseudo-wollastonite 11.00 9.72 -1.28 -0.255 0.21800E+04 191 zoisite 22.85 19.02 -3.83 -0.174 0.65389E+04 192 akaganeite 7.75 4.86 -2.90 -0.627 0.49497E+04 199 chalcedony -2.80 -3.18 -0.38 -0.126 0.64497E+03 201 montmorillonite-Ca -2.29 -6.01 -3.72 -0.230 0.63569E+04 202 montmorillonite-K -2.24 -6.12 -3.88 -0.238 0.66269E+04 203 montmorillonite-Mg -2.48 -6.62 -4.14 -0.256 0.70695E+04 204 montmorillonite-Na -2.04 -5.42 -3.39 -0.207 0.57818E+04 205 nontronite-Ca 3.21 0.47 -2.74 -0.178 0.46826E+04 206 nontronite-H 2.53 -1.66 -4.19 -0.281 0.71536E+04 207 nontronite-K 3.34 0.37 -2.97 -0.191 0.50758E+04 208 nontronite-Mg 3.07 -0.13 -3.21 -0.208 0.54793E+04 209 nontronite-Na 3.52 1.06 -2.46 -0.158 0.41967E+04 224 tobermorite 9.82 7.57 -2.25 -0.615 0.38500E+04 230 alabandite -0.98 -5.62 -4.64 -1.546 0.79208E+04 233 boehmite 4.41 0.92 -3.49 -0.581 0.59563E+04 235 ferrous-oxide 9.81 6.71 -3.10 -0.775 0.52944E+04 240 silica-amorphous -2.09 -3.18 -1.09 -0.363 0.18592E+04 242 an20ab80 2.02 1.37 -0.65 -0.050 0.11083E+04 243 an25ab75 2.65 1.81 -0.84 -0.065 0.14324E+04 244 an30ab70 3.28 2.24 -1.03 -0.080 0.17661E+04 245 tr.625ac.25prg.125 45.16 44.37 -0.79 -0.021 0.13539E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 2.0000000 g Current total amount of reactant added: 77.9990000 g New total amount of reactant added: 79.9990000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.1490E-12 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 10 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 79.9990000 Water: Moles liquid = 0.5499E+02 kg liquid = 0.9906E+00 Moles total = 0.5451E+02 kg total = 0.9819E+00 Activity = 1.0000 Stoichiometric ionic strength = .9793539E-02 Osmotic coef. = 0.9640 True ionic strength = .1749507E-01 Chg. balance for total moles = -.1490E-12 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.97237E-10 -10.0122 0.82380E-10 -10.0842 0.84721E+00 -0.0720 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13872E-03 -3.8579 0.11689E-03 -3.9322 0.84263E+00 -0.0744 4 SO4-- 0.37571E-09 -9.4251 0.20194E-09 -9.6948 0.53749E+00 -0.2696 5 HCO3- 0.47863E-05 -5.3200 0.40383E-05 -5.3938 0.84373E+00 -0.0738 6 HS- 0.25741E-04 -4.5894 0.21693E-04 -4.6637 0.84274E+00 -0.0743 7 Al+++ 0.17635E-28 -28.7536 0.44083E-29 -29.3557 0.24997E+00 -0.6021 8 H4SiO4 0.66593E-03 -3.1766 0.66593E-03 -3.1766 0.10000E+01 0.0000 9 Ca++ 0.10580E-06 -6.9755 0.56491E-07 -7.2480 0.53395E+00 -0.2725 10 Mg++ 0.21926E-10 -10.6590 0.11659E-10 -10.9333 0.53176E+00 -0.2743 11 Fe++ 0.65773E-13 -13.1820 0.35010E-13 -13.4558 0.53228E+00 -0.2739 12 K+ 0.13675E-03 -3.8641 0.11541E-03 -3.9378 0.84392E+00 -0.0737 13 Na+ 0.17350E-01 -1.7607 0.14617E-01 -1.8351 0.84249E+00 -0.0744 14 Mn++ 0.17354E-10 -10.7606 0.92442E-11 -11.0341 0.53268E+00 -0.2735 15 HPO4-- 0.71266E-07 -7.1471 0.38310E-07 -7.4167 0.53756E+00 -0.2696 16 HSiO3- 0.89578E-02 -2.0478 0.75481E-02 -2.1222 0.84263E+00 -0.0744 17 Ca(HSiO3)+ 0.11504E-07 -7.9391 0.97106E-08 -8.0128 0.84408E+00 -0.0736 18 Mg(HSiO3)+ 0.29550E-11 -11.5294 0.24943E-11 -11.6031 0.84408E+00 -0.0736 19 NaHSiO3,aq 0.17845E-02 -2.7485 0.17845E-02 -2.7485 0.10000E+01 0.0000 20 AlO+ 0.10469E-15 -15.9801 0.88369E-16 -16.0537 0.84408E+00 -0.0736 22 HAlO2,aq 0.21362E-09 -9.6703 0.21362E-09 -9.6703 0.10000E+01 0.0000 23 AlO2- 0.68233E-05 -5.1660 0.57402E-05 -5.2411 0.84126E+00 -0.0751 24 CH4,aq 0.42265E-06 -6.3740 0.42139E-06 -6.3753 0.99701E+00 -0.0013 25 C2H6,aq 0.13297E-16 -16.8763 0.13257E-16 -16.8776 0.99701E+00 -0.0013 29 CO,aq 0.40890E-16 -16.3884 0.40890E-16 -16.3884 0.10000E+01 0.0000 30 CO2,aq 0.71299E-09 -9.1469 0.71086E-09 -9.1482 0.99701E+00 -0.0013 31 CO3-2 0.79814E-05 -5.0979 0.42818E-05 -5.3684 0.53647E+00 -0.2705 32 CaCO3,aq 0.30329E-08 -8.5181 0.30329E-08 -8.5181 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.68989E-11 -11.1612 0.58232E-11 -11.2348 0.84408E+00 -0.0736 34 CaCl+ 0.12660E-10 -10.8976 0.10686E-10 -10.9712 0.84408E+00 -0.0736 35 CaCl2,aq 0.29674E-15 -15.5276 0.29674E-15 -15.5276 0.10000E+01 0.0000 36 CaOH+ 0.57899E-07 -7.2373 0.48872E-07 -7.3109 0.84408E+00 -0.0736 37 CaSO4,aq 0.36225E-14 -14.4410 0.36225E-14 -14.4410 0.10000E+01 0.0000 38 HCl,aq 0.17645E-14 -14.7534 0.17645E-14 -14.7534 0.10000E+01 0.0000 43 FeCl+ 0.76738E-17 -17.1150 0.64772E-17 -17.1886 0.84408E+00 -0.0736 46 FeO,aq 0.20050E-09 -9.6979 0.20050E-09 -9.6979 0.10000E+01 0.0000 47 FeOH+ 0.16389E-10 -10.7855 0.13833E-10 -10.8591 0.84408E+00 -0.0736 48 HFeO2- 0.30221E-07 -7.5197 0.25465E-07 -7.5941 0.84263E+00 -0.0744 49 FeO+ 0.25833E-16 -16.5878 0.21805E-16 -16.6614 0.84408E+00 -0.0736 51 FeO2- 0.78023E-09 -9.1078 0.65744E-09 -9.1821 0.84263E+00 -0.0744 52 HFeO2,aq 0.68884E-11 -11.1619 0.68884E-11 -11.1619 0.10000E+01 0.0000 53 H2,aq 0.22967E-05 -5.6389 0.22898E-05 -5.6402 0.99701E+00 -0.0013 54 KCl,aq 0.24449E-09 -9.6117 0.24449E-09 -9.6117 0.10000E+01 0.0000 56 KOH,aq 0.59827E-06 -6.2231 0.59827E-06 -6.2231 0.10000E+01 0.0000 57 KSO4- 0.42919E-12 -12.3674 0.36164E-12 -12.4417 0.84263E+00 -0.0744 58 MgCO3,aq 0.15691E-12 -12.8044 0.15691E-12 -12.8044 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.14550E-14 -14.8371 0.12281E-14 -14.9108 0.84408E+00 -0.0736 60 MgCl+ 0.23682E-14 -14.6256 0.19989E-14 -14.6992 0.84408E+00 -0.0736 61 MgOH+ 0.66126E-10 -10.1796 0.55816E-10 -10.2532 0.84408E+00 -0.0736 63 MnO,aq 0.14106E-08 -8.8506 0.14106E-08 -8.8506 0.10000E+01 0.0000 64 MnOH+ 0.40200E-09 -9.3958 0.33932E-09 -9.4694 0.84408E+00 -0.0736 65 MnO2-2 0.12859E-10 -10.8908 0.68983E-11 -11.1613 0.53647E+00 -0.2705 66 HMnO2- 0.14775E-09 -9.8305 0.12450E-09 -9.9048 0.84263E+00 -0.0744 69 MnCl+ 0.78830E-14 -14.1033 0.66539E-14 -14.1769 0.84408E+00 -0.0736 70 MnSO4,aq 0.53893E-18 -18.2685 0.53893E-18 -18.2685 0.10000E+01 0.0000 71 NaCl,aq 0.56622E-06 -6.2470 0.56622E-06 -6.2470 0.10000E+01 0.0000 72 NaOH,aq 0.76235E-04 -4.1178 0.76235E-04 -4.1178 0.10000E+01 0.0000 74 OH- 0.83369E-02 -2.0790 0.70135E-02 -2.1541 0.84126E+00 -0.0751 79 HPO3-2 0.50958E-15 -15.2928 0.27337E-15 -15.5632 0.53647E+00 -0.2705 81 H2PO3- 0.53595E-19 -19.2709 0.45160E-19 -19.3452 0.84263E+00 -0.0744 82 H3PO4,aq 0.18184E-17 -17.7403 0.18184E-17 -17.7403 0.10000E+01 0.0000 83 H2PO4- 0.69034E-10 -10.1609 0.58219E-10 -10.2349 0.84334E+00 -0.0740 84 PO4-3 0.14524E-08 -8.8379 0.37942E-09 -9.4209 0.26124E+00 -0.5830 88 HP2O7-3 0.25748E-17 -17.5893 0.64418E-18 -18.1910 0.25018E+00 -0.6017 89 P2O7-4 0.21124E-16 -16.6752 0.18681E-17 -17.7286 0.88435E-01 -1.0534 90 H2S,aq 0.55397E-08 -8.2565 0.55231E-08 -8.2578 0.99701E+00 -0.0013 91 S2-2 0.84882E-14 -14.0712 0.45536E-14 -14.3416 0.53647E+00 -0.2705 97 SO3-2 0.11057E-15 -15.9564 0.60089E-16 -16.2212 0.54344E+00 -0.2648 98 HSO3- 0.36783E-18 -18.4344 0.30994E-18 -18.5087 0.84263E+00 -0.0744 99 HSO4- 0.18977E-16 -16.7218 0.16032E-16 -16.7950 0.84481E+00 -0.0732 101 S2O3-2 0.24422E-19 -19.6122 0.13102E-19 -19.8827 0.53647E+00 -0.2705 Charge balance for all species = -.1501E-12 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.9723749E-10 -.1919200E-01 -.1931566E+02 0.0000 2 H2O 0.1000000E+01 0.5550594E+02 0.9984714E+06 0.0000 3 Cl- 0.1387178E-03 0.1392843E-03 0.4930715E+01 6.1519 4 SO4-- 0.3757085E-09 -.9963501E-06 -.9556887E-01 10.4736 5 HCO3- 0.4786280E-05 0.1319411E-04 0.8038720E+00 4.6904 6 HS- 0.2574073E-04 0.2674300E-04 0.8831312E+00 5.4205 7 Al+++ 0.1763518E-28 0.6823526E-05 0.1838356E+00 0.8968 8 H4SiO4 0.6659344E-03 0.1140817E-01 0.1094872E+04 -3.1766 9 Ca++ 0.1057967E-06 0.1782528E-06 0.7133410E-02 12.9203 10 Mg++ 0.2192607E-10 0.9116797E-10 0.2213185E-05 9.2350 11 Fe++ 0.6577289E-13 0.3122518E-07 0.1741243E-02 6.7125 12 K+ 0.1367527E-03 0.1373512E-03 0.5362732E+01 6.1464 13 Na+ 0.1734988E-01 0.1921113E-01 0.4410042E+03 8.2490 14 Mn++ 0.1735429E-10 0.1990626E-08 0.1091986E-03 9.1342 15 HPO4-- 0.7126573E-07 0.7278715E-07 0.6975665E-02 12.7517 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.1324652E+01 -.1901147E-01 -.1305640E+01 0.0000000E+00 2 H2O 0.5450543E+02 0.5498384E+02 -.4784080E+00 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.2242549E-02 -.9869783E-06 0.2243536E-02 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.2217045E-02 0.2649145E-04 -.2243536E-02 0.0000000E+00 7 Al+++ 0.2608561E+00 0.6759343E-05 0.2608493E+00 0.0000000E+00 8 H4SiO4 0.8330122E+00 0.1130086E-01 0.8217114E+00 0.0000000E+00 9 Ca++ 0.9202473E-01 0.1765762E-06 0.9202456E-01 0.0000000E+00 10 Mg++ 0.6349127E-01 0.9031043E-10 0.6349127E-01 0.0000000E+00 11 Fe++ 0.5703997E-01 0.3093147E-07 0.5703994E-01 0.0000000E+00 12 K+ 0.1698493E-01 0.1360592E-03 0.1684887E-01 0.0000000E+00 13 Na+ 0.1005783E+00 0.1903042E-01 0.8154788E-01 0.0000000E+00 14 Mn++ 0.1387070E-02 0.1971902E-08 0.1387068E-02 0.0000000E+00 15 HPO4-- 0.4734002E-03 0.7210250E-07 0.4733281E-03 0.0000000E+00 Chg. balance for solid moles: 0.1133E-15 Mass of aqueous solution: 0.992067E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 79.9990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 0.8155E-01 -1.089 21.38 1.330 24.50 8.209 andradite 0.8974E-02 -2.047 4.560 0.659 5.224 1.185 grossular 0.1463E-02 -2.835 0.6591 -0.181 0.7551 0.1834 apatite-OH 0.1578E-03 -3.802 0.7925E-01 -1.101 0.9079E-01 0.2518E-01 clinochlore 0.1270E-01 -1.896 7.058 0.849 8.085 2.685 daphnite 0.4000E-02 -2.398 2.854 0.456 3.270 0.8650 chlorite-Mn 0.2774E-03 -3.557 0.1967 -0.706 0.2253 0.6268E-01 microcline 0.1494E-01 -1.826 4.158 0.619 4.764 1.624 stilbite 0.5992E-01 -1.222 42.23 1.626 48.38 19.70 stilpnomelane-Fe 0.3818E-02 -2.418 4.116 0.614 4.715 1.422 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8598E+00 0.8598E+00 1.0000 -0.066 grossular 0.1402E+00 0.1402E+00 1.0000 -0.853 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.7480E+00 0.7480E+00 1.0000 -0.126 daphnite 0.2357E+00 0.2357E+00 1.0000 -0.628 chlorite-Mn 0.1634E-01 0.1634E-01 1.0000 -1.787 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 87.294734 g Volume = 35.956882 cm3 Porosity: -8.9616% V(tot) - V(min): -.29573E+01 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 79.9990000 g log = 1.9031 Original solution: 1000.0103000 g Original solution / Rock added: 12.50 (Water/Rock Ratio), log = 1.0969 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0240 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9965E+00 0.9859 0.1006E+01 0.1020E+01 CO2,gas 0.7375E-07 1.0071 0.7605E-07 0.7552E-07 CH4,gas 0.5982E-03 1.0126 0.6203E-03 0.6126E-03 H2,gas 0.2934E-02 1.0005 0.3006E-02 0.3005E-02 H2S,gas 0.1489E-06 0.9960 0.1518E-06 0.1524E-06 S2,gas 0.9350E-28 1.0000 0.9574E-28 0.9574E-28 CO,gas 0.5951E-13 1.0000 0.6093E-13 0.6093E-13 SO3,gas 0.5061E-45 1.0000 0.5182E-45 0.5182E-45 SO2,gas 0.5919E-25 1.0000 0.6061E-25 0.6061E-25 HCl,gas 0.3041E-17 1.0000 0.3114E-17 0.3114E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 16 albite -0.38 -0.38 0.00 0.000 0.11184E-10 22 andradite 39.01 39.01 0.00 0.000 0.00000E+00 23 grossular 32.73 32.73 0.00 0.000 -0.12132E-10 32 apatite-OH -18.15 -18.15 0.00 0.000 0.60662E-11 46 clinochlore 39.07 39.07 0.00 0.000 0.12132E-10 47 daphnite 28.97 28.97 0.00 0.000 0.24265E-10 48 chlorite-Mn 46.87 46.87 0.00 0.000 0.12132E-10 116 microcline -2.49 -2.49 0.00 0.000 0.13649E-10 163 stilbite -7.52 -7.52 0.00 0.000 0.15165E-10 164 stilpnomelane-Fe 13.02 13.02 0.00 0.000 0.21232E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -15.48 -8.82 -2.939 0.15056E+05 -7.119 3 CH4,gas 4.54 -0.36 -4.91 -1.227 0.83775E+04 -3.207 4 H2,gas 8.00 3.78 -4.22 -2.412 0.72071E+04 -2.522 5 H2S,gas -6.23 -14.75 -8.52 -4.259 0.14544E+05 -6.819 6 S2,gas -7.34 -37.05 -29.72 -4.572 0.50742E+05 -28.019 7 CO,gas 3.21 -11.70 -14.91 -4.589 0.25465E+05 -13.215 8 SO3,gas 17.12 -29.86 -46.98 -11.746 0.80225E+05 -45.286 9 SO2,gas 0.83 -26.08 -26.92 -7.178 0.45959E+05 -25.217 10 HCl,gas 5.19 -14.02 -19.21 -9.603 0.32793E+05 -17.507 11 acmite 7.71 6.72 -0.99 -0.103 0.16916E+04 15 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 19 spessartine 24.46 19.67 -4.79 -0.240 0.81801E+04 20 analcite 3.32 2.79 -0.53 -0.059 0.90353E+03 26 annite 20.12 17.65 -2.47 -0.137 0.42213E+04 27 phlogopite 27.06 25.22 -1.85 -0.103 0.31520E+04 29 anorthite 12.71 8.36 -4.35 -0.335 0.74267E+04 35 aragonite 0.97 -2.56 -3.52 -1.175 0.60174E+04 36 brucite 12.57 9.24 -3.33 -0.667 0.56919E+04 37 calcite 0.81 -2.56 -3.37 -1.123 0.57532E+04 38 carnegieite-low 9.02 5.97 -3.05 -0.436 0.52147E+04 39 carnegieite-high 10.09 5.97 -4.12 -0.589 0.70417E+04 40 carpholite-Mg 8.58 4.68 -3.91 -0.260 0.66704E+04 41 carpholite-Fe 6.71 2.15 -4.56 -0.304 0.77855E+04 42 celadonite 5.34 3.57 -1.77 -0.104 0.30216E+04 43 celadonite-Fe 3.88 1.05 -2.83 -0.166 0.48271E+04 44 chrysotile 23.89 21.35 -2.54 -0.212 0.43377E+04 49 chlorite-Al-free 47.17 42.70 -4.47 -0.186 0.76306E+04 51 chloritoid-Fe 9.17 5.33 -3.84 -0.256 0.65636E+04 52 chloritoid-Mn 11.40 7.75 -3.65 -0.243 0.62320E+04 54 coesite -2.38 -3.18 -0.80 -0.267 0.13668E+04 61 cristobalite -2.56 -3.18 -0.62 -0.205 0.10522E+04 63 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71234E+04 65 diaspore 2.87 0.90 -1.98 -0.329 0.33755E+04 66 diamond -3.10 -7.92 -4.82 -1.377 0.82265E+04 67 diopside 16.18 15.80 -0.38 -0.038 0.64736E+03 68 hedenbergite 14.21 13.28 -0.93 -0.093 0.15855E+04 75 epidote 24.67 22.93 -1.74 -0.084 0.29748E+04 76 clinozoisite 22.81 19.00 -3.80 -0.173 0.64964E+04 77 epidote-Fe 29.84 26.85 -2.99 -0.155 0.50998E+04 78 fayalite 14.05 10.25 -3.80 -0.542 0.64836E+04 79 ferrosilite 11.15 7.07 -4.08 -0.408 0.69622E+04 83 gibbsite 4.08 0.90 -3.18 -0.455 0.54340E+04 84 glaucophane 22.97 20.58 -2.39 -0.065 0.40819E+04 85 glaucophane-Fe 17.28 13.02 -4.26 -0.115 0.72722E+04 86 graphite -3.55 -7.92 -4.37 -1.250 0.74688E+04 87 greenalite 16.14 13.78 -2.36 -0.196 0.40211E+04 90 hematite 12.57 9.65 -2.92 -0.354 0.49857E+04 91 heulandite -5.83 -7.52 -1.69 -0.077 0.28938E+04 95 jadeite 4.22 2.79 -1.42 -0.142 0.24290E+04 97 kalsilite 7.58 3.87 -3.72 -0.531 0.63471E+04 98 kaolinite -1.33 -4.56 -3.23 -0.293 0.55096E+04 101 laumontite 2.88 2.01 -0.88 -0.058 0.14953E+04 102 lawsonite 9.62 8.36 -1.26 -0.084 0.21434E+04 103 leucite 4.12 0.69 -3.43 -0.343 0.58546E+04 105 lizardite 23.24 21.35 -1.89 -0.158 0.32304E+04 107 magnetite 20.09 16.36 -3.73 -0.304 0.63665E+04 108 minnesotaite 10.39 7.43 -2.96 -0.174 0.50486E+04 112 manganosite 14.06 9.13 -4.92 -1.231 0.84074E+04 120 muscovite 2.58 -0.69 -3.28 -0.193 0.55925E+04 121 paragonite 4.24 1.41 -2.83 -0.166 0.48316E+04 122 nepheline 8.34 5.97 -2.37 -0.339 0.40470E+04 128 periclase-Fe 11.63 6.71 -4.91 -1.229 0.83906E+04 134 phlogopite-Na 29.65 27.32 -2.33 -0.129 0.39708E+04 136 prehnite 19.37 18.10 -1.27 -0.075 0.21639E+04 137 prehnite-Fe 22.50 22.03 -0.47 -0.028 0.79735E+03 138 pumpellyite-Fe 46.27 43.82 -2.45 -0.054 0.41850E+04 139 pumpellyite-Mg 48.99 46.34 -2.65 -0.059 0.45315E+04 143 pyrrhotite -4.26 -8.04 -3.78 -1.258 0.64457E+04 144 pyrrhotiteFe0.875 -6.02 -9.34 -3.33 -1.223 0.56791E+04 145 pyroxmangite 7.40 5.96 -1.44 -0.288 0.24605E+04 146 pyrophyllite -6.18 -10.91 -4.74 -0.296 0.80881E+04 147 quartz -2.99 -3.18 -0.19 -0.062 0.31953E+03 152 rhodonite 7.45 5.96 -1.49 -0.298 0.25408E+04 153 sanidine -1.28 -2.49 -1.21 -0.093 0.20677E+04 165 stilpnomelane-Mg 27.44 25.63 -1.81 -0.054 0.30939E+04 171 talc 16.49 15.00 -1.49 -0.088 0.25480E+04 174 tephroite 18.09 15.09 -2.99 -0.428 0.51120E+04 178 tridymite -2.63 -3.18 -0.55 -0.183 0.93950E+03 179 tremolite 47.87 46.60 -1.27 -0.034 0.21617E+04 180 ferroactinolite 38.45 33.99 -4.46 -0.121 0.76180E+04 181 troilite-low -4.41 -8.04 -3.62 -1.208 0.61885E+04 187 wairakite 3.95 2.01 -1.94 -0.114 0.33173E+04 188 walstromite 11.51 9.74 -1.77 -0.353 0.30145E+04 189 wollastonite 10.46 9.74 -0.72 -0.143 0.12249E+04 190 pseudo-wollastonite 11.00 9.74 -1.26 -0.251 0.21447E+04 191 zoisite 22.85 19.00 -3.85 -0.175 0.65704E+04 192 akaganeite 7.75 4.82 -2.93 -0.634 0.50054E+04 199 chalcedony -2.80 -3.18 -0.37 -0.125 0.63882E+03 201 montmorillonite-Ca -2.29 -6.03 -3.74 -0.231 0.63834E+04 202 montmorillonite-K -2.24 -6.13 -3.90 -0.239 0.66524E+04 203 montmorillonite-Mg -2.48 -6.64 -4.16 -0.257 0.70987E+04 204 montmorillonite-Na -2.04 -5.44 -3.40 -0.208 0.58072E+04 205 nontronite-Ca 3.21 0.42 -2.80 -0.182 0.47783E+04 206 nontronite-H 2.53 -1.72 -4.25 -0.285 0.72542E+04 207 nontronite-K 3.34 0.31 -3.03 -0.194 0.51705E+04 208 nontronite-Mg 3.07 -0.19 -3.27 -0.212 0.55777E+04 209 nontronite-Na 3.52 1.01 -2.51 -0.161 0.42914E+04 224 tobermorite 9.82 7.59 -2.24 -0.610 0.38196E+04 230 alabandite -0.98 -5.61 -4.64 -1.545 0.79154E+04 233 boehmite 4.41 0.90 -3.51 -0.585 0.59924E+04 235 ferrous-oxide 9.81 6.71 -3.10 -0.775 0.52915E+04 240 silica-amorphous -2.09 -3.18 -1.09 -0.362 0.18530E+04 242 an20ab80 2.02 1.37 -0.65 -0.050 0.11145E+04 243 an25ab75 2.65 1.80 -0.84 -0.065 0.14401E+04 244 an30ab70 3.28 2.24 -1.04 -0.080 0.17753E+04 245 tr.625ac.25prg.125 45.16 44.46 -0.71 -0.019 0.12079E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 2.0000000 g Current total amount of reactant added: 79.9990000 g New total amount of reactant added: 81.9990000 g Mixing fraction reached given limit of 0.8000E+02 TOTMIX = 0.8200E+02 Execution stopped.