File SKIP_SPECIES.TXT lists species and minerals omitted from the calculations due to given T, P, option switches, or suppression in CHIMRUN, or are suppressed in the SOLTHERM database. It also lists minerals for which density is not specified in SOLTHERM. This is an extended P(to 5 kB), T(to 600 C) run (CON_FLAG = 1). methanol,aq is suppressed in SOLTHERM data file. methanol,aq is suppressed in SOLTHERM data file. CuCl4-3 is suppressed in SOLTHERM data file. H2BO3- is suppressed in SOLTHERM data file. UO2CO3,aq is suppressed in SOLTHERM data file. UO2SO4,aq is suppressed in SOLTHERM data file. UO2Cl2,aq is suppressed in SOLTHERM data file. UO2F2,aq is suppressed in SOLTHERM data file. PO4-3 is suppressed in SOLTHERM data file. H2PO4- is suppressed in SOLTHERM data file. H3PO4 is suppressed in SOLTHERM data file. O2,gas is suppressed in THIS RUN. O2,gas is suppressed in THIS RUN. amesite is suppressed in SOLTHERM data file. antigorite is suppressed in SOLTHERM data file. goethite is suppressed in THIS RUN. goethite is suppressed in THIS RUN. riebeckite is suppressed in THIS RUN. riebeckite is suppressed in THIS RUN. sapphirine-Fe(221) is suppressed in SOLTHERM data file. sapphirine(221) is suppressed in SOLTHERM data file. talc-prl is suppressed in SOLTHERM data file. PrO1.833(s) is suppressed in SOLTHERM data file. niter-NH4 is suppressed in SOLTHERM data file. FMQ_HS-1 is suppressed in THIS RUN. kf-ab-equil is suppressed in THIS RUN. ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Species No. Charge Tot.moles Trial molality Gamma Mixing solution H+ 1 1. -0.13247E+01 0.97237E-10 0.8472 0.00000000E+00 H2O 2 0. 0.54505E+02 0.10000E+01 1.0000 0.00000000E+00 Cl- 3 -1. 0.13797E-03 0.13872E-03 0.8426 0.00000000E+00 SO4-- 4 -2. 0.22425E-02 0.37571E-09 0.5375 0.00000000E+00 HCO3- 5 -1. 0.13070E-04 0.47863E-05 0.8437 0.00000000E+00 HS- 6 -1. -0.22170E-02 0.25741E-04 0.8427 0.00000000E+00 Al+++ 7 3. 0.26086E+00 0.17635E-28 0.2500 0.00000000E+00 H4SiO4 8 0. 0.83301E+00 0.66593E-03 1.0000 0.00000000E+00 Ca++ 9 2. 0.92025E-01 0.10580E-06 0.5340 0.00000000E+00 Mg++ 10 2. 0.63491E-01 0.21926E-10 0.5318 0.00000000E+00 Fe++ 11 2. 0.57040E-01 0.65773E-13 0.5323 0.00000000E+00 K+ 12 1. 0.16985E-01 0.13675E-03 0.8439 0.00000000E+00 Na+ 13 1. 0.10058E+00 0.17350E-01 0.8425 0.00000000E+00 Mn++ 14 2. 0.13871E-02 0.17354E-10 0.5327 0.00000000E+00 HPO4-- 15 -2. 0.47340E-03 0.71266E-07 0.5376 0.00000000E+00 Chg. balance for total moles = -.7416E-13 Max. difference allowed = 0.1380E-07 The following parameters were given: ERPC = 0.1000E-11 pH = 0.0000 PFLUID = 50.0000 SLIM = 0.200000E+03 TEMP = 100.0000 SINC = 0.4000E+01 TEMPC = 0.0000 TOTMIX = 0.799990E+02 ENTH = 0.0000 SENTH = 0.0000 DENTH = 0.0000 TOTWAT = 90.0000 SOLMIN = 0.0000E+00 RM = 0.0000 AQGRM = 1000.0103 SUPRNT = 0.1000E-19 VBOX-1 = 32.9996 RHOFRS = 0.0000 RHOROC = 2.5000 The following options were selected: CONFLG = 1 C = 3 IFRAC = 0 IPUNCH = 2 NLOOP = 400 ISTEP = 2 LIMSOL = 1 LOOC = 0 IENTH = 0 ITREF = 0 IDEAL = 0 IPSAT = 1 INCREM = 0 INCP = 0 MINSOL = 1 NEUT = 0 AWAT = 0 CHGF = 0 Of the derived species, only those with molality > 0.10E-19 will appear in the output Species No. Charge Log K(diss) Species No. Charge Log K(diss) HSiO3- 16 -1. 9.0298 MnO2-2 65 -2. 40.4638 Ca(HSiO3)+ 17 1. 7.6723 HMnO2- 66 -1. 29.1232 Mg(HSiO3)+ 18 1. 7.5773 MnO4- 67 -1. 83.3111 NaHSiO3,aq 19 0. 7.8210 MnO4-2 68 -2. 81.3005 AlO+ 20 1. 6.8663 MnCl+ 69 1. -0.7894 AlOH+2 21 2. 3.1691 MnSO4,aq 70 0. -2.4604 HAlO2,aq 22 0. 10.5671 NaCl,aq 71 0. 0.4796 AlO2- 23 -1. 16.2221 NaOH,aq 72 0. 12.3669 CH4,aq 24 0. 6.0126 O2,aq 73 0. 53.5502 C2H6,aq 25 0. 12.3733 OH- 74 -1. 12.2382 C3H8,aq 26 0. 17.3707 HO2- 75 -1. 50.8010 C4H10,aq 27 0. 22.3757 H2O2,aq 76 0. 40.0166 ethanol,aq 28 0. 15.3258 H3PO2,aq 77 0. 24.3066 CO,aq 29 0. 4.6892 H2PO2- 78 -1. 26.5366 CO2,aq 30 0. -6.3298 HPO3-2 79 -2. 11.9254 CO3-2 31 -2. 10.0588 H3PO3,aq 80 0. 3.5792 CaCO3,aq 32 0. 5.9605 H2PO3- 81 -1. 5.6232 Ca(HCO3)+ 33 1. -1.4070 H3PO4,aq 82 0. -9.8447 CaCl+ 34 1. -0.2091 H2PO4- 83 -1. -7.2659 CaCl2,aq 35 0. 0.4151 PO4-3 84 -3. 12.0884 CaOH+ 36 1. 10.1471 H4P2O7,aq 85 0. -17.8095 CaSO4,aq 37 0. -2.5018 H3P2O7- 86 -1. -15.9156 HCl,aq 38 0. 0.7370 H2P2O7-2 87 -2. -13.4262 HClO,aq 39 0. 32.4260 HP2O7-3 88 -3. -6.7266 ClO- 40 -1. 39.6530 P2O7-4 89 -4. 2.8952 HClO2,aq 41 0. 70.1812 H2S,aq 90 0. -6.4900 Fe+3 42 3. 8.3809 S2-2 91 -2. 1.2355 FeCl+ 43 1. -0.1994 S3-2 92 -2. -8.8031 FeCl2,aq 44 0. 4.3001 S3- 93 -1. -16.3389 FeCl+2 45 2. 6.5269 S4-2 94 -2. -18.6615 FeO,aq 46 0. 16.4104 S5-2 95 -2. -28.3439 FeOH+ 47 1. 7.4874 SO2,aq 96 0. -0.2309 HFeO2- 48 -1. 24.3908 SO3-2 97 -2. 10.3052 FeO+ 49 1. 11.4004 HSO3- 98 -1. 2.5086 FeOH+2 50 2. 9.1194 HSO4- 99 -1. -2.9839 FeO2- 51 -1. 24.0895 HSO5- 100 -1. 38.8366 HFeO2,aq 52 0. 15.9850 S2O3-2 101 -2. -4.5600 H2,aq 53 0. 9.4190 HS2O3- 102 -1. -6.8123 KCl,aq 54 0. 1.7417 H2S2O3,aq 103 0. -8.0173 KHSO4,aq 55 0. -0.4514 S2O4-2 104 -2. 10.5541 KOH,aq 56 0. 12.3695 HS2O4- 105 -1. 7.6551 KSO4- 57 -1. -1.1908 H2S2O4,aq 106 0. 6.6259 MgCO3,aq 58 0. 6.5614 S2O5-2 107 -2. 10.0741 Mg(HCO3)+ 59 1. -1.4164 S2O6-2 108 -2. 11.5521 MgCl+ 60 1. -0.1664 S2O8-2 109 -2. 42.0620 MgOH+ 61 1. 9.4041 S3O6-2 110 -2. 3.7866 Mn+3 62 3. 19.1453 S4O6-2 111 -2. -17.8657 MnO,aq 63 0. 17.9848 S5O6-2 112 -2. -14.1333 MnOH+ 64 1. 8.5194 113 0. 10.3111 For mixed gases (JSOLS=6), log K(hydrol) = log (K*P) Log K Trial Log K Trial Mineral No. hydrol Moles Mineral No. hydrol Moles H2O,gas 1 1.696 0.0000E+00 osumilite(2) 124 20.667 0.0000E+00 CO2,gas 2 -6.660 0.0000E+00 osumilite-Fe 125 14.390 0.0000E+00 CH4,gas 3 4.544 0.0000E+00 pargasite 126 65.092 0.0000E+00 H2,gas 4 8.000 0.0000E+00 periclase 127 16.138 0.0000E+00 H2S,gas 5 -6.230 0.0000E+00 periclase-Fe 128 11.627 0.0000E+00 S2,gas 6 -7.335 0.0000E+00 perovskite-Al 129 12.344 0.0000E+00 CO,gas 7 3.215 0.0000E+00 perovskite-Ca 130 23.807 0.0000E+00 SO3,gas 8 17.121 0.0000E+00 perovskite-Fe 131 21.143 0.0000E+00 SO2,gas 9 0.832 0.0000E+00 perovskite-Mg 132 23.119 0.0000E+00 HCl,gas 10 5.189 0.0000E+00 phase_A 133 80.189 0.0000E+00 acmite 11 7.710 0.0000E+00 phlogopite-Na 134 29.647 0.0000E+00 akermanite 12 36.442 0.0000E+00 piemontite(ordered) 135 33.776 0.0000E+00 akimotoite 13 16.591 0.0000E+00 prehnite 136 19.372 0.0000E+00 akimotoite-Fe 14 13.067 0.0000E+00 prehnite-Fe 137 22.498 0.0000E+00 albite-high 15 0.693 0.0000E+00 pumpellyite-Fe 138 46.269 0.0000E+00 albite 16 -0.384 0.8155E-01 pumpellyite-Mg 139 48.995 0.0000E+00 almandine 17 24.442 0.0000E+00 px-Mg-tschermaks 140 19.616 0.0000E+00 pyrope 18 37.248 0.0000E+00 px-Ca-tschermaks 141 18.610 0.0000E+00 spessartine 19 24.457 0.0000E+00 pyrite 142 -21.247 0.0000E+00 analcite 20 3.322 0.0000E+00 pyrrhotite 143 -4.260 0.0000E+00 andalusite 21 5.002 0.0000E+00 pyrrhotiteFe0.875 144 -6.017 0.0000E+00 andradite 22 39.009 0.8974E-02 pyroxmangite 145 7.399 0.0000E+00 grossular 23 32.731 0.1463E-02 pyrophyllite 146 -6.176 0.0000E+00 anhydrite 24 -5.317 0.0000E+00 quartz 147 -2.989 0.0000E+00 ankerite 25 -2.135 0.0000E+00 rankinite 148 40.713 0.0000E+00 annite 26 20.123 0.0000E+00 ringwoodite-Fe 149 15.456 0.0000E+00 phlogopite 27 27.065 0.0000E+00 ringwoodite-Mg 150 27.575 0.0000E+00 biotite-Mn 28 32.960 0.0000E+00 rhodochrosite 151 -0.976 0.0000E+00 anorthite 29 12.710 0.0000E+00 rhodonite 152 7.446 0.0000E+00 anthophyllite 30 51.852 0.0000E+00 sanidine 153 -1.275 0.0000E+00 anthophyllite-Fe 31 29.306 0.0000E+00 sapphirine(351) 154 78.899 0.0000E+00 apatite-OH 32 -18.153 0.1578E-03 siderite 155 -2.608 0.0000E+00 apatite-OH-zs 33 -12.736 0.0000E+00 sillimanite 156 5.262 0.0000E+00 apatite-Cl-zs 34 -16.674 0.0000E+00 sodalite 157 49.976 0.0000E+00 aragonite 35 0.967 0.0000E+00 spinel 158 20.870 0.0000E+00 brucite 36 12.569 0.0000E+00 spurrite 159 59.482 0.0000E+00 calcite 37 0.812 0.0000E+00 staurolite-Fe 160 73.598 0.0000E+00 carnegieite-low 38 9.023 0.0000E+00 staurolite-Mg 161 89.802 0.0000E+00 carnegieite-high 39 10.093 0.0000E+00 staurolite-Mn 162 83.909 0.0000E+00 carpholite-Mg 40 8.582 0.0000E+00 stilbite 163 -7.522 0.5992E-01 carpholite-Fe 41 6.713 0.0000E+00 stilpnomelane-Fe 164 13.017 0.3818E-02 celadonite 42 5.342 0.0000E+00 stilpnomelane-Mg 165 27.441 0.0000E+00 celadonite-Fe 43 3.877 0.0000E+00 stishovite 166 2.720 0.0000E+00 chrysotile 44 23.892 0.0000E+00 sudoite-Fe 167 18.296 0.0000E+00 chondrodite 45 56.475 0.0000E+00 sudoite 168 21.077 0.0000E+00 clinochlore 46 39.070 0.1270E-01 sulfur 169 -9.152 0.0000E+00 daphnite 47 28.965 0.4000E-02 sylvite 170 1.338 0.0000E+00 chlorite-Mn 48 46.869 0.2774E-03 talc 171 16.491 0.0000E+00 chlorite-Al-free 49 47.173 0.0000E+00 talc-Fe 172 13.448 0.0000E+00 chloritoid-Mg 50 13.198 0.0000E+00 talc-tschermaks 173 19.091 0.0000E+00 chloritoid-Fe 51 9.174 0.0000E+00 tephroite 174 18.086 0.0000E+00 chloritoid-Mn 52 11.401 0.0000E+00 tilleyite 175 41.377 0.0000E+00 clinohumite 53 97.128 0.0000E+00 titanite-CaSi 176 15.479 0.0000E+00 coesite 54 -2.376 0.0000E+00 topaz-H 177 4.618 0.0000E+00 cordierite-H 55 23.715 0.0000E+00 tridymite 178 -2.626 0.0000E+00 cordierite 56 24.049 0.0000E+00 tremolite 179 47.869 0.0000E+00 cordierite-Fe 57 20.450 0.0000E+00 ferroactinolite 180 38.452 0.0000E+00 cordierite-Mn 58 25.066 0.0000E+00 troilite-low 181 -4.411 0.0000E+00 corundum 59 8.383 0.0000E+00 tschermakite 182 48.210 0.0000E+00 corundum-MgSi 60 18.891 0.0000E+00 vesuvianite 183 223.471 0.0000E+00 cristobalite 61 -2.560 0.0000E+00 wadeite-Si 184 20.216 0.0000E+00 cummingtonite 62 52.099 0.0000E+00 wadsleyite-Fe 185 15.680 0.0000E+00 cymrite-K 63 1.685 0.0000E+00 wadsleyite-Mg 186 25.850 0.0000E+00 deerite 64 95.671 0.0000E+00 wairakite 187 3.950 0.0000E+00 diaspore 65 2.874 0.0000E+00 walstromite 188 11.509 0.0000E+00 diamond 66 -3.102 0.0000E+00 wollastonite 189 10.461 0.0000E+00 diopside 67 16.181 0.0000E+00 pseudo-wollastonite 190 11.000 0.0000E+00 hedenbergite 68 14.208 0.0000E+00 zoisite 191 22.849 0.0000E+00 dolomite,ordered 69 0.546 0.0000E+00 akaganeite 192 7.755 0.0000E+00 eastonite 70 28.489 0.0000E+00 beidellite-Ca 193 -1.646 0.0000E+00 enstatite 71 17.265 0.0000E+00 beidellite-H 194 -2.326 0.0000E+00 clinoenstatite-HiP 72 18.354 0.0000E+00 beidellite-K 195 -1.520 0.0000E+00 clinoenstatite 73 17.166 0.0000E+00 beidellite-Mg 196 -1.790 0.0000E+00 protoenstatite 74 17.824 0.0000E+00 beidellite-Na 197 -1.342 0.0000E+00 epidote 75 24.670 0.0000E+00 calcium 198 84.026 0.0000E+00 clinozoisite 76 22.806 0.0000E+00 chalcedony 199 -2.802 0.0000E+00 epidote-Fe 77 29.841 0.0000E+00 dawsonite 200 1.682 0.0000E+00 fayalite 78 14.046 0.0000E+00 montmorillonite-Ca 201 -2.291 0.0000E+00 ferrosilite 79 11.149 0.0000E+00 montmorillonite-K 202 -2.237 0.0000E+00 forsterite 80 21.016 0.0000E+00 montmorillonite-Mg 203 -2.480 0.0000E+00 gedrite 81 50.522 0.0000E+00 montmorillonite-Na 204 -2.038 0.0000E+00 gehlenite 82 36.628 0.0000E+00 nontronite-Ca 205 3.215 0.0000E+00 gibbsite 83 4.079 0.0000E+00 nontronite-H 206 2.533 0.0000E+00 glaucophane 84 22.975 0.0000E+00 nontronite-K 207 3.341 0.0000E+00 glaucophane-Fe 85 17.276 0.0000E+00 nontronite-Mg 208 3.075 0.0000E+00 graphite 86 -3.546 0.0000E+00 nontronite-Na 209 3.520 0.0000E+00 greenalite 87 16.140 0.0000E+00 sepiolite 210 24.118 0.0000E+00 grunerite 88 31.215 0.0000E+00 alite 211 57.999 0.0000E+00 halite 89 1.575 0.0000E+00 belite 212 30.433 0.0000E+00 hematite 90 12.566 0.0000E+00 ettringite 213 43.232 0.0000E+00 heulandite 91 -5.827 0.0000E+00 gypsum 214 -4.955 0.0000E+00 hercynite 92 17.279 0.0000E+00 hemicarboaluminate 215 70.954 0.0000E+00 hollandite 93 25.673 0.0000E+00 hydrogarnet 216 60.662 0.0000E+00 iron 94 19.086 0.0000E+00 hydrogarnet-Si 217 50.586 0.0000E+00 jadeite 95 4.215 0.0000E+00 jennite 218 24.367 0.0000E+00 julgoldite 96 70.427 0.0000E+00 monosulfoaluminate 219 53.400 0.0000E+00 kalsilite 97 7.584 0.0000E+00 monocarboaluminate 220 61.898 0.0000E+00 kaolinite 98 -1.333 0.0000E+00 portlandite 221 18.272 0.0000E+00 kyanite 99 4.876 0.0000E+00 stratlingite 222 36.502 0.0000E+00 larnite-bredigite 100 30.686 0.0000E+00 tricarboaluminate 223 70.370 0.0000E+00 laumontite 101 2.883 0.0000E+00 tobermorite 224 9.823 0.0000E+00 lawsonite 102 9.616 0.0000E+00 C4AH13 225 81.816 0.0000E+00 leucite 103 4.119 0.0000E+00 C2AH8 226 45.203 0.0000E+00 lime 104 25.998 0.0000E+00 C3A 227 86.953 0.0000E+00 lizardite 105 23.244 0.0000E+00 C4AF 228 117.416 0.0000E+00 magnesite 106 0.691 0.0000E+00 CAH10 229 28.335 0.0000E+00 magnetite 107 20.087 0.0000E+00 alabandite 230 -0.978 0.0000E+00 minnesotaite 108 10.388 0.0000E+00 alunite 231 -10.435 0.0000E+00 minnesotaite-Mg 109 20.602 0.0000E+00 artinite 232 15.121 0.0000E+00 magnesioferrite 110 26.212 0.0000E+00 boehmite 233 4.406 0.0000E+00 majorite 111 53.251 0.0000E+00 dolomite,disordered 234 1.247 0.0000E+00 manganosite 112 14.058 0.0000E+00 ferrous-oxide 235 9.812 0.0000E+00 margarite 113 17.324 0.0000E+00 huntite 236 3.770 0.0000E+00 meionite 114 44.874 0.0000E+00 hydromagnesite 237 19.995 0.0000E+00 merwinite 115 55.930 0.0000E+00 nesquehonite 238 4.723 0.0000E+00 microcline 116 -2.486 0.1494E-01 potassium-oxide 239 69.038 0.0000E+00 monticellite 117 24.339 0.0000E+00 silica-amorphous 240 -2.091 0.0000E+00 mullite-Al 118 363.148 0.0000E+00 sodium-oxide 241 55.169 0.0000E+00 mullite-Si 119 7.264 0.0000E+00 an20ab80 242 2.018 0.0000E+00 muscovite 120 2.582 0.0000E+00 an25ab75 243 2.646 0.0000E+00 paragonite 121 4.239 0.0000E+00 an30ab70 244 3.279 0.0000E+00 nepheline 122 8.339 0.0000E+00 tr.625ac.25prg.125 245 45.165 0.0000E+00 osumilite(1) 123 21.717 0.0000E+00 246 0.000 0.0000E+00 Initial composition of reactant (wt%): SiO2 62.56 MgO 3.200 Al2O3 16.62 CaO 6.450 FeO 3.530 Na2O 3.890 Fe2O3 1.770 K2O 1.000 MnO 0.1230 P2O5 0.4200E-01 Sum of wt% of reactants: 99.1850 Reactant consumed: 79.9990000 g log = 1.9031 Original solution: 1000.0103000 g Original solution / Rock added: 12.50 (Water/Rock Ratio), log = 1.0969 The following minerals and/or gases with identical index are in solid solution: H2O,gas 6 CO2,gas 6 CH4,gas 6 H2,gas 6 H2S,gas 6 S2,gas 6 CO,gas 6 SO3,gas 6 SO2,gas 6 HCl,gas 6 almandine 16 pyrope 16 spessartine 16 andradite 8 grossular 8 annite 15 phlogopite 15 biotite-Mn 15 clinochlore 1 daphnite 1 chlorite-Mn 1 diopside 5 hedenbergite 5 epidote 3 clinozoisite 3 greenalite 18 iron 9 lizardite 18 magnetite 14 talc 7 talc-Fe 7 tremolite 2 ferroactinolite 2 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 12 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 79.9990000 Water: Moles liquid = 0.5499E+02 kg liquid = 0.9906E+00 Moles total = 0.5451E+02 kg total = 0.9819E+00 Activity = 1.0000 Stoichiometric ionic strength = .9793539E-02 Osmotic coef. = 0.9640 True ionic strength = .1749507E-01 Chg. balance for total moles = -.7416E-13 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.97237E-10 -10.0122 0.82380E-10 -10.0842 0.84721E+00 -0.0720 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13872E-03 -3.8579 0.11689E-03 -3.9322 0.84263E+00 -0.0744 4 SO4-- 0.37571E-09 -9.4251 0.20194E-09 -9.6948 0.53749E+00 -0.2696 5 HCO3- 0.47863E-05 -5.3200 0.40383E-05 -5.3938 0.84373E+00 -0.0738 6 HS- 0.25741E-04 -4.5894 0.21693E-04 -4.6637 0.84274E+00 -0.0743 7 Al+++ 0.17635E-28 -28.7536 0.44083E-29 -29.3557 0.24997E+00 -0.6021 8 H4SiO4 0.66593E-03 -3.1766 0.66593E-03 -3.1766 0.10000E+01 0.0000 9 Ca++ 0.10580E-06 -6.9755 0.56491E-07 -7.2480 0.53395E+00 -0.2725 10 Mg++ 0.21926E-10 -10.6590 0.11659E-10 -10.9333 0.53176E+00 -0.2743 11 Fe++ 0.65773E-13 -13.1820 0.35010E-13 -13.4558 0.53228E+00 -0.2739 12 K+ 0.13675E-03 -3.8641 0.11541E-03 -3.9378 0.84392E+00 -0.0737 13 Na+ 0.17350E-01 -1.7607 0.14617E-01 -1.8351 0.84249E+00 -0.0744 14 Mn++ 0.17354E-10 -10.7606 0.92442E-11 -11.0341 0.53268E+00 -0.2735 15 HPO4-- 0.71266E-07 -7.1471 0.38310E-07 -7.4167 0.53756E+00 -0.2696 16 HSiO3- 0.89578E-02 -2.0478 0.75481E-02 -2.1222 0.84263E+00 -0.0744 17 Ca(HSiO3)+ 0.11504E-07 -7.9391 0.97106E-08 -8.0128 0.84408E+00 -0.0736 18 Mg(HSiO3)+ 0.29550E-11 -11.5294 0.24943E-11 -11.6031 0.84408E+00 -0.0736 19 NaHSiO3,aq 0.17845E-02 -2.7485 0.17845E-02 -2.7485 0.10000E+01 0.0000 20 AlO+ 0.10469E-15 -15.9801 0.88369E-16 -16.0537 0.84408E+00 -0.0736 22 HAlO2,aq 0.21362E-09 -9.6703 0.21362E-09 -9.6703 0.10000E+01 0.0000 23 AlO2- 0.68233E-05 -5.1660 0.57402E-05 -5.2411 0.84126E+00 -0.0751 24 CH4,aq 0.42265E-06 -6.3740 0.42139E-06 -6.3753 0.99701E+00 -0.0013 25 C2H6,aq 0.13297E-16 -16.8763 0.13257E-16 -16.8776 0.99701E+00 -0.0013 29 CO,aq 0.40890E-16 -16.3884 0.40890E-16 -16.3884 0.10000E+01 0.0000 30 CO2,aq 0.71299E-09 -9.1469 0.71086E-09 -9.1482 0.99701E+00 -0.0013 31 CO3-2 0.79814E-05 -5.0979 0.42818E-05 -5.3684 0.53647E+00 -0.2705 32 CaCO3,aq 0.30329E-08 -8.5181 0.30329E-08 -8.5181 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.68989E-11 -11.1612 0.58232E-11 -11.2348 0.84408E+00 -0.0736 34 CaCl+ 0.12660E-10 -10.8976 0.10686E-10 -10.9712 0.84408E+00 -0.0736 35 CaCl2,aq 0.29674E-15 -15.5276 0.29674E-15 -15.5276 0.10000E+01 0.0000 36 CaOH+ 0.57899E-07 -7.2373 0.48872E-07 -7.3109 0.84408E+00 -0.0736 37 CaSO4,aq 0.36225E-14 -14.4410 0.36225E-14 -14.4410 0.10000E+01 0.0000 38 HCl,aq 0.17645E-14 -14.7534 0.17645E-14 -14.7534 0.10000E+01 0.0000 43 FeCl+ 0.76738E-17 -17.1150 0.64772E-17 -17.1886 0.84408E+00 -0.0736 46 FeO,aq 0.20050E-09 -9.6979 0.20050E-09 -9.6979 0.10000E+01 0.0000 47 FeOH+ 0.16389E-10 -10.7855 0.13833E-10 -10.8591 0.84408E+00 -0.0736 48 HFeO2- 0.30221E-07 -7.5197 0.25465E-07 -7.5941 0.84263E+00 -0.0744 49 FeO+ 0.25833E-16 -16.5878 0.21805E-16 -16.6614 0.84408E+00 -0.0736 51 FeO2- 0.78023E-09 -9.1078 0.65744E-09 -9.1821 0.84263E+00 -0.0744 52 HFeO2,aq 0.68884E-11 -11.1619 0.68884E-11 -11.1619 0.10000E+01 0.0000 53 H2,aq 0.22967E-05 -5.6389 0.22898E-05 -5.6402 0.99701E+00 -0.0013 54 KCl,aq 0.24449E-09 -9.6117 0.24449E-09 -9.6117 0.10000E+01 0.0000 56 KOH,aq 0.59827E-06 -6.2231 0.59827E-06 -6.2231 0.10000E+01 0.0000 57 KSO4- 0.42919E-12 -12.3674 0.36164E-12 -12.4417 0.84263E+00 -0.0744 58 MgCO3,aq 0.15691E-12 -12.8044 0.15691E-12 -12.8044 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.14550E-14 -14.8371 0.12281E-14 -14.9108 0.84408E+00 -0.0736 60 MgCl+ 0.23682E-14 -14.6256 0.19989E-14 -14.6992 0.84408E+00 -0.0736 61 MgOH+ 0.66126E-10 -10.1796 0.55816E-10 -10.2532 0.84408E+00 -0.0736 63 MnO,aq 0.14106E-08 -8.8506 0.14106E-08 -8.8506 0.10000E+01 0.0000 64 MnOH+ 0.40200E-09 -9.3958 0.33932E-09 -9.4694 0.84408E+00 -0.0736 65 MnO2-2 0.12859E-10 -10.8908 0.68983E-11 -11.1613 0.53647E+00 -0.2705 66 HMnO2- 0.14775E-09 -9.8305 0.12450E-09 -9.9048 0.84263E+00 -0.0744 69 MnCl+ 0.78830E-14 -14.1033 0.66539E-14 -14.1769 0.84408E+00 -0.0736 70 MnSO4,aq 0.53893E-18 -18.2685 0.53893E-18 -18.2685 0.10000E+01 0.0000 71 NaCl,aq 0.56622E-06 -6.2470 0.56622E-06 -6.2470 0.10000E+01 0.0000 72 NaOH,aq 0.76235E-04 -4.1178 0.76235E-04 -4.1178 0.10000E+01 0.0000 74 OH- 0.83369E-02 -2.0790 0.70135E-02 -2.1541 0.84126E+00 -0.0751 79 HPO3-2 0.50958E-15 -15.2928 0.27337E-15 -15.5632 0.53647E+00 -0.2705 81 H2PO3- 0.53595E-19 -19.2709 0.45160E-19 -19.3452 0.84263E+00 -0.0744 82 H3PO4,aq 0.18184E-17 -17.7403 0.18184E-17 -17.7403 0.10000E+01 0.0000 83 H2PO4- 0.69034E-10 -10.1609 0.58219E-10 -10.2349 0.84334E+00 -0.0740 84 PO4-3 0.14524E-08 -8.8379 0.37942E-09 -9.4209 0.26124E+00 -0.5830 88 HP2O7-3 0.25748E-17 -17.5893 0.64418E-18 -18.1910 0.25018E+00 -0.6017 89 P2O7-4 0.21124E-16 -16.6752 0.18681E-17 -17.7286 0.88435E-01 -1.0534 90 H2S,aq 0.55397E-08 -8.2565 0.55231E-08 -8.2578 0.99701E+00 -0.0013 91 S2-2 0.84882E-14 -14.0712 0.45536E-14 -14.3416 0.53647E+00 -0.2705 97 SO3-2 0.11057E-15 -15.9564 0.60089E-16 -16.2212 0.54344E+00 -0.2648 98 HSO3- 0.36783E-18 -18.4344 0.30994E-18 -18.5087 0.84263E+00 -0.0744 99 HSO4- 0.18977E-16 -16.7218 0.16032E-16 -16.7950 0.84481E+00 -0.0732 101 S2O3-2 0.24422E-19 -19.6122 0.13102E-19 -19.8827 0.53647E+00 -0.2705 Charge balance for all species = -.7332E-13 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.9723749E-10 -.1919200E-01 -.1931566E+02 0.0000 2 H2O 0.1000000E+01 0.5550594E+02 0.9984714E+06 0.0000 3 Cl- 0.1387178E-03 0.1392843E-03 0.4930715E+01 6.1519 4 SO4-- 0.3757085E-09 -.9963501E-06 -.9556887E-01 10.4736 5 HCO3- 0.4786280E-05 0.1319411E-04 0.8038720E+00 4.6904 6 HS- 0.2574073E-04 0.2674300E-04 0.8831312E+00 5.4205 7 Al+++ 0.1763518E-28 0.6823526E-05 0.1838356E+00 0.8968 8 H4SiO4 0.6659344E-03 0.1140817E-01 0.1094872E+04 -3.1766 9 Ca++ 0.1057967E-06 0.1782528E-06 0.7133410E-02 12.9203 10 Mg++ 0.2192607E-10 0.9116796E-10 0.2213184E-05 9.2350 11 Fe++ 0.6577289E-13 0.3122518E-07 0.1741243E-02 6.7125 12 K+ 0.1367527E-03 0.1373512E-03 0.5362732E+01 6.1464 13 Na+ 0.1734988E-01 0.1921113E-01 0.4410042E+03 8.2490 14 Mn++ 0.1735429E-10 0.1990626E-08 0.1091986E-03 9.1342 15 HPO4-- 0.7126573E-07 0.7278715E-07 0.6975665E-02 12.7517 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.1324652E+01 -.1901147E-01 -.1305640E+01 0.0000000E+00 2 H2O 0.5450543E+02 0.5498384E+02 -.4784080E+00 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.2242549E-02 -.9869783E-06 0.2243536E-02 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.2217045E-02 0.2649145E-04 -.2243536E-02 0.0000000E+00 7 Al+++ 0.2608561E+00 0.6759343E-05 0.2608493E+00 0.0000000E+00 8 H4SiO4 0.8330122E+00 0.1130086E-01 0.8217114E+00 0.0000000E+00 9 Ca++ 0.9202473E-01 0.1765762E-06 0.9202456E-01 0.0000000E+00 10 Mg++ 0.6349127E-01 0.9031041E-10 0.6349127E-01 0.0000000E+00 11 Fe++ 0.5703997E-01 0.3093147E-07 0.5703994E-01 0.0000000E+00 12 K+ 0.1698493E-01 0.1360592E-03 0.1684887E-01 0.0000000E+00 13 Na+ 0.1005783E+00 0.1903042E-01 0.8154788E-01 0.0000000E+00 14 Mn++ 0.1387070E-02 0.1971902E-08 0.1387068E-02 0.0000000E+00 15 HPO4-- 0.4734002E-03 0.7210250E-07 0.4733281E-03 0.0000000E+00 Chg. balance for solid moles: -.9476E-16 Mass of aqueous solution: 0.992067E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 79.9990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 0.8155E-01 -1.089 21.38 1.330 24.50 8.209 andradite 0.8974E-02 -2.047 4.560 0.659 5.224 1.185 grossular 0.1463E-02 -2.835 0.6591 -0.181 0.7551 0.1834 apatite-OH 0.1578E-03 -3.802 0.7925E-01 -1.101 0.9079E-01 0.2518E-01 clinochlore 0.1270E-01 -1.896 7.058 0.849 8.085 2.685 daphnite 0.4000E-02 -2.398 2.854 0.456 3.270 0.8650 chlorite-Mn 0.2774E-03 -3.557 0.1967 -0.706 0.2253 0.6268E-01 microcline 0.1494E-01 -1.826 4.158 0.619 4.764 1.624 stilbite 0.5992E-01 -1.222 42.23 1.626 48.38 19.70 stilpnomelane-Fe 0.3818E-02 -2.418 4.116 0.614 4.715 1.422 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8598E+00 0.8598E+00 1.0000 -0.066 grossular 0.1402E+00 0.1402E+00 1.0000 -0.853 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.7480E+00 0.7480E+00 1.0000 -0.126 daphnite 0.2357E+00 0.2357E+00 1.0000 -0.628 chlorite-Mn 0.1634E-01 0.1634E-01 1.0000 -1.787 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 87.294734 g Volume = 35.956882 cm3 Porosity: -8.9616% V(tot) - V(min): -.29573E+01 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 79.9990000 g log = 1.9031 Original solution: 1000.0103000 g Original solution / Rock added: 12.50 (Water/Rock Ratio), log = 1.0969 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0240 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9965E+00 0.9859 0.1006E+01 0.1020E+01 CO2,gas 0.7375E-07 1.0071 0.7605E-07 0.7552E-07 CH4,gas 0.5982E-03 1.0126 0.6203E-03 0.6126E-03 H2,gas 0.2934E-02 1.0005 0.3006E-02 0.3005E-02 H2S,gas 0.1489E-06 0.9960 0.1518E-06 0.1524E-06 S2,gas 0.9350E-28 1.0000 0.9574E-28 0.9574E-28 CO,gas 0.5951E-13 1.0000 0.6093E-13 0.6093E-13 SO3,gas 0.5061E-45 1.0000 0.5182E-45 0.5182E-45 SO2,gas 0.5919E-25 1.0000 0.6061E-25 0.6061E-25 HCl,gas 0.3041E-17 1.0000 0.3114E-17 0.3114E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 16 albite -0.38 -0.38 0.00 0.000 -0.94784E-12 22 andradite 39.01 39.01 0.00 0.000 0.24265E-10 23 grossular 32.73 32.73 0.00 0.000 -0.12132E-10 32 apatite-OH -18.15 -18.15 0.00 0.000 0.00000E+00 46 clinochlore 39.07 39.07 0.00 0.000 -0.36397E-10 47 daphnite 28.97 28.97 0.00 0.000 -0.18198E-10 48 chlorite-Mn 46.87 46.87 0.00 0.000 -0.12132E-10 116 microcline -2.49 -2.49 0.00 0.000 0.15165E-11 163 stilbite -7.52 -7.52 0.00 0.000 -0.33364E-10 164 stilpnomelane-Fe 13.02 13.02 0.00 0.000 -0.27298E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -15.48 -8.82 -2.939 0.15056E+05 -7.119 3 CH4,gas 4.54 -0.36 -4.91 -1.227 0.83775E+04 -3.207 4 H2,gas 8.00 3.78 -4.22 -2.412 0.72071E+04 -2.522 5 H2S,gas -6.23 -14.75 -8.52 -4.259 0.14544E+05 -6.819 6 S2,gas -7.34 -37.05 -29.72 -4.572 0.50742E+05 -28.019 7 CO,gas 3.21 -11.70 -14.91 -4.589 0.25465E+05 -13.215 8 SO3,gas 17.12 -29.86 -46.98 -11.746 0.80225E+05 -45.286 9 SO2,gas 0.83 -26.08 -26.92 -7.178 0.45959E+05 -25.217 10 HCl,gas 5.19 -14.02 -19.21 -9.603 0.32793E+05 -17.507 11 acmite 7.71 6.72 -0.99 -0.103 0.16916E+04 15 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 19 spessartine 24.46 19.67 -4.79 -0.240 0.81801E+04 20 analcite 3.32 2.79 -0.53 -0.059 0.90353E+03 26 annite 20.12 17.65 -2.47 -0.137 0.42213E+04 27 phlogopite 27.06 25.22 -1.85 -0.103 0.31520E+04 29 anorthite 12.71 8.36 -4.35 -0.335 0.74267E+04 35 aragonite 0.97 -2.56 -3.52 -1.175 0.60174E+04 36 brucite 12.57 9.24 -3.33 -0.667 0.56919E+04 37 calcite 0.81 -2.56 -3.37 -1.123 0.57532E+04 38 carnegieite-low 9.02 5.97 -3.05 -0.436 0.52147E+04 39 carnegieite-high 10.09 5.97 -4.12 -0.589 0.70417E+04 40 carpholite-Mg 8.58 4.68 -3.91 -0.260 0.66704E+04 41 carpholite-Fe 6.71 2.15 -4.56 -0.304 0.77855E+04 42 celadonite 5.34 3.57 -1.77 -0.104 0.30216E+04 43 celadonite-Fe 3.88 1.05 -2.83 -0.166 0.48271E+04 44 chrysotile 23.89 21.35 -2.54 -0.212 0.43377E+04 49 chlorite-Al-free 47.17 42.70 -4.47 -0.186 0.76306E+04 51 chloritoid-Fe 9.17 5.33 -3.84 -0.256 0.65636E+04 52 chloritoid-Mn 11.40 7.75 -3.65 -0.243 0.62320E+04 54 coesite -2.38 -3.18 -0.80 -0.267 0.13668E+04 61 cristobalite -2.56 -3.18 -0.62 -0.205 0.10522E+04 63 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71234E+04 65 diaspore 2.87 0.90 -1.98 -0.329 0.33755E+04 66 diamond -3.10 -7.92 -4.82 -1.377 0.82265E+04 67 diopside 16.18 15.80 -0.38 -0.038 0.64736E+03 68 hedenbergite 14.21 13.28 -0.93 -0.093 0.15855E+04 75 epidote 24.67 22.93 -1.74 -0.084 0.29748E+04 76 clinozoisite 22.81 19.00 -3.80 -0.173 0.64964E+04 77 epidote-Fe 29.84 26.85 -2.99 -0.155 0.50998E+04 78 fayalite 14.05 10.25 -3.80 -0.542 0.64836E+04 79 ferrosilite 11.15 7.07 -4.08 -0.408 0.69622E+04 83 gibbsite 4.08 0.90 -3.18 -0.455 0.54340E+04 84 glaucophane 22.97 20.58 -2.39 -0.065 0.40819E+04 85 glaucophane-Fe 17.28 13.02 -4.26 -0.115 0.72722E+04 86 graphite -3.55 -7.92 -4.37 -1.250 0.74688E+04 87 greenalite 16.14 13.78 -2.36 -0.196 0.40211E+04 90 hematite 12.57 9.65 -2.92 -0.354 0.49857E+04 91 heulandite -5.83 -7.52 -1.69 -0.077 0.28938E+04 95 jadeite 4.22 2.79 -1.42 -0.142 0.24290E+04 97 kalsilite 7.58 3.87 -3.72 -0.531 0.63471E+04 98 kaolinite -1.33 -4.56 -3.23 -0.293 0.55096E+04 101 laumontite 2.88 2.01 -0.88 -0.058 0.14953E+04 102 lawsonite 9.62 8.36 -1.26 -0.084 0.21434E+04 103 leucite 4.12 0.69 -3.43 -0.343 0.58546E+04 105 lizardite 23.24 21.35 -1.89 -0.158 0.32304E+04 107 magnetite 20.09 16.36 -3.73 -0.304 0.63665E+04 108 minnesotaite 10.39 7.43 -2.96 -0.174 0.50486E+04 112 manganosite 14.06 9.13 -4.92 -1.231 0.84074E+04 120 muscovite 2.58 -0.69 -3.28 -0.193 0.55925E+04 121 paragonite 4.24 1.41 -2.83 -0.166 0.48316E+04 122 nepheline 8.34 5.97 -2.37 -0.339 0.40470E+04 128 periclase-Fe 11.63 6.71 -4.91 -1.229 0.83906E+04 134 phlogopite-Na 29.65 27.32 -2.33 -0.129 0.39708E+04 136 prehnite 19.37 18.10 -1.27 -0.075 0.21639E+04 137 prehnite-Fe 22.50 22.03 -0.47 -0.028 0.79735E+03 138 pumpellyite-Fe 46.27 43.82 -2.45 -0.054 0.41850E+04 139 pumpellyite-Mg 48.99 46.34 -2.65 -0.059 0.45315E+04 143 pyrrhotite -4.26 -8.04 -3.78 -1.258 0.64457E+04 144 pyrrhotiteFe0.875 -6.02 -9.34 -3.33 -1.223 0.56791E+04 145 pyroxmangite 7.40 5.96 -1.44 -0.288 0.24605E+04 146 pyrophyllite -6.18 -10.91 -4.74 -0.296 0.80881E+04 147 quartz -2.99 -3.18 -0.19 -0.062 0.31953E+03 152 rhodonite 7.45 5.96 -1.49 -0.298 0.25408E+04 153 sanidine -1.28 -2.49 -1.21 -0.093 0.20677E+04 165 stilpnomelane-Mg 27.44 25.63 -1.81 -0.054 0.30939E+04 171 talc 16.49 15.00 -1.49 -0.088 0.25480E+04 174 tephroite 18.09 15.09 -2.99 -0.428 0.51120E+04 178 tridymite -2.63 -3.18 -0.55 -0.183 0.93950E+03 179 tremolite 47.87 46.60 -1.27 -0.034 0.21617E+04 180 ferroactinolite 38.45 33.99 -4.46 -0.121 0.76180E+04 181 troilite-low -4.41 -8.04 -3.62 -1.208 0.61885E+04 187 wairakite 3.95 2.01 -1.94 -0.114 0.33173E+04 188 walstromite 11.51 9.74 -1.77 -0.353 0.30145E+04 189 wollastonite 10.46 9.74 -0.72 -0.143 0.12249E+04 190 pseudo-wollastonite 11.00 9.74 -1.26 -0.251 0.21447E+04 191 zoisite 22.85 19.00 -3.85 -0.175 0.65704E+04 192 akaganeite 7.75 4.82 -2.93 -0.634 0.50054E+04 199 chalcedony -2.80 -3.18 -0.37 -0.125 0.63882E+03 201 montmorillonite-Ca -2.29 -6.03 -3.74 -0.231 0.63834E+04 202 montmorillonite-K -2.24 -6.13 -3.90 -0.239 0.66524E+04 203 montmorillonite-Mg -2.48 -6.64 -4.16 -0.257 0.70987E+04 204 montmorillonite-Na -2.04 -5.44 -3.40 -0.208 0.58072E+04 205 nontronite-Ca 3.21 0.42 -2.80 -0.182 0.47783E+04 206 nontronite-H 2.53 -1.72 -4.25 -0.285 0.72542E+04 207 nontronite-K 3.34 0.31 -3.03 -0.194 0.51705E+04 208 nontronite-Mg 3.07 -0.19 -3.27 -0.212 0.55777E+04 209 nontronite-Na 3.52 1.01 -2.51 -0.161 0.42914E+04 224 tobermorite 9.82 7.59 -2.24 -0.610 0.38196E+04 230 alabandite -0.98 -5.61 -4.64 -1.545 0.79154E+04 233 boehmite 4.41 0.90 -3.51 -0.585 0.59924E+04 235 ferrous-oxide 9.81 6.71 -3.10 -0.775 0.52915E+04 240 silica-amorphous -2.09 -3.18 -1.09 -0.362 0.18530E+04 242 an20ab80 2.02 1.37 -0.65 -0.050 0.11145E+04 243 an25ab75 2.65 1.80 -0.84 -0.065 0.14401E+04 244 an30ab70 3.28 2.24 -1.04 -0.080 0.17753E+04 245 tr.625ac.25prg.125 45.16 44.46 -0.71 -0.019 0.12079E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 4.0000000 g Current total amount of reactant added: 79.9990000 g New total amount of reactant added: 83.9990000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.7403E-13 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 10 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 83.9990000 Water: Moles liquid = 0.5496E+02 kg liquid = 0.9902E+00 Moles total = 0.5446E+02 kg total = 0.9810E+00 Activity = 1.0000 Stoichiometric ionic strength = .1009856E-01 Osmotic coef. = 0.9640 True ionic strength = .1799592E-01 Chg. balance for total moles = -.7403E-13 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.95632E-10 -10.0194 0.80883E-10 -10.0921 0.84577E+00 -0.0727 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13877E-03 -3.8577 0.11671E-03 -3.9329 0.84109E+00 -0.0752 4 SO4-- 0.11775E-09 -9.9290 0.62844E-10 -10.2017 0.53370E+00 -0.2727 5 HCO3- 0.44129E-05 -5.3553 0.37166E-05 -5.4298 0.84222E+00 -0.0746 6 HS- 0.25753E-04 -4.5892 0.21663E-04 -4.6643 0.84120E+00 -0.0751 7 Al+++ 0.15446E-28 -28.8112 0.37989E-29 -29.4203 0.24595E+00 -0.6092 8 H4SiO4 0.67689E-03 -3.1695 0.67689E-03 -3.1695 0.10000E+01 0.0000 9 Ca++ 0.11053E-06 -6.9565 0.58594E-07 -7.2321 0.53010E+00 -0.2756 10 Mg++ 0.22029E-10 -10.6570 0.11628E-10 -10.9345 0.52787E+00 -0.2775 11 Fe++ 0.64311E-13 -13.1917 0.33982E-13 -13.4687 0.52840E+00 -0.2770 12 K+ 0.14067E-03 -3.8518 0.11850E-03 -3.9263 0.84241E+00 -0.0745 13 Na+ 0.17847E-01 -1.7484 0.15009E-01 -1.8237 0.84095E+00 -0.0752 14 Mn++ 0.17435E-10 -10.7586 0.92196E-11 -11.0353 0.52881E+00 -0.2767 15 HPO4-- 0.65898E-07 -7.1811 0.35174E-07 -7.4538 0.53377E+00 -0.2726 16 HSiO3- 0.92906E-02 -2.0320 0.78143E-02 -2.1071 0.84109E+00 -0.0752 17 Ca(HSiO3)+ 0.12376E-07 -7.9074 0.10427E-07 -7.9818 0.84257E+00 -0.0744 18 Mg(HSiO3)+ 0.30566E-11 -11.5148 0.25754E-11 -11.5892 0.84257E+00 -0.0744 19 NaHSiO3,aq 0.18969E-02 -2.7220 0.18969E-02 -2.7220 0.10000E+01 0.0000 20 AlO+ 0.93760E-16 -16.0280 0.79000E-16 -16.1024 0.84257E+00 -0.0744 22 HAlO2,aq 0.19451E-09 -9.7111 0.19451E-09 -9.7111 0.10000E+01 0.0000 23 AlO2- 0.63396E-05 -5.1979 0.53234E-05 -5.2738 0.83969E+00 -0.0759 24 CH4,aq 0.12484E-05 -5.9037 0.12445E-05 -5.9050 0.99691E+00 -0.0013 25 C2H6,aq 0.86265E-16 -16.0642 0.85999E-16 -16.0655 0.99691E+00 -0.0013 29 CO,aq 0.49680E-16 -16.3038 0.49680E-16 -16.3038 0.10000E+01 0.0000 30 CO2,aq 0.64433E-09 -9.1909 0.64234E-09 -9.1922 0.99691E+00 -0.0013 31 CO3-2 0.75351E-05 -5.1229 0.40136E-05 -5.3965 0.53266E+00 -0.2736 32 CaCO3,aq 0.29488E-08 -8.5303 0.29488E-08 -8.5303 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.65975E-11 -11.1806 0.55589E-11 -11.2550 0.84257E+00 -0.0744 34 CaCl+ 0.13135E-10 -10.8816 0.11067E-10 -10.9560 0.84257E+00 -0.0744 35 CaCl2,aq 0.30688E-15 -15.5130 0.30688E-15 -15.5130 0.10000E+01 0.0000 36 CaOH+ 0.61276E-07 -7.2127 0.51630E-07 -7.2871 0.84257E+00 -0.0744 37 CaSO4,aq 0.11693E-14 -14.9321 0.11693E-14 -14.9321 0.10000E+01 0.0000 38 HCl,aq 0.17299E-14 -14.7620 0.17299E-14 -14.7620 0.10000E+01 0.0000 43 FeCl+ 0.74509E-17 -17.1278 0.62779E-17 -17.2022 0.84257E+00 -0.0744 46 FeO,aq 0.20189E-09 -9.6949 0.20189E-09 -9.6949 0.10000E+01 0.0000 47 FeOH+ 0.16231E-10 -10.7896 0.13676E-10 -10.8640 0.84257E+00 -0.0744 48 HFeO2- 0.31051E-07 -7.5079 0.26116E-07 -7.5831 0.84109E+00 -0.0752 49 FeO+ 0.22064E-16 -16.6563 0.18591E-16 -16.7307 0.84257E+00 -0.0744 51 FeO2- 0.69134E-09 -9.1603 0.58148E-09 -9.2355 0.84109E+00 -0.0752 52 HFeO2,aq 0.59817E-11 -11.2232 0.59817E-11 -11.2232 0.10000E+01 0.0000 53 H2,aq 0.30883E-05 -5.5103 0.30788E-05 -5.5116 0.99691E+00 -0.0013 54 KCl,aq 0.25067E-09 -9.6009 0.25067E-09 -9.6009 0.10000E+01 0.0000 56 KOH,aq 0.62567E-06 -6.2037 0.62567E-06 -6.2037 0.10000E+01 0.0000 57 KSO4- 0.13739E-12 -12.8620 0.11556E-12 -12.9372 0.84109E+00 -0.0752 58 MgCO3,aq 0.14669E-12 -12.8336 0.14669E-12 -12.8336 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.13379E-14 -14.8736 0.11273E-14 -14.9480 0.84257E+00 -0.0744 60 MgCl+ 0.23626E-14 -14.6266 0.19907E-14 -14.7010 0.84257E+00 -0.0744 61 MgOH+ 0.67291E-10 -10.1720 0.56698E-10 -10.2464 0.84257E+00 -0.0744 63 MnO,aq 0.14595E-08 -8.8358 0.14595E-08 -8.8358 0.10000E+01 0.0000 64 MnOH+ 0.40909E-09 -9.3882 0.34469E-09 -9.4626 0.84257E+00 -0.0744 65 MnO2-2 0.13900E-10 -10.8570 0.74038E-11 -11.1305 0.53266E+00 -0.2736 66 HMnO2- 0.15598E-09 -9.8069 0.13120E-09 -9.8821 0.84109E+00 -0.0752 69 MnCl+ 0.78644E-14 -14.1043 0.66264E-14 -14.1787 0.84257E+00 -0.0744 70 MnSO4,aq 0.16727E-18 -18.7766 0.16727E-18 -18.7766 0.10000E+01 0.0000 71 NaCl,aq 0.58053E-06 -6.2362 0.58053E-06 -6.2362 0.10000E+01 0.0000 72 NaOH,aq 0.79726E-04 -4.0984 0.79726E-04 -4.0984 0.10000E+01 0.0000 74 OH- 0.85071E-02 -2.0702 0.71434E-02 -2.1461 0.83969E+00 -0.0759 79 HPO3-2 0.63359E-15 -15.1982 0.33748E-15 -15.4717 0.53266E+00 -0.2736 81 H2PO3- 0.65079E-19 -19.1866 0.54738E-19 -19.2617 0.84109E+00 -0.0752 82 H3PO4,aq 0.16094E-17 -17.7933 0.16094E-17 -17.7933 0.10000E+01 0.0000 83 H2PO4- 0.62343E-10 -10.2052 0.52482E-10 -10.2800 0.84182E+00 -0.0748 84 PO4-3 0.13790E-08 -8.8604 0.35481E-09 -9.4500 0.25729E+00 -0.5896 88 HP2O7-3 0.21659E-17 -17.6644 0.53317E-18 -18.2731 0.24617E+00 -0.6088 89 P2O7-4 0.18317E-16 -16.7371 0.15748E-17 -17.8028 0.85974E-01 -1.0656 90 H2S,aq 0.54321E-08 -8.2650 0.54153E-08 -8.2664 0.99691E+00 -0.0013 91 S2-2 0.63409E-14 -14.1979 0.33775E-14 -14.4714 0.53266E+00 -0.2736 97 SO3-2 0.46585E-16 -16.3318 0.25143E-16 -16.5996 0.53974E+00 -0.2678 98 HSO3- 0.15139E-18 -18.8199 0.12733E-18 -18.8951 0.84109E+00 -0.0752 99 HSO4- 0.58087E-17 -17.2359 0.48986E-17 -17.3099 0.84332E+00 -0.0740 Charge balance for all species = -.7676E-13 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.9563227E-10 -.1980876E-01 -.1993535E+02 0.0000 2 H2O 0.1000000E+01 0.5550567E+02 0.9984141E+06 0.0000 3 Cl- 0.1387659E-03 0.1393467E-03 0.4932663E+01 6.1593 4 SO4-- 0.1177529E-09 -.2020239E-05 -.1937690E+00 9.9826 5 HCO3- 0.4412906E-05 0.1320001E-04 0.8041898E+00 4.6623 6 HS- 0.2575263E-04 0.2777841E-04 0.9172755E+00 5.4279 7 Al+++ 0.1544596E-28 0.6339841E-05 0.1707955E+00 0.8561 8 H4SiO4 0.6768882E-03 0.1186438E-01 0.1138597E+04 -3.1695 9 Ca++ 0.1105334E-06 0.1871539E-06 0.7489223E-02 12.9521 10 Mg++ 0.2202869E-10 0.9252678E-10 0.2246053E-05 9.2498 11 Fe++ 0.6431139E-13 0.3196608E-07 0.1782465E-02 6.7155 12 K+ 0.1406675E-03 0.1412934E-03 0.5516362E+01 6.1659 13 Na+ 0.1784724E-01 0.1982443E-01 0.4550590E+03 8.2685 14 Mn++ 0.1743482E-10 0.2055884E-08 0.1127725E-03 9.1490 15 HPO4-- 0.6589797E-07 0.6733933E-07 0.6453226E-02 12.7305 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.1390886E+01 -.1961366E-01 -.1371272E+01 0.0000000E+00 2 H2O 0.5445529E+02 0.5495896E+02 -.5036760E+00 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.2353403E-02 -.2000340E-05 0.2355403E-02 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.2327899E-02 0.2750481E-04 -.2355403E-02 0.0000000E+00 7 Al+++ 0.2738990E+00 0.6277397E-05 0.2738928E+00 0.0000000E+00 8 H4SiO4 0.8746634E+00 0.1174753E-01 0.8629158E+00 0.0000000E+00 9 Ca++ 0.9662530E-01 0.1853105E-06 0.9662512E-01 0.0000000E+00 10 Mg++ 0.6666587E-01 0.9161544E-10 0.6666587E-01 0.0000000E+00 11 Fe++ 0.5989201E-01 0.3165123E-07 0.5989198E-01 0.0000000E+00 12 K+ 0.1783418E-01 0.1399017E-03 0.1769428E-01 0.0000000E+00 13 Na+ 0.1055993E+00 0.1962916E-01 0.8597012E-01 0.0000000E+00 14 Mn++ 0.1456425E-02 0.2035634E-08 0.1456423E-02 0.0000000E+00 15 HPO4-- 0.4970705E-03 0.6667607E-07 0.4970038E-03 0.0000000E+00 Chg. balance for solid moles: 0.1414E-15 Mass of aqueous solution: 0.991675E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 83.9990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 0.8597E-01 -1.066 22.54 1.353 24.60 8.654 andradite 0.9422E-02 -2.026 4.788 0.680 5.224 1.244 grossular 0.1611E-02 -2.793 0.7256 -0.139 0.7916 0.2019 apatite-OH 0.1657E-03 -3.781 0.8322E-01 -1.080 0.9080E-01 0.2644E-01 clinochlore 0.1333E-01 -1.875 7.411 0.870 8.086 2.819 daphnite 0.4088E-02 -2.388 2.917 0.465 3.183 0.8839 chlorite-Mn 0.2913E-03 -3.536 0.2065 -0.685 0.2253 0.6581E-01 microcline 0.1563E-01 -1.806 4.351 0.639 4.748 1.700 stilbite 0.6270E-01 -1.203 44.19 1.645 48.21 20.61 stilpnomelane-Fe 0.4122E-02 -2.385 4.443 0.648 4.848 1.535 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8540E+00 0.8540E+00 1.0000 -0.069 grossular 0.1460E+00 0.1460E+00 1.0000 -0.836 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.7528E+00 0.7528E+00 1.0000 -0.123 daphnite 0.2308E+00 0.2308E+00 1.0000 -0.637 chlorite-Mn 0.1645E-01 0.1645E-01 1.0000 -1.784 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 91.654297 g Volume = 37.738180 cm3 Porosity: -9.0711% V(tot) - V(min): -.31386E+01 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 83.9990000 g log = 1.9243 Original solution: 1000.0103000 g Original solution / Rock added: 11.91 (Water/Rock Ratio), log = 1.0757 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0262 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9943E+00 0.9859 0.1006E+01 0.1020E+01 CO2,gas 0.6649E-07 1.0071 0.6872E-07 0.6824E-07 CH4,gas 0.1763E-02 1.0126 0.1832E-02 0.1809E-02 H2,gas 0.3937E-02 1.0005 0.4042E-02 0.4040E-02 H2S,gas 0.1456E-06 0.9960 0.1489E-06 0.1495E-06 S2,gas 0.4961E-28 1.0000 0.5091E-28 0.5091E-28 CO,gas 0.7214E-13 1.0000 0.7403E-13 0.7403E-13 SO3,gas 0.1515E-45 1.0000 0.1554E-45 0.1554E-45 SO2,gas 0.2382E-25 1.0000 0.2445E-25 0.2445E-25 HCl,gas 0.2974E-17 1.0000 0.3052E-17 0.3052E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 16 albite -0.38 -0.38 0.00 0.000 -0.94784E-12 22 andradite 39.01 39.01 0.00 0.000 0.12132E-10 23 grossular 32.73 32.73 0.00 0.000 -0.24265E-10 32 apatite-OH -18.15 -18.15 0.00 0.000 0.00000E+00 46 clinochlore 39.07 39.07 0.00 0.000 -0.24265E-10 47 daphnite 28.97 28.97 0.00 0.000 -0.12132E-10 48 chlorite-Mn 46.87 46.87 0.00 0.000 -0.36397E-10 116 microcline -2.49 -2.49 0.00 0.000 0.15165E-11 163 stilbite -7.52 -7.52 0.00 0.000 -0.33364E-10 164 stilpnomelane-Fe 13.02 13.02 0.00 0.000 0.21232E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -15.52 -8.86 -2.954 0.15131E+05 -7.163 3 CH4,gas 4.54 0.11 -4.44 -1.109 0.75745E+04 -2.737 4 H2,gas 8.00 3.91 -4.09 -2.338 0.69876E+04 -2.393 5 H2S,gas -6.23 -14.76 -8.53 -4.263 0.14558E+05 -6.827 6 S2,gas -7.34 -37.33 -29.99 -4.614 0.51211E+05 -28.293 7 CO,gas 3.21 -11.61 -14.83 -4.563 0.25321E+05 -13.131 8 SO3,gas 17.12 -30.39 -47.51 -11.877 0.81118E+05 -45.808 9 SO2,gas 0.83 -26.48 -27.31 -7.283 0.46632E+05 -25.612 10 HCl,gas 5.19 -14.03 -19.21 -9.607 0.32808E+05 -17.515 11 acmite 7.71 6.69 -1.02 -0.106 0.17388E+04 15 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 19 spessartine 24.46 19.65 -4.81 -0.240 0.82071E+04 20 analcite 3.32 2.79 -0.54 -0.060 0.91562E+03 26 annite 20.12 17.66 -2.46 -0.137 0.42060E+04 27 phlogopite 27.06 25.26 -1.80 -0.100 0.30763E+04 29 anorthite 12.71 8.33 -4.38 -0.337 0.74872E+04 35 aragonite 0.97 -2.57 -3.54 -1.179 0.60383E+04 36 brucite 12.57 9.25 -3.32 -0.664 0.56667E+04 37 calcite 0.81 -2.57 -3.38 -1.127 0.57740E+04 38 carnegieite-low 9.02 5.96 -3.07 -0.438 0.52389E+04 39 carnegieite-high 10.09 5.96 -4.14 -0.591 0.70659E+04 40 carpholite-Mg 8.58 4.62 -3.96 -0.264 0.67600E+04 41 carpholite-Fe 6.71 2.09 -4.62 -0.308 0.78951E+04 42 celadonite 5.34 3.59 -1.75 -0.103 0.29843E+04 43 celadonite-Fe 3.88 1.06 -2.82 -0.166 0.48099E+04 44 chrysotile 23.89 21.41 -2.48 -0.207 0.42378E+04 49 chlorite-Al-free 47.17 42.82 -4.35 -0.181 0.74308E+04 51 chloritoid-Fe 9.17 5.26 -3.92 -0.261 0.66854E+04 52 chloritoid-Mn 11.40 7.69 -3.71 -0.247 0.63336E+04 54 coesite -2.38 -3.17 -0.79 -0.264 0.13547E+04 61 cristobalite -2.56 -3.17 -0.61 -0.203 0.10401E+04 63 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71234E+04 65 diaspore 2.87 0.86 -2.02 -0.336 0.34450E+04 66 diamond -3.10 -7.71 -4.60 -1.316 0.78626E+04 67 diopside 16.18 15.86 -0.32 -0.032 0.54362E+03 68 hedenbergite 14.21 13.33 -0.88 -0.088 0.15018E+04 75 epidote 24.67 22.87 -1.80 -0.087 0.30735E+04 76 clinozoisite 22.81 18.96 -3.84 -0.175 0.65600E+04 77 epidote-Fe 29.84 26.78 -3.07 -0.159 0.52337E+04 78 fayalite 14.05 10.26 -3.78 -0.541 0.64613E+04 79 ferrosilite 11.15 7.09 -4.06 -0.406 0.69278E+04 83 gibbsite 4.08 0.86 -3.22 -0.460 0.55035E+04 84 glaucophane 22.97 20.64 -2.33 -0.063 0.39820E+04 85 glaucophane-Fe 17.28 13.04 -4.24 -0.114 0.72327E+04 86 graphite -3.55 -7.71 -4.16 -1.189 0.71048E+04 87 greenalite 16.14 13.81 -2.33 -0.194 0.39816E+04 90 hematite 12.57 9.52 -3.04 -0.369 0.51950E+04 91 heulandite -5.83 -7.52 -1.69 -0.077 0.28938E+04 95 jadeite 4.22 2.79 -1.43 -0.143 0.24411E+04 97 kalsilite 7.58 3.85 -3.73 -0.533 0.63713E+04 98 kaolinite -1.33 -4.63 -3.29 -0.299 0.56244E+04 101 laumontite 2.88 1.99 -0.90 -0.060 0.15316E+04 102 lawsonite 9.62 8.33 -1.29 -0.086 0.22039E+04 103 leucite 4.12 0.68 -3.44 -0.344 0.58667E+04 105 lizardite 23.24 21.41 -1.83 -0.153 0.31305E+04 107 magnetite 20.09 16.24 -3.85 -0.314 0.65706E+04 108 minnesotaite 10.39 7.47 -2.92 -0.172 0.49848E+04 112 manganosite 14.06 9.15 -4.91 -1.227 0.83822E+04 120 muscovite 2.58 -0.77 -3.36 -0.197 0.57315E+04 121 paragonite 4.24 1.33 -2.91 -0.171 0.49706E+04 122 nepheline 8.34 5.96 -2.38 -0.341 0.40712E+04 128 periclase-Fe 11.63 6.72 -4.91 -1.228 0.83855E+04 134 phlogopite-Na 29.65 27.37 -2.28 -0.127 0.38951E+04 136 prehnite 19.37 18.11 -1.26 -0.074 0.21580E+04 137 prehnite-Fe 22.50 22.01 -0.48 -0.029 0.82658E+03 138 pumpellyite-Fe 46.27 43.79 -2.48 -0.055 0.42375E+04 139 pumpellyite-Mg 48.99 46.32 -2.67 -0.059 0.45640E+04 143 pyrrhotite -4.26 -8.04 -3.78 -1.260 0.64552E+04 144 pyrrhotiteFe0.875 -6.02 -9.36 -3.35 -1.231 0.57164E+04 145 pyroxmangite 7.40 5.98 -1.42 -0.284 0.24232E+04 146 pyrophyllite -6.18 -10.97 -4.79 -0.299 0.81787E+04 147 quartz -2.99 -3.17 -0.18 -0.060 0.30743E+03 152 rhodonite 7.45 5.98 -1.47 -0.293 0.25034E+04 153 sanidine -1.28 -2.49 -1.21 -0.093 0.20677E+04 165 stilpnomelane-Mg 27.44 25.69 -1.75 -0.052 0.29934E+04 171 talc 16.49 15.07 -1.42 -0.084 0.24239E+04 174 tephroite 18.09 15.13 -2.96 -0.422 0.50495E+04 178 tridymite -2.63 -3.17 -0.54 -0.181 0.92740E+03 179 tremolite 47.87 46.80 -1.07 -0.029 0.18301E+04 180 ferroactinolite 38.45 34.13 -4.33 -0.117 0.73869E+04 181 troilite-low -4.41 -8.04 -3.63 -1.210 0.61980E+04 187 wairakite 3.95 1.99 -1.96 -0.116 0.33536E+04 188 walstromite 11.51 9.78 -1.73 -0.345 0.29481E+04 189 wollastonite 10.46 9.78 -0.68 -0.136 0.11585E+04 190 pseudo-wollastonite 11.00 9.78 -1.22 -0.243 0.20783E+04 191 zoisite 22.85 18.96 -3.89 -0.177 0.66340E+04 192 akaganeite 7.75 4.76 -2.99 -0.647 0.51100E+04 199 chalcedony -2.80 -3.17 -0.37 -0.122 0.62672E+03 201 montmorillonite-Ca -2.29 -6.06 -3.77 -0.233 0.64338E+04 202 montmorillonite-K -2.24 -6.16 -3.92 -0.240 0.67007E+04 203 montmorillonite-Mg -2.48 -6.67 -4.19 -0.259 0.71538E+04 204 montmorillonite-Na -2.04 -5.47 -3.43 -0.210 0.58556E+04 205 nontronite-Ca 3.21 0.31 -2.90 -0.188 0.49572E+04 206 nontronite-H 2.53 -1.83 -4.36 -0.292 0.74420E+04 207 nontronite-K 3.34 0.21 -3.13 -0.201 0.53474E+04 208 nontronite-Mg 3.07 -0.30 -3.37 -0.219 0.57614E+04 209 nontronite-Na 3.52 0.90 -2.62 -0.168 0.44683E+04 224 tobermorite 9.82 7.62 -2.20 -0.601 0.37622E+04 230 alabandite -0.98 -5.61 -4.63 -1.543 0.79048E+04 233 boehmite 4.41 0.86 -3.55 -0.592 0.60619E+04 235 ferrous-oxide 9.81 6.72 -3.10 -0.774 0.52864E+04 240 silica-amorphous -2.09 -3.17 -1.08 -0.359 0.18409E+04 242 an20ab80 2.02 1.36 -0.66 -0.051 0.11266E+04 243 an25ab75 2.65 1.79 -0.85 -0.066 0.14552E+04 244 an30ab70 3.28 2.23 -1.05 -0.081 0.17934E+04 245 tr.625ac.25prg.125 45.16 44.62 -0.54 -0.015 0.92951E+03 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 4.0000000 g Current total amount of reactant added: 83.9990000 g New total amount of reactant added: 87.9990000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.7396E-13 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 10 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 87.9990000 Water: Moles liquid = 0.5494E+02 kg liquid = 0.9897E+00 Moles total = 0.5441E+02 kg total = 0.9801E+00 Activity = 1.0000 Stoichiometric ionic strength = .1038959E-01 Osmotic coef. = 0.9645 True ionic strength = .1847211E-01 Chg. balance for total moles = -.7396E-13 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.94207E-10 -10.0259 0.79551E-10 -10.0994 0.84443E+00 -0.0734 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13881E-03 -3.8576 0.11656E-03 -3.9335 0.83966E+00 -0.0759 4 SO4-- 0.40790E-10 -10.3894 0.21626E-10 -10.6650 0.53018E+00 -0.2756 5 HCO3- 0.37039E-05 -5.4313 0.31143E-05 -5.5066 0.84081E+00 -0.0753 6 HS- 0.25764E-04 -4.5890 0.21636E-04 -4.6648 0.83978E+00 -0.0758 7 Al+++ 0.13653E-28 -28.8648 0.33075E-29 -29.4805 0.24225E+00 -0.6157 8 H4SiO4 0.68772E-03 -3.1626 0.68772E-03 -3.1626 0.10000E+01 0.0000 9 Ca++ 0.11503E-06 -6.9392 0.60565E-07 -7.2178 0.52653E+00 -0.2786 10 Mg++ 0.22150E-10 -10.6546 0.11613E-10 -10.9351 0.52427E+00 -0.2804 11 Fe++ 0.63012E-13 -13.2006 0.33069E-13 -13.4806 0.52481E+00 -0.2800 12 K+ 0.14439E-03 -3.8404 0.12144E-03 -3.9157 0.84100E+00 -0.0752 13 Na+ 0.18321E-01 -1.7371 0.15381E-01 -1.8130 0.83952E+00 -0.0760 14 Mn++ 0.17531E-10 -10.7562 0.92073E-11 -11.0359 0.52522E+00 -0.2797 15 HPO4-- 0.61401E-07 -7.2118 0.32558E-07 -7.4873 0.53025E+00 -0.2755 16 HSiO3- 0.96136E-02 -2.0171 0.80722E-02 -2.0930 0.83966E+00 -0.0759 17 Ca(HSiO3)+ 0.13236E-07 -7.8782 0.11134E-07 -7.9534 0.84117E+00 -0.0751 18 Mg(HSiO3)+ 0.31585E-11 -11.5005 0.26568E-11 -11.5756 0.84117E+00 -0.0751 19 NaHSiO3,aq 0.20080E-02 -2.6972 0.20080E-02 -2.6972 0.10000E+01 0.0000 20 AlO+ 0.84530E-16 -16.0730 0.71104E-16 -16.1481 0.84117E+00 -0.0751 22 HAlO2,aq 0.17800E-09 -9.7496 0.17800E-09 -9.7496 0.10000E+01 0.0000 23 AlO2- 0.59090E-05 -5.2285 0.49531E-05 -5.3051 0.83824E+00 -0.0766 24 CH4,aq 0.30363E-05 -5.5177 0.30266E-05 -5.5190 0.99683E+00 -0.0014 25 C2H6,aq 0.38932E-15 -15.4097 0.38808E-15 -15.4111 0.99683E+00 -0.0014 29 CO,aq 0.53662E-16 -16.2703 0.53662E-16 -16.2703 0.10000E+01 0.0000 30 CO2,aq 0.53106E-09 -9.2749 0.52938E-09 -9.2762 0.99683E+00 -0.0014 31 CO3-2 0.64626E-05 -5.1896 0.34195E-05 -5.4660 0.52912E+00 -0.2764 32 CaCO3,aq 0.25968E-08 -8.5856 0.25968E-08 -8.5856 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.57238E-11 -11.2423 0.48147E-11 -11.3174 0.84117E+00 -0.0751 34 CaCl+ 0.13581E-10 -10.8671 0.11424E-10 -10.9422 0.84117E+00 -0.0751 35 CaCl2,aq 0.31635E-15 -15.4998 0.31635E-15 -15.4998 0.10000E+01 0.0000 36 CaOH+ 0.64506E-07 -7.1904 0.54260E-07 -7.2655 0.84117E+00 -0.0751 37 CaSO4,aq 0.41592E-15 -15.3810 0.41592E-15 -15.3810 0.10000E+01 0.0000 38 HCl,aq 0.16991E-14 -14.7698 0.16991E-14 -14.7698 0.10000E+01 0.0000 43 FeCl+ 0.72530E-17 -17.1395 0.61010E-17 -17.2146 0.84117E+00 -0.0751 46 FeO,aq 0.20310E-09 -9.6923 0.20310E-09 -9.6923 0.10000E+01 0.0000 47 FeOH+ 0.16087E-10 -10.7935 0.13532E-10 -10.8687 0.84117E+00 -0.0751 48 HFeO2- 0.31814E-07 -7.4974 0.26713E-07 -7.5733 0.83966E+00 -0.0759 49 FeO+ 0.19101E-16 -16.7189 0.16067E-16 -16.7941 0.84117E+00 -0.0751 51 FeO2- 0.61872E-09 -9.2085 0.51951E-09 -9.2844 0.83966E+00 -0.0759 52 HFeO2,aq 0.52563E-11 -11.2793 0.52563E-11 -11.2793 0.10000E+01 0.0000 53 H2,aq 0.40481E-05 -5.3927 0.40353E-05 -5.3941 0.99683E+00 -0.0014 54 KCl,aq 0.25653E-09 -9.5909 0.25653E-09 -9.5909 0.10000E+01 0.0000 56 KOH,aq 0.65191E-06 -6.1858 0.65191E-06 -6.1858 0.10000E+01 0.0000 57 KSO4- 0.48534E-13 -13.3140 0.40752E-13 -13.3899 0.83966E+00 -0.0759 58 MgCO3,aq 0.12481E-12 -12.9038 0.12481E-12 -12.9038 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.11214E-14 -14.9502 0.94331E-15 -15.0253 0.84117E+00 -0.0751 60 MgCl+ 0.23602E-14 -14.6271 0.19853E-14 -14.7022 0.84117E+00 -0.0751 61 MgOH+ 0.68440E-10 -10.1647 0.57570E-10 -10.2398 0.84117E+00 -0.0751 63 MnO,aq 0.15067E-08 -8.8220 0.15067E-08 -8.8220 0.10000E+01 0.0000 64 MnOH+ 0.41607E-09 -9.3808 0.34999E-09 -9.4559 0.84117E+00 -0.0751 65 MnO2-2 0.14934E-10 -10.8258 0.79017E-11 -11.1023 0.52912E+00 -0.2764 66 HMnO2- 0.16401E-09 -9.7851 0.13771E-09 -9.8610 0.83966E+00 -0.0759 69 MnCl+ 0.78564E-14 -14.1048 0.66086E-14 -14.1799 0.84117E+00 -0.0751 70 MnSO4,aq 0.57484E-19 -19.2405 0.57484E-19 -19.2405 0.10000E+01 0.0000 71 NaCl,aq 0.59411E-06 -6.2261 0.59411E-06 -6.2261 0.10000E+01 0.0000 72 NaOH,aq 0.83070E-04 -4.0806 0.83070E-04 -4.0806 0.10000E+01 0.0000 74 OH- 0.86646E-02 -2.0623 0.72630E-02 -2.1389 0.83824E+00 -0.0766 79 HPO3-2 0.77378E-15 -15.1114 0.40943E-15 -15.3878 0.52912E+00 -0.2764 81 H2PO3- 0.77785E-19 -19.1091 0.65313E-19 -19.1850 0.83966E+00 -0.0759 82 H3PO4,aq 0.14410E-17 -17.8413 0.14410E-17 -17.8413 0.10000E+01 0.0000 83 H2PO4- 0.56852E-10 -10.2453 0.47779E-10 -10.3208 0.84041E+00 -0.0755 84 PO4-3 0.13164E-08 -8.8806 0.33392E-09 -9.4764 0.25367E+00 -0.5957 88 HP2O7-3 0.18529E-17 -17.7321 0.44928E-18 -18.3475 0.24247E+00 -0.6153 89 P2O7-4 0.16112E-16 -16.7928 0.13492E-17 -17.8699 0.83739E-01 -1.0771 90 H2S,aq 0.53364E-08 -8.2727 0.53195E-08 -8.2741 0.99683E+00 -0.0014 91 S2-2 0.48581E-14 -14.3135 0.25705E-14 -14.5900 0.52912E+00 -0.2764 97 SO3-2 0.21145E-16 -16.6748 0.11340E-16 -16.9454 0.53630E+00 -0.2706 98 HSO3- 0.67271E-19 -19.1722 0.56484E-19 -19.2481 0.83966E+00 -0.0759 99 HSO4- 0.19692E-17 -17.7057 0.16579E-17 -17.7804 0.84194E+00 -0.0747 Charge balance for all species = -.7864E-13 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.9420659E-10 -.2040124E-01 -.2053058E+02 0.0000 2 H2O 0.1000000E+01 0.5550540E+02 0.9983586E+06 0.0000 3 Cl- 0.1388145E-03 0.1394089E-03 0.4934614E+01 6.1659 4 SO4-- 0.4079011E-10 -.4048163E-05 -.3882555E+00 9.5337 5 HCO3- 0.3703934E-05 0.1320590E-04 0.8045078E+00 4.5927 6 HS- 0.2576429E-04 0.2981783E-04 0.9845695E+00 5.4345 7 Al+++ 0.1365323E-28 0.5909147E-05 0.1591845E+00 0.8176 8 H4SiO4 0.6877156E-03 0.1230940E-01 0.1181244E+04 -3.1626 9 Ca++ 0.1150271E-06 0.1953853E-06 0.7818217E-02 12.9809 10 Mg++ 0.2215041E-10 0.9387744E-10 0.2278724E-05 9.2636 11 Fe++ 0.6301236E-13 0.3265710E-07 0.1820905E-02 6.7181 12 K+ 0.1443943E-03 0.1450465E-03 0.5662602E+01 6.1837 13 Na+ 0.1832076E-01 0.2041247E-01 0.4685335E+03 8.2863 14 Mn++ 0.1753051E-10 0.2119294E-08 0.1162449E-03 9.1628 15 HPO4-- 0.6140117E-07 0.6277439E-07 0.6015456E-02 12.7114 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.1457120E+01 -.2019129E-01 -.1436928E+01 0.0000000E+00 2 H2O 0.5440515E+02 0.5493418E+02 -.5290330E+00 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.2464257E-02 -.4006502E-05 0.2468263E-02 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.2438752E-02 0.2951097E-04 -.2468263E-02 0.0000000E+00 7 Al+++ 0.2869420E+00 0.5848334E-05 0.2869362E+00 0.0000000E+00 8 H4SiO4 0.9163145E+00 0.1218272E-01 0.9041318E+00 0.0000000E+00 9 Ca++ 0.1012259E+00 0.1933745E-06 0.1012257E+00 0.0000000E+00 10 Mg++ 0.6984048E-01 0.9291133E-10 0.6984048E-01 0.0000000E+00 11 Fe++ 0.6274404E-01 0.3232102E-07 0.6274401E-01 0.0000000E+00 12 K+ 0.1868344E-01 0.1435538E-03 0.1853989E-01 0.0000000E+00 13 Na+ 0.1106203E+00 0.2020240E-01 0.9041785E-01 0.0000000E+00 14 Mn++ 0.1525779E-02 0.2097484E-08 0.1525777E-02 0.0000000E+00 15 HPO4-- 0.5207408E-03 0.6212837E-07 0.5206787E-03 0.0000000E+00 Chg. balance for solid moles: 0.1689E-15 Mass of aqueous solution: 0.991283E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 87.9990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 0.9042E-01 -1.044 23.71 1.375 24.69 9.101 andradite 0.9873E-02 -2.006 5.017 0.700 5.226 1.304 grossular 0.1758E-02 -2.755 0.7918 -0.101 0.8247 0.2203 apatite-OH 0.1736E-03 -3.761 0.8718E-01 -1.060 0.9080E-01 0.2770E-01 clinochlore 0.1397E-01 -1.855 7.764 0.890 8.086 2.953 daphnite 0.4173E-02 -2.380 2.978 0.474 3.101 0.9023 chlorite-Mn 0.3052E-03 -3.515 0.2163 -0.665 0.2253 0.6894E-01 microcline 0.1633E-01 -1.787 4.544 0.657 4.733 1.775 stilbite 0.6547E-01 -1.184 46.13 1.664 48.05 21.52 stilpnomelane-Fe 0.4426E-02 -2.354 4.771 0.679 4.970 1.648 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8489E+00 0.8489E+00 1.0000 -0.071 grossular 0.1511E+00 0.1511E+00 1.0000 -0.821 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.7572E+00 0.7572E+00 1.0000 -0.121 daphnite 0.2262E+00 0.2262E+00 1.0000 -0.645 chlorite-Mn 0.1654E-01 0.1654E-01 1.0000 -1.781 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 96.013988 g Volume = 39.518784 cm3 Porosity: -9.1691% V(tot) - V(min): -.33192E+01 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 87.9990000 g log = 1.9445 Original solution: 1000.0103000 g Original solution / Rock added: 11.36 (Water/Rock Ratio), log = 1.0555 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0301 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9906E+00 0.9858 0.1006E+01 0.1020E+01 CO2,gas 0.5459E-07 1.0071 0.5664E-07 0.5624E-07 CH4,gas 0.4271E-02 1.0125 0.4455E-02 0.4400E-02 H2,gas 0.5140E-02 1.0005 0.5298E-02 0.5295E-02 H2S,gas 0.1425E-06 0.9960 0.1462E-06 0.1468E-06 S2,gas 0.2776E-28 1.0000 0.2860E-28 0.2860E-28 CO,gas 0.7763E-13 1.0000 0.7997E-13 0.7997E-13 SO3,gas 0.5023E-46 1.0000 0.5175E-46 0.5175E-46 SO2,gas 0.1035E-25 1.0000 0.1067E-25 0.1067E-25 HCl,gas 0.2910E-17 1.0000 0.2998E-17 0.2998E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 16 albite -0.38 -0.38 0.00 0.000 -0.94784E-12 22 andradite 39.01 39.01 0.00 0.000 0.00000E+00 23 grossular 32.73 32.73 0.00 0.000 -0.12132E-10 32 apatite-OH -18.15 -18.15 0.00 0.000 0.60662E-11 46 clinochlore 39.07 39.07 0.00 0.000 0.24265E-10 47 daphnite 28.97 28.97 0.00 0.000 -0.30331E-10 48 chlorite-Mn 46.87 46.87 0.00 0.000 0.00000E+00 116 microcline -2.49 -2.49 0.00 0.000 0.15165E-11 163 stilbite -7.52 -7.52 0.00 0.000 0.15165E-10 164 stilpnomelane-Fe 13.02 13.02 0.00 0.000 -0.27298E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -15.61 -8.95 -2.982 0.15275E+05 -7.247 3 CH4,gas 4.54 0.49 -4.05 -1.013 0.69155E+04 -2.351 4 H2,gas 8.00 4.02 -3.97 -2.271 0.67870E+04 -2.276 5 H2S,gas -6.23 -14.76 -8.53 -4.267 0.14571E+05 -6.835 6 S2,gas -7.34 -37.58 -30.24 -4.653 0.51638E+05 -28.544 7 CO,gas 3.21 -11.58 -14.80 -4.553 0.25264E+05 -13.097 8 SO3,gas 17.12 -30.86 -47.99 -11.996 0.81933E+05 -46.286 9 SO2,gas 0.83 -26.84 -27.67 -7.379 0.47247E+05 -25.972 10 HCl,gas 5.19 -14.03 -19.22 -9.611 0.32821E+05 -17.523 11 acmite 7.71 6.67 -1.04 -0.108 0.17807E+04 15 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 19 spessartine 24.46 19.64 -4.82 -0.241 0.82324E+04 20 analcite 3.32 2.78 -0.54 -0.060 0.92739E+03 26 annite 20.12 17.67 -2.46 -0.136 0.41927E+04 27 phlogopite 27.06 25.30 -1.76 -0.098 0.30054E+04 29 anorthite 12.71 8.29 -4.42 -0.340 0.75460E+04 35 aragonite 0.97 -2.63 -3.59 -1.197 0.61325E+04 36 brucite 12.57 9.26 -3.30 -0.661 0.56431E+04 37 calcite 0.81 -2.63 -3.44 -1.146 0.58683E+04 38 carnegieite-low 9.02 5.94 -3.08 -0.440 0.52624E+04 39 carnegieite-high 10.09 5.94 -4.15 -0.593 0.70894E+04 40 carpholite-Mg 8.58 4.57 -4.01 -0.267 0.68444E+04 41 carpholite-Fe 6.71 2.03 -4.68 -0.312 0.79987E+04 42 celadonite 5.34 3.61 -1.73 -0.102 0.29489E+04 43 celadonite-Fe 3.88 1.07 -2.81 -0.165 0.47937E+04 44 chrysotile 23.89 21.47 -2.43 -0.202 0.41434E+04 49 chlorite-Al-free 47.17 42.93 -4.24 -0.177 0.72420E+04 51 chloritoid-Fe 9.17 5.19 -3.98 -0.266 0.68007E+04 52 chloritoid-Mn 11.40 7.64 -3.77 -0.251 0.64298E+04 54 coesite -2.38 -3.16 -0.79 -0.262 0.13430E+04 61 cristobalite -2.56 -3.16 -0.60 -0.201 0.10283E+04 63 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71234E+04 65 diaspore 2.87 0.82 -2.06 -0.343 0.35108E+04 66 diamond -3.10 -7.56 -4.45 -1.273 0.76048E+04 67 diopside 16.18 15.92 -0.26 -0.026 0.44728E+03 68 hedenbergite 14.21 13.37 -0.83 -0.083 0.14247E+04 73 clinoenstatite 17.17 12.20 -4.96 -0.496 0.84762E+04 75 epidote 24.67 22.81 -1.85 -0.090 0.31673E+04 76 clinozoisite 22.81 18.93 -3.88 -0.176 0.66236E+04 77 epidote-Fe 29.84 26.70 -3.14 -0.163 0.53576E+04 78 fayalite 14.05 10.27 -3.77 -0.539 0.64407E+04 79 ferrosilite 11.15 7.11 -4.04 -0.404 0.68954E+04 83 gibbsite 4.08 0.82 -3.26 -0.466 0.55693E+04 84 glaucophane 22.97 20.70 -2.28 -0.062 0.38875E+04 85 glaucophane-Fe 17.28 13.06 -4.21 -0.114 0.71958E+04 86 graphite -3.55 -7.56 -4.01 -1.146 0.68470E+04 87 greenalite 16.14 13.83 -2.31 -0.193 0.39447E+04 90 hematite 12.57 9.41 -3.15 -0.382 0.53867E+04 91 heulandite -5.83 -7.52 -1.69 -0.077 0.28938E+04 95 jadeite 4.22 2.78 -1.44 -0.144 0.24529E+04 97 kalsilite 7.58 3.84 -3.75 -0.535 0.63949E+04 98 kaolinite -1.33 -4.69 -3.36 -0.305 0.57324E+04 101 laumontite 2.88 1.97 -0.92 -0.061 0.15669E+04 102 lawsonite 9.62 8.29 -1.33 -0.088 0.22627E+04 103 leucite 4.12 0.68 -3.44 -0.344 0.58784E+04 105 lizardite 23.24 21.47 -1.78 -0.148 0.30360E+04 107 magnetite 20.09 16.13 -3.96 -0.323 0.67579E+04 108 minnesotaite 10.39 7.50 -2.88 -0.170 0.49244E+04 112 manganosite 14.06 9.16 -4.90 -1.224 0.83585E+04 120 muscovite 2.58 -0.85 -3.43 -0.202 0.58631E+04 121 paragonite 4.24 1.25 -2.99 -0.176 0.51022E+04 122 nepheline 8.34 5.94 -2.40 -0.343 0.40948E+04 128 periclase-Fe 11.63 6.72 -4.91 -1.227 0.83810E+04 134 phlogopite-Na 29.65 27.41 -2.24 -0.124 0.38242E+04 136 prehnite 19.37 18.11 -1.26 -0.074 0.21559E+04 137 prehnite-Fe 22.50 22.00 -0.50 -0.030 0.85458E+03 138 pumpellyite-Fe 46.27 43.75 -2.52 -0.056 0.42947E+04 139 pumpellyite-Mg 48.99 46.30 -2.70 -0.060 0.46019E+04 143 pyrrhotite -4.26 -8.05 -3.79 -1.262 0.64640E+04 144 pyrrhotiteFe0.875 -6.02 -9.38 -3.37 -1.239 0.57507E+04 145 pyroxmangite 7.40 6.00 -1.40 -0.280 0.23878E+04 146 pyrophyllite -6.18 -11.02 -4.84 -0.302 0.82632E+04 147 quartz -2.99 -3.16 -0.17 -0.058 0.29566E+03 152 rhodonite 7.45 6.00 -1.45 -0.289 0.24680E+04 153 sanidine -1.28 -2.49 -1.21 -0.093 0.20677E+04 165 stilpnomelane-Mg 27.44 25.74 -1.70 -0.051 0.28974E+04 171 talc 16.49 15.14 -1.35 -0.079 0.23059E+04 174 tephroite 18.09 15.16 -2.92 -0.418 0.49904E+04 178 tridymite -2.63 -3.16 -0.54 -0.179 0.91564E+03 179 tremolite 47.87 46.98 -0.89 -0.024 0.15194E+04 180 ferroactinolite 38.45 34.25 -4.20 -0.114 0.71723E+04 181 troilite-low -4.41 -8.05 -3.64 -1.212 0.62068E+04 187 wairakite 3.95 1.97 -1.98 -0.117 0.33889E+04 188 walstromite 11.51 9.82 -1.69 -0.338 0.28871E+04 189 wollastonite 10.46 9.82 -0.64 -0.129 0.10976E+04 190 pseudo-wollastonite 11.00 9.82 -1.18 -0.236 0.20174E+04 191 zoisite 22.85 18.93 -3.92 -0.178 0.66977E+04 192 akaganeite 7.75 4.71 -3.05 -0.659 0.52059E+04 199 chalcedony -2.80 -3.16 -0.36 -0.120 0.61496E+03 201 montmorillonite-Ca -2.29 -6.09 -3.80 -0.235 0.64806E+04 202 montmorillonite-K -2.24 -6.19 -3.95 -0.242 0.67457E+04 203 montmorillonite-Mg -2.48 -6.70 -4.22 -0.261 0.72049E+04 204 montmorillonite-Na -2.04 -5.49 -3.46 -0.212 0.59006E+04 205 nontronite-Ca 3.21 0.22 -3.00 -0.194 0.51194E+04 206 nontronite-H 2.53 -1.93 -4.46 -0.299 0.76123E+04 207 nontronite-K 3.34 0.12 -3.23 -0.207 0.55076E+04 208 nontronite-Mg 3.07 -0.40 -3.47 -0.225 0.59277E+04 209 nontronite-Na 3.52 0.81 -2.71 -0.174 0.46285E+04 224 tobermorite 9.82 7.65 -2.17 -0.593 0.37095E+04 230 alabandite -0.98 -5.60 -4.62 -1.541 0.78944E+04 233 boehmite 4.41 0.82 -3.59 -0.598 0.61277E+04 235 ferrous-oxide 9.81 6.72 -3.09 -0.773 0.52820E+04 240 silica-amorphous -2.09 -3.16 -1.07 -0.357 0.18291E+04 242 an20ab80 2.02 1.35 -0.67 -0.051 0.11384E+04 243 an25ab75 2.65 1.78 -0.86 -0.066 0.14699E+04 244 an30ab70 3.28 2.22 -1.06 -0.082 0.18111E+04 245 tr.625ac.25prg.125 45.16 44.77 -0.39 -0.011 0.66961E+03 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 4.0000000 g Current total amount of reactant added: 87.9990000 g New total amount of reactant added: 91.9990000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.7383E-13 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 11 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 91.9990000 Water: Moles liquid = 0.5491E+02 kg liquid = 0.9893E+00 Moles total = 0.5436E+02 kg total = 0.9792E+00 Activity = 1.0000 Stoichiometric ionic strength = .1066728E-01 Osmotic coef. = 0.9656 True ionic strength = .1892514E-01 Chg. balance for total moles = -.7383E-13 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.92932E-10 -10.0318 0.78358E-10 -10.1059 0.84318E+00 -0.0741 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13886E-03 -3.8574 0.11641E-03 -3.9340 0.83833E+00 -0.0766 4 SO4-- 0.15429E-10 -10.8117 0.81298E-11 -11.0899 0.52691E+00 -0.2783 5 HCO3- 0.26662E-05 -5.5741 0.22382E-05 -5.6501 0.83950E+00 -0.0760 6 HS- 0.25776E-04 -4.5888 0.21612E-04 -4.6653 0.83844E+00 -0.0765 7 Al+++ 0.12168E-28 -28.9148 0.29064E-29 -29.5366 0.23885E+00 -0.6219 8 H4SiO4 0.69838E-03 -3.1559 0.69838E-03 -3.1559 0.10000E+01 0.0000 9 Ca++ 0.11929E-06 -6.9234 0.62415E-07 -7.2047 0.52321E+00 -0.2813 10 Mg++ 0.22286E-10 -10.6520 0.11609E-10 -10.9352 0.52092E+00 -0.2832 11 Fe++ 0.61850E-13 -13.2087 0.32253E-13 -13.4914 0.52147E+00 -0.2828 12 K+ 0.14795E-03 -3.8299 0.12423E-03 -3.9058 0.83969E+00 -0.0759 13 Na+ 0.18772E-01 -1.7265 0.15734E-01 -1.8032 0.83818E+00 -0.0767 14 Mn++ 0.17637E-10 -10.7536 0.92046E-11 -11.0360 0.52188E+00 -0.2824 15 HPO4-- 0.57590E-07 -7.2397 0.30349E-07 -7.5179 0.52698E+00 -0.2782 16 HSiO3- 0.99270E-02 -2.0032 0.83221E-02 -2.0798 0.83833E+00 -0.0766 17 Ca(HSiO3)+ 0.14085E-07 -7.8513 0.11829E-07 -7.9270 0.83986E+00 -0.0758 18 Mg(HSiO3)+ 0.32604E-11 -11.4867 0.27383E-11 -11.5625 0.83986E+00 -0.0758 19 NaHSiO3,aq 0.21178E-02 -2.6741 0.21178E-02 -2.6741 0.10000E+01 0.0000 20 AlO+ 0.76674E-16 -16.1154 0.64395E-16 -16.1911 0.83986E+00 -0.0758 22 HAlO2,aq 0.16366E-09 -9.7861 0.16366E-09 -9.7861 0.10000E+01 0.0000 23 AlO2- 0.55245E-05 -5.2577 0.46233E-05 -5.3350 0.83688E+00 -0.0773 24 CH4,aq 0.57985E-05 -5.2367 0.57796E-05 -5.2381 0.99674E+00 -0.0014 25 C2H6,aq 0.11079E-14 -14.9555 0.11043E-14 -14.9569 0.99674E+00 -0.0014 29 CO,aq 0.48685E-16 -16.3126 0.48685E-16 -16.3126 0.10000E+01 0.0000 30 CO2,aq 0.37598E-09 -9.4248 0.37476E-09 -9.4262 0.99674E+00 -0.0014 31 CO3-2 0.47447E-05 -5.3238 0.24950E-05 -5.6029 0.52584E+00 -0.2791 32 CaCO3,aq 0.19526E-08 -8.7094 0.19526E-08 -8.7094 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.42459E-11 -11.3720 0.35660E-11 -11.4478 0.83986E+00 -0.0758 34 CaCl+ 0.14000E-10 -10.8539 0.11758E-10 -10.9297 0.83986E+00 -0.0758 35 CaCl2,aq 0.32521E-15 -15.4878 0.32521E-15 -15.4878 0.10000E+01 0.0000 36 CaOH+ 0.67592E-07 -7.1701 0.56768E-07 -7.2459 0.83986E+00 -0.0758 37 CaSO4,aq 0.16113E-15 -15.7928 0.16113E-15 -15.7928 0.10000E+01 0.0000 38 HCl,aq 0.16716E-14 -14.7769 0.16716E-14 -14.7769 0.10000E+01 0.0000 43 FeCl+ 0.70761E-17 -17.1502 0.59430E-17 -17.2260 0.83986E+00 -0.0758 46 FeO,aq 0.20415E-09 -9.6900 0.20415E-09 -9.6900 0.10000E+01 0.0000 47 FeOH+ 0.15953E-10 -10.7972 0.13398E-10 -10.8730 0.83986E+00 -0.0758 48 HFeO2- 0.32518E-07 -7.4879 0.27261E-07 -7.5645 0.83833E+00 -0.0766 49 FeO+ 0.16732E-16 -16.7764 0.14053E-16 -16.8522 0.83986E+00 -0.0758 51 FeO2- 0.55864E-09 -9.2529 0.46832E-09 -9.3295 0.83833E+00 -0.0766 52 HFeO2,aq 0.46673E-11 -11.3309 0.46673E-11 -11.3309 0.10000E+01 0.0000 53 H2,aq 0.51884E-05 -5.2850 0.51715E-05 -5.2864 0.99674E+00 -0.0014 54 KCl,aq 0.26211E-09 -9.5815 0.26211E-09 -9.5815 0.10000E+01 0.0000 56 KOH,aq 0.67705E-06 -6.1694 0.67705E-06 -6.1694 0.10000E+01 0.0000 57 KSO4- 0.18694E-13 -13.7283 0.15672E-13 -13.8049 0.83833E+00 -0.0766 58 MgCO3,aq 0.91036E-13 -13.0408 0.91036E-13 -13.0408 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.80698E-15 -15.0931 0.67775E-15 -15.1689 0.83986E+00 -0.0758 60 MgCl+ 0.23602E-14 -14.6270 0.19823E-14 -14.7028 0.83986E+00 -0.0758 61 MgOH+ 0.69569E-10 -10.1576 0.58429E-10 -10.2334 0.83986E+00 -0.0758 63 MnO,aq 0.15525E-08 -8.8090 0.15525E-08 -8.8090 0.10000E+01 0.0000 64 MnOH+ 0.42294E-09 -9.3737 0.35521E-09 -9.4495 0.83986E+00 -0.0758 65 MnO2-2 0.15958E-10 -10.7970 0.83912E-11 -11.0762 0.52584E+00 -0.2791 66 HMnO2- 0.17183E-09 -9.7649 0.14405E-09 -9.8415 0.83833E+00 -0.0766 69 MnCl+ 0.78566E-14 -14.1048 0.65984E-14 -14.1806 0.83986E+00 -0.0758 70 MnSO4,aq 0.21603E-19 -19.6655 0.21603E-19 -19.6655 0.10000E+01 0.0000 71 NaCl,aq 0.60702E-06 -6.2168 0.60702E-06 -6.2168 0.10000E+01 0.0000 72 NaOH,aq 0.86273E-04 -4.0641 0.86273E-04 -4.0641 0.10000E+01 0.0000 74 OH- 0.88107E-02 -2.0550 0.73735E-02 -2.1323 0.83688E+00 -0.0773 79 HPO3-2 0.93014E-15 -15.0315 0.48910E-15 -15.3106 0.52584E+00 -0.2791 81 H2PO3- 0.91675E-19 -19.0377 0.76854E-19 -19.1143 0.83833E+00 -0.0766 82 H3PO4,aq 0.13033E-17 -17.8850 0.13033E-17 -17.8850 0.10000E+01 0.0000 83 H2PO4- 0.52282E-10 -10.2816 0.43869E-10 -10.3578 0.83909E+00 -0.0762 84 PO4-3 0.12624E-08 -8.8988 0.31600E-09 -9.5003 0.25032E+00 -0.6015 88 HP2O7-3 0.16085E-17 -17.7936 0.38453E-18 -18.4151 0.23907E+00 -0.6215 89 P2O7-4 0.14349E-16 -16.8432 0.11724E-17 -17.9309 0.81700E-01 -1.0878 90 H2S,aq 0.52509E-08 -8.2798 0.52338E-08 -8.2812 0.99674E+00 -0.0014 91 S2-2 0.38058E-14 -14.4196 0.20012E-14 -14.6987 0.52584E+00 -0.2791 97 SO3-2 0.10248E-16 -16.9893 0.54635E-17 -17.2625 0.53311E+00 -0.2732 98 HSO3- 0.31974E-19 -19.4952 0.26805E-19 -19.5718 0.83833E+00 -0.0766 99 HSO4- 0.73031E-18 -18.1365 0.61393E-18 -18.2119 0.84064E+00 -0.0754 Charge balance for all species = -.7407E-13 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.9293237E-10 -.2097083E-01 -.2110274E+02 0.0000 2 H2O 0.1000000E+01 0.5550513E+02 0.9983047E+06 0.0000 3 Cl- 0.1388636E-03 0.1394709E-03 0.4936568E+01 6.1719 4 SO4-- 0.1542936E-10 -.7095531E-05 -.6804924E+00 9.1219 5 HCO3- 0.2666169E-05 0.1321178E-04 0.8048263E+00 4.4558 6 HS- 0.2577587E-04 0.3287667E-04 0.1085517E+01 5.4406 7 Al+++ 0.1216834E-28 0.5524677E-05 0.1488201E+00 0.7811 8 H4SiO4 0.6983808E-03 0.1274325E-01 0.1222818E+04 -3.1559 9 Ca++ 0.1192914E-06 0.2029388E-06 0.8120068E-02 13.0071 10 Mg++ 0.2228620E-10 0.9520999E-10 0.2310956E-05 9.2766 11 Fe++ 0.6185003E-13 0.3330133E-07 0.1856735E-02 6.7204 12 K+ 0.1479452E-03 0.1486225E-03 0.5801925E+01 6.2001 13 Na+ 0.1877195E-01 0.2097664E-01 0.4814594E+03 8.3028 14 Mn++ 0.1763735E-10 0.2180849E-08 0.1196154E-03 9.1758 15 HPO4-- 0.5759023E-07 0.5890487E-07 0.5644377E-02 12.6940 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.1523354E+01 -.2074578E-01 -.1502608E+01 0.0000000E+00 2 H2O 0.5435500E+02 0.5490948E+02 -.5544740E+00 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.2575110E-02 -.7019386E-05 0.2582130E-02 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.2549606E-02 0.3252386E-04 -.2582130E-02 0.0000000E+00 7 Al+++ 0.2999850E+00 0.5465389E-05 0.2999795E+00 0.0000000E+00 8 H4SiO4 0.9579656E+00 0.1260650E-01 0.9453591E+00 0.0000000E+00 9 Ca++ 0.1058264E+00 0.2007610E-06 0.1058262E+00 0.0000000E+00 10 Mg++ 0.7301508E-01 0.9418825E-10 0.7301508E-01 0.0000000E+00 11 Fe++ 0.6559608E-01 0.3294396E-07 0.6559604E-01 0.0000000E+00 12 K+ 0.1953270E-01 0.1470276E-03 0.1938567E-01 0.0000000E+00 13 Na+ 0.1156412E+00 0.2075153E-01 0.9488970E-01 0.0000000E+00 14 Mn++ 0.1595133E-02 0.2157446E-08 0.1595131E-02 0.0000000E+00 15 HPO4-- 0.5444111E-03 0.5827274E-07 0.5443529E-03 0.0000000E+00 Chg. balance for solid moles: -.7741E-16 Mass of aqueous solution: 0.990891E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 91.9990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 0.9489E-01 -1.023 24.88 1.396 24.79 9.552 andradite 0.1033E-01 -1.986 5.249 0.720 5.229 1.364 grossular 0.1904E-02 -2.720 0.8577 -0.067 0.8545 0.2387 apatite-OH 0.1815E-03 -3.741 0.9115E-01 -1.040 0.9081E-01 0.2896E-01 clinochlore 0.1460E-01 -1.836 8.117 0.909 8.087 3.087 daphnite 0.4257E-02 -2.371 3.037 0.482 3.026 0.9203 chlorite-Mn 0.3190E-03 -3.496 0.2262 -0.646 0.2253 0.7208E-01 microcline 0.1702E-01 -1.769 4.737 0.676 4.720 1.851 stilbite 0.6822E-01 -1.166 48.08 1.682 47.90 22.42 stilpnomelane-Fe 0.4731E-02 -2.325 5.100 0.708 5.081 1.762 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8443E+00 0.8443E+00 1.0000 -0.073 grossular 0.1557E+00 0.1557E+00 1.0000 -0.808 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.7614E+00 0.7614E+00 1.0000 -0.118 daphnite 0.2219E+00 0.2219E+00 1.0000 -0.654 chlorite-Mn 0.1663E-01 0.1663E-01 1.0000 -1.779 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 100.373863 g Volume = 41.298780 cm3 Porosity: -9.2572% V(tot) - V(min): -.34992E+01 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 91.9990000 g log = 1.9638 Original solution: 1000.0103000 g Original solution / Rock added: 10.87 (Water/Rock Ratio), log = 1.0362 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0357 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9853E+00 0.9857 0.1006E+01 0.1021E+01 CO2,gas 0.3844E-07 1.0070 0.4009E-07 0.3982E-07 CH4,gas 0.8113E-02 1.0125 0.8507E-02 0.8402E-02 H2,gas 0.6552E-02 1.0006 0.6790E-02 0.6786E-02 H2S,gas 0.1395E-06 0.9960 0.1439E-06 0.1445E-06 S2,gas 0.1627E-28 1.0000 0.1686E-28 0.1686E-28 CO,gas 0.7005E-13 1.0000 0.7255E-13 0.7255E-13 SO3,gas 0.1822E-46 1.0000 0.1887E-46 0.1887E-46 SO2,gas 0.4814E-26 1.0000 0.4985E-26 0.4985E-26 HCl,gas 0.2848E-17 1.0000 0.2950E-17 0.2950E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 16 albite -0.38 -0.38 0.00 0.000 -0.94784E-12 22 andradite 39.01 39.01 0.00 0.000 0.12132E-10 23 grossular 32.73 32.73 0.00 0.000 0.00000E+00 32 apatite-OH -18.15 -18.15 0.00 0.000 0.00000E+00 46 clinochlore 39.07 39.07 0.00 0.000 -0.36397E-10 47 daphnite 28.97 28.97 0.00 0.000 0.12132E-10 48 chlorite-Mn 46.87 46.87 0.00 0.000 -0.48529E-10 116 microcline -2.49 -2.49 0.00 0.000 0.15165E-11 163 stilbite -7.52 -7.52 0.00 0.000 -0.90992E-11 164 stilpnomelane-Fe 13.02 13.02 0.00 0.000 -0.27298E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -15.76 -9.10 -3.032 0.15531E+05 -7.397 3 CH4,gas 4.54 0.77 -3.77 -0.942 0.64358E+04 -2.070 4 H2,gas 8.00 4.13 -3.87 -2.210 0.66030E+04 -2.168 5 H2S,gas -6.23 -14.77 -8.54 -4.270 0.14584E+05 -6.842 6 S2,gas -7.34 -37.81 -30.47 -4.688 0.52031E+05 -28.773 7 CO,gas 3.21 -11.62 -14.84 -4.566 0.25336E+05 -13.139 8 SO3,gas 17.12 -31.30 -48.42 -12.106 0.82681E+05 -46.724 9 SO2,gas 0.83 -27.17 -28.00 -7.467 0.47811E+05 -26.302 10 HCl,gas 5.19 -14.04 -19.23 -9.615 0.32833E+05 -17.530 11 acmite 7.71 6.65 -1.06 -0.111 0.18179E+04 15 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 19 spessartine 24.46 19.62 -4.84 -0.242 0.82563E+04 20 analcite 3.32 2.77 -0.55 -0.061 0.93880E+03 26 annite 20.12 17.67 -2.45 -0.136 0.41811E+04 27 phlogopite 27.06 25.34 -1.72 -0.096 0.29389E+04 29 anorthite 12.71 8.26 -4.45 -0.343 0.76031E+04 35 aragonite 0.97 -2.75 -3.72 -1.238 0.63440E+04 36 brucite 12.57 9.28 -3.29 -0.658 0.56209E+04 37 calcite 0.81 -2.75 -3.56 -1.187 0.60797E+04 38 carnegieite-low 9.02 5.93 -3.10 -0.442 0.52852E+04 39 carnegieite-high 10.09 5.93 -4.17 -0.595 0.71122E+04 40 carpholite-Mg 8.58 4.53 -4.06 -0.270 0.69239E+04 41 carpholite-Fe 6.71 1.97 -4.74 -0.316 0.80966E+04 42 celadonite 5.34 3.63 -1.71 -0.100 0.29153E+04 43 celadonite-Fe 3.88 1.08 -2.80 -0.165 0.47784E+04 44 chrysotile 23.89 21.52 -2.37 -0.198 0.40540E+04 49 chlorite-Al-free 47.17 43.04 -4.14 -0.172 0.70633E+04 51 chloritoid-Fe 9.17 5.13 -4.05 -0.270 0.69100E+04 52 chloritoid-Mn 11.40 7.58 -3.82 -0.255 0.65208E+04 54 coesite -2.38 -3.16 -0.78 -0.260 0.13316E+04 61 cristobalite -2.56 -3.16 -0.60 -0.199 0.10169E+04 63 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71234E+04 65 diaspore 2.87 0.78 -2.09 -0.349 0.35731E+04 66 diamond -3.10 -7.49 -4.39 -1.254 0.74930E+04 67 diopside 16.18 15.97 -0.21 -0.021 0.35758E+03 68 hedenbergite 14.21 13.42 -0.79 -0.079 0.13533E+04 73 clinoenstatite 17.17 12.24 -4.92 -0.492 0.84090E+04 75 epidote 24.67 22.76 -1.91 -0.092 0.32564E+04 76 clinozoisite 22.81 18.89 -3.92 -0.178 0.66869E+04 77 epidote-Fe 29.84 26.64 -3.21 -0.166 0.54725E+04 78 fayalite 14.05 10.28 -3.76 -0.537 0.64215E+04 79 ferrosilite 11.15 7.13 -4.02 -0.402 0.68649E+04 83 gibbsite 4.08 0.78 -3.30 -0.471 0.56316E+04 84 glaucophane 22.97 20.75 -2.22 -0.060 0.37982E+04 85 glaucophane-Fe 17.28 13.08 -4.19 -0.113 0.71615E+04 86 graphite -3.55 -7.49 -3.94 -1.127 0.67352E+04 87 greenalite 16.14 13.85 -2.29 -0.191 0.39103E+04 90 hematite 12.57 9.31 -3.26 -0.395 0.55630E+04 91 heulandite -5.83 -7.52 -1.69 -0.077 0.28938E+04 95 jadeite 4.22 2.77 -1.44 -0.144 0.24643E+04 97 kalsilite 7.58 3.83 -3.76 -0.537 0.64177E+04 98 kaolinite -1.33 -4.75 -3.42 -0.311 0.58342E+04 101 laumontite 2.88 1.95 -0.94 -0.063 0.16012E+04 102 lawsonite 9.62 8.26 -1.36 -0.091 0.23197E+04 103 leucite 4.12 0.67 -3.45 -0.345 0.58898E+04 105 lizardite 23.24 21.52 -1.73 -0.144 0.29467E+04 107 magnetite 20.09 16.03 -4.06 -0.331 0.69304E+04 108 minnesotaite 10.39 7.54 -2.85 -0.168 0.48672E+04 112 manganosite 14.06 9.18 -4.88 -1.221 0.83364E+04 120 muscovite 2.58 -0.92 -3.51 -0.206 0.59877E+04 121 paragonite 4.24 1.18 -3.06 -0.180 0.52268E+04 122 nepheline 8.34 5.93 -2.41 -0.345 0.41176E+04 128 periclase-Fe 11.63 6.72 -4.91 -1.227 0.83772E+04 134 phlogopite-Na 29.65 27.45 -2.20 -0.122 0.37577E+04 136 prehnite 19.37 18.11 -1.26 -0.074 0.21569E+04 137 prehnite-Fe 22.50 21.98 -0.52 -0.031 0.88137E+03 138 pumpellyite-Fe 46.27 43.72 -2.55 -0.057 0.43550E+04 139 pumpellyite-Mg 48.99 46.28 -2.72 -0.060 0.46439E+04 143 pyrrhotite -4.26 -8.05 -3.79 -1.264 0.64722E+04 144 pyrrhotiteFe0.875 -6.02 -9.40 -3.39 -1.245 0.57821E+04 145 pyroxmangite 7.40 6.02 -1.38 -0.276 0.23542E+04 146 pyrophyllite -6.18 -11.06 -4.89 -0.305 0.83421E+04 147 quartz -2.99 -3.16 -0.17 -0.055 0.28425E+03 152 rhodonite 7.45 6.02 -1.43 -0.285 0.24344E+04 153 sanidine -1.28 -2.49 -1.21 -0.093 0.20677E+04 165 stilpnomelane-Mg 27.44 25.80 -1.64 -0.049 0.28058E+04 171 talc 16.49 15.21 -1.28 -0.076 0.21937E+04 174 tephroite 18.09 15.20 -2.89 -0.413 0.49347E+04 178 tridymite -2.63 -3.16 -0.53 -0.177 0.90422E+03 179 tremolite 47.87 47.15 -0.72 -0.019 0.12279E+04 180 ferroactinolite 38.45 34.37 -4.08 -0.110 0.69723E+04 181 troilite-low -4.41 -8.05 -3.64 -1.213 0.62150E+04 187 wairakite 3.95 1.95 -2.00 -0.118 0.34231E+04 188 walstromite 11.51 9.85 -1.66 -0.332 0.28310E+04 189 wollastonite 10.46 9.85 -0.61 -0.122 0.10415E+04 190 pseudo-wollastonite 11.00 9.85 -1.15 -0.230 0.19613E+04 191 zoisite 22.85 18.89 -3.96 -0.180 0.67609E+04 192 akaganeite 7.75 4.65 -3.10 -0.670 0.52940E+04 199 chalcedony -2.80 -3.16 -0.35 -0.118 0.60354E+03 201 montmorillonite-Ca -2.29 -6.11 -3.82 -0.236 0.65243E+04 202 montmorillonite-K -2.24 -6.21 -3.98 -0.243 0.67875E+04 203 montmorillonite-Mg -2.48 -6.73 -4.25 -0.263 0.72523E+04 204 montmorillonite-Na -2.04 -5.52 -3.48 -0.213 0.59424E+04 205 nontronite-Ca 3.21 0.13 -3.08 -0.200 0.52669E+04 206 nontronite-H 2.53 -2.02 -4.55 -0.305 0.77672E+04 207 nontronite-K 3.34 0.03 -3.31 -0.213 0.56533E+04 208 nontronite-Mg 3.07 -0.49 -3.56 -0.231 0.60790E+04 209 nontronite-Na 3.52 0.72 -2.80 -0.179 0.47742E+04 224 tobermorite 9.82 7.68 -2.14 -0.585 0.36609E+04 230 alabandite -0.98 -5.60 -4.62 -1.539 0.78843E+04 233 boehmite 4.41 0.78 -3.63 -0.604 0.61900E+04 235 ferrous-oxide 9.81 6.72 -3.09 -0.773 0.52781E+04 240 silica-amorphous -2.09 -3.16 -1.06 -0.355 0.18177E+04 242 an20ab80 2.02 1.34 -0.67 -0.052 0.11498E+04 243 an25ab75 2.65 1.78 -0.87 -0.067 0.14842E+04 244 an30ab70 3.28 2.21 -1.07 -0.082 0.18282E+04 245 tr.625ac.25prg.125 45.16 44.91 -0.25 -0.007 0.42642E+03 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 4.0000000 g Current total amount of reactant added: 91.9990000 g New total amount of reactant added: 95.9990000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.7370E-13 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 14 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 95.9990000 Water: Moles liquid = 0.5489E+02 kg liquid = 0.9888E+00 Moles total = 0.5430E+02 kg total = 0.9783E+00 Activity = 1.0000 Stoichiometric ionic strength = .1093905E-01 Osmotic coef. = 0.9670 True ionic strength = .1936618E-01 Chg. balance for total moles = -.7370E-13 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.91760E-10 -10.0373 0.77260E-10 -10.1120 0.84198E+00 -0.0747 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13891E-03 -3.8573 0.11628E-03 -3.9345 0.83705E+00 -0.0772 4 SO4-- 0.61752E-11 -11.2094 0.32345E-11 -11.4902 0.52379E+00 -0.2808 5 HCO3- 0.15989E-05 -5.7962 0.13403E-05 -5.8728 0.83824E+00 -0.0766 6 HS- 0.25787E-04 -4.5886 0.21588E-04 -4.6658 0.83717E+00 -0.0772 7 Al+++ 0.10907E-28 -28.9623 0.25699E-29 -29.5901 0.23563E+00 -0.6278 8 H4SiO4 0.70893E-03 -3.1494 0.70893E-03 -3.1494 0.10000E+01 0.0000 9 Ca++ 0.12345E-06 -6.9085 0.64201E-07 -7.1925 0.52005E+00 -0.2840 10 Mg++ 0.22430E-10 -10.6492 0.11613E-10 -10.9351 0.51773E+00 -0.2859 11 Fe++ 0.60784E-13 -13.2162 0.31503E-13 -13.5016 0.51828E+00 -0.2854 12 K+ 0.15140E-03 -3.8199 0.12694E-03 -3.8964 0.83844E+00 -0.0765 13 Na+ 0.19211E-01 -1.7164 0.16078E-01 -1.7938 0.83690E+00 -0.0773 14 Mn++ 0.17751E-10 -10.7508 0.92073E-11 -11.0359 0.51870E+00 -0.2851 15 HPO4-- 0.54240E-07 -7.2657 0.28415E-07 -7.5465 0.52387E+00 -0.2808 16 HSiO3- 0.10236E-01 -1.9899 0.85679E-02 -2.0671 0.83705E+00 -0.0772 17 Ca(HSiO3)+ 0.14938E-07 -7.8257 0.12527E-07 -7.9021 0.83861E+00 -0.0764 18 Mg(HSiO3)+ 0.33627E-11 -11.4733 0.28200E-11 -11.5498 0.83861E+00 -0.0764 19 NaHSiO3,aq 0.22280E-02 -2.6521 0.22280E-02 -2.6521 0.10000E+01 0.0000 20 AlO+ 0.69842E-16 -16.1559 0.58570E-16 -16.2323 0.83861E+00 -0.0764 22 HAlO2,aq 0.15097E-09 -9.8211 0.15097E-09 -9.8211 0.10000E+01 0.0000 23 AlO2- 0.51766E-05 -5.2860 0.43255E-05 -5.3640 0.83558E+00 -0.0780 24 CH4,aq 0.87185E-05 -5.0596 0.86894E-05 -5.0610 0.99666E+00 -0.0015 25 C2H6,aq 0.19825E-14 -14.7028 0.19759E-14 -14.7042 0.99666E+00 -0.0015 29 CO,aq 0.36311E-16 -16.4400 0.36311E-16 -16.4400 0.10000E+01 0.0000 30 CO2,aq 0.22200E-09 -9.6536 0.22126E-09 -9.6551 0.99666E+00 -0.0015 31 CO3-2 0.28988E-05 -5.5378 0.15152E-05 -5.8195 0.52271E+00 -0.2817 32 CaCO3,aq 0.12198E-08 -8.9137 0.12198E-08 -8.9137 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.26191E-11 -11.5818 0.21964E-11 -11.6583 0.83861E+00 -0.0764 34 CaCl+ 0.14406E-10 -10.8415 0.12081E-10 -10.9179 0.83861E+00 -0.0764 35 CaCl2,aq 0.33373E-15 -15.4766 0.33373E-15 -15.4766 0.10000E+01 0.0000 36 CaOH+ 0.70620E-07 -7.1511 0.59223E-07 -7.2275 0.83861E+00 -0.0764 37 CaSO4,aq 0.65941E-16 -16.1808 0.65941E-16 -16.1808 0.10000E+01 0.0000 38 HCl,aq 0.16462E-14 -14.7835 0.16462E-14 -14.7835 0.10000E+01 0.0000 43 FeCl+ 0.69139E-17 -17.1603 0.57981E-17 -17.2367 0.83861E+00 -0.0764 46 FeO,aq 0.20512E-09 -9.6880 0.20512E-09 -9.6880 0.10000E+01 0.0000 47 FeOH+ 0.15827E-10 -10.8006 0.13273E-10 -10.8770 0.83861E+00 -0.0764 48 HFeO2- 0.33187E-07 -7.4790 0.27779E-07 -7.5563 0.83705E+00 -0.0772 49 FeO+ 0.14770E-16 -16.8306 0.12386E-16 -16.9071 0.83861E+00 -0.0764 51 FeO2- 0.50726E-09 -9.2948 0.42460E-09 -9.3720 0.83705E+00 -0.0772 52 HFeO2,aq 0.41722E-11 -11.3796 0.41722E-11 -11.3796 0.10000E+01 0.0000 53 H2,aq 0.65546E-05 -5.1835 0.65328E-05 -5.1849 0.99666E+00 -0.0015 54 KCl,aq 0.26752E-09 -9.5726 0.26752E-09 -9.5726 0.10000E+01 0.0000 56 KOH,aq 0.70167E-06 -6.1539 0.70167E-06 -6.1539 0.10000E+01 0.0000 57 KSO4- 0.76118E-14 -14.1185 0.63714E-14 -14.1958 0.83705E+00 -0.0772 58 MgCO3,aq 0.55303E-13 -13.2572 0.55303E-13 -13.2572 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.48408E-15 -15.3151 0.40596E-15 -15.3915 0.83861E+00 -0.0764 60 MgCl+ 0.23617E-14 -14.6268 0.19805E-14 -14.7032 0.83861E+00 -0.0764 61 MgOH+ 0.70684E-10 -10.1507 0.59276E-10 -10.2271 0.83861E+00 -0.0764 63 MnO,aq 0.15974E-08 -8.7966 0.15974E-08 -8.7966 0.10000E+01 0.0000 64 MnOH+ 0.42971E-09 -9.3668 0.36036E-09 -9.4433 0.83861E+00 -0.0764 65 MnO2-2 0.16991E-10 -10.7698 0.88811E-11 -11.0515 0.52271E+00 -0.2817 66 HMnO2- 0.17959E-09 -9.7457 0.15033E-09 -9.8230 0.83705E+00 -0.0772 69 MnCl+ 0.78614E-14 -14.1045 0.65927E-14 -14.1809 0.83861E+00 -0.0764 71 NaCl,aq 0.61956E-06 -6.2079 0.61956E-06 -6.2079 0.10000E+01 0.0000 72 NaOH,aq 0.89410E-04 -4.0486 0.89410E-04 -4.0486 0.10000E+01 0.0000 74 OH- 0.89498E-02 -2.0482 0.74783E-02 -2.1262 0.83558E+00 -0.0780 79 HPO3-2 0.11067E-14 -14.9560 0.57847E-15 -15.2377 0.52271E+00 -0.2817 81 H2PO3- 0.10707E-18 -18.9703 0.89623E-19 -19.0476 0.83705E+00 -0.0772 82 H3PO4,aq 0.11863E-17 -17.9258 0.11863E-17 -17.9258 0.10000E+01 0.0000 83 H2PO4- 0.48337E-10 -10.3157 0.40498E-10 -10.3926 0.83782E+00 -0.0768 84 PO4-3 0.12140E-08 -8.9158 0.30007E-09 -9.5228 0.24716E+00 -0.6070 88 HP2O7-3 0.14092E-17 -17.8510 0.33236E-18 -18.4784 0.23585E+00 -0.6274 89 P2O7-4 0.12879E-16 -16.8901 0.10277E-17 -17.9881 0.79794E-01 -1.0980 90 H2S,aq 0.51722E-08 -8.2863 0.51549E-08 -8.2878 0.99666E+00 -0.0015 91 S2-2 0.30242E-14 -14.5194 0.15808E-14 -14.8011 0.52271E+00 -0.2817 97 SO3-2 0.51802E-17 -17.2857 0.27459E-17 -17.5613 0.53007E+00 -0.2757 98 HSO3- 0.15869E-19 -19.7995 0.13283E-19 -19.8767 0.83705E+00 -0.0772 99 HSO4- 0.28691E-18 -18.5423 0.24083E-18 -18.6183 0.83940E+00 -0.0760 Charge balance for all species = -.7413E-13 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.9176027E-10 -.2152922E-01 -.2166359E+02 0.0000 2 H2O 0.1000000E+01 0.5550485E+02 0.9982515E+06 0.0000 3 Cl- 0.1389130E-03 0.1395329E-03 0.4938523E+01 6.1775 4 SO4-- 0.6175170E-11 -.1035711E-04 -.9932443E+00 8.7339 5 HCO3- 0.1598900E-05 0.1321765E-04 0.8051450E+00 4.2392 6 HS- 0.2578741E-04 0.3614971E-04 0.1193528E+01 5.4463 7 Al+++ 0.1090658E-28 0.5176792E-05 0.1394422E+00 0.7460 8 H4SiO4 0.7089321E-03 0.1317279E-01 0.1263974E+04 -3.1494 9 Ca++ 0.1234522E-06 0.2102471E-06 0.8412085E-02 13.0316 10 Mg++ 0.2243012E-10 0.9653512E-10 0.2343007E-05 9.2890 11 Fe++ 0.6078416E-13 0.3391901E-07 0.1891083E-02 6.7224 12 K+ 0.1514033E-03 0.1521052E-03 0.5937595E+01 6.2156 13 Na+ 0.1921137E-01 0.2152939E-01 0.4941223E+03 8.3183 14 Mn++ 0.1775066E-10 0.2241445E-08 0.1229330E-03 9.1882 15 HPO4-- 0.5424032E-07 0.5550270E-07 0.5318117E-02 12.6776 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.1589588E+01 -.2128872E-01 -.1568299E+01 0.0000000E+00 2 H2O 0.5430486E+02 0.5488482E+02 -.5799588E+00 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.2685964E-02 -.1024142E-04 0.2696205E-02 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.2660460E-02 0.3574589E-04 -.2696205E-02 0.0000000E+00 7 Al+++ 0.3130279E+00 0.5118964E-05 0.3130228E+00 0.0000000E+00 8 H4SiO4 0.9996168E+00 0.1302564E-01 0.9865911E+00 0.0000000E+00 9 Ca++ 0.1104270E+00 0.2078985E-06 0.1104268E+00 0.0000000E+00 10 Mg++ 0.7618968E-01 0.9545675E-10 0.7618968E-01 0.0000000E+00 11 Fe++ 0.6844811E-01 0.3354011E-07 0.6844808E-01 0.0000000E+00 12 K+ 0.2038195E-01 0.1504061E-03 0.2023155E-01 0.0000000E+00 13 Na+ 0.1206622E+00 0.2128889E-01 0.9937331E-01 0.0000000E+00 14 Mn++ 0.1664488E-02 0.2216406E-08 0.1664486E-02 0.0000000E+00 15 HPO4-- 0.5680814E-03 0.5488269E-07 0.5680266E-03 0.0000000E+00 Chg. balance for solid moles: 0.2194E-15 Mass of aqueous solution: 0.990498E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 95.9990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 0.9937E-01 -1.003 26.06 1.416 24.88 10.00 andradite 0.1078E-01 -1.967 5.481 0.739 5.233 1.424 grossular 0.2052E-02 -2.688 0.9242 -0.034 0.8824 0.2572 apatite-OH 0.1893E-03 -3.723 0.9511E-01 -1.022 0.9081E-01 0.3022E-01 clinochlore 0.1524E-01 -1.817 8.470 0.928 8.087 3.222 daphnite 0.4337E-02 -2.363 3.095 0.491 2.955 0.9378 chlorite-Mn 0.3329E-03 -3.478 0.2360 -0.627 0.2253 0.7521E-01 microcline 0.1771E-01 -1.752 4.930 0.693 4.707 1.926 stilbite 0.7097E-01 -1.149 50.01 1.699 47.75 23.33 stilpnomelane-Fe 0.5039E-02 -2.298 5.431 0.735 5.186 1.876 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8402E+00 0.8402E+00 1.0000 -0.076 grossular 0.1598E+00 0.1598E+00 1.0000 -0.796 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.7654E+00 0.7654E+00 1.0000 -0.116 daphnite 0.2179E+00 0.2179E+00 1.0000 -0.662 chlorite-Mn 0.1672E-01 0.1672E-01 1.0000 -1.777 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 104.733670 g Volume = 43.078323 cm3 Porosity: -9.3370% V(tot) - V(min): -.36787E+01 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 95.9990000 g log = 1.9823 Original solution: 1000.0103000 g Original solution / Rock added: 10.42 (Water/Rock Ratio), log = 1.0177 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0418 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9796E+00 0.9857 0.1006E+01 0.1021E+01 CO2,gas 0.2257E-07 1.0070 0.2367E-07 0.2351E-07 CH4,gas 0.1213E-01 1.0125 0.1279E-01 0.1263E-01 H2,gas 0.8228E-02 1.0006 0.8577E-02 0.8572E-02 H2S,gas 0.1366E-06 0.9960 0.1417E-06 0.1423E-06 S2,gas 0.9835E-29 1.0000 0.1025E-28 0.1025E-28 CO,gas 0.5194E-13 1.0000 0.5411E-13 0.5411E-13 SO3,gas 0.7007E-47 1.0000 0.7300E-47 0.7300E-47 SO2,gas 0.2338E-26 1.0000 0.2436E-26 0.2436E-26 HCl,gas 0.2788E-17 1.0000 0.2905E-17 0.2905E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 16 albite -0.38 -0.38 0.00 0.000 -0.94784E-12 22 andradite 39.01 39.01 0.00 0.000 0.00000E+00 23 grossular 32.73 32.73 0.00 0.000 0.00000E+00 32 apatite-OH -18.15 -18.15 0.00 0.000 -0.60662E-11 46 clinochlore 39.07 39.07 0.00 0.000 0.12132E-10 47 daphnite 28.97 28.97 0.00 0.000 0.12132E-10 48 chlorite-Mn 46.87 46.87 0.00 0.000 0.24265E-10 116 microcline -2.49 -2.49 0.00 0.000 0.15165E-11 163 stilbite -7.52 -7.52 0.00 0.000 0.15165E-10 164 stilpnomelane-Fe 13.02 13.02 0.00 0.000 0.21232E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -15.98 -9.32 -3.108 0.15922E+05 -7.626 3 CH4,gas 4.54 0.95 -3.59 -0.898 0.61334E+04 -1.893 4 H2,gas 8.00 4.23 -3.77 -2.152 0.64297E+04 -2.067 5 H2S,gas -6.23 -14.78 -8.55 -4.274 0.14595E+05 -6.849 6 S2,gas -7.34 -38.02 -30.69 -4.721 0.52400E+05 -28.989 7 CO,gas 3.21 -11.75 -14.97 -4.605 0.25554E+05 -13.267 8 SO3,gas 17.12 -31.71 -48.84 -12.209 0.83386E+05 -47.137 9 SO2,gas 0.83 -27.48 -28.31 -7.550 0.48343E+05 -26.613 10 HCl,gas 5.19 -14.05 -19.24 -9.618 0.32845E+05 -17.537 11 acmite 7.71 6.62 -1.08 -0.113 0.18523E+04 15 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 19 spessartine 24.46 19.61 -4.85 -0.242 0.82792E+04 20 analcite 3.32 2.77 -0.56 -0.062 0.94992E+03 26 annite 20.12 17.68 -2.44 -0.136 0.41706E+04 27 phlogopite 27.06 25.38 -1.68 -0.094 0.28754E+04 29 anorthite 12.71 8.22 -4.49 -0.345 0.76587E+04 35 aragonite 0.97 -2.95 -3.92 -1.307 0.66929E+04 36 brucite 12.57 9.29 -3.28 -0.656 0.55997E+04 37 calcite 0.81 -2.95 -3.76 -1.255 0.64286E+04 38 carnegieite-low 9.02 5.91 -3.11 -0.444 0.53075E+04 39 carnegieite-high 10.09 5.91 -4.18 -0.597 0.71345E+04 40 carpholite-Mg 8.58 4.48 -4.10 -0.273 0.70002E+04 41 carpholite-Fe 6.71 1.92 -4.80 -0.320 0.81906E+04 42 celadonite 5.34 3.65 -1.69 -0.099 0.28830E+04 43 celadonite-Fe 3.88 1.09 -2.79 -0.164 0.47638E+04 44 chrysotile 23.89 21.57 -2.32 -0.194 0.39684E+04 49 chlorite-Al-free 47.17 43.14 -4.04 -0.168 0.68919E+04 51 chloritoid-Fe 9.17 5.07 -4.11 -0.274 0.70151E+04 52 chloritoid-Mn 11.40 7.53 -3.87 -0.258 0.66082E+04 54 coesite -2.38 -3.15 -0.77 -0.258 0.13204E+04 61 cristobalite -2.56 -3.15 -0.59 -0.196 0.10058E+04 63 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71234E+04 65 diaspore 2.87 0.75 -2.13 -0.355 0.36329E+04 66 diamond -3.10 -7.52 -4.41 -1.261 0.75372E+04 67 diopside 16.18 16.02 -0.16 -0.016 0.27234E+03 68 hedenbergite 14.21 13.46 -0.75 -0.075 0.12857E+04 71 enstatite 17.26 12.28 -4.99 -0.499 0.85129E+04 73 clinoenstatite 17.17 12.28 -4.89 -0.489 0.83445E+04 75 epidote 24.67 22.71 -1.96 -0.095 0.33422E+04 76 clinozoisite 22.81 18.85 -3.95 -0.180 0.67493E+04 77 epidote-Fe 29.84 26.57 -3.27 -0.170 0.55816E+04 78 fayalite 14.05 10.30 -3.75 -0.536 0.64034E+04 79 ferrosilite 11.15 7.15 -4.00 -0.400 0.68356E+04 83 gibbsite 4.08 0.75 -3.33 -0.476 0.56915E+04 84 glaucophane 22.97 20.80 -2.17 -0.059 0.37125E+04 85 glaucophane-Fe 17.28 13.10 -4.18 -0.113 0.71287E+04 86 graphite -3.55 -7.52 -3.97 -1.134 0.67794E+04 87 greenalite 16.14 13.87 -2.27 -0.189 0.38776E+04 90 hematite 12.57 9.21 -3.36 -0.407 0.57293E+04 91 heulandite -5.83 -7.52 -1.69 -0.077 0.28938E+04 95 jadeite 4.22 2.77 -1.45 -0.145 0.24754E+04 97 kalsilite 7.58 3.81 -3.77 -0.539 0.64399E+04 98 kaolinite -1.33 -4.81 -3.47 -0.316 0.59317E+04 101 laumontite 2.88 1.93 -0.96 -0.064 0.16345E+04 102 lawsonite 9.62 8.22 -1.39 -0.093 0.23753E+04 103 leucite 4.12 0.66 -3.46 -0.346 0.59010E+04 105 lizardite 23.24 21.57 -1.68 -0.140 0.28610E+04 107 magnetite 20.09 15.93 -4.15 -0.339 0.70931E+04 108 minnesotaite 10.39 7.57 -2.82 -0.166 0.48123E+04 112 manganosite 14.06 9.19 -4.87 -1.217 0.83152E+04 120 muscovite 2.58 -0.99 -3.58 -0.210 0.61074E+04 121 paragonite 4.24 1.11 -3.13 -0.184 0.53465E+04 122 nepheline 8.34 5.91 -2.42 -0.346 0.41398E+04 128 periclase-Fe 11.63 6.72 -4.90 -1.226 0.83737E+04 134 phlogopite-Na 29.65 27.48 -2.16 -0.120 0.36942E+04 136 prehnite 19.37 18.11 -1.26 -0.074 0.21595E+04 137 prehnite-Fe 22.50 21.97 -0.53 -0.032 0.90728E+03 138 pumpellyite-Fe 46.27 43.68 -2.59 -0.057 0.44166E+04 139 pumpellyite-Mg 48.99 46.25 -2.75 -0.061 0.46879E+04 143 pyrrhotite -4.26 -8.06 -3.80 -1.265 0.64800E+04 144 pyrrhotiteFe0.875 -6.02 -9.42 -3.40 -1.252 0.58118E+04 145 pyroxmangite 7.40 6.04 -1.36 -0.272 0.23219E+04 146 pyrophyllite -6.18 -11.11 -4.93 -0.308 0.84173E+04 147 quartz -2.99 -3.15 -0.16 -0.053 0.27313E+03 152 rhodonite 7.45 6.04 -1.41 -0.281 0.24022E+04 153 sanidine -1.28 -2.49 -1.21 -0.093 0.20677E+04 165 stilpnomelane-Mg 27.44 25.85 -1.59 -0.048 0.27175E+04 171 talc 16.49 15.27 -1.22 -0.072 0.20858E+04 174 tephroite 18.09 15.23 -2.86 -0.408 0.48812E+04 178 tridymite -2.63 -3.15 -0.52 -0.174 0.89310E+03 179 tremolite 47.87 47.31 -0.56 -0.015 0.94943E+03 180 ferroactinolite 38.45 34.48 -3.97 -0.107 0.67822E+04 181 troilite-low -4.41 -8.06 -3.64 -1.215 0.62228E+04 187 wairakite 3.95 1.93 -2.02 -0.119 0.34565E+04 188 walstromite 11.51 9.88 -1.63 -0.325 0.27780E+04 189 wollastonite 10.46 9.88 -0.58 -0.116 0.98848E+03 190 pseudo-wollastonite 11.00 9.88 -1.12 -0.224 0.19083E+04 191 zoisite 22.85 18.85 -4.00 -0.182 0.68234E+04 192 akaganeite 7.75 4.61 -3.15 -0.681 0.53772E+04 199 chalcedony -2.80 -3.15 -0.35 -0.116 0.59243E+03 201 montmorillonite-Ca -2.29 -6.14 -3.85 -0.238 0.65659E+04 202 montmorillonite-K -2.24 -6.24 -4.00 -0.245 0.68272E+04 203 montmorillonite-Mg -2.48 -6.75 -4.27 -0.264 0.72973E+04 204 montmorillonite-Na -2.04 -5.54 -3.50 -0.215 0.59821E+04 205 nontronite-Ca 3.21 0.05 -3.17 -0.205 0.54052E+04 206 nontronite-H 2.53 -2.10 -4.63 -0.311 0.79124E+04 207 nontronite-K 3.34 -0.05 -3.39 -0.218 0.57898E+04 208 nontronite-Mg 3.07 -0.57 -3.64 -0.236 0.62207E+04 209 nontronite-Na 3.52 0.64 -2.88 -0.185 0.49107E+04 224 tobermorite 9.82 7.71 -2.12 -0.578 0.36149E+04 230 alabandite -0.98 -5.59 -4.61 -1.537 0.78744E+04 233 boehmite 4.41 0.75 -3.66 -0.610 0.62498E+04 235 ferrous-oxide 9.81 6.72 -3.09 -0.772 0.52746E+04 240 silica-amorphous -2.09 -3.15 -1.06 -0.353 0.18066E+04 242 an20ab80 2.02 1.34 -0.68 -0.052 0.11609E+04 243 an25ab75 2.65 1.77 -0.88 -0.067 0.14981E+04 244 an30ab70 3.28 2.20 -1.08 -0.083 0.18449E+04 245 tr.625ac.25prg.125 45.16 45.05 -0.11 -0.003 0.19462E+03 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 4.0000000 g Current total amount of reactant added: 95.9990000 g New total amount of reactant added: 99.9990000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.7352E-13 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 12 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 99.9990000 Water: Moles liquid = 0.5486E+02 kg liquid = 0.9884E+00 Moles total = 0.5425E+02 kg total = 0.9774E+00 Activity = 1.0000 Stoichiometric ionic strength = .1121276E-01 Osmotic coef. = 0.9681 True ionic strength = .1980672E-01 Chg. balance for total moles = -.7352E-13 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.90650E-10 -10.0426 0.76219E-10 -10.1179 0.84081E+00 -0.0753 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13896E-03 -3.8571 0.11614E-03 -3.9350 0.83579E+00 -0.0779 4 SO4-- 0.25420E-11 -11.5948 0.13237E-11 -11.8782 0.52075E+00 -0.2834 5 HCO3- 0.81940E-06 -6.0865 0.68584E-06 -6.1638 0.83701E+00 -0.0773 6 HS- 0.25799E-04 -4.5884 0.21566E-04 -4.6662 0.83591E+00 -0.0778 7 Al+++ 0.98081E-29 -29.0084 0.22804E-29 -29.6420 0.23250E+00 -0.6336 8 H4SiO4 0.71945E-03 -3.1430 0.71945E-03 -3.1430 0.10000E+01 0.0000 9 Ca++ 0.12764E-06 -6.8940 0.65985E-07 -7.1806 0.51696E+00 -0.2865 10 Mg++ 0.22579E-10 -10.6463 0.11619E-10 -10.9348 0.51461E+00 -0.2885 11 Fe++ 0.59783E-13 -13.2234 0.30798E-13 -13.5115 0.51517E+00 -0.2880 12 K+ 0.15485E-03 -3.8101 0.12964E-03 -3.8872 0.83720E+00 -0.0772 13 Na+ 0.19650E-01 -1.7066 0.16420E-01 -1.7846 0.83564E+00 -0.0780 14 Mn++ 0.17868E-10 -10.7479 0.92124E-11 -11.0356 0.51559E+00 -0.2877 15 HPO4-- 0.51187E-07 -7.2908 0.26659E-07 -7.5741 0.52082E+00 -0.2833 16 HSiO3- 0.10545E-01 -1.9769 0.88138E-02 -2.0548 0.83579E+00 -0.0779 17 Ca(HSiO3)+ 0.15817E-07 -7.8009 0.13245E-07 -7.8780 0.83738E+00 -0.0771 18 Mg(HSiO3)+ 0.34662E-11 -11.4601 0.29025E-11 -11.5372 0.83738E+00 -0.0771 19 NaHSiO3,aq 0.23407E-02 -2.6307 0.23407E-02 -2.6307 0.10000E+01 0.0000 20 AlO+ 0.63773E-16 -16.1954 0.53402E-16 -16.2724 0.83738E+00 -0.0771 22 HAlO2,aq 0.13953E-09 -9.8553 0.13953E-09 -9.8553 0.10000E+01 0.0000 23 AlO2- 0.48572E-05 -5.3136 0.40523E-05 -5.3923 0.83430E+00 -0.0787 24 CH4,aq 0.10891E-04 -4.9629 0.10854E-04 -4.9644 0.99658E+00 -0.0015 25 C2H6,aq 0.24664E-14 -14.6079 0.24580E-14 -14.6094 0.99658E+00 -0.0015 29 CO,aq 0.22990E-16 -16.6385 0.22990E-16 -16.6385 0.10000E+01 0.0000 30 CO2,aq 0.11208E-09 -9.9505 0.11170E-09 -9.9520 0.99658E+00 -0.0015 31 CO3-2 0.15125E-05 -5.8203 0.78596E-06 -6.1046 0.51965E+00 -0.2843 32 CaCO3,aq 0.65028E-09 -9.1869 0.65028E-09 -9.1869 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.13795E-11 -11.8603 0.11552E-11 -11.9374 0.83738E+00 -0.0771 34 CaCl+ 0.14811E-10 -10.8294 0.12402E-10 -10.9065 0.83738E+00 -0.0771 35 CaCl2,aq 0.34222E-15 -15.4657 0.34222E-15 -15.4657 0.10000E+01 0.0000 36 CaOH+ 0.73682E-07 -7.1326 0.61700E-07 -7.2097 0.83738E+00 -0.0771 37 CaSO4,aq 0.27736E-16 -16.5570 0.27736E-16 -16.5570 0.10000E+01 0.0000 38 HCl,aq 0.16222E-14 -14.7899 0.16222E-14 -14.7899 0.10000E+01 0.0000 43 FeCl+ 0.67614E-17 -17.1700 0.56618E-17 -17.2470 0.83738E+00 -0.0771 46 FeO,aq 0.20605E-09 -9.6860 0.20605E-09 -9.6860 0.10000E+01 0.0000 47 FeOH+ 0.15707E-10 -10.8039 0.13153E-10 -10.8810 0.83738E+00 -0.0771 48 HFeO2- 0.33842E-07 -7.4705 0.28285E-07 -7.5484 0.83579E+00 -0.0779 49 FeO+ 0.13089E-16 -16.8831 0.10960E-16 -16.9602 0.83738E+00 -0.0771 51 FeO2- 0.46190E-09 -9.3355 0.38605E-09 -9.4134 0.83579E+00 -0.0779 52 HFeO2,aq 0.37423E-11 -11.4269 0.37423E-11 -11.4269 0.10000E+01 0.0000 53 H2,aq 0.82214E-05 -5.0851 0.81933E-05 -5.0865 0.99658E+00 -0.0015 54 KCl,aq 0.27290E-09 -9.5640 0.27290E-09 -9.5640 0.10000E+01 0.0000 56 KOH,aq 0.72640E-06 -6.1388 0.72640E-06 -6.1388 0.10000E+01 0.0000 57 KSO4- 0.31862E-14 -14.4967 0.26630E-14 -14.5746 0.83579E+00 -0.0779 58 MgCO3,aq 0.28702E-13 -13.5421 0.28702E-13 -13.5421 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.24822E-15 -15.6052 0.20785E-15 -15.6822 0.83738E+00 -0.0771 60 MgCl+ 0.23638E-14 -14.6264 0.19794E-14 -14.7035 0.83738E+00 -0.0771 61 MgOH+ 0.71795E-10 -10.1439 0.60120E-10 -10.2210 0.83738E+00 -0.0771 63 MnO,aq 0.16422E-08 -8.7846 0.16422E-08 -8.7846 0.10000E+01 0.0000 64 MnOH+ 0.43647E-09 -9.3600 0.36549E-09 -9.4371 0.83738E+00 -0.0771 65 MnO2-2 0.18054E-10 -10.7434 0.93817E-11 -11.0277 0.51965E+00 -0.2843 66 HMnO2- 0.18744E-09 -9.7271 0.15666E-09 -9.8050 0.83579E+00 -0.0779 69 MnCl+ 0.78683E-14 -14.1041 0.65888E-14 -14.1812 0.83738E+00 -0.0771 71 NaCl,aq 0.63202E-06 -6.1993 0.63202E-06 -6.1993 0.10000E+01 0.0000 72 NaOH,aq 0.92561E-04 -4.0336 0.92561E-04 -4.0336 0.10000E+01 0.0000 74 OH- 0.90860E-02 -2.0416 0.75804E-02 -2.1203 0.83430E+00 -0.0787 79 HPO3-2 0.13099E-14 -14.8828 0.68070E-15 -15.1670 0.51965E+00 -0.2843 81 H2PO3- 0.12448E-18 -18.9049 0.10404E-18 -18.9828 0.83579E+00 -0.0779 82 H3PO4,aq 0.10832E-17 -17.9653 0.10832E-17 -17.9653 0.10000E+01 0.0000 83 H2PO4- 0.44806E-10 -10.3487 0.37484E-10 -10.4262 0.83658E+00 -0.0775 84 PO4-3 0.11691E-08 -8.9321 0.28538E-09 -9.5446 0.24409E+00 -0.6124 88 HP2O7-3 0.12402E-17 -17.9065 0.28862E-18 -18.5397 0.23273E+00 -0.6331 89 P2O7-4 0.11603E-16 -16.9354 0.90464E-18 -18.0435 0.77963E-01 -1.1081 90 H2S,aq 0.50975E-08 -8.2926 0.50801E-08 -8.2941 0.99658E+00 -0.0015 91 S2-2 0.24204E-14 -14.6161 0.12578E-14 -14.9004 0.51965E+00 -0.2843 97 SO3-2 0.26738E-17 -17.5729 0.14094E-17 -17.8510 0.52710E+00 -0.2781 99 HSO4- 0.11600E-18 -18.9355 0.97233E-19 -19.0122 0.83819E+00 -0.0767 Charge balance for all species = -.7241E-13 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.9064990E-10 -.2208862E-01 -.2222540E+02 0.0000 2 H2O 0.1000000E+01 0.5550457E+02 0.9981980E+06 0.0000 3 Cl- 0.1389626E-03 0.1395949E-03 0.4940477E+01 6.1829 4 SO4-- 0.2541985E-11 -.1294617E-04 -.1241474E+01 8.3577 5 HCO3- 0.8193959E-06 0.1322352E-04 0.8054636E+00 3.9542 6 HS- 0.2579895E-04 0.3875023E-04 0.1279326E+01 5.4517 7 Al+++ 0.9808054E-29 0.4857301E-05 0.1308301E+00 0.7118 8 H4SiO4 0.7194475E-03 0.1360558E-01 0.1305439E+04 -3.1430 9 Ca++ 0.1276404E-06 0.2178053E-06 0.8714067E-02 13.0553 10 Mg++ 0.2257860E-10 0.9787099E-10 0.2375314E-05 9.3010 11 Fe++ 0.5978251E-13 0.3452990E-07 0.1925048E-02 6.7244 12 K+ 0.1548536E-03 0.1555803E-03 0.6072953E+01 6.2307 13 Na+ 0.1964983E-01 0.2208374E-01 0.5068205E+03 8.3333 14 Mn++ 0.1786755E-10 0.2302082E-08 0.1262525E-03 9.2002 15 HPO4-- 0.5118737E-07 0.5240130E-07 0.5020705E-02 12.6617 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.1655822E+01 -.2183217E-01 -.1633990E+01 0.0000000E+00 2 H2O 0.5425472E+02 0.5486017E+02 -.6054458E+00 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.2796818E-02 -.1279587E-04 0.2809614E-02 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.2771313E-02 0.3830034E-04 -.2809614E-02 0.0000000E+00 7 Al+++ 0.3260709E+00 0.4800908E-05 0.3260661E+00 0.0000000E+00 8 H4SiO4 0.1041268E+01 0.1344762E-01 0.1027820E+01 0.0000000E+00 9 Ca++ 0.1150276E+00 0.2152766E-06 0.1150274E+00 0.0000000E+00 10 Mg++ 0.7936429E-01 0.9673472E-10 0.7936429E-01 0.0000000E+00 11 Fe++ 0.7130015E-01 0.3412901E-07 0.7130011E-01 0.0000000E+00 12 K+ 0.2123121E-01 0.1537740E-03 0.2107744E-01 0.0000000E+00 13 Na+ 0.1256832E+00 0.2182734E-01 0.1038558E+00 0.0000000E+00 14 Mn++ 0.1733842E-02 0.2275355E-08 0.1733840E-02 0.0000000E+00 15 HPO4-- 0.5917517E-03 0.5179293E-07 0.5917000E-03 0.0000000E+00 Chg. balance for solid moles: 0.1952E-17 Mass of aqueous solution: 0.990107E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 99.9990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 0.1039 -0.984 27.23 1.435 24.96 10.45 andradite 0.1124E-01 -1.949 5.711 0.757 5.235 1.484 grossular 0.2203E-02 -2.657 0.9924 -0.003 0.9096 0.2761 apatite-OH 0.1972E-03 -3.705 0.9907E-01 -1.004 0.9082E-01 0.3148E-01 clinochlore 0.1587E-01 -1.799 8.823 0.946 8.087 3.356 daphnite 0.4414E-02 -2.355 3.150 0.498 2.887 0.9544 chlorite-Mn 0.3468E-03 -3.460 0.2458 -0.609 0.2254 0.7835E-01 microcline 0.1840E-01 -1.735 5.122 0.709 4.695 2.001 stilbite 0.7372E-01 -1.132 51.95 1.716 47.62 24.23 stilpnomelane-Fe 0.5350E-02 -2.272 5.768 0.761 5.287 1.992 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8361E+00 0.8361E+00 1.0000 -0.078 grossular 0.1639E+00 0.1639E+00 1.0000 -0.785 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.7693E+00 0.7693E+00 1.0000 -0.114 daphnite 0.2139E+00 0.2139E+00 1.0000 -0.670 chlorite-Mn 0.1681E-01 0.1681E-01 1.0000 -1.775 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 109.093096 g Volume = 44.857539 cm3 Porosity: -9.4097% V(tot) - V(min): -.38579E+01 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 99.9990000 g log = 2.0000 Original solution: 1000.0103000 g Original solution / Rock added: 10.00 (Water/Rock Ratio), log = 1.0000 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0472 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9747E+00 0.9856 0.1006E+01 0.1021E+01 CO2,gas 0.1133E-07 1.0069 0.1195E-07 0.1187E-07 CH4,gas 0.1507E-01 1.0124 0.1598E-01 0.1578E-01 H2,gas 0.1027E-01 1.0006 0.1076E-01 0.1075E-01 H2S,gas 0.1339E-06 0.9959 0.1396E-06 0.1402E-06 S2,gas 0.6041E-29 1.0000 0.6326E-29 0.6326E-29 CO,gas 0.3271E-13 1.0000 0.3426E-13 0.3426E-13 SO3,gas 0.2777E-47 1.0000 0.2908E-47 0.2908E-47 SO2,gas 0.1162E-26 1.0000 0.1217E-26 0.1217E-26 HCl,gas 0.2733E-17 1.0000 0.2862E-17 0.2862E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 16 albite -0.38 -0.38 0.00 0.000 -0.13080E-10 22 andradite 39.01 39.01 0.00 0.000 -0.24265E-10 23 grossular 32.73 32.73 0.00 0.000 -0.24265E-10 32 apatite-OH -18.15 -18.15 0.00 0.000 0.00000E+00 46 clinochlore 39.07 39.07 0.00 0.000 -0.48529E-10 47 daphnite 28.97 28.97 0.00 0.000 -0.42463E-10 48 chlorite-Mn 46.87 46.87 0.00 0.000 -0.36397E-10 116 microcline -2.49 -2.49 0.00 0.000 -0.10616E-10 163 stilbite -7.52 -7.52 0.00 0.000 -0.90992E-11 164 stilpnomelane-Fe 13.02 13.02 0.00 0.000 0.21232E-10 245 tr.625ac.25prg.125 45.16 45.18 0.02 0.000 -0.30797E+02 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -16.28 -9.62 -3.207 0.16429E+05 -7.923 3 CH4,gas 4.54 1.05 -3.50 -0.874 0.59685E+04 -1.797 4 H2,gas 8.00 4.33 -3.67 -2.096 0.62618E+04 -1.968 5 H2S,gas -6.23 -14.78 -8.55 -4.277 0.14606E+05 -6.855 6 S2,gas -7.34 -38.23 -30.90 -4.754 0.52757E+05 -29.199 7 CO,gas 3.21 -11.95 -15.16 -4.666 0.25892E+05 -13.465 8 SO3,gas 17.12 -32.11 -49.24 -12.309 0.84068E+05 -47.536 9 SO2,gas 0.83 -27.78 -28.61 -7.630 0.48857E+05 -26.915 10 HCl,gas 5.19 -14.05 -19.24 -9.621 0.32856E+05 -17.543 11 acmite 7.71 6.61 -1.10 -0.115 0.18855E+04 15 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 19 spessartine 24.46 19.60 -4.86 -0.243 0.83017E+04 20 analcite 3.32 2.76 -0.56 -0.063 0.96084E+03 26 annite 20.12 17.69 -2.44 -0.135 0.41606E+04 27 phlogopite 27.06 25.42 -1.65 -0.092 0.28138E+04 29 anorthite 12.71 8.19 -4.52 -0.347 0.77133E+04 35 aragonite 0.97 -3.23 -4.19 -1.398 0.71593E+04 36 brucite 12.57 9.30 -3.27 -0.654 0.55792E+04 37 calcite 0.81 -3.23 -4.04 -1.346 0.68951E+04 38 carnegieite-low 9.02 5.90 -3.12 -0.446 0.53293E+04 39 carnegieite-high 10.09 5.90 -4.19 -0.599 0.71563E+04 40 carpholite-Mg 8.58 4.44 -4.14 -0.276 0.70747E+04 41 carpholite-Fe 6.71 1.86 -4.85 -0.323 0.82823E+04 42 celadonite 5.34 3.67 -1.67 -0.098 0.28516E+04 43 celadonite-Fe 3.88 1.09 -2.78 -0.164 0.47495E+04 44 chrysotile 23.89 21.62 -2.28 -0.190 0.38849E+04 49 chlorite-Al-free 47.17 43.23 -3.94 -0.164 0.67250E+04 51 chloritoid-Fe 9.17 5.01 -4.17 -0.278 0.71177E+04 52 chloritoid-Mn 11.40 7.48 -3.92 -0.261 0.66936E+04 54 coesite -2.38 -3.14 -0.77 -0.256 0.13095E+04 61 cristobalite -2.56 -3.14 -0.58 -0.194 0.99488E+03 63 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71234E+04 65 diaspore 2.87 0.71 -2.16 -0.360 0.36913E+04 66 diamond -3.10 -7.62 -4.51 -1.290 0.77082E+04 67 diopside 16.18 16.07 -0.11 -0.011 0.18952E+03 68 hedenbergite 14.21 13.49 -0.71 -0.071 0.12201E+04 71 enstatite 17.26 12.32 -4.95 -0.495 0.84500E+04 73 clinoenstatite 17.17 12.32 -4.85 -0.485 0.82815E+04 75 epidote 24.67 22.66 -2.01 -0.097 0.34260E+04 76 clinozoisite 22.81 18.82 -3.99 -0.181 0.68110E+04 77 epidote-Fe 29.84 26.51 -3.33 -0.173 0.56876E+04 78 fayalite 14.05 10.31 -3.74 -0.534 0.63858E+04 79 ferrosilite 11.15 7.16 -3.99 -0.399 0.68071E+04 83 gibbsite 4.08 0.71 -3.37 -0.481 0.57499E+04 84 glaucophane 22.97 20.85 -2.13 -0.057 0.36290E+04 85 glaucophane-Fe 17.28 13.12 -4.16 -0.112 0.70969E+04 86 graphite -3.55 -7.62 -4.07 -1.163 0.69504E+04 87 greenalite 16.14 13.89 -2.25 -0.188 0.38458E+04 90 hematite 12.57 9.12 -3.45 -0.418 0.58905E+04 91 heulandite -5.83 -7.52 -1.69 -0.077 0.28938E+04 95 jadeite 4.22 2.76 -1.46 -0.146 0.24863E+04 97 kalsilite 7.58 3.80 -3.78 -0.541 0.64618E+04 98 kaolinite -1.33 -4.86 -3.53 -0.321 0.60267E+04 101 laumontite 2.88 1.91 -0.98 -0.065 0.16673E+04 102 lawsonite 9.62 8.19 -1.42 -0.095 0.24299E+04 103 leucite 4.12 0.66 -3.46 -0.346 0.59119E+04 105 lizardite 23.24 21.62 -1.63 -0.136 0.27775E+04 107 magnetite 20.09 15.84 -4.25 -0.347 0.72511E+04 108 minnesotaite 10.39 7.60 -2.79 -0.164 0.47586E+04 112 manganosite 14.06 9.20 -4.86 -1.214 0.82947E+04 120 muscovite 2.58 -1.06 -3.65 -0.214 0.62242E+04 121 paragonite 4.24 1.04 -3.20 -0.188 0.54633E+04 122 nepheline 8.34 5.90 -2.44 -0.348 0.41617E+04 128 periclase-Fe 11.63 6.72 -4.90 -1.226 0.83703E+04 134 phlogopite-Na 29.65 27.52 -2.13 -0.118 0.36326E+04 136 prehnite 19.37 18.11 -1.27 -0.075 0.21627E+04 137 prehnite-Fe 22.50 21.95 -0.55 -0.033 0.93271E+03 138 pumpellyite-Fe 46.27 43.65 -2.62 -0.058 0.44781E+04 139 pumpellyite-Mg 48.99 46.22 -2.77 -0.062 0.47322E+04 143 pyrrhotite -4.26 -8.06 -3.80 -1.266 0.64875E+04 144 pyrrhotiteFe0.875 -6.02 -9.44 -3.42 -1.258 0.58406E+04 145 pyroxmangite 7.40 6.06 -1.34 -0.268 0.22905E+04 146 pyrophyllite -6.18 -11.15 -4.97 -0.311 0.84905E+04 147 quartz -2.99 -3.14 -0.15 -0.051 0.26221E+03 152 rhodonite 7.45 6.06 -1.39 -0.278 0.23707E+04 153 sanidine -1.28 -2.49 -1.21 -0.093 0.20677E+04 165 stilpnomelane-Mg 27.44 25.90 -1.54 -0.046 0.26315E+04 171 talc 16.49 15.33 -1.16 -0.068 0.19805E+04 174 tephroite 18.09 15.26 -2.83 -0.404 0.48292E+04 178 tridymite -2.63 -3.14 -0.52 -0.172 0.88219E+03 179 tremolite 47.87 47.47 -0.40 -0.011 0.67851E+03 180 ferroactinolite 38.45 34.59 -3.86 -0.104 0.65972E+04 181 troilite-low -4.41 -8.06 -3.65 -1.216 0.62303E+04 187 wairakite 3.95 1.91 -2.04 -0.120 0.34892E+04 188 walstromite 11.51 9.91 -1.60 -0.319 0.27267E+04 189 wollastonite 10.46 9.91 -0.55 -0.110 0.93712E+03 190 pseudo-wollastonite 11.00 9.91 -1.09 -0.218 0.18569E+04 191 zoisite 22.85 18.82 -4.03 -0.183 0.68851E+04 192 akaganeite 7.75 4.56 -3.20 -0.691 0.54578E+04 199 chalcedony -2.80 -3.14 -0.34 -0.114 0.58151E+03 201 montmorillonite-Ca -2.29 -6.16 -3.87 -0.239 0.66063E+04 202 montmorillonite-K -2.24 -6.26 -4.02 -0.246 0.68659E+04 203 montmorillonite-Mg -2.48 -6.78 -4.30 -0.266 0.73411E+04 204 montmorillonite-Na -2.04 -5.56 -3.53 -0.216 0.60208E+04 205 nontronite-Ca 3.21 -0.03 -3.24 -0.210 0.55390E+04 206 nontronite-H 2.53 -2.18 -4.72 -0.316 0.80529E+04 207 nontronite-K 3.34 -0.13 -3.47 -0.223 0.59218E+04 208 nontronite-Mg 3.07 -0.65 -3.72 -0.242 0.63578E+04 209 nontronite-Na 3.52 0.57 -2.95 -0.190 0.50427E+04 224 tobermorite 9.82 7.73 -2.09 -0.571 0.35703E+04 230 alabandite -0.98 -5.58 -4.61 -1.535 0.78647E+04 233 boehmite 4.41 0.71 -3.69 -0.616 0.63083E+04 235 ferrous-oxide 9.81 6.72 -3.09 -0.772 0.52713E+04 240 silica-amorphous -2.09 -3.14 -1.05 -0.351 0.17957E+04 242 an20ab80 2.02 1.33 -0.69 -0.053 0.11718E+04 243 an25ab75 2.65 1.76 -0.89 -0.068 0.15117E+04 244 an30ab70 3.28 2.19 -1.09 -0.084 0.18613E+04 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 10 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 99.9990000 Water: Moles liquid = 0.5486E+02 kg liquid = 0.9884E+00 Moles total = 0.5425E+02 kg total = 0.9774E+00 Activity = 1.0000 Stoichiometric ionic strength = .1117672E-01 Osmotic coef. = 0.9680 True ionic strength = .1974939E-01 Chg. balance for total moles = -.7352E-13 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.90763E-10 -10.0421 0.76328E-10 -10.1173 0.84096E+00 -0.0752 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13896E-03 -3.8571 0.11617E-03 -3.9349 0.83596E+00 -0.0778 4 SO4-- 0.28117E-11 -11.5510 0.14653E-11 -11.8341 0.52114E+00 -0.2830 5 HCO3- 0.89017E-06 -6.0505 0.74522E-06 -6.1277 0.83716E+00 -0.0772 6 HS- 0.25799E-04 -4.5884 0.21570E-04 -4.6662 0.83608E+00 -0.0778 7 Al+++ 0.99474E-29 -29.0023 0.23168E-29 -29.6351 0.23290E+00 -0.6328 8 H4SiO4 0.71768E-03 -3.1441 0.71768E-03 -3.1441 0.10000E+01 0.0000 9 Ca++ 0.12717E-06 -6.8956 0.65790E-07 -7.1818 0.51736E+00 -0.2862 10 Mg++ 0.22537E-10 -10.6471 0.11607E-10 -10.9353 0.51501E+00 -0.2882 11 Fe++ 0.59892E-13 -13.2226 0.30879E-13 -13.5103 0.51557E+00 -0.2877 12 K+ 0.15441E-03 -3.8113 0.12929E-03 -3.8884 0.83736E+00 -0.0771 13 Na+ 0.19593E-01 -1.7079 0.16376E-01 -1.7858 0.83581E+00 -0.0779 14 Mn++ 0.17848E-10 -10.7484 0.92097E-11 -11.0358 0.51600E+00 -0.2874 15 HPO4-- 0.51500E-07 -7.2882 0.26842E-07 -7.5712 0.52121E+00 -0.2830 16 HSiO3- 0.10502E-01 -1.9787 0.87795E-02 -2.0565 0.83596E+00 -0.0778 17 Ca(HSiO3)+ 0.15706E-07 -7.8039 0.13154E-07 -7.8809 0.83754E+00 -0.0770 18 Mg(HSiO3)+ 0.34483E-11 -11.4624 0.28881E-11 -11.5394 0.83754E+00 -0.0770 19 NaHSiO3,aq 0.23253E-02 -2.6335 0.23253E-02 -2.6335 0.10000E+01 0.0000 20 AlO+ 0.64593E-16 -16.1898 0.54099E-16 -16.2668 0.83754E+00 -0.0770 22 HAlO2,aq 0.14115E-09 -9.8503 0.14115E-09 -9.8503 0.10000E+01 0.0000 23 AlO2- 0.49055E-05 -5.3093 0.40935E-05 -5.3879 0.83446E+00 -0.0786 24 CH4,aq 0.10693E-04 -4.9709 0.10656E-04 -4.9724 0.99659E+00 -0.0015 25 C2H6,aq 0.24394E-14 -14.6127 0.24310E-14 -14.6142 0.99659E+00 -0.0015 29 CO,aq 0.24381E-16 -16.6129 0.24381E-16 -16.6129 0.10000E+01 0.0000 30 CO2,aq 0.12196E-09 -9.9138 0.12154E-09 -9.9153 0.99659E+00 -0.0015 31 CO3-2 0.16398E-05 -5.7852 0.85279E-06 -6.0692 0.52005E+00 -0.2840 32 CaCO3,aq 0.70349E-09 -9.1527 0.70349E-09 -9.1527 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.14942E-11 -11.8256 0.12515E-11 -11.9026 0.83754E+00 -0.0770 34 CaCl+ 0.14767E-10 -10.8307 0.12368E-10 -10.9077 0.83754E+00 -0.0770 35 CaCl2,aq 0.34135E-15 -15.4668 0.34135E-15 -15.4668 0.10000E+01 0.0000 36 CaOH+ 0.73345E-07 -7.1346 0.61430E-07 -7.2116 0.83754E+00 -0.0770 37 CaSO4,aq 0.30611E-16 -16.5141 0.30611E-16 -16.5141 0.10000E+01 0.0000 38 HCl,aq 0.16248E-14 -14.7892 0.16248E-14 -14.7892 0.10000E+01 0.0000 43 FeCl+ 0.67791E-17 -17.1688 0.56777E-17 -17.2458 0.83754E+00 -0.0770 46 FeO,aq 0.20599E-09 -9.6861 0.20599E-09 -9.6861 0.10000E+01 0.0000 47 FeOH+ 0.15723E-10 -10.8035 0.13169E-10 -10.8805 0.83754E+00 -0.0770 48 HFeO2- 0.33779E-07 -7.4714 0.28238E-07 -7.5492 0.83596E+00 -0.0778 49 FeO+ 0.13271E-16 -16.8771 0.11115E-16 -16.9541 0.83754E+00 -0.0770 51 FeO2- 0.46699E-09 -9.3307 0.39039E-09 -9.4085 0.83596E+00 -0.0778 52 HFeO2,aq 0.37898E-11 -11.4214 0.37898E-11 -11.4214 0.10000E+01 0.0000 53 H2,aq 0.80127E-05 -5.0962 0.79853E-05 -5.0977 0.99659E+00 -0.0015 54 KCl,aq 0.27222E-09 -9.5651 0.27222E-09 -9.5651 0.10000E+01 0.0000 56 KOH,aq 0.72339E-06 -6.1406 0.72339E-06 -6.1406 0.10000E+01 0.0000 57 KSO4- 0.35167E-14 -14.4539 0.29398E-14 -14.5317 0.83596E+00 -0.0778 58 MgCO3,aq 0.31109E-13 -13.5071 0.31109E-13 -13.5071 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.26937E-15 -15.5697 0.22560E-15 -15.6467 0.83754E+00 -0.0770 60 MgCl+ 0.23613E-14 -14.6269 0.19776E-14 -14.7039 0.83754E+00 -0.0770 61 MgOH+ 0.71602E-10 -10.1451 0.59969E-10 -10.2221 0.83754E+00 -0.0770 63 MnO,aq 0.16371E-08 -8.7859 0.16371E-08 -8.7859 0.10000E+01 0.0000 64 MnOH+ 0.43563E-09 -9.3609 0.36486E-09 -9.4379 0.83754E+00 -0.0770 65 MnO2-2 0.17932E-10 -10.7464 0.93254E-11 -11.0303 0.52005E+00 -0.2840 66 HMnO2- 0.18654E-09 -9.7292 0.15594E-09 -9.8070 0.83596E+00 -0.0778 69 MnCl+ 0.78661E-14 -14.1042 0.65882E-14 -14.1812 0.83754E+00 -0.0770 71 NaCl,aq 0.63044E-06 -6.2004 0.63044E-06 -6.2004 0.10000E+01 0.0000 72 NaOH,aq 0.92179E-04 -4.0354 0.92179E-04 -4.0354 0.10000E+01 0.0000 74 OH- 0.90712E-02 -2.0423 0.75696E-02 -2.1209 0.83446E+00 -0.0786 79 HPO3-2 0.12844E-14 -14.8913 0.66797E-15 -15.1752 0.52005E+00 -0.2840 81 H2PO3- 0.12230E-18 -18.9126 0.10224E-18 -18.9904 0.83596E+00 -0.0778 82 H3PO4,aq 0.10937E-17 -17.9611 0.10937E-17 -17.9611 0.10000E+01 0.0000 83 H2PO4- 0.45170E-10 -10.3452 0.37795E-10 -10.4226 0.83674E+00 -0.0774 84 PO4-3 0.11736E-08 -8.9305 0.28692E-09 -9.5422 0.24449E+00 -0.6117 88 HP2O7-3 0.12568E-17 -17.9007 0.29301E-18 -18.5331 0.23313E+00 -0.6324 89 P2O7-4 0.11728E-16 -16.9308 0.91709E-18 -18.0376 0.78197E-01 -1.1068 90 H2S,aq 0.51057E-08 -8.2919 0.50883E-08 -8.2934 0.99659E+00 -0.0015 91 S2-2 0.24825E-14 -14.6051 0.12910E-14 -14.8891 0.52005E+00 -0.2840 97 SO3-2 0.28825E-17 -17.5402 0.15205E-17 -17.8180 0.52749E+00 -0.2778 99 HSO4- 0.12857E-18 -18.8909 0.10778E-18 -18.9674 0.83835E+00 -0.0766 Charge balance for all species = -.7220E-13 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.9076330E-10 -.2201525E-01 -.2215173E+02 0.0000 2 H2O 0.1000000E+01 0.5550462E+02 0.9982053E+06 0.0000 3 Cl- 0.1389634E-03 0.1395941E-03 0.4940483E+01 6.1824 4 SO4-- 0.2811661E-11 -.1269573E-04 -.1217465E+01 8.4005 5 HCO3- 0.8901691E-06 0.1322345E-04 0.8054646E+00 3.9896 6 HS- 0.2579881E-04 0.3849964E-04 0.1271061E+01 5.4512 7 Al+++ 0.9947372E-29 0.4905681E-05 0.1321340E+00 0.7168 8 H4SiO4 0.7176755E-03 0.1354535E-01 0.1299668E+04 -3.1441 9 Ca++ 0.1271656E-06 0.2169364E-06 0.8679362E-02 13.0528 10 Mg++ 0.2253667E-10 0.9762027E-10 0.2369245E-05 9.2993 11 Fe++ 0.5989178E-13 0.3447143E-07 0.1921801E-02 6.7243 12 K+ 0.1544050E-03 0.1551287E-03 0.6055365E+01 6.2289 13 Na+ 0.1959282E-01 0.2201093E-01 0.5051529E+03 8.3315 14 Mn++ 0.1784840E-10 0.2295036E-08 0.1258669E-03 9.1989 15 HPO4-- 0.5149953E-07 0.5271826E-07 0.5051108E-02 12.6634 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.1655822E+01 -.2175977E-01 -.1634062E+01 0.0000000E+00 2 H2O 0.5425472E+02 0.5486050E+02 -.6057800E+00 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.2796818E-02 -.1254840E-04 0.2809366E-02 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.2771313E-02 0.3805287E-04 -.2809366E-02 0.0000000E+00 7 Al+++ 0.3260709E+00 0.4848752E-05 0.3260661E+00 0.0000000E+00 8 H4SiO4 0.1041268E+01 0.1338816E-01 0.1027880E+01 0.0000000E+00 9 Ca++ 0.1150276E+00 0.2144189E-06 0.1150274E+00 0.0000000E+00 10 Mg++ 0.7936429E-01 0.9648742E-10 0.7936429E-01 0.0000000E+00 11 Fe++ 0.7130015E-01 0.3407140E-07 0.7130011E-01 0.0000000E+00 12 K+ 0.2123121E-01 0.1533285E-03 0.2107788E-01 0.0000000E+00 13 Na+ 0.1256832E+00 0.2175550E-01 0.1039277E+00 0.0000000E+00 14 Mn++ 0.1733842E-02 0.2268403E-08 0.1733840E-02 0.0000000E+00 15 HPO4-- 0.5917517E-03 0.5210649E-07 0.5916996E-03 0.0000000E+00 Chg. balance for solid moles: 0.1089E-15 Mass of aqueous solution: 0.990105E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 99.9990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 0.1039 -0.983 27.25 1.435 24.98 10.46 andradite 0.1124E-01 -1.949 5.711 0.757 5.235 1.484 grossular 0.2201E-02 -2.657 0.9912 -0.004 0.9086 0.2758 apatite-OH 0.1972E-03 -3.705 0.9907E-01 -1.004 0.9082E-01 0.3148E-01 clinochlore 0.1586E-01 -1.800 8.816 0.945 8.081 3.353 daphnite 0.4427E-02 -2.354 3.159 0.500 2.895 0.9572 chlorite-Mn 0.3468E-03 -3.460 0.2458 -0.609 0.2254 0.7835E-01 microcline 0.1841E-01 -1.735 5.125 0.710 4.697 2.002 stilbite 0.7369E-01 -1.133 51.93 1.715 47.60 24.22 stilpnomelane-Fe 0.5334E-02 -2.273 5.750 0.760 5.270 1.986 tr.625ac.25prg.125 0.1711E-04 -4.767 0.1462E-01 -1.835 0.1340E-01 0.4707E-02 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8362E+00 0.8362E+00 1.0000 -0.078 grossular 0.1638E+00 0.1638E+00 1.0000 -0.786 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.7686E+00 0.7686E+00 1.0000 -0.114 daphnite 0.2145E+00 0.2145E+00 1.0000 -0.668 chlorite-Mn 0.1681E-01 0.1681E-01 1.0000 -1.775 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 tr.625ac.25prg.125 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 109.094371 g Volume = 44.855920 cm3 Porosity: -9.4058% V(tot) - V(min): -.38563E+01 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 99.9990000 g log = 2.0000 Original solution: 1000.0103000 g Original solution / Rock added: 10.00 (Water/Rock Ratio), log = 1.0000 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0466 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9752E+00 0.9856 0.1006E+01 0.1021E+01 CO2,gas 0.1234E-07 1.0069 0.1300E-07 0.1291E-07 CH4,gas 0.1480E-01 1.0124 0.1569E-01 0.1549E-01 H2,gas 0.1001E-01 1.0006 0.1048E-01 0.1048E-01 H2S,gas 0.1342E-06 0.9959 0.1399E-06 0.1404E-06 S2,gas 0.6384E-29 1.0000 0.6682E-29 0.6682E-29 CO,gas 0.3471E-13 1.0000 0.3633E-13 0.3633E-13 SO3,gas 0.3084E-47 1.0000 0.3228E-47 0.3228E-47 SO2,gas 0.1258E-26 1.0000 0.1317E-26 0.1317E-26 HCl,gas 0.2739E-17 1.0000 0.2867E-17 0.2867E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 16 albite -0.38 -0.38 0.00 0.000 -0.94784E-12 22 andradite 39.01 39.01 0.00 0.000 0.00000E+00 23 grossular 32.73 32.73 0.00 0.000 -0.12132E-10 32 apatite-OH -18.15 -18.15 0.00 0.000 -0.60662E-11 46 clinochlore 39.07 39.07 0.00 0.000 0.24265E-10 47 daphnite 28.97 28.97 0.00 0.000 -0.30331E-10 48 chlorite-Mn 46.87 46.87 0.00 0.000 0.12132E-10 116 microcline -2.49 -2.49 0.00 0.000 0.13649E-10 163 stilbite -7.52 -7.52 0.00 0.000 -0.90992E-11 164 stilpnomelane-Fe 13.02 13.02 0.00 0.000 0.21232E-10 245 tr.625ac.25prg.125 45.16 45.16 0.00 0.000 0.12132E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -16.25 -9.58 -3.195 0.16366E+05 -7.886 3 CH4,gas 4.54 1.04 -3.50 -0.876 0.59821E+04 -1.805 4 H2,gas 8.00 4.32 -3.68 -2.102 0.62809E+04 -1.979 5 H2S,gas -6.23 -14.78 -8.55 -4.277 0.14604E+05 -6.854 6 S2,gas -7.34 -38.21 -30.87 -4.750 0.52717E+05 -29.175 7 CO,gas 3.21 -11.92 -15.14 -4.658 0.25849E+05 -13.440 8 SO3,gas 17.12 -32.07 -49.19 -12.298 0.83991E+05 -47.491 9 SO2,gas 0.83 -27.75 -28.58 -7.621 0.48799E+05 -26.881 10 HCl,gas 5.19 -14.05 -19.24 -9.621 0.32854E+05 -17.543 11 acmite 7.71 6.61 -1.10 -0.115 0.18828E+04 15 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 19 spessartine 24.46 19.60 -4.86 -0.243 0.82971E+04 20 analcite 3.32 2.76 -0.56 -0.062 0.95901E+03 26 annite 20.12 17.69 -2.44 -0.135 0.41612E+04 27 phlogopite 27.06 25.41 -1.65 -0.092 0.28226E+04 29 anorthite 12.71 8.20 -4.51 -0.347 0.77041E+04 35 aragonite 0.97 -3.19 -4.16 -1.386 0.71010E+04 36 brucite 12.57 9.30 -3.27 -0.654 0.55821E+04 37 calcite 0.81 -3.19 -4.00 -1.335 0.68368E+04 38 carnegieite-low 9.02 5.90 -3.12 -0.446 0.53256E+04 39 carnegieite-high 10.09 5.90 -4.19 -0.598 0.71526E+04 40 carpholite-Mg 8.58 4.44 -4.14 -0.276 0.70642E+04 41 carpholite-Fe 6.71 1.87 -4.84 -0.323 0.82690E+04 42 celadonite 5.34 3.67 -1.67 -0.098 0.28563E+04 43 celadonite-Fe 3.88 1.09 -2.78 -0.164 0.47516E+04 44 chrysotile 23.89 21.61 -2.28 -0.190 0.38973E+04 49 chlorite-Al-free 47.17 43.22 -3.95 -0.165 0.67498E+04 51 chloritoid-Fe 9.17 5.01 -4.16 -0.277 0.71027E+04 52 chloritoid-Mn 11.40 7.49 -3.91 -0.261 0.66807E+04 54 coesite -2.38 -3.14 -0.77 -0.256 0.13114E+04 61 cristobalite -2.56 -3.14 -0.58 -0.195 0.99671E+03 63 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71234E+04 65 diaspore 2.87 0.72 -2.16 -0.359 0.36828E+04 66 diamond -3.10 -7.60 -4.50 -1.286 0.76837E+04 67 diopside 16.18 16.06 -0.12 -0.012 0.20041E+03 68 hedenbergite 14.21 13.49 -0.72 -0.072 0.12283E+04 71 enstatite 17.26 12.31 -4.95 -0.495 0.84595E+04 73 clinoenstatite 17.17 12.31 -4.86 -0.486 0.82910E+04 75 epidote 24.67 22.67 -2.00 -0.097 0.34137E+04 76 clinozoisite 22.81 18.82 -3.98 -0.181 0.67995E+04 77 epidote-Fe 29.84 26.52 -3.32 -0.173 0.56745E+04 78 fayalite 14.05 10.30 -3.74 -0.534 0.63880E+04 79 ferrosilite 11.15 7.16 -3.99 -0.399 0.68111E+04 83 gibbsite 4.08 0.72 -3.36 -0.480 0.57413E+04 84 glaucophane 22.97 20.84 -2.13 -0.058 0.36415E+04 85 glaucophane-Fe 17.28 13.12 -4.16 -0.112 0.71011E+04 86 graphite -3.55 -7.60 -4.06 -1.159 0.69259E+04 87 greenalite 16.14 13.88 -2.25 -0.188 0.38500E+04 90 hematite 12.57 9.13 -3.44 -0.417 0.58719E+04 91 heulandite -5.83 -7.52 -1.69 -0.077 0.28938E+04 95 jadeite 4.22 2.76 -1.46 -0.146 0.24845E+04 97 kalsilite 7.58 3.80 -3.78 -0.540 0.64581E+04 98 kaolinite -1.33 -4.85 -3.52 -0.320 0.60132E+04 101 laumontite 2.88 1.91 -0.97 -0.065 0.16618E+04 102 lawsonite 9.62 8.20 -1.42 -0.095 0.24208E+04 103 leucite 4.12 0.66 -3.46 -0.346 0.59100E+04 105 lizardite 23.24 21.61 -1.63 -0.136 0.27900E+04 107 magnetite 20.09 15.85 -4.24 -0.346 0.72326E+04 108 minnesotaite 10.39 7.60 -2.79 -0.164 0.47665E+04 112 manganosite 14.06 9.20 -4.86 -1.215 0.82970E+04 120 muscovite 2.58 -1.05 -3.64 -0.214 0.62071E+04 121 paragonite 4.24 1.05 -3.19 -0.188 0.54462E+04 122 nepheline 8.34 5.90 -2.44 -0.348 0.41580E+04 128 periclase-Fe 11.63 6.72 -4.90 -1.226 0.83705E+04 134 phlogopite-Na 29.65 27.51 -2.13 -0.118 0.36414E+04 136 prehnite 19.37 18.11 -1.26 -0.074 0.21597E+04 137 prehnite-Fe 22.50 21.95 -0.54 -0.033 0.92893E+03 138 pumpellyite-Fe 46.27 43.66 -2.61 -0.058 0.44638E+04 139 pumpellyite-Mg 48.99 46.23 -2.76 -0.061 0.47206E+04 143 pyrrhotite -4.26 -8.06 -3.80 -1.266 0.64865E+04 144 pyrrhotiteFe0.875 -6.02 -9.44 -3.42 -1.257 0.58372E+04 145 pyroxmangite 7.40 6.05 -1.34 -0.269 0.22946E+04 146 pyrophyllite -6.18 -11.14 -4.97 -0.310 0.84807E+04 147 quartz -2.99 -3.14 -0.15 -0.052 0.26404E+03 152 rhodonite 7.45 6.05 -1.39 -0.278 0.23749E+04 153 sanidine -1.28 -2.49 -1.21 -0.093 0.20677E+04 165 stilpnomelane-Mg 27.44 25.89 -1.55 -0.046 0.26452E+04 171 talc 16.49 15.32 -1.17 -0.069 0.19966E+04 174 tephroite 18.09 15.25 -2.83 -0.405 0.48358E+04 178 tridymite -2.63 -3.14 -0.52 -0.173 0.88402E+03 179 tremolite 47.87 47.45 -0.42 -0.011 0.71637E+03 180 ferroactinolite 38.45 34.57 -3.88 -0.105 0.66215E+04 181 troilite-low -4.41 -8.06 -3.65 -1.216 0.62293E+04 187 wairakite 3.95 1.91 -2.04 -0.120 0.34838E+04 188 walstromite 11.51 9.91 -1.60 -0.320 0.27328E+04 189 wollastonite 10.46 9.91 -0.55 -0.110 0.94326E+03 190 pseudo-wollastonite 11.00 9.91 -1.09 -0.218 0.18631E+04 191 zoisite 22.85 18.82 -4.03 -0.183 0.68735E+04 192 akaganeite 7.75 4.56 -3.19 -0.690 0.54485E+04 199 chalcedony -2.80 -3.14 -0.34 -0.114 0.58334E+03 201 montmorillonite-Ca -2.29 -6.16 -3.87 -0.239 0.66010E+04 202 montmorillonite-K -2.24 -6.25 -4.02 -0.246 0.68609E+04 203 montmorillonite-Mg -2.48 -6.78 -4.30 -0.266 0.73355E+04 204 montmorillonite-Na -2.04 -5.56 -3.52 -0.216 0.60158E+04 205 nontronite-Ca 3.21 -0.02 -3.24 -0.210 0.55250E+04 206 nontronite-H 2.53 -2.17 -4.71 -0.316 0.80381E+04 207 nontronite-K 3.34 -0.12 -3.46 -0.222 0.59080E+04 208 nontronite-Mg 3.07 -0.64 -3.72 -0.241 0.63435E+04 209 nontronite-Na 3.52 0.57 -2.95 -0.189 0.50289E+04 224 tobermorite 9.82 7.73 -2.09 -0.571 0.35757E+04 230 alabandite -0.98 -5.58 -4.61 -1.536 0.78659E+04 233 boehmite 4.41 0.72 -3.69 -0.615 0.62997E+04 235 ferrous-oxide 9.81 6.72 -3.09 -0.772 0.52715E+04 240 silica-amorphous -2.09 -3.14 -1.05 -0.351 0.17975E+04 242 an20ab80 2.02 1.33 -0.69 -0.053 0.11700E+04 243 an25ab75 2.65 1.76 -0.88 -0.068 0.15094E+04 244 an30ab70 3.28 2.19 -1.09 -0.084 0.18585E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 4.0000000 g Current total amount of reactant added: 99.9990000 g New total amount of reactant added: 103.9990000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.7343E-13 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 11 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 103.9990000 Water: Moles liquid = 0.5484E+02 kg liquid = 0.9880E+00 Moles total = 0.5420E+02 kg total = 0.9765E+00 Activity = 1.0000 Stoichiometric ionic strength = .1119020E-01 Osmotic coef. = 0.9682 True ionic strength = .1977421E-01 Chg. balance for total moles = -.7343E-13 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.90511E-10 -10.0433 0.76110E-10 -10.1186 0.84089E+00 -0.0753 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13902E-03 -3.8569 0.11620E-03 -3.9348 0.83589E+00 -0.0779 4 SO4-- 0.24426E-11 -11.6121 0.12725E-11 -11.8953 0.52097E+00 -0.2832 5 HCO3- 0.79293E-06 -6.1008 0.66376E-06 -6.1780 0.83710E+00 -0.0772 6 HS- 0.25809E-04 -4.5882 0.21577E-04 -4.6660 0.83601E+00 -0.0778 7 Al+++ 0.99213E-29 -29.0034 0.23090E-29 -29.6366 0.23273E+00 -0.6331 8 H4SiO4 0.71546E-03 -3.1454 0.71546E-03 -3.1454 0.10000E+01 0.0000 9 Ca++ 0.12790E-06 -6.8931 0.66150E-07 -7.1795 0.51718E+00 -0.2864 10 Mg++ 0.22391E-10 -10.6499 0.11528E-10 -10.9383 0.51484E+00 -0.2883 11 Fe++ 0.59716E-13 -13.2239 0.30777E-13 -13.5118 0.51540E+00 -0.2879 12 K+ 0.15460E-03 -3.8108 0.12945E-03 -3.8879 0.83729E+00 -0.0771 13 Na+ 0.19618E-01 -1.7074 0.16395E-01 -1.7853 0.83574E+00 -0.0779 14 Mn++ 0.17830E-10 -10.7489 0.91970E-11 -11.0364 0.51582E+00 -0.2875 15 HPO4-- 0.50856E-07 -7.2937 0.26498E-07 -7.5768 0.52104E+00 -0.2831 16 HSiO3- 0.10501E-01 -1.9788 0.87775E-02 -2.0566 0.83589E+00 -0.0779 17 Ca(HSiO3)+ 0.15789E-07 -7.8016 0.13223E-07 -7.8787 0.83747E+00 -0.0770 18 Mg(HSiO3)+ 0.34244E-11 -11.4654 0.28678E-11 -11.5424 0.83747E+00 -0.0770 19 NaHSiO3,aq 0.23275E-02 -2.6331 0.23275E-02 -2.6331 0.10000E+01 0.0000 20 AlO+ 0.64751E-16 -16.1888 0.54227E-16 -16.2658 0.83747E+00 -0.0770 22 HAlO2,aq 0.14189E-09 -9.8480 0.14189E-09 -9.8480 0.10000E+01 0.0000 23 AlO2- 0.49458E-05 -5.3058 0.41267E-05 -5.3844 0.83439E+00 -0.0786 24 CH4,aq 0.10970E-04 -4.9598 0.10932E-04 -4.9613 0.99659E+00 -0.0015 25 C2H6,aq 0.24766E-14 -14.6061 0.24681E-14 -14.6076 0.99659E+00 -0.0015 29 CO,aq 0.22449E-16 -16.6488 0.22449E-16 -16.6488 0.10000E+01 0.0000 30 CO2,aq 0.10832E-09 -9.9653 0.10795E-09 -9.9668 0.99659E+00 -0.0015 31 CO3-2 0.14653E-05 -5.8341 0.76175E-06 -6.1182 0.51987E+00 -0.2841 32 CaCO3,aq 0.63183E-09 -9.1994 0.63183E-09 -9.1994 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.13383E-11 -11.8734 0.11208E-11 -11.9505 0.83747E+00 -0.0770 34 CaCl+ 0.14854E-10 -10.8282 0.12440E-10 -10.9052 0.83747E+00 -0.0770 35 CaCl2,aq 0.34343E-15 -15.4642 0.34343E-15 -15.4642 0.10000E+01 0.0000 36 CaOH+ 0.73964E-07 -7.1310 0.61943E-07 -7.2080 0.83747E+00 -0.0770 37 CaSO4,aq 0.26730E-16 -16.5730 0.26730E-16 -16.5730 0.10000E+01 0.0000 38 HCl,aq 0.16207E-14 -14.7903 0.16207E-14 -14.7903 0.10000E+01 0.0000 43 FeCl+ 0.67596E-17 -17.1701 0.56609E-17 -17.2471 0.83747E+00 -0.0770 46 FeO,aq 0.20650E-09 -9.6851 0.20650E-09 -9.6851 0.10000E+01 0.0000 47 FeOH+ 0.15718E-10 -10.8036 0.13163E-10 -10.8806 0.83747E+00 -0.0770 48 HFeO2- 0.33962E-07 -7.4690 0.28388E-07 -7.5469 0.83589E+00 -0.0779 49 FeO+ 0.13030E-16 -16.8851 0.10912E-16 -16.9621 0.83747E+00 -0.0770 51 FeO2- 0.46113E-09 -9.3362 0.38546E-09 -9.4140 0.83589E+00 -0.0779 52 HFeO2,aq 0.37312E-11 -11.4282 0.37312E-11 -11.4282 0.10000E+01 0.0000 53 H2,aq 0.83069E-05 -5.0806 0.82785E-05 -5.0820 0.99659E+00 -0.0015 54 KCl,aq 0.27263E-09 -9.5644 0.27263E-09 -9.5644 0.10000E+01 0.0000 56 KOH,aq 0.72633E-06 -6.1389 0.72633E-06 -6.1389 0.10000E+01 0.0000 57 KSO4- 0.30580E-14 -14.5146 0.25561E-14 -14.5924 0.83589E+00 -0.0779 58 MgCO3,aq 0.27599E-13 -13.5591 0.27599E-13 -13.5591 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.23831E-15 -15.6229 0.19958E-15 -15.6999 0.83747E+00 -0.0770 60 MgCl+ 0.23461E-14 -14.6296 0.19648E-14 -14.7067 0.83747E+00 -0.0770 61 MgOH+ 0.71325E-10 -10.1468 0.59732E-10 -10.2238 0.83747E+00 -0.0770 63 MnO,aq 0.16442E-08 -8.7840 0.16442E-08 -8.7840 0.10000E+01 0.0000 64 MnOH+ 0.43632E-09 -9.3602 0.36540E-09 -9.4372 0.83747E+00 -0.0770 65 MnO2-2 0.18120E-10 -10.7418 0.94200E-11 -11.0260 0.51987E+00 -0.2841 66 HMnO2- 0.18791E-09 -9.7260 0.15707E-09 -9.8039 0.83589E+00 -0.0779 69 MnCl+ 0.78584E-14 -14.1047 0.65812E-14 -14.1817 0.83747E+00 -0.0770 71 NaCl,aq 0.63138E-06 -6.1997 0.63138E-06 -6.1997 0.10000E+01 0.0000 72 NaOH,aq 0.92552E-04 -4.0336 0.92552E-04 -4.0336 0.10000E+01 0.0000 74 OH- 0.90980E-02 -2.0411 0.75913E-02 -2.1197 0.83439E+00 -0.0786 79 HPO3-2 0.13150E-14 -14.8811 0.68361E-15 -15.1652 0.51987E+00 -0.2841 81 H2PO3- 0.12482E-18 -18.9037 0.10433E-18 -18.9816 0.83589E+00 -0.0779 82 H3PO4,aq 0.10735E-17 -17.9692 0.10735E-17 -17.9692 0.10000E+01 0.0000 83 H2PO4- 0.44466E-10 -10.3520 0.37204E-10 -10.4294 0.83667E+00 -0.0774 84 PO4-3 0.11627E-08 -8.9346 0.28406E-09 -9.5466 0.24432E+00 -0.6120 88 HP2O7-3 0.12222E-17 -17.9129 0.28473E-18 -18.5456 0.23296E+00 -0.6327 89 P2O7-4 0.11444E-16 -16.9414 0.89371E-18 -18.0488 0.78096E-01 -1.1074 90 H2S,aq 0.50928E-08 -8.2930 0.50754E-08 -8.2945 0.99659E+00 -0.0015 91 S2-2 0.23969E-14 -14.6203 0.12461E-14 -14.9044 0.51987E+00 -0.2841 97 SO3-2 0.25961E-17 -17.5857 0.13690E-17 -17.8636 0.52732E+00 -0.2779 99 HSO4- 0.11134E-18 -18.9533 0.93338E-19 -19.0299 0.83828E+00 -0.0766 Charge balance for all species = -.7653E-13 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.9051059E-10 -.2204325E-01 -.2217988E+02 0.0000 2 H2O 0.1000000E+01 0.5550464E+02 0.9982049E+06 0.0000 3 Cl- 0.1390191E-03 0.1396508E-03 0.4942484E+01 6.1838 4 SO4-- 0.2442620E-11 -.1304654E-04 -.1251106E+01 8.3418 5 HCO3- 0.7929314E-06 0.1322882E-04 0.8057908E+00 3.9406 6 HS- 0.2580929E-04 0.3886093E-04 0.1282988E+01 5.4525 7 Al+++ 0.9921299E-29 0.4945963E-05 0.1332189E+00 0.7191 8 H4SiO4 0.7154606E-03 0.1354388E-01 0.1299526E+04 -3.1454 9 Ca++ 0.1279036E-06 0.2183050E-06 0.8734108E-02 13.0576 10 Mg++ 0.2239107E-10 0.9717050E-10 0.2358327E-05 9.2989 11 Fe++ 0.5971568E-13 0.3464893E-07 0.1931695E-02 6.7254 12 K+ 0.1546001E-03 0.1553267E-03 0.6063091E+01 6.2306 13 Na+ 0.1961762E-01 0.2203833E-01 0.5057812E+03 8.3333 14 Mn++ 0.1782983E-10 0.2304402E-08 0.1263805E-03 9.2008 15 HPO4-- 0.5085559E-07 0.5206271E-07 0.4988292E-02 12.6603 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.1722056E+01 -.2177860E-01 -.1700277E+01 0.0000000E+00 2 H2O 0.5420458E+02 0.5483827E+02 -.6336909E+00 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.2907671E-02 -.1288991E-04 0.2920561E-02 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.2882167E-02 0.3839438E-04 -.2920561E-02 0.0000000E+00 7 Al+++ 0.3391139E+00 0.4886584E-05 0.3391090E+00 0.0000000E+00 8 H4SiO4 0.1082919E+01 0.1338127E-01 0.1069538E+01 0.0000000E+00 9 Ca++ 0.1196282E+00 0.2156841E-06 0.1196279E+00 0.0000000E+00 10 Mg++ 0.8253889E-01 0.9600390E-10 0.8253889E-01 0.0000000E+00 11 Fe++ 0.7415218E-01 0.3423294E-07 0.7415215E-01 0.0000000E+00 12 K+ 0.2208047E-01 0.1534619E-03 0.2192701E-01 0.0000000E+00 13 Na+ 0.1307042E+00 0.2177374E-01 0.1089304E+00 0.0000000E+00 14 Mn++ 0.1803197E-02 0.2276736E-08 0.1803194E-02 0.0000000E+00 15 HPO4-- 0.6154221E-03 0.5143766E-07 0.6153706E-03 0.0000000E+00 Chg. balance for solid moles: -.3279E-15 Mass of aqueous solution: 0.989705E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 103.9990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 0.1089 -0.963 28.56 1.456 25.17 10.96 andradite 0.1168E-01 -1.932 5.937 0.774 5.232 1.542 grossular 0.2336E-02 -2.632 1.052 0.022 0.9273 0.2927 apatite-OH 0.2051E-03 -3.688 0.1030 -0.987 0.9081E-01 0.3274E-01 clinochlore 0.1641E-01 -1.785 9.119 0.960 8.037 3.468 daphnite 0.4595E-02 -2.338 3.279 0.516 2.890 0.9936 chlorite-Mn 0.3606E-03 -3.443 0.2557 -0.592 0.2253 0.8148E-01 microcline 0.1916E-01 -1.718 5.334 0.727 4.701 2.084 stilbite 0.7627E-01 -1.118 53.75 1.730 47.37 25.07 stilpnomelane-Fe 0.5527E-02 -2.258 5.958 0.775 5.251 2.058 tr.625ac.25prg.125 0.1413E-03 -3.850 0.1208 -0.918 0.1064 0.3887E-01 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8334E+00 0.8334E+00 1.0000 -0.079 grossular 0.1666E+00 0.1666E+00 1.0000 -0.778 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.7680E+00 0.7680E+00 1.0000 -0.115 daphnite 0.2151E+00 0.2151E+00 1.0000 -0.667 chlorite-Mn 0.1688E-01 0.1688E-01 1.0000 -1.773 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 tr.625ac.25prg.125 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 113.462765 g Volume = 46.623182 cm3 Porosity: -9.4451% V(tot) - V(min): -.40236E+01 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 103.9990000 g log = 2.0170 Original solution: 1000.0103000 g Original solution / Rock added: 9.62 (Water/Rock Ratio), log = 0.9830 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0474 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9745E+00 0.9856 0.1006E+01 0.1021E+01 CO2,gas 0.1095E-07 1.0069 0.1155E-07 0.1147E-07 CH4,gas 0.1517E-01 1.0124 0.1609E-01 0.1589E-01 H2,gas 0.1037E-01 1.0006 0.1087E-01 0.1086E-01 H2S,gas 0.1337E-06 0.9959 0.1395E-06 0.1401E-06 S2,gas 0.5905E-29 1.0000 0.6185E-29 0.6185E-29 CO,gas 0.3194E-13 1.0000 0.3345E-13 0.3345E-13 SO3,gas 0.2661E-47 1.0000 0.2787E-47 0.2787E-47 SO2,gas 0.1125E-26 1.0000 0.1179E-26 0.1179E-26 HCl,gas 0.2730E-17 1.0000 0.2860E-17 0.2860E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 16 albite -0.38 -0.38 0.00 0.000 0.11184E-10 22 andradite 39.01 39.01 0.00 0.000 0.00000E+00 23 grossular 32.73 32.73 0.00 0.000 -0.24265E-10 32 apatite-OH -18.15 -18.15 0.00 0.000 0.00000E+00 46 clinochlore 39.07 39.07 0.00 0.000 0.00000E+00 47 daphnite 28.97 28.97 0.00 0.000 0.18198E-10 48 chlorite-Mn 46.87 46.87 0.00 0.000 -0.24265E-10 116 microcline -2.49 -2.49 0.00 0.000 -0.10616E-10 163 stilbite -7.52 -7.52 0.00 0.000 0.15165E-10 164 stilpnomelane-Fe 13.02 13.02 0.00 0.000 0.21232E-10 245 tr.625ac.25prg.125 45.16 45.16 0.00 0.000 0.36397E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -16.30 -9.64 -3.212 0.16454E+05 -7.937 3 CH4,gas 4.54 1.05 -3.49 -0.873 0.59631E+04 -1.793 4 H2,gas 8.00 4.34 -3.66 -2.093 0.62541E+04 -1.964 5 H2S,gas -6.23 -14.78 -8.55 -4.277 0.14606E+05 -6.855 6 S2,gas -7.34 -38.24 -30.91 -4.755 0.52774E+05 -29.209 7 CO,gas 3.21 -11.96 -15.17 -4.669 0.25910E+05 -13.476 8 SO3,gas 17.12 -32.13 -49.25 -12.313 0.84100E+05 -47.555 9 SO2,gas 0.83 -27.80 -28.63 -7.634 0.48881E+05 -26.929 10 HCl,gas 5.19 -14.05 -19.24 -9.621 0.32856E+05 -17.544 11 acmite 7.71 6.60 -1.11 -0.115 0.18960E+04 15 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 19 spessartine 24.46 19.60 -4.85 -0.243 0.82865E+04 20 analcite 3.32 2.76 -0.56 -0.062 0.95672E+03 26 annite 20.12 17.69 -2.43 -0.135 0.41557E+04 27 phlogopite 27.06 25.41 -1.65 -0.092 0.28250E+04 29 anorthite 12.71 8.21 -4.51 -0.347 0.76927E+04 35 aragonite 0.97 -3.24 -4.21 -1.402 0.71806E+04 36 brucite 12.57 9.30 -3.27 -0.654 0.55829E+04 37 calcite 0.81 -3.24 -4.05 -1.350 0.69164E+04 38 carnegieite-low 9.02 5.91 -3.12 -0.445 0.53211E+04 39 carnegieite-high 10.09 5.91 -4.19 -0.598 0.71481E+04 40 carpholite-Mg 8.58 4.45 -4.14 -0.276 0.70619E+04 41 carpholite-Fe 6.71 1.87 -4.84 -0.323 0.82640E+04 42 celadonite 5.34 3.67 -1.67 -0.099 0.28594E+04 43 celadonite-Fe 3.88 1.09 -2.78 -0.164 0.47520E+04 44 chrysotile 23.89 21.61 -2.29 -0.191 0.39043E+04 49 chlorite-Al-free 47.17 43.21 -3.96 -0.165 0.67638E+04 51 chloritoid-Fe 9.17 5.02 -4.16 -0.277 0.70954E+04 52 chloritoid-Mn 11.40 7.49 -3.91 -0.261 0.66720E+04 54 coesite -2.38 -3.15 -0.77 -0.256 0.13136E+04 61 cristobalite -2.56 -3.15 -0.59 -0.195 0.99900E+03 63 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71234E+04 65 diaspore 2.87 0.72 -2.15 -0.359 0.36789E+04 66 diamond -3.10 -7.62 -4.52 -1.291 0.77182E+04 67 diopside 16.18 16.07 -0.12 -0.012 0.19751E+03 68 hedenbergite 14.21 13.49 -0.72 -0.072 0.12227E+04 71 enstatite 17.26 12.31 -4.96 -0.496 0.84656E+04 73 clinoenstatite 17.17 12.31 -4.86 -0.486 0.82972E+04 75 epidote 24.67 22.67 -2.00 -0.097 0.34078E+04 76 clinozoisite 22.81 18.84 -3.97 -0.180 0.67781E+04 77 epidote-Fe 29.84 26.51 -3.33 -0.173 0.56840E+04 78 fayalite 14.05 10.31 -3.74 -0.534 0.63867E+04 79 ferrosilite 11.15 7.16 -3.99 -0.399 0.68121E+04 83 gibbsite 4.08 0.72 -3.36 -0.480 0.57375E+04 84 glaucophane 22.97 20.84 -2.14 -0.058 0.36485E+04 85 glaucophane-Fe 17.28 13.12 -4.16 -0.112 0.71002E+04 86 graphite -3.55 -7.62 -4.08 -1.165 0.69604E+04 87 greenalite 16.14 13.89 -2.25 -0.188 0.38491E+04 90 hematite 12.57 9.11 -3.45 -0.418 0.58950E+04 91 heulandite -5.83 -7.52 -1.69 -0.077 0.28938E+04 95 jadeite 4.22 2.76 -1.45 -0.145 0.24822E+04 97 kalsilite 7.58 3.80 -3.78 -0.540 0.64535E+04 98 kaolinite -1.33 -4.85 -3.52 -0.320 0.60101E+04 101 laumontite 2.88 1.91 -0.97 -0.065 0.16549E+04 102 lawsonite 9.62 8.21 -1.41 -0.094 0.24093E+04 103 leucite 4.12 0.66 -3.46 -0.346 0.59078E+04 105 lizardite 23.24 21.61 -1.64 -0.137 0.27970E+04 107 magnetite 20.09 15.84 -4.25 -0.347 0.72539E+04 108 minnesotaite 10.39 7.59 -2.79 -0.164 0.47702E+04 112 manganosite 14.06 9.20 -4.86 -1.214 0.82938E+04 120 muscovite 2.58 -1.05 -3.63 -0.214 0.61994E+04 121 paragonite 4.24 1.05 -3.19 -0.187 0.54385E+04 122 nepheline 8.34 5.91 -2.43 -0.347 0.41534E+04 128 periclase-Fe 11.63 6.73 -4.90 -1.225 0.83687E+04 134 phlogopite-Na 29.65 27.51 -2.13 -0.119 0.36438E+04 136 prehnite 19.37 18.12 -1.25 -0.074 0.21422E+04 137 prehnite-Fe 22.50 21.96 -0.54 -0.033 0.92689E+03 138 pumpellyite-Fe 46.27 43.68 -2.59 -0.058 0.44232E+04 139 pumpellyite-Mg 48.99 46.25 -2.74 -0.061 0.46826E+04 143 pyrrhotite -4.26 -8.06 -3.80 -1.266 0.64865E+04 144 pyrrhotiteFe0.875 -6.02 -9.44 -3.42 -1.258 0.58408E+04 145 pyroxmangite 7.40 6.06 -1.34 -0.269 0.22937E+04 146 pyrophyllite -6.18 -11.14 -4.97 -0.310 0.84821E+04 147 quartz -2.99 -3.15 -0.16 -0.052 0.26633E+03 152 rhodonite 7.45 6.06 -1.39 -0.278 0.23739E+04 153 sanidine -1.28 -2.49 -1.21 -0.093 0.20677E+04 165 stilpnomelane-Mg 27.44 25.88 -1.56 -0.046 0.26583E+04 171 talc 16.49 15.31 -1.18 -0.069 0.20082E+04 174 tephroite 18.09 15.26 -2.83 -0.404 0.48316E+04 178 tridymite -2.63 -3.15 -0.52 -0.173 0.88631E+03 179 tremolite 47.87 47.45 -0.42 -0.011 0.72215E+03 180 ferroactinolite 38.45 34.58 -3.87 -0.105 0.66141E+04 181 troilite-low -4.41 -8.06 -3.65 -1.216 0.62293E+04 187 wairakite 3.95 1.91 -2.04 -0.120 0.34769E+04 188 walstromite 11.51 9.91 -1.60 -0.319 0.27268E+04 189 wollastonite 10.46 9.91 -0.55 -0.110 0.93726E+03 190 pseudo-wollastonite 11.00 9.91 -1.09 -0.218 0.18571E+04 191 zoisite 22.85 18.84 -4.01 -0.182 0.68522E+04 192 akaganeite 7.75 4.56 -3.20 -0.691 0.54600E+04 199 chalcedony -2.80 -3.15 -0.34 -0.114 0.58563E+03 201 montmorillonite-Ca -2.29 -6.16 -3.87 -0.239 0.66026E+04 202 montmorillonite-K -2.24 -6.26 -4.02 -0.246 0.68628E+04 203 montmorillonite-Mg -2.48 -6.78 -4.30 -0.266 0.73386E+04 204 montmorillonite-Na -2.04 -5.56 -3.52 -0.216 0.60177E+04 205 nontronite-Ca 3.21 -0.04 -3.25 -0.211 0.55538E+04 206 nontronite-H 2.53 -2.19 -4.73 -0.317 0.80684E+04 207 nontronite-K 3.34 -0.14 -3.48 -0.223 0.59373E+04 208 nontronite-Mg 3.07 -0.66 -3.73 -0.242 0.63739E+04 209 nontronite-Na 3.52 0.56 -2.96 -0.190 0.50581E+04 224 tobermorite 9.82 7.73 -2.09 -0.571 0.35711E+04 230 alabandite -0.98 -5.58 -4.61 -1.535 0.78645E+04 233 boehmite 4.41 0.72 -3.69 -0.615 0.62958E+04 235 ferrous-oxide 9.81 6.73 -3.09 -0.772 0.52697E+04 240 silica-amorphous -2.09 -3.15 -1.05 -0.351 0.17998E+04 242 an20ab80 2.02 1.33 -0.68 -0.053 0.11677E+04 243 an25ab75 2.65 1.76 -0.88 -0.068 0.15066E+04 244 an30ab70 3.28 2.19 -1.09 -0.084 0.18551E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 4.0000000 g Current total amount of reactant added: 103.9990000 g New total amount of reactant added: 107.9990000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.7351E-13 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 11 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 107.9990000 Water: Moles liquid = 0.5482E+02 kg liquid = 0.9876E+00 Moles total = 0.5415E+02 kg total = 0.9756E+00 Activity = 1.0000 Stoichiometric ionic strength = .1120264E-01 Osmotic coef. = 0.9684 True ionic strength = .1979706E-01 Chg. balance for total moles = -.7351E-13 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.90280E-10 -10.0444 0.75910E-10 -10.1197 0.84083E+00 -0.0753 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13907E-03 -3.8568 0.11624E-03 -3.9346 0.83582E+00 -0.0779 4 SO4-- 0.21461E-11 -11.6684 0.11177E-11 -11.9517 0.52081E+00 -0.2833 5 HCO3- 0.71116E-06 -6.1480 0.59527E-06 -6.2253 0.83703E+00 -0.0773 6 HS- 0.25820E-04 -4.5880 0.21584E-04 -4.6659 0.83594E+00 -0.0778 7 Al+++ 0.98975E-29 -29.0045 0.23019E-29 -29.6379 0.23257E+00 -0.6334 8 H4SiO4 0.71344E-03 -3.1466 0.71344E-03 -3.1466 0.10000E+01 0.0000 9 Ca++ 0.12858E-06 -6.8908 0.66481E-07 -7.1773 0.51702E+00 -0.2865 10 Mg++ 0.22259E-10 -10.6525 0.11456E-10 -10.9410 0.51468E+00 -0.2885 11 Fe++ 0.59555E-13 -13.2251 0.30685E-13 -13.5131 0.51524E+00 -0.2880 12 K+ 0.15478E-03 -3.8103 0.12959E-03 -3.8874 0.83723E+00 -0.0772 13 Na+ 0.19640E-01 -1.7068 0.16413E-01 -1.7848 0.83567E+00 -0.0780 14 Mn++ 0.17814E-10 -10.7492 0.91862E-11 -11.0369 0.51566E+00 -0.2876 15 HPO4-- 0.50272E-07 -7.2987 0.26186E-07 -7.5819 0.52089E+00 -0.2833 16 HSiO3- 0.10500E-01 -1.9788 0.87757E-02 -2.0567 0.83582E+00 -0.0779 17 Ca(HSiO3)+ 0.15866E-07 -7.7995 0.13287E-07 -7.8766 0.83741E+00 -0.0771 18 Mg(HSiO3)+ 0.34026E-11 -11.4682 0.28494E-11 -11.5452 0.83741E+00 -0.0771 19 NaHSiO3,aq 0.23296E-02 -2.6327 0.23296E-02 -2.6327 0.10000E+01 0.0000 20 AlO+ 0.64896E-16 -16.1878 0.54344E-16 -16.2648 0.83741E+00 -0.0771 22 HAlO2,aq 0.14257E-09 -9.8460 0.14257E-09 -9.8460 0.10000E+01 0.0000 23 AlO2- 0.49830E-05 -5.3025 0.41574E-05 -5.3812 0.83432E+00 -0.0787 24 CH4,aq 0.11204E-04 -4.9506 0.11166E-04 -4.9521 0.99658E+00 -0.0015 25 C2H6,aq 0.24993E-14 -14.6022 0.24908E-14 -14.6037 0.99658E+00 -0.0015 29 CO,aq 0.20757E-16 -16.6828 0.20757E-16 -16.6828 0.10000E+01 0.0000 30 CO2,aq 0.96885E-10 -10.0137 0.96554E-10 -10.0152 0.99658E+00 -0.0015 31 CO3-2 0.13179E-05 -5.8801 0.68494E-06 -6.1643 0.51972E+00 -0.2842 32 CaCO3,aq 0.57097E-09 -9.2434 0.57097E-09 -9.2434 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.12063E-11 -11.9185 0.10102E-11 -11.9956 0.83741E+00 -0.0771 34 CaCl+ 0.14934E-10 -10.8258 0.12506E-10 -10.9029 0.83741E+00 -0.0771 35 CaCl2,aq 0.34538E-15 -15.4617 0.34538E-15 -15.4617 0.10000E+01 0.0000 36 CaOH+ 0.74536E-07 -7.1276 0.62417E-07 -7.2047 0.83741E+00 -0.0771 37 CaSO4,aq 0.23596E-16 -16.6272 0.23596E-16 -16.6272 0.10000E+01 0.0000 38 HCl,aq 0.16169E-14 -14.7913 0.16169E-14 -14.7913 0.10000E+01 0.0000 43 FeCl+ 0.67420E-17 -17.1712 0.56458E-17 -17.2483 0.83741E+00 -0.0771 46 FeO,aq 0.20696E-09 -9.6841 0.20696E-09 -9.6841 0.10000E+01 0.0000 47 FeOH+ 0.15713E-10 -10.8037 0.13158E-10 -10.8808 0.83741E+00 -0.0771 48 HFeO2- 0.34130E-07 -7.4669 0.28527E-07 -7.5447 0.83582E+00 -0.0779 49 FeO+ 0.12812E-16 -16.8924 0.10728E-16 -16.9695 0.83741E+00 -0.0771 51 FeO2- 0.45580E-09 -9.3412 0.38097E-09 -9.4191 0.83582E+00 -0.0779 52 HFeO2,aq 0.36781E-11 -11.4344 0.36781E-11 -11.4344 0.10000E+01 0.0000 53 H2,aq 0.85871E-05 -5.0662 0.85577E-05 -5.0676 0.99658E+00 -0.0015 54 KCl,aq 0.27301E-09 -9.5638 0.27301E-09 -9.5638 0.10000E+01 0.0000 56 KOH,aq 0.72903E-06 -6.1373 0.72903E-06 -6.1373 0.10000E+01 0.0000 57 KSO4- 0.26890E-14 -14.5704 0.22475E-14 -14.6483 0.83582E+00 -0.0779 58 MgCO3,aq 0.24662E-13 -13.6080 0.24662E-13 -13.6080 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.21240E-15 -15.6728 0.17787E-15 -15.7499 0.83741E+00 -0.0771 60 MgCl+ 0.23325E-14 -14.6322 0.19532E-14 -14.7092 0.83741E+00 -0.0771 61 MgOH+ 0.71072E-10 -10.1483 0.59516E-10 -10.2254 0.83741E+00 -0.0771 63 MnO,aq 0.16509E-08 -8.7823 0.16509E-08 -8.7823 0.10000E+01 0.0000 64 MnOH+ 0.43698E-09 -9.3595 0.36593E-09 -9.4366 0.83741E+00 -0.0771 65 MnO2-2 0.18295E-10 -10.7377 0.95082E-11 -11.0219 0.51972E+00 -0.2842 66 HMnO2- 0.18919E-09 -9.7231 0.15813E-09 -9.8010 0.83582E+00 -0.0779 69 MnCl+ 0.78523E-14 -14.1050 0.65756E-14 -14.1821 0.83741E+00 -0.0771 71 NaCl,aq 0.63227E-06 -6.1991 0.63227E-06 -6.1991 0.10000E+01 0.0000 72 NaOH,aq 0.92896E-04 -4.0320 0.92896E-04 -4.0320 0.10000E+01 0.0000 74 OH- 0.91227E-02 -2.0399 0.76113E-02 -2.1185 0.83432E+00 -0.0787 79 HPO3-2 0.13437E-14 -14.8717 0.69835E-15 -15.1559 0.51972E+00 -0.2842 81 H2PO3- 0.12719E-18 -18.8956 0.10631E-18 -18.9734 0.83582E+00 -0.0779 82 H3PO4,aq 0.10553E-17 -17.9766 0.10553E-17 -17.9766 0.10000E+01 0.0000 83 H2PO4- 0.43831E-10 -10.3582 0.36670E-10 -10.4357 0.83661E+00 -0.0775 84 PO4-3 0.11527E-08 -8.9383 0.28145E-09 -9.5506 0.24416E+00 -0.6123 88 HP2O7-3 0.11913E-17 -17.9240 0.27734E-18 -18.5570 0.23280E+00 -0.6330 89 P2O7-4 0.11190E-16 -16.9512 0.87281E-18 -18.0591 0.78002E-01 -1.1079 90 H2S,aq 0.50811E-08 -8.2940 0.50638E-08 -8.2955 0.99658E+00 -0.0015 91 S2-2 0.23209E-14 -14.6343 0.12062E-14 -14.9186 0.51972E+00 -0.2842 97 SO3-2 0.23578E-17 -17.6275 0.12430E-17 -17.9055 0.52717E+00 -0.2781 99 HSO4- 0.97548E-19 -19.0108 0.81766E-19 -19.0874 0.83822E+00 -0.0766 Charge balance for all species = -.7623E-13 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.9027983E-10 -.2206898E-01 -.2220575E+02 0.0000 2 H2O 0.1000000E+01 0.5550467E+02 0.9982045E+06 0.0000 3 Cl- 0.1390749E-03 0.1397075E-03 0.4944485E+01 6.1851 4 SO4-- 0.2146068E-11 -.1335115E-04 -.1280316E+01 8.2877 5 HCO3- 0.7111633E-06 0.1323419E-04 0.8061171E+00 3.8944 6 HS- 0.2581978E-04 0.3917602E-04 0.1293389E+01 5.4538 7 Al+++ 0.9897494E-29 0.4983133E-05 0.1342199E+00 0.7212 8 H4SiO4 0.7134379E-03 0.1354254E-01 0.1299397E+04 -3.1466 9 Ca++ 0.1285843E-06 0.2195737E-06 0.8784860E-02 13.0621 10 Mg++ 0.2225852E-10 0.9676051E-10 0.2348374E-05 9.2984 11 Fe++ 0.5955505E-13 0.3481242E-07 0.1940808E-02 6.7263 12 K+ 0.1547797E-03 0.1555090E-03 0.6070199E+01 6.2323 13 Na+ 0.1964043E-01 0.2206353E-01 0.5063592E+03 8.3349 14 Mn++ 0.1781442E-10 0.2313220E-08 0.1268640E-03 9.2025 15 HPO4-- 0.5027238E-07 0.5146894E-07 0.4931397E-02 12.6575 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.1788290E+01 -.2179519E-01 -.1766495E+01 0.0000000E+00 2 H2O 0.5415444E+02 0.5481605E+02 -.6616101E+00 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.3018525E-02 -.1318551E-04 0.3031710E-02 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.2993020E-02 0.3868998E-04 -.3031710E-02 0.0000000E+00 7 Al+++ 0.3521568E+00 0.4921310E-05 0.3521519E+00 0.0000000E+00 8 H4SiO4 0.1124570E+01 0.1337453E-01 0.1111196E+01 0.0000000E+00 9 Ca++ 0.1242287E+00 0.2168495E-06 0.1242285E+00 0.0000000E+00 10 Mg++ 0.8571349E-01 0.9556005E-10 0.8571349E-01 0.0000000E+00 11 Fe++ 0.7700422E-01 0.3438052E-07 0.7700418E-01 0.0000000E+00 12 K+ 0.2292972E-01 0.1535797E-03 0.2277614E-01 0.0000000E+00 13 Na+ 0.1357251E+00 0.2178980E-01 0.1139353E+00 0.0000000E+00 14 Mn++ 0.1872551E-02 0.2284521E-08 0.1872549E-02 0.0000000E+00 15 HPO4-- 0.6390924E-03 0.5083039E-07 0.6390415E-03 0.0000000E+00 Chg. balance for solid moles: 0.1405E-15 Mass of aqueous solution: 0.989304E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 107.9990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 0.1139 -0.943 29.87 1.475 25.35 11.47 andradite 0.1213E-01 -1.916 6.163 0.790 5.230 1.601 grossular 0.2471E-02 -2.607 1.113 0.047 0.9448 0.3098 apatite-OH 0.2130E-03 -3.672 0.1070 -0.971 0.9081E-01 0.3400E-01 clinochlore 0.1695E-01 -1.771 9.421 0.974 7.996 3.584 daphnite 0.4763E-02 -2.322 3.399 0.531 2.884 1.030 chlorite-Mn 0.3745E-03 -3.427 0.2655 -0.576 0.2253 0.8461E-01 microcline 0.1992E-01 -1.701 5.543 0.744 4.705 2.165 stilbite 0.7884E-01 -1.103 55.56 1.745 47.15 25.91 stilpnomelane-Fe 0.5720E-02 -2.243 6.166 0.790 5.233 2.130 tr.625ac.25prg.125 0.2657E-03 -3.576 0.2271 -0.644 0.1927 0.7308E-01 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8307E+00 0.8307E+00 1.0000 -0.081 grossular 0.1693E+00 0.1693E+00 1.0000 -0.771 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.7674E+00 0.7674E+00 1.0000 -0.115 daphnite 0.2157E+00 0.2157E+00 1.0000 -0.666 chlorite-Mn 0.1696E-01 0.1696E-01 1.0000 -1.771 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 tr.625ac.25prg.125 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 117.831043 g Volume = 48.390295 cm3 Porosity: -9.4813% V(tot) - V(min): -.41907E+01 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 107.9990000 g log = 2.0334 Original solution: 1000.0103000 g Original solution / Rock added: 9.26 (Water/Rock Ratio), log = 0.9666 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0481 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9738E+00 0.9856 0.1006E+01 0.1021E+01 CO2,gas 0.9788E-08 1.0069 0.1033E-07 0.1026E-07 CH4,gas 0.1549E-01 1.0124 0.1644E-01 0.1623E-01 H2,gas 0.1071E-01 1.0006 0.1124E-01 0.1123E-01 H2S,gas 0.1333E-06 0.9959 0.1392E-06 0.1398E-06 S2,gas 0.5497E-29 1.0000 0.5762E-29 0.5762E-29 CO,gas 0.2951E-13 1.0000 0.3093E-13 0.3093E-13 SO3,gas 0.2323E-47 1.0000 0.2435E-47 0.2435E-47 SO2,gas 0.1016E-26 1.0000 0.1064E-26 0.1064E-26 HCl,gas 0.2722E-17 1.0000 0.2853E-17 0.2853E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 16 albite -0.38 -0.38 0.00 0.000 -0.13080E-10 22 andradite 39.01 39.01 0.00 0.000 0.00000E+00 23 grossular 32.73 32.73 0.00 0.000 0.36397E-10 32 apatite-OH -18.15 -18.15 0.00 0.000 -0.60662E-11 46 clinochlore 39.07 39.07 0.00 0.000 -0.36397E-10 47 daphnite 28.97 28.97 0.00 0.000 -0.30331E-10 48 chlorite-Mn 46.87 46.87 0.00 0.000 -0.48529E-10 116 microcline -2.49 -2.49 0.00 0.000 0.15165E-11 163 stilbite -7.52 -7.52 0.00 0.000 0.15165E-10 164 stilpnomelane-Fe 13.02 13.02 0.00 0.000 -0.27298E-10 245 tr.625ac.25prg.125 45.16 45.16 0.00 0.000 0.24265E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -16.34 -9.68 -3.228 0.16537E+05 -7.986 3 CH4,gas 4.54 1.06 -3.48 -0.871 0.59474E+04 -1.784 4 H2,gas 8.00 4.35 -3.65 -2.085 0.62295E+04 -1.949 5 H2S,gas -6.23 -14.79 -8.56 -4.278 0.14608E+05 -6.856 6 S2,gas -7.34 -38.27 -30.94 -4.760 0.52826E+05 -29.239 7 CO,gas 3.21 -11.99 -15.21 -4.680 0.25968E+05 -13.510 8 SO3,gas 17.12 -32.19 -49.31 -12.328 0.84200E+05 -47.613 9 SO2,gas 0.83 -27.84 -28.67 -7.646 0.48956E+05 -26.973 10 HCl,gas 5.19 -14.05 -19.24 -9.622 0.32858E+05 -17.545 11 acmite 7.71 6.59 -1.12 -0.116 0.19081E+04 15 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 19 spessartine 24.46 19.61 -4.85 -0.242 0.82766E+04 20 analcite 3.32 2.76 -0.56 -0.062 0.95462E+03 26 annite 20.12 17.69 -2.43 -0.135 0.41507E+04 27 phlogopite 27.06 25.41 -1.66 -0.092 0.28272E+04 29 anorthite 12.71 8.21 -4.50 -0.346 0.76822E+04 35 aragonite 0.97 -3.28 -4.25 -1.416 0.72558E+04 36 brucite 12.57 9.30 -3.27 -0.654 0.55837E+04 37 calcite 0.81 -3.28 -4.09 -1.365 0.69915E+04 38 carnegieite-low 9.02 5.91 -3.11 -0.445 0.53169E+04 39 carnegieite-high 10.09 5.91 -4.18 -0.598 0.71439E+04 40 carpholite-Mg 8.58 4.45 -4.13 -0.276 0.70597E+04 41 carpholite-Fe 6.71 1.88 -4.84 -0.322 0.82595E+04 42 celadonite 5.34 3.67 -1.68 -0.099 0.28622E+04 43 celadonite-Fe 3.88 1.09 -2.78 -0.164 0.47525E+04 44 chrysotile 23.89 21.60 -2.29 -0.191 0.39108E+04 49 chlorite-Al-free 47.17 43.20 -3.97 -0.165 0.67767E+04 51 chloritoid-Fe 9.17 5.02 -4.15 -0.277 0.70887E+04 52 chloritoid-Mn 11.40 7.50 -3.90 -0.260 0.66640E+04 54 coesite -2.38 -3.15 -0.77 -0.257 0.13157E+04 61 cristobalite -2.56 -3.15 -0.59 -0.195 0.10011E+04 63 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71234E+04 65 diaspore 2.87 0.72 -2.15 -0.359 0.36754E+04 66 diamond -3.10 -7.64 -4.54 -1.297 0.77517E+04 67 diopside 16.18 16.07 -0.11 -0.011 0.19484E+03 68 hedenbergite 14.21 13.50 -0.71 -0.071 0.12177E+04 71 enstatite 17.26 12.30 -4.96 -0.496 0.84713E+04 73 clinoenstatite 17.17 12.30 -4.86 -0.486 0.83029E+04 75 epidote 24.67 22.68 -1.99 -0.097 0.34024E+04 76 clinozoisite 22.81 18.85 -3.96 -0.180 0.67586E+04 77 epidote-Fe 29.84 26.51 -3.33 -0.173 0.56929E+04 78 fayalite 14.05 10.31 -3.74 -0.534 0.63855E+04 79 ferrosilite 11.15 7.16 -3.99 -0.399 0.68130E+04 83 gibbsite 4.08 0.72 -3.36 -0.480 0.57339E+04 84 glaucophane 22.97 20.83 -2.14 -0.058 0.36549E+04 85 glaucophane-Fe 17.28 13.12 -4.16 -0.112 0.70994E+04 86 graphite -3.55 -7.64 -4.10 -1.170 0.69939E+04 87 greenalite 16.14 13.89 -2.25 -0.188 0.38483E+04 90 hematite 12.57 9.10 -3.46 -0.420 0.59162E+04 91 heulandite -5.83 -7.52 -1.69 -0.077 0.28938E+04 95 jadeite 4.22 2.76 -1.45 -0.145 0.24801E+04 97 kalsilite 7.58 3.81 -3.78 -0.540 0.64493E+04 98 kaolinite -1.33 -4.85 -3.52 -0.320 0.60072E+04 101 laumontite 2.88 1.92 -0.97 -0.064 0.16486E+04 102 lawsonite 9.62 8.21 -1.40 -0.094 0.23988E+04 103 leucite 4.12 0.66 -3.46 -0.346 0.59057E+04 105 lizardite 23.24 21.60 -1.64 -0.137 0.28034E+04 107 magnetite 20.09 15.83 -4.26 -0.348 0.72735E+04 108 minnesotaite 10.39 7.59 -2.80 -0.164 0.47736E+04 112 manganosite 14.06 9.20 -4.86 -1.214 0.82908E+04 120 muscovite 2.58 -1.04 -3.63 -0.213 0.61923E+04 121 paragonite 4.24 1.06 -3.18 -0.187 0.54314E+04 122 nepheline 8.34 5.91 -2.43 -0.347 0.41492E+04 128 periclase-Fe 11.63 6.73 -4.90 -1.225 0.83671E+04 134 phlogopite-Na 29.65 27.51 -2.14 -0.119 0.36460E+04 136 prehnite 19.37 18.13 -1.25 -0.073 0.21262E+04 137 prehnite-Fe 22.50 21.96 -0.54 -0.033 0.92508E+03 138 pumpellyite-Fe 46.27 43.70 -2.57 -0.057 0.43859E+04 139 pumpellyite-Mg 48.99 46.27 -2.72 -0.060 0.46478E+04 143 pyrrhotite -4.26 -8.06 -3.80 -1.266 0.64866E+04 144 pyrrhotiteFe0.875 -6.02 -9.44 -3.42 -1.259 0.58441E+04 145 pyroxmangite 7.40 6.06 -1.34 -0.269 0.22928E+04 146 pyrophyllite -6.18 -11.14 -4.97 -0.311 0.84834E+04 147 quartz -2.99 -3.15 -0.16 -0.052 0.26843E+03 152 rhodonite 7.45 6.06 -1.39 -0.278 0.23730E+04 153 sanidine -1.28 -2.49 -1.21 -0.093 0.20677E+04 165 stilpnomelane-Mg 27.44 25.88 -1.56 -0.047 0.26703E+04 171 talc 16.49 15.31 -1.18 -0.070 0.20188E+04 174 tephroite 18.09 15.26 -2.83 -0.404 0.48276E+04 178 tridymite -2.63 -3.15 -0.52 -0.173 0.88841E+03 179 tremolite 47.87 47.44 -0.43 -0.012 0.72745E+03 180 ferroactinolite 38.45 34.58 -3.87 -0.105 0.66074E+04 181 troilite-low -4.41 -8.06 -3.65 -1.216 0.62294E+04 187 wairakite 3.95 1.92 -2.03 -0.120 0.34706E+04 188 walstromite 11.51 9.92 -1.59 -0.319 0.27213E+04 189 wollastonite 10.46 9.92 -0.55 -0.109 0.93176E+03 190 pseudo-wollastonite 11.00 9.92 -1.08 -0.217 0.18516E+04 191 zoisite 22.85 18.85 -4.00 -0.182 0.68326E+04 192 akaganeite 7.75 4.55 -3.20 -0.693 0.54706E+04 199 chalcedony -2.80 -3.15 -0.34 -0.115 0.58773E+03 201 montmorillonite-Ca -2.29 -6.16 -3.87 -0.239 0.66041E+04 202 montmorillonite-K -2.24 -6.26 -4.02 -0.246 0.68647E+04 203 montmorillonite-Mg -2.48 -6.78 -4.30 -0.266 0.73415E+04 204 montmorillonite-Na -2.04 -5.56 -3.53 -0.216 0.60195E+04 205 nontronite-Ca 3.21 -0.05 -3.27 -0.212 0.55804E+04 206 nontronite-H 2.53 -2.21 -4.74 -0.318 0.80962E+04 207 nontronite-K 3.34 -0.15 -3.49 -0.224 0.59641E+04 208 nontronite-Mg 3.07 -0.67 -3.75 -0.243 0.64018E+04 209 nontronite-Na 3.52 0.54 -2.98 -0.191 0.50850E+04 224 tobermorite 9.82 7.73 -2.09 -0.570 0.35669E+04 230 alabandite -0.98 -5.58 -4.61 -1.535 0.78632E+04 233 boehmite 4.41 0.72 -3.69 -0.614 0.62923E+04 235 ferrous-oxide 9.81 6.73 -3.09 -0.771 0.52680E+04 240 silica-amorphous -2.09 -3.15 -1.06 -0.352 0.18019E+04 242 an20ab80 2.02 1.34 -0.68 -0.053 0.11656E+04 243 an25ab75 2.65 1.76 -0.88 -0.068 0.15040E+04 244 an30ab70 3.28 2.19 -1.08 -0.083 0.18519E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 4.0000000 g Current total amount of reactant added: 107.9990000 g New total amount of reactant added: 111.9990000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.7314E-13 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 11 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 111.9990000 Water: Moles liquid = 0.5480E+02 kg liquid = 0.9872E+00 Moles total = 0.5410E+02 kg total = 0.9747E+00 Activity = 1.0000 Stoichiometric ionic strength = .1121414E-01 Osmotic coef. = 0.9685 True ionic strength = .1981816E-01 Chg. balance for total moles = -.7314E-13 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.90068E-10 -10.0454 0.75727E-10 -10.1207 0.84078E+00 -0.0753 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13913E-03 -3.8566 0.11628E-03 -3.9345 0.83576E+00 -0.0779 4 SO4-- 0.19045E-11 -11.7202 0.99160E-12 -12.0037 0.52067E+00 -0.2834 5 HCO3- 0.64200E-06 -6.1925 0.53734E-06 -6.2698 0.83697E+00 -0.0773 6 HS- 0.25830E-04 -4.5879 0.21591E-04 -4.6657 0.83588E+00 -0.0779 7 Al+++ 0.98757E-29 -29.0054 0.22953E-29 -29.6392 0.23242E+00 -0.6337 8 H4SiO4 0.71158E-03 -3.1478 0.71158E-03 -3.1478 0.10000E+01 0.0000 9 Ca++ 0.12921E-06 -6.8887 0.66788E-07 -7.1753 0.51688E+00 -0.2866 10 Mg++ 0.22137E-10 -10.6549 0.11390E-10 -10.9435 0.51453E+00 -0.2886 11 Fe++ 0.59408E-13 -13.2262 0.30601E-13 -13.5143 0.51509E+00 -0.2881 12 K+ 0.15495E-03 -3.8098 0.12972E-03 -3.8870 0.83717E+00 -0.0772 13 Na+ 0.19661E-01 -1.7064 0.16429E-01 -1.7844 0.83561E+00 -0.0780 14 Mn++ 0.17802E-10 -10.7495 0.91770E-11 -11.0373 0.51551E+00 -0.2878 15 HPO4-- 0.49742E-07 -7.3033 0.25903E-07 -7.5867 0.52074E+00 -0.2834 16 HSiO3- 0.10498E-01 -1.9789 0.87740E-02 -2.0568 0.83576E+00 -0.0779 17 Ca(HSiO3)+ 0.15938E-07 -7.7976 0.13345E-07 -7.8747 0.83735E+00 -0.0771 18 Mg(HSiO3)+ 0.33827E-11 -11.4707 0.28325E-11 -11.5478 0.83735E+00 -0.0771 19 NaHSiO3,aq 0.23315E-02 -2.6324 0.23315E-02 -2.6324 0.10000E+01 0.0000 20 AlO+ 0.65029E-16 -16.1869 0.54452E-16 -16.2640 0.83735E+00 -0.0771 22 HAlO2,aq 0.14320E-09 -9.8441 0.14320E-09 -9.8441 0.10000E+01 0.0000 23 AlO2- 0.50174E-05 -5.2995 0.41858E-05 -5.3782 0.83426E+00 -0.0787 24 CH4,aq 0.11404E-04 -4.9429 0.11365E-04 -4.9444 0.99658E+00 -0.0015 25 C2H6,aq 0.25111E-14 -14.6001 0.25025E-14 -14.6016 0.99658E+00 -0.0015 29 CO,aq 0.19273E-16 -16.7151 0.19273E-16 -16.7151 0.10000E+01 0.0000 30 CO2,aq 0.87246E-10 -10.0593 0.86947E-10 -10.0607 0.99658E+00 -0.0015 31 CO3-2 0.11929E-05 -5.9234 0.61978E-06 -6.2078 0.51957E+00 -0.2844 32 CaCO3,aq 0.51903E-09 -9.2848 0.51903E-09 -9.2848 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.10940E-11 -11.9610 0.91607E-12 -12.0381 0.83735E+00 -0.0771 34 CaCl+ 0.15009E-10 -10.8236 0.12568E-10 -10.9007 0.83735E+00 -0.0771 35 CaCl2,aq 0.34720E-15 -15.4594 0.34720E-15 -15.4594 0.10000E+01 0.0000 36 CaOH+ 0.75066E-07 -7.1246 0.62856E-07 -7.2017 0.83735E+00 -0.0771 37 CaSO4,aq 0.21030E-16 -16.6772 0.21030E-16 -16.6772 0.10000E+01 0.0000 38 HCl,aq 0.16136E-14 -14.7922 0.16136E-14 -14.7922 0.10000E+01 0.0000 43 FeCl+ 0.67261E-17 -17.1722 0.56321E-17 -17.2493 0.83735E+00 -0.0771 46 FeO,aq 0.20739E-09 -9.6832 0.20739E-09 -9.6832 0.10000E+01 0.0000 47 FeOH+ 0.15708E-10 -10.8039 0.13153E-10 -10.8810 0.83735E+00 -0.0771 48 HFeO2- 0.34286E-07 -7.4649 0.28655E-07 -7.5428 0.83576E+00 -0.0779 49 FeO+ 0.12613E-16 -16.8992 0.10562E-16 -16.9763 0.83735E+00 -0.0771 51 FeO2- 0.45092E-09 -9.3459 0.37686E-09 -9.4238 0.83576E+00 -0.0779 52 HFeO2,aq 0.36297E-11 -11.4401 0.36297E-11 -11.4401 0.10000E+01 0.0000 53 H2,aq 0.88541E-05 -5.0529 0.88238E-05 -5.0543 0.99658E+00 -0.0015 54 KCl,aq 0.27337E-09 -9.5632 0.27337E-09 -9.5632 0.10000E+01 0.0000 56 KOH,aq 0.73152E-06 -6.1358 0.73152E-06 -6.1358 0.10000E+01 0.0000 57 KSO4- 0.23882E-14 -14.6219 0.19960E-14 -14.6998 0.83576E+00 -0.0779 58 MgCO3,aq 0.22188E-13 -13.6539 0.22188E-13 -13.6539 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.19065E-15 -15.7198 0.15964E-15 -15.7969 0.83735E+00 -0.0771 60 MgCl+ 0.23200E-14 -14.6345 0.19427E-14 -14.7116 0.83735E+00 -0.0771 61 MgOH+ 0.70841E-10 -10.1497 0.59318E-10 -10.2268 0.83735E+00 -0.0771 63 MnO,aq 0.16573E-08 -8.7806 0.16573E-08 -8.7806 0.10000E+01 0.0000 64 MnOH+ 0.43763E-09 -9.3589 0.36645E-09 -9.4360 0.83735E+00 -0.0771 65 MnO2-2 0.18459E-10 -10.7338 0.95908E-11 -11.0181 0.51957E+00 -0.2844 66 HMnO2- 0.19039E-09 -9.7204 0.15912E-09 -9.7983 0.83576E+00 -0.0779 69 MnCl+ 0.78476E-14 -14.1053 0.65712E-14 -14.1824 0.83735E+00 -0.0771 71 NaCl,aq 0.63311E-06 -6.1985 0.63311E-06 -6.1985 0.10000E+01 0.0000 72 NaOH,aq 0.93214E-04 -4.0305 0.93214E-04 -4.0305 0.10000E+01 0.0000 74 OH- 0.91454E-02 -2.0388 0.76297E-02 -2.1175 0.83426E+00 -0.0787 79 HPO3-2 0.13709E-14 -14.8630 0.71227E-15 -15.1474 0.51957E+00 -0.2844 81 H2PO3- 0.12942E-18 -18.8880 0.10816E-18 -18.9659 0.83576E+00 -0.0779 82 H3PO4,aq 0.10389E-17 -17.9834 0.10389E-17 -17.9834 0.10000E+01 0.0000 83 H2PO4- 0.43255E-10 -10.3640 0.36185E-10 -10.4415 0.83655E+00 -0.0775 84 PO4-3 0.11437E-08 -8.9417 0.27908E-09 -9.5543 0.24402E+00 -0.6126 88 HP2O7-3 0.11636E-17 -17.9342 0.27071E-18 -18.5675 0.23265E+00 -0.6333 89 P2O7-4 0.10961E-16 -16.9602 0.85401E-18 -18.0685 0.77916E-01 -1.1084 90 H2S,aq 0.50706E-08 -8.2949 0.50533E-08 -8.2964 0.99658E+00 -0.0015 91 S2-2 0.22531E-14 -14.6472 0.11706E-14 -14.9316 0.51957E+00 -0.2844 97 SO3-2 0.21574E-17 -17.6661 0.11370E-17 -17.9442 0.52703E+00 -0.2782 99 HSO4- 0.86340E-19 -19.0638 0.72367E-19 -19.1405 0.83816E+00 -0.0767 Charge balance for all species = -.7474E-13 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.9006834E-10 -.2209271E-01 -.2222961E+02 0.0000 2 H2O 0.1000000E+01 0.5550469E+02 0.9982041E+06 0.0000 3 Cl- 0.1391308E-03 0.1397642E-03 0.4946488E+01 6.1863 4 SO4-- 0.1904475E-11 -.1361755E-04 -.1305861E+01 8.2378 5 HCO3- 0.6419993E-06 0.1323956E-04 0.8064436E+00 3.8510 6 HS- 0.2583027E-04 0.3945289E-04 0.1302529E+01 5.4550 7 Al+++ 0.9875678E-29 0.5017524E-05 0.1351462E+00 0.7231 8 H4SiO4 0.7115841E-03 0.1354133E-01 0.1299279E+04 -3.1478 9 Ca++ 0.1292140E-06 0.2207525E-06 0.8832015E-02 13.0662 10 Mg++ 0.2213737E-10 0.9638539E-10 0.2339268E-05 9.2980 11 Fe++ 0.5940797E-13 0.3496346E-07 0.1949227E-02 6.7272 12 K+ 0.1549454E-03 0.1556772E-03 0.6076759E+01 6.2337 13 Na+ 0.1966149E-01 0.2208679E-01 0.5068926E+03 8.3364 14 Mn++ 0.1780166E-10 0.2321535E-08 0.1273199E-03 9.2042 15 HPO4-- 0.4974189E-07 0.5092883E-07 0.4879644E-02 12.6548 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.1854524E+01 -.2180977E-01 -.1832714E+01 0.0000000E+00 2 H2O 0.5410430E+02 0.5479383E+02 -.6895365E+00 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.3129379E-02 -.1344314E-04 0.3142822E-02 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.3103874E-02 0.3894761E-04 -.3142822E-02 0.0000000E+00 7 Al+++ 0.3651998E+00 0.4953264E-05 0.3651948E+00 0.0000000E+00 8 H4SiO4 0.1166221E+01 0.1336790E-01 0.1152853E+01 0.0000000E+00 9 Ca++ 0.1288293E+00 0.2179253E-06 0.1288291E+00 0.0000000E+00 10 Mg++ 0.8888810E-01 0.9515097E-10 0.8888810E-01 0.0000000E+00 11 Fe++ 0.7985625E-01 0.3451568E-07 0.7985621E-01 0.0000000E+00 12 K+ 0.2377898E-01 0.1536834E-03 0.2362530E-01 0.0000000E+00 13 Na+ 0.1407461E+00 0.2180392E-01 0.1189422E+00 0.0000000E+00 14 Mn++ 0.1941905E-02 0.2291802E-08 0.1941903E-02 0.0000000E+00 15 HPO4-- 0.6627627E-03 0.5027658E-07 0.6627124E-03 0.0000000E+00 Chg. balance for solid moles: 0.1973E-15 Mass of aqueous solution: 0.988903E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 111.9990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 0.1189 -0.925 31.18 1.494 25.51 11.97 andradite 0.1257E-01 -1.901 6.388 0.805 5.228 1.660 grossular 0.2608E-02 -2.584 1.175 0.070 0.9612 0.3268 apatite-OH 0.2209E-03 -3.656 0.1110 -0.955 0.9081E-01 0.3526E-01 clinochlore 0.1749E-01 -1.757 9.724 0.988 7.958 3.699 daphnite 0.4931E-02 -2.307 3.518 0.546 2.879 1.066 chlorite-Mn 0.3884E-03 -3.411 0.2754 -0.560 0.2253 0.8775E-01 microcline 0.2067E-01 -1.685 5.753 0.760 4.708 2.247 stilbite 0.8141E-01 -1.089 57.37 1.759 46.95 26.76 stilpnomelane-Fe 0.5914E-02 -2.228 6.375 0.804 5.217 2.202 tr.625ac.25prg.125 0.3902E-03 -3.409 0.3335 -0.477 0.2729 0.1073 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8282E+00 0.8282E+00 1.0000 -0.082 grossular 0.1718E+00 0.1718E+00 1.0000 -0.765 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.7668E+00 0.7668E+00 1.0000 -0.115 daphnite 0.2161E+00 0.2161E+00 1.0000 -0.665 chlorite-Mn 0.1702E-01 0.1702E-01 1.0000 -1.769 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 tr.625ac.25prg.125 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 122.199220 g Volume = 50.157278 cm3 Porosity: -9.5147% V(tot) - V(min): -.43577E+01 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 111.9990000 g log = 2.0492 Original solution: 1000.0103000 g Original solution / Rock added: 8.93 (Water/Rock Ratio), log = 0.9508 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0488 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9732E+00 0.9856 0.1006E+01 0.1021E+01 CO2,gas 0.8808E-08 1.0069 0.9302E-08 0.9238E-08 CH4,gas 0.1575E-01 1.0124 0.1673E-01 0.1652E-01 H2,gas 0.1104E-01 1.0006 0.1158E-01 0.1158E-01 H2S,gas 0.1330E-06 0.9959 0.1389E-06 0.1395E-06 S2,gas 0.5146E-29 1.0000 0.5397E-29 0.5397E-29 CO,gas 0.2738E-13 1.0000 0.2872E-13 0.2872E-13 SO3,gas 0.2050E-47 1.0000 0.2150E-47 0.2150E-47 SO2,gas 0.9239E-27 1.0000 0.9690E-27 0.9690E-27 HCl,gas 0.2715E-17 1.0000 0.2847E-17 0.2847E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 16 albite -0.38 -0.38 0.00 0.000 -0.13080E-10 22 andradite 39.01 39.01 0.00 0.000 0.00000E+00 23 grossular 32.73 32.73 0.00 0.000 -0.24265E-10 32 apatite-OH -18.15 -18.15 0.00 0.000 -0.60662E-11 46 clinochlore 39.07 39.07 0.00 0.000 -0.36397E-10 47 daphnite 28.97 28.97 0.00 0.000 -0.36397E-10 48 chlorite-Mn 46.87 46.87 0.00 0.000 -0.12132E-10 116 microcline -2.49 -2.49 0.00 0.000 -0.10616E-10 163 stilbite -7.52 -7.52 0.00 0.000 0.15165E-10 164 stilpnomelane-Fe 13.02 13.02 0.00 0.000 -0.27298E-10 245 tr.625ac.25prg.125 45.16 45.16 0.00 0.000 -0.24265E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -16.39 -9.73 -3.243 0.16614E+05 -8.031 3 CH4,gas 4.54 1.07 -3.48 -0.869 0.59343E+04 -1.777 4 H2,gas 8.00 4.36 -3.64 -2.077 0.62068E+04 -1.936 5 H2S,gas -6.23 -14.79 -8.56 -4.278 0.14610E+05 -6.857 6 S2,gas -7.34 -38.30 -30.97 -4.764 0.52875E+05 -29.268 7 CO,gas 3.21 -12.03 -15.24 -4.689 0.26023E+05 -13.542 8 SO3,gas 17.12 -32.25 -49.37 -12.342 0.84292E+05 -47.668 9 SO2,gas 0.83 -27.88 -28.71 -7.657 0.49026E+05 -27.014 10 HCl,gas 5.19 -14.06 -19.24 -9.622 0.32860E+05 -17.546 11 acmite 7.71 6.59 -1.12 -0.117 0.19192E+04 15 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 19 spessartine 24.46 19.62 -4.84 -0.242 0.82674E+04 20 analcite 3.32 2.76 -0.56 -0.062 0.95269E+03 26 annite 20.12 17.70 -2.43 -0.135 0.41461E+04 27 phlogopite 27.06 25.41 -1.66 -0.092 0.28293E+04 29 anorthite 12.71 8.22 -4.49 -0.346 0.76725E+04 35 aragonite 0.97 -3.32 -4.29 -1.430 0.73265E+04 36 brucite 12.57 9.30 -3.27 -0.654 0.55843E+04 37 calcite 0.81 -3.32 -4.14 -1.379 0.70623E+04 38 carnegieite-low 9.02 5.91 -3.11 -0.445 0.53130E+04 39 carnegieite-high 10.09 5.91 -4.18 -0.597 0.71400E+04 40 carpholite-Mg 8.58 4.45 -4.13 -0.276 0.70577E+04 41 carpholite-Fe 6.71 1.88 -4.83 -0.322 0.82553E+04 42 celadonite 5.34 3.66 -1.68 -0.099 0.28649E+04 43 celadonite-Fe 3.88 1.09 -2.78 -0.164 0.47529E+04 44 chrysotile 23.89 21.60 -2.29 -0.191 0.39167E+04 49 chlorite-Al-free 47.17 43.20 -3.98 -0.166 0.67885E+04 51 chloritoid-Fe 9.17 5.03 -4.15 -0.277 0.70826E+04 52 chloritoid-Mn 11.40 7.50 -3.90 -0.260 0.66565E+04 54 coesite -2.38 -3.15 -0.77 -0.257 0.13177E+04 61 cristobalite -2.56 -3.15 -0.59 -0.196 0.10030E+04 63 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71234E+04 65 diaspore 2.87 0.72 -2.15 -0.358 0.36721E+04 66 diamond -3.10 -7.66 -4.56 -1.303 0.77840E+04 67 diopside 16.18 16.07 -0.11 -0.011 0.19240E+03 68 hedenbergite 14.21 13.50 -0.71 -0.071 0.12130E+04 71 enstatite 17.26 12.30 -4.96 -0.496 0.84766E+04 73 clinoenstatite 17.17 12.30 -4.87 -0.487 0.83082E+04 75 epidote 24.67 22.68 -1.99 -0.096 0.33975E+04 76 clinozoisite 22.81 18.86 -3.95 -0.179 0.67406E+04 77 epidote-Fe 29.84 26.50 -3.34 -0.173 0.57010E+04 78 fayalite 14.05 10.31 -3.74 -0.534 0.63843E+04 79 ferrosilite 11.15 7.16 -3.99 -0.399 0.68138E+04 83 gibbsite 4.08 0.72 -3.36 -0.479 0.57307E+04 84 glaucophane 22.97 20.83 -2.14 -0.058 0.36608E+04 85 glaucophane-Fe 17.28 13.12 -4.16 -0.112 0.70987E+04 86 graphite -3.55 -7.66 -4.11 -1.176 0.70262E+04 87 greenalite 16.14 13.89 -2.25 -0.188 0.38476E+04 90 hematite 12.57 9.09 -3.48 -0.421 0.59359E+04 91 heulandite -5.83 -7.52 -1.69 -0.077 0.28938E+04 95 jadeite 4.22 2.76 -1.45 -0.145 0.24782E+04 97 kalsilite 7.58 3.81 -3.77 -0.539 0.64455E+04 98 kaolinite -1.33 -4.85 -3.52 -0.320 0.60045E+04 101 laumontite 2.88 1.92 -0.96 -0.064 0.16428E+04 102 lawsonite 9.62 8.22 -1.40 -0.093 0.23892E+04 103 leucite 4.12 0.66 -3.46 -0.346 0.59037E+04 105 lizardite 23.24 21.60 -1.65 -0.137 0.28093E+04 107 magnetite 20.09 15.82 -4.27 -0.349 0.72916E+04 108 minnesotaite 10.39 7.59 -2.80 -0.165 0.47767E+04 112 manganosite 14.06 9.20 -4.85 -1.213 0.82879E+04 120 muscovite 2.58 -1.04 -3.62 -0.213 0.61858E+04 121 paragonite 4.24 1.06 -3.18 -0.187 0.54249E+04 122 nepheline 8.34 5.91 -2.43 -0.347 0.41454E+04 128 periclase-Fe 11.63 6.73 -4.90 -1.225 0.83655E+04 134 phlogopite-Na 29.65 27.51 -2.14 -0.119 0.36481E+04 136 prehnite 19.37 18.14 -1.24 -0.073 0.21115E+04 137 prehnite-Fe 22.50 21.96 -0.54 -0.033 0.92345E+03 138 pumpellyite-Fe 46.27 43.72 -2.55 -0.057 0.43517E+04 139 pumpellyite-Mg 48.99 46.29 -2.70 -0.060 0.46158E+04 143 pyrrhotite -4.26 -8.06 -3.80 -1.266 0.64866E+04 144 pyrrhotiteFe0.875 -6.02 -9.44 -3.42 -1.259 0.58471E+04 145 pyroxmangite 7.40 6.06 -1.34 -0.268 0.22919E+04 146 pyrophyllite -6.18 -11.14 -4.97 -0.311 0.84846E+04 147 quartz -2.99 -3.15 -0.16 -0.053 0.27036E+03 152 rhodonite 7.45 6.06 -1.39 -0.278 0.23721E+04 153 sanidine -1.28 -2.49 -1.21 -0.093 0.20677E+04 165 stilpnomelane-Mg 27.44 25.87 -1.57 -0.047 0.26814E+04 171 talc 16.49 15.30 -1.19 -0.070 0.20286E+04 174 tephroite 18.09 15.26 -2.83 -0.404 0.48239E+04 178 tridymite -2.63 -3.15 -0.52 -0.174 0.89034E+03 179 tremolite 47.87 47.44 -0.43 -0.012 0.73233E+03 180 ferroactinolite 38.45 34.59 -3.87 -0.104 0.66012E+04 181 troilite-low -4.41 -8.06 -3.65 -1.216 0.62294E+04 187 wairakite 3.95 1.92 -2.03 -0.119 0.34648E+04 188 walstromite 11.51 9.92 -1.59 -0.318 0.27163E+04 189 wollastonite 10.46 9.92 -0.54 -0.109 0.92670E+03 190 pseudo-wollastonite 11.00 9.92 -1.08 -0.216 0.18465E+04 191 zoisite 22.85 18.86 -3.99 -0.181 0.68147E+04 192 akaganeite 7.75 4.54 -3.21 -0.694 0.54805E+04 199 chalcedony -2.80 -3.15 -0.35 -0.115 0.58966E+03 201 montmorillonite-Ca -2.29 -6.16 -3.87 -0.239 0.66054E+04 202 montmorillonite-K -2.24 -6.26 -4.02 -0.246 0.68663E+04 203 montmorillonite-Mg -2.48 -6.78 -4.30 -0.266 0.73441E+04 204 montmorillonite-Na -2.04 -5.56 -3.53 -0.216 0.60212E+04 205 nontronite-Ca 3.21 -0.07 -3.28 -0.213 0.56049E+04 206 nontronite-H 2.53 -2.22 -4.76 -0.319 0.81218E+04 207 nontronite-K 3.34 -0.17 -3.51 -0.225 0.59890E+04 208 nontronite-Mg 3.07 -0.69 -3.76 -0.244 0.64276E+04 209 nontronite-Na 3.52 0.53 -2.99 -0.192 0.51098E+04 224 tobermorite 9.82 7.74 -2.09 -0.569 0.35630E+04 230 alabandite -0.98 -5.58 -4.60 -1.535 0.78619E+04 233 boehmite 4.41 0.72 -3.68 -0.614 0.62890E+04 235 ferrous-oxide 9.81 6.73 -3.08 -0.771 0.52665E+04 240 silica-amorphous -2.09 -3.15 -1.06 -0.352 0.18038E+04 242 an20ab80 2.02 1.34 -0.68 -0.052 0.11637E+04 243 an25ab75 2.65 1.77 -0.88 -0.068 0.15015E+04 244 an30ab70 3.28 2.20 -1.08 -0.083 0.18490E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 4.0000000 g Current total amount of reactant added: 111.9990000 g New total amount of reactant added: 115.9990000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.7317E-13 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 11 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 115.9990000 Water: Moles liquid = 0.5478E+02 kg liquid = 0.9868E+00 Moles total = 0.5405E+02 kg total = 0.9738E+00 Activity = 1.0000 Stoichiometric ionic strength = .1122481E-01 Osmotic coef. = 0.9687 True ionic strength = .1983769E-01 Chg. balance for total moles = -.7317E-13 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.89874E-10 -10.0464 0.75559E-10 -10.1217 0.84073E+00 -0.0753 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13919E-03 -3.8564 0.11632E-03 -3.9343 0.83571E+00 -0.0779 4 SO4-- 0.17052E-11 -11.7682 0.88762E-12 -12.0518 0.52054E+00 -0.2835 5 HCO3- 0.58314E-06 -6.2342 0.48804E-06 -6.3115 0.83692E+00 -0.0773 6 HS- 0.25841E-04 -4.5877 0.21598E-04 -4.6656 0.83583E+00 -0.0779 7 Al+++ 0.98556E-29 -29.0063 0.22893E-29 -29.6403 0.23229E+00 -0.6340 8 H4SiO4 0.70988E-03 -3.1488 0.70988E-03 -3.1488 0.10000E+01 0.0000 9 Ca++ 0.12980E-06 -6.8867 0.67072E-07 -7.1735 0.51674E+00 -0.2867 10 Mg++ 0.22026E-10 -10.6571 0.11330E-10 -10.9458 0.51440E+00 -0.2887 11 Fe++ 0.59273E-13 -13.2271 0.30523E-13 -13.5154 0.51495E+00 -0.2882 12 K+ 0.15510E-03 -3.8094 0.12984E-03 -3.8866 0.83712E+00 -0.0772 13 Na+ 0.19681E-01 -1.7060 0.16445E-01 -1.7840 0.83556E+00 -0.0780 14 Mn++ 0.17791E-10 -10.7498 0.91692E-11 -11.0377 0.51538E+00 -0.2879 15 HPO4-- 0.49257E-07 -7.3075 0.25644E-07 -7.5910 0.52061E+00 -0.2835 16 HSiO3- 0.10497E-01 -1.9789 0.87725E-02 -2.0569 0.83571E+00 -0.0779 17 Ca(HSiO3)+ 0.16004E-07 -7.7958 0.13400E-07 -7.8729 0.83730E+00 -0.0771 18 Mg(HSiO3)+ 0.33645E-11 -11.4731 0.28171E-11 -11.5502 0.83730E+00 -0.0771 19 NaHSiO3,aq 0.23332E-02 -2.6320 0.23332E-02 -2.6320 0.10000E+01 0.0000 20 AlO+ 0.65152E-16 -16.1861 0.54552E-16 -16.2632 0.83730E+00 -0.0771 22 HAlO2,aq 0.14378E-09 -9.8423 0.14378E-09 -9.8423 0.10000E+01 0.0000 23 AlO2- 0.50493E-05 -5.2968 0.42122E-05 -5.3755 0.83421E+00 -0.0787 24 CH4,aq 0.11575E-04 -4.9365 0.11535E-04 -4.9380 0.99658E+00 -0.0015 25 C2H6,aq 0.25147E-14 -14.5995 0.25061E-14 -14.6010 0.99658E+00 -0.0015 29 CO,aq 0.17968E-16 -16.7455 0.17968E-16 -16.7455 0.10000E+01 0.0000 30 CO2,aq 0.79066E-10 -10.1020 0.78795E-10 -10.1035 0.99658E+00 -0.0015 31 CO3-2 0.10861E-05 -5.9641 0.56417E-06 -6.2486 0.51944E+00 -0.2845 32 CaCO3,aq 0.47447E-09 -9.3238 0.47447E-09 -9.3238 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.99793E-12 -12.0009 0.83556E-12 -12.0780 0.83730E+00 -0.0771 34 CaCl+ 0.15079E-10 -10.8216 0.12626E-10 -10.8987 0.83730E+00 -0.0771 35 CaCl2,aq 0.34891E-15 -15.4573 0.34891E-15 -15.4573 0.10000E+01 0.0000 36 CaOH+ 0.75558E-07 -7.1217 0.63264E-07 -7.1988 0.83730E+00 -0.0771 37 CaSO4,aq 0.18905E-16 -16.7234 0.18905E-16 -16.7234 0.10000E+01 0.0000 38 HCl,aq 0.16105E-14 -14.7930 0.16105E-14 -14.7930 0.10000E+01 0.0000 43 FeCl+ 0.67117E-17 -17.1732 0.56197E-17 -17.2503 0.83730E+00 -0.0771 46 FeO,aq 0.20779E-09 -9.6824 0.20779E-09 -9.6824 0.10000E+01 0.0000 47 FeOH+ 0.15704E-10 -10.8040 0.13149E-10 -10.8811 0.83730E+00 -0.0771 48 HFeO2- 0.34430E-07 -7.4631 0.28773E-07 -7.5410 0.83571E+00 -0.0779 49 FeO+ 0.12433E-16 -16.9054 0.10410E-16 -16.9826 0.83730E+00 -0.0771 51 FeO2- 0.44644E-09 -9.3502 0.37310E-09 -9.4282 0.83571E+00 -0.0779 52 HFeO2,aq 0.35855E-11 -11.4455 0.35855E-11 -11.4455 0.10000E+01 0.0000 53 H2,aq 0.91085E-05 -5.0406 0.90774E-05 -5.0420 0.99658E+00 -0.0015 54 KCl,aq 0.27372E-09 -9.5627 0.27372E-09 -9.5627 0.10000E+01 0.0000 56 KOH,aq 0.73382E-06 -6.1344 0.73382E-06 -6.1344 0.10000E+01 0.0000 57 KSO4- 0.21399E-14 -14.6696 0.17883E-14 -14.7476 0.83571E+00 -0.0779 58 MgCO3,aq 0.20090E-13 -13.6970 0.20090E-13 -13.6970 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.17225E-15 -15.7638 0.14423E-15 -15.8410 0.83730E+00 -0.0771 60 MgCl+ 0.23087E-14 -14.6366 0.19331E-14 -14.7138 0.83730E+00 -0.0771 61 MgOH+ 0.70628E-10 -10.1510 0.59136E-10 -10.2281 0.83730E+00 -0.0771 63 MnO,aq 0.16632E-08 -8.7791 0.16632E-08 -8.7791 0.10000E+01 0.0000 64 MnOH+ 0.43826E-09 -9.3583 0.36695E-09 -9.4354 0.83730E+00 -0.0771 65 MnO2-2 0.18613E-10 -10.7302 0.96681E-11 -11.0147 0.51944E+00 -0.2845 66 HMnO2- 0.19151E-09 -9.7178 0.16004E-09 -9.7958 0.83571E+00 -0.0779 69 MnCl+ 0.78440E-14 -14.1055 0.65677E-14 -14.1826 0.83730E+00 -0.0771 71 NaCl,aq 0.63391E-06 -6.1980 0.63391E-06 -6.1980 0.10000E+01 0.0000 72 NaOH,aq 0.93508E-04 -4.0292 0.93508E-04 -4.0292 0.10000E+01 0.0000 74 OH- 0.91663E-02 -2.0378 0.76466E-02 -2.1165 0.83421E+00 -0.0787 79 HPO3-2 0.13965E-14 -14.8549 0.72542E-15 -15.1394 0.51944E+00 -0.2845 81 H2PO3- 0.13152E-18 -18.8810 0.10991E-18 -18.9589 0.83571E+00 -0.0779 82 H3PO4,aq 0.10240E-17 -17.9897 0.10240E-17 -17.9897 0.10000E+01 0.0000 83 H2PO4- 0.42731E-10 -10.3693 0.35744E-10 -10.4468 0.83649E+00 -0.0775 84 PO4-3 0.11354E-08 -8.9449 0.27690E-09 -9.5577 0.24388E+00 -0.6128 88 HP2O7-3 0.11386E-17 -17.9436 0.26474E-18 -18.5772 0.23252E+00 -0.6335 89 P2O7-4 0.10754E-16 -16.9684 0.83703E-18 -18.0773 0.77837E-01 -1.1088 90 H2S,aq 0.50611E-08 -8.2958 0.50438E-08 -8.2972 0.99658E+00 -0.0015 91 S2-2 0.21922E-14 -14.6591 0.11387E-14 -14.9436 0.51944E+00 -0.2845 97 SO3-2 0.19872E-17 -17.7018 0.10470E-17 -17.9800 0.52690E+00 -0.2783 99 HSO4- 0.77120E-19 -19.1128 0.64635E-19 -19.1895 0.83810E+00 -0.0767 Charge balance for all species = -.7467E-13 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.8987385E-10 -.2211466E-01 -.2225168E+02 0.0000 2 H2O 0.1000000E+01 0.5550471E+02 0.9982037E+06 0.0000 3 Cl- 0.1391867E-03 0.1398209E-03 0.4948492E+01 6.1874 4 SO4-- 0.1705212E-11 -.1385221E-04 -.1328363E+01 8.1917 5 HCO3- 0.5831365E-06 0.1324493E-04 0.8067703E+00 3.8102 6 HS- 0.2584077E-04 0.3969804E-04 0.1310622E+01 5.4561 7 Al+++ 0.9855617E-29 0.5049428E-05 0.1360054E+00 0.7248 8 H4SiO4 0.7098794E-03 0.1354022E-01 0.1299171E+04 -3.1488 9 Ca++ 0.1297980E-06 0.2218502E-06 0.8875925E-02 13.0700 10 Mg++ 0.2202625E-10 0.9604096E-10 0.2330907E-05 9.2977 11 Fe++ 0.5927283E-13 0.3510338E-07 0.1957026E-02 6.7280 12 K+ 0.1550987E-03 0.1558328E-03 0.6082830E+01 6.2351 13 Na+ 0.1968097E-01 0.2210832E-01 0.5073863E+03 8.3377 14 Mn++ 0.1779113E-10 0.2329387E-08 0.1277504E-03 9.2058 15 HPO4-- 0.4925744E-07 0.5043557E-07 0.4832379E-02 12.6524 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.1920758E+01 -.2182258E-01 -.1898936E+01 0.0000000E+00 2 H2O 0.5405416E+02 0.5477162E+02 -.7174693E+00 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.3240232E-02 -.1366925E-04 0.3253901E-02 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.3214728E-02 0.3917372E-04 -.3253901E-02 0.0000000E+00 7 Al+++ 0.3782428E+00 0.4982737E-05 0.3782378E+00 0.0000000E+00 8 H4SiO4 0.1207872E+01 0.1336138E-01 0.1194511E+01 0.0000000E+00 9 Ca++ 0.1334299E+00 0.2189200E-06 0.1334296E+00 0.0000000E+00 10 Mg++ 0.9206270E-01 0.9477248E-10 0.9206270E-01 0.0000000E+00 11 Fe++ 0.8270828E-01 0.3463974E-07 0.8270825E-01 0.0000000E+00 12 K+ 0.2462824E-01 0.1537746E-03 0.2447446E-01 0.0000000E+00 13 Na+ 0.1457671E+00 0.2181632E-01 0.1239508E+00 0.0000000E+00 14 Mn++ 0.2011260E-02 0.2298621E-08 0.2011257E-02 0.0000000E+00 15 HPO4-- 0.6864330E-03 0.4976944E-07 0.6863832E-03 0.0000000E+00 Chg. balance for solid moles: 0.9476E-16 Mass of aqueous solution: 0.988503E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 115.9990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 0.1239 -0.907 32.49 1.512 25.67 12.47 andradite 0.1302E-01 -1.886 6.614 0.820 5.226 1.718 grossular 0.2744E-02 -2.562 1.236 0.092 0.9766 0.3439 apatite-OH 0.2288E-03 -3.641 0.1149 -0.940 0.9080E-01 0.3652E-01 clinochlore 0.1804E-01 -1.744 10.03 1.001 7.922 3.814 daphnite 0.5099E-02 -2.293 3.638 0.561 2.874 1.102 chlorite-Mn 0.4023E-03 -3.396 0.2852 -0.545 0.2253 0.9088E-01 microcline 0.2142E-01 -1.669 5.962 0.775 4.711 2.329 stilbite 0.8398E-01 -1.076 59.18 1.772 46.76 27.60 stilpnomelane-Fe 0.6108E-02 -2.214 6.584 0.819 5.202 2.274 tr.625ac.25prg.125 0.5149E-03 -3.288 0.4401 -0.356 0.3477 0.1417 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8259E+00 0.8259E+00 1.0000 -0.083 grossular 0.1741E+00 0.1741E+00 1.0000 -0.759 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.7663E+00 0.7663E+00 1.0000 -0.116 daphnite 0.2166E+00 0.2166E+00 1.0000 -0.664 chlorite-Mn 0.1709E-01 0.1709E-01 1.0000 -1.767 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 tr.625ac.25prg.125 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 126.567306 g Volume = 51.924145 cm3 Porosity: -9.5455% V(tot) - V(min): -.45245E+01 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 115.9990000 g log = 2.0645 Original solution: 1000.0103000 g Original solution / Rock added: 8.62 (Water/Rock Ratio), log = 0.9356 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0494 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9727E+00 0.9856 0.1006E+01 0.1021E+01 CO2,gas 0.7978E-08 1.0069 0.8430E-08 0.8372E-08 CH4,gas 0.1598E-01 1.0124 0.1698E-01 0.1677E-01 H2,gas 0.1135E-01 1.0006 0.1192E-01 0.1191E-01 H2S,gas 0.1327E-06 0.9959 0.1386E-06 0.1392E-06 S2,gas 0.4842E-29 1.0000 0.5081E-29 0.5081E-29 CO,gas 0.2552E-13 1.0000 0.2678E-13 0.2678E-13 SO3,gas 0.1826E-47 1.0000 0.1916E-47 0.1916E-47 SO2,gas 0.8466E-27 1.0000 0.8884E-27 0.8884E-27 HCl,gas 0.2708E-17 1.0000 0.2842E-17 0.2842E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 16 albite -0.38 -0.38 0.00 0.000 -0.13080E-10 22 andradite 39.01 39.01 0.00 0.000 -0.12132E-10 23 grossular 32.73 32.73 0.00 0.000 -0.36397E-10 32 apatite-OH -18.15 -18.15 0.00 0.000 -0.12132E-10 46 clinochlore 39.07 39.07 0.00 0.000 -0.36397E-10 47 daphnite 28.97 28.97 0.00 0.000 -0.60662E-10 48 chlorite-Mn 46.87 46.87 0.00 0.000 -0.72794E-10 116 microcline -2.49 -2.49 0.00 0.000 0.15165E-11 163 stilbite -7.52 -7.52 0.00 0.000 -0.90992E-11 164 stilpnomelane-Fe 13.02 13.02 0.00 0.000 -0.27298E-10 245 tr.625ac.25prg.125 45.16 45.16 0.00 0.000 -0.60662E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -16.43 -9.77 -3.258 0.16687E+05 -8.074 3 CH4,gas 4.54 1.07 -3.47 -0.867 0.59233E+04 -1.770 4 H2,gas 8.00 4.38 -3.62 -2.070 0.61858E+04 -1.924 5 H2S,gas -6.23 -14.79 -8.56 -4.279 0.14611E+05 -6.858 6 S2,gas -7.34 -38.33 -30.99 -4.768 0.52920E+05 -29.294 7 CO,gas 3.21 -12.06 -15.27 -4.699 0.26075E+05 -13.572 8 SO3,gas 17.12 -32.30 -49.42 -12.354 0.84377E+05 -47.718 9 SO2,gas 0.83 -27.92 -28.75 -7.667 0.49090E+05 -27.051 10 HCl,gas 5.19 -14.06 -19.25 -9.623 0.32861E+05 -17.546 11 acmite 7.71 6.58 -1.13 -0.117 0.19295E+04 15 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 19 spessartine 24.46 19.62 -4.84 -0.242 0.82587E+04 20 analcite 3.32 2.76 -0.56 -0.062 0.95091E+03 26 annite 20.12 17.70 -2.43 -0.135 0.41419E+04 27 phlogopite 27.06 25.41 -1.66 -0.092 0.28312E+04 29 anorthite 12.71 8.22 -4.49 -0.345 0.76636E+04 35 aragonite 0.97 -3.36 -4.33 -1.443 0.73930E+04 36 brucite 12.57 9.30 -3.27 -0.654 0.55850E+04 37 calcite 0.81 -3.36 -4.18 -1.392 0.71288E+04 38 carnegieite-low 9.02 5.91 -3.11 -0.444 0.53094E+04 39 carnegieite-high 10.09 5.91 -4.18 -0.597 0.71364E+04 40 carpholite-Mg 8.58 4.45 -4.13 -0.275 0.70559E+04 41 carpholite-Fe 6.71 1.88 -4.83 -0.322 0.82514E+04 42 celadonite 5.34 3.66 -1.68 -0.099 0.28673E+04 43 celadonite-Fe 3.88 1.09 -2.78 -0.164 0.47532E+04 44 chrysotile 23.89 21.60 -2.30 -0.191 0.39221E+04 49 chlorite-Al-free 47.17 43.19 -3.98 -0.166 0.67994E+04 51 chloritoid-Fe 9.17 5.03 -4.14 -0.276 0.70770E+04 52 chloritoid-Mn 11.40 7.51 -3.89 -0.260 0.66497E+04 54 coesite -2.38 -3.15 -0.77 -0.258 0.13195E+04 61 cristobalite -2.56 -3.15 -0.59 -0.196 0.10048E+04 63 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71234E+04 65 diaspore 2.87 0.72 -2.15 -0.358 0.36691E+04 66 diamond -3.10 -7.68 -4.58 -1.308 0.78150E+04 67 diopside 16.18 16.07 -0.11 -0.011 0.19014E+03 68 hedenbergite 14.21 13.50 -0.71 -0.071 0.12087E+04 71 enstatite 17.26 12.30 -4.97 -0.497 0.84814E+04 73 clinoenstatite 17.17 12.30 -4.87 -0.487 0.83130E+04 75 epidote 24.67 22.68 -1.99 -0.096 0.33931E+04 76 clinozoisite 22.81 18.87 -3.94 -0.179 0.67240E+04 77 epidote-Fe 29.84 26.50 -3.34 -0.174 0.57087E+04 78 fayalite 14.05 10.31 -3.74 -0.534 0.63833E+04 79 ferrosilite 11.15 7.16 -3.99 -0.399 0.68145E+04 83 gibbsite 4.08 0.72 -3.35 -0.479 0.57277E+04 84 glaucophane 22.97 20.83 -2.15 -0.058 0.36663E+04 85 glaucophane-Fe 17.28 13.12 -4.16 -0.112 0.70980E+04 86 graphite -3.55 -7.68 -4.13 -1.181 0.70572E+04 87 greenalite 16.14 13.89 -2.25 -0.188 0.38469E+04 90 hematite 12.57 9.08 -3.49 -0.423 0.59541E+04 91 heulandite -5.83 -7.52 -1.69 -0.077 0.28938E+04 95 jadeite 4.22 2.76 -1.45 -0.145 0.24764E+04 97 kalsilite 7.58 3.81 -3.77 -0.539 0.64419E+04 98 kaolinite -1.33 -4.85 -3.52 -0.320 0.60021E+04 101 laumontite 2.88 1.92 -0.96 -0.064 0.16375E+04 102 lawsonite 9.62 8.22 -1.39 -0.093 0.23803E+04 103 leucite 4.12 0.66 -3.46 -0.346 0.59019E+04 105 lizardite 23.24 21.60 -1.65 -0.137 0.28147E+04 107 magnetite 20.09 15.81 -4.28 -0.349 0.73084E+04 108 minnesotaite 10.39 7.59 -2.80 -0.165 0.47796E+04 112 manganosite 14.06 9.21 -4.85 -1.213 0.82853E+04 120 muscovite 2.58 -1.04 -3.62 -0.213 0.61797E+04 121 paragonite 4.24 1.07 -3.17 -0.187 0.54189E+04 122 nepheline 8.34 5.91 -2.43 -0.347 0.41418E+04 128 periclase-Fe 11.63 6.73 -4.90 -1.225 0.83641E+04 134 phlogopite-Na 29.65 27.51 -2.14 -0.119 0.36500E+04 136 prehnite 19.37 18.14 -1.23 -0.072 0.20980E+04 137 prehnite-Fe 22.50 21.96 -0.54 -0.032 0.92198E+03 138 pumpellyite-Fe 46.27 43.74 -2.53 -0.056 0.43202E+04 139 pumpellyite-Mg 48.99 46.31 -2.69 -0.060 0.45863E+04 143 pyrrhotite -4.26 -8.06 -3.80 -1.266 0.64866E+04 144 pyrrhotiteFe0.875 -6.02 -9.44 -3.43 -1.260 0.58499E+04 145 pyroxmangite 7.40 6.06 -1.34 -0.268 0.22910E+04 146 pyrophyllite -6.18 -11.15 -4.97 -0.311 0.84858E+04 147 quartz -2.99 -3.15 -0.16 -0.053 0.27214E+03 152 rhodonite 7.45 6.06 -1.39 -0.278 0.23712E+04 153 sanidine -1.28 -2.49 -1.21 -0.093 0.20677E+04 165 stilpnomelane-Mg 27.44 25.87 -1.58 -0.047 0.26916E+04 171 talc 16.49 15.30 -1.19 -0.070 0.20376E+04 174 tephroite 18.09 15.26 -2.82 -0.403 0.48204E+04 178 tridymite -2.63 -3.15 -0.52 -0.174 0.89211E+03 179 tremolite 47.87 47.44 -0.43 -0.012 0.73682E+03 180 ferroactinolite 38.45 34.59 -3.86 -0.104 0.65955E+04 181 troilite-low -4.41 -8.06 -3.65 -1.216 0.62294E+04 187 wairakite 3.95 1.92 -2.03 -0.119 0.34595E+04 188 walstromite 11.51 9.92 -1.59 -0.318 0.27116E+04 189 wollastonite 10.46 9.92 -0.54 -0.108 0.92203E+03 190 pseudo-wollastonite 11.00 9.92 -1.08 -0.216 0.18419E+04 191 zoisite 22.85 18.87 -3.98 -0.181 0.67981E+04 192 akaganeite 7.75 4.54 -3.22 -0.695 0.54896E+04 199 chalcedony -2.80 -3.15 -0.35 -0.115 0.59143E+03 201 montmorillonite-Ca -2.29 -6.16 -3.87 -0.239 0.66067E+04 202 montmorillonite-K -2.24 -6.26 -4.02 -0.246 0.68679E+04 203 montmorillonite-Mg -2.48 -6.78 -4.30 -0.266 0.73465E+04 204 montmorillonite-Na -2.04 -5.57 -3.53 -0.216 0.60228E+04 205 nontronite-Ca 3.21 -0.08 -3.30 -0.214 0.56275E+04 206 nontronite-H 2.53 -2.24 -4.77 -0.320 0.81455E+04 207 nontronite-K 3.34 -0.18 -3.52 -0.226 0.60119E+04 208 nontronite-Mg 3.07 -0.70 -3.78 -0.245 0.64514E+04 209 nontronite-Na 3.52 0.51 -3.01 -0.193 0.51328E+04 224 tobermorite 9.82 7.74 -2.08 -0.569 0.35594E+04 230 alabandite -0.98 -5.58 -4.60 -1.535 0.78606E+04 233 boehmite 4.41 0.72 -3.68 -0.614 0.62860E+04 235 ferrous-oxide 9.81 6.73 -3.08 -0.771 0.52650E+04 240 silica-amorphous -2.09 -3.15 -1.06 -0.352 0.18056E+04 242 an20ab80 2.02 1.34 -0.68 -0.052 0.11619E+04 243 an25ab75 2.65 1.77 -0.88 -0.068 0.14993E+04 244 an30ab70 3.28 2.20 -1.08 -0.083 0.18464E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 4.0000000 g Current total amount of reactant added: 115.9990000 g New total amount of reactant added: 119.9990000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.7297E-13 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 11 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 119.9990000 Water: Moles liquid = 0.5475E+02 kg liquid = 0.9864E+00 Moles total = 0.5400E+02 kg total = 0.9729E+00 Activity = 1.0000 Stoichiometric ionic strength = .1123473E-01 Osmotic coef. = 0.9688 True ionic strength = .1985583E-01 Chg. balance for total moles = -.7297E-13 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.89694E-10 -10.0472 0.75404E-10 -10.1226 0.84068E+00 -0.0754 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13924E-03 -3.8562 0.11636E-03 -3.9342 0.83566E+00 -0.0780 4 SO4-- 0.15390E-11 -11.8128 0.80092E-12 -12.0964 0.52041E+00 -0.2837 5 HCO3- 0.53273E-06 -6.2735 0.44582E-06 -6.3508 0.83687E+00 -0.0773 6 HS- 0.25851E-04 -4.5875 0.21606E-04 -4.6654 0.83578E+00 -0.0779 7 Al+++ 0.98371E-29 -29.0071 0.22838E-29 -29.6413 0.23216E+00 -0.6342 8 H4SiO4 0.70831E-03 -3.1498 0.70831E-03 -3.1498 0.10000E+01 0.0000 9 Ca++ 0.13034E-06 -6.8849 0.67336E-07 -7.1718 0.51662E+00 -0.2868 10 Mg++ 0.21924E-10 -10.6591 0.11275E-10 -10.9479 0.51427E+00 -0.2888 11 Fe++ 0.59148E-13 -13.2281 0.30451E-13 -13.5164 0.51483E+00 -0.2883 12 K+ 0.15524E-03 -3.8090 0.12995E-03 -3.8862 0.83707E+00 -0.0772 13 Na+ 0.19699E-01 -1.7056 0.16459E-01 -1.7836 0.83550E+00 -0.0781 14 Mn++ 0.17782E-10 -10.7500 0.91625E-11 -11.0380 0.51525E+00 -0.2880 15 HPO4-- 0.48813E-07 -7.3115 0.25407E-07 -7.5951 0.52049E+00 -0.2836 16 HSiO3- 0.10496E-01 -1.9790 0.87711E-02 -2.0569 0.83566E+00 -0.0780 17 Ca(HSiO3)+ 0.16065E-07 -7.7941 0.13450E-07 -7.8713 0.83725E+00 -0.0771 18 Mg(HSiO3)+ 0.33477E-11 -11.4753 0.28028E-11 -11.5524 0.83725E+00 -0.0771 19 NaHSiO3,aq 0.23348E-02 -2.6317 0.23348E-02 -2.6317 0.10000E+01 0.0000 20 AlO+ 0.65266E-16 -16.1853 0.54644E-16 -16.2625 0.83725E+00 -0.0771 22 HAlO2,aq 0.14432E-09 -9.8407 0.14432E-09 -9.8407 0.10000E+01 0.0000 23 AlO2- 0.50790E-05 -5.2942 0.42366E-05 -5.3730 0.83416E+00 -0.0788 24 CH4,aq 0.11723E-04 -4.9310 0.11682E-04 -4.9325 0.99657E+00 -0.0015 25 C2H6,aq 0.25122E-14 -14.5999 0.25036E-14 -14.6014 0.99657E+00 -0.0015 29 CO,aq 0.16816E-16 -16.7743 0.16816E-16 -16.7743 0.10000E+01 0.0000 30 CO2,aq 0.72079E-10 -10.1422 0.71832E-10 -10.1437 0.99657E+00 -0.0015 31 CO3-2 0.99445E-06 -6.0024 0.51643E-06 -6.2870 0.51931E+00 -0.2846 32 CaCO3,aq 0.43604E-09 -9.3605 0.43604E-09 -9.3605 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.91526E-12 -12.0385 0.76630E-12 -12.1156 0.83725E+00 -0.0771 34 CaCl+ 0.15145E-10 -10.8197 0.12680E-10 -10.8969 0.83725E+00 -0.0771 35 CaCl2,aq 0.35052E-15 -15.4553 0.35052E-15 -15.4553 0.10000E+01 0.0000 36 CaOH+ 0.76016E-07 -7.1191 0.63644E-07 -7.1962 0.83725E+00 -0.0771 37 CaSO4,aq 0.17126E-16 -16.7664 0.17126E-16 -16.7664 0.10000E+01 0.0000 38 HCl,aq 0.16078E-14 -14.7938 0.16078E-14 -14.7938 0.10000E+01 0.0000 43 FeCl+ 0.66986E-17 -17.1740 0.56084E-17 -17.2512 0.83725E+00 -0.0771 46 FeO,aq 0.20815E-09 -9.6816 0.20815E-09 -9.6816 0.10000E+01 0.0000 47 FeOH+ 0.15701E-10 -10.8041 0.13145E-10 -10.8812 0.83725E+00 -0.0771 48 HFeO2- 0.34564E-07 -7.4614 0.28883E-07 -7.5394 0.83566E+00 -0.0780 49 FeO+ 0.12268E-16 -16.9112 0.10271E-16 -16.9884 0.83725E+00 -0.0771 51 FeO2- 0.44233E-09 -9.3543 0.36963E-09 -9.4322 0.83566E+00 -0.0780 52 HFeO2,aq 0.35449E-11 -11.4504 0.35449E-11 -11.4504 0.10000E+01 0.0000 53 H2,aq 0.93513E-05 -5.0291 0.93192E-05 -5.0306 0.99657E+00 -0.0015 54 KCl,aq 0.27405E-09 -9.5622 0.27405E-09 -9.5622 0.10000E+01 0.0000 56 KOH,aq 0.73596E-06 -6.1331 0.73596E-06 -6.1331 0.10000E+01 0.0000 57 KSO4- 0.19327E-14 -14.7138 0.16150E-14 -14.7918 0.83566E+00 -0.0780 58 MgCO3,aq 0.18300E-13 -13.7375 0.18300E-13 -13.7375 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.15659E-15 -15.8052 0.13111E-15 -15.8824 0.83725E+00 -0.0771 60 MgCl+ 0.22983E-14 -14.6386 0.19243E-14 -14.7157 0.83725E+00 -0.0771 61 MgOH+ 0.70431E-10 -10.1522 0.58968E-10 -10.2294 0.83725E+00 -0.0771 63 MnO,aq 0.16688E-08 -8.7776 0.16688E-08 -8.7776 0.10000E+01 0.0000 64 MnOH+ 0.43886E-09 -9.3577 0.36744E-09 -9.4348 0.83725E+00 -0.0771 65 MnO2-2 0.18757E-10 -10.7268 0.97408E-11 -11.0114 0.51931E+00 -0.2846 66 HMnO2- 0.19256E-09 -9.7154 0.16092E-09 -9.7934 0.83566E+00 -0.0780 69 MnCl+ 0.78414E-14 -14.1056 0.65652E-14 -14.1828 0.83725E+00 -0.0771 71 NaCl,aq 0.63467E-06 -6.1975 0.63467E-06 -6.1975 0.10000E+01 0.0000 72 NaOH,aq 0.93780E-04 -4.0279 0.93780E-04 -4.0279 0.10000E+01 0.0000 74 OH- 0.91858E-02 -2.0369 0.76624E-02 -2.1156 0.83416E+00 -0.0788 79 HPO3-2 0.14208E-14 -14.8475 0.73786E-15 -15.1320 0.51931E+00 -0.2846 81 H2PO3- 0.13351E-18 -18.8745 0.11157E-18 -18.9525 0.83566E+00 -0.0780 82 H3PO4,aq 0.10103E-17 -17.9955 0.10103E-17 -17.9955 0.10000E+01 0.0000 83 H2PO4- 0.42251E-10 -10.3742 0.35341E-10 -10.4517 0.83644E+00 -0.0776 84 PO4-3 0.11278E-08 -8.9478 0.27491E-09 -9.5608 0.24376E+00 -0.6130 88 HP2O7-3 0.11159E-17 -17.9524 0.25933E-18 -18.5861 0.23239E+00 -0.6338 89 P2O7-4 0.10566E-16 -16.9761 0.82162E-18 -18.0853 0.77763E-01 -1.1092 90 H2S,aq 0.50525E-08 -8.2965 0.50352E-08 -8.2980 0.99657E+00 -0.0015 91 S2-2 0.21373E-14 -14.6701 0.11099E-14 -14.9547 0.51931E+00 -0.2846 97 SO3-2 0.18413E-17 -17.7349 0.96994E-18 -18.0133 0.52678E+00 -0.2784 99 HSO4- 0.69449E-19 -19.1583 0.58202E-19 -19.2351 0.83805E+00 -0.0767 Charge balance for all species = -.7492E-13 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.8969444E-10 -.2213501E-01 -.2227214E+02 0.0000 2 H2O 0.1000000E+01 0.5550473E+02 0.9982034E+06 0.0000 3 Cl- 0.1392427E-03 0.1398776E-03 0.4950497E+01 6.1884 4 SO4-- 0.1539020E-11 -.1406038E-04 -.1348325E+01 8.1488 5 HCO3- 0.5327295E-06 0.1325031E-04 0.8070973E+00 3.7718 6 HS- 0.2585127E-04 0.3991670E-04 0.1317840E+01 5.4572 7 Al+++ 0.9837111E-29 0.5079096E-05 0.1368044E+00 0.7265 8 H4SiO4 0.7083068E-03 0.1353920E-01 0.1299073E+04 -3.1498 9 Ca++ 0.1303411E-06 0.2228744E-06 0.8916897E-02 13.0735 10 Mg++ 0.2192398E-10 0.9572359E-10 0.2323203E-05 9.2973 11 Fe++ 0.5914827E-13 0.3523332E-07 0.1964269E-02 6.7288 12 K+ 0.1552410E-03 0.1559772E-03 0.6088463E+01 6.2364 13 Na+ 0.1969905E-01 0.2212829E-01 0.5078444E+03 8.3390 14 Mn++ 0.1778248E-10 0.2336814E-08 0.1281576E-03 9.2072 15 HPO4-- 0.4881341E-07 0.4998345E-07 0.4789057E-02 12.6502 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.1986992E+01 -.2183379E-01 -.1965158E+01 0.0000000E+00 2 H2O 0.5400401E+02 0.5474942E+02 -.7454079E+00 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.3351086E-02 -.1386905E-04 0.3364955E-02 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.3325581E-02 0.3937352E-04 -.3364955E-02 0.0000000E+00 7 Al+++ 0.3912857E+00 0.5009980E-05 0.3912807E+00 0.0000000E+00 8 H4SiO4 0.1249524E+01 0.1335496E-01 0.1236169E+01 0.0000000E+00 9 Ca++ 0.1380304E+00 0.2198415E-06 0.1380302E+00 0.0000000E+00 10 Mg++ 0.9523730E-01 0.9442098E-10 0.9523730E-01 0.0000000E+00 11 Fe++ 0.8556032E-01 0.3475386E-07 0.8556028E-01 0.0000000E+00 12 K+ 0.2547749E-01 0.1538547E-03 0.2532364E-01 0.0000000E+00 13 Na+ 0.1507881E+00 0.2182717E-01 0.1289609E+00 0.0000000E+00 14 Mn++ 0.2080614E-02 0.2305015E-08 0.2080612E-02 0.0000000E+00 15 HPO4-- 0.7101033E-03 0.4930327E-07 0.7100540E-03 0.0000000E+00 Chg. balance for solid moles: 0.1392E-15 Mass of aqueous solution: 0.988102E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 119.9990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 0.1289 -0.890 33.80 1.529 25.81 12.97 andradite 0.1346E-01 -1.871 6.840 0.835 5.224 1.777 grossular 0.2881E-02 -2.540 1.298 0.113 0.9912 0.3611 apatite-OH 0.2367E-03 -3.626 0.1189 -0.925 0.9080E-01 0.3778E-01 clinochlore 0.1858E-01 -1.731 10.33 1.014 7.889 3.929 daphnite 0.5266E-02 -2.279 3.757 0.575 2.870 1.139 chlorite-Mn 0.4161E-03 -3.381 0.2950 -0.530 0.2253 0.9401E-01 microcline 0.2217E-01 -1.654 6.172 0.790 4.713 2.411 stilbite 0.8654E-01 -1.063 60.99 1.785 46.58 28.45 stilpnomelane-Fe 0.6302E-02 -2.201 6.794 0.832 5.189 2.347 tr.625ac.25prg.125 0.6398E-03 -3.194 0.5468 -0.262 0.4176 0.1760 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8237E+00 0.8237E+00 1.0000 -0.084 grossular 0.1763E+00 0.1763E+00 1.0000 -0.754 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.7658E+00 0.7658E+00 1.0000 -0.116 daphnite 0.2170E+00 0.2170E+00 1.0000 -0.664 chlorite-Mn 0.1715E-01 0.1715E-01 1.0000 -1.766 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 tr.625ac.25prg.125 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 130.935313 g Volume = 53.690909 cm3 Porosity: -9.5742% V(tot) - V(min): -.46913E+01 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 119.9990000 g log = 2.0792 Original solution: 1000.0103000 g Original solution / Rock added: 8.33 (Water/Rock Ratio), log = 0.9208 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0499 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9722E+00 0.9855 0.1006E+01 0.1021E+01 CO2,gas 0.7269E-08 1.0069 0.7685E-08 0.7632E-08 CH4,gas 0.1618E-01 1.0124 0.1720E-01 0.1698E-01 H2,gas 0.1165E-01 1.0006 0.1224E-01 0.1223E-01 H2S,gas 0.1324E-06 0.9959 0.1384E-06 0.1390E-06 S2,gas 0.4575E-29 1.0000 0.4804E-29 0.4804E-29 CO,gas 0.2387E-13 1.0000 0.2506E-13 0.2506E-13 SO3,gas 0.1640E-47 1.0000 0.1722E-47 0.1722E-47 SO2,gas 0.7806E-27 1.0000 0.8196E-27 0.8196E-27 HCl,gas 0.2702E-17 1.0000 0.2837E-17 0.2837E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 16 albite -0.38 -0.38 0.00 0.000 -0.94784E-12 22 andradite 39.01 39.01 0.00 0.000 0.36397E-10 23 grossular 32.73 32.73 0.00 0.000 0.00000E+00 32 apatite-OH -18.15 -18.15 0.00 0.000 0.12132E-10 46 clinochlore 39.07 39.07 0.00 0.000 0.12132E-10 47 daphnite 28.97 28.97 0.00 0.000 0.42463E-10 48 chlorite-Mn 46.87 46.87 0.00 0.000 0.24265E-10 116 microcline -2.49 -2.49 0.00 0.000 0.15165E-11 163 stilbite -7.52 -7.52 0.00 0.000 -0.90992E-11 164 stilpnomelane-Fe 13.02 13.02 0.00 0.000 -0.27298E-10 245 tr.625ac.25prg.125 45.16 45.16 0.00 0.000 -0.24265E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -16.47 -9.81 -3.271 0.16756E+05 -8.114 3 CH4,gas 4.54 1.08 -3.46 -0.866 0.59139E+04 -1.765 4 H2,gas 8.00 4.39 -3.61 -2.064 0.61663E+04 -1.912 5 H2S,gas -6.23 -14.79 -8.56 -4.279 0.14612E+05 -6.859 6 S2,gas -7.34 -38.35 -31.02 -4.772 0.52961E+05 -29.318 7 CO,gas 3.21 -12.09 -15.30 -4.708 0.26124E+05 -13.601 8 SO3,gas 17.12 -32.34 -49.46 -12.366 0.84457E+05 -47.764 9 SO2,gas 0.83 -27.95 -28.79 -7.676 0.49150E+05 -27.086 10 HCl,gas 5.19 -14.06 -19.25 -9.623 0.32862E+05 -17.547 11 acmite 7.71 6.57 -1.14 -0.118 0.19391E+04 15 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 19 spessartine 24.46 19.63 -4.83 -0.242 0.82506E+04 20 analcite 3.32 2.77 -0.56 -0.062 0.94927E+03 26 annite 20.12 17.70 -2.42 -0.135 0.41380E+04 27 phlogopite 27.06 25.41 -1.66 -0.092 0.28329E+04 29 anorthite 12.71 8.23 -4.48 -0.345 0.76554E+04 35 aragonite 0.97 -3.40 -4.37 -1.456 0.74557E+04 36 brucite 12.57 9.30 -3.27 -0.654 0.55856E+04 37 calcite 0.81 -3.40 -4.21 -1.404 0.71915E+04 38 carnegieite-low 9.02 5.92 -3.11 -0.444 0.53062E+04 39 carnegieite-high 10.09 5.92 -4.18 -0.597 0.71331E+04 40 carpholite-Mg 8.58 4.45 -4.13 -0.275 0.70542E+04 41 carpholite-Fe 6.71 1.88 -4.83 -0.322 0.82478E+04 42 celadonite 5.34 3.66 -1.68 -0.099 0.28695E+04 43 celadonite-Fe 3.88 1.09 -2.78 -0.164 0.47536E+04 44 chrysotile 23.89 21.59 -2.30 -0.192 0.39272E+04 49 chlorite-Al-free 47.17 43.18 -3.99 -0.166 0.68095E+04 51 chloritoid-Fe 9.17 5.03 -4.14 -0.276 0.70718E+04 52 chloritoid-Mn 11.40 7.51 -3.89 -0.259 0.66432E+04 54 coesite -2.38 -3.15 -0.77 -0.258 0.13211E+04 61 cristobalite -2.56 -3.15 -0.59 -0.196 0.10065E+04 63 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71234E+04 65 diaspore 2.87 0.73 -2.15 -0.358 0.36663E+04 66 diamond -3.10 -7.70 -4.59 -1.313 0.78446E+04 67 diopside 16.18 16.07 -0.11 -0.011 0.18805E+03 68 hedenbergite 14.21 13.50 -0.71 -0.071 0.12047E+04 71 enstatite 17.26 12.30 -4.97 -0.497 0.84858E+04 73 clinoenstatite 17.17 12.30 -4.87 -0.487 0.83174E+04 75 epidote 24.67 22.69 -1.98 -0.096 0.33890E+04 76 clinozoisite 22.81 18.88 -3.93 -0.179 0.67087E+04 77 epidote-Fe 29.84 26.49 -3.35 -0.174 0.57158E+04 78 fayalite 14.05 10.31 -3.74 -0.534 0.63823E+04 79 ferrosilite 11.15 7.16 -3.99 -0.399 0.68152E+04 83 gibbsite 4.08 0.73 -3.35 -0.479 0.57249E+04 84 glaucophane 22.97 20.82 -2.15 -0.058 0.36713E+04 85 glaucophane-Fe 17.28 13.12 -4.16 -0.112 0.70974E+04 86 graphite -3.55 -7.70 -4.15 -1.186 0.70868E+04 87 greenalite 16.14 13.89 -2.25 -0.188 0.38463E+04 90 hematite 12.57 9.07 -3.50 -0.424 0.59709E+04 91 heulandite -5.83 -7.52 -1.69 -0.077 0.28938E+04 95 jadeite 4.22 2.77 -1.45 -0.145 0.24748E+04 97 kalsilite 7.58 3.81 -3.77 -0.539 0.64386E+04 98 kaolinite -1.33 -4.85 -3.51 -0.319 0.59998E+04 101 laumontite 2.88 1.93 -0.96 -0.064 0.16326E+04 102 lawsonite 9.62 8.23 -1.39 -0.093 0.23721E+04 103 leucite 4.12 0.66 -3.46 -0.346 0.59003E+04 105 lizardite 23.24 21.59 -1.65 -0.138 0.28198E+04 107 magnetite 20.09 15.80 -4.29 -0.350 0.73239E+04 108 minnesotaite 10.39 7.59 -2.80 -0.165 0.47822E+04 112 manganosite 14.06 9.21 -4.85 -1.213 0.82828E+04 120 muscovite 2.58 -1.03 -3.62 -0.213 0.61742E+04 121 paragonite 4.24 1.07 -3.17 -0.186 0.54133E+04 122 nepheline 8.34 5.92 -2.42 -0.346 0.41385E+04 128 periclase-Fe 11.63 6.73 -4.90 -1.224 0.83628E+04 134 phlogopite-Na 29.65 27.51 -2.14 -0.119 0.36517E+04 136 prehnite 19.37 18.15 -1.22 -0.072 0.20854E+04 137 prehnite-Fe 22.50 21.96 -0.54 -0.032 0.92066E+03 138 pumpellyite-Fe 46.27 43.76 -2.51 -0.056 0.42910E+04 139 pumpellyite-Mg 48.99 46.32 -2.67 -0.059 0.45590E+04 143 pyrrhotite -4.26 -8.06 -3.80 -1.266 0.64865E+04 144 pyrrhotiteFe0.875 -6.02 -9.44 -3.43 -1.261 0.58524E+04 145 pyroxmangite 7.40 6.06 -1.34 -0.268 0.22901E+04 146 pyrophyllite -6.18 -11.15 -4.97 -0.311 0.84868E+04 147 quartz -2.99 -3.15 -0.16 -0.053 0.27378E+03 152 rhodonite 7.45 6.06 -1.39 -0.278 0.23704E+04 153 sanidine -1.28 -2.49 -1.21 -0.093 0.20677E+04 165 stilpnomelane-Mg 27.44 25.86 -1.58 -0.047 0.27011E+04 171 talc 16.49 15.29 -1.20 -0.070 0.20459E+04 174 tephroite 18.09 15.26 -2.82 -0.403 0.48170E+04 178 tridymite -2.63 -3.15 -0.52 -0.174 0.89376E+03 179 tremolite 47.87 47.44 -0.43 -0.012 0.74098E+03 180 ferroactinolite 38.45 34.59 -3.86 -0.104 0.65902E+04 181 troilite-low -4.41 -8.06 -3.65 -1.216 0.62293E+04 187 wairakite 3.95 1.93 -2.02 -0.119 0.34545E+04 188 walstromite 11.51 9.92 -1.59 -0.317 0.27073E+04 189 wollastonite 10.46 9.92 -0.54 -0.107 0.91771E+03 190 pseudo-wollastonite 11.00 9.92 -1.08 -0.215 0.18375E+04 191 zoisite 22.85 18.88 -3.97 -0.181 0.67828E+04 192 akaganeite 7.75 4.53 -3.22 -0.696 0.54980E+04 199 chalcedony -2.80 -3.15 -0.35 -0.116 0.59308E+03 201 montmorillonite-Ca -2.29 -6.16 -3.87 -0.239 0.66078E+04 202 montmorillonite-K -2.24 -6.26 -4.02 -0.246 0.68693E+04 203 montmorillonite-Mg -2.48 -6.78 -4.30 -0.266 0.73487E+04 204 montmorillonite-Na -2.04 -5.57 -3.53 -0.216 0.60242E+04 205 nontronite-Ca 3.21 -0.09 -3.31 -0.215 0.56486E+04 206 nontronite-H 2.53 -2.25 -4.78 -0.321 0.81676E+04 207 nontronite-K 3.34 -0.19 -3.53 -0.227 0.60332E+04 208 nontronite-Mg 3.07 -0.72 -3.79 -0.246 0.64735E+04 209 nontronite-Na 3.52 0.50 -3.02 -0.194 0.51541E+04 224 tobermorite 9.82 7.74 -2.08 -0.568 0.35560E+04 230 alabandite -0.98 -5.58 -4.60 -1.534 0.78594E+04 233 boehmite 4.41 0.73 -3.68 -0.613 0.62833E+04 235 ferrous-oxide 9.81 6.73 -3.08 -0.771 0.52637E+04 240 silica-amorphous -2.09 -3.15 -1.06 -0.353 0.18073E+04 242 an20ab80 2.02 1.34 -0.68 -0.052 0.11602E+04 243 an25ab75 2.65 1.77 -0.88 -0.067 0.14973E+04 244 an30ab70 3.28 2.20 -1.08 -0.083 0.18439E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 4.0000000 g Current total amount of reactant added: 119.9990000 g New total amount of reactant added: 123.9990000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.7249E-13 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 11 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 123.9990000 Water: Moles liquid = 0.5473E+02 kg liquid = 0.9860E+00 Moles total = 0.5395E+02 kg total = 0.9720E+00 Activity = 1.0000 Stoichiometric ionic strength = .1124397E-01 Osmotic coef. = 0.9689 True ionic strength = .1987270E-01 Chg. balance for total moles = -.7249E-13 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.89528E-10 -10.0480 0.75261E-10 -10.1234 0.84063E+00 -0.0754 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13930E-03 -3.8561 0.11640E-03 -3.9341 0.83561E+00 -0.0780 4 SO4-- 0.13990E-11 -11.8542 0.72790E-12 -12.1379 0.52030E+00 -0.2837 5 HCO3- 0.48930E-06 -6.3104 0.40946E-06 -6.3878 0.83682E+00 -0.0774 6 HS- 0.25862E-04 -4.5873 0.21613E-04 -4.6653 0.83573E+00 -0.0779 7 Al+++ 0.98200E-29 -29.0079 0.22786E-29 -29.6423 0.23204E+00 -0.6344 8 H4SiO4 0.70685E-03 -3.1507 0.70685E-03 -3.1507 0.10000E+01 0.0000 9 Ca++ 0.13085E-06 -6.8832 0.67583E-07 -7.1702 0.51650E+00 -0.2869 10 Mg++ 0.21830E-10 -10.6610 0.11224E-10 -10.9499 0.51415E+00 -0.2889 11 Fe++ 0.59033E-13 -13.2289 0.30385E-13 -13.5173 0.51471E+00 -0.2884 12 K+ 0.15537E-03 -3.8086 0.13005E-03 -3.8859 0.83702E+00 -0.0773 13 Na+ 0.19716E-01 -1.7052 0.16472E-01 -1.7833 0.83546E+00 -0.0781 14 Mn++ 0.17775E-10 -10.7502 0.91567E-11 -11.0383 0.51513E+00 -0.2881 15 HPO4-- 0.48405E-07 -7.3151 0.25189E-07 -7.5988 0.52037E+00 -0.2837 16 HSiO3- 0.10495E-01 -1.9790 0.87698E-02 -2.0570 0.83561E+00 -0.0780 17 Ca(HSiO3)+ 0.16122E-07 -7.7926 0.13498E-07 -7.8697 0.83720E+00 -0.0772 18 Mg(HSiO3)+ 0.33322E-11 -11.4773 0.27897E-11 -11.5544 0.83720E+00 -0.0772 19 NaHSiO3,aq 0.23363E-02 -2.6315 0.23363E-02 -2.6315 0.10000E+01 0.0000 20 AlO+ 0.65372E-16 -16.1846 0.54729E-16 -16.2618 0.83720E+00 -0.0772 22 HAlO2,aq 0.14482E-09 -9.8392 0.14482E-09 -9.8392 0.10000E+01 0.0000 23 AlO2- 0.51066E-05 -5.2919 0.42595E-05 -5.3706 0.83411E+00 -0.0788 24 CH4,aq 0.11851E-04 -4.9263 0.11810E-04 -4.9277 0.99657E+00 -0.0015 25 C2H6,aq 0.25054E-14 -14.6011 0.24968E-14 -14.6026 0.99657E+00 -0.0015 29 CO,aq 0.15797E-16 -16.8014 0.15797E-16 -16.8014 0.10000E+01 0.0000 30 CO2,aq 0.66073E-10 -10.1800 0.65846E-10 -10.1815 0.99657E+00 -0.0015 31 CO3-2 0.91527E-06 -6.0385 0.47521E-06 -6.3231 0.51920E+00 -0.2847 32 CaCO3,aq 0.40270E-09 -9.3950 0.40270E-09 -9.3950 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.84372E-12 -12.0738 0.70636E-12 -12.1510 0.83720E+00 -0.0772 34 CaCl+ 0.15206E-10 -10.8180 0.12731E-10 -10.8952 0.83720E+00 -0.0772 35 CaCl2,aq 0.35205E-15 -15.4534 0.35205E-15 -15.4534 0.10000E+01 0.0000 36 CaOH+ 0.76444E-07 -7.1167 0.63999E-07 -7.1938 0.83720E+00 -0.0772 37 CaSO4,aq 0.15621E-16 -16.8063 0.15621E-16 -16.8063 0.10000E+01 0.0000 38 HCl,aq 0.16053E-14 -14.7944 0.16053E-14 -14.7944 0.10000E+01 0.0000 43 FeCl+ 0.66867E-17 -17.1748 0.55981E-17 -17.2520 0.83720E+00 -0.0772 46 FeO,aq 0.20849E-09 -9.6809 0.20849E-09 -9.6809 0.10000E+01 0.0000 47 FeOH+ 0.15697E-10 -10.8042 0.13142E-10 -10.8813 0.83720E+00 -0.0772 48 HFeO2- 0.34688E-07 -7.4598 0.28986E-07 -7.5378 0.83561E+00 -0.0780 49 FeO+ 0.12116E-16 -16.9166 0.10143E-16 -16.9938 0.83720E+00 -0.0772 51 FeO2- 0.43852E-09 -9.3580 0.36643E-09 -9.4360 0.83561E+00 -0.0780 52 HFeO2,aq 0.35075E-11 -11.4550 0.35075E-11 -11.4550 0.10000E+01 0.0000 53 H2,aq 0.95829E-05 -5.0185 0.95500E-05 -5.0200 0.99657E+00 -0.0015 54 KCl,aq 0.27436E-09 -9.5617 0.27436E-09 -9.5617 0.10000E+01 0.0000 56 KOH,aq 0.73796E-06 -6.1320 0.73796E-06 -6.1320 0.10000E+01 0.0000 57 KSO4- 0.17579E-14 -14.7550 0.14689E-14 -14.8330 0.83561E+00 -0.0780 58 MgCO3,aq 0.16763E-13 -13.7756 0.16763E-13 -13.7756 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.14318E-15 -15.8441 0.11987E-15 -15.9213 0.83720E+00 -0.0772 60 MgCl+ 0.22888E-14 -14.6404 0.19162E-14 -14.7176 0.83720E+00 -0.0772 61 MgOH+ 0.70249E-10 -10.1534 0.58813E-10 -10.2305 0.83720E+00 -0.0772 63 MnO,aq 0.16742E-08 -8.7762 0.16742E-08 -8.7762 0.10000E+01 0.0000 64 MnOH+ 0.43945E-09 -9.3571 0.36791E-09 -9.4343 0.83720E+00 -0.0772 65 MnO2-2 0.18893E-10 -10.7237 0.98092E-11 -11.0084 0.51920E+00 -0.2847 66 HMnO2- 0.19356E-09 -9.7132 0.16174E-09 -9.7912 0.83561E+00 -0.0780 69 MnCl+ 0.78397E-14 -14.1057 0.65633E-14 -14.1829 0.83720E+00 -0.0772 71 NaCl,aq 0.63540E-06 -6.1970 0.63540E-06 -6.1970 0.10000E+01 0.0000 72 NaOH,aq 0.94034E-04 -4.0267 0.94034E-04 -4.0267 0.10000E+01 0.0000 74 OH- 0.92038E-02 -2.0360 0.76770E-02 -2.1148 0.83411E+00 -0.0788 79 HPO3-2 0.14438E-14 -14.8405 0.74964E-15 -15.1251 0.51920E+00 -0.2847 81 H2PO3- 0.13539E-18 -18.8684 0.11314E-18 -18.9464 0.83561E+00 -0.0780 82 H3PO4,aq 0.99784E-18 -18.0009 0.99784E-18 -18.0009 0.10000E+01 0.0000 83 H2PO4- 0.41811E-10 -10.3787 0.34971E-10 -10.4563 0.83639E+00 -0.0776 84 PO4-3 0.11208E-08 -8.9505 0.27307E-09 -9.5637 0.24364E+00 -0.6132 88 HP2O7-3 0.10953E-17 -17.9605 0.25441E-18 -18.5945 0.23227E+00 -0.6340 89 P2O7-4 0.10394E-16 -16.9832 0.80757E-18 -18.0928 0.77695E-01 -1.1096 90 H2S,aq 0.50446E-08 -8.2972 0.50273E-08 -8.2987 0.99657E+00 -0.0015 91 S2-2 0.20876E-14 -14.6804 0.10839E-14 -14.9650 0.51920E+00 -0.2847 97 SO3-2 0.17152E-17 -17.7657 0.90334E-18 -18.0442 0.52666E+00 -0.2785 99 HSO4- 0.63000E-19 -19.2007 0.52794E-19 -19.2774 0.83801E+00 -0.0768 Charge balance for all species = -.7530E-13 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.8952845E-10 -.2215392E-01 -.2229116E+02 0.0000 2 H2O 0.1000000E+01 0.5550475E+02 0.9982031E+06 0.0000 3 Cl- 0.1392987E-03 0.1399344E-03 0.4952504E+01 6.1894 4 SO4-- 0.1399005E-11 -.1424632E-04 -.1366154E+01 8.1089 5 HCO3- 0.4892988E-06 0.1325569E-04 0.8074244E+00 3.7356 6 HS- 0.2586177E-04 0.4011314E-04 0.1324324E+01 5.4582 7 Al+++ 0.9819988E-29 0.5106750E-05 0.1375492E+00 0.7280 8 H4SiO4 0.7068519E-03 0.1353826E-01 0.1298982E+04 -3.1507 9 Ca++ 0.1308472E-06 0.2238320E-06 0.8955204E-02 13.0767 10 Mg++ 0.2182957E-10 0.9543037E-10 0.2316085E-05 9.2970 11 Fe++ 0.5903311E-13 0.3535429E-07 0.1971012E-02 6.7295 12 K+ 0.1553733E-03 0.1561116E-03 0.6093704E+01 6.2375 13 Na+ 0.1971588E-01 0.2214688E-01 0.5082706E+03 8.3402 14 Mn++ 0.1777542E-10 0.2343848E-08 0.1285433E-03 9.2086 15 HPO4-- 0.4840504E-07 0.4956762E-07 0.4749211E-02 12.6481 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.2053226E+01 -.2184359E-01 -.2031383E+01 0.0000000E+00 2 H2O 0.5395387E+02 0.5472722E+02 -.7733517E+00 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.3461939E-02 -.1404675E-04 0.3475986E-02 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.3436435E-02 0.3955122E-04 -.3475986E-02 0.0000000E+00 7 Al+++ 0.4043287E+00 0.5035213E-05 0.4043237E+00 0.0000000E+00 8 H4SiO4 0.1291175E+01 0.1334862E-01 0.1277826E+01 0.0000000E+00 9 Ca++ 0.1426310E+00 0.2206965E-06 0.1426308E+00 0.0000000E+00 10 Mg++ 0.9841190E-01 0.9409355E-10 0.9841190E-01 0.0000000E+00 11 Fe++ 0.8841235E-01 0.3485904E-07 0.8841232E-01 0.0000000E+00 12 K+ 0.2632675E-01 0.1539247E-03 0.2617283E-01 0.0000000E+00 13 Na+ 0.1558090E+00 0.2183664E-01 0.1339724E+00 0.0000000E+00 14 Mn++ 0.2149969E-02 0.2311015E-08 0.2149966E-02 0.0000000E+00 15 HPO4-- 0.7337736E-03 0.4887326E-07 0.7337247E-03 0.0000000E+00 Chg. balance for solid moles: 0.2880E-15 Mass of aqueous solution: 0.987702E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 123.9990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 0.1339 -0.873 35.11 1.545 25.95 13.48 andradite 0.1390E-01 -1.857 7.066 0.849 5.222 1.836 grossular 0.3018E-02 -2.520 1.360 0.133 1.005 0.3783 apatite-OH 0.2446E-03 -3.612 0.1229 -0.911 0.9080E-01 0.3904E-01 clinochlore 0.1913E-01 -1.718 10.63 1.027 7.858 4.044 daphnite 0.5433E-02 -2.265 3.877 0.588 2.865 1.175 chlorite-Mn 0.4300E-03 -3.367 0.3049 -0.516 0.2253 0.9715E-01 microcline 0.2292E-01 -1.640 6.381 0.805 4.716 2.493 stilbite 0.8911E-01 -1.050 62.80 1.798 46.41 29.29 stilpnomelane-Fe 0.6497E-02 -2.187 7.003 0.845 5.176 2.419 tr.625ac.25prg.125 0.7647E-03 -3.117 0.6536 -0.185 0.4831 0.2104 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8216E+00 0.8216E+00 1.0000 -0.085 grossular 0.1784E+00 0.1784E+00 1.0000 -0.749 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.7654E+00 0.7654E+00 1.0000 -0.116 daphnite 0.2174E+00 0.2174E+00 1.0000 -0.663 chlorite-Mn 0.1721E-01 0.1721E-01 1.0000 -1.764 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 tr.625ac.25prg.125 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 135.303249 g Volume = 55.457582 cm3 Porosity: -9.6008% V(tot) - V(min): -.48580E+01 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 123.9990000 g log = 2.0934 Original solution: 1000.0103000 g Original solution / Rock added: 8.06 (Water/Rock Ratio), log = 0.9066 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0504 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9717E+00 0.9855 0.1006E+01 0.1021E+01 CO2,gas 0.6660E-08 1.0069 0.7045E-08 0.6996E-08 CH4,gas 0.1635E-01 1.0125 0.1738E-01 0.1717E-01 H2,gas 0.1193E-01 1.0006 0.1254E-01 0.1253E-01 H2S,gas 0.1321E-06 0.9959 0.1382E-06 0.1388E-06 S2,gas 0.4341E-29 1.0000 0.4560E-29 0.4560E-29 CO,gas 0.2241E-13 1.0000 0.2354E-13 0.2354E-13 SO3,gas 0.1484E-47 1.0000 0.1559E-47 0.1559E-47 SO2,gas 0.7239E-27 1.0000 0.7604E-27 0.7604E-27 HCl,gas 0.2697E-17 1.0000 0.2833E-17 0.2833E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 16 albite -0.38 -0.38 0.00 0.000 -0.94784E-12 22 andradite 39.01 39.01 0.00 0.000 0.00000E+00 23 grossular 32.73 32.73 0.00 0.000 0.00000E+00 32 apatite-OH -18.15 -18.15 0.00 0.000 -0.60662E-11 46 clinochlore 39.07 39.07 0.00 0.000 0.00000E+00 47 daphnite 28.97 28.97 0.00 0.000 -0.30331E-10 48 chlorite-Mn 46.87 46.87 0.00 0.000 -0.12132E-10 116 microcline -2.49 -2.49 0.00 0.000 0.13649E-10 163 stilbite -7.52 -7.52 0.00 0.000 0.15165E-10 164 stilpnomelane-Fe 13.02 13.02 0.00 0.000 -0.27298E-10 245 tr.625ac.25prg.125 45.16 45.16 0.00 0.000 0.24265E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -16.51 -9.85 -3.284 0.16820E+05 -8.152 3 CH4,gas 4.54 1.08 -3.46 -0.865 0.59059E+04 -1.760 4 H2,gas 8.00 4.40 -3.60 -2.058 0.61482E+04 -1.902 5 H2S,gas -6.23 -14.79 -8.56 -4.279 0.14613E+05 -6.859 6 S2,gas -7.34 -38.38 -31.04 -4.775 0.53000E+05 -29.341 7 CO,gas 3.21 -12.11 -15.33 -4.716 0.26171E+05 -13.628 8 SO3,gas 17.12 -32.38 -49.51 -12.377 0.84530E+05 -47.807 9 SO2,gas 0.83 -27.99 -28.82 -7.685 0.49206E+05 -27.119 10 HCl,gas 5.19 -14.06 -19.25 -9.623 0.32863E+05 -17.548 11 acmite 7.71 6.57 -1.14 -0.119 0.19480E+04 15 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 19 spessartine 24.46 19.63 -4.83 -0.241 0.82430E+04 20 analcite 3.32 2.77 -0.56 -0.062 0.94774E+03 26 annite 20.12 17.70 -2.42 -0.135 0.41343E+04 27 phlogopite 27.06 25.40 -1.66 -0.092 0.28345E+04 29 anorthite 12.71 8.23 -4.48 -0.345 0.76478E+04 35 aragonite 0.97 -3.43 -4.40 -1.467 0.75147E+04 36 brucite 12.57 9.30 -3.27 -0.654 0.55861E+04 37 calcite 0.81 -3.43 -4.25 -1.415 0.72504E+04 38 carnegieite-low 9.02 5.92 -3.11 -0.444 0.53031E+04 39 carnegieite-high 10.09 5.92 -4.18 -0.597 0.71301E+04 40 carpholite-Mg 8.58 4.45 -4.13 -0.275 0.70527E+04 41 carpholite-Fe 6.71 1.88 -4.83 -0.322 0.82445E+04 42 celadonite 5.34 3.66 -1.68 -0.099 0.28716E+04 43 celadonite-Fe 3.88 1.09 -2.78 -0.164 0.47539E+04 44 chrysotile 23.89 21.59 -2.30 -0.192 0.39319E+04 49 chlorite-Al-free 47.17 43.18 -3.99 -0.166 0.68189E+04 51 chloritoid-Fe 9.17 5.03 -4.14 -0.276 0.70669E+04 52 chloritoid-Mn 11.40 7.51 -3.89 -0.259 0.66373E+04 54 coesite -2.38 -3.15 -0.77 -0.258 0.13226E+04 61 cristobalite -2.56 -3.15 -0.59 -0.197 0.10080E+04 63 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71234E+04 65 diaspore 2.87 0.73 -2.15 -0.358 0.36638E+04 66 diamond -3.10 -7.71 -4.61 -1.317 0.78728E+04 67 diopside 16.18 16.07 -0.11 -0.011 0.18611E+03 68 hedenbergite 14.21 13.50 -0.70 -0.070 0.12010E+04 71 enstatite 17.26 12.29 -4.97 -0.497 0.84900E+04 73 clinoenstatite 17.17 12.29 -4.87 -0.487 0.83216E+04 75 epidote 24.67 22.69 -1.98 -0.096 0.33852E+04 76 clinozoisite 22.81 18.89 -3.92 -0.178 0.66945E+04 77 epidote-Fe 29.84 26.49 -3.35 -0.174 0.57225E+04 78 fayalite 14.05 10.31 -3.74 -0.534 0.63814E+04 79 ferrosilite 11.15 7.16 -3.99 -0.399 0.68158E+04 83 gibbsite 4.08 0.73 -3.35 -0.479 0.57223E+04 84 glaucophane 22.97 20.82 -2.15 -0.058 0.36760E+04 85 glaucophane-Fe 17.28 13.12 -4.16 -0.112 0.70968E+04 86 graphite -3.55 -7.71 -4.17 -1.191 0.71150E+04 87 greenalite 16.14 13.89 -2.25 -0.188 0.38457E+04 90 hematite 12.57 9.06 -3.51 -0.425 0.59867E+04 91 heulandite -5.83 -7.52 -1.69 -0.077 0.28938E+04 95 jadeite 4.22 2.77 -1.45 -0.145 0.24732E+04 97 kalsilite 7.58 3.81 -3.77 -0.538 0.64356E+04 98 kaolinite -1.33 -4.85 -3.51 -0.319 0.59977E+04 101 laumontite 2.88 1.93 -0.95 -0.064 0.16280E+04 102 lawsonite 9.62 8.23 -1.38 -0.092 0.23645E+04 103 leucite 4.12 0.66 -3.45 -0.345 0.58988E+04 105 lizardite 23.24 21.59 -1.65 -0.138 0.28245E+04 107 magnetite 20.09 15.79 -4.30 -0.351 0.73384E+04 108 minnesotaite 10.39 7.59 -2.80 -0.165 0.47847E+04 112 manganosite 14.06 9.21 -4.85 -1.212 0.82804E+04 120 muscovite 2.58 -1.03 -3.61 -0.213 0.61691E+04 121 paragonite 4.24 1.07 -3.17 -0.186 0.54082E+04 122 nepheline 8.34 5.92 -2.42 -0.346 0.41355E+04 128 periclase-Fe 11.63 6.73 -4.90 -1.224 0.83616E+04 134 phlogopite-Na 29.65 27.51 -2.14 -0.119 0.36534E+04 136 prehnite 19.37 18.16 -1.21 -0.071 0.20738E+04 137 prehnite-Fe 22.50 21.96 -0.54 -0.032 0.91946E+03 138 pumpellyite-Fe 46.27 43.77 -2.50 -0.055 0.42640E+04 139 pumpellyite-Mg 48.99 46.34 -2.66 -0.059 0.45337E+04 143 pyrrhotite -4.26 -8.06 -3.80 -1.266 0.64865E+04 144 pyrrhotiteFe0.875 -6.02 -9.45 -3.43 -1.261 0.58548E+04 145 pyroxmangite 7.40 6.06 -1.34 -0.268 0.22893E+04 146 pyrophyllite -6.18 -11.15 -4.97 -0.311 0.84877E+04 147 quartz -2.99 -3.15 -0.16 -0.054 0.27531E+03 152 rhodonite 7.45 6.06 -1.39 -0.278 0.23695E+04 153 sanidine -1.28 -2.49 -1.21 -0.093 0.20677E+04 165 stilpnomelane-Mg 27.44 25.85 -1.59 -0.047 0.27098E+04 171 talc 16.49 15.29 -1.20 -0.071 0.20537E+04 174 tephroite 18.09 15.27 -2.82 -0.403 0.48138E+04 178 tridymite -2.63 -3.15 -0.52 -0.175 0.89528E+03 179 tremolite 47.87 47.43 -0.44 -0.012 0.74484E+03 180 ferroactinolite 38.45 34.60 -3.86 -0.104 0.65852E+04 181 troilite-low -4.41 -8.06 -3.65 -1.216 0.62293E+04 187 wairakite 3.95 1.93 -2.02 -0.119 0.34499E+04 188 walstromite 11.51 9.93 -1.58 -0.317 0.27033E+04 189 wollastonite 10.46 9.93 -0.54 -0.107 0.91370E+03 190 pseudo-wollastonite 11.00 9.93 -1.07 -0.215 0.18335E+04 191 zoisite 22.85 18.89 -3.96 -0.180 0.67686E+04 192 akaganeite 7.75 4.53 -3.22 -0.697 0.55059E+04 199 chalcedony -2.80 -3.15 -0.35 -0.116 0.59460E+03 201 montmorillonite-Ca -2.29 -6.16 -3.87 -0.239 0.66089E+04 202 montmorillonite-K -2.24 -6.26 -4.02 -0.246 0.68706E+04 203 montmorillonite-Mg -2.48 -6.78 -4.31 -0.266 0.73508E+04 204 montmorillonite-Na -2.04 -5.57 -3.53 -0.216 0.60255E+04 205 nontronite-Ca 3.21 -0.11 -3.32 -0.215 0.56681E+04 206 nontronite-H 2.53 -2.26 -4.80 -0.321 0.81880E+04 207 nontronite-K 3.34 -0.20 -3.55 -0.228 0.60530E+04 208 nontronite-Mg 3.07 -0.73 -3.80 -0.247 0.64941E+04 209 nontronite-Na 3.52 0.49 -3.03 -0.194 0.51739E+04 224 tobermorite 9.82 7.74 -2.08 -0.568 0.35530E+04 230 alabandite -0.98 -5.58 -4.60 -1.534 0.78582E+04 233 boehmite 4.41 0.73 -3.68 -0.613 0.62807E+04 235 ferrous-oxide 9.81 6.73 -3.08 -0.771 0.52625E+04 240 silica-amorphous -2.09 -3.15 -1.06 -0.353 0.18088E+04 242 an20ab80 2.02 1.34 -0.68 -0.052 0.11587E+04 243 an25ab75 2.65 1.77 -0.88 -0.067 0.14954E+04 244 an30ab70 3.28 2.20 -1.08 -0.083 0.18416E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 4.0000000 g Current total amount of reactant added: 123.9990000 g New total amount of reactant added: 127.9990000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.7268E-13 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 11 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 127.9990000 Water: Moles liquid = 0.5471E+02 kg liquid = 0.9856E+00 Moles total = 0.5390E+02 kg total = 0.9711E+00 Activity = 1.0000 Stoichiometric ionic strength = .1125259E-01 Osmotic coef. = 0.9689 True ionic strength = .1988844E-01 Chg. balance for total moles = -.7268E-13 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.89374E-10 -10.0488 0.75127E-10 -10.1242 0.84059E+00 -0.0754 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13935E-03 -3.8559 0.11644E-03 -3.9339 0.83556E+00 -0.0780 4 SO4-- 0.12800E-11 -11.8928 0.66582E-12 -12.1766 0.52019E+00 -0.2838 5 HCO3- 0.45166E-06 -6.3452 0.37794E-06 -6.4226 0.83678E+00 -0.0774 6 HS- 0.25872E-04 -4.5872 0.21621E-04 -4.6651 0.83568E+00 -0.0780 7 Al+++ 0.98041E-29 -29.0086 0.22739E-29 -29.6432 0.23193E+00 -0.6346 8 H4SiO4 0.70550E-03 -3.1515 0.70550E-03 -3.1515 0.10000E+01 0.0000 9 Ca++ 0.13132E-06 -6.8817 0.67812E-07 -7.1687 0.51639E+00 -0.2870 10 Mg++ 0.21742E-10 -10.6627 0.11176E-10 -10.9517 0.51404E+00 -0.2890 11 Fe++ 0.58926E-13 -13.2297 0.30324E-13 -13.5182 0.51460E+00 -0.2885 12 K+ 0.15550E-03 -3.8083 0.13015E-03 -3.8856 0.83698E+00 -0.0773 13 Na+ 0.19732E-01 -1.7048 0.16484E-01 -1.7829 0.83541E+00 -0.0781 14 Mn++ 0.17770E-10 -10.7503 0.91519E-11 -11.0385 0.51503E+00 -0.2882 15 HPO4-- 0.48028E-07 -7.3185 0.24987E-07 -7.6023 0.52026E+00 -0.2838 16 HSiO3- 0.10494E-01 -1.9791 0.87685E-02 -2.0571 0.83556E+00 -0.0780 17 Ca(HSiO3)+ 0.16176E-07 -7.7911 0.13542E-07 -7.8683 0.83716E+00 -0.0772 18 Mg(HSiO3)+ 0.33178E-11 -11.4791 0.27775E-11 -11.5563 0.83716E+00 -0.0772 19 NaHSiO3,aq 0.23377E-02 -2.6312 0.23377E-02 -2.6312 0.10000E+01 0.0000 20 AlO+ 0.65470E-16 -16.1840 0.54808E-16 -16.2612 0.83716E+00 -0.0772 22 HAlO2,aq 0.14529E-09 -9.8378 0.14529E-09 -9.8378 0.10000E+01 0.0000 23 AlO2- 0.51324E-05 -5.2897 0.42808E-05 -5.3685 0.83406E+00 -0.0788 24 CH4,aq 0.11962E-04 -4.9222 0.11921E-04 -4.9237 0.99657E+00 -0.0015 25 C2H6,aq 0.24953E-14 -14.6029 0.24867E-14 -14.6044 0.99657E+00 -0.0015 29 CO,aq 0.14891E-16 -16.8271 0.14891E-16 -16.8271 0.10000E+01 0.0000 30 CO2,aq 0.60879E-10 -10.2155 0.60670E-10 -10.2170 0.99657E+00 -0.0015 31 CO3-2 0.84649E-06 -6.0724 0.43940E-06 -6.3571 0.51909E+00 -0.2848 32 CaCO3,aq 0.37362E-09 -9.4276 0.37362E-09 -9.4276 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.78146E-12 -12.1071 0.65420E-12 -12.1843 0.83716E+00 -0.0772 34 CaCl+ 0.15264E-10 -10.8163 0.12778E-10 -10.8935 0.83716E+00 -0.0772 35 CaCl2,aq 0.35349E-15 -15.4516 0.35349E-15 -15.4516 0.10000E+01 0.0000 36 CaOH+ 0.76844E-07 -7.1144 0.64330E-07 -7.1916 0.83716E+00 -0.0772 37 CaSO4,aq 0.14337E-16 -16.8435 0.14337E-16 -16.8435 0.10000E+01 0.0000 38 HCl,aq 0.16030E-14 -14.7951 0.16030E-14 -14.7951 0.10000E+01 0.0000 43 FeCl+ 0.66759E-17 -17.1755 0.55888E-17 -17.2527 0.83716E+00 -0.0772 46 FeO,aq 0.20881E-09 -9.6803 0.20881E-09 -9.6803 0.10000E+01 0.0000 47 FeOH+ 0.15694E-10 -10.8043 0.13139E-10 -10.8815 0.83716E+00 -0.0772 48 HFeO2- 0.34804E-07 -7.4584 0.29081E-07 -7.5364 0.83556E+00 -0.0780 49 FeO+ 0.11976E-16 -16.9217 0.10026E-16 -16.9989 0.83716E+00 -0.0772 51 FeO2- 0.43500E-09 -9.3615 0.36347E-09 -9.4395 0.83556E+00 -0.0780 52 HFeO2,aq 0.34730E-11 -11.4593 0.34730E-11 -11.4593 0.10000E+01 0.0000 53 H2,aq 0.98041E-05 -5.0086 0.97704E-05 -5.0101 0.99657E+00 -0.0015 54 KCl,aq 0.27466E-09 -9.5612 0.27466E-09 -9.5612 0.10000E+01 0.0000 56 KOH,aq 0.73981E-06 -6.1309 0.73981E-06 -6.1309 0.10000E+01 0.0000 57 KSO4- 0.16093E-14 -14.7934 0.13447E-14 -14.8714 0.83556E+00 -0.0780 58 MgCO3,aq 0.15435E-13 -13.8115 0.15435E-13 -13.8115 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.13160E-15 -15.8807 0.11017E-15 -15.9579 0.83716E+00 -0.0772 60 MgCl+ 0.22801E-14 -14.6420 0.19088E-14 -14.7192 0.83716E+00 -0.0772 61 MgOH+ 0.70081E-10 -10.1544 0.58668E-10 -10.2316 0.83716E+00 -0.0772 63 MnO,aq 0.16792E-08 -8.7749 0.16792E-08 -8.7749 0.10000E+01 0.0000 64 MnOH+ 0.44002E-09 -9.3565 0.36836E-09 -9.4337 0.83716E+00 -0.0772 65 MnO2-2 0.19021E-10 -10.7208 0.98737E-11 -11.0055 0.51909E+00 -0.2848 66 HMnO2- 0.19449E-09 -9.7111 0.16251E-09 -9.7891 0.83556E+00 -0.0780 69 MnCl+ 0.78386E-14 -14.1058 0.65621E-14 -14.1830 0.83716E+00 -0.0772 71 NaCl,aq 0.63609E-06 -6.1965 0.63609E-06 -6.1965 0.10000E+01 0.0000 72 NaOH,aq 0.94271E-04 -4.0256 0.94271E-04 -4.0256 0.10000E+01 0.0000 74 OH- 0.92206E-02 -2.0352 0.76906E-02 -2.1140 0.83406E+00 -0.0788 79 HPO3-2 0.14657E-14 -14.8340 0.76081E-15 -15.1187 0.51909E+00 -0.2848 81 H2PO3- 0.13718E-18 -18.8627 0.11462E-18 -18.9407 0.83556E+00 -0.0780 82 H3PO4,aq 0.98637E-18 -18.0060 0.98637E-18 -18.0060 0.10000E+01 0.0000 83 H2PO4- 0.41406E-10 -10.3829 0.34630E-10 -10.4605 0.83635E+00 -0.0776 84 PO4-3 0.11143E-08 -8.9530 0.27136E-09 -9.5664 0.24353E+00 -0.6134 88 HP2O7-3 0.10765E-17 -17.9680 0.24992E-18 -18.6022 0.23216E+00 -0.6342 89 P2O7-4 0.10237E-16 -16.9898 0.79472E-18 -18.0998 0.77631E-01 -1.1100 90 H2S,aq 0.50375E-08 -8.2978 0.50202E-08 -8.2993 0.99657E+00 -0.0015 91 S2-2 0.20423E-14 -14.6899 0.10602E-14 -14.9746 0.51909E+00 -0.2848 97 SO3-2 0.16054E-17 -17.7944 0.84537E-18 -18.0730 0.52656E+00 -0.2786 99 HSO4- 0.57528E-19 -19.2401 0.48206E-19 -19.3169 0.83797E+00 -0.0768 Charge balance for all species = -.7554E-13 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.8937446E-10 -.2217155E-01 -.2230888E+02 0.0000 2 H2O 0.1000000E+01 0.5550477E+02 0.9982028E+06 0.0000 3 Cl- 0.1393549E-03 0.1399912E-03 0.4954511E+01 6.1903 4 SO4-- 0.1279954E-11 -.1441346E-04 -.1382181E+01 8.0718 5 HCO3- 0.4516556E-06 0.1326107E-04 0.8077517E+00 3.7016 6 HS- 0.2587228E-04 0.4029078E-04 0.1330188E+01 5.4591 7 Al+++ 0.9804101E-29 0.5132584E-05 0.1382449E+00 0.7294 8 H4SiO4 0.7055022E-03 0.1353740E-01 0.1298899E+04 -3.1515 9 Ca++ 0.1313199E-06 0.2247290E-06 0.8991087E-02 13.0797 10 Mg++ 0.2174215E-10 0.9515860E-10 0.2309488E-05 9.2967 11 Fe++ 0.5892635E-13 0.3546718E-07 0.1977304E-02 6.7302 12 K+ 0.1554968E-03 0.1562369E-03 0.6098590E+01 6.2386 13 Na+ 0.1973156E-01 0.2216421E-01 0.5086680E+03 8.3413 14 Mn++ 0.1776972E-10 0.2350518E-08 0.1289091E-03 9.2099 15 HPO4-- 0.4802826E-07 0.4918394E-07 0.4712448E-02 12.6461 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.2119460E+01 -.2185209E-01 -.2097608E+01 0.0000000E+00 2 H2O 0.5390373E+02 0.5470503E+02 -.8013000E+00 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.3572793E-02 -.1420578E-04 0.3586999E-02 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.3547289E-02 0.3971025E-04 -.3586999E-02 0.0000000E+00 7 Al+++ 0.4173717E+00 0.5058631E-05 0.4173666E+00 0.0000000E+00 8 H4SiO4 0.1332826E+01 0.1334235E-01 0.1319483E+01 0.0000000E+00 9 Ca++ 0.1472316E+00 0.2214910E-06 0.1472314E+00 0.0000000E+00 10 Mg++ 0.1015865E+00 0.9378752E-10 0.1015865E+00 0.0000000E+00 11 Fe++ 0.9126439E-01 0.3495615E-07 0.9126435E-01 0.0000000E+00 12 K+ 0.2717601E-01 0.1539857E-03 0.2702202E-01 0.0000000E+00 13 Na+ 0.1608300E+00 0.2184486E-01 0.1389851E+00 0.0000000E+00 14 Mn++ 0.2219323E-02 0.2316651E-08 0.2219321E-02 0.0000000E+00 15 HPO4-- 0.7574439E-03 0.4847528E-07 0.7573954E-03 0.0000000E+00 Chg. balance for solid moles: -.3294E-15 Mass of aqueous solution: 0.987302E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 127.9990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 0.1389 -0.857 36.42 1.561 26.07 13.98 andradite 0.1435E-01 -1.843 7.291 0.863 5.220 1.894 grossular 0.3156E-02 -2.501 1.422 0.153 1.018 0.3955 apatite-OH 0.2525E-03 -3.598 0.1268 -0.897 0.9080E-01 0.4030E-01 clinochlore 0.1967E-01 -1.706 10.93 1.039 7.829 4.159 daphnite 0.5600E-02 -2.252 3.996 0.602 2.861 1.211 chlorite-Mn 0.4439E-03 -3.353 0.3147 -0.502 0.2253 0.1003 microcline 0.2368E-01 -1.626 6.590 0.819 4.718 2.574 stilbite 0.9168E-01 -1.038 64.61 1.810 46.26 30.13 stilpnomelane-Fe 0.6691E-02 -2.174 7.213 0.858 5.164 2.492 tr.625ac.25prg.125 0.8898E-03 -3.051 0.7605 -0.119 0.5445 0.2448 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8197E+00 0.8197E+00 1.0000 -0.086 grossular 0.1803E+00 0.1803E+00 1.0000 -0.744 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.7650E+00 0.7650E+00 1.0000 -0.116 daphnite 0.2178E+00 0.2178E+00 1.0000 -0.662 chlorite-Mn 0.1726E-01 0.1726E-01 1.0000 -1.763 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 tr.625ac.25prg.125 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 139.671121 g Volume = 57.224173 cm3 Porosity: -9.6257% V(tot) - V(min): -.50246E+01 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 127.9990000 g log = 2.1072 Original solution: 1000.0103000 g Original solution / Rock added: 7.81 (Water/Rock Ratio), log = 0.8928 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0509 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9713E+00 0.9855 0.1006E+01 0.1021E+01 CO2,gas 0.6134E-08 1.0069 0.6491E-08 0.6446E-08 CH4,gas 0.1649E-01 1.0125 0.1755E-01 0.1733E-01 H2,gas 0.1220E-01 1.0006 0.1283E-01 0.1282E-01 H2S,gas 0.1319E-06 0.9959 0.1380E-06 0.1386E-06 S2,gas 0.4134E-29 1.0000 0.4345E-29 0.4345E-29 CO,gas 0.2112E-13 1.0000 0.2219E-13 0.2219E-13 SO3,gas 0.1352E-47 1.0000 0.1421E-47 0.1421E-47 SO2,gas 0.6748E-27 1.0000 0.7091E-27 0.7091E-27 HCl,gas 0.2692E-17 1.0000 0.2829E-17 0.2829E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 16 albite -0.38 -0.38 0.00 0.000 -0.94784E-12 22 andradite 39.01 39.01 0.00 0.000 0.00000E+00 23 grossular 32.73 32.73 0.00 0.000 0.12132E-10 32 apatite-OH -18.15 -18.15 0.00 0.000 0.00000E+00 46 clinochlore 39.07 39.07 0.00 0.000 0.12132E-10 47 daphnite 28.97 28.97 0.00 0.000 0.36397E-10 48 chlorite-Mn 46.87 46.87 0.00 0.000 -0.36397E-10 116 microcline -2.49 -2.49 0.00 0.000 0.15165E-11 163 stilbite -7.52 -7.52 0.00 0.000 -0.90992E-11 164 stilpnomelane-Fe 13.02 13.02 0.00 0.000 0.21232E-10 245 tr.625ac.25prg.125 45.16 45.16 0.00 0.000 -0.60662E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -16.55 -9.89 -3.296 0.16881E+05 -8.188 3 CH4,gas 4.54 1.09 -3.45 -0.864 0.58989E+04 -1.756 4 H2,gas 8.00 4.41 -3.59 -2.052 0.61312E+04 -1.892 5 H2S,gas -6.23 -14.79 -8.56 -4.280 0.14614E+05 -6.860 6 S2,gas -7.34 -38.40 -31.06 -4.779 0.53036E+05 -29.362 7 CO,gas 3.21 -12.14 -15.35 -4.724 0.26214E+05 -13.654 8 SO3,gas 17.12 -32.43 -49.55 -12.387 0.84599E+05 -47.847 9 SO2,gas 0.83 -28.02 -28.85 -7.693 0.49258E+05 -27.149 10 HCl,gas 5.19 -14.06 -19.25 -9.624 0.32864E+05 -17.548 11 acmite 7.71 6.56 -1.15 -0.119 0.19563E+04 15 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 19 spessartine 24.46 19.63 -4.82 -0.241 0.82357E+04 20 analcite 3.32 2.77 -0.55 -0.062 0.94633E+03 26 annite 20.12 17.70 -2.42 -0.134 0.41310E+04 27 phlogopite 27.06 25.40 -1.66 -0.092 0.28361E+04 29 anorthite 12.71 8.24 -4.47 -0.344 0.76407E+04 35 aragonite 0.97 -3.47 -4.43 -1.478 0.75702E+04 36 brucite 12.57 9.30 -3.27 -0.654 0.55866E+04 37 calcite 0.81 -3.47 -4.28 -1.426 0.73060E+04 38 carnegieite-low 9.02 5.92 -3.10 -0.443 0.53003E+04 39 carnegieite-high 10.09 5.92 -4.17 -0.596 0.71273E+04 40 carpholite-Mg 8.58 4.45 -4.13 -0.275 0.70513E+04 41 carpholite-Fe 6.71 1.89 -4.83 -0.322 0.82415E+04 42 celadonite 5.34 3.66 -1.68 -0.099 0.28735E+04 43 celadonite-Fe 3.88 1.09 -2.78 -0.164 0.47542E+04 44 chrysotile 23.89 21.59 -2.31 -0.192 0.39362E+04 49 chlorite-Al-free 47.17 43.17 -4.00 -0.167 0.68276E+04 51 chloritoid-Fe 9.17 5.04 -4.14 -0.276 0.70624E+04 52 chloritoid-Mn 11.40 7.52 -3.88 -0.259 0.66317E+04 54 coesite -2.38 -3.15 -0.78 -0.258 0.13240E+04 61 cristobalite -2.56 -3.15 -0.59 -0.197 0.10094E+04 63 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71234E+04 65 diaspore 2.87 0.73 -2.14 -0.357 0.36614E+04 66 diamond -3.10 -7.73 -4.63 -1.322 0.78997E+04 67 diopside 16.18 16.07 -0.11 -0.011 0.18431E+03 68 hedenbergite 14.21 13.51 -0.70 -0.070 0.11976E+04 71 enstatite 17.26 12.29 -4.97 -0.497 0.84938E+04 73 clinoenstatite 17.17 12.29 -4.88 -0.488 0.83254E+04 75 epidote 24.67 22.69 -1.98 -0.096 0.33817E+04 76 clinozoisite 22.81 18.89 -3.91 -0.178 0.66813E+04 77 epidote-Fe 29.84 26.49 -3.36 -0.174 0.57287E+04 78 fayalite 14.05 10.31 -3.74 -0.534 0.63806E+04 79 ferrosilite 11.15 7.16 -3.99 -0.399 0.68164E+04 83 gibbsite 4.08 0.73 -3.35 -0.479 0.57199E+04 84 glaucophane 22.97 20.82 -2.16 -0.058 0.36803E+04 85 glaucophane-Fe 17.28 13.12 -4.16 -0.112 0.70963E+04 86 graphite -3.55 -7.73 -4.18 -1.195 0.71419E+04 87 greenalite 16.14 13.89 -2.25 -0.188 0.38452E+04 90 hematite 12.57 9.05 -3.51 -0.426 0.60013E+04 91 heulandite -5.83 -7.52 -1.69 -0.077 0.28938E+04 95 jadeite 4.22 2.77 -1.45 -0.145 0.24718E+04 97 kalsilite 7.58 3.82 -3.77 -0.538 0.64327E+04 98 kaolinite -1.33 -4.84 -3.51 -0.319 0.59958E+04 101 laumontite 2.88 1.93 -0.95 -0.063 0.16237E+04 102 lawsonite 9.62 8.24 -1.38 -0.092 0.23574E+04 103 leucite 4.12 0.67 -3.45 -0.345 0.58974E+04 105 lizardite 23.24 21.59 -1.66 -0.138 0.28288E+04 107 magnetite 20.09 15.78 -4.31 -0.351 0.73520E+04 108 minnesotaite 10.39 7.58 -2.80 -0.165 0.47870E+04 112 manganosite 14.06 9.21 -4.85 -1.212 0.82782E+04 120 muscovite 2.58 -1.03 -3.61 -0.212 0.61643E+04 121 paragonite 4.24 1.07 -3.16 -0.186 0.54034E+04 122 nepheline 8.34 5.92 -2.42 -0.346 0.41326E+04 128 periclase-Fe 11.63 6.73 -4.90 -1.224 0.83605E+04 134 phlogopite-Na 29.65 27.51 -2.14 -0.119 0.36549E+04 136 prehnite 19.37 18.16 -1.21 -0.071 0.20630E+04 137 prehnite-Fe 22.50 21.96 -0.54 -0.032 0.91837E+03 138 pumpellyite-Fe 46.27 43.79 -2.48 -0.055 0.42389E+04 139 pumpellyite-Mg 48.99 46.35 -2.64 -0.059 0.45102E+04 143 pyrrhotite -4.26 -8.06 -3.80 -1.266 0.64864E+04 144 pyrrhotiteFe0.875 -6.02 -9.45 -3.43 -1.262 0.58569E+04 145 pyroxmangite 7.40 6.06 -1.34 -0.268 0.22885E+04 146 pyrophyllite -6.18 -11.15 -4.97 -0.311 0.84886E+04 147 quartz -2.99 -3.15 -0.16 -0.054 0.27672E+03 152 rhodonite 7.45 6.06 -1.39 -0.277 0.23687E+04 153 sanidine -1.28 -2.49 -1.21 -0.093 0.20677E+04 165 stilpnomelane-Mg 27.44 25.85 -1.59 -0.048 0.27180E+04 171 talc 16.49 15.28 -1.21 -0.071 0.20609E+04 174 tephroite 18.09 15.27 -2.82 -0.402 0.48108E+04 178 tridymite -2.63 -3.15 -0.53 -0.175 0.89670E+03 179 tremolite 47.87 47.43 -0.44 -0.012 0.74843E+03 180 ferroactinolite 38.45 34.60 -3.85 -0.104 0.65807E+04 181 troilite-low -4.41 -8.06 -3.65 -1.216 0.62292E+04 187 wairakite 3.95 1.93 -2.02 -0.119 0.34457E+04 188 walstromite 11.51 9.93 -1.58 -0.316 0.26995E+04 189 wollastonite 10.46 9.93 -0.53 -0.107 0.90997E+03 190 pseudo-wollastonite 11.00 9.93 -1.07 -0.214 0.18298E+04 191 zoisite 22.85 18.89 -3.96 -0.180 0.67554E+04 192 akaganeite 7.75 4.53 -3.23 -0.698 0.55132E+04 199 chalcedony -2.80 -3.15 -0.35 -0.116 0.59602E+03 201 montmorillonite-Ca -2.29 -6.16 -3.87 -0.239 0.66099E+04 202 montmorillonite-K -2.24 -6.26 -4.02 -0.246 0.68718E+04 203 montmorillonite-Mg -2.48 -6.79 -4.31 -0.266 0.73527E+04 204 montmorillonite-Na -2.04 -5.57 -3.53 -0.216 0.60267E+04 205 nontronite-Ca 3.21 -0.12 -3.33 -0.216 0.56863E+04 206 nontronite-H 2.53 -2.27 -4.81 -0.322 0.82071E+04 207 nontronite-K 3.34 -0.22 -3.56 -0.228 0.60715E+04 208 nontronite-Mg 3.07 -0.74 -3.81 -0.247 0.65132E+04 209 nontronite-Na 3.52 0.48 -3.04 -0.195 0.51924E+04 224 tobermorite 9.82 7.74 -2.08 -0.567 0.35501E+04 230 alabandite -0.98 -5.58 -4.60 -1.534 0.78570E+04 233 boehmite 4.41 0.73 -3.68 -0.613 0.62783E+04 235 ferrous-oxide 9.81 6.73 -3.08 -0.770 0.52614E+04 240 silica-amorphous -2.09 -3.15 -1.06 -0.353 0.18102E+04 242 an20ab80 2.02 1.34 -0.68 -0.052 0.11573E+04 243 an25ab75 2.65 1.77 -0.87 -0.067 0.14936E+04 244 an30ab70 3.28 2.20 -1.08 -0.083 0.18395E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 4.0000000 g Current total amount of reactant added: 127.9990000 g New total amount of reactant added: 131.9990000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.7248E-13 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 11 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 131.9990000 Water: Moles liquid = 0.5469E+02 kg liquid = 0.9852E+00 Moles total = 0.5385E+02 kg total = 0.9702E+00 Activity = 1.0000 Stoichiometric ionic strength = .1126067E-01 Osmotic coef. = 0.9690 True ionic strength = .1990316E-01 Chg. balance for total moles = -.7248E-13 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.89231E-10 -10.0495 0.75004E-10 -10.1249 0.84055E+00 -0.0754 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13941E-03 -3.8557 0.11648E-03 -3.9337 0.83552E+00 -0.0780 4 SO4-- 0.11779E-11 -11.9289 0.61260E-12 -12.2128 0.52009E+00 -0.2839 5 HCO3- 0.41884E-06 -6.3780 0.35046E-06 -6.4554 0.83674E+00 -0.0774 6 HS- 0.25883E-04 -4.5870 0.21629E-04 -4.6650 0.83564E+00 -0.0780 7 Al+++ 0.97893E-29 -29.0092 0.22695E-29 -29.6441 0.23183E+00 -0.6348 8 H4SiO4 0.70425E-03 -3.1523 0.70425E-03 -3.1523 0.10000E+01 0.0000 9 Ca++ 0.13176E-06 -6.8802 0.68028E-07 -7.1673 0.51629E+00 -0.2871 10 Mg++ 0.21661E-10 -10.6643 0.11132E-10 -10.9534 0.51394E+00 -0.2891 11 Fe++ 0.58827E-13 -13.2304 0.30266E-13 -13.5190 0.51450E+00 -0.2886 12 K+ 0.15561E-03 -3.8080 0.13024E-03 -3.8853 0.83694E+00 -0.0773 13 Na+ 0.19746E-01 -1.7045 0.16495E-01 -1.7826 0.83537E+00 -0.0781 14 Mn++ 0.17765E-10 -10.7504 0.91477E-11 -11.0387 0.51492E+00 -0.2883 15 HPO4-- 0.47680E-07 -7.3217 0.24801E-07 -7.6055 0.52016E+00 -0.2839 16 HSiO3- 0.10493E-01 -1.9791 0.87674E-02 -2.0571 0.83552E+00 -0.0780 17 Ca(HSiO3)+ 0.16226E-07 -7.7898 0.13583E-07 -7.8670 0.83711E+00 -0.0772 18 Mg(HSiO3)+ 0.33045E-11 -11.4809 0.27663E-11 -11.5581 0.83711E+00 -0.0772 19 NaHSiO3,aq 0.23391E-02 -2.6310 0.23391E-02 -2.6310 0.10000E+01 0.0000 20 AlO+ 0.65561E-16 -16.1834 0.54882E-16 -16.2606 0.83711E+00 -0.0772 22 HAlO2,aq 0.14572E-09 -9.8365 0.14572E-09 -9.8365 0.10000E+01 0.0000 23 AlO2- 0.51566E-05 -5.2876 0.43007E-05 -5.3665 0.83402E+00 -0.0788 24 CH4,aq 0.12061E-04 -4.9186 0.12019E-04 -4.9201 0.99657E+00 -0.0015 25 C2H6,aq 0.24829E-14 -14.6050 0.24744E-14 -14.6065 0.99657E+00 -0.0015 29 CO,aq 0.14083E-16 -16.8513 0.14083E-16 -16.8513 0.10000E+01 0.0000 30 CO2,aq 0.56360E-10 -10.2490 0.56167E-10 -10.2505 0.99657E+00 -0.0015 31 CO3-2 0.78640E-06 -6.1044 0.40813E-06 -6.3892 0.51899E+00 -0.2848 32 CaCO3,aq 0.34813E-09 -9.4583 0.34813E-09 -9.4583 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.72698E-12 -12.1385 0.60856E-12 -12.2157 0.83711E+00 -0.0772 34 CaCl+ 0.15319E-10 -10.8148 0.12823E-10 -10.8920 0.83711E+00 -0.0772 35 CaCl2,aq 0.35487E-15 -15.4499 0.35487E-15 -15.4499 0.10000E+01 0.0000 36 CaOH+ 0.77218E-07 -7.1123 0.64641E-07 -7.1895 0.83711E+00 -0.0772 37 CaSO4,aq 0.13233E-16 -16.8783 0.13233E-16 -16.8783 0.10000E+01 0.0000 38 HCl,aq 0.16009E-14 -14.7956 0.16009E-14 -14.7956 0.10000E+01 0.0000 43 FeCl+ 0.66660E-17 -17.1761 0.55802E-17 -17.2533 0.83711E+00 -0.0772 46 FeO,aq 0.20910E-09 -9.6796 0.20910E-09 -9.6796 0.10000E+01 0.0000 47 FeOH+ 0.15691E-10 -10.8043 0.13135E-10 -10.8816 0.83711E+00 -0.0772 48 HFeO2- 0.34913E-07 -7.4570 0.29170E-07 -7.5351 0.83552E+00 -0.0780 49 FeO+ 0.11847E-16 -16.9264 0.99170E-17 -17.0036 0.83711E+00 -0.0772 51 FeO2- 0.43173E-09 -9.3648 0.36072E-09 -9.4428 0.83552E+00 -0.0780 52 HFeO2,aq 0.34410E-11 -11.4633 0.34410E-11 -11.4633 0.10000E+01 0.0000 53 H2,aq 0.10015E-04 -4.9993 0.99810E-05 -5.0008 0.99657E+00 -0.0015 54 KCl,aq 0.27495E-09 -9.5608 0.27495E-09 -9.5608 0.10000E+01 0.0000 56 KOH,aq 0.74155E-06 -6.1299 0.74155E-06 -6.1299 0.10000E+01 0.0000 57 KSO4- 0.14818E-14 -14.8292 0.12380E-14 -14.9073 0.83552E+00 -0.0780 58 MgCO3,aq 0.14280E-13 -13.8453 0.14280E-13 -13.8453 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.12156E-15 -15.9152 0.10176E-15 -15.9924 0.83711E+00 -0.0772 60 MgCl+ 0.22720E-14 -14.6436 0.19020E-14 -14.7208 0.83711E+00 -0.0772 61 MgOH+ 0.69924E-10 -10.1554 0.58534E-10 -10.2326 0.83711E+00 -0.0772 63 MnO,aq 0.16840E-08 -8.7737 0.16840E-08 -8.7737 0.10000E+01 0.0000 64 MnOH+ 0.44056E-09 -9.3560 0.36880E-09 -9.4332 0.83711E+00 -0.0772 65 MnO2-2 0.19142E-10 -10.7180 0.99345E-11 -11.0029 0.51899E+00 -0.2848 66 HMnO2- 0.19538E-09 -9.7091 0.16324E-09 -9.7872 0.83552E+00 -0.0780 69 MnCl+ 0.78382E-14 -14.1058 0.65615E-14 -14.1830 0.83711E+00 -0.0772 71 NaCl,aq 0.63676E-06 -6.1960 0.63676E-06 -6.1960 0.10000E+01 0.0000 72 NaOH,aq 0.94492E-04 -4.0246 0.94492E-04 -4.0246 0.10000E+01 0.0000 74 OH- 0.92363E-02 -2.0345 0.77033E-02 -2.1133 0.83402E+00 -0.0788 79 HPO3-2 0.14864E-14 -14.8279 0.77142E-15 -15.1127 0.51899E+00 -0.2848 81 H2PO3- 0.13887E-18 -18.8574 0.11603E-18 -18.9354 0.83552E+00 -0.0780 82 H3PO4,aq 0.97580E-18 -18.0106 0.97580E-18 -18.0106 0.10000E+01 0.0000 83 H2PO4- 0.41032E-10 -10.3869 0.34315E-10 -10.4645 0.83631E+00 -0.0776 84 PO4-3 0.11083E-08 -8.9554 0.26979E-09 -9.5690 0.24343E+00 -0.6136 88 HP2O7-3 0.10592E-17 -17.9750 0.24580E-18 -18.6094 0.23206E+00 -0.6344 89 P2O7-4 0.10093E-16 -16.9960 0.78292E-18 -18.1063 0.77571E-01 -1.1103 90 H2S,aq 0.50310E-08 -8.2983 0.50137E-08 -8.2998 0.99657E+00 -0.0015 91 S2-2 0.20011E-14 -14.6987 0.10385E-14 -14.9836 0.51899E+00 -0.2848 97 SO3-2 0.15093E-17 -17.8212 0.79456E-18 -18.0999 0.52646E+00 -0.2786 99 HSO4- 0.52845E-19 -19.2770 0.44280E-19 -19.3538 0.83793E+00 -0.0768 Charge balance for all species = -.7540E-13 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.8923122E-10 -.2218802E-01 -.2232543E+02 0.0000 2 H2O 0.1000000E+01 0.5550478E+02 0.9982025E+06 0.0000 3 Cl- 0.1394110E-03 0.1400481E-03 0.4956520E+01 6.1912 4 SO4-- 0.1177877E-11 -.1456462E-04 -.1396676E+01 8.0370 5 HCO3- 0.4188413E-06 0.1326646E-04 0.8080792E+00 3.6696 6 HS- 0.2588280E-04 0.4045245E-04 0.1335525E+01 5.4600 7 Al+++ 0.9789321E-29 0.5156767E-05 0.1388962E+00 0.7307 8 H4SiO4 0.7042468E-03 0.1353661E-01 0.1298822E+04 -3.1523 9 Ca++ 0.1317624E-06 0.2255708E-06 0.9024760E-02 13.0825 10 Mg++ 0.2166099E-10 0.9490608E-10 0.2303358E-05 9.2964 11 Fe++ 0.5882710E-13 0.3557274E-07 0.1983188E-02 6.7308 12 K+ 0.1556121E-03 0.1563539E-03 0.6103157E+01 6.2397 13 Na+ 0.1974622E-01 0.2218040E-01 0.5090393E+03 8.3423 14 Mn++ 0.1776516E-10 0.2356852E-08 0.1292564E-03 9.2111 15 HPO4-- 0.4767961E-07 0.4882890E-07 0.4678428E-02 12.6443 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.2185694E+01 -.2185945E-01 -.2163835E+01 0.0000000E+00 2 H2O 0.5385359E+02 0.5468284E+02 -.8292525E+00 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.3683647E-02 -.1434894E-04 0.3697996E-02 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.3658142E-02 0.3985341E-04 -.3697996E-02 0.0000000E+00 7 Al+++ 0.4304146E+00 0.5080403E-05 0.4304096E+00 0.0000000E+00 8 H4SiO4 0.1374477E+01 0.1333615E-01 0.1361141E+01 0.0000000E+00 9 Ca++ 0.1518322E+00 0.2222304E-06 0.1518319E+00 0.0000000E+00 10 Mg++ 0.1047611E+00 0.9350067E-10 0.1047611E+00 0.0000000E+00 11 Fe++ 0.9411642E-01 0.3504597E-07 0.9411639E-01 0.0000000E+00 12 K+ 0.2802527E-01 0.1540386E-03 0.2787123E-01 0.0000000E+00 13 Na+ 0.1658510E+00 0.2185194E-01 0.1439990E+00 0.0000000E+00 14 Mn++ 0.2288677E-02 0.2321951E-08 0.2288675E-02 0.0000000E+00 15 HPO4-- 0.7811142E-03 0.4810582E-07 0.7810661E-03 0.0000000E+00 Chg. balance for solid moles: 0.7251E-15 Mass of aqueous solution: 0.986902E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 131.9990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 0.1439 -0.842 37.73 1.577 26.19 14.48 andradite 0.1479E-01 -1.830 7.517 0.876 5.219 1.953 grossular 0.3294E-02 -2.482 1.484 0.171 1.030 0.4128 apatite-OH 0.2604E-03 -3.584 0.1308 -0.883 0.9080E-01 0.4156E-01 clinochlore 0.2022E-01 -1.694 11.24 1.051 7.801 4.274 daphnite 0.5767E-02 -2.239 4.115 0.614 2.857 1.247 chlorite-Mn 0.4577E-03 -3.339 0.3245 -0.489 0.2253 0.1034 microcline 0.2443E-01 -1.612 6.799 0.832 4.720 2.656 stilbite 0.9424E-01 -1.026 66.42 1.822 46.11 30.98 stilpnomelane-Fe 0.6886E-02 -2.162 7.423 0.871 5.153 2.564 tr.625ac.25prg.125 0.1015E-02 -2.994 0.8675 -0.062 0.6023 0.2792 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8179E+00 0.8179E+00 1.0000 -0.087 grossular 0.1821E+00 0.1821E+00 1.0000 -0.740 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.7646E+00 0.7646E+00 1.0000 -0.117 daphnite 0.2181E+00 0.2181E+00 1.0000 -0.661 chlorite-Mn 0.1731E-01 0.1731E-01 1.0000 -1.762 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 tr.625ac.25prg.125 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 144.038936 g Volume = 58.990689 cm3 Porosity: -9.6489% V(tot) - V(min): -.51911E+01 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 131.9990000 g log = 2.1206 Original solution: 1000.0103000 g Original solution / Rock added: 7.58 (Water/Rock Ratio), log = 0.8794 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0513 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9709E+00 0.9855 0.1006E+01 0.1021E+01 CO2,gas 0.5677E-08 1.0069 0.6009E-08 0.5968E-08 CH4,gas 0.1662E-01 1.0125 0.1769E-01 0.1747E-01 H2,gas 0.1246E-01 1.0006 0.1310E-01 0.1310E-01 H2S,gas 0.1316E-06 0.9959 0.1378E-06 0.1384E-06 S2,gas 0.3950E-29 1.0000 0.4152E-29 0.4152E-29 CO,gas 0.1996E-13 1.0000 0.2099E-13 0.2099E-13 SO3,gas 0.1239E-47 1.0000 0.1303E-47 0.1303E-47 SO2,gas 0.6319E-27 1.0000 0.6643E-27 0.6643E-27 HCl,gas 0.2687E-17 1.0000 0.2825E-17 0.2825E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 16 albite -0.38 -0.38 0.00 0.000 -0.94784E-12 22 andradite 39.01 39.01 0.00 0.000 0.24265E-10 23 grossular 32.73 32.73 0.00 0.000 0.00000E+00 32 apatite-OH -18.15 -18.15 0.00 0.000 0.60662E-11 46 clinochlore 39.07 39.07 0.00 0.000 -0.12132E-10 47 daphnite 28.97 28.97 0.00 0.000 0.24265E-10 48 chlorite-Mn 46.87 46.87 0.00 0.000 -0.24265E-10 116 microcline -2.49 -2.49 0.00 0.000 0.15165E-11 163 stilbite -7.52 -7.52 0.00 0.000 -0.90992E-11 164 stilpnomelane-Fe 13.02 13.02 0.00 0.000 0.21232E-10 245 tr.625ac.25prg.125 45.16 45.16 0.00 0.000 0.00000E+00 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -16.58 -9.92 -3.307 0.16938E+05 -8.221 3 CH4,gas 4.54 1.09 -3.45 -0.863 0.58928E+04 -1.752 4 H2,gas 8.00 4.42 -3.58 -2.047 0.61154E+04 -1.883 5 H2S,gas -6.23 -14.79 -8.56 -4.280 0.14615E+05 -6.861 6 S2,gas -7.34 -38.42 -31.08 -4.782 0.53069E+05 -29.382 7 CO,gas 3.21 -12.16 -15.38 -4.731 0.26256E+05 -13.678 8 SO3,gas 17.12 -32.46 -49.58 -12.396 0.84663E+05 -47.885 9 SO2,gas 0.83 -28.04 -28.88 -7.700 0.49306E+05 -27.178 10 HCl,gas 5.19 -14.06 -19.25 -9.624 0.32865E+05 -17.549 11 acmite 7.71 6.56 -1.15 -0.120 0.19641E+04 15 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 19 spessartine 24.46 19.64 -4.82 -0.241 0.82289E+04 20 analcite 3.32 2.77 -0.55 -0.061 0.94501E+03 26 annite 20.12 17.71 -2.42 -0.134 0.41278E+04 27 phlogopite 27.06 25.40 -1.66 -0.092 0.28375E+04 29 anorthite 12.71 8.24 -4.47 -0.344 0.76341E+04 35 aragonite 0.97 -3.50 -4.46 -1.488 0.76226E+04 36 brucite 12.57 9.30 -3.27 -0.654 0.55871E+04 37 calcite 0.81 -3.50 -4.31 -1.437 0.73584E+04 38 carnegieite-low 9.02 5.92 -3.10 -0.443 0.52976E+04 39 carnegieite-high 10.09 5.92 -4.17 -0.596 0.71246E+04 40 carpholite-Mg 8.58 4.45 -4.13 -0.275 0.70499E+04 41 carpholite-Fe 6.71 1.89 -4.83 -0.322 0.82386E+04 42 celadonite 5.34 3.66 -1.68 -0.099 0.28753E+04 43 celadonite-Fe 3.88 1.09 -2.78 -0.164 0.47544E+04 44 chrysotile 23.89 21.58 -2.31 -0.192 0.39403E+04 49 chlorite-Al-free 47.17 43.17 -4.00 -0.167 0.68357E+04 51 chloritoid-Fe 9.17 5.04 -4.13 -0.276 0.70583E+04 52 chloritoid-Mn 11.40 7.52 -3.88 -0.259 0.66264E+04 54 coesite -2.38 -3.15 -0.78 -0.259 0.13254E+04 61 cristobalite -2.56 -3.15 -0.59 -0.197 0.10107E+04 63 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71234E+04 65 diaspore 2.87 0.73 -2.14 -0.357 0.36591E+04 66 diamond -3.10 -7.74 -4.64 -1.326 0.79252E+04 67 diopside 16.18 16.07 -0.11 -0.011 0.18263E+03 68 hedenbergite 14.21 13.51 -0.70 -0.070 0.11944E+04 71 enstatite 17.26 12.29 -4.98 -0.498 0.84974E+04 73 clinoenstatite 17.17 12.29 -4.88 -0.488 0.83290E+04 75 epidote 24.67 22.69 -1.98 -0.096 0.33785E+04 76 clinozoisite 22.81 18.90 -3.91 -0.178 0.66690E+04 77 epidote-Fe 29.84 26.48 -3.36 -0.174 0.57346E+04 78 fayalite 14.05 10.31 -3.74 -0.534 0.63798E+04 79 ferrosilite 11.15 7.16 -3.99 -0.399 0.68169E+04 83 gibbsite 4.08 0.73 -3.35 -0.478 0.57177E+04 84 glaucophane 22.97 20.82 -2.16 -0.058 0.36844E+04 85 glaucophane-Fe 17.28 13.12 -4.16 -0.112 0.70958E+04 86 graphite -3.55 -7.74 -4.20 -1.199 0.71675E+04 87 greenalite 16.14 13.89 -2.25 -0.188 0.38447E+04 90 hematite 12.57 9.04 -3.52 -0.427 0.60150E+04 91 heulandite -5.83 -7.52 -1.69 -0.077 0.28938E+04 95 jadeite 4.22 2.77 -1.45 -0.145 0.24705E+04 97 kalsilite 7.58 3.82 -3.77 -0.538 0.64301E+04 98 kaolinite -1.33 -4.84 -3.51 -0.319 0.59940E+04 101 laumontite 2.88 1.93 -0.95 -0.063 0.16198E+04 102 lawsonite 9.62 8.24 -1.38 -0.092 0.23508E+04 103 leucite 4.12 0.67 -3.45 -0.345 0.58960E+04 105 lizardite 23.24 21.58 -1.66 -0.138 0.28329E+04 107 magnetite 20.09 15.77 -4.31 -0.352 0.73647E+04 108 minnesotaite 10.39 7.58 -2.80 -0.165 0.47891E+04 112 manganosite 14.06 9.21 -4.85 -1.212 0.82761E+04 120 muscovite 2.58 -1.03 -3.61 -0.212 0.61598E+04 121 paragonite 4.24 1.08 -3.16 -0.186 0.53989E+04 122 nepheline 8.34 5.92 -2.42 -0.346 0.41300E+04 128 periclase-Fe 11.63 6.73 -4.90 -1.224 0.83594E+04 134 phlogopite-Na 29.65 27.51 -2.14 -0.119 0.36563E+04 136 prehnite 19.37 18.17 -1.20 -0.071 0.20529E+04 137 prehnite-Fe 22.50 21.96 -0.54 -0.032 0.91737E+03 138 pumpellyite-Fe 46.27 43.80 -2.47 -0.055 0.42154E+04 139 pumpellyite-Mg 48.99 46.37 -2.63 -0.058 0.44883E+04 143 pyrrhotite -4.26 -8.06 -3.80 -1.266 0.64863E+04 144 pyrrhotiteFe0.875 -6.02 -9.45 -3.43 -1.262 0.58589E+04 145 pyroxmangite 7.40 6.06 -1.34 -0.268 0.22877E+04 146 pyrophyllite -6.18 -11.15 -4.97 -0.311 0.84895E+04 147 quartz -2.99 -3.15 -0.16 -0.054 0.27804E+03 152 rhodonite 7.45 6.06 -1.39 -0.277 0.23679E+04 153 sanidine -1.28 -2.49 -1.21 -0.093 0.20677E+04 165 stilpnomelane-Mg 27.44 25.85 -1.60 -0.048 0.27256E+04 171 talc 16.49 15.28 -1.21 -0.071 0.20676E+04 174 tephroite 18.09 15.27 -2.82 -0.402 0.48079E+04 178 tridymite -2.63 -3.15 -0.53 -0.175 0.89802E+03 179 tremolite 47.87 47.43 -0.44 -0.012 0.75177E+03 180 ferroactinolite 38.45 34.60 -3.85 -0.104 0.65764E+04 181 troilite-low -4.41 -8.06 -3.65 -1.216 0.62291E+04 187 wairakite 3.95 1.93 -2.02 -0.119 0.34417E+04 188 walstromite 11.51 9.93 -1.58 -0.316 0.26961E+04 189 wollastonite 10.46 9.93 -0.53 -0.106 0.90650E+03 190 pseudo-wollastonite 11.00 9.93 -1.07 -0.214 0.18263E+04 191 zoisite 22.85 18.90 -3.95 -0.180 0.67431E+04 192 akaganeite 7.75 4.52 -3.23 -0.699 0.55201E+04 199 chalcedony -2.80 -3.15 -0.35 -0.117 0.59734E+03 201 montmorillonite-Ca -2.29 -6.16 -3.87 -0.240 0.66108E+04 202 montmorillonite-K -2.24 -6.26 -4.03 -0.246 0.68730E+04 203 montmorillonite-Mg -2.48 -6.79 -4.31 -0.266 0.73545E+04 204 montmorillonite-Na -2.04 -5.57 -3.53 -0.216 0.60279E+04 205 nontronite-Ca 3.21 -0.13 -3.34 -0.217 0.57034E+04 206 nontronite-H 2.53 -2.28 -4.82 -0.323 0.82249E+04 207 nontronite-K 3.34 -0.23 -3.57 -0.229 0.60887E+04 208 nontronite-Mg 3.07 -0.75 -3.83 -0.248 0.65311E+04 209 nontronite-Na 3.52 0.47 -3.05 -0.196 0.52096E+04 224 tobermorite 9.82 7.75 -2.08 -0.567 0.35474E+04 230 alabandite -0.98 -5.58 -4.60 -1.534 0.78559E+04 233 boehmite 4.41 0.73 -3.68 -0.613 0.62761E+04 235 ferrous-oxide 9.81 6.73 -3.08 -0.770 0.52604E+04 240 silica-amorphous -2.09 -3.15 -1.06 -0.354 0.18115E+04 242 an20ab80 2.02 1.34 -0.68 -0.052 0.11560E+04 243 an25ab75 2.65 1.77 -0.87 -0.067 0.14919E+04 244 an30ab70 3.28 2.20 -1.08 -0.083 0.18375E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 4.0000000 g Current total amount of reactant added: 131.9990000 g New total amount of reactant added: 135.9990000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.7273E-13 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 11 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 135.9990000 Water: Moles liquid = 0.5466E+02 kg liquid = 0.9848E+00 Moles total = 0.5380E+02 kg total = 0.9693E+00 Activity = 1.0000 Stoichiometric ionic strength = .1126823E-01 Osmotic coef. = 0.9691 True ionic strength = .1991694E-01 Chg. balance for total moles = -.7273E-13 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.89098E-10 -10.0501 0.74888E-10 -10.1256 0.84052E+00 -0.0755 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13947E-03 -3.8555 0.11652E-03 -3.9336 0.83548E+00 -0.0781 4 SO4-- 0.10897E-11 -11.9627 0.56663E-12 -12.2467 0.52000E+00 -0.2840 5 HCO3- 0.39008E-06 -6.4088 0.32638E-06 -6.4863 0.83670E+00 -0.0774 6 HS- 0.25893E-04 -4.5868 0.21637E-04 -4.6648 0.83560E+00 -0.0780 7 Al+++ 0.97755E-29 -29.0099 0.22653E-29 -29.6449 0.23173E+00 -0.6350 8 H4SiO4 0.70308E-03 -3.1530 0.70308E-03 -3.1530 0.10000E+01 0.0000 9 Ca++ 0.13218E-06 -6.8788 0.68229E-07 -7.1660 0.51619E+00 -0.2872 10 Mg++ 0.21585E-10 -10.6658 0.11092E-10 -10.9550 0.51384E+00 -0.2892 11 Fe++ 0.58735E-13 -13.2311 0.30213E-13 -13.5198 0.51440E+00 -0.2887 12 K+ 0.15572E-03 -3.8077 0.13032E-03 -3.8850 0.83690E+00 -0.0773 13 Na+ 0.19760E-01 -1.7042 0.16506E-01 -1.7824 0.83533E+00 -0.0781 14 Mn++ 0.17762E-10 -10.7505 0.91442E-11 -11.0389 0.51483E+00 -0.2883 15 HPO4-- 0.47356E-07 -7.3246 0.24628E-07 -7.6086 0.52007E+00 -0.2839 16 HSiO3- 0.10492E-01 -1.9791 0.87663E-02 -2.0572 0.83548E+00 -0.0781 17 Ca(HSiO3)+ 0.16273E-07 -7.7885 0.13621E-07 -7.8658 0.83708E+00 -0.0772 18 Mg(HSiO3)+ 0.32921E-11 -11.4825 0.27558E-11 -11.5598 0.83708E+00 -0.0772 19 NaHSiO3,aq 0.23403E-02 -2.6307 0.23403E-02 -2.6307 0.10000E+01 0.0000 20 AlO+ 0.65647E-16 -16.1828 0.54952E-16 -16.2600 0.83708E+00 -0.0772 22 HAlO2,aq 0.14613E-09 -9.8353 0.14613E-09 -9.8353 0.10000E+01 0.0000 23 AlO2- 0.51793E-05 -5.2857 0.43194E-05 -5.3646 0.83398E+00 -0.0788 24 CH4,aq 0.12148E-04 -4.9155 0.12106E-04 -4.9170 0.99656E+00 -0.0015 25 C2H6,aq 0.24690E-14 -14.6075 0.24606E-14 -14.6090 0.99656E+00 -0.0015 29 CO,aq 0.13359E-16 -16.8742 0.13359E-16 -16.8742 0.10000E+01 0.0000 30 CO2,aq 0.52407E-10 -10.2806 0.52227E-10 -10.2821 0.99656E+00 -0.0015 31 CO3-2 0.73362E-06 -6.1345 0.38067E-06 -6.4194 0.51890E+00 -0.2849 32 CaCO3,aq 0.32567E-09 -9.4872 0.32567E-09 -9.4872 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.67906E-12 -12.1681 0.56843E-12 -12.2453 0.83708E+00 -0.0772 34 CaCl+ 0.15370E-10 -10.8133 0.12866E-10 -10.8906 0.83708E+00 -0.0772 35 CaCl2,aq 0.35617E-15 -15.4483 0.35617E-15 -15.4483 0.10000E+01 0.0000 36 CaOH+ 0.77570E-07 -7.1103 0.64932E-07 -7.1875 0.83708E+00 -0.0772 37 CaSO4,aq 0.12277E-16 -16.9109 0.12277E-16 -16.9109 0.10000E+01 0.0000 38 HCl,aq 0.15990E-14 -14.7961 0.15990E-14 -14.7961 0.10000E+01 0.0000 43 FeCl+ 0.66570E-17 -17.1767 0.55724E-17 -17.2540 0.83708E+00 -0.0772 46 FeO,aq 0.20938E-09 -9.6791 0.20938E-09 -9.6791 0.10000E+01 0.0000 47 FeOH+ 0.15689E-10 -10.8044 0.13133E-10 -10.8817 0.83708E+00 -0.0772 48 HFeO2- 0.35014E-07 -7.4558 0.29254E-07 -7.5338 0.83548E+00 -0.0781 49 FeO+ 0.11727E-16 -16.9308 0.98163E-17 -17.0081 0.83708E+00 -0.0772 51 FeO2- 0.42868E-09 -9.3679 0.35816E-09 -9.4459 0.83548E+00 -0.0781 52 HFeO2,aq 0.34113E-11 -11.4671 0.34113E-11 -11.4671 0.10000E+01 0.0000 53 H2,aq 0.10218E-04 -4.9907 0.10182E-04 -4.9921 0.99656E+00 -0.0015 54 KCl,aq 0.27522E-09 -9.5603 0.27522E-09 -9.5603 0.10000E+01 0.0000 56 KOH,aq 0.74317E-06 -6.1289 0.74317E-06 -6.1289 0.10000E+01 0.0000 57 KSO4- 0.13715E-14 -14.8628 0.11459E-14 -14.9409 0.83548E+00 -0.0781 58 MgCO3,aq 0.13270E-13 -13.8771 0.13270E-13 -13.8771 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.11280E-15 -15.9477 0.94421E-16 -16.0249 0.83708E+00 -0.0772 60 MgCl+ 0.22646E-14 -14.6450 0.18956E-14 -14.7222 0.83708E+00 -0.0772 61 MgOH+ 0.69778E-10 -10.1563 0.58409E-10 -10.2335 0.83708E+00 -0.0772 63 MnO,aq 0.16885E-08 -8.7725 0.16885E-08 -8.7725 0.10000E+01 0.0000 64 MnOH+ 0.44109E-09 -9.3555 0.36923E-09 -9.4327 0.83708E+00 -0.0772 65 MnO2-2 0.19256E-10 -10.7154 0.99921E-11 -11.0003 0.51890E+00 -0.2849 66 HMnO2- 0.19622E-09 -9.7073 0.16394E-09 -9.7853 0.83548E+00 -0.0781 69 MnCl+ 0.78383E-14 -14.1058 0.65613E-14 -14.1830 0.83708E+00 -0.0772 71 NaCl,aq 0.63740E-06 -6.1956 0.63740E-06 -6.1956 0.10000E+01 0.0000 72 NaOH,aq 0.94699E-04 -4.0237 0.94699E-04 -4.0237 0.10000E+01 0.0000 74 OH- 0.92510E-02 -2.0338 0.77152E-02 -2.1127 0.83398E+00 -0.0788 79 HPO3-2 0.15061E-14 -14.8221 0.78151E-15 -15.1071 0.51890E+00 -0.2849 81 H2PO3- 0.14047E-18 -18.8524 0.11736E-18 -18.9305 0.83548E+00 -0.0781 82 H3PO4,aq 0.96602E-18 -18.0150 0.96602E-18 -18.0150 0.10000E+01 0.0000 83 H2PO4- 0.40685E-10 -10.3906 0.34024E-10 -10.4682 0.83627E+00 -0.0777 84 PO4-3 0.11027E-08 -8.9576 0.26832E-09 -9.5713 0.24334E+00 -0.6138 88 HP2O7-3 0.10433E-17 -17.9816 0.24202E-18 -18.6161 0.23196E+00 -0.6346 89 P2O7-4 0.99600E-17 -17.0017 0.77205E-18 -18.1124 0.77516E-01 -1.1106 90 H2S,aq 0.50251E-08 -8.2989 0.50078E-08 -8.3004 0.99656E+00 -0.0015 91 S2-2 0.19633E-14 -14.7070 0.10187E-14 -14.9919 0.51890E+00 -0.2849 97 SO3-2 0.14244E-17 -17.8464 0.74977E-18 -18.1251 0.52637E+00 -0.2787 99 HSO4- 0.48806E-19 -19.3115 0.40894E-19 -19.3883 0.83789E+00 -0.0768 Charge balance for all species = -.7493E-13 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.8909767E-10 -.2220343E-01 -.2234093E+02 0.0000 2 H2O 0.1000000E+01 0.5550480E+02 0.9982022E+06 0.0000 3 Cl- 0.1394673E-03 0.1401050E-03 0.4958531E+01 6.1920 4 SO4-- 0.1089682E-11 -.1470210E-04 -.1409859E+01 8.0045 5 HCO3- 0.3900793E-06 0.1327184E-04 0.8084070E+00 3.6393 6 HS- 0.2589332E-04 0.4060044E-04 0.1340410E+01 5.4608 7 Al+++ 0.9775539E-29 0.5179450E-05 0.1395071E+00 0.7319 8 H4SiO4 0.7030763E-03 0.1353587E-01 0.1298750E+04 -3.1530 9 Ca++ 0.1321775E-06 0.2263621E-06 0.9056415E-02 13.0851 10 Mg++ 0.2158545E-10 0.9467084E-10 0.2297648E-05 9.2962 11 Fe++ 0.5873462E-13 0.3567167E-07 0.1988703E-02 6.7314 12 K+ 0.1557201E-03 0.1564636E-03 0.6107434E+01 6.2406 13 Na+ 0.1975995E-01 0.2219557E-01 0.5093871E+03 8.3432 14 Mn++ 0.1776159E-10 0.2362874E-08 0.1295866E-03 9.2123 15 HPO4-- 0.4735609E-07 0.4849944E-07 0.4646859E-02 12.6426 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.2251928E+01 -.2186575E-01 -.2230063E+01 0.0000000E+00 2 H2O 0.5380345E+02 0.5466066E+02 -.8572087E+00 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.3794500E-02 -.1447850E-04 0.3808979E-02 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.3768996E-02 0.3998297E-04 -.3808979E-02 0.0000000E+00 7 Al+++ 0.4434576E+00 0.5100679E-05 0.4434525E+00 0.0000000E+00 8 H4SiO4 0.1416128E+01 0.1333001E-01 0.1402798E+01 0.0000000E+00 9 Ca++ 0.1564327E+00 0.2229195E-06 0.1564325E+00 0.0000000E+00 10 Mg++ 0.1079357E+00 0.9323105E-10 0.1079357E+00 0.0000000E+00 11 Fe++ 0.9696846E-01 0.3512916E-07 0.9696842E-01 0.0000000E+00 12 K+ 0.2887452E-01 0.1540840E-03 0.2872044E-01 0.0000000E+00 13 Na+ 0.1708719E+00 0.2185801E-01 0.1490139E+00 0.0000000E+00 14 Mn++ 0.2358032E-02 0.2326939E-08 0.2358029E-02 0.0000000E+00 15 HPO4-- 0.8047845E-03 0.4776184E-07 0.8047367E-03 0.0000000E+00 Chg. balance for solid moles: 0.1609E-15 Mass of aqueous solution: 0.986502E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 135.9990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 0.1489 -0.827 39.04 1.591 26.30 14.99 andradite 0.1524E-01 -1.817 7.743 0.889 5.217 2.012 grossular 0.3431E-02 -2.465 1.546 0.189 1.042 0.4301 apatite-OH 0.2682E-03 -3.571 0.1347 -0.870 0.9079E-01 0.4282E-01 clinochlore 0.2076E-01 -1.683 11.54 1.062 7.775 4.389 daphnite 0.5933E-02 -2.227 4.234 0.627 2.853 1.283 chlorite-Mn 0.4716E-03 -3.326 0.3344 -0.476 0.2253 0.1066 microcline 0.2518E-01 -1.599 7.009 0.846 4.723 2.738 stilbite 0.9681E-01 -1.014 68.22 1.834 45.97 31.82 stilpnomelane-Fe 0.7081E-02 -2.150 7.633 0.883 5.143 2.637 tr.625ac.25prg.125 0.1140E-02 -2.943 0.9745 -0.011 0.6567 0.3137 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8162E+00 0.8162E+00 1.0000 -0.088 grossular 0.1838E+00 0.1838E+00 1.0000 -0.736 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.7642E+00 0.7642E+00 1.0000 -0.117 daphnite 0.2184E+00 0.2184E+00 1.0000 -0.661 chlorite-Mn 0.1736E-01 0.1736E-01 1.0000 -1.760 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 tr.625ac.25prg.125 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 148.406701 g Volume = 60.757139 cm3 Porosity: -9.6707% V(tot) - V(min): -.53575E+01 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 135.9990000 g log = 2.1335 Original solution: 1000.0103000 g Original solution / Rock added: 7.35 (Water/Rock Ratio), log = 0.8665 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0517 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9706E+00 0.9855 0.1006E+01 0.1021E+01 CO2,gas 0.5276E-08 1.0069 0.5588E-08 0.5549E-08 CH4,gas 0.1673E-01 1.0125 0.1782E-01 0.1760E-01 H2,gas 0.1270E-01 1.0006 0.1337E-01 0.1336E-01 H2S,gas 0.1314E-06 0.9959 0.1377E-06 0.1382E-06 S2,gas 0.3785E-29 1.0000 0.3980E-29 0.3980E-29 CO,gas 0.1893E-13 1.0000 0.1991E-13 0.1991E-13 SO3,gas 0.1142E-47 1.0000 0.1202E-47 0.1202E-47 SO2,gas 0.5942E-27 1.0000 0.6249E-27 0.6249E-27 HCl,gas 0.2683E-17 1.0000 0.2822E-17 0.2822E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 16 albite -0.38 -0.38 0.00 0.000 0.23317E-10 22 andradite 39.01 39.01 0.00 0.000 -0.12132E-10 23 grossular 32.73 32.73 0.00 0.000 -0.24265E-10 32 apatite-OH -18.15 -18.15 0.00 0.000 0.12132E-10 46 clinochlore 39.07 39.07 0.00 0.000 0.12132E-10 47 daphnite 28.97 28.97 0.00 0.000 0.66728E-10 48 chlorite-Mn 46.87 46.87 0.00 0.000 0.24265E-10 116 microcline -2.49 -2.49 0.00 0.000 0.13649E-10 163 stilbite -7.52 -7.52 0.00 0.000 0.15165E-10 164 stilpnomelane-Fe 13.02 13.02 0.00 0.000 -0.27298E-10 245 tr.625ac.25prg.125 45.16 45.16 0.00 0.000 -0.72794E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -16.61 -9.95 -3.317 0.16992E+05 -8.253 3 CH4,gas 4.54 1.10 -3.45 -0.862 0.58875E+04 -1.749 4 H2,gas 8.00 4.43 -3.57 -2.042 0.61006E+04 -1.874 5 H2S,gas -6.23 -14.79 -8.56 -4.280 0.14616E+05 -6.861 6 S2,gas -7.34 -38.43 -31.10 -4.784 0.53101E+05 -29.400 7 CO,gas 3.21 -12.18 -15.40 -4.738 0.26295E+05 -13.701 8 SO3,gas 17.12 -32.50 -49.62 -12.405 0.84723E+05 -47.920 9 SO2,gas 0.83 -28.07 -28.90 -7.708 0.49351E+05 -27.204 10 HCl,gas 5.19 -14.06 -19.25 -9.624 0.32866E+05 -17.550 11 acmite 7.71 6.56 -1.15 -0.120 0.19713E+04 15 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 19 spessartine 24.46 19.64 -4.82 -0.241 0.82225E+04 20 analcite 3.32 2.77 -0.55 -0.061 0.94377E+03 26 annite 20.12 17.71 -2.42 -0.134 0.41249E+04 27 phlogopite 27.06 25.40 -1.66 -0.092 0.28388E+04 29 anorthite 12.71 8.24 -4.47 -0.344 0.76279E+04 35 aragonite 0.97 -3.53 -4.49 -1.498 0.76721E+04 36 brucite 12.57 9.30 -3.27 -0.654 0.55875E+04 37 calcite 0.81 -3.53 -4.34 -1.446 0.74079E+04 38 carnegieite-low 9.02 5.92 -3.10 -0.443 0.52952E+04 39 carnegieite-high 10.09 5.92 -4.17 -0.596 0.71222E+04 40 carpholite-Mg 8.58 4.45 -4.13 -0.275 0.70487E+04 41 carpholite-Fe 6.71 1.89 -4.82 -0.322 0.82360E+04 42 celadonite 5.34 3.66 -1.68 -0.099 0.28770E+04 43 celadonite-Fe 3.88 1.09 -2.78 -0.164 0.47547E+04 44 chrysotile 23.89 21.58 -2.31 -0.192 0.39441E+04 49 chlorite-Al-free 47.17 43.17 -4.01 -0.167 0.68433E+04 51 chloritoid-Fe 9.17 5.04 -4.13 -0.275 0.70544E+04 52 chloritoid-Mn 11.40 7.52 -3.88 -0.259 0.66215E+04 54 coesite -2.38 -3.15 -0.78 -0.259 0.13266E+04 61 cristobalite -2.56 -3.15 -0.59 -0.198 0.10119E+04 63 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71234E+04 65 diaspore 2.87 0.73 -2.14 -0.357 0.36571E+04 66 diamond -3.10 -7.76 -4.66 -1.330 0.79495E+04 67 diopside 16.18 16.08 -0.11 -0.011 0.18106E+03 68 hedenbergite 14.21 13.51 -0.70 -0.070 0.11914E+04 71 enstatite 17.26 12.29 -4.98 -0.498 0.85008E+04 73 clinoenstatite 17.17 12.29 -4.88 -0.488 0.83324E+04 75 epidote 24.67 22.69 -1.98 -0.096 0.33755E+04 76 clinozoisite 22.81 18.91 -3.90 -0.177 0.66575E+04 77 epidote-Fe 29.84 26.48 -3.36 -0.175 0.57401E+04 78 fayalite 14.05 10.31 -3.74 -0.534 0.63791E+04 79 ferrosilite 11.15 7.16 -3.99 -0.399 0.68174E+04 83 gibbsite 4.08 0.73 -3.35 -0.478 0.57156E+04 84 glaucophane 22.97 20.81 -2.16 -0.058 0.36882E+04 85 glaucophane-Fe 17.28 13.12 -4.16 -0.112 0.70953E+04 86 graphite -3.55 -7.76 -4.21 -1.203 0.71918E+04 87 greenalite 16.14 13.89 -2.25 -0.188 0.38442E+04 90 hematite 12.57 9.04 -3.53 -0.428 0.60279E+04 91 heulandite -5.83 -7.52 -1.69 -0.077 0.28938E+04 95 jadeite 4.22 2.77 -1.45 -0.145 0.24693E+04 97 kalsilite 7.58 3.82 -3.76 -0.538 0.64276E+04 98 kaolinite -1.33 -4.84 -3.51 -0.319 0.59923E+04 101 laumontite 2.88 1.94 -0.95 -0.063 0.16161E+04 102 lawsonite 9.62 8.24 -1.37 -0.092 0.23446E+04 103 leucite 4.12 0.67 -3.45 -0.345 0.58948E+04 105 lizardite 23.24 21.58 -1.66 -0.138 0.28367E+04 107 magnetite 20.09 15.77 -4.32 -0.353 0.73765E+04 108 minnesotaite 10.39 7.58 -2.81 -0.165 0.47911E+04 112 manganosite 14.06 9.21 -4.85 -1.211 0.82741E+04 120 muscovite 2.58 -1.02 -3.61 -0.212 0.61557E+04 121 paragonite 4.24 1.08 -3.16 -0.186 0.53948E+04 122 nepheline 8.34 5.92 -2.42 -0.345 0.41275E+04 128 periclase-Fe 11.63 6.73 -4.90 -1.224 0.83584E+04 134 phlogopite-Na 29.65 27.50 -2.14 -0.119 0.36576E+04 136 prehnite 19.37 18.18 -1.20 -0.070 0.20435E+04 137 prehnite-Fe 22.50 21.96 -0.54 -0.032 0.91646E+03 138 pumpellyite-Fe 46.27 43.81 -2.46 -0.055 0.41935E+04 139 pumpellyite-Mg 48.99 46.38 -2.62 -0.058 0.44679E+04 143 pyrrhotite -4.26 -8.06 -3.80 -1.266 0.64862E+04 144 pyrrhotiteFe0.875 -6.02 -9.45 -3.43 -1.262 0.58608E+04 145 pyroxmangite 7.40 6.06 -1.34 -0.268 0.22869E+04 146 pyrophyllite -6.18 -11.15 -4.97 -0.311 0.84902E+04 147 quartz -2.99 -3.15 -0.16 -0.055 0.27928E+03 152 rhodonite 7.45 6.06 -1.39 -0.277 0.23672E+04 153 sanidine -1.28 -2.49 -1.21 -0.093 0.20677E+04 165 stilpnomelane-Mg 27.44 25.84 -1.60 -0.048 0.27328E+04 171 talc 16.49 15.28 -1.21 -0.071 0.20738E+04 174 tephroite 18.09 15.27 -2.81 -0.402 0.48051E+04 178 tridymite -2.63 -3.15 -0.53 -0.176 0.89926E+03 179 tremolite 47.87 47.43 -0.44 -0.012 0.75490E+03 180 ferroactinolite 38.45 34.60 -3.85 -0.104 0.65724E+04 181 troilite-low -4.41 -8.06 -3.65 -1.216 0.62290E+04 183 vesuvianite 223.47 218.51 -4.96 -0.038 0.84759E+04 187 wairakite 3.95 1.94 -2.01 -0.118 0.34380E+04 188 walstromite 11.51 9.93 -1.58 -0.315 0.26928E+04 189 wollastonite 10.46 9.93 -0.53 -0.106 0.90325E+03 190 pseudo-wollastonite 11.00 9.93 -1.07 -0.214 0.18231E+04 191 zoisite 22.85 18.91 -3.94 -0.179 0.67316E+04 192 akaganeite 7.75 4.52 -3.24 -0.700 0.55265E+04 199 chalcedony -2.80 -3.15 -0.35 -0.117 0.59858E+03 201 montmorillonite-Ca -2.29 -6.16 -3.87 -0.240 0.66117E+04 202 montmorillonite-K -2.24 -6.26 -4.03 -0.247 0.68741E+04 203 montmorillonite-Mg -2.48 -6.79 -4.31 -0.267 0.73562E+04 204 montmorillonite-Na -2.04 -5.57 -3.53 -0.216 0.60290E+04 205 nontronite-Ca 3.21 -0.14 -3.35 -0.217 0.57193E+04 206 nontronite-H 2.53 -2.29 -4.83 -0.324 0.82416E+04 207 nontronite-K 3.34 -0.23 -3.58 -0.229 0.61049E+04 208 nontronite-Mg 3.07 -0.76 -3.83 -0.249 0.65479E+04 209 nontronite-Na 3.52 0.46 -3.06 -0.196 0.52258E+04 224 tobermorite 9.82 7.75 -2.08 -0.566 0.35449E+04 230 alabandite -0.98 -5.58 -4.60 -1.533 0.78547E+04 233 boehmite 4.41 0.73 -3.67 -0.612 0.62740E+04 235 ferrous-oxide 9.81 6.73 -3.08 -0.770 0.52594E+04 240 silica-amorphous -2.09 -3.15 -1.06 -0.354 0.18128E+04 242 an20ab80 2.02 1.34 -0.68 -0.052 0.11547E+04 243 an25ab75 2.65 1.77 -0.87 -0.067 0.14904E+04 244 an30ab70 3.28 2.20 -1.08 -0.083 0.18357E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 4.0000000 g Current total amount of reactant added: 135.9990000 g New total amount of reactant added: 139.9990000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.7248E-13 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 11 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 139.9990000 Water: Moles liquid = 0.5464E+02 kg liquid = 0.9844E+00 Moles total = 0.5375E+02 kg total = 0.9684E+00 Activity = 1.0000 Stoichiometric ionic strength = .1127534E-01 Osmotic coef. = 0.9692 True ionic strength = .1992988E-01 Chg. balance for total moles = -.7248E-13 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.88973E-10 -10.0507 0.74780E-10 -10.1262 0.84048E+00 -0.0755 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13952E-03 -3.8554 0.11656E-03 -3.9334 0.83545E+00 -0.0781 4 SO4-- 0.10129E-11 -11.9944 0.52664E-12 -12.2785 0.51991E+00 -0.2841 5 HCO3- 0.36474E-06 -6.4380 0.30516E-06 -6.5155 0.83666E+00 -0.0774 6 HS- 0.25904E-04 -4.5866 0.21644E-04 -4.6647 0.83557E+00 -0.0780 7 Al+++ 0.97627E-29 -29.0104 0.22615E-29 -29.6456 0.23164E+00 -0.6352 8 H4SiO4 0.70198E-03 -3.1537 0.70198E-03 -3.1537 0.10000E+01 0.0000 9 Ca++ 0.13257E-06 -6.8776 0.68419E-07 -7.1648 0.51610E+00 -0.2873 10 Mg++ 0.21515E-10 -10.6673 0.11053E-10 -10.9565 0.51375E+00 -0.2892 11 Fe++ 0.58648E-13 -13.2317 0.30164E-13 -13.5205 0.51431E+00 -0.2888 12 K+ 0.15582E-03 -3.8074 0.13040E-03 -3.8847 0.83686E+00 -0.0773 13 Na+ 0.19773E-01 -1.7039 0.16516E-01 -1.7821 0.83530E+00 -0.0782 14 Mn++ 0.17759E-10 -10.7506 0.91411E-11 -11.0390 0.51474E+00 -0.2884 15 HPO4-- 0.47055E-07 -7.3274 0.24468E-07 -7.6114 0.51998E+00 -0.2840 16 HSiO3- 0.10492E-01 -1.9792 0.87653E-02 -2.0572 0.83545E+00 -0.0781 17 Ca(HSiO3)+ 0.16317E-07 -7.7874 0.13658E-07 -7.8646 0.83704E+00 -0.0773 18 Mg(HSiO3)+ 0.32806E-11 -11.4841 0.27460E-11 -11.5613 0.83704E+00 -0.0773 19 NaHSiO3,aq 0.23414E-02 -2.6305 0.23414E-02 -2.6305 0.10000E+01 0.0000 20 AlO+ 0.65727E-16 -16.1823 0.55016E-16 -16.2595 0.83704E+00 -0.0773 22 HAlO2,aq 0.14651E-09 -9.8341 0.14651E-09 -9.8341 0.10000E+01 0.0000 23 AlO2- 0.52006E-05 -5.2839 0.43370E-05 -5.3628 0.83394E+00 -0.0789 24 CH4,aq 0.12225E-04 -4.9127 0.12183E-04 -4.9142 0.99656E+00 -0.0015 25 C2H6,aq 0.24541E-14 -14.6101 0.24457E-14 -14.6116 0.99656E+00 -0.0015 29 CO,aq 0.12709E-16 -16.8959 0.12709E-16 -16.8959 0.10000E+01 0.0000 30 CO2,aq 0.48930E-10 -10.3104 0.48761E-10 -10.3119 0.99656E+00 -0.0015 31 CO3-2 0.68704E-06 -6.1630 0.35644E-06 -6.4480 0.51881E+00 -0.2850 32 CaCO3,aq 0.30579E-09 -9.5146 0.30579E-09 -9.5146 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.63671E-12 -12.1961 0.53295E-12 -12.2733 0.83704E+00 -0.0773 34 CaCl+ 0.15419E-10 -10.8119 0.12906E-10 -10.8892 0.83704E+00 -0.0773 35 CaCl2,aq 0.35742E-15 -15.4468 0.35742E-15 -15.4468 0.10000E+01 0.0000 36 CaOH+ 0.77901E-07 -7.1085 0.65207E-07 -7.1857 0.83704E+00 -0.0773 37 CaSO4,aq 0.11442E-16 -16.9415 0.11442E-16 -16.9415 0.10000E+01 0.0000 38 HCl,aq 0.15973E-14 -14.7966 0.15973E-14 -14.7966 0.10000E+01 0.0000 43 FeCl+ 0.66487E-17 -17.1773 0.55652E-17 -17.2545 0.83704E+00 -0.0773 46 FeO,aq 0.20964E-09 -9.6785 0.20964E-09 -9.6785 0.10000E+01 0.0000 47 FeOH+ 0.15686E-10 -10.8045 0.13130E-10 -10.8817 0.83704E+00 -0.0773 48 HFeO2- 0.35110E-07 -7.4546 0.29332E-07 -7.5327 0.83545E+00 -0.0781 49 FeO+ 0.11616E-16 -16.9350 0.97227E-17 -17.0122 0.83704E+00 -0.0773 51 FeO2- 0.42584E-09 -9.3708 0.35577E-09 -9.4488 0.83545E+00 -0.0781 52 HFeO2,aq 0.33837E-11 -11.4706 0.33837E-11 -11.4706 0.10000E+01 0.0000 53 H2,aq 0.10411E-04 -4.9825 0.10375E-04 -4.9840 0.99656E+00 -0.0015 54 KCl,aq 0.27549E-09 -9.5599 0.27549E-09 -9.5599 0.10000E+01 0.0000 56 KOH,aq 0.74470E-06 -6.1280 0.74470E-06 -6.1280 0.10000E+01 0.0000 57 KSO4- 0.12755E-14 -14.8943 0.10657E-14 -14.9724 0.83545E+00 -0.0781 58 MgCO3,aq 0.12383E-13 -13.9072 0.12383E-13 -13.9072 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.10511E-15 -15.9784 0.87979E-16 -16.0556 0.83704E+00 -0.0773 60 MgCl+ 0.22577E-14 -14.6463 0.18898E-14 -14.7236 0.83704E+00 -0.0773 61 MgOH+ 0.69641E-10 -10.1571 0.58292E-10 -10.2344 0.83704E+00 -0.0773 63 MnO,aq 0.16929E-08 -8.7714 0.16929E-08 -8.7714 0.10000E+01 0.0000 64 MnOH+ 0.44160E-09 -9.3550 0.36964E-09 -9.4322 0.83704E+00 -0.0773 65 MnO2-2 0.19365E-10 -10.7130 0.10047E-10 -10.9980 0.51881E+00 -0.2850 66 HMnO2- 0.19701E-09 -9.7055 0.16459E-09 -9.7836 0.83545E+00 -0.0781 69 MnCl+ 0.78389E-14 -14.1057 0.65615E-14 -14.1830 0.83704E+00 -0.0773 71 NaCl,aq 0.63802E-06 -6.1952 0.63802E-06 -6.1952 0.10000E+01 0.0000 72 NaOH,aq 0.94893E-04 -4.0228 0.94893E-04 -4.0228 0.10000E+01 0.0000 74 OH- 0.92648E-02 -2.0332 0.77263E-02 -2.1120 0.83394E+00 -0.0789 79 HPO3-2 0.15249E-14 -14.8168 0.79111E-15 -15.1018 0.51881E+00 -0.2850 81 H2PO3- 0.14200E-18 -18.8477 0.11863E-18 -18.9258 0.83545E+00 -0.0781 82 H3PO4,aq 0.95695E-18 -18.0191 0.95695E-18 -18.0191 0.10000E+01 0.0000 83 H2PO4- 0.40363E-10 -10.3940 0.33753E-10 -10.4717 0.83624E+00 -0.0777 84 PO4-3 0.10974E-08 -8.9596 0.26696E-09 -9.5736 0.24325E+00 -0.6139 88 HP2O7-3 0.10287E-17 -17.9877 0.23853E-18 -18.6225 0.23187E+00 -0.6347 89 P2O7-4 0.98371E-17 -17.0071 0.76201E-18 -18.1180 0.77463E-01 -1.1109 90 H2S,aq 0.50197E-08 -8.2993 0.50024E-08 -8.3008 0.99656E+00 -0.0015 91 S2-2 0.19285E-14 -14.7148 0.10005E-14 -14.9998 0.51881E+00 -0.2850 97 SO3-2 0.13491E-17 -17.8699 0.71004E-18 -18.1487 0.52628E+00 -0.2788 99 HSO4- 0.45298E-19 -19.3439 0.37953E-19 -19.4208 0.83785E+00 -0.0768 Charge balance for all species = -.7433E-13 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.8897286E-10 -.2221788E-01 -.2235546E+02 0.0000 2 H2O 0.1000000E+01 0.5550481E+02 0.9982020E+06 0.0000 3 Cl- 0.1395236E-03 0.1401619E-03 0.4960543E+01 6.1928 4 SO4-- 0.1012942E-11 -.1482779E-04 -.1421912E+01 7.9739 5 HCO3- 0.3647375E-06 0.1327724E-04 0.8087350E+00 3.6107 6 HS- 0.2590384E-04 0.4073666E-04 0.1344907E+01 5.4616 7 Al+++ 0.9762657E-29 0.5200766E-05 0.1400812E+00 0.7330 8 H4SiO4 0.7019825E-03 0.1353518E-01 0.1298684E+04 -3.1537 9 Ca++ 0.1325675E-06 0.2271073E-06 0.9086222E-02 13.0876 10 Mg++ 0.2151497E-10 0.9445116E-10 0.2292315E-05 9.2959 11 Fe++ 0.5864825E-13 0.3576455E-07 0.1993880E-02 6.7319 12 K+ 0.1558215E-03 0.1565665E-03 0.6111447E+01 6.2415 13 Na+ 0.1977283E-01 0.2220980E-01 0.5097135E+03 8.3441 14 Mn++ 0.1775885E-10 0.2368606E-08 0.1299009E-03 9.2134 15 HPO4-- 0.4705512E-07 0.4819293E-07 0.4617489E-02 12.6410 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.2318163E+01 -.2187110E-01 -.2296291E+01 0.0000000E+00 2 H2O 0.5375331E+02 0.5463847E+02 -.8851683E+00 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.3905354E-02 -.1459635E-04 0.3919950E-02 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.3879850E-02 0.4010082E-04 -.3919950E-02 0.0000000E+00 7 Al+++ 0.4565006E+00 0.5119591E-05 0.4564954E+00 0.0000000E+00 8 H4SiO4 0.1457779E+01 0.1332392E-01 0.1444455E+01 0.0000000E+00 9 Ca++ 0.1610333E+00 0.2235625E-06 0.1610331E+00 0.0000000E+00 10 Mg++ 0.1111103E+00 0.9297693E-10 0.1111103E+00 0.0000000E+00 11 Fe++ 0.9982049E-01 0.3520633E-07 0.9982045E-01 0.0000000E+00 12 K+ 0.2972378E-01 0.1541227E-03 0.2956966E-01 0.0000000E+00 13 Na+ 0.1758929E+00 0.2186314E-01 0.1540298E+00 0.0000000E+00 14 Mn++ 0.2427386E-02 0.2331636E-08 0.2427384E-02 0.0000000E+00 15 HPO4-- 0.8284548E-03 0.4744072E-07 0.8284074E-03 0.0000000E+00 Chg. balance for solid moles: -.3578E-16 Mass of aqueous solution: 0.986102E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 139.9990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 0.1539 -0.813 40.35 1.606 26.41 15.49 andradite 0.1568E-01 -1.805 7.968 0.901 5.216 2.070 grossular 0.3570E-02 -2.447 1.608 0.206 1.053 0.4474 apatite-OH 0.2761E-03 -3.559 0.1387 -0.858 0.9079E-01 0.4408E-01 clinochlore 0.2130E-01 -1.672 11.84 1.073 7.751 4.504 daphnite 0.6100E-02 -2.215 4.352 0.639 2.849 1.319 chlorite-Mn 0.4855E-03 -3.314 0.3442 -0.463 0.2253 0.1097 microcline 0.2593E-01 -1.586 7.218 0.858 4.724 2.819 stilbite 0.9937E-01 -1.003 70.03 1.845 45.84 32.66 stilpnomelane-Fe 0.7276E-02 -2.138 7.843 0.895 5.134 2.709 tr.625ac.25prg.125 0.1265E-02 -2.898 1.082 0.034 0.7080 0.3481 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8146E+00 0.8146E+00 1.0000 -0.089 grossular 0.1854E+00 0.1854E+00 1.0000 -0.732 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.7639E+00 0.7639E+00 1.0000 -0.117 daphnite 0.2187E+00 0.2187E+00 1.0000 -0.660 chlorite-Mn 0.1741E-01 0.1741E-01 1.0000 -1.759 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 tr.625ac.25prg.125 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 152.774418 g Volume = 62.523529 cm3 Porosity: -9.6912% V(tot) - V(min): -.55239E+01 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 139.9990000 g log = 2.1461 Original solution: 1000.0103000 g Original solution / Rock added: 7.14 (Water/Rock Ratio), log = 0.8539 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0521 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9702E+00 0.9855 0.1006E+01 0.1021E+01 CO2,gas 0.4925E-08 1.0069 0.5217E-08 0.5181E-08 CH4,gas 0.1684E-01 1.0125 0.1793E-01 0.1771E-01 H2,gas 0.1294E-01 1.0006 0.1362E-01 0.1361E-01 H2S,gas 0.1312E-06 0.9959 0.1375E-06 0.1381E-06 S2,gas 0.3636E-29 1.0000 0.3826E-29 0.3826E-29 CO,gas 0.1800E-13 1.0000 0.1894E-13 0.1894E-13 SO3,gas 0.1058E-47 1.0000 0.1114E-47 0.1114E-47 SO2,gas 0.5609E-27 1.0000 0.5901E-27 0.5901E-27 HCl,gas 0.2679E-17 1.0000 0.2818E-17 0.2818E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 16 albite -0.38 -0.38 0.00 0.000 -0.13080E-10 22 andradite 39.01 39.01 0.00 0.000 0.00000E+00 23 grossular 32.73 32.73 0.00 0.000 0.12132E-10 32 apatite-OH -18.15 -18.15 0.00 0.000 -0.12132E-10 46 clinochlore 39.07 39.07 0.00 0.000 -0.12132E-10 47 daphnite 28.97 28.97 0.00 0.000 0.18198E-10 48 chlorite-Mn 46.87 46.87 0.00 0.000 0.12132E-10 116 microcline -2.49 -2.49 0.00 0.000 0.15165E-11 163 stilbite -7.52 -7.52 0.00 0.000 -0.90992E-11 164 stilpnomelane-Fe 13.02 13.02 0.00 0.000 0.21232E-10 245 tr.625ac.25prg.125 45.16 45.16 0.00 0.000 0.24265E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -16.64 -9.98 -3.327 0.17043E+05 -8.283 3 CH4,gas 4.54 1.10 -3.45 -0.861 0.58828E+04 -1.746 4 H2,gas 8.00 4.44 -3.56 -2.037 0.60867E+04 -1.866 5 H2S,gas -6.23 -14.79 -8.56 -4.280 0.14617E+05 -6.862 6 S2,gas -7.34 -38.45 -31.12 -4.787 0.53130E+05 -29.417 7 CO,gas 3.21 -12.21 -15.42 -4.745 0.26332E+05 -13.723 8 SO3,gas 17.12 -32.53 -49.65 -12.413 0.84780E+05 -47.953 9 SO2,gas 0.83 -28.10 -28.93 -7.714 0.49394E+05 -27.229 10 HCl,gas 5.19 -14.06 -19.25 -9.624 0.32867E+05 -17.550 11 acmite 7.71 6.55 -1.16 -0.120 0.19782E+04 15 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 19 spessartine 24.46 19.65 -4.81 -0.241 0.82164E+04 20 analcite 3.32 2.77 -0.55 -0.061 0.94262E+03 26 annite 20.12 17.71 -2.41 -0.134 0.41221E+04 27 phlogopite 27.06 25.40 -1.66 -0.092 0.28401E+04 29 anorthite 12.71 8.25 -4.46 -0.343 0.76222E+04 35 aragonite 0.97 -3.55 -4.52 -1.507 0.77188E+04 36 brucite 12.57 9.30 -3.27 -0.655 0.55880E+04 37 calcite 0.81 -3.55 -4.37 -1.455 0.74546E+04 38 carnegieite-low 9.02 5.92 -3.10 -0.443 0.52929E+04 39 carnegieite-high 10.09 5.92 -4.17 -0.596 0.71198E+04 40 carpholite-Mg 8.58 4.45 -4.13 -0.275 0.70475E+04 41 carpholite-Fe 6.71 1.89 -4.82 -0.321 0.82335E+04 42 celadonite 5.34 3.66 -1.69 -0.099 0.28785E+04 43 celadonite-Fe 3.88 1.09 -2.78 -0.164 0.47549E+04 44 chrysotile 23.89 21.58 -2.31 -0.193 0.39476E+04 49 chlorite-Al-free 47.17 43.16 -4.01 -0.167 0.68504E+04 51 chloritoid-Fe 9.17 5.04 -4.13 -0.275 0.70507E+04 52 chloritoid-Mn 11.40 7.53 -3.88 -0.258 0.66169E+04 54 coesite -2.38 -3.15 -0.78 -0.259 0.13277E+04 61 cristobalite -2.56 -3.15 -0.59 -0.198 0.10131E+04 63 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71234E+04 65 diaspore 2.87 0.73 -2.14 -0.357 0.36551E+04 66 diamond -3.10 -7.77 -4.67 -1.334 0.79726E+04 67 diopside 16.18 16.08 -0.11 -0.011 0.17959E+03 68 hedenbergite 14.21 13.51 -0.70 -0.070 0.11886E+04 71 enstatite 17.26 12.28 -4.98 -0.498 0.85039E+04 73 clinoenstatite 17.17 12.28 -4.88 -0.488 0.83355E+04 75 epidote 24.67 22.69 -1.98 -0.096 0.33727E+04 76 clinozoisite 22.81 18.91 -3.89 -0.177 0.66468E+04 77 epidote-Fe 29.84 26.48 -3.36 -0.175 0.57453E+04 78 fayalite 14.05 10.31 -3.74 -0.534 0.63784E+04 79 ferrosilite 11.15 7.16 -3.99 -0.399 0.68179E+04 83 gibbsite 4.08 0.73 -3.35 -0.478 0.57137E+04 84 glaucophane 22.97 20.81 -2.16 -0.058 0.36918E+04 85 glaucophane-Fe 17.28 13.12 -4.16 -0.112 0.70948E+04 86 graphite -3.55 -7.77 -4.23 -1.207 0.72149E+04 87 greenalite 16.14 13.89 -2.25 -0.188 0.38437E+04 90 hematite 12.57 9.03 -3.54 -0.429 0.60400E+04 91 heulandite -5.83 -7.52 -1.69 -0.077 0.28938E+04 95 jadeite 4.22 2.77 -1.45 -0.145 0.24681E+04 97 kalsilite 7.58 3.82 -3.76 -0.538 0.64253E+04 98 kaolinite -1.33 -4.84 -3.51 -0.319 0.59907E+04 101 laumontite 2.88 1.94 -0.94 -0.063 0.16126E+04 102 lawsonite 9.62 8.25 -1.37 -0.091 0.23388E+04 103 leucite 4.12 0.67 -3.45 -0.345 0.58937E+04 105 lizardite 23.24 21.58 -1.66 -0.139 0.28403E+04 107 magnetite 20.09 15.76 -4.33 -0.353 0.73877E+04 108 minnesotaite 10.39 7.58 -2.81 -0.165 0.47930E+04 112 manganosite 14.06 9.21 -4.84 -1.211 0.82722E+04 120 muscovite 2.58 -1.02 -3.60 -0.212 0.61518E+04 121 paragonite 4.24 1.08 -3.16 -0.186 0.53909E+04 122 nepheline 8.34 5.92 -2.42 -0.345 0.41252E+04 128 periclase-Fe 11.63 6.73 -4.89 -1.224 0.83575E+04 134 phlogopite-Na 29.65 27.50 -2.14 -0.119 0.36589E+04 136 prehnite 19.37 18.18 -1.19 -0.070 0.20347E+04 137 prehnite-Fe 22.50 21.96 -0.54 -0.032 0.91562E+03 138 pumpellyite-Fe 46.27 43.83 -2.44 -0.054 0.41731E+04 139 pumpellyite-Mg 48.99 46.39 -2.61 -0.058 0.44487E+04 143 pyrrhotite -4.26 -8.06 -3.80 -1.266 0.64861E+04 144 pyrrhotiteFe0.875 -6.02 -9.45 -3.43 -1.263 0.58625E+04 145 pyroxmangite 7.40 6.06 -1.34 -0.268 0.22862E+04 146 pyrophyllite -6.18 -11.15 -4.97 -0.311 0.84910E+04 147 quartz -2.99 -3.15 -0.16 -0.055 0.28043E+03 152 rhodonite 7.45 6.06 -1.39 -0.277 0.23664E+04 153 sanidine -1.28 -2.49 -1.21 -0.093 0.20677E+04 165 stilpnomelane-Mg 27.44 25.84 -1.60 -0.048 0.27394E+04 171 talc 16.49 15.27 -1.22 -0.072 0.20797E+04 174 tephroite 18.09 15.27 -2.81 -0.402 0.48025E+04 178 tridymite -2.63 -3.15 -0.53 -0.176 0.90041E+03 179 tremolite 47.87 47.43 -0.44 -0.012 0.75783E+03 180 ferroactinolite 38.45 34.61 -3.85 -0.104 0.65687E+04 181 troilite-low -4.41 -8.06 -3.65 -1.216 0.62289E+04 183 vesuvianite 223.47 218.55 -4.92 -0.038 0.83964E+04 187 wairakite 3.95 1.94 -2.01 -0.118 0.34346E+04 188 walstromite 11.51 9.93 -1.58 -0.315 0.26898E+04 189 wollastonite 10.46 9.93 -0.53 -0.105 0.90021E+03 190 pseudo-wollastonite 11.00 9.93 -1.07 -0.213 0.18200E+04 191 zoisite 22.85 18.91 -3.94 -0.179 0.67208E+04 192 akaganeite 7.75 4.51 -3.24 -0.701 0.55325E+04 199 chalcedony -2.80 -3.15 -0.35 -0.117 0.59973E+03 201 montmorillonite-Ca -2.29 -6.16 -3.87 -0.240 0.66125E+04 202 montmorillonite-K -2.24 -6.26 -4.03 -0.247 0.68751E+04 203 montmorillonite-Mg -2.48 -6.79 -4.31 -0.267 0.73578E+04 204 montmorillonite-Na -2.04 -5.57 -3.53 -0.216 0.60300E+04 205 nontronite-Ca 3.21 -0.14 -3.36 -0.218 0.57343E+04 206 nontronite-H 2.53 -2.30 -4.84 -0.324 0.82573E+04 207 nontronite-K 3.34 -0.24 -3.58 -0.230 0.61201E+04 208 nontronite-Mg 3.07 -0.77 -3.84 -0.249 0.65636E+04 209 nontronite-Na 3.52 0.45 -3.07 -0.197 0.52409E+04 224 tobermorite 9.82 7.75 -2.07 -0.566 0.35426E+04 230 alabandite -0.98 -5.58 -4.60 -1.533 0.78536E+04 233 boehmite 4.41 0.73 -3.67 -0.612 0.62720E+04 235 ferrous-oxide 9.81 6.73 -3.08 -0.770 0.52585E+04 240 silica-amorphous -2.09 -3.15 -1.06 -0.354 0.18139E+04 242 an20ab80 2.02 1.34 -0.68 -0.052 0.11536E+04 243 an25ab75 2.65 1.77 -0.87 -0.067 0.14889E+04 244 an30ab70 3.28 2.21 -1.07 -0.083 0.18339E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 4.0000000 g Current total amount of reactant added: 139.9990000 g New total amount of reactant added: 143.9990000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.7222E-13 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 11 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 143.9990000 Water: Moles liquid = 0.5462E+02 kg liquid = 0.9840E+00 Moles total = 0.5370E+02 kg total = 0.9675E+00 Activity = 1.0000 Stoichiometric ionic strength = .1128204E-01 Osmotic coef. = 0.9692 True ionic strength = .1994205E-01 Chg. balance for total moles = -.7222E-13 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.88856E-10 -10.0513 0.74679E-10 -10.1268 0.84045E+00 -0.0755 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13958E-03 -3.8552 0.11661E-03 -3.9333 0.83541E+00 -0.0781 4 SO4-- 0.94574E-12 -12.0242 0.49162E-12 -12.3084 0.51982E+00 -0.2841 5 HCO3- 0.34230E-06 -6.4656 0.28638E-06 -6.5431 0.83663E+00 -0.0775 6 HS- 0.25914E-04 -4.5865 0.21652E-04 -4.6645 0.83553E+00 -0.0780 7 Al+++ 0.97506E-29 -29.0110 0.22578E-29 -29.6463 0.23156E+00 -0.6353 8 H4SiO4 0.70096E-03 -3.1543 0.70096E-03 -3.1543 0.10000E+01 0.0000 9 Ca++ 0.13293E-06 -6.8764 0.68597E-07 -7.1637 0.51602E+00 -0.2873 10 Mg++ 0.21449E-10 -10.6686 0.11018E-10 -10.9579 0.51367E+00 -0.2893 11 Fe++ 0.58567E-13 -13.2323 0.30117E-13 -13.5212 0.51423E+00 -0.2888 12 K+ 0.15592E-03 -3.8071 0.13048E-03 -3.8845 0.83683E+00 -0.0774 13 Na+ 0.19785E-01 -1.7037 0.16526E-01 -1.7818 0.83526E+00 -0.0782 14 Mn++ 0.17757E-10 -10.7506 0.91386E-11 -11.0391 0.51465E+00 -0.2885 15 HPO4-- 0.46774E-07 -7.3300 0.24318E-07 -7.6141 0.51990E+00 -0.2841 16 HSiO3- 0.10491E-01 -1.9792 0.87644E-02 -2.0573 0.83541E+00 -0.0781 17 Ca(HSiO3)+ 0.16358E-07 -7.7863 0.13692E-07 -7.8635 0.83701E+00 -0.0773 18 Mg(HSiO3)+ 0.32698E-11 -11.4855 0.27368E-11 -11.5628 0.83701E+00 -0.0773 19 NaHSiO3,aq 0.23425E-02 -2.6303 0.23425E-02 -2.6303 0.10000E+01 0.0000 20 AlO+ 0.65803E-16 -16.1818 0.55077E-16 -16.2590 0.83701E+00 -0.0773 22 HAlO2,aq 0.14688E-09 -9.8331 0.14688E-09 -9.8331 0.10000E+01 0.0000 23 AlO2- 0.52207E-05 -5.2823 0.43536E-05 -5.3612 0.83391E+00 -0.0789 24 CH4,aq 0.12294E-04 -4.9103 0.12252E-04 -4.9118 0.99656E+00 -0.0015 25 C2H6,aq 0.24386E-14 -14.6129 0.24302E-14 -14.6144 0.99656E+00 -0.0015 29 CO,aq 0.12122E-16 -16.9164 0.12122E-16 -16.9164 0.10000E+01 0.0000 30 CO2,aq 0.45856E-10 -10.3386 0.45698E-10 -10.3401 0.99656E+00 -0.0015 31 CO3-2 0.64572E-06 -6.1900 0.33495E-06 -6.4750 0.51872E+00 -0.2851 32 CaCO3,aq 0.28810E-09 -9.5405 0.28810E-09 -9.5405 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.59910E-12 -12.2225 0.50145E-12 -12.2998 0.83701E+00 -0.0773 34 CaCl+ 0.15465E-10 -10.8106 0.12945E-10 -10.8879 0.83701E+00 -0.0773 35 CaCl2,aq 0.35861E-15 -15.4454 0.35861E-15 -15.4454 0.10000E+01 0.0000 36 CaOH+ 0.78213E-07 -7.1067 0.65465E-07 -7.1840 0.83701E+00 -0.0773 37 CaSO4,aq 0.10709E-16 -16.9703 0.10709E-16 -16.9703 0.10000E+01 0.0000 38 HCl,aq 0.15957E-14 -14.7970 0.15957E-14 -14.7970 0.10000E+01 0.0000 43 FeCl+ 0.66411E-17 -17.1778 0.55587E-17 -17.2550 0.83701E+00 -0.0773 46 FeO,aq 0.20988E-09 -9.6780 0.20988E-09 -9.6780 0.10000E+01 0.0000 47 FeOH+ 0.15684E-10 -10.8046 0.13127E-10 -10.8818 0.83701E+00 -0.0773 48 HFeO2- 0.35200E-07 -7.4535 0.29406E-07 -7.5316 0.83541E+00 -0.0781 49 FeO+ 0.11512E-16 -16.9389 0.96356E-17 -17.0161 0.83701E+00 -0.0773 51 FeO2- 0.42318E-09 -9.3735 0.35353E-09 -9.4516 0.83541E+00 -0.0781 52 HFeO2,aq 0.33579E-11 -11.4739 0.33579E-11 -11.4739 0.10000E+01 0.0000 53 H2,aq 0.10596E-04 -4.9749 0.10560E-04 -4.9763 0.99656E+00 -0.0015 54 KCl,aq 0.27575E-09 -9.5595 0.27575E-09 -9.5595 0.10000E+01 0.0000 56 KOH,aq 0.74613E-06 -6.1272 0.74613E-06 -6.1272 0.10000E+01 0.0000 57 KSO4- 0.11915E-14 -14.9239 0.99536E-15 -15.0020 0.83541E+00 -0.0781 58 MgCO3,aq 0.11599E-13 -13.9356 0.11599E-13 -13.9356 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.98323E-16 -16.0073 0.82297E-16 -16.0846 0.83701E+00 -0.0773 60 MgCl+ 0.22513E-14 -14.6476 0.18844E-14 -14.7248 0.83701E+00 -0.0773 61 MgOH+ 0.69513E-10 -10.1579 0.58183E-10 -10.2352 0.83701E+00 -0.0773 63 MnO,aq 0.16970E-08 -8.7703 0.16970E-08 -8.7703 0.10000E+01 0.0000 64 MnOH+ 0.44210E-09 -9.3545 0.37004E-09 -9.4318 0.83701E+00 -0.0773 65 MnO2-2 0.19468E-10 -10.7107 0.10098E-10 -10.9958 0.51872E+00 -0.2851 66 HMnO2- 0.19777E-09 -9.7038 0.16522E-09 -9.7819 0.83541E+00 -0.0781 69 MnCl+ 0.78399E-14 -14.1057 0.65620E-14 -14.1830 0.83701E+00 -0.0773 71 NaCl,aq 0.63861E-06 -6.1948 0.63861E-06 -6.1948 0.10000E+01 0.0000 72 NaOH,aq 0.95076E-04 -4.0219 0.95076E-04 -4.0219 0.10000E+01 0.0000 74 OH- 0.92777E-02 -2.0326 0.77368E-02 -2.1114 0.83391E+00 -0.0789 79 HPO3-2 0.15427E-14 -14.8117 0.80025E-15 -15.0968 0.51872E+00 -0.2851 81 H2PO3- 0.14345E-18 -18.8433 0.11984E-18 -18.9214 0.83541E+00 -0.0781 82 H3PO4,aq 0.94852E-18 -18.0230 0.94852E-18 -18.0230 0.10000E+01 0.0000 83 H2PO4- 0.40063E-10 -10.3973 0.33501E-10 -10.4749 0.83620E+00 -0.0777 84 PO4-3 0.10926E-08 -8.9615 0.26568E-09 -9.5756 0.24317E+00 -0.6141 88 HP2O7-3 0.10151E-17 -17.9935 0.23530E-18 -18.6284 0.23179E+00 -0.6349 89 P2O7-4 0.97231E-17 -17.0122 0.75271E-18 -18.1234 0.77414E-01 -1.1112 90 H2S,aq 0.50147E-08 -8.2998 0.49975E-08 -8.3013 0.99656E+00 -0.0015 91 S2-2 0.18965E-14 -14.7220 0.98376E-15 -15.0071 0.51872E+00 -0.2851 97 SO3-2 0.12820E-17 -17.8921 0.67461E-18 -18.1709 0.52620E+00 -0.2788 99 HSO4- 0.42230E-19 -19.3744 0.35381E-19 -19.4512 0.83782E+00 -0.0768 Charge balance for all species = -.7454E-13 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.8885597E-10 -.2223147E-01 -.2236912E+02 0.0000 2 H2O 0.1000000E+01 0.5550482E+02 0.9982018E+06 0.0000 3 Cl- 0.1395799E-03 0.1402188E-03 0.4962556E+01 6.1935 4 SO4-- 0.9457365E-12 -.1494327E-04 -.1432984E+01 7.9452 5 HCO3- 0.3422985E-06 0.1328263E-04 0.8090632E+00 3.5837 6 HS- 0.2591438E-04 0.4086266E-04 0.1349066E+01 5.4623 7 Al+++ 0.9750591E-29 0.5220833E-05 0.1406216E+00 0.7341 8 H4SiO4 0.7009582E-03 0.1353454E-01 0.1298622E+04 -3.1543 9 Ca++ 0.1329346E-06 0.2278100E-06 0.9114335E-02 13.0899 10 Mg++ 0.2144906E-10 0.9424561E-10 0.2287325E-05 9.2957 11 Fe++ 0.5856740E-13 0.3585192E-07 0.1998750E-02 6.7324 12 K+ 0.1559168E-03 0.1566632E-03 0.6115221E+01 6.2423 13 Na+ 0.1978494E-01 0.2222318E-01 0.5100204E+03 8.3450 14 Mn++ 0.1775683E-10 0.2374068E-08 0.1302003E-03 9.2145 15 HPO4-- 0.4677444E-07 0.4790708E-07 0.4590099E-02 12.6395 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.2384397E+01 -.2187558E-01 -.2362521E+01 0.0000000E+00 2 H2O 0.5370316E+02 0.5461629E+02 -.9131310E+00 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.4016208E-02 -.1470405E-04 0.4030912E-02 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.3990703E-02 0.4020852E-04 -.4030912E-02 0.0000000E+00 7 Al+++ 0.4695435E+00 0.5137257E-05 0.4695384E+00 0.0000000E+00 8 H4SiO4 0.1499430E+01 0.1331788E-01 0.1486112E+01 0.0000000E+00 9 Ca++ 0.1656339E+00 0.2241632E-06 0.1656336E+00 0.0000000E+00 10 Mg++ 0.1142849E+00 0.9273692E-10 0.1142849E+00 0.0000000E+00 11 Fe++ 0.1026725E+00 0.3527800E-07 0.1026725E+00 0.0000000E+00 12 K+ 0.3057304E-01 0.1541553E-03 0.3041888E-01 0.0000000E+00 13 Na+ 0.1809139E+00 0.2186743E-01 0.1590465E+00 0.0000000E+00 14 Mn++ 0.2496740E-02 0.2336064E-08 0.2496738E-02 0.0000000E+00 15 HPO4-- 0.8521251E-03 0.4714018E-07 0.8520780E-03 0.0000000E+00 Chg. balance for solid moles: 0.3257E-15 Mass of aqueous solution: 0.985701E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 143.9990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 0.1589 -0.799 41.66 1.620 26.51 15.99 andradite 0.1612E-01 -1.793 8.194 0.913 5.214 2.129 grossular 0.3708E-02 -2.431 1.670 0.223 1.063 0.4647 apatite-OH 0.2840E-03 -3.547 0.1427 -0.846 0.9079E-01 0.4534E-01 clinochlore 0.2185E-01 -1.661 12.14 1.084 7.728 4.619 daphnite 0.6266E-02 -2.203 4.471 0.650 2.845 1.355 chlorite-Mn 0.4993E-03 -3.302 0.3540 -0.451 0.2253 0.1128 microcline 0.2668E-01 -1.574 7.427 0.871 4.726 2.901 stilbite 0.1019 -0.992 71.84 1.856 45.71 33.51 stilpnomelane-Fe 0.7471E-02 -2.127 8.054 0.906 5.125 2.782 tr.625ac.25prg.125 0.1391E-02 -2.857 1.189 0.075 0.7565 0.3826 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8130E+00 0.8130E+00 1.0000 -0.090 grossular 0.1870E+00 0.1870E+00 1.0000 -0.728 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.7636E+00 0.7636E+00 1.0000 -0.117 daphnite 0.2190E+00 0.2190E+00 1.0000 -0.660 chlorite-Mn 0.1745E-01 0.1745E-01 1.0000 -1.758 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 tr.625ac.25prg.125 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 157.142094 g Volume = 64.289864 cm3 Porosity: -9.7104% V(tot) - V(min): -.56903E+01 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 143.9990000 g log = 2.1584 Original solution: 1000.0103000 g Original solution / Rock added: 6.94 (Water/Rock Ratio), log = 0.8416 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0524 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9699E+00 0.9855 0.1006E+01 0.1021E+01 CO2,gas 0.4614E-08 1.0069 0.4889E-08 0.4855E-08 CH4,gas 0.1693E-01 1.0125 0.1803E-01 0.1781E-01 H2,gas 0.1317E-01 1.0006 0.1386E-01 0.1386E-01 H2S,gas 0.1311E-06 0.9959 0.1374E-06 0.1379E-06 S2,gas 0.3502E-29 1.0000 0.3686E-29 0.3686E-29 CO,gas 0.1716E-13 1.0000 0.1806E-13 0.1806E-13 SO3,gas 0.9850E-48 1.0000 0.1037E-47 0.1037E-47 SO2,gas 0.5313E-27 1.0000 0.5591E-27 0.5591E-27 HCl,gas 0.2675E-17 1.0000 0.2816E-17 0.2816E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 16 albite -0.38 -0.38 0.00 0.000 -0.94784E-12 22 andradite 39.01 39.01 0.00 0.000 -0.24265E-10 23 grossular 32.73 32.73 0.00 0.000 0.24265E-10 32 apatite-OH -18.15 -18.15 0.00 0.000 -0.60662E-11 46 clinochlore 39.07 39.07 0.00 0.000 -0.36397E-10 47 daphnite 28.97 28.97 0.00 0.000 -0.24265E-10 48 chlorite-Mn 46.87 46.87 0.00 0.000 -0.24265E-10 116 microcline -2.49 -2.49 0.00 0.000 0.15165E-11 163 stilbite -7.52 -7.52 0.00 0.000 -0.90992E-11 164 stilpnomelane-Fe 13.02 13.02 0.00 0.000 0.21232E-10 245 tr.625ac.25prg.125 45.16 45.16 0.00 0.000 0.60662E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -16.67 -10.01 -3.337 0.17091E+05 -8.311 3 CH4,gas 4.54 1.10 -3.44 -0.861 0.58786E+04 -1.744 4 H2,gas 8.00 4.44 -3.56 -2.033 0.60736E+04 -1.858 5 H2S,gas -6.23 -14.79 -8.56 -4.281 0.14618E+05 -6.862 6 S2,gas -7.34 -38.47 -31.13 -4.790 0.53158E+05 -29.433 7 CO,gas 3.21 -12.23 -15.44 -4.751 0.26367E+05 -13.743 8 SO3,gas 17.12 -32.56 -49.68 -12.421 0.84833E+05 -47.984 9 SO2,gas 0.83 -28.12 -28.95 -7.720 0.49434E+05 -27.252 10 HCl,gas 5.19 -14.06 -19.25 -9.625 0.32868E+05 -17.550 11 acmite 7.71 6.55 -1.16 -0.121 0.19846E+04 15 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 19 spessartine 24.46 19.65 -4.81 -0.240 0.82106E+04 20 analcite 3.32 2.77 -0.55 -0.061 0.94154E+03 26 annite 20.12 17.71 -2.41 -0.134 0.41195E+04 27 phlogopite 27.06 25.40 -1.66 -0.092 0.28412E+04 29 anorthite 12.71 8.25 -4.46 -0.343 0.76167E+04 35 aragonite 0.97 -3.58 -4.55 -1.515 0.77630E+04 36 brucite 12.57 9.30 -3.27 -0.655 0.55883E+04 37 calcite 0.81 -3.58 -4.39 -1.464 0.74988E+04 38 carnegieite-low 9.02 5.92 -3.10 -0.443 0.52907E+04 39 carnegieite-high 10.09 5.92 -4.17 -0.596 0.71177E+04 40 carpholite-Mg 8.58 4.46 -4.13 -0.275 0.70464E+04 41 carpholite-Fe 6.71 1.89 -4.82 -0.321 0.82311E+04 42 celadonite 5.34 3.65 -1.69 -0.099 0.28800E+04 43 celadonite-Fe 3.88 1.09 -2.78 -0.164 0.47552E+04 44 chrysotile 23.89 21.58 -2.31 -0.193 0.39510E+04 49 chlorite-Al-free 47.17 43.16 -4.02 -0.167 0.68571E+04 51 chloritoid-Fe 9.17 5.05 -4.13 -0.275 0.70473E+04 52 chloritoid-Mn 11.40 7.53 -3.87 -0.258 0.66125E+04 54 coesite -2.38 -3.15 -0.78 -0.259 0.13288E+04 61 cristobalite -2.56 -3.15 -0.59 -0.198 0.10142E+04 63 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71234E+04 65 diaspore 2.87 0.73 -2.14 -0.357 0.36533E+04 66 diamond -3.10 -7.78 -4.68 -1.338 0.79946E+04 67 diopside 16.18 16.08 -0.10 -0.010 0.17821E+03 68 hedenbergite 14.21 13.51 -0.69 -0.069 0.11860E+04 71 enstatite 17.26 12.28 -4.98 -0.498 0.85069E+04 73 clinoenstatite 17.17 12.28 -4.88 -0.488 0.83385E+04 75 epidote 24.67 22.70 -1.97 -0.096 0.33701E+04 76 clinozoisite 22.81 18.92 -3.89 -0.177 0.66367E+04 77 epidote-Fe 29.84 26.47 -3.37 -0.175 0.57502E+04 78 fayalite 14.05 10.31 -3.74 -0.534 0.63778E+04 79 ferrosilite 11.15 7.16 -3.99 -0.399 0.68184E+04 83 gibbsite 4.08 0.73 -3.35 -0.478 0.57119E+04 84 glaucophane 22.97 20.81 -2.16 -0.058 0.36951E+04 85 glaucophane-Fe 17.28 13.12 -4.15 -0.112 0.70944E+04 86 graphite -3.55 -7.78 -4.24 -1.211 0.72369E+04 87 greenalite 16.14 13.89 -2.25 -0.188 0.38433E+04 90 hematite 12.57 9.02 -3.54 -0.430 0.60513E+04 91 heulandite -5.83 -7.52 -1.69 -0.077 0.28938E+04 95 jadeite 4.22 2.77 -1.44 -0.144 0.24670E+04 97 kalsilite 7.58 3.82 -3.76 -0.537 0.64231E+04 98 kaolinite -1.33 -4.84 -3.51 -0.319 0.59892E+04 101 laumontite 2.88 1.94 -0.94 -0.063 0.16094E+04 102 lawsonite 9.62 8.25 -1.37 -0.091 0.23334E+04 103 leucite 4.12 0.67 -3.45 -0.345 0.58926E+04 105 lizardite 23.24 21.58 -1.67 -0.139 0.28436E+04 107 magnetite 20.09 15.75 -4.33 -0.354 0.73982E+04 108 minnesotaite 10.39 7.58 -2.81 -0.165 0.47947E+04 112 manganosite 14.06 9.21 -4.84 -1.211 0.82704E+04 120 muscovite 2.58 -1.02 -3.60 -0.212 0.61481E+04 121 paragonite 4.24 1.08 -3.16 -0.186 0.53873E+04 122 nepheline 8.34 5.92 -2.41 -0.345 0.41230E+04 128 periclase-Fe 11.63 6.73 -4.89 -1.224 0.83567E+04 134 phlogopite-Na 29.65 27.50 -2.14 -0.119 0.36601E+04 136 prehnite 19.37 18.19 -1.19 -0.070 0.20264E+04 137 prehnite-Fe 22.50 21.96 -0.54 -0.032 0.91485E+03 138 pumpellyite-Fe 46.27 43.84 -2.43 -0.054 0.41538E+04 139 pumpellyite-Mg 48.99 46.40 -2.59 -0.058 0.44307E+04 143 pyrrhotite -4.26 -8.06 -3.80 -1.266 0.64859E+04 144 pyrrhotiteFe0.875 -6.02 -9.45 -3.43 -1.263 0.58641E+04 145 pyroxmangite 7.40 6.06 -1.34 -0.268 0.22855E+04 146 pyrophyllite -6.18 -11.15 -4.97 -0.311 0.84917E+04 147 quartz -2.99 -3.15 -0.16 -0.055 0.28152E+03 152 rhodonite 7.45 6.06 -1.39 -0.277 0.23657E+04 153 sanidine -1.28 -2.49 -1.21 -0.093 0.20677E+04 165 stilpnomelane-Mg 27.44 25.83 -1.61 -0.048 0.27457E+04 171 talc 16.49 15.27 -1.22 -0.072 0.20852E+04 174 tephroite 18.09 15.27 -2.81 -0.402 0.47999E+04 178 tridymite -2.63 -3.15 -0.53 -0.176 0.90149E+03 179 tremolite 47.87 47.42 -0.45 -0.012 0.76057E+03 180 ferroactinolite 38.45 34.61 -3.84 -0.104 0.65651E+04 181 troilite-low -4.41 -8.06 -3.65 -1.216 0.62287E+04 183 vesuvianite 223.47 218.60 -4.87 -0.037 0.83219E+04 187 wairakite 3.95 1.94 -2.01 -0.118 0.34313E+04 188 walstromite 11.51 9.94 -1.57 -0.315 0.26869E+04 189 wollastonite 10.46 9.94 -0.53 -0.105 0.89736E+03 190 pseudo-wollastonite 11.00 9.94 -1.06 -0.213 0.18172E+04 191 zoisite 22.85 18.92 -3.93 -0.179 0.67107E+04 192 akaganeite 7.75 4.51 -3.24 -0.701 0.55382E+04 199 chalcedony -2.80 -3.15 -0.35 -0.117 0.60081E+03 201 montmorillonite-Ca -2.29 -6.16 -3.87 -0.240 0.66133E+04 202 montmorillonite-K -2.24 -6.26 -4.03 -0.247 0.68760E+04 203 montmorillonite-Mg -2.48 -6.79 -4.31 -0.267 0.73593E+04 204 montmorillonite-Na -2.04 -5.57 -3.53 -0.216 0.60309E+04 205 nontronite-Ca 3.21 -0.15 -3.37 -0.218 0.57484E+04 206 nontronite-H 2.53 -2.31 -4.84 -0.325 0.82720E+04 207 nontronite-K 3.34 -0.25 -3.59 -0.231 0.61343E+04 208 nontronite-Mg 3.07 -0.78 -3.85 -0.250 0.65784E+04 209 nontronite-Na 3.52 0.44 -3.08 -0.198 0.52552E+04 224 tobermorite 9.82 7.75 -2.07 -0.566 0.35404E+04 230 alabandite -0.98 -5.58 -4.60 -1.533 0.78526E+04 233 boehmite 4.41 0.73 -3.67 -0.612 0.62702E+04 235 ferrous-oxide 9.81 6.73 -3.08 -0.770 0.52576E+04 240 silica-amorphous -2.09 -3.15 -1.06 -0.354 0.18150E+04 242 an20ab80 2.02 1.34 -0.67 -0.052 0.11525E+04 243 an25ab75 2.65 1.77 -0.87 -0.067 0.14876E+04 244 an30ab70 3.28 2.21 -1.07 -0.083 0.18323E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 4.0000000 g Current total amount of reactant added: 143.9990000 g New total amount of reactant added: 147.9990000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.7247E-13 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 11 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 147.9990000 Water: Moles liquid = 0.5460E+02 kg liquid = 0.9836E+00 Moles total = 0.5365E+02 kg total = 0.9666E+00 Activity = 1.0000 Stoichiometric ionic strength = .1128834E-01 Osmotic coef. = 0.9693 True ionic strength = .1995351E-01 Chg. balance for total moles = -.7247E-13 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.88746E-10 -10.0518 0.74584E-10 -10.1274 0.84042E+00 -0.0755 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13964E-03 -3.8550 0.11665E-03 -3.9331 0.83538E+00 -0.0781 4 SO4-- 0.88653E-12 -12.0523 0.46077E-12 -12.3365 0.51975E+00 -0.2842 5 HCO3- 0.32234E-06 -6.4917 0.26967E-06 -6.5692 0.83660E+00 -0.0775 6 HS- 0.25925E-04 -4.5863 0.21660E-04 -4.6643 0.83550E+00 -0.0781 7 Al+++ 0.97393E-29 -29.0115 0.22544E-29 -29.6470 0.23148E+00 -0.6355 8 H4SiO4 0.70000E-03 -3.1549 0.70000E-03 -3.1549 0.10000E+01 0.0000 9 Ca++ 0.13328E-06 -6.8752 0.68765E-07 -7.1626 0.51594E+00 -0.2874 10 Mg++ 0.21387E-10 -10.6698 0.10984E-10 -10.9592 0.51359E+00 -0.2894 11 Fe++ 0.58492E-13 -13.2329 0.30073E-13 -13.5218 0.51415E+00 -0.2889 12 K+ 0.15601E-03 -3.8069 0.13055E-03 -3.8842 0.83680E+00 -0.0774 13 Na+ 0.19796E-01 -1.7034 0.16534E-01 -1.7816 0.83523E+00 -0.0782 14 Mn++ 0.17755E-10 -10.7507 0.91365E-11 -11.0392 0.51457E+00 -0.2886 15 HPO4-- 0.46512E-07 -7.3324 0.24178E-07 -7.6166 0.51982E+00 -0.2841 16 HSiO3- 0.10490E-01 -1.9792 0.87635E-02 -2.0573 0.83538E+00 -0.0781 17 Ca(HSiO3)+ 0.16397E-07 -7.7852 0.13724E-07 -7.8625 0.83698E+00 -0.0773 18 Mg(HSiO3)+ 0.32596E-11 -11.4868 0.27282E-11 -11.5641 0.83698E+00 -0.0773 19 NaHSiO3,aq 0.23435E-02 -2.6301 0.23435E-02 -2.6301 0.10000E+01 0.0000 20 AlO+ 0.65873E-16 -16.1813 0.55134E-16 -16.2586 0.83698E+00 -0.0773 22 HAlO2,aq 0.14721E-09 -9.8320 0.14721E-09 -9.8320 0.10000E+01 0.0000 23 AlO2- 0.52396E-05 -5.2807 0.43692E-05 -5.3596 0.83388E+00 -0.0789 24 CH4,aq 0.12356E-04 -4.9081 0.12314E-04 -4.9096 0.99656E+00 -0.0015 25 C2H6,aq 0.24227E-14 -14.6157 0.24144E-14 -14.6172 0.99656E+00 -0.0015 29 CO,aq 0.11591E-16 -16.9359 0.11591E-16 -16.9359 0.10000E+01 0.0000 30 CO2,aq 0.43125E-10 -10.3653 0.42976E-10 -10.3668 0.99656E+00 -0.0015 31 CO3-2 0.60891E-06 -6.2154 0.31581E-06 -6.5006 0.51865E+00 -0.2851 32 CaCO3,aq 0.27230E-09 -9.5649 0.27230E-09 -9.5649 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.56554E-12 -12.2475 0.47335E-12 -12.3248 0.83698E+00 -0.0773 34 CaCl+ 0.15510E-10 -10.8094 0.12981E-10 -10.8867 0.83698E+00 -0.0773 35 CaCl2,aq 0.35975E-15 -15.4440 0.35975E-15 -15.4440 0.10000E+01 0.0000 36 CaOH+ 0.78508E-07 -7.1051 0.65709E-07 -7.1824 0.83698E+00 -0.0773 37 CaSO4,aq 0.10061E-16 -16.9973 0.10061E-16 -16.9973 0.10000E+01 0.0000 38 HCl,aq 0.15943E-14 -14.7974 0.15943E-14 -14.7974 0.10000E+01 0.0000 43 FeCl+ 0.66342E-17 -17.1782 0.55526E-17 -17.2555 0.83698E+00 -0.0773 46 FeO,aq 0.21011E-09 -9.6775 0.21011E-09 -9.6775 0.10000E+01 0.0000 47 FeOH+ 0.15681E-10 -10.8046 0.13125E-10 -10.8819 0.83698E+00 -0.0773 48 HFeO2- 0.35284E-07 -7.4524 0.29476E-07 -7.5305 0.83538E+00 -0.0781 49 FeO+ 0.11415E-16 -16.9425 0.95541E-17 -17.0198 0.83698E+00 -0.0773 51 FeO2- 0.42069E-09 -9.3760 0.35144E-09 -9.4542 0.83538E+00 -0.0781 52 HFeO2,aq 0.33337E-11 -11.4771 0.33337E-11 -11.4771 0.10000E+01 0.0000 53 H2,aq 0.10774E-04 -4.9676 0.10737E-04 -4.9691 0.99656E+00 -0.0015 54 KCl,aq 0.27600E-09 -9.5591 0.27600E-09 -9.5591 0.10000E+01 0.0000 56 KOH,aq 0.74748E-06 -6.1264 0.74748E-06 -6.1264 0.10000E+01 0.0000 57 KSO4- 0.11173E-14 -14.9518 0.93341E-15 -15.0299 0.83538E+00 -0.0781 58 MgCO3,aq 0.10903E-13 -13.9625 0.10903E-13 -13.9625 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.92308E-16 -16.0348 0.77260E-16 -16.1120 0.83698E+00 -0.0773 60 MgCl+ 0.22454E-14 -14.6487 0.18794E-14 -14.7260 0.83698E+00 -0.0773 61 MgOH+ 0.69393E-10 -10.1587 0.58080E-10 -10.2360 0.83698E+00 -0.0773 63 MnO,aq 0.17009E-08 -8.7693 0.17009E-08 -8.7693 0.10000E+01 0.0000 64 MnOH+ 0.44257E-09 -9.3540 0.37042E-09 -9.4313 0.83698E+00 -0.0773 65 MnO2-2 0.19565E-10 -10.7085 0.10147E-10 -10.9936 0.51865E+00 -0.2851 66 HMnO2- 0.19848E-09 -9.7023 0.16581E-09 -9.7804 0.83538E+00 -0.0781 69 MnCl+ 0.78412E-14 -14.1056 0.65629E-14 -14.1829 0.83698E+00 -0.0773 71 NaCl,aq 0.63919E-06 -6.1944 0.63919E-06 -6.1944 0.10000E+01 0.0000 72 NaOH,aq 0.95248E-04 -4.0211 0.95248E-04 -4.0211 0.10000E+01 0.0000 74 OH- 0.92899E-02 -2.0320 0.77466E-02 -2.1109 0.83388E+00 -0.0789 79 HPO3-2 0.15598E-14 -14.8069 0.80897E-15 -15.0921 0.51865E+00 -0.2851 81 H2PO3- 0.14483E-18 -18.8391 0.12099E-18 -18.9172 0.83538E+00 -0.0781 82 H3PO4,aq 0.94067E-18 -18.0266 0.94067E-18 -18.0266 0.10000E+01 0.0000 83 H2PO4- 0.39784E-10 -10.4003 0.33266E-10 -10.4780 0.83617E+00 -0.0777 84 PO4-3 0.10880E-08 -8.9634 0.26449E-09 -9.5776 0.24309E+00 -0.6142 88 HP2O7-3 0.10025E-17 -17.9989 0.23230E-18 -18.6340 0.23171E+00 -0.6351 89 P2O7-4 0.96172E-17 -17.0169 0.74407E-18 -18.1284 0.77368E-01 -1.1114 90 H2S,aq 0.50102E-08 -8.3001 0.49930E-08 -8.3016 0.99656E+00 -0.0015 91 S2-2 0.18669E-14 -14.7289 0.96827E-15 -15.0140 0.51865E+00 -0.2851 97 SO3-2 0.12219E-17 -17.9130 0.64287E-18 -18.1919 0.52613E+00 -0.2789 99 HSO4- 0.39532E-19 -19.4031 0.33119E-19 -19.4799 0.83779E+00 -0.0769 Charge balance for all species = -.7480E-13 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.8874629E-10 -.2224425E-01 -.2238197E+02 0.0000 2 H2O 0.1000000E+01 0.5550484E+02 0.9982015E+06 0.0000 3 Cl- 0.1396363E-03 0.1402758E-03 0.4964571E+01 6.1942 4 SO4-- 0.8865289E-12 -.1504983E-04 -.1443203E+01 7.9182 5 HCO3- 0.3223368E-06 0.1328803E-04 0.8093917E+00 3.5582 6 HS- 0.2592491E-04 0.4097976E-04 0.1352931E+01 5.4630 7 Al+++ 0.9739267E-29 0.5239756E-05 0.1411312E+00 0.7351 8 H4SiO4 0.6999970E-03 0.1353395E-01 0.1298564E+04 -3.1549 9 Ca++ 0.1332808E-06 0.2284738E-06 0.9140889E-02 13.0921 10 Mg++ 0.2138730E-10 0.9405286E-10 0.2282646E-05 9.2955 11 Fe++ 0.5849156E-13 0.3593425E-07 0.2003338E-02 6.7329 12 K+ 0.1560066E-03 0.1567543E-03 0.6118775E+01 6.2431 13 Na+ 0.1979635E-01 0.2223578E-01 0.5103094E+03 8.3457 14 Mn++ 0.1775543E-10 0.2379278E-08 0.1304860E-03 9.2155 15 HPO4-- 0.4651210E-07 0.4763990E-07 0.4564498E-02 12.6381 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.2450631E+01 -.2187927E-01 -.2428751E+01 0.0000000E+00 2 H2O 0.5365302E+02 0.5459412E+02 -.9410966E+00 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.4127061E-02 -.1480290E-04 0.4141864E-02 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.4101557E-02 0.4030737E-04 -.4141864E-02 0.0000000E+00 7 Al+++ 0.4825865E+00 0.5153782E-05 0.4825813E+00 0.0000000E+00 8 H4SiO4 0.1541081E+01 0.1331188E-01 0.1527770E+01 0.0000000E+00 9 Ca++ 0.1702344E+00 0.2247251E-06 0.1702342E+00 0.0000000E+00 10 Mg++ 0.1174595E+00 0.9250965E-10 0.1174595E+00 0.0000000E+00 11 Fe++ 0.1055246E+00 0.3534464E-07 0.1055245E+00 0.0000000E+00 12 K+ 0.3142229E-01 0.1541823E-03 0.3126811E-01 0.0000000E+00 13 Na+ 0.1859349E+00 0.2187094E-01 0.1640639E+00 0.0000000E+00 14 Mn++ 0.2566095E-02 0.2340239E-08 0.2566093E-02 0.0000000E+00 15 HPO4-- 0.8757954E-03 0.4685823E-07 0.8757486E-03 0.0000000E+00 Chg. balance for solid moles: -.5200E-15 Mass of aqueous solution: 0.985301E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 147.9990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 0.1639 -0.785 42.97 1.633 26.61 16.50 andradite 0.1657E-01 -1.781 8.419 0.925 5.213 2.187 grossular 0.3847E-02 -2.415 1.733 0.239 1.073 0.4821 apatite-OH 0.2919E-03 -3.535 0.1466 -0.834 0.9079E-01 0.4660E-01 clinochlore 0.2239E-01 -1.650 12.45 1.095 7.706 4.734 daphnite 0.6432E-02 -2.192 4.590 0.662 2.842 1.391 chlorite-Mn 0.5132E-03 -3.290 0.3639 -0.439 0.2253 0.1160 microcline 0.2743E-01 -1.562 7.636 0.883 4.728 2.983 stilbite 0.1045 -0.981 73.64 1.867 45.60 34.35 stilpnomelane-Fe 0.7666E-02 -2.115 8.264 0.917 5.117 2.855 tr.625ac.25prg.125 0.1516E-02 -2.819 1.296 0.113 0.8024 0.4171 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8116E+00 0.8116E+00 1.0000 -0.091 grossular 0.1884E+00 0.1884E+00 1.0000 -0.725 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.7633E+00 0.7633E+00 1.0000 -0.117 daphnite 0.2192E+00 0.2192E+00 1.0000 -0.659 chlorite-Mn 0.1749E-01 0.1749E-01 1.0000 -1.757 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 tr.625ac.25prg.125 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 161.509732 g Volume = 66.056148 cm3 Porosity: -9.7286% V(tot) - V(min): -.58565E+01 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 147.9990000 g log = 2.1703 Original solution: 1000.0103000 g Original solution / Rock added: 6.76 (Water/Rock Ratio), log = 0.8297 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0527 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9696E+00 0.9855 0.1006E+01 0.1021E+01 CO2,gas 0.4338E-08 1.0069 0.4598E-08 0.4566E-08 CH4,gas 0.1701E-01 1.0125 0.1813E-01 0.1790E-01 H2,gas 0.1338E-01 1.0006 0.1410E-01 0.1409E-01 H2S,gas 0.1309E-06 0.9959 0.1373E-06 0.1378E-06 S2,gas 0.3381E-29 1.0000 0.3559E-29 0.3559E-29 CO,gas 0.1641E-13 1.0000 0.1727E-13 0.1727E-13 SO3,gas 0.9206E-48 1.0000 0.9691E-48 0.9691E-48 SO2,gas 0.5049E-27 1.0000 0.5315E-27 0.5315E-27 HCl,gas 0.2672E-17 1.0000 0.2813E-17 0.2813E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 16 albite -0.38 -0.38 0.00 0.000 -0.94784E-12 22 andradite 39.01 39.01 0.00 0.000 0.12132E-10 23 grossular 32.73 32.73 0.00 0.000 -0.12132E-10 32 apatite-OH -18.15 -18.15 0.00 0.000 -0.60662E-11 46 clinochlore 39.07 39.07 0.00 0.000 0.24265E-10 47 daphnite 28.97 28.97 0.00 0.000 -0.24265E-10 48 chlorite-Mn 46.87 46.87 0.00 0.000 0.00000E+00 116 microcline -2.49 -2.49 0.00 0.000 0.15165E-11 163 stilbite -7.52 -7.52 0.00 0.000 -0.90992E-11 164 stilpnomelane-Fe 13.02 13.02 0.00 0.000 0.69761E-10 245 tr.625ac.25prg.125 45.16 45.16 0.00 0.000 0.36397E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -16.70 -10.04 -3.345 0.17137E+05 -8.337 3 CH4,gas 4.54 1.10 -3.44 -0.860 0.58749E+04 -1.742 4 H2,gas 8.00 4.45 -3.55 -2.029 0.60613E+04 -1.851 5 H2S,gas -6.23 -14.79 -8.56 -4.281 0.14618E+05 -6.862 6 S2,gas -7.34 -38.48 -31.15 -4.792 0.53184E+05 -29.449 7 CO,gas 3.21 -12.25 -15.46 -4.757 0.26400E+05 -13.763 8 SO3,gas 17.12 -32.59 -49.71 -12.428 0.84883E+05 -48.014 9 SO2,gas 0.83 -28.14 -28.97 -7.726 0.49471E+05 -27.275 10 HCl,gas 5.19 -14.06 -19.25 -9.625 0.32868E+05 -17.551 11 acmite 7.71 6.54 -1.17 -0.121 0.19906E+04 15 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 19 spessartine 24.46 19.65 -4.81 -0.240 0.82051E+04 20 analcite 3.32 2.77 -0.55 -0.061 0.94052E+03 26 annite 20.12 17.71 -2.41 -0.134 0.41171E+04 27 phlogopite 27.06 25.40 -1.66 -0.092 0.28424E+04 29 anorthite 12.71 8.25 -4.46 -0.343 0.76117E+04 35 aragonite 0.97 -3.60 -4.57 -1.524 0.78048E+04 36 brucite 12.57 9.30 -3.27 -0.655 0.55887E+04 37 calcite 0.81 -3.60 -4.42 -1.472 0.75406E+04 38 carnegieite-low 9.02 5.93 -3.10 -0.442 0.52887E+04 39 carnegieite-high 10.09 5.93 -4.17 -0.595 0.71156E+04 40 carpholite-Mg 8.58 4.46 -4.13 -0.275 0.70454E+04 41 carpholite-Fe 6.71 1.89 -4.82 -0.321 0.82289E+04 42 celadonite 5.34 3.65 -1.69 -0.099 0.28814E+04 43 celadonite-Fe 3.88 1.09 -2.79 -0.164 0.47554E+04 44 chrysotile 23.89 21.58 -2.32 -0.193 0.39541E+04 49 chlorite-Al-free 47.17 43.15 -4.02 -0.167 0.68634E+04 51 chloritoid-Fe 9.17 5.05 -4.13 -0.275 0.70441E+04 52 chloritoid-Mn 11.40 7.53 -3.87 -0.258 0.66084E+04 54 coesite -2.38 -3.15 -0.78 -0.260 0.13298E+04 61 cristobalite -2.56 -3.15 -0.59 -0.198 0.10152E+04 63 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71234E+04 65 diaspore 2.87 0.74 -2.14 -0.356 0.36516E+04 66 diamond -3.10 -7.80 -4.69 -1.341 0.80155E+04 67 diopside 16.18 16.08 -0.10 -0.010 0.17692E+03 68 hedenbergite 14.21 13.52 -0.69 -0.069 0.11835E+04 71 enstatite 17.26 12.28 -4.98 -0.498 0.85096E+04 73 clinoenstatite 17.17 12.28 -4.89 -0.489 0.83412E+04 75 epidote 24.67 22.70 -1.97 -0.096 0.33677E+04 76 clinozoisite 22.81 18.92 -3.88 -0.176 0.66272E+04 77 epidote-Fe 29.84 26.47 -3.37 -0.175 0.57548E+04 78 fayalite 14.05 10.31 -3.73 -0.534 0.63772E+04 79 ferrosilite 11.15 7.16 -3.99 -0.399 0.68188E+04 83 gibbsite 4.08 0.74 -3.34 -0.478 0.57101E+04 84 glaucophane 22.97 20.81 -2.17 -0.059 0.36982E+04 85 glaucophane-Fe 17.28 13.12 -4.15 -0.112 0.70940E+04 86 graphite -3.55 -7.80 -4.25 -1.214 0.72578E+04 87 greenalite 16.14 13.89 -2.25 -0.188 0.38429E+04 90 hematite 12.57 9.02 -3.55 -0.430 0.60620E+04 91 heulandite -5.83 -7.52 -1.69 -0.077 0.28938E+04 95 jadeite 4.22 2.77 -1.44 -0.144 0.24660E+04 97 kalsilite 7.58 3.82 -3.76 -0.537 0.64211E+04 98 kaolinite -1.33 -4.84 -3.51 -0.319 0.59878E+04 101 laumontite 2.88 1.94 -0.94 -0.063 0.16063E+04 102 lawsonite 9.62 8.25 -1.36 -0.091 0.23283E+04 103 leucite 4.12 0.67 -3.45 -0.345 0.58916E+04 105 lizardite 23.24 21.58 -1.67 -0.139 0.28467E+04 107 magnetite 20.09 15.75 -4.34 -0.354 0.74081E+04 108 minnesotaite 10.39 7.58 -2.81 -0.165 0.47964E+04 112 manganosite 14.06 9.22 -4.84 -1.211 0.82687E+04 120 muscovite 2.58 -1.02 -3.60 -0.212 0.61447E+04 121 paragonite 4.24 1.09 -3.15 -0.185 0.53838E+04 122 nepheline 8.34 5.93 -2.41 -0.345 0.41210E+04 128 periclase-Fe 11.63 6.73 -4.89 -1.223 0.83559E+04 134 phlogopite-Na 29.65 27.50 -2.14 -0.119 0.36612E+04 136 prehnite 19.37 18.19 -1.18 -0.070 0.20186E+04 137 prehnite-Fe 22.50 21.96 -0.54 -0.032 0.91415E+03 138 pumpellyite-Fe 46.27 43.85 -2.42 -0.054 0.41358E+04 139 pumpellyite-Mg 48.99 46.41 -2.59 -0.057 0.44139E+04 143 pyrrhotite -4.26 -8.06 -3.80 -1.266 0.64858E+04 144 pyrrhotiteFe0.875 -6.02 -9.45 -3.44 -1.263 0.58656E+04 145 pyroxmangite 7.40 6.06 -1.34 -0.268 0.22848E+04 146 pyrophyllite -6.18 -11.15 -4.97 -0.311 0.84923E+04 147 quartz -2.99 -3.15 -0.17 -0.055 0.28253E+03 152 rhodonite 7.45 6.06 -1.39 -0.277 0.23650E+04 153 sanidine -1.28 -2.49 -1.21 -0.093 0.20677E+04 165 stilpnomelane-Mg 27.44 25.83 -1.61 -0.048 0.27516E+04 171 talc 16.49 15.27 -1.22 -0.072 0.20904E+04 174 tephroite 18.09 15.28 -2.81 -0.401 0.47975E+04 178 tridymite -2.63 -3.15 -0.53 -0.176 0.90251E+03 179 tremolite 47.87 47.42 -0.45 -0.012 0.76315E+03 180 ferroactinolite 38.45 34.61 -3.84 -0.104 0.65618E+04 181 troilite-low -4.41 -8.06 -3.65 -1.216 0.62286E+04 183 vesuvianite 223.47 218.64 -4.83 -0.037 0.82518E+04 187 wairakite 3.95 1.94 -2.01 -0.118 0.34283E+04 188 walstromite 11.51 9.94 -1.57 -0.314 0.26842E+04 189 wollastonite 10.46 9.94 -0.52 -0.105 0.89468E+03 190 pseudo-wollastonite 11.00 9.94 -1.06 -0.213 0.18145E+04 191 zoisite 22.85 18.92 -3.92 -0.178 0.67013E+04 192 akaganeite 7.75 4.51 -3.25 -0.702 0.55435E+04 199 chalcedony -2.80 -3.15 -0.35 -0.117 0.60183E+03 201 montmorillonite-Ca -2.29 -6.16 -3.87 -0.240 0.66140E+04 202 montmorillonite-K -2.24 -6.26 -4.03 -0.247 0.68769E+04 203 montmorillonite-Mg -2.48 -6.79 -4.31 -0.267 0.73607E+04 204 montmorillonite-Na -2.04 -5.57 -3.53 -0.216 0.60318E+04 205 nontronite-Ca 3.21 -0.16 -3.37 -0.219 0.57616E+04 206 nontronite-H 2.53 -2.32 -4.85 -0.325 0.82859E+04 207 nontronite-K 3.34 -0.26 -3.60 -0.231 0.61477E+04 208 nontronite-Mg 3.07 -0.79 -3.86 -0.250 0.65924E+04 209 nontronite-Na 3.52 0.43 -3.09 -0.198 0.52686E+04 224 tobermorite 9.82 7.75 -2.07 -0.565 0.35383E+04 230 alabandite -0.98 -5.58 -4.60 -1.533 0.78515E+04 233 boehmite 4.41 0.74 -3.67 -0.612 0.62685E+04 235 ferrous-oxide 9.81 6.73 -3.08 -0.770 0.52568E+04 240 silica-amorphous -2.09 -3.15 -1.06 -0.355 0.18160E+04 242 an20ab80 2.02 1.34 -0.67 -0.052 0.11515E+04 243 an25ab75 2.65 1.78 -0.87 -0.067 0.14863E+04 244 an30ab70 3.28 2.21 -1.07 -0.082 0.18308E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 4.0000000 g Current total amount of reactant added: 147.9990000 g New total amount of reactant added: 151.9990000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.7227E-13 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 11 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 151.9990000 Water: Moles liquid = 0.5458E+02 kg liquid = 0.9832E+00 Moles total = 0.5360E+02 kg total = 0.9657E+00 Activity = 1.0000 Stoichiometric ionic strength = .1129430E-01 Osmotic coef. = 0.9693 True ionic strength = .1996432E-01 Chg. balance for total moles = -.7227E-13 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.88643E-10 -10.0524 0.74495E-10 -10.1279 0.84039E+00 -0.0755 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13969E-03 -3.8548 0.11669E-03 -3.9330 0.83535E+00 -0.0781 4 SO4-- 0.83408E-12 -12.0788 0.43345E-12 -12.3631 0.51967E+00 -0.2843 5 HCO3- 0.30450E-06 -6.5164 0.25474E-06 -6.5939 0.83657E+00 -0.0775 6 HS- 0.25935E-04 -4.5861 0.21668E-04 -4.6642 0.83547E+00 -0.0781 7 Al+++ 0.97286E-29 -29.0119 0.22513E-29 -29.6476 0.23141E+00 -0.6356 8 H4SiO4 0.69909E-03 -3.1555 0.69909E-03 -3.1555 0.10000E+01 0.0000 9 Ca++ 0.13361E-06 -6.8742 0.68924E-07 -7.1616 0.51587E+00 -0.2875 10 Mg++ 0.21329E-10 -10.6710 0.10953E-10 -10.9605 0.51351E+00 -0.2894 11 Fe++ 0.58420E-13 -13.2334 0.30032E-13 -13.5224 0.51407E+00 -0.2890 12 K+ 0.15609E-03 -3.8066 0.13061E-03 -3.8840 0.83677E+00 -0.0774 13 Na+ 0.19807E-01 -1.7032 0.16543E-01 -1.7814 0.83520E+00 -0.0782 14 Mn++ 0.17755E-10 -10.7507 0.91347E-11 -11.0393 0.51450E+00 -0.2886 15 HPO4-- 0.46266E-07 -7.3347 0.24047E-07 -7.6189 0.51975E+00 -0.2842 16 HSiO3- 0.10490E-01 -1.9792 0.87626E-02 -2.0574 0.83535E+00 -0.0781 17 Ca(HSiO3)+ 0.16434E-07 -7.7843 0.13754E-07 -7.8616 0.83695E+00 -0.0773 18 Mg(HSiO3)+ 0.32501E-11 -11.4881 0.27202E-11 -11.5654 0.83695E+00 -0.0773 19 NaHSiO3,aq 0.23445E-02 -2.6299 0.23445E-02 -2.6299 0.10000E+01 0.0000 20 AlO+ 0.65940E-16 -16.1809 0.55188E-16 -16.2582 0.83695E+00 -0.0773 22 HAlO2,aq 0.14753E-09 -9.8311 0.14753E-09 -9.8311 0.10000E+01 0.0000 23 AlO2- 0.52575E-05 -5.2792 0.43839E-05 -5.3581 0.83385E+00 -0.0789 24 CH4,aq 0.12413E-04 -4.9061 0.12370E-04 -4.9076 0.99656E+00 -0.0015 25 C2H6,aq 0.24068E-14 -14.6186 0.23985E-14 -14.6201 0.99656E+00 -0.0015 29 CO,aq 0.11109E-16 -16.9543 0.11109E-16 -16.9543 0.10000E+01 0.0000 30 CO2,aq 0.40689E-10 -10.3905 0.40548E-10 -10.3920 0.99656E+00 -0.0015 31 CO3-2 0.57596E-06 -6.2396 0.29868E-06 -6.5248 0.51857E+00 -0.2852 32 CaCO3,aq 0.25813E-09 -9.5882 0.25813E-09 -9.5882 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.53548E-12 -12.2713 0.44817E-12 -12.3486 0.83695E+00 -0.0773 34 CaCl+ 0.15552E-10 -10.8082 0.13016E-10 -10.8855 0.83695E+00 -0.0773 35 CaCl2,aq 0.36085E-15 -15.4427 0.36085E-15 -15.4427 0.10000E+01 0.0000 36 CaOH+ 0.78786E-07 -7.1036 0.65940E-07 -7.1809 0.83695E+00 -0.0773 37 CaSO4,aq 0.94867E-17 -17.0229 0.94867E-17 -17.0229 0.10000E+01 0.0000 38 HCl,aq 0.15930E-14 -14.7978 0.15930E-14 -14.7978 0.10000E+01 0.0000 43 FeCl+ 0.66278E-17 -17.1786 0.55471E-17 -17.2559 0.83695E+00 -0.0773 46 FeO,aq 0.21033E-09 -9.6771 0.21033E-09 -9.6771 0.10000E+01 0.0000 47 FeOH+ 0.15679E-10 -10.8047 0.13123E-10 -10.8820 0.83695E+00 -0.0773 48 HFeO2- 0.35364E-07 -7.4514 0.29542E-07 -7.5296 0.83535E+00 -0.0781 49 FeO+ 0.11324E-16 -16.9460 0.94780E-17 -17.0233 0.83695E+00 -0.0773 51 FeO2- 0.41835E-09 -9.3785 0.34947E-09 -9.4566 0.83535E+00 -0.0781 52 HFeO2,aq 0.33111E-11 -11.4800 0.33111E-11 -11.4800 0.10000E+01 0.0000 53 H2,aq 0.10944E-04 -4.9608 0.10906E-04 -4.9623 0.99656E+00 -0.0015 54 KCl,aq 0.27624E-09 -9.5587 0.27624E-09 -9.5587 0.10000E+01 0.0000 56 KOH,aq 0.74876E-06 -6.1257 0.74876E-06 -6.1257 0.10000E+01 0.0000 57 KSO4- 0.10517E-14 -14.9781 0.87851E-15 -15.0563 0.83535E+00 -0.0781 58 MgCO3,aq 0.10282E-13 -13.9879 0.10282E-13 -13.9879 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.86951E-16 -16.0607 0.72773E-16 -16.1380 0.83695E+00 -0.0773 60 MgCl+ 0.22399E-14 -14.6498 0.18747E-14 -14.7271 0.83695E+00 -0.0773 61 MgOH+ 0.69280E-10 -10.1594 0.57983E-10 -10.2367 0.83695E+00 -0.0773 63 MnO,aq 0.17046E-08 -8.7684 0.17046E-08 -8.7684 0.10000E+01 0.0000 64 MnOH+ 0.44303E-09 -9.3536 0.37079E-09 -9.4309 0.83695E+00 -0.0773 65 MnO2-2 0.19658E-10 -10.7065 0.10194E-10 -10.9917 0.51857E+00 -0.2852 66 HMnO2- 0.19917E-09 -9.7008 0.16637E-09 -9.7789 0.83535E+00 -0.0781 69 MnCl+ 0.78428E-14 -14.1055 0.65640E-14 -14.1828 0.83695E+00 -0.0773 71 NaCl,aq 0.63975E-06 -6.1940 0.63975E-06 -6.1940 0.10000E+01 0.0000 72 NaOH,aq 0.95411E-04 -4.0204 0.95411E-04 -4.0204 0.10000E+01 0.0000 74 OH- 0.93013E-02 -2.0315 0.77559E-02 -2.1104 0.83385E+00 -0.0789 79 HPO3-2 0.15760E-14 -14.8024 0.81729E-15 -15.0876 0.51857E+00 -0.2852 81 H2PO3- 0.14616E-18 -18.8352 0.12209E-18 -18.9133 0.83535E+00 -0.0781 82 H3PO4,aq 0.93333E-18 -18.0300 0.93333E-18 -18.0300 0.10000E+01 0.0000 83 H2PO4- 0.39522E-10 -10.4032 0.33046E-10 -10.4809 0.83614E+00 -0.0777 84 PO4-3 0.10837E-08 -8.9651 0.26337E-09 -9.5794 0.24302E+00 -0.6144 88 HP2O7-3 0.99083E-18 -18.0040 0.22951E-18 -18.6392 0.23164E+00 -0.6352 89 P2O7-4 0.95186E-17 -17.0214 0.73602E-18 -18.1331 0.77325E-01 -1.1117 90 H2S,aq 0.50061E-08 -8.3005 0.49888E-08 -8.3020 0.99656E+00 -0.0015 91 S2-2 0.18395E-14 -14.7353 0.95392E-15 -15.0205 0.51857E+00 -0.2852 97 SO3-2 0.11678E-17 -17.9326 0.61431E-18 -18.2116 0.52606E+00 -0.2790 99 HSO4- 0.37145E-19 -19.4301 0.31118E-19 -19.5070 0.83776E+00 -0.0769 Charge balance for all species = -.7463E-13 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.8864317E-10 -.2225631E-01 -.2239410E+02 0.0000 2 H2O 0.1000000E+01 0.5550485E+02 0.9982013E+06 0.0000 3 Cl- 0.1396928E-03 0.1403328E-03 0.4966587E+01 6.1949 4 SO4-- 0.8340791E-12 -.1514859E-04 -.1452672E+01 7.8927 5 HCO3- 0.3045001E-06 0.1329343E-04 0.8097204E+00 3.5340 6 HS- 0.2593546E-04 0.4108905E-04 0.1356539E+01 5.4637 7 Al+++ 0.9728618E-29 0.5257628E-05 0.1416125E+00 0.7360 8 H4SiO4 0.6990934E-03 0.1353339E-01 0.1298510E+04 -3.1555 9 Ca++ 0.1336078E-06 0.2291018E-06 0.9166008E-02 13.0941 10 Mg++ 0.2132932E-10 0.9387174E-10 0.2278249E-05 9.2953 11 Fe++ 0.5842030E-13 0.3601195E-07 0.2007670E-02 6.7333 12 K+ 0.1560913E-03 0.1568403E-03 0.6122127E+01 6.2439 13 Na+ 0.1980711E-01 0.2224767E-01 0.5105821E+03 8.3465 14 Mn++ 0.1775455E-10 0.2384254E-08 0.1307588E-03 9.2164 15 HPO4-- 0.4626636E-07 0.4738963E-07 0.4540516E-02 12.6368 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.2516865E+01 -.2188223E-01 -.2494983E+01 0.0000000E+00 2 H2O 0.5360288E+02 0.5457195E+02 -.9690647E+00 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.4237915E-02 -.1489397E-04 0.4252809E-02 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.4212410E-02 0.4039844E-04 -.4252809E-02 0.0000000E+00 7 Al+++ 0.4956295E+00 0.5169260E-05 0.4956243E+00 0.0000000E+00 8 H4SiO4 0.1582733E+01 0.1330593E-01 0.1569427E+01 0.0000000E+00 9 Ca++ 0.1748350E+00 0.2252511E-06 0.1748348E+00 0.0000000E+00 10 Mg++ 0.1206341E+00 0.9229398E-10 0.1206341E+00 0.0000000E+00 11 Fe++ 0.1083766E+00 0.3540668E-07 0.1083766E+00 0.0000000E+00 12 K+ 0.3227155E-01 0.1542042E-03 0.3211735E-01 0.0000000E+00 13 Na+ 0.1909558E+00 0.2187374E-01 0.1690821E+00 0.0000000E+00 14 Mn++ 0.2635449E-02 0.2344180E-08 0.2635447E-02 0.0000000E+00 15 HPO4-- 0.8994657E-03 0.4659312E-07 0.8994191E-03 0.0000000E+00 Chg. balance for solid moles: -.3073E-15 Mass of aqueous solution: 0.984901E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 151.9990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 0.1689 -0.772 44.28 1.646 26.70 17.00 andradite 0.1701E-01 -1.769 8.645 0.937 5.212 2.246 grossular 0.3985E-02 -2.400 1.795 0.254 1.082 0.4995 apatite-OH 0.2998E-03 -3.523 0.1506 -0.822 0.9079E-01 0.4785E-01 clinochlore 0.2294E-01 -1.639 12.75 1.105 7.686 4.849 daphnite 0.6599E-02 -2.181 4.708 0.673 2.838 1.427 chlorite-Mn 0.5271E-03 -3.278 0.3737 -0.427 0.2253 0.1191 microcline 0.2819E-01 -1.550 7.845 0.895 4.730 3.065 stilbite 0.1071 -0.970 75.45 1.878 45.49 35.19 stilpnomelane-Fe 0.7862E-02 -2.104 8.475 0.928 5.109 2.927 tr.625ac.25prg.125 0.1642E-02 -2.785 1.403 0.147 0.8459 0.4516 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8102E+00 0.8102E+00 1.0000 -0.091 grossular 0.1898E+00 0.1898E+00 1.0000 -0.722 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.7630E+00 0.7630E+00 1.0000 -0.117 daphnite 0.2195E+00 0.2195E+00 1.0000 -0.659 chlorite-Mn 0.1753E-01 0.1753E-01 1.0000 -1.756 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 tr.625ac.25prg.125 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 165.877335 g Volume = 67.822387 cm3 Porosity: -9.7457% V(tot) - V(min): -.60228E+01 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 151.9990000 g log = 2.1818 Original solution: 1000.0103000 g Original solution / Rock added: 6.58 (Water/Rock Ratio), log = 0.8182 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0531 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9693E+00 0.9855 0.1006E+01 0.1021E+01 CO2,gas 0.4091E-08 1.0069 0.4338E-08 0.4308E-08 CH4,gas 0.1708E-01 1.0125 0.1821E-01 0.1798E-01 H2,gas 0.1359E-01 1.0006 0.1432E-01 0.1431E-01 H2S,gas 0.1308E-06 0.9959 0.1371E-06 0.1377E-06 S2,gas 0.3270E-29 1.0000 0.3443E-29 0.3443E-29 CO,gas 0.1572E-13 1.0000 0.1655E-13 0.1655E-13 SO3,gas 0.8637E-48 1.0000 0.9095E-48 0.9095E-48 SO2,gas 0.4811E-27 1.0000 0.5066E-27 0.5066E-27 HCl,gas 0.2669E-17 1.0000 0.2811E-17 0.2811E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 16 albite -0.38 -0.38 0.00 0.000 -0.94784E-12 22 andradite 39.01 39.01 0.00 0.000 0.12132E-10 23 grossular 32.73 32.73 0.00 0.000 0.24265E-10 32 apatite-OH -18.15 -18.15 0.00 0.000 0.00000E+00 46 clinochlore 39.07 39.07 0.00 0.000 -0.36397E-10 47 daphnite 28.97 28.97 0.00 0.000 -0.18198E-10 48 chlorite-Mn 46.87 46.87 0.00 0.000 0.00000E+00 116 microcline -2.49 -2.49 0.00 0.000 -0.10616E-10 163 stilbite -7.52 -7.52 0.00 0.000 -0.90992E-11 164 stilpnomelane-Fe 13.02 13.02 0.00 0.000 0.21232E-10 245 tr.625ac.25prg.125 45.16 45.16 0.00 0.000 0.00000E+00 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -16.72 -10.06 -3.354 0.17180E+05 -8.363 3 CH4,gas 4.54 1.10 -3.44 -0.860 0.58715E+04 -1.740 4 H2,gas 8.00 4.46 -3.54 -2.025 0.60497E+04 -1.844 5 H2S,gas -6.23 -14.79 -8.56 -4.281 0.14619E+05 -6.863 6 S2,gas -7.34 -38.50 -31.16 -4.794 0.53208E+05 -29.463 7 CO,gas 3.21 -12.27 -15.48 -4.763 0.26432E+05 -13.781 8 SO3,gas 17.12 -32.62 -49.74 -12.435 0.84930E+05 -48.041 9 SO2,gas 0.83 -28.16 -28.99 -7.732 0.49507E+05 -27.295 10 HCl,gas 5.19 -14.06 -19.25 -9.625 0.32869E+05 -17.551 11 acmite 7.71 6.54 -1.17 -0.121 0.19963E+04 15 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 19 spessartine 24.46 19.66 -4.80 -0.240 0.81998E+04 20 analcite 3.32 2.77 -0.55 -0.061 0.93956E+03 26 annite 20.12 17.71 -2.41 -0.134 0.41148E+04 27 phlogopite 27.06 25.40 -1.67 -0.093 0.28434E+04 29 anorthite 12.71 8.26 -4.46 -0.343 0.76069E+04 35 aragonite 0.97 -3.63 -4.59 -1.531 0.78445E+04 36 brucite 12.57 9.30 -3.27 -0.655 0.55891E+04 37 calcite 0.81 -3.63 -4.44 -1.480 0.75802E+04 38 carnegieite-low 9.02 5.93 -3.10 -0.442 0.52867E+04 39 carnegieite-high 10.09 5.93 -4.17 -0.595 0.71137E+04 40 carpholite-Mg 8.58 4.46 -4.13 -0.275 0.70445E+04 41 carpholite-Fe 6.71 1.89 -4.82 -0.321 0.82269E+04 42 celadonite 5.34 3.65 -1.69 -0.099 0.28827E+04 43 celadonite-Fe 3.88 1.09 -2.79 -0.164 0.47556E+04 44 chrysotile 23.89 21.57 -2.32 -0.193 0.39571E+04 49 chlorite-Al-free 47.17 43.15 -4.02 -0.168 0.68693E+04 51 chloritoid-Fe 9.17 5.05 -4.12 -0.275 0.70410E+04 52 chloritoid-Mn 11.40 7.53 -3.87 -0.258 0.66045E+04 54 coesite -2.38 -3.16 -0.78 -0.260 0.13308E+04 61 cristobalite -2.56 -3.16 -0.60 -0.198 0.10162E+04 63 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71234E+04 65 diaspore 2.87 0.74 -2.14 -0.356 0.36500E+04 66 diamond -3.10 -7.81 -4.71 -1.345 0.80354E+04 67 diopside 16.18 16.08 -0.10 -0.010 0.17570E+03 68 hedenbergite 14.21 13.52 -0.69 -0.069 0.11812E+04 71 enstatite 17.26 12.28 -4.99 -0.499 0.85122E+04 73 clinoenstatite 17.17 12.28 -4.89 -0.489 0.83438E+04 75 epidote 24.67 22.70 -1.97 -0.096 0.33654E+04 76 clinozoisite 22.81 18.93 -3.88 -0.176 0.66183E+04 77 epidote-Fe 29.84 26.47 -3.37 -0.175 0.57592E+04 78 fayalite 14.05 10.31 -3.73 -0.534 0.63766E+04 79 ferrosilite 11.15 7.16 -3.99 -0.399 0.68192E+04 83 gibbsite 4.08 0.74 -3.34 -0.478 0.57085E+04 84 glaucophane 22.97 20.81 -2.17 -0.059 0.37012E+04 85 glaucophane-Fe 17.28 13.12 -4.15 -0.112 0.70937E+04 86 graphite -3.55 -7.81 -4.26 -1.218 0.72776E+04 87 greenalite 16.14 13.89 -2.25 -0.188 0.38426E+04 90 hematite 12.57 9.01 -3.56 -0.431 0.60721E+04 91 heulandite -5.83 -7.52 -1.69 -0.077 0.28938E+04 95 jadeite 4.22 2.77 -1.44 -0.144 0.24650E+04 97 kalsilite 7.58 3.82 -3.76 -0.537 0.64192E+04 98 kaolinite -1.33 -4.84 -3.51 -0.319 0.59865E+04 101 laumontite 2.88 1.94 -0.94 -0.063 0.16034E+04 102 lawsonite 9.62 8.26 -1.36 -0.091 0.23235E+04 103 leucite 4.12 0.67 -3.45 -0.345 0.58906E+04 105 lizardite 23.24 21.57 -1.67 -0.139 0.28497E+04 107 magnetite 20.09 15.74 -4.34 -0.355 0.74174E+04 108 minnesotaite 10.39 7.58 -2.81 -0.165 0.47979E+04 112 manganosite 14.06 9.22 -4.84 -1.210 0.82670E+04 120 muscovite 2.58 -1.01 -3.60 -0.212 0.61415E+04 121 paragonite 4.24 1.09 -3.15 -0.185 0.53806E+04 122 nepheline 8.34 5.93 -2.41 -0.345 0.41191E+04 128 periclase-Fe 11.63 6.73 -4.89 -1.223 0.83551E+04 134 phlogopite-Na 29.65 27.50 -2.14 -0.119 0.36622E+04 136 prehnite 19.37 18.19 -1.18 -0.069 0.20113E+04 137 prehnite-Fe 22.50 21.96 -0.53 -0.032 0.91349E+03 138 pumpellyite-Fe 46.27 43.86 -2.41 -0.054 0.41188E+04 139 pumpellyite-Mg 48.99 46.42 -2.58 -0.057 0.43980E+04 143 pyrrhotite -4.26 -8.06 -3.80 -1.266 0.64856E+04 144 pyrrhotiteFe0.875 -6.02 -9.45 -3.44 -1.264 0.58670E+04 145 pyroxmangite 7.40 6.06 -1.34 -0.268 0.22841E+04 146 pyrophyllite -6.18 -11.15 -4.97 -0.311 0.84929E+04 147 quartz -2.99 -3.16 -0.17 -0.055 0.28349E+03 152 rhodonite 7.45 6.06 -1.38 -0.277 0.23643E+04 153 sanidine -1.28 -2.49 -1.21 -0.093 0.20677E+04 165 stilpnomelane-Mg 27.44 25.83 -1.61 -0.048 0.27571E+04 171 talc 16.49 15.26 -1.23 -0.072 0.20953E+04 174 tephroite 18.09 15.28 -2.81 -0.401 0.47952E+04 178 tridymite -2.63 -3.16 -0.53 -0.176 0.90347E+03 179 tremolite 47.87 47.42 -0.45 -0.012 0.76559E+03 180 ferroactinolite 38.45 34.61 -3.84 -0.104 0.65587E+04 181 troilite-low -4.41 -8.06 -3.65 -1.216 0.62285E+04 183 vesuvianite 223.47 218.68 -4.79 -0.037 0.81858E+04 187 wairakite 3.95 1.94 -2.01 -0.118 0.34254E+04 188 walstromite 11.51 9.94 -1.57 -0.314 0.26817E+04 189 wollastonite 10.46 9.94 -0.52 -0.104 0.89215E+03 190 pseudo-wollastonite 11.00 9.94 -1.06 -0.212 0.18120E+04 191 zoisite 22.85 18.93 -3.92 -0.178 0.66923E+04 192 akaganeite 7.75 4.50 -3.25 -0.703 0.55486E+04 199 chalcedony -2.80 -3.16 -0.35 -0.118 0.60279E+03 201 montmorillonite-Ca -2.29 -6.16 -3.87 -0.240 0.66147E+04 202 montmorillonite-K -2.24 -6.26 -4.03 -0.247 0.68778E+04 203 montmorillonite-Mg -2.48 -6.79 -4.31 -0.267 0.73620E+04 204 montmorillonite-Na -2.04 -5.57 -3.53 -0.216 0.60327E+04 205 nontronite-Ca 3.21 -0.17 -3.38 -0.219 0.57741E+04 206 nontronite-H 2.53 -2.33 -4.86 -0.326 0.82990E+04 207 nontronite-K 3.34 -0.27 -3.61 -0.232 0.61604E+04 208 nontronite-Mg 3.07 -0.79 -3.87 -0.251 0.66055E+04 209 nontronite-Na 3.52 0.43 -3.09 -0.199 0.52813E+04 224 tobermorite 9.82 7.75 -2.07 -0.565 0.35364E+04 230 alabandite -0.98 -5.58 -4.60 -1.533 0.78505E+04 233 boehmite 4.41 0.74 -3.67 -0.612 0.62669E+04 235 ferrous-oxide 9.81 6.73 -3.08 -0.770 0.52560E+04 240 silica-amorphous -2.09 -3.16 -1.06 -0.355 0.18170E+04 242 an20ab80 2.02 1.34 -0.67 -0.052 0.11505E+04 243 an25ab75 2.65 1.78 -0.87 -0.067 0.14851E+04 244 an30ab70 3.28 2.21 -1.07 -0.082 0.18293E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 4.0000000 g Current total amount of reactant added: 151.9990000 g New total amount of reactant added: 155.9990000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.7202E-13 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 11 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 155.9990000 Water: Moles liquid = 0.5455E+02 kg liquid = 0.9828E+00 Moles total = 0.5355E+02 kg total = 0.9648E+00 Activity = 1.0000 Stoichiometric ionic strength = .1129993E-01 Osmotic coef. = 0.9694 True ionic strength = .1997455E-01 Chg. balance for total moles = -.7202E-13 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.88546E-10 -10.0528 0.74411E-10 -10.1284 0.84037E+00 -0.0755 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13975E-03 -3.8547 0.11674E-03 -3.9328 0.83532E+00 -0.0781 4 SO4-- 0.78738E-12 -12.1038 0.40912E-12 -12.3881 0.51960E+00 -0.2843 5 HCO3- 0.28850E-06 -6.5399 0.24134E-06 -6.6174 0.83654E+00 -0.0775 6 HS- 0.25946E-04 -4.5859 0.21676E-04 -4.6640 0.83544E+00 -0.0781 7 Al+++ 0.97186E-29 -29.0124 0.22482E-29 -29.6482 0.23133E+00 -0.6358 8 H4SiO4 0.69824E-03 -3.1560 0.69824E-03 -3.1560 0.10000E+01 0.0000 9 Ca++ 0.13392E-06 -6.8732 0.69074E-07 -7.1607 0.51580E+00 -0.2875 10 Mg++ 0.21275E-10 -10.6721 0.10923E-10 -10.9616 0.51344E+00 -0.2895 11 Fe++ 0.58353E-13 -13.2339 0.29994E-13 -13.5230 0.51400E+00 -0.2890 12 K+ 0.15617E-03 -3.8064 0.13067E-03 -3.8838 0.83674E+00 -0.0774 13 Na+ 0.19817E-01 -1.7030 0.16551E-01 -1.7812 0.83517E+00 -0.0782 14 Mn++ 0.17754E-10 -10.7507 0.91332E-11 -11.0394 0.51443E+00 -0.2887 15 HPO4-- 0.46036E-07 -7.3369 0.23924E-07 -7.6212 0.51968E+00 -0.2843 16 HSiO3- 0.10489E-01 -1.9793 0.87618E-02 -2.0574 0.83532E+00 -0.0781 17 Ca(HSiO3)+ 0.16469E-07 -7.7833 0.13783E-07 -7.8607 0.83692E+00 -0.0773 18 Mg(HSiO3)+ 0.32412E-11 -11.4893 0.27126E-11 -11.5666 0.83692E+00 -0.0773 19 NaHSiO3,aq 0.23454E-02 -2.6298 0.23454E-02 -2.6298 0.10000E+01 0.0000 20 AlO+ 0.66003E-16 -16.1804 0.55239E-16 -16.2578 0.83692E+00 -0.0773 22 HAlO2,aq 0.14784E-09 -9.8302 0.14784E-09 -9.8302 0.10000E+01 0.0000 23 AlO2- 0.52744E-05 -5.2778 0.43979E-05 -5.3568 0.83382E+00 -0.0789 24 CH4,aq 0.12464E-04 -4.9044 0.12421E-04 -4.9059 0.99655E+00 -0.0015 25 C2H6,aq 0.23910E-14 -14.6214 0.23827E-14 -14.6229 0.99655E+00 -0.0015 29 CO,aq 0.10670E-16 -16.9718 0.10670E-16 -16.9718 0.10000E+01 0.0000 30 CO2,aq 0.38505E-10 -10.4145 0.38373E-10 -10.4160 0.99655E+00 -0.0015 31 CO3-2 0.54636E-06 -6.2625 0.28329E-06 -6.5478 0.51850E+00 -0.2852 32 CaCO3,aq 0.24536E-09 -9.6102 0.24536E-09 -9.6102 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.50844E-12 -12.2938 0.42552E-12 -12.3711 0.83692E+00 -0.0773 34 CaCl+ 0.15592E-10 -10.8071 0.13049E-10 -10.8844 0.83692E+00 -0.0773 35 CaCl2,aq 0.36190E-15 -15.4414 0.36190E-15 -15.4414 0.10000E+01 0.0000 36 CaOH+ 0.79049E-07 -7.1021 0.66158E-07 -7.1794 0.83692E+00 -0.0773 37 CaSO4,aq 0.89738E-17 -17.0470 0.89738E-17 -17.0470 0.10000E+01 0.0000 38 HCl,aq 0.15917E-14 -14.7981 0.15917E-14 -14.7981 0.10000E+01 0.0000 43 FeCl+ 0.66219E-17 -17.1790 0.55420E-17 -17.2563 0.83692E+00 -0.0773 46 FeO,aq 0.21053E-09 -9.6767 0.21053E-09 -9.6767 0.10000E+01 0.0000 47 FeOH+ 0.15677E-10 -10.8047 0.13121E-10 -10.8820 0.83692E+00 -0.0773 48 HFeO2- 0.35440E-07 -7.4505 0.29604E-07 -7.5287 0.83532E+00 -0.0781 49 FeO+ 0.11239E-16 -16.9493 0.94065E-17 -17.0266 0.83692E+00 -0.0773 51 FeO2- 0.41615E-09 -9.3808 0.34762E-09 -9.4589 0.83532E+00 -0.0781 52 HFeO2,aq 0.32898E-11 -11.4828 0.32898E-11 -11.4828 0.10000E+01 0.0000 53 H2,aq 0.11107E-04 -4.9544 0.11069E-04 -4.9559 0.99655E+00 -0.0015 54 KCl,aq 0.27647E-09 -9.5583 0.27647E-09 -9.5583 0.10000E+01 0.0000 56 KOH,aq 0.74996E-06 -6.1250 0.74996E-06 -6.1250 0.10000E+01 0.0000 57 KSO4- 0.99316E-15 -15.0030 0.82960E-15 -15.0811 0.83532E+00 -0.0781 58 MgCO3,aq 0.97258E-14 -14.0121 0.97258E-14 -14.0121 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.82159E-16 -16.0853 0.68760E-16 -16.1627 0.83692E+00 -0.0773 60 MgCl+ 0.22348E-14 -14.6508 0.18703E-14 -14.7281 0.83692E+00 -0.0773 61 MgOH+ 0.69173E-10 -10.1601 0.57892E-10 -10.2374 0.83692E+00 -0.0773 63 MnO,aq 0.17082E-08 -8.7675 0.17082E-08 -8.7675 0.10000E+01 0.0000 64 MnOH+ 0.44347E-09 -9.3531 0.37115E-09 -9.4304 0.83692E+00 -0.0773 65 MnO2-2 0.19746E-10 -10.7045 0.10239E-10 -10.9898 0.51850E+00 -0.2852 66 HMnO2- 0.19982E-09 -9.6994 0.16691E-09 -9.7775 0.83532E+00 -0.0781 69 MnCl+ 0.78447E-14 -14.1054 0.65654E-14 -14.1827 0.83692E+00 -0.0773 71 NaCl,aq 0.64029E-06 -6.1936 0.64029E-06 -6.1936 0.10000E+01 0.0000 72 NaOH,aq 0.95564E-04 -4.0197 0.95564E-04 -4.0197 0.10000E+01 0.0000 74 OH- 0.93122E-02 -2.0310 0.77646E-02 -2.1099 0.83382E+00 -0.0789 79 HPO3-2 0.15916E-14 -14.7982 0.82524E-15 -15.0834 0.51850E+00 -0.2852 81 H2PO3- 0.14742E-18 -18.8315 0.12314E-18 -18.9096 0.83532E+00 -0.0781 82 H3PO4,aq 0.92646E-18 -18.0332 0.92646E-18 -18.0332 0.10000E+01 0.0000 83 H2PO4- 0.39277E-10 -10.4059 0.32840E-10 -10.4836 0.83611E+00 -0.0777 84 PO4-3 0.10797E-08 -8.9667 0.26232E-09 -9.5812 0.24295E+00 -0.6145 88 HP2O7-3 0.97991E-18 -18.0088 0.22691E-18 -18.6441 0.23157E+00 -0.6353 89 P2O7-4 0.94264E-17 -17.0257 0.72850E-18 -18.1376 0.77283E-01 -1.1119 90 H2S,aq 0.50023E-08 -8.3008 0.49851E-08 -8.3023 0.99655E+00 -0.0015 91 S2-2 0.18140E-14 -14.7414 0.94059E-15 -15.0266 0.51850E+00 -0.2852 97 SO3-2 0.11188E-17 -17.9512 0.58849E-18 -18.2303 0.52599E+00 -0.2790 99 HSO4- 0.35022E-19 -19.4557 0.29339E-19 -19.5326 0.83773E+00 -0.0769 Charge balance for all species = -.7403E-13 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.8854604E-10 -.2226770E-01 -.2240555E+02 0.0000 2 H2O 0.1000000E+01 0.5550486E+02 0.9982011E+06 0.0000 3 Cl- 0.1397493E-03 0.1403899E-03 0.4968604E+01 6.1956 4 SO4-- 0.7873781E-12 -.1524045E-04 -.1461481E+01 7.8686 5 HCO3- 0.2884957E-06 0.1329884E-04 0.8100493E+00 3.5110 6 HS- 0.2594601E-04 0.4119146E-04 0.1359920E+01 5.4644 7 Al+++ 0.9718587E-29 0.5274535E-05 0.1420679E+00 0.7369 8 H4SiO4 0.6982423E-03 0.1353287E-01 0.1298459E+04 -3.1560 9 Ca++ 0.1339172E-06 0.2296966E-06 0.9189804E-02 13.0960 10 Mg++ 0.2127477E-10 0.9370127E-10 0.2274111E-05 9.2951 11 Fe++ 0.5835321E-13 0.3608540E-07 0.2011764E-02 6.7338 12 K+ 0.1561713E-03 0.1569215E-03 0.6125296E+01 6.2446 13 Na+ 0.1981728E-01 0.2225891E-01 0.5108397E+03 8.3472 14 Mn++ 0.1775412E-10 0.2389010E-08 0.1310196E-03 9.2173 15 HPO4-- 0.4603573E-07 0.4715472E-07 0.4518008E-02 12.6356 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.2583099E+01 -.2188453E-01 -.2561214E+01 0.0000000E+00 2 H2O 0.5355274E+02 0.5454977E+02 -.9970351E+00 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.4348769E-02 -.1497820E-04 0.4363747E-02 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.4323264E-02 0.4048267E-04 -.4363747E-02 0.0000000E+00 7 Al+++ 0.5086724E+00 0.5183775E-05 0.5086672E+00 0.0000000E+00 8 H4SiO4 0.1624384E+01 0.1330000E-01 0.1611084E+01 0.0000000E+00 9 Ca++ 0.1794356E+00 0.2257442E-06 0.1794353E+00 0.0000000E+00 10 Mg++ 0.1238087E+00 0.9208893E-10 0.1238087E+00 0.0000000E+00 11 Fe++ 0.1112286E+00 0.3546447E-07 0.1112286E+00 0.0000000E+00 12 K+ 0.3312081E-01 0.1542213E-03 0.3296659E-01 0.0000000E+00 13 Na+ 0.1959768E+00 0.2187590E-01 0.1741009E+00 0.0000000E+00 14 Mn++ 0.2704804E-02 0.2347902E-08 0.2704801E-02 0.0000000E+00 15 HPO4-- 0.9231360E-03 0.4634332E-07 0.9230897E-03 0.0000000E+00 Chg. balance for solid moles: 0.3123E-15 Mass of aqueous solution: 0.984502E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 155.9990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 0.1739 -0.760 45.59 1.659 26.78 17.50 andradite 0.1745E-01 -1.758 8.870 0.948 5.210 2.305 grossular 0.4124E-02 -2.385 1.858 0.269 1.091 0.5169 apatite-OH 0.3077E-03 -3.512 0.1546 -0.811 0.9079E-01 0.4911E-01 clinochlore 0.2348E-01 -1.629 13.05 1.116 7.666 4.964 daphnite 0.6765E-02 -2.170 4.827 0.684 2.835 1.463 chlorite-Mn 0.5410E-03 -3.267 0.3835 -0.416 0.2253 0.1222 microcline 0.2894E-01 -1.539 8.055 0.906 4.731 3.146 stilbite 0.1096 -0.960 77.26 1.888 45.38 36.03 stilpnomelane-Fe 0.8057E-02 -2.094 8.686 0.939 5.102 3.000 tr.625ac.25prg.125 0.1767E-02 -2.753 1.510 0.179 0.8872 0.4861 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8089E+00 0.8089E+00 1.0000 -0.092 grossular 0.1911E+00 0.1911E+00 1.0000 -0.719 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.7627E+00 0.7627E+00 1.0000 -0.118 daphnite 0.2197E+00 0.2197E+00 1.0000 -0.658 chlorite-Mn 0.1757E-01 0.1757E-01 1.0000 -1.755 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 tr.625ac.25prg.125 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 170.244906 g Volume = 69.588585 cm3 Porosity: -9.7619% V(tot) - V(min): -.61890E+01 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 155.9990000 g log = 2.1931 Original solution: 1000.0103000 g Original solution / Rock added: 6.41 (Water/Rock Ratio), log = 0.8069 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0533 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9691E+00 0.9855 0.1006E+01 0.1021E+01 CO2,gas 0.3871E-08 1.0069 0.4105E-08 0.4077E-08 CH4,gas 0.1714E-01 1.0125 0.1828E-01 0.1806E-01 H2,gas 0.1379E-01 1.0006 0.1453E-01 0.1452E-01 H2S,gas 0.1306E-06 0.9959 0.1370E-06 0.1376E-06 S2,gas 0.3169E-29 1.0000 0.3338E-29 0.3338E-29 CO,gas 0.1510E-13 1.0000 0.1590E-13 0.1590E-13 SO3,gas 0.8132E-48 1.0000 0.8565E-48 0.8565E-48 SO2,gas 0.4597E-27 1.0000 0.4843E-27 0.4843E-27 HCl,gas 0.2666E-17 1.0000 0.2809E-17 0.2809E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 16 albite -0.38 -0.38 0.00 0.000 -0.94784E-12 22 andradite 39.01 39.01 0.00 0.000 0.24265E-10 23 grossular 32.73 32.73 0.00 0.000 -0.12132E-10 32 apatite-OH -18.15 -18.15 0.00 0.000 0.00000E+00 46 clinochlore 39.07 39.07 0.00 0.000 -0.12132E-10 47 daphnite 28.97 28.97 0.00 0.000 -0.42463E-10 48 chlorite-Mn 46.87 46.87 0.00 0.000 -0.48529E-10 116 microcline -2.49 -2.49 0.00 0.000 0.15165E-11 163 stilbite -7.52 -7.52 0.00 0.000 -0.90992E-11 164 stilpnomelane-Fe 13.02 13.02 0.00 0.000 -0.75827E-10 245 tr.625ac.25prg.125 45.16 45.16 0.00 0.000 0.00000E+00 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -16.75 -10.09 -3.362 0.17221E+05 -8.387 3 CH4,gas 4.54 1.11 -3.44 -0.859 0.58685E+04 -1.738 4 H2,gas 8.00 4.46 -3.54 -2.021 0.60387E+04 -1.838 5 H2S,gas -6.23 -14.79 -8.56 -4.281 0.14620E+05 -6.863 6 S2,gas -7.34 -38.51 -31.18 -4.796 0.53231E+05 -29.477 7 CO,gas 3.21 -12.28 -15.50 -4.768 0.26462E+05 -13.799 8 SO3,gas 17.12 -32.64 -49.77 -12.442 0.84974E+05 -48.067 9 SO2,gas 0.83 -28.18 -29.01 -7.737 0.49540E+05 -27.315 10 HCl,gas 5.19 -14.06 -19.25 -9.625 0.32870E+05 -17.551 11 acmite 7.71 6.54 -1.17 -0.122 0.20017E+04 15 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 19 spessartine 24.46 19.66 -4.80 -0.240 0.81948E+04 20 analcite 3.32 2.77 -0.55 -0.061 0.93866E+03 26 annite 20.12 17.71 -2.41 -0.134 0.41127E+04 27 phlogopite 27.06 25.40 -1.67 -0.093 0.28444E+04 29 anorthite 12.71 8.26 -4.45 -0.342 0.76024E+04 35 aragonite 0.97 -3.65 -4.62 -1.539 0.78821E+04 36 brucite 12.57 9.30 -3.27 -0.655 0.55894E+04 37 calcite 0.81 -3.65 -4.46 -1.487 0.76178E+04 38 carnegieite-low 9.02 5.93 -3.10 -0.442 0.52849E+04 39 carnegieite-high 10.09 5.93 -4.17 -0.595 0.71119E+04 40 carpholite-Mg 8.58 4.46 -4.13 -0.275 0.70436E+04 41 carpholite-Fe 6.71 1.90 -4.82 -0.321 0.82249E+04 42 celadonite 5.34 3.65 -1.69 -0.099 0.28839E+04 43 celadonite-Fe 3.88 1.09 -2.79 -0.164 0.47557E+04 44 chrysotile 23.89 21.57 -2.32 -0.193 0.39599E+04 49 chlorite-Al-free 47.17 43.15 -4.03 -0.168 0.68749E+04 51 chloritoid-Fe 9.17 5.05 -4.12 -0.275 0.70382E+04 52 chloritoid-Mn 11.40 7.54 -3.87 -0.258 0.66008E+04 54 coesite -2.38 -3.16 -0.78 -0.260 0.13317E+04 61 cristobalite -2.56 -3.16 -0.60 -0.199 0.10171E+04 63 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71234E+04 65 diaspore 2.87 0.74 -2.14 -0.356 0.36485E+04 66 diamond -3.10 -7.82 -4.72 -1.348 0.80543E+04 67 diopside 16.18 16.08 -0.10 -0.010 0.17454E+03 68 hedenbergite 14.21 13.52 -0.69 -0.069 0.11790E+04 71 enstatite 17.26 12.28 -4.99 -0.499 0.85147E+04 73 clinoenstatite 17.17 12.28 -4.89 -0.489 0.83463E+04 75 epidote 24.67 22.70 -1.97 -0.096 0.33633E+04 76 clinozoisite 22.81 18.93 -3.87 -0.176 0.66099E+04 77 epidote-Fe 29.84 26.47 -3.38 -0.175 0.57634E+04 78 fayalite 14.05 10.31 -3.73 -0.533 0.63761E+04 79 ferrosilite 11.15 7.16 -3.99 -0.399 0.68195E+04 83 gibbsite 4.08 0.74 -3.34 -0.477 0.57070E+04 84 glaucophane 22.97 20.81 -2.17 -0.059 0.37040E+04 85 glaucophane-Fe 17.28 13.12 -4.15 -0.112 0.70933E+04 86 graphite -3.55 -7.82 -4.27 -1.221 0.72966E+04 87 greenalite 16.14 13.89 -2.25 -0.188 0.38422E+04 90 hematite 12.57 9.00 -3.56 -0.432 0.60817E+04 91 heulandite -5.83 -7.52 -1.69 -0.077 0.28938E+04 95 jadeite 4.22 2.77 -1.44 -0.144 0.24641E+04 97 kalsilite 7.58 3.83 -3.76 -0.537 0.64174E+04 98 kaolinite -1.33 -4.84 -3.51 -0.319 0.59853E+04 101 laumontite 2.88 1.95 -0.94 -0.062 0.16007E+04 102 lawsonite 9.62 8.26 -1.36 -0.091 0.23190E+04 103 leucite 4.12 0.67 -3.45 -0.345 0.58897E+04 105 lizardite 23.24 21.57 -1.67 -0.139 0.28525E+04 107 magnetite 20.09 15.74 -4.35 -0.355 0.74262E+04 108 minnesotaite 10.39 7.58 -2.81 -0.165 0.47994E+04 112 manganosite 14.06 9.22 -4.84 -1.210 0.82655E+04 120 muscovite 2.58 -1.01 -3.60 -0.211 0.61385E+04 121 paragonite 4.24 1.09 -3.15 -0.185 0.53776E+04 122 nepheline 8.34 5.93 -2.41 -0.344 0.41173E+04 128 periclase-Fe 11.63 6.73 -4.89 -1.223 0.83544E+04 134 phlogopite-Na 29.65 27.50 -2.15 -0.119 0.36632E+04 136 prehnite 19.37 18.20 -1.17 -0.069 0.20044E+04 137 prehnite-Fe 22.50 21.96 -0.53 -0.032 0.91288E+03 138 pumpellyite-Fe 46.27 43.87 -2.40 -0.053 0.41027E+04 139 pumpellyite-Mg 48.99 46.43 -2.57 -0.057 0.43830E+04 143 pyrrhotite -4.26 -8.06 -3.80 -1.266 0.64855E+04 144 pyrrhotiteFe0.875 -6.02 -9.45 -3.44 -1.264 0.58683E+04 145 pyroxmangite 7.40 6.06 -1.34 -0.267 0.22834E+04 146 pyrophyllite -6.18 -11.15 -4.97 -0.311 0.84935E+04 147 quartz -2.99 -3.16 -0.17 -0.056 0.28439E+03 152 rhodonite 7.45 6.06 -1.38 -0.277 0.23637E+04 153 sanidine -1.28 -2.49 -1.21 -0.093 0.20677E+04 165 stilpnomelane-Mg 27.44 25.82 -1.62 -0.048 0.27624E+04 171 talc 16.49 15.26 -1.23 -0.072 0.20999E+04 174 tephroite 18.09 15.28 -2.81 -0.401 0.47930E+04 178 tridymite -2.63 -3.16 -0.53 -0.177 0.90437E+03 179 tremolite 47.87 47.42 -0.45 -0.012 0.76788E+03 180 ferroactinolite 38.45 34.61 -3.84 -0.104 0.65558E+04 181 troilite-low -4.41 -8.06 -3.65 -1.216 0.62283E+04 183 vesuvianite 223.47 218.71 -4.76 -0.036 0.81236E+04 187 wairakite 3.95 1.95 -2.00 -0.118 0.34227E+04 188 walstromite 11.51 9.94 -1.57 -0.314 0.26793E+04 189 wollastonite 10.46 9.94 -0.52 -0.104 0.88977E+03 190 pseudo-wollastonite 11.00 9.94 -1.06 -0.212 0.18096E+04 191 zoisite 22.85 18.93 -3.91 -0.178 0.66839E+04 192 akaganeite 7.75 4.50 -3.25 -0.703 0.55534E+04 199 chalcedony -2.80 -3.16 -0.35 -0.118 0.60369E+03 201 montmorillonite-Ca -2.29 -6.17 -3.87 -0.240 0.66154E+04 202 montmorillonite-K -2.24 -6.27 -4.03 -0.247 0.68786E+04 203 montmorillonite-Mg -2.48 -6.79 -4.31 -0.267 0.73632E+04 204 montmorillonite-Na -2.04 -5.57 -3.53 -0.216 0.60334E+04 205 nontronite-Ca 3.21 -0.17 -3.39 -0.220 0.57860E+04 206 nontronite-H 2.53 -2.33 -4.87 -0.326 0.83113E+04 207 nontronite-K 3.34 -0.27 -3.61 -0.232 0.61724E+04 208 nontronite-Mg 3.07 -0.80 -3.88 -0.251 0.66179E+04 209 nontronite-Na 3.52 0.42 -3.10 -0.199 0.52933E+04 224 tobermorite 9.82 7.75 -2.07 -0.565 0.35345E+04 230 alabandite -0.98 -5.58 -4.60 -1.532 0.78495E+04 233 boehmite 4.41 0.74 -3.67 -0.612 0.62654E+04 235 ferrous-oxide 9.81 6.73 -3.08 -0.769 0.52553E+04 240 silica-amorphous -2.09 -3.16 -1.06 -0.355 0.18179E+04 242 an20ab80 2.02 1.34 -0.67 -0.052 0.11496E+04 243 an25ab75 2.65 1.78 -0.87 -0.067 0.14840E+04 244 an30ab70 3.28 2.21 -1.07 -0.082 0.18280E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 4.0000000 g Current total amount of reactant added: 155.9990000 g New total amount of reactant added: 159.9990000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.7204E-13 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 11 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 159.9990000 Water: Moles liquid = 0.5453E+02 kg liquid = 0.9824E+00 Moles total = 0.5350E+02 kg total = 0.9639E+00 Activity = 1.0000 Stoichiometric ionic strength = .1130527E-01 Osmotic coef. = 0.9694 True ionic strength = .1998422E-01 Chg. balance for total moles = -.7204E-13 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.88454E-10 -10.0533 0.74332E-10 -10.1288 0.84034E+00 -0.0755 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13981E-03 -3.8545 0.11678E-03 -3.9326 0.83529E+00 -0.0782 4 SO4-- 0.74560E-12 -12.1275 0.38737E-12 -12.4119 0.51954E+00 -0.2844 5 HCO3- 0.27408E-06 -6.5621 0.22927E-06 -6.6397 0.83651E+00 -0.0775 6 HS- 0.25957E-04 -4.5858 0.21685E-04 -4.6638 0.83542E+00 -0.0781 7 Al+++ 0.97091E-29 -29.0128 0.22454E-29 -29.6487 0.23127E+00 -0.6359 8 H4SiO4 0.69744E-03 -3.1565 0.69744E-03 -3.1565 0.10000E+01 0.0000 9 Ca++ 0.13421E-06 -6.8722 0.69216E-07 -7.1598 0.51573E+00 -0.2876 10 Mg++ 0.21223E-10 -10.6732 0.10896E-10 -10.9628 0.51337E+00 -0.2896 11 Fe++ 0.58290E-13 -13.2344 0.29957E-13 -13.5235 0.51394E+00 -0.2891 12 K+ 0.15625E-03 -3.8062 0.13073E-03 -3.8836 0.83671E+00 -0.0774 13 Na+ 0.19827E-01 -1.7027 0.16558E-01 -1.7810 0.83514E+00 -0.0782 14 Mn++ 0.17754E-10 -10.7507 0.91320E-11 -11.0394 0.51436E+00 -0.2887 15 HPO4-- 0.45819E-07 -7.3390 0.23808E-07 -7.6233 0.51961E+00 -0.2843 16 HSiO3- 0.10489E-01 -1.9793 0.87611E-02 -2.0574 0.83529E+00 -0.0782 17 Ca(HSiO3)+ 0.16502E-07 -7.7825 0.13810E-07 -7.8598 0.83689E+00 -0.0773 18 Mg(HSiO3)+ 0.32328E-11 -11.4904 0.27055E-11 -11.5678 0.83689E+00 -0.0773 19 NaHSiO3,aq 0.23463E-02 -2.6296 0.23463E-02 -2.6296 0.10000E+01 0.0000 20 AlO+ 0.66062E-16 -16.1800 0.55287E-16 -16.2574 0.83689E+00 -0.0773 22 HAlO2,aq 0.14812E-09 -9.8294 0.14812E-09 -9.8294 0.10000E+01 0.0000 23 AlO2- 0.52904E-05 -5.2765 0.44111E-05 -5.3555 0.83379E+00 -0.0789 24 CH4,aq 0.12510E-04 -4.9027 0.12467E-04 -4.9042 0.99655E+00 -0.0015 25 C2H6,aq 0.23753E-14 -14.6243 0.23671E-14 -14.6258 0.99655E+00 -0.0015 29 CO,aq 0.10269E-16 -16.9885 0.10269E-16 -16.9885 0.10000E+01 0.0000 30 CO2,aq 0.36541E-10 -10.4372 0.36415E-10 -10.4387 0.99655E+00 -0.0015 31 CO3-2 0.51966E-06 -6.2843 0.26941E-06 -6.5696 0.51844E+00 -0.2853 32 CaCO3,aq 0.23382E-09 -9.6311 0.23382E-09 -9.6311 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.48403E-12 -12.3151 0.40508E-12 -12.3925 0.83689E+00 -0.0773 34 CaCl+ 0.15630E-10 -10.8060 0.13081E-10 -10.8834 0.83689E+00 -0.0773 35 CaCl2,aq 0.36292E-15 -15.4402 0.36292E-15 -15.4402 0.10000E+01 0.0000 36 CaOH+ 0.79299E-07 -7.1007 0.66365E-07 -7.1781 0.83689E+00 -0.0773 37 CaSO4,aq 0.85141E-17 -17.0699 0.85141E-17 -17.0699 0.10000E+01 0.0000 38 HCl,aq 0.15906E-14 -14.7984 0.15906E-14 -14.7984 0.10000E+01 0.0000 43 FeCl+ 0.66166E-17 -17.1794 0.55374E-17 -17.2567 0.83689E+00 -0.0773 46 FeO,aq 0.21073E-09 -9.6763 0.21073E-09 -9.6763 0.10000E+01 0.0000 47 FeOH+ 0.15676E-10 -10.8048 0.13119E-10 -10.8821 0.83689E+00 -0.0773 48 HFeO2- 0.35511E-07 -7.4496 0.29662E-07 -7.5278 0.83529E+00 -0.0782 49 FeO+ 0.11160E-16 -16.9523 0.93394E-17 -17.0297 0.83689E+00 -0.0773 51 FeO2- 0.41408E-09 -9.3829 0.34588E-09 -9.4611 0.83529E+00 -0.0782 52 HFeO2,aq 0.32699E-11 -11.4855 0.32699E-11 -11.4855 0.10000E+01 0.0000 53 H2,aq 0.11264E-04 -4.9483 0.11225E-04 -4.9498 0.99655E+00 -0.0015 54 KCl,aq 0.27670E-09 -9.5580 0.27670E-09 -9.5580 0.10000E+01 0.0000 56 KOH,aq 0.75110E-06 -6.1243 0.75110E-06 -6.1243 0.10000E+01 0.0000 57 KSO4- 0.94079E-15 -15.0265 0.78584E-15 -15.1047 0.83529E+00 -0.0782 58 MgCO3,aq 0.92258E-14 -14.0350 0.92258E-14 -14.0350 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.77854E-16 -16.1087 0.65156E-16 -16.1860 0.83689E+00 -0.0773 60 MgCl+ 0.22300E-14 -14.6517 0.18662E-14 -14.7290 0.83689E+00 -0.0773 61 MgOH+ 0.69073E-10 -10.1607 0.57807E-10 -10.2380 0.83689E+00 -0.0773 63 MnO,aq 0.17116E-08 -8.7666 0.17116E-08 -8.7666 0.10000E+01 0.0000 64 MnOH+ 0.44390E-09 -9.3527 0.37150E-09 -9.4300 0.83689E+00 -0.0773 65 MnO2-2 0.19831E-10 -10.7027 0.10281E-10 -10.9880 0.51844E+00 -0.2853 66 HMnO2- 0.20044E-09 -9.6980 0.16742E-09 -9.7762 0.83529E+00 -0.0782 69 MnCl+ 0.78469E-14 -14.1053 0.65670E-14 -14.1826 0.83689E+00 -0.0773 71 NaCl,aq 0.64082E-06 -6.1933 0.64082E-06 -6.1933 0.10000E+01 0.0000 72 NaOH,aq 0.95709E-04 -4.0190 0.95709E-04 -4.0190 0.10000E+01 0.0000 74 OH- 0.93224E-02 -2.0305 0.77729E-02 -2.1094 0.83379E+00 -0.0789 79 HPO3-2 0.16065E-14 -14.7941 0.83285E-15 -15.0794 0.51844E+00 -0.2853 81 H2PO3- 0.14862E-18 -18.8279 0.12414E-18 -18.9061 0.83529E+00 -0.0782 82 H3PO4,aq 0.92002E-18 -18.0362 0.92002E-18 -18.0362 0.10000E+01 0.0000 83 H2PO4- 0.39046E-10 -10.4084 0.32646E-10 -10.4862 0.83608E+00 -0.0777 84 PO4-3 0.10759E-08 -8.9682 0.26133E-09 -9.5828 0.24288E+00 -0.6146 88 HP2O7-3 0.96970E-18 -18.0134 0.22448E-18 -18.6488 0.23150E+00 -0.6355 89 P2O7-4 0.93401E-17 -17.0296 0.72147E-18 -18.1418 0.77245E-01 -1.1121 90 H2S,aq 0.49989E-08 -8.3011 0.49816E-08 -8.3026 0.99655E+00 -0.0015 91 S2-2 0.17904E-14 -14.7471 0.92819E-15 -15.0324 0.51844E+00 -0.2853 97 SO3-2 0.10744E-17 -17.9688 0.56506E-18 -18.2479 0.52593E+00 -0.2791 99 HSO4- 0.33125E-19 -19.4798 0.27749E-19 -19.5568 0.83771E+00 -0.0769 Charge balance for all species = -.7508E-13 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.8845440E-10 -.2227847E-01 -.2241638E+02 0.0000 2 H2O 0.1000000E+01 0.5550487E+02 0.9982010E+06 0.0000 3 Cl- 0.1398059E-03 0.1404470E-03 0.4970624E+01 6.1962 4 SO4-- 0.7455981E-12 -.1532620E-04 -.1469704E+01 7.8458 5 HCO3- 0.2740787E-06 0.1330425E-04 0.8103785E+00 3.4892 6 HS- 0.2595657E-04 0.4128777E-04 0.1363099E+01 5.4650 7 Al+++ 0.9709121E-29 0.5290550E-05 0.1424992E+00 0.7378 8 H4SiO4 0.6974394E-03 0.1353238E-01 0.1298412E+04 -3.1565 9 Ca++ 0.1342102E-06 0.2302609E-06 0.9212375E-02 13.0979 10 Mg++ 0.2122336E-10 0.9354053E-10 0.2270209E-05 9.2949 11 Fe++ 0.5828993E-13 0.3615494E-07 0.2015640E-02 6.7342 12 K+ 0.1562470E-03 0.1569984E-03 0.6128294E+01 6.2452 13 Na+ 0.1982691E-01 0.2226954E-01 0.5110836E+03 8.3478 14 Mn++ 0.1775409E-10 0.2393560E-08 0.1312691E-03 9.2182 15 HPO4-- 0.4581885E-07 0.4693383E-07 0.4496842E-02 12.6344 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.2649333E+01 -.2188622E-01 -.2627447E+01 0.0000000E+00 2 H2O 0.5350260E+02 0.5452760E+02 -.1025008E+01 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.4459622E-02 -.1505636E-04 0.4474679E-02 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.4434118E-02 0.4056083E-04 -.4474679E-02 0.0000000E+00 7 Al+++ 0.5217154E+00 0.5197401E-05 0.5217102E+00 0.0000000E+00 8 H4SiO4 0.1666035E+01 0.1329412E-01 0.1652741E+01 0.0000000E+00 9 Ca++ 0.1840361E+00 0.2262067E-06 0.1840359E+00 0.0000000E+00 10 Mg++ 0.1269833E+00 0.9189358E-10 0.1269833E+00 0.0000000E+00 11 Fe++ 0.1140807E+00 0.3551837E-07 0.1140806E+00 0.0000000E+00 12 K+ 0.3397006E-01 0.1542342E-03 0.3381583E-01 0.0000000E+00 13 Na+ 0.2009978E+00 0.2187745E-01 0.1791203E+00 0.0000000E+00 14 Mn++ 0.2774158E-02 0.2351417E-08 0.2774156E-02 0.0000000E+00 15 HPO4-- 0.9468063E-03 0.4610747E-07 0.9467602E-03 0.0000000E+00 Chg. balance for solid moles: -.5356E-15 Mass of aqueous solution: 0.984102E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 159.9990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 0.1789 -0.747 46.91 1.671 26.86 18.01 andradite 0.1790E-01 -1.747 9.096 0.959 5.209 2.363 grossular 0.4263E-02 -2.370 1.920 0.283 1.100 0.5343 apatite-OH 0.3156E-03 -3.501 0.1585 -0.800 0.9079E-01 0.5037E-01 clinochlore 0.2402E-01 -1.619 13.35 1.126 7.648 5.079 daphnite 0.6930E-02 -2.159 4.945 0.694 2.832 1.498 chlorite-Mn 0.5548E-03 -3.256 0.3934 -0.405 0.2253 0.1254 microcline 0.2969E-01 -1.527 8.264 0.917 4.733 3.228 stilbite 0.1122 -0.950 79.06 1.898 45.28 36.88 stilpnomelane-Fe 0.8253E-02 -2.083 8.897 0.949 5.095 3.073 tr.625ac.25prg.125 0.1893E-02 -2.723 1.618 0.209 0.9265 0.5207 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8076E+00 0.8076E+00 1.0000 -0.093 grossular 0.1924E+00 0.1924E+00 1.0000 -0.716 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.7624E+00 0.7624E+00 1.0000 -0.118 daphnite 0.2199E+00 0.2199E+00 1.0000 -0.658 chlorite-Mn 0.1761E-01 0.1761E-01 1.0000 -1.754 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 tr.625ac.25prg.125 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 174.612448 g Volume = 71.354744 cm3 Porosity: -9.7772% V(tot) - V(min): -.63551E+01 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 159.9990000 g log = 2.2041 Original solution: 1000.0103000 g Original solution / Rock added: 6.25 (Water/Rock Ratio), log = 0.7959 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0536 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9688E+00 0.9855 0.1006E+01 0.1021E+01 CO2,gas 0.3672E-08 1.0069 0.3896E-08 0.3869E-08 CH4,gas 0.1720E-01 1.0125 0.1835E-01 0.1812E-01 H2,gas 0.1398E-01 1.0006 0.1474E-01 0.1473E-01 H2S,gas 0.1305E-06 0.9959 0.1369E-06 0.1375E-06 S2,gas 0.3076E-29 1.0000 0.3241E-29 0.3241E-29 CO,gas 0.1452E-13 1.0000 0.1530E-13 0.1530E-13 SO3,gas 0.7681E-48 1.0000 0.8093E-48 0.8093E-48 SO2,gas 0.4404E-27 1.0000 0.4640E-27 0.4640E-27 HCl,gas 0.2664E-17 1.0000 0.2807E-17 0.2807E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 16 albite -0.38 -0.38 0.00 0.000 -0.94784E-12 22 andradite 39.01 39.01 0.00 0.000 0.12132E-10 23 grossular 32.73 32.73 0.00 0.000 0.12132E-10 32 apatite-OH -18.15 -18.15 0.00 0.000 0.00000E+00 46 clinochlore 39.07 39.07 0.00 0.000 -0.12132E-10 47 daphnite 28.97 28.97 0.00 0.000 -0.12132E-10 48 chlorite-Mn 46.87 46.87 0.00 0.000 -0.24265E-10 116 microcline -2.49 -2.49 0.00 0.000 -0.10616E-10 163 stilbite -7.52 -7.52 0.00 0.000 0.15165E-10 164 stilpnomelane-Fe 13.02 13.02 0.00 0.000 -0.27298E-10 245 tr.625ac.25prg.125 45.16 45.16 0.00 0.000 0.24265E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -16.77 -10.11 -3.369 0.17260E+05 -8.409 3 CH4,gas 4.54 1.11 -3.44 -0.859 0.58657E+04 -1.736 4 H2,gas 8.00 4.47 -3.53 -2.017 0.60283E+04 -1.832 5 H2S,gas -6.23 -14.79 -8.56 -4.281 0.14620E+05 -6.863 6 S2,gas -7.34 -38.52 -31.19 -4.798 0.53253E+05 -29.489 7 CO,gas 3.21 -12.30 -15.51 -4.774 0.26490E+05 -13.815 8 SO3,gas 17.12 -32.67 -49.79 -12.448 0.85017E+05 -48.092 9 SO2,gas 0.83 -28.20 -29.03 -7.742 0.49572E+05 -27.333 10 HCl,gas 5.19 -14.06 -19.25 -9.625 0.32870E+05 -17.552 11 acmite 7.71 6.53 -1.18 -0.122 0.20068E+04 15 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 19 spessartine 24.46 19.66 -4.80 -0.240 0.81901E+04 20 analcite 3.32 2.77 -0.55 -0.061 0.93780E+03 26 annite 20.12 17.72 -2.41 -0.134 0.41106E+04 27 phlogopite 27.06 25.40 -1.67 -0.093 0.28453E+04 29 anorthite 12.71 8.26 -4.45 -0.342 0.75981E+04 35 aragonite 0.97 -3.67 -4.64 -1.546 0.79178E+04 36 brucite 12.57 9.29 -3.27 -0.655 0.55897E+04 37 calcite 0.81 -3.67 -4.48 -1.494 0.76536E+04 38 carnegieite-low 9.02 5.93 -3.09 -0.442 0.52832E+04 39 carnegieite-high 10.09 5.93 -4.16 -0.595 0.71102E+04 40 carpholite-Mg 8.58 4.46 -4.12 -0.275 0.70427E+04 41 carpholite-Fe 6.71 1.90 -4.82 -0.321 0.82231E+04 42 celadonite 5.34 3.65 -1.69 -0.099 0.28851E+04 43 celadonite-Fe 3.88 1.09 -2.79 -0.164 0.47559E+04 44 chrysotile 23.89 21.57 -2.32 -0.193 0.39625E+04 49 chlorite-Al-free 47.17 43.14 -4.03 -0.168 0.68802E+04 51 chloritoid-Fe 9.17 5.05 -4.12 -0.275 0.70355E+04 52 chloritoid-Mn 11.40 7.54 -3.86 -0.258 0.65973E+04 54 coesite -2.38 -3.16 -0.78 -0.260 0.13326E+04 61 cristobalite -2.56 -3.16 -0.60 -0.199 0.10179E+04 63 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71234E+04 65 diaspore 2.87 0.74 -2.14 -0.356 0.36470E+04 66 diamond -3.10 -7.83 -4.73 -1.351 0.80724E+04 67 diopside 16.18 16.08 -0.10 -0.010 0.17346E+03 68 hedenbergite 14.21 13.52 -0.69 -0.069 0.11769E+04 71 enstatite 17.26 12.28 -4.99 -0.499 0.85170E+04 73 clinoenstatite 17.17 12.28 -4.89 -0.489 0.83486E+04 75 epidote 24.67 22.70 -1.97 -0.095 0.33613E+04 76 clinozoisite 22.81 18.94 -3.87 -0.176 0.66019E+04 77 epidote-Fe 29.84 26.46 -3.38 -0.175 0.57673E+04 78 fayalite 14.05 10.31 -3.73 -0.533 0.63756E+04 79 ferrosilite 11.15 7.16 -3.99 -0.399 0.68199E+04 83 gibbsite 4.08 0.74 -3.34 -0.477 0.57056E+04 84 glaucophane 22.97 20.80 -2.17 -0.059 0.37066E+04 85 glaucophane-Fe 17.28 13.12 -4.15 -0.112 0.70930E+04 86 graphite -3.55 -7.83 -4.28 -1.224 0.73146E+04 87 greenalite 16.14 13.89 -2.25 -0.188 0.38419E+04 90 hematite 12.57 9.00 -3.57 -0.432 0.60907E+04 91 heulandite -5.83 -7.52 -1.69 -0.077 0.28938E+04 95 jadeite 4.22 2.77 -1.44 -0.144 0.24633E+04 97 kalsilite 7.58 3.83 -3.76 -0.537 0.64157E+04 98 kaolinite -1.33 -4.84 -3.50 -0.319 0.59841E+04 101 laumontite 2.88 1.95 -0.94 -0.062 0.15982E+04 102 lawsonite 9.62 8.26 -1.36 -0.090 0.23147E+04 103 leucite 4.12 0.67 -3.45 -0.345 0.58888E+04 105 lizardite 23.24 21.57 -1.67 -0.139 0.28551E+04 107 magnetite 20.09 15.73 -4.35 -0.355 0.74346E+04 108 minnesotaite 10.39 7.58 -2.81 -0.165 0.48008E+04 112 manganosite 14.06 9.22 -4.84 -1.210 0.82640E+04 120 muscovite 2.58 -1.01 -3.59 -0.211 0.61356E+04 121 paragonite 4.24 1.09 -3.15 -0.185 0.53747E+04 122 nepheline 8.34 5.93 -2.41 -0.344 0.41156E+04 128 periclase-Fe 11.63 6.73 -4.89 -1.223 0.83537E+04 134 phlogopite-Na 29.65 27.50 -2.15 -0.119 0.36641E+04 136 prehnite 19.37 18.20 -1.17 -0.069 0.19979E+04 137 prehnite-Fe 22.50 21.96 -0.53 -0.032 0.91232E+03 138 pumpellyite-Fe 46.27 43.88 -2.39 -0.053 0.40876E+04 139 pumpellyite-Mg 48.99 46.44 -2.56 -0.057 0.43688E+04 143 pyrrhotite -4.26 -8.06 -3.80 -1.266 0.64853E+04 144 pyrrhotiteFe0.875 -6.02 -9.45 -3.44 -1.264 0.58695E+04 145 pyroxmangite 7.40 6.06 -1.34 -0.267 0.22828E+04 146 pyrophyllite -6.18 -11.15 -4.97 -0.311 0.84940E+04 147 quartz -2.99 -3.16 -0.17 -0.056 0.28525E+03 152 rhodonite 7.45 6.06 -1.38 -0.277 0.23631E+04 153 sanidine -1.28 -2.49 -1.21 -0.093 0.20677E+04 165 stilpnomelane-Mg 27.44 25.82 -1.62 -0.048 0.27673E+04 171 talc 16.49 15.26 -1.23 -0.072 0.21042E+04 174 tephroite 18.09 15.28 -2.81 -0.401 0.47909E+04 178 tridymite -2.63 -3.16 -0.53 -0.177 0.90522E+03 179 tremolite 47.87 47.42 -0.45 -0.012 0.77005E+03 180 ferroactinolite 38.45 34.61 -3.84 -0.104 0.65530E+04 181 troilite-low -4.41 -8.06 -3.65 -1.216 0.62281E+04 183 vesuvianite 223.47 218.75 -4.72 -0.036 0.80648E+04 187 wairakite 3.95 1.95 -2.00 -0.118 0.34201E+04 188 walstromite 11.51 9.94 -1.57 -0.314 0.26771E+04 189 wollastonite 10.46 9.94 -0.52 -0.104 0.88751E+03 190 pseudo-wollastonite 11.00 9.94 -1.06 -0.212 0.18073E+04 191 zoisite 22.85 18.94 -3.91 -0.178 0.66760E+04 192 akaganeite 7.75 4.50 -3.26 -0.704 0.55579E+04 199 chalcedony -2.80 -3.16 -0.35 -0.118 0.60454E+03 201 montmorillonite-Ca -2.29 -6.17 -3.87 -0.240 0.66160E+04 202 montmorillonite-K -2.24 -6.27 -4.03 -0.247 0.68793E+04 203 montmorillonite-Mg -2.48 -6.79 -4.31 -0.267 0.73644E+04 204 montmorillonite-Na -2.04 -5.57 -3.53 -0.216 0.60342E+04 205 nontronite-Ca 3.21 -0.18 -3.40 -0.220 0.57972E+04 206 nontronite-H 2.53 -2.34 -4.87 -0.327 0.83230E+04 207 nontronite-K 3.34 -0.28 -3.62 -0.232 0.61837E+04 208 nontronite-Mg 3.07 -0.81 -3.88 -0.252 0.66297E+04 209 nontronite-Na 3.52 0.41 -3.11 -0.199 0.53046E+04 224 tobermorite 9.82 7.75 -2.07 -0.565 0.35328E+04 230 alabandite -0.98 -5.57 -4.60 -1.532 0.78485E+04 233 boehmite 4.41 0.74 -3.67 -0.611 0.62640E+04 235 ferrous-oxide 9.81 6.73 -3.08 -0.769 0.52546E+04 240 silica-amorphous -2.09 -3.16 -1.07 -0.355 0.18187E+04 242 an20ab80 2.02 1.34 -0.67 -0.052 0.11488E+04 243 an25ab75 2.65 1.78 -0.87 -0.067 0.14829E+04 244 an30ab70 3.28 2.21 -1.07 -0.082 0.18267E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 4.0000000 g Current total amount of reactant added: 159.9990000 g New total amount of reactant added: 163.9990000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.7229E-13 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 11 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 163.9990000 Water: Moles liquid = 0.5451E+02 kg liquid = 0.9820E+00 Moles total = 0.5345E+02 kg total = 0.9630E+00 Activity = 1.0000 Stoichiometric ionic strength = .1131033E-01 Osmotic coef. = 0.9695 True ionic strength = .1999339E-01 Chg. balance for total moles = -.7229E-13 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.88368E-10 -10.0537 0.74257E-10 -10.1293 0.84032E+00 -0.0756 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13986E-03 -3.8543 0.11682E-03 -3.9325 0.83527E+00 -0.0782 4 SO4-- 0.70806E-12 -12.1499 0.36782E-12 -12.4344 0.51948E+00 -0.2844 5 HCO3- 0.26104E-06 -6.5833 0.21836E-06 -6.6608 0.83649E+00 -0.0775 6 HS- 0.25967E-04 -4.5856 0.21693E-04 -4.6637 0.83539E+00 -0.0781 7 Al+++ 0.97002E-29 -29.0132 0.22427E-29 -29.6492 0.23120E+00 -0.6360 8 H4SiO4 0.69668E-03 -3.1570 0.69668E-03 -3.1570 0.10000E+01 0.0000 9 Ca++ 0.13449E-06 -6.8713 0.69351E-07 -7.1589 0.51567E+00 -0.2876 10 Mg++ 0.21175E-10 -10.6742 0.10869E-10 -10.9638 0.51331E+00 -0.2896 11 Fe++ 0.58230E-13 -13.2349 0.29923E-13 -13.5240 0.51387E+00 -0.2891 12 K+ 0.15632E-03 -3.8060 0.13079E-03 -3.8834 0.83669E+00 -0.0774 13 Na+ 0.19836E-01 -1.7025 0.16565E-01 -1.7808 0.83512E+00 -0.0783 14 Mn++ 0.17754E-10 -10.7507 0.91310E-11 -11.0395 0.51430E+00 -0.2888 15 HPO4-- 0.45615E-07 -7.3409 0.23699E-07 -7.6253 0.51955E+00 -0.2844 16 HSiO3- 0.10488E-01 -1.9793 0.87604E-02 -2.0575 0.83527E+00 -0.0782 17 Ca(HSiO3)+ 0.16533E-07 -7.7816 0.13836E-07 -7.8590 0.83687E+00 -0.0773 18 Mg(HSiO3)+ 0.32248E-11 -11.4915 0.26987E-11 -11.5688 0.83687E+00 -0.0773 19 NaHSiO3,aq 0.23471E-02 -2.6295 0.23471E-02 -2.6295 0.10000E+01 0.0000 20 AlO+ 0.66118E-16 -16.1797 0.55332E-16 -16.2570 0.83687E+00 -0.0773 22 HAlO2,aq 0.14839E-09 -9.8286 0.14839E-09 -9.8286 0.10000E+01 0.0000 23 AlO2- 0.53056E-05 -5.2753 0.44236E-05 -5.3542 0.83376E+00 -0.0790 24 CH4,aq 0.12553E-04 -4.9013 0.12510E-04 -4.9028 0.99655E+00 -0.0015 25 C2H6,aq 0.23599E-14 -14.6271 0.23518E-14 -14.6286 0.99655E+00 -0.0015 29 CO,aq 0.99008E-17 -17.0043 0.99008E-17 -17.0043 0.10000E+01 0.0000 30 CO2,aq 0.34767E-10 -10.4588 0.34647E-10 -10.4603 0.99655E+00 -0.0015 31 CO3-2 0.49549E-06 -6.3050 0.25685E-06 -6.5903 0.51837E+00 -0.2854 32 CaCO3,aq 0.22335E-09 -9.6510 0.22335E-09 -9.6510 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.46191E-12 -12.3354 0.38655E-12 -12.4128 0.83687E+00 -0.0773 34 CaCl+ 0.15667E-10 -10.8050 0.13111E-10 -10.8824 0.83687E+00 -0.0773 35 CaCl2,aq 0.36390E-15 -15.4390 0.36390E-15 -15.4390 0.10000E+01 0.0000 36 CaOH+ 0.79536E-07 -7.0994 0.66561E-07 -7.1768 0.83687E+00 -0.0773 37 CaSO4,aq 0.81002E-17 -17.0915 0.81002E-17 -17.0915 0.10000E+01 0.0000 38 HCl,aq 0.15896E-14 -14.7987 0.15896E-14 -14.7987 0.10000E+01 0.0000 43 FeCl+ 0.66116E-17 -17.1797 0.55331E-17 -17.2570 0.83687E+00 -0.0773 46 FeO,aq 0.21091E-09 -9.6759 0.21091E-09 -9.6759 0.10000E+01 0.0000 47 FeOH+ 0.15674E-10 -10.8048 0.13117E-10 -10.8822 0.83687E+00 -0.0773 48 HFeO2- 0.35579E-07 -7.4488 0.29718E-07 -7.5270 0.83527E+00 -0.0782 49 FeO+ 0.11084E-16 -16.9553 0.92762E-17 -17.0326 0.83687E+00 -0.0773 51 FeO2- 0.41212E-09 -9.3850 0.34423E-09 -9.4632 0.83527E+00 -0.0782 52 HFeO2,aq 0.32510E-11 -11.4880 0.32510E-11 -11.4880 0.10000E+01 0.0000 53 H2,aq 0.11415E-04 -4.9425 0.11375E-04 -4.9440 0.99655E+00 -0.0015 54 KCl,aq 0.27692E-09 -9.5576 0.27692E-09 -9.5576 0.10000E+01 0.0000 56 KOH,aq 0.75218E-06 -6.1237 0.75218E-06 -6.1237 0.10000E+01 0.0000 57 KSO4- 0.89373E-15 -15.0488 0.74650E-15 -15.1270 0.83527E+00 -0.0782 58 MgCO3,aq 0.87744E-14 -14.0568 0.87744E-14 -14.0568 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.73973E-16 -16.1309 0.61905E-16 -16.2083 0.83687E+00 -0.0773 60 MgCl+ 0.22255E-14 -14.6526 0.18624E-14 -14.7299 0.83687E+00 -0.0773 61 MgOH+ 0.68978E-10 -10.1613 0.57725E-10 -10.2386 0.83687E+00 -0.0773 63 MnO,aq 0.17149E-08 -8.7658 0.17149E-08 -8.7658 0.10000E+01 0.0000 64 MnOH+ 0.44432E-09 -9.3523 0.37183E-09 -9.4297 0.83687E+00 -0.0773 65 MnO2-2 0.19911E-10 -10.7009 0.10321E-10 -10.9863 0.51837E+00 -0.2854 66 HMnO2- 0.20103E-09 -9.6967 0.16791E-09 -9.7749 0.83527E+00 -0.0782 69 MnCl+ 0.78492E-14 -14.1052 0.65688E-14 -14.1825 0.83687E+00 -0.0773 71 NaCl,aq 0.64134E-06 -6.1929 0.64134E-06 -6.1929 0.10000E+01 0.0000 72 NaOH,aq 0.95847E-04 -4.0184 0.95847E-04 -4.0184 0.10000E+01 0.0000 74 OH- 0.93321E-02 -2.0300 0.77807E-02 -2.1090 0.83376E+00 -0.0790 79 HPO3-2 0.16207E-14 -14.7903 0.84013E-15 -15.0757 0.51837E+00 -0.2854 81 H2PO3- 0.14977E-18 -18.8246 0.12510E-18 -18.9027 0.83527E+00 -0.0782 82 H3PO4,aq 0.91396E-18 -18.0391 0.91396E-18 -18.0391 0.10000E+01 0.0000 83 H2PO4- 0.38830E-10 -10.4108 0.32464E-10 -10.4886 0.83606E+00 -0.0778 84 PO4-3 0.10724E-08 -8.9697 0.26039E-09 -9.5844 0.24282E+00 -0.6147 88 HP2O7-3 0.96014E-18 -18.0177 0.22221E-18 -18.6532 0.23143E+00 -0.6356 89 P2O7-4 0.92592E-17 -17.0334 0.71488E-18 -18.1458 0.77208E-01 -1.1123 90 H2S,aq 0.49957E-08 -8.3014 0.49785E-08 -8.3029 0.99655E+00 -0.0015 91 S2-2 0.17683E-14 -14.7525 0.91662E-15 -15.0378 0.51837E+00 -0.2854 97 SO3-2 0.10340E-17 -17.9855 0.54372E-18 -18.2646 0.52586E+00 -0.2791 99 HSO4- 0.31423E-19 -19.5028 0.26322E-19 -19.5797 0.83768E+00 -0.0769 Charge balance for all species = -.7451E-13 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.8836781E-10 -.2228868E-01 -.2242664E+02 0.0000 2 H2O 0.1000000E+01 0.5550488E+02 0.9982008E+06 0.0000 3 Cl- 0.1398625E-03 0.1405041E-03 0.4972644E+01 6.1968 4 SO4-- 0.7080556E-12 -.1540652E-04 -.1477405E+01 7.8242 5 HCO3- 0.2610432E-06 0.1330966E-04 0.8107080E+00 3.4684 6 HS- 0.2596714E-04 0.4137866E-04 0.1366099E+01 5.4656 7 Al+++ 0.9700175E-29 0.5305743E-05 0.1429083E+00 0.7386 8 H4SiO4 0.6966807E-03 0.1353192E-01 0.1298367E+04 -3.1570 9 Ca++ 0.1344882E-06 0.2307968E-06 0.9233813E-02 13.0996 10 Mg++ 0.2117484E-10 0.9338868E-10 0.2266523E-05 9.2947 11 Fe++ 0.5823017E-13 0.3622087E-07 0.2019315E-02 6.7345 12 K+ 0.1563188E-03 0.1570713E-03 0.6131136E+01 6.2458 13 Na+ 0.1983603E-01 0.2227962E-01 0.5113147E+03 8.3485 14 Mn++ 0.1775439E-10 0.2397918E-08 0.1315081E-03 9.2190 15 HPO4-- 0.4561454E-07 0.4672573E-07 0.4476902E-02 12.6333 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.2715567E+01 -.2188734E-01 -.2693680E+01 0.0000000E+00 2 H2O 0.5345246E+02 0.5450544E+02 -.1052982E+01 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.4570476E-02 -.1512911E-04 0.4585605E-02 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.4544971E-02 0.4063358E-04 -.4585605E-02 0.0000000E+00 7 Al+++ 0.5347584E+00 0.5210206E-05 0.5347532E+00 0.0000000E+00 8 H4SiO4 0.1707686E+01 0.1328826E-01 0.1694398E+01 0.0000000E+00 9 Ca++ 0.1886367E+00 0.2266410E-06 0.1886365E+00 0.0000000E+00 10 Mg++ 0.1301579E+00 0.9170709E-10 0.1301579E+00 0.0000000E+00 11 Fe++ 0.1169327E+00 0.3556867E-07 0.1169327E+00 0.0000000E+00 12 K+ 0.3481932E-01 0.1542430E-03 0.3466508E-01 0.0000000E+00 13 Na+ 0.2060188E+00 0.2187845E-01 0.1841403E+00 0.0000000E+00 14 Mn++ 0.2843512E-02 0.2354741E-08 0.2843510E-02 0.0000000E+00 15 HPO4-- 0.9704766E-03 0.4588437E-07 0.9704308E-03 0.0000000E+00 Chg. balance for solid moles: 0.2992E-16 Mass of aqueous solution: 0.983702E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 163.9990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 0.1839 -0.735 48.22 1.683 26.94 18.51 andradite 0.1834E-01 -1.737 9.321 0.969 5.208 2.422 grossular 0.4402E-02 -2.356 1.983 0.297 1.108 0.5517 apatite-OH 0.3235E-03 -3.490 0.1625 -0.789 0.9079E-01 0.5163E-01 clinochlore 0.2457E-01 -1.610 13.66 1.135 7.630 5.194 daphnite 0.7096E-02 -2.149 5.063 0.704 2.829 1.534 chlorite-Mn 0.5687E-03 -3.245 0.4032 -0.394 0.2253 0.1285 microcline 0.3044E-01 -1.517 8.473 0.928 4.734 3.310 stilbite 0.1147 -0.940 80.87 1.908 45.18 37.72 stilpnomelane-Fe 0.8449E-02 -2.073 9.108 0.959 5.089 3.146 tr.625ac.25prg.125 0.2018E-02 -2.695 1.725 0.237 0.9638 0.5552 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8065E+00 0.8065E+00 1.0000 -0.093 grossular 0.1935E+00 0.1935E+00 1.0000 -0.713 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.7622E+00 0.7622E+00 1.0000 -0.118 daphnite 0.2202E+00 0.2202E+00 1.0000 -0.657 chlorite-Mn 0.1764E-01 0.1764E-01 1.0000 -1.753 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 tr.625ac.25prg.125 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 178.979963 g Volume = 73.120867 cm3 Porosity: -9.7918% V(tot) - V(min): -.65213E+01 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 163.9990000 g log = 2.2148 Original solution: 1000.0103000 g Original solution / Rock added: 6.10 (Water/Rock Ratio), log = 0.7852 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0539 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9686E+00 0.9855 0.1006E+01 0.1021E+01 CO2,gas 0.3493E-08 1.0069 0.3707E-08 0.3681E-08 CH4,gas 0.1726E-01 1.0125 0.1841E-01 0.1819E-01 H2,gas 0.1416E-01 1.0006 0.1493E-01 0.1493E-01 H2S,gas 0.1304E-06 0.9959 0.1369E-06 0.1374E-06 S2,gas 0.2991E-29 1.0000 0.3152E-29 0.3152E-29 CO,gas 0.1400E-13 1.0000 0.1475E-13 0.1475E-13 SO3,gas 0.7277E-48 1.0000 0.7669E-48 0.7669E-48 SO2,gas 0.4228E-27 1.0000 0.4456E-27 0.4456E-27 HCl,gas 0.2662E-17 1.0000 0.2805E-17 0.2805E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 16 albite -0.38 -0.38 0.00 0.000 -0.94784E-12 22 andradite 39.01 39.01 0.00 0.000 0.00000E+00 23 grossular 32.73 32.73 0.00 0.000 -0.12132E-10 32 apatite-OH -18.15 -18.15 0.00 0.000 -0.60662E-11 46 clinochlore 39.07 39.07 0.00 0.000 -0.12132E-10 47 daphnite 28.97 28.97 0.00 0.000 0.00000E+00 48 chlorite-Mn 46.87 46.87 0.00 0.000 0.12132E-10 116 microcline -2.49 -2.49 0.00 0.000 0.15165E-11 163 stilbite -7.52 -7.52 0.00 0.000 -0.90992E-11 164 stilpnomelane-Fe 13.02 13.02 0.00 0.000 0.21232E-10 245 tr.625ac.25prg.125 45.16 45.16 0.00 0.000 0.24265E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -16.79 -10.13 -3.377 0.17297E+05 -8.431 3 CH4,gas 4.54 1.11 -3.43 -0.858 0.58632E+04 -1.735 4 H2,gas 8.00 4.47 -3.52 -2.014 0.60185E+04 -1.826 5 H2S,gas -6.23 -14.79 -8.56 -4.281 0.14621E+05 -6.864 6 S2,gas -7.34 -38.54 -31.20 -4.800 0.53274E+05 -29.501 7 CO,gas 3.21 -12.32 -15.53 -4.778 0.26517E+05 -13.831 8 SO3,gas 17.12 -32.69 -49.81 -12.454 0.85056E+05 -48.115 9 SO2,gas 0.83 -28.22 -29.05 -7.747 0.49602E+05 -27.351 10 HCl,gas 5.19 -14.06 -19.25 -9.626 0.32871E+05 -17.552 11 acmite 7.71 6.53 -1.18 -0.122 0.20116E+04 15 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 19 spessartine 24.46 19.66 -4.79 -0.240 0.81856E+04 20 analcite 3.32 2.77 -0.55 -0.061 0.93700E+03 26 annite 20.12 17.72 -2.41 -0.134 0.41087E+04 27 phlogopite 27.06 25.40 -1.67 -0.093 0.28462E+04 29 anorthite 12.71 8.26 -4.45 -0.342 0.75940E+04 35 aragonite 0.97 -3.69 -4.66 -1.552 0.79518E+04 36 brucite 12.57 9.29 -3.27 -0.655 0.55900E+04 37 calcite 0.81 -3.69 -4.50 -1.501 0.76875E+04 38 carnegieite-low 9.02 5.93 -3.09 -0.442 0.52816E+04 39 carnegieite-high 10.09 5.93 -4.16 -0.595 0.71086E+04 40 carpholite-Mg 8.58 4.46 -4.12 -0.275 0.70419E+04 41 carpholite-Fe 6.71 1.90 -4.81 -0.321 0.82213E+04 42 celadonite 5.34 3.65 -1.69 -0.099 0.28862E+04 43 celadonite-Fe 3.88 1.09 -2.79 -0.164 0.47561E+04 44 chrysotile 23.89 21.57 -2.32 -0.194 0.39650E+04 49 chlorite-Al-free 47.17 43.14 -4.03 -0.168 0.68852E+04 51 chloritoid-Fe 9.17 5.05 -4.12 -0.275 0.70330E+04 52 chloritoid-Mn 11.40 7.54 -3.86 -0.257 0.65940E+04 54 coesite -2.38 -3.16 -0.78 -0.260 0.13334E+04 61 cristobalite -2.56 -3.16 -0.60 -0.199 0.10187E+04 63 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71234E+04 65 diaspore 2.87 0.74 -2.14 -0.356 0.36457E+04 66 diamond -3.10 -7.84 -4.74 -1.354 0.80895E+04 67 diopside 16.18 16.08 -0.10 -0.010 0.17243E+03 68 hedenbergite 14.21 13.52 -0.69 -0.069 0.11749E+04 71 enstatite 17.26 12.28 -4.99 -0.499 0.85192E+04 73 clinoenstatite 17.17 12.28 -4.89 -0.489 0.83508E+04 75 epidote 24.67 22.70 -1.97 -0.095 0.33594E+04 76 clinozoisite 22.81 18.94 -3.86 -0.176 0.65944E+04 77 epidote-Fe 29.84 26.46 -3.38 -0.176 0.57711E+04 78 fayalite 14.05 10.31 -3.73 -0.533 0.63751E+04 79 ferrosilite 11.15 7.16 -3.99 -0.399 0.68202E+04 83 gibbsite 4.08 0.74 -3.34 -0.477 0.57042E+04 84 glaucophane 22.97 20.80 -2.17 -0.059 0.37091E+04 85 glaucophane-Fe 17.28 13.12 -4.15 -0.112 0.70927E+04 86 graphite -3.55 -7.84 -4.29 -1.227 0.73318E+04 87 greenalite 16.14 13.89 -2.25 -0.187 0.38416E+04 90 hematite 12.57 8.99 -3.57 -0.433 0.60993E+04 91 heulandite -5.83 -7.52 -1.69 -0.077 0.28938E+04 95 jadeite 4.22 2.77 -1.44 -0.144 0.24625E+04 97 kalsilite 7.58 3.83 -3.76 -0.537 0.64141E+04 98 kaolinite -1.33 -4.84 -3.50 -0.319 0.59830E+04 101 laumontite 2.88 1.95 -0.93 -0.062 0.15957E+04 102 lawsonite 9.62 8.26 -1.35 -0.090 0.23107E+04 103 leucite 4.12 0.67 -3.45 -0.345 0.58880E+04 105 lizardite 23.24 21.57 -1.67 -0.139 0.28576E+04 107 magnetite 20.09 15.73 -4.36 -0.356 0.74425E+04 108 minnesotaite 10.39 7.58 -2.81 -0.165 0.48021E+04 112 manganosite 14.06 9.22 -4.84 -1.210 0.82626E+04 120 muscovite 2.58 -1.01 -3.59 -0.211 0.61329E+04 121 paragonite 4.24 1.09 -3.15 -0.185 0.53720E+04 122 nepheline 8.34 5.93 -2.41 -0.344 0.41140E+04 128 periclase-Fe 11.63 6.73 -4.89 -1.223 0.83530E+04 134 phlogopite-Na 29.65 27.50 -2.15 -0.119 0.36650E+04 136 prehnite 19.37 18.21 -1.17 -0.069 0.19917E+04 137 prehnite-Fe 22.50 21.96 -0.53 -0.032 0.91179E+03 138 pumpellyite-Fe 46.27 43.88 -2.39 -0.053 0.40733E+04 139 pumpellyite-Mg 48.99 46.44 -2.55 -0.057 0.43554E+04 143 pyrrhotite -4.26 -8.06 -3.80 -1.266 0.64852E+04 144 pyrrhotiteFe0.875 -6.02 -9.46 -3.44 -1.265 0.58706E+04 145 pyroxmangite 7.40 6.06 -1.34 -0.267 0.22822E+04 146 pyrophyllite -6.18 -11.15 -4.97 -0.311 0.84946E+04 147 quartz -2.99 -3.16 -0.17 -0.056 0.28605E+03 152 rhodonite 7.45 6.06 -1.38 -0.277 0.23625E+04 153 sanidine -1.28 -2.49 -1.21 -0.093 0.20677E+04 165 stilpnomelane-Mg 27.44 25.82 -1.62 -0.048 0.27720E+04 171 talc 16.49 15.26 -1.23 -0.073 0.21083E+04 174 tephroite 18.09 15.28 -2.80 -0.401 0.47889E+04 178 tridymite -2.63 -3.16 -0.53 -0.177 0.90603E+03 179 tremolite 47.87 47.42 -0.45 -0.012 0.77210E+03 180 ferroactinolite 38.45 34.62 -3.84 -0.104 0.65504E+04 181 troilite-low -4.41 -8.06 -3.65 -1.216 0.62280E+04 183 vesuvianite 223.47 218.78 -4.69 -0.036 0.80092E+04 187 wairakite 3.95 1.95 -2.00 -0.118 0.34177E+04 188 walstromite 11.51 9.94 -1.57 -0.313 0.26749E+04 189 wollastonite 10.46 9.94 -0.52 -0.104 0.88538E+03 190 pseudo-wollastonite 11.00 9.94 -1.06 -0.211 0.18052E+04 191 zoisite 22.85 18.94 -3.91 -0.178 0.66684E+04 192 akaganeite 7.75 4.50 -3.26 -0.704 0.55622E+04 199 chalcedony -2.80 -3.16 -0.35 -0.118 0.60535E+03 201 montmorillonite-Ca -2.29 -6.17 -3.88 -0.240 0.66165E+04 202 montmorillonite-K -2.24 -6.27 -4.03 -0.247 0.68800E+04 203 montmorillonite-Mg -2.48 -6.79 -4.31 -0.267 0.73655E+04 204 montmorillonite-Na -2.04 -5.57 -3.53 -0.216 0.60349E+04 205 nontronite-Ca 3.21 -0.19 -3.40 -0.221 0.58078E+04 206 nontronite-H 2.53 -2.35 -4.88 -0.327 0.83341E+04 207 nontronite-K 3.34 -0.29 -3.63 -0.233 0.61944E+04 208 nontronite-Mg 3.07 -0.81 -3.89 -0.252 0.66408E+04 209 nontronite-Na 3.52 0.41 -3.11 -0.200 0.53153E+04 224 tobermorite 9.82 7.75 -2.07 -0.564 0.35312E+04 230 alabandite -0.98 -5.57 -4.60 -1.532 0.78476E+04 233 boehmite 4.41 0.74 -3.67 -0.611 0.62626E+04 235 ferrous-oxide 9.81 6.73 -3.08 -0.769 0.52540E+04 240 silica-amorphous -2.09 -3.16 -1.07 -0.355 0.18195E+04 242 an20ab80 2.02 1.35 -0.67 -0.052 0.11480E+04 243 an25ab75 2.65 1.78 -0.87 -0.067 0.14819E+04 244 an30ab70 3.28 2.21 -1.07 -0.082 0.18255E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 4.0000000 g Current total amount of reactant added: 163.9990000 g New total amount of reactant added: 167.9990000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.7164E-13 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 11 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 167.9990000 Water: Moles liquid = 0.5449E+02 kg liquid = 0.9816E+00 Moles total = 0.5340E+02 kg total = 0.9621E+00 Activity = 1.0000 Stoichiometric ionic strength = .1131513E-01 Osmotic coef. = 0.9695 True ionic strength = .2000210E-01 Chg. balance for total moles = -.7164E-13 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.88286E-10 -10.0541 0.74186E-10 -10.1297 0.84029E+00 -0.0756 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13992E-03 -3.8541 0.11687E-03 -3.9323 0.83524E+00 -0.0782 4 SO4-- 0.67418E-12 -12.1712 0.35018E-12 -12.4557 0.51942E+00 -0.2845 5 HCO3- 0.24922E-06 -6.6034 0.20846E-06 -6.6810 0.83646E+00 -0.0776 6 HS- 0.25978E-04 -4.5854 0.21701E-04 -4.6635 0.83537E+00 -0.0781 7 Al+++ 0.96917E-29 -29.0136 0.22402E-29 -29.6497 0.23114E+00 -0.6361 8 H4SiO4 0.69596E-03 -3.1574 0.69596E-03 -3.1574 0.10000E+01 0.0000 9 Ca++ 0.13475E-06 -6.8705 0.69479E-07 -7.1581 0.51561E+00 -0.2877 10 Mg++ 0.21129E-10 -10.6751 0.10844E-10 -10.9648 0.51325E+00 -0.2897 11 Fe++ 0.58174E-13 -13.2353 0.29890E-13 -13.5245 0.51381E+00 -0.2892 12 K+ 0.15639E-03 -3.8058 0.13084E-03 -3.8832 0.83666E+00 -0.0774 13 Na+ 0.19845E-01 -1.7024 0.16572E-01 -1.7806 0.83509E+00 -0.0783 14 Mn++ 0.17755E-10 -10.7507 0.91303E-11 -11.0395 0.51424E+00 -0.2888 15 HPO4-- 0.45422E-07 -7.3427 0.23596E-07 -7.6272 0.51949E+00 -0.2844 16 HSiO3- 0.10488E-01 -1.9793 0.87597E-02 -2.0575 0.83524E+00 -0.0782 17 Ca(HSiO3)+ 0.16563E-07 -7.7809 0.13861E-07 -7.8582 0.83684E+00 -0.0774 18 Mg(HSiO3)+ 0.32173E-11 -11.4925 0.26924E-11 -11.5699 0.83684E+00 -0.0774 19 NaHSiO3,aq 0.23479E-02 -2.6293 0.23479E-02 -2.6293 0.10000E+01 0.0000 20 AlO+ 0.66172E-16 -16.1793 0.55375E-16 -16.2567 0.83684E+00 -0.0774 22 HAlO2,aq 0.14865E-09 -9.8278 0.14865E-09 -9.8278 0.10000E+01 0.0000 23 AlO2- 0.53200E-05 -5.2741 0.44355E-05 -5.3531 0.83374E+00 -0.0790 24 CH4,aq 0.12592E-04 -4.8999 0.12549E-04 -4.9014 0.99655E+00 -0.0015 25 C2H6,aq 0.23449E-14 -14.6299 0.23368E-14 -14.6314 0.99655E+00 -0.0015 29 CO,aq 0.95628E-17 -17.0194 0.95628E-17 -17.0194 0.10000E+01 0.0000 30 CO2,aq 0.33159E-10 -10.4794 0.33045E-10 -10.4809 0.99655E+00 -0.0015 31 CO3-2 0.47353E-06 -6.3247 0.24544E-06 -6.6101 0.51832E+00 -0.2854 32 CaCO3,aq 0.21382E-09 -9.6699 0.21382E-09 -9.6699 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.44179E-12 -12.3548 0.36971E-12 -12.4321 0.83684E+00 -0.0774 34 CaCl+ 0.15702E-10 -10.8040 0.13140E-10 -10.8814 0.83684E+00 -0.0774 35 CaCl2,aq 0.36484E-15 -15.4379 0.36484E-15 -15.4379 0.10000E+01 0.0000 36 CaOH+ 0.79761E-07 -7.0982 0.66748E-07 -7.1756 0.83684E+00 -0.0774 37 CaSO4,aq 0.77260E-17 -17.1120 0.77260E-17 -17.1120 0.10000E+01 0.0000 38 HCl,aq 0.15887E-14 -14.7990 0.15887E-14 -14.7990 0.10000E+01 0.0000 43 FeCl+ 0.66071E-17 -17.1800 0.55291E-17 -17.2573 0.83684E+00 -0.0774 46 FeO,aq 0.21108E-09 -9.6755 0.21108E-09 -9.6755 0.10000E+01 0.0000 47 FeOH+ 0.15672E-10 -10.8049 0.13115E-10 -10.8822 0.83684E+00 -0.0774 48 HFeO2- 0.35643E-07 -7.4480 0.29771E-07 -7.5262 0.83524E+00 -0.0782 49 FeO+ 0.11014E-16 -16.9581 0.92167E-17 -17.0354 0.83684E+00 -0.0774 51 FeO2- 0.41027E-09 -9.3869 0.34267E-09 -9.4651 0.83524E+00 -0.0782 52 HFeO2,aq 0.32332E-11 -11.4904 0.32332E-11 -11.4904 0.10000E+01 0.0000 53 H2,aq 0.11560E-04 -4.9371 0.11520E-04 -4.9386 0.99655E+00 -0.0015 54 KCl,aq 0.27714E-09 -9.5573 0.27714E-09 -9.5573 0.10000E+01 0.0000 56 KOH,aq 0.75321E-06 -6.1231 0.75321E-06 -6.1231 0.10000E+01 0.0000 57 KSO4- 0.85125E-15 -15.0699 0.71100E-15 -15.1481 0.83524E+00 -0.0782 58 MgCO3,aq 0.83655E-14 -14.0775 0.83655E-14 -14.0775 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.70460E-16 -16.1521 0.58964E-16 -16.2294 0.83684E+00 -0.0774 60 MgCl+ 0.22213E-14 -14.6534 0.18589E-14 -14.7307 0.83684E+00 -0.0774 61 MgOH+ 0.68888E-10 -10.1619 0.57649E-10 -10.2392 0.83684E+00 -0.0774 63 MnO,aq 0.17180E-08 -8.7650 0.17180E-08 -8.7650 0.10000E+01 0.0000 64 MnOH+ 0.44472E-09 -9.3519 0.37216E-09 -9.4293 0.83684E+00 -0.0774 65 MnO2-2 0.19988E-10 -10.6992 0.10360E-10 -10.9846 0.51832E+00 -0.2854 66 HMnO2- 0.20159E-09 -9.6955 0.16838E-09 -9.7737 0.83524E+00 -0.0782 69 MnCl+ 0.78517E-14 -14.1050 0.65707E-14 -14.1824 0.83684E+00 -0.0774 71 NaCl,aq 0.64184E-06 -6.1926 0.64184E-06 -6.1926 0.10000E+01 0.0000 72 NaOH,aq 0.95978E-04 -4.0178 0.95978E-04 -4.0178 0.10000E+01 0.0000 74 OH- 0.93413E-02 -2.0296 0.77882E-02 -2.1086 0.83374E+00 -0.0790 79 HPO3-2 0.16343E-14 -14.7867 0.84710E-15 -15.0721 0.51832E+00 -0.2854 81 H2PO3- 0.15088E-18 -18.8214 0.12602E-18 -18.8996 0.83524E+00 -0.0782 82 H3PO4,aq 0.90826E-18 -18.0418 0.90826E-18 -18.0418 0.10000E+01 0.0000 83 H2PO4- 0.38625E-10 -10.4131 0.32292E-10 -10.4909 0.83603E+00 -0.0778 84 PO4-3 0.10690E-08 -8.9710 0.25951E-09 -9.5858 0.24276E+00 -0.6148 88 HP2O7-3 0.95116E-18 -18.0217 0.22007E-18 -18.6574 0.23137E+00 -0.6357 89 P2O7-4 0.91832E-17 -17.0370 0.70869E-18 -18.1495 0.77173E-01 -1.1125 90 H2S,aq 0.49928E-08 -8.3017 0.49756E-08 -8.3032 0.99655E+00 -0.0015 91 S2-2 0.17476E-14 -14.7576 0.90581E-15 -15.0430 0.51832E+00 -0.2854 97 SO3-2 0.99699E-18 -18.0013 0.52422E-18 -18.2805 0.52581E+00 -0.2792 99 HSO4- 0.29888E-19 -19.5245 0.25036E-19 -19.6014 0.83766E+00 -0.0769 Charge balance for all species = -.7458E-13 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.8828586E-10 -.2229836E-01 -.2243638E+02 0.0000 2 H2O 0.1000000E+01 0.5550489E+02 0.9982006E+06 0.0000 3 Cl- 0.1399192E-03 0.1405613E-03 0.4974666E+01 6.1974 4 SO4-- 0.6741819E-12 -.1548197E-04 -.1484640E+01 7.8036 5 HCO3- 0.2492155E-06 0.1331508E-04 0.8110376E+00 3.4487 6 HS- 0.2597771E-04 0.4146468E-04 0.1368938E+01 5.4662 7 Al+++ 0.9691707E-29 0.5320174E-05 0.1432970E+00 0.7393 8 H4SiO4 0.6959626E-03 0.1353148E-01 0.1298325E+04 -3.1574 9 Ca++ 0.1347523E-06 0.2313064E-06 0.9254199E-02 13.1012 10 Mg++ 0.2112897E-10 0.9324510E-10 0.2263038E-05 9.2946 11 Fe++ 0.5817362E-13 0.3628346E-07 0.2022803E-02 6.7349 12 K+ 0.1563869E-03 0.1571404E-03 0.6133834E+01 6.2464 13 Na+ 0.1984469E-01 0.2228919E-01 0.5115341E+03 8.3491 14 Mn++ 0.1775498E-10 0.2402096E-08 0.1317371E-03 9.2198 15 HPO4-- 0.4542174E-07 0.4652936E-07 0.4458086E-02 12.6322 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.2781801E+01 -.2188794E-01 -.2759913E+01 0.0000000E+00 2 H2O 0.5340231E+02 0.5448327E+02 -.1080959E+01 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.4681329E-02 -.1519702E-04 0.4696526E-02 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.4655825E-02 0.4070149E-04 -.4696526E-02 0.0000000E+00 7 Al+++ 0.5478013E+00 0.5222252E-05 0.5477961E+00 0.0000000E+00 8 H4SiO4 0.1749337E+01 0.1328242E-01 0.1736055E+01 0.0000000E+00 9 Ca++ 0.1932373E+00 0.2270490E-06 0.1932371E+00 0.0000000E+00 10 Mg++ 0.1333325E+00 0.9152884E-10 0.1333325E+00 0.0000000E+00 11 Fe++ 0.1197847E+00 0.3561563E-07 0.1197847E+00 0.0000000E+00 12 K+ 0.3566858E-01 0.1542481E-03 0.3551433E-01 0.0000000E+00 13 Na+ 0.2110397E+00 0.2187894E-01 0.1891608E+00 0.0000000E+00 14 Mn++ 0.2912867E-02 0.2357883E-08 0.2912864E-02 0.0000000E+00 15 HPO4-- 0.9941470E-03 0.4567295E-07 0.9941013E-03 0.0000000E+00 Chg. balance for solid moles: -.7242E-16 Mass of aqueous solution: 0.983302E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 167.9990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 0.1889 -0.724 49.53 1.695 27.02 19.01 andradite 0.1879E-01 -1.726 9.547 0.980 5.207 2.480 grossular 0.4541E-02 -2.343 2.046 0.311 1.116 0.5692 apatite-OH 0.3314E-03 -3.480 0.1665 -0.779 0.9079E-01 0.5289E-01 clinochlore 0.2511E-01 -1.600 13.96 1.145 7.613 5.309 daphnite 0.7262E-02 -2.139 5.182 0.714 2.826 1.570 chlorite-Mn 0.5826E-03 -3.235 0.4130 -0.384 0.2253 0.1316 microcline 0.3119E-01 -1.506 8.682 0.939 4.735 3.391 stilbite 0.1173 -0.931 82.67 1.917 45.09 38.56 stilpnomelane-Fe 0.8644E-02 -2.063 9.319 0.969 5.082 3.219 tr.625ac.25prg.125 0.2144E-02 -2.669 1.832 0.263 0.9994 0.5898 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8053E+00 0.8053E+00 1.0000 -0.094 grossular 0.1947E+00 0.1947E+00 1.0000 -0.711 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.7620E+00 0.7620E+00 1.0000 -0.118 daphnite 0.2204E+00 0.2204E+00 1.0000 -0.657 chlorite-Mn 0.1768E-01 0.1768E-01 1.0000 -1.753 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 tr.625ac.25prg.125 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 183.347453 g Volume = 74.886958 cm3 Porosity: -9.8056% V(tot) - V(min): -.66874E+01 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 167.9990000 g log = 2.2253 Original solution: 1000.0103000 g Original solution / Rock added: 5.95 (Water/Rock Ratio), log = 0.7747 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0541 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9684E+00 0.9855 0.1006E+01 0.1021E+01 CO2,gas 0.3331E-08 1.0069 0.3535E-08 0.3511E-08 CH4,gas 0.1731E-01 1.0125 0.1847E-01 0.1824E-01 H2,gas 0.1434E-01 1.0006 0.1512E-01 0.1512E-01 H2S,gas 0.1303E-06 0.9959 0.1368E-06 0.1373E-06 S2,gas 0.2912E-29 1.0000 0.3070E-29 0.3070E-29 CO,gas 0.1352E-13 1.0000 0.1425E-13 0.1425E-13 SO3,gas 0.6913E-48 1.0000 0.7287E-48 0.7287E-48 SO2,gas 0.4068E-27 1.0000 0.4288E-27 0.4288E-27 HCl,gas 0.2659E-17 1.0000 0.2803E-17 0.2803E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 16 albite -0.38 -0.38 0.00 0.000 -0.94784E-12 22 andradite 39.01 39.01 0.00 0.000 0.00000E+00 23 grossular 32.73 32.73 0.00 0.000 -0.12132E-10 32 apatite-OH -18.15 -18.15 0.00 0.000 0.60662E-11 46 clinochlore 39.07 39.07 0.00 0.000 -0.24265E-10 47 daphnite 28.97 28.97 0.00 0.000 0.42463E-10 48 chlorite-Mn 46.87 46.87 0.00 0.000 -0.24265E-10 116 microcline -2.49 -2.49 0.00 0.000 -0.10616E-10 163 stilbite -7.52 -7.52 0.00 0.000 -0.90992E-11 164 stilpnomelane-Fe 13.02 13.02 0.00 0.000 0.21232E-10 245 tr.625ac.25prg.125 45.16 45.16 0.00 0.000 0.24265E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -16.81 -10.15 -3.384 0.17332E+05 -8.452 3 CH4,gas 4.54 1.11 -3.43 -0.858 0.58609E+04 -1.734 4 H2,gas 8.00 4.48 -3.52 -2.011 0.60091E+04 -1.820 5 H2S,gas -6.23 -14.79 -8.56 -4.281 0.14621E+05 -6.864 6 S2,gas -7.34 -38.55 -31.21 -4.802 0.53293E+05 -29.513 7 CO,gas 3.21 -12.33 -15.55 -4.783 0.26543E+05 -13.846 8 SO3,gas 17.12 -32.72 -49.84 -12.459 0.85094E+05 -48.137 9 SO2,gas 0.83 -28.23 -29.07 -7.751 0.49631E+05 -27.368 10 HCl,gas 5.19 -14.06 -19.25 -9.626 0.32871E+05 -17.552 11 acmite 7.71 6.53 -1.18 -0.123 0.20162E+04 15 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 19 spessartine 24.46 19.67 -4.79 -0.240 0.81812E+04 20 analcite 3.32 2.77 -0.55 -0.061 0.93623E+03 26 annite 20.12 17.72 -2.41 -0.134 0.41069E+04 27 phlogopite 27.06 25.40 -1.67 -0.093 0.28470E+04 29 anorthite 12.71 8.27 -4.45 -0.342 0.75902E+04 35 aragonite 0.97 -3.71 -4.68 -1.559 0.79841E+04 36 brucite 12.57 9.29 -3.27 -0.655 0.55903E+04 37 calcite 0.81 -3.71 -4.52 -1.507 0.77199E+04 38 carnegieite-low 9.02 5.93 -3.09 -0.442 0.52801E+04 39 carnegieite-high 10.09 5.93 -4.16 -0.595 0.71071E+04 40 carpholite-Mg 8.58 4.46 -4.12 -0.275 0.70411E+04 41 carpholite-Fe 6.71 1.90 -4.81 -0.321 0.82197E+04 42 celadonite 5.34 3.65 -1.69 -0.099 0.28872E+04 43 celadonite-Fe 3.88 1.09 -2.79 -0.164 0.47562E+04 44 chrysotile 23.89 21.57 -2.32 -0.194 0.39674E+04 49 chlorite-Al-free 47.17 43.14 -4.04 -0.168 0.68899E+04 51 chloritoid-Fe 9.17 5.06 -4.12 -0.275 0.70305E+04 52 chloritoid-Mn 11.40 7.54 -3.86 -0.257 0.65909E+04 54 coesite -2.38 -3.16 -0.78 -0.260 0.13341E+04 61 cristobalite -2.56 -3.16 -0.60 -0.199 0.10195E+04 63 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71234E+04 65 diaspore 2.87 0.74 -2.13 -0.356 0.36444E+04 66 diamond -3.10 -7.85 -4.75 -1.356 0.81059E+04 67 diopside 16.18 16.08 -0.10 -0.010 0.17145E+03 68 hedenbergite 14.21 13.52 -0.69 -0.069 0.11730E+04 71 enstatite 17.26 12.27 -4.99 -0.499 0.85213E+04 73 clinoenstatite 17.17 12.27 -4.89 -0.489 0.83529E+04 75 epidote 24.67 22.70 -1.97 -0.095 0.33577E+04 76 clinozoisite 22.81 18.95 -3.86 -0.175 0.65873E+04 77 epidote-Fe 29.84 26.46 -3.38 -0.176 0.57747E+04 78 fayalite 14.05 10.31 -3.73 -0.533 0.63746E+04 79 ferrosilite 11.15 7.15 -3.99 -0.399 0.68205E+04 83 gibbsite 4.08 0.74 -3.34 -0.477 0.57029E+04 84 glaucophane 22.97 20.80 -2.17 -0.059 0.37115E+04 85 glaucophane-Fe 17.28 13.12 -4.15 -0.112 0.70924E+04 86 graphite -3.55 -7.85 -4.30 -1.230 0.73482E+04 87 greenalite 16.14 13.89 -2.25 -0.187 0.38413E+04 90 hematite 12.57 8.99 -3.58 -0.434 0.61074E+04 91 heulandite -5.83 -7.52 -1.69 -0.077 0.28938E+04 95 jadeite 4.22 2.77 -1.44 -0.144 0.24617E+04 97 kalsilite 7.58 3.83 -3.76 -0.537 0.64125E+04 98 kaolinite -1.33 -4.84 -3.50 -0.318 0.59820E+04 101 laumontite 2.88 1.95 -0.93 -0.062 0.15935E+04 102 lawsonite 9.62 8.27 -1.35 -0.090 0.23069E+04 103 leucite 4.12 0.67 -3.45 -0.345 0.58873E+04 105 lizardite 23.24 21.57 -1.67 -0.140 0.28600E+04 107 magnetite 20.09 15.72 -4.36 -0.356 0.74500E+04 108 minnesotaite 10.39 7.58 -2.81 -0.165 0.48033E+04 112 manganosite 14.06 9.22 -4.84 -1.210 0.82612E+04 120 muscovite 2.58 -1.01 -3.59 -0.211 0.61303E+04 121 paragonite 4.24 1.09 -3.14 -0.185 0.53694E+04 122 nepheline 8.34 5.93 -2.41 -0.344 0.41124E+04 128 periclase-Fe 11.63 6.73 -4.89 -1.223 0.83524E+04 134 phlogopite-Na 29.65 27.50 -2.15 -0.119 0.36658E+04 136 prehnite 19.37 18.21 -1.16 -0.068 0.19859E+04 137 prehnite-Fe 22.50 21.96 -0.53 -0.032 0.91130E+03 138 pumpellyite-Fe 46.27 43.89 -2.38 -0.053 0.40597E+04 139 pumpellyite-Mg 48.99 46.45 -2.54 -0.057 0.43427E+04 143 pyrrhotite -4.26 -8.06 -3.80 -1.266 0.64850E+04 144 pyrrhotiteFe0.875 -6.02 -9.46 -3.44 -1.265 0.58717E+04 145 pyroxmangite 7.40 6.06 -1.34 -0.267 0.22816E+04 146 pyrophyllite -6.18 -11.15 -4.98 -0.311 0.84951E+04 147 quartz -2.99 -3.16 -0.17 -0.056 0.28682E+03 152 rhodonite 7.45 6.06 -1.38 -0.277 0.23619E+04 153 sanidine -1.28 -2.49 -1.21 -0.093 0.20677E+04 165 stilpnomelane-Mg 27.44 25.82 -1.63 -0.049 0.27764E+04 171 talc 16.49 15.25 -1.24 -0.073 0.21122E+04 174 tephroite 18.09 15.28 -2.80 -0.401 0.47869E+04 178 tridymite -2.63 -3.16 -0.53 -0.177 0.90680E+03 179 tremolite 47.87 47.42 -0.45 -0.012 0.77404E+03 180 ferroactinolite 38.45 34.62 -3.83 -0.104 0.65479E+04 181 troilite-low -4.41 -8.06 -3.65 -1.216 0.62278E+04 183 vesuvianite 223.47 218.81 -4.66 -0.036 0.79565E+04 187 wairakite 3.95 1.95 -2.00 -0.118 0.34154E+04 188 walstromite 11.51 9.94 -1.57 -0.313 0.26729E+04 189 wollastonite 10.46 9.94 -0.52 -0.103 0.88336E+03 190 pseudo-wollastonite 11.00 9.94 -1.06 -0.211 0.18032E+04 191 zoisite 22.85 18.95 -3.90 -0.177 0.66613E+04 192 akaganeite 7.75 4.49 -3.26 -0.705 0.55662E+04 199 chalcedony -2.80 -3.16 -0.35 -0.118 0.60612E+03 201 montmorillonite-Ca -2.29 -6.17 -3.88 -0.240 0.66171E+04 202 montmorillonite-K -2.24 -6.27 -4.03 -0.247 0.68807E+04 203 montmorillonite-Mg -2.48 -6.79 -4.31 -0.267 0.73666E+04 204 montmorillonite-Na -2.04 -5.57 -3.53 -0.216 0.60356E+04 205 nontronite-Ca 3.21 -0.19 -3.41 -0.221 0.58178E+04 206 nontronite-H 2.53 -2.35 -4.89 -0.328 0.83446E+04 207 nontronite-K 3.34 -0.29 -3.63 -0.233 0.62046E+04 208 nontronite-Mg 3.07 -0.82 -3.90 -0.253 0.66514E+04 209 nontronite-Na 3.52 0.40 -3.12 -0.200 0.53255E+04 224 tobermorite 9.82 7.76 -2.07 -0.564 0.35296E+04 230 alabandite -0.98 -5.57 -4.60 -1.532 0.78467E+04 233 boehmite 4.41 0.74 -3.67 -0.611 0.62613E+04 235 ferrous-oxide 9.81 6.73 -3.08 -0.769 0.52534E+04 240 silica-amorphous -2.09 -3.16 -1.07 -0.355 0.18203E+04 242 an20ab80 2.02 1.35 -0.67 -0.052 0.11472E+04 243 an25ab75 2.65 1.78 -0.87 -0.067 0.14810E+04 244 an30ab70 3.28 2.21 -1.07 -0.082 0.18243E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 4.0000000 g Current total amount of reactant added: 167.9990000 g New total amount of reactant added: 171.9990000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.7172E-13 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 11 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 171.9990000 Water: Moles liquid = 0.5446E+02 kg liquid = 0.9812E+00 Moles total = 0.5335E+02 kg total = 0.9612E+00 Activity = 1.0000 Stoichiometric ionic strength = .1131970E-01 Osmotic coef. = 0.9695 True ionic strength = .2001037E-01 Chg. balance for total moles = -.7172E-13 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.88208E-10 -10.0545 0.74119E-10 -10.1301 0.84027E+00 -0.0756 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13998E-03 -3.8539 0.11691E-03 -3.9321 0.83522E+00 -0.0782 4 SO4-- 0.64350E-12 -12.1915 0.33421E-12 -12.4760 0.51936E+00 -0.2845 5 HCO3- 0.23845E-06 -6.6226 0.19945E-06 -6.7002 0.83644E+00 -0.0776 6 HS- 0.25988E-04 -4.5852 0.21709E-04 -4.6634 0.83534E+00 -0.0781 7 Al+++ 0.96837E-29 -29.0140 0.22378E-29 -29.6502 0.23109E+00 -0.6362 8 H4SiO4 0.69528E-03 -3.1578 0.69528E-03 -3.1578 0.10000E+01 0.0000 9 Ca++ 0.13500E-06 -6.8697 0.69601E-07 -7.1574 0.51555E+00 -0.2877 10 Mg++ 0.21086E-10 -10.6760 0.10821E-10 -10.9657 0.51319E+00 -0.2897 11 Fe++ 0.58120E-13 -13.2357 0.29859E-13 -13.5249 0.51375E+00 -0.2892 12 K+ 0.15645E-03 -3.8056 0.13089E-03 -3.8831 0.83664E+00 -0.0775 13 Na+ 0.19853E-01 -1.7022 0.16579E-01 -1.7805 0.83507E+00 -0.0783 14 Mn++ 0.17756E-10 -10.7507 0.91297E-11 -11.0395 0.51418E+00 -0.2889 15 HPO4-- 0.45240E-07 -7.3445 0.23499E-07 -7.6290 0.51943E+00 -0.2845 16 HSiO3- 0.10487E-01 -1.9793 0.87591E-02 -2.0575 0.83522E+00 -0.0782 17 Ca(HSiO3)+ 0.16591E-07 -7.7801 0.13884E-07 -7.8575 0.83682E+00 -0.0774 18 Mg(HSiO3)+ 0.32102E-11 -11.4935 0.26863E-11 -11.5708 0.83682E+00 -0.0774 19 NaHSiO3,aq 0.23486E-02 -2.6292 0.23486E-02 -2.6292 0.10000E+01 0.0000 20 AlO+ 0.66222E-16 -16.1790 0.55416E-16 -16.2564 0.83682E+00 -0.0774 22 HAlO2,aq 0.14890E-09 -9.8271 0.14890E-09 -9.8271 0.10000E+01 0.0000 23 AlO2- 0.53338E-05 -5.2730 0.44468E-05 -5.3520 0.83371E+00 -0.0790 24 CH4,aq 0.12628E-04 -4.8987 0.12585E-04 -4.9002 0.99655E+00 -0.0015 25 C2H6,aq 0.23303E-14 -14.6326 0.23223E-14 -14.6341 0.99655E+00 -0.0015 29 CO,aq 0.92514E-17 -17.0338 0.92514E-17 -17.0338 0.10000E+01 0.0000 30 CO2,aq 0.31697E-10 -10.4990 0.31587E-10 -10.5005 0.99655E+00 -0.0015 31 CO3-2 0.45352E-06 -6.3434 0.23504E-06 -6.6289 0.51826E+00 -0.2855 32 CaCO3,aq 0.20513E-09 -9.6880 0.20513E-09 -9.6880 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.42344E-12 -12.3732 0.35435E-12 -12.4506 0.83682E+00 -0.0774 34 CaCl+ 0.15736E-10 -10.8031 0.13168E-10 -10.8805 0.83682E+00 -0.0774 35 CaCl2,aq 0.36576E-15 -15.4368 0.36576E-15 -15.4368 0.10000E+01 0.0000 36 CaOH+ 0.79976E-07 -7.0970 0.66925E-07 -7.1744 0.83682E+00 -0.0774 37 CaSO4,aq 0.73865E-17 -17.1316 0.73865E-17 -17.1316 0.10000E+01 0.0000 38 HCl,aq 0.15879E-14 -14.7992 0.15879E-14 -14.7992 0.10000E+01 0.0000 43 FeCl+ 0.66030E-17 -17.1803 0.55255E-17 -17.2576 0.83682E+00 -0.0774 46 FeO,aq 0.21125E-09 -9.6752 0.21125E-09 -9.6752 0.10000E+01 0.0000 47 FeOH+ 0.15671E-10 -10.8049 0.13113E-10 -10.8823 0.83682E+00 -0.0774 48 HFeO2- 0.35704E-07 -7.4473 0.29821E-07 -7.5255 0.83522E+00 -0.0782 49 FeO+ 0.10947E-16 -16.9607 0.91604E-17 -17.0381 0.83682E+00 -0.0774 51 FeO2- 0.40851E-09 -9.3888 0.34120E-09 -9.4670 0.83522E+00 -0.0782 52 HFeO2,aq 0.32164E-11 -11.4926 0.32164E-11 -11.4926 0.10000E+01 0.0000 53 H2,aq 0.11699E-04 -4.9318 0.11659E-04 -4.9333 0.99655E+00 -0.0015 54 KCl,aq 0.27735E-09 -9.5570 0.27735E-09 -9.5570 0.10000E+01 0.0000 56 KOH,aq 0.75418E-06 -6.1225 0.75418E-06 -6.1225 0.10000E+01 0.0000 57 KSO4- 0.81276E-15 -15.0900 0.67883E-15 -15.1682 0.83522E+00 -0.0782 58 MgCO3,aq 0.79937E-14 -14.0973 0.79937E-14 -14.0973 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.67269E-16 -16.1722 0.56292E-16 -16.2496 0.83682E+00 -0.0774 60 MgCl+ 0.22174E-14 -14.6542 0.18556E-14 -14.7315 0.83682E+00 -0.0774 61 MgOH+ 0.68803E-10 -10.1624 0.57576E-10 -10.2398 0.83682E+00 -0.0774 63 MnO,aq 0.17210E-08 -8.7642 0.17210E-08 -8.7642 0.10000E+01 0.0000 64 MnOH+ 0.44510E-09 -9.3515 0.37247E-09 -9.4289 0.83682E+00 -0.0774 65 MnO2-2 0.20061E-10 -10.6976 0.10397E-10 -10.9831 0.51826E+00 -0.2855 66 HMnO2- 0.20214E-09 -9.6944 0.16883E-09 -9.7726 0.83522E+00 -0.0782 69 MnCl+ 0.78544E-14 -14.1049 0.65727E-14 -14.1823 0.83682E+00 -0.0774 71 NaCl,aq 0.64233E-06 -6.1922 0.64233E-06 -6.1922 0.10000E+01 0.0000 72 NaOH,aq 0.96102E-04 -4.0173 0.96102E-04 -4.0173 0.10000E+01 0.0000 74 OH- 0.93500E-02 -2.0292 0.77952E-02 -2.1082 0.83371E+00 -0.0790 79 HPO3-2 0.16474E-14 -14.7832 0.85379E-15 -15.0686 0.51826E+00 -0.2855 81 H2PO3- 0.15193E-18 -18.8183 0.12690E-18 -18.8965 0.83522E+00 -0.0782 82 H3PO4,aq 0.90288E-18 -18.0444 0.90288E-18 -18.0444 0.10000E+01 0.0000 83 H2PO4- 0.38432E-10 -10.4153 0.32130E-10 -10.4931 0.83601E+00 -0.0778 84 PO4-3 0.10658E-08 -8.9723 0.25867E-09 -9.5872 0.24270E+00 -0.6149 88 HP2O7-3 0.94272E-18 -18.0256 0.21807E-18 -18.6614 0.23132E+00 -0.6358 89 P2O7-4 0.91116E-17 -17.0404 0.70287E-18 -18.1531 0.77140E-01 -1.1127 90 H2S,aq 0.49902E-08 -8.3019 0.49730E-08 -8.3034 0.99655E+00 -0.0015 91 S2-2 0.17283E-14 -14.7624 0.89569E-15 -15.0478 0.51826E+00 -0.2855 97 SO3-2 0.96309E-18 -18.0163 0.50635E-18 -18.2955 0.52575E+00 -0.2792 99 HSO4- 0.28500E-19 -19.5452 0.23872E-19 -19.6221 0.83763E+00 -0.0769 Charge balance for all species = -.7407E-13 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.8820818E-10 -.2230756E-01 -.2244562E+02 0.0000 2 H2O 0.1000000E+01 0.5550490E+02 0.9982005E+06 0.0000 3 Cl- 0.1399759E-03 0.1406186E-03 0.4976690E+01 6.1979 4 SO4-- 0.6435010E-12 -.1555305E-04 -.1491456E+01 7.7842 5 HCO3- 0.2384480E-06 0.1332050E-04 0.8113676E+00 3.4299 6 HS- 0.2598829E-04 0.4154634E-04 0.1371634E+01 5.4667 7 Al+++ 0.9683681E-29 0.5333899E-05 0.1436666E+00 0.7400 8 H4SiO4 0.6952821E-03 0.1353107E-01 0.1298285E+04 -3.1578 9 Ca++ 0.1350034E-06 0.2317916E-06 0.9273608E-02 13.1028 10 Mg++ 0.2108553E-10 0.9310900E-10 0.2259734E-05 9.2944 11 Fe++ 0.5812005E-13 0.3634296E-07 0.2026120E-02 6.7352 12 K+ 0.1564517E-03 0.1572061E-03 0.6136397E+01 6.2470 13 Na+ 0.1985291E-01 0.2229828E-01 0.5117426E+03 8.3496 14 Mn++ 0.1775581E-10 0.2406103E-08 0.1319569E-03 9.2206 15 HPO4-- 0.4523953E-07 0.4634376E-07 0.4440301E-02 12.6312 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.2848035E+01 -.2188806E-01 -.2826147E+01 0.0000000E+00 2 H2O 0.5335217E+02 0.5446111E+02 -.1108937E+01 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.4792183E-02 -.1526057E-04 0.4807444E-02 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.4766679E-02 0.4076504E-04 -.4807444E-02 0.0000000E+00 7 Al+++ 0.5608443E+00 0.5233594E-05 0.5608391E+00 0.0000000E+00 8 H4SiO4 0.1790988E+01 0.1327662E-01 0.1777712E+01 0.0000000E+00 9 Ca++ 0.1978379E+00 0.2274327E-06 0.1978376E+00 0.0000000E+00 10 Mg++ 0.1365071E+00 0.9135806E-10 0.1365071E+00 0.0000000E+00 11 Fe++ 0.1226368E+00 0.3565952E-07 0.1226367E+00 0.0000000E+00 12 K+ 0.3651783E-01 0.1542498E-03 0.3636358E-01 0.0000000E+00 13 Na+ 0.2160607E+00 0.2187895E-01 0.1941818E+00 0.0000000E+00 14 Mn++ 0.2982221E-02 0.2360855E-08 0.2982219E-02 0.0000000E+00 15 HPO4-- 0.1017817E-02 0.4547225E-07 0.1017772E-02 0.0000000E+00 Chg. balance for solid moles: 0.6922E-15 Mass of aqueous solution: 0.982902E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 171.9990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 0.1939 -0.712 50.84 1.706 27.09 19.52 andradite 0.1923E-01 -1.716 9.772 0.990 5.206 2.539 grossular 0.4680E-02 -2.330 2.108 0.324 1.123 0.5866 apatite-OH 0.3393E-03 -3.469 0.1704 -0.768 0.9078E-01 0.5415E-01 clinochlore 0.2566E-01 -1.591 14.26 1.154 7.597 5.424 daphnite 0.7428E-02 -2.129 5.300 0.724 2.823 1.606 chlorite-Mn 0.5964E-03 -3.224 0.4229 -0.374 0.2253 0.1348 microcline 0.3194E-01 -1.496 8.891 0.949 4.737 3.473 stilbite 0.1199 -0.921 84.48 1.927 45.00 39.40 stilpnomelane-Fe 0.8840E-02 -2.054 9.530 0.979 5.077 3.292 tr.625ac.25prg.125 0.2269E-02 -2.644 1.940 0.288 1.033 0.6243 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8043E+00 0.8043E+00 1.0000 -0.095 grossular 0.1957E+00 0.1957E+00 1.0000 -0.708 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.7618E+00 0.7618E+00 1.0000 -0.118 daphnite 0.2205E+00 0.2205E+00 1.0000 -0.657 chlorite-Mn 0.1771E-01 0.1771E-01 1.0000 -1.752 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 tr.625ac.25prg.125 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 187.714920 g Volume = 76.653019 cm3 Porosity: -9.8187% V(tot) - V(min): -.68534E+01 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 171.9990000 g log = 2.2355 Original solution: 1000.0103000 g Original solution / Rock added: 5.81 (Water/Rock Ratio), log = 0.7645 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0544 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9681E+00 0.9855 0.1006E+01 0.1021E+01 CO2,gas 0.3183E-08 1.0069 0.3380E-08 0.3356E-08 CH4,gas 0.1735E-01 1.0125 0.1852E-01 0.1830E-01 H2,gas 0.1451E-01 1.0006 0.1531E-01 0.1530E-01 H2S,gas 0.1302E-06 0.9959 0.1367E-06 0.1373E-06 S2,gas 0.2840E-29 1.0000 0.2994E-29 0.2994E-29 CO,gas 0.1308E-13 1.0000 0.1379E-13 0.1379E-13 SO3,gas 0.6584E-48 1.0000 0.6942E-48 0.6942E-48 SO2,gas 0.3921E-27 1.0000 0.4134E-27 0.4134E-27 HCl,gas 0.2657E-17 1.0000 0.2802E-17 0.2802E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 16 albite -0.38 -0.38 0.00 0.000 -0.94784E-12 22 andradite 39.01 39.01 0.00 0.000 0.12132E-10 23 grossular 32.73 32.73 0.00 0.000 0.00000E+00 32 apatite-OH -18.15 -18.15 0.00 0.000 -0.60662E-11 46 clinochlore 39.07 39.07 0.00 0.000 -0.24265E-10 47 daphnite 28.97 28.97 0.00 0.000 -0.60662E-11 48 chlorite-Mn 46.87 46.87 0.00 0.000 0.00000E+00 116 microcline -2.49 -2.49 0.00 0.000 0.15165E-11 163 stilbite -7.52 -7.52 0.00 0.000 0.15165E-10 164 stilpnomelane-Fe 13.02 13.02 0.00 0.000 -0.75827E-10 245 tr.625ac.25prg.125 45.16 45.16 0.00 0.000 0.48529E-10 67 diopside 16.18 16.08 -0.10 -0.010 0.17052E+03 68 hedenbergite 14.21 13.52 -0.69 -0.069 0.11713E+04 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -16.83 -10.17 -3.390 0.17365E+05 -8.471 3 CH4,gas 4.54 1.11 -3.43 -0.858 0.58587E+04 -1.732 4 H2,gas 8.00 4.49 -3.51 -2.008 0.60002E+04 -1.815 5 H2S,gas -6.23 -14.79 -8.56 -4.282 0.14621E+05 -6.864 6 S2,gas -7.34 -38.56 -31.22 -4.803 0.53312E+05 -29.524 7 CO,gas 3.21 -12.34 -15.56 -4.788 0.26567E+05 -13.861 8 SO3,gas 17.12 -32.74 -49.86 -12.464 0.85130E+05 -48.159 9 SO2,gas 0.83 -28.25 -29.08 -7.755 0.49658E+05 -27.384 10 HCl,gas 5.19 -14.06 -19.25 -9.626 0.32871E+05 -17.553 11 acmite 7.71 6.53 -1.18 -0.123 0.20206E+04 15 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 19 spessartine 24.46 19.67 -4.79 -0.239 0.81771E+04 20 analcite 3.32 2.77 -0.55 -0.061 0.93551E+03 26 annite 20.12 17.72 -2.40 -0.134 0.41051E+04 27 phlogopite 27.06 25.40 -1.67 -0.093 0.28478E+04 29 anorthite 12.71 8.27 -4.44 -0.342 0.75866E+04 35 aragonite 0.97 -3.73 -4.69 -1.565 0.80149E+04 36 brucite 12.57 9.29 -3.27 -0.655 0.55905E+04 37 calcite 0.81 -3.73 -4.54 -1.513 0.77507E+04 38 carnegieite-low 9.02 5.93 -3.09 -0.442 0.52786E+04 39 carnegieite-high 10.09 5.93 -4.16 -0.594 0.71056E+04 40 carpholite-Mg 8.58 4.46 -4.12 -0.275 0.70404E+04 41 carpholite-Fe 6.71 1.90 -4.81 -0.321 0.82181E+04 42 celadonite 5.34 3.65 -1.69 -0.100 0.28882E+04 43 celadonite-Fe 3.88 1.09 -2.79 -0.164 0.47564E+04 44 chrysotile 23.89 21.57 -2.32 -0.194 0.39696E+04 49 chlorite-Al-free 47.17 43.14 -4.04 -0.168 0.68944E+04 51 chloritoid-Fe 9.17 5.06 -4.12 -0.274 0.70283E+04 52 chloritoid-Mn 11.40 7.54 -3.86 -0.257 0.65879E+04 54 coesite -2.38 -3.16 -0.78 -0.261 0.13349E+04 61 cristobalite -2.56 -3.16 -0.60 -0.199 0.10202E+04 63 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71234E+04 65 diaspore 2.87 0.74 -2.13 -0.356 0.36432E+04 66 diamond -3.10 -7.86 -4.76 -1.359 0.81216E+04 71 enstatite 17.26 12.27 -4.99 -0.499 0.85233E+04 73 clinoenstatite 17.17 12.27 -4.89 -0.489 0.83549E+04 75 epidote 24.67 22.70 -1.97 -0.095 0.33560E+04 76 clinozoisite 22.81 18.95 -3.85 -0.175 0.65805E+04 77 epidote-Fe 29.84 26.46 -3.38 -0.176 0.57781E+04 78 fayalite 14.05 10.31 -3.73 -0.533 0.63742E+04 79 ferrosilite 11.15 7.15 -3.99 -0.399 0.68208E+04 83 gibbsite 4.08 0.74 -3.34 -0.477 0.57017E+04 84 glaucophane 22.97 20.80 -2.17 -0.059 0.37137E+04 85 glaucophane-Fe 17.28 13.12 -4.15 -0.112 0.70921E+04 86 graphite -3.55 -7.86 -4.31 -1.232 0.73638E+04 87 greenalite 16.14 13.89 -2.25 -0.187 0.38410E+04 90 hematite 12.57 8.98 -3.58 -0.434 0.61152E+04 91 heulandite -5.83 -7.52 -1.69 -0.077 0.28938E+04 95 jadeite 4.22 2.77 -1.44 -0.144 0.24610E+04 97 kalsilite 7.58 3.83 -3.75 -0.536 0.64111E+04 98 kaolinite -1.33 -4.84 -3.50 -0.318 0.59810E+04 101 laumontite 2.88 1.95 -0.93 -0.062 0.15913E+04 102 lawsonite 9.62 8.27 -1.35 -0.090 0.23033E+04 103 leucite 4.12 0.67 -3.45 -0.345 0.58865E+04 105 lizardite 23.24 21.57 -1.68 -0.140 0.28622E+04 107 magnetite 20.09 15.72 -4.37 -0.357 0.74572E+04 108 minnesotaite 10.39 7.57 -2.81 -0.166 0.48045E+04 112 manganosite 14.06 9.22 -4.84 -1.209 0.82599E+04 120 muscovite 2.58 -1.01 -3.59 -0.211 0.61279E+04 121 paragonite 4.24 1.10 -3.14 -0.185 0.53670E+04 122 nepheline 8.34 5.93 -2.41 -0.344 0.41110E+04 128 periclase-Fe 11.63 6.74 -4.89 -1.223 0.83519E+04 134 phlogopite-Na 29.65 27.50 -2.15 -0.119 0.36666E+04 136 prehnite 19.37 18.21 -1.16 -0.068 0.19804E+04 137 prehnite-Fe 22.50 21.96 -0.53 -0.032 0.91084E+03 138 pumpellyite-Fe 46.27 43.90 -2.37 -0.053 0.40468E+04 139 pumpellyite-Mg 48.99 46.46 -2.54 -0.056 0.43307E+04 143 pyrrhotite -4.26 -8.06 -3.80 -1.266 0.64848E+04 144 pyrrhotiteFe0.875 -6.02 -9.46 -3.44 -1.265 0.58727E+04 145 pyroxmangite 7.40 6.06 -1.34 -0.267 0.22810E+04 146 pyrophyllite -6.18 -11.15 -4.98 -0.311 0.84955E+04 147 quartz -2.99 -3.16 -0.17 -0.056 0.28754E+03 152 rhodonite 7.45 6.06 -1.38 -0.277 0.23613E+04 153 sanidine -1.28 -2.49 -1.21 -0.093 0.20677E+04 165 stilpnomelane-Mg 27.44 25.81 -1.63 -0.049 0.27807E+04 171 talc 16.49 15.25 -1.24 -0.073 0.21159E+04 174 tephroite 18.09 15.28 -2.80 -0.400 0.47851E+04 178 tridymite -2.63 -3.16 -0.53 -0.177 0.90752E+03 179 tremolite 47.87 47.41 -0.45 -0.012 0.77589E+03 180 ferroactinolite 38.45 34.62 -3.83 -0.104 0.65455E+04 181 troilite-low -4.41 -8.06 -3.65 -1.216 0.62276E+04 183 vesuvianite 223.47 218.84 -4.63 -0.035 0.79065E+04 187 wairakite 3.95 1.95 -2.00 -0.118 0.34132E+04 188 walstromite 11.51 9.94 -1.56 -0.313 0.26710E+04 189 wollastonite 10.46 9.94 -0.52 -0.103 0.88144E+03 190 pseudo-wollastonite 11.00 9.94 -1.05 -0.211 0.18013E+04 191 zoisite 22.85 18.95 -3.90 -0.177 0.66545E+04 192 akaganeite 7.75 4.49 -3.26 -0.705 0.55701E+04 199 chalcedony -2.80 -3.16 -0.36 -0.118 0.60684E+03 201 montmorillonite-Ca -2.29 -6.17 -3.88 -0.240 0.66176E+04 202 montmorillonite-K -2.24 -6.27 -4.03 -0.247 0.68813E+04 203 montmorillonite-Mg -2.48 -6.79 -4.31 -0.267 0.73676E+04 204 montmorillonite-Na -2.04 -5.57 -3.54 -0.216 0.60362E+04 205 nontronite-Ca 3.21 -0.20 -3.41 -0.221 0.58274E+04 206 nontronite-H 2.53 -2.36 -4.89 -0.328 0.83546E+04 207 nontronite-K 3.34 -0.30 -3.64 -0.234 0.62143E+04 208 nontronite-Mg 3.07 -0.83 -3.90 -0.253 0.66614E+04 209 nontronite-Na 3.52 0.40 -3.12 -0.201 0.53352E+04 224 tobermorite 9.82 7.76 -2.07 -0.564 0.35281E+04 230 alabandite -0.98 -5.57 -4.59 -1.532 0.78458E+04 233 boehmite 4.41 0.74 -3.67 -0.611 0.62601E+04 235 ferrous-oxide 9.81 6.74 -3.08 -0.769 0.52528E+04 240 silica-amorphous -2.09 -3.16 -1.07 -0.356 0.18210E+04 242 an20ab80 2.02 1.35 -0.67 -0.052 0.11465E+04 243 an25ab75 2.65 1.78 -0.87 -0.067 0.14801E+04 244 an30ab70 3.28 2.21 -1.07 -0.082 0.18233E+04 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 9 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 171.9990000 Water: Moles liquid = 0.5446E+02 kg liquid = 0.9812E+00 Moles total = 0.5335E+02 kg total = 0.9612E+00 Activity = 1.0000 Stoichiometric ionic strength = .1131776E-01 Osmotic coef. = 0.9695 True ionic strength = .2000682E-01 Chg. balance for total moles = -.7172E-13 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.88242E-10 -10.0543 0.74148E-10 -10.1299 0.84028E+00 -0.0756 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13998E-03 -3.8539 0.11691E-03 -3.9321 0.83523E+00 -0.0782 4 SO4-- 0.65682E-12 -12.1826 0.34114E-12 -12.4671 0.51939E+00 -0.2845 5 HCO3- 0.24313E-06 -6.6142 0.20337E-06 -6.6917 0.83645E+00 -0.0776 6 HS- 0.25988E-04 -4.5852 0.21709E-04 -4.6634 0.83535E+00 -0.0781 7 Al+++ 0.96871E-29 -29.0138 0.22388E-29 -29.6500 0.23111E+00 -0.6362 8 H4SiO4 0.69558E-03 -3.1577 0.69558E-03 -3.1577 0.10000E+01 0.0000 9 Ca++ 0.13489E-06 -6.8700 0.69548E-07 -7.1577 0.51557E+00 -0.2877 10 Mg++ 0.21104E-10 -10.6756 0.10831E-10 -10.9653 0.51322E+00 -0.2897 11 Fe++ 0.58143E-13 -13.2355 0.29873E-13 -13.5247 0.51378E+00 -0.2892 12 K+ 0.15642E-03 -3.8057 0.13087E-03 -3.8832 0.83665E+00 -0.0775 13 Na+ 0.19849E-01 -1.7023 0.16576E-01 -1.7805 0.83508E+00 -0.0783 14 Mn++ 0.17765E-10 -10.7504 0.91346E-11 -11.0393 0.51420E+00 -0.2889 15 HPO4-- 0.45319E-07 -7.3437 0.23541E-07 -7.6282 0.51946E+00 -0.2844 16 HSiO3- 0.10487E-01 -1.9793 0.87594E-02 -2.0575 0.83523E+00 -0.0782 17 Ca(HSiO3)+ 0.16579E-07 -7.7804 0.13874E-07 -7.8578 0.83683E+00 -0.0774 18 Mg(HSiO3)+ 0.32133E-11 -11.4931 0.26890E-11 -11.5704 0.83683E+00 -0.0774 19 NaHSiO3,aq 0.23483E-02 -2.6292 0.23483E-02 -2.6292 0.10000E+01 0.0000 20 AlO+ 0.66199E-16 -16.1791 0.55397E-16 -16.2565 0.83683E+00 -0.0774 22 HAlO2,aq 0.14879E-09 -9.8274 0.14879E-09 -9.8274 0.10000E+01 0.0000 23 AlO2- 0.53277E-05 -5.2735 0.44418E-05 -5.3524 0.83372E+00 -0.0790 24 CH4,aq 0.12615E-04 -4.8991 0.12571E-04 -4.9006 0.99655E+00 -0.0015 25 C2H6,aq 0.23376E-14 -14.6312 0.23295E-14 -14.6327 0.99655E+00 -0.0015 29 CO,aq 0.93876E-17 -17.0274 0.93876E-17 -17.0274 0.10000E+01 0.0000 30 CO2,aq 0.32332E-10 -10.4904 0.32221E-10 -10.4919 0.99655E+00 -0.0015 31 CO3-2 0.46223E-06 -6.3351 0.23956E-06 -6.6206 0.51828E+00 -0.2854 32 CaCO3,aq 0.20891E-09 -9.6800 0.20891E-09 -9.6800 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.43143E-12 -12.3651 0.36103E-12 -12.4425 0.83683E+00 -0.0774 34 CaCl+ 0.15724E-10 -10.8034 0.13159E-10 -10.8808 0.83683E+00 -0.0774 35 CaCl2,aq 0.36549E-15 -15.4371 0.36549E-15 -15.4371 0.10000E+01 0.0000 36 CaOH+ 0.79882E-07 -7.0976 0.66848E-07 -7.1749 0.83683E+00 -0.0774 37 CaSO4,aq 0.75340E-17 -17.1230 0.75340E-17 -17.1230 0.10000E+01 0.0000 38 HCl,aq 0.15885E-14 -14.7990 0.15885E-14 -14.7990 0.10000E+01 0.0000 43 FeCl+ 0.66060E-17 -17.1801 0.55281E-17 -17.2574 0.83683E+00 -0.0774 46 FeO,aq 0.21117E-09 -9.6754 0.21117E-09 -9.6754 0.10000E+01 0.0000 47 FeOH+ 0.15671E-10 -10.8049 0.13114E-10 -10.8823 0.83683E+00 -0.0774 48 HFeO2- 0.35678E-07 -7.4476 0.29799E-07 -7.5258 0.83523E+00 -0.0782 49 FeO+ 0.10976E-16 -16.9596 0.91849E-17 -17.0369 0.83683E+00 -0.0774 51 FeO2- 0.40927E-09 -9.3880 0.34184E-09 -9.4662 0.83523E+00 -0.0782 52 HFeO2,aq 0.32237E-11 -11.4916 0.32237E-11 -11.4916 0.10000E+01 0.0000 53 H2,aq 0.11638E-04 -4.9341 0.11598E-04 -4.9356 0.99655E+00 -0.0015 54 KCl,aq 0.27731E-09 -9.5570 0.27731E-09 -9.5570 0.10000E+01 0.0000 56 KOH,aq 0.75376E-06 -6.1228 0.75376E-06 -6.1228 0.10000E+01 0.0000 57 KSO4- 0.82946E-15 -15.0812 0.69279E-15 -15.1594 0.83523E+00 -0.0782 58 MgCO3,aq 0.81552E-14 -14.0886 0.81552E-14 -14.0886 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.68655E-16 -16.1633 0.57452E-16 -16.2407 0.83683E+00 -0.0774 60 MgCl+ 0.22195E-14 -14.6537 0.18573E-14 -14.7311 0.83683E+00 -0.0774 61 MgOH+ 0.68840E-10 -10.1622 0.57607E-10 -10.2395 0.83683E+00 -0.0774 63 MnO,aq 0.17206E-08 -8.7643 0.17206E-08 -8.7643 0.10000E+01 0.0000 64 MnOH+ 0.44516E-09 -9.3515 0.37252E-09 -9.4288 0.83683E+00 -0.0774 65 MnO2-2 0.20039E-10 -10.6981 0.10386E-10 -10.9835 0.51828E+00 -0.2854 66 HMnO2- 0.20200E-09 -9.6946 0.16872E-09 -9.7728 0.83523E+00 -0.0782 69 MnCl+ 0.78587E-14 -14.1047 0.65764E-14 -14.1820 0.83683E+00 -0.0774 71 NaCl,aq 0.64223E-06 -6.1923 0.64223E-06 -6.1923 0.10000E+01 0.0000 72 NaOH,aq 0.96048E-04 -4.0175 0.96048E-04 -4.0175 0.10000E+01 0.0000 74 OH- 0.93462E-02 -2.0294 0.77921E-02 -2.1083 0.83372E+00 -0.0790 79 HPO3-2 0.16417E-14 -14.7847 0.85087E-15 -15.0701 0.51828E+00 -0.2854 81 H2PO3- 0.15147E-18 -18.8197 0.12652E-18 -18.8979 0.83523E+00 -0.0782 82 H3PO4,aq 0.90522E-18 -18.0432 0.90522E-18 -18.0432 0.10000E+01 0.0000 83 H2PO4- 0.38516E-10 -10.4144 0.32201E-10 -10.4921 0.83602E+00 -0.0778 84 PO4-3 0.10672E-08 -8.9718 0.25904E-09 -9.5866 0.24273E+00 -0.6149 88 HP2O7-3 0.94639E-18 -18.0239 0.21894E-18 -18.6597 0.23134E+00 -0.6357 89 P2O7-4 0.91427E-17 -17.0389 0.70540E-18 -18.1516 0.77154E-01 -1.1126 90 H2S,aq 0.49923E-08 -8.3017 0.49750E-08 -8.3032 0.99655E+00 -0.0015 91 S2-2 0.17373E-14 -14.7601 0.90041E-15 -15.0456 0.51828E+00 -0.2854 97 SO3-2 0.97790E-18 -18.0097 0.51416E-18 -18.2889 0.52578E+00 -0.2792 99 HSO4- 0.29102E-19 -19.5361 0.24377E-19 -19.6130 0.83764E+00 -0.0769 Charge balance for all species = -.7134E-13 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.8824214E-10 -.2230359E-01 -.2244164E+02 0.0000 2 H2O 0.1000000E+01 0.5550489E+02 0.9982005E+06 0.0000 3 Cl- 0.1399762E-03 0.1406187E-03 0.4976696E+01 6.1978 4 SO4-- 0.6568162E-12 -.1552443E-04 -.1488711E+01 7.7927 5 HCO3- 0.2431296E-06 0.1332051E-04 0.8113685E+00 3.4382 6 HS- 0.2598832E-04 0.4151773E-04 0.1370690E+01 5.4665 7 Al+++ 0.9687080E-29 0.5327827E-05 0.1435031E+00 0.7397 8 H4SiO4 0.6955818E-03 0.1353131E-01 0.1298308E+04 -3.1577 9 Ca++ 0.1348941E-06 0.2315803E-06 0.9265155E-02 13.1021 10 Mg++ 0.2110437E-10 0.9316780E-10 0.2261161E-05 9.2945 11 Fe++ 0.5814349E-13 0.3631693E-07 0.2024669E-02 6.7351 12 K+ 0.1564239E-03 0.1571779E-03 0.6135297E+01 6.2467 13 Na+ 0.1984939E-01 0.2229439E-01 0.5116533E+03 8.3494 14 Mn++ 0.1776453E-10 0.2405579E-08 0.1319282E-03 9.2205 15 HPO4-- 0.4531890E-07 0.4642460E-07 0.4448048E-02 12.6316 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.2848035E+01 -.2188414E-01 -.2826151E+01 0.0000000E+00 2 H2O 0.5335217E+02 0.5446105E+02 -.1108878E+01 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.4792183E-02 -.1523247E-04 0.4807416E-02 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.4766679E-02 0.4073694E-04 -.4807416E-02 0.0000000E+00 7 Al+++ 0.5608443E+00 0.5227630E-05 0.5608391E+00 0.0000000E+00 8 H4SiO4 0.1790988E+01 0.1327683E-01 0.1777711E+01 0.0000000E+00 9 Ca++ 0.1978379E+00 0.2272251E-06 0.1978376E+00 0.0000000E+00 10 Mg++ 0.1365071E+00 0.9141565E-10 0.1365071E+00 0.0000000E+00 11 Fe++ 0.1226368E+00 0.3563394E-07 0.1226367E+00 0.0000000E+00 12 K+ 0.3651783E-01 0.1542220E-03 0.3636361E-01 0.0000000E+00 13 Na+ 0.2160607E+00 0.2187511E-01 0.1941856E+00 0.0000000E+00 14 Mn++ 0.2982221E-02 0.2360339E-08 0.2982219E-02 0.0000000E+00 15 HPO4-- 0.1017817E-02 0.4555153E-07 0.1017772E-02 0.0000000E+00 Chg. balance for solid moles: 0.5031E-15 Mass of aqueous solution: 0.982901E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 171.9990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 0.1939 -0.712 50.85 1.706 27.09 19.52 andradite 0.1923E-01 -1.716 9.772 0.990 5.206 2.539 grossular 0.4666E-02 -2.331 2.102 0.323 1.120 0.5848 apatite-OH 0.3393E-03 -3.469 0.1704 -0.768 0.9078E-01 0.5415E-01 clinochlore 0.2567E-01 -1.591 14.27 1.154 7.600 5.426 daphnite 0.7427E-02 -2.129 5.299 0.724 2.823 1.606 chlorite-Mn 0.5964E-03 -3.224 0.4229 -0.374 0.2253 0.1348 microcline 0.3194E-01 -1.496 8.890 0.949 4.736 3.473 stilbite 0.1199 -0.921 84.48 1.927 45.00 39.40 stilpnomelane-Fe 0.8846E-02 -2.053 9.536 0.979 5.080 3.294 tr.625ac.25prg.125 0.2229E-02 -2.652 1.905 0.280 1.015 0.6131 diopside 0.9592E-04 -4.018 0.2077E-01 -1.682 0.1107E-01 0.6349E-02 hedenbergite 0.2487E-04 -4.604 0.6169E-02 -2.210 0.3286E-02 0.1690E-02 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8047E+00 0.8047E+00 1.0000 -0.094 grossular 0.1953E+00 0.1953E+00 1.0000 -0.709 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.7618E+00 0.7618E+00 1.0000 -0.118 daphnite 0.2205E+00 0.2205E+00 1.0000 -0.657 chlorite-Mn 0.1770E-01 0.1770E-01 1.0000 -1.752 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 tr.625ac.25prg.125 0.1000E+01 0.1000E+01 1.0000 0.000 diopside 0.7941E+00 0.7941E+00 1.0000 -0.100 hedenbergite 0.2059E+00 0.2059E+00 1.0000 -0.686 Solid products produced: Mass = 187.716048 g Volume = 76.653932 cm3 Porosity: -9.8200% V(tot) - V(min): -.68543E+01 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 171.9990000 g log = 2.2355 Original solution: 1000.0103000 g Original solution / Rock added: 5.81 (Water/Rock Ratio), log = 0.7645 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0543 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9682E+00 0.9855 0.1006E+01 0.1021E+01 CO2,gas 0.3247E-08 1.0069 0.3447E-08 0.3424E-08 CH4,gas 0.1734E-01 1.0125 0.1850E-01 0.1828E-01 H2,gas 0.1444E-01 1.0006 0.1523E-01 0.1522E-01 H2S,gas 0.1303E-06 0.9959 0.1368E-06 0.1373E-06 S2,gas 0.2872E-29 1.0000 0.3028E-29 0.3028E-29 CO,gas 0.1327E-13 1.0000 0.1399E-13 0.1399E-13 SO3,gas 0.6727E-48 1.0000 0.7092E-48 0.7092E-48 SO2,gas 0.3985E-27 1.0000 0.4201E-27 0.4201E-27 HCl,gas 0.2659E-17 1.0000 0.2803E-17 0.2803E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 16 albite -0.38 -0.38 0.00 0.000 -0.94784E-12 22 andradite 39.01 39.01 0.00 0.000 0.12132E-10 23 grossular 32.73 32.73 0.00 0.000 0.00000E+00 32 apatite-OH -18.15 -18.15 0.00 0.000 0.60662E-11 46 clinochlore 39.07 39.07 0.00 0.000 0.12132E-10 47 daphnite 28.97 28.97 0.00 0.000 0.36397E-10 48 chlorite-Mn 46.87 46.87 0.00 0.000 0.12132E-10 67 diopside 16.18 16.18 0.00 0.000 0.60662E-11 68 hedenbergite 14.21 14.21 0.00 0.000 0.12132E-10 116 microcline -2.49 -2.49 0.00 0.000 0.15165E-11 163 stilbite -7.52 -7.52 0.00 0.000 0.15165E-10 164 stilpnomelane-Fe 13.02 13.02 0.00 0.000 -0.27298E-10 245 tr.625ac.25prg.125 45.16 45.16 0.00 0.000 0.00000E+00 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -16.82 -10.16 -3.387 0.17350E+05 -8.463 3 CH4,gas 4.54 1.11 -3.43 -0.858 0.58595E+04 -1.733 4 H2,gas 8.00 4.48 -3.52 -2.009 0.60041E+04 -1.817 5 H2S,gas -6.23 -14.79 -8.56 -4.282 0.14621E+05 -6.864 6 S2,gas -7.34 -38.55 -31.22 -4.803 0.53304E+05 -29.519 7 CO,gas 3.21 -12.34 -15.55 -4.786 0.26557E+05 -13.854 8 SO3,gas 17.12 -32.73 -49.85 -12.462 0.85114E+05 -48.149 9 SO2,gas 0.83 -28.24 -29.08 -7.753 0.49646E+05 -27.377 10 HCl,gas 5.19 -14.06 -19.25 -9.626 0.32871E+05 -17.552 11 acmite 7.71 6.53 -1.18 -0.123 0.20187E+04 15 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 19 spessartine 24.46 19.67 -4.79 -0.239 0.81778E+04 20 analcite 3.32 2.77 -0.55 -0.061 0.93583E+03 26 annite 20.12 17.72 -2.40 -0.134 0.41059E+04 27 phlogopite 27.06 25.40 -1.67 -0.093 0.28475E+04 29 anorthite 12.71 8.27 -4.44 -0.342 0.75882E+04 35 aragonite 0.97 -3.72 -4.69 -1.562 0.80013E+04 36 brucite 12.57 9.29 -3.27 -0.655 0.55904E+04 37 calcite 0.81 -3.72 -4.53 -1.510 0.77371E+04 38 carnegieite-low 9.02 5.93 -3.09 -0.442 0.52793E+04 39 carnegieite-high 10.09 5.93 -4.16 -0.595 0.71063E+04 40 carpholite-Mg 8.58 4.46 -4.12 -0.275 0.70408E+04 41 carpholite-Fe 6.71 1.90 -4.81 -0.321 0.82188E+04 42 celadonite 5.34 3.65 -1.69 -0.099 0.28878E+04 43 celadonite-Fe 3.88 1.09 -2.79 -0.164 0.47563E+04 44 chrysotile 23.89 21.57 -2.32 -0.194 0.39686E+04 49 chlorite-Al-free 47.17 43.14 -4.04 -0.168 0.68924E+04 51 chloritoid-Fe 9.17 5.06 -4.12 -0.274 0.70293E+04 52 chloritoid-Mn 11.40 7.54 -3.86 -0.257 0.65888E+04 54 coesite -2.38 -3.16 -0.78 -0.261 0.13345E+04 61 cristobalite -2.56 -3.16 -0.60 -0.199 0.10199E+04 63 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71234E+04 65 diaspore 2.87 0.74 -2.13 -0.356 0.36437E+04 66 diamond -3.10 -7.85 -4.75 -1.358 0.81146E+04 71 enstatite 17.26 12.27 -4.99 -0.499 0.85224E+04 73 clinoenstatite 17.17 12.27 -4.89 -0.489 0.83540E+04 75 epidote 24.67 22.70 -1.97 -0.095 0.33567E+04 76 clinozoisite 22.81 18.95 -3.86 -0.175 0.65835E+04 77 epidote-Fe 29.84 26.46 -3.38 -0.176 0.57766E+04 78 fayalite 14.05 10.31 -3.73 -0.533 0.63744E+04 79 ferrosilite 11.15 7.15 -3.99 -0.399 0.68207E+04 83 gibbsite 4.08 0.74 -3.34 -0.477 0.57023E+04 84 glaucophane 22.97 20.80 -2.17 -0.059 0.37128E+04 85 glaucophane-Fe 17.28 13.12 -4.15 -0.112 0.70922E+04 86 graphite -3.55 -7.85 -4.31 -1.231 0.73569E+04 87 greenalite 16.14 13.89 -2.25 -0.187 0.38411E+04 90 hematite 12.57 8.99 -3.58 -0.434 0.61118E+04 91 heulandite -5.83 -7.52 -1.69 -0.077 0.28938E+04 95 jadeite 4.22 2.77 -1.44 -0.144 0.24613E+04 97 kalsilite 7.58 3.83 -3.76 -0.536 0.64117E+04 98 kaolinite -1.33 -4.84 -3.50 -0.318 0.59815E+04 101 laumontite 2.88 1.95 -0.93 -0.062 0.15922E+04 102 lawsonite 9.62 8.27 -1.35 -0.090 0.23049E+04 103 leucite 4.12 0.67 -3.45 -0.345 0.58869E+04 105 lizardite 23.24 21.57 -1.68 -0.140 0.28613E+04 107 magnetite 20.09 15.72 -4.37 -0.356 0.74541E+04 108 minnesotaite 10.39 7.57 -2.81 -0.165 0.48039E+04 112 manganosite 14.06 9.22 -4.84 -1.209 0.82601E+04 120 muscovite 2.58 -1.01 -3.59 -0.211 0.61290E+04 121 paragonite 4.24 1.10 -3.14 -0.185 0.53681E+04 122 nepheline 8.34 5.93 -2.41 -0.344 0.41116E+04 128 periclase-Fe 11.63 6.74 -4.89 -1.223 0.83521E+04 134 phlogopite-Na 29.65 27.50 -2.15 -0.119 0.36663E+04 136 prehnite 19.37 18.21 -1.16 -0.068 0.19828E+04 137 prehnite-Fe 22.50 21.96 -0.53 -0.032 0.91105E+03 138 pumpellyite-Fe 46.27 43.90 -2.37 -0.053 0.40524E+04 139 pumpellyite-Mg 48.99 46.46 -2.54 -0.056 0.43360E+04 143 pyrrhotite -4.26 -8.06 -3.80 -1.266 0.64847E+04 144 pyrrhotiteFe0.875 -6.02 -9.46 -3.44 -1.265 0.58721E+04 145 pyroxmangite 7.40 6.06 -1.34 -0.267 0.22809E+04 146 pyrophyllite -6.18 -11.15 -4.98 -0.311 0.84953E+04 147 quartz -2.99 -3.16 -0.17 -0.056 0.28723E+03 152 rhodonite 7.45 6.06 -1.38 -0.277 0.23612E+04 153 sanidine -1.28 -2.49 -1.21 -0.093 0.20677E+04 165 stilpnomelane-Mg 27.44 25.81 -1.63 -0.049 0.27788E+04 171 talc 16.49 15.25 -1.24 -0.073 0.21143E+04 174 tephroite 18.09 15.28 -2.80 -0.400 0.47851E+04 178 tridymite -2.63 -3.16 -0.53 -0.177 0.90720E+03 179 tremolite 47.87 47.42 -0.45 -0.012 0.77508E+03 180 ferroactinolite 38.45 34.62 -3.83 -0.104 0.65465E+04 181 troilite-low -4.41 -8.06 -3.65 -1.216 0.62275E+04 183 vesuvianite 223.47 218.83 -4.64 -0.035 0.79283E+04 187 wairakite 3.95 1.95 -2.00 -0.118 0.34142E+04 188 walstromite 11.51 9.94 -1.56 -0.313 0.26718E+04 189 wollastonite 10.46 9.94 -0.52 -0.103 0.88228E+03 190 pseudo-wollastonite 11.00 9.94 -1.06 -0.211 0.18021E+04 191 zoisite 22.85 18.95 -3.90 -0.177 0.66575E+04 192 akaganeite 7.75 4.49 -3.26 -0.705 0.55684E+04 199 chalcedony -2.80 -3.16 -0.36 -0.118 0.60652E+03 201 montmorillonite-Ca -2.29 -6.17 -3.88 -0.240 0.66174E+04 202 montmorillonite-K -2.24 -6.27 -4.03 -0.247 0.68811E+04 203 montmorillonite-Mg -2.48 -6.79 -4.31 -0.267 0.73671E+04 204 montmorillonite-Na -2.04 -5.57 -3.54 -0.216 0.60359E+04 205 nontronite-Ca 3.21 -0.20 -3.41 -0.221 0.58232E+04 206 nontronite-H 2.53 -2.36 -4.89 -0.328 0.83503E+04 207 nontronite-K 3.34 -0.30 -3.64 -0.233 0.62101E+04 208 nontronite-Mg 3.07 -0.82 -3.90 -0.253 0.66570E+04 209 nontronite-Na 3.52 0.40 -3.12 -0.200 0.53310E+04 224 tobermorite 9.82 7.76 -2.07 -0.564 0.35288E+04 230 alabandite -0.98 -5.57 -4.59 -1.532 0.78457E+04 233 boehmite 4.41 0.74 -3.67 -0.611 0.62606E+04 235 ferrous-oxide 9.81 6.74 -3.08 -0.769 0.52531E+04 240 silica-amorphous -2.09 -3.16 -1.07 -0.355 0.18207E+04 242 an20ab80 2.02 1.35 -0.67 -0.052 0.11468E+04 243 an25ab75 2.65 1.78 -0.87 -0.067 0.14805E+04 244 an30ab70 3.28 2.21 -1.07 -0.082 0.18237E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 4.0000000 g Current total amount of reactant added: 171.9990000 g New total amount of reactant added: 175.9990000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.7175E-13 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 11 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 175.9990000 Water: Moles liquid = 0.5444E+02 kg liquid = 0.9808E+00 Moles total = 0.5330E+02 kg total = 0.9603E+00 Activity = 1.0000 Stoichiometric ionic strength = .1131785E-01 Osmotic coef. = 0.9695 True ionic strength = .2000693E-01 Chg. balance for total moles = -.7175E-13 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.88243E-10 -10.0543 0.74149E-10 -10.1299 0.84028E+00 -0.0756 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.14003E-03 -3.8538 0.11696E-03 -3.9320 0.83523E+00 -0.0782 4 SO4-- 0.65716E-12 -12.1823 0.34132E-12 -12.4668 0.51938E+00 -0.2845 5 HCO3- 0.24326E-06 -6.6139 0.20347E-06 -6.6915 0.83645E+00 -0.0776 6 HS- 0.25999E-04 -4.5850 0.21718E-04 -4.6632 0.83535E+00 -0.0781 7 Al+++ 0.96869E-29 -29.0138 0.22387E-29 -29.6500 0.23111E+00 -0.6362 8 H4SiO4 0.69559E-03 -3.1576 0.69559E-03 -3.1576 0.10000E+01 0.0000 9 Ca++ 0.13489E-06 -6.8700 0.69548E-07 -7.1577 0.51557E+00 -0.2877 10 Mg++ 0.21104E-10 -10.6756 0.10831E-10 -10.9653 0.51322E+00 -0.2897 11 Fe++ 0.58144E-13 -13.2355 0.29873E-13 -13.5247 0.51378E+00 -0.2892 12 K+ 0.15642E-03 -3.8057 0.13087E-03 -3.8832 0.83665E+00 -0.0775 13 Na+ 0.19849E-01 -1.7023 0.16576E-01 -1.7805 0.83508E+00 -0.0783 14 Mn++ 0.17785E-10 -10.7500 0.91449E-11 -11.0388 0.51420E+00 -0.2889 15 HPO4-- 0.45319E-07 -7.3437 0.23542E-07 -7.6282 0.51946E+00 -0.2844 16 HSiO3- 0.10487E-01 -1.9793 0.87595E-02 -2.0575 0.83523E+00 -0.0782 17 Ca(HSiO3)+ 0.16579E-07 -7.7804 0.13874E-07 -7.8578 0.83683E+00 -0.0774 18 Mg(HSiO3)+ 0.32133E-11 -11.4931 0.26890E-11 -11.5704 0.83683E+00 -0.0774 19 NaHSiO3,aq 0.23483E-02 -2.6292 0.23483E-02 -2.6292 0.10000E+01 0.0000 20 AlO+ 0.66197E-16 -16.1792 0.55396E-16 -16.2565 0.83683E+00 -0.0774 22 HAlO2,aq 0.14878E-09 -9.8275 0.14878E-09 -9.8275 0.10000E+01 0.0000 23 AlO2- 0.53274E-05 -5.2735 0.44416E-05 -5.3525 0.83372E+00 -0.0790 24 CH4,aq 0.12620E-04 -4.8989 0.12576E-04 -4.9004 0.99655E+00 -0.0015 25 C2H6,aq 0.23395E-14 -14.6309 0.23314E-14 -14.6324 0.99655E+00 -0.0015 29 CO,aq 0.93923E-17 -17.0272 0.93923E-17 -17.0272 0.10000E+01 0.0000 30 CO2,aq 0.32349E-10 -10.4901 0.32238E-10 -10.4916 0.99655E+00 -0.0015 31 CO3-2 0.46246E-06 -6.3349 0.23969E-06 -6.6204 0.51828E+00 -0.2854 32 CaCO3,aq 0.20902E-09 -9.6798 0.20902E-09 -9.6798 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.43165E-12 -12.3649 0.36122E-12 -12.4422 0.83683E+00 -0.0774 34 CaCl+ 0.15731E-10 -10.8033 0.13164E-10 -10.8806 0.83683E+00 -0.0774 35 CaCl2,aq 0.36579E-15 -15.4368 0.36579E-15 -15.4368 0.10000E+01 0.0000 36 CaOH+ 0.79882E-07 -7.0976 0.66847E-07 -7.1749 0.83683E+00 -0.0774 37 CaSO4,aq 0.75379E-17 -17.1227 0.75379E-17 -17.1227 0.10000E+01 0.0000 38 HCl,aq 0.15892E-14 -14.7988 0.15892E-14 -14.7988 0.10000E+01 0.0000 43 FeCl+ 0.66087E-17 -17.1799 0.55304E-17 -17.2572 0.83683E+00 -0.0774 46 FeO,aq 0.21117E-09 -9.6754 0.21117E-09 -9.6754 0.10000E+01 0.0000 47 FeOH+ 0.15671E-10 -10.8049 0.13114E-10 -10.8823 0.83683E+00 -0.0774 48 HFeO2- 0.35677E-07 -7.4476 0.29799E-07 -7.5258 0.83523E+00 -0.0782 49 FeO+ 0.10976E-16 -16.9596 0.91850E-17 -17.0369 0.83683E+00 -0.0774 51 FeO2- 0.40928E-09 -9.3880 0.34184E-09 -9.4662 0.83523E+00 -0.0782 52 HFeO2,aq 0.32237E-11 -11.4916 0.32237E-11 -11.4916 0.10000E+01 0.0000 53 H2,aq 0.11638E-04 -4.9341 0.11598E-04 -4.9356 0.99655E+00 -0.0015 54 KCl,aq 0.27743E-09 -9.5569 0.27743E-09 -9.5569 0.10000E+01 0.0000 56 KOH,aq 0.75376E-06 -6.1228 0.75376E-06 -6.1228 0.10000E+01 0.0000 57 KSO4- 0.82990E-15 -15.0810 0.69316E-15 -15.1592 0.83523E+00 -0.0782 58 MgCO3,aq 0.81593E-14 -14.0883 0.81593E-14 -14.0883 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.68690E-16 -16.1631 0.57482E-16 -16.2405 0.83683E+00 -0.0774 60 MgCl+ 0.22204E-14 -14.6536 0.18581E-14 -14.7309 0.83683E+00 -0.0774 61 MgOH+ 0.68839E-10 -10.1622 0.57607E-10 -10.2395 0.83683E+00 -0.0774 63 MnO,aq 0.17225E-08 -8.7638 0.17225E-08 -8.7638 0.10000E+01 0.0000 64 MnOH+ 0.44566E-09 -9.3510 0.37294E-09 -9.4284 0.83683E+00 -0.0774 65 MnO2-2 0.20062E-10 -10.6976 0.10398E-10 -10.9831 0.51828E+00 -0.2854 66 HMnO2- 0.20223E-09 -9.6942 0.16891E-09 -9.7724 0.83523E+00 -0.0782 69 MnCl+ 0.78707E-14 -14.1040 0.65865E-14 -14.1813 0.83683E+00 -0.0774 71 NaCl,aq 0.64250E-06 -6.1921 0.64250E-06 -6.1921 0.10000E+01 0.0000 72 NaOH,aq 0.96048E-04 -4.0175 0.96048E-04 -4.0175 0.10000E+01 0.0000 74 OH- 0.93461E-02 -2.0294 0.77921E-02 -2.1083 0.83372E+00 -0.0790 79 HPO3-2 0.16417E-14 -14.7847 0.85085E-15 -15.0701 0.51828E+00 -0.2854 81 H2PO3- 0.15147E-18 -18.8197 0.12651E-18 -18.8979 0.83523E+00 -0.0782 82 H3PO4,aq 0.90524E-18 -18.0432 0.90524E-18 -18.0432 0.10000E+01 0.0000 83 H2PO4- 0.38517E-10 -10.4143 0.32201E-10 -10.4921 0.83602E+00 -0.0778 84 PO4-3 0.10672E-08 -8.9718 0.25904E-09 -9.5866 0.24273E+00 -0.6149 88 HP2O7-3 0.94642E-18 -18.0239 0.21895E-18 -18.6597 0.23134E+00 -0.6357 89 P2O7-4 0.91430E-17 -17.0389 0.70542E-18 -18.1516 0.77153E-01 -1.1126 90 H2S,aq 0.49943E-08 -8.3015 0.49771E-08 -8.3030 0.99655E+00 -0.0015 91 S2-2 0.17388E-14 -14.7598 0.90118E-15 -15.0452 0.51828E+00 -0.2854 97 SO3-2 0.97838E-18 -18.0095 0.51441E-18 -18.2887 0.52578E+00 -0.2792 99 HSO4- 0.29117E-19 -19.5358 0.24390E-19 -19.6128 0.83764E+00 -0.0769 Charge balance for all species = -.7430E-13 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.8824263E-10 -.2230366E-01 -.2244170E+02 0.0000 2 H2O 0.1000000E+01 0.5550489E+02 0.9982005E+06 0.0000 3 Cl- 0.1400335E-03 0.1406763E-03 0.4978734E+01 6.1979 4 SO4-- 0.6571616E-12 -.1552943E-04 -.1489191E+01 7.7930 5 HCO3- 0.2432558E-06 0.1332597E-04 0.8117008E+00 3.4384 6 HS- 0.2599896E-04 0.4153338E-04 0.1371206E+01 5.4667 7 Al+++ 0.9686891E-29 0.5327597E-05 0.1434969E+00 0.7397 8 H4SiO4 0.6955907E-03 0.1353143E-01 0.1298320E+04 -3.1576 9 Ca++ 0.1348939E-06 0.2315797E-06 0.9265131E-02 13.1021 10 Mg++ 0.2110432E-10 0.9316710E-10 0.2261144E-05 9.2945 11 Fe++ 0.5814388E-13 0.3631658E-07 0.2024649E-02 6.7351 12 K+ 0.1564248E-03 0.1571788E-03 0.6135330E+01 6.2467 13 Na+ 0.1984949E-01 0.2229453E-01 0.5116565E+03 8.3494 14 Mn++ 0.1778457E-10 0.2408266E-08 0.1320755E-03 9.2210 15 HPO4-- 0.4531948E-07 0.4642520E-07 0.4448105E-02 12.6316 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.2914269E+01 -.2187525E-01 -.2892394E+01 0.0000000E+00 2 H2O 0.5330203E+02 0.5443875E+02 -.1136722E+01 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.4903037E-02 -.1523114E-04 0.4918268E-02 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.4877532E-02 0.4073561E-04 -.4918268E-02 0.0000000E+00 7 Al+++ 0.5738873E+00 0.5225264E-05 0.5738820E+00 0.0000000E+00 8 H4SiO4 0.1832639E+01 0.1327152E-01 0.1819368E+01 0.0000000E+00 9 Ca++ 0.2024384E+00 0.2271315E-06 0.2024382E+00 0.0000000E+00 10 Mg++ 0.1396817E+00 0.9137754E-10 0.1396817E+00 0.0000000E+00 11 Fe++ 0.1254888E+00 0.3561901E-07 0.1254888E+00 0.0000000E+00 12 K+ 0.3736709E-01 0.1541597E-03 0.3721293E-01 0.0000000E+00 13 Na+ 0.2210817E+00 0.2186629E-01 0.1992154E+00 0.0000000E+00 14 Mn++ 0.3051576E-02 0.2362008E-08 0.3051573E-02 0.0000000E+00 15 HPO4-- 0.1041488E-02 0.4553346E-07 0.1041442E-02 0.0000000E+00 Chg. balance for solid moles: 0.6891E-15 Mass of aqueous solution: 0.982498E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 175.9990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 0.1989 -0.701 52.16 1.717 27.16 20.02 andradite 0.1967E-01 -1.706 9.997 1.000 5.205 2.597 grossular 0.4774E-02 -2.321 2.150 0.332 1.119 0.5983 apatite-OH 0.3471E-03 -3.459 0.1744 -0.759 0.9078E-01 0.5541E-01 clinochlore 0.2623E-01 -1.581 14.58 1.164 7.591 5.546 daphnite 0.7591E-02 -2.120 5.417 0.734 2.820 1.641 chlorite-Mn 0.6103E-03 -3.214 0.4327 -0.364 0.2253 0.1379 diopside 0.3135E-03 -3.504 0.6788E-01 -1.168 0.3534E-01 0.2075E-01 hedenbergite 0.8126E-04 -4.090 0.2016E-01 -1.695 0.1050E-01 0.5522E-02 microcline 0.3269E-01 -1.486 9.098 0.959 4.736 3.554 stilbite 0.1224 -0.912 86.29 1.936 44.92 40.25 stilpnomelane-Fe 0.9055E-02 -2.043 9.762 0.990 5.082 3.372 tr.625ac.25prg.125 0.2262E-02 -2.646 1.933 0.286 1.007 0.6223 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8047E+00 0.8047E+00 1.0000 -0.094 grossular 0.1953E+00 0.1953E+00 1.0000 -0.709 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.7618E+00 0.7618E+00 1.0000 -0.118 daphnite 0.2205E+00 0.2205E+00 1.0000 -0.657 chlorite-Mn 0.1772E-01 0.1772E-01 1.0000 -1.751 diopside 0.7941E+00 0.7941E+00 1.0000 -0.100 hedenbergite 0.2059E+00 0.2059E+00 1.0000 -0.686 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 tr.625ac.25prg.125 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 192.086068 g Volume = 78.422054 cm3 Porosity: -9.8354% V(tot) - V(min): -.70225E+01 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 175.9990000 g log = 2.2455 Original solution: 1000.0103000 g Original solution / Rock added: 5.68 (Water/Rock Ratio), log = 0.7545 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0543 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9682E+00 0.9855 0.1006E+01 0.1021E+01 CO2,gas 0.3249E-08 1.0069 0.3449E-08 0.3425E-08 CH4,gas 0.1734E-01 1.0125 0.1851E-01 0.1828E-01 H2,gas 0.1443E-01 1.0006 0.1523E-01 0.1522E-01 H2S,gas 0.1303E-06 0.9959 0.1368E-06 0.1374E-06 S2,gas 0.2875E-29 1.0000 0.3031E-29 0.3031E-29 CO,gas 0.1328E-13 1.0000 0.1400E-13 0.1400E-13 SO3,gas 0.6730E-48 1.0000 0.7095E-48 0.7095E-48 SO2,gas 0.3987E-27 1.0000 0.4203E-27 0.4203E-27 HCl,gas 0.2660E-17 1.0000 0.2804E-17 0.2804E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 16 albite -0.38 -0.38 0.00 0.000 -0.94784E-12 22 andradite 39.01 39.01 0.00 0.000 -0.12132E-10 23 grossular 32.73 32.73 0.00 0.000 0.24265E-10 32 apatite-OH -18.15 -18.15 0.00 0.000 -0.60662E-11 46 clinochlore 39.07 39.07 0.00 0.000 0.12132E-10 47 daphnite 28.97 28.97 0.00 0.000 0.00000E+00 48 chlorite-Mn 46.87 46.87 0.00 0.000 0.00000E+00 67 diopside 16.18 16.18 0.00 0.000 0.00000E+00 68 hedenbergite 14.21 14.21 0.00 0.000 -0.30331E-11 116 microcline -2.49 -2.49 0.00 0.000 0.15165E-11 163 stilbite -7.52 -7.52 0.00 0.000 -0.90992E-11 164 stilpnomelane-Fe 13.02 13.02 0.00 0.000 0.21232E-10 245 tr.625ac.25prg.125 45.16 45.16 0.00 0.000 -0.12132E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -16.82 -10.16 -3.387 0.17350E+05 -8.462 3 CH4,gas 4.54 1.11 -3.43 -0.858 0.58592E+04 -1.733 4 H2,gas 8.00 4.48 -3.52 -2.009 0.60041E+04 -1.817 5 H2S,gas -6.23 -14.79 -8.56 -4.281 0.14621E+05 -6.864 6 S2,gas -7.34 -38.55 -31.22 -4.803 0.53303E+05 -29.518 7 CO,gas 3.21 -12.34 -15.55 -4.786 0.26556E+05 -13.854 8 SO3,gas 17.12 -32.73 -49.85 -12.462 0.85114E+05 -48.149 9 SO2,gas 0.83 -28.24 -29.08 -7.753 0.49645E+05 -27.376 10 HCl,gas 5.19 -14.06 -19.25 -9.626 0.32871E+05 -17.552 11 acmite 7.71 6.53 -1.18 -0.123 0.20187E+04 15 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 19 spessartine 24.46 19.67 -4.79 -0.239 0.81753E+04 20 analcite 3.32 2.77 -0.55 -0.061 0.93584E+03 26 annite 20.12 17.72 -2.40 -0.134 0.41059E+04 27 phlogopite 27.06 25.40 -1.67 -0.093 0.28475E+04 29 anorthite 12.71 8.27 -4.44 -0.342 0.75882E+04 35 aragonite 0.97 -3.72 -4.69 -1.562 0.80009E+04 36 brucite 12.57 9.29 -3.27 -0.655 0.55904E+04 37 calcite 0.81 -3.72 -4.53 -1.510 0.77367E+04 38 carnegieite-low 9.02 5.93 -3.09 -0.442 0.52793E+04 39 carnegieite-high 10.09 5.93 -4.16 -0.595 0.71063E+04 40 carpholite-Mg 8.58 4.46 -4.12 -0.275 0.70408E+04 41 carpholite-Fe 6.71 1.90 -4.81 -0.321 0.82189E+04 42 celadonite 5.34 3.65 -1.69 -0.099 0.28878E+04 43 celadonite-Fe 3.88 1.09 -2.79 -0.164 0.47563E+04 44 chrysotile 23.89 21.57 -2.32 -0.194 0.39687E+04 49 chlorite-Al-free 47.17 43.14 -4.04 -0.168 0.68925E+04 51 chloritoid-Fe 9.17 5.06 -4.12 -0.274 0.70293E+04 52 chloritoid-Mn 11.40 7.54 -3.86 -0.257 0.65880E+04 54 coesite -2.38 -3.16 -0.78 -0.261 0.13345E+04 61 cristobalite -2.56 -3.16 -0.60 -0.199 0.10199E+04 63 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71234E+04 65 diaspore 2.87 0.74 -2.13 -0.356 0.36437E+04 66 diamond -3.10 -7.85 -4.75 -1.358 0.81143E+04 71 enstatite 17.26 12.27 -4.99 -0.499 0.85224E+04 73 clinoenstatite 17.17 12.27 -4.89 -0.489 0.83540E+04 75 epidote 24.67 22.70 -1.97 -0.095 0.33568E+04 76 clinozoisite 22.81 18.95 -3.86 -0.175 0.65835E+04 77 epidote-Fe 29.84 26.46 -3.38 -0.176 0.57766E+04 78 fayalite 14.05 10.31 -3.73 -0.533 0.63744E+04 79 ferrosilite 11.15 7.15 -3.99 -0.399 0.68207E+04 83 gibbsite 4.08 0.74 -3.34 -0.477 0.57023E+04 84 glaucophane 22.97 20.80 -2.17 -0.059 0.37128E+04 85 glaucophane-Fe 17.28 13.12 -4.15 -0.112 0.70922E+04 86 graphite -3.55 -7.85 -4.31 -1.231 0.73565E+04 87 greenalite 16.14 13.89 -2.25 -0.187 0.38411E+04 90 hematite 12.57 8.99 -3.58 -0.434 0.61118E+04 91 heulandite -5.83 -7.52 -1.69 -0.077 0.28938E+04 95 jadeite 4.22 2.77 -1.44 -0.144 0.24613E+04 97 kalsilite 7.58 3.83 -3.76 -0.536 0.64117E+04 98 kaolinite -1.33 -4.84 -3.50 -0.318 0.59815E+04 101 laumontite 2.88 1.95 -0.93 -0.062 0.15923E+04 102 lawsonite 9.62 8.27 -1.35 -0.090 0.23049E+04 103 leucite 4.12 0.67 -3.45 -0.345 0.58869E+04 105 lizardite 23.24 21.57 -1.68 -0.140 0.28613E+04 107 magnetite 20.09 15.72 -4.37 -0.356 0.74541E+04 108 minnesotaite 10.39 7.57 -2.81 -0.165 0.48039E+04 112 manganosite 14.06 9.22 -4.84 -1.209 0.82593E+04 120 muscovite 2.58 -1.01 -3.59 -0.211 0.61290E+04 121 paragonite 4.24 1.10 -3.14 -0.185 0.53681E+04 122 nepheline 8.34 5.93 -2.41 -0.344 0.41116E+04 128 periclase-Fe 11.63 6.74 -4.89 -1.223 0.83521E+04 134 phlogopite-Na 29.65 27.50 -2.15 -0.119 0.36663E+04 136 prehnite 19.37 18.21 -1.16 -0.068 0.19828E+04 137 prehnite-Fe 22.50 21.96 -0.53 -0.032 0.91106E+03 138 pumpellyite-Fe 46.27 43.90 -2.37 -0.053 0.40526E+04 139 pumpellyite-Mg 48.99 46.46 -2.54 -0.056 0.43361E+04 143 pyrrhotite -4.26 -8.06 -3.80 -1.266 0.64844E+04 144 pyrrhotiteFe0.875 -6.02 -9.46 -3.44 -1.265 0.58718E+04 145 pyroxmangite 7.40 6.06 -1.34 -0.267 0.22801E+04 146 pyrophyllite -6.18 -11.15 -4.98 -0.311 0.84953E+04 147 quartz -2.99 -3.16 -0.17 -0.056 0.28722E+03 152 rhodonite 7.45 6.06 -1.38 -0.276 0.23603E+04 153 sanidine -1.28 -2.49 -1.21 -0.093 0.20677E+04 165 stilpnomelane-Mg 27.44 25.81 -1.63 -0.049 0.27789E+04 171 talc 16.49 15.25 -1.24 -0.073 0.21143E+04 174 tephroite 18.09 15.28 -2.80 -0.400 0.47835E+04 178 tridymite -2.63 -3.16 -0.53 -0.177 0.90719E+03 179 tremolite 47.87 47.42 -0.45 -0.012 0.77508E+03 180 ferroactinolite 38.45 34.62 -3.83 -0.104 0.65465E+04 181 troilite-low -4.41 -8.06 -3.65 -1.216 0.62272E+04 183 vesuvianite 223.47 218.83 -4.64 -0.035 0.79287E+04 187 wairakite 3.95 1.95 -2.00 -0.118 0.34142E+04 188 walstromite 11.51 9.94 -1.56 -0.313 0.26718E+04 189 wollastonite 10.46 9.94 -0.52 -0.103 0.88228E+03 190 pseudo-wollastonite 11.00 9.94 -1.06 -0.211 0.18021E+04 191 zoisite 22.85 18.95 -3.90 -0.177 0.66576E+04 192 akaganeite 7.75 4.49 -3.26 -0.705 0.55684E+04 199 chalcedony -2.80 -3.16 -0.36 -0.118 0.60651E+03 201 montmorillonite-Ca -2.29 -6.17 -3.88 -0.240 0.66174E+04 202 montmorillonite-K -2.24 -6.27 -4.03 -0.247 0.68811E+04 203 montmorillonite-Mg -2.48 -6.79 -4.31 -0.267 0.73672E+04 204 montmorillonite-Na -2.04 -5.57 -3.54 -0.216 0.60360E+04 205 nontronite-Ca 3.21 -0.20 -3.41 -0.221 0.58232E+04 206 nontronite-H 2.53 -2.36 -4.89 -0.328 0.83502E+04 207 nontronite-K 3.34 -0.30 -3.64 -0.233 0.62100E+04 208 nontronite-Mg 3.07 -0.82 -3.90 -0.253 0.66570E+04 209 nontronite-Na 3.52 0.40 -3.12 -0.200 0.53309E+04 224 tobermorite 9.82 7.76 -2.07 -0.564 0.35288E+04 230 alabandite -0.98 -5.57 -4.59 -1.531 0.78445E+04 233 boehmite 4.41 0.74 -3.67 -0.611 0.62607E+04 235 ferrous-oxide 9.81 6.74 -3.08 -0.769 0.52531E+04 240 silica-amorphous -2.09 -3.16 -1.07 -0.355 0.18207E+04 242 an20ab80 2.02 1.35 -0.67 -0.052 0.11468E+04 243 an25ab75 2.65 1.78 -0.87 -0.067 0.14805E+04 244 an30ab70 3.28 2.21 -1.07 -0.082 0.18238E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 4.0000000 g Current total amount of reactant added: 175.9990000 g New total amount of reactant added: 179.9990000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.7199E-13 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 11 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 179.9990000 Water: Moles liquid = 0.5442E+02 kg liquid = 0.9804E+00 Moles total = 0.5325E+02 kg total = 0.9594E+00 Activity = 1.0000 Stoichiometric ionic strength = .1131795E-01 Osmotic coef. = 0.9695 True ionic strength = .2000703E-01 Chg. balance for total moles = -.7199E-13 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.88243E-10 -10.0543 0.74149E-10 -10.1299 0.84028E+00 -0.0756 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.14009E-03 -3.8536 0.11701E-03 -3.9318 0.83523E+00 -0.0782 4 SO4-- 0.65750E-12 -12.1821 0.34150E-12 -12.4666 0.51938E+00 -0.2845 5 HCO3- 0.24338E-06 -6.6137 0.20358E-06 -6.6913 0.83645E+00 -0.0776 6 HS- 0.26010E-04 -4.5849 0.21727E-04 -4.6630 0.83535E+00 -0.0781 7 Al+++ 0.96867E-29 -29.0138 0.22387E-29 -29.6500 0.23111E+00 -0.6362 8 H4SiO4 0.69560E-03 -3.1576 0.69560E-03 -3.1576 0.10000E+01 0.0000 9 Ca++ 0.13489E-06 -6.8700 0.69548E-07 -7.1577 0.51557E+00 -0.2877 10 Mg++ 0.21104E-10 -10.6756 0.10831E-10 -10.9653 0.51322E+00 -0.2897 11 Fe++ 0.58144E-13 -13.2355 0.29873E-13 -13.5247 0.51378E+00 -0.2892 12 K+ 0.15643E-03 -3.8057 0.13087E-03 -3.8831 0.83665E+00 -0.0775 13 Na+ 0.19850E-01 -1.7022 0.16576E-01 -1.7805 0.83508E+00 -0.0783 14 Mn++ 0.17804E-10 -10.7495 0.91548E-11 -11.0384 0.51420E+00 -0.2889 15 HPO4-- 0.45320E-07 -7.3437 0.23542E-07 -7.6282 0.51946E+00 -0.2844 16 HSiO3- 0.10488E-01 -1.9793 0.87595E-02 -2.0575 0.83523E+00 -0.0782 17 Ca(HSiO3)+ 0.16579E-07 -7.7804 0.13874E-07 -7.8578 0.83683E+00 -0.0774 18 Mg(HSiO3)+ 0.32133E-11 -11.4931 0.26890E-11 -11.5704 0.83683E+00 -0.0774 19 NaHSiO3,aq 0.23484E-02 -2.6292 0.23484E-02 -2.6292 0.10000E+01 0.0000 20 AlO+ 0.66195E-16 -16.1792 0.55394E-16 -16.2565 0.83683E+00 -0.0774 22 HAlO2,aq 0.14878E-09 -9.8275 0.14878E-09 -9.8275 0.10000E+01 0.0000 23 AlO2- 0.53272E-05 -5.2735 0.44414E-05 -5.3525 0.83372E+00 -0.0790 24 CH4,aq 0.12625E-04 -4.8988 0.12582E-04 -4.9003 0.99655E+00 -0.0015 25 C2H6,aq 0.23415E-14 -14.6305 0.23334E-14 -14.6320 0.99655E+00 -0.0015 29 CO,aq 0.93969E-17 -17.0270 0.93969E-17 -17.0270 0.10000E+01 0.0000 30 CO2,aq 0.32366E-10 -10.4899 0.32254E-10 -10.4914 0.99655E+00 -0.0015 31 CO3-2 0.46270E-06 -6.3347 0.23981E-06 -6.6201 0.51828E+00 -0.2854 32 CaCO3,aq 0.20913E-09 -9.6796 0.20913E-09 -9.6796 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.43187E-12 -12.3646 0.36140E-12 -12.4420 0.83683E+00 -0.0774 34 CaCl+ 0.15737E-10 -10.8031 0.13169E-10 -10.8804 0.83683E+00 -0.0774 35 CaCl2,aq 0.36609E-15 -15.4364 0.36609E-15 -15.4364 0.10000E+01 0.0000 36 CaOH+ 0.79881E-07 -7.0976 0.66847E-07 -7.1749 0.83683E+00 -0.0774 37 CaSO4,aq 0.75418E-17 -17.1225 0.75418E-17 -17.1225 0.10000E+01 0.0000 38 HCl,aq 0.15898E-14 -14.7986 0.15898E-14 -14.7986 0.10000E+01 0.0000 43 FeCl+ 0.66114E-17 -17.1797 0.55326E-17 -17.2571 0.83683E+00 -0.0774 46 FeO,aq 0.21117E-09 -9.6754 0.21117E-09 -9.6754 0.10000E+01 0.0000 47 FeOH+ 0.15671E-10 -10.8049 0.13114E-10 -10.8823 0.83683E+00 -0.0774 48 HFeO2- 0.35677E-07 -7.4476 0.29798E-07 -7.5258 0.83523E+00 -0.0782 49 FeO+ 0.10976E-16 -16.9596 0.91852E-17 -17.0369 0.83683E+00 -0.0774 51 FeO2- 0.40928E-09 -9.3880 0.34184E-09 -9.4662 0.83523E+00 -0.0782 52 HFeO2,aq 0.32238E-11 -11.4916 0.32238E-11 -11.4916 0.10000E+01 0.0000 53 H2,aq 0.11638E-04 -4.9341 0.11597E-04 -4.9356 0.99655E+00 -0.0015 54 KCl,aq 0.27754E-09 -9.5567 0.27754E-09 -9.5567 0.10000E+01 0.0000 56 KOH,aq 0.75376E-06 -6.1228 0.75376E-06 -6.1228 0.10000E+01 0.0000 57 KSO4- 0.83034E-15 -15.0807 0.69353E-15 -15.1589 0.83523E+00 -0.0782 58 MgCO3,aq 0.81635E-14 -14.0881 0.81635E-14 -14.0881 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.68725E-16 -16.1629 0.57511E-16 -16.2402 0.83683E+00 -0.0774 60 MgCl+ 0.22213E-14 -14.6534 0.18588E-14 -14.7308 0.83683E+00 -0.0774 61 MgOH+ 0.68839E-10 -10.1622 0.57606E-10 -10.2395 0.83683E+00 -0.0774 63 MnO,aq 0.17244E-08 -8.7634 0.17244E-08 -8.7634 0.10000E+01 0.0000 64 MnOH+ 0.44614E-09 -9.3505 0.37334E-09 -9.4279 0.83683E+00 -0.0774 65 MnO2-2 0.20083E-10 -10.6972 0.10409E-10 -10.9826 0.51828E+00 -0.2854 66 HMnO2- 0.20244E-09 -9.6937 0.16909E-09 -9.7719 0.83523E+00 -0.0782 69 MnCl+ 0.78824E-14 -14.1033 0.65963E-14 -14.1807 0.83683E+00 -0.0774 71 NaCl,aq 0.64276E-06 -6.1919 0.64276E-06 -6.1919 0.10000E+01 0.0000 72 NaOH,aq 0.96048E-04 -4.0175 0.96048E-04 -4.0175 0.10000E+01 0.0000 74 OH- 0.93461E-02 -2.0294 0.77921E-02 -2.1083 0.83372E+00 -0.0790 79 HPO3-2 0.16416E-14 -14.7847 0.85084E-15 -15.0702 0.51828E+00 -0.2854 81 H2PO3- 0.15147E-18 -18.8197 0.12651E-18 -18.8979 0.83523E+00 -0.0782 82 H3PO4,aq 0.90526E-18 -18.0432 0.90526E-18 -18.0432 0.10000E+01 0.0000 83 H2PO4- 0.38518E-10 -10.4143 0.32202E-10 -10.4921 0.83602E+00 -0.0778 84 PO4-3 0.10672E-08 -8.9718 0.25904E-09 -9.5866 0.24273E+00 -0.6149 88 HP2O7-3 0.94645E-18 -18.0239 0.21895E-18 -18.6597 0.23134E+00 -0.6357 89 P2O7-4 0.91433E-17 -17.0389 0.70543E-18 -18.1515 0.77153E-01 -1.1126 90 H2S,aq 0.49964E-08 -8.3013 0.49791E-08 -8.3028 0.99655E+00 -0.0015 91 S2-2 0.17403E-14 -14.7594 0.90194E-15 -15.0448 0.51828E+00 -0.2854 97 SO3-2 0.97887E-18 -18.0093 0.51466E-18 -18.2885 0.52577E+00 -0.2792 99 HSO4- 0.29133E-19 -19.5356 0.24403E-19 -19.6126 0.83764E+00 -0.0769 Charge balance for all species = -.7261E-13 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.8824310E-10 -.2230372E-01 -.2244177E+02 0.0000 2 H2O 0.1000000E+01 0.5550489E+02 0.9982005E+06 0.0000 3 Cl- 0.1400909E-03 0.1407339E-03 0.4980774E+01 6.1981 4 SO4-- 0.6575041E-12 -.1553444E-04 -.1489672E+01 7.7932 5 HCO3- 0.2433810E-06 0.1333143E-04 0.8120334E+00 3.4386 6 HS- 0.2600961E-04 0.4154905E-04 0.1371724E+01 5.4669 7 Al+++ 0.9686711E-29 0.5327377E-05 0.1434909E+00 0.7397 8 H4SiO4 0.6955993E-03 0.1353155E-01 0.1298331E+04 -3.1576 9 Ca++ 0.1348938E-06 0.2315792E-06 0.9265110E-02 13.1021 10 Mg++ 0.2110427E-10 0.9316649E-10 0.2261129E-05 9.2945 11 Fe++ 0.5814426E-13 0.3631623E-07 0.2024630E-02 6.7351 12 K+ 0.1564256E-03 0.1571796E-03 0.6135362E+01 6.2467 13 Na+ 0.1984960E-01 0.2229466E-01 0.5116595E+03 8.3494 14 Mn++ 0.1780377E-10 0.2410839E-08 0.1322166E-03 9.2214 15 HPO4-- 0.4532004E-07 0.4642577E-07 0.4448159E-02 12.6316 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.2980503E+01 -.2186635E-01 -.2958637E+01 0.0000000E+00 2 H2O 0.5325189E+02 0.5441646E+02 -.1164567E+01 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.5013890E-02 -.1522982E-04 0.5029120E-02 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.4988386E-02 0.4073429E-04 -.5029120E-02 0.0000000E+00 7 Al+++ 0.5869302E+00 0.5222908E-05 0.5869250E+00 0.0000000E+00 8 H4SiO4 0.1874291E+01 0.1326620E-01 0.1861024E+01 0.0000000E+00 9 Ca++ 0.2070390E+00 0.2270380E-06 0.2070388E+00 0.0000000E+00 10 Mg++ 0.1428563E+00 0.9133952E-10 0.1428563E+00 0.0000000E+00 11 Fe++ 0.1283408E+00 0.3560408E-07 0.1283408E+00 0.0000000E+00 12 K+ 0.3821635E-01 0.1540974E-03 0.3806225E-01 0.0000000E+00 13 Na+ 0.2261027E+00 0.2185747E-01 0.2042452E+00 0.0000000E+00 14 Mn++ 0.3120930E-02 0.2363563E-08 0.3120928E-02 0.0000000E+00 15 HPO4-- 0.1065158E-02 0.4551537E-07 0.1065112E-02 0.0000000E+00 Chg. balance for solid moles: -.4766E-15 Mass of aqueous solution: 0.982096E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 179.9990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 0.2040 -0.690 53.48 1.728 27.22 20.53 andradite 0.2012E-01 -1.696 10.22 1.010 5.204 2.656 grossular 0.4881E-02 -2.311 2.199 0.342 1.119 0.6118 apatite-OH 0.3550E-03 -3.450 0.1783 -0.749 0.9078E-01 0.5667E-01 clinochlore 0.2680E-01 -1.572 14.90 1.173 7.583 5.666 daphnite 0.7756E-02 -2.110 5.534 0.743 2.817 1.677 chlorite-Mn 0.6242E-03 -3.205 0.4425 -0.354 0.2253 0.1410 diopside 0.5310E-03 -3.275 0.1150 -0.939 0.5854E-01 0.3515E-01 hedenbergite 0.1377E-03 -3.861 0.3415E-01 -1.467 0.1738E-01 0.9354E-02 microcline 0.3343E-01 -1.476 9.305 0.969 4.736 3.635 stilbite 0.1250 -0.903 88.10 1.945 44.84 41.09 stilpnomelane-Fe 0.9265E-02 -2.033 9.987 0.999 5.084 3.450 tr.625ac.25prg.125 0.2295E-02 -2.639 1.962 0.293 0.9987 0.6315 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8047E+00 0.8047E+00 1.0000 -0.094 grossular 0.1953E+00 0.1953E+00 1.0000 -0.709 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.7618E+00 0.7618E+00 1.0000 -0.118 daphnite 0.2205E+00 0.2205E+00 1.0000 -0.657 chlorite-Mn 0.1774E-01 0.1774E-01 1.0000 -1.751 diopside 0.7941E+00 0.7941E+00 1.0000 -0.100 hedenbergite 0.2059E+00 0.2059E+00 1.0000 -0.686 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 tr.625ac.25prg.125 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 196.456088 g Volume = 80.190176 cm3 Porosity: -9.8502% V(tot) - V(min): -.71906E+01 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 179.9990000 g log = 2.2553 Original solution: 1000.0103000 g Original solution / Rock added: 5.56 (Water/Rock Ratio), log = 0.7447 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0543 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9682E+00 0.9855 0.1006E+01 0.1021E+01 CO2,gas 0.3251E-08 1.0069 0.3451E-08 0.3427E-08 CH4,gas 0.1735E-01 1.0125 0.1852E-01 0.1829E-01 H2,gas 0.1443E-01 1.0006 0.1523E-01 0.1522E-01 H2S,gas 0.1304E-06 0.9959 0.1369E-06 0.1374E-06 S2,gas 0.2877E-29 1.0000 0.3033E-29 0.3033E-29 CO,gas 0.1328E-13 1.0000 0.1400E-13 0.1400E-13 SO3,gas 0.6734E-48 1.0000 0.7099E-48 0.7099E-48 SO2,gas 0.3989E-27 1.0000 0.4205E-27 0.4205E-27 HCl,gas 0.2661E-17 1.0000 0.2805E-17 0.2805E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 16 albite -0.38 -0.38 0.00 0.000 0.11184E-10 22 andradite 39.01 39.01 0.00 0.000 -0.12132E-10 23 grossular 32.73 32.73 0.00 0.000 -0.36397E-10 32 apatite-OH -18.15 -18.15 0.00 0.000 0.00000E+00 46 clinochlore 39.07 39.07 0.00 0.000 0.48529E-10 47 daphnite 28.97 28.97 0.00 0.000 0.18198E-10 48 chlorite-Mn 46.87 46.87 0.00 0.000 0.12132E-10 67 diopside 16.18 16.18 0.00 0.000 0.12132E-10 68 hedenbergite 14.21 14.21 0.00 0.000 0.60662E-11 116 microcline -2.49 -2.49 0.00 0.000 0.13649E-10 163 stilbite -7.52 -7.52 0.00 0.000 -0.90992E-11 164 stilpnomelane-Fe 13.02 13.02 0.00 0.000 0.69761E-10 245 tr.625ac.25prg.125 45.16 45.16 0.00 0.000 0.24265E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -16.82 -10.16 -3.387 0.17350E+05 -8.462 3 CH4,gas 4.54 1.11 -3.43 -0.858 0.58589E+04 -1.732 4 H2,gas 8.00 4.48 -3.52 -2.009 0.60041E+04 -1.817 5 H2S,gas -6.23 -14.79 -8.56 -4.281 0.14620E+05 -6.864 6 S2,gas -7.34 -38.55 -31.22 -4.803 0.53302E+05 -29.518 7 CO,gas 3.21 -12.34 -15.55 -4.785 0.26556E+05 -13.854 8 SO3,gas 17.12 -32.73 -49.85 -12.462 0.85114E+05 -48.149 9 SO2,gas 0.83 -28.24 -29.08 -7.753 0.49645E+05 -27.376 10 HCl,gas 5.19 -14.06 -19.25 -9.625 0.32871E+05 -17.552 11 acmite 7.71 6.53 -1.18 -0.123 0.20186E+04 15 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 19 spessartine 24.46 19.67 -4.79 -0.239 0.81730E+04 20 analcite 3.32 2.77 -0.55 -0.061 0.93584E+03 26 annite 20.12 17.72 -2.40 -0.134 0.41059E+04 27 phlogopite 27.06 25.40 -1.67 -0.093 0.28476E+04 29 anorthite 12.71 8.27 -4.44 -0.342 0.75883E+04 35 aragonite 0.97 -3.72 -4.69 -1.562 0.80006E+04 36 brucite 12.57 9.29 -3.27 -0.655 0.55904E+04 37 calcite 0.81 -3.72 -4.53 -1.510 0.77363E+04 38 carnegieite-low 9.02 5.93 -3.09 -0.442 0.52793E+04 39 carnegieite-high 10.09 5.93 -4.16 -0.595 0.71063E+04 40 carpholite-Mg 8.58 4.46 -4.12 -0.275 0.70408E+04 41 carpholite-Fe 6.71 1.90 -4.81 -0.321 0.82189E+04 42 celadonite 5.34 3.65 -1.69 -0.099 0.28878E+04 43 celadonite-Fe 3.88 1.09 -2.79 -0.164 0.47563E+04 44 chrysotile 23.89 21.57 -2.32 -0.194 0.39687E+04 49 chlorite-Al-free 47.17 43.14 -4.04 -0.168 0.68925E+04 51 chloritoid-Fe 9.17 5.06 -4.12 -0.274 0.70294E+04 52 chloritoid-Mn 11.40 7.54 -3.86 -0.257 0.65873E+04 54 coesite -2.38 -3.16 -0.78 -0.261 0.13345E+04 61 cristobalite -2.56 -3.16 -0.60 -0.199 0.10199E+04 63 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71234E+04 65 diaspore 2.87 0.74 -2.13 -0.356 0.36438E+04 66 diamond -3.10 -7.85 -4.75 -1.358 0.81139E+04 71 enstatite 17.26 12.27 -4.99 -0.499 0.85225E+04 73 clinoenstatite 17.17 12.27 -4.89 -0.489 0.83540E+04 75 epidote 24.67 22.70 -1.97 -0.095 0.33568E+04 76 clinozoisite 22.81 18.95 -3.86 -0.175 0.65836E+04 77 epidote-Fe 29.84 26.46 -3.38 -0.176 0.57766E+04 78 fayalite 14.05 10.31 -3.73 -0.533 0.63744E+04 79 ferrosilite 11.15 7.15 -3.99 -0.399 0.68207E+04 83 gibbsite 4.08 0.74 -3.34 -0.477 0.57023E+04 84 glaucophane 22.97 20.80 -2.17 -0.059 0.37128E+04 85 glaucophane-Fe 17.28 13.12 -4.15 -0.112 0.70922E+04 86 graphite -3.55 -7.85 -4.31 -1.231 0.73562E+04 87 greenalite 16.14 13.89 -2.25 -0.187 0.38411E+04 90 hematite 12.57 8.99 -3.58 -0.434 0.61118E+04 91 heulandite -5.83 -7.52 -1.69 -0.077 0.28938E+04 95 jadeite 4.22 2.77 -1.44 -0.144 0.24613E+04 97 kalsilite 7.58 3.83 -3.76 -0.536 0.64118E+04 98 kaolinite -1.33 -4.84 -3.50 -0.318 0.59815E+04 101 laumontite 2.88 1.95 -0.93 -0.062 0.15923E+04 102 lawsonite 9.62 8.27 -1.35 -0.090 0.23050E+04 103 leucite 4.12 0.67 -3.45 -0.345 0.58869E+04 105 lizardite 23.24 21.57 -1.68 -0.140 0.28613E+04 107 magnetite 20.09 15.72 -4.37 -0.356 0.74541E+04 108 minnesotaite 10.39 7.57 -2.81 -0.165 0.48039E+04 112 manganosite 14.06 9.22 -4.84 -1.209 0.82585E+04 120 muscovite 2.58 -1.01 -3.59 -0.211 0.61291E+04 121 paragonite 4.24 1.10 -3.14 -0.185 0.53682E+04 122 nepheline 8.34 5.93 -2.41 -0.344 0.41117E+04 128 periclase-Fe 11.63 6.74 -4.89 -1.223 0.83521E+04 134 phlogopite-Na 29.65 27.50 -2.15 -0.119 0.36664E+04 136 prehnite 19.37 18.21 -1.16 -0.068 0.19829E+04 137 prehnite-Fe 22.50 21.96 -0.53 -0.032 0.91107E+03 138 pumpellyite-Fe 46.27 43.90 -2.37 -0.053 0.40527E+04 139 pumpellyite-Mg 48.99 46.46 -2.54 -0.056 0.43362E+04 143 pyrrhotite -4.26 -8.06 -3.80 -1.266 0.64841E+04 144 pyrrhotiteFe0.875 -6.02 -9.46 -3.44 -1.265 0.58715E+04 145 pyroxmangite 7.40 6.06 -1.33 -0.267 0.22793E+04 146 pyrophyllite -6.18 -11.15 -4.98 -0.311 0.84954E+04 147 quartz -2.99 -3.16 -0.17 -0.056 0.28721E+03 152 rhodonite 7.45 6.06 -1.38 -0.276 0.23595E+04 153 sanidine -1.28 -2.49 -1.21 -0.093 0.20677E+04 165 stilpnomelane-Mg 27.44 25.81 -1.63 -0.049 0.27789E+04 171 talc 16.49 15.25 -1.24 -0.073 0.21143E+04 174 tephroite 18.09 15.29 -2.80 -0.400 0.47819E+04 178 tridymite -2.63 -3.16 -0.53 -0.177 0.90718E+03 179 tremolite 47.87 47.42 -0.45 -0.012 0.77508E+03 180 ferroactinolite 38.45 34.62 -3.83 -0.104 0.65464E+04 181 troilite-low -4.41 -8.06 -3.65 -1.216 0.62269E+04 183 vesuvianite 223.47 218.83 -4.64 -0.035 0.79290E+04 187 wairakite 3.95 1.95 -2.00 -0.118 0.34142E+04 188 walstromite 11.51 9.94 -1.56 -0.313 0.26718E+04 189 wollastonite 10.46 9.94 -0.52 -0.103 0.88228E+03 190 pseudo-wollastonite 11.00 9.94 -1.06 -0.211 0.18021E+04 191 zoisite 22.85 18.95 -3.90 -0.177 0.66577E+04 192 akaganeite 7.75 4.49 -3.26 -0.705 0.55684E+04 199 chalcedony -2.80 -3.16 -0.36 -0.118 0.60650E+03 201 montmorillonite-Ca -2.29 -6.17 -3.88 -0.240 0.66174E+04 202 montmorillonite-K -2.24 -6.27 -4.03 -0.247 0.68811E+04 203 montmorillonite-Mg -2.48 -6.79 -4.31 -0.267 0.73672E+04 204 montmorillonite-Na -2.04 -5.57 -3.54 -0.216 0.60360E+04 205 nontronite-Ca 3.21 -0.20 -3.41 -0.221 0.58231E+04 206 nontronite-H 2.53 -2.36 -4.89 -0.328 0.83502E+04 207 nontronite-K 3.34 -0.30 -3.64 -0.233 0.62100E+04 208 nontronite-Mg 3.07 -0.82 -3.90 -0.253 0.66569E+04 209 nontronite-Na 3.52 0.40 -3.12 -0.200 0.53309E+04 224 tobermorite 9.82 7.76 -2.07 -0.564 0.35288E+04 230 alabandite -0.98 -5.57 -4.59 -1.531 0.78434E+04 233 boehmite 4.41 0.74 -3.67 -0.611 0.62607E+04 235 ferrous-oxide 9.81 6.74 -3.08 -0.769 0.52531E+04 240 silica-amorphous -2.09 -3.16 -1.07 -0.355 0.18207E+04 242 an20ab80 2.02 1.35 -0.67 -0.052 0.11468E+04 243 an25ab75 2.65 1.78 -0.87 -0.067 0.14805E+04 244 an30ab70 3.28 2.21 -1.07 -0.082 0.18238E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 4.0000000 g Current total amount of reactant added: 179.9990000 g New total amount of reactant added: 183.9990000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.7135E-13 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 11 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 183.9990000 Water: Moles liquid = 0.5440E+02 kg liquid = 0.9800E+00 Moles total = 0.5320E+02 kg total = 0.9584E+00 Activity = 1.0000 Stoichiometric ionic strength = .1131804E-01 Osmotic coef. = 0.9695 True ionic strength = .2000714E-01 Chg. balance for total moles = -.7135E-13 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.88244E-10 -10.0543 0.74149E-10 -10.1299 0.84028E+00 -0.0756 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.14015E-03 -3.8534 0.11706E-03 -3.9316 0.83523E+00 -0.0782 4 SO4-- 0.65784E-12 -12.1819 0.34167E-12 -12.4664 0.51938E+00 -0.2845 5 HCO3- 0.24351E-06 -6.6135 0.20368E-06 -6.6911 0.83645E+00 -0.0776 6 HS- 0.26020E-04 -4.5847 0.21736E-04 -4.6628 0.83535E+00 -0.0781 7 Al+++ 0.96865E-29 -29.0138 0.22386E-29 -29.6500 0.23111E+00 -0.6362 8 H4SiO4 0.69561E-03 -3.1576 0.69561E-03 -3.1576 0.10000E+01 0.0000 9 Ca++ 0.13489E-06 -6.8700 0.69547E-07 -7.1577 0.51557E+00 -0.2877 10 Mg++ 0.21104E-10 -10.6756 0.10831E-10 -10.9653 0.51322E+00 -0.2897 11 Fe++ 0.58145E-13 -13.2355 0.29873E-13 -13.5247 0.51378E+00 -0.2892 12 K+ 0.15643E-03 -3.8057 0.13087E-03 -3.8831 0.83665E+00 -0.0775 13 Na+ 0.19850E-01 -1.7022 0.16576E-01 -1.7805 0.83508E+00 -0.0783 14 Mn++ 0.17822E-10 -10.7490 0.91642E-11 -11.0379 0.51420E+00 -0.2889 15 HPO4-- 0.45321E-07 -7.3437 0.23542E-07 -7.6282 0.51946E+00 -0.2845 16 HSiO3- 0.10488E-01 -1.9793 0.87596E-02 -2.0575 0.83523E+00 -0.0782 17 Ca(HSiO3)+ 0.16579E-07 -7.7804 0.13874E-07 -7.8578 0.83683E+00 -0.0774 18 Mg(HSiO3)+ 0.32133E-11 -11.4930 0.26890E-11 -11.5704 0.83683E+00 -0.0774 19 NaHSiO3,aq 0.23484E-02 -2.6292 0.23484E-02 -2.6292 0.10000E+01 0.0000 20 AlO+ 0.66193E-16 -16.1792 0.55392E-16 -16.2566 0.83683E+00 -0.0774 22 HAlO2,aq 0.14877E-09 -9.8275 0.14877E-09 -9.8275 0.10000E+01 0.0000 23 AlO2- 0.53270E-05 -5.2735 0.44413E-05 -5.3525 0.83372E+00 -0.0790 24 CH4,aq 0.12630E-04 -4.8986 0.12587E-04 -4.9001 0.99655E+00 -0.0015 25 C2H6,aq 0.23434E-14 -14.6301 0.23354E-14 -14.6316 0.99655E+00 -0.0015 29 CO,aq 0.94015E-17 -17.0268 0.94015E-17 -17.0268 0.10000E+01 0.0000 30 CO2,aq 0.32383E-10 -10.4897 0.32271E-10 -10.4912 0.99655E+00 -0.0015 31 CO3-2 0.46293E-06 -6.3345 0.23993E-06 -6.6199 0.51828E+00 -0.2854 32 CaCO3,aq 0.20923E-09 -9.6794 0.20923E-09 -9.6794 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.43209E-12 -12.3644 0.36159E-12 -12.4418 0.83683E+00 -0.0774 34 CaCl+ 0.15743E-10 -10.8029 0.13175E-10 -10.8803 0.83683E+00 -0.0774 35 CaCl2,aq 0.36639E-15 -15.4361 0.36639E-15 -15.4361 0.10000E+01 0.0000 36 CaOH+ 0.79880E-07 -7.0976 0.66846E-07 -7.1749 0.83683E+00 -0.0774 37 CaSO4,aq 0.75457E-17 -17.1223 0.75457E-17 -17.1223 0.10000E+01 0.0000 38 HCl,aq 0.15905E-14 -14.7985 0.15905E-14 -14.7985 0.10000E+01 0.0000 43 FeCl+ 0.66142E-17 -17.1795 0.55349E-17 -17.2569 0.83683E+00 -0.0774 46 FeO,aq 0.21117E-09 -9.6754 0.21117E-09 -9.6754 0.10000E+01 0.0000 47 FeOH+ 0.15671E-10 -10.8049 0.13114E-10 -10.8823 0.83683E+00 -0.0774 48 HFeO2- 0.35676E-07 -7.4476 0.29798E-07 -7.5258 0.83523E+00 -0.0782 49 FeO+ 0.10976E-16 -16.9595 0.91853E-17 -17.0369 0.83683E+00 -0.0774 51 FeO2- 0.40928E-09 -9.3880 0.34184E-09 -9.4662 0.83523E+00 -0.0782 52 HFeO2,aq 0.32238E-11 -11.4916 0.32238E-11 -11.4916 0.10000E+01 0.0000 53 H2,aq 0.11637E-04 -4.9341 0.11597E-04 -4.9357 0.99655E+00 -0.0015 54 KCl,aq 0.27766E-09 -9.5565 0.27766E-09 -9.5565 0.10000E+01 0.0000 56 KOH,aq 0.75376E-06 -6.1228 0.75376E-06 -6.1228 0.10000E+01 0.0000 57 KSO4- 0.83077E-15 -15.0805 0.69389E-15 -15.1587 0.83523E+00 -0.0782 58 MgCO3,aq 0.81676E-14 -14.0879 0.81676E-14 -14.0879 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.68760E-16 -16.1627 0.57540E-16 -16.2400 0.83683E+00 -0.0774 60 MgCl+ 0.22222E-14 -14.6532 0.18596E-14 -14.7306 0.83683E+00 -0.0774 61 MgOH+ 0.68838E-10 -10.1622 0.57606E-10 -10.2395 0.83683E+00 -0.0774 63 MnO,aq 0.17261E-08 -8.7629 0.17261E-08 -8.7629 0.10000E+01 0.0000 64 MnOH+ 0.44660E-09 -9.3501 0.37373E-09 -9.4274 0.83683E+00 -0.0774 65 MnO2-2 0.20103E-10 -10.6967 0.10419E-10 -10.9822 0.51828E+00 -0.2854 66 HMnO2- 0.20265E-09 -9.6933 0.16926E-09 -9.7715 0.83523E+00 -0.0782 69 MnCl+ 0.78938E-14 -14.1027 0.66058E-14 -14.1801 0.83683E+00 -0.0774 71 NaCl,aq 0.64303E-06 -6.1918 0.64303E-06 -6.1918 0.10000E+01 0.0000 72 NaOH,aq 0.96048E-04 -4.0175 0.96048E-04 -4.0175 0.10000E+01 0.0000 74 OH- 0.93461E-02 -2.0294 0.77920E-02 -2.1083 0.83372E+00 -0.0790 79 HPO3-2 0.16416E-14 -14.7847 0.85082E-15 -15.0702 0.51828E+00 -0.2854 81 H2PO3- 0.15147E-18 -18.8197 0.12651E-18 -18.8979 0.83523E+00 -0.0782 82 H3PO4,aq 0.90528E-18 -18.0432 0.90528E-18 -18.0432 0.10000E+01 0.0000 83 H2PO4- 0.38518E-10 -10.4143 0.32202E-10 -10.4921 0.83602E+00 -0.0778 84 PO4-3 0.10672E-08 -8.9717 0.25904E-09 -9.5866 0.24273E+00 -0.6149 88 HP2O7-3 0.94648E-18 -18.0239 0.21896E-18 -18.6596 0.23134E+00 -0.6357 89 P2O7-4 0.91435E-17 -17.0389 0.70545E-18 -18.1515 0.77153E-01 -1.1126 90 H2S,aq 0.49985E-08 -8.3012 0.49812E-08 -8.3027 0.99655E+00 -0.0015 91 S2-2 0.17417E-14 -14.7590 0.90270E-15 -15.0445 0.51828E+00 -0.2854 97 SO3-2 0.97934E-18 -18.0091 0.51491E-18 -18.2883 0.52577E+00 -0.2792 99 HSO4- 0.29148E-19 -19.5354 0.24416E-19 -19.6123 0.83764E+00 -0.0769 Charge balance for all species = -.7480E-13 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.8824356E-10 -.2230378E-01 -.2244183E+02 0.0000 2 H2O 0.1000000E+01 0.5550489E+02 0.9982005E+06 0.0000 3 Cl- 0.1401483E-03 0.1407916E-03 0.4982816E+01 6.1983 4 SO4-- 0.6578438E-12 -.1553947E-04 -.1490154E+01 7.7934 5 HCO3- 0.2435053E-06 0.1333689E-04 0.8123662E+00 3.4388 6 HS- 0.2602027E-04 0.4156474E-04 0.1372242E+01 5.4671 7 Al+++ 0.9686542E-29 0.5327165E-05 0.1434852E+00 0.7397 8 H4SiO4 0.6956074E-03 0.1353166E-01 0.1298342E+04 -3.1576 9 Ca++ 0.1348937E-06 0.2315787E-06 0.9265091E-02 13.1021 10 Mg++ 0.2110422E-10 0.9316588E-10 0.2261115E-05 9.2945 11 Fe++ 0.5814463E-13 0.3631590E-07 0.2024611E-02 6.7351 12 K+ 0.1564264E-03 0.1571804E-03 0.6135393E+01 6.2467 13 Na+ 0.1984970E-01 0.2229479E-01 0.5116625E+03 8.3494 14 Mn++ 0.1782217E-10 0.2413305E-08 0.1323519E-03 9.2219 15 HPO4-- 0.4532057E-07 0.4642630E-07 0.4448211E-02 12.6316 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.3046737E+01 -.2185745E-01 -.3024880E+01 0.0000000E+00 2 H2O 0.5320175E+02 0.5439416E+02 -.1192412E+01 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.5124744E-02 -.1522850E-04 0.5139972E-02 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.5099240E-02 0.4073297E-04 -.5139972E-02 0.0000000E+00 7 Al+++ 0.5999732E+00 0.5220561E-05 0.5999680E+00 0.0000000E+00 8 H4SiO4 0.1915942E+01 0.1326087E-01 0.1902681E+01 0.0000000E+00 9 Ca++ 0.2116396E+00 0.2269445E-06 0.2116393E+00 0.0000000E+00 10 Mg++ 0.1460310E+00 0.9130149E-10 0.1460310E+00 0.0000000E+00 11 Fe++ 0.1311929E+00 0.3558917E-07 0.1311928E+00 0.0000000E+00 12 K+ 0.3906561E-01 0.1540350E-03 0.3891157E-01 0.0000000E+00 13 Na+ 0.2311236E+00 0.2184864E-01 0.2092750E+00 0.0000000E+00 14 Mn++ 0.3190284E-02 0.2365011E-08 0.3190282E-02 0.0000000E+00 15 HPO4-- 0.1088828E-02 0.4549725E-07 0.1088783E-02 0.0000000E+00 Chg. balance for solid moles: -.3578E-15 Mass of aqueous solution: 0.981694E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 183.9990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 0.2090 -0.680 54.80 1.739 27.29 21.04 andradite 0.2056E-01 -1.687 10.45 1.019 5.203 2.715 grossular 0.4988E-02 -2.302 2.247 0.352 1.119 0.6252 apatite-OH 0.3629E-03 -3.440 0.1823 -0.739 0.9078E-01 0.5793E-01 clinochlore 0.2737E-01 -1.563 15.21 1.182 7.575 5.786 daphnite 0.7920E-02 -2.101 5.651 0.752 2.814 1.712 chlorite-Mn 0.6381E-03 -3.195 0.4524 -0.345 0.2253 0.1442 diopside 0.7486E-03 -3.126 0.1621 -0.790 0.8072E-01 0.4954E-01 hedenbergite 0.1941E-03 -3.712 0.4814E-01 -1.317 0.2397E-01 0.1319E-01 microcline 0.3417E-01 -1.466 9.512 0.978 4.737 3.716 stilbite 0.1276 -0.894 89.91 1.954 44.77 41.93 stilpnomelane-Fe 0.9474E-02 -2.023 10.21 1.009 5.085 3.528 tr.625ac.25prg.125 0.2329E-02 -2.633 1.990 0.299 0.9912 0.6406 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8047E+00 0.8047E+00 1.0000 -0.094 grossular 0.1953E+00 0.1953E+00 1.0000 -0.709 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.7618E+00 0.7618E+00 1.0000 -0.118 daphnite 0.2204E+00 0.2204E+00 1.0000 -0.657 chlorite-Mn 0.1776E-01 0.1776E-01 1.0000 -1.751 diopside 0.7941E+00 0.7941E+00 1.0000 -0.100 hedenbergite 0.2059E+00 0.2059E+00 1.0000 -0.686 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 tr.625ac.25prg.125 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 200.826109 g Volume = 81.958298 cm3 Porosity: -9.8643% V(tot) - V(min): -.73587E+01 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 183.9990000 g log = 2.2648 Original solution: 1000.0103000 g Original solution / Rock added: 5.43 (Water/Rock Ratio), log = 0.7352 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0543 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9682E+00 0.9855 0.1006E+01 0.1021E+01 CO2,gas 0.3252E-08 1.0069 0.3453E-08 0.3429E-08 CH4,gas 0.1736E-01 1.0125 0.1853E-01 0.1830E-01 H2,gas 0.1443E-01 1.0006 0.1523E-01 0.1522E-01 H2S,gas 0.1304E-06 0.9959 0.1369E-06 0.1375E-06 S2,gas 0.2880E-29 1.0000 0.3036E-29 0.3036E-29 CO,gas 0.1329E-13 1.0000 0.1401E-13 0.1401E-13 SO3,gas 0.6737E-48 1.0000 0.7103E-48 0.7103E-48 SO2,gas 0.3991E-27 1.0000 0.4207E-27 0.4207E-27 HCl,gas 0.2662E-17 1.0000 0.2806E-17 0.2806E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 16 albite -0.38 -0.38 0.00 0.000 -0.13080E-10 22 andradite 39.01 39.01 0.00 0.000 0.12132E-10 23 grossular 32.73 32.73 0.00 0.000 -0.12132E-10 32 apatite-OH -18.15 -18.15 0.00 0.000 0.00000E+00 46 clinochlore 39.07 39.07 0.00 0.000 0.00000E+00 47 daphnite 28.97 28.97 0.00 0.000 0.00000E+00 48 chlorite-Mn 46.87 46.87 0.00 0.000 0.00000E+00 67 diopside 16.18 16.18 0.00 0.000 0.60662E-11 68 hedenbergite 14.21 14.21 0.00 0.000 0.60662E-11 116 microcline -2.49 -2.49 0.00 0.000 0.15165E-11 163 stilbite -7.52 -7.52 0.00 0.000 -0.90992E-11 164 stilpnomelane-Fe 13.02 13.02 0.00 0.000 0.69761E-10 245 tr.625ac.25prg.125 45.16 45.16 0.00 0.000 -0.60662E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -16.82 -10.16 -3.387 0.17349E+05 -8.462 3 CH4,gas 4.54 1.11 -3.43 -0.858 0.58586E+04 -1.732 4 H2,gas 8.00 4.48 -3.52 -2.009 0.60041E+04 -1.817 5 H2S,gas -6.23 -14.79 -8.56 -4.281 0.14620E+05 -6.864 6 S2,gas -7.34 -38.55 -31.22 -4.803 0.53302E+05 -29.518 7 CO,gas 3.21 -12.34 -15.55 -4.785 0.26556E+05 -13.854 8 SO3,gas 17.12 -32.73 -49.85 -12.462 0.85113E+05 -48.149 9 SO2,gas 0.83 -28.24 -29.07 -7.753 0.49645E+05 -27.376 10 HCl,gas 5.19 -14.06 -19.25 -9.625 0.32870E+05 -17.552 11 acmite 7.71 6.53 -1.18 -0.123 0.20186E+04 15 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 19 spessartine 24.46 19.67 -4.79 -0.239 0.81707E+04 20 analcite 3.32 2.77 -0.55 -0.061 0.93585E+03 26 annite 20.12 17.72 -2.40 -0.134 0.41059E+04 27 phlogopite 27.06 25.40 -1.67 -0.093 0.28476E+04 29 anorthite 12.71 8.27 -4.44 -0.342 0.75883E+04 35 aragonite 0.97 -3.72 -4.69 -1.562 0.80002E+04 36 brucite 12.57 9.29 -3.27 -0.655 0.55905E+04 37 calcite 0.81 -3.72 -4.53 -1.510 0.77360E+04 38 carnegieite-low 9.02 5.93 -3.09 -0.442 0.52793E+04 39 carnegieite-high 10.09 5.93 -4.16 -0.595 0.71063E+04 40 carpholite-Mg 8.58 4.46 -4.12 -0.275 0.70409E+04 41 carpholite-Fe 6.71 1.90 -4.81 -0.321 0.82189E+04 42 celadonite 5.34 3.65 -1.69 -0.099 0.28878E+04 43 celadonite-Fe 3.88 1.09 -2.79 -0.164 0.47563E+04 44 chrysotile 23.89 21.57 -2.32 -0.194 0.39687E+04 49 chlorite-Al-free 47.17 43.14 -4.04 -0.168 0.68925E+04 51 chloritoid-Fe 9.17 5.06 -4.12 -0.274 0.70294E+04 52 chloritoid-Mn 11.40 7.54 -3.86 -0.257 0.65866E+04 54 coesite -2.38 -3.16 -0.78 -0.261 0.13345E+04 61 cristobalite -2.56 -3.16 -0.60 -0.199 0.10199E+04 63 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71234E+04 65 diaspore 2.87 0.74 -2.13 -0.356 0.36438E+04 66 diamond -3.10 -7.85 -4.75 -1.358 0.81136E+04 71 enstatite 17.26 12.27 -4.99 -0.499 0.85225E+04 73 clinoenstatite 17.17 12.27 -4.89 -0.489 0.83541E+04 75 epidote 24.67 22.70 -1.97 -0.095 0.33568E+04 76 clinozoisite 22.81 18.95 -3.86 -0.175 0.65837E+04 77 epidote-Fe 29.84 26.46 -3.38 -0.176 0.57766E+04 78 fayalite 14.05 10.31 -3.73 -0.533 0.63744E+04 79 ferrosilite 11.15 7.15 -3.99 -0.399 0.68206E+04 83 gibbsite 4.08 0.74 -3.34 -0.477 0.57023E+04 84 glaucophane 22.97 20.80 -2.17 -0.059 0.37128E+04 85 glaucophane-Fe 17.28 13.12 -4.15 -0.112 0.70922E+04 86 graphite -3.55 -7.85 -4.31 -1.231 0.73559E+04 87 greenalite 16.14 13.89 -2.25 -0.187 0.38411E+04 90 hematite 12.57 8.99 -3.58 -0.434 0.61117E+04 91 heulandite -5.83 -7.52 -1.69 -0.077 0.28938E+04 95 jadeite 4.22 2.77 -1.44 -0.144 0.24613E+04 97 kalsilite 7.58 3.83 -3.76 -0.536 0.64118E+04 98 kaolinite -1.33 -4.84 -3.50 -0.318 0.59816E+04 101 laumontite 2.88 1.95 -0.93 -0.062 0.15923E+04 102 lawsonite 9.62 8.27 -1.35 -0.090 0.23050E+04 103 leucite 4.12 0.67 -3.45 -0.345 0.58869E+04 105 lizardite 23.24 21.57 -1.68 -0.140 0.28613E+04 107 magnetite 20.09 15.72 -4.37 -0.356 0.74541E+04 108 minnesotaite 10.39 7.57 -2.81 -0.165 0.48039E+04 112 manganosite 14.06 9.22 -4.84 -1.209 0.82577E+04 120 muscovite 2.58 -1.01 -3.59 -0.211 0.61291E+04 121 paragonite 4.24 1.10 -3.14 -0.185 0.53682E+04 122 nepheline 8.34 5.93 -2.41 -0.344 0.41117E+04 128 periclase-Fe 11.63 6.74 -4.89 -1.223 0.83521E+04 134 phlogopite-Na 29.65 27.50 -2.15 -0.119 0.36664E+04 136 prehnite 19.37 18.21 -1.16 -0.068 0.19829E+04 137 prehnite-Fe 22.50 21.96 -0.53 -0.032 0.91108E+03 138 pumpellyite-Fe 46.27 43.90 -2.37 -0.053 0.40528E+04 139 pumpellyite-Mg 48.99 46.46 -2.54 -0.056 0.43364E+04 143 pyrrhotite -4.26 -8.06 -3.80 -1.266 0.64838E+04 144 pyrrhotiteFe0.875 -6.02 -9.46 -3.44 -1.265 0.58712E+04 145 pyroxmangite 7.40 6.06 -1.33 -0.267 0.22785E+04 146 pyrophyllite -6.18 -11.15 -4.98 -0.311 0.84954E+04 147 quartz -2.99 -3.16 -0.17 -0.056 0.28720E+03 152 rhodonite 7.45 6.06 -1.38 -0.276 0.23588E+04 153 sanidine -1.28 -2.49 -1.21 -0.093 0.20677E+04 165 stilpnomelane-Mg 27.44 25.81 -1.63 -0.049 0.27789E+04 171 talc 16.49 15.25 -1.24 -0.073 0.21143E+04 174 tephroite 18.09 15.29 -2.80 -0.400 0.47804E+04 178 tridymite -2.63 -3.16 -0.53 -0.177 0.90717E+03 179 tremolite 47.87 47.42 -0.45 -0.012 0.77508E+03 180 ferroactinolite 38.45 34.62 -3.83 -0.104 0.65464E+04 181 troilite-low -4.41 -8.06 -3.65 -1.216 0.62266E+04 183 vesuvianite 223.47 218.83 -4.64 -0.035 0.79293E+04 187 wairakite 3.95 1.95 -2.00 -0.118 0.34143E+04 188 walstromite 11.51 9.94 -1.56 -0.313 0.26718E+04 189 wollastonite 10.46 9.94 -0.52 -0.103 0.88228E+03 190 pseudo-wollastonite 11.00 9.94 -1.06 -0.211 0.18021E+04 191 zoisite 22.85 18.95 -3.90 -0.177 0.66577E+04 192 akaganeite 7.75 4.49 -3.26 -0.705 0.55684E+04 199 chalcedony -2.80 -3.16 -0.36 -0.118 0.60650E+03 201 montmorillonite-Ca -2.29 -6.17 -3.88 -0.240 0.66174E+04 202 montmorillonite-K -2.24 -6.27 -4.03 -0.247 0.68811E+04 203 montmorillonite-Mg -2.48 -6.79 -4.31 -0.267 0.73672E+04 204 montmorillonite-Na -2.04 -5.57 -3.54 -0.216 0.60360E+04 205 nontronite-Ca 3.21 -0.20 -3.41 -0.221 0.58231E+04 206 nontronite-H 2.53 -2.36 -4.89 -0.328 0.83502E+04 207 nontronite-K 3.34 -0.30 -3.64 -0.233 0.62100E+04 208 nontronite-Mg 3.07 -0.82 -3.90 -0.253 0.66569E+04 209 nontronite-Na 3.52 0.40 -3.12 -0.200 0.53308E+04 224 tobermorite 9.82 7.76 -2.07 -0.564 0.35288E+04 230 alabandite -0.98 -5.57 -4.59 -1.531 0.78424E+04 233 boehmite 4.41 0.74 -3.67 -0.611 0.62607E+04 235 ferrous-oxide 9.81 6.74 -3.08 -0.769 0.52531E+04 240 silica-amorphous -2.09 -3.16 -1.07 -0.355 0.18207E+04 242 an20ab80 2.02 1.35 -0.67 -0.052 0.11468E+04 243 an25ab75 2.65 1.78 -0.87 -0.067 0.14805E+04 244 an30ab70 3.28 2.21 -1.07 -0.082 0.18238E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 4.0000000 g Current total amount of reactant added: 183.9990000 g New total amount of reactant added: 187.9990000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.7138E-13 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 11 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 187.9990000 Water: Moles liquid = 0.5438E+02 kg liquid = 0.9796E+00 Moles total = 0.5315E+02 kg total = 0.9575E+00 Activity = 1.0000 Stoichiometric ionic strength = .1131813E-01 Osmotic coef. = 0.9695 True ionic strength = .2000724E-01 Chg. balance for total moles = -.7138E-13 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.88244E-10 -10.0543 0.74150E-10 -10.1299 0.84028E+00 -0.0756 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.14021E-03 -3.8532 0.11710E-03 -3.9314 0.83523E+00 -0.0782 4 SO4-- 0.65818E-12 -12.1817 0.34185E-12 -12.4662 0.51938E+00 -0.2845 5 HCO3- 0.24363E-06 -6.6133 0.20378E-06 -6.6908 0.83645E+00 -0.0776 6 HS- 0.26031E-04 -4.5845 0.21745E-04 -4.6626 0.83535E+00 -0.0781 7 Al+++ 0.96864E-29 -29.0138 0.22386E-29 -29.6500 0.23111E+00 -0.6362 8 H4SiO4 0.69562E-03 -3.1576 0.69562E-03 -3.1576 0.10000E+01 0.0000 9 Ca++ 0.13489E-06 -6.8700 0.69547E-07 -7.1577 0.51557E+00 -0.2877 10 Mg++ 0.21104E-10 -10.6756 0.10831E-10 -10.9653 0.51321E+00 -0.2897 11 Fe++ 0.58145E-13 -13.2355 0.29874E-13 -13.5247 0.51378E+00 -0.2892 12 K+ 0.15643E-03 -3.8057 0.13087E-03 -3.8831 0.83665E+00 -0.0775 13 Na+ 0.19850E-01 -1.7022 0.16576E-01 -1.7805 0.83508E+00 -0.0783 14 Mn++ 0.17840E-10 -10.7486 0.91733E-11 -11.0375 0.51420E+00 -0.2889 15 HPO4-- 0.45321E-07 -7.3437 0.23542E-07 -7.6282 0.51946E+00 -0.2845 16 HSiO3- 0.10488E-01 -1.9793 0.87596E-02 -2.0575 0.83523E+00 -0.0782 17 Ca(HSiO3)+ 0.16579E-07 -7.7804 0.13874E-07 -7.8578 0.83683E+00 -0.0774 18 Mg(HSiO3)+ 0.32133E-11 -11.4930 0.26890E-11 -11.5704 0.83683E+00 -0.0774 19 NaHSiO3,aq 0.23484E-02 -2.6292 0.23484E-02 -2.6292 0.10000E+01 0.0000 20 AlO+ 0.66191E-16 -16.1792 0.55391E-16 -16.2566 0.83683E+00 -0.0774 22 HAlO2,aq 0.14877E-09 -9.8275 0.14877E-09 -9.8275 0.10000E+01 0.0000 23 AlO2- 0.53268E-05 -5.2735 0.44411E-05 -5.3525 0.83372E+00 -0.0790 24 CH4,aq 0.12635E-04 -4.8984 0.12592E-04 -4.8999 0.99655E+00 -0.0015 25 C2H6,aq 0.23454E-14 -14.6298 0.23373E-14 -14.6313 0.99655E+00 -0.0015 29 CO,aq 0.94060E-17 -17.0266 0.94060E-17 -17.0266 0.10000E+01 0.0000 30 CO2,aq 0.32399E-10 -10.4895 0.32288E-10 -10.4910 0.99655E+00 -0.0015 31 CO3-2 0.46317E-06 -6.3343 0.24005E-06 -6.6197 0.51828E+00 -0.2854 32 CaCO3,aq 0.20934E-09 -9.6792 0.20934E-09 -9.6792 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.43231E-12 -12.3642 0.36177E-12 -12.4416 0.83683E+00 -0.0774 34 CaCl+ 0.15750E-10 -10.8027 0.13180E-10 -10.8801 0.83683E+00 -0.0774 35 CaCl2,aq 0.36669E-15 -15.4357 0.36669E-15 -15.4357 0.10000E+01 0.0000 36 CaOH+ 0.79880E-07 -7.0976 0.66846E-07 -7.1749 0.83683E+00 -0.0774 37 CaSO4,aq 0.75495E-17 -17.1221 0.75495E-17 -17.1221 0.10000E+01 0.0000 38 HCl,aq 0.15912E-14 -14.7983 0.15912E-14 -14.7983 0.10000E+01 0.0000 43 FeCl+ 0.66169E-17 -17.1793 0.55372E-17 -17.2567 0.83683E+00 -0.0774 46 FeO,aq 0.21117E-09 -9.6754 0.21117E-09 -9.6754 0.10000E+01 0.0000 47 FeOH+ 0.15671E-10 -10.8049 0.13114E-10 -10.8823 0.83683E+00 -0.0774 48 HFeO2- 0.35676E-07 -7.4476 0.29798E-07 -7.5258 0.83523E+00 -0.0782 49 FeO+ 0.10976E-16 -16.9595 0.91854E-17 -17.0369 0.83683E+00 -0.0774 51 FeO2- 0.40928E-09 -9.3880 0.34184E-09 -9.4662 0.83523E+00 -0.0782 52 HFeO2,aq 0.32238E-11 -11.4916 0.32238E-11 -11.4916 0.10000E+01 0.0000 53 H2,aq 0.11637E-04 -4.9342 0.11597E-04 -4.9357 0.99655E+00 -0.0015 54 KCl,aq 0.27777E-09 -9.5563 0.27777E-09 -9.5563 0.10000E+01 0.0000 56 KOH,aq 0.75376E-06 -6.1228 0.75376E-06 -6.1228 0.10000E+01 0.0000 57 KSO4- 0.83120E-15 -15.0803 0.69424E-15 -15.1585 0.83523E+00 -0.0782 58 MgCO3,aq 0.81716E-14 -14.0877 0.81716E-14 -14.0877 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.68795E-16 -16.1624 0.57569E-16 -16.2398 0.83683E+00 -0.0774 60 MgCl+ 0.22231E-14 -14.6530 0.18604E-14 -14.7304 0.83683E+00 -0.0774 61 MgOH+ 0.68837E-10 -10.1622 0.57605E-10 -10.2395 0.83683E+00 -0.0774 63 MnO,aq 0.17278E-08 -8.7625 0.17278E-08 -8.7625 0.10000E+01 0.0000 64 MnOH+ 0.44704E-09 -9.3497 0.37409E-09 -9.4270 0.83683E+00 -0.0774 65 MnO2-2 0.20123E-10 -10.6963 0.10429E-10 -10.9817 0.51828E+00 -0.2854 66 HMnO2- 0.20285E-09 -9.6928 0.16942E-09 -9.7710 0.83523E+00 -0.0782 69 MnCl+ 0.79049E-14 -14.1021 0.66150E-14 -14.1795 0.83683E+00 -0.0774 71 NaCl,aq 0.64330E-06 -6.1916 0.64330E-06 -6.1916 0.10000E+01 0.0000 72 NaOH,aq 0.96048E-04 -4.0175 0.96048E-04 -4.0175 0.10000E+01 0.0000 74 OH- 0.93460E-02 -2.0294 0.77920E-02 -2.1084 0.83372E+00 -0.0790 79 HPO3-2 0.16416E-14 -14.7847 0.85081E-15 -15.0702 0.51828E+00 -0.2854 81 H2PO3- 0.15147E-18 -18.8197 0.12651E-18 -18.8979 0.83523E+00 -0.0782 82 H3PO4,aq 0.90530E-18 -18.0432 0.90530E-18 -18.0432 0.10000E+01 0.0000 83 H2PO4- 0.38519E-10 -10.4143 0.32203E-10 -10.4921 0.83602E+00 -0.0778 84 PO4-3 0.10672E-08 -8.9717 0.25904E-09 -9.5866 0.24273E+00 -0.6149 88 HP2O7-3 0.94650E-18 -18.0239 0.21896E-18 -18.6596 0.23134E+00 -0.6358 89 P2O7-4 0.91437E-17 -17.0389 0.70546E-18 -18.1515 0.77152E-01 -1.1127 90 H2S,aq 0.50005E-08 -8.3010 0.49833E-08 -8.3025 0.99655E+00 -0.0015 91 S2-2 0.17432E-14 -14.7587 0.90347E-15 -15.0441 0.51828E+00 -0.2854 97 SO3-2 0.97982E-18 -18.0089 0.51516E-18 -18.2881 0.52577E+00 -0.2792 99 HSO4- 0.29163E-19 -19.5352 0.24428E-19 -19.6121 0.83764E+00 -0.0769 Charge balance for all species = -.7307E-13 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.8824401E-10 -.2230384E-01 -.2244188E+02 0.0000 2 H2O 0.1000000E+01 0.5550489E+02 0.9982005E+06 0.0000 3 Cl- 0.1402058E-03 0.1408494E-03 0.4984859E+01 6.1985 4 SO4-- 0.6581808E-12 -.1554451E-04 -.1490636E+01 7.7936 5 HCO3- 0.2436286E-06 0.1334236E-04 0.8126994E+00 3.4391 6 HS- 0.2603094E-04 0.4158045E-04 0.1372760E+01 5.4673 7 Al+++ 0.9686383E-29 0.5326962E-05 0.1434798E+00 0.7396 8 H4SiO4 0.6956153E-03 0.1353176E-01 0.1298352E+04 -3.1576 9 Ca++ 0.1348936E-06 0.2315783E-06 0.9265073E-02 13.1021 10 Mg++ 0.2110418E-10 0.9316535E-10 0.2261102E-05 9.2944 11 Fe++ 0.5814500E-13 0.3631558E-07 0.2024594E-02 6.7351 12 K+ 0.1564271E-03 0.1571812E-03 0.6135423E+01 6.2467 13 Na+ 0.1984980E-01 0.2229491E-01 0.5116653E+03 8.3494 14 Mn++ 0.1783982E-10 0.2415671E-08 0.1324816E-03 9.2223 15 HPO4-- 0.4532107E-07 0.4642681E-07 0.4448259E-02 12.6316 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.3112971E+01 -.2184855E-01 -.3091123E+01 0.0000000E+00 2 H2O 0.5315161E+02 0.5437186E+02 -.1220256E+01 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.5235598E-02 -.1522719E-04 0.5250825E-02 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.5210093E-02 0.4073166E-04 -.5250825E-02 0.0000000E+00 7 Al+++ 0.6130162E+00 0.5218222E-05 0.6130109E+00 0.0000000E+00 8 H4SiO4 0.1957593E+01 0.1325554E-01 0.1944337E+01 0.0000000E+00 9 Ca++ 0.2162401E+00 0.2268510E-06 0.2162399E+00 0.0000000E+00 10 Mg++ 0.1492056E+00 0.9126355E-10 0.1492056E+00 0.0000000E+00 11 Fe++ 0.1340449E+00 0.3557427E-07 0.1340449E+00 0.0000000E+00 12 K+ 0.3991486E-01 0.1539726E-03 0.3976089E-01 0.0000000E+00 13 Na+ 0.2361446E+00 0.2183980E-01 0.2143048E+00 0.0000000E+00 14 Mn++ 0.3259639E-02 0.2366359E-08 0.3259636E-02 0.0000000E+00 15 HPO4-- 0.1112498E-02 0.4547910E-07 0.1112453E-02 0.0000000E+00 Chg. balance for solid moles: 0.4770E-16 Mass of aqueous solution: 0.981291E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 187.9990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 0.2140 -0.670 56.12 1.749 27.35 21.54 andradite 0.2100E-01 -1.678 10.67 1.028 5.202 2.773 grossular 0.5096E-02 -2.293 2.295 0.361 1.119 0.6387 apatite-OH 0.3708E-03 -3.431 0.1863 -0.730 0.9078E-01 0.5919E-01 clinochlore 0.2794E-01 -1.554 15.53 1.191 7.567 5.906 daphnite 0.8084E-02 -2.092 5.768 0.761 2.811 1.748 chlorite-Mn 0.6519E-03 -3.186 0.4622 -0.335 0.2252 0.1473 diopside 0.9661E-03 -3.015 0.2092 -0.679 0.1020 0.6394E-01 hedenbergite 0.2505E-03 -3.601 0.6214E-01 -1.207 0.3028E-01 0.1702E-01 microcline 0.3492E-01 -1.457 9.719 0.988 4.737 3.797 stilbite 0.1301 -0.886 91.72 1.962 44.70 42.78 stilpnomelane-Fe 0.9683E-02 -2.014 10.44 1.019 5.087 3.606 tr.625ac.25prg.125 0.2362E-02 -2.627 2.019 0.305 0.9839 0.6498 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8048E+00 0.8048E+00 1.0000 -0.094 grossular 0.1952E+00 0.1952E+00 1.0000 -0.709 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.7618E+00 0.7618E+00 1.0000 -0.118 daphnite 0.2204E+00 0.2204E+00 1.0000 -0.657 chlorite-Mn 0.1778E-01 0.1778E-01 1.0000 -1.750 diopside 0.7941E+00 0.7941E+00 1.0000 -0.100 hedenbergite 0.2059E+00 0.2059E+00 1.0000 -0.686 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 tr.625ac.25prg.125 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 205.196129 g Volume = 83.726421 cm3 Porosity: -9.8778% V(tot) - V(min): -.75268E+01 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 187.9990000 g log = 2.2742 Original solution: 1000.0103000 g Original solution / Rock added: 5.32 (Water/Rock Ratio), log = 0.7258 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0543 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9682E+00 0.9855 0.1006E+01 0.1021E+01 CO2,gas 0.3254E-08 1.0069 0.3454E-08 0.3431E-08 CH4,gas 0.1736E-01 1.0125 0.1853E-01 0.1831E-01 H2,gas 0.1443E-01 1.0006 0.1523E-01 0.1522E-01 H2S,gas 0.1305E-06 0.9959 0.1370E-06 0.1376E-06 S2,gas 0.2882E-29 1.0000 0.3039E-29 0.3039E-29 CO,gas 0.1329E-13 1.0000 0.1402E-13 0.1402E-13 SO3,gas 0.6741E-48 1.0000 0.7107E-48 0.7107E-48 SO2,gas 0.3993E-27 1.0000 0.4209E-27 0.4209E-27 HCl,gas 0.2663E-17 1.0000 0.2808E-17 0.2808E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 16 albite -0.38 -0.38 0.00 0.000 -0.94784E-12 22 andradite 39.01 39.01 0.00 0.000 0.12132E-10 23 grossular 32.73 32.73 0.00 0.000 0.00000E+00 32 apatite-OH -18.15 -18.15 0.00 0.000 0.60662E-11 46 clinochlore 39.07 39.07 0.00 0.000 0.00000E+00 47 daphnite 28.97 28.97 0.00 0.000 0.00000E+00 48 chlorite-Mn 46.87 46.87 0.00 0.000 0.24265E-10 67 diopside 16.18 16.18 0.00 0.000 0.00000E+00 68 hedenbergite 14.21 14.21 0.00 0.000 0.60662E-11 116 microcline -2.49 -2.49 0.00 0.000 0.13649E-10 163 stilbite -7.52 -7.52 0.00 0.000 0.39430E-10 164 stilpnomelane-Fe 13.02 13.02 0.00 0.000 -0.27298E-10 245 tr.625ac.25prg.125 45.16 45.16 0.00 0.000 -0.12132E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -16.82 -10.16 -3.387 0.17349E+05 -8.462 3 CH4,gas 4.54 1.11 -3.43 -0.858 0.58583E+04 -1.732 4 H2,gas 8.00 4.48 -3.52 -2.009 0.60042E+04 -1.817 5 H2S,gas -6.23 -14.79 -8.56 -4.281 0.14620E+05 -6.863 6 S2,gas -7.34 -38.55 -31.22 -4.803 0.53301E+05 -29.517 7 CO,gas 3.21 -12.34 -15.55 -4.785 0.26555E+05 -13.853 8 SO3,gas 17.12 -32.73 -49.85 -12.462 0.85113E+05 -48.148 9 SO2,gas 0.83 -28.24 -29.07 -7.753 0.49644E+05 -27.376 10 HCl,gas 5.19 -14.06 -19.25 -9.625 0.32870E+05 -17.552 11 acmite 7.71 6.53 -1.18 -0.123 0.20186E+04 15 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 19 spessartine 24.46 19.67 -4.78 -0.239 0.81686E+04 20 analcite 3.32 2.77 -0.55 -0.061 0.93586E+03 26 annite 20.12 17.72 -2.40 -0.134 0.41059E+04 27 phlogopite 27.06 25.40 -1.67 -0.093 0.28476E+04 29 anorthite 12.71 8.27 -4.44 -0.342 0.75884E+04 35 aragonite 0.97 -3.72 -4.69 -1.562 0.79998E+04 36 brucite 12.57 9.29 -3.27 -0.655 0.55905E+04 37 calcite 0.81 -3.72 -4.53 -1.510 0.77356E+04 38 carnegieite-low 9.02 5.93 -3.09 -0.442 0.52793E+04 39 carnegieite-high 10.09 5.93 -4.16 -0.595 0.71063E+04 40 carpholite-Mg 8.58 4.46 -4.12 -0.275 0.70409E+04 41 carpholite-Fe 6.71 1.90 -4.81 -0.321 0.82190E+04 42 celadonite 5.34 3.65 -1.69 -0.099 0.28878E+04 43 celadonite-Fe 3.88 1.09 -2.79 -0.164 0.47563E+04 44 chrysotile 23.89 21.57 -2.32 -0.194 0.39687E+04 49 chlorite-Al-free 47.17 43.14 -4.04 -0.168 0.68925E+04 51 chloritoid-Fe 9.17 5.06 -4.12 -0.274 0.70295E+04 52 chloritoid-Mn 11.40 7.54 -3.86 -0.257 0.65859E+04 54 coesite -2.38 -3.16 -0.78 -0.261 0.13345E+04 61 cristobalite -2.56 -3.16 -0.60 -0.199 0.10199E+04 63 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71234E+04 65 diaspore 2.87 0.74 -2.13 -0.356 0.36438E+04 66 diamond -3.10 -7.85 -4.75 -1.358 0.81133E+04 71 enstatite 17.26 12.27 -4.99 -0.499 0.85225E+04 73 clinoenstatite 17.17 12.27 -4.89 -0.489 0.83541E+04 75 epidote 24.67 22.70 -1.97 -0.095 0.33569E+04 76 clinozoisite 22.81 18.95 -3.86 -0.175 0.65838E+04 77 epidote-Fe 29.84 26.46 -3.38 -0.176 0.57766E+04 78 fayalite 14.05 10.31 -3.73 -0.533 0.63744E+04 79 ferrosilite 11.15 7.15 -3.99 -0.399 0.68206E+04 83 gibbsite 4.08 0.74 -3.34 -0.477 0.57024E+04 84 glaucophane 22.97 20.80 -2.17 -0.059 0.37128E+04 85 glaucophane-Fe 17.28 13.12 -4.15 -0.112 0.70922E+04 86 graphite -3.55 -7.85 -4.31 -1.231 0.73555E+04 87 greenalite 16.14 13.89 -2.25 -0.187 0.38411E+04 90 hematite 12.57 8.99 -3.58 -0.434 0.61117E+04 91 heulandite -5.83 -7.52 -1.69 -0.077 0.28938E+04 95 jadeite 4.22 2.77 -1.44 -0.144 0.24613E+04 97 kalsilite 7.58 3.83 -3.76 -0.536 0.64118E+04 98 kaolinite -1.33 -4.84 -3.50 -0.318 0.59816E+04 101 laumontite 2.88 1.95 -0.93 -0.062 0.15923E+04 102 lawsonite 9.62 8.27 -1.35 -0.090 0.23050E+04 103 leucite 4.12 0.67 -3.45 -0.345 0.58869E+04 105 lizardite 23.24 21.57 -1.68 -0.140 0.28613E+04 107 magnetite 20.09 15.72 -4.37 -0.356 0.74540E+04 108 minnesotaite 10.39 7.57 -2.81 -0.165 0.48038E+04 112 manganosite 14.06 9.22 -4.84 -1.209 0.82570E+04 120 muscovite 2.58 -1.01 -3.59 -0.211 0.61292E+04 121 paragonite 4.24 1.10 -3.14 -0.185 0.53683E+04 122 nepheline 8.34 5.93 -2.41 -0.344 0.41117E+04 128 periclase-Fe 11.63 6.74 -4.89 -1.223 0.83521E+04 134 phlogopite-Na 29.65 27.50 -2.15 -0.119 0.36664E+04 136 prehnite 19.37 18.21 -1.16 -0.068 0.19830E+04 137 prehnite-Fe 22.50 21.96 -0.53 -0.032 0.91109E+03 138 pumpellyite-Fe 46.27 43.90 -2.37 -0.053 0.40529E+04 139 pumpellyite-Mg 48.99 46.46 -2.54 -0.056 0.43365E+04 143 pyrrhotite -4.26 -8.06 -3.80 -1.266 0.64835E+04 144 pyrrhotiteFe0.875 -6.02 -9.46 -3.44 -1.265 0.58709E+04 145 pyroxmangite 7.40 6.06 -1.33 -0.267 0.22778E+04 146 pyrophyllite -6.18 -11.15 -4.98 -0.311 0.84954E+04 147 quartz -2.99 -3.16 -0.17 -0.056 0.28719E+03 152 rhodonite 7.45 6.06 -1.38 -0.276 0.23580E+04 153 sanidine -1.28 -2.49 -1.21 -0.093 0.20677E+04 165 stilpnomelane-Mg 27.44 25.81 -1.63 -0.049 0.27790E+04 171 talc 16.49 15.25 -1.24 -0.073 0.21143E+04 174 tephroite 18.09 15.29 -2.80 -0.400 0.47789E+04 178 tridymite -2.63 -3.16 -0.53 -0.177 0.90717E+03 179 tremolite 47.87 47.42 -0.45 -0.012 0.77507E+03 180 ferroactinolite 38.45 34.62 -3.83 -0.104 0.65464E+04 181 troilite-low -4.41 -8.06 -3.65 -1.216 0.62263E+04 183 vesuvianite 223.47 218.83 -4.64 -0.035 0.79297E+04 187 wairakite 3.95 1.95 -2.00 -0.118 0.34143E+04 188 walstromite 11.51 9.94 -1.56 -0.313 0.26718E+04 189 wollastonite 10.46 9.94 -0.52 -0.103 0.88228E+03 190 pseudo-wollastonite 11.00 9.94 -1.06 -0.211 0.18021E+04 191 zoisite 22.85 18.95 -3.90 -0.177 0.66578E+04 192 akaganeite 7.75 4.49 -3.26 -0.705 0.55684E+04 199 chalcedony -2.80 -3.16 -0.36 -0.118 0.60649E+03 201 montmorillonite-Ca -2.29 -6.17 -3.88 -0.240 0.66174E+04 202 montmorillonite-K -2.24 -6.27 -4.03 -0.247 0.68811E+04 203 montmorillonite-Mg -2.48 -6.79 -4.31 -0.267 0.73672E+04 204 montmorillonite-Na -2.04 -5.57 -3.54 -0.216 0.60360E+04 205 nontronite-Ca 3.21 -0.20 -3.41 -0.221 0.58231E+04 206 nontronite-H 2.53 -2.36 -4.89 -0.328 0.83501E+04 207 nontronite-K 3.34 -0.30 -3.64 -0.233 0.62099E+04 208 nontronite-Mg 3.07 -0.82 -3.90 -0.253 0.66569E+04 209 nontronite-Na 3.52 0.40 -3.12 -0.200 0.53308E+04 224 tobermorite 9.82 7.76 -2.07 -0.564 0.35288E+04 230 alabandite -0.98 -5.57 -4.59 -1.531 0.78413E+04 233 boehmite 4.41 0.74 -3.67 -0.611 0.62607E+04 235 ferrous-oxide 9.81 6.74 -3.08 -0.769 0.52531E+04 240 silica-amorphous -2.09 -3.16 -1.07 -0.355 0.18207E+04 242 an20ab80 2.02 1.35 -0.67 -0.052 0.11468E+04 243 an25ab75 2.65 1.78 -0.87 -0.067 0.14805E+04 244 an30ab70 3.28 2.21 -1.07 -0.082 0.18238E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 4.0000000 g Current total amount of reactant added: 187.9990000 g New total amount of reactant added: 191.9990000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.7184E-13 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 11 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 191.9990000 Water: Moles liquid = 0.5435E+02 kg liquid = 0.9792E+00 Moles total = 0.5310E+02 kg total = 0.9566E+00 Activity = 1.0000 Stoichiometric ionic strength = .1131822E-01 Osmotic coef. = 0.9695 True ionic strength = .2000733E-01 Chg. balance for total moles = -.7184E-13 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.88244E-10 -10.0543 0.74150E-10 -10.1299 0.84028E+00 -0.0756 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.14026E-03 -3.8531 0.11715E-03 -3.9313 0.83523E+00 -0.0782 4 SO4-- 0.65852E-12 -12.1814 0.34202E-12 -12.4659 0.51938E+00 -0.2845 5 HCO3- 0.24375E-06 -6.6131 0.20389E-06 -6.6906 0.83645E+00 -0.0776 6 HS- 0.26042E-04 -4.5843 0.21754E-04 -4.6625 0.83535E+00 -0.0781 7 Al+++ 0.96862E-29 -29.0138 0.22386E-29 -29.6500 0.23111E+00 -0.6362 8 H4SiO4 0.69562E-03 -3.1576 0.69562E-03 -3.1576 0.10000E+01 0.0000 9 Ca++ 0.13489E-06 -6.8700 0.69547E-07 -7.1577 0.51557E+00 -0.2877 10 Mg++ 0.21104E-10 -10.6756 0.10831E-10 -10.9653 0.51321E+00 -0.2897 11 Fe++ 0.58145E-13 -13.2355 0.29874E-13 -13.5247 0.51378E+00 -0.2892 12 K+ 0.15643E-03 -3.8057 0.13088E-03 -3.8831 0.83665E+00 -0.0775 13 Na+ 0.19850E-01 -1.7022 0.16576E-01 -1.7805 0.83508E+00 -0.0783 14 Mn++ 0.17857E-10 -10.7482 0.91820E-11 -11.0371 0.51420E+00 -0.2889 15 HPO4-- 0.45322E-07 -7.3437 0.23543E-07 -7.6281 0.51946E+00 -0.2845 16 HSiO3- 0.10488E-01 -1.9793 0.87597E-02 -2.0575 0.83523E+00 -0.0782 17 Ca(HSiO3)+ 0.16579E-07 -7.7804 0.13874E-07 -7.8578 0.83683E+00 -0.0774 18 Mg(HSiO3)+ 0.32133E-11 -11.4930 0.26890E-11 -11.5704 0.83683E+00 -0.0774 19 NaHSiO3,aq 0.23485E-02 -2.6292 0.23485E-02 -2.6292 0.10000E+01 0.0000 20 AlO+ 0.66189E-16 -16.1792 0.55389E-16 -16.2566 0.83683E+00 -0.0774 22 HAlO2,aq 0.14876E-09 -9.8275 0.14876E-09 -9.8275 0.10000E+01 0.0000 23 AlO2- 0.53266E-05 -5.2735 0.44409E-05 -5.3525 0.83372E+00 -0.0790 24 CH4,aq 0.12640E-04 -4.8982 0.12597E-04 -4.8997 0.99655E+00 -0.0015 25 C2H6,aq 0.23474E-14 -14.6294 0.23393E-14 -14.6309 0.99655E+00 -0.0015 29 CO,aq 0.94106E-17 -17.0264 0.94106E-17 -17.0264 0.10000E+01 0.0000 30 CO2,aq 0.32416E-10 -10.4892 0.32304E-10 -10.4907 0.99655E+00 -0.0015 31 CO3-2 0.46340E-06 -6.3340 0.24017E-06 -6.6195 0.51828E+00 -0.2854 32 CaCO3,aq 0.20944E-09 -9.6789 0.20944E-09 -9.6789 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.43253E-12 -12.3640 0.36195E-12 -12.4414 0.83683E+00 -0.0774 34 CaCl+ 0.15756E-10 -10.8025 0.13185E-10 -10.8799 0.83683E+00 -0.0774 35 CaCl2,aq 0.36699E-15 -15.4354 0.36699E-15 -15.4354 0.10000E+01 0.0000 36 CaOH+ 0.79879E-07 -7.0976 0.66845E-07 -7.1749 0.83683E+00 -0.0774 37 CaSO4,aq 0.75533E-17 -17.1219 0.75533E-17 -17.1219 0.10000E+01 0.0000 38 HCl,aq 0.15918E-14 -14.7981 0.15918E-14 -14.7981 0.10000E+01 0.0000 43 FeCl+ 0.66197E-17 -17.1792 0.55395E-17 -17.2565 0.83683E+00 -0.0774 46 FeO,aq 0.21117E-09 -9.6754 0.21117E-09 -9.6754 0.10000E+01 0.0000 47 FeOH+ 0.15671E-10 -10.8049 0.13114E-10 -10.8823 0.83683E+00 -0.0774 48 HFeO2- 0.35676E-07 -7.4476 0.29798E-07 -7.5258 0.83523E+00 -0.0782 49 FeO+ 0.10977E-16 -16.9595 0.91855E-17 -17.0369 0.83683E+00 -0.0774 51 FeO2- 0.40928E-09 -9.3880 0.34185E-09 -9.4662 0.83523E+00 -0.0782 52 HFeO2,aq 0.32239E-11 -11.4916 0.32239E-11 -11.4916 0.10000E+01 0.0000 53 H2,aq 0.11637E-04 -4.9342 0.11596E-04 -4.9357 0.99655E+00 -0.0015 54 KCl,aq 0.27789E-09 -9.5561 0.27789E-09 -9.5561 0.10000E+01 0.0000 56 KOH,aq 0.75376E-06 -6.1228 0.75376E-06 -6.1228 0.10000E+01 0.0000 57 KSO4- 0.83163E-15 -15.0801 0.69460E-15 -15.1583 0.83523E+00 -0.0782 58 MgCO3,aq 0.81757E-14 -14.0875 0.81757E-14 -14.0875 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.68829E-16 -16.1622 0.57598E-16 -16.2396 0.83683E+00 -0.0774 60 MgCl+ 0.22240E-14 -14.6529 0.18611E-14 -14.7302 0.83683E+00 -0.0774 61 MgOH+ 0.68837E-10 -10.1622 0.57605E-10 -10.2395 0.83683E+00 -0.0774 63 MnO,aq 0.17294E-08 -8.7621 0.17294E-08 -8.7621 0.10000E+01 0.0000 64 MnOH+ 0.44746E-09 -9.3492 0.37445E-09 -9.4266 0.83683E+00 -0.0774 65 MnO2-2 0.20141E-10 -10.6959 0.10439E-10 -10.9813 0.51828E+00 -0.2854 66 HMnO2- 0.20303E-09 -9.6924 0.16958E-09 -9.7706 0.83523E+00 -0.0782 69 MnCl+ 0.79156E-14 -14.1015 0.66240E-14 -14.1789 0.83683E+00 -0.0774 71 NaCl,aq 0.64356E-06 -6.1914 0.64356E-06 -6.1914 0.10000E+01 0.0000 72 NaOH,aq 0.96048E-04 -4.0175 0.96048E-04 -4.0175 0.10000E+01 0.0000 74 OH- 0.93460E-02 -2.0294 0.77920E-02 -2.1084 0.83372E+00 -0.0790 79 HPO3-2 0.16416E-14 -14.7847 0.85079E-15 -15.0702 0.51828E+00 -0.2854 81 H2PO3- 0.15146E-18 -18.8197 0.12651E-18 -18.8979 0.83523E+00 -0.0782 82 H3PO4,aq 0.90531E-18 -18.0432 0.90531E-18 -18.0432 0.10000E+01 0.0000 83 H2PO4- 0.38519E-10 -10.4143 0.32203E-10 -10.4921 0.83602E+00 -0.0778 84 PO4-3 0.10672E-08 -8.9717 0.25904E-09 -9.5866 0.24273E+00 -0.6149 88 HP2O7-3 0.94653E-18 -18.0239 0.21897E-18 -18.6596 0.23134E+00 -0.6358 89 P2O7-4 0.91439E-17 -17.0389 0.70547E-18 -18.1515 0.77152E-01 -1.1127 90 H2S,aq 0.50026E-08 -8.3008 0.49853E-08 -8.3023 0.99655E+00 -0.0015 91 S2-2 0.17447E-14 -14.7583 0.90423E-15 -15.0437 0.51828E+00 -0.2854 97 SO3-2 0.98029E-18 -18.0086 0.51541E-18 -18.2878 0.52577E+00 -0.2792 99 HSO4- 0.29178E-19 -19.5349 0.24441E-19 -19.6119 0.83764E+00 -0.0769 Charge balance for all species = -.7304E-13 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.8824445E-10 -.2230389E-01 -.2244194E+02 0.0000 2 H2O 0.1000000E+01 0.5550489E+02 0.9982004E+06 0.0000 3 Cl- 0.1402633E-03 0.1409071E-03 0.4986904E+01 6.1986 4 SO4-- 0.6585155E-12 -.1554955E-04 -.1491120E+01 7.7938 5 HCO3- 0.2437511E-06 0.1334783E-04 0.8130328E+00 3.4393 6 HS- 0.2604162E-04 0.4159618E-04 0.1373279E+01 5.4674 7 Al+++ 0.9686232E-29 0.5326766E-05 0.1434745E+00 0.7396 8 H4SiO4 0.6956228E-03 0.1353186E-01 0.1298361E+04 -3.1576 9 Ca++ 0.1348935E-06 0.2315779E-06 0.9265058E-02 13.1021 10 Mg++ 0.2110415E-10 0.9316482E-10 0.2261089E-05 9.2944 11 Fe++ 0.5814536E-13 0.3631527E-07 0.2024576E-02 6.7351 12 K+ 0.1564279E-03 0.1571819E-03 0.6135452E+01 6.2467 13 Na+ 0.1984989E-01 0.2229503E-01 0.5116681E+03 8.3494 14 Mn++ 0.1785678E-10 0.2417943E-08 0.1326062E-03 9.2227 15 HPO4-- 0.4532154E-07 0.4642730E-07 0.4448306E-02 12.6316 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.3179205E+01 -.2183964E-01 -.3157366E+01 0.0000000E+00 2 H2O 0.5310146E+02 0.5434956E+02 -.1248101E+01 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.5346451E-02 -.1522589E-04 0.5361677E-02 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.5320947E-02 0.4073036E-04 -.5361677E-02 0.0000000E+00 7 Al+++ 0.6260591E+00 0.5215890E-05 0.6260539E+00 0.0000000E+00 8 H4SiO4 0.1999244E+01 0.1325020E-01 0.1985994E+01 0.0000000E+00 9 Ca++ 0.2208407E+00 0.2267576E-06 0.2208405E+00 0.0000000E+00 10 Mg++ 0.1523802E+00 0.9122561E-10 0.1523802E+00 0.0000000E+00 11 Fe++ 0.1368969E+00 0.3555937E-07 0.1368969E+00 0.0000000E+00 12 K+ 0.4076412E-01 0.1539102E-03 0.4061021E-01 0.0000000E+00 13 Na+ 0.2411656E+00 0.2183097E-01 0.2193346E+00 0.0000000E+00 14 Mn++ 0.3328993E-02 0.2367614E-08 0.3328991E-02 0.0000000E+00 15 HPO4-- 0.1136169E-02 0.4546092E-07 0.1136123E-02 0.0000000E+00 Chg. balance for solid moles: -.1254E-14 Mass of aqueous solution: 0.980889E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 191.9990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 0.2190 -0.659 57.44 1.759 27.41 22.05 andradite 0.2145E-01 -1.669 10.90 1.037 5.201 2.832 grossular 0.5203E-02 -2.284 2.344 0.370 1.118 0.6521 apatite-OH 0.3787E-03 -3.422 0.1902 -0.721 0.9077E-01 0.6045E-01 clinochlore 0.2850E-01 -1.545 15.84 1.200 7.560 6.026 daphnite 0.8248E-02 -2.084 5.885 0.770 2.808 1.783 chlorite-Mn 0.6658E-03 -3.177 0.4720 -0.326 0.2252 0.1504 diopside 0.1184E-02 -2.927 0.2563 -0.591 0.1223 0.7834E-01 hedenbergite 0.3069E-03 -3.513 0.7613E-01 -1.118 0.3633E-01 0.2085E-01 microcline 0.3566E-01 -1.448 9.927 0.997 4.737 3.878 stilbite 0.1327 -0.877 93.53 1.971 44.63 43.62 stilpnomelane-Fe 0.9892E-02 -2.005 10.66 1.028 5.088 3.683 tr.625ac.25prg.125 0.2395E-02 -2.621 2.047 0.311 0.9770 0.6590 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8048E+00 0.8048E+00 1.0000 -0.094 grossular 0.1952E+00 0.1952E+00 1.0000 -0.709 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.7618E+00 0.7618E+00 1.0000 -0.118 daphnite 0.2204E+00 0.2204E+00 1.0000 -0.657 chlorite-Mn 0.1779E-01 0.1779E-01 1.0000 -1.750 diopside 0.7941E+00 0.7941E+00 1.0000 -0.100 hedenbergite 0.2059E+00 0.2059E+00 1.0000 -0.686 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 tr.625ac.25prg.125 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 209.566150 g Volume = 85.494543 cm3 Porosity: -9.8907% V(tot) - V(min): -.76949E+01 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 191.9990000 g log = 2.2833 Original solution: 1000.0103000 g Original solution / Rock added: 5.21 (Water/Rock Ratio), log = 0.7167 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0543 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9682E+00 0.9855 0.1006E+01 0.1021E+01 CO2,gas 0.3256E-08 1.0069 0.3456E-08 0.3432E-08 CH4,gas 0.1737E-01 1.0125 0.1854E-01 0.1831E-01 H2,gas 0.1443E-01 1.0006 0.1522E-01 0.1522E-01 H2S,gas 0.1305E-06 0.9959 0.1370E-06 0.1376E-06 S2,gas 0.2885E-29 1.0000 0.3041E-29 0.3041E-29 CO,gas 0.1330E-13 1.0000 0.1402E-13 0.1402E-13 SO3,gas 0.6744E-48 1.0000 0.7110E-48 0.7110E-48 SO2,gas 0.3995E-27 1.0000 0.4212E-27 0.4212E-27 HCl,gas 0.2664E-17 1.0000 0.2809E-17 0.2809E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 16 albite -0.38 -0.38 0.00 0.000 0.11184E-10 22 andradite 39.01 39.01 0.00 0.000 -0.12132E-10 23 grossular 32.73 32.73 0.00 0.000 0.12132E-10 32 apatite-OH -18.15 -18.15 0.00 0.000 0.60662E-11 46 clinochlore 39.07 39.07 0.00 0.000 0.60662E-10 47 daphnite 28.97 28.97 0.00 0.000 0.60662E-11 48 chlorite-Mn 46.87 46.87 0.00 0.000 0.72794E-10 67 diopside 16.18 16.18 0.00 0.000 0.60662E-11 68 hedenbergite 14.21 14.21 0.00 0.000 0.60662E-11 116 microcline -2.49 -2.49 0.00 0.000 0.13649E-10 163 stilbite -7.52 -7.52 0.00 0.000 0.39430E-10 164 stilpnomelane-Fe 13.02 13.02 0.00 0.000 -0.27298E-10 245 tr.625ac.25prg.125 45.16 45.16 0.00 0.000 0.24265E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -16.82 -10.16 -3.387 0.17349E+05 -8.461 3 CH4,gas 4.54 1.11 -3.43 -0.858 0.58580E+04 -1.732 4 H2,gas 8.00 4.48 -3.52 -2.009 0.60042E+04 -1.817 5 H2S,gas -6.23 -14.79 -8.56 -4.281 0.14620E+05 -6.863 6 S2,gas -7.34 -38.55 -31.22 -4.802 0.53300E+05 -29.517 7 CO,gas 3.21 -12.34 -15.55 -4.785 0.26555E+05 -13.853 8 SO3,gas 17.12 -32.73 -49.85 -12.462 0.85113E+05 -48.148 9 SO2,gas 0.83 -28.24 -29.07 -7.753 0.49644E+05 -27.376 10 HCl,gas 5.19 -14.06 -19.25 -9.625 0.32870E+05 -17.551 11 acmite 7.71 6.53 -1.18 -0.123 0.20186E+04 15 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 19 spessartine 24.46 19.67 -4.78 -0.239 0.81665E+04 20 analcite 3.32 2.77 -0.55 -0.061 0.93587E+03 26 annite 20.12 17.72 -2.40 -0.134 0.41059E+04 27 phlogopite 27.06 25.40 -1.67 -0.093 0.28476E+04 29 anorthite 12.71 8.27 -4.44 -0.342 0.75884E+04 35 aragonite 0.97 -3.72 -4.68 -1.562 0.79994E+04 36 brucite 12.57 9.29 -3.27 -0.655 0.55905E+04 37 calcite 0.81 -3.72 -4.53 -1.510 0.77352E+04 38 carnegieite-low 9.02 5.93 -3.09 -0.442 0.52794E+04 39 carnegieite-high 10.09 5.93 -4.16 -0.595 0.71064E+04 40 carpholite-Mg 8.58 4.46 -4.12 -0.275 0.70410E+04 41 carpholite-Fe 6.71 1.90 -4.81 -0.321 0.82190E+04 42 celadonite 5.34 3.65 -1.69 -0.099 0.28878E+04 43 celadonite-Fe 3.88 1.09 -2.79 -0.164 0.47563E+04 44 chrysotile 23.89 21.57 -2.32 -0.194 0.39687E+04 49 chlorite-Al-free 47.17 43.14 -4.04 -0.168 0.68926E+04 51 chloritoid-Fe 9.17 5.06 -4.12 -0.274 0.70295E+04 52 chloritoid-Mn 11.40 7.54 -3.86 -0.257 0.65852E+04 54 coesite -2.38 -3.16 -0.78 -0.261 0.13345E+04 61 cristobalite -2.56 -3.16 -0.60 -0.199 0.10199E+04 63 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71234E+04 65 diaspore 2.87 0.74 -2.13 -0.356 0.36439E+04 66 diamond -3.10 -7.85 -4.75 -1.358 0.81129E+04 71 enstatite 17.26 12.27 -4.99 -0.499 0.85225E+04 73 clinoenstatite 17.17 12.27 -4.89 -0.489 0.83541E+04 75 epidote 24.67 22.70 -1.97 -0.095 0.33569E+04 76 clinozoisite 22.81 18.95 -3.86 -0.175 0.65838E+04 77 epidote-Fe 29.84 26.46 -3.38 -0.176 0.57766E+04 78 fayalite 14.05 10.31 -3.73 -0.533 0.63744E+04 79 ferrosilite 11.15 7.15 -3.99 -0.399 0.68206E+04 83 gibbsite 4.08 0.74 -3.34 -0.477 0.57024E+04 84 glaucophane 22.97 20.80 -2.17 -0.059 0.37128E+04 85 glaucophane-Fe 17.28 13.12 -4.15 -0.112 0.70922E+04 86 graphite -3.55 -7.85 -4.31 -1.231 0.73552E+04 87 greenalite 16.14 13.89 -2.25 -0.187 0.38411E+04 90 hematite 12.57 8.99 -3.58 -0.434 0.61117E+04 91 heulandite -5.83 -7.52 -1.69 -0.077 0.28938E+04 95 jadeite 4.22 2.77 -1.44 -0.144 0.24614E+04 97 kalsilite 7.58 3.83 -3.76 -0.536 0.64118E+04 98 kaolinite -1.33 -4.84 -3.50 -0.318 0.59816E+04 101 laumontite 2.88 1.95 -0.93 -0.062 0.15924E+04 102 lawsonite 9.62 8.27 -1.35 -0.090 0.23051E+04 103 leucite 4.12 0.67 -3.45 -0.345 0.58869E+04 105 lizardite 23.24 21.57 -1.68 -0.140 0.28613E+04 107 magnetite 20.09 15.72 -4.37 -0.356 0.74540E+04 108 minnesotaite 10.39 7.57 -2.81 -0.165 0.48038E+04 112 manganosite 14.06 9.22 -4.84 -1.209 0.82563E+04 120 muscovite 2.58 -1.01 -3.59 -0.211 0.61292E+04 121 paragonite 4.24 1.10 -3.14 -0.185 0.53683E+04 122 nepheline 8.34 5.93 -2.41 -0.344 0.41117E+04 128 periclase-Fe 11.63 6.74 -4.89 -1.223 0.83521E+04 134 phlogopite-Na 29.65 27.50 -2.15 -0.119 0.36665E+04 136 prehnite 19.37 18.21 -1.16 -0.068 0.19830E+04 137 prehnite-Fe 22.50 21.96 -0.53 -0.032 0.91110E+03 138 pumpellyite-Fe 46.27 43.90 -2.37 -0.053 0.40530E+04 139 pumpellyite-Mg 48.99 46.46 -2.54 -0.056 0.43366E+04 143 pyrrhotite -4.26 -8.06 -3.80 -1.266 0.64832E+04 144 pyrrhotiteFe0.875 -6.02 -9.46 -3.44 -1.264 0.58706E+04 145 pyroxmangite 7.40 6.07 -1.33 -0.267 0.22771E+04 146 pyrophyllite -6.18 -11.15 -4.98 -0.311 0.84954E+04 147 quartz -2.99 -3.16 -0.17 -0.056 0.28718E+03 152 rhodonite 7.45 6.07 -1.38 -0.276 0.23573E+04 153 sanidine -1.28 -2.49 -1.21 -0.093 0.20677E+04 165 stilpnomelane-Mg 27.44 25.81 -1.63 -0.049 0.27790E+04 171 talc 16.49 15.25 -1.24 -0.073 0.21143E+04 174 tephroite 18.09 15.29 -2.80 -0.400 0.47775E+04 178 tridymite -2.63 -3.16 -0.53 -0.177 0.90716E+03 179 tremolite 47.87 47.42 -0.45 -0.012 0.77507E+03 180 ferroactinolite 38.45 34.62 -3.83 -0.104 0.65463E+04 181 troilite-low -4.41 -8.06 -3.65 -1.215 0.62260E+04 183 vesuvianite 223.47 218.83 -4.64 -0.035 0.79299E+04 187 wairakite 3.95 1.95 -2.00 -0.118 0.34143E+04 188 walstromite 11.51 9.94 -1.56 -0.313 0.26718E+04 189 wollastonite 10.46 9.94 -0.52 -0.103 0.88228E+03 190 pseudo-wollastonite 11.00 9.94 -1.06 -0.211 0.18021E+04 191 zoisite 22.85 18.95 -3.90 -0.177 0.66579E+04 192 akaganeite 7.75 4.49 -3.26 -0.705 0.55684E+04 199 chalcedony -2.80 -3.16 -0.36 -0.118 0.60648E+03 201 montmorillonite-Ca -2.29 -6.17 -3.88 -0.240 0.66175E+04 202 montmorillonite-K -2.24 -6.27 -4.03 -0.247 0.68811E+04 203 montmorillonite-Mg -2.48 -6.79 -4.31 -0.267 0.73672E+04 204 montmorillonite-Na -2.04 -5.57 -3.54 -0.216 0.60360E+04 205 nontronite-Ca 3.21 -0.20 -3.41 -0.221 0.58230E+04 206 nontronite-H 2.53 -2.36 -4.89 -0.328 0.83501E+04 207 nontronite-K 3.34 -0.30 -3.64 -0.233 0.62099E+04 208 nontronite-Mg 3.07 -0.82 -3.90 -0.253 0.66568E+04 209 nontronite-Na 3.52 0.40 -3.12 -0.200 0.53308E+04 224 tobermorite 9.82 7.76 -2.07 -0.564 0.35288E+04 230 alabandite -0.98 -5.57 -4.59 -1.531 0.78403E+04 233 boehmite 4.41 0.74 -3.67 -0.611 0.62608E+04 235 ferrous-oxide 9.81 6.74 -3.08 -0.769 0.52531E+04 240 silica-amorphous -2.09 -3.16 -1.07 -0.355 0.18207E+04 242 an20ab80 2.02 1.35 -0.67 -0.052 0.11468E+04 243 an25ab75 2.65 1.78 -0.87 -0.067 0.14805E+04 244 an30ab70 3.28 2.21 -1.07 -0.082 0.18238E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 4.0000000 g Current total amount of reactant added: 191.9990000 g New total amount of reactant added: 195.9990000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.7165E-13 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 11 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 195.9990000 Water: Moles liquid = 0.5433E+02 kg liquid = 0.9788E+00 Moles total = 0.5305E+02 kg total = 0.9557E+00 Activity = 1.0000 Stoichiometric ionic strength = .1131831E-01 Osmotic coef. = 0.9695 True ionic strength = .2000743E-01 Chg. balance for total moles = -.7165E-13 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.88245E-10 -10.0543 0.74150E-10 -10.1299 0.84028E+00 -0.0756 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.14032E-03 -3.8529 0.11720E-03 -3.9311 0.83523E+00 -0.0782 4 SO4-- 0.65885E-12 -12.1812 0.34219E-12 -12.4657 0.51938E+00 -0.2845 5 HCO3- 0.24387E-06 -6.6128 0.20399E-06 -6.6904 0.83645E+00 -0.0776 6 HS- 0.26052E-04 -4.5842 0.21763E-04 -4.6623 0.83535E+00 -0.0781 7 Al+++ 0.96861E-29 -29.0139 0.22385E-29 -29.6500 0.23111E+00 -0.6362 8 H4SiO4 0.69563E-03 -3.1576 0.69563E-03 -3.1576 0.10000E+01 0.0000 9 Ca++ 0.13489E-06 -6.8700 0.69547E-07 -7.1577 0.51557E+00 -0.2877 10 Mg++ 0.21104E-10 -10.6756 0.10831E-10 -10.9653 0.51321E+00 -0.2897 11 Fe++ 0.58146E-13 -13.2355 0.29874E-13 -13.5247 0.51377E+00 -0.2892 12 K+ 0.15643E-03 -3.8057 0.13088E-03 -3.8831 0.83665E+00 -0.0775 13 Na+ 0.19850E-01 -1.7022 0.16576E-01 -1.7805 0.83508E+00 -0.0783 14 Mn++ 0.17873E-10 -10.7478 0.91903E-11 -11.0367 0.51420E+00 -0.2889 15 HPO4-- 0.45322E-07 -7.3437 0.23543E-07 -7.6281 0.51945E+00 -0.2845 16 HSiO3- 0.10488E-01 -1.9793 0.87598E-02 -2.0575 0.83523E+00 -0.0782 17 Ca(HSiO3)+ 0.16579E-07 -7.7804 0.13874E-07 -7.8578 0.83683E+00 -0.0774 18 Mg(HSiO3)+ 0.32133E-11 -11.4930 0.26890E-11 -11.5704 0.83683E+00 -0.0774 19 NaHSiO3,aq 0.23485E-02 -2.6292 0.23485E-02 -2.6292 0.10000E+01 0.0000 20 AlO+ 0.66187E-16 -16.1792 0.55388E-16 -16.2566 0.83683E+00 -0.0774 22 HAlO2,aq 0.14876E-09 -9.8275 0.14876E-09 -9.8275 0.10000E+01 0.0000 23 AlO2- 0.53264E-05 -5.2736 0.44408E-05 -5.3525 0.83372E+00 -0.0790 24 CH4,aq 0.12646E-04 -4.8981 0.12602E-04 -4.8996 0.99655E+00 -0.0015 25 C2H6,aq 0.23493E-14 -14.6291 0.23412E-14 -14.6306 0.99655E+00 -0.0015 29 CO,aq 0.94151E-17 -17.0262 0.94151E-17 -17.0262 0.10000E+01 0.0000 30 CO2,aq 0.32432E-10 -10.4890 0.32320E-10 -10.4905 0.99655E+00 -0.0015 31 CO3-2 0.46363E-06 -6.3338 0.24029E-06 -6.6193 0.51828E+00 -0.2854 32 CaCO3,aq 0.20954E-09 -9.6787 0.20954E-09 -9.6787 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.43274E-12 -12.3638 0.36213E-12 -12.4411 0.83683E+00 -0.0774 34 CaCl+ 0.15763E-10 -10.8024 0.13191E-10 -10.8797 0.83683E+00 -0.0774 35 CaCl2,aq 0.36729E-15 -15.4350 0.36729E-15 -15.4350 0.10000E+01 0.0000 36 CaOH+ 0.79879E-07 -7.0976 0.66845E-07 -7.1749 0.83683E+00 -0.0774 37 CaSO4,aq 0.75571E-17 -17.1216 0.75571E-17 -17.1216 0.10000E+01 0.0000 38 HCl,aq 0.15925E-14 -14.7979 0.15925E-14 -14.7979 0.10000E+01 0.0000 43 FeCl+ 0.66224E-17 -17.1790 0.55418E-17 -17.2563 0.83683E+00 -0.0774 46 FeO,aq 0.21117E-09 -9.6754 0.21117E-09 -9.6754 0.10000E+01 0.0000 47 FeOH+ 0.15671E-10 -10.8049 0.13114E-10 -10.8823 0.83683E+00 -0.0774 48 HFeO2- 0.35676E-07 -7.4476 0.29797E-07 -7.5258 0.83523E+00 -0.0782 49 FeO+ 0.10977E-16 -16.9595 0.91856E-17 -17.0369 0.83683E+00 -0.0774 51 FeO2- 0.40929E-09 -9.3880 0.34185E-09 -9.4662 0.83523E+00 -0.0782 52 HFeO2,aq 0.32239E-11 -11.4916 0.32239E-11 -11.4916 0.10000E+01 0.0000 53 H2,aq 0.11636E-04 -4.9342 0.11596E-04 -4.9357 0.99655E+00 -0.0015 54 KCl,aq 0.27800E-09 -9.5560 0.27800E-09 -9.5560 0.10000E+01 0.0000 56 KOH,aq 0.75376E-06 -6.1228 0.75376E-06 -6.1228 0.10000E+01 0.0000 57 KSO4- 0.83205E-15 -15.0799 0.69495E-15 -15.1580 0.83523E+00 -0.0782 58 MgCO3,aq 0.81797E-14 -14.0873 0.81797E-14 -14.0873 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.68863E-16 -16.1620 0.57627E-16 -16.2394 0.83683E+00 -0.0774 60 MgCl+ 0.22249E-14 -14.6527 0.18619E-14 -14.7301 0.83683E+00 -0.0774 61 MgOH+ 0.68836E-10 -10.1622 0.57604E-10 -10.2395 0.83683E+00 -0.0774 63 MnO,aq 0.17310E-08 -8.7617 0.17310E-08 -8.7617 0.10000E+01 0.0000 64 MnOH+ 0.44787E-09 -9.3489 0.37479E-09 -9.4262 0.83683E+00 -0.0774 65 MnO2-2 0.20159E-10 -10.6955 0.10448E-10 -10.9810 0.51828E+00 -0.2854 66 HMnO2- 0.20322E-09 -9.6920 0.16973E-09 -9.7702 0.83523E+00 -0.0782 69 MnCl+ 0.79261E-14 -14.1009 0.66328E-14 -14.1783 0.83683E+00 -0.0774 71 NaCl,aq 0.64383E-06 -6.1912 0.64383E-06 -6.1912 0.10000E+01 0.0000 72 NaOH,aq 0.96048E-04 -4.0175 0.96048E-04 -4.0175 0.10000E+01 0.0000 74 OH- 0.93459E-02 -2.0294 0.77919E-02 -2.1084 0.83372E+00 -0.0790 79 HPO3-2 0.16415E-14 -14.7847 0.85078E-15 -15.0702 0.51828E+00 -0.2854 81 H2PO3- 0.15146E-18 -18.8197 0.12651E-18 -18.8979 0.83523E+00 -0.0782 82 H3PO4,aq 0.90533E-18 -18.0432 0.90533E-18 -18.0432 0.10000E+01 0.0000 83 H2PO4- 0.38520E-10 -10.4143 0.32203E-10 -10.4921 0.83602E+00 -0.0778 84 PO4-3 0.10672E-08 -8.9717 0.25905E-09 -9.5866 0.24272E+00 -0.6149 88 HP2O7-3 0.94655E-18 -18.0239 0.21897E-18 -18.6596 0.23134E+00 -0.6358 89 P2O7-4 0.91441E-17 -17.0389 0.70548E-18 -18.1515 0.77152E-01 -1.1127 90 H2S,aq 0.50047E-08 -8.3006 0.49874E-08 -8.3021 0.99655E+00 -0.0015 91 S2-2 0.17462E-14 -14.7579 0.90500E-15 -15.0434 0.51828E+00 -0.2854 97 SO3-2 0.98076E-18 -18.0084 0.51566E-18 -18.2876 0.52577E+00 -0.2792 99 HSO4- 0.29193E-19 -19.5347 0.24453E-19 -19.6117 0.83764E+00 -0.0769 Charge balance for all species = -.7275E-13 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.8824487E-10 -.2230394E-01 -.2244199E+02 0.0000 2 H2O 0.1000000E+01 0.5550489E+02 0.9982004E+06 0.0000 3 Cl- 0.1403209E-03 0.1409650E-03 0.4988951E+01 6.1988 4 SO4-- 0.6588478E-12 -.1555461E-04 -.1491605E+01 7.7940 5 HCO3- 0.2438728E-06 0.1335331E-04 0.8133664E+00 3.4395 6 HS- 0.2605231E-04 0.4161192E-04 0.1373799E+01 5.4676 7 Al+++ 0.9686089E-29 0.5326578E-05 0.1434694E+00 0.7396 8 H4SiO4 0.6956301E-03 0.1353196E-01 0.1298371E+04 -3.1576 9 Ca++ 0.1348934E-06 0.2315776E-06 0.9265045E-02 13.1021 10 Mg++ 0.2110412E-10 0.9316435E-10 0.2261078E-05 9.2944 11 Fe++ 0.5814571E-13 0.3631497E-07 0.2024560E-02 6.7351 12 K+ 0.1564286E-03 0.1571827E-03 0.6135481E+01 6.2467 13 Na+ 0.1984999E-01 0.2229515E-01 0.5116708E+03 8.3494 14 Mn++ 0.1787308E-10 0.2420126E-08 0.1327259E-03 9.2231 15 HPO4-- 0.4532200E-07 0.4642776E-07 0.4448350E-02 12.6316 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.3245439E+01 -.2183073E-01 -.3223609E+01 0.0000000E+00 2 H2O 0.5305132E+02 0.5432727E+02 -.1275945E+01 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.5457305E-02 -.1522459E-04 0.5472529E-02 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.5431800E-02 0.4072906E-04 -.5472529E-02 0.0000000E+00 7 Al+++ 0.6391021E+00 0.5213566E-05 0.6390969E+00 0.0000000E+00 8 H4SiO4 0.2040895E+01 0.1324486E-01 0.2027650E+01 0.0000000E+00 9 Ca++ 0.2254413E+00 0.2266643E-06 0.2254411E+00 0.0000000E+00 10 Mg++ 0.1555548E+00 0.9118772E-10 0.1555548E+00 0.0000000E+00 11 Fe++ 0.1397490E+00 0.3554449E-07 0.1397489E+00 0.0000000E+00 12 K+ 0.4161338E-01 0.1538478E-03 0.4145953E-01 0.0000000E+00 13 Na+ 0.2461866E+00 0.2182213E-01 0.2243644E+00 0.0000000E+00 14 Mn++ 0.3398347E-02 0.2368779E-08 0.3398345E-02 0.0000000E+00 15 HPO4-- 0.1159839E-02 0.4544272E-07 0.1159794E-02 0.0000000E+00 Chg. balance for solid moles: 0.1138E-14 Mass of aqueous solution: 0.980486E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 195.9990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 0.2241 -0.650 58.75 1.769 27.46 22.55 andradite 0.2189E-01 -1.660 11.12 1.046 5.200 2.890 grossular 0.5310E-02 -2.275 2.392 0.379 1.118 0.6656 apatite-OH 0.3866E-03 -3.413 0.1942 -0.712 0.9077E-01 0.6171E-01 clinochlore 0.2907E-01 -1.537 16.16 1.208 7.553 6.146 daphnite 0.8412E-02 -2.075 6.002 0.778 2.806 1.819 chlorite-Mn 0.6797E-03 -3.168 0.4819 -0.317 0.2252 0.1536 diopside 0.1401E-02 -2.853 0.3034 -0.518 0.1418 0.9274E-01 hedenbergite 0.3633E-03 -3.440 0.9012E-01 -1.045 0.4213E-01 0.2468E-01 microcline 0.3641E-01 -1.439 10.13 1.006 4.737 3.959 stilbite 0.1353 -0.869 95.34 1.979 44.56 44.47 stilpnomelane-Fe 0.1010E-01 -1.996 10.89 1.037 5.090 3.761 tr.625ac.25prg.125 0.2429E-02 -2.615 2.076 0.317 0.9704 0.6682 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8048E+00 0.8048E+00 1.0000 -0.094 grossular 0.1952E+00 0.1952E+00 1.0000 -0.709 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.7617E+00 0.7617E+00 1.0000 -0.118 daphnite 0.2204E+00 0.2204E+00 1.0000 -0.657 chlorite-Mn 0.1781E-01 0.1781E-01 1.0000 -1.749 diopside 0.7941E+00 0.7941E+00 1.0000 -0.100 hedenbergite 0.2059E+00 0.2059E+00 1.0000 -0.686 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 tr.625ac.25prg.125 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 213.936171 g Volume = 87.262665 cm3 Porosity: -9.9032% V(tot) - V(min): -.78631E+01 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 195.9990000 g log = 2.2923 Original solution: 1000.0103000 g Original solution / Rock added: 5.10 (Water/Rock Ratio), log = 0.7078 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0543 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9682E+00 0.9855 0.1006E+01 0.1021E+01 CO2,gas 0.3257E-08 1.0069 0.3458E-08 0.3434E-08 CH4,gas 0.1738E-01 1.0125 0.1855E-01 0.1832E-01 H2,gas 0.1443E-01 1.0006 0.1522E-01 0.1522E-01 H2S,gas 0.1306E-06 0.9959 0.1371E-06 0.1377E-06 S2,gas 0.2887E-29 1.0000 0.3044E-29 0.3044E-29 CO,gas 0.1331E-13 1.0000 0.1403E-13 0.1403E-13 SO3,gas 0.6747E-48 1.0000 0.7114E-48 0.7114E-48 SO2,gas 0.3997E-27 1.0000 0.4214E-27 0.4214E-27 HCl,gas 0.2665E-17 1.0000 0.2810E-17 0.2810E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 16 albite -0.38 -0.38 0.00 0.000 -0.94784E-12 22 andradite 39.01 39.01 0.00 0.000 -0.12132E-10 23 grossular 32.73 32.73 0.00 0.000 -0.24265E-10 32 apatite-OH -18.15 -18.15 0.00 0.000 0.60662E-11 46 clinochlore 39.07 39.07 0.00 0.000 0.48529E-10 47 daphnite 28.97 28.97 0.00 0.000 -0.30331E-10 48 chlorite-Mn 46.87 46.87 0.00 0.000 0.24265E-10 67 diopside 16.18 16.18 0.00 0.000 0.60662E-11 68 hedenbergite 14.21 14.21 0.00 0.000 0.90992E-11 116 microcline -2.49 -2.49 0.00 0.000 0.13649E-10 163 stilbite -7.52 -7.52 0.00 0.000 -0.90992E-11 164 stilpnomelane-Fe 13.02 13.02 0.00 0.000 0.69761E-10 245 tr.625ac.25prg.125 45.16 45.16 0.00 0.000 -0.24265E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -16.82 -10.16 -3.387 0.17348E+05 -8.461 3 CH4,gas 4.54 1.11 -3.43 -0.858 0.58577E+04 -1.732 4 H2,gas 8.00 4.48 -3.52 -2.009 0.60042E+04 -1.817 5 H2S,gas -6.23 -14.79 -8.56 -4.281 0.14619E+05 -6.863 6 S2,gas -7.34 -38.55 -31.22 -4.802 0.53300E+05 -29.517 7 CO,gas 3.21 -12.34 -15.55 -4.785 0.26554E+05 -13.853 8 SO3,gas 17.12 -32.73 -49.85 -12.462 0.85112E+05 -48.148 9 SO2,gas 0.83 -28.24 -29.07 -7.753 0.49644E+05 -27.375 10 HCl,gas 5.19 -14.06 -19.25 -9.625 0.32869E+05 -17.551 11 acmite 7.71 6.53 -1.18 -0.123 0.20185E+04 15 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 19 spessartine 24.46 19.68 -4.78 -0.239 0.81645E+04 20 analcite 3.32 2.77 -0.55 -0.061 0.93588E+03 26 annite 20.12 17.72 -2.40 -0.134 0.41060E+04 27 phlogopite 27.06 25.40 -1.67 -0.093 0.28477E+04 29 anorthite 12.71 8.27 -4.44 -0.342 0.75885E+04 35 aragonite 0.97 -3.72 -4.68 -1.562 0.79991E+04 36 brucite 12.57 9.29 -3.27 -0.655 0.55905E+04 37 calcite 0.81 -3.72 -4.53 -1.510 0.77349E+04 38 carnegieite-low 9.02 5.93 -3.09 -0.442 0.52794E+04 39 carnegieite-high 10.09 5.93 -4.16 -0.595 0.71064E+04 40 carpholite-Mg 8.58 4.46 -4.12 -0.275 0.70410E+04 41 carpholite-Fe 6.71 1.90 -4.81 -0.321 0.82190E+04 42 celadonite 5.34 3.65 -1.69 -0.099 0.28878E+04 43 celadonite-Fe 3.88 1.09 -2.79 -0.164 0.47563E+04 44 chrysotile 23.89 21.57 -2.32 -0.194 0.39687E+04 49 chlorite-Al-free 47.17 43.14 -4.04 -0.168 0.68926E+04 51 chloritoid-Fe 9.17 5.06 -4.12 -0.274 0.70295E+04 52 chloritoid-Mn 11.40 7.54 -3.86 -0.257 0.65846E+04 54 coesite -2.38 -3.16 -0.78 -0.261 0.13345E+04 61 cristobalite -2.56 -3.16 -0.60 -0.199 0.10198E+04 63 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71234E+04 65 diaspore 2.87 0.74 -2.13 -0.356 0.36439E+04 66 diamond -3.10 -7.85 -4.75 -1.357 0.81126E+04 71 enstatite 17.26 12.27 -4.99 -0.499 0.85225E+04 73 clinoenstatite 17.17 12.27 -4.89 -0.489 0.83541E+04 75 epidote 24.67 22.70 -1.97 -0.095 0.33569E+04 76 clinozoisite 22.81 18.95 -3.86 -0.175 0.65839E+04 77 epidote-Fe 29.84 26.46 -3.38 -0.176 0.57766E+04 78 fayalite 14.05 10.31 -3.73 -0.533 0.63744E+04 79 ferrosilite 11.15 7.15 -3.99 -0.399 0.68206E+04 83 gibbsite 4.08 0.74 -3.34 -0.477 0.57024E+04 84 glaucophane 22.97 20.80 -2.17 -0.059 0.37128E+04 85 glaucophane-Fe 17.28 13.12 -4.15 -0.112 0.70922E+04 86 graphite -3.55 -7.85 -4.31 -1.231 0.73548E+04 87 greenalite 16.14 13.89 -2.25 -0.187 0.38411E+04 90 hematite 12.57 8.99 -3.58 -0.434 0.61117E+04 91 heulandite -5.83 -7.52 -1.69 -0.077 0.28938E+04 95 jadeite 4.22 2.77 -1.44 -0.144 0.24614E+04 97 kalsilite 7.58 3.83 -3.76 -0.536 0.64118E+04 98 kaolinite -1.33 -4.84 -3.50 -0.318 0.59817E+04 101 laumontite 2.88 1.95 -0.93 -0.062 0.15924E+04 102 lawsonite 9.62 8.27 -1.35 -0.090 0.23051E+04 103 leucite 4.12 0.67 -3.45 -0.345 0.58869E+04 105 lizardite 23.24 21.57 -1.68 -0.140 0.28613E+04 107 magnetite 20.09 15.72 -4.37 -0.356 0.74540E+04 108 minnesotaite 10.39 7.57 -2.81 -0.165 0.48038E+04 112 manganosite 14.06 9.22 -4.84 -1.209 0.82556E+04 120 muscovite 2.58 -1.01 -3.59 -0.211 0.61293E+04 121 paragonite 4.24 1.10 -3.14 -0.185 0.53684E+04 122 nepheline 8.34 5.93 -2.41 -0.344 0.41117E+04 128 periclase-Fe 11.63 6.74 -4.89 -1.223 0.83521E+04 134 phlogopite-Na 29.65 27.50 -2.15 -0.119 0.36665E+04 136 prehnite 19.37 18.21 -1.16 -0.068 0.19830E+04 137 prehnite-Fe 22.50 21.96 -0.53 -0.032 0.91111E+03 138 pumpellyite-Fe 46.27 43.90 -2.37 -0.053 0.40531E+04 139 pumpellyite-Mg 48.99 46.46 -2.54 -0.056 0.43367E+04 143 pyrrhotite -4.26 -8.06 -3.80 -1.266 0.64829E+04 144 pyrrhotiteFe0.875 -6.02 -9.45 -3.44 -1.264 0.58702E+04 145 pyroxmangite 7.40 6.07 -1.33 -0.267 0.22764E+04 146 pyrophyllite -6.18 -11.15 -4.98 -0.311 0.84954E+04 147 quartz -2.99 -3.16 -0.17 -0.056 0.28717E+03 152 rhodonite 7.45 6.07 -1.38 -0.276 0.23566E+04 153 sanidine -1.28 -2.49 -1.21 -0.093 0.20677E+04 165 stilpnomelane-Mg 27.44 25.81 -1.63 -0.049 0.27790E+04 171 talc 16.49 15.25 -1.24 -0.073 0.21143E+04 174 tephroite 18.09 15.29 -2.80 -0.400 0.47761E+04 178 tridymite -2.63 -3.16 -0.53 -0.177 0.90715E+03 179 tremolite 47.87 47.42 -0.45 -0.012 0.77507E+03 180 ferroactinolite 38.45 34.62 -3.83 -0.104 0.65463E+04 181 troilite-low -4.41 -8.06 -3.65 -1.215 0.62257E+04 183 vesuvianite 223.47 218.83 -4.64 -0.035 0.79302E+04 187 wairakite 3.95 1.95 -2.00 -0.118 0.34143E+04 188 walstromite 11.51 9.94 -1.56 -0.313 0.26718E+04 189 wollastonite 10.46 9.94 -0.52 -0.103 0.88228E+03 190 pseudo-wollastonite 11.00 9.94 -1.06 -0.211 0.18021E+04 191 zoisite 22.85 18.95 -3.90 -0.177 0.66579E+04 192 akaganeite 7.75 4.49 -3.26 -0.705 0.55684E+04 199 chalcedony -2.80 -3.16 -0.36 -0.118 0.60647E+03 201 montmorillonite-Ca -2.29 -6.17 -3.88 -0.240 0.66175E+04 202 montmorillonite-K -2.24 -6.27 -4.03 -0.247 0.68811E+04 203 montmorillonite-Mg -2.48 -6.79 -4.31 -0.267 0.73672E+04 204 montmorillonite-Na -2.04 -5.57 -3.54 -0.216 0.60360E+04 205 nontronite-Ca 3.21 -0.20 -3.41 -0.221 0.58230E+04 206 nontronite-H 2.53 -2.36 -4.89 -0.328 0.83500E+04 207 nontronite-K 3.34 -0.30 -3.64 -0.233 0.62099E+04 208 nontronite-Mg 3.07 -0.82 -3.90 -0.253 0.66568E+04 209 nontronite-Na 3.52 0.40 -3.12 -0.200 0.53307E+04 224 tobermorite 9.82 7.76 -2.07 -0.564 0.35288E+04 230 alabandite -0.98 -5.57 -4.59 -1.530 0.78393E+04 233 boehmite 4.41 0.74 -3.67 -0.611 0.62608E+04 235 ferrous-oxide 9.81 6.74 -3.08 -0.769 0.52531E+04 240 silica-amorphous -2.09 -3.16 -1.07 -0.355 0.18206E+04 242 an20ab80 2.02 1.35 -0.67 -0.052 0.11468E+04 243 an25ab75 2.65 1.78 -0.87 -0.067 0.14805E+04 244 an30ab70 3.28 2.21 -1.07 -0.082 0.18238E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 4.0000000 g Current total amount of reactant added: 195.9990000 g New total amount of reactant added: 199.9990000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.7147E-13 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 11 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 199.9990000 Water: Moles liquid = 0.5431E+02 kg liquid = 0.9784E+00 Moles total = 0.5300E+02 kg total = 0.9548E+00 Activity = 1.0000 Stoichiometric ionic strength = .1131840E-01 Osmotic coef. = 0.9695 True ionic strength = .2000752E-01 Chg. balance for total moles = -.7147E-13 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.88245E-10 -10.0543 0.74151E-10 -10.1299 0.84028E+00 -0.0756 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.14038E-03 -3.8527 0.11725E-03 -3.9309 0.83523E+00 -0.0782 4 SO4-- 0.65918E-12 -12.1810 0.34236E-12 -12.4655 0.51938E+00 -0.2845 5 HCO3- 0.24399E-06 -6.6126 0.20409E-06 -6.6902 0.83645E+00 -0.0776 6 HS- 0.26063E-04 -4.5840 0.21772E-04 -4.6621 0.83535E+00 -0.0781 7 Al+++ 0.96860E-29 -29.0139 0.22385E-29 -29.6500 0.23111E+00 -0.6362 8 H4SiO4 0.69564E-03 -3.1576 0.69564E-03 -3.1576 0.10000E+01 0.0000 9 Ca++ 0.13489E-06 -6.8700 0.69547E-07 -7.1577 0.51557E+00 -0.2877 10 Mg++ 0.21104E-10 -10.6756 0.10831E-10 -10.9653 0.51321E+00 -0.2897 11 Fe++ 0.58146E-13 -13.2355 0.29874E-13 -13.5247 0.51377E+00 -0.2892 12 K+ 0.15643E-03 -3.8057 0.13088E-03 -3.8831 0.83665E+00 -0.0775 13 Na+ 0.19850E-01 -1.7022 0.16576E-01 -1.7805 0.83508E+00 -0.0783 14 Mn++ 0.17889E-10 -10.7474 0.91984E-11 -11.0363 0.51420E+00 -0.2889 15 HPO4-- 0.45322E-07 -7.3437 0.23543E-07 -7.6281 0.51945E+00 -0.2845 16 HSiO3- 0.10488E-01 -1.9793 0.87598E-02 -2.0575 0.83523E+00 -0.0782 17 Ca(HSiO3)+ 0.16579E-07 -7.7804 0.13874E-07 -7.8578 0.83683E+00 -0.0774 18 Mg(HSiO3)+ 0.32133E-11 -11.4930 0.26890E-11 -11.5704 0.83683E+00 -0.0774 19 NaHSiO3,aq 0.23485E-02 -2.6292 0.23485E-02 -2.6292 0.10000E+01 0.0000 20 AlO+ 0.66186E-16 -16.1792 0.55386E-16 -16.2566 0.83683E+00 -0.0774 22 HAlO2,aq 0.14875E-09 -9.8275 0.14875E-09 -9.8275 0.10000E+01 0.0000 23 AlO2- 0.53262E-05 -5.2736 0.44406E-05 -5.3526 0.83372E+00 -0.0790 24 CH4,aq 0.12651E-04 -4.8979 0.12607E-04 -4.8994 0.99655E+00 -0.0015 25 C2H6,aq 0.23513E-14 -14.6287 0.23432E-14 -14.6302 0.99655E+00 -0.0015 29 CO,aq 0.94195E-17 -17.0260 0.94195E-17 -17.0260 0.10000E+01 0.0000 30 CO2,aq 0.32448E-10 -10.4888 0.32336E-10 -10.4903 0.99655E+00 -0.0015 31 CO3-2 0.46386E-06 -6.3336 0.24041E-06 -6.6191 0.51828E+00 -0.2854 32 CaCO3,aq 0.20964E-09 -9.6785 0.20964E-09 -9.6785 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.43296E-12 -12.3636 0.36231E-12 -12.4409 0.83683E+00 -0.0774 34 CaCl+ 0.15769E-10 -10.8022 0.13196E-10 -10.8796 0.83683E+00 -0.0774 35 CaCl2,aq 0.36759E-15 -15.4346 0.36759E-15 -15.4346 0.10000E+01 0.0000 36 CaOH+ 0.79879E-07 -7.0976 0.66845E-07 -7.1749 0.83683E+00 -0.0774 37 CaSO4,aq 0.75609E-17 -17.1214 0.75609E-17 -17.1214 0.10000E+01 0.0000 38 HCl,aq 0.15931E-14 -14.7977 0.15931E-14 -14.7977 0.10000E+01 0.0000 43 FeCl+ 0.66252E-17 -17.1788 0.55441E-17 -17.2562 0.83683E+00 -0.0774 46 FeO,aq 0.21117E-09 -9.6754 0.21117E-09 -9.6754 0.10000E+01 0.0000 47 FeOH+ 0.15671E-10 -10.8049 0.13114E-10 -10.8823 0.83683E+00 -0.0774 48 HFeO2- 0.35675E-07 -7.4476 0.29797E-07 -7.5258 0.83523E+00 -0.0782 49 FeO+ 0.10977E-16 -16.9595 0.91858E-17 -17.0369 0.83683E+00 -0.0774 51 FeO2- 0.40929E-09 -9.3880 0.34185E-09 -9.4662 0.83523E+00 -0.0782 52 HFeO2,aq 0.32239E-11 -11.4916 0.32239E-11 -11.4916 0.10000E+01 0.0000 53 H2,aq 0.11636E-04 -4.9342 0.11596E-04 -4.9357 0.99655E+00 -0.0015 54 KCl,aq 0.27812E-09 -9.5558 0.27812E-09 -9.5558 0.10000E+01 0.0000 56 KOH,aq 0.75376E-06 -6.1228 0.75376E-06 -6.1228 0.10000E+01 0.0000 57 KSO4- 0.83247E-15 -15.0796 0.69530E-15 -15.1578 0.83523E+00 -0.0782 58 MgCO3,aq 0.81837E-14 -14.0871 0.81837E-14 -14.0871 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.68897E-16 -16.1618 0.57655E-16 -16.2392 0.83683E+00 -0.0774 60 MgCl+ 0.22258E-14 -14.6525 0.18626E-14 -14.7299 0.83683E+00 -0.0774 61 MgOH+ 0.68836E-10 -10.1622 0.57604E-10 -10.2395 0.83683E+00 -0.0774 63 MnO,aq 0.17325E-08 -8.7613 0.17325E-08 -8.7613 0.10000E+01 0.0000 64 MnOH+ 0.44826E-09 -9.3485 0.37511E-09 -9.4258 0.83683E+00 -0.0774 65 MnO2-2 0.20177E-10 -10.6951 0.10457E-10 -10.9806 0.51828E+00 -0.2854 66 HMnO2- 0.20339E-09 -9.6917 0.16988E-09 -9.7699 0.83523E+00 -0.0782 69 MnCl+ 0.79363E-14 -14.1004 0.66413E-14 -14.1777 0.83683E+00 -0.0774 71 NaCl,aq 0.64410E-06 -6.1910 0.64410E-06 -6.1910 0.10000E+01 0.0000 72 NaOH,aq 0.96048E-04 -4.0175 0.96048E-04 -4.0175 0.10000E+01 0.0000 74 OH- 0.93459E-02 -2.0294 0.77919E-02 -2.1084 0.83372E+00 -0.0790 79 HPO3-2 0.16415E-14 -14.7848 0.85077E-15 -15.0702 0.51828E+00 -0.2854 81 H2PO3- 0.15146E-18 -18.8197 0.12650E-18 -18.8979 0.83523E+00 -0.0782 82 H3PO4,aq 0.90534E-18 -18.0432 0.90534E-18 -18.0432 0.10000E+01 0.0000 83 H2PO4- 0.38520E-10 -10.4143 0.32204E-10 -10.4921 0.83602E+00 -0.0778 84 PO4-3 0.10672E-08 -8.9717 0.25905E-09 -9.5866 0.24272E+00 -0.6149 88 HP2O7-3 0.94657E-18 -18.0238 0.21898E-18 -18.6596 0.23134E+00 -0.6358 89 P2O7-4 0.91443E-17 -17.0388 0.70550E-18 -18.1515 0.77151E-01 -1.1127 90 H2S,aq 0.50068E-08 -8.3004 0.49895E-08 -8.3019 0.99655E+00 -0.0015 91 S2-2 0.17476E-14 -14.7576 0.90576E-15 -15.0430 0.51828E+00 -0.2854 97 SO3-2 0.98123E-18 -18.0082 0.51590E-18 -18.2874 0.52577E+00 -0.2792 99 HSO4- 0.29207E-19 -19.5345 0.24465E-19 -19.6114 0.83764E+00 -0.0769 Charge balance for all species = -.7202E-13 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.8824529E-10 -.2230399E-01 -.2244203E+02 0.0000 2 H2O 0.1000000E+01 0.5550489E+02 0.9982004E+06 0.0000 3 Cl- 0.1403785E-03 0.1410229E-03 0.4990999E+01 6.1990 4 SO4-- 0.6591780E-12 -.1555967E-04 -.1492091E+01 7.7943 5 HCO3- 0.2439937E-06 0.1335879E-04 0.8137004E+00 3.4397 6 HS- 0.2606301E-04 0.4162769E-04 0.1374320E+01 5.4678 7 Al+++ 0.9685954E-29 0.5326396E-05 0.1434645E+00 0.7396 8 H4SiO4 0.6956371E-03 0.1353205E-01 0.1298379E+04 -3.1576 9 Ca++ 0.1348934E-06 0.2315773E-06 0.9265034E-02 13.1020 10 Mg++ 0.2110410E-10 0.9316391E-10 0.2261067E-05 9.2944 11 Fe++ 0.5814607E-13 0.3631468E-07 0.2024543E-02 6.7351 12 K+ 0.1564294E-03 0.1571834E-03 0.6135509E+01 6.2467 13 Na+ 0.1985008E-01 0.2229527E-01 0.5116734E+03 8.3494 14 Mn++ 0.1788876E-10 0.2422226E-08 0.1328411E-03 9.2235 15 HPO4-- 0.4532242E-07 0.4642819E-07 0.4448391E-02 12.6316 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.3311673E+01 -.2182181E-01 -.3289852E+01 0.0000000E+00 2 H2O 0.5300118E+02 0.5430497E+02 -.1303790E+01 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.5568159E-02 -.1522330E-04 0.5583382E-02 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.5542654E-02 0.4072777E-04 -.5583382E-02 0.0000000E+00 7 Al+++ 0.6521451E+00 0.5211249E-05 0.6521399E+00 0.0000000E+00 8 H4SiO4 0.2082546E+01 0.1323951E-01 0.2069307E+01 0.0000000E+00 9 Ca++ 0.2300419E+00 0.2265710E-06 0.2300416E+00 0.0000000E+00 10 Mg++ 0.1587294E+00 0.9114987E-10 0.1587294E+00 0.0000000E+00 11 Fe++ 0.1426010E+00 0.3552962E-07 0.1426010E+00 0.0000000E+00 12 K+ 0.4246263E-01 0.1537854E-03 0.4230885E-01 0.0000000E+00 13 Na+ 0.2512075E+00 0.2181328E-01 0.2293943E+00 0.0000000E+00 14 Mn++ 0.3467702E-02 0.2369861E-08 0.3467699E-02 0.0000000E+00 15 HPO4-- 0.1183509E-02 0.4542450E-07 0.1183464E-02 0.0000000E+00 Chg. balance for solid moles: -.1674E-15 Mass of aqueous solution: 0.980084E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 199.9990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 0.2291 -0.640 60.07 1.779 27.52 23.06 andradite 0.2233E-01 -1.651 11.35 1.055 5.199 2.949 grossular 0.5418E-02 -2.266 2.440 0.387 1.118 0.6790 apatite-OH 0.3945E-03 -3.404 0.1982 -0.703 0.9077E-01 0.6297E-01 clinochlore 0.2964E-01 -1.528 16.47 1.217 7.546 6.266 daphnite 0.8577E-02 -2.067 6.120 0.787 2.803 1.854 chlorite-Mn 0.6935E-03 -3.159 0.4917 -0.308 0.2252 0.1567 diopside 0.1619E-02 -2.791 0.3506 -0.455 0.1606 0.1071 hedenbergite 0.4197E-03 -3.377 0.1041 -0.982 0.4769E-01 0.2852E-01 microcline 0.3715E-01 -1.430 10.34 1.015 4.737 4.040 stilbite 0.1379 -0.861 97.15 1.987 44.50 45.31 stilpnomelane-Fe 0.1031E-01 -1.987 11.11 1.046 5.091 3.839 tr.625ac.25prg.125 0.2462E-02 -2.609 2.105 0.323 0.9640 0.6773 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8048E+00 0.8048E+00 1.0000 -0.094 grossular 0.1952E+00 0.1952E+00 1.0000 -0.709 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.7617E+00 0.7617E+00 1.0000 -0.118 daphnite 0.2204E+00 0.2204E+00 1.0000 -0.657 chlorite-Mn 0.1783E-01 0.1783E-01 1.0000 -1.749 diopside 0.7941E+00 0.7941E+00 1.0000 -0.100 hedenbergite 0.2059E+00 0.2059E+00 1.0000 -0.686 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 tr.625ac.25prg.125 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 218.306193 g Volume = 89.030788 cm3 Porosity: -9.9151% V(tot) - V(min): -.80312E+01 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 199.9990000 g log = 2.3010 Original solution: 1000.0103000 g Original solution / Rock added: 5.00 (Water/Rock Ratio), log = 0.6990 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0543 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9682E+00 0.9855 0.1006E+01 0.1021E+01 CO2,gas 0.3259E-08 1.0069 0.3460E-08 0.3436E-08 CH4,gas 0.1738E-01 1.0125 0.1856E-01 0.1833E-01 H2,gas 0.1443E-01 1.0006 0.1522E-01 0.1522E-01 H2S,gas 0.1306E-06 0.9959 0.1372E-06 0.1377E-06 S2,gas 0.2890E-29 1.0000 0.3047E-29 0.3047E-29 CO,gas 0.1331E-13 1.0000 0.1404E-13 0.1404E-13 SO3,gas 0.6751E-48 1.0000 0.7118E-48 0.7118E-48 SO2,gas 0.3998E-27 1.0000 0.4216E-27 0.4216E-27 HCl,gas 0.2666E-17 1.0000 0.2811E-17 0.2811E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 16 albite -0.38 -0.38 0.00 0.000 -0.94784E-12 22 andradite 39.01 39.01 0.00 0.000 0.00000E+00 23 grossular 32.73 32.73 0.00 0.000 -0.12132E-10 32 apatite-OH -18.15 -18.15 0.00 0.000 0.00000E+00 46 clinochlore 39.07 39.07 0.00 0.000 0.00000E+00 47 daphnite 28.97 28.97 0.00 0.000 0.48529E-10 48 chlorite-Mn 46.87 46.87 0.00 0.000 0.12132E-10 67 diopside 16.18 16.18 0.00 0.000 0.00000E+00 68 hedenbergite 14.21 14.21 0.00 0.000 0.30331E-11 116 microcline -2.49 -2.49 0.00 0.000 0.13649E-10 163 stilbite -7.52 -7.52 0.00 0.000 -0.90992E-11 164 stilpnomelane-Fe 13.02 13.02 0.00 0.000 -0.27298E-10 245 tr.625ac.25prg.125 45.16 45.16 0.00 0.000 -0.12132E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -16.82 -10.16 -3.387 0.17348E+05 -8.461 3 CH4,gas 4.54 1.11 -3.43 -0.858 0.58574E+04 -1.731 4 H2,gas 8.00 4.48 -3.52 -2.009 0.60042E+04 -1.817 5 H2S,gas -6.23 -14.79 -8.56 -4.281 0.14619E+05 -6.863 6 S2,gas -7.34 -38.55 -31.22 -4.802 0.53299E+05 -29.516 7 CO,gas 3.21 -12.34 -15.55 -4.785 0.26554E+05 -13.853 8 SO3,gas 17.12 -32.73 -49.85 -12.462 0.85112E+05 -48.148 9 SO2,gas 0.83 -28.24 -29.07 -7.753 0.49643E+05 -27.375 10 HCl,gas 5.19 -14.06 -19.25 -9.625 0.32869E+05 -17.551 11 acmite 7.71 6.53 -1.18 -0.123 0.20185E+04 15 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 19 spessartine 24.46 19.68 -4.78 -0.239 0.81626E+04 20 analcite 3.32 2.77 -0.55 -0.061 0.93588E+03 26 annite 20.12 17.72 -2.40 -0.134 0.41060E+04 27 phlogopite 27.06 25.40 -1.67 -0.093 0.28477E+04 29 anorthite 12.71 8.27 -4.44 -0.342 0.75885E+04 35 aragonite 0.97 -3.72 -4.68 -1.562 0.79987E+04 36 brucite 12.57 9.29 -3.27 -0.655 0.55905E+04 37 calcite 0.81 -3.72 -4.53 -1.510 0.77345E+04 38 carnegieite-low 9.02 5.93 -3.09 -0.442 0.52794E+04 39 carnegieite-high 10.09 5.93 -4.16 -0.595 0.71064E+04 40 carpholite-Mg 8.58 4.46 -4.12 -0.275 0.70411E+04 41 carpholite-Fe 6.71 1.90 -4.81 -0.321 0.82191E+04 42 celadonite 5.34 3.65 -1.69 -0.099 0.28878E+04 43 celadonite-Fe 3.88 1.09 -2.79 -0.164 0.47563E+04 44 chrysotile 23.89 21.57 -2.32 -0.194 0.39687E+04 49 chlorite-Al-free 47.17 43.14 -4.04 -0.168 0.68926E+04 51 chloritoid-Fe 9.17 5.06 -4.12 -0.274 0.70296E+04 52 chloritoid-Mn 11.40 7.55 -3.86 -0.257 0.65840E+04 54 coesite -2.38 -3.16 -0.78 -0.261 0.13345E+04 61 cristobalite -2.56 -3.16 -0.60 -0.199 0.10198E+04 63 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71234E+04 65 diaspore 2.87 0.74 -2.13 -0.356 0.36439E+04 66 diamond -3.10 -7.85 -4.75 -1.357 0.81123E+04 71 enstatite 17.26 12.27 -4.99 -0.499 0.85225E+04 73 clinoenstatite 17.17 12.27 -4.89 -0.489 0.83541E+04 75 epidote 24.67 22.70 -1.97 -0.095 0.33570E+04 76 clinozoisite 22.81 18.95 -3.86 -0.175 0.65839E+04 77 epidote-Fe 29.84 26.46 -3.38 -0.176 0.57766E+04 78 fayalite 14.05 10.31 -3.73 -0.533 0.63744E+04 79 ferrosilite 11.15 7.15 -3.99 -0.399 0.68206E+04 83 gibbsite 4.08 0.74 -3.34 -0.477 0.57024E+04 84 glaucophane 22.97 20.80 -2.17 -0.059 0.37128E+04 85 glaucophane-Fe 17.28 13.12 -4.15 -0.112 0.70922E+04 86 graphite -3.55 -7.85 -4.31 -1.231 0.73545E+04 87 greenalite 16.14 13.89 -2.25 -0.187 0.38410E+04 90 hematite 12.57 8.99 -3.58 -0.434 0.61117E+04 91 heulandite -5.83 -7.52 -1.69 -0.077 0.28938E+04 95 jadeite 4.22 2.77 -1.44 -0.144 0.24614E+04 97 kalsilite 7.58 3.83 -3.76 -0.536 0.64118E+04 98 kaolinite -1.33 -4.84 -3.50 -0.318 0.59817E+04 101 laumontite 2.88 1.95 -0.93 -0.062 0.15924E+04 102 lawsonite 9.62 8.27 -1.35 -0.090 0.23052E+04 103 leucite 4.12 0.67 -3.45 -0.345 0.58869E+04 105 lizardite 23.24 21.57 -1.68 -0.140 0.28613E+04 107 magnetite 20.09 15.72 -4.37 -0.356 0.74540E+04 108 minnesotaite 10.39 7.57 -2.81 -0.165 0.48038E+04 112 manganosite 14.06 9.22 -4.83 -1.209 0.82550E+04 120 muscovite 2.58 -1.01 -3.59 -0.211 0.61293E+04 121 paragonite 4.24 1.10 -3.14 -0.185 0.53684E+04 122 nepheline 8.34 5.93 -2.41 -0.344 0.41117E+04 128 periclase-Fe 11.63 6.74 -4.89 -1.223 0.83521E+04 134 phlogopite-Na 29.65 27.50 -2.15 -0.119 0.36665E+04 136 prehnite 19.37 18.21 -1.16 -0.068 0.19831E+04 137 prehnite-Fe 22.50 21.96 -0.53 -0.032 0.91112E+03 138 pumpellyite-Fe 46.27 43.90 -2.37 -0.053 0.40532E+04 139 pumpellyite-Mg 48.99 46.45 -2.54 -0.056 0.43368E+04 143 pyrrhotite -4.26 -8.06 -3.80 -1.266 0.64826E+04 144 pyrrhotiteFe0.875 -6.02 -9.45 -3.44 -1.264 0.58699E+04 145 pyroxmangite 7.40 6.07 -1.33 -0.267 0.22757E+04 146 pyrophyllite -6.18 -11.15 -4.98 -0.311 0.84954E+04 147 quartz -2.99 -3.16 -0.17 -0.056 0.28717E+03 152 rhodonite 7.45 6.07 -1.38 -0.276 0.23560E+04 153 sanidine -1.28 -2.49 -1.21 -0.093 0.20677E+04 165 stilpnomelane-Mg 27.44 25.81 -1.63 -0.049 0.27790E+04 171 talc 16.49 15.25 -1.24 -0.073 0.21143E+04 174 tephroite 18.09 15.29 -2.80 -0.399 0.47749E+04 178 tridymite -2.63 -3.16 -0.53 -0.177 0.90714E+03 179 tremolite 47.87 47.42 -0.45 -0.012 0.77507E+03 180 ferroactinolite 38.45 34.62 -3.83 -0.104 0.65463E+04 181 troilite-low -4.41 -8.06 -3.65 -1.215 0.62254E+04 183 vesuvianite 223.47 218.83 -4.64 -0.035 0.79305E+04 187 wairakite 3.95 1.95 -2.00 -0.118 0.34144E+04 188 walstromite 11.51 9.94 -1.56 -0.313 0.26718E+04 189 wollastonite 10.46 9.94 -0.52 -0.103 0.88228E+03 190 pseudo-wollastonite 11.00 9.94 -1.06 -0.211 0.18021E+04 191 zoisite 22.85 18.95 -3.90 -0.177 0.66580E+04 192 akaganeite 7.75 4.49 -3.26 -0.705 0.55684E+04 199 chalcedony -2.80 -3.16 -0.36 -0.118 0.60646E+03 201 montmorillonite-Ca -2.29 -6.17 -3.88 -0.240 0.66175E+04 202 montmorillonite-K -2.24 -6.27 -4.03 -0.247 0.68811E+04 203 montmorillonite-Mg -2.48 -6.79 -4.31 -0.267 0.73672E+04 204 montmorillonite-Na -2.04 -5.57 -3.54 -0.216 0.60360E+04 205 nontronite-Ca 3.21 -0.20 -3.41 -0.221 0.58230E+04 206 nontronite-H 2.53 -2.36 -4.89 -0.328 0.83500E+04 207 nontronite-K 3.34 -0.30 -3.64 -0.233 0.62098E+04 208 nontronite-Mg 3.07 -0.82 -3.90 -0.253 0.66568E+04 209 nontronite-Na 3.52 0.40 -3.12 -0.200 0.53307E+04 224 tobermorite 9.82 7.76 -2.07 -0.564 0.35288E+04 230 alabandite -0.98 -5.57 -4.59 -1.530 0.78384E+04 233 boehmite 4.41 0.74 -3.67 -0.611 0.62608E+04 235 ferrous-oxide 9.81 6.74 -3.08 -0.769 0.52531E+04 240 silica-amorphous -2.09 -3.16 -1.07 -0.355 0.18206E+04 242 an20ab80 2.02 1.35 -0.67 -0.052 0.11468E+04 243 an25ab75 2.65 1.78 -0.87 -0.067 0.14805E+04 244 an30ab70 3.28 2.21 -1.07 -0.082 0.18238E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 4.0000000 g Current total amount of reactant added: 199.9990000 g New total amount of reactant added: 203.9990000 g Mixing fraction reached given limit of 0.2000E+03 TOTMIX = 0.2040E+03 Execution stopped.