File SKIP_SPECIES.TXT lists species and minerals omitted from the calculations due to given T, P, option switches, or suppression in CHIMRUN, or are suppressed in the SOLTHERM database. It also lists minerals for which density is not specified in SOLTHERM. This is an extended P(to 5 kB), T(to 600 C) run (CON_FLAG = 1). methanol,aq is suppressed in SOLTHERM data file. methanol,aq is suppressed in SOLTHERM data file. CuCl4-3 is suppressed in SOLTHERM data file. H2BO3- is suppressed in SOLTHERM data file. UO2CO3,aq is suppressed in SOLTHERM data file. UO2SO4,aq is suppressed in SOLTHERM data file. UO2Cl2,aq is suppressed in SOLTHERM data file. UO2F2,aq is suppressed in SOLTHERM data file. PO4-3 is suppressed in SOLTHERM data file. H2PO4- is suppressed in SOLTHERM data file. H3PO4 is suppressed in SOLTHERM data file. O2,gas is suppressed in THIS RUN. O2,gas is suppressed in THIS RUN. amesite is suppressed in SOLTHERM data file. antigorite is suppressed in SOLTHERM data file. goethite is suppressed in THIS RUN. goethite is suppressed in THIS RUN. riebeckite is suppressed in THIS RUN. riebeckite is suppressed in THIS RUN. sapphirine-Fe(221) is suppressed in SOLTHERM data file. sapphirine(221) is suppressed in SOLTHERM data file. talc-prl is suppressed in SOLTHERM data file. PrO1.833(s) is suppressed in SOLTHERM data file. niter-NH4 is suppressed in SOLTHERM data file. FMQ_HS-1 is suppressed in THIS RUN. kf-ab-equil is suppressed in THIS RUN. ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Species No. Charge Tot.moles Trial molality Gamma Mixing solution H+ 1 1. -0.33117E+01 0.88245E-10 0.8403 0.00000000E+00 H2O 2 0. 0.53001E+02 0.10000E+01 1.0000 0.00000000E+00 Cl- 3 -1. 0.13797E-03 0.14038E-03 0.8352 0.00000000E+00 SO4-- 4 -2. 0.55682E-02 0.65918E-12 0.5194 0.00000000E+00 HCO3- 5 -1. 0.13070E-04 0.24399E-06 0.8364 0.00000000E+00 HS- 6 -1. -0.55427E-02 0.26063E-04 0.8354 0.00000000E+00 Al+++ 7 3. 0.65215E+00 0.96860E-29 0.2311 0.00000000E+00 H4SiO4 8 0. 0.20825E+01 0.69564E-03 1.0000 0.00000000E+00 Ca++ 9 2. 0.23004E+00 0.13489E-06 0.5156 0.00000000E+00 Mg++ 10 2. 0.15873E+00 0.21104E-10 0.5132 0.00000000E+00 Fe++ 11 2. 0.14260E+00 0.58146E-13 0.5138 0.00000000E+00 K+ 12 1. 0.42463E-01 0.15643E-03 0.8366 0.00000000E+00 Na+ 13 1. 0.25121E+00 0.19850E-01 0.8351 0.00000000E+00 Mn++ 14 2. 0.34677E-02 0.17889E-10 0.5142 0.00000000E+00 HPO4-- 15 -2. 0.11835E-02 0.45322E-07 0.5195 0.00000000E+00 Chg. balance for total moles = 0.3650E-11 Max. difference allowed = 0.1380E-07 The following parameters were given: ERPC = 0.1000E-11 pH = 0.0000 PFLUID = 50.0000 SLIM = 0.400000E+03 TEMP = 100.0000 SINC = 0.1000E+02 TEMPC = 0.0000 TOTMIX = 0.199999E+03 ENTH = 0.0000 SENTH = 0.0000 DENTH = 0.0000 TOTWAT = 90.0000 SOLMIN = 0.0000E+00 RM = 0.0000 AQGRM = 1000.0103 SUPRNT = 0.1000E-19 VBOX-1 = 80.9996 RHOFRS = 0.0000 RHOROC = 2.5000 The following options were selected: CONFLG = 1 C = 3 IFRAC = 0 IPUNCH = 2 NLOOP = 400 ISTEP = 2 LIMSOL = 1 LOOC = 0 IENTH = 0 ITREF = 0 IDEAL = 0 IPSAT = 1 INCREM = 0 INCP = 0 MINSOL = 1 NEUT = 0 AWAT = 0 CHGF = 0 Of the derived species, only those with molality > 0.10E-19 will appear in the output Species No. Charge Log K(diss) Species No. Charge Log K(diss) HSiO3- 16 -1. 9.0298 MnO2-2 65 -2. 40.4638 Ca(HSiO3)+ 17 1. 7.6723 HMnO2- 66 -1. 29.1232 Mg(HSiO3)+ 18 1. 7.5773 MnO4- 67 -1. 83.3111 NaHSiO3,aq 19 0. 7.8210 MnO4-2 68 -2. 81.3005 AlO+ 20 1. 6.8663 MnCl+ 69 1. -0.7894 AlOH+2 21 2. 3.1691 MnSO4,aq 70 0. -2.4604 HAlO2,aq 22 0. 10.5671 NaCl,aq 71 0. 0.4796 AlO2- 23 -1. 16.2221 NaOH,aq 72 0. 12.3669 CH4,aq 24 0. 6.0126 O2,aq 73 0. 53.5502 C2H6,aq 25 0. 12.3733 OH- 74 -1. 12.2382 C3H8,aq 26 0. 17.3707 HO2- 75 -1. 50.8010 C4H10,aq 27 0. 22.3757 H2O2,aq 76 0. 40.0166 ethanol,aq 28 0. 15.3258 H3PO2,aq 77 0. 24.3066 CO,aq 29 0. 4.6892 H2PO2- 78 -1. 26.5366 CO2,aq 30 0. -6.3298 HPO3-2 79 -2. 11.9254 CO3-2 31 -2. 10.0588 H3PO3,aq 80 0. 3.5792 CaCO3,aq 32 0. 5.9605 H2PO3- 81 -1. 5.6232 Ca(HCO3)+ 33 1. -1.4070 H3PO4,aq 82 0. -9.8447 CaCl+ 34 1. -0.2091 H2PO4- 83 -1. -7.2659 CaCl2,aq 35 0. 0.4151 PO4-3 84 -3. 12.0884 CaOH+ 36 1. 10.1471 H4P2O7,aq 85 0. -17.8095 CaSO4,aq 37 0. -2.5018 H3P2O7- 86 -1. -15.9156 HCl,aq 38 0. 0.7370 H2P2O7-2 87 -2. -13.4262 HClO,aq 39 0. 32.4260 HP2O7-3 88 -3. -6.7266 ClO- 40 -1. 39.6530 P2O7-4 89 -4. 2.8952 HClO2,aq 41 0. 70.1812 H2S,aq 90 0. -6.4900 Fe+3 42 3. 8.3809 S2-2 91 -2. 1.2355 FeCl+ 43 1. -0.1994 S3-2 92 -2. -8.8031 FeCl2,aq 44 0. 4.3001 S3- 93 -1. -16.3389 FeCl+2 45 2. 6.5269 S4-2 94 -2. -18.6615 FeO,aq 46 0. 16.4104 S5-2 95 -2. -28.3439 FeOH+ 47 1. 7.4874 SO2,aq 96 0. -0.2309 HFeO2- 48 -1. 24.3908 SO3-2 97 -2. 10.3052 FeO+ 49 1. 11.4004 HSO3- 98 -1. 2.5086 FeOH+2 50 2. 9.1194 HSO4- 99 -1. -2.9839 FeO2- 51 -1. 24.0895 HSO5- 100 -1. 38.8366 HFeO2,aq 52 0. 15.9850 S2O3-2 101 -2. -4.5600 H2,aq 53 0. 9.4190 HS2O3- 102 -1. -6.8123 KCl,aq 54 0. 1.7417 H2S2O3,aq 103 0. -8.0173 KHSO4,aq 55 0. -0.4514 S2O4-2 104 -2. 10.5541 KOH,aq 56 0. 12.3695 HS2O4- 105 -1. 7.6551 KSO4- 57 -1. -1.1908 H2S2O4,aq 106 0. 6.6259 MgCO3,aq 58 0. 6.5614 S2O5-2 107 -2. 10.0741 Mg(HCO3)+ 59 1. -1.4164 S2O6-2 108 -2. 11.5521 MgCl+ 60 1. -0.1664 S2O8-2 109 -2. 42.0620 MgOH+ 61 1. 9.4041 S3O6-2 110 -2. 3.7866 Mn+3 62 3. 19.1453 S4O6-2 111 -2. -17.8657 MnO,aq 63 0. 17.9848 S5O6-2 112 -2. -14.1333 MnOH+ 64 1. 8.5194 113 0. 10.3111 For mixed gases (JSOLS=6), log K(hydrol) = log (K*P) Log K Trial Log K Trial Mineral No. hydrol Moles Mineral No. hydrol Moles H2O,gas 1 1.696 0.0000E+00 osumilite(2) 124 20.667 0.0000E+00 CO2,gas 2 -6.660 0.0000E+00 osumilite-Fe 125 14.390 0.0000E+00 CH4,gas 3 4.544 0.0000E+00 pargasite 126 65.092 0.0000E+00 H2,gas 4 8.000 0.0000E+00 periclase 127 16.138 0.0000E+00 H2S,gas 5 -6.230 0.0000E+00 periclase-Fe 128 11.627 0.0000E+00 S2,gas 6 -7.335 0.0000E+00 perovskite-Al 129 12.344 0.0000E+00 CO,gas 7 3.215 0.0000E+00 perovskite-Ca 130 23.807 0.0000E+00 SO3,gas 8 17.121 0.0000E+00 perovskite-Fe 131 21.143 0.0000E+00 SO2,gas 9 0.832 0.0000E+00 perovskite-Mg 132 23.119 0.0000E+00 HCl,gas 10 5.189 0.0000E+00 phase_A 133 80.189 0.0000E+00 acmite 11 7.710 0.0000E+00 phlogopite-Na 134 29.647 0.0000E+00 akermanite 12 36.442 0.0000E+00 piemontite(ordered) 135 33.776 0.0000E+00 akimotoite 13 16.591 0.0000E+00 prehnite 136 19.372 0.0000E+00 akimotoite-Fe 14 13.067 0.0000E+00 prehnite-Fe 137 22.498 0.0000E+00 albite-high 15 0.693 0.0000E+00 pumpellyite-Fe 138 46.269 0.0000E+00 albite 16 -0.384 0.2291E+00 pumpellyite-Mg 139 48.995 0.0000E+00 almandine 17 24.442 0.0000E+00 px-Mg-tschermaks 140 19.616 0.0000E+00 pyrope 18 37.248 0.0000E+00 px-Ca-tschermaks 141 18.610 0.0000E+00 spessartine 19 24.457 0.0000E+00 pyrite 142 -21.247 0.0000E+00 analcite 20 3.322 0.0000E+00 pyrrhotite 143 -4.260 0.0000E+00 andalusite 21 5.002 0.0000E+00 pyrrhotiteFe0.875 144 -6.017 0.0000E+00 andradite 22 39.009 0.2233E-01 pyroxmangite 145 7.399 0.0000E+00 grossular 23 32.731 0.5418E-02 pyrophyllite 146 -6.176 0.0000E+00 anhydrite 24 -5.317 0.0000E+00 quartz 147 -2.989 0.0000E+00 ankerite 25 -2.135 0.0000E+00 rankinite 148 40.713 0.0000E+00 annite 26 20.123 0.0000E+00 ringwoodite-Fe 149 15.456 0.0000E+00 phlogopite 27 27.065 0.0000E+00 ringwoodite-Mg 150 27.575 0.0000E+00 biotite-Mn 28 32.960 0.0000E+00 rhodochrosite 151 -0.976 0.0000E+00 anorthite 29 12.710 0.0000E+00 rhodonite 152 7.446 0.0000E+00 anthophyllite 30 51.852 0.0000E+00 sanidine 153 -1.275 0.0000E+00 anthophyllite-Fe 31 29.306 0.0000E+00 sapphirine(351) 154 78.899 0.0000E+00 apatite-OH 32 -18.153 0.3945E-03 siderite 155 -2.608 0.0000E+00 apatite-OH-zs 33 -12.736 0.0000E+00 sillimanite 156 5.262 0.0000E+00 apatite-Cl-zs 34 -16.674 0.0000E+00 sodalite 157 49.976 0.0000E+00 aragonite 35 0.967 0.0000E+00 spinel 158 20.870 0.0000E+00 brucite 36 12.569 0.0000E+00 spurrite 159 59.482 0.0000E+00 calcite 37 0.812 0.0000E+00 staurolite-Fe 160 73.598 0.0000E+00 carnegieite-low 38 9.023 0.0000E+00 staurolite-Mg 161 89.802 0.0000E+00 carnegieite-high 39 10.093 0.0000E+00 staurolite-Mn 162 83.909 0.0000E+00 carpholite-Mg 40 8.582 0.0000E+00 stilbite 163 -7.522 0.1379E+00 carpholite-Fe 41 6.713 0.0000E+00 stilpnomelane-Fe 164 13.017 0.1031E-01 celadonite 42 5.342 0.0000E+00 stilpnomelane-Mg 165 27.441 0.0000E+00 celadonite-Fe 43 3.877 0.0000E+00 stishovite 166 2.720 0.0000E+00 chrysotile 44 23.892 0.0000E+00 sudoite-Fe 167 18.296 0.0000E+00 chondrodite 45 56.475 0.0000E+00 sudoite 168 21.077 0.0000E+00 clinochlore 46 39.070 0.2964E-01 sulfur 169 -9.152 0.0000E+00 daphnite 47 28.965 0.8577E-02 sylvite 170 1.338 0.0000E+00 chlorite-Mn 48 46.869 0.6935E-03 talc 171 16.491 0.0000E+00 chlorite-Al-free 49 47.173 0.0000E+00 talc-Fe 172 13.448 0.0000E+00 chloritoid-Mg 50 13.198 0.0000E+00 talc-tschermaks 173 19.091 0.0000E+00 chloritoid-Fe 51 9.174 0.0000E+00 tephroite 174 18.086 0.0000E+00 chloritoid-Mn 52 11.401 0.0000E+00 tilleyite 175 41.377 0.0000E+00 clinohumite 53 97.128 0.0000E+00 titanite-CaSi 176 15.479 0.0000E+00 coesite 54 -2.376 0.0000E+00 topaz-H 177 4.618 0.0000E+00 cordierite-H 55 23.715 0.0000E+00 tridymite 178 -2.626 0.0000E+00 cordierite 56 24.049 0.0000E+00 tremolite 179 47.869 0.0000E+00 cordierite-Fe 57 20.450 0.0000E+00 ferroactinolite 180 38.452 0.0000E+00 cordierite-Mn 58 25.066 0.0000E+00 troilite-low 181 -4.411 0.0000E+00 corundum 59 8.383 0.0000E+00 tschermakite 182 48.210 0.0000E+00 corundum-MgSi 60 18.891 0.0000E+00 vesuvianite 183 223.471 0.0000E+00 cristobalite 61 -2.560 0.0000E+00 wadeite-Si 184 20.216 0.0000E+00 cummingtonite 62 52.099 0.0000E+00 wadsleyite-Fe 185 15.680 0.0000E+00 cymrite-K 63 1.685 0.0000E+00 wadsleyite-Mg 186 25.850 0.0000E+00 deerite 64 95.671 0.0000E+00 wairakite 187 3.950 0.0000E+00 diaspore 65 2.874 0.0000E+00 walstromite 188 11.509 0.0000E+00 diamond 66 -3.102 0.0000E+00 wollastonite 189 10.461 0.0000E+00 diopside 67 16.181 0.1619E-02 pseudo-wollastonite 190 11.000 0.0000E+00 hedenbergite 68 14.208 0.4197E-03 zoisite 191 22.849 0.0000E+00 dolomite,ordered 69 0.546 0.0000E+00 akaganeite 192 7.755 0.0000E+00 eastonite 70 28.489 0.0000E+00 beidellite-Ca 193 -1.646 0.0000E+00 enstatite 71 17.265 0.0000E+00 beidellite-H 194 -2.326 0.0000E+00 clinoenstatite-HiP 72 18.354 0.0000E+00 beidellite-K 195 -1.520 0.0000E+00 clinoenstatite 73 17.166 0.0000E+00 beidellite-Mg 196 -1.790 0.0000E+00 protoenstatite 74 17.824 0.0000E+00 beidellite-Na 197 -1.342 0.0000E+00 epidote 75 24.670 0.0000E+00 calcium 198 84.026 0.0000E+00 clinozoisite 76 22.806 0.0000E+00 chalcedony 199 -2.802 0.0000E+00 epidote-Fe 77 29.841 0.0000E+00 dawsonite 200 1.682 0.0000E+00 fayalite 78 14.046 0.0000E+00 montmorillonite-Ca 201 -2.291 0.0000E+00 ferrosilite 79 11.149 0.0000E+00 montmorillonite-K 202 -2.237 0.0000E+00 forsterite 80 21.016 0.0000E+00 montmorillonite-Mg 203 -2.480 0.0000E+00 gedrite 81 50.522 0.0000E+00 montmorillonite-Na 204 -2.038 0.0000E+00 gehlenite 82 36.628 0.0000E+00 nontronite-Ca 205 3.215 0.0000E+00 gibbsite 83 4.079 0.0000E+00 nontronite-H 206 2.533 0.0000E+00 glaucophane 84 22.975 0.0000E+00 nontronite-K 207 3.341 0.0000E+00 glaucophane-Fe 85 17.276 0.0000E+00 nontronite-Mg 208 3.075 0.0000E+00 graphite 86 -3.546 0.0000E+00 nontronite-Na 209 3.520 0.0000E+00 greenalite 87 16.140 0.0000E+00 sepiolite 210 24.118 0.0000E+00 grunerite 88 31.215 0.0000E+00 alite 211 57.999 0.0000E+00 halite 89 1.575 0.0000E+00 belite 212 30.433 0.0000E+00 hematite 90 12.566 0.0000E+00 ettringite 213 43.232 0.0000E+00 heulandite 91 -5.827 0.0000E+00 gypsum 214 -4.955 0.0000E+00 hercynite 92 17.279 0.0000E+00 hemicarboaluminate 215 70.954 0.0000E+00 hollandite 93 25.673 0.0000E+00 hydrogarnet 216 60.662 0.0000E+00 iron 94 19.086 0.0000E+00 hydrogarnet-Si 217 50.586 0.0000E+00 jadeite 95 4.215 0.0000E+00 jennite 218 24.367 0.0000E+00 julgoldite 96 70.427 0.0000E+00 monosulfoaluminate 219 53.400 0.0000E+00 kalsilite 97 7.584 0.0000E+00 monocarboaluminate 220 61.898 0.0000E+00 kaolinite 98 -1.333 0.0000E+00 portlandite 221 18.272 0.0000E+00 kyanite 99 4.876 0.0000E+00 stratlingite 222 36.502 0.0000E+00 larnite-bredigite 100 30.686 0.0000E+00 tricarboaluminate 223 70.370 0.0000E+00 laumontite 101 2.883 0.0000E+00 tobermorite 224 9.823 0.0000E+00 lawsonite 102 9.616 0.0000E+00 C4AH13 225 81.816 0.0000E+00 leucite 103 4.119 0.0000E+00 C2AH8 226 45.203 0.0000E+00 lime 104 25.998 0.0000E+00 C3A 227 86.953 0.0000E+00 lizardite 105 23.244 0.0000E+00 C4AF 228 117.416 0.0000E+00 magnesite 106 0.691 0.0000E+00 CAH10 229 28.335 0.0000E+00 magnetite 107 20.087 0.0000E+00 alabandite 230 -0.978 0.0000E+00 minnesotaite 108 10.388 0.0000E+00 alunite 231 -10.435 0.0000E+00 minnesotaite-Mg 109 20.602 0.0000E+00 artinite 232 15.121 0.0000E+00 magnesioferrite 110 26.212 0.0000E+00 boehmite 233 4.406 0.0000E+00 majorite 111 53.251 0.0000E+00 dolomite,disordered 234 1.247 0.0000E+00 manganosite 112 14.058 0.0000E+00 ferrous-oxide 235 9.812 0.0000E+00 margarite 113 17.324 0.0000E+00 huntite 236 3.770 0.0000E+00 meionite 114 44.874 0.0000E+00 hydromagnesite 237 19.995 0.0000E+00 merwinite 115 55.930 0.0000E+00 nesquehonite 238 4.723 0.0000E+00 microcline 116 -2.486 0.3715E-01 potassium-oxide 239 69.038 0.0000E+00 monticellite 117 24.339 0.0000E+00 silica-amorphous 240 -2.091 0.0000E+00 mullite-Al 118 363.148 0.0000E+00 sodium-oxide 241 55.169 0.0000E+00 mullite-Si 119 7.264 0.0000E+00 an20ab80 242 2.018 0.0000E+00 muscovite 120 2.582 0.0000E+00 an25ab75 243 2.646 0.0000E+00 paragonite 121 4.239 0.0000E+00 an30ab70 244 3.279 0.0000E+00 nepheline 122 8.339 0.0000E+00 tr.625ac.25prg.125 245 45.165 0.2462E-02 osumilite(1) 123 21.717 0.0000E+00 246 0.000 0.0000E+00 Initial composition of reactant (wt%): SiO2 62.56 MgO 3.200 Al2O3 16.62 CaO 6.450 FeO 3.530 Na2O 3.890 Fe2O3 1.770 K2O 1.000 MnO 0.1230 P2O5 0.4200E-01 Sum of wt% of reactants: 99.1850 Reactant consumed: 199.9990000 g log = 2.3010 Original solution: 1000.0103000 g Original solution / Rock added: 5.00 (Water/Rock Ratio), log = 0.6990 The following minerals and/or gases with identical index are in solid solution: H2O,gas 6 CO2,gas 6 CH4,gas 6 H2,gas 6 H2S,gas 6 S2,gas 6 CO,gas 6 SO3,gas 6 SO2,gas 6 HCl,gas 6 almandine 16 pyrope 16 spessartine 16 andradite 8 grossular 8 annite 15 phlogopite 15 biotite-Mn 15 clinochlore 1 daphnite 1 chlorite-Mn 1 diopside 5 hedenbergite 5 epidote 3 clinozoisite 3 greenalite 18 iron 9 lizardite 18 magnetite 14 talc 7 talc-Fe 7 tremolite 2 ferroactinolite 2 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 13 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 199.9990000 Water: Moles liquid = 0.5431E+02 kg liquid = 0.9784E+00 Moles total = 0.5300E+02 kg total = 0.9548E+00 Activity = 1.0000 Stoichiometric ionic strength = .1131840E-01 Osmotic coef. = 0.9695 True ionic strength = .2000752E-01 Chg. balance for total moles = 0.3650E-11 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.88245E-10 -10.0543 0.74151E-10 -10.1299 0.84028E+00 -0.0756 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.14038E-03 -3.8527 0.11725E-03 -3.9309 0.83523E+00 -0.0782 4 SO4-- 0.65918E-12 -12.1810 0.34236E-12 -12.4655 0.51938E+00 -0.2845 5 HCO3- 0.24399E-06 -6.6126 0.20409E-06 -6.6902 0.83645E+00 -0.0776 6 HS- 0.26063E-04 -4.5840 0.21772E-04 -4.6621 0.83535E+00 -0.0781 7 Al+++ 0.96860E-29 -29.0139 0.22385E-29 -29.6500 0.23111E+00 -0.6362 8 H4SiO4 0.69564E-03 -3.1576 0.69564E-03 -3.1576 0.10000E+01 0.0000 9 Ca++ 0.13489E-06 -6.8700 0.69547E-07 -7.1577 0.51557E+00 -0.2877 10 Mg++ 0.21104E-10 -10.6756 0.10831E-10 -10.9653 0.51321E+00 -0.2897 11 Fe++ 0.58146E-13 -13.2355 0.29874E-13 -13.5247 0.51377E+00 -0.2892 12 K+ 0.15643E-03 -3.8057 0.13088E-03 -3.8831 0.83665E+00 -0.0775 13 Na+ 0.19850E-01 -1.7022 0.16576E-01 -1.7805 0.83508E+00 -0.0783 14 Mn++ 0.17889E-10 -10.7474 0.91984E-11 -11.0363 0.51420E+00 -0.2889 15 HPO4-- 0.45322E-07 -7.3437 0.23543E-07 -7.6281 0.51945E+00 -0.2845 16 HSiO3- 0.10488E-01 -1.9793 0.87598E-02 -2.0575 0.83523E+00 -0.0782 17 Ca(HSiO3)+ 0.16579E-07 -7.7804 0.13874E-07 -7.8578 0.83683E+00 -0.0774 18 Mg(HSiO3)+ 0.32133E-11 -11.4930 0.26890E-11 -11.5704 0.83683E+00 -0.0774 19 NaHSiO3,aq 0.23485E-02 -2.6292 0.23485E-02 -2.6292 0.10000E+01 0.0000 20 AlO+ 0.66186E-16 -16.1792 0.55386E-16 -16.2566 0.83683E+00 -0.0774 22 HAlO2,aq 0.14875E-09 -9.8275 0.14875E-09 -9.8275 0.10000E+01 0.0000 23 AlO2- 0.53262E-05 -5.2736 0.44406E-05 -5.3526 0.83372E+00 -0.0790 24 CH4,aq 0.12651E-04 -4.8979 0.12607E-04 -4.8994 0.99655E+00 -0.0015 25 C2H6,aq 0.23513E-14 -14.6287 0.23432E-14 -14.6302 0.99655E+00 -0.0015 29 CO,aq 0.94195E-17 -17.0260 0.94195E-17 -17.0260 0.10000E+01 0.0000 30 CO2,aq 0.32448E-10 -10.4888 0.32336E-10 -10.4903 0.99655E+00 -0.0015 31 CO3-2 0.46386E-06 -6.3336 0.24041E-06 -6.6191 0.51828E+00 -0.2854 32 CaCO3,aq 0.20964E-09 -9.6785 0.20964E-09 -9.6785 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.43296E-12 -12.3636 0.36231E-12 -12.4409 0.83683E+00 -0.0774 34 CaCl+ 0.15769E-10 -10.8022 0.13196E-10 -10.8796 0.83683E+00 -0.0774 35 CaCl2,aq 0.36759E-15 -15.4346 0.36759E-15 -15.4346 0.10000E+01 0.0000 36 CaOH+ 0.79879E-07 -7.0976 0.66845E-07 -7.1749 0.83683E+00 -0.0774 37 CaSO4,aq 0.75609E-17 -17.1214 0.75609E-17 -17.1214 0.10000E+01 0.0000 38 HCl,aq 0.15931E-14 -14.7977 0.15931E-14 -14.7977 0.10000E+01 0.0000 43 FeCl+ 0.66252E-17 -17.1788 0.55441E-17 -17.2562 0.83683E+00 -0.0774 46 FeO,aq 0.21117E-09 -9.6754 0.21117E-09 -9.6754 0.10000E+01 0.0000 47 FeOH+ 0.15671E-10 -10.8049 0.13114E-10 -10.8823 0.83683E+00 -0.0774 48 HFeO2- 0.35675E-07 -7.4476 0.29797E-07 -7.5258 0.83523E+00 -0.0782 49 FeO+ 0.10977E-16 -16.9595 0.91858E-17 -17.0369 0.83683E+00 -0.0774 51 FeO2- 0.40929E-09 -9.3880 0.34185E-09 -9.4662 0.83523E+00 -0.0782 52 HFeO2,aq 0.32239E-11 -11.4916 0.32239E-11 -11.4916 0.10000E+01 0.0000 53 H2,aq 0.11636E-04 -4.9342 0.11596E-04 -4.9357 0.99655E+00 -0.0015 54 KCl,aq 0.27812E-09 -9.5558 0.27812E-09 -9.5558 0.10000E+01 0.0000 56 KOH,aq 0.75376E-06 -6.1228 0.75376E-06 -6.1228 0.10000E+01 0.0000 57 KSO4- 0.83247E-15 -15.0796 0.69530E-15 -15.1578 0.83523E+00 -0.0782 58 MgCO3,aq 0.81837E-14 -14.0871 0.81837E-14 -14.0871 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.68897E-16 -16.1618 0.57655E-16 -16.2392 0.83683E+00 -0.0774 60 MgCl+ 0.22258E-14 -14.6525 0.18626E-14 -14.7299 0.83683E+00 -0.0774 61 MgOH+ 0.68836E-10 -10.1622 0.57604E-10 -10.2395 0.83683E+00 -0.0774 63 MnO,aq 0.17325E-08 -8.7613 0.17325E-08 -8.7613 0.10000E+01 0.0000 64 MnOH+ 0.44826E-09 -9.3485 0.37511E-09 -9.4258 0.83683E+00 -0.0774 65 MnO2-2 0.20177E-10 -10.6951 0.10457E-10 -10.9806 0.51828E+00 -0.2854 66 HMnO2- 0.20339E-09 -9.6917 0.16988E-09 -9.7699 0.83523E+00 -0.0782 69 MnCl+ 0.79363E-14 -14.1004 0.66413E-14 -14.1777 0.83683E+00 -0.0774 71 NaCl,aq 0.64410E-06 -6.1910 0.64410E-06 -6.1910 0.10000E+01 0.0000 72 NaOH,aq 0.96048E-04 -4.0175 0.96048E-04 -4.0175 0.10000E+01 0.0000 74 OH- 0.93459E-02 -2.0294 0.77919E-02 -2.1084 0.83372E+00 -0.0790 79 HPO3-2 0.16415E-14 -14.7848 0.85077E-15 -15.0702 0.51828E+00 -0.2854 81 H2PO3- 0.15146E-18 -18.8197 0.12650E-18 -18.8979 0.83523E+00 -0.0782 82 H3PO4,aq 0.90534E-18 -18.0432 0.90534E-18 -18.0432 0.10000E+01 0.0000 83 H2PO4- 0.38520E-10 -10.4143 0.32204E-10 -10.4921 0.83602E+00 -0.0778 84 PO4-3 0.10672E-08 -8.9717 0.25905E-09 -9.5866 0.24272E+00 -0.6149 88 HP2O7-3 0.94657E-18 -18.0238 0.21898E-18 -18.6596 0.23134E+00 -0.6358 89 P2O7-4 0.91443E-17 -17.0388 0.70550E-18 -18.1515 0.77151E-01 -1.1127 90 H2S,aq 0.50068E-08 -8.3004 0.49895E-08 -8.3019 0.99655E+00 -0.0015 91 S2-2 0.17476E-14 -14.7576 0.90576E-15 -15.0430 0.51828E+00 -0.2854 97 SO3-2 0.98123E-18 -18.0082 0.51590E-18 -18.2874 0.52577E+00 -0.2792 99 HSO4- 0.29207E-19 -19.5345 0.24465E-19 -19.6114 0.83764E+00 -0.0769 Charge balance for all species = 0.3730E-11 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.8824529E-10 -.2230399E-01 -.2244203E+02 0.0000 2 H2O 0.1000000E+01 0.5550489E+02 0.9982004E+06 0.0000 3 Cl- 0.1403785E-03 0.1410229E-03 0.4990999E+01 6.1990 4 SO4-- 0.6591780E-12 -.1555967E-04 -.1492091E+01 7.7943 5 HCO3- 0.2439937E-06 0.1335879E-04 0.8137004E+00 3.4397 6 HS- 0.2606301E-04 0.4162769E-04 0.1374320E+01 5.4678 7 Al+++ 0.9685954E-29 0.5326396E-05 0.1434645E+00 0.7396 8 H4SiO4 0.6956371E-03 0.1353205E-01 0.1298379E+04 -3.1576 9 Ca++ 0.1348934E-06 0.2315773E-06 0.9265034E-02 13.1020 10 Mg++ 0.2110410E-10 0.9316391E-10 0.2261067E-05 9.2944 11 Fe++ 0.5814607E-13 0.3631468E-07 0.2024543E-02 6.7351 12 K+ 0.1564294E-03 0.1571834E-03 0.6135509E+01 6.2467 13 Na+ 0.1985008E-01 0.2229527E-01 0.5116734E+03 8.3494 14 Mn++ 0.1788876E-10 0.2422226E-08 0.1328411E-03 9.2235 15 HPO4-- 0.4532242E-07 0.4642819E-07 0.4448391E-02 12.6316 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.3311673E+01 -.2182181E-01 -.3289852E+01 0.0000000E+00 2 H2O 0.5300118E+02 0.5430497E+02 -.1303790E+01 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.5568159E-02 -.1522330E-04 0.5583382E-02 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.5542654E-02 0.4072777E-04 -.5583382E-02 0.0000000E+00 7 Al+++ 0.6521451E+00 0.5211249E-05 0.6521399E+00 0.0000000E+00 8 H4SiO4 0.2082546E+01 0.1323951E-01 0.2069307E+01 0.0000000E+00 9 Ca++ 0.2300419E+00 0.2265710E-06 0.2300416E+00 0.0000000E+00 10 Mg++ 0.1587294E+00 0.9114987E-10 0.1587294E+00 0.0000000E+00 11 Fe++ 0.1426010E+00 0.3552962E-07 0.1426010E+00 0.0000000E+00 12 K+ 0.4246263E-01 0.1537854E-03 0.4230885E-01 0.0000000E+00 13 Na+ 0.2512075E+00 0.2181328E-01 0.2293943E+00 0.0000000E+00 14 Mn++ 0.3467702E-02 0.2369861E-08 0.3467699E-02 0.0000000E+00 15 HPO4-- 0.1183509E-02 0.4542450E-07 0.1183464E-02 0.0000000E+00 Chg. balance for solid moles: 0.2515E-15 Mass of aqueous solution: 0.980084E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 199.9990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 0.2291 -0.640 60.07 1.779 27.52 23.06 andradite 0.2233E-01 -1.651 11.35 1.055 5.199 2.949 grossular 0.5418E-02 -2.266 2.440 0.387 1.118 0.6790 apatite-OH 0.3945E-03 -3.404 0.1982 -0.703 0.9077E-01 0.6297E-01 clinochlore 0.2964E-01 -1.528 16.47 1.217 7.546 6.266 daphnite 0.8577E-02 -2.067 6.120 0.787 2.803 1.854 chlorite-Mn 0.6935E-03 -3.159 0.4917 -0.308 0.2252 0.1567 diopside 0.1619E-02 -2.791 0.3506 -0.455 0.1606 0.1071 hedenbergite 0.4197E-03 -3.377 0.1041 -0.982 0.4769E-01 0.2852E-01 microcline 0.3715E-01 -1.430 10.34 1.015 4.737 4.040 stilbite 0.1379 -0.861 97.15 1.987 44.50 45.31 stilpnomelane-Fe 0.1031E-01 -1.987 11.11 1.046 5.091 3.839 tr.625ac.25prg.125 0.2462E-02 -2.609 2.105 0.323 0.9640 0.6773 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8048E+00 0.8048E+00 1.0000 -0.094 grossular 0.1952E+00 0.1952E+00 1.0000 -0.709 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.7617E+00 0.7617E+00 1.0000 -0.118 daphnite 0.2204E+00 0.2204E+00 1.0000 -0.657 chlorite-Mn 0.1783E-01 0.1783E-01 1.0000 -1.749 diopside 0.7941E+00 0.7941E+00 1.0000 -0.100 hedenbergite 0.2059E+00 0.2059E+00 1.0000 -0.686 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 tr.625ac.25prg.125 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 218.306193 g Volume = 89.030788 cm3 Porosity: -9.9151% V(tot) - V(min): -.80312E+01 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 199.9990000 g log = 2.3010 Original solution: 1000.0103000 g Original solution / Rock added: 5.00 (Water/Rock Ratio), log = 0.6990 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0543 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9682E+00 0.9855 0.1006E+01 0.1021E+01 CO2,gas 0.3259E-08 1.0069 0.3460E-08 0.3436E-08 CH4,gas 0.1738E-01 1.0125 0.1856E-01 0.1833E-01 H2,gas 0.1443E-01 1.0006 0.1522E-01 0.1522E-01 H2S,gas 0.1306E-06 0.9959 0.1372E-06 0.1377E-06 S2,gas 0.2890E-29 1.0000 0.3047E-29 0.3047E-29 CO,gas 0.1331E-13 1.0000 0.1404E-13 0.1404E-13 SO3,gas 0.6751E-48 1.0000 0.7118E-48 0.7118E-48 SO2,gas 0.3998E-27 1.0000 0.4216E-27 0.4216E-27 HCl,gas 0.2666E-17 1.0000 0.2811E-17 0.2811E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 16 albite -0.38 -0.38 0.00 0.000 -0.94784E-12 22 andradite 39.01 39.01 0.00 0.000 0.12132E-10 23 grossular 32.73 32.73 0.00 0.000 0.12132E-10 32 apatite-OH -18.15 -18.15 0.00 0.000 -0.60662E-11 46 clinochlore 39.07 39.07 0.00 0.000 0.24265E-10 47 daphnite 28.97 28.97 0.00 0.000 0.12132E-10 48 chlorite-Mn 46.87 46.87 0.00 0.000 -0.24265E-10 67 diopside 16.18 16.18 0.00 0.000 0.60662E-11 68 hedenbergite 14.21 14.21 0.00 0.000 0.30331E-11 116 microcline -2.49 -2.49 0.00 0.000 0.15165E-11 163 stilbite -7.52 -7.52 0.00 0.000 -0.90992E-11 164 stilpnomelane-Fe 13.02 13.02 0.00 0.000 -0.27298E-10 245 tr.625ac.25prg.125 45.16 45.16 0.00 0.000 -0.36397E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -16.82 -10.16 -3.387 0.17348E+05 -8.461 3 CH4,gas 4.54 1.11 -3.43 -0.858 0.58574E+04 -1.731 4 H2,gas 8.00 4.48 -3.52 -2.009 0.60042E+04 -1.817 5 H2S,gas -6.23 -14.79 -8.56 -4.281 0.14619E+05 -6.863 6 S2,gas -7.34 -38.55 -31.22 -4.802 0.53299E+05 -29.516 7 CO,gas 3.21 -12.34 -15.55 -4.785 0.26554E+05 -13.853 8 SO3,gas 17.12 -32.73 -49.85 -12.462 0.85112E+05 -48.148 9 SO2,gas 0.83 -28.24 -29.07 -7.753 0.49643E+05 -27.375 10 HCl,gas 5.19 -14.06 -19.25 -9.625 0.32869E+05 -17.551 11 acmite 7.71 6.53 -1.18 -0.123 0.20185E+04 15 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 19 spessartine 24.46 19.68 -4.78 -0.239 0.81626E+04 20 analcite 3.32 2.77 -0.55 -0.061 0.93588E+03 26 annite 20.12 17.72 -2.40 -0.134 0.41060E+04 27 phlogopite 27.06 25.40 -1.67 -0.093 0.28477E+04 29 anorthite 12.71 8.27 -4.44 -0.342 0.75885E+04 35 aragonite 0.97 -3.72 -4.68 -1.562 0.79987E+04 36 brucite 12.57 9.29 -3.27 -0.655 0.55905E+04 37 calcite 0.81 -3.72 -4.53 -1.510 0.77345E+04 38 carnegieite-low 9.02 5.93 -3.09 -0.442 0.52794E+04 39 carnegieite-high 10.09 5.93 -4.16 -0.595 0.71064E+04 40 carpholite-Mg 8.58 4.46 -4.12 -0.275 0.70411E+04 41 carpholite-Fe 6.71 1.90 -4.81 -0.321 0.82191E+04 42 celadonite 5.34 3.65 -1.69 -0.099 0.28878E+04 43 celadonite-Fe 3.88 1.09 -2.79 -0.164 0.47563E+04 44 chrysotile 23.89 21.57 -2.32 -0.194 0.39687E+04 49 chlorite-Al-free 47.17 43.14 -4.04 -0.168 0.68926E+04 51 chloritoid-Fe 9.17 5.06 -4.12 -0.274 0.70296E+04 52 chloritoid-Mn 11.40 7.55 -3.86 -0.257 0.65840E+04 54 coesite -2.38 -3.16 -0.78 -0.261 0.13345E+04 61 cristobalite -2.56 -3.16 -0.60 -0.199 0.10198E+04 63 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71234E+04 65 diaspore 2.87 0.74 -2.13 -0.356 0.36439E+04 66 diamond -3.10 -7.85 -4.75 -1.357 0.81123E+04 71 enstatite 17.26 12.27 -4.99 -0.499 0.85225E+04 73 clinoenstatite 17.17 12.27 -4.89 -0.489 0.83541E+04 75 epidote 24.67 22.70 -1.97 -0.095 0.33570E+04 76 clinozoisite 22.81 18.95 -3.86 -0.175 0.65839E+04 77 epidote-Fe 29.84 26.46 -3.38 -0.176 0.57766E+04 78 fayalite 14.05 10.31 -3.73 -0.533 0.63744E+04 79 ferrosilite 11.15 7.15 -3.99 -0.399 0.68206E+04 83 gibbsite 4.08 0.74 -3.34 -0.477 0.57024E+04 84 glaucophane 22.97 20.80 -2.17 -0.059 0.37128E+04 85 glaucophane-Fe 17.28 13.12 -4.15 -0.112 0.70922E+04 86 graphite -3.55 -7.85 -4.31 -1.231 0.73545E+04 87 greenalite 16.14 13.89 -2.25 -0.187 0.38410E+04 90 hematite 12.57 8.99 -3.58 -0.434 0.61117E+04 91 heulandite -5.83 -7.52 -1.69 -0.077 0.28938E+04 95 jadeite 4.22 2.77 -1.44 -0.144 0.24614E+04 97 kalsilite 7.58 3.83 -3.76 -0.536 0.64118E+04 98 kaolinite -1.33 -4.84 -3.50 -0.318 0.59817E+04 101 laumontite 2.88 1.95 -0.93 -0.062 0.15924E+04 102 lawsonite 9.62 8.27 -1.35 -0.090 0.23052E+04 103 leucite 4.12 0.67 -3.45 -0.345 0.58869E+04 105 lizardite 23.24 21.57 -1.68 -0.140 0.28613E+04 107 magnetite 20.09 15.72 -4.37 -0.356 0.74540E+04 108 minnesotaite 10.39 7.57 -2.81 -0.165 0.48038E+04 112 manganosite 14.06 9.22 -4.83 -1.209 0.82550E+04 120 muscovite 2.58 -1.01 -3.59 -0.211 0.61293E+04 121 paragonite 4.24 1.10 -3.14 -0.185 0.53684E+04 122 nepheline 8.34 5.93 -2.41 -0.344 0.41117E+04 128 periclase-Fe 11.63 6.74 -4.89 -1.223 0.83521E+04 134 phlogopite-Na 29.65 27.50 -2.15 -0.119 0.36665E+04 136 prehnite 19.37 18.21 -1.16 -0.068 0.19831E+04 137 prehnite-Fe 22.50 21.96 -0.53 -0.032 0.91112E+03 138 pumpellyite-Fe 46.27 43.90 -2.37 -0.053 0.40532E+04 139 pumpellyite-Mg 48.99 46.45 -2.54 -0.056 0.43368E+04 143 pyrrhotite -4.26 -8.06 -3.80 -1.266 0.64826E+04 144 pyrrhotiteFe0.875 -6.02 -9.45 -3.44 -1.264 0.58699E+04 145 pyroxmangite 7.40 6.07 -1.33 -0.267 0.22757E+04 146 pyrophyllite -6.18 -11.15 -4.98 -0.311 0.84954E+04 147 quartz -2.99 -3.16 -0.17 -0.056 0.28717E+03 152 rhodonite 7.45 6.07 -1.38 -0.276 0.23560E+04 153 sanidine -1.28 -2.49 -1.21 -0.093 0.20677E+04 165 stilpnomelane-Mg 27.44 25.81 -1.63 -0.049 0.27790E+04 171 talc 16.49 15.25 -1.24 -0.073 0.21143E+04 174 tephroite 18.09 15.29 -2.80 -0.399 0.47749E+04 178 tridymite -2.63 -3.16 -0.53 -0.177 0.90714E+03 179 tremolite 47.87 47.42 -0.45 -0.012 0.77507E+03 180 ferroactinolite 38.45 34.62 -3.83 -0.104 0.65463E+04 181 troilite-low -4.41 -8.06 -3.65 -1.215 0.62254E+04 183 vesuvianite 223.47 218.83 -4.64 -0.035 0.79305E+04 187 wairakite 3.95 1.95 -2.00 -0.118 0.34144E+04 188 walstromite 11.51 9.94 -1.56 -0.313 0.26718E+04 189 wollastonite 10.46 9.94 -0.52 -0.103 0.88228E+03 190 pseudo-wollastonite 11.00 9.94 -1.06 -0.211 0.18021E+04 191 zoisite 22.85 18.95 -3.90 -0.177 0.66580E+04 192 akaganeite 7.75 4.49 -3.26 -0.705 0.55684E+04 199 chalcedony -2.80 -3.16 -0.36 -0.118 0.60646E+03 201 montmorillonite-Ca -2.29 -6.17 -3.88 -0.240 0.66175E+04 202 montmorillonite-K -2.24 -6.27 -4.03 -0.247 0.68811E+04 203 montmorillonite-Mg -2.48 -6.79 -4.31 -0.267 0.73672E+04 204 montmorillonite-Na -2.04 -5.57 -3.54 -0.216 0.60360E+04 205 nontronite-Ca 3.21 -0.20 -3.41 -0.221 0.58230E+04 206 nontronite-H 2.53 -2.36 -4.89 -0.328 0.83500E+04 207 nontronite-K 3.34 -0.30 -3.64 -0.233 0.62098E+04 208 nontronite-Mg 3.07 -0.82 -3.90 -0.253 0.66568E+04 209 nontronite-Na 3.52 0.40 -3.12 -0.200 0.53307E+04 224 tobermorite 9.82 7.76 -2.07 -0.564 0.35288E+04 230 alabandite -0.98 -5.57 -4.59 -1.530 0.78384E+04 233 boehmite 4.41 0.74 -3.67 -0.611 0.62608E+04 235 ferrous-oxide 9.81 6.74 -3.08 -0.769 0.52531E+04 240 silica-amorphous -2.09 -3.16 -1.07 -0.355 0.18206E+04 242 an20ab80 2.02 1.35 -0.67 -0.052 0.11468E+04 243 an25ab75 2.65 1.78 -0.87 -0.067 0.14805E+04 244 an30ab70 3.28 2.21 -1.07 -0.082 0.18238E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 10.0000000 g Current total amount of reactant added: 199.9990000 g New total amount of reactant added: 209.9990000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.3650E-11 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 11 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 209.9990000 Water: Moles liquid = 0.5425E+02 kg liquid = 0.9774E+00 Moles total = 0.5288E+02 kg total = 0.9526E+00 Activity = 1.0000 Stoichiometric ionic strength = .1131861E-01 Osmotic coef. = 0.9695 True ionic strength = .2000774E-01 Chg. balance for total moles = 0.3650E-11 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.88246E-10 -10.0543 0.74151E-10 -10.1299 0.84028E+00 -0.0756 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.14052E-03 -3.8523 0.11737E-03 -3.9304 0.83523E+00 -0.0782 4 SO4-- 0.66000E-12 -12.1805 0.34279E-12 -12.4650 0.51938E+00 -0.2845 5 HCO3- 0.24429E-06 -6.6121 0.20434E-06 -6.6896 0.83645E+00 -0.0776 6 HS- 0.26090E-04 -4.5835 0.21794E-04 -4.6617 0.83535E+00 -0.0781 7 Al+++ 0.96856E-29 -29.0139 0.22384E-29 -29.6501 0.23110E+00 -0.6362 8 H4SiO4 0.69565E-03 -3.1576 0.69565E-03 -3.1576 0.10000E+01 0.0000 9 Ca++ 0.13489E-06 -6.8700 0.69547E-07 -7.1577 0.51557E+00 -0.2877 10 Mg++ 0.21104E-10 -10.6756 0.10831E-10 -10.9653 0.51321E+00 -0.2897 11 Fe++ 0.58147E-13 -13.2355 0.29874E-13 -13.5247 0.51377E+00 -0.2892 12 K+ 0.15643E-03 -3.8057 0.13088E-03 -3.8831 0.83665E+00 -0.0775 13 Na+ 0.19850E-01 -1.7022 0.16577E-01 -1.7805 0.83508E+00 -0.0783 14 Mn++ 0.17925E-10 -10.7465 0.92172E-11 -11.0354 0.51420E+00 -0.2889 15 HPO4-- 0.45323E-07 -7.3437 0.23543E-07 -7.6281 0.51945E+00 -0.2845 16 HSiO3- 0.10488E-01 -1.9793 0.87599E-02 -2.0575 0.83523E+00 -0.0782 17 Ca(HSiO3)+ 0.16580E-07 -7.7804 0.13874E-07 -7.8578 0.83683E+00 -0.0774 18 Mg(HSiO3)+ 0.32134E-11 -11.4930 0.26890E-11 -11.5704 0.83683E+00 -0.0774 19 NaHSiO3,aq 0.23486E-02 -2.6292 0.23486E-02 -2.6292 0.10000E+01 0.0000 20 AlO+ 0.66182E-16 -16.1793 0.55383E-16 -16.2566 0.83683E+00 -0.0774 22 HAlO2,aq 0.14874E-09 -9.8276 0.14874E-09 -9.8276 0.10000E+01 0.0000 23 AlO2- 0.53258E-05 -5.2736 0.44402E-05 -5.3526 0.83372E+00 -0.0790 24 CH4,aq 0.12664E-04 -4.8974 0.12620E-04 -4.8989 0.99655E+00 -0.0015 25 C2H6,aq 0.23562E-14 -14.6278 0.23481E-14 -14.6293 0.99655E+00 -0.0015 29 CO,aq 0.94307E-17 -17.0255 0.94307E-17 -17.0255 0.10000E+01 0.0000 30 CO2,aq 0.32488E-10 -10.4883 0.32376E-10 -10.4898 0.99655E+00 -0.0015 31 CO3-2 0.46442E-06 -6.3331 0.24070E-06 -6.6185 0.51828E+00 -0.2854 32 CaCO3,aq 0.20990E-09 -9.6780 0.20990E-09 -9.6780 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.43349E-12 -12.3630 0.36275E-12 -12.4404 0.83683E+00 -0.0774 34 CaCl+ 0.15785E-10 -10.8017 0.13210E-10 -10.8791 0.83683E+00 -0.0774 35 CaCl2,aq 0.36834E-15 -15.4337 0.36834E-15 -15.4337 0.10000E+01 0.0000 36 CaOH+ 0.79878E-07 -7.0976 0.66844E-07 -7.1749 0.83683E+00 -0.0774 37 CaSO4,aq 0.75702E-17 -17.1209 0.75702E-17 -17.1209 0.10000E+01 0.0000 38 HCl,aq 0.15948E-14 -14.7973 0.15948E-14 -14.7973 0.10000E+01 0.0000 43 FeCl+ 0.66321E-17 -17.1784 0.55499E-17 -17.2557 0.83683E+00 -0.0774 46 FeO,aq 0.21117E-09 -9.6754 0.21117E-09 -9.6754 0.10000E+01 0.0000 47 FeOH+ 0.15671E-10 -10.8049 0.13114E-10 -10.8823 0.83683E+00 -0.0774 48 HFeO2- 0.35675E-07 -7.4476 0.29796E-07 -7.5258 0.83523E+00 -0.0782 49 FeO+ 0.10977E-16 -16.9595 0.91860E-17 -17.0369 0.83683E+00 -0.0774 51 FeO2- 0.40929E-09 -9.3880 0.34185E-09 -9.4662 0.83523E+00 -0.0782 52 HFeO2,aq 0.32240E-11 -11.4916 0.32240E-11 -11.4916 0.10000E+01 0.0000 53 H2,aq 0.11635E-04 -4.9342 0.11595E-04 -4.9357 0.99655E+00 -0.0015 54 KCl,aq 0.27840E-09 -9.5553 0.27840E-09 -9.5553 0.10000E+01 0.0000 56 KOH,aq 0.75376E-06 -6.1228 0.75376E-06 -6.1228 0.10000E+01 0.0000 57 KSO4- 0.83351E-15 -15.0791 0.69617E-15 -15.1573 0.83523E+00 -0.0782 58 MgCO3,aq 0.81936E-14 -14.0865 0.81936E-14 -14.0865 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.68981E-16 -16.1613 0.57726E-16 -16.2386 0.83683E+00 -0.0774 60 MgCl+ 0.22281E-14 -14.6521 0.18645E-14 -14.7294 0.83683E+00 -0.0774 61 MgOH+ 0.68835E-10 -10.1622 0.57603E-10 -10.2396 0.83683E+00 -0.0774 63 MnO,aq 0.17360E-08 -8.7604 0.17360E-08 -8.7604 0.10000E+01 0.0000 64 MnOH+ 0.44917E-09 -9.3476 0.37588E-09 -9.4250 0.83683E+00 -0.0774 65 MnO2-2 0.20217E-10 -10.6943 0.10478E-10 -10.9797 0.51828E+00 -0.2854 66 HMnO2- 0.20380E-09 -9.6908 0.17022E-09 -9.7690 0.83523E+00 -0.0782 69 MnCl+ 0.79607E-14 -14.0990 0.66617E-14 -14.1764 0.83683E+00 -0.0774 71 NaCl,aq 0.64476E-06 -6.1906 0.64476E-06 -6.1906 0.10000E+01 0.0000 72 NaOH,aq 0.96048E-04 -4.0175 0.96048E-04 -4.0175 0.10000E+01 0.0000 74 OH- 0.93458E-02 -2.0294 0.77918E-02 -2.1084 0.83372E+00 -0.0790 79 HPO3-2 0.16415E-14 -14.7848 0.85074E-15 -15.0702 0.51828E+00 -0.2854 81 H2PO3- 0.15146E-18 -18.8197 0.12650E-18 -18.8979 0.83523E+00 -0.0782 82 H3PO4,aq 0.90538E-18 -18.0432 0.90538E-18 -18.0432 0.10000E+01 0.0000 83 H2PO4- 0.38522E-10 -10.4143 0.32205E-10 -10.4921 0.83602E+00 -0.0778 84 PO4-3 0.10673E-08 -8.9717 0.25905E-09 -9.5866 0.24272E+00 -0.6149 88 HP2O7-3 0.94663E-18 -18.0238 0.21899E-18 -18.6596 0.23134E+00 -0.6358 89 P2O7-4 0.91448E-17 -17.0388 0.70552E-18 -18.1515 0.77150E-01 -1.1127 90 H2S,aq 0.50119E-08 -8.3000 0.49946E-08 -8.3015 0.99655E+00 -0.0015 91 S2-2 0.17513E-14 -14.7566 0.90767E-15 -15.0421 0.51828E+00 -0.2854 97 SO3-2 0.98239E-18 -18.0077 0.51651E-18 -18.2869 0.52577E+00 -0.2792 99 HSO4- 0.29244E-19 -19.5340 0.24496E-19 -19.6109 0.83764E+00 -0.0769 Charge balance for all species = 0.3732E-11 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.8824629E-10 -.2230409E-01 -.2244214E+02 0.0000 2 H2O 0.1000000E+01 0.5550489E+02 0.9982004E+06 0.0000 3 Cl- 0.1405227E-03 0.1411678E-03 0.4996127E+01 6.1994 4 SO4-- 0.6599951E-12 -.1557237E-04 -.1493309E+01 7.7948 5 HCO3- 0.2442931E-06 0.1337252E-04 0.8145365E+00 3.4402 6 HS- 0.2608979E-04 0.4166718E-04 0.1375623E+01 5.4682 7 Al+++ 0.9685649E-29 0.5325970E-05 0.1434531E+00 0.7396 8 H4SiO4 0.6956534E-03 0.1353227E-01 0.1298400E+04 -3.1576 9 Ca++ 0.1348934E-06 0.2315768E-06 0.9265012E-02 13.1020 10 Mg++ 0.2110405E-10 0.9316289E-10 0.2261042E-05 9.2944 11 Fe++ 0.5814693E-13 0.3631399E-07 0.2024505E-02 6.7351 12 K+ 0.1564311E-03 0.1571851E-03 0.6135577E+01 6.2467 13 Na+ 0.1985030E-01 0.2229554E-01 0.5116797E+03 8.3494 14 Mn++ 0.1792546E-10 0.2427139E-08 0.1331106E-03 9.2244 15 HPO4-- 0.4532341E-07 0.4642919E-07 0.4448487E-02 12.6316 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.3477259E+01 -.2179952E-01 -.3455459E+01 0.0000000E+00 2 H2O 0.5287583E+02 0.5424923E+02 -.1373402E+01 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.5845293E-02 -.1522009E-04 0.5860513E-02 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.5819788E-02 0.4072456E-04 -.5860513E-02 0.0000000E+00 7 Al+++ 0.6847525E+00 0.5205483E-05 0.6847473E+00 0.0000000E+00 8 H4SiO4 0.2186674E+01 0.1322613E-01 0.2173448E+01 0.0000000E+00 9 Ca++ 0.2415433E+00 0.2263379E-06 0.2415431E+00 0.0000000E+00 10 Mg++ 0.1666659E+00 0.9105530E-10 0.1666659E+00 0.0000000E+00 11 Fe++ 0.1497311E+00 0.3549248E-07 0.1497311E+00 0.0000000E+00 12 K+ 0.4458577E-01 0.1536292E-03 0.4443215E-01 0.0000000E+00 13 Na+ 0.2637600E+00 0.2179116E-01 0.2419688E+00 0.0000000E+00 14 Mn++ 0.3641088E-02 0.2372231E-08 0.3641085E-02 0.0000000E+00 15 HPO4-- 0.1242685E-02 0.4537885E-07 0.1242640E-02 0.0000000E+00 Chg. balance for solid moles: 0.2485E-15 Mass of aqueous solution: 0.979078E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 209.9990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 0.2417 -0.617 63.37 1.802 27.64 24.32 andradite 0.2344E-01 -1.630 11.91 1.076 5.197 3.095 grossular 0.5686E-02 -2.245 2.561 0.408 1.117 0.7127 apatite-OH 0.4142E-03 -3.383 0.2081 -0.682 0.9077E-01 0.6612E-01 clinochlore 0.3106E-01 -1.508 17.26 1.237 7.530 6.566 daphnite 0.8987E-02 -2.046 6.412 0.807 2.797 1.943 chlorite-Mn 0.7282E-03 -3.138 0.5163 -0.287 0.2252 0.1645 diopside 0.2163E-02 -2.665 0.4683 -0.329 0.2043 0.1431 hedenbergite 0.5607E-03 -3.251 0.1391 -0.857 0.6068E-01 0.3810E-01 microcline 0.3902E-01 -1.409 10.86 1.036 4.737 4.242 stilbite 0.1443 -0.841 101.7 2.007 44.35 47.42 stilpnomelane-Fe 0.1083E-01 -1.965 11.68 1.067 5.095 4.034 tr.625ac.25prg.125 0.2545E-02 -2.594 2.176 0.338 0.9492 0.7003 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8048E+00 0.8048E+00 1.0000 -0.094 grossular 0.1952E+00 0.1952E+00 1.0000 -0.709 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.7617E+00 0.7617E+00 1.0000 -0.118 daphnite 0.2204E+00 0.2204E+00 1.0000 -0.657 chlorite-Mn 0.1786E-01 0.1786E-01 1.0000 -1.748 diopside 0.7941E+00 0.7941E+00 1.0000 -0.100 hedenbergite 0.2059E+00 0.2059E+00 1.0000 -0.686 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 tr.625ac.25prg.125 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 229.231247 g Volume = 93.451093 cm3 Porosity: -9.9430% V(tot) - V(min): -.84515E+01 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 209.9990000 g log = 2.3222 Original solution: 1000.0103000 g Original solution / Rock added: 4.76 (Water/Rock Ratio), log = 0.6778 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0543 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9682E+00 0.9855 0.1006E+01 0.1021E+01 CO2,gas 0.3263E-08 1.0069 0.3464E-08 0.3440E-08 CH4,gas 0.1740E-01 1.0125 0.1858E-01 0.1835E-01 H2,gas 0.1443E-01 1.0006 0.1522E-01 0.1521E-01 H2S,gas 0.1308E-06 0.9959 0.1373E-06 0.1379E-06 S2,gas 0.2896E-29 1.0000 0.3053E-29 0.3053E-29 CO,gas 0.1333E-13 1.0000 0.1405E-13 0.1405E-13 SO3,gas 0.6759E-48 1.0000 0.7126E-48 0.7126E-48 SO2,gas 0.4003E-27 1.0000 0.4221E-27 0.4221E-27 HCl,gas 0.2669E-17 1.0000 0.2814E-17 0.2814E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 16 albite -0.38 -0.38 0.00 0.000 -0.94784E-12 22 andradite 39.01 39.01 0.00 0.000 -0.12132E-10 23 grossular 32.73 32.73 0.00 0.000 0.12132E-10 32 apatite-OH -18.15 -18.15 0.00 0.000 0.60662E-11 46 clinochlore 39.07 39.07 0.00 0.000 0.00000E+00 47 daphnite 28.97 28.97 0.00 0.000 -0.30331E-10 48 chlorite-Mn 46.87 46.87 0.00 0.000 0.12132E-10 67 diopside 16.18 16.18 0.00 0.000 -0.12132E-10 68 hedenbergite 14.21 14.21 0.00 0.000 -0.90992E-11 116 microcline -2.49 -2.49 0.00 0.000 -0.10616E-10 163 stilbite -7.52 -7.52 0.00 0.000 0.15165E-10 164 stilpnomelane-Fe 13.02 13.02 0.00 0.000 0.21232E-10 245 tr.625ac.25prg.125 45.16 45.16 0.00 0.000 -0.12132E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -16.82 -10.16 -3.386 0.17347E+05 -8.460 3 CH4,gas 4.54 1.11 -3.43 -0.858 0.58567E+04 -1.731 4 H2,gas 8.00 4.48 -3.52 -2.009 0.60043E+04 -1.817 5 H2S,gas -6.23 -14.79 -8.56 -4.281 0.14618E+05 -6.862 6 S2,gas -7.34 -38.55 -31.21 -4.802 0.53297E+05 -29.515 7 CO,gas 3.21 -12.34 -15.55 -4.785 0.26553E+05 -13.852 8 SO3,gas 17.12 -32.72 -49.85 -12.462 0.85111E+05 -48.147 9 SO2,gas 0.83 -28.24 -29.07 -7.753 0.49642E+05 -27.375 10 HCl,gas 5.19 -14.06 -19.25 -9.625 0.32868E+05 -17.551 11 acmite 7.71 6.53 -1.18 -0.123 0.20185E+04 15 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 19 spessartine 24.46 19.68 -4.78 -0.239 0.81582E+04 20 analcite 3.32 2.77 -0.55 -0.061 0.93590E+03 26 annite 20.12 17.72 -2.40 -0.134 0.41060E+04 27 phlogopite 27.06 25.40 -1.67 -0.093 0.28478E+04 29 anorthite 12.71 8.27 -4.44 -0.342 0.75886E+04 35 aragonite 0.97 -3.72 -4.68 -1.561 0.79978E+04 36 brucite 12.57 9.29 -3.27 -0.655 0.55905E+04 37 calcite 0.81 -3.72 -4.53 -1.510 0.77336E+04 38 carnegieite-low 9.02 5.93 -3.09 -0.442 0.52794E+04 39 carnegieite-high 10.09 5.93 -4.16 -0.595 0.71064E+04 40 carpholite-Mg 8.58 4.46 -4.12 -0.275 0.70411E+04 41 carpholite-Fe 6.71 1.90 -4.81 -0.321 0.82191E+04 42 celadonite 5.34 3.65 -1.69 -0.099 0.28878E+04 43 celadonite-Fe 3.88 1.09 -2.79 -0.164 0.47563E+04 44 chrysotile 23.89 21.57 -2.32 -0.194 0.39687E+04 49 chlorite-Al-free 47.17 43.14 -4.04 -0.168 0.68927E+04 51 chloritoid-Fe 9.17 5.06 -4.12 -0.274 0.70297E+04 52 chloritoid-Mn 11.40 7.55 -3.86 -0.257 0.65826E+04 54 coesite -2.38 -3.16 -0.78 -0.261 0.13345E+04 61 cristobalite -2.56 -3.16 -0.60 -0.199 0.10198E+04 63 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71234E+04 65 diaspore 2.87 0.74 -2.13 -0.356 0.36439E+04 66 diamond -3.10 -7.85 -4.75 -1.357 0.81114E+04 71 enstatite 17.26 12.27 -4.99 -0.499 0.85225E+04 73 clinoenstatite 17.17 12.27 -4.89 -0.489 0.83541E+04 75 epidote 24.67 22.70 -1.97 -0.095 0.33570E+04 76 clinozoisite 22.81 18.95 -3.86 -0.175 0.65841E+04 77 epidote-Fe 29.84 26.46 -3.38 -0.176 0.57766E+04 78 fayalite 14.05 10.31 -3.73 -0.533 0.63744E+04 79 ferrosilite 11.15 7.15 -3.99 -0.399 0.68206E+04 83 gibbsite 4.08 0.74 -3.34 -0.477 0.57025E+04 84 glaucophane 22.97 20.80 -2.17 -0.059 0.37129E+04 85 glaucophane-Fe 17.28 13.12 -4.15 -0.112 0.70921E+04 86 graphite -3.55 -7.85 -4.31 -1.231 0.73537E+04 87 greenalite 16.14 13.89 -2.25 -0.187 0.38410E+04 90 hematite 12.57 8.99 -3.58 -0.434 0.61117E+04 91 heulandite -5.83 -7.52 -1.69 -0.077 0.28938E+04 95 jadeite 4.22 2.77 -1.44 -0.144 0.24614E+04 97 kalsilite 7.58 3.83 -3.76 -0.536 0.64119E+04 98 kaolinite -1.33 -4.84 -3.50 -0.318 0.59818E+04 101 laumontite 2.88 1.95 -0.93 -0.062 0.15925E+04 102 lawsonite 9.62 8.27 -1.35 -0.090 0.23052E+04 103 leucite 4.12 0.67 -3.45 -0.345 0.58869E+04 105 lizardite 23.24 21.57 -1.68 -0.140 0.28614E+04 107 magnetite 20.09 15.72 -4.37 -0.356 0.74540E+04 108 minnesotaite 10.39 7.57 -2.81 -0.165 0.48037E+04 112 manganosite 14.06 9.22 -4.83 -1.208 0.82535E+04 120 muscovite 2.58 -1.01 -3.59 -0.211 0.61294E+04 121 paragonite 4.24 1.10 -3.14 -0.185 0.53685E+04 122 nepheline 8.34 5.93 -2.41 -0.344 0.41118E+04 128 periclase-Fe 11.63 6.74 -4.89 -1.223 0.83521E+04 134 phlogopite-Na 29.65 27.50 -2.15 -0.119 0.36666E+04 136 prehnite 19.37 18.21 -1.16 -0.068 0.19832E+04 137 prehnite-Fe 22.50 21.96 -0.53 -0.032 0.91114E+03 138 pumpellyite-Fe 46.27 43.90 -2.37 -0.053 0.40535E+04 139 pumpellyite-Mg 48.99 46.45 -2.54 -0.056 0.43371E+04 143 pyrrhotite -4.26 -8.06 -3.80 -1.265 0.64818E+04 144 pyrrhotiteFe0.875 -6.02 -9.45 -3.44 -1.264 0.58692E+04 145 pyroxmangite 7.40 6.07 -1.33 -0.266 0.22742E+04 146 pyrophyllite -6.18 -11.15 -4.98 -0.311 0.84955E+04 147 quartz -2.99 -3.16 -0.17 -0.056 0.28715E+03 152 rhodonite 7.45 6.07 -1.38 -0.276 0.23545E+04 153 sanidine -1.28 -2.49 -1.21 -0.093 0.20677E+04 165 stilpnomelane-Mg 27.44 25.81 -1.63 -0.049 0.27791E+04 171 talc 16.49 15.25 -1.24 -0.073 0.21142E+04 174 tephroite 18.09 15.29 -2.79 -0.399 0.47718E+04 178 tridymite -2.63 -3.16 -0.53 -0.177 0.90713E+03 179 tremolite 47.87 47.42 -0.45 -0.012 0.77506E+03 180 ferroactinolite 38.45 34.62 -3.83 -0.104 0.65462E+04 181 troilite-low -4.41 -8.06 -3.65 -1.215 0.62246E+04 183 vesuvianite 223.47 218.83 -4.64 -0.035 0.79311E+04 187 wairakite 3.95 1.95 -2.00 -0.118 0.34144E+04 188 walstromite 11.51 9.94 -1.56 -0.313 0.26718E+04 189 wollastonite 10.46 9.94 -0.52 -0.103 0.88228E+03 190 pseudo-wollastonite 11.00 9.94 -1.06 -0.211 0.18021E+04 191 zoisite 22.85 18.95 -3.90 -0.177 0.66581E+04 192 akaganeite 7.75 4.49 -3.26 -0.705 0.55684E+04 199 chalcedony -2.80 -3.16 -0.36 -0.118 0.60645E+03 201 montmorillonite-Ca -2.29 -6.17 -3.88 -0.240 0.66175E+04 202 montmorillonite-K -2.24 -6.27 -4.03 -0.247 0.68812E+04 203 montmorillonite-Mg -2.48 -6.79 -4.31 -0.267 0.73673E+04 204 montmorillonite-Na -2.04 -5.57 -3.54 -0.216 0.60361E+04 205 nontronite-Ca 3.21 -0.20 -3.41 -0.221 0.58229E+04 206 nontronite-H 2.53 -2.36 -4.89 -0.328 0.83499E+04 207 nontronite-K 3.34 -0.30 -3.64 -0.233 0.62098E+04 208 nontronite-Mg 3.07 -0.82 -3.90 -0.253 0.66567E+04 209 nontronite-Na 3.52 0.40 -3.12 -0.200 0.53306E+04 224 tobermorite 9.82 7.76 -2.07 -0.564 0.35288E+04 230 alabandite -0.98 -5.57 -4.59 -1.530 0.78361E+04 233 boehmite 4.41 0.74 -3.67 -0.611 0.62609E+04 235 ferrous-oxide 9.81 6.74 -3.08 -0.769 0.52531E+04 240 silica-amorphous -2.09 -3.16 -1.07 -0.355 0.18206E+04 242 an20ab80 2.02 1.35 -0.67 -0.052 0.11469E+04 243 an25ab75 2.65 1.78 -0.87 -0.067 0.14806E+04 244 an30ab70 3.28 2.21 -1.07 -0.082 0.18239E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 10.0000000 g Current total amount of reactant added: 209.9990000 g New total amount of reactant added: 219.9990000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.3651E-11 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 11 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 219.9990000 Water: Moles liquid = 0.5420E+02 kg liquid = 0.9764E+00 Moles total = 0.5275E+02 kg total = 0.9503E+00 Activity = 1.0000 Stoichiometric ionic strength = .1131881E-01 Osmotic coef. = 0.9695 True ionic strength = .2000795E-01 Chg. balance for total moles = 0.3651E-11 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.88247E-10 -10.0543 0.74152E-10 -10.1299 0.84028E+00 -0.0756 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.14067E-03 -3.8518 0.11749E-03 -3.9300 0.83523E+00 -0.0782 4 SO4-- 0.66080E-12 -12.1799 0.34321E-12 -12.4644 0.51938E+00 -0.2845 5 HCO3- 0.24459E-06 -6.6116 0.20459E-06 -6.6891 0.83645E+00 -0.0776 6 HS- 0.26117E-04 -4.5831 0.21817E-04 -4.6612 0.83535E+00 -0.0781 7 Al+++ 0.96854E-29 -29.0139 0.22383E-29 -29.6501 0.23110E+00 -0.6362 8 H4SiO4 0.69567E-03 -3.1576 0.69567E-03 -3.1576 0.10000E+01 0.0000 9 Ca++ 0.13489E-06 -6.8700 0.69547E-07 -7.1577 0.51557E+00 -0.2877 10 Mg++ 0.21104E-10 -10.6756 0.10831E-10 -10.9653 0.51321E+00 -0.2897 11 Fe++ 0.58148E-13 -13.2355 0.29875E-13 -13.5247 0.51377E+00 -0.2892 12 K+ 0.15643E-03 -3.8057 0.13088E-03 -3.8831 0.83665E+00 -0.0775 13 Na+ 0.19851E-01 -1.7022 0.16577E-01 -1.7805 0.83508E+00 -0.0783 14 Mn++ 0.17959E-10 -10.7457 0.92344E-11 -11.0346 0.51420E+00 -0.2889 15 HPO4-- 0.45324E-07 -7.3437 0.23544E-07 -7.6281 0.51945E+00 -0.2845 16 HSiO3- 0.10488E-01 -1.9793 0.87600E-02 -2.0575 0.83523E+00 -0.0782 17 Ca(HSiO3)+ 0.16580E-07 -7.7804 0.13874E-07 -7.8578 0.83683E+00 -0.0774 18 Mg(HSiO3)+ 0.32134E-11 -11.4930 0.26891E-11 -11.5704 0.83683E+00 -0.0774 19 NaHSiO3,aq 0.23486E-02 -2.6292 0.23486E-02 -2.6292 0.10000E+01 0.0000 20 AlO+ 0.66178E-16 -16.1793 0.55380E-16 -16.2566 0.83683E+00 -0.0774 22 HAlO2,aq 0.14873E-09 -9.8276 0.14873E-09 -9.8276 0.10000E+01 0.0000 23 AlO2- 0.53254E-05 -5.2736 0.44399E-05 -5.3526 0.83372E+00 -0.0790 24 CH4,aq 0.12676E-04 -4.8970 0.12633E-04 -4.8985 0.99655E+00 -0.0015 25 C2H6,aq 0.23611E-14 -14.6269 0.23530E-14 -14.6284 0.99655E+00 -0.0015 29 CO,aq 0.94417E-17 -17.0249 0.94417E-17 -17.0249 0.10000E+01 0.0000 30 CO2,aq 0.32528E-10 -10.4877 0.32416E-10 -10.4892 0.99655E+00 -0.0015 31 CO3-2 0.46498E-06 -6.3326 0.24099E-06 -6.6180 0.51828E+00 -0.2854 32 CaCO3,aq 0.21015E-09 -9.6775 0.21015E-09 -9.6775 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.43401E-12 -12.3625 0.36319E-12 -12.4399 0.83683E+00 -0.0774 34 CaCl+ 0.15802E-10 -10.8013 0.13223E-10 -10.8787 0.83683E+00 -0.0774 35 CaCl2,aq 0.36910E-15 -15.4329 0.36910E-15 -15.4329 0.10000E+01 0.0000 36 CaOH+ 0.79877E-07 -7.0976 0.66843E-07 -7.1749 0.83683E+00 -0.0774 37 CaSO4,aq 0.75794E-17 -17.1204 0.75794E-17 -17.1204 0.10000E+01 0.0000 38 HCl,aq 0.15965E-14 -14.7968 0.15965E-14 -14.7968 0.10000E+01 0.0000 43 FeCl+ 0.66390E-17 -17.1779 0.55557E-17 -17.2553 0.83683E+00 -0.0774 46 FeO,aq 0.21116E-09 -9.6754 0.21116E-09 -9.6754 0.10000E+01 0.0000 47 FeOH+ 0.15671E-10 -10.8049 0.13114E-10 -10.8823 0.83683E+00 -0.0774 48 HFeO2- 0.35674E-07 -7.4476 0.29796E-07 -7.5258 0.83523E+00 -0.0782 49 FeO+ 0.10977E-16 -16.9595 0.91863E-17 -17.0369 0.83683E+00 -0.0774 51 FeO2- 0.40929E-09 -9.3880 0.34185E-09 -9.4662 0.83523E+00 -0.0782 52 HFeO2,aq 0.32240E-11 -11.4916 0.32240E-11 -11.4916 0.10000E+01 0.0000 53 H2,aq 0.11635E-04 -4.9342 0.11595E-04 -4.9357 0.99655E+00 -0.0015 54 KCl,aq 0.27869E-09 -9.5549 0.27869E-09 -9.5549 0.10000E+01 0.0000 56 KOH,aq 0.75376E-06 -6.1228 0.75376E-06 -6.1228 0.10000E+01 0.0000 57 KSO4- 0.83453E-15 -15.0786 0.69702E-15 -15.1568 0.83523E+00 -0.0782 58 MgCO3,aq 0.82034E-14 -14.0860 0.82034E-14 -14.0860 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.69065E-16 -16.1607 0.57795E-16 -16.2381 0.83683E+00 -0.0774 60 MgCl+ 0.22304E-14 -14.6516 0.18664E-14 -14.7290 0.83683E+00 -0.0774 61 MgOH+ 0.68834E-10 -10.1622 0.57602E-10 -10.2396 0.83683E+00 -0.0774 63 MnO,aq 0.17392E-08 -8.7596 0.17392E-08 -8.7596 0.10000E+01 0.0000 64 MnOH+ 0.45000E-09 -9.3468 0.37658E-09 -9.4241 0.83683E+00 -0.0774 65 MnO2-2 0.20254E-10 -10.6935 0.10497E-10 -10.9789 0.51828E+00 -0.2854 66 HMnO2- 0.20418E-09 -9.6900 0.17053E-09 -9.7682 0.83523E+00 -0.0782 69 MnCl+ 0.79838E-14 -14.0978 0.66810E-14 -14.1752 0.83683E+00 -0.0774 71 NaCl,aq 0.64543E-06 -6.1901 0.64543E-06 -6.1901 0.10000E+01 0.0000 72 NaOH,aq 0.96048E-04 -4.0175 0.96048E-04 -4.0175 0.10000E+01 0.0000 74 OH- 0.93457E-02 -2.0294 0.77917E-02 -2.1084 0.83372E+00 -0.0790 79 HPO3-2 0.16414E-14 -14.7848 0.85071E-15 -15.0702 0.51828E+00 -0.2854 81 H2PO3- 0.15145E-18 -18.8197 0.12650E-18 -18.8979 0.83523E+00 -0.0782 82 H3PO4,aq 0.90541E-18 -18.0432 0.90541E-18 -18.0432 0.10000E+01 0.0000 83 H2PO4- 0.38523E-10 -10.4143 0.32206E-10 -10.4921 0.83602E+00 -0.0778 84 PO4-3 0.10673E-08 -8.9717 0.25905E-09 -9.5866 0.24272E+00 -0.6149 88 HP2O7-3 0.94667E-18 -18.0238 0.21900E-18 -18.6596 0.23133E+00 -0.6358 89 P2O7-4 0.91452E-17 -17.0388 0.70555E-18 -18.1515 0.77149E-01 -1.1127 90 H2S,aq 0.50172E-08 -8.2995 0.49998E-08 -8.3010 0.99655E+00 -0.0015 91 S2-2 0.17550E-14 -14.7557 0.90958E-15 -15.0412 0.51828E+00 -0.2854 97 SO3-2 0.98355E-18 -18.0072 0.51712E-18 -18.2864 0.52577E+00 -0.2792 99 HSO4- 0.29280E-19 -19.5334 0.24526E-19 -19.6104 0.83764E+00 -0.0769 Charge balance for all species = 0.3738E-11 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.8824724E-10 -.2230418E-01 -.2244222E+02 0.0000 2 H2O 0.1000000E+01 0.5550489E+02 0.9982003E+06 0.0000 3 Cl- 0.1406672E-03 0.1413130E-03 0.5001266E+01 6.1999 4 SO4-- 0.6608014E-12 -.1558513E-04 -.1494532E+01 7.7953 5 HCO3- 0.2445888E-06 0.1338628E-04 0.8153742E+00 3.4408 6 HS- 0.2611662E-04 0.4170677E-04 0.1376930E+01 5.4687 7 Al+++ 0.9685384E-29 0.5325580E-05 0.1434425E+00 0.7396 8 H4SiO4 0.6956683E-03 0.1353246E-01 0.1298418E+04 -3.1576 9 Ca++ 0.1348936E-06 0.2315765E-06 0.9265000E-02 13.1020 10 Mg++ 0.2110403E-10 0.9316197E-10 0.2261020E-05 9.2944 11 Fe++ 0.5814776E-13 0.3631335E-07 0.2024469E-02 6.7351 12 K+ 0.1564327E-03 0.1571868E-03 0.6135641E+01 6.2467 13 Na+ 0.1985051E-01 0.2229580E-01 0.5116857E+03 8.3494 14 Mn++ 0.1795897E-10 0.2431624E-08 0.1333565E-03 9.2252 15 HPO4-- 0.4532427E-07 0.4643007E-07 0.4448571E-02 12.6316 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.3642844E+01 -.2177720E-01 -.3621067E+01 0.0000000E+00 2 H2O 0.5275047E+02 0.5419349E+02 -.1443014E+01 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.6122427E-02 -.1521690E-04 0.6137644E-02 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.6096922E-02 0.4072137E-04 -.6137644E-02 0.0000000E+00 7 Al+++ 0.7173599E+00 0.5199753E-05 0.7173547E+00 0.0000000E+00 8 H4SiO4 0.2290802E+01 0.1321273E-01 0.2277589E+01 0.0000000E+00 9 Ca++ 0.2530447E+00 0.2261050E-06 0.2530445E+00 0.0000000E+00 10 Mg++ 0.1746024E+00 0.9096085E-10 0.1746024E+00 0.0000000E+00 11 Fe++ 0.1568612E+00 0.3545538E-07 0.1568611E+00 0.0000000E+00 12 K+ 0.4670892E-01 0.1534729E-03 0.4655544E-01 0.0000000E+00 13 Na+ 0.2763124E+00 0.2176902E-01 0.2545434E+00 0.0000000E+00 14 Mn++ 0.3814474E-02 0.2374172E-08 0.3814471E-02 0.0000000E+00 15 HPO4-- 0.1301861E-02 0.4533308E-07 0.1301816E-02 0.0000000E+00 Chg. balance for solid moles: -.3656E-15 Mass of aqueous solution: 0.978072E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 219.9990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 0.2542 -0.595 66.66 1.824 27.76 25.59 andradite 0.2455E-01 -1.610 12.48 1.096 5.195 3.241 grossular 0.5955E-02 -2.225 2.682 0.429 1.117 0.7463 apatite-OH 0.4339E-03 -3.363 0.2180 -0.662 0.9076E-01 0.6926E-01 clinochlore 0.3247E-01 -1.488 18.05 1.256 7.516 6.866 daphnite 0.9398E-02 -2.027 6.705 0.826 2.792 2.032 chlorite-Mn 0.7629E-03 -3.118 0.5409 -0.267 0.2252 0.1724 diopside 0.2707E-02 -2.568 0.5861 -0.232 0.2441 0.1791 hedenbergite 0.7017E-03 -3.154 0.1741 -0.759 0.7249E-01 0.4768E-01 microcline 0.4088E-01 -1.389 11.38 1.056 4.738 4.444 stilbite 0.1507 -0.822 106.2 2.026 44.22 49.53 stilpnomelane-Fe 0.1136E-01 -1.945 12.24 1.088 5.098 4.229 tr.625ac.25prg.125 0.2629E-02 -2.580 2.247 0.352 0.9356 0.7232 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8048E+00 0.8048E+00 1.0000 -0.094 grossular 0.1952E+00 0.1952E+00 1.0000 -0.710 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.7617E+00 0.7617E+00 1.0000 -0.118 daphnite 0.2204E+00 0.2204E+00 1.0000 -0.657 chlorite-Mn 0.1789E-01 0.1789E-01 1.0000 -1.747 diopside 0.7941E+00 0.7941E+00 1.0000 -0.100 hedenbergite 0.2059E+00 0.2059E+00 1.0000 -0.686 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 tr.625ac.25prg.125 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 240.156302 g Volume = 97.871399 cm3 Porosity: -9.9684% V(tot) - V(min): -.88718E+01 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 219.9990000 g log = 2.3424 Original solution: 1000.0103000 g Original solution / Rock added: 4.55 (Water/Rock Ratio), log = 0.6576 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0544 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9682E+00 0.9855 0.1006E+01 0.1021E+01 CO2,gas 0.3267E-08 1.0069 0.3468E-08 0.3444E-08 CH4,gas 0.1742E-01 1.0125 0.1859E-01 0.1837E-01 H2,gas 0.1443E-01 1.0006 0.1522E-01 0.1521E-01 H2S,gas 0.1309E-06 0.9959 0.1374E-06 0.1380E-06 S2,gas 0.2902E-29 1.0000 0.3060E-29 0.3060E-29 CO,gas 0.1334E-13 1.0000 0.1407E-13 0.1407E-13 SO3,gas 0.6767E-48 1.0000 0.7135E-48 0.7135E-48 SO2,gas 0.4008E-27 1.0000 0.4226E-27 0.4226E-27 HCl,gas 0.2672E-17 1.0000 0.2817E-17 0.2817E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 16 albite -0.38 -0.38 0.00 0.000 0.11184E-10 22 andradite 39.01 39.01 0.00 0.000 0.24265E-10 23 grossular 32.73 32.73 0.00 0.000 0.24265E-10 32 apatite-OH -18.15 -18.15 0.00 0.000 0.00000E+00 46 clinochlore 39.07 39.07 0.00 0.000 0.36397E-10 47 daphnite 28.97 28.97 0.00 0.000 -0.12132E-10 48 chlorite-Mn 46.87 46.87 0.00 0.000 0.36397E-10 67 diopside 16.18 16.18 0.00 0.000 0.00000E+00 68 hedenbergite 14.21 14.21 0.00 0.000 -0.60662E-11 116 microcline -2.49 -2.49 0.00 0.000 0.13649E-10 163 stilbite -7.52 -7.52 0.00 0.000 0.15165E-10 164 stilpnomelane-Fe 13.02 13.02 0.00 0.000 0.21232E-10 245 tr.625ac.25prg.125 45.16 45.16 0.00 0.000 -0.36397E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -16.82 -10.16 -3.386 0.17346E+05 -8.460 3 CH4,gas 4.54 1.11 -3.43 -0.857 0.58559E+04 -1.731 4 H2,gas 8.00 4.48 -3.52 -2.009 0.60043E+04 -1.818 5 H2S,gas -6.23 -14.79 -8.56 -4.280 0.14617E+05 -6.862 6 S2,gas -7.34 -38.55 -31.21 -4.802 0.53296E+05 -29.514 7 CO,gas 3.21 -12.34 -15.55 -4.785 0.26552E+05 -13.852 8 SO3,gas 17.12 -32.72 -49.85 -12.461 0.85110E+05 -48.147 9 SO2,gas 0.83 -28.24 -29.07 -7.753 0.49641E+05 -27.374 10 HCl,gas 5.19 -14.06 -19.25 -9.625 0.32867E+05 -17.550 11 acmite 7.71 6.53 -1.18 -0.123 0.20184E+04 15 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 19 spessartine 24.46 19.68 -4.78 -0.239 0.81541E+04 20 analcite 3.32 2.77 -0.55 -0.061 0.93592E+03 26 annite 20.12 17.72 -2.40 -0.134 0.41060E+04 27 phlogopite 27.06 25.40 -1.67 -0.093 0.28478E+04 29 anorthite 12.71 8.27 -4.44 -0.342 0.75887E+04 35 aragonite 0.97 -3.72 -4.68 -1.561 0.79969E+04 36 brucite 12.57 9.29 -3.27 -0.655 0.55905E+04 37 calcite 0.81 -3.72 -4.53 -1.510 0.77327E+04 38 carnegieite-low 9.02 5.93 -3.09 -0.442 0.52795E+04 39 carnegieite-high 10.09 5.93 -4.16 -0.595 0.71064E+04 40 carpholite-Mg 8.58 4.46 -4.12 -0.275 0.70412E+04 41 carpholite-Fe 6.71 1.90 -4.81 -0.321 0.82192E+04 42 celadonite 5.34 3.65 -1.69 -0.099 0.28878E+04 43 celadonite-Fe 3.88 1.09 -2.79 -0.164 0.47563E+04 44 chrysotile 23.89 21.57 -2.32 -0.194 0.39688E+04 49 chlorite-Al-free 47.17 43.14 -4.04 -0.168 0.68927E+04 51 chloritoid-Fe 9.17 5.06 -4.12 -0.274 0.70298E+04 52 chloritoid-Mn 11.40 7.55 -3.85 -0.257 0.65813E+04 54 coesite -2.38 -3.16 -0.78 -0.261 0.13344E+04 61 cristobalite -2.56 -3.16 -0.60 -0.199 0.10198E+04 63 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71234E+04 65 diaspore 2.87 0.74 -2.13 -0.356 0.36440E+04 66 diamond -3.10 -7.85 -4.75 -1.357 0.81106E+04 71 enstatite 17.26 12.27 -4.99 -0.499 0.85225E+04 73 clinoenstatite 17.17 12.27 -4.89 -0.489 0.83541E+04 75 epidote 24.67 22.70 -1.97 -0.095 0.33571E+04 76 clinozoisite 22.81 18.95 -3.86 -0.175 0.65842E+04 77 epidote-Fe 29.84 26.46 -3.38 -0.176 0.57766E+04 78 fayalite 14.05 10.31 -3.73 -0.533 0.63744E+04 79 ferrosilite 11.15 7.15 -3.99 -0.399 0.68206E+04 83 gibbsite 4.08 0.74 -3.34 -0.477 0.57025E+04 84 glaucophane 22.97 20.80 -2.17 -0.059 0.37129E+04 85 glaucophane-Fe 17.28 13.12 -4.15 -0.112 0.70921E+04 86 graphite -3.55 -7.85 -4.31 -1.230 0.73528E+04 87 greenalite 16.14 13.89 -2.25 -0.187 0.38410E+04 90 hematite 12.57 8.99 -3.58 -0.434 0.61116E+04 91 heulandite -5.83 -7.52 -1.69 -0.077 0.28938E+04 95 jadeite 4.22 2.77 -1.44 -0.144 0.24614E+04 97 kalsilite 7.58 3.83 -3.76 -0.536 0.64119E+04 98 kaolinite -1.33 -4.84 -3.50 -0.318 0.59818E+04 101 laumontite 2.88 1.95 -0.93 -0.062 0.15925E+04 102 lawsonite 9.62 8.27 -1.35 -0.090 0.23053E+04 103 leucite 4.12 0.67 -3.45 -0.345 0.58870E+04 105 lizardite 23.24 21.57 -1.68 -0.140 0.28614E+04 107 magnetite 20.09 15.72 -4.37 -0.356 0.74540E+04 108 minnesotaite 10.39 7.57 -2.81 -0.165 0.48037E+04 112 manganosite 14.06 9.23 -4.83 -1.208 0.82521E+04 120 muscovite 2.58 -1.01 -3.59 -0.211 0.61295E+04 121 paragonite 4.24 1.10 -3.14 -0.185 0.53686E+04 122 nepheline 8.34 5.93 -2.41 -0.344 0.41118E+04 128 periclase-Fe 11.63 6.74 -4.89 -1.223 0.83522E+04 134 phlogopite-Na 29.65 27.50 -2.15 -0.119 0.36666E+04 136 prehnite 19.37 18.21 -1.16 -0.068 0.19833E+04 137 prehnite-Fe 22.50 21.96 -0.53 -0.032 0.91116E+03 138 pumpellyite-Fe 46.27 43.90 -2.37 -0.053 0.40537E+04 139 pumpellyite-Mg 48.99 46.45 -2.54 -0.056 0.43373E+04 143 pyrrhotite -4.26 -8.06 -3.80 -1.265 0.64811E+04 144 pyrrhotiteFe0.875 -6.02 -9.45 -3.44 -1.264 0.58684E+04 145 pyroxmangite 7.40 6.07 -1.33 -0.266 0.22728E+04 146 pyrophyllite -6.18 -11.15 -4.98 -0.311 0.84955E+04 147 quartz -2.99 -3.16 -0.17 -0.056 0.28713E+03 152 rhodonite 7.45 6.07 -1.38 -0.276 0.23531E+04 153 sanidine -1.28 -2.49 -1.21 -0.093 0.20677E+04 165 stilpnomelane-Mg 27.44 25.81 -1.63 -0.049 0.27792E+04 171 talc 16.49 15.25 -1.24 -0.073 0.21142E+04 174 tephroite 18.09 15.29 -2.79 -0.399 0.47691E+04 178 tridymite -2.63 -3.16 -0.53 -0.177 0.90711E+03 179 tremolite 47.87 47.42 -0.45 -0.012 0.77505E+03 180 ferroactinolite 38.45 34.62 -3.83 -0.104 0.65461E+04 181 troilite-low -4.41 -8.06 -3.65 -1.215 0.62239E+04 183 vesuvianite 223.47 218.83 -4.65 -0.035 0.79317E+04 187 wairakite 3.95 1.95 -2.00 -0.118 0.34145E+04 188 walstromite 11.51 9.94 -1.56 -0.313 0.26718E+04 189 wollastonite 10.46 9.94 -0.52 -0.103 0.88228E+03 190 pseudo-wollastonite 11.00 9.94 -1.06 -0.211 0.18021E+04 191 zoisite 22.85 18.95 -3.90 -0.177 0.66583E+04 192 akaganeite 7.75 4.49 -3.26 -0.705 0.55684E+04 199 chalcedony -2.80 -3.16 -0.36 -0.118 0.60643E+03 201 montmorillonite-Ca -2.29 -6.17 -3.88 -0.240 0.66175E+04 202 montmorillonite-K -2.24 -6.27 -4.03 -0.247 0.68812E+04 203 montmorillonite-Mg -2.48 -6.79 -4.31 -0.267 0.73673E+04 204 montmorillonite-Na -2.04 -5.57 -3.54 -0.216 0.60361E+04 205 nontronite-Ca 3.21 -0.20 -3.41 -0.221 0.58228E+04 206 nontronite-H 2.53 -2.36 -4.89 -0.328 0.83499E+04 207 nontronite-K 3.34 -0.30 -3.64 -0.233 0.62097E+04 208 nontronite-Mg 3.07 -0.82 -3.90 -0.253 0.66566E+04 209 nontronite-Na 3.52 0.40 -3.12 -0.200 0.53306E+04 224 tobermorite 9.82 7.76 -2.07 -0.564 0.35288E+04 230 alabandite -0.98 -5.57 -4.59 -1.529 0.78340E+04 233 boehmite 4.41 0.74 -3.67 -0.611 0.62609E+04 235 ferrous-oxide 9.81 6.74 -3.08 -0.769 0.52531E+04 240 silica-amorphous -2.09 -3.16 -1.07 -0.355 0.18206E+04 242 an20ab80 2.02 1.35 -0.67 -0.052 0.11469E+04 243 an25ab75 2.65 1.78 -0.87 -0.067 0.14806E+04 244 an30ab70 3.28 2.21 -1.07 -0.082 0.18239E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 10.0000000 g Current total amount of reactant added: 219.9990000 g New total amount of reactant added: 229.9990000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.3651E-11 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 11 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 229.9990000 Water: Moles liquid = 0.5414E+02 kg liquid = 0.9754E+00 Moles total = 0.5263E+02 kg total = 0.9481E+00 Activity = 1.0000 Stoichiometric ionic strength = .1131901E-01 Osmotic coef. = 0.9695 True ionic strength = .2000816E-01 Chg. balance for total moles = 0.3651E-11 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.88248E-10 -10.0543 0.74153E-10 -10.1299 0.84028E+00 -0.0756 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.14081E-03 -3.8514 0.11761E-03 -3.9296 0.83523E+00 -0.0782 4 SO4-- 0.66160E-12 -12.1794 0.34362E-12 -12.4639 0.51938E+00 -0.2845 5 HCO3- 0.24488E-06 -6.6110 0.20483E-06 -6.6886 0.83645E+00 -0.0776 6 HS- 0.26144E-04 -4.5826 0.21839E-04 -4.6608 0.83535E+00 -0.0781 7 Al+++ 0.96852E-29 -29.0139 0.22383E-29 -29.6501 0.23110E+00 -0.6362 8 H4SiO4 0.69568E-03 -3.1576 0.69568E-03 -3.1576 0.10000E+01 0.0000 9 Ca++ 0.13489E-06 -6.8700 0.69547E-07 -7.1577 0.51557E+00 -0.2877 10 Mg++ 0.21104E-10 -10.6756 0.10831E-10 -10.9653 0.51321E+00 -0.2897 11 Fe++ 0.58149E-13 -13.2355 0.29875E-13 -13.5247 0.51377E+00 -0.2892 12 K+ 0.15643E-03 -3.8057 0.13088E-03 -3.8831 0.83665E+00 -0.0775 13 Na+ 0.19851E-01 -1.7022 0.16577E-01 -1.7805 0.83508E+00 -0.0783 14 Mn++ 0.17990E-10 -10.7450 0.92502E-11 -11.0338 0.51420E+00 -0.2889 15 HPO4-- 0.45325E-07 -7.3437 0.23544E-07 -7.6281 0.51945E+00 -0.2845 16 HSiO3- 0.10488E-01 -1.9793 0.87601E-02 -2.0575 0.83523E+00 -0.0782 17 Ca(HSiO3)+ 0.16580E-07 -7.7804 0.13875E-07 -7.8578 0.83683E+00 -0.0774 18 Mg(HSiO3)+ 0.32134E-11 -11.4930 0.26891E-11 -11.5704 0.83683E+00 -0.0774 19 NaHSiO3,aq 0.23486E-02 -2.6292 0.23486E-02 -2.6292 0.10000E+01 0.0000 20 AlO+ 0.66175E-16 -16.1793 0.55377E-16 -16.2567 0.83683E+00 -0.0774 22 HAlO2,aq 0.14872E-09 -9.8276 0.14872E-09 -9.8276 0.10000E+01 0.0000 23 AlO2- 0.53251E-05 -5.2737 0.44396E-05 -5.3527 0.83372E+00 -0.0790 24 CH4,aq 0.12689E-04 -4.8966 0.12646E-04 -4.8981 0.99655E+00 -0.0015 25 C2H6,aq 0.23660E-14 -14.6260 0.23579E-14 -14.6275 0.99655E+00 -0.0015 29 CO,aq 0.94526E-17 -17.0244 0.94526E-17 -17.0244 0.10000E+01 0.0000 30 CO2,aq 0.32567E-10 -10.4872 0.32455E-10 -10.4887 0.99655E+00 -0.0015 31 CO3-2 0.46553E-06 -6.3321 0.24127E-06 -6.6175 0.51827E+00 -0.2854 32 CaCO3,aq 0.21040E-09 -9.6770 0.21040E-09 -9.6770 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.43453E-12 -12.3620 0.36362E-12 -12.4393 0.83683E+00 -0.0774 34 CaCl+ 0.15818E-10 -10.8009 0.13237E-10 -10.8782 0.83683E+00 -0.0774 35 CaCl2,aq 0.36986E-15 -15.4320 0.36986E-15 -15.4320 0.10000E+01 0.0000 36 CaOH+ 0.79876E-07 -7.0976 0.66842E-07 -7.1749 0.83683E+00 -0.0774 37 CaSO4,aq 0.75886E-17 -17.1198 0.75886E-17 -17.1198 0.10000E+01 0.0000 38 HCl,aq 0.15981E-14 -14.7964 0.15981E-14 -14.7964 0.10000E+01 0.0000 43 FeCl+ 0.66459E-17 -17.1774 0.55614E-17 -17.2548 0.83683E+00 -0.0774 46 FeO,aq 0.21116E-09 -9.6754 0.21116E-09 -9.6754 0.10000E+01 0.0000 47 FeOH+ 0.15671E-10 -10.8049 0.13114E-10 -10.8823 0.83683E+00 -0.0774 48 HFeO2- 0.35673E-07 -7.4477 0.29795E-07 -7.5259 0.83523E+00 -0.0782 49 FeO+ 0.10978E-16 -16.9595 0.91865E-17 -17.0369 0.83683E+00 -0.0774 51 FeO2- 0.40930E-09 -9.3880 0.34185E-09 -9.4662 0.83523E+00 -0.0782 52 HFeO2,aq 0.32241E-11 -11.4916 0.32241E-11 -11.4916 0.10000E+01 0.0000 53 H2,aq 0.11634E-04 -4.9343 0.11594E-04 -4.9358 0.99655E+00 -0.0015 54 KCl,aq 0.27898E-09 -9.5544 0.27898E-09 -9.5544 0.10000E+01 0.0000 56 KOH,aq 0.75376E-06 -6.1228 0.75376E-06 -6.1228 0.10000E+01 0.0000 57 KSO4- 0.83555E-15 -15.0780 0.69787E-15 -15.1562 0.83523E+00 -0.0782 58 MgCO3,aq 0.82131E-14 -14.0855 0.82131E-14 -14.0855 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.69147E-16 -16.1602 0.57864E-16 -16.2376 0.83683E+00 -0.0774 60 MgCl+ 0.22327E-14 -14.6512 0.18684E-14 -14.7285 0.83683E+00 -0.0774 61 MgOH+ 0.68833E-10 -10.1622 0.57601E-10 -10.2396 0.83683E+00 -0.0774 63 MnO,aq 0.17422E-08 -8.7589 0.17422E-08 -8.7589 0.10000E+01 0.0000 64 MnOH+ 0.45077E-09 -9.3460 0.37721E-09 -9.4234 0.83683E+00 -0.0774 65 MnO2-2 0.20288E-10 -10.6928 0.10515E-10 -10.9782 0.51827E+00 -0.2854 66 HMnO2- 0.20452E-09 -9.6893 0.17082E-09 -9.7675 0.83523E+00 -0.0782 69 MnCl+ 0.80056E-14 -14.0966 0.66993E-14 -14.1740 0.83683E+00 -0.0774 71 NaCl,aq 0.64610E-06 -6.1897 0.64610E-06 -6.1897 0.10000E+01 0.0000 72 NaOH,aq 0.96048E-04 -4.0175 0.96048E-04 -4.0175 0.10000E+01 0.0000 74 OH- 0.93456E-02 -2.0294 0.77916E-02 -2.1084 0.83372E+00 -0.0790 79 HPO3-2 0.16414E-14 -14.7848 0.85068E-15 -15.0702 0.51827E+00 -0.2854 81 H2PO3- 0.15145E-18 -18.8197 0.12650E-18 -18.8979 0.83523E+00 -0.0782 82 H3PO4,aq 0.90544E-18 -18.0431 0.90544E-18 -18.0431 0.10000E+01 0.0000 83 H2PO4- 0.38524E-10 -10.4143 0.32206E-10 -10.4921 0.83602E+00 -0.0778 84 PO4-3 0.10673E-08 -8.9717 0.25905E-09 -9.5866 0.24272E+00 -0.6149 88 HP2O7-3 0.94671E-18 -18.0238 0.21901E-18 -18.6595 0.23133E+00 -0.6358 89 P2O7-4 0.91455E-17 -17.0388 0.70557E-18 -18.1515 0.77149E-01 -1.1127 90 H2S,aq 0.50224E-08 -8.2991 0.50050E-08 -8.3006 0.99655E+00 -0.0015 91 S2-2 0.17587E-14 -14.7548 0.91150E-15 -15.0402 0.51827E+00 -0.2854 97 SO3-2 0.98469E-18 -18.0067 0.51772E-18 -18.2859 0.52577E+00 -0.2792 99 HSO4- 0.29315E-19 -19.5329 0.24556E-19 -19.6098 0.83764E+00 -0.0769 Charge balance for all species = 0.3742E-11 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.8824814E-10 -.2230425E-01 -.2244230E+02 0.0000 2 H2O 0.1000000E+01 0.5550489E+02 0.9982003E+06 0.0000 3 Cl- 0.1408121E-03 0.1414585E-03 0.5006415E+01 6.2003 4 SO4-- 0.6615985E-12 -.1559793E-04 -.1495760E+01 7.7958 5 HCO3- 0.2448813E-06 0.1340006E-04 0.8162138E+00 3.4413 6 HS- 0.2614351E-04 0.4174647E-04 0.1378241E+01 5.4691 7 Al+++ 0.9685154E-29 0.5325220E-05 0.1434328E+00 0.7395 8 H4SiO4 0.6956819E-03 0.1353263E-01 0.1298435E+04 -3.1576 9 Ca++ 0.1348938E-06 0.2315764E-06 0.9264995E-02 13.1020 10 Mg++ 0.2110403E-10 0.9316120E-10 0.2261001E-05 9.2944 11 Fe++ 0.5814858E-13 0.3631275E-07 0.2024436E-02 6.7351 12 K+ 0.1564343E-03 0.1571883E-03 0.6135702E+01 6.2467 13 Na+ 0.1985071E-01 0.2229605E-01 0.5116913E+03 8.3494 14 Mn++ 0.1798969E-10 0.2435733E-08 0.1335818E-03 9.2259 15 HPO4-- 0.4532504E-07 0.4643085E-07 0.4448646E-02 12.6316 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.3808429E+01 -.2175487E-01 -.3786674E+01 0.0000000E+00 2 H2O 0.5262512E+02 0.5413774E+02 -.1512625E+01 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.6399561E-02 -.1521374E-04 0.6414775E-02 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.6374056E-02 0.4071821E-04 -.6414775E-02 0.0000000E+00 7 Al+++ 0.7499673E+00 0.5194054E-05 0.7499621E+00 0.0000000E+00 8 H4SiO4 0.2394930E+01 0.1319930E-01 0.2381730E+01 0.0000000E+00 9 Ca++ 0.2645461E+00 0.2258724E-06 0.2645459E+00 0.0000000E+00 10 Mg++ 0.1825389E+00 0.9086654E-10 0.1825389E+00 0.0000000E+00 11 Fe++ 0.1639913E+00 0.3541833E-07 0.1639912E+00 0.0000000E+00 12 K+ 0.4883206E-01 0.1533166E-03 0.4867874E-01 0.0000000E+00 13 Na+ 0.2888648E+00 0.2174687E-01 0.2671180E+00 0.0000000E+00 14 Mn++ 0.3987860E-02 0.2375738E-08 0.3987857E-02 0.0000000E+00 15 HPO4-- 0.1361037E-02 0.4528721E-07 0.1360991E-02 0.0000000E+00 Chg. balance for solid moles: -.9515E-15 Mass of aqueous solution: 0.977066E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 229.9990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 0.2668 -0.574 69.95 1.845 27.86 26.85 andradite 0.2566E-01 -1.591 13.04 1.115 5.193 3.388 grossular 0.6223E-02 -2.206 2.803 0.448 1.116 0.7800 apatite-OH 0.4537E-03 -3.343 0.2279 -0.642 0.9076E-01 0.7241E-01 clinochlore 0.3389E-01 -1.470 18.84 1.275 7.503 7.165 daphnite 0.9808E-02 -2.008 6.998 0.845 2.787 2.121 chlorite-Mn 0.7976E-03 -3.098 0.5655 -0.248 0.2252 0.1802 diopside 0.3250E-02 -2.488 0.7039 -0.152 0.2804 0.2151 hedenbergite 0.8427E-03 -3.074 0.2091 -0.680 0.8327E-01 0.5726E-01 microcline 0.4274E-01 -1.369 11.90 1.075 4.738 4.647 stilbite 0.1571 -0.804 110.7 2.044 44.10 51.64 stilpnomelane-Fe 0.1188E-01 -1.925 12.81 1.107 5.100 4.424 tr.625ac.25prg.125 0.2712E-02 -2.567 2.318 0.365 0.9233 0.7461 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8048E+00 0.8048E+00 1.0000 -0.094 grossular 0.1952E+00 0.1952E+00 1.0000 -0.710 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.7617E+00 0.7617E+00 1.0000 -0.118 daphnite 0.2204E+00 0.2204E+00 1.0000 -0.657 chlorite-Mn 0.1792E-01 0.1792E-01 1.0000 -1.747 diopside 0.7941E+00 0.7941E+00 1.0000 -0.100 hedenbergite 0.2059E+00 0.2059E+00 1.0000 -0.686 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 tr.625ac.25prg.125 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 251.081359 g Volume = 102.291705 cm3 Porosity: -9.9916% V(tot) - V(min): -.92921E+01 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 229.9990000 g log = 2.3617 Original solution: 1000.0103000 g Original solution / Rock added: 4.35 (Water/Rock Ratio), log = 0.6383 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0544 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9681E+00 0.9855 0.1006E+01 0.1021E+01 CO2,gas 0.3271E-08 1.0069 0.3472E-08 0.3448E-08 CH4,gas 0.1744E-01 1.0125 0.1861E-01 0.1838E-01 H2,gas 0.1443E-01 1.0006 0.1522E-01 0.1521E-01 H2S,gas 0.1310E-06 0.9959 0.1376E-06 0.1382E-06 S2,gas 0.2908E-29 1.0000 0.3067E-29 0.3067E-29 CO,gas 0.1336E-13 1.0000 0.1409E-13 0.1409E-13 SO3,gas 0.6776E-48 1.0000 0.7144E-48 0.7144E-48 SO2,gas 0.4013E-27 1.0000 0.4231E-27 0.4231E-27 HCl,gas 0.2674E-17 1.0000 0.2820E-17 0.2820E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 16 albite -0.38 -0.38 0.00 0.000 -0.94784E-12 22 andradite 39.01 39.01 0.00 0.000 -0.24265E-10 23 grossular 32.73 32.73 0.00 0.000 -0.24265E-10 32 apatite-OH -18.15 -18.15 0.00 0.000 0.00000E+00 46 clinochlore 39.07 39.07 0.00 0.000 -0.36397E-10 47 daphnite 28.97 28.97 0.00 0.000 -0.36397E-10 48 chlorite-Mn 46.87 46.87 0.00 0.000 -0.24265E-10 67 diopside 16.18 16.18 0.00 0.000 -0.12132E-10 68 hedenbergite 14.21 14.21 0.00 0.000 -0.90992E-11 116 microcline -2.49 -2.49 0.00 0.000 0.15165E-11 163 stilbite -7.52 -7.52 0.00 0.000 -0.90992E-11 164 stilpnomelane-Fe 13.02 13.02 0.00 0.000 -0.27298E-10 245 tr.625ac.25prg.125 45.16 45.16 0.00 0.000 -0.60662E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -16.82 -10.16 -3.386 0.17345E+05 -8.459 3 CH4,gas 4.54 1.11 -3.43 -0.857 0.58552E+04 -1.730 4 H2,gas 8.00 4.48 -3.52 -2.009 0.60043E+04 -1.818 5 H2S,gas -6.23 -14.79 -8.56 -4.280 0.14617E+05 -6.861 6 S2,gas -7.34 -38.55 -31.21 -4.802 0.53294E+05 -29.513 7 CO,gas 3.21 -12.34 -15.55 -4.785 0.26551E+05 -13.851 8 SO3,gas 17.12 -32.72 -49.85 -12.461 0.85109E+05 -48.146 9 SO2,gas 0.83 -28.24 -29.07 -7.753 0.49641E+05 -27.374 10 HCl,gas 5.19 -14.06 -19.25 -9.624 0.32867E+05 -17.550 11 acmite 7.71 6.53 -1.18 -0.123 0.20184E+04 15 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 19 spessartine 24.46 19.68 -4.77 -0.239 0.81504E+04 20 analcite 3.32 2.77 -0.55 -0.061 0.93593E+03 26 annite 20.12 17.72 -2.40 -0.134 0.41060E+04 27 phlogopite 27.06 25.40 -1.67 -0.093 0.28479E+04 29 anorthite 12.71 8.27 -4.44 -0.342 0.75887E+04 35 aragonite 0.97 -3.72 -4.68 -1.561 0.79961E+04 36 brucite 12.57 9.29 -3.27 -0.655 0.55905E+04 37 calcite 0.81 -3.72 -4.53 -1.509 0.77318E+04 38 carnegieite-low 9.02 5.93 -3.09 -0.442 0.52795E+04 39 carnegieite-high 10.09 5.93 -4.16 -0.595 0.71065E+04 40 carpholite-Mg 8.58 4.46 -4.12 -0.275 0.70413E+04 41 carpholite-Fe 6.71 1.90 -4.81 -0.321 0.82193E+04 42 celadonite 5.34 3.65 -1.69 -0.099 0.28878E+04 43 celadonite-Fe 3.88 1.09 -2.79 -0.164 0.47563E+04 44 chrysotile 23.89 21.57 -2.32 -0.194 0.39688E+04 49 chlorite-Al-free 47.17 43.14 -4.04 -0.168 0.68927E+04 51 chloritoid-Fe 9.17 5.06 -4.12 -0.274 0.70298E+04 52 chloritoid-Mn 11.40 7.55 -3.85 -0.257 0.65801E+04 54 coesite -2.38 -3.16 -0.78 -0.261 0.13344E+04 61 cristobalite -2.56 -3.16 -0.60 -0.199 0.10198E+04 63 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71234E+04 65 diaspore 2.87 0.74 -2.13 -0.356 0.36440E+04 66 diamond -3.10 -7.85 -4.75 -1.357 0.81098E+04 71 enstatite 17.26 12.27 -4.99 -0.499 0.85225E+04 73 clinoenstatite 17.17 12.27 -4.89 -0.489 0.83541E+04 75 epidote 24.67 22.70 -1.97 -0.095 0.33572E+04 76 clinozoisite 22.81 18.95 -3.86 -0.175 0.65843E+04 77 epidote-Fe 29.84 26.46 -3.38 -0.176 0.57767E+04 78 fayalite 14.05 10.31 -3.73 -0.533 0.63744E+04 79 ferrosilite 11.15 7.15 -3.99 -0.399 0.68206E+04 83 gibbsite 4.08 0.74 -3.34 -0.477 0.57026E+04 84 glaucophane 22.97 20.80 -2.17 -0.059 0.37129E+04 85 glaucophane-Fe 17.28 13.12 -4.15 -0.112 0.70921E+04 86 graphite -3.55 -7.85 -4.31 -1.230 0.73520E+04 87 greenalite 16.14 13.89 -2.25 -0.187 0.38410E+04 90 hematite 12.57 8.99 -3.58 -0.434 0.61116E+04 91 heulandite -5.83 -7.52 -1.69 -0.077 0.28938E+04 95 jadeite 4.22 2.77 -1.44 -0.144 0.24614E+04 97 kalsilite 7.58 3.83 -3.76 -0.536 0.64119E+04 98 kaolinite -1.33 -4.84 -3.50 -0.318 0.59819E+04 101 laumontite 2.88 1.95 -0.93 -0.062 0.15926E+04 102 lawsonite 9.62 8.27 -1.35 -0.090 0.23054E+04 103 leucite 4.12 0.67 -3.45 -0.345 0.58870E+04 105 lizardite 23.24 21.57 -1.68 -0.140 0.28614E+04 107 magnetite 20.09 15.72 -4.37 -0.356 0.74540E+04 108 minnesotaite 10.39 7.57 -2.81 -0.165 0.48036E+04 112 manganosite 14.06 9.23 -4.83 -1.208 0.82509E+04 120 muscovite 2.58 -1.01 -3.59 -0.211 0.61296E+04 121 paragonite 4.24 1.10 -3.14 -0.185 0.53687E+04 122 nepheline 8.34 5.93 -2.41 -0.344 0.41118E+04 128 periclase-Fe 11.63 6.74 -4.89 -1.223 0.83522E+04 134 phlogopite-Na 29.65 27.50 -2.15 -0.119 0.36667E+04 136 prehnite 19.37 18.21 -1.16 -0.068 0.19833E+04 137 prehnite-Fe 22.50 21.96 -0.53 -0.032 0.91118E+03 138 pumpellyite-Fe 46.27 43.90 -2.37 -0.053 0.40539E+04 139 pumpellyite-Mg 48.99 46.45 -2.54 -0.056 0.43375E+04 143 pyrrhotite -4.26 -8.06 -3.80 -1.265 0.64803E+04 144 pyrrhotiteFe0.875 -6.02 -9.45 -3.44 -1.264 0.58676E+04 145 pyroxmangite 7.40 6.07 -1.33 -0.266 0.22716E+04 146 pyrophyllite -6.18 -11.15 -4.98 -0.311 0.84955E+04 147 quartz -2.99 -3.16 -0.17 -0.056 0.28712E+03 152 rhodonite 7.45 6.07 -1.38 -0.275 0.23518E+04 153 sanidine -1.28 -2.49 -1.21 -0.093 0.20677E+04 165 stilpnomelane-Mg 27.44 25.81 -1.63 -0.049 0.27792E+04 171 talc 16.49 15.25 -1.24 -0.073 0.21142E+04 174 tephroite 18.09 15.29 -2.79 -0.399 0.47666E+04 178 tridymite -2.63 -3.16 -0.53 -0.177 0.90710E+03 179 tremolite 47.87 47.42 -0.45 -0.012 0.77505E+03 180 ferroactinolite 38.45 34.62 -3.83 -0.104 0.65461E+04 181 troilite-low -4.41 -8.06 -3.64 -1.215 0.62231E+04 183 vesuvianite 223.47 218.83 -4.65 -0.035 0.79323E+04 187 wairakite 3.95 1.95 -2.00 -0.118 0.34145E+04 188 walstromite 11.51 9.94 -1.56 -0.313 0.26718E+04 189 wollastonite 10.46 9.94 -0.52 -0.103 0.88228E+03 190 pseudo-wollastonite 11.00 9.94 -1.06 -0.211 0.18021E+04 191 zoisite 22.85 18.95 -3.90 -0.177 0.66584E+04 192 akaganeite 7.75 4.49 -3.26 -0.705 0.55683E+04 199 chalcedony -2.80 -3.16 -0.36 -0.118 0.60642E+03 201 montmorillonite-Ca -2.29 -6.17 -3.88 -0.240 0.66176E+04 202 montmorillonite-K -2.24 -6.27 -4.03 -0.247 0.68812E+04 203 montmorillonite-Mg -2.48 -6.79 -4.31 -0.267 0.73673E+04 204 montmorillonite-Na -2.04 -5.57 -3.54 -0.216 0.60361E+04 205 nontronite-Ca 3.21 -0.20 -3.41 -0.221 0.58228E+04 206 nontronite-H 2.53 -2.36 -4.89 -0.328 0.83498E+04 207 nontronite-K 3.34 -0.30 -3.64 -0.233 0.62096E+04 208 nontronite-Mg 3.07 -0.82 -3.90 -0.253 0.66566E+04 209 nontronite-Na 3.52 0.40 -3.12 -0.200 0.53305E+04 224 tobermorite 9.82 7.76 -2.07 -0.564 0.35288E+04 230 alabandite -0.98 -5.56 -4.59 -1.529 0.78320E+04 233 boehmite 4.41 0.74 -3.67 -0.611 0.62610E+04 235 ferrous-oxide 9.81 6.74 -3.08 -0.769 0.52531E+04 240 silica-amorphous -2.09 -3.16 -1.07 -0.355 0.18206E+04 242 an20ab80 2.02 1.35 -0.67 -0.052 0.11469E+04 243 an25ab75 2.65 1.78 -0.87 -0.067 0.14806E+04 244 an30ab70 3.28 2.21 -1.07 -0.082 0.18239E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 10.0000000 g Current total amount of reactant added: 229.9990000 g New total amount of reactant added: 239.9990000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.3651E-11 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 11 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 239.9990000 Water: Moles liquid = 0.5409E+02 kg liquid = 0.9744E+00 Moles total = 0.5250E+02 kg total = 0.9458E+00 Activity = 1.0000 Stoichiometric ionic strength = .1131920E-01 Osmotic coef. = 0.9695 True ionic strength = .2000835E-01 Chg. balance for total moles = 0.3651E-11 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.88249E-10 -10.0543 0.74154E-10 -10.1299 0.84028E+00 -0.0756 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.14096E-03 -3.8509 0.11773E-03 -3.9291 0.83523E+00 -0.0782 4 SO4-- 0.66239E-12 -12.1789 0.34403E-12 -12.4634 0.51937E+00 -0.2845 5 HCO3- 0.24517E-06 -6.6105 0.20507E-06 -6.6881 0.83645E+00 -0.0776 6 HS- 0.26170E-04 -4.5822 0.21861E-04 -4.6603 0.83535E+00 -0.0781 7 Al+++ 0.96850E-29 -29.0139 0.22382E-29 -29.6501 0.23110E+00 -0.6362 8 H4SiO4 0.69569E-03 -3.1576 0.69569E-03 -3.1576 0.10000E+01 0.0000 9 Ca++ 0.13489E-06 -6.8700 0.69547E-07 -7.1577 0.51556E+00 -0.2877 10 Mg++ 0.21104E-10 -10.6756 0.10831E-10 -10.9653 0.51321E+00 -0.2897 11 Fe++ 0.58149E-13 -13.2355 0.29875E-13 -13.5247 0.51377E+00 -0.2892 12 K+ 0.15644E-03 -3.8057 0.13088E-03 -3.8831 0.83665E+00 -0.0775 13 Na+ 0.19851E-01 -1.7022 0.16577E-01 -1.7805 0.83508E+00 -0.0783 14 Mn++ 0.18018E-10 -10.7443 0.92647E-11 -11.0332 0.51419E+00 -0.2889 15 HPO4-- 0.45326E-07 -7.3437 0.23544E-07 -7.6281 0.51945E+00 -0.2845 16 HSiO3- 0.10488E-01 -1.9793 0.87602E-02 -2.0575 0.83523E+00 -0.0782 17 Ca(HSiO3)+ 0.16580E-07 -7.7804 0.13875E-07 -7.8578 0.83683E+00 -0.0774 18 Mg(HSiO3)+ 0.32134E-11 -11.4930 0.26891E-11 -11.5704 0.83683E+00 -0.0774 19 NaHSiO3,aq 0.23487E-02 -2.6292 0.23487E-02 -2.6292 0.10000E+01 0.0000 20 AlO+ 0.66172E-16 -16.1793 0.55375E-16 -16.2567 0.83683E+00 -0.0774 22 HAlO2,aq 0.14871E-09 -9.8276 0.14871E-09 -9.8276 0.10000E+01 0.0000 23 AlO2- 0.53247E-05 -5.2737 0.44393E-05 -5.3527 0.83372E+00 -0.0790 24 CH4,aq 0.12702E-04 -4.8961 0.12659E-04 -4.8976 0.99655E+00 -0.0015 25 C2H6,aq 0.23710E-14 -14.6251 0.23628E-14 -14.6266 0.99655E+00 -0.0015 29 CO,aq 0.94635E-17 -17.0239 0.94635E-17 -17.0239 0.10000E+01 0.0000 30 CO2,aq 0.32606E-10 -10.4867 0.32494E-10 -10.4882 0.99655E+00 -0.0015 31 CO3-2 0.46608E-06 -6.3315 0.24156E-06 -6.6170 0.51827E+00 -0.2854 32 CaCO3,aq 0.21065E-09 -9.6764 0.21065E-09 -9.6764 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.43504E-12 -12.3615 0.36405E-12 -12.4388 0.83683E+00 -0.0774 34 CaCl+ 0.15834E-10 -10.8004 0.13250E-10 -10.8778 0.83683E+00 -0.0774 35 CaCl2,aq 0.37062E-15 -15.4311 0.37062E-15 -15.4311 0.10000E+01 0.0000 36 CaOH+ 0.79875E-07 -7.0976 0.66842E-07 -7.1750 0.83683E+00 -0.0774 37 CaSO4,aq 0.75976E-17 -17.1193 0.75976E-17 -17.1193 0.10000E+01 0.0000 38 HCl,aq 0.15998E-14 -14.7959 0.15998E-14 -14.7959 0.10000E+01 0.0000 43 FeCl+ 0.66528E-17 -17.1770 0.55672E-17 -17.2544 0.83683E+00 -0.0774 46 FeO,aq 0.21116E-09 -9.6754 0.21116E-09 -9.6754 0.10000E+01 0.0000 47 FeOH+ 0.15671E-10 -10.8049 0.13114E-10 -10.8823 0.83683E+00 -0.0774 48 HFeO2- 0.35673E-07 -7.4477 0.29795E-07 -7.5259 0.83523E+00 -0.0782 49 FeO+ 0.10978E-16 -16.9595 0.91867E-17 -17.0368 0.83683E+00 -0.0774 51 FeO2- 0.40930E-09 -9.3880 0.34186E-09 -9.4662 0.83523E+00 -0.0782 52 HFeO2,aq 0.32241E-11 -11.4916 0.32241E-11 -11.4916 0.10000E+01 0.0000 53 H2,aq 0.11634E-04 -4.9343 0.11594E-04 -4.9358 0.99655E+00 -0.0015 54 KCl,aq 0.27927E-09 -9.5540 0.27927E-09 -9.5540 0.10000E+01 0.0000 56 KOH,aq 0.75376E-06 -6.1228 0.75376E-06 -6.1228 0.10000E+01 0.0000 57 KSO4- 0.83655E-15 -15.0775 0.69871E-15 -15.1557 0.83523E+00 -0.0782 58 MgCO3,aq 0.82227E-14 -14.0850 0.82227E-14 -14.0850 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.69229E-16 -16.1597 0.57932E-16 -16.2371 0.83683E+00 -0.0774 60 MgCl+ 0.22350E-14 -14.6507 0.18703E-14 -14.7281 0.83683E+00 -0.0774 61 MgOH+ 0.68833E-10 -10.1622 0.57601E-10 -10.2396 0.83683E+00 -0.0774 63 MnO,aq 0.17449E-08 -8.7582 0.17449E-08 -8.7582 0.10000E+01 0.0000 64 MnOH+ 0.45147E-09 -9.3454 0.37780E-09 -9.4227 0.83683E+00 -0.0774 65 MnO2-2 0.20319E-10 -10.6921 0.10531E-10 -10.9775 0.51827E+00 -0.2854 66 HMnO2- 0.20484E-09 -9.6886 0.17108E-09 -9.7668 0.83523E+00 -0.0782 69 MnCl+ 0.80265E-14 -14.0955 0.67168E-14 -14.1728 0.83683E+00 -0.0774 71 NaCl,aq 0.64677E-06 -6.1892 0.64677E-06 -6.1892 0.10000E+01 0.0000 72 NaOH,aq 0.96048E-04 -4.0175 0.96048E-04 -4.0175 0.10000E+01 0.0000 74 OH- 0.93456E-02 -2.0294 0.77916E-02 -2.1084 0.83372E+00 -0.0790 79 HPO3-2 0.16413E-14 -14.7848 0.85065E-15 -15.0702 0.51827E+00 -0.2854 81 H2PO3- 0.15145E-18 -18.8197 0.12649E-18 -18.8979 0.83523E+00 -0.0782 82 H3PO4,aq 0.90547E-18 -18.0431 0.90547E-18 -18.0431 0.10000E+01 0.0000 83 H2PO4- 0.38524E-10 -10.4143 0.32207E-10 -10.4920 0.83602E+00 -0.0778 84 PO4-3 0.10673E-08 -8.9717 0.25905E-09 -9.5866 0.24272E+00 -0.6149 88 HP2O7-3 0.94675E-18 -18.0238 0.21901E-18 -18.6595 0.23133E+00 -0.6358 89 P2O7-4 0.91459E-17 -17.0388 0.70558E-18 -18.1515 0.77148E-01 -1.1127 90 H2S,aq 0.50276E-08 -8.2986 0.50102E-08 -8.3001 0.99655E+00 -0.0015 91 S2-2 0.17624E-14 -14.7539 0.91342E-15 -15.0393 0.51827E+00 -0.2854 97 SO3-2 0.98582E-18 -18.0062 0.51831E-18 -18.2854 0.52577E+00 -0.2792 99 HSO4- 0.29351E-19 -19.5324 0.24585E-19 -19.6093 0.83764E+00 -0.0769 Charge balance for all species = 0.3746E-11 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.8824901E-10 -.2230431E-01 -.2244236E+02 0.0000 2 H2O 0.1000000E+01 0.5550489E+02 0.9982003E+06 0.0000 3 Cl- 0.1409572E-03 0.1416043E-03 0.5011575E+01 6.2008 4 SO4-- 0.6623878E-12 -.1561078E-04 -.1496992E+01 7.7963 5 HCO3- 0.2451711E-06 0.1341387E-04 0.8170550E+00 3.4418 6 HS- 0.2617046E-04 0.4178627E-04 0.1379555E+01 5.4695 7 Al+++ 0.9684955E-29 0.5324888E-05 0.1434239E+00 0.7395 8 H4SiO4 0.6956945E-03 0.1353278E-01 0.1298449E+04 -3.1576 9 Ca++ 0.1348942E-06 0.2315764E-06 0.9264998E-02 13.1020 10 Mg++ 0.2110404E-10 0.9316057E-10 0.2260985E-05 9.2944 11 Fe++ 0.5814938E-13 0.3631219E-07 0.2024404E-02 6.7350 12 K+ 0.1564358E-03 0.1571898E-03 0.6135761E+01 6.2467 13 Na+ 0.1985090E-01 0.2229628E-01 0.5116967E+03 8.3494 14 Mn++ 0.1801796E-10 0.2439512E-08 0.1337891E-03 9.2266 15 HPO4-- 0.4532571E-07 0.4643154E-07 0.4448711E-02 12.6316 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.3974014E+01 -.2173253E-01 -.3952282E+01 0.0000000E+00 2 H2O 0.5249976E+02 0.5408200E+02 -.1582237E+01 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.6676695E-02 -.1521059E-04 0.6691905E-02 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.6651190E-02 0.4071506E-04 -.6691905E-02 0.0000000E+00 7 Al+++ 0.7825747E+00 0.5188382E-05 0.7825695E+00 0.0000000E+00 8 H4SiO4 0.2499057E+01 0.1318586E-01 0.2485872E+01 0.0000000E+00 9 Ca++ 0.2760476E+00 0.2256399E-06 0.2760473E+00 0.0000000E+00 10 Mg++ 0.1904754E+00 0.9077236E-10 0.1904754E+00 0.0000000E+00 11 Fe++ 0.1711213E+00 0.3538131E-07 0.1711213E+00 0.0000000E+00 12 K+ 0.5095520E-01 0.1531602E-03 0.5080204E-01 0.0000000E+00 13 Na+ 0.3014173E+00 0.2172471E-01 0.2796926E+00 0.0000000E+00 14 Mn++ 0.4161246E-02 0.2376974E-08 0.4161243E-02 0.0000000E+00 15 HPO4-- 0.1420212E-02 0.4524125E-07 0.1420167E-02 0.0000000E+00 Chg. balance for solid moles: 0.2572E-15 Mass of aqueous solution: 0.976060E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 239.9990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 0.2793 -0.554 73.25 1.865 27.96 28.12 andradite 0.2677E-01 -1.572 13.60 1.134 5.192 3.534 grossular 0.6491E-02 -2.188 2.924 0.466 1.116 0.8136 apatite-OH 0.4734E-03 -3.325 0.2378 -0.624 0.9076E-01 0.7556E-01 clinochlore 0.3531E-01 -1.452 19.63 1.293 7.491 7.465 daphnite 0.1022E-01 -1.991 7.291 0.863 2.783 2.209 chlorite-Mn 0.8322E-03 -3.080 0.5900 -0.229 0.2252 0.1880 diopside 0.3794E-02 -2.421 0.8217 -0.085 0.3136 0.2511 hedenbergite 0.9837E-03 -3.007 0.2441 -0.613 0.9315E-01 0.6685E-01 microcline 0.4460E-01 -1.351 12.41 1.094 4.738 4.849 stilbite 0.1635 -0.786 115.2 2.062 43.99 53.75 stilpnomelane-Fe 0.1240E-01 -1.906 13.37 1.126 5.103 4.618 tr.625ac.25prg.125 0.2796E-02 -2.554 2.390 0.378 0.9120 0.7691 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8048E+00 0.8048E+00 1.0000 -0.094 grossular 0.1952E+00 0.1952E+00 1.0000 -0.710 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.7616E+00 0.7616E+00 1.0000 -0.118 daphnite 0.2204E+00 0.2204E+00 1.0000 -0.657 chlorite-Mn 0.1795E-01 0.1795E-01 1.0000 -1.746 diopside 0.7941E+00 0.7941E+00 1.0000 -0.100 hedenbergite 0.2059E+00 0.2059E+00 1.0000 -0.686 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 tr.625ac.25prg.125 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 262.006416 g Volume = 106.712011 cm3 Porosity: -10.0128% V(tot) - V(min): -.97124E+01 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 239.9990000 g log = 2.3802 Original solution: 1000.0103000 g Original solution / Rock added: 4.17 (Water/Rock Ratio), log = 0.6198 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0544 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9681E+00 0.9855 0.1006E+01 0.1021E+01 CO2,gas 0.3274E-08 1.0069 0.3476E-08 0.3453E-08 CH4,gas 0.1745E-01 1.0125 0.1863E-01 0.1840E-01 H2,gas 0.1443E-01 1.0006 0.1522E-01 0.1521E-01 H2S,gas 0.1312E-06 0.9959 0.1377E-06 0.1383E-06 S2,gas 0.2915E-29 1.0000 0.3073E-29 0.3073E-29 CO,gas 0.1338E-13 1.0000 0.1410E-13 0.1410E-13 SO3,gas 0.6784E-48 1.0000 0.7153E-48 0.7153E-48 SO2,gas 0.4017E-27 1.0000 0.4236E-27 0.4236E-27 HCl,gas 0.2677E-17 1.0000 0.2823E-17 0.2823E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 16 albite -0.38 -0.38 0.00 0.000 0.11184E-10 22 andradite 39.01 39.01 0.00 0.000 0.00000E+00 23 grossular 32.73 32.73 0.00 0.000 0.24265E-10 32 apatite-OH -18.15 -18.15 0.00 0.000 0.00000E+00 46 clinochlore 39.07 39.07 0.00 0.000 0.48529E-10 47 daphnite 28.97 28.97 0.00 0.000 -0.60662E-11 48 chlorite-Mn 46.87 46.87 0.00 0.000 0.36397E-10 67 diopside 16.18 16.18 0.00 0.000 0.12132E-10 68 hedenbergite 14.21 14.21 0.00 0.000 0.00000E+00 116 microcline -2.49 -2.49 0.00 0.000 0.15165E-11 163 stilbite -7.52 -7.52 0.00 0.000 -0.90992E-11 164 stilpnomelane-Fe 13.02 13.02 0.00 0.000 0.21232E-10 245 tr.625ac.25prg.125 45.16 45.16 0.00 0.000 -0.24265E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -16.82 -10.16 -3.386 0.17344E+05 -8.459 3 CH4,gas 4.54 1.11 -3.43 -0.857 0.58544E+04 -1.730 4 H2,gas 8.00 4.48 -3.52 -2.009 0.60044E+04 -1.818 5 H2S,gas -6.23 -14.79 -8.56 -4.280 0.14616E+05 -6.861 6 S2,gas -7.34 -38.55 -31.21 -4.802 0.53293E+05 -29.512 7 CO,gas 3.21 -12.33 -15.55 -4.785 0.26551E+05 -13.851 8 SO3,gas 17.12 -32.72 -49.84 -12.461 0.85108E+05 -48.146 9 SO2,gas 0.83 -28.24 -29.07 -7.753 0.49640E+05 -27.373 10 HCl,gas 5.19 -14.06 -19.25 -9.624 0.32866E+05 -17.549 11 acmite 7.71 6.53 -1.18 -0.123 0.20184E+04 15 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 19 spessartine 24.46 19.69 -4.77 -0.239 0.81470E+04 20 analcite 3.32 2.77 -0.55 -0.061 0.93595E+03 26 annite 20.12 17.72 -2.40 -0.134 0.41060E+04 27 phlogopite 27.06 25.40 -1.67 -0.093 0.28479E+04 29 anorthite 12.71 8.27 -4.44 -0.342 0.75888E+04 35 aragonite 0.97 -3.72 -4.68 -1.561 0.79952E+04 36 brucite 12.57 9.29 -3.27 -0.655 0.55906E+04 37 calcite 0.81 -3.72 -4.53 -1.509 0.77310E+04 38 carnegieite-low 9.02 5.93 -3.09 -0.442 0.52795E+04 39 carnegieite-high 10.09 5.93 -4.16 -0.595 0.71065E+04 40 carpholite-Mg 8.58 4.46 -4.12 -0.275 0.70414E+04 41 carpholite-Fe 6.71 1.90 -4.81 -0.321 0.82193E+04 42 celadonite 5.34 3.65 -1.69 -0.099 0.28878E+04 43 celadonite-Fe 3.88 1.09 -2.79 -0.164 0.47563E+04 44 chrysotile 23.89 21.57 -2.32 -0.194 0.39688E+04 49 chlorite-Al-free 47.17 43.14 -4.04 -0.168 0.68928E+04 51 chloritoid-Fe 9.17 5.06 -4.12 -0.274 0.70299E+04 52 chloritoid-Mn 11.40 7.55 -3.85 -0.257 0.65790E+04 54 coesite -2.38 -3.16 -0.78 -0.261 0.13344E+04 61 cristobalite -2.56 -3.16 -0.60 -0.199 0.10198E+04 63 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71234E+04 65 diaspore 2.87 0.74 -2.13 -0.356 0.36441E+04 66 diamond -3.10 -7.85 -4.75 -1.357 0.81089E+04 71 enstatite 17.26 12.27 -4.99 -0.499 0.85225E+04 73 clinoenstatite 17.17 12.27 -4.89 -0.489 0.83541E+04 75 epidote 24.67 22.70 -1.97 -0.095 0.33572E+04 76 clinozoisite 22.81 18.95 -3.86 -0.175 0.65844E+04 77 epidote-Fe 29.84 26.46 -3.38 -0.176 0.57767E+04 78 fayalite 14.05 10.31 -3.73 -0.533 0.63744E+04 79 ferrosilite 11.15 7.15 -3.99 -0.399 0.68205E+04 83 gibbsite 4.08 0.74 -3.34 -0.477 0.57026E+04 84 glaucophane 22.97 20.80 -2.17 -0.059 0.37129E+04 85 glaucophane-Fe 17.28 13.12 -4.15 -0.112 0.70921E+04 86 graphite -3.55 -7.85 -4.31 -1.230 0.73512E+04 87 greenalite 16.14 13.89 -2.25 -0.187 0.38410E+04 90 hematite 12.57 8.99 -3.58 -0.434 0.61116E+04 91 heulandite -5.83 -7.52 -1.69 -0.077 0.28938E+04 95 jadeite 4.22 2.77 -1.44 -0.144 0.24614E+04 97 kalsilite 7.58 3.83 -3.76 -0.536 0.64120E+04 98 kaolinite -1.33 -4.84 -3.50 -0.318 0.59819E+04 101 laumontite 2.88 1.95 -0.93 -0.062 0.15926E+04 102 lawsonite 9.62 8.27 -1.35 -0.090 0.23055E+04 103 leucite 4.12 0.67 -3.45 -0.345 0.58870E+04 105 lizardite 23.24 21.57 -1.68 -0.140 0.28614E+04 107 magnetite 20.09 15.72 -4.37 -0.356 0.74539E+04 108 minnesotaite 10.39 7.57 -2.81 -0.165 0.48036E+04 112 manganosite 14.06 9.23 -4.83 -1.208 0.82497E+04 120 muscovite 2.58 -1.01 -3.59 -0.211 0.61297E+04 121 paragonite 4.24 1.10 -3.14 -0.185 0.53688E+04 122 nepheline 8.34 5.93 -2.41 -0.344 0.41119E+04 128 periclase-Fe 11.63 6.74 -4.89 -1.223 0.83522E+04 134 phlogopite-Na 29.65 27.50 -2.15 -0.119 0.36667E+04 136 prehnite 19.37 18.21 -1.16 -0.068 0.19834E+04 137 prehnite-Fe 22.50 21.96 -0.53 -0.032 0.91120E+03 138 pumpellyite-Fe 46.27 43.90 -2.37 -0.053 0.40541E+04 139 pumpellyite-Mg 48.99 46.45 -2.54 -0.056 0.43377E+04 143 pyrrhotite -4.26 -8.06 -3.79 -1.265 0.64796E+04 144 pyrrhotiteFe0.875 -6.02 -9.45 -3.44 -1.264 0.58669E+04 145 pyroxmangite 7.40 6.07 -1.33 -0.266 0.22704E+04 146 pyrophyllite -6.18 -11.15 -4.98 -0.311 0.84956E+04 147 quartz -2.99 -3.16 -0.17 -0.056 0.28710E+03 152 rhodonite 7.45 6.07 -1.38 -0.275 0.23507E+04 153 sanidine -1.28 -2.49 -1.21 -0.093 0.20677E+04 165 stilpnomelane-Mg 27.44 25.81 -1.63 -0.049 0.27793E+04 171 talc 16.49 15.25 -1.24 -0.073 0.21142E+04 174 tephroite 18.09 15.30 -2.79 -0.399 0.47643E+04 178 tridymite -2.63 -3.16 -0.53 -0.177 0.90708E+03 179 tremolite 47.87 47.42 -0.45 -0.012 0.77504E+03 180 ferroactinolite 38.45 34.62 -3.83 -0.104 0.65460E+04 181 troilite-low -4.41 -8.06 -3.64 -1.215 0.62224E+04 183 vesuvianite 223.47 218.83 -4.65 -0.035 0.79327E+04 187 wairakite 3.95 1.95 -2.00 -0.118 0.34146E+04 188 walstromite 11.51 9.94 -1.56 -0.313 0.26718E+04 189 wollastonite 10.46 9.94 -0.52 -0.103 0.88228E+03 190 pseudo-wollastonite 11.00 9.94 -1.06 -0.211 0.18021E+04 191 zoisite 22.85 18.95 -3.90 -0.177 0.66585E+04 192 akaganeite 7.75 4.49 -3.26 -0.705 0.55683E+04 199 chalcedony -2.80 -3.16 -0.36 -0.118 0.60640E+03 201 montmorillonite-Ca -2.29 -6.17 -3.88 -0.240 0.66176E+04 202 montmorillonite-K -2.24 -6.27 -4.03 -0.247 0.68812E+04 203 montmorillonite-Mg -2.48 -6.79 -4.31 -0.267 0.73673E+04 204 montmorillonite-Na -2.04 -5.57 -3.54 -0.216 0.60361E+04 205 nontronite-Ca 3.21 -0.20 -3.41 -0.221 0.58227E+04 206 nontronite-H 2.53 -2.36 -4.89 -0.328 0.83498E+04 207 nontronite-K 3.34 -0.30 -3.64 -0.233 0.62096E+04 208 nontronite-Mg 3.07 -0.82 -3.90 -0.253 0.66565E+04 209 nontronite-Na 3.52 0.40 -3.12 -0.200 0.53304E+04 224 tobermorite 9.82 7.76 -2.07 -0.564 0.35288E+04 230 alabandite -0.98 -5.56 -4.59 -1.529 0.78300E+04 233 boehmite 4.41 0.74 -3.67 -0.611 0.62610E+04 235 ferrous-oxide 9.81 6.74 -3.08 -0.769 0.52531E+04 240 silica-amorphous -2.09 -3.16 -1.07 -0.355 0.18206E+04 242 an20ab80 2.02 1.35 -0.67 -0.052 0.11469E+04 243 an25ab75 2.65 1.78 -0.87 -0.067 0.14806E+04 244 an30ab70 3.28 2.21 -1.07 -0.082 0.18239E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 10.0000000 g Current total amount of reactant added: 239.9990000 g New total amount of reactant added: 249.9990000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.3651E-11 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 11 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 249.9990000 Water: Moles liquid = 0.5403E+02 kg liquid = 0.9734E+00 Moles total = 0.5237E+02 kg total = 0.9435E+00 Activity = 1.0000 Stoichiometric ionic strength = .1131938E-01 Osmotic coef. = 0.9695 True ionic strength = .2000854E-01 Chg. balance for total moles = 0.3651E-11 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.88250E-10 -10.0543 0.74154E-10 -10.1299 0.84028E+00 -0.0756 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.14110E-03 -3.8505 0.11785E-03 -3.9287 0.83523E+00 -0.0782 4 SO4-- 0.66317E-12 -12.1784 0.34443E-12 -12.4629 0.51937E+00 -0.2845 5 HCO3- 0.24546E-06 -6.6100 0.20531E-06 -6.6876 0.83645E+00 -0.0776 6 HS- 0.26197E-04 -4.5817 0.21884E-04 -4.6599 0.83535E+00 -0.0781 7 Al+++ 0.96848E-29 -29.0139 0.22381E-29 -29.6501 0.23110E+00 -0.6362 8 H4SiO4 0.69571E-03 -3.1576 0.69571E-03 -3.1576 0.10000E+01 0.0000 9 Ca++ 0.13489E-06 -6.8700 0.69547E-07 -7.1577 0.51556E+00 -0.2877 10 Mg++ 0.21104E-10 -10.6756 0.10831E-10 -10.9653 0.51321E+00 -0.2897 11 Fe++ 0.58150E-13 -13.2354 0.29876E-13 -13.5247 0.51377E+00 -0.2892 12 K+ 0.15644E-03 -3.8057 0.13088E-03 -3.8831 0.83665E+00 -0.0775 13 Na+ 0.19851E-01 -1.7022 0.16577E-01 -1.7805 0.83507E+00 -0.0783 14 Mn++ 0.18044E-10 -10.7437 0.92781E-11 -11.0325 0.51419E+00 -0.2889 15 HPO4-- 0.45326E-07 -7.3436 0.23545E-07 -7.6281 0.51945E+00 -0.2845 16 HSiO3- 0.10488E-01 -1.9793 0.87602E-02 -2.0575 0.83523E+00 -0.0782 17 Ca(HSiO3)+ 0.16580E-07 -7.7804 0.13875E-07 -7.8578 0.83683E+00 -0.0774 18 Mg(HSiO3)+ 0.32135E-11 -11.4930 0.26891E-11 -11.5704 0.83683E+00 -0.0774 19 NaHSiO3,aq 0.23487E-02 -2.6292 0.23487E-02 -2.6292 0.10000E+01 0.0000 20 AlO+ 0.66170E-16 -16.1793 0.55372E-16 -16.2567 0.83683E+00 -0.0774 22 HAlO2,aq 0.14871E-09 -9.8277 0.14871E-09 -9.8277 0.10000E+01 0.0000 23 AlO2- 0.53244E-05 -5.2737 0.44391E-05 -5.3527 0.83372E+00 -0.0790 24 CH4,aq 0.12715E-04 -4.8957 0.12671E-04 -4.8972 0.99655E+00 -0.0015 25 C2H6,aq 0.23759E-14 -14.6242 0.23677E-14 -14.6257 0.99655E+00 -0.0015 29 CO,aq 0.94743E-17 -17.0235 0.94743E-17 -17.0235 0.10000E+01 0.0000 30 CO2,aq 0.32645E-10 -10.4862 0.32532E-10 -10.4877 0.99655E+00 -0.0015 31 CO3-2 0.46662E-06 -6.3310 0.24184E-06 -6.6165 0.51827E+00 -0.2854 32 CaCO3,aq 0.21089E-09 -9.6759 0.21089E-09 -9.6759 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.43555E-12 -12.3610 0.36448E-12 -12.4383 0.83683E+00 -0.0774 34 CaCl+ 0.15851E-10 -10.8000 0.13264E-10 -10.8773 0.83683E+00 -0.0774 35 CaCl2,aq 0.37139E-15 -15.4302 0.37139E-15 -15.4302 0.10000E+01 0.0000 36 CaOH+ 0.79875E-07 -7.0976 0.66841E-07 -7.1750 0.83683E+00 -0.0774 37 CaSO4,aq 0.76066E-17 -17.1188 0.76066E-17 -17.1188 0.10000E+01 0.0000 38 HCl,aq 0.16014E-14 -14.7955 0.16014E-14 -14.7955 0.10000E+01 0.0000 43 FeCl+ 0.66597E-17 -17.1765 0.55730E-17 -17.2539 0.83683E+00 -0.0774 46 FeO,aq 0.21116E-09 -9.6754 0.21116E-09 -9.6754 0.10000E+01 0.0000 47 FeOH+ 0.15672E-10 -10.8049 0.13114E-10 -10.8823 0.83683E+00 -0.0774 48 HFeO2- 0.35672E-07 -7.4477 0.29794E-07 -7.5259 0.83523E+00 -0.0782 49 FeO+ 0.10978E-16 -16.9595 0.91869E-17 -17.0368 0.83683E+00 -0.0774 51 FeO2- 0.40930E-09 -9.3880 0.34186E-09 -9.4662 0.83523E+00 -0.0782 52 HFeO2,aq 0.32242E-11 -11.4916 0.32242E-11 -11.4916 0.10000E+01 0.0000 53 H2,aq 0.11633E-04 -4.9343 0.11593E-04 -4.9358 0.99655E+00 -0.0015 54 KCl,aq 0.27956E-09 -9.5535 0.27956E-09 -9.5535 0.10000E+01 0.0000 56 KOH,aq 0.75376E-06 -6.1228 0.75376E-06 -6.1228 0.10000E+01 0.0000 57 KSO4- 0.83754E-15 -15.0770 0.69954E-15 -15.1552 0.83523E+00 -0.0782 58 MgCO3,aq 0.82323E-14 -14.0845 0.82323E-14 -14.0845 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.69310E-16 -16.1592 0.58000E-16 -16.2366 0.83683E+00 -0.0774 60 MgCl+ 0.22373E-14 -14.6503 0.18722E-14 -14.7276 0.83683E+00 -0.0774 61 MgOH+ 0.68832E-10 -10.1622 0.57600E-10 -10.2396 0.83683E+00 -0.0774 63 MnO,aq 0.17474E-08 -8.7576 0.17474E-08 -8.7576 0.10000E+01 0.0000 64 MnOH+ 0.45212E-09 -9.3447 0.37835E-09 -9.4221 0.83683E+00 -0.0774 65 MnO2-2 0.20348E-10 -10.6915 0.10546E-10 -10.9769 0.51827E+00 -0.2854 66 HMnO2- 0.20513E-09 -9.6880 0.17133E-09 -9.7662 0.83523E+00 -0.0782 69 MnCl+ 0.80464E-14 -14.0944 0.67334E-14 -14.1718 0.83683E+00 -0.0774 71 NaCl,aq 0.64745E-06 -6.1888 0.64745E-06 -6.1888 0.10000E+01 0.0000 72 NaOH,aq 0.96048E-04 -4.0175 0.96048E-04 -4.0175 0.10000E+01 0.0000 74 OH- 0.93455E-02 -2.0294 0.77915E-02 -2.1084 0.83372E+00 -0.0790 79 HPO3-2 0.16413E-14 -14.7848 0.85063E-15 -15.0703 0.51827E+00 -0.2854 81 H2PO3- 0.15144E-18 -18.8197 0.12649E-18 -18.8979 0.83523E+00 -0.0782 82 H3PO4,aq 0.90550E-18 -18.0431 0.90550E-18 -18.0431 0.10000E+01 0.0000 83 H2PO4- 0.38525E-10 -10.4143 0.32208E-10 -10.4920 0.83602E+00 -0.0778 84 PO4-3 0.10673E-08 -8.9717 0.25905E-09 -9.5866 0.24272E+00 -0.6149 88 HP2O7-3 0.94678E-18 -18.0237 0.21902E-18 -18.6595 0.23133E+00 -0.6358 89 P2O7-4 0.91461E-17 -17.0388 0.70560E-18 -18.1514 0.77147E-01 -1.1127 90 H2S,aq 0.50328E-08 -8.2982 0.50154E-08 -8.2997 0.99655E+00 -0.0015 91 S2-2 0.17661E-14 -14.7530 0.91534E-15 -15.0384 0.51827E+00 -0.2854 97 SO3-2 0.98694E-18 -18.0057 0.51890E-18 -18.2849 0.52576E+00 -0.2792 99 HSO4- 0.29386E-19 -19.5319 0.24614E-19 -19.6088 0.83764E+00 -0.0769 Charge balance for all species = 0.3750E-11 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.8824984E-10 -.2230436E-01 -.2244241E+02 0.0000 2 H2O 0.1000000E+01 0.5550489E+02 0.9982003E+06 0.0000 3 Cl- 0.1411026E-03 0.1417504E-03 0.5016746E+01 6.2012 4 SO4-- 0.6631701E-12 -.1562368E-04 -.1498228E+01 7.7968 5 HCO3- 0.2454585E-06 0.1342771E-04 0.8178980E+00 3.4423 6 HS- 0.2619746E-04 0.4182617E-04 0.1380872E+01 5.4700 7 Al+++ 0.9684784E-29 0.5324579E-05 0.1434156E+00 0.7395 8 H4SiO4 0.6957061E-03 0.1353292E-01 0.1298463E+04 -3.1576 9 Ca++ 0.1348946E-06 0.2315766E-06 0.9265006E-02 13.1020 10 Mg++ 0.2110408E-10 0.9315996E-10 0.2260971E-05 9.2944 11 Fe++ 0.5815016E-13 0.3631165E-07 0.2024374E-02 6.7350 12 K+ 0.1564373E-03 0.1571913E-03 0.6135817E+01 6.2467 13 Na+ 0.1985108E-01 0.2229651E-01 0.5117018E+03 8.3494 14 Mn++ 0.1804406E-10 0.2442999E-08 0.1339803E-03 9.2272 15 HPO4-- 0.4532631E-07 0.4643214E-07 0.4448769E-02 12.6316 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.4139599E+01 -.2171018E-01 -.4117889E+01 0.0000000E+00 2 H2O 0.5237441E+02 0.5402626E+02 -.1651849E+01 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.6953829E-02 -.1520747E-04 0.6969036E-02 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.6928325E-02 0.4071194E-04 -.6969036E-02 0.0000000E+00 7 Al+++ 0.8151821E+00 0.5182734E-05 0.8151770E+00 0.0000000E+00 8 H4SiO4 0.2603185E+01 0.1317241E-01 0.2590013E+01 0.0000000E+00 9 Ca++ 0.2875490E+00 0.2254075E-06 0.2875488E+00 0.0000000E+00 10 Mg++ 0.1984119E+00 0.9067821E-10 0.1984119E+00 0.0000000E+00 11 Fe++ 0.1782514E+00 0.3534432E-07 0.1782514E+00 0.0000000E+00 12 K+ 0.5307834E-01 0.1530038E-03 0.5292534E-01 0.0000000E+00 13 Na+ 0.3139697E+00 0.2170253E-01 0.2922672E+00 0.0000000E+00 14 Mn++ 0.4334632E-02 0.2377919E-08 0.4334629E-02 0.0000000E+00 15 HPO4-- 0.1479388E-02 0.4519520E-07 0.1479343E-02 0.0000000E+00 Chg. balance for solid moles: 0.1435E-14 Mass of aqueous solution: 0.975054E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 249.9990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 0.2919 -0.535 76.54 1.884 28.05 29.38 andradite 0.2788E-01 -1.555 14.17 1.151 5.190 3.680 grossular 0.6760E-02 -2.170 3.045 0.484 1.116 0.8472 apatite-OH 0.4931E-03 -3.307 0.2477 -0.606 0.9076E-01 0.7871E-01 clinochlore 0.3673E-01 -1.435 20.41 1.310 7.480 7.765 daphnite 0.1063E-01 -1.973 7.584 0.880 2.779 2.298 chlorite-Mn 0.8669E-03 -3.062 0.6146 -0.211 0.2252 0.1959 diopside 0.4338E-02 -2.363 0.9395 -0.027 0.3442 0.2871 hedenbergite 0.1125E-02 -2.949 0.2790 -0.554 0.1022 0.7643E-01 microcline 0.4646E-01 -1.333 12.93 1.112 4.738 5.052 stilbite 0.1700 -0.770 119.8 2.078 43.88 55.86 stilpnomelane-Fe 0.1293E-01 -1.889 13.93 1.144 5.105 4.813 tr.625ac.25prg.125 0.2879E-02 -2.541 2.461 0.391 0.9016 0.7920 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8048E+00 0.8048E+00 1.0000 -0.094 grossular 0.1952E+00 0.1952E+00 1.0000 -0.710 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.7616E+00 0.7616E+00 1.0000 -0.118 daphnite 0.2204E+00 0.2204E+00 1.0000 -0.657 chlorite-Mn 0.1798E-01 0.1798E-01 1.0000 -1.745 diopside 0.7941E+00 0.7941E+00 1.0000 -0.100 hedenbergite 0.2059E+00 0.2059E+00 1.0000 -0.686 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 tr.625ac.25prg.125 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 272.931474 g Volume = 111.132317 cm3 Porosity: -10.0324% V(tot) - V(min): -.10133E+02 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 249.9990000 g log = 2.3979 Original solution: 1000.0103000 g Original solution / Rock added: 4.00 (Water/Rock Ratio), log = 0.6021 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0544 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9681E+00 0.9855 0.1006E+01 0.1021E+01 CO2,gas 0.3278E-08 1.0069 0.3481E-08 0.3457E-08 CH4,gas 0.1747E-01 1.0125 0.1865E-01 0.1842E-01 H2,gas 0.1443E-01 1.0006 0.1522E-01 0.1521E-01 H2S,gas 0.1313E-06 0.9959 0.1379E-06 0.1384E-06 S2,gas 0.2921E-29 1.0000 0.3080E-29 0.3080E-29 CO,gas 0.1339E-13 1.0000 0.1412E-13 0.1412E-13 SO3,gas 0.6792E-48 1.0000 0.7161E-48 0.7161E-48 SO2,gas 0.4022E-27 1.0000 0.4241E-27 0.4241E-27 HCl,gas 0.2680E-17 1.0000 0.2826E-17 0.2826E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 16 albite -0.38 -0.38 0.00 0.000 0.11184E-10 22 andradite 39.01 39.01 0.00 0.000 0.24265E-10 23 grossular 32.73 32.73 0.00 0.000 -0.24265E-10 32 apatite-OH -18.15 -18.15 0.00 0.000 0.60662E-11 46 clinochlore 39.07 39.07 0.00 0.000 0.36397E-10 47 daphnite 28.97 28.97 0.00 0.000 0.84926E-10 48 chlorite-Mn 46.87 46.87 0.00 0.000 0.00000E+00 67 diopside 16.18 16.18 0.00 0.000 0.18198E-10 68 hedenbergite 14.21 14.21 0.00 0.000 0.12132E-10 116 microcline -2.49 -2.49 0.00 0.000 0.13649E-10 163 stilbite -7.52 -7.52 0.00 0.000 0.15165E-10 164 stilpnomelane-Fe 13.02 13.02 0.00 0.000 -0.75827E-10 245 tr.625ac.25prg.125 45.16 45.16 0.00 0.000 0.36397E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -16.82 -10.16 -3.386 0.17343E+05 -8.458 3 CH4,gas 4.54 1.12 -3.43 -0.857 0.58537E+04 -1.729 4 H2,gas 8.00 4.48 -3.52 -2.009 0.60044E+04 -1.818 5 H2S,gas -6.23 -14.79 -8.56 -4.280 0.14615E+05 -6.861 6 S2,gas -7.34 -38.55 -31.21 -4.802 0.53291E+05 -29.511 7 CO,gas 3.21 -12.33 -15.55 -4.784 0.26550E+05 -13.850 8 SO3,gas 17.12 -32.72 -49.84 -12.461 0.85107E+05 -48.145 9 SO2,gas 0.83 -28.24 -29.07 -7.752 0.49639E+05 -27.373 10 HCl,gas 5.19 -14.06 -19.25 -9.624 0.32865E+05 -17.549 11 acmite 7.71 6.53 -1.18 -0.123 0.20183E+04 15 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 19 spessartine 24.46 19.69 -4.77 -0.238 0.81438E+04 20 analcite 3.32 2.77 -0.55 -0.061 0.93596E+03 26 annite 20.12 17.72 -2.40 -0.134 0.41061E+04 27 phlogopite 27.06 25.40 -1.67 -0.093 0.28479E+04 29 anorthite 12.71 8.27 -4.44 -0.342 0.75889E+04 35 aragonite 0.97 -3.72 -4.68 -1.561 0.79943E+04 36 brucite 12.57 9.29 -3.27 -0.655 0.55906E+04 37 calcite 0.81 -3.72 -4.53 -1.509 0.77301E+04 38 carnegieite-low 9.02 5.93 -3.09 -0.442 0.52795E+04 39 carnegieite-high 10.09 5.93 -4.16 -0.595 0.71065E+04 40 carpholite-Mg 8.58 4.46 -4.12 -0.275 0.70414E+04 41 carpholite-Fe 6.71 1.90 -4.81 -0.321 0.82194E+04 42 celadonite 5.34 3.65 -1.69 -0.099 0.28878E+04 43 celadonite-Fe 3.88 1.09 -2.79 -0.164 0.47562E+04 44 chrysotile 23.89 21.57 -2.32 -0.194 0.39688E+04 49 chlorite-Al-free 47.17 43.14 -4.04 -0.168 0.68928E+04 51 chloritoid-Fe 9.17 5.06 -4.12 -0.274 0.70300E+04 52 chloritoid-Mn 11.40 7.55 -3.85 -0.257 0.65780E+04 54 coesite -2.38 -3.16 -0.78 -0.261 0.13344E+04 61 cristobalite -2.56 -3.16 -0.60 -0.199 0.10198E+04 63 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71234E+04 65 diaspore 2.87 0.74 -2.13 -0.356 0.36441E+04 66 diamond -3.10 -7.85 -4.75 -1.357 0.81081E+04 71 enstatite 17.26 12.27 -4.99 -0.499 0.85225E+04 73 clinoenstatite 17.17 12.27 -4.89 -0.489 0.83541E+04 75 epidote 24.67 22.70 -1.97 -0.095 0.33573E+04 76 clinozoisite 22.81 18.95 -3.86 -0.175 0.65845E+04 77 epidote-Fe 29.84 26.46 -3.38 -0.176 0.57767E+04 78 fayalite 14.05 10.31 -3.73 -0.533 0.63744E+04 79 ferrosilite 11.15 7.15 -3.99 -0.399 0.68205E+04 83 gibbsite 4.08 0.74 -3.34 -0.477 0.57027E+04 84 glaucophane 22.97 20.80 -2.17 -0.059 0.37130E+04 85 glaucophane-Fe 17.28 13.12 -4.15 -0.112 0.70921E+04 86 graphite -3.55 -7.85 -4.30 -1.230 0.73504E+04 87 greenalite 16.14 13.89 -2.25 -0.187 0.38410E+04 90 hematite 12.57 8.99 -3.58 -0.434 0.61116E+04 91 heulandite -5.83 -7.52 -1.69 -0.077 0.28938E+04 95 jadeite 4.22 2.77 -1.44 -0.144 0.24614E+04 97 kalsilite 7.58 3.83 -3.76 -0.536 0.64120E+04 98 kaolinite -1.33 -4.84 -3.50 -0.318 0.59820E+04 101 laumontite 2.88 1.95 -0.93 -0.062 0.15926E+04 102 lawsonite 9.62 8.27 -1.35 -0.090 0.23055E+04 103 leucite 4.12 0.67 -3.45 -0.345 0.58870E+04 105 lizardite 23.24 21.57 -1.68 -0.140 0.28614E+04 107 magnetite 20.09 15.72 -4.37 -0.356 0.74539E+04 108 minnesotaite 10.39 7.57 -2.81 -0.165 0.48036E+04 112 manganosite 14.06 9.23 -4.83 -1.208 0.82487E+04 120 muscovite 2.58 -1.01 -3.59 -0.211 0.61298E+04 121 paragonite 4.24 1.10 -3.14 -0.185 0.53689E+04 122 nepheline 8.34 5.93 -2.41 -0.344 0.41119E+04 128 periclase-Fe 11.63 6.74 -4.89 -1.223 0.83522E+04 134 phlogopite-Na 29.65 27.50 -2.15 -0.119 0.36668E+04 136 prehnite 19.37 18.21 -1.16 -0.068 0.19835E+04 137 prehnite-Fe 22.50 21.96 -0.53 -0.032 0.91121E+03 138 pumpellyite-Fe 46.27 43.90 -2.37 -0.053 0.40542E+04 139 pumpellyite-Mg 48.99 46.45 -2.54 -0.056 0.43379E+04 143 pyrrhotite -4.26 -8.05 -3.79 -1.265 0.64788E+04 144 pyrrhotiteFe0.875 -6.02 -9.45 -3.44 -1.264 0.58661E+04 145 pyroxmangite 7.40 6.07 -1.33 -0.266 0.22693E+04 146 pyrophyllite -6.18 -11.15 -4.98 -0.311 0.84956E+04 147 quartz -2.99 -3.16 -0.17 -0.056 0.28709E+03 152 rhodonite 7.45 6.07 -1.38 -0.275 0.23496E+04 153 sanidine -1.28 -2.49 -1.21 -0.093 0.20677E+04 165 stilpnomelane-Mg 27.44 25.81 -1.63 -0.049 0.27793E+04 171 talc 16.49 15.25 -1.24 -0.073 0.21142E+04 174 tephroite 18.09 15.30 -2.79 -0.398 0.47621E+04 178 tridymite -2.63 -3.16 -0.53 -0.177 0.90707E+03 179 tremolite 47.87 47.42 -0.45 -0.012 0.77504E+03 180 ferroactinolite 38.45 34.62 -3.83 -0.104 0.65460E+04 181 troilite-low -4.41 -8.05 -3.64 -1.215 0.62216E+04 183 vesuvianite 223.47 218.82 -4.65 -0.035 0.79332E+04 187 wairakite 3.95 1.95 -2.00 -0.118 0.34146E+04 188 walstromite 11.51 9.94 -1.56 -0.313 0.26718E+04 189 wollastonite 10.46 9.94 -0.52 -0.103 0.88228E+03 190 pseudo-wollastonite 11.00 9.94 -1.06 -0.211 0.18021E+04 191 zoisite 22.85 18.95 -3.90 -0.177 0.66586E+04 192 akaganeite 7.75 4.49 -3.26 -0.705 0.55683E+04 199 chalcedony -2.80 -3.16 -0.36 -0.118 0.60639E+03 201 montmorillonite-Ca -2.29 -6.17 -3.88 -0.240 0.66176E+04 202 montmorillonite-K -2.24 -6.27 -4.03 -0.247 0.68812E+04 203 montmorillonite-Mg -2.48 -6.79 -4.31 -0.267 0.73673E+04 204 montmorillonite-Na -2.04 -5.57 -3.54 -0.216 0.60361E+04 205 nontronite-Ca 3.21 -0.20 -3.41 -0.221 0.58227E+04 206 nontronite-H 2.53 -2.36 -4.89 -0.328 0.83497E+04 207 nontronite-K 3.34 -0.30 -3.64 -0.233 0.62095E+04 208 nontronite-Mg 3.07 -0.82 -3.90 -0.253 0.66565E+04 209 nontronite-Na 3.52 0.40 -3.12 -0.200 0.53304E+04 224 tobermorite 9.82 7.76 -2.07 -0.564 0.35288E+04 230 alabandite -0.98 -5.56 -4.58 -1.528 0.78282E+04 233 boehmite 4.41 0.74 -3.67 -0.611 0.62610E+04 235 ferrous-oxide 9.81 6.74 -3.08 -0.769 0.52531E+04 240 silica-amorphous -2.09 -3.16 -1.07 -0.355 0.18206E+04 242 an20ab80 2.02 1.35 -0.67 -0.052 0.11469E+04 243 an25ab75 2.65 1.78 -0.87 -0.067 0.14806E+04 244 an30ab70 3.28 2.21 -1.07 -0.082 0.18239E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 10.0000000 g Current total amount of reactant added: 249.9990000 g New total amount of reactant added: 259.9990000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.3650E-11 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 11 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 259.9990000 Water: Moles liquid = 0.5397E+02 kg liquid = 0.9724E+00 Moles total = 0.5225E+02 kg total = 0.9413E+00 Activity = 1.0000 Stoichiometric ionic strength = .1131956E-01 Osmotic coef. = 0.9695 True ionic strength = .2000871E-01 Chg. balance for total moles = 0.3650E-11 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.88251E-10 -10.0543 0.74155E-10 -10.1299 0.84028E+00 -0.0756 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.14125E-03 -3.8500 0.11797E-03 -3.9282 0.83523E+00 -0.0782 4 SO4-- 0.66395E-12 -12.1779 0.34484E-12 -12.4624 0.51937E+00 -0.2845 5 HCO3- 0.24574E-06 -6.6095 0.20555E-06 -6.6871 0.83645E+00 -0.0776 6 HS- 0.26225E-04 -4.5813 0.21907E-04 -4.6594 0.83535E+00 -0.0781 7 Al+++ 0.96846E-29 -29.0139 0.22381E-29 -29.6501 0.23110E+00 -0.6362 8 H4SiO4 0.69572E-03 -3.1576 0.69572E-03 -3.1576 0.10000E+01 0.0000 9 Ca++ 0.13490E-06 -6.8700 0.69547E-07 -7.1577 0.51556E+00 -0.2877 10 Mg++ 0.21104E-10 -10.6756 0.10831E-10 -10.9653 0.51320E+00 -0.2897 11 Fe++ 0.58151E-13 -13.2354 0.29876E-13 -13.5247 0.51377E+00 -0.2892 12 K+ 0.15644E-03 -3.8057 0.13088E-03 -3.8831 0.83665E+00 -0.0775 13 Na+ 0.19851E-01 -1.7022 0.16577E-01 -1.7805 0.83507E+00 -0.0783 14 Mn++ 0.18068E-10 -10.7431 0.92905E-11 -11.0320 0.51419E+00 -0.2889 15 HPO4-- 0.45327E-07 -7.3436 0.23545E-07 -7.6281 0.51945E+00 -0.2845 16 HSiO3- 0.10489E-01 -1.9793 0.87603E-02 -2.0575 0.83523E+00 -0.0782 17 Ca(HSiO3)+ 0.16580E-07 -7.7804 0.13875E-07 -7.8578 0.83682E+00 -0.0774 18 Mg(HSiO3)+ 0.32135E-11 -11.4930 0.26891E-11 -11.5704 0.83682E+00 -0.0774 19 NaHSiO3,aq 0.23488E-02 -2.6292 0.23488E-02 -2.6292 0.10000E+01 0.0000 20 AlO+ 0.66167E-16 -16.1794 0.55370E-16 -16.2567 0.83682E+00 -0.0774 22 HAlO2,aq 0.14870E-09 -9.8277 0.14870E-09 -9.8277 0.10000E+01 0.0000 23 AlO2- 0.53241E-05 -5.2738 0.44388E-05 -5.3527 0.83372E+00 -0.0790 24 CH4,aq 0.12728E-04 -4.8952 0.12684E-04 -4.8967 0.99655E+00 -0.0015 25 C2H6,aq 0.23809E-14 -14.6233 0.23727E-14 -14.6248 0.99655E+00 -0.0015 29 CO,aq 0.94851E-17 -17.0230 0.94851E-17 -17.0230 0.10000E+01 0.0000 30 CO2,aq 0.32683E-10 -10.4857 0.32570E-10 -10.4872 0.99655E+00 -0.0015 31 CO3-2 0.46716E-06 -6.3305 0.24212E-06 -6.6160 0.51827E+00 -0.2854 32 CaCO3,aq 0.21113E-09 -9.6754 0.21113E-09 -9.6754 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.43606E-12 -12.3605 0.36491E-12 -12.4378 0.83682E+00 -0.0774 34 CaCl+ 0.15867E-10 -10.7995 0.13278E-10 -10.8769 0.83682E+00 -0.0774 35 CaCl2,aq 0.37215E-15 -15.4293 0.37215E-15 -15.4293 0.10000E+01 0.0000 36 CaOH+ 0.79874E-07 -7.0976 0.66841E-07 -7.1750 0.83682E+00 -0.0774 37 CaSO4,aq 0.76155E-17 -17.1183 0.76155E-17 -17.1183 0.10000E+01 0.0000 38 HCl,aq 0.16031E-14 -14.7950 0.16031E-14 -14.7950 0.10000E+01 0.0000 43 FeCl+ 0.66667E-17 -17.1761 0.55788E-17 -17.2535 0.83682E+00 -0.0774 46 FeO,aq 0.21116E-09 -9.6754 0.21116E-09 -9.6754 0.10000E+01 0.0000 47 FeOH+ 0.15672E-10 -10.8049 0.13114E-10 -10.8823 0.83682E+00 -0.0774 48 HFeO2- 0.35672E-07 -7.4477 0.29794E-07 -7.5259 0.83523E+00 -0.0782 49 FeO+ 0.10979E-16 -16.9595 0.91871E-17 -17.0368 0.83682E+00 -0.0774 51 FeO2- 0.40930E-09 -9.3880 0.34186E-09 -9.4662 0.83523E+00 -0.0782 52 HFeO2,aq 0.32242E-11 -11.4916 0.32242E-11 -11.4916 0.10000E+01 0.0000 53 H2,aq 0.11633E-04 -4.9343 0.11593E-04 -4.9358 0.99655E+00 -0.0015 54 KCl,aq 0.27985E-09 -9.5531 0.27985E-09 -9.5531 0.10000E+01 0.0000 56 KOH,aq 0.75376E-06 -6.1228 0.75376E-06 -6.1228 0.10000E+01 0.0000 57 KSO4- 0.83853E-15 -15.0765 0.70036E-15 -15.1547 0.83523E+00 -0.0782 58 MgCO3,aq 0.82418E-14 -14.0840 0.82418E-14 -14.0840 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.69390E-16 -16.1587 0.58068E-16 -16.2361 0.83682E+00 -0.0774 60 MgCl+ 0.22396E-14 -14.6498 0.18741E-14 -14.7272 0.83682E+00 -0.0774 61 MgOH+ 0.68831E-10 -10.1622 0.57600E-10 -10.2396 0.83682E+00 -0.0774 63 MnO,aq 0.17497E-08 -8.7570 0.17497E-08 -8.7570 0.10000E+01 0.0000 64 MnOH+ 0.45272E-09 -9.3442 0.37885E-09 -9.4215 0.83682E+00 -0.0774 65 MnO2-2 0.20375E-10 -10.6909 0.10560E-10 -10.9764 0.51827E+00 -0.2854 66 HMnO2- 0.20540E-09 -9.6874 0.17155E-09 -9.7656 0.83523E+00 -0.0782 69 MnCl+ 0.80654E-14 -14.0934 0.67494E-14 -14.1707 0.83682E+00 -0.0774 71 NaCl,aq 0.64812E-06 -6.1883 0.64812E-06 -6.1883 0.10000E+01 0.0000 72 NaOH,aq 0.96048E-04 -4.0175 0.96048E-04 -4.0175 0.10000E+01 0.0000 74 OH- 0.93454E-02 -2.0294 0.77914E-02 -2.1084 0.83372E+00 -0.0790 79 HPO3-2 0.16412E-14 -14.7848 0.85061E-15 -15.0703 0.51827E+00 -0.2854 81 H2PO3- 0.15144E-18 -18.8198 0.12649E-18 -18.8980 0.83523E+00 -0.0782 82 H3PO4,aq 0.90552E-18 -18.0431 0.90552E-18 -18.0431 0.10000E+01 0.0000 83 H2PO4- 0.38526E-10 -10.4142 0.32208E-10 -10.4920 0.83602E+00 -0.0778 84 PO4-3 0.10673E-08 -8.9717 0.25905E-09 -9.5866 0.24272E+00 -0.6149 88 HP2O7-3 0.94682E-18 -18.0237 0.21903E-18 -18.6595 0.23133E+00 -0.6358 89 P2O7-4 0.91464E-17 -17.0387 0.70561E-18 -18.1514 0.77146E-01 -1.1127 90 H2S,aq 0.50381E-08 -8.2977 0.50207E-08 -8.2992 0.99655E+00 -0.0015 91 S2-2 0.17698E-14 -14.7521 0.91726E-15 -15.0375 0.51827E+00 -0.2854 97 SO3-2 0.98806E-18 -18.0052 0.51949E-18 -18.2844 0.52576E+00 -0.2792 99 HSO4- 0.29420E-19 -19.5314 0.24643E-19 -19.6083 0.83764E+00 -0.0769 Charge balance for all species = 0.3752E-11 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.8825064E-10 -.2230440E-01 -.2244245E+02 0.0000 2 H2O 0.1000000E+01 0.5550489E+02 0.9982002E+06 0.0000 3 Cl- 0.1412483E-03 0.1418968E-03 0.5021927E+01 6.2016 4 SO4-- 0.6639466E-12 -.1563662E-04 -.1499469E+01 7.7973 5 HCO3- 0.2457439E-06 0.1344158E-04 0.8187427E+00 3.4428 6 HS- 0.2622452E-04 0.4186618E-04 0.1382193E+01 5.4704 7 Al+++ 0.9684637E-29 0.5324292E-05 0.1434078E+00 0.7395 8 H4SiO4 0.6957168E-03 0.1353305E-01 0.1298475E+04 -3.1576 9 Ca++ 0.1348951E-06 0.2315770E-06 0.9265021E-02 13.1020 10 Mg++ 0.2110412E-10 0.9315950E-10 0.2260959E-05 9.2944 11 Fe++ 0.5815093E-13 0.3631115E-07 0.2024346E-02 6.7350 12 K+ 0.1564387E-03 0.1571927E-03 0.6135871E+01 6.2467 13 Na+ 0.1985126E-01 0.2229672E-01 0.5117067E+03 8.3494 14 Mn++ 0.1806824E-10 0.2446227E-08 0.1341574E-03 9.2278 15 HPO4-- 0.4532684E-07 0.4643267E-07 0.4448820E-02 12.6316 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.4305184E+01 -.2168782E-01 -.4283497E+01 0.0000000E+00 2 H2O 0.5224906E+02 0.5397052E+02 -.1721461E+01 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.7230963E-02 -.1520436E-04 0.7246167E-02 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.7205459E-02 0.4070883E-04 -.7246167E-02 0.0000000E+00 7 Al+++ 0.8477896E+00 0.5177108E-05 0.8477844E+00 0.0000000E+00 8 H4SiO4 0.2707313E+01 0.1315894E-01 0.2694154E+01 0.0000000E+00 9 Ca++ 0.2990504E+00 0.2251753E-06 0.2990502E+00 0.0000000E+00 10 Mg++ 0.2063484E+00 0.9058421E-10 0.2063484E+00 0.0000000E+00 11 Fe++ 0.1853815E+00 0.3530737E-07 0.1853815E+00 0.0000000E+00 12 K+ 0.5520149E-01 0.1528473E-03 0.5504864E-01 0.0000000E+00 13 Na+ 0.3265222E+00 0.2168035E-01 0.3048418E+00 0.0000000E+00 14 Mn++ 0.4508018E-02 0.2378604E-08 0.4508015E-02 0.0000000E+00 15 HPO4-- 0.1538564E-02 0.4514909E-07 0.1538519E-02 0.0000000E+00 Chg. balance for solid moles: -.2689E-16 Mass of aqueous solution: 0.974048E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 259.9990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 0.3045 -0.516 79.84 1.902 28.13 30.65 andradite 0.2898E-01 -1.538 14.73 1.168 5.189 3.827 grossular 0.7028E-02 -2.153 3.166 0.500 1.115 0.8809 apatite-OH 0.5128E-03 -3.290 0.2576 -0.589 0.9075E-01 0.8186E-01 clinochlore 0.3815E-01 -1.419 21.20 1.326 7.469 8.065 daphnite 0.1104E-01 -1.957 7.877 0.896 2.775 2.387 chlorite-Mn 0.9016E-03 -3.045 0.6392 -0.194 0.2252 0.2037 diopside 0.4882E-02 -2.311 1.057 0.024 0.3725 0.3231 hedenbergite 0.1266E-02 -2.898 0.3140 -0.503 0.1106 0.8601E-01 microcline 0.4832E-01 -1.316 13.45 1.129 4.739 5.254 stilbite 0.1764 -0.754 124.3 2.094 43.79 57.97 stilpnomelane-Fe 0.1345E-01 -1.871 14.50 1.161 5.107 5.008 tr.625ac.25prg.125 0.2962E-02 -2.528 2.532 0.403 0.8920 0.8150 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8048E+00 0.8048E+00 1.0000 -0.094 grossular 0.1952E+00 0.1952E+00 1.0000 -0.710 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.7616E+00 0.7616E+00 1.0000 -0.118 daphnite 0.2204E+00 0.2204E+00 1.0000 -0.657 chlorite-Mn 0.1800E-01 0.1800E-01 1.0000 -1.745 diopside 0.7941E+00 0.7941E+00 1.0000 -0.100 hedenbergite 0.2059E+00 0.2059E+00 1.0000 -0.686 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 tr.625ac.25prg.125 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 283.856532 g Volume = 115.552623 cm3 Porosity: -10.0505% V(tot) - V(min): -.10553E+02 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 259.9990000 g log = 2.4150 Original solution: 1000.0103000 g Original solution / Rock added: 3.85 (Water/Rock Ratio), log = 0.5850 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0544 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9681E+00 0.9855 0.1006E+01 0.1021E+01 CO2,gas 0.3282E-08 1.0069 0.3485E-08 0.3461E-08 CH4,gas 0.1749E-01 1.0125 0.1867E-01 0.1844E-01 H2,gas 0.1443E-01 1.0006 0.1522E-01 0.1521E-01 H2S,gas 0.1314E-06 0.9959 0.1380E-06 0.1386E-06 S2,gas 0.2927E-29 1.0000 0.3087E-29 0.3087E-29 CO,gas 0.1341E-13 1.0000 0.1413E-13 0.1413E-13 SO3,gas 0.6800E-48 1.0000 0.7170E-48 0.7170E-48 SO2,gas 0.4026E-27 1.0000 0.4245E-27 0.4245E-27 HCl,gas 0.2683E-17 1.0000 0.2829E-17 0.2829E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 16 albite -0.38 -0.38 0.00 0.000 -0.94784E-12 22 andradite 39.01 39.01 0.00 0.000 0.24265E-10 23 grossular 32.73 32.73 0.00 0.000 0.24265E-10 32 apatite-OH -18.15 -18.15 0.00 0.000 0.12132E-10 46 clinochlore 39.07 39.07 0.00 0.000 -0.12132E-10 47 daphnite 28.97 28.97 0.00 0.000 -0.24265E-10 48 chlorite-Mn 46.87 46.87 0.00 0.000 0.24265E-10 67 diopside 16.18 16.18 0.00 0.000 0.00000E+00 68 hedenbergite 14.21 14.21 0.00 0.000 -0.60662E-11 116 microcline -2.49 -2.49 0.00 0.000 0.15165E-11 163 stilbite -7.52 -7.52 0.00 0.000 -0.90992E-11 164 stilpnomelane-Fe 13.02 13.02 0.00 0.000 -0.27298E-10 245 tr.625ac.25prg.125 45.16 45.16 0.00 0.000 0.00000E+00 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -16.82 -10.16 -3.386 0.17342E+05 -8.458 3 CH4,gas 4.54 1.12 -3.43 -0.857 0.58529E+04 -1.729 4 H2,gas 8.00 4.48 -3.52 -2.009 0.60044E+04 -1.818 5 H2S,gas -6.23 -14.79 -8.56 -4.280 0.14614E+05 -6.860 6 S2,gas -7.34 -38.54 -31.21 -4.801 0.53289E+05 -29.511 7 CO,gas 3.21 -12.33 -15.55 -4.784 0.26549E+05 -13.850 8 SO3,gas 17.12 -32.72 -49.84 -12.461 0.85106E+05 -48.144 9 SO2,gas 0.83 -28.24 -29.07 -7.752 0.49638E+05 -27.372 10 HCl,gas 5.19 -14.06 -19.25 -9.624 0.32864E+05 -17.548 11 acmite 7.71 6.53 -1.18 -0.123 0.20183E+04 15 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 19 spessartine 24.46 19.69 -4.77 -0.238 0.81409E+04 20 analcite 3.32 2.77 -0.55 -0.061 0.93597E+03 26 annite 20.12 17.72 -2.40 -0.134 0.41061E+04 27 phlogopite 27.06 25.40 -1.67 -0.093 0.28480E+04 29 anorthite 12.71 8.27 -4.44 -0.342 0.75889E+04 35 aragonite 0.97 -3.71 -4.68 -1.560 0.79935E+04 36 brucite 12.57 9.29 -3.27 -0.655 0.55906E+04 37 calcite 0.81 -3.71 -4.53 -1.509 0.77292E+04 38 carnegieite-low 9.02 5.93 -3.09 -0.442 0.52796E+04 39 carnegieite-high 10.09 5.93 -4.16 -0.595 0.71066E+04 40 carpholite-Mg 8.58 4.46 -4.12 -0.275 0.70415E+04 41 carpholite-Fe 6.71 1.90 -4.81 -0.321 0.82194E+04 42 celadonite 5.34 3.65 -1.69 -0.099 0.28878E+04 43 celadonite-Fe 3.88 1.09 -2.79 -0.164 0.47562E+04 44 chrysotile 23.89 21.57 -2.32 -0.194 0.39688E+04 49 chlorite-Al-free 47.17 43.14 -4.04 -0.168 0.68928E+04 51 chloritoid-Fe 9.17 5.06 -4.12 -0.274 0.70300E+04 52 chloritoid-Mn 11.40 7.55 -3.85 -0.257 0.65771E+04 54 coesite -2.38 -3.16 -0.78 -0.261 0.13344E+04 61 cristobalite -2.56 -3.16 -0.60 -0.199 0.10198E+04 63 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71234E+04 65 diaspore 2.87 0.74 -2.13 -0.356 0.36441E+04 66 diamond -3.10 -7.85 -4.75 -1.357 0.81073E+04 71 enstatite 17.26 12.27 -4.99 -0.499 0.85225E+04 73 clinoenstatite 17.17 12.27 -4.89 -0.489 0.83541E+04 75 epidote 24.67 22.70 -1.97 -0.095 0.33573E+04 76 clinozoisite 22.81 18.95 -3.86 -0.175 0.65846E+04 77 epidote-Fe 29.84 26.46 -3.38 -0.176 0.57767E+04 78 fayalite 14.05 10.31 -3.73 -0.533 0.63744E+04 79 ferrosilite 11.15 7.15 -3.99 -0.399 0.68205E+04 83 gibbsite 4.08 0.74 -3.34 -0.477 0.57027E+04 84 glaucophane 22.97 20.80 -2.17 -0.059 0.37130E+04 85 glaucophane-Fe 17.28 13.12 -4.15 -0.112 0.70921E+04 86 graphite -3.55 -7.85 -4.30 -1.230 0.73496E+04 87 greenalite 16.14 13.89 -2.25 -0.187 0.38410E+04 90 hematite 12.57 8.99 -3.58 -0.434 0.61116E+04 91 heulandite -5.83 -7.52 -1.69 -0.077 0.28938E+04 95 jadeite 4.22 2.77 -1.44 -0.144 0.24615E+04 97 kalsilite 7.58 3.83 -3.76 -0.536 0.64120E+04 98 kaolinite -1.33 -4.84 -3.50 -0.318 0.59820E+04 101 laumontite 2.88 1.95 -0.93 -0.062 0.15927E+04 102 lawsonite 9.62 8.27 -1.35 -0.090 0.23056E+04 103 leucite 4.12 0.67 -3.45 -0.345 0.58870E+04 105 lizardite 23.24 21.57 -1.68 -0.140 0.28615E+04 107 magnetite 20.09 15.72 -4.37 -0.356 0.74539E+04 108 minnesotaite 10.39 7.57 -2.81 -0.165 0.48035E+04 112 manganosite 14.06 9.23 -4.83 -1.208 0.82477E+04 120 muscovite 2.58 -1.01 -3.59 -0.211 0.61298E+04 121 paragonite 4.24 1.10 -3.14 -0.185 0.53689E+04 122 nepheline 8.34 5.93 -2.41 -0.344 0.41119E+04 128 periclase-Fe 11.63 6.74 -4.89 -1.223 0.83522E+04 134 phlogopite-Na 29.65 27.50 -2.15 -0.119 0.36668E+04 136 prehnite 19.37 18.21 -1.16 -0.068 0.19835E+04 137 prehnite-Fe 22.50 21.96 -0.53 -0.032 0.91123E+03 138 pumpellyite-Fe 46.27 43.89 -2.37 -0.053 0.40544E+04 139 pumpellyite-Mg 48.99 46.45 -2.54 -0.056 0.43380E+04 143 pyrrhotite -4.26 -8.05 -3.79 -1.265 0.64780E+04 144 pyrrhotiteFe0.875 -6.02 -9.45 -3.44 -1.263 0.58653E+04 145 pyroxmangite 7.40 6.07 -1.33 -0.266 0.22684E+04 146 pyrophyllite -6.18 -11.15 -4.98 -0.311 0.84956E+04 147 quartz -2.99 -3.16 -0.17 -0.056 0.28708E+03 152 rhodonite 7.45 6.07 -1.38 -0.275 0.23486E+04 153 sanidine -1.28 -2.49 -1.21 -0.093 0.20677E+04 165 stilpnomelane-Mg 27.44 25.81 -1.63 -0.049 0.27794E+04 171 talc 16.49 15.25 -1.24 -0.073 0.21142E+04 174 tephroite 18.09 15.30 -2.79 -0.398 0.47602E+04 178 tridymite -2.63 -3.16 -0.53 -0.177 0.90706E+03 179 tremolite 47.87 47.42 -0.45 -0.012 0.77504E+03 180 ferroactinolite 38.45 34.62 -3.83 -0.104 0.65459E+04 181 troilite-low -4.41 -8.05 -3.64 -1.214 0.62208E+04 183 vesuvianite 223.47 218.82 -4.65 -0.035 0.79336E+04 187 wairakite 3.95 1.95 -2.00 -0.118 0.34146E+04 188 walstromite 11.51 9.94 -1.56 -0.313 0.26718E+04 189 wollastonite 10.46 9.94 -0.52 -0.103 0.88228E+03 190 pseudo-wollastonite 11.00 9.94 -1.06 -0.211 0.18021E+04 191 zoisite 22.85 18.95 -3.90 -0.177 0.66587E+04 192 akaganeite 7.75 4.49 -3.26 -0.705 0.55683E+04 199 chalcedony -2.80 -3.16 -0.36 -0.118 0.60638E+03 201 montmorillonite-Ca -2.29 -6.17 -3.88 -0.240 0.66176E+04 202 montmorillonite-K -2.24 -6.27 -4.03 -0.247 0.68813E+04 203 montmorillonite-Mg -2.48 -6.79 -4.31 -0.267 0.73674E+04 204 montmorillonite-Na -2.04 -5.57 -3.54 -0.216 0.60361E+04 205 nontronite-Ca 3.21 -0.20 -3.41 -0.221 0.58226E+04 206 nontronite-H 2.53 -2.36 -4.89 -0.328 0.83497E+04 207 nontronite-K 3.34 -0.30 -3.64 -0.233 0.62095E+04 208 nontronite-Mg 3.07 -0.82 -3.90 -0.253 0.66564E+04 209 nontronite-Na 3.52 0.40 -3.12 -0.200 0.53303E+04 224 tobermorite 9.82 7.76 -2.07 -0.564 0.35288E+04 230 alabandite -0.98 -5.56 -4.58 -1.528 0.78265E+04 233 boehmite 4.41 0.74 -3.67 -0.611 0.62611E+04 235 ferrous-oxide 9.81 6.74 -3.08 -0.769 0.52531E+04 240 silica-amorphous -2.09 -3.16 -1.07 -0.355 0.18206E+04 242 an20ab80 2.02 1.35 -0.67 -0.052 0.11469E+04 243 an25ab75 2.65 1.78 -0.87 -0.067 0.14806E+04 244 an30ab70 3.28 2.21 -1.07 -0.082 0.18240E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 10.0000000 g Current total amount of reactant added: 259.9990000 g New total amount of reactant added: 269.9990000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.3649E-11 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 11 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 269.9990000 Water: Moles liquid = 0.5392E+02 kg liquid = 0.9714E+00 Moles total = 0.5212E+02 kg total = 0.9390E+00 Activity = 1.0000 Stoichiometric ionic strength = .1131974E-01 Osmotic coef. = 0.9695 True ionic strength = .2000889E-01 Chg. balance for total moles = 0.3649E-11 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.88251E-10 -10.0543 0.74156E-10 -10.1299 0.84028E+00 -0.0756 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.14139E-03 -3.8496 0.11810E-03 -3.9278 0.83523E+00 -0.0782 4 SO4-- 0.66472E-12 -12.1774 0.34524E-12 -12.4619 0.51937E+00 -0.2845 5 HCO3- 0.24603E-06 -6.6090 0.20579E-06 -6.6866 0.83645E+00 -0.0776 6 HS- 0.26252E-04 -4.5808 0.21929E-04 -4.6590 0.83535E+00 -0.0781 7 Al+++ 0.96845E-29 -29.0139 0.22381E-29 -29.6501 0.23110E+00 -0.6362 8 H4SiO4 0.69573E-03 -3.1576 0.69573E-03 -3.1576 0.10000E+01 0.0000 9 Ca++ 0.13490E-06 -6.8700 0.69547E-07 -7.1577 0.51556E+00 -0.2877 10 Mg++ 0.21104E-10 -10.6756 0.10831E-10 -10.9653 0.51320E+00 -0.2897 11 Fe++ 0.58152E-13 -13.2354 0.29876E-13 -13.5247 0.51376E+00 -0.2892 12 K+ 0.15644E-03 -3.8057 0.13088E-03 -3.8831 0.83664E+00 -0.0775 13 Na+ 0.19851E-01 -1.7022 0.16577E-01 -1.7805 0.83507E+00 -0.0783 14 Mn++ 0.18091E-10 -10.7425 0.93021E-11 -11.0314 0.51419E+00 -0.2889 15 HPO4-- 0.45327E-07 -7.3436 0.23545E-07 -7.6281 0.51944E+00 -0.2845 16 HSiO3- 0.10489E-01 -1.9793 0.87604E-02 -2.0575 0.83523E+00 -0.0782 17 Ca(HSiO3)+ 0.16581E-07 -7.7804 0.13875E-07 -7.8578 0.83682E+00 -0.0774 18 Mg(HSiO3)+ 0.32135E-11 -11.4930 0.26891E-11 -11.5704 0.83682E+00 -0.0774 19 NaHSiO3,aq 0.23488E-02 -2.6292 0.23488E-02 -2.6292 0.10000E+01 0.0000 20 AlO+ 0.66165E-16 -16.1794 0.55368E-16 -16.2567 0.83682E+00 -0.0774 22 HAlO2,aq 0.14869E-09 -9.8277 0.14869E-09 -9.8277 0.10000E+01 0.0000 23 AlO2- 0.53239E-05 -5.2738 0.44386E-05 -5.3528 0.83372E+00 -0.0790 24 CH4,aq 0.12742E-04 -4.8948 0.12698E-04 -4.8963 0.99655E+00 -0.0015 25 C2H6,aq 0.23859E-14 -14.6224 0.23776E-14 -14.6239 0.99655E+00 -0.0015 29 CO,aq 0.94958E-17 -17.0225 0.94958E-17 -17.0225 0.10000E+01 0.0000 30 CO2,aq 0.32721E-10 -10.4852 0.32608E-10 -10.4867 0.99655E+00 -0.0015 31 CO3-2 0.46770E-06 -6.3300 0.24239E-06 -6.6155 0.51827E+00 -0.2854 32 CaCO3,aq 0.21138E-09 -9.6749 0.21138E-09 -9.6749 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.43656E-12 -12.3600 0.36533E-12 -12.4373 0.83682E+00 -0.0774 34 CaCl+ 0.15883E-10 -10.7991 0.13292E-10 -10.8764 0.83682E+00 -0.0774 35 CaCl2,aq 0.37292E-15 -15.4284 0.37292E-15 -15.4284 0.10000E+01 0.0000 36 CaOH+ 0.79874E-07 -7.0976 0.66840E-07 -7.1750 0.83682E+00 -0.0774 37 CaSO4,aq 0.76243E-17 -17.1178 0.76243E-17 -17.1178 0.10000E+01 0.0000 38 HCl,aq 0.16048E-14 -14.7946 0.16048E-14 -14.7946 0.10000E+01 0.0000 43 FeCl+ 0.66736E-17 -17.1756 0.55847E-17 -17.2530 0.83682E+00 -0.0774 46 FeO,aq 0.21116E-09 -9.6754 0.21116E-09 -9.6754 0.10000E+01 0.0000 47 FeOH+ 0.15672E-10 -10.8049 0.13114E-10 -10.8823 0.83682E+00 -0.0774 48 HFeO2- 0.35671E-07 -7.4477 0.29794E-07 -7.5259 0.83523E+00 -0.0782 49 FeO+ 0.10979E-16 -16.9594 0.91873E-17 -17.0368 0.83682E+00 -0.0774 51 FeO2- 0.40930E-09 -9.3880 0.34186E-09 -9.4662 0.83523E+00 -0.0782 52 HFeO2,aq 0.32242E-11 -11.4916 0.32242E-11 -11.4916 0.10000E+01 0.0000 53 H2,aq 0.11633E-04 -4.9343 0.11592E-04 -4.9358 0.99655E+00 -0.0015 54 KCl,aq 0.28015E-09 -9.5526 0.28015E-09 -9.5526 0.10000E+01 0.0000 56 KOH,aq 0.75376E-06 -6.1228 0.75376E-06 -6.1228 0.10000E+01 0.0000 57 KSO4- 0.83951E-15 -15.0760 0.70118E-15 -15.1542 0.83523E+00 -0.0782 58 MgCO3,aq 0.82512E-14 -14.0835 0.82512E-14 -14.0835 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.69470E-16 -16.1582 0.58135E-16 -16.2356 0.83682E+00 -0.0774 60 MgCl+ 0.22419E-14 -14.6494 0.18761E-14 -14.7268 0.83682E+00 -0.0774 61 MgOH+ 0.68831E-10 -10.1622 0.57599E-10 -10.2396 0.83682E+00 -0.0774 63 MnO,aq 0.17518E-08 -8.7565 0.17518E-08 -8.7565 0.10000E+01 0.0000 64 MnOH+ 0.45328E-09 -9.3436 0.37932E-09 -9.4210 0.83682E+00 -0.0774 65 MnO2-2 0.20399E-10 -10.6904 0.10572E-10 -10.9758 0.51827E+00 -0.2854 66 HMnO2- 0.20565E-09 -9.6869 0.17176E-09 -9.7651 0.83523E+00 -0.0782 69 MnCl+ 0.80838E-14 -14.0924 0.67647E-14 -14.1698 0.83682E+00 -0.0774 71 NaCl,aq 0.64880E-06 -6.1879 0.64880E-06 -6.1879 0.10000E+01 0.0000 72 NaOH,aq 0.96048E-04 -4.0175 0.96048E-04 -4.0175 0.10000E+01 0.0000 74 OH- 0.93453E-02 -2.0294 0.77914E-02 -2.1084 0.83372E+00 -0.0790 79 HPO3-2 0.16412E-14 -14.7848 0.85059E-15 -15.0703 0.51827E+00 -0.2854 81 H2PO3- 0.15144E-18 -18.8198 0.12649E-18 -18.8980 0.83523E+00 -0.0782 82 H3PO4,aq 0.90554E-18 -18.0431 0.90554E-18 -18.0431 0.10000E+01 0.0000 83 H2PO4- 0.38527E-10 -10.4142 0.32209E-10 -10.4920 0.83602E+00 -0.0778 84 PO4-3 0.10673E-08 -8.9717 0.25905E-09 -9.5866 0.24271E+00 -0.6149 88 HP2O7-3 0.94684E-18 -18.0237 0.21903E-18 -18.6595 0.23133E+00 -0.6358 89 P2O7-4 0.91466E-17 -17.0387 0.70562E-18 -18.1514 0.77146E-01 -1.1127 90 H2S,aq 0.50433E-08 -8.2973 0.50259E-08 -8.2988 0.99655E+00 -0.0015 91 S2-2 0.17736E-14 -14.7512 0.91919E-15 -15.0366 0.51827E+00 -0.2854 97 SO3-2 0.98918E-18 -18.0047 0.52007E-18 -18.2839 0.52576E+00 -0.2792 99 HSO4- 0.29454E-19 -19.5308 0.24672E-19 -19.6078 0.83764E+00 -0.0769 Charge balance for all species = 0.3757E-11 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.8825141E-10 -.2230443E-01 -.2244248E+02 0.0000 2 H2O 0.1000000E+01 0.5550489E+02 0.9982002E+06 0.0000 3 Cl- 0.1413944E-03 0.1420435E-03 0.5027119E+01 6.2021 4 SO4-- 0.6647179E-12 -.1564960E-04 -.1500714E+01 7.7978 5 HCO3- 0.2460275E-06 0.1345548E-04 0.8195892E+00 3.4433 6 HS- 0.2625163E-04 0.4190627E-04 0.1383517E+01 5.4709 7 Al+++ 0.9684513E-29 0.5324024E-05 0.1434006E+00 0.7394 8 H4SiO4 0.6957267E-03 0.1353316E-01 0.1298485E+04 -3.1576 9 Ca++ 0.1348956E-06 0.2315775E-06 0.9265040E-02 13.1020 10 Mg++ 0.2110418E-10 0.9315909E-10 0.2260949E-05 9.2944 11 Fe++ 0.5815169E-13 0.3631067E-07 0.2024319E-02 6.7350 12 K+ 0.1564400E-03 0.1571940E-03 0.6135924E+01 6.2467 13 Na+ 0.1985143E-01 0.2229692E-01 0.5117114E+03 8.3494 14 Mn++ 0.1809069E-10 0.2449224E-08 0.1343217E-03 9.2283 15 HPO4-- 0.4532730E-07 0.4643314E-07 0.4448865E-02 12.6316 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.4470770E+01 -.2166545E-01 -.4449104E+01 0.0000000E+00 2 H2O 0.5212370E+02 0.5391478E+02 -.1791073E+01 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.7508097E-02 -.1520126E-04 0.7523298E-02 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.7482593E-02 0.4070573E-04 -.7523298E-02 0.0000000E+00 7 Al+++ 0.8803970E+00 0.5171500E-05 0.8803918E+00 0.0000000E+00 8 H4SiO4 0.2811441E+01 0.1314546E-01 0.2798296E+01 0.0000000E+00 9 Ca++ 0.3105518E+00 0.2249432E-06 0.3105516E+00 0.0000000E+00 10 Mg++ 0.2142849E+00 0.9049025E-10 0.2142849E+00 0.0000000E+00 11 Fe++ 0.1925116E+00 0.3527044E-07 0.1925116E+00 0.0000000E+00 12 K+ 0.5732463E-01 0.1526907E-03 0.5717194E-01 0.0000000E+00 13 Na+ 0.3390746E+00 0.2165816E-01 0.3174164E+00 0.0000000E+00 14 Mn++ 0.4681404E-02 0.2379058E-08 0.4681401E-02 0.0000000E+00 15 HPO4-- 0.1597740E-02 0.4510292E-07 0.1597695E-02 0.0000000E+00 Chg. balance for solid moles: 0.9376E-15 Mass of aqueous solution: 0.973042E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 269.9990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 0.3170 -0.499 83.13 1.920 28.20 31.91 andradite 0.3009E-01 -1.522 15.29 1.184 5.188 3.973 grossular 0.7297E-02 -2.137 3.287 0.517 1.115 0.9145 apatite-OH 0.5326E-03 -3.274 0.2675 -0.573 0.9075E-01 0.8501E-01 clinochlore 0.3956E-01 -1.403 21.99 1.342 7.460 8.365 daphnite 0.1145E-01 -1.941 8.170 0.912 2.772 2.476 chlorite-Mn 0.9363E-03 -3.029 0.6638 -0.178 0.2252 0.2115 diopside 0.5426E-02 -2.266 1.175 0.070 0.3986 0.3591 hedenbergite 0.1407E-02 -2.852 0.3490 -0.457 0.1184 0.9560E-01 microcline 0.5019E-01 -1.299 13.97 1.145 4.739 5.457 stilbite 0.1828 -0.738 128.8 2.110 43.70 60.08 stilpnomelane-Fe 0.1397E-01 -1.855 15.06 1.178 5.109 5.203 tr.625ac.25prg.125 0.3046E-02 -2.516 2.603 0.416 0.8831 0.8379 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8048E+00 0.8048E+00 1.0000 -0.094 grossular 0.1952E+00 0.1952E+00 1.0000 -0.710 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.7616E+00 0.7616E+00 1.0000 -0.118 daphnite 0.2204E+00 0.2204E+00 1.0000 -0.657 chlorite-Mn 0.1802E-01 0.1802E-01 1.0000 -1.744 diopside 0.7941E+00 0.7941E+00 1.0000 -0.100 hedenbergite 0.2059E+00 0.2059E+00 1.0000 -0.686 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 tr.625ac.25prg.125 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 294.781591 g Volume = 119.972929 cm3 Porosity: -10.0673% V(tot) - V(min): -.10973E+02 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 269.9990000 g log = 2.4314 Original solution: 1000.0103000 g Original solution / Rock added: 3.70 (Water/Rock Ratio), log = 0.5686 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0544 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9681E+00 0.9855 0.1006E+01 0.1021E+01 CO2,gas 0.3286E-08 1.0069 0.3489E-08 0.3465E-08 CH4,gas 0.1751E-01 1.0125 0.1869E-01 0.1846E-01 H2,gas 0.1443E-01 1.0006 0.1522E-01 0.1521E-01 H2S,gas 0.1316E-06 0.9959 0.1382E-06 0.1387E-06 S2,gas 0.2933E-29 1.0000 0.3093E-29 0.3093E-29 CO,gas 0.1342E-13 1.0000 0.1415E-13 0.1415E-13 SO3,gas 0.6808E-48 1.0000 0.7178E-48 0.7178E-48 SO2,gas 0.4031E-27 1.0000 0.4250E-27 0.4250E-27 HCl,gas 0.2685E-17 1.0000 0.2832E-17 0.2832E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 16 albite -0.38 -0.38 0.00 0.000 -0.94784E-12 22 andradite 39.01 39.01 0.00 0.000 -0.12132E-10 23 grossular 32.73 32.73 0.00 0.000 -0.12132E-10 32 apatite-OH -18.15 -18.15 0.00 0.000 0.60662E-11 46 clinochlore 39.07 39.07 0.00 0.000 -0.12132E-10 47 daphnite 28.97 28.97 0.00 0.000 -0.60662E-11 48 chlorite-Mn 46.87 46.87 0.00 0.000 -0.24265E-10 67 diopside 16.18 16.18 0.00 0.000 0.00000E+00 68 hedenbergite 14.21 14.21 0.00 0.000 -0.30331E-11 116 microcline -2.49 -2.49 0.00 0.000 -0.10616E-10 163 stilbite -7.52 -7.52 0.00 0.000 -0.33364E-10 164 stilpnomelane-Fe 13.02 13.02 0.00 0.000 0.21232E-10 245 tr.625ac.25prg.125 45.16 45.16 0.00 0.000 0.12132E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -16.82 -10.16 -3.385 0.17342E+05 -8.457 3 CH4,gas 4.54 1.12 -3.43 -0.857 0.58521E+04 -1.728 4 H2,gas 8.00 4.48 -3.52 -2.009 0.60044E+04 -1.818 5 H2S,gas -6.23 -14.79 -8.56 -4.279 0.14614E+05 -6.860 6 S2,gas -7.34 -38.54 -31.21 -4.801 0.53288E+05 -29.510 7 CO,gas 3.21 -12.33 -15.55 -4.784 0.26548E+05 -13.849 8 SO3,gas 17.12 -32.72 -49.84 -12.461 0.85105E+05 -48.144 9 SO2,gas 0.83 -28.24 -29.07 -7.752 0.49637E+05 -27.372 10 HCl,gas 5.19 -14.06 -19.25 -9.623 0.32864E+05 -17.548 11 acmite 7.71 6.53 -1.18 -0.123 0.20183E+04 15 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 19 spessartine 24.46 19.69 -4.77 -0.238 0.81382E+04 20 analcite 3.32 2.77 -0.55 -0.061 0.93598E+03 26 annite 20.12 17.72 -2.40 -0.134 0.41061E+04 27 phlogopite 27.06 25.40 -1.67 -0.093 0.28480E+04 29 anorthite 12.71 8.27 -4.44 -0.342 0.75890E+04 35 aragonite 0.97 -3.71 -4.68 -1.560 0.79926E+04 36 brucite 12.57 9.29 -3.27 -0.655 0.55906E+04 37 calcite 0.81 -3.71 -4.53 -1.509 0.77284E+04 38 carnegieite-low 9.02 5.93 -3.09 -0.442 0.52796E+04 39 carnegieite-high 10.09 5.93 -4.16 -0.595 0.71066E+04 40 carpholite-Mg 8.58 4.46 -4.12 -0.275 0.70415E+04 41 carpholite-Fe 6.71 1.90 -4.81 -0.321 0.82195E+04 42 celadonite 5.34 3.65 -1.69 -0.099 0.28878E+04 43 celadonite-Fe 3.88 1.09 -2.79 -0.164 0.47562E+04 44 chrysotile 23.89 21.57 -2.32 -0.194 0.39689E+04 49 chlorite-Al-free 47.17 43.14 -4.04 -0.168 0.68929E+04 51 chloritoid-Fe 9.17 5.06 -4.12 -0.274 0.70301E+04 52 chloritoid-Mn 11.40 7.55 -3.85 -0.257 0.65763E+04 54 coesite -2.38 -3.16 -0.78 -0.260 0.13344E+04 61 cristobalite -2.56 -3.16 -0.60 -0.199 0.10197E+04 63 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71234E+04 65 diaspore 2.87 0.74 -2.13 -0.356 0.36442E+04 66 diamond -3.10 -7.85 -4.75 -1.356 0.81065E+04 71 enstatite 17.26 12.27 -4.99 -0.499 0.85225E+04 73 clinoenstatite 17.17 12.27 -4.89 -0.489 0.83541E+04 75 epidote 24.67 22.70 -1.97 -0.095 0.33574E+04 76 clinozoisite 22.81 18.95 -3.86 -0.175 0.65847E+04 77 epidote-Fe 29.84 26.46 -3.38 -0.176 0.57767E+04 78 fayalite 14.05 10.31 -3.73 -0.533 0.63744E+04 79 ferrosilite 11.15 7.15 -3.99 -0.399 0.68205E+04 83 gibbsite 4.08 0.74 -3.34 -0.477 0.57027E+04 84 glaucophane 22.97 20.80 -2.17 -0.059 0.37130E+04 85 glaucophane-Fe 17.28 13.12 -4.15 -0.112 0.70921E+04 86 graphite -3.55 -7.85 -4.30 -1.230 0.73488E+04 87 greenalite 16.14 13.89 -2.25 -0.187 0.38410E+04 90 hematite 12.57 8.99 -3.58 -0.434 0.61115E+04 91 heulandite -5.83 -7.52 -1.69 -0.077 0.28938E+04 95 jadeite 4.22 2.77 -1.44 -0.144 0.24615E+04 97 kalsilite 7.58 3.83 -3.76 -0.536 0.64120E+04 98 kaolinite -1.33 -4.84 -3.50 -0.318 0.59821E+04 101 laumontite 2.88 1.95 -0.93 -0.062 0.15927E+04 102 lawsonite 9.62 8.27 -1.35 -0.090 0.23056E+04 103 leucite 4.12 0.67 -3.45 -0.345 0.58870E+04 105 lizardite 23.24 21.57 -1.68 -0.140 0.28615E+04 107 magnetite 20.09 15.72 -4.37 -0.356 0.74539E+04 108 minnesotaite 10.39 7.57 -2.81 -0.165 0.48035E+04 112 manganosite 14.06 9.23 -4.83 -1.207 0.82468E+04 120 muscovite 2.58 -1.01 -3.59 -0.211 0.61299E+04 121 paragonite 4.24 1.10 -3.14 -0.185 0.53690E+04 122 nepheline 8.34 5.93 -2.41 -0.344 0.41119E+04 128 periclase-Fe 11.63 6.74 -4.89 -1.223 0.83522E+04 134 phlogopite-Na 29.65 27.50 -2.15 -0.119 0.36668E+04 136 prehnite 19.37 18.21 -1.16 -0.068 0.19836E+04 137 prehnite-Fe 22.50 21.96 -0.53 -0.032 0.91124E+03 138 pumpellyite-Fe 46.27 43.89 -2.37 -0.053 0.40545E+04 139 pumpellyite-Mg 48.99 46.45 -2.54 -0.056 0.43382E+04 143 pyrrhotite -4.26 -8.05 -3.79 -1.264 0.64773E+04 144 pyrrhotiteFe0.875 -6.02 -9.45 -3.43 -1.263 0.58646E+04 145 pyroxmangite 7.40 6.07 -1.33 -0.266 0.22674E+04 146 pyrophyllite -6.18 -11.15 -4.98 -0.311 0.84956E+04 147 quartz -2.99 -3.16 -0.17 -0.056 0.28707E+03 152 rhodonite 7.45 6.07 -1.37 -0.275 0.23477E+04 153 sanidine -1.28 -2.49 -1.21 -0.093 0.20677E+04 165 stilpnomelane-Mg 27.44 25.81 -1.63 -0.049 0.27794E+04 171 talc 16.49 15.25 -1.24 -0.073 0.21142E+04 174 tephroite 18.09 15.30 -2.79 -0.398 0.47583E+04 178 tridymite -2.63 -3.16 -0.53 -0.177 0.90705E+03 179 tremolite 47.87 47.42 -0.45 -0.012 0.77503E+03 180 ferroactinolite 38.45 34.62 -3.83 -0.104 0.65459E+04 181 troilite-low -4.41 -8.05 -3.64 -1.214 0.62201E+04 183 vesuvianite 223.47 218.82 -4.65 -0.035 0.79340E+04 187 wairakite 3.95 1.95 -2.00 -0.118 0.34147E+04 188 walstromite 11.51 9.94 -1.56 -0.313 0.26718E+04 189 wollastonite 10.46 9.94 -0.52 -0.103 0.88228E+03 190 pseudo-wollastonite 11.00 9.94 -1.06 -0.211 0.18021E+04 191 zoisite 22.85 18.95 -3.90 -0.177 0.66588E+04 192 akaganeite 7.75 4.49 -3.26 -0.705 0.55683E+04 199 chalcedony -2.80 -3.16 -0.36 -0.118 0.60637E+03 201 montmorillonite-Ca -2.29 -6.17 -3.88 -0.240 0.66176E+04 202 montmorillonite-K -2.24 -6.27 -4.03 -0.247 0.68813E+04 203 montmorillonite-Mg -2.48 -6.79 -4.31 -0.267 0.73674E+04 204 montmorillonite-Na -2.04 -5.57 -3.54 -0.216 0.60362E+04 205 nontronite-Ca 3.21 -0.20 -3.41 -0.221 0.58226E+04 206 nontronite-H 2.53 -2.36 -4.89 -0.328 0.83496E+04 207 nontronite-K 3.34 -0.30 -3.64 -0.233 0.62094E+04 208 nontronite-Mg 3.07 -0.82 -3.90 -0.253 0.66564E+04 209 nontronite-Na 3.52 0.40 -3.12 -0.200 0.53303E+04 224 tobermorite 9.82 7.76 -2.07 -0.564 0.35288E+04 230 alabandite -0.98 -5.56 -4.58 -1.528 0.78248E+04 233 boehmite 4.41 0.74 -3.67 -0.611 0.62611E+04 235 ferrous-oxide 9.81 6.74 -3.08 -0.769 0.52531E+04 240 silica-amorphous -2.09 -3.16 -1.07 -0.355 0.18205E+04 242 an20ab80 2.02 1.35 -0.67 -0.052 0.11469E+04 243 an25ab75 2.65 1.78 -0.87 -0.067 0.14807E+04 244 an30ab70 3.28 2.21 -1.07 -0.082 0.18240E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 10.0000000 g Current total amount of reactant added: 269.9990000 g New total amount of reactant added: 279.9990000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.3649E-11 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 11 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 279.9990000 Water: Moles liquid = 0.5386E+02 kg liquid = 0.9703E+00 Moles total = 0.5200E+02 kg total = 0.9368E+00 Activity = 1.0000 Stoichiometric ionic strength = .1131991E-01 Osmotic coef. = 0.9695 True ionic strength = .2000906E-01 Chg. balance for total moles = 0.3649E-11 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.88252E-10 -10.0543 0.74156E-10 -10.1299 0.84028E+00 -0.0756 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.14154E-03 -3.8491 0.11822E-03 -3.9273 0.83522E+00 -0.0782 4 SO4-- 0.66548E-12 -12.1769 0.34563E-12 -12.4614 0.51937E+00 -0.2845 5 HCO3- 0.24631E-06 -6.6085 0.20602E-06 -6.6861 0.83645E+00 -0.0776 6 HS- 0.26279E-04 -4.5804 0.21952E-04 -4.6585 0.83535E+00 -0.0781 7 Al+++ 0.96844E-29 -29.0139 0.22380E-29 -29.6501 0.23110E+00 -0.6362 8 H4SiO4 0.69574E-03 -3.1576 0.69574E-03 -3.1576 0.10000E+01 0.0000 9 Ca++ 0.13490E-06 -6.8700 0.69547E-07 -7.1577 0.51556E+00 -0.2877 10 Mg++ 0.21104E-10 -10.6756 0.10831E-10 -10.9653 0.51320E+00 -0.2897 11 Fe++ 0.58152E-13 -13.2354 0.29877E-13 -13.5247 0.51376E+00 -0.2892 12 K+ 0.15644E-03 -3.8056 0.13089E-03 -3.8831 0.83664E+00 -0.0775 13 Na+ 0.19852E-01 -1.7022 0.16578E-01 -1.7805 0.83507E+00 -0.0783 14 Mn++ 0.18112E-10 -10.7420 0.93128E-11 -11.0309 0.51419E+00 -0.2889 15 HPO4-- 0.45328E-07 -7.3436 0.23545E-07 -7.6281 0.51944E+00 -0.2845 16 HSiO3- 0.10489E-01 -1.9793 0.87604E-02 -2.0575 0.83522E+00 -0.0782 17 Ca(HSiO3)+ 0.16581E-07 -7.7804 0.13875E-07 -7.8578 0.83682E+00 -0.0774 18 Mg(HSiO3)+ 0.32135E-11 -11.4930 0.26892E-11 -11.5704 0.83682E+00 -0.0774 19 NaHSiO3,aq 0.23488E-02 -2.6291 0.23488E-02 -2.6291 0.10000E+01 0.0000 20 AlO+ 0.66163E-16 -16.1794 0.55367E-16 -16.2568 0.83682E+00 -0.0774 22 HAlO2,aq 0.14869E-09 -9.8277 0.14869E-09 -9.8277 0.10000E+01 0.0000 23 AlO2- 0.53236E-05 -5.2738 0.44384E-05 -5.3528 0.83372E+00 -0.0790 24 CH4,aq 0.12755E-04 -4.8943 0.12711E-04 -4.8958 0.99655E+00 -0.0015 25 C2H6,aq 0.23909E-14 -14.6214 0.23826E-14 -14.6229 0.99655E+00 -0.0015 29 CO,aq 0.95064E-17 -17.0220 0.95064E-17 -17.0220 0.10000E+01 0.0000 30 CO2,aq 0.32759E-10 -10.4847 0.32645E-10 -10.4862 0.99655E+00 -0.0015 31 CO3-2 0.46823E-06 -6.3295 0.24267E-06 -6.6150 0.51827E+00 -0.2854 32 CaCO3,aq 0.21162E-09 -9.6744 0.21162E-09 -9.6744 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.43707E-12 -12.3595 0.36575E-12 -12.4368 0.83682E+00 -0.0774 34 CaCl+ 0.15900E-10 -10.7986 0.13305E-10 -10.8760 0.83682E+00 -0.0774 35 CaCl2,aq 0.37370E-15 -15.4275 0.37370E-15 -15.4275 0.10000E+01 0.0000 36 CaOH+ 0.79873E-07 -7.0976 0.66840E-07 -7.1750 0.83682E+00 -0.0774 37 CaSO4,aq 0.76331E-17 -17.1173 0.76331E-17 -17.1173 0.10000E+01 0.0000 38 HCl,aq 0.16064E-14 -14.7941 0.16064E-14 -14.7941 0.10000E+01 0.0000 43 FeCl+ 0.66806E-17 -17.1752 0.55905E-17 -17.2525 0.83682E+00 -0.0774 46 FeO,aq 0.21116E-09 -9.6754 0.21116E-09 -9.6754 0.10000E+01 0.0000 47 FeOH+ 0.15672E-10 -10.8049 0.13114E-10 -10.8823 0.83682E+00 -0.0774 48 HFeO2- 0.35671E-07 -7.4477 0.29793E-07 -7.5259 0.83522E+00 -0.0782 49 FeO+ 0.10979E-16 -16.9594 0.91874E-17 -17.0368 0.83682E+00 -0.0774 51 FeO2- 0.40930E-09 -9.3880 0.34186E-09 -9.4662 0.83522E+00 -0.0782 52 HFeO2,aq 0.32243E-11 -11.4916 0.32243E-11 -11.4916 0.10000E+01 0.0000 53 H2,aq 0.11632E-04 -4.9343 0.11592E-04 -4.9358 0.99655E+00 -0.0015 54 KCl,aq 0.28044E-09 -9.5522 0.28044E-09 -9.5522 0.10000E+01 0.0000 56 KOH,aq 0.75376E-06 -6.1228 0.75376E-06 -6.1228 0.10000E+01 0.0000 57 KSO4- 0.84048E-15 -15.0755 0.70199E-15 -15.1537 0.83522E+00 -0.0782 58 MgCO3,aq 0.82606E-14 -14.0830 0.82606E-14 -14.0830 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.69550E-16 -16.1577 0.58201E-16 -16.2351 0.83682E+00 -0.0774 60 MgCl+ 0.22442E-14 -14.6489 0.18780E-14 -14.7263 0.83682E+00 -0.0774 61 MgOH+ 0.68830E-10 -10.1622 0.57599E-10 -10.2396 0.83682E+00 -0.0774 63 MnO,aq 0.17538E-08 -8.7560 0.17538E-08 -8.7560 0.10000E+01 0.0000 64 MnOH+ 0.45380E-09 -9.3431 0.37975E-09 -9.4205 0.83682E+00 -0.0774 65 MnO2-2 0.20422E-10 -10.6899 0.10584E-10 -10.9753 0.51827E+00 -0.2854 66 HMnO2- 0.20588E-09 -9.6864 0.17195E-09 -9.7646 0.83522E+00 -0.0782 69 MnCl+ 0.81015E-14 -14.0914 0.67795E-14 -14.1688 0.83682E+00 -0.0774 71 NaCl,aq 0.64947E-06 -6.1874 0.64947E-06 -6.1874 0.10000E+01 0.0000 72 NaOH,aq 0.96048E-04 -4.0175 0.96048E-04 -4.0175 0.10000E+01 0.0000 74 OH- 0.93453E-02 -2.0294 0.77913E-02 -2.1084 0.83372E+00 -0.0790 79 HPO3-2 0.16412E-14 -14.7848 0.85057E-15 -15.0703 0.51827E+00 -0.2854 81 H2PO3- 0.15144E-18 -18.8198 0.12648E-18 -18.8980 0.83522E+00 -0.0782 82 H3PO4,aq 0.90556E-18 -18.0431 0.90556E-18 -18.0431 0.10000E+01 0.0000 83 H2PO4- 0.38527E-10 -10.4142 0.32209E-10 -10.4920 0.83602E+00 -0.0778 84 PO4-3 0.10673E-08 -8.9717 0.25905E-09 -9.5866 0.24271E+00 -0.6149 88 HP2O7-3 0.94687E-18 -18.0237 0.21904E-18 -18.6595 0.23133E+00 -0.6358 89 P2O7-4 0.91468E-17 -17.0387 0.70563E-18 -18.1514 0.77145E-01 -1.1127 90 H2S,aq 0.50486E-08 -8.2968 0.50311E-08 -8.2983 0.99655E+00 -0.0015 91 S2-2 0.17773E-14 -14.7502 0.92112E-15 -15.0357 0.51827E+00 -0.2854 97 SO3-2 0.99029E-18 -18.0042 0.52066E-18 -18.2834 0.52576E+00 -0.2792 99 HSO4- 0.29489E-19 -19.5303 0.24701E-19 -19.6073 0.83764E+00 -0.0769 Charge balance for all species = 0.3761E-11 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.8825216E-10 -.2230446E-01 -.2244250E+02 0.0000 2 H2O 0.1000000E+01 0.5550489E+02 0.9982002E+06 0.0000 3 Cl- 0.1415407E-03 0.1421905E-03 0.5032322E+01 6.2025 4 SO4-- 0.6654848E-12 -.1566262E-04 -.1501962E+01 7.7983 5 HCO3- 0.2463096E-06 0.1346940E-04 0.8204374E+00 3.4438 6 HS- 0.2627880E-04 0.4194647E-04 0.1384844E+01 5.4713 7 Al+++ 0.9684407E-29 0.5323773E-05 0.1433938E+00 0.7394 8 H4SiO4 0.6957360E-03 0.1353326E-01 0.1298495E+04 -3.1576 9 Ca++ 0.1348963E-06 0.2315781E-06 0.9265064E-02 13.1020 10 Mg++ 0.2110425E-10 0.9315874E-10 0.2260941E-05 9.2944 11 Fe++ 0.5815243E-13 0.3631022E-07 0.2024294E-02 6.7350 12 K+ 0.1564413E-03 0.1571953E-03 0.6135975E+01 6.2467 13 Na+ 0.1985160E-01 0.2229712E-01 0.5117159E+03 8.3494 14 Mn++ 0.1811161E-10 0.2452013E-08 0.1344747E-03 9.2288 15 HPO4-- 0.4532771E-07 0.4643355E-07 0.4448904E-02 12.6316 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.4636355E+01 -.2164307E-01 -.4614712E+01 0.0000000E+00 2 H2O 0.5199835E+02 0.5385903E+02 -.1860685E+01 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.7785231E-02 -.1519818E-04 0.7800429E-02 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.7759727E-02 0.4070265E-04 -.7800429E-02 0.0000000E+00 7 Al+++ 0.9130044E+00 0.5165910E-05 0.9129992E+00 0.0000000E+00 8 H4SiO4 0.2915569E+01 0.1313197E-01 0.2902437E+01 0.0000000E+00 9 Ca++ 0.3220533E+00 0.2247112E-06 0.3220530E+00 0.0000000E+00 10 Mg++ 0.2222214E+00 0.9039636E-10 0.2222214E+00 0.0000000E+00 11 Fe++ 0.1996417E+00 0.3523353E-07 0.1996417E+00 0.0000000E+00 12 K+ 0.5944777E-01 0.1525341E-03 0.5929524E-01 0.0000000E+00 13 Na+ 0.3516270E+00 0.2163596E-01 0.3299911E+00 0.0000000E+00 14 Mn++ 0.4854790E-02 0.2379305E-08 0.4854787E-02 0.0000000E+00 15 HPO4-- 0.1656916E-02 0.4505669E-07 0.1656870E-02 0.0000000E+00 Chg. balance for solid moles: 0.1207E-14 Mass of aqueous solution: 0.972036E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 279.9990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 0.3296 -0.482 86.43 1.937 28.27 33.18 andradite 0.3120E-01 -1.506 15.86 1.200 5.187 4.120 grossular 0.7565E-02 -2.121 3.408 0.532 1.115 0.9482 apatite-OH 0.5523E-03 -3.258 0.2774 -0.557 0.9075E-01 0.8816E-01 clinochlore 0.4098E-01 -1.387 22.78 1.358 7.451 8.664 daphnite 0.1186E-01 -1.926 8.463 0.928 2.768 2.565 chlorite-Mn 0.9710E-03 -3.013 0.6884 -0.162 0.2252 0.2194 diopside 0.5970E-02 -2.224 1.293 0.112 0.4229 0.3951 hedenbergite 0.1548E-02 -2.810 0.3840 -0.416 0.1256 0.1052 microcline 0.5205E-01 -1.284 14.49 1.161 4.739 5.659 stilbite 0.1892 -0.723 133.3 2.125 43.62 62.19 stilpnomelane-Fe 0.1449E-01 -1.839 15.63 1.194 5.111 5.397 tr.625ac.25prg.125 0.3129E-02 -2.505 2.675 0.427 0.8749 0.8608 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8049E+00 0.8049E+00 1.0000 -0.094 grossular 0.1951E+00 0.1951E+00 1.0000 -0.710 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.7615E+00 0.7615E+00 1.0000 -0.118 daphnite 0.2204E+00 0.2204E+00 1.0000 -0.657 chlorite-Mn 0.1804E-01 0.1804E-01 1.0000 -1.744 diopside 0.7941E+00 0.7941E+00 1.0000 -0.100 hedenbergite 0.2059E+00 0.2059E+00 1.0000 -0.686 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 tr.625ac.25prg.125 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 305.706651 g Volume = 124.393235 cm3 Porosity: -10.0829% V(tot) - V(min): -.11394E+02 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 279.9990000 g log = 2.4472 Original solution: 1000.0103000 g Original solution / Rock added: 3.57 (Water/Rock Ratio), log = 0.5528 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0545 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9681E+00 0.9855 0.1006E+01 0.1021E+01 CO2,gas 0.3289E-08 1.0069 0.3493E-08 0.3469E-08 CH4,gas 0.1752E-01 1.0125 0.1871E-01 0.1848E-01 H2,gas 0.1442E-01 1.0006 0.1522E-01 0.1521E-01 H2S,gas 0.1317E-06 0.9959 0.1383E-06 0.1389E-06 S2,gas 0.2940E-29 1.0000 0.3100E-29 0.3100E-29 CO,gas 0.1343E-13 1.0000 0.1417E-13 0.1417E-13 SO3,gas 0.6815E-48 1.0000 0.7187E-48 0.7187E-48 SO2,gas 0.4035E-27 1.0000 0.4255E-27 0.4255E-27 HCl,gas 0.2688E-17 1.0000 0.2835E-17 0.2835E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 16 albite -0.38 -0.38 0.00 0.000 -0.94784E-12 22 andradite 39.01 39.01 0.00 0.000 -0.12132E-10 23 grossular 32.73 32.73 0.00 0.000 0.00000E+00 32 apatite-OH -18.15 -18.15 0.00 0.000 0.00000E+00 46 clinochlore 39.07 39.07 0.00 0.000 0.00000E+00 47 daphnite 28.97 28.97 0.00 0.000 -0.18198E-10 48 chlorite-Mn 46.87 46.87 0.00 0.000 -0.24265E-10 67 diopside 16.18 16.18 0.00 0.000 0.00000E+00 68 hedenbergite 14.21 14.21 0.00 0.000 -0.30331E-11 116 microcline -2.49 -2.49 0.00 0.000 0.15165E-11 163 stilbite -7.52 -7.52 0.00 0.000 -0.90992E-11 164 stilpnomelane-Fe 13.02 13.02 0.00 0.000 0.21232E-10 245 tr.625ac.25prg.125 45.16 45.16 0.00 0.000 -0.12132E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -16.82 -10.16 -3.385 0.17341E+05 -8.457 3 CH4,gas 4.54 1.12 -3.43 -0.857 0.58514E+04 -1.728 4 H2,gas 8.00 4.48 -3.52 -2.009 0.60045E+04 -1.818 5 H2S,gas -6.23 -14.79 -8.56 -4.279 0.14613E+05 -6.859 6 S2,gas -7.34 -38.54 -31.21 -4.801 0.53286E+05 -29.509 7 CO,gas 3.21 -12.33 -15.55 -4.784 0.26547E+05 -13.849 8 SO3,gas 17.12 -32.72 -49.84 -12.461 0.85105E+05 -48.143 9 SO2,gas 0.83 -28.24 -29.07 -7.752 0.49636E+05 -27.371 10 HCl,gas 5.19 -14.06 -19.25 -9.623 0.32863E+05 -17.548 11 acmite 7.71 6.53 -1.18 -0.123 0.20182E+04 15 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 19 spessartine 24.46 19.69 -4.76 -0.238 0.81357E+04 20 analcite 3.32 2.77 -0.55 -0.061 0.93599E+03 26 annite 20.12 17.72 -2.40 -0.134 0.41061E+04 27 phlogopite 27.06 25.40 -1.67 -0.093 0.28481E+04 29 anorthite 12.71 8.27 -4.44 -0.342 0.75890E+04 35 aragonite 0.97 -3.71 -4.68 -1.560 0.79918E+04 36 brucite 12.57 9.29 -3.27 -0.655 0.55906E+04 37 calcite 0.81 -3.71 -4.53 -1.509 0.77276E+04 38 carnegieite-low 9.02 5.93 -3.09 -0.442 0.52796E+04 39 carnegieite-high 10.09 5.93 -4.16 -0.595 0.71066E+04 40 carpholite-Mg 8.58 4.46 -4.12 -0.275 0.70416E+04 41 carpholite-Fe 6.71 1.90 -4.81 -0.321 0.82195E+04 42 celadonite 5.34 3.65 -1.69 -0.099 0.28878E+04 43 celadonite-Fe 3.88 1.09 -2.79 -0.164 0.47562E+04 44 chrysotile 23.89 21.57 -2.32 -0.194 0.39689E+04 49 chlorite-Al-free 47.17 43.14 -4.04 -0.168 0.68929E+04 51 chloritoid-Fe 9.17 5.06 -4.12 -0.274 0.70302E+04 52 chloritoid-Mn 11.40 7.55 -3.85 -0.257 0.65755E+04 54 coesite -2.38 -3.16 -0.78 -0.260 0.13344E+04 61 cristobalite -2.56 -3.16 -0.60 -0.199 0.10197E+04 63 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71234E+04 65 diaspore 2.87 0.74 -2.13 -0.356 0.36442E+04 66 diamond -3.10 -7.85 -4.75 -1.356 0.81057E+04 71 enstatite 17.26 12.27 -4.99 -0.499 0.85225E+04 73 clinoenstatite 17.17 12.27 -4.89 -0.489 0.83541E+04 75 epidote 24.67 22.70 -1.97 -0.095 0.33574E+04 76 clinozoisite 22.81 18.95 -3.86 -0.175 0.65848E+04 77 epidote-Fe 29.84 26.46 -3.38 -0.176 0.57767E+04 78 fayalite 14.05 10.31 -3.73 -0.533 0.63744E+04 79 ferrosilite 11.15 7.15 -3.99 -0.399 0.68205E+04 83 gibbsite 4.08 0.74 -3.34 -0.477 0.57028E+04 84 glaucophane 22.97 20.80 -2.17 -0.059 0.37130E+04 85 glaucophane-Fe 17.28 13.12 -4.15 -0.112 0.70921E+04 86 graphite -3.55 -7.85 -4.30 -1.230 0.73479E+04 87 greenalite 16.14 13.89 -2.25 -0.187 0.38410E+04 90 hematite 12.57 8.99 -3.58 -0.434 0.61115E+04 91 heulandite -5.83 -7.52 -1.69 -0.077 0.28938E+04 95 jadeite 4.22 2.77 -1.44 -0.144 0.24615E+04 97 kalsilite 7.58 3.83 -3.76 -0.536 0.64121E+04 98 kaolinite -1.33 -4.84 -3.50 -0.318 0.59821E+04 101 laumontite 2.88 1.95 -0.93 -0.062 0.15927E+04 102 lawsonite 9.62 8.27 -1.35 -0.090 0.23057E+04 103 leucite 4.12 0.67 -3.45 -0.345 0.58870E+04 105 lizardite 23.24 21.57 -1.68 -0.140 0.28615E+04 107 magnetite 20.09 15.72 -4.37 -0.356 0.74539E+04 108 minnesotaite 10.39 7.57 -2.81 -0.165 0.48035E+04 112 manganosite 14.06 9.23 -4.83 -1.207 0.82459E+04 120 muscovite 2.58 -1.01 -3.59 -0.211 0.61300E+04 121 paragonite 4.24 1.09 -3.14 -0.185 0.53691E+04 122 nepheline 8.34 5.93 -2.41 -0.344 0.41120E+04 128 periclase-Fe 11.63 6.74 -4.89 -1.223 0.83522E+04 134 phlogopite-Na 29.65 27.50 -2.15 -0.119 0.36669E+04 136 prehnite 19.37 18.21 -1.16 -0.068 0.19836E+04 137 prehnite-Fe 22.50 21.96 -0.53 -0.032 0.91125E+03 138 pumpellyite-Fe 46.27 43.89 -2.37 -0.053 0.40547E+04 139 pumpellyite-Mg 48.99 46.45 -2.54 -0.056 0.43383E+04 143 pyrrhotite -4.26 -8.05 -3.79 -1.264 0.64765E+04 144 pyrrhotiteFe0.875 -6.02 -9.45 -3.43 -1.263 0.58638E+04 145 pyroxmangite 7.40 6.07 -1.33 -0.265 0.22666E+04 146 pyrophyllite -6.18 -11.15 -4.98 -0.311 0.84957E+04 147 quartz -2.99 -3.16 -0.17 -0.056 0.28706E+03 152 rhodonite 7.45 6.07 -1.37 -0.275 0.23468E+04 153 sanidine -1.28 -2.49 -1.21 -0.093 0.20677E+04 165 stilpnomelane-Mg 27.44 25.81 -1.63 -0.049 0.27794E+04 171 talc 16.49 15.25 -1.24 -0.073 0.21142E+04 174 tephroite 18.09 15.30 -2.79 -0.398 0.47566E+04 178 tridymite -2.63 -3.16 -0.53 -0.177 0.90704E+03 179 tremolite 47.87 47.42 -0.45 -0.012 0.77503E+03 180 ferroactinolite 38.45 34.62 -3.83 -0.104 0.65459E+04 181 troilite-low -4.41 -8.05 -3.64 -1.214 0.62193E+04 183 vesuvianite 223.47 218.82 -4.65 -0.035 0.79344E+04 187 wairakite 3.95 1.95 -2.00 -0.118 0.34147E+04 188 walstromite 11.51 9.94 -1.56 -0.313 0.26718E+04 189 wollastonite 10.46 9.94 -0.52 -0.103 0.88228E+03 190 pseudo-wollastonite 11.00 9.94 -1.06 -0.211 0.18021E+04 191 zoisite 22.85 18.95 -3.90 -0.177 0.66588E+04 192 akaganeite 7.75 4.49 -3.26 -0.705 0.55683E+04 199 chalcedony -2.80 -3.16 -0.36 -0.118 0.60636E+03 201 montmorillonite-Ca -2.29 -6.17 -3.88 -0.240 0.66176E+04 202 montmorillonite-K -2.24 -6.27 -4.03 -0.247 0.68813E+04 203 montmorillonite-Mg -2.48 -6.79 -4.31 -0.267 0.73674E+04 204 montmorillonite-Na -2.04 -5.57 -3.54 -0.216 0.60362E+04 205 nontronite-Ca 3.21 -0.20 -3.41 -0.221 0.58225E+04 206 nontronite-H 2.53 -2.36 -4.89 -0.328 0.83496E+04 207 nontronite-K 3.34 -0.30 -3.64 -0.233 0.62094E+04 208 nontronite-Mg 3.07 -0.82 -3.90 -0.253 0.66564E+04 209 nontronite-Na 3.52 0.40 -3.12 -0.200 0.53303E+04 224 tobermorite 9.82 7.76 -2.07 -0.564 0.35288E+04 230 alabandite -0.98 -5.56 -4.58 -1.527 0.78232E+04 233 boehmite 4.41 0.74 -3.67 -0.611 0.62611E+04 235 ferrous-oxide 9.81 6.74 -3.08 -0.769 0.52531E+04 240 silica-amorphous -2.09 -3.16 -1.07 -0.355 0.18205E+04 242 an20ab80 2.02 1.35 -0.67 -0.052 0.11470E+04 243 an25ab75 2.65 1.78 -0.87 -0.067 0.14807E+04 244 an30ab70 3.28 2.21 -1.07 -0.082 0.18240E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 10.0000000 g Current total amount of reactant added: 279.9990000 g New total amount of reactant added: 289.9990000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.3649E-11 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 11 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 289.9990000 Water: Moles liquid = 0.5381E+02 kg liquid = 0.9693E+00 Moles total = 0.5187E+02 kg total = 0.9345E+00 Activity = 1.0000 Stoichiometric ionic strength = .1132008E-01 Osmotic coef. = 0.9695 True ionic strength = .2000922E-01 Chg. balance for total moles = 0.3649E-11 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.88253E-10 -10.0543 0.74157E-10 -10.1298 0.84027E+00 -0.0756 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.14169E-03 -3.8487 0.11834E-03 -3.9269 0.83522E+00 -0.0782 4 SO4-- 0.66625E-12 -12.1764 0.34603E-12 -12.4609 0.51937E+00 -0.2845 5 HCO3- 0.24659E-06 -6.6080 0.20626E-06 -6.6856 0.83645E+00 -0.0776 6 HS- 0.26306E-04 -4.5799 0.21975E-04 -4.6581 0.83535E+00 -0.0781 7 Al+++ 0.96843E-29 -29.0139 0.22380E-29 -29.6501 0.23109E+00 -0.6362 8 H4SiO4 0.69574E-03 -3.1576 0.69574E-03 -3.1576 0.10000E+01 0.0000 9 Ca++ 0.13490E-06 -6.8700 0.69547E-07 -7.1577 0.51556E+00 -0.2877 10 Mg++ 0.21104E-10 -10.6756 0.10831E-10 -10.9653 0.51320E+00 -0.2897 11 Fe++ 0.58153E-13 -13.2354 0.29877E-13 -13.5247 0.51376E+00 -0.2892 12 K+ 0.15644E-03 -3.8056 0.13089E-03 -3.8831 0.83664E+00 -0.0775 13 Na+ 0.19852E-01 -1.7022 0.16578E-01 -1.7805 0.83507E+00 -0.0783 14 Mn++ 0.18131E-10 -10.7416 0.93228E-11 -11.0305 0.51419E+00 -0.2889 15 HPO4-- 0.45328E-07 -7.3436 0.23545E-07 -7.6281 0.51944E+00 -0.2845 16 HSiO3- 0.10489E-01 -1.9793 0.87604E-02 -2.0575 0.83522E+00 -0.0782 17 Ca(HSiO3)+ 0.16581E-07 -7.7804 0.13875E-07 -7.8578 0.83682E+00 -0.0774 18 Mg(HSiO3)+ 0.32136E-11 -11.4930 0.26892E-11 -11.5704 0.83682E+00 -0.0774 19 NaHSiO3,aq 0.23489E-02 -2.6291 0.23489E-02 -2.6291 0.10000E+01 0.0000 20 AlO+ 0.66161E-16 -16.1794 0.55365E-16 -16.2568 0.83682E+00 -0.0774 22 HAlO2,aq 0.14868E-09 -9.8277 0.14868E-09 -9.8277 0.10000E+01 0.0000 23 AlO2- 0.53234E-05 -5.2738 0.44382E-05 -5.3528 0.83372E+00 -0.0790 24 CH4,aq 0.12768E-04 -4.8939 0.12724E-04 -4.8954 0.99655E+00 -0.0015 25 C2H6,aq 0.23959E-14 -14.6205 0.23876E-14 -14.6220 0.99655E+00 -0.0015 29 CO,aq 0.95171E-17 -17.0215 0.95171E-17 -17.0215 0.10000E+01 0.0000 30 CO2,aq 0.32796E-10 -10.4842 0.32683E-10 -10.4857 0.99655E+00 -0.0015 31 CO3-2 0.46876E-06 -6.3290 0.24294E-06 -6.6145 0.51827E+00 -0.2854 32 CaCO3,aq 0.21186E-09 -9.6740 0.21186E-09 -9.6740 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.43756E-12 -12.3590 0.36616E-12 -12.4363 0.83682E+00 -0.0774 34 CaCl+ 0.15916E-10 -10.7982 0.13319E-10 -10.8755 0.83682E+00 -0.0774 35 CaCl2,aq 0.37447E-15 -15.4266 0.37447E-15 -15.4266 0.10000E+01 0.0000 36 CaOH+ 0.79873E-07 -7.0976 0.66839E-07 -7.1750 0.83682E+00 -0.0774 37 CaSO4,aq 0.76419E-17 -17.1168 0.76419E-17 -17.1168 0.10000E+01 0.0000 38 HCl,aq 0.16081E-14 -14.7937 0.16081E-14 -14.7937 0.10000E+01 0.0000 43 FeCl+ 0.66876E-17 -17.1747 0.55963E-17 -17.2521 0.83682E+00 -0.0774 46 FeO,aq 0.21115E-09 -9.6754 0.21115E-09 -9.6754 0.10000E+01 0.0000 47 FeOH+ 0.15672E-10 -10.8049 0.13114E-10 -10.8822 0.83682E+00 -0.0774 48 HFeO2- 0.35670E-07 -7.4477 0.29793E-07 -7.5259 0.83522E+00 -0.0782 49 FeO+ 0.10979E-16 -16.9594 0.91876E-17 -17.0368 0.83682E+00 -0.0774 51 FeO2- 0.40930E-09 -9.3880 0.34186E-09 -9.4661 0.83522E+00 -0.0782 52 HFeO2,aq 0.32243E-11 -11.4916 0.32243E-11 -11.4916 0.10000E+01 0.0000 53 H2,aq 0.11632E-04 -4.9344 0.11592E-04 -4.9359 0.99655E+00 -0.0015 54 KCl,aq 0.28073E-09 -9.5517 0.28073E-09 -9.5517 0.10000E+01 0.0000 56 KOH,aq 0.75376E-06 -6.1228 0.75376E-06 -6.1228 0.10000E+01 0.0000 57 KSO4- 0.84145E-15 -15.0750 0.70280E-15 -15.1532 0.83522E+00 -0.0782 58 MgCO3,aq 0.82700E-14 -14.0825 0.82700E-14 -14.0825 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.69630E-16 -16.1572 0.58268E-16 -16.2346 0.83682E+00 -0.0774 60 MgCl+ 0.22465E-14 -14.6485 0.18800E-14 -14.7259 0.83682E+00 -0.0774 61 MgOH+ 0.68830E-10 -10.1622 0.57599E-10 -10.2396 0.83682E+00 -0.0774 63 MnO,aq 0.17557E-08 -8.7556 0.17557E-08 -8.7556 0.10000E+01 0.0000 64 MnOH+ 0.45428E-09 -9.3427 0.38016E-09 -9.4200 0.83682E+00 -0.0774 65 MnO2-2 0.20444E-10 -10.6894 0.10595E-10 -10.9749 0.51827E+00 -0.2854 66 HMnO2- 0.20609E-09 -9.6859 0.17214E-09 -9.7641 0.83522E+00 -0.0782 69 MnCl+ 0.81186E-14 -14.0905 0.67939E-14 -14.1679 0.83682E+00 -0.0774 71 NaCl,aq 0.65015E-06 -6.1870 0.65015E-06 -6.1870 0.10000E+01 0.0000 72 NaOH,aq 0.96047E-04 -4.0175 0.96047E-04 -4.0175 0.10000E+01 0.0000 74 OH- 0.93452E-02 -2.0294 0.77913E-02 -2.1084 0.83372E+00 -0.0790 79 HPO3-2 0.16411E-14 -14.7849 0.85055E-15 -15.0703 0.51827E+00 -0.2854 81 H2PO3- 0.15143E-18 -18.8198 0.12648E-18 -18.8980 0.83522E+00 -0.0782 82 H3PO4,aq 0.90558E-18 -18.0431 0.90558E-18 -18.0431 0.10000E+01 0.0000 83 H2PO4- 0.38528E-10 -10.4142 0.32210E-10 -10.4920 0.83602E+00 -0.0778 84 PO4-3 0.10673E-08 -8.9717 0.25905E-09 -9.5866 0.24271E+00 -0.6149 88 HP2O7-3 0.94689E-18 -18.0237 0.21904E-18 -18.6595 0.23133E+00 -0.6358 89 P2O7-4 0.91470E-17 -17.0387 0.70564E-18 -18.1514 0.77144E-01 -1.1127 90 H2S,aq 0.50538E-08 -8.2964 0.50364E-08 -8.2979 0.99655E+00 -0.0015 91 S2-2 0.17810E-14 -14.7493 0.92305E-15 -15.0348 0.51827E+00 -0.2854 97 SO3-2 0.99140E-18 -18.0038 0.52124E-18 -18.2830 0.52576E+00 -0.2792 99 HSO4- 0.29523E-19 -19.5298 0.24729E-19 -19.6068 0.83764E+00 -0.0769 Charge balance for all species = 0.3764E-11 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.8825289E-10 -.2230447E-01 -.2244252E+02 0.0000 2 H2O 0.1000000E+01 0.5550489E+02 0.9982002E+06 0.0000 3 Cl- 0.1416873E-03 0.1423378E-03 0.5037535E+01 6.2030 4 SO4-- 0.6662478E-12 -.1567567E-04 -.1503215E+01 7.7988 5 HCO3- 0.2465903E-06 0.1348336E-04 0.8212874E+00 3.4443 6 HS- 0.2630603E-04 0.4198676E-04 0.1386174E+01 5.4718 7 Al+++ 0.9684320E-29 0.5323537E-05 0.1433875E+00 0.7394 8 H4SiO4 0.6957446E-03 0.1353335E-01 0.1298504E+04 -3.1576 9 Ca++ 0.1348969E-06 0.2315788E-06 0.9265092E-02 13.1020 10 Mg++ 0.2110432E-10 0.9315845E-10 0.2260934E-05 9.2944 11 Fe++ 0.5815317E-13 0.3630978E-07 0.2024270E-02 6.7350 12 K+ 0.1564426E-03 0.1571966E-03 0.6136024E+01 6.2467 13 Na+ 0.1985176E-01 0.2229731E-01 0.5117203E+03 8.3494 14 Mn++ 0.1813113E-10 0.2454616E-08 0.1346174E-03 9.2292 15 HPO4-- 0.4532806E-07 0.4643391E-07 0.4448939E-02 12.6316 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.4801940E+01 -.2162069E-01 -.4780319E+01 0.0000000E+00 2 H2O 0.5187299E+02 0.5380329E+02 -.1930298E+01 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.8062365E-02 -.1519511E-04 0.8077560E-02 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.8036861E-02 0.4069958E-04 -.8077560E-02 0.0000000E+00 7 Al+++ 0.9456118E+00 0.5160335E-05 0.9456066E+00 0.0000000E+00 8 H4SiO4 0.3019697E+01 0.1311846E-01 0.3006578E+01 0.0000000E+00 9 Ca++ 0.3335547E+00 0.2244793E-06 0.3335545E+00 0.0000000E+00 10 Mg++ 0.2301579E+00 0.9030252E-10 0.2301579E+00 0.0000000E+00 11 Fe++ 0.2067718E+00 0.3519664E-07 0.2067717E+00 0.0000000E+00 12 K+ 0.6157091E-01 0.1523775E-03 0.6141854E-01 0.0000000E+00 13 Na+ 0.3641795E+00 0.2161375E-01 0.3425657E+00 0.0000000E+00 14 Mn++ 0.5028176E-02 0.2379366E-08 0.5028173E-02 0.0000000E+00 15 HPO4-- 0.1716091E-02 0.4501040E-07 0.1716046E-02 0.0000000E+00 Chg. balance for solid moles: 0.7867E-15 Mass of aqueous solution: 0.971030E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 289.9990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 0.3422 -0.466 89.72 1.953 28.34 34.44 andradite 0.3231E-01 -1.491 16.42 1.215 5.186 4.266 grossular 0.7834E-02 -2.106 3.529 0.548 1.114 0.9818 apatite-OH 0.5720E-03 -3.243 0.2873 -0.542 0.9075E-01 0.9130E-01 clinochlore 0.4240E-01 -1.373 23.57 1.372 7.443 8.964 daphnite 0.1227E-01 -1.911 8.756 0.942 2.765 2.653 chlorite-Mn 0.1006E-02 -2.998 0.7130 -0.147 0.2252 0.2272 diopside 0.6514E-02 -2.186 1.411 0.149 0.4455 0.4311 hedenbergite 0.1689E-02 -2.772 0.4190 -0.378 0.1323 0.1148 microcline 0.5391E-01 -1.268 15.01 1.176 4.739 5.861 stilbite 0.1956 -0.709 137.9 2.139 43.54 64.30 stilpnomelane-Fe 0.1502E-01 -1.823 16.19 1.209 5.113 5.592 tr.625ac.25prg.125 0.3212E-02 -2.493 2.746 0.439 0.8672 0.8838 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8049E+00 0.8049E+00 1.0000 -0.094 grossular 0.1951E+00 0.1951E+00 1.0000 -0.710 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.7615E+00 0.7615E+00 1.0000 -0.118 daphnite 0.2204E+00 0.2204E+00 1.0000 -0.657 chlorite-Mn 0.1806E-01 0.1806E-01 1.0000 -1.743 diopside 0.7941E+00 0.7941E+00 1.0000 -0.100 hedenbergite 0.2059E+00 0.2059E+00 1.0000 -0.686 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 tr.625ac.25prg.125 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 316.631711 g Volume = 128.813541 cm3 Porosity: -10.0974% V(tot) - V(min): -.11814E+02 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 289.9990000 g log = 2.4624 Original solution: 1000.0103000 g Original solution / Rock added: 3.45 (Water/Rock Ratio), log = 0.5376 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0545 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9680E+00 0.9855 0.1006E+01 0.1021E+01 CO2,gas 0.3293E-08 1.0069 0.3497E-08 0.3473E-08 CH4,gas 0.1754E-01 1.0125 0.1873E-01 0.1850E-01 H2,gas 0.1442E-01 1.0006 0.1522E-01 0.1521E-01 H2S,gas 0.1318E-06 0.9959 0.1384E-06 0.1390E-06 S2,gas 0.2946E-29 1.0000 0.3106E-29 0.3106E-29 CO,gas 0.1345E-13 1.0000 0.1418E-13 0.1418E-13 SO3,gas 0.6823E-48 1.0000 0.7195E-48 0.7195E-48 SO2,gas 0.4040E-27 1.0000 0.4260E-27 0.4260E-27 HCl,gas 0.2691E-17 1.0000 0.2838E-17 0.2838E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 16 albite -0.38 -0.38 0.00 0.000 0.11184E-10 22 andradite 39.01 39.01 0.00 0.000 0.00000E+00 23 grossular 32.73 32.73 0.00 0.000 -0.12132E-10 32 apatite-OH -18.15 -18.15 0.00 0.000 0.12132E-10 46 clinochlore 39.07 39.07 0.00 0.000 0.36397E-10 47 daphnite 28.97 28.97 0.00 0.000 -0.60662E-11 48 chlorite-Mn 46.87 46.87 0.00 0.000 0.12132E-10 67 diopside 16.18 16.18 0.00 0.000 0.12132E-10 68 hedenbergite 14.21 14.21 0.00 0.000 0.00000E+00 116 microcline -2.49 -2.49 0.00 0.000 0.13649E-10 163 stilbite -7.52 -7.52 0.00 0.000 0.15165E-10 164 stilpnomelane-Fe 13.02 13.02 0.00 0.000 -0.27298E-10 245 tr.625ac.25prg.125 45.16 45.16 0.00 0.000 0.36397E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -16.82 -10.16 -3.385 0.17340E+05 -8.456 3 CH4,gas 4.54 1.12 -3.43 -0.857 0.58506E+04 -1.727 4 H2,gas 8.00 4.48 -3.52 -2.009 0.60045E+04 -1.818 5 H2S,gas -6.23 -14.79 -8.56 -4.279 0.14612E+05 -6.859 6 S2,gas -7.34 -38.54 -31.21 -4.801 0.53285E+05 -29.508 7 CO,gas 3.21 -12.33 -15.55 -4.784 0.26546E+05 -13.848 8 SO3,gas 17.12 -32.72 -49.84 -12.460 0.85104E+05 -48.143 9 SO2,gas 0.83 -28.24 -29.07 -7.752 0.49635E+05 -27.371 10 HCl,gas 5.19 -14.06 -19.25 -9.623 0.32862E+05 -17.547 11 acmite 7.71 6.53 -1.18 -0.123 0.20182E+04 15 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 19 spessartine 24.46 19.69 -4.76 -0.238 0.81334E+04 20 analcite 3.32 2.77 -0.55 -0.061 0.93600E+03 26 annite 20.12 17.72 -2.40 -0.134 0.41061E+04 27 phlogopite 27.06 25.40 -1.67 -0.093 0.28481E+04 29 anorthite 12.71 8.27 -4.44 -0.342 0.75891E+04 35 aragonite 0.97 -3.71 -4.68 -1.560 0.79909E+04 36 brucite 12.57 9.29 -3.27 -0.655 0.55906E+04 37 calcite 0.81 -3.71 -4.53 -1.508 0.77267E+04 38 carnegieite-low 9.02 5.93 -3.09 -0.442 0.52796E+04 39 carnegieite-high 10.09 5.93 -4.16 -0.595 0.71066E+04 40 carpholite-Mg 8.58 4.46 -4.12 -0.275 0.70416E+04 41 carpholite-Fe 6.71 1.90 -4.81 -0.321 0.82196E+04 42 celadonite 5.34 3.65 -1.69 -0.099 0.28878E+04 43 celadonite-Fe 3.88 1.09 -2.79 -0.164 0.47562E+04 44 chrysotile 23.89 21.57 -2.32 -0.194 0.39689E+04 49 chlorite-Al-free 47.17 43.14 -4.04 -0.168 0.68929E+04 51 chloritoid-Fe 9.17 5.06 -4.12 -0.274 0.70302E+04 52 chloritoid-Mn 11.40 7.55 -3.85 -0.257 0.65747E+04 54 coesite -2.38 -3.16 -0.78 -0.260 0.13344E+04 61 cristobalite -2.56 -3.16 -0.60 -0.199 0.10197E+04 63 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71234E+04 65 diaspore 2.87 0.74 -2.13 -0.356 0.36442E+04 66 diamond -3.10 -7.85 -4.75 -1.356 0.81049E+04 71 enstatite 17.26 12.27 -4.99 -0.499 0.85225E+04 73 clinoenstatite 17.17 12.27 -4.89 -0.489 0.83541E+04 75 epidote 24.67 22.70 -1.97 -0.095 0.33575E+04 76 clinozoisite 22.81 18.95 -3.86 -0.175 0.65849E+04 77 epidote-Fe 29.84 26.46 -3.38 -0.176 0.57767E+04 78 fayalite 14.05 10.31 -3.73 -0.533 0.63744E+04 79 ferrosilite 11.15 7.15 -3.99 -0.399 0.68205E+04 83 gibbsite 4.08 0.74 -3.34 -0.477 0.57028E+04 84 glaucophane 22.97 20.80 -2.17 -0.059 0.37130E+04 85 glaucophane-Fe 17.28 13.12 -4.15 -0.112 0.70921E+04 86 graphite -3.55 -7.85 -4.30 -1.229 0.73471E+04 87 greenalite 16.14 13.89 -2.25 -0.187 0.38410E+04 90 hematite 12.57 8.99 -3.58 -0.434 0.61115E+04 91 heulandite -5.83 -7.52 -1.69 -0.077 0.28938E+04 95 jadeite 4.22 2.77 -1.44 -0.144 0.24615E+04 97 kalsilite 7.58 3.83 -3.76 -0.536 0.64121E+04 98 kaolinite -1.33 -4.84 -3.50 -0.319 0.59822E+04 101 laumontite 2.88 1.95 -0.93 -0.062 0.15928E+04 102 lawsonite 9.62 8.27 -1.35 -0.090 0.23057E+04 103 leucite 4.12 0.67 -3.45 -0.345 0.58870E+04 105 lizardite 23.24 21.57 -1.68 -0.140 0.28615E+04 107 magnetite 20.09 15.72 -4.37 -0.356 0.74539E+04 108 minnesotaite 10.39 7.57 -2.81 -0.165 0.48035E+04 112 manganosite 14.06 9.23 -4.83 -1.207 0.82452E+04 120 muscovite 2.58 -1.01 -3.59 -0.211 0.61300E+04 121 paragonite 4.24 1.09 -3.14 -0.185 0.53691E+04 122 nepheline 8.34 5.93 -2.41 -0.344 0.41120E+04 128 periclase-Fe 11.63 6.74 -4.89 -1.223 0.83522E+04 134 phlogopite-Na 29.65 27.50 -2.15 -0.119 0.36669E+04 136 prehnite 19.37 18.21 -1.16 -0.068 0.19837E+04 137 prehnite-Fe 22.50 21.96 -0.53 -0.032 0.91127E+03 138 pumpellyite-Fe 46.27 43.89 -2.37 -0.053 0.40548E+04 139 pumpellyite-Mg 48.99 46.45 -2.54 -0.056 0.43384E+04 143 pyrrhotite -4.26 -8.05 -3.79 -1.264 0.64757E+04 144 pyrrhotiteFe0.875 -6.02 -9.45 -3.43 -1.263 0.58630E+04 145 pyroxmangite 7.40 6.07 -1.33 -0.265 0.22658E+04 146 pyrophyllite -6.18 -11.15 -4.98 -0.311 0.84957E+04 147 quartz -2.99 -3.16 -0.17 -0.056 0.28705E+03 152 rhodonite 7.45 6.07 -1.37 -0.275 0.23460E+04 153 sanidine -1.28 -2.49 -1.21 -0.093 0.20677E+04 165 stilpnomelane-Mg 27.44 25.81 -1.63 -0.049 0.27795E+04 171 talc 16.49 15.25 -1.24 -0.073 0.21142E+04 174 tephroite 18.09 15.30 -2.78 -0.398 0.47551E+04 178 tridymite -2.63 -3.16 -0.53 -0.177 0.90703E+03 179 tremolite 47.87 47.42 -0.45 -0.012 0.77503E+03 180 ferroactinolite 38.45 34.62 -3.83 -0.104 0.65458E+04 181 troilite-low -4.41 -8.05 -3.64 -1.214 0.62185E+04 183 vesuvianite 223.47 218.82 -4.65 -0.035 0.79347E+04 187 wairakite 3.95 1.95 -2.00 -0.118 0.34147E+04 188 walstromite 11.51 9.94 -1.56 -0.313 0.26718E+04 189 wollastonite 10.46 9.94 -0.52 -0.103 0.88228E+03 190 pseudo-wollastonite 11.00 9.94 -1.06 -0.211 0.18021E+04 191 zoisite 22.85 18.95 -3.90 -0.177 0.66589E+04 192 akaganeite 7.75 4.49 -3.26 -0.705 0.55683E+04 199 chalcedony -2.80 -3.16 -0.36 -0.118 0.60635E+03 201 montmorillonite-Ca -2.29 -6.17 -3.88 -0.240 0.66177E+04 202 montmorillonite-K -2.24 -6.27 -4.03 -0.247 0.68813E+04 203 montmorillonite-Mg -2.48 -6.79 -4.31 -0.267 0.73674E+04 204 montmorillonite-Na -2.04 -5.57 -3.54 -0.216 0.60362E+04 205 nontronite-Ca 3.21 -0.20 -3.41 -0.221 0.58225E+04 206 nontronite-H 2.53 -2.36 -4.89 -0.328 0.83495E+04 207 nontronite-K 3.34 -0.30 -3.64 -0.233 0.62093E+04 208 nontronite-Mg 3.07 -0.82 -3.90 -0.253 0.66563E+04 209 nontronite-Na 3.52 0.40 -3.12 -0.200 0.53302E+04 224 tobermorite 9.82 7.76 -2.07 -0.564 0.35288E+04 230 alabandite -0.98 -5.56 -4.58 -1.527 0.78216E+04 233 boehmite 4.41 0.74 -3.67 -0.611 0.62612E+04 235 ferrous-oxide 9.81 6.74 -3.08 -0.769 0.52531E+04 240 silica-amorphous -2.09 -3.16 -1.07 -0.355 0.18205E+04 242 an20ab80 2.02 1.35 -0.67 -0.052 0.11470E+04 243 an25ab75 2.65 1.78 -0.87 -0.067 0.14807E+04 244 an30ab70 3.28 2.21 -1.07 -0.082 0.18240E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 10.0000000 g Current total amount of reactant added: 289.9990000 g New total amount of reactant added: 299.9990000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.3648E-11 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 11 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 299.9990000 Water: Moles liquid = 0.5375E+02 kg liquid = 0.9683E+00 Moles total = 0.5175E+02 kg total = 0.9323E+00 Activity = 1.0000 Stoichiometric ionic strength = .1132025E-01 Osmotic coef. = 0.9695 True ionic strength = .2000938E-01 Chg. balance for total moles = 0.3648E-11 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.88254E-10 -10.0543 0.74157E-10 -10.1298 0.84027E+00 -0.0756 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.14183E-03 -3.8482 0.11846E-03 -3.9264 0.83522E+00 -0.0782 4 SO4-- 0.66701E-12 -12.1759 0.34642E-12 -12.4604 0.51937E+00 -0.2845 5 HCO3- 0.24687E-06 -6.6075 0.20649E-06 -6.6851 0.83644E+00 -0.0776 6 HS- 0.26333E-04 -4.5795 0.21997E-04 -4.6576 0.83535E+00 -0.0781 7 Al+++ 0.96842E-29 -29.0139 0.22380E-29 -29.6501 0.23109E+00 -0.6362 8 H4SiO4 0.69575E-03 -3.1575 0.69575E-03 -3.1575 0.10000E+01 0.0000 9 Ca++ 0.13490E-06 -6.8700 0.69547E-07 -7.1577 0.51556E+00 -0.2877 10 Mg++ 0.21104E-10 -10.6756 0.10831E-10 -10.9653 0.51320E+00 -0.2897 11 Fe++ 0.58154E-13 -13.2354 0.29877E-13 -13.5247 0.51376E+00 -0.2892 12 K+ 0.15644E-03 -3.8056 0.13089E-03 -3.8831 0.83664E+00 -0.0775 13 Na+ 0.19852E-01 -1.7022 0.16578E-01 -1.7805 0.83507E+00 -0.0783 14 Mn++ 0.18149E-10 -10.7411 0.93322E-11 -11.0300 0.51419E+00 -0.2889 15 HPO4-- 0.45328E-07 -7.3436 0.23545E-07 -7.6281 0.51944E+00 -0.2845 16 HSiO3- 0.10489E-01 -1.9793 0.87605E-02 -2.0575 0.83522E+00 -0.0782 17 Ca(HSiO3)+ 0.16581E-07 -7.7804 0.13875E-07 -7.8578 0.83682E+00 -0.0774 18 Mg(HSiO3)+ 0.32136E-11 -11.4930 0.26892E-11 -11.5704 0.83682E+00 -0.0774 19 NaHSiO3,aq 0.23489E-02 -2.6291 0.23489E-02 -2.6291 0.10000E+01 0.0000 20 AlO+ 0.66159E-16 -16.1794 0.55363E-16 -16.2568 0.83682E+00 -0.0774 22 HAlO2,aq 0.14868E-09 -9.8278 0.14868E-09 -9.8278 0.10000E+01 0.0000 23 AlO2- 0.53232E-05 -5.2738 0.44380E-05 -5.3528 0.83372E+00 -0.0790 24 CH4,aq 0.12781E-04 -4.8934 0.12737E-04 -4.8949 0.99655E+00 -0.0015 25 C2H6,aq 0.24009E-14 -14.6196 0.23926E-14 -14.6211 0.99655E+00 -0.0015 29 CO,aq 0.95277E-17 -17.0210 0.95277E-17 -17.0210 0.10000E+01 0.0000 30 CO2,aq 0.32834E-10 -10.4837 0.32720E-10 -10.4852 0.99655E+00 -0.0015 31 CO3-2 0.46929E-06 -6.3286 0.24322E-06 -6.6140 0.51827E+00 -0.2854 32 CaCO3,aq 0.21210E-09 -9.6735 0.21210E-09 -9.6735 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.43806E-12 -12.3585 0.36658E-12 -12.4358 0.83682E+00 -0.0774 34 CaCl+ 0.15933E-10 -10.7977 0.13333E-10 -10.8751 0.83682E+00 -0.0774 35 CaCl2,aq 0.37525E-15 -15.4257 0.37525E-15 -15.4257 0.10000E+01 0.0000 36 CaOH+ 0.79872E-07 -7.0976 0.66839E-07 -7.1750 0.83682E+00 -0.0774 37 CaSO4,aq 0.76506E-17 -17.1163 0.76506E-17 -17.1163 0.10000E+01 0.0000 38 HCl,aq 0.16098E-14 -14.7932 0.16098E-14 -14.7932 0.10000E+01 0.0000 43 FeCl+ 0.66946E-17 -17.1743 0.56022E-17 -17.2516 0.83682E+00 -0.0774 46 FeO,aq 0.21115E-09 -9.6754 0.21115E-09 -9.6754 0.10000E+01 0.0000 47 FeOH+ 0.15672E-10 -10.8049 0.13114E-10 -10.8822 0.83682E+00 -0.0774 48 HFeO2- 0.35670E-07 -7.4477 0.29792E-07 -7.5259 0.83522E+00 -0.0782 49 FeO+ 0.10979E-16 -16.9594 0.91877E-17 -17.0368 0.83682E+00 -0.0774 51 FeO2- 0.40931E-09 -9.3880 0.34186E-09 -9.4661 0.83522E+00 -0.0782 52 HFeO2,aq 0.32243E-11 -11.4916 0.32243E-11 -11.4916 0.10000E+01 0.0000 53 H2,aq 0.11632E-04 -4.9344 0.11591E-04 -4.9359 0.99655E+00 -0.0015 54 KCl,aq 0.28102E-09 -9.5513 0.28102E-09 -9.5513 0.10000E+01 0.0000 56 KOH,aq 0.75376E-06 -6.1228 0.75376E-06 -6.1228 0.10000E+01 0.0000 57 KSO4- 0.84241E-15 -15.0745 0.70360E-15 -15.1527 0.83522E+00 -0.0782 58 MgCO3,aq 0.82793E-14 -14.0820 0.82793E-14 -14.0820 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.69709E-16 -16.1567 0.58334E-16 -16.2341 0.83682E+00 -0.0774 60 MgCl+ 0.22489E-14 -14.6480 0.18819E-14 -14.7254 0.83682E+00 -0.0774 61 MgOH+ 0.68830E-10 -10.1622 0.57598E-10 -10.2396 0.83682E+00 -0.0774 63 MnO,aq 0.17574E-08 -8.7551 0.17574E-08 -8.7551 0.10000E+01 0.0000 64 MnOH+ 0.45474E-09 -9.3422 0.38054E-09 -9.4196 0.83682E+00 -0.0774 65 MnO2-2 0.20464E-10 -10.6890 0.10606E-10 -10.9745 0.51827E+00 -0.2854 66 HMnO2- 0.20630E-09 -9.6855 0.17230E-09 -9.7637 0.83522E+00 -0.0782 69 MnCl+ 0.81352E-14 -14.0896 0.68077E-14 -14.1670 0.83682E+00 -0.0774 71 NaCl,aq 0.65083E-06 -6.1865 0.65083E-06 -6.1865 0.10000E+01 0.0000 72 NaOH,aq 0.96047E-04 -4.0175 0.96047E-04 -4.0175 0.10000E+01 0.0000 74 OH- 0.93451E-02 -2.0294 0.77912E-02 -2.1084 0.83372E+00 -0.0790 79 HPO3-2 0.16411E-14 -14.7849 0.85053E-15 -15.0703 0.51827E+00 -0.2854 81 H2PO3- 0.15143E-18 -18.8198 0.12648E-18 -18.8980 0.83522E+00 -0.0782 82 H3PO4,aq 0.90560E-18 -18.0431 0.90560E-18 -18.0431 0.10000E+01 0.0000 83 H2PO4- 0.38528E-10 -10.4142 0.32210E-10 -10.4920 0.83601E+00 -0.0778 84 PO4-3 0.10673E-08 -8.9717 0.25905E-09 -9.5866 0.24271E+00 -0.6149 88 HP2O7-3 0.94691E-18 -18.0237 0.21904E-18 -18.6595 0.23132E+00 -0.6358 89 P2O7-4 0.91472E-17 -17.0387 0.70565E-18 -18.1514 0.77144E-01 -1.1127 90 H2S,aq 0.50591E-08 -8.2959 0.50416E-08 -8.2974 0.99655E+00 -0.0015 91 S2-2 0.17848E-14 -14.7484 0.92499E-15 -15.0339 0.51827E+00 -0.2854 97 SO3-2 0.99250E-18 -18.0033 0.52182E-18 -18.2825 0.52576E+00 -0.2792 99 HSO4- 0.29556E-19 -19.5293 0.24758E-19 -19.6063 0.83764E+00 -0.0769 Charge balance for all species = 0.3769E-11 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.8825360E-10 -.2230448E-01 -.2244252E+02 0.0000 2 H2O 0.1000000E+01 0.5550489E+02 0.9982002E+06 0.0000 3 Cl- 0.1418343E-03 0.1424854E-03 0.5042760E+01 6.2034 4 SO4-- 0.6670075E-12 -.1568877E-04 -.1504470E+01 7.7993 5 HCO3- 0.2468700E-06 0.1349734E-04 0.8221392E+00 3.4448 6 HS- 0.2633331E-04 0.4202714E-04 0.1387507E+01 5.4722 7 Al+++ 0.9684249E-29 0.5323315E-05 0.1433815E+00 0.7394 8 H4SiO4 0.6957527E-03 0.1353344E-01 0.1298512E+04 -3.1575 9 Ca++ 0.1348976E-06 0.2315796E-06 0.9265123E-02 13.1020 10 Mg++ 0.2110441E-10 0.9315830E-10 0.2260930E-05 9.2944 11 Fe++ 0.5815390E-13 0.3630936E-07 0.2024246E-02 6.7350 12 K+ 0.1564438E-03 0.1571979E-03 0.6136073E+01 6.2467 13 Na+ 0.1985192E-01 0.2229750E-01 0.5117245E+03 8.3494 14 Mn++ 0.1814941E-10 0.2457050E-08 0.1347509E-03 9.2297 15 HPO4-- 0.4532837E-07 0.4643423E-07 0.4448969E-02 12.6316 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.4967525E+01 -.2159830E-01 -.4945927E+01 0.0000000E+00 2 H2O 0.5174764E+02 0.5374755E+02 -.1999910E+01 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.8339499E-02 -.1519205E-04 0.8354691E-02 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.8313995E-02 0.4069652E-04 -.8354691E-02 0.0000000E+00 7 Al+++ 0.9782192E+00 0.5154773E-05 0.9782141E+00 0.0000000E+00 8 H4SiO4 0.3123824E+01 0.1310495E-01 0.3110720E+01 0.0000000E+00 9 Ca++ 0.3450561E+00 0.2242475E-06 0.3450559E+00 0.0000000E+00 10 Mg++ 0.2380944E+00 0.9020881E-10 0.2380944E+00 0.0000000E+00 11 Fe++ 0.2139019E+00 0.3515977E-07 0.2139018E+00 0.0000000E+00 12 K+ 0.6369406E-01 0.1522208E-03 0.6354183E-01 0.0000000E+00 13 Na+ 0.3767319E+00 0.2159154E-01 0.3551404E+00 0.0000000E+00 14 Mn++ 0.5201561E-02 0.2379258E-08 0.5201559E-02 0.0000000E+00 15 HPO4-- 0.1775267E-02 0.4496407E-07 0.1775222E-02 0.0000000E+00 Chg. balance for solid moles: 0.2056E-15 Mass of aqueous solution: 0.970024E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 299.9990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 0.3547 -0.450 93.02 1.969 28.40 35.71 andradite 0.3342E-01 -1.476 16.98 1.230 5.185 4.412 grossular 0.8102E-02 -2.091 3.650 0.562 1.114 1.015 apatite-OH 0.5917E-03 -3.228 0.2972 -0.527 0.9075E-01 0.9445E-01 clinochlore 0.4382E-01 -1.358 24.36 1.387 7.435 9.264 daphnite 0.1268E-01 -1.897 9.049 0.957 2.762 2.742 chlorite-Mn 0.1040E-02 -2.983 0.7375 -0.132 0.2252 0.2350 diopside 0.7058E-02 -2.151 1.528 0.184 0.4666 0.4671 hedenbergite 0.1830E-02 -2.738 0.4540 -0.343 0.1386 0.1243 microcline 0.5577E-01 -1.254 15.52 1.191 4.739 6.064 stilbite 0.2021 -0.695 142.4 2.153 43.47 66.41 stilpnomelane-Fe 0.1554E-01 -1.809 16.75 1.224 5.115 5.787 tr.625ac.25prg.125 0.3296E-02 -2.482 2.817 0.450 0.8600 0.9067 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8049E+00 0.8049E+00 1.0000 -0.094 grossular 0.1951E+00 0.1951E+00 1.0000 -0.710 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.7615E+00 0.7615E+00 1.0000 -0.118 daphnite 0.2204E+00 0.2204E+00 1.0000 -0.657 chlorite-Mn 0.1808E-01 0.1808E-01 1.0000 -1.743 diopside 0.7941E+00 0.7941E+00 1.0000 -0.100 hedenbergite 0.2059E+00 0.2059E+00 1.0000 -0.686 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 tr.625ac.25prg.125 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 327.556771 g Volume = 133.233847 cm3 Porosity: -10.1110% V(tot) - V(min): -.12234E+02 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 299.9990000 g log = 2.4771 Original solution: 1000.0103000 g Original solution / Rock added: 3.33 (Water/Rock Ratio), log = 0.5229 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0545 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9680E+00 0.9855 0.1006E+01 0.1021E+01 CO2,gas 0.3297E-08 1.0069 0.3501E-08 0.3477E-08 CH4,gas 0.1756E-01 1.0125 0.1875E-01 0.1852E-01 H2,gas 0.1442E-01 1.0006 0.1522E-01 0.1521E-01 H2S,gas 0.1320E-06 0.9959 0.1386E-06 0.1392E-06 S2,gas 0.2952E-29 1.0000 0.3113E-29 0.3113E-29 CO,gas 0.1346E-13 1.0000 0.1420E-13 0.1420E-13 SO3,gas 0.6831E-48 1.0000 0.7203E-48 0.7203E-48 SO2,gas 0.4044E-27 1.0000 0.4265E-27 0.4265E-27 HCl,gas 0.2694E-17 1.0000 0.2841E-17 0.2841E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 16 albite -0.38 -0.38 0.00 0.000 -0.94784E-12 22 andradite 39.01 39.01 0.00 0.000 0.12132E-10 23 grossular 32.73 32.73 0.00 0.000 0.24265E-10 32 apatite-OH -18.15 -18.15 0.00 0.000 0.60662E-11 46 clinochlore 39.07 39.07 0.00 0.000 0.00000E+00 47 daphnite 28.97 28.97 0.00 0.000 0.30331E-10 48 chlorite-Mn 46.87 46.87 0.00 0.000 0.00000E+00 67 diopside 16.18 16.18 0.00 0.000 0.00000E+00 68 hedenbergite 14.21 14.21 0.00 0.000 0.00000E+00 116 microcline -2.49 -2.49 0.00 0.000 0.13649E-10 163 stilbite -7.52 -7.52 0.00 0.000 -0.33364E-10 164 stilpnomelane-Fe 13.02 13.02 0.00 0.000 0.69761E-10 245 tr.625ac.25prg.125 45.16 45.16 0.00 0.000 0.72794E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -16.81 -10.15 -3.385 0.17339E+05 -8.456 3 CH4,gas 4.54 1.12 -3.43 -0.857 0.58498E+04 -1.727 4 H2,gas 8.00 4.48 -3.52 -2.009 0.60045E+04 -1.818 5 H2S,gas -6.23 -14.79 -8.56 -4.279 0.14611E+05 -6.858 6 S2,gas -7.34 -38.54 -31.21 -4.801 0.53283E+05 -29.507 7 CO,gas 3.21 -12.33 -15.55 -4.784 0.26546E+05 -13.848 8 SO3,gas 17.12 -32.72 -49.84 -12.460 0.85103E+05 -48.142 9 SO2,gas 0.83 -28.24 -29.07 -7.752 0.49635E+05 -27.370 10 HCl,gas 5.19 -14.06 -19.25 -9.623 0.32861E+05 -17.547 11 acmite 7.71 6.53 -1.18 -0.123 0.20182E+04 15 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 19 spessartine 24.46 19.70 -4.76 -0.238 0.81312E+04 20 analcite 3.32 2.77 -0.55 -0.061 0.93601E+03 26 annite 20.12 17.72 -2.40 -0.134 0.41061E+04 27 phlogopite 27.06 25.40 -1.67 -0.093 0.28481E+04 29 anorthite 12.71 8.27 -4.44 -0.342 0.75891E+04 35 aragonite 0.97 -3.71 -4.68 -1.560 0.79901E+04 36 brucite 12.57 9.29 -3.27 -0.655 0.55906E+04 37 calcite 0.81 -3.71 -4.52 -1.508 0.77259E+04 38 carnegieite-low 9.02 5.93 -3.09 -0.442 0.52796E+04 39 carnegieite-high 10.09 5.93 -4.16 -0.595 0.71066E+04 40 carpholite-Mg 8.58 4.46 -4.12 -0.275 0.70417E+04 41 carpholite-Fe 6.71 1.90 -4.81 -0.321 0.82196E+04 42 celadonite 5.34 3.65 -1.69 -0.099 0.28878E+04 43 celadonite-Fe 3.88 1.09 -2.79 -0.164 0.47562E+04 44 chrysotile 23.89 21.57 -2.32 -0.194 0.39689E+04 49 chlorite-Al-free 47.17 43.14 -4.04 -0.168 0.68929E+04 51 chloritoid-Fe 9.17 5.06 -4.12 -0.274 0.70303E+04 52 chloritoid-Mn 11.40 7.55 -3.85 -0.257 0.65740E+04 54 coesite -2.38 -3.16 -0.78 -0.260 0.13344E+04 61 cristobalite -2.56 -3.16 -0.60 -0.199 0.10197E+04 63 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71234E+04 65 diaspore 2.87 0.74 -2.13 -0.356 0.36443E+04 66 diamond -3.10 -7.85 -4.75 -1.356 0.81041E+04 71 enstatite 17.26 12.27 -4.99 -0.499 0.85225E+04 73 clinoenstatite 17.17 12.27 -4.89 -0.489 0.83541E+04 75 epidote 24.67 22.70 -1.97 -0.095 0.33575E+04 76 clinozoisite 22.81 18.95 -3.86 -0.175 0.65849E+04 77 epidote-Fe 29.84 26.46 -3.38 -0.176 0.57767E+04 78 fayalite 14.05 10.31 -3.73 -0.533 0.63744E+04 79 ferrosilite 11.15 7.15 -3.99 -0.399 0.68205E+04 83 gibbsite 4.08 0.74 -3.34 -0.477 0.57028E+04 84 glaucophane 22.97 20.80 -2.17 -0.059 0.37130E+04 85 glaucophane-Fe 17.28 13.12 -4.15 -0.112 0.70921E+04 86 graphite -3.55 -7.85 -4.30 -1.229 0.73463E+04 87 greenalite 16.14 13.89 -2.25 -0.187 0.38410E+04 90 hematite 12.57 8.99 -3.58 -0.434 0.61115E+04 91 heulandite -5.83 -7.52 -1.69 -0.077 0.28938E+04 95 jadeite 4.22 2.77 -1.44 -0.144 0.24615E+04 97 kalsilite 7.58 3.83 -3.76 -0.536 0.64121E+04 98 kaolinite -1.33 -4.84 -3.50 -0.319 0.59822E+04 101 laumontite 2.88 1.95 -0.93 -0.062 0.15928E+04 102 lawsonite 9.62 8.27 -1.35 -0.090 0.23058E+04 103 leucite 4.12 0.67 -3.45 -0.345 0.58870E+04 105 lizardite 23.24 21.57 -1.68 -0.140 0.28615E+04 107 magnetite 20.09 15.72 -4.37 -0.356 0.74539E+04 108 minnesotaite 10.39 7.57 -2.81 -0.165 0.48034E+04 112 manganosite 14.06 9.23 -4.83 -1.207 0.82444E+04 120 muscovite 2.58 -1.01 -3.59 -0.211 0.61301E+04 121 paragonite 4.24 1.09 -3.14 -0.185 0.53692E+04 122 nepheline 8.34 5.93 -2.41 -0.344 0.41120E+04 128 periclase-Fe 11.63 6.74 -4.89 -1.223 0.83522E+04 134 phlogopite-Na 29.65 27.50 -2.15 -0.119 0.36669E+04 136 prehnite 19.37 18.21 -1.16 -0.068 0.19837E+04 137 prehnite-Fe 22.50 21.96 -0.53 -0.032 0.91128E+03 138 pumpellyite-Fe 46.27 43.89 -2.37 -0.053 0.40549E+04 139 pumpellyite-Mg 48.99 46.45 -2.54 -0.056 0.43386E+04 143 pyrrhotite -4.26 -8.05 -3.79 -1.264 0.64749E+04 144 pyrrhotiteFe0.875 -6.02 -9.45 -3.43 -1.263 0.58622E+04 145 pyroxmangite 7.40 6.07 -1.33 -0.265 0.22650E+04 146 pyrophyllite -6.18 -11.15 -4.98 -0.311 0.84957E+04 147 quartz -2.99 -3.16 -0.17 -0.056 0.28704E+03 152 rhodonite 7.45 6.07 -1.37 -0.275 0.23453E+04 153 sanidine -1.28 -2.49 -1.21 -0.093 0.20677E+04 165 stilpnomelane-Mg 27.44 25.81 -1.63 -0.049 0.27795E+04 171 talc 16.49 15.25 -1.24 -0.073 0.21142E+04 174 tephroite 18.09 15.30 -2.78 -0.398 0.47536E+04 178 tridymite -2.63 -3.16 -0.53 -0.177 0.90702E+03 179 tremolite 47.87 47.42 -0.45 -0.012 0.77502E+03 180 ferroactinolite 38.45 34.62 -3.83 -0.104 0.65458E+04 181 troilite-low -4.41 -8.05 -3.64 -1.214 0.62177E+04 183 vesuvianite 223.47 218.82 -4.65 -0.035 0.79350E+04 187 wairakite 3.95 1.95 -2.00 -0.118 0.34147E+04 188 walstromite 11.51 9.94 -1.56 -0.313 0.26718E+04 189 wollastonite 10.46 9.94 -0.52 -0.103 0.88228E+03 190 pseudo-wollastonite 11.00 9.94 -1.06 -0.211 0.18021E+04 191 zoisite 22.85 18.95 -3.90 -0.177 0.66590E+04 192 akaganeite 7.75 4.49 -3.26 -0.705 0.55683E+04 199 chalcedony -2.80 -3.16 -0.36 -0.118 0.60634E+03 201 montmorillonite-Ca -2.29 -6.17 -3.88 -0.240 0.66177E+04 202 montmorillonite-K -2.24 -6.27 -4.03 -0.247 0.68813E+04 203 montmorillonite-Mg -2.48 -6.79 -4.31 -0.267 0.73674E+04 204 montmorillonite-Na -2.04 -5.57 -3.54 -0.216 0.60362E+04 205 nontronite-Ca 3.21 -0.20 -3.41 -0.221 0.58225E+04 206 nontronite-H 2.53 -2.36 -4.89 -0.328 0.83495E+04 207 nontronite-K 3.34 -0.30 -3.64 -0.233 0.62093E+04 208 nontronite-Mg 3.07 -0.82 -3.90 -0.253 0.66563E+04 209 nontronite-Na 3.52 0.40 -3.12 -0.200 0.53302E+04 224 tobermorite 9.82 7.76 -2.07 -0.564 0.35288E+04 230 alabandite -0.98 -5.56 -4.58 -1.527 0.78201E+04 233 boehmite 4.41 0.74 -3.67 -0.611 0.62612E+04 235 ferrous-oxide 9.81 6.74 -3.08 -0.769 0.52531E+04 240 silica-amorphous -2.09 -3.16 -1.07 -0.355 0.18205E+04 242 an20ab80 2.02 1.35 -0.67 -0.052 0.11470E+04 243 an25ab75 2.65 1.78 -0.87 -0.067 0.14807E+04 244 an30ab70 3.28 2.21 -1.07 -0.082 0.18240E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 10.0000000 g Current total amount of reactant added: 299.9990000 g New total amount of reactant added: 309.9990000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.3650E-11 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 11 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 309.9990000 Water: Moles liquid = 0.5370E+02 kg liquid = 0.9673E+00 Moles total = 0.5162E+02 kg total = 0.9300E+00 Activity = 1.0000 Stoichiometric ionic strength = .1132041E-01 Osmotic coef. = 0.9695 True ionic strength = .2000953E-01 Chg. balance for total moles = 0.3650E-11 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.88254E-10 -10.0543 0.74158E-10 -10.1298 0.84027E+00 -0.0756 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.14198E-03 -3.8478 0.11859E-03 -3.9260 0.83522E+00 -0.0782 4 SO4-- 0.66776E-12 -12.1754 0.34681E-12 -12.4599 0.51937E+00 -0.2845 5 HCO3- 0.24715E-06 -6.6070 0.20673E-06 -6.6846 0.83644E+00 -0.0776 6 HS- 0.26361E-04 -4.5790 0.22020E-04 -4.6572 0.83535E+00 -0.0781 7 Al+++ 0.96842E-29 -29.0139 0.22379E-29 -29.6502 0.23109E+00 -0.6362 8 H4SiO4 0.69576E-03 -3.1575 0.69576E-03 -3.1575 0.10000E+01 0.0000 9 Ca++ 0.13490E-06 -6.8700 0.69548E-07 -7.1577 0.51556E+00 -0.2877 10 Mg++ 0.21105E-10 -10.6756 0.10831E-10 -10.9653 0.51320E+00 -0.2897 11 Fe++ 0.58155E-13 -13.2354 0.29878E-13 -13.5247 0.51376E+00 -0.2892 12 K+ 0.15645E-03 -3.8056 0.13089E-03 -3.8831 0.83664E+00 -0.0775 13 Na+ 0.19852E-01 -1.7022 0.16578E-01 -1.7805 0.83507E+00 -0.0783 14 Mn++ 0.18167E-10 -10.7407 0.93410E-11 -11.0296 0.51419E+00 -0.2889 15 HPO4-- 0.45329E-07 -7.3436 0.23546E-07 -7.6281 0.51944E+00 -0.2845 16 HSiO3- 0.10489E-01 -1.9793 0.87605E-02 -2.0575 0.83522E+00 -0.0782 17 Ca(HSiO3)+ 0.16581E-07 -7.7804 0.13875E-07 -7.8578 0.83682E+00 -0.0774 18 Mg(HSiO3)+ 0.32136E-11 -11.4930 0.26892E-11 -11.5704 0.83682E+00 -0.0774 19 NaHSiO3,aq 0.23489E-02 -2.6291 0.23489E-02 -2.6291 0.10000E+01 0.0000 20 AlO+ 0.66158E-16 -16.1794 0.55362E-16 -16.2568 0.83682E+00 -0.0774 22 HAlO2,aq 0.14867E-09 -9.8278 0.14867E-09 -9.8278 0.10000E+01 0.0000 23 AlO2- 0.53230E-05 -5.2738 0.44378E-05 -5.3528 0.83372E+00 -0.0790 24 CH4,aq 0.12794E-04 -4.8930 0.12750E-04 -4.8945 0.99655E+00 -0.0015 25 C2H6,aq 0.24059E-14 -14.6187 0.23976E-14 -14.6202 0.99655E+00 -0.0015 29 CO,aq 0.95382E-17 -17.0205 0.95382E-17 -17.0205 0.10000E+01 0.0000 30 CO2,aq 0.32871E-10 -10.4832 0.32757E-10 -10.4847 0.99655E+00 -0.0015 31 CO3-2 0.46982E-06 -6.3281 0.24349E-06 -6.6135 0.51826E+00 -0.2854 32 CaCO3,aq 0.21234E-09 -9.6730 0.21234E-09 -9.6730 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.43856E-12 -12.3580 0.36700E-12 -12.4353 0.83682E+00 -0.0774 34 CaCl+ 0.15949E-10 -10.7973 0.13347E-10 -10.8746 0.83682E+00 -0.0774 35 CaCl2,aq 0.37603E-15 -15.4248 0.37603E-15 -15.4248 0.10000E+01 0.0000 36 CaOH+ 0.79872E-07 -7.0976 0.66839E-07 -7.1750 0.83682E+00 -0.0774 37 CaSO4,aq 0.76593E-17 -17.1158 0.76593E-17 -17.1158 0.10000E+01 0.0000 38 HCl,aq 0.16115E-14 -14.7928 0.16115E-14 -14.7928 0.10000E+01 0.0000 43 FeCl+ 0.67016E-17 -17.1738 0.56081E-17 -17.2512 0.83682E+00 -0.0774 46 FeO,aq 0.21115E-09 -9.6754 0.21115E-09 -9.6754 0.10000E+01 0.0000 47 FeOH+ 0.15672E-10 -10.8049 0.13115E-10 -10.8822 0.83682E+00 -0.0774 48 HFeO2- 0.35670E-07 -7.4477 0.29792E-07 -7.5259 0.83522E+00 -0.0782 49 FeO+ 0.10979E-16 -16.9594 0.91879E-17 -17.0368 0.83682E+00 -0.0774 51 FeO2- 0.40931E-09 -9.3880 0.34186E-09 -9.4661 0.83522E+00 -0.0782 52 HFeO2,aq 0.32244E-11 -11.4916 0.32244E-11 -11.4916 0.10000E+01 0.0000 53 H2,aq 0.11631E-04 -4.9344 0.11591E-04 -4.9359 0.99655E+00 -0.0015 54 KCl,aq 0.28132E-09 -9.5508 0.28132E-09 -9.5508 0.10000E+01 0.0000 56 KOH,aq 0.75376E-06 -6.1228 0.75376E-06 -6.1228 0.10000E+01 0.0000 57 KSO4- 0.84337E-15 -15.0740 0.70441E-15 -15.1522 0.83522E+00 -0.0782 58 MgCO3,aq 0.82886E-14 -14.0815 0.82886E-14 -14.0815 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.69788E-16 -16.1562 0.58400E-16 -16.2336 0.83682E+00 -0.0774 60 MgCl+ 0.22512E-14 -14.6476 0.18839E-14 -14.7249 0.83682E+00 -0.0774 61 MgOH+ 0.68829E-10 -10.1622 0.57598E-10 -10.2396 0.83682E+00 -0.0774 63 MnO,aq 0.17590E-08 -8.7547 0.17590E-08 -8.7547 0.10000E+01 0.0000 64 MnOH+ 0.45516E-09 -9.3418 0.38089E-09 -9.4192 0.83682E+00 -0.0774 65 MnO2-2 0.20482E-10 -10.6886 0.10615E-10 -10.9741 0.51826E+00 -0.2854 66 HMnO2- 0.20649E-09 -9.6851 0.17246E-09 -9.7633 0.83522E+00 -0.0782 69 MnCl+ 0.81513E-14 -14.0888 0.68212E-14 -14.1661 0.83682E+00 -0.0774 71 NaCl,aq 0.65151E-06 -6.1861 0.65151E-06 -6.1861 0.10000E+01 0.0000 72 NaOH,aq 0.96047E-04 -4.0175 0.96047E-04 -4.0175 0.10000E+01 0.0000 74 OH- 0.93451E-02 -2.0294 0.77911E-02 -2.1084 0.83372E+00 -0.0790 79 HPO3-2 0.16411E-14 -14.7849 0.85051E-15 -15.0703 0.51826E+00 -0.2854 81 H2PO3- 0.15143E-18 -18.8198 0.12648E-18 -18.8980 0.83522E+00 -0.0782 82 H3PO4,aq 0.90562E-18 -18.0431 0.90562E-18 -18.0431 0.10000E+01 0.0000 83 H2PO4- 0.38529E-10 -10.4142 0.32211E-10 -10.4920 0.83601E+00 -0.0778 84 PO4-3 0.10673E-08 -8.9717 0.25905E-09 -9.5866 0.24271E+00 -0.6149 88 HP2O7-3 0.94693E-18 -18.0237 0.21905E-18 -18.6595 0.23132E+00 -0.6358 89 P2O7-4 0.91473E-17 -17.0387 0.70565E-18 -18.1514 0.77143E-01 -1.1127 90 H2S,aq 0.50644E-08 -8.2955 0.50469E-08 -8.2970 0.99655E+00 -0.0015 91 S2-2 0.17885E-14 -14.7475 0.92694E-15 -15.0329 0.51826E+00 -0.2854 97 SO3-2 0.99360E-18 -18.0028 0.52239E-18 -18.2820 0.52576E+00 -0.2792 99 HSO4- 0.29590E-19 -19.5289 0.24786E-19 -19.6058 0.83764E+00 -0.0769 Charge balance for all species = 0.3773E-11 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.8825429E-10 -.2230449E-01 -.2244253E+02 0.0000 2 H2O 0.1000000E+01 0.5550489E+02 0.9982001E+06 0.0000 3 Cl- 0.1419815E-03 0.1426333E-03 0.5047995E+01 6.2039 4 SO4-- 0.6677644E-12 -.1570190E-04 -.1505730E+01 7.7998 5 HCO3- 0.2471486E-06 0.1351135E-04 0.8229927E+00 3.4452 6 HS- 0.2636065E-04 0.4206762E-04 0.1388843E+01 5.4727 7 Al+++ 0.9684192E-29 0.5323105E-05 0.1433759E+00 0.7394 8 H4SiO4 0.6957603E-03 0.1353351E-01 0.1298519E+04 -3.1575 9 Ca++ 0.1348984E-06 0.2315805E-06 0.9265158E-02 13.1020 10 Mg++ 0.2110451E-10 0.9315803E-10 0.2260924E-05 9.2943 11 Fe++ 0.5815462E-13 0.3630896E-07 0.2024224E-02 6.7350 12 K+ 0.1564450E-03 0.1571991E-03 0.6136120E+01 6.2467 13 Na+ 0.1985207E-01 0.2229768E-01 0.5117286E+03 8.3494 14 Mn++ 0.1816655E-10 0.2459332E-08 0.1348761E-03 9.2301 15 HPO4-- 0.4532864E-07 0.4643450E-07 0.4448994E-02 12.6316 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.5133110E+01 -.2157590E-01 -.5111534E+01 0.0000000E+00 2 H2O 0.5162229E+02 0.5369181E+02 -.2069522E+01 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.8616634E-02 -.1518900E-04 0.8631823E-02 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.8591129E-02 0.4069347E-04 -.8631823E-02 0.0000000E+00 7 Al+++ 0.1010827E+01 0.5149225E-05 0.1010821E+01 0.0000000E+00 8 H4SiO4 0.3227952E+01 0.1309144E-01 0.3214861E+01 0.0000000E+00 9 Ca++ 0.3565575E+00 0.2240158E-06 0.3565573E+00 0.0000000E+00 10 Mg++ 0.2460310E+00 0.9011500E-10 0.2460310E+00 0.0000000E+00 11 Fe++ 0.2210320E+00 0.3512292E-07 0.2210319E+00 0.0000000E+00 12 K+ 0.6581720E-01 0.1520641E-03 0.6566513E-01 0.0000000E+00 13 Na+ 0.3892843E+00 0.2156932E-01 0.3677150E+00 0.0000000E+00 14 Mn++ 0.5374947E-02 0.2378997E-08 0.5374945E-02 0.0000000E+00 15 HPO4-- 0.1834443E-02 0.4491770E-07 0.1834398E-02 0.0000000E+00 Chg. balance for solid moles: 0.1120E-14 Mass of aqueous solution: 0.969018E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 309.9990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 0.3673 -0.435 96.31 1.984 28.45 36.97 andradite 0.3453E-01 -1.462 17.55 1.244 5.184 4.559 grossular 0.8370E-02 -2.077 3.770 0.576 1.114 1.049 apatite-OH 0.6115E-03 -3.214 0.3072 -0.513 0.9074E-01 0.9760E-01 clinochlore 0.4524E-01 -1.345 25.14 1.400 7.428 9.564 daphnite 0.1309E-01 -1.883 9.342 0.970 2.760 2.831 chlorite-Mn 0.1075E-02 -2.969 0.7621 -0.118 0.2252 0.2429 diopside 0.7602E-02 -2.119 1.646 0.216 0.4863 0.5031 hedenbergite 0.1971E-02 -2.705 0.4890 -0.311 0.1445 0.1339 microcline 0.5763E-01 -1.239 16.04 1.205 4.739 6.266 stilbite 0.2085 -0.681 146.9 2.167 43.40 68.52 stilpnomelane-Fe 0.1606E-01 -1.794 17.32 1.238 5.116 5.982 tr.625ac.25prg.125 0.3379E-02 -2.471 2.888 0.461 0.8533 0.9296 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8049E+00 0.8049E+00 1.0000 -0.094 grossular 0.1951E+00 0.1951E+00 1.0000 -0.710 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.7615E+00 0.7615E+00 1.0000 -0.118 daphnite 0.2204E+00 0.2204E+00 1.0000 -0.657 chlorite-Mn 0.1810E-01 0.1810E-01 1.0000 -1.742 diopside 0.7941E+00 0.7941E+00 1.0000 -0.100 hedenbergite 0.2059E+00 0.2059E+00 1.0000 -0.686 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 tr.625ac.25prg.125 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 338.481832 g Volume = 137.654154 cm3 Porosity: -10.1237% V(tot) - V(min): -.12655E+02 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 309.9990000 g log = 2.4914 Original solution: 1000.0103000 g Original solution / Rock added: 3.23 (Water/Rock Ratio), log = 0.5086 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0545 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9680E+00 0.9855 0.1006E+01 0.1021E+01 CO2,gas 0.3301E-08 1.0069 0.3505E-08 0.3481E-08 CH4,gas 0.1758E-01 1.0125 0.1877E-01 0.1854E-01 H2,gas 0.1442E-01 1.0006 0.1522E-01 0.1521E-01 H2S,gas 0.1321E-06 0.9959 0.1387E-06 0.1393E-06 S2,gas 0.2958E-29 1.0000 0.3120E-29 0.3120E-29 CO,gas 0.1348E-13 1.0000 0.1421E-13 0.1421E-13 SO3,gas 0.6839E-48 1.0000 0.7211E-48 0.7211E-48 SO2,gas 0.4049E-27 1.0000 0.4270E-27 0.4270E-27 HCl,gas 0.2696E-17 1.0000 0.2843E-17 0.2843E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 16 albite -0.38 -0.38 0.00 0.000 -0.94784E-12 22 andradite 39.01 39.01 0.00 0.000 0.12132E-10 23 grossular 32.73 32.73 0.00 0.000 0.12132E-10 32 apatite-OH -18.15 -18.15 0.00 0.000 0.00000E+00 46 clinochlore 39.07 39.07 0.00 0.000 0.24265E-10 47 daphnite 28.97 28.97 0.00 0.000 -0.60662E-11 48 chlorite-Mn 46.87 46.87 0.00 0.000 0.00000E+00 67 diopside 16.18 16.18 0.00 0.000 0.00000E+00 68 hedenbergite 14.21 14.21 0.00 0.000 0.30331E-11 116 microcline -2.49 -2.49 0.00 0.000 0.15165E-11 163 stilbite -7.52 -7.52 0.00 0.000 0.15165E-10 164 stilpnomelane-Fe 13.02 13.02 0.00 0.000 -0.27298E-10 245 tr.625ac.25prg.125 45.16 45.16 0.00 0.000 -0.36397E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -16.81 -10.15 -3.385 0.17338E+05 -8.455 3 CH4,gas 4.54 1.12 -3.43 -0.856 0.58491E+04 -1.727 4 H2,gas 8.00 4.48 -3.52 -2.009 0.60045E+04 -1.818 5 H2S,gas -6.23 -14.79 -8.56 -4.278 0.14610E+05 -6.858 6 S2,gas -7.34 -38.54 -31.20 -4.801 0.53281E+05 -29.506 7 CO,gas 3.21 -12.33 -15.55 -4.783 0.26545E+05 -13.847 8 SO3,gas 17.12 -32.72 -49.84 -12.460 0.85102E+05 -48.142 9 SO2,gas 0.83 -28.24 -29.07 -7.752 0.49634E+05 -27.370 10 HCl,gas 5.19 -14.06 -19.25 -9.623 0.32861E+05 -17.546 11 acmite 7.71 6.53 -1.18 -0.123 0.20182E+04 15 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 19 spessartine 24.46 19.70 -4.76 -0.238 0.81292E+04 20 analcite 3.32 2.77 -0.55 -0.061 0.93602E+03 26 annite 20.12 17.72 -2.40 -0.134 0.41061E+04 27 phlogopite 27.06 25.40 -1.67 -0.093 0.28481E+04 29 anorthite 12.71 8.27 -4.44 -0.342 0.75891E+04 35 aragonite 0.97 -3.71 -4.68 -1.560 0.79893E+04 36 brucite 12.57 9.29 -3.27 -0.655 0.55906E+04 37 calcite 0.81 -3.71 -4.52 -1.508 0.77250E+04 38 carnegieite-low 9.02 5.93 -3.09 -0.442 0.52796E+04 39 carnegieite-high 10.09 5.93 -4.16 -0.595 0.71066E+04 40 carpholite-Mg 8.58 4.46 -4.12 -0.275 0.70417E+04 41 carpholite-Fe 6.71 1.90 -4.81 -0.321 0.82196E+04 42 celadonite 5.34 3.65 -1.69 -0.099 0.28878E+04 43 celadonite-Fe 3.88 1.09 -2.79 -0.164 0.47562E+04 44 chrysotile 23.89 21.57 -2.32 -0.194 0.39689E+04 49 chlorite-Al-free 47.17 43.14 -4.04 -0.168 0.68930E+04 51 chloritoid-Fe 9.17 5.06 -4.12 -0.274 0.70303E+04 52 chloritoid-Mn 11.40 7.55 -3.85 -0.257 0.65734E+04 54 coesite -2.38 -3.16 -0.78 -0.260 0.13344E+04 61 cristobalite -2.56 -3.16 -0.60 -0.199 0.10197E+04 63 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71234E+04 65 diaspore 2.87 0.74 -2.13 -0.356 0.36443E+04 66 diamond -3.10 -7.85 -4.75 -1.356 0.81033E+04 71 enstatite 17.26 12.27 -4.99 -0.499 0.85225E+04 73 clinoenstatite 17.17 12.27 -4.89 -0.489 0.83541E+04 75 epidote 24.67 22.70 -1.97 -0.095 0.33575E+04 76 clinozoisite 22.81 18.95 -3.86 -0.175 0.65850E+04 77 epidote-Fe 29.84 26.46 -3.38 -0.176 0.57767E+04 78 fayalite 14.05 10.31 -3.73 -0.533 0.63744E+04 79 ferrosilite 11.15 7.15 -3.99 -0.399 0.68205E+04 83 gibbsite 4.08 0.74 -3.34 -0.477 0.57028E+04 84 glaucophane 22.97 20.80 -2.17 -0.059 0.37130E+04 85 glaucophane-Fe 17.28 13.12 -4.15 -0.112 0.70921E+04 86 graphite -3.55 -7.85 -4.30 -1.229 0.73455E+04 87 greenalite 16.14 13.89 -2.25 -0.187 0.38409E+04 90 hematite 12.57 8.99 -3.58 -0.434 0.61115E+04 91 heulandite -5.83 -7.52 -1.69 -0.077 0.28938E+04 95 jadeite 4.22 2.77 -1.44 -0.144 0.24615E+04 97 kalsilite 7.58 3.83 -3.76 -0.536 0.64121E+04 98 kaolinite -1.33 -4.84 -3.50 -0.319 0.59822E+04 101 laumontite 2.88 1.95 -0.93 -0.062 0.15928E+04 102 lawsonite 9.62 8.27 -1.35 -0.090 0.23058E+04 103 leucite 4.12 0.67 -3.45 -0.345 0.58871E+04 105 lizardite 23.24 21.57 -1.68 -0.140 0.28615E+04 107 magnetite 20.09 15.72 -4.37 -0.356 0.74539E+04 108 minnesotaite 10.39 7.57 -2.81 -0.165 0.48034E+04 112 manganosite 14.06 9.23 -4.83 -1.207 0.82437E+04 120 muscovite 2.58 -1.01 -3.59 -0.211 0.61301E+04 121 paragonite 4.24 1.09 -3.14 -0.185 0.53692E+04 122 nepheline 8.34 5.93 -2.41 -0.344 0.41120E+04 128 periclase-Fe 11.63 6.74 -4.89 -1.223 0.83522E+04 134 phlogopite-Na 29.65 27.50 -2.15 -0.119 0.36670E+04 136 prehnite 19.37 18.21 -1.16 -0.068 0.19837E+04 137 prehnite-Fe 22.50 21.96 -0.53 -0.032 0.91129E+03 138 pumpellyite-Fe 46.27 43.89 -2.37 -0.053 0.40550E+04 139 pumpellyite-Mg 48.99 46.45 -2.54 -0.056 0.43387E+04 143 pyrrhotite -4.26 -8.05 -3.79 -1.264 0.64742E+04 144 pyrrhotiteFe0.875 -6.02 -9.45 -3.43 -1.263 0.58615E+04 145 pyroxmangite 7.40 6.07 -1.33 -0.265 0.22643E+04 146 pyrophyllite -6.18 -11.15 -4.98 -0.311 0.84957E+04 147 quartz -2.99 -3.16 -0.17 -0.056 0.28703E+03 152 rhodonite 7.45 6.07 -1.37 -0.275 0.23446E+04 153 sanidine -1.28 -2.49 -1.21 -0.093 0.20677E+04 165 stilpnomelane-Mg 27.44 25.81 -1.63 -0.049 0.27795E+04 171 talc 16.49 15.25 -1.24 -0.073 0.21142E+04 174 tephroite 18.09 15.30 -2.78 -0.398 0.47522E+04 178 tridymite -2.63 -3.16 -0.53 -0.177 0.90701E+03 179 tremolite 47.87 47.42 -0.45 -0.012 0.77502E+03 180 ferroactinolite 38.45 34.62 -3.83 -0.104 0.65458E+04 181 troilite-low -4.41 -8.05 -3.64 -1.214 0.62170E+04 183 vesuvianite 223.47 218.82 -4.65 -0.035 0.79353E+04 187 wairakite 3.95 1.95 -2.00 -0.118 0.34148E+04 188 walstromite 11.51 9.94 -1.56 -0.313 0.26718E+04 189 wollastonite 10.46 9.94 -0.52 -0.103 0.88228E+03 190 pseudo-wollastonite 11.00 9.94 -1.06 -0.211 0.18021E+04 191 zoisite 22.85 18.95 -3.90 -0.177 0.66590E+04 192 akaganeite 7.75 4.49 -3.26 -0.705 0.55683E+04 199 chalcedony -2.80 -3.16 -0.36 -0.118 0.60633E+03 201 montmorillonite-Ca -2.29 -6.17 -3.88 -0.240 0.66177E+04 202 montmorillonite-K -2.24 -6.27 -4.03 -0.247 0.68813E+04 203 montmorillonite-Mg -2.48 -6.79 -4.31 -0.267 0.73674E+04 204 montmorillonite-Na -2.04 -5.57 -3.54 -0.216 0.60362E+04 205 nontronite-Ca 3.21 -0.20 -3.41 -0.221 0.58224E+04 206 nontronite-H 2.53 -2.36 -4.89 -0.328 0.83495E+04 207 nontronite-K 3.34 -0.30 -3.64 -0.233 0.62093E+04 208 nontronite-Mg 3.07 -0.82 -3.90 -0.253 0.66563E+04 209 nontronite-Na 3.52 0.40 -3.12 -0.200 0.53302E+04 224 tobermorite 9.82 7.76 -2.07 -0.564 0.35288E+04 230 alabandite -0.98 -5.56 -4.58 -1.526 0.78186E+04 233 boehmite 4.41 0.74 -3.67 -0.611 0.62612E+04 235 ferrous-oxide 9.81 6.74 -3.08 -0.769 0.52531E+04 240 silica-amorphous -2.09 -3.16 -1.07 -0.355 0.18205E+04 242 an20ab80 2.02 1.35 -0.67 -0.052 0.11470E+04 243 an25ab75 2.65 1.78 -0.87 -0.067 0.14807E+04 244 an30ab70 3.28 2.21 -1.07 -0.082 0.18240E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 10.0000000 g Current total amount of reactant added: 309.9990000 g New total amount of reactant added: 319.9990000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.3649E-11 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 11 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 319.9990000 Water: Moles liquid = 0.5364E+02 kg liquid = 0.9663E+00 Moles total = 0.5150E+02 kg total = 0.9277E+00 Activity = 1.0000 Stoichiometric ionic strength = .1132058E-01 Osmotic coef. = 0.9695 True ionic strength = .2000969E-01 Chg. balance for total moles = 0.3649E-11 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.88255E-10 -10.0543 0.74158E-10 -10.1298 0.84027E+00 -0.0756 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.14213E-03 -3.8473 0.11871E-03 -3.9255 0.83522E+00 -0.0782 4 SO4-- 0.66852E-12 -12.1749 0.34721E-12 -12.4594 0.51937E+00 -0.2845 5 HCO3- 0.24743E-06 -6.6066 0.20696E-06 -6.6841 0.83644E+00 -0.0776 6 HS- 0.26388E-04 -4.5786 0.22043E-04 -4.6567 0.83535E+00 -0.0781 7 Al+++ 0.96841E-29 -29.0139 0.22379E-29 -29.6502 0.23109E+00 -0.6362 8 H4SiO4 0.69577E-03 -3.1575 0.69577E-03 -3.1575 0.10000E+01 0.0000 9 Ca++ 0.13490E-06 -6.8700 0.69548E-07 -7.1577 0.51555E+00 -0.2877 10 Mg++ 0.21105E-10 -10.6756 0.10831E-10 -10.9653 0.51320E+00 -0.2897 11 Fe++ 0.58155E-13 -13.2354 0.29878E-13 -13.5247 0.51376E+00 -0.2892 12 K+ 0.15645E-03 -3.8056 0.13089E-03 -3.8831 0.83664E+00 -0.0775 13 Na+ 0.19852E-01 -1.7022 0.16578E-01 -1.7805 0.83507E+00 -0.0783 14 Mn++ 0.18183E-10 -10.7403 0.93493E-11 -11.0292 0.51418E+00 -0.2889 15 HPO4-- 0.45329E-07 -7.3436 0.23546E-07 -7.6281 0.51944E+00 -0.2845 16 HSiO3- 0.10489E-01 -1.9793 0.87605E-02 -2.0575 0.83522E+00 -0.0782 17 Ca(HSiO3)+ 0.16581E-07 -7.7804 0.13876E-07 -7.8577 0.83682E+00 -0.0774 18 Mg(HSiO3)+ 0.32136E-11 -11.4930 0.26892E-11 -11.5704 0.83682E+00 -0.0774 19 NaHSiO3,aq 0.23489E-02 -2.6291 0.23489E-02 -2.6291 0.10000E+01 0.0000 20 AlO+ 0.66156E-16 -16.1794 0.55361E-16 -16.2568 0.83682E+00 -0.0774 22 HAlO2,aq 0.14867E-09 -9.8278 0.14867E-09 -9.8278 0.10000E+01 0.0000 23 AlO2- 0.53228E-05 -5.2739 0.44377E-05 -5.3528 0.83372E+00 -0.0790 24 CH4,aq 0.12807E-04 -4.8925 0.12763E-04 -4.8940 0.99655E+00 -0.0015 25 C2H6,aq 0.24109E-14 -14.6178 0.24026E-14 -14.6193 0.99655E+00 -0.0015 29 CO,aq 0.95488E-17 -17.0201 0.95488E-17 -17.0201 0.10000E+01 0.0000 30 CO2,aq 0.32908E-10 -10.4827 0.32794E-10 -10.4842 0.99655E+00 -0.0015 31 CO3-2 0.47034E-06 -6.3276 0.24376E-06 -6.6130 0.51826E+00 -0.2854 32 CaCO3,aq 0.21257E-09 -9.6725 0.21257E-09 -9.6725 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.43905E-12 -12.3575 0.36741E-12 -12.4348 0.83682E+00 -0.0774 34 CaCl+ 0.15966E-10 -10.7968 0.13361E-10 -10.8742 0.83682E+00 -0.0774 35 CaCl2,aq 0.37681E-15 -15.4239 0.37681E-15 -15.4239 0.10000E+01 0.0000 36 CaOH+ 0.79872E-07 -7.0976 0.66839E-07 -7.1750 0.83682E+00 -0.0774 37 CaSO4,aq 0.76679E-17 -17.1153 0.76679E-17 -17.1153 0.10000E+01 0.0000 38 HCl,aq 0.16132E-14 -14.7923 0.16132E-14 -14.7923 0.10000E+01 0.0000 43 FeCl+ 0.67087E-17 -17.1734 0.56140E-17 -17.2507 0.83682E+00 -0.0774 46 FeO,aq 0.21115E-09 -9.6754 0.21115E-09 -9.6754 0.10000E+01 0.0000 47 FeOH+ 0.15672E-10 -10.8049 0.13115E-10 -10.8822 0.83682E+00 -0.0774 48 HFeO2- 0.35669E-07 -7.4477 0.29792E-07 -7.5259 0.83522E+00 -0.0782 49 FeO+ 0.10980E-16 -16.9594 0.91880E-17 -17.0368 0.83682E+00 -0.0774 51 FeO2- 0.40931E-09 -9.3880 0.34186E-09 -9.4661 0.83522E+00 -0.0782 52 HFeO2,aq 0.32244E-11 -11.4916 0.32244E-11 -11.4916 0.10000E+01 0.0000 53 H2,aq 0.11631E-04 -4.9344 0.11591E-04 -4.9359 0.99655E+00 -0.0015 54 KCl,aq 0.28161E-09 -9.5504 0.28161E-09 -9.5504 0.10000E+01 0.0000 56 KOH,aq 0.75376E-06 -6.1228 0.75376E-06 -6.1228 0.10000E+01 0.0000 57 KSO4- 0.84433E-15 -15.0735 0.70521E-15 -15.1517 0.83522E+00 -0.0782 58 MgCO3,aq 0.82979E-14 -14.0810 0.82979E-14 -14.0810 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.69866E-16 -16.1557 0.58466E-16 -16.2331 0.83682E+00 -0.0774 60 MgCl+ 0.22536E-14 -14.6471 0.18858E-14 -14.7245 0.83682E+00 -0.0774 61 MgOH+ 0.68829E-10 -10.1622 0.57598E-10 -10.2396 0.83682E+00 -0.0774 63 MnO,aq 0.17606E-08 -8.7544 0.17606E-08 -8.7544 0.10000E+01 0.0000 64 MnOH+ 0.45556E-09 -9.3415 0.38123E-09 -9.4188 0.83682E+00 -0.0774 65 MnO2-2 0.20500E-10 -10.6883 0.10624E-10 -10.9737 0.51826E+00 -0.2854 66 HMnO2- 0.20667E-09 -9.6847 0.17261E-09 -9.7629 0.83522E+00 -0.0782 69 MnCl+ 0.81670E-14 -14.0879 0.68344E-14 -14.1653 0.83682E+00 -0.0774 71 NaCl,aq 0.65219E-06 -6.1856 0.65219E-06 -6.1856 0.10000E+01 0.0000 72 NaOH,aq 0.96047E-04 -4.0175 0.96047E-04 -4.0175 0.10000E+01 0.0000 74 OH- 0.93450E-02 -2.0294 0.77911E-02 -2.1084 0.83372E+00 -0.0790 79 HPO3-2 0.16410E-14 -14.7849 0.85049E-15 -15.0703 0.51826E+00 -0.2854 81 H2PO3- 0.15143E-18 -18.8198 0.12648E-18 -18.8980 0.83522E+00 -0.0782 82 H3PO4,aq 0.90563E-18 -18.0430 0.90563E-18 -18.0430 0.10000E+01 0.0000 83 H2PO4- 0.38529E-10 -10.4142 0.32211E-10 -10.4920 0.83601E+00 -0.0778 84 PO4-3 0.10673E-08 -8.9717 0.25905E-09 -9.5866 0.24271E+00 -0.6149 88 HP2O7-3 0.94695E-18 -18.0237 0.21905E-18 -18.6595 0.23132E+00 -0.6358 89 P2O7-4 0.91475E-17 -17.0387 0.70566E-18 -18.1514 0.77142E-01 -1.1127 90 H2S,aq 0.50697E-08 -8.2950 0.50522E-08 -8.2965 0.99655E+00 -0.0015 91 S2-2 0.17923E-14 -14.7466 0.92889E-15 -15.0320 0.51826E+00 -0.2854 97 SO3-2 0.99470E-18 -18.0023 0.52297E-18 -18.2815 0.52576E+00 -0.2792 99 HSO4- 0.29624E-19 -19.5284 0.24814E-19 -19.6053 0.83764E+00 -0.0769 Charge balance for all species = 0.3772E-11 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.8825496E-10 -.2230448E-01 -.2244253E+02 0.0000 2 H2O 0.1000000E+01 0.5550489E+02 0.9982001E+06 0.0000 3 Cl- 0.1421291E-03 0.1427816E-03 0.5053241E+01 6.2043 4 SO4-- 0.6685187E-12 -.1571507E-04 -.1506992E+01 7.8003 5 HCO3- 0.2474264E-06 0.1352539E-04 0.8238480E+00 3.4457 6 HS- 0.2638804E-04 0.4210819E-04 0.1390183E+01 5.4731 7 Al+++ 0.9684148E-29 0.5322907E-05 0.1433705E+00 0.7394 8 H4SiO4 0.6957674E-03 0.1353358E-01 0.1298526E+04 -3.1575 9 Ca++ 0.1348992E-06 0.2315814E-06 0.9265196E-02 13.1020 10 Mg++ 0.2110461E-10 0.9315791E-10 0.2260920E-05 9.2943 11 Fe++ 0.5815533E-13 0.3630858E-07 0.2024203E-02 6.7350 12 K+ 0.1564462E-03 0.1572002E-03 0.6136166E+01 6.2467 13 Na+ 0.1985222E-01 0.2229785E-01 0.5117326E+03 8.3494 14 Mn++ 0.1818267E-10 0.2461475E-08 0.1349936E-03 9.2305 15 HPO4-- 0.4532887E-07 0.4643473E-07 0.4449016E-02 12.6316 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.5298695E+01 -.2155350E-01 -.5277142E+01 0.0000000E+00 2 H2O 0.5149693E+02 0.5363607E+02 -.2139134E+01 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.8893768E-02 -.1518595E-04 0.8908954E-02 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.8868263E-02 0.4069042E-04 -.8908954E-02 0.0000000E+00 7 Al+++ 0.1043434E+01 0.5143687E-05 0.1043429E+01 0.0000000E+00 8 H4SiO4 0.3332080E+01 0.1307791E-01 0.3319002E+01 0.0000000E+00 9 Ca++ 0.3680590E+00 0.2237842E-06 0.3680587E+00 0.0000000E+00 10 Mg++ 0.2539675E+00 0.9002132E-10 0.2539675E+00 0.0000000E+00 11 Fe++ 0.2281620E+00 0.3508609E-07 0.2281620E+00 0.0000000E+00 12 K+ 0.6794034E-01 0.1519074E-03 0.6778843E-01 0.0000000E+00 13 Na+ 0.4018368E+00 0.2154709E-01 0.3802897E+00 0.0000000E+00 14 Mn++ 0.5548333E-02 0.2378599E-08 0.5548331E-02 0.0000000E+00 15 HPO4-- 0.1893619E-02 0.4487129E-07 0.1893574E-02 0.0000000E+00 Chg. balance for solid moles: 0.1102E-14 Mass of aqueous solution: 0.968012E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 319.9990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 0.3799 -0.420 99.61 1.998 28.51 38.24 andradite 0.3564E-01 -1.448 18.11 1.258 5.183 4.705 grossular 0.8639E-02 -2.064 3.891 0.590 1.114 1.083 apatite-OH 0.6312E-03 -3.200 0.3171 -0.499 0.9074E-01 0.1007 clinochlore 0.4665E-01 -1.331 25.93 1.414 7.422 9.864 daphnite 0.1350E-01 -1.870 9.635 0.984 2.757 2.920 chlorite-Mn 0.1110E-02 -2.955 0.7867 -0.104 0.2252 0.2507 diopside 0.8145E-02 -2.089 1.764 0.246 0.5048 0.5391 hedenbergite 0.2112E-02 -2.675 0.5240 -0.281 0.1500 0.1435 microcline 0.5949E-01 -1.226 16.56 1.219 4.739 6.469 stilbite 0.2149 -0.668 151.4 2.180 43.34 70.64 stilpnomelane-Fe 0.1659E-01 -1.780 17.88 1.252 5.117 6.176 tr.625ac.25prg.125 0.3463E-02 -2.461 2.960 0.471 0.8470 0.9526 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8049E+00 0.8049E+00 1.0000 -0.094 grossular 0.1951E+00 0.1951E+00 1.0000 -0.710 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.7615E+00 0.7615E+00 1.0000 -0.118 daphnite 0.2204E+00 0.2204E+00 1.0000 -0.657 chlorite-Mn 0.1811E-01 0.1811E-01 1.0000 -1.742 diopside 0.7941E+00 0.7941E+00 1.0000 -0.100 hedenbergite 0.2059E+00 0.2059E+00 1.0000 -0.686 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 tr.625ac.25prg.125 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 349.406893 g Volume = 142.074460 cm3 Porosity: -10.1356% V(tot) - V(min): -.13075E+02 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 319.9990000 g log = 2.5051 Original solution: 1000.0103000 g Original solution / Rock added: 3.13 (Water/Rock Ratio), log = 0.4949 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0545 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9680E+00 0.9855 0.1006E+01 0.1021E+01 CO2,gas 0.3304E-08 1.0069 0.3509E-08 0.3484E-08 CH4,gas 0.1760E-01 1.0125 0.1879E-01 0.1856E-01 H2,gas 0.1442E-01 1.0006 0.1522E-01 0.1521E-01 H2S,gas 0.1322E-06 0.9959 0.1389E-06 0.1395E-06 S2,gas 0.2965E-29 1.0000 0.3126E-29 0.3126E-29 CO,gas 0.1349E-13 1.0000 0.1423E-13 0.1423E-13 SO3,gas 0.6846E-48 1.0000 0.7220E-48 0.7220E-48 SO2,gas 0.4053E-27 1.0000 0.4274E-27 0.4274E-27 HCl,gas 0.2699E-17 1.0000 0.2846E-17 0.2846E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 16 albite -0.38 -0.38 0.00 0.000 -0.13080E-10 22 andradite 39.01 39.01 0.00 0.000 0.12132E-10 23 grossular 32.73 32.73 0.00 0.000 -0.12132E-10 32 apatite-OH -18.15 -18.15 0.00 0.000 0.00000E+00 46 clinochlore 39.07 39.07 0.00 0.000 -0.12132E-10 47 daphnite 28.97 28.97 0.00 0.000 -0.24265E-10 48 chlorite-Mn 46.87 46.87 0.00 0.000 0.00000E+00 67 diopside 16.18 16.18 0.00 0.000 -0.60662E-11 68 hedenbergite 14.21 14.21 0.00 0.000 -0.30331E-11 116 microcline -2.49 -2.49 0.00 0.000 -0.10616E-10 163 stilbite -7.52 -7.52 0.00 0.000 -0.90992E-11 164 stilpnomelane-Fe 13.02 13.02 0.00 0.000 -0.27298E-10 245 tr.625ac.25prg.125 45.16 45.16 0.00 0.000 -0.48529E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -16.81 -10.15 -3.385 0.17337E+05 -8.455 3 CH4,gas 4.54 1.12 -3.43 -0.856 0.58483E+04 -1.726 4 H2,gas 8.00 4.48 -3.52 -2.010 0.60045E+04 -1.818 5 H2S,gas -6.23 -14.79 -8.56 -4.278 0.14610E+05 -6.857 6 S2,gas -7.34 -38.54 -31.20 -4.801 0.53280E+05 -29.505 7 CO,gas 3.21 -12.33 -15.55 -4.783 0.26544E+05 -13.847 8 SO3,gas 17.12 -32.72 -49.84 -12.460 0.85101E+05 -48.141 9 SO2,gas 0.83 -28.24 -29.07 -7.751 0.49633E+05 -27.369 10 HCl,gas 5.19 -14.06 -19.24 -9.622 0.32860E+05 -17.546 11 acmite 7.71 6.53 -1.18 -0.123 0.20181E+04 15 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 19 spessartine 24.46 19.70 -4.76 -0.238 0.81273E+04 20 analcite 3.32 2.77 -0.55 -0.061 0.93602E+03 26 annite 20.12 17.72 -2.40 -0.134 0.41061E+04 27 phlogopite 27.06 25.40 -1.67 -0.093 0.28482E+04 29 anorthite 12.71 8.27 -4.44 -0.342 0.75892E+04 35 aragonite 0.97 -3.71 -4.68 -1.560 0.79884E+04 36 brucite 12.57 9.29 -3.27 -0.655 0.55906E+04 37 calcite 0.81 -3.71 -4.52 -1.508 0.77242E+04 38 carnegieite-low 9.02 5.93 -3.09 -0.442 0.52797E+04 39 carnegieite-high 10.09 5.93 -4.16 -0.595 0.71067E+04 40 carpholite-Mg 8.58 4.46 -4.12 -0.275 0.70418E+04 41 carpholite-Fe 6.71 1.90 -4.81 -0.321 0.82197E+04 42 celadonite 5.34 3.65 -1.69 -0.099 0.28878E+04 43 celadonite-Fe 3.88 1.09 -2.79 -0.164 0.47562E+04 44 chrysotile 23.89 21.57 -2.32 -0.194 0.39689E+04 49 chlorite-Al-free 47.17 43.14 -4.04 -0.168 0.68930E+04 51 chloritoid-Fe 9.17 5.06 -4.12 -0.274 0.70303E+04 52 chloritoid-Mn 11.40 7.55 -3.85 -0.257 0.65728E+04 54 coesite -2.38 -3.16 -0.78 -0.260 0.13343E+04 61 cristobalite -2.56 -3.16 -0.60 -0.199 0.10197E+04 63 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71234E+04 65 diaspore 2.87 0.74 -2.13 -0.356 0.36443E+04 66 diamond -3.10 -7.85 -4.75 -1.356 0.81025E+04 71 enstatite 17.26 12.27 -4.99 -0.499 0.85225E+04 73 clinoenstatite 17.17 12.27 -4.89 -0.489 0.83541E+04 75 epidote 24.67 22.70 -1.97 -0.095 0.33576E+04 76 clinozoisite 22.81 18.95 -3.86 -0.175 0.65851E+04 77 epidote-Fe 29.84 26.46 -3.38 -0.176 0.57767E+04 78 fayalite 14.05 10.31 -3.73 -0.533 0.63743E+04 79 ferrosilite 11.15 7.15 -3.99 -0.399 0.68204E+04 83 gibbsite 4.08 0.74 -3.34 -0.477 0.57029E+04 84 glaucophane 22.97 20.80 -2.17 -0.059 0.37130E+04 85 glaucophane-Fe 17.28 13.12 -4.15 -0.112 0.70921E+04 86 graphite -3.55 -7.85 -4.30 -1.229 0.73447E+04 87 greenalite 16.14 13.89 -2.25 -0.187 0.38409E+04 90 hematite 12.57 8.99 -3.58 -0.434 0.61115E+04 91 heulandite -5.83 -7.52 -1.69 -0.077 0.28938E+04 95 jadeite 4.22 2.77 -1.44 -0.144 0.24615E+04 97 kalsilite 7.58 3.83 -3.76 -0.536 0.64121E+04 98 kaolinite -1.33 -4.84 -3.50 -0.319 0.59822E+04 101 laumontite 2.88 1.95 -0.93 -0.062 0.15928E+04 102 lawsonite 9.62 8.27 -1.35 -0.090 0.23058E+04 103 leucite 4.12 0.67 -3.45 -0.345 0.58871E+04 105 lizardite 23.24 21.57 -1.68 -0.140 0.28615E+04 107 magnetite 20.09 15.72 -4.37 -0.356 0.74539E+04 108 minnesotaite 10.39 7.57 -2.81 -0.165 0.48034E+04 112 manganosite 14.06 9.23 -4.83 -1.207 0.82431E+04 120 muscovite 2.58 -1.01 -3.59 -0.211 0.61302E+04 121 paragonite 4.24 1.09 -3.14 -0.185 0.53693E+04 122 nepheline 8.34 5.93 -2.41 -0.344 0.41120E+04 128 periclase-Fe 11.63 6.74 -4.89 -1.223 0.83522E+04 134 phlogopite-Na 29.65 27.50 -2.15 -0.119 0.36670E+04 136 prehnite 19.37 18.21 -1.16 -0.068 0.19838E+04 137 prehnite-Fe 22.50 21.96 -0.53 -0.032 0.91130E+03 138 pumpellyite-Fe 46.27 43.89 -2.37 -0.053 0.40551E+04 139 pumpellyite-Mg 48.99 46.45 -2.54 -0.056 0.43388E+04 143 pyrrhotite -4.26 -8.05 -3.79 -1.264 0.64734E+04 144 pyrrhotiteFe0.875 -6.02 -9.45 -3.43 -1.262 0.58607E+04 145 pyroxmangite 7.40 6.07 -1.33 -0.265 0.22637E+04 146 pyrophyllite -6.18 -11.15 -4.98 -0.311 0.84957E+04 147 quartz -2.99 -3.16 -0.17 -0.056 0.28703E+03 152 rhodonite 7.45 6.07 -1.37 -0.275 0.23439E+04 153 sanidine -1.28 -2.49 -1.21 -0.093 0.20677E+04 165 stilpnomelane-Mg 27.44 25.81 -1.63 -0.049 0.27795E+04 171 talc 16.49 15.25 -1.24 -0.073 0.21142E+04 174 tephroite 18.09 15.30 -2.78 -0.397 0.47509E+04 178 tridymite -2.63 -3.16 -0.53 -0.177 0.90700E+03 179 tremolite 47.87 47.42 -0.45 -0.012 0.77502E+03 180 ferroactinolite 38.45 34.62 -3.83 -0.104 0.65457E+04 181 troilite-low -4.41 -8.05 -3.64 -1.214 0.62162E+04 183 vesuvianite 223.47 218.82 -4.65 -0.035 0.79356E+04 187 wairakite 3.95 1.95 -2.00 -0.118 0.34148E+04 188 walstromite 11.51 9.94 -1.56 -0.313 0.26718E+04 189 wollastonite 10.46 9.94 -0.52 -0.103 0.88228E+03 190 pseudo-wollastonite 11.00 9.94 -1.06 -0.211 0.18021E+04 191 zoisite 22.85 18.95 -3.90 -0.177 0.66591E+04 192 akaganeite 7.75 4.49 -3.26 -0.705 0.55683E+04 199 chalcedony -2.80 -3.16 -0.36 -0.118 0.60632E+03 201 montmorillonite-Ca -2.29 -6.17 -3.88 -0.240 0.66177E+04 202 montmorillonite-K -2.24 -6.27 -4.03 -0.247 0.68813E+04 203 montmorillonite-Mg -2.48 -6.79 -4.31 -0.267 0.73674E+04 204 montmorillonite-Na -2.04 -5.57 -3.54 -0.216 0.60362E+04 205 nontronite-Ca 3.21 -0.20 -3.41 -0.221 0.58224E+04 206 nontronite-H 2.53 -2.36 -4.89 -0.328 0.83494E+04 207 nontronite-K 3.34 -0.30 -3.64 -0.233 0.62092E+04 208 nontronite-Mg 3.07 -0.82 -3.90 -0.253 0.66562E+04 209 nontronite-Na 3.52 0.40 -3.12 -0.200 0.53301E+04 224 tobermorite 9.82 7.76 -2.07 -0.564 0.35287E+04 230 alabandite -0.98 -5.56 -4.58 -1.526 0.78172E+04 233 boehmite 4.41 0.74 -3.67 -0.611 0.62612E+04 235 ferrous-oxide 9.81 6.74 -3.08 -0.769 0.52531E+04 240 silica-amorphous -2.09 -3.16 -1.07 -0.355 0.18205E+04 242 an20ab80 2.02 1.35 -0.67 -0.052 0.11470E+04 243 an25ab75 2.65 1.78 -0.87 -0.067 0.14807E+04 244 an30ab70 3.28 2.21 -1.07 -0.082 0.18240E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 10.0000000 g Current total amount of reactant added: 319.9990000 g New total amount of reactant added: 329.9990000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.3649E-11 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 11 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 329.9990000 Water: Moles liquid = 0.5358E+02 kg liquid = 0.9653E+00 Moles total = 0.5137E+02 kg total = 0.9255E+00 Activity = 1.0000 Stoichiometric ionic strength = .1132074E-01 Osmotic coef. = 0.9695 True ionic strength = .2000983E-01 Chg. balance for total moles = 0.3649E-11 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.88256E-10 -10.0543 0.74159E-10 -10.1298 0.84027E+00 -0.0756 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.14228E-03 -3.8469 0.11883E-03 -3.9251 0.83522E+00 -0.0782 4 SO4-- 0.66927E-12 -12.1744 0.34760E-12 -12.4589 0.51936E+00 -0.2845 5 HCO3- 0.24770E-06 -6.6061 0.20719E-06 -6.6836 0.83644E+00 -0.0776 6 HS- 0.26415E-04 -4.5781 0.22066E-04 -4.6563 0.83534E+00 -0.0781 7 Al+++ 0.96841E-29 -29.0139 0.22379E-29 -29.6502 0.23109E+00 -0.6362 8 H4SiO4 0.69577E-03 -3.1575 0.69577E-03 -3.1575 0.10000E+01 0.0000 9 Ca++ 0.13490E-06 -6.8700 0.69548E-07 -7.1577 0.51555E+00 -0.2877 10 Mg++ 0.21105E-10 -10.6756 0.10831E-10 -10.9653 0.51320E+00 -0.2897 11 Fe++ 0.58156E-13 -13.2354 0.29878E-13 -13.5246 0.51376E+00 -0.2892 12 K+ 0.15645E-03 -3.8056 0.13089E-03 -3.8831 0.83664E+00 -0.0775 13 Na+ 0.19852E-01 -1.7022 0.16578E-01 -1.7805 0.83507E+00 -0.0783 14 Mn++ 0.18198E-10 -10.7400 0.93570E-11 -11.0289 0.51418E+00 -0.2889 15 HPO4-- 0.45329E-07 -7.3436 0.23546E-07 -7.6281 0.51944E+00 -0.2845 16 HSiO3- 0.10489E-01 -1.9793 0.87606E-02 -2.0575 0.83522E+00 -0.0782 17 Ca(HSiO3)+ 0.16581E-07 -7.7804 0.13876E-07 -7.8577 0.83682E+00 -0.0774 18 Mg(HSiO3)+ 0.32136E-11 -11.4930 0.26892E-11 -11.5704 0.83682E+00 -0.0774 19 NaHSiO3,aq 0.23490E-02 -2.6291 0.23490E-02 -2.6291 0.10000E+01 0.0000 20 AlO+ 0.66155E-16 -16.1794 0.55360E-16 -16.2568 0.83682E+00 -0.0774 22 HAlO2,aq 0.14866E-09 -9.8278 0.14866E-09 -9.8278 0.10000E+01 0.0000 23 AlO2- 0.53226E-05 -5.2739 0.44375E-05 -5.3529 0.83372E+00 -0.0790 24 CH4,aq 0.12821E-04 -4.8921 0.12776E-04 -4.8936 0.99655E+00 -0.0015 25 C2H6,aq 0.24160E-14 -14.6169 0.24077E-14 -14.6184 0.99655E+00 -0.0015 29 CO,aq 0.95593E-17 -17.0196 0.95593E-17 -17.0196 0.10000E+01 0.0000 30 CO2,aq 0.32945E-10 -10.4822 0.32831E-10 -10.4837 0.99655E+00 -0.0015 31 CO3-2 0.47087E-06 -6.3271 0.24403E-06 -6.6126 0.51826E+00 -0.2854 32 CaCO3,aq 0.21281E-09 -9.6720 0.21281E-09 -9.6720 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.43955E-12 -12.3570 0.36782E-12 -12.4344 0.83682E+00 -0.0774 34 CaCl+ 0.15983E-10 -10.7963 0.13375E-10 -10.8737 0.83682E+00 -0.0774 35 CaCl2,aq 0.37760E-15 -15.4230 0.37760E-15 -15.4230 0.10000E+01 0.0000 36 CaOH+ 0.79872E-07 -7.0976 0.66838E-07 -7.1750 0.83682E+00 -0.0774 37 CaSO4,aq 0.76766E-17 -17.1148 0.76766E-17 -17.1148 0.10000E+01 0.0000 38 HCl,aq 0.16149E-14 -14.7919 0.16149E-14 -14.7919 0.10000E+01 0.0000 43 FeCl+ 0.67157E-17 -17.1729 0.56199E-17 -17.2503 0.83682E+00 -0.0774 46 FeO,aq 0.21115E-09 -9.6754 0.21115E-09 -9.6754 0.10000E+01 0.0000 47 FeOH+ 0.15672E-10 -10.8049 0.13115E-10 -10.8822 0.83682E+00 -0.0774 48 HFeO2- 0.35669E-07 -7.4477 0.29791E-07 -7.5259 0.83522E+00 -0.0782 49 FeO+ 0.10980E-16 -16.9594 0.91882E-17 -17.0368 0.83682E+00 -0.0774 51 FeO2- 0.40931E-09 -9.3880 0.34186E-09 -9.4661 0.83522E+00 -0.0782 52 HFeO2,aq 0.32244E-11 -11.4916 0.32244E-11 -11.4916 0.10000E+01 0.0000 53 H2,aq 0.11631E-04 -4.9344 0.11591E-04 -4.9359 0.99655E+00 -0.0015 54 KCl,aq 0.28191E-09 -9.5499 0.28191E-09 -9.5499 0.10000E+01 0.0000 56 KOH,aq 0.75376E-06 -6.1228 0.75376E-06 -6.1228 0.10000E+01 0.0000 57 KSO4- 0.84529E-15 -15.0730 0.70600E-15 -15.1512 0.83522E+00 -0.0782 58 MgCO3,aq 0.83071E-14 -14.0805 0.83071E-14 -14.0805 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.69945E-16 -16.1552 0.58531E-16 -16.2326 0.83682E+00 -0.0774 60 MgCl+ 0.22559E-14 -14.6467 0.18878E-14 -14.7240 0.83682E+00 -0.0774 61 MgOH+ 0.68829E-10 -10.1622 0.57597E-10 -10.2396 0.83682E+00 -0.0774 63 MnO,aq 0.17620E-08 -8.7540 0.17620E-08 -8.7540 0.10000E+01 0.0000 64 MnOH+ 0.45594E-09 -9.3411 0.38154E-09 -9.4185 0.83682E+00 -0.0774 65 MnO2-2 0.20516E-10 -10.6879 0.10633E-10 -10.9734 0.51826E+00 -0.2854 66 HMnO2- 0.20683E-09 -9.6844 0.17275E-09 -9.7626 0.83522E+00 -0.0782 69 MnCl+ 0.81823E-14 -14.0871 0.68472E-14 -14.1645 0.83682E+00 -0.0774 71 NaCl,aq 0.65287E-06 -6.1852 0.65287E-06 -6.1852 0.10000E+01 0.0000 72 NaOH,aq 0.96047E-04 -4.0175 0.96047E-04 -4.0175 0.10000E+01 0.0000 74 OH- 0.93450E-02 -2.0294 0.77910E-02 -2.1084 0.83372E+00 -0.0790 79 HPO3-2 0.16410E-14 -14.7849 0.85047E-15 -15.0703 0.51826E+00 -0.2854 81 H2PO3- 0.15143E-18 -18.8198 0.12647E-18 -18.8980 0.83522E+00 -0.0782 82 H3PO4,aq 0.90565E-18 -18.0430 0.90565E-18 -18.0430 0.10000E+01 0.0000 83 H2PO4- 0.38529E-10 -10.4142 0.32211E-10 -10.4920 0.83601E+00 -0.0778 84 PO4-3 0.10673E-08 -8.9717 0.25905E-09 -9.5866 0.24271E+00 -0.6149 88 HP2O7-3 0.94696E-18 -18.0237 0.21905E-18 -18.6595 0.23132E+00 -0.6358 89 P2O7-4 0.91476E-17 -17.0387 0.70566E-18 -18.1514 0.77142E-01 -1.1127 90 H2S,aq 0.50750E-08 -8.2946 0.50575E-08 -8.2961 0.99655E+00 -0.0015 91 S2-2 0.17961E-14 -14.7457 0.93084E-15 -15.0311 0.51826E+00 -0.2854 97 SO3-2 0.99579E-18 -18.0018 0.52354E-18 -18.2810 0.52576E+00 -0.2792 99 HSO4- 0.29657E-19 -19.5279 0.24842E-19 -19.6048 0.83764E+00 -0.0769 Charge balance for all species = 0.3778E-11 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.8825562E-10 -.2230448E-01 -.2244252E+02 0.0000 2 H2O 0.1000000E+01 0.5550489E+02 0.9982001E+06 0.0000 3 Cl- 0.1422769E-03 0.1429301E-03 0.5058498E+01 6.2048 4 SO4-- 0.6692709E-12 -.1572828E-04 -.1508259E+01 7.8007 5 HCO3- 0.2477035E-06 0.1353946E-04 0.8247050E+00 3.4462 6 HS- 0.2641550E-04 0.4214885E-04 0.1391525E+01 5.4736 7 Al+++ 0.9684117E-29 0.5322720E-05 0.1433655E+00 0.7394 8 H4SiO4 0.6957741E-03 0.1353364E-01 0.1298532E+04 -3.1575 9 Ca++ 0.1349000E-06 0.2315824E-06 0.9265236E-02 13.1020 10 Mg++ 0.2110472E-10 0.9315775E-10 0.2260917E-05 9.2943 11 Fe++ 0.5815604E-13 0.3630821E-07 0.2024182E-02 6.7350 12 K+ 0.1564474E-03 0.1572014E-03 0.6136211E+01 6.2467 13 Na+ 0.1985237E-01 0.2229802E-01 0.5117365E+03 8.3494 14 Mn++ 0.1819784E-10 0.2463492E-08 0.1351042E-03 9.2308 15 HPO4-- 0.4532907E-07 0.4643492E-07 0.4449035E-02 12.6316 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.5464280E+01 -.2153110E-01 -.5442749E+01 0.0000000E+00 2 H2O 0.5137158E+02 0.5358032E+02 -.2208746E+01 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.9170902E-02 -.1518292E-04 0.9186085E-02 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.9145397E-02 0.4068739E-04 -.9186085E-02 0.0000000E+00 7 Al+++ 0.1076041E+01 0.5138161E-05 0.1076036E+01 0.0000000E+00 8 H4SiO4 0.3436208E+01 0.1306438E-01 0.3423144E+01 0.0000000E+00 9 Ca++ 0.3795604E+00 0.2235526E-06 0.3795602E+00 0.0000000E+00 10 Mg++ 0.2619040E+00 0.8992762E-10 0.2619040E+00 0.0000000E+00 11 Fe++ 0.2352921E+00 0.3504926E-07 0.2352921E+00 0.0000000E+00 12 K+ 0.7006348E-01 0.1517506E-03 0.6991173E-01 0.0000000E+00 13 Na+ 0.4143892E+00 0.2152486E-01 0.3928643E+00 0.0000000E+00 14 Mn++ 0.5721719E-02 0.2378073E-08 0.5721717E-02 0.0000000E+00 15 HPO4-- 0.1952794E-02 0.4482485E-07 0.1952750E-02 0.0000000E+00 Chg. balance for solid moles: -.4476E-15 Mass of aqueous solution: 0.967006E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 329.9990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 0.3924 -0.406 102.9 2.012 28.56 39.50 andradite 0.3674E-01 -1.435 18.67 1.271 5.182 4.851 grossular 0.8907E-02 -2.050 4.012 0.603 1.113 1.116 apatite-OH 0.6509E-03 -3.186 0.3270 -0.485 0.9074E-01 0.1039 clinochlore 0.4807E-01 -1.318 26.72 1.427 7.415 10.16 daphnite 0.1391E-01 -1.857 9.927 0.997 2.755 3.008 chlorite-Mn 0.1144E-02 -2.941 0.8113 -0.091 0.2252 0.2585 diopside 0.8689E-02 -2.061 1.882 0.275 0.5222 0.5751 hedenbergite 0.2253E-02 -2.647 0.5590 -0.253 0.1551 0.1531 microcline 0.6136E-01 -1.212 17.08 1.232 4.740 6.671 stilbite 0.2213 -0.655 156.0 2.193 43.28 72.75 stilpnomelane-Fe 0.1711E-01 -1.767 18.44 1.266 5.119 6.371 tr.625ac.25prg.125 0.3546E-02 -2.450 3.031 0.482 0.8411 0.9755 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8049E+00 0.8049E+00 1.0000 -0.094 grossular 0.1951E+00 0.1951E+00 1.0000 -0.710 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.7615E+00 0.7615E+00 1.0000 -0.118 daphnite 0.2204E+00 0.2204E+00 1.0000 -0.657 chlorite-Mn 0.1813E-01 0.1813E-01 1.0000 -1.742 diopside 0.7941E+00 0.7941E+00 1.0000 -0.100 hedenbergite 0.2059E+00 0.2059E+00 1.0000 -0.686 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 tr.625ac.25prg.125 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 360.331954 g Volume = 146.494766 cm3 Porosity: -10.1468% V(tot) - V(min): -.13495E+02 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 329.9990000 g log = 2.5185 Original solution: 1000.0103000 g Original solution / Rock added: 3.03 (Water/Rock Ratio), log = 0.4815 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0546 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9680E+00 0.9855 0.1006E+01 0.1021E+01 CO2,gas 0.3308E-08 1.0069 0.3513E-08 0.3488E-08 CH4,gas 0.1761E-01 1.0125 0.1881E-01 0.1857E-01 H2,gas 0.1442E-01 1.0006 0.1522E-01 0.1521E-01 H2S,gas 0.1324E-06 0.9959 0.1390E-06 0.1396E-06 S2,gas 0.2971E-29 1.0000 0.3133E-29 0.3133E-29 CO,gas 0.1351E-13 1.0000 0.1425E-13 0.1425E-13 SO3,gas 0.6854E-48 1.0000 0.7228E-48 0.7228E-48 SO2,gas 0.4058E-27 1.0000 0.4279E-27 0.4279E-27 HCl,gas 0.2702E-17 1.0000 0.2849E-17 0.2849E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 16 albite -0.38 -0.38 0.00 0.000 -0.13080E-10 22 andradite 39.01 39.01 0.00 0.000 0.24265E-10 23 grossular 32.73 32.73 0.00 0.000 -0.12132E-10 32 apatite-OH -18.15 -18.15 0.00 0.000 -0.18198E-10 46 clinochlore 39.07 39.07 0.00 0.000 -0.24265E-10 47 daphnite 28.97 28.97 0.00 0.000 -0.24265E-10 48 chlorite-Mn 46.87 46.87 0.00 0.000 -0.12132E-10 67 diopside 16.18 16.18 0.00 0.000 -0.60662E-11 68 hedenbergite 14.21 14.21 0.00 0.000 -0.12132E-10 116 microcline -2.49 -2.49 0.00 0.000 -0.10616E-10 163 stilbite -7.52 -7.52 0.00 0.000 -0.33364E-10 164 stilpnomelane-Fe 13.02 13.02 0.00 0.000 -0.27298E-10 245 tr.625ac.25prg.125 45.16 45.16 0.00 0.000 -0.12132E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -16.81 -10.15 -3.384 0.17337E+05 -8.454 3 CH4,gas 4.54 1.12 -3.42 -0.856 0.58475E+04 -1.726 4 H2,gas 8.00 4.48 -3.52 -2.010 0.60046E+04 -1.818 5 H2S,gas -6.23 -14.79 -8.56 -4.278 0.14609E+05 -6.857 6 S2,gas -7.34 -38.54 -31.20 -4.800 0.53278E+05 -29.504 7 CO,gas 3.21 -12.33 -15.55 -4.783 0.26543E+05 -13.846 8 SO3,gas 17.12 -32.72 -49.84 -12.460 0.85100E+05 -48.141 9 SO2,gas 0.83 -28.24 -29.07 -7.751 0.49632E+05 -27.369 10 HCl,gas 5.19 -14.05 -19.24 -9.622 0.32859E+05 -17.545 11 acmite 7.71 6.53 -1.18 -0.123 0.20181E+04 15 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 19 spessartine 24.46 19.70 -4.76 -0.238 0.81255E+04 20 analcite 3.32 2.77 -0.55 -0.061 0.93603E+03 26 annite 20.12 17.72 -2.40 -0.134 0.41061E+04 27 phlogopite 27.06 25.40 -1.67 -0.093 0.28482E+04 29 anorthite 12.71 8.27 -4.44 -0.342 0.75892E+04 35 aragonite 0.97 -3.71 -4.68 -1.559 0.79876E+04 36 brucite 12.57 9.29 -3.27 -0.655 0.55907E+04 37 calcite 0.81 -3.71 -4.52 -1.508 0.77234E+04 38 carnegieite-low 9.02 5.93 -3.09 -0.442 0.52797E+04 39 carnegieite-high 10.09 5.93 -4.16 -0.595 0.71067E+04 40 carpholite-Mg 8.58 4.46 -4.12 -0.275 0.70418E+04 41 carpholite-Fe 6.71 1.90 -4.81 -0.321 0.82197E+04 42 celadonite 5.34 3.65 -1.69 -0.099 0.28878E+04 43 celadonite-Fe 3.88 1.09 -2.79 -0.164 0.47562E+04 44 chrysotile 23.89 21.57 -2.32 -0.194 0.39689E+04 49 chlorite-Al-free 47.17 43.14 -4.04 -0.168 0.68930E+04 51 chloritoid-Fe 9.17 5.06 -4.12 -0.274 0.70304E+04 52 chloritoid-Mn 11.40 7.55 -3.85 -0.257 0.65722E+04 54 coesite -2.38 -3.16 -0.78 -0.260 0.13343E+04 61 cristobalite -2.56 -3.16 -0.60 -0.199 0.10197E+04 63 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71234E+04 65 diaspore 2.87 0.74 -2.13 -0.356 0.36443E+04 66 diamond -3.10 -7.85 -4.74 -1.356 0.81017E+04 71 enstatite 17.26 12.27 -4.99 -0.499 0.85225E+04 73 clinoenstatite 17.17 12.27 -4.89 -0.489 0.83541E+04 75 epidote 24.67 22.70 -1.97 -0.095 0.33576E+04 76 clinozoisite 22.81 18.95 -3.86 -0.175 0.65851E+04 77 epidote-Fe 29.84 26.46 -3.38 -0.176 0.57767E+04 78 fayalite 14.05 10.31 -3.73 -0.533 0.63743E+04 79 ferrosilite 11.15 7.15 -3.99 -0.399 0.68204E+04 83 gibbsite 4.08 0.74 -3.34 -0.477 0.57029E+04 84 glaucophane 22.97 20.80 -2.17 -0.059 0.37131E+04 85 glaucophane-Fe 17.28 13.12 -4.15 -0.112 0.70920E+04 86 graphite -3.55 -7.85 -4.30 -1.229 0.73439E+04 87 greenalite 16.14 13.89 -2.25 -0.187 0.38409E+04 90 hematite 12.57 8.99 -3.58 -0.434 0.61115E+04 91 heulandite -5.83 -7.52 -1.69 -0.077 0.28938E+04 95 jadeite 4.22 2.77 -1.44 -0.144 0.24615E+04 97 kalsilite 7.58 3.83 -3.76 -0.536 0.64121E+04 98 kaolinite -1.33 -4.84 -3.50 -0.319 0.59823E+04 101 laumontite 2.88 1.95 -0.93 -0.062 0.15928E+04 102 lawsonite 9.62 8.27 -1.35 -0.090 0.23059E+04 103 leucite 4.12 0.67 -3.45 -0.345 0.58871E+04 105 lizardite 23.24 21.57 -1.68 -0.140 0.28615E+04 107 magnetite 20.09 15.72 -4.37 -0.356 0.74539E+04 108 minnesotaite 10.39 7.57 -2.81 -0.165 0.48034E+04 112 manganosite 14.06 9.23 -4.83 -1.207 0.82425E+04 120 muscovite 2.58 -1.01 -3.59 -0.211 0.61302E+04 121 paragonite 4.24 1.09 -3.14 -0.185 0.53693E+04 122 nepheline 8.34 5.93 -2.41 -0.344 0.41120E+04 128 periclase-Fe 11.63 6.74 -4.89 -1.223 0.83522E+04 134 phlogopite-Na 29.65 27.50 -2.15 -0.119 0.36670E+04 136 prehnite 19.37 18.21 -1.16 -0.068 0.19838E+04 137 prehnite-Fe 22.50 21.96 -0.53 -0.032 0.91130E+03 138 pumpellyite-Fe 46.27 43.89 -2.37 -0.053 0.40552E+04 139 pumpellyite-Mg 48.99 46.45 -2.54 -0.056 0.43389E+04 143 pyrrhotite -4.26 -8.05 -3.79 -1.264 0.64726E+04 144 pyrrhotiteFe0.875 -6.02 -9.45 -3.43 -1.262 0.58599E+04 145 pyroxmangite 7.40 6.07 -1.33 -0.265 0.22631E+04 146 pyrophyllite -6.18 -11.15 -4.98 -0.311 0.84957E+04 147 quartz -2.99 -3.16 -0.17 -0.056 0.28702E+03 152 rhodonite 7.45 6.07 -1.37 -0.274 0.23433E+04 153 sanidine -1.28 -2.49 -1.21 -0.093 0.20677E+04 165 stilpnomelane-Mg 27.44 25.81 -1.63 -0.049 0.27796E+04 171 talc 16.49 15.25 -1.24 -0.073 0.21142E+04 174 tephroite 18.09 15.30 -2.78 -0.397 0.47497E+04 178 tridymite -2.63 -3.16 -0.53 -0.177 0.90700E+03 179 tremolite 47.87 47.42 -0.45 -0.012 0.77502E+03 180 ferroactinolite 38.45 34.62 -3.83 -0.104 0.65457E+04 181 troilite-low -4.41 -8.05 -3.64 -1.213 0.62154E+04 183 vesuvianite 223.47 218.82 -4.65 -0.035 0.79358E+04 187 wairakite 3.95 1.95 -2.00 -0.118 0.34148E+04 188 walstromite 11.51 9.94 -1.56 -0.313 0.26719E+04 189 wollastonite 10.46 9.94 -0.52 -0.103 0.88228E+03 190 pseudo-wollastonite 11.00 9.94 -1.06 -0.211 0.18021E+04 191 zoisite 22.85 18.95 -3.90 -0.177 0.66592E+04 192 akaganeite 7.75 4.49 -3.26 -0.705 0.55683E+04 199 chalcedony -2.80 -3.16 -0.36 -0.118 0.60632E+03 201 montmorillonite-Ca -2.29 -6.17 -3.88 -0.240 0.66177E+04 202 montmorillonite-K -2.24 -6.27 -4.03 -0.247 0.68813E+04 203 montmorillonite-Mg -2.48 -6.79 -4.31 -0.267 0.73675E+04 204 montmorillonite-Na -2.04 -5.57 -3.54 -0.216 0.60362E+04 205 nontronite-Ca 3.21 -0.20 -3.41 -0.221 0.58224E+04 206 nontronite-H 2.53 -2.36 -4.89 -0.328 0.83494E+04 207 nontronite-K 3.34 -0.30 -3.64 -0.233 0.62092E+04 208 nontronite-Mg 3.07 -0.82 -3.90 -0.253 0.66562E+04 209 nontronite-Na 3.52 0.40 -3.12 -0.200 0.53301E+04 224 tobermorite 9.82 7.76 -2.07 -0.564 0.35287E+04 230 alabandite -0.98 -5.56 -4.58 -1.526 0.78158E+04 233 boehmite 4.41 0.74 -3.67 -0.611 0.62613E+04 235 ferrous-oxide 9.81 6.74 -3.08 -0.769 0.52531E+04 240 silica-amorphous -2.09 -3.16 -1.07 -0.355 0.18205E+04 242 an20ab80 2.02 1.35 -0.67 -0.052 0.11470E+04 243 an25ab75 2.65 1.78 -0.87 -0.067 0.14807E+04 244 an30ab70 3.28 2.21 -1.07 -0.082 0.18240E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 10.0000000 g Current total amount of reactant added: 329.9990000 g New total amount of reactant added: 339.9990000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.3648E-11 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 11 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 339.9990000 Water: Moles liquid = 0.5353E+02 kg liquid = 0.9643E+00 Moles total = 0.5125E+02 kg total = 0.9232E+00 Activity = 1.0000 Stoichiometric ionic strength = .1132089E-01 Osmotic coef. = 0.9695 True ionic strength = .2000998E-01 Chg. balance for total moles = 0.3648E-11 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.88256E-10 -10.0543 0.74159E-10 -10.1298 0.84027E+00 -0.0756 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.14243E-03 -3.8464 0.11896E-03 -3.9246 0.83522E+00 -0.0782 4 SO4-- 0.67002E-12 -12.1739 0.34798E-12 -12.4584 0.51936E+00 -0.2845 5 HCO3- 0.24798E-06 -6.6056 0.20742E-06 -6.6831 0.83644E+00 -0.0776 6 HS- 0.26443E-04 -4.5777 0.22089E-04 -4.6558 0.83534E+00 -0.0781 7 Al+++ 0.96841E-29 -29.0139 0.22379E-29 -29.6502 0.23109E+00 -0.6362 8 H4SiO4 0.69578E-03 -3.1575 0.69578E-03 -3.1575 0.10000E+01 0.0000 9 Ca++ 0.13490E-06 -6.8700 0.69549E-07 -7.1577 0.51555E+00 -0.2877 10 Mg++ 0.21105E-10 -10.6756 0.10831E-10 -10.9653 0.51320E+00 -0.2897 11 Fe++ 0.58157E-13 -13.2354 0.29878E-13 -13.5246 0.51376E+00 -0.2892 12 K+ 0.15645E-03 -3.8056 0.13089E-03 -3.8831 0.83664E+00 -0.0775 13 Na+ 0.19853E-01 -1.7022 0.16578E-01 -1.7805 0.83507E+00 -0.0783 14 Mn++ 0.18212E-10 -10.7396 0.93644E-11 -11.0285 0.51418E+00 -0.2889 15 HPO4-- 0.45329E-07 -7.3436 0.23546E-07 -7.6281 0.51944E+00 -0.2845 16 HSiO3- 0.10489E-01 -1.9793 0.87606E-02 -2.0575 0.83522E+00 -0.0782 17 Ca(HSiO3)+ 0.16581E-07 -7.7804 0.13876E-07 -7.8577 0.83682E+00 -0.0774 18 Mg(HSiO3)+ 0.32137E-11 -11.4930 0.26893E-11 -11.5704 0.83682E+00 -0.0774 19 NaHSiO3,aq 0.23490E-02 -2.6291 0.23490E-02 -2.6291 0.10000E+01 0.0000 20 AlO+ 0.66153E-16 -16.1794 0.55358E-16 -16.2568 0.83682E+00 -0.0774 22 HAlO2,aq 0.14866E-09 -9.8278 0.14866E-09 -9.8278 0.10000E+01 0.0000 23 AlO2- 0.53224E-05 -5.2739 0.44374E-05 -5.3529 0.83371E+00 -0.0790 24 CH4,aq 0.12834E-04 -4.8916 0.12790E-04 -4.8931 0.99655E+00 -0.0015 25 C2H6,aq 0.24211E-14 -14.6160 0.24127E-14 -14.6175 0.99655E+00 -0.0015 29 CO,aq 0.95699E-17 -17.0191 0.95699E-17 -17.0191 0.10000E+01 0.0000 30 CO2,aq 0.32982E-10 -10.4817 0.32868E-10 -10.4832 0.99655E+00 -0.0015 31 CO3-2 0.47139E-06 -6.3266 0.24430E-06 -6.6121 0.51826E+00 -0.2855 32 CaCO3,aq 0.21305E-09 -9.6715 0.21305E-09 -9.6715 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.44004E-12 -12.3565 0.36823E-12 -12.4339 0.83682E+00 -0.0774 34 CaCl+ 0.16000E-10 -10.7959 0.13389E-10 -10.8733 0.83682E+00 -0.0774 35 CaCl2,aq 0.37839E-15 -15.4221 0.37839E-15 -15.4221 0.10000E+01 0.0000 36 CaOH+ 0.79872E-07 -7.0976 0.66838E-07 -7.1750 0.83682E+00 -0.0774 37 CaSO4,aq 0.76852E-17 -17.1143 0.76852E-17 -17.1143 0.10000E+01 0.0000 38 HCl,aq 0.16165E-14 -14.7914 0.16165E-14 -14.7914 0.10000E+01 0.0000 43 FeCl+ 0.67228E-17 -17.1725 0.56258E-17 -17.2498 0.83682E+00 -0.0774 46 FeO,aq 0.21115E-09 -9.6754 0.21115E-09 -9.6754 0.10000E+01 0.0000 47 FeOH+ 0.15672E-10 -10.8049 0.13115E-10 -10.8822 0.83682E+00 -0.0774 48 HFeO2- 0.35668E-07 -7.4477 0.29791E-07 -7.5259 0.83522E+00 -0.0782 49 FeO+ 0.10980E-16 -16.9594 0.91883E-17 -17.0368 0.83682E+00 -0.0774 51 FeO2- 0.40931E-09 -9.3880 0.34186E-09 -9.4661 0.83522E+00 -0.0782 52 HFeO2,aq 0.32244E-11 -11.4915 0.32244E-11 -11.4915 0.10000E+01 0.0000 53 H2,aq 0.11630E-04 -4.9344 0.11590E-04 -4.9359 0.99655E+00 -0.0015 54 KCl,aq 0.28220E-09 -9.5494 0.28220E-09 -9.5494 0.10000E+01 0.0000 56 KOH,aq 0.75376E-06 -6.1228 0.75376E-06 -6.1228 0.10000E+01 0.0000 57 KSO4- 0.84624E-15 -15.0725 0.70680E-15 -15.1507 0.83522E+00 -0.0782 58 MgCO3,aq 0.83164E-14 -14.0801 0.83164E-14 -14.0801 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.70023E-16 -16.1548 0.58597E-16 -16.2321 0.83682E+00 -0.0774 60 MgCl+ 0.22583E-14 -14.6462 0.18898E-14 -14.7236 0.83682E+00 -0.0774 61 MgOH+ 0.68829E-10 -10.1622 0.57597E-10 -10.2396 0.83682E+00 -0.0774 63 MnO,aq 0.17634E-08 -8.7537 0.17634E-08 -8.7537 0.10000E+01 0.0000 64 MnOH+ 0.45629E-09 -9.3408 0.38184E-09 -9.4181 0.83682E+00 -0.0774 65 MnO2-2 0.20532E-10 -10.6876 0.10641E-10 -10.9730 0.51826E+00 -0.2855 66 HMnO2- 0.20699E-09 -9.6840 0.17288E-09 -9.7622 0.83522E+00 -0.0782 69 MnCl+ 0.81973E-14 -14.0863 0.68597E-14 -14.1637 0.83682E+00 -0.0774 71 NaCl,aq 0.65356E-06 -6.1847 0.65356E-06 -6.1847 0.10000E+01 0.0000 72 NaOH,aq 0.96047E-04 -4.0175 0.96047E-04 -4.0175 0.10000E+01 0.0000 74 OH- 0.93449E-02 -2.0294 0.77910E-02 -2.1084 0.83371E+00 -0.0790 79 HPO3-2 0.16410E-14 -14.7849 0.85046E-15 -15.0703 0.51826E+00 -0.2855 81 H2PO3- 0.15142E-18 -18.8198 0.12647E-18 -18.8980 0.83522E+00 -0.0782 82 H3PO4,aq 0.90566E-18 -18.0430 0.90566E-18 -18.0430 0.10000E+01 0.0000 83 H2PO4- 0.38530E-10 -10.4142 0.32211E-10 -10.4920 0.83601E+00 -0.0778 84 PO4-3 0.10673E-08 -8.9717 0.25905E-09 -9.5866 0.24271E+00 -0.6149 88 HP2O7-3 0.94698E-18 -18.0237 0.21906E-18 -18.6594 0.23132E+00 -0.6358 89 P2O7-4 0.91477E-17 -17.0387 0.70566E-18 -18.1514 0.77141E-01 -1.1127 90 H2S,aq 0.50803E-08 -8.2941 0.50628E-08 -8.2956 0.99655E+00 -0.0015 91 S2-2 0.17999E-14 -14.7448 0.93280E-15 -15.0302 0.51826E+00 -0.2855 97 SO3-2 0.99689E-18 -18.0014 0.52412E-18 -18.2806 0.52575E+00 -0.2792 99 HSO4- 0.29691E-19 -19.5274 0.24870E-19 -19.6043 0.83764E+00 -0.0769 Charge balance for all species = 0.3783E-11 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.8825627E-10 -.2230447E-01 -.2244251E+02 0.0000 2 H2O 0.1000000E+01 0.5550489E+02 0.9982001E+06 0.0000 3 Cl- 0.1424251E-03 0.1430790E-03 0.5063766E+01 6.2052 4 SO4-- 0.6700213E-12 -.1574151E-04 -.1509528E+01 7.8012 5 HCO3- 0.2479800E-06 0.1355357E-04 0.8255639E+00 3.4467 6 HS- 0.2644301E-04 0.4218960E-04 0.1392871E+01 5.4740 7 Al+++ 0.9684096E-29 0.5322541E-05 0.1433607E+00 0.7393 8 H4SiO4 0.6957804E-03 0.1353370E-01 0.1298537E+04 -3.1575 9 Ca++ 0.1349009E-06 0.2315835E-06 0.9265280E-02 13.1020 10 Mg++ 0.2110484E-10 0.9315777E-10 0.2260917E-05 9.2943 11 Fe++ 0.5815674E-13 0.3630785E-07 0.2024162E-02 6.7350 12 K+ 0.1564485E-03 0.1572025E-03 0.6136255E+01 6.2467 13 Na+ 0.1985251E-01 0.2229819E-01 0.5117403E+03 8.3494 14 Mn++ 0.1821216E-10 0.2465393E-08 0.1352085E-03 9.2311 15 HPO4-- 0.4532923E-07 0.4643509E-07 0.4449051E-02 12.6316 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.5629866E+01 -.2150869E-01 -.5608357E+01 0.0000000E+00 2 H2O 0.5124622E+02 0.5352458E+02 -.2278359E+01 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.9448036E-02 -.1517989E-04 0.9463216E-02 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.9422531E-02 0.4068436E-04 -.9463216E-02 0.0000000E+00 7 Al+++ 0.1108649E+01 0.5132643E-05 0.1108644E+01 0.0000000E+00 8 H4SiO4 0.3540336E+01 0.1305084E-01 0.3527285E+01 0.0000000E+00 9 Ca++ 0.3910618E+00 0.2233211E-06 0.3910616E+00 0.0000000E+00 10 Mg++ 0.2698405E+00 0.8983408E-10 0.2698405E+00 0.0000000E+00 11 Fe++ 0.2424222E+00 0.3501245E-07 0.2424222E+00 0.0000000E+00 12 K+ 0.7218662E-01 0.1515939E-03 0.7203503E-01 0.0000000E+00 13 Na+ 0.4269416E+00 0.2150263E-01 0.4054390E+00 0.0000000E+00 14 Mn++ 0.5895105E-02 0.2377433E-08 0.5895103E-02 0.0000000E+00 15 HPO4-- 0.2011970E-02 0.4477837E-07 0.2011925E-02 0.0000000E+00 Chg. balance for solid moles: -.2535E-14 Mass of aqueous solution: 0.966000E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 339.9990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 0.4050 -0.393 106.2 2.026 28.60 40.77 andradite 0.3785E-01 -1.422 19.24 1.284 5.181 4.998 grossular 0.9176E-02 -2.037 4.133 0.616 1.113 1.150 apatite-OH 0.6706E-03 -3.174 0.3369 -0.473 0.9074E-01 0.1070 clinochlore 0.4949E-01 -1.305 27.51 1.439 7.409 10.46 daphnite 0.1432E-01 -1.844 10.22 1.009 2.753 3.097 chlorite-Mn 0.1179E-02 -2.928 0.8359 -0.078 0.2252 0.2664 diopside 0.9233E-02 -2.035 2.000 0.301 0.5386 0.6111 hedenbergite 0.2394E-02 -2.621 0.5940 -0.226 0.1600 0.1627 microcline 0.6322E-01 -1.199 17.60 1.245 4.740 6.874 stilbite 0.2277 -0.643 160.5 2.205 43.23 74.86 stilpnomelane-Fe 0.1763E-01 -1.754 19.01 1.279 5.120 6.566 tr.625ac.25prg.125 0.3629E-02 -2.440 3.102 0.492 0.8356 0.9984 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8049E+00 0.8049E+00 1.0000 -0.094 grossular 0.1951E+00 0.1951E+00 1.0000 -0.710 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.7615E+00 0.7615E+00 1.0000 -0.118 daphnite 0.2204E+00 0.2204E+00 1.0000 -0.657 chlorite-Mn 0.1814E-01 0.1814E-01 1.0000 -1.741 diopside 0.7941E+00 0.7941E+00 1.0000 -0.100 hedenbergite 0.2059E+00 0.2059E+00 1.0000 -0.686 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 tr.625ac.25prg.125 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 371.257016 g Volume = 150.915072 cm3 Porosity: -10.1573% V(tot) - V(min): -.13915E+02 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 339.9990000 g log = 2.5315 Original solution: 1000.0103000 g Original solution / Rock added: 2.94 (Water/Rock Ratio), log = 0.4685 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0546 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9679E+00 0.9855 0.1006E+01 0.1021E+01 CO2,gas 0.3312E-08 1.0069 0.3517E-08 0.3492E-08 CH4,gas 0.1763E-01 1.0125 0.1883E-01 0.1859E-01 H2,gas 0.1442E-01 1.0006 0.1522E-01 0.1521E-01 H2S,gas 0.1325E-06 0.9959 0.1392E-06 0.1397E-06 S2,gas 0.2977E-29 1.0000 0.3140E-29 0.3140E-29 CO,gas 0.1352E-13 1.0000 0.1426E-13 0.1426E-13 SO3,gas 0.6862E-48 1.0000 0.7236E-48 0.7236E-48 SO2,gas 0.4062E-27 1.0000 0.4284E-27 0.4284E-27 HCl,gas 0.2705E-17 1.0000 0.2852E-17 0.2852E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 16 albite -0.38 -0.38 0.00 0.000 0.11184E-10 22 andradite 39.01 39.01 0.00 0.000 0.00000E+00 23 grossular 32.73 32.73 0.00 0.000 0.12132E-10 32 apatite-OH -18.15 -18.15 0.00 0.000 -0.60662E-11 46 clinochlore 39.07 39.07 0.00 0.000 -0.24265E-10 47 daphnite 28.97 28.97 0.00 0.000 0.00000E+00 48 chlorite-Mn 46.87 46.87 0.00 0.000 -0.12132E-10 67 diopside 16.18 16.18 0.00 0.000 -0.60662E-11 68 hedenbergite 14.21 14.21 0.00 0.000 -0.90992E-11 116 microcline -2.49 -2.49 0.00 0.000 0.13649E-10 163 stilbite -7.52 -7.52 0.00 0.000 -0.90992E-11 164 stilpnomelane-Fe 13.02 13.02 0.00 0.000 0.21232E-10 245 tr.625ac.25prg.125 45.16 45.16 0.00 0.000 -0.36397E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -16.81 -10.15 -3.384 0.17336E+05 -8.454 3 CH4,gas 4.54 1.12 -3.42 -0.856 0.58468E+04 -1.725 4 H2,gas 8.00 4.48 -3.52 -2.010 0.60046E+04 -1.818 5 H2S,gas -6.23 -14.79 -8.56 -4.278 0.14608E+05 -6.856 6 S2,gas -7.34 -38.54 -31.20 -4.800 0.53277E+05 -29.503 7 CO,gas 3.21 -12.33 -15.54 -4.783 0.26542E+05 -13.846 8 SO3,gas 17.12 -32.72 -49.84 -12.460 0.85100E+05 -48.140 9 SO2,gas 0.83 -28.23 -29.07 -7.751 0.49631E+05 -27.368 10 HCl,gas 5.19 -14.05 -19.24 -9.622 0.32858E+05 -17.545 11 acmite 7.71 6.53 -1.18 -0.123 0.20181E+04 15 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 19 spessartine 24.46 19.70 -4.76 -0.238 0.81238E+04 20 analcite 3.32 2.77 -0.55 -0.061 0.93604E+03 26 annite 20.12 17.72 -2.40 -0.134 0.41061E+04 27 phlogopite 27.06 25.40 -1.67 -0.093 0.28482E+04 29 anorthite 12.71 8.27 -4.44 -0.342 0.75893E+04 35 aragonite 0.97 -3.71 -4.68 -1.559 0.79868E+04 36 brucite 12.57 9.29 -3.27 -0.655 0.55907E+04 37 calcite 0.81 -3.71 -4.52 -1.508 0.77226E+04 38 carnegieite-low 9.02 5.93 -3.09 -0.442 0.52797E+04 39 carnegieite-high 10.09 5.93 -4.16 -0.595 0.71067E+04 40 carpholite-Mg 8.58 4.46 -4.12 -0.275 0.70418E+04 41 carpholite-Fe 6.71 1.90 -4.81 -0.321 0.82197E+04 42 celadonite 5.34 3.65 -1.69 -0.099 0.28878E+04 43 celadonite-Fe 3.88 1.09 -2.79 -0.164 0.47562E+04 44 chrysotile 23.89 21.57 -2.32 -0.194 0.39689E+04 49 chlorite-Al-free 47.17 43.14 -4.04 -0.168 0.68930E+04 51 chloritoid-Fe 9.17 5.06 -4.12 -0.274 0.70304E+04 52 chloritoid-Mn 11.40 7.55 -3.85 -0.257 0.65717E+04 54 coesite -2.38 -3.16 -0.78 -0.260 0.13343E+04 61 cristobalite -2.56 -3.16 -0.60 -0.199 0.10197E+04 63 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71234E+04 65 diaspore 2.87 0.74 -2.13 -0.356 0.36444E+04 66 diamond -3.10 -7.85 -4.74 -1.356 0.81009E+04 71 enstatite 17.26 12.27 -4.99 -0.499 0.85225E+04 73 clinoenstatite 17.17 12.27 -4.89 -0.489 0.83541E+04 75 epidote 24.67 22.70 -1.97 -0.095 0.33576E+04 76 clinozoisite 22.81 18.95 -3.86 -0.175 0.65852E+04 77 epidote-Fe 29.84 26.46 -3.38 -0.176 0.57767E+04 78 fayalite 14.05 10.31 -3.73 -0.533 0.63743E+04 79 ferrosilite 11.15 7.15 -3.99 -0.399 0.68204E+04 83 gibbsite 4.08 0.74 -3.34 -0.477 0.57029E+04 84 glaucophane 22.97 20.80 -2.17 -0.059 0.37131E+04 85 glaucophane-Fe 17.28 13.12 -4.15 -0.112 0.70920E+04 86 graphite -3.55 -7.85 -4.30 -1.229 0.73431E+04 87 greenalite 16.14 13.89 -2.25 -0.187 0.38409E+04 90 hematite 12.57 8.99 -3.58 -0.434 0.61115E+04 91 heulandite -5.83 -7.52 -1.69 -0.077 0.28938E+04 95 jadeite 4.22 2.77 -1.44 -0.144 0.24615E+04 97 kalsilite 7.58 3.83 -3.76 -0.536 0.64122E+04 98 kaolinite -1.33 -4.84 -3.50 -0.319 0.59823E+04 101 laumontite 2.88 1.95 -0.93 -0.062 0.15929E+04 102 lawsonite 9.62 8.27 -1.35 -0.090 0.23059E+04 103 leucite 4.12 0.67 -3.45 -0.345 0.58871E+04 105 lizardite 23.24 21.57 -1.68 -0.140 0.28616E+04 107 magnetite 20.09 15.72 -4.37 -0.356 0.74538E+04 108 minnesotaite 10.39 7.57 -2.81 -0.165 0.48034E+04 112 manganosite 14.06 9.23 -4.83 -1.207 0.82419E+04 120 muscovite 2.58 -1.01 -3.59 -0.211 0.61302E+04 121 paragonite 4.24 1.09 -3.14 -0.185 0.53693E+04 122 nepheline 8.34 5.93 -2.41 -0.344 0.41121E+04 128 periclase-Fe 11.63 6.74 -4.89 -1.223 0.83522E+04 134 phlogopite-Na 29.65 27.50 -2.15 -0.119 0.36670E+04 136 prehnite 19.37 18.21 -1.16 -0.068 0.19839E+04 137 prehnite-Fe 22.50 21.96 -0.53 -0.032 0.91131E+03 138 pumpellyite-Fe 46.27 43.89 -2.38 -0.053 0.40553E+04 139 pumpellyite-Mg 48.99 46.45 -2.54 -0.056 0.43390E+04 143 pyrrhotite -4.26 -8.05 -3.79 -1.263 0.64719E+04 144 pyrrhotiteFe0.875 -6.02 -9.45 -3.43 -1.262 0.58591E+04 145 pyroxmangite 7.40 6.07 -1.33 -0.265 0.22625E+04 146 pyrophyllite -6.18 -11.15 -4.98 -0.311 0.84957E+04 147 quartz -2.99 -3.16 -0.17 -0.056 0.28701E+03 152 rhodonite 7.45 6.07 -1.37 -0.274 0.23428E+04 153 sanidine -1.28 -2.49 -1.21 -0.093 0.20677E+04 165 stilpnomelane-Mg 27.44 25.81 -1.63 -0.049 0.27796E+04 171 talc 16.49 15.25 -1.24 -0.073 0.21142E+04 174 tephroite 18.09 15.30 -2.78 -0.397 0.47485E+04 178 tridymite -2.63 -3.16 -0.53 -0.177 0.90699E+03 179 tremolite 47.87 47.42 -0.45 -0.012 0.77501E+03 180 ferroactinolite 38.45 34.62 -3.83 -0.104 0.65457E+04 181 troilite-low -4.41 -8.05 -3.64 -1.213 0.62147E+04 183 vesuvianite 223.47 218.82 -4.65 -0.035 0.79361E+04 187 wairakite 3.95 1.95 -2.00 -0.118 0.34148E+04 188 walstromite 11.51 9.94 -1.56 -0.313 0.26719E+04 189 wollastonite 10.46 9.94 -0.52 -0.103 0.88228E+03 190 pseudo-wollastonite 11.00 9.94 -1.06 -0.211 0.18021E+04 191 zoisite 22.85 18.95 -3.90 -0.177 0.66592E+04 192 akaganeite 7.75 4.49 -3.26 -0.705 0.55683E+04 199 chalcedony -2.80 -3.16 -0.36 -0.118 0.60631E+03 201 montmorillonite-Ca -2.29 -6.17 -3.88 -0.240 0.66177E+04 202 montmorillonite-K -2.24 -6.27 -4.03 -0.247 0.68813E+04 203 montmorillonite-Mg -2.48 -6.79 -4.31 -0.267 0.73675E+04 204 montmorillonite-Na -2.04 -5.57 -3.54 -0.216 0.60362E+04 205 nontronite-Ca 3.21 -0.20 -3.41 -0.221 0.58223E+04 206 nontronite-H 2.53 -2.36 -4.89 -0.328 0.83494E+04 207 nontronite-K 3.34 -0.30 -3.64 -0.233 0.62092E+04 208 nontronite-Mg 3.07 -0.82 -3.90 -0.253 0.66562E+04 209 nontronite-Na 3.52 0.40 -3.12 -0.200 0.53301E+04 224 tobermorite 9.82 7.76 -2.07 -0.564 0.35287E+04 230 alabandite -0.98 -5.55 -4.58 -1.526 0.78145E+04 233 boehmite 4.41 0.74 -3.67 -0.611 0.62613E+04 235 ferrous-oxide 9.81 6.74 -3.08 -0.769 0.52531E+04 240 silica-amorphous -2.09 -3.16 -1.07 -0.355 0.18205E+04 242 an20ab80 2.02 1.35 -0.67 -0.052 0.11470E+04 243 an25ab75 2.65 1.78 -0.87 -0.067 0.14807E+04 244 an30ab70 3.28 2.21 -1.07 -0.082 0.18241E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 10.0000000 g Current total amount of reactant added: 339.9990000 g New total amount of reactant added: 349.9990000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.3649E-11 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 11 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 349.9990000 Water: Moles liquid = 0.5347E+02 kg liquid = 0.9633E+00 Moles total = 0.5112E+02 kg total = 0.9210E+00 Activity = 1.0000 Stoichiometric ionic strength = .1132105E-01 Osmotic coef. = 0.9695 True ionic strength = .2001012E-01 Chg. balance for total moles = 0.3649E-11 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.88257E-10 -10.0543 0.74160E-10 -10.1298 0.84027E+00 -0.0756 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.14257E-03 -3.8460 0.11908E-03 -3.9242 0.83522E+00 -0.0782 4 SO4-- 0.67077E-12 -12.1734 0.34837E-12 -12.4580 0.51936E+00 -0.2845 5 HCO3- 0.24826E-06 -6.6051 0.20765E-06 -6.6827 0.83644E+00 -0.0776 6 HS- 0.26471E-04 -4.5772 0.22112E-04 -4.6554 0.83534E+00 -0.0781 7 Al+++ 0.96841E-29 -29.0139 0.22379E-29 -29.6502 0.23109E+00 -0.6362 8 H4SiO4 0.69579E-03 -3.1575 0.69579E-03 -3.1575 0.10000E+01 0.0000 9 Ca++ 0.13490E-06 -6.8700 0.69549E-07 -7.1577 0.51555E+00 -0.2877 10 Mg++ 0.21105E-10 -10.6756 0.10831E-10 -10.9653 0.51319E+00 -0.2897 11 Fe++ 0.58157E-13 -13.2354 0.29879E-13 -13.5246 0.51376E+00 -0.2892 12 K+ 0.15645E-03 -3.8056 0.13089E-03 -3.8831 0.83664E+00 -0.0775 13 Na+ 0.19853E-01 -1.7022 0.16578E-01 -1.7805 0.83507E+00 -0.0783 14 Mn++ 0.18226E-10 -10.7393 0.93713E-11 -11.0282 0.51418E+00 -0.2889 15 HPO4-- 0.45329E-07 -7.3436 0.23546E-07 -7.6281 0.51944E+00 -0.2845 16 HSiO3- 0.10489E-01 -1.9793 0.87606E-02 -2.0575 0.83522E+00 -0.0782 17 Ca(HSiO3)+ 0.16582E-07 -7.7804 0.13876E-07 -7.8577 0.83682E+00 -0.0774 18 Mg(HSiO3)+ 0.32137E-11 -11.4930 0.26893E-11 -11.5704 0.83682E+00 -0.0774 19 NaHSiO3,aq 0.23490E-02 -2.6291 0.23490E-02 -2.6291 0.10000E+01 0.0000 20 AlO+ 0.66152E-16 -16.1795 0.55357E-16 -16.2568 0.83682E+00 -0.0774 22 HAlO2,aq 0.14866E-09 -9.8278 0.14866E-09 -9.8278 0.10000E+01 0.0000 23 AlO2- 0.53222E-05 -5.2739 0.44372E-05 -5.3529 0.83371E+00 -0.0790 24 CH4,aq 0.12847E-04 -4.8912 0.12803E-04 -4.8927 0.99655E+00 -0.0015 25 C2H6,aq 0.24261E-14 -14.6151 0.24178E-14 -14.6166 0.99655E+00 -0.0015 29 CO,aq 0.95804E-17 -17.0186 0.95804E-17 -17.0186 0.10000E+01 0.0000 30 CO2,aq 0.33019E-10 -10.4812 0.32905E-10 -10.4827 0.99655E+00 -0.0015 31 CO3-2 0.47191E-06 -6.3261 0.24457E-06 -6.6116 0.51826E+00 -0.2855 32 CaCO3,aq 0.21328E-09 -9.6710 0.21328E-09 -9.6710 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.44053E-12 -12.3560 0.36865E-12 -12.4334 0.83682E+00 -0.0774 34 CaCl+ 0.16016E-10 -10.7954 0.13403E-10 -10.8728 0.83682E+00 -0.0774 35 CaCl2,aq 0.37918E-15 -15.4212 0.37918E-15 -15.4212 0.10000E+01 0.0000 36 CaOH+ 0.79872E-07 -7.0976 0.66838E-07 -7.1750 0.83682E+00 -0.0774 37 CaSO4,aq 0.76938E-17 -17.1139 0.76938E-17 -17.1139 0.10000E+01 0.0000 38 HCl,aq 0.16182E-14 -14.7910 0.16182E-14 -14.7910 0.10000E+01 0.0000 43 FeCl+ 0.67299E-17 -17.1720 0.56317E-17 -17.2494 0.83682E+00 -0.0774 46 FeO,aq 0.21115E-09 -9.6754 0.21115E-09 -9.6754 0.10000E+01 0.0000 47 FeOH+ 0.15672E-10 -10.8049 0.13115E-10 -10.8822 0.83682E+00 -0.0774 48 HFeO2- 0.35668E-07 -7.4477 0.29791E-07 -7.5259 0.83522E+00 -0.0782 49 FeO+ 0.10980E-16 -16.9594 0.91884E-17 -17.0368 0.83682E+00 -0.0774 51 FeO2- 0.40931E-09 -9.3880 0.34186E-09 -9.4661 0.83522E+00 -0.0782 52 HFeO2,aq 0.32244E-11 -11.4915 0.32244E-11 -11.4915 0.10000E+01 0.0000 53 H2,aq 0.11630E-04 -4.9344 0.11590E-04 -4.9359 0.99655E+00 -0.0015 54 KCl,aq 0.28250E-09 -9.5490 0.28250E-09 -9.5490 0.10000E+01 0.0000 56 KOH,aq 0.75376E-06 -6.1228 0.75376E-06 -6.1228 0.10000E+01 0.0000 57 KSO4- 0.84719E-15 -15.0720 0.70759E-15 -15.1502 0.83522E+00 -0.0782 58 MgCO3,aq 0.83256E-14 -14.0796 0.83256E-14 -14.0796 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.70101E-16 -16.1543 0.58662E-16 -16.2316 0.83682E+00 -0.0774 60 MgCl+ 0.22606E-14 -14.6458 0.18917E-14 -14.7231 0.83682E+00 -0.0774 61 MgOH+ 0.68829E-10 -10.1622 0.57597E-10 -10.2396 0.83682E+00 -0.0774 63 MnO,aq 0.17646E-08 -8.7533 0.17646E-08 -8.7533 0.10000E+01 0.0000 64 MnOH+ 0.45663E-09 -9.3404 0.38212E-09 -9.4178 0.83682E+00 -0.0774 65 MnO2-2 0.20547E-10 -10.6873 0.10649E-10 -10.9727 0.51826E+00 -0.2855 66 HMnO2- 0.20714E-09 -9.6837 0.17301E-09 -9.7619 0.83522E+00 -0.0782 69 MnCl+ 0.82119E-14 -14.0856 0.68719E-14 -14.1629 0.83682E+00 -0.0774 71 NaCl,aq 0.65424E-06 -6.1843 0.65424E-06 -6.1843 0.10000E+01 0.0000 72 NaOH,aq 0.96047E-04 -4.0175 0.96047E-04 -4.0175 0.10000E+01 0.0000 74 OH- 0.93448E-02 -2.0294 0.77909E-02 -2.1084 0.83371E+00 -0.0790 79 HPO3-2 0.16409E-14 -14.7849 0.85044E-15 -15.0704 0.51826E+00 -0.2855 81 H2PO3- 0.15142E-18 -18.8198 0.12647E-18 -18.8980 0.83522E+00 -0.0782 82 H3PO4,aq 0.90568E-18 -18.0430 0.90568E-18 -18.0430 0.10000E+01 0.0000 83 H2PO4- 0.38530E-10 -10.4142 0.32212E-10 -10.4920 0.83601E+00 -0.0778 84 PO4-3 0.10673E-08 -8.9717 0.25905E-09 -9.5866 0.24271E+00 -0.6149 88 HP2O7-3 0.94699E-18 -18.0237 0.21906E-18 -18.6594 0.23132E+00 -0.6358 89 P2O7-4 0.91478E-17 -17.0387 0.70566E-18 -18.1514 0.77141E-01 -1.1127 90 H2S,aq 0.50856E-08 -8.2937 0.50681E-08 -8.2952 0.99655E+00 -0.0015 91 S2-2 0.18037E-14 -14.7438 0.93476E-15 -15.0293 0.51826E+00 -0.2855 97 SO3-2 0.99798E-18 -18.0009 0.52469E-18 -18.2801 0.52575E+00 -0.2792 99 HSO4- 0.29724E-19 -19.5269 0.24898E-19 -19.6038 0.83764E+00 -0.0769 Charge balance for all species = 0.3786E-11 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.8825691E-10 -.2230445E-01 -.2244249E+02 0.0000 2 H2O 0.1000000E+01 0.5550489E+02 0.9982001E+06 0.0000 3 Cl- 0.1425736E-03 0.1432281E-03 0.5069045E+01 6.2057 4 SO4-- 0.6707701E-12 -.1575479E-04 -.1510801E+01 7.8017 5 HCO3- 0.2482560E-06 0.1356769E-04 0.8264245E+00 3.4472 6 HS- 0.2647057E-04 0.4223045E-04 0.1394219E+01 5.4745 7 Al+++ 0.9684086E-29 0.5322372E-05 0.1433561E+00 0.7393 8 H4SiO4 0.6957864E-03 0.1353375E-01 0.1298542E+04 -3.1575 9 Ca++ 0.1349018E-06 0.2315846E-06 0.9265325E-02 13.1020 10 Mg++ 0.2110496E-10 0.9315774E-10 0.2260916E-05 9.2943 11 Fe++ 0.5815744E-13 0.3630750E-07 0.2024142E-02 6.7350 12 K+ 0.1564496E-03 0.1572037E-03 0.6136298E+01 6.2467 13 Na+ 0.1985265E-01 0.2229835E-01 0.5117440E+03 8.3494 14 Mn++ 0.1822569E-10 0.2467189E-08 0.1353069E-03 9.2315 15 HPO4-- 0.4532937E-07 0.4643522E-07 0.4449064E-02 12.6316 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.5795451E+01 -.2148627E-01 -.5773965E+01 0.0000000E+00 2 H2O 0.5112087E+02 0.5346884E+02 -.2347971E+01 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.9725170E-02 -.1517687E-04 0.9740347E-02 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.9699665E-02 0.4068134E-04 -.9740347E-02 0.0000000E+00 7 Al+++ 0.1141256E+01 0.5127135E-05 0.1141251E+01 0.0000000E+00 8 H4SiO4 0.3644464E+01 0.1303730E-01 0.3631426E+01 0.0000000E+00 9 Ca++ 0.4025632E+00 0.2230896E-06 0.4025630E+00 0.0000000E+00 10 Mg++ 0.2777770E+00 0.8974049E-10 0.2777770E+00 0.0000000E+00 11 Fe++ 0.2495523E+00 0.3497566E-07 0.2495523E+00 0.0000000E+00 12 K+ 0.7430977E-01 0.1514371E-03 0.7415833E-01 0.0000000E+00 13 Na+ 0.4394941E+00 0.2148039E-01 0.4180137E+00 0.0000000E+00 14 Mn++ 0.6068491E-02 0.2376687E-08 0.6068489E-02 0.0000000E+00 15 HPO4-- 0.2071146E-02 0.4473187E-07 0.2071101E-02 0.0000000E+00 Chg. balance for solid moles: 0.2064E-15 Mass of aqueous solution: 0.964994E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 349.9990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 0.4175 -0.379 109.5 2.039 28.65 42.03 andradite 0.3896E-01 -1.409 19.80 1.297 5.181 5.144 grossular 0.9444E-02 -2.025 4.254 0.629 1.113 1.184 apatite-OH 0.6904E-03 -3.161 0.3468 -0.460 0.9074E-01 0.1102 clinochlore 0.5091E-01 -1.293 28.30 1.452 7.404 10.76 daphnite 0.1473E-01 -1.832 10.51 1.022 2.751 3.186 chlorite-Mn 0.1214E-02 -2.916 0.8605 -0.065 0.2251 0.2742 diopside 0.9777E-02 -2.010 2.117 0.326 0.5540 0.6471 hedenbergite 0.2535E-02 -2.596 0.6289 -0.201 0.1646 0.1723 microcline 0.6508E-01 -1.187 18.11 1.258 4.740 7.076 stilbite 0.2342 -0.630 165.0 2.218 43.18 76.97 stilpnomelane-Fe 0.1816E-01 -1.741 19.57 1.292 5.121 6.761 tr.625ac.25prg.125 0.3713E-02 -2.430 3.173 0.502 0.8303 1.021 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8049E+00 0.8049E+00 1.0000 -0.094 grossular 0.1951E+00 0.1951E+00 1.0000 -0.710 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.7615E+00 0.7615E+00 1.0000 -0.118 daphnite 0.2204E+00 0.2204E+00 1.0000 -0.657 chlorite-Mn 0.1815E-01 0.1815E-01 1.0000 -1.741 diopside 0.7941E+00 0.7941E+00 1.0000 -0.100 hedenbergite 0.2059E+00 0.2059E+00 1.0000 -0.686 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 tr.625ac.25prg.125 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 382.182078 g Volume = 155.335378 cm3 Porosity: -10.1672% V(tot) - V(min): -.14336E+02 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 349.9990000 g log = 2.5441 Original solution: 1000.0103000 g Original solution / Rock added: 2.86 (Water/Rock Ratio), log = 0.4559 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0546 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9679E+00 0.9855 0.1006E+01 0.1021E+01 CO2,gas 0.3315E-08 1.0069 0.3520E-08 0.3496E-08 CH4,gas 0.1765E-01 1.0125 0.1885E-01 0.1861E-01 H2,gas 0.1442E-01 1.0006 0.1522E-01 0.1521E-01 H2S,gas 0.1326E-06 0.9959 0.1393E-06 0.1399E-06 S2,gas 0.2984E-29 1.0000 0.3147E-29 0.3147E-29 CO,gas 0.1354E-13 1.0000 0.1428E-13 0.1428E-13 SO3,gas 0.6869E-48 1.0000 0.7244E-48 0.7244E-48 SO2,gas 0.4067E-27 1.0000 0.4289E-27 0.4289E-27 HCl,gas 0.2708E-17 1.0000 0.2855E-17 0.2855E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 16 albite -0.38 -0.38 0.00 0.000 -0.94784E-12 22 andradite 39.01 39.01 0.00 0.000 0.00000E+00 23 grossular 32.73 32.73 0.00 0.000 -0.24265E-10 32 apatite-OH -18.15 -18.15 0.00 0.000 -0.18198E-10 46 clinochlore 39.07 39.07 0.00 0.000 -0.36397E-10 47 daphnite 28.97 28.97 0.00 0.000 -0.42463E-10 48 chlorite-Mn 46.87 46.87 0.00 0.000 -0.24265E-10 67 diopside 16.18 16.18 0.00 0.000 -0.12132E-10 68 hedenbergite 14.21 14.21 0.00 0.000 -0.15165E-10 116 microcline -2.49 -2.49 0.00 0.000 -0.10616E-10 163 stilbite -7.52 -7.52 0.00 0.000 -0.33364E-10 164 stilpnomelane-Fe 13.02 13.02 0.00 0.000 0.21232E-10 245 tr.625ac.25prg.125 45.16 45.16 0.00 0.000 -0.24265E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -16.81 -10.15 -3.384 0.17335E+05 -8.453 3 CH4,gas 4.54 1.12 -3.42 -0.856 0.58460E+04 -1.725 4 H2,gas 8.00 4.48 -3.52 -2.010 0.60046E+04 -1.818 5 H2S,gas -6.23 -14.79 -8.55 -4.277 0.14607E+05 -6.856 6 S2,gas -7.34 -38.54 -31.20 -4.800 0.53275E+05 -29.502 7 CO,gas 3.21 -12.33 -15.54 -4.783 0.26542E+05 -13.845 8 SO3,gas 17.12 -32.72 -49.84 -12.460 0.85099E+05 -48.140 9 SO2,gas 0.83 -28.23 -29.07 -7.751 0.49631E+05 -27.368 10 HCl,gas 5.19 -14.05 -19.24 -9.622 0.32857E+05 -17.544 11 acmite 7.71 6.53 -1.18 -0.123 0.20181E+04 15 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 19 spessartine 24.46 19.70 -4.76 -0.238 0.81222E+04 20 analcite 3.32 2.77 -0.55 -0.061 0.93604E+03 26 annite 20.12 17.72 -2.40 -0.134 0.41062E+04 27 phlogopite 27.06 25.40 -1.67 -0.093 0.28482E+04 29 anorthite 12.71 8.27 -4.44 -0.342 0.75893E+04 35 aragonite 0.97 -3.71 -4.68 -1.559 0.79860E+04 36 brucite 12.57 9.29 -3.27 -0.655 0.55907E+04 37 calcite 0.81 -3.71 -4.52 -1.507 0.77217E+04 38 carnegieite-low 9.02 5.93 -3.09 -0.442 0.52797E+04 39 carnegieite-high 10.09 5.93 -4.16 -0.595 0.71067E+04 40 carpholite-Mg 8.58 4.46 -4.12 -0.275 0.70419E+04 41 carpholite-Fe 6.71 1.90 -4.81 -0.321 0.82198E+04 42 celadonite 5.34 3.65 -1.69 -0.099 0.28878E+04 43 celadonite-Fe 3.88 1.09 -2.79 -0.164 0.47562E+04 44 chrysotile 23.89 21.57 -2.32 -0.194 0.39689E+04 49 chlorite-Al-free 47.17 43.14 -4.04 -0.168 0.68930E+04 51 chloritoid-Fe 9.17 5.06 -4.12 -0.274 0.70304E+04 52 chloritoid-Mn 11.40 7.55 -3.85 -0.257 0.65712E+04 54 coesite -2.38 -3.16 -0.78 -0.260 0.13343E+04 61 cristobalite -2.56 -3.16 -0.60 -0.199 0.10197E+04 63 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71234E+04 65 diaspore 2.87 0.74 -2.13 -0.356 0.36444E+04 66 diamond -3.10 -7.85 -4.74 -1.355 0.81001E+04 71 enstatite 17.26 12.27 -4.99 -0.499 0.85225E+04 73 clinoenstatite 17.17 12.27 -4.89 -0.489 0.83541E+04 75 epidote 24.67 22.70 -1.97 -0.095 0.33577E+04 76 clinozoisite 22.81 18.95 -3.86 -0.175 0.65852E+04 77 epidote-Fe 29.84 26.46 -3.38 -0.176 0.57767E+04 78 fayalite 14.05 10.31 -3.73 -0.533 0.63743E+04 79 ferrosilite 11.15 7.16 -3.99 -0.399 0.68204E+04 83 gibbsite 4.08 0.74 -3.34 -0.477 0.57029E+04 84 glaucophane 22.97 20.80 -2.17 -0.059 0.37131E+04 85 glaucophane-Fe 17.28 13.12 -4.15 -0.112 0.70920E+04 86 graphite -3.55 -7.85 -4.30 -1.229 0.73423E+04 87 greenalite 16.14 13.89 -2.25 -0.187 0.38409E+04 90 hematite 12.57 8.99 -3.58 -0.434 0.61114E+04 91 heulandite -5.83 -7.52 -1.69 -0.077 0.28938E+04 95 jadeite 4.22 2.77 -1.44 -0.144 0.24615E+04 97 kalsilite 7.58 3.83 -3.76 -0.536 0.64122E+04 98 kaolinite -1.33 -4.84 -3.50 -0.319 0.59823E+04 101 laumontite 2.88 1.95 -0.93 -0.062 0.15929E+04 102 lawsonite 9.62 8.27 -1.35 -0.090 0.23059E+04 103 leucite 4.12 0.67 -3.45 -0.345 0.58871E+04 105 lizardite 23.24 21.57 -1.68 -0.140 0.28616E+04 107 magnetite 20.09 15.72 -4.37 -0.356 0.74538E+04 108 minnesotaite 10.39 7.57 -2.81 -0.165 0.48033E+04 112 manganosite 14.06 9.23 -4.83 -1.207 0.82414E+04 120 muscovite 2.58 -1.01 -3.59 -0.211 0.61303E+04 121 paragonite 4.24 1.09 -3.14 -0.185 0.53694E+04 122 nepheline 8.34 5.93 -2.41 -0.344 0.41121E+04 128 periclase-Fe 11.63 6.74 -4.89 -1.223 0.83522E+04 134 phlogopite-Na 29.65 27.50 -2.15 -0.119 0.36670E+04 136 prehnite 19.37 18.21 -1.16 -0.068 0.19839E+04 137 prehnite-Fe 22.50 21.96 -0.53 -0.032 0.91132E+03 138 pumpellyite-Fe 46.27 43.89 -2.38 -0.053 0.40554E+04 139 pumpellyite-Mg 48.99 46.45 -2.54 -0.056 0.43391E+04 143 pyrrhotite -4.26 -8.05 -3.79 -1.263 0.64711E+04 144 pyrrhotiteFe0.875 -6.02 -9.45 -3.43 -1.262 0.58584E+04 145 pyroxmangite 7.40 6.07 -1.32 -0.265 0.22620E+04 146 pyrophyllite -6.18 -11.15 -4.98 -0.311 0.84958E+04 147 quartz -2.99 -3.16 -0.17 -0.056 0.28701E+03 152 rhodonite 7.45 6.07 -1.37 -0.274 0.23422E+04 153 sanidine -1.28 -2.49 -1.21 -0.093 0.20677E+04 165 stilpnomelane-Mg 27.44 25.81 -1.63 -0.049 0.27796E+04 171 talc 16.49 15.25 -1.24 -0.073 0.21142E+04 174 tephroite 18.09 15.31 -2.78 -0.397 0.47474E+04 178 tridymite -2.63 -3.16 -0.53 -0.177 0.90698E+03 179 tremolite 47.87 47.42 -0.45 -0.012 0.77501E+03 180 ferroactinolite 38.45 34.62 -3.83 -0.104 0.65456E+04 181 troilite-low -4.41 -8.05 -3.64 -1.213 0.62139E+04 183 vesuvianite 223.47 218.82 -4.65 -0.035 0.79363E+04 187 wairakite 3.95 1.95 -2.00 -0.118 0.34148E+04 188 walstromite 11.51 9.94 -1.56 -0.313 0.26719E+04 189 wollastonite 10.46 9.94 -0.52 -0.103 0.88228E+03 190 pseudo-wollastonite 11.00 9.94 -1.06 -0.211 0.18021E+04 191 zoisite 22.85 18.95 -3.90 -0.177 0.66593E+04 192 akaganeite 7.75 4.49 -3.26 -0.705 0.55683E+04 199 chalcedony -2.80 -3.16 -0.36 -0.118 0.60630E+03 201 montmorillonite-Ca -2.29 -6.17 -3.88 -0.240 0.66177E+04 202 montmorillonite-K -2.24 -6.27 -4.03 -0.247 0.68814E+04 203 montmorillonite-Mg -2.48 -6.79 -4.31 -0.267 0.73675E+04 204 montmorillonite-Na -2.04 -5.57 -3.54 -0.216 0.60362E+04 205 nontronite-Ca 3.21 -0.20 -3.41 -0.221 0.58223E+04 206 nontronite-H 2.53 -2.36 -4.89 -0.328 0.83493E+04 207 nontronite-K 3.34 -0.30 -3.64 -0.233 0.62092E+04 208 nontronite-Mg 3.07 -0.82 -3.90 -0.253 0.66561E+04 209 nontronite-Na 3.52 0.40 -3.12 -0.200 0.53300E+04 224 tobermorite 9.82 7.76 -2.07 -0.564 0.35287E+04 230 alabandite -0.98 -5.55 -4.58 -1.525 0.78132E+04 233 boehmite 4.41 0.74 -3.67 -0.611 0.62613E+04 235 ferrous-oxide 9.81 6.74 -3.08 -0.769 0.52531E+04 240 silica-amorphous -2.09 -3.16 -1.07 -0.355 0.18205E+04 242 an20ab80 2.02 1.35 -0.67 -0.052 0.11470E+04 243 an25ab75 2.65 1.78 -0.87 -0.067 0.14807E+04 244 an30ab70 3.28 2.21 -1.07 -0.082 0.18241E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 10.0000000 g Current total amount of reactant added: 349.9990000 g New total amount of reactant added: 359.9990000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.3649E-11 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 11 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 359.9990000 Water: Moles liquid = 0.5342E+02 kg liquid = 0.9623E+00 Moles total = 0.5100E+02 kg total = 0.9187E+00 Activity = 1.0000 Stoichiometric ionic strength = .1132121E-01 Osmotic coef. = 0.9695 True ionic strength = .2001026E-01 Chg. balance for total moles = 0.3649E-11 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.88258E-10 -10.0542 0.74160E-10 -10.1298 0.84027E+00 -0.0756 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.14272E-03 -3.8455 0.11920E-03 -3.9237 0.83522E+00 -0.0782 4 SO4-- 0.67152E-12 -12.1729 0.34876E-12 -12.4575 0.51936E+00 -0.2845 5 HCO3- 0.24853E-06 -6.6046 0.20788E-06 -6.6822 0.83644E+00 -0.0776 6 HS- 0.26498E-04 -4.5768 0.22135E-04 -4.6549 0.83534E+00 -0.0781 7 Al+++ 0.96841E-29 -29.0139 0.22379E-29 -29.6502 0.23109E+00 -0.6362 8 H4SiO4 0.69579E-03 -3.1575 0.69579E-03 -3.1575 0.10000E+01 0.0000 9 Ca++ 0.13490E-06 -6.8700 0.69549E-07 -7.1577 0.51555E+00 -0.2877 10 Mg++ 0.21105E-10 -10.6756 0.10831E-10 -10.9653 0.51319E+00 -0.2897 11 Fe++ 0.58158E-13 -13.2354 0.29879E-13 -13.5246 0.51376E+00 -0.2892 12 K+ 0.15645E-03 -3.8056 0.13089E-03 -3.8831 0.83664E+00 -0.0775 13 Na+ 0.19853E-01 -1.7022 0.16578E-01 -1.7805 0.83507E+00 -0.0783 14 Mn++ 0.18238E-10 -10.7390 0.93779E-11 -11.0279 0.51418E+00 -0.2889 15 HPO4-- 0.45329E-07 -7.3436 0.23546E-07 -7.6281 0.51944E+00 -0.2845 16 HSiO3- 0.10489E-01 -1.9793 0.87606E-02 -2.0575 0.83522E+00 -0.0782 17 Ca(HSiO3)+ 0.16582E-07 -7.7804 0.13876E-07 -7.8577 0.83682E+00 -0.0774 18 Mg(HSiO3)+ 0.32137E-11 -11.4930 0.26893E-11 -11.5704 0.83682E+00 -0.0774 19 NaHSiO3,aq 0.23490E-02 -2.6291 0.23490E-02 -2.6291 0.10000E+01 0.0000 20 AlO+ 0.66151E-16 -16.1795 0.55356E-16 -16.2568 0.83682E+00 -0.0774 22 HAlO2,aq 0.14865E-09 -9.8278 0.14865E-09 -9.8278 0.10000E+01 0.0000 23 AlO2- 0.53221E-05 -5.2739 0.44371E-05 -5.3529 0.83371E+00 -0.0790 24 CH4,aq 0.12861E-04 -4.8907 0.12816E-04 -4.8922 0.99655E+00 -0.0015 25 C2H6,aq 0.24312E-14 -14.6142 0.24228E-14 -14.6157 0.99655E+00 -0.0015 29 CO,aq 0.95909E-17 -17.0181 0.95909E-17 -17.0181 0.10000E+01 0.0000 30 CO2,aq 0.33056E-10 -10.4808 0.32942E-10 -10.4823 0.99655E+00 -0.0015 31 CO3-2 0.47243E-06 -6.3257 0.24484E-06 -6.6111 0.51826E+00 -0.2855 32 CaCO3,aq 0.21352E-09 -9.6706 0.21352E-09 -9.6706 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.44102E-12 -12.3555 0.36906E-12 -12.4329 0.83682E+00 -0.0774 34 CaCl+ 0.16033E-10 -10.7950 0.13417E-10 -10.8724 0.83682E+00 -0.0774 35 CaCl2,aq 0.37997E-15 -15.4203 0.37997E-15 -15.4203 0.10000E+01 0.0000 36 CaOH+ 0.79871E-07 -7.0976 0.66838E-07 -7.1750 0.83682E+00 -0.0774 37 CaSO4,aq 0.77024E-17 -17.1134 0.77024E-17 -17.1134 0.10000E+01 0.0000 38 HCl,aq 0.16199E-14 -14.7905 0.16199E-14 -14.7905 0.10000E+01 0.0000 43 FeCl+ 0.67369E-17 -17.1715 0.56376E-17 -17.2489 0.83682E+00 -0.0774 46 FeO,aq 0.21115E-09 -9.6754 0.21115E-09 -9.6754 0.10000E+01 0.0000 47 FeOH+ 0.15672E-10 -10.8049 0.13115E-10 -10.8822 0.83682E+00 -0.0774 48 HFeO2- 0.35668E-07 -7.4477 0.29790E-07 -7.5259 0.83522E+00 -0.0782 49 FeO+ 0.10980E-16 -16.9594 0.91885E-17 -17.0368 0.83682E+00 -0.0774 51 FeO2- 0.40931E-09 -9.3880 0.34186E-09 -9.4661 0.83522E+00 -0.0782 52 HFeO2,aq 0.32245E-11 -11.4915 0.32245E-11 -11.4915 0.10000E+01 0.0000 53 H2,aq 0.11630E-04 -4.9344 0.11590E-04 -4.9359 0.99655E+00 -0.0015 54 KCl,aq 0.28279E-09 -9.5485 0.28279E-09 -9.5485 0.10000E+01 0.0000 56 KOH,aq 0.75376E-06 -6.1228 0.75376E-06 -6.1228 0.10000E+01 0.0000 57 KSO4- 0.84814E-15 -15.0715 0.70838E-15 -15.1497 0.83522E+00 -0.0782 58 MgCO3,aq 0.83348E-14 -14.0791 0.83348E-14 -14.0791 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.70179E-16 -16.1538 0.58727E-16 -16.2312 0.83682E+00 -0.0774 60 MgCl+ 0.22630E-14 -14.6453 0.18937E-14 -14.7227 0.83682E+00 -0.0774 61 MgOH+ 0.68828E-10 -10.1622 0.57597E-10 -10.2396 0.83682E+00 -0.0774 63 MnO,aq 0.17659E-08 -8.7530 0.17659E-08 -8.7530 0.10000E+01 0.0000 64 MnOH+ 0.45695E-09 -9.3401 0.38238E-09 -9.4175 0.83682E+00 -0.0774 65 MnO2-2 0.20560E-10 -10.6870 0.10656E-10 -10.9724 0.51826E+00 -0.2855 66 HMnO2- 0.20728E-09 -9.6834 0.17313E-09 -9.7616 0.83522E+00 -0.0782 69 MnCl+ 0.82262E-14 -14.0848 0.68839E-14 -14.1622 0.83682E+00 -0.0774 71 NaCl,aq 0.65493E-06 -6.1838 0.65493E-06 -6.1838 0.10000E+01 0.0000 72 NaOH,aq 0.96047E-04 -4.0175 0.96047E-04 -4.0175 0.10000E+01 0.0000 74 OH- 0.93448E-02 -2.0294 0.77909E-02 -2.1084 0.83371E+00 -0.0790 79 HPO3-2 0.16409E-14 -14.7849 0.85042E-15 -15.0704 0.51826E+00 -0.2855 81 H2PO3- 0.15142E-18 -18.8198 0.12647E-18 -18.8980 0.83522E+00 -0.0782 82 H3PO4,aq 0.90569E-18 -18.0430 0.90569E-18 -18.0430 0.10000E+01 0.0000 83 H2PO4- 0.38530E-10 -10.4142 0.32212E-10 -10.4920 0.83601E+00 -0.0778 84 PO4-3 0.10673E-08 -8.9717 0.25904E-09 -9.5866 0.24271E+00 -0.6149 88 HP2O7-3 0.94700E-18 -18.0236 0.21906E-18 -18.6594 0.23132E+00 -0.6358 89 P2O7-4 0.91478E-17 -17.0387 0.70566E-18 -18.1514 0.77140E-01 -1.1127 90 H2S,aq 0.50910E-08 -8.2932 0.50734E-08 -8.2947 0.99655E+00 -0.0015 91 S2-2 0.18075E-14 -14.7429 0.93673E-15 -15.0284 0.51826E+00 -0.2855 97 SO3-2 0.99908E-18 -18.0004 0.52527E-18 -18.2796 0.52575E+00 -0.2792 99 HSO4- 0.29757E-19 -19.5264 0.24926E-19 -19.6034 0.83763E+00 -0.0769 Charge balance for all species = 0.3791E-11 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.8825753E-10 -.2230443E-01 -.2244247E+02 0.0000 2 H2O 0.1000000E+01 0.5550489E+02 0.9982001E+06 0.0000 3 Cl- 0.1427224E-03 0.1433776E-03 0.5074335E+01 6.2061 4 SO4-- 0.6715176E-12 -.1576809E-04 -.1512077E+01 7.8022 5 HCO3- 0.2485315E-06 0.1358185E-04 0.8272870E+00 3.4476 6 HS- 0.2649820E-04 0.4227138E-04 0.1395570E+01 5.4749 7 Al+++ 0.9684085E-29 0.5322210E-05 0.1433517E+00 0.7393 8 H4SiO4 0.6957920E-03 0.1353379E-01 0.1298546E+04 -3.1575 9 Ca++ 0.1349027E-06 0.2315858E-06 0.9265373E-02 13.1019 10 Mg++ 0.2110509E-10 0.9315781E-10 0.2260918E-05 9.2943 11 Fe++ 0.5815813E-13 0.3630716E-07 0.2024124E-02 6.7350 12 K+ 0.1564507E-03 0.1572047E-03 0.6136341E+01 6.2467 13 Na+ 0.1985279E-01 0.2229851E-01 0.5117477E+03 8.3494 14 Mn++ 0.1823849E-10 0.2468887E-08 0.1354001E-03 9.2318 15 HPO4-- 0.4532948E-07 0.4643533E-07 0.4449074E-02 12.6316 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.5961036E+01 -.2146386E-01 -.5939572E+01 0.0000000E+00 2 H2O 0.5099552E+02 0.5341310E+02 -.2417583E+01 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.1000230E-01 -.1517385E-04 0.1001748E-01 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.9976799E-02 0.4067832E-04 -.1001748E-01 0.0000000E+00 7 Al+++ 0.1173864E+01 0.5121634E-05 0.1173859E+01 0.0000000E+00 8 H4SiO4 0.3748591E+01 0.1302375E-01 0.3735568E+01 0.0000000E+00 9 Ca++ 0.4140647E+00 0.2228582E-06 0.4140645E+00 0.0000000E+00 10 Mg++ 0.2857135E+00 0.8964701E-10 0.2857135E+00 0.0000000E+00 11 Fe++ 0.2566824E+00 0.3493887E-07 0.2566823E+00 0.0000000E+00 12 K+ 0.7643291E-01 0.1512802E-03 0.7628163E-01 0.0000000E+00 13 Na+ 0.4520465E+00 0.2145815E-01 0.4305884E+00 0.0000000E+00 14 Mn++ 0.6241877E-02 0.2375843E-08 0.6241875E-02 0.0000000E+00 15 HPO4-- 0.2130322E-02 0.4468534E-07 0.2130277E-02 0.0000000E+00 Chg. balance for solid moles: -.1665E-15 Mass of aqueous solution: 0.963988E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 359.9990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 0.4301 -0.366 112.8 2.052 28.69 43.30 andradite 0.4007E-01 -1.397 20.36 1.309 5.180 5.290 grossular 0.9712E-02 -2.013 4.375 0.641 1.113 1.217 apatite-OH 0.7101E-03 -3.149 0.3567 -0.448 0.9074E-01 0.1133 clinochlore 0.5233E-01 -1.281 29.08 1.464 7.399 11.06 daphnite 0.1515E-01 -1.820 10.81 1.034 2.749 3.275 chlorite-Mn 0.1248E-02 -2.904 0.8851 -0.053 0.2251 0.2820 diopside 0.1032E-01 -1.986 2.235 0.349 0.5686 0.6831 hedenbergite 0.2676E-02 -2.573 0.6639 -0.178 0.1689 0.1819 microcline 0.6694E-01 -1.174 18.63 1.270 4.740 7.278 stilbite 0.2406 -0.619 169.5 2.229 43.13 79.08 stilpnomelane-Fe 0.1868E-01 -1.729 20.14 1.304 5.122 6.955 tr.625ac.25prg.125 0.3796E-02 -2.421 3.245 0.511 0.8254 1.044 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8049E+00 0.8049E+00 1.0000 -0.094 grossular 0.1951E+00 0.1951E+00 1.0000 -0.710 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.7614E+00 0.7614E+00 1.0000 -0.118 daphnite 0.2204E+00 0.2204E+00 1.0000 -0.657 chlorite-Mn 0.1817E-01 0.1817E-01 1.0000 -1.741 diopside 0.7941E+00 0.7941E+00 1.0000 -0.100 hedenbergite 0.2059E+00 0.2059E+00 1.0000 -0.686 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 tr.625ac.25prg.125 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 393.107141 g Volume = 159.755685 cm3 Porosity: -10.1766% V(tot) - V(min): -.14756E+02 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 359.9990000 g log = 2.5563 Original solution: 1000.0103000 g Original solution / Rock added: 2.78 (Water/Rock Ratio), log = 0.4437 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0546 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9679E+00 0.9855 0.1006E+01 0.1021E+01 CO2,gas 0.3319E-08 1.0069 0.3524E-08 0.3500E-08 CH4,gas 0.1767E-01 1.0125 0.1886E-01 0.1863E-01 H2,gas 0.1442E-01 1.0006 0.1522E-01 0.1521E-01 H2S,gas 0.1328E-06 0.9959 0.1395E-06 0.1400E-06 S2,gas 0.2990E-29 1.0000 0.3153E-29 0.3153E-29 CO,gas 0.1355E-13 1.0000 0.1429E-13 0.1429E-13 SO3,gas 0.6877E-48 1.0000 0.7252E-48 0.7252E-48 SO2,gas 0.4071E-27 1.0000 0.4293E-27 0.4293E-27 HCl,gas 0.2710E-17 1.0000 0.2858E-17 0.2858E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 16 albite -0.38 -0.38 0.00 0.000 -0.94784E-12 22 andradite 39.01 39.01 0.00 0.000 0.00000E+00 23 grossular 32.73 32.73 0.00 0.000 0.00000E+00 32 apatite-OH -18.15 -18.15 0.00 0.000 0.00000E+00 46 clinochlore 39.07 39.07 0.00 0.000 0.00000E+00 47 daphnite 28.97 28.97 0.00 0.000 -0.12132E-10 48 chlorite-Mn 46.87 46.87 0.00 0.000 0.12132E-10 67 diopside 16.18 16.18 0.00 0.000 0.00000E+00 68 hedenbergite 14.21 14.21 0.00 0.000 0.00000E+00 116 microcline -2.49 -2.49 0.00 0.000 0.15165E-11 163 stilbite -7.52 -7.52 0.00 0.000 -0.90992E-11 164 stilpnomelane-Fe 13.02 13.02 0.00 0.000 0.21232E-10 245 tr.625ac.25prg.125 45.16 45.16 0.00 0.000 -0.24265E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -16.81 -10.15 -3.384 0.17334E+05 -8.453 3 CH4,gas 4.54 1.12 -3.42 -0.856 0.58452E+04 -1.724 4 H2,gas 8.00 4.48 -3.52 -2.010 0.60046E+04 -1.818 5 H2S,gas -6.23 -14.78 -8.55 -4.277 0.14607E+05 -6.856 6 S2,gas -7.34 -38.54 -31.20 -4.800 0.53273E+05 -29.501 7 CO,gas 3.21 -12.33 -15.54 -4.783 0.26541E+05 -13.845 8 SO3,gas 17.12 -32.72 -49.84 -12.460 0.85098E+05 -48.140 9 SO2,gas 0.83 -28.23 -29.07 -7.751 0.49630E+05 -27.367 10 HCl,gas 5.19 -14.05 -19.24 -9.621 0.32857E+05 -17.544 11 acmite 7.71 6.53 -1.18 -0.123 0.20181E+04 15 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 19 spessartine 24.46 19.70 -4.76 -0.238 0.81207E+04 20 analcite 3.32 2.77 -0.55 -0.061 0.93605E+03 26 annite 20.12 17.72 -2.40 -0.134 0.41062E+04 27 phlogopite 27.06 25.40 -1.67 -0.093 0.28483E+04 29 anorthite 12.71 8.27 -4.44 -0.342 0.75893E+04 35 aragonite 0.97 -3.71 -4.68 -1.559 0.79851E+04 36 brucite 12.57 9.29 -3.27 -0.655 0.55907E+04 37 calcite 0.81 -3.71 -4.52 -1.507 0.77209E+04 38 carnegieite-low 9.02 5.93 -3.09 -0.442 0.52797E+04 39 carnegieite-high 10.09 5.93 -4.16 -0.595 0.71067E+04 40 carpholite-Mg 8.58 4.46 -4.12 -0.275 0.70419E+04 41 carpholite-Fe 6.71 1.90 -4.81 -0.321 0.82198E+04 42 celadonite 5.34 3.65 -1.69 -0.099 0.28878E+04 43 celadonite-Fe 3.88 1.09 -2.79 -0.164 0.47562E+04 44 chrysotile 23.89 21.57 -2.32 -0.194 0.39689E+04 49 chlorite-Al-free 47.17 43.14 -4.04 -0.168 0.68931E+04 51 chloritoid-Fe 9.17 5.06 -4.12 -0.274 0.70305E+04 52 chloritoid-Mn 11.40 7.55 -3.85 -0.257 0.65707E+04 54 coesite -2.38 -3.16 -0.78 -0.260 0.13343E+04 61 cristobalite -2.56 -3.16 -0.60 -0.199 0.10197E+04 63 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71234E+04 65 diaspore 2.87 0.74 -2.13 -0.356 0.36444E+04 66 diamond -3.10 -7.85 -4.74 -1.355 0.80993E+04 71 enstatite 17.26 12.27 -4.99 -0.499 0.85225E+04 73 clinoenstatite 17.17 12.27 -4.89 -0.489 0.83541E+04 75 epidote 24.67 22.70 -1.97 -0.095 0.33577E+04 76 clinozoisite 22.81 18.95 -3.86 -0.175 0.65853E+04 77 epidote-Fe 29.84 26.46 -3.38 -0.176 0.57767E+04 78 fayalite 14.05 10.31 -3.73 -0.533 0.63743E+04 79 ferrosilite 11.15 7.16 -3.99 -0.399 0.68204E+04 83 gibbsite 4.08 0.74 -3.34 -0.477 0.57029E+04 84 glaucophane 22.97 20.80 -2.17 -0.059 0.37131E+04 85 glaucophane-Fe 17.28 13.12 -4.15 -0.112 0.70920E+04 86 graphite -3.55 -7.85 -4.30 -1.228 0.73415E+04 87 greenalite 16.14 13.89 -2.25 -0.187 0.38409E+04 90 hematite 12.57 8.99 -3.58 -0.434 0.61114E+04 91 heulandite -5.83 -7.52 -1.69 -0.077 0.28938E+04 95 jadeite 4.22 2.77 -1.44 -0.144 0.24615E+04 97 kalsilite 7.58 3.83 -3.76 -0.536 0.64122E+04 98 kaolinite -1.33 -4.84 -3.50 -0.319 0.59824E+04 101 laumontite 2.88 1.95 -0.93 -0.062 0.15929E+04 102 lawsonite 9.62 8.27 -1.35 -0.090 0.23060E+04 103 leucite 4.12 0.67 -3.45 -0.345 0.58871E+04 105 lizardite 23.24 21.57 -1.68 -0.140 0.28616E+04 107 magnetite 20.09 15.72 -4.37 -0.356 0.74538E+04 108 minnesotaite 10.39 7.57 -2.81 -0.165 0.48033E+04 112 manganosite 14.06 9.23 -4.83 -1.207 0.82409E+04 120 muscovite 2.58 -1.01 -3.59 -0.211 0.61303E+04 121 paragonite 4.24 1.09 -3.14 -0.185 0.53694E+04 122 nepheline 8.34 5.93 -2.41 -0.344 0.41121E+04 128 periclase-Fe 11.63 6.74 -4.89 -1.223 0.83522E+04 134 phlogopite-Na 29.65 27.50 -2.15 -0.119 0.36671E+04 136 prehnite 19.37 18.21 -1.16 -0.068 0.19839E+04 137 prehnite-Fe 22.50 21.96 -0.53 -0.032 0.91133E+03 138 pumpellyite-Fe 46.27 43.89 -2.38 -0.053 0.40555E+04 139 pumpellyite-Mg 48.99 46.45 -2.54 -0.056 0.43392E+04 143 pyrrhotite -4.26 -8.05 -3.79 -1.263 0.64703E+04 144 pyrrhotiteFe0.875 -6.02 -9.45 -3.43 -1.262 0.58576E+04 145 pyroxmangite 7.40 6.07 -1.32 -0.265 0.22614E+04 146 pyrophyllite -6.18 -11.15 -4.98 -0.311 0.84958E+04 147 quartz -2.99 -3.16 -0.17 -0.056 0.28700E+03 152 rhodonite 7.45 6.07 -1.37 -0.274 0.23417E+04 153 sanidine -1.28 -2.49 -1.21 -0.093 0.20677E+04 165 stilpnomelane-Mg 27.44 25.81 -1.63 -0.049 0.27796E+04 171 talc 16.49 15.25 -1.24 -0.073 0.21142E+04 174 tephroite 18.09 15.31 -2.78 -0.397 0.47464E+04 178 tridymite -2.63 -3.16 -0.53 -0.177 0.90698E+03 179 tremolite 47.87 47.42 -0.45 -0.012 0.77501E+03 180 ferroactinolite 38.45 34.62 -3.83 -0.104 0.65456E+04 181 troilite-low -4.41 -8.05 -3.64 -1.213 0.62131E+04 183 vesuvianite 223.47 218.82 -4.65 -0.035 0.79365E+04 187 wairakite 3.95 1.95 -2.00 -0.118 0.34149E+04 188 walstromite 11.51 9.94 -1.56 -0.313 0.26719E+04 189 wollastonite 10.46 9.94 -0.52 -0.103 0.88228E+03 190 pseudo-wollastonite 11.00 9.94 -1.06 -0.211 0.18021E+04 191 zoisite 22.85 18.95 -3.90 -0.177 0.66593E+04 192 akaganeite 7.75 4.49 -3.26 -0.705 0.55683E+04 199 chalcedony -2.80 -3.16 -0.36 -0.118 0.60630E+03 201 montmorillonite-Ca -2.29 -6.17 -3.88 -0.240 0.66177E+04 202 montmorillonite-K -2.24 -6.27 -4.03 -0.247 0.68814E+04 203 montmorillonite-Mg -2.48 -6.79 -4.31 -0.267 0.73675E+04 204 montmorillonite-Na -2.04 -5.57 -3.54 -0.216 0.60363E+04 205 nontronite-Ca 3.21 -0.20 -3.41 -0.221 0.58223E+04 206 nontronite-H 2.53 -2.36 -4.89 -0.328 0.83493E+04 207 nontronite-K 3.34 -0.30 -3.64 -0.233 0.62091E+04 208 nontronite-Mg 3.07 -0.82 -3.90 -0.253 0.66561E+04 209 nontronite-Na 3.52 0.40 -3.12 -0.200 0.53300E+04 224 tobermorite 9.82 7.76 -2.07 -0.564 0.35287E+04 230 alabandite -0.98 -5.55 -4.58 -1.525 0.78119E+04 233 boehmite 4.41 0.74 -3.67 -0.611 0.62613E+04 235 ferrous-oxide 9.81 6.74 -3.08 -0.769 0.52531E+04 240 silica-amorphous -2.09 -3.16 -1.07 -0.355 0.18205E+04 242 an20ab80 2.02 1.35 -0.67 -0.052 0.11470E+04 243 an25ab75 2.65 1.78 -0.87 -0.067 0.14807E+04 244 an30ab70 3.28 2.21 -1.07 -0.082 0.18241E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 10.0000000 g Current total amount of reactant added: 359.9990000 g New total amount of reactant added: 369.9990000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.3649E-11 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 11 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 369.9990000 Water: Moles liquid = 0.5336E+02 kg liquid = 0.9613E+00 Moles total = 0.5087E+02 kg total = 0.9164E+00 Activity = 1.0000 Stoichiometric ionic strength = .1132136E-01 Osmotic coef. = 0.9695 True ionic strength = .2001040E-01 Chg. balance for total moles = 0.3649E-11 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.88258E-10 -10.0542 0.74161E-10 -10.1298 0.84027E+00 -0.0756 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.14287E-03 -3.8451 0.11933E-03 -3.9233 0.83522E+00 -0.0782 4 SO4-- 0.67226E-12 -12.1725 0.34915E-12 -12.4570 0.51936E+00 -0.2845 5 HCO3- 0.24881E-06 -6.6041 0.20811E-06 -6.6817 0.83644E+00 -0.0776 6 HS- 0.26526E-04 -4.5763 0.22158E-04 -4.6545 0.83534E+00 -0.0781 7 Al+++ 0.96841E-29 -29.0139 0.22379E-29 -29.6502 0.23109E+00 -0.6362 8 H4SiO4 0.69580E-03 -3.1575 0.69580E-03 -3.1575 0.10000E+01 0.0000 9 Ca++ 0.13490E-06 -6.8700 0.69550E-07 -7.1577 0.51555E+00 -0.2877 10 Mg++ 0.21105E-10 -10.6756 0.10831E-10 -10.9653 0.51319E+00 -0.2897 11 Fe++ 0.58159E-13 -13.2354 0.29879E-13 -13.5246 0.51375E+00 -0.2892 12 K+ 0.15645E-03 -3.8056 0.13089E-03 -3.8831 0.83664E+00 -0.0775 13 Na+ 0.19853E-01 -1.7022 0.16579E-01 -1.7805 0.83507E+00 -0.0783 14 Mn++ 0.18251E-10 -10.7387 0.93841E-11 -11.0276 0.51418E+00 -0.2889 15 HPO4-- 0.45330E-07 -7.3436 0.23546E-07 -7.6281 0.51943E+00 -0.2845 16 HSiO3- 0.10489E-01 -1.9793 0.87606E-02 -2.0575 0.83522E+00 -0.0782 17 Ca(HSiO3)+ 0.16582E-07 -7.7804 0.13876E-07 -7.8577 0.83682E+00 -0.0774 18 Mg(HSiO3)+ 0.32137E-11 -11.4930 0.26893E-11 -11.5704 0.83682E+00 -0.0774 19 NaHSiO3,aq 0.23490E-02 -2.6291 0.23490E-02 -2.6291 0.10000E+01 0.0000 20 AlO+ 0.66150E-16 -16.1795 0.55356E-16 -16.2568 0.83682E+00 -0.0774 22 HAlO2,aq 0.14865E-09 -9.8278 0.14865E-09 -9.8278 0.10000E+01 0.0000 23 AlO2- 0.53219E-05 -5.2739 0.44369E-05 -5.3529 0.83371E+00 -0.0790 24 CH4,aq 0.12874E-04 -4.8903 0.12830E-04 -4.8918 0.99655E+00 -0.0015 25 C2H6,aq 0.24363E-14 -14.6133 0.24279E-14 -14.6148 0.99655E+00 -0.0015 29 CO,aq 0.96014E-17 -17.0177 0.96014E-17 -17.0177 0.10000E+01 0.0000 30 CO2,aq 0.33093E-10 -10.4803 0.32978E-10 -10.4818 0.99655E+00 -0.0015 31 CO3-2 0.47296E-06 -6.3252 0.24511E-06 -6.6106 0.51826E+00 -0.2855 32 CaCO3,aq 0.21376E-09 -9.6701 0.21376E-09 -9.6701 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.44151E-12 -12.3551 0.36947E-12 -12.4324 0.83682E+00 -0.0774 34 CaCl+ 0.16050E-10 -10.7945 0.13431E-10 -10.8719 0.83682E+00 -0.0774 35 CaCl2,aq 0.38077E-15 -15.4193 0.38077E-15 -15.4193 0.10000E+01 0.0000 36 CaOH+ 0.79871E-07 -7.0976 0.66838E-07 -7.1750 0.83682E+00 -0.0774 37 CaSO4,aq 0.77110E-17 -17.1129 0.77110E-17 -17.1129 0.10000E+01 0.0000 38 HCl,aq 0.16216E-14 -14.7900 0.16216E-14 -14.7900 0.10000E+01 0.0000 43 FeCl+ 0.67440E-17 -17.1711 0.56436E-17 -17.2484 0.83682E+00 -0.0774 46 FeO,aq 0.21115E-09 -9.6754 0.21115E-09 -9.6754 0.10000E+01 0.0000 47 FeOH+ 0.15672E-10 -10.8049 0.13115E-10 -10.8822 0.83682E+00 -0.0774 48 HFeO2- 0.35667E-07 -7.4477 0.29790E-07 -7.5259 0.83522E+00 -0.0782 49 FeO+ 0.10980E-16 -16.9594 0.91886E-17 -17.0367 0.83682E+00 -0.0774 51 FeO2- 0.40931E-09 -9.3880 0.34186E-09 -9.4661 0.83522E+00 -0.0782 52 HFeO2,aq 0.32245E-11 -11.4915 0.32245E-11 -11.4915 0.10000E+01 0.0000 53 H2,aq 0.11630E-04 -4.9344 0.11590E-04 -4.9359 0.99655E+00 -0.0015 54 KCl,aq 0.28309E-09 -9.5481 0.28309E-09 -9.5481 0.10000E+01 0.0000 56 KOH,aq 0.75375E-06 -6.1228 0.75375E-06 -6.1228 0.10000E+01 0.0000 57 KSO4- 0.84909E-15 -15.0710 0.70917E-15 -15.1492 0.83522E+00 -0.0782 58 MgCO3,aq 0.83440E-14 -14.0786 0.83440E-14 -14.0786 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.70257E-16 -16.1533 0.58793E-16 -16.2307 0.83682E+00 -0.0774 60 MgCl+ 0.22654E-14 -14.6449 0.18957E-14 -14.7222 0.83682E+00 -0.0774 61 MgOH+ 0.68828E-10 -10.1622 0.57597E-10 -10.2396 0.83682E+00 -0.0774 63 MnO,aq 0.17670E-08 -8.7528 0.17670E-08 -8.7528 0.10000E+01 0.0000 64 MnOH+ 0.45725E-09 -9.3398 0.38263E-09 -9.4172 0.83682E+00 -0.0774 65 MnO2-2 0.20574E-10 -10.6867 0.10662E-10 -10.9721 0.51826E+00 -0.2855 66 HMnO2- 0.20742E-09 -9.6832 0.17324E-09 -9.7614 0.83522E+00 -0.0782 69 MnCl+ 0.82403E-14 -14.0841 0.68956E-14 -14.1614 0.83682E+00 -0.0774 71 NaCl,aq 0.65562E-06 -6.1834 0.65562E-06 -6.1834 0.10000E+01 0.0000 72 NaOH,aq 0.96047E-04 -4.0175 0.96047E-04 -4.0175 0.10000E+01 0.0000 74 OH- 0.93447E-02 -2.0294 0.77908E-02 -2.1084 0.83371E+00 -0.0790 79 HPO3-2 0.16409E-14 -14.7849 0.85041E-15 -15.0704 0.51826E+00 -0.2855 81 H2PO3- 0.15142E-18 -18.8198 0.12647E-18 -18.8980 0.83522E+00 -0.0782 82 H3PO4,aq 0.90570E-18 -18.0430 0.90570E-18 -18.0430 0.10000E+01 0.0000 83 H2PO4- 0.38531E-10 -10.4142 0.32212E-10 -10.4920 0.83601E+00 -0.0778 84 PO4-3 0.10673E-08 -8.9717 0.25904E-09 -9.5866 0.24270E+00 -0.6149 88 HP2O7-3 0.94701E-18 -18.0236 0.21906E-18 -18.6594 0.23132E+00 -0.6358 89 P2O7-4 0.91479E-17 -17.0387 0.70567E-18 -18.1514 0.77140E-01 -1.1127 90 H2S,aq 0.50963E-08 -8.2927 0.50787E-08 -8.2942 0.99655E+00 -0.0015 91 S2-2 0.18113E-14 -14.7420 0.93871E-15 -15.0275 0.51826E+00 -0.2855 97 SO3-2 0.10002E-17 -17.9999 0.52584E-18 -18.2791 0.52575E+00 -0.2792 99 HSO4- 0.29791E-19 -19.5259 0.24954E-19 -19.6029 0.83763E+00 -0.0769 Charge balance for all species = 0.3796E-11 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.8825815E-10 -.2230441E-01 -.2244245E+02 0.0000 2 H2O 0.1000000E+01 0.5550489E+02 0.9982001E+06 0.0000 3 Cl- 0.1428715E-03 0.1435274E-03 0.5079636E+01 6.2066 4 SO4-- 0.6722641E-12 -.1578143E-04 -.1513356E+01 7.8027 5 HCO3- 0.2488068E-06 0.1359604E-04 0.8281512E+00 3.4481 6 HS- 0.2652588E-04 0.4231241E-04 0.1396925E+01 5.4754 7 Al+++ 0.9684093E-29 0.5322056E-05 0.1433476E+00 0.7393 8 H4SiO4 0.6957974E-03 0.1353383E-01 0.1298550E+04 -3.1575 9 Ca++ 0.1349037E-06 0.2315871E-06 0.9265423E-02 13.1019 10 Mg++ 0.2110522E-10 0.9315789E-10 0.2260920E-05 9.2943 11 Fe++ 0.5815882E-13 0.3630684E-07 0.2024105E-02 6.7350 12 K+ 0.1564518E-03 0.1572058E-03 0.6136383E+01 6.2467 13 Na+ 0.1985293E-01 0.2229866E-01 0.5117512E+03 8.3494 14 Mn++ 0.1825063E-10 0.2470495E-08 0.1354883E-03 9.2320 15 HPO4-- 0.4532956E-07 0.4643541E-07 0.4449081E-02 12.6316 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.6126621E+01 -.2144143E-01 -.6105180E+01 0.0000000E+00 2 H2O 0.5087016E+02 0.5335736E+02 -.2487196E+01 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.1027944E-01 -.1517084E-04 0.1029461E-01 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.1025393E-01 0.4067531E-04 -.1029461E-01 0.0000000E+00 7 Al+++ 0.1206471E+01 0.5116141E-05 0.1206466E+01 0.0000000E+00 8 H4SiO4 0.3852719E+01 0.1301020E-01 0.3839709E+01 0.0000000E+00 9 Ca++ 0.4255661E+00 0.2226268E-06 0.4255659E+00 0.0000000E+00 10 Mg++ 0.2936500E+00 0.8955353E-10 0.2936500E+00 0.0000000E+00 11 Fe++ 0.2638125E+00 0.3490209E-07 0.2638124E+00 0.0000000E+00 12 K+ 0.7855605E-01 0.1511234E-03 0.7840493E-01 0.0000000E+00 13 Na+ 0.4645990E+00 0.2143591E-01 0.4431630E+00 0.0000000E+00 14 Mn++ 0.6415263E-02 0.2374910E-08 0.6415261E-02 0.0000000E+00 15 HPO4-- 0.2189497E-02 0.4463878E-07 0.2189453E-02 0.0000000E+00 Chg. balance for solid moles: 0.1447E-14 Mass of aqueous solution: 0.962982E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 369.9990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 0.4427 -0.354 116.1 2.065 28.73 44.56 andradite 0.4118E-01 -1.385 20.93 1.321 5.179 5.437 grossular 0.9981E-02 -2.001 4.496 0.653 1.113 1.251 apatite-OH 0.7298E-03 -3.137 0.3666 -0.436 0.9074E-01 0.1165 clinochlore 0.5374E-01 -1.270 29.87 1.475 7.394 11.36 daphnite 0.1556E-01 -1.808 11.10 1.045 2.747 3.363 chlorite-Mn 0.1283E-02 -2.892 0.9096 -0.041 0.2251 0.2899 diopside 0.1086E-01 -1.964 2.353 0.372 0.5824 0.7191 hedenbergite 0.2817E-02 -2.550 0.6989 -0.156 0.1730 0.1914 microcline 0.6880E-01 -1.162 19.15 1.282 4.740 7.481 stilbite 0.2470 -0.607 174.1 2.241 43.08 81.19 stilpnomelane-Fe 0.1920E-01 -1.717 20.70 1.316 5.123 7.150 tr.625ac.25prg.125 0.3879E-02 -2.411 3.316 0.521 0.8207 1.067 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8049E+00 0.8049E+00 1.0000 -0.094 grossular 0.1951E+00 0.1951E+00 1.0000 -0.710 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.7614E+00 0.7614E+00 1.0000 -0.118 daphnite 0.2204E+00 0.2204E+00 1.0000 -0.657 chlorite-Mn 0.1818E-01 0.1818E-01 1.0000 -1.740 diopside 0.7941E+00 0.7941E+00 1.0000 -0.100 hedenbergite 0.2059E+00 0.2059E+00 1.0000 -0.686 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 tr.625ac.25prg.125 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 404.032203 g Volume = 164.175991 cm3 Porosity: -10.1855% V(tot) - V(min): -.15176E+02 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 369.9990000 g log = 2.5682 Original solution: 1000.0103000 g Original solution / Rock added: 2.70 (Water/Rock Ratio), log = 0.4318 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0546 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9679E+00 0.9855 0.1006E+01 0.1021E+01 CO2,gas 0.3322E-08 1.0069 0.3528E-08 0.3504E-08 CH4,gas 0.1769E-01 1.0125 0.1888E-01 0.1865E-01 H2,gas 0.1442E-01 1.0006 0.1522E-01 0.1521E-01 H2S,gas 0.1329E-06 0.9959 0.1396E-06 0.1402E-06 S2,gas 0.2996E-29 1.0000 0.3160E-29 0.3160E-29 CO,gas 0.1357E-13 1.0000 0.1431E-13 0.1431E-13 SO3,gas 0.6884E-48 1.0000 0.7261E-48 0.7261E-48 SO2,gas 0.4075E-27 1.0000 0.4298E-27 0.4298E-27 HCl,gas 0.2713E-17 1.0000 0.2861E-17 0.2861E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 16 albite -0.38 -0.38 0.00 0.000 -0.94784E-12 22 andradite 39.01 39.01 0.00 0.000 0.00000E+00 23 grossular 32.73 32.73 0.00 0.000 0.24265E-10 32 apatite-OH -18.15 -18.15 0.00 0.000 0.00000E+00 46 clinochlore 39.07 39.07 0.00 0.000 0.00000E+00 47 daphnite 28.97 28.97 0.00 0.000 -0.24265E-10 48 chlorite-Mn 46.87 46.87 0.00 0.000 0.00000E+00 67 diopside 16.18 16.18 0.00 0.000 0.00000E+00 68 hedenbergite 14.21 14.21 0.00 0.000 -0.30331E-11 116 microcline -2.49 -2.49 0.00 0.000 0.15165E-11 163 stilbite -7.52 -7.52 0.00 0.000 0.15165E-10 164 stilpnomelane-Fe 13.02 13.02 0.00 0.000 0.21232E-10 245 tr.625ac.25prg.125 45.16 45.16 0.00 0.000 -0.24265E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -16.81 -10.15 -3.384 0.17333E+05 -8.452 3 CH4,gas 4.54 1.12 -3.42 -0.856 0.58445E+04 -1.724 4 H2,gas 8.00 4.48 -3.52 -2.010 0.60046E+04 -1.818 5 H2S,gas -6.23 -14.78 -8.55 -4.277 0.14606E+05 -6.855 6 S2,gas -7.34 -38.53 -31.20 -4.800 0.53272E+05 -29.500 7 CO,gas 3.21 -12.33 -15.54 -4.783 0.26540E+05 -13.844 8 SO3,gas 17.12 -32.72 -49.84 -12.460 0.85097E+05 -48.139 9 SO2,gas 0.83 -28.23 -29.07 -7.751 0.49629E+05 -27.367 10 HCl,gas 5.19 -14.05 -19.24 -9.621 0.32856E+05 -17.543 11 acmite 7.71 6.53 -1.18 -0.123 0.20181E+04 15 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 19 spessartine 24.46 19.70 -4.76 -0.238 0.81193E+04 20 analcite 3.32 2.77 -0.55 -0.061 0.93606E+03 26 annite 20.12 17.72 -2.40 -0.134 0.41062E+04 27 phlogopite 27.06 25.40 -1.67 -0.093 0.28483E+04 29 anorthite 12.71 8.27 -4.44 -0.342 0.75893E+04 35 aragonite 0.97 -3.71 -4.68 -1.559 0.79843E+04 36 brucite 12.57 9.29 -3.27 -0.655 0.55907E+04 37 calcite 0.81 -3.71 -4.52 -1.507 0.77201E+04 38 carnegieite-low 9.02 5.93 -3.09 -0.442 0.52797E+04 39 carnegieite-high 10.09 5.93 -4.16 -0.595 0.71067E+04 40 carpholite-Mg 8.58 4.46 -4.12 -0.275 0.70419E+04 41 carpholite-Fe 6.71 1.90 -4.81 -0.321 0.82198E+04 42 celadonite 5.34 3.65 -1.69 -0.099 0.28878E+04 43 celadonite-Fe 3.88 1.09 -2.79 -0.164 0.47562E+04 44 chrysotile 23.89 21.57 -2.32 -0.194 0.39690E+04 49 chlorite-Al-free 47.17 43.14 -4.04 -0.168 0.68931E+04 51 chloritoid-Fe 9.17 5.06 -4.12 -0.274 0.70305E+04 52 chloritoid-Mn 11.40 7.55 -3.85 -0.257 0.65702E+04 54 coesite -2.38 -3.16 -0.78 -0.260 0.13343E+04 61 cristobalite -2.56 -3.16 -0.60 -0.199 0.10197E+04 63 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71234E+04 65 diaspore 2.87 0.74 -2.13 -0.356 0.36444E+04 66 diamond -3.10 -7.85 -4.74 -1.355 0.80985E+04 71 enstatite 17.26 12.27 -4.99 -0.499 0.85225E+04 73 clinoenstatite 17.17 12.27 -4.89 -0.489 0.83541E+04 75 epidote 24.67 22.70 -1.97 -0.095 0.33577E+04 76 clinozoisite 22.81 18.95 -3.86 -0.175 0.65853E+04 77 epidote-Fe 29.84 26.46 -3.38 -0.176 0.57767E+04 78 fayalite 14.05 10.31 -3.73 -0.533 0.63743E+04 79 ferrosilite 11.15 7.16 -3.99 -0.399 0.68204E+04 83 gibbsite 4.08 0.74 -3.34 -0.477 0.57030E+04 84 glaucophane 22.97 20.80 -2.17 -0.059 0.37131E+04 85 glaucophane-Fe 17.28 13.12 -4.15 -0.112 0.70920E+04 86 graphite -3.55 -7.85 -4.30 -1.228 0.73407E+04 87 greenalite 16.14 13.89 -2.25 -0.187 0.38409E+04 90 hematite 12.57 8.99 -3.58 -0.434 0.61114E+04 91 heulandite -5.83 -7.52 -1.69 -0.077 0.28938E+04 95 jadeite 4.22 2.77 -1.44 -0.144 0.24615E+04 97 kalsilite 7.58 3.83 -3.76 -0.536 0.64122E+04 98 kaolinite -1.33 -4.84 -3.50 -0.319 0.59824E+04 101 laumontite 2.88 1.95 -0.93 -0.062 0.15929E+04 102 lawsonite 9.62 8.27 -1.35 -0.090 0.23060E+04 103 leucite 4.12 0.67 -3.45 -0.345 0.58871E+04 105 lizardite 23.24 21.57 -1.68 -0.140 0.28616E+04 107 magnetite 20.09 15.72 -4.37 -0.356 0.74538E+04 108 minnesotaite 10.39 7.57 -2.81 -0.165 0.48033E+04 112 manganosite 14.06 9.23 -4.83 -1.207 0.82404E+04 120 muscovite 2.58 -1.01 -3.59 -0.211 0.61303E+04 121 paragonite 4.24 1.09 -3.14 -0.185 0.53694E+04 122 nepheline 8.34 5.93 -2.41 -0.344 0.41121E+04 128 periclase-Fe 11.63 6.74 -4.89 -1.223 0.83522E+04 134 phlogopite-Na 29.65 27.50 -2.15 -0.119 0.36671E+04 136 prehnite 19.37 18.21 -1.16 -0.068 0.19839E+04 137 prehnite-Fe 22.50 21.96 -0.53 -0.032 0.91134E+03 138 pumpellyite-Fe 46.27 43.89 -2.38 -0.053 0.40555E+04 139 pumpellyite-Mg 48.99 46.45 -2.54 -0.056 0.43392E+04 143 pyrrhotite -4.26 -8.05 -3.79 -1.263 0.64695E+04 144 pyrrhotiteFe0.875 -6.02 -9.45 -3.43 -1.262 0.58568E+04 145 pyroxmangite 7.40 6.07 -1.32 -0.265 0.22610E+04 146 pyrophyllite -6.18 -11.15 -4.98 -0.311 0.84958E+04 147 quartz -2.99 -3.16 -0.17 -0.056 0.28700E+03 152 rhodonite 7.45 6.07 -1.37 -0.274 0.23412E+04 153 sanidine -1.28 -2.49 -1.21 -0.093 0.20677E+04 165 stilpnomelane-Mg 27.44 25.81 -1.63 -0.049 0.27797E+04 171 talc 16.49 15.25 -1.24 -0.073 0.21141E+04 174 tephroite 18.09 15.31 -2.78 -0.397 0.47454E+04 178 tridymite -2.63 -3.16 -0.53 -0.177 0.90697E+03 179 tremolite 47.87 47.42 -0.45 -0.012 0.77501E+03 180 ferroactinolite 38.45 34.62 -3.83 -0.104 0.65456E+04 181 troilite-low -4.41 -8.05 -3.64 -1.213 0.62123E+04 183 vesuvianite 223.47 218.82 -4.65 -0.035 0.79368E+04 187 wairakite 3.95 1.95 -2.00 -0.118 0.34149E+04 188 walstromite 11.51 9.94 -1.56 -0.313 0.26719E+04 189 wollastonite 10.46 9.94 -0.52 -0.103 0.88228E+03 190 pseudo-wollastonite 11.00 9.94 -1.06 -0.211 0.18021E+04 191 zoisite 22.85 18.95 -3.90 -0.177 0.66594E+04 192 akaganeite 7.75 4.49 -3.26 -0.705 0.55682E+04 199 chalcedony -2.80 -3.16 -0.36 -0.118 0.60629E+03 201 montmorillonite-Ca -2.29 -6.17 -3.88 -0.240 0.66177E+04 202 montmorillonite-K -2.24 -6.27 -4.03 -0.247 0.68814E+04 203 montmorillonite-Mg -2.48 -6.79 -4.31 -0.267 0.73675E+04 204 montmorillonite-Na -2.04 -5.57 -3.54 -0.216 0.60363E+04 205 nontronite-Ca 3.21 -0.20 -3.41 -0.221 0.58223E+04 206 nontronite-H 2.53 -2.36 -4.89 -0.328 0.83493E+04 207 nontronite-K 3.34 -0.30 -3.64 -0.233 0.62091E+04 208 nontronite-Mg 3.07 -0.82 -3.90 -0.253 0.66561E+04 209 nontronite-Na 3.52 0.40 -3.12 -0.200 0.53300E+04 224 tobermorite 9.82 7.76 -2.07 -0.564 0.35287E+04 230 alabandite -0.98 -5.55 -4.57 -1.525 0.78106E+04 233 boehmite 4.41 0.74 -3.67 -0.611 0.62613E+04 235 ferrous-oxide 9.81 6.74 -3.08 -0.769 0.52531E+04 240 silica-amorphous -2.09 -3.16 -1.07 -0.355 0.18205E+04 242 an20ab80 2.02 1.35 -0.67 -0.052 0.11470E+04 243 an25ab75 2.65 1.78 -0.87 -0.067 0.14807E+04 244 an30ab70 3.28 2.21 -1.07 -0.082 0.18241E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 10.0000000 g Current total amount of reactant added: 369.9990000 g New total amount of reactant added: 379.9990000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.3647E-11 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 11 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 379.9990000 Water: Moles liquid = 0.5330E+02 kg liquid = 0.9603E+00 Moles total = 0.5074E+02 kg total = 0.9142E+00 Activity = 1.0000 Stoichiometric ionic strength = .1132151E-01 Osmotic coef. = 0.9695 True ionic strength = .2001054E-01 Chg. balance for total moles = 0.3647E-11 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.88259E-10 -10.0542 0.74161E-10 -10.1298 0.84027E+00 -0.0756 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.14302E-03 -3.8446 0.11945E-03 -3.9228 0.83522E+00 -0.0782 4 SO4-- 0.67301E-12 -12.1720 0.34953E-12 -12.4565 0.51936E+00 -0.2845 5 HCO3- 0.24908E-06 -6.6037 0.20834E-06 -6.6812 0.83644E+00 -0.0776 6 HS- 0.26554E-04 -4.5759 0.22181E-04 -4.6540 0.83534E+00 -0.0781 7 Al+++ 0.96841E-29 -29.0139 0.22379E-29 -29.6502 0.23109E+00 -0.6362 8 H4SiO4 0.69580E-03 -3.1575 0.69580E-03 -3.1575 0.10000E+01 0.0000 9 Ca++ 0.13490E-06 -6.8700 0.69550E-07 -7.1577 0.51555E+00 -0.2877 10 Mg++ 0.21105E-10 -10.6756 0.10831E-10 -10.9653 0.51319E+00 -0.2897 11 Fe++ 0.58160E-13 -13.2354 0.29880E-13 -13.5246 0.51375E+00 -0.2892 12 K+ 0.15645E-03 -3.8056 0.13089E-03 -3.8831 0.83664E+00 -0.0775 13 Na+ 0.19853E-01 -1.7022 0.16579E-01 -1.7805 0.83507E+00 -0.0783 14 Mn++ 0.18262E-10 -10.7384 0.93900E-11 -11.0273 0.51418E+00 -0.2889 15 HPO4-- 0.45330E-07 -7.3436 0.23546E-07 -7.6281 0.51943E+00 -0.2845 16 HSiO3- 0.10489E-01 -1.9793 0.87606E-02 -2.0575 0.83522E+00 -0.0782 17 Ca(HSiO3)+ 0.16582E-07 -7.7804 0.13876E-07 -7.8577 0.83682E+00 -0.0774 18 Mg(HSiO3)+ 0.32137E-11 -11.4930 0.26893E-11 -11.5704 0.83682E+00 -0.0774 19 NaHSiO3,aq 0.23491E-02 -2.6291 0.23491E-02 -2.6291 0.10000E+01 0.0000 20 AlO+ 0.66149E-16 -16.1795 0.55355E-16 -16.2568 0.83682E+00 -0.0774 22 HAlO2,aq 0.14865E-09 -9.8278 0.14865E-09 -9.8278 0.10000E+01 0.0000 23 AlO2- 0.53218E-05 -5.2739 0.44368E-05 -5.3529 0.83371E+00 -0.0790 24 CH4,aq 0.12887E-04 -4.8898 0.12843E-04 -4.8913 0.99655E+00 -0.0015 25 C2H6,aq 0.24415E-14 -14.6123 0.24330E-14 -14.6138 0.99655E+00 -0.0015 29 CO,aq 0.96119E-17 -17.0172 0.96119E-17 -17.0172 0.10000E+01 0.0000 30 CO2,aq 0.33129E-10 -10.4798 0.33015E-10 -10.4813 0.99655E+00 -0.0015 31 CO3-2 0.47348E-06 -6.3247 0.24538E-06 -6.6102 0.51826E+00 -0.2855 32 CaCO3,aq 0.21399E-09 -9.6696 0.21399E-09 -9.6696 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.44200E-12 -12.3546 0.36988E-12 -12.4319 0.83682E+00 -0.0774 34 CaCl+ 0.16067E-10 -10.7941 0.13445E-10 -10.8714 0.83682E+00 -0.0774 35 CaCl2,aq 0.38156E-15 -15.4184 0.38156E-15 -15.4184 0.10000E+01 0.0000 36 CaOH+ 0.79871E-07 -7.0976 0.66838E-07 -7.1750 0.83682E+00 -0.0774 37 CaSO4,aq 0.77196E-17 -17.1124 0.77196E-17 -17.1124 0.10000E+01 0.0000 38 HCl,aq 0.16233E-14 -14.7896 0.16233E-14 -14.7896 0.10000E+01 0.0000 43 FeCl+ 0.67512E-17 -17.1706 0.56495E-17 -17.2480 0.83682E+00 -0.0774 46 FeO,aq 0.21115E-09 -9.6754 0.21115E-09 -9.6754 0.10000E+01 0.0000 47 FeOH+ 0.15672E-10 -10.8049 0.13115E-10 -10.8822 0.83682E+00 -0.0774 48 HFeO2- 0.35667E-07 -7.4477 0.29790E-07 -7.5259 0.83522E+00 -0.0782 49 FeO+ 0.10981E-16 -16.9594 0.91887E-17 -17.0367 0.83682E+00 -0.0774 51 FeO2- 0.40931E-09 -9.3880 0.34186E-09 -9.4661 0.83522E+00 -0.0782 52 HFeO2,aq 0.32245E-11 -11.4915 0.32245E-11 -11.4915 0.10000E+01 0.0000 53 H2,aq 0.11630E-04 -4.9344 0.11589E-04 -4.9359 0.99655E+00 -0.0015 54 KCl,aq 0.28339E-09 -9.5476 0.28339E-09 -9.5476 0.10000E+01 0.0000 56 KOH,aq 0.75375E-06 -6.1228 0.75375E-06 -6.1228 0.10000E+01 0.0000 57 KSO4- 0.85003E-15 -15.0706 0.70996E-15 -15.1488 0.83522E+00 -0.0782 58 MgCO3,aq 0.83532E-14 -14.0781 0.83532E-14 -14.0781 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.70335E-16 -16.1528 0.58858E-16 -16.2302 0.83682E+00 -0.0774 60 MgCl+ 0.22678E-14 -14.6444 0.18977E-14 -14.7218 0.83682E+00 -0.0774 61 MgOH+ 0.68828E-10 -10.1622 0.57597E-10 -10.2396 0.83682E+00 -0.0774 63 MnO,aq 0.17681E-08 -8.7525 0.17681E-08 -8.7525 0.10000E+01 0.0000 64 MnOH+ 0.45753E-09 -9.3396 0.38287E-09 -9.4169 0.83682E+00 -0.0774 65 MnO2-2 0.20586E-10 -10.6864 0.10669E-10 -10.9719 0.51826E+00 -0.2855 66 HMnO2- 0.20754E-09 -9.6829 0.17334E-09 -9.7611 0.83522E+00 -0.0782 69 MnCl+ 0.82541E-14 -14.0833 0.69072E-14 -14.1607 0.83682E+00 -0.0774 71 NaCl,aq 0.65631E-06 -6.1829 0.65631E-06 -6.1829 0.10000E+01 0.0000 72 NaOH,aq 0.96047E-04 -4.0175 0.96047E-04 -4.0175 0.10000E+01 0.0000 74 OH- 0.93447E-02 -2.0294 0.77908E-02 -2.1084 0.83371E+00 -0.0790 79 HPO3-2 0.16409E-14 -14.7849 0.85039E-15 -15.0704 0.51826E+00 -0.2855 81 H2PO3- 0.15142E-18 -18.8198 0.12647E-18 -18.8980 0.83522E+00 -0.0782 82 H3PO4,aq 0.90571E-18 -18.0430 0.90571E-18 -18.0430 0.10000E+01 0.0000 83 H2PO4- 0.38531E-10 -10.4142 0.32212E-10 -10.4920 0.83601E+00 -0.0778 84 PO4-3 0.10673E-08 -8.9717 0.25904E-09 -9.5866 0.24270E+00 -0.6149 88 HP2O7-3 0.94702E-18 -18.0236 0.21906E-18 -18.6594 0.23132E+00 -0.6358 89 P2O7-4 0.91480E-17 -17.0387 0.70566E-18 -18.1514 0.77139E-01 -1.1127 90 H2S,aq 0.51017E-08 -8.2923 0.50841E-08 -8.2938 0.99655E+00 -0.0015 91 S2-2 0.18151E-14 -14.7411 0.94069E-15 -15.0266 0.51826E+00 -0.2855 97 SO3-2 0.10013E-17 -17.9995 0.52641E-18 -18.2787 0.52575E+00 -0.2792 99 HSO4- 0.29824E-19 -19.5254 0.24981E-19 -19.6024 0.83763E+00 -0.0769 Charge balance for all species = 0.3800E-11 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.8825875E-10 -.2230439E-01 -.2244243E+02 0.0000 2 H2O 0.1000000E+01 0.5550489E+02 0.9982000E+06 0.0000 3 Cl- 0.1430209E-03 0.1436775E-03 0.5084948E+01 6.2070 4 SO4-- 0.6730097E-12 -.1579481E-04 -.1514639E+01 7.8031 5 HCO3- 0.2490817E-06 0.1361026E-04 0.8290173E+00 3.4486 6 HS- 0.2655362E-04 0.4235353E-04 0.1398283E+01 5.4758 7 Al+++ 0.9684109E-29 0.5321908E-05 0.1433436E+00 0.7393 8 H4SiO4 0.6958024E-03 0.1353387E-01 0.1298553E+04 -3.1575 9 Ca++ 0.1349046E-06 0.2315884E-06 0.9265475E-02 13.1019 10 Mg++ 0.2110536E-10 0.9315791E-10 0.2260920E-05 9.2943 11 Fe++ 0.5815950E-13 0.3630652E-07 0.2024088E-02 6.7350 12 K+ 0.1564529E-03 0.1572069E-03 0.6136424E+01 6.2467 13 Na+ 0.1985306E-01 0.2229882E-01 0.5117547E+03 8.3494 14 Mn++ 0.1826216E-10 0.2472021E-08 0.1355720E-03 9.2323 15 HPO4-- 0.4532962E-07 0.4643547E-07 0.4449087E-02 12.6316 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.6292206E+01 -.2141901E-01 -.6270787E+01 0.0000000E+00 2 H2O 0.5074481E+02 0.5330161E+02 -.2556808E+01 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.1055657E-01 -.1516783E-04 0.1057174E-01 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.1053107E-01 0.4067230E-04 -.1057174E-01 0.0000000E+00 7 Al+++ 0.1239079E+01 0.5110654E-05 0.1239073E+01 0.0000000E+00 8 H4SiO4 0.3956847E+01 0.1299664E-01 0.3943850E+01 0.0000000E+00 9 Ca++ 0.4370675E+00 0.2223955E-06 0.4370673E+00 0.0000000E+00 10 Mg++ 0.3015865E+00 0.8945999E-10 0.3015865E+00 0.0000000E+00 11 Fe++ 0.2709426E+00 0.3486532E-07 0.2709425E+00 0.0000000E+00 12 K+ 0.8067919E-01 0.1509665E-03 0.8052823E-01 0.0000000E+00 13 Na+ 0.4771514E+00 0.2141366E-01 0.4557377E+00 0.0000000E+00 14 Mn++ 0.6588649E-02 0.2373894E-08 0.6588647E-02 0.0000000E+00 15 HPO4-- 0.2248673E-02 0.4459220E-07 0.2248629E-02 0.0000000E+00 Chg. balance for solid moles: 0.1507E-14 Mass of aqueous solution: 0.961976E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 379.9990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 0.4552 -0.342 119.4 2.077 28.77 45.82 andradite 0.4229E-01 -1.374 21.49 1.332 5.179 5.583 grossular 0.1025E-01 -1.989 4.617 0.664 1.113 1.285 apatite-OH 0.7495E-03 -3.125 0.3765 -0.424 0.9073E-01 0.1196 clinochlore 0.5516E-01 -1.258 30.66 1.487 7.389 11.66 daphnite 0.1597E-01 -1.797 11.39 1.057 2.745 3.452 chlorite-Mn 0.1318E-02 -2.880 0.9342 -0.030 0.2251 0.2977 diopside 0.1141E-01 -1.943 2.471 0.393 0.5954 0.7551 hedenbergite 0.2958E-02 -2.529 0.7339 -0.134 0.1769 0.2010 microcline 0.7067E-01 -1.151 19.67 1.294 4.740 7.683 stilbite 0.2534 -0.596 178.6 2.252 43.04 83.30 stilpnomelane-Fe 0.1973E-01 -1.705 21.26 1.328 5.124 7.345 tr.625ac.25prg.125 0.3963E-02 -2.402 3.387 0.530 0.8163 1.090 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8049E+00 0.8049E+00 1.0000 -0.094 grossular 0.1951E+00 0.1951E+00 1.0000 -0.710 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.7614E+00 0.7614E+00 1.0000 -0.118 daphnite 0.2204E+00 0.2204E+00 1.0000 -0.657 chlorite-Mn 0.1819E-01 0.1819E-01 1.0000 -1.740 diopside 0.7941E+00 0.7941E+00 1.0000 -0.100 hedenbergite 0.2059E+00 0.2059E+00 1.0000 -0.686 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 tr.625ac.25prg.125 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 414.957266 g Volume = 168.596297 cm3 Porosity: -10.1939% V(tot) - V(min): -.15597E+02 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 379.9990000 g log = 2.5798 Original solution: 1000.0103000 g Original solution / Rock added: 2.63 (Water/Rock Ratio), log = 0.4202 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0547 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9679E+00 0.9855 0.1006E+01 0.1021E+01 CO2,gas 0.3326E-08 1.0069 0.3532E-08 0.3508E-08 CH4,gas 0.1770E-01 1.0125 0.1890E-01 0.1867E-01 H2,gas 0.1442E-01 1.0006 0.1522E-01 0.1521E-01 H2S,gas 0.1331E-06 0.9959 0.1398E-06 0.1403E-06 S2,gas 0.3003E-29 1.0000 0.3167E-29 0.3167E-29 CO,gas 0.1358E-13 1.0000 0.1432E-13 0.1432E-13 SO3,gas 0.6892E-48 1.0000 0.7269E-48 0.7269E-48 SO2,gas 0.4080E-27 1.0000 0.4303E-27 0.4303E-27 HCl,gas 0.2716E-17 1.0000 0.2864E-17 0.2864E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 16 albite -0.38 -0.38 0.00 0.000 -0.94784E-12 22 andradite 39.01 39.01 0.00 0.000 -0.24265E-10 23 grossular 32.73 32.73 0.00 0.000 0.00000E+00 32 apatite-OH -18.15 -18.15 0.00 0.000 0.60662E-11 46 clinochlore 39.07 39.07 0.00 0.000 0.48529E-10 47 daphnite 28.97 28.97 0.00 0.000 0.60662E-10 48 chlorite-Mn 46.87 46.87 0.00 0.000 0.00000E+00 67 diopside 16.18 16.18 0.00 0.000 0.00000E+00 68 hedenbergite 14.21 14.21 0.00 0.000 0.00000E+00 116 microcline -2.49 -2.49 0.00 0.000 0.15165E-11 163 stilbite -7.52 -7.52 0.00 0.000 0.15165E-10 164 stilpnomelane-Fe 13.02 13.02 0.00 0.000 0.21232E-10 245 tr.625ac.25prg.125 45.16 45.16 0.00 0.000 -0.36397E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -16.81 -10.15 -3.384 0.17332E+05 -8.452 3 CH4,gas 4.54 1.12 -3.42 -0.856 0.58437E+04 -1.723 4 H2,gas 8.00 4.48 -3.52 -2.010 0.60046E+04 -1.818 5 H2S,gas -6.23 -14.78 -8.55 -4.277 0.14605E+05 -6.855 6 S2,gas -7.34 -38.53 -31.20 -4.800 0.53270E+05 -29.499 7 CO,gas 3.21 -12.33 -15.54 -4.782 0.26539E+05 -13.844 8 SO3,gas 17.12 -32.72 -49.84 -12.459 0.85096E+05 -48.139 9 SO2,gas 0.83 -28.23 -29.07 -7.751 0.49628E+05 -27.366 10 HCl,gas 5.19 -14.05 -19.24 -9.621 0.32855E+05 -17.543 11 acmite 7.71 6.53 -1.18 -0.123 0.20180E+04 15 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 19 spessartine 24.46 19.70 -4.75 -0.238 0.81179E+04 20 analcite 3.32 2.77 -0.55 -0.061 0.93606E+03 26 annite 20.12 17.72 -2.40 -0.134 0.41062E+04 27 phlogopite 27.06 25.40 -1.67 -0.093 0.28483E+04 29 anorthite 12.71 8.27 -4.44 -0.342 0.75894E+04 35 aragonite 0.97 -3.71 -4.68 -1.559 0.79835E+04 36 brucite 12.57 9.29 -3.27 -0.655 0.55907E+04 37 calcite 0.81 -3.71 -4.52 -1.507 0.77193E+04 38 carnegieite-low 9.02 5.93 -3.09 -0.442 0.52797E+04 39 carnegieite-high 10.09 5.93 -4.16 -0.595 0.71067E+04 40 carpholite-Mg 8.58 4.46 -4.12 -0.275 0.70420E+04 41 carpholite-Fe 6.71 1.90 -4.81 -0.321 0.82198E+04 42 celadonite 5.34 3.65 -1.69 -0.099 0.28878E+04 43 celadonite-Fe 3.88 1.09 -2.79 -0.164 0.47562E+04 44 chrysotile 23.89 21.57 -2.32 -0.194 0.39690E+04 49 chlorite-Al-free 47.17 43.14 -4.04 -0.168 0.68931E+04 51 chloritoid-Fe 9.17 5.06 -4.12 -0.275 0.70305E+04 52 chloritoid-Mn 11.40 7.55 -3.85 -0.257 0.65698E+04 54 coesite -2.38 -3.16 -0.78 -0.260 0.13343E+04 61 cristobalite -2.56 -3.16 -0.60 -0.199 0.10197E+04 63 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71234E+04 65 diaspore 2.87 0.74 -2.13 -0.356 0.36444E+04 66 diamond -3.10 -7.84 -4.74 -1.355 0.80977E+04 71 enstatite 17.26 12.27 -4.99 -0.499 0.85225E+04 73 clinoenstatite 17.17 12.27 -4.89 -0.489 0.83541E+04 75 epidote 24.67 22.70 -1.97 -0.095 0.33577E+04 76 clinozoisite 22.81 18.95 -3.86 -0.175 0.65854E+04 77 epidote-Fe 29.84 26.46 -3.38 -0.176 0.57767E+04 78 fayalite 14.05 10.31 -3.73 -0.533 0.63743E+04 79 ferrosilite 11.15 7.16 -3.99 -0.399 0.68204E+04 83 gibbsite 4.08 0.74 -3.34 -0.477 0.57030E+04 84 glaucophane 22.97 20.80 -2.17 -0.059 0.37131E+04 85 glaucophane-Fe 17.28 13.12 -4.15 -0.112 0.70920E+04 86 graphite -3.55 -7.84 -4.30 -1.228 0.73399E+04 87 greenalite 16.14 13.89 -2.25 -0.187 0.38409E+04 90 hematite 12.57 8.99 -3.58 -0.434 0.61114E+04 91 heulandite -5.83 -7.52 -1.69 -0.077 0.28938E+04 95 jadeite 4.22 2.77 -1.44 -0.144 0.24615E+04 97 kalsilite 7.58 3.83 -3.76 -0.536 0.64122E+04 98 kaolinite -1.33 -4.84 -3.50 -0.319 0.59824E+04 101 laumontite 2.88 1.95 -0.93 -0.062 0.15929E+04 102 lawsonite 9.62 8.27 -1.35 -0.090 0.23060E+04 103 leucite 4.12 0.67 -3.45 -0.345 0.58871E+04 105 lizardite 23.24 21.57 -1.68 -0.140 0.28616E+04 107 magnetite 20.09 15.72 -4.37 -0.356 0.74538E+04 108 minnesotaite 10.39 7.58 -2.81 -0.165 0.48033E+04 112 manganosite 14.06 9.23 -4.83 -1.206 0.82399E+04 120 muscovite 2.58 -1.01 -3.59 -0.211 0.61304E+04 121 paragonite 4.24 1.09 -3.14 -0.185 0.53695E+04 122 nepheline 8.34 5.93 -2.41 -0.344 0.41121E+04 128 periclase-Fe 11.63 6.74 -4.89 -1.223 0.83522E+04 134 phlogopite-Na 29.65 27.50 -2.15 -0.119 0.36671E+04 136 prehnite 19.37 18.21 -1.16 -0.068 0.19840E+04 137 prehnite-Fe 22.50 21.96 -0.53 -0.032 0.91134E+03 138 pumpellyite-Fe 46.27 43.89 -2.38 -0.053 0.40556E+04 139 pumpellyite-Mg 48.99 46.45 -2.54 -0.056 0.43393E+04 143 pyrrhotite -4.26 -8.05 -3.79 -1.263 0.64687E+04 144 pyrrhotiteFe0.875 -6.02 -9.45 -3.43 -1.261 0.58560E+04 145 pyroxmangite 7.40 6.07 -1.32 -0.265 0.22605E+04 146 pyrophyllite -6.18 -11.15 -4.98 -0.311 0.84958E+04 147 quartz -2.99 -3.16 -0.17 -0.056 0.28699E+03 152 rhodonite 7.45 6.07 -1.37 -0.274 0.23407E+04 153 sanidine -1.28 -2.49 -1.21 -0.093 0.20677E+04 165 stilpnomelane-Mg 27.44 25.81 -1.63 -0.049 0.27797E+04 171 talc 16.49 15.25 -1.24 -0.073 0.21141E+04 174 tephroite 18.09 15.31 -2.78 -0.397 0.47445E+04 178 tridymite -2.63 -3.16 -0.53 -0.177 0.90697E+03 179 tremolite 47.87 47.42 -0.45 -0.012 0.77501E+03 180 ferroactinolite 38.45 34.62 -3.83 -0.104 0.65456E+04 181 troilite-low -4.41 -8.05 -3.64 -1.213 0.62116E+04 183 vesuvianite 223.47 218.82 -4.65 -0.035 0.79369E+04 187 wairakite 3.95 1.95 -2.00 -0.118 0.34149E+04 188 walstromite 11.51 9.94 -1.56 -0.313 0.26719E+04 189 wollastonite 10.46 9.94 -0.52 -0.103 0.88228E+03 190 pseudo-wollastonite 11.00 9.94 -1.06 -0.211 0.18021E+04 191 zoisite 22.85 18.95 -3.90 -0.177 0.66594E+04 192 akaganeite 7.75 4.49 -3.26 -0.705 0.55682E+04 199 chalcedony -2.80 -3.16 -0.36 -0.118 0.60629E+03 201 montmorillonite-Ca -2.29 -6.17 -3.88 -0.240 0.66178E+04 202 montmorillonite-K -2.24 -6.27 -4.03 -0.247 0.68814E+04 203 montmorillonite-Mg -2.48 -6.79 -4.31 -0.267 0.73675E+04 204 montmorillonite-Na -2.04 -5.57 -3.54 -0.216 0.60363E+04 205 nontronite-Ca 3.21 -0.20 -3.41 -0.221 0.58222E+04 206 nontronite-H 2.53 -2.36 -4.89 -0.328 0.83493E+04 207 nontronite-K 3.34 -0.30 -3.64 -0.233 0.62091E+04 208 nontronite-Mg 3.07 -0.82 -3.90 -0.253 0.66561E+04 209 nontronite-Na 3.52 0.40 -3.12 -0.200 0.53300E+04 224 tobermorite 9.82 7.76 -2.07 -0.564 0.35287E+04 230 alabandite -0.98 -5.55 -4.57 -1.525 0.78094E+04 233 boehmite 4.41 0.74 -3.67 -0.611 0.62613E+04 235 ferrous-oxide 9.81 6.74 -3.08 -0.769 0.52531E+04 240 silica-amorphous -2.09 -3.16 -1.07 -0.355 0.18205E+04 242 an20ab80 2.02 1.35 -0.67 -0.052 0.11470E+04 243 an25ab75 2.65 1.78 -0.87 -0.067 0.14808E+04 244 an30ab70 3.28 2.21 -1.07 -0.082 0.18241E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 10.0000000 g Current total amount of reactant added: 379.9990000 g New total amount of reactant added: 389.9990000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.3648E-11 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 11 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 389.9990000 Water: Moles liquid = 0.5325E+02 kg liquid = 0.9593E+00 Moles total = 0.5062E+02 kg total = 0.9119E+00 Activity = 1.0000 Stoichiometric ionic strength = .1132166E-01 Osmotic coef. = 0.9695 True ionic strength = .2001067E-01 Chg. balance for total moles = 0.3648E-11 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.88259E-10 -10.0542 0.74162E-10 -10.1298 0.84027E+00 -0.0756 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.14317E-03 -3.8441 0.11958E-03 -3.9223 0.83522E+00 -0.0782 4 SO4-- 0.67375E-12 -12.1715 0.34992E-12 -12.4560 0.51936E+00 -0.2845 5 HCO3- 0.24936E-06 -6.6032 0.20857E-06 -6.6807 0.83644E+00 -0.0776 6 HS- 0.26581E-04 -4.5754 0.22205E-04 -4.6536 0.83534E+00 -0.0781 7 Al+++ 0.96841E-29 -29.0139 0.22379E-29 -29.6502 0.23108E+00 -0.6362 8 H4SiO4 0.69581E-03 -3.1575 0.69581E-03 -3.1575 0.10000E+01 0.0000 9 Ca++ 0.13491E-06 -6.8700 0.69550E-07 -7.1577 0.51555E+00 -0.2877 10 Mg++ 0.21106E-10 -10.6756 0.10831E-10 -10.9653 0.51319E+00 -0.2897 11 Fe++ 0.58160E-13 -13.2354 0.29880E-13 -13.5246 0.51375E+00 -0.2892 12 K+ 0.15645E-03 -3.8056 0.13090E-03 -3.8831 0.83664E+00 -0.0775 13 Na+ 0.19853E-01 -1.7022 0.16579E-01 -1.7804 0.83507E+00 -0.0783 14 Mn++ 0.18273E-10 -10.7382 0.93956E-11 -11.0271 0.51418E+00 -0.2889 15 HPO4-- 0.45330E-07 -7.3436 0.23546E-07 -7.6281 0.51943E+00 -0.2845 16 HSiO3- 0.10489E-01 -1.9793 0.87606E-02 -2.0575 0.83522E+00 -0.0782 17 Ca(HSiO3)+ 0.16582E-07 -7.7804 0.13876E-07 -7.8577 0.83682E+00 -0.0774 18 Mg(HSiO3)+ 0.32138E-11 -11.4930 0.26893E-11 -11.5704 0.83682E+00 -0.0774 19 NaHSiO3,aq 0.23491E-02 -2.6291 0.23491E-02 -2.6291 0.10000E+01 0.0000 20 AlO+ 0.66148E-16 -16.1795 0.55354E-16 -16.2569 0.83682E+00 -0.0774 22 HAlO2,aq 0.14864E-09 -9.8279 0.14864E-09 -9.8279 0.10000E+01 0.0000 23 AlO2- 0.53216E-05 -5.2740 0.44367E-05 -5.3529 0.83371E+00 -0.0790 24 CH4,aq 0.12901E-04 -4.8894 0.12856E-04 -4.8909 0.99655E+00 -0.0015 25 C2H6,aq 0.24466E-14 -14.6114 0.24382E-14 -14.6129 0.99655E+00 -0.0015 29 CO,aq 0.96224E-17 -17.0167 0.96224E-17 -17.0167 0.10000E+01 0.0000 30 CO2,aq 0.33166E-10 -10.4793 0.33052E-10 -10.4808 0.99655E+00 -0.0015 31 CO3-2 0.47400E-06 -6.3242 0.24565E-06 -6.6097 0.51826E+00 -0.2855 32 CaCO3,aq 0.21423E-09 -9.6691 0.21423E-09 -9.6691 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.44249E-12 -12.3541 0.37029E-12 -12.4315 0.83682E+00 -0.0774 34 CaCl+ 0.16084E-10 -10.7936 0.13459E-10 -10.8710 0.83682E+00 -0.0774 35 CaCl2,aq 0.38237E-15 -15.4175 0.38237E-15 -15.4175 0.10000E+01 0.0000 36 CaOH+ 0.79871E-07 -7.0976 0.66838E-07 -7.1750 0.83682E+00 -0.0774 37 CaSO4,aq 0.77282E-17 -17.1119 0.77282E-17 -17.1119 0.10000E+01 0.0000 38 HCl,aq 0.16251E-14 -14.7891 0.16251E-14 -14.7891 0.10000E+01 0.0000 43 FeCl+ 0.67583E-17 -17.1702 0.56555E-17 -17.2475 0.83682E+00 -0.0774 46 FeO,aq 0.21115E-09 -9.6754 0.21115E-09 -9.6754 0.10000E+01 0.0000 47 FeOH+ 0.15672E-10 -10.8049 0.13115E-10 -10.8822 0.83682E+00 -0.0774 48 HFeO2- 0.35667E-07 -7.4477 0.29790E-07 -7.5259 0.83522E+00 -0.0782 49 FeO+ 0.10981E-16 -16.9594 0.91889E-17 -17.0367 0.83682E+00 -0.0774 51 FeO2- 0.40931E-09 -9.3880 0.34186E-09 -9.4661 0.83522E+00 -0.0782 52 HFeO2,aq 0.32245E-11 -11.4915 0.32245E-11 -11.4915 0.10000E+01 0.0000 53 H2,aq 0.11629E-04 -4.9344 0.11589E-04 -4.9359 0.99655E+00 -0.0015 54 KCl,aq 0.28369E-09 -9.5472 0.28369E-09 -9.5472 0.10000E+01 0.0000 56 KOH,aq 0.75375E-06 -6.1228 0.75375E-06 -6.1228 0.10000E+01 0.0000 57 KSO4- 0.85098E-15 -15.0701 0.71075E-15 -15.1483 0.83522E+00 -0.0782 58 MgCO3,aq 0.83624E-14 -14.0777 0.83624E-14 -14.0777 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.70413E-16 -16.1523 0.58923E-16 -16.2297 0.83682E+00 -0.0774 60 MgCl+ 0.22701E-14 -14.6439 0.18997E-14 -14.7213 0.83682E+00 -0.0774 61 MgOH+ 0.68828E-10 -10.1622 0.57597E-10 -10.2396 0.83682E+00 -0.0774 63 MnO,aq 0.17691E-08 -8.7522 0.17691E-08 -8.7522 0.10000E+01 0.0000 64 MnOH+ 0.45780E-09 -9.3393 0.38310E-09 -9.4167 0.83682E+00 -0.0774 65 MnO2-2 0.20598E-10 -10.6862 0.10675E-10 -10.9716 0.51826E+00 -0.2855 66 HMnO2- 0.20766E-09 -9.6826 0.17344E-09 -9.7608 0.83522E+00 -0.0782 69 MnCl+ 0.82677E-14 -14.0826 0.69186E-14 -14.1600 0.83682E+00 -0.0774 71 NaCl,aq 0.65700E-06 -6.1824 0.65700E-06 -6.1824 0.10000E+01 0.0000 72 NaOH,aq 0.96047E-04 -4.0175 0.96047E-04 -4.0175 0.10000E+01 0.0000 74 OH- 0.93446E-02 -2.0294 0.77907E-02 -2.1084 0.83371E+00 -0.0790 79 HPO3-2 0.16408E-14 -14.7849 0.85038E-15 -15.0704 0.51826E+00 -0.2855 81 H2PO3- 0.15142E-18 -18.8198 0.12647E-18 -18.8980 0.83522E+00 -0.0782 82 H3PO4,aq 0.90572E-18 -18.0430 0.90572E-18 -18.0430 0.10000E+01 0.0000 83 H2PO4- 0.38531E-10 -10.4142 0.32213E-10 -10.4920 0.83601E+00 -0.0778 84 PO4-3 0.10673E-08 -8.9717 0.25904E-09 -9.5866 0.24270E+00 -0.6149 88 HP2O7-3 0.94703E-18 -18.0236 0.21906E-18 -18.6594 0.23132E+00 -0.6358 89 P2O7-4 0.91480E-17 -17.0387 0.70566E-18 -18.1514 0.77138E-01 -1.1127 90 H2S,aq 0.51071E-08 -8.2918 0.50894E-08 -8.2933 0.99655E+00 -0.0015 91 S2-2 0.18189E-14 -14.7402 0.94267E-15 -15.0256 0.51826E+00 -0.2855 97 SO3-2 0.10024E-17 -17.9990 0.52699E-18 -18.2782 0.52575E+00 -0.2792 99 HSO4- 0.29857E-19 -19.5250 0.25009E-19 -19.6019 0.83763E+00 -0.0769 Charge balance for all species = 0.3802E-11 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.8825935E-10 -.2230436E-01 -.2244240E+02 0.0000 2 H2O 0.1000000E+01 0.5550489E+02 0.9982000E+06 0.0000 3 Cl- 0.1431706E-03 0.1438279E-03 0.5090271E+01 6.2075 4 SO4-- 0.6737545E-12 -.1580821E-04 -.1515924E+01 7.8036 5 HCO3- 0.2493564E-06 0.1362451E-04 0.8298851E+00 3.4491 6 HS- 0.2658142E-04 0.4239474E-04 0.1399643E+01 5.4763 7 Al+++ 0.9684132E-29 0.5321767E-05 0.1433398E+00 0.7393 8 H4SiO4 0.6958072E-03 0.1353390E-01 0.1298556E+04 -3.1575 9 Ca++ 0.1349056E-06 0.2315897E-06 0.9265528E-02 13.1019 10 Mg++ 0.2110550E-10 0.9315810E-10 0.2260925E-05 9.2943 11 Fe++ 0.5816018E-13 0.3630621E-07 0.2024070E-02 6.7350 12 K+ 0.1564539E-03 0.1572079E-03 0.6136465E+01 6.2467 13 Na+ 0.1985320E-01 0.2229897E-01 0.5117582E+03 8.3494 14 Mn++ 0.1827312E-10 0.2473471E-08 0.1356515E-03 9.2326 15 HPO4-- 0.4532966E-07 0.4643550E-07 0.4449090E-02 12.6316 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.6457791E+01 -.2139658E-01 -.6436395E+01 0.0000000E+00 2 H2O 0.5061945E+02 0.5324587E+02 -.2626420E+01 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.1083371E-01 -.1516483E-04 0.1084887E-01 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.1080820E-01 0.4066930E-04 -.1084887E-01 0.0000000E+00 7 Al+++ 0.1271686E+01 0.5105174E-05 0.1271681E+01 0.0000000E+00 8 H4SiO4 0.4060975E+01 0.1298308E-01 0.4047992E+01 0.0000000E+00 9 Ca++ 0.4485690E+00 0.2221642E-06 0.4485687E+00 0.0000000E+00 10 Mg++ 0.3095230E+00 0.8936663E-10 0.3095230E+00 0.0000000E+00 11 Fe++ 0.2780726E+00 0.3482857E-07 0.2780726E+00 0.0000000E+00 12 K+ 0.8280234E-01 0.1508097E-03 0.8265153E-01 0.0000000E+00 13 Na+ 0.4897038E+00 0.2139141E-01 0.4683124E+00 0.0000000E+00 14 Mn++ 0.6762035E-02 0.2372802E-08 0.6762033E-02 0.0000000E+00 15 HPO4-- 0.2307849E-02 0.4454561E-07 0.2307804E-02 0.0000000E+00 Chg. balance for solid moles: -.6141E-15 Mass of aqueous solution: 0.960970E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 389.9990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 0.4678 -0.330 122.7 2.089 28.80 47.09 andradite 0.4340E-01 -1.363 22.05 1.343 5.178 5.729 grossular 0.1052E-01 -1.978 4.738 0.676 1.112 1.318 apatite-OH 0.7693E-03 -3.114 0.3864 -0.413 0.9073E-01 0.1228 clinochlore 0.5658E-01 -1.247 31.45 1.498 7.384 11.96 daphnite 0.1638E-01 -1.786 11.68 1.068 2.744 3.541 chlorite-Mn 0.1352E-02 -2.869 0.9588 -0.018 0.2251 0.3055 diopside 0.1195E-01 -1.923 2.588 0.413 0.6078 0.7911 hedenbergite 0.3099E-02 -2.509 0.7689 -0.114 0.1805 0.2106 microcline 0.7253E-01 -1.139 20.19 1.305 4.740 7.886 stilbite 0.2598 -0.585 183.1 2.263 43.00 85.41 stilpnomelane-Fe 0.2025E-01 -1.694 21.83 1.339 5.125 7.540 tr.625ac.25prg.125 0.4046E-02 -2.393 3.458 0.539 0.8121 1.113 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8049E+00 0.8049E+00 1.0000 -0.094 grossular 0.1951E+00 0.1951E+00 1.0000 -0.710 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.7614E+00 0.7614E+00 1.0000 -0.118 daphnite 0.2204E+00 0.2204E+00 1.0000 -0.657 chlorite-Mn 0.1820E-01 0.1820E-01 1.0000 -1.740 diopside 0.7941E+00 0.7941E+00 1.0000 -0.100 hedenbergite 0.2059E+00 0.2059E+00 1.0000 -0.686 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 tr.625ac.25prg.125 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 425.882329 g Volume = 173.016603 cm3 Porosity: -10.2019% V(tot) - V(min): -.16017E+02 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 389.9990000 g log = 2.5911 Original solution: 1000.0103000 g Original solution / Rock added: 2.56 (Water/Rock Ratio), log = 0.4089 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0547 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9679E+00 0.9855 0.1006E+01 0.1021E+01 CO2,gas 0.3330E-08 1.0069 0.3536E-08 0.3512E-08 CH4,gas 0.1772E-01 1.0125 0.1892E-01 0.1869E-01 H2,gas 0.1442E-01 1.0006 0.1522E-01 0.1521E-01 H2S,gas 0.1332E-06 0.9959 0.1399E-06 0.1405E-06 S2,gas 0.3009E-29 1.0000 0.3174E-29 0.3174E-29 CO,gas 0.1360E-13 1.0000 0.1434E-13 0.1434E-13 SO3,gas 0.6900E-48 1.0000 0.7277E-48 0.7277E-48 SO2,gas 0.4084E-27 1.0000 0.4308E-27 0.4308E-27 HCl,gas 0.2719E-17 1.0000 0.2867E-17 0.2867E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 16 albite -0.38 -0.38 0.00 0.000 -0.94784E-12 22 andradite 39.01 39.01 0.00 0.000 0.12132E-10 23 grossular 32.73 32.73 0.00 0.000 -0.24265E-10 32 apatite-OH -18.15 -18.15 0.00 0.000 0.60662E-11 46 clinochlore 39.07 39.07 0.00 0.000 -0.12132E-10 47 daphnite 28.97 28.97 0.00 0.000 -0.36397E-10 48 chlorite-Mn 46.87 46.87 0.00 0.000 0.12132E-10 67 diopside 16.18 16.18 0.00 0.000 0.00000E+00 68 hedenbergite 14.21 14.21 0.00 0.000 0.00000E+00 116 microcline -2.49 -2.49 0.00 0.000 0.15165E-11 163 stilbite -7.52 -7.52 0.00 0.000 0.15165E-10 164 stilpnomelane-Fe 13.02 13.02 0.00 0.000 -0.27298E-10 245 tr.625ac.25prg.125 45.16 45.16 0.00 0.000 0.12132E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -16.81 -10.15 -3.383 0.17332E+05 -8.451 3 CH4,gas 4.54 1.12 -3.42 -0.855 0.58429E+04 -1.723 4 H2,gas 8.00 4.48 -3.52 -2.010 0.60046E+04 -1.818 5 H2S,gas -6.23 -14.78 -8.55 -4.277 0.14604E+05 -6.854 6 S2,gas -7.34 -38.53 -31.20 -4.800 0.53269E+05 -29.498 7 CO,gas 3.21 -12.33 -15.54 -4.782 0.26538E+05 -13.843 8 SO3,gas 17.12 -32.72 -49.84 -12.459 0.85095E+05 -48.138 9 SO2,gas 0.83 -28.23 -29.06 -7.751 0.49627E+05 -27.366 10 HCl,gas 5.19 -14.05 -19.24 -9.621 0.32854E+05 -17.543 11 acmite 7.71 6.53 -1.18 -0.123 0.20180E+04 15 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 19 spessartine 24.46 19.70 -4.75 -0.238 0.81166E+04 20 analcite 3.32 2.77 -0.55 -0.061 0.93607E+03 26 annite 20.12 17.72 -2.40 -0.134 0.41062E+04 27 phlogopite 27.06 25.40 -1.67 -0.093 0.28483E+04 29 anorthite 12.71 8.27 -4.44 -0.342 0.75894E+04 35 aragonite 0.97 -3.71 -4.68 -1.558 0.79827E+04 36 brucite 12.57 9.29 -3.27 -0.655 0.55907E+04 37 calcite 0.81 -3.71 -4.52 -1.507 0.77185E+04 38 carnegieite-low 9.02 5.93 -3.09 -0.442 0.52797E+04 39 carnegieite-high 10.09 5.93 -4.16 -0.595 0.71067E+04 40 carpholite-Mg 8.58 4.46 -4.12 -0.275 0.70420E+04 41 carpholite-Fe 6.71 1.90 -4.81 -0.321 0.82199E+04 42 celadonite 5.34 3.65 -1.69 -0.099 0.28878E+04 43 celadonite-Fe 3.88 1.09 -2.79 -0.164 0.47562E+04 44 chrysotile 23.89 21.57 -2.32 -0.194 0.39690E+04 49 chlorite-Al-free 47.17 43.14 -4.04 -0.168 0.68931E+04 51 chloritoid-Fe 9.17 5.06 -4.12 -0.275 0.70306E+04 52 chloritoid-Mn 11.40 7.55 -3.85 -0.256 0.65694E+04 54 coesite -2.38 -3.16 -0.78 -0.260 0.13343E+04 61 cristobalite -2.56 -3.16 -0.60 -0.199 0.10197E+04 63 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71234E+04 65 diaspore 2.87 0.74 -2.13 -0.356 0.36444E+04 66 diamond -3.10 -7.84 -4.74 -1.355 0.80969E+04 71 enstatite 17.26 12.27 -4.99 -0.499 0.85225E+04 73 clinoenstatite 17.17 12.27 -4.89 -0.489 0.83541E+04 75 epidote 24.67 22.70 -1.97 -0.095 0.33577E+04 76 clinozoisite 22.81 18.95 -3.86 -0.175 0.65854E+04 77 epidote-Fe 29.84 26.46 -3.38 -0.176 0.57767E+04 78 fayalite 14.05 10.31 -3.73 -0.533 0.63743E+04 79 ferrosilite 11.15 7.16 -3.99 -0.399 0.68204E+04 83 gibbsite 4.08 0.74 -3.34 -0.477 0.57030E+04 84 glaucophane 22.97 20.80 -2.17 -0.059 0.37131E+04 85 glaucophane-Fe 17.28 13.12 -4.15 -0.112 0.70920E+04 86 graphite -3.55 -7.84 -4.30 -1.228 0.73391E+04 87 greenalite 16.14 13.89 -2.25 -0.187 0.38409E+04 90 hematite 12.57 8.99 -3.58 -0.434 0.61114E+04 91 heulandite -5.83 -7.52 -1.69 -0.077 0.28938E+04 95 jadeite 4.22 2.77 -1.44 -0.144 0.24616E+04 97 kalsilite 7.58 3.83 -3.76 -0.536 0.64122E+04 98 kaolinite -1.33 -4.84 -3.50 -0.319 0.59824E+04 101 laumontite 2.88 1.95 -0.93 -0.062 0.15930E+04 102 lawsonite 9.62 8.27 -1.35 -0.090 0.23061E+04 103 leucite 4.12 0.67 -3.45 -0.345 0.58871E+04 105 lizardite 23.24 21.57 -1.68 -0.140 0.28616E+04 107 magnetite 20.09 15.72 -4.37 -0.356 0.74538E+04 108 minnesotaite 10.39 7.58 -2.81 -0.165 0.48033E+04 112 manganosite 14.06 9.23 -4.83 -1.206 0.82395E+04 120 muscovite 2.58 -1.01 -3.59 -0.211 0.61304E+04 121 paragonite 4.24 1.09 -3.14 -0.185 0.53695E+04 122 nepheline 8.34 5.93 -2.41 -0.344 0.41121E+04 128 periclase-Fe 11.63 6.74 -4.89 -1.223 0.83522E+04 134 phlogopite-Na 29.65 27.50 -2.15 -0.119 0.36671E+04 136 prehnite 19.37 18.21 -1.16 -0.068 0.19840E+04 137 prehnite-Fe 22.50 21.96 -0.53 -0.032 0.91135E+03 138 pumpellyite-Fe 46.27 43.89 -2.38 -0.053 0.40557E+04 139 pumpellyite-Mg 48.99 46.45 -2.54 -0.056 0.43394E+04 143 pyrrhotite -4.26 -8.05 -3.79 -1.263 0.64680E+04 144 pyrrhotiteFe0.875 -6.02 -9.45 -3.43 -1.261 0.58552E+04 145 pyroxmangite 7.40 6.08 -1.32 -0.265 0.22601E+04 146 pyrophyllite -6.18 -11.15 -4.98 -0.311 0.84958E+04 147 quartz -2.99 -3.16 -0.17 -0.056 0.28698E+03 152 rhodonite 7.45 6.08 -1.37 -0.274 0.23403E+04 153 sanidine -1.28 -2.49 -1.21 -0.093 0.20677E+04 165 stilpnomelane-Mg 27.44 25.81 -1.63 -0.049 0.27797E+04 171 talc 16.49 15.25 -1.24 -0.073 0.21141E+04 174 tephroite 18.09 15.31 -2.78 -0.397 0.47437E+04 178 tridymite -2.63 -3.16 -0.53 -0.177 0.90696E+03 179 tremolite 47.87 47.42 -0.45 -0.012 0.77501E+03 180 ferroactinolite 38.45 34.62 -3.83 -0.104 0.65456E+04 181 troilite-low -4.41 -8.05 -3.64 -1.212 0.62108E+04 183 vesuvianite 223.47 218.82 -4.65 -0.035 0.79371E+04 187 wairakite 3.95 1.95 -2.00 -0.118 0.34149E+04 188 walstromite 11.51 9.94 -1.56 -0.313 0.26719E+04 189 wollastonite 10.46 9.94 -0.52 -0.103 0.88228E+03 190 pseudo-wollastonite 11.00 9.94 -1.06 -0.211 0.18021E+04 191 zoisite 22.85 18.95 -3.90 -0.177 0.66594E+04 192 akaganeite 7.75 4.49 -3.26 -0.705 0.55682E+04 199 chalcedony -2.80 -3.16 -0.36 -0.118 0.60628E+03 201 montmorillonite-Ca -2.29 -6.17 -3.88 -0.240 0.66178E+04 202 montmorillonite-K -2.24 -6.27 -4.03 -0.247 0.68814E+04 203 montmorillonite-Mg -2.48 -6.79 -4.31 -0.267 0.73675E+04 204 montmorillonite-Na -2.04 -5.57 -3.54 -0.216 0.60363E+04 205 nontronite-Ca 3.21 -0.20 -3.41 -0.221 0.58222E+04 206 nontronite-H 2.53 -2.36 -4.89 -0.328 0.83493E+04 207 nontronite-K 3.34 -0.30 -3.64 -0.233 0.62091E+04 208 nontronite-Mg 3.07 -0.82 -3.90 -0.253 0.66561E+04 209 nontronite-Na 3.52 0.40 -3.12 -0.200 0.53299E+04 224 tobermorite 9.82 7.76 -2.07 -0.564 0.35287E+04 230 alabandite -0.98 -5.55 -4.57 -1.524 0.78082E+04 233 boehmite 4.41 0.74 -3.67 -0.611 0.62614E+04 235 ferrous-oxide 9.81 6.74 -3.08 -0.769 0.52531E+04 240 silica-amorphous -2.09 -3.16 -1.07 -0.355 0.18205E+04 242 an20ab80 2.02 1.35 -0.67 -0.052 0.11470E+04 243 an25ab75 2.65 1.78 -0.87 -0.067 0.14808E+04 244 an30ab70 3.28 2.21 -1.07 -0.082 0.18241E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 10.0000000 g Current total amount of reactant added: 389.9990000 g New total amount of reactant added: 399.9990000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.3648E-11 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 11 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 399.9990000 Water: Moles liquid = 0.5319E+02 kg liquid = 0.9583E+00 Moles total = 0.5049E+02 kg total = 0.9097E+00 Activity = 1.0000 Stoichiometric ionic strength = .1132181E-01 Osmotic coef. = 0.9695 True ionic strength = .2001081E-01 Chg. balance for total moles = 0.3648E-11 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.88260E-10 -10.0542 0.74162E-10 -10.1298 0.84027E+00 -0.0756 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.14332E-03 -3.8437 0.11970E-03 -3.9219 0.83522E+00 -0.0782 4 SO4-- 0.67450E-12 -12.1710 0.35031E-12 -12.4556 0.51936E+00 -0.2845 5 HCO3- 0.24963E-06 -6.6027 0.20880E-06 -6.6803 0.83644E+00 -0.0776 6 HS- 0.26609E-04 -4.5750 0.22228E-04 -4.6531 0.83534E+00 -0.0781 7 Al+++ 0.96842E-29 -29.0139 0.22379E-29 -29.6502 0.23108E+00 -0.6362 8 H4SiO4 0.69581E-03 -3.1575 0.69581E-03 -3.1575 0.10000E+01 0.0000 9 Ca++ 0.13491E-06 -6.8700 0.69551E-07 -7.1577 0.51555E+00 -0.2877 10 Mg++ 0.21106E-10 -10.6756 0.10831E-10 -10.9653 0.51319E+00 -0.2897 11 Fe++ 0.58161E-13 -13.2354 0.29880E-13 -13.5246 0.51375E+00 -0.2892 12 K+ 0.15645E-03 -3.8056 0.13090E-03 -3.8831 0.83664E+00 -0.0775 13 Na+ 0.19853E-01 -1.7022 0.16579E-01 -1.7804 0.83507E+00 -0.0783 14 Mn++ 0.18284E-10 -10.7379 0.94010E-11 -11.0268 0.51418E+00 -0.2889 15 HPO4-- 0.45330E-07 -7.3436 0.23546E-07 -7.6281 0.51943E+00 -0.2845 16 HSiO3- 0.10489E-01 -1.9793 0.87606E-02 -2.0575 0.83522E+00 -0.0782 17 Ca(HSiO3)+ 0.16582E-07 -7.7804 0.13876E-07 -7.8577 0.83682E+00 -0.0774 18 Mg(HSiO3)+ 0.32138E-11 -11.4930 0.26893E-11 -11.5704 0.83682E+00 -0.0774 19 NaHSiO3,aq 0.23491E-02 -2.6291 0.23491E-02 -2.6291 0.10000E+01 0.0000 20 AlO+ 0.66147E-16 -16.1795 0.55353E-16 -16.2569 0.83682E+00 -0.0774 22 HAlO2,aq 0.14864E-09 -9.8279 0.14864E-09 -9.8279 0.10000E+01 0.0000 23 AlO2- 0.53215E-05 -5.2740 0.44366E-05 -5.3530 0.83371E+00 -0.0790 24 CH4,aq 0.12914E-04 -4.8889 0.12870E-04 -4.8904 0.99655E+00 -0.0015 25 C2H6,aq 0.24518E-14 -14.6105 0.24433E-14 -14.6120 0.99655E+00 -0.0015 29 CO,aq 0.96329E-17 -17.0162 0.96329E-17 -17.0162 0.10000E+01 0.0000 30 CO2,aq 0.33203E-10 -10.4788 0.33088E-10 -10.4803 0.99655E+00 -0.0015 31 CO3-2 0.47451E-06 -6.3238 0.24592E-06 -6.6092 0.51826E+00 -0.2855 32 CaCO3,aq 0.21446E-09 -9.6686 0.21446E-09 -9.6686 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.44298E-12 -12.3536 0.37070E-12 -12.4310 0.83682E+00 -0.0774 34 CaCl+ 0.16101E-10 -10.7932 0.13473E-10 -10.8705 0.83682E+00 -0.0774 35 CaCl2,aq 0.38317E-15 -15.4166 0.38317E-15 -15.4166 0.10000E+01 0.0000 36 CaOH+ 0.79871E-07 -7.0976 0.66838E-07 -7.1750 0.83682E+00 -0.0774 37 CaSO4,aq 0.77367E-17 -17.1114 0.77367E-17 -17.1114 0.10000E+01 0.0000 38 HCl,aq 0.16268E-14 -14.7887 0.16268E-14 -14.7887 0.10000E+01 0.0000 43 FeCl+ 0.67655E-17 -17.1697 0.56615E-17 -17.2471 0.83682E+00 -0.0774 46 FeO,aq 0.21115E-09 -9.6754 0.21115E-09 -9.6754 0.10000E+01 0.0000 47 FeOH+ 0.15672E-10 -10.8049 0.13115E-10 -10.8822 0.83682E+00 -0.0774 48 HFeO2- 0.35666E-07 -7.4477 0.29789E-07 -7.5259 0.83522E+00 -0.0782 49 FeO+ 0.10981E-16 -16.9594 0.91890E-17 -17.0367 0.83682E+00 -0.0774 51 FeO2- 0.40931E-09 -9.3880 0.34186E-09 -9.4662 0.83522E+00 -0.0782 52 HFeO2,aq 0.32245E-11 -11.4915 0.32245E-11 -11.4915 0.10000E+01 0.0000 53 H2,aq 0.11629E-04 -4.9344 0.11589E-04 -4.9360 0.99655E+00 -0.0015 54 KCl,aq 0.28399E-09 -9.5467 0.28399E-09 -9.5467 0.10000E+01 0.0000 56 KOH,aq 0.75375E-06 -6.1228 0.75375E-06 -6.1228 0.10000E+01 0.0000 57 KSO4- 0.85192E-15 -15.0696 0.71154E-15 -15.1478 0.83522E+00 -0.0782 58 MgCO3,aq 0.83716E-14 -14.0772 0.83716E-14 -14.0772 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.70491E-16 -16.1519 0.58988E-16 -16.2292 0.83682E+00 -0.0774 60 MgCl+ 0.22725E-14 -14.6435 0.19017E-14 -14.7209 0.83682E+00 -0.0774 61 MgOH+ 0.68828E-10 -10.1622 0.57597E-10 -10.2396 0.83682E+00 -0.0774 63 MnO,aq 0.17701E-08 -8.7520 0.17701E-08 -8.7520 0.10000E+01 0.0000 64 MnOH+ 0.45806E-09 -9.3391 0.38331E-09 -9.4164 0.83682E+00 -0.0774 65 MnO2-2 0.20609E-10 -10.6859 0.10681E-10 -10.9714 0.51826E+00 -0.2855 66 HMnO2- 0.20778E-09 -9.6824 0.17354E-09 -9.7606 0.83522E+00 -0.0782 69 MnCl+ 0.82811E-14 -14.0819 0.69298E-14 -14.1593 0.83682E+00 -0.0774 71 NaCl,aq 0.65769E-06 -6.1820 0.65769E-06 -6.1820 0.10000E+01 0.0000 72 NaOH,aq 0.96047E-04 -4.0175 0.96047E-04 -4.0175 0.10000E+01 0.0000 74 OH- 0.93446E-02 -2.0294 0.77907E-02 -2.1084 0.83371E+00 -0.0790 79 HPO3-2 0.16408E-14 -14.7849 0.85037E-15 -15.0704 0.51826E+00 -0.2855 81 H2PO3- 0.15141E-18 -18.8198 0.12646E-18 -18.8980 0.83522E+00 -0.0782 82 H3PO4,aq 0.90573E-18 -18.0430 0.90573E-18 -18.0430 0.10000E+01 0.0000 83 H2PO4- 0.38531E-10 -10.4142 0.32213E-10 -10.4920 0.83601E+00 -0.0778 84 PO4-3 0.10673E-08 -8.9717 0.25904E-09 -9.5866 0.24270E+00 -0.6149 88 HP2O7-3 0.94704E-18 -18.0236 0.21906E-18 -18.6594 0.23131E+00 -0.6358 89 P2O7-4 0.91480E-17 -17.0387 0.70566E-18 -18.1514 0.77138E-01 -1.1127 90 H2S,aq 0.51124E-08 -8.2914 0.50948E-08 -8.2929 0.99655E+00 -0.0015 91 S2-2 0.18228E-14 -14.7393 0.94466E-15 -15.0247 0.51826E+00 -0.2855 97 SO3-2 0.10034E-17 -17.9985 0.52756E-18 -18.2777 0.52575E+00 -0.2792 99 HSO4- 0.29890E-19 -19.5245 0.25037E-19 -19.6014 0.83763E+00 -0.0769 Charge balance for all species = 0.3808E-11 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.8825994E-10 -.2230433E-01 -.2244237E+02 0.0000 2 H2O 0.1000000E+01 0.5550489E+02 0.9982000E+06 0.0000 3 Cl- 0.1433206E-03 0.1439786E-03 0.5095606E+01 6.2079 4 SO4-- 0.6744989E-12 -.1582165E-04 -.1517213E+01 7.8041 5 HCO3- 0.2496310E-06 0.1363879E-04 0.8307548E+00 3.4496 6 HS- 0.2660927E-04 0.4243604E-04 0.1401007E+01 5.4767 7 Al+++ 0.9684162E-29 0.5321631E-05 0.1433361E+00 0.7393 8 H4SiO4 0.6958118E-03 0.1353393E-01 0.1298559E+04 -3.1575 9 Ca++ 0.1349067E-06 0.2315911E-06 0.9265583E-02 13.1019 10 Mg++ 0.2110565E-10 0.9315824E-10 0.2260928E-05 9.2943 11 Fe++ 0.5816086E-13 0.3630590E-07 0.2024053E-02 6.7350 12 K+ 0.1564549E-03 0.1572090E-03 0.6136506E+01 6.2467 13 Na+ 0.1985333E-01 0.2229912E-01 0.5117616E+03 8.3494 14 Mn++ 0.1828355E-10 0.2474850E-08 0.1357271E-03 9.2328 15 HPO4-- 0.4532968E-07 0.4643552E-07 0.4449092E-02 12.6315 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.6623377E+01 -.2137415E-01 -.6602002E+01 0.0000000E+00 2 H2O 0.5049410E+02 0.5319013E+02 -.2696033E+01 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.1111084E-01 -.1516183E-04 0.1112600E-01 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.1108534E-01 0.4066630E-04 -.1112600E-01 0.0000000E+00 7 Al+++ 0.1304293E+01 0.5099700E-05 0.1304288E+01 0.0000000E+00 8 H4SiO4 0.4165103E+01 0.1296951E-01 0.4152133E+01 0.0000000E+00 9 Ca++ 0.4600704E+00 0.2219329E-06 0.4600702E+00 0.0000000E+00 10 Mg++ 0.3174595E+00 0.8927320E-10 0.3174595E+00 0.0000000E+00 11 Fe++ 0.2852027E+00 0.3479181E-07 0.2852027E+00 0.0000000E+00 12 K+ 0.8492548E-01 0.1506528E-03 0.8477482E-01 0.0000000E+00 13 Na+ 0.5022563E+00 0.2136916E-01 0.4808871E+00 0.0000000E+00 14 Mn++ 0.6935421E-02 0.2371639E-08 0.6935419E-02 0.0000000E+00 15 HPO4-- 0.2367025E-02 0.4449899E-07 0.2366980E-02 0.0000000E+00 Chg. balance for solid moles: -.6167E-15 Mass of aqueous solution: 0.959964E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 399.9990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 0.4804 -0.318 126.0 2.100 28.84 48.35 andradite 0.4450E-01 -1.352 22.62 1.354 5.178 5.876 grossular 0.1079E-01 -1.967 4.859 0.687 1.112 1.352 apatite-OH 0.7890E-03 -3.103 0.3963 -0.402 0.9073E-01 0.1259 clinochlore 0.5800E-01 -1.237 32.24 1.508 7.380 12.26 daphnite 0.1679E-01 -1.775 11.98 1.078 2.742 3.630 chlorite-Mn 0.1387E-02 -2.858 0.9834 -0.007 0.2251 0.3134 diopside 0.1250E-01 -1.903 2.706 0.432 0.6196 0.8271 hedenbergite 0.3240E-02 -2.489 0.8039 -0.095 0.1840 0.2202 microcline 0.7439E-01 -1.128 20.71 1.316 4.740 8.088 stilbite 0.2663 -0.575 187.6 2.273 42.96 87.52 stilpnomelane-Fe 0.2077E-01 -1.683 22.39 1.350 5.126 7.734 tr.625ac.25prg.125 0.4129E-02 -2.384 3.530 0.548 0.8081 1.136 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8049E+00 0.8049E+00 1.0000 -0.094 grossular 0.1951E+00 0.1951E+00 1.0000 -0.710 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.7614E+00 0.7614E+00 1.0000 -0.118 daphnite 0.2204E+00 0.2204E+00 1.0000 -0.657 chlorite-Mn 0.1821E-01 0.1821E-01 1.0000 -1.740 diopside 0.7941E+00 0.7941E+00 1.0000 -0.100 hedenbergite 0.2059E+00 0.2059E+00 1.0000 -0.686 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 tr.625ac.25prg.125 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 436.807392 g Volume = 177.436910 cm3 Porosity: -10.2095% V(tot) - V(min): -.16437E+02 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 399.9990000 g log = 2.6021 Original solution: 1000.0103000 g Original solution / Rock added: 2.50 (Water/Rock Ratio), log = 0.3979 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0547 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9678E+00 0.9855 0.1006E+01 0.1021E+01 CO2,gas 0.3333E-08 1.0069 0.3540E-08 0.3516E-08 CH4,gas 0.1774E-01 1.0125 0.1894E-01 0.1871E-01 H2,gas 0.1442E-01 1.0006 0.1522E-01 0.1521E-01 H2S,gas 0.1333E-06 0.9959 0.1401E-06 0.1406E-06 S2,gas 0.3015E-29 1.0000 0.3180E-29 0.3180E-29 CO,gas 0.1361E-13 1.0000 0.1435E-13 0.1435E-13 SO3,gas 0.6907E-48 1.0000 0.7285E-48 0.7285E-48 SO2,gas 0.4089E-27 1.0000 0.4312E-27 0.4312E-27 HCl,gas 0.2722E-17 1.0000 0.2870E-17 0.2870E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 16 albite -0.38 -0.38 0.00 0.000 -0.13080E-10 22 andradite 39.01 39.01 0.00 0.000 0.24265E-10 23 grossular 32.73 32.73 0.00 0.000 0.24265E-10 32 apatite-OH -18.15 -18.15 0.00 0.000 0.00000E+00 46 clinochlore 39.07 39.07 0.00 0.000 -0.12132E-10 47 daphnite 28.97 28.97 0.00 0.000 0.24265E-10 48 chlorite-Mn 46.87 46.87 0.00 0.000 -0.24265E-10 67 diopside 16.18 16.18 0.00 0.000 0.00000E+00 68 hedenbergite 14.21 14.21 0.00 0.000 0.30331E-11 116 microcline -2.49 -2.49 0.00 0.000 0.15165E-11 163 stilbite -7.52 -7.52 0.00 0.000 0.15165E-10 164 stilpnomelane-Fe 13.02 13.02 0.00 0.000 -0.27298E-10 245 tr.625ac.25prg.125 45.16 45.16 0.00 0.000 -0.24265E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -16.81 -10.15 -3.383 0.17331E+05 -8.451 3 CH4,gas 4.54 1.12 -3.42 -0.855 0.58421E+04 -1.723 4 H2,gas 8.00 4.48 -3.52 -2.010 0.60047E+04 -1.818 5 H2S,gas -6.23 -14.78 -8.55 -4.276 0.14603E+05 -6.854 6 S2,gas -7.34 -38.53 -31.20 -4.799 0.53267E+05 -29.498 7 CO,gas 3.21 -12.33 -15.54 -4.782 0.26537E+05 -13.843 8 SO3,gas 17.12 -32.72 -49.84 -12.459 0.85095E+05 -48.138 9 SO2,gas 0.83 -28.23 -29.06 -7.750 0.49626E+05 -27.365 10 HCl,gas 5.19 -14.05 -19.24 -9.621 0.32854E+05 -17.542 11 acmite 7.71 6.53 -1.18 -0.123 0.20180E+04 15 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 19 spessartine 24.46 19.70 -4.75 -0.238 0.81154E+04 20 analcite 3.32 2.77 -0.55 -0.061 0.93607E+03 26 annite 20.12 17.72 -2.40 -0.134 0.41062E+04 27 phlogopite 27.06 25.40 -1.67 -0.093 0.28483E+04 29 anorthite 12.71 8.27 -4.44 -0.342 0.75894E+04 35 aragonite 0.97 -3.71 -4.67 -1.558 0.79819E+04 36 brucite 12.57 9.29 -3.27 -0.655 0.55907E+04 37 calcite 0.81 -3.71 -4.52 -1.507 0.77176E+04 38 carnegieite-low 9.02 5.93 -3.09 -0.442 0.52798E+04 39 carnegieite-high 10.09 5.93 -4.16 -0.595 0.71068E+04 40 carpholite-Mg 8.58 4.46 -4.12 -0.275 0.70420E+04 41 carpholite-Fe 6.71 1.90 -4.81 -0.321 0.82199E+04 42 celadonite 5.34 3.65 -1.69 -0.099 0.28878E+04 43 celadonite-Fe 3.88 1.09 -2.79 -0.164 0.47562E+04 44 chrysotile 23.89 21.57 -2.32 -0.194 0.39690E+04 49 chlorite-Al-free 47.17 43.14 -4.04 -0.168 0.68931E+04 51 chloritoid-Fe 9.17 5.06 -4.12 -0.275 0.70306E+04 52 chloritoid-Mn 11.40 7.55 -3.85 -0.256 0.65690E+04 54 coesite -2.38 -3.16 -0.78 -0.260 0.13343E+04 61 cristobalite -2.56 -3.16 -0.60 -0.199 0.10197E+04 63 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71234E+04 65 diaspore 2.87 0.74 -2.13 -0.356 0.36445E+04 66 diamond -3.10 -7.84 -4.74 -1.355 0.80961E+04 71 enstatite 17.26 12.27 -4.99 -0.499 0.85225E+04 73 clinoenstatite 17.17 12.27 -4.89 -0.489 0.83541E+04 75 epidote 24.67 22.70 -1.97 -0.095 0.33578E+04 76 clinozoisite 22.81 18.95 -3.86 -0.175 0.65854E+04 77 epidote-Fe 29.84 26.46 -3.38 -0.176 0.57767E+04 78 fayalite 14.05 10.31 -3.73 -0.533 0.63743E+04 79 ferrosilite 11.15 7.16 -3.99 -0.399 0.68204E+04 83 gibbsite 4.08 0.74 -3.34 -0.477 0.57030E+04 84 glaucophane 22.97 20.80 -2.17 -0.059 0.37131E+04 85 glaucophane-Fe 17.28 13.12 -4.15 -0.112 0.70920E+04 86 graphite -3.55 -7.84 -4.30 -1.228 0.73383E+04 87 greenalite 16.14 13.89 -2.25 -0.187 0.38409E+04 90 hematite 12.57 8.99 -3.58 -0.434 0.61114E+04 91 heulandite -5.83 -7.52 -1.69 -0.077 0.28938E+04 95 jadeite 4.22 2.77 -1.44 -0.144 0.24616E+04 97 kalsilite 7.58 3.83 -3.76 -0.536 0.64122E+04 98 kaolinite -1.33 -4.84 -3.50 -0.319 0.59824E+04 101 laumontite 2.88 1.95 -0.93 -0.062 0.15930E+04 102 lawsonite 9.62 8.27 -1.35 -0.090 0.23061E+04 103 leucite 4.12 0.67 -3.45 -0.345 0.58871E+04 105 lizardite 23.24 21.57 -1.68 -0.140 0.28616E+04 107 magnetite 20.09 15.72 -4.37 -0.356 0.74538E+04 108 minnesotaite 10.39 7.58 -2.81 -0.165 0.48033E+04 112 manganosite 14.06 9.23 -4.83 -1.206 0.82391E+04 120 muscovite 2.58 -1.01 -3.59 -0.211 0.61304E+04 121 paragonite 4.24 1.09 -3.14 -0.185 0.53695E+04 122 nepheline 8.34 5.93 -2.41 -0.344 0.41121E+04 128 periclase-Fe 11.63 6.74 -4.89 -1.223 0.83522E+04 134 phlogopite-Na 29.65 27.50 -2.15 -0.119 0.36671E+04 136 prehnite 19.37 18.21 -1.16 -0.068 0.19840E+04 137 prehnite-Fe 22.50 21.96 -0.53 -0.032 0.91136E+03 138 pumpellyite-Fe 46.27 43.89 -2.38 -0.053 0.40557E+04 139 pumpellyite-Mg 48.99 46.45 -2.54 -0.056 0.43395E+04 143 pyrrhotite -4.26 -8.05 -3.79 -1.263 0.64672E+04 144 pyrrhotiteFe0.875 -6.02 -9.45 -3.43 -1.261 0.58545E+04 145 pyroxmangite 7.40 6.08 -1.32 -0.265 0.22596E+04 146 pyrophyllite -6.18 -11.15 -4.98 -0.311 0.84958E+04 147 quartz -2.99 -3.16 -0.17 -0.056 0.28698E+03 152 rhodonite 7.45 6.08 -1.37 -0.274 0.23399E+04 153 sanidine -1.28 -2.49 -1.21 -0.093 0.20677E+04 165 stilpnomelane-Mg 27.44 25.81 -1.63 -0.049 0.27797E+04 171 talc 16.49 15.25 -1.24 -0.073 0.21141E+04 174 tephroite 18.09 15.31 -2.78 -0.397 0.47428E+04 178 tridymite -2.63 -3.16 -0.53 -0.177 0.90696E+03 179 tremolite 47.87 47.42 -0.45 -0.012 0.77500E+03 180 ferroactinolite 38.45 34.62 -3.83 -0.104 0.65455E+04 181 troilite-low -4.41 -8.05 -3.64 -1.212 0.62100E+04 183 vesuvianite 223.47 218.82 -4.65 -0.035 0.79373E+04 187 wairakite 3.95 1.95 -2.00 -0.118 0.34149E+04 188 walstromite 11.51 9.94 -1.56 -0.313 0.26719E+04 189 wollastonite 10.46 9.94 -0.52 -0.103 0.88228E+03 190 pseudo-wollastonite 11.00 9.94 -1.06 -0.211 0.18021E+04 191 zoisite 22.85 18.95 -3.90 -0.177 0.66595E+04 192 akaganeite 7.75 4.49 -3.26 -0.705 0.55682E+04 199 chalcedony -2.80 -3.16 -0.36 -0.118 0.60628E+03 201 montmorillonite-Ca -2.29 -6.17 -3.88 -0.240 0.66178E+04 202 montmorillonite-K -2.24 -6.27 -4.03 -0.247 0.68814E+04 203 montmorillonite-Mg -2.48 -6.79 -4.31 -0.267 0.73675E+04 204 montmorillonite-Na -2.04 -5.57 -3.54 -0.216 0.60363E+04 205 nontronite-Ca 3.21 -0.20 -3.41 -0.221 0.58222E+04 206 nontronite-H 2.53 -2.36 -4.89 -0.328 0.83492E+04 207 nontronite-K 3.34 -0.30 -3.64 -0.233 0.62090E+04 208 nontronite-Mg 3.07 -0.82 -3.90 -0.253 0.66560E+04 209 nontronite-Na 3.52 0.40 -3.12 -0.200 0.53299E+04 224 tobermorite 9.82 7.76 -2.07 -0.564 0.35287E+04 230 alabandite -0.98 -5.55 -4.57 -1.524 0.78070E+04 233 boehmite 4.41 0.74 -3.67 -0.611 0.62614E+04 235 ferrous-oxide 9.81 6.74 -3.08 -0.769 0.52531E+04 240 silica-amorphous -2.09 -3.16 -1.07 -0.355 0.18205E+04 242 an20ab80 2.02 1.35 -0.67 -0.052 0.11470E+04 243 an25ab75 2.65 1.78 -0.87 -0.067 0.14808E+04 244 an30ab70 3.28 2.21 -1.07 -0.082 0.18241E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 10.0000000 g Current total amount of reactant added: 399.9990000 g New total amount of reactant added: 409.9990000 g Mixing fraction reached given limit of 0.4000E+03 TOTMIX = 0.4100E+03 Execution stopped.