File SKIP_SPECIES.TXT lists species and minerals omitted from the calculations due to given T, P, option switches, or suppression in CHIMRUN, or are suppressed in the SOLTHERM database. It also lists minerals for which density is not specified in SOLTHERM. This is an extended P(to 5 kB), T(to 600 C) run (CON_FLAG = 1). methanol,aq is suppressed in SOLTHERM data file. methanol,aq is suppressed in SOLTHERM data file. CuCl4-3 is suppressed in SOLTHERM data file. H2BO3- is suppressed in SOLTHERM data file. UO2CO3,aq is suppressed in SOLTHERM data file. UO2SO4,aq is suppressed in SOLTHERM data file. UO2Cl2,aq is suppressed in SOLTHERM data file. UO2F2,aq is suppressed in SOLTHERM data file. PO4-3 is suppressed in SOLTHERM data file. H2PO4- is suppressed in SOLTHERM data file. H3PO4 is suppressed in SOLTHERM data file. O2,gas is suppressed in THIS RUN. O2,gas is suppressed in THIS RUN. amesite is suppressed in SOLTHERM data file. antigorite is suppressed in SOLTHERM data file. goethite is suppressed in THIS RUN. goethite is suppressed in THIS RUN. riebeckite is suppressed in THIS RUN. riebeckite is suppressed in THIS RUN. sapphirine-Fe(221) is suppressed in SOLTHERM data file. sapphirine(221) is suppressed in SOLTHERM data file. talc-prl is suppressed in SOLTHERM data file. PrO1.833(s) is suppressed in SOLTHERM data file. niter-NH4 is suppressed in SOLTHERM data file. FMQ_HS-1 is suppressed in THIS RUN. kf-ab-equil is suppressed in THIS RUN. ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Species No. Charge Tot.moles Trial molality Gamma Mixing solution H+ 1 1. -0.66234E+01 0.88260E-10 0.8403 0.00000000E+00 H2O 2 0. 0.50494E+02 0.10000E+01 1.0000 0.00000000E+00 Cl- 3 -1. 0.13797E-03 0.14332E-03 0.8352 0.00000000E+00 SO4-- 4 -2. 0.11111E-01 0.67450E-12 0.5194 0.00000000E+00 HCO3- 5 -1. 0.13070E-04 0.24963E-06 0.8364 0.00000000E+00 HS- 6 -1. -0.11085E-01 0.26609E-04 0.8353 0.00000000E+00 Al+++ 7 3. 0.13043E+01 0.96842E-29 0.2311 0.00000000E+00 H4SiO4 8 0. 0.41651E+01 0.69581E-03 1.0000 0.00000000E+00 Ca++ 9 2. 0.46007E+00 0.13491E-06 0.5155 0.00000000E+00 Mg++ 10 2. 0.31746E+00 0.21106E-10 0.5132 0.00000000E+00 Fe++ 11 2. 0.28520E+00 0.58161E-13 0.5138 0.00000000E+00 K+ 12 1. 0.84925E-01 0.15645E-03 0.8366 0.00000000E+00 Na+ 13 1. 0.50226E+00 0.19853E-01 0.8351 0.00000000E+00 Mn++ 14 2. 0.69354E-02 0.18284E-10 0.5142 0.00000000E+00 HPO4-- 15 -2. 0.23670E-02 0.45330E-07 0.5194 0.00000000E+00 Chg. balance for total moles = -.1586E-10 Max. difference allowed = 0.1380E-07 The following parameters were given: ERPC = 0.1000E-11 pH = 0.0000 PFLUID = 50.0000 SLIM = 0.800000E+03 TEMP = 100.0000 SINC = 0.2000E+02 TEMPC = 0.0000 TOTMIX = 0.399999E+03 ENTH = 0.0000 SENTH = 0.0000 DENTH = 0.0000 TOTWAT = 90.0000 SOLMIN = 0.0000E+00 RM = 0.0000 AQGRM = 1000.0103 SUPRNT = 0.1000E-19 VBOX-1 = 160.9996 RHOFRS = 0.0000 RHOROC = 2.5000 The following options were selected: CONFLG = 1 C = 3 IFRAC = 0 IPUNCH = 2 NLOOP = 400 ISTEP = 2 LIMSOL = 1 LOOC = 0 IENTH = 0 ITREF = 0 IDEAL = 0 IPSAT = 1 INCREM = 0 INCP = 0 MINSOL = 1 NEUT = 0 AWAT = 0 CHGF = 0 Of the derived species, only those with molality > 0.10E-19 will appear in the output Species No. Charge Log K(diss) Species No. Charge Log K(diss) HSiO3- 16 -1. 9.0298 MnO2-2 65 -2. 40.4638 Ca(HSiO3)+ 17 1. 7.6723 HMnO2- 66 -1. 29.1232 Mg(HSiO3)+ 18 1. 7.5773 MnO4- 67 -1. 83.3111 NaHSiO3,aq 19 0. 7.8210 MnO4-2 68 -2. 81.3005 AlO+ 20 1. 6.8663 MnCl+ 69 1. -0.7894 AlOH+2 21 2. 3.1691 MnSO4,aq 70 0. -2.4604 HAlO2,aq 22 0. 10.5671 NaCl,aq 71 0. 0.4796 AlO2- 23 -1. 16.2221 NaOH,aq 72 0. 12.3669 CH4,aq 24 0. 6.0126 O2,aq 73 0. 53.5502 C2H6,aq 25 0. 12.3733 OH- 74 -1. 12.2382 C3H8,aq 26 0. 17.3707 HO2- 75 -1. 50.8010 C4H10,aq 27 0. 22.3757 H2O2,aq 76 0. 40.0166 ethanol,aq 28 0. 15.3258 H3PO2,aq 77 0. 24.3066 CO,aq 29 0. 4.6892 H2PO2- 78 -1. 26.5366 CO2,aq 30 0. -6.3298 HPO3-2 79 -2. 11.9254 CO3-2 31 -2. 10.0588 H3PO3,aq 80 0. 3.5792 CaCO3,aq 32 0. 5.9605 H2PO3- 81 -1. 5.6232 Ca(HCO3)+ 33 1. -1.4070 H3PO4,aq 82 0. -9.8447 CaCl+ 34 1. -0.2091 H2PO4- 83 -1. -7.2659 CaCl2,aq 35 0. 0.4151 PO4-3 84 -3. 12.0884 CaOH+ 36 1. 10.1471 H4P2O7,aq 85 0. -17.8095 CaSO4,aq 37 0. -2.5018 H3P2O7- 86 -1. -15.9156 HCl,aq 38 0. 0.7370 H2P2O7-2 87 -2. -13.4262 HClO,aq 39 0. 32.4260 HP2O7-3 88 -3. -6.7266 ClO- 40 -1. 39.6530 P2O7-4 89 -4. 2.8952 HClO2,aq 41 0. 70.1812 H2S,aq 90 0. -6.4900 Fe+3 42 3. 8.3809 S2-2 91 -2. 1.2355 FeCl+ 43 1. -0.1994 S3-2 92 -2. -8.8031 FeCl2,aq 44 0. 4.3001 S3- 93 -1. -16.3389 FeCl+2 45 2. 6.5269 S4-2 94 -2. -18.6615 FeO,aq 46 0. 16.4104 S5-2 95 -2. -28.3439 FeOH+ 47 1. 7.4874 SO2,aq 96 0. -0.2309 HFeO2- 48 -1. 24.3908 SO3-2 97 -2. 10.3052 FeO+ 49 1. 11.4004 HSO3- 98 -1. 2.5086 FeOH+2 50 2. 9.1194 HSO4- 99 -1. -2.9839 FeO2- 51 -1. 24.0895 HSO5- 100 -1. 38.8366 HFeO2,aq 52 0. 15.9850 S2O3-2 101 -2. -4.5600 H2,aq 53 0. 9.4190 HS2O3- 102 -1. -6.8123 KCl,aq 54 0. 1.7417 H2S2O3,aq 103 0. -8.0173 KHSO4,aq 55 0. -0.4514 S2O4-2 104 -2. 10.5541 KOH,aq 56 0. 12.3695 HS2O4- 105 -1. 7.6551 KSO4- 57 -1. -1.1908 H2S2O4,aq 106 0. 6.6259 MgCO3,aq 58 0. 6.5614 S2O5-2 107 -2. 10.0741 Mg(HCO3)+ 59 1. -1.4164 S2O6-2 108 -2. 11.5521 MgCl+ 60 1. -0.1664 S2O8-2 109 -2. 42.0620 MgOH+ 61 1. 9.4041 S3O6-2 110 -2. 3.7866 Mn+3 62 3. 19.1453 S4O6-2 111 -2. -17.8657 MnO,aq 63 0. 17.9848 S5O6-2 112 -2. -14.1333 MnOH+ 64 1. 8.5194 113 0. 10.3111 For mixed gases (JSOLS=6), log K(hydrol) = log (K*P) Log K Trial Log K Trial Mineral No. hydrol Moles Mineral No. hydrol Moles H2O,gas 1 1.696 0.0000E+00 osumilite(2) 124 20.667 0.0000E+00 CO2,gas 2 -6.660 0.0000E+00 osumilite-Fe 125 14.390 0.0000E+00 CH4,gas 3 4.544 0.0000E+00 pargasite 126 65.092 0.0000E+00 H2,gas 4 8.000 0.0000E+00 periclase 127 16.138 0.0000E+00 H2S,gas 5 -6.230 0.0000E+00 periclase-Fe 128 11.627 0.0000E+00 S2,gas 6 -7.335 0.0000E+00 perovskite-Al 129 12.344 0.0000E+00 CO,gas 7 3.215 0.0000E+00 perovskite-Ca 130 23.807 0.0000E+00 SO3,gas 8 17.121 0.0000E+00 perovskite-Fe 131 21.143 0.0000E+00 SO2,gas 9 0.832 0.0000E+00 perovskite-Mg 132 23.119 0.0000E+00 HCl,gas 10 5.189 0.0000E+00 phase_A 133 80.189 0.0000E+00 acmite 11 7.710 0.0000E+00 phlogopite-Na 134 29.647 0.0000E+00 akermanite 12 36.442 0.0000E+00 piemontite(ordered) 135 33.776 0.0000E+00 akimotoite 13 16.591 0.0000E+00 prehnite 136 19.372 0.0000E+00 akimotoite-Fe 14 13.067 0.0000E+00 prehnite-Fe 137 22.498 0.0000E+00 albite-high 15 0.693 0.0000E+00 pumpellyite-Fe 138 46.269 0.0000E+00 albite 16 -0.384 0.4804E+00 pumpellyite-Mg 139 48.995 0.0000E+00 almandine 17 24.442 0.0000E+00 px-Mg-tschermaks 140 19.616 0.0000E+00 pyrope 18 37.248 0.0000E+00 px-Ca-tschermaks 141 18.610 0.0000E+00 spessartine 19 24.457 0.0000E+00 pyrite 142 -21.247 0.0000E+00 analcite 20 3.322 0.0000E+00 pyrrhotite 143 -4.260 0.0000E+00 andalusite 21 5.002 0.0000E+00 pyrrhotiteFe0.875 144 -6.017 0.0000E+00 andradite 22 39.009 0.4450E-01 pyroxmangite 145 7.399 0.0000E+00 grossular 23 32.731 0.1079E-01 pyrophyllite 146 -6.176 0.0000E+00 anhydrite 24 -5.317 0.0000E+00 quartz 147 -2.989 0.0000E+00 ankerite 25 -2.135 0.0000E+00 rankinite 148 40.713 0.0000E+00 annite 26 20.123 0.0000E+00 ringwoodite-Fe 149 15.456 0.0000E+00 phlogopite 27 27.065 0.0000E+00 ringwoodite-Mg 150 27.575 0.0000E+00 biotite-Mn 28 32.960 0.0000E+00 rhodochrosite 151 -0.976 0.0000E+00 anorthite 29 12.710 0.0000E+00 rhodonite 152 7.446 0.0000E+00 anthophyllite 30 51.852 0.0000E+00 sanidine 153 -1.275 0.0000E+00 anthophyllite-Fe 31 29.306 0.0000E+00 sapphirine(351) 154 78.899 0.0000E+00 apatite-OH 32 -18.153 0.7890E-03 siderite 155 -2.608 0.0000E+00 apatite-OH-zs 33 -12.736 0.0000E+00 sillimanite 156 5.262 0.0000E+00 apatite-Cl-zs 34 -16.674 0.0000E+00 sodalite 157 49.976 0.0000E+00 aragonite 35 0.967 0.0000E+00 spinel 158 20.870 0.0000E+00 brucite 36 12.569 0.0000E+00 spurrite 159 59.482 0.0000E+00 calcite 37 0.812 0.0000E+00 staurolite-Fe 160 73.598 0.0000E+00 carnegieite-low 38 9.023 0.0000E+00 staurolite-Mg 161 89.802 0.0000E+00 carnegieite-high 39 10.093 0.0000E+00 staurolite-Mn 162 83.909 0.0000E+00 carpholite-Mg 40 8.582 0.0000E+00 stilbite 163 -7.522 0.2663E+00 carpholite-Fe 41 6.713 0.0000E+00 stilpnomelane-Fe 164 13.017 0.2077E-01 celadonite 42 5.342 0.0000E+00 stilpnomelane-Mg 165 27.441 0.0000E+00 celadonite-Fe 43 3.877 0.0000E+00 stishovite 166 2.720 0.0000E+00 chrysotile 44 23.892 0.0000E+00 sudoite-Fe 167 18.296 0.0000E+00 chondrodite 45 56.475 0.0000E+00 sudoite 168 21.077 0.0000E+00 clinochlore 46 39.070 0.5800E-01 sulfur 169 -9.152 0.0000E+00 daphnite 47 28.965 0.1679E-01 sylvite 170 1.338 0.0000E+00 chlorite-Mn 48 46.869 0.1387E-02 talc 171 16.491 0.0000E+00 chlorite-Al-free 49 47.173 0.0000E+00 talc-Fe 172 13.448 0.0000E+00 chloritoid-Mg 50 13.198 0.0000E+00 talc-tschermaks 173 19.091 0.0000E+00 chloritoid-Fe 51 9.174 0.0000E+00 tephroite 174 18.086 0.0000E+00 chloritoid-Mn 52 11.401 0.0000E+00 tilleyite 175 41.377 0.0000E+00 clinohumite 53 97.128 0.0000E+00 titanite-CaSi 176 15.479 0.0000E+00 coesite 54 -2.376 0.0000E+00 topaz-H 177 4.618 0.0000E+00 cordierite-H 55 23.715 0.0000E+00 tridymite 178 -2.626 0.0000E+00 cordierite 56 24.049 0.0000E+00 tremolite 179 47.869 0.0000E+00 cordierite-Fe 57 20.450 0.0000E+00 ferroactinolite 180 38.452 0.0000E+00 cordierite-Mn 58 25.066 0.0000E+00 troilite-low 181 -4.411 0.0000E+00 corundum 59 8.383 0.0000E+00 tschermakite 182 48.210 0.0000E+00 corundum-MgSi 60 18.891 0.0000E+00 vesuvianite 183 223.471 0.0000E+00 cristobalite 61 -2.560 0.0000E+00 wadeite-Si 184 20.216 0.0000E+00 cummingtonite 62 52.099 0.0000E+00 wadsleyite-Fe 185 15.680 0.0000E+00 cymrite-K 63 1.685 0.0000E+00 wadsleyite-Mg 186 25.850 0.0000E+00 deerite 64 95.671 0.0000E+00 wairakite 187 3.950 0.0000E+00 diaspore 65 2.874 0.0000E+00 walstromite 188 11.509 0.0000E+00 diamond 66 -3.102 0.0000E+00 wollastonite 189 10.461 0.0000E+00 diopside 67 16.181 0.1250E-01 pseudo-wollastonite 190 11.000 0.0000E+00 hedenbergite 68 14.208 0.3240E-02 zoisite 191 22.849 0.0000E+00 dolomite,ordered 69 0.546 0.0000E+00 akaganeite 192 7.755 0.0000E+00 eastonite 70 28.489 0.0000E+00 beidellite-Ca 193 -1.646 0.0000E+00 enstatite 71 17.265 0.0000E+00 beidellite-H 194 -2.326 0.0000E+00 clinoenstatite-HiP 72 18.354 0.0000E+00 beidellite-K 195 -1.520 0.0000E+00 clinoenstatite 73 17.166 0.0000E+00 beidellite-Mg 196 -1.790 0.0000E+00 protoenstatite 74 17.824 0.0000E+00 beidellite-Na 197 -1.342 0.0000E+00 epidote 75 24.670 0.0000E+00 calcium 198 84.026 0.0000E+00 clinozoisite 76 22.806 0.0000E+00 chalcedony 199 -2.802 0.0000E+00 epidote-Fe 77 29.841 0.0000E+00 dawsonite 200 1.682 0.0000E+00 fayalite 78 14.046 0.0000E+00 montmorillonite-Ca 201 -2.291 0.0000E+00 ferrosilite 79 11.149 0.0000E+00 montmorillonite-K 202 -2.237 0.0000E+00 forsterite 80 21.016 0.0000E+00 montmorillonite-Mg 203 -2.480 0.0000E+00 gedrite 81 50.522 0.0000E+00 montmorillonite-Na 204 -2.038 0.0000E+00 gehlenite 82 36.628 0.0000E+00 nontronite-Ca 205 3.215 0.0000E+00 gibbsite 83 4.079 0.0000E+00 nontronite-H 206 2.533 0.0000E+00 glaucophane 84 22.975 0.0000E+00 nontronite-K 207 3.341 0.0000E+00 glaucophane-Fe 85 17.276 0.0000E+00 nontronite-Mg 208 3.075 0.0000E+00 graphite 86 -3.546 0.0000E+00 nontronite-Na 209 3.520 0.0000E+00 greenalite 87 16.140 0.0000E+00 sepiolite 210 24.118 0.0000E+00 grunerite 88 31.215 0.0000E+00 alite 211 57.999 0.0000E+00 halite 89 1.575 0.0000E+00 belite 212 30.433 0.0000E+00 hematite 90 12.566 0.0000E+00 ettringite 213 43.232 0.0000E+00 heulandite 91 -5.827 0.0000E+00 gypsum 214 -4.955 0.0000E+00 hercynite 92 17.279 0.0000E+00 hemicarboaluminate 215 70.954 0.0000E+00 hollandite 93 25.673 0.0000E+00 hydrogarnet 216 60.662 0.0000E+00 iron 94 19.086 0.0000E+00 hydrogarnet-Si 217 50.586 0.0000E+00 jadeite 95 4.215 0.0000E+00 jennite 218 24.367 0.0000E+00 julgoldite 96 70.427 0.0000E+00 monosulfoaluminate 219 53.400 0.0000E+00 kalsilite 97 7.584 0.0000E+00 monocarboaluminate 220 61.898 0.0000E+00 kaolinite 98 -1.333 0.0000E+00 portlandite 221 18.272 0.0000E+00 kyanite 99 4.876 0.0000E+00 stratlingite 222 36.502 0.0000E+00 larnite-bredigite 100 30.686 0.0000E+00 tricarboaluminate 223 70.370 0.0000E+00 laumontite 101 2.883 0.0000E+00 tobermorite 224 9.823 0.0000E+00 lawsonite 102 9.616 0.0000E+00 C4AH13 225 81.816 0.0000E+00 leucite 103 4.119 0.0000E+00 C2AH8 226 45.203 0.0000E+00 lime 104 25.998 0.0000E+00 C3A 227 86.953 0.0000E+00 lizardite 105 23.244 0.0000E+00 C4AF 228 117.416 0.0000E+00 magnesite 106 0.691 0.0000E+00 CAH10 229 28.335 0.0000E+00 magnetite 107 20.087 0.0000E+00 alabandite 230 -0.978 0.0000E+00 minnesotaite 108 10.388 0.0000E+00 alunite 231 -10.435 0.0000E+00 minnesotaite-Mg 109 20.602 0.0000E+00 artinite 232 15.121 0.0000E+00 magnesioferrite 110 26.212 0.0000E+00 boehmite 233 4.406 0.0000E+00 majorite 111 53.251 0.0000E+00 dolomite,disordered 234 1.247 0.0000E+00 manganosite 112 14.058 0.0000E+00 ferrous-oxide 235 9.812 0.0000E+00 margarite 113 17.324 0.0000E+00 huntite 236 3.770 0.0000E+00 meionite 114 44.874 0.0000E+00 hydromagnesite 237 19.995 0.0000E+00 merwinite 115 55.930 0.0000E+00 nesquehonite 238 4.723 0.0000E+00 microcline 116 -2.486 0.7439E-01 potassium-oxide 239 69.038 0.0000E+00 monticellite 117 24.339 0.0000E+00 silica-amorphous 240 -2.091 0.0000E+00 mullite-Al 118 363.148 0.0000E+00 sodium-oxide 241 55.169 0.0000E+00 mullite-Si 119 7.264 0.0000E+00 an20ab80 242 2.018 0.0000E+00 muscovite 120 2.582 0.0000E+00 an25ab75 243 2.646 0.0000E+00 paragonite 121 4.239 0.0000E+00 an30ab70 244 3.279 0.0000E+00 nepheline 122 8.339 0.0000E+00 tr.625ac.25prg.125 245 45.165 0.4129E-02 osumilite(1) 123 21.717 0.0000E+00 246 0.000 0.0000E+00 Initial composition of reactant (wt%): SiO2 62.56 MgO 3.200 Al2O3 16.62 CaO 6.450 FeO 3.530 Na2O 3.890 Fe2O3 1.770 K2O 1.000 MnO 0.1230 P2O5 0.4200E-01 Sum of wt% of reactants: 99.1850 Reactant consumed: 399.9990000 g log = 2.6021 Original solution: 1000.0103000 g Original solution / Rock added: 2.50 (Water/Rock Ratio), log = 0.3979 The following minerals and/or gases with identical index are in solid solution: H2O,gas 6 CO2,gas 6 CH4,gas 6 H2,gas 6 H2S,gas 6 S2,gas 6 CO,gas 6 SO3,gas 6 SO2,gas 6 HCl,gas 6 almandine 16 pyrope 16 spessartine 16 andradite 8 grossular 8 annite 15 phlogopite 15 biotite-Mn 15 clinochlore 1 daphnite 1 chlorite-Mn 1 diopside 5 hedenbergite 5 epidote 3 clinozoisite 3 greenalite 18 iron 9 lizardite 18 magnetite 14 talc 7 talc-Fe 7 tremolite 2 ferroactinolite 2 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 13 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 399.9990000 Water: Moles liquid = 0.5319E+02 kg liquid = 0.9583E+00 Moles total = 0.5049E+02 kg total = 0.9097E+00 Activity = 1.0000 Stoichiometric ionic strength = .1132181E-01 Osmotic coef. = 0.9695 True ionic strength = .2001081E-01 Chg. balance for total moles = -.1586E-10 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.88260E-10 -10.0542 0.74162E-10 -10.1298 0.84027E+00 -0.0756 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.14332E-03 -3.8437 0.11970E-03 -3.9219 0.83522E+00 -0.0782 4 SO4-- 0.67450E-12 -12.1710 0.35031E-12 -12.4556 0.51936E+00 -0.2845 5 HCO3- 0.24963E-06 -6.6027 0.20880E-06 -6.6803 0.83644E+00 -0.0776 6 HS- 0.26609E-04 -4.5750 0.22228E-04 -4.6531 0.83534E+00 -0.0781 7 Al+++ 0.96842E-29 -29.0139 0.22379E-29 -29.6502 0.23108E+00 -0.6362 8 H4SiO4 0.69581E-03 -3.1575 0.69581E-03 -3.1575 0.10000E+01 0.0000 9 Ca++ 0.13491E-06 -6.8700 0.69551E-07 -7.1577 0.51555E+00 -0.2877 10 Mg++ 0.21106E-10 -10.6756 0.10831E-10 -10.9653 0.51319E+00 -0.2897 11 Fe++ 0.58161E-13 -13.2354 0.29880E-13 -13.5246 0.51375E+00 -0.2892 12 K+ 0.15645E-03 -3.8056 0.13090E-03 -3.8831 0.83664E+00 -0.0775 13 Na+ 0.19853E-01 -1.7022 0.16579E-01 -1.7804 0.83507E+00 -0.0783 14 Mn++ 0.18284E-10 -10.7379 0.94010E-11 -11.0268 0.51418E+00 -0.2889 15 HPO4-- 0.45330E-07 -7.3436 0.23546E-07 -7.6281 0.51943E+00 -0.2845 16 HSiO3- 0.10489E-01 -1.9793 0.87606E-02 -2.0575 0.83522E+00 -0.0782 17 Ca(HSiO3)+ 0.16582E-07 -7.7804 0.13876E-07 -7.8577 0.83682E+00 -0.0774 18 Mg(HSiO3)+ 0.32138E-11 -11.4930 0.26893E-11 -11.5704 0.83682E+00 -0.0774 19 NaHSiO3,aq 0.23491E-02 -2.6291 0.23491E-02 -2.6291 0.10000E+01 0.0000 20 AlO+ 0.66147E-16 -16.1795 0.55353E-16 -16.2569 0.83682E+00 -0.0774 22 HAlO2,aq 0.14864E-09 -9.8279 0.14864E-09 -9.8279 0.10000E+01 0.0000 23 AlO2- 0.53215E-05 -5.2740 0.44366E-05 -5.3530 0.83371E+00 -0.0790 24 CH4,aq 0.12914E-04 -4.8889 0.12870E-04 -4.8904 0.99655E+00 -0.0015 25 C2H6,aq 0.24518E-14 -14.6105 0.24433E-14 -14.6120 0.99655E+00 -0.0015 29 CO,aq 0.96329E-17 -17.0162 0.96329E-17 -17.0162 0.10000E+01 0.0000 30 CO2,aq 0.33203E-10 -10.4788 0.33088E-10 -10.4803 0.99655E+00 -0.0015 31 CO3-2 0.47451E-06 -6.3238 0.24592E-06 -6.6092 0.51826E+00 -0.2855 32 CaCO3,aq 0.21446E-09 -9.6686 0.21446E-09 -9.6686 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.44298E-12 -12.3536 0.37070E-12 -12.4310 0.83682E+00 -0.0774 34 CaCl+ 0.16101E-10 -10.7932 0.13473E-10 -10.8705 0.83682E+00 -0.0774 35 CaCl2,aq 0.38317E-15 -15.4166 0.38317E-15 -15.4166 0.10000E+01 0.0000 36 CaOH+ 0.79871E-07 -7.0976 0.66838E-07 -7.1750 0.83682E+00 -0.0774 37 CaSO4,aq 0.77367E-17 -17.1114 0.77367E-17 -17.1114 0.10000E+01 0.0000 38 HCl,aq 0.16268E-14 -14.7887 0.16268E-14 -14.7887 0.10000E+01 0.0000 43 FeCl+ 0.67655E-17 -17.1697 0.56615E-17 -17.2471 0.83682E+00 -0.0774 46 FeO,aq 0.21115E-09 -9.6754 0.21115E-09 -9.6754 0.10000E+01 0.0000 47 FeOH+ 0.15672E-10 -10.8049 0.13115E-10 -10.8822 0.83682E+00 -0.0774 48 HFeO2- 0.35666E-07 -7.4477 0.29789E-07 -7.5259 0.83522E+00 -0.0782 49 FeO+ 0.10981E-16 -16.9594 0.91890E-17 -17.0367 0.83682E+00 -0.0774 51 FeO2- 0.40931E-09 -9.3880 0.34186E-09 -9.4662 0.83522E+00 -0.0782 52 HFeO2,aq 0.32245E-11 -11.4915 0.32245E-11 -11.4915 0.10000E+01 0.0000 53 H2,aq 0.11629E-04 -4.9344 0.11589E-04 -4.9360 0.99655E+00 -0.0015 54 KCl,aq 0.28399E-09 -9.5467 0.28399E-09 -9.5467 0.10000E+01 0.0000 56 KOH,aq 0.75375E-06 -6.1228 0.75375E-06 -6.1228 0.10000E+01 0.0000 57 KSO4- 0.85192E-15 -15.0696 0.71154E-15 -15.1478 0.83522E+00 -0.0782 58 MgCO3,aq 0.83716E-14 -14.0772 0.83716E-14 -14.0772 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.70491E-16 -16.1519 0.58988E-16 -16.2292 0.83682E+00 -0.0774 60 MgCl+ 0.22725E-14 -14.6435 0.19017E-14 -14.7209 0.83682E+00 -0.0774 61 MgOH+ 0.68828E-10 -10.1622 0.57597E-10 -10.2396 0.83682E+00 -0.0774 63 MnO,aq 0.17701E-08 -8.7520 0.17701E-08 -8.7520 0.10000E+01 0.0000 64 MnOH+ 0.45806E-09 -9.3391 0.38331E-09 -9.4164 0.83682E+00 -0.0774 65 MnO2-2 0.20609E-10 -10.6859 0.10681E-10 -10.9714 0.51826E+00 -0.2855 66 HMnO2- 0.20778E-09 -9.6824 0.17354E-09 -9.7606 0.83522E+00 -0.0782 69 MnCl+ 0.82811E-14 -14.0819 0.69298E-14 -14.1593 0.83682E+00 -0.0774 71 NaCl,aq 0.65769E-06 -6.1820 0.65769E-06 -6.1820 0.10000E+01 0.0000 72 NaOH,aq 0.96047E-04 -4.0175 0.96047E-04 -4.0175 0.10000E+01 0.0000 74 OH- 0.93446E-02 -2.0294 0.77907E-02 -2.1084 0.83371E+00 -0.0790 79 HPO3-2 0.16408E-14 -14.7849 0.85037E-15 -15.0704 0.51826E+00 -0.2855 81 H2PO3- 0.15141E-18 -18.8198 0.12646E-18 -18.8980 0.83522E+00 -0.0782 82 H3PO4,aq 0.90573E-18 -18.0430 0.90573E-18 -18.0430 0.10000E+01 0.0000 83 H2PO4- 0.38531E-10 -10.4142 0.32213E-10 -10.4920 0.83601E+00 -0.0778 84 PO4-3 0.10673E-08 -8.9717 0.25904E-09 -9.5866 0.24270E+00 -0.6149 88 HP2O7-3 0.94704E-18 -18.0236 0.21906E-18 -18.6594 0.23131E+00 -0.6358 89 P2O7-4 0.91480E-17 -17.0387 0.70566E-18 -18.1514 0.77138E-01 -1.1127 90 H2S,aq 0.51124E-08 -8.2914 0.50948E-08 -8.2929 0.99655E+00 -0.0015 91 S2-2 0.18228E-14 -14.7393 0.94466E-15 -15.0247 0.51826E+00 -0.2855 97 SO3-2 0.10034E-17 -17.9985 0.52756E-18 -18.2777 0.52575E+00 -0.2792 99 HSO4- 0.29890E-19 -19.5245 0.25037E-19 -19.6014 0.83763E+00 -0.0769 Charge balance for all species = -.1655E-10 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.8825994E-10 -.2230433E-01 -.2244237E+02 0.0000 2 H2O 0.1000000E+01 0.5550489E+02 0.9982000E+06 0.0000 3 Cl- 0.1433206E-03 0.1439786E-03 0.5095606E+01 6.2079 4 SO4-- 0.6744989E-12 -.1582165E-04 -.1517213E+01 7.8041 5 HCO3- 0.2496310E-06 0.1363879E-04 0.8307548E+00 3.4496 6 HS- 0.2660927E-04 0.4243604E-04 0.1401007E+01 5.4767 7 Al+++ 0.9684162E-29 0.5321631E-05 0.1433361E+00 0.7393 8 H4SiO4 0.6958118E-03 0.1353393E-01 0.1298559E+04 -3.1575 9 Ca++ 0.1349067E-06 0.2315911E-06 0.9265583E-02 13.1019 10 Mg++ 0.2110565E-10 0.9315830E-10 0.2260930E-05 9.2943 11 Fe++ 0.5816086E-13 0.3630590E-07 0.2024053E-02 6.7350 12 K+ 0.1564549E-03 0.1572090E-03 0.6136506E+01 6.2467 13 Na+ 0.1985333E-01 0.2229912E-01 0.5117616E+03 8.3494 14 Mn++ 0.1828355E-10 0.2474850E-08 0.1357271E-03 9.2328 15 HPO4-- 0.4532968E-07 0.4643552E-07 0.4449092E-02 12.6315 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.6623377E+01 -.2137415E-01 -.6602002E+01 0.0000000E+00 2 H2O 0.5049410E+02 0.5319013E+02 -.2696033E+01 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.1111084E-01 -.1516183E-04 0.1112600E-01 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.1108534E-01 0.4066630E-04 -.1112600E-01 0.0000000E+00 7 Al+++ 0.1304293E+01 0.5099700E-05 0.1304288E+01 0.0000000E+00 8 H4SiO4 0.4165103E+01 0.1296951E-01 0.4152133E+01 0.0000000E+00 9 Ca++ 0.4600704E+00 0.2219329E-06 0.4600702E+00 0.0000000E+00 10 Mg++ 0.3174595E+00 0.8927326E-10 0.3174595E+00 0.0000000E+00 11 Fe++ 0.2852027E+00 0.3479181E-07 0.2852027E+00 0.0000000E+00 12 K+ 0.8492548E-01 0.1506528E-03 0.8477482E-01 0.0000000E+00 13 Na+ 0.5022563E+00 0.2136916E-01 0.4808871E+00 0.0000000E+00 14 Mn++ 0.6935421E-02 0.2371639E-08 0.6935419E-02 0.0000000E+00 15 HPO4-- 0.2367025E-02 0.4449899E-07 0.2366980E-02 0.0000000E+00 Chg. balance for solid moles: -.9584E-15 Mass of aqueous solution: 0.959964E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 399.9990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 0.4804 -0.318 126.0 2.100 28.84 48.35 andradite 0.4450E-01 -1.352 22.62 1.354 5.178 5.876 grossular 0.1079E-01 -1.967 4.859 0.687 1.112 1.352 apatite-OH 0.7890E-03 -3.103 0.3963 -0.402 0.9073E-01 0.1259 clinochlore 0.5800E-01 -1.237 32.24 1.508 7.380 12.26 daphnite 0.1679E-01 -1.775 11.98 1.078 2.742 3.630 chlorite-Mn 0.1387E-02 -2.858 0.9834 -0.007 0.2251 0.3134 diopside 0.1250E-01 -1.903 2.706 0.432 0.6196 0.8271 hedenbergite 0.3240E-02 -2.489 0.8039 -0.095 0.1840 0.2202 microcline 0.7439E-01 -1.128 20.71 1.316 4.740 8.088 stilbite 0.2663 -0.575 187.6 2.273 42.96 87.52 stilpnomelane-Fe 0.2077E-01 -1.683 22.39 1.350 5.126 7.734 tr.625ac.25prg.125 0.4129E-02 -2.384 3.530 0.548 0.8081 1.136 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8049E+00 0.8049E+00 1.0000 -0.094 grossular 0.1951E+00 0.1951E+00 1.0000 -0.710 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.7614E+00 0.7614E+00 1.0000 -0.118 daphnite 0.2204E+00 0.2204E+00 1.0000 -0.657 chlorite-Mn 0.1821E-01 0.1821E-01 1.0000 -1.740 diopside 0.7941E+00 0.7941E+00 1.0000 -0.100 hedenbergite 0.2059E+00 0.2059E+00 1.0000 -0.686 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 tr.625ac.25prg.125 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 436.807392 g Volume = 177.436910 cm3 Porosity: -10.2095% V(tot) - V(min): -.16437E+02 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 399.9990000 g log = 2.6021 Original solution: 1000.0103000 g Original solution / Rock added: 2.50 (Water/Rock Ratio), log = 0.3979 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0547 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9678E+00 0.9855 0.1006E+01 0.1021E+01 CO2,gas 0.3333E-08 1.0069 0.3540E-08 0.3516E-08 CH4,gas 0.1774E-01 1.0125 0.1894E-01 0.1871E-01 H2,gas 0.1442E-01 1.0006 0.1522E-01 0.1521E-01 H2S,gas 0.1333E-06 0.9959 0.1401E-06 0.1406E-06 S2,gas 0.3015E-29 1.0000 0.3180E-29 0.3180E-29 CO,gas 0.1361E-13 1.0000 0.1435E-13 0.1435E-13 SO3,gas 0.6907E-48 1.0000 0.7285E-48 0.7285E-48 SO2,gas 0.4089E-27 1.0000 0.4312E-27 0.4312E-27 HCl,gas 0.2722E-17 1.0000 0.2870E-17 0.2870E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 16 albite -0.38 -0.38 0.00 0.000 -0.94784E-12 22 andradite 39.01 39.01 0.00 0.000 -0.12132E-10 23 grossular 32.73 32.73 0.00 0.000 -0.36397E-10 32 apatite-OH -18.15 -18.15 0.00 0.000 0.00000E+00 46 clinochlore 39.07 39.07 0.00 0.000 -0.12132E-10 47 daphnite 28.97 28.97 0.00 0.000 0.18198E-10 48 chlorite-Mn 46.87 46.87 0.00 0.000 -0.36397E-10 67 diopside 16.18 16.18 0.00 0.000 0.60662E-11 68 hedenbergite 14.21 14.21 0.00 0.000 0.30331E-11 116 microcline -2.49 -2.49 0.00 0.000 0.15165E-11 163 stilbite -7.52 -7.52 0.00 0.000 -0.90992E-11 164 stilpnomelane-Fe 13.02 13.02 0.00 0.000 0.21232E-10 245 tr.625ac.25prg.125 45.16 45.16 0.00 0.000 0.12132E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -16.81 -10.15 -3.383 0.17331E+05 -8.451 3 CH4,gas 4.54 1.12 -3.42 -0.855 0.58421E+04 -1.723 4 H2,gas 8.00 4.48 -3.52 -2.010 0.60047E+04 -1.818 5 H2S,gas -6.23 -14.78 -8.55 -4.276 0.14603E+05 -6.854 6 S2,gas -7.34 -38.53 -31.20 -4.799 0.53267E+05 -29.498 7 CO,gas 3.21 -12.33 -15.54 -4.782 0.26537E+05 -13.843 8 SO3,gas 17.12 -32.72 -49.84 -12.459 0.85095E+05 -48.138 9 SO2,gas 0.83 -28.23 -29.06 -7.750 0.49626E+05 -27.365 10 HCl,gas 5.19 -14.05 -19.24 -9.621 0.32854E+05 -17.542 11 acmite 7.71 6.53 -1.18 -0.123 0.20180E+04 15 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 19 spessartine 24.46 19.70 -4.75 -0.238 0.81154E+04 20 analcite 3.32 2.77 -0.55 -0.061 0.93607E+03 26 annite 20.12 17.72 -2.40 -0.134 0.41062E+04 27 phlogopite 27.06 25.40 -1.67 -0.093 0.28483E+04 29 anorthite 12.71 8.27 -4.44 -0.342 0.75894E+04 35 aragonite 0.97 -3.71 -4.67 -1.558 0.79819E+04 36 brucite 12.57 9.29 -3.27 -0.655 0.55907E+04 37 calcite 0.81 -3.71 -4.52 -1.507 0.77176E+04 38 carnegieite-low 9.02 5.93 -3.09 -0.442 0.52798E+04 39 carnegieite-high 10.09 5.93 -4.16 -0.595 0.71068E+04 40 carpholite-Mg 8.58 4.46 -4.12 -0.275 0.70420E+04 41 carpholite-Fe 6.71 1.90 -4.81 -0.321 0.82199E+04 42 celadonite 5.34 3.65 -1.69 -0.099 0.28878E+04 43 celadonite-Fe 3.88 1.09 -2.79 -0.164 0.47562E+04 44 chrysotile 23.89 21.57 -2.32 -0.194 0.39690E+04 49 chlorite-Al-free 47.17 43.14 -4.04 -0.168 0.68931E+04 51 chloritoid-Fe 9.17 5.06 -4.12 -0.275 0.70306E+04 52 chloritoid-Mn 11.40 7.55 -3.85 -0.256 0.65690E+04 54 coesite -2.38 -3.16 -0.78 -0.260 0.13343E+04 61 cristobalite -2.56 -3.16 -0.60 -0.199 0.10197E+04 63 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71234E+04 65 diaspore 2.87 0.74 -2.13 -0.356 0.36445E+04 66 diamond -3.10 -7.84 -4.74 -1.355 0.80961E+04 71 enstatite 17.26 12.27 -4.99 -0.499 0.85225E+04 73 clinoenstatite 17.17 12.27 -4.89 -0.489 0.83541E+04 75 epidote 24.67 22.70 -1.97 -0.095 0.33578E+04 76 clinozoisite 22.81 18.95 -3.86 -0.175 0.65854E+04 77 epidote-Fe 29.84 26.46 -3.38 -0.176 0.57767E+04 78 fayalite 14.05 10.31 -3.73 -0.533 0.63743E+04 79 ferrosilite 11.15 7.16 -3.99 -0.399 0.68204E+04 83 gibbsite 4.08 0.74 -3.34 -0.477 0.57030E+04 84 glaucophane 22.97 20.80 -2.17 -0.059 0.37131E+04 85 glaucophane-Fe 17.28 13.12 -4.15 -0.112 0.70920E+04 86 graphite -3.55 -7.84 -4.30 -1.228 0.73383E+04 87 greenalite 16.14 13.89 -2.25 -0.187 0.38409E+04 90 hematite 12.57 8.99 -3.58 -0.434 0.61114E+04 91 heulandite -5.83 -7.52 -1.69 -0.077 0.28938E+04 95 jadeite 4.22 2.77 -1.44 -0.144 0.24616E+04 97 kalsilite 7.58 3.83 -3.76 -0.536 0.64122E+04 98 kaolinite -1.33 -4.84 -3.50 -0.319 0.59824E+04 101 laumontite 2.88 1.95 -0.93 -0.062 0.15930E+04 102 lawsonite 9.62 8.27 -1.35 -0.090 0.23061E+04 103 leucite 4.12 0.67 -3.45 -0.345 0.58871E+04 105 lizardite 23.24 21.57 -1.68 -0.140 0.28616E+04 107 magnetite 20.09 15.72 -4.37 -0.356 0.74538E+04 108 minnesotaite 10.39 7.58 -2.81 -0.165 0.48033E+04 112 manganosite 14.06 9.23 -4.83 -1.206 0.82391E+04 120 muscovite 2.58 -1.01 -3.59 -0.211 0.61304E+04 121 paragonite 4.24 1.09 -3.14 -0.185 0.53695E+04 122 nepheline 8.34 5.93 -2.41 -0.344 0.41121E+04 128 periclase-Fe 11.63 6.74 -4.89 -1.223 0.83522E+04 134 phlogopite-Na 29.65 27.50 -2.15 -0.119 0.36671E+04 136 prehnite 19.37 18.21 -1.16 -0.068 0.19840E+04 137 prehnite-Fe 22.50 21.96 -0.53 -0.032 0.91136E+03 138 pumpellyite-Fe 46.27 43.89 -2.38 -0.053 0.40557E+04 139 pumpellyite-Mg 48.99 46.45 -2.54 -0.056 0.43395E+04 143 pyrrhotite -4.26 -8.05 -3.79 -1.263 0.64672E+04 144 pyrrhotiteFe0.875 -6.02 -9.45 -3.43 -1.261 0.58545E+04 145 pyroxmangite 7.40 6.08 -1.32 -0.265 0.22596E+04 146 pyrophyllite -6.18 -11.15 -4.98 -0.311 0.84958E+04 147 quartz -2.99 -3.16 -0.17 -0.056 0.28698E+03 152 rhodonite 7.45 6.08 -1.37 -0.274 0.23399E+04 153 sanidine -1.28 -2.49 -1.21 -0.093 0.20677E+04 165 stilpnomelane-Mg 27.44 25.81 -1.63 -0.049 0.27797E+04 171 talc 16.49 15.25 -1.24 -0.073 0.21141E+04 174 tephroite 18.09 15.31 -2.78 -0.397 0.47428E+04 178 tridymite -2.63 -3.16 -0.53 -0.177 0.90696E+03 179 tremolite 47.87 47.42 -0.45 -0.012 0.77500E+03 180 ferroactinolite 38.45 34.62 -3.83 -0.104 0.65455E+04 181 troilite-low -4.41 -8.05 -3.64 -1.212 0.62100E+04 183 vesuvianite 223.47 218.82 -4.65 -0.035 0.79373E+04 187 wairakite 3.95 1.95 -2.00 -0.118 0.34149E+04 188 walstromite 11.51 9.94 -1.56 -0.313 0.26719E+04 189 wollastonite 10.46 9.94 -0.52 -0.103 0.88228E+03 190 pseudo-wollastonite 11.00 9.94 -1.06 -0.211 0.18021E+04 191 zoisite 22.85 18.95 -3.90 -0.177 0.66595E+04 192 akaganeite 7.75 4.49 -3.26 -0.705 0.55682E+04 199 chalcedony -2.80 -3.16 -0.36 -0.118 0.60628E+03 201 montmorillonite-Ca -2.29 -6.17 -3.88 -0.240 0.66178E+04 202 montmorillonite-K -2.24 -6.27 -4.03 -0.247 0.68814E+04 203 montmorillonite-Mg -2.48 -6.79 -4.31 -0.267 0.73675E+04 204 montmorillonite-Na -2.04 -5.57 -3.54 -0.216 0.60363E+04 205 nontronite-Ca 3.21 -0.20 -3.41 -0.221 0.58222E+04 206 nontronite-H 2.53 -2.36 -4.89 -0.328 0.83492E+04 207 nontronite-K 3.34 -0.30 -3.64 -0.233 0.62090E+04 208 nontronite-Mg 3.07 -0.82 -3.90 -0.253 0.66560E+04 209 nontronite-Na 3.52 0.40 -3.12 -0.200 0.53299E+04 224 tobermorite 9.82 7.76 -2.07 -0.564 0.35287E+04 230 alabandite -0.98 -5.55 -4.57 -1.524 0.78070E+04 233 boehmite 4.41 0.74 -3.67 -0.611 0.62614E+04 235 ferrous-oxide 9.81 6.74 -3.08 -0.769 0.52531E+04 240 silica-amorphous -2.09 -3.16 -1.07 -0.355 0.18205E+04 242 an20ab80 2.02 1.35 -0.67 -0.052 0.11470E+04 243 an25ab75 2.65 1.78 -0.87 -0.067 0.14808E+04 244 an30ab70 3.28 2.21 -1.07 -0.082 0.18241E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 20.0000000 g Current total amount of reactant added: 399.9990000 g New total amount of reactant added: 419.9990000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.1586E-10 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 11 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 419.9990000 Water: Moles liquid = 0.5308E+02 kg liquid = 0.9563E+00 Moles total = 0.5024E+02 kg total = 0.9052E+00 Activity = 1.0000 Stoichiometric ionic strength = .1132211E-01 Osmotic coef. = 0.9695 True ionic strength = .2001107E-01 Chg. balance for total moles = -.1586E-10 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.88261E-10 -10.0542 0.74163E-10 -10.1298 0.84027E+00 -0.0756 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.14362E-03 -3.8428 0.11996E-03 -3.9210 0.83522E+00 -0.0782 4 SO4-- 0.67599E-12 -12.1701 0.35108E-12 -12.4546 0.51936E+00 -0.2845 5 HCO3- 0.25018E-06 -6.6017 0.20926E-06 -6.6793 0.83644E+00 -0.0776 6 HS- 0.26665E-04 -4.5741 0.22275E-04 -4.6522 0.83534E+00 -0.0781 7 Al+++ 0.96842E-29 -29.0139 0.22379E-29 -29.6502 0.23108E+00 -0.6362 8 H4SiO4 0.69582E-03 -3.1575 0.69582E-03 -3.1575 0.10000E+01 0.0000 9 Ca++ 0.13491E-06 -6.8700 0.69552E-07 -7.1577 0.51555E+00 -0.2877 10 Mg++ 0.21106E-10 -10.6756 0.10831E-10 -10.9653 0.51319E+00 -0.2897 11 Fe++ 0.58162E-13 -13.2354 0.29881E-13 -13.5246 0.51375E+00 -0.2892 12 K+ 0.15646E-03 -3.8056 0.13090E-03 -3.8831 0.83664E+00 -0.0775 13 Na+ 0.19854E-01 -1.7022 0.16579E-01 -1.7804 0.83507E+00 -0.0783 14 Mn++ 0.18303E-10 -10.7375 0.94109E-11 -11.0264 0.51418E+00 -0.2889 15 HPO4-- 0.45330E-07 -7.3436 0.23546E-07 -7.6281 0.51943E+00 -0.2845 16 HSiO3- 0.10489E-01 -1.9793 0.87606E-02 -2.0575 0.83522E+00 -0.0782 17 Ca(HSiO3)+ 0.16582E-07 -7.7804 0.13876E-07 -7.8577 0.83682E+00 -0.0774 18 Mg(HSiO3)+ 0.32138E-11 -11.4930 0.26894E-11 -11.5703 0.83682E+00 -0.0774 19 NaHSiO3,aq 0.23491E-02 -2.6291 0.23491E-02 -2.6291 0.10000E+01 0.0000 20 AlO+ 0.66146E-16 -16.1795 0.55352E-16 -16.2569 0.83682E+00 -0.0774 22 HAlO2,aq 0.14863E-09 -9.8279 0.14863E-09 -9.8279 0.10000E+01 0.0000 23 AlO2- 0.53212E-05 -5.2740 0.44364E-05 -5.3530 0.83371E+00 -0.0790 24 CH4,aq 0.12941E-04 -4.8880 0.12897E-04 -4.8895 0.99655E+00 -0.0015 25 C2H6,aq 0.24621E-14 -14.6087 0.24536E-14 -14.6102 0.99655E+00 -0.0015 29 CO,aq 0.96539E-17 -17.0153 0.96539E-17 -17.0153 0.10000E+01 0.0000 30 CO2,aq 0.33276E-10 -10.4779 0.33161E-10 -10.4794 0.99655E+00 -0.0015 31 CO3-2 0.47555E-06 -6.3228 0.24646E-06 -6.6083 0.51825E+00 -0.2855 32 CaCO3,aq 0.21494E-09 -9.6677 0.21494E-09 -9.6677 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.44396E-12 -12.3527 0.37152E-12 -12.4300 0.83682E+00 -0.0774 34 CaCl+ 0.16135E-10 -10.7922 0.13502E-10 -10.8696 0.83682E+00 -0.0774 35 CaCl2,aq 0.38478E-15 -15.4148 0.38478E-15 -15.4148 0.10000E+01 0.0000 36 CaOH+ 0.79871E-07 -7.0976 0.66838E-07 -7.1750 0.83682E+00 -0.0774 37 CaSO4,aq 0.77539E-17 -17.1105 0.77539E-17 -17.1105 0.10000E+01 0.0000 38 HCl,aq 0.16302E-14 -14.7878 0.16302E-14 -14.7878 0.10000E+01 0.0000 43 FeCl+ 0.67798E-17 -17.1688 0.56735E-17 -17.2462 0.83682E+00 -0.0774 46 FeO,aq 0.21114E-09 -9.6754 0.21114E-09 -9.6754 0.10000E+01 0.0000 47 FeOH+ 0.15672E-10 -10.8049 0.13115E-10 -10.8822 0.83682E+00 -0.0774 48 HFeO2- 0.35666E-07 -7.4477 0.29789E-07 -7.5259 0.83522E+00 -0.0782 49 FeO+ 0.10981E-16 -16.9594 0.91892E-17 -17.0367 0.83682E+00 -0.0774 51 FeO2- 0.40931E-09 -9.3880 0.34186E-09 -9.4662 0.83522E+00 -0.0782 52 HFeO2,aq 0.32246E-11 -11.4915 0.32246E-11 -11.4915 0.10000E+01 0.0000 53 H2,aq 0.11629E-04 -4.9345 0.11589E-04 -4.9360 0.99655E+00 -0.0015 54 KCl,aq 0.28459E-09 -9.5458 0.28459E-09 -9.5458 0.10000E+01 0.0000 56 KOH,aq 0.75375E-06 -6.1228 0.75375E-06 -6.1228 0.10000E+01 0.0000 57 KSO4- 0.85381E-15 -15.0686 0.71312E-15 -15.1468 0.83522E+00 -0.0782 58 MgCO3,aq 0.83900E-14 -14.0762 0.83900E-14 -14.0762 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.70647E-16 -16.1509 0.59119E-16 -16.2283 0.83682E+00 -0.0774 60 MgCl+ 0.22773E-14 -14.6426 0.19057E-14 -14.7199 0.83682E+00 -0.0774 61 MgOH+ 0.68828E-10 -10.1622 0.57597E-10 -10.2396 0.83682E+00 -0.0774 63 MnO,aq 0.17719E-08 -8.7516 0.17719E-08 -8.7516 0.10000E+01 0.0000 64 MnOH+ 0.45854E-09 -9.3386 0.38372E-09 -9.4160 0.83682E+00 -0.0774 65 MnO2-2 0.20630E-10 -10.6855 0.10692E-10 -10.9710 0.51825E+00 -0.2855 66 HMnO2- 0.20799E-09 -9.6820 0.17372E-09 -9.7602 0.83522E+00 -0.0782 69 MnCl+ 0.83073E-14 -14.0805 0.69517E-14 -14.1579 0.83682E+00 -0.0774 71 NaCl,aq 0.65908E-06 -6.1811 0.65908E-06 -6.1811 0.10000E+01 0.0000 72 NaOH,aq 0.96047E-04 -4.0175 0.96047E-04 -4.0175 0.10000E+01 0.0000 74 OH- 0.93444E-02 -2.0294 0.77906E-02 -2.1084 0.83371E+00 -0.0790 79 HPO3-2 0.16408E-14 -14.7850 0.85034E-15 -15.0704 0.51825E+00 -0.2855 81 H2PO3- 0.15141E-18 -18.8198 0.12646E-18 -18.8980 0.83522E+00 -0.0782 82 H3PO4,aq 0.90575E-18 -18.0430 0.90575E-18 -18.0430 0.10000E+01 0.0000 83 H2PO4- 0.38532E-10 -10.4142 0.32213E-10 -10.4920 0.83601E+00 -0.0778 84 PO4-3 0.10673E-08 -8.9717 0.25903E-09 -9.5866 0.24270E+00 -0.6149 88 HP2O7-3 0.94705E-18 -18.0236 0.21906E-18 -18.6594 0.23131E+00 -0.6358 89 P2O7-4 0.91481E-17 -17.0387 0.70566E-18 -18.1514 0.77137E-01 -1.1127 90 H2S,aq 0.51232E-08 -8.2905 0.51055E-08 -8.2920 0.99655E+00 -0.0015 91 S2-2 0.18305E-14 -14.7374 0.94866E-15 -15.0229 0.51825E+00 -0.2855 97 SO3-2 0.10056E-17 -17.9976 0.52871E-18 -18.2768 0.52575E+00 -0.2792 99 HSO4- 0.29956E-19 -19.5235 0.25092E-19 -19.6005 0.83763E+00 -0.0769 Charge balance for all species = -.1659E-10 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.8826110E-10 -.2230426E-01 -.2244229E+02 0.0000 2 H2O 0.1000000E+01 0.5550489E+02 0.9982000E+06 0.0000 3 Cl- 0.1436216E-03 0.1442810E-03 0.5106308E+01 6.2088 4 SO4-- 0.6759866E-12 -.1584863E-04 -.1519800E+01 7.8050 5 HCO3- 0.2501798E-06 0.1366743E-04 0.8324997E+00 3.4505 6 HS- 0.2666516E-04 0.4251892E-04 0.1403743E+01 5.4776 7 Al+++ 0.9684242E-29 0.5321376E-05 0.1433293E+00 0.7393 8 H4SiO4 0.6958203E-03 0.1353397E-01 0.1298563E+04 -3.1575 9 Ca++ 0.1349088E-06 0.2315940E-06 0.9265698E-02 13.1019 10 Mg++ 0.2110595E-10 0.9315851E-10 0.2260935E-05 9.2943 11 Fe++ 0.5816221E-13 0.3630532E-07 0.2024021E-02 6.7350 12 K+ 0.1564570E-03 0.1572110E-03 0.6136585E+01 6.2467 13 Na+ 0.1985359E-01 0.2229940E-01 0.5117682E+03 8.3494 14 Mn++ 0.1830299E-10 0.2477414E-08 0.1358677E-03 9.2333 15 HPO4-- 0.4532967E-07 0.4643550E-07 0.4449089E-02 12.6315 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.6954547E+01 -.2132929E-01 -.6933218E+01 0.0000000E+00 2 H2O 0.5024339E+02 0.5307865E+02 -.2835257E+01 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.1166511E-01 -.1515585E-04 0.1168026E-01 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.1163960E-01 0.4066032E-04 -.1168026E-01 0.0000000E+00 7 Al+++ 0.1369508E+01 0.5088767E-05 0.1369503E+01 0.0000000E+00 8 H4SiO4 0.4373358E+01 0.1294237E-01 0.4360416E+01 0.0000000E+00 9 Ca++ 0.4830732E+00 0.2214705E-06 0.4830730E+00 0.0000000E+00 10 Mg++ 0.3333325E+00 0.8908635E-10 0.3333325E+00 0.0000000E+00 11 Fe++ 0.2994629E+00 0.3471833E-07 0.2994629E+00 0.0000000E+00 12 K+ 0.8917176E-01 0.1503390E-03 0.8902142E-01 0.0000000E+00 13 Na+ 0.5273611E+00 0.2132465E-01 0.5060365E+00 0.0000000E+00 14 Mn++ 0.7282193E-02 0.2369121E-08 0.7282191E-02 0.0000000E+00 15 HPO4-- 0.2485376E-02 0.4440570E-07 0.2485332E-02 0.0000000E+00 Chg. balance for solid moles: 0.6098E-15 Mass of aqueous solution: 0.957952E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 419.9990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 0.5055 -0.296 132.6 2.122 28.90 50.88 andradite 0.4672E-01 -1.330 23.74 1.376 5.177 6.169 grossular 0.1132E-01 -1.946 5.100 0.708 1.112 1.419 apatite-OH 0.8284E-03 -3.082 0.4161 -0.381 0.9073E-01 0.1322 clinochlore 0.6083E-01 -1.216 33.81 1.529 7.372 12.86 daphnite 0.1761E-01 -1.754 12.56 1.099 2.739 3.807 chlorite-Mn 0.1456E-02 -2.837 1.033 0.014 0.2251 0.3291 diopside 0.1358E-01 -1.867 2.942 0.469 0.6414 0.8991 hedenbergite 0.3522E-02 -2.453 0.8739 -0.059 0.1905 0.2394 microcline 0.7811E-01 -1.107 21.74 1.337 4.740 8.493 stilbite 0.2791 -0.554 196.7 2.294 42.88 91.74 stilpnomelane-Fe 0.2182E-01 -1.661 23.52 1.371 5.128 8.124 tr.625ac.25prg.125 0.4296E-02 -2.367 3.672 0.565 0.8006 1.182 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8049E+00 0.8049E+00 1.0000 -0.094 grossular 0.1951E+00 0.1951E+00 1.0000 -0.710 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.7614E+00 0.7614E+00 1.0000 -0.118 daphnite 0.2204E+00 0.2204E+00 1.0000 -0.657 chlorite-Mn 0.1823E-01 0.1823E-01 1.0000 -1.739 diopside 0.7941E+00 0.7941E+00 1.0000 -0.100 hedenbergite 0.2059E+00 0.2059E+00 1.0000 -0.686 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 tr.625ac.25prg.125 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 458.657518 g Volume = 186.277522 cm3 Porosity: -10.2236% V(tot) - V(min): -.17278E+02 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 419.9990000 g log = 2.6232 Original solution: 1000.0103000 g Original solution / Rock added: 2.38 (Water/Rock Ratio), log = 0.3768 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0547 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9678E+00 0.9855 0.1006E+01 0.1021E+01 CO2,gas 0.3341E-08 1.0069 0.3548E-08 0.3523E-08 CH4,gas 0.1778E-01 1.0125 0.1898E-01 0.1875E-01 H2,gas 0.1442E-01 1.0006 0.1521E-01 0.1521E-01 H2S,gas 0.1336E-06 0.9959 0.1403E-06 0.1409E-06 S2,gas 0.3028E-29 1.0000 0.3194E-29 0.3194E-29 CO,gas 0.1364E-13 1.0000 0.1439E-13 0.1439E-13 SO3,gas 0.6922E-48 1.0000 0.7301E-48 0.7301E-48 SO2,gas 0.4097E-27 1.0000 0.4322E-27 0.4322E-27 HCl,gas 0.2727E-17 1.0000 0.2877E-17 0.2877E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 16 albite -0.38 -0.38 0.00 0.000 0.23317E-10 22 andradite 39.01 39.01 0.00 0.000 0.00000E+00 23 grossular 32.73 32.73 0.00 0.000 0.36397E-10 32 apatite-OH -18.15 -18.15 0.00 0.000 0.24265E-10 46 clinochlore 39.07 39.07 0.00 0.000 0.60662E-10 47 daphnite 28.97 28.97 0.00 0.000 0.36397E-10 48 chlorite-Mn 46.87 46.87 0.00 0.000 0.72794E-10 67 diopside 16.18 16.18 0.00 0.000 0.60662E-11 68 hedenbergite 14.21 14.21 0.00 0.000 0.60662E-11 116 microcline -2.49 -2.49 0.00 0.000 0.13649E-10 163 stilbite -7.52 -7.52 0.00 0.000 0.15165E-10 164 stilpnomelane-Fe 13.02 13.02 0.00 0.000 0.21232E-10 245 tr.625ac.25prg.125 45.16 45.16 0.00 0.000 0.60662E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -16.81 -10.15 -3.383 0.17329E+05 -8.450 3 CH4,gas 4.54 1.12 -3.42 -0.855 0.58406E+04 -1.722 4 H2,gas 8.00 4.48 -3.52 -2.010 0.60047E+04 -1.818 5 H2S,gas -6.23 -14.78 -8.55 -4.276 0.14602E+05 -6.853 6 S2,gas -7.34 -38.53 -31.19 -4.799 0.53264E+05 -29.496 7 CO,gas 3.21 -12.33 -15.54 -4.782 0.26536E+05 -13.842 8 SO3,gas 17.12 -32.71 -49.84 -12.459 0.85093E+05 -48.137 9 SO2,gas 0.83 -28.23 -29.06 -7.750 0.49625E+05 -27.364 10 HCl,gas 5.19 -14.05 -19.24 -9.620 0.32852E+05 -17.541 11 acmite 7.71 6.53 -1.18 -0.123 0.20180E+04 15 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 19 spessartine 24.46 19.71 -4.75 -0.238 0.81131E+04 20 analcite 3.32 2.77 -0.55 -0.061 0.93608E+03 26 annite 20.12 17.72 -2.40 -0.134 0.41062E+04 27 phlogopite 27.06 25.40 -1.67 -0.093 0.28484E+04 29 anorthite 12.71 8.27 -4.44 -0.342 0.75895E+04 35 aragonite 0.97 -3.71 -4.67 -1.558 0.79802E+04 36 brucite 12.57 9.29 -3.27 -0.655 0.55907E+04 37 calcite 0.81 -3.71 -4.52 -1.506 0.77160E+04 38 carnegieite-low 9.02 5.93 -3.09 -0.442 0.52798E+04 39 carnegieite-high 10.09 5.93 -4.16 -0.595 0.71068E+04 40 carpholite-Mg 8.58 4.46 -4.12 -0.275 0.70421E+04 41 carpholite-Fe 6.71 1.90 -4.81 -0.321 0.82199E+04 42 celadonite 5.34 3.65 -1.69 -0.099 0.28878E+04 43 celadonite-Fe 3.88 1.09 -2.79 -0.164 0.47562E+04 44 chrysotile 23.89 21.57 -2.32 -0.194 0.39690E+04 49 chlorite-Al-free 47.17 43.14 -4.04 -0.168 0.68931E+04 51 chloritoid-Fe 9.17 5.06 -4.12 -0.275 0.70306E+04 52 chloritoid-Mn 11.40 7.55 -3.85 -0.256 0.65683E+04 54 coesite -2.38 -3.16 -0.78 -0.260 0.13343E+04 61 cristobalite -2.56 -3.16 -0.60 -0.199 0.10196E+04 63 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71234E+04 65 diaspore 2.87 0.74 -2.13 -0.356 0.36445E+04 66 diamond -3.10 -7.84 -4.74 -1.354 0.80945E+04 71 enstatite 17.26 12.27 -4.99 -0.499 0.85225E+04 73 clinoenstatite 17.17 12.27 -4.89 -0.489 0.83541E+04 75 epidote 24.67 22.70 -1.97 -0.095 0.33578E+04 76 clinozoisite 22.81 18.95 -3.86 -0.175 0.65855E+04 77 epidote-Fe 29.84 26.46 -3.38 -0.176 0.57767E+04 78 fayalite 14.05 10.31 -3.73 -0.533 0.63743E+04 79 ferrosilite 11.15 7.16 -3.99 -0.399 0.68204E+04 83 gibbsite 4.08 0.74 -3.34 -0.477 0.57030E+04 84 glaucophane 22.97 20.80 -2.17 -0.059 0.37131E+04 85 glaucophane-Fe 17.28 13.12 -4.15 -0.112 0.70920E+04 86 graphite -3.55 -7.84 -4.30 -1.228 0.73367E+04 87 greenalite 16.14 13.89 -2.25 -0.187 0.38409E+04 90 hematite 12.57 8.99 -3.58 -0.434 0.61114E+04 91 heulandite -5.83 -7.52 -1.69 -0.077 0.28938E+04 95 jadeite 4.22 2.77 -1.44 -0.144 0.24616E+04 97 kalsilite 7.58 3.83 -3.76 -0.536 0.64122E+04 98 kaolinite -1.33 -4.84 -3.50 -0.319 0.59825E+04 101 laumontite 2.88 1.95 -0.93 -0.062 0.15930E+04 102 lawsonite 9.62 8.27 -1.35 -0.090 0.23061E+04 103 leucite 4.12 0.67 -3.45 -0.345 0.58871E+04 105 lizardite 23.24 21.57 -1.68 -0.140 0.28616E+04 107 magnetite 20.09 15.72 -4.37 -0.356 0.74538E+04 108 minnesotaite 10.39 7.58 -2.81 -0.165 0.48032E+04 112 manganosite 14.06 9.23 -4.82 -1.206 0.82383E+04 120 muscovite 2.58 -1.01 -3.59 -0.211 0.61305E+04 121 paragonite 4.24 1.09 -3.14 -0.185 0.53696E+04 122 nepheline 8.34 5.93 -2.41 -0.344 0.41121E+04 128 periclase-Fe 11.63 6.74 -4.89 -1.223 0.83522E+04 134 phlogopite-Na 29.65 27.50 -2.15 -0.119 0.36672E+04 136 prehnite 19.37 18.21 -1.16 -0.068 0.19841E+04 137 prehnite-Fe 22.50 21.96 -0.53 -0.032 0.91137E+03 138 pumpellyite-Fe 46.27 43.89 -2.38 -0.053 0.40559E+04 139 pumpellyite-Mg 48.99 46.45 -2.54 -0.056 0.43396E+04 143 pyrrhotite -4.26 -8.05 -3.79 -1.262 0.64656E+04 144 pyrrhotiteFe0.875 -6.02 -9.44 -3.43 -1.261 0.58529E+04 145 pyroxmangite 7.40 6.08 -1.32 -0.265 0.22589E+04 146 pyrophyllite -6.18 -11.15 -4.98 -0.311 0.84958E+04 147 quartz -2.99 -3.16 -0.17 -0.056 0.28697E+03 152 rhodonite 7.45 6.08 -1.37 -0.274 0.23391E+04 153 sanidine -1.28 -2.49 -1.21 -0.093 0.20677E+04 165 stilpnomelane-Mg 27.44 25.81 -1.63 -0.049 0.27797E+04 171 talc 16.49 15.25 -1.24 -0.073 0.21141E+04 174 tephroite 18.09 15.31 -2.78 -0.397 0.47413E+04 178 tridymite -2.63 -3.16 -0.53 -0.177 0.90695E+03 179 tremolite 47.87 47.42 -0.45 -0.012 0.77500E+03 180 ferroactinolite 38.45 34.62 -3.83 -0.104 0.65455E+04 181 troilite-low -4.41 -8.05 -3.64 -1.212 0.62084E+04 183 vesuvianite 223.47 218.82 -4.65 -0.035 0.79376E+04 187 wairakite 3.95 1.95 -2.00 -0.118 0.34150E+04 188 walstromite 11.51 9.94 -1.56 -0.313 0.26719E+04 189 wollastonite 10.46 9.94 -0.52 -0.103 0.88228E+03 190 pseudo-wollastonite 11.00 9.94 -1.06 -0.211 0.18021E+04 191 zoisite 22.85 18.95 -3.90 -0.177 0.66596E+04 192 akaganeite 7.75 4.49 -3.26 -0.705 0.55682E+04 199 chalcedony -2.80 -3.16 -0.36 -0.118 0.60627E+03 201 montmorillonite-Ca -2.29 -6.17 -3.88 -0.240 0.66178E+04 202 montmorillonite-K -2.24 -6.27 -4.03 -0.247 0.68814E+04 203 montmorillonite-Mg -2.48 -6.79 -4.31 -0.267 0.73675E+04 204 montmorillonite-Na -2.04 -5.57 -3.54 -0.216 0.60363E+04 205 nontronite-Ca 3.21 -0.20 -3.41 -0.221 0.58222E+04 206 nontronite-H 2.53 -2.36 -4.89 -0.328 0.83492E+04 207 nontronite-K 3.34 -0.30 -3.64 -0.233 0.62090E+04 208 nontronite-Mg 3.07 -0.82 -3.90 -0.253 0.66560E+04 209 nontronite-Na 3.52 0.40 -3.12 -0.200 0.53299E+04 224 tobermorite 9.82 7.76 -2.07 -0.564 0.35287E+04 230 alabandite -0.98 -5.55 -4.57 -1.524 0.78046E+04 233 boehmite 4.41 0.74 -3.67 -0.611 0.62614E+04 235 ferrous-oxide 9.81 6.74 -3.08 -0.769 0.52532E+04 240 silica-amorphous -2.09 -3.16 -1.07 -0.355 0.18204E+04 242 an20ab80 2.02 1.35 -0.67 -0.052 0.11470E+04 243 an25ab75 2.65 1.78 -0.87 -0.067 0.14808E+04 244 an30ab70 3.28 2.21 -1.07 -0.082 0.18241E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 20.0000000 g Current total amount of reactant added: 419.9990000 g New total amount of reactant added: 439.9990000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.1586E-10 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 11 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 439.9990000 Water: Moles liquid = 0.5297E+02 kg liquid = 0.9543E+00 Moles total = 0.4999E+02 kg total = 0.9006E+00 Activity = 1.0000 Stoichiometric ionic strength = .1132240E-01 Osmotic coef. = 0.9695 True ionic strength = .2001133E-01 Chg. balance for total moles = -.1586E-10 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.88262E-10 -10.0542 0.74164E-10 -10.1298 0.84027E+00 -0.0756 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.14392E-03 -3.8419 0.12021E-03 -3.9201 0.83522E+00 -0.0782 4 SO4-- 0.67747E-12 -12.1691 0.35185E-12 -12.4536 0.51935E+00 -0.2845 5 HCO3- 0.25073E-06 -6.6008 0.20972E-06 -6.6784 0.83644E+00 -0.0776 6 HS- 0.26721E-04 -4.5731 0.22321E-04 -4.6513 0.83534E+00 -0.0781 7 Al+++ 0.96843E-29 -29.0139 0.22379E-29 -29.6502 0.23108E+00 -0.6362 8 H4SiO4 0.69583E-03 -3.1575 0.69583E-03 -3.1575 0.10000E+01 0.0000 9 Ca++ 0.13491E-06 -6.8700 0.69552E-07 -7.1577 0.51554E+00 -0.2877 10 Mg++ 0.21106E-10 -10.6756 0.10831E-10 -10.9653 0.51319E+00 -0.2897 11 Fe++ 0.58164E-13 -13.2353 0.29881E-13 -13.5246 0.51375E+00 -0.2893 12 K+ 0.15646E-03 -3.8056 0.13090E-03 -3.8831 0.83664E+00 -0.0775 13 Na+ 0.19854E-01 -1.7022 0.16579E-01 -1.7804 0.83507E+00 -0.0783 14 Mn++ 0.18321E-10 -10.7371 0.94200E-11 -11.0259 0.51417E+00 -0.2889 15 HPO4-- 0.45330E-07 -7.3436 0.23545E-07 -7.6281 0.51943E+00 -0.2845 16 HSiO3- 0.10489E-01 -1.9793 0.87606E-02 -2.0575 0.83522E+00 -0.0782 17 Ca(HSiO3)+ 0.16583E-07 -7.7803 0.13877E-07 -7.8577 0.83682E+00 -0.0774 18 Mg(HSiO3)+ 0.32139E-11 -11.4930 0.26894E-11 -11.5703 0.83682E+00 -0.0774 19 NaHSiO3,aq 0.23491E-02 -2.6291 0.23491E-02 -2.6291 0.10000E+01 0.0000 20 AlO+ 0.66144E-16 -16.1795 0.55351E-16 -16.2569 0.83682E+00 -0.0774 22 HAlO2,aq 0.14863E-09 -9.8279 0.14863E-09 -9.8279 0.10000E+01 0.0000 23 AlO2- 0.53210E-05 -5.2740 0.44362E-05 -5.3530 0.83371E+00 -0.0790 24 CH4,aq 0.12969E-04 -4.8871 0.12924E-04 -4.8886 0.99655E+00 -0.0015 25 C2H6,aq 0.24725E-14 -14.6069 0.24640E-14 -14.6084 0.99655E+00 -0.0015 29 CO,aq 0.96749E-17 -17.0144 0.96749E-17 -17.0144 0.10000E+01 0.0000 30 CO2,aq 0.33350E-10 -10.4769 0.33234E-10 -10.4784 0.99655E+00 -0.0015 31 CO3-2 0.47659E-06 -6.3219 0.24700E-06 -6.6073 0.51825E+00 -0.2855 32 CaCO3,aq 0.21541E-09 -9.6667 0.21541E-09 -9.6667 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.44494E-12 -12.3517 0.37234E-12 -12.4291 0.83682E+00 -0.0774 34 CaCl+ 0.16169E-10 -10.7913 0.13530E-10 -10.8687 0.83682E+00 -0.0774 35 CaCl2,aq 0.38641E-15 -15.4130 0.38641E-15 -15.4130 0.10000E+01 0.0000 36 CaOH+ 0.79871E-07 -7.0976 0.66838E-07 -7.1750 0.83682E+00 -0.0774 37 CaSO4,aq 0.77710E-17 -17.1095 0.77710E-17 -17.1095 0.10000E+01 0.0000 38 HCl,aq 0.16337E-14 -14.7868 0.16337E-14 -14.7868 0.10000E+01 0.0000 43 FeCl+ 0.67942E-17 -17.1679 0.56855E-17 -17.2452 0.83682E+00 -0.0774 46 FeO,aq 0.21114E-09 -9.6754 0.21114E-09 -9.6754 0.10000E+01 0.0000 47 FeOH+ 0.15673E-10 -10.8049 0.13115E-10 -10.8822 0.83682E+00 -0.0774 48 HFeO2- 0.35665E-07 -7.4478 0.29788E-07 -7.5260 0.83522E+00 -0.0782 49 FeO+ 0.10981E-16 -16.9593 0.91893E-17 -17.0367 0.83682E+00 -0.0774 51 FeO2- 0.40930E-09 -9.3880 0.34186E-09 -9.4662 0.83522E+00 -0.0782 52 HFeO2,aq 0.32246E-11 -11.4915 0.32246E-11 -11.4915 0.10000E+01 0.0000 53 H2,aq 0.11629E-04 -4.9345 0.11588E-04 -4.9360 0.99655E+00 -0.0015 54 KCl,aq 0.28519E-09 -9.5449 0.28519E-09 -9.5449 0.10000E+01 0.0000 56 KOH,aq 0.75375E-06 -6.1228 0.75375E-06 -6.1228 0.10000E+01 0.0000 57 KSO4- 0.85569E-15 -15.0677 0.71469E-15 -15.1459 0.83522E+00 -0.0782 58 MgCO3,aq 0.84084E-14 -14.0753 0.84084E-14 -14.0753 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.70803E-16 -16.1500 0.59249E-16 -16.2273 0.83682E+00 -0.0774 60 MgCl+ 0.22821E-14 -14.6417 0.19097E-14 -14.7190 0.83682E+00 -0.0774 61 MgOH+ 0.68828E-10 -10.1622 0.57597E-10 -10.2396 0.83682E+00 -0.0774 63 MnO,aq 0.17736E-08 -8.7511 0.17736E-08 -8.7511 0.10000E+01 0.0000 64 MnOH+ 0.45898E-09 -9.3382 0.38408E-09 -9.4156 0.83682E+00 -0.0774 65 MnO2-2 0.20649E-10 -10.6851 0.10701E-10 -10.9706 0.51825E+00 -0.2855 66 HMnO2- 0.20818E-09 -9.6816 0.17388E-09 -9.7598 0.83522E+00 -0.0782 69 MnCl+ 0.83328E-14 -14.0792 0.69730E-14 -14.1566 0.83682E+00 -0.0774 71 NaCl,aq 0.66047E-06 -6.1801 0.66047E-06 -6.1801 0.10000E+01 0.0000 72 NaOH,aq 0.96047E-04 -4.0175 0.96047E-04 -4.0175 0.10000E+01 0.0000 74 OH- 0.93443E-02 -2.0295 0.77905E-02 -2.1084 0.83371E+00 -0.0790 79 HPO3-2 0.16407E-14 -14.7850 0.85031E-15 -15.0704 0.51825E+00 -0.2855 81 H2PO3- 0.15141E-18 -18.8198 0.12646E-18 -18.8980 0.83522E+00 -0.0782 82 H3PO4,aq 0.90577E-18 -18.0430 0.90577E-18 -18.0430 0.10000E+01 0.0000 83 H2PO4- 0.38532E-10 -10.4142 0.32213E-10 -10.4920 0.83601E+00 -0.0778 84 PO4-3 0.10673E-08 -8.9717 0.25903E-09 -9.5867 0.24270E+00 -0.6149 88 HP2O7-3 0.94706E-18 -18.0236 0.21906E-18 -18.6594 0.23131E+00 -0.6358 89 P2O7-4 0.91481E-17 -17.0387 0.70565E-18 -18.1514 0.77136E-01 -1.1127 90 H2S,aq 0.51341E-08 -8.2895 0.51163E-08 -8.2910 0.99655E+00 -0.0015 91 S2-2 0.18383E-14 -14.7356 0.95268E-15 -15.0211 0.51825E+00 -0.2855 97 SO3-2 0.10078E-17 -17.9966 0.52985E-18 -18.2758 0.52575E+00 -0.2792 99 HSO4- 0.30022E-19 -19.5226 0.25148E-19 -19.5995 0.83763E+00 -0.0769 Charge balance for all species = -.1662E-10 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.8826223E-10 -.2230418E-01 -.2244221E+02 0.0000 2 H2O 0.1000000E+01 0.5550489E+02 0.9982000E+06 0.0000 3 Cl- 0.1439239E-03 0.1445847E-03 0.5117056E+01 6.2097 4 SO4-- 0.6774737E-12 -.1587573E-04 -.1522399E+01 7.8060 5 HCO3- 0.2507286E-06 0.1369620E-04 0.8342519E+00 3.4514 6 HS- 0.2672129E-04 0.4260215E-04 0.1406491E+01 5.4785 7 Al+++ 0.9684344E-29 0.5321139E-05 0.1433229E+00 0.7393 8 H4SiO4 0.6958281E-03 0.1353401E-01 0.1298566E+04 -3.1575 9 Ca++ 0.1349109E-06 0.2315970E-06 0.9265818E-02 13.1019 10 Mg++ 0.2110627E-10 0.9315896E-10 0.2260946E-05 9.2943 11 Fe++ 0.5816356E-13 0.3630476E-07 0.2023989E-02 6.7350 12 K+ 0.1564590E-03 0.1572130E-03 0.6136663E+01 6.2467 13 Na+ 0.1985384E-01 0.2229968E-01 0.5117746E+03 8.3494 14 Mn++ 0.1832073E-10 0.2479751E-08 0.1359959E-03 9.2337 15 HPO4-- 0.4532959E-07 0.4643541E-07 0.4449081E-02 12.6315 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.7285717E+01 -.2128441E-01 -.7264433E+01 0.0000000E+00 2 H2O 0.4999268E+02 0.5296716E+02 -.2974482E+01 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.1221938E-01 -.1514988E-04 0.1223453E-01 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.1219387E-01 0.4065435E-04 -.1223453E-01 0.0000000E+00 7 Al+++ 0.1434723E+01 0.5077853E-05 0.1434718E+01 0.0000000E+00 8 H4SiO4 0.4581614E+01 0.1291522E-01 0.4568699E+01 0.0000000E+00 9 Ca++ 0.5060761E+00 0.2210082E-06 0.5060759E+00 0.0000000E+00 10 Mg++ 0.3492056E+00 0.8889967E-10 0.3492056E+00 0.0000000E+00 11 Fe++ 0.3137231E+00 0.3464488E-07 0.3137230E+00 0.0000000E+00 12 K+ 0.9341805E-01 0.1500251E-03 0.9326802E-01 0.0000000E+00 13 Na+ 0.5524660E+00 0.2128013E-01 0.5311859E+00 0.0000000E+00 14 Mn++ 0.7628965E-02 0.2366375E-08 0.7628963E-02 0.0000000E+00 15 HPO4-- 0.2603728E-02 0.4431235E-07 0.2603683E-02 0.0000000E+00 Chg. balance for solid moles: 0.1687E-14 Mass of aqueous solution: 0.955940E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 439.9990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 0.5306 -0.275 139.1 2.143 28.96 53.41 andradite 0.4894E-01 -1.310 24.87 1.396 5.176 6.461 grossular 0.1186E-01 -1.926 5.342 0.728 1.112 1.486 apatite-OH 0.8679E-03 -3.062 0.4360 -0.361 0.9073E-01 0.1385 clinochlore 0.6367E-01 -1.196 35.39 1.549 7.365 13.46 daphnite 0.1843E-01 -1.734 13.15 1.119 2.737 3.985 chlorite-Mn 0.1526E-02 -2.817 1.082 0.034 0.2251 0.3447 diopside 0.1467E-01 -1.834 3.177 0.502 0.6613 0.9711 hedenbergite 0.3804E-02 -2.420 0.9439 -0.025 0.1964 0.2585 microcline 0.8184E-01 -1.087 22.78 1.358 4.740 8.898 stilbite 0.2919 -0.535 205.7 2.313 42.82 95.96 stilpnomelane-Fe 0.2286E-01 -1.641 24.65 1.392 5.129 8.513 tr.625ac.25prg.125 0.4463E-02 -2.350 3.815 0.581 0.7939 1.228 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8049E+00 0.8049E+00 1.0000 -0.094 grossular 0.1951E+00 0.1951E+00 1.0000 -0.710 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.7614E+00 0.7614E+00 1.0000 -0.118 daphnite 0.2204E+00 0.2204E+00 1.0000 -0.657 chlorite-Mn 0.1825E-01 0.1825E-01 1.0000 -1.739 diopside 0.7941E+00 0.7941E+00 1.0000 -0.100 hedenbergite 0.2059E+00 0.2059E+00 1.0000 -0.686 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 tr.625ac.25prg.125 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 480.507646 g Volume = 195.118135 cm3 Porosity: -10.2365% V(tot) - V(min): -.18119E+02 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 439.9990000 g log = 2.6435 Original solution: 1000.0103000 g Original solution / Rock added: 2.27 (Water/Rock Ratio), log = 0.3566 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0548 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9678E+00 0.9855 0.1006E+01 0.1021E+01 CO2,gas 0.3348E-08 1.0069 0.3556E-08 0.3531E-08 CH4,gas 0.1781E-01 1.0125 0.1902E-01 0.1879E-01 H2,gas 0.1442E-01 1.0006 0.1521E-01 0.1521E-01 H2S,gas 0.1339E-06 0.9959 0.1406E-06 0.1412E-06 S2,gas 0.3041E-29 1.0000 0.3208E-29 0.3208E-29 CO,gas 0.1367E-13 1.0000 0.1442E-13 0.1442E-13 SO3,gas 0.6937E-48 1.0000 0.7317E-48 0.7317E-48 SO2,gas 0.4106E-27 1.0000 0.4331E-27 0.4331E-27 HCl,gas 0.2733E-17 1.0000 0.2883E-17 0.2883E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 16 albite -0.38 -0.38 0.00 0.000 -0.94784E-12 22 andradite 39.01 39.01 0.00 0.000 0.24265E-10 23 grossular 32.73 32.73 0.00 0.000 0.00000E+00 32 apatite-OH -18.15 -18.15 0.00 0.000 0.00000E+00 46 clinochlore 39.07 39.07 0.00 0.000 0.00000E+00 47 daphnite 28.97 28.97 0.00 0.000 -0.36397E-10 48 chlorite-Mn 46.87 46.87 0.00 0.000 0.24265E-10 67 diopside 16.18 16.18 0.00 0.000 0.00000E+00 68 hedenbergite 14.21 14.21 0.00 0.000 -0.30331E-11 116 microcline -2.49 -2.49 0.00 0.000 -0.10616E-10 163 stilbite -7.52 -7.52 0.00 0.000 0.15165E-10 164 stilpnomelane-Fe 13.02 13.02 0.00 0.000 -0.75827E-10 245 tr.625ac.25prg.125 45.16 45.16 0.00 0.000 0.12132E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -16.81 -10.15 -3.383 0.17328E+05 -8.449 3 CH4,gas 4.54 1.12 -3.42 -0.855 0.58390E+04 -1.721 4 H2,gas 8.00 4.48 -3.52 -2.010 0.60047E+04 -1.818 5 H2S,gas -6.23 -14.78 -8.55 -4.275 0.14600E+05 -6.852 6 S2,gas -7.34 -38.53 -31.19 -4.799 0.53261E+05 -29.494 7 CO,gas 3.21 -12.33 -15.54 -4.782 0.26534E+05 -13.841 8 SO3,gas 17.12 -32.71 -49.83 -12.459 0.85091E+05 -48.136 9 SO2,gas 0.83 -28.23 -29.06 -7.750 0.49623E+05 -27.363 10 HCl,gas 5.19 -14.05 -19.24 -9.620 0.32850E+05 -17.540 11 acmite 7.71 6.53 -1.18 -0.123 0.20180E+04 15 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 19 spessartine 24.46 19.71 -4.75 -0.238 0.81110E+04 20 analcite 3.32 2.77 -0.55 -0.061 0.93609E+03 26 annite 20.12 17.72 -2.40 -0.134 0.41062E+04 27 phlogopite 27.06 25.40 -1.67 -0.093 0.28484E+04 29 anorthite 12.71 8.27 -4.44 -0.342 0.75895E+04 35 aragonite 0.97 -3.71 -4.67 -1.558 0.79786E+04 36 brucite 12.57 9.29 -3.27 -0.655 0.55907E+04 37 calcite 0.81 -3.71 -4.52 -1.506 0.77144E+04 38 carnegieite-low 9.02 5.93 -3.09 -0.442 0.52798E+04 39 carnegieite-high 10.09 5.93 -4.16 -0.595 0.71068E+04 40 carpholite-Mg 8.58 4.46 -4.12 -0.275 0.70421E+04 41 carpholite-Fe 6.71 1.90 -4.81 -0.321 0.82200E+04 42 celadonite 5.34 3.65 -1.69 -0.099 0.28878E+04 43 celadonite-Fe 3.88 1.09 -2.79 -0.164 0.47562E+04 44 chrysotile 23.89 21.57 -2.32 -0.194 0.39690E+04 49 chlorite-Al-free 47.17 43.14 -4.04 -0.168 0.68932E+04 51 chloritoid-Fe 9.17 5.06 -4.12 -0.275 0.70307E+04 52 chloritoid-Mn 11.40 7.55 -3.85 -0.256 0.65676E+04 54 coesite -2.38 -3.16 -0.78 -0.260 0.13343E+04 61 cristobalite -2.56 -3.16 -0.60 -0.199 0.10196E+04 63 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71234E+04 65 diaspore 2.87 0.74 -2.13 -0.356 0.36445E+04 66 diamond -3.10 -7.84 -4.74 -1.354 0.80929E+04 71 enstatite 17.26 12.27 -4.99 -0.499 0.85225E+04 73 clinoenstatite 17.17 12.27 -4.89 -0.489 0.83541E+04 75 epidote 24.67 22.70 -1.97 -0.095 0.33578E+04 76 clinozoisite 22.81 18.95 -3.86 -0.175 0.65856E+04 77 epidote-Fe 29.84 26.46 -3.38 -0.176 0.57767E+04 78 fayalite 14.05 10.31 -3.73 -0.533 0.63743E+04 79 ferrosilite 11.15 7.16 -3.99 -0.399 0.68204E+04 83 gibbsite 4.08 0.74 -3.34 -0.477 0.57031E+04 84 glaucophane 22.97 20.80 -2.17 -0.059 0.37131E+04 85 glaucophane-Fe 17.28 13.12 -4.15 -0.112 0.70920E+04 86 graphite -3.55 -7.84 -4.30 -1.227 0.73351E+04 87 greenalite 16.14 13.89 -2.25 -0.187 0.38409E+04 90 hematite 12.57 8.99 -3.58 -0.434 0.61114E+04 91 heulandite -5.83 -7.52 -1.69 -0.077 0.28938E+04 95 jadeite 4.22 2.77 -1.44 -0.144 0.24616E+04 97 kalsilite 7.58 3.83 -3.76 -0.536 0.64123E+04 98 kaolinite -1.33 -4.84 -3.50 -0.319 0.59825E+04 101 laumontite 2.88 1.95 -0.93 -0.062 0.15930E+04 102 lawsonite 9.62 8.27 -1.35 -0.090 0.23062E+04 103 leucite 4.12 0.67 -3.45 -0.345 0.58871E+04 105 lizardite 23.24 21.57 -1.68 -0.140 0.28616E+04 107 magnetite 20.09 15.72 -4.37 -0.356 0.74538E+04 108 minnesotaite 10.39 7.58 -2.81 -0.165 0.48032E+04 112 manganosite 14.06 9.23 -4.82 -1.206 0.82376E+04 120 muscovite 2.58 -1.01 -3.59 -0.211 0.61305E+04 121 paragonite 4.24 1.09 -3.14 -0.185 0.53696E+04 122 nepheline 8.34 5.93 -2.41 -0.344 0.41122E+04 128 periclase-Fe 11.63 6.74 -4.89 -1.223 0.83522E+04 134 phlogopite-Na 29.65 27.50 -2.15 -0.119 0.36672E+04 136 prehnite 19.37 18.21 -1.16 -0.068 0.19841E+04 137 prehnite-Fe 22.50 21.96 -0.53 -0.032 0.91138E+03 138 pumpellyite-Fe 46.27 43.89 -2.38 -0.053 0.40560E+04 139 pumpellyite-Mg 48.99 46.45 -2.54 -0.056 0.43397E+04 143 pyrrhotite -4.26 -8.05 -3.79 -1.262 0.64641E+04 144 pyrrhotiteFe0.875 -6.02 -9.44 -3.43 -1.260 0.58513E+04 145 pyroxmangite 7.40 6.08 -1.32 -0.265 0.22582E+04 146 pyrophyllite -6.18 -11.15 -4.98 -0.311 0.84958E+04 147 quartz -2.99 -3.16 -0.17 -0.056 0.28696E+03 152 rhodonite 7.45 6.08 -1.37 -0.274 0.23384E+04 153 sanidine -1.28 -2.49 -1.21 -0.093 0.20677E+04 165 stilpnomelane-Mg 27.44 25.81 -1.63 -0.049 0.27798E+04 171 talc 16.49 15.25 -1.24 -0.073 0.21141E+04 174 tephroite 18.09 15.31 -2.78 -0.397 0.47399E+04 178 tridymite -2.63 -3.16 -0.53 -0.177 0.90694E+03 179 tremolite 47.87 47.42 -0.45 -0.012 0.77500E+03 180 ferroactinolite 38.45 34.62 -3.83 -0.104 0.65455E+04 181 troilite-low -4.41 -8.05 -3.64 -1.212 0.62069E+04 183 vesuvianite 223.47 218.82 -4.65 -0.035 0.79379E+04 187 wairakite 3.95 1.95 -2.00 -0.118 0.34150E+04 188 walstromite 11.51 9.94 -1.56 -0.313 0.26719E+04 189 wollastonite 10.46 9.94 -0.52 -0.103 0.88228E+03 190 pseudo-wollastonite 11.00 9.94 -1.06 -0.211 0.18021E+04 191 zoisite 22.85 18.95 -3.90 -0.177 0.66596E+04 192 akaganeite 7.75 4.49 -3.26 -0.705 0.55682E+04 199 chalcedony -2.80 -3.16 -0.36 -0.118 0.60626E+03 201 montmorillonite-Ca -2.29 -6.17 -3.88 -0.240 0.66178E+04 202 montmorillonite-K -2.24 -6.27 -4.03 -0.247 0.68814E+04 203 montmorillonite-Mg -2.48 -6.79 -4.31 -0.267 0.73675E+04 204 montmorillonite-Na -2.04 -5.57 -3.54 -0.216 0.60363E+04 205 nontronite-Ca 3.21 -0.20 -3.41 -0.221 0.58221E+04 206 nontronite-H 2.53 -2.36 -4.89 -0.328 0.83492E+04 207 nontronite-K 3.34 -0.30 -3.64 -0.233 0.62090E+04 208 nontronite-Mg 3.07 -0.82 -3.90 -0.253 0.66560E+04 209 nontronite-Na 3.52 0.40 -3.12 -0.200 0.53298E+04 224 tobermorite 9.82 7.76 -2.07 -0.564 0.35287E+04 230 alabandite -0.98 -5.55 -4.57 -1.523 0.78024E+04 233 boehmite 4.41 0.74 -3.67 -0.611 0.62614E+04 235 ferrous-oxide 9.81 6.74 -3.08 -0.769 0.52532E+04 240 silica-amorphous -2.09 -3.16 -1.07 -0.355 0.18204E+04 242 an20ab80 2.02 1.35 -0.67 -0.052 0.11471E+04 243 an25ab75 2.65 1.78 -0.87 -0.067 0.14808E+04 244 an30ab70 3.28 2.21 -1.07 -0.082 0.18241E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 20.0000000 g Current total amount of reactant added: 439.9990000 g New total amount of reactant added: 459.9990000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.1586E-10 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 11 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 459.9990000 Water: Moles liquid = 0.5286E+02 kg liquid = 0.9523E+00 Moles total = 0.4974E+02 kg total = 0.8961E+00 Activity = 1.0000 Stoichiometric ionic strength = .1132270E-01 Osmotic coef. = 0.9695 True ionic strength = .2001158E-01 Chg. balance for total moles = -.1586E-10 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.88263E-10 -10.0542 0.74165E-10 -10.1298 0.84027E+00 -0.0756 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.14423E-03 -3.8410 0.12046E-03 -3.9192 0.83522E+00 -0.0782 4 SO4-- 0.67896E-12 -12.1682 0.35262E-12 -12.4527 0.51935E+00 -0.2845 5 HCO3- 0.25128E-06 -6.5998 0.21018E-06 -6.6774 0.83644E+00 -0.0776 6 HS- 0.26778E-04 -4.5722 0.22368E-04 -4.6504 0.83534E+00 -0.0781 7 Al+++ 0.96845E-29 -29.0139 0.22379E-29 -29.6502 0.23108E+00 -0.6362 8 H4SiO4 0.69584E-03 -3.1575 0.69584E-03 -3.1575 0.10000E+01 0.0000 9 Ca++ 0.13491E-06 -6.8699 0.69553E-07 -7.1577 0.51554E+00 -0.2877 10 Mg++ 0.21107E-10 -10.6756 0.10832E-10 -10.9653 0.51318E+00 -0.2897 11 Fe++ 0.58165E-13 -13.2353 0.29882E-13 -13.5246 0.51375E+00 -0.2893 12 K+ 0.15646E-03 -3.8056 0.13090E-03 -3.8831 0.83664E+00 -0.0775 13 Na+ 0.19854E-01 -1.7022 0.16579E-01 -1.7804 0.83507E+00 -0.0783 14 Mn++ 0.18337E-10 -10.7367 0.94284E-11 -11.0256 0.51417E+00 -0.2889 15 HPO4-- 0.45329E-07 -7.3436 0.23545E-07 -7.6281 0.51943E+00 -0.2845 16 HSiO3- 0.10489E-01 -1.9793 0.87606E-02 -2.0575 0.83522E+00 -0.0782 17 Ca(HSiO3)+ 0.16583E-07 -7.7803 0.13877E-07 -7.8577 0.83682E+00 -0.0774 18 Mg(HSiO3)+ 0.32139E-11 -11.4930 0.26894E-11 -11.5703 0.83682E+00 -0.0774 19 NaHSiO3,aq 0.23492E-02 -2.6291 0.23492E-02 -2.6291 0.10000E+01 0.0000 20 AlO+ 0.66143E-16 -16.1795 0.55350E-16 -16.2569 0.83682E+00 -0.0774 22 HAlO2,aq 0.14862E-09 -9.8279 0.14862E-09 -9.8279 0.10000E+01 0.0000 23 AlO2- 0.53208E-05 -5.2740 0.44360E-05 -5.3530 0.83371E+00 -0.0790 24 CH4,aq 0.12996E-04 -4.8862 0.12951E-04 -4.8877 0.99655E+00 -0.0015 25 C2H6,aq 0.24830E-14 -14.6050 0.24744E-14 -14.6065 0.99655E+00 -0.0015 29 CO,aq 0.96960E-17 -17.0134 0.96960E-17 -17.0134 0.10000E+01 0.0000 30 CO2,aq 0.33423E-10 -10.4760 0.33308E-10 -10.4775 0.99655E+00 -0.0015 31 CO3-2 0.47763E-06 -6.3209 0.24753E-06 -6.6064 0.51825E+00 -0.2855 32 CaCO3,aq 0.21588E-09 -9.6658 0.21588E-09 -9.6658 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.44592E-12 -12.3507 0.37316E-12 -12.4281 0.83682E+00 -0.0774 34 CaCl+ 0.16203E-10 -10.7904 0.13559E-10 -10.8678 0.83682E+00 -0.0774 35 CaCl2,aq 0.38805E-15 -15.4111 0.38805E-15 -15.4111 0.10000E+01 0.0000 36 CaOH+ 0.79872E-07 -7.0976 0.66838E-07 -7.1750 0.83682E+00 -0.0774 37 CaSO4,aq 0.77881E-17 -17.1086 0.77881E-17 -17.1086 0.10000E+01 0.0000 38 HCl,aq 0.16371E-14 -14.7859 0.16371E-14 -14.7859 0.10000E+01 0.0000 43 FeCl+ 0.68087E-17 -17.1669 0.56976E-17 -17.2443 0.83682E+00 -0.0774 46 FeO,aq 0.21114E-09 -9.6754 0.21114E-09 -9.6754 0.10000E+01 0.0000 47 FeOH+ 0.15673E-10 -10.8049 0.13115E-10 -10.8822 0.83682E+00 -0.0774 48 HFeO2- 0.35665E-07 -7.4478 0.29788E-07 -7.5260 0.83522E+00 -0.0782 49 FeO+ 0.10982E-16 -16.9593 0.91895E-17 -17.0367 0.83682E+00 -0.0774 51 FeO2- 0.40930E-09 -9.3880 0.34186E-09 -9.4662 0.83522E+00 -0.0782 52 HFeO2,aq 0.32246E-11 -11.4915 0.32246E-11 -11.4915 0.10000E+01 0.0000 53 H2,aq 0.11628E-04 -4.9345 0.11588E-04 -4.9360 0.99655E+00 -0.0015 54 KCl,aq 0.28579E-09 -9.5440 0.28579E-09 -9.5440 0.10000E+01 0.0000 56 KOH,aq 0.75375E-06 -6.1228 0.75375E-06 -6.1228 0.10000E+01 0.0000 57 KSO4- 0.85758E-15 -15.0667 0.71627E-15 -15.1449 0.83522E+00 -0.0782 58 MgCO3,aq 0.84268E-14 -14.0743 0.84268E-14 -14.0743 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.70959E-16 -16.1490 0.59379E-16 -16.2264 0.83682E+00 -0.0774 60 MgCl+ 0.22870E-14 -14.6407 0.19138E-14 -14.7181 0.83682E+00 -0.0774 61 MgOH+ 0.68828E-10 -10.1622 0.57597E-10 -10.2396 0.83682E+00 -0.0774 63 MnO,aq 0.17751E-08 -8.7508 0.17751E-08 -8.7508 0.10000E+01 0.0000 64 MnOH+ 0.45938E-09 -9.3378 0.38442E-09 -9.4152 0.83682E+00 -0.0774 65 MnO2-2 0.20666E-10 -10.6847 0.10710E-10 -10.9702 0.51825E+00 -0.2855 66 HMnO2- 0.20836E-09 -9.6812 0.17403E-09 -9.7594 0.83522E+00 -0.0782 69 MnCl+ 0.83577E-14 -14.0779 0.69939E-14 -14.1553 0.83682E+00 -0.0774 71 NaCl,aq 0.66187E-06 -6.1792 0.66187E-06 -6.1792 0.10000E+01 0.0000 72 NaOH,aq 0.96047E-04 -4.0175 0.96047E-04 -4.0175 0.10000E+01 0.0000 74 OH- 0.93442E-02 -2.0295 0.77904E-02 -2.1084 0.83371E+00 -0.0790 79 HPO3-2 0.16407E-14 -14.7850 0.85029E-15 -15.0704 0.51825E+00 -0.2855 81 H2PO3- 0.15141E-18 -18.8199 0.12646E-18 -18.8981 0.83522E+00 -0.0782 82 H3PO4,aq 0.90578E-18 -18.0430 0.90578E-18 -18.0430 0.10000E+01 0.0000 83 H2PO4- 0.38532E-10 -10.4142 0.32213E-10 -10.4920 0.83601E+00 -0.0778 84 PO4-3 0.10673E-08 -8.9717 0.25902E-09 -9.5867 0.24270E+00 -0.6149 88 HP2O7-3 0.94706E-18 -18.0236 0.21906E-18 -18.6594 0.23131E+00 -0.6358 89 P2O7-4 0.91481E-17 -17.0387 0.70564E-18 -18.1514 0.77135E-01 -1.1127 90 H2S,aq 0.51450E-08 -8.2886 0.51272E-08 -8.2901 0.99655E+00 -0.0015 91 S2-2 0.18461E-14 -14.7338 0.95673E-15 -15.0192 0.51825E+00 -0.2855 97 SO3-2 0.10100E-17 -17.9957 0.53100E-18 -18.2749 0.52574E+00 -0.2792 99 HSO4- 0.30089E-19 -19.5216 0.25203E-19 -19.5985 0.83763E+00 -0.0769 Charge balance for all species = -.1666E-10 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.8826335E-10 -.2230409E-01 -.2244213E+02 0.0000 2 H2O 0.1000000E+01 0.5550489E+02 0.9981999E+06 0.0000 3 Cl- 0.1442275E-03 0.1448897E-03 0.5127848E+01 6.2106 4 SO4-- 0.6789612E-12 -.1590296E-04 -.1525010E+01 7.8069 5 HCO3- 0.2512776E-06 0.1372509E-04 0.8360115E+00 3.4524 6 HS- 0.2677765E-04 0.4268575E-04 0.1409251E+01 5.4794 7 Al+++ 0.9684466E-29 0.5320919E-05 0.1433169E+00 0.7392 8 H4SiO4 0.6958352E-03 0.1353403E-01 0.1298568E+04 -3.1575 9 Ca++ 0.1349132E-06 0.2316001E-06 0.9265943E-02 13.1019 10 Mg++ 0.2110660E-10 0.9315947E-10 0.2260958E-05 9.2943 11 Fe++ 0.5816489E-13 0.3630422E-07 0.2023959E-02 6.7350 12 K+ 0.1564609E-03 0.1572150E-03 0.6136740E+01 6.2467 13 Na+ 0.1985409E-01 0.2229996E-01 0.5117809E+03 8.3494 14 Mn++ 0.1833699E-10 0.2481888E-08 0.1361131E-03 9.2340 15 HPO4-- 0.4532945E-07 0.4643526E-07 0.4449067E-02 12.6315 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.7616887E+01 -.2123953E-01 -.7595648E+01 0.0000000E+00 2 H2O 0.4974197E+02 0.5285568E+02 -.3113707E+01 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.1277364E-01 -.1514392E-04 0.1278879E-01 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.1274814E-01 0.4064839E-04 -.1278879E-01 0.0000000E+00 7 Al+++ 0.1499938E+01 0.5066955E-05 0.1499933E+01 0.0000000E+00 8 H4SiO4 0.4789870E+01 0.1288806E-01 0.4776982E+01 0.0000000E+00 9 Ca++ 0.5290789E+00 0.2205460E-06 0.5290787E+00 0.0000000E+00 10 Mg++ 0.3650786E+00 0.8871304E-10 0.3650786E+00 0.0000000E+00 11 Fe++ 0.3279832E+00 0.3457144E-07 0.3279832E+00 0.0000000E+00 12 K+ 0.9766433E-01 0.1497112E-03 0.9751462E-01 0.0000000E+00 13 Na+ 0.5775709E+00 0.2123560E-01 0.5563353E+00 0.0000000E+00 14 Mn++ 0.7975737E-02 0.2363430E-08 0.7975734E-02 0.0000000E+00 15 HPO4-- 0.2722079E-02 0.4421894E-07 0.2722035E-02 0.0000000E+00 Chg. balance for solid moles: -.7425E-15 Mass of aqueous solution: 0.953928E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 459.9990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 0.5558 -0.255 145.7 2.164 29.01 55.94 andradite 0.5116E-01 -1.291 26.00 1.415 5.175 6.754 grossular 0.1240E-01 -1.907 5.584 0.747 1.112 1.554 apatite-OH 0.9073E-03 -3.042 0.4558 -0.341 0.9073E-01 0.1448 clinochlore 0.6651E-01 -1.177 36.97 1.568 7.359 14.06 daphnite 0.1925E-01 -1.716 13.74 1.138 2.734 4.162 chlorite-Mn 0.1595E-02 -2.797 1.131 0.053 0.2251 0.3604 diopside 0.1576E-01 -1.802 3.413 0.533 0.6794 1.043 hedenbergite 0.4087E-02 -2.389 1.014 0.006 0.2018 0.2777 microcline 0.8556E-01 -1.068 23.81 1.377 4.741 9.303 stilbite 0.3048 -0.516 214.8 2.332 42.76 100.2 stilpnomelane-Fe 0.2391E-01 -1.621 25.77 1.411 5.131 8.903 tr.625ac.25prg.125 0.4630E-02 -2.334 3.957 0.597 0.7877 1.274 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8049E+00 0.8049E+00 1.0000 -0.094 grossular 0.1951E+00 0.1951E+00 1.0000 -0.710 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.7614E+00 0.7614E+00 1.0000 -0.118 daphnite 0.2204E+00 0.2204E+00 1.0000 -0.657 chlorite-Mn 0.1826E-01 0.1826E-01 1.0000 -1.738 diopside 0.7941E+00 0.7941E+00 1.0000 -0.100 hedenbergite 0.2059E+00 0.2059E+00 1.0000 -0.686 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 tr.625ac.25prg.125 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 502.357773 g Volume = 203.958747 cm3 Porosity: -10.2482% V(tot) - V(min): -.18959E+02 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 459.9990000 g log = 2.6628 Original solution: 1000.0103000 g Original solution / Rock added: 2.17 (Water/Rock Ratio), log = 0.3372 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0548 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9677E+00 0.9855 0.1006E+01 0.1021E+01 CO2,gas 0.3355E-08 1.0069 0.3564E-08 0.3539E-08 CH4,gas 0.1785E-01 1.0125 0.1906E-01 0.1883E-01 H2,gas 0.1442E-01 1.0006 0.1521E-01 0.1521E-01 H2S,gas 0.1342E-06 0.9959 0.1409E-06 0.1415E-06 S2,gas 0.3054E-29 1.0000 0.3221E-29 0.3221E-29 CO,gas 0.1370E-13 1.0000 0.1445E-13 0.1445E-13 SO3,gas 0.6952E-48 1.0000 0.7334E-48 0.7334E-48 SO2,gas 0.4115E-27 1.0000 0.4341E-27 0.4341E-27 HCl,gas 0.2739E-17 1.0000 0.2889E-17 0.2889E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 16 albite -0.38 -0.38 0.00 0.000 -0.13080E-10 22 andradite 39.01 39.01 0.00 0.000 0.00000E+00 23 grossular 32.73 32.73 0.00 0.000 -0.24265E-10 32 apatite-OH -18.15 -18.15 0.00 0.000 0.60662E-11 46 clinochlore 39.07 39.07 0.00 0.000 -0.36397E-10 47 daphnite 28.97 28.97 0.00 0.000 0.60662E-11 48 chlorite-Mn 46.87 46.87 0.00 0.000 -0.36397E-10 67 diopside 16.18 16.18 0.00 0.000 -0.60662E-11 68 hedenbergite 14.21 14.21 0.00 0.000 0.00000E+00 116 microcline -2.49 -2.49 0.00 0.000 0.15165E-11 163 stilbite -7.52 -7.52 0.00 0.000 0.15165E-10 164 stilpnomelane-Fe 13.02 13.02 0.00 0.000 0.21232E-10 245 tr.625ac.25prg.125 45.16 45.16 0.00 0.000 0.24265E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -16.81 -10.15 -3.382 0.17326E+05 -8.448 3 CH4,gas 4.54 1.12 -3.42 -0.855 0.58375E+04 -1.720 4 H2,gas 8.00 4.48 -3.52 -2.010 0.60047E+04 -1.818 5 H2S,gas -6.23 -14.78 -8.55 -4.275 0.14599E+05 -6.851 6 S2,gas -7.34 -38.53 -31.19 -4.799 0.53258E+05 -29.492 7 CO,gas 3.21 -12.32 -15.54 -4.781 0.26533E+05 -13.840 8 SO3,gas 17.12 -32.71 -49.83 -12.458 0.85090E+05 -48.135 9 SO2,gas 0.83 -28.23 -29.06 -7.750 0.49622E+05 -27.362 10 HCl,gas 5.19 -14.05 -19.24 -9.619 0.32849E+05 -17.539 11 acmite 7.71 6.53 -1.18 -0.123 0.20179E+04 15 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 19 spessartine 24.46 19.71 -4.75 -0.237 0.81092E+04 20 analcite 3.32 2.77 -0.55 -0.061 0.93610E+03 26 annite 20.12 17.72 -2.40 -0.134 0.41062E+04 27 phlogopite 27.06 25.40 -1.67 -0.093 0.28484E+04 29 anorthite 12.71 8.27 -4.44 -0.342 0.75895E+04 35 aragonite 0.97 -3.71 -4.67 -1.557 0.79770E+04 36 brucite 12.57 9.29 -3.27 -0.655 0.55907E+04 37 calcite 0.81 -3.71 -4.52 -1.506 0.77128E+04 38 carnegieite-low 9.02 5.93 -3.09 -0.442 0.52798E+04 39 carnegieite-high 10.09 5.93 -4.16 -0.595 0.71068E+04 40 carpholite-Mg 8.58 4.46 -4.12 -0.275 0.70421E+04 41 carpholite-Fe 6.71 1.90 -4.81 -0.321 0.82200E+04 42 celadonite 5.34 3.65 -1.69 -0.099 0.28878E+04 43 celadonite-Fe 3.88 1.09 -2.79 -0.164 0.47562E+04 44 chrysotile 23.89 21.57 -2.32 -0.194 0.39690E+04 49 chlorite-Al-free 47.17 43.14 -4.04 -0.168 0.68932E+04 51 chloritoid-Fe 9.17 5.06 -4.12 -0.275 0.70307E+04 52 chloritoid-Mn 11.40 7.56 -3.85 -0.256 0.65670E+04 54 coesite -2.38 -3.16 -0.78 -0.260 0.13343E+04 61 cristobalite -2.56 -3.16 -0.60 -0.199 0.10196E+04 63 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71234E+04 65 diaspore 2.87 0.74 -2.13 -0.356 0.36445E+04 66 diamond -3.10 -7.84 -4.74 -1.354 0.80913E+04 71 enstatite 17.26 12.27 -4.99 -0.499 0.85225E+04 73 clinoenstatite 17.17 12.27 -4.89 -0.489 0.83541E+04 75 epidote 24.67 22.70 -1.97 -0.095 0.33579E+04 76 clinozoisite 22.81 18.95 -3.86 -0.175 0.65856E+04 77 epidote-Fe 29.84 26.46 -3.38 -0.176 0.57767E+04 78 fayalite 14.05 10.31 -3.73 -0.533 0.63743E+04 79 ferrosilite 11.15 7.16 -3.99 -0.399 0.68204E+04 83 gibbsite 4.08 0.74 -3.34 -0.477 0.57031E+04 84 glaucophane 22.97 20.80 -2.17 -0.059 0.37131E+04 85 glaucophane-Fe 17.28 13.12 -4.15 -0.112 0.70920E+04 86 graphite -3.55 -7.84 -4.29 -1.227 0.73335E+04 87 greenalite 16.14 13.89 -2.25 -0.187 0.38409E+04 90 hematite 12.57 8.99 -3.58 -0.434 0.61114E+04 91 heulandite -5.83 -7.52 -1.69 -0.077 0.28938E+04 95 jadeite 4.22 2.77 -1.44 -0.144 0.24616E+04 97 kalsilite 7.58 3.83 -3.76 -0.536 0.64123E+04 98 kaolinite -1.33 -4.84 -3.50 -0.319 0.59825E+04 101 laumontite 2.88 1.95 -0.93 -0.062 0.15930E+04 102 lawsonite 9.62 8.27 -1.35 -0.090 0.23062E+04 103 leucite 4.12 0.67 -3.45 -0.345 0.58871E+04 105 lizardite 23.24 21.57 -1.68 -0.140 0.28616E+04 107 magnetite 20.09 15.72 -4.37 -0.356 0.74538E+04 108 minnesotaite 10.39 7.58 -2.81 -0.165 0.48032E+04 112 manganosite 14.06 9.23 -4.82 -1.206 0.82370E+04 120 muscovite 2.58 -1.01 -3.59 -0.211 0.61306E+04 121 paragonite 4.24 1.09 -3.14 -0.185 0.53697E+04 122 nepheline 8.34 5.93 -2.41 -0.344 0.41122E+04 128 periclase-Fe 11.63 6.74 -4.89 -1.223 0.83522E+04 134 phlogopite-Na 29.65 27.50 -2.15 -0.119 0.36672E+04 136 prehnite 19.37 18.21 -1.16 -0.068 0.19841E+04 137 prehnite-Fe 22.50 21.96 -0.53 -0.032 0.91139E+03 138 pumpellyite-Fe 46.27 43.89 -2.38 -0.053 0.40561E+04 139 pumpellyite-Mg 48.99 46.45 -2.54 -0.056 0.43398E+04 143 pyrrhotite -4.26 -8.05 -3.78 -1.262 0.64625E+04 144 pyrrhotiteFe0.875 -6.02 -9.44 -3.43 -1.260 0.58498E+04 145 pyroxmangite 7.40 6.08 -1.32 -0.264 0.22575E+04 146 pyrophyllite -6.18 -11.15 -4.98 -0.311 0.84959E+04 147 quartz -2.99 -3.16 -0.17 -0.056 0.28695E+03 152 rhodonite 7.45 6.08 -1.37 -0.274 0.23378E+04 153 sanidine -1.28 -2.49 -1.21 -0.093 0.20677E+04 165 stilpnomelane-Mg 27.44 25.81 -1.63 -0.049 0.27798E+04 171 talc 16.49 15.25 -1.24 -0.073 0.21141E+04 174 tephroite 18.09 15.31 -2.78 -0.396 0.47386E+04 178 tridymite -2.63 -3.16 -0.53 -0.177 0.90693E+03 179 tremolite 47.87 47.42 -0.45 -0.012 0.77500E+03 180 ferroactinolite 38.45 34.62 -3.83 -0.104 0.65454E+04 181 troilite-low -4.41 -8.05 -3.63 -1.211 0.62053E+04 183 vesuvianite 223.47 218.82 -4.65 -0.035 0.79382E+04 187 wairakite 3.95 1.95 -2.00 -0.118 0.34150E+04 188 walstromite 11.51 9.94 -1.56 -0.313 0.26719E+04 189 wollastonite 10.46 9.94 -0.52 -0.103 0.88228E+03 190 pseudo-wollastonite 11.00 9.94 -1.06 -0.211 0.18021E+04 191 zoisite 22.85 18.95 -3.90 -0.177 0.66597E+04 192 akaganeite 7.75 4.49 -3.26 -0.705 0.55682E+04 199 chalcedony -2.80 -3.16 -0.36 -0.118 0.60625E+03 201 montmorillonite-Ca -2.29 -6.17 -3.88 -0.240 0.66178E+04 202 montmorillonite-K -2.24 -6.27 -4.03 -0.247 0.68814E+04 203 montmorillonite-Mg -2.48 -6.79 -4.31 -0.267 0.73676E+04 204 montmorillonite-Na -2.04 -5.57 -3.54 -0.216 0.60363E+04 205 nontronite-Ca 3.21 -0.20 -3.41 -0.221 0.58221E+04 206 nontronite-H 2.53 -2.36 -4.89 -0.328 0.83491E+04 207 nontronite-K 3.34 -0.30 -3.64 -0.233 0.62089E+04 208 nontronite-Mg 3.07 -0.82 -3.90 -0.253 0.66559E+04 209 nontronite-Na 3.52 0.40 -3.12 -0.200 0.53298E+04 224 tobermorite 9.82 7.76 -2.07 -0.564 0.35287E+04 230 alabandite -0.98 -5.55 -4.57 -1.523 0.78002E+04 233 boehmite 4.41 0.74 -3.67 -0.611 0.62614E+04 235 ferrous-oxide 9.81 6.74 -3.08 -0.769 0.52532E+04 240 silica-amorphous -2.09 -3.16 -1.07 -0.355 0.18204E+04 242 an20ab80 2.02 1.35 -0.67 -0.052 0.11471E+04 243 an25ab75 2.65 1.78 -0.87 -0.067 0.14808E+04 244 an30ab70 3.28 2.21 -1.07 -0.082 0.18241E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 20.0000000 g Current total amount of reactant added: 459.9990000 g New total amount of reactant added: 479.9990000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.1586E-10 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 11 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 479.9990000 Water: Moles liquid = 0.5275E+02 kg liquid = 0.9503E+00 Moles total = 0.4949E+02 kg total = 0.8916E+00 Activity = 1.0000 Stoichiometric ionic strength = .1132298E-01 Osmotic coef. = 0.9695 True ionic strength = .2001183E-01 Chg. balance for total moles = -.1586E-10 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.88264E-10 -10.0542 0.74166E-10 -10.1298 0.84027E+00 -0.0756 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.14453E-03 -3.8400 0.12072E-03 -3.9182 0.83522E+00 -0.0782 4 SO4-- 0.68045E-12 -12.1672 0.35339E-12 -12.4517 0.51935E+00 -0.2845 5 HCO3- 0.25183E-06 -6.5989 0.21064E-06 -6.6765 0.83644E+00 -0.0776 6 HS- 0.26834E-04 -4.5713 0.22416E-04 -4.6494 0.83534E+00 -0.0781 7 Al+++ 0.96846E-29 -29.0139 0.22379E-29 -29.6502 0.23108E+00 -0.6362 8 H4SiO4 0.69584E-03 -3.1575 0.69584E-03 -3.1575 0.10000E+01 0.0000 9 Ca++ 0.13492E-06 -6.8699 0.69554E-07 -7.1577 0.51554E+00 -0.2877 10 Mg++ 0.21107E-10 -10.6756 0.10832E-10 -10.9653 0.51318E+00 -0.2897 11 Fe++ 0.58166E-13 -13.2353 0.29883E-13 -13.5246 0.51374E+00 -0.2893 12 K+ 0.15646E-03 -3.8056 0.13090E-03 -3.8831 0.83664E+00 -0.0775 13 Na+ 0.19854E-01 -1.7021 0.16580E-01 -1.7804 0.83507E+00 -0.0783 14 Mn++ 0.18352E-10 -10.7363 0.94360E-11 -11.0252 0.51417E+00 -0.2889 15 HPO4-- 0.45329E-07 -7.3436 0.23545E-07 -7.6281 0.51943E+00 -0.2845 16 HSiO3- 0.10489E-01 -1.9793 0.87606E-02 -2.0575 0.83522E+00 -0.0782 17 Ca(HSiO3)+ 0.16583E-07 -7.7803 0.13877E-07 -7.8577 0.83682E+00 -0.0774 18 Mg(HSiO3)+ 0.32139E-11 -11.4930 0.26895E-11 -11.5703 0.83682E+00 -0.0774 19 NaHSiO3,aq 0.23492E-02 -2.6291 0.23492E-02 -2.6291 0.10000E+01 0.0000 20 AlO+ 0.66142E-16 -16.1795 0.55349E-16 -16.2569 0.83682E+00 -0.0774 22 HAlO2,aq 0.14862E-09 -9.8279 0.14862E-09 -9.8279 0.10000E+01 0.0000 23 AlO2- 0.53206E-05 -5.2740 0.44358E-05 -5.3530 0.83371E+00 -0.0790 24 CH4,aq 0.13023E-04 -4.8853 0.12978E-04 -4.8868 0.99655E+00 -0.0015 25 C2H6,aq 0.24936E-14 -14.6032 0.24850E-14 -14.6047 0.99655E+00 -0.0015 29 CO,aq 0.97171E-17 -17.0125 0.97171E-17 -17.0125 0.10000E+01 0.0000 30 CO2,aq 0.33496E-10 -10.4750 0.33381E-10 -10.4765 0.99655E+00 -0.0015 31 CO3-2 0.47867E-06 -6.3200 0.24807E-06 -6.6054 0.51825E+00 -0.2855 32 CaCO3,aq 0.21635E-09 -9.6648 0.21635E-09 -9.6648 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.44690E-12 -12.3498 0.37398E-12 -12.4272 0.83682E+00 -0.0774 34 CaCl+ 0.16238E-10 -10.7895 0.13588E-10 -10.8668 0.83682E+00 -0.0774 35 CaCl2,aq 0.38969E-15 -15.4093 0.38969E-15 -15.4093 0.10000E+01 0.0000 36 CaOH+ 0.79872E-07 -7.0976 0.66838E-07 -7.1750 0.83682E+00 -0.0774 37 CaSO4,aq 0.78053E-17 -17.1076 0.78053E-17 -17.1076 0.10000E+01 0.0000 38 HCl,aq 0.16406E-14 -14.7850 0.16406E-14 -14.7850 0.10000E+01 0.0000 43 FeCl+ 0.68232E-17 -17.1660 0.57098E-17 -17.2434 0.83682E+00 -0.0774 46 FeO,aq 0.21114E-09 -9.6754 0.21114E-09 -9.6754 0.10000E+01 0.0000 47 FeOH+ 0.15673E-10 -10.8049 0.13115E-10 -10.8822 0.83682E+00 -0.0774 48 HFeO2- 0.35664E-07 -7.4478 0.29787E-07 -7.5260 0.83522E+00 -0.0782 49 FeO+ 0.10982E-16 -16.9593 0.91897E-17 -17.0367 0.83682E+00 -0.0774 51 FeO2- 0.40930E-09 -9.3880 0.34186E-09 -9.4662 0.83522E+00 -0.0782 52 HFeO2,aq 0.32246E-11 -11.4915 0.32246E-11 -11.4915 0.10000E+01 0.0000 53 H2,aq 0.11628E-04 -4.9345 0.11588E-04 -4.9360 0.99655E+00 -0.0015 54 KCl,aq 0.28640E-09 -9.5430 0.28640E-09 -9.5430 0.10000E+01 0.0000 56 KOH,aq 0.75375E-06 -6.1228 0.75375E-06 -6.1228 0.10000E+01 0.0000 57 KSO4- 0.85947E-15 -15.0658 0.71784E-15 -15.1440 0.83522E+00 -0.0782 58 MgCO3,aq 0.84452E-14 -14.0734 0.84452E-14 -14.0734 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.71115E-16 -16.1480 0.59510E-16 -16.2254 0.83682E+00 -0.0774 60 MgCl+ 0.22919E-14 -14.6398 0.19179E-14 -14.7172 0.83682E+00 -0.0774 61 MgOH+ 0.68828E-10 -10.1622 0.57597E-10 -10.2396 0.83682E+00 -0.0774 63 MnO,aq 0.17765E-08 -8.7504 0.17765E-08 -8.7504 0.10000E+01 0.0000 64 MnOH+ 0.45975E-09 -9.3375 0.38472E-09 -9.4148 0.83682E+00 -0.0774 65 MnO2-2 0.20682E-10 -10.6844 0.10719E-10 -10.9699 0.51825E+00 -0.2855 66 HMnO2- 0.20852E-09 -9.6808 0.17416E-09 -9.7590 0.83522E+00 -0.0782 69 MnCl+ 0.83822E-14 -14.0766 0.70144E-14 -14.1540 0.83682E+00 -0.0774 71 NaCl,aq 0.66328E-06 -6.1783 0.66328E-06 -6.1783 0.10000E+01 0.0000 72 NaOH,aq 0.96047E-04 -4.0175 0.96047E-04 -4.0175 0.10000E+01 0.0000 74 OH- 0.93441E-02 -2.0295 0.77903E-02 -2.1084 0.83371E+00 -0.0790 79 HPO3-2 0.16406E-14 -14.7850 0.85026E-15 -15.0704 0.51825E+00 -0.2855 81 H2PO3- 0.15140E-18 -18.8199 0.12645E-18 -18.8981 0.83522E+00 -0.0782 82 H3PO4,aq 0.90580E-18 -18.0430 0.90580E-18 -18.0430 0.10000E+01 0.0000 83 H2PO4- 0.38533E-10 -10.4142 0.32213E-10 -10.4920 0.83601E+00 -0.0778 84 PO4-3 0.10673E-08 -8.9717 0.25902E-09 -9.5867 0.24269E+00 -0.6149 88 HP2O7-3 0.94707E-18 -18.0236 0.21906E-18 -18.6594 0.23131E+00 -0.6358 89 P2O7-4 0.91481E-17 -17.0387 0.70563E-18 -18.1514 0.77134E-01 -1.1128 90 H2S,aq 0.51559E-08 -8.2877 0.51381E-08 -8.2892 0.99655E+00 -0.0015 91 S2-2 0.18539E-14 -14.7319 0.96079E-15 -15.0174 0.51825E+00 -0.2855 97 SO3-2 0.10122E-17 -17.9947 0.53215E-18 -18.2740 0.52574E+00 -0.2792 99 HSO4- 0.30155E-19 -19.5206 0.25259E-19 -19.5976 0.83763E+00 -0.0769 Charge balance for all species = -.1669E-10 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.8826444E-10 -.2230400E-01 -.2244203E+02 0.0000 2 H2O 0.1000000E+01 0.5550489E+02 0.9981999E+06 0.0000 3 Cl- 0.1445323E-03 0.1451959E-03 0.5138687E+01 6.2116 4 SO4-- 0.6804498E-12 -.1593032E-04 -.1527633E+01 7.8078 5 HCO3- 0.2518272E-06 0.1375410E-04 0.8377785E+00 3.4533 6 HS- 0.2683425E-04 0.4276972E-04 0.1412023E+01 5.4803 7 Al+++ 0.9684606E-29 0.5320713E-05 0.1433114E+00 0.7392 8 H4SiO4 0.6958417E-03 0.1353404E-01 0.1298570E+04 -3.1575 9 Ca++ 0.1349155E-06 0.2316034E-06 0.9266073E-02 13.1019 10 Mg++ 0.2110694E-10 0.9315986E-10 0.2260968E-05 9.2943 11 Fe++ 0.5816622E-13 0.3630369E-07 0.2023930E-02 6.7350 12 K+ 0.1564629E-03 0.1572169E-03 0.6136815E+01 6.2467 13 Na+ 0.1985434E-01 0.2230023E-01 0.5117871E+03 8.3494 14 Mn++ 0.1835195E-10 0.2483851E-08 0.1362207E-03 9.2344 15 HPO4-- 0.4532927E-07 0.4643506E-07 0.4449048E-02 12.6315 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.7948058E+01 -.2119464E-01 -.7926863E+01 0.0000000E+00 2 H2O 0.4949127E+02 0.5274420E+02 -.3252932E+01 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.1332791E-01 -.1513798E-04 0.1334305E-01 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.1330241E-01 0.4064245E-04 -.1334305E-01 0.0000000E+00 7 Al+++ 0.1565153E+01 0.5056072E-05 0.1565148E+01 0.0000000E+00 8 H4SiO4 0.4998125E+01 0.1286089E-01 0.4985265E+01 0.0000000E+00 9 Ca++ 0.5520818E+00 0.2200839E-06 0.5520816E+00 0.0000000E+00 10 Mg++ 0.3809516E+00 0.8852630E-10 0.3809516E+00 0.0000000E+00 11 Fe++ 0.3422434E+00 0.3449803E-07 0.3422434E+00 0.0000000E+00 12 K+ 0.1019106E+00 0.1493973E-03 0.1017612E+00 0.0000000E+00 13 Na+ 0.6026758E+00 0.2119106E-01 0.5814847E+00 0.0000000E+00 14 Mn++ 0.8322509E-02 0.2360310E-08 0.8322506E-02 0.0000000E+00 15 HPO4-- 0.2840431E-02 0.4412548E-07 0.2840387E-02 0.0000000E+00 Chg. balance for solid moles: -.1579E-15 Mass of aqueous solution: 0.951916E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 479.9990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 0.5809 -0.236 152.3 2.183 29.06 58.47 andradite 0.5337E-01 -1.273 27.12 1.433 5.174 7.047 grossular 0.1293E-01 -1.888 5.826 0.765 1.111 1.621 apatite-OH 0.9468E-03 -3.024 0.4756 -0.323 0.9073E-01 0.1511 clinochlore 0.6934E-01 -1.159 38.54 1.586 7.353 14.66 daphnite 0.2007E-01 -1.697 14.32 1.156 2.732 4.340 chlorite-Mn 0.1665E-02 -2.779 1.180 0.072 0.2251 0.3761 diopside 0.1685E-01 -1.773 3.649 0.562 0.6960 1.115 hedenbergite 0.4369E-02 -2.360 1.084 0.035 0.2068 0.2969 microcline 0.8928E-01 -1.049 24.85 1.395 4.741 9.707 stilbite 0.3176 -0.498 223.8 2.350 42.70 104.4 stilpnomelane-Fe 0.2496E-01 -1.603 26.90 1.430 5.132 9.292 tr.625ac.25prg.125 0.4796E-02 -2.319 4.100 0.613 0.7821 1.320 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8049E+00 0.8049E+00 1.0000 -0.094 grossular 0.1951E+00 0.1951E+00 1.0000 -0.710 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.7614E+00 0.7614E+00 1.0000 -0.118 daphnite 0.2204E+00 0.2204E+00 1.0000 -0.657 chlorite-Mn 0.1828E-01 0.1828E-01 1.0000 -1.738 diopside 0.7941E+00 0.7941E+00 1.0000 -0.100 hedenbergite 0.2059E+00 0.2059E+00 1.0000 -0.686 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 tr.625ac.25prg.125 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 524.207902 g Volume = 212.799360 cm3 Porosity: -10.2590% V(tot) - V(min): -.19800E+02 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 479.9990000 g log = 2.6812 Original solution: 1000.0103000 g Original solution / Rock added: 2.08 (Water/Rock Ratio), log = 0.3188 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0549 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9677E+00 0.9855 0.1006E+01 0.1021E+01 CO2,gas 0.3362E-08 1.0069 0.3571E-08 0.3547E-08 CH4,gas 0.1789E-01 1.0125 0.1910E-01 0.1887E-01 H2,gas 0.1441E-01 1.0006 0.1521E-01 0.1521E-01 H2S,gas 0.1344E-06 0.9959 0.1412E-06 0.1418E-06 S2,gas 0.3067E-29 1.0000 0.3235E-29 0.3235E-29 CO,gas 0.1373E-13 1.0000 0.1448E-13 0.1448E-13 SO3,gas 0.6968E-48 1.0000 0.7350E-48 0.7350E-48 SO2,gas 0.4124E-27 1.0000 0.4350E-27 0.4350E-27 HCl,gas 0.2744E-17 1.0000 0.2895E-17 0.2895E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 16 albite -0.38 -0.38 0.00 0.000 -0.13080E-10 22 andradite 39.01 39.01 0.00 0.000 0.24265E-10 23 grossular 32.73 32.73 0.00 0.000 0.12132E-10 32 apatite-OH -18.15 -18.15 0.00 0.000 -0.18198E-10 46 clinochlore 39.07 39.07 0.00 0.000 -0.12132E-10 47 daphnite 28.97 28.97 0.00 0.000 -0.12132E-10 48 chlorite-Mn 46.87 46.87 0.00 0.000 -0.36397E-10 67 diopside 16.18 16.18 0.00 0.000 -0.60662E-11 68 hedenbergite 14.21 14.21 0.00 0.000 -0.12132E-10 116 microcline -2.49 -2.49 0.00 0.000 -0.10616E-10 163 stilbite -7.52 -7.52 0.00 0.000 -0.33364E-10 164 stilpnomelane-Fe 13.02 13.02 0.00 0.000 0.21232E-10 245 tr.625ac.25prg.125 45.16 45.16 0.00 0.000 0.24265E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -16.81 -10.15 -3.382 0.17324E+05 -8.447 3 CH4,gas 4.54 1.13 -3.42 -0.854 0.58359E+04 -1.719 4 H2,gas 8.00 4.48 -3.52 -2.010 0.60047E+04 -1.818 5 H2S,gas -6.23 -14.78 -8.55 -4.275 0.14597E+05 -6.850 6 S2,gas -7.34 -38.52 -31.19 -4.798 0.53254E+05 -29.490 7 CO,gas 3.21 -12.32 -15.54 -4.781 0.26531E+05 -13.839 8 SO3,gas 17.12 -32.71 -49.83 -12.458 0.85088E+05 -48.134 9 SO2,gas 0.83 -28.23 -29.06 -7.749 0.49620E+05 -27.361 10 HCl,gas 5.19 -14.05 -19.24 -9.619 0.32847E+05 -17.538 11 acmite 7.71 6.53 -1.18 -0.123 0.20179E+04 15 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 19 spessartine 24.46 19.71 -4.75 -0.237 0.81074E+04 20 analcite 3.32 2.77 -0.55 -0.061 0.93610E+03 26 annite 20.12 17.72 -2.40 -0.134 0.41062E+04 27 phlogopite 27.06 25.40 -1.67 -0.093 0.28484E+04 29 anorthite 12.71 8.27 -4.44 -0.342 0.75896E+04 35 aragonite 0.97 -3.70 -4.67 -1.557 0.79754E+04 36 brucite 12.57 9.29 -3.27 -0.655 0.55907E+04 37 calcite 0.81 -3.70 -4.52 -1.505 0.77111E+04 38 carnegieite-low 9.02 5.93 -3.09 -0.442 0.52798E+04 39 carnegieite-high 10.09 5.93 -4.16 -0.595 0.71068E+04 40 carpholite-Mg 8.58 4.46 -4.12 -0.275 0.70422E+04 41 carpholite-Fe 6.71 1.90 -4.81 -0.321 0.82200E+04 42 celadonite 5.34 3.65 -1.69 -0.099 0.28878E+04 43 celadonite-Fe 3.88 1.09 -2.79 -0.164 0.47562E+04 44 chrysotile 23.89 21.57 -2.32 -0.194 0.39690E+04 49 chlorite-Al-free 47.17 43.14 -4.04 -0.168 0.68932E+04 51 chloritoid-Fe 9.17 5.06 -4.12 -0.275 0.70308E+04 52 chloritoid-Mn 11.40 7.56 -3.85 -0.256 0.65665E+04 54 coesite -2.38 -3.16 -0.78 -0.260 0.13343E+04 61 cristobalite -2.56 -3.16 -0.60 -0.199 0.10196E+04 63 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71234E+04 65 diaspore 2.87 0.74 -2.13 -0.356 0.36445E+04 66 diamond -3.10 -7.84 -4.74 -1.354 0.80897E+04 71 enstatite 17.26 12.27 -4.99 -0.499 0.85225E+04 73 clinoenstatite 17.17 12.27 -4.89 -0.489 0.83541E+04 75 epidote 24.67 22.70 -1.97 -0.095 0.33579E+04 76 clinozoisite 22.81 18.95 -3.86 -0.175 0.65857E+04 77 epidote-Fe 29.84 26.46 -3.38 -0.176 0.57767E+04 78 fayalite 14.05 10.31 -3.73 -0.533 0.63743E+04 79 ferrosilite 11.15 7.16 -3.99 -0.399 0.68203E+04 83 gibbsite 4.08 0.74 -3.34 -0.477 0.57031E+04 84 glaucophane 22.97 20.80 -2.17 -0.059 0.37131E+04 85 glaucophane-Fe 17.28 13.12 -4.15 -0.112 0.70920E+04 86 graphite -3.55 -7.84 -4.29 -1.227 0.73320E+04 87 greenalite 16.14 13.89 -2.25 -0.187 0.38409E+04 90 hematite 12.57 8.99 -3.58 -0.434 0.61114E+04 91 heulandite -5.83 -7.52 -1.69 -0.077 0.28938E+04 95 jadeite 4.22 2.77 -1.44 -0.144 0.24616E+04 97 kalsilite 7.58 3.83 -3.76 -0.536 0.64123E+04 98 kaolinite -1.33 -4.84 -3.50 -0.319 0.59826E+04 101 laumontite 2.88 1.95 -0.93 -0.062 0.15931E+04 102 lawsonite 9.62 8.27 -1.35 -0.090 0.23062E+04 103 leucite 4.12 0.67 -3.45 -0.345 0.58871E+04 105 lizardite 23.24 21.57 -1.68 -0.140 0.28616E+04 107 magnetite 20.09 15.72 -4.37 -0.356 0.74538E+04 108 minnesotaite 10.39 7.58 -2.81 -0.165 0.48032E+04 112 manganosite 14.06 9.23 -4.82 -1.206 0.82364E+04 120 muscovite 2.58 -1.01 -3.59 -0.211 0.61306E+04 121 paragonite 4.24 1.09 -3.14 -0.185 0.53697E+04 122 nepheline 8.34 5.93 -2.41 -0.344 0.41122E+04 128 periclase-Fe 11.63 6.74 -4.89 -1.223 0.83522E+04 134 phlogopite-Na 29.65 27.50 -2.15 -0.119 0.36672E+04 136 prehnite 19.37 18.21 -1.16 -0.068 0.19842E+04 137 prehnite-Fe 22.50 21.96 -0.53 -0.032 0.91140E+03 138 pumpellyite-Fe 46.27 43.89 -2.38 -0.053 0.40562E+04 139 pumpellyite-Mg 48.99 46.45 -2.54 -0.056 0.43399E+04 143 pyrrhotite -4.26 -8.04 -3.78 -1.261 0.64609E+04 144 pyrrhotiteFe0.875 -6.02 -9.44 -3.43 -1.260 0.58482E+04 145 pyroxmangite 7.40 6.08 -1.32 -0.264 0.22569E+04 146 pyrophyllite -6.18 -11.15 -4.98 -0.311 0.84959E+04 147 quartz -2.99 -3.16 -0.17 -0.056 0.28695E+03 152 rhodonite 7.45 6.08 -1.37 -0.274 0.23372E+04 153 sanidine -1.28 -2.49 -1.21 -0.093 0.20677E+04 165 stilpnomelane-Mg 27.44 25.81 -1.63 -0.049 0.27798E+04 171 talc 16.49 15.25 -1.24 -0.073 0.21141E+04 174 tephroite 18.09 15.31 -2.77 -0.396 0.47374E+04 178 tridymite -2.63 -3.16 -0.53 -0.177 0.90693E+03 179 tremolite 47.87 47.42 -0.45 -0.012 0.77499E+03 180 ferroactinolite 38.45 34.62 -3.83 -0.104 0.65454E+04 181 troilite-low -4.41 -8.04 -3.63 -1.211 0.62037E+04 183 vesuvianite 223.47 218.82 -4.65 -0.035 0.79385E+04 187 wairakite 3.95 1.95 -2.00 -0.118 0.34150E+04 188 walstromite 11.51 9.94 -1.56 -0.313 0.26719E+04 189 wollastonite 10.46 9.94 -0.52 -0.103 0.88228E+03 190 pseudo-wollastonite 11.00 9.94 -1.06 -0.211 0.18021E+04 191 zoisite 22.85 18.95 -3.90 -0.177 0.66597E+04 192 akaganeite 7.75 4.49 -3.26 -0.705 0.55682E+04 199 chalcedony -2.80 -3.16 -0.36 -0.118 0.60625E+03 201 montmorillonite-Ca -2.29 -6.17 -3.88 -0.240 0.66178E+04 202 montmorillonite-K -2.24 -6.27 -4.03 -0.247 0.68814E+04 203 montmorillonite-Mg -2.48 -6.79 -4.31 -0.267 0.73676E+04 204 montmorillonite-Na -2.04 -5.57 -3.54 -0.216 0.60363E+04 205 nontronite-Ca 3.21 -0.20 -3.41 -0.221 0.58221E+04 206 nontronite-H 2.53 -2.36 -4.89 -0.328 0.83491E+04 207 nontronite-K 3.34 -0.30 -3.64 -0.233 0.62089E+04 208 nontronite-Mg 3.07 -0.82 -3.90 -0.253 0.66559E+04 209 nontronite-Na 3.52 0.40 -3.12 -0.200 0.53298E+04 224 tobermorite 9.82 7.76 -2.07 -0.564 0.35287E+04 230 alabandite -0.98 -5.54 -4.57 -1.522 0.77980E+04 233 boehmite 4.41 0.74 -3.67 -0.611 0.62615E+04 235 ferrous-oxide 9.81 6.74 -3.08 -0.769 0.52532E+04 240 silica-amorphous -2.09 -3.16 -1.07 -0.355 0.18204E+04 242 an20ab80 2.02 1.35 -0.67 -0.052 0.11471E+04 243 an25ab75 2.65 1.78 -0.87 -0.067 0.14808E+04 244 an30ab70 3.28 2.21 -1.07 -0.082 0.18242E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 20.0000000 g Current total amount of reactant added: 479.9990000 g New total amount of reactant added: 499.9990000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.1586E-10 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 11 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 499.9990000 Water: Moles liquid = 0.5264E+02 kg liquid = 0.9483E+00 Moles total = 0.4924E+02 kg total = 0.8871E+00 Activity = 1.0000 Stoichiometric ionic strength = .1132327E-01 Osmotic coef. = 0.9695 True ionic strength = .2001207E-01 Chg. balance for total moles = -.1586E-10 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.88266E-10 -10.0542 0.74167E-10 -10.1298 0.84027E+00 -0.0756 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.14484E-03 -3.8391 0.12097E-03 -3.9173 0.83522E+00 -0.0782 4 SO4-- 0.68194E-12 -12.1663 0.35417E-12 -12.4508 0.51935E+00 -0.2845 5 HCO3- 0.25238E-06 -6.5979 0.21110E-06 -6.6755 0.83644E+00 -0.0776 6 HS- 0.26891E-04 -4.5704 0.22463E-04 -4.6485 0.83534E+00 -0.0781 7 Al+++ 0.96848E-29 -29.0139 0.22379E-29 -29.6502 0.23108E+00 -0.6362 8 H4SiO4 0.69585E-03 -3.1575 0.69585E-03 -3.1575 0.10000E+01 0.0000 9 Ca++ 0.13492E-06 -6.8699 0.69555E-07 -7.1577 0.51554E+00 -0.2877 10 Mg++ 0.21107E-10 -10.6756 0.10832E-10 -10.9653 0.51318E+00 -0.2897 11 Fe++ 0.58168E-13 -13.2353 0.29883E-13 -13.5246 0.51374E+00 -0.2893 12 K+ 0.15646E-03 -3.8056 0.13090E-03 -3.8830 0.83664E+00 -0.0775 13 Na+ 0.19855E-01 -1.7021 0.16580E-01 -1.7804 0.83506E+00 -0.0783 14 Mn++ 0.18366E-10 -10.7360 0.94431E-11 -11.0249 0.51417E+00 -0.2889 15 HPO4-- 0.45329E-07 -7.3436 0.23545E-07 -7.6281 0.51942E+00 -0.2845 16 HSiO3- 0.10489E-01 -1.9793 0.87606E-02 -2.0575 0.83522E+00 -0.0782 17 Ca(HSiO3)+ 0.16583E-07 -7.7803 0.13877E-07 -7.8577 0.83682E+00 -0.0774 18 Mg(HSiO3)+ 0.32140E-11 -11.4930 0.26895E-11 -11.5703 0.83682E+00 -0.0774 19 NaHSiO3,aq 0.23492E-02 -2.6291 0.23492E-02 -2.6291 0.10000E+01 0.0000 20 AlO+ 0.66141E-16 -16.1795 0.55348E-16 -16.2569 0.83682E+00 -0.0774 22 HAlO2,aq 0.14862E-09 -9.8279 0.14862E-09 -9.8279 0.10000E+01 0.0000 23 AlO2- 0.53204E-05 -5.2741 0.44356E-05 -5.3530 0.83371E+00 -0.0790 24 CH4,aq 0.13051E-04 -4.8844 0.13006E-04 -4.8859 0.99655E+00 -0.0015 25 C2H6,aq 0.25042E-14 -14.6013 0.24955E-14 -14.6028 0.99655E+00 -0.0015 29 CO,aq 0.97382E-17 -17.0115 0.97382E-17 -17.0115 0.10000E+01 0.0000 30 CO2,aq 0.33570E-10 -10.4740 0.33454E-10 -10.4756 0.99655E+00 -0.0015 31 CO3-2 0.47971E-06 -6.3190 0.24861E-06 -6.6045 0.51825E+00 -0.2855 32 CaCO3,aq 0.21682E-09 -9.6639 0.21682E-09 -9.6639 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.44789E-12 -12.3488 0.37480E-12 -12.4262 0.83682E+00 -0.0774 34 CaCl+ 0.16272E-10 -10.7886 0.13617E-10 -10.8659 0.83682E+00 -0.0774 35 CaCl2,aq 0.39135E-15 -15.4074 0.39135E-15 -15.4074 0.10000E+01 0.0000 36 CaOH+ 0.79872E-07 -7.0976 0.66838E-07 -7.1750 0.83682E+00 -0.0774 37 CaSO4,aq 0.78225E-17 -17.1067 0.78225E-17 -17.1067 0.10000E+01 0.0000 38 HCl,aq 0.16441E-14 -14.7841 0.16441E-14 -14.7841 0.10000E+01 0.0000 43 FeCl+ 0.68378E-17 -17.1651 0.57220E-17 -17.2425 0.83682E+00 -0.0774 46 FeO,aq 0.21114E-09 -9.6754 0.21114E-09 -9.6754 0.10000E+01 0.0000 47 FeOH+ 0.15673E-10 -10.8048 0.13115E-10 -10.8822 0.83682E+00 -0.0774 48 HFeO2- 0.35664E-07 -7.4478 0.29787E-07 -7.5260 0.83522E+00 -0.0782 49 FeO+ 0.10982E-16 -16.9593 0.91899E-17 -17.0367 0.83682E+00 -0.0774 51 FeO2- 0.40930E-09 -9.3880 0.34185E-09 -9.4662 0.83522E+00 -0.0782 52 HFeO2,aq 0.32247E-11 -11.4915 0.32247E-11 -11.4915 0.10000E+01 0.0000 53 H2,aq 0.11628E-04 -4.9345 0.11588E-04 -4.9360 0.99655E+00 -0.0015 54 KCl,aq 0.28701E-09 -9.5421 0.28701E-09 -9.5421 0.10000E+01 0.0000 56 KOH,aq 0.75375E-06 -6.1228 0.75375E-06 -6.1228 0.10000E+01 0.0000 57 KSO4- 0.86136E-15 -15.0648 0.71942E-15 -15.1430 0.83522E+00 -0.0782 58 MgCO3,aq 0.84637E-14 -14.0724 0.84637E-14 -14.0724 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.71271E-16 -16.1471 0.59641E-16 -16.2245 0.83682E+00 -0.0774 60 MgCl+ 0.22967E-14 -14.6389 0.19219E-14 -14.7163 0.83682E+00 -0.0774 61 MgOH+ 0.68828E-10 -10.1622 0.57597E-10 -10.2396 0.83682E+00 -0.0774 63 MnO,aq 0.17778E-08 -8.7501 0.17778E-08 -8.7501 0.10000E+01 0.0000 64 MnOH+ 0.46009E-09 -9.3372 0.38501E-09 -9.4145 0.83682E+00 -0.0774 65 MnO2-2 0.20697E-10 -10.6841 0.10726E-10 -10.9696 0.51825E+00 -0.2855 66 HMnO2- 0.20867E-09 -9.6805 0.17429E-09 -9.7587 0.83522E+00 -0.0782 69 MnCl+ 0.84063E-14 -14.0754 0.70345E-14 -14.1528 0.83682E+00 -0.0774 71 NaCl,aq 0.66469E-06 -6.1774 0.66469E-06 -6.1774 0.10000E+01 0.0000 72 NaOH,aq 0.96047E-04 -4.0175 0.96047E-04 -4.0175 0.10000E+01 0.0000 74 OH- 0.93440E-02 -2.0295 0.77902E-02 -2.1085 0.83371E+00 -0.0790 79 HPO3-2 0.16406E-14 -14.7850 0.85024E-15 -15.0705 0.51825E+00 -0.2855 81 H2PO3- 0.15140E-18 -18.8199 0.12645E-18 -18.8981 0.83522E+00 -0.0782 82 H3PO4,aq 0.90581E-18 -18.0430 0.90581E-18 -18.0430 0.10000E+01 0.0000 83 H2PO4- 0.38533E-10 -10.4142 0.32214E-10 -10.4920 0.83601E+00 -0.0778 84 PO4-3 0.10672E-08 -8.9717 0.25901E-09 -9.5867 0.24269E+00 -0.6149 88 HP2O7-3 0.94707E-18 -18.0236 0.21906E-18 -18.6594 0.23131E+00 -0.6358 89 P2O7-4 0.91481E-17 -17.0387 0.70562E-18 -18.1514 0.77133E-01 -1.1128 90 H2S,aq 0.51669E-08 -8.2868 0.51490E-08 -8.2883 0.99655E+00 -0.0015 91 S2-2 0.18618E-14 -14.7301 0.96489E-15 -15.0155 0.51825E+00 -0.2855 97 SO3-2 0.10144E-17 -17.9938 0.53331E-18 -18.2730 0.52574E+00 -0.2792 99 HSO4- 0.30221E-19 -19.5197 0.25314E-19 -19.5966 0.83763E+00 -0.0769 Charge balance for all species = -.1672E-10 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.8826553E-10 -.2230390E-01 -.2244193E+02 0.0000 2 H2O 0.1000000E+01 0.5550489E+02 0.9981999E+06 0.0000 3 Cl- 0.1448385E-03 0.1455034E-03 0.5149571E+01 6.2125 4 SO4-- 0.6819400E-12 -.1595780E-04 -.1530268E+01 7.8088 5 HCO3- 0.2523774E-06 0.1378323E-04 0.8395530E+00 3.4543 6 HS- 0.2689108E-04 0.4285405E-04 0.1414807E+01 5.4813 7 Al+++ 0.9684761E-29 0.5320519E-05 0.1433062E+00 0.7392 8 H4SiO4 0.6958477E-03 0.1353405E-01 0.1298570E+04 -3.1575 9 Ca++ 0.1349178E-06 0.2316067E-06 0.9266206E-02 13.1019 10 Mg++ 0.2110729E-10 0.9316049E-10 0.2260983E-05 9.2943 11 Fe++ 0.5816755E-13 0.3630319E-07 0.2023902E-02 6.7350 12 K+ 0.1564648E-03 0.1572188E-03 0.6136889E+01 6.2467 13 Na+ 0.1985458E-01 0.2230049E-01 0.5117931E+03 8.3494 14 Mn++ 0.1836577E-10 0.2485660E-08 0.1363199E-03 9.2347 15 HPO4-- 0.4532904E-07 0.4643482E-07 0.4449024E-02 12.6315 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.8279228E+01 -.2114975E-01 -.8258078E+01 0.0000000E+00 2 H2O 0.4924056E+02 0.5263271E+02 -.3392157E+01 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.1388218E-01 -.1513204E-04 0.1389731E-01 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.1385668E-01 0.4063651E-04 -.1389731E-01 0.0000000E+00 7 Al+++ 0.1630368E+01 0.5045202E-05 0.1630363E+01 0.0000000E+00 8 H4SiO4 0.5206381E+01 0.1283371E-01 0.5193547E+01 0.0000000E+00 9 Ca++ 0.5750846E+00 0.2196219E-06 0.5750844E+00 0.0000000E+00 10 Mg++ 0.3968246E+00 0.8833978E-10 0.3968246E+00 0.0000000E+00 11 Fe++ 0.3565036E+00 0.3442463E-07 0.3565035E+00 0.0000000E+00 12 K+ 0.1061569E+00 0.1490833E-03 0.1060078E+00 0.0000000E+00 13 Na+ 0.6277806E+00 0.2114652E-01 0.6066341E+00 0.0000000E+00 14 Mn++ 0.8669281E-02 0.2357036E-08 0.8669278E-02 0.0000000E+00 15 HPO4-- 0.2958782E-02 0.4403199E-07 0.2958738E-02 0.0000000E+00 Chg. balance for solid moles: -.5568E-15 Mass of aqueous solution: 0.949904E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 499.9990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 0.6060 -0.218 158.9 2.201 29.10 61.00 andradite 0.5559E-01 -1.255 28.25 1.451 5.173 7.339 grossular 0.1347E-01 -1.871 6.068 0.783 1.111 1.688 apatite-OH 0.9862E-03 -3.006 0.4954 -0.305 0.9073E-01 0.1574 clinochlore 0.7218E-01 -1.142 40.12 1.603 7.347 15.26 daphnite 0.2089E-01 -1.680 14.91 1.173 2.730 4.517 chlorite-Mn 0.1734E-02 -2.761 1.229 0.090 0.2251 0.3917 diopside 0.1794E-01 -1.746 3.884 0.589 0.7113 1.187 hedenbergite 0.4651E-02 -2.332 1.154 0.062 0.2113 0.3160 microcline 0.9301E-01 -1.031 25.89 1.413 4.741 10.11 stilbite 0.3305 -0.481 232.9 2.367 42.65 108.6 stilpnomelane-Fe 0.2600E-01 -1.585 28.03 1.448 5.133 9.682 tr.625ac.25prg.125 0.4963E-02 -2.304 4.242 0.628 0.7769 1.365 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8050E+00 0.8050E+00 1.0000 -0.094 grossular 0.1950E+00 0.1950E+00 1.0000 -0.710 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.7613E+00 0.7613E+00 1.0000 -0.118 daphnite 0.2204E+00 0.2204E+00 1.0000 -0.657 chlorite-Mn 0.1829E-01 0.1829E-01 1.0000 -1.738 diopside 0.7941E+00 0.7941E+00 1.0000 -0.100 hedenbergite 0.2059E+00 0.2059E+00 1.0000 -0.686 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 tr.625ac.25prg.125 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 546.058030 g Volume = 221.639973 cm3 Porosity: -10.2689% V(tot) - V(min): -.20640E+02 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 499.9990000 g log = 2.6990 Original solution: 1000.0103000 g Original solution / Rock added: 2.00 (Water/Rock Ratio), log = 0.3010 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0549 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9677E+00 0.9855 0.1006E+01 0.1021E+01 CO2,gas 0.3370E-08 1.0069 0.3579E-08 0.3555E-08 CH4,gas 0.1792E-01 1.0125 0.1914E-01 0.1891E-01 H2,gas 0.1441E-01 1.0006 0.1521E-01 0.1520E-01 H2S,gas 0.1347E-06 0.9959 0.1415E-06 0.1421E-06 S2,gas 0.3080E-29 1.0000 0.3249E-29 0.3249E-29 CO,gas 0.1376E-13 1.0000 0.1451E-13 0.1451E-13 SO3,gas 0.6983E-48 1.0000 0.7366E-48 0.7366E-48 SO2,gas 0.4133E-27 1.0000 0.4360E-27 0.4360E-27 HCl,gas 0.2750E-17 1.0000 0.2901E-17 0.2901E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 16 albite -0.38 -0.38 0.00 0.000 -0.94784E-12 22 andradite 39.01 39.01 0.00 0.000 0.12132E-10 23 grossular 32.73 32.73 0.00 0.000 0.24265E-10 32 apatite-OH -18.15 -18.15 0.00 0.000 0.00000E+00 46 clinochlore 39.07 39.07 0.00 0.000 0.12132E-10 47 daphnite 28.97 28.97 0.00 0.000 0.60662E-11 48 chlorite-Mn 46.87 46.87 0.00 0.000 0.00000E+00 67 diopside 16.18 16.18 0.00 0.000 0.00000E+00 68 hedenbergite 14.21 14.21 0.00 0.000 0.30331E-11 116 microcline -2.49 -2.49 0.00 0.000 -0.10616E-10 163 stilbite -7.52 -7.52 0.00 0.000 -0.90992E-11 164 stilpnomelane-Fe 13.02 13.02 0.00 0.000 0.69761E-10 245 tr.625ac.25prg.125 45.16 45.16 0.00 0.000 0.00000E+00 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -16.81 -10.15 -3.382 0.17323E+05 -8.446 3 CH4,gas 4.54 1.13 -3.42 -0.854 0.58343E+04 -1.718 4 H2,gas 8.00 4.48 -3.52 -2.010 0.60047E+04 -1.818 5 H2S,gas -6.23 -14.78 -8.55 -4.274 0.14596E+05 -6.849 6 S2,gas -7.34 -38.52 -31.19 -4.798 0.53251E+05 -29.488 7 CO,gas 3.21 -12.32 -15.54 -4.781 0.26529E+05 -13.838 8 SO3,gas 17.12 -32.71 -49.83 -12.458 0.85086E+05 -48.133 9 SO2,gas 0.83 -28.23 -29.06 -7.749 0.49618E+05 -27.361 10 HCl,gas 5.19 -14.05 -19.24 -9.618 0.32846E+05 -17.537 11 acmite 7.71 6.53 -1.18 -0.123 0.20179E+04 15 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 19 spessartine 24.46 19.71 -4.75 -0.237 0.81058E+04 20 analcite 3.32 2.77 -0.55 -0.061 0.93611E+03 26 annite 20.12 17.72 -2.40 -0.134 0.41062E+04 27 phlogopite 27.06 25.40 -1.67 -0.093 0.28485E+04 29 anorthite 12.71 8.27 -4.44 -0.342 0.75896E+04 35 aragonite 0.97 -3.70 -4.67 -1.557 0.79738E+04 36 brucite 12.57 9.29 -3.27 -0.655 0.55907E+04 37 calcite 0.81 -3.70 -4.52 -1.505 0.77095E+04 38 carnegieite-low 9.02 5.93 -3.09 -0.442 0.52798E+04 39 carnegieite-high 10.09 5.93 -4.16 -0.595 0.71068E+04 40 carpholite-Mg 8.58 4.46 -4.12 -0.275 0.70422E+04 41 carpholite-Fe 6.71 1.90 -4.81 -0.321 0.82201E+04 42 celadonite 5.34 3.65 -1.69 -0.099 0.28878E+04 43 celadonite-Fe 3.88 1.09 -2.79 -0.164 0.47562E+04 44 chrysotile 23.89 21.57 -2.32 -0.194 0.39690E+04 49 chlorite-Al-free 47.17 43.14 -4.04 -0.168 0.68932E+04 51 chloritoid-Fe 9.17 5.06 -4.12 -0.275 0.70308E+04 52 chloritoid-Mn 11.40 7.56 -3.85 -0.256 0.65660E+04 54 coesite -2.38 -3.16 -0.78 -0.260 0.13343E+04 61 cristobalite -2.56 -3.16 -0.60 -0.199 0.10196E+04 63 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71234E+04 65 diaspore 2.87 0.74 -2.13 -0.356 0.36446E+04 66 diamond -3.10 -7.84 -4.74 -1.353 0.80881E+04 71 enstatite 17.26 12.27 -4.99 -0.499 0.85225E+04 73 clinoenstatite 17.17 12.27 -4.89 -0.489 0.83541E+04 75 epidote 24.67 22.70 -1.97 -0.095 0.33579E+04 76 clinozoisite 22.81 18.95 -3.86 -0.175 0.65857E+04 77 epidote-Fe 29.84 26.46 -3.38 -0.176 0.57767E+04 78 fayalite 14.05 10.31 -3.73 -0.533 0.63743E+04 79 ferrosilite 11.15 7.16 -3.99 -0.399 0.68203E+04 83 gibbsite 4.08 0.74 -3.34 -0.477 0.57031E+04 84 glaucophane 22.97 20.80 -2.17 -0.059 0.37132E+04 85 glaucophane-Fe 17.28 13.12 -4.15 -0.112 0.70920E+04 86 graphite -3.55 -7.84 -4.29 -1.227 0.73304E+04 87 greenalite 16.14 13.89 -2.25 -0.187 0.38409E+04 90 hematite 12.57 8.99 -3.58 -0.434 0.61113E+04 91 heulandite -5.83 -7.52 -1.69 -0.077 0.28938E+04 95 jadeite 4.22 2.77 -1.44 -0.144 0.24616E+04 97 kalsilite 7.58 3.83 -3.76 -0.536 0.64123E+04 98 kaolinite -1.33 -4.84 -3.50 -0.319 0.59826E+04 101 laumontite 2.88 1.95 -0.93 -0.062 0.15931E+04 102 lawsonite 9.62 8.27 -1.35 -0.090 0.23063E+04 103 leucite 4.12 0.67 -3.45 -0.345 0.58871E+04 105 lizardite 23.24 21.57 -1.68 -0.140 0.28617E+04 107 magnetite 20.09 15.72 -4.37 -0.356 0.74538E+04 108 minnesotaite 10.39 7.58 -2.81 -0.165 0.48032E+04 112 manganosite 14.06 9.23 -4.82 -1.206 0.82359E+04 120 muscovite 2.58 -1.01 -3.59 -0.211 0.61307E+04 121 paragonite 4.24 1.09 -3.14 -0.185 0.53698E+04 122 nepheline 8.34 5.93 -2.41 -0.344 0.41122E+04 128 periclase-Fe 11.63 6.74 -4.89 -1.223 0.83522E+04 134 phlogopite-Na 29.65 27.50 -2.15 -0.119 0.36673E+04 136 prehnite 19.37 18.21 -1.16 -0.068 0.19842E+04 137 prehnite-Fe 22.50 21.96 -0.53 -0.032 0.91140E+03 138 pumpellyite-Fe 46.27 43.89 -2.38 -0.053 0.40563E+04 139 pumpellyite-Mg 48.99 46.45 -2.54 -0.056 0.43400E+04 143 pyrrhotite -4.26 -8.04 -3.78 -1.261 0.64594E+04 144 pyrrhotiteFe0.875 -6.02 -9.44 -3.42 -1.259 0.58466E+04 145 pyroxmangite 7.40 6.08 -1.32 -0.264 0.22564E+04 146 pyrophyllite -6.18 -11.15 -4.98 -0.311 0.84959E+04 147 quartz -2.99 -3.16 -0.17 -0.056 0.28694E+03 152 rhodonite 7.45 6.08 -1.37 -0.274 0.23366E+04 153 sanidine -1.28 -2.49 -1.21 -0.093 0.20677E+04 165 stilpnomelane-Mg 27.44 25.81 -1.63 -0.049 0.27799E+04 171 talc 16.49 15.25 -1.24 -0.073 0.21141E+04 174 tephroite 18.09 15.31 -2.77 -0.396 0.47363E+04 178 tridymite -2.63 -3.16 -0.53 -0.177 0.90692E+03 179 tremolite 47.87 47.42 -0.45 -0.012 0.77499E+03 180 ferroactinolite 38.45 34.62 -3.83 -0.104 0.65454E+04 181 troilite-low -4.41 -8.04 -3.63 -1.211 0.62022E+04 183 vesuvianite 223.47 218.82 -4.65 -0.035 0.79387E+04 187 wairakite 3.95 1.95 -2.00 -0.118 0.34150E+04 188 walstromite 11.51 9.94 -1.56 -0.313 0.26719E+04 189 wollastonite 10.46 9.94 -0.52 -0.103 0.88228E+03 190 pseudo-wollastonite 11.00 9.94 -1.06 -0.211 0.18021E+04 191 zoisite 22.85 18.95 -3.90 -0.177 0.66598E+04 192 akaganeite 7.75 4.49 -3.26 -0.705 0.55682E+04 199 chalcedony -2.80 -3.16 -0.36 -0.118 0.60624E+03 201 montmorillonite-Ca -2.29 -6.17 -3.88 -0.240 0.66178E+04 202 montmorillonite-K -2.24 -6.27 -4.03 -0.247 0.68814E+04 203 montmorillonite-Mg -2.48 -6.79 -4.31 -0.267 0.73676E+04 204 montmorillonite-Na -2.04 -5.57 -3.54 -0.216 0.60363E+04 205 nontronite-Ca 3.21 -0.20 -3.41 -0.221 0.58221E+04 206 nontronite-H 2.53 -2.36 -4.89 -0.328 0.83491E+04 207 nontronite-K 3.34 -0.30 -3.64 -0.233 0.62089E+04 208 nontronite-Mg 3.07 -0.82 -3.90 -0.253 0.66559E+04 209 nontronite-Na 3.52 0.40 -3.12 -0.200 0.53298E+04 224 tobermorite 9.82 7.76 -2.07 -0.564 0.35287E+04 230 alabandite -0.98 -5.54 -4.57 -1.522 0.77959E+04 233 boehmite 4.41 0.74 -3.67 -0.611 0.62615E+04 235 ferrous-oxide 9.81 6.74 -3.08 -0.769 0.52532E+04 240 silica-amorphous -2.09 -3.16 -1.07 -0.355 0.18204E+04 242 an20ab80 2.02 1.35 -0.67 -0.052 0.11471E+04 243 an25ab75 2.65 1.78 -0.87 -0.067 0.14808E+04 244 an30ab70 3.28 2.21 -1.07 -0.082 0.18242E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 20.0000000 g Current total amount of reactant added: 499.9990000 g New total amount of reactant added: 519.9990000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.1586E-10 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 11 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 519.9990000 Water: Moles liquid = 0.5252E+02 kg liquid = 0.9462E+00 Moles total = 0.4899E+02 kg total = 0.8826E+00 Activity = 1.0000 Stoichiometric ionic strength = .1132356E-01 Osmotic coef. = 0.9694 True ionic strength = .2001232E-01 Chg. balance for total moles = -.1586E-10 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.88267E-10 -10.0542 0.74167E-10 -10.1298 0.84027E+00 -0.0756 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.14515E-03 -3.8382 0.12123E-03 -3.9164 0.83522E+00 -0.0782 4 SO4-- 0.68343E-12 -12.1653 0.35494E-12 -12.4498 0.51935E+00 -0.2845 5 HCO3- 0.25293E-06 -6.5970 0.21156E-06 -6.6746 0.83644E+00 -0.0776 6 HS- 0.26948E-04 -4.5695 0.22511E-04 -4.6476 0.83534E+00 -0.0781 7 Al+++ 0.96849E-29 -29.0139 0.22379E-29 -29.6502 0.23107E+00 -0.6363 8 H4SiO4 0.69585E-03 -3.1575 0.69585E-03 -3.1575 0.10000E+01 0.0000 9 Ca++ 0.13492E-06 -6.8699 0.69556E-07 -7.1577 0.51554E+00 -0.2877 10 Mg++ 0.21108E-10 -10.6756 0.10832E-10 -10.9653 0.51318E+00 -0.2897 11 Fe++ 0.58169E-13 -13.2353 0.29884E-13 -13.5246 0.51374E+00 -0.2893 12 K+ 0.15647E-03 -3.8056 0.13091E-03 -3.8830 0.83664E+00 -0.0775 13 Na+ 0.19855E-01 -1.7021 0.16580E-01 -1.7804 0.83506E+00 -0.0783 14 Mn++ 0.18379E-10 -10.7357 0.94497E-11 -11.0246 0.51417E+00 -0.2889 15 HPO4-- 0.45329E-07 -7.3436 0.23545E-07 -7.6281 0.51942E+00 -0.2845 16 HSiO3- 0.10489E-01 -1.9793 0.87605E-02 -2.0575 0.83522E+00 -0.0782 17 Ca(HSiO3)+ 0.16583E-07 -7.7803 0.13877E-07 -7.8577 0.83681E+00 -0.0774 18 Mg(HSiO3)+ 0.32140E-11 -11.4930 0.26895E-11 -11.5703 0.83681E+00 -0.0774 19 NaHSiO3,aq 0.23492E-02 -2.6291 0.23492E-02 -2.6291 0.10000E+01 0.0000 20 AlO+ 0.66140E-16 -16.1795 0.55347E-16 -16.2569 0.83681E+00 -0.0774 22 HAlO2,aq 0.14861E-09 -9.8279 0.14861E-09 -9.8279 0.10000E+01 0.0000 23 AlO2- 0.53202E-05 -5.2741 0.44355E-05 -5.3531 0.83371E+00 -0.0790 24 CH4,aq 0.13079E-04 -4.8834 0.13033E-04 -4.8849 0.99655E+00 -0.0015 25 C2H6,aq 0.25148E-14 -14.5995 0.25062E-14 -14.6010 0.99655E+00 -0.0015 29 CO,aq 0.97594E-17 -17.0106 0.97594E-17 -17.0106 0.10000E+01 0.0000 30 CO2,aq 0.33644E-10 -10.4731 0.33528E-10 -10.4746 0.99655E+00 -0.0015 31 CO3-2 0.48076E-06 -6.3181 0.24915E-06 -6.6035 0.51825E+00 -0.2855 32 CaCO3,aq 0.21730E-09 -9.6629 0.21730E-09 -9.6629 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.44887E-12 -12.3479 0.37562E-12 -12.4252 0.83681E+00 -0.0774 34 CaCl+ 0.16307E-10 -10.7876 0.13646E-10 -10.8650 0.83681E+00 -0.0774 35 CaCl2,aq 0.39302E-15 -15.4056 0.39302E-15 -15.4056 0.10000E+01 0.0000 36 CaOH+ 0.79872E-07 -7.0976 0.66838E-07 -7.1750 0.83681E+00 -0.0774 37 CaSO4,aq 0.78397E-17 -17.1057 0.78397E-17 -17.1057 0.10000E+01 0.0000 38 HCl,aq 0.16476E-14 -14.7831 0.16476E-14 -14.7831 0.10000E+01 0.0000 43 FeCl+ 0.68524E-17 -17.1642 0.57342E-17 -17.2415 0.83681E+00 -0.0774 46 FeO,aq 0.21114E-09 -9.6754 0.21114E-09 -9.6754 0.10000E+01 0.0000 47 FeOH+ 0.15673E-10 -10.8048 0.13116E-10 -10.8822 0.83681E+00 -0.0774 48 HFeO2- 0.35663E-07 -7.4478 0.29787E-07 -7.5260 0.83522E+00 -0.0782 49 FeO+ 0.10982E-16 -16.9593 0.91900E-17 -17.0367 0.83681E+00 -0.0774 51 FeO2- 0.40930E-09 -9.3880 0.34185E-09 -9.4662 0.83522E+00 -0.0782 52 HFeO2,aq 0.32247E-11 -11.4915 0.32247E-11 -11.4915 0.10000E+01 0.0000 53 H2,aq 0.11628E-04 -4.9345 0.11587E-04 -4.9360 0.99655E+00 -0.0015 54 KCl,aq 0.28762E-09 -9.5412 0.28762E-09 -9.5412 0.10000E+01 0.0000 56 KOH,aq 0.75375E-06 -6.1228 0.75375E-06 -6.1228 0.10000E+01 0.0000 57 KSO4- 0.86325E-15 -15.0639 0.72100E-15 -15.1421 0.83522E+00 -0.0782 58 MgCO3,aq 0.84822E-14 -14.0715 0.84822E-14 -14.0715 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.71428E-16 -16.1461 0.59772E-16 -16.2235 0.83681E+00 -0.0774 60 MgCl+ 0.23016E-14 -14.6380 0.19261E-14 -14.7153 0.83681E+00 -0.0774 61 MgOH+ 0.68829E-10 -10.1622 0.57597E-10 -10.2396 0.83681E+00 -0.0774 63 MnO,aq 0.17790E-08 -8.7498 0.17790E-08 -8.7498 0.10000E+01 0.0000 64 MnOH+ 0.46040E-09 -9.3369 0.38527E-09 -9.4142 0.83681E+00 -0.0774 65 MnO2-2 0.20710E-10 -10.6838 0.10733E-10 -10.9693 0.51825E+00 -0.2855 66 HMnO2- 0.20881E-09 -9.6802 0.17440E-09 -9.7585 0.83522E+00 -0.0782 69 MnCl+ 0.84299E-14 -14.0742 0.70543E-14 -14.1515 0.83681E+00 -0.0774 71 NaCl,aq 0.66611E-06 -6.1765 0.66611E-06 -6.1765 0.10000E+01 0.0000 72 NaOH,aq 0.96047E-04 -4.0175 0.96047E-04 -4.0175 0.10000E+01 0.0000 74 OH- 0.93439E-02 -2.0295 0.77901E-02 -2.1085 0.83371E+00 -0.0790 79 HPO3-2 0.16406E-14 -14.7850 0.85021E-15 -15.0705 0.51825E+00 -0.2855 81 H2PO3- 0.15140E-18 -18.8199 0.12645E-18 -18.8981 0.83522E+00 -0.0782 82 H3PO4,aq 0.90582E-18 -18.0430 0.90582E-18 -18.0430 0.10000E+01 0.0000 83 H2PO4- 0.38533E-10 -10.4142 0.32214E-10 -10.4920 0.83601E+00 -0.0778 84 PO4-3 0.10672E-08 -8.9717 0.25901E-09 -9.5867 0.24269E+00 -0.6149 88 HP2O7-3 0.94707E-18 -18.0236 0.21906E-18 -18.6594 0.23130E+00 -0.6358 89 P2O7-4 0.91480E-17 -17.0387 0.70561E-18 -18.1514 0.77132E-01 -1.1128 90 H2S,aq 0.51779E-08 -8.2858 0.51600E-08 -8.2873 0.99655E+00 -0.0015 91 S2-2 0.18698E-14 -14.7282 0.96900E-15 -15.0137 0.51825E+00 -0.2855 97 SO3-2 0.10166E-17 -17.9929 0.53446E-18 -18.2721 0.52574E+00 -0.2792 99 HSO4- 0.30288E-19 -19.5187 0.25370E-19 -19.5957 0.83763E+00 -0.0769 Charge balance for all species = -.1676E-10 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.8826659E-10 -.2230379E-01 -.2244182E+02 0.0000 2 H2O 0.1000000E+01 0.5550489E+02 0.9981999E+06 0.0000 3 Cl- 0.1451459E-03 0.1458123E-03 0.5160502E+01 6.2134 4 SO4-- 0.6834325E-12 -.1598541E-04 -.1532916E+01 7.8097 5 HCO3- 0.2529286E-06 0.1381249E-04 0.8413351E+00 3.4552 6 HS- 0.2694816E-04 0.4293875E-04 0.1417603E+01 5.4822 7 Al+++ 0.9684931E-29 0.5320336E-05 0.1433012E+00 0.7392 8 H4SiO4 0.6958532E-03 0.1353404E-01 0.1298570E+04 -3.1575 9 Ca++ 0.1349202E-06 0.2316101E-06 0.9266343E-02 13.1019 10 Mg++ 0.2110765E-10 0.9316124E-10 0.2261001E-05 9.2943 11 Fe++ 0.5816887E-13 0.3630269E-07 0.2023874E-02 6.7350 12 K+ 0.1564667E-03 0.1572207E-03 0.6136963E+01 6.2467 13 Na+ 0.1985482E-01 0.2230075E-01 0.5117991E+03 8.3494 14 Mn++ 0.1837858E-10 0.2487332E-08 0.1364116E-03 9.2350 15 HPO4-- 0.4532877E-07 0.4643453E-07 0.4448997E-02 12.6315 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.8610398E+01 -.2110485E-01 -.8589294E+01 0.0000000E+00 2 H2O 0.4898985E+02 0.5252123E+02 -.3531381E+01 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.1443645E-01 -.1512611E-04 0.1445158E-01 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.1441094E-01 0.4063058E-04 -.1445158E-01 0.0000000E+00 7 Al+++ 0.1695582E+01 0.5034342E-05 0.1695577E+01 0.0000000E+00 8 H4SiO4 0.5414637E+01 0.1280652E-01 0.5401830E+01 0.0000000E+00 9 Ca++ 0.5980875E+00 0.2191600E-06 0.5980873E+00 0.0000000E+00 10 Mg++ 0.4126976E+00 0.8815337E-10 0.4126976E+00 0.0000000E+00 11 Fe++ 0.3707638E+00 0.3435125E-07 0.3707637E+00 0.0000000E+00 12 K+ 0.1104032E+00 0.1487693E-03 0.1102544E+00 0.0000000E+00 13 Na+ 0.6528855E+00 0.2110198E-01 0.6317835E+00 0.0000000E+00 14 Mn++ 0.9016053E-02 0.2353626E-08 0.9016050E-02 0.0000000E+00 15 HPO4-- 0.3077134E-02 0.4393845E-07 0.3077090E-02 0.0000000E+00 Chg. balance for solid moles: -.4285E-15 Mass of aqueous solution: 0.947892E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 519.9990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 0.6311 -0.200 165.5 2.219 29.14 63.53 andradite 0.5781E-01 -1.238 29.38 1.468 5.173 7.632 grossular 0.1401E-01 -1.854 6.309 0.800 1.111 1.756 apatite-OH 0.1026E-02 -2.989 0.5152 -0.288 0.9072E-01 0.1637 clinochlore 0.7502E-01 -1.125 41.70 1.620 7.342 15.86 daphnite 0.2171E-01 -1.663 15.49 1.190 2.728 4.695 chlorite-Mn 0.1803E-02 -2.744 1.278 0.107 0.2251 0.4074 diopside 0.1902E-01 -1.721 4.120 0.615 0.7254 1.259 hedenbergite 0.4933E-02 -2.307 1.224 0.088 0.2155 0.3352 microcline 0.9673E-01 -1.014 26.92 1.430 4.741 10.52 stilbite 0.3433 -0.464 241.9 2.384 42.60 112.8 stilpnomelane-Fe 0.2705E-01 -1.568 29.16 1.465 5.134 10.07 tr.625ac.25prg.125 0.5130E-02 -2.290 4.385 0.642 0.7721 1.411 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8050E+00 0.8050E+00 1.0000 -0.094 grossular 0.1950E+00 0.1950E+00 1.0000 -0.710 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.7613E+00 0.7613E+00 1.0000 -0.118 daphnite 0.2204E+00 0.2204E+00 1.0000 -0.657 chlorite-Mn 0.1830E-01 0.1830E-01 1.0000 -1.738 diopside 0.7941E+00 0.7941E+00 1.0000 -0.100 hedenbergite 0.2059E+00 0.2059E+00 1.0000 -0.686 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 tr.625ac.25prg.125 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 567.908159 g Volume = 230.480585 cm3 Porosity: -10.2780% V(tot) - V(min): -.21481E+02 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 519.9990000 g log = 2.7160 Original solution: 1000.0103000 g Original solution / Rock added: 1.92 (Water/Rock Ratio), log = 0.2840 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0549 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9676E+00 0.9855 0.1006E+01 0.1021E+01 CO2,gas 0.3377E-08 1.0069 0.3587E-08 0.3562E-08 CH4,gas 0.1796E-01 1.0125 0.1918E-01 0.1895E-01 H2,gas 0.1441E-01 1.0006 0.1521E-01 0.1520E-01 H2S,gas 0.1350E-06 0.9959 0.1418E-06 0.1424E-06 S2,gas 0.3093E-29 1.0000 0.3263E-29 0.3263E-29 CO,gas 0.1379E-13 1.0000 0.1454E-13 0.1454E-13 SO3,gas 0.6998E-48 1.0000 0.7382E-48 0.7382E-48 SO2,gas 0.4142E-27 1.0000 0.4369E-27 0.4369E-27 HCl,gas 0.2756E-17 1.0000 0.2907E-17 0.2907E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 16 albite -0.38 -0.38 0.00 0.000 0.23317E-10 22 andradite 39.01 39.01 0.00 0.000 0.12132E-10 23 grossular 32.73 32.73 0.00 0.000 0.12132E-10 32 apatite-OH -18.15 -18.15 0.00 0.000 0.12132E-10 46 clinochlore 39.07 39.07 0.00 0.000 0.36397E-10 47 daphnite 28.97 28.97 0.00 0.000 0.60662E-10 48 chlorite-Mn 46.87 46.87 0.00 0.000 0.36397E-10 67 diopside 16.18 16.18 0.00 0.000 0.60662E-11 68 hedenbergite 14.21 14.21 0.00 0.000 0.90992E-11 116 microcline -2.49 -2.49 0.00 0.000 0.15165E-11 163 stilbite -7.52 -7.52 0.00 0.000 0.15165E-10 164 stilpnomelane-Fe 13.02 13.02 0.00 0.000 -0.27298E-10 245 tr.625ac.25prg.125 45.16 45.16 0.00 0.000 0.12132E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -16.80 -10.14 -3.381 0.17321E+05 -8.445 3 CH4,gas 4.54 1.13 -3.42 -0.854 0.58328E+04 -1.717 4 H2,gas 8.00 4.48 -3.52 -2.010 0.60048E+04 -1.818 5 H2S,gas -6.23 -14.78 -8.55 -4.274 0.14594E+05 -6.848 6 S2,gas -7.34 -38.52 -31.19 -4.798 0.53248E+05 -29.486 7 CO,gas 3.21 -12.32 -15.54 -4.780 0.26528E+05 -13.837 8 SO3,gas 17.12 -32.71 -49.83 -12.458 0.85085E+05 -48.132 9 SO2,gas 0.83 -28.23 -29.06 -7.749 0.49617E+05 -27.360 10 HCl,gas 5.19 -14.05 -19.24 -9.618 0.32844E+05 -17.537 11 acmite 7.71 6.53 -1.18 -0.123 0.20179E+04 15 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 19 spessartine 24.46 19.71 -4.75 -0.237 0.81043E+04 20 analcite 3.32 2.77 -0.55 -0.061 0.93612E+03 26 annite 20.12 17.72 -2.40 -0.134 0.41062E+04 27 phlogopite 27.06 25.40 -1.67 -0.093 0.28485E+04 29 anorthite 12.71 8.27 -4.44 -0.342 0.75896E+04 35 aragonite 0.97 -3.70 -4.67 -1.556 0.79721E+04 36 brucite 12.57 9.29 -3.27 -0.655 0.55908E+04 37 calcite 0.81 -3.70 -4.51 -1.505 0.77079E+04 38 carnegieite-low 9.02 5.93 -3.09 -0.442 0.52798E+04 39 carnegieite-high 10.09 5.93 -4.16 -0.595 0.71068E+04 40 carpholite-Mg 8.58 4.46 -4.12 -0.275 0.70422E+04 41 carpholite-Fe 6.71 1.90 -4.81 -0.321 0.82201E+04 42 celadonite 5.34 3.65 -1.69 -0.099 0.28878E+04 43 celadonite-Fe 3.88 1.09 -2.79 -0.164 0.47562E+04 44 chrysotile 23.89 21.57 -2.32 -0.194 0.39690E+04 49 chlorite-Al-free 47.17 43.14 -4.04 -0.168 0.68932E+04 51 chloritoid-Fe 9.17 5.06 -4.12 -0.275 0.70308E+04 52 chloritoid-Mn 11.40 7.56 -3.85 -0.256 0.65655E+04 54 coesite -2.38 -3.16 -0.78 -0.260 0.13343E+04 61 cristobalite -2.56 -3.16 -0.60 -0.199 0.10196E+04 63 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71234E+04 65 diaspore 2.87 0.74 -2.13 -0.356 0.36446E+04 66 diamond -3.10 -7.84 -4.74 -1.353 0.80865E+04 71 enstatite 17.26 12.27 -4.99 -0.499 0.85225E+04 73 clinoenstatite 17.17 12.27 -4.89 -0.489 0.83541E+04 75 epidote 24.67 22.70 -1.97 -0.095 0.33580E+04 76 clinozoisite 22.81 18.95 -3.86 -0.175 0.65858E+04 77 epidote-Fe 29.84 26.46 -3.38 -0.176 0.57767E+04 78 fayalite 14.05 10.31 -3.73 -0.533 0.63743E+04 79 ferrosilite 11.15 7.16 -3.99 -0.399 0.68203E+04 83 gibbsite 4.08 0.74 -3.34 -0.477 0.57031E+04 84 glaucophane 22.97 20.80 -2.17 -0.059 0.37132E+04 85 glaucophane-Fe 17.28 13.12 -4.15 -0.112 0.70920E+04 86 graphite -3.55 -7.84 -4.29 -1.226 0.73288E+04 87 greenalite 16.14 13.89 -2.25 -0.187 0.38409E+04 90 hematite 12.57 8.99 -3.58 -0.434 0.61113E+04 91 heulandite -5.83 -7.52 -1.69 -0.077 0.28938E+04 95 jadeite 4.22 2.77 -1.44 -0.144 0.24616E+04 97 kalsilite 7.58 3.83 -3.76 -0.536 0.64123E+04 98 kaolinite -1.33 -4.84 -3.50 -0.319 0.59826E+04 101 laumontite 2.88 1.95 -0.93 -0.062 0.15931E+04 102 lawsonite 9.62 8.27 -1.35 -0.090 0.23063E+04 103 leucite 4.12 0.67 -3.45 -0.345 0.58872E+04 105 lizardite 23.24 21.57 -1.68 -0.140 0.28617E+04 107 magnetite 20.09 15.72 -4.37 -0.356 0.74538E+04 108 minnesotaite 10.39 7.58 -2.81 -0.165 0.48031E+04 112 manganosite 14.06 9.23 -4.82 -1.206 0.82354E+04 120 muscovite 2.58 -1.01 -3.59 -0.211 0.61307E+04 121 paragonite 4.24 1.09 -3.14 -0.185 0.53698E+04 122 nepheline 8.34 5.93 -2.41 -0.344 0.41122E+04 128 periclase-Fe 11.63 6.74 -4.89 -1.223 0.83522E+04 134 phlogopite-Na 29.65 27.50 -2.15 -0.119 0.36673E+04 136 prehnite 19.37 18.21 -1.16 -0.068 0.19842E+04 137 prehnite-Fe 22.50 21.96 -0.53 -0.032 0.91141E+03 138 pumpellyite-Fe 46.27 43.89 -2.38 -0.053 0.40563E+04 139 pumpellyite-Mg 48.99 46.45 -2.54 -0.056 0.43401E+04 143 pyrrhotite -4.26 -8.04 -3.78 -1.261 0.64578E+04 144 pyrrhotiteFe0.875 -6.02 -9.44 -3.42 -1.259 0.58450E+04 145 pyroxmangite 7.40 6.08 -1.32 -0.264 0.22559E+04 146 pyrophyllite -6.18 -11.15 -4.98 -0.311 0.84959E+04 147 quartz -2.99 -3.16 -0.17 -0.056 0.28694E+03 152 rhodonite 7.45 6.08 -1.37 -0.274 0.23361E+04 153 sanidine -1.28 -2.49 -1.21 -0.093 0.20677E+04 165 stilpnomelane-Mg 27.44 25.81 -1.63 -0.049 0.27799E+04 171 talc 16.49 15.25 -1.24 -0.073 0.21141E+04 174 tephroite 18.09 15.31 -2.77 -0.396 0.47353E+04 178 tridymite -2.63 -3.16 -0.53 -0.177 0.90691E+03 179 tremolite 47.87 47.42 -0.45 -0.012 0.77499E+03 180 ferroactinolite 38.45 34.62 -3.83 -0.104 0.65454E+04 181 troilite-low -4.41 -8.04 -3.63 -1.210 0.62006E+04 183 vesuvianite 223.47 218.82 -4.65 -0.035 0.79389E+04 187 wairakite 3.95 1.95 -2.00 -0.118 0.34151E+04 188 walstromite 11.51 9.94 -1.56 -0.313 0.26719E+04 189 wollastonite 10.46 9.94 -0.52 -0.103 0.88228E+03 190 pseudo-wollastonite 11.00 9.94 -1.06 -0.211 0.18021E+04 191 zoisite 22.85 18.95 -3.90 -0.177 0.66598E+04 192 akaganeite 7.75 4.49 -3.26 -0.705 0.55682E+04 199 chalcedony -2.80 -3.16 -0.36 -0.118 0.60623E+03 201 montmorillonite-Ca -2.29 -6.17 -3.88 -0.240 0.66178E+04 202 montmorillonite-K -2.24 -6.27 -4.03 -0.247 0.68814E+04 203 montmorillonite-Mg -2.48 -6.79 -4.31 -0.267 0.73676E+04 204 montmorillonite-Na -2.04 -5.57 -3.54 -0.216 0.60363E+04 205 nontronite-Ca 3.21 -0.20 -3.41 -0.221 0.58220E+04 206 nontronite-H 2.53 -2.36 -4.89 -0.328 0.83490E+04 207 nontronite-K 3.34 -0.30 -3.64 -0.233 0.62089E+04 208 nontronite-Mg 3.07 -0.82 -3.90 -0.253 0.66559E+04 209 nontronite-Na 3.52 0.40 -3.12 -0.200 0.53297E+04 224 tobermorite 9.82 7.76 -2.07 -0.564 0.35287E+04 230 alabandite -0.98 -5.54 -4.56 -1.522 0.77938E+04 233 boehmite 4.41 0.74 -3.67 -0.611 0.62615E+04 235 ferrous-oxide 9.81 6.74 -3.08 -0.769 0.52532E+04 240 silica-amorphous -2.09 -3.16 -1.07 -0.355 0.18204E+04 242 an20ab80 2.02 1.35 -0.67 -0.052 0.11471E+04 243 an25ab75 2.65 1.78 -0.87 -0.067 0.14808E+04 244 an30ab70 3.28 2.21 -1.07 -0.082 0.18242E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 20.0000000 g Current total amount of reactant added: 519.9990000 g New total amount of reactant added: 539.9990000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.1586E-10 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 11 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 539.9990000 Water: Moles liquid = 0.5241E+02 kg liquid = 0.9442E+00 Moles total = 0.4874E+02 kg total = 0.8781E+00 Activity = 1.0000 Stoichiometric ionic strength = .1132384E-01 Osmotic coef. = 0.9694 True ionic strength = .2001256E-01 Chg. balance for total moles = -.1586E-10 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.88268E-10 -10.0542 0.74168E-10 -10.1298 0.84027E+00 -0.0756 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.14545E-03 -3.8373 0.12149E-03 -3.9155 0.83522E+00 -0.0782 4 SO4-- 0.68493E-12 -12.1644 0.35571E-12 -12.4489 0.51935E+00 -0.2845 5 HCO3- 0.25348E-06 -6.5961 0.21202E-06 -6.6736 0.83644E+00 -0.0776 6 HS- 0.27005E-04 -4.5685 0.22559E-04 -4.6467 0.83534E+00 -0.0781 7 Al+++ 0.96851E-29 -29.0139 0.22380E-29 -29.6501 0.23107E+00 -0.6363 8 H4SiO4 0.69586E-03 -3.1575 0.69586E-03 -3.1575 0.10000E+01 0.0000 9 Ca++ 0.13492E-06 -6.8699 0.69557E-07 -7.1577 0.51554E+00 -0.2877 10 Mg++ 0.21108E-10 -10.6756 0.10832E-10 -10.9653 0.51318E+00 -0.2897 11 Fe++ 0.58170E-13 -13.2353 0.29884E-13 -13.5246 0.51374E+00 -0.2893 12 K+ 0.15647E-03 -3.8056 0.13091E-03 -3.8830 0.83663E+00 -0.0775 13 Na+ 0.19855E-01 -1.7021 0.16580E-01 -1.7804 0.83506E+00 -0.0783 14 Mn++ 0.18390E-10 -10.7354 0.94557E-11 -11.0243 0.51417E+00 -0.2889 15 HPO4-- 0.45328E-07 -7.3436 0.23545E-07 -7.6281 0.51942E+00 -0.2845 16 HSiO3- 0.10489E-01 -1.9793 0.87605E-02 -2.0575 0.83522E+00 -0.0782 17 Ca(HSiO3)+ 0.16584E-07 -7.7803 0.13877E-07 -7.8577 0.83681E+00 -0.0774 18 Mg(HSiO3)+ 0.32140E-11 -11.4929 0.26895E-11 -11.5703 0.83681E+00 -0.0774 19 NaHSiO3,aq 0.23492E-02 -2.6291 0.23492E-02 -2.6291 0.10000E+01 0.0000 20 AlO+ 0.66140E-16 -16.1795 0.55347E-16 -16.2569 0.83681E+00 -0.0774 22 HAlO2,aq 0.14861E-09 -9.8280 0.14861E-09 -9.8280 0.10000E+01 0.0000 23 AlO2- 0.53200E-05 -5.2741 0.44353E-05 -5.3531 0.83371E+00 -0.0790 24 CH4,aq 0.13106E-04 -4.8825 0.13061E-04 -4.8840 0.99655E+00 -0.0015 25 C2H6,aq 0.25256E-14 -14.5976 0.25169E-14 -14.5991 0.99655E+00 -0.0015 29 CO,aq 0.97807E-17 -17.0096 0.97807E-17 -17.0096 0.10000E+01 0.0000 30 CO2,aq 0.33718E-10 -10.4721 0.33601E-10 -10.4736 0.99655E+00 -0.0015 31 CO3-2 0.48180E-06 -6.3171 0.24969E-06 -6.6026 0.51824E+00 -0.2855 32 CaCO3,aq 0.21777E-09 -9.6620 0.21777E-09 -9.6620 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.44986E-12 -12.3469 0.37645E-12 -12.4243 0.83681E+00 -0.0774 34 CaCl+ 0.16342E-10 -10.7867 0.13675E-10 -10.8641 0.83681E+00 -0.0774 35 CaCl2,aq 0.39470E-15 -15.4037 0.39470E-15 -15.4037 0.10000E+01 0.0000 36 CaOH+ 0.79873E-07 -7.0976 0.66839E-07 -7.1750 0.83681E+00 -0.0774 37 CaSO4,aq 0.78569E-17 -17.1047 0.78569E-17 -17.1047 0.10000E+01 0.0000 38 HCl,aq 0.16511E-14 -14.7822 0.16511E-14 -14.7822 0.10000E+01 0.0000 43 FeCl+ 0.68671E-17 -17.1632 0.57465E-17 -17.2406 0.83681E+00 -0.0774 46 FeO,aq 0.21114E-09 -9.6754 0.21114E-09 -9.6754 0.10000E+01 0.0000 47 FeOH+ 0.15673E-10 -10.8048 0.13116E-10 -10.8822 0.83681E+00 -0.0774 48 HFeO2- 0.35663E-07 -7.4478 0.29786E-07 -7.5260 0.83522E+00 -0.0782 49 FeO+ 0.10982E-16 -16.9593 0.91902E-17 -17.0367 0.83681E+00 -0.0774 51 FeO2- 0.40930E-09 -9.3880 0.34185E-09 -9.4662 0.83522E+00 -0.0782 52 HFeO2,aq 0.32247E-11 -11.4915 0.32247E-11 -11.4915 0.10000E+01 0.0000 53 H2,aq 0.11627E-04 -4.9345 0.11587E-04 -4.9360 0.99655E+00 -0.0015 54 KCl,aq 0.28824E-09 -9.5403 0.28824E-09 -9.5403 0.10000E+01 0.0000 56 KOH,aq 0.75375E-06 -6.1228 0.75375E-06 -6.1228 0.10000E+01 0.0000 57 KSO4- 0.86515E-15 -15.0629 0.72258E-15 -15.1411 0.83522E+00 -0.0782 58 MgCO3,aq 0.85007E-14 -14.0705 0.85007E-14 -14.0705 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.71585E-16 -16.1452 0.59903E-16 -16.2226 0.83681E+00 -0.0774 60 MgCl+ 0.23066E-14 -14.6370 0.19302E-14 -14.7144 0.83681E+00 -0.0774 61 MgOH+ 0.68829E-10 -10.1622 0.57597E-10 -10.2396 0.83681E+00 -0.0774 63 MnO,aq 0.17801E-08 -8.7495 0.17801E-08 -8.7495 0.10000E+01 0.0000 64 MnOH+ 0.46069E-09 -9.3366 0.38552E-09 -9.4140 0.83681E+00 -0.0774 65 MnO2-2 0.20723E-10 -10.6835 0.10740E-10 -10.9690 0.51824E+00 -0.2855 66 HMnO2- 0.20894E-09 -9.6800 0.17451E-09 -9.7582 0.83522E+00 -0.0782 69 MnCl+ 0.84533E-14 -14.0730 0.70739E-14 -14.1503 0.83681E+00 -0.0774 71 NaCl,aq 0.66753E-06 -6.1755 0.66753E-06 -6.1755 0.10000E+01 0.0000 72 NaOH,aq 0.96047E-04 -4.0175 0.96047E-04 -4.0175 0.10000E+01 0.0000 74 OH- 0.93438E-02 -2.0295 0.77900E-02 -2.1085 0.83371E+00 -0.0790 79 HPO3-2 0.16405E-14 -14.7850 0.85019E-15 -15.0705 0.51824E+00 -0.2855 81 H2PO3- 0.15140E-18 -18.8199 0.12645E-18 -18.8981 0.83522E+00 -0.0782 82 H3PO4,aq 0.90584E-18 -18.0430 0.90584E-18 -18.0430 0.10000E+01 0.0000 83 H2PO4- 0.38533E-10 -10.4142 0.32214E-10 -10.4920 0.83601E+00 -0.0778 84 PO4-3 0.10672E-08 -8.9717 0.25900E-09 -9.5867 0.24269E+00 -0.6149 88 HP2O7-3 0.94707E-18 -18.0236 0.21906E-18 -18.6594 0.23130E+00 -0.6358 89 P2O7-4 0.91480E-17 -17.0387 0.70559E-18 -18.1514 0.77131E-01 -1.1128 90 H2S,aq 0.51890E-08 -8.2849 0.51710E-08 -8.2864 0.99655E+00 -0.0015 91 S2-2 0.18778E-14 -14.7264 0.97315E-15 -15.0118 0.51824E+00 -0.2855 97 SO3-2 0.10188E-17 -17.9919 0.53562E-18 -18.2711 0.52574E+00 -0.2792 99 HSO4- 0.30354E-19 -19.5178 0.25426E-19 -19.5947 0.83763E+00 -0.0769 Charge balance for all species = -.1680E-10 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.8826765E-10 -.2230368E-01 -.2244171E+02 0.0000 2 H2O 0.1000000E+01 0.5550489E+02 0.9981999E+06 0.0000 3 Cl- 0.1454546E-03 0.1461225E-03 0.5171479E+01 6.2143 4 SO4-- 0.6849276E-12 -.1601314E-04 -.1535575E+01 7.8107 5 HCO3- 0.2534808E-06 0.1384187E-04 0.8431247E+00 3.4562 6 HS- 0.2700549E-04 0.4302382E-04 0.1420412E+01 5.4831 7 Al+++ 0.9685113E-29 0.5320163E-05 0.1432966E+00 0.7392 8 H4SiO4 0.6958584E-03 0.1353403E-01 0.1298569E+04 -3.1575 9 Ca++ 0.1349227E-06 0.2316136E-06 0.9266483E-02 13.1019 10 Mg++ 0.2110802E-10 0.9316182E-10 0.2261015E-05 9.2943 11 Fe++ 0.5817020E-13 0.3630221E-07 0.2023847E-02 6.7350 12 K+ 0.1564685E-03 0.1572226E-03 0.6137036E+01 6.2467 13 Na+ 0.1985506E-01 0.2230101E-01 0.5118049E+03 8.3494 14 Mn++ 0.1839048E-10 0.2488883E-08 0.1364967E-03 9.2353 15 HPO4-- 0.4532846E-07 0.4643421E-07 0.4448966E-02 12.6315 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.8941569E+01 -.2105995E-01 -.8920509E+01 0.0000000E+00 2 H2O 0.4873914E+02 0.5240975E+02 -.3670606E+01 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.1499072E-01 -.1512019E-04 0.1500584E-01 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.1496521E-01 0.4062466E-04 -.1500584E-01 0.0000000E+00 7 Al+++ 0.1760797E+01 0.5023493E-05 0.1760792E+01 0.0000000E+00 8 H4SiO4 0.5622892E+01 0.1277933E-01 0.5610113E+01 0.0000000E+00 9 Ca++ 0.6210904E+00 0.2186981E-06 0.6210901E+00 0.0000000E+00 10 Mg++ 0.4285706E+00 0.8796680E-10 0.4285706E+00 0.0000000E+00 11 Fe++ 0.3850239E+00 0.3427788E-07 0.3850239E+00 0.0000000E+00 12 K+ 0.1146495E+00 0.1484553E-03 0.1145010E+00 0.0000000E+00 13 Na+ 0.6779904E+00 0.2105743E-01 0.6569329E+00 0.0000000E+00 14 Mn++ 0.9362824E-02 0.2350094E-08 0.9362822E-02 0.0000000E+00 15 HPO4-- 0.3195485E-02 0.4384489E-07 0.3195442E-02 0.0000000E+00 Chg. balance for solid moles: -.7772E-15 Mass of aqueous solution: 0.945880E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 539.9990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 0.6563 -0.183 172.1 2.236 29.18 66.06 andradite 0.6002E-01 -1.222 30.50 1.484 5.172 7.925 grossular 0.1454E-01 -1.837 6.551 0.816 1.111 1.823 apatite-OH 0.1065E-02 -2.973 0.5350 -0.272 0.9072E-01 0.1700 clinochlore 0.7785E-01 -1.109 43.27 1.636 7.337 16.46 daphnite 0.2253E-01 -1.647 16.08 1.206 2.726 4.872 chlorite-Mn 0.1873E-02 -2.728 1.328 0.123 0.2251 0.4231 diopside 0.2011E-01 -1.697 4.355 0.639 0.7385 1.331 hedenbergite 0.5215E-02 -2.283 1.294 0.112 0.2194 0.3544 microcline 0.1005 -0.998 27.96 1.447 4.741 10.92 stilbite 0.3561 -0.448 251.0 2.400 42.56 117.1 stilpnomelane-Fe 0.2809E-01 -1.551 30.28 1.481 5.135 10.46 tr.625ac.25prg.125 0.5297E-02 -2.276 4.527 0.656 0.7677 1.457 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8050E+00 0.8050E+00 1.0000 -0.094 grossular 0.1950E+00 0.1950E+00 1.0000 -0.710 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.7613E+00 0.7613E+00 1.0000 -0.118 daphnite 0.2204E+00 0.2204E+00 1.0000 -0.657 chlorite-Mn 0.1831E-01 0.1831E-01 1.0000 -1.737 diopside 0.7941E+00 0.7941E+00 1.0000 -0.100 hedenbergite 0.2059E+00 0.2059E+00 1.0000 -0.686 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 tr.625ac.25prg.125 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 589.758288 g Volume = 239.321198 cm3 Porosity: -10.2865% V(tot) - V(min): -.22322E+02 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 539.9990000 g log = 2.7324 Original solution: 1000.0103000 g Original solution / Rock added: 1.85 (Water/Rock Ratio), log = 0.2676 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0550 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9676E+00 0.9855 0.1006E+01 0.1021E+01 CO2,gas 0.3384E-08 1.0069 0.3595E-08 0.3570E-08 CH4,gas 0.1800E-01 1.0125 0.1923E-01 0.1899E-01 H2,gas 0.1441E-01 1.0006 0.1521E-01 0.1520E-01 H2S,gas 0.1353E-06 0.9959 0.1421E-06 0.1427E-06 S2,gas 0.3107E-29 1.0000 0.3277E-29 0.3277E-29 CO,gas 0.1382E-13 1.0000 0.1458E-13 0.1458E-13 SO3,gas 0.7013E-48 1.0000 0.7399E-48 0.7399E-48 SO2,gas 0.4151E-27 1.0000 0.4379E-27 0.4379E-27 HCl,gas 0.2762E-17 1.0000 0.2913E-17 0.2913E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 16 albite -0.38 -0.38 0.00 0.000 -0.13080E-10 22 andradite 39.01 39.01 0.00 0.000 0.00000E+00 23 grossular 32.73 32.73 0.00 0.000 0.24265E-10 32 apatite-OH -18.15 -18.15 0.00 0.000 0.60662E-11 46 clinochlore 39.07 39.07 0.00 0.000 -0.48529E-10 47 daphnite 28.97 28.97 0.00 0.000 -0.42463E-10 48 chlorite-Mn 46.87 46.87 0.00 0.000 0.00000E+00 67 diopside 16.18 16.18 0.00 0.000 -0.12132E-10 68 hedenbergite 14.21 14.21 0.00 0.000 0.30331E-11 116 microcline -2.49 -2.49 0.00 0.000 -0.10616E-10 163 stilbite -7.52 -7.52 0.00 0.000 -0.90992E-11 164 stilpnomelane-Fe 13.02 13.02 0.00 0.000 0.21232E-10 245 tr.625ac.25prg.125 45.16 45.16 0.00 0.000 -0.12132E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -16.80 -10.14 -3.381 0.17319E+05 -8.444 3 CH4,gas 4.54 1.13 -3.42 -0.854 0.58312E+04 -1.716 4 H2,gas 8.00 4.48 -3.52 -2.010 0.60048E+04 -1.818 5 H2S,gas -6.23 -14.78 -8.55 -4.273 0.14592E+05 -6.847 6 S2,gas -7.34 -38.52 -31.18 -4.797 0.53245E+05 -29.484 7 CO,gas 3.21 -12.32 -15.54 -4.780 0.26526E+05 -13.836 8 SO3,gas 17.12 -32.71 -49.83 -12.457 0.85083E+05 -48.131 9 SO2,gas 0.83 -28.23 -29.06 -7.749 0.49615E+05 -27.359 10 HCl,gas 5.19 -14.05 -19.23 -9.617 0.32842E+05 -17.536 11 acmite 7.71 6.53 -1.18 -0.123 0.20179E+04 15 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 19 spessartine 24.46 19.71 -4.75 -0.237 0.81030E+04 20 analcite 3.32 2.77 -0.55 -0.061 0.93612E+03 26 annite 20.12 17.72 -2.40 -0.134 0.41062E+04 27 phlogopite 27.06 25.40 -1.67 -0.093 0.28485E+04 29 anorthite 12.71 8.27 -4.44 -0.342 0.75897E+04 35 aragonite 0.97 -3.70 -4.67 -1.556 0.79705E+04 36 brucite 12.57 9.29 -3.27 -0.655 0.55908E+04 37 calcite 0.81 -3.70 -4.51 -1.504 0.77063E+04 38 carnegieite-low 9.02 5.93 -3.09 -0.442 0.52799E+04 39 carnegieite-high 10.09 5.93 -4.16 -0.595 0.71069E+04 40 carpholite-Mg 8.58 4.46 -4.12 -0.275 0.70423E+04 41 carpholite-Fe 6.71 1.90 -4.81 -0.321 0.82201E+04 42 celadonite 5.34 3.65 -1.69 -0.099 0.28878E+04 43 celadonite-Fe 3.88 1.09 -2.79 -0.164 0.47561E+04 44 chrysotile 23.89 21.57 -2.32 -0.194 0.39690E+04 49 chlorite-Al-free 47.17 43.14 -4.04 -0.168 0.68933E+04 51 chloritoid-Fe 9.17 5.06 -4.12 -0.275 0.70309E+04 52 chloritoid-Mn 11.40 7.56 -3.84 -0.256 0.65651E+04 54 coesite -2.38 -3.16 -0.78 -0.260 0.13342E+04 61 cristobalite -2.56 -3.16 -0.60 -0.199 0.10196E+04 63 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71234E+04 65 diaspore 2.87 0.74 -2.13 -0.356 0.36446E+04 66 diamond -3.10 -7.84 -4.74 -1.353 0.80849E+04 71 enstatite 17.26 12.27 -4.99 -0.499 0.85225E+04 73 clinoenstatite 17.17 12.27 -4.89 -0.489 0.83541E+04 75 epidote 24.67 22.70 -1.97 -0.095 0.33580E+04 76 clinozoisite 22.81 18.95 -3.86 -0.175 0.65858E+04 77 epidote-Fe 29.84 26.46 -3.38 -0.176 0.57767E+04 78 fayalite 14.05 10.31 -3.73 -0.533 0.63743E+04 79 ferrosilite 11.15 7.16 -3.99 -0.399 0.68203E+04 83 gibbsite 4.08 0.74 -3.34 -0.477 0.57031E+04 84 glaucophane 22.97 20.80 -2.17 -0.059 0.37132E+04 85 glaucophane-Fe 17.28 13.12 -4.15 -0.112 0.70920E+04 86 graphite -3.55 -7.84 -4.29 -1.226 0.73272E+04 87 greenalite 16.14 13.89 -2.25 -0.187 0.38409E+04 90 hematite 12.57 8.99 -3.58 -0.434 0.61113E+04 91 heulandite -5.83 -7.52 -1.69 -0.077 0.28938E+04 95 jadeite 4.22 2.77 -1.44 -0.144 0.24616E+04 97 kalsilite 7.58 3.83 -3.76 -0.536 0.64123E+04 98 kaolinite -1.33 -4.84 -3.50 -0.319 0.59826E+04 101 laumontite 2.88 1.95 -0.93 -0.062 0.15931E+04 102 lawsonite 9.62 8.27 -1.35 -0.090 0.23063E+04 103 leucite 4.12 0.67 -3.45 -0.345 0.58872E+04 105 lizardite 23.24 21.57 -1.68 -0.140 0.28617E+04 107 magnetite 20.09 15.72 -4.37 -0.356 0.74538E+04 108 minnesotaite 10.39 7.58 -2.81 -0.165 0.48031E+04 112 manganosite 14.06 9.24 -4.82 -1.206 0.82349E+04 120 muscovite 2.58 -1.01 -3.59 -0.211 0.61307E+04 121 paragonite 4.24 1.09 -3.14 -0.185 0.53698E+04 122 nepheline 8.34 5.93 -2.41 -0.344 0.41122E+04 128 periclase-Fe 11.63 6.74 -4.89 -1.223 0.83522E+04 134 phlogopite-Na 29.65 27.50 -2.15 -0.119 0.36673E+04 136 prehnite 19.37 18.21 -1.16 -0.068 0.19843E+04 137 prehnite-Fe 22.50 21.96 -0.53 -0.032 0.91142E+03 138 pumpellyite-Fe 46.27 43.89 -2.38 -0.053 0.40564E+04 139 pumpellyite-Mg 48.99 46.45 -2.54 -0.056 0.43402E+04 143 pyrrhotite -4.26 -8.04 -3.78 -1.260 0.64562E+04 144 pyrrhotiteFe0.875 -6.02 -9.44 -3.42 -1.259 0.58434E+04 145 pyroxmangite 7.40 6.08 -1.32 -0.264 0.22554E+04 146 pyrophyllite -6.18 -11.15 -4.98 -0.311 0.84959E+04 147 quartz -2.99 -3.16 -0.17 -0.056 0.28693E+03 152 rhodonite 7.45 6.08 -1.37 -0.274 0.23356E+04 153 sanidine -1.28 -2.49 -1.21 -0.093 0.20677E+04 165 stilpnomelane-Mg 27.44 25.81 -1.63 -0.049 0.27799E+04 171 talc 16.49 15.25 -1.24 -0.073 0.21141E+04 174 tephroite 18.09 15.31 -2.77 -0.396 0.47344E+04 178 tridymite -2.63 -3.16 -0.53 -0.177 0.90691E+03 179 tremolite 47.87 47.42 -0.45 -0.012 0.77499E+03 180 ferroactinolite 38.45 34.62 -3.83 -0.104 0.65453E+04 181 troilite-low -4.41 -8.04 -3.63 -1.210 0.61990E+04 183 vesuvianite 223.47 218.82 -4.65 -0.035 0.79391E+04 187 wairakite 3.95 1.95 -2.00 -0.118 0.34151E+04 188 walstromite 11.51 9.94 -1.56 -0.313 0.26719E+04 189 wollastonite 10.46 9.94 -0.52 -0.103 0.88228E+03 190 pseudo-wollastonite 11.00 9.94 -1.06 -0.211 0.18021E+04 191 zoisite 22.85 18.95 -3.90 -0.177 0.66599E+04 192 akaganeite 7.75 4.49 -3.26 -0.705 0.55682E+04 199 chalcedony -2.80 -3.16 -0.36 -0.118 0.60623E+03 201 montmorillonite-Ca -2.29 -6.17 -3.88 -0.240 0.66178E+04 202 montmorillonite-K -2.24 -6.27 -4.03 -0.247 0.68815E+04 203 montmorillonite-Mg -2.48 -6.79 -4.31 -0.267 0.73676E+04 204 montmorillonite-Na -2.04 -5.57 -3.54 -0.216 0.60363E+04 205 nontronite-Ca 3.21 -0.20 -3.41 -0.221 0.58220E+04 206 nontronite-H 2.53 -2.36 -4.89 -0.328 0.83490E+04 207 nontronite-K 3.34 -0.30 -3.64 -0.233 0.62088E+04 208 nontronite-Mg 3.07 -0.82 -3.90 -0.253 0.66558E+04 209 nontronite-Na 3.52 0.40 -3.12 -0.200 0.53297E+04 224 tobermorite 9.82 7.76 -2.07 -0.564 0.35287E+04 230 alabandite -0.98 -5.54 -4.56 -1.521 0.77918E+04 233 boehmite 4.41 0.74 -3.67 -0.611 0.62615E+04 235 ferrous-oxide 9.81 6.74 -3.08 -0.769 0.52532E+04 240 silica-amorphous -2.09 -3.16 -1.07 -0.355 0.18204E+04 242 an20ab80 2.02 1.35 -0.67 -0.052 0.11471E+04 243 an25ab75 2.65 1.78 -0.87 -0.067 0.14808E+04 244 an30ab70 3.28 2.21 -1.07 -0.082 0.18242E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 20.0000000 g Current total amount of reactant added: 539.9990000 g New total amount of reactant added: 559.9990000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.1586E-10 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 11 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 559.9990000 Water: Moles liquid = 0.5230E+02 kg liquid = 0.9422E+00 Moles total = 0.4849E+02 kg total = 0.8735E+00 Activity = 1.0000 Stoichiometric ionic strength = .1132413E-01 Osmotic coef. = 0.9694 True ionic strength = .2001279E-01 Chg. balance for total moles = -.1586E-10 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.88269E-10 -10.0542 0.74169E-10 -10.1298 0.84027E+00 -0.0756 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.14576E-03 -3.8363 0.12174E-03 -3.9145 0.83521E+00 -0.0782 4 SO4-- 0.68643E-12 -12.1634 0.35649E-12 -12.4480 0.51934E+00 -0.2845 5 HCO3- 0.25403E-06 -6.5951 0.21248E-06 -6.6727 0.83644E+00 -0.0776 6 HS- 0.27063E-04 -4.5676 0.22607E-04 -4.6458 0.83534E+00 -0.0781 7 Al+++ 0.96853E-29 -29.0139 0.22380E-29 -29.6501 0.23107E+00 -0.6363 8 H4SiO4 0.69586E-03 -3.1575 0.69586E-03 -3.1575 0.10000E+01 0.0000 9 Ca++ 0.13493E-06 -6.8699 0.69558E-07 -7.1577 0.51553E+00 -0.2877 10 Mg++ 0.21108E-10 -10.6755 0.10832E-10 -10.9653 0.51318E+00 -0.2897 11 Fe++ 0.58172E-13 -13.2353 0.29885E-13 -13.5245 0.51374E+00 -0.2893 12 K+ 0.15647E-03 -3.8056 0.13091E-03 -3.8830 0.83663E+00 -0.0775 13 Na+ 0.19855E-01 -1.7021 0.16580E-01 -1.7804 0.83506E+00 -0.0783 14 Mn++ 0.18402E-10 -10.7351 0.94614E-11 -11.0240 0.51416E+00 -0.2889 15 HPO4-- 0.45328E-07 -7.3436 0.23544E-07 -7.6281 0.51942E+00 -0.2845 16 HSiO3- 0.10489E-01 -1.9793 0.87605E-02 -2.0575 0.83521E+00 -0.0782 17 Ca(HSiO3)+ 0.16584E-07 -7.7803 0.13878E-07 -7.8577 0.83681E+00 -0.0774 18 Mg(HSiO3)+ 0.32141E-11 -11.4929 0.26896E-11 -11.5703 0.83681E+00 -0.0774 19 NaHSiO3,aq 0.23493E-02 -2.6291 0.23493E-02 -2.6291 0.10000E+01 0.0000 20 AlO+ 0.66139E-16 -16.1795 0.55346E-16 -16.2569 0.83681E+00 -0.0774 22 HAlO2,aq 0.14861E-09 -9.8280 0.14861E-09 -9.8280 0.10000E+01 0.0000 23 AlO2- 0.53199E-05 -5.2741 0.44352E-05 -5.3531 0.83371E+00 -0.0790 24 CH4,aq 0.13134E-04 -4.8816 0.13089E-04 -4.8831 0.99655E+00 -0.0015 25 C2H6,aq 0.25364E-14 -14.5958 0.25276E-14 -14.5973 0.99655E+00 -0.0015 29 CO,aq 0.98020E-17 -17.0087 0.98020E-17 -17.0087 0.10000E+01 0.0000 30 CO2,aq 0.33791E-10 -10.4712 0.33675E-10 -10.4727 0.99655E+00 -0.0015 31 CO3-2 0.48285E-06 -6.3162 0.25023E-06 -6.6017 0.51824E+00 -0.2855 32 CaCO3,aq 0.21825E-09 -9.6610 0.21825E-09 -9.6610 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.45085E-12 -12.3460 0.37727E-12 -12.4233 0.83681E+00 -0.0774 34 CaCl+ 0.16377E-10 -10.7858 0.13704E-10 -10.8631 0.83681E+00 -0.0774 35 CaCl2,aq 0.39639E-15 -15.4019 0.39639E-15 -15.4019 0.10000E+01 0.0000 36 CaOH+ 0.79873E-07 -7.0976 0.66839E-07 -7.1750 0.83681E+00 -0.0774 37 CaSO4,aq 0.78742E-17 -17.1038 0.78742E-17 -17.1038 0.10000E+01 0.0000 38 HCl,aq 0.16547E-14 -14.7813 0.16547E-14 -14.7813 0.10000E+01 0.0000 43 FeCl+ 0.68819E-17 -17.1623 0.57589E-17 -17.2397 0.83681E+00 -0.0774 46 FeO,aq 0.21114E-09 -9.6754 0.21114E-09 -9.6754 0.10000E+01 0.0000 47 FeOH+ 0.15673E-10 -10.8048 0.13116E-10 -10.8822 0.83681E+00 -0.0774 48 HFeO2- 0.35662E-07 -7.4478 0.29786E-07 -7.5260 0.83521E+00 -0.0782 49 FeO+ 0.10983E-16 -16.9593 0.91903E-17 -17.0367 0.83681E+00 -0.0774 51 FeO2- 0.40929E-09 -9.3880 0.34185E-09 -9.4662 0.83521E+00 -0.0782 52 HFeO2,aq 0.32247E-11 -11.4915 0.32247E-11 -11.4915 0.10000E+01 0.0000 53 H2,aq 0.11627E-04 -4.9345 0.11587E-04 -4.9360 0.99655E+00 -0.0015 54 KCl,aq 0.28885E-09 -9.5393 0.28885E-09 -9.5393 0.10000E+01 0.0000 56 KOH,aq 0.75375E-06 -6.1228 0.75375E-06 -6.1228 0.10000E+01 0.0000 57 KSO4- 0.86705E-15 -15.0620 0.72417E-15 -15.1402 0.83521E+00 -0.0782 58 MgCO3,aq 0.85193E-14 -14.0696 0.85193E-14 -14.0696 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.71742E-16 -16.1442 0.60035E-16 -16.2216 0.83681E+00 -0.0774 60 MgCl+ 0.23115E-14 -14.6361 0.19343E-14 -14.7135 0.83681E+00 -0.0774 61 MgOH+ 0.68829E-10 -10.1622 0.57597E-10 -10.2396 0.83681E+00 -0.0774 63 MnO,aq 0.17812E-08 -8.7493 0.17812E-08 -8.7493 0.10000E+01 0.0000 64 MnOH+ 0.46097E-09 -9.3363 0.38574E-09 -9.4137 0.83681E+00 -0.0774 65 MnO2-2 0.20734E-10 -10.6833 0.10745E-10 -10.9688 0.51824E+00 -0.2855 66 HMnO2- 0.20906E-09 -9.6797 0.17461E-09 -9.7579 0.83521E+00 -0.0782 69 MnCl+ 0.84764E-14 -14.0718 0.70932E-14 -14.1492 0.83681E+00 -0.0774 71 NaCl,aq 0.66896E-06 -6.1746 0.66896E-06 -6.1746 0.10000E+01 0.0000 72 NaOH,aq 0.96047E-04 -4.0175 0.96047E-04 -4.0175 0.10000E+01 0.0000 74 OH- 0.93437E-02 -2.0295 0.77899E-02 -2.1085 0.83371E+00 -0.0790 79 HPO3-2 0.16405E-14 -14.7850 0.85017E-15 -15.0705 0.51824E+00 -0.2855 81 H2PO3- 0.15139E-18 -18.8199 0.12645E-18 -18.8981 0.83521E+00 -0.0782 82 H3PO4,aq 0.90585E-18 -18.0429 0.90585E-18 -18.0429 0.10000E+01 0.0000 83 H2PO4- 0.38533E-10 -10.4142 0.32214E-10 -10.4920 0.83601E+00 -0.0778 84 PO4-3 0.10672E-08 -8.9718 0.25900E-09 -9.5867 0.24269E+00 -0.6150 88 HP2O7-3 0.94707E-18 -18.0236 0.21906E-18 -18.6594 0.23130E+00 -0.6358 89 P2O7-4 0.91479E-17 -17.0387 0.70558E-18 -18.1515 0.77130E-01 -1.1128 90 H2S,aq 0.52001E-08 -8.2840 0.51821E-08 -8.2855 0.99655E+00 -0.0015 91 S2-2 0.18858E-14 -14.7245 0.97731E-15 -15.0100 0.51824E+00 -0.2855 97 SO3-2 0.10210E-17 -17.9910 0.53678E-18 -18.2702 0.52574E+00 -0.2792 99 HSO4- 0.30421E-19 -19.5168 0.25481E-19 -19.5938 0.83763E+00 -0.0769 Charge balance for all species = -.1683E-10 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.8826870E-10 -.2230356E-01 -.2244159E+02 0.0000 2 H2O 0.1000000E+01 0.5550489E+02 0.9981999E+06 0.0000 3 Cl- 0.1457647E-03 0.1464340E-03 0.5182503E+01 6.2152 4 SO4-- 0.6864259E-12 -.1604100E-04 -.1538247E+01 7.8116 5 HCO3- 0.2540342E-06 0.1387138E-04 0.8449219E+00 3.4571 6 HS- 0.2706305E-04 0.4310925E-04 0.1423232E+01 5.4840 7 Al+++ 0.9685307E-29 0.5319999E-05 0.1432922E+00 0.7392 8 H4SiO4 0.6958632E-03 0.1353402E-01 0.1298567E+04 -3.1575 9 Ca++ 0.1349252E-06 0.2316172E-06 0.9266626E-02 13.1019 10 Mg++ 0.2110840E-10 0.9316263E-10 0.2261035E-05 9.2943 11 Fe++ 0.5817152E-13 0.3630174E-07 0.2023821E-02 6.7350 12 K+ 0.1564704E-03 0.1572244E-03 0.6137108E+01 6.2467 13 Na+ 0.1985529E-01 0.2230126E-01 0.5118107E+03 8.3494 14 Mn++ 0.1840158E-10 0.2490324E-08 0.1365757E-03 9.2355 15 HPO4-- 0.4532813E-07 0.4643386E-07 0.4448932E-02 12.6314 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.9272739E+01 -.2101504E-01 -.9251724E+01 0.0000000E+00 2 H2O 0.4848843E+02 0.5229826E+02 -.3809831E+01 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.1554499E-01 -.1511428E-04 0.1556010E-01 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.1551948E-01 0.4061875E-04 -.1556010E-01 0.0000000E+00 7 Al+++ 0.1826012E+01 0.5012653E-05 0.1826007E+01 0.0000000E+00 8 H4SiO4 0.5831148E+01 0.1275213E-01 0.5818396E+01 0.0000000E+00 9 Ca++ 0.6440932E+00 0.2182362E-06 0.6440930E+00 0.0000000E+00 10 Mg++ 0.4444437E+00 0.8778045E-10 0.4444437E+00 0.0000000E+00 11 Fe++ 0.3992841E+00 0.3420452E-07 0.3992841E+00 0.0000000E+00 12 K+ 0.1188958E+00 0.1481413E-03 0.1187476E+00 0.0000000E+00 13 Na+ 0.7030952E+00 0.2101287E-01 0.6820824E+00 0.0000000E+00 14 Mn++ 0.9709596E-02 0.2346453E-08 0.9709594E-02 0.0000000E+00 15 HPO4-- 0.3313837E-02 0.4375129E-07 0.3313793E-02 0.0000000E+00 Chg. balance for solid moles: -.2463E-15 Mass of aqueous solution: 0.943868E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 559.9990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 0.6814 -0.167 178.7 2.252 29.21 68.59 andradite 0.6224E-01 -1.206 31.63 1.500 5.171 8.218 grossular 0.1508E-01 -1.822 6.793 0.832 1.111 1.890 apatite-OH 0.1105E-02 -2.957 0.5549 -0.256 0.9072E-01 0.1763 clinochlore 0.8069E-01 -1.093 44.85 1.652 7.333 17.06 daphnite 0.2336E-01 -1.632 16.66 1.222 2.725 5.050 chlorite-Mn 0.1942E-02 -2.712 1.377 0.139 0.2251 0.4387 diopside 0.2120E-01 -1.674 4.591 0.662 0.7506 1.403 hedenbergite 0.5497E-02 -2.260 1.364 0.135 0.2230 0.3735 microcline 0.1042 -0.982 29.00 1.462 4.741 11.33 stilbite 0.3690 -0.433 260.0 2.415 42.52 121.3 stilpnomelane-Fe 0.2914E-01 -1.536 31.41 1.497 5.136 10.85 tr.625ac.25prg.125 0.5463E-02 -2.263 4.670 0.669 0.7635 1.503 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8050E+00 0.8050E+00 1.0000 -0.094 grossular 0.1950E+00 0.1950E+00 1.0000 -0.710 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.7613E+00 0.7613E+00 1.0000 -0.118 daphnite 0.2204E+00 0.2204E+00 1.0000 -0.657 chlorite-Mn 0.1832E-01 0.1832E-01 1.0000 -1.737 diopside 0.7941E+00 0.7941E+00 1.0000 -0.100 hedenbergite 0.2059E+00 0.2059E+00 1.0000 -0.686 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 tr.625ac.25prg.125 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 611.608418 g Volume = 248.161811 cm3 Porosity: -10.2943% V(tot) - V(min): -.23162E+02 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 559.9990000 g log = 2.7482 Original solution: 1000.0103000 g Original solution / Rock added: 1.79 (Water/Rock Ratio), log = 0.2518 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0550 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9676E+00 0.9855 0.1006E+01 0.1021E+01 CO2,gas 0.3391E-08 1.0069 0.3603E-08 0.3578E-08 CH4,gas 0.1804E-01 1.0125 0.1927E-01 0.1903E-01 H2,gas 0.1441E-01 1.0006 0.1521E-01 0.1520E-01 H2S,gas 0.1356E-06 0.9959 0.1425E-06 0.1430E-06 S2,gas 0.3120E-29 1.0000 0.3291E-29 0.3291E-29 CO,gas 0.1385E-13 1.0000 0.1461E-13 0.1461E-13 SO3,gas 0.7028E-48 1.0000 0.7415E-48 0.7415E-48 SO2,gas 0.4160E-27 1.0000 0.4388E-27 0.4388E-27 HCl,gas 0.2767E-17 1.0000 0.2920E-17 0.2920E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 16 albite -0.38 -0.38 0.00 0.000 0.11184E-10 22 andradite 39.01 39.01 0.00 0.000 -0.24265E-10 23 grossular 32.73 32.73 0.00 0.000 0.00000E+00 32 apatite-OH -18.15 -18.15 0.00 0.000 0.18198E-10 46 clinochlore 39.07 39.07 0.00 0.000 0.36397E-10 47 daphnite 28.97 28.97 0.00 0.000 0.12132E-10 48 chlorite-Mn 46.87 46.87 0.00 0.000 0.24265E-10 67 diopside 16.18 16.18 0.00 0.000 0.60662E-11 68 hedenbergite 14.21 14.21 0.00 0.000 0.30331E-11 116 microcline -2.49 -2.49 0.00 0.000 0.25781E-10 163 stilbite -7.52 -7.52 0.00 0.000 -0.90992E-11 164 stilpnomelane-Fe 13.02 13.02 0.00 0.000 -0.27298E-10 245 tr.625ac.25prg.125 45.16 45.16 0.00 0.000 -0.36397E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -16.80 -10.14 -3.381 0.17318E+05 -8.443 3 CH4,gas 4.54 1.13 -3.41 -0.854 0.58296E+04 -1.715 4 H2,gas 8.00 4.48 -3.52 -2.010 0.60048E+04 -1.818 5 H2S,gas -6.23 -14.78 -8.55 -4.273 0.14591E+05 -6.846 6 S2,gas -7.34 -38.52 -31.18 -4.797 0.53242E+05 -29.483 7 CO,gas 3.21 -12.32 -15.53 -4.780 0.26525E+05 -13.835 8 SO3,gas 17.12 -32.71 -49.83 -12.457 0.85081E+05 -48.130 9 SO2,gas 0.83 -28.22 -29.06 -7.748 0.49613E+05 -27.358 10 HCl,gas 5.19 -14.04 -19.23 -9.617 0.32841E+05 -17.535 11 acmite 7.71 6.53 -1.18 -0.123 0.20179E+04 15 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 19 spessartine 24.46 19.71 -4.74 -0.237 0.81017E+04 20 analcite 3.32 2.77 -0.55 -0.061 0.93613E+03 26 annite 20.12 17.72 -2.40 -0.134 0.41063E+04 27 phlogopite 27.06 25.40 -1.67 -0.093 0.28485E+04 29 anorthite 12.71 8.27 -4.44 -0.342 0.75897E+04 35 aragonite 0.97 -3.70 -4.67 -1.556 0.79689E+04 36 brucite 12.57 9.29 -3.27 -0.655 0.55908E+04 37 calcite 0.81 -3.70 -4.51 -1.504 0.77047E+04 38 carnegieite-low 9.02 5.93 -3.09 -0.442 0.52799E+04 39 carnegieite-high 10.09 5.93 -4.16 -0.595 0.71069E+04 40 carpholite-Mg 8.58 4.46 -4.12 -0.275 0.70423E+04 41 carpholite-Fe 6.71 1.90 -4.81 -0.321 0.82201E+04 42 celadonite 5.34 3.65 -1.69 -0.099 0.28878E+04 43 celadonite-Fe 3.88 1.09 -2.79 -0.164 0.47561E+04 44 chrysotile 23.89 21.57 -2.32 -0.194 0.39691E+04 49 chlorite-Al-free 47.17 43.14 -4.04 -0.168 0.68933E+04 51 chloritoid-Fe 9.17 5.06 -4.12 -0.275 0.70309E+04 52 chloritoid-Mn 11.40 7.56 -3.84 -0.256 0.65647E+04 54 coesite -2.38 -3.16 -0.78 -0.260 0.13342E+04 61 cristobalite -2.56 -3.16 -0.60 -0.199 0.10196E+04 63 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71234E+04 65 diaspore 2.87 0.74 -2.13 -0.356 0.36446E+04 66 diamond -3.10 -7.84 -4.73 -1.353 0.80833E+04 71 enstatite 17.26 12.27 -4.99 -0.499 0.85225E+04 73 clinoenstatite 17.17 12.27 -4.89 -0.489 0.83541E+04 75 epidote 24.67 22.70 -1.97 -0.095 0.33580E+04 76 clinozoisite 22.81 18.95 -3.86 -0.175 0.65859E+04 77 epidote-Fe 29.84 26.46 -3.38 -0.176 0.57767E+04 78 fayalite 14.05 10.31 -3.73 -0.533 0.63743E+04 79 ferrosilite 11.15 7.16 -3.99 -0.399 0.68203E+04 83 gibbsite 4.08 0.74 -3.34 -0.477 0.57032E+04 84 glaucophane 22.97 20.80 -2.17 -0.059 0.37132E+04 85 glaucophane-Fe 17.28 13.12 -4.15 -0.112 0.70920E+04 86 graphite -3.55 -7.84 -4.29 -1.226 0.73256E+04 87 greenalite 16.14 13.89 -2.25 -0.187 0.38409E+04 90 hematite 12.57 8.99 -3.58 -0.434 0.61113E+04 91 heulandite -5.83 -7.52 -1.69 -0.077 0.28938E+04 95 jadeite 4.22 2.77 -1.44 -0.144 0.24616E+04 97 kalsilite 7.58 3.83 -3.76 -0.536 0.64123E+04 98 kaolinite -1.33 -4.84 -3.50 -0.319 0.59827E+04 101 laumontite 2.88 1.95 -0.93 -0.062 0.15931E+04 102 lawsonite 9.62 8.27 -1.35 -0.090 0.23064E+04 103 leucite 4.12 0.67 -3.45 -0.345 0.58872E+04 105 lizardite 23.24 21.57 -1.68 -0.140 0.28617E+04 107 magnetite 20.09 15.72 -4.37 -0.356 0.74537E+04 108 minnesotaite 10.39 7.58 -2.81 -0.165 0.48031E+04 112 manganosite 14.06 9.24 -4.82 -1.206 0.82345E+04 120 muscovite 2.58 -1.01 -3.59 -0.211 0.61308E+04 121 paragonite 4.24 1.09 -3.14 -0.185 0.53699E+04 122 nepheline 8.34 5.93 -2.41 -0.344 0.41122E+04 128 periclase-Fe 11.63 6.74 -4.89 -1.223 0.83522E+04 134 phlogopite-Na 29.65 27.50 -2.15 -0.119 0.36673E+04 136 prehnite 19.37 18.21 -1.16 -0.068 0.19843E+04 137 prehnite-Fe 22.50 21.96 -0.53 -0.032 0.91143E+03 138 pumpellyite-Fe 46.27 43.89 -2.38 -0.053 0.40565E+04 139 pumpellyite-Mg 48.99 46.45 -2.54 -0.056 0.43402E+04 143 pyrrhotite -4.26 -8.04 -3.78 -1.260 0.64546E+04 144 pyrrhotiteFe0.875 -6.02 -9.44 -3.42 -1.258 0.58419E+04 145 pyroxmangite 7.40 6.08 -1.32 -0.264 0.22550E+04 146 pyrophyllite -6.18 -11.15 -4.98 -0.311 0.84959E+04 147 quartz -2.99 -3.16 -0.17 -0.056 0.28693E+03 152 rhodonite 7.45 6.08 -1.37 -0.274 0.23352E+04 153 sanidine -1.28 -2.49 -1.21 -0.093 0.20677E+04 165 stilpnomelane-Mg 27.44 25.81 -1.63 -0.049 0.27799E+04 171 talc 16.49 15.25 -1.24 -0.073 0.21141E+04 174 tephroite 18.09 15.31 -2.77 -0.396 0.47335E+04 178 tridymite -2.63 -3.16 -0.53 -0.177 0.90690E+03 179 tremolite 47.87 47.42 -0.45 -0.012 0.77499E+03 180 ferroactinolite 38.45 34.62 -3.83 -0.104 0.65453E+04 181 troilite-low -4.41 -8.04 -3.63 -1.210 0.61974E+04 183 vesuvianite 223.47 218.82 -4.65 -0.035 0.79393E+04 187 wairakite 3.95 1.95 -2.00 -0.118 0.34151E+04 188 walstromite 11.51 9.94 -1.56 -0.313 0.26719E+04 189 wollastonite 10.46 9.94 -0.52 -0.103 0.88229E+03 190 pseudo-wollastonite 11.00 9.94 -1.06 -0.211 0.18021E+04 191 zoisite 22.85 18.95 -3.90 -0.177 0.66599E+04 192 akaganeite 7.75 4.49 -3.26 -0.705 0.55682E+04 199 chalcedony -2.80 -3.16 -0.36 -0.118 0.60622E+03 201 montmorillonite-Ca -2.29 -6.17 -3.88 -0.240 0.66178E+04 202 montmorillonite-K -2.24 -6.27 -4.03 -0.247 0.68815E+04 203 montmorillonite-Mg -2.48 -6.79 -4.31 -0.267 0.73676E+04 204 montmorillonite-Na -2.04 -5.57 -3.54 -0.216 0.60364E+04 205 nontronite-Ca 3.21 -0.20 -3.41 -0.221 0.58220E+04 206 nontronite-H 2.53 -2.36 -4.89 -0.328 0.83490E+04 207 nontronite-K 3.34 -0.30 -3.64 -0.233 0.62088E+04 208 nontronite-Mg 3.07 -0.82 -3.90 -0.253 0.66558E+04 209 nontronite-Na 3.52 0.40 -3.12 -0.200 0.53297E+04 224 tobermorite 9.82 7.76 -2.07 -0.564 0.35287E+04 230 alabandite -0.98 -5.54 -4.56 -1.521 0.77898E+04 233 boehmite 4.41 0.74 -3.67 -0.611 0.62615E+04 235 ferrous-oxide 9.81 6.74 -3.08 -0.769 0.52532E+04 240 silica-amorphous -2.09 -3.16 -1.07 -0.355 0.18204E+04 242 an20ab80 2.02 1.35 -0.67 -0.052 0.11471E+04 243 an25ab75 2.65 1.78 -0.87 -0.067 0.14808E+04 244 an30ab70 3.28 2.21 -1.07 -0.082 0.18242E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 20.0000000 g Current total amount of reactant added: 559.9990000 g New total amount of reactant added: 579.9990000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.1586E-10 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 11 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 579.9990000 Water: Moles liquid = 0.5219E+02 kg liquid = 0.9402E+00 Moles total = 0.4824E+02 kg total = 0.8690E+00 Activity = 1.0000 Stoichiometric ionic strength = .1132441E-01 Osmotic coef. = 0.9694 True ionic strength = .2001303E-01 Chg. balance for total moles = -.1586E-10 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.88270E-10 -10.0542 0.74170E-10 -10.1298 0.84026E+00 -0.0756 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.14608E-03 -3.8354 0.12200E-03 -3.9136 0.83521E+00 -0.0782 4 SO4-- 0.68793E-12 -12.1625 0.35727E-12 -12.4470 0.51934E+00 -0.2845 5 HCO3- 0.25459E-06 -6.5942 0.21295E-06 -6.6717 0.83643E+00 -0.0776 6 HS- 0.27121E-04 -4.5667 0.22655E-04 -4.6448 0.83534E+00 -0.0781 7 Al+++ 0.96855E-29 -29.0139 0.22380E-29 -29.6501 0.23107E+00 -0.6363 8 H4SiO4 0.69587E-03 -3.1575 0.69587E-03 -3.1575 0.10000E+01 0.0000 9 Ca++ 0.13493E-06 -6.8699 0.69560E-07 -7.1576 0.51553E+00 -0.2877 10 Mg++ 0.21109E-10 -10.6755 0.10832E-10 -10.9653 0.51317E+00 -0.2897 11 Fe++ 0.58173E-13 -13.2353 0.29885E-13 -13.5245 0.51374E+00 -0.2893 12 K+ 0.15647E-03 -3.8056 0.13091E-03 -3.8830 0.83663E+00 -0.0775 13 Na+ 0.19856E-01 -1.7021 0.16581E-01 -1.7804 0.83506E+00 -0.0783 14 Mn++ 0.18412E-10 -10.7349 0.94667E-11 -11.0238 0.51416E+00 -0.2889 15 HPO4-- 0.45328E-07 -7.3436 0.23544E-07 -7.6281 0.51942E+00 -0.2845 16 HSiO3- 0.10489E-01 -1.9793 0.87604E-02 -2.0575 0.83521E+00 -0.0782 17 Ca(HSiO3)+ 0.16584E-07 -7.7803 0.13878E-07 -7.8577 0.83681E+00 -0.0774 18 Mg(HSiO3)+ 0.32141E-11 -11.4929 0.26896E-11 -11.5703 0.83681E+00 -0.0774 19 NaHSiO3,aq 0.23493E-02 -2.6291 0.23493E-02 -2.6291 0.10000E+01 0.0000 20 AlO+ 0.66139E-16 -16.1795 0.55346E-16 -16.2569 0.83681E+00 -0.0774 22 HAlO2,aq 0.14860E-09 -9.8280 0.14860E-09 -9.8280 0.10000E+01 0.0000 23 AlO2- 0.53197E-05 -5.2741 0.44351E-05 -5.3531 0.83371E+00 -0.0790 24 CH4,aq 0.13162E-04 -4.8807 0.13117E-04 -4.8822 0.99655E+00 -0.0015 25 C2H6,aq 0.25473E-14 -14.5939 0.25385E-14 -14.5954 0.99655E+00 -0.0015 29 CO,aq 0.98233E-17 -17.0077 0.98233E-17 -17.0077 0.10000E+01 0.0000 30 CO2,aq 0.33866E-10 -10.4702 0.33749E-10 -10.4717 0.99655E+00 -0.0015 31 CO3-2 0.48390E-06 -6.3152 0.25078E-06 -6.6007 0.51824E+00 -0.2855 32 CaCO3,aq 0.21873E-09 -9.6601 0.21873E-09 -9.6601 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.45184E-12 -12.3450 0.37810E-12 -12.4224 0.83681E+00 -0.0774 34 CaCl+ 0.16412E-10 -10.7848 0.13734E-10 -10.8622 0.83681E+00 -0.0774 35 CaCl2,aq 0.39809E-15 -15.4000 0.39809E-15 -15.4000 0.10000E+01 0.0000 36 CaOH+ 0.79874E-07 -7.0976 0.66839E-07 -7.1750 0.83681E+00 -0.0774 37 CaSO4,aq 0.78915E-17 -17.1028 0.78915E-17 -17.1028 0.10000E+01 0.0000 38 HCl,aq 0.16582E-14 -14.7804 0.16582E-14 -14.7804 0.10000E+01 0.0000 43 FeCl+ 0.68967E-17 -17.1614 0.57713E-17 -17.2387 0.83681E+00 -0.0774 46 FeO,aq 0.21114E-09 -9.6754 0.21114E-09 -9.6754 0.10000E+01 0.0000 47 FeOH+ 0.15674E-10 -10.8048 0.13116E-10 -10.8822 0.83681E+00 -0.0774 48 HFeO2- 0.35662E-07 -7.4478 0.29785E-07 -7.5260 0.83521E+00 -0.0782 49 FeO+ 0.10983E-16 -16.9593 0.91905E-17 -17.0367 0.83681E+00 -0.0774 51 FeO2- 0.40929E-09 -9.3880 0.34185E-09 -9.4662 0.83521E+00 -0.0782 52 HFeO2,aq 0.32247E-11 -11.4915 0.32247E-11 -11.4915 0.10000E+01 0.0000 53 H2,aq 0.11627E-04 -4.9345 0.11587E-04 -4.9360 0.99655E+00 -0.0015 54 KCl,aq 0.28947E-09 -9.5384 0.28947E-09 -9.5384 0.10000E+01 0.0000 56 KOH,aq 0.75375E-06 -6.1228 0.75375E-06 -6.1228 0.10000E+01 0.0000 57 KSO4- 0.86895E-15 -15.0610 0.72576E-15 -15.1392 0.83521E+00 -0.0782 58 MgCO3,aq 0.85379E-14 -14.0686 0.85379E-14 -14.0686 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.71900E-16 -16.1433 0.60167E-16 -16.2206 0.83681E+00 -0.0774 60 MgCl+ 0.23165E-14 -14.6352 0.19385E-14 -14.7125 0.83681E+00 -0.0774 61 MgOH+ 0.68830E-10 -10.1622 0.57597E-10 -10.2396 0.83681E+00 -0.0774 63 MnO,aq 0.17821E-08 -8.7491 0.17821E-08 -8.7491 0.10000E+01 0.0000 64 MnOH+ 0.46122E-09 -9.3361 0.38595E-09 -9.4135 0.83681E+00 -0.0774 65 MnO2-2 0.20745E-10 -10.6831 0.10751E-10 -10.9685 0.51824E+00 -0.2855 66 HMnO2- 0.20917E-09 -9.6795 0.17470E-09 -9.7577 0.83521E+00 -0.0782 69 MnCl+ 0.84993E-14 -14.0706 0.71123E-14 -14.1480 0.83681E+00 -0.0774 71 NaCl,aq 0.67040E-06 -6.1737 0.67040E-06 -6.1737 0.10000E+01 0.0000 72 NaOH,aq 0.96047E-04 -4.0175 0.96047E-04 -4.0175 0.10000E+01 0.0000 74 OH- 0.93437E-02 -2.0295 0.77899E-02 -2.1085 0.83371E+00 -0.0790 79 HPO3-2 0.16404E-14 -14.7850 0.85014E-15 -15.0705 0.51824E+00 -0.2855 81 H2PO3- 0.15139E-18 -18.8199 0.12644E-18 -18.8981 0.83521E+00 -0.0782 82 H3PO4,aq 0.90586E-18 -18.0429 0.90586E-18 -18.0429 0.10000E+01 0.0000 83 H2PO4- 0.38533E-10 -10.4142 0.32214E-10 -10.4920 0.83600E+00 -0.0778 84 PO4-3 0.10672E-08 -8.9718 0.25899E-09 -9.5867 0.24269E+00 -0.6150 88 HP2O7-3 0.94706E-18 -18.0236 0.21905E-18 -18.6594 0.23130E+00 -0.6358 89 P2O7-4 0.91478E-17 -17.0387 0.70556E-18 -18.1515 0.77129E-01 -1.1128 90 H2S,aq 0.52112E-08 -8.2831 0.51932E-08 -8.2846 0.99655E+00 -0.0015 91 S2-2 0.18939E-14 -14.7226 0.98151E-15 -15.0081 0.51824E+00 -0.2855 97 SO3-2 0.10232E-17 -17.9900 0.53795E-18 -18.2693 0.52573E+00 -0.2792 99 HSO4- 0.30488E-19 -19.5159 0.25537E-19 -19.5928 0.83763E+00 -0.0769 Charge balance for all species = -.1687E-10 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.8826974E-10 -.2230344E-01 -.2244147E+02 0.0000 2 H2O 0.1000000E+01 0.5550489E+02 0.9981998E+06 0.0000 3 Cl- 0.1460761E-03 0.1467468E-03 0.5193574E+01 6.2161 4 SO4-- 0.6879275E-12 -.1606898E-04 -.1540930E+01 7.8125 5 HCO3- 0.2545889E-06 0.1390101E-04 0.8467269E+00 3.4580 6 HS- 0.2712087E-04 0.4319506E-04 0.1426065E+01 5.4849 7 Al+++ 0.9685511E-29 0.5319843E-05 0.1432879E+00 0.7392 8 H4SiO4 0.6958676E-03 0.1353400E-01 0.1298565E+04 -3.1575 9 Ca++ 0.1349277E-06 0.2316209E-06 0.9266772E-02 13.1019 10 Mg++ 0.2110878E-10 0.9316333E-10 0.2261052E-05 9.2943 11 Fe++ 0.5817284E-13 0.3630128E-07 0.2023795E-02 6.7350 12 K+ 0.1564722E-03 0.1572263E-03 0.6137180E+01 6.2467 13 Na+ 0.1985552E-01 0.2230151E-01 0.5118164E+03 8.3494 14 Mn++ 0.1841195E-10 0.2491668E-08 0.1366494E-03 9.2357 15 HPO4-- 0.4532776E-07 0.4643348E-07 0.4448895E-02 12.6314 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.9603909E+01 -.2097013E-01 -.9582939E+01 0.0000000E+00 2 H2O 0.4823772E+02 0.5218678E+02 -.3949056E+01 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.1609925E-01 -.1510837E-04 0.1611436E-01 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.1607375E-01 0.4061284E-04 -.1611436E-01 0.0000000E+00 7 Al+++ 0.1891227E+01 0.5001820E-05 0.1891222E+01 0.0000000E+00 8 H4SiO4 0.6039404E+01 0.1272493E-01 0.6026679E+01 0.0000000E+00 9 Ca++ 0.6670961E+00 0.2177745E-06 0.6670958E+00 0.0000000E+00 10 Mg++ 0.4603167E+00 0.8759399E-10 0.4603167E+00 0.0000000E+00 11 Fe++ 0.4135443E+00 0.3413117E-07 0.4135442E+00 0.0000000E+00 12 K+ 0.1231420E+00 0.1478272E-03 0.1229942E+00 0.0000000E+00 13 Na+ 0.7282001E+00 0.2096832E-01 0.7072318E+00 0.0000000E+00 14 Mn++ 0.1005637E-01 0.2342715E-08 0.1005637E-01 0.0000000E+00 15 HPO4-- 0.3432189E-02 0.4365766E-07 0.3432145E-02 0.0000000E+00 Chg. balance for solid moles: 0.1549E-14 Mass of aqueous solution: 0.941856E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 579.9990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 0.7065 -0.151 185.3 2.268 29.25 71.12 andradite 0.6446E-01 -1.191 32.76 1.515 5.171 8.510 grossular 0.1562E-01 -1.806 7.035 0.847 1.111 1.957 apatite-OH 0.1144E-02 -2.942 0.5747 -0.241 0.9072E-01 0.1826 clinochlore 0.8352E-01 -1.078 46.43 1.667 7.329 17.66 daphnite 0.2418E-01 -1.617 17.25 1.237 2.723 5.227 chlorite-Mn 0.2011E-02 -2.697 1.426 0.154 0.2251 0.4544 diopside 0.2229E-01 -1.652 4.826 0.684 0.7619 1.475 hedenbergite 0.5779E-02 -2.238 1.434 0.156 0.2263 0.3927 microcline 0.1079 -0.967 30.03 1.478 4.741 11.73 stilbite 0.3818 -0.418 269.1 2.430 42.48 125.5 stilpnomelane-Fe 0.3019E-01 -1.520 32.54 1.512 5.137 11.24 tr.625ac.25prg.125 0.5630E-02 -2.249 4.812 0.682 0.7597 1.549 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8050E+00 0.8050E+00 1.0000 -0.094 grossular 0.1950E+00 0.1950E+00 1.0000 -0.710 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.7613E+00 0.7613E+00 1.0000 -0.118 daphnite 0.2204E+00 0.2204E+00 1.0000 -0.657 chlorite-Mn 0.1833E-01 0.1833E-01 1.0000 -1.737 diopside 0.7941E+00 0.7941E+00 1.0000 -0.100 hedenbergite 0.2059E+00 0.2059E+00 1.0000 -0.686 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 tr.625ac.25prg.125 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 633.458547 g Volume = 257.002423 cm3 Porosity: -10.3017% V(tot) - V(min): -.24003E+02 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 579.9990000 g log = 2.7634 Original solution: 1000.0103000 g Original solution / Rock added: 1.72 (Water/Rock Ratio), log = 0.2366 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0551 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9675E+00 0.9855 0.1006E+01 0.1021E+01 CO2,gas 0.3399E-08 1.0069 0.3611E-08 0.3586E-08 CH4,gas 0.1807E-01 1.0125 0.1931E-01 0.1907E-01 H2,gas 0.1441E-01 1.0006 0.1521E-01 0.1520E-01 H2S,gas 0.1359E-06 0.9959 0.1428E-06 0.1433E-06 S2,gas 0.3133E-29 1.0000 0.3306E-29 0.3306E-29 CO,gas 0.1387E-13 1.0000 0.1464E-13 0.1464E-13 SO3,gas 0.7043E-48 1.0000 0.7431E-48 0.7431E-48 SO2,gas 0.4169E-27 1.0000 0.4398E-27 0.4398E-27 HCl,gas 0.2773E-17 1.0000 0.2926E-17 0.2926E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 16 albite -0.38 -0.38 0.00 0.000 -0.94784E-12 22 andradite 39.01 39.01 0.00 0.000 -0.12132E-10 23 grossular 32.73 32.73 0.00 0.000 0.12132E-10 32 apatite-OH -18.15 -18.15 0.00 0.000 -0.12132E-10 46 clinochlore 39.07 39.07 0.00 0.000 -0.12132E-10 47 daphnite 28.97 28.97 0.00 0.000 -0.54595E-10 48 chlorite-Mn 46.87 46.87 0.00 0.000 -0.12132E-10 67 diopside 16.18 16.18 0.00 0.000 -0.60662E-11 68 hedenbergite 14.21 14.21 0.00 0.000 -0.15165E-10 116 microcline -2.49 -2.49 0.00 0.000 -0.10616E-10 163 stilbite -7.52 -7.52 0.00 0.000 -0.90992E-11 164 stilpnomelane-Fe 13.02 13.02 0.00 0.000 -0.27298E-10 245 tr.625ac.25prg.125 45.16 45.16 0.00 0.000 0.24265E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -16.80 -10.14 -3.380 0.17316E+05 -8.442 3 CH4,gas 4.54 1.13 -3.41 -0.853 0.58280E+04 -1.714 4 H2,gas 8.00 4.48 -3.52 -2.010 0.60048E+04 -1.818 5 H2S,gas -6.23 -14.77 -8.54 -4.272 0.14589E+05 -6.845 6 S2,gas -7.34 -38.52 -31.18 -4.797 0.53238E+05 -29.481 7 CO,gas 3.21 -12.32 -15.53 -4.780 0.26523E+05 -13.834 8 SO3,gas 17.12 -32.71 -49.83 -12.457 0.85080E+05 -48.129 9 SO2,gas 0.83 -28.22 -29.06 -7.748 0.49612E+05 -27.357 10 HCl,gas 5.19 -14.04 -19.23 -9.616 0.32839E+05 -17.534 11 acmite 7.71 6.53 -1.18 -0.123 0.20178E+04 15 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 19 spessartine 24.46 19.71 -4.74 -0.237 0.81005E+04 20 analcite 3.32 2.77 -0.55 -0.061 0.93613E+03 26 annite 20.12 17.72 -2.40 -0.134 0.41063E+04 27 phlogopite 27.06 25.40 -1.67 -0.093 0.28485E+04 29 anorthite 12.71 8.27 -4.45 -0.342 0.75897E+04 35 aragonite 0.97 -3.70 -4.67 -1.555 0.79673E+04 36 brucite 12.57 9.29 -3.27 -0.655 0.55908E+04 37 calcite 0.81 -3.70 -4.51 -1.504 0.77030E+04 38 carnegieite-low 9.02 5.93 -3.09 -0.442 0.52799E+04 39 carnegieite-high 10.09 5.93 -4.16 -0.595 0.71069E+04 40 carpholite-Mg 8.58 4.46 -4.12 -0.275 0.70423E+04 41 carpholite-Fe 6.71 1.90 -4.81 -0.321 0.82201E+04 42 celadonite 5.34 3.65 -1.69 -0.099 0.28878E+04 43 celadonite-Fe 3.88 1.09 -2.79 -0.164 0.47561E+04 44 chrysotile 23.89 21.57 -2.32 -0.194 0.39691E+04 49 chlorite-Al-free 47.17 43.14 -4.04 -0.168 0.68933E+04 51 chloritoid-Fe 9.17 5.06 -4.12 -0.275 0.70309E+04 52 chloritoid-Mn 11.40 7.56 -3.84 -0.256 0.65643E+04 54 coesite -2.38 -3.16 -0.78 -0.260 0.13342E+04 61 cristobalite -2.56 -3.16 -0.60 -0.199 0.10196E+04 63 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71234E+04 65 diaspore 2.87 0.74 -2.13 -0.356 0.36446E+04 66 diamond -3.10 -7.84 -4.73 -1.352 0.80817E+04 71 enstatite 17.26 12.27 -4.99 -0.499 0.85225E+04 73 clinoenstatite 17.17 12.27 -4.89 -0.489 0.83541E+04 75 epidote 24.67 22.70 -1.97 -0.095 0.33580E+04 76 clinozoisite 22.81 18.95 -3.86 -0.175 0.65859E+04 77 epidote-Fe 29.84 26.46 -3.38 -0.176 0.57767E+04 78 fayalite 14.05 10.31 -3.73 -0.533 0.63743E+04 79 ferrosilite 11.15 7.16 -3.99 -0.399 0.68203E+04 83 gibbsite 4.08 0.74 -3.34 -0.477 0.57032E+04 84 glaucophane 22.97 20.80 -2.17 -0.059 0.37132E+04 85 glaucophane-Fe 17.28 13.12 -4.15 -0.112 0.70920E+04 86 graphite -3.55 -7.84 -4.29 -1.226 0.73240E+04 87 greenalite 16.14 13.89 -2.25 -0.187 0.38409E+04 90 hematite 12.57 8.99 -3.58 -0.434 0.61113E+04 91 heulandite -5.83 -7.52 -1.69 -0.077 0.28938E+04 95 jadeite 4.22 2.77 -1.44 -0.144 0.24616E+04 97 kalsilite 7.58 3.83 -3.76 -0.536 0.64123E+04 98 kaolinite -1.33 -4.84 -3.50 -0.319 0.59827E+04 101 laumontite 2.88 1.95 -0.93 -0.062 0.15931E+04 102 lawsonite 9.62 8.27 -1.35 -0.090 0.23064E+04 103 leucite 4.12 0.67 -3.45 -0.345 0.58872E+04 105 lizardite 23.24 21.57 -1.68 -0.140 0.28617E+04 107 magnetite 20.09 15.72 -4.37 -0.356 0.74537E+04 108 minnesotaite 10.39 7.58 -2.81 -0.165 0.48031E+04 112 manganosite 14.06 9.24 -4.82 -1.206 0.82341E+04 120 muscovite 2.58 -1.01 -3.59 -0.211 0.61308E+04 121 paragonite 4.24 1.09 -3.14 -0.185 0.53699E+04 122 nepheline 8.34 5.93 -2.41 -0.344 0.41122E+04 128 periclase-Fe 11.63 6.74 -4.89 -1.223 0.83522E+04 134 phlogopite-Na 29.65 27.50 -2.15 -0.119 0.36673E+04 136 prehnite 19.37 18.21 -1.16 -0.068 0.19843E+04 137 prehnite-Fe 22.50 21.96 -0.53 -0.032 0.91143E+03 138 pumpellyite-Fe 46.27 43.89 -2.38 -0.053 0.40565E+04 139 pumpellyite-Mg 48.99 46.45 -2.54 -0.056 0.43403E+04 143 pyrrhotite -4.26 -8.04 -3.78 -1.260 0.64530E+04 144 pyrrhotiteFe0.875 -6.02 -9.44 -3.42 -1.258 0.58403E+04 145 pyroxmangite 7.40 6.08 -1.32 -0.264 0.22546E+04 146 pyrophyllite -6.18 -11.15 -4.98 -0.311 0.84959E+04 147 quartz -2.99 -3.16 -0.17 -0.056 0.28692E+03 152 rhodonite 7.45 6.08 -1.37 -0.273 0.23348E+04 153 sanidine -1.28 -2.49 -1.21 -0.093 0.20677E+04 165 stilpnomelane-Mg 27.44 25.81 -1.63 -0.049 0.27799E+04 171 talc 16.49 15.25 -1.24 -0.073 0.21141E+04 174 tephroite 18.09 15.31 -2.77 -0.396 0.47327E+04 178 tridymite -2.63 -3.16 -0.53 -0.177 0.90690E+03 179 tremolite 47.87 47.42 -0.45 -0.012 0.77498E+03 180 ferroactinolite 38.45 34.62 -3.83 -0.104 0.65453E+04 181 troilite-low -4.41 -8.04 -3.63 -1.210 0.61958E+04 183 vesuvianite 223.47 218.82 -4.65 -0.035 0.79395E+04 187 wairakite 3.95 1.95 -2.00 -0.118 0.34151E+04 188 walstromite 11.51 9.94 -1.56 -0.313 0.26719E+04 189 wollastonite 10.46 9.94 -0.52 -0.103 0.88229E+03 190 pseudo-wollastonite 11.00 9.94 -1.06 -0.211 0.18021E+04 191 zoisite 22.85 18.95 -3.90 -0.177 0.66600E+04 192 akaganeite 7.75 4.49 -3.26 -0.705 0.55682E+04 199 chalcedony -2.80 -3.16 -0.36 -0.118 0.60622E+03 201 montmorillonite-Ca -2.29 -6.17 -3.88 -0.240 0.66179E+04 202 montmorillonite-K -2.24 -6.27 -4.03 -0.247 0.68815E+04 203 montmorillonite-Mg -2.48 -6.79 -4.31 -0.267 0.73676E+04 204 montmorillonite-Na -2.04 -5.57 -3.54 -0.216 0.60364E+04 205 nontronite-Ca 3.21 -0.20 -3.41 -0.221 0.58220E+04 206 nontronite-H 2.53 -2.36 -4.89 -0.328 0.83490E+04 207 nontronite-K 3.34 -0.30 -3.64 -0.233 0.62088E+04 208 nontronite-Mg 3.07 -0.82 -3.90 -0.253 0.66558E+04 209 nontronite-Na 3.52 0.40 -3.12 -0.200 0.53297E+04 224 tobermorite 9.82 7.76 -2.07 -0.564 0.35287E+04 230 alabandite -0.98 -5.54 -4.56 -1.520 0.77878E+04 233 boehmite 4.41 0.74 -3.67 -0.611 0.62615E+04 235 ferrous-oxide 9.81 6.74 -3.08 -0.769 0.52532E+04 240 silica-amorphous -2.09 -3.16 -1.07 -0.355 0.18204E+04 242 an20ab80 2.02 1.35 -0.67 -0.052 0.11471E+04 243 an25ab75 2.65 1.78 -0.87 -0.067 0.14808E+04 244 an30ab70 3.28 2.21 -1.07 -0.082 0.18242E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 20.0000000 g Current total amount of reactant added: 579.9990000 g New total amount of reactant added: 599.9990000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.1586E-10 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 11 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 599.9990000 Water: Moles liquid = 0.5208E+02 kg liquid = 0.9382E+00 Moles total = 0.4799E+02 kg total = 0.8645E+00 Activity = 1.0000 Stoichiometric ionic strength = .1132469E-01 Osmotic coef. = 0.9694 True ionic strength = .2001327E-01 Chg. balance for total moles = -.1586E-10 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.88271E-10 -10.0542 0.74171E-10 -10.1298 0.84026E+00 -0.0756 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.14639E-03 -3.8345 0.12227E-03 -3.9127 0.83521E+00 -0.0782 4 SO4-- 0.68943E-12 -12.1615 0.35805E-12 -12.4461 0.51934E+00 -0.2845 5 HCO3- 0.25515E-06 -6.5932 0.21341E-06 -6.6708 0.83643E+00 -0.0776 6 HS- 0.27179E-04 -4.5658 0.22704E-04 -4.6439 0.83534E+00 -0.0781 7 Al+++ 0.96857E-29 -29.0139 0.22380E-29 -29.6501 0.23107E+00 -0.6363 8 H4SiO4 0.69587E-03 -3.1575 0.69587E-03 -3.1575 0.10000E+01 0.0000 9 Ca++ 0.13493E-06 -6.8699 0.69561E-07 -7.1576 0.51553E+00 -0.2877 10 Mg++ 0.21109E-10 -10.6755 0.10833E-10 -10.9653 0.51317E+00 -0.2897 11 Fe++ 0.58174E-13 -13.2353 0.29886E-13 -13.5245 0.51373E+00 -0.2893 12 K+ 0.15647E-03 -3.8056 0.13091E-03 -3.8830 0.83663E+00 -0.0775 13 Na+ 0.19856E-01 -1.7021 0.16581E-01 -1.7804 0.83506E+00 -0.0783 14 Mn++ 0.18422E-10 -10.7347 0.94717E-11 -11.0236 0.51416E+00 -0.2889 15 HPO4-- 0.45327E-07 -7.3436 0.23544E-07 -7.6281 0.51942E+00 -0.2845 16 HSiO3- 0.10489E-01 -1.9793 0.87604E-02 -2.0575 0.83521E+00 -0.0782 17 Ca(HSiO3)+ 0.16584E-07 -7.7803 0.13878E-07 -7.8577 0.83681E+00 -0.0774 18 Mg(HSiO3)+ 0.32141E-11 -11.4929 0.26896E-11 -11.5703 0.83681E+00 -0.0774 19 NaHSiO3,aq 0.23493E-02 -2.6291 0.23493E-02 -2.6291 0.10000E+01 0.0000 20 AlO+ 0.66138E-16 -16.1795 0.55345E-16 -16.2569 0.83681E+00 -0.0774 22 HAlO2,aq 0.14860E-09 -9.8280 0.14860E-09 -9.8280 0.10000E+01 0.0000 23 AlO2- 0.53195E-05 -5.2741 0.44349E-05 -5.3531 0.83371E+00 -0.0790 24 CH4,aq 0.13190E-04 -4.8797 0.13145E-04 -4.8812 0.99655E+00 -0.0015 25 C2H6,aq 0.25582E-14 -14.5921 0.25494E-14 -14.5936 0.99655E+00 -0.0015 29 CO,aq 0.98447E-17 -17.0068 0.98447E-17 -17.0068 0.10000E+01 0.0000 30 CO2,aq 0.33940E-10 -10.4693 0.33823E-10 -10.4708 0.99655E+00 -0.0015 31 CO3-2 0.48495E-06 -6.3143 0.25132E-06 -6.5998 0.51824E+00 -0.2855 32 CaCO3,aq 0.21921E-09 -9.6591 0.21921E-09 -9.6591 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.45283E-12 -12.3441 0.37894E-12 -12.4214 0.83681E+00 -0.0774 34 CaCl+ 0.16448E-10 -10.7839 0.13764E-10 -10.8613 0.83681E+00 -0.0774 35 CaCl2,aq 0.39980E-15 -15.3982 0.39980E-15 -15.3982 0.10000E+01 0.0000 36 CaOH+ 0.79874E-07 -7.0976 0.66840E-07 -7.1750 0.83681E+00 -0.0774 37 CaSO4,aq 0.79089E-17 -17.1019 0.79089E-17 -17.1019 0.10000E+01 0.0000 38 HCl,aq 0.16618E-14 -14.7794 0.16618E-14 -14.7794 0.10000E+01 0.0000 43 FeCl+ 0.69116E-17 -17.1604 0.57837E-17 -17.2378 0.83681E+00 -0.0774 46 FeO,aq 0.21114E-09 -9.6754 0.21114E-09 -9.6754 0.10000E+01 0.0000 47 FeOH+ 0.15674E-10 -10.8048 0.13116E-10 -10.8822 0.83681E+00 -0.0774 48 HFeO2- 0.35661E-07 -7.4478 0.29785E-07 -7.5260 0.83521E+00 -0.0782 49 FeO+ 0.10983E-16 -16.9593 0.91906E-17 -17.0367 0.83681E+00 -0.0774 51 FeO2- 0.40929E-09 -9.3880 0.34184E-09 -9.4662 0.83521E+00 -0.0782 52 HFeO2,aq 0.32248E-11 -11.4915 0.32248E-11 -11.4915 0.10000E+01 0.0000 53 H2,aq 0.11627E-04 -4.9345 0.11587E-04 -4.9360 0.99655E+00 -0.0015 54 KCl,aq 0.29010E-09 -9.5375 0.29010E-09 -9.5375 0.10000E+01 0.0000 56 KOH,aq 0.75375E-06 -6.1228 0.75375E-06 -6.1228 0.10000E+01 0.0000 57 KSO4- 0.87086E-15 -15.0601 0.72735E-15 -15.1383 0.83521E+00 -0.0782 58 MgCO3,aq 0.85566E-14 -14.0677 0.85566E-14 -14.0677 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.72058E-16 -16.1423 0.60299E-16 -16.2197 0.83681E+00 -0.0774 60 MgCl+ 0.23215E-14 -14.6342 0.19427E-14 -14.7116 0.83681E+00 -0.0774 61 MgOH+ 0.68830E-10 -10.1622 0.57598E-10 -10.2396 0.83681E+00 -0.0774 63 MnO,aq 0.17830E-08 -8.7488 0.17830E-08 -8.7488 0.10000E+01 0.0000 64 MnOH+ 0.46146E-09 -9.3359 0.38615E-09 -9.4132 0.83681E+00 -0.0774 65 MnO2-2 0.20755E-10 -10.6829 0.10756E-10 -10.9683 0.51824E+00 -0.2855 66 HMnO2- 0.20927E-09 -9.6793 0.17478E-09 -9.7575 0.83521E+00 -0.0782 69 MnCl+ 0.85220E-14 -14.0695 0.71313E-14 -14.1468 0.83681E+00 -0.0774 71 NaCl,aq 0.67184E-06 -6.1727 0.67184E-06 -6.1727 0.10000E+01 0.0000 72 NaOH,aq 0.96047E-04 -4.0175 0.96047E-04 -4.0175 0.10000E+01 0.0000 74 OH- 0.93436E-02 -2.0295 0.77898E-02 -2.1085 0.83371E+00 -0.0790 79 HPO3-2 0.16404E-14 -14.7850 0.85012E-15 -15.0705 0.51824E+00 -0.2855 81 H2PO3- 0.15139E-18 -18.8199 0.12644E-18 -18.8981 0.83521E+00 -0.0782 82 H3PO4,aq 0.90587E-18 -18.0429 0.90587E-18 -18.0429 0.10000E+01 0.0000 83 H2PO4- 0.38533E-10 -10.4142 0.32214E-10 -10.4920 0.83600E+00 -0.0778 84 PO4-3 0.10672E-08 -8.9718 0.25899E-09 -9.5867 0.24269E+00 -0.6150 88 HP2O7-3 0.94706E-18 -18.0236 0.21905E-18 -18.6595 0.23130E+00 -0.6358 89 P2O7-4 0.91477E-17 -17.0387 0.70554E-18 -18.1515 0.77128E-01 -1.1128 90 H2S,aq 0.52224E-08 -8.2821 0.52044E-08 -8.2836 0.99655E+00 -0.0015 91 S2-2 0.19021E-14 -14.7208 0.98573E-15 -15.0062 0.51824E+00 -0.2855 97 SO3-2 0.10255E-17 -17.9891 0.53912E-18 -18.2683 0.52573E+00 -0.2792 99 HSO4- 0.30555E-19 -19.5149 0.25593E-19 -19.5919 0.83763E+00 -0.0769 Charge balance for all species = -.1691E-10 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.8827078E-10 -.2230331E-01 -.2244134E+02 0.0000 2 H2O 0.1000000E+01 0.5550489E+02 0.9981998E+06 0.0000 3 Cl- 0.1463888E-03 0.1470609E-03 0.5204692E+01 6.2171 4 SO4-- 0.6894330E-12 -.1609709E-04 -.1543626E+01 7.8135 5 HCO3- 0.2551451E-06 0.1393077E-04 0.8485395E+00 3.4590 6 HS- 0.2717893E-04 0.4328124E-04 0.1428910E+01 5.4859 7 Al+++ 0.9685725E-29 0.5319694E-05 0.1432839E+00 0.7392 8 H4SiO4 0.6958718E-03 0.1353397E-01 0.1298563E+04 -3.1575 9 Ca++ 0.1349302E-06 0.2316246E-06 0.9266921E-02 13.1019 10 Mg++ 0.2110917E-10 0.9316410E-10 0.2261070E-05 9.2943 11 Fe++ 0.5817416E-13 0.3630083E-07 0.2023770E-02 6.7350 12 K+ 0.1564740E-03 0.1572281E-03 0.6137251E+01 6.2467 13 Na+ 0.1985576E-01 0.2230176E-01 0.5118221E+03 8.3494 14 Mn++ 0.1842167E-10 0.2492924E-08 0.1367183E-03 9.2360 15 HPO4-- 0.4532737E-07 0.4643307E-07 0.4448856E-02 12.6314 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.9935080E+01 -.2092522E-01 -.9914154E+01 0.0000000E+00 2 H2O 0.4798702E+02 0.5207530E+02 -.4088281E+01 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.1665352E-01 -.1510247E-04 0.1666862E-01 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.1662802E-01 0.4060694E-04 -.1666862E-01 0.0000000E+00 7 Al+++ 0.1956442E+01 0.4990995E-05 0.1956437E+01 0.0000000E+00 8 H4SiO4 0.6247659E+01 0.1269772E-01 0.6234962E+01 0.0000000E+00 9 Ca++ 0.6900989E+00 0.2173127E-06 0.6900987E+00 0.0000000E+00 10 Mg++ 0.4761897E+00 0.8740758E-10 0.4761897E+00 0.0000000E+00 11 Fe++ 0.4278044E+00 0.3405784E-07 0.4278044E+00 0.0000000E+00 12 K+ 0.1273883E+00 0.1475131E-03 0.1272408E+00 0.0000000E+00 13 Na+ 0.7533050E+00 0.2092376E-01 0.7323812E+00 0.0000000E+00 14 Mn++ 0.1040314E-01 0.2338889E-08 0.1040314E-01 0.0000000E+00 15 HPO4-- 0.3550540E-02 0.4356402E-07 0.3550496E-02 0.0000000E+00 Chg. balance for solid moles: 0.5967E-15 Mass of aqueous solution: 0.939844E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 599.9990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 0.7317 -0.136 191.9 2.283 29.28 73.65 andradite 0.6667E-01 -1.176 33.88 1.530 5.170 8.803 grossular 0.1615E-01 -1.792 7.277 0.862 1.110 2.025 apatite-OH 0.1183E-02 -2.927 0.5945 -0.226 0.9072E-01 0.1889 clinochlore 0.8636E-01 -1.064 48.00 1.681 7.325 18.26 daphnite 0.2500E-01 -1.602 17.84 1.251 2.722 5.405 chlorite-Mn 0.2081E-02 -2.682 1.475 0.169 0.2251 0.4701 diopside 0.2337E-01 -1.631 5.062 0.704 0.7725 1.547 hedenbergite 0.6061E-02 -2.217 1.504 0.177 0.2295 0.4119 microcline 0.1116 -0.952 31.07 1.492 4.741 12.14 stilbite 0.3947 -0.404 278.1 2.444 42.44 129.7 stilpnomelane-Fe 0.3123E-01 -1.505 33.67 1.527 5.138 11.63 tr.625ac.25prg.125 0.5797E-02 -2.237 4.955 0.695 0.7561 1.595 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8050E+00 0.8050E+00 1.0000 -0.094 grossular 0.1950E+00 0.1950E+00 1.0000 -0.710 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.7613E+00 0.7613E+00 1.0000 -0.118 daphnite 0.2204E+00 0.2204E+00 1.0000 -0.657 chlorite-Mn 0.1834E-01 0.1834E-01 1.0000 -1.737 diopside 0.7941E+00 0.7941E+00 1.0000 -0.100 hedenbergite 0.2059E+00 0.2059E+00 1.0000 -0.686 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 tr.625ac.25prg.125 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 655.308677 g Volume = 265.843036 cm3 Porosity: -10.3085% V(tot) - V(min): -.24843E+02 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 599.9990000 g log = 2.7782 Original solution: 1000.0103000 g Original solution / Rock added: 1.67 (Water/Rock Ratio), log = 0.2219 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0551 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9675E+00 0.9855 0.1006E+01 0.1021E+01 CO2,gas 0.3406E-08 1.0069 0.3619E-08 0.3594E-08 CH4,gas 0.1811E-01 1.0125 0.1935E-01 0.1911E-01 H2,gas 0.1441E-01 1.0006 0.1521E-01 0.1520E-01 H2S,gas 0.1362E-06 0.9959 0.1431E-06 0.1437E-06 S2,gas 0.3147E-29 1.0000 0.3320E-29 0.3320E-29 CO,gas 0.1390E-13 1.0000 0.1467E-13 0.1467E-13 SO3,gas 0.7059E-48 1.0000 0.7448E-48 0.7448E-48 SO2,gas 0.4178E-27 1.0000 0.4408E-27 0.4408E-27 HCl,gas 0.2779E-17 1.0000 0.2932E-17 0.2932E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 16 albite -0.38 -0.38 0.00 0.000 0.11184E-10 22 andradite 39.01 39.01 0.00 0.000 0.00000E+00 23 grossular 32.73 32.73 0.00 0.000 -0.24265E-10 32 apatite-OH -18.15 -18.15 0.00 0.000 0.12132E-10 46 clinochlore 39.07 39.07 0.00 0.000 0.24265E-10 47 daphnite 28.97 28.97 0.00 0.000 0.12132E-10 48 chlorite-Mn 46.87 46.87 0.00 0.000 0.36397E-10 67 diopside 16.18 16.18 0.00 0.000 0.12132E-10 68 hedenbergite 14.21 14.21 0.00 0.000 0.90992E-11 116 microcline -2.49 -2.49 0.00 0.000 0.13649E-10 163 stilbite -7.52 -7.52 0.00 0.000 0.15165E-10 164 stilpnomelane-Fe 13.02 13.02 0.00 0.000 0.21232E-10 245 tr.625ac.25prg.125 45.16 45.16 0.00 0.000 0.24265E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -16.80 -10.14 -3.380 0.17314E+05 -8.441 3 CH4,gas 4.54 1.13 -3.41 -0.853 0.58265E+04 -1.713 4 H2,gas 8.00 4.48 -3.52 -2.010 0.60048E+04 -1.818 5 H2S,gas -6.23 -14.77 -8.54 -4.272 0.14588E+05 -6.844 6 S2,gas -7.34 -38.51 -31.18 -4.797 0.53235E+05 -29.479 7 CO,gas 3.21 -12.32 -15.53 -4.779 0.26521E+05 -13.834 8 SO3,gas 17.12 -32.71 -49.83 -12.457 0.85078E+05 -48.128 9 SO2,gas 0.83 -28.22 -29.05 -7.748 0.49610E+05 -27.356 10 HCl,gas 5.19 -14.04 -19.23 -9.616 0.32838E+05 -17.533 11 acmite 7.71 6.53 -1.18 -0.123 0.20178E+04 15 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 19 spessartine 24.46 19.71 -4.74 -0.237 0.80994E+04 20 analcite 3.32 2.77 -0.55 -0.061 0.93613E+03 26 annite 20.12 17.72 -2.40 -0.134 0.41063E+04 27 phlogopite 27.06 25.40 -1.67 -0.093 0.28485E+04 29 anorthite 12.71 8.27 -4.45 -0.342 0.75897E+04 35 aragonite 0.97 -3.70 -4.67 -1.555 0.79657E+04 36 brucite 12.57 9.29 -3.27 -0.655 0.55908E+04 37 calcite 0.81 -3.70 -4.51 -1.503 0.77014E+04 38 carnegieite-low 9.02 5.93 -3.09 -0.442 0.52799E+04 39 carnegieite-high 10.09 5.93 -4.16 -0.595 0.71069E+04 40 carpholite-Mg 8.58 4.46 -4.12 -0.275 0.70423E+04 41 carpholite-Fe 6.71 1.90 -4.81 -0.321 0.82202E+04 42 celadonite 5.34 3.65 -1.69 -0.099 0.28878E+04 43 celadonite-Fe 3.88 1.09 -2.79 -0.164 0.47561E+04 44 chrysotile 23.89 21.57 -2.32 -0.194 0.39691E+04 49 chlorite-Al-free 47.17 43.14 -4.04 -0.168 0.68933E+04 51 chloritoid-Fe 9.17 5.06 -4.12 -0.275 0.70309E+04 52 chloritoid-Mn 11.40 7.56 -3.84 -0.256 0.65639E+04 54 coesite -2.38 -3.16 -0.78 -0.260 0.13342E+04 61 cristobalite -2.56 -3.16 -0.60 -0.199 0.10196E+04 63 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71234E+04 65 diaspore 2.87 0.74 -2.13 -0.356 0.36446E+04 66 diamond -3.10 -7.83 -4.73 -1.352 0.80801E+04 71 enstatite 17.26 12.27 -4.99 -0.499 0.85225E+04 73 clinoenstatite 17.17 12.27 -4.89 -0.489 0.83541E+04 75 epidote 24.67 22.70 -1.97 -0.095 0.33580E+04 76 clinozoisite 22.81 18.95 -3.86 -0.175 0.65859E+04 77 epidote-Fe 29.84 26.46 -3.38 -0.176 0.57768E+04 78 fayalite 14.05 10.31 -3.73 -0.533 0.63743E+04 79 ferrosilite 11.15 7.16 -3.99 -0.399 0.68203E+04 83 gibbsite 4.08 0.74 -3.34 -0.477 0.57032E+04 84 glaucophane 22.97 20.80 -2.17 -0.059 0.37132E+04 85 glaucophane-Fe 17.28 13.12 -4.15 -0.112 0.70920E+04 86 graphite -3.55 -7.83 -4.29 -1.225 0.73224E+04 87 greenalite 16.14 13.89 -2.25 -0.187 0.38409E+04 90 hematite 12.57 8.99 -3.58 -0.434 0.61113E+04 91 heulandite -5.83 -7.52 -1.69 -0.077 0.28938E+04 95 jadeite 4.22 2.77 -1.44 -0.144 0.24616E+04 97 kalsilite 7.58 3.83 -3.76 -0.536 0.64123E+04 98 kaolinite -1.33 -4.84 -3.50 -0.319 0.59827E+04 101 laumontite 2.88 1.95 -0.93 -0.062 0.15932E+04 102 lawsonite 9.62 8.27 -1.35 -0.090 0.23064E+04 103 leucite 4.12 0.67 -3.45 -0.345 0.58872E+04 105 lizardite 23.24 21.57 -1.68 -0.140 0.28617E+04 107 magnetite 20.09 15.72 -4.37 -0.356 0.74537E+04 108 minnesotaite 10.39 7.58 -2.81 -0.165 0.48031E+04 112 manganosite 14.06 9.24 -4.82 -1.206 0.82337E+04 120 muscovite 2.58 -1.01 -3.59 -0.211 0.61308E+04 121 paragonite 4.24 1.09 -3.14 -0.185 0.53699E+04 122 nepheline 8.34 5.93 -2.41 -0.344 0.41122E+04 128 periclase-Fe 11.63 6.74 -4.89 -1.223 0.83522E+04 134 phlogopite-Na 29.65 27.50 -2.15 -0.119 0.36674E+04 136 prehnite 19.37 18.21 -1.16 -0.068 0.19843E+04 137 prehnite-Fe 22.50 21.96 -0.53 -0.032 0.91144E+03 138 pumpellyite-Fe 46.27 43.89 -2.38 -0.053 0.40566E+04 139 pumpellyite-Mg 48.99 46.45 -2.54 -0.056 0.43404E+04 143 pyrrhotite -4.26 -8.04 -3.78 -1.259 0.64514E+04 144 pyrrhotiteFe0.875 -6.02 -9.44 -3.42 -1.258 0.58387E+04 145 pyroxmangite 7.40 6.08 -1.32 -0.264 0.22542E+04 146 pyrophyllite -6.18 -11.15 -4.98 -0.311 0.84959E+04 147 quartz -2.99 -3.16 -0.17 -0.056 0.28692E+03 152 rhodonite 7.45 6.08 -1.37 -0.273 0.23344E+04 153 sanidine -1.28 -2.49 -1.21 -0.093 0.20677E+04 165 stilpnomelane-Mg 27.44 25.81 -1.63 -0.049 0.27799E+04 171 talc 16.49 15.25 -1.24 -0.073 0.21141E+04 174 tephroite 18.09 15.31 -2.77 -0.396 0.47320E+04 178 tridymite -2.63 -3.16 -0.53 -0.177 0.90689E+03 179 tremolite 47.87 47.42 -0.45 -0.012 0.77498E+03 180 ferroactinolite 38.45 34.62 -3.83 -0.104 0.65453E+04 181 troilite-low -4.41 -8.04 -3.63 -1.209 0.61942E+04 183 vesuvianite 223.47 218.82 -4.65 -0.035 0.79397E+04 187 wairakite 3.95 1.95 -2.00 -0.118 0.34151E+04 188 walstromite 11.51 9.94 -1.56 -0.313 0.26719E+04 189 wollastonite 10.46 9.94 -0.52 -0.103 0.88229E+03 190 pseudo-wollastonite 11.00 9.94 -1.06 -0.211 0.18021E+04 191 zoisite 22.85 18.95 -3.90 -0.177 0.66600E+04 192 akaganeite 7.75 4.49 -3.26 -0.705 0.55682E+04 199 chalcedony -2.80 -3.16 -0.36 -0.118 0.60621E+03 201 montmorillonite-Ca -2.29 -6.17 -3.88 -0.240 0.66179E+04 202 montmorillonite-K -2.24 -6.27 -4.03 -0.247 0.68815E+04 203 montmorillonite-Mg -2.48 -6.79 -4.31 -0.267 0.73676E+04 204 montmorillonite-Na -2.04 -5.57 -3.54 -0.216 0.60364E+04 205 nontronite-Ca 3.21 -0.20 -3.41 -0.221 0.58219E+04 206 nontronite-H 2.53 -2.36 -4.89 -0.328 0.83490E+04 207 nontronite-K 3.34 -0.30 -3.64 -0.233 0.62088E+04 208 nontronite-Mg 3.07 -0.82 -3.90 -0.253 0.66558E+04 209 nontronite-Na 3.52 0.40 -3.12 -0.200 0.53296E+04 224 tobermorite 9.82 7.76 -2.07 -0.564 0.35287E+04 230 alabandite -0.98 -5.54 -4.56 -1.520 0.77858E+04 233 boehmite 4.41 0.74 -3.67 -0.611 0.62616E+04 235 ferrous-oxide 9.81 6.74 -3.08 -0.769 0.52532E+04 240 silica-amorphous -2.09 -3.16 -1.07 -0.355 0.18204E+04 242 an20ab80 2.02 1.35 -0.67 -0.052 0.11471E+04 243 an25ab75 2.65 1.78 -0.87 -0.067 0.14808E+04 244 an30ab70 3.28 2.21 -1.07 -0.082 0.18242E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 20.0000000 g Current total amount of reactant added: 599.9990000 g New total amount of reactant added: 619.9990000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.1586E-10 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 11 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 619.9990000 Water: Moles liquid = 0.5197E+02 kg liquid = 0.9362E+00 Moles total = 0.4774E+02 kg total = 0.8600E+00 Activity = 1.0000 Stoichiometric ionic strength = .1132498E-01 Osmotic coef. = 0.9694 True ionic strength = .2001350E-01 Chg. balance for total moles = -.1586E-10 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.88272E-10 -10.0542 0.74172E-10 -10.1298 0.84026E+00 -0.0756 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.14670E-03 -3.8336 0.12253E-03 -3.9118 0.83521E+00 -0.0782 4 SO4-- 0.69094E-12 -12.1606 0.35883E-12 -12.4451 0.51934E+00 -0.2845 5 HCO3- 0.25570E-06 -6.5923 0.21388E-06 -6.6698 0.83643E+00 -0.0776 6 HS- 0.27237E-04 -4.5648 0.22752E-04 -4.6430 0.83533E+00 -0.0781 7 Al+++ 0.96859E-29 -29.0139 0.22381E-29 -29.6501 0.23107E+00 -0.6363 8 H4SiO4 0.69588E-03 -3.1575 0.69588E-03 -3.1575 0.10000E+01 0.0000 9 Ca++ 0.13493E-06 -6.8699 0.69562E-07 -7.1576 0.51553E+00 -0.2877 10 Mg++ 0.21110E-10 -10.6755 0.10833E-10 -10.9653 0.51317E+00 -0.2897 11 Fe++ 0.58175E-13 -13.2353 0.29887E-13 -13.5245 0.51373E+00 -0.2893 12 K+ 0.15648E-03 -3.8056 0.13091E-03 -3.8830 0.83663E+00 -0.0775 13 Na+ 0.19856E-01 -1.7021 0.16581E-01 -1.7804 0.83506E+00 -0.0783 14 Mn++ 0.18431E-10 -10.7345 0.94764E-11 -11.0234 0.51416E+00 -0.2889 15 HPO4-- 0.45327E-07 -7.3436 0.23543E-07 -7.6281 0.51941E+00 -0.2845 16 HSiO3- 0.10489E-01 -1.9793 0.87603E-02 -2.0575 0.83521E+00 -0.0782 17 Ca(HSiO3)+ 0.16584E-07 -7.7803 0.13878E-07 -7.8577 0.83681E+00 -0.0774 18 Mg(HSiO3)+ 0.32142E-11 -11.4929 0.26897E-11 -11.5703 0.83681E+00 -0.0774 19 NaHSiO3,aq 0.23493E-02 -2.6291 0.23493E-02 -2.6291 0.10000E+01 0.0000 20 AlO+ 0.66138E-16 -16.1795 0.55345E-16 -16.2569 0.83681E+00 -0.0774 22 HAlO2,aq 0.14860E-09 -9.8280 0.14860E-09 -9.8280 0.10000E+01 0.0000 23 AlO2- 0.53194E-05 -5.2741 0.44348E-05 -5.3531 0.83370E+00 -0.0790 24 CH4,aq 0.13219E-04 -4.8788 0.13173E-04 -4.8803 0.99655E+00 -0.0015 25 C2H6,aq 0.25692E-14 -14.5902 0.25603E-14 -14.5917 0.99655E+00 -0.0015 29 CO,aq 0.98662E-17 -17.0058 0.98662E-17 -17.0058 0.10000E+01 0.0000 30 CO2,aq 0.34014E-10 -10.4683 0.33897E-10 -10.4698 0.99655E+00 -0.0015 31 CO3-2 0.48601E-06 -6.3134 0.25187E-06 -6.5988 0.51824E+00 -0.2855 32 CaCO3,aq 0.21969E-09 -9.6582 0.21969E-09 -9.6582 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.45383E-12 -12.3431 0.37977E-12 -12.4205 0.83681E+00 -0.0774 34 CaCl+ 0.16483E-10 -10.7830 0.13793E-10 -10.8603 0.83681E+00 -0.0774 35 CaCl2,aq 0.40152E-15 -15.3963 0.40152E-15 -15.3963 0.10000E+01 0.0000 36 CaOH+ 0.79875E-07 -7.0976 0.66840E-07 -7.1750 0.83681E+00 -0.0774 37 CaSO4,aq 0.79263E-17 -17.1009 0.79263E-17 -17.1009 0.10000E+01 0.0000 38 HCl,aq 0.16654E-14 -14.7785 0.16654E-14 -14.7785 0.10000E+01 0.0000 43 FeCl+ 0.69266E-17 -17.1595 0.57963E-17 -17.2369 0.83681E+00 -0.0774 46 FeO,aq 0.21114E-09 -9.6754 0.21114E-09 -9.6754 0.10000E+01 0.0000 47 FeOH+ 0.15674E-10 -10.8048 0.13116E-10 -10.8822 0.83681E+00 -0.0774 48 HFeO2- 0.35661E-07 -7.4478 0.29785E-07 -7.5260 0.83521E+00 -0.0782 49 FeO+ 0.10983E-16 -16.9593 0.91908E-17 -17.0366 0.83681E+00 -0.0774 51 FeO2- 0.40929E-09 -9.3880 0.34184E-09 -9.4662 0.83521E+00 -0.0782 52 HFeO2,aq 0.32248E-11 -11.4915 0.32248E-11 -11.4915 0.10000E+01 0.0000 53 H2,aq 0.11627E-04 -4.9345 0.11587E-04 -4.9360 0.99655E+00 -0.0015 54 KCl,aq 0.29072E-09 -9.5365 0.29072E-09 -9.5365 0.10000E+01 0.0000 56 KOH,aq 0.75375E-06 -6.1228 0.75375E-06 -6.1228 0.10000E+01 0.0000 57 KSO4- 0.87278E-15 -15.0591 0.72895E-15 -15.1373 0.83521E+00 -0.0782 58 MgCO3,aq 0.85754E-14 -14.0667 0.85754E-14 -14.0667 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.72216E-16 -16.1414 0.60432E-16 -16.2187 0.83681E+00 -0.0774 60 MgCl+ 0.23265E-14 -14.6333 0.19468E-14 -14.7107 0.83681E+00 -0.0774 61 MgOH+ 0.68830E-10 -10.1622 0.57598E-10 -10.2396 0.83681E+00 -0.0774 63 MnO,aq 0.17839E-08 -8.7486 0.17839E-08 -8.7486 0.10000E+01 0.0000 64 MnOH+ 0.46168E-09 -9.3357 0.38634E-09 -9.4130 0.83681E+00 -0.0774 65 MnO2-2 0.20765E-10 -10.6827 0.10761E-10 -10.9681 0.51824E+00 -0.2855 66 HMnO2- 0.20937E-09 -9.6791 0.17486E-09 -9.7573 0.83521E+00 -0.0782 69 MnCl+ 0.85444E-14 -14.0683 0.71501E-14 -14.1457 0.83681E+00 -0.0774 71 NaCl,aq 0.67329E-06 -6.1718 0.67329E-06 -6.1718 0.10000E+01 0.0000 72 NaOH,aq 0.96047E-04 -4.0175 0.96047E-04 -4.0175 0.10000E+01 0.0000 74 OH- 0.93435E-02 -2.0295 0.77897E-02 -2.1085 0.83370E+00 -0.0790 79 HPO3-2 0.16404E-14 -14.7851 0.85010E-15 -15.0705 0.51824E+00 -0.2855 81 H2PO3- 0.15139E-18 -18.8199 0.12644E-18 -18.8981 0.83521E+00 -0.0782 82 H3PO4,aq 0.90587E-18 -18.0429 0.90587E-18 -18.0429 0.10000E+01 0.0000 83 H2PO4- 0.38533E-10 -10.4142 0.32214E-10 -10.4920 0.83600E+00 -0.0778 84 PO4-3 0.10671E-08 -8.9718 0.25898E-09 -9.5867 0.24268E+00 -0.6150 88 HP2O7-3 0.94705E-18 -18.0236 0.21905E-18 -18.6595 0.23130E+00 -0.6358 89 P2O7-4 0.91476E-17 -17.0387 0.70553E-18 -18.1515 0.77127E-01 -1.1128 90 H2S,aq 0.52337E-08 -8.2812 0.52156E-08 -8.2827 0.99655E+00 -0.0015 91 S2-2 0.19103E-14 -14.7189 0.98997E-15 -15.0044 0.51824E+00 -0.2855 97 SO3-2 0.10277E-17 -17.9881 0.54029E-18 -18.2674 0.52573E+00 -0.2792 99 HSO4- 0.30622E-19 -19.5140 0.25650E-19 -19.5909 0.83763E+00 -0.0769 Charge balance for all species = -.1694E-10 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.8827180E-10 -.2230319E-01 -.2244121E+02 0.0000 2 H2O 0.1000000E+01 0.5550489E+02 0.9981998E+06 0.0000 3 Cl- 0.1467028E-03 0.1473764E-03 0.5215858E+01 6.2180 4 SO4-- 0.6909424E-12 -.1612533E-04 -.1546333E+01 7.8144 5 HCO3- 0.2557028E-06 0.1396065E-04 0.8503600E+00 3.4599 6 HS- 0.2723724E-04 0.4336780E-04 0.1431768E+01 5.4868 7 Al+++ 0.9685947E-29 0.5319551E-05 0.1432801E+00 0.7392 8 H4SiO4 0.6958757E-03 0.1353394E-01 0.1298560E+04 -3.1575 9 Ca++ 0.1349328E-06 0.2316284E-06 0.9267072E-02 13.1019 10 Mg++ 0.2110956E-10 0.9316486E-10 0.2261089E-05 9.2943 11 Fe++ 0.5817548E-13 0.3630038E-07 0.2023745E-02 6.7350 12 K+ 0.1564759E-03 0.1572299E-03 0.6137322E+01 6.2467 13 Na+ 0.1985599E-01 0.2230200E-01 0.5118277E+03 8.3494 14 Mn++ 0.1843080E-10 0.2494101E-08 0.1367828E-03 9.2362 15 HPO4-- 0.4532695E-07 0.4643263E-07 0.4448814E-02 12.6314 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.1026625E+02 -.2088030E-01 -.1024537E+02 0.0000000E+00 2 H2O 0.4773631E+02 0.5196381E+02 -.4227506E+01 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.1720779E-01 -.1509657E-04 0.1722289E-01 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.1718229E-01 0.4060104E-04 -.1722289E-01 0.0000000E+00 7 Al+++ 0.2021657E+01 0.4980177E-05 0.2021652E+01 0.0000000E+00 8 H4SiO4 0.6455915E+01 0.1267051E-01 0.6443245E+01 0.0000000E+00 9 Ca++ 0.7131018E+00 0.2168510E-06 0.7131015E+00 0.0000000E+00 10 Mg++ 0.4920627E+00 0.8722117E-10 0.4920627E+00 0.0000000E+00 11 Fe++ 0.4420646E+00 0.3398451E-07 0.4420646E+00 0.0000000E+00 12 K+ 0.1316346E+00 0.1471990E-03 0.1314874E+00 0.0000000E+00 13 Na+ 0.7784099E+00 0.2087919E-01 0.7575307E+00 0.0000000E+00 14 Mn++ 0.1074991E-01 0.2334983E-08 0.1074991E-01 0.0000000E+00 15 HPO4-- 0.3668892E-02 0.4347035E-07 0.3668848E-02 0.0000000E+00 Chg. balance for solid moles: 0.1928E-14 Mass of aqueous solution: 0.937832E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 619.9990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 0.7568 -0.121 198.4 2.298 29.31 76.18 andradite 0.6889E-01 -1.162 35.01 1.544 5.170 9.096 grossular 0.1669E-01 -1.778 7.518 0.876 1.110 2.092 apatite-OH 0.1223E-02 -2.913 0.6143 -0.212 0.9072E-01 0.1952 clinochlore 0.8920E-01 -1.050 49.58 1.695 7.321 18.86 daphnite 0.2582E-01 -1.588 18.42 1.265 2.720 5.582 chlorite-Mn 0.2150E-02 -2.668 1.524 0.183 0.2251 0.4857 diopside 0.2446E-01 -1.611 5.298 0.724 0.7823 1.619 hedenbergite 0.6343E-02 -2.198 1.574 0.197 0.2324 0.4311 microcline 0.1153 -0.938 32.11 1.507 4.741 12.54 stilbite 0.4075 -0.390 287.2 2.458 42.41 133.9 stilpnomelane-Fe 0.3228E-01 -1.491 34.80 1.542 5.138 12.02 tr.625ac.25prg.125 0.5964E-02 -2.224 5.097 0.707 0.7528 1.641 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8050E+00 0.8050E+00 1.0000 -0.094 grossular 0.1950E+00 0.1950E+00 1.0000 -0.710 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.7613E+00 0.7613E+00 1.0000 -0.118 daphnite 0.2204E+00 0.2204E+00 1.0000 -0.657 chlorite-Mn 0.1835E-01 0.1835E-01 1.0000 -1.736 diopside 0.7941E+00 0.7941E+00 1.0000 -0.100 hedenbergite 0.2059E+00 0.2059E+00 1.0000 -0.686 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 tr.625ac.25prg.125 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 677.158807 g Volume = 274.683649 cm3 Porosity: -10.3149% V(tot) - V(min): -.25684E+02 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 619.9990000 g log = 2.7924 Original solution: 1000.0103000 g Original solution / Rock added: 1.61 (Water/Rock Ratio), log = 0.2076 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0551 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9674E+00 0.9855 0.1006E+01 0.1021E+01 CO2,gas 0.3413E-08 1.0069 0.3627E-08 0.3602E-08 CH4,gas 0.1815E-01 1.0125 0.1939E-01 0.1915E-01 H2,gas 0.1441E-01 1.0006 0.1521E-01 0.1520E-01 H2S,gas 0.1364E-06 0.9959 0.1434E-06 0.1440E-06 S2,gas 0.3160E-29 1.0000 0.3334E-29 0.3334E-29 CO,gas 0.1393E-13 1.0000 0.1470E-13 0.1470E-13 SO3,gas 0.7074E-48 1.0000 0.7464E-48 0.7464E-48 SO2,gas 0.4187E-27 1.0000 0.4417E-27 0.4417E-27 HCl,gas 0.2785E-17 1.0000 0.2939E-17 0.2939E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 16 albite -0.38 -0.38 0.00 0.000 -0.94784E-12 22 andradite 39.01 39.01 0.00 0.000 0.12132E-10 23 grossular 32.73 32.73 0.00 0.000 -0.12132E-10 32 apatite-OH -18.15 -18.15 0.00 0.000 0.60662E-11 46 clinochlore 39.07 39.07 0.00 0.000 0.12132E-10 47 daphnite 28.97 28.97 0.00 0.000 0.24265E-10 48 chlorite-Mn 46.87 46.87 0.00 0.000 0.12132E-10 67 diopside 16.18 16.18 0.00 0.000 0.60662E-11 68 hedenbergite 14.21 14.21 0.00 0.000 0.90992E-11 116 microcline -2.49 -2.49 0.00 0.000 0.15165E-11 163 stilbite -7.52 -7.52 0.00 0.000 0.39430E-10 164 stilpnomelane-Fe 13.02 13.02 0.00 0.000 0.21232E-10 245 tr.625ac.25prg.125 45.16 45.16 0.00 0.000 0.24265E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -16.80 -10.14 -3.380 0.17313E+05 -8.440 3 CH4,gas 4.54 1.13 -3.41 -0.853 0.58249E+04 -1.712 4 H2,gas 8.00 4.48 -3.52 -2.010 0.60048E+04 -1.818 5 H2S,gas -6.23 -14.77 -8.54 -4.271 0.14586E+05 -6.844 6 S2,gas -7.34 -38.51 -31.18 -4.796 0.53232E+05 -29.477 7 CO,gas 3.21 -12.32 -15.53 -4.779 0.26520E+05 -13.833 8 SO3,gas 17.12 -32.70 -49.83 -12.456 0.85077E+05 -48.127 9 SO2,gas 0.83 -28.22 -29.05 -7.748 0.49609E+05 -27.355 10 HCl,gas 5.19 -14.04 -19.23 -9.615 0.32836E+05 -17.532 11 acmite 7.71 6.53 -1.18 -0.123 0.20178E+04 15 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 19 spessartine 24.46 19.71 -4.74 -0.237 0.80984E+04 20 analcite 3.32 2.77 -0.55 -0.061 0.93614E+03 26 annite 20.12 17.72 -2.40 -0.134 0.41063E+04 27 phlogopite 27.06 25.40 -1.67 -0.093 0.28486E+04 29 anorthite 12.71 8.27 -4.45 -0.342 0.75898E+04 35 aragonite 0.97 -3.70 -4.66 -1.555 0.79640E+04 36 brucite 12.57 9.29 -3.27 -0.655 0.55908E+04 37 calcite 0.81 -3.70 -4.51 -1.503 0.76998E+04 38 carnegieite-low 9.02 5.93 -3.09 -0.442 0.52799E+04 39 carnegieite-high 10.09 5.93 -4.16 -0.595 0.71069E+04 40 carpholite-Mg 8.58 4.46 -4.12 -0.275 0.70424E+04 41 carpholite-Fe 6.71 1.90 -4.81 -0.321 0.82202E+04 42 celadonite 5.34 3.65 -1.69 -0.099 0.28878E+04 43 celadonite-Fe 3.88 1.09 -2.79 -0.164 0.47561E+04 44 chrysotile 23.89 21.57 -2.32 -0.194 0.39691E+04 49 chlorite-Al-free 47.17 43.14 -4.04 -0.168 0.68933E+04 51 chloritoid-Fe 9.17 5.06 -4.12 -0.275 0.70310E+04 52 chloritoid-Mn 11.40 7.56 -3.84 -0.256 0.65636E+04 54 coesite -2.38 -3.16 -0.78 -0.260 0.13342E+04 61 cristobalite -2.56 -3.16 -0.60 -0.199 0.10196E+04 63 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71234E+04 65 diaspore 2.87 0.74 -2.13 -0.356 0.36447E+04 66 diamond -3.10 -7.83 -4.73 -1.352 0.80785E+04 71 enstatite 17.26 12.27 -4.99 -0.499 0.85225E+04 73 clinoenstatite 17.17 12.27 -4.89 -0.489 0.83541E+04 75 epidote 24.67 22.70 -1.97 -0.095 0.33581E+04 76 clinozoisite 22.81 18.95 -3.86 -0.175 0.65860E+04 77 epidote-Fe 29.84 26.46 -3.38 -0.176 0.57768E+04 78 fayalite 14.05 10.31 -3.73 -0.533 0.63743E+04 79 ferrosilite 11.15 7.16 -3.99 -0.399 0.68203E+04 83 gibbsite 4.08 0.74 -3.34 -0.477 0.57032E+04 84 glaucophane 22.97 20.80 -2.17 -0.059 0.37132E+04 85 glaucophane-Fe 17.28 13.12 -4.15 -0.112 0.70920E+04 86 graphite -3.55 -7.83 -4.29 -1.225 0.73207E+04 87 greenalite 16.14 13.89 -2.25 -0.187 0.38408E+04 90 hematite 12.57 8.99 -3.58 -0.434 0.61113E+04 91 heulandite -5.83 -7.52 -1.69 -0.077 0.28938E+04 95 jadeite 4.22 2.77 -1.44 -0.144 0.24616E+04 97 kalsilite 7.58 3.83 -3.76 -0.536 0.64124E+04 98 kaolinite -1.33 -4.84 -3.50 -0.319 0.59827E+04 101 laumontite 2.88 1.95 -0.93 -0.062 0.15932E+04 102 lawsonite 9.62 8.27 -1.35 -0.090 0.23064E+04 103 leucite 4.12 0.67 -3.45 -0.345 0.58872E+04 105 lizardite 23.24 21.57 -1.68 -0.140 0.28617E+04 107 magnetite 20.09 15.72 -4.37 -0.356 0.74537E+04 108 minnesotaite 10.39 7.58 -2.81 -0.165 0.48031E+04 112 manganosite 14.06 9.24 -4.82 -1.205 0.82333E+04 120 muscovite 2.58 -1.01 -3.59 -0.211 0.61308E+04 121 paragonite 4.24 1.09 -3.14 -0.185 0.53699E+04 122 nepheline 8.34 5.93 -2.41 -0.344 0.41123E+04 128 periclase-Fe 11.63 6.74 -4.89 -1.223 0.83522E+04 134 phlogopite-Na 29.65 27.50 -2.15 -0.119 0.36674E+04 136 prehnite 19.37 18.21 -1.16 -0.068 0.19844E+04 137 prehnite-Fe 22.50 21.96 -0.53 -0.032 0.91144E+03 138 pumpellyite-Fe 46.27 43.89 -2.38 -0.053 0.40567E+04 139 pumpellyite-Mg 48.99 46.45 -2.54 -0.056 0.43404E+04 143 pyrrhotite -4.26 -8.04 -3.78 -1.259 0.64498E+04 144 pyrrhotiteFe0.875 -6.02 -9.44 -3.42 -1.257 0.58371E+04 145 pyroxmangite 7.40 6.08 -1.32 -0.264 0.22538E+04 146 pyrophyllite -6.18 -11.15 -4.98 -0.311 0.84959E+04 147 quartz -2.99 -3.16 -0.17 -0.056 0.28691E+03 152 rhodonite 7.45 6.08 -1.37 -0.273 0.23341E+04 153 sanidine -1.28 -2.49 -1.21 -0.093 0.20677E+04 165 stilpnomelane-Mg 27.44 25.81 -1.63 -0.049 0.27800E+04 171 talc 16.49 15.25 -1.24 -0.073 0.21141E+04 174 tephroite 18.09 15.31 -2.77 -0.396 0.47313E+04 178 tridymite -2.63 -3.16 -0.53 -0.177 0.90689E+03 179 tremolite 47.87 47.42 -0.45 -0.012 0.77498E+03 180 ferroactinolite 38.45 34.62 -3.83 -0.104 0.65453E+04 181 troilite-low -4.41 -8.04 -3.63 -1.209 0.61926E+04 183 vesuvianite 223.47 218.82 -4.65 -0.035 0.79398E+04 187 wairakite 3.95 1.95 -2.00 -0.118 0.34151E+04 188 walstromite 11.51 9.94 -1.56 -0.313 0.26719E+04 189 wollastonite 10.46 9.94 -0.52 -0.103 0.88229E+03 190 pseudo-wollastonite 11.00 9.94 -1.06 -0.211 0.18021E+04 191 zoisite 22.85 18.95 -3.90 -0.177 0.66600E+04 192 akaganeite 7.75 4.49 -3.26 -0.705 0.55682E+04 199 chalcedony -2.80 -3.16 -0.36 -0.118 0.60621E+03 201 montmorillonite-Ca -2.29 -6.17 -3.88 -0.240 0.66179E+04 202 montmorillonite-K -2.24 -6.27 -4.03 -0.247 0.68815E+04 203 montmorillonite-Mg -2.48 -6.79 -4.31 -0.267 0.73676E+04 204 montmorillonite-Na -2.04 -5.57 -3.54 -0.216 0.60364E+04 205 nontronite-Ca 3.21 -0.20 -3.41 -0.221 0.58219E+04 206 nontronite-H 2.53 -2.36 -4.89 -0.328 0.83489E+04 207 nontronite-K 3.34 -0.30 -3.64 -0.233 0.62088E+04 208 nontronite-Mg 3.07 -0.82 -3.90 -0.253 0.66558E+04 209 nontronite-Na 3.52 0.40 -3.12 -0.200 0.53296E+04 224 tobermorite 9.82 7.76 -2.07 -0.564 0.35287E+04 230 alabandite -0.98 -5.54 -4.56 -1.520 0.77839E+04 233 boehmite 4.41 0.74 -3.67 -0.611 0.62616E+04 235 ferrous-oxide 9.81 6.74 -3.08 -0.769 0.52532E+04 240 silica-amorphous -2.09 -3.16 -1.07 -0.355 0.18204E+04 242 an20ab80 2.02 1.35 -0.67 -0.052 0.11471E+04 243 an25ab75 2.65 1.78 -0.87 -0.067 0.14809E+04 244 an30ab70 3.28 2.21 -1.07 -0.082 0.18242E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 20.0000000 g Current total amount of reactant added: 619.9990000 g New total amount of reactant added: 639.9990000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.1586E-10 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 11 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 639.9990000 Water: Moles liquid = 0.5186E+02 kg liquid = 0.9342E+00 Moles total = 0.4749E+02 kg total = 0.8555E+00 Activity = 1.0000 Stoichiometric ionic strength = .1132526E-01 Osmotic coef. = 0.9694 True ionic strength = .2001373E-01 Chg. balance for total moles = -.1586E-10 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.88273E-10 -10.0542 0.74172E-10 -10.1298 0.84026E+00 -0.0756 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.14702E-03 -3.8326 0.12279E-03 -3.9108 0.83521E+00 -0.0782 4 SO4-- 0.69246E-12 -12.1596 0.35962E-12 -12.4442 0.51934E+00 -0.2845 5 HCO3- 0.25626E-06 -6.5913 0.21435E-06 -6.6689 0.83643E+00 -0.0776 6 HS- 0.27296E-04 -4.5639 0.22801E-04 -4.6420 0.83533E+00 -0.0781 7 Al+++ 0.96862E-29 -29.0138 0.22381E-29 -29.6501 0.23106E+00 -0.6363 8 H4SiO4 0.69588E-03 -3.1575 0.69588E-03 -3.1575 0.10000E+01 0.0000 9 Ca++ 0.13494E-06 -6.8699 0.69563E-07 -7.1576 0.51553E+00 -0.2877 10 Mg++ 0.21110E-10 -10.6755 0.10833E-10 -10.9653 0.51317E+00 -0.2897 11 Fe++ 0.58177E-13 -13.2353 0.29887E-13 -13.5245 0.51373E+00 -0.2893 12 K+ 0.15648E-03 -3.8055 0.13091E-03 -3.8830 0.83663E+00 -0.0775 13 Na+ 0.19856E-01 -1.7021 0.16581E-01 -1.7804 0.83506E+00 -0.0783 14 Mn++ 0.18439E-10 -10.7343 0.94807E-11 -11.0232 0.51416E+00 -0.2889 15 HPO4-- 0.45327E-07 -7.3436 0.23543E-07 -7.6281 0.51941E+00 -0.2845 16 HSiO3- 0.10489E-01 -1.9793 0.87603E-02 -2.0575 0.83521E+00 -0.0782 17 Ca(HSiO3)+ 0.16585E-07 -7.7803 0.13878E-07 -7.8577 0.83681E+00 -0.0774 18 Mg(HSiO3)+ 0.32142E-11 -11.4929 0.26897E-11 -11.5703 0.83681E+00 -0.0774 19 NaHSiO3,aq 0.23493E-02 -2.6291 0.23493E-02 -2.6291 0.10000E+01 0.0000 20 AlO+ 0.66138E-16 -16.1796 0.55345E-16 -16.2569 0.83681E+00 -0.0774 22 HAlO2,aq 0.14860E-09 -9.8280 0.14860E-09 -9.8280 0.10000E+01 0.0000 23 AlO2- 0.53193E-05 -5.2741 0.44347E-05 -5.3531 0.83370E+00 -0.0790 24 CH4,aq 0.13247E-04 -4.8779 0.13201E-04 -4.8794 0.99655E+00 -0.0015 25 C2H6,aq 0.25803E-14 -14.5883 0.25714E-14 -14.5898 0.99655E+00 -0.0015 29 CO,aq 0.98878E-17 -17.0049 0.98878E-17 -17.0049 0.10000E+01 0.0000 30 CO2,aq 0.34089E-10 -10.4674 0.33971E-10 -10.4689 0.99655E+00 -0.0015 31 CO3-2 0.48707E-06 -6.3124 0.25242E-06 -6.5979 0.51824E+00 -0.2855 32 CaCO3,aq 0.22017E-09 -9.6572 0.22017E-09 -9.6572 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.45483E-12 -12.3422 0.38061E-12 -12.4195 0.83681E+00 -0.0774 34 CaCl+ 0.16519E-10 -10.7820 0.13823E-10 -10.8594 0.83681E+00 -0.0774 35 CaCl2,aq 0.40326E-15 -15.3944 0.40326E-15 -15.3944 0.10000E+01 0.0000 36 CaOH+ 0.79875E-07 -7.0976 0.66840E-07 -7.1750 0.83681E+00 -0.0774 37 CaSO4,aq 0.79438E-17 -17.1000 0.79438E-17 -17.1000 0.10000E+01 0.0000 38 HCl,aq 0.16690E-14 -14.7776 0.16690E-14 -14.7776 0.10000E+01 0.0000 43 FeCl+ 0.69416E-17 -17.1585 0.58088E-17 -17.2359 0.83681E+00 -0.0774 46 FeO,aq 0.21114E-09 -9.6754 0.21114E-09 -9.6754 0.10000E+01 0.0000 47 FeOH+ 0.15674E-10 -10.8048 0.13116E-10 -10.8822 0.83681E+00 -0.0774 48 HFeO2- 0.35661E-07 -7.4478 0.29784E-07 -7.5260 0.83521E+00 -0.0782 49 FeO+ 0.10983E-16 -16.9593 0.91909E-17 -17.0366 0.83681E+00 -0.0774 51 FeO2- 0.40929E-09 -9.3880 0.34184E-09 -9.4662 0.83521E+00 -0.0782 52 HFeO2,aq 0.32248E-11 -11.4915 0.32248E-11 -11.4915 0.10000E+01 0.0000 53 H2,aq 0.11627E-04 -4.9345 0.11586E-04 -4.9360 0.99655E+00 -0.0015 54 KCl,aq 0.29135E-09 -9.5356 0.29135E-09 -9.5356 0.10000E+01 0.0000 56 KOH,aq 0.75375E-06 -6.1228 0.75375E-06 -6.1228 0.10000E+01 0.0000 57 KSO4- 0.87470E-15 -15.0581 0.73056E-15 -15.1363 0.83521E+00 -0.0782 58 MgCO3,aq 0.85942E-14 -14.0658 0.85942E-14 -14.0658 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.72376E-16 -16.1404 0.60565E-16 -16.2178 0.83681E+00 -0.0774 60 MgCl+ 0.23315E-14 -14.6324 0.19511E-14 -14.7097 0.83681E+00 -0.0774 61 MgOH+ 0.68831E-10 -10.1622 0.57598E-10 -10.2396 0.83681E+00 -0.0774 63 MnO,aq 0.17846E-08 -8.7484 0.17846E-08 -8.7484 0.10000E+01 0.0000 64 MnOH+ 0.46189E-09 -9.3355 0.38651E-09 -9.4128 0.83681E+00 -0.0774 65 MnO2-2 0.20773E-10 -10.6825 0.10766E-10 -10.9680 0.51824E+00 -0.2855 66 HMnO2- 0.20946E-09 -9.6789 0.17494E-09 -9.7571 0.83521E+00 -0.0782 69 MnCl+ 0.85668E-14 -14.0672 0.71688E-14 -14.1446 0.83681E+00 -0.0774 71 NaCl,aq 0.67474E-06 -6.1709 0.67474E-06 -6.1709 0.10000E+01 0.0000 72 NaOH,aq 0.96047E-04 -4.0175 0.96047E-04 -4.0175 0.10000E+01 0.0000 74 OH- 0.93434E-02 -2.0295 0.77896E-02 -2.1085 0.83370E+00 -0.0790 79 HPO3-2 0.16403E-14 -14.7851 0.85008E-15 -15.0705 0.51824E+00 -0.2855 81 H2PO3- 0.15139E-18 -18.8199 0.12644E-18 -18.8981 0.83521E+00 -0.0782 82 H3PO4,aq 0.90588E-18 -18.0429 0.90588E-18 -18.0429 0.10000E+01 0.0000 83 H2PO4- 0.38533E-10 -10.4142 0.32214E-10 -10.4920 0.83600E+00 -0.0778 84 PO4-3 0.10671E-08 -8.9718 0.25897E-09 -9.5867 0.24268E+00 -0.6150 88 HP2O7-3 0.94704E-18 -18.0236 0.21905E-18 -18.6595 0.23129E+00 -0.6358 89 P2O7-4 0.91475E-17 -17.0387 0.70551E-18 -18.1515 0.77126E-01 -1.1128 90 H2S,aq 0.52450E-08 -8.2803 0.52269E-08 -8.2818 0.99655E+00 -0.0015 91 S2-2 0.19185E-14 -14.7170 0.99424E-15 -15.0025 0.51824E+00 -0.2855 97 SO3-2 0.10299E-17 -17.9872 0.54146E-18 -18.2664 0.52573E+00 -0.2792 99 HSO4- 0.30689E-19 -19.5130 0.25706E-19 -19.5900 0.83763E+00 -0.0770 Charge balance for all species = -.1698E-10 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.8827283E-10 -.2230305E-01 -.2244108E+02 0.0000 2 H2O 0.1000000E+01 0.5550489E+02 0.9981998E+06 0.0000 3 Cl- 0.1470182E-03 0.1476933E-03 0.5227072E+01 6.2189 4 SO4-- 0.6924561E-12 -.1615369E-04 -.1549053E+01 7.8154 5 HCO3- 0.2562622E-06 0.1399067E-04 0.8521883E+00 3.4609 6 HS- 0.2729580E-04 0.4345473E-04 0.1434638E+01 5.4877 7 Al+++ 0.9686178E-29 0.5319414E-05 0.1432764E+00 0.7392 8 H4SiO4 0.6958793E-03 0.1353390E-01 0.1298556E+04 -3.1575 9 Ca++ 0.1349355E-06 0.2316322E-06 0.9267225E-02 13.1019 10 Mg++ 0.2110996E-10 0.9316581E-10 0.2261112E-05 9.2943 11 Fe++ 0.5817680E-13 0.3629995E-07 0.2023721E-02 6.7350 12 K+ 0.1564777E-03 0.1572317E-03 0.6137392E+01 6.2467 13 Na+ 0.1985622E-01 0.2230225E-01 0.5118333E+03 8.3494 14 Mn++ 0.1843939E-10 0.2495205E-08 0.1368434E-03 9.2364 15 HPO4-- 0.4532651E-07 0.4643217E-07 0.4448770E-02 12.6314 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.1059742E+02 -.2083538E-01 -.1057658E+02 0.0000000E+00 2 H2O 0.4748560E+02 0.5185233E+02 -.4366731E+01 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.1776206E-01 -.1509068E-04 0.1777715E-01 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.1773655E-01 0.4059515E-04 -.1777715E-01 0.0000000E+00 7 Al+++ 0.2086871E+01 0.4969364E-05 0.2086866E+01 0.0000000E+00 8 H4SiO4 0.6664171E+01 0.1264329E-01 0.6651527E+01 0.0000000E+00 9 Ca++ 0.7361046E+00 0.2163894E-06 0.7361044E+00 0.0000000E+00 10 Mg++ 0.5079357E+00 0.8703493E-10 0.5079357E+00 0.0000000E+00 11 Fe++ 0.4563248E+00 0.3391119E-07 0.4563248E+00 0.0000000E+00 12 K+ 0.1358809E+00 0.1468849E-03 0.1357340E+00 0.0000000E+00 13 Na+ 0.8035147E+00 0.2083462E-01 0.7826801E+00 0.0000000E+00 14 Mn++ 0.1109668E-01 0.2331005E-08 0.1109668E-01 0.0000000E+00 15 HPO4-- 0.3787243E-02 0.4337666E-07 0.3787200E-02 0.0000000E+00 Chg. balance for solid moles: -.3045E-14 Mass of aqueous solution: 0.935820E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 639.9990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 0.7819 -0.107 205.0 2.312 29.33 78.71 andradite 0.7111E-01 -1.148 36.14 1.558 5.170 9.388 grossular 0.1723E-01 -1.764 7.760 0.890 1.110 2.159 apatite-OH 0.1262E-02 -2.899 0.6341 -0.198 0.9072E-01 0.2015 clinochlore 0.9203E-01 -1.036 51.15 1.709 7.318 19.46 daphnite 0.2664E-01 -1.574 19.01 1.279 2.719 5.760 chlorite-Mn 0.2219E-02 -2.654 1.573 0.197 0.2251 0.5014 diopside 0.2555E-01 -1.593 5.533 0.743 0.7916 1.691 hedenbergite 0.6625E-02 -2.179 1.644 0.216 0.2352 0.4502 microcline 0.1191 -0.924 33.14 1.520 4.741 12.95 stilbite 0.4203 -0.376 296.2 2.472 42.38 138.2 stilpnomelane-Fe 0.3332E-01 -1.477 35.92 1.555 5.139 12.41 tr.625ac.25prg.125 0.6130E-02 -2.213 5.240 0.719 0.7496 1.687 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8050E+00 0.8050E+00 1.0000 -0.094 grossular 0.1950E+00 0.1950E+00 1.0000 -0.710 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.7613E+00 0.7613E+00 1.0000 -0.118 daphnite 0.2204E+00 0.2204E+00 1.0000 -0.657 chlorite-Mn 0.1836E-01 0.1836E-01 1.0000 -1.736 diopside 0.7941E+00 0.7941E+00 1.0000 -0.100 hedenbergite 0.2059E+00 0.2059E+00 1.0000 -0.686 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 tr.625ac.25prg.125 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 699.008938 g Volume = 283.524261 cm3 Porosity: -10.3209% V(tot) - V(min): -.26525E+02 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 639.9990000 g log = 2.8062 Original solution: 1000.0103000 g Original solution / Rock added: 1.56 (Water/Rock Ratio), log = 0.1938 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0552 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9674E+00 0.9855 0.1006E+01 0.1021E+01 CO2,gas 0.3421E-08 1.0069 0.3635E-08 0.3610E-08 CH4,gas 0.1819E-01 1.0125 0.1943E-01 0.1919E-01 H2,gas 0.1441E-01 1.0006 0.1521E-01 0.1520E-01 H2S,gas 0.1367E-06 0.9959 0.1437E-06 0.1443E-06 S2,gas 0.3174E-29 1.0000 0.3349E-29 0.3349E-29 CO,gas 0.1396E-13 1.0000 0.1473E-13 0.1473E-13 SO3,gas 0.7089E-48 1.0000 0.7481E-48 0.7481E-48 SO2,gas 0.4196E-27 1.0000 0.4427E-27 0.4427E-27 HCl,gas 0.2791E-17 1.0000 0.2945E-17 0.2945E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 16 albite -0.38 -0.38 0.00 0.000 -0.94784E-12 22 andradite 39.01 39.01 0.00 0.000 0.00000E+00 23 grossular 32.73 32.73 0.00 0.000 -0.12132E-10 32 apatite-OH -18.15 -18.15 0.00 0.000 0.00000E+00 46 clinochlore 39.07 39.07 0.00 0.000 0.12132E-10 47 daphnite 28.97 28.97 0.00 0.000 0.48529E-10 48 chlorite-Mn 46.87 46.87 0.00 0.000 -0.12132E-10 67 diopside 16.18 16.18 0.00 0.000 -0.60662E-11 68 hedenbergite 14.21 14.21 0.00 0.000 -0.90992E-11 116 microcline -2.49 -2.49 0.00 0.000 -0.10616E-10 163 stilbite -7.52 -7.52 0.00 0.000 0.15165E-10 164 stilpnomelane-Fe 13.02 13.02 0.00 0.000 0.21232E-10 245 tr.625ac.25prg.125 45.16 45.16 0.00 0.000 -0.36397E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -16.80 -10.14 -3.380 0.17311E+05 -8.440 3 CH4,gas 4.54 1.13 -3.41 -0.853 0.58233E+04 -1.711 4 H2,gas 8.00 4.48 -3.52 -2.010 0.60048E+04 -1.818 5 H2S,gas -6.23 -14.77 -8.54 -4.271 0.14584E+05 -6.843 6 S2,gas -7.34 -38.51 -31.17 -4.796 0.53229E+05 -29.475 7 CO,gas 3.21 -12.32 -15.53 -4.779 0.26518E+05 -13.832 8 SO3,gas 17.12 -32.70 -49.83 -12.456 0.85075E+05 -48.126 9 SO2,gas 0.83 -28.22 -29.05 -7.747 0.49607E+05 -27.354 10 HCl,gas 5.19 -14.04 -19.23 -9.615 0.32835E+05 -17.531 11 acmite 7.71 6.53 -1.18 -0.123 0.20178E+04 15 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 19 spessartine 24.46 19.71 -4.74 -0.237 0.80974E+04 20 analcite 3.32 2.77 -0.55 -0.061 0.93614E+03 26 annite 20.12 17.72 -2.40 -0.134 0.41063E+04 27 phlogopite 27.06 25.40 -1.67 -0.093 0.28486E+04 29 anorthite 12.71 8.27 -4.45 -0.342 0.75898E+04 35 aragonite 0.97 -3.70 -4.66 -1.554 0.79624E+04 36 brucite 12.57 9.29 -3.27 -0.655 0.55908E+04 37 calcite 0.81 -3.70 -4.51 -1.503 0.76982E+04 38 carnegieite-low 9.02 5.93 -3.09 -0.442 0.52799E+04 39 carnegieite-high 10.09 5.93 -4.16 -0.595 0.71069E+04 40 carpholite-Mg 8.58 4.46 -4.12 -0.275 0.70424E+04 41 carpholite-Fe 6.71 1.90 -4.81 -0.321 0.82202E+04 42 celadonite 5.34 3.65 -1.69 -0.099 0.28878E+04 43 celadonite-Fe 3.88 1.09 -2.79 -0.164 0.47561E+04 44 chrysotile 23.89 21.57 -2.32 -0.194 0.39691E+04 49 chlorite-Al-free 47.17 43.14 -4.04 -0.168 0.68933E+04 51 chloritoid-Fe 9.17 5.06 -4.12 -0.275 0.70310E+04 52 chloritoid-Mn 11.40 7.56 -3.84 -0.256 0.65633E+04 54 coesite -2.38 -3.16 -0.78 -0.260 0.13342E+04 61 cristobalite -2.56 -3.16 -0.60 -0.199 0.10196E+04 63 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71234E+04 65 diaspore 2.87 0.74 -2.13 -0.356 0.36447E+04 66 diamond -3.10 -7.83 -4.73 -1.352 0.80769E+04 71 enstatite 17.26 12.27 -4.99 -0.499 0.85225E+04 73 clinoenstatite 17.17 12.27 -4.89 -0.489 0.83541E+04 75 epidote 24.67 22.70 -1.97 -0.095 0.33581E+04 76 clinozoisite 22.81 18.95 -3.86 -0.175 0.65860E+04 77 epidote-Fe 29.84 26.46 -3.38 -0.176 0.57768E+04 78 fayalite 14.05 10.31 -3.73 -0.533 0.63743E+04 79 ferrosilite 11.15 7.16 -3.99 -0.399 0.68203E+04 83 gibbsite 4.08 0.74 -3.34 -0.477 0.57032E+04 84 glaucophane 22.97 20.80 -2.17 -0.059 0.37132E+04 85 glaucophane-Fe 17.28 13.12 -4.15 -0.112 0.70920E+04 86 graphite -3.55 -7.83 -4.29 -1.225 0.73191E+04 87 greenalite 16.14 13.89 -2.25 -0.187 0.38408E+04 90 hematite 12.57 8.99 -3.58 -0.434 0.61113E+04 91 heulandite -5.83 -7.52 -1.69 -0.077 0.28938E+04 95 jadeite 4.22 2.77 -1.44 -0.144 0.24616E+04 97 kalsilite 7.58 3.83 -3.76 -0.536 0.64124E+04 98 kaolinite -1.33 -4.84 -3.50 -0.319 0.59827E+04 101 laumontite 2.88 1.95 -0.93 -0.062 0.15932E+04 102 lawsonite 9.62 8.27 -1.35 -0.090 0.23064E+04 103 leucite 4.12 0.67 -3.45 -0.345 0.58872E+04 105 lizardite 23.24 21.57 -1.68 -0.140 0.28617E+04 107 magnetite 20.09 15.72 -4.37 -0.356 0.74537E+04 108 minnesotaite 10.39 7.58 -2.81 -0.165 0.48031E+04 112 manganosite 14.06 9.24 -4.82 -1.205 0.82330E+04 120 muscovite 2.58 -1.01 -3.59 -0.211 0.61309E+04 121 paragonite 4.24 1.09 -3.14 -0.185 0.53700E+04 122 nepheline 8.34 5.93 -2.41 -0.344 0.41123E+04 128 periclase-Fe 11.63 6.74 -4.89 -1.223 0.83522E+04 134 phlogopite-Na 29.65 27.50 -2.15 -0.119 0.36674E+04 136 prehnite 19.37 18.21 -1.16 -0.068 0.19844E+04 137 prehnite-Fe 22.50 21.96 -0.53 -0.032 0.91145E+03 138 pumpellyite-Fe 46.27 43.89 -2.38 -0.053 0.40567E+04 139 pumpellyite-Mg 48.99 46.45 -2.54 -0.056 0.43405E+04 143 pyrrhotite -4.26 -8.04 -3.78 -1.259 0.64482E+04 144 pyrrhotiteFe0.875 -6.02 -9.43 -3.42 -1.257 0.58355E+04 145 pyroxmangite 7.40 6.08 -1.32 -0.264 0.22535E+04 146 pyrophyllite -6.18 -11.15 -4.98 -0.311 0.84960E+04 147 quartz -2.99 -3.16 -0.17 -0.056 0.28691E+03 152 rhodonite 7.45 6.08 -1.37 -0.273 0.23338E+04 153 sanidine -1.28 -2.49 -1.21 -0.093 0.20677E+04 165 stilpnomelane-Mg 27.44 25.81 -1.63 -0.049 0.27800E+04 171 talc 16.49 15.25 -1.24 -0.073 0.21141E+04 174 tephroite 18.09 15.32 -2.77 -0.396 0.47306E+04 178 tridymite -2.63 -3.16 -0.53 -0.177 0.90689E+03 179 tremolite 47.87 47.42 -0.45 -0.012 0.77498E+03 180 ferroactinolite 38.45 34.62 -3.83 -0.104 0.65453E+04 181 troilite-low -4.41 -8.04 -3.63 -1.209 0.61910E+04 183 vesuvianite 223.47 218.82 -4.65 -0.035 0.79399E+04 187 wairakite 3.95 1.95 -2.00 -0.118 0.34151E+04 188 walstromite 11.51 9.94 -1.56 -0.313 0.26719E+04 189 wollastonite 10.46 9.94 -0.52 -0.103 0.88229E+03 190 pseudo-wollastonite 11.00 9.94 -1.06 -0.211 0.18021E+04 191 zoisite 22.85 18.95 -3.90 -0.177 0.66601E+04 192 akaganeite 7.75 4.49 -3.26 -0.705 0.55682E+04 199 chalcedony -2.80 -3.16 -0.36 -0.118 0.60621E+03 201 montmorillonite-Ca -2.29 -6.17 -3.88 -0.240 0.66179E+04 202 montmorillonite-K -2.24 -6.27 -4.03 -0.247 0.68815E+04 203 montmorillonite-Mg -2.48 -6.79 -4.31 -0.267 0.73676E+04 204 montmorillonite-Na -2.04 -5.57 -3.54 -0.216 0.60364E+04 205 nontronite-Ca 3.21 -0.20 -3.41 -0.221 0.58219E+04 206 nontronite-H 2.53 -2.36 -4.89 -0.328 0.83489E+04 207 nontronite-K 3.34 -0.30 -3.64 -0.233 0.62087E+04 208 nontronite-Mg 3.07 -0.82 -3.90 -0.253 0.66557E+04 209 nontronite-Na 3.52 0.40 -3.12 -0.200 0.53296E+04 224 tobermorite 9.82 7.76 -2.07 -0.564 0.35287E+04 230 alabandite -0.98 -5.54 -4.56 -1.519 0.77819E+04 233 boehmite 4.41 0.74 -3.67 -0.611 0.62616E+04 235 ferrous-oxide 9.81 6.74 -3.08 -0.769 0.52532E+04 240 silica-amorphous -2.09 -3.16 -1.07 -0.355 0.18204E+04 242 an20ab80 2.02 1.35 -0.67 -0.052 0.11471E+04 243 an25ab75 2.65 1.78 -0.87 -0.067 0.14809E+04 244 an30ab70 3.28 2.21 -1.07 -0.082 0.18242E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 20.0000000 g Current total amount of reactant added: 639.9990000 g New total amount of reactant added: 659.9990000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.1586E-10 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 11 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 659.9990000 Water: Moles liquid = 0.5174E+02 kg liquid = 0.9322E+00 Moles total = 0.4723E+02 kg total = 0.8510E+00 Activity = 1.0000 Stoichiometric ionic strength = .1132554E-01 Osmotic coef. = 0.9694 True ionic strength = .2001397E-01 Chg. balance for total moles = -.1586E-10 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.88274E-10 -10.0542 0.74173E-10 -10.1298 0.84026E+00 -0.0756 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.14734E-03 -3.8317 0.12306E-03 -3.9099 0.83521E+00 -0.0782 4 SO4-- 0.69397E-12 -12.1587 0.36041E-12 -12.4432 0.51934E+00 -0.2846 5 HCO3- 0.25682E-06 -6.5904 0.21482E-06 -6.6679 0.83643E+00 -0.0776 6 HS- 0.27355E-04 -4.5630 0.22850E-04 -4.6411 0.83533E+00 -0.0781 7 Al+++ 0.96864E-29 -29.0138 0.22382E-29 -29.6501 0.23106E+00 -0.6363 8 H4SiO4 0.69588E-03 -3.1575 0.69588E-03 -3.1575 0.10000E+01 0.0000 9 Ca++ 0.13494E-06 -6.8699 0.69564E-07 -7.1576 0.51553E+00 -0.2877 10 Mg++ 0.21110E-10 -10.6755 0.10833E-10 -10.9652 0.51317E+00 -0.2897 11 Fe++ 0.58178E-13 -13.2352 0.29888E-13 -13.5245 0.51373E+00 -0.2893 12 K+ 0.15648E-03 -3.8055 0.13092E-03 -3.8830 0.83663E+00 -0.0775 13 Na+ 0.19856E-01 -1.7021 0.16581E-01 -1.7804 0.83506E+00 -0.0783 14 Mn++ 0.18447E-10 -10.7341 0.94849E-11 -11.0230 0.51416E+00 -0.2889 15 HPO4-- 0.45326E-07 -7.3437 0.23543E-07 -7.6281 0.51941E+00 -0.2845 16 HSiO3- 0.10489E-01 -1.9793 0.87602E-02 -2.0575 0.83521E+00 -0.0782 17 Ca(HSiO3)+ 0.16585E-07 -7.7803 0.13878E-07 -7.8577 0.83681E+00 -0.0774 18 Mg(HSiO3)+ 0.32142E-11 -11.4929 0.26897E-11 -11.5703 0.83681E+00 -0.0774 19 NaHSiO3,aq 0.23493E-02 -2.6291 0.23493E-02 -2.6291 0.10000E+01 0.0000 20 AlO+ 0.66137E-16 -16.1796 0.55344E-16 -16.2569 0.83681E+00 -0.0774 22 HAlO2,aq 0.14859E-09 -9.8280 0.14859E-09 -9.8280 0.10000E+01 0.0000 23 AlO2- 0.53191E-05 -5.2742 0.44346E-05 -5.3531 0.83370E+00 -0.0790 24 CH4,aq 0.13276E-04 -4.8769 0.13230E-04 -4.8784 0.99655E+00 -0.0015 25 C2H6,aq 0.25915E-14 -14.5865 0.25825E-14 -14.5880 0.99655E+00 -0.0015 29 CO,aq 0.99094E-17 -17.0040 0.99094E-17 -17.0040 0.10000E+01 0.0000 30 CO2,aq 0.34164E-10 -10.4664 0.34046E-10 -10.4679 0.99655E+00 -0.0015 31 CO3-2 0.48813E-06 -6.3115 0.25297E-06 -6.5969 0.51823E+00 -0.2855 32 CaCO3,aq 0.22065E-09 -9.6563 0.22065E-09 -9.6563 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.45583E-12 -12.3412 0.38145E-12 -12.4186 0.83681E+00 -0.0774 34 CaCl+ 0.16555E-10 -10.7811 0.13853E-10 -10.8585 0.83681E+00 -0.0774 35 CaCl2,aq 0.40500E-15 -15.3925 0.40500E-15 -15.3925 0.10000E+01 0.0000 36 CaOH+ 0.79876E-07 -7.0976 0.66841E-07 -7.1750 0.83681E+00 -0.0774 37 CaSO4,aq 0.79613E-17 -17.0990 0.79613E-17 -17.0990 0.10000E+01 0.0000 38 HCl,aq 0.16726E-14 -14.7766 0.16726E-14 -14.7766 0.10000E+01 0.0000 43 FeCl+ 0.69567E-17 -17.1576 0.58215E-17 -17.2350 0.83681E+00 -0.0774 46 FeO,aq 0.21114E-09 -9.6754 0.21114E-09 -9.6754 0.10000E+01 0.0000 47 FeOH+ 0.15674E-10 -10.8048 0.13116E-10 -10.8822 0.83681E+00 -0.0774 48 HFeO2- 0.35660E-07 -7.4478 0.29784E-07 -7.5260 0.83521E+00 -0.0782 49 FeO+ 0.10983E-16 -16.9593 0.91910E-17 -17.0366 0.83681E+00 -0.0774 51 FeO2- 0.40928E-09 -9.3880 0.34184E-09 -9.4662 0.83521E+00 -0.0782 52 HFeO2,aq 0.32248E-11 -11.4915 0.32248E-11 -11.4915 0.10000E+01 0.0000 53 H2,aq 0.11626E-04 -4.9346 0.11586E-04 -4.9361 0.99655E+00 -0.0015 54 KCl,aq 0.29198E-09 -9.5346 0.29198E-09 -9.5346 0.10000E+01 0.0000 56 KOH,aq 0.75375E-06 -6.1228 0.75375E-06 -6.1228 0.10000E+01 0.0000 57 KSO4- 0.87662E-15 -15.0572 0.73216E-15 -15.1354 0.83521E+00 -0.0782 58 MgCO3,aq 0.86130E-14 -14.0648 0.86130E-14 -14.0648 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.72535E-16 -16.1395 0.60698E-16 -16.2168 0.83681E+00 -0.0774 60 MgCl+ 0.23366E-14 -14.6314 0.19553E-14 -14.7088 0.83681E+00 -0.0774 61 MgOH+ 0.68831E-10 -10.1622 0.57599E-10 -10.2396 0.83681E+00 -0.0774 63 MnO,aq 0.17854E-08 -8.7483 0.17854E-08 -8.7483 0.10000E+01 0.0000 64 MnOH+ 0.46209E-09 -9.3353 0.38668E-09 -9.4127 0.83681E+00 -0.0774 65 MnO2-2 0.20782E-10 -10.6823 0.10770E-10 -10.9678 0.51823E+00 -0.2855 66 HMnO2- 0.20954E-09 -9.6787 0.17501E-09 -9.7569 0.83521E+00 -0.0782 69 MnCl+ 0.85890E-14 -14.0661 0.71874E-14 -14.1434 0.83681E+00 -0.0774 71 NaCl,aq 0.67620E-06 -6.1699 0.67620E-06 -6.1699 0.10000E+01 0.0000 72 NaOH,aq 0.96047E-04 -4.0175 0.96047E-04 -4.0175 0.10000E+01 0.0000 74 OH- 0.93433E-02 -2.0295 0.77895E-02 -2.1085 0.83370E+00 -0.0790 79 HPO3-2 0.16403E-14 -14.7851 0.85006E-15 -15.0706 0.51823E+00 -0.2855 81 H2PO3- 0.15138E-18 -18.8199 0.12644E-18 -18.8981 0.83521E+00 -0.0782 82 H3PO4,aq 0.90589E-18 -18.0429 0.90589E-18 -18.0429 0.10000E+01 0.0000 83 H2PO4- 0.38533E-10 -10.4142 0.32214E-10 -10.4920 0.83600E+00 -0.0778 84 PO4-3 0.10671E-08 -8.9718 0.25897E-09 -9.5868 0.24268E+00 -0.6150 88 HP2O7-3 0.94703E-18 -18.0236 0.21904E-18 -18.6595 0.23129E+00 -0.6358 89 P2O7-4 0.91473E-17 -17.0387 0.70549E-18 -18.1515 0.77125E-01 -1.1128 90 H2S,aq 0.52564E-08 -8.2793 0.52382E-08 -8.2808 0.99655E+00 -0.0015 91 S2-2 0.19268E-14 -14.7152 0.99854E-15 -15.0006 0.51823E+00 -0.2855 97 SO3-2 0.10322E-17 -17.9862 0.54264E-18 -18.2655 0.52573E+00 -0.2792 99 HSO4- 0.30757E-19 -19.5121 0.25763E-19 -19.5890 0.83762E+00 -0.0770 Charge balance for all species = -.1701E-10 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.8827385E-10 -.2230292E-01 -.2244094E+02 0.0000 2 H2O 0.1000000E+01 0.5550489E+02 0.9981998E+06 0.0000 3 Cl- 0.1473350E-03 0.1480115E-03 0.5238335E+01 6.2199 4 SO4-- 0.6939744E-12 -.1618218E-04 -.1551785E+01 7.8163 5 HCO3- 0.2568232E-06 0.1402082E-04 0.8540244E+00 3.4618 6 HS- 0.2735461E-04 0.4354204E-04 0.1437520E+01 5.4886 7 Al+++ 0.9686417E-29 0.5319282E-05 0.1432728E+00 0.7392 8 H4SiO4 0.6958828E-03 0.1353387E-01 0.1298553E+04 -3.1575 9 Ca++ 0.1349381E-06 0.2316361E-06 0.9267380E-02 13.1019 10 Mg++ 0.2111037E-10 0.9316682E-10 0.2261136E-05 9.2943 11 Fe++ 0.5817813E-13 0.3629951E-07 0.2023697E-02 6.7350 12 K+ 0.1564795E-03 0.1572335E-03 0.6137463E+01 6.2467 13 Na+ 0.1985645E-01 0.2230249E-01 0.5118389E+03 8.3494 14 Mn++ 0.1844749E-10 0.2496243E-08 0.1369003E-03 9.2365 15 HPO4-- 0.4532605E-07 0.4643169E-07 0.4448724E-02 12.6314 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.1092859E+02 -.2079046E-01 -.1090780E+02 0.0000000E+00 2 H2O 0.4723489E+02 0.5174085E+02 -.4505956E+01 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.1831633E-01 -.1508479E-04 0.1833141E-01 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.1829082E-01 0.4058926E-04 -.1833141E-01 0.0000000E+00 7 Al+++ 0.2152086E+01 0.4958557E-05 0.2152081E+01 0.0000000E+00 8 H4SiO4 0.6872426E+01 0.1261607E-01 0.6859810E+01 0.0000000E+00 9 Ca++ 0.7591075E+00 0.2159278E-06 0.7591073E+00 0.0000000E+00 10 Mg++ 0.5238087E+00 0.8684875E-10 0.5238087E+00 0.0000000E+00 11 Fe++ 0.4705850E+00 0.3383788E-07 0.4705849E+00 0.0000000E+00 12 K+ 0.1401272E+00 0.1465708E-03 0.1399806E+00 0.0000000E+00 13 Na+ 0.8286196E+00 0.2079006E-01 0.8078296E+00 0.0000000E+00 14 Mn++ 0.1144346E-01 0.2326961E-08 0.1144345E-01 0.0000000E+00 15 HPO4-- 0.3905595E-02 0.4328295E-07 0.3905551E-02 0.0000000E+00 Chg. balance for solid moles: -.2182E-14 Mass of aqueous solution: 0.933808E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 659.9990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 0.8070 -0.093 211.6 2.326 29.36 81.24 andradite 0.7333E-01 -1.135 37.26 1.571 5.169 9.681 grossular 0.1776E-01 -1.750 8.002 0.903 1.110 2.226 apatite-OH 0.1302E-02 -2.885 0.6539 -0.184 0.9072E-01 0.2078 clinochlore 0.9487E-01 -1.023 52.73 1.722 7.315 20.06 daphnite 0.2746E-01 -1.561 19.59 1.292 2.718 5.937 chlorite-Mn 0.2289E-02 -2.640 1.623 0.210 0.2251 0.5171 diopside 0.2664E-01 -1.574 5.769 0.761 0.8003 1.763 hedenbergite 0.6908E-02 -2.161 1.714 0.234 0.2377 0.4694 microcline 0.1228 -0.911 34.18 1.534 4.741 13.35 stilbite 0.4332 -0.363 305.3 2.485 42.35 142.4 stilpnomelane-Fe 0.3437E-01 -1.464 37.05 1.569 5.140 12.80 tr.625ac.25prg.125 0.6297E-02 -2.201 5.383 0.731 0.7467 1.732 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8050E+00 0.8050E+00 1.0000 -0.094 grossular 0.1950E+00 0.1950E+00 1.0000 -0.710 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.7613E+00 0.7613E+00 1.0000 -0.118 daphnite 0.2204E+00 0.2204E+00 1.0000 -0.657 chlorite-Mn 0.1837E-01 0.1837E-01 1.0000 -1.736 diopside 0.7941E+00 0.7941E+00 1.0000 -0.100 hedenbergite 0.2059E+00 0.2059E+00 1.0000 -0.686 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 tr.625ac.25prg.125 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 720.859068 g Volume = 292.364874 cm3 Porosity: -10.3265% V(tot) - V(min): -.27365E+02 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 659.9990000 g log = 2.8195 Original solution: 1000.0103000 g Original solution / Rock added: 1.52 (Water/Rock Ratio), log = 0.1805 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0552 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9674E+00 0.9855 0.1006E+01 0.1021E+01 CO2,gas 0.3428E-08 1.0069 0.3643E-08 0.3618E-08 CH4,gas 0.1823E-01 1.0125 0.1947E-01 0.1923E-01 H2,gas 0.1441E-01 1.0006 0.1521E-01 0.1520E-01 H2S,gas 0.1370E-06 0.9959 0.1440E-06 0.1446E-06 S2,gas 0.3188E-29 1.0000 0.3364E-29 0.3364E-29 CO,gas 0.1399E-13 1.0000 0.1477E-13 0.1477E-13 SO3,gas 0.7105E-48 1.0000 0.7497E-48 0.7497E-48 SO2,gas 0.4205E-27 1.0000 0.4437E-27 0.4437E-27 HCl,gas 0.2797E-17 1.0000 0.2951E-17 0.2951E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 16 albite -0.38 -0.38 0.00 0.000 0.11184E-10 22 andradite 39.01 39.01 0.00 0.000 0.12132E-10 23 grossular 32.73 32.73 0.00 0.000 0.12132E-10 32 apatite-OH -18.15 -18.15 0.00 0.000 0.12132E-10 46 clinochlore 39.07 39.07 0.00 0.000 0.24265E-10 47 daphnite 28.97 28.97 0.00 0.000 -0.12132E-10 48 chlorite-Mn 46.87 46.87 0.00 0.000 0.24265E-10 67 diopside 16.18 16.18 0.00 0.000 0.00000E+00 68 hedenbergite 14.21 14.21 0.00 0.000 -0.60662E-11 116 microcline -2.49 -2.49 0.00 0.000 -0.10616E-10 163 stilbite -7.52 -7.52 0.00 0.000 0.15165E-10 164 stilpnomelane-Fe 13.02 13.02 0.00 0.000 -0.27298E-10 245 tr.625ac.25prg.125 45.16 45.16 0.00 0.000 0.36397E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -16.80 -10.14 -3.379 0.17310E+05 -8.439 3 CH4,gas 4.54 1.13 -3.41 -0.852 0.58217E+04 -1.711 4 H2,gas 8.00 4.48 -3.52 -2.010 0.60048E+04 -1.818 5 H2S,gas -6.23 -14.77 -8.54 -4.270 0.14583E+05 -6.842 6 S2,gas -7.34 -38.51 -31.17 -4.796 0.53226E+05 -29.473 7 CO,gas 3.21 -12.31 -15.53 -4.778 0.26517E+05 -13.831 8 SO3,gas 17.12 -32.70 -49.82 -12.456 0.85073E+05 -48.125 9 SO2,gas 0.83 -28.22 -29.05 -7.747 0.49605E+05 -27.353 10 HCl,gas 5.19 -14.04 -19.23 -9.614 0.32833E+05 -17.530 11 acmite 7.71 6.53 -1.18 -0.123 0.20178E+04 15 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 19 spessartine 24.46 19.72 -4.74 -0.237 0.80965E+04 20 analcite 3.32 2.77 -0.55 -0.061 0.93615E+03 26 annite 20.12 17.72 -2.40 -0.134 0.41063E+04 27 phlogopite 27.06 25.40 -1.67 -0.093 0.28486E+04 29 anorthite 12.71 8.27 -4.45 -0.342 0.75898E+04 35 aragonite 0.97 -3.70 -4.66 -1.554 0.79608E+04 36 brucite 12.57 9.29 -3.27 -0.655 0.55908E+04 37 calcite 0.81 -3.70 -4.51 -1.503 0.76966E+04 38 carnegieite-low 9.02 5.93 -3.09 -0.442 0.52799E+04 39 carnegieite-high 10.09 5.93 -4.16 -0.595 0.71069E+04 40 carpholite-Mg 8.58 4.46 -4.12 -0.275 0.70424E+04 41 carpholite-Fe 6.71 1.90 -4.81 -0.321 0.82202E+04 42 celadonite 5.34 3.65 -1.69 -0.099 0.28878E+04 43 celadonite-Fe 3.88 1.09 -2.79 -0.164 0.47561E+04 44 chrysotile 23.89 21.57 -2.32 -0.194 0.39691E+04 49 chlorite-Al-free 47.17 43.14 -4.04 -0.168 0.68933E+04 51 chloritoid-Fe 9.17 5.06 -4.12 -0.275 0.70310E+04 52 chloritoid-Mn 11.40 7.56 -3.84 -0.256 0.65630E+04 54 coesite -2.38 -3.16 -0.78 -0.260 0.13342E+04 61 cristobalite -2.56 -3.16 -0.60 -0.199 0.10196E+04 63 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71234E+04 65 diaspore 2.87 0.74 -2.13 -0.356 0.36447E+04 66 diamond -3.10 -7.83 -4.73 -1.351 0.80753E+04 71 enstatite 17.26 12.27 -4.99 -0.499 0.85225E+04 73 clinoenstatite 17.17 12.27 -4.89 -0.489 0.83541E+04 75 epidote 24.67 22.70 -1.97 -0.095 0.33581E+04 76 clinozoisite 22.81 18.95 -3.86 -0.175 0.65860E+04 77 epidote-Fe 29.84 26.46 -3.38 -0.176 0.57768E+04 78 fayalite 14.05 10.31 -3.73 -0.533 0.63743E+04 79 ferrosilite 11.15 7.16 -3.99 -0.399 0.68203E+04 83 gibbsite 4.08 0.74 -3.34 -0.477 0.57032E+04 84 glaucophane 22.97 20.80 -2.17 -0.059 0.37132E+04 85 glaucophane-Fe 17.28 13.12 -4.15 -0.112 0.70920E+04 86 graphite -3.55 -7.83 -4.29 -1.224 0.73175E+04 87 greenalite 16.14 13.89 -2.25 -0.187 0.38408E+04 90 hematite 12.57 8.99 -3.58 -0.434 0.61113E+04 91 heulandite -5.83 -7.52 -1.69 -0.077 0.28938E+04 95 jadeite 4.22 2.77 -1.44 -0.144 0.24616E+04 97 kalsilite 7.58 3.83 -3.76 -0.536 0.64124E+04 98 kaolinite -1.33 -4.84 -3.50 -0.319 0.59827E+04 101 laumontite 2.88 1.95 -0.93 -0.062 0.15932E+04 102 lawsonite 9.62 8.27 -1.35 -0.090 0.23065E+04 103 leucite 4.12 0.67 -3.45 -0.345 0.58872E+04 105 lizardite 23.24 21.57 -1.68 -0.140 0.28617E+04 107 magnetite 20.09 15.72 -4.37 -0.356 0.74537E+04 108 minnesotaite 10.39 7.58 -2.81 -0.165 0.48030E+04 112 manganosite 14.06 9.24 -4.82 -1.205 0.82327E+04 120 muscovite 2.58 -1.01 -3.59 -0.211 0.61309E+04 121 paragonite 4.24 1.09 -3.14 -0.185 0.53700E+04 122 nepheline 8.34 5.93 -2.41 -0.344 0.41123E+04 128 periclase-Fe 11.63 6.73 -4.89 -1.223 0.83522E+04 134 phlogopite-Na 29.65 27.50 -2.15 -0.119 0.36674E+04 136 prehnite 19.37 18.21 -1.16 -0.068 0.19844E+04 137 prehnite-Fe 22.50 21.96 -0.53 -0.032 0.91145E+03 138 pumpellyite-Fe 46.27 43.89 -2.38 -0.053 0.40568E+04 139 pumpellyite-Mg 48.99 46.45 -2.54 -0.056 0.43405E+04 143 pyrrhotite -4.26 -8.04 -3.78 -1.259 0.64466E+04 144 pyrrhotiteFe0.875 -6.02 -9.43 -3.42 -1.257 0.58339E+04 145 pyroxmangite 7.40 6.08 -1.32 -0.264 0.22532E+04 146 pyrophyllite -6.18 -11.15 -4.98 -0.311 0.84960E+04 147 quartz -2.99 -3.16 -0.17 -0.056 0.28690E+03 152 rhodonite 7.45 6.08 -1.37 -0.273 0.23334E+04 153 sanidine -1.28 -2.49 -1.21 -0.093 0.20677E+04 165 stilpnomelane-Mg 27.44 25.81 -1.63 -0.049 0.27800E+04 171 talc 16.49 15.25 -1.24 -0.073 0.21141E+04 174 tephroite 18.09 15.32 -2.77 -0.396 0.47300E+04 178 tridymite -2.63 -3.16 -0.53 -0.177 0.90688E+03 179 tremolite 47.87 47.42 -0.45 -0.012 0.77498E+03 180 ferroactinolite 38.45 34.62 -3.83 -0.104 0.65452E+04 181 troilite-low -4.41 -8.04 -3.62 -1.208 0.61894E+04 183 vesuvianite 223.47 218.82 -4.65 -0.035 0.79401E+04 187 wairakite 3.95 1.95 -2.00 -0.118 0.34152E+04 188 walstromite 11.51 9.94 -1.56 -0.313 0.26719E+04 189 wollastonite 10.46 9.94 -0.52 -0.103 0.88229E+03 190 pseudo-wollastonite 11.00 9.94 -1.06 -0.211 0.18021E+04 191 zoisite 22.85 18.95 -3.90 -0.177 0.66601E+04 192 akaganeite 7.75 4.49 -3.26 -0.705 0.55682E+04 199 chalcedony -2.80 -3.16 -0.36 -0.118 0.60620E+03 201 montmorillonite-Ca -2.29 -6.17 -3.88 -0.240 0.66179E+04 202 montmorillonite-K -2.24 -6.27 -4.03 -0.247 0.68815E+04 203 montmorillonite-Mg -2.48 -6.79 -4.31 -0.267 0.73676E+04 204 montmorillonite-Na -2.04 -5.57 -3.54 -0.216 0.60364E+04 205 nontronite-Ca 3.21 -0.20 -3.41 -0.221 0.58219E+04 206 nontronite-H 2.53 -2.36 -4.89 -0.328 0.83489E+04 207 nontronite-K 3.34 -0.30 -3.64 -0.233 0.62087E+04 208 nontronite-Mg 3.07 -0.82 -3.90 -0.253 0.66557E+04 209 nontronite-Na 3.52 0.40 -3.12 -0.200 0.53296E+04 224 tobermorite 9.82 7.76 -2.07 -0.564 0.35287E+04 230 alabandite -0.98 -5.53 -4.56 -1.519 0.77800E+04 233 boehmite 4.41 0.74 -3.67 -0.611 0.62616E+04 235 ferrous-oxide 9.81 6.73 -3.08 -0.769 0.52532E+04 240 silica-amorphous -2.09 -3.16 -1.07 -0.355 0.18204E+04 242 an20ab80 2.02 1.35 -0.67 -0.052 0.11471E+04 243 an25ab75 2.65 1.78 -0.87 -0.067 0.14809E+04 244 an30ab70 3.28 2.21 -1.07 -0.082 0.18242E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 20.0000000 g Current total amount of reactant added: 659.9990000 g New total amount of reactant added: 679.9990000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.1586E-10 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 11 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 679.9990000 Water: Moles liquid = 0.5163E+02 kg liquid = 0.9302E+00 Moles total = 0.4698E+02 kg total = 0.8464E+00 Activity = 1.0000 Stoichiometric ionic strength = .1132582E-01 Osmotic coef. = 0.9694 True ionic strength = .2001420E-01 Chg. balance for total moles = -.1586E-10 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.88275E-10 -10.0542 0.74174E-10 -10.1297 0.84026E+00 -0.0756 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.14765E-03 -3.8308 0.12332E-03 -3.9090 0.83521E+00 -0.0782 4 SO4-- 0.69550E-12 -12.1577 0.36120E-12 -12.4423 0.51934E+00 -0.2846 5 HCO3- 0.25739E-06 -6.5894 0.21529E-06 -6.6670 0.83643E+00 -0.0776 6 HS- 0.27414E-04 -4.5620 0.22900E-04 -4.6402 0.83533E+00 -0.0781 7 Al+++ 0.96867E-29 -29.0138 0.22382E-29 -29.6501 0.23106E+00 -0.6363 8 H4SiO4 0.69589E-03 -3.1575 0.69589E-03 -3.1575 0.10000E+01 0.0000 9 Ca++ 0.13494E-06 -6.8699 0.69565E-07 -7.1576 0.51552E+00 -0.2878 10 Mg++ 0.21111E-10 -10.6755 0.10833E-10 -10.9652 0.51317E+00 -0.2897 11 Fe++ 0.58179E-13 -13.2352 0.29888E-13 -13.5245 0.51373E+00 -0.2893 12 K+ 0.15648E-03 -3.8055 0.13092E-03 -3.8830 0.83663E+00 -0.0775 13 Na+ 0.19857E-01 -1.7021 0.16581E-01 -1.7804 0.83506E+00 -0.0783 14 Mn++ 0.18455E-10 -10.7339 0.94888E-11 -11.0228 0.51415E+00 -0.2889 15 HPO4-- 0.45326E-07 -7.3437 0.23543E-07 -7.6281 0.51941E+00 -0.2845 16 HSiO3- 0.10489E-01 -1.9793 0.87602E-02 -2.0575 0.83521E+00 -0.0782 17 Ca(HSiO3)+ 0.16585E-07 -7.7803 0.13878E-07 -7.8577 0.83681E+00 -0.0774 18 Mg(HSiO3)+ 0.32143E-11 -11.4929 0.26897E-11 -11.5703 0.83681E+00 -0.0774 19 NaHSiO3,aq 0.23493E-02 -2.6291 0.23493E-02 -2.6291 0.10000E+01 0.0000 20 AlO+ 0.66137E-16 -16.1796 0.55344E-16 -16.2569 0.83681E+00 -0.0774 22 HAlO2,aq 0.14859E-09 -9.8280 0.14859E-09 -9.8280 0.10000E+01 0.0000 23 AlO2- 0.53190E-05 -5.2742 0.44345E-05 -5.3532 0.83370E+00 -0.0790 24 CH4,aq 0.13304E-04 -4.8760 0.13258E-04 -4.8775 0.99655E+00 -0.0015 25 C2H6,aq 0.26027E-14 -14.5846 0.25937E-14 -14.5861 0.99655E+00 -0.0015 29 CO,aq 0.99311E-17 -17.0030 0.99311E-17 -17.0030 0.10000E+01 0.0000 30 CO2,aq 0.34239E-10 -10.4655 0.34121E-10 -10.4670 0.99655E+00 -0.0015 31 CO3-2 0.48919E-06 -6.3105 0.25352E-06 -6.5960 0.51823E+00 -0.2855 32 CaCO3,aq 0.22114E-09 -9.6553 0.22114E-09 -9.6553 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.45684E-12 -12.3402 0.38229E-12 -12.4176 0.83681E+00 -0.0774 34 CaCl+ 0.16591E-10 -10.7801 0.13883E-10 -10.8575 0.83681E+00 -0.0774 35 CaCl2,aq 0.40676E-15 -15.3907 0.40676E-15 -15.3907 0.10000E+01 0.0000 36 CaOH+ 0.79876E-07 -7.0976 0.66841E-07 -7.1750 0.83681E+00 -0.0774 37 CaSO4,aq 0.79789E-17 -17.0981 0.79789E-17 -17.0981 0.10000E+01 0.0000 38 HCl,aq 0.16762E-14 -14.7757 0.16762E-14 -14.7757 0.10000E+01 0.0000 43 FeCl+ 0.69719E-17 -17.1567 0.58341E-17 -17.2340 0.83681E+00 -0.0774 46 FeO,aq 0.21114E-09 -9.6754 0.21114E-09 -9.6754 0.10000E+01 0.0000 47 FeOH+ 0.15674E-10 -10.8048 0.13116E-10 -10.8822 0.83681E+00 -0.0774 48 HFeO2- 0.35660E-07 -7.4478 0.29783E-07 -7.5260 0.83521E+00 -0.0782 49 FeO+ 0.10984E-16 -16.9593 0.91912E-17 -17.0366 0.83681E+00 -0.0774 51 FeO2- 0.40928E-09 -9.3880 0.34184E-09 -9.4662 0.83521E+00 -0.0782 52 HFeO2,aq 0.32248E-11 -11.4915 0.32248E-11 -11.4915 0.10000E+01 0.0000 53 H2,aq 0.11626E-04 -4.9346 0.11586E-04 -4.9361 0.99655E+00 -0.0015 54 KCl,aq 0.29261E-09 -9.5337 0.29261E-09 -9.5337 0.10000E+01 0.0000 56 KOH,aq 0.75375E-06 -6.1228 0.75375E-06 -6.1228 0.10000E+01 0.0000 57 KSO4- 0.87855E-15 -15.0562 0.73378E-15 -15.1344 0.83521E+00 -0.0782 58 MgCO3,aq 0.86319E-14 -14.0639 0.86319E-14 -14.0639 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.72695E-16 -16.1385 0.60832E-16 -16.2159 0.83681E+00 -0.0774 60 MgCl+ 0.23417E-14 -14.6305 0.19595E-14 -14.7078 0.83681E+00 -0.0774 61 MgOH+ 0.68831E-10 -10.1622 0.57599E-10 -10.2396 0.83681E+00 -0.0774 63 MnO,aq 0.17861E-08 -8.7481 0.17861E-08 -8.7481 0.10000E+01 0.0000 64 MnOH+ 0.46227E-09 -9.3351 0.38683E-09 -9.4125 0.83681E+00 -0.0774 65 MnO2-2 0.20789E-10 -10.6822 0.10774E-10 -10.9676 0.51823E+00 -0.2855 66 HMnO2- 0.20962E-09 -9.6786 0.17508E-09 -9.7568 0.83521E+00 -0.0782 69 MnCl+ 0.86111E-14 -14.0649 0.72058E-14 -14.1423 0.83681E+00 -0.0774 71 NaCl,aq 0.67767E-06 -6.1690 0.67767E-06 -6.1690 0.10000E+01 0.0000 72 NaOH,aq 0.96047E-04 -4.0175 0.96047E-04 -4.0175 0.10000E+01 0.0000 74 OH- 0.93432E-02 -2.0295 0.77894E-02 -2.1085 0.83370E+00 -0.0790 79 HPO3-2 0.16403E-14 -14.7851 0.85004E-15 -15.0706 0.51823E+00 -0.2855 81 H2PO3- 0.15138E-18 -18.8199 0.12644E-18 -18.8981 0.83521E+00 -0.0782 82 H3PO4,aq 0.90590E-18 -18.0429 0.90590E-18 -18.0429 0.10000E+01 0.0000 83 H2PO4- 0.38533E-10 -10.4142 0.32213E-10 -10.4920 0.83600E+00 -0.0778 84 PO4-3 0.10671E-08 -8.9718 0.25896E-09 -9.5868 0.24268E+00 -0.6150 88 HP2O7-3 0.94703E-18 -18.0236 0.21904E-18 -18.6595 0.23129E+00 -0.6358 89 P2O7-4 0.91472E-17 -17.0387 0.70547E-18 -18.1515 0.77124E-01 -1.1128 90 H2S,aq 0.52678E-08 -8.2784 0.52496E-08 -8.2799 0.99655E+00 -0.0015 91 S2-2 0.19352E-14 -14.7133 0.10029E-14 -14.9988 0.51823E+00 -0.2855 97 SO3-2 0.10344E-17 -17.9853 0.54382E-18 -18.2645 0.52573E+00 -0.2792 99 HSO4- 0.30824E-19 -19.5111 0.25819E-19 -19.5881 0.83762E+00 -0.0770 Charge balance for all species = -.1706E-10 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.8827486E-10 -.2230278E-01 -.2244080E+02 0.0000 2 H2O 0.1000000E+01 0.5550489E+02 0.9981998E+06 0.0000 3 Cl- 0.1476531E-03 0.1483311E-03 0.5249646E+01 6.2208 4 SO4-- 0.6954973E-12 -.1621079E-04 -.1554529E+01 7.8172 5 HCO3- 0.2573860E-06 0.1405109E-04 0.8558685E+00 3.4628 6 HS- 0.2741368E-04 0.4362974E-04 0.1440415E+01 5.4896 7 Al+++ 0.9686662E-29 0.5319154E-05 0.1432694E+00 0.7391 8 H4SiO4 0.6958860E-03 0.1353382E-01 0.1298549E+04 -3.1575 9 Ca++ 0.1349408E-06 0.2316400E-06 0.9267538E-02 13.1019 10 Mg++ 0.2111078E-10 0.9316759E-10 0.2261155E-05 9.2943 11 Fe++ 0.5817946E-13 0.3629909E-07 0.2023673E-02 6.7350 12 K+ 0.1564813E-03 0.1572353E-03 0.6137533E+01 6.2467 13 Na+ 0.1985668E-01 0.2230273E-01 0.5118444E+03 8.3494 14 Mn++ 0.1845515E-10 0.2497221E-08 0.1369539E-03 9.2367 15 HPO4-- 0.4532557E-07 0.4643119E-07 0.4448676E-02 12.6313 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.1125976E+02 -.2074553E-01 -.1123902E+02 0.0000000E+00 2 H2O 0.4698418E+02 0.5162937E+02 -.4645181E+01 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.1887059E-01 -.1507890E-04 0.1888567E-01 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.1884509E-01 0.4058337E-04 -.1888567E-01 0.0000000E+00 7 Al+++ 0.2217301E+01 0.4947755E-05 0.2217296E+01 0.0000000E+00 8 H4SiO4 0.7080682E+01 0.1258885E-01 0.7068093E+01 0.0000000E+00 9 Ca++ 0.7821103E+00 0.2154662E-06 0.7821101E+00 0.0000000E+00 10 Mg++ 0.5396817E+00 0.8666234E-10 0.5396817E+00 0.0000000E+00 11 Fe++ 0.4848451E+00 0.3376457E-07 0.4848451E+00 0.0000000E+00 12 K+ 0.1443735E+00 0.1462567E-03 0.1442272E+00 0.0000000E+00 13 Na+ 0.8537245E+00 0.2074548E-01 0.8329790E+00 0.0000000E+00 14 Mn++ 0.1179023E-01 0.2322857E-08 0.1179023E-01 0.0000000E+00 15 HPO4-- 0.4023946E-02 0.4318922E-07 0.4023903E-02 0.0000000E+00 Chg. balance for solid moles: 0.6262E-15 Mass of aqueous solution: 0.931796E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 679.9990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 0.8322 -0.080 218.2 2.339 29.38 83.77 andradite 0.7554E-01 -1.122 38.39 1.584 5.169 9.974 grossular 0.1830E-01 -1.738 8.244 0.916 1.110 2.294 apatite-OH 0.1341E-02 -2.872 0.6738 -0.171 0.9072E-01 0.2141 clinochlore 0.9770E-01 -1.010 54.31 1.735 7.312 20.66 daphnite 0.2828E-01 -1.548 20.18 1.305 2.717 6.115 chlorite-Mn 0.2358E-02 -2.627 1.672 0.223 0.2251 0.5328 diopside 0.2773E-01 -1.557 6.004 0.778 0.8084 1.835 hedenbergite 0.7190E-02 -2.143 1.784 0.251 0.2402 0.4886 microcline 0.1265 -0.898 35.22 1.547 4.741 13.76 stilbite 0.4460 -0.351 314.3 2.497 42.32 146.6 stilpnomelane-Fe 0.3542E-01 -1.451 38.18 1.582 5.140 13.19 tr.625ac.25prg.125 0.6464E-02 -2.190 5.525 0.742 0.7439 1.778 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8050E+00 0.8050E+00 1.0000 -0.094 grossular 0.1950E+00 0.1950E+00 1.0000 -0.710 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.7613E+00 0.7613E+00 1.0000 -0.118 daphnite 0.2204E+00 0.2204E+00 1.0000 -0.657 chlorite-Mn 0.1837E-01 0.1837E-01 1.0000 -1.736 diopside 0.7941E+00 0.7941E+00 1.0000 -0.100 hedenbergite 0.2059E+00 0.2059E+00 1.0000 -0.686 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 tr.625ac.25prg.125 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 742.709199 g Volume = 301.205487 cm3 Porosity: -10.3318% V(tot) - V(min): -.28206E+02 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 679.9990000 g log = 2.8325 Original solution: 1000.0103000 g Original solution / Rock added: 1.47 (Water/Rock Ratio), log = 0.1675 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0553 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9673E+00 0.9855 0.1006E+01 0.1021E+01 CO2,gas 0.3436E-08 1.0069 0.3651E-08 0.3625E-08 CH4,gas 0.1827E-01 1.0125 0.1952E-01 0.1928E-01 H2,gas 0.1441E-01 1.0006 0.1521E-01 0.1520E-01 H2S,gas 0.1373E-06 0.9959 0.1443E-06 0.1449E-06 S2,gas 0.3201E-29 1.0000 0.3378E-29 0.3378E-29 CO,gas 0.1402E-13 1.0000 0.1480E-13 0.1480E-13 SO3,gas 0.7120E-48 1.0000 0.7514E-48 0.7514E-48 SO2,gas 0.4214E-27 1.0000 0.4447E-27 0.4447E-27 HCl,gas 0.2803E-17 1.0000 0.2958E-17 0.2958E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 16 albite -0.38 -0.38 0.00 0.000 -0.13080E-10 22 andradite 39.01 39.01 0.00 0.000 0.12132E-10 23 grossular 32.73 32.73 0.00 0.000 0.00000E+00 32 apatite-OH -18.15 -18.15 0.00 0.000 -0.60662E-11 46 clinochlore 39.07 39.07 0.00 0.000 -0.36397E-10 47 daphnite 28.97 28.97 0.00 0.000 -0.72794E-10 48 chlorite-Mn 46.87 46.87 0.00 0.000 -0.12132E-10 67 diopside 16.18 16.18 0.00 0.000 -0.12132E-10 68 hedenbergite 14.21 14.21 0.00 0.000 -0.30331E-11 116 microcline -2.49 -2.49 0.00 0.000 0.15165E-11 163 stilbite -7.52 -7.52 0.00 0.000 0.15165E-10 164 stilpnomelane-Fe 13.02 13.02 0.00 0.000 -0.75827E-10 245 tr.625ac.25prg.125 45.16 45.16 0.00 0.000 0.36397E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -16.80 -10.14 -3.379 0.17308E+05 -8.438 3 CH4,gas 4.54 1.14 -3.41 -0.852 0.58201E+04 -1.710 4 H2,gas 8.00 4.48 -3.52 -2.010 0.60048E+04 -1.818 5 H2S,gas -6.23 -14.77 -8.54 -4.270 0.14581E+05 -6.841 6 S2,gas -7.34 -38.51 -31.17 -4.795 0.53222E+05 -29.471 7 CO,gas 3.21 -12.31 -15.53 -4.778 0.26515E+05 -13.830 8 SO3,gas 17.12 -32.70 -49.82 -12.456 0.85072E+05 -48.124 9 SO2,gas 0.83 -28.22 -29.05 -7.747 0.49604E+05 -27.352 10 HCl,gas 5.19 -14.04 -19.23 -9.614 0.32831E+05 -17.529 11 acmite 7.71 6.53 -1.18 -0.123 0.20178E+04 15 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 19 spessartine 24.46 19.72 -4.74 -0.237 0.80956E+04 20 analcite 3.32 2.77 -0.55 -0.061 0.93615E+03 26 annite 20.12 17.72 -2.40 -0.134 0.41063E+04 27 phlogopite 27.06 25.40 -1.67 -0.093 0.28486E+04 29 anorthite 12.71 8.27 -4.45 -0.342 0.75898E+04 35 aragonite 0.97 -3.69 -4.66 -1.554 0.79592E+04 36 brucite 12.57 9.29 -3.27 -0.655 0.55908E+04 37 calcite 0.81 -3.69 -4.51 -1.502 0.76949E+04 38 carnegieite-low 9.02 5.93 -3.09 -0.442 0.52799E+04 39 carnegieite-high 10.09 5.93 -4.16 -0.595 0.71069E+04 40 carpholite-Mg 8.58 4.46 -4.12 -0.275 0.70424E+04 41 carpholite-Fe 6.71 1.90 -4.81 -0.321 0.82202E+04 42 celadonite 5.34 3.65 -1.69 -0.099 0.28878E+04 43 celadonite-Fe 3.88 1.09 -2.79 -0.164 0.47561E+04 44 chrysotile 23.89 21.57 -2.32 -0.194 0.39691E+04 49 chlorite-Al-free 47.17 43.14 -4.04 -0.168 0.68933E+04 51 chloritoid-Fe 9.17 5.06 -4.12 -0.275 0.70310E+04 52 chloritoid-Mn 11.40 7.56 -3.84 -0.256 0.65627E+04 54 coesite -2.38 -3.16 -0.78 -0.260 0.13342E+04 61 cristobalite -2.56 -3.16 -0.60 -0.199 0.10196E+04 63 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71234E+04 65 diaspore 2.87 0.74 -2.13 -0.356 0.36447E+04 66 diamond -3.10 -7.83 -4.73 -1.351 0.80737E+04 71 enstatite 17.26 12.27 -4.99 -0.499 0.85225E+04 73 clinoenstatite 17.17 12.27 -4.89 -0.489 0.83541E+04 75 epidote 24.67 22.70 -1.97 -0.095 0.33581E+04 76 clinozoisite 22.81 18.95 -3.86 -0.175 0.65861E+04 77 epidote-Fe 29.84 26.46 -3.38 -0.176 0.57768E+04 78 fayalite 14.05 10.31 -3.73 -0.533 0.63743E+04 79 ferrosilite 11.15 7.16 -3.99 -0.399 0.68203E+04 83 gibbsite 4.08 0.74 -3.34 -0.477 0.57032E+04 84 glaucophane 22.97 20.80 -2.17 -0.059 0.37132E+04 85 glaucophane-Fe 17.28 13.12 -4.15 -0.112 0.70920E+04 86 graphite -3.55 -7.83 -4.28 -1.224 0.73159E+04 87 greenalite 16.14 13.89 -2.25 -0.187 0.38408E+04 90 hematite 12.57 8.99 -3.58 -0.434 0.61113E+04 91 heulandite -5.83 -7.52 -1.69 -0.077 0.28938E+04 95 jadeite 4.22 2.77 -1.44 -0.144 0.24616E+04 97 kalsilite 7.58 3.83 -3.76 -0.536 0.64124E+04 98 kaolinite -1.33 -4.84 -3.50 -0.319 0.59828E+04 101 laumontite 2.88 1.95 -0.93 -0.062 0.15932E+04 102 lawsonite 9.62 8.27 -1.35 -0.090 0.23065E+04 103 leucite 4.12 0.67 -3.45 -0.345 0.58872E+04 105 lizardite 23.24 21.57 -1.68 -0.140 0.28617E+04 107 magnetite 20.09 15.72 -4.37 -0.356 0.74537E+04 108 minnesotaite 10.39 7.58 -2.81 -0.165 0.48030E+04 112 manganosite 14.06 9.24 -4.82 -1.205 0.82324E+04 120 muscovite 2.58 -1.01 -3.59 -0.211 0.61309E+04 121 paragonite 4.24 1.09 -3.15 -0.185 0.53700E+04 122 nepheline 8.34 5.93 -2.41 -0.344 0.41123E+04 128 periclase-Fe 11.63 6.73 -4.89 -1.223 0.83522E+04 134 phlogopite-Na 29.65 27.50 -2.15 -0.119 0.36674E+04 136 prehnite 19.37 18.21 -1.16 -0.068 0.19844E+04 137 prehnite-Fe 22.50 21.96 -0.53 -0.032 0.91146E+03 138 pumpellyite-Fe 46.27 43.89 -2.38 -0.053 0.40568E+04 139 pumpellyite-Mg 48.99 46.45 -2.54 -0.056 0.43406E+04 143 pyrrhotite -4.26 -8.03 -3.77 -1.258 0.64450E+04 144 pyrrhotiteFe0.875 -6.02 -9.43 -3.42 -1.256 0.58323E+04 145 pyroxmangite 7.40 6.08 -1.32 -0.264 0.22529E+04 146 pyrophyllite -6.18 -11.15 -4.98 -0.311 0.84960E+04 147 quartz -2.99 -3.16 -0.17 -0.056 0.28690E+03 152 rhodonite 7.45 6.08 -1.37 -0.273 0.23331E+04 153 sanidine -1.28 -2.49 -1.21 -0.093 0.20677E+04 165 stilpnomelane-Mg 27.44 25.81 -1.63 -0.049 0.27800E+04 171 talc 16.49 15.25 -1.24 -0.073 0.21141E+04 174 tephroite 18.09 15.32 -2.77 -0.396 0.47294E+04 178 tridymite -2.63 -3.16 -0.53 -0.177 0.90688E+03 179 tremolite 47.87 47.42 -0.45 -0.012 0.77498E+03 180 ferroactinolite 38.45 34.62 -3.83 -0.104 0.65452E+04 181 troilite-low -4.41 -8.03 -3.62 -1.208 0.61878E+04 183 vesuvianite 223.47 218.82 -4.65 -0.035 0.79402E+04 187 wairakite 3.95 1.95 -2.00 -0.118 0.34152E+04 188 walstromite 11.51 9.94 -1.56 -0.313 0.26719E+04 189 wollastonite 10.46 9.94 -0.52 -0.103 0.88229E+03 190 pseudo-wollastonite 11.00 9.94 -1.06 -0.211 0.18021E+04 191 zoisite 22.85 18.95 -3.90 -0.177 0.66601E+04 192 akaganeite 7.75 4.49 -3.26 -0.705 0.55682E+04 199 chalcedony -2.80 -3.16 -0.36 -0.118 0.60620E+03 201 montmorillonite-Ca -2.29 -6.17 -3.88 -0.240 0.66179E+04 202 montmorillonite-K -2.24 -6.27 -4.03 -0.247 0.68815E+04 203 montmorillonite-Mg -2.48 -6.79 -4.31 -0.267 0.73676E+04 204 montmorillonite-Na -2.04 -5.57 -3.54 -0.216 0.60364E+04 205 nontronite-Ca 3.21 -0.20 -3.41 -0.221 0.58219E+04 206 nontronite-H 2.53 -2.36 -4.89 -0.328 0.83489E+04 207 nontronite-K 3.34 -0.30 -3.64 -0.233 0.62087E+04 208 nontronite-Mg 3.07 -0.82 -3.90 -0.253 0.66557E+04 209 nontronite-Na 3.52 0.40 -3.12 -0.200 0.53296E+04 224 tobermorite 9.82 7.76 -2.07 -0.564 0.35287E+04 230 alabandite -0.98 -5.53 -4.56 -1.518 0.77781E+04 233 boehmite 4.41 0.74 -3.67 -0.611 0.62616E+04 235 ferrous-oxide 9.81 6.73 -3.08 -0.769 0.52532E+04 240 silica-amorphous -2.09 -3.16 -1.07 -0.355 0.18204E+04 242 an20ab80 2.02 1.35 -0.67 -0.052 0.11471E+04 243 an25ab75 2.65 1.78 -0.87 -0.067 0.14809E+04 244 an30ab70 3.28 2.21 -1.07 -0.082 0.18242E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 20.0000000 g Current total amount of reactant added: 679.9990000 g New total amount of reactant added: 699.9990000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.1586E-10 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 11 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 699.9990000 Water: Moles liquid = 0.5152E+02 kg liquid = 0.9282E+00 Moles total = 0.4673E+02 kg total = 0.8419E+00 Activity = 1.0000 Stoichiometric ionic strength = .1132611E-01 Osmotic coef. = 0.9694 True ionic strength = .2001443E-01 Chg. balance for total moles = -.1586E-10 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.88276E-10 -10.0542 0.74175E-10 -10.1297 0.84026E+00 -0.0756 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.14797E-03 -3.8298 0.12359E-03 -3.9080 0.83521E+00 -0.0782 4 SO4-- 0.69703E-12 -12.1568 0.36199E-12 -12.4413 0.51933E+00 -0.2846 5 HCO3- 0.25795E-06 -6.5885 0.21576E-06 -6.6660 0.83643E+00 -0.0776 6 HS- 0.27473E-04 -4.5611 0.22949E-04 -4.6392 0.83533E+00 -0.0781 7 Al+++ 0.96869E-29 -29.0138 0.22382E-29 -29.6501 0.23106E+00 -0.6363 8 H4SiO4 0.69589E-03 -3.1575 0.69589E-03 -3.1575 0.10000E+01 0.0000 9 Ca++ 0.13494E-06 -6.8698 0.69566E-07 -7.1576 0.51552E+00 -0.2878 10 Mg++ 0.21111E-10 -10.6755 0.10834E-10 -10.9652 0.51316E+00 -0.2897 11 Fe++ 0.58181E-13 -13.2352 0.29889E-13 -13.5245 0.51373E+00 -0.2893 12 K+ 0.15648E-03 -3.8055 0.13092E-03 -3.8830 0.83663E+00 -0.0775 13 Na+ 0.19857E-01 -1.7021 0.16582E-01 -1.7804 0.83506E+00 -0.0783 14 Mn++ 0.18462E-10 -10.7337 0.94925E-11 -11.0226 0.51415E+00 -0.2889 15 HPO4-- 0.45325E-07 -7.3437 0.23542E-07 -7.6282 0.51941E+00 -0.2845 16 HSiO3- 0.10489E-01 -1.9793 0.87601E-02 -2.0575 0.83521E+00 -0.0782 17 Ca(HSiO3)+ 0.16585E-07 -7.7803 0.13879E-07 -7.8577 0.83681E+00 -0.0774 18 Mg(HSiO3)+ 0.32143E-11 -11.4929 0.26898E-11 -11.5703 0.83681E+00 -0.0774 19 NaHSiO3,aq 0.23493E-02 -2.6291 0.23493E-02 -2.6291 0.10000E+01 0.0000 20 AlO+ 0.66137E-16 -16.1796 0.55344E-16 -16.2569 0.83681E+00 -0.0774 22 HAlO2,aq 0.14859E-09 -9.8280 0.14859E-09 -9.8280 0.10000E+01 0.0000 23 AlO2- 0.53189E-05 -5.2742 0.44344E-05 -5.3532 0.83370E+00 -0.0790 24 CH4,aq 0.13333E-04 -4.8751 0.13287E-04 -4.8766 0.99655E+00 -0.0015 25 C2H6,aq 0.26140E-14 -14.5827 0.26049E-14 -14.5842 0.99655E+00 -0.0015 29 CO,aq 0.99529E-17 -17.0020 0.99529E-17 -17.0020 0.10000E+01 0.0000 30 CO2,aq 0.34315E-10 -10.4645 0.34196E-10 -10.4660 0.99655E+00 -0.0015 31 CO3-2 0.49026E-06 -6.3096 0.25407E-06 -6.5950 0.51823E+00 -0.2855 32 CaCO3,aq 0.22162E-09 -9.6544 0.22162E-09 -9.6544 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.45785E-12 -12.3393 0.38313E-12 -12.4167 0.83681E+00 -0.0774 34 CaCl+ 0.16627E-10 -10.7792 0.13914E-10 -10.8566 0.83681E+00 -0.0774 35 CaCl2,aq 0.40853E-15 -15.3888 0.40853E-15 -15.3888 0.10000E+01 0.0000 36 CaOH+ 0.79877E-07 -7.0976 0.66842E-07 -7.1750 0.83681E+00 -0.0774 37 CaSO4,aq 0.79965E-17 -17.0971 0.79965E-17 -17.0971 0.10000E+01 0.0000 38 HCl,aq 0.16798E-14 -14.7747 0.16798E-14 -14.7747 0.10000E+01 0.0000 43 FeCl+ 0.69871E-17 -17.1557 0.58469E-17 -17.2331 0.83681E+00 -0.0774 46 FeO,aq 0.21114E-09 -9.6754 0.21114E-09 -9.6754 0.10000E+01 0.0000 47 FeOH+ 0.15674E-10 -10.8048 0.13117E-10 -10.8822 0.83681E+00 -0.0774 48 HFeO2- 0.35659E-07 -7.4478 0.29783E-07 -7.5260 0.83521E+00 -0.0782 49 FeO+ 0.10984E-16 -16.9592 0.91913E-17 -17.0366 0.83681E+00 -0.0774 51 FeO2- 0.40928E-09 -9.3880 0.34183E-09 -9.4662 0.83521E+00 -0.0782 52 HFeO2,aq 0.32248E-11 -11.4915 0.32248E-11 -11.4915 0.10000E+01 0.0000 53 H2,aq 0.11626E-04 -4.9346 0.11586E-04 -4.9361 0.99655E+00 -0.0015 54 KCl,aq 0.29325E-09 -9.5328 0.29325E-09 -9.5328 0.10000E+01 0.0000 56 KOH,aq 0.75375E-06 -6.1228 0.75375E-06 -6.1228 0.10000E+01 0.0000 57 KSO4- 0.88049E-15 -15.0553 0.73539E-15 -15.1335 0.83521E+00 -0.0782 58 MgCO3,aq 0.86509E-14 -14.0629 0.86509E-14 -14.0629 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.72856E-16 -16.1375 0.60967E-16 -16.2149 0.83681E+00 -0.0774 60 MgCl+ 0.23468E-14 -14.6295 0.19638E-14 -14.7069 0.83681E+00 -0.0774 61 MgOH+ 0.68832E-10 -10.1622 0.57599E-10 -10.2396 0.83681E+00 -0.0774 63 MnO,aq 0.17867E-08 -8.7479 0.17867E-08 -8.7479 0.10000E+01 0.0000 64 MnOH+ 0.46245E-09 -9.3349 0.38698E-09 -9.4123 0.83681E+00 -0.0774 65 MnO2-2 0.20797E-10 -10.6820 0.10777E-10 -10.9675 0.51823E+00 -0.2855 66 HMnO2- 0.20970E-09 -9.6784 0.17514E-09 -9.7566 0.83521E+00 -0.0782 69 MnCl+ 0.86331E-14 -14.0638 0.72242E-14 -14.1412 0.83681E+00 -0.0774 71 NaCl,aq 0.67914E-06 -6.1680 0.67914E-06 -6.1680 0.10000E+01 0.0000 72 NaOH,aq 0.96047E-04 -4.0175 0.96047E-04 -4.0175 0.10000E+01 0.0000 74 OH- 0.93431E-02 -2.0295 0.77894E-02 -2.1085 0.83370E+00 -0.0790 79 HPO3-2 0.16402E-14 -14.7851 0.85002E-15 -15.0706 0.51823E+00 -0.2855 81 H2PO3- 0.15138E-18 -18.8199 0.12643E-18 -18.8981 0.83521E+00 -0.0782 82 H3PO4,aq 0.90590E-18 -18.0429 0.90590E-18 -18.0429 0.10000E+01 0.0000 83 H2PO4- 0.38533E-10 -10.4142 0.32213E-10 -10.4920 0.83600E+00 -0.0778 84 PO4-3 0.10671E-08 -8.9718 0.25895E-09 -9.5868 0.24268E+00 -0.6150 88 HP2O7-3 0.94702E-18 -18.0236 0.21904E-18 -18.6595 0.23129E+00 -0.6358 89 P2O7-4 0.91470E-17 -17.0387 0.70545E-18 -18.1515 0.77123E-01 -1.1128 90 H2S,aq 0.52792E-08 -8.2774 0.52610E-08 -8.2789 0.99655E+00 -0.0015 91 S2-2 0.19436E-14 -14.7114 0.10072E-14 -14.9969 0.51823E+00 -0.2855 97 SO3-2 0.10367E-17 -17.9844 0.54501E-18 -18.2636 0.52573E+00 -0.2792 99 HSO4- 0.30892E-19 -19.5101 0.25876E-19 -19.5871 0.83762E+00 -0.0770 Charge balance for all species = -.1709E-10 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.8827588E-10 -.2230264E-01 -.2244066E+02 0.0000 2 H2O 0.1000000E+01 0.5550489E+02 0.9981997E+06 0.0000 3 Cl- 0.1479726E-03 0.1486521E-03 0.5261006E+01 6.2217 4 SO4-- 0.6970251E-12 -.1623953E-04 -.1557285E+01 7.8182 5 HCO3- 0.2579507E-06 0.1408150E-04 0.8577206E+00 3.4637 6 HS- 0.2747300E-04 0.4371781E-04 0.1443323E+01 5.4905 7 Al+++ 0.9686915E-29 0.5319032E-05 0.1432661E+00 0.7391 8 H4SiO4 0.6958891E-03 0.1353378E-01 0.1298544E+04 -3.1575 9 Ca++ 0.1349435E-06 0.2316440E-06 0.9267697E-02 13.1019 10 Mg++ 0.2111119E-10 0.9316861E-10 0.2261179E-05 9.2943 11 Fe++ 0.5818079E-13 0.3629866E-07 0.2023649E-02 6.7350 12 K+ 0.1564831E-03 0.1572371E-03 0.6137603E+01 6.2467 13 Na+ 0.1985690E-01 0.2230297E-01 0.5118499E+03 8.3494 14 Mn++ 0.1846241E-10 0.2498144E-08 0.1370046E-03 9.2369 15 HPO4-- 0.4532507E-07 0.4643067E-07 0.4448626E-02 12.6313 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.1159093E+02 -.2070060E-01 -.1157023E+02 0.0000000E+00 2 H2O 0.4673348E+02 0.5151788E+02 -.4784406E+01 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.1942486E-01 -.1507302E-04 0.1943994E-01 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.1939936E-01 0.4057749E-04 -.1943994E-01 0.0000000E+00 7 Al+++ 0.2282516E+01 0.4936957E-05 0.2282511E+01 0.0000000E+00 8 H4SiO4 0.7288938E+01 0.1256163E-01 0.7276376E+01 0.0000000E+00 9 Ca++ 0.8051132E+00 0.2150046E-06 0.8051130E+00 0.0000000E+00 10 Mg++ 0.5555548E+00 0.8647616E-10 0.5555548E+00 0.0000000E+00 11 Fe++ 0.4991053E+00 0.3369127E-07 0.4991053E+00 0.0000000E+00 12 K+ 0.1486197E+00 0.1459425E-03 0.1484738E+00 0.0000000E+00 13 Na+ 0.8788294E+00 0.2070091E-01 0.8581284E+00 0.0000000E+00 14 Mn++ 0.1213700E-01 0.2318698E-08 0.1213700E-01 0.0000000E+00 15 HPO4-- 0.4142298E-02 0.4309548E-07 0.4142255E-02 0.0000000E+00 Chg. balance for solid moles: -.1887E-14 Mass of aqueous solution: 0.929784E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 699.9990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 0.8573 -0.067 224.8 2.352 29.40 86.30 andradite 0.7776E-01 -1.109 39.52 1.597 5.168 10.27 grossular 0.1884E-01 -1.725 8.486 0.929 1.110 2.361 apatite-OH 0.1381E-02 -2.860 0.6936 -0.159 0.9072E-01 0.2204 clinochlore 0.1005 -0.998 55.88 1.747 7.309 21.26 daphnite 0.2910E-01 -1.536 20.77 1.317 2.716 6.293 chlorite-Mn 0.2427E-02 -2.615 1.721 0.236 0.2251 0.5484 diopside 0.2881E-01 -1.540 6.240 0.795 0.8161 1.907 hedenbergite 0.7472E-02 -2.127 1.854 0.268 0.2425 0.5077 microcline 0.1302 -0.885 36.25 1.559 4.742 14.16 stilbite 0.4589 -0.338 323.4 2.510 42.30 150.8 stilpnomelane-Fe 0.3646E-01 -1.438 39.31 1.594 5.141 13.58 tr.625ac.25prg.125 0.6631E-02 -2.178 5.668 0.753 0.7413 1.824 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8050E+00 0.8050E+00 1.0000 -0.094 grossular 0.1950E+00 0.1950E+00 1.0000 -0.710 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.7613E+00 0.7613E+00 1.0000 -0.118 daphnite 0.2204E+00 0.2204E+00 1.0000 -0.657 chlorite-Mn 0.1838E-01 0.1838E-01 1.0000 -1.736 diopside 0.7941E+00 0.7941E+00 1.0000 -0.100 hedenbergite 0.2059E+00 0.2059E+00 1.0000 -0.686 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 tr.625ac.25prg.125 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 764.559329 g Volume = 310.046100 cm3 Porosity: -10.3368% V(tot) - V(min): -.29046E+02 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 699.9990000 g log = 2.8451 Original solution: 1000.0103000 g Original solution / Rock added: 1.43 (Water/Rock Ratio), log = 0.1549 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0553 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9673E+00 0.9855 0.1006E+01 0.1021E+01 CO2,gas 0.3443E-08 1.0069 0.3659E-08 0.3633E-08 CH4,gas 0.1830E-01 1.0125 0.1956E-01 0.1932E-01 H2,gas 0.1441E-01 1.0006 0.1521E-01 0.1520E-01 H2S,gas 0.1376E-06 0.9959 0.1446E-06 0.1452E-06 S2,gas 0.3215E-29 1.0000 0.3393E-29 0.3393E-29 CO,gas 0.1405E-13 1.0000 0.1483E-13 0.1483E-13 SO3,gas 0.7136E-48 1.0000 0.7530E-48 0.7530E-48 SO2,gas 0.4223E-27 1.0000 0.4456E-27 0.4456E-27 HCl,gas 0.2809E-17 1.0000 0.2964E-17 0.2964E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 16 albite -0.38 -0.38 0.00 0.000 -0.94784E-12 22 andradite 39.01 39.01 0.00 0.000 0.00000E+00 23 grossular 32.73 32.73 0.00 0.000 -0.12132E-10 32 apatite-OH -18.15 -18.15 0.00 0.000 0.00000E+00 46 clinochlore 39.07 39.07 0.00 0.000 0.12132E-10 47 daphnite 28.97 28.97 0.00 0.000 0.18198E-10 48 chlorite-Mn 46.87 46.87 0.00 0.000 -0.24265E-10 67 diopside 16.18 16.18 0.00 0.000 0.00000E+00 68 hedenbergite 14.21 14.21 0.00 0.000 0.00000E+00 116 microcline -2.49 -2.49 0.00 0.000 0.15165E-11 163 stilbite -7.52 -7.52 0.00 0.000 0.15165E-10 164 stilpnomelane-Fe 13.02 13.02 0.00 0.000 0.21232E-10 245 tr.625ac.25prg.125 45.16 45.16 0.00 0.000 -0.24265E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -16.80 -10.14 -3.379 0.17306E+05 -8.437 3 CH4,gas 4.54 1.14 -3.41 -0.852 0.58185E+04 -1.709 4 H2,gas 8.00 4.48 -3.52 -2.010 0.60049E+04 -1.818 5 H2S,gas -6.23 -14.77 -8.54 -4.269 0.14580E+05 -6.840 6 S2,gas -7.34 -38.50 -31.17 -4.795 0.53219E+05 -29.469 7 CO,gas 3.21 -12.31 -15.53 -4.778 0.26513E+05 -13.829 8 SO3,gas 17.12 -32.70 -49.82 -12.456 0.85070E+05 -48.123 9 SO2,gas 0.83 -28.22 -29.05 -7.747 0.49602E+05 -27.351 10 HCl,gas 5.19 -14.04 -19.23 -9.614 0.32830E+05 -17.528 11 acmite 7.71 6.53 -1.18 -0.123 0.20178E+04 15 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 19 spessartine 24.46 19.72 -4.74 -0.237 0.80948E+04 20 analcite 3.32 2.77 -0.55 -0.061 0.93615E+03 26 annite 20.12 17.72 -2.40 -0.134 0.41063E+04 27 phlogopite 27.06 25.40 -1.67 -0.093 0.28486E+04 29 anorthite 12.71 8.27 -4.45 -0.342 0.75898E+04 35 aragonite 0.97 -3.69 -4.66 -1.553 0.79575E+04 36 brucite 12.57 9.29 -3.27 -0.655 0.55908E+04 37 calcite 0.81 -3.69 -4.51 -1.502 0.76933E+04 38 carnegieite-low 9.02 5.93 -3.09 -0.442 0.52799E+04 39 carnegieite-high 10.09 5.93 -4.16 -0.595 0.71069E+04 40 carpholite-Mg 8.58 4.46 -4.12 -0.275 0.70424E+04 41 carpholite-Fe 6.71 1.90 -4.81 -0.321 0.82202E+04 42 celadonite 5.34 3.65 -1.69 -0.099 0.28878E+04 43 celadonite-Fe 3.88 1.09 -2.79 -0.164 0.47561E+04 44 chrysotile 23.89 21.57 -2.32 -0.194 0.39691E+04 49 chlorite-Al-free 47.17 43.14 -4.04 -0.168 0.68933E+04 51 chloritoid-Fe 9.17 5.06 -4.12 -0.275 0.70310E+04 52 chloritoid-Mn 11.40 7.56 -3.84 -0.256 0.65625E+04 54 coesite -2.38 -3.16 -0.78 -0.260 0.13342E+04 61 cristobalite -2.56 -3.16 -0.60 -0.199 0.10196E+04 63 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71234E+04 65 diaspore 2.87 0.74 -2.13 -0.356 0.36447E+04 66 diamond -3.10 -7.83 -4.73 -1.351 0.80720E+04 71 enstatite 17.26 12.27 -4.99 -0.499 0.85225E+04 73 clinoenstatite 17.17 12.27 -4.89 -0.489 0.83541E+04 75 epidote 24.67 22.70 -1.97 -0.095 0.33581E+04 76 clinozoisite 22.81 18.95 -3.86 -0.175 0.65861E+04 77 epidote-Fe 29.84 26.46 -3.38 -0.176 0.57768E+04 78 fayalite 14.05 10.31 -3.73 -0.533 0.63743E+04 79 ferrosilite 11.15 7.16 -3.99 -0.399 0.68203E+04 83 gibbsite 4.08 0.74 -3.34 -0.477 0.57032E+04 84 glaucophane 22.97 20.80 -2.17 -0.059 0.37132E+04 85 glaucophane-Fe 17.28 13.12 -4.15 -0.112 0.70919E+04 86 graphite -3.55 -7.83 -4.28 -1.224 0.73143E+04 87 greenalite 16.14 13.89 -2.25 -0.187 0.38408E+04 90 hematite 12.57 8.99 -3.58 -0.434 0.61113E+04 91 heulandite -5.83 -7.52 -1.69 -0.077 0.28938E+04 95 jadeite 4.22 2.77 -1.44 -0.144 0.24616E+04 97 kalsilite 7.58 3.83 -3.76 -0.536 0.64124E+04 98 kaolinite -1.33 -4.84 -3.50 -0.319 0.59828E+04 101 laumontite 2.88 1.95 -0.93 -0.062 0.15932E+04 102 lawsonite 9.62 8.27 -1.35 -0.090 0.23065E+04 103 leucite 4.12 0.67 -3.45 -0.345 0.58872E+04 105 lizardite 23.24 21.57 -1.68 -0.140 0.28617E+04 107 magnetite 20.09 15.72 -4.37 -0.356 0.74537E+04 108 minnesotaite 10.39 7.58 -2.81 -0.165 0.48030E+04 112 manganosite 14.06 9.24 -4.82 -1.205 0.82321E+04 120 muscovite 2.58 -1.01 -3.59 -0.211 0.61309E+04 121 paragonite 4.24 1.09 -3.15 -0.185 0.53700E+04 122 nepheline 8.34 5.93 -2.41 -0.344 0.41123E+04 128 periclase-Fe 11.63 6.73 -4.89 -1.223 0.83522E+04 134 phlogopite-Na 29.65 27.50 -2.15 -0.119 0.36674E+04 136 prehnite 19.37 18.21 -1.16 -0.068 0.19844E+04 137 prehnite-Fe 22.50 21.96 -0.53 -0.032 0.91146E+03 138 pumpellyite-Fe 46.27 43.89 -2.38 -0.053 0.40568E+04 139 pumpellyite-Mg 48.99 46.45 -2.54 -0.056 0.43406E+04 143 pyrrhotite -4.26 -8.03 -3.77 -1.258 0.64434E+04 144 pyrrhotiteFe0.875 -6.02 -9.43 -3.41 -1.256 0.58307E+04 145 pyroxmangite 7.40 6.08 -1.32 -0.264 0.22526E+04 146 pyrophyllite -6.18 -11.15 -4.98 -0.311 0.84960E+04 147 quartz -2.99 -3.16 -0.17 -0.056 0.28690E+03 152 rhodonite 7.45 6.08 -1.37 -0.273 0.23329E+04 153 sanidine -1.28 -2.49 -1.21 -0.093 0.20677E+04 165 stilpnomelane-Mg 27.44 25.81 -1.63 -0.049 0.27800E+04 171 talc 16.49 15.25 -1.24 -0.073 0.21141E+04 174 tephroite 18.09 15.32 -2.77 -0.396 0.47289E+04 178 tridymite -2.63 -3.16 -0.53 -0.177 0.90687E+03 179 tremolite 47.87 47.42 -0.45 -0.012 0.77498E+03 180 ferroactinolite 38.45 34.62 -3.83 -0.104 0.65452E+04 181 troilite-low -4.41 -8.03 -3.62 -1.208 0.61862E+04 183 vesuvianite 223.47 218.82 -4.65 -0.035 0.79403E+04 187 wairakite 3.95 1.95 -2.00 -0.118 0.34152E+04 188 walstromite 11.51 9.94 -1.56 -0.313 0.26719E+04 189 wollastonite 10.46 9.94 -0.52 -0.103 0.88229E+03 190 pseudo-wollastonite 11.00 9.94 -1.06 -0.211 0.18021E+04 191 zoisite 22.85 18.95 -3.90 -0.177 0.66601E+04 192 akaganeite 7.75 4.49 -3.26 -0.705 0.55682E+04 199 chalcedony -2.80 -3.16 -0.36 -0.118 0.60619E+03 201 montmorillonite-Ca -2.29 -6.17 -3.88 -0.240 0.66179E+04 202 montmorillonite-K -2.24 -6.27 -4.03 -0.247 0.68815E+04 203 montmorillonite-Mg -2.48 -6.79 -4.31 -0.267 0.73676E+04 204 montmorillonite-Na -2.04 -5.57 -3.54 -0.216 0.60364E+04 205 nontronite-Ca 3.21 -0.20 -3.41 -0.221 0.58219E+04 206 nontronite-H 2.53 -2.36 -4.89 -0.328 0.83489E+04 207 nontronite-K 3.34 -0.30 -3.64 -0.233 0.62087E+04 208 nontronite-Mg 3.07 -0.82 -3.90 -0.253 0.66557E+04 209 nontronite-Na 3.52 0.40 -3.12 -0.200 0.53296E+04 224 tobermorite 9.82 7.76 -2.07 -0.564 0.35287E+04 230 alabandite -0.98 -5.53 -4.55 -1.518 0.77762E+04 233 boehmite 4.41 0.74 -3.67 -0.611 0.62616E+04 235 ferrous-oxide 9.81 6.73 -3.08 -0.769 0.52532E+04 240 silica-amorphous -2.09 -3.16 -1.07 -0.355 0.18204E+04 242 an20ab80 2.02 1.35 -0.67 -0.052 0.11471E+04 243 an25ab75 2.65 1.78 -0.87 -0.067 0.14809E+04 244 an30ab70 3.28 2.21 -1.07 -0.082 0.18242E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 20.0000000 g Current total amount of reactant added: 699.9990000 g New total amount of reactant added: 719.9990000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.1586E-10 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 11 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 719.9990000 Water: Moles liquid = 0.5141E+02 kg liquid = 0.9262E+00 Moles total = 0.4648E+02 kg total = 0.8374E+00 Activity = 1.0000 Stoichiometric ionic strength = .1132639E-01 Osmotic coef. = 0.9694 True ionic strength = .2001466E-01 Chg. balance for total moles = -.1586E-10 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.88277E-10 -10.0542 0.74176E-10 -10.1297 0.84026E+00 -0.0756 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.14829E-03 -3.8289 0.12386E-03 -3.9071 0.83521E+00 -0.0782 4 SO4-- 0.69856E-12 -12.1558 0.36278E-12 -12.4404 0.51933E+00 -0.2846 5 HCO3- 0.25852E-06 -6.5875 0.21623E-06 -6.6651 0.83643E+00 -0.0776 6 HS- 0.27533E-04 -4.5602 0.22999E-04 -4.6383 0.83533E+00 -0.0781 7 Al+++ 0.96872E-29 -29.0138 0.22383E-29 -29.6501 0.23106E+00 -0.6363 8 H4SiO4 0.69589E-03 -3.1575 0.69589E-03 -3.1575 0.10000E+01 0.0000 9 Ca++ 0.13495E-06 -6.8698 0.69568E-07 -7.1576 0.51552E+00 -0.2878 10 Mg++ 0.21112E-10 -10.6755 0.10834E-10 -10.9652 0.51316E+00 -0.2897 11 Fe++ 0.58182E-13 -13.2352 0.29890E-13 -13.5245 0.51372E+00 -0.2893 12 K+ 0.15648E-03 -3.8055 0.13092E-03 -3.8830 0.83663E+00 -0.0775 13 Na+ 0.19857E-01 -1.7021 0.16582E-01 -1.7804 0.83506E+00 -0.0783 14 Mn++ 0.18469E-10 -10.7335 0.94960E-11 -11.0225 0.51415E+00 -0.2889 15 HPO4-- 0.45325E-07 -7.3437 0.23542E-07 -7.6282 0.51941E+00 -0.2845 16 HSiO3- 0.10488E-01 -1.9793 0.87601E-02 -2.0575 0.83521E+00 -0.0782 17 Ca(HSiO3)+ 0.16585E-07 -7.7803 0.13879E-07 -7.8577 0.83681E+00 -0.0774 18 Mg(HSiO3)+ 0.32143E-11 -11.4929 0.26898E-11 -11.5703 0.83681E+00 -0.0774 19 NaHSiO3,aq 0.23493E-02 -2.6291 0.23493E-02 -2.6291 0.10000E+01 0.0000 20 AlO+ 0.66137E-16 -16.1796 0.55344E-16 -16.2569 0.83681E+00 -0.0774 22 HAlO2,aq 0.14859E-09 -9.8280 0.14859E-09 -9.8280 0.10000E+01 0.0000 23 AlO2- 0.53188E-05 -5.2742 0.44343E-05 -5.3532 0.83370E+00 -0.0790 24 CH4,aq 0.13362E-04 -4.8741 0.13316E-04 -4.8756 0.99655E+00 -0.0015 25 C2H6,aq 0.26253E-14 -14.5808 0.26163E-14 -14.5823 0.99655E+00 -0.0015 29 CO,aq 0.99748E-17 -17.0011 0.99748E-17 -17.0011 0.10000E+01 0.0000 30 CO2,aq 0.34391E-10 -10.4636 0.34272E-10 -10.4651 0.99655E+00 -0.0015 31 CO3-2 0.49134E-06 -6.3086 0.25463E-06 -6.5941 0.51823E+00 -0.2855 32 CaCO3,aq 0.22211E-09 -9.6534 0.22211E-09 -9.6534 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.45886E-12 -12.3383 0.38398E-12 -12.4157 0.83681E+00 -0.0774 34 CaCl+ 0.16663E-10 -10.7782 0.13944E-10 -10.8556 0.83681E+00 -0.0774 35 CaCl2,aq 0.41031E-15 -15.3869 0.41031E-15 -15.3869 0.10000E+01 0.0000 36 CaOH+ 0.79877E-07 -7.0976 0.66842E-07 -7.1750 0.83681E+00 -0.0774 37 CaSO4,aq 0.80142E-17 -17.0961 0.80142E-17 -17.0961 0.10000E+01 0.0000 38 HCl,aq 0.16835E-14 -14.7738 0.16835E-14 -14.7738 0.10000E+01 0.0000 43 FeCl+ 0.70024E-17 -17.1548 0.58597E-17 -17.2321 0.83681E+00 -0.0774 46 FeO,aq 0.21114E-09 -9.6754 0.21114E-09 -9.6754 0.10000E+01 0.0000 47 FeOH+ 0.15675E-10 -10.8048 0.13117E-10 -10.8822 0.83681E+00 -0.0774 48 HFeO2- 0.35659E-07 -7.4478 0.29783E-07 -7.5260 0.83521E+00 -0.0782 49 FeO+ 0.10984E-16 -16.9592 0.91914E-17 -17.0366 0.83681E+00 -0.0774 51 FeO2- 0.40927E-09 -9.3880 0.34183E-09 -9.4662 0.83521E+00 -0.0782 52 HFeO2,aq 0.32248E-11 -11.4915 0.32248E-11 -11.4915 0.10000E+01 0.0000 53 H2,aq 0.11626E-04 -4.9346 0.11586E-04 -4.9361 0.99655E+00 -0.0015 54 KCl,aq 0.29389E-09 -9.5318 0.29389E-09 -9.5318 0.10000E+01 0.0000 56 KOH,aq 0.75375E-06 -6.1228 0.75375E-06 -6.1228 0.10000E+01 0.0000 57 KSO4- 0.88243E-15 -15.0543 0.73702E-15 -15.1325 0.83521E+00 -0.0782 58 MgCO3,aq 0.86700E-14 -14.0620 0.86700E-14 -14.0620 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.73017E-16 -16.1366 0.61101E-16 -16.2139 0.83681E+00 -0.0774 60 MgCl+ 0.23519E-14 -14.6286 0.19681E-14 -14.7060 0.83681E+00 -0.0774 61 MgOH+ 0.68832E-10 -10.1622 0.57600E-10 -10.2396 0.83681E+00 -0.0774 63 MnO,aq 0.17874E-08 -8.7478 0.17874E-08 -8.7478 0.10000E+01 0.0000 64 MnOH+ 0.46261E-09 -9.3348 0.38712E-09 -9.4122 0.83681E+00 -0.0774 65 MnO2-2 0.20804E-10 -10.6819 0.10781E-10 -10.9673 0.51823E+00 -0.2855 66 HMnO2- 0.20977E-09 -9.6783 0.17520E-09 -9.7565 0.83521E+00 -0.0782 69 MnCl+ 0.86550E-14 -14.0627 0.72426E-14 -14.1401 0.83681E+00 -0.0774 71 NaCl,aq 0.68062E-06 -6.1671 0.68062E-06 -6.1671 0.10000E+01 0.0000 72 NaOH,aq 0.96047E-04 -4.0175 0.96047E-04 -4.0175 0.10000E+01 0.0000 74 OH- 0.93430E-02 -2.0295 0.77893E-02 -2.1085 0.83370E+00 -0.0790 79 HPO3-2 0.16402E-14 -14.7851 0.85000E-15 -15.0706 0.51823E+00 -0.2855 81 H2PO3- 0.15138E-18 -18.8199 0.12643E-18 -18.8981 0.83521E+00 -0.0782 82 H3PO4,aq 0.90591E-18 -18.0429 0.90591E-18 -18.0429 0.10000E+01 0.0000 83 H2PO4- 0.38533E-10 -10.4142 0.32213E-10 -10.4920 0.83600E+00 -0.0778 84 PO4-3 0.10671E-08 -8.9718 0.25895E-09 -9.5868 0.24268E+00 -0.6150 88 HP2O7-3 0.94701E-18 -18.0236 0.21903E-18 -18.6595 0.23129E+00 -0.6358 89 P2O7-4 0.91469E-17 -17.0387 0.70543E-18 -18.1515 0.77123E-01 -1.1128 90 H2S,aq 0.52907E-08 -8.2765 0.52725E-08 -8.2780 0.99655E+00 -0.0015 91 S2-2 0.19520E-14 -14.7095 0.10116E-14 -14.9950 0.51823E+00 -0.2855 97 SO3-2 0.10390E-17 -17.9834 0.54620E-18 -18.2626 0.52572E+00 -0.2792 99 HSO4- 0.30961E-19 -19.5092 0.25933E-19 -19.5861 0.83762E+00 -0.0770 Charge balance for all species = -.1713E-10 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.8827689E-10 -.2230250E-01 -.2244052E+02 0.0000 2 H2O 0.1000000E+01 0.5550489E+02 0.9981997E+06 0.0000 3 Cl- 0.1482935E-03 0.1489745E-03 0.5272415E+01 6.2227 4 SO4-- 0.6985580E-12 -.1626840E-04 -.1560053E+01 7.8191 5 HCO3- 0.2585172E-06 0.1411203E-04 0.8595807E+00 3.4647 6 HS- 0.2753258E-04 0.4380627E-04 0.1446244E+01 5.4914 7 Al+++ 0.9687173E-29 0.5318913E-05 0.1432629E+00 0.7391 8 H4SiO4 0.6958920E-03 0.1353373E-01 0.1298540E+04 -3.1575 9 Ca++ 0.1349462E-06 0.2316480E-06 0.9267858E-02 13.1019 10 Mg++ 0.2111161E-10 0.9316940E-10 0.2261198E-05 9.2943 11 Fe++ 0.5818212E-13 0.3629825E-07 0.2023626E-02 6.7350 12 K+ 0.1564849E-03 0.1572389E-03 0.6137673E+01 6.2467 13 Na+ 0.1985713E-01 0.2230321E-01 0.5118554E+03 8.3494 14 Mn++ 0.1846928E-10 0.2499016E-08 0.1370524E-03 9.2370 15 HPO4-- 0.4532455E-07 0.4643014E-07 0.4448575E-02 12.6313 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.1192210E+02 -.2065568E-01 -.1190145E+02 0.0000000E+00 2 H2O 0.4648277E+02 0.5140640E+02 -.4923631E+01 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.1997913E-01 -.1506714E-04 0.1999420E-01 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.1995363E-01 0.4057161E-04 -.1999420E-01 0.0000000E+00 7 Al+++ 0.2347731E+01 0.4926163E-05 0.2347726E+01 0.0000000E+00 8 H4SiO4 0.7497193E+01 0.1253440E-01 0.7484659E+01 0.0000000E+00 9 Ca++ 0.8281160E+00 0.2145431E-06 0.8281158E+00 0.0000000E+00 10 Mg++ 0.5714278E+00 0.8628975E-10 0.5714278E+00 0.0000000E+00 11 Fe++ 0.5133655E+00 0.3361798E-07 0.5133654E+00 0.0000000E+00 12 K+ 0.1528660E+00 0.1456284E-03 0.1527204E+00 0.0000000E+00 13 Na+ 0.9039342E+00 0.2065634E-01 0.8832779E+00 0.0000000E+00 14 Mn++ 0.1248377E-01 0.2314489E-08 0.1248377E-01 0.0000000E+00 15 HPO4-- 0.4260649E-02 0.4300173E-07 0.4260606E-02 0.0000000E+00 Chg. balance for solid moles: -.1733E-14 Mass of aqueous solution: 0.927772E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 719.9990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 0.8824 -0.054 231.4 2.364 29.42 88.83 andradite 0.7998E-01 -1.097 40.64 1.609 5.168 10.56 grossular 0.1937E-01 -1.713 8.727 0.941 1.110 2.428 apatite-OH 0.1420E-02 -2.848 0.7134 -0.147 0.9072E-01 0.2267 clinochlore 0.1034 -0.986 57.46 1.759 7.307 21.86 daphnite 0.2992E-01 -1.524 21.35 1.329 2.715 6.470 chlorite-Mn 0.2497E-02 -2.603 1.770 0.248 0.2251 0.5641 diopside 0.2990E-01 -1.524 6.475 0.811 0.8234 1.979 hedenbergite 0.7754E-02 -2.110 1.924 0.284 0.2446 0.5269 microcline 0.1340 -0.873 37.29 1.572 4.742 14.57 stilbite 0.4717 -0.326 332.4 2.522 42.27 155.0 stilpnomelane-Fe 0.3751E-01 -1.426 40.43 1.607 5.141 13.97 tr.625ac.25prg.125 0.6797E-02 -2.168 5.810 0.764 0.7388 1.870 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8050E+00 0.8050E+00 1.0000 -0.094 grossular 0.1950E+00 0.1950E+00 1.0000 -0.710 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.7613E+00 0.7613E+00 1.0000 -0.118 daphnite 0.2204E+00 0.2204E+00 1.0000 -0.657 chlorite-Mn 0.1839E-01 0.1839E-01 1.0000 -1.736 diopside 0.7941E+00 0.7941E+00 1.0000 -0.100 hedenbergite 0.2059E+00 0.2059E+00 1.0000 -0.686 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 tr.625ac.25prg.125 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 786.409460 g Volume = 318.886712 cm3 Porosity: -10.3416% V(tot) - V(min): -.29887E+02 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 719.9990000 g log = 2.8573 Original solution: 1000.0103000 g Original solution / Rock added: 1.39 (Water/Rock Ratio), log = 0.1427 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0553 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9673E+00 0.9855 0.1006E+01 0.1021E+01 CO2,gas 0.3451E-08 1.0069 0.3667E-08 0.3641E-08 CH4,gas 0.1834E-01 1.0125 0.1960E-01 0.1936E-01 H2,gas 0.1441E-01 1.0006 0.1521E-01 0.1520E-01 H2S,gas 0.1379E-06 0.9959 0.1449E-06 0.1455E-06 S2,gas 0.3229E-29 1.0000 0.3408E-29 0.3408E-29 CO,gas 0.1408E-13 1.0000 0.1486E-13 0.1486E-13 SO3,gas 0.7151E-48 1.0000 0.7547E-48 0.7547E-48 SO2,gas 0.4232E-27 1.0000 0.4466E-27 0.4466E-27 HCl,gas 0.2815E-17 1.0000 0.2971E-17 0.2971E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 16 albite -0.38 -0.38 0.00 0.000 0.11184E-10 22 andradite 39.01 39.01 0.00 0.000 -0.24265E-10 23 grossular 32.73 32.73 0.00 0.000 0.00000E+00 32 apatite-OH -18.15 -18.15 0.00 0.000 0.00000E+00 46 clinochlore 39.07 39.07 0.00 0.000 0.12132E-10 47 daphnite 28.97 28.97 0.00 0.000 0.48529E-10 48 chlorite-Mn 46.87 46.87 0.00 0.000 0.24265E-10 67 diopside 16.18 16.18 0.00 0.000 0.60662E-11 68 hedenbergite 14.21 14.21 0.00 0.000 0.60662E-11 116 microcline -2.49 -2.49 0.00 0.000 0.13649E-10 163 stilbite -7.52 -7.52 0.00 0.000 0.15165E-10 164 stilpnomelane-Fe 13.02 13.02 0.00 0.000 -0.27298E-10 245 tr.625ac.25prg.125 45.16 45.16 0.00 0.000 -0.12132E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -16.79 -10.13 -3.378 0.17305E+05 -8.436 3 CH4,gas 4.54 1.14 -3.41 -0.852 0.58169E+04 -1.708 4 H2,gas 8.00 4.48 -3.52 -2.010 0.60049E+04 -1.818 5 H2S,gas -6.23 -14.77 -8.54 -4.269 0.14578E+05 -6.839 6 S2,gas -7.34 -38.50 -31.17 -4.795 0.53216E+05 -29.468 7 CO,gas 3.21 -12.31 -15.53 -4.777 0.26512E+05 -13.828 8 SO3,gas 17.12 -32.70 -49.82 -12.455 0.85068E+05 -48.122 9 SO2,gas 0.83 -28.22 -29.05 -7.746 0.49600E+05 -27.350 10 HCl,gas 5.19 -14.04 -19.23 -9.613 0.32828E+05 -17.527 11 acmite 7.71 6.53 -1.18 -0.123 0.20178E+04 15 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 19 spessartine 24.46 19.72 -4.74 -0.237 0.80941E+04 20 analcite 3.32 2.77 -0.55 -0.061 0.93616E+03 26 annite 20.12 17.72 -2.40 -0.134 0.41063E+04 27 phlogopite 27.06 25.40 -1.67 -0.093 0.28486E+04 29 anorthite 12.71 8.27 -4.45 -0.342 0.75898E+04 35 aragonite 0.97 -3.69 -4.66 -1.553 0.79559E+04 36 brucite 12.57 9.29 -3.27 -0.655 0.55908E+04 37 calcite 0.81 -3.69 -4.50 -1.502 0.76917E+04 38 carnegieite-low 9.02 5.93 -3.09 -0.442 0.52799E+04 39 carnegieite-high 10.09 5.93 -4.16 -0.595 0.71069E+04 40 carpholite-Mg 8.58 4.46 -4.12 -0.275 0.70424E+04 41 carpholite-Fe 6.71 1.90 -4.81 -0.321 0.82203E+04 42 celadonite 5.34 3.65 -1.69 -0.099 0.28878E+04 43 celadonite-Fe 3.88 1.09 -2.79 -0.164 0.47561E+04 44 chrysotile 23.89 21.57 -2.32 -0.194 0.39691E+04 49 chlorite-Al-free 47.17 43.14 -4.04 -0.168 0.68934E+04 51 chloritoid-Fe 9.17 5.06 -4.12 -0.275 0.70311E+04 52 chloritoid-Mn 11.40 7.56 -3.84 -0.256 0.65622E+04 54 coesite -2.38 -3.16 -0.78 -0.260 0.13342E+04 61 cristobalite -2.56 -3.16 -0.60 -0.199 0.10196E+04 63 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71234E+04 65 diaspore 2.87 0.74 -2.13 -0.356 0.36447E+04 66 diamond -3.10 -7.83 -4.73 -1.350 0.80704E+04 71 enstatite 17.26 12.27 -4.99 -0.499 0.85225E+04 73 clinoenstatite 17.17 12.27 -4.89 -0.489 0.83541E+04 75 epidote 24.67 22.70 -1.97 -0.095 0.33581E+04 76 clinozoisite 22.81 18.95 -3.86 -0.175 0.65861E+04 77 epidote-Fe 29.84 26.46 -3.38 -0.176 0.57768E+04 78 fayalite 14.05 10.31 -3.73 -0.533 0.63743E+04 79 ferrosilite 11.15 7.16 -3.99 -0.399 0.68203E+04 83 gibbsite 4.08 0.74 -3.34 -0.477 0.57033E+04 84 glaucophane 22.97 20.80 -2.17 -0.059 0.37132E+04 85 glaucophane-Fe 17.28 13.12 -4.15 -0.112 0.70919E+04 86 graphite -3.55 -7.83 -4.28 -1.224 0.73127E+04 87 greenalite 16.14 13.89 -2.25 -0.187 0.38408E+04 90 hematite 12.57 8.99 -3.58 -0.434 0.61113E+04 91 heulandite -5.83 -7.52 -1.69 -0.077 0.28938E+04 95 jadeite 4.22 2.77 -1.44 -0.144 0.24616E+04 97 kalsilite 7.58 3.83 -3.76 -0.536 0.64124E+04 98 kaolinite -1.33 -4.84 -3.50 -0.319 0.59828E+04 101 laumontite 2.88 1.95 -0.93 -0.062 0.15932E+04 102 lawsonite 9.62 8.27 -1.35 -0.090 0.23065E+04 103 leucite 4.12 0.67 -3.45 -0.345 0.58872E+04 105 lizardite 23.24 21.57 -1.68 -0.140 0.28617E+04 107 magnetite 20.09 15.72 -4.37 -0.356 0.74537E+04 108 minnesotaite 10.39 7.58 -2.81 -0.165 0.48030E+04 112 manganosite 14.06 9.24 -4.82 -1.205 0.82319E+04 120 muscovite 2.58 -1.01 -3.59 -0.211 0.61309E+04 121 paragonite 4.24 1.09 -3.15 -0.185 0.53701E+04 122 nepheline 8.34 5.93 -2.41 -0.344 0.41123E+04 128 periclase-Fe 11.63 6.73 -4.89 -1.223 0.83522E+04 134 phlogopite-Na 29.65 27.50 -2.15 -0.119 0.36674E+04 136 prehnite 19.37 18.21 -1.16 -0.068 0.19845E+04 137 prehnite-Fe 22.50 21.96 -0.53 -0.032 0.91146E+03 138 pumpellyite-Fe 46.27 43.89 -2.38 -0.053 0.40569E+04 139 pumpellyite-Mg 48.99 46.45 -2.54 -0.056 0.43407E+04 143 pyrrhotite -4.26 -8.03 -3.77 -1.258 0.64418E+04 144 pyrrhotiteFe0.875 -6.02 -9.43 -3.41 -1.256 0.58291E+04 145 pyroxmangite 7.40 6.08 -1.32 -0.264 0.22524E+04 146 pyrophyllite -6.18 -11.15 -4.98 -0.311 0.84960E+04 147 quartz -2.99 -3.16 -0.17 -0.056 0.28689E+03 152 rhodonite 7.45 6.08 -1.37 -0.273 0.23326E+04 153 sanidine -1.28 -2.49 -1.21 -0.093 0.20677E+04 165 stilpnomelane-Mg 27.44 25.81 -1.63 -0.049 0.27800E+04 171 talc 16.49 15.25 -1.24 -0.073 0.21141E+04 174 tephroite 18.09 15.32 -2.77 -0.396 0.47284E+04 178 tridymite -2.63 -3.16 -0.53 -0.177 0.90687E+03 179 tremolite 47.87 47.42 -0.45 -0.012 0.77498E+03 180 ferroactinolite 38.45 34.62 -3.83 -0.104 0.65452E+04 181 troilite-low -4.41 -8.03 -3.62 -1.207 0.61846E+04 183 vesuvianite 223.47 218.82 -4.65 -0.035 0.79404E+04 187 wairakite 3.95 1.95 -2.00 -0.118 0.34152E+04 188 walstromite 11.51 9.94 -1.56 -0.313 0.26719E+04 189 wollastonite 10.46 9.94 -0.52 -0.103 0.88229E+03 190 pseudo-wollastonite 11.00 9.94 -1.06 -0.211 0.18021E+04 191 zoisite 22.85 18.95 -3.90 -0.177 0.66602E+04 192 akaganeite 7.75 4.49 -3.26 -0.705 0.55682E+04 199 chalcedony -2.80 -3.16 -0.36 -0.118 0.60619E+03 201 montmorillonite-Ca -2.29 -6.17 -3.88 -0.240 0.66179E+04 202 montmorillonite-K -2.24 -6.27 -4.03 -0.247 0.68815E+04 203 montmorillonite-Mg -2.48 -6.79 -4.31 -0.267 0.73676E+04 204 montmorillonite-Na -2.04 -5.57 -3.54 -0.216 0.60364E+04 205 nontronite-Ca 3.21 -0.20 -3.41 -0.221 0.58219E+04 206 nontronite-H 2.53 -2.36 -4.89 -0.328 0.83489E+04 207 nontronite-K 3.34 -0.30 -3.64 -0.233 0.62087E+04 208 nontronite-Mg 3.07 -0.82 -3.90 -0.253 0.66557E+04 209 nontronite-Na 3.52 0.40 -3.12 -0.200 0.53296E+04 224 tobermorite 9.82 7.76 -2.07 -0.564 0.35287E+04 230 alabandite -0.98 -5.53 -4.55 -1.518 0.77744E+04 233 boehmite 4.41 0.74 -3.67 -0.611 0.62616E+04 235 ferrous-oxide 9.81 6.73 -3.08 -0.769 0.52532E+04 240 silica-amorphous -2.09 -3.16 -1.07 -0.355 0.18204E+04 242 an20ab80 2.02 1.35 -0.67 -0.052 0.11471E+04 243 an25ab75 2.65 1.78 -0.87 -0.067 0.14809E+04 244 an30ab70 3.28 2.21 -1.07 -0.082 0.18242E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 20.0000000 g Current total amount of reactant added: 719.9990000 g New total amount of reactant added: 739.9990000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.1586E-10 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 11 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 739.9990000 Water: Moles liquid = 0.5130E+02 kg liquid = 0.9242E+00 Moles total = 0.4623E+02 kg total = 0.8329E+00 Activity = 1.0000 Stoichiometric ionic strength = .1132667E-01 Osmotic coef. = 0.9694 True ionic strength = .2001489E-01 Chg. balance for total moles = -.1586E-10 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.88278E-10 -10.0541 0.74176E-10 -10.1297 0.84026E+00 -0.0756 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.14862E-03 -3.8279 0.12413E-03 -3.9061 0.83521E+00 -0.0782 4 SO4-- 0.70010E-12 -12.1548 0.36358E-12 -12.4394 0.51933E+00 -0.2846 5 HCO3- 0.25909E-06 -6.5866 0.21671E-06 -6.6641 0.83643E+00 -0.0776 6 HS- 0.27592E-04 -4.5592 0.23049E-04 -4.6374 0.83533E+00 -0.0781 7 Al+++ 0.96874E-29 -29.0138 0.22383E-29 -29.6501 0.23106E+00 -0.6363 8 H4SiO4 0.69589E-03 -3.1575 0.69589E-03 -3.1575 0.10000E+01 0.0000 9 Ca++ 0.13495E-06 -6.8698 0.69569E-07 -7.1576 0.51552E+00 -0.2878 10 Mg++ 0.21112E-10 -10.6755 0.10834E-10 -10.9652 0.51316E+00 -0.2897 11 Fe++ 0.58183E-13 -13.2352 0.29890E-13 -13.5245 0.51372E+00 -0.2893 12 K+ 0.15649E-03 -3.8055 0.13092E-03 -3.8830 0.83663E+00 -0.0775 13 Na+ 0.19857E-01 -1.7021 0.16582E-01 -1.7804 0.83506E+00 -0.0783 14 Mn++ 0.18476E-10 -10.7334 0.94993E-11 -11.0223 0.51415E+00 -0.2889 15 HPO4-- 0.45324E-07 -7.3437 0.23541E-07 -7.6282 0.51940E+00 -0.2845 16 HSiO3- 0.10488E-01 -1.9793 0.87600E-02 -2.0575 0.83521E+00 -0.0782 17 Ca(HSiO3)+ 0.16585E-07 -7.7803 0.13879E-07 -7.8576 0.83681E+00 -0.0774 18 Mg(HSiO3)+ 0.32144E-11 -11.4929 0.26898E-11 -11.5703 0.83681E+00 -0.0774 19 NaHSiO3,aq 0.23494E-02 -2.6291 0.23494E-02 -2.6291 0.10000E+01 0.0000 20 AlO+ 0.66137E-16 -16.1796 0.55344E-16 -16.2569 0.83681E+00 -0.0774 22 HAlO2,aq 0.14859E-09 -9.8280 0.14859E-09 -9.8280 0.10000E+01 0.0000 23 AlO2- 0.53186E-05 -5.2742 0.44342E-05 -5.3532 0.83370E+00 -0.0790 24 CH4,aq 0.13391E-04 -4.8732 0.13345E-04 -4.8747 0.99655E+00 -0.0015 25 C2H6,aq 0.26368E-14 -14.5789 0.26277E-14 -14.5804 0.99655E+00 -0.0015 29 CO,aq 0.99967E-17 -17.0001 0.99967E-17 -17.0001 0.10000E+01 0.0000 30 CO2,aq 0.34467E-10 -10.4626 0.34348E-10 -10.4641 0.99655E+00 -0.0015 31 CO3-2 0.49241E-06 -6.3077 0.25518E-06 -6.5931 0.51823E+00 -0.2855 32 CaCO3,aq 0.22260E-09 -9.6525 0.22260E-09 -9.6525 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.45988E-12 -12.3374 0.38483E-12 -12.4147 0.83681E+00 -0.0774 34 CaCl+ 0.16700E-10 -10.7773 0.13975E-10 -10.8547 0.83681E+00 -0.0774 35 CaCl2,aq 0.41210E-15 -15.3850 0.41210E-15 -15.3850 0.10000E+01 0.0000 36 CaOH+ 0.79878E-07 -7.0976 0.66842E-07 -7.1749 0.83681E+00 -0.0774 37 CaSO4,aq 0.80320E-17 -17.0952 0.80320E-17 -17.0952 0.10000E+01 0.0000 38 HCl,aq 0.16872E-14 -14.7728 0.16872E-14 -14.7728 0.10000E+01 0.0000 43 FeCl+ 0.70177E-17 -17.1538 0.58725E-17 -17.2312 0.83681E+00 -0.0774 46 FeO,aq 0.21114E-09 -9.6754 0.21114E-09 -9.6754 0.10000E+01 0.0000 47 FeOH+ 0.15675E-10 -10.8048 0.13117E-10 -10.8822 0.83681E+00 -0.0774 48 HFeO2- 0.35658E-07 -7.4478 0.29782E-07 -7.5260 0.83521E+00 -0.0782 49 FeO+ 0.10984E-16 -16.9592 0.91916E-17 -17.0366 0.83681E+00 -0.0774 51 FeO2- 0.40927E-09 -9.3880 0.34183E-09 -9.4662 0.83521E+00 -0.0782 52 HFeO2,aq 0.32248E-11 -11.4915 0.32248E-11 -11.4915 0.10000E+01 0.0000 53 H2,aq 0.11626E-04 -4.9346 0.11586E-04 -4.9361 0.99655E+00 -0.0015 54 KCl,aq 0.29453E-09 -9.5309 0.29453E-09 -9.5309 0.10000E+01 0.0000 56 KOH,aq 0.75375E-06 -6.1228 0.75375E-06 -6.1228 0.10000E+01 0.0000 57 KSO4- 0.88438E-15 -15.0534 0.73864E-15 -15.1316 0.83521E+00 -0.0782 58 MgCO3,aq 0.86891E-14 -14.0610 0.86891E-14 -14.0610 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.73179E-16 -16.1356 0.61237E-16 -16.2130 0.83681E+00 -0.0774 60 MgCl+ 0.23571E-14 -14.6276 0.19724E-14 -14.7050 0.83681E+00 -0.0774 61 MgOH+ 0.68833E-10 -10.1622 0.57600E-10 -10.2396 0.83681E+00 -0.0774 63 MnO,aq 0.17879E-08 -8.7476 0.17879E-08 -8.7476 0.10000E+01 0.0000 64 MnOH+ 0.46277E-09 -9.3346 0.38725E-09 -9.4120 0.83681E+00 -0.0774 65 MnO2-2 0.20810E-10 -10.6817 0.10784E-10 -10.9672 0.51823E+00 -0.2855 66 HMnO2- 0.20983E-09 -9.6781 0.17525E-09 -9.7563 0.83521E+00 -0.0782 69 MnCl+ 0.86768E-14 -14.0616 0.72609E-14 -14.1390 0.83681E+00 -0.0774 71 NaCl,aq 0.68211E-06 -6.1661 0.68211E-06 -6.1661 0.10000E+01 0.0000 72 NaOH,aq 0.96047E-04 -4.0175 0.96047E-04 -4.0175 0.10000E+01 0.0000 74 OH- 0.93429E-02 -2.0295 0.77892E-02 -2.1085 0.83370E+00 -0.0790 79 HPO3-2 0.16402E-14 -14.7851 0.84998E-15 -15.0706 0.51823E+00 -0.2855 81 H2PO3- 0.15138E-18 -18.8199 0.12643E-18 -18.8981 0.83521E+00 -0.0782 82 H3PO4,aq 0.90592E-18 -18.0429 0.90592E-18 -18.0429 0.10000E+01 0.0000 83 H2PO4- 0.38532E-10 -10.4142 0.32213E-10 -10.4920 0.83600E+00 -0.0778 84 PO4-3 0.10670E-08 -8.9718 0.25894E-09 -9.5868 0.24267E+00 -0.6150 88 HP2O7-3 0.94699E-18 -18.0237 0.21903E-18 -18.6595 0.23129E+00 -0.6358 89 P2O7-4 0.91467E-17 -17.0387 0.70541E-18 -18.1516 0.77122E-01 -1.1128 90 H2S,aq 0.53023E-08 -8.2755 0.52840E-08 -8.2770 0.99655E+00 -0.0015 91 S2-2 0.19606E-14 -14.7076 0.10160E-14 -14.9931 0.51823E+00 -0.2855 97 SO3-2 0.10412E-17 -17.9825 0.54740E-18 -18.2617 0.52572E+00 -0.2792 99 HSO4- 0.31029E-19 -19.5082 0.25991E-19 -19.5852 0.83762E+00 -0.0770 Charge balance for all species = -.1716E-10 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.8827790E-10 -.2230235E-01 -.2244037E+02 0.0000 2 H2O 0.1000000E+01 0.5550489E+02 0.9981997E+06 0.0000 3 Cl- 0.1486158E-03 0.1492983E-03 0.5283874E+01 6.2236 4 SO4-- 0.7000961E-12 -.1629740E-04 -.1562834E+01 7.8201 5 HCO3- 0.2590858E-06 0.1414271E-04 0.8614488E+00 3.4656 6 HS- 0.2759242E-04 0.4389512E-04 0.1449177E+01 5.4924 7 Al+++ 0.9687437E-29 0.5318797E-05 0.1432598E+00 0.7391 8 H4SiO4 0.6958947E-03 0.1353368E-01 0.1298535E+04 -3.1575 9 Ca++ 0.1349490E-06 0.2316521E-06 0.9268021E-02 13.1019 10 Mg++ 0.2111204E-10 0.9317054E-10 0.2261226E-05 9.2943 11 Fe++ 0.5818345E-13 0.3629783E-07 0.2023603E-02 6.7350 12 K+ 0.1564866E-03 0.1572407E-03 0.6137742E+01 6.2467 13 Na+ 0.1985736E-01 0.2230345E-01 0.5118608E+03 8.3494 14 Mn++ 0.1847582E-10 0.2499843E-08 0.1370977E-03 9.2372 15 HPO4-- 0.4532402E-07 0.4642959E-07 0.4448522E-02 12.6313 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.1225327E+02 -.2061075E-01 -.1223266E+02 0.0000000E+00 2 H2O 0.4623206E+02 0.5129492E+02 -.5062856E+01 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.2053340E-01 -.1506126E-04 0.2054846E-01 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.2050789E-01 0.4056573E-04 -.2054846E-01 0.0000000E+00 7 Al+++ 0.2412946E+01 0.4915374E-05 0.2412941E+01 0.0000000E+00 8 H4SiO4 0.7705449E+01 0.1250717E-01 0.7692942E+01 0.0000000E+00 9 Ca++ 0.8511189E+00 0.2140816E-06 0.8511187E+00 0.0000000E+00 10 Mg++ 0.5873008E+00 0.8610368E-10 0.5873008E+00 0.0000000E+00 11 Fe++ 0.5276256E+00 0.3354469E-07 0.5276256E+00 0.0000000E+00 12 K+ 0.1571123E+00 0.1453142E-03 0.1569670E+00 0.0000000E+00 13 Na+ 0.9290391E+00 0.2061176E-01 0.9084273E+00 0.0000000E+00 14 Mn++ 0.1283054E-01 0.2310233E-08 0.1283054E-01 0.0000000E+00 15 HPO4-- 0.4379001E-02 0.4290796E-07 0.4378958E-02 0.0000000E+00 Chg. balance for solid moles: 0.1313E-14 Mass of aqueous solution: 0.925760E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 739.9990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 0.9076 -0.042 238.0 2.377 29.44 91.35 andradite 0.8219E-01 -1.085 41.77 1.621 5.168 10.85 grossular 0.1991E-01 -1.701 8.969 0.953 1.110 2.496 apatite-OH 0.1460E-02 -2.836 0.7332 -0.135 0.9072E-01 0.2330 clinochlore 0.1062 -0.974 59.04 1.771 7.304 22.46 daphnite 0.3075E-01 -1.512 21.94 1.341 2.714 6.648 chlorite-Mn 0.2566E-02 -2.591 1.819 0.260 0.2251 0.5798 diopside 0.3099E-01 -1.509 6.711 0.827 0.8303 2.051 hedenbergite 0.8036E-02 -2.095 1.994 0.300 0.2467 0.5461 microcline 0.1377 -0.861 38.32 1.583 4.742 14.97 stilbite 0.4846 -0.315 341.5 2.533 42.25 159.3 stilpnomelane-Fe 0.3855E-01 -1.414 41.56 1.619 5.142 14.36 tr.625ac.25prg.125 0.6964E-02 -2.157 5.953 0.775 0.7365 1.916 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8050E+00 0.8050E+00 1.0000 -0.094 grossular 0.1950E+00 0.1950E+00 1.0000 -0.710 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.7613E+00 0.7613E+00 1.0000 -0.118 daphnite 0.2204E+00 0.2204E+00 1.0000 -0.657 chlorite-Mn 0.1839E-01 0.1839E-01 1.0000 -1.735 diopside 0.7941E+00 0.7941E+00 1.0000 -0.100 hedenbergite 0.2059E+00 0.2059E+00 1.0000 -0.686 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 tr.625ac.25prg.125 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 808.259591 g Volume = 327.727325 cm3 Porosity: -10.3460% V(tot) - V(min): -.30728E+02 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 739.9990000 g log = 2.8692 Original solution: 1000.0103000 g Original solution / Rock added: 1.35 (Water/Rock Ratio), log = 0.1308 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0554 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9672E+00 0.9855 0.1006E+01 0.1021E+01 CO2,gas 0.3458E-08 1.0069 0.3675E-08 0.3650E-08 CH4,gas 0.1838E-01 1.0125 0.1964E-01 0.1940E-01 H2,gas 0.1440E-01 1.0006 0.1521E-01 0.1520E-01 H2S,gas 0.1382E-06 0.9959 0.1453E-06 0.1459E-06 S2,gas 0.3243E-29 1.0000 0.3423E-29 0.3423E-29 CO,gas 0.1412E-13 1.0000 0.1490E-13 0.1490E-13 SO3,gas 0.7167E-48 1.0000 0.7564E-48 0.7564E-48 SO2,gas 0.4241E-27 1.0000 0.4476E-27 0.4476E-27 HCl,gas 0.2821E-17 1.0000 0.2977E-17 0.2977E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 16 albite -0.38 -0.38 0.00 0.000 -0.94784E-12 22 andradite 39.01 39.01 0.00 0.000 0.12132E-10 23 grossular 32.73 32.73 0.00 0.000 0.00000E+00 32 apatite-OH -18.15 -18.15 0.00 0.000 0.00000E+00 46 clinochlore 39.07 39.07 0.00 0.000 0.00000E+00 47 daphnite 28.97 28.97 0.00 0.000 0.00000E+00 48 chlorite-Mn 46.87 46.87 0.00 0.000 -0.24265E-10 67 diopside 16.18 16.18 0.00 0.000 -0.12132E-10 68 hedenbergite 14.21 14.21 0.00 0.000 -0.12132E-10 116 microcline -2.49 -2.49 0.00 0.000 -0.10616E-10 163 stilbite -7.52 -7.52 0.00 0.000 -0.90992E-11 164 stilpnomelane-Fe 13.02 13.02 0.00 0.000 0.21232E-10 245 tr.625ac.25prg.125 45.16 45.16 0.00 0.000 0.12132E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -16.79 -10.13 -3.378 0.17303E+05 -8.435 3 CH4,gas 4.54 1.14 -3.41 -0.851 0.58153E+04 -1.707 4 H2,gas 8.00 4.48 -3.52 -2.010 0.60049E+04 -1.818 5 H2S,gas -6.23 -14.77 -8.54 -4.268 0.14576E+05 -6.838 6 S2,gas -7.34 -38.50 -31.16 -4.795 0.53213E+05 -29.466 7 CO,gas 3.21 -12.31 -15.53 -4.777 0.26510E+05 -13.827 8 SO3,gas 17.12 -32.70 -49.82 -12.455 0.85067E+05 -48.121 9 SO2,gas 0.83 -28.22 -29.05 -7.746 0.49599E+05 -27.349 10 HCl,gas 5.19 -14.04 -19.23 -9.613 0.32826E+05 -17.526 11 acmite 7.71 6.53 -1.18 -0.123 0.20178E+04 15 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 19 spessartine 24.46 19.72 -4.74 -0.237 0.80934E+04 20 analcite 3.32 2.77 -0.55 -0.061 0.93616E+03 26 annite 20.12 17.72 -2.40 -0.134 0.41063E+04 27 phlogopite 27.06 25.40 -1.67 -0.093 0.28486E+04 29 anorthite 12.71 8.27 -4.45 -0.342 0.75899E+04 35 aragonite 0.97 -3.69 -4.66 -1.553 0.79543E+04 36 brucite 12.57 9.29 -3.27 -0.655 0.55908E+04 37 calcite 0.81 -3.69 -4.50 -1.501 0.76900E+04 38 carnegieite-low 9.02 5.93 -3.09 -0.442 0.52799E+04 39 carnegieite-high 10.09 5.93 -4.16 -0.595 0.71069E+04 40 carpholite-Mg 8.58 4.46 -4.12 -0.275 0.70425E+04 41 carpholite-Fe 6.71 1.90 -4.81 -0.321 0.82203E+04 42 celadonite 5.34 3.65 -1.69 -0.099 0.28878E+04 43 celadonite-Fe 3.88 1.09 -2.79 -0.164 0.47561E+04 44 chrysotile 23.89 21.57 -2.32 -0.194 0.39691E+04 49 chlorite-Al-free 47.17 43.14 -4.04 -0.168 0.68934E+04 51 chloritoid-Fe 9.17 5.06 -4.12 -0.275 0.70311E+04 52 chloritoid-Mn 11.40 7.56 -3.84 -0.256 0.65620E+04 54 coesite -2.38 -3.16 -0.78 -0.260 0.13342E+04 61 cristobalite -2.56 -3.16 -0.60 -0.199 0.10196E+04 63 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71234E+04 65 diaspore 2.87 0.74 -2.13 -0.356 0.36447E+04 66 diamond -3.10 -7.83 -4.73 -1.350 0.80688E+04 71 enstatite 17.26 12.27 -4.99 -0.499 0.85225E+04 73 clinoenstatite 17.17 12.27 -4.89 -0.489 0.83541E+04 75 epidote 24.67 22.70 -1.97 -0.095 0.33581E+04 76 clinozoisite 22.81 18.95 -3.86 -0.175 0.65861E+04 77 epidote-Fe 29.84 26.46 -3.38 -0.176 0.57768E+04 78 fayalite 14.05 10.31 -3.73 -0.533 0.63743E+04 79 ferrosilite 11.15 7.16 -3.99 -0.399 0.68203E+04 83 gibbsite 4.08 0.74 -3.34 -0.477 0.57033E+04 84 glaucophane 22.97 20.80 -2.17 -0.059 0.37132E+04 85 glaucophane-Fe 17.28 13.12 -4.15 -0.112 0.70919E+04 86 graphite -3.55 -7.83 -4.28 -1.223 0.73110E+04 87 greenalite 16.14 13.89 -2.25 -0.187 0.38408E+04 90 hematite 12.57 8.99 -3.58 -0.434 0.61113E+04 91 heulandite -5.83 -7.52 -1.69 -0.077 0.28938E+04 95 jadeite 4.22 2.77 -1.44 -0.144 0.24616E+04 97 kalsilite 7.58 3.83 -3.76 -0.536 0.64124E+04 98 kaolinite -1.33 -4.84 -3.50 -0.319 0.59828E+04 101 laumontite 2.88 1.95 -0.93 -0.062 0.15932E+04 102 lawsonite 9.62 8.27 -1.35 -0.090 0.23065E+04 103 leucite 4.12 0.67 -3.45 -0.345 0.58872E+04 105 lizardite 23.24 21.57 -1.68 -0.140 0.28617E+04 107 magnetite 20.09 15.72 -4.37 -0.356 0.74537E+04 108 minnesotaite 10.39 7.58 -2.81 -0.165 0.48030E+04 112 manganosite 14.06 9.24 -4.82 -1.205 0.82316E+04 120 muscovite 2.58 -1.01 -3.59 -0.211 0.61310E+04 121 paragonite 4.24 1.09 -3.15 -0.185 0.53701E+04 122 nepheline 8.34 5.93 -2.41 -0.344 0.41123E+04 128 periclase-Fe 11.63 6.73 -4.89 -1.223 0.83522E+04 134 phlogopite-Na 29.65 27.50 -2.15 -0.119 0.36674E+04 136 prehnite 19.37 18.21 -1.16 -0.068 0.19845E+04 137 prehnite-Fe 22.50 21.96 -0.53 -0.032 0.91147E+03 138 pumpellyite-Fe 46.27 43.89 -2.38 -0.053 0.40569E+04 139 pumpellyite-Mg 48.99 46.45 -2.54 -0.056 0.43407E+04 143 pyrrhotite -4.26 -8.03 -3.77 -1.257 0.64402E+04 144 pyrrhotiteFe0.875 -6.02 -9.43 -3.41 -1.255 0.58274E+04 145 pyroxmangite 7.40 6.08 -1.32 -0.264 0.22521E+04 146 pyrophyllite -6.18 -11.15 -4.98 -0.311 0.84960E+04 147 quartz -2.99 -3.16 -0.17 -0.056 0.28689E+03 152 rhodonite 7.45 6.08 -1.37 -0.273 0.23324E+04 153 sanidine -1.28 -2.49 -1.21 -0.093 0.20677E+04 165 stilpnomelane-Mg 27.44 25.81 -1.63 -0.049 0.27800E+04 171 talc 16.49 15.25 -1.24 -0.073 0.21141E+04 174 tephroite 18.09 15.32 -2.77 -0.396 0.47279E+04 178 tridymite -2.63 -3.16 -0.53 -0.177 0.90687E+03 179 tremolite 47.87 47.42 -0.45 -0.012 0.77497E+03 180 ferroactinolite 38.45 34.62 -3.83 -0.104 0.65452E+04 181 troilite-low -4.41 -8.03 -3.62 -1.207 0.61830E+04 183 vesuvianite 223.47 218.82 -4.65 -0.035 0.79405E+04 187 wairakite 3.95 1.95 -2.00 -0.118 0.34152E+04 188 walstromite 11.51 9.94 -1.56 -0.313 0.26719E+04 189 wollastonite 10.46 9.94 -0.52 -0.103 0.88229E+03 190 pseudo-wollastonite 11.00 9.94 -1.06 -0.211 0.18021E+04 191 zoisite 22.85 18.95 -3.90 -0.177 0.66602E+04 192 akaganeite 7.75 4.49 -3.26 -0.705 0.55682E+04 199 chalcedony -2.80 -3.16 -0.36 -0.118 0.60619E+03 201 montmorillonite-Ca -2.29 -6.17 -3.88 -0.240 0.66179E+04 202 montmorillonite-K -2.24 -6.27 -4.03 -0.247 0.68815E+04 203 montmorillonite-Mg -2.48 -6.79 -4.31 -0.267 0.73677E+04 204 montmorillonite-Na -2.04 -5.57 -3.54 -0.216 0.60364E+04 205 nontronite-Ca 3.21 -0.20 -3.41 -0.221 0.58219E+04 206 nontronite-H 2.53 -2.36 -4.89 -0.328 0.83489E+04 207 nontronite-K 3.34 -0.30 -3.64 -0.233 0.62087E+04 208 nontronite-Mg 3.07 -0.82 -3.90 -0.253 0.66557E+04 209 nontronite-Na 3.52 0.40 -3.12 -0.200 0.53295E+04 224 tobermorite 9.82 7.76 -2.07 -0.564 0.35287E+04 230 alabandite -0.98 -5.53 -4.55 -1.517 0.77725E+04 233 boehmite 4.41 0.74 -3.67 -0.611 0.62616E+04 235 ferrous-oxide 9.81 6.73 -3.08 -0.769 0.52532E+04 240 silica-amorphous -2.09 -3.16 -1.07 -0.355 0.18204E+04 242 an20ab80 2.02 1.35 -0.67 -0.052 0.11471E+04 243 an25ab75 2.65 1.78 -0.87 -0.067 0.14809E+04 244 an30ab70 3.28 2.21 -1.07 -0.082 0.18242E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 20.0000000 g Current total amount of reactant added: 739.9990000 g New total amount of reactant added: 759.9990000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.1586E-10 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 11 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 759.9990000 Water: Moles liquid = 0.5119E+02 kg liquid = 0.9221E+00 Moles total = 0.4598E+02 kg total = 0.8284E+00 Activity = 1.0000 Stoichiometric ionic strength = .1132695E-01 Osmotic coef. = 0.9694 True ionic strength = .2001512E-01 Chg. balance for total moles = -.1586E-10 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.88279E-10 -10.0541 0.74177E-10 -10.1297 0.84026E+00 -0.0756 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.14894E-03 -3.8270 0.12440E-03 -3.9052 0.83521E+00 -0.0782 4 SO4-- 0.70164E-12 -12.1539 0.36438E-12 -12.4384 0.51933E+00 -0.2846 5 HCO3- 0.25966E-06 -6.5856 0.21718E-06 -6.6632 0.83643E+00 -0.0776 6 HS- 0.27653E-04 -4.5583 0.23099E-04 -4.6364 0.83533E+00 -0.0781 7 Al+++ 0.96877E-29 -29.0138 0.22384E-29 -29.6501 0.23105E+00 -0.6363 8 H4SiO4 0.69590E-03 -3.1575 0.69590E-03 -3.1575 0.10000E+01 0.0000 9 Ca++ 0.13495E-06 -6.8698 0.69570E-07 -7.1576 0.51552E+00 -0.2878 10 Mg++ 0.21112E-10 -10.6755 0.10834E-10 -10.9652 0.51316E+00 -0.2897 11 Fe++ 0.58185E-13 -13.2352 0.29891E-13 -13.5245 0.51372E+00 -0.2893 12 K+ 0.15649E-03 -3.8055 0.13092E-03 -3.8830 0.83663E+00 -0.0775 13 Na+ 0.19858E-01 -1.7021 0.16582E-01 -1.7804 0.83506E+00 -0.0783 14 Mn++ 0.18482E-10 -10.7333 0.95025E-11 -11.0222 0.51415E+00 -0.2889 15 HPO4-- 0.45323E-07 -7.3437 0.23541E-07 -7.6282 0.51940E+00 -0.2845 16 HSiO3- 0.10488E-01 -1.9793 0.87599E-02 -2.0575 0.83521E+00 -0.0782 17 Ca(HSiO3)+ 0.16586E-07 -7.7803 0.13879E-07 -7.8576 0.83681E+00 -0.0774 18 Mg(HSiO3)+ 0.32144E-11 -11.4929 0.26898E-11 -11.5703 0.83681E+00 -0.0774 19 NaHSiO3,aq 0.23494E-02 -2.6290 0.23494E-02 -2.6290 0.10000E+01 0.0000 20 AlO+ 0.66137E-16 -16.1796 0.55344E-16 -16.2569 0.83681E+00 -0.0774 22 HAlO2,aq 0.14859E-09 -9.8280 0.14859E-09 -9.8280 0.10000E+01 0.0000 23 AlO2- 0.53185E-05 -5.2742 0.44341E-05 -5.3532 0.83370E+00 -0.0790 24 CH4,aq 0.13420E-04 -4.8722 0.13374E-04 -4.8737 0.99655E+00 -0.0015 25 C2H6,aq 0.26483E-14 -14.5770 0.26392E-14 -14.5785 0.99655E+00 -0.0015 29 CO,aq 0.10019E-16 -16.9992 0.10019E-16 -16.9992 0.10000E+01 0.0000 30 CO2,aq 0.34543E-10 -10.4616 0.34424E-10 -10.4631 0.99655E+00 -0.0015 31 CO3-2 0.49349E-06 -6.3067 0.25574E-06 -6.5922 0.51823E+00 -0.2855 32 CaCO3,aq 0.22309E-09 -9.6515 0.22309E-09 -9.6515 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.46090E-12 -12.3364 0.38569E-12 -12.4138 0.83681E+00 -0.0774 34 CaCl+ 0.16736E-10 -10.7763 0.14005E-10 -10.8537 0.83681E+00 -0.0774 35 CaCl2,aq 0.41391E-15 -15.3831 0.41391E-15 -15.3831 0.10000E+01 0.0000 36 CaOH+ 0.79878E-07 -7.0976 0.66843E-07 -7.1749 0.83681E+00 -0.0774 37 CaSO4,aq 0.80498E-17 -17.0942 0.80498E-17 -17.0942 0.10000E+01 0.0000 38 HCl,aq 0.16909E-14 -14.7719 0.16909E-14 -14.7719 0.10000E+01 0.0000 43 FeCl+ 0.70332E-17 -17.1528 0.58854E-17 -17.2302 0.83681E+00 -0.0774 46 FeO,aq 0.21114E-09 -9.6754 0.21114E-09 -9.6754 0.10000E+01 0.0000 47 FeOH+ 0.15675E-10 -10.8048 0.13117E-10 -10.8822 0.83681E+00 -0.0774 48 HFeO2- 0.35658E-07 -7.4478 0.29782E-07 -7.5260 0.83521E+00 -0.0782 49 FeO+ 0.10984E-16 -16.9592 0.91917E-17 -17.0366 0.83681E+00 -0.0774 51 FeO2- 0.40927E-09 -9.3880 0.34182E-09 -9.4662 0.83521E+00 -0.0782 52 HFeO2,aq 0.32248E-11 -11.4915 0.32248E-11 -11.4915 0.10000E+01 0.0000 53 H2,aq 0.11626E-04 -4.9346 0.11586E-04 -4.9361 0.99655E+00 -0.0015 54 KCl,aq 0.29517E-09 -9.5299 0.29517E-09 -9.5299 0.10000E+01 0.0000 56 KOH,aq 0.75375E-06 -6.1228 0.75375E-06 -6.1228 0.10000E+01 0.0000 57 KSO4- 0.88634E-15 -15.0524 0.74028E-15 -15.1306 0.83521E+00 -0.0782 58 MgCO3,aq 0.87083E-14 -14.0601 0.87083E-14 -14.0601 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.73341E-16 -16.1347 0.61373E-16 -16.2120 0.83681E+00 -0.0774 60 MgCl+ 0.23623E-14 -14.6267 0.19767E-14 -14.7040 0.83681E+00 -0.0774 61 MgOH+ 0.68833E-10 -10.1622 0.57600E-10 -10.2396 0.83681E+00 -0.0774 63 MnO,aq 0.17885E-08 -8.7475 0.17885E-08 -8.7475 0.10000E+01 0.0000 64 MnOH+ 0.46292E-09 -9.3345 0.38738E-09 -9.4119 0.83681E+00 -0.0774 65 MnO2-2 0.20816E-10 -10.6816 0.10787E-10 -10.9671 0.51823E+00 -0.2855 66 HMnO2- 0.20990E-09 -9.6780 0.17531E-09 -9.7562 0.83521E+00 -0.0782 69 MnCl+ 0.86986E-14 -14.0605 0.72791E-14 -14.1379 0.83681E+00 -0.0774 71 NaCl,aq 0.68360E-06 -6.1652 0.68360E-06 -6.1652 0.10000E+01 0.0000 72 NaOH,aq 0.96047E-04 -4.0175 0.96047E-04 -4.0175 0.10000E+01 0.0000 74 OH- 0.93428E-02 -2.0295 0.77891E-02 -2.1085 0.83370E+00 -0.0790 79 HPO3-2 0.16401E-14 -14.7851 0.84996E-15 -15.0706 0.51823E+00 -0.2855 81 H2PO3- 0.15137E-18 -18.8199 0.12643E-18 -18.8982 0.83521E+00 -0.0782 82 H3PO4,aq 0.90592E-18 -18.0429 0.90592E-18 -18.0429 0.10000E+01 0.0000 83 H2PO4- 0.38532E-10 -10.4142 0.32213E-10 -10.4920 0.83600E+00 -0.0778 84 PO4-3 0.10670E-08 -8.9718 0.25893E-09 -9.5868 0.24267E+00 -0.6150 88 HP2O7-3 0.94698E-18 -18.0237 0.21902E-18 -18.6595 0.23129E+00 -0.6359 89 P2O7-4 0.91466E-17 -17.0387 0.70539E-18 -18.1516 0.77121E-01 -1.1128 90 H2S,aq 0.53139E-08 -8.2746 0.52955E-08 -8.2761 0.99655E+00 -0.0015 91 S2-2 0.19691E-14 -14.7057 0.10205E-14 -14.9912 0.51823E+00 -0.2855 97 SO3-2 0.10435E-17 -17.9815 0.54860E-18 -18.2607 0.52572E+00 -0.2792 99 HSO4- 0.31098E-19 -19.5073 0.26048E-19 -19.5842 0.83762E+00 -0.0770 Charge balance for all species = -.1720E-10 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.8827890E-10 -.2230220E-01 -.2244022E+02 0.0000 2 H2O 0.1000000E+01 0.5550489E+02 0.9981997E+06 0.0000 3 Cl- 0.1489395E-03 0.1496234E-03 0.5295383E+01 6.2245 4 SO4-- 0.7016396E-12 -.1632653E-04 -.1565627E+01 7.8210 5 HCO3- 0.2596563E-06 0.1417351E-04 0.8633251E+00 3.4666 6 HS- 0.2765252E-04 0.4398436E-04 0.1452123E+01 5.4933 7 Al+++ 0.9687707E-29 0.5318686E-05 0.1432568E+00 0.7391 8 H4SiO4 0.6958973E-03 0.1353363E-01 0.1298530E+04 -3.1575 9 Ca++ 0.1349518E-06 0.2316562E-06 0.9268185E-02 13.1019 10 Mg++ 0.2111247E-10 0.9317169E-10 0.2261254E-05 9.2943 11 Fe++ 0.5818479E-13 0.3629742E-07 0.2023580E-02 6.7350 12 K+ 0.1564884E-03 0.1572425E-03 0.6137812E+01 6.2467 13 Na+ 0.1985758E-01 0.2230368E-01 0.5118662E+03 8.3494 14 Mn++ 0.1848203E-10 0.2500626E-08 0.1371407E-03 9.2373 15 HPO4-- 0.4532348E-07 0.4642902E-07 0.4448468E-02 12.6313 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.1258444E+02 -.2056581E-01 -.1256388E+02 0.0000000E+00 2 H2O 0.4598135E+02 0.5118343E+02 -.5202082E+01 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.2108767E-01 -.1505539E-04 0.2110272E-01 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.2106216E-01 0.4055986E-04 -.2110272E-01 0.0000000E+00 7 Al+++ 0.2478160E+01 0.4904588E-05 0.2478155E+01 0.0000000E+00 8 H4SiO4 0.7913705E+01 0.1247993E-01 0.7901225E+01 0.0000000E+00 9 Ca++ 0.8741217E+00 0.2136201E-06 0.8741215E+00 0.0000000E+00 10 Mg++ 0.6031738E+00 0.8591761E-10 0.6031738E+00 0.0000000E+00 11 Fe++ 0.5418858E+00 0.3347141E-07 0.5418858E+00 0.0000000E+00 12 K+ 0.1613586E+00 0.1450000E-03 0.1612136E+00 0.0000000E+00 13 Na+ 0.9541440E+00 0.2056718E-01 0.9335768E+00 0.0000000E+00 14 Mn++ 0.1317732E-01 0.2305934E-08 0.1317731E-01 0.0000000E+00 15 HPO4-- 0.4497352E-02 0.4281419E-07 0.4497309E-02 0.0000000E+00 Chg. balance for solid moles: 0.6557E-15 Mass of aqueous solution: 0.923748E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 759.9990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 0.9327 -0.030 244.6 2.388 29.46 93.88 andradite 0.8441E-01 -1.074 42.90 1.632 5.168 11.14 grossular 0.2045E-01 -1.689 9.211 0.964 1.110 2.563 apatite-OH 0.1499E-02 -2.824 0.7530 -0.123 0.9071E-01 0.2393 clinochlore 0.1090 -0.962 60.61 1.783 7.302 23.06 daphnite 0.3157E-01 -1.501 22.52 1.353 2.713 6.825 chlorite-Mn 0.2635E-02 -2.579 1.868 0.271 0.2251 0.5954 diopside 0.3208E-01 -1.494 6.947 0.842 0.8368 2.123 hedenbergite 0.8318E-02 -2.080 2.064 0.315 0.2486 0.5652 microcline 0.1414 -0.850 39.36 1.595 4.742 15.38 stilbite 0.4974 -0.303 350.5 2.545 42.23 163.5 stilpnomelane-Fe 0.3960E-01 -1.402 42.69 1.630 5.143 14.75 tr.625ac.25prg.125 0.7131E-02 -2.147 6.095 0.785 0.7343 1.962 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8050E+00 0.8050E+00 1.0000 -0.094 grossular 0.1950E+00 0.1950E+00 1.0000 -0.710 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.7612E+00 0.7612E+00 1.0000 -0.118 daphnite 0.2204E+00 0.2204E+00 1.0000 -0.657 chlorite-Mn 0.1840E-01 0.1840E-01 1.0000 -1.735 diopside 0.7941E+00 0.7941E+00 1.0000 -0.100 hedenbergite 0.2059E+00 0.2059E+00 1.0000 -0.686 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 tr.625ac.25prg.125 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 830.109722 g Volume = 336.567938 cm3 Porosity: -10.3503% V(tot) - V(min): -.31568E+02 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 759.9990000 g log = 2.8808 Original solution: 1000.0103000 g Original solution / Rock added: 1.32 (Water/Rock Ratio), log = 0.1192 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0554 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9672E+00 0.9855 0.1006E+01 0.1021E+01 CO2,gas 0.3466E-08 1.0069 0.3683E-08 0.3658E-08 CH4,gas 0.1842E-01 1.0125 0.1969E-01 0.1944E-01 H2,gas 0.1440E-01 1.0006 0.1521E-01 0.1520E-01 H2S,gas 0.1385E-06 0.9959 0.1456E-06 0.1462E-06 S2,gas 0.3257E-29 1.0000 0.3438E-29 0.3438E-29 CO,gas 0.1415E-13 1.0000 0.1493E-13 0.1493E-13 SO3,gas 0.7183E-48 1.0000 0.7581E-48 0.7581E-48 SO2,gas 0.4250E-27 1.0000 0.4486E-27 0.4486E-27 HCl,gas 0.2827E-17 1.0000 0.2984E-17 0.2984E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 16 albite -0.38 -0.38 0.00 0.000 -0.13080E-10 22 andradite 39.01 39.01 0.00 0.000 0.12132E-10 23 grossular 32.73 32.73 0.00 0.000 0.36397E-10 32 apatite-OH -18.15 -18.15 0.00 0.000 -0.60662E-11 46 clinochlore 39.07 39.07 0.00 0.000 -0.12132E-10 47 daphnite 28.97 28.97 0.00 0.000 0.18198E-10 48 chlorite-Mn 46.87 46.87 0.00 0.000 0.24265E-10 67 diopside 16.18 16.18 0.00 0.000 0.00000E+00 68 hedenbergite 14.21 14.21 0.00 0.000 -0.90992E-11 116 microcline -2.49 -2.49 0.00 0.000 0.15165E-11 163 stilbite -7.52 -7.52 0.00 0.000 0.15165E-10 164 stilpnomelane-Fe 13.02 13.02 0.00 0.000 -0.27298E-10 245 tr.625ac.25prg.125 45.16 45.16 0.00 0.000 0.24265E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -16.79 -10.13 -3.378 0.17301E+05 -8.434 3 CH4,gas 4.54 1.14 -3.40 -0.851 0.58137E+04 -1.706 4 H2,gas 8.00 4.48 -3.52 -2.010 0.60049E+04 -1.818 5 H2S,gas -6.23 -14.77 -8.54 -4.268 0.14575E+05 -6.837 6 S2,gas -7.34 -38.50 -31.16 -4.794 0.53209E+05 -29.464 7 CO,gas 3.21 -12.31 -15.52 -4.777 0.26508E+05 -13.826 8 SO3,gas 17.12 -32.70 -49.82 -12.455 0.85065E+05 -48.120 9 SO2,gas 0.83 -28.21 -29.05 -7.746 0.49597E+05 -27.348 10 HCl,gas 5.19 -14.03 -19.22 -9.612 0.32825E+05 -17.525 11 acmite 7.71 6.53 -1.18 -0.123 0.20178E+04 15 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 19 spessartine 24.46 19.72 -4.74 -0.237 0.80927E+04 20 analcite 3.32 2.77 -0.55 -0.061 0.93616E+03 26 annite 20.12 17.72 -2.40 -0.134 0.41063E+04 27 phlogopite 27.06 25.40 -1.67 -0.093 0.28486E+04 29 anorthite 12.71 8.27 -4.45 -0.342 0.75899E+04 35 aragonite 0.97 -3.69 -4.66 -1.553 0.79526E+04 36 brucite 12.57 9.29 -3.27 -0.655 0.55908E+04 37 calcite 0.81 -3.69 -4.50 -1.501 0.76884E+04 38 carnegieite-low 9.02 5.93 -3.09 -0.442 0.52799E+04 39 carnegieite-high 10.09 5.93 -4.16 -0.595 0.71069E+04 40 carpholite-Mg 8.58 4.46 -4.12 -0.275 0.70425E+04 41 carpholite-Fe 6.71 1.90 -4.81 -0.321 0.82203E+04 42 celadonite 5.34 3.65 -1.69 -0.099 0.28878E+04 43 celadonite-Fe 3.88 1.09 -2.79 -0.164 0.47561E+04 44 chrysotile 23.89 21.57 -2.32 -0.194 0.39691E+04 49 chlorite-Al-free 47.17 43.14 -4.04 -0.168 0.68934E+04 51 chloritoid-Fe 9.17 5.06 -4.12 -0.275 0.70311E+04 52 chloritoid-Mn 11.40 7.56 -3.84 -0.256 0.65618E+04 54 coesite -2.38 -3.16 -0.78 -0.260 0.13342E+04 61 cristobalite -2.56 -3.16 -0.60 -0.199 0.10196E+04 63 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71234E+04 65 diaspore 2.87 0.74 -2.13 -0.356 0.36447E+04 66 diamond -3.10 -7.83 -4.72 -1.350 0.80672E+04 71 enstatite 17.26 12.27 -4.99 -0.499 0.85225E+04 73 clinoenstatite 17.17 12.27 -4.89 -0.489 0.83541E+04 75 epidote 24.67 22.70 -1.97 -0.095 0.33582E+04 76 clinozoisite 22.81 18.95 -3.86 -0.175 0.65862E+04 77 epidote-Fe 29.84 26.46 -3.38 -0.176 0.57768E+04 78 fayalite 14.05 10.31 -3.73 -0.533 0.63743E+04 79 ferrosilite 11.15 7.16 -3.99 -0.399 0.68203E+04 83 gibbsite 4.08 0.74 -3.34 -0.477 0.57033E+04 84 glaucophane 22.97 20.80 -2.17 -0.059 0.37132E+04 85 glaucophane-Fe 17.28 13.12 -4.15 -0.112 0.70919E+04 86 graphite -3.55 -7.83 -4.28 -1.223 0.73094E+04 87 greenalite 16.14 13.89 -2.25 -0.187 0.38408E+04 90 hematite 12.57 8.99 -3.58 -0.434 0.61113E+04 91 heulandite -5.83 -7.52 -1.69 -0.077 0.28938E+04 95 jadeite 4.22 2.77 -1.44 -0.144 0.24616E+04 97 kalsilite 7.58 3.83 -3.76 -0.536 0.64124E+04 98 kaolinite -1.33 -4.84 -3.50 -0.319 0.59828E+04 101 laumontite 2.88 1.95 -0.93 -0.062 0.15932E+04 102 lawsonite 9.62 8.27 -1.35 -0.090 0.23065E+04 103 leucite 4.12 0.67 -3.45 -0.345 0.58872E+04 105 lizardite 23.24 21.57 -1.68 -0.140 0.28617E+04 107 magnetite 20.09 15.72 -4.37 -0.356 0.74537E+04 108 minnesotaite 10.39 7.58 -2.81 -0.165 0.48030E+04 112 manganosite 14.06 9.24 -4.82 -1.205 0.82314E+04 120 muscovite 2.58 -1.01 -3.59 -0.211 0.61310E+04 121 paragonite 4.24 1.09 -3.15 -0.185 0.53701E+04 122 nepheline 8.34 5.93 -2.41 -0.344 0.41123E+04 128 periclase-Fe 11.63 6.73 -4.89 -1.223 0.83522E+04 134 phlogopite-Na 29.65 27.50 -2.15 -0.119 0.36674E+04 136 prehnite 19.37 18.21 -1.16 -0.068 0.19845E+04 137 prehnite-Fe 22.50 21.96 -0.53 -0.032 0.91147E+03 138 pumpellyite-Fe 46.27 43.89 -2.38 -0.053 0.40570E+04 139 pumpellyite-Mg 48.99 46.45 -2.54 -0.056 0.43407E+04 143 pyrrhotite -4.26 -8.03 -3.77 -1.257 0.64386E+04 144 pyrrhotiteFe0.875 -6.02 -9.43 -3.41 -1.255 0.58258E+04 145 pyroxmangite 7.40 6.08 -1.32 -0.264 0.22519E+04 146 pyrophyllite -6.18 -11.15 -4.98 -0.311 0.84960E+04 147 quartz -2.99 -3.16 -0.17 -0.056 0.28689E+03 152 rhodonite 7.45 6.08 -1.37 -0.273 0.23321E+04 153 sanidine -1.28 -2.49 -1.21 -0.093 0.20677E+04 165 stilpnomelane-Mg 27.44 25.81 -1.63 -0.049 0.27800E+04 171 talc 16.49 15.25 -1.24 -0.073 0.21141E+04 174 tephroite 18.09 15.32 -2.77 -0.396 0.47274E+04 178 tridymite -2.63 -3.16 -0.53 -0.177 0.90687E+03 179 tremolite 47.87 47.42 -0.45 -0.012 0.77497E+03 180 ferroactinolite 38.45 34.62 -3.83 -0.104 0.65452E+04 181 troilite-low -4.41 -8.03 -3.62 -1.207 0.61814E+04 183 vesuvianite 223.47 218.82 -4.65 -0.036 0.79406E+04 187 wairakite 3.95 1.95 -2.00 -0.118 0.34152E+04 188 walstromite 11.51 9.94 -1.56 -0.313 0.26719E+04 189 wollastonite 10.46 9.94 -0.52 -0.103 0.88229E+03 190 pseudo-wollastonite 11.00 9.94 -1.06 -0.211 0.18021E+04 191 zoisite 22.85 18.95 -3.90 -0.177 0.66602E+04 192 akaganeite 7.75 4.49 -3.26 -0.705 0.55682E+04 199 chalcedony -2.80 -3.16 -0.36 -0.118 0.60619E+03 201 montmorillonite-Ca -2.29 -6.17 -3.88 -0.240 0.66179E+04 202 montmorillonite-K -2.24 -6.27 -4.03 -0.247 0.68815E+04 203 montmorillonite-Mg -2.48 -6.79 -4.31 -0.267 0.73677E+04 204 montmorillonite-Na -2.04 -5.57 -3.54 -0.216 0.60364E+04 205 nontronite-Ca 3.21 -0.20 -3.41 -0.221 0.58218E+04 206 nontronite-H 2.53 -2.36 -4.89 -0.328 0.83488E+04 207 nontronite-K 3.34 -0.30 -3.64 -0.233 0.62087E+04 208 nontronite-Mg 3.07 -0.82 -3.90 -0.253 0.66557E+04 209 nontronite-Na 3.52 0.40 -3.12 -0.200 0.53295E+04 224 tobermorite 9.82 7.76 -2.07 -0.564 0.35287E+04 230 alabandite -0.98 -5.53 -4.55 -1.517 0.77707E+04 233 boehmite 4.41 0.74 -3.67 -0.611 0.62616E+04 235 ferrous-oxide 9.81 6.73 -3.08 -0.769 0.52532E+04 240 silica-amorphous -2.09 -3.16 -1.07 -0.355 0.18204E+04 242 an20ab80 2.02 1.35 -0.67 -0.052 0.11471E+04 243 an25ab75 2.65 1.78 -0.87 -0.067 0.14809E+04 244 an30ab70 3.28 2.21 -1.07 -0.082 0.18242E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 20.0000000 g Current total amount of reactant added: 759.9990000 g New total amount of reactant added: 779.9990000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.1586E-10 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 11 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 779.9990000 Water: Moles liquid = 0.5108E+02 kg liquid = 0.9201E+00 Moles total = 0.4573E+02 kg total = 0.8239E+00 Activity = 1.0000 Stoichiometric ionic strength = .1132724E-01 Osmotic coef. = 0.9694 True ionic strength = .2001535E-01 Chg. balance for total moles = -.1586E-10 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.88280E-10 -10.0541 0.74178E-10 -10.1297 0.84026E+00 -0.0756 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.14926E-03 -3.8260 0.12467E-03 -3.9042 0.83521E+00 -0.0782 4 SO4-- 0.70319E-12 -12.1529 0.36519E-12 -12.4375 0.51933E+00 -0.2846 5 HCO3- 0.26023E-06 -6.5846 0.21766E-06 -6.6622 0.83643E+00 -0.0776 6 HS- 0.27713E-04 -4.5573 0.23149E-04 -4.6355 0.83533E+00 -0.0781 7 Al+++ 0.96880E-29 -29.0138 0.22384E-29 -29.6501 0.23105E+00 -0.6363 8 H4SiO4 0.69590E-03 -3.1575 0.69590E-03 -3.1575 0.10000E+01 0.0000 9 Ca++ 0.13495E-06 -6.8698 0.69571E-07 -7.1576 0.51552E+00 -0.2878 10 Mg++ 0.21113E-10 -10.6755 0.10834E-10 -10.9652 0.51316E+00 -0.2897 11 Fe++ 0.58186E-13 -13.2352 0.29891E-13 -13.5245 0.51372E+00 -0.2893 12 K+ 0.15649E-03 -3.8055 0.13092E-03 -3.8830 0.83663E+00 -0.0775 13 Na+ 0.19858E-01 -1.7021 0.16582E-01 -1.7804 0.83506E+00 -0.0783 14 Mn++ 0.18488E-10 -10.7331 0.95055E-11 -11.0220 0.51415E+00 -0.2889 15 HPO4-- 0.45323E-07 -7.3437 0.23541E-07 -7.6282 0.51940E+00 -0.2845 16 HSiO3- 0.10488E-01 -1.9793 0.87599E-02 -2.0575 0.83521E+00 -0.0782 17 Ca(HSiO3)+ 0.16586E-07 -7.7803 0.13879E-07 -7.8576 0.83681E+00 -0.0774 18 Mg(HSiO3)+ 0.32145E-11 -11.4929 0.26899E-11 -11.5703 0.83681E+00 -0.0774 19 NaHSiO3,aq 0.23494E-02 -2.6290 0.23494E-02 -2.6290 0.10000E+01 0.0000 20 AlO+ 0.66137E-16 -16.1796 0.55344E-16 -16.2569 0.83681E+00 -0.0774 22 HAlO2,aq 0.14858E-09 -9.8280 0.14858E-09 -9.8280 0.10000E+01 0.0000 23 AlO2- 0.53184E-05 -5.2742 0.44340E-05 -5.3532 0.83370E+00 -0.0790 24 CH4,aq 0.13449E-04 -4.8713 0.13403E-04 -4.8728 0.99655E+00 -0.0015 25 C2H6,aq 0.26599E-14 -14.5751 0.26507E-14 -14.5766 0.99655E+00 -0.0015 29 CO,aq 0.10041E-16 -16.9982 0.10041E-16 -16.9982 0.10000E+01 0.0000 30 CO2,aq 0.34619E-10 -10.4607 0.34500E-10 -10.4622 0.99655E+00 -0.0015 31 CO3-2 0.49458E-06 -6.3058 0.25630E-06 -6.5912 0.51823E+00 -0.2855 32 CaCO3,aq 0.22358E-09 -9.6506 0.22358E-09 -9.6506 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.46193E-12 -12.3354 0.38654E-12 -12.4128 0.83681E+00 -0.0774 34 CaCl+ 0.16773E-10 -10.7754 0.14036E-10 -10.8528 0.83681E+00 -0.0774 35 CaCl2,aq 0.41572E-15 -15.3812 0.41572E-15 -15.3812 0.10000E+01 0.0000 36 CaOH+ 0.79879E-07 -7.0976 0.66843E-07 -7.1749 0.83681E+00 -0.0774 37 CaSO4,aq 0.80677E-17 -17.0933 0.80677E-17 -17.0933 0.10000E+01 0.0000 38 HCl,aq 0.16946E-14 -14.7709 0.16946E-14 -14.7709 0.10000E+01 0.0000 43 FeCl+ 0.70487E-17 -17.1519 0.58984E-17 -17.2293 0.83681E+00 -0.0774 46 FeO,aq 0.21114E-09 -9.6754 0.21114E-09 -9.6754 0.10000E+01 0.0000 47 FeOH+ 0.15675E-10 -10.8048 0.13117E-10 -10.8822 0.83681E+00 -0.0774 48 HFeO2- 0.35658E-07 -7.4478 0.29782E-07 -7.5261 0.83521E+00 -0.0782 49 FeO+ 0.10984E-16 -16.9592 0.91918E-17 -17.0366 0.83681E+00 -0.0774 51 FeO2- 0.40927E-09 -9.3880 0.34182E-09 -9.4662 0.83521E+00 -0.0782 52 HFeO2,aq 0.32249E-11 -11.4915 0.32249E-11 -11.4915 0.10000E+01 0.0000 53 H2,aq 0.11626E-04 -4.9346 0.11586E-04 -4.9361 0.99655E+00 -0.0015 54 KCl,aq 0.29582E-09 -9.5290 0.29582E-09 -9.5290 0.10000E+01 0.0000 56 KOH,aq 0.75375E-06 -6.1228 0.75375E-06 -6.1228 0.10000E+01 0.0000 57 KSO4- 0.88830E-15 -15.0514 0.74192E-15 -15.1296 0.83521E+00 -0.0782 58 MgCO3,aq 0.87275E-14 -14.0591 0.87275E-14 -14.0591 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.73504E-16 -16.1337 0.61509E-16 -16.2111 0.83681E+00 -0.0774 60 MgCl+ 0.23674E-14 -14.6257 0.19811E-14 -14.7031 0.83681E+00 -0.0774 61 MgOH+ 0.68834E-10 -10.1622 0.57601E-10 -10.2396 0.83681E+00 -0.0774 63 MnO,aq 0.17890E-08 -8.7474 0.17890E-08 -8.7474 0.10000E+01 0.0000 64 MnOH+ 0.46306E-09 -9.3344 0.38749E-09 -9.4117 0.83681E+00 -0.0774 65 MnO2-2 0.20822E-10 -10.6815 0.10790E-10 -10.9670 0.51823E+00 -0.2855 66 HMnO2- 0.20996E-09 -9.6779 0.17536E-09 -9.7561 0.83521E+00 -0.0782 69 MnCl+ 0.87204E-14 -14.0595 0.72973E-14 -14.1368 0.83681E+00 -0.0774 71 NaCl,aq 0.68510E-06 -6.1642 0.68510E-06 -6.1642 0.10000E+01 0.0000 72 NaOH,aq 0.96047E-04 -4.0175 0.96047E-04 -4.0175 0.10000E+01 0.0000 74 OH- 0.93427E-02 -2.0295 0.77890E-02 -2.1085 0.83370E+00 -0.0790 79 HPO3-2 0.16401E-14 -14.7851 0.84994E-15 -15.0706 0.51823E+00 -0.2855 81 H2PO3- 0.15137E-18 -18.8200 0.12643E-18 -18.8982 0.83521E+00 -0.0782 82 H3PO4,aq 0.90593E-18 -18.0429 0.90593E-18 -18.0429 0.10000E+01 0.0000 83 H2PO4- 0.38532E-10 -10.4142 0.32213E-10 -10.4920 0.83600E+00 -0.0778 84 PO4-3 0.10670E-08 -8.9718 0.25893E-09 -9.5868 0.24267E+00 -0.6150 88 HP2O7-3 0.94697E-18 -18.0237 0.21902E-18 -18.6595 0.23128E+00 -0.6359 89 P2O7-4 0.91464E-17 -17.0388 0.70537E-18 -18.1516 0.77120E-01 -1.1128 90 H2S,aq 0.53255E-08 -8.2736 0.53071E-08 -8.2751 0.99655E+00 -0.0015 91 S2-2 0.19777E-14 -14.7038 0.10249E-14 -14.9893 0.51823E+00 -0.2855 97 SO3-2 0.10458E-17 -17.9805 0.54980E-18 -18.2598 0.52572E+00 -0.2792 99 HSO4- 0.31167E-19 -19.5063 0.26106E-19 -19.5833 0.83762E+00 -0.0770 Charge balance for all species = -.1723E-10 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.8827991E-10 -.2230205E-01 -.2244007E+02 0.0000 2 H2O 0.1000000E+01 0.5550489E+02 0.9981997E+06 0.0000 3 Cl- 0.1492646E-03 0.1499501E-03 0.5306942E+01 6.2255 4 SO4-- 0.7031886E-12 -.1635579E-04 -.1568433E+01 7.8220 5 HCO3- 0.2602289E-06 0.1420445E-04 0.8652097E+00 3.4675 6 HS- 0.2771288E-04 0.4407399E-04 0.1455082E+01 5.4943 7 Al+++ 0.9687982E-29 0.5318577E-05 0.1432538E+00 0.7391 8 H4SiO4 0.6958998E-03 0.1353357E-01 0.1298524E+04 -3.1575 9 Ca++ 0.1349546E-06 0.2316604E-06 0.9268351E-02 13.1019 10 Mg++ 0.2111290E-10 0.9317261E-10 0.2261276E-05 9.2942 11 Fe++ 0.5818613E-13 0.3629701E-07 0.2023557E-02 6.7350 12 K+ 0.1564902E-03 0.1572443E-03 0.6137881E+01 6.2467 13 Na+ 0.1985781E-01 0.2230392E-01 0.5118717E+03 8.3494 14 Mn++ 0.1848796E-10 0.2501370E-08 0.1371815E-03 9.2374 15 HPO4-- 0.4532292E-07 0.4642844E-07 0.4448412E-02 12.6313 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.1291561E+02 -.2052088E-01 -.1289509E+02 0.0000000E+00 2 H2O 0.4573064E+02 0.5107195E+02 -.5341307E+01 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.2164194E-01 -.1504952E-04 0.2165699E-01 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.2161643E-01 0.4055399E-04 -.2165699E-01 0.0000000E+00 7 Al+++ 0.2543375E+01 0.4893805E-05 0.2543370E+01 0.0000000E+00 8 H4SiO4 0.8121960E+01 0.1245270E-01 0.8109508E+01 0.0000000E+00 9 Ca++ 0.8971246E+00 0.2131586E-06 0.8971244E+00 0.0000000E+00 10 Mg++ 0.6190468E+00 0.8573131E-10 0.6190468E+00 0.0000000E+00 11 Fe++ 0.5561460E+00 0.3339813E-07 0.5561460E+00 0.0000000E+00 12 K+ 0.1656049E+00 0.1446858E-03 0.1654602E+00 0.0000000E+00 13 Na+ 0.9792488E+00 0.2052260E-01 0.9587262E+00 0.0000000E+00 14 Mn++ 0.1352409E-01 0.2301596E-08 0.1352409E-01 0.0000000E+00 15 HPO4-- 0.4615704E-02 0.4272040E-07 0.4615661E-02 0.0000000E+00 Chg. balance for solid moles: 0.2684E-14 Mass of aqueous solution: 0.921736E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 779.9990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 0.9578 -0.019 251.2 2.400 29.48 96.41 andradite 0.8663E-01 -1.062 44.02 1.644 5.167 11.44 grossular 0.2099E-01 -1.678 9.453 0.976 1.110 2.630 apatite-OH 0.1539E-02 -2.813 0.7728 -0.112 0.9071E-01 0.2456 clinochlore 0.1119 -0.951 62.19 1.794 7.300 23.66 daphnite 0.3239E-01 -1.490 23.11 1.364 2.712 7.003 chlorite-Mn 0.2705E-02 -2.568 1.918 0.283 0.2251 0.6111 diopside 0.3316E-01 -1.479 7.182 0.856 0.8430 2.195 hedenbergite 0.8600E-02 -2.065 2.134 0.329 0.2504 0.5844 microcline 0.1451 -0.838 40.40 1.606 4.742 15.78 stilbite 0.5102 -0.292 359.6 2.556 42.21 167.7 stilpnomelane-Fe 0.4065E-01 -1.391 43.82 1.642 5.143 15.14 tr.625ac.25prg.125 0.7298E-02 -2.137 6.238 0.795 0.7322 2.008 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8050E+00 0.8050E+00 1.0000 -0.094 grossular 0.1950E+00 0.1950E+00 1.0000 -0.710 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.7612E+00 0.7612E+00 1.0000 -0.118 daphnite 0.2204E+00 0.2204E+00 1.0000 -0.657 chlorite-Mn 0.1840E-01 0.1840E-01 1.0000 -1.735 diopside 0.7941E+00 0.7941E+00 1.0000 -0.100 hedenbergite 0.2059E+00 0.2059E+00 1.0000 -0.686 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 tr.625ac.25prg.125 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 851.959854 g Volume = 345.408551 cm3 Porosity: -10.3543% V(tot) - V(min): -.32409E+02 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 779.9990000 g log = 2.8921 Original solution: 1000.0103000 g Original solution / Rock added: 1.28 (Water/Rock Ratio), log = 0.1079 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0555 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9671E+00 0.9855 0.1006E+01 0.1021E+01 CO2,gas 0.3473E-08 1.0069 0.3691E-08 0.3666E-08 CH4,gas 0.1846E-01 1.0125 0.1973E-01 0.1949E-01 H2,gas 0.1440E-01 1.0006 0.1521E-01 0.1520E-01 H2S,gas 0.1388E-06 0.9959 0.1459E-06 0.1465E-06 S2,gas 0.3272E-29 1.0000 0.3453E-29 0.3453E-29 CO,gas 0.1418E-13 1.0000 0.1496E-13 0.1496E-13 SO3,gas 0.7198E-48 1.0000 0.7598E-48 0.7598E-48 SO2,gas 0.4260E-27 1.0000 0.4496E-27 0.4496E-27 HCl,gas 0.2833E-17 1.0000 0.2990E-17 0.2990E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 16 albite -0.38 -0.38 0.00 0.000 -0.13080E-10 22 andradite 39.01 39.01 0.00 0.000 -0.12132E-10 23 grossular 32.73 32.73 0.00 0.000 -0.24265E-10 32 apatite-OH -18.15 -18.15 0.00 0.000 -0.60662E-11 46 clinochlore 39.07 39.07 0.00 0.000 -0.24265E-10 47 daphnite 28.97 28.97 0.00 0.000 -0.36397E-10 48 chlorite-Mn 46.87 46.87 0.00 0.000 -0.24265E-10 67 diopside 16.18 16.18 0.00 0.000 -0.12132E-10 68 hedenbergite 14.21 14.21 0.00 0.000 -0.30331E-11 116 microcline -2.49 -2.49 0.00 0.000 -0.10616E-10 163 stilbite -7.52 -7.52 0.00 0.000 -0.33364E-10 164 stilpnomelane-Fe 13.02 13.02 0.00 0.000 0.21232E-10 245 tr.625ac.25prg.125 45.16 45.16 0.00 0.000 0.36397E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -16.79 -10.13 -3.377 0.17300E+05 -8.433 3 CH4,gas 4.54 1.14 -3.40 -0.851 0.58120E+04 -1.705 4 H2,gas 8.00 4.48 -3.52 -2.010 0.60049E+04 -1.818 5 H2S,gas -6.23 -14.77 -8.53 -4.267 0.14573E+05 -6.836 6 S2,gas -7.34 -38.50 -31.16 -4.794 0.53206E+05 -29.462 7 CO,gas 3.21 -12.31 -15.52 -4.777 0.26507E+05 -13.825 8 SO3,gas 17.12 -32.70 -49.82 -12.455 0.85063E+05 -48.119 9 SO2,gas 0.83 -28.21 -29.05 -7.746 0.49596E+05 -27.347 10 HCl,gas 5.19 -14.03 -19.22 -9.612 0.32823E+05 -17.524 11 acmite 7.71 6.53 -1.18 -0.123 0.20178E+04 15 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 19 spessartine 24.46 19.72 -4.74 -0.237 0.80920E+04 20 analcite 3.32 2.77 -0.55 -0.061 0.93616E+03 26 annite 20.12 17.72 -2.40 -0.134 0.41063E+04 27 phlogopite 27.06 25.40 -1.67 -0.093 0.28486E+04 29 anorthite 12.71 8.27 -4.45 -0.342 0.75899E+04 35 aragonite 0.97 -3.69 -4.66 -1.552 0.79510E+04 36 brucite 12.57 9.29 -3.27 -0.655 0.55908E+04 37 calcite 0.81 -3.69 -4.50 -1.501 0.76868E+04 38 carnegieite-low 9.02 5.93 -3.09 -0.442 0.52799E+04 39 carnegieite-high 10.09 5.93 -4.16 -0.595 0.71069E+04 40 carpholite-Mg 8.58 4.46 -4.12 -0.275 0.70425E+04 41 carpholite-Fe 6.71 1.90 -4.81 -0.321 0.82203E+04 42 celadonite 5.34 3.65 -1.69 -0.099 0.28878E+04 43 celadonite-Fe 3.88 1.09 -2.79 -0.164 0.47561E+04 44 chrysotile 23.89 21.57 -2.32 -0.194 0.39691E+04 49 chlorite-Al-free 47.17 43.14 -4.04 -0.168 0.68934E+04 51 chloritoid-Fe 9.17 5.06 -4.12 -0.275 0.70311E+04 52 chloritoid-Mn 11.40 7.56 -3.84 -0.256 0.65616E+04 54 coesite -2.38 -3.16 -0.78 -0.260 0.13342E+04 61 cristobalite -2.56 -3.16 -0.60 -0.199 0.10196E+04 63 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71234E+04 65 diaspore 2.87 0.74 -2.13 -0.356 0.36447E+04 66 diamond -3.10 -7.83 -4.72 -1.350 0.80655E+04 71 enstatite 17.26 12.27 -4.99 -0.499 0.85225E+04 73 clinoenstatite 17.17 12.27 -4.89 -0.489 0.83541E+04 75 epidote 24.67 22.70 -1.97 -0.095 0.33582E+04 76 clinozoisite 22.81 18.95 -3.86 -0.175 0.65862E+04 77 epidote-Fe 29.84 26.46 -3.38 -0.176 0.57768E+04 78 fayalite 14.05 10.31 -3.73 -0.533 0.63743E+04 79 ferrosilite 11.15 7.16 -3.99 -0.399 0.68203E+04 83 gibbsite 4.08 0.74 -3.34 -0.477 0.57033E+04 84 glaucophane 22.97 20.80 -2.17 -0.059 0.37132E+04 85 glaucophane-Fe 17.28 13.12 -4.15 -0.112 0.70919E+04 86 graphite -3.55 -7.83 -4.28 -1.223 0.73078E+04 87 greenalite 16.14 13.89 -2.25 -0.187 0.38408E+04 90 hematite 12.57 8.99 -3.58 -0.434 0.61113E+04 91 heulandite -5.83 -7.52 -1.69 -0.077 0.28938E+04 95 jadeite 4.22 2.77 -1.44 -0.144 0.24617E+04 97 kalsilite 7.58 3.83 -3.76 -0.536 0.64124E+04 98 kaolinite -1.33 -4.84 -3.50 -0.319 0.59828E+04 101 laumontite 2.88 1.95 -0.93 -0.062 0.15933E+04 102 lawsonite 9.62 8.27 -1.35 -0.090 0.23066E+04 103 leucite 4.12 0.67 -3.45 -0.345 0.58872E+04 105 lizardite 23.24 21.57 -1.68 -0.140 0.28617E+04 107 magnetite 20.09 15.72 -4.37 -0.356 0.74537E+04 108 minnesotaite 10.39 7.58 -2.81 -0.165 0.48030E+04 112 manganosite 14.06 9.24 -4.82 -1.205 0.82312E+04 120 muscovite 2.58 -1.01 -3.59 -0.211 0.61310E+04 121 paragonite 4.24 1.09 -3.15 -0.185 0.53701E+04 122 nepheline 8.34 5.93 -2.41 -0.344 0.41123E+04 128 periclase-Fe 11.63 6.73 -4.89 -1.223 0.83523E+04 134 phlogopite-Na 29.65 27.50 -2.15 -0.119 0.36675E+04 136 prehnite 19.37 18.21 -1.16 -0.068 0.19845E+04 137 prehnite-Fe 22.50 21.96 -0.53 -0.032 0.91147E+03 138 pumpellyite-Fe 46.27 43.89 -2.38 -0.053 0.40570E+04 139 pumpellyite-Mg 48.99 46.45 -2.54 -0.056 0.43408E+04 143 pyrrhotite -4.26 -8.03 -3.77 -1.257 0.64369E+04 144 pyrrhotiteFe0.875 -6.02 -9.43 -3.41 -1.255 0.58242E+04 145 pyroxmangite 7.40 6.08 -1.32 -0.264 0.22517E+04 146 pyrophyllite -6.18 -11.15 -4.98 -0.311 0.84960E+04 147 quartz -2.99 -3.16 -0.17 -0.056 0.28689E+03 152 rhodonite 7.45 6.08 -1.37 -0.273 0.23319E+04 153 sanidine -1.28 -2.49 -1.21 -0.093 0.20677E+04 165 stilpnomelane-Mg 27.44 25.81 -1.63 -0.049 0.27801E+04 171 talc 16.49 15.25 -1.24 -0.073 0.21141E+04 174 tephroite 18.09 15.32 -2.77 -0.395 0.47270E+04 178 tridymite -2.63 -3.16 -0.53 -0.177 0.90686E+03 179 tremolite 47.87 47.42 -0.45 -0.012 0.77497E+03 180 ferroactinolite 38.45 34.62 -3.83 -0.104 0.65452E+04 181 troilite-low -4.41 -8.03 -3.62 -1.206 0.61798E+04 183 vesuvianite 223.47 218.82 -4.65 -0.036 0.79407E+04 187 wairakite 3.95 1.95 -2.00 -0.118 0.34152E+04 188 walstromite 11.51 9.94 -1.56 -0.313 0.26719E+04 189 wollastonite 10.46 9.94 -0.52 -0.103 0.88229E+03 190 pseudo-wollastonite 11.00 9.94 -1.06 -0.211 0.18021E+04 191 zoisite 22.85 18.95 -3.90 -0.177 0.66602E+04 192 akaganeite 7.75 4.49 -3.26 -0.705 0.55682E+04 199 chalcedony -2.80 -3.16 -0.36 -0.118 0.60618E+03 201 montmorillonite-Ca -2.29 -6.17 -3.88 -0.240 0.66179E+04 202 montmorillonite-K -2.24 -6.27 -4.03 -0.247 0.68815E+04 203 montmorillonite-Mg -2.48 -6.79 -4.31 -0.267 0.73677E+04 204 montmorillonite-Na -2.04 -5.57 -3.54 -0.216 0.60364E+04 205 nontronite-Ca 3.21 -0.20 -3.41 -0.221 0.58218E+04 206 nontronite-H 2.53 -2.36 -4.89 -0.328 0.83488E+04 207 nontronite-K 3.34 -0.30 -3.64 -0.233 0.62086E+04 208 nontronite-Mg 3.07 -0.82 -3.90 -0.253 0.66557E+04 209 nontronite-Na 3.52 0.40 -3.12 -0.200 0.53295E+04 224 tobermorite 9.82 7.76 -2.07 -0.564 0.35287E+04 230 alabandite -0.98 -5.53 -4.55 -1.517 0.77688E+04 233 boehmite 4.41 0.74 -3.67 -0.611 0.62617E+04 235 ferrous-oxide 9.81 6.73 -3.08 -0.769 0.52532E+04 240 silica-amorphous -2.09 -3.16 -1.07 -0.355 0.18204E+04 242 an20ab80 2.02 1.35 -0.67 -0.052 0.11471E+04 243 an25ab75 2.65 1.78 -0.87 -0.067 0.14809E+04 244 an30ab70 3.28 2.21 -1.07 -0.082 0.18242E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 20.0000000 g Current total amount of reactant added: 779.9990000 g New total amount of reactant added: 799.9990000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.1586E-10 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 11 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 799.9990000 Water: Moles liquid = 0.5096E+02 kg liquid = 0.9181E+00 Moles total = 0.4548E+02 kg total = 0.8193E+00 Activity = 1.0000 Stoichiometric ionic strength = .1132752E-01 Osmotic coef. = 0.9694 True ionic strength = .2001558E-01 Chg. balance for total moles = -.1586E-10 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.88281E-10 -10.0541 0.74179E-10 -10.1297 0.84026E+00 -0.0756 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.14959E-03 -3.8251 0.12494E-03 -3.9033 0.83521E+00 -0.0782 4 SO4-- 0.70474E-12 -12.1520 0.36599E-12 -12.4365 0.51933E+00 -0.2846 5 HCO3- 0.26080E-06 -6.5837 0.21814E-06 -6.6613 0.83643E+00 -0.0776 6 HS- 0.27774E-04 -4.5564 0.23200E-04 -4.6345 0.83533E+00 -0.0781 7 Al+++ 0.96883E-29 -29.0138 0.22385E-29 -29.6500 0.23105E+00 -0.6363 8 H4SiO4 0.69590E-03 -3.1575 0.69590E-03 -3.1575 0.10000E+01 0.0000 9 Ca++ 0.13496E-06 -6.8698 0.69572E-07 -7.1576 0.51551E+00 -0.2878 10 Mg++ 0.21113E-10 -10.6754 0.10834E-10 -10.9652 0.51316E+00 -0.2898 11 Fe++ 0.58187E-13 -13.2352 0.29892E-13 -13.5244 0.51372E+00 -0.2893 12 K+ 0.15649E-03 -3.8055 0.13093E-03 -3.8830 0.83663E+00 -0.0775 13 Na+ 0.19858E-01 -1.7021 0.16583E-01 -1.7803 0.83505E+00 -0.0783 14 Mn++ 0.18494E-10 -10.7330 0.95084E-11 -11.0219 0.51414E+00 -0.2889 15 HPO4-- 0.45322E-07 -7.3437 0.23540E-07 -7.6282 0.51940E+00 -0.2845 16 HSiO3- 0.10488E-01 -1.9793 0.87598E-02 -2.0575 0.83521E+00 -0.0782 17 Ca(HSiO3)+ 0.16586E-07 -7.7803 0.13879E-07 -7.8576 0.83681E+00 -0.0774 18 Mg(HSiO3)+ 0.32145E-11 -11.4929 0.26899E-11 -11.5703 0.83681E+00 -0.0774 19 NaHSiO3,aq 0.23494E-02 -2.6290 0.23494E-02 -2.6290 0.10000E+01 0.0000 20 AlO+ 0.66137E-16 -16.1796 0.55344E-16 -16.2569 0.83681E+00 -0.0774 22 HAlO2,aq 0.14858E-09 -9.8280 0.14858E-09 -9.8280 0.10000E+01 0.0000 23 AlO2- 0.53183E-05 -5.2742 0.44339E-05 -5.3532 0.83370E+00 -0.0790 24 CH4,aq 0.13479E-04 -4.8703 0.13432E-04 -4.8719 0.99655E+00 -0.0015 25 C2H6,aq 0.26716E-14 -14.5732 0.26623E-14 -14.5747 0.99655E+00 -0.0015 29 CO,aq 0.10063E-16 -16.9973 0.10063E-16 -16.9973 0.10000E+01 0.0000 30 CO2,aq 0.34696E-10 -10.4597 0.34576E-10 -10.4612 0.99655E+00 -0.0015 31 CO3-2 0.49567E-06 -6.3048 0.25687E-06 -6.5903 0.51822E+00 -0.2855 32 CaCO3,aq 0.22408E-09 -9.6496 0.22408E-09 -9.6496 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.46295E-12 -12.3345 0.38740E-12 -12.4118 0.83681E+00 -0.0774 34 CaCl+ 0.16810E-10 -10.7744 0.14067E-10 -10.8518 0.83681E+00 -0.0774 35 CaCl2,aq 0.41755E-15 -15.3793 0.41755E-15 -15.3793 0.10000E+01 0.0000 36 CaOH+ 0.79880E-07 -7.0976 0.66844E-07 -7.1749 0.83681E+00 -0.0774 37 CaSO4,aq 0.80857E-17 -17.0923 0.80857E-17 -17.0923 0.10000E+01 0.0000 38 HCl,aq 0.16983E-14 -14.7700 0.16983E-14 -14.7700 0.10000E+01 0.0000 43 FeCl+ 0.70642E-17 -17.1509 0.59114E-17 -17.2283 0.83681E+00 -0.0774 46 FeO,aq 0.21113E-09 -9.6754 0.21113E-09 -9.6754 0.10000E+01 0.0000 47 FeOH+ 0.15675E-10 -10.8048 0.13117E-10 -10.8822 0.83681E+00 -0.0774 48 HFeO2- 0.35657E-07 -7.4479 0.29781E-07 -7.5261 0.83521E+00 -0.0782 49 FeO+ 0.10985E-16 -16.9592 0.91919E-17 -17.0366 0.83681E+00 -0.0774 51 FeO2- 0.40926E-09 -9.3880 0.34182E-09 -9.4662 0.83521E+00 -0.0782 52 HFeO2,aq 0.32249E-11 -11.4915 0.32249E-11 -11.4915 0.10000E+01 0.0000 53 H2,aq 0.11626E-04 -4.9346 0.11586E-04 -4.9361 0.99655E+00 -0.0015 54 KCl,aq 0.29647E-09 -9.5280 0.29647E-09 -9.5280 0.10000E+01 0.0000 56 KOH,aq 0.75375E-06 -6.1228 0.75375E-06 -6.1228 0.10000E+01 0.0000 57 KSO4- 0.89028E-15 -15.0505 0.74356E-15 -15.1287 0.83521E+00 -0.0782 58 MgCO3,aq 0.87468E-14 -14.0581 0.87468E-14 -14.0581 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.73668E-16 -16.1327 0.61646E-16 -16.2101 0.83681E+00 -0.0774 60 MgCl+ 0.23727E-14 -14.6248 0.19855E-14 -14.7021 0.83681E+00 -0.0774 61 MgOH+ 0.68834E-10 -10.1622 0.57601E-10 -10.2396 0.83681E+00 -0.0774 63 MnO,aq 0.17895E-08 -8.7473 0.17895E-08 -8.7473 0.10000E+01 0.0000 64 MnOH+ 0.46320E-09 -9.3342 0.38761E-09 -9.4116 0.83681E+00 -0.0774 65 MnO2-2 0.20827E-10 -10.6814 0.10793E-10 -10.9668 0.51822E+00 -0.2855 66 HMnO2- 0.21001E-09 -9.6778 0.17541E-09 -9.7560 0.83521E+00 -0.0782 69 MnCl+ 0.87421E-14 -14.0584 0.73155E-14 -14.1358 0.83681E+00 -0.0774 71 NaCl,aq 0.68660E-06 -6.1633 0.68660E-06 -6.1633 0.10000E+01 0.0000 72 NaOH,aq 0.96047E-04 -4.0175 0.96047E-04 -4.0175 0.10000E+01 0.0000 74 OH- 0.93426E-02 -2.0295 0.77889E-02 -2.1085 0.83370E+00 -0.0790 79 HPO3-2 0.16401E-14 -14.7851 0.84992E-15 -15.0706 0.51822E+00 -0.2855 81 H2PO3- 0.15137E-18 -18.8200 0.12643E-18 -18.8982 0.83521E+00 -0.0782 82 H3PO4,aq 0.90593E-18 -18.0429 0.90593E-18 -18.0429 0.10000E+01 0.0000 83 H2PO4- 0.38532E-10 -10.4142 0.32213E-10 -10.4920 0.83600E+00 -0.0778 84 PO4-3 0.10670E-08 -8.9718 0.25892E-09 -9.5868 0.24267E+00 -0.6150 88 HP2O7-3 0.94696E-18 -18.0237 0.21901E-18 -18.6595 0.23128E+00 -0.6359 89 P2O7-4 0.91462E-17 -17.0388 0.70535E-18 -18.1516 0.77119E-01 -1.1128 90 H2S,aq 0.53372E-08 -8.2727 0.53188E-08 -8.2742 0.99655E+00 -0.0015 91 S2-2 0.19864E-14 -14.7019 0.10294E-14 -14.9874 0.51822E+00 -0.2855 97 SO3-2 0.10481E-17 -17.9796 0.55101E-18 -18.2588 0.52572E+00 -0.2792 99 HSO4- 0.31236E-19 -19.5053 0.26164E-19 -19.5823 0.83762E+00 -0.0770 Charge balance for all species = -.1728E-10 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.8828092E-10 -.2230190E-01 -.2243991E+02 0.0000 2 H2O 0.1000000E+01 0.5550489E+02 0.9981997E+06 0.0000 3 Cl- 0.1495912E-03 0.1502781E-03 0.5318551E+01 6.2264 4 SO4-- 0.7047431E-12 -.1638518E-04 -.1571251E+01 7.8229 5 HCO3- 0.2608035E-06 0.1423552E-04 0.8671024E+00 3.4685 6 HS- 0.2777350E-04 0.4416402E-04 0.1458054E+01 5.4952 7 Al+++ 0.9688261E-29 0.5318471E-05 0.1432510E+00 0.7391 8 H4SiO4 0.6959021E-03 0.1353351E-01 0.1298518E+04 -3.1575 9 Ca++ 0.1349574E-06 0.2316646E-06 0.9268519E-02 13.1019 10 Mg++ 0.2111334E-10 0.9317353E-10 0.2261299E-05 9.2942 11 Fe++ 0.5818748E-13 0.3629661E-07 0.2023534E-02 6.7350 12 K+ 0.1564920E-03 0.1572461E-03 0.6137951E+01 6.2467 13 Na+ 0.1985804E-01 0.2230416E-01 0.5118771E+03 8.3494 14 Mn++ 0.1849362E-10 0.2502077E-08 0.1372202E-03 9.2375 15 HPO4-- 0.4532234E-07 0.4642785E-07 0.4448355E-02 12.6313 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.1324678E+02 -.2047595E-01 -.1322631E+02 0.0000000E+00 2 H2O 0.4547993E+02 0.5096047E+02 -.5480532E+01 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.2219620E-01 -.1504365E-04 0.2221125E-01 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.2217070E-01 0.4054812E-04 -.2221125E-01 0.0000000E+00 7 Al+++ 0.2608590E+01 0.4883025E-05 0.2608585E+01 0.0000000E+00 8 H4SiO4 0.8330216E+01 0.1242546E-01 0.8317790E+01 0.0000000E+00 9 Ca++ 0.9201274E+00 0.2126972E-06 0.9201272E+00 0.0000000E+00 10 Mg++ 0.6349198E+00 0.8554502E-10 0.6349198E+00 0.0000000E+00 11 Fe++ 0.5704062E+00 0.3332485E-07 0.5704061E+00 0.0000000E+00 12 K+ 0.1698512E+00 0.1443716E-03 0.1697068E+00 0.0000000E+00 13 Na+ 0.1004354E+01 0.2047802E-01 0.9838757E+00 0.0000000E+00 14 Mn++ 0.1387086E-01 0.2297221E-08 0.1387086E-01 0.0000000E+00 15 HPO4-- 0.4734055E-02 0.4262660E-07 0.4734013E-02 0.0000000E+00 Chg. balance for solid moles: -.1743E-14 Mass of aqueous solution: 0.919724E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 799.9990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 0.9829 -0.007 257.7 2.411 29.50 98.94 andradite 0.8884E-01 -1.051 45.15 1.655 5.167 11.73 grossular 0.2152E-01 -1.667 9.695 0.987 1.109 2.697 apatite-OH 0.1578E-02 -2.802 0.7927 -0.101 0.9071E-01 0.2519 clinochlore 0.1147 -0.940 63.77 1.805 7.297 24.25 daphnite 0.3321E-01 -1.479 23.69 1.375 2.712 7.180 chlorite-Mn 0.2774E-02 -2.557 1.967 0.294 0.2251 0.6268 diopside 0.3425E-01 -1.465 7.418 0.870 0.8489 2.267 hedenbergite 0.8882E-02 -2.051 2.204 0.343 0.2522 0.6036 microcline 0.1489 -0.827 41.43 1.617 4.742 16.19 stilbite 0.5231 -0.281 368.6 2.567 42.19 171.9 stilpnomelane-Fe 0.4169E-01 -1.380 44.94 1.653 5.143 15.52 tr.625ac.25prg.125 0.7464E-02 -2.127 6.380 0.805 0.7302 2.054 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8050E+00 0.8050E+00 1.0000 -0.094 grossular 0.1950E+00 0.1950E+00 1.0000 -0.710 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.7612E+00 0.7612E+00 1.0000 -0.118 daphnite 0.2204E+00 0.2204E+00 1.0000 -0.657 chlorite-Mn 0.1841E-01 0.1841E-01 1.0000 -1.735 diopside 0.7941E+00 0.7941E+00 1.0000 -0.100 hedenbergite 0.2059E+00 0.2059E+00 1.0000 -0.686 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 tr.625ac.25prg.125 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 873.809985 g Volume = 354.249163 cm3 Porosity: -10.3581% V(tot) - V(min): -.33250E+02 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 799.9990000 g log = 2.9031 Original solution: 1000.0103000 g Original solution / Rock added: 1.25 (Water/Rock Ratio), log = 0.0969 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0555 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9671E+00 0.9855 0.1006E+01 0.1021E+01 CO2,gas 0.3481E-08 1.0069 0.3699E-08 0.3674E-08 CH4,gas 0.1850E-01 1.0125 0.1977E-01 0.1953E-01 H2,gas 0.1440E-01 1.0006 0.1521E-01 0.1520E-01 H2S,gas 0.1391E-06 0.9959 0.1462E-06 0.1468E-06 S2,gas 0.3286E-29 1.0000 0.3468E-29 0.3468E-29 CO,gas 0.1421E-13 1.0000 0.1500E-13 0.1500E-13 SO3,gas 0.7214E-48 1.0000 0.7614E-48 0.7614E-48 SO2,gas 0.4269E-27 1.0000 0.4506E-27 0.4506E-27 HCl,gas 0.2839E-17 1.0000 0.2997E-17 0.2997E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 16 albite -0.38 -0.38 0.00 0.000 -0.94784E-12 22 andradite 39.01 39.01 0.00 0.000 0.00000E+00 23 grossular 32.73 32.73 0.00 0.000 -0.12132E-10 32 apatite-OH -18.15 -18.15 0.00 0.000 -0.60662E-11 46 clinochlore 39.07 39.07 0.00 0.000 -0.12132E-10 47 daphnite 28.97 28.97 0.00 0.000 0.18198E-10 48 chlorite-Mn 46.87 46.87 0.00 0.000 -0.12132E-10 67 diopside 16.18 16.18 0.00 0.000 0.60662E-11 68 hedenbergite 14.21 14.21 0.00 0.000 0.90992E-11 116 microcline -2.49 -2.49 0.00 0.000 0.15165E-11 163 stilbite -7.52 -7.52 0.00 0.000 -0.90992E-11 164 stilpnomelane-Fe 13.02 13.02 0.00 0.000 0.21232E-10 245 tr.625ac.25prg.125 45.16 45.16 0.00 0.000 -0.36397E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -16.79 -10.13 -3.377 0.17298E+05 -8.432 3 CH4,gas 4.54 1.14 -3.40 -0.851 0.58104E+04 -1.704 4 H2,gas 8.00 4.48 -3.52 -2.010 0.60049E+04 -1.818 5 H2S,gas -6.23 -14.76 -8.53 -4.267 0.14572E+05 -6.835 6 S2,gas -7.34 -38.49 -31.16 -4.794 0.53203E+05 -29.460 7 CO,gas 3.21 -12.31 -15.52 -4.776 0.26505E+05 -13.824 8 SO3,gas 17.12 -32.70 -49.82 -12.454 0.85062E+05 -48.118 9 SO2,gas 0.83 -28.21 -29.05 -7.745 0.49594E+05 -27.346 10 HCl,gas 5.19 -14.03 -19.22 -9.611 0.32822E+05 -17.523 11 acmite 7.71 6.53 -1.18 -0.123 0.20177E+04 15 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 19 spessartine 24.46 19.72 -4.74 -0.237 0.80914E+04 20 analcite 3.32 2.77 -0.55 -0.061 0.93617E+03 26 annite 20.12 17.72 -2.40 -0.134 0.41063E+04 27 phlogopite 27.06 25.40 -1.67 -0.093 0.28487E+04 29 anorthite 12.71 8.27 -4.45 -0.342 0.75899E+04 35 aragonite 0.97 -3.69 -4.66 -1.552 0.79493E+04 36 brucite 12.57 9.29 -3.27 -0.655 0.55908E+04 37 calcite 0.81 -3.69 -4.50 -1.500 0.76851E+04 38 carnegieite-low 9.02 5.93 -3.09 -0.442 0.52799E+04 39 carnegieite-high 10.09 5.93 -4.16 -0.595 0.71069E+04 40 carpholite-Mg 8.58 4.46 -4.12 -0.275 0.70425E+04 41 carpholite-Fe 6.71 1.90 -4.81 -0.321 0.82203E+04 42 celadonite 5.34 3.65 -1.69 -0.099 0.28879E+04 43 celadonite-Fe 3.88 1.09 -2.79 -0.164 0.47561E+04 44 chrysotile 23.89 21.57 -2.32 -0.194 0.39691E+04 49 chlorite-Al-free 47.17 43.14 -4.04 -0.168 0.68934E+04 51 chloritoid-Fe 9.17 5.06 -4.12 -0.275 0.70311E+04 52 chloritoid-Mn 11.40 7.56 -3.84 -0.256 0.65614E+04 54 coesite -2.38 -3.16 -0.78 -0.260 0.13342E+04 61 cristobalite -2.56 -3.16 -0.60 -0.199 0.10196E+04 63 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71234E+04 65 diaspore 2.87 0.74 -2.13 -0.356 0.36447E+04 66 diamond -3.10 -7.83 -4.72 -1.349 0.80639E+04 71 enstatite 17.26 12.27 -4.99 -0.499 0.85225E+04 73 clinoenstatite 17.17 12.27 -4.89 -0.489 0.83541E+04 75 epidote 24.67 22.70 -1.97 -0.095 0.33582E+04 76 clinozoisite 22.81 18.95 -3.86 -0.175 0.65862E+04 77 epidote-Fe 29.84 26.46 -3.38 -0.176 0.57768E+04 78 fayalite 14.05 10.31 -3.73 -0.533 0.63743E+04 79 ferrosilite 11.15 7.16 -3.99 -0.399 0.68203E+04 83 gibbsite 4.08 0.74 -3.34 -0.477 0.57033E+04 84 glaucophane 22.97 20.80 -2.17 -0.059 0.37132E+04 85 glaucophane-Fe 17.28 13.12 -4.15 -0.112 0.70919E+04 86 graphite -3.55 -7.83 -4.28 -1.223 0.73062E+04 87 greenalite 16.14 13.89 -2.25 -0.187 0.38408E+04 90 hematite 12.57 8.99 -3.58 -0.434 0.61113E+04 91 heulandite -5.83 -7.52 -1.69 -0.077 0.28938E+04 95 jadeite 4.22 2.77 -1.44 -0.144 0.24617E+04 97 kalsilite 7.58 3.83 -3.76 -0.536 0.64124E+04 98 kaolinite -1.33 -4.84 -3.50 -0.319 0.59828E+04 101 laumontite 2.88 1.95 -0.93 -0.062 0.15933E+04 102 lawsonite 9.62 8.27 -1.35 -0.090 0.23066E+04 103 leucite 4.12 0.67 -3.45 -0.345 0.58872E+04 105 lizardite 23.24 21.57 -1.68 -0.140 0.28617E+04 107 magnetite 20.09 15.72 -4.37 -0.356 0.74537E+04 108 minnesotaite 10.39 7.58 -2.81 -0.165 0.48030E+04 112 manganosite 14.06 9.24 -4.82 -1.205 0.82310E+04 120 muscovite 2.58 -1.01 -3.59 -0.211 0.61310E+04 121 paragonite 4.24 1.09 -3.15 -0.185 0.53701E+04 122 nepheline 8.34 5.93 -2.41 -0.344 0.41123E+04 128 periclase-Fe 11.63 6.73 -4.89 -1.223 0.83523E+04 134 phlogopite-Na 29.65 27.50 -2.15 -0.119 0.36675E+04 136 prehnite 19.37 18.21 -1.16 -0.068 0.19845E+04 137 prehnite-Fe 22.50 21.96 -0.53 -0.032 0.91148E+03 138 pumpellyite-Fe 46.27 43.89 -2.38 -0.053 0.40570E+04 139 pumpellyite-Mg 48.99 46.45 -2.54 -0.056 0.43408E+04 143 pyrrhotite -4.26 -8.03 -3.77 -1.256 0.64353E+04 144 pyrrhotiteFe0.875 -6.02 -9.43 -3.41 -1.254 0.58226E+04 145 pyroxmangite 7.40 6.08 -1.32 -0.264 0.22514E+04 146 pyrophyllite -6.18 -11.15 -4.98 -0.311 0.84960E+04 147 quartz -2.99 -3.16 -0.17 -0.056 0.28688E+03 152 rhodonite 7.45 6.08 -1.37 -0.273 0.23317E+04 153 sanidine -1.28 -2.49 -1.21 -0.093 0.20677E+04 165 stilpnomelane-Mg 27.44 25.81 -1.63 -0.049 0.27801E+04 171 talc 16.49 15.25 -1.24 -0.073 0.21141E+04 174 tephroite 18.09 15.32 -2.77 -0.395 0.47265E+04 178 tridymite -2.63 -3.16 -0.53 -0.177 0.90686E+03 179 tremolite 47.87 47.42 -0.45 -0.012 0.77497E+03 180 ferroactinolite 38.45 34.62 -3.83 -0.104 0.65452E+04 181 troilite-low -4.41 -8.03 -3.62 -1.206 0.61781E+04 183 vesuvianite 223.47 218.82 -4.65 -0.036 0.79408E+04 187 wairakite 3.95 1.95 -2.00 -0.118 0.34152E+04 188 walstromite 11.51 9.94 -1.56 -0.313 0.26719E+04 189 wollastonite 10.46 9.94 -0.52 -0.103 0.88229E+03 190 pseudo-wollastonite 11.00 9.94 -1.06 -0.211 0.18021E+04 191 zoisite 22.85 18.95 -3.90 -0.177 0.66603E+04 192 akaganeite 7.75 4.49 -3.26 -0.705 0.55682E+04 199 chalcedony -2.80 -3.16 -0.36 -0.118 0.60618E+03 201 montmorillonite-Ca -2.29 -6.17 -3.88 -0.240 0.66179E+04 202 montmorillonite-K -2.24 -6.27 -4.03 -0.247 0.68815E+04 203 montmorillonite-Mg -2.48 -6.79 -4.31 -0.267 0.73677E+04 204 montmorillonite-Na -2.04 -5.57 -3.54 -0.216 0.60364E+04 205 nontronite-Ca 3.21 -0.20 -3.41 -0.221 0.58218E+04 206 nontronite-H 2.53 -2.36 -4.89 -0.328 0.83488E+04 207 nontronite-K 3.34 -0.30 -3.64 -0.233 0.62086E+04 208 nontronite-Mg 3.07 -0.82 -3.90 -0.253 0.66556E+04 209 nontronite-Na 3.52 0.40 -3.12 -0.200 0.53295E+04 224 tobermorite 9.82 7.76 -2.07 -0.564 0.35287E+04 230 alabandite -0.98 -5.53 -4.55 -1.516 0.77670E+04 233 boehmite 4.41 0.74 -3.67 -0.611 0.62617E+04 235 ferrous-oxide 9.81 6.73 -3.08 -0.769 0.52532E+04 240 silica-amorphous -2.09 -3.16 -1.07 -0.355 0.18204E+04 242 an20ab80 2.02 1.35 -0.67 -0.052 0.11471E+04 243 an25ab75 2.65 1.78 -0.87 -0.067 0.14809E+04 244 an30ab70 3.28 2.21 -1.07 -0.082 0.18242E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 20.0000000 g Current total amount of reactant added: 799.9990000 g New total amount of reactant added: 819.9990000 g Mixing fraction reached given limit of 0.8000E+03 TOTMIX = 0.8200E+03 Execution stopped.