File SKIP_SPECIES.TXT lists species and minerals omitted from the calculations due to given T, P, option switches, or suppression in CHIMRUN, or are suppressed in the SOLTHERM database. It also lists minerals for which density is not specified in SOLTHERM. This is an extended P(to 5 kB), T(to 600 C) run (CON_FLAG = 1). methanol,aq is suppressed in SOLTHERM data file. methanol,aq is suppressed in SOLTHERM data file. CuCl4-3 is suppressed in SOLTHERM data file. H2BO3- is suppressed in SOLTHERM data file. UO2CO3,aq is suppressed in SOLTHERM data file. UO2SO4,aq is suppressed in SOLTHERM data file. UO2Cl2,aq is suppressed in SOLTHERM data file. UO2F2,aq is suppressed in SOLTHERM data file. PO4-3 is suppressed in SOLTHERM data file. H2PO4- is suppressed in SOLTHERM data file. H3PO4 is suppressed in SOLTHERM data file. O2,gas is suppressed in THIS RUN. O2,gas is suppressed in THIS RUN. amesite is suppressed in SOLTHERM data file. antigorite is suppressed in SOLTHERM data file. goethite is suppressed in THIS RUN. goethite is suppressed in THIS RUN. riebeckite is suppressed in THIS RUN. riebeckite is suppressed in THIS RUN. sapphirine-Fe(221) is suppressed in SOLTHERM data file. sapphirine(221) is suppressed in SOLTHERM data file. talc-prl is suppressed in SOLTHERM data file. PrO1.833(s) is suppressed in SOLTHERM data file. niter-NH4 is suppressed in SOLTHERM data file. FMQ_HS-1 is suppressed in THIS RUN. kf-ab-equil is suppressed in THIS RUN. ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Species No. Charge Tot.moles Trial molality Gamma Mixing solution H+ 1 1. -0.13247E+02 0.88281E-10 0.8403 0.00000000E+00 H2O 2 0. 0.45480E+02 0.10000E+01 1.0000 0.00000000E+00 Cl- 3 -1. 0.13797E-03 0.14959E-03 0.8352 0.00000000E+00 SO4-- 4 -2. 0.22196E-01 0.70474E-12 0.5193 0.00000000E+00 HCO3- 5 -1. 0.13070E-04 0.26080E-06 0.8364 0.00000000E+00 HS- 6 -1. -0.22171E-01 0.27774E-04 0.8353 0.00000000E+00 Al+++ 7 3. 0.26086E+01 0.96883E-29 0.2311 0.00000000E+00 H4SiO4 8 0. 0.83302E+01 0.69590E-03 1.0000 0.00000000E+00 Ca++ 9 2. 0.92013E+00 0.13496E-06 0.5155 0.00000000E+00 Mg++ 10 2. 0.63492E+00 0.21113E-10 0.5132 0.00000000E+00 Fe++ 11 2. 0.57041E+00 0.58187E-13 0.5137 0.00000000E+00 K+ 12 1. 0.16985E+00 0.15649E-03 0.8366 0.00000000E+00 Na+ 13 1. 0.10044E+01 0.19858E-01 0.8351 0.00000000E+00 Mn++ 14 2. 0.13871E-01 0.18494E-10 0.5141 0.00000000E+00 HPO4-- 15 -2. 0.47341E-02 0.45322E-07 0.5194 0.00000000E+00 Chg. balance for total moles = 0.3298E-10 Max. difference allowed = 0.1380E-07 The following parameters were given: ERPC = 0.1000E-11 pH = 0.0000 PFLUID = 50.0000 SLIM = 0.200000E+04 TEMP = 100.0000 SINC = 0.4000E+02 TEMPC = 0.0000 TOTMIX = 0.799999E+03 ENTH = 0.0000 SENTH = 0.0000 DENTH = 0.0000 TOTWAT = 90.0000 SOLMIN = 0.0000E+00 RM = 0.0000 AQGRM = 1000.0103 SUPRNT = 0.1000E-19 VBOX-1 = 320.9996 RHOFRS = 0.0000 RHOROC = 2.5000 The following options were selected: CONFLG = 1 C = 3 IFRAC = 0 IPUNCH = 2 NLOOP = 400 ISTEP = 2 LIMSOL = 1 LOOC = 0 IENTH = 0 ITREF = 0 IDEAL = 0 IPSAT = 1 INCREM = 0 INCP = 0 MINSOL = 1 NEUT = 0 AWAT = 0 CHGF = 0 Of the derived species, only those with molality > 0.10E-19 will appear in the output Species No. Charge Log K(diss) Species No. Charge Log K(diss) HSiO3- 16 -1. 9.0298 MnO2-2 65 -2. 40.4638 Ca(HSiO3)+ 17 1. 7.6723 HMnO2- 66 -1. 29.1232 Mg(HSiO3)+ 18 1. 7.5773 MnO4- 67 -1. 83.3111 NaHSiO3,aq 19 0. 7.8210 MnO4-2 68 -2. 81.3005 AlO+ 20 1. 6.8663 MnCl+ 69 1. -0.7894 AlOH+2 21 2. 3.1691 MnSO4,aq 70 0. -2.4604 HAlO2,aq 22 0. 10.5671 NaCl,aq 71 0. 0.4796 AlO2- 23 -1. 16.2221 NaOH,aq 72 0. 12.3669 CH4,aq 24 0. 6.0126 O2,aq 73 0. 53.5502 C2H6,aq 25 0. 12.3733 OH- 74 -1. 12.2382 C3H8,aq 26 0. 17.3707 HO2- 75 -1. 50.8010 C4H10,aq 27 0. 22.3757 H2O2,aq 76 0. 40.0166 ethanol,aq 28 0. 15.3258 H3PO2,aq 77 0. 24.3066 CO,aq 29 0. 4.6892 H2PO2- 78 -1. 26.5366 CO2,aq 30 0. -6.3298 HPO3-2 79 -2. 11.9254 CO3-2 31 -2. 10.0588 H3PO3,aq 80 0. 3.5792 CaCO3,aq 32 0. 5.9605 H2PO3- 81 -1. 5.6232 Ca(HCO3)+ 33 1. -1.4070 H3PO4,aq 82 0. -9.8447 CaCl+ 34 1. -0.2091 H2PO4- 83 -1. -7.2659 CaCl2,aq 35 0. 0.4151 PO4-3 84 -3. 12.0884 CaOH+ 36 1. 10.1471 H4P2O7,aq 85 0. -17.8095 CaSO4,aq 37 0. -2.5018 H3P2O7- 86 -1. -15.9156 HCl,aq 38 0. 0.7370 H2P2O7-2 87 -2. -13.4262 HClO,aq 39 0. 32.4260 HP2O7-3 88 -3. -6.7266 ClO- 40 -1. 39.6530 P2O7-4 89 -4. 2.8952 HClO2,aq 41 0. 70.1812 H2S,aq 90 0. -6.4900 Fe+3 42 3. 8.3809 S2-2 91 -2. 1.2355 FeCl+ 43 1. -0.1994 S3-2 92 -2. -8.8031 FeCl2,aq 44 0. 4.3001 S3- 93 -1. -16.3389 FeCl+2 45 2. 6.5269 S4-2 94 -2. -18.6615 FeO,aq 46 0. 16.4104 S5-2 95 -2. -28.3439 FeOH+ 47 1. 7.4874 SO2,aq 96 0. -0.2309 HFeO2- 48 -1. 24.3908 SO3-2 97 -2. 10.3052 FeO+ 49 1. 11.4004 HSO3- 98 -1. 2.5086 FeOH+2 50 2. 9.1194 HSO4- 99 -1. -2.9839 FeO2- 51 -1. 24.0895 HSO5- 100 -1. 38.8366 HFeO2,aq 52 0. 15.9850 S2O3-2 101 -2. -4.5600 H2,aq 53 0. 9.4190 HS2O3- 102 -1. -6.8123 KCl,aq 54 0. 1.7417 H2S2O3,aq 103 0. -8.0173 KHSO4,aq 55 0. -0.4514 S2O4-2 104 -2. 10.5541 KOH,aq 56 0. 12.3695 HS2O4- 105 -1. 7.6551 KSO4- 57 -1. -1.1908 H2S2O4,aq 106 0. 6.6259 MgCO3,aq 58 0. 6.5614 S2O5-2 107 -2. 10.0741 Mg(HCO3)+ 59 1. -1.4164 S2O6-2 108 -2. 11.5521 MgCl+ 60 1. -0.1664 S2O8-2 109 -2. 42.0620 MgOH+ 61 1. 9.4041 S3O6-2 110 -2. 3.7866 Mn+3 62 3. 19.1453 S4O6-2 111 -2. -17.8657 MnO,aq 63 0. 17.9848 S5O6-2 112 -2. -14.1333 MnOH+ 64 1. 8.5194 113 0. 10.3111 For mixed gases (JSOLS=6), log K(hydrol) = log (K*P) Log K Trial Log K Trial Mineral No. hydrol Moles Mineral No. hydrol Moles H2O,gas 1 1.696 0.0000E+00 osumilite(2) 124 20.667 0.0000E+00 CO2,gas 2 -6.660 0.0000E+00 osumilite-Fe 125 14.390 0.0000E+00 CH4,gas 3 4.544 0.0000E+00 pargasite 126 65.092 0.0000E+00 H2,gas 4 8.000 0.0000E+00 periclase 127 16.138 0.0000E+00 H2S,gas 5 -6.230 0.0000E+00 periclase-Fe 128 11.627 0.0000E+00 S2,gas 6 -7.335 0.0000E+00 perovskite-Al 129 12.344 0.0000E+00 CO,gas 7 3.215 0.0000E+00 perovskite-Ca 130 23.807 0.0000E+00 SO3,gas 8 17.121 0.0000E+00 perovskite-Fe 131 21.143 0.0000E+00 SO2,gas 9 0.832 0.0000E+00 perovskite-Mg 132 23.119 0.0000E+00 HCl,gas 10 5.189 0.0000E+00 phase_A 133 80.189 0.0000E+00 acmite 11 7.710 0.0000E+00 phlogopite-Na 134 29.647 0.0000E+00 akermanite 12 36.442 0.0000E+00 piemontite(ordered) 135 33.776 0.0000E+00 akimotoite 13 16.591 0.0000E+00 prehnite 136 19.372 0.0000E+00 akimotoite-Fe 14 13.067 0.0000E+00 prehnite-Fe 137 22.498 0.0000E+00 albite-high 15 0.693 0.0000E+00 pumpellyite-Fe 138 46.269 0.0000E+00 albite 16 -0.384 0.9829E+00 pumpellyite-Mg 139 48.995 0.0000E+00 almandine 17 24.442 0.0000E+00 px-Mg-tschermaks 140 19.616 0.0000E+00 pyrope 18 37.248 0.0000E+00 px-Ca-tschermaks 141 18.610 0.0000E+00 spessartine 19 24.457 0.0000E+00 pyrite 142 -21.247 0.0000E+00 analcite 20 3.322 0.0000E+00 pyrrhotite 143 -4.260 0.0000E+00 andalusite 21 5.002 0.0000E+00 pyrrhotiteFe0.875 144 -6.017 0.0000E+00 andradite 22 39.009 0.8884E-01 pyroxmangite 145 7.399 0.0000E+00 grossular 23 32.731 0.2152E-01 pyrophyllite 146 -6.176 0.0000E+00 anhydrite 24 -5.317 0.0000E+00 quartz 147 -2.989 0.0000E+00 ankerite 25 -2.135 0.0000E+00 rankinite 148 40.713 0.0000E+00 annite 26 20.123 0.0000E+00 ringwoodite-Fe 149 15.456 0.0000E+00 phlogopite 27 27.065 0.0000E+00 ringwoodite-Mg 150 27.575 0.0000E+00 biotite-Mn 28 32.960 0.0000E+00 rhodochrosite 151 -0.976 0.0000E+00 anorthite 29 12.710 0.0000E+00 rhodonite 152 7.446 0.0000E+00 anthophyllite 30 51.852 0.0000E+00 sanidine 153 -1.275 0.0000E+00 anthophyllite-Fe 31 29.306 0.0000E+00 sapphirine(351) 154 78.899 0.0000E+00 apatite-OH 32 -18.153 0.1578E-02 siderite 155 -2.608 0.0000E+00 apatite-OH-zs 33 -12.736 0.0000E+00 sillimanite 156 5.262 0.0000E+00 apatite-Cl-zs 34 -16.674 0.0000E+00 sodalite 157 49.976 0.0000E+00 aragonite 35 0.967 0.0000E+00 spinel 158 20.870 0.0000E+00 brucite 36 12.569 0.0000E+00 spurrite 159 59.482 0.0000E+00 calcite 37 0.812 0.0000E+00 staurolite-Fe 160 73.598 0.0000E+00 carnegieite-low 38 9.023 0.0000E+00 staurolite-Mg 161 89.802 0.0000E+00 carnegieite-high 39 10.093 0.0000E+00 staurolite-Mn 162 83.909 0.0000E+00 carpholite-Mg 40 8.582 0.0000E+00 stilbite 163 -7.522 0.5231E+00 carpholite-Fe 41 6.713 0.0000E+00 stilpnomelane-Fe 164 13.017 0.4169E-01 celadonite 42 5.342 0.0000E+00 stilpnomelane-Mg 165 27.441 0.0000E+00 celadonite-Fe 43 3.877 0.0000E+00 stishovite 166 2.720 0.0000E+00 chrysotile 44 23.892 0.0000E+00 sudoite-Fe 167 18.296 0.0000E+00 chondrodite 45 56.475 0.0000E+00 sudoite 168 21.077 0.0000E+00 clinochlore 46 39.070 0.1147E+00 sulfur 169 -9.152 0.0000E+00 daphnite 47 28.965 0.3321E-01 sylvite 170 1.338 0.0000E+00 chlorite-Mn 48 46.869 0.2774E-02 talc 171 16.491 0.0000E+00 chlorite-Al-free 49 47.173 0.0000E+00 talc-Fe 172 13.448 0.0000E+00 chloritoid-Mg 50 13.198 0.0000E+00 talc-tschermaks 173 19.091 0.0000E+00 chloritoid-Fe 51 9.174 0.0000E+00 tephroite 174 18.086 0.0000E+00 chloritoid-Mn 52 11.401 0.0000E+00 tilleyite 175 41.377 0.0000E+00 clinohumite 53 97.128 0.0000E+00 titanite-CaSi 176 15.479 0.0000E+00 coesite 54 -2.376 0.0000E+00 topaz-H 177 4.618 0.0000E+00 cordierite-H 55 23.715 0.0000E+00 tridymite 178 -2.626 0.0000E+00 cordierite 56 24.049 0.0000E+00 tremolite 179 47.869 0.0000E+00 cordierite-Fe 57 20.450 0.0000E+00 ferroactinolite 180 38.452 0.0000E+00 cordierite-Mn 58 25.066 0.0000E+00 troilite-low 181 -4.411 0.0000E+00 corundum 59 8.383 0.0000E+00 tschermakite 182 48.210 0.0000E+00 corundum-MgSi 60 18.891 0.0000E+00 vesuvianite 183 223.471 0.0000E+00 cristobalite 61 -2.560 0.0000E+00 wadeite-Si 184 20.216 0.0000E+00 cummingtonite 62 52.099 0.0000E+00 wadsleyite-Fe 185 15.680 0.0000E+00 cymrite-K 63 1.685 0.0000E+00 wadsleyite-Mg 186 25.850 0.0000E+00 deerite 64 95.671 0.0000E+00 wairakite 187 3.950 0.0000E+00 diaspore 65 2.874 0.0000E+00 walstromite 188 11.509 0.0000E+00 diamond 66 -3.102 0.0000E+00 wollastonite 189 10.461 0.0000E+00 diopside 67 16.181 0.3425E-01 pseudo-wollastonite 190 11.000 0.0000E+00 hedenbergite 68 14.208 0.8882E-02 zoisite 191 22.849 0.0000E+00 dolomite,ordered 69 0.546 0.0000E+00 akaganeite 192 7.755 0.0000E+00 eastonite 70 28.489 0.0000E+00 beidellite-Ca 193 -1.646 0.0000E+00 enstatite 71 17.265 0.0000E+00 beidellite-H 194 -2.326 0.0000E+00 clinoenstatite-HiP 72 18.354 0.0000E+00 beidellite-K 195 -1.520 0.0000E+00 clinoenstatite 73 17.166 0.0000E+00 beidellite-Mg 196 -1.790 0.0000E+00 protoenstatite 74 17.824 0.0000E+00 beidellite-Na 197 -1.342 0.0000E+00 epidote 75 24.670 0.0000E+00 calcium 198 84.026 0.0000E+00 clinozoisite 76 22.806 0.0000E+00 chalcedony 199 -2.802 0.0000E+00 epidote-Fe 77 29.841 0.0000E+00 dawsonite 200 1.682 0.0000E+00 fayalite 78 14.046 0.0000E+00 montmorillonite-Ca 201 -2.291 0.0000E+00 ferrosilite 79 11.149 0.0000E+00 montmorillonite-K 202 -2.237 0.0000E+00 forsterite 80 21.016 0.0000E+00 montmorillonite-Mg 203 -2.480 0.0000E+00 gedrite 81 50.522 0.0000E+00 montmorillonite-Na 204 -2.038 0.0000E+00 gehlenite 82 36.628 0.0000E+00 nontronite-Ca 205 3.215 0.0000E+00 gibbsite 83 4.079 0.0000E+00 nontronite-H 206 2.533 0.0000E+00 glaucophane 84 22.975 0.0000E+00 nontronite-K 207 3.341 0.0000E+00 glaucophane-Fe 85 17.276 0.0000E+00 nontronite-Mg 208 3.075 0.0000E+00 graphite 86 -3.546 0.0000E+00 nontronite-Na 209 3.520 0.0000E+00 greenalite 87 16.140 0.0000E+00 sepiolite 210 24.118 0.0000E+00 grunerite 88 31.215 0.0000E+00 alite 211 57.999 0.0000E+00 halite 89 1.575 0.0000E+00 belite 212 30.433 0.0000E+00 hematite 90 12.566 0.0000E+00 ettringite 213 43.232 0.0000E+00 heulandite 91 -5.827 0.0000E+00 gypsum 214 -4.955 0.0000E+00 hercynite 92 17.279 0.0000E+00 hemicarboaluminate 215 70.954 0.0000E+00 hollandite 93 25.673 0.0000E+00 hydrogarnet 216 60.662 0.0000E+00 iron 94 19.086 0.0000E+00 hydrogarnet-Si 217 50.586 0.0000E+00 jadeite 95 4.215 0.0000E+00 jennite 218 24.367 0.0000E+00 julgoldite 96 70.427 0.0000E+00 monosulfoaluminate 219 53.400 0.0000E+00 kalsilite 97 7.584 0.0000E+00 monocarboaluminate 220 61.898 0.0000E+00 kaolinite 98 -1.333 0.0000E+00 portlandite 221 18.272 0.0000E+00 kyanite 99 4.876 0.0000E+00 stratlingite 222 36.502 0.0000E+00 larnite-bredigite 100 30.686 0.0000E+00 tricarboaluminate 223 70.370 0.0000E+00 laumontite 101 2.883 0.0000E+00 tobermorite 224 9.823 0.0000E+00 lawsonite 102 9.616 0.0000E+00 C4AH13 225 81.816 0.0000E+00 leucite 103 4.119 0.0000E+00 C2AH8 226 45.203 0.0000E+00 lime 104 25.998 0.0000E+00 C3A 227 86.953 0.0000E+00 lizardite 105 23.244 0.0000E+00 C4AF 228 117.416 0.0000E+00 magnesite 106 0.691 0.0000E+00 CAH10 229 28.335 0.0000E+00 magnetite 107 20.087 0.0000E+00 alabandite 230 -0.978 0.0000E+00 minnesotaite 108 10.388 0.0000E+00 alunite 231 -10.435 0.0000E+00 minnesotaite-Mg 109 20.602 0.0000E+00 artinite 232 15.121 0.0000E+00 magnesioferrite 110 26.212 0.0000E+00 boehmite 233 4.406 0.0000E+00 majorite 111 53.251 0.0000E+00 dolomite,disordered 234 1.247 0.0000E+00 manganosite 112 14.058 0.0000E+00 ferrous-oxide 235 9.812 0.0000E+00 margarite 113 17.324 0.0000E+00 huntite 236 3.770 0.0000E+00 meionite 114 44.874 0.0000E+00 hydromagnesite 237 19.995 0.0000E+00 merwinite 115 55.930 0.0000E+00 nesquehonite 238 4.723 0.0000E+00 microcline 116 -2.486 0.1489E+00 potassium-oxide 239 69.038 0.0000E+00 monticellite 117 24.339 0.0000E+00 silica-amorphous 240 -2.091 0.0000E+00 mullite-Al 118 363.148 0.0000E+00 sodium-oxide 241 55.169 0.0000E+00 mullite-Si 119 7.264 0.0000E+00 an20ab80 242 2.018 0.0000E+00 muscovite 120 2.582 0.0000E+00 an25ab75 243 2.646 0.0000E+00 paragonite 121 4.239 0.0000E+00 an30ab70 244 3.279 0.0000E+00 nepheline 122 8.339 0.0000E+00 tr.625ac.25prg.125 245 45.165 0.7464E-02 osumilite(1) 123 21.717 0.0000E+00 246 0.000 0.0000E+00 Initial composition of reactant (wt%): SiO2 62.56 MgO 3.200 Al2O3 16.62 CaO 6.450 FeO 3.530 Na2O 3.890 Fe2O3 1.770 K2O 1.000 MnO 0.1230 P2O5 0.4200E-01 Sum of wt% of reactants: 99.1850 Reactant consumed: 799.9990000 g log = 2.9031 Original solution: 1000.0103000 g Original solution / Rock added: 1.25 (Water/Rock Ratio), log = 0.0969 The following minerals and/or gases with identical index are in solid solution: H2O,gas 6 CO2,gas 6 CH4,gas 6 H2,gas 6 H2S,gas 6 S2,gas 6 CO,gas 6 SO3,gas 6 SO2,gas 6 HCl,gas 6 almandine 16 pyrope 16 spessartine 16 andradite 8 grossular 8 annite 15 phlogopite 15 biotite-Mn 15 clinochlore 1 daphnite 1 chlorite-Mn 1 diopside 5 hedenbergite 5 epidote 3 clinozoisite 3 greenalite 18 iron 9 lizardite 18 magnetite 14 talc 7 talc-Fe 7 tremolite 2 ferroactinolite 2 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 13 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 799.9990000 Water: Moles liquid = 0.5096E+02 kg liquid = 0.9181E+00 Moles total = 0.4548E+02 kg total = 0.8193E+00 Activity = 1.0000 Stoichiometric ionic strength = .1132752E-01 Osmotic coef. = 0.9694 True ionic strength = .2001558E-01 Chg. balance for total moles = 0.3298E-10 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.88281E-10 -10.0541 0.74179E-10 -10.1297 0.84026E+00 -0.0756 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.14959E-03 -3.8251 0.12494E-03 -3.9033 0.83521E+00 -0.0782 4 SO4-- 0.70474E-12 -12.1520 0.36599E-12 -12.4365 0.51933E+00 -0.2846 5 HCO3- 0.26080E-06 -6.5837 0.21814E-06 -6.6613 0.83643E+00 -0.0776 6 HS- 0.27774E-04 -4.5564 0.23200E-04 -4.6345 0.83533E+00 -0.0781 7 Al+++ 0.96883E-29 -29.0138 0.22385E-29 -29.6500 0.23105E+00 -0.6363 8 H4SiO4 0.69590E-03 -3.1575 0.69590E-03 -3.1575 0.10000E+01 0.0000 9 Ca++ 0.13496E-06 -6.8698 0.69572E-07 -7.1576 0.51551E+00 -0.2878 10 Mg++ 0.21113E-10 -10.6754 0.10834E-10 -10.9652 0.51316E+00 -0.2898 11 Fe++ 0.58187E-13 -13.2352 0.29892E-13 -13.5244 0.51372E+00 -0.2893 12 K+ 0.15649E-03 -3.8055 0.13093E-03 -3.8830 0.83663E+00 -0.0775 13 Na+ 0.19858E-01 -1.7021 0.16583E-01 -1.7803 0.83505E+00 -0.0783 14 Mn++ 0.18494E-10 -10.7330 0.95084E-11 -11.0219 0.51414E+00 -0.2889 15 HPO4-- 0.45322E-07 -7.3437 0.23540E-07 -7.6282 0.51940E+00 -0.2845 16 HSiO3- 0.10488E-01 -1.9793 0.87598E-02 -2.0575 0.83521E+00 -0.0782 17 Ca(HSiO3)+ 0.16586E-07 -7.7803 0.13879E-07 -7.8576 0.83681E+00 -0.0774 18 Mg(HSiO3)+ 0.32145E-11 -11.4929 0.26899E-11 -11.5703 0.83681E+00 -0.0774 19 NaHSiO3,aq 0.23494E-02 -2.6290 0.23494E-02 -2.6290 0.10000E+01 0.0000 20 AlO+ 0.66137E-16 -16.1796 0.55344E-16 -16.2569 0.83681E+00 -0.0774 22 HAlO2,aq 0.14858E-09 -9.8280 0.14858E-09 -9.8280 0.10000E+01 0.0000 23 AlO2- 0.53183E-05 -5.2742 0.44339E-05 -5.3532 0.83370E+00 -0.0790 24 CH4,aq 0.13479E-04 -4.8703 0.13432E-04 -4.8719 0.99655E+00 -0.0015 25 C2H6,aq 0.26716E-14 -14.5732 0.26623E-14 -14.5747 0.99655E+00 -0.0015 29 CO,aq 0.10063E-16 -16.9973 0.10063E-16 -16.9973 0.10000E+01 0.0000 30 CO2,aq 0.34696E-10 -10.4597 0.34576E-10 -10.4612 0.99655E+00 -0.0015 31 CO3-2 0.49567E-06 -6.3048 0.25687E-06 -6.5903 0.51822E+00 -0.2855 32 CaCO3,aq 0.22408E-09 -9.6496 0.22408E-09 -9.6496 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.46295E-12 -12.3345 0.38740E-12 -12.4118 0.83681E+00 -0.0774 34 CaCl+ 0.16810E-10 -10.7744 0.14067E-10 -10.8518 0.83681E+00 -0.0774 35 CaCl2,aq 0.41755E-15 -15.3793 0.41755E-15 -15.3793 0.10000E+01 0.0000 36 CaOH+ 0.79880E-07 -7.0976 0.66844E-07 -7.1749 0.83681E+00 -0.0774 37 CaSO4,aq 0.80857E-17 -17.0923 0.80857E-17 -17.0923 0.10000E+01 0.0000 38 HCl,aq 0.16983E-14 -14.7700 0.16983E-14 -14.7700 0.10000E+01 0.0000 43 FeCl+ 0.70642E-17 -17.1509 0.59114E-17 -17.2283 0.83681E+00 -0.0774 46 FeO,aq 0.21113E-09 -9.6754 0.21113E-09 -9.6754 0.10000E+01 0.0000 47 FeOH+ 0.15675E-10 -10.8048 0.13117E-10 -10.8822 0.83681E+00 -0.0774 48 HFeO2- 0.35657E-07 -7.4479 0.29781E-07 -7.5261 0.83521E+00 -0.0782 49 FeO+ 0.10985E-16 -16.9592 0.91919E-17 -17.0366 0.83681E+00 -0.0774 51 FeO2- 0.40926E-09 -9.3880 0.34182E-09 -9.4662 0.83521E+00 -0.0782 52 HFeO2,aq 0.32249E-11 -11.4915 0.32249E-11 -11.4915 0.10000E+01 0.0000 53 H2,aq 0.11626E-04 -4.9346 0.11586E-04 -4.9361 0.99655E+00 -0.0015 54 KCl,aq 0.29647E-09 -9.5280 0.29647E-09 -9.5280 0.10000E+01 0.0000 56 KOH,aq 0.75375E-06 -6.1228 0.75375E-06 -6.1228 0.10000E+01 0.0000 57 KSO4- 0.89028E-15 -15.0505 0.74356E-15 -15.1287 0.83521E+00 -0.0782 58 MgCO3,aq 0.87468E-14 -14.0581 0.87468E-14 -14.0581 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.73668E-16 -16.1327 0.61646E-16 -16.2101 0.83681E+00 -0.0774 60 MgCl+ 0.23727E-14 -14.6248 0.19855E-14 -14.7021 0.83681E+00 -0.0774 61 MgOH+ 0.68834E-10 -10.1622 0.57601E-10 -10.2396 0.83681E+00 -0.0774 63 MnO,aq 0.17895E-08 -8.7473 0.17895E-08 -8.7473 0.10000E+01 0.0000 64 MnOH+ 0.46320E-09 -9.3342 0.38761E-09 -9.4116 0.83681E+00 -0.0774 65 MnO2-2 0.20827E-10 -10.6814 0.10793E-10 -10.9668 0.51822E+00 -0.2855 66 HMnO2- 0.21001E-09 -9.6778 0.17541E-09 -9.7560 0.83521E+00 -0.0782 69 MnCl+ 0.87421E-14 -14.0584 0.73155E-14 -14.1358 0.83681E+00 -0.0774 71 NaCl,aq 0.68660E-06 -6.1633 0.68660E-06 -6.1633 0.10000E+01 0.0000 72 NaOH,aq 0.96047E-04 -4.0175 0.96047E-04 -4.0175 0.10000E+01 0.0000 74 OH- 0.93426E-02 -2.0295 0.77889E-02 -2.1085 0.83370E+00 -0.0790 79 HPO3-2 0.16401E-14 -14.7851 0.84992E-15 -15.0706 0.51822E+00 -0.2855 81 H2PO3- 0.15137E-18 -18.8200 0.12643E-18 -18.8982 0.83521E+00 -0.0782 82 H3PO4,aq 0.90593E-18 -18.0429 0.90593E-18 -18.0429 0.10000E+01 0.0000 83 H2PO4- 0.38532E-10 -10.4142 0.32213E-10 -10.4920 0.83600E+00 -0.0778 84 PO4-3 0.10670E-08 -8.9718 0.25892E-09 -9.5868 0.24267E+00 -0.6150 88 HP2O7-3 0.94696E-18 -18.0237 0.21901E-18 -18.6595 0.23128E+00 -0.6359 89 P2O7-4 0.91462E-17 -17.0388 0.70535E-18 -18.1516 0.77119E-01 -1.1128 90 H2S,aq 0.53372E-08 -8.2727 0.53188E-08 -8.2742 0.99655E+00 -0.0015 91 S2-2 0.19864E-14 -14.7019 0.10294E-14 -14.9874 0.51822E+00 -0.2855 97 SO3-2 0.10481E-17 -17.9796 0.55101E-18 -18.2588 0.52572E+00 -0.2792 99 HSO4- 0.31236E-19 -19.5053 0.26164E-19 -19.5823 0.83762E+00 -0.0770 Charge balance for all species = 0.3592E-10 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.8828092E-10 -.2230190E-01 -.2243991E+02 0.0000 2 H2O 0.1000000E+01 0.5550489E+02 0.9981997E+06 0.0000 3 Cl- 0.1495912E-03 0.1502781E-03 0.5318551E+01 6.2264 4 SO4-- 0.7047431E-12 -.1638518E-04 -.1571251E+01 7.8229 5 HCO3- 0.2608035E-06 0.1423552E-04 0.8671024E+00 3.4685 6 HS- 0.2777350E-04 0.4416402E-04 0.1458054E+01 5.4952 7 Al+++ 0.9688261E-29 0.5318471E-05 0.1432510E+00 0.7391 8 H4SiO4 0.6959021E-03 0.1353351E-01 0.1298518E+04 -3.1575 9 Ca++ 0.1349574E-06 0.2316646E-06 0.9268519E-02 13.1019 10 Mg++ 0.2111334E-10 0.9317341E-10 0.2261296E-05 9.2942 11 Fe++ 0.5818748E-13 0.3629661E-07 0.2023534E-02 6.7350 12 K+ 0.1564920E-03 0.1572461E-03 0.6137951E+01 6.2467 13 Na+ 0.1985804E-01 0.2230416E-01 0.5118771E+03 8.3494 14 Mn++ 0.1849362E-10 0.2502077E-08 0.1372202E-03 9.2375 15 HPO4-- 0.4532234E-07 0.4642784E-07 0.4448355E-02 12.6313 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.1324678E+02 -.2047595E-01 -.1322631E+02 0.0000000E+00 2 H2O 0.4547993E+02 0.5096047E+02 -.5480532E+01 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.2219620E-01 -.1504365E-04 0.2221125E-01 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.2217070E-01 0.4054812E-04 -.2221125E-01 0.0000000E+00 7 Al+++ 0.2608590E+01 0.4883025E-05 0.2608585E+01 0.0000000E+00 8 H4SiO4 0.8330216E+01 0.1242546E-01 0.8317790E+01 0.0000000E+00 9 Ca++ 0.9201274E+00 0.2126972E-06 0.9201272E+00 0.0000000E+00 10 Mg++ 0.6349198E+00 0.8554490E-10 0.6349198E+00 0.0000000E+00 11 Fe++ 0.5704062E+00 0.3332485E-07 0.5704061E+00 0.0000000E+00 12 K+ 0.1698512E+00 0.1443716E-03 0.1697068E+00 0.0000000E+00 13 Na+ 0.1004354E+01 0.2047802E-01 0.9838757E+00 0.0000000E+00 14 Mn++ 0.1387086E-01 0.2297221E-08 0.1387086E-01 0.0000000E+00 15 HPO4-- 0.4734055E-02 0.4262660E-07 0.4734013E-02 0.0000000E+00 Chg. balance for solid moles: -.2017E-14 Mass of aqueous solution: 0.919724E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 799.9990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 0.9829 -0.007 257.7 2.411 29.50 98.94 andradite 0.8884E-01 -1.051 45.15 1.655 5.167 11.73 grossular 0.2152E-01 -1.667 9.695 0.987 1.109 2.697 apatite-OH 0.1578E-02 -2.802 0.7927 -0.101 0.9071E-01 0.2519 clinochlore 0.1147 -0.940 63.77 1.805 7.297 24.25 daphnite 0.3321E-01 -1.479 23.69 1.375 2.712 7.180 chlorite-Mn 0.2774E-02 -2.557 1.967 0.294 0.2251 0.6268 diopside 0.3425E-01 -1.465 7.418 0.870 0.8489 2.267 hedenbergite 0.8882E-02 -2.051 2.204 0.343 0.2522 0.6036 microcline 0.1489 -0.827 41.43 1.617 4.742 16.19 stilbite 0.5231 -0.281 368.6 2.567 42.19 171.9 stilpnomelane-Fe 0.4169E-01 -1.380 44.94 1.653 5.143 15.52 tr.625ac.25prg.125 0.7464E-02 -2.127 6.380 0.805 0.7302 2.054 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8050E+00 0.8050E+00 1.0000 -0.094 grossular 0.1950E+00 0.1950E+00 1.0000 -0.710 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.7612E+00 0.7612E+00 1.0000 -0.118 daphnite 0.2204E+00 0.2204E+00 1.0000 -0.657 chlorite-Mn 0.1841E-01 0.1841E-01 1.0000 -1.735 diopside 0.7941E+00 0.7941E+00 1.0000 -0.100 hedenbergite 0.2059E+00 0.2059E+00 1.0000 -0.686 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 tr.625ac.25prg.125 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 873.809985 g Volume = 354.249163 cm3 Porosity: -10.3581% V(tot) - V(min): -.33250E+02 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 799.9990000 g log = 2.9031 Original solution: 1000.0103000 g Original solution / Rock added: 1.25 (Water/Rock Ratio), log = 0.0969 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0555 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9671E+00 0.9855 0.1006E+01 0.1021E+01 CO2,gas 0.3481E-08 1.0069 0.3699E-08 0.3674E-08 CH4,gas 0.1850E-01 1.0125 0.1977E-01 0.1953E-01 H2,gas 0.1440E-01 1.0006 0.1521E-01 0.1520E-01 H2S,gas 0.1391E-06 0.9959 0.1462E-06 0.1468E-06 S2,gas 0.3286E-29 1.0000 0.3468E-29 0.3468E-29 CO,gas 0.1421E-13 1.0000 0.1500E-13 0.1500E-13 SO3,gas 0.7214E-48 1.0000 0.7614E-48 0.7614E-48 SO2,gas 0.4269E-27 1.0000 0.4506E-27 0.4506E-27 HCl,gas 0.2839E-17 1.0000 0.2997E-17 0.2997E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 16 albite -0.38 -0.38 0.00 0.000 -0.13080E-10 22 andradite 39.01 39.01 0.00 0.000 0.12132E-10 23 grossular 32.73 32.73 0.00 0.000 0.00000E+00 32 apatite-OH -18.15 -18.15 0.00 0.000 -0.60662E-11 46 clinochlore 39.07 39.07 0.00 0.000 0.00000E+00 47 daphnite 28.97 28.97 0.00 0.000 -0.24265E-10 48 chlorite-Mn 46.87 46.87 0.00 0.000 0.12132E-10 67 diopside 16.18 16.18 0.00 0.000 -0.60662E-11 68 hedenbergite 14.21 14.21 0.00 0.000 -0.30331E-11 116 microcline -2.49 -2.49 0.00 0.000 0.15165E-11 163 stilbite -7.52 -7.52 0.00 0.000 -0.90992E-11 164 stilpnomelane-Fe 13.02 13.02 0.00 0.000 0.21232E-10 245 tr.625ac.25prg.125 45.16 45.16 0.00 0.000 -0.36397E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -16.79 -10.13 -3.377 0.17298E+05 -8.432 3 CH4,gas 4.54 1.14 -3.40 -0.851 0.58104E+04 -1.704 4 H2,gas 8.00 4.48 -3.52 -2.010 0.60049E+04 -1.818 5 H2S,gas -6.23 -14.76 -8.53 -4.267 0.14572E+05 -6.835 6 S2,gas -7.34 -38.49 -31.16 -4.794 0.53203E+05 -29.460 7 CO,gas 3.21 -12.31 -15.52 -4.776 0.26505E+05 -13.824 8 SO3,gas 17.12 -32.70 -49.82 -12.454 0.85062E+05 -48.118 9 SO2,gas 0.83 -28.21 -29.05 -7.745 0.49594E+05 -27.346 10 HCl,gas 5.19 -14.03 -19.22 -9.611 0.32822E+05 -17.523 11 acmite 7.71 6.53 -1.18 -0.123 0.20177E+04 15 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 19 spessartine 24.46 19.72 -4.74 -0.237 0.80914E+04 20 analcite 3.32 2.77 -0.55 -0.061 0.93617E+03 26 annite 20.12 17.72 -2.40 -0.134 0.41063E+04 27 phlogopite 27.06 25.40 -1.67 -0.093 0.28487E+04 29 anorthite 12.71 8.27 -4.45 -0.342 0.75899E+04 35 aragonite 0.97 -3.69 -4.66 -1.552 0.79493E+04 36 brucite 12.57 9.29 -3.27 -0.655 0.55908E+04 37 calcite 0.81 -3.69 -4.50 -1.500 0.76851E+04 38 carnegieite-low 9.02 5.93 -3.09 -0.442 0.52799E+04 39 carnegieite-high 10.09 5.93 -4.16 -0.595 0.71069E+04 40 carpholite-Mg 8.58 4.46 -4.12 -0.275 0.70425E+04 41 carpholite-Fe 6.71 1.90 -4.81 -0.321 0.82203E+04 42 celadonite 5.34 3.65 -1.69 -0.099 0.28879E+04 43 celadonite-Fe 3.88 1.09 -2.79 -0.164 0.47561E+04 44 chrysotile 23.89 21.57 -2.32 -0.194 0.39691E+04 49 chlorite-Al-free 47.17 43.14 -4.04 -0.168 0.68934E+04 51 chloritoid-Fe 9.17 5.06 -4.12 -0.275 0.70311E+04 52 chloritoid-Mn 11.40 7.56 -3.84 -0.256 0.65614E+04 54 coesite -2.38 -3.16 -0.78 -0.260 0.13342E+04 61 cristobalite -2.56 -3.16 -0.60 -0.199 0.10196E+04 63 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71234E+04 65 diaspore 2.87 0.74 -2.13 -0.356 0.36447E+04 66 diamond -3.10 -7.83 -4.72 -1.349 0.80639E+04 71 enstatite 17.26 12.27 -4.99 -0.499 0.85225E+04 73 clinoenstatite 17.17 12.27 -4.89 -0.489 0.83541E+04 75 epidote 24.67 22.70 -1.97 -0.095 0.33582E+04 76 clinozoisite 22.81 18.95 -3.86 -0.175 0.65862E+04 77 epidote-Fe 29.84 26.46 -3.38 -0.176 0.57768E+04 78 fayalite 14.05 10.31 -3.73 -0.533 0.63743E+04 79 ferrosilite 11.15 7.16 -3.99 -0.399 0.68203E+04 83 gibbsite 4.08 0.74 -3.34 -0.477 0.57033E+04 84 glaucophane 22.97 20.80 -2.17 -0.059 0.37132E+04 85 glaucophane-Fe 17.28 13.12 -4.15 -0.112 0.70919E+04 86 graphite -3.55 -7.83 -4.28 -1.223 0.73062E+04 87 greenalite 16.14 13.89 -2.25 -0.187 0.38408E+04 90 hematite 12.57 8.99 -3.58 -0.434 0.61113E+04 91 heulandite -5.83 -7.52 -1.69 -0.077 0.28938E+04 95 jadeite 4.22 2.77 -1.44 -0.144 0.24617E+04 97 kalsilite 7.58 3.83 -3.76 -0.536 0.64124E+04 98 kaolinite -1.33 -4.84 -3.50 -0.319 0.59828E+04 101 laumontite 2.88 1.95 -0.93 -0.062 0.15933E+04 102 lawsonite 9.62 8.27 -1.35 -0.090 0.23066E+04 103 leucite 4.12 0.67 -3.45 -0.345 0.58872E+04 105 lizardite 23.24 21.57 -1.68 -0.140 0.28617E+04 107 magnetite 20.09 15.72 -4.37 -0.356 0.74537E+04 108 minnesotaite 10.39 7.58 -2.81 -0.165 0.48030E+04 112 manganosite 14.06 9.24 -4.82 -1.205 0.82310E+04 120 muscovite 2.58 -1.01 -3.59 -0.211 0.61310E+04 121 paragonite 4.24 1.09 -3.15 -0.185 0.53701E+04 122 nepheline 8.34 5.93 -2.41 -0.344 0.41123E+04 128 periclase-Fe 11.63 6.73 -4.89 -1.223 0.83523E+04 134 phlogopite-Na 29.65 27.50 -2.15 -0.119 0.36675E+04 136 prehnite 19.37 18.21 -1.16 -0.068 0.19845E+04 137 prehnite-Fe 22.50 21.96 -0.53 -0.032 0.91148E+03 138 pumpellyite-Fe 46.27 43.89 -2.38 -0.053 0.40570E+04 139 pumpellyite-Mg 48.99 46.45 -2.54 -0.056 0.43408E+04 143 pyrrhotite -4.26 -8.03 -3.77 -1.256 0.64353E+04 144 pyrrhotiteFe0.875 -6.02 -9.43 -3.41 -1.254 0.58226E+04 145 pyroxmangite 7.40 6.08 -1.32 -0.264 0.22514E+04 146 pyrophyllite -6.18 -11.15 -4.98 -0.311 0.84960E+04 147 quartz -2.99 -3.16 -0.17 -0.056 0.28688E+03 152 rhodonite 7.45 6.08 -1.37 -0.273 0.23317E+04 153 sanidine -1.28 -2.49 -1.21 -0.093 0.20677E+04 165 stilpnomelane-Mg 27.44 25.81 -1.63 -0.049 0.27801E+04 171 talc 16.49 15.25 -1.24 -0.073 0.21141E+04 174 tephroite 18.09 15.32 -2.77 -0.395 0.47265E+04 178 tridymite -2.63 -3.16 -0.53 -0.177 0.90686E+03 179 tremolite 47.87 47.42 -0.45 -0.012 0.77497E+03 180 ferroactinolite 38.45 34.62 -3.83 -0.104 0.65452E+04 181 troilite-low -4.41 -8.03 -3.62 -1.206 0.61781E+04 183 vesuvianite 223.47 218.82 -4.65 -0.036 0.79408E+04 187 wairakite 3.95 1.95 -2.00 -0.118 0.34152E+04 188 walstromite 11.51 9.94 -1.56 -0.313 0.26719E+04 189 wollastonite 10.46 9.94 -0.52 -0.103 0.88229E+03 190 pseudo-wollastonite 11.00 9.94 -1.06 -0.211 0.18021E+04 191 zoisite 22.85 18.95 -3.90 -0.177 0.66603E+04 192 akaganeite 7.75 4.49 -3.26 -0.705 0.55682E+04 199 chalcedony -2.80 -3.16 -0.36 -0.118 0.60618E+03 201 montmorillonite-Ca -2.29 -6.17 -3.88 -0.240 0.66179E+04 202 montmorillonite-K -2.24 -6.27 -4.03 -0.247 0.68815E+04 203 montmorillonite-Mg -2.48 -6.79 -4.31 -0.267 0.73677E+04 204 montmorillonite-Na -2.04 -5.57 -3.54 -0.216 0.60364E+04 205 nontronite-Ca 3.21 -0.20 -3.41 -0.221 0.58218E+04 206 nontronite-H 2.53 -2.36 -4.89 -0.328 0.83488E+04 207 nontronite-K 3.34 -0.30 -3.64 -0.233 0.62086E+04 208 nontronite-Mg 3.07 -0.82 -3.90 -0.253 0.66556E+04 209 nontronite-Na 3.52 0.40 -3.12 -0.200 0.53295E+04 224 tobermorite 9.82 7.76 -2.07 -0.564 0.35287E+04 230 alabandite -0.98 -5.53 -4.55 -1.516 0.77670E+04 233 boehmite 4.41 0.74 -3.67 -0.611 0.62617E+04 235 ferrous-oxide 9.81 6.73 -3.08 -0.769 0.52532E+04 240 silica-amorphous -2.09 -3.16 -1.07 -0.355 0.18204E+04 242 an20ab80 2.02 1.35 -0.67 -0.052 0.11471E+04 243 an25ab75 2.65 1.78 -0.87 -0.067 0.14809E+04 244 an30ab70 3.28 2.21 -1.07 -0.082 0.18242E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 40.0000000 g Current total amount of reactant added: 799.9990000 g New total amount of reactant added: 839.9990000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.3298E-10 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 11 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 839.9990000 Water: Moles liquid = 0.5074E+02 kg liquid = 0.9141E+00 Moles total = 0.4498E+02 kg total = 0.8103E+00 Activity = 1.0000 Stoichiometric ionic strength = .1132809E-01 Osmotic coef. = 0.9694 True ionic strength = .2001604E-01 Chg. balance for total moles = 0.3298E-10 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.88283E-10 -10.0541 0.74180E-10 -10.1297 0.84026E+00 -0.0756 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.15025E-03 -3.8232 0.12549E-03 -3.9014 0.83521E+00 -0.0782 4 SO4-- 0.70787E-12 -12.1500 0.36761E-12 -12.4346 0.51932E+00 -0.2846 5 HCO3- 0.26196E-06 -6.5818 0.21911E-06 -6.6593 0.83643E+00 -0.0776 6 HS- 0.27896E-04 -4.5545 0.23302E-04 -4.6326 0.83533E+00 -0.0781 7 Al+++ 0.96888E-29 -29.0137 0.22386E-29 -29.6500 0.23105E+00 -0.6363 8 H4SiO4 0.69591E-03 -3.1574 0.69591E-03 -3.1574 0.10000E+01 0.0000 9 Ca++ 0.13496E-06 -6.8698 0.69575E-07 -7.1575 0.51551E+00 -0.2878 10 Mg++ 0.21114E-10 -10.6754 0.10835E-10 -10.9652 0.51315E+00 -0.2898 11 Fe++ 0.58190E-13 -13.2352 0.29893E-13 -13.5244 0.51372E+00 -0.2893 12 K+ 0.15650E-03 -3.8055 0.13093E-03 -3.8830 0.83663E+00 -0.0775 13 Na+ 0.19858E-01 -1.7021 0.16583E-01 -1.7803 0.83505E+00 -0.0783 14 Mn++ 0.18504E-10 -10.7327 0.95138E-11 -11.0216 0.51414E+00 -0.2889 15 HPO4-- 0.45321E-07 -7.3437 0.23540E-07 -7.6282 0.51940E+00 -0.2845 16 HSiO3- 0.10488E-01 -1.9793 0.87597E-02 -2.0575 0.83521E+00 -0.0782 17 Ca(HSiO3)+ 0.16586E-07 -7.7802 0.13880E-07 -7.8576 0.83680E+00 -0.0774 18 Mg(HSiO3)+ 0.32146E-11 -11.4929 0.26900E-11 -11.5703 0.83680E+00 -0.0774 19 NaHSiO3,aq 0.23494E-02 -2.6290 0.23494E-02 -2.6290 0.10000E+01 0.0000 20 AlO+ 0.66138E-16 -16.1796 0.55344E-16 -16.2569 0.83680E+00 -0.0774 22 HAlO2,aq 0.14858E-09 -9.8280 0.14858E-09 -9.8280 0.10000E+01 0.0000 23 AlO2- 0.53181E-05 -5.2742 0.44337E-05 -5.3532 0.83370E+00 -0.0790 24 CH4,aq 0.13538E-04 -4.8684 0.13491E-04 -4.8699 0.99655E+00 -0.0015 25 C2H6,aq 0.26951E-14 -14.5694 0.26858E-14 -14.5709 0.99655E+00 -0.0015 29 CO,aq 0.10108E-16 -16.9953 0.10108E-16 -16.9953 0.10000E+01 0.0000 30 CO2,aq 0.34851E-10 -10.4578 0.34730E-10 -10.4593 0.99655E+00 -0.0015 31 CO3-2 0.49785E-06 -6.3029 0.25800E-06 -6.5884 0.51822E+00 -0.2855 32 CaCO3,aq 0.22508E-09 -9.6477 0.22508E-09 -9.6477 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.46502E-12 -12.3325 0.38913E-12 -12.4099 0.83680E+00 -0.0774 34 CaCl+ 0.16885E-10 -10.7725 0.14129E-10 -10.8499 0.83680E+00 -0.0774 35 CaCl2,aq 0.42124E-15 -15.3755 0.42124E-15 -15.3755 0.10000E+01 0.0000 36 CaOH+ 0.79881E-07 -7.0976 0.66845E-07 -7.1749 0.83680E+00 -0.0774 37 CaSO4,aq 0.81218E-17 -17.0903 0.81218E-17 -17.0903 0.10000E+01 0.0000 38 HCl,aq 0.17058E-14 -14.7681 0.17058E-14 -14.7681 0.10000E+01 0.0000 43 FeCl+ 0.70956E-17 -17.1490 0.59376E-17 -17.2264 0.83680E+00 -0.0774 46 FeO,aq 0.21113E-09 -9.6754 0.21113E-09 -9.6754 0.10000E+01 0.0000 47 FeOH+ 0.15676E-10 -10.8048 0.13117E-10 -10.8822 0.83680E+00 -0.0774 48 HFeO2- 0.35656E-07 -7.4479 0.29780E-07 -7.5261 0.83521E+00 -0.0782 49 FeO+ 0.10985E-16 -16.9592 0.91922E-17 -17.0366 0.83680E+00 -0.0774 51 FeO2- 0.40926E-09 -9.3880 0.34181E-09 -9.4662 0.83521E+00 -0.0782 52 HFeO2,aq 0.32249E-11 -11.4915 0.32249E-11 -11.4915 0.10000E+01 0.0000 53 H2,aq 0.11626E-04 -4.9346 0.11585E-04 -4.9361 0.99655E+00 -0.0015 54 KCl,aq 0.29778E-09 -9.5261 0.29778E-09 -9.5261 0.10000E+01 0.0000 56 KOH,aq 0.75375E-06 -6.1228 0.75375E-06 -6.1228 0.10000E+01 0.0000 57 KSO4- 0.89424E-15 -15.0485 0.74687E-15 -15.1268 0.83521E+00 -0.0782 58 MgCO3,aq 0.87857E-14 -14.0562 0.87857E-14 -14.0562 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.73997E-16 -16.1308 0.61921E-16 -16.2082 0.83680E+00 -0.0774 60 MgCl+ 0.23832E-14 -14.6228 0.19943E-14 -14.7002 0.83680E+00 -0.0774 61 MgOH+ 0.68836E-10 -10.1622 0.57602E-10 -10.2396 0.83680E+00 -0.0774 63 MnO,aq 0.17905E-08 -8.7470 0.17905E-08 -8.7470 0.10000E+01 0.0000 64 MnOH+ 0.46345E-09 -9.3340 0.38782E-09 -9.4114 0.83680E+00 -0.0774 65 MnO2-2 0.20837E-10 -10.6812 0.10798E-10 -10.9666 0.51822E+00 -0.2855 66 HMnO2- 0.21012E-09 -9.6775 0.17549E-09 -9.7557 0.83521E+00 -0.0782 69 MnCl+ 0.87855E-14 -14.0562 0.73518E-14 -14.1336 0.83680E+00 -0.0774 71 NaCl,aq 0.68964E-06 -6.1614 0.68964E-06 -6.1614 0.10000E+01 0.0000 72 NaOH,aq 0.96047E-04 -4.0175 0.96047E-04 -4.0175 0.10000E+01 0.0000 74 OH- 0.93424E-02 -2.0295 0.77888E-02 -2.1085 0.83370E+00 -0.0790 79 HPO3-2 0.16400E-14 -14.7852 0.84988E-15 -15.0706 0.51822E+00 -0.2855 81 H2PO3- 0.15137E-18 -18.8200 0.12642E-18 -18.8982 0.83521E+00 -0.0782 82 H3PO4,aq 0.90594E-18 -18.0429 0.90594E-18 -18.0429 0.10000E+01 0.0000 83 H2PO4- 0.38532E-10 -10.4142 0.32212E-10 -10.4920 0.83600E+00 -0.0778 84 PO4-3 0.10669E-08 -8.9719 0.25891E-09 -9.5869 0.24267E+00 -0.6150 88 HP2O7-3 0.94693E-18 -18.0237 0.21900E-18 -18.6595 0.23128E+00 -0.6359 89 P2O7-4 0.91458E-17 -17.0388 0.70530E-18 -18.1516 0.77117E-01 -1.1128 90 H2S,aq 0.53608E-08 -8.2708 0.53423E-08 -8.2723 0.99655E+00 -0.0015 91 S2-2 0.20040E-14 -14.6981 0.10385E-14 -14.9836 0.51822E+00 -0.2855 97 SO3-2 0.10528E-17 -17.9777 0.55345E-18 -18.2569 0.52571E+00 -0.2792 99 HSO4- 0.31375E-19 -19.5034 0.26280E-19 -19.5804 0.83762E+00 -0.0770 Charge balance for all species = 0.3608E-10 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.8828293E-10 -.2230159E-01 -.2243960E+02 0.0000 2 H2O 0.1000000E+01 0.5550489E+02 0.9981996E+06 0.0000 3 Cl- 0.1502485E-03 0.1509385E-03 0.5341923E+01 6.2283 4 SO4-- 0.7078697E-12 -.1644435E-04 -.1576925E+01 7.8248 5 HCO3- 0.2619594E-06 0.1429808E-04 0.8709129E+00 3.4704 6 HS- 0.2789555E-04 0.4434526E-04 0.1464038E+01 5.4971 7 Al+++ 0.9688835E-29 0.5318266E-05 0.1432454E+00 0.7391 8 H4SiO4 0.6959064E-03 0.1353339E-01 0.1298507E+04 -3.1574 9 Ca++ 0.1349632E-06 0.2316731E-06 0.9268859E-02 13.1019 10 Mg++ 0.2111422E-10 0.9317550E-10 0.2261347E-05 9.2942 11 Fe++ 0.5819018E-13 0.3629581E-07 0.2023490E-02 6.7350 12 K+ 0.1564956E-03 0.1572496E-03 0.6138090E+01 6.2467 13 Na+ 0.1985849E-01 0.2230463E-01 0.5118879E+03 8.3494 14 Mn++ 0.1850419E-10 0.2503392E-08 0.1372923E-03 9.2378 15 HPO4-- 0.4532116E-07 0.4642662E-07 0.4448237E-02 12.6312 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.1390912E+02 -.2038607E-01 -.1388874E+02 0.0000000E+00 2 H2O 0.4497852E+02 0.5073750E+02 -.5758982E+01 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.2330474E-01 -.1503192E-04 0.2331977E-01 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.2327924E-01 0.4053639E-04 -.2331977E-01 0.0000000E+00 7 Al+++ 0.2739020E+01 0.4861473E-05 0.2739015E+01 0.0000000E+00 8 H4SiO4 0.8746727E+01 0.1237099E-01 0.8734356E+01 0.0000000E+00 9 Ca++ 0.9661331E+00 0.2117744E-06 0.9661329E+00 0.0000000E+00 10 Mg++ 0.6666659E+00 0.8517254E-10 0.6666659E+00 0.0000000E+00 11 Fe++ 0.5989265E+00 0.3317831E-07 0.5989265E+00 0.0000000E+00 12 K+ 0.1783437E+00 0.1437432E-03 0.1782000E+00 0.0000000E+00 13 Na+ 0.1054563E+01 0.2038885E-01 0.1034175E+01 0.0000000E+00 14 Mn++ 0.1456440E-01 0.2288372E-08 0.1456440E-01 0.0000000E+00 15 HPO4-- 0.4970758E-02 0.4243898E-07 0.4970716E-02 0.0000000E+00 Chg. balance for solid moles: 0.5811E-15 Mass of aqueous solution: 0.915700E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 839.9990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 1.033 0.014 270.9 2.433 29.53 104.0 andradite 0.9328E-01 -1.030 47.40 1.676 5.166 12.32 grossular 0.2260E-01 -1.646 10.18 1.008 1.109 2.832 apatite-OH 0.1657E-02 -2.781 0.8323 -0.080 0.9071E-01 0.2645 clinochlore 0.1204 -0.919 66.92 1.826 7.294 25.45 daphnite 0.3485E-01 -1.458 24.87 1.396 2.710 7.535 chlorite-Mn 0.2913E-02 -2.536 2.065 0.315 0.2251 0.6581 diopside 0.3643E-01 -1.439 7.889 0.897 0.8598 2.411 hedenbergite 0.9446E-02 -2.025 2.344 0.370 0.2554 0.6419 microcline 0.1563 -0.806 43.51 1.639 4.742 16.99 stilbite 0.5488 -0.261 386.7 2.587 42.15 180.4 stilpnomelane-Fe 0.4378E-01 -1.359 47.20 1.674 5.144 16.30 tr.625ac.25prg.125 0.7798E-02 -2.108 6.665 0.824 0.7265 2.145 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8050E+00 0.8050E+00 1.0000 -0.094 grossular 0.1950E+00 0.1950E+00 1.0000 -0.710 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.7612E+00 0.7612E+00 1.0000 -0.118 daphnite 0.2204E+00 0.2204E+00 1.0000 -0.657 chlorite-Mn 0.1842E-01 0.1842E-01 1.0000 -1.735 diopside 0.7941E+00 0.7941E+00 1.0000 -0.100 hedenbergite 0.2059E+00 0.2059E+00 1.0000 -0.686 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 tr.625ac.25prg.125 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 917.510248 g Volume = 371.930389 cm3 Porosity: -10.3652% V(tot) - V(min): -.34931E+02 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 839.9990000 g log = 2.9243 Original solution: 1000.0103000 g Original solution / Rock added: 1.19 (Water/Rock Ratio), log = 0.0757 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0556 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9670E+00 0.9855 0.1006E+01 0.1021E+01 CO2,gas 0.3496E-08 1.0069 0.3716E-08 0.3690E-08 CH4,gas 0.1858E-01 1.0125 0.1986E-01 0.1961E-01 H2,gas 0.1440E-01 1.0006 0.1521E-01 0.1520E-01 H2S,gas 0.1397E-06 0.9959 0.1469E-06 0.1475E-06 S2,gas 0.3315E-29 1.0000 0.3499E-29 0.3499E-29 CO,gas 0.1427E-13 1.0000 0.1506E-13 0.1506E-13 SO3,gas 0.7246E-48 1.0000 0.7649E-48 0.7649E-48 SO2,gas 0.4288E-27 1.0000 0.4526E-27 0.4526E-27 HCl,gas 0.2851E-17 1.0000 0.3010E-17 0.3010E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 16 albite -0.38 -0.38 0.00 0.000 0.11184E-10 22 andradite 39.01 39.01 0.00 0.000 0.36397E-10 23 grossular 32.73 32.73 0.00 0.000 0.00000E+00 32 apatite-OH -18.15 -18.15 0.00 0.000 0.60662E-11 46 clinochlore 39.07 39.07 0.00 0.000 0.48529E-10 47 daphnite 28.97 28.97 0.00 0.000 0.00000E+00 48 chlorite-Mn 46.87 46.87 0.00 0.000 0.36397E-10 67 diopside 16.18 16.18 0.00 0.000 0.12132E-10 68 hedenbergite 14.21 14.21 0.00 0.000 0.90992E-11 116 microcline -2.49 -2.49 0.00 0.000 0.15165E-11 163 stilbite -7.52 -7.52 0.00 0.000 0.15165E-10 164 stilpnomelane-Fe 13.02 13.02 0.00 0.000 0.21232E-10 245 tr.625ac.25prg.125 45.16 45.16 0.00 0.000 -0.48529E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -16.79 -10.13 -3.376 0.17295E+05 -8.430 3 CH4,gas 4.54 1.14 -3.40 -0.850 0.58072E+04 -1.702 4 H2,gas 8.00 4.48 -3.52 -2.010 0.60049E+04 -1.818 5 H2S,gas -6.23 -14.76 -8.53 -4.266 0.14568E+05 -6.833 6 S2,gas -7.34 -38.49 -31.16 -4.793 0.53196E+05 -29.456 7 CO,gas 3.21 -12.31 -15.52 -4.776 0.26502E+05 -13.822 8 SO3,gas 17.12 -32.69 -49.82 -12.454 0.85058E+05 -48.116 9 SO2,gas 0.83 -28.21 -29.04 -7.745 0.49591E+05 -27.344 10 HCl,gas 5.19 -14.03 -19.22 -9.610 0.32818E+05 -17.521 11 acmite 7.71 6.53 -1.18 -0.123 0.20177E+04 15 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 19 spessartine 24.46 19.72 -4.74 -0.237 0.80902E+04 20 analcite 3.32 2.77 -0.55 -0.061 0.93617E+03 26 annite 20.12 17.72 -2.40 -0.134 0.41063E+04 27 phlogopite 27.06 25.40 -1.67 -0.093 0.28487E+04 29 anorthite 12.71 8.27 -4.45 -0.342 0.75899E+04 35 aragonite 0.97 -3.69 -4.65 -1.551 0.79461E+04 36 brucite 12.57 9.29 -3.27 -0.655 0.55908E+04 37 calcite 0.81 -3.69 -4.50 -1.500 0.76818E+04 38 carnegieite-low 9.02 5.93 -3.09 -0.442 0.52800E+04 39 carnegieite-high 10.09 5.93 -4.16 -0.595 0.71070E+04 40 carpholite-Mg 8.58 4.46 -4.12 -0.275 0.70425E+04 41 carpholite-Fe 6.71 1.90 -4.81 -0.321 0.82203E+04 42 celadonite 5.34 3.65 -1.69 -0.099 0.28879E+04 43 celadonite-Fe 3.88 1.09 -2.79 -0.164 0.47561E+04 44 chrysotile 23.89 21.57 -2.32 -0.194 0.39691E+04 49 chlorite-Al-free 47.17 43.14 -4.04 -0.168 0.68934E+04 51 chloritoid-Fe 9.17 5.06 -4.12 -0.275 0.70311E+04 52 chloritoid-Mn 11.40 7.56 -3.84 -0.256 0.65610E+04 54 coesite -2.38 -3.16 -0.78 -0.260 0.13342E+04 61 cristobalite -2.56 -3.16 -0.60 -0.199 0.10195E+04 63 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71234E+04 65 diaspore 2.87 0.74 -2.13 -0.356 0.36448E+04 66 diamond -3.10 -7.82 -4.72 -1.349 0.80606E+04 71 enstatite 17.26 12.27 -4.99 -0.499 0.85225E+04 73 clinoenstatite 17.17 12.27 -4.89 -0.489 0.83541E+04 75 epidote 24.67 22.70 -1.97 -0.095 0.33582E+04 76 clinozoisite 22.81 18.95 -3.86 -0.175 0.65862E+04 77 epidote-Fe 29.84 26.46 -3.38 -0.176 0.57768E+04 78 fayalite 14.05 10.31 -3.73 -0.533 0.63743E+04 79 ferrosilite 11.15 7.16 -3.99 -0.399 0.68203E+04 83 gibbsite 4.08 0.74 -3.34 -0.477 0.57033E+04 84 glaucophane 22.97 20.80 -2.17 -0.059 0.37132E+04 85 glaucophane-Fe 17.28 13.12 -4.15 -0.112 0.70919E+04 86 graphite -3.55 -7.82 -4.28 -1.222 0.73029E+04 87 greenalite 16.14 13.89 -2.25 -0.187 0.38408E+04 90 hematite 12.57 8.99 -3.58 -0.434 0.61113E+04 91 heulandite -5.83 -7.52 -1.69 -0.077 0.28938E+04 95 jadeite 4.22 2.77 -1.44 -0.144 0.24617E+04 97 kalsilite 7.58 3.83 -3.76 -0.537 0.64124E+04 98 kaolinite -1.33 -4.84 -3.50 -0.319 0.59828E+04 101 laumontite 2.88 1.95 -0.93 -0.062 0.15933E+04 102 lawsonite 9.62 8.27 -1.35 -0.090 0.23066E+04 103 leucite 4.12 0.67 -3.45 -0.345 0.58872E+04 105 lizardite 23.24 21.57 -1.68 -0.140 0.28617E+04 107 magnetite 20.09 15.72 -4.37 -0.356 0.74537E+04 108 minnesotaite 10.39 7.58 -2.81 -0.165 0.48030E+04 112 manganosite 14.06 9.24 -4.82 -1.205 0.82306E+04 120 muscovite 2.58 -1.01 -3.59 -0.211 0.61310E+04 121 paragonite 4.24 1.09 -3.15 -0.185 0.53701E+04 122 nepheline 8.34 5.93 -2.41 -0.344 0.41123E+04 128 periclase-Fe 11.63 6.73 -4.89 -1.223 0.83523E+04 134 phlogopite-Na 29.65 27.50 -2.15 -0.119 0.36675E+04 136 prehnite 19.37 18.21 -1.16 -0.068 0.19845E+04 137 prehnite-Fe 22.50 21.96 -0.53 -0.032 0.91148E+03 138 pumpellyite-Fe 46.27 43.89 -2.38 -0.053 0.40571E+04 139 pumpellyite-Mg 48.99 46.45 -2.54 -0.056 0.43409E+04 143 pyrrhotite -4.26 -8.03 -3.77 -1.256 0.64321E+04 144 pyrrhotiteFe0.875 -6.02 -9.43 -3.41 -1.253 0.58193E+04 145 pyroxmangite 7.40 6.08 -1.32 -0.264 0.22511E+04 146 pyrophyllite -6.18 -11.15 -4.98 -0.311 0.84960E+04 147 quartz -2.99 -3.16 -0.17 -0.056 0.28688E+03 152 rhodonite 7.45 6.08 -1.37 -0.273 0.23313E+04 153 sanidine -1.28 -2.49 -1.21 -0.093 0.20677E+04 165 stilpnomelane-Mg 27.44 25.81 -1.63 -0.049 0.27801E+04 171 talc 16.49 15.25 -1.24 -0.073 0.21141E+04 174 tephroite 18.09 15.32 -2.77 -0.395 0.47258E+04 178 tridymite -2.63 -3.16 -0.53 -0.177 0.90686E+03 179 tremolite 47.87 47.42 -0.45 -0.012 0.77497E+03 180 ferroactinolite 38.45 34.62 -3.83 -0.104 0.65451E+04 181 troilite-low -4.41 -8.03 -3.62 -1.205 0.61749E+04 183 vesuvianite 223.47 218.82 -4.65 -0.036 0.79410E+04 187 wairakite 3.95 1.95 -2.00 -0.118 0.34152E+04 188 walstromite 11.51 9.94 -1.56 -0.313 0.26719E+04 189 wollastonite 10.46 9.94 -0.52 -0.103 0.88229E+03 190 pseudo-wollastonite 11.00 9.94 -1.06 -0.211 0.18021E+04 191 zoisite 22.85 18.95 -3.90 -0.177 0.66603E+04 192 akaganeite 7.75 4.49 -3.26 -0.705 0.55682E+04 199 chalcedony -2.80 -3.16 -0.36 -0.118 0.60618E+03 201 montmorillonite-Ca -2.29 -6.17 -3.88 -0.240 0.66179E+04 202 montmorillonite-K -2.24 -6.27 -4.03 -0.247 0.68815E+04 203 montmorillonite-Mg -2.48 -6.79 -4.31 -0.267 0.73677E+04 204 montmorillonite-Na -2.04 -5.57 -3.54 -0.216 0.60364E+04 205 nontronite-Ca 3.21 -0.20 -3.41 -0.221 0.58218E+04 206 nontronite-H 2.53 -2.36 -4.89 -0.328 0.83488E+04 207 nontronite-K 3.34 -0.30 -3.64 -0.233 0.62086E+04 208 nontronite-Mg 3.07 -0.82 -3.90 -0.253 0.66556E+04 209 nontronite-Na 3.52 0.40 -3.12 -0.200 0.53295E+04 224 tobermorite 9.82 7.76 -2.07 -0.564 0.35287E+04 230 alabandite -0.98 -5.52 -4.55 -1.516 0.77633E+04 233 boehmite 4.41 0.74 -3.67 -0.611 0.62617E+04 235 ferrous-oxide 9.81 6.73 -3.08 -0.769 0.52532E+04 240 silica-amorphous -2.09 -3.16 -1.07 -0.355 0.18204E+04 242 an20ab80 2.02 1.35 -0.67 -0.052 0.11471E+04 243 an25ab75 2.65 1.78 -0.87 -0.067 0.14809E+04 244 an30ab70 3.28 2.21 -1.07 -0.082 0.18243E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 40.0000000 g Current total amount of reactant added: 839.9990000 g New total amount of reactant added: 879.9990000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.3298E-10 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 11 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 879.9990000 Water: Moles liquid = 0.5052E+02 kg liquid = 0.9101E+00 Moles total = 0.4448E+02 kg total = 0.8013E+00 Activity = 1.0000 Stoichiometric ionic strength = .1132867E-01 Osmotic coef. = 0.9694 True ionic strength = .2001650E-01 Chg. balance for total moles = 0.3298E-10 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.88285E-10 -10.0541 0.74182E-10 -10.1297 0.84026E+00 -0.0756 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.15091E-03 -3.8213 0.12604E-03 -3.8995 0.83520E+00 -0.0782 4 SO4-- 0.71102E-12 -12.1481 0.36925E-12 -12.4327 0.51932E+00 -0.2846 5 HCO3- 0.26312E-06 -6.5798 0.22008E-06 -6.6574 0.83643E+00 -0.0776 6 HS- 0.28019E-04 -4.5526 0.23405E-04 -4.6307 0.83533E+00 -0.0781 7 Al+++ 0.96894E-29 -29.0137 0.22387E-29 -29.6500 0.23104E+00 -0.6363 8 H4SiO4 0.69591E-03 -3.1574 0.69591E-03 -3.1574 0.10000E+01 0.0000 9 Ca++ 0.13497E-06 -6.8698 0.69578E-07 -7.1575 0.51551E+00 -0.2878 10 Mg++ 0.21115E-10 -10.6754 0.10835E-10 -10.9652 0.51315E+00 -0.2898 11 Fe++ 0.58193E-13 -13.2351 0.29894E-13 -13.5244 0.51371E+00 -0.2893 12 K+ 0.15650E-03 -3.8055 0.13093E-03 -3.8830 0.83662E+00 -0.0775 13 Na+ 0.19859E-01 -1.7020 0.16583E-01 -1.7803 0.83505E+00 -0.0783 14 Mn++ 0.18514E-10 -10.7325 0.95187E-11 -11.0214 0.51414E+00 -0.2889 15 HPO4-- 0.45320E-07 -7.3437 0.23539E-07 -7.6282 0.51939E+00 -0.2845 16 HSiO3- 0.10488E-01 -1.9793 0.87596E-02 -2.0575 0.83520E+00 -0.0782 17 Ca(HSiO3)+ 0.16587E-07 -7.7802 0.13880E-07 -7.8576 0.83680E+00 -0.0774 18 Mg(HSiO3)+ 0.32146E-11 -11.4929 0.26900E-11 -11.5702 0.83680E+00 -0.0774 19 NaHSiO3,aq 0.23494E-02 -2.6290 0.23494E-02 -2.6290 0.10000E+01 0.0000 20 AlO+ 0.66138E-16 -16.1795 0.55344E-16 -16.2569 0.83680E+00 -0.0774 22 HAlO2,aq 0.14858E-09 -9.8280 0.14858E-09 -9.8280 0.10000E+01 0.0000 23 AlO2- 0.53179E-05 -5.2743 0.44335E-05 -5.3533 0.83370E+00 -0.0790 24 CH4,aq 0.13598E-04 -4.8665 0.13551E-04 -4.8680 0.99655E+00 -0.0015 25 C2H6,aq 0.27190E-14 -14.5656 0.27096E-14 -14.5671 0.99655E+00 -0.0015 29 CO,aq 0.10153E-16 -16.9934 0.10153E-16 -16.9934 0.10000E+01 0.0000 30 CO2,aq 0.35006E-10 -10.4559 0.34885E-10 -10.4574 0.99655E+00 -0.0015 31 CO3-2 0.50006E-06 -6.3010 0.25914E-06 -6.5865 0.51822E+00 -0.2855 32 CaCO3,aq 0.22608E-09 -9.6457 0.22608E-09 -9.6457 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.46711E-12 -12.3306 0.39088E-12 -12.4080 0.83680E+00 -0.0774 34 CaCl+ 0.16960E-10 -10.7706 0.14192E-10 -10.8480 0.83680E+00 -0.0774 35 CaCl2,aq 0.42498E-15 -15.3716 0.42498E-15 -15.3716 0.10000E+01 0.0000 36 CaOH+ 0.79882E-07 -7.0975 0.66846E-07 -7.1749 0.83680E+00 -0.0774 37 CaSO4,aq 0.81582E-17 -17.0884 0.81582E-17 -17.0884 0.10000E+01 0.0000 38 HCl,aq 0.17134E-14 -14.7662 0.17134E-14 -14.7662 0.10000E+01 0.0000 43 FeCl+ 0.71272E-17 -17.1471 0.59640E-17 -17.2245 0.83680E+00 -0.0774 46 FeO,aq 0.21113E-09 -9.6754 0.21113E-09 -9.6754 0.10000E+01 0.0000 47 FeOH+ 0.15676E-10 -10.8048 0.13118E-10 -10.8821 0.83680E+00 -0.0774 48 HFeO2- 0.35656E-07 -7.4479 0.29780E-07 -7.5261 0.83520E+00 -0.0782 49 FeO+ 0.10985E-16 -16.9592 0.91924E-17 -17.0366 0.83680E+00 -0.0774 51 FeO2- 0.40925E-09 -9.3880 0.34181E-09 -9.4662 0.83520E+00 -0.0782 52 HFeO2,aq 0.32249E-11 -11.4915 0.32249E-11 -11.4915 0.10000E+01 0.0000 53 H2,aq 0.11625E-04 -4.9346 0.11585E-04 -4.9361 0.99655E+00 -0.0015 54 KCl,aq 0.29910E-09 -9.5242 0.29910E-09 -9.5242 0.10000E+01 0.0000 56 KOH,aq 0.75375E-06 -6.1228 0.75375E-06 -6.1228 0.10000E+01 0.0000 57 KSO4- 0.89824E-15 -15.0466 0.75021E-15 -15.1248 0.83520E+00 -0.0782 58 MgCO3,aq 0.88249E-14 -14.0543 0.88249E-14 -14.0543 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.74329E-16 -16.1288 0.62199E-16 -16.2062 0.83680E+00 -0.0774 60 MgCl+ 0.23938E-14 -14.6209 0.20031E-14 -14.6983 0.83680E+00 -0.0774 61 MgOH+ 0.68837E-10 -10.1622 0.57603E-10 -10.2396 0.83680E+00 -0.0774 63 MnO,aq 0.17913E-08 -8.7468 0.17913E-08 -8.7468 0.10000E+01 0.0000 64 MnOH+ 0.46368E-09 -9.3338 0.38801E-09 -9.4112 0.83680E+00 -0.0774 65 MnO2-2 0.20847E-10 -10.6810 0.10803E-10 -10.9665 0.51822E+00 -0.2855 66 HMnO2- 0.21022E-09 -9.6773 0.17557E-09 -9.7555 0.83520E+00 -0.0782 69 MnCl+ 0.88289E-14 -14.0541 0.73880E-14 -14.1315 0.83680E+00 -0.0774 71 NaCl,aq 0.69269E-06 -6.1595 0.69269E-06 -6.1595 0.10000E+01 0.0000 72 NaOH,aq 0.96047E-04 -4.0175 0.96047E-04 -4.0175 0.10000E+01 0.0000 74 OH- 0.93423E-02 -2.0295 0.77886E-02 -2.1085 0.83370E+00 -0.0790 79 HPO3-2 0.16399E-14 -14.7852 0.84984E-15 -15.0707 0.51822E+00 -0.2855 81 H2PO3- 0.15136E-18 -18.8200 0.12642E-18 -18.8982 0.83520E+00 -0.0782 82 H3PO4,aq 0.90595E-18 -18.0429 0.90595E-18 -18.0429 0.10000E+01 0.0000 83 H2PO4- 0.38531E-10 -10.4142 0.32212E-10 -10.4920 0.83600E+00 -0.0778 84 PO4-3 0.10669E-08 -8.9719 0.25889E-09 -9.5869 0.24266E+00 -0.6150 88 HP2O7-3 0.94690E-18 -18.0237 0.21899E-18 -18.6596 0.23128E+00 -0.6359 89 P2O7-4 0.91455E-17 -17.0388 0.70525E-18 -18.1517 0.77115E-01 -1.1129 90 H2S,aq 0.53846E-08 -8.2688 0.53660E-08 -8.2704 0.99655E+00 -0.0015 91 S2-2 0.20217E-14 -14.6943 0.10477E-14 -14.9798 0.51822E+00 -0.2855 97 SO3-2 0.10574E-17 -17.9758 0.55590E-18 -18.2550 0.52571E+00 -0.2793 99 HSO4- 0.31515E-19 -19.5015 0.26398E-19 -19.5784 0.83762E+00 -0.0770 Charge balance for all species = 0.3624E-10 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.8828495E-10 -.2230127E-01 -.2243928E+02 0.0000 2 H2O 0.1000000E+01 0.5550489E+02 0.9981996E+06 0.0000 3 Cl- 0.1509117E-03 0.1516047E-03 0.5365502E+01 6.2302 4 SO4-- 0.7110200E-12 -.1650405E-04 -.1582650E+01 7.8267 5 HCO3- 0.2631241E-06 0.1436119E-04 0.8747570E+00 3.4723 6 HS- 0.2801868E-04 0.4452812E-04 0.1470075E+01 5.4990 7 Al+++ 0.9689425E-29 0.5318070E-05 0.1432402E+00 0.7391 8 H4SiO4 0.6959104E-03 0.1353326E-01 0.1298494E+04 -3.1574 9 Ca++ 0.1349690E-06 0.2316817E-06 0.9269204E-02 13.1019 10 Mg++ 0.2111512E-10 0.9317798E-10 0.2261407E-05 9.2942 11 Fe++ 0.5819290E-13 0.3629501E-07 0.2023445E-02 6.7350 12 K+ 0.1564991E-03 0.1572532E-03 0.6138230E+01 6.2467 13 Na+ 0.1985895E-01 0.2230510E-01 0.5118986E+03 8.3494 14 Mn++ 0.1851390E-10 0.2504589E-08 0.1373580E-03 9.2380 15 HPO4-- 0.4531993E-07 0.4642535E-07 0.4448115E-02 12.6312 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.1457146E+02 -.2029620E-01 -.1455117E+02 0.0000000E+00 2 H2O 0.4447710E+02 0.5051453E+02 -.6037432E+01 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.2441328E-01 -.1502020E-04 0.2442830E-01 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.2438777E-01 0.4052467E-04 -.2442830E-01 0.0000000E+00 7 Al+++ 0.2869449E+01 0.4839931E-05 0.2869445E+01 0.0000000E+00 8 H4SiO4 0.9163239E+01 0.1231650E-01 0.9150922E+01 0.0000000E+00 9 Ca++ 0.1012139E+01 0.2108516E-06 0.1012139E+01 0.0000000E+00 10 Mg++ 0.6984119E+00 0.8480050E-10 0.6984119E+00 0.0000000E+00 11 Fe++ 0.6274468E+00 0.3303178E-07 0.6274468E+00 0.0000000E+00 12 K+ 0.1868363E+00 0.1431148E-03 0.1866932E+00 0.0000000E+00 13 Na+ 0.1104773E+01 0.2029968E-01 0.1084474E+01 0.0000000E+00 14 Mn++ 0.1525795E-01 0.2279405E-08 0.1525794E-01 0.0000000E+00 15 HPO4-- 0.5207462E-02 0.4225132E-07 0.5207419E-02 0.0000000E+00 Chg. balance for solid moles: 0.7286E-15 Mass of aqueous solution: 0.911676E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 879.9990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 1.083 0.035 284.1 2.453 29.56 109.1 andradite 0.9771E-01 -1.010 49.66 1.696 5.166 12.90 grossular 0.2367E-01 -1.626 10.66 1.028 1.109 2.967 apatite-OH 0.1736E-02 -2.760 0.8719 -0.060 0.9071E-01 0.2771 clinochlore 0.1261 -0.899 70.07 1.846 7.290 26.65 daphnite 0.3649E-01 -1.438 26.04 1.416 2.709 7.890 chlorite-Mn 0.3052E-02 -2.515 2.163 0.335 0.2251 0.6894 diopside 0.3860E-01 -1.413 8.360 0.922 0.8697 2.555 hedenbergite 0.1001E-01 -2.000 2.484 0.395 0.2584 0.6803 microcline 0.1638 -0.786 45.58 1.659 4.742 17.80 stilbite 0.5744 -0.241 404.8 2.607 42.12 188.8 stilpnomelane-Fe 0.4588E-01 -1.338 49.45 1.694 5.145 17.08 tr.625ac.25prg.125 0.8131E-02 -2.090 6.950 0.842 0.7231 2.237 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8050E+00 0.8050E+00 1.0000 -0.094 grossular 0.1950E+00 0.1950E+00 1.0000 -0.710 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.7612E+00 0.7612E+00 1.0000 -0.118 daphnite 0.2204E+00 0.2204E+00 1.0000 -0.657 chlorite-Mn 0.1843E-01 0.1843E-01 1.0000 -1.735 diopside 0.7941E+00 0.7941E+00 1.0000 -0.100 hedenbergite 0.2059E+00 0.2059E+00 1.0000 -0.686 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 tr.625ac.25prg.125 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 961.210511 g Volume = 389.611615 cm3 Porosity: -10.3717% V(tot) - V(min): -.36612E+02 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 879.9990000 g log = 2.9445 Original solution: 1000.0103000 g Original solution / Rock added: 1.14 (Water/Rock Ratio), log = 0.0555 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0557 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9669E+00 0.9855 0.1006E+01 0.1021E+01 CO2,gas 0.3511E-08 1.0069 0.3732E-08 0.3707E-08 CH4,gas 0.1866E-01 1.0124 0.1995E-01 0.1970E-01 H2,gas 0.1440E-01 1.0006 0.1521E-01 0.1520E-01 H2S,gas 0.1403E-06 0.9959 0.1475E-06 0.1481E-06 S2,gas 0.3344E-29 1.0000 0.3530E-29 0.3530E-29 CO,gas 0.1433E-13 1.0000 0.1513E-13 0.1513E-13 SO3,gas 0.7278E-48 1.0000 0.7683E-48 0.7683E-48 SO2,gas 0.4306E-27 1.0000 0.4546E-27 0.4546E-27 HCl,gas 0.2864E-17 1.0000 0.3023E-17 0.3023E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 16 albite -0.38 -0.38 0.00 0.000 -0.94784E-12 22 andradite 39.01 39.01 0.00 0.000 0.12132E-10 23 grossular 32.73 32.73 0.00 0.000 0.00000E+00 32 apatite-OH -18.15 -18.15 0.00 0.000 0.60662E-11 46 clinochlore 39.07 39.07 0.00 0.000 -0.12132E-10 47 daphnite 28.97 28.97 0.00 0.000 -0.24265E-10 48 chlorite-Mn 46.87 46.87 0.00 0.000 -0.48529E-10 67 diopside 16.18 16.18 0.00 0.000 -0.60662E-11 68 hedenbergite 14.21 14.21 0.00 0.000 -0.30331E-11 116 microcline -2.49 -2.49 0.00 0.000 0.15165E-11 163 stilbite -7.52 -7.52 0.00 0.000 -0.90992E-11 164 stilpnomelane-Fe 13.02 13.02 0.00 0.000 0.21232E-10 245 tr.625ac.25prg.125 45.16 45.16 0.00 0.000 -0.48529E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -16.79 -10.13 -3.376 0.17292E+05 -8.428 3 CH4,gas 4.54 1.14 -3.40 -0.850 0.58039E+04 -1.700 4 H2,gas 8.00 4.48 -3.52 -2.010 0.60049E+04 -1.818 5 H2S,gas -6.23 -14.76 -8.53 -4.265 0.14565E+05 -6.831 6 S2,gas -7.34 -38.49 -31.15 -4.792 0.53190E+05 -29.452 7 CO,gas 3.21 -12.30 -15.52 -4.775 0.26499E+05 -13.820 8 SO3,gas 17.12 -32.69 -49.81 -12.453 0.85055E+05 -48.114 9 SO2,gas 0.83 -28.21 -29.04 -7.744 0.49587E+05 -27.342 10 HCl,gas 5.19 -14.03 -19.22 -9.609 0.32815E+05 -17.520 11 acmite 7.71 6.53 -1.18 -0.123 0.20177E+04 15 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 19 spessartine 24.46 19.72 -4.74 -0.237 0.80892E+04 20 analcite 3.32 2.77 -0.55 -0.061 0.93618E+03 26 annite 20.12 17.72 -2.40 -0.134 0.41063E+04 27 phlogopite 27.06 25.40 -1.67 -0.093 0.28487E+04 29 anorthite 12.71 8.27 -4.45 -0.342 0.75899E+04 35 aragonite 0.97 -3.69 -4.65 -1.551 0.79428E+04 36 brucite 12.57 9.29 -3.27 -0.655 0.55908E+04 37 calcite 0.81 -3.69 -4.50 -1.499 0.76785E+04 38 carnegieite-low 9.02 5.93 -3.09 -0.442 0.52800E+04 39 carnegieite-high 10.09 5.93 -4.16 -0.595 0.71070E+04 40 carpholite-Mg 8.58 4.46 -4.12 -0.275 0.70425E+04 41 carpholite-Fe 6.71 1.90 -4.81 -0.321 0.82203E+04 42 celadonite 5.34 3.65 -1.69 -0.099 0.28879E+04 43 celadonite-Fe 3.88 1.09 -2.79 -0.164 0.47561E+04 44 chrysotile 23.89 21.57 -2.32 -0.194 0.39691E+04 49 chlorite-Al-free 47.17 43.14 -4.04 -0.168 0.68934E+04 51 chloritoid-Fe 9.17 5.06 -4.12 -0.275 0.70312E+04 52 chloritoid-Mn 11.40 7.56 -3.84 -0.256 0.65607E+04 54 coesite -2.38 -3.16 -0.78 -0.260 0.13342E+04 61 cristobalite -2.56 -3.16 -0.60 -0.199 0.10195E+04 63 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71234E+04 65 diaspore 2.87 0.74 -2.13 -0.356 0.36448E+04 66 diamond -3.10 -7.82 -4.72 -1.348 0.80574E+04 71 enstatite 17.26 12.27 -4.99 -0.499 0.85225E+04 73 clinoenstatite 17.17 12.27 -4.89 -0.489 0.83541E+04 75 epidote 24.67 22.70 -1.97 -0.095 0.33582E+04 76 clinozoisite 22.81 18.95 -3.86 -0.175 0.65863E+04 77 epidote-Fe 29.84 26.46 -3.38 -0.176 0.57768E+04 78 fayalite 14.05 10.31 -3.73 -0.533 0.63743E+04 79 ferrosilite 11.15 7.16 -3.99 -0.399 0.68203E+04 83 gibbsite 4.08 0.74 -3.34 -0.477 0.57033E+04 84 glaucophane 22.97 20.80 -2.17 -0.059 0.37132E+04 85 glaucophane-Fe 17.28 13.12 -4.15 -0.112 0.70919E+04 86 graphite -3.55 -7.82 -4.28 -1.221 0.72996E+04 87 greenalite 16.14 13.89 -2.25 -0.187 0.38408E+04 90 hematite 12.57 8.99 -3.58 -0.434 0.61112E+04 91 heulandite -5.83 -7.52 -1.69 -0.077 0.28938E+04 95 jadeite 4.22 2.77 -1.44 -0.144 0.24617E+04 97 kalsilite 7.58 3.83 -3.76 -0.537 0.64124E+04 98 kaolinite -1.33 -4.84 -3.50 -0.319 0.59829E+04 101 laumontite 2.88 1.95 -0.93 -0.062 0.15933E+04 102 lawsonite 9.62 8.27 -1.35 -0.090 0.23066E+04 103 leucite 4.12 0.67 -3.45 -0.345 0.58872E+04 105 lizardite 23.24 21.57 -1.68 -0.140 0.28617E+04 107 magnetite 20.09 15.72 -4.37 -0.356 0.74537E+04 108 minnesotaite 10.39 7.58 -2.81 -0.165 0.48030E+04 112 manganosite 14.06 9.24 -4.82 -1.205 0.82302E+04 120 muscovite 2.58 -1.01 -3.59 -0.211 0.61311E+04 121 paragonite 4.24 1.09 -3.15 -0.185 0.53702E+04 122 nepheline 8.34 5.93 -2.41 -0.344 0.41123E+04 128 periclase-Fe 11.63 6.73 -4.89 -1.223 0.83523E+04 134 phlogopite-Na 29.65 27.50 -2.15 -0.119 0.36675E+04 136 prehnite 19.37 18.21 -1.16 -0.068 0.19846E+04 137 prehnite-Fe 22.50 21.96 -0.53 -0.032 0.91149E+03 138 pumpellyite-Fe 46.27 43.89 -2.38 -0.053 0.40572E+04 139 pumpellyite-Mg 48.99 46.45 -2.54 -0.056 0.43409E+04 143 pyrrhotite -4.26 -8.03 -3.77 -1.255 0.64288E+04 144 pyrrhotiteFe0.875 -6.02 -9.42 -3.41 -1.253 0.58160E+04 145 pyroxmangite 7.40 6.08 -1.32 -0.264 0.22507E+04 146 pyrophyllite -6.18 -11.15 -4.98 -0.311 0.84960E+04 147 quartz -2.99 -3.16 -0.17 -0.056 0.28687E+03 152 rhodonite 7.45 6.08 -1.37 -0.273 0.23309E+04 153 sanidine -1.28 -2.49 -1.21 -0.093 0.20677E+04 165 stilpnomelane-Mg 27.44 25.81 -1.63 -0.049 0.27801E+04 171 talc 16.49 15.25 -1.24 -0.073 0.21141E+04 174 tephroite 18.09 15.32 -2.77 -0.395 0.47250E+04 178 tridymite -2.63 -3.16 -0.53 -0.177 0.90685E+03 179 tremolite 47.87 47.42 -0.45 -0.012 0.77497E+03 180 ferroactinolite 38.45 34.62 -3.83 -0.104 0.65451E+04 181 troilite-low -4.41 -8.03 -3.61 -1.205 0.61716E+04 183 vesuvianite 223.47 218.82 -4.65 -0.036 0.79412E+04 187 wairakite 3.95 1.95 -2.00 -0.118 0.34152E+04 188 walstromite 11.51 9.94 -1.56 -0.313 0.26719E+04 189 wollastonite 10.46 9.94 -0.52 -0.103 0.88229E+03 190 pseudo-wollastonite 11.00 9.94 -1.06 -0.211 0.18021E+04 191 zoisite 22.85 18.95 -3.90 -0.177 0.66603E+04 192 akaganeite 7.75 4.49 -3.26 -0.705 0.55682E+04 199 chalcedony -2.80 -3.16 -0.36 -0.118 0.60617E+03 201 montmorillonite-Ca -2.29 -6.17 -3.88 -0.240 0.66179E+04 202 montmorillonite-K -2.24 -6.27 -4.03 -0.247 0.68815E+04 203 montmorillonite-Mg -2.48 -6.79 -4.31 -0.267 0.73677E+04 204 montmorillonite-Na -2.04 -5.57 -3.54 -0.216 0.60364E+04 205 nontronite-Ca 3.21 -0.20 -3.41 -0.221 0.58218E+04 206 nontronite-H 2.53 -2.36 -4.89 -0.328 0.83488E+04 207 nontronite-K 3.34 -0.30 -3.64 -0.233 0.62086E+04 208 nontronite-Mg 3.07 -0.82 -3.90 -0.253 0.66556E+04 209 nontronite-Na 3.52 0.40 -3.12 -0.200 0.53295E+04 224 tobermorite 9.82 7.76 -2.07 -0.564 0.35287E+04 230 alabandite -0.98 -5.52 -4.54 -1.515 0.77597E+04 233 boehmite 4.41 0.74 -3.67 -0.611 0.62617E+04 235 ferrous-oxide 9.81 6.73 -3.08 -0.769 0.52532E+04 240 silica-amorphous -2.09 -3.16 -1.07 -0.355 0.18204E+04 242 an20ab80 2.02 1.35 -0.67 -0.052 0.11471E+04 243 an25ab75 2.65 1.78 -0.87 -0.067 0.14809E+04 244 an30ab70 3.28 2.21 -1.07 -0.082 0.18243E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 40.0000000 g Current total amount of reactant added: 879.9990000 g New total amount of reactant added: 919.9990000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.3298E-10 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 11 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 919.9990000 Water: Moles liquid = 0.5029E+02 kg liquid = 0.9061E+00 Moles total = 0.4398E+02 kg total = 0.7922E+00 Activity = 1.0000 Stoichiometric ionic strength = .1132924E-01 Osmotic coef. = 0.9694 True ionic strength = .2001696E-01 Chg. balance for total moles = 0.3298E-10 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.88287E-10 -10.0541 0.74184E-10 -10.1297 0.84025E+00 -0.0756 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.15158E-03 -3.8194 0.12660E-03 -3.8976 0.83520E+00 -0.0782 4 SO4-- 0.71419E-12 -12.1462 0.37089E-12 -12.4308 0.51932E+00 -0.2846 5 HCO3- 0.26430E-06 -6.5779 0.22107E-06 -6.6555 0.83642E+00 -0.0776 6 HS- 0.28143E-04 -4.5506 0.23508E-04 -4.6288 0.83532E+00 -0.0781 7 Al+++ 0.96900E-29 -29.0137 0.22388E-29 -29.6500 0.23104E+00 -0.6363 8 H4SiO4 0.69591E-03 -3.1574 0.69591E-03 -3.1574 0.10000E+01 0.0000 9 Ca++ 0.13497E-06 -6.8697 0.69580E-07 -7.1575 0.51550E+00 -0.2878 10 Mg++ 0.21116E-10 -10.6754 0.10836E-10 -10.9651 0.51315E+00 -0.2898 11 Fe++ 0.58196E-13 -13.2351 0.29896E-13 -13.5244 0.51371E+00 -0.2893 12 K+ 0.15650E-03 -3.8055 0.13093E-03 -3.8829 0.83662E+00 -0.0775 13 Na+ 0.19859E-01 -1.7020 0.16584E-01 -1.7803 0.83505E+00 -0.0783 14 Mn++ 0.18523E-10 -10.7323 0.95232E-11 -11.0212 0.51413E+00 -0.2889 15 HPO4-- 0.45319E-07 -7.3437 0.23538E-07 -7.6282 0.51939E+00 -0.2845 16 HSiO3- 0.10488E-01 -1.9793 0.87594E-02 -2.0575 0.83520E+00 -0.0782 17 Ca(HSiO3)+ 0.16587E-07 -7.7802 0.13880E-07 -7.8576 0.83680E+00 -0.0774 18 Mg(HSiO3)+ 0.32147E-11 -11.4929 0.26901E-11 -11.5702 0.83680E+00 -0.0774 19 NaHSiO3,aq 0.23494E-02 -2.6290 0.23494E-02 -2.6290 0.10000E+01 0.0000 20 AlO+ 0.66138E-16 -16.1795 0.55345E-16 -16.2569 0.83680E+00 -0.0774 22 HAlO2,aq 0.14857E-09 -9.8281 0.14857E-09 -9.8281 0.10000E+01 0.0000 23 AlO2- 0.53177E-05 -5.2743 0.44334E-05 -5.3533 0.83369E+00 -0.0790 24 CH4,aq 0.13658E-04 -4.8646 0.13611E-04 -4.8661 0.99654E+00 -0.0015 25 C2H6,aq 0.27432E-14 -14.5617 0.27337E-14 -14.5632 0.99654E+00 -0.0015 29 CO,aq 0.10198E-16 -16.9915 0.10198E-16 -16.9915 0.10000E+01 0.0000 30 CO2,aq 0.35163E-10 -10.4539 0.35042E-10 -10.4554 0.99654E+00 -0.0015 31 CO3-2 0.50228E-06 -6.2991 0.26029E-06 -6.5845 0.51821E+00 -0.2855 32 CaCO3,aq 0.22709E-09 -9.6438 0.22709E-09 -9.6438 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.46921E-12 -12.3286 0.39264E-12 -12.4060 0.83680E+00 -0.0774 34 CaCl+ 0.17036E-10 -10.7686 0.14256E-10 -10.8460 0.83680E+00 -0.0774 35 CaCl2,aq 0.42877E-15 -15.3678 0.42877E-15 -15.3678 0.10000E+01 0.0000 36 CaOH+ 0.79884E-07 -7.0975 0.66847E-07 -7.1749 0.83680E+00 -0.0774 37 CaSO4,aq 0.81949E-17 -17.0865 0.81949E-17 -17.0865 0.10000E+01 0.0000 38 HCl,aq 0.17210E-14 -14.7642 0.17210E-14 -14.7642 0.10000E+01 0.0000 43 FeCl+ 0.71591E-17 -17.1451 0.59907E-17 -17.2225 0.83680E+00 -0.0774 46 FeO,aq 0.21113E-09 -9.6754 0.21113E-09 -9.6754 0.10000E+01 0.0000 47 FeOH+ 0.15676E-10 -10.8048 0.13118E-10 -10.8821 0.83680E+00 -0.0774 48 HFeO2- 0.35655E-07 -7.4479 0.29779E-07 -7.5261 0.83520E+00 -0.0782 49 FeO+ 0.10985E-16 -16.9592 0.91926E-17 -17.0366 0.83680E+00 -0.0774 51 FeO2- 0.40924E-09 -9.3880 0.34180E-09 -9.4662 0.83520E+00 -0.0782 52 HFeO2,aq 0.32249E-11 -11.4915 0.32249E-11 -11.4915 0.10000E+01 0.0000 53 H2,aq 0.11625E-04 -4.9346 0.11585E-04 -4.9361 0.99654E+00 -0.0015 54 KCl,aq 0.30043E-09 -9.5223 0.30043E-09 -9.5223 0.10000E+01 0.0000 56 KOH,aq 0.75375E-06 -6.1228 0.75375E-06 -6.1228 0.10000E+01 0.0000 57 KSO4- 0.90226E-15 -15.0447 0.75357E-15 -15.1229 0.83520E+00 -0.0782 58 MgCO3,aq 0.88644E-14 -14.0524 0.88644E-14 -14.0524 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.74663E-16 -16.1269 0.62478E-16 -16.2043 0.83680E+00 -0.0774 60 MgCl+ 0.24045E-14 -14.6190 0.20121E-14 -14.6964 0.83680E+00 -0.0774 61 MgOH+ 0.68838E-10 -10.1622 0.57604E-10 -10.2396 0.83680E+00 -0.0774 63 MnO,aq 0.17921E-08 -8.7466 0.17921E-08 -8.7466 0.10000E+01 0.0000 64 MnOH+ 0.46389E-09 -9.3336 0.38819E-09 -9.4110 0.83680E+00 -0.0774 65 MnO2-2 0.20855E-10 -10.6808 0.10807E-10 -10.9663 0.51821E+00 -0.2855 66 HMnO2- 0.21030E-09 -9.6772 0.17565E-09 -9.7554 0.83520E+00 -0.0782 69 MnCl+ 0.88722E-14 -14.0520 0.74243E-14 -14.1293 0.83680E+00 -0.0774 71 NaCl,aq 0.69578E-06 -6.1575 0.69578E-06 -6.1575 0.10000E+01 0.0000 72 NaOH,aq 0.96047E-04 -4.0175 0.96047E-04 -4.0175 0.10000E+01 0.0000 74 OH- 0.93421E-02 -2.0296 0.77884E-02 -2.1085 0.83369E+00 -0.0790 79 HPO3-2 0.16399E-14 -14.7852 0.84980E-15 -15.0707 0.51821E+00 -0.2855 81 H2PO3- 0.15136E-18 -18.8200 0.12642E-18 -18.8982 0.83520E+00 -0.0782 82 H3PO4,aq 0.90596E-18 -18.0429 0.90596E-18 -18.0429 0.10000E+01 0.0000 83 H2PO4- 0.38531E-10 -10.4142 0.32212E-10 -10.4920 0.83599E+00 -0.0778 84 PO4-3 0.10668E-08 -8.9719 0.25888E-09 -9.5869 0.24266E+00 -0.6150 88 HP2O7-3 0.94687E-18 -18.0237 0.21898E-18 -18.6596 0.23127E+00 -0.6359 89 P2O7-4 0.91450E-17 -17.0388 0.70521E-18 -18.1517 0.77113E-01 -1.1129 90 H2S,aq 0.54085E-08 -8.2669 0.53899E-08 -8.2684 0.99654E+00 -0.0015 91 S2-2 0.20397E-14 -14.6904 0.10570E-14 -14.9759 0.51821E+00 -0.2855 97 SO3-2 0.10621E-17 -17.9738 0.55837E-18 -18.2531 0.52571E+00 -0.2793 99 HSO4- 0.31656E-19 -19.4995 0.26516E-19 -19.5765 0.83762E+00 -0.0770 Charge balance for all species = 0.3640E-10 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.8828697E-10 -.2230094E-01 -.2243895E+02 0.0000 2 H2O 0.1000000E+01 0.5550489E+02 0.9981996E+06 0.0000 3 Cl- 0.1515808E-03 0.1522768E-03 0.5389290E+01 6.2321 4 SO4-- 0.7141950E-12 -.1656428E-04 -.1588427E+01 7.8286 5 HCO3- 0.2642980E-06 0.1442486E-04 0.8786352E+00 3.4742 6 HS- 0.2814290E-04 0.4471260E-04 0.1476165E+01 5.5009 7 Al+++ 0.9690032E-29 0.5317882E-05 0.1432351E+00 0.7391 8 H4SiO4 0.6959140E-03 0.1353312E-01 0.1298481E+04 -3.1574 9 Ca++ 0.1349749E-06 0.2316905E-06 0.9269555E-02 13.1019 10 Mg++ 0.2111604E-10 0.9317987E-10 0.2261452E-05 9.2942 11 Fe++ 0.5819563E-13 0.3629422E-07 0.2023401E-02 6.7350 12 K+ 0.1565027E-03 0.1572568E-03 0.6138369E+01 6.2467 13 Na+ 0.1985940E-01 0.2230557E-01 0.5119094E+03 8.3494 14 Mn++ 0.1852285E-10 0.2505683E-08 0.1374180E-03 9.2382 15 HPO4-- 0.4531866E-07 0.4642403E-07 0.4447989E-02 12.6312 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.1523380E+02 -.2020632E-01 -.1521360E+02 0.0000000E+00 2 H2O 0.4397569E+02 0.5029157E+02 -.6315882E+01 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.2552181E-01 -.1500848E-04 0.2553682E-01 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.2549631E-01 0.4051295E-04 -.2553682E-01 0.0000000E+00 7 Al+++ 0.2999879E+01 0.4818398E-05 0.2999874E+01 0.0000000E+00 8 H4SiO4 0.9579750E+01 0.1226201E-01 0.9567488E+01 0.0000000E+00 9 Ca++ 0.1058145E+01 0.2099289E-06 0.1058144E+01 0.0000000E+00 10 Mg++ 0.7301579E+00 0.8442791E-10 0.7301579E+00 0.0000000E+00 11 Fe++ 0.6559672E+00 0.3288527E-07 0.6559672E+00 0.0000000E+00 12 K+ 0.1953289E+00 0.1424864E-03 0.1951864E+00 0.0000000E+00 13 Na+ 0.1154983E+01 0.2021051E-01 0.1134772E+01 0.0000000E+00 14 Mn++ 0.1595149E-01 0.2270336E-08 0.1595149E-01 0.0000000E+00 15 HPO4-- 0.5444165E-02 0.4206363E-07 0.5444123E-02 0.0000000E+00 Chg. balance for solid moles: -.5621E-15 Mass of aqueous solution: 0.907652E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 919.9990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 1.134 0.055 297.3 2.473 29.58 114.1 andradite 0.1021 -0.991 51.91 1.715 5.166 13.49 grossular 0.2474E-01 -1.607 11.15 1.047 1.109 3.101 apatite-OH 0.1815E-02 -2.741 0.9116 -0.040 0.9071E-01 0.2897 clinochlore 0.1317 -0.880 73.22 1.865 7.287 27.85 daphnite 0.3813E-01 -1.419 27.21 1.435 2.708 8.245 chlorite-Mn 0.3190E-02 -2.496 2.262 0.354 0.2251 0.7208 diopside 0.4078E-01 -1.390 8.831 0.946 0.8788 2.699 hedenbergite 0.1057E-01 -1.976 2.624 0.419 0.2611 0.7186 microcline 0.1712 -0.766 47.65 1.678 4.742 18.61 stilbite 0.6001 -0.222 422.9 2.626 42.08 197.3 stilpnomelane-Fe 0.4797E-01 -1.319 51.71 1.714 5.146 17.86 tr.625ac.25prg.125 0.8465E-02 -2.072 7.235 0.859 0.7200 2.329 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8050E+00 0.8050E+00 1.0000 -0.094 grossular 0.1950E+00 0.1950E+00 1.0000 -0.710 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.7612E+00 0.7612E+00 1.0000 -0.118 daphnite 0.2204E+00 0.2204E+00 1.0000 -0.657 chlorite-Mn 0.1843E-01 0.1843E-01 1.0000 -1.734 diopside 0.7941E+00 0.7941E+00 1.0000 -0.100 hedenbergite 0.2059E+00 0.2059E+00 1.0000 -0.686 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 tr.625ac.25prg.125 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 1004.910774 g Volume = 407.292840 cm3 Porosity: -10.3776% V(tot) - V(min): -.38293E+02 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 919.9990000 g log = 2.9638 Original solution: 1000.0103000 g Original solution / Rock added: 1.09 (Water/Rock Ratio), log = 0.0362 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0558 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9669E+00 0.9855 0.1006E+01 0.1021E+01 CO2,gas 0.3527E-08 1.0069 0.3749E-08 0.3723E-08 CH4,gas 0.1874E-01 1.0124 0.2003E-01 0.1979E-01 H2,gas 0.1440E-01 1.0006 0.1521E-01 0.1520E-01 H2S,gas 0.1409E-06 0.9959 0.1482E-06 0.1488E-06 S2,gas 0.3374E-29 1.0000 0.3562E-29 0.3562E-29 CO,gas 0.1439E-13 1.0000 0.1520E-13 0.1520E-13 SO3,gas 0.7310E-48 1.0000 0.7717E-48 0.7717E-48 SO2,gas 0.4325E-27 1.0000 0.4567E-27 0.4567E-27 HCl,gas 0.2876E-17 1.0000 0.3037E-17 0.3037E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 16 albite -0.38 -0.38 0.00 0.000 0.11184E-10 22 andradite 39.01 39.01 0.00 0.000 0.12132E-10 23 grossular 32.73 32.73 0.00 0.000 0.12132E-10 32 apatite-OH -18.15 -18.15 0.00 0.000 0.00000E+00 46 clinochlore 39.07 39.07 0.00 0.000 0.00000E+00 47 daphnite 28.97 28.97 0.00 0.000 0.12132E-10 48 chlorite-Mn 46.87 46.87 0.00 0.000 0.12132E-10 67 diopside 16.18 16.18 0.00 0.000 0.00000E+00 68 hedenbergite 14.21 14.21 0.00 0.000 0.30331E-11 116 microcline -2.49 -2.49 0.00 0.000 0.15165E-11 163 stilbite -7.52 -7.52 0.00 0.000 -0.90992E-11 164 stilpnomelane-Fe 13.02 13.02 0.00 0.000 -0.27298E-10 245 tr.625ac.25prg.125 45.16 45.16 0.00 0.000 -0.24265E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -16.79 -10.13 -3.375 0.17288E+05 -8.426 3 CH4,gas 4.54 1.15 -3.40 -0.849 0.58006E+04 -1.698 4 H2,gas 8.00 4.48 -3.52 -2.010 0.60049E+04 -1.818 5 H2S,gas -6.23 -14.76 -8.53 -4.264 0.14562E+05 -6.829 6 S2,gas -7.34 -38.48 -31.15 -4.792 0.53183E+05 -29.448 7 CO,gas 3.21 -12.30 -15.52 -4.775 0.26495E+05 -13.818 8 SO3,gas 17.12 -32.69 -49.81 -12.453 0.85052E+05 -48.113 9 SO2,gas 0.83 -28.21 -29.04 -7.744 0.49584E+05 -27.340 10 HCl,gas 5.19 -14.03 -19.22 -9.608 0.32812E+05 -17.518 11 acmite 7.71 6.53 -1.18 -0.123 0.20177E+04 15 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 19 spessartine 24.46 19.72 -4.74 -0.237 0.80882E+04 20 analcite 3.32 2.77 -0.55 -0.061 0.93618E+03 26 annite 20.12 17.72 -2.40 -0.134 0.41063E+04 27 phlogopite 27.06 25.40 -1.67 -0.093 0.28487E+04 29 anorthite 12.71 8.27 -4.45 -0.342 0.75900E+04 35 aragonite 0.97 -3.68 -4.65 -1.550 0.79394E+04 36 brucite 12.57 9.29 -3.27 -0.655 0.55908E+04 37 calcite 0.81 -3.68 -4.50 -1.498 0.76752E+04 38 carnegieite-low 9.02 5.93 -3.09 -0.442 0.52800E+04 39 carnegieite-high 10.09 5.93 -4.16 -0.595 0.71070E+04 40 carpholite-Mg 8.58 4.46 -4.12 -0.275 0.70426E+04 41 carpholite-Fe 6.71 1.90 -4.81 -0.321 0.82204E+04 42 celadonite 5.34 3.65 -1.69 -0.099 0.28879E+04 43 celadonite-Fe 3.88 1.09 -2.79 -0.164 0.47561E+04 44 chrysotile 23.89 21.57 -2.32 -0.194 0.39691E+04 49 chlorite-Al-free 47.17 43.14 -4.04 -0.168 0.68934E+04 51 chloritoid-Fe 9.17 5.06 -4.12 -0.275 0.70312E+04 52 chloritoid-Mn 11.40 7.56 -3.84 -0.256 0.65604E+04 54 coesite -2.38 -3.16 -0.78 -0.260 0.13342E+04 61 cristobalite -2.56 -3.16 -0.60 -0.199 0.10195E+04 63 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71234E+04 65 diaspore 2.87 0.74 -2.13 -0.356 0.36448E+04 66 diamond -3.10 -7.82 -4.72 -1.348 0.80541E+04 71 enstatite 17.26 12.27 -4.99 -0.499 0.85225E+04 73 clinoenstatite 17.17 12.27 -4.89 -0.489 0.83541E+04 75 epidote 24.67 22.70 -1.97 -0.095 0.33582E+04 76 clinozoisite 22.81 18.95 -3.86 -0.175 0.65863E+04 77 epidote-Fe 29.84 26.46 -3.38 -0.176 0.57768E+04 78 fayalite 14.05 10.31 -3.73 -0.533 0.63743E+04 79 ferrosilite 11.15 7.16 -3.99 -0.399 0.68203E+04 83 gibbsite 4.08 0.74 -3.34 -0.477 0.57033E+04 84 glaucophane 22.97 20.80 -2.17 -0.059 0.37133E+04 85 glaucophane-Fe 17.28 13.12 -4.15 -0.112 0.70919E+04 86 graphite -3.55 -7.82 -4.27 -1.221 0.72963E+04 87 greenalite 16.14 13.89 -2.25 -0.187 0.38408E+04 90 hematite 12.57 8.99 -3.58 -0.434 0.61112E+04 91 heulandite -5.83 -7.52 -1.69 -0.077 0.28938E+04 95 jadeite 4.22 2.77 -1.44 -0.144 0.24617E+04 97 kalsilite 7.58 3.83 -3.76 -0.537 0.64124E+04 98 kaolinite -1.33 -4.84 -3.50 -0.319 0.59829E+04 101 laumontite 2.88 1.95 -0.93 -0.062 0.15933E+04 102 lawsonite 9.62 8.27 -1.35 -0.090 0.23066E+04 103 leucite 4.12 0.67 -3.45 -0.345 0.58872E+04 105 lizardite 23.24 21.57 -1.68 -0.140 0.28617E+04 107 magnetite 20.09 15.72 -4.37 -0.356 0.74537E+04 108 minnesotaite 10.39 7.58 -2.81 -0.165 0.48030E+04 112 manganosite 14.06 9.24 -4.82 -1.205 0.82299E+04 120 muscovite 2.58 -1.01 -3.59 -0.211 0.61311E+04 121 paragonite 4.24 1.09 -3.15 -0.185 0.53702E+04 122 nepheline 8.34 5.93 -2.41 -0.344 0.41123E+04 128 periclase-Fe 11.63 6.73 -4.89 -1.223 0.83523E+04 134 phlogopite-Na 29.65 27.50 -2.15 -0.119 0.36675E+04 136 prehnite 19.37 18.21 -1.16 -0.068 0.19846E+04 137 prehnite-Fe 22.50 21.96 -0.53 -0.032 0.91149E+03 138 pumpellyite-Fe 46.27 43.89 -2.38 -0.053 0.40572E+04 139 pumpellyite-Mg 48.99 46.45 -2.54 -0.056 0.43410E+04 143 pyrrhotite -4.26 -8.02 -3.76 -1.254 0.64255E+04 144 pyrrhotiteFe0.875 -6.02 -9.42 -3.40 -1.252 0.58127E+04 145 pyroxmangite 7.40 6.08 -1.32 -0.264 0.22504E+04 146 pyrophyllite -6.18 -11.15 -4.98 -0.311 0.84960E+04 147 quartz -2.99 -3.16 -0.17 -0.056 0.28687E+03 152 rhodonite 7.45 6.08 -1.36 -0.273 0.23306E+04 153 sanidine -1.28 -2.49 -1.21 -0.093 0.20677E+04 165 stilpnomelane-Mg 27.44 25.81 -1.63 -0.049 0.27801E+04 171 talc 16.49 15.25 -1.24 -0.073 0.21141E+04 174 tephroite 18.09 15.32 -2.77 -0.395 0.47244E+04 178 tridymite -2.63 -3.16 -0.53 -0.177 0.90685E+03 179 tremolite 47.87 47.42 -0.45 -0.012 0.77497E+03 180 ferroactinolite 38.45 34.62 -3.83 -0.104 0.65451E+04 181 troilite-low -4.41 -8.02 -3.61 -1.204 0.61683E+04 183 vesuvianite 223.47 218.82 -4.65 -0.036 0.79413E+04 187 wairakite 3.95 1.95 -2.00 -0.118 0.34153E+04 188 walstromite 11.51 9.94 -1.56 -0.313 0.26719E+04 189 wollastonite 10.46 9.94 -0.52 -0.103 0.88229E+03 190 pseudo-wollastonite 11.00 9.94 -1.06 -0.211 0.18021E+04 191 zoisite 22.85 18.95 -3.90 -0.177 0.66604E+04 192 akaganeite 7.75 4.49 -3.26 -0.705 0.55682E+04 199 chalcedony -2.80 -3.16 -0.36 -0.118 0.60617E+03 201 montmorillonite-Ca -2.29 -6.17 -3.88 -0.240 0.66179E+04 202 montmorillonite-K -2.24 -6.27 -4.03 -0.247 0.68815E+04 203 montmorillonite-Mg -2.48 -6.79 -4.31 -0.267 0.73677E+04 204 montmorillonite-Na -2.04 -5.57 -3.54 -0.216 0.60364E+04 205 nontronite-Ca 3.21 -0.20 -3.41 -0.221 0.58218E+04 206 nontronite-H 2.53 -2.36 -4.89 -0.328 0.83488E+04 207 nontronite-K 3.34 -0.30 -3.64 -0.233 0.62086E+04 208 nontronite-Mg 3.07 -0.82 -3.90 -0.253 0.66556E+04 209 nontronite-Na 3.52 0.40 -3.12 -0.200 0.53295E+04 224 tobermorite 9.82 7.76 -2.07 -0.564 0.35287E+04 230 alabandite -0.98 -5.52 -4.54 -1.514 0.77561E+04 233 boehmite 4.41 0.74 -3.67 -0.611 0.62617E+04 235 ferrous-oxide 9.81 6.73 -3.08 -0.769 0.52532E+04 240 silica-amorphous -2.09 -3.16 -1.07 -0.355 0.18203E+04 242 an20ab80 2.02 1.35 -0.67 -0.052 0.11471E+04 243 an25ab75 2.65 1.78 -0.87 -0.067 0.14809E+04 244 an30ab70 3.28 2.21 -1.07 -0.082 0.18243E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 40.0000000 g Current total amount of reactant added: 919.9990000 g New total amount of reactant added: 959.9990000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.3298E-10 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 11 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 959.9990000 Water: Moles liquid = 0.5007E+02 kg liquid = 0.9021E+00 Moles total = 0.4347E+02 kg total = 0.7832E+00 Activity = 1.0000 Stoichiometric ionic strength = .1132982E-01 Osmotic coef. = 0.9694 True ionic strength = .2001742E-01 Chg. balance for total moles = 0.3298E-10 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.88289E-10 -10.0541 0.74185E-10 -10.1297 0.84025E+00 -0.0756 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.15226E-03 -3.8174 0.12716E-03 -3.8956 0.83520E+00 -0.0782 4 SO4-- 0.71740E-12 -12.1442 0.37255E-12 -12.4288 0.51931E+00 -0.2846 5 HCO3- 0.26548E-06 -6.5760 0.22205E-06 -6.6535 0.83642E+00 -0.0776 6 HS- 0.28268E-04 -4.5487 0.23613E-04 -4.6268 0.83532E+00 -0.0781 7 Al+++ 0.96907E-29 -29.0136 0.22389E-29 -29.6500 0.23104E+00 -0.6363 8 H4SiO4 0.69592E-03 -3.1574 0.69592E-03 -3.1574 0.10000E+01 0.0000 9 Ca++ 0.13498E-06 -6.8697 0.69583E-07 -7.1575 0.51550E+00 -0.2878 10 Mg++ 0.21117E-10 -10.6754 0.10836E-10 -10.9651 0.51314E+00 -0.2898 11 Fe++ 0.58198E-13 -13.2351 0.29897E-13 -13.5244 0.51371E+00 -0.2893 12 K+ 0.15651E-03 -3.8055 0.13094E-03 -3.8829 0.83662E+00 -0.0775 13 Na+ 0.19860E-01 -1.7020 0.16584E-01 -1.7803 0.83505E+00 -0.0783 14 Mn++ 0.18531E-10 -10.7321 0.95274E-11 -11.0210 0.51413E+00 -0.2889 15 HPO4-- 0.45317E-07 -7.3437 0.23537E-07 -7.6282 0.51939E+00 -0.2845 16 HSiO3- 0.10488E-01 -1.9793 0.87593E-02 -2.0575 0.83520E+00 -0.0782 17 Ca(HSiO3)+ 0.16588E-07 -7.7802 0.13880E-07 -7.8576 0.83680E+00 -0.0774 18 Mg(HSiO3)+ 0.32148E-11 -11.4928 0.26901E-11 -11.5702 0.83680E+00 -0.0774 19 NaHSiO3,aq 0.23494E-02 -2.6290 0.23494E-02 -2.6290 0.10000E+01 0.0000 20 AlO+ 0.66139E-16 -16.1795 0.55345E-16 -16.2569 0.83680E+00 -0.0774 22 HAlO2,aq 0.14857E-09 -9.8281 0.14857E-09 -9.8281 0.10000E+01 0.0000 23 AlO2- 0.53176E-05 -5.2743 0.44332E-05 -5.3533 0.83369E+00 -0.0790 24 CH4,aq 0.13719E-04 -4.8627 0.13671E-04 -4.8642 0.99654E+00 -0.0015 25 C2H6,aq 0.27677E-14 -14.5579 0.27581E-14 -14.5594 0.99654E+00 -0.0015 29 CO,aq 0.10244E-16 -16.9895 0.10244E-16 -16.9895 0.10000E+01 0.0000 30 CO2,aq 0.35321E-10 -10.4520 0.35199E-10 -10.4535 0.99654E+00 -0.0015 31 CO3-2 0.50452E-06 -6.2971 0.26145E-06 -6.5826 0.51821E+00 -0.2855 32 CaCO3,aq 0.22811E-09 -9.6419 0.22811E-09 -9.6419 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.47133E-12 -12.3267 0.39441E-12 -12.4041 0.83680E+00 -0.0774 34 CaCl+ 0.17112E-10 -10.7667 0.14320E-10 -10.8441 0.83680E+00 -0.0774 35 CaCl2,aq 0.43262E-15 -15.3639 0.43262E-15 -15.3639 0.10000E+01 0.0000 36 CaOH+ 0.79885E-07 -7.0975 0.66848E-07 -7.1749 0.83680E+00 -0.0774 37 CaSO4,aq 0.82319E-17 -17.0845 0.82319E-17 -17.0845 0.10000E+01 0.0000 38 HCl,aq 0.17287E-14 -14.7623 0.17287E-14 -14.7623 0.10000E+01 0.0000 43 FeCl+ 0.71912E-17 -17.1432 0.60176E-17 -17.2206 0.83680E+00 -0.0774 46 FeO,aq 0.21113E-09 -9.6754 0.21113E-09 -9.6754 0.10000E+01 0.0000 47 FeOH+ 0.15677E-10 -10.8047 0.13118E-10 -10.8821 0.83680E+00 -0.0774 48 HFeO2- 0.35654E-07 -7.4479 0.29778E-07 -7.5261 0.83520E+00 -0.0782 49 FeO+ 0.10986E-16 -16.9592 0.91929E-17 -17.0365 0.83680E+00 -0.0774 51 FeO2- 0.40924E-09 -9.3880 0.34180E-09 -9.4662 0.83520E+00 -0.0782 52 HFeO2,aq 0.32249E-11 -11.4915 0.32249E-11 -11.4915 0.10000E+01 0.0000 53 H2,aq 0.11625E-04 -4.9346 0.11585E-04 -4.9361 0.99654E+00 -0.0015 54 KCl,aq 0.30178E-09 -9.5203 0.30178E-09 -9.5203 0.10000E+01 0.0000 56 KOH,aq 0.75375E-06 -6.1228 0.75375E-06 -6.1228 0.10000E+01 0.0000 57 KSO4- 0.90632E-15 -15.0427 0.75696E-15 -15.1209 0.83520E+00 -0.0782 58 MgCO3,aq 0.89042E-14 -14.0504 0.89042E-14 -14.0504 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.75000E-16 -16.1249 0.62760E-16 -16.2023 0.83680E+00 -0.0774 60 MgCl+ 0.24153E-14 -14.6170 0.20211E-14 -14.6944 0.83680E+00 -0.0774 61 MgOH+ 0.68839E-10 -10.1622 0.57605E-10 -10.2395 0.83680E+00 -0.0774 63 MnO,aq 0.17928E-08 -8.7465 0.17928E-08 -8.7465 0.10000E+01 0.0000 64 MnOH+ 0.46409E-09 -9.3334 0.38835E-09 -9.4108 0.83680E+00 -0.0774 65 MnO2-2 0.20862E-10 -10.6806 0.10811E-10 -10.9661 0.51821E+00 -0.2855 66 HMnO2- 0.21038E-09 -9.6770 0.17571E-09 -9.7552 0.83520E+00 -0.0782 69 MnCl+ 0.89157E-14 -14.0498 0.74606E-14 -14.1272 0.83680E+00 -0.0774 71 NaCl,aq 0.69889E-06 -6.1556 0.69889E-06 -6.1556 0.10000E+01 0.0000 72 NaOH,aq 0.96047E-04 -4.0175 0.96047E-04 -4.0175 0.10000E+01 0.0000 74 OH- 0.93419E-02 -2.0296 0.77883E-02 -2.1086 0.83369E+00 -0.0790 79 HPO3-2 0.16398E-14 -14.7852 0.84976E-15 -15.0707 0.51821E+00 -0.2855 81 H2PO3- 0.15136E-18 -18.8200 0.12641E-18 -18.8982 0.83520E+00 -0.0782 82 H3PO4,aq 0.90597E-18 -18.0429 0.90597E-18 -18.0429 0.10000E+01 0.0000 83 H2PO4- 0.38530E-10 -10.4142 0.32211E-10 -10.4920 0.83599E+00 -0.0778 84 PO4-3 0.10668E-08 -8.9719 0.25886E-09 -9.5869 0.24266E+00 -0.6150 88 HP2O7-3 0.94684E-18 -18.0237 0.21897E-18 -18.6596 0.23127E+00 -0.6359 89 P2O7-4 0.91446E-17 -17.0388 0.70516E-18 -18.1517 0.77111E-01 -1.1129 90 H2S,aq 0.54327E-08 -8.2650 0.54140E-08 -8.2665 0.99654E+00 -0.0015 91 S2-2 0.20580E-14 -14.6866 0.10665E-14 -14.9721 0.51821E+00 -0.2855 97 SO3-2 0.10669E-17 -17.9719 0.56086E-18 -18.2511 0.52571E+00 -0.2793 99 HSO4- 0.31799E-19 -19.4976 0.26635E-19 -19.5745 0.83762E+00 -0.0770 Charge balance for all species = 0.3656E-10 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.8828899E-10 -.2230061E-01 -.2243861E+02 0.0000 2 H2O 0.1000000E+01 0.5550489E+02 0.9981996E+06 0.0000 3 Cl- 0.1522558E-03 0.1529550E-03 0.5413289E+01 6.2340 4 SO4-- 0.7173953E-12 -.1662506E-04 -.1594255E+01 7.8306 5 HCO3- 0.2654813E-06 0.1448910E-04 0.8825479E+00 3.4761 6 HS- 0.2826823E-04 0.4489873E-04 0.1482310E+01 5.5028 7 Al+++ 0.9690653E-29 0.5317700E-05 0.1432302E+00 0.7391 8 H4SiO4 0.6959173E-03 0.1353297E-01 0.1298467E+04 -3.1574 9 Ca++ 0.1349809E-06 0.2316994E-06 0.9269911E-02 13.1019 10 Mg++ 0.2111696E-10 0.9318226E-10 0.2261510E-05 9.2942 11 Fe++ 0.5819839E-13 0.3629343E-07 0.2023357E-02 6.7350 12 K+ 0.1565063E-03 0.1572604E-03 0.6138510E+01 6.2467 13 Na+ 0.1985986E-01 0.2230604E-01 0.5119202E+03 8.3494 14 Mn++ 0.1853114E-10 0.2506688E-08 0.1374731E-03 9.2383 15 HPO4-- 0.4531736E-07 0.4642268E-07 0.4447859E-02 12.6311 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.1589615E+02 -.2011643E-01 -.1587603E+02 0.0000000E+00 2 H2O 0.4347427E+02 0.5006860E+02 -.6594332E+01 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.2663035E-01 -.1499676E-04 0.2664535E-01 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.2660484E-01 0.4050123E-04 -.2664535E-01 0.0000000E+00 7 Al+++ 0.3130309E+01 0.4796871E-05 0.3130304E+01 0.0000000E+00 8 H4SiO4 0.9996261E+01 0.1220752E-01 0.9984054E+01 0.0000000E+00 9 Ca++ 0.1104150E+01 0.2090062E-06 0.1104150E+01 0.0000000E+00 10 Mg++ 0.7619040E+00 0.8405576E-10 0.7619040E+00 0.0000000E+00 11 Fe++ 0.6844875E+00 0.3273876E-07 0.6844875E+00 0.0000000E+00 12 K+ 0.2038214E+00 0.1418579E-03 0.2036796E+00 0.0000000E+00 13 Na+ 0.1205193E+01 0.2012133E-01 0.1185071E+01 0.0000000E+00 14 Mn++ 0.1664503E-01 0.2261177E-08 0.1664503E-01 0.0000000E+00 15 HPO4-- 0.5680868E-02 0.4187592E-07 0.5680826E-02 0.0000000E+00 Chg. balance for solid moles: 0.4054E-14 Mass of aqueous solution: 0.903628E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 959.9990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 1.184 0.073 310.5 2.492 29.61 119.2 andradite 0.1066 -0.972 54.16 1.734 5.165 14.07 grossular 0.2582E-01 -1.588 11.63 1.066 1.109 3.236 apatite-OH 0.1894E-02 -2.723 0.9512 -0.022 0.9071E-01 0.3023 clinochlore 0.1374 -0.862 76.38 1.883 7.284 29.05 daphnite 0.3978E-01 -1.400 28.38 1.453 2.707 8.600 chlorite-Mn 0.3329E-02 -2.478 2.360 0.373 0.2251 0.7521 diopside 0.4296E-01 -1.367 9.302 0.969 0.8871 2.843 hedenbergite 0.1114E-01 -1.953 2.764 0.441 0.2635 0.7569 microcline 0.1786 -0.748 49.73 1.697 4.742 19.42 stilbite 0.6258 -0.204 441.0 2.644 42.06 205.7 stilpnomelane-Fe 0.5006E-01 -1.301 53.96 1.732 5.146 18.64 tr.625ac.25prg.125 0.8798E-02 -2.056 7.520 0.876 0.7172 2.420 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8050E+00 0.8050E+00 1.0000 -0.094 grossular 0.1950E+00 0.1950E+00 1.0000 -0.710 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.7612E+00 0.7612E+00 1.0000 -0.118 daphnite 0.2204E+00 0.2204E+00 1.0000 -0.657 chlorite-Mn 0.1844E-01 0.1844E-01 1.0000 -1.734 diopside 0.7941E+00 0.7941E+00 1.0000 -0.100 hedenbergite 0.2059E+00 0.2059E+00 1.0000 -0.686 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 tr.625ac.25prg.125 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 1048.611038 g Volume = 424.974066 cm3 Porosity: -10.3830% V(tot) - V(min): -.39974E+02 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 959.9990000 g log = 2.9823 Original solution: 1000.0103000 g Original solution / Rock added: 1.04 (Water/Rock Ratio), log = 0.0177 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0559 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9668E+00 0.9855 0.1006E+01 0.1021E+01 CO2,gas 0.3542E-08 1.0069 0.3766E-08 0.3740E-08 CH4,gas 0.1882E-01 1.0124 0.2012E-01 0.1988E-01 H2,gas 0.1440E-01 1.0006 0.1521E-01 0.1520E-01 H2S,gas 0.1415E-06 0.9959 0.1488E-06 0.1494E-06 S2,gas 0.3404E-29 1.0000 0.3594E-29 0.3594E-29 CO,gas 0.1446E-13 1.0000 0.1527E-13 0.1527E-13 SO3,gas 0.7342E-48 1.0000 0.7752E-48 0.7752E-48 SO2,gas 0.4345E-27 1.0000 0.4587E-27 0.4587E-27 HCl,gas 0.2889E-17 1.0000 0.3050E-17 0.3050E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 16 albite -0.38 -0.38 0.00 0.000 -0.94784E-12 22 andradite 39.01 39.01 0.00 0.000 -0.12132E-10 23 grossular 32.73 32.73 0.00 0.000 0.00000E+00 32 apatite-OH -18.15 -18.15 0.00 0.000 0.00000E+00 46 clinochlore 39.07 39.07 0.00 0.000 0.00000E+00 47 daphnite 28.97 28.97 0.00 0.000 0.00000E+00 48 chlorite-Mn 46.87 46.87 0.00 0.000 0.24265E-10 67 diopside 16.18 16.18 0.00 0.000 0.00000E+00 68 hedenbergite 14.21 14.21 0.00 0.000 -0.30331E-11 116 microcline -2.49 -2.49 0.00 0.000 0.15165E-11 163 stilbite -7.52 -7.52 0.00 0.000 0.15165E-10 164 stilpnomelane-Fe 13.02 13.02 0.00 0.000 -0.27298E-10 245 tr.625ac.25prg.125 45.16 45.16 0.00 0.000 0.72794E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -16.78 -10.12 -3.374 0.17285E+05 -8.424 3 CH4,gas 4.54 1.15 -3.40 -0.849 0.57973E+04 -1.696 4 H2,gas 8.00 4.48 -3.52 -2.010 0.60049E+04 -1.818 5 H2S,gas -6.23 -14.76 -8.53 -4.263 0.14558E+05 -6.827 6 S2,gas -7.34 -38.48 -31.14 -4.791 0.53177E+05 -29.444 7 CO,gas 3.21 -12.30 -15.52 -4.774 0.26492E+05 -13.816 8 SO3,gas 17.12 -32.69 -49.81 -12.452 0.85048E+05 -48.111 9 SO2,gas 0.83 -28.21 -29.04 -7.743 0.49581E+05 -27.338 10 HCl,gas 5.19 -14.03 -19.21 -9.607 0.32808E+05 -17.516 11 acmite 7.71 6.53 -1.18 -0.123 0.20177E+04 15 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 19 spessartine 24.46 19.72 -4.74 -0.237 0.80874E+04 20 analcite 3.32 2.77 -0.55 -0.061 0.93618E+03 26 annite 20.12 17.72 -2.40 -0.134 0.41063E+04 27 phlogopite 27.06 25.40 -1.67 -0.093 0.28487E+04 29 anorthite 12.71 8.27 -4.45 -0.342 0.75900E+04 35 aragonite 0.97 -3.68 -4.65 -1.549 0.79361E+04 36 brucite 12.57 9.29 -3.27 -0.655 0.55908E+04 37 calcite 0.81 -3.68 -4.49 -1.498 0.76719E+04 38 carnegieite-low 9.02 5.93 -3.09 -0.442 0.52800E+04 39 carnegieite-high 10.09 5.93 -4.16 -0.595 0.71070E+04 40 carpholite-Mg 8.58 4.46 -4.12 -0.275 0.70426E+04 41 carpholite-Fe 6.71 1.90 -4.81 -0.321 0.82204E+04 42 celadonite 5.34 3.65 -1.69 -0.099 0.28879E+04 43 celadonite-Fe 3.88 1.09 -2.79 -0.164 0.47561E+04 44 chrysotile 23.89 21.57 -2.32 -0.194 0.39691E+04 49 chlorite-Al-free 47.17 43.14 -4.04 -0.168 0.68934E+04 51 chloritoid-Fe 9.17 5.06 -4.12 -0.275 0.70312E+04 52 chloritoid-Mn 11.40 7.56 -3.84 -0.256 0.65601E+04 54 coesite -2.38 -3.16 -0.78 -0.260 0.13342E+04 61 cristobalite -2.56 -3.16 -0.60 -0.199 0.10195E+04 63 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71234E+04 65 diaspore 2.87 0.74 -2.13 -0.356 0.36448E+04 66 diamond -3.10 -7.82 -4.72 -1.347 0.80508E+04 71 enstatite 17.26 12.27 -4.99 -0.499 0.85225E+04 73 clinoenstatite 17.17 12.27 -4.89 -0.489 0.83541E+04 75 epidote 24.67 22.70 -1.97 -0.095 0.33582E+04 76 clinozoisite 22.81 18.95 -3.86 -0.175 0.65863E+04 77 epidote-Fe 29.84 26.46 -3.38 -0.176 0.57768E+04 78 fayalite 14.05 10.31 -3.73 -0.533 0.63743E+04 79 ferrosilite 11.15 7.16 -3.99 -0.399 0.68203E+04 83 gibbsite 4.08 0.74 -3.34 -0.477 0.57033E+04 84 glaucophane 22.97 20.80 -2.17 -0.059 0.37133E+04 85 glaucophane-Fe 17.28 13.12 -4.15 -0.112 0.70919E+04 86 graphite -3.55 -7.82 -4.27 -1.220 0.72930E+04 87 greenalite 16.14 13.89 -2.25 -0.187 0.38408E+04 90 hematite 12.57 8.99 -3.58 -0.434 0.61112E+04 91 heulandite -5.83 -7.52 -1.69 -0.077 0.28938E+04 95 jadeite 4.22 2.77 -1.44 -0.144 0.24617E+04 97 kalsilite 7.58 3.83 -3.76 -0.537 0.64124E+04 98 kaolinite -1.33 -4.84 -3.50 -0.319 0.59829E+04 101 laumontite 2.88 1.95 -0.93 -0.062 0.15933E+04 102 lawsonite 9.62 8.27 -1.35 -0.090 0.23066E+04 103 leucite 4.12 0.67 -3.45 -0.345 0.58872E+04 105 lizardite 23.24 21.57 -1.68 -0.140 0.28618E+04 107 magnetite 20.09 15.72 -4.37 -0.356 0.74537E+04 108 minnesotaite 10.39 7.58 -2.81 -0.165 0.48029E+04 112 manganosite 14.06 9.24 -4.82 -1.205 0.82296E+04 120 muscovite 2.58 -1.01 -3.59 -0.211 0.61311E+04 121 paragonite 4.24 1.09 -3.15 -0.185 0.53702E+04 122 nepheline 8.34 5.93 -2.41 -0.344 0.41123E+04 128 periclase-Fe 11.63 6.73 -4.89 -1.223 0.83523E+04 134 phlogopite-Na 29.65 27.50 -2.15 -0.119 0.36675E+04 136 prehnite 19.37 18.21 -1.16 -0.068 0.19846E+04 137 prehnite-Fe 22.50 21.96 -0.53 -0.032 0.91150E+03 138 pumpellyite-Fe 46.27 43.89 -2.38 -0.053 0.40573E+04 139 pumpellyite-Mg 48.99 46.45 -2.54 -0.056 0.43410E+04 143 pyrrhotite -4.26 -8.02 -3.76 -1.254 0.64222E+04 144 pyrrhotiteFe0.875 -6.02 -9.42 -3.40 -1.251 0.58094E+04 145 pyroxmangite 7.40 6.08 -1.32 -0.264 0.22501E+04 146 pyrophyllite -6.18 -11.15 -4.98 -0.311 0.84960E+04 147 quartz -2.99 -3.16 -0.17 -0.056 0.28687E+03 152 rhodonite 7.45 6.08 -1.36 -0.273 0.23303E+04 153 sanidine -1.28 -2.49 -1.21 -0.093 0.20677E+04 165 stilpnomelane-Mg 27.44 25.81 -1.63 -0.049 0.27801E+04 171 talc 16.49 15.25 -1.24 -0.073 0.21141E+04 174 tephroite 18.09 15.32 -2.77 -0.395 0.47238E+04 178 tridymite -2.63 -3.16 -0.53 -0.177 0.90684E+03 179 tremolite 47.87 47.42 -0.45 -0.012 0.77497E+03 180 ferroactinolite 38.45 34.62 -3.83 -0.104 0.65451E+04 181 troilite-low -4.41 -8.02 -3.61 -1.204 0.61650E+04 183 vesuvianite 223.47 218.82 -4.65 -0.036 0.79414E+04 187 wairakite 3.95 1.95 -2.00 -0.118 0.34153E+04 188 walstromite 11.51 9.94 -1.56 -0.313 0.26719E+04 189 wollastonite 10.46 9.94 -0.52 -0.103 0.88229E+03 190 pseudo-wollastonite 11.00 9.94 -1.06 -0.211 0.18021E+04 191 zoisite 22.85 18.95 -3.90 -0.177 0.66604E+04 192 akaganeite 7.75 4.49 -3.26 -0.705 0.55681E+04 199 chalcedony -2.80 -3.16 -0.36 -0.118 0.60616E+03 201 montmorillonite-Ca -2.29 -6.17 -3.88 -0.240 0.66179E+04 202 montmorillonite-K -2.24 -6.27 -4.03 -0.247 0.68815E+04 203 montmorillonite-Mg -2.48 -6.79 -4.31 -0.267 0.73677E+04 204 montmorillonite-Na -2.04 -5.57 -3.54 -0.216 0.60364E+04 205 nontronite-Ca 3.21 -0.20 -3.41 -0.221 0.58218E+04 206 nontronite-H 2.53 -2.36 -4.89 -0.328 0.83488E+04 207 nontronite-K 3.34 -0.30 -3.64 -0.233 0.62086E+04 208 nontronite-Mg 3.07 -0.82 -3.90 -0.253 0.66556E+04 209 nontronite-Na 3.52 0.40 -3.12 -0.200 0.53294E+04 224 tobermorite 9.82 7.76 -2.07 -0.564 0.35287E+04 230 alabandite -0.98 -5.52 -4.54 -1.513 0.77525E+04 233 boehmite 4.41 0.74 -3.67 -0.611 0.62617E+04 235 ferrous-oxide 9.81 6.73 -3.08 -0.769 0.52532E+04 240 silica-amorphous -2.09 -3.16 -1.07 -0.355 0.18203E+04 242 an20ab80 2.02 1.35 -0.67 -0.052 0.11471E+04 243 an25ab75 2.65 1.78 -0.87 -0.067 0.14809E+04 244 an30ab70 3.28 2.21 -1.07 -0.082 0.18243E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 40.0000000 g Current total amount of reactant added: 959.9990000 g New total amount of reactant added: 999.9990000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.3298E-10 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 11 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 999.9990000 Water: Moles liquid = 0.4985E+02 kg liquid = 0.8980E+00 Moles total = 0.4297E+02 kg total = 0.7742E+00 Activity = 1.0000 Stoichiometric ionic strength = .1133040E-01 Osmotic coef. = 0.9694 True ionic strength = .2001788E-01 Chg. balance for total moles = 0.3298E-10 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.88291E-10 -10.0541 0.74187E-10 -10.1297 0.84025E+00 -0.0756 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.15294E-03 -3.8155 0.12773E-03 -3.8937 0.83520E+00 -0.0782 4 SO4-- 0.72062E-12 -12.1423 0.37423E-12 -12.4269 0.51931E+00 -0.2846 5 HCO3- 0.26667E-06 -6.5740 0.22305E-06 -6.6516 0.83642E+00 -0.0776 6 HS- 0.28395E-04 -4.5468 0.23719E-04 -4.6249 0.83532E+00 -0.0781 7 Al+++ 0.96913E-29 -29.0136 0.22390E-29 -29.6499 0.23103E+00 -0.6363 8 H4SiO4 0.69592E-03 -3.1574 0.69592E-03 -3.1574 0.10000E+01 0.0000 9 Ca++ 0.13499E-06 -6.8697 0.69586E-07 -7.1575 0.51550E+00 -0.2878 10 Mg++ 0.21118E-10 -10.6753 0.10836E-10 -10.9651 0.51314E+00 -0.2898 11 Fe++ 0.58201E-13 -13.2351 0.29898E-13 -13.5244 0.51370E+00 -0.2893 12 K+ 0.15651E-03 -3.8055 0.13094E-03 -3.8829 0.83662E+00 -0.0775 13 Na+ 0.19860E-01 -1.7020 0.16584E-01 -1.7803 0.83505E+00 -0.0783 14 Mn++ 0.18539E-10 -10.7319 0.95313E-11 -11.0208 0.51413E+00 -0.2889 15 HPO4-- 0.45316E-07 -7.3437 0.23536E-07 -7.6283 0.51938E+00 -0.2845 16 HSiO3- 0.10487E-01 -1.9793 0.87591E-02 -2.0575 0.83520E+00 -0.0782 17 Ca(HSiO3)+ 0.16588E-07 -7.7802 0.13881E-07 -7.8576 0.83680E+00 -0.0774 18 Mg(HSiO3)+ 0.32148E-11 -11.4928 0.26902E-11 -11.5702 0.83680E+00 -0.0774 19 NaHSiO3,aq 0.23494E-02 -2.6290 0.23494E-02 -2.6290 0.10000E+01 0.0000 20 AlO+ 0.66140E-16 -16.1795 0.55346E-16 -16.2569 0.83680E+00 -0.0774 22 HAlO2,aq 0.14857E-09 -9.8281 0.14857E-09 -9.8281 0.10000E+01 0.0000 23 AlO2- 0.53174E-05 -5.2743 0.44331E-05 -5.3533 0.83369E+00 -0.0790 24 CH4,aq 0.13780E-04 -4.8607 0.13733E-04 -4.8622 0.99654E+00 -0.0015 25 C2H6,aq 0.27925E-14 -14.5540 0.27829E-14 -14.5555 0.99654E+00 -0.0015 29 CO,aq 0.10290E-16 -16.9876 0.10290E-16 -16.9876 0.10000E+01 0.0000 30 CO2,aq 0.35481E-10 -10.4500 0.35358E-10 -10.4515 0.99654E+00 -0.0015 31 CO3-2 0.50678E-06 -6.2952 0.26262E-06 -6.5807 0.51821E+00 -0.2855 32 CaCO3,aq 0.22914E-09 -9.6399 0.22914E-09 -9.6399 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.47346E-12 -12.3247 0.39619E-12 -12.4021 0.83680E+00 -0.0774 34 CaCl+ 0.17189E-10 -10.7647 0.14384E-10 -10.8421 0.83680E+00 -0.0774 35 CaCl2,aq 0.43651E-15 -15.3600 0.43651E-15 -15.3600 0.10000E+01 0.0000 36 CaOH+ 0.79887E-07 -7.0975 0.66849E-07 -7.1749 0.83680E+00 -0.0774 37 CaSO4,aq 0.82691E-17 -17.0825 0.82691E-17 -17.0825 0.10000E+01 0.0000 38 HCl,aq 0.17365E-14 -14.7603 0.17365E-14 -14.7603 0.10000E+01 0.0000 43 FeCl+ 0.72237E-17 -17.1412 0.60448E-17 -17.2186 0.83680E+00 -0.0774 46 FeO,aq 0.21113E-09 -9.6754 0.21113E-09 -9.6754 0.10000E+01 0.0000 47 FeOH+ 0.15677E-10 -10.8047 0.13118E-10 -10.8821 0.83680E+00 -0.0774 48 HFeO2- 0.35653E-07 -7.4479 0.29778E-07 -7.5261 0.83520E+00 -0.0782 49 FeO+ 0.10986E-16 -16.9592 0.91931E-17 -17.0365 0.83680E+00 -0.0774 51 FeO2- 0.40923E-09 -9.3880 0.34179E-09 -9.4662 0.83520E+00 -0.0782 52 HFeO2,aq 0.32249E-11 -11.4915 0.32249E-11 -11.4915 0.10000E+01 0.0000 53 H2,aq 0.11625E-04 -4.9346 0.11585E-04 -4.9361 0.99654E+00 -0.0015 54 KCl,aq 0.30313E-09 -9.5184 0.30313E-09 -9.5184 0.10000E+01 0.0000 56 KOH,aq 0.75375E-06 -6.1228 0.75375E-06 -6.1228 0.10000E+01 0.0000 57 KSO4- 0.91041E-15 -15.0408 0.76038E-15 -15.1190 0.83520E+00 -0.0782 58 MgCO3,aq 0.89444E-14 -14.0485 0.89444E-14 -14.0485 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.75340E-16 -16.1230 0.63045E-16 -16.2004 0.83680E+00 -0.0774 60 MgCl+ 0.24262E-14 -14.6151 0.20302E-14 -14.6925 0.83680E+00 -0.0774 61 MgOH+ 0.68840E-10 -10.1622 0.57606E-10 -10.2395 0.83680E+00 -0.0774 63 MnO,aq 0.17935E-08 -8.7463 0.17935E-08 -8.7463 0.10000E+01 0.0000 64 MnOH+ 0.46427E-09 -9.3332 0.38850E-09 -9.4106 0.83680E+00 -0.0774 65 MnO2-2 0.20869E-10 -10.6805 0.10815E-10 -10.9660 0.51821E+00 -0.2855 66 HMnO2- 0.21046E-09 -9.6768 0.17577E-09 -9.7551 0.83520E+00 -0.0782 69 MnCl+ 0.89592E-14 -14.0477 0.74971E-14 -14.1251 0.83680E+00 -0.0774 71 NaCl,aq 0.70203E-06 -6.1536 0.70203E-06 -6.1536 0.10000E+01 0.0000 72 NaOH,aq 0.96047E-04 -4.0175 0.96047E-04 -4.0175 0.10000E+01 0.0000 74 OH- 0.93417E-02 -2.0296 0.77881E-02 -2.1086 0.83369E+00 -0.0790 79 HPO3-2 0.16397E-14 -14.7852 0.84972E-15 -15.0707 0.51821E+00 -0.2855 81 H2PO3- 0.15135E-18 -18.8200 0.12641E-18 -18.8982 0.83520E+00 -0.0782 82 H3PO4,aq 0.90597E-18 -18.0429 0.90597E-18 -18.0429 0.10000E+01 0.0000 83 H2PO4- 0.38530E-10 -10.4142 0.32211E-10 -10.4920 0.83599E+00 -0.0778 84 PO4-3 0.10667E-08 -8.9719 0.25885E-09 -9.5870 0.24265E+00 -0.6150 88 HP2O7-3 0.94680E-18 -18.0237 0.21896E-18 -18.6596 0.23127E+00 -0.6359 89 P2O7-4 0.91442E-17 -17.0389 0.70511E-18 -18.1517 0.77110E-01 -1.1129 90 H2S,aq 0.54572E-08 -8.2630 0.54383E-08 -8.2645 0.99654E+00 -0.0015 91 S2-2 0.20764E-14 -14.6827 0.10760E-14 -14.9682 0.51821E+00 -0.2855 97 SO3-2 0.10717E-17 -17.9699 0.56338E-18 -18.2492 0.52570E+00 -0.2793 99 HSO4- 0.31942E-19 -19.4956 0.26755E-19 -19.5726 0.83761E+00 -0.0770 Charge balance for all species = 0.3673E-10 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.8829103E-10 -.2230027E-01 -.2243827E+02 0.0000 2 H2O 0.1000000E+01 0.5550489E+02 0.9981995E+06 0.0000 3 Cl- 0.1529368E-03 0.1536392E-03 0.5437503E+01 6.2360 4 SO4-- 0.7206217E-12 -.1668639E-04 -.1600136E+01 7.8325 5 HCO3- 0.2666743E-06 0.1455391E-04 0.8864956E+00 3.4781 6 HS- 0.2839468E-04 0.4508653E-04 0.1488510E+01 5.5048 7 Al+++ 0.9691288E-29 0.5317524E-05 0.1432254E+00 0.7391 8 H4SiO4 0.6959204E-03 0.1353282E-01 0.1298452E+04 -3.1574 9 Ca++ 0.1349869E-06 0.2317084E-06 0.9270272E-02 13.1019 10 Mg++ 0.2111790E-10 0.9318444E-10 0.2261563E-05 9.2942 11 Fe++ 0.5820116E-13 0.3629265E-07 0.2023313E-02 6.7350 12 K+ 0.1565099E-03 0.1572640E-03 0.6138650E+01 6.2467 13 Na+ 0.1986032E-01 0.2230651E-01 0.5119310E+03 8.3494 14 Mn++ 0.1853885E-10 0.2507614E-08 0.1375239E-03 9.2385 15 HPO4-- 0.4531601E-07 0.4642129E-07 0.4447726E-02 12.6311 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.1655849E+02 -.2002654E-01 -.1653846E+02 0.0000000E+00 2 H2O 0.4297285E+02 0.4984564E+02 -.6872783E+01 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.2773889E-01 -.1498506E-04 0.2775387E-01 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.2771338E-01 0.4048953E-04 -.2775387E-01 0.0000000E+00 7 Al+++ 0.3260738E+01 0.4775352E-05 0.3260734E+01 0.0000000E+00 8 H4SiO4 0.1041277E+02 0.1215302E-01 0.1040062E+02 0.0000000E+00 9 Ca++ 0.1150156E+01 0.2080835E-06 0.1150156E+01 0.0000000E+00 10 Mg++ 0.7936500E+00 0.8368339E-10 0.7936500E+00 0.0000000E+00 11 Fe++ 0.7130079E+00 0.3259227E-07 0.7130078E+00 0.0000000E+00 12 K+ 0.2123140E+00 0.1412294E-03 0.2121728E+00 0.0000000E+00 13 Na+ 0.1255402E+01 0.2003215E-01 0.1235370E+01 0.0000000E+00 14 Mn++ 0.1733858E-01 0.2251939E-08 0.1733858E-01 0.0000000E+00 15 HPO4-- 0.5917571E-02 0.4168819E-07 0.5917529E-02 0.0000000E+00 Chg. balance for solid moles: 0.2619E-14 Mass of aqueous solution: 0.899604E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 999.9990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 1.234 0.091 323.6 2.510 29.63 124.2 andradite 0.1110 -0.955 56.42 1.751 5.165 14.66 grossular 0.2689E-01 -1.570 12.11 1.083 1.109 3.370 apatite-OH 0.1973E-02 -2.705 0.9908 -0.004 0.9071E-01 0.3148 clinochlore 0.1431 -0.844 79.53 1.901 7.281 30.25 daphnite 0.4142E-01 -1.383 29.55 1.471 2.706 8.955 chlorite-Mn 0.3468E-02 -2.460 2.459 0.391 0.2251 0.7835 diopside 0.4513E-01 -1.346 9.774 0.990 0.8948 2.987 hedenbergite 0.1170E-01 -1.932 2.904 0.463 0.2658 0.7953 microcline 0.1861 -0.730 51.80 1.714 4.742 20.23 stilbite 0.6515 -0.186 459.1 2.662 42.03 214.1 stilpnomelane-Fe 0.5215E-01 -1.283 56.22 1.750 5.147 19.42 tr.625ac.25prg.125 0.9132E-02 -2.039 7.806 0.892 0.7146 2.512 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8050E+00 0.8050E+00 1.0000 -0.094 grossular 0.1950E+00 0.1950E+00 1.0000 -0.710 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.7612E+00 0.7612E+00 1.0000 -0.118 daphnite 0.2203E+00 0.2203E+00 1.0000 -0.657 chlorite-Mn 0.1845E-01 0.1845E-01 1.0000 -1.734 diopside 0.7941E+00 0.7941E+00 1.0000 -0.100 hedenbergite 0.2059E+00 0.2059E+00 1.0000 -0.686 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 tr.625ac.25prg.125 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 1092.311302 g Volume = 442.655291 cm3 Porosity: -10.3880% V(tot) - V(min): -.41656E+02 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 999.9990000 g log = 3.0000 Original solution: 1000.0103000 g Original solution / Rock added: 1.00 (Water/Rock Ratio), log = 0.0000 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0560 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9667E+00 0.9855 0.1006E+01 0.1021E+01 CO2,gas 0.3558E-08 1.0069 0.3783E-08 0.3757E-08 CH4,gas 0.1891E-01 1.0124 0.2021E-01 0.1996E-01 H2,gas 0.1440E-01 1.0006 0.1521E-01 0.1520E-01 H2S,gas 0.1422E-06 0.9959 0.1495E-06 0.1501E-06 S2,gas 0.3434E-29 1.0000 0.3626E-29 0.3626E-29 CO,gas 0.1452E-13 1.0000 0.1533E-13 0.1533E-13 SO3,gas 0.7375E-48 1.0000 0.7787E-48 0.7787E-48 SO2,gas 0.4364E-27 1.0000 0.4608E-27 0.4608E-27 HCl,gas 0.2902E-17 1.0000 0.3064E-17 0.3064E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 16 albite -0.38 -0.38 0.00 0.000 0.11184E-10 22 andradite 39.01 39.01 0.00 0.000 0.12132E-10 23 grossular 32.73 32.73 0.00 0.000 0.24265E-10 32 apatite-OH -18.15 -18.15 0.00 0.000 0.60662E-11 46 clinochlore 39.07 39.07 0.00 0.000 0.24265E-10 47 daphnite 28.97 28.97 0.00 0.000 0.42463E-10 48 chlorite-Mn 46.87 46.87 0.00 0.000 0.24265E-10 67 diopside 16.18 16.18 0.00 0.000 0.60662E-11 68 hedenbergite 14.21 14.21 0.00 0.000 0.12132E-10 116 microcline -2.49 -2.49 0.00 0.000 0.13649E-10 163 stilbite -7.52 -7.52 0.00 0.000 0.15165E-10 164 stilpnomelane-Fe 13.02 13.02 0.00 0.000 0.21232E-10 245 tr.625ac.25prg.125 45.16 45.16 0.00 0.000 -0.12132E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -16.78 -10.12 -3.374 0.17282E+05 -8.422 3 CH4,gas 4.54 1.15 -3.39 -0.848 0.57940E+04 -1.694 4 H2,gas 8.00 4.48 -3.52 -2.010 0.60049E+04 -1.818 5 H2S,gas -6.23 -14.75 -8.52 -4.262 0.14555E+05 -6.825 6 S2,gas -7.34 -38.47 -31.14 -4.791 0.53170E+05 -29.441 7 CO,gas 3.21 -12.30 -15.51 -4.773 0.26489E+05 -13.814 8 SO3,gas 17.12 -32.69 -49.81 -12.452 0.85045E+05 -48.109 9 SO2,gas 0.83 -28.20 -29.04 -7.743 0.49577E+05 -27.336 10 HCl,gas 5.19 -14.02 -19.21 -9.606 0.32805E+05 -17.514 11 acmite 7.71 6.53 -1.18 -0.123 0.20177E+04 15 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 19 spessartine 24.46 19.72 -4.74 -0.237 0.80866E+04 20 analcite 3.32 2.77 -0.55 -0.061 0.93619E+03 26 annite 20.12 17.72 -2.40 -0.134 0.41063E+04 27 phlogopite 27.06 25.40 -1.67 -0.093 0.28487E+04 29 anorthite 12.71 8.27 -4.45 -0.342 0.75900E+04 35 aragonite 0.97 -3.68 -4.65 -1.549 0.79328E+04 36 brucite 12.57 9.29 -3.27 -0.655 0.55908E+04 37 calcite 0.81 -3.68 -4.49 -1.497 0.76686E+04 38 carnegieite-low 9.02 5.93 -3.09 -0.442 0.52800E+04 39 carnegieite-high 10.09 5.93 -4.16 -0.595 0.71070E+04 40 carpholite-Mg 8.58 4.46 -4.12 -0.275 0.70426E+04 41 carpholite-Fe 6.71 1.90 -4.81 -0.321 0.82204E+04 42 celadonite 5.34 3.65 -1.69 -0.099 0.28879E+04 43 celadonite-Fe 3.88 1.09 -2.79 -0.164 0.47561E+04 44 chrysotile 23.89 21.57 -2.32 -0.194 0.39691E+04 49 chlorite-Al-free 47.17 43.14 -4.04 -0.168 0.68934E+04 51 chloritoid-Fe 9.17 5.06 -4.12 -0.275 0.70312E+04 52 chloritoid-Mn 11.40 7.56 -3.84 -0.256 0.65599E+04 54 coesite -2.38 -3.16 -0.78 -0.260 0.13342E+04 61 cristobalite -2.56 -3.16 -0.60 -0.199 0.10195E+04 63 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71234E+04 65 diaspore 2.87 0.74 -2.13 -0.356 0.36448E+04 66 diamond -3.10 -7.82 -4.71 -1.347 0.80474E+04 71 enstatite 17.26 12.27 -4.99 -0.499 0.85225E+04 73 clinoenstatite 17.17 12.27 -4.89 -0.489 0.83541E+04 75 epidote 24.67 22.70 -1.97 -0.095 0.33583E+04 76 clinozoisite 22.81 18.95 -3.86 -0.175 0.65864E+04 77 epidote-Fe 29.84 26.46 -3.38 -0.176 0.57768E+04 78 fayalite 14.05 10.31 -3.73 -0.533 0.63743E+04 79 ferrosilite 11.15 7.16 -3.99 -0.399 0.68202E+04 83 gibbsite 4.08 0.74 -3.34 -0.477 0.57033E+04 84 glaucophane 22.97 20.80 -2.17 -0.059 0.37133E+04 85 glaucophane-Fe 17.28 13.12 -4.15 -0.112 0.70919E+04 86 graphite -3.55 -7.82 -4.27 -1.220 0.72897E+04 87 greenalite 16.14 13.89 -2.25 -0.187 0.38408E+04 90 hematite 12.57 8.99 -3.58 -0.434 0.61112E+04 91 heulandite -5.83 -7.52 -1.69 -0.077 0.28938E+04 95 jadeite 4.22 2.77 -1.44 -0.144 0.24617E+04 97 kalsilite 7.58 3.83 -3.76 -0.537 0.64125E+04 98 kaolinite -1.33 -4.84 -3.50 -0.319 0.59829E+04 101 laumontite 2.88 1.95 -0.93 -0.062 0.15933E+04 102 lawsonite 9.62 8.27 -1.35 -0.090 0.23067E+04 103 leucite 4.12 0.67 -3.45 -0.345 0.58872E+04 105 lizardite 23.24 21.57 -1.68 -0.140 0.28618E+04 107 magnetite 20.09 15.72 -4.37 -0.356 0.74537E+04 108 minnesotaite 10.39 7.58 -2.81 -0.165 0.48029E+04 112 manganosite 14.06 9.24 -4.82 -1.205 0.82294E+04 120 muscovite 2.58 -1.01 -3.59 -0.211 0.61311E+04 121 paragonite 4.24 1.09 -3.15 -0.185 0.53702E+04 122 nepheline 8.34 5.93 -2.41 -0.344 0.41123E+04 128 periclase-Fe 11.63 6.73 -4.89 -1.223 0.83523E+04 134 phlogopite-Na 29.65 27.50 -2.15 -0.119 0.36675E+04 136 prehnite 19.37 18.21 -1.16 -0.068 0.19846E+04 137 prehnite-Fe 22.50 21.96 -0.53 -0.032 0.91150E+03 138 pumpellyite-Fe 46.27 43.89 -2.38 -0.053 0.40573E+04 139 pumpellyite-Mg 48.99 46.45 -2.54 -0.056 0.43411E+04 143 pyrrhotite -4.26 -8.02 -3.76 -1.253 0.64189E+04 144 pyrrhotiteFe0.875 -6.02 -9.42 -3.40 -1.251 0.58061E+04 145 pyroxmangite 7.40 6.08 -1.32 -0.264 0.22498E+04 146 pyrophyllite -6.18 -11.15 -4.98 -0.311 0.84960E+04 147 quartz -2.99 -3.16 -0.17 -0.056 0.28686E+03 152 rhodonite 7.45 6.08 -1.36 -0.273 0.23300E+04 153 sanidine -1.28 -2.49 -1.21 -0.093 0.20677E+04 165 stilpnomelane-Mg 27.44 25.81 -1.63 -0.049 0.27801E+04 171 talc 16.49 15.25 -1.24 -0.073 0.21141E+04 174 tephroite 18.09 15.32 -2.77 -0.395 0.47233E+04 178 tridymite -2.63 -3.16 -0.53 -0.177 0.90684E+03 179 tremolite 47.87 47.42 -0.45 -0.012 0.77497E+03 180 ferroactinolite 38.45 34.62 -3.83 -0.104 0.65451E+04 181 troilite-low -4.41 -8.02 -3.61 -1.203 0.61617E+04 183 vesuvianite 223.47 218.82 -4.65 -0.036 0.79415E+04 187 wairakite 3.95 1.95 -2.00 -0.118 0.34153E+04 188 walstromite 11.51 9.94 -1.56 -0.313 0.26719E+04 189 wollastonite 10.46 9.94 -0.52 -0.103 0.88229E+03 190 pseudo-wollastonite 11.00 9.94 -1.06 -0.211 0.18021E+04 191 zoisite 22.85 18.95 -3.90 -0.177 0.66604E+04 192 akaganeite 7.75 4.49 -3.26 -0.705 0.55681E+04 199 chalcedony -2.80 -3.16 -0.36 -0.118 0.60616E+03 201 montmorillonite-Ca -2.29 -6.17 -3.88 -0.240 0.66179E+04 202 montmorillonite-K -2.24 -6.27 -4.03 -0.247 0.68815E+04 203 montmorillonite-Mg -2.48 -6.79 -4.31 -0.267 0.73677E+04 204 montmorillonite-Na -2.04 -5.57 -3.54 -0.216 0.60364E+04 205 nontronite-Ca 3.21 -0.20 -3.41 -0.221 0.58217E+04 206 nontronite-H 2.53 -2.36 -4.89 -0.328 0.83487E+04 207 nontronite-K 3.34 -0.30 -3.64 -0.233 0.62086E+04 208 nontronite-Mg 3.07 -0.82 -3.90 -0.253 0.66556E+04 209 nontronite-Na 3.52 0.40 -3.12 -0.200 0.53294E+04 224 tobermorite 9.82 7.76 -2.07 -0.564 0.35287E+04 230 alabandite -0.98 -5.52 -4.54 -1.513 0.77489E+04 233 boehmite 4.41 0.74 -3.67 -0.611 0.62617E+04 235 ferrous-oxide 9.81 6.73 -3.08 -0.769 0.52532E+04 240 silica-amorphous -2.09 -3.16 -1.07 -0.355 0.18203E+04 242 an20ab80 2.02 1.35 -0.67 -0.052 0.11472E+04 243 an25ab75 2.65 1.78 -0.87 -0.067 0.14809E+04 244 an30ab70 3.28 2.21 -1.07 -0.082 0.18243E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 40.0000000 g Current total amount of reactant added: 999.9990000 g New total amount of reactant added: 1039.9990000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.3298E-10 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 11 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 1039.9990000 Water: Moles liquid = 0.4963E+02 kg liquid = 0.8940E+00 Moles total = 0.4247E+02 kg total = 0.7651E+00 Activity = 1.0000 Stoichiometric ionic strength = .1133099E-01 Osmotic coef. = 0.9693 True ionic strength = .2001835E-01 Chg. balance for total moles = 0.3298E-10 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.88293E-10 -10.0541 0.74188E-10 -10.1297 0.84025E+00 -0.0756 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.15362E-03 -3.8135 0.12831E-03 -3.8918 0.83520E+00 -0.0782 4 SO4-- 0.72387E-12 -12.1403 0.37591E-12 -12.4249 0.51931E+00 -0.2846 5 HCO3- 0.26788E-06 -6.5721 0.22406E-06 -6.6496 0.83642E+00 -0.0776 6 HS- 0.28522E-04 -4.5448 0.23825E-04 -4.6230 0.83532E+00 -0.0781 7 Al+++ 0.96919E-29 -29.0136 0.22391E-29 -29.6499 0.23103E+00 -0.6363 8 H4SiO4 0.69592E-03 -3.1574 0.69592E-03 -3.1574 0.10000E+01 0.0000 9 Ca++ 0.13499E-06 -6.8697 0.69588E-07 -7.1575 0.51550E+00 -0.2878 10 Mg++ 0.21119E-10 -10.6753 0.10837E-10 -10.9651 0.51314E+00 -0.2898 11 Fe++ 0.58204E-13 -13.2350 0.29899E-13 -13.5243 0.51370E+00 -0.2893 12 K+ 0.15651E-03 -3.8054 0.13094E-03 -3.8829 0.83662E+00 -0.0775 13 Na+ 0.19861E-01 -1.7020 0.16585E-01 -1.7803 0.83505E+00 -0.0783 14 Mn++ 0.18546E-10 -10.7317 0.95350E-11 -11.0207 0.51413E+00 -0.2889 15 HPO4-- 0.45315E-07 -7.3438 0.23536E-07 -7.6283 0.51938E+00 -0.2845 16 HSiO3- 0.10487E-01 -1.9793 0.87590E-02 -2.0575 0.83520E+00 -0.0782 17 Ca(HSiO3)+ 0.16588E-07 -7.7802 0.13881E-07 -7.8576 0.83680E+00 -0.0774 18 Mg(HSiO3)+ 0.32149E-11 -11.4928 0.26902E-11 -11.5702 0.83680E+00 -0.0774 19 NaHSiO3,aq 0.23495E-02 -2.6290 0.23495E-02 -2.6290 0.10000E+01 0.0000 20 AlO+ 0.66140E-16 -16.1795 0.55346E-16 -16.2569 0.83680E+00 -0.0774 22 HAlO2,aq 0.14857E-09 -9.8281 0.14857E-09 -9.8281 0.10000E+01 0.0000 23 AlO2- 0.53172E-05 -5.2743 0.44329E-05 -5.3533 0.83369E+00 -0.0790 24 CH4,aq 0.13842E-04 -4.8588 0.13794E-04 -4.8603 0.99654E+00 -0.0015 25 C2H6,aq 0.28177E-14 -14.5501 0.28080E-14 -14.5516 0.99654E+00 -0.0015 29 CO,aq 0.10336E-16 -16.9856 0.10336E-16 -16.9856 0.10000E+01 0.0000 30 CO2,aq 0.35641E-10 -10.4480 0.35518E-10 -10.4495 0.99654E+00 -0.0015 31 CO3-2 0.50906E-06 -6.2932 0.26380E-06 -6.5787 0.51820E+00 -0.2855 32 CaCO3,aq 0.23018E-09 -9.6379 0.23018E-09 -9.6379 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.47562E-12 -12.3227 0.39800E-12 -12.4001 0.83680E+00 -0.0774 34 CaCl+ 0.17267E-10 -10.7628 0.14449E-10 -10.8402 0.83680E+00 -0.0774 35 CaCl2,aq 0.44046E-15 -15.3561 0.44046E-15 -15.3561 0.10000E+01 0.0000 36 CaOH+ 0.79888E-07 -7.0975 0.66850E-07 -7.1749 0.83680E+00 -0.0774 37 CaSO4,aq 0.83067E-17 -17.0806 0.83067E-17 -17.0806 0.10000E+01 0.0000 38 HCl,aq 0.17443E-14 -14.7584 0.17443E-14 -14.7584 0.10000E+01 0.0000 43 FeCl+ 0.72565E-17 -17.1393 0.60722E-17 -17.2167 0.83680E+00 -0.0774 46 FeO,aq 0.21113E-09 -9.6754 0.21113E-09 -9.6754 0.10000E+01 0.0000 47 FeOH+ 0.15677E-10 -10.8047 0.13119E-10 -10.8821 0.83680E+00 -0.0774 48 HFeO2- 0.35653E-07 -7.4479 0.29777E-07 -7.5261 0.83520E+00 -0.0782 49 FeO+ 0.10986E-16 -16.9591 0.91933E-17 -17.0365 0.83680E+00 -0.0774 51 FeO2- 0.40922E-09 -9.3880 0.34178E-09 -9.4662 0.83520E+00 -0.0782 52 HFeO2,aq 0.32249E-11 -11.4915 0.32249E-11 -11.4915 0.10000E+01 0.0000 53 H2,aq 0.11625E-04 -4.9346 0.11585E-04 -4.9361 0.99654E+00 -0.0015 54 KCl,aq 0.30450E-09 -9.5164 0.30450E-09 -9.5164 0.10000E+01 0.0000 56 KOH,aq 0.75375E-06 -6.1228 0.75375E-06 -6.1228 0.10000E+01 0.0000 57 KSO4- 0.91454E-15 -15.0388 0.76382E-15 -15.1170 0.83520E+00 -0.0782 58 MgCO3,aq 0.89848E-14 -14.0465 0.89848E-14 -14.0465 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.75683E-16 -16.1210 0.63331E-16 -16.1984 0.83680E+00 -0.0774 60 MgCl+ 0.24372E-14 -14.6131 0.20394E-14 -14.6905 0.83680E+00 -0.0774 61 MgOH+ 0.68842E-10 -10.1621 0.57607E-10 -10.2395 0.83680E+00 -0.0774 63 MnO,aq 0.17941E-08 -8.7462 0.17941E-08 -8.7462 0.10000E+01 0.0000 64 MnOH+ 0.46444E-09 -9.3331 0.38864E-09 -9.4105 0.83680E+00 -0.0774 65 MnO2-2 0.20876E-10 -10.6804 0.10818E-10 -10.9659 0.51820E+00 -0.2855 66 HMnO2- 0.21052E-09 -9.6767 0.17583E-09 -9.7549 0.83520E+00 -0.0782 69 MnCl+ 0.90029E-14 -14.0456 0.75336E-14 -14.1230 0.83680E+00 -0.0774 71 NaCl,aq 0.70520E-06 -6.1517 0.70520E-06 -6.1517 0.10000E+01 0.0000 72 NaOH,aq 0.96047E-04 -4.0175 0.96047E-04 -4.0175 0.10000E+01 0.0000 74 OH- 0.93415E-02 -2.0296 0.77879E-02 -2.1086 0.83369E+00 -0.0790 79 HPO3-2 0.16397E-14 -14.7852 0.84968E-15 -15.0707 0.51820E+00 -0.2855 81 H2PO3- 0.15135E-18 -18.8200 0.12641E-18 -18.8982 0.83520E+00 -0.0782 82 H3PO4,aq 0.90598E-18 -18.0429 0.90598E-18 -18.0429 0.10000E+01 0.0000 83 H2PO4- 0.38529E-10 -10.4142 0.32210E-10 -10.4920 0.83599E+00 -0.0778 84 PO4-3 0.10667E-08 -8.9720 0.25883E-09 -9.5870 0.24265E+00 -0.6150 88 HP2O7-3 0.94677E-18 -18.0238 0.21895E-18 -18.6597 0.23126E+00 -0.6359 89 P2O7-4 0.91438E-17 -17.0389 0.70505E-18 -18.1518 0.77108E-01 -1.1129 90 H2S,aq 0.54818E-08 -8.2611 0.54628E-08 -8.2626 0.99654E+00 -0.0015 91 S2-2 0.20952E-14 -14.6788 0.10857E-14 -14.9643 0.51820E+00 -0.2855 97 SO3-2 0.10765E-17 -17.9680 0.56591E-18 -18.2473 0.52570E+00 -0.2793 99 HSO4- 0.32087E-19 -19.4937 0.26876E-19 -19.5706 0.83761E+00 -0.0770 Charge balance for all species = 0.3690E-10 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.8829307E-10 -.2229992E-01 -.2243792E+02 0.0000 2 H2O 0.1000000E+01 0.5550489E+02 0.9981995E+06 0.0000 3 Cl- 0.1536240E-03 0.1543295E-03 0.5461935E+01 6.2379 4 SO4-- 0.7238747E-12 -.1674828E-04 -.1606071E+01 7.8344 5 HCO3- 0.2678771E-06 0.1461930E-04 0.8904788E+00 3.4800 6 HS- 0.2852226E-04 0.4527602E-04 0.1494767E+01 5.5067 7 Al+++ 0.9691935E-29 0.5317353E-05 0.1432208E+00 0.7391 8 H4SiO4 0.6959232E-03 0.1353266E-01 0.1298437E+04 -3.1574 9 Ca++ 0.1349930E-06 0.2317176E-06 0.9270638E-02 13.1019 10 Mg++ 0.2111886E-10 0.9318700E-10 0.2261625E-05 9.2942 11 Fe++ 0.5820395E-13 0.3629186E-07 0.2023270E-02 6.7350 12 K+ 0.1565136E-03 0.1572676E-03 0.6138792E+01 6.2467 13 Na+ 0.1986078E-01 0.2230698E-01 0.5119419E+03 8.3494 14 Mn++ 0.1854605E-10 0.2508470E-08 0.1375708E-03 9.2386 15 HPO4-- 0.4531464E-07 0.4641986E-07 0.4447590E-02 12.6311 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.1722083E+02 -.1993665E-01 -.1720089E+02 0.0000000E+00 2 H2O 0.4247144E+02 0.4962267E+02 -.7151233E+01 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.2884742E-01 -.1497335E-04 0.2886240E-01 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.2882192E-01 0.4047782E-04 -.2886240E-01 0.0000000E+00 7 Al+++ 0.3391168E+01 0.4753838E-05 0.3391163E+01 0.0000000E+00 8 H4SiO4 0.1082928E+02 0.1209852E-01 0.1081719E+02 0.0000000E+00 9 Ca++ 0.1196162E+01 0.2071609E-06 0.1196161E+01 0.0000000E+00 10 Mg++ 0.8253960E+00 0.8331136E-10 0.8253960E+00 0.0000000E+00 11 Fe++ 0.7415282E+00 0.3244578E-07 0.7415282E+00 0.0000000E+00 12 K+ 0.2208066E+00 0.1406009E-03 0.2206660E+00 0.0000000E+00 13 Na+ 0.1305612E+01 0.1994297E-01 0.1285669E+01 0.0000000E+00 14 Mn++ 0.1803212E-01 0.2242631E-08 0.1803212E-01 0.0000000E+00 15 HPO4-- 0.6154274E-02 0.4150044E-07 0.6154232E-02 0.0000000E+00 Chg. balance for solid moles: -.2082E-16 Mass of aqueous solution: 0.895580E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 1039.9990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 1.284 0.109 336.8 2.527 29.65 129.3 andradite 0.1154 -0.938 58.67 1.768 5.164 15.24 grossular 0.2796E-01 -1.553 12.60 1.100 1.109 3.505 apatite-OH 0.2051E-02 -2.688 1.030 0.013 0.9071E-01 0.3274 clinochlore 0.1488 -0.828 82.68 1.917 7.278 31.45 daphnite 0.4306E-01 -1.366 30.72 1.487 2.705 9.310 chlorite-Mn 0.3606E-02 -2.443 2.557 0.408 0.2251 0.8148 diopside 0.4731E-01 -1.325 10.24 1.010 0.9018 3.131 hedenbergite 0.1227E-01 -1.911 3.044 0.483 0.2679 0.8336 microcline 0.1935 -0.713 53.87 1.731 4.742 21.04 stilbite 0.6772 -0.169 477.2 2.679 42.01 222.6 stilpnomelane-Fe 0.5424E-01 -1.266 58.48 1.767 5.147 20.20 tr.625ac.25prg.125 0.9465E-02 -2.024 8.091 0.908 0.7122 2.604 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8050E+00 0.8050E+00 1.0000 -0.094 grossular 0.1950E+00 0.1950E+00 1.0000 -0.710 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.7612E+00 0.7612E+00 1.0000 -0.119 daphnite 0.2203E+00 0.2203E+00 1.0000 -0.657 chlorite-Mn 0.1845E-01 0.1845E-01 1.0000 -1.734 diopside 0.7941E+00 0.7941E+00 1.0000 -0.100 hedenbergite 0.2059E+00 0.2059E+00 1.0000 -0.686 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 tr.625ac.25prg.125 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 1136.011566 g Volume = 460.336517 cm3 Porosity: -10.3926% V(tot) - V(min): -.43337E+02 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 1039.9990000 g log = 3.0170 Original solution: 1000.0103000 g Original solution / Rock added: 0.96 (Water/Rock Ratio), log = -0.0170 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0561 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9666E+00 0.9855 0.1006E+01 0.1021E+01 CO2,gas 0.3574E-08 1.0069 0.3800E-08 0.3774E-08 CH4,gas 0.1899E-01 1.0124 0.2030E-01 0.2005E-01 H2,gas 0.1439E-01 1.0006 0.1521E-01 0.1520E-01 H2S,gas 0.1428E-06 0.9959 0.1502E-06 0.1508E-06 S2,gas 0.3465E-29 1.0000 0.3659E-29 0.3659E-29 CO,gas 0.1459E-13 1.0000 0.1540E-13 0.1540E-13 SO3,gas 0.7408E-48 1.0000 0.7823E-48 0.7823E-48 SO2,gas 0.4383E-27 1.0000 0.4629E-27 0.4629E-27 HCl,gas 0.2914E-17 1.0000 0.3078E-17 0.3078E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 16 albite -0.38 -0.38 0.00 0.000 -0.94784E-12 22 andradite 39.01 39.01 0.00 0.000 0.00000E+00 23 grossular 32.73 32.73 0.00 0.000 -0.24265E-10 32 apatite-OH -18.15 -18.15 0.00 0.000 -0.60662E-11 46 clinochlore 39.07 39.07 0.00 0.000 0.36397E-10 47 daphnite 28.97 28.97 0.00 0.000 0.12132E-10 48 chlorite-Mn 46.87 46.87 0.00 0.000 0.24265E-10 67 diopside 16.18 16.18 0.00 0.000 -0.60662E-11 68 hedenbergite 14.21 14.21 0.00 0.000 -0.60662E-11 116 microcline -2.49 -2.49 0.00 0.000 0.15165E-11 163 stilbite -7.52 -7.52 0.00 0.000 -0.33364E-10 164 stilpnomelane-Fe 13.02 13.02 0.00 0.000 0.21232E-10 245 tr.625ac.25prg.125 45.16 45.16 0.00 0.000 -0.12132E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -16.78 -10.12 -3.373 0.17278E+05 -8.420 3 CH4,gas 4.54 1.15 -3.39 -0.848 0.57907E+04 -1.692 4 H2,gas 8.00 4.48 -3.52 -2.010 0.60049E+04 -1.818 5 H2S,gas -6.23 -14.75 -8.52 -4.261 0.14552E+05 -6.823 6 S2,gas -7.34 -38.47 -31.14 -4.790 0.53163E+05 -29.437 7 CO,gas 3.21 -12.30 -15.51 -4.773 0.26485E+05 -13.812 8 SO3,gas 17.12 -32.68 -49.81 -12.451 0.85042E+05 -48.107 9 SO2,gas 0.83 -28.20 -29.03 -7.742 0.49574E+05 -27.335 10 HCl,gas 5.19 -14.02 -19.21 -9.605 0.32802E+05 -17.512 11 acmite 7.71 6.53 -1.18 -0.123 0.20177E+04 15 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 19 spessartine 24.46 19.72 -4.74 -0.237 0.80858E+04 20 analcite 3.32 2.77 -0.55 -0.061 0.93619E+03 26 annite 20.12 17.72 -2.40 -0.134 0.41063E+04 27 phlogopite 27.06 25.40 -1.67 -0.093 0.28487E+04 29 anorthite 12.71 8.27 -4.45 -0.342 0.75900E+04 35 aragonite 0.97 -3.68 -4.64 -1.548 0.79294E+04 36 brucite 12.57 9.29 -3.27 -0.655 0.55908E+04 37 calcite 0.81 -3.68 -4.49 -1.496 0.76652E+04 38 carnegieite-low 9.02 5.93 -3.09 -0.442 0.52800E+04 39 carnegieite-high 10.09 5.93 -4.16 -0.595 0.71070E+04 40 carpholite-Mg 8.58 4.46 -4.12 -0.275 0.70426E+04 41 carpholite-Fe 6.71 1.90 -4.81 -0.321 0.82204E+04 42 celadonite 5.34 3.65 -1.69 -0.099 0.28879E+04 43 celadonite-Fe 3.88 1.09 -2.79 -0.164 0.47561E+04 44 chrysotile 23.89 21.57 -2.32 -0.194 0.39691E+04 49 chlorite-Al-free 47.17 43.14 -4.04 -0.168 0.68934E+04 51 chloritoid-Fe 9.17 5.06 -4.12 -0.275 0.70312E+04 52 chloritoid-Mn 11.40 7.56 -3.84 -0.256 0.65596E+04 54 coesite -2.38 -3.16 -0.78 -0.260 0.13342E+04 61 cristobalite -2.56 -3.16 -0.60 -0.199 0.10195E+04 63 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71234E+04 65 diaspore 2.87 0.74 -2.13 -0.356 0.36448E+04 66 diamond -3.10 -7.81 -4.71 -1.346 0.80441E+04 71 enstatite 17.26 12.27 -4.99 -0.499 0.85225E+04 73 clinoenstatite 17.17 12.27 -4.89 -0.489 0.83541E+04 75 epidote 24.67 22.70 -1.97 -0.095 0.33583E+04 76 clinozoisite 22.81 18.95 -3.86 -0.175 0.65864E+04 77 epidote-Fe 29.84 26.46 -3.38 -0.176 0.57768E+04 78 fayalite 14.05 10.31 -3.73 -0.533 0.63743E+04 79 ferrosilite 11.15 7.16 -3.99 -0.399 0.68202E+04 83 gibbsite 4.08 0.74 -3.34 -0.477 0.57034E+04 84 glaucophane 22.97 20.80 -2.17 -0.059 0.37133E+04 85 glaucophane-Fe 17.28 13.12 -4.15 -0.112 0.70919E+04 86 graphite -3.55 -7.81 -4.27 -1.219 0.72863E+04 87 greenalite 16.14 13.89 -2.25 -0.187 0.38408E+04 90 hematite 12.57 8.99 -3.58 -0.434 0.61112E+04 91 heulandite -5.83 -7.52 -1.69 -0.077 0.28938E+04 95 jadeite 4.22 2.77 -1.44 -0.144 0.24617E+04 97 kalsilite 7.58 3.83 -3.76 -0.537 0.64125E+04 98 kaolinite -1.33 -4.84 -3.50 -0.319 0.59829E+04 101 laumontite 2.88 1.95 -0.93 -0.062 0.15933E+04 102 lawsonite 9.62 8.27 -1.35 -0.090 0.23067E+04 103 leucite 4.12 0.67 -3.45 -0.345 0.58872E+04 105 lizardite 23.24 21.57 -1.68 -0.140 0.28618E+04 107 magnetite 20.09 15.72 -4.37 -0.356 0.74537E+04 108 minnesotaite 10.39 7.58 -2.81 -0.165 0.48029E+04 112 manganosite 14.06 9.24 -4.82 -1.205 0.82291E+04 120 muscovite 2.58 -1.01 -3.59 -0.211 0.61311E+04 121 paragonite 4.24 1.09 -3.15 -0.185 0.53702E+04 122 nepheline 8.34 5.93 -2.41 -0.344 0.41124E+04 128 periclase-Fe 11.63 6.73 -4.89 -1.223 0.83523E+04 134 phlogopite-Na 29.65 27.50 -2.15 -0.119 0.36675E+04 136 prehnite 19.37 18.21 -1.16 -0.068 0.19846E+04 137 prehnite-Fe 22.50 21.96 -0.53 -0.032 0.91151E+03 138 pumpellyite-Fe 46.27 43.89 -2.38 -0.053 0.40573E+04 139 pumpellyite-Mg 48.99 46.45 -2.54 -0.056 0.43411E+04 143 pyrrhotite -4.26 -8.02 -3.76 -1.252 0.64155E+04 144 pyrrhotiteFe0.875 -6.02 -9.42 -3.40 -1.250 0.58027E+04 145 pyroxmangite 7.40 6.08 -1.32 -0.263 0.22495E+04 146 pyrophyllite -6.18 -11.15 -4.98 -0.311 0.84960E+04 147 quartz -2.99 -3.16 -0.17 -0.056 0.28686E+03 152 rhodonite 7.45 6.08 -1.36 -0.273 0.23298E+04 153 sanidine -1.28 -2.49 -1.21 -0.093 0.20677E+04 165 stilpnomelane-Mg 27.44 25.81 -1.63 -0.049 0.27801E+04 171 talc 16.49 15.25 -1.24 -0.073 0.21141E+04 174 tephroite 18.09 15.32 -2.77 -0.395 0.47228E+04 178 tridymite -2.63 -3.16 -0.53 -0.177 0.90684E+03 179 tremolite 47.87 47.42 -0.45 -0.012 0.77496E+03 180 ferroactinolite 38.45 34.62 -3.83 -0.104 0.65451E+04 181 troilite-low -4.41 -8.02 -3.61 -1.202 0.61583E+04 183 vesuvianite 223.47 218.82 -4.65 -0.036 0.79417E+04 187 wairakite 3.95 1.95 -2.00 -0.118 0.34153E+04 188 walstromite 11.51 9.94 -1.56 -0.313 0.26719E+04 189 wollastonite 10.46 9.94 -0.52 -0.103 0.88229E+03 190 pseudo-wollastonite 11.00 9.94 -1.06 -0.211 0.18021E+04 191 zoisite 22.85 18.95 -3.90 -0.177 0.66604E+04 192 akaganeite 7.75 4.49 -3.26 -0.705 0.55681E+04 199 chalcedony -2.80 -3.16 -0.36 -0.118 0.60616E+03 201 montmorillonite-Ca -2.29 -6.17 -3.88 -0.240 0.66179E+04 202 montmorillonite-K -2.24 -6.27 -4.03 -0.247 0.68816E+04 203 montmorillonite-Mg -2.48 -6.79 -4.31 -0.267 0.73677E+04 204 montmorillonite-Na -2.04 -5.57 -3.54 -0.216 0.60364E+04 205 nontronite-Ca 3.21 -0.20 -3.41 -0.221 0.58217E+04 206 nontronite-H 2.53 -2.36 -4.89 -0.328 0.83487E+04 207 nontronite-K 3.34 -0.30 -3.64 -0.233 0.62085E+04 208 nontronite-Mg 3.07 -0.82 -3.90 -0.253 0.66556E+04 209 nontronite-Na 3.52 0.40 -3.12 -0.200 0.53294E+04 224 tobermorite 9.82 7.76 -2.07 -0.564 0.35287E+04 230 alabandite -0.98 -5.51 -4.54 -1.512 0.77453E+04 233 boehmite 4.41 0.74 -3.67 -0.611 0.62617E+04 235 ferrous-oxide 9.81 6.73 -3.08 -0.769 0.52532E+04 240 silica-amorphous -2.09 -3.16 -1.07 -0.355 0.18203E+04 242 an20ab80 2.02 1.35 -0.67 -0.052 0.11472E+04 243 an25ab75 2.65 1.78 -0.87 -0.067 0.14809E+04 244 an30ab70 3.28 2.21 -1.07 -0.082 0.18243E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 40.0000000 g Current total amount of reactant added: 1039.9990000 g New total amount of reactant added: 1079.9990000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.3298E-10 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 11 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 1079.9990000 Water: Moles liquid = 0.4940E+02 kg liquid = 0.8900E+00 Moles total = 0.4197E+02 kg total = 0.7561E+00 Activity = 1.0000 Stoichiometric ionic strength = .1133158E-01 Osmotic coef. = 0.9693 True ionic strength = .2001882E-01 Chg. balance for total moles = 0.3298E-10 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.88295E-10 -10.0541 0.74190E-10 -10.1297 0.84025E+00 -0.0756 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.15432E-03 -3.8116 0.12889E-03 -3.8898 0.83520E+00 -0.0782 4 SO4-- 0.72716E-12 -12.1384 0.37761E-12 -12.4230 0.51930E+00 -0.2846 5 HCO3- 0.26909E-06 -6.5701 0.22507E-06 -6.6477 0.83642E+00 -0.0776 6 HS- 0.28651E-04 -4.5429 0.23933E-04 -4.6210 0.83532E+00 -0.0781 7 Al+++ 0.96926E-29 -29.0136 0.22393E-29 -29.6499 0.23103E+00 -0.6363 8 H4SiO4 0.69593E-03 -3.1574 0.69593E-03 -3.1574 0.10000E+01 0.0000 9 Ca++ 0.13500E-06 -6.8697 0.69591E-07 -7.1574 0.51549E+00 -0.2878 10 Mg++ 0.21120E-10 -10.6753 0.10837E-10 -10.9651 0.51313E+00 -0.2898 11 Fe++ 0.58207E-13 -13.2350 0.29901E-13 -13.5243 0.51370E+00 -0.2893 12 K+ 0.15652E-03 -3.8054 0.13095E-03 -3.8829 0.83662E+00 -0.0775 13 Na+ 0.19861E-01 -1.7020 0.16585E-01 -1.7803 0.83505E+00 -0.0783 14 Mn++ 0.18553E-10 -10.7316 0.95384E-11 -11.0205 0.51412E+00 -0.2889 15 HPO4-- 0.45313E-07 -7.3438 0.23535E-07 -7.6283 0.51938E+00 -0.2845 16 HSiO3- 0.10487E-01 -1.9793 0.87588E-02 -2.0576 0.83520E+00 -0.0782 17 Ca(HSiO3)+ 0.16589E-07 -7.7802 0.13881E-07 -7.8576 0.83680E+00 -0.0774 18 Mg(HSiO3)+ 0.32150E-11 -11.4928 0.26903E-11 -11.5702 0.83680E+00 -0.0774 19 NaHSiO3,aq 0.23495E-02 -2.6290 0.23495E-02 -2.6290 0.10000E+01 0.0000 20 AlO+ 0.66141E-16 -16.1795 0.55347E-16 -16.2569 0.83680E+00 -0.0774 22 HAlO2,aq 0.14857E-09 -9.8281 0.14857E-09 -9.8281 0.10000E+01 0.0000 23 AlO2- 0.53170E-05 -5.2743 0.44328E-05 -5.3533 0.83369E+00 -0.0790 24 CH4,aq 0.13905E-04 -4.8568 0.13857E-04 -4.8583 0.99654E+00 -0.0015 25 C2H6,aq 0.28432E-14 -14.5462 0.28334E-14 -14.5477 0.99654E+00 -0.0015 29 CO,aq 0.10383E-16 -16.9837 0.10383E-16 -16.9837 0.10000E+01 0.0000 30 CO2,aq 0.35804E-10 -10.4461 0.35680E-10 -10.4476 0.99654E+00 -0.0015 31 CO3-2 0.51135E-06 -6.2913 0.26498E-06 -6.5768 0.51820E+00 -0.2855 32 CaCO3,aq 0.23122E-09 -9.6360 0.23122E-09 -9.6360 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.47779E-12 -12.3208 0.39981E-12 -12.3981 0.83680E+00 -0.0774 34 CaCl+ 0.17346E-10 -10.7608 0.14515E-10 -10.8382 0.83680E+00 -0.0774 35 CaCl2,aq 0.44446E-15 -15.3522 0.44446E-15 -15.3522 0.10000E+01 0.0000 36 CaOH+ 0.79890E-07 -7.0975 0.66852E-07 -7.1749 0.83680E+00 -0.0774 37 CaSO4,aq 0.83447E-17 -17.0786 0.83447E-17 -17.0786 0.10000E+01 0.0000 38 HCl,aq 0.17522E-14 -14.7564 0.17522E-14 -14.7564 0.10000E+01 0.0000 43 FeCl+ 0.72895E-17 -17.1373 0.60998E-17 -17.2147 0.83680E+00 -0.0774 46 FeO,aq 0.21113E-09 -9.6754 0.21113E-09 -9.6754 0.10000E+01 0.0000 47 FeOH+ 0.15678E-10 -10.8047 0.13119E-10 -10.8821 0.83680E+00 -0.0774 48 HFeO2- 0.35652E-07 -7.4479 0.29776E-07 -7.5261 0.83520E+00 -0.0782 49 FeO+ 0.10987E-16 -16.9591 0.91936E-17 -17.0365 0.83680E+00 -0.0774 51 FeO2- 0.40922E-09 -9.3880 0.34178E-09 -9.4663 0.83520E+00 -0.0782 52 HFeO2,aq 0.32249E-11 -11.4915 0.32249E-11 -11.4915 0.10000E+01 0.0000 53 H2,aq 0.11625E-04 -4.9346 0.11585E-04 -4.9361 0.99654E+00 -0.0015 54 KCl,aq 0.30588E-09 -9.5144 0.30588E-09 -9.5144 0.10000E+01 0.0000 56 KOH,aq 0.75375E-06 -6.1228 0.75375E-06 -6.1228 0.10000E+01 0.0000 57 KSO4- 0.91870E-15 -15.0368 0.76729E-15 -15.1150 0.83520E+00 -0.0782 58 MgCO3,aq 0.90257E-14 -14.0445 0.90257E-14 -14.0445 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.76029E-16 -16.1190 0.63621E-16 -16.1964 0.83680E+00 -0.0774 60 MgCl+ 0.24483E-14 -14.6111 0.20487E-14 -14.6885 0.83680E+00 -0.0774 61 MgOH+ 0.68843E-10 -10.1621 0.57608E-10 -10.2395 0.83680E+00 -0.0774 63 MnO,aq 0.17946E-08 -8.7460 0.17946E-08 -8.7460 0.10000E+01 0.0000 64 MnOH+ 0.46460E-09 -9.3329 0.38877E-09 -9.4103 0.83680E+00 -0.0774 65 MnO2-2 0.20881E-10 -10.6802 0.10821E-10 -10.9657 0.51820E+00 -0.2855 66 HMnO2- 0.21058E-09 -9.6766 0.17588E-09 -9.7548 0.83520E+00 -0.0782 69 MnCl+ 0.90468E-14 -14.0435 0.75703E-14 -14.1209 0.83680E+00 -0.0774 71 NaCl,aq 0.70840E-06 -6.1497 0.70840E-06 -6.1497 0.10000E+01 0.0000 72 NaOH,aq 0.96047E-04 -4.0175 0.96047E-04 -4.0175 0.10000E+01 0.0000 74 OH- 0.93413E-02 -2.0296 0.77878E-02 -2.1086 0.83369E+00 -0.0790 79 HPO3-2 0.16396E-14 -14.7853 0.84964E-15 -15.0708 0.51820E+00 -0.2855 81 H2PO3- 0.15135E-18 -18.8200 0.12640E-18 -18.8982 0.83520E+00 -0.0782 82 H3PO4,aq 0.90599E-18 -18.0429 0.90599E-18 -18.0429 0.10000E+01 0.0000 83 H2PO4- 0.38529E-10 -10.4142 0.32210E-10 -10.4920 0.83599E+00 -0.0778 84 PO4-3 0.10666E-08 -8.9720 0.25882E-09 -9.5870 0.24265E+00 -0.6150 88 HP2O7-3 0.94673E-18 -18.0238 0.21894E-18 -18.6597 0.23126E+00 -0.6359 89 P2O7-4 0.91433E-17 -17.0389 0.70500E-18 -18.1518 0.77106E-01 -1.1129 90 H2S,aq 0.55066E-08 -8.2591 0.54876E-08 -8.2606 0.99654E+00 -0.0015 91 S2-2 0.21141E-14 -14.6749 0.10956E-14 -14.9604 0.51820E+00 -0.2855 97 SO3-2 0.10814E-17 -17.9660 0.56847E-18 -18.2453 0.52570E+00 -0.2793 99 HSO4- 0.32233E-19 -19.4917 0.26999E-19 -19.5687 0.83761E+00 -0.0770 Charge balance for all species = 0.3706E-10 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.8829512E-10 -.2229957E-01 -.2243757E+02 0.0000 2 H2O 0.1000000E+01 0.5550489E+02 0.9981995E+06 0.0000 3 Cl- 0.1543173E-03 0.1550261E-03 0.5486588E+01 6.2399 4 SO4-- 0.7271550E-12 -.1681073E-04 -.1612059E+01 7.8364 5 HCO3- 0.2690901E-06 0.1468529E-04 0.8944980E+00 3.4820 6 HS- 0.2865100E-04 0.4546723E-04 0.1501079E+01 5.5086 7 Al+++ 0.9692596E-29 0.5317186E-05 0.1432163E+00 0.7391 8 H4SiO4 0.6959258E-03 0.1353250E-01 0.1298422E+04 -3.1574 9 Ca++ 0.1349993E-06 0.2317269E-06 0.9271009E-02 13.1019 10 Mg++ 0.2111982E-10 0.9318934E-10 0.2261682E-05 9.2942 11 Fe++ 0.5820677E-13 0.3629108E-07 0.2023226E-02 6.7350 12 K+ 0.1565172E-03 0.1572713E-03 0.6138934E+01 6.2467 13 Na+ 0.1986124E-01 0.2230746E-01 0.5119528E+03 8.3494 14 Mn++ 0.1855279E-10 0.2509263E-08 0.1376143E-03 9.2388 15 HPO4-- 0.4531323E-07 0.4641841E-07 0.4447450E-02 12.6310 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.1788317E+02 -.1984676E-01 -.1786332E+02 0.0000000E+00 2 H2O 0.4197002E+02 0.4939970E+02 -.7429683E+01 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.2995596E-01 -.1496166E-04 0.2997092E-01 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.2993045E-01 0.4046613E-04 -.2997092E-01 0.0000000E+00 7 Al+++ 0.3521598E+01 0.4732329E-05 0.3521593E+01 0.0000000E+00 8 H4SiO4 0.1124580E+02 0.1204401E-01 0.1123375E+02 0.0000000E+00 9 Ca++ 0.1242167E+01 0.2062384E-06 0.1242167E+01 0.0000000E+00 10 Mg++ 0.8571421E+00 0.8293910E-10 0.8571421E+00 0.0000000E+00 11 Fe++ 0.7700486E+00 0.3229929E-07 0.7700485E+00 0.0000000E+00 12 K+ 0.2292992E+00 0.1399724E-03 0.2291592E+00 0.0000000E+00 13 Na+ 0.1355822E+01 0.1985378E-01 0.1335968E+01 0.0000000E+00 14 Mn++ 0.1872567E-01 0.2233260E-08 0.1872566E-01 0.0000000E+00 15 HPO4-- 0.6390977E-02 0.4131268E-07 0.6390936E-02 0.0000000E+00 Chg. balance for solid moles: -.8674E-15 Mass of aqueous solution: 0.891556E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 1079.9990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 1.335 0.125 350.0 2.544 29.67 134.4 andradite 0.1199 -0.921 60.92 1.785 5.164 15.83 grossular 0.2904E-01 -1.537 13.08 1.117 1.109 3.639 apatite-OH 0.2130E-02 -2.672 1.070 0.029 0.9071E-01 0.3400 clinochlore 0.1544 -0.811 85.84 1.934 7.276 32.65 daphnite 0.4470E-01 -1.350 31.90 1.504 2.704 9.666 chlorite-Mn 0.3745E-02 -2.427 2.655 0.424 0.2251 0.8461 diopside 0.4948E-01 -1.306 10.72 1.030 0.9083 3.275 hedenbergite 0.1283E-01 -1.892 3.184 0.503 0.2699 0.8720 microcline 0.2010 -0.697 55.94 1.748 4.742 21.85 stilbite 0.7028 -0.153 495.3 2.695 41.99 231.0 stilpnomelane-Fe 0.5634E-01 -1.249 60.73 1.783 5.148 20.98 tr.625ac.25prg.125 0.9799E-02 -2.009 8.376 0.923 0.7100 2.696 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8050E+00 0.8050E+00 1.0000 -0.094 grossular 0.1950E+00 0.1950E+00 1.0000 -0.710 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.7612E+00 0.7612E+00 1.0000 -0.119 daphnite 0.2203E+00 0.2203E+00 1.0000 -0.657 chlorite-Mn 0.1846E-01 0.1846E-01 1.0000 -1.734 diopside 0.7941E+00 0.7941E+00 1.0000 -0.100 hedenbergite 0.2059E+00 0.2059E+00 1.0000 -0.686 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 tr.625ac.25prg.125 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 1179.711830 g Volume = 478.017743 cm3 Porosity: -10.3968% V(tot) - V(min): -.45018E+02 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 1079.9990000 g log = 3.0334 Original solution: 1000.0103000 g Original solution / Rock added: 0.93 (Water/Rock Ratio), log = -0.0334 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0561 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9665E+00 0.9855 0.1006E+01 0.1021E+01 CO2,gas 0.3590E-08 1.0069 0.3817E-08 0.3791E-08 CH4,gas 0.1907E-01 1.0124 0.2040E-01 0.2015E-01 H2,gas 0.1439E-01 1.0006 0.1521E-01 0.1520E-01 H2S,gas 0.1434E-06 0.9959 0.1509E-06 0.1515E-06 S2,gas 0.3496E-29 1.0000 0.3693E-29 0.3693E-29 CO,gas 0.1465E-13 1.0000 0.1547E-13 0.1547E-13 SO3,gas 0.7441E-48 1.0000 0.7859E-48 0.7859E-48 SO2,gas 0.4403E-27 1.0000 0.4650E-27 0.4650E-27 HCl,gas 0.2927E-17 1.0000 0.3092E-17 0.3092E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 16 albite -0.38 -0.38 0.00 0.000 -0.94784E-12 22 andradite 39.01 39.01 0.00 0.000 -0.24265E-10 23 grossular 32.73 32.73 0.00 0.000 0.12132E-10 32 apatite-OH -18.15 -18.15 0.00 0.000 -0.60662E-11 46 clinochlore 39.07 39.07 0.00 0.000 0.12132E-10 47 daphnite 28.97 28.97 0.00 0.000 0.00000E+00 48 chlorite-Mn 46.87 46.87 0.00 0.000 0.24265E-10 67 diopside 16.18 16.18 0.00 0.000 0.00000E+00 68 hedenbergite 14.21 14.21 0.00 0.000 0.00000E+00 116 microcline -2.49 -2.49 0.00 0.000 0.15165E-11 163 stilbite -7.52 -7.52 0.00 0.000 0.15165E-10 164 stilpnomelane-Fe 13.02 13.02 0.00 0.000 0.69761E-10 245 tr.625ac.25prg.125 45.16 45.16 0.00 0.000 0.36397E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -16.78 -10.12 -3.372 0.17275E+05 -8.418 3 CH4,gas 4.54 1.15 -3.39 -0.847 0.57874E+04 -1.690 4 H2,gas 8.00 4.48 -3.52 -2.010 0.60049E+04 -1.818 5 H2S,gas -6.23 -14.75 -8.52 -4.260 0.14548E+05 -6.821 6 S2,gas -7.34 -38.47 -31.13 -4.789 0.53156E+05 -29.433 7 CO,gas 3.21 -12.29 -15.51 -4.772 0.26482E+05 -13.810 8 SO3,gas 17.12 -32.68 -49.80 -12.451 0.85038E+05 -48.105 9 SO2,gas 0.83 -28.20 -29.03 -7.742 0.49571E+05 -27.333 10 HCl,gas 5.19 -14.02 -19.21 -9.604 0.32798E+05 -17.510 11 acmite 7.71 6.53 -1.18 -0.123 0.20177E+04 15 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 19 spessartine 24.46 19.72 -4.74 -0.237 0.80851E+04 20 analcite 3.32 2.77 -0.55 -0.061 0.93619E+03 26 annite 20.12 17.72 -2.40 -0.134 0.41063E+04 27 phlogopite 27.06 25.40 -1.67 -0.093 0.28487E+04 29 anorthite 12.71 8.27 -4.45 -0.342 0.75900E+04 35 aragonite 0.97 -3.68 -4.64 -1.547 0.79261E+04 36 brucite 12.57 9.29 -3.27 -0.655 0.55908E+04 37 calcite 0.81 -3.68 -4.49 -1.496 0.76618E+04 38 carnegieite-low 9.02 5.93 -3.09 -0.442 0.52800E+04 39 carnegieite-high 10.09 5.93 -4.16 -0.595 0.71070E+04 40 carpholite-Mg 8.58 4.46 -4.12 -0.275 0.70426E+04 41 carpholite-Fe 6.71 1.90 -4.81 -0.321 0.82204E+04 42 celadonite 5.34 3.65 -1.69 -0.099 0.28879E+04 43 celadonite-Fe 3.88 1.09 -2.79 -0.164 0.47561E+04 44 chrysotile 23.89 21.57 -2.32 -0.194 0.39691E+04 49 chlorite-Al-free 47.17 43.14 -4.04 -0.168 0.68935E+04 51 chloritoid-Fe 9.17 5.06 -4.12 -0.275 0.70312E+04 52 chloritoid-Mn 11.40 7.56 -3.84 -0.256 0.65594E+04 54 coesite -2.38 -3.16 -0.78 -0.260 0.13342E+04 61 cristobalite -2.56 -3.16 -0.60 -0.199 0.10195E+04 63 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71234E+04 65 diaspore 2.87 0.74 -2.13 -0.356 0.36448E+04 66 diamond -3.10 -7.81 -4.71 -1.345 0.80407E+04 71 enstatite 17.26 12.27 -4.99 -0.499 0.85225E+04 73 clinoenstatite 17.17 12.27 -4.89 -0.489 0.83541E+04 75 epidote 24.67 22.70 -1.97 -0.095 0.33583E+04 76 clinozoisite 22.81 18.95 -3.86 -0.175 0.65864E+04 77 epidote-Fe 29.84 26.46 -3.38 -0.176 0.57768E+04 78 fayalite 14.05 10.31 -3.73 -0.533 0.63743E+04 79 ferrosilite 11.15 7.16 -3.99 -0.399 0.68202E+04 83 gibbsite 4.08 0.74 -3.34 -0.477 0.57034E+04 84 glaucophane 22.97 20.80 -2.17 -0.059 0.37133E+04 85 glaucophane-Fe 17.28 13.12 -4.15 -0.112 0.70919E+04 86 graphite -3.55 -7.81 -4.27 -1.219 0.72830E+04 87 greenalite 16.14 13.89 -2.25 -0.187 0.38408E+04 90 hematite 12.57 8.99 -3.58 -0.434 0.61112E+04 91 heulandite -5.83 -7.52 -1.69 -0.077 0.28938E+04 95 jadeite 4.22 2.77 -1.44 -0.144 0.24617E+04 97 kalsilite 7.58 3.83 -3.76 -0.537 0.64125E+04 98 kaolinite -1.33 -4.84 -3.50 -0.319 0.59829E+04 101 laumontite 2.88 1.95 -0.93 -0.062 0.15933E+04 102 lawsonite 9.62 8.27 -1.35 -0.090 0.23067E+04 103 leucite 4.12 0.67 -3.45 -0.345 0.58872E+04 105 lizardite 23.24 21.57 -1.68 -0.140 0.28618E+04 107 magnetite 20.09 15.72 -4.37 -0.356 0.74537E+04 108 minnesotaite 10.39 7.58 -2.81 -0.165 0.48029E+04 112 manganosite 14.06 9.24 -4.82 -1.205 0.82289E+04 120 muscovite 2.58 -1.01 -3.59 -0.211 0.61312E+04 121 paragonite 4.24 1.09 -3.15 -0.185 0.53703E+04 122 nepheline 8.34 5.93 -2.41 -0.344 0.41124E+04 128 periclase-Fe 11.63 6.73 -4.89 -1.223 0.83523E+04 134 phlogopite-Na 29.65 27.50 -2.15 -0.119 0.36676E+04 136 prehnite 19.37 18.21 -1.16 -0.068 0.19846E+04 137 prehnite-Fe 22.50 21.96 -0.53 -0.032 0.91151E+03 138 pumpellyite-Fe 46.27 43.89 -2.38 -0.053 0.40574E+04 139 pumpellyite-Mg 48.99 46.45 -2.54 -0.056 0.43412E+04 143 pyrrhotite -4.26 -8.02 -3.76 -1.252 0.64122E+04 144 pyrrhotiteFe0.875 -6.02 -9.41 -3.40 -1.249 0.57994E+04 145 pyroxmangite 7.40 6.08 -1.32 -0.263 0.22493E+04 146 pyrophyllite -6.18 -11.15 -4.98 -0.311 0.84961E+04 147 quartz -2.99 -3.16 -0.17 -0.056 0.28686E+03 152 rhodonite 7.45 6.08 -1.36 -0.273 0.23296E+04 153 sanidine -1.28 -2.49 -1.21 -0.093 0.20677E+04 165 stilpnomelane-Mg 27.44 25.81 -1.63 -0.049 0.27802E+04 171 talc 16.49 15.25 -1.24 -0.073 0.21141E+04 174 tephroite 18.09 15.32 -2.77 -0.395 0.47223E+04 178 tridymite -2.63 -3.16 -0.53 -0.177 0.90684E+03 179 tremolite 47.87 47.42 -0.45 -0.012 0.77496E+03 180 ferroactinolite 38.45 34.62 -3.83 -0.104 0.65451E+04 181 troilite-low -4.41 -8.02 -3.60 -1.202 0.61550E+04 183 vesuvianite 223.47 218.82 -4.65 -0.036 0.79418E+04 187 wairakite 3.95 1.95 -2.00 -0.118 0.34153E+04 188 walstromite 11.51 9.94 -1.56 -0.313 0.26719E+04 189 wollastonite 10.46 9.94 -0.52 -0.103 0.88229E+03 190 pseudo-wollastonite 11.00 9.94 -1.06 -0.211 0.18021E+04 191 zoisite 22.85 18.95 -3.90 -0.177 0.66605E+04 192 akaganeite 7.75 4.49 -3.26 -0.705 0.55681E+04 199 chalcedony -2.80 -3.16 -0.36 -0.118 0.60616E+03 201 montmorillonite-Ca -2.29 -6.17 -3.88 -0.240 0.66180E+04 202 montmorillonite-K -2.24 -6.27 -4.03 -0.247 0.68816E+04 203 montmorillonite-Mg -2.48 -6.79 -4.31 -0.267 0.73677E+04 204 montmorillonite-Na -2.04 -5.57 -3.54 -0.216 0.60364E+04 205 nontronite-Ca 3.21 -0.20 -3.41 -0.221 0.58217E+04 206 nontronite-H 2.53 -2.36 -4.89 -0.328 0.83487E+04 207 nontronite-K 3.34 -0.30 -3.64 -0.233 0.62085E+04 208 nontronite-Mg 3.07 -0.82 -3.90 -0.253 0.66555E+04 209 nontronite-Na 3.52 0.40 -3.12 -0.200 0.53294E+04 224 tobermorite 9.82 7.76 -2.07 -0.564 0.35287E+04 230 alabandite -0.98 -5.51 -4.53 -1.511 0.77417E+04 233 boehmite 4.41 0.74 -3.67 -0.611 0.62617E+04 235 ferrous-oxide 9.81 6.73 -3.08 -0.769 0.52532E+04 240 silica-amorphous -2.09 -3.16 -1.07 -0.355 0.18203E+04 242 an20ab80 2.02 1.35 -0.67 -0.052 0.11472E+04 243 an25ab75 2.65 1.78 -0.87 -0.067 0.14809E+04 244 an30ab70 3.28 2.21 -1.07 -0.082 0.18243E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 40.0000000 g Current total amount of reactant added: 1079.9990000 g New total amount of reactant added: 1119.9990000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.3298E-10 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 11 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 1119.9990000 Water: Moles liquid = 0.4918E+02 kg liquid = 0.8860E+00 Moles total = 0.4147E+02 kg total = 0.7471E+00 Activity = 1.0000 Stoichiometric ionic strength = .1133218E-01 Osmotic coef. = 0.9693 True ionic strength = .2001929E-01 Chg. balance for total moles = 0.3298E-10 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.88297E-10 -10.0541 0.74192E-10 -10.1296 0.84025E+00 -0.0756 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.15502E-03 -3.8096 0.12947E-03 -3.8878 0.83520E+00 -0.0782 4 SO4-- 0.73046E-12 -12.1364 0.37933E-12 -12.4210 0.51930E+00 -0.2846 5 HCO3- 0.27031E-06 -6.5681 0.22609E-06 -6.6457 0.83642E+00 -0.0776 6 HS- 0.28781E-04 -4.5409 0.24041E-04 -4.6190 0.83532E+00 -0.0781 7 Al+++ 0.96933E-29 -29.0135 0.22394E-29 -29.6499 0.23103E+00 -0.6363 8 H4SiO4 0.69593E-03 -3.1574 0.69593E-03 -3.1574 0.10000E+01 0.0000 9 Ca++ 0.13501E-06 -6.8696 0.69594E-07 -7.1574 0.51549E+00 -0.2878 10 Mg++ 0.21121E-10 -10.6753 0.10838E-10 -10.9651 0.51313E+00 -0.2898 11 Fe++ 0.58210E-13 -13.2350 0.29902E-13 -13.5243 0.51369E+00 -0.2893 12 K+ 0.15652E-03 -3.8054 0.13095E-03 -3.8829 0.83662E+00 -0.0775 13 Na+ 0.19862E-01 -1.7020 0.16585E-01 -1.7803 0.83504E+00 -0.0783 14 Mn++ 0.18559E-10 -10.7314 0.95416E-11 -11.0204 0.51412E+00 -0.2889 15 HPO4-- 0.45312E-07 -7.3438 0.23534E-07 -7.6283 0.51937E+00 -0.2845 16 HSiO3- 0.10487E-01 -1.9794 0.87586E-02 -2.0576 0.83520E+00 -0.0782 17 Ca(HSiO3)+ 0.16589E-07 -7.7802 0.13882E-07 -7.8576 0.83680E+00 -0.0774 18 Mg(HSiO3)+ 0.32151E-11 -11.4928 0.26904E-11 -11.5702 0.83680E+00 -0.0774 19 NaHSiO3,aq 0.23495E-02 -2.6290 0.23495E-02 -2.6290 0.10000E+01 0.0000 20 AlO+ 0.66142E-16 -16.1795 0.55347E-16 -16.2569 0.83680E+00 -0.0774 22 HAlO2,aq 0.14857E-09 -9.8281 0.14857E-09 -9.8281 0.10000E+01 0.0000 23 AlO2- 0.53169E-05 -5.2743 0.44326E-05 -5.3533 0.83369E+00 -0.0790 24 CH4,aq 0.13968E-04 -4.8549 0.13919E-04 -4.8564 0.99654E+00 -0.0015 25 C2H6,aq 0.28691E-14 -14.5423 0.28592E-14 -14.5438 0.99654E+00 -0.0015 29 CO,aq 0.10431E-16 -16.9817 0.10431E-16 -16.9817 0.10000E+01 0.0000 30 CO2,aq 0.35967E-10 -10.4441 0.35843E-10 -10.4456 0.99654E+00 -0.0015 31 CO3-2 0.51367E-06 -6.2893 0.26618E-06 -6.5748 0.51820E+00 -0.2855 32 CaCO3,aq 0.23228E-09 -9.6340 0.23228E-09 -9.6340 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.47998E-12 -12.3188 0.40165E-12 -12.3962 0.83680E+00 -0.0774 34 CaCl+ 0.17425E-10 -10.7588 0.14581E-10 -10.8362 0.83680E+00 -0.0774 35 CaCl2,aq 0.44851E-15 -15.3482 0.44851E-15 -15.3482 0.10000E+01 0.0000 36 CaOH+ 0.79891E-07 -7.0975 0.66853E-07 -7.1749 0.83680E+00 -0.0774 37 CaSO4,aq 0.83829E-17 -17.0766 0.83829E-17 -17.0766 0.10000E+01 0.0000 38 HCl,aq 0.17602E-14 -14.7544 0.17602E-14 -14.7544 0.10000E+01 0.0000 43 FeCl+ 0.73229E-17 -17.1353 0.61277E-17 -17.2127 0.83680E+00 -0.0774 46 FeO,aq 0.21113E-09 -9.6754 0.21113E-09 -9.6754 0.10000E+01 0.0000 47 FeOH+ 0.15678E-10 -10.8047 0.13119E-10 -10.8821 0.83680E+00 -0.0774 48 HFeO2- 0.35651E-07 -7.4479 0.29776E-07 -7.5261 0.83520E+00 -0.0782 49 FeO+ 0.10987E-16 -16.9591 0.91938E-17 -17.0365 0.83680E+00 -0.0774 51 FeO2- 0.40921E-09 -9.3881 0.34177E-09 -9.4663 0.83520E+00 -0.0782 52 HFeO2,aq 0.32250E-11 -11.4915 0.32250E-11 -11.4915 0.10000E+01 0.0000 53 H2,aq 0.11625E-04 -4.9346 0.11585E-04 -4.9361 0.99654E+00 -0.0015 54 KCl,aq 0.30727E-09 -9.5125 0.30727E-09 -9.5125 0.10000E+01 0.0000 56 KOH,aq 0.75375E-06 -6.1228 0.75375E-06 -6.1228 0.10000E+01 0.0000 57 KSO4- 0.92289E-15 -15.0348 0.77080E-15 -15.1131 0.83520E+00 -0.0782 58 MgCO3,aq 0.90668E-14 -14.0425 0.90668E-14 -14.0425 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.76377E-16 -16.1170 0.63912E-16 -16.1944 0.83680E+00 -0.0774 60 MgCl+ 0.24595E-14 -14.6092 0.20581E-14 -14.6865 0.83680E+00 -0.0774 61 MgOH+ 0.68844E-10 -10.1621 0.57609E-10 -10.2395 0.83680E+00 -0.0774 63 MnO,aq 0.17952E-08 -8.7459 0.17952E-08 -8.7459 0.10000E+01 0.0000 64 MnOH+ 0.46474E-09 -9.3328 0.38889E-09 -9.4102 0.83680E+00 -0.0774 65 MnO2-2 0.20887E-10 -10.6801 0.10823E-10 -10.9656 0.51820E+00 -0.2855 66 HMnO2- 0.21064E-09 -9.6765 0.17593E-09 -9.7547 0.83520E+00 -0.0782 69 MnCl+ 0.90908E-14 -14.0414 0.76072E-14 -14.1188 0.83680E+00 -0.0774 71 NaCl,aq 0.71162E-06 -6.1478 0.71162E-06 -6.1478 0.10000E+01 0.0000 72 NaOH,aq 0.96047E-04 -4.0175 0.96047E-04 -4.0175 0.10000E+01 0.0000 74 OH- 0.93411E-02 -2.0296 0.77876E-02 -2.1086 0.83369E+00 -0.0790 79 HPO3-2 0.16395E-14 -14.7853 0.84960E-15 -15.0708 0.51820E+00 -0.2855 81 H2PO3- 0.15134E-18 -18.8200 0.12640E-18 -18.8983 0.83520E+00 -0.0782 82 H3PO4,aq 0.90599E-18 -18.0429 0.90599E-18 -18.0429 0.10000E+01 0.0000 83 H2PO4- 0.38528E-10 -10.4142 0.32209E-10 -10.4920 0.83599E+00 -0.0778 84 PO4-3 0.10666E-08 -8.9720 0.25880E-09 -9.5870 0.24264E+00 -0.6150 88 HP2O7-3 0.94669E-18 -18.0238 0.21893E-18 -18.6597 0.23126E+00 -0.6359 89 P2O7-4 0.91428E-17 -17.0389 0.70495E-18 -18.1518 0.77104E-01 -1.1129 90 H2S,aq 0.55317E-08 -8.2571 0.55126E-08 -8.2586 0.99654E+00 -0.0015 91 S2-2 0.21334E-14 -14.6709 0.11055E-14 -14.9564 0.51820E+00 -0.2855 97 SO3-2 0.10863E-17 -17.9641 0.57105E-18 -18.2433 0.52569E+00 -0.2793 99 HSO4- 0.32380E-19 -19.4897 0.27122E-19 -19.5667 0.83761E+00 -0.0770 Charge balance for all species = 0.3723E-10 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.8829719E-10 -.2229922E-01 -.2243721E+02 0.0000 2 H2O 0.1000000E+01 0.5550489E+02 0.9981995E+06 0.0000 3 Cl- 0.1550170E-03 0.1557289E-03 0.5511464E+01 6.2418 4 SO4-- 0.7304632E-12 -.1687375E-04 -.1618102E+01 7.8383 5 HCO3- 0.2703135E-06 0.1475187E-04 0.8985536E+00 3.4839 6 HS- 0.2878090E-04 0.4566018E-04 0.1507449E+01 5.5106 7 Al+++ 0.9693268E-29 0.5317023E-05 0.1432119E+00 0.7391 8 H4SiO4 0.6959283E-03 0.1353234E-01 0.1298406E+04 -3.1574 9 Ca++ 0.1350055E-06 0.2317362E-06 0.9271385E-02 13.1019 10 Mg++ 0.2112080E-10 0.9319169E-10 0.2261739E-05 9.2942 11 Fe++ 0.5820961E-13 0.3629030E-07 0.2023182E-02 6.7350 12 K+ 0.1565209E-03 0.1572749E-03 0.6139077E+01 6.2467 13 Na+ 0.1986171E-01 0.2230794E-01 0.5119637E+03 8.3494 14 Mn++ 0.1855912E-10 0.2510001E-08 0.1376548E-03 9.2389 15 HPO4-- 0.4531179E-07 0.4641692E-07 0.4447307E-02 12.6310 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.1854551E+02 -.1975687E-01 -.1852575E+02 0.0000000E+00 2 H2O 0.4146860E+02 0.4917674E+02 -.7708134E+01 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.3106449E-01 -.1494996E-04 0.3107944E-01 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.3103899E-01 0.4045443E-04 -.3107944E-01 0.0000000E+00 7 Al+++ 0.3652027E+01 0.4710825E-05 0.3652023E+01 0.0000000E+00 8 H4SiO4 0.1166231E+02 0.1198951E-01 0.1165032E+02 0.0000000E+00 9 Ca++ 0.1288173E+01 0.2053158E-06 0.1288173E+01 0.0000000E+00 10 Mg++ 0.8888881E+00 0.8256684E-10 0.8888881E+00 0.0000000E+00 11 Fe++ 0.7985689E+00 0.3215282E-07 0.7985689E+00 0.0000000E+00 12 K+ 0.2377917E+00 0.1393439E-03 0.2376524E+00 0.0000000E+00 13 Na+ 0.1406032E+01 0.1976459E-01 0.1386267E+01 0.0000000E+00 14 Mn++ 0.1941921E-01 0.2223834E-08 0.1941921E-01 0.0000000E+00 15 HPO4-- 0.6627680E-02 0.4112489E-07 0.6627639E-02 0.0000000E+00 Chg. balance for solid moles: -.3979E-14 Mass of aqueous solution: 0.887532E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 1119.9990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 1.385 0.141 363.2 2.560 29.69 139.4 andradite 0.1243 -0.905 63.18 1.801 5.164 16.41 grossular 0.3011E-01 -1.521 13.56 1.132 1.109 3.774 apatite-OH 0.2209E-02 -2.656 1.110 0.045 0.9071E-01 0.3526 clinochlore 0.1601 -0.796 88.99 1.949 7.274 33.85 daphnite 0.4635E-01 -1.334 33.07 1.519 2.703 10.02 chlorite-Mn 0.3884E-02 -2.411 2.754 0.440 0.2251 0.8775 diopside 0.5166E-01 -1.287 11.19 1.049 0.9144 3.419 hedenbergite 0.1340E-01 -1.873 3.324 0.522 0.2717 0.9103 microcline 0.2084 -0.681 58.02 1.764 4.742 22.66 stilbite 0.7285 -0.138 513.4 2.710 41.97 239.5 stilpnomelane-Fe 0.5843E-01 -1.233 62.99 1.799 5.148 21.76 tr.625ac.25prg.125 0.1013E-01 -1.994 8.661 0.938 0.7079 2.787 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8050E+00 0.8050E+00 1.0000 -0.094 grossular 0.1950E+00 0.1950E+00 1.0000 -0.710 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.7612E+00 0.7612E+00 1.0000 -0.119 daphnite 0.2203E+00 0.2203E+00 1.0000 -0.657 chlorite-Mn 0.1847E-01 0.1847E-01 1.0000 -1.734 diopside 0.7941E+00 0.7941E+00 1.0000 -0.100 hedenbergite 0.2059E+00 0.2059E+00 1.0000 -0.686 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 tr.625ac.25prg.125 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 1223.412094 g Volume = 495.698968 cm3 Porosity: -10.4008% V(tot) - V(min): -.46699E+02 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 1119.9990000 g log = 3.0492 Original solution: 1000.0103000 g Original solution / Rock added: 0.89 (Water/Rock Ratio), log = -0.0492 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0562 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9664E+00 0.9855 0.1006E+01 0.1021E+01 CO2,gas 0.3606E-08 1.0069 0.3835E-08 0.3808E-08 CH4,gas 0.1916E-01 1.0124 0.2049E-01 0.2024E-01 H2,gas 0.1439E-01 1.0006 0.1521E-01 0.1520E-01 H2S,gas 0.1441E-06 0.9959 0.1515E-06 0.1522E-06 S2,gas 0.3528E-29 1.0000 0.3726E-29 0.3726E-29 CO,gas 0.1472E-13 1.0000 0.1554E-13 0.1554E-13 SO3,gas 0.7474E-48 1.0000 0.7895E-48 0.7895E-48 SO2,gas 0.4423E-27 1.0000 0.4671E-27 0.4671E-27 HCl,gas 0.2941E-17 1.0000 0.3106E-17 0.3106E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 16 albite -0.38 -0.38 0.00 0.000 0.11184E-10 22 andradite 39.01 39.01 0.00 0.000 0.12132E-10 23 grossular 32.73 32.73 0.00 0.000 0.12132E-10 32 apatite-OH -18.15 -18.15 0.00 0.000 0.60662E-11 46 clinochlore 39.07 39.07 0.00 0.000 0.60662E-10 47 daphnite 28.97 28.97 0.00 0.000 0.12132E-10 48 chlorite-Mn 46.87 46.87 0.00 0.000 0.36397E-10 67 diopside 16.18 16.18 0.00 0.000 0.12132E-10 68 hedenbergite 14.21 14.21 0.00 0.000 0.12132E-10 116 microcline -2.49 -2.49 0.00 0.000 0.13649E-10 163 stilbite -7.52 -7.52 0.00 0.000 0.15165E-10 164 stilpnomelane-Fe 13.02 13.02 0.00 0.000 -0.27298E-10 245 tr.625ac.25prg.125 45.16 45.16 0.00 0.000 0.00000E+00 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -16.78 -10.12 -3.372 0.17271E+05 -8.416 3 CH4,gas 4.54 1.16 -3.39 -0.847 0.57840E+04 -1.688 4 H2,gas 8.00 4.48 -3.52 -2.010 0.60050E+04 -1.818 5 H2S,gas -6.23 -14.75 -8.52 -4.259 0.14545E+05 -6.819 6 S2,gas -7.34 -38.46 -31.13 -4.789 0.53150E+05 -29.429 7 CO,gas 3.21 -12.29 -15.51 -4.772 0.26478E+05 -13.808 8 SO3,gas 17.12 -32.68 -49.80 -12.450 0.85035E+05 -48.103 9 SO2,gas 0.83 -28.20 -29.03 -7.741 0.49567E+05 -27.331 10 HCl,gas 5.19 -14.02 -19.21 -9.603 0.32795E+05 -17.508 11 acmite 7.71 6.53 -1.18 -0.123 0.20177E+04 15 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 19 spessartine 24.46 19.72 -4.73 -0.237 0.80845E+04 20 analcite 3.32 2.77 -0.55 -0.061 0.93620E+03 26 annite 20.12 17.72 -2.40 -0.134 0.41063E+04 27 phlogopite 27.06 25.40 -1.67 -0.093 0.28487E+04 29 anorthite 12.71 8.27 -4.45 -0.342 0.75900E+04 35 aragonite 0.97 -3.67 -4.64 -1.547 0.79227E+04 36 brucite 12.57 9.29 -3.27 -0.655 0.55908E+04 37 calcite 0.81 -3.67 -4.49 -1.495 0.76585E+04 38 carnegieite-low 9.02 5.93 -3.09 -0.442 0.52800E+04 39 carnegieite-high 10.09 5.93 -4.16 -0.595 0.71070E+04 40 carpholite-Mg 8.58 4.46 -4.12 -0.275 0.70426E+04 41 carpholite-Fe 6.71 1.90 -4.81 -0.321 0.82204E+04 42 celadonite 5.34 3.65 -1.69 -0.099 0.28879E+04 43 celadonite-Fe 3.88 1.09 -2.79 -0.164 0.47561E+04 44 chrysotile 23.89 21.57 -2.32 -0.194 0.39691E+04 49 chlorite-Al-free 47.17 43.14 -4.04 -0.168 0.68935E+04 51 chloritoid-Fe 9.17 5.06 -4.12 -0.275 0.70313E+04 52 chloritoid-Mn 11.40 7.56 -3.84 -0.256 0.65592E+04 54 coesite -2.38 -3.16 -0.78 -0.260 0.13342E+04 61 cristobalite -2.56 -3.16 -0.60 -0.199 0.10195E+04 63 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71234E+04 65 diaspore 2.87 0.74 -2.13 -0.356 0.36448E+04 66 diamond -3.10 -7.81 -4.71 -1.345 0.80374E+04 71 enstatite 17.26 12.27 -4.99 -0.499 0.85225E+04 73 clinoenstatite 17.17 12.27 -4.89 -0.489 0.83541E+04 75 epidote 24.67 22.70 -1.97 -0.095 0.33583E+04 76 clinozoisite 22.81 18.95 -3.86 -0.175 0.65864E+04 77 epidote-Fe 29.84 26.46 -3.38 -0.176 0.57768E+04 78 fayalite 14.05 10.31 -3.73 -0.533 0.63743E+04 79 ferrosilite 11.15 7.16 -3.99 -0.399 0.68202E+04 83 gibbsite 4.08 0.74 -3.34 -0.477 0.57034E+04 84 glaucophane 22.97 20.80 -2.17 -0.059 0.37133E+04 85 glaucophane-Fe 17.28 13.12 -4.15 -0.112 0.70919E+04 86 graphite -3.55 -7.81 -4.26 -1.218 0.72796E+04 87 greenalite 16.14 13.89 -2.25 -0.187 0.38408E+04 90 hematite 12.57 8.99 -3.58 -0.434 0.61112E+04 91 heulandite -5.83 -7.52 -1.69 -0.077 0.28938E+04 95 jadeite 4.22 2.77 -1.44 -0.144 0.24617E+04 97 kalsilite 7.58 3.83 -3.76 -0.537 0.64125E+04 98 kaolinite -1.33 -4.84 -3.50 -0.319 0.59829E+04 101 laumontite 2.88 1.95 -0.93 -0.062 0.15933E+04 102 lawsonite 9.62 8.27 -1.35 -0.090 0.23067E+04 103 leucite 4.12 0.67 -3.45 -0.345 0.58872E+04 105 lizardite 23.24 21.57 -1.68 -0.140 0.28618E+04 107 magnetite 20.09 15.72 -4.37 -0.356 0.74537E+04 108 minnesotaite 10.39 7.58 -2.81 -0.165 0.48029E+04 112 manganosite 14.06 9.24 -4.82 -1.205 0.82287E+04 120 muscovite 2.58 -1.01 -3.59 -0.211 0.61312E+04 121 paragonite 4.24 1.09 -3.15 -0.185 0.53703E+04 122 nepheline 8.34 5.93 -2.41 -0.344 0.41124E+04 128 periclase-Fe 11.63 6.73 -4.89 -1.223 0.83523E+04 134 phlogopite-Na 29.65 27.50 -2.15 -0.119 0.36676E+04 136 prehnite 19.37 18.21 -1.16 -0.068 0.19846E+04 137 prehnite-Fe 22.50 21.96 -0.53 -0.032 0.91151E+03 138 pumpellyite-Fe 46.27 43.89 -2.38 -0.053 0.40574E+04 139 pumpellyite-Mg 48.99 46.45 -2.54 -0.056 0.43412E+04 143 pyrrhotite -4.26 -8.01 -3.75 -1.251 0.64088E+04 144 pyrrhotiteFe0.875 -6.02 -9.41 -3.39 -1.248 0.57960E+04 145 pyroxmangite 7.40 6.08 -1.32 -0.263 0.22491E+04 146 pyrophyllite -6.18 -11.15 -4.98 -0.311 0.84961E+04 147 quartz -2.99 -3.16 -0.17 -0.056 0.28686E+03 152 rhodonite 7.45 6.08 -1.36 -0.273 0.23293E+04 153 sanidine -1.28 -2.49 -1.21 -0.093 0.20677E+04 165 stilpnomelane-Mg 27.44 25.81 -1.63 -0.049 0.27802E+04 171 talc 16.49 15.25 -1.24 -0.073 0.21141E+04 174 tephroite 18.09 15.32 -2.77 -0.395 0.47219E+04 178 tridymite -2.63 -3.16 -0.53 -0.177 0.90683E+03 179 tremolite 47.87 47.42 -0.45 -0.012 0.77496E+03 180 ferroactinolite 38.45 34.62 -3.83 -0.104 0.65451E+04 181 troilite-low -4.41 -8.01 -3.60 -1.201 0.61516E+04 183 vesuvianite 223.47 218.82 -4.65 -0.036 0.79419E+04 187 wairakite 3.95 1.95 -2.00 -0.118 0.34153E+04 188 walstromite 11.51 9.94 -1.56 -0.313 0.26719E+04 189 wollastonite 10.46 9.94 -0.52 -0.103 0.88229E+03 190 pseudo-wollastonite 11.00 9.94 -1.06 -0.211 0.18021E+04 191 zoisite 22.85 18.95 -3.90 -0.177 0.66605E+04 192 akaganeite 7.75 4.49 -3.26 -0.705 0.55681E+04 199 chalcedony -2.80 -3.16 -0.36 -0.118 0.60615E+03 201 montmorillonite-Ca -2.29 -6.17 -3.88 -0.240 0.66180E+04 202 montmorillonite-K -2.24 -6.27 -4.03 -0.247 0.68816E+04 203 montmorillonite-Mg -2.48 -6.79 -4.31 -0.267 0.73677E+04 204 montmorillonite-Na -2.04 -5.57 -3.54 -0.216 0.60364E+04 205 nontronite-Ca 3.21 -0.20 -3.41 -0.221 0.58217E+04 206 nontronite-H 2.53 -2.36 -4.89 -0.328 0.83487E+04 207 nontronite-K 3.34 -0.30 -3.64 -0.233 0.62085E+04 208 nontronite-Mg 3.07 -0.82 -3.90 -0.253 0.66555E+04 209 nontronite-Na 3.52 0.40 -3.12 -0.200 0.53294E+04 224 tobermorite 9.82 7.76 -2.07 -0.564 0.35287E+04 230 alabandite -0.98 -5.51 -4.53 -1.511 0.77381E+04 233 boehmite 4.41 0.74 -3.67 -0.611 0.62617E+04 235 ferrous-oxide 9.81 6.73 -3.08 -0.769 0.52532E+04 240 silica-amorphous -2.09 -3.16 -1.07 -0.355 0.18203E+04 242 an20ab80 2.02 1.35 -0.67 -0.052 0.11472E+04 243 an25ab75 2.65 1.78 -0.87 -0.067 0.14809E+04 244 an30ab70 3.28 2.21 -1.07 -0.082 0.18243E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 40.0000000 g Current total amount of reactant added: 1119.9990000 g New total amount of reactant added: 1159.9990000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.3298E-10 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 11 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 1159.9990000 Water: Moles liquid = 0.4896E+02 kg liquid = 0.8820E+00 Moles total = 0.4097E+02 kg total = 0.7380E+00 Activity = 1.0000 Stoichiometric ionic strength = .1133277E-01 Osmotic coef. = 0.9693 True ionic strength = .2001977E-01 Chg. balance for total moles = 0.3298E-10 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.88299E-10 -10.0540 0.74193E-10 -10.1296 0.84025E+00 -0.0756 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.15572E-03 -3.8076 0.13006E-03 -3.8859 0.83519E+00 -0.0782 4 SO4-- 0.73380E-12 -12.1344 0.38106E-12 -12.4190 0.51930E+00 -0.2846 5 HCO3- 0.27155E-06 -6.5662 0.22713E-06 -6.6437 0.83642E+00 -0.0776 6 HS- 0.28912E-04 -4.5389 0.24151E-04 -4.6171 0.83532E+00 -0.0781 7 Al+++ 0.96940E-29 -29.0135 0.22395E-29 -29.6498 0.23102E+00 -0.6363 8 H4SiO4 0.69593E-03 -3.1574 0.69593E-03 -3.1574 0.10000E+01 0.0000 9 Ca++ 0.13501E-06 -6.8696 0.69597E-07 -7.1574 0.51549E+00 -0.2878 10 Mg++ 0.21122E-10 -10.6753 0.10838E-10 -10.9650 0.51313E+00 -0.2898 11 Fe++ 0.58212E-13 -13.2350 0.29903E-13 -13.5243 0.51369E+00 -0.2893 12 K+ 0.15652E-03 -3.8054 0.13095E-03 -3.8829 0.83661E+00 -0.0775 13 Na+ 0.19862E-01 -1.7020 0.16586E-01 -1.7803 0.83504E+00 -0.0783 14 Mn++ 0.18565E-10 -10.7313 0.95446E-11 -11.0202 0.51412E+00 -0.2889 15 HPO4-- 0.45310E-07 -7.3438 0.23533E-07 -7.6283 0.51937E+00 -0.2845 16 HSiO3- 0.10487E-01 -1.9794 0.87585E-02 -2.0576 0.83519E+00 -0.0782 17 Ca(HSiO3)+ 0.16589E-07 -7.7802 0.13882E-07 -7.8575 0.83679E+00 -0.0774 18 Mg(HSiO3)+ 0.32151E-11 -11.4928 0.26904E-11 -11.5702 0.83679E+00 -0.0774 19 NaHSiO3,aq 0.23495E-02 -2.6290 0.23495E-02 -2.6290 0.10000E+01 0.0000 20 AlO+ 0.66143E-16 -16.1795 0.55348E-16 -16.2569 0.83679E+00 -0.0774 22 HAlO2,aq 0.14856E-09 -9.8281 0.14856E-09 -9.8281 0.10000E+01 0.0000 23 AlO2- 0.53167E-05 -5.2744 0.44325E-05 -5.3534 0.83369E+00 -0.0790 24 CH4,aq 0.14031E-04 -4.8529 0.13983E-04 -4.8544 0.99654E+00 -0.0015 25 C2H6,aq 0.28953E-14 -14.5383 0.28853E-14 -14.5398 0.99654E+00 -0.0015 29 CO,aq 0.10478E-16 -16.9797 0.10478E-16 -16.9797 0.10000E+01 0.0000 30 CO2,aq 0.36132E-10 -10.4421 0.36007E-10 -10.4436 0.99654E+00 -0.0015 31 CO3-2 0.51600E-06 -6.2873 0.26739E-06 -6.5729 0.51820E+00 -0.2855 32 CaCO3,aq 0.23334E-09 -9.6320 0.23334E-09 -9.6320 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.48219E-12 -12.3168 0.40350E-12 -12.3942 0.83679E+00 -0.0774 34 CaCl+ 0.17505E-10 -10.7568 0.14648E-10 -10.8342 0.83679E+00 -0.0774 35 CaCl2,aq 0.45263E-15 -15.3443 0.45263E-15 -15.3443 0.10000E+01 0.0000 36 CaOH+ 0.79893E-07 -7.0975 0.66854E-07 -7.1749 0.83679E+00 -0.0774 37 CaSO4,aq 0.84215E-17 -17.0746 0.84215E-17 -17.0746 0.10000E+01 0.0000 38 HCl,aq 0.17682E-14 -14.7525 0.17682E-14 -14.7525 0.10000E+01 0.0000 43 FeCl+ 0.73565E-17 -17.1333 0.61559E-17 -17.2107 0.83679E+00 -0.0774 46 FeO,aq 0.21113E-09 -9.6754 0.21113E-09 -9.6754 0.10000E+01 0.0000 47 FeOH+ 0.15678E-10 -10.8047 0.13119E-10 -10.8821 0.83679E+00 -0.0774 48 HFeO2- 0.35650E-07 -7.4479 0.29775E-07 -7.5261 0.83519E+00 -0.0782 49 FeO+ 0.10987E-16 -16.9591 0.91940E-17 -17.0365 0.83679E+00 -0.0774 51 FeO2- 0.40920E-09 -9.3881 0.34176E-09 -9.4663 0.83519E+00 -0.0782 52 HFeO2,aq 0.32250E-11 -11.4915 0.32250E-11 -11.4915 0.10000E+01 0.0000 53 H2,aq 0.11625E-04 -4.9346 0.11584E-04 -4.9361 0.99654E+00 -0.0015 54 KCl,aq 0.30868E-09 -9.5105 0.30868E-09 -9.5105 0.10000E+01 0.0000 56 KOH,aq 0.75375E-06 -6.1228 0.75375E-06 -6.1228 0.10000E+01 0.0000 57 KSO4- 0.92712E-15 -15.0329 0.77433E-15 -15.1111 0.83519E+00 -0.0782 58 MgCO3,aq 0.91084E-14 -14.0406 0.91084E-14 -14.0406 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.76729E-16 -16.1150 0.64207E-16 -16.1924 0.83679E+00 -0.0774 60 MgCl+ 0.24708E-14 -14.6072 0.20675E-14 -14.6845 0.83679E+00 -0.0774 61 MgOH+ 0.68846E-10 -10.1621 0.57610E-10 -10.2395 0.83679E+00 -0.0774 63 MnO,aq 0.17957E-08 -8.7458 0.17957E-08 -8.7458 0.10000E+01 0.0000 64 MnOH+ 0.46488E-09 -9.3327 0.38901E-09 -9.4100 0.83679E+00 -0.0774 65 MnO2-2 0.20892E-10 -10.6800 0.10826E-10 -10.9655 0.51820E+00 -0.2855 66 HMnO2- 0.21069E-09 -9.6763 0.17597E-09 -9.7546 0.83519E+00 -0.0782 69 MnCl+ 0.91351E-14 -14.0393 0.76442E-14 -14.1167 0.83679E+00 -0.0774 71 NaCl,aq 0.71488E-06 -6.1458 0.71488E-06 -6.1458 0.10000E+01 0.0000 72 NaOH,aq 0.96047E-04 -4.0175 0.96047E-04 -4.0175 0.10000E+01 0.0000 74 OH- 0.93409E-02 -2.0296 0.77874E-02 -2.1086 0.83369E+00 -0.0790 79 HPO3-2 0.16395E-14 -14.7853 0.84956E-15 -15.0708 0.51820E+00 -0.2855 81 H2PO3- 0.15134E-18 -18.8200 0.12640E-18 -18.8983 0.83519E+00 -0.0782 82 H3PO4,aq 0.90600E-18 -18.0429 0.90600E-18 -18.0429 0.10000E+01 0.0000 83 H2PO4- 0.38528E-10 -10.4142 0.32209E-10 -10.4920 0.83599E+00 -0.0778 84 PO4-3 0.10665E-08 -8.9720 0.25879E-09 -9.5871 0.24264E+00 -0.6150 88 HP2O7-3 0.94665E-18 -18.0238 0.21892E-18 -18.6597 0.23125E+00 -0.6359 89 P2O7-4 0.91424E-17 -17.0389 0.70489E-18 -18.1519 0.77102E-01 -1.1129 90 H2S,aq 0.55570E-08 -8.2552 0.55378E-08 -8.2567 0.99654E+00 -0.0015 91 S2-2 0.21529E-14 -14.6670 0.11156E-14 -14.9525 0.51820E+00 -0.2855 97 SO3-2 0.10912E-17 -17.9621 0.57365E-18 -18.2414 0.52569E+00 -0.2793 99 HSO4- 0.32529E-19 -19.4877 0.27246E-19 -19.5647 0.83761E+00 -0.0770 Charge balance for all species = 0.3739E-10 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.8829926E-10 -.2229885E-01 -.2243685E+02 0.0000 2 H2O 0.1000000E+01 0.5550489E+02 0.9981994E+06 0.0000 3 Cl- 0.1557230E-03 0.1564382E-03 0.5536566E+01 6.2438 4 SO4-- 0.7337998E-12 -.1693734E-04 -.1624201E+01 7.8403 5 HCO3- 0.2715474E-06 0.1481906E-04 0.9026462E+00 3.4859 6 HS- 0.2891198E-04 0.4585489E-04 0.1513877E+01 5.5126 7 Al+++ 0.9693952E-29 0.5316862E-05 0.1432076E+00 0.7391 8 H4SiO4 0.6959305E-03 0.1353217E-01 0.1298389E+04 -3.1574 9 Ca++ 0.1350119E-06 0.2317457E-06 0.9271765E-02 13.1019 10 Mg++ 0.2112179E-10 0.9319395E-10 0.2261794E-05 9.2942 11 Fe++ 0.5821247E-13 0.3628952E-07 0.2023139E-02 6.7350 12 K+ 0.1565245E-03 0.1572786E-03 0.6139220E+01 6.2467 13 Na+ 0.1986217E-01 0.2230841E-01 0.5119747E+03 8.3494 14 Mn++ 0.1856509E-10 0.2510688E-08 0.1376925E-03 9.2390 15 HPO4-- 0.4531033E-07 0.4641540E-07 0.4447162E-02 12.6309 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.1920785E+02 -.1966697E-01 -.1918818E+02 0.0000000E+00 2 H2O 0.4096719E+02 0.4895377E+02 -.7986584E+01 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.3217303E-01 -.1493827E-04 0.3218797E-01 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.3214753E-01 0.4044274E-04 -.3218797E-01 0.0000000E+00 7 Al+++ 0.3782457E+01 0.4689325E-05 0.3782452E+01 0.0000000E+00 8 H4SiO4 0.1207882E+02 0.1193500E-01 0.1206688E+02 0.0000000E+00 9 Ca++ 0.1334179E+01 0.2043933E-06 0.1334179E+01 0.0000000E+00 10 Mg++ 0.9206341E+00 0.8219447E-10 0.9206341E+00 0.0000000E+00 11 Fe++ 0.8270893E+00 0.3200635E-07 0.8270892E+00 0.0000000E+00 12 K+ 0.2462843E+00 0.1387154E-03 0.2461456E+00 0.0000000E+00 13 Na+ 0.1456241E+01 0.1967540E-01 0.1436566E+01 0.0000000E+00 14 Mn++ 0.2011275E-01 0.2214357E-08 0.2011275E-01 0.0000000E+00 15 HPO4-- 0.6864383E-02 0.4093710E-07 0.6864342E-02 0.0000000E+00 Chg. balance for solid moles: 0.2793E-14 Mass of aqueous solution: 0.883508E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 1159.9990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 1.435 0.157 376.4 2.576 29.70 144.5 andradite 0.1288 -0.890 65.43 1.816 5.164 17.00 grossular 0.3118E-01 -1.506 14.05 1.148 1.109 3.908 apatite-OH 0.2288E-02 -2.641 1.149 0.060 0.9071E-01 0.3652 clinochlore 0.1658 -0.780 92.14 1.964 7.272 35.05 daphnite 0.4799E-01 -1.319 34.24 1.535 2.702 10.38 chlorite-Mn 0.4023E-02 -2.395 2.852 0.455 0.2251 0.9088 diopside 0.5383E-01 -1.269 11.66 1.067 0.9201 3.563 hedenbergite 0.1396E-01 -1.855 3.464 0.540 0.2733 0.9487 microcline 0.2159 -0.666 60.09 1.779 4.742 23.47 stilbite 0.7542 -0.123 531.5 2.726 41.95 247.9 stilpnomelane-Fe 0.6052E-01 -1.218 65.24 1.815 5.149 22.54 tr.625ac.25prg.125 0.1047E-01 -1.980 8.946 0.952 0.7060 2.879 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8050E+00 0.8050E+00 1.0000 -0.094 grossular 0.1950E+00 0.1950E+00 1.0000 -0.710 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.7612E+00 0.7612E+00 1.0000 -0.119 daphnite 0.2203E+00 0.2203E+00 1.0000 -0.657 chlorite-Mn 0.1847E-01 0.1847E-01 1.0000 -1.734 diopside 0.7941E+00 0.7941E+00 1.0000 -0.100 hedenbergite 0.2059E+00 0.2059E+00 1.0000 -0.686 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 tr.625ac.25prg.125 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 1267.112358 g Volume = 513.380194 cm3 Porosity: -10.4044% V(tot) - V(min): -.48381E+02 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 1159.9990000 g log = 3.0645 Original solution: 1000.0103000 g Original solution / Rock added: 0.86 (Water/Rock Ratio), log = -0.0645 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0563 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9664E+00 0.9855 0.1006E+01 0.1021E+01 CO2,gas 0.3622E-08 1.0069 0.3852E-08 0.3826E-08 CH4,gas 0.1924E-01 1.0124 0.2058E-01 0.2033E-01 H2,gas 0.1439E-01 1.0006 0.1521E-01 0.1520E-01 H2S,gas 0.1447E-06 0.9959 0.1522E-06 0.1529E-06 S2,gas 0.3560E-29 1.0000 0.3761E-29 0.3761E-29 CO,gas 0.1478E-13 1.0000 0.1562E-13 0.1562E-13 SO3,gas 0.7508E-48 1.0000 0.7931E-48 0.7931E-48 SO2,gas 0.4443E-27 1.0000 0.4693E-27 0.4693E-27 HCl,gas 0.2954E-17 1.0000 0.3120E-17 0.3120E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 16 albite -0.38 -0.38 0.00 0.000 -0.94784E-12 22 andradite 39.01 39.01 0.00 0.000 0.24265E-10 23 grossular 32.73 32.73 0.00 0.000 0.00000E+00 32 apatite-OH -18.15 -18.15 0.00 0.000 -0.60662E-11 46 clinochlore 39.07 39.07 0.00 0.000 0.00000E+00 47 daphnite 28.97 28.97 0.00 0.000 0.60662E-11 48 chlorite-Mn 46.87 46.87 0.00 0.000 0.12132E-10 67 diopside 16.18 16.18 0.00 0.000 0.00000E+00 68 hedenbergite 14.21 14.21 0.00 0.000 0.00000E+00 116 microcline -2.49 -2.49 0.00 0.000 0.15165E-11 163 stilbite -7.52 -7.52 0.00 0.000 0.15165E-10 164 stilpnomelane-Fe 13.02 13.02 0.00 0.000 0.21232E-10 245 tr.625ac.25prg.125 45.16 45.16 0.00 0.000 0.00000E+00 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -16.77 -10.11 -3.371 0.17268E+05 -8.414 3 CH4,gas 4.54 1.16 -3.39 -0.846 0.57806E+04 -1.687 4 H2,gas 8.00 4.48 -3.52 -2.010 0.60050E+04 -1.818 5 H2S,gas -6.23 -14.75 -8.52 -4.258 0.14542E+05 -6.817 6 S2,gas -7.34 -38.46 -31.12 -4.788 0.53143E+05 -29.425 7 CO,gas 3.21 -12.29 -15.51 -4.771 0.26475E+05 -13.806 8 SO3,gas 17.12 -32.68 -49.80 -12.450 0.85032E+05 -48.101 9 SO2,gas 0.83 -28.20 -29.03 -7.741 0.49564E+05 -27.329 10 HCl,gas 5.19 -14.02 -19.20 -9.602 0.32792E+05 -17.506 11 acmite 7.71 6.53 -1.18 -0.123 0.20177E+04 15 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 19 spessartine 24.46 19.72 -4.73 -0.237 0.80839E+04 20 analcite 3.32 2.77 -0.55 -0.061 0.93620E+03 26 annite 20.12 17.72 -2.40 -0.134 0.41063E+04 27 phlogopite 27.06 25.40 -1.67 -0.093 0.28488E+04 29 anorthite 12.71 8.27 -4.45 -0.342 0.75901E+04 35 aragonite 0.97 -3.67 -4.64 -1.546 0.79193E+04 36 brucite 12.57 9.29 -3.27 -0.655 0.55908E+04 37 calcite 0.81 -3.67 -4.48 -1.494 0.76551E+04 38 carnegieite-low 9.02 5.93 -3.09 -0.442 0.52800E+04 39 carnegieite-high 10.09 5.93 -4.16 -0.595 0.71070E+04 40 carpholite-Mg 8.58 4.46 -4.12 -0.275 0.70426E+04 41 carpholite-Fe 6.71 1.90 -4.81 -0.321 0.82204E+04 42 celadonite 5.34 3.65 -1.69 -0.099 0.28879E+04 43 celadonite-Fe 3.88 1.09 -2.79 -0.164 0.47561E+04 44 chrysotile 23.89 21.57 -2.32 -0.194 0.39692E+04 49 chlorite-Al-free 47.17 43.14 -4.04 -0.168 0.68935E+04 51 chloritoid-Fe 9.17 5.06 -4.12 -0.275 0.70313E+04 52 chloritoid-Mn 11.40 7.56 -3.84 -0.256 0.65590E+04 54 coesite -2.38 -3.16 -0.78 -0.260 0.13342E+04 61 cristobalite -2.56 -3.16 -0.60 -0.199 0.10195E+04 63 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71234E+04 65 diaspore 2.87 0.74 -2.13 -0.356 0.36448E+04 66 diamond -3.10 -7.81 -4.71 -1.344 0.80340E+04 71 enstatite 17.26 12.27 -4.99 -0.499 0.85225E+04 73 clinoenstatite 17.17 12.27 -4.89 -0.489 0.83541E+04 75 epidote 24.67 22.70 -1.97 -0.095 0.33583E+04 76 clinozoisite 22.81 18.95 -3.86 -0.175 0.65864E+04 77 epidote-Fe 29.84 26.46 -3.38 -0.176 0.57768E+04 78 fayalite 14.05 10.31 -3.73 -0.533 0.63743E+04 79 ferrosilite 11.15 7.16 -3.99 -0.399 0.68202E+04 83 gibbsite 4.08 0.74 -3.34 -0.477 0.57034E+04 84 glaucophane 22.97 20.80 -2.17 -0.059 0.37133E+04 85 glaucophane-Fe 17.28 13.12 -4.15 -0.112 0.70919E+04 86 graphite -3.55 -7.81 -4.26 -1.218 0.72762E+04 87 greenalite 16.14 13.89 -2.25 -0.187 0.38408E+04 90 hematite 12.57 8.99 -3.58 -0.434 0.61112E+04 91 heulandite -5.83 -7.52 -1.69 -0.077 0.28938E+04 95 jadeite 4.22 2.77 -1.44 -0.144 0.24617E+04 97 kalsilite 7.58 3.83 -3.76 -0.537 0.64125E+04 98 kaolinite -1.33 -4.84 -3.50 -0.319 0.59829E+04 101 laumontite 2.88 1.95 -0.93 -0.062 0.15933E+04 102 lawsonite 9.62 8.27 -1.35 -0.090 0.23067E+04 103 leucite 4.12 0.67 -3.45 -0.345 0.58872E+04 105 lizardite 23.24 21.57 -1.68 -0.140 0.28618E+04 107 magnetite 20.09 15.72 -4.37 -0.356 0.74537E+04 108 minnesotaite 10.39 7.58 -2.81 -0.165 0.48029E+04 112 manganosite 14.06 9.24 -4.82 -1.205 0.82285E+04 120 muscovite 2.58 -1.01 -3.59 -0.211 0.61312E+04 121 paragonite 4.24 1.09 -3.15 -0.185 0.53703E+04 122 nepheline 8.34 5.93 -2.41 -0.344 0.41124E+04 128 periclase-Fe 11.63 6.73 -4.89 -1.223 0.83523E+04 134 phlogopite-Na 29.65 27.50 -2.15 -0.119 0.36676E+04 136 prehnite 19.37 18.21 -1.16 -0.068 0.19847E+04 137 prehnite-Fe 22.50 21.96 -0.53 -0.032 0.91152E+03 138 pumpellyite-Fe 46.27 43.89 -2.38 -0.053 0.40574E+04 139 pumpellyite-Mg 48.99 46.45 -2.54 -0.056 0.43412E+04 143 pyrrhotite -4.26 -8.01 -3.75 -1.250 0.64054E+04 144 pyrrhotiteFe0.875 -6.02 -9.41 -3.39 -1.248 0.57926E+04 145 pyroxmangite 7.40 6.08 -1.32 -0.263 0.22489E+04 146 pyrophyllite -6.18 -11.15 -4.98 -0.311 0.84961E+04 147 quartz -2.99 -3.16 -0.17 -0.056 0.28685E+03 152 rhodonite 7.45 6.08 -1.36 -0.273 0.23291E+04 153 sanidine -1.28 -2.49 -1.21 -0.093 0.20677E+04 165 stilpnomelane-Mg 27.44 25.81 -1.63 -0.049 0.27802E+04 171 talc 16.49 15.25 -1.24 -0.073 0.21141E+04 174 tephroite 18.09 15.32 -2.77 -0.395 0.47214E+04 178 tridymite -2.63 -3.16 -0.53 -0.177 0.90683E+03 179 tremolite 47.87 47.42 -0.45 -0.012 0.77496E+03 180 ferroactinolite 38.45 34.62 -3.83 -0.104 0.65450E+04 181 troilite-low -4.41 -8.01 -3.60 -1.200 0.61482E+04 183 vesuvianite 223.47 218.82 -4.65 -0.036 0.79419E+04 187 wairakite 3.95 1.95 -2.00 -0.118 0.34153E+04 188 walstromite 11.51 9.94 -1.56 -0.313 0.26719E+04 189 wollastonite 10.46 9.94 -0.52 -0.103 0.88229E+03 190 pseudo-wollastonite 11.00 9.94 -1.06 -0.211 0.18021E+04 191 zoisite 22.85 18.95 -3.90 -0.177 0.66605E+04 192 akaganeite 7.75 4.49 -3.26 -0.705 0.55681E+04 199 chalcedony -2.80 -3.16 -0.35 -0.118 0.60615E+03 201 montmorillonite-Ca -2.29 -6.17 -3.88 -0.240 0.66180E+04 202 montmorillonite-K -2.24 -6.27 -4.03 -0.247 0.68816E+04 203 montmorillonite-Mg -2.48 -6.79 -4.31 -0.267 0.73677E+04 204 montmorillonite-Na -2.04 -5.57 -3.54 -0.216 0.60365E+04 205 nontronite-Ca 3.21 -0.20 -3.41 -0.221 0.58217E+04 206 nontronite-H 2.53 -2.36 -4.89 -0.328 0.83487E+04 207 nontronite-K 3.34 -0.30 -3.64 -0.233 0.62085E+04 208 nontronite-Mg 3.07 -0.82 -3.90 -0.253 0.66555E+04 209 nontronite-Na 3.52 0.40 -3.12 -0.200 0.53294E+04 224 tobermorite 9.82 7.76 -2.07 -0.564 0.35287E+04 230 alabandite -0.98 -5.51 -4.53 -1.510 0.77345E+04 233 boehmite 4.41 0.74 -3.67 -0.611 0.62618E+04 235 ferrous-oxide 9.81 6.73 -3.08 -0.769 0.52532E+04 240 silica-amorphous -2.09 -3.16 -1.07 -0.355 0.18203E+04 242 an20ab80 2.02 1.35 -0.67 -0.052 0.11472E+04 243 an25ab75 2.65 1.78 -0.87 -0.067 0.14809E+04 244 an30ab70 3.28 2.21 -1.07 -0.082 0.18243E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 40.0000000 g Current total amount of reactant added: 1159.9990000 g New total amount of reactant added: 1199.9990000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.3297E-10 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 11 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 1199.9990000 Water: Moles liquid = 0.4873E+02 kg liquid = 0.8780E+00 Moles total = 0.4047E+02 kg total = 0.7290E+00 Activity = 1.0000 Stoichiometric ionic strength = .1133338E-01 Osmotic coef. = 0.9693 True ionic strength = .2002024E-01 Chg. balance for total moles = 0.3297E-10 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.88301E-10 -10.0540 0.74195E-10 -10.1296 0.84025E+00 -0.0756 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.15644E-03 -3.8057 0.13065E-03 -3.8839 0.83519E+00 -0.0782 4 SO4-- 0.73717E-12 -12.1324 0.38281E-12 -12.4170 0.51929E+00 -0.2846 5 HCO3- 0.27279E-06 -6.5642 0.22817E-06 -6.6417 0.83641E+00 -0.0776 6 HS- 0.29044E-04 -4.5369 0.24261E-04 -4.6151 0.83532E+00 -0.0781 7 Al+++ 0.96946E-29 -29.0135 0.22396E-29 -29.6498 0.23102E+00 -0.6364 8 H4SiO4 0.69593E-03 -3.1574 0.69593E-03 -3.1574 0.10000E+01 0.0000 9 Ca++ 0.13502E-06 -6.8696 0.69600E-07 -7.1574 0.51548E+00 -0.2878 10 Mg++ 0.21123E-10 -10.6752 0.10839E-10 -10.9650 0.51312E+00 -0.2898 11 Fe++ 0.58215E-13 -13.2350 0.29904E-13 -13.5243 0.51369E+00 -0.2893 12 K+ 0.15653E-03 -3.8054 0.13095E-03 -3.8829 0.83661E+00 -0.0775 13 Na+ 0.19863E-01 -1.7020 0.16586E-01 -1.7803 0.83504E+00 -0.0783 14 Mn++ 0.18571E-10 -10.7312 0.95474E-11 -11.0201 0.51411E+00 -0.2889 15 HPO4-- 0.45309E-07 -7.3438 0.23532E-07 -7.6283 0.51937E+00 -0.2845 16 HSiO3- 0.10487E-01 -1.9794 0.87583E-02 -2.0576 0.83519E+00 -0.0782 17 Ca(HSiO3)+ 0.16590E-07 -7.7802 0.13882E-07 -7.8575 0.83679E+00 -0.0774 18 Mg(HSiO3)+ 0.32152E-11 -11.4928 0.26905E-11 -11.5702 0.83679E+00 -0.0774 19 NaHSiO3,aq 0.23495E-02 -2.6290 0.23495E-02 -2.6290 0.10000E+01 0.0000 20 AlO+ 0.66144E-16 -16.1795 0.55349E-16 -16.2569 0.83679E+00 -0.0774 22 HAlO2,aq 0.14856E-09 -9.8281 0.14856E-09 -9.8281 0.10000E+01 0.0000 23 AlO2- 0.53166E-05 -5.2744 0.44323E-05 -5.3534 0.83369E+00 -0.0790 24 CH4,aq 0.14095E-04 -4.8509 0.14047E-04 -4.8524 0.99654E+00 -0.0015 25 C2H6,aq 0.29219E-14 -14.5343 0.29118E-14 -14.5358 0.99654E+00 -0.0015 29 CO,aq 0.10527E-16 -16.9777 0.10527E-16 -16.9777 0.10000E+01 0.0000 30 CO2,aq 0.36298E-10 -10.4401 0.36173E-10 -10.4416 0.99654E+00 -0.0015 31 CO3-2 0.51836E-06 -6.2854 0.26861E-06 -6.5709 0.51819E+00 -0.2855 32 CaCO3,aq 0.23442E-09 -9.6300 0.23442E-09 -9.6300 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.48442E-12 -12.3148 0.40536E-12 -12.3922 0.83679E+00 -0.0774 34 CaCl+ 0.17586E-10 -10.7548 0.14716E-10 -10.8322 0.83679E+00 -0.0774 35 CaCl2,aq 0.45679E-15 -15.3403 0.45679E-15 -15.3403 0.10000E+01 0.0000 36 CaOH+ 0.79895E-07 -7.0975 0.66855E-07 -7.1749 0.83679E+00 -0.0774 37 CaSO4,aq 0.84604E-17 -17.0726 0.84604E-17 -17.0726 0.10000E+01 0.0000 38 HCl,aq 0.17764E-14 -14.7505 0.17764E-14 -14.7505 0.10000E+01 0.0000 43 FeCl+ 0.73905E-17 -17.1313 0.61843E-17 -17.2087 0.83679E+00 -0.0774 46 FeO,aq 0.21113E-09 -9.6754 0.21113E-09 -9.6754 0.10000E+01 0.0000 47 FeOH+ 0.15679E-10 -10.8047 0.13120E-10 -10.8821 0.83679E+00 -0.0774 48 HFeO2- 0.35649E-07 -7.4479 0.29774E-07 -7.5262 0.83519E+00 -0.0782 49 FeO+ 0.10987E-16 -16.9591 0.91942E-17 -17.0365 0.83679E+00 -0.0774 51 FeO2- 0.40919E-09 -9.3881 0.34176E-09 -9.4663 0.83519E+00 -0.0782 52 HFeO2,aq 0.32250E-11 -11.4915 0.32250E-11 -11.4915 0.10000E+01 0.0000 53 H2,aq 0.11625E-04 -4.9346 0.11584E-04 -4.9361 0.99654E+00 -0.0015 54 KCl,aq 0.31010E-09 -9.5085 0.31010E-09 -9.5085 0.10000E+01 0.0000 56 KOH,aq 0.75375E-06 -6.1228 0.75375E-06 -6.1228 0.10000E+01 0.0000 57 KSO4- 0.93139E-15 -15.0309 0.77789E-15 -15.1091 0.83519E+00 -0.0782 58 MgCO3,aq 0.91503E-14 -14.0386 0.91503E-14 -14.0386 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.77084E-16 -16.1130 0.64503E-16 -16.1904 0.83679E+00 -0.0774 60 MgCl+ 0.24822E-14 -14.6052 0.20771E-14 -14.6825 0.83679E+00 -0.0774 61 MgOH+ 0.68847E-10 -10.1621 0.57611E-10 -10.2395 0.83679E+00 -0.0774 63 MnO,aq 0.17961E-08 -8.7457 0.17961E-08 -8.7457 0.10000E+01 0.0000 64 MnOH+ 0.46501E-09 -9.3325 0.38911E-09 -9.4099 0.83679E+00 -0.0774 65 MnO2-2 0.20896E-10 -10.6799 0.10828E-10 -10.9654 0.51819E+00 -0.2855 66 HMnO2- 0.21074E-09 -9.6762 0.17601E-09 -9.7545 0.83519E+00 -0.0782 69 MnCl+ 0.91797E-14 -14.0372 0.76815E-14 -14.1146 0.83679E+00 -0.0774 71 NaCl,aq 0.71816E-06 -6.1438 0.71816E-06 -6.1438 0.10000E+01 0.0000 72 NaOH,aq 0.96047E-04 -4.0175 0.96047E-04 -4.0175 0.10000E+01 0.0000 74 OH- 0.93407E-02 -2.0296 0.77872E-02 -2.1086 0.83369E+00 -0.0790 79 HPO3-2 0.16394E-14 -14.7853 0.84952E-15 -15.0708 0.51819E+00 -0.2855 81 H2PO3- 0.15134E-18 -18.8201 0.12639E-18 -18.8983 0.83519E+00 -0.0782 82 H3PO4,aq 0.90600E-18 -18.0429 0.90600E-18 -18.0429 0.10000E+01 0.0000 83 H2PO4- 0.38527E-10 -10.4142 0.32208E-10 -10.4920 0.83598E+00 -0.0778 84 PO4-3 0.10665E-08 -8.9720 0.25877E-09 -9.5871 0.24264E+00 -0.6150 88 HP2O7-3 0.94661E-18 -18.0238 0.21890E-18 -18.6597 0.23125E+00 -0.6359 89 P2O7-4 0.91419E-17 -17.0390 0.70484E-18 -18.1519 0.77100E-01 -1.1129 90 H2S,aq 0.55826E-08 -8.2532 0.55633E-08 -8.2547 0.99654E+00 -0.0015 91 S2-2 0.21727E-14 -14.6630 0.11259E-14 -14.9485 0.51819E+00 -0.2855 97 SO3-2 0.10962E-17 -17.9601 0.57627E-18 -18.2394 0.52569E+00 -0.2793 99 HSO4- 0.32678E-19 -19.4857 0.27372E-19 -19.5627 0.83761E+00 -0.0770 Charge balance for all species = 0.3758E-10 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.8830135E-10 -.2229849E-01 -.2243648E+02 0.0000 2 H2O 0.1000000E+01 0.5550489E+02 0.9981994E+06 0.0000 3 Cl- 0.1564355E-03 0.1571540E-03 0.5561898E+01 6.2457 4 SO4-- 0.7371653E-12 -.1700153E-04 -.1630356E+01 7.8422 5 HCO3- 0.2727920E-06 0.1488686E-04 0.9067762E+00 3.4879 6 HS- 0.2904427E-04 0.4605138E-04 0.1520364E+01 5.5145 7 Al+++ 0.9694647E-29 0.5316705E-05 0.1432034E+00 0.7391 8 H4SiO4 0.6959326E-03 0.1353199E-01 0.1298372E+04 -3.1574 9 Ca++ 0.1350183E-06 0.2317554E-06 0.9272150E-02 13.1019 10 Mg++ 0.2112279E-10 0.9319685E-10 0.2261864E-05 9.2942 11 Fe++ 0.5821535E-13 0.3628873E-07 0.2023095E-02 6.7350 12 K+ 0.1565283E-03 0.1572823E-03 0.6139365E+01 6.2467 13 Na+ 0.1986265E-01 0.2230890E-01 0.5119857E+03 8.3494 14 Mn++ 0.1857073E-10 0.2511331E-08 0.1377277E-03 9.2391 15 HPO4-- 0.4530884E-07 0.4641386E-07 0.4447014E-02 12.6309 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.1987019E+02 -.1957707E-01 -.1985061E+02 0.0000000E+00 2 H2O 0.4046577E+02 0.4873080E+02 -.8265034E+01 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.3328157E-01 -.1492658E-04 0.3329649E-01 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.3325606E-01 0.4043105E-04 -.3329649E-01 0.0000000E+00 7 Al+++ 0.3912887E+01 0.4667829E-05 0.3912882E+01 0.0000000E+00 8 H4SiO4 0.1249533E+02 0.1188048E-01 0.1248345E+02 0.0000000E+00 9 Ca++ 0.1380185E+01 0.2034708E-06 0.1380184E+01 0.0000000E+00 10 Mg++ 0.9523802E+00 0.8182266E-10 0.9523802E+00 0.0000000E+00 11 Fe++ 0.8556096E+00 0.3185988E-07 0.8556096E+00 0.0000000E+00 12 K+ 0.2547769E+00 0.1380868E-03 0.2546388E+00 0.0000000E+00 13 Na+ 0.1506451E+01 0.1958621E-01 0.1486865E+01 0.0000000E+00 14 Mn++ 0.2080630E-01 0.2204836E-08 0.2080630E-01 0.0000000E+00 15 HPO4-- 0.7101086E-02 0.4074929E-07 0.7101045E-02 0.0000000E+00 Chg. balance for solid moles: 0.1985E-14 Mass of aqueous solution: 0.879484E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 1199.9990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 1.486 0.172 389.5 2.591 29.72 149.5 andradite 0.1332 -0.876 67.68 1.830 5.163 17.58 grossular 0.3226E-01 -1.491 14.53 1.162 1.109 4.043 apatite-OH 0.2367E-02 -2.626 1.189 0.075 0.9071E-01 0.3778 clinochlore 0.1714 -0.766 95.29 1.979 7.270 36.25 daphnite 0.4963E-01 -1.304 35.41 1.549 2.701 10.73 chlorite-Mn 0.4161E-02 -2.381 2.950 0.470 0.2251 0.9402 diopside 0.5601E-01 -1.252 12.13 1.084 0.9253 3.707 hedenbergite 0.1452E-01 -1.838 3.604 0.557 0.2749 0.9870 microcline 0.2233 -0.651 62.16 1.794 4.742 24.28 stilbite 0.7799 -0.108 549.6 2.740 41.93 256.3 stilpnomelane-Fe 0.6261E-01 -1.203 67.50 1.829 5.149 23.31 tr.625ac.25prg.125 0.1080E-01 -1.967 9.231 0.965 0.7042 2.971 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8050E+00 0.8050E+00 1.0000 -0.094 grossular 0.1950E+00 0.1950E+00 1.0000 -0.710 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.7612E+00 0.7612E+00 1.0000 -0.119 daphnite 0.2203E+00 0.2203E+00 1.0000 -0.657 chlorite-Mn 0.1848E-01 0.1848E-01 1.0000 -1.733 diopside 0.7941E+00 0.7941E+00 1.0000 -0.100 hedenbergite 0.2059E+00 0.2059E+00 1.0000 -0.686 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 tr.625ac.25prg.125 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 1310.812623 g Volume = 531.061419 cm3 Porosity: -10.4079% V(tot) - V(min): -.50062E+02 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 1199.9990000 g log = 3.0792 Original solution: 1000.0103000 g Original solution / Rock added: 0.83 (Water/Rock Ratio), log = -0.0792 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0564 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9663E+00 0.9855 0.1006E+01 0.1021E+01 CO2,gas 0.3638E-08 1.0069 0.3870E-08 0.3844E-08 CH4,gas 0.1933E-01 1.0124 0.2068E-01 0.2042E-01 H2,gas 0.1439E-01 1.0006 0.1521E-01 0.1520E-01 H2S,gas 0.1454E-06 0.9959 0.1529E-06 0.1536E-06 S2,gas 0.3593E-29 1.0000 0.3795E-29 0.3795E-29 CO,gas 0.1485E-13 1.0000 0.1569E-13 0.1569E-13 SO3,gas 0.7542E-48 1.0000 0.7968E-48 0.7968E-48 SO2,gas 0.4463E-27 1.0000 0.4715E-27 0.4715E-27 HCl,gas 0.2967E-17 1.0000 0.3134E-17 0.3134E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 16 albite -0.38 -0.38 0.00 0.000 -0.13080E-10 22 andradite 39.01 39.01 0.00 0.000 -0.12132E-10 23 grossular 32.73 32.73 0.00 0.000 0.24265E-10 32 apatite-OH -18.15 -18.15 0.00 0.000 -0.60662E-11 46 clinochlore 39.07 39.07 0.00 0.000 0.12132E-10 47 daphnite 28.97 28.97 0.00 0.000 -0.48529E-10 48 chlorite-Mn 46.87 46.87 0.00 0.000 0.00000E+00 67 diopside 16.18 16.18 0.00 0.000 -0.60662E-11 68 hedenbergite 14.21 14.21 0.00 0.000 -0.90992E-11 116 microcline -2.49 -2.49 0.00 0.000 -0.10616E-10 163 stilbite -7.52 -7.52 0.00 0.000 0.15165E-10 164 stilpnomelane-Fe 13.02 13.02 0.00 0.000 -0.27298E-10 245 tr.625ac.25prg.125 45.16 45.16 0.00 0.000 0.00000E+00 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -16.77 -10.11 -3.370 0.17265E+05 -8.412 3 CH4,gas 4.54 1.16 -3.38 -0.846 0.57772E+04 -1.685 4 H2,gas 8.00 4.48 -3.52 -2.010 0.60050E+04 -1.818 5 H2S,gas -6.23 -14.74 -8.51 -4.257 0.14538E+05 -6.816 6 S2,gas -7.34 -38.46 -31.12 -4.788 0.53136E+05 -29.421 7 CO,gas 3.21 -12.29 -15.50 -4.770 0.26472E+05 -13.804 8 SO3,gas 17.12 -32.68 -49.80 -12.449 0.85028E+05 -48.099 9 SO2,gas 0.83 -28.19 -29.03 -7.740 0.49560E+05 -27.327 10 HCl,gas 5.19 -14.01 -19.20 -9.601 0.32788E+05 -17.504 11 acmite 7.71 6.53 -1.18 -0.123 0.20177E+04 15 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 19 spessartine 24.46 19.72 -4.73 -0.237 0.80833E+04 20 analcite 3.32 2.77 -0.55 -0.061 0.93620E+03 26 annite 20.12 17.72 -2.40 -0.134 0.41063E+04 27 phlogopite 27.06 25.40 -1.67 -0.093 0.28488E+04 29 anorthite 12.71 8.27 -4.45 -0.342 0.75901E+04 35 aragonite 0.97 -3.67 -4.64 -1.545 0.79159E+04 36 brucite 12.57 9.29 -3.27 -0.655 0.55908E+04 37 calcite 0.81 -3.67 -4.48 -1.494 0.76517E+04 38 carnegieite-low 9.02 5.93 -3.09 -0.442 0.52800E+04 39 carnegieite-high 10.09 5.93 -4.16 -0.595 0.71070E+04 40 carpholite-Mg 8.58 4.46 -4.12 -0.275 0.70427E+04 41 carpholite-Fe 6.71 1.90 -4.81 -0.321 0.82205E+04 42 celadonite 5.34 3.65 -1.69 -0.099 0.28879E+04 43 celadonite-Fe 3.88 1.09 -2.79 -0.164 0.47561E+04 44 chrysotile 23.89 21.57 -2.32 -0.194 0.39692E+04 49 chlorite-Al-free 47.17 43.14 -4.04 -0.168 0.68935E+04 51 chloritoid-Fe 9.17 5.06 -4.12 -0.275 0.70313E+04 52 chloritoid-Mn 11.40 7.56 -3.84 -0.256 0.65588E+04 54 coesite -2.38 -3.16 -0.78 -0.260 0.13342E+04 61 cristobalite -2.56 -3.16 -0.60 -0.199 0.10195E+04 63 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71234E+04 65 diaspore 2.87 0.74 -2.13 -0.356 0.36448E+04 66 diamond -3.10 -7.81 -4.70 -1.344 0.80306E+04 71 enstatite 17.26 12.27 -4.99 -0.499 0.85225E+04 73 clinoenstatite 17.17 12.27 -4.89 -0.489 0.83541E+04 75 epidote 24.67 22.70 -1.97 -0.095 0.33583E+04 76 clinozoisite 22.81 18.95 -3.86 -0.175 0.65865E+04 77 epidote-Fe 29.84 26.46 -3.38 -0.176 0.57768E+04 78 fayalite 14.05 10.31 -3.73 -0.533 0.63743E+04 79 ferrosilite 11.15 7.16 -3.99 -0.399 0.68202E+04 83 gibbsite 4.08 0.74 -3.34 -0.477 0.57034E+04 84 glaucophane 22.97 20.80 -2.17 -0.059 0.37133E+04 85 glaucophane-Fe 17.28 13.12 -4.15 -0.112 0.70919E+04 86 graphite -3.55 -7.81 -4.26 -1.217 0.72728E+04 87 greenalite 16.14 13.89 -2.25 -0.187 0.38408E+04 90 hematite 12.57 8.99 -3.58 -0.434 0.61112E+04 91 heulandite -5.83 -7.52 -1.69 -0.077 0.28938E+04 95 jadeite 4.22 2.77 -1.44 -0.144 0.24617E+04 97 kalsilite 7.58 3.83 -3.76 -0.537 0.64125E+04 98 kaolinite -1.33 -4.84 -3.50 -0.319 0.59829E+04 101 laumontite 2.88 1.95 -0.93 -0.062 0.15934E+04 102 lawsonite 9.62 8.27 -1.35 -0.090 0.23067E+04 103 leucite 4.12 0.67 -3.45 -0.345 0.58872E+04 105 lizardite 23.24 21.57 -1.68 -0.140 0.28618E+04 107 magnetite 20.09 15.72 -4.37 -0.356 0.74537E+04 108 minnesotaite 10.39 7.58 -2.81 -0.165 0.48029E+04 112 manganosite 14.06 9.24 -4.82 -1.205 0.82283E+04 120 muscovite 2.58 -1.01 -3.59 -0.211 0.61312E+04 121 paragonite 4.24 1.09 -3.15 -0.185 0.53703E+04 122 nepheline 8.34 5.93 -2.41 -0.344 0.41124E+04 128 periclase-Fe 11.63 6.73 -4.89 -1.223 0.83523E+04 134 phlogopite-Na 29.65 27.50 -2.15 -0.119 0.36676E+04 136 prehnite 19.37 18.21 -1.16 -0.068 0.19847E+04 137 prehnite-Fe 22.50 21.96 -0.53 -0.032 0.91152E+03 138 pumpellyite-Fe 46.27 43.89 -2.38 -0.053 0.40575E+04 139 pumpellyite-Mg 48.99 46.45 -2.54 -0.057 0.43413E+04 143 pyrrhotite -4.26 -8.01 -3.75 -1.250 0.64020E+04 144 pyrrhotiteFe0.875 -6.02 -9.41 -3.39 -1.247 0.57892E+04 145 pyroxmangite 7.40 6.08 -1.32 -0.263 0.22487E+04 146 pyrophyllite -6.18 -11.15 -4.98 -0.311 0.84961E+04 147 quartz -2.99 -3.16 -0.17 -0.056 0.28685E+03 152 rhodonite 7.45 6.08 -1.36 -0.273 0.23289E+04 153 sanidine -1.28 -2.49 -1.21 -0.093 0.20677E+04 165 stilpnomelane-Mg 27.44 25.81 -1.63 -0.049 0.27802E+04 171 talc 16.49 15.25 -1.24 -0.073 0.21141E+04 174 tephroite 18.09 15.32 -2.76 -0.395 0.47211E+04 178 tridymite -2.63 -3.16 -0.53 -0.177 0.90683E+03 179 tremolite 47.87 47.42 -0.45 -0.012 0.77496E+03 180 ferroactinolite 38.45 34.62 -3.83 -0.104 0.65450E+04 181 troilite-low -4.41 -8.01 -3.60 -1.200 0.61448E+04 183 vesuvianite 223.47 218.82 -4.65 -0.036 0.79420E+04 187 wairakite 3.95 1.95 -2.00 -0.118 0.34153E+04 188 walstromite 11.51 9.94 -1.56 -0.313 0.26719E+04 189 wollastonite 10.46 9.94 -0.52 -0.103 0.88229E+03 190 pseudo-wollastonite 11.00 9.94 -1.06 -0.211 0.18021E+04 191 zoisite 22.85 18.95 -3.90 -0.177 0.66605E+04 192 akaganeite 7.75 4.49 -3.26 -0.705 0.55681E+04 199 chalcedony -2.80 -3.16 -0.35 -0.118 0.60615E+03 201 montmorillonite-Ca -2.29 -6.17 -3.88 -0.240 0.66180E+04 202 montmorillonite-K -2.24 -6.27 -4.03 -0.247 0.68816E+04 203 montmorillonite-Mg -2.48 -6.79 -4.31 -0.267 0.73677E+04 204 montmorillonite-Na -2.04 -5.57 -3.54 -0.216 0.60365E+04 205 nontronite-Ca 3.21 -0.19 -3.41 -0.221 0.58217E+04 206 nontronite-H 2.53 -2.36 -4.89 -0.328 0.83487E+04 207 nontronite-K 3.34 -0.30 -3.64 -0.233 0.62085E+04 208 nontronite-Mg 3.07 -0.82 -3.90 -0.253 0.66555E+04 209 nontronite-Na 3.52 0.40 -3.12 -0.200 0.53294E+04 224 tobermorite 9.82 7.76 -2.07 -0.564 0.35287E+04 230 alabandite -0.98 -5.51 -4.53 -1.509 0.77309E+04 233 boehmite 4.41 0.74 -3.67 -0.611 0.62618E+04 235 ferrous-oxide 9.81 6.73 -3.08 -0.769 0.52532E+04 240 silica-amorphous -2.09 -3.16 -1.07 -0.355 0.18203E+04 242 an20ab80 2.02 1.35 -0.67 -0.052 0.11472E+04 243 an25ab75 2.65 1.78 -0.87 -0.067 0.14809E+04 244 an30ab70 3.28 2.21 -1.07 -0.082 0.18243E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 40.0000000 g Current total amount of reactant added: 1199.9990000 g New total amount of reactant added: 1239.9990000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.3297E-10 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 11 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 1239.9990000 Water: Moles liquid = 0.4851E+02 kg liquid = 0.8739E+00 Moles total = 0.3996E+02 kg total = 0.7200E+00 Activity = 1.0000 Stoichiometric ionic strength = .1133399E-01 Osmotic coef. = 0.9693 True ionic strength = .2002072E-01 Chg. balance for total moles = 0.3297E-10 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.88303E-10 -10.0540 0.74197E-10 -10.1296 0.84024E+00 -0.0756 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.15715E-03 -3.8037 0.13125E-03 -3.8819 0.83519E+00 -0.0782 4 SO4-- 0.74056E-12 -12.1304 0.38457E-12 -12.4150 0.51929E+00 -0.2846 5 HCO3- 0.27405E-06 -6.5622 0.22922E-06 -6.6398 0.83641E+00 -0.0776 6 HS- 0.29178E-04 -4.5349 0.24373E-04 -4.6131 0.83531E+00 -0.0782 7 Al+++ 0.96954E-29 -29.0134 0.22398E-29 -29.6498 0.23102E+00 -0.6364 8 H4SiO4 0.69593E-03 -3.1574 0.69593E-03 -3.1574 0.10000E+01 0.0000 9 Ca++ 0.13502E-06 -6.8696 0.69602E-07 -7.1574 0.51548E+00 -0.2878 10 Mg++ 0.21124E-10 -10.6752 0.10839E-10 -10.9650 0.51312E+00 -0.2898 11 Fe++ 0.58218E-13 -13.2349 0.29906E-13 -13.5242 0.51368E+00 -0.2893 12 K+ 0.15653E-03 -3.8054 0.13096E-03 -3.8829 0.83661E+00 -0.0775 13 Na+ 0.19863E-01 -1.7020 0.16587E-01 -1.7802 0.83504E+00 -0.0783 14 Mn++ 0.18576E-10 -10.7310 0.95501E-11 -11.0200 0.51411E+00 -0.2889 15 HPO4-- 0.45307E-07 -7.3438 0.23531E-07 -7.6284 0.51936E+00 -0.2845 16 HSiO3- 0.10486E-01 -1.9794 0.87581E-02 -2.0576 0.83519E+00 -0.0782 17 Ca(HSiO3)+ 0.16590E-07 -7.7801 0.13883E-07 -7.8575 0.83679E+00 -0.0774 18 Mg(HSiO3)+ 0.32153E-11 -11.4928 0.26905E-11 -11.5702 0.83679E+00 -0.0774 19 NaHSiO3,aq 0.23495E-02 -2.6290 0.23495E-02 -2.6290 0.10000E+01 0.0000 20 AlO+ 0.66145E-16 -16.1795 0.55350E-16 -16.2569 0.83679E+00 -0.0774 22 HAlO2,aq 0.14856E-09 -9.8281 0.14856E-09 -9.8281 0.10000E+01 0.0000 23 AlO2- 0.53164E-05 -5.2744 0.44322E-05 -5.3534 0.83368E+00 -0.0790 24 CH4,aq 0.14160E-04 -4.8489 0.14111E-04 -4.8504 0.99654E+00 -0.0015 25 C2H6,aq 0.29488E-14 -14.5303 0.29386E-14 -14.5319 0.99654E+00 -0.0015 29 CO,aq 0.10575E-16 -16.9757 0.10575E-16 -16.9757 0.10000E+01 0.0000 30 CO2,aq 0.36466E-10 -10.4381 0.36340E-10 -10.4396 0.99654E+00 -0.0015 31 CO3-2 0.52074E-06 -6.2834 0.26984E-06 -6.5689 0.51819E+00 -0.2855 32 CaCO3,aq 0.23550E-09 -9.6280 0.23550E-09 -9.6280 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.48667E-12 -12.3128 0.40724E-12 -12.3901 0.83679E+00 -0.0774 34 CaCl+ 0.17668E-10 -10.7528 0.14784E-10 -10.8302 0.83679E+00 -0.0774 35 CaCl2,aq 0.46102E-15 -15.3363 0.46102E-15 -15.3363 0.10000E+01 0.0000 36 CaOH+ 0.79896E-07 -7.0975 0.66857E-07 -7.1749 0.83679E+00 -0.0774 37 CaSO4,aq 0.84997E-17 -17.0706 0.84997E-17 -17.0706 0.10000E+01 0.0000 38 HCl,aq 0.17846E-14 -14.7485 0.17846E-14 -14.7485 0.10000E+01 0.0000 43 FeCl+ 0.74248E-17 -17.1293 0.62130E-17 -17.2067 0.83679E+00 -0.0774 46 FeO,aq 0.21113E-09 -9.6754 0.21113E-09 -9.6754 0.10000E+01 0.0000 47 FeOH+ 0.15679E-10 -10.8047 0.13120E-10 -10.8821 0.83679E+00 -0.0774 48 HFeO2- 0.35649E-07 -7.4480 0.29773E-07 -7.5262 0.83519E+00 -0.0782 49 FeO+ 0.10988E-16 -16.9591 0.91945E-17 -17.0365 0.83679E+00 -0.0774 51 FeO2- 0.40919E-09 -9.3881 0.34175E-09 -9.4663 0.83519E+00 -0.0782 52 HFeO2,aq 0.32250E-11 -11.4915 0.32250E-11 -11.4915 0.10000E+01 0.0000 53 H2,aq 0.11624E-04 -4.9346 0.11584E-04 -4.9361 0.99654E+00 -0.0015 54 KCl,aq 0.31153E-09 -9.5065 0.31153E-09 -9.5065 0.10000E+01 0.0000 56 KOH,aq 0.75375E-06 -6.1228 0.75375E-06 -6.1228 0.10000E+01 0.0000 57 KSO4- 0.93570E-15 -15.0289 0.78149E-15 -15.1071 0.83519E+00 -0.0782 58 MgCO3,aq 0.91926E-14 -14.0366 0.91926E-14 -14.0366 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.77442E-16 -16.1110 0.64803E-16 -16.1884 0.83679E+00 -0.0774 60 MgCl+ 0.24937E-14 -14.6032 0.20867E-14 -14.6805 0.83679E+00 -0.0774 61 MgOH+ 0.68848E-10 -10.1621 0.57612E-10 -10.2395 0.83679E+00 -0.0774 63 MnO,aq 0.17965E-08 -8.7456 0.17965E-08 -8.7456 0.10000E+01 0.0000 64 MnOH+ 0.46513E-09 -9.3324 0.38922E-09 -9.4098 0.83679E+00 -0.0774 65 MnO2-2 0.20900E-10 -10.6798 0.10830E-10 -10.9654 0.51819E+00 -0.2855 66 HMnO2- 0.21079E-09 -9.6762 0.17605E-09 -9.7544 0.83519E+00 -0.0782 69 MnCl+ 0.92244E-14 -14.0351 0.77189E-14 -14.1124 0.83679E+00 -0.0774 71 NaCl,aq 0.72148E-06 -6.1418 0.72148E-06 -6.1418 0.10000E+01 0.0000 72 NaOH,aq 0.96047E-04 -4.0175 0.96047E-04 -4.0175 0.10000E+01 0.0000 74 OH- 0.93406E-02 -2.0296 0.77871E-02 -2.1086 0.83368E+00 -0.0790 79 HPO3-2 0.16393E-14 -14.7853 0.84948E-15 -15.0708 0.51819E+00 -0.2855 81 H2PO3- 0.15133E-18 -18.8201 0.12639E-18 -18.8983 0.83519E+00 -0.0782 82 H3PO4,aq 0.90601E-18 -18.0429 0.90601E-18 -18.0429 0.10000E+01 0.0000 83 H2PO4- 0.38526E-10 -10.4142 0.32207E-10 -10.4920 0.83598E+00 -0.0778 84 PO4-3 0.10664E-08 -8.9721 0.25876E-09 -9.5871 0.24263E+00 -0.6150 88 HP2O7-3 0.94657E-18 -18.0238 0.21889E-18 -18.6598 0.23125E+00 -0.6359 89 P2O7-4 0.91414E-17 -17.0390 0.70478E-18 -18.1519 0.77098E-01 -1.1130 90 H2S,aq 0.56083E-08 -8.2512 0.55890E-08 -8.2527 0.99654E+00 -0.0015 91 S2-2 0.21927E-14 -14.6590 0.11362E-14 -14.9445 0.51819E+00 -0.2855 97 SO3-2 0.11013E-17 -17.9581 0.57892E-18 -18.2374 0.52568E+00 -0.2793 99 HSO4- 0.32829E-19 -19.4837 0.27498E-19 -19.5607 0.83761E+00 -0.0770 Charge balance for all species = 0.3773E-10 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.8830345E-10 -.2229812E-01 -.2243610E+02 0.0000 2 H2O 0.1000000E+01 0.5550489E+02 0.9981994E+06 0.0000 3 Cl- 0.1571546E-03 0.1578764E-03 0.5587463E+01 6.2477 4 SO4-- 0.7405604E-12 -.1706630E-04 -.1636567E+01 7.8442 5 HCO3- 0.2740475E-06 0.1495529E-04 0.9109441E+00 3.4899 6 HS- 0.2917777E-04 0.4624968E-04 0.1526911E+01 5.5165 7 Al+++ 0.9695352E-29 0.5316550E-05 0.1431992E+00 0.7391 8 H4SiO4 0.6959346E-03 0.1353181E-01 0.1298355E+04 -3.1574 9 Ca++ 0.1350248E-06 0.2317651E-06 0.9272539E-02 13.1019 10 Mg++ 0.2112380E-10 0.9319940E-10 0.2261926E-05 9.2942 11 Fe++ 0.5821826E-13 0.3628795E-07 0.2023051E-02 6.7350 12 K+ 0.1565320E-03 0.1572861E-03 0.6139511E+01 6.2467 13 Na+ 0.1986312E-01 0.2230938E-01 0.5119968E+03 8.3494 14 Mn++ 0.1857608E-10 0.2511933E-08 0.1377607E-03 9.2392 15 HPO4-- 0.4530732E-07 0.4641229E-07 0.4446864E-02 12.6309 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.2053253E+02 -.1948717E-01 -.2051304E+02 0.0000000E+00 2 H2O 0.3996435E+02 0.4850784E+02 -.8543484E+01 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.3439010E-01 -.1491489E-04 0.3440502E-01 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.3436460E-01 0.4041936E-04 -.3440502E-01 0.0000000E+00 7 Al+++ 0.4043316E+01 0.4646336E-05 0.4043312E+01 0.0000000E+00 8 H4SiO4 0.1291184E+02 0.1182597E-01 0.1290001E+02 0.0000000E+00 9 Ca++ 0.1426190E+01 0.2025484E-06 0.1426190E+01 0.0000000E+00 10 Mg++ 0.9841262E+00 0.8145051E-10 0.9841262E+00 0.0000000E+00 11 Fe++ 0.8841299E+00 0.3171342E-07 0.8841299E+00 0.0000000E+00 12 K+ 0.2632694E+00 0.1374583E-03 0.2631320E+00 0.0000000E+00 13 Na+ 0.1556661E+01 0.1949702E-01 0.1537164E+01 0.0000000E+00 14 Mn++ 0.2149984E-01 0.2195274E-08 0.2149984E-01 0.0000000E+00 15 HPO4-- 0.7337789E-02 0.4056147E-07 0.7337749E-02 0.0000000E+00 Chg. balance for solid moles: -.3999E-14 Mass of aqueous solution: 0.875460E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 1239.9990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 1.536 0.186 402.7 2.605 29.73 154.6 andradite 0.1376 -0.861 69.94 1.845 5.163 18.17 grossular 0.3333E-01 -1.477 15.01 1.176 1.108 4.178 apatite-OH 0.2446E-02 -2.612 1.229 0.089 0.9071E-01 0.3904 clinochlore 0.1771 -0.752 98.45 1.993 7.268 37.45 daphnite 0.5127E-01 -1.290 36.58 1.563 2.701 11.09 chlorite-Mn 0.4300E-02 -2.367 3.049 0.484 0.2251 0.9715 diopside 0.5818E-01 -1.235 12.60 1.100 0.9303 3.851 hedenbergite 0.1509E-01 -1.821 3.743 0.573 0.2764 1.025 microcline 0.2308 -0.637 64.24 1.808 4.742 25.09 stilbite 0.8056 -0.094 567.7 2.754 41.91 264.8 stilpnomelane-Fe 0.6471E-01 -1.189 69.75 1.844 5.150 24.09 tr.625ac.25prg.125 0.1113E-01 -1.953 9.516 0.978 0.7025 3.063 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8050E+00 0.8050E+00 1.0000 -0.094 grossular 0.1950E+00 0.1950E+00 1.0000 -0.710 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.7612E+00 0.7612E+00 1.0000 -0.119 daphnite 0.2203E+00 0.2203E+00 1.0000 -0.657 chlorite-Mn 0.1848E-01 0.1848E-01 1.0000 -1.733 diopside 0.7941E+00 0.7941E+00 1.0000 -0.100 hedenbergite 0.2059E+00 0.2059E+00 1.0000 -0.686 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 tr.625ac.25prg.125 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 1354.512888 g Volume = 548.742645 cm3 Porosity: -10.4111% V(tot) - V(min): -.51743E+02 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 1239.9990000 g log = 3.0934 Original solution: 1000.0103000 g Original solution / Rock added: 0.81 (Water/Rock Ratio), log = -0.0934 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0565 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9662E+00 0.9855 0.1006E+01 0.1021E+01 CO2,gas 0.3655E-08 1.0069 0.3888E-08 0.3861E-08 CH4,gas 0.1942E-01 1.0124 0.2077E-01 0.2052E-01 H2,gas 0.1439E-01 1.0006 0.1521E-01 0.1520E-01 H2S,gas 0.1460E-06 0.9959 0.1536E-06 0.1543E-06 S2,gas 0.3626E-29 1.0000 0.3830E-29 0.3830E-29 CO,gas 0.1492E-13 1.0000 0.1576E-13 0.1576E-13 SO3,gas 0.7577E-48 1.0000 0.8005E-48 0.8005E-48 SO2,gas 0.4483E-27 1.0000 0.4736E-27 0.4736E-27 HCl,gas 0.2980E-17 1.0000 0.3149E-17 0.3149E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 16 albite -0.38 -0.38 0.00 0.000 0.11184E-10 22 andradite 39.01 39.01 0.00 0.000 0.36397E-10 23 grossular 32.73 32.73 0.00 0.000 0.00000E+00 32 apatite-OH -18.15 -18.15 0.00 0.000 0.60662E-11 46 clinochlore 39.07 39.07 0.00 0.000 0.00000E+00 47 daphnite 28.97 28.97 0.00 0.000 0.60662E-10 48 chlorite-Mn 46.87 46.87 0.00 0.000 -0.24265E-10 67 diopside 16.18 16.18 0.00 0.000 0.60662E-11 68 hedenbergite 14.21 14.21 0.00 0.000 0.00000E+00 116 microcline -2.49 -2.49 0.00 0.000 0.15165E-11 163 stilbite -7.52 -7.52 0.00 0.000 0.15165E-10 164 stilpnomelane-Fe 13.02 13.02 0.00 0.000 -0.27298E-10 245 tr.625ac.25prg.125 45.16 45.16 0.00 0.000 -0.48529E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -16.77 -10.11 -3.370 0.17261E+05 -8.410 3 CH4,gas 4.54 1.16 -3.38 -0.845 0.57738E+04 -1.683 4 H2,gas 8.00 4.48 -3.52 -2.010 0.60050E+04 -1.818 5 H2S,gas -6.23 -14.74 -8.51 -4.256 0.14535E+05 -6.814 6 S2,gas -7.34 -38.45 -31.12 -4.787 0.53129E+05 -29.417 7 CO,gas 3.21 -12.29 -15.50 -4.770 0.26468E+05 -13.802 8 SO3,gas 17.12 -32.67 -49.80 -12.449 0.85025E+05 -48.097 9 SO2,gas 0.83 -28.19 -29.02 -7.740 0.49557E+05 -27.325 10 HCl,gas 5.19 -14.01 -19.20 -9.600 0.32785E+05 -17.502 11 acmite 7.71 6.53 -1.18 -0.123 0.20177E+04 15 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 19 spessartine 24.46 19.72 -4.73 -0.237 0.80828E+04 20 analcite 3.32 2.77 -0.55 -0.061 0.93620E+03 26 annite 20.12 17.72 -2.40 -0.134 0.41063E+04 27 phlogopite 27.06 25.40 -1.67 -0.093 0.28488E+04 29 anorthite 12.71 8.27 -4.45 -0.342 0.75901E+04 35 aragonite 0.97 -3.67 -4.63 -1.545 0.79125E+04 36 brucite 12.57 9.29 -3.27 -0.655 0.55908E+04 37 calcite 0.81 -3.67 -4.48 -1.493 0.76483E+04 38 carnegieite-low 9.02 5.93 -3.09 -0.442 0.52800E+04 39 carnegieite-high 10.09 5.93 -4.16 -0.595 0.71070E+04 40 carpholite-Mg 8.58 4.46 -4.12 -0.275 0.70427E+04 41 carpholite-Fe 6.71 1.90 -4.81 -0.321 0.82205E+04 42 celadonite 5.34 3.65 -1.69 -0.099 0.28879E+04 43 celadonite-Fe 3.88 1.09 -2.79 -0.164 0.47561E+04 44 chrysotile 23.89 21.57 -2.32 -0.194 0.39692E+04 49 chlorite-Al-free 47.17 43.14 -4.04 -0.168 0.68935E+04 51 chloritoid-Fe 9.17 5.06 -4.12 -0.275 0.70313E+04 52 chloritoid-Mn 11.40 7.56 -3.84 -0.256 0.65587E+04 54 coesite -2.38 -3.16 -0.78 -0.260 0.13342E+04 61 cristobalite -2.56 -3.16 -0.60 -0.199 0.10195E+04 63 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71234E+04 65 diaspore 2.87 0.74 -2.13 -0.356 0.36448E+04 66 diamond -3.10 -7.80 -4.70 -1.343 0.80272E+04 71 enstatite 17.26 12.27 -4.99 -0.499 0.85225E+04 73 clinoenstatite 17.17 12.27 -4.89 -0.489 0.83541E+04 75 epidote 24.67 22.70 -1.97 -0.095 0.33583E+04 76 clinozoisite 22.81 18.95 -3.86 -0.175 0.65865E+04 77 epidote-Fe 29.84 26.46 -3.38 -0.176 0.57768E+04 78 fayalite 14.05 10.31 -3.73 -0.533 0.63743E+04 79 ferrosilite 11.15 7.16 -3.99 -0.399 0.68202E+04 83 gibbsite 4.08 0.74 -3.34 -0.477 0.57034E+04 84 glaucophane 22.97 20.80 -2.17 -0.059 0.37133E+04 85 glaucophane-Fe 17.28 13.12 -4.15 -0.112 0.70919E+04 86 graphite -3.55 -7.80 -4.26 -1.216 0.72694E+04 87 greenalite 16.14 13.89 -2.25 -0.187 0.38408E+04 90 hematite 12.57 8.99 -3.58 -0.434 0.61112E+04 91 heulandite -5.83 -7.52 -1.69 -0.077 0.28938E+04 95 jadeite 4.22 2.77 -1.44 -0.144 0.24617E+04 97 kalsilite 7.58 3.83 -3.76 -0.537 0.64125E+04 98 kaolinite -1.33 -4.84 -3.50 -0.319 0.59830E+04 101 laumontite 2.88 1.95 -0.93 -0.062 0.15934E+04 102 lawsonite 9.62 8.27 -1.35 -0.090 0.23067E+04 103 leucite 4.12 0.67 -3.45 -0.345 0.58872E+04 105 lizardite 23.24 21.57 -1.68 -0.140 0.28618E+04 107 magnetite 20.09 15.72 -4.37 -0.356 0.74537E+04 108 minnesotaite 10.39 7.58 -2.81 -0.165 0.48029E+04 112 manganosite 14.06 9.24 -4.82 -1.205 0.82281E+04 120 muscovite 2.58 -1.01 -3.59 -0.211 0.61312E+04 121 paragonite 4.24 1.09 -3.15 -0.185 0.53703E+04 122 nepheline 8.34 5.93 -2.41 -0.344 0.41124E+04 128 periclase-Fe 11.63 6.73 -4.89 -1.223 0.83523E+04 134 phlogopite-Na 29.65 27.50 -2.15 -0.119 0.36676E+04 136 prehnite 19.37 18.21 -1.16 -0.068 0.19847E+04 137 prehnite-Fe 22.50 21.96 -0.53 -0.032 0.91152E+03 138 pumpellyite-Fe 46.27 43.89 -2.38 -0.053 0.40575E+04 139 pumpellyite-Mg 48.99 46.45 -2.54 -0.057 0.43413E+04 143 pyrrhotite -4.26 -8.01 -3.75 -1.249 0.63986E+04 144 pyrrhotiteFe0.875 -6.02 -9.41 -3.39 -1.246 0.57858E+04 145 pyroxmangite 7.40 6.08 -1.32 -0.263 0.22485E+04 146 pyrophyllite -6.18 -11.15 -4.98 -0.311 0.84961E+04 147 quartz -2.99 -3.16 -0.17 -0.056 0.28685E+03 152 rhodonite 7.45 6.08 -1.36 -0.273 0.23288E+04 153 sanidine -1.28 -2.49 -1.21 -0.093 0.20677E+04 165 stilpnomelane-Mg 27.44 25.81 -1.63 -0.049 0.27802E+04 171 talc 16.49 15.25 -1.24 -0.073 0.21141E+04 174 tephroite 18.09 15.32 -2.76 -0.395 0.47207E+04 178 tridymite -2.63 -3.16 -0.53 -0.177 0.90683E+03 179 tremolite 47.87 47.42 -0.45 -0.012 0.77496E+03 180 ferroactinolite 38.45 34.62 -3.83 -0.104 0.65450E+04 181 troilite-low -4.41 -8.01 -3.60 -1.199 0.61414E+04 183 vesuvianite 223.47 218.82 -4.65 -0.036 0.79421E+04 187 wairakite 3.95 1.95 -2.00 -0.118 0.34153E+04 188 walstromite 11.51 9.94 -1.56 -0.313 0.26719E+04 189 wollastonite 10.46 9.94 -0.52 -0.103 0.88229E+03 190 pseudo-wollastonite 11.00 9.94 -1.06 -0.211 0.18021E+04 191 zoisite 22.85 18.95 -3.90 -0.177 0.66605E+04 192 akaganeite 7.75 4.49 -3.26 -0.705 0.55681E+04 199 chalcedony -2.80 -3.16 -0.35 -0.118 0.60615E+03 201 montmorillonite-Ca -2.29 -6.17 -3.88 -0.240 0.66180E+04 202 montmorillonite-K -2.24 -6.27 -4.03 -0.247 0.68816E+04 203 montmorillonite-Mg -2.48 -6.79 -4.31 -0.267 0.73677E+04 204 montmorillonite-Na -2.04 -5.57 -3.54 -0.216 0.60365E+04 205 nontronite-Ca 3.21 -0.19 -3.41 -0.221 0.58217E+04 206 nontronite-H 2.53 -2.36 -4.89 -0.328 0.83487E+04 207 nontronite-K 3.34 -0.30 -3.64 -0.233 0.62085E+04 208 nontronite-Mg 3.07 -0.82 -3.90 -0.253 0.66555E+04 209 nontronite-Na 3.52 0.40 -3.12 -0.200 0.53294E+04 224 tobermorite 9.82 7.76 -2.07 -0.564 0.35287E+04 230 alabandite -0.98 -5.50 -4.53 -1.509 0.77273E+04 233 boehmite 4.41 0.74 -3.67 -0.611 0.62618E+04 235 ferrous-oxide 9.81 6.73 -3.08 -0.769 0.52532E+04 240 silica-amorphous -2.09 -3.16 -1.07 -0.355 0.18203E+04 242 an20ab80 2.02 1.35 -0.67 -0.052 0.11472E+04 243 an25ab75 2.65 1.78 -0.87 -0.067 0.14809E+04 244 an30ab70 3.28 2.21 -1.07 -0.082 0.18243E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 40.0000000 g Current total amount of reactant added: 1239.9990000 g New total amount of reactant added: 1279.9990000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.3297E-10 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 11 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 1279.9990000 Water: Moles liquid = 0.4829E+02 kg liquid = 0.8699E+00 Moles total = 0.3946E+02 kg total = 0.7109E+00 Activity = 1.0000 Stoichiometric ionic strength = .1133460E-01 Osmotic coef. = 0.9693 True ionic strength = .2002121E-01 Chg. balance for total moles = 0.3297E-10 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.88306E-10 -10.0540 0.74198E-10 -10.1296 0.84024E+00 -0.0756 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.15788E-03 -3.8017 0.13186E-03 -3.8799 0.83519E+00 -0.0782 4 SO4-- 0.74399E-12 -12.1284 0.38634E-12 -12.4130 0.51929E+00 -0.2846 5 HCO3- 0.27531E-06 -6.5602 0.23028E-06 -6.6378 0.83641E+00 -0.0776 6 HS- 0.29313E-04 -4.5329 0.24485E-04 -4.6111 0.83531E+00 -0.0782 7 Al+++ 0.96961E-29 -29.0134 0.22399E-29 -29.6498 0.23101E+00 -0.6364 8 H4SiO4 0.69594E-03 -3.1574 0.69594E-03 -3.1574 0.10000E+01 0.0000 9 Ca++ 0.13503E-06 -6.8696 0.69605E-07 -7.1574 0.51548E+00 -0.2878 10 Mg++ 0.21125E-10 -10.6752 0.10840E-10 -10.9650 0.51312E+00 -0.2898 11 Fe++ 0.58221E-13 -13.2349 0.29907E-13 -13.5242 0.51368E+00 -0.2893 12 K+ 0.15654E-03 -3.8054 0.13096E-03 -3.8829 0.83661E+00 -0.0775 13 Na+ 0.19864E-01 -1.7019 0.16587E-01 -1.7802 0.83504E+00 -0.0783 14 Mn++ 0.18581E-10 -10.7309 0.95527E-11 -11.0199 0.51411E+00 -0.2889 15 HPO4-- 0.45306E-07 -7.3438 0.23530E-07 -7.6284 0.51936E+00 -0.2845 16 HSiO3- 0.10486E-01 -1.9794 0.87580E-02 -2.0576 0.83519E+00 -0.0782 17 Ca(HSiO3)+ 0.16591E-07 -7.7801 0.13883E-07 -7.8575 0.83679E+00 -0.0774 18 Mg(HSiO3)+ 0.32154E-11 -11.4928 0.26906E-11 -11.5702 0.83679E+00 -0.0774 19 NaHSiO3,aq 0.23495E-02 -2.6290 0.23495E-02 -2.6290 0.10000E+01 0.0000 20 AlO+ 0.66146E-16 -16.1795 0.55350E-16 -16.2569 0.83679E+00 -0.0774 22 HAlO2,aq 0.14856E-09 -9.8281 0.14856E-09 -9.8281 0.10000E+01 0.0000 23 AlO2- 0.53162E-05 -5.2744 0.44321E-05 -5.3534 0.83368E+00 -0.0790 24 CH4,aq 0.14226E-04 -4.8469 0.14176E-04 -4.8484 0.99654E+00 -0.0015 25 C2H6,aq 0.29762E-14 -14.5263 0.29659E-14 -14.5278 0.99654E+00 -0.0015 29 CO,aq 0.10624E-16 -16.9737 0.10624E-16 -16.9737 0.10000E+01 0.0000 30 CO2,aq 0.36636E-10 -10.4361 0.36509E-10 -10.4376 0.99654E+00 -0.0015 31 CO3-2 0.52314E-06 -6.2814 0.27108E-06 -6.5669 0.51819E+00 -0.2855 32 CaCO3,aq 0.23659E-09 -9.6260 0.23659E-09 -9.6260 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.48894E-12 -12.3107 0.40914E-12 -12.3881 0.83679E+00 -0.0774 34 CaCl+ 0.17750E-10 -10.7508 0.14853E-10 -10.8282 0.83679E+00 -0.0774 35 CaCl2,aq 0.46531E-15 -15.3323 0.46531E-15 -15.3323 0.10000E+01 0.0000 36 CaOH+ 0.79898E-07 -7.0975 0.66858E-07 -7.1748 0.83679E+00 -0.0774 37 CaSO4,aq 0.85393E-17 -17.0686 0.85393E-17 -17.0686 0.10000E+01 0.0000 38 HCl,aq 0.17928E-14 -14.7465 0.17928E-14 -14.7465 0.10000E+01 0.0000 43 FeCl+ 0.74594E-17 -17.1273 0.62420E-17 -17.2047 0.83679E+00 -0.0774 46 FeO,aq 0.21113E-09 -9.6754 0.21113E-09 -9.6754 0.10000E+01 0.0000 47 FeOH+ 0.15679E-10 -10.8047 0.13120E-10 -10.8821 0.83679E+00 -0.0774 48 HFeO2- 0.35648E-07 -7.4480 0.29773E-07 -7.5262 0.83519E+00 -0.0782 49 FeO+ 0.10988E-16 -16.9591 0.91947E-17 -17.0365 0.83679E+00 -0.0774 51 FeO2- 0.40918E-09 -9.3881 0.34174E-09 -9.4663 0.83519E+00 -0.0782 52 HFeO2,aq 0.32250E-11 -11.4915 0.32250E-11 -11.4915 0.10000E+01 0.0000 53 H2,aq 0.11624E-04 -4.9346 0.11584E-04 -4.9361 0.99654E+00 -0.0015 54 KCl,aq 0.31297E-09 -9.5045 0.31297E-09 -9.5045 0.10000E+01 0.0000 56 KOH,aq 0.75375E-06 -6.1228 0.75375E-06 -6.1228 0.10000E+01 0.0000 57 KSO4- 0.94004E-15 -15.0269 0.78512E-15 -15.1051 0.83519E+00 -0.0782 58 MgCO3,aq 0.92352E-14 -14.0346 0.92352E-14 -14.0346 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.77803E-16 -16.1090 0.65105E-16 -16.1864 0.83679E+00 -0.0774 60 MgCl+ 0.25053E-14 -14.6011 0.20964E-14 -14.6785 0.83679E+00 -0.0774 61 MgOH+ 0.68850E-10 -10.1621 0.57613E-10 -10.2395 0.83679E+00 -0.0774 63 MnO,aq 0.17969E-08 -8.7455 0.17969E-08 -8.7455 0.10000E+01 0.0000 64 MnOH+ 0.46524E-09 -9.3323 0.38931E-09 -9.4097 0.83679E+00 -0.0774 65 MnO2-2 0.20904E-10 -10.6798 0.10832E-10 -10.9653 0.51819E+00 -0.2855 66 HMnO2- 0.21083E-09 -9.6761 0.17608E-09 -9.7543 0.83519E+00 -0.0782 69 MnCl+ 0.92695E-14 -14.0329 0.77566E-14 -14.1103 0.83679E+00 -0.0774 71 NaCl,aq 0.72483E-06 -6.1398 0.72483E-06 -6.1398 0.10000E+01 0.0000 72 NaOH,aq 0.96047E-04 -4.0175 0.96047E-04 -4.0175 0.10000E+01 0.0000 74 OH- 0.93404E-02 -2.0296 0.77869E-02 -2.1086 0.83368E+00 -0.0790 79 HPO3-2 0.16393E-14 -14.7854 0.84944E-15 -15.0709 0.51819E+00 -0.2855 81 H2PO3- 0.15133E-18 -18.8201 0.12639E-18 -18.8983 0.83519E+00 -0.0782 82 H3PO4,aq 0.90601E-18 -18.0429 0.90601E-18 -18.0429 0.10000E+01 0.0000 83 H2PO4- 0.38526E-10 -10.4142 0.32207E-10 -10.4921 0.83598E+00 -0.0778 84 PO4-3 0.10664E-08 -8.9721 0.25874E-09 -9.5871 0.24263E+00 -0.6151 88 HP2O7-3 0.94653E-18 -18.0239 0.21888E-18 -18.6598 0.23124E+00 -0.6359 89 P2O7-4 0.91409E-17 -17.0390 0.70473E-18 -18.1520 0.77096E-01 -1.1130 90 H2S,aq 0.56344E-08 -8.2492 0.56149E-08 -8.2507 0.99654E+00 -0.0015 91 S2-2 0.22130E-14 -14.6550 0.11467E-14 -14.9405 0.51819E+00 -0.2855 97 SO3-2 0.11063E-17 -17.9561 0.58159E-18 -18.2354 0.52568E+00 -0.2793 99 HSO4- 0.32982E-19 -19.4817 0.27626E-19 -19.5587 0.83761E+00 -0.0770 Charge balance for all species = 0.3789E-10 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.8830557E-10 -.2229774E-01 -.2243572E+02 0.0000 2 H2O 0.1000000E+01 0.5550489E+02 0.9981994E+06 0.0000 3 Cl- 0.1578802E-03 0.1586054E-03 0.5613265E+01 6.2497 4 SO4-- 0.7439855E-12 -.1713168E-04 -.1642836E+01 7.8462 5 HCO3- 0.2753142E-06 0.1502435E-04 0.9151506E+00 3.4919 6 HS- 0.2931251E-04 0.4644982E-04 0.1533519E+01 5.5185 7 Al+++ 0.9696068E-29 0.5316397E-05 0.1431951E+00 0.7391 8 H4SiO4 0.6959365E-03 0.1353163E-01 0.1298338E+04 -3.1574 9 Ca++ 0.1350314E-06 0.2317749E-06 0.9272932E-02 13.1019 10 Mg++ 0.2112482E-10 0.9320160E-10 0.2261979E-05 9.2942 11 Fe++ 0.5822119E-13 0.3628716E-07 0.2023007E-02 6.7350 12 K+ 0.1565357E-03 0.1572898E-03 0.6139657E+01 6.2467 13 Na+ 0.1986360E-01 0.2230987E-01 0.5120080E+03 8.3494 14 Mn++ 0.1858117E-10 0.2512498E-08 0.1377917E-03 9.2393 15 HPO4-- 0.4530578E-07 0.4641069E-07 0.4446710E-02 12.6308 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.2119487E+02 -.1939727E-01 -.2117547E+02 0.0000000E+00 2 H2O 0.3946294E+02 0.4828487E+02 -.8821935E+01 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.3549864E-01 -.1490321E-04 0.3551354E-01 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.3547314E-01 0.4040768E-04 -.3551354E-01 0.0000000E+00 7 Al+++ 0.4173746E+01 0.4624846E-05 0.4173741E+01 0.0000000E+00 8 H4SiO4 0.1332835E+02 0.1177145E-01 0.1331658E+02 0.0000000E+00 9 Ca++ 0.1472196E+01 0.2016259E-06 0.1472196E+01 0.0000000E+00 10 Mg++ 0.1015872E+01 0.8107803E-10 0.1015872E+01 0.0000000E+00 11 Fe++ 0.9126503E+00 0.3156696E-07 0.9126503E+00 0.0000000E+00 12 K+ 0.2717620E+00 0.1368297E-03 0.2716252E+00 0.0000000E+00 13 Na+ 0.1606871E+01 0.1940782E-01 0.1587463E+01 0.0000000E+00 14 Mn++ 0.2219339E-01 0.2185675E-08 0.2219338E-01 0.0000000E+00 15 HPO4-- 0.7574492E-02 0.4037364E-07 0.7574452E-02 0.0000000E+00 Chg. balance for solid moles: -.6557E-15 Mass of aqueous solution: 0.871436E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 1279.9990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 1.586 0.200 415.9 2.619 29.74 159.7 andradite 0.1421 -0.848 72.19 1.858 5.163 18.76 grossular 0.3440E-01 -1.463 15.50 1.190 1.108 4.312 apatite-OH 0.2525E-02 -2.598 1.268 0.103 0.9071E-01 0.4030 clinochlore 0.1828 -0.738 101.6 2.007 7.266 38.65 daphnite 0.5291E-01 -1.276 37.75 1.577 2.700 11.44 chlorite-Mn 0.4439E-02 -2.353 3.147 0.498 0.2251 1.003 diopside 0.6036E-01 -1.219 13.07 1.116 0.9349 3.995 hedenbergite 0.1565E-01 -1.805 3.883 0.589 0.2777 1.064 microcline 0.2382 -0.623 66.31 1.822 4.742 25.90 stilbite 0.8312 -0.080 585.8 2.768 41.90 273.2 stilpnomelane-Fe 0.6680E-01 -1.175 72.01 1.857 5.150 24.87 tr.625ac.25prg.125 0.1147E-01 -1.941 9.801 0.991 0.7010 3.154 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8050E+00 0.8050E+00 1.0000 -0.094 grossular 0.1950E+00 0.1950E+00 1.0000 -0.710 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.7612E+00 0.7612E+00 1.0000 -0.119 daphnite 0.2203E+00 0.2203E+00 1.0000 -0.657 chlorite-Mn 0.1848E-01 0.1848E-01 1.0000 -1.733 diopside 0.7941E+00 0.7941E+00 1.0000 -0.100 hedenbergite 0.2059E+00 0.2059E+00 1.0000 -0.686 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 tr.625ac.25prg.125 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 1398.213152 g Volume = 566.423871 cm3 Porosity: -10.4141% V(tot) - V(min): -.53424E+02 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 1279.9990000 g log = 3.1072 Original solution: 1000.0103000 g Original solution / Rock added: 0.78 (Water/Rock Ratio), log = -0.1072 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0566 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9661E+00 0.9855 0.1006E+01 0.1021E+01 CO2,gas 0.3671E-08 1.0069 0.3906E-08 0.3879E-08 CH4,gas 0.1951E-01 1.0124 0.2087E-01 0.2061E-01 H2,gas 0.1439E-01 1.0006 0.1521E-01 0.1520E-01 H2S,gas 0.1467E-06 0.9959 0.1543E-06 0.1550E-06 S2,gas 0.3659E-29 1.0000 0.3866E-29 0.3866E-29 CO,gas 0.1498E-13 1.0000 0.1583E-13 0.1583E-13 SO3,gas 0.7611E-48 1.0000 0.8042E-48 0.8042E-48 SO2,gas 0.4504E-27 1.0000 0.4758E-27 0.4758E-27 HCl,gas 0.2994E-17 1.0000 0.3164E-17 0.3164E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 16 albite -0.38 -0.38 0.00 0.000 -0.94784E-12 22 andradite 39.01 39.01 0.00 0.000 -0.12132E-10 23 grossular 32.73 32.73 0.00 0.000 -0.24265E-10 32 apatite-OH -18.15 -18.15 0.00 0.000 0.60662E-11 46 clinochlore 39.07 39.07 0.00 0.000 -0.12132E-10 47 daphnite 28.97 28.97 0.00 0.000 0.00000E+00 48 chlorite-Mn 46.87 46.87 0.00 0.000 -0.12132E-10 67 diopside 16.18 16.18 0.00 0.000 0.12132E-10 68 hedenbergite 14.21 14.21 0.00 0.000 0.00000E+00 116 microcline -2.49 -2.49 0.00 0.000 0.15165E-11 163 stilbite -7.52 -7.52 0.00 0.000 -0.90992E-11 164 stilpnomelane-Fe 13.02 13.02 0.00 0.000 -0.75827E-10 245 tr.625ac.25prg.125 45.16 45.16 0.00 0.000 0.00000E+00 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -16.77 -10.11 -3.369 0.17258E+05 -8.408 3 CH4,gas 4.54 1.16 -3.38 -0.845 0.57704E+04 -1.681 4 H2,gas 8.00 4.48 -3.52 -2.010 0.60050E+04 -1.818 5 H2S,gas -6.23 -14.74 -8.51 -4.255 0.14531E+05 -6.811 6 S2,gas -7.34 -38.45 -31.11 -4.786 0.53122E+05 -29.413 7 CO,gas 3.21 -12.28 -15.50 -4.769 0.26465E+05 -13.800 8 SO3,gas 17.12 -32.67 -49.79 -12.448 0.85021E+05 -48.095 9 SO2,gas 0.83 -28.19 -29.02 -7.739 0.49553E+05 -27.323 10 HCl,gas 5.19 -14.01 -19.20 -9.599 0.32781E+05 -17.500 11 acmite 7.71 6.53 -1.18 -0.123 0.20176E+04 15 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 19 spessartine 24.46 19.72 -4.73 -0.237 0.80823E+04 20 analcite 3.32 2.77 -0.55 -0.061 0.93620E+03 26 annite 20.12 17.72 -2.40 -0.134 0.41064E+04 27 phlogopite 27.06 25.40 -1.67 -0.093 0.28488E+04 29 anorthite 12.71 8.27 -4.45 -0.342 0.75901E+04 35 aragonite 0.97 -3.67 -4.63 -1.544 0.79090E+04 36 brucite 12.57 9.29 -3.27 -0.655 0.55909E+04 37 calcite 0.81 -3.67 -4.48 -1.492 0.76448E+04 38 carnegieite-low 9.02 5.93 -3.09 -0.442 0.52800E+04 39 carnegieite-high 10.09 5.93 -4.16 -0.595 0.71070E+04 40 carpholite-Mg 8.58 4.46 -4.12 -0.275 0.70427E+04 41 carpholite-Fe 6.71 1.90 -4.81 -0.321 0.82205E+04 42 celadonite 5.34 3.65 -1.69 -0.099 0.28879E+04 43 celadonite-Fe 3.88 1.09 -2.79 -0.164 0.47561E+04 44 chrysotile 23.89 21.57 -2.32 -0.194 0.39692E+04 49 chlorite-Al-free 47.17 43.14 -4.04 -0.168 0.68935E+04 51 chloritoid-Fe 9.17 5.06 -4.12 -0.275 0.70313E+04 52 chloritoid-Mn 11.40 7.56 -3.84 -0.256 0.65585E+04 54 coesite -2.38 -3.16 -0.78 -0.260 0.13342E+04 61 cristobalite -2.56 -3.16 -0.60 -0.199 0.10195E+04 63 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71234E+04 65 diaspore 2.87 0.74 -2.13 -0.356 0.36448E+04 66 diamond -3.10 -7.80 -4.70 -1.343 0.80238E+04 71 enstatite 17.26 12.27 -4.99 -0.499 0.85225E+04 73 clinoenstatite 17.17 12.27 -4.89 -0.489 0.83541E+04 75 epidote 24.67 22.70 -1.97 -0.095 0.33583E+04 76 clinozoisite 22.81 18.95 -3.86 -0.175 0.65865E+04 77 epidote-Fe 29.84 26.46 -3.38 -0.176 0.57768E+04 78 fayalite 14.05 10.31 -3.73 -0.533 0.63743E+04 79 ferrosilite 11.15 7.16 -3.99 -0.399 0.68202E+04 83 gibbsite 4.08 0.74 -3.34 -0.477 0.57034E+04 84 glaucophane 22.97 20.80 -2.17 -0.059 0.37133E+04 85 glaucophane-Fe 17.28 13.12 -4.15 -0.112 0.70919E+04 86 graphite -3.55 -7.80 -4.26 -1.216 0.72660E+04 87 greenalite 16.14 13.89 -2.25 -0.187 0.38408E+04 90 hematite 12.57 8.99 -3.58 -0.434 0.61112E+04 91 heulandite -5.83 -7.52 -1.69 -0.077 0.28938E+04 95 jadeite 4.22 2.77 -1.44 -0.144 0.24617E+04 97 kalsilite 7.58 3.83 -3.76 -0.537 0.64125E+04 98 kaolinite -1.33 -4.84 -3.50 -0.319 0.59830E+04 101 laumontite 2.88 1.95 -0.93 -0.062 0.15934E+04 102 lawsonite 9.62 8.27 -1.35 -0.090 0.23067E+04 103 leucite 4.12 0.67 -3.45 -0.345 0.58872E+04 105 lizardite 23.24 21.57 -1.68 -0.140 0.28618E+04 107 magnetite 20.09 15.72 -4.37 -0.356 0.74537E+04 108 minnesotaite 10.39 7.58 -2.81 -0.165 0.48029E+04 112 manganosite 14.06 9.24 -4.82 -1.205 0.82279E+04 120 muscovite 2.58 -1.01 -3.59 -0.211 0.61312E+04 121 paragonite 4.24 1.09 -3.15 -0.185 0.53703E+04 122 nepheline 8.34 5.93 -2.41 -0.344 0.41124E+04 128 periclase-Fe 11.63 6.73 -4.89 -1.223 0.83523E+04 134 phlogopite-Na 29.65 27.50 -2.15 -0.119 0.36676E+04 136 prehnite 19.37 18.21 -1.16 -0.068 0.19847E+04 137 prehnite-Fe 22.50 21.96 -0.53 -0.032 0.91152E+03 138 pumpellyite-Fe 46.27 43.89 -2.38 -0.053 0.40575E+04 139 pumpellyite-Mg 48.99 46.45 -2.54 -0.057 0.43413E+04 143 pyrrhotite -4.26 -8.01 -3.75 -1.248 0.63952E+04 144 pyrrhotiteFe0.875 -6.02 -9.40 -3.39 -1.246 0.57824E+04 145 pyroxmangite 7.40 6.08 -1.32 -0.263 0.22483E+04 146 pyrophyllite -6.18 -11.15 -4.98 -0.311 0.84961E+04 147 quartz -2.99 -3.16 -0.17 -0.056 0.28685E+03 152 rhodonite 7.45 6.08 -1.36 -0.273 0.23286E+04 153 sanidine -1.28 -2.49 -1.21 -0.093 0.20677E+04 165 stilpnomelane-Mg 27.44 25.81 -1.63 -0.049 0.27802E+04 171 talc 16.49 15.25 -1.24 -0.073 0.21141E+04 174 tephroite 18.09 15.32 -2.76 -0.395 0.47204E+04 178 tridymite -2.63 -3.16 -0.53 -0.177 0.90682E+03 179 tremolite 47.87 47.42 -0.45 -0.012 0.77496E+03 180 ferroactinolite 38.45 34.62 -3.83 -0.104 0.65450E+04 181 troilite-low -4.41 -8.01 -3.59 -1.198 0.61380E+04 183 vesuvianite 223.47 218.82 -4.65 -0.036 0.79422E+04 187 wairakite 3.95 1.95 -2.00 -0.118 0.34153E+04 188 walstromite 11.51 9.94 -1.56 -0.313 0.26719E+04 189 wollastonite 10.46 9.94 -0.52 -0.103 0.88229E+03 190 pseudo-wollastonite 11.00 9.94 -1.06 -0.211 0.18021E+04 191 zoisite 22.85 18.95 -3.90 -0.177 0.66606E+04 192 akaganeite 7.75 4.49 -3.26 -0.705 0.55681E+04 199 chalcedony -2.80 -3.16 -0.35 -0.118 0.60614E+03 201 montmorillonite-Ca -2.29 -6.17 -3.88 -0.240 0.66180E+04 202 montmorillonite-K -2.24 -6.27 -4.03 -0.247 0.68816E+04 203 montmorillonite-Mg -2.48 -6.79 -4.31 -0.267 0.73677E+04 204 montmorillonite-Na -2.04 -5.57 -3.54 -0.216 0.60365E+04 205 nontronite-Ca 3.21 -0.19 -3.41 -0.221 0.58217E+04 206 nontronite-H 2.53 -2.36 -4.89 -0.328 0.83487E+04 207 nontronite-K 3.34 -0.30 -3.64 -0.233 0.62085E+04 208 nontronite-Mg 3.07 -0.82 -3.90 -0.253 0.66555E+04 209 nontronite-Na 3.52 0.40 -3.12 -0.200 0.53294E+04 224 tobermorite 9.82 7.76 -2.07 -0.564 0.35287E+04 230 alabandite -0.98 -5.50 -4.52 -1.508 0.77237E+04 233 boehmite 4.41 0.74 -3.67 -0.611 0.62618E+04 235 ferrous-oxide 9.81 6.73 -3.08 -0.769 0.52532E+04 240 silica-amorphous -2.09 -3.16 -1.07 -0.355 0.18203E+04 242 an20ab80 2.02 1.35 -0.67 -0.052 0.11472E+04 243 an25ab75 2.65 1.78 -0.87 -0.067 0.14809E+04 244 an30ab70 3.28 2.21 -1.07 -0.082 0.18243E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 40.0000000 g Current total amount of reactant added: 1279.9990000 g New total amount of reactant added: 1319.9990000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.3297E-10 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 11 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 1319.9990000 Water: Moles liquid = 0.4806E+02 kg liquid = 0.8659E+00 Moles total = 0.3896E+02 kg total = 0.7019E+00 Activity = 1.0000 Stoichiometric ionic strength = .1133522E-01 Osmotic coef. = 0.9693 True ionic strength = .2002170E-01 Chg. balance for total moles = 0.3297E-10 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.88308E-10 -10.0540 0.74200E-10 -10.1296 0.84024E+00 -0.0756 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.15861E-03 -3.7997 0.13247E-03 -3.8779 0.83519E+00 -0.0782 4 SO4-- 0.74744E-12 -12.1264 0.38813E-12 -12.4110 0.51928E+00 -0.2846 5 HCO3- 0.27659E-06 -6.5582 0.23134E-06 -6.6357 0.83641E+00 -0.0776 6 HS- 0.29448E-04 -4.5309 0.24599E-04 -4.6091 0.83531E+00 -0.0782 7 Al+++ 0.96968E-29 -29.0134 0.22400E-29 -29.6497 0.23101E+00 -0.6364 8 H4SiO4 0.69594E-03 -3.1574 0.69594E-03 -3.1574 0.10000E+01 0.0000 9 Ca++ 0.13504E-06 -6.8695 0.69608E-07 -7.1573 0.51547E+00 -0.2878 10 Mg++ 0.21126E-10 -10.6752 0.10840E-10 -10.9650 0.51311E+00 -0.2898 11 Fe++ 0.58224E-13 -13.2349 0.29908E-13 -13.5242 0.51368E+00 -0.2893 12 K+ 0.15654E-03 -3.8054 0.13096E-03 -3.8829 0.83661E+00 -0.0775 13 Na+ 0.19864E-01 -1.7019 0.16587E-01 -1.7802 0.83504E+00 -0.0783 14 Mn++ 0.18586E-10 -10.7308 0.95551E-11 -11.0198 0.51410E+00 -0.2890 15 HPO4-- 0.45304E-07 -7.3439 0.23529E-07 -7.6284 0.51936E+00 -0.2845 16 HSiO3- 0.10486E-01 -1.9794 0.87578E-02 -2.0576 0.83519E+00 -0.0782 17 Ca(HSiO3)+ 0.16591E-07 -7.7801 0.13883E-07 -7.8575 0.83679E+00 -0.0774 18 Mg(HSiO3)+ 0.32154E-11 -11.4928 0.26907E-11 -11.5701 0.83679E+00 -0.0774 19 NaHSiO3,aq 0.23495E-02 -2.6290 0.23495E-02 -2.6290 0.10000E+01 0.0000 20 AlO+ 0.66147E-16 -16.1795 0.55351E-16 -16.2569 0.83679E+00 -0.0774 22 HAlO2,aq 0.14856E-09 -9.8281 0.14856E-09 -9.8281 0.10000E+01 0.0000 23 AlO2- 0.53161E-05 -5.2744 0.44319E-05 -5.3534 0.83368E+00 -0.0790 24 CH4,aq 0.14292E-04 -4.8449 0.14242E-04 -4.8464 0.99654E+00 -0.0015 25 C2H6,aq 0.30039E-14 -14.5223 0.29935E-14 -14.5238 0.99654E+00 -0.0015 29 CO,aq 0.10674E-16 -16.9717 0.10674E-16 -16.9717 0.10000E+01 0.0000 30 CO2,aq 0.36806E-10 -10.4341 0.36679E-10 -10.4356 0.99654E+00 -0.0015 31 CO3-2 0.52555E-06 -6.2794 0.27233E-06 -6.5649 0.51818E+00 -0.2855 32 CaCO3,aq 0.23770E-09 -9.6240 0.23770E-09 -9.6240 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.49123E-12 -12.3087 0.41106E-12 -12.3861 0.83679E+00 -0.0774 34 CaCl+ 0.17833E-10 -10.7488 0.14923E-10 -10.8262 0.83679E+00 -0.0774 35 CaCl2,aq 0.46965E-15 -15.3282 0.46965E-15 -15.3282 0.10000E+01 0.0000 36 CaOH+ 0.79900E-07 -7.0975 0.66859E-07 -7.1748 0.83679E+00 -0.0774 37 CaSO4,aq 0.85793E-17 -17.0665 0.85793E-17 -17.0665 0.10000E+01 0.0000 38 HCl,aq 0.18012E-14 -14.7444 0.18012E-14 -14.7444 0.10000E+01 0.0000 43 FeCl+ 0.74944E-17 -17.1253 0.62712E-17 -17.2026 0.83679E+00 -0.0774 46 FeO,aq 0.21113E-09 -9.6754 0.21113E-09 -9.6754 0.10000E+01 0.0000 47 FeOH+ 0.15680E-10 -10.8047 0.13121E-10 -10.8820 0.83679E+00 -0.0774 48 HFeO2- 0.35647E-07 -7.4480 0.29772E-07 -7.5262 0.83519E+00 -0.0782 49 FeO+ 0.10988E-16 -16.9591 0.91949E-17 -17.0365 0.83679E+00 -0.0774 51 FeO2- 0.40917E-09 -9.3881 0.34174E-09 -9.4663 0.83519E+00 -0.0782 52 HFeO2,aq 0.32250E-11 -11.4915 0.32250E-11 -11.4915 0.10000E+01 0.0000 53 H2,aq 0.11624E-04 -4.9346 0.11584E-04 -4.9361 0.99654E+00 -0.0015 54 KCl,aq 0.31443E-09 -9.5025 0.31443E-09 -9.5025 0.10000E+01 0.0000 56 KOH,aq 0.75375E-06 -6.1228 0.75375E-06 -6.1228 0.10000E+01 0.0000 57 KSO4- 0.94443E-15 -15.0248 0.78878E-15 -15.1030 0.83519E+00 -0.0782 58 MgCO3,aq 0.92783E-14 -14.0325 0.92783E-14 -14.0325 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.78168E-16 -16.1070 0.65410E-16 -16.1844 0.83679E+00 -0.0774 60 MgCl+ 0.25170E-14 -14.5991 0.21062E-14 -14.6765 0.83679E+00 -0.0774 61 MgOH+ 0.68851E-10 -10.1621 0.57614E-10 -10.2395 0.83679E+00 -0.0774 63 MnO,aq 0.17973E-08 -8.7454 0.17973E-08 -8.7454 0.10000E+01 0.0000 64 MnOH+ 0.46535E-09 -9.3322 0.38940E-09 -9.4096 0.83679E+00 -0.0774 65 MnO2-2 0.20908E-10 -10.6797 0.10834E-10 -10.9652 0.51818E+00 -0.2855 66 HMnO2- 0.21087E-09 -9.6760 0.17612E-09 -9.7542 0.83519E+00 -0.0782 69 MnCl+ 0.93149E-14 -14.0308 0.77946E-14 -14.1082 0.83679E+00 -0.0774 71 NaCl,aq 0.72820E-06 -6.1377 0.72820E-06 -6.1377 0.10000E+01 0.0000 72 NaOH,aq 0.96047E-04 -4.0175 0.96047E-04 -4.0175 0.10000E+01 0.0000 74 OH- 0.93402E-02 -2.0296 0.77867E-02 -2.1086 0.83368E+00 -0.0790 79 HPO3-2 0.16392E-14 -14.7854 0.84941E-15 -15.0709 0.51818E+00 -0.2855 81 H2PO3- 0.15133E-18 -18.8201 0.12639E-18 -18.8983 0.83519E+00 -0.0782 82 H3PO4,aq 0.90601E-18 -18.0429 0.90601E-18 -18.0429 0.10000E+01 0.0000 83 H2PO4- 0.38525E-10 -10.4143 0.32206E-10 -10.4921 0.83598E+00 -0.0778 84 PO4-3 0.10663E-08 -8.9721 0.25872E-09 -9.5872 0.24263E+00 -0.6151 88 HP2O7-3 0.94649E-18 -18.0239 0.21887E-18 -18.6598 0.23124E+00 -0.6359 89 P2O7-4 0.91403E-17 -17.0390 0.70467E-18 -18.1520 0.77094E-01 -1.1130 90 H2S,aq 0.56606E-08 -8.2471 0.56411E-08 -8.2486 0.99654E+00 -0.0015 91 S2-2 0.22336E-14 -14.6510 0.11574E-14 -14.9365 0.51818E+00 -0.2855 97 SO3-2 0.11115E-17 -17.9541 0.58428E-18 -18.2334 0.52568E+00 -0.2793 99 HSO4- 0.33136E-19 -19.4797 0.27755E-19 -19.5567 0.83760E+00 -0.0770 Charge balance for all species = 0.3808E-10 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.8830770E-10 -.2229736E-01 -.2243534E+02 0.0000 2 H2O 0.1000000E+01 0.5550489E+02 0.9981993E+06 0.0000 3 Cl- 0.1586127E-03 0.1593412E-03 0.5639305E+01 6.2517 4 SO4-- 0.7474411E-12 -.1719766E-04 -.1649164E+01 7.8482 5 HCO3- 0.2765922E-06 0.1509405E-04 0.9193961E+00 3.4939 6 HS- 0.2944849E-04 0.4665182E-04 0.1540187E+01 5.5205 7 Al+++ 0.9696795E-29 0.5316246E-05 0.1431910E+00 0.7390 8 H4SiO4 0.6959382E-03 0.1353145E-01 0.1298320E+04 -3.1574 9 Ca++ 0.1350380E-06 0.2317849E-06 0.9273331E-02 13.1019 10 Mg++ 0.2112586E-10 0.9320471E-10 0.2262055E-05 9.2942 11 Fe++ 0.5822415E-13 0.3628637E-07 0.2022963E-02 6.7350 12 K+ 0.1565395E-03 0.1572936E-03 0.6139805E+01 6.2467 13 Na+ 0.1986408E-01 0.2231036E-01 0.5120192E+03 8.3494 14 Mn++ 0.1858601E-10 0.2513029E-08 0.1378209E-03 9.2394 15 HPO4-- 0.4530421E-07 0.4640907E-07 0.4446555E-02 12.6308 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.2185721E+02 -.1930737E-01 -.2183790E+02 0.0000000E+00 2 H2O 0.3896152E+02 0.4806191E+02 -.9100385E+01 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.3660718E-01 -.1489153E-04 0.3662207E-01 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.3658167E-01 0.4039600E-04 -.3662207E-01 0.0000000E+00 7 Al+++ 0.4304176E+01 0.4603359E-05 0.4304171E+01 0.0000000E+00 8 H4SiO4 0.1374486E+02 0.1171693E-01 0.1373315E+02 0.0000000E+00 9 Ca++ 0.1518202E+01 0.2007035E-06 0.1518201E+01 0.0000000E+00 10 Mg++ 0.1047618E+01 0.8070633E-10 0.1047618E+01 0.0000000E+00 11 Fe++ 0.9411706E+00 0.3142051E-07 0.9411706E+00 0.0000000E+00 12 K+ 0.2802546E+00 0.1362012E-03 0.2801184E+00 0.0000000E+00 13 Na+ 0.1657080E+01 0.1931863E-01 0.1637762E+01 0.0000000E+00 14 Mn++ 0.2288693E-01 0.2176042E-08 0.2288693E-01 0.0000000E+00 15 HPO4-- 0.7811195E-02 0.4018580E-07 0.7811155E-02 0.0000000E+00 Chg. balance for solid moles: -.7286E-14 Mass of aqueous solution: 0.867412E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 1319.9990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 1.636 0.214 429.1 2.633 29.76 164.7 andradite 0.1465 -0.834 74.44 1.872 5.163 19.34 grossular 0.3548E-01 -1.450 15.98 1.204 1.108 4.447 apatite-OH 0.2604E-02 -2.584 1.308 0.117 0.9071E-01 0.4156 clinochlore 0.1885 -0.725 104.8 2.020 7.265 39.85 daphnite 0.5456E-01 -1.263 38.93 1.590 2.700 11.80 chlorite-Mn 0.4577E-02 -2.339 3.245 0.511 0.2251 1.034 diopside 0.6254E-01 -1.204 13.54 1.132 0.9392 4.139 hedenbergite 0.1622E-01 -1.790 4.023 0.605 0.2790 1.102 microcline 0.2457 -0.610 68.38 1.835 4.742 26.71 stilbite 0.8569 -0.067 603.9 2.781 41.88 281.7 stilpnomelane-Fe 0.6889E-01 -1.162 74.26 1.871 5.150 25.65 tr.625ac.25prg.125 0.1180E-01 -1.928 10.09 1.004 0.6995 3.246 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8050E+00 0.8050E+00 1.0000 -0.094 grossular 0.1950E+00 0.1950E+00 1.0000 -0.710 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.7612E+00 0.7612E+00 1.0000 -0.119 daphnite 0.2203E+00 0.2203E+00 1.0000 -0.657 chlorite-Mn 0.1849E-01 0.1849E-01 1.0000 -1.733 diopside 0.7941E+00 0.7941E+00 1.0000 -0.100 hedenbergite 0.2059E+00 0.2059E+00 1.0000 -0.686 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 tr.625ac.25prg.125 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 1441.913417 g Volume = 584.105096 cm3 Porosity: -10.4169% V(tot) - V(min): -.55105E+02 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 1319.9990000 g log = 3.1206 Original solution: 1000.0103000 g Original solution / Rock added: 0.76 (Water/Rock Ratio), log = -0.1206 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0567 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9660E+00 0.9855 0.1006E+01 0.1021E+01 CO2,gas 0.3688E-08 1.0069 0.3924E-08 0.3897E-08 CH4,gas 0.1959E-01 1.0124 0.2096E-01 0.2071E-01 H2,gas 0.1438E-01 1.0006 0.1521E-01 0.1520E-01 H2S,gas 0.1474E-06 0.9959 0.1551E-06 0.1557E-06 S2,gas 0.3693E-29 1.0000 0.3902E-29 0.3902E-29 CO,gas 0.1505E-13 1.0000 0.1591E-13 0.1591E-13 SO3,gas 0.7646E-48 1.0000 0.8080E-48 0.8080E-48 SO2,gas 0.4524E-27 1.0000 0.4781E-27 0.4781E-27 HCl,gas 0.3008E-17 1.0000 0.3178E-17 0.3178E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 16 albite -0.38 -0.38 0.00 0.000 0.11184E-10 22 andradite 39.01 39.01 0.00 0.000 0.36397E-10 23 grossular 32.73 32.73 0.00 0.000 -0.36397E-10 32 apatite-OH -18.15 -18.15 0.00 0.000 0.12132E-10 46 clinochlore 39.07 39.07 0.00 0.000 0.12132E-10 47 daphnite 28.97 28.97 0.00 0.000 0.36397E-10 48 chlorite-Mn 46.87 46.87 0.00 0.000 0.00000E+00 67 diopside 16.18 16.18 0.00 0.000 -0.60662E-11 68 hedenbergite 14.21 14.21 0.00 0.000 -0.30331E-11 116 microcline -2.49 -2.49 0.00 0.000 0.13649E-10 163 stilbite -7.52 -7.52 0.00 0.000 -0.33364E-10 164 stilpnomelane-Fe 13.02 13.02 0.00 0.000 0.21232E-10 245 tr.625ac.25prg.125 45.16 45.16 0.00 0.000 0.36397E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -16.77 -10.11 -3.368 0.17254E+05 -8.406 3 CH4,gas 4.54 1.17 -3.38 -0.844 0.57670E+04 -1.679 4 H2,gas 8.00 4.48 -3.52 -2.010 0.60050E+04 -1.818 5 H2S,gas -6.23 -14.74 -8.51 -4.254 0.14528E+05 -6.809 6 S2,gas -7.34 -38.44 -31.11 -4.786 0.53115E+05 -29.409 7 CO,gas 3.21 -12.28 -15.50 -4.768 0.26461E+05 -13.798 8 SO3,gas 17.12 -32.67 -49.79 -12.448 0.85018E+05 -48.093 9 SO2,gas 0.83 -28.19 -29.02 -7.739 0.49550E+05 -27.321 10 HCl,gas 5.19 -14.01 -19.20 -9.598 0.32778E+05 -17.498 11 acmite 7.71 6.53 -1.18 -0.123 0.20176E+04 15 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 19 spessartine 24.46 19.72 -4.73 -0.237 0.80819E+04 20 analcite 3.32 2.77 -0.55 -0.061 0.93621E+03 26 annite 20.12 17.72 -2.40 -0.134 0.41064E+04 27 phlogopite 27.06 25.40 -1.67 -0.093 0.28488E+04 29 anorthite 12.71 8.27 -4.45 -0.342 0.75901E+04 35 aragonite 0.97 -3.66 -4.63 -1.543 0.79056E+04 36 brucite 12.57 9.29 -3.27 -0.655 0.55909E+04 37 calcite 0.81 -3.66 -4.48 -1.492 0.76414E+04 38 carnegieite-low 9.02 5.93 -3.09 -0.442 0.52800E+04 39 carnegieite-high 10.09 5.93 -4.16 -0.595 0.71070E+04 40 carpholite-Mg 8.58 4.46 -4.12 -0.275 0.70427E+04 41 carpholite-Fe 6.71 1.90 -4.81 -0.321 0.82205E+04 42 celadonite 5.34 3.65 -1.69 -0.099 0.28879E+04 43 celadonite-Fe 3.88 1.09 -2.79 -0.164 0.47561E+04 44 chrysotile 23.89 21.57 -2.32 -0.194 0.39692E+04 49 chlorite-Al-free 47.17 43.14 -4.04 -0.168 0.68935E+04 51 chloritoid-Fe 9.17 5.06 -4.12 -0.275 0.70313E+04 52 chloritoid-Mn 11.40 7.56 -3.84 -0.256 0.65584E+04 54 coesite -2.38 -3.16 -0.78 -0.260 0.13342E+04 61 cristobalite -2.56 -3.16 -0.60 -0.199 0.10195E+04 63 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71234E+04 65 diaspore 2.87 0.74 -2.13 -0.356 0.36449E+04 66 diamond -3.10 -7.80 -4.70 -1.342 0.80203E+04 71 enstatite 17.26 12.27 -4.99 -0.499 0.85225E+04 73 clinoenstatite 17.17 12.27 -4.89 -0.489 0.83541E+04 75 epidote 24.67 22.70 -1.97 -0.095 0.33583E+04 76 clinozoisite 22.81 18.95 -3.86 -0.175 0.65865E+04 77 epidote-Fe 29.84 26.46 -3.38 -0.176 0.57768E+04 78 fayalite 14.05 10.31 -3.73 -0.533 0.63743E+04 79 ferrosilite 11.15 7.16 -3.99 -0.399 0.68202E+04 83 gibbsite 4.08 0.74 -3.34 -0.477 0.57034E+04 84 glaucophane 22.97 20.80 -2.17 -0.059 0.37133E+04 85 glaucophane-Fe 17.28 13.12 -4.15 -0.112 0.70919E+04 86 graphite -3.55 -7.80 -4.25 -1.215 0.72626E+04 87 greenalite 16.14 13.89 -2.25 -0.187 0.38408E+04 90 hematite 12.57 8.99 -3.58 -0.434 0.61112E+04 91 heulandite -5.83 -7.52 -1.69 -0.077 0.28938E+04 95 jadeite 4.22 2.77 -1.44 -0.144 0.24617E+04 97 kalsilite 7.58 3.83 -3.76 -0.537 0.64125E+04 98 kaolinite -1.33 -4.84 -3.50 -0.319 0.59830E+04 101 laumontite 2.88 1.95 -0.93 -0.062 0.15934E+04 102 lawsonite 9.62 8.27 -1.35 -0.090 0.23068E+04 103 leucite 4.12 0.67 -3.45 -0.345 0.58872E+04 105 lizardite 23.24 21.57 -1.68 -0.140 0.28618E+04 107 magnetite 20.09 15.72 -4.37 -0.356 0.74537E+04 108 minnesotaite 10.39 7.58 -2.81 -0.165 0.48029E+04 112 manganosite 14.06 9.24 -4.82 -1.205 0.82278E+04 120 muscovite 2.58 -1.01 -3.59 -0.211 0.61312E+04 121 paragonite 4.24 1.09 -3.15 -0.185 0.53703E+04 122 nepheline 8.34 5.93 -2.41 -0.344 0.41124E+04 128 periclase-Fe 11.63 6.73 -4.89 -1.223 0.83523E+04 134 phlogopite-Na 29.65 27.50 -2.15 -0.119 0.36676E+04 136 prehnite 19.37 18.21 -1.16 -0.068 0.19847E+04 137 prehnite-Fe 22.50 21.96 -0.53 -0.032 0.91153E+03 138 pumpellyite-Fe 46.27 43.89 -2.38 -0.053 0.40576E+04 139 pumpellyite-Mg 48.99 46.45 -2.54 -0.057 0.43414E+04 143 pyrrhotite -4.26 -8.00 -3.74 -1.248 0.63917E+04 144 pyrrhotiteFe0.875 -6.02 -9.40 -3.38 -1.245 0.57789E+04 145 pyroxmangite 7.40 6.08 -1.32 -0.263 0.22482E+04 146 pyrophyllite -6.18 -11.15 -4.98 -0.311 0.84961E+04 147 quartz -2.99 -3.16 -0.17 -0.056 0.28685E+03 152 rhodonite 7.45 6.08 -1.36 -0.273 0.23284E+04 153 sanidine -1.28 -2.49 -1.21 -0.093 0.20677E+04 165 stilpnomelane-Mg 27.44 25.81 -1.63 -0.049 0.27802E+04 171 talc 16.49 15.25 -1.24 -0.073 0.21141E+04 174 tephroite 18.09 15.32 -2.76 -0.395 0.47201E+04 178 tridymite -2.63 -3.16 -0.53 -0.177 0.90682E+03 179 tremolite 47.87 47.42 -0.45 -0.012 0.77496E+03 180 ferroactinolite 38.45 34.62 -3.83 -0.104 0.65450E+04 181 troilite-low -4.41 -8.00 -3.59 -1.198 0.61345E+04 183 vesuvianite 223.47 218.82 -4.65 -0.036 0.79422E+04 187 wairakite 3.95 1.95 -2.00 -0.118 0.34153E+04 188 walstromite 11.51 9.94 -1.56 -0.313 0.26719E+04 189 wollastonite 10.46 9.94 -0.52 -0.103 0.88229E+03 190 pseudo-wollastonite 11.00 9.94 -1.06 -0.211 0.18021E+04 191 zoisite 22.85 18.95 -3.90 -0.177 0.66606E+04 192 akaganeite 7.75 4.49 -3.26 -0.705 0.55681E+04 199 chalcedony -2.80 -3.16 -0.35 -0.118 0.60614E+03 201 montmorillonite-Ca -2.29 -6.17 -3.88 -0.240 0.66180E+04 202 montmorillonite-K -2.24 -6.27 -4.03 -0.247 0.68816E+04 203 montmorillonite-Mg -2.48 -6.79 -4.31 -0.267 0.73677E+04 204 montmorillonite-Na -2.04 -5.57 -3.54 -0.216 0.60365E+04 205 nontronite-Ca 3.21 -0.19 -3.41 -0.221 0.58217E+04 206 nontronite-H 2.53 -2.36 -4.89 -0.328 0.83487E+04 207 nontronite-K 3.34 -0.30 -3.64 -0.233 0.62085E+04 208 nontronite-Mg 3.07 -0.82 -3.90 -0.253 0.66555E+04 209 nontronite-Na 3.52 0.40 -3.12 -0.200 0.53294E+04 224 tobermorite 9.82 7.76 -2.07 -0.564 0.35287E+04 230 alabandite -0.98 -5.50 -4.52 -1.507 0.77201E+04 233 boehmite 4.41 0.74 -3.67 -0.611 0.62618E+04 235 ferrous-oxide 9.81 6.73 -3.08 -0.769 0.52532E+04 240 silica-amorphous -2.09 -3.16 -1.07 -0.355 0.18203E+04 242 an20ab80 2.02 1.35 -0.67 -0.052 0.11472E+04 243 an25ab75 2.65 1.78 -0.87 -0.067 0.14809E+04 244 an30ab70 3.28 2.21 -1.07 -0.082 0.18243E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 40.0000000 g Current total amount of reactant added: 1319.9990000 g New total amount of reactant added: 1359.9990000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.3297E-10 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 11 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 1359.9990000 Water: Moles liquid = 0.4784E+02 kg liquid = 0.8619E+00 Moles total = 0.3846E+02 kg total = 0.6929E+00 Activity = 1.0000 Stoichiometric ionic strength = .1133584E-01 Osmotic coef. = 0.9693 True ionic strength = .2002219E-01 Chg. balance for total moles = 0.3297E-10 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.88310E-10 -10.0540 0.74202E-10 -10.1296 0.84024E+00 -0.0756 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.15935E-03 -3.7976 0.13309E-03 -3.8759 0.83519E+00 -0.0782 4 SO4-- 0.75093E-12 -12.1244 0.38994E-12 -12.4090 0.51928E+00 -0.2846 5 HCO3- 0.27788E-06 -6.5561 0.23242E-06 -6.6337 0.83641E+00 -0.0776 6 HS- 0.29586E-04 -4.5289 0.24713E-04 -4.6071 0.83531E+00 -0.0782 7 Al+++ 0.96975E-29 -29.0133 0.22402E-29 -29.6497 0.23101E+00 -0.6364 8 H4SiO4 0.69594E-03 -3.1574 0.69594E-03 -3.1574 0.10000E+01 0.0000 9 Ca++ 0.13504E-06 -6.8695 0.69611E-07 -7.1573 0.51547E+00 -0.2878 10 Mg++ 0.21127E-10 -10.6752 0.10840E-10 -10.9650 0.51311E+00 -0.2898 11 Fe++ 0.58227E-13 -13.2349 0.29910E-13 -13.5242 0.51367E+00 -0.2893 12 K+ 0.15654E-03 -3.8054 0.13097E-03 -3.8828 0.83661E+00 -0.0775 13 Na+ 0.19865E-01 -1.7019 0.16588E-01 -1.7802 0.83504E+00 -0.0783 14 Mn++ 0.18591E-10 -10.7307 0.95574E-11 -11.0197 0.51410E+00 -0.2890 15 HPO4-- 0.45303E-07 -7.3439 0.23528E-07 -7.6284 0.51935E+00 -0.2845 16 HSiO3- 0.10486E-01 -1.9794 0.87576E-02 -2.0576 0.83519E+00 -0.0782 17 Ca(HSiO3)+ 0.16591E-07 -7.7801 0.13884E-07 -7.8575 0.83679E+00 -0.0774 18 Mg(HSiO3)+ 0.32155E-11 -11.4927 0.26907E-11 -11.5701 0.83679E+00 -0.0774 19 NaHSiO3,aq 0.23495E-02 -2.6290 0.23495E-02 -2.6290 0.10000E+01 0.0000 20 AlO+ 0.66148E-16 -16.1795 0.55352E-16 -16.2569 0.83679E+00 -0.0774 22 HAlO2,aq 0.14856E-09 -9.8281 0.14856E-09 -9.8281 0.10000E+01 0.0000 23 AlO2- 0.53159E-05 -5.2744 0.44318E-05 -5.3534 0.83368E+00 -0.0790 24 CH4,aq 0.14358E-04 -4.8429 0.14309E-04 -4.8444 0.99654E+00 -0.0015 25 C2H6,aq 0.30319E-14 -14.5183 0.30215E-14 -14.5198 0.99654E+00 -0.0015 29 CO,aq 0.10724E-16 -16.9697 0.10724E-16 -16.9697 0.10000E+01 0.0000 30 CO2,aq 0.36979E-10 -10.4320 0.36851E-10 -10.4336 0.99654E+00 -0.0015 31 CO3-2 0.52799E-06 -6.2774 0.27360E-06 -6.5629 0.51818E+00 -0.2855 32 CaCO3,aq 0.23881E-09 -9.6220 0.23881E-09 -9.6220 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.49355E-12 -12.3067 0.41299E-12 -12.3841 0.83679E+00 -0.0774 34 CaCl+ 0.17917E-10 -10.7467 0.14993E-10 -10.8241 0.83679E+00 -0.0774 35 CaCl2,aq 0.47406E-15 -15.3242 0.47406E-15 -15.3242 0.10000E+01 0.0000 36 CaOH+ 0.79902E-07 -7.0974 0.66861E-07 -7.1748 0.83679E+00 -0.0774 37 CaSO4,aq 0.86196E-17 -17.0645 0.86196E-17 -17.0645 0.10000E+01 0.0000 38 HCl,aq 0.18096E-14 -14.7424 0.18096E-14 -14.7424 0.10000E+01 0.0000 43 FeCl+ 0.75296E-17 -17.1232 0.63007E-17 -17.2006 0.83679E+00 -0.0774 46 FeO,aq 0.21113E-09 -9.6754 0.21113E-09 -9.6754 0.10000E+01 0.0000 47 FeOH+ 0.15680E-10 -10.8047 0.13121E-10 -10.8820 0.83679E+00 -0.0774 48 HFeO2- 0.35646E-07 -7.4480 0.29771E-07 -7.5262 0.83519E+00 -0.0782 49 FeO+ 0.10989E-16 -16.9591 0.91951E-17 -17.0364 0.83679E+00 -0.0774 51 FeO2- 0.40916E-09 -9.3881 0.34173E-09 -9.4663 0.83519E+00 -0.0782 52 HFeO2,aq 0.32250E-11 -11.4915 0.32250E-11 -11.4915 0.10000E+01 0.0000 53 H2,aq 0.11624E-04 -4.9346 0.11584E-04 -4.9361 0.99654E+00 -0.0015 54 KCl,aq 0.31591E-09 -9.5004 0.31591E-09 -9.5004 0.10000E+01 0.0000 56 KOH,aq 0.75375E-06 -6.1228 0.75375E-06 -6.1228 0.10000E+01 0.0000 57 KSO4- 0.94885E-15 -15.0228 0.79247E-15 -15.1010 0.83519E+00 -0.0782 58 MgCO3,aq 0.93217E-14 -14.0305 0.93217E-14 -14.0305 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.78535E-16 -16.1049 0.65718E-16 -16.1823 0.83679E+00 -0.0774 60 MgCl+ 0.25289E-14 -14.5971 0.21161E-14 -14.6745 0.83679E+00 -0.0774 61 MgOH+ 0.68853E-10 -10.1621 0.57615E-10 -10.2395 0.83679E+00 -0.0774 63 MnO,aq 0.17977E-08 -8.7453 0.17977E-08 -8.7453 0.10000E+01 0.0000 64 MnOH+ 0.46545E-09 -9.3321 0.38949E-09 -9.4095 0.83679E+00 -0.0774 65 MnO2-2 0.20911E-10 -10.6796 0.10836E-10 -10.9651 0.51818E+00 -0.2855 66 HMnO2- 0.21091E-09 -9.6759 0.17615E-09 -9.7541 0.83519E+00 -0.0782 69 MnCl+ 0.93606E-14 -14.0287 0.78328E-14 -14.1061 0.83679E+00 -0.0774 71 NaCl,aq 0.73161E-06 -6.1357 0.73161E-06 -6.1357 0.10000E+01 0.0000 72 NaOH,aq 0.96047E-04 -4.0175 0.96047E-04 -4.0175 0.10000E+01 0.0000 74 OH- 0.93400E-02 -2.0297 0.77865E-02 -2.1087 0.83368E+00 -0.0790 79 HPO3-2 0.16391E-14 -14.7854 0.84937E-15 -15.0709 0.51818E+00 -0.2855 81 H2PO3- 0.15132E-18 -18.8201 0.12638E-18 -18.8983 0.83519E+00 -0.0782 82 H3PO4,aq 0.90602E-18 -18.0429 0.90602E-18 -18.0429 0.10000E+01 0.0000 83 H2PO4- 0.38525E-10 -10.4143 0.32206E-10 -10.4921 0.83598E+00 -0.0778 84 PO4-3 0.10663E-08 -8.9721 0.25871E-09 -9.5872 0.24262E+00 -0.6151 88 HP2O7-3 0.94645E-18 -18.0239 0.21885E-18 -18.6598 0.23124E+00 -0.6359 89 P2O7-4 0.91398E-17 -17.0391 0.70461E-18 -18.1521 0.77092E-01 -1.1130 90 H2S,aq 0.56871E-08 -8.2451 0.56675E-08 -8.2466 0.99654E+00 -0.0015 91 S2-2 0.22545E-14 -14.6469 0.11682E-14 -14.9325 0.51818E+00 -0.2855 97 SO3-2 0.11167E-17 -17.9521 0.58700E-18 -18.2314 0.52567E+00 -0.2793 99 HSO4- 0.33291E-19 -19.4777 0.27885E-19 -19.5546 0.83760E+00 -0.0770 Charge balance for all species = 0.3826E-10 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.8830985E-10 -.2229697E-01 -.2243495E+02 0.0000 2 H2O 0.1000000E+01 0.5550489E+02 0.9981993E+06 0.0000 3 Cl- 0.1593519E-03 0.1600838E-03 0.5665589E+01 6.2537 4 SO4-- 0.7509278E-12 -.1726427E-04 -.1655551E+01 7.8502 5 HCO3- 0.2778817E-06 0.1516440E-04 0.9236812E+00 3.4959 6 HS- 0.2958574E-04 0.4685570E-04 0.1546918E+01 5.5225 7 Al+++ 0.9697531E-29 0.5316096E-05 0.1431870E+00 0.7390 8 H4SiO4 0.6959398E-03 0.1353126E-01 0.1298302E+04 -3.1574 9 Ca++ 0.1350447E-06 0.2317950E-06 0.9273733E-02 13.1019 10 Mg++ 0.2112691E-10 0.9320707E-10 0.2262112E-05 9.2942 11 Fe++ 0.5822713E-13 0.3628557E-07 0.2022918E-02 6.7350 12 K+ 0.1565433E-03 0.1572974E-03 0.6139954E+01 6.2467 13 Na+ 0.1986456E-01 0.2231085E-01 0.5120306E+03 8.3494 14 Mn++ 0.1859063E-10 0.2513530E-08 0.1378483E-03 9.2395 15 HPO4-- 0.4530262E-07 0.4640743E-07 0.4446397E-02 12.6308 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.2251955E+02 -.1921747E-01 -.2250033E+02 0.0000000E+00 2 H2O 0.3846010E+02 0.4783894E+02 -.9378835E+01 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.3771571E-01 -.1487985E-04 0.3773059E-01 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.3769021E-01 0.4038432E-04 -.3773059E-01 0.0000000E+00 7 Al+++ 0.4434605E+01 0.4581874E-05 0.4434601E+01 0.0000000E+00 8 H4SiO4 0.1416137E+02 0.1166241E-01 0.1414971E+02 0.0000000E+00 9 Ca++ 0.1564207E+01 0.1997811E-06 0.1564207E+01 0.0000000E+00 10 Mg++ 0.1079364E+01 0.8033396E-10 0.1079364E+01 0.0000000E+00 11 Fe++ 0.9696910E+00 0.3127406E-07 0.9696909E+00 0.0000000E+00 12 K+ 0.2887471E+00 0.1355726E-03 0.2886116E+00 0.0000000E+00 13 Na+ 0.1707290E+01 0.1922943E-01 0.1688061E+01 0.0000000E+00 14 Mn++ 0.2358047E-01 0.2166379E-08 0.2358047E-01 0.0000000E+00 15 HPO4-- 0.8047898E-02 0.3999796E-07 0.8047858E-02 0.0000000E+00 Chg. balance for solid moles: -.2824E-14 Mass of aqueous solution: 0.863388E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 1359.9990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 1.687 0.227 442.2 2.646 29.77 169.8 andradite 0.1509 -0.821 76.70 1.885 5.163 19.93 grossular 0.3655E-01 -1.437 16.46 1.217 1.108 4.581 apatite-OH 0.2683E-02 -2.571 1.348 0.130 0.9071E-01 0.4282 clinochlore 0.1941 -0.712 107.9 2.033 7.263 41.04 daphnite 0.5620E-01 -1.250 40.10 1.603 2.699 12.15 chlorite-Mn 0.4716E-02 -2.326 3.344 0.524 0.2251 1.066 diopside 0.6471E-01 -1.189 14.01 1.147 0.9433 4.283 hedenbergite 0.1678E-01 -1.775 4.163 0.619 0.2803 1.140 microcline 0.2531 -0.597 70.45 1.848 4.742 27.52 stilbite 0.8826 -0.054 622.0 2.794 41.87 290.1 stilpnomelane-Fe 0.7098E-01 -1.149 76.52 1.884 5.151 26.43 tr.625ac.25prg.125 0.1213E-01 -1.916 10.37 1.016 0.6981 3.338 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8050E+00 0.8050E+00 1.0000 -0.094 grossular 0.1950E+00 0.1950E+00 1.0000 -0.710 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.7612E+00 0.7612E+00 1.0000 -0.119 daphnite 0.2203E+00 0.2203E+00 1.0000 -0.657 chlorite-Mn 0.1849E-01 0.1849E-01 1.0000 -1.733 diopside 0.7941E+00 0.7941E+00 1.0000 -0.100 hedenbergite 0.2059E+00 0.2059E+00 1.0000 -0.686 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 tr.625ac.25prg.125 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 1485.613682 g Volume = 601.786322 cm3 Porosity: -10.4196% V(tot) - V(min): -.56787E+02 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 1359.9990000 g log = 3.1335 Original solution: 1000.0103000 g Original solution / Rock added: 0.74 (Water/Rock Ratio), log = -0.1335 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0568 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9659E+00 0.9855 0.1006E+01 0.1021E+01 CO2,gas 0.3705E-08 1.0069 0.3943E-08 0.3916E-08 CH4,gas 0.1968E-01 1.0124 0.2106E-01 0.2080E-01 H2,gas 0.1438E-01 1.0006 0.1521E-01 0.1520E-01 H2S,gas 0.1480E-06 0.9959 0.1558E-06 0.1564E-06 S2,gas 0.3727E-29 1.0000 0.3939E-29 0.3939E-29 CO,gas 0.1512E-13 1.0000 0.1598E-13 0.1598E-13 SO3,gas 0.7681E-48 1.0000 0.8118E-48 0.8118E-48 SO2,gas 0.4545E-27 1.0000 0.4803E-27 0.4803E-27 HCl,gas 0.3021E-17 1.0000 0.3193E-17 0.3193E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 16 albite -0.38 -0.38 0.00 0.000 -0.94784E-12 22 andradite 39.01 39.01 0.00 0.000 -0.36397E-10 23 grossular 32.73 32.73 0.00 0.000 0.12132E-10 32 apatite-OH -18.15 -18.15 0.00 0.000 0.60662E-11 46 clinochlore 39.07 39.07 0.00 0.000 0.12132E-10 47 daphnite 28.97 28.97 0.00 0.000 -0.60662E-11 48 chlorite-Mn 46.87 46.87 0.00 0.000 0.36397E-10 67 diopside 16.18 16.18 0.00 0.000 0.60662E-11 68 hedenbergite 14.21 14.21 0.00 0.000 0.60662E-11 116 microcline -2.49 -2.49 0.00 0.000 0.15165E-11 163 stilbite -7.52 -7.52 0.00 0.000 -0.90992E-11 164 stilpnomelane-Fe 13.02 13.02 0.00 0.000 0.21232E-10 245 tr.625ac.25prg.125 45.16 45.16 0.00 0.000 -0.12132E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -16.76 -10.10 -3.368 0.17251E+05 -8.404 3 CH4,gas 4.54 1.17 -3.38 -0.844 0.57635E+04 -1.677 4 H2,gas 8.00 4.48 -3.52 -2.010 0.60050E+04 -1.818 5 H2S,gas -6.23 -14.74 -8.51 -4.253 0.14524E+05 -6.807 6 S2,gas -7.34 -38.44 -31.10 -4.785 0.53109E+05 -29.405 7 CO,gas 3.21 -12.28 -15.50 -4.768 0.26458E+05 -13.796 8 SO3,gas 17.12 -32.67 -49.79 -12.447 0.85014E+05 -48.091 9 SO2,gas 0.83 -28.19 -29.02 -7.738 0.49546E+05 -27.318 10 HCl,gas 5.19 -14.01 -19.19 -9.597 0.32775E+05 -17.496 11 acmite 7.71 6.53 -1.18 -0.123 0.20176E+04 15 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 19 spessartine 24.46 19.72 -4.73 -0.237 0.80814E+04 20 analcite 3.32 2.77 -0.55 -0.061 0.93621E+03 26 annite 20.12 17.72 -2.40 -0.134 0.41064E+04 27 phlogopite 27.06 25.40 -1.67 -0.093 0.28488E+04 29 anorthite 12.71 8.27 -4.45 -0.342 0.75901E+04 35 aragonite 0.97 -3.66 -4.63 -1.543 0.79021E+04 36 brucite 12.57 9.29 -3.27 -0.655 0.55909E+04 37 calcite 0.81 -3.66 -4.47 -1.491 0.76379E+04 38 carnegieite-low 9.02 5.93 -3.09 -0.442 0.52800E+04 39 carnegieite-high 10.09 5.93 -4.16 -0.595 0.71070E+04 40 carpholite-Mg 8.58 4.46 -4.12 -0.275 0.70427E+04 41 carpholite-Fe 6.71 1.90 -4.81 -0.321 0.82205E+04 42 celadonite 5.34 3.65 -1.69 -0.099 0.28879E+04 43 celadonite-Fe 3.88 1.09 -2.79 -0.164 0.47561E+04 44 chrysotile 23.89 21.57 -2.32 -0.194 0.39692E+04 49 chlorite-Al-free 47.17 43.14 -4.04 -0.168 0.68935E+04 51 chloritoid-Fe 9.17 5.06 -4.12 -0.275 0.70313E+04 52 chloritoid-Mn 11.40 7.56 -3.84 -0.256 0.65582E+04 54 coesite -2.38 -3.16 -0.78 -0.260 0.13342E+04 61 cristobalite -2.56 -3.16 -0.60 -0.199 0.10195E+04 63 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71234E+04 65 diaspore 2.87 0.74 -2.13 -0.356 0.36449E+04 66 diamond -3.10 -7.80 -4.70 -1.341 0.80169E+04 71 enstatite 17.26 12.27 -4.99 -0.499 0.85225E+04 73 clinoenstatite 17.17 12.27 -4.89 -0.489 0.83541E+04 75 epidote 24.67 22.70 -1.97 -0.095 0.33583E+04 76 clinozoisite 22.81 18.95 -3.86 -0.175 0.65865E+04 77 epidote-Fe 29.84 26.46 -3.38 -0.176 0.57768E+04 78 fayalite 14.05 10.31 -3.73 -0.533 0.63743E+04 79 ferrosilite 11.15 7.16 -3.99 -0.399 0.68202E+04 83 gibbsite 4.08 0.74 -3.34 -0.477 0.57034E+04 84 glaucophane 22.97 20.80 -2.17 -0.059 0.37133E+04 85 glaucophane-Fe 17.28 13.12 -4.15 -0.112 0.70919E+04 86 graphite -3.55 -7.80 -4.25 -1.215 0.72591E+04 87 greenalite 16.14 13.89 -2.25 -0.187 0.38408E+04 90 hematite 12.57 8.99 -3.58 -0.434 0.61112E+04 91 heulandite -5.83 -7.52 -1.69 -0.077 0.28938E+04 95 jadeite 4.22 2.77 -1.44 -0.144 0.24617E+04 97 kalsilite 7.58 3.83 -3.76 -0.537 0.64125E+04 98 kaolinite -1.33 -4.84 -3.50 -0.319 0.59830E+04 101 laumontite 2.88 1.95 -0.93 -0.062 0.15934E+04 102 lawsonite 9.62 8.27 -1.35 -0.090 0.23068E+04 103 leucite 4.12 0.67 -3.45 -0.345 0.58872E+04 105 lizardite 23.24 21.57 -1.68 -0.140 0.28618E+04 107 magnetite 20.09 15.72 -4.37 -0.356 0.74537E+04 108 minnesotaite 10.39 7.58 -2.81 -0.165 0.48029E+04 112 manganosite 14.06 9.24 -4.82 -1.205 0.82276E+04 120 muscovite 2.58 -1.01 -3.59 -0.211 0.61313E+04 121 paragonite 4.24 1.09 -3.15 -0.185 0.53704E+04 122 nepheline 8.34 5.93 -2.41 -0.344 0.41124E+04 128 periclase-Fe 11.63 6.73 -4.89 -1.223 0.83523E+04 134 phlogopite-Na 29.65 27.50 -2.15 -0.119 0.36676E+04 136 prehnite 19.37 18.21 -1.16 -0.068 0.19847E+04 137 prehnite-Fe 22.50 21.96 -0.53 -0.032 0.91153E+03 138 pumpellyite-Fe 46.27 43.89 -2.38 -0.053 0.40576E+04 139 pumpellyite-Mg 48.99 46.45 -2.54 -0.057 0.43414E+04 143 pyrrhotite -4.26 -8.00 -3.74 -1.247 0.63883E+04 144 pyrrhotiteFe0.875 -6.02 -9.40 -3.38 -1.244 0.57755E+04 145 pyroxmangite 7.40 6.08 -1.32 -0.263 0.22480E+04 146 pyrophyllite -6.18 -11.15 -4.98 -0.311 0.84961E+04 147 quartz -2.99 -3.16 -0.17 -0.056 0.28684E+03 152 rhodonite 7.45 6.08 -1.36 -0.273 0.23283E+04 153 sanidine -1.28 -2.49 -1.21 -0.093 0.20677E+04 165 stilpnomelane-Mg 27.44 25.81 -1.63 -0.049 0.27802E+04 171 talc 16.49 15.25 -1.24 -0.073 0.21141E+04 174 tephroite 18.09 15.32 -2.76 -0.395 0.47198E+04 178 tridymite -2.63 -3.16 -0.53 -0.177 0.90682E+03 179 tremolite 47.87 47.42 -0.45 -0.012 0.77496E+03 180 ferroactinolite 38.45 34.62 -3.83 -0.104 0.65450E+04 181 troilite-low -4.41 -8.00 -3.59 -1.197 0.61311E+04 183 vesuvianite 223.47 218.82 -4.65 -0.036 0.79423E+04 187 wairakite 3.95 1.95 -2.00 -0.118 0.34153E+04 188 walstromite 11.51 9.94 -1.56 -0.313 0.26719E+04 189 wollastonite 10.46 9.94 -0.52 -0.103 0.88229E+03 190 pseudo-wollastonite 11.00 9.94 -1.06 -0.211 0.18021E+04 191 zoisite 22.85 18.95 -3.90 -0.177 0.66606E+04 192 akaganeite 7.75 4.49 -3.26 -0.705 0.55681E+04 199 chalcedony -2.80 -3.16 -0.35 -0.118 0.60614E+03 201 montmorillonite-Ca -2.29 -6.17 -3.88 -0.240 0.66180E+04 202 montmorillonite-K -2.24 -6.27 -4.03 -0.247 0.68816E+04 203 montmorillonite-Mg -2.48 -6.79 -4.31 -0.267 0.73677E+04 204 montmorillonite-Na -2.04 -5.57 -3.54 -0.216 0.60365E+04 205 nontronite-Ca 3.21 -0.19 -3.41 -0.221 0.58217E+04 206 nontronite-H 2.53 -2.36 -4.89 -0.328 0.83487E+04 207 nontronite-K 3.34 -0.30 -3.64 -0.233 0.62085E+04 208 nontronite-Mg 3.07 -0.82 -3.90 -0.253 0.66555E+04 209 nontronite-Na 3.52 0.40 -3.12 -0.200 0.53293E+04 224 tobermorite 9.82 7.76 -2.07 -0.564 0.35287E+04 230 alabandite -0.98 -5.50 -4.52 -1.506 0.77165E+04 233 boehmite 4.41 0.74 -3.67 -0.611 0.62618E+04 235 ferrous-oxide 9.81 6.73 -3.08 -0.769 0.52532E+04 240 silica-amorphous -2.09 -3.16 -1.07 -0.355 0.18203E+04 242 an20ab80 2.02 1.35 -0.67 -0.052 0.11472E+04 243 an25ab75 2.65 1.78 -0.87 -0.067 0.14809E+04 244 an30ab70 3.28 2.21 -1.07 -0.082 0.18243E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 40.0000000 g Current total amount of reactant added: 1359.9990000 g New total amount of reactant added: 1399.9990000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.3297E-10 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 11 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 1399.9990000 Water: Moles liquid = 0.4762E+02 kg liquid = 0.8579E+00 Moles total = 0.3796E+02 kg total = 0.6838E+00 Activity = 1.0000 Stoichiometric ionic strength = .1133647E-01 Osmotic coef. = 0.9693 True ionic strength = .2002268E-01 Chg. balance for total moles = 0.3297E-10 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.88312E-10 -10.0540 0.74203E-10 -10.1296 0.84024E+00 -0.0756 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.16010E-03 -3.7956 0.13371E-03 -3.8738 0.83519E+00 -0.0782 4 SO4-- 0.75445E-12 -12.1224 0.39177E-12 -12.4070 0.51928E+00 -0.2846 5 HCO3- 0.27918E-06 -6.5541 0.23351E-06 -6.6317 0.83641E+00 -0.0776 6 HS- 0.29724E-04 -4.5269 0.24829E-04 -4.6050 0.83531E+00 -0.0782 7 Al+++ 0.96983E-29 -29.0133 0.22403E-29 -29.6497 0.23100E+00 -0.6364 8 H4SiO4 0.69594E-03 -3.1574 0.69594E-03 -3.1574 0.10000E+01 0.0000 9 Ca++ 0.13505E-06 -6.8695 0.69614E-07 -7.1573 0.51547E+00 -0.2878 10 Mg++ 0.21128E-10 -10.6751 0.10841E-10 -10.9649 0.51311E+00 -0.2898 11 Fe++ 0.58230E-13 -13.2349 0.29911E-13 -13.5242 0.51367E+00 -0.2893 12 K+ 0.15655E-03 -3.8054 0.13097E-03 -3.8828 0.83661E+00 -0.0775 13 Na+ 0.19865E-01 -1.7019 0.16588E-01 -1.7802 0.83504E+00 -0.0783 14 Mn++ 0.18595E-10 -10.7306 0.95596E-11 -11.0196 0.51410E+00 -0.2890 15 HPO4-- 0.45301E-07 -7.3439 0.23527E-07 -7.6284 0.51935E+00 -0.2845 16 HSiO3- 0.10486E-01 -1.9794 0.87574E-02 -2.0576 0.83519E+00 -0.0782 17 Ca(HSiO3)+ 0.16592E-07 -7.7801 0.13884E-07 -7.8575 0.83679E+00 -0.0774 18 Mg(HSiO3)+ 0.32156E-11 -11.4927 0.26908E-11 -11.5701 0.83679E+00 -0.0774 19 NaHSiO3,aq 0.23495E-02 -2.6290 0.23495E-02 -2.6290 0.10000E+01 0.0000 20 AlO+ 0.66149E-16 -16.1795 0.55353E-16 -16.2569 0.83679E+00 -0.0774 22 HAlO2,aq 0.14856E-09 -9.8281 0.14856E-09 -9.8281 0.10000E+01 0.0000 23 AlO2- 0.53158E-05 -5.2744 0.44317E-05 -5.3534 0.83368E+00 -0.0790 24 CH4,aq 0.14425E-04 -4.8409 0.14376E-04 -4.8424 0.99654E+00 -0.0015 25 C2H6,aq 0.30604E-14 -14.5142 0.30498E-14 -14.5157 0.99654E+00 -0.0015 29 CO,aq 0.10774E-16 -16.9676 0.10774E-16 -16.9676 0.10000E+01 0.0000 30 CO2,aq 0.37153E-10 -10.4300 0.37024E-10 -10.4315 0.99654E+00 -0.0015 31 CO3-2 0.53046E-06 -6.2753 0.27487E-06 -6.5609 0.51818E+00 -0.2855 32 CaCO3,aq 0.23993E-09 -9.6199 0.23993E-09 -9.6199 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.49588E-12 -12.3046 0.41494E-12 -12.3820 0.83679E+00 -0.0774 34 CaCl+ 0.18002E-10 -10.7447 0.15064E-10 -10.8221 0.83679E+00 -0.0774 35 CaCl2,aq 0.47853E-15 -15.3201 0.47853E-15 -15.3201 0.10000E+01 0.0000 36 CaOH+ 0.79903E-07 -7.0974 0.66862E-07 -7.1748 0.83679E+00 -0.0774 37 CaSO4,aq 0.86603E-17 -17.0625 0.86603E-17 -17.0625 0.10000E+01 0.0000 38 HCl,aq 0.18181E-14 -14.7404 0.18181E-14 -14.7404 0.10000E+01 0.0000 43 FeCl+ 0.75652E-17 -17.1212 0.63305E-17 -17.1986 0.83679E+00 -0.0774 46 FeO,aq 0.21113E-09 -9.6754 0.21113E-09 -9.6754 0.10000E+01 0.0000 47 FeOH+ 0.15680E-10 -10.8046 0.13121E-10 -10.8820 0.83679E+00 -0.0774 48 HFeO2- 0.35646E-07 -7.4480 0.29771E-07 -7.5262 0.83519E+00 -0.0782 49 FeO+ 0.10989E-16 -16.9590 0.91954E-17 -17.0364 0.83679E+00 -0.0774 51 FeO2- 0.40916E-09 -9.3881 0.34172E-09 -9.4663 0.83519E+00 -0.0782 52 HFeO2,aq 0.32250E-11 -11.4915 0.32250E-11 -11.4915 0.10000E+01 0.0000 53 H2,aq 0.11624E-04 -4.9346 0.11584E-04 -4.9361 0.99654E+00 -0.0015 54 KCl,aq 0.31739E-09 -9.4984 0.31739E-09 -9.4984 0.10000E+01 0.0000 56 KOH,aq 0.75375E-06 -6.1228 0.75375E-06 -6.1228 0.10000E+01 0.0000 57 KSO4- 0.95331E-15 -15.0208 0.79619E-15 -15.0990 0.83519E+00 -0.0782 58 MgCO3,aq 0.93655E-14 -14.0285 0.93655E-14 -14.0285 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.78907E-16 -16.1029 0.66028E-16 -16.1803 0.83679E+00 -0.0774 60 MgCl+ 0.25408E-14 -14.5950 0.21261E-14 -14.6724 0.83679E+00 -0.0774 61 MgOH+ 0.68854E-10 -10.1621 0.57616E-10 -10.2395 0.83679E+00 -0.0774 63 MnO,aq 0.17980E-08 -8.7452 0.17980E-08 -8.7452 0.10000E+01 0.0000 64 MnOH+ 0.46555E-09 -9.3320 0.38957E-09 -9.4094 0.83679E+00 -0.0774 65 MnO2-2 0.20914E-10 -10.6796 0.10837E-10 -10.9651 0.51818E+00 -0.2855 66 HMnO2- 0.21094E-09 -9.6758 0.17618E-09 -9.7541 0.83519E+00 -0.0782 69 MnCl+ 0.94066E-14 -14.0266 0.78713E-14 -14.1040 0.83679E+00 -0.0774 71 NaCl,aq 0.73505E-06 -6.1337 0.73505E-06 -6.1337 0.10000E+01 0.0000 72 NaOH,aq 0.96047E-04 -4.0175 0.96047E-04 -4.0175 0.10000E+01 0.0000 74 OH- 0.93398E-02 -2.0297 0.77864E-02 -2.1087 0.83368E+00 -0.0790 79 HPO3-2 0.16391E-14 -14.7854 0.84932E-15 -15.0709 0.51818E+00 -0.2855 81 H2PO3- 0.15132E-18 -18.8201 0.12638E-18 -18.8983 0.83519E+00 -0.0782 82 H3PO4,aq 0.90602E-18 -18.0429 0.90602E-18 -18.0429 0.10000E+01 0.0000 83 H2PO4- 0.38524E-10 -10.4143 0.32205E-10 -10.4921 0.83598E+00 -0.0778 84 PO4-3 0.10662E-08 -8.9722 0.25869E-09 -9.5872 0.24262E+00 -0.6151 88 HP2O7-3 0.94640E-18 -18.0239 0.21884E-18 -18.6599 0.23123E+00 -0.6360 89 P2O7-4 0.91393E-17 -17.0391 0.70455E-18 -18.1521 0.77090E-01 -1.1130 90 H2S,aq 0.57139E-08 -8.2431 0.56941E-08 -8.2446 0.99654E+00 -0.0015 91 S2-2 0.22757E-14 -14.6429 0.11792E-14 -14.9284 0.51818E+00 -0.2855 97 SO3-2 0.11219E-17 -17.9501 0.58974E-18 -18.2293 0.52567E+00 -0.2793 99 HSO4- 0.33447E-19 -19.4756 0.28016E-19 -19.5526 0.83760E+00 -0.0770 Charge balance for all species = 0.3843E-10 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.8831201E-10 -.2229658E-01 -.2243455E+02 0.0000 2 H2O 0.1000000E+01 0.5550489E+02 0.9981993E+06 0.0000 3 Cl- 0.1600981E-03 0.1608335E-03 0.5692118E+01 6.2557 4 SO4-- 0.7544462E-12 -.1733150E-04 -.1661998E+01 7.8522 5 HCO3- 0.2791829E-06 0.1523541E-04 0.9280064E+00 3.4979 6 HS- 0.2972428E-04 0.4706149E-04 0.1553713E+01 5.5245 7 Al+++ 0.9698278E-29 0.5315948E-05 0.1431830E+00 0.7390 8 H4SiO4 0.6959414E-03 0.1353106E-01 0.1298283E+04 -3.1574 9 Ca++ 0.1350515E-06 0.2318052E-06 0.9274140E-02 13.1019 10 Mg++ 0.2112796E-10 0.9320998E-10 0.2262182E-05 9.2942 11 Fe++ 0.5823014E-13 0.3628477E-07 0.2022874E-02 6.7350 12 K+ 0.1565472E-03 0.1573013E-03 0.6140104E+01 6.2467 13 Na+ 0.1986505E-01 0.2231135E-01 0.5120419E+03 8.3494 14 Mn++ 0.1859505E-10 0.2514003E-08 0.1378743E-03 9.2396 15 HPO4-- 0.4530100E-07 0.4640576E-07 0.4446237E-02 12.6307 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.2318189E+02 -.1912756E-01 -.2316276E+02 0.0000000E+00 2 H2O 0.3795869E+02 0.4761597E+02 -.9657286E+01 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.3882425E-01 -.1486817E-04 0.3883912E-01 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.3879874E-01 0.4037264E-04 -.3883912E-01 0.0000000E+00 7 Al+++ 0.4565035E+01 0.4560392E-05 0.4565030E+01 0.0000000E+00 8 H4SiO4 0.1457789E+02 0.1160789E-01 0.1456628E+02 0.0000000E+00 9 Ca++ 0.1610213E+01 0.1988587E-06 0.1610213E+01 0.0000000E+00 10 Mg++ 0.1111110E+01 0.7996204E-10 0.1111110E+01 0.0000000E+00 11 Fe++ 0.9982113E+00 0.3112762E-07 0.9982113E+00 0.0000000E+00 12 K+ 0.2972397E+00 0.1349440E-03 0.2971048E+00 0.0000000E+00 13 Na+ 0.1757500E+01 0.1914023E-01 0.1738360E+01 0.0000000E+00 14 Mn++ 0.2427402E-01 0.2156688E-08 0.2427401E-01 0.0000000E+00 15 HPO4-- 0.8284601E-02 0.3981010E-07 0.8284562E-02 0.0000000E+00 Chg. balance for solid moles: 0.2248E-14 Mass of aqueous solution: 0.859364E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 1399.9990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 1.737 0.240 455.4 2.658 29.78 174.8 andradite 0.1554 -0.809 78.95 1.897 5.162 20.51 grossular 0.3763E-01 -1.425 16.95 1.229 1.108 4.716 apatite-OH 0.2762E-02 -2.559 1.387 0.142 0.9071E-01 0.4408 clinochlore 0.1998 -0.699 111.1 2.046 7.262 42.24 daphnite 0.5784E-01 -1.238 41.27 1.616 2.699 12.51 chlorite-Mn 0.4855E-02 -2.314 3.442 0.537 0.2251 1.097 diopside 0.6689E-01 -1.175 14.49 1.161 0.9472 4.427 hedenbergite 0.1735E-01 -1.761 4.303 0.634 0.2814 1.179 microcline 0.2606 -0.584 72.53 1.860 4.742 28.33 stilbite 0.9083 -0.042 640.1 2.806 41.85 298.6 stilpnomelane-Fe 0.7307E-01 -1.136 78.77 1.896 5.151 27.21 tr.625ac.25prg.125 0.1247E-01 -1.904 10.66 1.028 0.6968 3.430 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8050E+00 0.8050E+00 1.0000 -0.094 grossular 0.1950E+00 0.1950E+00 1.0000 -0.710 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.7612E+00 0.7612E+00 1.0000 -0.119 daphnite 0.2203E+00 0.2203E+00 1.0000 -0.657 chlorite-Mn 0.1849E-01 0.1849E-01 1.0000 -1.733 diopside 0.7941E+00 0.7941E+00 1.0000 -0.100 hedenbergite 0.2059E+00 0.2059E+00 1.0000 -0.686 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 tr.625ac.25prg.125 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 1529.313947 g Volume = 619.467548 cm3 Porosity: -10.4221% V(tot) - V(min): -.58468E+02 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 1399.9990000 g log = 3.1461 Original solution: 1000.0103000 g Original solution / Rock added: 0.71 (Water/Rock Ratio), log = -0.1461 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0569 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9658E+00 0.9855 0.1006E+01 0.1021E+01 CO2,gas 0.3722E-08 1.0069 0.3961E-08 0.3934E-08 CH4,gas 0.1977E-01 1.0124 0.2116E-01 0.2090E-01 H2,gas 0.1438E-01 1.0006 0.1521E-01 0.1520E-01 H2S,gas 0.1487E-06 0.9959 0.1565E-06 0.1572E-06 S2,gas 0.3762E-29 1.0000 0.3976E-29 0.3976E-29 CO,gas 0.1519E-13 1.0000 0.1606E-13 0.1606E-13 SO3,gas 0.7717E-48 1.0000 0.8156E-48 0.8156E-48 SO2,gas 0.4566E-27 1.0000 0.4826E-27 0.4826E-27 HCl,gas 0.3035E-17 1.0000 0.3208E-17 0.3208E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 16 albite -0.38 -0.38 0.00 0.000 -0.94784E-12 22 andradite 39.01 39.01 0.00 0.000 0.00000E+00 23 grossular 32.73 32.73 0.00 0.000 0.00000E+00 32 apatite-OH -18.15 -18.15 0.00 0.000 0.00000E+00 46 clinochlore 39.07 39.07 0.00 0.000 0.12132E-10 47 daphnite 28.97 28.97 0.00 0.000 0.18198E-10 48 chlorite-Mn 46.87 46.87 0.00 0.000 0.24265E-10 67 diopside 16.18 16.18 0.00 0.000 0.00000E+00 68 hedenbergite 14.21 14.21 0.00 0.000 0.60662E-11 116 microcline -2.49 -2.49 0.00 0.000 0.15165E-11 163 stilbite -7.52 -7.52 0.00 0.000 0.15165E-10 164 stilpnomelane-Fe 13.02 13.02 0.00 0.000 0.21232E-10 245 tr.625ac.25prg.125 45.16 45.16 0.00 0.000 -0.36397E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -16.76 -10.10 -3.367 0.17247E+05 -8.402 3 CH4,gas 4.54 1.17 -3.37 -0.843 0.57601E+04 -1.674 4 H2,gas 8.00 4.48 -3.52 -2.010 0.60050E+04 -1.818 5 H2S,gas -6.23 -14.73 -8.50 -4.252 0.14521E+05 -6.805 6 S2,gas -7.34 -38.43 -31.10 -4.785 0.53102E+05 -29.401 7 CO,gas 3.21 -12.28 -15.49 -4.767 0.26454E+05 -13.794 8 SO3,gas 17.12 -32.67 -49.79 -12.447 0.85011E+05 -48.089 9 SO2,gas 0.83 -28.18 -29.02 -7.737 0.49543E+05 -27.316 10 HCl,gas 5.19 -14.00 -19.19 -9.596 0.32771E+05 -17.494 11 acmite 7.71 6.53 -1.18 -0.123 0.20176E+04 15 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 19 spessartine 24.46 19.72 -4.73 -0.237 0.80810E+04 20 analcite 3.32 2.77 -0.55 -0.061 0.93621E+03 26 annite 20.12 17.72 -2.40 -0.134 0.41064E+04 27 phlogopite 27.06 25.40 -1.67 -0.093 0.28488E+04 29 anorthite 12.71 8.27 -4.45 -0.342 0.75901E+04 35 aragonite 0.97 -3.66 -4.63 -1.542 0.78987E+04 36 brucite 12.57 9.29 -3.27 -0.655 0.55909E+04 37 calcite 0.81 -3.66 -4.47 -1.490 0.76344E+04 38 carnegieite-low 9.02 5.93 -3.09 -0.442 0.52800E+04 39 carnegieite-high 10.09 5.93 -4.16 -0.595 0.71070E+04 40 carpholite-Mg 8.58 4.46 -4.12 -0.275 0.70427E+04 41 carpholite-Fe 6.71 1.90 -4.81 -0.321 0.82205E+04 42 celadonite 5.34 3.65 -1.69 -0.099 0.28879E+04 43 celadonite-Fe 3.88 1.09 -2.79 -0.164 0.47561E+04 44 chrysotile 23.89 21.57 -2.32 -0.194 0.39692E+04 49 chlorite-Al-free 47.17 43.14 -4.04 -0.168 0.68935E+04 51 chloritoid-Fe 9.17 5.06 -4.12 -0.275 0.70313E+04 52 chloritoid-Mn 11.40 7.56 -3.84 -0.256 0.65581E+04 54 coesite -2.38 -3.16 -0.78 -0.260 0.13342E+04 61 cristobalite -2.56 -3.16 -0.60 -0.199 0.10195E+04 63 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71234E+04 65 diaspore 2.87 0.74 -2.13 -0.356 0.36449E+04 66 diamond -3.10 -7.80 -4.69 -1.341 0.80134E+04 71 enstatite 17.26 12.27 -4.99 -0.499 0.85225E+04 73 clinoenstatite 17.17 12.27 -4.89 -0.489 0.83541E+04 75 epidote 24.67 22.70 -1.97 -0.095 0.33584E+04 76 clinozoisite 22.81 18.95 -3.86 -0.175 0.65865E+04 77 epidote-Fe 29.84 26.46 -3.38 -0.176 0.57768E+04 78 fayalite 14.05 10.31 -3.73 -0.533 0.63743E+04 79 ferrosilite 11.15 7.16 -3.99 -0.399 0.68202E+04 83 gibbsite 4.08 0.74 -3.34 -0.477 0.57034E+04 84 glaucophane 22.97 20.80 -2.17 -0.059 0.37133E+04 85 glaucophane-Fe 17.28 13.12 -4.15 -0.112 0.70919E+04 86 graphite -3.55 -7.80 -4.25 -1.214 0.72556E+04 87 greenalite 16.14 13.89 -2.25 -0.187 0.38408E+04 90 hematite 12.57 8.99 -3.58 -0.434 0.61112E+04 91 heulandite -5.83 -7.52 -1.69 -0.077 0.28938E+04 95 jadeite 4.22 2.77 -1.44 -0.144 0.24617E+04 97 kalsilite 7.58 3.83 -3.76 -0.537 0.64125E+04 98 kaolinite -1.33 -4.84 -3.50 -0.319 0.59830E+04 101 laumontite 2.88 1.95 -0.93 -0.062 0.15934E+04 102 lawsonite 9.62 8.27 -1.35 -0.090 0.23068E+04 103 leucite 4.12 0.67 -3.45 -0.345 0.58872E+04 105 lizardite 23.24 21.57 -1.68 -0.140 0.28618E+04 107 magnetite 20.09 15.72 -4.37 -0.356 0.74537E+04 108 minnesotaite 10.39 7.58 -2.81 -0.165 0.48029E+04 112 manganosite 14.06 9.24 -4.82 -1.205 0.82275E+04 120 muscovite 2.58 -1.01 -3.59 -0.211 0.61313E+04 121 paragonite 4.24 1.09 -3.15 -0.185 0.53704E+04 122 nepheline 8.34 5.93 -2.41 -0.344 0.41124E+04 128 periclase-Fe 11.63 6.73 -4.89 -1.223 0.83523E+04 134 phlogopite-Na 29.65 27.50 -2.15 -0.119 0.36676E+04 136 prehnite 19.37 18.21 -1.16 -0.068 0.19847E+04 137 prehnite-Fe 22.50 21.96 -0.53 -0.032 0.91153E+03 138 pumpellyite-Fe 46.27 43.89 -2.38 -0.053 0.40576E+04 139 pumpellyite-Mg 48.99 46.45 -2.54 -0.057 0.43414E+04 143 pyrrhotite -4.26 -8.00 -3.74 -1.246 0.63848E+04 144 pyrrhotiteFe0.875 -6.02 -9.40 -3.38 -1.243 0.57720E+04 145 pyroxmangite 7.40 6.08 -1.32 -0.263 0.22479E+04 146 pyrophyllite -6.18 -11.15 -4.98 -0.311 0.84961E+04 147 quartz -2.99 -3.16 -0.17 -0.056 0.28684E+03 152 rhodonite 7.45 6.08 -1.36 -0.273 0.23282E+04 153 sanidine -1.28 -2.49 -1.21 -0.093 0.20677E+04 165 stilpnomelane-Mg 27.44 25.81 -1.63 -0.049 0.27802E+04 171 talc 16.49 15.25 -1.24 -0.073 0.21141E+04 174 tephroite 18.09 15.32 -2.76 -0.395 0.47195E+04 178 tridymite -2.63 -3.16 -0.53 -0.177 0.90682E+03 179 tremolite 47.87 47.42 -0.45 -0.012 0.77496E+03 180 ferroactinolite 38.45 34.62 -3.83 -0.104 0.65450E+04 181 troilite-low -4.41 -8.00 -3.59 -1.196 0.61276E+04 183 vesuvianite 223.47 218.82 -4.65 -0.036 0.79424E+04 187 wairakite 3.95 1.95 -2.00 -0.118 0.34153E+04 188 walstromite 11.51 9.94 -1.56 -0.313 0.26719E+04 189 wollastonite 10.46 9.94 -0.52 -0.103 0.88229E+03 190 pseudo-wollastonite 11.00 9.94 -1.06 -0.211 0.18021E+04 191 zoisite 22.85 18.95 -3.90 -0.177 0.66606E+04 192 akaganeite 7.75 4.49 -3.26 -0.705 0.55681E+04 199 chalcedony -2.80 -3.16 -0.35 -0.118 0.60614E+03 201 montmorillonite-Ca -2.29 -6.17 -3.88 -0.240 0.66180E+04 202 montmorillonite-K -2.24 -6.27 -4.03 -0.247 0.68816E+04 203 montmorillonite-Mg -2.48 -6.79 -4.31 -0.267 0.73677E+04 204 montmorillonite-Na -2.04 -5.57 -3.54 -0.216 0.60365E+04 205 nontronite-Ca 3.21 -0.19 -3.41 -0.221 0.58216E+04 206 nontronite-H 2.53 -2.36 -4.89 -0.328 0.83486E+04 207 nontronite-K 3.34 -0.30 -3.64 -0.233 0.62085E+04 208 nontronite-Mg 3.07 -0.82 -3.90 -0.253 0.66555E+04 209 nontronite-Na 3.52 0.40 -3.12 -0.200 0.53293E+04 224 tobermorite 9.82 7.76 -2.07 -0.564 0.35287E+04 230 alabandite -0.98 -5.50 -4.52 -1.506 0.77129E+04 233 boehmite 4.41 0.74 -3.67 -0.611 0.62618E+04 235 ferrous-oxide 9.81 6.73 -3.08 -0.769 0.52532E+04 240 silica-amorphous -2.09 -3.16 -1.07 -0.355 0.18203E+04 242 an20ab80 2.02 1.35 -0.67 -0.052 0.11472E+04 243 an25ab75 2.65 1.78 -0.87 -0.067 0.14809E+04 244 an30ab70 3.28 2.21 -1.07 -0.082 0.18243E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 40.0000000 g Current total amount of reactant added: 1399.9990000 g New total amount of reactant added: 1439.9990000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.3298E-10 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 11 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 1439.9990000 Water: Moles liquid = 0.4740E+02 kg liquid = 0.8539E+00 Moles total = 0.3746E+02 kg total = 0.6748E+00 Activity = 1.0000 Stoichiometric ionic strength = .1133710E-01 Osmotic coef. = 0.9693 True ionic strength = .2002318E-01 Chg. balance for total moles = 0.3298E-10 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.88314E-10 -10.0540 0.74205E-10 -10.1296 0.84024E+00 -0.0756 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.16085E-03 -3.7936 0.13434E-03 -3.8718 0.83519E+00 -0.0782 4 SO4-- 0.75800E-12 -12.1203 0.39361E-12 -12.4049 0.51927E+00 -0.2846 5 HCO3- 0.28050E-06 -6.5521 0.23461E-06 -6.6297 0.83641E+00 -0.0776 6 HS- 0.29864E-04 -4.5249 0.24946E-04 -4.6030 0.83531E+00 -0.0782 7 Al+++ 0.96990E-29 -29.0133 0.22405E-29 -29.6497 0.23100E+00 -0.6364 8 H4SiO4 0.69594E-03 -3.1574 0.69594E-03 -3.1574 0.10000E+01 0.0000 9 Ca++ 0.13506E-06 -6.8695 0.69617E-07 -7.1573 0.51546E+00 -0.2878 10 Mg++ 0.21129E-10 -10.6751 0.10841E-10 -10.9649 0.51310E+00 -0.2898 11 Fe++ 0.58233E-13 -13.2348 0.29912E-13 -13.5241 0.51367E+00 -0.2893 12 K+ 0.15655E-03 -3.8053 0.13097E-03 -3.8828 0.83661E+00 -0.0775 13 Na+ 0.19866E-01 -1.7019 0.16588E-01 -1.7802 0.83503E+00 -0.0783 14 Mn++ 0.18599E-10 -10.7305 0.95617E-11 -11.0195 0.51409E+00 -0.2890 15 HPO4-- 0.45299E-07 -7.3439 0.23526E-07 -7.6284 0.51935E+00 -0.2845 16 HSiO3- 0.10485E-01 -1.9794 0.87572E-02 -2.0576 0.83519E+00 -0.0782 17 Ca(HSiO3)+ 0.16592E-07 -7.7801 0.13884E-07 -7.8575 0.83679E+00 -0.0774 18 Mg(HSiO3)+ 0.32157E-11 -11.4927 0.26908E-11 -11.5701 0.83679E+00 -0.0774 19 NaHSiO3,aq 0.23495E-02 -2.6290 0.23495E-02 -2.6290 0.10000E+01 0.0000 20 AlO+ 0.66151E-16 -16.1795 0.55354E-16 -16.2569 0.83679E+00 -0.0774 22 HAlO2,aq 0.14856E-09 -9.8281 0.14856E-09 -9.8281 0.10000E+01 0.0000 23 AlO2- 0.53157E-05 -5.2744 0.44315E-05 -5.3534 0.83368E+00 -0.0790 24 CH4,aq 0.14493E-04 -4.8388 0.14443E-04 -4.8403 0.99654E+00 -0.0015 25 C2H6,aq 0.30893E-14 -14.5101 0.30786E-14 -14.5116 0.99654E+00 -0.0015 29 CO,aq 0.10825E-16 -16.9656 0.10825E-16 -16.9656 0.10000E+01 0.0000 30 CO2,aq 0.37328E-10 -10.4280 0.37199E-10 -10.4295 0.99654E+00 -0.0015 31 CO3-2 0.53294E-06 -6.2733 0.27616E-06 -6.5588 0.51817E+00 -0.2855 32 CaCO3,aq 0.24106E-09 -9.6179 0.24106E-09 -9.6179 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.49823E-12 -12.3026 0.41691E-12 -12.3800 0.83679E+00 -0.0774 34 CaCl+ 0.18087E-10 -10.7426 0.15135E-10 -10.8200 0.83679E+00 -0.0774 35 CaCl2,aq 0.48306E-15 -15.3160 0.48306E-15 -15.3160 0.10000E+01 0.0000 36 CaOH+ 0.79905E-07 -7.0974 0.66863E-07 -7.1748 0.83679E+00 -0.0774 37 CaSO4,aq 0.87014E-17 -17.0604 0.87014E-17 -17.0604 0.10000E+01 0.0000 38 HCl,aq 0.18267E-14 -14.7383 0.18267E-14 -14.7383 0.10000E+01 0.0000 43 FeCl+ 0.76012E-17 -17.1191 0.63605E-17 -17.1965 0.83679E+00 -0.0774 46 FeO,aq 0.21113E-09 -9.6755 0.21113E-09 -9.6755 0.10000E+01 0.0000 47 FeOH+ 0.15681E-10 -10.8046 0.13121E-10 -10.8820 0.83679E+00 -0.0774 48 HFeO2- 0.35645E-07 -7.4480 0.29770E-07 -7.5262 0.83519E+00 -0.0782 49 FeO+ 0.10989E-16 -16.9590 0.91956E-17 -17.0364 0.83679E+00 -0.0774 51 FeO2- 0.40915E-09 -9.3881 0.34171E-09 -9.4663 0.83519E+00 -0.0782 52 HFeO2,aq 0.32250E-11 -11.4915 0.32250E-11 -11.4915 0.10000E+01 0.0000 53 H2,aq 0.11624E-04 -4.9346 0.11584E-04 -4.9361 0.99654E+00 -0.0015 54 KCl,aq 0.31889E-09 -9.4964 0.31889E-09 -9.4964 0.10000E+01 0.0000 56 KOH,aq 0.75375E-06 -6.1228 0.75375E-06 -6.1228 0.10000E+01 0.0000 57 KSO4- 0.95782E-15 -15.0187 0.79995E-15 -15.0969 0.83519E+00 -0.0782 58 MgCO3,aq 0.94097E-14 -14.0264 0.94097E-14 -14.0264 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.79281E-16 -16.1008 0.66341E-16 -16.1782 0.83679E+00 -0.0774 60 MgCl+ 0.25529E-14 -14.5930 0.21362E-14 -14.6704 0.83679E+00 -0.0774 61 MgOH+ 0.68856E-10 -10.1621 0.57618E-10 -10.2394 0.83679E+00 -0.0774 63 MnO,aq 0.17983E-08 -8.7451 0.17983E-08 -8.7451 0.10000E+01 0.0000 64 MnOH+ 0.46565E-09 -9.3319 0.38964E-09 -9.4093 0.83679E+00 -0.0774 65 MnO2-2 0.20917E-10 -10.6795 0.10838E-10 -10.9650 0.51817E+00 -0.2855 66 HMnO2- 0.21097E-09 -9.6758 0.17620E-09 -9.7540 0.83519E+00 -0.0782 69 MnCl+ 0.94529E-14 -14.0244 0.79101E-14 -14.1018 0.83679E+00 -0.0774 71 NaCl,aq 0.73853E-06 -6.1316 0.73853E-06 -6.1316 0.10000E+01 0.0000 72 NaOH,aq 0.96047E-04 -4.0175 0.96047E-04 -4.0175 0.10000E+01 0.0000 74 OH- 0.93396E-02 -2.0297 0.77862E-02 -2.1087 0.83368E+00 -0.0790 79 HPO3-2 0.16390E-14 -14.7854 0.84928E-15 -15.0709 0.51817E+00 -0.2855 81 H2PO3- 0.15132E-18 -18.8201 0.12638E-18 -18.8983 0.83519E+00 -0.0782 82 H3PO4,aq 0.90602E-18 -18.0429 0.90602E-18 -18.0429 0.10000E+01 0.0000 83 H2PO4- 0.38523E-10 -10.4143 0.32204E-10 -10.4921 0.83598E+00 -0.0778 84 PO4-3 0.10662E-08 -8.9722 0.25867E-09 -9.5872 0.24262E+00 -0.6151 88 HP2O7-3 0.94636E-18 -18.0239 0.21883E-18 -18.6599 0.23123E+00 -0.6360 89 P2O7-4 0.91387E-17 -17.0391 0.70449E-18 -18.1521 0.77088E-01 -1.1130 90 H2S,aq 0.57409E-08 -8.2410 0.57210E-08 -8.2425 0.99654E+00 -0.0015 91 S2-2 0.22972E-14 -14.6388 0.11903E-14 -14.9243 0.51817E+00 -0.2855 97 SO3-2 0.11272E-17 -17.9480 0.59251E-18 -18.2273 0.52567E+00 -0.2793 99 HSO4- 0.33605E-19 -19.4736 0.28148E-19 -19.5506 0.83760E+00 -0.0770 Charge balance for all species = 0.3861E-10 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.8831419E-10 -.2229618E-01 -.2243415E+02 0.0000 2 H2O 0.1000000E+01 0.5550489E+02 0.9981993E+06 0.0000 3 Cl- 0.1608512E-03 0.1615901E-03 0.5718897E+01 6.2578 4 SO4-- 0.7579966E-12 -.1739936E-04 -.1668505E+01 7.8542 5 HCO3- 0.2804960E-06 0.1530709E-04 0.9323723E+00 3.4999 6 HS- 0.2986412E-04 0.4726922E-04 0.1560571E+01 5.5266 7 Al+++ 0.9699034E-29 0.5315801E-05 0.1431790E+00 0.7390 8 H4SiO4 0.6959429E-03 0.1353087E-01 0.1298264E+04 -3.1574 9 Ca++ 0.1350584E-06 0.2318154E-06 0.9274552E-02 13.1019 10 Mg++ 0.2112903E-10 0.9321291E-10 0.2262254E-05 9.2942 11 Fe++ 0.5823317E-13 0.3628397E-07 0.2022829E-02 6.7350 12 K+ 0.1565511E-03 0.1573051E-03 0.6140255E+01 6.2467 13 Na+ 0.1986554E-01 0.2231185E-01 0.5120534E+03 8.3494 14 Mn++ 0.1859929E-10 0.2514451E-08 0.1378988E-03 9.2397 15 HPO4-- 0.4529936E-07 0.4640406E-07 0.4446074E-02 12.6307 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.2384423E+02 -.1903766E-01 -.2382519E+02 0.0000000E+00 2 H2O 0.3745727E+02 0.4739301E+02 -.9935736E+01 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.3993279E-01 -.1485649E-04 0.3994764E-01 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.3990728E-01 0.4036096E-04 -.3994764E-01 0.0000000E+00 7 Al+++ 0.4695465E+01 0.4538912E-05 0.4695460E+01 0.0000000E+00 8 H4SiO4 0.1499440E+02 0.1155337E-01 0.1498284E+02 0.0000000E+00 9 Ca++ 0.1656219E+01 0.1979363E-06 0.1656219E+01 0.0000000E+00 10 Mg++ 0.1142856E+01 0.7959011E-10 0.1142856E+01 0.0000000E+00 11 Fe++ 0.1026732E+01 0.3098117E-07 0.1026732E+01 0.0000000E+00 12 K+ 0.3057323E+00 0.1343154E-03 0.3055980E+00 0.0000000E+00 13 Na+ 0.1807710E+01 0.1905104E-01 0.1788659E+01 0.0000000E+00 14 Mn++ 0.2496756E-01 0.2146971E-08 0.2496756E-01 0.0000000E+00 15 HPO4-- 0.8521304E-02 0.3962224E-07 0.8521265E-02 0.0000000E+00 Chg. balance for solid moles: -.3834E-14 Mass of aqueous solution: 0.855339E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 1439.9990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 1.787 0.252 468.6 2.671 29.79 179.9 andradite 0.1598 -0.796 81.20 1.910 5.162 21.10 grossular 0.3870E-01 -1.412 17.43 1.241 1.108 4.850 apatite-OH 0.2840E-02 -2.547 1.427 0.154 0.9070E-01 0.4534 clinochlore 0.2055 -0.687 114.2 2.058 7.261 43.44 daphnite 0.5948E-01 -1.226 42.44 1.628 2.698 12.86 chlorite-Mn 0.4994E-02 -2.302 3.540 0.549 0.2251 1.128 diopside 0.6906E-01 -1.161 14.96 1.175 0.9508 4.571 hedenbergite 0.1791E-01 -1.747 4.443 0.648 0.2825 1.217 microcline 0.2680 -0.572 74.60 1.873 4.742 29.14 stilbite 0.9340 -0.030 658.2 2.818 41.84 307.0 stilpnomelane-Fe 0.7517E-01 -1.124 81.03 1.909 5.151 27.99 tr.625ac.25prg.125 0.1280E-01 -1.893 10.94 1.039 0.6956 3.521 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8050E+00 0.8050E+00 1.0000 -0.094 grossular 0.1950E+00 0.1950E+00 1.0000 -0.710 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.7612E+00 0.7612E+00 1.0000 -0.119 daphnite 0.2203E+00 0.2203E+00 1.0000 -0.657 chlorite-Mn 0.1850E-01 0.1850E-01 1.0000 -1.733 diopside 0.7941E+00 0.7941E+00 1.0000 -0.100 hedenbergite 0.2059E+00 0.2059E+00 1.0000 -0.686 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 tr.625ac.25prg.125 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 1573.014212 g Volume = 637.148773 cm3 Porosity: -10.4245% V(tot) - V(min): -.60149E+02 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 1439.9990000 g log = 3.1584 Original solution: 1000.0103000 g Original solution / Rock added: 0.69 (Water/Rock Ratio), log = -0.1584 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0570 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9658E+00 0.9855 0.1006E+01 0.1021E+01 CO2,gas 0.3739E-08 1.0069 0.3980E-08 0.3953E-08 CH4,gas 0.1987E-01 1.0124 0.2126E-01 0.2100E-01 H2,gas 0.1438E-01 1.0006 0.1521E-01 0.1520E-01 H2S,gas 0.1494E-06 0.9959 0.1573E-06 0.1579E-06 S2,gas 0.3797E-29 1.0000 0.4014E-29 0.4014E-29 CO,gas 0.1526E-13 1.0000 0.1613E-13 0.1613E-13 SO3,gas 0.7753E-48 1.0000 0.8195E-48 0.8195E-48 SO2,gas 0.4587E-27 1.0000 0.4849E-27 0.4849E-27 HCl,gas 0.3049E-17 1.0000 0.3223E-17 0.3223E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 16 albite -0.38 -0.38 0.00 0.000 -0.13080E-10 22 andradite 39.01 39.01 0.00 0.000 -0.12132E-10 23 grossular 32.73 32.73 0.00 0.000 0.12132E-10 32 apatite-OH -18.15 -18.15 0.00 0.000 0.00000E+00 46 clinochlore 39.07 39.07 0.00 0.000 0.12132E-10 47 daphnite 28.97 28.97 0.00 0.000 -0.12132E-10 48 chlorite-Mn 46.87 46.87 0.00 0.000 0.24265E-10 67 diopside 16.18 16.18 0.00 0.000 0.60662E-11 68 hedenbergite 14.21 14.21 0.00 0.000 0.30331E-11 116 microcline -2.49 -2.49 0.00 0.000 -0.10616E-10 163 stilbite -7.52 -7.52 0.00 0.000 0.15165E-10 164 stilpnomelane-Fe 13.02 13.02 0.00 0.000 -0.27298E-10 245 tr.625ac.25prg.125 45.16 45.16 0.00 0.000 -0.24265E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -16.76 -10.10 -3.366 0.17244E+05 -8.400 3 CH4,gas 4.54 1.17 -3.37 -0.843 0.57566E+04 -1.672 4 H2,gas 8.00 4.48 -3.52 -2.010 0.60050E+04 -1.818 5 H2S,gas -6.23 -14.73 -8.50 -4.251 0.14517E+05 -6.803 6 S2,gas -7.34 -38.43 -31.10 -4.784 0.53095E+05 -29.396 7 CO,gas 3.21 -12.28 -15.49 -4.767 0.26451E+05 -13.792 8 SO3,gas 17.12 -32.66 -49.79 -12.446 0.85007E+05 -48.086 9 SO2,gas 0.83 -28.18 -29.01 -7.737 0.49539E+05 -27.314 10 HCl,gas 5.19 -14.00 -19.19 -9.595 0.32768E+05 -17.492 11 acmite 7.71 6.53 -1.18 -0.123 0.20176E+04 15 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 19 spessartine 24.46 19.72 -4.73 -0.237 0.80806E+04 20 analcite 3.32 2.77 -0.55 -0.061 0.93621E+03 26 annite 20.12 17.72 -2.40 -0.134 0.41064E+04 27 phlogopite 27.06 25.40 -1.67 -0.093 0.28488E+04 29 anorthite 12.71 8.27 -4.45 -0.342 0.75901E+04 35 aragonite 0.97 -3.66 -4.62 -1.541 0.78952E+04 36 brucite 12.57 9.29 -3.27 -0.655 0.55909E+04 37 calcite 0.81 -3.66 -4.47 -1.490 0.76309E+04 38 carnegieite-low 9.02 5.93 -3.09 -0.442 0.52800E+04 39 carnegieite-high 10.09 5.93 -4.16 -0.595 0.71070E+04 40 carpholite-Mg 8.58 4.46 -4.12 -0.275 0.70427E+04 41 carpholite-Fe 6.71 1.90 -4.81 -0.321 0.82205E+04 42 celadonite 5.34 3.65 -1.69 -0.099 0.28879E+04 43 celadonite-Fe 3.88 1.09 -2.79 -0.164 0.47561E+04 44 chrysotile 23.89 21.57 -2.32 -0.194 0.39692E+04 49 chlorite-Al-free 47.17 43.14 -4.04 -0.168 0.68935E+04 51 chloritoid-Fe 9.17 5.06 -4.12 -0.275 0.70313E+04 52 chloritoid-Mn 11.40 7.56 -3.84 -0.256 0.65580E+04 54 coesite -2.38 -3.16 -0.78 -0.260 0.13342E+04 61 cristobalite -2.56 -3.16 -0.60 -0.199 0.10195E+04 63 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71234E+04 65 diaspore 2.87 0.74 -2.13 -0.356 0.36449E+04 66 diamond -3.10 -7.79 -4.69 -1.340 0.80099E+04 71 enstatite 17.26 12.27 -4.99 -0.499 0.85225E+04 73 clinoenstatite 17.17 12.27 -4.89 -0.489 0.83541E+04 75 epidote 24.67 22.70 -1.97 -0.095 0.33584E+04 76 clinozoisite 22.81 18.95 -3.86 -0.175 0.65865E+04 77 epidote-Fe 29.84 26.46 -3.38 -0.176 0.57768E+04 78 fayalite 14.05 10.31 -3.73 -0.533 0.63743E+04 79 ferrosilite 11.15 7.16 -3.99 -0.399 0.68202E+04 83 gibbsite 4.08 0.74 -3.34 -0.477 0.57034E+04 84 glaucophane 22.97 20.80 -2.17 -0.059 0.37133E+04 85 glaucophane-Fe 17.28 13.12 -4.15 -0.112 0.70919E+04 86 graphite -3.55 -7.79 -4.25 -1.214 0.72521E+04 87 greenalite 16.14 13.89 -2.25 -0.187 0.38408E+04 90 hematite 12.57 8.99 -3.58 -0.434 0.61112E+04 91 heulandite -5.83 -7.52 -1.69 -0.077 0.28938E+04 95 jadeite 4.22 2.77 -1.44 -0.144 0.24617E+04 97 kalsilite 7.58 3.83 -3.76 -0.537 0.64125E+04 98 kaolinite -1.33 -4.84 -3.50 -0.319 0.59830E+04 101 laumontite 2.88 1.95 -0.93 -0.062 0.15934E+04 102 lawsonite 9.62 8.27 -1.35 -0.090 0.23068E+04 103 leucite 4.12 0.67 -3.45 -0.345 0.58872E+04 105 lizardite 23.24 21.57 -1.68 -0.140 0.28618E+04 107 magnetite 20.09 15.72 -4.37 -0.356 0.74536E+04 108 minnesotaite 10.39 7.58 -2.81 -0.165 0.48029E+04 112 manganosite 14.06 9.24 -4.82 -1.205 0.82274E+04 120 muscovite 2.58 -1.01 -3.59 -0.211 0.61313E+04 121 paragonite 4.24 1.09 -3.15 -0.185 0.53704E+04 122 nepheline 8.34 5.93 -2.41 -0.344 0.41124E+04 128 periclase-Fe 11.63 6.73 -4.89 -1.223 0.83523E+04 134 phlogopite-Na 29.65 27.50 -2.15 -0.119 0.36676E+04 136 prehnite 19.37 18.21 -1.16 -0.068 0.19847E+04 137 prehnite-Fe 22.50 21.96 -0.53 -0.032 0.91153E+03 138 pumpellyite-Fe 46.27 43.89 -2.38 -0.053 0.40576E+04 139 pumpellyite-Mg 48.99 46.45 -2.54 -0.057 0.43414E+04 143 pyrrhotite -4.26 -8.00 -3.74 -1.246 0.63813E+04 144 pyrrhotiteFe0.875 -6.02 -9.40 -3.38 -1.243 0.57685E+04 145 pyroxmangite 7.40 6.08 -1.32 -0.263 0.22478E+04 146 pyrophyllite -6.18 -11.15 -4.98 -0.311 0.84961E+04 147 quartz -2.99 -3.16 -0.17 -0.056 0.28684E+03 152 rhodonite 7.45 6.08 -1.36 -0.273 0.23280E+04 153 sanidine -1.28 -2.49 -1.21 -0.093 0.20677E+04 165 stilpnomelane-Mg 27.44 25.81 -1.63 -0.049 0.27802E+04 171 talc 16.49 15.25 -1.24 -0.073 0.21141E+04 174 tephroite 18.09 15.32 -2.76 -0.395 0.47192E+04 178 tridymite -2.63 -3.16 -0.53 -0.177 0.90682E+03 179 tremolite 47.87 47.42 -0.45 -0.012 0.77496E+03 180 ferroactinolite 38.45 34.62 -3.83 -0.104 0.65450E+04 181 troilite-low -4.41 -8.00 -3.59 -1.196 0.61241E+04 183 vesuvianite 223.47 218.82 -4.65 -0.036 0.79424E+04 187 wairakite 3.95 1.95 -2.00 -0.118 0.34153E+04 188 walstromite 11.51 9.94 -1.56 -0.313 0.26719E+04 189 wollastonite 10.46 9.94 -0.52 -0.103 0.88229E+03 190 pseudo-wollastonite 11.00 9.94 -1.06 -0.211 0.18021E+04 191 zoisite 22.85 18.95 -3.90 -0.177 0.66606E+04 192 akaganeite 7.75 4.49 -3.26 -0.705 0.55681E+04 199 chalcedony -2.80 -3.16 -0.35 -0.118 0.60614E+03 201 montmorillonite-Ca -2.29 -6.17 -3.88 -0.240 0.66180E+04 202 montmorillonite-K -2.24 -6.27 -4.03 -0.247 0.68816E+04 203 montmorillonite-Mg -2.48 -6.79 -4.31 -0.267 0.73677E+04 204 montmorillonite-Na -2.04 -5.57 -3.54 -0.216 0.60365E+04 205 nontronite-Ca 3.21 -0.19 -3.41 -0.221 0.58216E+04 206 nontronite-H 2.53 -2.36 -4.89 -0.328 0.83486E+04 207 nontronite-K 3.34 -0.30 -3.64 -0.233 0.62085E+04 208 nontronite-Mg 3.07 -0.82 -3.90 -0.253 0.66555E+04 209 nontronite-Na 3.52 0.40 -3.12 -0.200 0.53293E+04 224 tobermorite 9.82 7.76 -2.07 -0.564 0.35287E+04 230 alabandite -0.98 -5.49 -4.52 -1.505 0.77093E+04 233 boehmite 4.41 0.74 -3.67 -0.611 0.62618E+04 235 ferrous-oxide 9.81 6.73 -3.08 -0.769 0.52532E+04 240 silica-amorphous -2.09 -3.16 -1.07 -0.355 0.18203E+04 242 an20ab80 2.02 1.35 -0.67 -0.052 0.11472E+04 243 an25ab75 2.65 1.78 -0.87 -0.067 0.14809E+04 244 an30ab70 3.28 2.21 -1.07 -0.082 0.18243E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 40.0000000 g Current total amount of reactant added: 1439.9990000 g New total amount of reactant added: 1479.9990000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.3298E-10 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 11 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 1479.9990000 Water: Moles liquid = 0.4717E+02 kg liquid = 0.8498E+00 Moles total = 0.3696E+02 kg total = 0.6658E+00 Activity = 1.0000 Stoichiometric ionic strength = .1133774E-01 Osmotic coef. = 0.9693 True ionic strength = .2002368E-01 Chg. balance for total moles = 0.3298E-10 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.88316E-10 -10.0540 0.74207E-10 -10.1296 0.84024E+00 -0.0756 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.16161E-03 -3.7915 0.13498E-03 -3.8697 0.83518E+00 -0.0782 4 SO4-- 0.76158E-12 -12.1183 0.39547E-12 -12.4029 0.51927E+00 -0.2846 5 HCO3- 0.28182E-06 -6.5500 0.23572E-06 -6.6276 0.83641E+00 -0.0776 6 HS- 0.30005E-04 -4.5228 0.25064E-04 -4.6010 0.83531E+00 -0.0782 7 Al+++ 0.96998E-29 -29.0132 0.22406E-29 -29.6496 0.23099E+00 -0.6364 8 H4SiO4 0.69594E-03 -3.1574 0.69594E-03 -3.1574 0.10000E+01 0.0000 9 Ca++ 0.13507E-06 -6.8695 0.69621E-07 -7.1573 0.51546E+00 -0.2878 10 Mg++ 0.21130E-10 -10.6751 0.10842E-10 -10.9649 0.51310E+00 -0.2898 11 Fe++ 0.58236E-13 -13.2348 0.29914E-13 -13.5241 0.51366E+00 -0.2893 12 K+ 0.15655E-03 -3.8053 0.13097E-03 -3.8828 0.83660E+00 -0.0775 13 Na+ 0.19866E-01 -1.7019 0.16589E-01 -1.7802 0.83503E+00 -0.0783 14 Mn++ 0.18603E-10 -10.7304 0.95638E-11 -11.0194 0.51409E+00 -0.2890 15 HPO4-- 0.45298E-07 -7.3439 0.23525E-07 -7.6285 0.51934E+00 -0.2845 16 HSiO3- 0.10485E-01 -1.9794 0.87571E-02 -2.0576 0.83518E+00 -0.0782 17 Ca(HSiO3)+ 0.16593E-07 -7.7801 0.13885E-07 -7.8575 0.83678E+00 -0.0774 18 Mg(HSiO3)+ 0.32158E-11 -11.4927 0.26909E-11 -11.5701 0.83678E+00 -0.0774 19 NaHSiO3,aq 0.23495E-02 -2.6290 0.23495E-02 -2.6290 0.10000E+01 0.0000 20 AlO+ 0.66152E-16 -16.1795 0.55355E-16 -16.2568 0.83678E+00 -0.0774 22 HAlO2,aq 0.14856E-09 -9.8281 0.14856E-09 -9.8281 0.10000E+01 0.0000 23 AlO2- 0.53155E-05 -5.2745 0.44314E-05 -5.3535 0.83368E+00 -0.0790 24 CH4,aq 0.14562E-04 -4.8368 0.14512E-04 -4.8383 0.99654E+00 -0.0015 25 C2H6,aq 0.31186E-14 -14.5060 0.31078E-14 -14.5075 0.99654E+00 -0.0015 29 CO,aq 0.10876E-16 -16.9635 0.10876E-16 -16.9635 0.10000E+01 0.0000 30 CO2,aq 0.37505E-10 -10.4259 0.37376E-10 -10.4274 0.99654E+00 -0.0015 31 CO3-2 0.53545E-06 -6.2713 0.27745E-06 -6.5568 0.51817E+00 -0.2855 32 CaCO3,aq 0.24221E-09 -9.6158 0.24221E-09 -9.6158 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.50061E-12 -12.3005 0.41890E-12 -12.3779 0.83678E+00 -0.0774 34 CaCl+ 0.18174E-10 -10.7406 0.15207E-10 -10.8179 0.83678E+00 -0.0774 35 CaCl2,aq 0.48766E-15 -15.3119 0.48766E-15 -15.3119 0.10000E+01 0.0000 36 CaOH+ 0.79907E-07 -7.0974 0.66865E-07 -7.1748 0.83678E+00 -0.0774 37 CaSO4,aq 0.87429E-17 -17.0583 0.87429E-17 -17.0583 0.10000E+01 0.0000 38 HCl,aq 0.18354E-14 -14.7363 0.18354E-14 -14.7363 0.10000E+01 0.0000 43 FeCl+ 0.76374E-17 -17.1171 0.63909E-17 -17.1944 0.83678E+00 -0.0774 46 FeO,aq 0.21113E-09 -9.6755 0.21113E-09 -9.6755 0.10000E+01 0.0000 47 FeOH+ 0.15681E-10 -10.8046 0.13122E-10 -10.8820 0.83678E+00 -0.0774 48 HFeO2- 0.35644E-07 -7.4480 0.29769E-07 -7.5262 0.83518E+00 -0.0782 49 FeO+ 0.10989E-16 -16.9590 0.91958E-17 -17.0364 0.83678E+00 -0.0774 51 FeO2- 0.40914E-09 -9.3881 0.34171E-09 -9.4663 0.83518E+00 -0.0782 52 HFeO2,aq 0.32250E-11 -11.4915 0.32250E-11 -11.4915 0.10000E+01 0.0000 53 H2,aq 0.11624E-04 -4.9346 0.11584E-04 -4.9361 0.99654E+00 -0.0015 54 KCl,aq 0.32041E-09 -9.4943 0.32041E-09 -9.4943 0.10000E+01 0.0000 56 KOH,aq 0.75375E-06 -6.1228 0.75375E-06 -6.1228 0.10000E+01 0.0000 57 KSO4- 0.96236E-15 -15.0167 0.80375E-15 -15.0949 0.83518E+00 -0.0782 58 MgCO3,aq 0.94544E-14 -14.0244 0.94544E-14 -14.0244 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.79659E-16 -16.0988 0.66658E-16 -16.1762 0.83678E+00 -0.0774 60 MgCl+ 0.25651E-14 -14.5909 0.21464E-14 -14.6683 0.83678E+00 -0.0774 61 MgOH+ 0.68857E-10 -10.1620 0.57619E-10 -10.2394 0.83678E+00 -0.0774 63 MnO,aq 0.17986E-08 -8.7451 0.17986E-08 -8.7451 0.10000E+01 0.0000 64 MnOH+ 0.46573E-09 -9.3319 0.38972E-09 -9.4092 0.83678E+00 -0.0774 65 MnO2-2 0.20919E-10 -10.6795 0.10840E-10 -10.9650 0.51817E+00 -0.2855 66 HMnO2- 0.21100E-09 -9.6757 0.17623E-09 -9.7539 0.83518E+00 -0.0782 69 MnCl+ 0.94996E-14 -14.0223 0.79491E-14 -14.0997 0.83678E+00 -0.0774 71 NaCl,aq 0.74204E-06 -6.1296 0.74204E-06 -6.1296 0.10000E+01 0.0000 72 NaOH,aq 0.96047E-04 -4.0175 0.96047E-04 -4.0175 0.10000E+01 0.0000 74 OH- 0.93394E-02 -2.0297 0.77860E-02 -2.1087 0.83368E+00 -0.0790 79 HPO3-2 0.16389E-14 -14.7854 0.84924E-15 -15.0710 0.51817E+00 -0.2855 81 H2PO3- 0.15131E-18 -18.8201 0.12637E-18 -18.8983 0.83518E+00 -0.0782 82 H3PO4,aq 0.90603E-18 -18.0429 0.90603E-18 -18.0429 0.10000E+01 0.0000 83 H2PO4- 0.38522E-10 -10.4143 0.32204E-10 -10.4921 0.83598E+00 -0.0778 84 PO4-3 0.10661E-08 -8.9722 0.25866E-09 -9.5873 0.24261E+00 -0.6151 88 HP2O7-3 0.94631E-18 -18.0240 0.21881E-18 -18.6599 0.23123E+00 -0.6360 89 P2O7-4 0.91382E-17 -17.0391 0.70443E-18 -18.1522 0.77086E-01 -1.1130 90 H2S,aq 0.57681E-08 -8.2390 0.57482E-08 -8.2405 0.99654E+00 -0.0015 91 S2-2 0.23189E-14 -14.6347 0.12016E-14 -14.9202 0.51817E+00 -0.2855 97 SO3-2 0.11325E-17 -17.9460 0.59531E-18 -18.2253 0.52566E+00 -0.2793 99 HSO4- 0.33765E-19 -19.4715 0.28281E-19 -19.5485 0.83760E+00 -0.0770 Charge balance for all species = 0.3880E-10 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.8831639E-10 -.2229578E-01 -.2243375E+02 0.0000 2 H2O 0.1000000E+01 0.5550489E+02 0.9981992E+06 0.0000 3 Cl- 0.1616116E-03 0.1623539E-03 0.5745929E+01 6.2598 4 SO4-- 0.7615797E-12 -.1746787E-04 -.1675075E+01 7.8562 5 HCO3- 0.2818212E-06 0.1537944E-04 0.9367794E+00 3.5019 6 HS- 0.3000529E-04 0.4747892E-04 0.1567494E+01 5.5286 7 Al+++ 0.9699801E-29 0.5315654E-05 0.1431750E+00 0.7390 8 H4SiO4 0.6959442E-03 0.1353067E-01 0.1298245E+04 -3.1574 9 Ca++ 0.1350653E-06 0.2318259E-06 0.9274968E-02 13.1019 10 Mg++ 0.2113012E-10 0.9321587E-10 0.2262325E-05 9.2942 11 Fe++ 0.5823624E-13 0.3628316E-07 0.2022784E-02 6.7350 12 K+ 0.1565550E-03 0.1573090E-03 0.6140407E+01 6.2467 13 Na+ 0.1986604E-01 0.2231235E-01 0.5120650E+03 8.3494 14 Mn++ 0.1860337E-10 0.2514874E-08 0.1379220E-03 9.2397 15 HPO4-- 0.4529770E-07 0.4640234E-07 0.4445910E-02 12.6306 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.2450657E+02 -.1894775E-01 -.2448763E+02 0.0000000E+00 2 H2O 0.3695586E+02 0.4717004E+02 -.1021419E+02 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.4104132E-01 -.1484482E-04 0.4105617E-01 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.4101582E-01 0.4034929E-04 -.4105617E-01 0.0000000E+00 7 Al+++ 0.4825894E+01 0.4517433E-05 0.4825890E+01 0.0000000E+00 8 H4SiO4 0.1541091E+02 0.1149884E-01 0.1539941E+02 0.0000000E+00 9 Ca++ 0.1702224E+01 0.1970139E-06 0.1702224E+01 0.0000000E+00 10 Mg++ 0.1174602E+01 0.7921819E-10 0.1174602E+01 0.0000000E+00 11 Fe++ 0.1055252E+01 0.3083473E-07 0.1055252E+01 0.0000000E+00 12 K+ 0.3142248E+00 0.1336869E-03 0.3140912E+00 0.0000000E+00 13 Na+ 0.1857919E+01 0.1896184E-01 0.1838958E+01 0.0000000E+00 14 Mn++ 0.2566110E-01 0.2137230E-08 0.2566110E-01 0.0000000E+00 15 HPO4-- 0.8758007E-02 0.3943437E-07 0.8757968E-02 0.0000000E+00 Chg. balance for solid moles: 0.4101E-14 Mass of aqueous solution: 0.851315E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 1479.9990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 1.837 0.264 481.8 2.683 29.80 184.9 andradite 0.1642 -0.785 83.46 1.921 5.162 21.68 grossular 0.3977E-01 -1.400 17.92 1.253 1.108 4.985 apatite-OH 0.2919E-02 -2.535 1.466 0.166 0.9070E-01 0.4660 clinochlore 0.2112 -0.675 117.4 2.070 7.259 44.64 daphnite 0.6112E-01 -1.214 43.61 1.640 2.698 13.22 chlorite-Mn 0.5132E-02 -2.290 3.639 0.561 0.2251 1.160 diopside 0.7124E-01 -1.147 15.43 1.188 0.9542 4.715 hedenbergite 0.1847E-01 -1.733 4.583 0.661 0.2835 1.255 microcline 0.2755 -0.560 76.67 1.885 4.742 29.95 stilbite 0.9597 -0.018 676.3 2.830 41.83 315.4 stilpnomelane-Fe 0.7726E-01 -1.112 83.28 1.921 5.151 28.77 tr.625ac.25prg.125 0.1313E-01 -1.882 11.23 1.050 0.6944 3.613 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8050E+00 0.8050E+00 1.0000 -0.094 grossular 0.1950E+00 0.1950E+00 1.0000 -0.710 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.7612E+00 0.7612E+00 1.0000 -0.119 daphnite 0.2203E+00 0.2203E+00 1.0000 -0.657 chlorite-Mn 0.1850E-01 0.1850E-01 1.0000 -1.733 diopside 0.7941E+00 0.7941E+00 1.0000 -0.100 hedenbergite 0.2059E+00 0.2059E+00 1.0000 -0.686 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 tr.625ac.25prg.125 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 1616.714477 g Volume = 654.829999 cm3 Porosity: -10.4267% V(tot) - V(min): -.61830E+02 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 1479.9990000 g log = 3.1703 Original solution: 1000.0103000 g Original solution / Rock added: 0.68 (Water/Rock Ratio), log = -0.1703 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0571 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9657E+00 0.9855 0.1006E+01 0.1021E+01 CO2,gas 0.3757E-08 1.0069 0.3999E-08 0.3971E-08 CH4,gas 0.1996E-01 1.0124 0.2136E-01 0.2110E-01 H2,gas 0.1438E-01 1.0006 0.1521E-01 0.1520E-01 H2S,gas 0.1501E-06 0.9959 0.1580E-06 0.1587E-06 S2,gas 0.3833E-29 1.0000 0.4052E-29 0.4052E-29 CO,gas 0.1533E-13 1.0000 0.1621E-13 0.1621E-13 SO3,gas 0.7789E-48 1.0000 0.8234E-48 0.8234E-48 SO2,gas 0.4609E-27 1.0000 0.4872E-27 0.4872E-27 HCl,gas 0.3064E-17 1.0000 0.3239E-17 0.3239E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 16 albite -0.38 -0.38 0.00 0.000 -0.94784E-12 22 andradite 39.01 39.01 0.00 0.000 0.00000E+00 23 grossular 32.73 32.73 0.00 0.000 0.36397E-10 32 apatite-OH -18.15 -18.15 0.00 0.000 -0.60662E-11 46 clinochlore 39.07 39.07 0.00 0.000 0.12132E-10 47 daphnite 28.97 28.97 0.00 0.000 -0.30331E-10 48 chlorite-Mn 46.87 46.87 0.00 0.000 0.00000E+00 67 diopside 16.18 16.18 0.00 0.000 0.00000E+00 68 hedenbergite 14.21 14.21 0.00 0.000 -0.30331E-11 116 microcline -2.49 -2.49 0.00 0.000 -0.10616E-10 163 stilbite -7.52 -7.52 0.00 0.000 -0.90992E-11 164 stilpnomelane-Fe 13.02 13.02 0.00 0.000 -0.27298E-10 245 tr.625ac.25prg.125 45.16 45.16 0.00 0.000 0.00000E+00 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -16.76 -10.10 -3.366 0.17240E+05 -8.398 3 CH4,gas 4.54 1.17 -3.37 -0.842 0.57531E+04 -1.670 4 H2,gas 8.00 4.48 -3.52 -2.010 0.60050E+04 -1.818 5 H2S,gas -6.23 -14.73 -8.50 -4.250 0.14514E+05 -6.801 6 S2,gas -7.34 -38.43 -31.09 -4.783 0.53088E+05 -29.392 7 CO,gas 3.21 -12.27 -15.49 -4.766 0.26447E+05 -13.790 8 SO3,gas 17.12 -32.66 -49.78 -12.446 0.85004E+05 -48.084 9 SO2,gas 0.83 -28.18 -29.01 -7.736 0.49536E+05 -27.312 10 HCl,gas 5.19 -14.00 -19.19 -9.594 0.32764E+05 -17.490 11 acmite 7.71 6.53 -1.18 -0.123 0.20176E+04 15 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 19 spessartine 24.46 19.73 -4.73 -0.237 0.80803E+04 20 analcite 3.32 2.77 -0.55 -0.061 0.93621E+03 26 annite 20.12 17.72 -2.40 -0.134 0.41064E+04 27 phlogopite 27.06 25.40 -1.67 -0.093 0.28488E+04 29 anorthite 12.71 8.27 -4.45 -0.342 0.75901E+04 35 aragonite 0.97 -3.66 -4.62 -1.541 0.78917E+04 36 brucite 12.57 9.29 -3.27 -0.655 0.55909E+04 37 calcite 0.81 -3.66 -4.47 -1.489 0.76274E+04 38 carnegieite-low 9.02 5.93 -3.09 -0.442 0.52800E+04 39 carnegieite-high 10.09 5.93 -4.16 -0.595 0.71070E+04 40 carpholite-Mg 8.58 4.46 -4.12 -0.275 0.70427E+04 41 carpholite-Fe 6.71 1.90 -4.81 -0.321 0.82205E+04 42 celadonite 5.34 3.65 -1.69 -0.099 0.28879E+04 43 celadonite-Fe 3.88 1.09 -2.79 -0.164 0.47561E+04 44 chrysotile 23.89 21.57 -2.32 -0.194 0.39692E+04 49 chlorite-Al-free 47.17 43.14 -4.04 -0.168 0.68935E+04 51 chloritoid-Fe 9.17 5.06 -4.12 -0.275 0.70314E+04 52 chloritoid-Mn 11.40 7.56 -3.84 -0.256 0.65579E+04 54 coesite -2.38 -3.16 -0.78 -0.260 0.13342E+04 61 cristobalite -2.56 -3.16 -0.60 -0.199 0.10195E+04 63 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71234E+04 65 diaspore 2.87 0.74 -2.13 -0.356 0.36449E+04 66 diamond -3.10 -7.79 -4.69 -1.340 0.80064E+04 71 enstatite 17.26 12.27 -4.99 -0.499 0.85225E+04 73 clinoenstatite 17.17 12.27 -4.89 -0.489 0.83541E+04 75 epidote 24.67 22.70 -1.97 -0.095 0.33584E+04 76 clinozoisite 22.81 18.95 -3.86 -0.175 0.65866E+04 77 epidote-Fe 29.84 26.46 -3.38 -0.176 0.57768E+04 78 fayalite 14.05 10.31 -3.73 -0.533 0.63743E+04 79 ferrosilite 11.15 7.16 -3.99 -0.399 0.68202E+04 83 gibbsite 4.08 0.74 -3.34 -0.477 0.57034E+04 84 glaucophane 22.97 20.80 -2.17 -0.059 0.37133E+04 85 glaucophane-Fe 17.28 13.12 -4.15 -0.112 0.70919E+04 86 graphite -3.55 -7.79 -4.25 -1.213 0.72486E+04 87 greenalite 16.14 13.89 -2.25 -0.187 0.38408E+04 90 hematite 12.57 8.99 -3.58 -0.434 0.61112E+04 91 heulandite -5.83 -7.52 -1.69 -0.077 0.28938E+04 95 jadeite 4.22 2.77 -1.44 -0.144 0.24617E+04 97 kalsilite 7.58 3.83 -3.76 -0.537 0.64125E+04 98 kaolinite -1.33 -4.84 -3.50 -0.319 0.59830E+04 101 laumontite 2.88 1.95 -0.93 -0.062 0.15934E+04 102 lawsonite 9.62 8.27 -1.35 -0.090 0.23068E+04 103 leucite 4.12 0.67 -3.45 -0.345 0.58872E+04 105 lizardite 23.24 21.57 -1.68 -0.140 0.28618E+04 107 magnetite 20.09 15.72 -4.37 -0.356 0.74536E+04 108 minnesotaite 10.39 7.58 -2.81 -0.165 0.48029E+04 112 manganosite 14.06 9.24 -4.82 -1.205 0.82272E+04 120 muscovite 2.58 -1.01 -3.59 -0.211 0.61313E+04 121 paragonite 4.24 1.09 -3.15 -0.185 0.53704E+04 122 nepheline 8.34 5.93 -2.41 -0.344 0.41124E+04 128 periclase-Fe 11.63 6.73 -4.89 -1.223 0.83523E+04 134 phlogopite-Na 29.65 27.50 -2.15 -0.119 0.36676E+04 136 prehnite 19.37 18.21 -1.16 -0.068 0.19847E+04 137 prehnite-Fe 22.50 21.96 -0.53 -0.032 0.91153E+03 138 pumpellyite-Fe 46.27 43.89 -2.38 -0.053 0.40576E+04 139 pumpellyite-Mg 48.99 46.45 -2.54 -0.057 0.43415E+04 143 pyrrhotite -4.26 -8.00 -3.74 -1.245 0.63778E+04 144 pyrrhotiteFe0.875 -6.02 -9.39 -3.38 -1.242 0.57650E+04 145 pyroxmangite 7.40 6.08 -1.32 -0.263 0.22477E+04 146 pyrophyllite -6.18 -11.15 -4.98 -0.311 0.84961E+04 147 quartz -2.99 -3.16 -0.17 -0.056 0.28684E+03 152 rhodonite 7.45 6.08 -1.36 -0.273 0.23279E+04 153 sanidine -1.28 -2.49 -1.21 -0.093 0.20677E+04 165 stilpnomelane-Mg 27.44 25.81 -1.63 -0.049 0.27802E+04 171 talc 16.49 15.25 -1.24 -0.073 0.21141E+04 174 tephroite 18.09 15.32 -2.76 -0.395 0.47190E+04 178 tridymite -2.63 -3.16 -0.53 -0.177 0.90682E+03 179 tremolite 47.87 47.42 -0.45 -0.012 0.77496E+03 180 ferroactinolite 38.45 34.62 -3.83 -0.104 0.65450E+04 181 troilite-low -4.41 -8.00 -3.58 -1.195 0.61206E+04 183 vesuvianite 223.47 218.82 -4.65 -0.036 0.79425E+04 187 wairakite 3.95 1.95 -2.00 -0.118 0.34154E+04 188 walstromite 11.51 9.94 -1.56 -0.313 0.26719E+04 189 wollastonite 10.46 9.94 -0.52 -0.103 0.88229E+03 190 pseudo-wollastonite 11.00 9.94 -1.06 -0.211 0.18021E+04 191 zoisite 22.85 18.95 -3.90 -0.177 0.66606E+04 192 akaganeite 7.75 4.49 -3.26 -0.705 0.55681E+04 199 chalcedony -2.80 -3.16 -0.35 -0.118 0.60614E+03 201 montmorillonite-Ca -2.29 -6.17 -3.88 -0.240 0.66180E+04 202 montmorillonite-K -2.24 -6.27 -4.03 -0.247 0.68816E+04 203 montmorillonite-Mg -2.48 -6.79 -4.31 -0.267 0.73677E+04 204 montmorillonite-Na -2.04 -5.57 -3.54 -0.216 0.60365E+04 205 nontronite-Ca 3.21 -0.19 -3.41 -0.221 0.58216E+04 206 nontronite-H 2.53 -2.36 -4.89 -0.328 0.83486E+04 207 nontronite-K 3.34 -0.30 -3.64 -0.233 0.62084E+04 208 nontronite-Mg 3.07 -0.82 -3.90 -0.253 0.66555E+04 209 nontronite-Na 3.52 0.40 -3.12 -0.200 0.53293E+04 224 tobermorite 9.82 7.76 -2.07 -0.564 0.35287E+04 230 alabandite -0.98 -5.49 -4.51 -1.504 0.77057E+04 233 boehmite 4.41 0.74 -3.67 -0.611 0.62618E+04 235 ferrous-oxide 9.81 6.73 -3.08 -0.769 0.52532E+04 240 silica-amorphous -2.09 -3.16 -1.07 -0.355 0.18203E+04 242 an20ab80 2.02 1.35 -0.67 -0.052 0.11472E+04 243 an25ab75 2.65 1.78 -0.87 -0.067 0.14809E+04 244 an30ab70 3.28 2.21 -1.07 -0.082 0.18243E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 40.0000000 g Current total amount of reactant added: 1479.9990000 g New total amount of reactant added: 1519.9990000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.3297E-10 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 11 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 1519.9990000 Water: Moles liquid = 0.4695E+02 kg liquid = 0.8458E+00 Moles total = 0.3645E+02 kg total = 0.6567E+00 Activity = 1.0000 Stoichiometric ionic strength = .1133839E-01 Osmotic coef. = 0.9692 True ionic strength = .2002419E-01 Chg. balance for total moles = 0.3297E-10 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.88319E-10 -10.0539 0.74208E-10 -10.1295 0.84024E+00 -0.0756 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.16238E-03 -3.7895 0.13562E-03 -3.8677 0.83518E+00 -0.0782 4 SO4-- 0.76520E-12 -12.1162 0.39734E-12 -12.4008 0.51927E+00 -0.2846 5 HCO3- 0.28316E-06 -6.5480 0.23684E-06 -6.6256 0.83640E+00 -0.0776 6 HS- 0.30148E-04 -4.5207 0.25183E-04 -4.5989 0.83530E+00 -0.0782 7 Al+++ 0.97006E-29 -29.0132 0.22408E-29 -29.6496 0.23099E+00 -0.6364 8 H4SiO4 0.69595E-03 -3.1574 0.69595E-03 -3.1574 0.10000E+01 0.0000 9 Ca++ 0.13507E-06 -6.8694 0.69624E-07 -7.1572 0.51546E+00 -0.2878 10 Mg++ 0.21131E-10 -10.6751 0.10842E-10 -10.9649 0.51310E+00 -0.2898 11 Fe++ 0.58239E-13 -13.2348 0.29915E-13 -13.5241 0.51366E+00 -0.2893 12 K+ 0.15656E-03 -3.8053 0.13098E-03 -3.8828 0.83660E+00 -0.0775 13 Na+ 0.19867E-01 -1.7019 0.16589E-01 -1.7802 0.83503E+00 -0.0783 14 Mn++ 0.18607E-10 -10.7303 0.95657E-11 -11.0193 0.51408E+00 -0.2890 15 HPO4-- 0.45296E-07 -7.3439 0.23524E-07 -7.6285 0.51934E+00 -0.2845 16 HSiO3- 0.10485E-01 -1.9794 0.87569E-02 -2.0577 0.83518E+00 -0.0782 17 Ca(HSiO3)+ 0.16593E-07 -7.7801 0.13885E-07 -7.8575 0.83678E+00 -0.0774 18 Mg(HSiO3)+ 0.32158E-11 -11.4927 0.26910E-11 -11.5701 0.83678E+00 -0.0774 19 NaHSiO3,aq 0.23495E-02 -2.6290 0.23495E-02 -2.6290 0.10000E+01 0.0000 20 AlO+ 0.66153E-16 -16.1794 0.55356E-16 -16.2568 0.83678E+00 -0.0774 22 HAlO2,aq 0.14855E-09 -9.8281 0.14855E-09 -9.8281 0.10000E+01 0.0000 23 AlO2- 0.53154E-05 -5.2745 0.44313E-05 -5.3535 0.83367E+00 -0.0790 24 CH4,aq 0.14631E-04 -4.8347 0.14580E-04 -4.8362 0.99654E+00 -0.0015 25 C2H6,aq 0.31483E-14 -14.5019 0.31374E-14 -14.5034 0.99654E+00 -0.0015 29 CO,aq 0.10928E-16 -16.9615 0.10928E-16 -16.9615 0.10000E+01 0.0000 30 CO2,aq 0.37684E-10 -10.4238 0.37554E-10 -10.4253 0.99654E+00 -0.0015 31 CO3-2 0.53798E-06 -6.2692 0.27876E-06 -6.5548 0.51817E+00 -0.2855 32 CaCO3,aq 0.24336E-09 -9.6137 0.24336E-09 -9.6137 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.50301E-12 -12.2984 0.42091E-12 -12.3758 0.83678E+00 -0.0774 34 CaCl+ 0.18261E-10 -10.7385 0.15280E-10 -10.8159 0.83678E+00 -0.0774 35 CaCl2,aq 0.49232E-15 -15.3078 0.49232E-15 -15.3078 0.10000E+01 0.0000 36 CaOH+ 0.79909E-07 -7.0974 0.66866E-07 -7.1748 0.83678E+00 -0.0774 37 CaSO4,aq 0.87847E-17 -17.0563 0.87847E-17 -17.0563 0.10000E+01 0.0000 38 HCl,aq 0.18442E-14 -14.7342 0.18442E-14 -14.7342 0.10000E+01 0.0000 43 FeCl+ 0.76741E-17 -17.1150 0.64215E-17 -17.1924 0.83678E+00 -0.0774 46 FeO,aq 0.21113E-09 -9.6755 0.21113E-09 -9.6755 0.10000E+01 0.0000 47 FeOH+ 0.15682E-10 -10.8046 0.13122E-10 -10.8820 0.83678E+00 -0.0774 48 HFeO2- 0.35643E-07 -7.4480 0.29769E-07 -7.5262 0.83518E+00 -0.0782 49 FeO+ 0.10990E-16 -16.9590 0.91960E-17 -17.0364 0.83678E+00 -0.0774 51 FeO2- 0.40913E-09 -9.3881 0.34170E-09 -9.4664 0.83518E+00 -0.0782 52 HFeO2,aq 0.32250E-11 -11.4915 0.32250E-11 -11.4915 0.10000E+01 0.0000 53 H2,aq 0.11624E-04 -4.9346 0.11584E-04 -4.9361 0.99654E+00 -0.0015 54 KCl,aq 0.32193E-09 -9.4922 0.32193E-09 -9.4922 0.10000E+01 0.0000 56 KOH,aq 0.75375E-06 -6.1228 0.75375E-06 -6.1228 0.10000E+01 0.0000 57 KSO4- 0.96695E-15 -15.0146 0.80758E-15 -15.0928 0.83518E+00 -0.0782 58 MgCO3,aq 0.94994E-14 -14.0223 0.94994E-14 -14.0223 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.80041E-16 -16.0967 0.66977E-16 -16.1741 0.83678E+00 -0.0774 60 MgCl+ 0.25774E-14 -14.5888 0.21567E-14 -14.6662 0.83678E+00 -0.0774 61 MgOH+ 0.68859E-10 -10.1620 0.57620E-10 -10.2394 0.83678E+00 -0.0774 63 MnO,aq 0.17989E-08 -8.7450 0.17989E-08 -8.7450 0.10000E+01 0.0000 64 MnOH+ 0.46582E-09 -9.3318 0.38979E-09 -9.4092 0.83678E+00 -0.0774 65 MnO2-2 0.20922E-10 -10.6794 0.10841E-10 -10.9649 0.51817E+00 -0.2855 66 HMnO2- 0.21103E-09 -9.6756 0.17625E-09 -9.7539 0.83518E+00 -0.0782 69 MnCl+ 0.95467E-14 -14.0201 0.79885E-14 -14.0975 0.83678E+00 -0.0774 71 NaCl,aq 0.74558E-06 -6.1275 0.74558E-06 -6.1275 0.10000E+01 0.0000 72 NaOH,aq 0.96047E-04 -4.0175 0.96047E-04 -4.0175 0.10000E+01 0.0000 74 OH- 0.93392E-02 -2.0297 0.77858E-02 -2.1087 0.83367E+00 -0.0790 79 HPO3-2 0.16389E-14 -14.7855 0.84920E-15 -15.0710 0.51817E+00 -0.2855 81 H2PO3- 0.15131E-18 -18.8201 0.12637E-18 -18.8984 0.83518E+00 -0.0782 82 H3PO4,aq 0.90603E-18 -18.0429 0.90603E-18 -18.0429 0.10000E+01 0.0000 83 H2PO4- 0.38522E-10 -10.4143 0.32203E-10 -10.4921 0.83597E+00 -0.0778 84 PO4-3 0.10661E-08 -8.9722 0.25864E-09 -9.5873 0.24261E+00 -0.6151 88 HP2O7-3 0.94627E-18 -18.0240 0.21880E-18 -18.6600 0.23122E+00 -0.6360 89 P2O7-4 0.91376E-17 -17.0392 0.70437E-18 -18.1522 0.77084E-01 -1.1130 90 H2S,aq 0.57957E-08 -8.2369 0.57756E-08 -8.2384 0.99654E+00 -0.0015 91 S2-2 0.23410E-14 -14.6306 0.12130E-14 -14.9161 0.51817E+00 -0.2855 97 SO3-2 0.11379E-17 -17.9439 0.59813E-18 -18.2232 0.52566E+00 -0.2793 99 HSO4- 0.33926E-19 -19.4695 0.28416E-19 -19.5464 0.83760E+00 -0.0770 Charge balance for all species = 0.3899E-10 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.8831860E-10 -.2229538E-01 -.2243334E+02 0.0000 2 H2O 0.1000000E+01 0.5550489E+02 0.9981992E+06 0.0000 3 Cl- 0.1623791E-03 0.1631250E-03 0.5773219E+01 6.2619 4 SO4-- 0.7651960E-12 -.1753702E-04 -.1681707E+01 7.8583 5 HCO3- 0.2831587E-06 0.1545248E-04 0.9412284E+00 3.5040 6 HS- 0.3014779E-04 0.4769061E-04 0.1574483E+01 5.5306 7 Al+++ 0.9700577E-29 0.5315509E-05 0.1431711E+00 0.7390 8 H4SiO4 0.6959455E-03 0.1353046E-01 0.1298225E+04 -3.1574 9 Ca++ 0.1350723E-06 0.2318364E-06 0.9275388E-02 13.1019 10 Mg++ 0.2113121E-10 0.9321860E-10 0.2262392E-05 9.2942 11 Fe++ 0.5823933E-13 0.3628235E-07 0.2022739E-02 6.7350 12 K+ 0.1565589E-03 0.1573130E-03 0.6140561E+01 6.2467 13 Na+ 0.1986654E-01 0.2231286E-01 0.5120766E+03 8.3494 14 Mn++ 0.1860729E-10 0.2515276E-08 0.1379441E-03 9.2398 15 HPO4-- 0.4529602E-07 0.4640060E-07 0.4445743E-02 12.6306 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.2516891E+02 -.1885785E-01 -.2515006E+02 0.0000000E+00 2 H2O 0.3645444E+02 0.4694708E+02 -.1049264E+02 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.4214986E-01 -.1483314E-04 0.4216469E-01 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.4212435E-01 0.4033761E-04 -.4216469E-01 0.0000000E+00 7 Al+++ 0.4956324E+01 0.4495957E-05 0.4956319E+01 0.0000000E+00 8 H4SiO4 0.1582742E+02 0.1144432E-01 0.1581598E+02 0.0000000E+00 9 Ca++ 0.1748230E+01 0.1960915E-06 0.1748230E+01 0.0000000E+00 10 Mg++ 0.1206348E+01 0.7884604E-10 0.1206348E+01 0.0000000E+00 11 Fe++ 0.1083772E+01 0.3068829E-07 0.1083772E+01 0.0000000E+00 12 K+ 0.3227174E+00 0.1330583E-03 0.3225844E+00 0.0000000E+00 13 Na+ 0.1908129E+01 0.1887264E-01 0.1889256E+01 0.0000000E+00 14 Mn++ 0.2635465E-01 0.2127468E-08 0.2635465E-01 0.0000000E+00 15 HPO4-- 0.8994711E-02 0.3924650E-07 0.8994671E-02 0.0000000E+00 Chg. balance for solid moles: -.1509E-14 Mass of aqueous solution: 0.847291E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 1519.9990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 1.888 0.276 495.0 2.695 29.81 190.0 andradite 0.1687 -0.773 85.71 1.933 5.162 22.27 grossular 0.4085E-01 -1.389 18.40 1.265 1.108 5.119 apatite-OH 0.2998E-02 -2.523 1.506 0.178 0.9070E-01 0.4786 clinochlore 0.2168 -0.664 120.5 2.081 7.258 45.84 daphnite 0.6277E-01 -1.202 44.78 1.651 2.697 13.57 chlorite-Mn 0.5271E-02 -2.278 3.737 0.573 0.2251 1.191 diopside 0.7341E-01 -1.134 15.90 1.201 0.9575 4.859 hedenbergite 0.1904E-01 -1.720 4.723 0.674 0.2845 1.294 microcline 0.2829 -0.548 78.74 1.896 4.742 30.76 stilbite 0.9853 -0.006 694.4 2.842 41.82 323.9 stilpnomelane-Fe 0.7935E-01 -1.100 85.54 1.932 5.152 29.55 tr.625ac.25prg.125 0.1347E-01 -1.871 11.51 1.061 0.6933 3.705 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8050E+00 0.8050E+00 1.0000 -0.094 grossular 0.1950E+00 0.1950E+00 1.0000 -0.710 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.7612E+00 0.7612E+00 1.0000 -0.119 daphnite 0.2203E+00 0.2203E+00 1.0000 -0.657 chlorite-Mn 0.1850E-01 0.1850E-01 1.0000 -1.733 diopside 0.7941E+00 0.7941E+00 1.0000 -0.100 hedenbergite 0.2059E+00 0.2059E+00 1.0000 -0.686 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 tr.625ac.25prg.125 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 1660.414742 g Volume = 672.511225 cm3 Porosity: -10.4288% V(tot) - V(min): -.63512E+02 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 1519.9990000 g log = 3.1818 Original solution: 1000.0103000 g Original solution / Rock added: 0.66 (Water/Rock Ratio), log = -0.1818 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0572 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9656E+00 0.9855 0.1006E+01 0.1021E+01 CO2,gas 0.3774E-08 1.0069 0.4018E-08 0.3990E-08 CH4,gas 0.2005E-01 1.0124 0.2146E-01 0.2120E-01 H2,gas 0.1438E-01 1.0006 0.1521E-01 0.1520E-01 H2S,gas 0.1508E-06 0.9959 0.1588E-06 0.1594E-06 S2,gas 0.3870E-29 1.0000 0.4091E-29 0.4091E-29 CO,gas 0.1540E-13 1.0000 0.1628E-13 0.1628E-13 SO3,gas 0.7826E-48 1.0000 0.8273E-48 0.8273E-48 SO2,gas 0.4630E-27 1.0000 0.4895E-27 0.4895E-27 HCl,gas 0.3078E-17 1.0000 0.3254E-17 0.3254E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 16 albite -0.38 -0.38 0.00 0.000 0.11184E-10 22 andradite 39.01 39.01 0.00 0.000 -0.12132E-10 23 grossular 32.73 32.73 0.00 0.000 0.00000E+00 32 apatite-OH -18.15 -18.15 0.00 0.000 0.18198E-10 46 clinochlore 39.07 39.07 0.00 0.000 0.12132E-10 47 daphnite 28.97 28.97 0.00 0.000 0.54595E-10 48 chlorite-Mn 46.87 46.87 0.00 0.000 0.24265E-10 67 diopside 16.18 16.18 0.00 0.000 0.18198E-10 68 hedenbergite 14.21 14.21 0.00 0.000 0.12132E-10 116 microcline -2.49 -2.49 0.00 0.000 0.15165E-11 163 stilbite -7.52 -7.52 0.00 0.000 -0.90992E-11 164 stilpnomelane-Fe 13.02 13.02 0.00 0.000 -0.27298E-10 245 tr.625ac.25prg.125 45.16 45.16 0.00 0.000 0.12132E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -16.76 -10.09 -3.365 0.17237E+05 -8.396 3 CH4,gas 4.54 1.18 -3.37 -0.842 0.57496E+04 -1.668 4 H2,gas 8.00 4.48 -3.52 -2.010 0.60050E+04 -1.818 5 H2S,gas -6.23 -14.73 -8.50 -4.249 0.14510E+05 -6.799 6 S2,gas -7.34 -38.42 -31.09 -4.783 0.53080E+05 -29.388 7 CO,gas 3.21 -12.27 -15.49 -4.765 0.26444E+05 -13.788 8 SO3,gas 17.12 -32.66 -49.78 -12.445 0.85000E+05 -48.082 9 SO2,gas 0.83 -28.18 -29.01 -7.736 0.49532E+05 -27.310 10 HCl,gas 5.19 -14.00 -19.19 -9.593 0.32761E+05 -17.488 11 acmite 7.71 6.53 -1.18 -0.123 0.20176E+04 15 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 19 spessartine 24.46 19.73 -4.73 -0.237 0.80799E+04 20 analcite 3.32 2.77 -0.55 -0.061 0.93621E+03 26 annite 20.12 17.72 -2.40 -0.134 0.41064E+04 27 phlogopite 27.06 25.40 -1.67 -0.093 0.28488E+04 29 anorthite 12.71 8.27 -4.45 -0.342 0.75901E+04 35 aragonite 0.97 -3.65 -4.62 -1.540 0.78881E+04 36 brucite 12.57 9.29 -3.27 -0.655 0.55909E+04 37 calcite 0.81 -3.65 -4.47 -1.488 0.76239E+04 38 carnegieite-low 9.02 5.93 -3.09 -0.442 0.52800E+04 39 carnegieite-high 10.09 5.93 -4.16 -0.595 0.71070E+04 40 carpholite-Mg 8.58 4.46 -4.12 -0.275 0.70427E+04 41 carpholite-Fe 6.71 1.90 -4.81 -0.321 0.82205E+04 42 celadonite 5.34 3.65 -1.69 -0.099 0.28879E+04 43 celadonite-Fe 3.88 1.09 -2.79 -0.164 0.47561E+04 44 chrysotile 23.89 21.57 -2.32 -0.194 0.39692E+04 49 chlorite-Al-free 47.17 43.14 -4.04 -0.168 0.68935E+04 51 chloritoid-Fe 9.17 5.06 -4.12 -0.275 0.70314E+04 52 chloritoid-Mn 11.40 7.56 -3.84 -0.256 0.65577E+04 54 coesite -2.38 -3.16 -0.78 -0.260 0.13342E+04 61 cristobalite -2.56 -3.16 -0.60 -0.199 0.10195E+04 63 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71234E+04 65 diaspore 2.87 0.74 -2.13 -0.356 0.36449E+04 66 diamond -3.10 -7.79 -4.69 -1.339 0.80029E+04 71 enstatite 17.26 12.27 -4.99 -0.499 0.85225E+04 73 clinoenstatite 17.17 12.27 -4.89 -0.489 0.83541E+04 75 epidote 24.67 22.70 -1.97 -0.095 0.33584E+04 76 clinozoisite 22.81 18.95 -3.86 -0.175 0.65866E+04 77 epidote-Fe 29.84 26.46 -3.38 -0.176 0.57768E+04 78 fayalite 14.05 10.31 -3.73 -0.533 0.63743E+04 79 ferrosilite 11.15 7.16 -3.99 -0.399 0.68202E+04 83 gibbsite 4.08 0.74 -3.34 -0.477 0.57034E+04 84 glaucophane 22.97 20.80 -2.17 -0.059 0.37133E+04 85 glaucophane-Fe 17.28 13.12 -4.15 -0.112 0.70919E+04 86 graphite -3.55 -7.79 -4.24 -1.212 0.72451E+04 87 greenalite 16.14 13.89 -2.25 -0.187 0.38408E+04 90 hematite 12.57 8.99 -3.58 -0.434 0.61112E+04 91 heulandite -5.83 -7.52 -1.69 -0.077 0.28938E+04 95 jadeite 4.22 2.77 -1.44 -0.144 0.24617E+04 97 kalsilite 7.58 3.83 -3.76 -0.537 0.64125E+04 98 kaolinite -1.33 -4.84 -3.50 -0.319 0.59830E+04 101 laumontite 2.88 1.95 -0.93 -0.062 0.15934E+04 102 lawsonite 9.62 8.27 -1.35 -0.090 0.23068E+04 103 leucite 4.12 0.67 -3.45 -0.345 0.58872E+04 105 lizardite 23.24 21.57 -1.68 -0.140 0.28618E+04 107 magnetite 20.09 15.72 -4.37 -0.356 0.74536E+04 108 minnesotaite 10.39 7.58 -2.81 -0.165 0.48029E+04 112 manganosite 14.06 9.24 -4.82 -1.205 0.82271E+04 120 muscovite 2.58 -1.01 -3.59 -0.211 0.61313E+04 121 paragonite 4.24 1.09 -3.15 -0.185 0.53704E+04 122 nepheline 8.34 5.93 -2.41 -0.344 0.41124E+04 128 periclase-Fe 11.63 6.73 -4.89 -1.223 0.83523E+04 134 phlogopite-Na 29.65 27.50 -2.15 -0.119 0.36676E+04 136 prehnite 19.37 18.21 -1.16 -0.068 0.19847E+04 137 prehnite-Fe 22.50 21.96 -0.53 -0.032 0.91154E+03 138 pumpellyite-Fe 46.27 43.89 -2.38 -0.053 0.40577E+04 139 pumpellyite-Mg 48.99 46.45 -2.54 -0.057 0.43415E+04 143 pyrrhotite -4.26 -7.99 -3.73 -1.244 0.63742E+04 144 pyrrhotiteFe0.875 -6.02 -9.39 -3.37 -1.241 0.57615E+04 145 pyroxmangite 7.40 6.08 -1.32 -0.263 0.22475E+04 146 pyrophyllite -6.18 -11.15 -4.98 -0.311 0.84961E+04 147 quartz -2.99 -3.16 -0.17 -0.056 0.28684E+03 152 rhodonite 7.45 6.08 -1.36 -0.273 0.23278E+04 153 sanidine -1.28 -2.49 -1.21 -0.093 0.20677E+04 165 stilpnomelane-Mg 27.44 25.81 -1.63 -0.049 0.27802E+04 171 talc 16.49 15.25 -1.24 -0.073 0.21140E+04 174 tephroite 18.09 15.32 -2.76 -0.395 0.47188E+04 178 tridymite -2.63 -3.16 -0.53 -0.177 0.90681E+03 179 tremolite 47.87 47.42 -0.45 -0.012 0.77496E+03 180 ferroactinolite 38.45 34.62 -3.83 -0.104 0.65450E+04 181 troilite-low -4.41 -7.99 -3.58 -1.194 0.61170E+04 183 vesuvianite 223.47 218.82 -4.65 -0.036 0.79425E+04 187 wairakite 3.95 1.95 -2.00 -0.118 0.34154E+04 188 walstromite 11.51 9.94 -1.56 -0.313 0.26719E+04 189 wollastonite 10.46 9.94 -0.52 -0.103 0.88229E+03 190 pseudo-wollastonite 11.00 9.94 -1.06 -0.211 0.18021E+04 191 zoisite 22.85 18.95 -3.90 -0.177 0.66606E+04 192 akaganeite 7.75 4.49 -3.26 -0.705 0.55681E+04 199 chalcedony -2.80 -3.16 -0.35 -0.118 0.60613E+03 201 montmorillonite-Ca -2.29 -6.17 -3.88 -0.240 0.66180E+04 202 montmorillonite-K -2.24 -6.27 -4.03 -0.247 0.68816E+04 203 montmorillonite-Mg -2.48 -6.79 -4.31 -0.267 0.73677E+04 204 montmorillonite-Na -2.04 -5.57 -3.54 -0.216 0.60365E+04 205 nontronite-Ca 3.21 -0.19 -3.41 -0.221 0.58216E+04 206 nontronite-H 2.53 -2.36 -4.89 -0.328 0.83486E+04 207 nontronite-K 3.34 -0.30 -3.64 -0.233 0.62084E+04 208 nontronite-Mg 3.07 -0.82 -3.90 -0.253 0.66555E+04 209 nontronite-Na 3.52 0.40 -3.12 -0.200 0.53293E+04 224 tobermorite 9.82 7.76 -2.07 -0.564 0.35287E+04 230 alabandite -0.98 -5.49 -4.51 -1.504 0.77020E+04 233 boehmite 4.41 0.74 -3.67 -0.611 0.62618E+04 235 ferrous-oxide 9.81 6.73 -3.08 -0.769 0.52532E+04 240 silica-amorphous -2.09 -3.16 -1.07 -0.355 0.18203E+04 242 an20ab80 2.02 1.35 -0.67 -0.052 0.11472E+04 243 an25ab75 2.65 1.78 -0.87 -0.067 0.14809E+04 244 an30ab70 3.28 2.21 -1.07 -0.082 0.18243E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 40.0000000 g Current total amount of reactant added: 1519.9990000 g New total amount of reactant added: 1559.9990000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.3297E-10 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 11 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 1559.9990000 Water: Moles liquid = 0.4673E+02 kg liquid = 0.8418E+00 Moles total = 0.3595E+02 kg total = 0.6477E+00 Activity = 1.0000 Stoichiometric ionic strength = .1133904E-01 Osmotic coef. = 0.9692 True ionic strength = .2002470E-01 Chg. balance for total moles = 0.3297E-10 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.88321E-10 -10.0539 0.74210E-10 -10.1295 0.84023E+00 -0.0756 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.16315E-03 -3.7874 0.13626E-03 -3.8656 0.83518E+00 -0.0782 4 SO4-- 0.76885E-12 -12.1142 0.39923E-12 -12.3988 0.51926E+00 -0.2846 5 HCO3- 0.28451E-06 -6.5459 0.23796E-06 -6.6235 0.83640E+00 -0.0776 6 HS- 0.30292E-04 -4.5187 0.25303E-04 -4.5968 0.83530E+00 -0.0782 7 Al+++ 0.97014E-29 -29.0132 0.22409E-29 -29.6496 0.23099E+00 -0.6364 8 H4SiO4 0.69595E-03 -3.1574 0.69595E-03 -3.1574 0.10000E+01 0.0000 9 Ca++ 0.13508E-06 -6.8694 0.69627E-07 -7.1572 0.51545E+00 -0.2878 10 Mg++ 0.21132E-10 -10.6751 0.10843E-10 -10.9649 0.51309E+00 -0.2898 11 Fe++ 0.58242E-13 -13.2348 0.29917E-13 -13.5241 0.51366E+00 -0.2893 12 K+ 0.15656E-03 -3.8053 0.13098E-03 -3.8828 0.83660E+00 -0.0775 13 Na+ 0.19867E-01 -1.7019 0.16590E-01 -1.7802 0.83503E+00 -0.0783 14 Mn++ 0.18611E-10 -10.7302 0.95676E-11 -11.0192 0.51408E+00 -0.2890 15 HPO4-- 0.45294E-07 -7.3440 0.23523E-07 -7.6285 0.51934E+00 -0.2845 16 HSiO3- 0.10485E-01 -1.9794 0.87567E-02 -2.0577 0.83518E+00 -0.0782 17 Ca(HSiO3)+ 0.16594E-07 -7.7801 0.13885E-07 -7.8574 0.83678E+00 -0.0774 18 Mg(HSiO3)+ 0.32159E-11 -11.4927 0.26910E-11 -11.5701 0.83678E+00 -0.0774 19 NaHSiO3,aq 0.23495E-02 -2.6290 0.23495E-02 -2.6290 0.10000E+01 0.0000 20 AlO+ 0.66155E-16 -16.1794 0.55357E-16 -16.2568 0.83678E+00 -0.0774 22 HAlO2,aq 0.14855E-09 -9.8281 0.14855E-09 -9.8281 0.10000E+01 0.0000 23 AlO2- 0.53152E-05 -5.2745 0.44311E-05 -5.3535 0.83367E+00 -0.0790 24 CH4,aq 0.14701E-04 -4.8327 0.14650E-04 -4.8342 0.99654E+00 -0.0015 25 C2H6,aq 0.31784E-14 -14.4978 0.31675E-14 -14.4993 0.99654E+00 -0.0015 29 CO,aq 0.10980E-16 -16.9594 0.10980E-16 -16.9594 0.10000E+01 0.0000 30 CO2,aq 0.37865E-10 -10.4218 0.37734E-10 -10.4233 0.99654E+00 -0.0015 31 CO3-2 0.54054E-06 -6.2672 0.28009E-06 -6.5527 0.51816E+00 -0.2855 32 CaCO3,aq 0.24453E-09 -9.6117 0.24453E-09 -9.6117 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.50543E-12 -12.2963 0.42293E-12 -12.3737 0.83678E+00 -0.0774 34 CaCl+ 0.18349E-10 -10.7364 0.15354E-10 -10.8138 0.83678E+00 -0.0774 35 CaCl2,aq 0.49705E-15 -15.3036 0.49705E-15 -15.3036 0.10000E+01 0.0000 36 CaOH+ 0.79911E-07 -7.0974 0.66868E-07 -7.1748 0.83678E+00 -0.0774 37 CaSO4,aq 0.88270E-17 -17.0542 0.88270E-17 -17.0542 0.10000E+01 0.0000 38 HCl,aq 0.18530E-14 -14.7321 0.18530E-14 -14.7321 0.10000E+01 0.0000 43 FeCl+ 0.77110E-17 -17.1129 0.64524E-17 -17.1903 0.83678E+00 -0.0774 46 FeO,aq 0.21113E-09 -9.6755 0.21113E-09 -9.6755 0.10000E+01 0.0000 47 FeOH+ 0.15682E-10 -10.8046 0.13122E-10 -10.8820 0.83678E+00 -0.0774 48 HFeO2- 0.35642E-07 -7.4480 0.29768E-07 -7.5263 0.83518E+00 -0.0782 49 FeO+ 0.10990E-16 -16.9590 0.91963E-17 -17.0364 0.83678E+00 -0.0774 51 FeO2- 0.40912E-09 -9.3881 0.34169E-09 -9.4664 0.83518E+00 -0.0782 52 HFeO2,aq 0.32250E-11 -11.4915 0.32250E-11 -11.4915 0.10000E+01 0.0000 53 H2,aq 0.11624E-04 -4.9346 0.11584E-04 -4.9361 0.99654E+00 -0.0015 54 KCl,aq 0.32348E-09 -9.4902 0.32348E-09 -9.4902 0.10000E+01 0.0000 56 KOH,aq 0.75375E-06 -6.1228 0.75375E-06 -6.1228 0.10000E+01 0.0000 57 KSO4- 0.97158E-15 -15.0125 0.81144E-15 -15.0907 0.83518E+00 -0.0782 58 MgCO3,aq 0.95449E-14 -14.0202 0.95449E-14 -14.0202 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.80426E-16 -16.0946 0.67299E-16 -16.1720 0.83678E+00 -0.0774 60 MgCl+ 0.25898E-14 -14.5867 0.21671E-14 -14.6641 0.83678E+00 -0.0774 61 MgOH+ 0.68861E-10 -10.1620 0.57621E-10 -10.2394 0.83678E+00 -0.0774 63 MnO,aq 0.17992E-08 -8.7449 0.17992E-08 -8.7449 0.10000E+01 0.0000 64 MnOH+ 0.46590E-09 -9.3317 0.38986E-09 -9.4091 0.83678E+00 -0.0774 65 MnO2-2 0.20924E-10 -10.6794 0.10842E-10 -10.9649 0.51816E+00 -0.2855 66 HMnO2- 0.21106E-09 -9.6756 0.17627E-09 -9.7538 0.83518E+00 -0.0782 69 MnCl+ 0.95941E-14 -14.0180 0.80282E-14 -14.0954 0.83678E+00 -0.0774 71 NaCl,aq 0.74915E-06 -6.1254 0.74915E-06 -6.1254 0.10000E+01 0.0000 72 NaOH,aq 0.96047E-04 -4.0175 0.96047E-04 -4.0175 0.10000E+01 0.0000 74 OH- 0.93390E-02 -2.0297 0.77856E-02 -2.1087 0.83367E+00 -0.0790 79 HPO3-2 0.16388E-14 -14.7855 0.84916E-15 -15.0710 0.51816E+00 -0.2855 81 H2PO3- 0.15130E-18 -18.8201 0.12637E-18 -18.8984 0.83518E+00 -0.0782 82 H3PO4,aq 0.90603E-18 -18.0429 0.90603E-18 -18.0429 0.10000E+01 0.0000 83 H2PO4- 0.38521E-10 -10.4143 0.32203E-10 -10.4921 0.83597E+00 -0.0778 84 PO4-3 0.10660E-08 -8.9722 0.25862E-09 -9.5873 0.24261E+00 -0.6151 88 HP2O7-3 0.94622E-18 -18.0240 0.21878E-18 -18.6600 0.23122E+00 -0.6360 89 P2O7-4 0.91371E-17 -17.0392 0.70431E-18 -18.1522 0.77082E-01 -1.1130 90 H2S,aq 0.58235E-08 -8.2348 0.58033E-08 -8.2363 0.99654E+00 -0.0015 91 S2-2 0.23635E-14 -14.6265 0.12247E-14 -14.9120 0.51816E+00 -0.2855 97 SO3-2 0.11433E-17 -17.9418 0.60097E-18 -18.2211 0.52566E+00 -0.2793 99 HSO4- 0.34088E-19 -19.4674 0.28552E-19 -19.5444 0.83760E+00 -0.0770 Charge balance for all species = 0.3916E-10 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.8832083E-10 -.2229496E-01 -.2243293E+02 0.0000 2 H2O 0.1000000E+01 0.5550489E+02 0.9981992E+06 0.0000 3 Cl- 0.1631539E-03 0.1639034E-03 0.5800768E+01 6.2639 4 SO4-- 0.7688460E-12 -.1760685E-04 -.1688402E+01 7.8603 5 HCO3- 0.2845086E-06 0.1552622E-04 0.9457199E+00 3.5060 6 HS- 0.3029166E-04 0.4790433E-04 0.1581538E+01 5.5327 7 Al+++ 0.9701363E-29 0.5315364E-05 0.1431672E+00 0.7390 8 H4SiO4 0.6959468E-03 0.1353026E-01 0.1298206E+04 -3.1574 9 Ca++ 0.1350794E-06 0.2318470E-06 0.9275813E-02 13.1018 10 Mg++ 0.2113231E-10 0.9322135E-10 0.2262458E-05 9.2942 11 Fe++ 0.5824245E-13 0.3628153E-07 0.2022693E-02 6.7350 12 K+ 0.1565629E-03 0.1573169E-03 0.6140715E+01 6.2467 13 Na+ 0.1986705E-01 0.2231337E-01 0.5120884E+03 8.3494 14 Mn++ 0.1861107E-10 0.2515658E-08 0.1379650E-03 9.2399 15 HPO4-- 0.4529431E-07 0.4639884E-07 0.4445574E-02 12.6306 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.2583125E+02 -.1876794E-01 -.2581249E+02 0.0000000E+00 2 H2O 0.3595302E+02 0.4672411E+02 -.1077109E+02 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.4325839E-01 -.1482147E-04 0.4327322E-01 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.4323289E-01 0.4032594E-04 -.4327322E-01 0.0000000E+00 7 Al+++ 0.5086754E+01 0.4474482E-05 0.5086749E+01 0.0000000E+00 8 H4SiO4 0.1624393E+02 0.1138979E-01 0.1623254E+02 0.0000000E+00 9 Ca++ 0.1794236E+01 0.1951692E-06 0.1794236E+01 0.0000000E+00 10 Mg++ 0.1238094E+01 0.7847389E-10 0.1238094E+01 0.0000000E+00 11 Fe++ 0.1112293E+01 0.3054186E-07 0.1112293E+01 0.0000000E+00 12 K+ 0.3312100E+00 0.1324297E-03 0.3310775E+00 0.0000000E+00 13 Na+ 0.1958339E+01 0.1878344E-01 0.1939555E+01 0.0000000E+00 14 Mn++ 0.2704819E-01 0.2117685E-08 0.2704819E-01 0.0000000E+00 15 HPO4-- 0.9231414E-02 0.3905862E-07 0.9231375E-02 0.0000000E+00 Chg. balance for solid moles: 0.2682E-14 Mass of aqueous solution: 0.843267E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 1559.9990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 1.938 0.287 508.1 2.706 29.82 195.1 andradite 0.1731 -0.762 87.96 1.944 5.162 22.85 grossular 0.4192E-01 -1.378 18.88 1.276 1.108 5.254 apatite-OH 0.3077E-02 -2.512 1.546 0.189 0.9070E-01 0.4912 clinochlore 0.2225 -0.653 123.7 2.092 7.257 47.04 daphnite 0.6441E-01 -1.191 45.96 1.662 2.697 13.93 chlorite-Mn 0.5410E-02 -2.267 3.835 0.584 0.2251 1.222 diopside 0.7559E-01 -1.122 16.37 1.214 0.9606 5.003 hedenbergite 0.1960E-01 -1.708 4.863 0.687 0.2854 1.332 microcline 0.2904 -0.537 80.82 1.908 4.743 31.57 stilbite 1.011 0.005 712.5 2.853 41.81 332.3 stilpnomelane-Fe 0.8144E-01 -1.089 87.79 1.943 5.152 30.33 tr.625ac.25prg.125 0.1380E-01 -1.860 11.80 1.072 0.6922 3.797 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8050E+00 0.8050E+00 1.0000 -0.094 grossular 0.1950E+00 0.1950E+00 1.0000 -0.710 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.7612E+00 0.7612E+00 1.0000 -0.119 daphnite 0.2203E+00 0.2203E+00 1.0000 -0.657 chlorite-Mn 0.1851E-01 0.1851E-01 1.0000 -1.733 diopside 0.7941E+00 0.7941E+00 1.0000 -0.100 hedenbergite 0.2059E+00 0.2059E+00 1.0000 -0.686 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 tr.625ac.25prg.125 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 1704.115007 g Volume = 690.192450 cm3 Porosity: -10.4309% V(tot) - V(min): -.65193E+02 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 1559.9990000 g log = 3.1931 Original solution: 1000.0103000 g Original solution / Rock added: 0.64 (Water/Rock Ratio), log = -0.1931 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0573 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9655E+00 0.9855 0.1006E+01 0.1021E+01 CO2,gas 0.3792E-08 1.0069 0.4037E-08 0.4009E-08 CH4,gas 0.2014E-01 1.0124 0.2156E-01 0.2130E-01 H2,gas 0.1438E-01 1.0006 0.1521E-01 0.1520E-01 H2S,gas 0.1515E-06 0.9959 0.1595E-06 0.1602E-06 S2,gas 0.3906E-29 1.0000 0.4130E-29 0.4130E-29 CO,gas 0.1548E-13 1.0000 0.1636E-13 0.1636E-13 SO3,gas 0.7863E-48 1.0000 0.8313E-48 0.8313E-48 SO2,gas 0.4652E-27 1.0000 0.4919E-27 0.4919E-27 HCl,gas 0.3092E-17 1.0000 0.3270E-17 0.3270E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 16 albite -0.38 -0.38 0.00 0.000 -0.94784E-12 22 andradite 39.01 39.01 0.00 0.000 0.12132E-10 23 grossular 32.73 32.73 0.00 0.000 0.00000E+00 32 apatite-OH -18.15 -18.15 0.00 0.000 0.00000E+00 46 clinochlore 39.07 39.07 0.00 0.000 -0.36397E-10 47 daphnite 28.97 28.97 0.00 0.000 -0.12132E-10 48 chlorite-Mn 46.87 46.87 0.00 0.000 -0.72794E-10 67 diopside 16.18 16.18 0.00 0.000 0.00000E+00 68 hedenbergite 14.21 14.21 0.00 0.000 -0.60662E-11 116 microcline -2.49 -2.49 0.00 0.000 -0.10616E-10 163 stilbite -7.52 -7.52 0.00 0.000 -0.90992E-11 164 stilpnomelane-Fe 13.02 13.02 0.00 0.000 -0.75827E-10 245 tr.625ac.25prg.125 45.16 45.16 0.00 0.000 0.24265E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -16.75 -10.09 -3.364 0.17233E+05 -8.394 3 CH4,gas 4.54 1.18 -3.37 -0.841 0.57461E+04 -1.666 4 H2,gas 8.00 4.48 -3.52 -2.010 0.60050E+04 -1.818 5 H2S,gas -6.23 -14.73 -8.50 -4.248 0.14507E+05 -6.797 6 S2,gas -7.34 -38.42 -31.08 -4.782 0.53073E+05 -29.384 7 CO,gas 3.21 -12.27 -15.49 -4.765 0.26440E+05 -13.786 8 SO3,gas 17.12 -32.66 -49.78 -12.445 0.84997E+05 -48.080 9 SO2,gas 0.83 -28.17 -29.01 -7.735 0.49529E+05 -27.308 10 HCl,gas 5.19 -14.00 -19.18 -9.592 0.32757E+05 -17.485 11 acmite 7.71 6.53 -1.18 -0.123 0.20176E+04 15 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 19 spessartine 24.46 19.73 -4.73 -0.237 0.80796E+04 20 analcite 3.32 2.77 -0.55 -0.061 0.93621E+03 26 annite 20.12 17.72 -2.40 -0.134 0.41064E+04 27 phlogopite 27.06 25.40 -1.67 -0.093 0.28488E+04 29 anorthite 12.71 8.27 -4.45 -0.342 0.75901E+04 35 aragonite 0.97 -3.65 -4.62 -1.539 0.78846E+04 36 brucite 12.57 9.29 -3.27 -0.655 0.55909E+04 37 calcite 0.81 -3.65 -4.46 -1.488 0.76204E+04 38 carnegieite-low 9.02 5.93 -3.09 -0.442 0.52800E+04 39 carnegieite-high 10.09 5.93 -4.16 -0.595 0.71070E+04 40 carpholite-Mg 8.58 4.46 -4.12 -0.275 0.70427E+04 41 carpholite-Fe 6.71 1.90 -4.81 -0.321 0.82205E+04 42 celadonite 5.34 3.65 -1.69 -0.099 0.28879E+04 43 celadonite-Fe 3.88 1.09 -2.79 -0.164 0.47561E+04 44 chrysotile 23.89 21.57 -2.32 -0.194 0.39692E+04 49 chlorite-Al-free 47.17 43.14 -4.04 -0.168 0.68935E+04 51 chloritoid-Fe 9.17 5.06 -4.12 -0.275 0.70314E+04 52 chloritoid-Mn 11.40 7.56 -3.84 -0.256 0.65576E+04 54 coesite -2.38 -3.16 -0.78 -0.260 0.13342E+04 61 cristobalite -2.56 -3.16 -0.60 -0.199 0.10195E+04 63 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71234E+04 65 diaspore 2.87 0.74 -2.13 -0.356 0.36449E+04 66 diamond -3.10 -7.79 -4.68 -1.339 0.79993E+04 71 enstatite 17.26 12.27 -4.99 -0.499 0.85225E+04 73 clinoenstatite 17.17 12.27 -4.89 -0.489 0.83541E+04 75 epidote 24.67 22.70 -1.97 -0.095 0.33584E+04 76 clinozoisite 22.81 18.95 -3.86 -0.175 0.65866E+04 77 epidote-Fe 29.84 26.46 -3.38 -0.176 0.57768E+04 78 fayalite 14.05 10.31 -3.73 -0.533 0.63743E+04 79 ferrosilite 11.15 7.16 -3.99 -0.399 0.68202E+04 83 gibbsite 4.08 0.74 -3.34 -0.477 0.57034E+04 84 glaucophane 22.97 20.80 -2.17 -0.059 0.37133E+04 85 glaucophane-Fe 17.28 13.12 -4.15 -0.112 0.70919E+04 86 graphite -3.55 -7.79 -4.24 -1.212 0.72416E+04 87 greenalite 16.14 13.89 -2.25 -0.187 0.38408E+04 90 hematite 12.57 8.99 -3.58 -0.434 0.61112E+04 91 heulandite -5.83 -7.52 -1.69 -0.077 0.28938E+04 95 jadeite 4.22 2.77 -1.44 -0.144 0.24617E+04 97 kalsilite 7.58 3.83 -3.76 -0.537 0.64125E+04 98 kaolinite -1.33 -4.84 -3.50 -0.319 0.59830E+04 101 laumontite 2.88 1.95 -0.93 -0.062 0.15934E+04 102 lawsonite 9.62 8.27 -1.35 -0.090 0.23068E+04 103 leucite 4.12 0.67 -3.45 -0.345 0.58873E+04 105 lizardite 23.24 21.57 -1.68 -0.140 0.28618E+04 107 magnetite 20.09 15.72 -4.37 -0.356 0.74536E+04 108 minnesotaite 10.39 7.58 -2.81 -0.165 0.48029E+04 112 manganosite 14.06 9.24 -4.82 -1.205 0.82270E+04 120 muscovite 2.58 -1.01 -3.59 -0.211 0.61313E+04 121 paragonite 4.24 1.09 -3.15 -0.185 0.53704E+04 122 nepheline 8.34 5.93 -2.41 -0.344 0.41124E+04 128 periclase-Fe 11.63 6.73 -4.89 -1.223 0.83523E+04 134 phlogopite-Na 29.65 27.50 -2.15 -0.119 0.36676E+04 136 prehnite 19.37 18.21 -1.16 -0.068 0.19847E+04 137 prehnite-Fe 22.50 21.96 -0.53 -0.032 0.91154E+03 138 pumpellyite-Fe 46.27 43.89 -2.38 -0.053 0.40577E+04 139 pumpellyite-Mg 48.99 46.45 -2.54 -0.057 0.43415E+04 143 pyrrhotite -4.26 -7.99 -3.73 -1.244 0.63707E+04 144 pyrrhotiteFe0.875 -6.02 -9.39 -3.37 -1.240 0.57579E+04 145 pyroxmangite 7.40 6.08 -1.32 -0.263 0.22474E+04 146 pyrophyllite -6.18 -11.15 -4.98 -0.311 0.84961E+04 147 quartz -2.99 -3.16 -0.17 -0.056 0.28684E+03 152 rhodonite 7.45 6.08 -1.36 -0.273 0.23277E+04 153 sanidine -1.28 -2.49 -1.21 -0.093 0.20677E+04 165 stilpnomelane-Mg 27.44 25.81 -1.63 -0.049 0.27802E+04 171 talc 16.49 15.25 -1.24 -0.073 0.21140E+04 174 tephroite 18.09 15.32 -2.76 -0.395 0.47185E+04 178 tridymite -2.63 -3.16 -0.53 -0.177 0.90681E+03 179 tremolite 47.87 47.42 -0.45 -0.012 0.77496E+03 180 ferroactinolite 38.45 34.62 -3.83 -0.104 0.65450E+04 181 troilite-low -4.41 -7.99 -3.58 -1.193 0.61135E+04 183 vesuvianite 223.47 218.82 -4.65 -0.036 0.79426E+04 187 wairakite 3.95 1.95 -2.00 -0.118 0.34154E+04 188 walstromite 11.51 9.94 -1.56 -0.313 0.26719E+04 189 wollastonite 10.46 9.94 -0.52 -0.103 0.88229E+03 190 pseudo-wollastonite 11.00 9.94 -1.06 -0.211 0.18021E+04 191 zoisite 22.85 18.95 -3.90 -0.177 0.66606E+04 192 akaganeite 7.75 4.49 -3.26 -0.705 0.55681E+04 199 chalcedony -2.80 -3.16 -0.35 -0.118 0.60613E+03 201 montmorillonite-Ca -2.29 -6.17 -3.88 -0.240 0.66180E+04 202 montmorillonite-K -2.24 -6.27 -4.03 -0.247 0.68816E+04 203 montmorillonite-Mg -2.48 -6.79 -4.31 -0.267 0.73677E+04 204 montmorillonite-Na -2.04 -5.57 -3.54 -0.216 0.60365E+04 205 nontronite-Ca 3.21 -0.19 -3.41 -0.221 0.58216E+04 206 nontronite-H 2.53 -2.36 -4.89 -0.328 0.83486E+04 207 nontronite-K 3.34 -0.30 -3.64 -0.233 0.62084E+04 208 nontronite-Mg 3.07 -0.82 -3.90 -0.253 0.66555E+04 209 nontronite-Na 3.52 0.40 -3.12 -0.200 0.53293E+04 224 tobermorite 9.82 7.76 -2.07 -0.564 0.35287E+04 230 alabandite -0.98 -5.49 -4.51 -1.503 0.76984E+04 233 boehmite 4.41 0.74 -3.67 -0.611 0.62618E+04 235 ferrous-oxide 9.81 6.73 -3.08 -0.769 0.52532E+04 240 silica-amorphous -2.09 -3.16 -1.07 -0.355 0.18203E+04 242 an20ab80 2.02 1.35 -0.67 -0.052 0.11472E+04 243 an25ab75 2.65 1.78 -0.87 -0.067 0.14809E+04 244 an30ab70 3.28 2.21 -1.07 -0.082 0.18243E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 40.0000000 g Current total amount of reactant added: 1559.9990000 g New total amount of reactant added: 1599.9990000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.3297E-10 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 11 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 1599.9990000 Water: Moles liquid = 0.4650E+02 kg liquid = 0.8378E+00 Moles total = 0.3545E+02 kg total = 0.6387E+00 Activity = 1.0000 Stoichiometric ionic strength = .1133970E-01 Osmotic coef. = 0.9692 True ionic strength = .2002521E-01 Chg. balance for total moles = 0.3297E-10 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.88323E-10 -10.0539 0.74212E-10 -10.1295 0.84023E+00 -0.0756 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.16394E-03 -3.7853 0.13692E-03 -3.8635 0.83518E+00 -0.0782 4 SO4-- 0.77253E-12 -12.1121 0.40114E-12 -12.3967 0.51926E+00 -0.2846 5 HCO3- 0.28587E-06 -6.5438 0.23910E-06 -6.6214 0.83640E+00 -0.0776 6 HS- 0.30437E-04 -4.5166 0.25424E-04 -4.5948 0.83530E+00 -0.0782 7 Al+++ 0.97022E-29 -29.0131 0.22410E-29 -29.6495 0.23098E+00 -0.6364 8 H4SiO4 0.69595E-03 -3.1574 0.69595E-03 -3.1574 0.10000E+01 0.0000 9 Ca++ 0.13509E-06 -6.8694 0.69630E-07 -7.1572 0.51545E+00 -0.2878 10 Mg++ 0.21133E-10 -10.6750 0.10843E-10 -10.9648 0.51309E+00 -0.2898 11 Fe++ 0.58246E-13 -13.2347 0.29918E-13 -13.5241 0.51365E+00 -0.2893 12 K+ 0.15657E-03 -3.8053 0.13098E-03 -3.8828 0.83660E+00 -0.0775 13 Na+ 0.19868E-01 -1.7019 0.16590E-01 -1.7802 0.83503E+00 -0.0783 14 Mn++ 0.18615E-10 -10.7301 0.95694E-11 -11.0191 0.51408E+00 -0.2890 15 HPO4-- 0.45293E-07 -7.3440 0.23522E-07 -7.6285 0.51933E+00 -0.2846 16 HSiO3- 0.10485E-01 -1.9795 0.87565E-02 -2.0577 0.83518E+00 -0.0782 17 Ca(HSiO3)+ 0.16594E-07 -7.7800 0.13885E-07 -7.8574 0.83678E+00 -0.0774 18 Mg(HSiO3)+ 0.32160E-11 -11.4927 0.26911E-11 -11.5701 0.83678E+00 -0.0774 19 NaHSiO3,aq 0.23495E-02 -2.6290 0.23495E-02 -2.6290 0.10000E+01 0.0000 20 AlO+ 0.66156E-16 -16.1794 0.55358E-16 -16.2568 0.83678E+00 -0.0774 22 HAlO2,aq 0.14855E-09 -9.8281 0.14855E-09 -9.8281 0.10000E+01 0.0000 23 AlO2- 0.53151E-05 -5.2745 0.44310E-05 -5.3535 0.83367E+00 -0.0790 24 CH4,aq 0.14771E-04 -4.8306 0.14720E-04 -4.8321 0.99654E+00 -0.0015 25 C2H6,aq 0.32090E-14 -14.4936 0.31979E-14 -14.4951 0.99654E+00 -0.0015 29 CO,aq 0.11033E-16 -16.9573 0.11033E-16 -16.9573 0.10000E+01 0.0000 30 CO2,aq 0.38047E-10 -10.4197 0.37915E-10 -10.4212 0.99654E+00 -0.0015 31 CO3-2 0.54312E-06 -6.2651 0.28142E-06 -6.5506 0.51816E+00 -0.2855 32 CaCO3,aq 0.24570E-09 -9.6096 0.24570E-09 -9.6096 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.50787E-12 -12.2942 0.42498E-12 -12.3716 0.83678E+00 -0.0774 34 CaCl+ 0.18438E-10 -10.7343 0.15428E-10 -10.8117 0.83678E+00 -0.0774 35 CaCl2,aq 0.50185E-15 -15.2994 0.50185E-15 -15.2994 0.10000E+01 0.0000 36 CaOH+ 0.79913E-07 -7.0974 0.66869E-07 -7.1748 0.83678E+00 -0.0774 37 CaSO4,aq 0.88696E-17 -17.0521 0.88696E-17 -17.0521 0.10000E+01 0.0000 38 HCl,aq 0.18619E-14 -14.7300 0.18619E-14 -14.7300 0.10000E+01 0.0000 43 FeCl+ 0.77484E-17 -17.1108 0.64837E-17 -17.1882 0.83678E+00 -0.0774 46 FeO,aq 0.21113E-09 -9.6755 0.21113E-09 -9.6755 0.10000E+01 0.0000 47 FeOH+ 0.15682E-10 -10.8046 0.13123E-10 -10.8820 0.83678E+00 -0.0774 48 HFeO2- 0.35642E-07 -7.4480 0.29767E-07 -7.5263 0.83518E+00 -0.0782 49 FeO+ 0.10990E-16 -16.9590 0.91965E-17 -17.0364 0.83678E+00 -0.0774 51 FeO2- 0.40911E-09 -9.3882 0.34168E-09 -9.4664 0.83518E+00 -0.0782 52 HFeO2,aq 0.32250E-11 -11.4915 0.32250E-11 -11.4915 0.10000E+01 0.0000 53 H2,aq 0.11624E-04 -4.9346 0.11584E-04 -4.9361 0.99654E+00 -0.0015 54 KCl,aq 0.32504E-09 -9.4881 0.32504E-09 -9.4881 0.10000E+01 0.0000 56 KOH,aq 0.75375E-06 -6.1228 0.75375E-06 -6.1228 0.10000E+01 0.0000 57 KSO4- 0.97625E-15 -15.0104 0.81535E-15 -15.0887 0.83518E+00 -0.0782 58 MgCO3,aq 0.95908E-14 -14.0181 0.95908E-14 -14.0181 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.80815E-16 -16.0925 0.67624E-16 -16.1699 0.83678E+00 -0.0774 60 MgCl+ 0.26023E-14 -14.5846 0.21776E-14 -14.6620 0.83678E+00 -0.0774 61 MgOH+ 0.68862E-10 -10.1620 0.57623E-10 -10.2394 0.83678E+00 -0.0774 63 MnO,aq 0.17994E-08 -8.7449 0.17994E-08 -8.7449 0.10000E+01 0.0000 64 MnOH+ 0.46598E-09 -9.3316 0.38992E-09 -9.4090 0.83678E+00 -0.0774 65 MnO2-2 0.20926E-10 -10.6793 0.10843E-10 -10.9648 0.51816E+00 -0.2855 66 HMnO2- 0.21109E-09 -9.6755 0.17629E-09 -9.7538 0.83518E+00 -0.0782 69 MnCl+ 0.96419E-14 -14.0158 0.80682E-14 -14.0932 0.83678E+00 -0.0774 71 NaCl,aq 0.75276E-06 -6.1233 0.75276E-06 -6.1233 0.10000E+01 0.0000 72 NaOH,aq 0.96047E-04 -4.0175 0.96047E-04 -4.0175 0.10000E+01 0.0000 74 OH- 0.93388E-02 -2.0297 0.77854E-02 -2.1087 0.83367E+00 -0.0790 79 HPO3-2 0.16387E-14 -14.7855 0.84912E-15 -15.0710 0.51816E+00 -0.2855 81 H2PO3- 0.15130E-18 -18.8202 0.12636E-18 -18.8984 0.83518E+00 -0.0782 82 H3PO4,aq 0.90604E-18 -18.0429 0.90604E-18 -18.0429 0.10000E+01 0.0000 83 H2PO4- 0.38520E-10 -10.4143 0.32202E-10 -10.4921 0.83597E+00 -0.0778 84 PO4-3 0.10659E-08 -8.9723 0.25860E-09 -9.5874 0.24260E+00 -0.6151 88 HP2O7-3 0.94617E-18 -18.0240 0.21877E-18 -18.6600 0.23122E+00 -0.6360 89 P2O7-4 0.91365E-17 -17.0392 0.70424E-18 -18.1523 0.77080E-01 -1.1131 90 H2S,aq 0.58515E-08 -8.2327 0.58313E-08 -8.2342 0.99654E+00 -0.0015 91 S2-2 0.23862E-14 -14.6223 0.12364E-14 -14.9078 0.51816E+00 -0.2855 97 SO3-2 0.11488E-17 -17.9398 0.60385E-18 -18.2191 0.52565E+00 -0.2793 99 HSO4- 0.34252E-19 -19.4653 0.28690E-19 -19.5423 0.83759E+00 -0.0770 Charge balance for all species = 0.3935E-10 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.8832309E-10 -.2229455E-01 -.2243251E+02 0.0000 2 H2O 0.1000000E+01 0.5550489E+02 0.9981992E+06 0.0000 3 Cl- 0.1639362E-03 0.1646893E-03 0.5828582E+01 6.2660 4 SO4-- 0.7725302E-12 -.1767734E-04 -.1695162E+01 7.8624 5 HCO3- 0.2858713E-06 0.1560067E-04 0.9502545E+00 3.5081 6 HS- 0.3043690E-04 0.4812009E-04 0.1588661E+01 5.5348 7 Al+++ 0.9702158E-29 0.5315219E-05 0.1431633E+00 0.7390 8 H4SiO4 0.6959480E-03 0.1353005E-01 0.1298185E+04 -3.1574 9 Ca++ 0.1350865E-06 0.2318577E-06 0.9276243E-02 13.1018 10 Mg++ 0.2113343E-10 0.9322387E-10 0.2262519E-05 9.2942 11 Fe++ 0.5824559E-13 0.3628071E-07 0.2022647E-02 6.7350 12 K+ 0.1565669E-03 0.1573210E-03 0.6140872E+01 6.2467 13 Na+ 0.1986755E-01 0.2231389E-01 0.5121002E+03 8.3494 14 Mn++ 0.1861472E-10 0.2516022E-08 0.1379849E-03 9.2399 15 HPO4-- 0.4529258E-07 0.4639705E-07 0.4445402E-02 12.6305 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.2649360E+02 -.1867803E-01 -.2647492E+02 0.0000000E+00 2 H2O 0.3545161E+02 0.4650114E+02 -.1104954E+02 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.4436693E-01 -.1480980E-04 0.4438174E-01 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.4434143E-01 0.4031427E-04 -.4438174E-01 0.0000000E+00 7 Al+++ 0.5217183E+01 0.4453009E-05 0.5217179E+01 0.0000000E+00 8 H4SiO4 0.1666044E+02 0.1133527E-01 0.1664911E+02 0.0000000E+00 9 Ca++ 0.1840242E+01 0.1942469E-06 0.1840241E+01 0.0000000E+00 10 Mg++ 0.1269840E+01 0.7810153E-10 0.1269840E+01 0.0000000E+00 11 Fe++ 0.1140813E+01 0.3039542E-07 0.1140813E+01 0.0000000E+00 12 K+ 0.3397025E+00 0.1318011E-03 0.3395707E+00 0.0000000E+00 13 Na+ 0.2008549E+01 0.1869423E-01 0.1989854E+01 0.0000000E+00 14 Mn++ 0.2774174E-01 0.2107884E-08 0.2774173E-01 0.0000000E+00 15 HPO4-- 0.9468117E-02 0.3887074E-07 0.9468078E-02 0.0000000E+00 Chg. balance for solid moles: 0.4965E-14 Mass of aqueous solution: 0.839243E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 1599.9990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 1.988 0.298 521.3 2.717 29.83 200.1 andradite 0.1775 -0.751 90.22 1.955 5.162 23.44 grossular 0.4299E-01 -1.367 19.37 1.287 1.108 5.389 apatite-OH 0.3156E-02 -2.501 1.585 0.200 0.9070E-01 0.5038 clinochlore 0.2282 -0.642 126.8 2.103 7.256 48.24 daphnite 0.6605E-01 -1.180 47.13 1.673 2.696 14.28 chlorite-Mn 0.5548E-02 -2.256 3.934 0.595 0.2251 1.254 diopside 0.7777E-01 -1.109 16.84 1.226 0.9635 5.147 hedenbergite 0.2017E-01 -1.695 5.003 0.699 0.2863 1.370 microcline 0.2978 -0.526 82.89 1.919 4.743 32.38 stilbite 1.037 0.016 730.6 2.864 41.80 340.8 stilpnomelane-Fe 0.8353E-01 -1.078 90.05 1.954 5.152 31.10 tr.625ac.25prg.125 0.1413E-01 -1.850 12.08 1.082 0.6912 3.888 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8050E+00 0.8050E+00 1.0000 -0.094 grossular 0.1950E+00 0.1950E+00 1.0000 -0.710 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.7612E+00 0.7612E+00 1.0000 -0.119 daphnite 0.2203E+00 0.2203E+00 1.0000 -0.657 chlorite-Mn 0.1851E-01 0.1851E-01 1.0000 -1.733 diopside 0.7941E+00 0.7941E+00 1.0000 -0.100 hedenbergite 0.2059E+00 0.2059E+00 1.0000 -0.686 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 tr.625ac.25prg.125 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 1747.815272 g Volume = 707.873676 cm3 Porosity: -10.4328% V(tot) - V(min): -.66874E+02 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 1599.9990000 g log = 3.2041 Original solution: 1000.0103000 g Original solution / Rock added: 0.63 (Water/Rock Ratio), log = -0.2041 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0574 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9654E+00 0.9854 0.1006E+01 0.1021E+01 CO2,gas 0.3810E-08 1.0069 0.4057E-08 0.4029E-08 CH4,gas 0.2024E-01 1.0124 0.2167E-01 0.2140E-01 H2,gas 0.1437E-01 1.0006 0.1521E-01 0.1520E-01 H2S,gas 0.1522E-06 0.9959 0.1603E-06 0.1610E-06 S2,gas 0.3944E-29 1.0000 0.4170E-29 0.4170E-29 CO,gas 0.1555E-13 1.0000 0.1644E-13 0.1644E-13 SO3,gas 0.7900E-48 1.0000 0.8353E-48 0.8353E-48 SO2,gas 0.4674E-27 1.0000 0.4942E-27 0.4942E-27 HCl,gas 0.3107E-17 1.0000 0.3285E-17 0.3285E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 16 albite -0.38 -0.38 0.00 0.000 -0.94784E-12 22 andradite 39.01 39.01 0.00 0.000 -0.24265E-10 23 grossular 32.73 32.73 0.00 0.000 -0.12132E-10 32 apatite-OH -18.15 -18.15 0.00 0.000 0.60662E-11 46 clinochlore 39.07 39.07 0.00 0.000 -0.12132E-10 47 daphnite 28.97 28.97 0.00 0.000 0.00000E+00 48 chlorite-Mn 46.87 46.87 0.00 0.000 0.24265E-10 67 diopside 16.18 16.18 0.00 0.000 0.00000E+00 68 hedenbergite 14.21 14.21 0.00 0.000 0.60662E-11 116 microcline -2.49 -2.49 0.00 0.000 0.15165E-11 163 stilbite -7.52 -7.52 0.00 0.000 0.15165E-10 164 stilpnomelane-Fe 13.02 13.02 0.00 0.000 0.21232E-10 245 tr.625ac.25prg.125 45.16 45.16 0.00 0.000 -0.36397E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -16.75 -10.09 -3.364 0.17230E+05 -8.392 3 CH4,gas 4.54 1.18 -3.36 -0.841 0.57425E+04 -1.664 4 H2,gas 8.00 4.48 -3.52 -2.010 0.60050E+04 -1.818 5 H2S,gas -6.23 -14.72 -8.49 -4.247 0.14503E+05 -6.795 6 S2,gas -7.34 -38.41 -31.08 -4.781 0.53066E+05 -29.380 7 CO,gas 3.21 -12.27 -15.48 -4.764 0.26437E+05 -13.784 8 SO3,gas 17.12 -32.66 -49.78 -12.444 0.84993E+05 -48.078 9 SO2,gas 0.83 -28.17 -29.01 -7.735 0.49525E+05 -27.306 10 HCl,gas 5.19 -13.99 -19.18 -9.591 0.32753E+05 -17.483 11 acmite 7.71 6.53 -1.18 -0.123 0.20176E+04 15 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 19 spessartine 24.46 19.73 -4.73 -0.237 0.80793E+04 20 analcite 3.32 2.77 -0.55 -0.061 0.93622E+03 26 annite 20.12 17.72 -2.40 -0.134 0.41064E+04 27 phlogopite 27.06 25.40 -1.67 -0.093 0.28488E+04 29 anorthite 12.71 8.27 -4.45 -0.342 0.75901E+04 35 aragonite 0.97 -3.65 -4.62 -1.539 0.78810E+04 36 brucite 12.57 9.29 -3.27 -0.655 0.55909E+04 37 calcite 0.81 -3.65 -4.46 -1.487 0.76168E+04 38 carnegieite-low 9.02 5.93 -3.09 -0.442 0.52800E+04 39 carnegieite-high 10.09 5.93 -4.16 -0.595 0.71070E+04 40 carpholite-Mg 8.58 4.46 -4.12 -0.275 0.70427E+04 41 carpholite-Fe 6.71 1.90 -4.81 -0.321 0.82205E+04 42 celadonite 5.34 3.65 -1.69 -0.099 0.28879E+04 43 celadonite-Fe 3.88 1.09 -2.79 -0.164 0.47561E+04 44 chrysotile 23.89 21.57 -2.32 -0.194 0.39692E+04 49 chlorite-Al-free 47.17 43.14 -4.04 -0.168 0.68935E+04 51 chloritoid-Fe 9.17 5.06 -4.12 -0.275 0.70314E+04 52 chloritoid-Mn 11.40 7.56 -3.84 -0.256 0.65575E+04 54 coesite -2.38 -3.16 -0.78 -0.260 0.13342E+04 61 cristobalite -2.56 -3.16 -0.60 -0.199 0.10195E+04 63 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71234E+04 65 diaspore 2.87 0.74 -2.13 -0.356 0.36449E+04 66 diamond -3.10 -7.79 -4.68 -1.338 0.79958E+04 71 enstatite 17.26 12.27 -4.99 -0.499 0.85225E+04 73 clinoenstatite 17.17 12.27 -4.89 -0.489 0.83541E+04 75 epidote 24.67 22.70 -1.97 -0.095 0.33584E+04 76 clinozoisite 22.81 18.95 -3.86 -0.175 0.65866E+04 77 epidote-Fe 29.84 26.46 -3.38 -0.176 0.57768E+04 78 fayalite 14.05 10.31 -3.73 -0.533 0.63743E+04 79 ferrosilite 11.15 7.16 -3.99 -0.399 0.68202E+04 83 gibbsite 4.08 0.74 -3.34 -0.477 0.57034E+04 84 glaucophane 22.97 20.80 -2.17 -0.059 0.37133E+04 85 glaucophane-Fe 17.28 13.12 -4.15 -0.112 0.70919E+04 86 graphite -3.55 -7.79 -4.24 -1.211 0.72380E+04 87 greenalite 16.14 13.89 -2.25 -0.187 0.38408E+04 90 hematite 12.57 8.99 -3.58 -0.434 0.61112E+04 91 heulandite -5.83 -7.52 -1.69 -0.077 0.28938E+04 95 jadeite 4.22 2.77 -1.44 -0.144 0.24617E+04 97 kalsilite 7.58 3.83 -3.76 -0.537 0.64125E+04 98 kaolinite -1.33 -4.84 -3.50 -0.319 0.59830E+04 101 laumontite 2.88 1.95 -0.93 -0.062 0.15934E+04 102 lawsonite 9.62 8.27 -1.35 -0.090 0.23068E+04 103 leucite 4.12 0.67 -3.45 -0.345 0.58873E+04 105 lizardite 23.24 21.57 -1.68 -0.140 0.28618E+04 107 magnetite 20.09 15.72 -4.37 -0.356 0.74536E+04 108 minnesotaite 10.39 7.58 -2.81 -0.165 0.48029E+04 112 manganosite 14.06 9.24 -4.82 -1.205 0.82269E+04 120 muscovite 2.58 -1.01 -3.59 -0.211 0.61313E+04 121 paragonite 4.24 1.09 -3.15 -0.185 0.53704E+04 122 nepheline 8.34 5.93 -2.41 -0.344 0.41124E+04 128 periclase-Fe 11.63 6.73 -4.89 -1.223 0.83523E+04 134 phlogopite-Na 29.65 27.50 -2.15 -0.119 0.36676E+04 136 prehnite 19.37 18.21 -1.16 -0.068 0.19848E+04 137 prehnite-Fe 22.50 21.96 -0.53 -0.032 0.91154E+03 138 pumpellyite-Fe 46.27 43.89 -2.38 -0.053 0.40577E+04 139 pumpellyite-Mg 48.99 46.45 -2.54 -0.057 0.43415E+04 143 pyrrhotite -4.26 -7.99 -3.73 -1.243 0.63671E+04 144 pyrrhotiteFe0.875 -6.02 -9.39 -3.37 -1.239 0.57544E+04 145 pyroxmangite 7.40 6.08 -1.32 -0.263 0.22473E+04 146 pyrophyllite -6.18 -11.15 -4.98 -0.311 0.84961E+04 147 quartz -2.99 -3.16 -0.17 -0.056 0.28683E+03 152 rhodonite 7.45 6.08 -1.36 -0.273 0.23276E+04 153 sanidine -1.28 -2.49 -1.21 -0.093 0.20677E+04 165 stilpnomelane-Mg 27.44 25.81 -1.63 -0.049 0.27802E+04 171 talc 16.49 15.25 -1.24 -0.073 0.21140E+04 174 tephroite 18.09 15.32 -2.76 -0.395 0.47183E+04 178 tridymite -2.63 -3.16 -0.53 -0.177 0.90681E+03 179 tremolite 47.87 47.42 -0.45 -0.012 0.77496E+03 180 ferroactinolite 38.45 34.62 -3.83 -0.104 0.65450E+04 181 troilite-low -4.41 -7.99 -3.58 -1.193 0.61099E+04 183 vesuvianite 223.47 218.82 -4.65 -0.036 0.79426E+04 187 wairakite 3.95 1.95 -2.00 -0.118 0.34154E+04 188 walstromite 11.51 9.94 -1.56 -0.313 0.26719E+04 189 wollastonite 10.46 9.94 -0.52 -0.103 0.88229E+03 190 pseudo-wollastonite 11.00 9.94 -1.06 -0.211 0.18021E+04 191 zoisite 22.85 18.95 -3.90 -0.177 0.66607E+04 192 akaganeite 7.75 4.49 -3.26 -0.705 0.55681E+04 199 chalcedony -2.80 -3.16 -0.35 -0.118 0.60613E+03 201 montmorillonite-Ca -2.29 -6.17 -3.88 -0.240 0.66180E+04 202 montmorillonite-K -2.24 -6.27 -4.03 -0.247 0.68816E+04 203 montmorillonite-Mg -2.48 -6.79 -4.31 -0.267 0.73677E+04 204 montmorillonite-Na -2.04 -5.57 -3.54 -0.216 0.60365E+04 205 nontronite-Ca 3.21 -0.19 -3.41 -0.221 0.58216E+04 206 nontronite-H 2.53 -2.36 -4.89 -0.328 0.83486E+04 207 nontronite-K 3.34 -0.30 -3.64 -0.233 0.62084E+04 208 nontronite-Mg 3.07 -0.82 -3.90 -0.253 0.66554E+04 209 nontronite-Na 3.52 0.40 -3.12 -0.200 0.53293E+04 224 tobermorite 9.82 7.76 -2.07 -0.564 0.35287E+04 230 alabandite -0.98 -5.48 -4.51 -1.502 0.76947E+04 233 boehmite 4.41 0.74 -3.67 -0.611 0.62618E+04 235 ferrous-oxide 9.81 6.73 -3.08 -0.769 0.52532E+04 240 silica-amorphous -2.09 -3.16 -1.07 -0.355 0.18203E+04 242 an20ab80 2.02 1.35 -0.67 -0.052 0.11472E+04 243 an25ab75 2.65 1.78 -0.87 -0.067 0.14809E+04 244 an30ab70 3.28 2.21 -1.07 -0.082 0.18243E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 40.0000000 g Current total amount of reactant added: 1599.9990000 g New total amount of reactant added: 1639.9990000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.3297E-10 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 11 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 1639.9990000 Water: Moles liquid = 0.4628E+02 kg liquid = 0.8338E+00 Moles total = 0.3495E+02 kg total = 0.6296E+00 Activity = 1.0000 Stoichiometric ionic strength = .1134036E-01 Osmotic coef. = 0.9692 True ionic strength = .2002573E-01 Chg. balance for total moles = 0.3297E-10 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.88325E-10 -10.0539 0.74214E-10 -10.1295 0.84023E+00 -0.0756 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.16473E-03 -3.7832 0.13758E-03 -3.8615 0.83518E+00 -0.0782 4 SO4-- 0.77625E-12 -12.1100 0.40307E-12 -12.3946 0.51926E+00 -0.2846 5 HCO3- 0.28725E-06 -6.5417 0.24025E-06 -6.6193 0.83640E+00 -0.0776 6 HS- 0.30584E-04 -4.5145 0.25546E-04 -4.5927 0.83530E+00 -0.0782 7 Al+++ 0.97030E-29 -29.0131 0.22412E-29 -29.6495 0.23098E+00 -0.6364 8 H4SiO4 0.69595E-03 -3.1574 0.69595E-03 -3.1574 0.10000E+01 0.0000 9 Ca++ 0.13509E-06 -6.8694 0.69633E-07 -7.1572 0.51544E+00 -0.2878 10 Mg++ 0.21135E-10 -10.6750 0.10844E-10 -10.9648 0.51309E+00 -0.2898 11 Fe++ 0.58249E-13 -13.2347 0.29919E-13 -13.5240 0.51365E+00 -0.2893 12 K+ 0.15657E-03 -3.8053 0.13099E-03 -3.8828 0.83660E+00 -0.0775 13 Na+ 0.19868E-01 -1.7018 0.16590E-01 -1.7801 0.83503E+00 -0.0783 14 Mn++ 0.18618E-10 -10.7301 0.95712E-11 -11.0190 0.51407E+00 -0.2890 15 HPO4-- 0.45291E-07 -7.3440 0.23521E-07 -7.6285 0.51933E+00 -0.2846 16 HSiO3- 0.10484E-01 -1.9795 0.87563E-02 -2.0577 0.83518E+00 -0.0782 17 Ca(HSiO3)+ 0.16594E-07 -7.7800 0.13886E-07 -7.8574 0.83678E+00 -0.0774 18 Mg(HSiO3)+ 0.32161E-11 -11.4927 0.26912E-11 -11.5701 0.83678E+00 -0.0774 19 NaHSiO3,aq 0.23495E-02 -2.6290 0.23495E-02 -2.6290 0.10000E+01 0.0000 20 AlO+ 0.66157E-16 -16.1794 0.55359E-16 -16.2568 0.83678E+00 -0.0774 22 HAlO2,aq 0.14855E-09 -9.8281 0.14855E-09 -9.8281 0.10000E+01 0.0000 23 AlO2- 0.53149E-05 -5.2745 0.44309E-05 -5.3535 0.83367E+00 -0.0790 24 CH4,aq 0.14843E-04 -4.8285 0.14791E-04 -4.8300 0.99654E+00 -0.0015 25 C2H6,aq 0.32400E-14 -14.4895 0.32288E-14 -14.4910 0.99654E+00 -0.0015 29 CO,aq 0.11086E-16 -16.9552 0.11086E-16 -16.9552 0.10000E+01 0.0000 30 CO2,aq 0.38231E-10 -10.4176 0.38099E-10 -10.4191 0.99654E+00 -0.0015 31 CO3-2 0.54572E-06 -6.2630 0.28277E-06 -6.5486 0.51815E+00 -0.2855 32 CaCO3,aq 0.24689E-09 -9.6075 0.24689E-09 -9.6075 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.51034E-12 -12.2921 0.42704E-12 -12.3695 0.83678E+00 -0.0774 34 CaCl+ 0.18527E-10 -10.7322 0.15503E-10 -10.8096 0.83678E+00 -0.0774 35 CaCl2,aq 0.50672E-15 -15.2952 0.50672E-15 -15.2952 0.10000E+01 0.0000 36 CaOH+ 0.79915E-07 -7.0974 0.66871E-07 -7.1748 0.83678E+00 -0.0774 37 CaSO4,aq 0.89127E-17 -17.0500 0.89127E-17 -17.0500 0.10000E+01 0.0000 38 HCl,aq 0.18709E-14 -14.7279 0.18709E-14 -14.7279 0.10000E+01 0.0000 43 FeCl+ 0.77861E-17 -17.1087 0.65152E-17 -17.1861 0.83678E+00 -0.0774 46 FeO,aq 0.21113E-09 -9.6755 0.21113E-09 -9.6755 0.10000E+01 0.0000 47 FeOH+ 0.15683E-10 -10.8046 0.13123E-10 -10.8820 0.83678E+00 -0.0774 48 HFeO2- 0.35641E-07 -7.4481 0.29766E-07 -7.5263 0.83518E+00 -0.0782 49 FeO+ 0.10991E-16 -16.9590 0.91967E-17 -17.0364 0.83678E+00 -0.0774 51 FeO2- 0.40911E-09 -9.3882 0.34168E-09 -9.4664 0.83518E+00 -0.0782 52 HFeO2,aq 0.32250E-11 -11.4915 0.32250E-11 -11.4915 0.10000E+01 0.0000 53 H2,aq 0.11624E-04 -4.9346 0.11584E-04 -4.9362 0.99654E+00 -0.0015 54 KCl,aq 0.32661E-09 -9.4860 0.32661E-09 -9.4860 0.10000E+01 0.0000 56 KOH,aq 0.75375E-06 -6.1228 0.75375E-06 -6.1228 0.10000E+01 0.0000 57 KSO4- 0.98097E-15 -15.0083 0.81929E-15 -15.0866 0.83518E+00 -0.0782 58 MgCO3,aq 0.96372E-14 -14.0161 0.96372E-14 -14.0161 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.81208E-16 -16.0904 0.67953E-16 -16.1678 0.83678E+00 -0.0774 60 MgCl+ 0.26150E-14 -14.5825 0.21882E-14 -14.6599 0.83678E+00 -0.0774 61 MgOH+ 0.68864E-10 -10.1620 0.57624E-10 -10.2394 0.83678E+00 -0.0774 63 MnO,aq 0.17997E-08 -8.7448 0.17997E-08 -8.7448 0.10000E+01 0.0000 64 MnOH+ 0.46605E-09 -9.3316 0.38998E-09 -9.4090 0.83678E+00 -0.0774 65 MnO2-2 0.20928E-10 -10.6793 0.10844E-10 -10.9648 0.51815E+00 -0.2855 66 HMnO2- 0.21111E-09 -9.6755 0.17631E-09 -9.7537 0.83518E+00 -0.0782 69 MnCl+ 0.96902E-14 -14.0137 0.81085E-14 -14.0911 0.83678E+00 -0.0774 71 NaCl,aq 0.75640E-06 -6.1212 0.75640E-06 -6.1212 0.10000E+01 0.0000 72 NaOH,aq 0.96047E-04 -4.0175 0.96047E-04 -4.0175 0.10000E+01 0.0000 74 OH- 0.93385E-02 -2.0297 0.77853E-02 -2.1087 0.83367E+00 -0.0790 79 HPO3-2 0.16387E-14 -14.7855 0.84908E-15 -15.0711 0.51815E+00 -0.2855 81 H2PO3- 0.15130E-18 -18.8202 0.12636E-18 -18.8984 0.83518E+00 -0.0782 82 H3PO4,aq 0.90604E-18 -18.0429 0.90604E-18 -18.0429 0.10000E+01 0.0000 83 H2PO4- 0.38520E-10 -10.4143 0.32201E-10 -10.4921 0.83597E+00 -0.0778 84 PO4-3 0.10659E-08 -8.9723 0.25858E-09 -9.5874 0.24260E+00 -0.6151 88 HP2O7-3 0.94612E-18 -18.0241 0.21875E-18 -18.6600 0.23121E+00 -0.6360 89 P2O7-4 0.91359E-17 -17.0392 0.70418E-18 -18.1523 0.77078E-01 -1.1131 90 H2S,aq 0.58798E-08 -8.2306 0.58595E-08 -8.2321 0.99654E+00 -0.0015 91 S2-2 0.24093E-14 -14.6181 0.12484E-14 -14.9037 0.51815E+00 -0.2855 97 SO3-2 0.11543E-17 -17.9377 0.60675E-18 -18.2170 0.52565E+00 -0.2793 99 HSO4- 0.34418E-19 -19.4632 0.28828E-19 -19.5402 0.83759E+00 -0.0770 Charge balance for all species = 0.3954E-10 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.8832536E-10 -.2229413E-01 -.2243209E+02 0.0000 2 H2O 0.1000000E+01 0.5550489E+02 0.9981991E+06 0.0000 3 Cl- 0.1647260E-03 0.1654828E-03 0.5856663E+01 6.2681 4 SO4-- 0.7762492E-12 -.1774851E-04 -.1701987E+01 7.8644 5 HCO3- 0.2872467E-06 0.1567583E-04 0.9548328E+00 3.5102 6 HS- 0.3058354E-04 0.4833793E-04 0.1595853E+01 5.5368 7 Al+++ 0.9702963E-29 0.5315075E-05 0.1431594E+00 0.7390 8 H4SiO4 0.6959491E-03 0.1352983E-01 0.1298165E+04 -3.1574 9 Ca++ 0.1350937E-06 0.2318686E-06 0.9276677E-02 13.1018 10 Mg++ 0.2113456E-10 0.9322667E-10 0.2262587E-05 9.2942 11 Fe++ 0.5824877E-13 0.3627988E-07 0.2022601E-02 6.7350 12 K+ 0.1565709E-03 0.1573250E-03 0.6141029E+01 6.2467 13 Na+ 0.1986807E-01 0.2231441E-01 0.5121121E+03 8.3494 14 Mn++ 0.1861825E-10 0.2516368E-08 0.1380039E-03 9.2400 15 HPO4-- 0.4529083E-07 0.4639524E-07 0.4445229E-02 12.6305 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.2715594E+02 -.1858812E-01 -.2713735E+02 0.0000000E+00 2 H2O 0.3495019E+02 0.4627818E+02 -.1132799E+02 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.4547547E-01 -.1479813E-04 0.4549027E-01 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.4544996E-01 0.4030260E-04 -.4549027E-01 0.0000000E+00 7 Al+++ 0.5347613E+01 0.4431537E-05 0.5347609E+01 0.0000000E+00 8 H4SiO4 0.1707695E+02 0.1128074E-01 0.1706567E+02 0.0000000E+00 9 Ca++ 0.1886247E+01 0.1933245E-06 0.1886247E+01 0.0000000E+00 10 Mg++ 0.1301587E+01 0.7772938E-10 0.1301587E+01 0.0000000E+00 11 Fe++ 0.1169333E+01 0.3024899E-07 0.1169333E+01 0.0000000E+00 12 K+ 0.3481951E+00 0.1311725E-03 0.3480639E+00 0.0000000E+00 13 Na+ 0.2058758E+01 0.1860503E-01 0.2040153E+01 0.0000000E+00 14 Mn++ 0.2843528E-01 0.2098066E-08 0.2843528E-01 0.0000000E+00 15 HPO4-- 0.9704820E-02 0.3868285E-07 0.9704781E-02 0.0000000E+00 Chg. balance for solid moles: 0.2460E-14 Mass of aqueous solution: 0.835219E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 1639.9990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 2.038 0.309 534.5 2.728 29.83 205.2 andradite 0.1820 -0.740 92.47 1.966 5.161 24.02 grossular 0.4407E-01 -1.356 19.85 1.298 1.108 5.523 apatite-OH 0.3235E-02 -2.490 1.625 0.211 0.9070E-01 0.5164 clinochlore 0.2338 -0.631 130.0 2.114 7.255 49.44 daphnite 0.6769E-01 -1.169 48.30 1.684 2.696 14.64 chlorite-Mn 0.5687E-02 -2.245 4.032 0.606 0.2251 1.285 diopside 0.7994E-01 -1.097 17.31 1.238 0.9663 5.291 hedenbergite 0.2073E-01 -1.683 5.143 0.711 0.2871 1.409 microcline 0.3053 -0.515 84.96 1.929 4.743 33.19 stilbite 1.062 0.026 748.7 2.874 41.79 349.2 stilpnomelane-Fe 0.8563E-01 -1.067 92.30 1.965 5.152 31.88 tr.625ac.25prg.125 0.1447E-01 -1.840 12.37 1.092 0.6903 3.980 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8050E+00 0.8050E+00 1.0000 -0.094 grossular 0.1950E+00 0.1950E+00 1.0000 -0.710 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.7611E+00 0.7611E+00 1.0000 -0.119 daphnite 0.2203E+00 0.2203E+00 1.0000 -0.657 chlorite-Mn 0.1851E-01 0.1851E-01 1.0000 -1.733 diopside 0.7941E+00 0.7941E+00 1.0000 -0.100 hedenbergite 0.2059E+00 0.2059E+00 1.0000 -0.686 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 tr.625ac.25prg.125 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 1791.515538 g Volume = 725.554902 cm3 Porosity: -10.4346% V(tot) - V(min): -.68555E+02 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 1639.9990000 g log = 3.2148 Original solution: 1000.0103000 g Original solution / Rock added: 0.61 (Water/Rock Ratio), log = -0.2148 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0575 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9653E+00 0.9854 0.1006E+01 0.1021E+01 CO2,gas 0.3828E-08 1.0069 0.4076E-08 0.4048E-08 CH4,gas 0.2033E-01 1.0124 0.2177E-01 0.2150E-01 H2,gas 0.1437E-01 1.0006 0.1521E-01 0.1520E-01 H2S,gas 0.1529E-06 0.9959 0.1611E-06 0.1617E-06 S2,gas 0.3982E-29 1.0000 0.4211E-29 0.4211E-29 CO,gas 0.1562E-13 1.0000 0.1652E-13 0.1652E-13 SO3,gas 0.7937E-48 1.0000 0.8394E-48 0.8394E-48 SO2,gas 0.4696E-27 1.0000 0.4966E-27 0.4966E-27 HCl,gas 0.3122E-17 1.0000 0.3301E-17 0.3301E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 16 albite -0.38 -0.38 0.00 0.000 0.11184E-10 22 andradite 39.01 39.01 0.00 0.000 0.24265E-10 23 grossular 32.73 32.73 0.00 0.000 0.12132E-10 32 apatite-OH -18.15 -18.15 0.00 0.000 0.00000E+00 46 clinochlore 39.07 39.07 0.00 0.000 0.24265E-10 47 daphnite 28.97 28.97 0.00 0.000 -0.60662E-11 48 chlorite-Mn 46.87 46.87 0.00 0.000 0.00000E+00 67 diopside 16.18 16.18 0.00 0.000 0.00000E+00 68 hedenbergite 14.21 14.21 0.00 0.000 -0.60662E-11 116 microcline -2.49 -2.49 0.00 0.000 -0.10616E-10 163 stilbite -7.52 -7.52 0.00 0.000 -0.90992E-11 164 stilpnomelane-Fe 13.02 13.02 0.00 0.000 0.21232E-10 245 tr.625ac.25prg.125 45.16 45.16 0.00 0.000 0.36397E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -16.75 -10.09 -3.363 0.17226E+05 -8.390 3 CH4,gas 4.54 1.18 -3.36 -0.840 0.57389E+04 -1.662 4 H2,gas 8.00 4.48 -3.52 -2.010 0.60050E+04 -1.818 5 H2S,gas -6.23 -14.72 -8.49 -4.246 0.14500E+05 -6.793 6 S2,gas -7.34 -38.41 -31.07 -4.781 0.53059E+05 -29.376 7 CO,gas 3.21 -12.27 -15.48 -4.763 0.26433E+05 -13.782 8 SO3,gas 17.12 -32.65 -49.78 -12.444 0.84989E+05 -48.076 9 SO2,gas 0.83 -28.17 -29.00 -7.734 0.49522E+05 -27.304 10 HCl,gas 5.19 -13.99 -19.18 -9.590 0.32750E+05 -17.481 11 acmite 7.71 6.53 -1.18 -0.123 0.20176E+04 15 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 19 spessartine 24.46 19.73 -4.73 -0.237 0.80790E+04 20 analcite 3.32 2.77 -0.55 -0.061 0.93622E+03 26 annite 20.12 17.72 -2.40 -0.134 0.41064E+04 27 phlogopite 27.06 25.40 -1.67 -0.093 0.28488E+04 29 anorthite 12.71 8.27 -4.45 -0.342 0.75902E+04 35 aragonite 0.97 -3.65 -4.61 -1.538 0.78775E+04 36 brucite 12.57 9.29 -3.27 -0.655 0.55909E+04 37 calcite 0.81 -3.65 -4.46 -1.486 0.76132E+04 38 carnegieite-low 9.02 5.93 -3.09 -0.442 0.52800E+04 39 carnegieite-high 10.09 5.93 -4.16 -0.595 0.71070E+04 40 carpholite-Mg 8.58 4.46 -4.12 -0.275 0.70428E+04 41 carpholite-Fe 6.71 1.90 -4.81 -0.321 0.82205E+04 42 celadonite 5.34 3.65 -1.69 -0.099 0.28879E+04 43 celadonite-Fe 3.88 1.09 -2.79 -0.164 0.47561E+04 44 chrysotile 23.89 21.57 -2.32 -0.194 0.39692E+04 49 chlorite-Al-free 47.17 43.14 -4.04 -0.168 0.68935E+04 51 chloritoid-Fe 9.17 5.06 -4.12 -0.275 0.70314E+04 52 chloritoid-Mn 11.40 7.56 -3.84 -0.256 0.65575E+04 54 coesite -2.38 -3.16 -0.78 -0.260 0.13342E+04 61 cristobalite -2.56 -3.16 -0.60 -0.199 0.10195E+04 63 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71234E+04 65 diaspore 2.87 0.74 -2.13 -0.356 0.36449E+04 66 diamond -3.10 -7.78 -4.68 -1.337 0.79922E+04 71 enstatite 17.26 12.27 -4.99 -0.499 0.85225E+04 73 clinoenstatite 17.17 12.27 -4.89 -0.489 0.83541E+04 75 epidote 24.67 22.70 -1.97 -0.095 0.33584E+04 76 clinozoisite 22.81 18.95 -3.86 -0.175 0.65866E+04 77 epidote-Fe 29.84 26.46 -3.38 -0.176 0.57768E+04 78 fayalite 14.05 10.31 -3.73 -0.533 0.63743E+04 79 ferrosilite 11.15 7.16 -3.99 -0.399 0.68202E+04 83 gibbsite 4.08 0.74 -3.34 -0.477 0.57034E+04 84 glaucophane 22.97 20.80 -2.17 -0.059 0.37133E+04 85 glaucophane-Fe 17.28 13.12 -4.15 -0.112 0.70919E+04 86 graphite -3.55 -7.78 -4.24 -1.211 0.72345E+04 87 greenalite 16.14 13.89 -2.25 -0.187 0.38408E+04 90 hematite 12.57 8.99 -3.58 -0.434 0.61112E+04 91 heulandite -5.83 -7.52 -1.69 -0.077 0.28938E+04 95 jadeite 4.22 2.77 -1.44 -0.144 0.24617E+04 97 kalsilite 7.58 3.83 -3.76 -0.537 0.64125E+04 98 kaolinite -1.33 -4.84 -3.50 -0.319 0.59830E+04 101 laumontite 2.88 1.95 -0.93 -0.062 0.15934E+04 102 lawsonite 9.62 8.27 -1.35 -0.090 0.23068E+04 103 leucite 4.12 0.67 -3.45 -0.345 0.58873E+04 105 lizardite 23.24 21.57 -1.68 -0.140 0.28618E+04 107 magnetite 20.09 15.72 -4.37 -0.356 0.74536E+04 108 minnesotaite 10.39 7.58 -2.81 -0.165 0.48029E+04 112 manganosite 14.06 9.24 -4.82 -1.205 0.82268E+04 120 muscovite 2.58 -1.01 -3.59 -0.211 0.61313E+04 121 paragonite 4.24 1.09 -3.15 -0.185 0.53704E+04 122 nepheline 8.34 5.93 -2.41 -0.344 0.41124E+04 128 periclase-Fe 11.63 6.73 -4.89 -1.223 0.83523E+04 134 phlogopite-Na 29.65 27.50 -2.15 -0.119 0.36676E+04 136 prehnite 19.37 18.21 -1.16 -0.068 0.19848E+04 137 prehnite-Fe 22.50 21.96 -0.53 -0.032 0.91154E+03 138 pumpellyite-Fe 46.27 43.89 -2.38 -0.053 0.40577E+04 139 pumpellyite-Mg 48.99 46.45 -2.54 -0.057 0.43415E+04 143 pyrrhotite -4.26 -7.99 -3.73 -1.242 0.63635E+04 144 pyrrhotiteFe0.875 -6.02 -9.38 -3.37 -1.239 0.57508E+04 145 pyroxmangite 7.40 6.08 -1.32 -0.263 0.22472E+04 146 pyrophyllite -6.18 -11.15 -4.98 -0.311 0.84961E+04 147 quartz -2.99 -3.16 -0.17 -0.056 0.28683E+03 152 rhodonite 7.45 6.08 -1.36 -0.273 0.23275E+04 153 sanidine -1.28 -2.49 -1.21 -0.093 0.20677E+04 165 stilpnomelane-Mg 27.44 25.81 -1.63 -0.049 0.27802E+04 171 talc 16.49 15.25 -1.24 -0.073 0.21140E+04 174 tephroite 18.09 15.32 -2.76 -0.395 0.47181E+04 178 tridymite -2.63 -3.16 -0.53 -0.177 0.90681E+03 179 tremolite 47.87 47.42 -0.45 -0.012 0.77496E+03 180 ferroactinolite 38.45 34.62 -3.83 -0.104 0.65450E+04 181 troilite-low -4.41 -7.99 -3.58 -1.192 0.61064E+04 183 vesuvianite 223.47 218.82 -4.65 -0.036 0.79427E+04 187 wairakite 3.95 1.95 -2.00 -0.118 0.34154E+04 188 walstromite 11.51 9.94 -1.56 -0.313 0.26719E+04 189 wollastonite 10.46 9.94 -0.52 -0.103 0.88229E+03 190 pseudo-wollastonite 11.00 9.94 -1.06 -0.211 0.18021E+04 191 zoisite 22.85 18.95 -3.90 -0.177 0.66607E+04 192 akaganeite 7.75 4.49 -3.26 -0.705 0.55681E+04 199 chalcedony -2.80 -3.16 -0.35 -0.118 0.60613E+03 201 montmorillonite-Ca -2.29 -6.17 -3.88 -0.240 0.66180E+04 202 montmorillonite-K -2.24 -6.27 -4.03 -0.247 0.68816E+04 203 montmorillonite-Mg -2.48 -6.79 -4.31 -0.267 0.73677E+04 204 montmorillonite-Na -2.04 -5.57 -3.54 -0.216 0.60365E+04 205 nontronite-Ca 3.21 -0.19 -3.41 -0.221 0.58216E+04 206 nontronite-H 2.53 -2.36 -4.89 -0.328 0.83486E+04 207 nontronite-K 3.34 -0.30 -3.64 -0.233 0.62084E+04 208 nontronite-Mg 3.07 -0.82 -3.90 -0.253 0.66554E+04 209 nontronite-Na 3.52 0.40 -3.12 -0.200 0.53293E+04 224 tobermorite 9.82 7.76 -2.07 -0.564 0.35287E+04 230 alabandite -0.98 -5.48 -4.50 -1.501 0.76910E+04 233 boehmite 4.41 0.74 -3.67 -0.611 0.62618E+04 235 ferrous-oxide 9.81 6.73 -3.08 -0.769 0.52532E+04 240 silica-amorphous -2.09 -3.16 -1.07 -0.355 0.18203E+04 242 an20ab80 2.02 1.35 -0.67 -0.052 0.11472E+04 243 an25ab75 2.65 1.78 -0.87 -0.067 0.14809E+04 244 an30ab70 3.28 2.21 -1.07 -0.082 0.18243E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 40.0000000 g Current total amount of reactant added: 1639.9990000 g New total amount of reactant added: 1679.9990000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.3297E-10 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 11 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 1679.9990000 Water: Moles liquid = 0.4606E+02 kg liquid = 0.8298E+00 Moles total = 0.3445E+02 kg total = 0.6206E+00 Activity = 1.0000 Stoichiometric ionic strength = .1134103E-01 Osmotic coef. = 0.9692 True ionic strength = .2002626E-01 Chg. balance for total moles = 0.3297E-10 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.88328E-10 -10.0539 0.74216E-10 -10.1295 0.84023E+00 -0.0756 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.16552E-03 -3.7811 0.13824E-03 -3.8594 0.83518E+00 -0.0782 4 SO4-- 0.78000E-12 -12.1079 0.40502E-12 -12.3925 0.51925E+00 -0.2846 5 HCO3- 0.28864E-06 -6.5397 0.24141E-06 -6.6172 0.83640E+00 -0.0776 6 HS- 0.30732E-04 -4.5124 0.25670E-04 -4.5906 0.83530E+00 -0.0782 7 Al+++ 0.97038E-29 -29.0131 0.22414E-29 -29.6495 0.23098E+00 -0.6364 8 H4SiO4 0.69595E-03 -3.1574 0.69595E-03 -3.1574 0.10000E+01 0.0000 9 Ca++ 0.13510E-06 -6.8693 0.69637E-07 -7.1572 0.51544E+00 -0.2878 10 Mg++ 0.21136E-10 -10.6750 0.10844E-10 -10.9648 0.51308E+00 -0.2898 11 Fe++ 0.58252E-13 -13.2347 0.29921E-13 -13.5240 0.51364E+00 -0.2893 12 K+ 0.15657E-03 -3.8053 0.13099E-03 -3.8828 0.83660E+00 -0.0775 13 Na+ 0.19869E-01 -1.7018 0.16591E-01 -1.7801 0.83502E+00 -0.0783 14 Mn++ 0.18622E-10 -10.7300 0.95729E-11 -11.0190 0.51407E+00 -0.2890 15 HPO4-- 0.45289E-07 -7.3440 0.23520E-07 -7.6286 0.51933E+00 -0.2846 16 HSiO3- 0.10484E-01 -1.9795 0.87561E-02 -2.0577 0.83518E+00 -0.0782 17 Ca(HSiO3)+ 0.16595E-07 -7.7800 0.13886E-07 -7.8574 0.83678E+00 -0.0774 18 Mg(HSiO3)+ 0.32162E-11 -11.4927 0.26912E-11 -11.5701 0.83678E+00 -0.0774 19 NaHSiO3,aq 0.23495E-02 -2.6290 0.23495E-02 -2.6290 0.10000E+01 0.0000 20 AlO+ 0.66159E-16 -16.1794 0.55360E-16 -16.2568 0.83678E+00 -0.0774 22 HAlO2,aq 0.14855E-09 -9.8281 0.14855E-09 -9.8281 0.10000E+01 0.0000 23 AlO2- 0.53148E-05 -5.2745 0.44308E-05 -5.3535 0.83367E+00 -0.0790 24 CH4,aq 0.14914E-04 -4.8264 0.14863E-04 -4.8279 0.99654E+00 -0.0015 25 C2H6,aq 0.32715E-14 -14.4853 0.32602E-14 -14.4868 0.99654E+00 -0.0015 29 CO,aq 0.11140E-16 -16.9531 0.11140E-16 -16.9531 0.10000E+01 0.0000 30 CO2,aq 0.38417E-10 -10.4155 0.38284E-10 -10.4170 0.99654E+00 -0.0015 31 CO3-2 0.54835E-06 -6.2609 0.28413E-06 -6.5465 0.51815E+00 -0.2855 32 CaCO3,aq 0.24809E-09 -9.6054 0.24809E-09 -9.6054 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.51283E-12 -12.2900 0.42912E-12 -12.3674 0.83678E+00 -0.0774 34 CaCl+ 0.18618E-10 -10.7301 0.15579E-10 -10.8075 0.83678E+00 -0.0774 35 CaCl2,aq 0.51166E-15 -15.2910 0.51166E-15 -15.2910 0.10000E+01 0.0000 36 CaOH+ 0.79916E-07 -7.0974 0.66872E-07 -7.1748 0.83678E+00 -0.0774 37 CaSO4,aq 0.89561E-17 -17.0479 0.89561E-17 -17.0479 0.10000E+01 0.0000 38 HCl,aq 0.18800E-14 -14.7258 0.18800E-14 -14.7258 0.10000E+01 0.0000 43 FeCl+ 0.78241E-17 -17.1066 0.65471E-17 -17.1840 0.83678E+00 -0.0774 46 FeO,aq 0.21113E-09 -9.6755 0.21113E-09 -9.6755 0.10000E+01 0.0000 47 FeOH+ 0.15683E-10 -10.8046 0.13123E-10 -10.8820 0.83678E+00 -0.0774 48 HFeO2- 0.35640E-07 -7.4481 0.29766E-07 -7.5263 0.83518E+00 -0.0782 49 FeO+ 0.10991E-16 -16.9590 0.91970E-17 -17.0364 0.83678E+00 -0.0774 51 FeO2- 0.40910E-09 -9.3882 0.34167E-09 -9.4664 0.83518E+00 -0.0782 52 HFeO2,aq 0.32250E-11 -11.4915 0.32250E-11 -11.4915 0.10000E+01 0.0000 53 H2,aq 0.11624E-04 -4.9346 0.11584E-04 -4.9362 0.99654E+00 -0.0015 54 KCl,aq 0.32820E-09 -9.4839 0.32820E-09 -9.4839 0.10000E+01 0.0000 56 KOH,aq 0.75375E-06 -6.1228 0.75375E-06 -6.1228 0.10000E+01 0.0000 57 KSO4- 0.98574E-15 -15.0062 0.82326E-15 -15.0845 0.83518E+00 -0.0782 58 MgCO3,aq 0.96840E-14 -14.0139 0.96840E-14 -14.0139 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.81604E-16 -16.0883 0.68284E-16 -16.1657 0.83678E+00 -0.0774 60 MgCl+ 0.26278E-14 -14.5804 0.21989E-14 -14.6578 0.83678E+00 -0.0774 61 MgOH+ 0.68866E-10 -10.1620 0.57625E-10 -10.2394 0.83678E+00 -0.0774 63 MnO,aq 0.17999E-08 -8.7448 0.17999E-08 -8.7448 0.10000E+01 0.0000 64 MnOH+ 0.46612E-09 -9.3315 0.39004E-09 -9.4089 0.83678E+00 -0.0774 65 MnO2-2 0.20930E-10 -10.6792 0.10845E-10 -10.9648 0.51815E+00 -0.2855 66 HMnO2- 0.21113E-09 -9.6754 0.17633E-09 -9.7537 0.83518E+00 -0.0782 69 MnCl+ 0.97388E-14 -14.0115 0.81492E-14 -14.0889 0.83678E+00 -0.0774 71 NaCl,aq 0.76008E-06 -6.1191 0.76008E-06 -6.1191 0.10000E+01 0.0000 72 NaOH,aq 0.96047E-04 -4.0175 0.96047E-04 -4.0175 0.10000E+01 0.0000 74 OH- 0.93383E-02 -2.0297 0.77851E-02 -2.1087 0.83367E+00 -0.0790 79 HPO3-2 0.16386E-14 -14.7855 0.84904E-15 -15.0711 0.51815E+00 -0.2855 81 H2PO3- 0.15129E-18 -18.8202 0.12636E-18 -18.8984 0.83518E+00 -0.0782 82 H3PO4,aq 0.90604E-18 -18.0429 0.90604E-18 -18.0429 0.10000E+01 0.0000 83 H2PO4- 0.38519E-10 -10.4143 0.32200E-10 -10.4921 0.83597E+00 -0.0778 84 PO4-3 0.10658E-08 -8.9723 0.25857E-09 -9.5874 0.24260E+00 -0.6151 88 HP2O7-3 0.94607E-18 -18.0241 0.21874E-18 -18.6601 0.23121E+00 -0.6360 89 P2O7-4 0.91353E-17 -17.0393 0.70411E-18 -18.1524 0.77076E-01 -1.1131 90 H2S,aq 0.59084E-08 -8.2285 0.58880E-08 -8.2300 0.99654E+00 -0.0015 91 S2-2 0.24327E-14 -14.6139 0.12605E-14 -14.8995 0.51815E+00 -0.2855 97 SO3-2 0.11599E-17 -17.9356 0.60967E-18 -18.2149 0.52565E+00 -0.2793 99 HSO4- 0.34585E-19 -19.4611 0.28968E-19 -19.5381 0.83759E+00 -0.0770 Charge balance for all species = 0.3975E-10 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.8832765E-10 -.2229370E-01 -.2243166E+02 0.0000 2 H2O 0.1000000E+01 0.5550489E+02 0.9981991E+06 0.0000 3 Cl- 0.1655235E-03 0.1662839E-03 0.5885017E+01 6.2701 4 SO4-- 0.7800035E-12 -.1782038E-04 -.1708878E+01 7.8665 5 HCO3- 0.2886353E-06 0.1575172E-04 0.9594553E+00 3.5123 6 HS- 0.3073161E-04 0.4855789E-04 0.1603115E+01 5.5389 7 Al+++ 0.9703778E-29 0.5314931E-05 0.1431555E+00 0.7390 8 H4SiO4 0.6959502E-03 0.1352962E-01 0.1298144E+04 -3.1574 9 Ca++ 0.1351010E-06 0.2318796E-06 0.9277116E-02 13.1018 10 Mg++ 0.2113570E-10 0.9322977E-10 0.2262662E-05 9.2942 11 Fe++ 0.5825198E-13 0.3627905E-07 0.2022554E-02 6.7350 12 K+ 0.1565750E-03 0.1573291E-03 0.6141188E+01 6.2467 13 Na+ 0.1986858E-01 0.2231493E-01 0.5121242E+03 8.3494 14 Mn++ 0.1862167E-10 0.2516698E-08 0.1380220E-03 9.2401 15 HPO4-- 0.4528906E-07 0.4639341E-07 0.4445053E-02 12.6304 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.2781828E+02 -.1849821E-01 -.2779978E+02 0.0000000E+00 2 H2O 0.3444877E+02 0.4605521E+02 -.1160644E+02 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.4658400E-01 -.1478647E-04 0.4659879E-01 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.4655850E-01 0.4029094E-04 -.4659879E-01 0.0000000E+00 7 Al+++ 0.5478043E+01 0.4410066E-05 0.5478038E+01 0.0000000E+00 8 H4SiO4 0.1749346E+02 0.1122621E-01 0.1748224E+02 0.0000000E+00 9 Ca++ 0.1932253E+01 0.1924022E-06 0.1932253E+01 0.0000000E+00 10 Mg++ 0.1333333E+01 0.7735745E-10 0.1333333E+01 0.0000000E+00 11 Fe++ 0.1197854E+01 0.3010256E-07 0.1197854E+01 0.0000000E+00 12 K+ 0.3566877E+00 0.1305439E-03 0.3565571E+00 0.0000000E+00 13 Na+ 0.2108968E+01 0.1851583E-01 0.2090452E+01 0.0000000E+00 14 Mn++ 0.2912882E-01 0.2088232E-08 0.2912882E-01 0.0000000E+00 15 HPO4-- 0.9941523E-02 0.3849495E-07 0.9941484E-02 0.0000000E+00 Chg. balance for solid moles: 0.4059E-14 Mass of aqueous solution: 0.831195E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 1679.9990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 2.089 0.320 547.7 2.739 29.84 210.2 andradite 0.1864 -0.730 94.72 1.976 5.161 24.61 grossular 0.4514E-01 -1.345 20.33 1.308 1.108 5.658 apatite-OH 0.3314E-02 -2.480 1.665 0.221 0.9070E-01 0.5289 clinochlore 0.2395 -0.621 133.1 2.124 7.254 50.64 daphnite 0.6934E-01 -1.159 49.47 1.694 2.696 14.99 chlorite-Mn 0.5826E-02 -2.235 4.130 0.616 0.2251 1.316 diopside 0.8212E-01 -1.086 17.78 1.250 0.9690 5.435 hedenbergite 0.2130E-01 -1.672 5.283 0.723 0.2879 1.447 microcline 0.3127 -0.505 87.04 1.940 4.743 34.00 stilbite 1.088 0.037 766.8 2.885 41.78 357.6 stilpnomelane-Fe 0.8772E-01 -1.057 94.56 1.976 5.152 32.66 tr.625ac.25prg.125 0.1480E-01 -1.830 12.65 1.102 0.6894 4.072 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8050E+00 0.8050E+00 1.0000 -0.094 grossular 0.1950E+00 0.1950E+00 1.0000 -0.710 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.7611E+00 0.7611E+00 1.0000 -0.119 daphnite 0.2203E+00 0.2203E+00 1.0000 -0.657 chlorite-Mn 0.1851E-01 0.1851E-01 1.0000 -1.733 diopside 0.7941E+00 0.7941E+00 1.0000 -0.100 hedenbergite 0.2059E+00 0.2059E+00 1.0000 -0.686 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 tr.625ac.25prg.125 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 1835.215803 g Volume = 743.236127 cm3 Porosity: -10.4363% V(tot) - V(min): -.70237E+02 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 1679.9990000 g log = 3.2253 Original solution: 1000.0103000 g Original solution / Rock added: 0.60 (Water/Rock Ratio), log = -0.2253 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0576 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9652E+00 0.9854 0.1006E+01 0.1021E+01 CO2,gas 0.3846E-08 1.0069 0.4096E-08 0.4068E-08 CH4,gas 0.2043E-01 1.0124 0.2188E-01 0.2161E-01 H2,gas 0.1437E-01 1.0006 0.1521E-01 0.1520E-01 H2S,gas 0.1537E-06 0.9959 0.1619E-06 0.1625E-06 S2,gas 0.4020E-29 1.0000 0.4252E-29 0.4252E-29 CO,gas 0.1570E-13 1.0000 0.1660E-13 0.1660E-13 SO3,gas 0.7975E-48 1.0000 0.8435E-48 0.8435E-48 SO2,gas 0.4719E-27 1.0000 0.4991E-27 0.4991E-27 HCl,gas 0.3137E-17 1.0000 0.3317E-17 0.3317E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 16 albite -0.38 -0.38 0.00 0.000 -0.94784E-12 22 andradite 39.01 39.01 0.00 0.000 0.00000E+00 23 grossular 32.73 32.73 0.00 0.000 0.00000E+00 32 apatite-OH -18.15 -18.15 0.00 0.000 0.00000E+00 46 clinochlore 39.07 39.07 0.00 0.000 0.24265E-10 47 daphnite 28.97 28.97 0.00 0.000 0.72794E-10 48 chlorite-Mn 46.87 46.87 0.00 0.000 0.12132E-10 67 diopside 16.18 16.18 0.00 0.000 0.00000E+00 68 hedenbergite 14.21 14.21 0.00 0.000 0.60662E-11 116 microcline -2.49 -2.49 0.00 0.000 -0.10616E-10 163 stilbite -7.52 -7.52 0.00 0.000 -0.90992E-11 164 stilpnomelane-Fe 13.02 13.02 0.00 0.000 -0.27298E-10 245 tr.625ac.25prg.125 45.16 45.16 0.00 0.000 0.12132E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -16.75 -10.09 -3.362 0.17223E+05 -8.388 3 CH4,gas 4.54 1.18 -3.36 -0.840 0.57354E+04 -1.660 4 H2,gas 8.00 4.48 -3.52 -2.010 0.60050E+04 -1.818 5 H2S,gas -6.23 -14.72 -8.49 -4.245 0.14496E+05 -6.791 6 S2,gas -7.34 -38.41 -31.07 -4.780 0.53052E+05 -29.371 7 CO,gas 3.21 -12.26 -15.48 -4.763 0.26430E+05 -13.780 8 SO3,gas 17.12 -32.65 -49.77 -12.443 0.84986E+05 -48.074 9 SO2,gas 0.83 -28.17 -29.00 -7.734 0.49518E+05 -27.302 10 HCl,gas 5.19 -13.99 -19.18 -9.589 0.32746E+05 -17.479 11 acmite 7.71 6.53 -1.18 -0.123 0.20176E+04 15 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 19 spessartine 24.46 19.73 -4.73 -0.237 0.80787E+04 20 analcite 3.32 2.77 -0.55 -0.061 0.93622E+03 26 annite 20.12 17.72 -2.40 -0.134 0.41064E+04 27 phlogopite 27.06 25.40 -1.67 -0.093 0.28488E+04 29 anorthite 12.71 8.27 -4.45 -0.342 0.75902E+04 35 aragonite 0.97 -3.64 -4.61 -1.537 0.78739E+04 36 brucite 12.57 9.29 -3.27 -0.655 0.55909E+04 37 calcite 0.81 -3.64 -4.46 -1.486 0.76096E+04 38 carnegieite-low 9.02 5.93 -3.09 -0.442 0.52801E+04 39 carnegieite-high 10.09 5.93 -4.16 -0.595 0.71070E+04 40 carpholite-Mg 8.58 4.46 -4.12 -0.275 0.70428E+04 41 carpholite-Fe 6.71 1.90 -4.81 -0.321 0.82205E+04 42 celadonite 5.34 3.65 -1.69 -0.099 0.28879E+04 43 celadonite-Fe 3.88 1.09 -2.79 -0.164 0.47561E+04 44 chrysotile 23.89 21.57 -2.32 -0.194 0.39692E+04 49 chlorite-Al-free 47.17 43.14 -4.04 -0.168 0.68935E+04 51 chloritoid-Fe 9.17 5.06 -4.12 -0.275 0.70314E+04 52 chloritoid-Mn 11.40 7.56 -3.84 -0.256 0.65574E+04 54 coesite -2.38 -3.16 -0.78 -0.260 0.13341E+04 61 cristobalite -2.56 -3.16 -0.60 -0.199 0.10195E+04 63 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71234E+04 65 diaspore 2.87 0.74 -2.13 -0.356 0.36449E+04 66 diamond -3.10 -7.78 -4.68 -1.337 0.79886E+04 71 enstatite 17.26 12.27 -4.99 -0.499 0.85225E+04 73 clinoenstatite 17.17 12.27 -4.89 -0.489 0.83541E+04 75 epidote 24.67 22.70 -1.97 -0.095 0.33584E+04 76 clinozoisite 22.81 18.95 -3.86 -0.175 0.65866E+04 77 epidote-Fe 29.84 26.46 -3.38 -0.176 0.57768E+04 78 fayalite 14.05 10.31 -3.73 -0.533 0.63743E+04 79 ferrosilite 11.15 7.16 -3.99 -0.399 0.68202E+04 83 gibbsite 4.08 0.74 -3.34 -0.477 0.57034E+04 84 glaucophane 22.97 20.80 -2.17 -0.059 0.37133E+04 85 glaucophane-Fe 17.28 13.12 -4.15 -0.112 0.70919E+04 86 graphite -3.55 -7.78 -4.23 -1.210 0.72309E+04 87 greenalite 16.14 13.89 -2.25 -0.187 0.38408E+04 90 hematite 12.57 8.99 -3.58 -0.434 0.61112E+04 91 heulandite -5.83 -7.52 -1.69 -0.077 0.28938E+04 95 jadeite 4.22 2.77 -1.44 -0.144 0.24617E+04 97 kalsilite 7.58 3.83 -3.76 -0.537 0.64125E+04 98 kaolinite -1.33 -4.84 -3.50 -0.319 0.59830E+04 101 laumontite 2.88 1.95 -0.93 -0.062 0.15934E+04 102 lawsonite 9.62 8.27 -1.35 -0.090 0.23068E+04 103 leucite 4.12 0.67 -3.45 -0.345 0.58873E+04 105 lizardite 23.24 21.57 -1.68 -0.140 0.28618E+04 107 magnetite 20.09 15.72 -4.37 -0.356 0.74536E+04 108 minnesotaite 10.39 7.58 -2.81 -0.165 0.48028E+04 112 manganosite 14.06 9.24 -4.82 -1.205 0.82267E+04 120 muscovite 2.58 -1.01 -3.59 -0.211 0.61313E+04 121 paragonite 4.24 1.09 -3.15 -0.185 0.53704E+04 122 nepheline 8.34 5.93 -2.41 -0.344 0.41124E+04 128 periclase-Fe 11.63 6.73 -4.89 -1.223 0.83523E+04 134 phlogopite-Na 29.65 27.50 -2.15 -0.119 0.36676E+04 136 prehnite 19.37 18.21 -1.16 -0.068 0.19848E+04 137 prehnite-Fe 22.50 21.96 -0.53 -0.032 0.91154E+03 138 pumpellyite-Fe 46.27 43.89 -2.38 -0.053 0.40577E+04 139 pumpellyite-Mg 48.99 46.45 -2.54 -0.057 0.43415E+04 143 pyrrhotite -4.26 -7.99 -3.72 -1.242 0.63599E+04 144 pyrrhotiteFe0.875 -6.02 -9.38 -3.37 -1.238 0.57472E+04 145 pyroxmangite 7.40 6.08 -1.32 -0.263 0.22471E+04 146 pyrophyllite -6.18 -11.15 -4.98 -0.311 0.84961E+04 147 quartz -2.99 -3.16 -0.17 -0.056 0.28683E+03 152 rhodonite 7.45 6.08 -1.36 -0.273 0.23274E+04 153 sanidine -1.28 -2.49 -1.21 -0.093 0.20677E+04 165 stilpnomelane-Mg 27.44 25.81 -1.63 -0.049 0.27802E+04 171 talc 16.49 15.25 -1.24 -0.073 0.21140E+04 174 tephroite 18.09 15.32 -2.76 -0.395 0.47179E+04 178 tridymite -2.63 -3.16 -0.53 -0.177 0.90681E+03 179 tremolite 47.87 47.42 -0.45 -0.012 0.77495E+03 180 ferroactinolite 38.45 34.62 -3.83 -0.104 0.65450E+04 181 troilite-low -4.41 -7.99 -3.57 -1.191 0.61028E+04 183 vesuvianite 223.47 218.82 -4.65 -0.036 0.79427E+04 187 wairakite 3.95 1.95 -2.00 -0.118 0.34154E+04 188 walstromite 11.51 9.94 -1.56 -0.313 0.26719E+04 189 wollastonite 10.46 9.94 -0.52 -0.103 0.88229E+03 190 pseudo-wollastonite 11.00 9.94 -1.06 -0.211 0.18021E+04 191 zoisite 22.85 18.95 -3.90 -0.177 0.66607E+04 192 akaganeite 7.75 4.49 -3.26 -0.705 0.55681E+04 199 chalcedony -2.80 -3.16 -0.35 -0.118 0.60613E+03 201 montmorillonite-Ca -2.29 -6.17 -3.88 -0.240 0.66180E+04 202 montmorillonite-K -2.24 -6.27 -4.03 -0.247 0.68816E+04 203 montmorillonite-Mg -2.48 -6.79 -4.31 -0.267 0.73677E+04 204 montmorillonite-Na -2.04 -5.57 -3.54 -0.216 0.60365E+04 205 nontronite-Ca 3.21 -0.19 -3.41 -0.221 0.58216E+04 206 nontronite-H 2.53 -2.36 -4.89 -0.328 0.83486E+04 207 nontronite-K 3.34 -0.30 -3.64 -0.233 0.62084E+04 208 nontronite-Mg 3.07 -0.82 -3.90 -0.253 0.66554E+04 209 nontronite-Na 3.52 0.40 -3.12 -0.200 0.53293E+04 224 tobermorite 9.82 7.76 -2.07 -0.564 0.35287E+04 230 alabandite -0.98 -5.48 -4.50 -1.501 0.76873E+04 233 boehmite 4.41 0.74 -3.67 -0.611 0.62618E+04 235 ferrous-oxide 9.81 6.73 -3.08 -0.769 0.52532E+04 240 silica-amorphous -2.09 -3.16 -1.07 -0.355 0.18203E+04 242 an20ab80 2.02 1.35 -0.67 -0.052 0.11472E+04 243 an25ab75 2.65 1.78 -0.87 -0.067 0.14810E+04 244 an30ab70 3.28 2.21 -1.07 -0.082 0.18243E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 40.0000000 g Current total amount of reactant added: 1679.9990000 g New total amount of reactant added: 1719.9990000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.3297E-10 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 11 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 1719.9990000 Water: Moles liquid = 0.4584E+02 kg liquid = 0.8257E+00 Moles total = 0.3395E+02 kg total = 0.6116E+00 Activity = 1.0000 Stoichiometric ionic strength = .1134170E-01 Osmotic coef. = 0.9692 True ionic strength = .2002679E-01 Chg. balance for total moles = 0.3297E-10 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.88330E-10 -10.0539 0.74217E-10 -10.1295 0.84023E+00 -0.0756 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.16633E-03 -3.7790 0.13891E-03 -3.8573 0.83518E+00 -0.0782 4 SO4-- 0.78379E-12 -12.1058 0.40698E-12 -12.3904 0.51925E+00 -0.2846 5 HCO3- 0.29004E-06 -6.5375 0.24259E-06 -6.6151 0.83640E+00 -0.0776 6 HS- 0.30881E-04 -4.5103 0.25795E-04 -4.5885 0.83530E+00 -0.0782 7 Al+++ 0.97046E-29 -29.0130 0.22415E-29 -29.6495 0.23097E+00 -0.6364 8 H4SiO4 0.69595E-03 -3.1574 0.69595E-03 -3.1574 0.10000E+01 0.0000 9 Ca++ 0.13511E-06 -6.8693 0.69640E-07 -7.1571 0.51544E+00 -0.2878 10 Mg++ 0.21137E-10 -10.6750 0.10845E-10 -10.9648 0.51308E+00 -0.2898 11 Fe++ 0.58255E-13 -13.2347 0.29922E-13 -13.5240 0.51364E+00 -0.2893 12 K+ 0.15658E-03 -3.8053 0.13099E-03 -3.8828 0.83660E+00 -0.0775 13 Na+ 0.19869E-01 -1.7018 0.16591E-01 -1.7801 0.83502E+00 -0.0783 14 Mn++ 0.18625E-10 -10.7299 0.95745E-11 -11.0189 0.51407E+00 -0.2890 15 HPO4-- 0.45287E-07 -7.3440 0.23519E-07 -7.6286 0.51932E+00 -0.2846 16 HSiO3- 0.10484E-01 -1.9795 0.87559E-02 -2.0577 0.83518E+00 -0.0782 17 Ca(HSiO3)+ 0.16595E-07 -7.7800 0.13887E-07 -7.8574 0.83678E+00 -0.0774 18 Mg(HSiO3)+ 0.32163E-11 -11.4926 0.26913E-11 -11.5700 0.83678E+00 -0.0774 19 NaHSiO3,aq 0.23495E-02 -2.6290 0.23495E-02 -2.6290 0.10000E+01 0.0000 20 AlO+ 0.66160E-16 -16.1794 0.55361E-16 -16.2568 0.83678E+00 -0.0774 22 HAlO2,aq 0.14855E-09 -9.8281 0.14855E-09 -9.8281 0.10000E+01 0.0000 23 AlO2- 0.53146E-05 -5.2745 0.44306E-05 -5.3535 0.83367E+00 -0.0790 24 CH4,aq 0.14987E-04 -4.8243 0.14935E-04 -4.8258 0.99654E+00 -0.0015 25 C2H6,aq 0.33034E-14 -14.4810 0.32920E-14 -14.4825 0.99654E+00 -0.0015 29 CO,aq 0.11195E-16 -16.9510 0.11195E-16 -16.9510 0.10000E+01 0.0000 30 CO2,aq 0.38604E-10 -10.4134 0.38471E-10 -10.4149 0.99654E+00 -0.0015 31 CO3-2 0.55100E-06 -6.2588 0.28550E-06 -6.5444 0.51815E+00 -0.2855 32 CaCO3,aq 0.24930E-09 -9.6033 0.24930E-09 -9.6033 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.51535E-12 -12.2879 0.43123E-12 -12.3653 0.83678E+00 -0.0774 34 CaCl+ 0.18709E-10 -10.7279 0.15655E-10 -10.8053 0.83678E+00 -0.0774 35 CaCl2,aq 0.51668E-15 -15.2868 0.51668E-15 -15.2868 0.10000E+01 0.0000 36 CaOH+ 0.79918E-07 -7.0974 0.66874E-07 -7.1747 0.83678E+00 -0.0774 37 CaSO4,aq 0.90000E-17 -17.0458 0.90000E-17 -17.0458 0.10000E+01 0.0000 38 HCl,aq 0.18892E-14 -14.7237 0.18892E-14 -14.7237 0.10000E+01 0.0000 43 FeCl+ 0.78626E-17 -17.1044 0.65792E-17 -17.1818 0.83678E+00 -0.0774 46 FeO,aq 0.21113E-09 -9.6755 0.21113E-09 -9.6755 0.10000E+01 0.0000 47 FeOH+ 0.15684E-10 -10.8046 0.13124E-10 -10.8819 0.83678E+00 -0.0774 48 HFeO2- 0.35639E-07 -7.4481 0.29765E-07 -7.5263 0.83518E+00 -0.0782 49 FeO+ 0.10991E-16 -16.9590 0.91972E-17 -17.0363 0.83678E+00 -0.0774 51 FeO2- 0.40909E-09 -9.3882 0.34166E-09 -9.4664 0.83518E+00 -0.0782 52 HFeO2,aq 0.32250E-11 -11.4915 0.32250E-11 -11.4915 0.10000E+01 0.0000 53 H2,aq 0.11624E-04 -4.9346 0.11584E-04 -4.9362 0.99654E+00 -0.0015 54 KCl,aq 0.32980E-09 -9.4817 0.32980E-09 -9.4817 0.10000E+01 0.0000 56 KOH,aq 0.75375E-06 -6.1228 0.75375E-06 -6.1228 0.10000E+01 0.0000 57 KSO4- 0.99054E-15 -15.0041 0.82728E-15 -15.0823 0.83518E+00 -0.0782 58 MgCO3,aq 0.97312E-14 -14.0118 0.97312E-14 -14.0118 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.82004E-16 -16.0862 0.68619E-16 -16.1636 0.83678E+00 -0.0774 60 MgCl+ 0.26407E-14 -14.5783 0.22097E-14 -14.6557 0.83678E+00 -0.0774 61 MgOH+ 0.68867E-10 -10.1620 0.57626E-10 -10.2394 0.83678E+00 -0.0774 63 MnO,aq 0.18001E-08 -8.7447 0.18001E-08 -8.7447 0.10000E+01 0.0000 64 MnOH+ 0.46619E-09 -9.3314 0.39010E-09 -9.4088 0.83678E+00 -0.0774 65 MnO2-2 0.20932E-10 -10.6792 0.10846E-10 -10.9647 0.51815E+00 -0.2855 66 HMnO2- 0.21115E-09 -9.6754 0.17635E-09 -9.7536 0.83518E+00 -0.0782 69 MnCl+ 0.97878E-14 -14.0093 0.81902E-14 -14.0867 0.83678E+00 -0.0774 71 NaCl,aq 0.76380E-06 -6.1170 0.76380E-06 -6.1170 0.10000E+01 0.0000 72 NaOH,aq 0.96047E-04 -4.0175 0.96047E-04 -4.0175 0.10000E+01 0.0000 74 OH- 0.93381E-02 -2.0297 0.77849E-02 -2.1087 0.83367E+00 -0.0790 79 HPO3-2 0.16385E-14 -14.7855 0.84899E-15 -15.0711 0.51815E+00 -0.2855 81 H2PO3- 0.15129E-18 -18.8202 0.12635E-18 -18.8984 0.83518E+00 -0.0782 82 H3PO4,aq 0.90604E-18 -18.0429 0.90604E-18 -18.0429 0.10000E+01 0.0000 83 H2PO4- 0.38518E-10 -10.4143 0.32200E-10 -10.4921 0.83597E+00 -0.0778 84 PO4-3 0.10658E-08 -8.9723 0.25855E-09 -9.5875 0.24259E+00 -0.6151 88 HP2O7-3 0.94602E-18 -18.0241 0.21872E-18 -18.6601 0.23120E+00 -0.6360 89 P2O7-4 0.91347E-17 -17.0393 0.70405E-18 -18.1524 0.77074E-01 -1.1131 90 H2S,aq 0.59373E-08 -8.2264 0.59168E-08 -8.2279 0.99654E+00 -0.0015 91 S2-2 0.24564E-14 -14.6097 0.12728E-14 -14.8952 0.51815E+00 -0.2855 97 SO3-2 0.11655E-17 -17.9335 0.61263E-18 -18.2128 0.52564E+00 -0.2793 99 HSO4- 0.34754E-19 -19.4590 0.29109E-19 -19.5360 0.83759E+00 -0.0770 Charge balance for all species = 0.3993E-10 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.8832996E-10 -.2229327E-01 -.2243122E+02 0.0000 2 H2O 0.1000000E+01 0.5550489E+02 0.9981991E+06 0.0000 3 Cl- 0.1663287E-03 0.1670929E-03 0.5913646E+01 6.2722 4 SO4-- 0.7837937E-12 -.1789294E-04 -.1715837E+01 7.8686 5 HCO3- 0.2900371E-06 0.1582835E-04 0.9641229E+00 3.5144 6 HS- 0.3088111E-04 0.4877999E-04 0.1610448E+01 5.5410 7 Al+++ 0.9704602E-29 0.5314787E-05 0.1431516E+00 0.7390 8 H4SiO4 0.6959512E-03 0.1352940E-01 0.1298123E+04 -3.1574 9 Ca++ 0.1351084E-06 0.2318907E-06 0.9277560E-02 13.1018 10 Mg++ 0.2113685E-10 0.9323263E-10 0.2262732E-05 9.2942 11 Fe++ 0.5825521E-13 0.3627821E-07 0.2022507E-02 6.7350 12 K+ 0.1565791E-03 0.1573332E-03 0.6141348E+01 6.2467 13 Na+ 0.1986911E-01 0.2231546E-01 0.5121363E+03 8.3494 14 Mn++ 0.1862500E-10 0.2517013E-08 0.1380393E-03 9.2401 15 HPO4-- 0.4528726E-07 0.4639155E-07 0.4444875E-02 12.6304 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.2848062E+02 -.1840830E-01 -.2846221E+02 0.0000000E+00 2 H2O 0.3394736E+02 0.4583225E+02 -.1188489E+02 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.4769254E-01 -.1477480E-04 0.4770731E-01 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.4766704E-01 0.4027927E-04 -.4770731E-01 0.0000000E+00 7 Al+++ 0.5608472E+01 0.4388597E-05 0.5608468E+01 0.0000000E+00 8 H4SiO4 0.1790998E+02 0.1117168E-01 0.1789880E+02 0.0000000E+00 9 Ca++ 0.1978259E+01 0.1914799E-06 0.1978258E+01 0.0000000E+00 10 Mg++ 0.1365079E+01 0.7698531E-10 0.1365079E+01 0.0000000E+00 11 Fe++ 0.1226374E+01 0.2995613E-07 0.1226374E+01 0.0000000E+00 12 K+ 0.3651803E+00 0.1299153E-03 0.3650503E+00 0.0000000E+00 13 Na+ 0.2159178E+01 0.1842663E-01 0.2140751E+01 0.0000000E+00 14 Mn++ 0.2982237E-01 0.2078382E-08 0.2982237E-01 0.0000000E+00 15 HPO4-- 0.1017823E-01 0.3830706E-07 0.1017819E-01 0.0000000E+00 Chg. balance for solid moles: -.5392E-14 Mass of aqueous solution: 0.827171E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 1719.9990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 2.139 0.330 560.9 2.749 29.85 215.3 andradite 0.1908 -0.719 96.98 1.987 5.161 25.20 grossular 0.4621E-01 -1.335 20.82 1.318 1.108 5.792 apatite-OH 0.3393E-02 -2.469 1.704 0.232 0.9070E-01 0.5415 clinochlore 0.2452 -0.611 136.3 2.134 7.253 51.84 daphnite 0.7098E-01 -1.149 50.64 1.705 2.695 15.35 chlorite-Mn 0.5964E-02 -2.224 4.229 0.626 0.2251 1.348 diopside 0.8429E-01 -1.074 18.25 1.261 0.9715 5.579 hedenbergite 0.2186E-01 -1.660 5.423 0.734 0.2886 1.485 microcline 0.3201 -0.495 89.11 1.950 4.743 34.81 stilbite 1.114 0.047 784.9 2.895 41.77 366.1 stilpnomelane-Fe 0.8981E-01 -1.047 96.81 1.986 5.153 33.44 tr.625ac.25prg.125 0.1513E-01 -1.820 12.94 1.112 0.6885 4.164 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8050E+00 0.8050E+00 1.0000 -0.094 grossular 0.1950E+00 0.1950E+00 1.0000 -0.710 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.7611E+00 0.7611E+00 1.0000 -0.119 daphnite 0.2203E+00 0.2203E+00 1.0000 -0.657 chlorite-Mn 0.1852E-01 0.1852E-01 1.0000 -1.732 diopside 0.7941E+00 0.7941E+00 1.0000 -0.100 hedenbergite 0.2059E+00 0.2059E+00 1.0000 -0.686 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 tr.625ac.25prg.125 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 1878.916068 g Volume = 760.917353 cm3 Porosity: -10.4380% V(tot) - V(min): -.71918E+02 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 1719.9990000 g log = 3.2355 Original solution: 1000.0103000 g Original solution / Rock added: 0.58 (Water/Rock Ratio), log = -0.2355 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0577 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9651E+00 0.9854 0.1006E+01 0.1021E+01 CO2,gas 0.3865E-08 1.0069 0.4116E-08 0.4088E-08 CH4,gas 0.2053E-01 1.0124 0.2198E-01 0.2171E-01 H2,gas 0.1437E-01 1.0006 0.1521E-01 0.1520E-01 H2S,gas 0.1544E-06 0.9959 0.1626E-06 0.1633E-06 S2,gas 0.4059E-29 1.0000 0.4293E-29 0.4293E-29 CO,gas 0.1577E-13 1.0000 0.1668E-13 0.1668E-13 SO3,gas 0.8014E-48 1.0000 0.8476E-48 0.8476E-48 SO2,gas 0.4741E-27 1.0000 0.5015E-27 0.5015E-27 HCl,gas 0.3152E-17 1.0000 0.3334E-17 0.3334E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 16 albite -0.38 -0.38 0.00 0.000 -0.13080E-10 22 andradite 39.01 39.01 0.00 0.000 0.12132E-10 23 grossular 32.73 32.73 0.00 0.000 -0.24265E-10 32 apatite-OH -18.15 -18.15 0.00 0.000 0.60662E-11 46 clinochlore 39.07 39.07 0.00 0.000 0.12132E-10 47 daphnite 28.97 28.97 0.00 0.000 -0.12132E-10 48 chlorite-Mn 46.87 46.87 0.00 0.000 0.24265E-10 67 diopside 16.18 16.18 0.00 0.000 0.60662E-11 68 hedenbergite 14.21 14.21 0.00 0.000 0.30331E-11 116 microcline -2.49 -2.49 0.00 0.000 -0.10616E-10 163 stilbite -7.52 -7.52 0.00 0.000 0.15165E-10 164 stilpnomelane-Fe 13.02 13.02 0.00 0.000 -0.27298E-10 245 tr.625ac.25prg.125 45.16 45.16 0.00 0.000 0.48529E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -16.74 -10.08 -3.362 0.17219E+05 -8.386 3 CH4,gas 4.54 1.19 -3.36 -0.839 0.57318E+04 -1.658 4 H2,gas 8.00 4.48 -3.52 -2.010 0.60050E+04 -1.818 5 H2S,gas -6.23 -14.72 -8.49 -4.244 0.14493E+05 -6.789 6 S2,gas -7.34 -38.40 -31.07 -4.779 0.53045E+05 -29.367 7 CO,gas 3.21 -12.26 -15.48 -4.762 0.26426E+05 -13.778 8 SO3,gas 17.12 -32.65 -49.77 -12.443 0.84982E+05 -48.072 9 SO2,gas 0.83 -28.17 -29.00 -7.733 0.49514E+05 -27.300 10 HCl,gas 5.19 -13.99 -19.18 -9.588 0.32743E+05 -17.477 11 acmite 7.71 6.53 -1.18 -0.123 0.20176E+04 15 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 19 spessartine 24.46 19.73 -4.73 -0.237 0.80785E+04 20 analcite 3.32 2.77 -0.55 -0.061 0.93622E+03 26 annite 20.12 17.72 -2.40 -0.134 0.41064E+04 27 phlogopite 27.06 25.40 -1.67 -0.093 0.28488E+04 29 anorthite 12.71 8.27 -4.45 -0.342 0.75902E+04 35 aragonite 0.97 -3.64 -4.61 -1.536 0.78703E+04 36 brucite 12.57 9.29 -3.27 -0.655 0.55909E+04 37 calcite 0.81 -3.64 -4.45 -1.485 0.76060E+04 38 carnegieite-low 9.02 5.93 -3.09 -0.442 0.52801E+04 39 carnegieite-high 10.09 5.93 -4.16 -0.595 0.71071E+04 40 carpholite-Mg 8.58 4.46 -4.12 -0.275 0.70428E+04 41 carpholite-Fe 6.71 1.90 -4.81 -0.321 0.82205E+04 42 celadonite 5.34 3.65 -1.69 -0.099 0.28879E+04 43 celadonite-Fe 3.88 1.09 -2.79 -0.164 0.47561E+04 44 chrysotile 23.89 21.57 -2.32 -0.194 0.39692E+04 49 chlorite-Al-free 47.17 43.14 -4.04 -0.168 0.68935E+04 51 chloritoid-Fe 9.17 5.06 -4.12 -0.275 0.70314E+04 52 chloritoid-Mn 11.40 7.56 -3.84 -0.256 0.65573E+04 54 coesite -2.38 -3.16 -0.78 -0.260 0.13341E+04 61 cristobalite -2.56 -3.16 -0.60 -0.199 0.10195E+04 63 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71234E+04 65 diaspore 2.87 0.74 -2.13 -0.356 0.36449E+04 66 diamond -3.10 -7.78 -4.68 -1.336 0.79850E+04 71 enstatite 17.26 12.27 -4.99 -0.499 0.85225E+04 73 clinoenstatite 17.17 12.27 -4.89 -0.489 0.83541E+04 75 epidote 24.67 22.70 -1.97 -0.095 0.33584E+04 76 clinozoisite 22.81 18.95 -3.86 -0.175 0.65866E+04 77 epidote-Fe 29.84 26.46 -3.38 -0.176 0.57768E+04 78 fayalite 14.05 10.31 -3.73 -0.533 0.63743E+04 79 ferrosilite 11.15 7.16 -3.99 -0.399 0.68202E+04 83 gibbsite 4.08 0.74 -3.34 -0.477 0.57034E+04 84 glaucophane 22.97 20.80 -2.17 -0.059 0.37133E+04 85 glaucophane-Fe 17.28 13.12 -4.15 -0.112 0.70919E+04 86 graphite -3.55 -7.78 -4.23 -1.209 0.72273E+04 87 greenalite 16.14 13.89 -2.25 -0.187 0.38408E+04 90 hematite 12.57 8.99 -3.58 -0.434 0.61112E+04 91 heulandite -5.83 -7.52 -1.69 -0.077 0.28938E+04 95 jadeite 4.22 2.77 -1.44 -0.144 0.24617E+04 97 kalsilite 7.58 3.83 -3.76 -0.537 0.64125E+04 98 kaolinite -1.33 -4.84 -3.50 -0.319 0.59830E+04 101 laumontite 2.88 1.95 -0.93 -0.062 0.15934E+04 102 lawsonite 9.62 8.27 -1.35 -0.090 0.23068E+04 103 leucite 4.12 0.67 -3.45 -0.345 0.58873E+04 105 lizardite 23.24 21.57 -1.68 -0.140 0.28618E+04 107 magnetite 20.09 15.72 -4.37 -0.356 0.74536E+04 108 minnesotaite 10.39 7.58 -2.81 -0.165 0.48028E+04 112 manganosite 14.06 9.24 -4.82 -1.205 0.82266E+04 120 muscovite 2.58 -1.01 -3.59 -0.211 0.61313E+04 121 paragonite 4.24 1.09 -3.15 -0.185 0.53704E+04 122 nepheline 8.34 5.93 -2.41 -0.344 0.41124E+04 128 periclase-Fe 11.63 6.73 -4.89 -1.223 0.83523E+04 134 phlogopite-Na 29.65 27.50 -2.15 -0.119 0.36676E+04 136 prehnite 19.37 18.21 -1.16 -0.068 0.19848E+04 137 prehnite-Fe 22.50 21.96 -0.53 -0.032 0.91154E+03 138 pumpellyite-Fe 46.27 43.89 -2.38 -0.053 0.40577E+04 139 pumpellyite-Mg 48.99 46.45 -2.54 -0.057 0.43416E+04 143 pyrrhotite -4.26 -7.98 -3.72 -1.241 0.63563E+04 144 pyrrhotiteFe0.875 -6.02 -9.38 -3.36 -1.237 0.57436E+04 145 pyroxmangite 7.40 6.08 -1.32 -0.263 0.22470E+04 146 pyrophyllite -6.18 -11.15 -4.98 -0.311 0.84961E+04 147 quartz -2.99 -3.16 -0.17 -0.056 0.28683E+03 152 rhodonite 7.45 6.08 -1.36 -0.273 0.23273E+04 153 sanidine -1.28 -2.49 -1.21 -0.093 0.20677E+04 165 stilpnomelane-Mg 27.44 25.81 -1.63 -0.049 0.27803E+04 171 talc 16.49 15.25 -1.24 -0.073 0.21140E+04 174 tephroite 18.09 15.32 -2.76 -0.395 0.47178E+04 178 tridymite -2.63 -3.16 -0.53 -0.177 0.90681E+03 179 tremolite 47.87 47.42 -0.45 -0.012 0.77495E+03 180 ferroactinolite 38.45 34.62 -3.83 -0.104 0.65450E+04 181 troilite-low -4.41 -7.98 -3.57 -1.191 0.60991E+04 183 vesuvianite 223.47 218.82 -4.65 -0.036 0.79427E+04 187 wairakite 3.95 1.95 -2.00 -0.118 0.34154E+04 188 walstromite 11.51 9.94 -1.56 -0.313 0.26719E+04 189 wollastonite 10.46 9.94 -0.52 -0.103 0.88229E+03 190 pseudo-wollastonite 11.00 9.94 -1.06 -0.211 0.18021E+04 191 zoisite 22.85 18.95 -3.90 -0.177 0.66607E+04 192 akaganeite 7.75 4.49 -3.26 -0.705 0.55681E+04 199 chalcedony -2.80 -3.16 -0.35 -0.118 0.60613E+03 201 montmorillonite-Ca -2.29 -6.17 -3.88 -0.240 0.66180E+04 202 montmorillonite-K -2.24 -6.27 -4.03 -0.247 0.68816E+04 203 montmorillonite-Mg -2.48 -6.79 -4.31 -0.267 0.73677E+04 204 montmorillonite-Na -2.04 -5.57 -3.54 -0.216 0.60365E+04 205 nontronite-Ca 3.21 -0.19 -3.41 -0.221 0.58216E+04 206 nontronite-H 2.53 -2.36 -4.89 -0.328 0.83486E+04 207 nontronite-K 3.34 -0.30 -3.64 -0.233 0.62084E+04 208 nontronite-Mg 3.07 -0.82 -3.90 -0.253 0.66554E+04 209 nontronite-Na 3.52 0.40 -3.12 -0.200 0.53293E+04 224 tobermorite 9.82 7.76 -2.07 -0.564 0.35287E+04 230 alabandite -0.98 -5.48 -4.50 -1.500 0.76836E+04 233 boehmite 4.41 0.74 -3.67 -0.611 0.62618E+04 235 ferrous-oxide 9.81 6.73 -3.08 -0.769 0.52532E+04 240 silica-amorphous -2.09 -3.16 -1.07 -0.355 0.18203E+04 242 an20ab80 2.02 1.35 -0.67 -0.052 0.11472E+04 243 an25ab75 2.65 1.78 -0.87 -0.067 0.14810E+04 244 an30ab70 3.28 2.21 -1.07 -0.082 0.18243E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 40.0000000 g Current total amount of reactant added: 1719.9990000 g New total amount of reactant added: 1759.9990000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.3297E-10 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 11 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 1759.9990000 Water: Moles liquid = 0.4561E+02 kg liquid = 0.8217E+00 Moles total = 0.3345E+02 kg total = 0.6025E+00 Activity = 1.0000 Stoichiometric ionic strength = .1134238E-01 Osmotic coef. = 0.9692 True ionic strength = .2002732E-01 Chg. balance for total moles = 0.3297E-10 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.88332E-10 -10.0539 0.74219E-10 -10.1295 0.84023E+00 -0.0756 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.16714E-03 -3.7769 0.13959E-03 -3.8551 0.83517E+00 -0.0782 4 SO4-- 0.78762E-12 -12.1037 0.40897E-12 -12.3883 0.51925E+00 -0.2846 5 HCO3- 0.29145E-06 -6.5354 0.24377E-06 -6.6130 0.83640E+00 -0.0776 6 HS- 0.31032E-04 -4.5082 0.25921E-04 -4.5863 0.83530E+00 -0.0782 7 Al+++ 0.97054E-29 -29.0130 0.22417E-29 -29.6494 0.23097E+00 -0.6364 8 H4SiO4 0.69595E-03 -3.1574 0.69595E-03 -3.1574 0.10000E+01 0.0000 9 Ca++ 0.13512E-06 -6.8693 0.69643E-07 -7.1571 0.51543E+00 -0.2878 10 Mg++ 0.21138E-10 -10.6749 0.10845E-10 -10.9648 0.51308E+00 -0.2898 11 Fe++ 0.58258E-13 -13.2346 0.29924E-13 -13.5240 0.51364E+00 -0.2893 12 K+ 0.15658E-03 -3.8053 0.13100E-03 -3.8827 0.83659E+00 -0.0775 13 Na+ 0.19870E-01 -1.7018 0.16592E-01 -1.7801 0.83502E+00 -0.0783 14 Mn++ 0.18628E-10 -10.7298 0.95761E-11 -11.0188 0.51406E+00 -0.2890 15 HPO4-- 0.45285E-07 -7.3440 0.23518E-07 -7.6286 0.51932E+00 -0.2846 16 HSiO3- 0.10484E-01 -1.9795 0.87557E-02 -2.0577 0.83517E+00 -0.0782 17 Ca(HSiO3)+ 0.16596E-07 -7.7800 0.13887E-07 -7.8574 0.83677E+00 -0.0774 18 Mg(HSiO3)+ 0.32163E-11 -11.4926 0.26913E-11 -11.5700 0.83677E+00 -0.0774 19 NaHSiO3,aq 0.23495E-02 -2.6290 0.23495E-02 -2.6290 0.10000E+01 0.0000 20 AlO+ 0.66162E-16 -16.1794 0.55362E-16 -16.2568 0.83677E+00 -0.0774 22 HAlO2,aq 0.14855E-09 -9.8281 0.14855E-09 -9.8281 0.10000E+01 0.0000 23 AlO2- 0.53145E-05 -5.2745 0.44305E-05 -5.3535 0.83367E+00 -0.0790 24 CH4,aq 0.15060E-04 -4.8222 0.15008E-04 -4.8237 0.99654E+00 -0.0015 25 C2H6,aq 0.33358E-14 -14.4768 0.33243E-14 -14.4783 0.99654E+00 -0.0015 29 CO,aq 0.11249E-16 -16.9489 0.11249E-16 -16.9489 0.10000E+01 0.0000 30 CO2,aq 0.38793E-10 -10.4112 0.38659E-10 -10.4127 0.99654E+00 -0.0015 31 CO3-2 0.55368E-06 -6.2567 0.28688E-06 -6.5423 0.51814E+00 -0.2855 32 CaCO3,aq 0.25052E-09 -9.6012 0.25052E-09 -9.6012 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.51789E-12 -12.2858 0.43335E-12 -12.3632 0.83677E+00 -0.0774 34 CaCl+ 0.18802E-10 -10.7258 0.15733E-10 -10.8032 0.83677E+00 -0.0774 35 CaCl2,aq 0.52176E-15 -15.2825 0.52176E-15 -15.2825 0.10000E+01 0.0000 36 CaOH+ 0.79920E-07 -7.0973 0.66875E-07 -7.1747 0.83677E+00 -0.0774 37 CaSO4,aq 0.90443E-17 -17.0436 0.90443E-17 -17.0436 0.10000E+01 0.0000 38 HCl,aq 0.18985E-14 -14.7216 0.18985E-14 -14.7216 0.10000E+01 0.0000 43 FeCl+ 0.79014E-17 -17.1023 0.66117E-17 -17.1797 0.83677E+00 -0.0774 46 FeO,aq 0.21113E-09 -9.6755 0.21113E-09 -9.6755 0.10000E+01 0.0000 47 FeOH+ 0.15684E-10 -10.8045 0.13124E-10 -10.8819 0.83677E+00 -0.0774 48 HFeO2- 0.35638E-07 -7.4481 0.29764E-07 -7.5263 0.83517E+00 -0.0782 49 FeO+ 0.10992E-16 -16.9589 0.91974E-17 -17.0363 0.83677E+00 -0.0774 51 FeO2- 0.40908E-09 -9.3882 0.34165E-09 -9.4664 0.83517E+00 -0.0782 52 HFeO2,aq 0.32250E-11 -11.4915 0.32250E-11 -11.4915 0.10000E+01 0.0000 53 H2,aq 0.11624E-04 -4.9347 0.11584E-04 -4.9362 0.99654E+00 -0.0015 54 KCl,aq 0.33142E-09 -9.4796 0.33142E-09 -9.4796 0.10000E+01 0.0000 56 KOH,aq 0.75375E-06 -6.1228 0.75375E-06 -6.1228 0.10000E+01 0.0000 57 KSO4- 0.99540E-15 -15.0020 0.83133E-15 -15.0802 0.83517E+00 -0.0782 58 MgCO3,aq 0.97789E-14 -14.0097 0.97789E-14 -14.0097 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.82408E-16 -16.0840 0.68957E-16 -16.1614 0.83677E+00 -0.0774 60 MgCl+ 0.26537E-14 -14.5761 0.22206E-14 -14.6535 0.83677E+00 -0.0774 61 MgOH+ 0.68869E-10 -10.1620 0.57628E-10 -10.2394 0.83677E+00 -0.0774 63 MnO,aq 0.18003E-08 -8.7447 0.18003E-08 -8.7447 0.10000E+01 0.0000 64 MnOH+ 0.46626E-09 -9.3314 0.39015E-09 -9.4088 0.83677E+00 -0.0774 65 MnO2-2 0.20933E-10 -10.6792 0.10846E-10 -10.9647 0.51814E+00 -0.2855 66 HMnO2- 0.21117E-09 -9.6754 0.17637E-09 -9.7536 0.83517E+00 -0.0782 69 MnCl+ 0.98373E-14 -14.0071 0.82316E-14 -14.0845 0.83677E+00 -0.0774 71 NaCl,aq 0.76755E-06 -6.1149 0.76755E-06 -6.1149 0.10000E+01 0.0000 72 NaOH,aq 0.96047E-04 -4.0175 0.96047E-04 -4.0175 0.10000E+01 0.0000 74 OH- 0.93379E-02 -2.0298 0.77847E-02 -2.1088 0.83367E+00 -0.0790 79 HPO3-2 0.16384E-14 -14.7856 0.84895E-15 -15.0711 0.51814E+00 -0.2855 81 H2PO3- 0.15129E-18 -18.8202 0.12635E-18 -18.8984 0.83517E+00 -0.0782 82 H3PO4,aq 0.90604E-18 -18.0429 0.90604E-18 -18.0429 0.10000E+01 0.0000 83 H2PO4- 0.38517E-10 -10.4143 0.32199E-10 -10.4922 0.83597E+00 -0.0778 84 PO4-3 0.10657E-08 -8.9724 0.25853E-09 -9.5875 0.24259E+00 -0.6151 88 HP2O7-3 0.94597E-18 -18.0241 0.21871E-18 -18.6601 0.23120E+00 -0.6360 89 P2O7-4 0.91341E-17 -17.0393 0.70398E-18 -18.1524 0.77072E-01 -1.1131 90 H2S,aq 0.59665E-08 -8.2243 0.59458E-08 -8.2258 0.99654E+00 -0.0015 91 S2-2 0.24805E-14 -14.6055 0.12853E-14 -14.8910 0.51814E+00 -0.2855 97 SO3-2 0.11712E-17 -17.9314 0.61562E-18 -18.2107 0.52564E+00 -0.2793 99 HSO4- 0.34924E-19 -19.4569 0.29252E-19 -19.5338 0.83759E+00 -0.0770 Charge balance for all species = 0.4013E-10 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.8833229E-10 -.2229284E-01 -.2243079E+02 0.0000 2 H2O 0.1000000E+01 0.5550489E+02 0.9981991E+06 0.0000 3 Cl- 0.1671418E-03 0.1679097E-03 0.5942556E+01 6.2743 4 SO4-- 0.7876203E-12 -.1796621E-04 -.1722863E+01 7.8707 5 HCO3- 0.2914524E-06 0.1590573E-04 0.9688361E+00 3.5165 6 HS- 0.3103208E-04 0.4900426E-04 0.1617852E+01 5.5431 7 Al+++ 0.9705436E-29 0.5314642E-05 0.1431478E+00 0.7390 8 H4SiO4 0.6959522E-03 0.1352918E-01 0.1298102E+04 -3.1574 9 Ca++ 0.1351159E-06 0.2319019E-06 0.9278008E-02 13.1018 10 Mg++ 0.2113802E-10 0.9323579E-10 0.2262808E-05 9.2942 11 Fe++ 0.5825848E-13 0.3627736E-07 0.2022460E-02 6.7350 12 K+ 0.1565832E-03 0.1573373E-03 0.6141510E+01 6.2467 13 Na+ 0.1986963E-01 0.2231600E-01 0.5121485E+03 8.3494 14 Mn++ 0.1862823E-10 0.2517315E-08 0.1380558E-03 9.2402 15 HPO4-- 0.4528545E-07 0.4638967E-07 0.4444695E-02 12.6304 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.2914296E+02 -.1831839E-01 -.2912464E+02 0.0000000E+00 2 H2O 0.3344594E+02 0.4560928E+02 -.1216334E+02 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.4880108E-01 -.1476313E-04 0.4881584E-01 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.4877557E-01 0.4026760E-04 -.4881584E-01 0.0000000E+00 7 Al+++ 0.5738902E+01 0.4367129E-05 0.5738898E+01 0.0000000E+00 8 H4SiO4 0.1832649E+02 0.1111715E-01 0.1831537E+02 0.0000000E+00 9 Ca++ 0.2024264E+01 0.1905576E-06 0.2024264E+01 0.0000000E+00 10 Mg++ 0.1396825E+01 0.7661338E-10 0.1396825E+01 0.0000000E+00 11 Fe++ 0.1254894E+01 0.2980970E-07 0.1254894E+01 0.0000000E+00 12 K+ 0.3736728E+00 0.1292867E-03 0.3735435E+00 0.0000000E+00 13 Na+ 0.2209388E+01 0.1833742E-01 0.2191050E+01 0.0000000E+00 14 Mn++ 0.3051591E-01 0.2068519E-08 0.3051591E-01 0.0000000E+00 15 HPO4-- 0.1041493E-01 0.3811916E-07 0.1041489E-01 0.0000000E+00 Chg. balance for solid moles: -.9576E-14 Mass of aqueous solution: 0.823147E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 1759.9990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 2.189 0.340 574.0 2.759 29.86 220.4 andradite 0.1953 -0.709 99.23 1.997 5.161 25.78 grossular 0.4729E-01 -1.325 21.30 1.328 1.108 5.927 apatite-OH 0.3472E-02 -2.459 1.744 0.242 0.9070E-01 0.5541 clinochlore 0.2509 -0.601 139.4 2.144 7.252 53.04 daphnite 0.7262E-01 -1.139 51.81 1.714 2.695 15.70 chlorite-Mn 0.6103E-02 -2.214 4.327 0.636 0.2251 1.379 diopside 0.8647E-01 -1.063 18.73 1.272 0.9740 5.723 hedenbergite 0.2242E-01 -1.649 5.563 0.745 0.2894 1.524 microcline 0.3276 -0.485 91.18 1.960 4.743 35.62 stilbite 1.139 0.057 803.0 2.905 41.76 374.5 stilpnomelane-Fe 0.9190E-01 -1.037 99.07 1.996 5.153 34.22 tr.625ac.25prg.125 0.1547E-01 -1.811 13.22 1.121 0.6877 4.255 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8050E+00 0.8050E+00 1.0000 -0.094 grossular 0.1950E+00 0.1950E+00 1.0000 -0.710 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.7611E+00 0.7611E+00 1.0000 -0.119 daphnite 0.2203E+00 0.2203E+00 1.0000 -0.657 chlorite-Mn 0.1852E-01 0.1852E-01 1.0000 -1.732 diopside 0.7941E+00 0.7941E+00 1.0000 -0.100 hedenbergite 0.2059E+00 0.2059E+00 1.0000 -0.686 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 tr.625ac.25prg.125 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 1922.616334 g Volume = 778.598579 cm3 Porosity: -10.4396% V(tot) - V(min): -.73599E+02 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 1759.9990000 g log = 3.2455 Original solution: 1000.0103000 g Original solution / Rock added: 0.57 (Water/Rock Ratio), log = -0.2455 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0578 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9650E+00 0.9854 0.1006E+01 0.1021E+01 CO2,gas 0.3883E-08 1.0069 0.4136E-08 0.4108E-08 CH4,gas 0.2063E-01 1.0124 0.2209E-01 0.2182E-01 H2,gas 0.1437E-01 1.0006 0.1521E-01 0.1520E-01 H2S,gas 0.1551E-06 0.9959 0.1634E-06 0.1641E-06 S2,gas 0.4099E-29 1.0000 0.4336E-29 0.4336E-29 CO,gas 0.1585E-13 1.0000 0.1676E-13 0.1676E-13 SO3,gas 0.8052E-48 1.0000 0.8518E-48 0.8518E-48 SO2,gas 0.4764E-27 1.0000 0.5040E-27 0.5040E-27 HCl,gas 0.3167E-17 1.0000 0.3350E-17 0.3350E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 16 albite -0.38 -0.38 0.00 0.000 -0.94784E-12 22 andradite 39.01 39.01 0.00 0.000 0.12132E-10 23 grossular 32.73 32.73 0.00 0.000 0.00000E+00 32 apatite-OH -18.15 -18.15 0.00 0.000 0.00000E+00 46 clinochlore 39.07 39.07 0.00 0.000 0.00000E+00 47 daphnite 28.97 28.97 0.00 0.000 -0.24265E-10 48 chlorite-Mn 46.87 46.87 0.00 0.000 0.00000E+00 67 diopside 16.18 16.18 0.00 0.000 -0.60662E-11 68 hedenbergite 14.21 14.21 0.00 0.000 -0.90992E-11 116 microcline -2.49 -2.49 0.00 0.000 -0.10616E-10 163 stilbite -7.52 -7.52 0.00 0.000 -0.90992E-11 164 stilpnomelane-Fe 13.02 13.02 0.00 0.000 0.69761E-10 245 tr.625ac.25prg.125 45.16 45.16 0.00 0.000 -0.24265E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -16.74 -10.08 -3.361 0.17215E+05 -8.383 3 CH4,gas 4.54 1.19 -3.35 -0.839 0.57281E+04 -1.656 4 H2,gas 8.00 4.48 -3.52 -2.010 0.60050E+04 -1.818 5 H2S,gas -6.23 -14.72 -8.49 -4.243 0.14489E+05 -6.787 6 S2,gas -7.34 -38.40 -31.06 -4.779 0.53037E+05 -29.363 7 CO,gas 3.21 -12.26 -15.47 -4.761 0.26422E+05 -13.776 8 SO3,gas 17.12 -32.65 -49.77 -12.442 0.84979E+05 -48.070 9 SO2,gas 0.83 -28.16 -29.00 -7.732 0.49511E+05 -27.298 10 HCl,gas 5.19 -13.98 -19.17 -9.587 0.32739E+05 -17.475 11 acmite 7.71 6.53 -1.18 -0.123 0.20176E+04 15 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 19 spessartine 24.46 19.73 -4.73 -0.237 0.80782E+04 20 analcite 3.32 2.77 -0.55 -0.061 0.93622E+03 26 annite 20.12 17.72 -2.40 -0.134 0.41064E+04 27 phlogopite 27.06 25.40 -1.67 -0.093 0.28488E+04 29 anorthite 12.71 8.27 -4.45 -0.342 0.75902E+04 35 aragonite 0.97 -3.64 -4.61 -1.536 0.78666E+04 36 brucite 12.57 9.29 -3.27 -0.655 0.55909E+04 37 calcite 0.81 -3.64 -4.45 -1.484 0.76024E+04 38 carnegieite-low 9.02 5.93 -3.09 -0.442 0.52801E+04 39 carnegieite-high 10.09 5.93 -4.16 -0.595 0.71071E+04 40 carpholite-Mg 8.58 4.46 -4.12 -0.275 0.70428E+04 41 carpholite-Fe 6.71 1.90 -4.81 -0.321 0.82205E+04 42 celadonite 5.34 3.65 -1.69 -0.099 0.28879E+04 43 celadonite-Fe 3.88 1.09 -2.79 -0.164 0.47561E+04 44 chrysotile 23.89 21.57 -2.32 -0.194 0.39692E+04 49 chlorite-Al-free 47.17 43.14 -4.04 -0.168 0.68935E+04 51 chloritoid-Fe 9.17 5.06 -4.12 -0.275 0.70314E+04 52 chloritoid-Mn 11.40 7.56 -3.84 -0.256 0.65572E+04 54 coesite -2.38 -3.16 -0.78 -0.260 0.13341E+04 61 cristobalite -2.56 -3.16 -0.60 -0.199 0.10195E+04 63 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71234E+04 65 diaspore 2.87 0.74 -2.13 -0.356 0.36449E+04 66 diamond -3.10 -7.78 -4.67 -1.336 0.79814E+04 71 enstatite 17.26 12.27 -4.99 -0.499 0.85225E+04 73 clinoenstatite 17.17 12.27 -4.89 -0.489 0.83541E+04 75 epidote 24.67 22.70 -1.97 -0.095 0.33584E+04 76 clinozoisite 22.81 18.95 -3.86 -0.175 0.65866E+04 77 epidote-Fe 29.84 26.46 -3.38 -0.176 0.57768E+04 78 fayalite 14.05 10.31 -3.73 -0.533 0.63743E+04 79 ferrosilite 11.15 7.16 -3.99 -0.399 0.68202E+04 83 gibbsite 4.08 0.74 -3.34 -0.477 0.57034E+04 84 glaucophane 22.97 20.80 -2.17 -0.059 0.37133E+04 85 glaucophane-Fe 17.28 13.12 -4.15 -0.112 0.70919E+04 86 graphite -3.55 -7.78 -4.23 -1.209 0.72236E+04 87 greenalite 16.14 13.89 -2.25 -0.187 0.38408E+04 90 hematite 12.57 8.99 -3.58 -0.434 0.61112E+04 91 heulandite -5.83 -7.52 -1.69 -0.077 0.28938E+04 95 jadeite 4.22 2.77 -1.44 -0.144 0.24617E+04 97 kalsilite 7.58 3.83 -3.76 -0.537 0.64125E+04 98 kaolinite -1.33 -4.84 -3.50 -0.319 0.59830E+04 101 laumontite 2.88 1.95 -0.93 -0.062 0.15934E+04 102 lawsonite 9.62 8.27 -1.35 -0.090 0.23068E+04 103 leucite 4.12 0.67 -3.45 -0.345 0.58873E+04 105 lizardite 23.24 21.57 -1.68 -0.140 0.28618E+04 107 magnetite 20.09 15.72 -4.37 -0.356 0.74536E+04 108 minnesotaite 10.39 7.58 -2.81 -0.165 0.48028E+04 112 manganosite 14.06 9.24 -4.82 -1.204 0.82265E+04 120 muscovite 2.58 -1.01 -3.59 -0.211 0.61313E+04 121 paragonite 4.24 1.09 -3.15 -0.185 0.53704E+04 122 nepheline 8.34 5.93 -2.41 -0.344 0.41124E+04 128 periclase-Fe 11.63 6.73 -4.89 -1.223 0.83523E+04 134 phlogopite-Na 29.65 27.50 -2.15 -0.119 0.36676E+04 136 prehnite 19.37 18.21 -1.16 -0.068 0.19848E+04 137 prehnite-Fe 22.50 21.96 -0.53 -0.032 0.91155E+03 138 pumpellyite-Fe 46.27 43.89 -2.38 -0.053 0.40578E+04 139 pumpellyite-Mg 48.99 46.45 -2.54 -0.057 0.43416E+04 143 pyrrhotite -4.26 -7.98 -3.72 -1.240 0.63527E+04 144 pyrrhotiteFe0.875 -6.02 -9.38 -3.36 -1.236 0.57399E+04 145 pyroxmangite 7.40 6.08 -1.32 -0.263 0.22469E+04 146 pyrophyllite -6.18 -11.15 -4.98 -0.311 0.84961E+04 147 quartz -2.99 -3.16 -0.17 -0.056 0.28683E+03 152 rhodonite 7.45 6.08 -1.36 -0.273 0.23272E+04 153 sanidine -1.28 -2.49 -1.21 -0.093 0.20677E+04 165 stilpnomelane-Mg 27.44 25.81 -1.63 -0.049 0.27803E+04 171 talc 16.49 15.25 -1.24 -0.073 0.21140E+04 174 tephroite 18.09 15.32 -2.76 -0.395 0.47176E+04 178 tridymite -2.63 -3.16 -0.53 -0.177 0.90681E+03 179 tremolite 47.87 47.42 -0.45 -0.012 0.77495E+03 180 ferroactinolite 38.45 34.62 -3.83 -0.104 0.65450E+04 181 troilite-low -4.41 -7.98 -3.57 -1.190 0.60955E+04 183 vesuvianite 223.47 218.82 -4.65 -0.036 0.79428E+04 187 wairakite 3.95 1.95 -2.00 -0.118 0.34154E+04 188 walstromite 11.51 9.94 -1.56 -0.313 0.26719E+04 189 wollastonite 10.46 9.94 -0.52 -0.103 0.88229E+03 190 pseudo-wollastonite 11.00 9.94 -1.06 -0.211 0.18021E+04 191 zoisite 22.85 18.95 -3.90 -0.177 0.66607E+04 192 akaganeite 7.75 4.49 -3.26 -0.705 0.55681E+04 199 chalcedony -2.80 -3.16 -0.35 -0.118 0.60613E+03 201 montmorillonite-Ca -2.29 -6.17 -3.88 -0.240 0.66180E+04 202 montmorillonite-K -2.24 -6.27 -4.03 -0.247 0.68816E+04 203 montmorillonite-Mg -2.48 -6.79 -4.32 -0.267 0.73677E+04 204 montmorillonite-Na -2.04 -5.57 -3.54 -0.216 0.60365E+04 205 nontronite-Ca 3.21 -0.19 -3.41 -0.221 0.58216E+04 206 nontronite-H 2.53 -2.36 -4.89 -0.328 0.83486E+04 207 nontronite-K 3.34 -0.30 -3.64 -0.233 0.62084E+04 208 nontronite-Mg 3.07 -0.82 -3.90 -0.253 0.66554E+04 209 nontronite-Na 3.52 0.40 -3.12 -0.200 0.53293E+04 224 tobermorite 9.82 7.76 -2.07 -0.564 0.35287E+04 230 alabandite -0.98 -5.48 -4.50 -1.499 0.76799E+04 233 boehmite 4.41 0.74 -3.67 -0.611 0.62618E+04 235 ferrous-oxide 9.81 6.73 -3.08 -0.769 0.52532E+04 240 silica-amorphous -2.09 -3.16 -1.07 -0.355 0.18203E+04 242 an20ab80 2.02 1.35 -0.67 -0.052 0.11472E+04 243 an25ab75 2.65 1.78 -0.87 -0.067 0.14810E+04 244 an30ab70 3.28 2.21 -1.07 -0.082 0.18243E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 40.0000000 g Current total amount of reactant added: 1759.9990000 g New total amount of reactant added: 1799.9990000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.3297E-10 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 11 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 1799.9990000 Water: Moles liquid = 0.4539E+02 kg liquid = 0.8177E+00 Moles total = 0.3294E+02 kg total = 0.5935E+00 Activity = 1.0000 Stoichiometric ionic strength = .1134307E-01 Osmotic coef. = 0.9692 True ionic strength = .2002786E-01 Chg. balance for total moles = 0.3297E-10 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.88335E-10 -10.0539 0.74221E-10 -10.1295 0.84023E+00 -0.0756 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.16796E-03 -3.7748 0.14028E-03 -3.8530 0.83517E+00 -0.0782 4 SO4-- 0.79148E-12 -12.1016 0.41097E-12 -12.3862 0.51924E+00 -0.2846 5 HCO3- 0.29288E-06 -6.5333 0.24496E-06 -6.6109 0.83639E+00 -0.0776 6 HS- 0.31185E-04 -4.5061 0.26048E-04 -4.5842 0.83529E+00 -0.0782 7 Al+++ 0.97063E-29 -29.0129 0.22418E-29 -29.6494 0.23097E+00 -0.6365 8 H4SiO4 0.69595E-03 -3.1574 0.69595E-03 -3.1574 0.10000E+01 0.0000 9 Ca++ 0.13512E-06 -6.8693 0.69647E-07 -7.1571 0.51543E+00 -0.2878 10 Mg++ 0.21139E-10 -10.6749 0.10846E-10 -10.9647 0.51307E+00 -0.2898 11 Fe++ 0.58262E-13 -13.2346 0.29925E-13 -13.5240 0.51363E+00 -0.2893 12 K+ 0.15659E-03 -3.8052 0.13100E-03 -3.8827 0.83659E+00 -0.0775 13 Na+ 0.19870E-01 -1.7018 0.16592E-01 -1.7801 0.83502E+00 -0.0783 14 Mn++ 0.18631E-10 -10.7298 0.95776E-11 -11.0187 0.51406E+00 -0.2890 15 HPO4-- 0.45284E-07 -7.3441 0.23517E-07 -7.6286 0.51932E+00 -0.2846 16 HSiO3- 0.10483E-01 -1.9795 0.87555E-02 -2.0577 0.83517E+00 -0.0782 17 Ca(HSiO3)+ 0.16596E-07 -7.7800 0.13887E-07 -7.8574 0.83677E+00 -0.0774 18 Mg(HSiO3)+ 0.32164E-11 -11.4926 0.26914E-11 -11.5700 0.83677E+00 -0.0774 19 NaHSiO3,aq 0.23496E-02 -2.6290 0.23496E-02 -2.6290 0.10000E+01 0.0000 20 AlO+ 0.66163E-16 -16.1794 0.55363E-16 -16.2568 0.83677E+00 -0.0774 22 HAlO2,aq 0.14855E-09 -9.8281 0.14855E-09 -9.8281 0.10000E+01 0.0000 23 AlO2- 0.53143E-05 -5.2745 0.44304E-05 -5.3536 0.83366E+00 -0.0790 24 CH4,aq 0.15134E-04 -4.8200 0.15082E-04 -4.8215 0.99654E+00 -0.0015 25 C2H6,aq 0.33687E-14 -14.4725 0.33570E-14 -14.4740 0.99654E+00 -0.0015 29 CO,aq 0.11305E-16 -16.9467 0.11305E-16 -16.9467 0.10000E+01 0.0000 30 CO2,aq 0.38984E-10 -10.4091 0.38850E-10 -10.4106 0.99654E+00 -0.0015 31 CO3-2 0.55638E-06 -6.2546 0.28828E-06 -6.5402 0.51814E+00 -0.2856 32 CaCO3,aq 0.25175E-09 -9.5990 0.25175E-09 -9.5990 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.52045E-12 -12.2836 0.43550E-12 -12.3610 0.83677E+00 -0.0774 34 CaCl+ 0.18895E-10 -10.7237 0.15811E-10 -10.8010 0.83677E+00 -0.0774 35 CaCl2,aq 0.52693E-15 -15.2783 0.52693E-15 -15.2783 0.10000E+01 0.0000 36 CaOH+ 0.79922E-07 -7.0973 0.66877E-07 -7.1747 0.83677E+00 -0.0774 37 CaSO4,aq 0.90891E-17 -17.0415 0.90891E-17 -17.0415 0.10000E+01 0.0000 38 HCl,aq 0.19079E-14 -14.7194 0.19079E-14 -14.7194 0.10000E+01 0.0000 43 FeCl+ 0.79406E-17 -17.1001 0.66445E-17 -17.1775 0.83677E+00 -0.0774 46 FeO,aq 0.21113E-09 -9.6755 0.21113E-09 -9.6755 0.10000E+01 0.0000 47 FeOH+ 0.15684E-10 -10.8045 0.13124E-10 -10.8819 0.83677E+00 -0.0774 48 HFeO2- 0.35637E-07 -7.4481 0.29763E-07 -7.5263 0.83517E+00 -0.0782 49 FeO+ 0.10992E-16 -16.9589 0.91977E-17 -17.0363 0.83677E+00 -0.0774 51 FeO2- 0.40907E-09 -9.3882 0.34164E-09 -9.4664 0.83517E+00 -0.0782 52 HFeO2,aq 0.32250E-11 -11.4915 0.32250E-11 -11.4915 0.10000E+01 0.0000 53 H2,aq 0.11624E-04 -4.9347 0.11584E-04 -4.9362 0.99654E+00 -0.0015 54 KCl,aq 0.33306E-09 -9.4775 0.33306E-09 -9.4775 0.10000E+01 0.0000 56 KOH,aq 0.75375E-06 -6.1228 0.75375E-06 -6.1228 0.10000E+01 0.0000 57 KSO4- 0.10003E-14 -14.9999 0.83542E-15 -15.0781 0.83517E+00 -0.0782 58 MgCO3,aq 0.98271E-14 -14.0076 0.98271E-14 -14.0076 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.82817E-16 -16.0819 0.69299E-16 -16.1593 0.83677E+00 -0.0774 60 MgCl+ 0.26669E-14 -14.5740 0.22316E-14 -14.6514 0.83677E+00 -0.0774 61 MgOH+ 0.68871E-10 -10.1620 0.57629E-10 -10.2394 0.83677E+00 -0.0774 63 MnO,aq 0.18005E-08 -8.7446 0.18005E-08 -8.7446 0.10000E+01 0.0000 64 MnOH+ 0.46632E-09 -9.3313 0.39021E-09 -9.4087 0.83677E+00 -0.0774 65 MnO2-2 0.20935E-10 -10.6791 0.10847E-10 -10.9647 0.51814E+00 -0.2856 66 HMnO2- 0.21119E-09 -9.6753 0.17638E-09 -9.7535 0.83517E+00 -0.0782 69 MnCl+ 0.98872E-14 -14.0049 0.82734E-14 -14.0823 0.83677E+00 -0.0774 71 NaCl,aq 0.77134E-06 -6.1128 0.77134E-06 -6.1128 0.10000E+01 0.0000 72 NaOH,aq 0.96047E-04 -4.0175 0.96047E-04 -4.0175 0.10000E+01 0.0000 74 OH- 0.93377E-02 -2.0298 0.77845E-02 -2.1088 0.83366E+00 -0.0790 79 HPO3-2 0.16384E-14 -14.7856 0.84891E-15 -15.0711 0.51814E+00 -0.2856 81 H2PO3- 0.15128E-18 -18.8202 0.12635E-18 -18.8984 0.83517E+00 -0.0782 82 H3PO4,aq 0.90605E-18 -18.0428 0.90605E-18 -18.0428 0.10000E+01 0.0000 83 H2PO4- 0.38516E-10 -10.4144 0.32198E-10 -10.4922 0.83596E+00 -0.0778 84 PO4-3 0.10656E-08 -8.9724 0.25851E-09 -9.5875 0.24259E+00 -0.6151 88 HP2O7-3 0.94592E-18 -18.0241 0.21869E-18 -18.6602 0.23120E+00 -0.6360 89 P2O7-4 0.91335E-17 -17.0394 0.70391E-18 -18.1525 0.77070E-01 -1.1131 90 H2S,aq 0.59959E-08 -8.2221 0.59752E-08 -8.2236 0.99654E+00 -0.0015 91 S2-2 0.25049E-14 -14.6012 0.12979E-14 -14.8868 0.51814E+00 -0.2856 97 SO3-2 0.11769E-17 -17.9293 0.61863E-18 -18.2086 0.52564E+00 -0.2793 99 HSO4- 0.35096E-19 -19.4547 0.29396E-19 -19.5317 0.83759E+00 -0.0770 Charge balance for all species = 0.4032E-10 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.8833464E-10 -.2229240E-01 -.2243034E+02 0.0000 2 H2O 0.1000000E+01 0.5550489E+02 0.9981990E+06 0.0000 3 Cl- 0.1679629E-03 0.1687346E-03 0.5971749E+01 6.2765 4 SO4-- 0.7914839E-12 -.1804021E-04 -.1729959E+01 7.8728 5 HCO3- 0.2928814E-06 0.1598387E-04 0.9735956E+00 3.5186 6 HS- 0.3118452E-04 0.4923073E-04 0.1625329E+01 5.5453 7 Al+++ 0.9706280E-29 0.5314498E-05 0.1431439E+00 0.7390 8 H4SiO4 0.6959531E-03 0.1352895E-01 0.1298080E+04 -3.1574 9 Ca++ 0.1351234E-06 0.2319132E-06 0.9278461E-02 13.1018 10 Mg++ 0.2113919E-10 0.9323898E-10 0.2262886E-05 9.2942 11 Fe++ 0.5826178E-13 0.3627651E-07 0.2022412E-02 6.7350 12 K+ 0.1565874E-03 0.1573415E-03 0.6141673E+01 6.2467 13 Na+ 0.1987016E-01 0.2231654E-01 0.5121609E+03 8.3494 14 Mn++ 0.1863137E-10 0.2517603E-08 0.1380717E-03 9.2402 15 HPO4-- 0.4528361E-07 0.4638777E-07 0.4444512E-02 12.6303 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.2980530E+02 -.1822848E-01 -.2978707E+02 0.0000000E+00 2 H2O 0.3294452E+02 0.4538631E+02 -.1244179E+02 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.4990961E-01 -.1475147E-04 0.4992436E-01 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.4988411E-01 0.4025594E-04 -.4992436E-01 0.0000000E+00 7 Al+++ 0.5869332E+01 0.4345662E-05 0.5869327E+01 0.0000000E+00 8 H4SiO4 0.1874300E+02 0.1106262E-01 0.1873194E+02 0.0000000E+00 9 Ca++ 0.2070270E+01 0.1896353E-06 0.2070270E+01 0.0000000E+00 10 Mg++ 0.1428571E+01 0.7624146E-10 0.1428571E+01 0.0000000E+00 11 Fe++ 0.1283415E+01 0.2966328E-07 0.1283415E+01 0.0000000E+00 12 K+ 0.3821654E+00 0.1286580E-03 0.3820367E+00 0.0000000E+00 13 Na+ 0.2259597E+01 0.1824822E-01 0.2241349E+01 0.0000000E+00 14 Mn++ 0.3120946E-01 0.2058643E-08 0.3120945E-01 0.0000000E+00 15 HPO4-- 0.1065163E-01 0.3793125E-07 0.1065159E-01 0.0000000E+00 Chg. balance for solid moles: -.2328E-14 Mass of aqueous solution: 0.819123E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 1799.9990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 2.239 0.350 587.2 2.769 29.86 225.4 andradite 0.1997 -0.700 101.5 2.006 5.161 26.37 grossular 0.4836E-01 -1.315 21.78 1.338 1.108 6.061 apatite-OH 0.3551E-02 -2.450 1.784 0.251 0.9070E-01 0.5667 clinochlore 0.2565 -0.591 142.6 2.154 7.251 54.24 daphnite 0.7426E-01 -1.129 52.99 1.724 2.695 16.06 chlorite-Mn 0.6242E-02 -2.205 4.425 0.646 0.2251 1.410 diopside 0.8864E-01 -1.052 19.20 1.283 0.9763 5.867 hedenbergite 0.2299E-01 -1.639 5.703 0.756 0.2900 1.562 microcline 0.3350 -0.475 93.25 1.970 4.743 36.43 stilbite 1.165 0.066 821.1 2.914 41.76 383.0 stilpnomelane-Fe 0.9399E-01 -1.027 101.3 2.006 5.153 35.00 tr.625ac.25prg.125 0.1580E-01 -1.801 13.51 1.131 0.6869 4.347 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8050E+00 0.8050E+00 1.0000 -0.094 grossular 0.1950E+00 0.1950E+00 1.0000 -0.710 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.7611E+00 0.7611E+00 1.0000 -0.119 daphnite 0.2203E+00 0.2203E+00 1.0000 -0.657 chlorite-Mn 0.1852E-01 0.1852E-01 1.0000 -1.732 diopside 0.7941E+00 0.7941E+00 1.0000 -0.100 hedenbergite 0.2059E+00 0.2059E+00 1.0000 -0.686 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 tr.625ac.25prg.125 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 1966.316599 g Volume = 796.279804 cm3 Porosity: -10.4411% V(tot) - V(min): -.75280E+02 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 1799.9990000 g log = 3.2553 Original solution: 1000.0103000 g Original solution / Rock added: 0.56 (Water/Rock Ratio), log = -0.2553 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0580 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9649E+00 0.9854 0.1006E+01 0.1021E+01 CO2,gas 0.3902E-08 1.0069 0.4156E-08 0.4128E-08 CH4,gas 0.2073E-01 1.0124 0.2220E-01 0.2193E-01 H2,gas 0.1437E-01 1.0006 0.1521E-01 0.1520E-01 H2S,gas 0.1559E-06 0.9959 0.1643E-06 0.1649E-06 S2,gas 0.4139E-29 1.0000 0.4379E-29 0.4379E-29 CO,gas 0.1592E-13 1.0000 0.1685E-13 0.1685E-13 SO3,gas 0.8091E-48 1.0000 0.8560E-48 0.8560E-48 SO2,gas 0.4787E-27 1.0000 0.5065E-27 0.5065E-27 HCl,gas 0.3182E-17 1.0000 0.3366E-17 0.3366E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 16 albite -0.38 -0.38 0.00 0.000 0.11184E-10 22 andradite 39.01 39.01 0.00 0.000 -0.12132E-10 23 grossular 32.73 32.73 0.00 0.000 0.12132E-10 32 apatite-OH -18.15 -18.15 0.00 0.000 0.00000E+00 46 clinochlore 39.07 39.07 0.00 0.000 0.24265E-10 47 daphnite 28.97 28.97 0.00 0.000 0.24265E-10 48 chlorite-Mn 46.87 46.87 0.00 0.000 0.12132E-10 67 diopside 16.18 16.18 0.00 0.000 0.60662E-11 68 hedenbergite 14.21 14.21 0.00 0.000 0.00000E+00 116 microcline -2.49 -2.49 0.00 0.000 -0.10616E-10 163 stilbite -7.52 -7.52 0.00 0.000 0.15165E-10 164 stilpnomelane-Fe 13.02 13.02 0.00 0.000 0.21232E-10 245 tr.625ac.25prg.125 45.16 45.16 0.00 0.000 0.12132E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -16.74 -10.08 -3.360 0.17212E+05 -8.381 3 CH4,gas 4.54 1.19 -3.35 -0.838 0.57245E+04 -1.654 4 H2,gas 8.00 4.48 -3.52 -2.010 0.60050E+04 -1.818 5 H2S,gas -6.23 -14.71 -8.48 -4.242 0.14485E+05 -6.784 6 S2,gas -7.34 -38.39 -31.06 -4.778 0.53030E+05 -29.359 7 CO,gas 3.21 -12.26 -15.47 -4.761 0.26419E+05 -13.773 8 SO3,gas 17.12 -32.65 -49.77 -12.442 0.84975E+05 -48.068 9 SO2,gas 0.83 -28.16 -28.99 -7.732 0.49507E+05 -27.295 10 HCl,gas 5.19 -13.98 -19.17 -9.586 0.32735E+05 -17.473 11 acmite 7.71 6.53 -1.18 -0.123 0.20176E+04 15 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 19 spessartine 24.46 19.73 -4.73 -0.237 0.80780E+04 20 analcite 3.32 2.77 -0.55 -0.061 0.93622E+03 26 annite 20.12 17.72 -2.40 -0.134 0.41064E+04 27 phlogopite 27.06 25.40 -1.67 -0.093 0.28488E+04 29 anorthite 12.71 8.27 -4.45 -0.342 0.75902E+04 35 aragonite 0.97 -3.64 -4.61 -1.535 0.78630E+04 36 brucite 12.57 9.29 -3.27 -0.655 0.55909E+04 37 calcite 0.81 -3.64 -4.45 -1.483 0.75988E+04 38 carnegieite-low 9.02 5.93 -3.09 -0.442 0.52801E+04 39 carnegieite-high 10.09 5.93 -4.16 -0.595 0.71071E+04 40 carpholite-Mg 8.58 4.46 -4.12 -0.275 0.70428E+04 41 carpholite-Fe 6.71 1.90 -4.81 -0.321 0.82205E+04 42 celadonite 5.34 3.65 -1.69 -0.099 0.28879E+04 43 celadonite-Fe 3.88 1.09 -2.79 -0.164 0.47561E+04 44 chrysotile 23.89 21.57 -2.32 -0.194 0.39692E+04 49 chlorite-Al-free 47.17 43.14 -4.04 -0.168 0.68935E+04 51 chloritoid-Fe 9.17 5.06 -4.12 -0.275 0.70314E+04 52 chloritoid-Mn 11.40 7.56 -3.84 -0.256 0.65571E+04 54 coesite -2.38 -3.16 -0.78 -0.260 0.13341E+04 61 cristobalite -2.56 -3.16 -0.60 -0.199 0.10195E+04 63 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71234E+04 65 diaspore 2.87 0.74 -2.13 -0.356 0.36449E+04 66 diamond -3.10 -7.77 -4.67 -1.335 0.79778E+04 71 enstatite 17.26 12.27 -4.99 -0.499 0.85225E+04 73 clinoenstatite 17.17 12.27 -4.89 -0.489 0.83541E+04 75 epidote 24.67 22.70 -1.97 -0.095 0.33584E+04 76 clinozoisite 22.81 18.95 -3.86 -0.175 0.65866E+04 77 epidote-Fe 29.84 26.46 -3.38 -0.176 0.57768E+04 78 fayalite 14.05 10.31 -3.73 -0.533 0.63743E+04 79 ferrosilite 11.15 7.16 -3.99 -0.399 0.68202E+04 83 gibbsite 4.08 0.74 -3.34 -0.477 0.57034E+04 84 glaucophane 22.97 20.80 -2.17 -0.059 0.37133E+04 85 glaucophane-Fe 17.28 13.12 -4.15 -0.112 0.70919E+04 86 graphite -3.55 -7.77 -4.23 -1.208 0.72200E+04 87 greenalite 16.14 13.89 -2.25 -0.187 0.38408E+04 90 hematite 12.57 8.99 -3.58 -0.434 0.61112E+04 91 heulandite -5.83 -7.52 -1.69 -0.077 0.28938E+04 95 jadeite 4.22 2.77 -1.44 -0.144 0.24617E+04 97 kalsilite 7.58 3.83 -3.76 -0.537 0.64125E+04 98 kaolinite -1.33 -4.84 -3.50 -0.319 0.59830E+04 101 laumontite 2.88 1.95 -0.93 -0.062 0.15934E+04 102 lawsonite 9.62 8.27 -1.35 -0.090 0.23068E+04 103 leucite 4.12 0.67 -3.45 -0.345 0.58873E+04 105 lizardite 23.24 21.57 -1.68 -0.140 0.28618E+04 107 magnetite 20.09 15.72 -4.37 -0.356 0.74536E+04 108 minnesotaite 10.39 7.58 -2.81 -0.165 0.48028E+04 112 manganosite 14.06 9.24 -4.82 -1.204 0.82265E+04 120 muscovite 2.58 -1.01 -3.59 -0.211 0.61313E+04 121 paragonite 4.24 1.09 -3.15 -0.185 0.53704E+04 122 nepheline 8.34 5.93 -2.41 -0.344 0.41124E+04 128 periclase-Fe 11.63 6.73 -4.89 -1.223 0.83523E+04 134 phlogopite-Na 29.65 27.50 -2.15 -0.119 0.36676E+04 136 prehnite 19.37 18.21 -1.16 -0.068 0.19848E+04 137 prehnite-Fe 22.50 21.96 -0.53 -0.032 0.91155E+03 138 pumpellyite-Fe 46.27 43.89 -2.38 -0.053 0.40578E+04 139 pumpellyite-Mg 48.99 46.45 -2.54 -0.057 0.43416E+04 143 pyrrhotite -4.26 -7.98 -3.72 -1.239 0.63490E+04 144 pyrrhotiteFe0.875 -6.02 -9.38 -3.36 -1.236 0.57363E+04 145 pyroxmangite 7.40 6.08 -1.32 -0.263 0.22469E+04 146 pyrophyllite -6.18 -11.15 -4.98 -0.311 0.84961E+04 147 quartz -2.99 -3.16 -0.17 -0.056 0.28683E+03 152 rhodonite 7.45 6.08 -1.36 -0.273 0.23271E+04 153 sanidine -1.28 -2.49 -1.21 -0.093 0.20677E+04 165 stilpnomelane-Mg 27.44 25.81 -1.63 -0.049 0.27803E+04 171 talc 16.49 15.25 -1.24 -0.073 0.21140E+04 174 tephroite 18.09 15.32 -2.76 -0.395 0.47174E+04 178 tridymite -2.63 -3.16 -0.53 -0.177 0.90681E+03 179 tremolite 47.87 47.42 -0.45 -0.012 0.77495E+03 180 ferroactinolite 38.45 34.62 -3.83 -0.104 0.65449E+04 181 troilite-low -4.41 -7.98 -3.57 -1.189 0.60919E+04 183 vesuvianite 223.47 218.82 -4.65 -0.036 0.79428E+04 187 wairakite 3.95 1.95 -2.00 -0.118 0.34154E+04 188 walstromite 11.51 9.94 -1.56 -0.313 0.26719E+04 189 wollastonite 10.46 9.94 -0.52 -0.103 0.88229E+03 190 pseudo-wollastonite 11.00 9.94 -1.06 -0.211 0.18021E+04 191 zoisite 22.85 18.95 -3.90 -0.177 0.66607E+04 192 akaganeite 7.75 4.49 -3.26 -0.705 0.55681E+04 199 chalcedony -2.80 -3.16 -0.35 -0.118 0.60613E+03 201 montmorillonite-Ca -2.29 -6.17 -3.88 -0.240 0.66180E+04 202 montmorillonite-K -2.24 -6.27 -4.03 -0.247 0.68816E+04 203 montmorillonite-Mg -2.48 -6.79 -4.32 -0.267 0.73677E+04 204 montmorillonite-Na -2.04 -5.57 -3.54 -0.216 0.60365E+04 205 nontronite-Ca 3.21 -0.19 -3.41 -0.221 0.58216E+04 206 nontronite-H 2.53 -2.36 -4.89 -0.328 0.83486E+04 207 nontronite-K 3.34 -0.30 -3.64 -0.233 0.62084E+04 208 nontronite-Mg 3.07 -0.82 -3.90 -0.253 0.66554E+04 209 nontronite-Na 3.52 0.40 -3.12 -0.200 0.53293E+04 224 tobermorite 9.82 7.76 -2.07 -0.564 0.35287E+04 230 alabandite -0.98 -5.47 -4.50 -1.499 0.76762E+04 233 boehmite 4.41 0.74 -3.67 -0.611 0.62618E+04 235 ferrous-oxide 9.81 6.73 -3.08 -0.769 0.52532E+04 240 silica-amorphous -2.09 -3.16 -1.07 -0.355 0.18203E+04 242 an20ab80 2.02 1.35 -0.67 -0.052 0.11472E+04 243 an25ab75 2.65 1.78 -0.87 -0.067 0.14810E+04 244 an30ab70 3.28 2.21 -1.07 -0.082 0.18243E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 40.0000000 g Current total amount of reactant added: 1799.9990000 g New total amount of reactant added: 1839.9990000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.3297E-10 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 11 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 1839.9990000 Water: Moles liquid = 0.4517E+02 kg liquid = 0.8137E+00 Moles total = 0.3244E+02 kg total = 0.5845E+00 Activity = 1.0000 Stoichiometric ionic strength = .1134376E-01 Osmotic coef. = 0.9692 True ionic strength = .2002840E-01 Chg. balance for total moles = 0.3297E-10 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.88337E-10 -10.0539 0.74223E-10 -10.1295 0.84022E+00 -0.0756 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.16879E-03 -3.7726 0.14097E-03 -3.8509 0.83517E+00 -0.0782 4 SO4-- 0.79539E-12 -12.0994 0.41299E-12 -12.3841 0.51924E+00 -0.2846 5 HCO3- 0.29432E-06 -6.5312 0.24617E-06 -6.6088 0.83639E+00 -0.0776 6 HS- 0.31338E-04 -4.5039 0.26177E-04 -4.5821 0.83529E+00 -0.0782 7 Al+++ 0.97071E-29 -29.0129 0.22420E-29 -29.6494 0.23096E+00 -0.6365 8 H4SiO4 0.69595E-03 -3.1574 0.69595E-03 -3.1574 0.10000E+01 0.0000 9 Ca++ 0.13513E-06 -6.8692 0.69650E-07 -7.1571 0.51543E+00 -0.2878 10 Mg++ 0.21140E-10 -10.6749 0.10846E-10 -10.9647 0.51307E+00 -0.2898 11 Fe++ 0.58265E-13 -13.2346 0.29927E-13 -13.5239 0.51363E+00 -0.2893 12 K+ 0.15659E-03 -3.8052 0.13100E-03 -3.8827 0.83659E+00 -0.0775 13 Na+ 0.19871E-01 -1.7018 0.16592E-01 -1.7801 0.83502E+00 -0.0783 14 Mn++ 0.18634E-10 -10.7297 0.95791E-11 -11.0187 0.51406E+00 -0.2890 15 HPO4-- 0.45282E-07 -7.3441 0.23515E-07 -7.6286 0.51931E+00 -0.2846 16 HSiO3- 0.10483E-01 -1.9795 0.87553E-02 -2.0577 0.83517E+00 -0.0782 17 Ca(HSiO3)+ 0.16597E-07 -7.7800 0.13888E-07 -7.8574 0.83677E+00 -0.0774 18 Mg(HSiO3)+ 0.32165E-11 -11.4926 0.26915E-11 -11.5700 0.83677E+00 -0.0774 19 NaHSiO3,aq 0.23496E-02 -2.6290 0.23496E-02 -2.6290 0.10000E+01 0.0000 20 AlO+ 0.66165E-16 -16.1794 0.55365E-16 -16.2568 0.83677E+00 -0.0774 22 HAlO2,aq 0.14855E-09 -9.8281 0.14855E-09 -9.8281 0.10000E+01 0.0000 23 AlO2- 0.53142E-05 -5.2746 0.44303E-05 -5.3536 0.83366E+00 -0.0790 24 CH4,aq 0.15209E-04 -4.8179 0.15156E-04 -4.8194 0.99654E+00 -0.0015 25 C2H6,aq 0.34021E-14 -14.4683 0.33903E-14 -14.4698 0.99654E+00 -0.0015 29 CO,aq 0.11361E-16 -16.9446 0.11361E-16 -16.9446 0.10000E+01 0.0000 30 CO2,aq 0.39177E-10 -10.4070 0.39042E-10 -10.4085 0.99654E+00 -0.0015 31 CO3-2 0.55911E-06 -6.2525 0.28970E-06 -6.5381 0.51814E+00 -0.2856 32 CaCO3,aq 0.25300E-09 -9.5969 0.25300E-09 -9.5969 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.52304E-12 -12.2815 0.43766E-12 -12.3589 0.83677E+00 -0.0774 34 CaCl+ 0.18989E-10 -10.7215 0.15890E-10 -10.7989 0.83677E+00 -0.0774 35 CaCl2,aq 0.53216E-15 -15.2740 0.53216E-15 -15.2740 0.10000E+01 0.0000 36 CaOH+ 0.79925E-07 -7.0973 0.66879E-07 -7.1747 0.83677E+00 -0.0774 37 CaSO4,aq 0.91343E-17 -17.0393 0.91343E-17 -17.0393 0.10000E+01 0.0000 38 HCl,aq 0.19173E-14 -14.7173 0.19173E-14 -14.7173 0.10000E+01 0.0000 43 FeCl+ 0.79802E-17 -17.0980 0.66776E-17 -17.1754 0.83677E+00 -0.0774 46 FeO,aq 0.21113E-09 -9.6755 0.21113E-09 -9.6755 0.10000E+01 0.0000 47 FeOH+ 0.15685E-10 -10.8045 0.13125E-10 -10.8819 0.83677E+00 -0.0774 48 HFeO2- 0.35636E-07 -7.4481 0.29763E-07 -7.5263 0.83517E+00 -0.0782 49 FeO+ 0.10992E-16 -16.9589 0.91979E-17 -17.0363 0.83677E+00 -0.0774 51 FeO2- 0.40906E-09 -9.3882 0.34164E-09 -9.4664 0.83517E+00 -0.0782 52 HFeO2,aq 0.32250E-11 -11.4915 0.32250E-11 -11.4915 0.10000E+01 0.0000 53 H2,aq 0.11624E-04 -4.9347 0.11584E-04 -4.9362 0.99654E+00 -0.0015 54 KCl,aq 0.33471E-09 -9.4753 0.33471E-09 -9.4753 0.10000E+01 0.0000 56 KOH,aq 0.75375E-06 -6.1228 0.75375E-06 -6.1228 0.10000E+01 0.0000 57 KSO4- 0.10053E-14 -14.9977 0.83956E-15 -15.0759 0.83517E+00 -0.0782 58 MgCO3,aq 0.98757E-14 -14.0054 0.98757E-14 -14.0054 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.83229E-16 -16.0797 0.69643E-16 -16.1571 0.83677E+00 -0.0774 60 MgCl+ 0.26802E-14 -14.5718 0.22427E-14 -14.6492 0.83677E+00 -0.0774 61 MgOH+ 0.68873E-10 -10.1620 0.57631E-10 -10.2393 0.83677E+00 -0.0774 63 MnO,aq 0.18007E-08 -8.7446 0.18007E-08 -8.7446 0.10000E+01 0.0000 64 MnOH+ 0.46639E-09 -9.3313 0.39026E-09 -9.4086 0.83677E+00 -0.0774 65 MnO2-2 0.20936E-10 -10.6791 0.10848E-10 -10.9647 0.51814E+00 -0.2856 66 HMnO2- 0.21121E-09 -9.6753 0.17639E-09 -9.7535 0.83517E+00 -0.0782 69 MnCl+ 0.99376E-14 -14.0027 0.83155E-14 -14.0801 0.83677E+00 -0.0774 71 NaCl,aq 0.77516E-06 -6.1106 0.77516E-06 -6.1106 0.10000E+01 0.0000 72 NaOH,aq 0.96047E-04 -4.0175 0.96047E-04 -4.0175 0.10000E+01 0.0000 74 OH- 0.93375E-02 -2.0298 0.77843E-02 -2.1088 0.83366E+00 -0.0790 79 HPO3-2 0.16383E-14 -14.7856 0.84886E-15 -15.0712 0.51814E+00 -0.2856 81 H2PO3- 0.15128E-18 -18.8202 0.12634E-18 -18.8984 0.83517E+00 -0.0782 82 H3PO4,aq 0.90605E-18 -18.0428 0.90605E-18 -18.0428 0.10000E+01 0.0000 83 H2PO4- 0.38516E-10 -10.4144 0.32198E-10 -10.4922 0.83596E+00 -0.0778 84 PO4-3 0.10656E-08 -8.9724 0.25849E-09 -9.5876 0.24258E+00 -0.6151 88 HP2O7-3 0.94587E-18 -18.0242 0.21868E-18 -18.6602 0.23119E+00 -0.6360 89 P2O7-4 0.91329E-17 -17.0394 0.70385E-18 -18.1525 0.77068E-01 -1.1131 90 H2S,aq 0.60257E-08 -8.2200 0.60048E-08 -8.2215 0.99654E+00 -0.0015 91 S2-2 0.25298E-14 -14.5969 0.13108E-14 -14.8825 0.51814E+00 -0.2856 97 SO3-2 0.11827E-17 -17.9271 0.62167E-18 -18.2064 0.52563E+00 -0.2793 99 HSO4- 0.35270E-19 -19.4526 0.29541E-19 -19.5296 0.83759E+00 -0.0770 Charge balance for all species = 0.4052E-10 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.8833702E-10 -.2229196E-01 -.2242990E+02 0.0000 2 H2O 0.1000000E+01 0.5550489E+02 0.9981990E+06 0.0000 3 Cl- 0.1687921E-03 0.1695676E-03 0.6001231E+01 6.2786 4 SO4-- 0.7953851E-12 -.1811494E-04 -.1737125E+01 7.8749 5 HCO3- 0.2943243E-06 0.1606278E-04 0.9784021E+00 3.5207 6 HS- 0.3133848E-04 0.4945944E-04 0.1632879E+01 5.5474 7 Al+++ 0.9707134E-29 0.5314354E-05 0.1431400E+00 0.7390 8 H4SiO4 0.6959540E-03 0.1352873E-01 0.1298059E+04 -3.1574 9 Ca++ 0.1351310E-06 0.2319247E-06 0.9278918E-02 13.1018 10 Mg++ 0.2114038E-10 0.9324193E-10 0.2262957E-05 9.2942 11 Fe++ 0.5826511E-13 0.3627565E-07 0.2022364E-02 6.7350 12 K+ 0.1565916E-03 0.1573457E-03 0.6141837E+01 6.2467 13 Na+ 0.1987070E-01 0.2231708E-01 0.5121733E+03 8.3494 14 Mn++ 0.1863443E-10 0.2517880E-08 0.1380868E-03 9.2402 15 HPO4-- 0.4528175E-07 0.4638585E-07 0.4444328E-02 12.6303 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.3046764E+02 -.1813857E-01 -.3044950E+02 0.0000000E+00 2 H2O 0.3244311E+02 0.4516335E+02 -.1272024E+02 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.5101815E-01 -.1473981E-04 0.5103289E-01 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.5099264E-01 0.4024428E-04 -.5103289E-01 0.0000000E+00 7 Al+++ 0.5999761E+01 0.4324196E-05 0.5999757E+01 0.0000000E+00 8 H4SiO4 0.1915951E+02 0.1100809E-01 0.1914850E+02 0.0000000E+00 9 Ca++ 0.2116276E+01 0.1887130E-06 0.2116276E+01 0.0000000E+00 10 Mg++ 0.1460317E+01 0.7586931E-10 0.1460317E+01 0.0000000E+00 11 Fe++ 0.1311935E+01 0.2951685E-07 0.1311935E+01 0.0000000E+00 12 K+ 0.3906580E+00 0.1280294E-03 0.3905299E+00 0.0000000E+00 13 Na+ 0.2309807E+01 0.1815901E-01 0.2291648E+01 0.0000000E+00 14 Mn++ 0.3190300E-01 0.2048754E-08 0.3190300E-01 0.0000000E+00 15 HPO4-- 0.1088834E-01 0.3774334E-07 0.1088830E-01 0.0000000E+00 Chg. balance for solid moles: -.3962E-14 Mass of aqueous solution: 0.815099E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 1839.9990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 2.290 0.360 600.4 2.778 29.87 230.5 andradite 0.2041 -0.690 103.7 2.016 5.161 26.95 grossular 0.4944E-01 -1.306 22.27 1.348 1.108 6.196 apatite-OH 0.3629E-02 -2.440 1.823 0.261 0.9070E-01 0.5793 clinochlore 0.2622 -0.581 145.7 2.164 7.251 55.44 daphnite 0.7590E-01 -1.120 54.16 1.734 2.694 16.41 chlorite-Mn 0.6381E-02 -2.195 4.524 0.655 0.2251 1.442 diopside 0.9082E-01 -1.042 19.67 1.294 0.9785 6.011 hedenbergite 0.2355E-01 -1.628 5.843 0.767 0.2907 1.600 microcline 0.3425 -0.465 95.33 1.979 4.743 37.24 stilbite 1.191 0.076 839.2 2.924 41.75 391.4 stilpnomelane-Fe 0.9609E-01 -1.017 103.6 2.015 5.153 35.78 tr.625ac.25prg.125 0.1614E-01 -1.792 13.79 1.140 0.6861 4.439 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8050E+00 0.8050E+00 1.0000 -0.094 grossular 0.1950E+00 0.1950E+00 1.0000 -0.710 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.7611E+00 0.7611E+00 1.0000 -0.119 daphnite 0.2203E+00 0.2203E+00 1.0000 -0.657 chlorite-Mn 0.1852E-01 0.1852E-01 1.0000 -1.732 diopside 0.7941E+00 0.7941E+00 1.0000 -0.100 hedenbergite 0.2059E+00 0.2059E+00 1.0000 -0.686 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 tr.625ac.25prg.125 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 2010.016864 g Volume = 813.961030 cm3 Porosity: -10.4425% V(tot) - V(min): -.76961E+02 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 1839.9990000 g log = 3.2648 Original solution: 1000.0103000 g Original solution / Rock added: 0.54 (Water/Rock Ratio), log = -0.2648 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0581 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9648E+00 0.9854 0.1006E+01 0.1021E+01 CO2,gas 0.3921E-08 1.0069 0.4177E-08 0.4148E-08 CH4,gas 0.2083E-01 1.0124 0.2231E-01 0.2204E-01 H2,gas 0.1437E-01 1.0006 0.1521E-01 0.1520E-01 H2S,gas 0.1567E-06 0.9959 0.1651E-06 0.1657E-06 S2,gas 0.4180E-29 1.0000 0.4422E-29 0.4422E-29 CO,gas 0.1600E-13 1.0000 0.1693E-13 0.1693E-13 SO3,gas 0.8131E-48 1.0000 0.8603E-48 0.8603E-48 SO2,gas 0.4811E-27 1.0000 0.5090E-27 0.5090E-27 HCl,gas 0.3198E-17 1.0000 0.3383E-17 0.3383E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 16 albite -0.38 -0.38 0.00 0.000 0.11184E-10 22 andradite 39.01 39.01 0.00 0.000 0.12132E-10 23 grossular 32.73 32.73 0.00 0.000 -0.12132E-10 32 apatite-OH -18.15 -18.15 0.00 0.000 0.12132E-10 46 clinochlore 39.07 39.07 0.00 0.000 0.36397E-10 47 daphnite 28.97 28.97 0.00 0.000 0.54595E-10 48 chlorite-Mn 46.87 46.87 0.00 0.000 0.36397E-10 67 diopside 16.18 16.18 0.00 0.000 0.12132E-10 68 hedenbergite 14.21 14.21 0.00 0.000 0.90992E-11 116 microcline -2.49 -2.49 0.00 0.000 0.15165E-11 163 stilbite -7.52 -7.52 0.00 0.000 0.15165E-10 164 stilpnomelane-Fe 13.02 13.02 0.00 0.000 0.69761E-10 245 tr.625ac.25prg.125 45.16 45.16 0.00 0.000 -0.12132E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -16.74 -10.08 -3.359 0.17208E+05 -8.379 3 CH4,gas 4.54 1.19 -3.35 -0.838 0.57209E+04 -1.652 4 H2,gas 8.00 4.48 -3.52 -2.010 0.60050E+04 -1.818 5 H2S,gas -6.23 -14.71 -8.48 -4.241 0.14482E+05 -6.782 6 S2,gas -7.34 -38.39 -31.05 -4.777 0.53023E+05 -29.354 7 CO,gas 3.21 -12.26 -15.47 -4.760 0.26415E+05 -13.771 8 SO3,gas 17.12 -32.64 -49.76 -12.441 0.84971E+05 -48.065 9 SO2,gas 0.83 -28.16 -28.99 -7.731 0.49504E+05 -27.293 10 HCl,gas 5.19 -13.98 -19.17 -9.585 0.32732E+05 -17.471 11 acmite 7.71 6.53 -1.18 -0.123 0.20176E+04 15 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 19 spessartine 24.46 19.73 -4.73 -0.237 0.80777E+04 20 analcite 3.32 2.77 -0.55 -0.061 0.93622E+03 26 annite 20.12 17.72 -2.40 -0.134 0.41064E+04 27 phlogopite 27.06 25.40 -1.67 -0.093 0.28488E+04 29 anorthite 12.71 8.27 -4.45 -0.342 0.75902E+04 35 aragonite 0.97 -3.64 -4.60 -1.534 0.78593E+04 36 brucite 12.57 9.29 -3.27 -0.655 0.55909E+04 37 calcite 0.81 -3.64 -4.45 -1.483 0.75951E+04 38 carnegieite-low 9.02 5.93 -3.09 -0.442 0.52801E+04 39 carnegieite-high 10.09 5.93 -4.16 -0.595 0.71071E+04 40 carpholite-Mg 8.58 4.46 -4.12 -0.275 0.70428E+04 41 carpholite-Fe 6.71 1.90 -4.81 -0.321 0.82206E+04 42 celadonite 5.34 3.65 -1.69 -0.099 0.28879E+04 43 celadonite-Fe 3.88 1.09 -2.79 -0.164 0.47561E+04 44 chrysotile 23.89 21.57 -2.32 -0.194 0.39692E+04 49 chlorite-Al-free 47.17 43.14 -4.04 -0.168 0.68935E+04 51 chloritoid-Fe 9.17 5.06 -4.12 -0.275 0.70314E+04 52 chloritoid-Mn 11.40 7.56 -3.84 -0.256 0.65570E+04 54 coesite -2.38 -3.16 -0.78 -0.260 0.13341E+04 61 cristobalite -2.56 -3.16 -0.60 -0.199 0.10195E+04 63 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71234E+04 65 diaspore 2.87 0.74 -2.13 -0.356 0.36449E+04 66 diamond -3.10 -7.77 -4.67 -1.334 0.79741E+04 71 enstatite 17.26 12.27 -4.99 -0.499 0.85225E+04 73 clinoenstatite 17.17 12.27 -4.89 -0.489 0.83541E+04 75 epidote 24.67 22.70 -1.97 -0.095 0.33584E+04 76 clinozoisite 22.81 18.95 -3.86 -0.175 0.65866E+04 77 epidote-Fe 29.84 26.46 -3.38 -0.176 0.57768E+04 78 fayalite 14.05 10.31 -3.73 -0.533 0.63743E+04 79 ferrosilite 11.15 7.16 -3.99 -0.399 0.68202E+04 83 gibbsite 4.08 0.74 -3.34 -0.477 0.57035E+04 84 glaucophane 22.97 20.80 -2.17 -0.059 0.37133E+04 85 glaucophane-Fe 17.28 13.12 -4.15 -0.112 0.70919E+04 86 graphite -3.55 -7.77 -4.23 -1.208 0.72163E+04 87 greenalite 16.14 13.89 -2.25 -0.187 0.38408E+04 90 hematite 12.57 8.99 -3.58 -0.434 0.61112E+04 91 heulandite -5.83 -7.52 -1.69 -0.077 0.28938E+04 95 jadeite 4.22 2.77 -1.44 -0.144 0.24617E+04 97 kalsilite 7.58 3.83 -3.76 -0.537 0.64125E+04 98 kaolinite -1.33 -4.84 -3.50 -0.319 0.59830E+04 101 laumontite 2.88 1.95 -0.93 -0.062 0.15934E+04 102 lawsonite 9.62 8.27 -1.35 -0.090 0.23068E+04 103 leucite 4.12 0.67 -3.45 -0.345 0.58873E+04 105 lizardite 23.24 21.57 -1.68 -0.140 0.28618E+04 107 magnetite 20.09 15.72 -4.37 -0.356 0.74536E+04 108 minnesotaite 10.39 7.58 -2.81 -0.165 0.48028E+04 112 manganosite 14.06 9.24 -4.82 -1.204 0.82264E+04 120 muscovite 2.58 -1.01 -3.59 -0.211 0.61313E+04 121 paragonite 4.24 1.09 -3.15 -0.185 0.53704E+04 122 nepheline 8.34 5.93 -2.41 -0.344 0.41124E+04 128 periclase-Fe 11.63 6.73 -4.89 -1.223 0.83523E+04 134 phlogopite-Na 29.65 27.50 -2.15 -0.119 0.36677E+04 136 prehnite 19.37 18.21 -1.16 -0.068 0.19848E+04 137 prehnite-Fe 22.50 21.96 -0.53 -0.032 0.91155E+03 138 pumpellyite-Fe 46.27 43.89 -2.38 -0.053 0.40578E+04 139 pumpellyite-Mg 48.99 46.45 -2.54 -0.057 0.43416E+04 143 pyrrhotite -4.26 -7.98 -3.72 -1.239 0.63454E+04 144 pyrrhotiteFe0.875 -6.02 -9.37 -3.36 -1.235 0.57326E+04 145 pyroxmangite 7.40 6.08 -1.32 -0.263 0.22468E+04 146 pyrophyllite -6.18 -11.15 -4.98 -0.311 0.84961E+04 147 quartz -2.99 -3.16 -0.17 -0.056 0.28683E+03 152 rhodonite 7.45 6.08 -1.36 -0.273 0.23270E+04 153 sanidine -1.28 -2.49 -1.21 -0.093 0.20677E+04 165 stilpnomelane-Mg 27.44 25.81 -1.63 -0.049 0.27803E+04 171 talc 16.49 15.25 -1.24 -0.073 0.21140E+04 174 tephroite 18.09 15.32 -2.76 -0.395 0.47173E+04 178 tridymite -2.63 -3.16 -0.53 -0.177 0.90681E+03 179 tremolite 47.87 47.42 -0.45 -0.012 0.77495E+03 180 ferroactinolite 38.45 34.62 -3.83 -0.104 0.65449E+04 181 troilite-low -4.41 -7.98 -3.57 -1.189 0.60882E+04 183 vesuvianite 223.47 218.82 -4.65 -0.036 0.79429E+04 187 wairakite 3.95 1.95 -2.00 -0.118 0.34154E+04 188 walstromite 11.51 9.94 -1.56 -0.313 0.26719E+04 189 wollastonite 10.46 9.94 -0.52 -0.103 0.88229E+03 190 pseudo-wollastonite 11.00 9.94 -1.06 -0.211 0.18021E+04 191 zoisite 22.85 18.95 -3.90 -0.177 0.66607E+04 192 akaganeite 7.75 4.49 -3.26 -0.705 0.55681E+04 199 chalcedony -2.80 -3.16 -0.35 -0.118 0.60613E+03 201 montmorillonite-Ca -2.29 -6.17 -3.88 -0.240 0.66180E+04 202 montmorillonite-K -2.24 -6.27 -4.03 -0.247 0.68816E+04 203 montmorillonite-Mg -2.48 -6.79 -4.32 -0.267 0.73677E+04 204 montmorillonite-Na -2.04 -5.57 -3.54 -0.216 0.60365E+04 205 nontronite-Ca 3.21 -0.19 -3.41 -0.221 0.58216E+04 206 nontronite-H 2.53 -2.36 -4.89 -0.328 0.83486E+04 207 nontronite-K 3.34 -0.30 -3.64 -0.233 0.62084E+04 208 nontronite-Mg 3.07 -0.82 -3.90 -0.253 0.66554E+04 209 nontronite-Na 3.52 0.40 -3.12 -0.200 0.53293E+04 224 tobermorite 9.82 7.76 -2.07 -0.564 0.35287E+04 230 alabandite -0.98 -5.47 -4.49 -1.498 0.76724E+04 233 boehmite 4.41 0.74 -3.67 -0.611 0.62618E+04 235 ferrous-oxide 9.81 6.73 -3.08 -0.769 0.52532E+04 240 silica-amorphous -2.09 -3.16 -1.07 -0.355 0.18203E+04 242 an20ab80 2.02 1.35 -0.67 -0.052 0.11472E+04 243 an25ab75 2.65 1.78 -0.87 -0.067 0.14810E+04 244 an30ab70 3.28 2.21 -1.07 -0.082 0.18243E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 40.0000000 g Current total amount of reactant added: 1839.9990000 g New total amount of reactant added: 1879.9990000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.3297E-10 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 11 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 1879.9990000 Water: Moles liquid = 0.4494E+02 kg liquid = 0.8097E+00 Moles total = 0.3194E+02 kg total = 0.5754E+00 Activity = 1.0000 Stoichiometric ionic strength = .1134446E-01 Osmotic coef. = 0.9692 True ionic strength = .2002895E-01 Chg. balance for total moles = 0.3297E-10 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.88339E-10 -10.0538 0.74225E-10 -10.1295 0.84022E+00 -0.0756 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.16963E-03 -3.7705 0.14167E-03 -3.8487 0.83517E+00 -0.0782 4 SO4-- 0.79932E-12 -12.0973 0.41504E-12 -12.3819 0.51924E+00 -0.2846 5 HCO3- 0.29578E-06 -6.5290 0.24739E-06 -6.6066 0.83639E+00 -0.0776 6 HS- 0.31494E-04 -4.5018 0.26307E-04 -4.5799 0.83529E+00 -0.0782 7 Al+++ 0.97080E-29 -29.0129 0.22421E-29 -29.6493 0.23096E+00 -0.6365 8 H4SiO4 0.69595E-03 -3.1574 0.69595E-03 -3.1574 0.10000E+01 0.0000 9 Ca++ 0.13514E-06 -6.8692 0.69654E-07 -7.1571 0.51542E+00 -0.2878 10 Mg++ 0.21142E-10 -10.6749 0.10847E-10 -10.9647 0.51306E+00 -0.2898 11 Fe++ 0.58268E-13 -13.2346 0.29928E-13 -13.5239 0.51363E+00 -0.2894 12 K+ 0.15660E-03 -3.8052 0.13101E-03 -3.8827 0.83659E+00 -0.0775 13 Na+ 0.19871E-01 -1.7018 0.16593E-01 -1.7801 0.83502E+00 -0.0783 14 Mn++ 0.18637E-10 -10.7296 0.95806E-11 -11.0186 0.51405E+00 -0.2890 15 HPO4-- 0.45280E-07 -7.3441 0.23514E-07 -7.6287 0.51931E+00 -0.2846 16 HSiO3- 0.10483E-01 -1.9795 0.87550E-02 -2.0577 0.83517E+00 -0.0782 17 Ca(HSiO3)+ 0.16597E-07 -7.7800 0.13888E-07 -7.8574 0.83677E+00 -0.0774 18 Mg(HSiO3)+ 0.32166E-11 -11.4926 0.26915E-11 -11.5700 0.83677E+00 -0.0774 19 NaHSiO3,aq 0.23496E-02 -2.6290 0.23496E-02 -2.6290 0.10000E+01 0.0000 20 AlO+ 0.66166E-16 -16.1794 0.55366E-16 -16.2568 0.83677E+00 -0.0774 22 HAlO2,aq 0.14855E-09 -9.8281 0.14855E-09 -9.8281 0.10000E+01 0.0000 23 AlO2- 0.53141E-05 -5.2746 0.44301E-05 -5.3536 0.83366E+00 -0.0790 24 CH4,aq 0.15285E-04 -4.8157 0.15232E-04 -4.8173 0.99654E+00 -0.0015 25 C2H6,aq 0.34359E-14 -14.4640 0.34240E-14 -14.4655 0.99654E+00 -0.0015 29 CO,aq 0.11417E-16 -16.9424 0.11417E-16 -16.9424 0.10000E+01 0.0000 30 CO2,aq 0.39372E-10 -10.4048 0.39236E-10 -10.4063 0.99654E+00 -0.0015 31 CO3-2 0.56187E-06 -6.2504 0.29112E-06 -6.5359 0.51813E+00 -0.2856 32 CaCO3,aq 0.25426E-09 -9.5947 0.25426E-09 -9.5947 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.52565E-12 -12.2793 0.43985E-12 -12.3567 0.83677E+00 -0.0774 34 CaCl+ 0.19084E-10 -10.7193 0.15969E-10 -10.7967 0.83677E+00 -0.0774 35 CaCl2,aq 0.53748E-15 -15.2696 0.53748E-15 -15.2696 0.10000E+01 0.0000 36 CaOH+ 0.79927E-07 -7.0973 0.66880E-07 -7.1747 0.83677E+00 -0.0774 37 CaSO4,aq 0.91799E-17 -17.0372 0.91799E-17 -17.0372 0.10000E+01 0.0000 38 HCl,aq 0.19269E-14 -14.7151 0.19269E-14 -14.7151 0.10000E+01 0.0000 43 FeCl+ 0.80202E-17 -17.0958 0.67111E-17 -17.1732 0.83677E+00 -0.0774 46 FeO,aq 0.21113E-09 -9.6755 0.21113E-09 -9.6755 0.10000E+01 0.0000 47 FeOH+ 0.15685E-10 -10.8045 0.13125E-10 -10.8819 0.83677E+00 -0.0774 48 HFeO2- 0.35636E-07 -7.4481 0.29762E-07 -7.5263 0.83517E+00 -0.0782 49 FeO+ 0.10992E-16 -16.9589 0.91982E-17 -17.0363 0.83677E+00 -0.0774 51 FeO2- 0.40905E-09 -9.3882 0.34163E-09 -9.4664 0.83517E+00 -0.0782 52 HFeO2,aq 0.32250E-11 -11.4915 0.32250E-11 -11.4915 0.10000E+01 0.0000 53 H2,aq 0.11624E-04 -4.9347 0.11584E-04 -4.9362 0.99654E+00 -0.0015 54 KCl,aq 0.33638E-09 -9.4732 0.33638E-09 -9.4732 0.10000E+01 0.0000 56 KOH,aq 0.75375E-06 -6.1228 0.75375E-06 -6.1228 0.10000E+01 0.0000 57 KSO4- 0.10103E-14 -14.9956 0.84373E-15 -15.0738 0.83517E+00 -0.0782 58 MgCO3,aq 0.99248E-14 -14.0033 0.99248E-14 -14.0033 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.83645E-16 -16.0776 0.69991E-16 -16.1550 0.83677E+00 -0.0774 60 MgCl+ 0.26936E-14 -14.5697 0.22539E-14 -14.6471 0.83677E+00 -0.0774 61 MgOH+ 0.68874E-10 -10.1619 0.57632E-10 -10.2393 0.83677E+00 -0.0774 63 MnO,aq 0.18009E-08 -8.7445 0.18009E-08 -8.7445 0.10000E+01 0.0000 64 MnOH+ 0.46645E-09 -9.3312 0.39031E-09 -9.4086 0.83677E+00 -0.0774 65 MnO2-2 0.20937E-10 -10.6791 0.10848E-10 -10.9646 0.51813E+00 -0.2856 66 HMnO2- 0.21122E-09 -9.6753 0.17641E-09 -9.7535 0.83517E+00 -0.0782 69 MnCl+ 0.99884E-14 -14.0005 0.83580E-14 -14.0779 0.83677E+00 -0.0774 71 NaCl,aq 0.77903E-06 -6.1084 0.77903E-06 -6.1084 0.10000E+01 0.0000 72 NaOH,aq 0.96047E-04 -4.0175 0.96047E-04 -4.0175 0.10000E+01 0.0000 74 OH- 0.93373E-02 -2.0298 0.77841E-02 -2.1088 0.83366E+00 -0.0790 79 HPO3-2 0.16382E-14 -14.7856 0.84882E-15 -15.0712 0.51813E+00 -0.2856 81 H2PO3- 0.15128E-18 -18.8202 0.12634E-18 -18.8985 0.83517E+00 -0.0782 82 H3PO4,aq 0.90605E-18 -18.0428 0.90605E-18 -18.0428 0.10000E+01 0.0000 83 H2PO4- 0.38515E-10 -10.4144 0.32197E-10 -10.4922 0.83596E+00 -0.0778 84 PO4-3 0.10655E-08 -8.9724 0.25847E-09 -9.5876 0.24258E+00 -0.6151 88 HP2O7-3 0.94582E-18 -18.0242 0.21866E-18 -18.6602 0.23119E+00 -0.6360 89 P2O7-4 0.91322E-17 -17.0394 0.70378E-18 -18.1526 0.77065E-01 -1.1131 90 H2S,aq 0.60557E-08 -8.2178 0.60348E-08 -8.2193 0.99654E+00 -0.0015 91 S2-2 0.25549E-14 -14.5926 0.13238E-14 -14.8782 0.51813E+00 -0.2856 97 SO3-2 0.11886E-17 -17.9250 0.62474E-18 -18.2043 0.52563E+00 -0.2793 99 HSO4- 0.35445E-19 -19.4504 0.29688E-19 -19.5274 0.83758E+00 -0.0770 Charge balance for all species = 0.4073E-10 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.8833941E-10 -.2229151E-01 -.2242944E+02 0.0000 2 H2O 0.1000000E+01 0.5550489E+02 0.9981990E+06 0.0000 3 Cl- 0.1696295E-03 0.1704089E-03 0.6031005E+01 6.2807 4 SO4-- 0.7993244E-12 -.1819041E-04 -.1744362E+01 7.8770 5 HCO3- 0.2957814E-06 0.1614247E-04 0.9832563E+00 3.5228 6 HS- 0.3149396E-04 0.4969043E-04 0.1640505E+01 5.5495 7 Al+++ 0.9707997E-29 0.5314209E-05 0.1431361E+00 0.7390 8 H4SiO4 0.6959548E-03 0.1352850E-01 0.1298036E+04 -3.1574 9 Ca++ 0.1351387E-06 0.2319362E-06 0.9279381E-02 13.1018 10 Mg++ 0.2114158E-10 0.9324546E-10 0.2263043E-05 9.2942 11 Fe++ 0.5826848E-13 0.3627478E-07 0.2022316E-02 6.7350 12 K+ 0.1565959E-03 0.1573500E-03 0.6142004E+01 6.2467 13 Na+ 0.1987124E-01 0.2231763E-01 0.5121859E+03 8.3494 14 Mn++ 0.1863742E-10 0.2518145E-08 0.1381014E-03 9.2403 15 HPO4-- 0.4527986E-07 0.4638390E-07 0.4444141E-02 12.6302 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.3112998E+02 -.1804866E-01 -.3111193E+02 0.0000000E+00 2 H2O 0.3194169E+02 0.4494038E+02 -.1299869E+02 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.5212669E-01 -.1472814E-04 0.5214141E-01 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.5210118E-01 0.4023261E-04 -.5214141E-01 0.0000000E+00 7 Al+++ 0.6130191E+01 0.4302731E-05 0.6130187E+01 0.0000000E+00 8 H4SiO4 0.1957602E+02 0.1095355E-01 0.1956507E+02 0.0000000E+00 9 Ca++ 0.2162282E+01 0.1877907E-06 0.2162281E+01 0.0000000E+00 10 Mg++ 0.1492063E+01 0.7549761E-10 0.1492063E+01 0.0000000E+00 11 Fe++ 0.1340455E+01 0.2937043E-07 0.1340455E+01 0.0000000E+00 12 K+ 0.3991505E+00 0.1274008E-03 0.3990231E+00 0.0000000E+00 13 Na+ 0.2360017E+01 0.1806981E-01 0.2341947E+01 0.0000000E+00 14 Mn++ 0.3259654E-01 0.2038855E-08 0.3259654E-01 0.0000000E+00 15 HPO4-- 0.1112504E-01 0.3755543E-07 0.1112500E-01 0.0000000E+00 Chg. balance for solid moles: 0.6675E-14 Mass of aqueous solution: 0.811075E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 1879.9990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 2.340 0.369 613.6 2.788 29.88 235.5 andradite 0.2086 -0.681 106.0 2.025 5.161 27.54 grossular 0.5051E-01 -1.297 22.75 1.357 1.108 6.330 apatite-OH 0.3708E-02 -2.431 1.863 0.270 0.9070E-01 0.5919 clinochlore 0.2679 -0.572 148.9 2.173 7.250 56.63 daphnite 0.7755E-01 -1.110 55.33 1.743 2.694 16.77 chlorite-Mn 0.6519E-02 -2.186 4.622 0.665 0.2251 1.473 diopside 0.9299E-01 -1.032 20.14 1.304 0.9806 6.155 hedenbergite 0.2412E-01 -1.618 5.983 0.777 0.2913 1.639 microcline 0.3499 -0.456 97.40 1.989 4.743 38.05 stilbite 1.216 0.085 857.3 2.933 41.74 399.8 stilpnomelane-Fe 0.9818E-01 -1.008 105.8 2.025 5.153 36.56 tr.625ac.25prg.125 0.1647E-01 -1.783 14.08 1.149 0.6854 4.531 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8050E+00 0.8050E+00 1.0000 -0.094 grossular 0.1950E+00 0.1950E+00 1.0000 -0.710 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.7611E+00 0.7611E+00 1.0000 -0.119 daphnite 0.2203E+00 0.2203E+00 1.0000 -0.657 chlorite-Mn 0.1852E-01 0.1852E-01 1.0000 -1.732 diopside 0.7941E+00 0.7941E+00 1.0000 -0.100 hedenbergite 0.2059E+00 0.2059E+00 1.0000 -0.686 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 tr.625ac.25prg.125 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 2053.717130 g Volume = 831.642256 cm3 Porosity: -10.4439% V(tot) - V(min): -.78643E+02 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 1879.9990000 g log = 3.2742 Original solution: 1000.0103000 g Original solution / Rock added: 0.53 (Water/Rock Ratio), log = -0.2742 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0582 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9647E+00 0.9854 0.1006E+01 0.1021E+01 CO2,gas 0.3940E-08 1.0069 0.4198E-08 0.4169E-08 CH4,gas 0.2093E-01 1.0124 0.2242E-01 0.2214E-01 H2,gas 0.1436E-01 1.0006 0.1521E-01 0.1520E-01 H2S,gas 0.1574E-06 0.9959 0.1659E-06 0.1666E-06 S2,gas 0.4221E-29 1.0000 0.4466E-29 0.4466E-29 CO,gas 0.1608E-13 1.0000 0.1701E-13 0.1701E-13 SO3,gas 0.8170E-48 1.0000 0.8646E-48 0.8646E-48 SO2,gas 0.4834E-27 1.0000 0.5115E-27 0.5115E-27 HCl,gas 0.3213E-17 1.0000 0.3400E-17 0.3400E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 16 albite -0.38 -0.38 0.00 0.000 -0.94784E-12 22 andradite 39.01 39.01 0.00 0.000 0.00000E+00 23 grossular 32.73 32.73 0.00 0.000 0.00000E+00 32 apatite-OH -18.15 -18.15 0.00 0.000 0.12132E-10 46 clinochlore 39.07 39.07 0.00 0.000 -0.12132E-10 47 daphnite 28.97 28.97 0.00 0.000 0.12132E-10 48 chlorite-Mn 46.87 46.87 0.00 0.000 -0.12132E-10 67 diopside 16.18 16.18 0.00 0.000 0.60662E-11 68 hedenbergite 14.21 14.21 0.00 0.000 -0.30331E-11 116 microcline -2.49 -2.49 0.00 0.000 0.15165E-11 163 stilbite -7.52 -7.52 0.00 0.000 0.15165E-10 164 stilpnomelane-Fe 13.02 13.02 0.00 0.000 0.21232E-10 245 tr.625ac.25prg.125 45.16 45.16 0.00 0.000 -0.48529E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -16.74 -10.08 -3.359 0.17204E+05 -8.377 3 CH4,gas 4.54 1.20 -3.35 -0.837 0.57172E+04 -1.649 4 H2,gas 8.00 4.48 -3.52 -2.010 0.60050E+04 -1.818 5 H2S,gas -6.23 -14.71 -8.48 -4.240 0.14478E+05 -6.780 6 S2,gas -7.34 -38.38 -31.05 -4.777 0.53015E+05 -29.350 7 CO,gas 3.21 -12.25 -15.47 -4.759 0.26411E+05 -13.769 8 SO3,gas 17.12 -32.64 -49.76 -12.441 0.84968E+05 -48.063 9 SO2,gas 0.83 -28.16 -28.99 -7.731 0.49500E+05 -27.291 10 HCl,gas 5.19 -13.98 -19.17 -9.584 0.32728E+05 -17.469 11 acmite 7.71 6.53 -1.18 -0.123 0.20176E+04 15 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 19 spessartine 24.46 19.73 -4.73 -0.237 0.80775E+04 20 analcite 3.32 2.77 -0.55 -0.061 0.93622E+03 26 annite 20.12 17.72 -2.40 -0.134 0.41064E+04 27 phlogopite 27.06 25.40 -1.67 -0.093 0.28488E+04 29 anorthite 12.71 8.27 -4.45 -0.342 0.75902E+04 35 aragonite 0.97 -3.63 -4.60 -1.534 0.78556E+04 36 brucite 12.57 9.29 -3.27 -0.655 0.55909E+04 37 calcite 0.81 -3.63 -4.45 -1.482 0.75914E+04 38 carnegieite-low 9.02 5.93 -3.09 -0.442 0.52801E+04 39 carnegieite-high 10.09 5.93 -4.16 -0.595 0.71071E+04 40 carpholite-Mg 8.58 4.46 -4.12 -0.275 0.70428E+04 41 carpholite-Fe 6.71 1.90 -4.81 -0.321 0.82206E+04 42 celadonite 5.34 3.65 -1.69 -0.099 0.28879E+04 43 celadonite-Fe 3.88 1.09 -2.79 -0.164 0.47561E+04 44 chrysotile 23.89 21.57 -2.32 -0.194 0.39692E+04 49 chlorite-Al-free 47.17 43.14 -4.04 -0.168 0.68935E+04 51 chloritoid-Fe 9.17 5.06 -4.12 -0.275 0.70314E+04 52 chloritoid-Mn 11.40 7.56 -3.84 -0.256 0.65570E+04 54 coesite -2.38 -3.16 -0.78 -0.260 0.13341E+04 61 cristobalite -2.56 -3.16 -0.60 -0.199 0.10195E+04 63 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71234E+04 65 diaspore 2.87 0.74 -2.13 -0.356 0.36449E+04 66 diamond -3.10 -7.77 -4.67 -1.334 0.79704E+04 71 enstatite 17.26 12.27 -4.99 -0.499 0.85225E+04 73 clinoenstatite 17.17 12.27 -4.89 -0.489 0.83541E+04 75 epidote 24.67 22.70 -1.97 -0.095 0.33584E+04 76 clinozoisite 22.81 18.95 -3.86 -0.175 0.65867E+04 77 epidote-Fe 29.84 26.46 -3.38 -0.176 0.57768E+04 78 fayalite 14.05 10.31 -3.73 -0.533 0.63743E+04 79 ferrosilite 11.15 7.16 -3.99 -0.399 0.68202E+04 83 gibbsite 4.08 0.74 -3.34 -0.477 0.57035E+04 84 glaucophane 22.97 20.80 -2.17 -0.059 0.37133E+04 85 glaucophane-Fe 17.28 13.12 -4.15 -0.112 0.70919E+04 86 graphite -3.55 -7.77 -4.22 -1.207 0.72127E+04 87 greenalite 16.14 13.89 -2.25 -0.187 0.38408E+04 90 hematite 12.57 8.99 -3.58 -0.434 0.61112E+04 91 heulandite -5.83 -7.52 -1.69 -0.077 0.28938E+04 95 jadeite 4.22 2.77 -1.44 -0.144 0.24617E+04 97 kalsilite 7.58 3.83 -3.76 -0.537 0.64125E+04 98 kaolinite -1.33 -4.84 -3.50 -0.319 0.59830E+04 101 laumontite 2.88 1.95 -0.93 -0.062 0.15934E+04 102 lawsonite 9.62 8.27 -1.35 -0.090 0.23068E+04 103 leucite 4.12 0.67 -3.45 -0.345 0.58873E+04 105 lizardite 23.24 21.57 -1.68 -0.140 0.28618E+04 107 magnetite 20.09 15.72 -4.37 -0.356 0.74536E+04 108 minnesotaite 10.39 7.58 -2.81 -0.165 0.48028E+04 112 manganosite 14.06 9.24 -4.82 -1.204 0.82263E+04 120 muscovite 2.58 -1.01 -3.59 -0.211 0.61313E+04 121 paragonite 4.24 1.09 -3.15 -0.185 0.53705E+04 122 nepheline 8.34 5.93 -2.41 -0.344 0.41124E+04 128 periclase-Fe 11.63 6.73 -4.89 -1.223 0.83523E+04 134 phlogopite-Na 29.65 27.50 -2.15 -0.119 0.36677E+04 136 prehnite 19.37 18.21 -1.16 -0.068 0.19848E+04 137 prehnite-Fe 22.50 21.96 -0.53 -0.032 0.91155E+03 138 pumpellyite-Fe 46.27 43.89 -2.38 -0.053 0.40578E+04 139 pumpellyite-Mg 48.99 46.45 -2.54 -0.057 0.43416E+04 143 pyrrhotite -4.26 -7.97 -3.71 -1.238 0.63417E+04 144 pyrrhotiteFe0.875 -6.02 -9.37 -3.36 -1.234 0.57289E+04 145 pyroxmangite 7.40 6.08 -1.32 -0.263 0.22467E+04 146 pyrophyllite -6.18 -11.15 -4.98 -0.311 0.84961E+04 147 quartz -2.99 -3.16 -0.17 -0.056 0.28683E+03 152 rhodonite 7.45 6.08 -1.36 -0.273 0.23269E+04 153 sanidine -1.28 -2.49 -1.21 -0.093 0.20677E+04 165 stilpnomelane-Mg 27.44 25.81 -1.63 -0.049 0.27803E+04 171 talc 16.49 15.25 -1.24 -0.073 0.21140E+04 174 tephroite 18.09 15.32 -2.76 -0.395 0.47171E+04 178 tridymite -2.63 -3.16 -0.53 -0.177 0.90680E+03 179 tremolite 47.87 47.42 -0.45 -0.012 0.77495E+03 180 ferroactinolite 38.45 34.62 -3.83 -0.104 0.65449E+04 181 troilite-low -4.41 -7.97 -3.56 -1.188 0.60845E+04 183 vesuvianite 223.47 218.82 -4.65 -0.036 0.79429E+04 187 wairakite 3.95 1.95 -2.00 -0.118 0.34154E+04 188 walstromite 11.51 9.94 -1.56 -0.313 0.26719E+04 189 wollastonite 10.46 9.94 -0.52 -0.103 0.88229E+03 190 pseudo-wollastonite 11.00 9.94 -1.06 -0.211 0.18021E+04 191 zoisite 22.85 18.95 -3.90 -0.177 0.66607E+04 192 akaganeite 7.75 4.49 -3.26 -0.705 0.55681E+04 199 chalcedony -2.80 -3.16 -0.35 -0.118 0.60612E+03 201 montmorillonite-Ca -2.29 -6.17 -3.88 -0.240 0.66180E+04 202 montmorillonite-K -2.24 -6.27 -4.03 -0.247 0.68816E+04 203 montmorillonite-Mg -2.48 -6.79 -4.32 -0.267 0.73678E+04 204 montmorillonite-Na -2.04 -5.57 -3.54 -0.216 0.60365E+04 205 nontronite-Ca 3.21 -0.19 -3.41 -0.221 0.58216E+04 206 nontronite-H 2.53 -2.36 -4.89 -0.328 0.83486E+04 207 nontronite-K 3.34 -0.30 -3.64 -0.233 0.62084E+04 208 nontronite-Mg 3.07 -0.82 -3.90 -0.253 0.66554E+04 209 nontronite-Na 3.52 0.40 -3.12 -0.200 0.53293E+04 224 tobermorite 9.82 7.76 -2.07 -0.564 0.35287E+04 230 alabandite -0.98 -5.47 -4.49 -1.497 0.76686E+04 233 boehmite 4.41 0.74 -3.67 -0.611 0.62618E+04 235 ferrous-oxide 9.81 6.73 -3.08 -0.769 0.52532E+04 240 silica-amorphous -2.09 -3.16 -1.07 -0.355 0.18203E+04 242 an20ab80 2.02 1.35 -0.67 -0.052 0.11472E+04 243 an25ab75 2.65 1.78 -0.87 -0.067 0.14810E+04 244 an30ab70 3.28 2.21 -1.07 -0.082 0.18243E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 40.0000000 g Current total amount of reactant added: 1879.9990000 g New total amount of reactant added: 1919.9990000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.3297E-10 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 11 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 1919.9990000 Water: Moles liquid = 0.4472E+02 kg liquid = 0.8056E+00 Moles total = 0.3144E+02 kg total = 0.5664E+00 Activity = 1.0000 Stoichiometric ionic strength = .1134517E-01 Osmotic coef. = 0.9692 True ionic strength = .2002950E-01 Chg. balance for total moles = 0.3297E-10 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.88342E-10 -10.0538 0.74227E-10 -10.1294 0.84022E+00 -0.0756 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.17048E-03 -3.7683 0.14238E-03 -3.8466 0.83517E+00 -0.0782 4 SO4-- 0.80330E-12 -12.0951 0.41710E-12 -12.3798 0.51923E+00 -0.2846 5 HCO3- 0.29725E-06 -6.5269 0.24862E-06 -6.6045 0.83639E+00 -0.0776 6 HS- 0.31651E-04 -4.4996 0.26438E-04 -4.5778 0.83529E+00 -0.0782 7 Al+++ 0.97089E-29 -29.0128 0.22423E-29 -29.6493 0.23095E+00 -0.6365 8 H4SiO4 0.69596E-03 -3.1574 0.69596E-03 -3.1574 0.10000E+01 0.0000 9 Ca++ 0.13515E-06 -6.8692 0.69657E-07 -7.1570 0.51542E+00 -0.2878 10 Mg++ 0.21143E-10 -10.6748 0.10848E-10 -10.9647 0.51306E+00 -0.2898 11 Fe++ 0.58272E-13 -13.2345 0.29930E-13 -13.5239 0.51362E+00 -0.2894 12 K+ 0.15660E-03 -3.8052 0.13101E-03 -3.8827 0.83659E+00 -0.0775 13 Na+ 0.19872E-01 -1.7018 0.16593E-01 -1.7801 0.83502E+00 -0.0783 14 Mn++ 0.18640E-10 -10.7295 0.95820E-11 -11.0185 0.51405E+00 -0.2890 15 HPO4-- 0.45278E-07 -7.3441 0.23513E-07 -7.6287 0.51931E+00 -0.2846 16 HSiO3- 0.10483E-01 -1.9795 0.87548E-02 -2.0578 0.83517E+00 -0.0782 17 Ca(HSiO3)+ 0.16598E-07 -7.7800 0.13888E-07 -7.8574 0.83677E+00 -0.0774 18 Mg(HSiO3)+ 0.32167E-11 -11.4926 0.26916E-11 -11.5700 0.83677E+00 -0.0774 19 NaHSiO3,aq 0.23496E-02 -2.6290 0.23496E-02 -2.6290 0.10000E+01 0.0000 20 AlO+ 0.66168E-16 -16.1794 0.55367E-16 -16.2567 0.83677E+00 -0.0774 22 HAlO2,aq 0.14855E-09 -9.8281 0.14855E-09 -9.8281 0.10000E+01 0.0000 23 AlO2- 0.53139E-05 -5.2746 0.44300E-05 -5.3536 0.83366E+00 -0.0790 24 CH4,aq 0.15361E-04 -4.8136 0.15308E-04 -4.8151 0.99654E+00 -0.0015 25 C2H6,aq 0.34703E-14 -14.4596 0.34583E-14 -14.4611 0.99654E+00 -0.0015 29 CO,aq 0.11474E-16 -16.9403 0.11474E-16 -16.9403 0.10000E+01 0.0000 30 CO2,aq 0.39569E-10 -10.4026 0.39432E-10 -10.4041 0.99654E+00 -0.0015 31 CO3-2 0.56465E-06 -6.2482 0.29256E-06 -6.5338 0.51813E+00 -0.2856 32 CaCO3,aq 0.25553E-09 -9.5926 0.25553E-09 -9.5926 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.52830E-12 -12.2771 0.44206E-12 -12.3545 0.83677E+00 -0.0774 34 CaCl+ 0.19180E-10 -10.7171 0.16050E-10 -10.7945 0.83677E+00 -0.0774 35 CaCl2,aq 0.54288E-15 -15.2653 0.54288E-15 -15.2653 0.10000E+01 0.0000 36 CaOH+ 0.79929E-07 -7.0973 0.66882E-07 -7.1747 0.83677E+00 -0.0774 37 CaSO4,aq 0.92260E-17 -17.0350 0.92260E-17 -17.0350 0.10000E+01 0.0000 38 HCl,aq 0.19366E-14 -14.7130 0.19366E-14 -14.7130 0.10000E+01 0.0000 43 FeCl+ 0.80606E-17 -17.0936 0.67449E-17 -17.1710 0.83677E+00 -0.0774 46 FeO,aq 0.21113E-09 -9.6755 0.21113E-09 -9.6755 0.10000E+01 0.0000 47 FeOH+ 0.15686E-10 -10.8045 0.13125E-10 -10.8819 0.83677E+00 -0.0774 48 HFeO2- 0.35635E-07 -7.4481 0.29761E-07 -7.5264 0.83517E+00 -0.0782 49 FeO+ 0.10993E-16 -16.9589 0.91984E-17 -17.0363 0.83677E+00 -0.0774 51 FeO2- 0.40904E-09 -9.3882 0.34162E-09 -9.4665 0.83517E+00 -0.0782 52 HFeO2,aq 0.32251E-11 -11.4915 0.32251E-11 -11.4915 0.10000E+01 0.0000 53 H2,aq 0.11624E-04 -4.9347 0.11583E-04 -4.9362 0.99654E+00 -0.0015 54 KCl,aq 0.33806E-09 -9.4710 0.33806E-09 -9.4710 0.10000E+01 0.0000 56 KOH,aq 0.75375E-06 -6.1228 0.75375E-06 -6.1228 0.10000E+01 0.0000 57 KSO4- 0.10153E-14 -14.9934 0.84795E-15 -15.0716 0.83517E+00 -0.0782 58 MgCO3,aq 0.99744E-14 -14.0011 0.99744E-14 -14.0011 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.84065E-16 -16.0754 0.70343E-16 -16.1528 0.83677E+00 -0.0774 60 MgCl+ 0.27072E-14 -14.5675 0.22653E-14 -14.6449 0.83677E+00 -0.0774 61 MgOH+ 0.68876E-10 -10.1619 0.57633E-10 -10.2393 0.83677E+00 -0.0774 63 MnO,aq 0.18011E-08 -8.7445 0.18011E-08 -8.7445 0.10000E+01 0.0000 64 MnOH+ 0.46651E-09 -9.3311 0.39036E-09 -9.4085 0.83677E+00 -0.0774 65 MnO2-2 0.20938E-10 -10.6791 0.10849E-10 -10.9646 0.51813E+00 -0.2856 66 HMnO2- 0.21124E-09 -9.6752 0.17642E-09 -9.7534 0.83517E+00 -0.0782 69 MnCl+ 0.10040E-13 -13.9983 0.84009E-14 -14.0757 0.83677E+00 -0.0774 71 NaCl,aq 0.78293E-06 -6.1063 0.78293E-06 -6.1063 0.10000E+01 0.0000 72 NaOH,aq 0.96047E-04 -4.0175 0.96047E-04 -4.0175 0.10000E+01 0.0000 74 OH- 0.93370E-02 -2.0298 0.77839E-02 -2.1088 0.83366E+00 -0.0790 79 HPO3-2 0.16382E-14 -14.7856 0.84878E-15 -15.0712 0.51813E+00 -0.2856 81 H2PO3- 0.15127E-18 -18.8202 0.12634E-18 -18.8985 0.83517E+00 -0.0782 82 H3PO4,aq 0.90605E-18 -18.0428 0.90605E-18 -18.0428 0.10000E+01 0.0000 83 H2PO4- 0.38514E-10 -10.4144 0.32196E-10 -10.4922 0.83596E+00 -0.0778 84 PO4-3 0.10655E-08 -8.9725 0.25845E-09 -9.5876 0.24258E+00 -0.6152 88 HP2O7-3 0.94576E-18 -18.0242 0.21865E-18 -18.6603 0.23119E+00 -0.6360 89 P2O7-4 0.91316E-17 -17.0395 0.70371E-18 -18.1526 0.77063E-01 -1.1132 90 H2S,aq 0.60861E-08 -8.2157 0.60650E-08 -8.2172 0.99654E+00 -0.0015 91 S2-2 0.25805E-14 -14.5883 0.13370E-14 -14.8739 0.51813E+00 -0.2856 97 SO3-2 0.11945E-17 -17.9228 0.62785E-18 -18.2021 0.52563E+00 -0.2793 99 HSO4- 0.35622E-19 -19.4483 0.29837E-19 -19.5253 0.83758E+00 -0.0770 Charge balance for all species = 0.4091E-10 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.8834183E-10 -.2229105E-01 -.2242899E+02 0.0000 2 H2O 0.1000000E+01 0.5550489E+02 0.9981990E+06 0.0000 3 Cl- 0.1704753E-03 0.1712586E-03 0.6061076E+01 6.2829 4 SO4-- 0.8033025E-12 -.1826663E-04 -.1751672E+01 7.8791 5 HCO3- 0.2972527E-06 0.1622296E-04 0.9881589E+00 3.5250 6 HS- 0.3165099E-04 0.4992371E-04 0.1648207E+01 5.5517 7 Al+++ 0.9708871E-29 0.5314064E-05 0.1431322E+00 0.7390 8 H4SiO4 0.6959557E-03 0.1352826E-01 0.1298014E+04 -3.1574 9 Ca++ 0.1351464E-06 0.2319479E-06 0.9279848E-02 13.1018 10 Mg++ 0.2114280E-10 0.9324819E-10 0.2263109E-05 9.2942 11 Fe++ 0.5827187E-13 0.3627391E-07 0.2022267E-02 6.7350 12 K+ 0.1566002E-03 0.1573543E-03 0.6142171E+01 6.2467 13 Na+ 0.1987179E-01 0.2231818E-01 0.5121986E+03 8.3494 14 Mn++ 0.1864034E-10 0.2518400E-08 0.1381153E-03 9.2403 15 HPO4-- 0.4527796E-07 0.4638193E-07 0.4443952E-02 12.6302 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.3179232E+02 -.1795875E-01 -.3177436E+02 0.0000000E+00 2 H2O 0.3144027E+02 0.4471742E+02 -.1327714E+02 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.5323522E-01 -.1471648E-04 0.5324994E-01 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.5320972E-01 0.4022095E-04 -.5324994E-01 0.0000000E+00 7 Al+++ 0.6260621E+01 0.4281267E-05 0.6260616E+01 0.0000000E+00 8 H4SiO4 0.1999253E+02 0.1089902E-01 0.1998163E+02 0.0000000E+00 9 Ca++ 0.2208287E+01 0.1868684E-06 0.2208287E+01 0.0000000E+00 10 Mg++ 0.1523809E+01 0.7512524E-10 0.1523809E+01 0.0000000E+00 11 Fe++ 0.1368976E+01 0.2922401E-07 0.1368976E+01 0.0000000E+00 12 K+ 0.4076431E+00 0.1267722E-03 0.4075163E+00 0.0000000E+00 13 Na+ 0.2410227E+01 0.1798060E-01 0.2392246E+01 0.0000000E+00 14 Mn++ 0.3329009E-01 0.2028944E-08 0.3329008E-01 0.0000000E+00 15 HPO4-- 0.1136174E-01 0.3736752E-07 0.1136170E-01 0.0000000E+00 Chg. balance for solid moles: 0.4056E-14 Mass of aqueous solution: 0.807051E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 1919.9990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 2.390 0.378 626.7 2.797 29.88 240.6 andradite 0.2130 -0.672 108.2 2.034 5.161 28.12 grossular 0.5158E-01 -1.287 23.24 1.366 1.108 6.465 apatite-OH 0.3787E-02 -2.422 1.902 0.279 0.9070E-01 0.6045 clinochlore 0.2735 -0.563 152.0 2.182 7.249 57.83 daphnite 0.7919E-01 -1.101 56.50 1.752 2.694 17.12 chlorite-Mn 0.6658E-02 -2.177 4.720 0.674 0.2251 1.504 diopside 0.9517E-01 -1.021 20.61 1.314 0.9826 6.299 hedenbergite 0.2468E-01 -1.608 6.123 0.787 0.2919 1.677 microcline 0.3574 -0.447 99.47 1.998 4.743 38.86 stilbite 1.242 0.094 875.4 2.942 41.74 408.3 stilpnomelane-Fe 0.1003 -0.999 108.1 2.034 5.154 37.34 tr.625ac.25prg.125 0.1680E-01 -1.775 14.36 1.157 0.6847 4.622 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8050E+00 0.8050E+00 1.0000 -0.094 grossular 0.1950E+00 0.1950E+00 1.0000 -0.710 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.7611E+00 0.7611E+00 1.0000 -0.119 daphnite 0.2203E+00 0.2203E+00 1.0000 -0.657 chlorite-Mn 0.1853E-01 0.1853E-01 1.0000 -1.732 diopside 0.7941E+00 0.7941E+00 1.0000 -0.100 hedenbergite 0.2059E+00 0.2059E+00 1.0000 -0.686 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 tr.625ac.25prg.125 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 2097.417395 g Volume = 849.323481 cm3 Porosity: -10.4452% V(tot) - V(min): -.80324E+02 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 1919.9990000 g log = 3.2833 Original solution: 1000.0103000 g Original solution / Rock added: 0.52 (Water/Rock Ratio), log = -0.2833 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0583 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9646E+00 0.9854 0.1006E+01 0.1021E+01 CO2,gas 0.3959E-08 1.0069 0.4219E-08 0.4190E-08 CH4,gas 0.2103E-01 1.0124 0.2253E-01 0.2226E-01 H2,gas 0.1436E-01 1.0006 0.1521E-01 0.1520E-01 H2S,gas 0.1582E-06 0.9959 0.1667E-06 0.1674E-06 S2,gas 0.4263E-29 1.0000 0.4511E-29 0.4511E-29 CO,gas 0.1616E-13 1.0000 0.1710E-13 0.1710E-13 SO3,gas 0.8211E-48 1.0000 0.8689E-48 0.8689E-48 SO2,gas 0.4858E-27 1.0000 0.5141E-27 0.5141E-27 HCl,gas 0.3229E-17 1.0000 0.3417E-17 0.3417E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 16 albite -0.38 -0.38 0.00 0.000 0.11184E-10 22 andradite 39.01 39.01 0.00 0.000 0.12132E-10 23 grossular 32.73 32.73 0.00 0.000 -0.12132E-10 32 apatite-OH -18.15 -18.15 0.00 0.000 0.60662E-11 46 clinochlore 39.07 39.07 0.00 0.000 0.48529E-10 47 daphnite 28.97 28.97 0.00 0.000 0.24265E-10 48 chlorite-Mn 46.87 46.87 0.00 0.000 0.36397E-10 67 diopside 16.18 16.18 0.00 0.000 0.60662E-11 68 hedenbergite 14.21 14.21 0.00 0.000 0.90992E-11 116 microcline -2.49 -2.49 0.00 0.000 0.13649E-10 163 stilbite -7.52 -7.52 0.00 0.000 0.39430E-10 164 stilpnomelane-Fe 13.02 13.02 0.00 0.000 0.21232E-10 245 tr.625ac.25prg.125 45.16 45.16 0.00 0.000 -0.24265E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -16.73 -10.07 -3.358 0.17201E+05 -8.375 3 CH4,gas 4.54 1.20 -3.35 -0.837 0.57135E+04 -1.647 4 H2,gas 8.00 4.48 -3.52 -2.010 0.60050E+04 -1.818 5 H2S,gas -6.23 -14.71 -8.48 -4.238 0.14474E+05 -6.778 6 S2,gas -7.34 -38.38 -31.04 -4.776 0.53008E+05 -29.346 7 CO,gas 3.21 -12.25 -15.47 -4.759 0.26408E+05 -13.767 8 SO3,gas 17.12 -32.64 -49.76 -12.440 0.84964E+05 -48.061 9 SO2,gas 0.83 -28.16 -28.99 -7.730 0.49496E+05 -27.289 10 HCl,gas 5.19 -13.98 -19.17 -9.583 0.32724E+05 -17.466 11 acmite 7.71 6.53 -1.18 -0.123 0.20176E+04 15 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 19 spessartine 24.46 19.73 -4.73 -0.237 0.80773E+04 20 analcite 3.32 2.77 -0.55 -0.061 0.93622E+03 26 annite 20.12 17.72 -2.40 -0.134 0.41064E+04 27 phlogopite 27.06 25.40 -1.67 -0.093 0.28488E+04 29 anorthite 12.71 8.27 -4.45 -0.342 0.75902E+04 35 aragonite 0.97 -3.63 -4.60 -1.533 0.78520E+04 36 brucite 12.57 9.29 -3.27 -0.655 0.55909E+04 37 calcite 0.81 -3.63 -4.44 -1.481 0.75877E+04 38 carnegieite-low 9.02 5.93 -3.09 -0.442 0.52801E+04 39 carnegieite-high 10.09 5.93 -4.16 -0.595 0.71071E+04 40 carpholite-Mg 8.58 4.46 -4.12 -0.275 0.70428E+04 41 carpholite-Fe 6.71 1.90 -4.81 -0.321 0.82206E+04 42 celadonite 5.34 3.65 -1.69 -0.099 0.28879E+04 43 celadonite-Fe 3.88 1.09 -2.79 -0.164 0.47561E+04 44 chrysotile 23.89 21.57 -2.32 -0.194 0.39692E+04 49 chlorite-Al-free 47.17 43.14 -4.04 -0.168 0.68935E+04 51 chloritoid-Fe 9.17 5.06 -4.12 -0.275 0.70314E+04 52 chloritoid-Mn 11.40 7.56 -3.84 -0.256 0.65569E+04 54 coesite -2.38 -3.16 -0.78 -0.260 0.13341E+04 61 cristobalite -2.56 -3.16 -0.60 -0.199 0.10195E+04 63 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71234E+04 65 diaspore 2.87 0.74 -2.13 -0.356 0.36449E+04 66 diamond -3.10 -7.77 -4.67 -1.333 0.79667E+04 71 enstatite 17.26 12.27 -4.99 -0.499 0.85225E+04 73 clinoenstatite 17.17 12.27 -4.89 -0.489 0.83541E+04 75 epidote 24.67 22.70 -1.97 -0.095 0.33584E+04 76 clinozoisite 22.81 18.95 -3.86 -0.175 0.65867E+04 77 epidote-Fe 29.84 26.46 -3.38 -0.176 0.57768E+04 78 fayalite 14.05 10.31 -3.73 -0.533 0.63743E+04 79 ferrosilite 11.15 7.16 -3.99 -0.399 0.68202E+04 83 gibbsite 4.08 0.74 -3.34 -0.477 0.57035E+04 84 glaucophane 22.97 20.80 -2.17 -0.059 0.37133E+04 85 glaucophane-Fe 17.28 13.12 -4.15 -0.112 0.70919E+04 86 graphite -3.55 -7.77 -4.22 -1.206 0.72090E+04 87 greenalite 16.14 13.89 -2.25 -0.187 0.38408E+04 90 hematite 12.57 8.99 -3.58 -0.434 0.61112E+04 91 heulandite -5.83 -7.52 -1.69 -0.077 0.28938E+04 95 jadeite 4.22 2.77 -1.44 -0.144 0.24617E+04 97 kalsilite 7.58 3.83 -3.76 -0.537 0.64125E+04 98 kaolinite -1.33 -4.84 -3.50 -0.319 0.59830E+04 101 laumontite 2.88 1.95 -0.93 -0.062 0.15934E+04 102 lawsonite 9.62 8.27 -1.35 -0.090 0.23069E+04 103 leucite 4.12 0.67 -3.45 -0.345 0.58873E+04 105 lizardite 23.24 21.57 -1.68 -0.140 0.28618E+04 107 magnetite 20.09 15.72 -4.37 -0.356 0.74536E+04 108 minnesotaite 10.39 7.58 -2.81 -0.165 0.48028E+04 112 manganosite 14.06 9.24 -4.82 -1.204 0.82262E+04 120 muscovite 2.58 -1.01 -3.59 -0.211 0.61314E+04 121 paragonite 4.24 1.09 -3.15 -0.185 0.53705E+04 122 nepheline 8.34 5.93 -2.41 -0.344 0.41124E+04 128 periclase-Fe 11.63 6.73 -4.89 -1.223 0.83523E+04 134 phlogopite-Na 29.65 27.50 -2.15 -0.119 0.36677E+04 136 prehnite 19.37 18.21 -1.16 -0.068 0.19848E+04 137 prehnite-Fe 22.50 21.96 -0.53 -0.032 0.91155E+03 138 pumpellyite-Fe 46.27 43.89 -2.38 -0.053 0.40578E+04 139 pumpellyite-Mg 48.99 46.45 -2.54 -0.057 0.43416E+04 143 pyrrhotite -4.26 -7.97 -3.71 -1.237 0.63380E+04 144 pyrrhotiteFe0.875 -6.02 -9.37 -3.35 -1.233 0.57252E+04 145 pyroxmangite 7.40 6.08 -1.32 -0.263 0.22466E+04 146 pyrophyllite -6.18 -11.15 -4.98 -0.311 0.84961E+04 147 quartz -2.99 -3.16 -0.17 -0.056 0.28683E+03 152 rhodonite 7.45 6.08 -1.36 -0.273 0.23269E+04 153 sanidine -1.28 -2.49 -1.21 -0.093 0.20677E+04 165 stilpnomelane-Mg 27.44 25.81 -1.63 -0.049 0.27803E+04 171 talc 16.49 15.25 -1.24 -0.073 0.21140E+04 174 tephroite 18.09 15.32 -2.76 -0.395 0.47170E+04 178 tridymite -2.63 -3.16 -0.53 -0.177 0.90680E+03 179 tremolite 47.87 47.42 -0.45 -0.012 0.77495E+03 180 ferroactinolite 38.45 34.62 -3.83 -0.104 0.65449E+04 181 troilite-low -4.41 -7.97 -3.56 -1.187 0.60808E+04 183 vesuvianite 223.47 218.82 -4.65 -0.036 0.79429E+04 187 wairakite 3.95 1.95 -2.00 -0.118 0.34154E+04 188 walstromite 11.51 9.94 -1.56 -0.313 0.26719E+04 189 wollastonite 10.46 9.94 -0.52 -0.103 0.88229E+03 190 pseudo-wollastonite 11.00 9.94 -1.06 -0.211 0.18021E+04 191 zoisite 22.85 18.95 -3.90 -0.177 0.66607E+04 192 akaganeite 7.75 4.49 -3.26 -0.705 0.55681E+04 199 chalcedony -2.80 -3.16 -0.35 -0.118 0.60612E+03 201 montmorillonite-Ca -2.29 -6.17 -3.88 -0.240 0.66180E+04 202 montmorillonite-K -2.24 -6.27 -4.03 -0.247 0.68816E+04 203 montmorillonite-Mg -2.48 -6.79 -4.32 -0.267 0.73678E+04 204 montmorillonite-Na -2.04 -5.57 -3.54 -0.216 0.60365E+04 205 nontronite-Ca 3.21 -0.19 -3.41 -0.221 0.58216E+04 206 nontronite-H 2.53 -2.36 -4.89 -0.328 0.83486E+04 207 nontronite-K 3.34 -0.30 -3.64 -0.233 0.62084E+04 208 nontronite-Mg 3.07 -0.82 -3.90 -0.253 0.66554E+04 209 nontronite-Na 3.52 0.40 -3.12 -0.200 0.53293E+04 224 tobermorite 9.82 7.76 -2.07 -0.564 0.35287E+04 230 alabandite -0.98 -5.47 -4.49 -1.496 0.76649E+04 233 boehmite 4.41 0.74 -3.67 -0.611 0.62618E+04 235 ferrous-oxide 9.81 6.73 -3.08 -0.769 0.52532E+04 240 silica-amorphous -2.09 -3.16 -1.07 -0.355 0.18203E+04 242 an20ab80 2.02 1.35 -0.67 -0.052 0.11472E+04 243 an25ab75 2.65 1.78 -0.87 -0.067 0.14810E+04 244 an30ab70 3.28 2.21 -1.07 -0.082 0.18243E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 40.0000000 g Current total amount of reactant added: 1919.9990000 g New total amount of reactant added: 1959.9990000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.3298E-10 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 11 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 1959.9990000 Water: Moles liquid = 0.4450E+02 kg liquid = 0.8016E+00 Moles total = 0.3094E+02 kg total = 0.5574E+00 Activity = 1.0000 Stoichiometric ionic strength = .1134589E-01 Osmotic coef. = 0.9692 True ionic strength = .2003006E-01 Chg. balance for total moles = 0.3298E-10 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.88344E-10 -10.0538 0.74229E-10 -10.1294 0.84022E+00 -0.0756 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.17133E-03 -3.7662 0.14309E-03 -3.8444 0.83517E+00 -0.0782 4 SO4-- 0.80732E-12 -12.0930 0.41918E-12 -12.3776 0.51923E+00 -0.2846 5 HCO3- 0.29874E-06 -6.5247 0.24986E-06 -6.6023 0.83639E+00 -0.0776 6 HS- 0.31810E-04 -4.4974 0.26570E-04 -4.5756 0.83529E+00 -0.0782 7 Al+++ 0.97098E-29 -29.0128 0.22425E-29 -29.6493 0.23095E+00 -0.6365 8 H4SiO4 0.69596E-03 -3.1574 0.69596E-03 -3.1574 0.10000E+01 0.0000 9 Ca++ 0.13515E-06 -6.8692 0.69661E-07 -7.1570 0.51541E+00 -0.2878 10 Mg++ 0.21144E-10 -10.6748 0.10848E-10 -10.9646 0.51306E+00 -0.2898 11 Fe++ 0.58275E-13 -13.2345 0.29931E-13 -13.5239 0.51362E+00 -0.2894 12 K+ 0.15660E-03 -3.8052 0.13101E-03 -3.8827 0.83659E+00 -0.0775 13 Na+ 0.19872E-01 -1.7018 0.16594E-01 -1.7801 0.83501E+00 -0.0783 14 Mn++ 0.18643E-10 -10.7295 0.95834E-11 -11.0185 0.51404E+00 -0.2890 15 HPO4-- 0.45276E-07 -7.3441 0.23512E-07 -7.6287 0.51930E+00 -0.2846 16 HSiO3- 0.10482E-01 -1.9795 0.87546E-02 -2.0578 0.83517E+00 -0.0782 17 Ca(HSiO3)+ 0.16598E-07 -7.7799 0.13889E-07 -7.8573 0.83677E+00 -0.0774 18 Mg(HSiO3)+ 0.32168E-11 -11.4926 0.26917E-11 -11.5700 0.83677E+00 -0.0774 19 NaHSiO3,aq 0.23496E-02 -2.6290 0.23496E-02 -2.6290 0.10000E+01 0.0000 20 AlO+ 0.66169E-16 -16.1793 0.55368E-16 -16.2567 0.83677E+00 -0.0774 22 HAlO2,aq 0.14855E-09 -9.8281 0.14855E-09 -9.8281 0.10000E+01 0.0000 23 AlO2- 0.53138E-05 -5.2746 0.44299E-05 -5.3536 0.83366E+00 -0.0790 24 CH4,aq 0.15438E-04 -4.8114 0.15384E-04 -4.8129 0.99654E+00 -0.0015 25 C2H6,aq 0.35052E-14 -14.4553 0.34930E-14 -14.4568 0.99654E+00 -0.0015 29 CO,aq 0.11532E-16 -16.9381 0.11532E-16 -16.9381 0.10000E+01 0.0000 30 CO2,aq 0.39768E-10 -10.4005 0.39630E-10 -10.4020 0.99654E+00 -0.0015 31 CO3-2 0.56746E-06 -6.2461 0.29402E-06 -6.5316 0.51813E+00 -0.2856 32 CaCO3,aq 0.25681E-09 -9.5904 0.25681E-09 -9.5904 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.53096E-12 -12.2749 0.44429E-12 -12.3523 0.83677E+00 -0.0774 34 CaCl+ 0.19277E-10 -10.7149 0.16131E-10 -10.7923 0.83677E+00 -0.0774 35 CaCl2,aq 0.54836E-15 -15.2609 0.54836E-15 -15.2609 0.10000E+01 0.0000 36 CaOH+ 0.79931E-07 -7.0973 0.66883E-07 -7.1747 0.83677E+00 -0.0774 37 CaSO4,aq 0.92725E-17 -17.0328 0.92725E-17 -17.0328 0.10000E+01 0.0000 38 HCl,aq 0.19463E-14 -14.7108 0.19463E-14 -14.7108 0.10000E+01 0.0000 43 FeCl+ 0.81014E-17 -17.0914 0.67790E-17 -17.1688 0.83677E+00 -0.0774 46 FeO,aq 0.21113E-09 -9.6755 0.21113E-09 -9.6755 0.10000E+01 0.0000 47 FeOH+ 0.15686E-10 -10.8045 0.13126E-10 -10.8819 0.83677E+00 -0.0774 48 HFeO2- 0.35634E-07 -7.4481 0.29760E-07 -7.5264 0.83517E+00 -0.0782 49 FeO+ 0.10993E-16 -16.9589 0.91987E-17 -17.0363 0.83677E+00 -0.0774 51 FeO2- 0.40903E-09 -9.3882 0.34161E-09 -9.4665 0.83517E+00 -0.0782 52 HFeO2,aq 0.32251E-11 -11.4915 0.32251E-11 -11.4915 0.10000E+01 0.0000 53 H2,aq 0.11624E-04 -4.9347 0.11583E-04 -4.9362 0.99654E+00 -0.0015 54 KCl,aq 0.33977E-09 -9.4688 0.33977E-09 -9.4688 0.10000E+01 0.0000 56 KOH,aq 0.75375E-06 -6.1228 0.75375E-06 -6.1228 0.10000E+01 0.0000 57 KSO4- 0.10204E-14 -14.9912 0.85220E-15 -15.0695 0.83517E+00 -0.0782 58 MgCO3,aq 0.10024E-13 -13.9989 0.10024E-13 -13.9989 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.84490E-16 -16.0732 0.70698E-16 -16.1506 0.83677E+00 -0.0774 60 MgCl+ 0.27209E-14 -14.5653 0.22767E-14 -14.6427 0.83677E+00 -0.0774 61 MgOH+ 0.68878E-10 -10.1619 0.57635E-10 -10.2393 0.83677E+00 -0.0774 63 MnO,aq 0.18012E-08 -8.7444 0.18012E-08 -8.7444 0.10000E+01 0.0000 64 MnOH+ 0.46656E-09 -9.3311 0.39040E-09 -9.4085 0.83677E+00 -0.0774 65 MnO2-2 0.20939E-10 -10.6790 0.10849E-10 -10.9646 0.51813E+00 -0.2856 66 HMnO2- 0.21126E-09 -9.6752 0.17643E-09 -9.7534 0.83517E+00 -0.0782 69 MnCl+ 0.10092E-13 -13.9960 0.84442E-14 -14.0734 0.83677E+00 -0.0774 71 NaCl,aq 0.78687E-06 -6.1041 0.78687E-06 -6.1041 0.10000E+01 0.0000 72 NaOH,aq 0.96047E-04 -4.0175 0.96047E-04 -4.0175 0.10000E+01 0.0000 74 OH- 0.93368E-02 -2.0298 0.77837E-02 -2.1088 0.83366E+00 -0.0790 79 HPO3-2 0.16381E-14 -14.7857 0.84873E-15 -15.0712 0.51813E+00 -0.2856 81 H2PO3- 0.15127E-18 -18.8203 0.12633E-18 -18.8985 0.83517E+00 -0.0782 82 H3PO4,aq 0.90605E-18 -18.0428 0.90605E-18 -18.0428 0.10000E+01 0.0000 83 H2PO4- 0.38513E-10 -10.4144 0.32195E-10 -10.4922 0.83596E+00 -0.0778 84 PO4-3 0.10654E-08 -8.9725 0.25843E-09 -9.5877 0.24257E+00 -0.6152 88 HP2O7-3 0.94571E-18 -18.0242 0.21863E-18 -18.6603 0.23118E+00 -0.6360 89 P2O7-4 0.91309E-17 -17.0395 0.70364E-18 -18.1527 0.77061E-01 -1.1132 90 H2S,aq 0.61167E-08 -8.2135 0.60955E-08 -8.2150 0.99654E+00 -0.0015 91 S2-2 0.26064E-14 -14.5840 0.13505E-14 -14.8695 0.51813E+00 -0.2856 97 SO3-2 0.12004E-17 -17.9207 0.63098E-18 -18.2000 0.52562E+00 -0.2793 99 HSO4- 0.35801E-19 -19.4461 0.29986E-19 -19.5231 0.83758E+00 -0.0770 Charge balance for all species = 0.4113E-10 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.8834427E-10 -.2229059E-01 -.2242852E+02 0.0000 2 H2O 0.1000000E+01 0.5550489E+02 0.9981989E+06 0.0000 3 Cl- 0.1713296E-03 0.1721168E-03 0.6091449E+01 6.2850 4 SO4-- 0.8073200E-12 -.1834362E-04 -.1759055E+01 7.8813 5 HCO3- 0.2987386E-06 0.1630426E-04 0.9931106E+00 3.5271 6 HS- 0.3180960E-04 0.5015934E-04 0.1655986E+01 5.5538 7 Al+++ 0.9709754E-29 0.5313919E-05 0.1431283E+00 0.7390 8 H4SiO4 0.6959564E-03 0.1352802E-01 0.1297991E+04 -3.1574 9 Ca++ 0.1351543E-06 0.2319597E-06 0.9280321E-02 13.1018 10 Mg++ 0.2114403E-10 0.9325151E-10 0.2263189E-05 9.2942 11 Fe++ 0.5827530E-13 0.3627302E-07 0.2022218E-02 6.7350 12 K+ 0.1566045E-03 0.1573586E-03 0.6142341E+01 6.2467 13 Na+ 0.1987234E-01 0.2231874E-01 0.5122113E+03 8.3494 14 Mn++ 0.1864320E-10 0.2518644E-08 0.1381287E-03 9.2404 15 HPO4-- 0.4527603E-07 0.4637994E-07 0.4443761E-02 12.6301 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.3245466E+02 -.1786883E-01 -.3243679E+02 0.0000000E+00 2 H2O 0.3093886E+02 0.4449445E+02 -.1355559E+02 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.5434376E-01 -.1470482E-04 0.5435846E-01 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.5431825E-01 0.4020929E-04 -.5435846E-01 0.0000000E+00 7 Al+++ 0.6391050E+01 0.4259803E-05 0.6391046E+01 0.0000000E+00 8 H4SiO4 0.2040904E+02 0.1084449E-01 0.2039820E+02 0.0000000E+00 9 Ca++ 0.2254293E+01 0.1859461E-06 0.2254293E+01 0.0000000E+00 10 Mg++ 0.1555555E+01 0.7475331E-10 0.1555555E+01 0.0000000E+00 11 Fe++ 0.1397496E+01 0.2907759E-07 0.1397496E+01 0.0000000E+00 12 K+ 0.4161357E+00 0.1261436E-03 0.4160095E+00 0.0000000E+00 13 Na+ 0.2460436E+01 0.1789140E-01 0.2442545E+01 0.0000000E+00 14 Mn++ 0.3398363E-01 0.2019024E-08 0.3398363E-01 0.0000000E+00 15 HPO4-- 0.1159844E-01 0.3717960E-07 0.1159841E-01 0.0000000E+00 Chg. balance for solid moles: -.2495E-14 Mass of aqueous solution: 0.803027E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 1959.9990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 2.440 0.387 639.9 2.806 29.89 245.7 andradite 0.2174 -0.663 110.5 2.043 5.161 28.71 grossular 0.5266E-01 -1.279 23.72 1.375 1.108 6.600 apatite-OH 0.3866E-02 -2.413 1.942 0.288 0.9070E-01 0.6171 clinochlore 0.2792 -0.554 155.2 2.191 7.248 59.03 daphnite 0.8083E-01 -1.092 57.67 1.761 2.694 17.48 chlorite-Mn 0.6797E-02 -2.168 4.819 0.683 0.2251 1.536 diopside 0.9735E-01 -1.012 21.08 1.324 0.9846 6.443 hedenbergite 0.2524E-01 -1.598 6.263 0.797 0.2925 1.715 microcline 0.3648 -0.438 101.5 2.007 4.743 39.67 stilbite 1.268 0.103 893.5 2.951 41.73 416.7 stilpnomelane-Fe 0.1024 -0.990 110.3 2.043 5.154 38.12 tr.625ac.25prg.125 0.1714E-01 -1.766 14.65 1.166 0.6841 4.714 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8050E+00 0.8050E+00 1.0000 -0.094 grossular 0.1950E+00 0.1950E+00 1.0000 -0.710 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.7611E+00 0.7611E+00 1.0000 -0.119 daphnite 0.2203E+00 0.2203E+00 1.0000 -0.657 chlorite-Mn 0.1853E-01 0.1853E-01 1.0000 -1.732 diopside 0.7941E+00 0.7941E+00 1.0000 -0.100 hedenbergite 0.2059E+00 0.2059E+00 1.0000 -0.686 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 tr.625ac.25prg.125 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 2141.117661 g Volume = 867.004707 cm3 Porosity: -10.4465% V(tot) - V(min): -.82005E+02 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 1959.9990000 g log = 3.2923 Original solution: 1000.0103000 g Original solution / Rock added: 0.51 (Water/Rock Ratio), log = -0.2923 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0584 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9645E+00 0.9854 0.1006E+01 0.1021E+01 CO2,gas 0.3979E-08 1.0069 0.4240E-08 0.4211E-08 CH4,gas 0.2113E-01 1.0124 0.2264E-01 0.2237E-01 H2,gas 0.1436E-01 1.0006 0.1521E-01 0.1520E-01 H2S,gas 0.1590E-06 0.9959 0.1676E-06 0.1683E-06 S2,gas 0.4306E-29 1.0000 0.4557E-29 0.4557E-29 CO,gas 0.1624E-13 1.0000 0.1718E-13 0.1718E-13 SO3,gas 0.8251E-48 1.0000 0.8733E-48 0.8733E-48 SO2,gas 0.4882E-27 1.0000 0.5167E-27 0.5167E-27 HCl,gas 0.3245E-17 1.0000 0.3434E-17 0.3434E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 16 albite -0.38 -0.38 0.00 0.000 0.11184E-10 22 andradite 39.01 39.01 0.00 0.000 -0.36397E-10 23 grossular 32.73 32.73 0.00 0.000 -0.12132E-10 32 apatite-OH -18.15 -18.15 0.00 0.000 0.12132E-10 46 clinochlore 39.07 39.07 0.00 0.000 0.24265E-10 47 daphnite 28.97 28.97 0.00 0.000 0.60662E-11 48 chlorite-Mn 46.87 46.87 0.00 0.000 0.12132E-10 67 diopside 16.18 16.18 0.00 0.000 0.12132E-10 68 hedenbergite 14.21 14.21 0.00 0.000 0.00000E+00 116 microcline -2.49 -2.49 0.00 0.000 0.15165E-11 163 stilbite -7.52 -7.52 0.00 0.000 0.15165E-10 164 stilpnomelane-Fe 13.02 13.02 0.00 0.000 0.21232E-10 245 tr.625ac.25prg.125 45.16 45.16 0.00 0.000 0.24265E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -16.73 -10.07 -3.357 0.17197E+05 -8.373 3 CH4,gas 4.54 1.20 -3.34 -0.836 0.57098E+04 -1.645 4 H2,gas 8.00 4.48 -3.52 -2.010 0.60050E+04 -1.818 5 H2S,gas -6.23 -14.71 -8.47 -4.237 0.14470E+05 -6.776 6 S2,gas -7.34 -38.38 -31.04 -4.775 0.53000E+05 -29.341 7 CO,gas 3.21 -12.25 -15.46 -4.758 0.26404E+05 -13.765 8 SO3,gas 17.12 -32.64 -49.76 -12.439 0.84960E+05 -48.059 9 SO2,gas 0.83 -28.15 -28.99 -7.730 0.49492E+05 -27.287 10 HCl,gas 5.19 -13.97 -19.16 -9.582 0.32721E+05 -17.464 11 acmite 7.71 6.53 -1.18 -0.123 0.20176E+04 15 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 19 spessartine 24.46 19.73 -4.73 -0.237 0.80771E+04 20 analcite 3.32 2.77 -0.55 -0.061 0.93623E+03 26 annite 20.12 17.72 -2.40 -0.134 0.41064E+04 27 phlogopite 27.06 25.40 -1.67 -0.093 0.28488E+04 29 anorthite 12.71 8.27 -4.45 -0.342 0.75902E+04 35 aragonite 0.97 -3.63 -4.60 -1.532 0.78482E+04 36 brucite 12.57 9.29 -3.27 -0.655 0.55909E+04 37 calcite 0.81 -3.63 -4.44 -1.481 0.75840E+04 38 carnegieite-low 9.02 5.93 -3.09 -0.442 0.52801E+04 39 carnegieite-high 10.09 5.93 -4.16 -0.595 0.71071E+04 40 carpholite-Mg 8.58 4.46 -4.12 -0.275 0.70428E+04 41 carpholite-Fe 6.71 1.90 -4.81 -0.321 0.82206E+04 42 celadonite 5.34 3.65 -1.69 -0.099 0.28879E+04 43 celadonite-Fe 3.88 1.09 -2.79 -0.164 0.47561E+04 44 chrysotile 23.89 21.57 -2.32 -0.194 0.39692E+04 49 chlorite-Al-free 47.17 43.14 -4.04 -0.168 0.68935E+04 51 chloritoid-Fe 9.17 5.06 -4.12 -0.275 0.70314E+04 52 chloritoid-Mn 11.40 7.56 -3.84 -0.256 0.65568E+04 54 coesite -2.38 -3.16 -0.78 -0.260 0.13341E+04 61 cristobalite -2.56 -3.16 -0.60 -0.199 0.10195E+04 63 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71234E+04 65 diaspore 2.87 0.74 -2.13 -0.356 0.36449E+04 66 diamond -3.10 -7.77 -4.66 -1.332 0.79630E+04 71 enstatite 17.26 12.27 -4.99 -0.499 0.85225E+04 73 clinoenstatite 17.17 12.27 -4.89 -0.489 0.83541E+04 75 epidote 24.67 22.70 -1.97 -0.095 0.33584E+04 76 clinozoisite 22.81 18.95 -3.86 -0.175 0.65867E+04 77 epidote-Fe 29.84 26.46 -3.38 -0.176 0.57768E+04 78 fayalite 14.05 10.31 -3.73 -0.533 0.63743E+04 79 ferrosilite 11.15 7.16 -3.99 -0.399 0.68202E+04 83 gibbsite 4.08 0.74 -3.34 -0.477 0.57035E+04 84 glaucophane 22.97 20.80 -2.17 -0.059 0.37133E+04 85 glaucophane-Fe 17.28 13.12 -4.15 -0.112 0.70919E+04 86 graphite -3.55 -7.77 -4.22 -1.206 0.72053E+04 87 greenalite 16.14 13.89 -2.25 -0.187 0.38408E+04 90 hematite 12.57 8.99 -3.58 -0.434 0.61112E+04 91 heulandite -5.83 -7.52 -1.69 -0.077 0.28938E+04 95 jadeite 4.22 2.77 -1.44 -0.144 0.24617E+04 97 kalsilite 7.58 3.83 -3.76 -0.537 0.64125E+04 98 kaolinite -1.33 -4.84 -3.50 -0.319 0.59830E+04 101 laumontite 2.88 1.95 -0.93 -0.062 0.15934E+04 102 lawsonite 9.62 8.27 -1.35 -0.090 0.23069E+04 103 leucite 4.12 0.67 -3.45 -0.345 0.58873E+04 105 lizardite 23.24 21.57 -1.68 -0.140 0.28618E+04 107 magnetite 20.09 15.72 -4.37 -0.356 0.74536E+04 108 minnesotaite 10.39 7.58 -2.81 -0.165 0.48028E+04 112 manganosite 14.06 9.24 -4.82 -1.204 0.82262E+04 120 muscovite 2.58 -1.01 -3.59 -0.211 0.61314E+04 121 paragonite 4.24 1.09 -3.15 -0.185 0.53705E+04 122 nepheline 8.34 5.93 -2.41 -0.344 0.41124E+04 128 periclase-Fe 11.63 6.73 -4.89 -1.223 0.83523E+04 134 phlogopite-Na 29.65 27.50 -2.15 -0.119 0.36677E+04 136 prehnite 19.37 18.21 -1.16 -0.068 0.19848E+04 137 prehnite-Fe 22.50 21.96 -0.53 -0.032 0.91155E+03 138 pumpellyite-Fe 46.27 43.89 -2.38 -0.053 0.40578E+04 139 pumpellyite-Mg 48.99 46.45 -2.54 -0.057 0.43416E+04 143 pyrrhotite -4.26 -7.97 -3.71 -1.237 0.63343E+04 144 pyrrhotiteFe0.875 -6.02 -9.37 -3.35 -1.232 0.57215E+04 145 pyroxmangite 7.40 6.08 -1.32 -0.263 0.22466E+04 146 pyrophyllite -6.18 -11.15 -4.98 -0.311 0.84961E+04 147 quartz -2.99 -3.16 -0.17 -0.056 0.28683E+03 152 rhodonite 7.45 6.08 -1.36 -0.273 0.23268E+04 153 sanidine -1.28 -2.49 -1.21 -0.093 0.20677E+04 165 stilpnomelane-Mg 27.44 25.81 -1.63 -0.049 0.27803E+04 171 talc 16.49 15.25 -1.24 -0.073 0.21140E+04 174 tephroite 18.09 15.32 -2.76 -0.395 0.47168E+04 178 tridymite -2.63 -3.16 -0.53 -0.177 0.90680E+03 179 tremolite 47.87 47.42 -0.45 -0.012 0.77495E+03 180 ferroactinolite 38.45 34.62 -3.83 -0.104 0.65449E+04 181 troilite-low -4.41 -7.97 -3.56 -1.186 0.60771E+04 183 vesuvianite 223.47 218.82 -4.65 -0.036 0.79430E+04 187 wairakite 3.95 1.95 -2.00 -0.118 0.34154E+04 188 walstromite 11.51 9.94 -1.56 -0.313 0.26719E+04 189 wollastonite 10.46 9.94 -0.52 -0.103 0.88229E+03 190 pseudo-wollastonite 11.00 9.94 -1.06 -0.211 0.18021E+04 191 zoisite 22.85 18.95 -3.90 -0.177 0.66607E+04 192 akaganeite 7.75 4.49 -3.26 -0.705 0.55681E+04 199 chalcedony -2.80 -3.16 -0.35 -0.118 0.60612E+03 201 montmorillonite-Ca -2.29 -6.17 -3.88 -0.240 0.66180E+04 202 montmorillonite-K -2.24 -6.27 -4.03 -0.247 0.68816E+04 203 montmorillonite-Mg -2.48 -6.79 -4.32 -0.267 0.73678E+04 204 montmorillonite-Na -2.04 -5.57 -3.54 -0.216 0.60365E+04 205 nontronite-Ca 3.21 -0.19 -3.41 -0.221 0.58216E+04 206 nontronite-H 2.53 -2.36 -4.89 -0.328 0.83486E+04 207 nontronite-K 3.34 -0.30 -3.64 -0.233 0.62084E+04 208 nontronite-Mg 3.07 -0.82 -3.90 -0.253 0.66554E+04 209 nontronite-Na 3.52 0.40 -3.12 -0.200 0.53293E+04 224 tobermorite 9.82 7.76 -2.07 -0.564 0.35287E+04 230 alabandite -0.98 -5.46 -4.49 -1.496 0.76611E+04 233 boehmite 4.41 0.74 -3.67 -0.611 0.62618E+04 235 ferrous-oxide 9.81 6.73 -3.08 -0.769 0.52532E+04 240 silica-amorphous -2.09 -3.16 -1.07 -0.355 0.18203E+04 242 an20ab80 2.02 1.35 -0.67 -0.052 0.11472E+04 243 an25ab75 2.65 1.78 -0.87 -0.067 0.14810E+04 244 an30ab70 3.28 2.21 -1.07 -0.082 0.18243E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 40.0000000 g Current total amount of reactant added: 1959.9990000 g New total amount of reactant added: 1999.9990000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.3298E-10 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 11 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 1999.9990000 Water: Moles liquid = 0.4427E+02 kg liquid = 0.7976E+00 Moles total = 0.3044E+02 kg total = 0.5483E+00 Activity = 1.0000 Stoichiometric ionic strength = .1134661E-01 Osmotic coef. = 0.9692 True ionic strength = .2003063E-01 Chg. balance for total moles = 0.3298E-10 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.88347E-10 -10.0538 0.74231E-10 -10.1294 0.84022E+00 -0.0756 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.17219E-03 -3.7640 0.14381E-03 -3.8422 0.83516E+00 -0.0782 4 SO4-- 0.81138E-12 -12.0908 0.42129E-12 -12.3754 0.51922E+00 -0.2846 5 HCO3- 0.30024E-06 -6.5225 0.25112E-06 -6.6001 0.83639E+00 -0.0776 6 HS- 0.31970E-04 -4.4953 0.26704E-04 -4.5734 0.83529E+00 -0.0782 7 Al+++ 0.97106E-29 -29.0128 0.22426E-29 -29.6492 0.23095E+00 -0.6365 8 H4SiO4 0.69596E-03 -3.1574 0.69596E-03 -3.1574 0.10000E+01 0.0000 9 Ca++ 0.13516E-06 -6.8691 0.69664E-07 -7.1570 0.51541E+00 -0.2878 10 Mg++ 0.21145E-10 -10.6748 0.10849E-10 -10.9646 0.51305E+00 -0.2898 11 Fe++ 0.58279E-13 -13.2345 0.29933E-13 -13.5239 0.51361E+00 -0.2894 12 K+ 0.15661E-03 -3.8052 0.13102E-03 -3.8827 0.83658E+00 -0.0775 13 Na+ 0.19873E-01 -1.7017 0.16594E-01 -1.7800 0.83501E+00 -0.0783 14 Mn++ 0.18646E-10 -10.7294 0.95848E-11 -11.0184 0.51404E+00 -0.2890 15 HPO4-- 0.45274E-07 -7.3442 0.23511E-07 -7.6287 0.51930E+00 -0.2846 16 HSiO3- 0.10482E-01 -1.9795 0.87544E-02 -2.0578 0.83516E+00 -0.0782 17 Ca(HSiO3)+ 0.16598E-07 -7.7799 0.13889E-07 -7.8573 0.83676E+00 -0.0774 18 Mg(HSiO3)+ 0.32169E-11 -11.4926 0.26918E-11 -11.5700 0.83676E+00 -0.0774 19 NaHSiO3,aq 0.23496E-02 -2.6290 0.23496E-02 -2.6290 0.10000E+01 0.0000 20 AlO+ 0.66171E-16 -16.1793 0.55370E-16 -16.2567 0.83676E+00 -0.0774 22 HAlO2,aq 0.14855E-09 -9.8281 0.14855E-09 -9.8281 0.10000E+01 0.0000 23 AlO2- 0.53136E-05 -5.2746 0.44297E-05 -5.3536 0.83366E+00 -0.0790 24 CH4,aq 0.15516E-04 -4.8092 0.15462E-04 -4.8107 0.99654E+00 -0.0015 25 C2H6,aq 0.35406E-14 -14.4509 0.35283E-14 -14.4524 0.99654E+00 -0.0015 29 CO,aq 0.11590E-16 -16.9359 0.11590E-16 -16.9359 0.10000E+01 0.0000 30 CO2,aq 0.39969E-10 -10.3983 0.39830E-10 -10.3998 0.99654E+00 -0.0015 31 CO3-2 0.57030E-06 -6.2439 0.29548E-06 -6.5295 0.51812E+00 -0.2856 32 CaCO3,aq 0.25811E-09 -9.5882 0.25811E-09 -9.5882 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.53366E-12 -12.2727 0.44655E-12 -12.3501 0.83676E+00 -0.0774 34 CaCl+ 0.19376E-10 -10.7127 0.16213E-10 -10.7901 0.83676E+00 -0.0774 35 CaCl2,aq 0.55392E-15 -15.2565 0.55392E-15 -15.2565 0.10000E+01 0.0000 36 CaOH+ 0.79933E-07 -7.0973 0.66885E-07 -7.1747 0.83676E+00 -0.0774 37 CaSO4,aq 0.93195E-17 -17.0306 0.93195E-17 -17.0306 0.10000E+01 0.0000 38 HCl,aq 0.19562E-14 -14.7086 0.19562E-14 -14.7086 0.10000E+01 0.0000 43 FeCl+ 0.81426E-17 -17.0892 0.68135E-17 -17.1666 0.83676E+00 -0.0774 46 FeO,aq 0.21113E-09 -9.6755 0.21113E-09 -9.6755 0.10000E+01 0.0000 47 FeOH+ 0.15686E-10 -10.8045 0.13126E-10 -10.8819 0.83676E+00 -0.0774 48 HFeO2- 0.35633E-07 -7.4481 0.29759E-07 -7.5264 0.83516E+00 -0.0782 49 FeO+ 0.10993E-16 -16.9589 0.91989E-17 -17.0363 0.83676E+00 -0.0774 51 FeO2- 0.40902E-09 -9.3883 0.34160E-09 -9.4665 0.83516E+00 -0.0782 52 HFeO2,aq 0.32251E-11 -11.4915 0.32251E-11 -11.4915 0.10000E+01 0.0000 53 H2,aq 0.11624E-04 -4.9347 0.11583E-04 -4.9362 0.99654E+00 -0.0015 54 KCl,aq 0.34148E-09 -9.4666 0.34148E-09 -9.4666 0.10000E+01 0.0000 56 KOH,aq 0.75375E-06 -6.1228 0.75375E-06 -6.1228 0.10000E+01 0.0000 57 KSO4- 0.10255E-14 -14.9890 0.85650E-15 -15.0673 0.83516E+00 -0.0782 58 MgCO3,aq 0.10075E-13 -13.9968 0.10075E-13 -13.9968 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.84918E-16 -16.0710 0.71057E-16 -16.1484 0.83676E+00 -0.0774 60 MgCl+ 0.27347E-14 -14.5631 0.22883E-14 -14.6405 0.83676E+00 -0.0774 61 MgOH+ 0.68880E-10 -10.1619 0.57636E-10 -10.2393 0.83676E+00 -0.0774 63 MnO,aq 0.18014E-08 -8.7444 0.18014E-08 -8.7444 0.10000E+01 0.0000 64 MnOH+ 0.46662E-09 -9.3310 0.39045E-09 -9.4084 0.83676E+00 -0.0774 65 MnO2-2 0.20940E-10 -10.6790 0.10850E-10 -10.9646 0.51812E+00 -0.2856 66 HMnO2- 0.21127E-09 -9.6752 0.17644E-09 -9.7534 0.83516E+00 -0.0782 69 MnCl+ 0.10144E-13 -13.9938 0.84880E-14 -14.0712 0.83676E+00 -0.0774 71 NaCl,aq 0.79085E-06 -6.1019 0.79085E-06 -6.1019 0.10000E+01 0.0000 72 NaOH,aq 0.96047E-04 -4.0175 0.96047E-04 -4.0175 0.10000E+01 0.0000 74 OH- 0.93366E-02 -2.0298 0.77835E-02 -2.1088 0.83366E+00 -0.0790 79 HPO3-2 0.16380E-14 -14.7857 0.84869E-15 -15.0713 0.51812E+00 -0.2856 81 H2PO3- 0.15126E-18 -18.8203 0.12633E-18 -18.8985 0.83516E+00 -0.0782 82 H3PO4,aq 0.90606E-18 -18.0428 0.90606E-18 -18.0428 0.10000E+01 0.0000 83 H2PO4- 0.38512E-10 -10.4144 0.32194E-10 -10.4922 0.83596E+00 -0.0778 84 PO4-3 0.10653E-08 -8.9725 0.25841E-09 -9.5877 0.24257E+00 -0.6152 88 HP2O7-3 0.94565E-18 -18.0243 0.21861E-18 -18.6603 0.23118E+00 -0.6361 89 P2O7-4 0.91303E-17 -17.0395 0.70357E-18 -18.1527 0.77059E-01 -1.1132 90 H2S,aq 0.61477E-08 -8.2113 0.61264E-08 -8.2128 0.99654E+00 -0.0015 91 S2-2 0.26328E-14 -14.5796 0.13641E-14 -14.8652 0.51812E+00 -0.2856 97 SO3-2 0.12065E-17 -17.9185 0.63415E-18 -18.1978 0.52562E+00 -0.2793 99 HSO4- 0.35982E-19 -19.4439 0.30138E-19 -19.5209 0.83758E+00 -0.0770 Charge balance for all species = 0.4136E-10 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.8834674E-10 -.2229013E-01 -.2242806E+02 0.0000 2 H2O 0.1000000E+01 0.5550489E+02 0.9981989E+06 0.0000 3 Cl- 0.1721924E-03 0.1729836E-03 0.6122127E+01 6.2872 4 SO4-- 0.8113774E-12 -.1842139E-04 -.1766512E+01 7.8834 5 HCO3- 0.3002393E-06 0.1638637E-04 0.9981123E+00 3.5293 6 HS- 0.3196980E-04 0.5039734E-04 0.1663843E+01 5.5560 7 Al+++ 0.9710648E-29 0.5313773E-05 0.1431243E+00 0.7390 8 H4SiO4 0.6959572E-03 0.1352779E-01 0.1297968E+04 -3.1574 9 Ca++ 0.1351622E-06 0.2319717E-06 0.9280798E-02 13.1018 10 Mg++ 0.2114527E-10 0.9325430E-10 0.2263257E-05 9.2942 11 Fe++ 0.5827877E-13 0.3627214E-07 0.2022168E-02 6.7350 12 K+ 0.1566089E-03 0.1573630E-03 0.6142512E+01 6.2467 13 Na+ 0.1987290E-01 0.2231930E-01 0.5122243E+03 8.3494 14 Mn++ 0.1864599E-10 0.2518880E-08 0.1381416E-03 9.2404 15 HPO4-- 0.4527408E-07 0.4637792E-07 0.4443568E-02 12.6301 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.3311700E+02 -.1777892E-01 -.3309922E+02 0.0000000E+00 2 H2O 0.3043744E+02 0.4427148E+02 -.1383404E+02 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.5545229E-01 -.1469316E-04 0.5546699E-01 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.5542679E-01 0.4019763E-04 -.5546699E-01 0.0000000E+00 7 Al+++ 0.6521480E+01 0.4238340E-05 0.6521476E+01 0.0000000E+00 8 H4SiO4 0.2082556E+02 0.1078995E-01 0.2081477E+02 0.0000000E+00 9 Ca++ 0.2300299E+01 0.1850239E-06 0.2300298E+01 0.0000000E+00 10 Mg++ 0.1587301E+01 0.7438095E-10 0.1587301E+01 0.0000000E+00 11 Fe++ 0.1426016E+01 0.2893117E-07 0.1426016E+01 0.0000000E+00 12 K+ 0.4246282E+00 0.1255150E-03 0.4245027E+00 0.0000000E+00 13 Na+ 0.2510646E+01 0.1780219E-01 0.2492844E+01 0.0000000E+00 14 Mn++ 0.3467717E-01 0.2009094E-08 0.3467717E-01 0.0000000E+00 15 HPO4-- 0.1183515E-01 0.3699168E-07 0.1183511E-01 0.0000000E+00 Chg. balance for solid moles: 0.2560E-14 Mass of aqueous solution: 0.799003E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 1999.9990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 2.491 0.396 653.1 2.815 29.89 250.7 andradite 0.2219 -0.654 112.7 2.052 5.161 29.29 grossular 0.5373E-01 -1.270 24.20 1.384 1.108 6.734 apatite-OH 0.3945E-02 -2.404 1.982 0.297 0.9070E-01 0.6297 clinochlore 0.2849 -0.545 158.4 2.200 7.248 60.23 daphnite 0.8247E-01 -1.084 58.84 1.770 2.693 17.83 chlorite-Mn 0.6935E-02 -2.159 4.917 0.692 0.2251 1.567 diopside 0.9952E-01 -1.002 21.55 1.333 0.9865 6.587 hedenbergite 0.2581E-01 -1.588 6.403 0.806 0.2931 1.754 microcline 0.3723 -0.429 103.6 2.015 4.743 40.48 stilbite 1.294 0.112 911.6 2.960 41.72 425.2 stilpnomelane-Fe 0.1045 -0.981 112.6 2.052 5.154 38.90 tr.625ac.25prg.125 0.1747E-01 -1.758 14.93 1.174 0.6834 4.806 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8050E+00 0.8050E+00 1.0000 -0.094 grossular 0.1950E+00 0.1950E+00 1.0000 -0.710 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.7611E+00 0.7611E+00 1.0000 -0.119 daphnite 0.2203E+00 0.2203E+00 1.0000 -0.657 chlorite-Mn 0.1853E-01 0.1853E-01 1.0000 -1.732 diopside 0.7941E+00 0.7941E+00 1.0000 -0.100 hedenbergite 0.2059E+00 0.2059E+00 1.0000 -0.686 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 tr.625ac.25prg.125 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 2184.817926 g Volume = 884.685933 cm3 Porosity: -10.4477% V(tot) - V(min): -.83686E+02 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 1999.9990000 g log = 3.3010 Original solution: 1000.0103000 g Original solution / Rock added: 0.50 (Water/Rock Ratio), log = -0.3010 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0585 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9644E+00 0.9854 0.1006E+01 0.1021E+01 CO2,gas 0.3998E-08 1.0069 0.4261E-08 0.4232E-08 CH4,gas 0.2124E-01 1.0124 0.2276E-01 0.2248E-01 H2,gas 0.1436E-01 1.0006 0.1521E-01 0.1520E-01 H2S,gas 0.1598E-06 0.9959 0.1684E-06 0.1691E-06 S2,gas 0.4349E-29 1.0000 0.4603E-29 0.4603E-29 CO,gas 0.1632E-13 1.0000 0.1727E-13 0.1727E-13 SO3,gas 0.8292E-48 1.0000 0.8777E-48 0.8777E-48 SO2,gas 0.4906E-27 1.0000 0.5193E-27 0.5193E-27 HCl,gas 0.3261E-17 1.0000 0.3452E-17 0.3452E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 16 albite -0.38 -0.38 0.00 0.000 0.11184E-10 22 andradite 39.01 39.01 0.00 0.000 0.12132E-10 23 grossular 32.73 32.73 0.00 0.000 0.12132E-10 32 apatite-OH -18.15 -18.15 0.00 0.000 0.00000E+00 46 clinochlore 39.07 39.07 0.00 0.000 0.12132E-10 47 daphnite 28.97 28.97 0.00 0.000 -0.30331E-10 48 chlorite-Mn 46.87 46.87 0.00 0.000 0.24265E-10 67 diopside 16.18 16.18 0.00 0.000 0.00000E+00 68 hedenbergite 14.21 14.21 0.00 0.000 0.60662E-11 116 microcline -2.49 -2.49 0.00 0.000 0.13649E-10 163 stilbite -7.52 -7.52 0.00 0.000 0.39430E-10 164 stilpnomelane-Fe 13.02 13.02 0.00 0.000 -0.27298E-10 245 tr.625ac.25prg.125 45.16 45.16 0.00 0.000 0.48529E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -16.73 -10.07 -3.356 0.17193E+05 -8.370 3 CH4,gas 4.54 1.20 -3.34 -0.835 0.57061E+04 -1.643 4 H2,gas 8.00 4.48 -3.52 -2.010 0.60050E+04 -1.818 5 H2S,gas -6.23 -14.70 -8.47 -4.236 0.14467E+05 -6.774 6 S2,gas -7.34 -38.37 -31.04 -4.775 0.52993E+05 -29.337 7 CO,gas 3.21 -12.25 -15.46 -4.757 0.26400E+05 -13.763 8 SO3,gas 17.12 -32.63 -49.76 -12.439 0.84956E+05 -48.057 9 SO2,gas 0.83 -28.15 -28.98 -7.729 0.49489E+05 -27.285 10 HCl,gas 5.19 -13.97 -19.16 -9.580 0.32717E+05 -17.462 11 acmite 7.71 6.53 -1.18 -0.123 0.20176E+04 15 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 19 spessartine 24.46 19.73 -4.73 -0.237 0.80769E+04 20 analcite 3.32 2.77 -0.55 -0.061 0.93623E+03 26 annite 20.12 17.72 -2.40 -0.134 0.41064E+04 27 phlogopite 27.06 25.40 -1.67 -0.093 0.28488E+04 29 anorthite 12.71 8.27 -4.45 -0.342 0.75902E+04 35 aragonite 0.97 -3.63 -4.59 -1.531 0.78445E+04 36 brucite 12.57 9.29 -3.27 -0.655 0.55909E+04 37 calcite 0.81 -3.63 -4.44 -1.480 0.75803E+04 38 carnegieite-low 9.02 5.93 -3.09 -0.442 0.52801E+04 39 carnegieite-high 10.09 5.93 -4.16 -0.595 0.71071E+04 40 carpholite-Mg 8.58 4.46 -4.12 -0.275 0.70428E+04 41 carpholite-Fe 6.71 1.90 -4.81 -0.321 0.82206E+04 42 celadonite 5.34 3.65 -1.69 -0.099 0.28879E+04 43 celadonite-Fe 3.88 1.09 -2.79 -0.164 0.47561E+04 44 chrysotile 23.89 21.57 -2.32 -0.194 0.39692E+04 49 chlorite-Al-free 47.17 43.14 -4.04 -0.168 0.68935E+04 51 chloritoid-Fe 9.17 5.06 -4.12 -0.275 0.70314E+04 52 chloritoid-Mn 11.40 7.56 -3.84 -0.256 0.65568E+04 54 coesite -2.38 -3.16 -0.78 -0.260 0.13341E+04 61 cristobalite -2.56 -3.16 -0.60 -0.199 0.10195E+04 63 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71234E+04 65 diaspore 2.87 0.74 -2.13 -0.356 0.36449E+04 66 diamond -3.10 -7.76 -4.66 -1.332 0.79593E+04 71 enstatite 17.26 12.27 -4.99 -0.499 0.85225E+04 73 clinoenstatite 17.17 12.27 -4.89 -0.489 0.83541E+04 75 epidote 24.67 22.70 -1.97 -0.095 0.33584E+04 76 clinozoisite 22.81 18.95 -3.86 -0.175 0.65867E+04 77 epidote-Fe 29.84 26.46 -3.38 -0.176 0.57768E+04 78 fayalite 14.05 10.31 -3.73 -0.533 0.63743E+04 79 ferrosilite 11.15 7.16 -3.99 -0.399 0.68202E+04 83 gibbsite 4.08 0.74 -3.34 -0.477 0.57035E+04 84 glaucophane 22.97 20.80 -2.17 -0.059 0.37133E+04 85 glaucophane-Fe 17.28 13.12 -4.15 -0.112 0.70919E+04 86 graphite -3.55 -7.76 -4.22 -1.205 0.72015E+04 87 greenalite 16.14 13.89 -2.25 -0.187 0.38408E+04 90 hematite 12.57 8.99 -3.58 -0.434 0.61112E+04 91 heulandite -5.83 -7.52 -1.69 -0.077 0.28938E+04 95 jadeite 4.22 2.77 -1.44 -0.144 0.24617E+04 97 kalsilite 7.58 3.83 -3.76 -0.537 0.64125E+04 98 kaolinite -1.33 -4.84 -3.50 -0.319 0.59831E+04 101 laumontite 2.88 1.95 -0.93 -0.062 0.15934E+04 102 lawsonite 9.62 8.27 -1.35 -0.090 0.23069E+04 103 leucite 4.12 0.67 -3.45 -0.345 0.58873E+04 105 lizardite 23.24 21.57 -1.68 -0.140 0.28618E+04 107 magnetite 20.09 15.72 -4.37 -0.356 0.74536E+04 108 minnesotaite 10.39 7.58 -2.81 -0.165 0.48028E+04 112 manganosite 14.06 9.24 -4.82 -1.204 0.82261E+04 120 muscovite 2.58 -1.01 -3.59 -0.211 0.61314E+04 121 paragonite 4.24 1.09 -3.15 -0.185 0.53705E+04 122 nepheline 8.34 5.93 -2.41 -0.344 0.41124E+04 128 periclase-Fe 11.63 6.73 -4.89 -1.223 0.83523E+04 134 phlogopite-Na 29.65 27.50 -2.15 -0.119 0.36677E+04 136 prehnite 19.37 18.21 -1.16 -0.068 0.19848E+04 137 prehnite-Fe 22.50 21.96 -0.53 -0.032 0.91155E+03 138 pumpellyite-Fe 46.27 43.89 -2.38 -0.053 0.40578E+04 139 pumpellyite-Mg 48.99 46.45 -2.54 -0.057 0.43416E+04 143 pyrrhotite -4.26 -7.97 -3.71 -1.236 0.63305E+04 144 pyrrhotiteFe0.875 -6.02 -9.37 -3.35 -1.232 0.57177E+04 145 pyroxmangite 7.40 6.08 -1.32 -0.263 0.22465E+04 146 pyrophyllite -6.18 -11.15 -4.98 -0.311 0.84961E+04 147 quartz -2.99 -3.16 -0.17 -0.056 0.28682E+03 152 rhodonite 7.45 6.08 -1.36 -0.273 0.23267E+04 153 sanidine -1.28 -2.49 -1.21 -0.093 0.20677E+04 165 stilpnomelane-Mg 27.44 25.81 -1.63 -0.049 0.27803E+04 171 talc 16.49 15.25 -1.24 -0.073 0.21140E+04 174 tephroite 18.09 15.32 -2.76 -0.395 0.47167E+04 178 tridymite -2.63 -3.16 -0.53 -0.177 0.90680E+03 179 tremolite 47.87 47.42 -0.45 -0.012 0.77495E+03 180 ferroactinolite 38.45 34.62 -3.83 -0.104 0.65449E+04 181 troilite-low -4.41 -7.97 -3.56 -1.186 0.60733E+04 183 vesuvianite 223.47 218.82 -4.65 -0.036 0.79430E+04 187 wairakite 3.95 1.95 -2.00 -0.118 0.34154E+04 188 walstromite 11.51 9.94 -1.56 -0.313 0.26719E+04 189 wollastonite 10.46 9.94 -0.52 -0.103 0.88229E+03 190 pseudo-wollastonite 11.00 9.94 -1.06 -0.211 0.18021E+04 191 zoisite 22.85 18.95 -3.90 -0.177 0.66607E+04 192 akaganeite 7.75 4.49 -3.26 -0.705 0.55681E+04 199 chalcedony -2.80 -3.16 -0.35 -0.118 0.60612E+03 201 montmorillonite-Ca -2.29 -6.17 -3.88 -0.240 0.66180E+04 202 montmorillonite-K -2.24 -6.27 -4.03 -0.247 0.68816E+04 203 montmorillonite-Mg -2.48 -6.79 -4.32 -0.267 0.73678E+04 204 montmorillonite-Na -2.04 -5.57 -3.54 -0.216 0.60365E+04 205 nontronite-Ca 3.21 -0.19 -3.41 -0.221 0.58216E+04 206 nontronite-H 2.53 -2.36 -4.89 -0.328 0.83486E+04 207 nontronite-K 3.34 -0.30 -3.64 -0.233 0.62084E+04 208 nontronite-Mg 3.07 -0.82 -3.90 -0.253 0.66554E+04 209 nontronite-Na 3.52 0.40 -3.12 -0.200 0.53293E+04 224 tobermorite 9.82 7.76 -2.07 -0.564 0.35287E+04 230 alabandite -0.98 -5.46 -4.48 -1.495 0.76573E+04 233 boehmite 4.41 0.74 -3.67 -0.611 0.62618E+04 235 ferrous-oxide 9.81 6.73 -3.08 -0.769 0.52532E+04 240 silica-amorphous -2.09 -3.16 -1.07 -0.355 0.18203E+04 242 an20ab80 2.02 1.35 -0.67 -0.052 0.11472E+04 243 an25ab75 2.65 1.78 -0.87 -0.067 0.14810E+04 244 an30ab70 3.28 2.21 -1.07 -0.082 0.18243E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 40.0000000 g Current total amount of reactant added: 1999.9990000 g New total amount of reactant added: 2039.9990000 g Mixing fraction reached given limit of 0.2000E+04 TOTMIX = 0.2040E+04 Execution stopped.