File SKIP_SPECIES.TXT lists species and minerals omitted from the calculations due to given T, P, option switches, or suppression in CHIMRUN, or are suppressed in the SOLTHERM database. It also lists minerals for which density is not specified in SOLTHERM. This is an extended P(to 5 kB), T(to 600 C) run (CON_FLAG = 1). methanol,aq is suppressed in SOLTHERM data file. methanol,aq is suppressed in SOLTHERM data file. CuCl4-3 is suppressed in SOLTHERM data file. H2BO3- is suppressed in SOLTHERM data file. UO2CO3,aq is suppressed in SOLTHERM data file. UO2SO4,aq is suppressed in SOLTHERM data file. UO2Cl2,aq is suppressed in SOLTHERM data file. UO2F2,aq is suppressed in SOLTHERM data file. PO4-3 is suppressed in SOLTHERM data file. H2PO4- is suppressed in SOLTHERM data file. H3PO4 is suppressed in SOLTHERM data file. O2,gas is suppressed in THIS RUN. O2,gas is suppressed in THIS RUN. amesite is suppressed in SOLTHERM data file. antigorite is suppressed in SOLTHERM data file. goethite is suppressed in THIS RUN. goethite is suppressed in THIS RUN. riebeckite is suppressed in THIS RUN. riebeckite is suppressed in THIS RUN. sapphirine-Fe(221) is suppressed in SOLTHERM data file. sapphirine(221) is suppressed in SOLTHERM data file. talc-prl is suppressed in SOLTHERM data file. PrO1.833(s) is suppressed in SOLTHERM data file. niter-NH4 is suppressed in SOLTHERM data file. FMQ_HS-1 is suppressed in THIS RUN. kf-ab-equil is suppressed in THIS RUN. ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Species No. Charge Tot.moles Trial molality Gamma Mixing solution H+ 1 1. -0.33117E+02 0.88347E-10 0.8402 0.00000000E+00 H2O 2 0. 0.30437E+02 0.10000E+01 1.0000 0.00000000E+00 Cl- 3 -1. 0.13797E-03 0.17219E-03 0.8352 0.00000000E+00 SO4-- 4 -2. 0.55452E-01 0.81138E-12 0.5192 0.00000000E+00 HCO3- 5 -1. 0.13070E-04 0.30024E-06 0.8364 0.00000000E+00 HS- 6 -1. -0.55427E-01 0.31970E-04 0.8353 0.00000000E+00 Al+++ 7 3. 0.65215E+01 0.97106E-29 0.2309 0.00000000E+00 H4SiO4 8 0. 0.20826E+02 0.69596E-03 1.0000 0.00000000E+00 Ca++ 9 2. 0.23003E+01 0.13516E-06 0.5154 0.00000000E+00 Mg++ 10 2. 0.15873E+01 0.21145E-10 0.5131 0.00000000E+00 Fe++ 11 2. 0.14260E+01 0.58279E-13 0.5136 0.00000000E+00 K+ 12 1. 0.42463E+00 0.15661E-03 0.8366 0.00000000E+00 Na+ 13 1. 0.25106E+01 0.19873E-01 0.8350 0.00000000E+00 Mn++ 14 2. 0.34677E-01 0.18646E-10 0.5140 0.00000000E+00 HPO4-- 15 -2. 0.11835E-01 0.45274E-07 0.5193 0.00000000E+00 Chg. balance for total moles = 0.5220E-10 Max. difference allowed = 0.1380E-07 The following parameters were given: ERPC = 0.1000E-11 pH = 0.0000 PFLUID = 50.0000 SLIM = 0.100000E+05 TEMP = 100.0000 SINC = 0.1000E+03 TEMPC = 0.0000 TOTMIX = 0.200000E+04 ENTH = 0.0000 SENTH = 0.0000 DENTH = 0.0000 TOTWAT = 90.0000 SOLMIN = 0.0000E+00 RM = 0.0000 AQGRM = 1000.0103 SUPRNT = 0.1000E-19 VBOX-1 = 800.9996 RHOFRS = 0.0000 RHOROC = 2.5000 The following options were selected: CONFLG = 1 C = 3 IFRAC = 0 IPUNCH = 2 NLOOP = 400 ISTEP = 2 LIMSOL = 1 LOOC = 0 IENTH = 0 ITREF = 0 IDEAL = 0 IPSAT = 1 INCREM = 0 INCP = 0 MINSOL = 1 NEUT = 0 AWAT = 0 CHGF = 0 Of the derived species, only those with molality > 0.10E-19 will appear in the output Species No. Charge Log K(diss) Species No. Charge Log K(diss) HSiO3- 16 -1. 9.0298 MnO2-2 65 -2. 40.4638 Ca(HSiO3)+ 17 1. 7.6723 HMnO2- 66 -1. 29.1232 Mg(HSiO3)+ 18 1. 7.5773 MnO4- 67 -1. 83.3111 NaHSiO3,aq 19 0. 7.8210 MnO4-2 68 -2. 81.3005 AlO+ 20 1. 6.8663 MnCl+ 69 1. -0.7894 AlOH+2 21 2. 3.1691 MnSO4,aq 70 0. -2.4604 HAlO2,aq 22 0. 10.5671 NaCl,aq 71 0. 0.4796 AlO2- 23 -1. 16.2221 NaOH,aq 72 0. 12.3669 CH4,aq 24 0. 6.0126 O2,aq 73 0. 53.5502 C2H6,aq 25 0. 12.3733 OH- 74 -1. 12.2382 C3H8,aq 26 0. 17.3707 HO2- 75 -1. 50.8010 C4H10,aq 27 0. 22.3757 H2O2,aq 76 0. 40.0166 ethanol,aq 28 0. 15.3258 H3PO2,aq 77 0. 24.3066 CO,aq 29 0. 4.6892 H2PO2- 78 -1. 26.5366 CO2,aq 30 0. -6.3298 HPO3-2 79 -2. 11.9254 CO3-2 31 -2. 10.0588 H3PO3,aq 80 0. 3.5792 CaCO3,aq 32 0. 5.9605 H2PO3- 81 -1. 5.6232 Ca(HCO3)+ 33 1. -1.4070 H3PO4,aq 82 0. -9.8447 CaCl+ 34 1. -0.2091 H2PO4- 83 -1. -7.2659 CaCl2,aq 35 0. 0.4151 PO4-3 84 -3. 12.0884 CaOH+ 36 1. 10.1471 H4P2O7,aq 85 0. -17.8095 CaSO4,aq 37 0. -2.5018 H3P2O7- 86 -1. -15.9156 HCl,aq 38 0. 0.7370 H2P2O7-2 87 -2. -13.4262 HClO,aq 39 0. 32.4260 HP2O7-3 88 -3. -6.7266 ClO- 40 -1. 39.6530 P2O7-4 89 -4. 2.8952 HClO2,aq 41 0. 70.1812 H2S,aq 90 0. -6.4900 Fe+3 42 3. 8.3809 S2-2 91 -2. 1.2355 FeCl+ 43 1. -0.1994 S3-2 92 -2. -8.8031 FeCl2,aq 44 0. 4.3001 S3- 93 -1. -16.3389 FeCl+2 45 2. 6.5269 S4-2 94 -2. -18.6615 FeO,aq 46 0. 16.4104 S5-2 95 -2. -28.3439 FeOH+ 47 1. 7.4874 SO2,aq 96 0. -0.2309 HFeO2- 48 -1. 24.3908 SO3-2 97 -2. 10.3052 FeO+ 49 1. 11.4004 HSO3- 98 -1. 2.5086 FeOH+2 50 2. 9.1194 HSO4- 99 -1. -2.9839 FeO2- 51 -1. 24.0895 HSO5- 100 -1. 38.8366 HFeO2,aq 52 0. 15.9850 S2O3-2 101 -2. -4.5600 H2,aq 53 0. 9.4190 HS2O3- 102 -1. -6.8123 KCl,aq 54 0. 1.7417 H2S2O3,aq 103 0. -8.0173 KHSO4,aq 55 0. -0.4514 S2O4-2 104 -2. 10.5541 KOH,aq 56 0. 12.3695 HS2O4- 105 -1. 7.6551 KSO4- 57 -1. -1.1908 H2S2O4,aq 106 0. 6.6259 MgCO3,aq 58 0. 6.5614 S2O5-2 107 -2. 10.0741 Mg(HCO3)+ 59 1. -1.4164 S2O6-2 108 -2. 11.5521 MgCl+ 60 1. -0.1664 S2O8-2 109 -2. 42.0620 MgOH+ 61 1. 9.4041 S3O6-2 110 -2. 3.7866 Mn+3 62 3. 19.1453 S4O6-2 111 -2. -17.8657 MnO,aq 63 0. 17.9848 S5O6-2 112 -2. -14.1333 MnOH+ 64 1. 8.5194 113 0. 10.3111 For mixed gases (JSOLS=6), log K(hydrol) = log (K*P) Log K Trial Log K Trial Mineral No. hydrol Moles Mineral No. hydrol Moles H2O,gas 1 1.696 0.0000E+00 osumilite(2) 124 20.667 0.0000E+00 CO2,gas 2 -6.660 0.0000E+00 osumilite-Fe 125 14.390 0.0000E+00 CH4,gas 3 4.544 0.0000E+00 pargasite 126 65.092 0.0000E+00 H2,gas 4 8.000 0.0000E+00 periclase 127 16.138 0.0000E+00 H2S,gas 5 -6.230 0.0000E+00 periclase-Fe 128 11.627 0.0000E+00 S2,gas 6 -7.335 0.0000E+00 perovskite-Al 129 12.344 0.0000E+00 CO,gas 7 3.215 0.0000E+00 perovskite-Ca 130 23.807 0.0000E+00 SO3,gas 8 17.121 0.0000E+00 perovskite-Fe 131 21.143 0.0000E+00 SO2,gas 9 0.832 0.0000E+00 perovskite-Mg 132 23.119 0.0000E+00 HCl,gas 10 5.189 0.0000E+00 phase_A 133 80.189 0.0000E+00 acmite 11 7.710 0.0000E+00 phlogopite-Na 134 29.647 0.0000E+00 akermanite 12 36.442 0.0000E+00 piemontite(ordered) 135 33.776 0.0000E+00 akimotoite 13 16.591 0.0000E+00 prehnite 136 19.372 0.0000E+00 akimotoite-Fe 14 13.067 0.0000E+00 prehnite-Fe 137 22.498 0.0000E+00 albite-high 15 0.693 0.0000E+00 pumpellyite-Fe 138 46.269 0.0000E+00 albite 16 -0.384 0.2491E+01 pumpellyite-Mg 139 48.995 0.0000E+00 almandine 17 24.442 0.0000E+00 px-Mg-tschermaks 140 19.616 0.0000E+00 pyrope 18 37.248 0.0000E+00 px-Ca-tschermaks 141 18.610 0.0000E+00 spessartine 19 24.457 0.0000E+00 pyrite 142 -21.247 0.0000E+00 analcite 20 3.322 0.0000E+00 pyrrhotite 143 -4.260 0.0000E+00 andalusite 21 5.002 0.0000E+00 pyrrhotiteFe0.875 144 -6.017 0.0000E+00 andradite 22 39.009 0.2219E+00 pyroxmangite 145 7.399 0.0000E+00 grossular 23 32.731 0.5373E-01 pyrophyllite 146 -6.176 0.0000E+00 anhydrite 24 -5.317 0.0000E+00 quartz 147 -2.989 0.0000E+00 ankerite 25 -2.135 0.0000E+00 rankinite 148 40.713 0.0000E+00 annite 26 20.123 0.0000E+00 ringwoodite-Fe 149 15.456 0.0000E+00 phlogopite 27 27.065 0.0000E+00 ringwoodite-Mg 150 27.575 0.0000E+00 biotite-Mn 28 32.960 0.0000E+00 rhodochrosite 151 -0.976 0.0000E+00 anorthite 29 12.710 0.0000E+00 rhodonite 152 7.446 0.0000E+00 anthophyllite 30 51.852 0.0000E+00 sanidine 153 -1.275 0.0000E+00 anthophyllite-Fe 31 29.306 0.0000E+00 sapphirine(351) 154 78.899 0.0000E+00 apatite-OH 32 -18.153 0.3945E-02 siderite 155 -2.608 0.0000E+00 apatite-OH-zs 33 -12.736 0.0000E+00 sillimanite 156 5.262 0.0000E+00 apatite-Cl-zs 34 -16.674 0.0000E+00 sodalite 157 49.976 0.0000E+00 aragonite 35 0.967 0.0000E+00 spinel 158 20.870 0.0000E+00 brucite 36 12.569 0.0000E+00 spurrite 159 59.482 0.0000E+00 calcite 37 0.812 0.0000E+00 staurolite-Fe 160 73.598 0.0000E+00 carnegieite-low 38 9.023 0.0000E+00 staurolite-Mg 161 89.802 0.0000E+00 carnegieite-high 39 10.093 0.0000E+00 staurolite-Mn 162 83.909 0.0000E+00 carpholite-Mg 40 8.582 0.0000E+00 stilbite 163 -7.522 0.1294E+01 carpholite-Fe 41 6.713 0.0000E+00 stilpnomelane-Fe 164 13.017 0.1045E+00 celadonite 42 5.342 0.0000E+00 stilpnomelane-Mg 165 27.441 0.0000E+00 celadonite-Fe 43 3.877 0.0000E+00 stishovite 166 2.720 0.0000E+00 chrysotile 44 23.892 0.0000E+00 sudoite-Fe 167 18.296 0.0000E+00 chondrodite 45 56.475 0.0000E+00 sudoite 168 21.077 0.0000E+00 clinochlore 46 39.070 0.2849E+00 sulfur 169 -9.152 0.0000E+00 daphnite 47 28.965 0.8247E-01 sylvite 170 1.338 0.0000E+00 chlorite-Mn 48 46.869 0.6935E-02 talc 171 16.491 0.0000E+00 chlorite-Al-free 49 47.173 0.0000E+00 talc-Fe 172 13.448 0.0000E+00 chloritoid-Mg 50 13.198 0.0000E+00 talc-tschermaks 173 19.091 0.0000E+00 chloritoid-Fe 51 9.174 0.0000E+00 tephroite 174 18.086 0.0000E+00 chloritoid-Mn 52 11.401 0.0000E+00 tilleyite 175 41.377 0.0000E+00 clinohumite 53 97.128 0.0000E+00 titanite-CaSi 176 15.479 0.0000E+00 coesite 54 -2.376 0.0000E+00 topaz-H 177 4.618 0.0000E+00 cordierite-H 55 23.715 0.0000E+00 tridymite 178 -2.626 0.0000E+00 cordierite 56 24.049 0.0000E+00 tremolite 179 47.869 0.0000E+00 cordierite-Fe 57 20.450 0.0000E+00 ferroactinolite 180 38.452 0.0000E+00 cordierite-Mn 58 25.066 0.0000E+00 troilite-low 181 -4.411 0.0000E+00 corundum 59 8.383 0.0000E+00 tschermakite 182 48.210 0.0000E+00 corundum-MgSi 60 18.891 0.0000E+00 vesuvianite 183 223.471 0.0000E+00 cristobalite 61 -2.560 0.0000E+00 wadeite-Si 184 20.216 0.0000E+00 cummingtonite 62 52.099 0.0000E+00 wadsleyite-Fe 185 15.680 0.0000E+00 cymrite-K 63 1.685 0.0000E+00 wadsleyite-Mg 186 25.850 0.0000E+00 deerite 64 95.671 0.0000E+00 wairakite 187 3.950 0.0000E+00 diaspore 65 2.874 0.0000E+00 walstromite 188 11.509 0.0000E+00 diamond 66 -3.102 0.0000E+00 wollastonite 189 10.461 0.0000E+00 diopside 67 16.181 0.9952E-01 pseudo-wollastonite 190 11.000 0.0000E+00 hedenbergite 68 14.208 0.2581E-01 zoisite 191 22.849 0.0000E+00 dolomite,ordered 69 0.546 0.0000E+00 akaganeite 192 7.755 0.0000E+00 eastonite 70 28.489 0.0000E+00 beidellite-Ca 193 -1.646 0.0000E+00 enstatite 71 17.265 0.0000E+00 beidellite-H 194 -2.326 0.0000E+00 clinoenstatite-HiP 72 18.354 0.0000E+00 beidellite-K 195 -1.520 0.0000E+00 clinoenstatite 73 17.166 0.0000E+00 beidellite-Mg 196 -1.790 0.0000E+00 protoenstatite 74 17.824 0.0000E+00 beidellite-Na 197 -1.342 0.0000E+00 epidote 75 24.670 0.0000E+00 calcium 198 84.026 0.0000E+00 clinozoisite 76 22.806 0.0000E+00 chalcedony 199 -2.802 0.0000E+00 epidote-Fe 77 29.841 0.0000E+00 dawsonite 200 1.682 0.0000E+00 fayalite 78 14.046 0.0000E+00 montmorillonite-Ca 201 -2.291 0.0000E+00 ferrosilite 79 11.149 0.0000E+00 montmorillonite-K 202 -2.237 0.0000E+00 forsterite 80 21.016 0.0000E+00 montmorillonite-Mg 203 -2.480 0.0000E+00 gedrite 81 50.522 0.0000E+00 montmorillonite-Na 204 -2.038 0.0000E+00 gehlenite 82 36.628 0.0000E+00 nontronite-Ca 205 3.215 0.0000E+00 gibbsite 83 4.079 0.0000E+00 nontronite-H 206 2.533 0.0000E+00 glaucophane 84 22.975 0.0000E+00 nontronite-K 207 3.341 0.0000E+00 glaucophane-Fe 85 17.276 0.0000E+00 nontronite-Mg 208 3.075 0.0000E+00 graphite 86 -3.546 0.0000E+00 nontronite-Na 209 3.520 0.0000E+00 greenalite 87 16.140 0.0000E+00 sepiolite 210 24.118 0.0000E+00 grunerite 88 31.215 0.0000E+00 alite 211 57.999 0.0000E+00 halite 89 1.575 0.0000E+00 belite 212 30.433 0.0000E+00 hematite 90 12.566 0.0000E+00 ettringite 213 43.232 0.0000E+00 heulandite 91 -5.827 0.0000E+00 gypsum 214 -4.955 0.0000E+00 hercynite 92 17.279 0.0000E+00 hemicarboaluminate 215 70.954 0.0000E+00 hollandite 93 25.673 0.0000E+00 hydrogarnet 216 60.662 0.0000E+00 iron 94 19.086 0.0000E+00 hydrogarnet-Si 217 50.586 0.0000E+00 jadeite 95 4.215 0.0000E+00 jennite 218 24.367 0.0000E+00 julgoldite 96 70.427 0.0000E+00 monosulfoaluminate 219 53.400 0.0000E+00 kalsilite 97 7.584 0.0000E+00 monocarboaluminate 220 61.898 0.0000E+00 kaolinite 98 -1.333 0.0000E+00 portlandite 221 18.272 0.0000E+00 kyanite 99 4.876 0.0000E+00 stratlingite 222 36.502 0.0000E+00 larnite-bredigite 100 30.686 0.0000E+00 tricarboaluminate 223 70.370 0.0000E+00 laumontite 101 2.883 0.0000E+00 tobermorite 224 9.823 0.0000E+00 lawsonite 102 9.616 0.0000E+00 C4AH13 225 81.816 0.0000E+00 leucite 103 4.119 0.0000E+00 C2AH8 226 45.203 0.0000E+00 lime 104 25.998 0.0000E+00 C3A 227 86.953 0.0000E+00 lizardite 105 23.244 0.0000E+00 C4AF 228 117.416 0.0000E+00 magnesite 106 0.691 0.0000E+00 CAH10 229 28.335 0.0000E+00 magnetite 107 20.087 0.0000E+00 alabandite 230 -0.978 0.0000E+00 minnesotaite 108 10.388 0.0000E+00 alunite 231 -10.435 0.0000E+00 minnesotaite-Mg 109 20.602 0.0000E+00 artinite 232 15.121 0.0000E+00 magnesioferrite 110 26.212 0.0000E+00 boehmite 233 4.406 0.0000E+00 majorite 111 53.251 0.0000E+00 dolomite,disordered 234 1.247 0.0000E+00 manganosite 112 14.058 0.0000E+00 ferrous-oxide 235 9.812 0.0000E+00 margarite 113 17.324 0.0000E+00 huntite 236 3.770 0.0000E+00 meionite 114 44.874 0.0000E+00 hydromagnesite 237 19.995 0.0000E+00 merwinite 115 55.930 0.0000E+00 nesquehonite 238 4.723 0.0000E+00 microcline 116 -2.486 0.3723E+00 potassium-oxide 239 69.038 0.0000E+00 monticellite 117 24.339 0.0000E+00 silica-amorphous 240 -2.091 0.0000E+00 mullite-Al 118 363.148 0.0000E+00 sodium-oxide 241 55.169 0.0000E+00 mullite-Si 119 7.264 0.0000E+00 an20ab80 242 2.018 0.0000E+00 muscovite 120 2.582 0.0000E+00 an25ab75 243 2.646 0.0000E+00 paragonite 121 4.239 0.0000E+00 an30ab70 244 3.279 0.0000E+00 nepheline 122 8.339 0.0000E+00 tr.625ac.25prg.125 245 45.165 0.1747E-01 osumilite(1) 123 21.717 0.0000E+00 246 0.000 0.0000E+00 Initial composition of reactant (wt%): SiO2 62.56 MgO 3.200 Al2O3 16.62 CaO 6.450 FeO 3.530 Na2O 3.890 Fe2O3 1.770 K2O 1.000 MnO 0.1230 P2O5 0.4200E-01 Sum of wt% of reactants: 99.1850 Reactant consumed: 1999.9990000 g log = 3.3010 Original solution: 1000.0103000 g Original solution / Rock added: 0.50 (Water/Rock Ratio), log = -0.3010 The following minerals and/or gases with identical index are in solid solution: H2O,gas 6 CO2,gas 6 CH4,gas 6 H2,gas 6 H2S,gas 6 S2,gas 6 CO,gas 6 SO3,gas 6 SO2,gas 6 HCl,gas 6 almandine 16 pyrope 16 spessartine 16 andradite 8 grossular 8 annite 15 phlogopite 15 biotite-Mn 15 clinochlore 1 daphnite 1 chlorite-Mn 1 diopside 5 hedenbergite 5 epidote 3 clinozoisite 3 greenalite 18 iron 9 lizardite 18 magnetite 14 talc 7 talc-Fe 7 tremolite 2 ferroactinolite 2 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 13 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 1999.9990000 Water: Moles liquid = 0.4427E+02 kg liquid = 0.7976E+00 Moles total = 0.3044E+02 kg total = 0.5483E+00 Activity = 1.0000 Stoichiometric ionic strength = .1134661E-01 Osmotic coef. = 0.9692 True ionic strength = .2003063E-01 Chg. balance for total moles = 0.5220E-10 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.88347E-10 -10.0538 0.74231E-10 -10.1294 0.84022E+00 -0.0756 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.17219E-03 -3.7640 0.14381E-03 -3.8422 0.83516E+00 -0.0782 4 SO4-- 0.81138E-12 -12.0908 0.42129E-12 -12.3754 0.51922E+00 -0.2846 5 HCO3- 0.30024E-06 -6.5225 0.25112E-06 -6.6001 0.83639E+00 -0.0776 6 HS- 0.31970E-04 -4.4953 0.26704E-04 -4.5734 0.83529E+00 -0.0782 7 Al+++ 0.97106E-29 -29.0128 0.22426E-29 -29.6492 0.23095E+00 -0.6365 8 H4SiO4 0.69596E-03 -3.1574 0.69596E-03 -3.1574 0.10000E+01 0.0000 9 Ca++ 0.13516E-06 -6.8691 0.69664E-07 -7.1570 0.51541E+00 -0.2878 10 Mg++ 0.21145E-10 -10.6748 0.10849E-10 -10.9646 0.51305E+00 -0.2898 11 Fe++ 0.58279E-13 -13.2345 0.29933E-13 -13.5239 0.51361E+00 -0.2894 12 K+ 0.15661E-03 -3.8052 0.13102E-03 -3.8827 0.83658E+00 -0.0775 13 Na+ 0.19873E-01 -1.7017 0.16594E-01 -1.7800 0.83501E+00 -0.0783 14 Mn++ 0.18646E-10 -10.7294 0.95848E-11 -11.0184 0.51404E+00 -0.2890 15 HPO4-- 0.45274E-07 -7.3442 0.23511E-07 -7.6287 0.51930E+00 -0.2846 16 HSiO3- 0.10482E-01 -1.9795 0.87544E-02 -2.0578 0.83516E+00 -0.0782 17 Ca(HSiO3)+ 0.16598E-07 -7.7799 0.13889E-07 -7.8573 0.83676E+00 -0.0774 18 Mg(HSiO3)+ 0.32169E-11 -11.4926 0.26918E-11 -11.5700 0.83676E+00 -0.0774 19 NaHSiO3,aq 0.23496E-02 -2.6290 0.23496E-02 -2.6290 0.10000E+01 0.0000 20 AlO+ 0.66171E-16 -16.1793 0.55370E-16 -16.2567 0.83676E+00 -0.0774 22 HAlO2,aq 0.14855E-09 -9.8281 0.14855E-09 -9.8281 0.10000E+01 0.0000 23 AlO2- 0.53136E-05 -5.2746 0.44297E-05 -5.3536 0.83366E+00 -0.0790 24 CH4,aq 0.15516E-04 -4.8092 0.15462E-04 -4.8107 0.99654E+00 -0.0015 25 C2H6,aq 0.35406E-14 -14.4509 0.35283E-14 -14.4524 0.99654E+00 -0.0015 29 CO,aq 0.11590E-16 -16.9359 0.11590E-16 -16.9359 0.10000E+01 0.0000 30 CO2,aq 0.39969E-10 -10.3983 0.39830E-10 -10.3998 0.99654E+00 -0.0015 31 CO3-2 0.57030E-06 -6.2439 0.29548E-06 -6.5295 0.51812E+00 -0.2856 32 CaCO3,aq 0.25811E-09 -9.5882 0.25811E-09 -9.5882 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.53366E-12 -12.2727 0.44655E-12 -12.3501 0.83676E+00 -0.0774 34 CaCl+ 0.19376E-10 -10.7127 0.16213E-10 -10.7901 0.83676E+00 -0.0774 35 CaCl2,aq 0.55392E-15 -15.2565 0.55392E-15 -15.2565 0.10000E+01 0.0000 36 CaOH+ 0.79933E-07 -7.0973 0.66885E-07 -7.1747 0.83676E+00 -0.0774 37 CaSO4,aq 0.93195E-17 -17.0306 0.93195E-17 -17.0306 0.10000E+01 0.0000 38 HCl,aq 0.19562E-14 -14.7086 0.19562E-14 -14.7086 0.10000E+01 0.0000 43 FeCl+ 0.81426E-17 -17.0892 0.68135E-17 -17.1666 0.83676E+00 -0.0774 46 FeO,aq 0.21113E-09 -9.6755 0.21113E-09 -9.6755 0.10000E+01 0.0000 47 FeOH+ 0.15686E-10 -10.8045 0.13126E-10 -10.8819 0.83676E+00 -0.0774 48 HFeO2- 0.35633E-07 -7.4481 0.29759E-07 -7.5264 0.83516E+00 -0.0782 49 FeO+ 0.10993E-16 -16.9589 0.91989E-17 -17.0363 0.83676E+00 -0.0774 51 FeO2- 0.40902E-09 -9.3883 0.34160E-09 -9.4665 0.83516E+00 -0.0782 52 HFeO2,aq 0.32251E-11 -11.4915 0.32251E-11 -11.4915 0.10000E+01 0.0000 53 H2,aq 0.11624E-04 -4.9347 0.11583E-04 -4.9362 0.99654E+00 -0.0015 54 KCl,aq 0.34148E-09 -9.4666 0.34148E-09 -9.4666 0.10000E+01 0.0000 56 KOH,aq 0.75375E-06 -6.1228 0.75375E-06 -6.1228 0.10000E+01 0.0000 57 KSO4- 0.10255E-14 -14.9890 0.85650E-15 -15.0673 0.83516E+00 -0.0782 58 MgCO3,aq 0.10075E-13 -13.9968 0.10075E-13 -13.9968 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.84918E-16 -16.0710 0.71057E-16 -16.1484 0.83676E+00 -0.0774 60 MgCl+ 0.27347E-14 -14.5631 0.22883E-14 -14.6405 0.83676E+00 -0.0774 61 MgOH+ 0.68880E-10 -10.1619 0.57636E-10 -10.2393 0.83676E+00 -0.0774 63 MnO,aq 0.18014E-08 -8.7444 0.18014E-08 -8.7444 0.10000E+01 0.0000 64 MnOH+ 0.46662E-09 -9.3310 0.39045E-09 -9.4084 0.83676E+00 -0.0774 65 MnO2-2 0.20940E-10 -10.6790 0.10850E-10 -10.9646 0.51812E+00 -0.2856 66 HMnO2- 0.21127E-09 -9.6752 0.17644E-09 -9.7534 0.83516E+00 -0.0782 69 MnCl+ 0.10144E-13 -13.9938 0.84880E-14 -14.0712 0.83676E+00 -0.0774 71 NaCl,aq 0.79085E-06 -6.1019 0.79085E-06 -6.1019 0.10000E+01 0.0000 72 NaOH,aq 0.96047E-04 -4.0175 0.96047E-04 -4.0175 0.10000E+01 0.0000 74 OH- 0.93366E-02 -2.0298 0.77835E-02 -2.1088 0.83366E+00 -0.0790 79 HPO3-2 0.16380E-14 -14.7857 0.84869E-15 -15.0713 0.51812E+00 -0.2856 81 H2PO3- 0.15126E-18 -18.8203 0.12633E-18 -18.8985 0.83516E+00 -0.0782 82 H3PO4,aq 0.90606E-18 -18.0428 0.90606E-18 -18.0428 0.10000E+01 0.0000 83 H2PO4- 0.38512E-10 -10.4144 0.32194E-10 -10.4922 0.83596E+00 -0.0778 84 PO4-3 0.10653E-08 -8.9725 0.25841E-09 -9.5877 0.24257E+00 -0.6152 88 HP2O7-3 0.94565E-18 -18.0243 0.21861E-18 -18.6603 0.23118E+00 -0.6361 89 P2O7-4 0.91303E-17 -17.0395 0.70357E-18 -18.1527 0.77059E-01 -1.1132 90 H2S,aq 0.61477E-08 -8.2113 0.61264E-08 -8.2128 0.99654E+00 -0.0015 91 S2-2 0.26328E-14 -14.5796 0.13641E-14 -14.8652 0.51812E+00 -0.2856 97 SO3-2 0.12065E-17 -17.9185 0.63415E-18 -18.1978 0.52562E+00 -0.2793 99 HSO4- 0.35982E-19 -19.4439 0.30138E-19 -19.5209 0.83758E+00 -0.0770 Charge balance for all species = 0.6546E-10 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.8834674E-10 -.2229013E-01 -.2242806E+02 0.0000 2 H2O 0.1000000E+01 0.5550489E+02 0.9981989E+06 0.0000 3 Cl- 0.1721924E-03 0.1729836E-03 0.6122127E+01 6.2872 4 SO4-- 0.8113774E-12 -.1842139E-04 -.1766512E+01 7.8834 5 HCO3- 0.3002393E-06 0.1638637E-04 0.9981123E+00 3.5293 6 HS- 0.3196980E-04 0.5039734E-04 0.1663843E+01 5.5560 7 Al+++ 0.9710648E-29 0.5313773E-05 0.1431243E+00 0.7390 8 H4SiO4 0.6959572E-03 0.1352779E-01 0.1297968E+04 -3.1574 9 Ca++ 0.1351622E-06 0.2319717E-06 0.9280798E-02 13.1018 10 Mg++ 0.2114527E-10 0.9325458E-10 0.2263264E-05 9.2942 11 Fe++ 0.5827877E-13 0.3627213E-07 0.2022168E-02 6.7350 12 K+ 0.1566089E-03 0.1573630E-03 0.6142512E+01 6.2467 13 Na+ 0.1987290E-01 0.2231930E-01 0.5122243E+03 8.3494 14 Mn++ 0.1864599E-10 0.2518880E-08 0.1381416E-03 9.2404 15 HPO4-- 0.4527408E-07 0.4637792E-07 0.4443568E-02 12.6301 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.3311700E+02 -.1777892E-01 -.3309922E+02 0.0000000E+00 2 H2O 0.3043744E+02 0.4427148E+02 -.1383404E+02 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.5545229E-01 -.1469316E-04 0.5546699E-01 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.5542679E-01 0.4019763E-04 -.5546699E-01 0.0000000E+00 7 Al+++ 0.6521480E+01 0.4238340E-05 0.6521476E+01 0.0000000E+00 8 H4SiO4 0.2082556E+02 0.1078995E-01 0.2081477E+02 0.0000000E+00 9 Ca++ 0.2300299E+01 0.1850239E-06 0.2300298E+01 0.0000000E+00 10 Mg++ 0.1587301E+01 0.7438117E-10 0.1587301E+01 0.0000000E+00 11 Fe++ 0.1426016E+01 0.2893117E-07 0.1426016E+01 0.0000000E+00 12 K+ 0.4246282E+00 0.1255150E-03 0.4245027E+00 0.0000000E+00 13 Na+ 0.2510646E+01 0.1780219E-01 0.2492844E+01 0.0000000E+00 14 Mn++ 0.3467717E-01 0.2009094E-08 0.3467717E-01 0.0000000E+00 15 HPO4-- 0.1183515E-01 0.3699168E-07 0.1183511E-01 0.0000000E+00 Chg. balance for solid moles: -.9374E-14 Mass of aqueous solution: 0.799003E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 1999.9990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 2.491 0.396 653.1 2.815 29.89 250.7 andradite 0.2219 -0.654 112.7 2.052 5.161 29.29 grossular 0.5373E-01 -1.270 24.20 1.384 1.108 6.734 apatite-OH 0.3945E-02 -2.404 1.982 0.297 0.9070E-01 0.6297 clinochlore 0.2849 -0.545 158.4 2.200 7.248 60.23 daphnite 0.8247E-01 -1.084 58.84 1.770 2.693 17.83 chlorite-Mn 0.6935E-02 -2.159 4.917 0.692 0.2251 1.567 diopside 0.9952E-01 -1.002 21.55 1.333 0.9865 6.587 hedenbergite 0.2581E-01 -1.588 6.403 0.806 0.2931 1.754 microcline 0.3723 -0.429 103.6 2.015 4.743 40.48 stilbite 1.294 0.112 911.6 2.960 41.72 425.2 stilpnomelane-Fe 0.1045 -0.981 112.6 2.052 5.154 38.90 tr.625ac.25prg.125 0.1747E-01 -1.758 14.93 1.174 0.6834 4.806 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8050E+00 0.8050E+00 1.0000 -0.094 grossular 0.1950E+00 0.1950E+00 1.0000 -0.710 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.7611E+00 0.7611E+00 1.0000 -0.119 daphnite 0.2203E+00 0.2203E+00 1.0000 -0.657 chlorite-Mn 0.1853E-01 0.1853E-01 1.0000 -1.732 diopside 0.7941E+00 0.7941E+00 1.0000 -0.100 hedenbergite 0.2059E+00 0.2059E+00 1.0000 -0.686 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 tr.625ac.25prg.125 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 2184.817926 g Volume = 884.685933 cm3 Porosity: -10.4477% V(tot) - V(min): -.83686E+02 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 1999.9990000 g log = 3.3010 Original solution: 1000.0103000 g Original solution / Rock added: 0.50 (Water/Rock Ratio), log = -0.3010 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0585 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9644E+00 0.9854 0.1006E+01 0.1021E+01 CO2,gas 0.3998E-08 1.0069 0.4261E-08 0.4232E-08 CH4,gas 0.2124E-01 1.0124 0.2276E-01 0.2248E-01 H2,gas 0.1436E-01 1.0006 0.1521E-01 0.1520E-01 H2S,gas 0.1598E-06 0.9959 0.1684E-06 0.1691E-06 S2,gas 0.4349E-29 1.0000 0.4603E-29 0.4603E-29 CO,gas 0.1632E-13 1.0000 0.1727E-13 0.1727E-13 SO3,gas 0.8292E-48 1.0000 0.8777E-48 0.8777E-48 SO2,gas 0.4906E-27 1.0000 0.5193E-27 0.5193E-27 HCl,gas 0.3261E-17 1.0000 0.3452E-17 0.3452E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 16 albite -0.38 -0.38 0.00 0.000 -0.94784E-12 22 andradite 39.01 39.01 0.00 0.000 -0.12132E-10 23 grossular 32.73 32.73 0.00 0.000 0.12132E-10 32 apatite-OH -18.15 -18.15 0.00 0.000 -0.60662E-11 46 clinochlore 39.07 39.07 0.00 0.000 -0.36397E-10 47 daphnite 28.97 28.97 0.00 0.000 0.12132E-10 48 chlorite-Mn 46.87 46.87 0.00 0.000 -0.36397E-10 67 diopside 16.18 16.18 0.00 0.000 0.60662E-11 68 hedenbergite 14.21 14.21 0.00 0.000 0.00000E+00 116 microcline -2.49 -2.49 0.00 0.000 0.15165E-11 163 stilbite -7.52 -7.52 0.00 0.000 -0.33364E-10 164 stilpnomelane-Fe 13.02 13.02 0.00 0.000 -0.27298E-10 245 tr.625ac.25prg.125 45.16 45.16 0.00 0.000 -0.12132E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -16.73 -10.07 -3.356 0.17193E+05 -8.370 3 CH4,gas 4.54 1.20 -3.34 -0.835 0.57061E+04 -1.643 4 H2,gas 8.00 4.48 -3.52 -2.010 0.60050E+04 -1.818 5 H2S,gas -6.23 -14.70 -8.47 -4.236 0.14467E+05 -6.774 6 S2,gas -7.34 -38.37 -31.04 -4.775 0.52993E+05 -29.337 7 CO,gas 3.21 -12.25 -15.46 -4.757 0.26400E+05 -13.763 8 SO3,gas 17.12 -32.63 -49.76 -12.439 0.84956E+05 -48.057 9 SO2,gas 0.83 -28.15 -28.98 -7.729 0.49489E+05 -27.285 10 HCl,gas 5.19 -13.97 -19.16 -9.580 0.32717E+05 -17.462 11 acmite 7.71 6.53 -1.18 -0.123 0.20176E+04 15 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 19 spessartine 24.46 19.73 -4.73 -0.237 0.80769E+04 20 analcite 3.32 2.77 -0.55 -0.061 0.93623E+03 26 annite 20.12 17.72 -2.40 -0.134 0.41064E+04 27 phlogopite 27.06 25.40 -1.67 -0.093 0.28488E+04 29 anorthite 12.71 8.27 -4.45 -0.342 0.75902E+04 35 aragonite 0.97 -3.63 -4.59 -1.531 0.78445E+04 36 brucite 12.57 9.29 -3.27 -0.655 0.55909E+04 37 calcite 0.81 -3.63 -4.44 -1.480 0.75803E+04 38 carnegieite-low 9.02 5.93 -3.09 -0.442 0.52801E+04 39 carnegieite-high 10.09 5.93 -4.16 -0.595 0.71071E+04 40 carpholite-Mg 8.58 4.46 -4.12 -0.275 0.70428E+04 41 carpholite-Fe 6.71 1.90 -4.81 -0.321 0.82206E+04 42 celadonite 5.34 3.65 -1.69 -0.099 0.28879E+04 43 celadonite-Fe 3.88 1.09 -2.79 -0.164 0.47561E+04 44 chrysotile 23.89 21.57 -2.32 -0.194 0.39692E+04 49 chlorite-Al-free 47.17 43.14 -4.04 -0.168 0.68935E+04 51 chloritoid-Fe 9.17 5.06 -4.12 -0.275 0.70314E+04 52 chloritoid-Mn 11.40 7.56 -3.84 -0.256 0.65568E+04 54 coesite -2.38 -3.16 -0.78 -0.260 0.13341E+04 61 cristobalite -2.56 -3.16 -0.60 -0.199 0.10195E+04 63 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71234E+04 65 diaspore 2.87 0.74 -2.13 -0.356 0.36449E+04 66 diamond -3.10 -7.76 -4.66 -1.332 0.79593E+04 71 enstatite 17.26 12.27 -4.99 -0.499 0.85225E+04 73 clinoenstatite 17.17 12.27 -4.89 -0.489 0.83541E+04 75 epidote 24.67 22.70 -1.97 -0.095 0.33584E+04 76 clinozoisite 22.81 18.95 -3.86 -0.175 0.65867E+04 77 epidote-Fe 29.84 26.46 -3.38 -0.176 0.57768E+04 78 fayalite 14.05 10.31 -3.73 -0.533 0.63743E+04 79 ferrosilite 11.15 7.16 -3.99 -0.399 0.68202E+04 83 gibbsite 4.08 0.74 -3.34 -0.477 0.57035E+04 84 glaucophane 22.97 20.80 -2.17 -0.059 0.37133E+04 85 glaucophane-Fe 17.28 13.12 -4.15 -0.112 0.70919E+04 86 graphite -3.55 -7.76 -4.22 -1.205 0.72015E+04 87 greenalite 16.14 13.89 -2.25 -0.187 0.38408E+04 90 hematite 12.57 8.99 -3.58 -0.434 0.61112E+04 91 heulandite -5.83 -7.52 -1.69 -0.077 0.28938E+04 95 jadeite 4.22 2.77 -1.44 -0.144 0.24617E+04 97 kalsilite 7.58 3.83 -3.76 -0.537 0.64125E+04 98 kaolinite -1.33 -4.84 -3.50 -0.319 0.59831E+04 101 laumontite 2.88 1.95 -0.93 -0.062 0.15934E+04 102 lawsonite 9.62 8.27 -1.35 -0.090 0.23069E+04 103 leucite 4.12 0.67 -3.45 -0.345 0.58873E+04 105 lizardite 23.24 21.57 -1.68 -0.140 0.28618E+04 107 magnetite 20.09 15.72 -4.37 -0.356 0.74536E+04 108 minnesotaite 10.39 7.58 -2.81 -0.165 0.48028E+04 112 manganosite 14.06 9.24 -4.82 -1.204 0.82261E+04 120 muscovite 2.58 -1.01 -3.59 -0.211 0.61314E+04 121 paragonite 4.24 1.09 -3.15 -0.185 0.53705E+04 122 nepheline 8.34 5.93 -2.41 -0.344 0.41124E+04 128 periclase-Fe 11.63 6.73 -4.89 -1.223 0.83523E+04 134 phlogopite-Na 29.65 27.50 -2.15 -0.119 0.36677E+04 136 prehnite 19.37 18.21 -1.16 -0.068 0.19848E+04 137 prehnite-Fe 22.50 21.96 -0.53 -0.032 0.91155E+03 138 pumpellyite-Fe 46.27 43.89 -2.38 -0.053 0.40578E+04 139 pumpellyite-Mg 48.99 46.45 -2.54 -0.057 0.43416E+04 143 pyrrhotite -4.26 -7.97 -3.71 -1.236 0.63305E+04 144 pyrrhotiteFe0.875 -6.02 -9.37 -3.35 -1.232 0.57177E+04 145 pyroxmangite 7.40 6.08 -1.32 -0.263 0.22465E+04 146 pyrophyllite -6.18 -11.15 -4.98 -0.311 0.84961E+04 147 quartz -2.99 -3.16 -0.17 -0.056 0.28682E+03 152 rhodonite 7.45 6.08 -1.36 -0.273 0.23267E+04 153 sanidine -1.28 -2.49 -1.21 -0.093 0.20677E+04 165 stilpnomelane-Mg 27.44 25.81 -1.63 -0.049 0.27803E+04 171 talc 16.49 15.25 -1.24 -0.073 0.21140E+04 174 tephroite 18.09 15.32 -2.76 -0.395 0.47167E+04 178 tridymite -2.63 -3.16 -0.53 -0.177 0.90680E+03 179 tremolite 47.87 47.42 -0.45 -0.012 0.77495E+03 180 ferroactinolite 38.45 34.62 -3.83 -0.104 0.65449E+04 181 troilite-low -4.41 -7.97 -3.56 -1.186 0.60733E+04 183 vesuvianite 223.47 218.82 -4.65 -0.036 0.79430E+04 187 wairakite 3.95 1.95 -2.00 -0.118 0.34154E+04 188 walstromite 11.51 9.94 -1.56 -0.313 0.26719E+04 189 wollastonite 10.46 9.94 -0.52 -0.103 0.88229E+03 190 pseudo-wollastonite 11.00 9.94 -1.06 -0.211 0.18021E+04 191 zoisite 22.85 18.95 -3.90 -0.177 0.66607E+04 192 akaganeite 7.75 4.49 -3.26 -0.705 0.55681E+04 199 chalcedony -2.80 -3.16 -0.35 -0.118 0.60612E+03 201 montmorillonite-Ca -2.29 -6.17 -3.88 -0.240 0.66180E+04 202 montmorillonite-K -2.24 -6.27 -4.03 -0.247 0.68816E+04 203 montmorillonite-Mg -2.48 -6.79 -4.32 -0.267 0.73678E+04 204 montmorillonite-Na -2.04 -5.57 -3.54 -0.216 0.60365E+04 205 nontronite-Ca 3.21 -0.19 -3.41 -0.221 0.58216E+04 206 nontronite-H 2.53 -2.36 -4.89 -0.328 0.83486E+04 207 nontronite-K 3.34 -0.30 -3.64 -0.233 0.62084E+04 208 nontronite-Mg 3.07 -0.82 -3.90 -0.253 0.66554E+04 209 nontronite-Na 3.52 0.40 -3.12 -0.200 0.53293E+04 224 tobermorite 9.82 7.76 -2.07 -0.564 0.35287E+04 230 alabandite -0.98 -5.46 -4.48 -1.495 0.76573E+04 233 boehmite 4.41 0.74 -3.67 -0.611 0.62618E+04 235 ferrous-oxide 9.81 6.73 -3.08 -0.769 0.52532E+04 240 silica-amorphous -2.09 -3.16 -1.07 -0.355 0.18203E+04 242 an20ab80 2.02 1.35 -0.67 -0.052 0.11472E+04 243 an25ab75 2.65 1.78 -0.87 -0.067 0.14810E+04 244 an30ab70 3.28 2.21 -1.07 -0.082 0.18243E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 100.0000000 g Current total amount of reactant added: 1999.9990000 g New total amount of reactant added: 2099.9990000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.5220E-10 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 11 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 2099.9990000 Water: Moles liquid = 0.4372E+02 kg liquid = 0.7876E+00 Moles total = 0.2918E+02 kg total = 0.5258E+00 Activity = 1.0000 Stoichiometric ionic strength = .1134844E-01 Osmotic coef. = 0.9691 True ionic strength = .2003206E-01 Chg. balance for total moles = 0.5220E-10 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.88353E-10 -10.0538 0.74236E-10 -10.1294 0.84022E+00 -0.0756 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.17439E-03 -3.7585 0.14564E-03 -3.8367 0.83516E+00 -0.0782 4 SO4-- 0.82170E-12 -12.0853 0.42664E-12 -12.3699 0.51921E+00 -0.2847 5 HCO3- 0.30406E-06 -6.5170 0.25431E-06 -6.5946 0.83638E+00 -0.0776 6 HS- 0.32377E-04 -4.4898 0.27044E-04 -4.5679 0.83528E+00 -0.0782 7 Al+++ 0.97129E-29 -29.0126 0.22431E-29 -29.6492 0.23094E+00 -0.6365 8 H4SiO4 0.69596E-03 -3.1574 0.69596E-03 -3.1574 0.10000E+01 0.0000 9 Ca++ 0.13518E-06 -6.8691 0.69673E-07 -7.1569 0.51540E+00 -0.2879 10 Mg++ 0.21148E-10 -10.6747 0.10850E-10 -10.9646 0.51304E+00 -0.2898 11 Fe++ 0.58288E-13 -13.2344 0.29937E-13 -13.5238 0.51360E+00 -0.2894 12 K+ 0.15662E-03 -3.8052 0.13103E-03 -3.8826 0.83658E+00 -0.0775 13 Na+ 0.19874E-01 -1.7017 0.16595E-01 -1.7800 0.83501E+00 -0.0783 14 Mn++ 0.18653E-10 -10.7293 0.95881E-11 -11.0183 0.51403E+00 -0.2890 15 HPO4-- 0.45269E-07 -7.3442 0.23508E-07 -7.6288 0.51929E+00 -0.2846 16 HSiO3- 0.10482E-01 -1.9796 0.87538E-02 -2.0578 0.83516E+00 -0.0782 17 Ca(HSiO3)+ 0.16600E-07 -7.7799 0.13890E-07 -7.8573 0.83676E+00 -0.0774 18 Mg(HSiO3)+ 0.32171E-11 -11.4925 0.26919E-11 -11.5699 0.83676E+00 -0.0774 19 NaHSiO3,aq 0.23496E-02 -2.6290 0.23496E-02 -2.6290 0.10000E+01 0.0000 20 AlO+ 0.66175E-16 -16.1793 0.55373E-16 -16.2567 0.83676E+00 -0.0774 22 HAlO2,aq 0.14855E-09 -9.8281 0.14855E-09 -9.8281 0.10000E+01 0.0000 23 AlO2- 0.53133E-05 -5.2746 0.44294E-05 -5.3537 0.83365E+00 -0.0790 24 CH4,aq 0.15713E-04 -4.8037 0.15659E-04 -4.8052 0.99654E+00 -0.0015 25 C2H6,aq 0.36315E-14 -14.4399 0.36189E-14 -14.4414 0.99654E+00 -0.0015 29 CO,aq 0.11738E-16 -16.9304 0.11738E-16 -16.9304 0.10000E+01 0.0000 30 CO2,aq 0.40479E-10 -10.3928 0.40339E-10 -10.3943 0.99654E+00 -0.0015 31 CO3-2 0.57752E-06 -6.2384 0.29922E-06 -6.5240 0.51811E+00 -0.2856 32 CaCO3,aq 0.26141E-09 -9.5827 0.26141E-09 -9.5827 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.54051E-12 -12.2672 0.45228E-12 -12.3446 0.83676E+00 -0.0774 34 CaCl+ 0.19625E-10 -10.7072 0.16422E-10 -10.7846 0.83676E+00 -0.0774 35 CaCl2,aq 0.56821E-15 -15.2455 0.56821E-15 -15.2455 0.10000E+01 0.0000 36 CaOH+ 0.79938E-07 -7.0972 0.66889E-07 -7.1746 0.83676E+00 -0.0774 37 CaSO4,aq 0.94391E-17 -17.0251 0.94391E-17 -17.0251 0.10000E+01 0.0000 38 HCl,aq 0.19812E-14 -14.7031 0.19812E-14 -14.7031 0.10000E+01 0.0000 43 FeCl+ 0.82476E-17 -17.0837 0.69012E-17 -17.1611 0.83676E+00 -0.0774 46 FeO,aq 0.21113E-09 -9.6755 0.21113E-09 -9.6755 0.10000E+01 0.0000 47 FeOH+ 0.15688E-10 -10.8044 0.13127E-10 -10.8818 0.83676E+00 -0.0774 48 HFeO2- 0.35631E-07 -7.4482 0.29757E-07 -7.5264 0.83516E+00 -0.0782 49 FeO+ 0.10994E-16 -16.9588 0.91995E-17 -17.0362 0.83676E+00 -0.0774 51 FeO2- 0.40900E-09 -9.3883 0.34158E-09 -9.4665 0.83516E+00 -0.0782 52 HFeO2,aq 0.32251E-11 -11.4915 0.32251E-11 -11.4915 0.10000E+01 0.0000 53 H2,aq 0.11624E-04 -4.9347 0.11583E-04 -4.9362 0.99654E+00 -0.0015 54 KCl,aq 0.34586E-09 -9.4611 0.34586E-09 -9.4611 0.10000E+01 0.0000 56 KOH,aq 0.75375E-06 -6.1228 0.75375E-06 -6.1228 0.10000E+01 0.0000 57 KSO4- 0.10387E-14 -14.9835 0.86744E-15 -15.0618 0.83516E+00 -0.0782 58 MgCO3,aq 0.10204E-13 -13.9912 0.10204E-13 -13.9912 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.86009E-16 -16.0655 0.71969E-16 -16.1429 0.83676E+00 -0.0774 60 MgCl+ 0.27700E-14 -14.5575 0.23178E-14 -14.6349 0.83676E+00 -0.0774 61 MgOH+ 0.68884E-10 -10.1619 0.57640E-10 -10.2393 0.83676E+00 -0.0774 63 MnO,aq 0.18018E-08 -8.7443 0.18018E-08 -8.7443 0.10000E+01 0.0000 64 MnOH+ 0.46675E-09 -9.3309 0.39056E-09 -9.4083 0.83676E+00 -0.0774 65 MnO2-2 0.20942E-10 -10.6790 0.10850E-10 -10.9646 0.51811E+00 -0.2856 66 HMnO2- 0.21130E-09 -9.6751 0.17647E-09 -9.7533 0.83516E+00 -0.0782 69 MnCl+ 0.10277E-13 -13.9881 0.85991E-14 -14.0655 0.83676E+00 -0.0774 71 NaCl,aq 0.80099E-06 -6.0964 0.80099E-06 -6.0964 0.10000E+01 0.0000 72 NaOH,aq 0.96047E-04 -4.0175 0.96047E-04 -4.0175 0.10000E+01 0.0000 74 OH- 0.93360E-02 -2.0298 0.77830E-02 -2.1089 0.83365E+00 -0.0790 79 HPO3-2 0.16378E-14 -14.7857 0.84857E-15 -15.0713 0.51811E+00 -0.2856 81 H2PO3- 0.15126E-18 -18.8203 0.12632E-18 -18.8985 0.83516E+00 -0.0782 82 H3PO4,aq 0.90606E-18 -18.0428 0.90606E-18 -18.0428 0.10000E+01 0.0000 83 H2PO4- 0.38510E-10 -10.4144 0.32192E-10 -10.4922 0.83595E+00 -0.0778 84 PO4-3 0.10652E-08 -8.9726 0.25836E-09 -9.5878 0.24256E+00 -0.6152 88 HP2O7-3 0.94551E-18 -18.0243 0.21857E-18 -18.6604 0.23117E+00 -0.6361 89 P2O7-4 0.91286E-17 -17.0396 0.70339E-18 -18.1528 0.77053E-01 -1.1132 90 H2S,aq 0.62264E-08 -8.2058 0.62049E-08 -8.2073 0.99654E+00 -0.0015 91 S2-2 0.27004E-14 -14.5686 0.13991E-14 -14.8542 0.51811E+00 -0.2856 97 SO3-2 0.12218E-17 -17.9130 0.64220E-18 -18.1923 0.52561E+00 -0.2793 99 HSO4- 0.36442E-19 -19.4384 0.30523E-19 -19.5154 0.83758E+00 -0.0770 Charge balance for all species = 0.6629E-10 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.8835301E-10 -.2228895E-01 -.2242686E+02 0.0000 2 H2O 0.1000000E+01 0.5550489E+02 0.9981988E+06 0.0000 3 Cl- 0.1743881E-03 0.1751894E-03 0.6200192E+01 6.2927 4 SO4-- 0.8216999E-12 -.1861928E-04 -.1785488E+01 7.8888 5 HCO3- 0.3040572E-06 0.1659532E-04 0.1010840E+01 3.5347 6 HS- 0.3237746E-04 0.5100297E-04 0.1683838E+01 5.5615 7 Al+++ 0.9712926E-29 0.5313406E-05 0.1431144E+00 0.7390 8 H4SiO4 0.6959590E-03 0.1352717E-01 0.1297909E+04 -3.1574 9 Ca++ 0.1351824E-06 0.2320021E-06 0.9282015E-02 13.1018 10 Mg++ 0.2114843E-10 0.9326324E-10 0.2263474E-05 9.2942 11 Fe++ 0.5828758E-13 0.3626988E-07 0.2022042E-02 6.7350 12 K+ 0.1566201E-03 0.1573742E-03 0.6142946E+01 6.2467 13 Na+ 0.1987431E-01 0.2232073E-01 0.5122571E+03 8.3494 14 Mn++ 0.1865276E-10 0.2519431E-08 0.1381718E-03 9.2405 15 HPO4-- 0.4526910E-07 0.4637278E-07 0.4443075E-02 12.6300 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.3477285E+02 -.1755414E-01 -.3475530E+02 0.0000000E+00 2 H2O 0.2918390E+02 0.4371407E+02 -.1453017E+02 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.5822364E-01 -.1466401E-04 0.5823830E-01 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.5819813E-01 0.4016848E-04 -.5823830E-01 0.0000000E+00 7 Al+++ 0.6847554E+01 0.4184687E-05 0.6847550E+01 0.0000000E+00 8 H4SiO4 0.2186683E+02 0.1065362E-01 0.2185618E+02 0.0000000E+00 9 Ca++ 0.2415313E+01 0.1827182E-06 0.2415313E+01 0.0000000E+00 10 Mg++ 0.1666666E+01 0.7345147E-10 0.1666666E+01 0.0000000E+00 11 Fe++ 0.1497317E+01 0.2856512E-07 0.1497317E+01 0.0000000E+00 12 K+ 0.4458597E+00 0.1239434E-03 0.4457357E+00 0.0000000E+00 13 Na+ 0.2636170E+01 0.1757917E-01 0.2618591E+01 0.0000000E+00 14 Mn++ 0.3641103E-01 0.1984232E-08 0.3641103E-01 0.0000000E+00 15 HPO4-- 0.1242690E-01 0.3652188E-07 0.1242687E-01 0.0000000E+00 Chg. balance for solid moles: -.2335E-14 Mass of aqueous solution: 0.788943E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 2099.9990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 2.616 0.418 686.0 2.836 29.91 263.4 andradite 0.2330 -0.633 118.4 2.073 5.160 30.76 grossular 0.5641E-01 -1.249 25.41 1.405 1.108 7.071 apatite-OH 0.4142E-02 -2.383 2.081 0.318 0.9070E-01 0.6612 clinochlore 0.2991 -0.524 166.2 2.221 7.246 63.23 daphnite 0.8658E-01 -1.063 61.77 1.791 2.693 18.72 chlorite-Mn 0.7282E-02 -2.138 5.163 0.713 0.2251 1.645 diopside 0.1050 -0.979 22.73 1.357 0.9908 6.947 hedenbergite 0.2722E-01 -1.565 6.753 0.830 0.2944 1.850 microcline 0.3909 -0.408 108.8 2.037 4.743 42.50 stilbite 1.358 0.133 956.8 2.981 41.71 446.3 stilpnomelane-Fe 0.1097 -0.960 118.2 2.073 5.154 40.84 tr.625ac.25prg.125 0.1830E-01 -1.737 15.64 1.194 0.6820 5.035 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8050E+00 0.8050E+00 1.0000 -0.094 grossular 0.1950E+00 0.1950E+00 1.0000 -0.710 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.7611E+00 0.7611E+00 1.0000 -0.119 daphnite 0.2203E+00 0.2203E+00 1.0000 -0.657 chlorite-Mn 0.1853E-01 0.1853E-01 1.0000 -1.732 diopside 0.7941E+00 0.7941E+00 1.0000 -0.100 hedenbergite 0.2059E+00 0.2059E+00 1.0000 -0.686 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 tr.625ac.25prg.125 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 2294.068590 g Volume = 928.888997 cm3 Porosity: -10.4506% V(tot) - V(min): -.87889E+02 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 2099.9990000 g log = 3.3222 Original solution: 1000.0103000 g Original solution / Rock added: 0.48 (Water/Rock Ratio), log = -0.3222 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0588 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9641E+00 0.9854 0.1006E+01 0.1021E+01 CO2,gas 0.4048E-08 1.0069 0.4316E-08 0.4286E-08 CH4,gas 0.2150E-01 1.0124 0.2305E-01 0.2277E-01 H2,gas 0.1435E-01 1.0006 0.1521E-01 0.1520E-01 H2S,gas 0.1618E-06 0.9959 0.1706E-06 0.1713E-06 S2,gas 0.4460E-29 1.0000 0.4722E-29 0.4722E-29 CO,gas 0.1652E-13 1.0000 0.1749E-13 0.1749E-13 SO3,gas 0.8396E-48 1.0000 0.8890E-48 0.8890E-48 SO2,gas 0.4968E-27 1.0000 0.5260E-27 0.5260E-27 HCl,gas 0.3302E-17 1.0000 0.3496E-17 0.3496E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 16 albite -0.38 -0.38 0.00 0.000 -0.94784E-12 22 andradite 39.01 39.01 0.00 0.000 -0.12132E-10 23 grossular 32.73 32.73 0.00 0.000 -0.24265E-10 32 apatite-OH -18.15 -18.15 0.00 0.000 0.00000E+00 46 clinochlore 39.07 39.07 0.00 0.000 0.00000E+00 47 daphnite 28.97 28.97 0.00 0.000 0.60662E-10 48 chlorite-Mn 46.87 46.87 0.00 0.000 0.12132E-10 67 diopside 16.18 16.18 0.00 0.000 0.60662E-11 68 hedenbergite 14.21 14.21 0.00 0.000 0.60662E-11 116 microcline -2.49 -2.49 0.00 0.000 0.15165E-11 163 stilbite -7.52 -7.52 0.00 0.000 0.15165E-10 164 stilpnomelane-Fe 13.02 13.02 0.00 0.000 0.21232E-10 245 tr.625ac.25prg.125 45.16 45.16 0.00 0.000 0.00000E+00 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -16.72 -10.06 -3.355 0.17184E+05 -8.365 3 CH4,gas 4.54 1.21 -3.34 -0.834 0.56967E+04 -1.637 4 H2,gas 8.00 4.48 -3.52 -2.010 0.60050E+04 -1.818 5 H2S,gas -6.23 -14.70 -8.47 -4.234 0.14457E+05 -6.768 6 S2,gas -7.34 -38.36 -31.02 -4.773 0.52974E+05 -29.326 7 CO,gas 3.21 -12.24 -15.46 -4.756 0.26391E+05 -13.757 8 SO3,gas 17.12 -32.63 -49.75 -12.438 0.84947E+05 -48.051 9 SO2,gas 0.83 -28.15 -28.98 -7.727 0.49479E+05 -27.279 10 HCl,gas 5.19 -13.97 -19.16 -9.578 0.32707E+05 -17.456 11 acmite 7.71 6.53 -1.18 -0.123 0.20176E+04 15 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 19 spessartine 24.46 19.73 -4.73 -0.237 0.80764E+04 20 analcite 3.32 2.77 -0.55 -0.061 0.93623E+03 26 annite 20.12 17.72 -2.40 -0.134 0.41064E+04 27 phlogopite 27.06 25.40 -1.67 -0.093 0.28489E+04 29 anorthite 12.71 8.27 -4.45 -0.342 0.75902E+04 35 aragonite 0.97 -3.62 -4.59 -1.530 0.78351E+04 36 brucite 12.57 9.29 -3.27 -0.655 0.55909E+04 37 calcite 0.81 -3.62 -4.43 -1.478 0.75709E+04 38 carnegieite-low 9.02 5.93 -3.09 -0.442 0.52801E+04 39 carnegieite-high 10.09 5.93 -4.16 -0.595 0.71071E+04 40 carpholite-Mg 8.58 4.46 -4.12 -0.275 0.70428E+04 41 carpholite-Fe 6.71 1.90 -4.81 -0.321 0.82206E+04 42 celadonite 5.34 3.65 -1.69 -0.099 0.28879E+04 43 celadonite-Fe 3.88 1.09 -2.79 -0.164 0.47561E+04 44 chrysotile 23.89 21.57 -2.32 -0.194 0.39692E+04 49 chlorite-Al-free 47.17 43.14 -4.04 -0.168 0.68935E+04 51 chloritoid-Fe 9.17 5.06 -4.12 -0.275 0.70314E+04 52 chloritoid-Mn 11.40 7.56 -3.84 -0.256 0.65566E+04 54 coesite -2.38 -3.16 -0.78 -0.260 0.13341E+04 61 cristobalite -2.56 -3.16 -0.60 -0.199 0.10195E+04 63 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71234E+04 65 diaspore 2.87 0.74 -2.13 -0.356 0.36449E+04 66 diamond -3.10 -7.76 -4.66 -1.330 0.79499E+04 71 enstatite 17.26 12.27 -4.99 -0.499 0.85225E+04 73 clinoenstatite 17.17 12.27 -4.89 -0.489 0.83541E+04 75 epidote 24.67 22.70 -1.97 -0.095 0.33584E+04 76 clinozoisite 22.81 18.95 -3.86 -0.175 0.65867E+04 77 epidote-Fe 29.84 26.46 -3.38 -0.176 0.57768E+04 78 fayalite 14.05 10.31 -3.73 -0.533 0.63743E+04 79 ferrosilite 11.15 7.16 -3.99 -0.399 0.68202E+04 83 gibbsite 4.08 0.74 -3.34 -0.477 0.57035E+04 84 glaucophane 22.97 20.80 -2.17 -0.059 0.37133E+04 85 glaucophane-Fe 17.28 13.12 -4.15 -0.112 0.70919E+04 86 graphite -3.55 -7.76 -4.21 -1.203 0.71921E+04 87 greenalite 16.14 13.89 -2.25 -0.187 0.38408E+04 90 hematite 12.57 8.99 -3.58 -0.434 0.61112E+04 91 heulandite -5.83 -7.52 -1.69 -0.077 0.28938E+04 95 jadeite 4.22 2.77 -1.44 -0.144 0.24617E+04 97 kalsilite 7.58 3.83 -3.76 -0.537 0.64125E+04 98 kaolinite -1.33 -4.84 -3.50 -0.319 0.59831E+04 101 laumontite 2.88 1.95 -0.93 -0.062 0.15934E+04 102 lawsonite 9.62 8.27 -1.35 -0.090 0.23069E+04 103 leucite 4.12 0.67 -3.45 -0.345 0.58873E+04 105 lizardite 23.24 21.57 -1.68 -0.140 0.28618E+04 107 magnetite 20.09 15.72 -4.37 -0.356 0.74536E+04 108 minnesotaite 10.39 7.58 -2.81 -0.165 0.48028E+04 112 manganosite 14.06 9.24 -4.82 -1.204 0.82259E+04 120 muscovite 2.58 -1.01 -3.59 -0.211 0.61314E+04 121 paragonite 4.24 1.09 -3.15 -0.185 0.53705E+04 122 nepheline 8.34 5.93 -2.41 -0.344 0.41124E+04 128 periclase-Fe 11.63 6.73 -4.89 -1.223 0.83523E+04 134 phlogopite-Na 29.65 27.50 -2.15 -0.119 0.36677E+04 136 prehnite 19.37 18.21 -1.16 -0.068 0.19848E+04 137 prehnite-Fe 22.50 21.96 -0.53 -0.032 0.91155E+03 138 pumpellyite-Fe 46.27 43.89 -2.38 -0.053 0.40579E+04 139 pumpellyite-Mg 48.99 46.45 -2.54 -0.057 0.43417E+04 143 pyrrhotite -4.26 -7.96 -3.70 -1.234 0.63211E+04 144 pyrrhotiteFe0.875 -6.02 -9.36 -3.34 -1.230 0.57083E+04 145 pyroxmangite 7.40 6.08 -1.32 -0.263 0.22463E+04 146 pyrophyllite -6.18 -11.15 -4.98 -0.311 0.84961E+04 147 quartz -2.99 -3.16 -0.17 -0.056 0.28682E+03 152 rhodonite 7.45 6.08 -1.36 -0.273 0.23266E+04 153 sanidine -1.28 -2.49 -1.21 -0.093 0.20677E+04 165 stilpnomelane-Mg 27.44 25.81 -1.63 -0.049 0.27803E+04 171 talc 16.49 15.25 -1.24 -0.073 0.21140E+04 174 tephroite 18.09 15.32 -2.76 -0.395 0.47164E+04 178 tridymite -2.63 -3.16 -0.53 -0.177 0.90680E+03 179 tremolite 47.87 47.42 -0.45 -0.012 0.77495E+03 180 ferroactinolite 38.45 34.62 -3.83 -0.104 0.65449E+04 181 troilite-low -4.41 -7.96 -3.55 -1.184 0.60639E+04 183 vesuvianite 223.47 218.82 -4.65 -0.036 0.79431E+04 187 wairakite 3.95 1.95 -2.00 -0.118 0.34154E+04 188 walstromite 11.51 9.94 -1.56 -0.313 0.26719E+04 189 wollastonite 10.46 9.94 -0.52 -0.103 0.88229E+03 190 pseudo-wollastonite 11.00 9.94 -1.06 -0.211 0.18021E+04 191 zoisite 22.85 18.95 -3.90 -0.177 0.66607E+04 192 akaganeite 7.75 4.49 -3.26 -0.705 0.55681E+04 199 chalcedony -2.80 -3.16 -0.35 -0.118 0.60612E+03 201 montmorillonite-Ca -2.29 -6.17 -3.88 -0.240 0.66180E+04 202 montmorillonite-K -2.24 -6.27 -4.03 -0.247 0.68816E+04 203 montmorillonite-Mg -2.48 -6.79 -4.32 -0.267 0.73678E+04 204 montmorillonite-Na -2.04 -5.57 -3.54 -0.216 0.60365E+04 205 nontronite-Ca 3.21 -0.19 -3.41 -0.221 0.58216E+04 206 nontronite-H 2.53 -2.36 -4.89 -0.328 0.83486E+04 207 nontronite-K 3.34 -0.30 -3.64 -0.233 0.62084E+04 208 nontronite-Mg 3.07 -0.82 -3.90 -0.253 0.66554E+04 209 nontronite-Na 3.52 0.40 -3.12 -0.200 0.53293E+04 224 tobermorite 9.82 7.76 -2.07 -0.564 0.35287E+04 230 alabandite -0.98 -5.46 -4.48 -1.493 0.76477E+04 233 boehmite 4.41 0.74 -3.67 -0.611 0.62618E+04 235 ferrous-oxide 9.81 6.73 -3.08 -0.769 0.52532E+04 240 silica-amorphous -2.09 -3.16 -1.07 -0.355 0.18203E+04 242 an20ab80 2.02 1.35 -0.67 -0.052 0.11472E+04 243 an25ab75 2.65 1.78 -0.87 -0.067 0.14810E+04 244 an30ab70 3.28 2.21 -1.07 -0.082 0.18243E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 100.0000000 g Current total amount of reactant added: 2099.9990000 g New total amount of reactant added: 2199.9990000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.5220E-10 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 11 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 2199.9990000 Water: Moles liquid = 0.4316E+02 kg liquid = 0.7775E+00 Moles total = 0.2793E+02 kg total = 0.5032E+00 Activity = 1.0000 Stoichiometric ionic strength = .1135032E-01 Osmotic coef. = 0.9691 True ionic strength = .2003353E-01 Chg. balance for total moles = 0.5220E-10 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.88359E-10 -10.0537 0.74241E-10 -10.1294 0.84021E+00 -0.0756 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.17664E-03 -3.7529 0.14752E-03 -3.8311 0.83516E+00 -0.0782 4 SO4-- 0.83229E-12 -12.0797 0.43213E-12 -12.3644 0.51920E+00 -0.2847 5 HCO3- 0.30797E-06 -6.5115 0.25758E-06 -6.5891 0.83638E+00 -0.0776 6 HS- 0.32796E-04 -4.4842 0.27394E-04 -4.5624 0.83528E+00 -0.0782 7 Al+++ 0.97153E-29 -29.0125 0.22435E-29 -29.6491 0.23093E+00 -0.6365 8 H4SiO4 0.69596E-03 -3.1574 0.69596E-03 -3.1574 0.10000E+01 0.0000 9 Ca++ 0.13520E-06 -6.8690 0.69682E-07 -7.1569 0.51539E+00 -0.2879 10 Mg++ 0.21152E-10 -10.6747 0.10851E-10 -10.9645 0.51303E+00 -0.2899 11 Fe++ 0.58297E-13 -13.2344 0.29941E-13 -13.5237 0.51359E+00 -0.2894 12 K+ 0.15663E-03 -3.8051 0.13103E-03 -3.8826 0.83658E+00 -0.0775 13 Na+ 0.19876E-01 -1.7017 0.16596E-01 -1.7800 0.83500E+00 -0.0783 14 Mn++ 0.18659E-10 -10.7291 0.95912E-11 -11.0181 0.51402E+00 -0.2890 15 HPO4-- 0.45264E-07 -7.3442 0.23505E-07 -7.6288 0.51928E+00 -0.2846 16 HSiO3- 0.10481E-01 -1.9796 0.87533E-02 -2.0578 0.83516E+00 -0.0782 17 Ca(HSiO3)+ 0.16601E-07 -7.7799 0.13891E-07 -7.8573 0.83676E+00 -0.0774 18 Mg(HSiO3)+ 0.32173E-11 -11.4925 0.26921E-11 -11.5699 0.83676E+00 -0.0774 19 NaHSiO3,aq 0.23496E-02 -2.6290 0.23496E-02 -2.6290 0.10000E+01 0.0000 20 AlO+ 0.66180E-16 -16.1793 0.55376E-16 -16.2567 0.83676E+00 -0.0774 22 HAlO2,aq 0.14854E-09 -9.8281 0.14854E-09 -9.8281 0.10000E+01 0.0000 23 AlO2- 0.53129E-05 -5.2747 0.44291E-05 -5.3537 0.83365E+00 -0.0790 24 CH4,aq 0.15916E-04 -4.7982 0.15861E-04 -4.7997 0.99654E+00 -0.0015 25 C2H6,aq 0.37260E-14 -14.4288 0.37131E-14 -14.4303 0.99654E+00 -0.0015 29 CO,aq 0.11890E-16 -16.9248 0.11890E-16 -16.9248 0.10000E+01 0.0000 30 CO2,aq 0.41003E-10 -10.3872 0.40861E-10 -10.3887 0.99654E+00 -0.0015 31 CO3-2 0.58493E-06 -6.2329 0.30305E-06 -6.5185 0.51810E+00 -0.2856 32 CaCO3,aq 0.26479E-09 -9.5771 0.26479E-09 -9.5771 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.54755E-12 -12.2616 0.45816E-12 -12.3390 0.83676E+00 -0.0774 34 CaCl+ 0.19881E-10 -10.7016 0.16636E-10 -10.7790 0.83676E+00 -0.0774 35 CaCl2,aq 0.58305E-15 -15.2343 0.58305E-15 -15.2343 0.10000E+01 0.0000 36 CaOH+ 0.79944E-07 -7.0972 0.66894E-07 -7.1746 0.83676E+00 -0.0774 37 CaSO4,aq 0.95618E-17 -17.0195 0.95618E-17 -17.0195 0.10000E+01 0.0000 38 HCl,aq 0.20069E-14 -14.6975 0.20069E-14 -14.6975 0.10000E+01 0.0000 43 FeCl+ 0.83552E-17 -17.0780 0.69913E-17 -17.1554 0.83676E+00 -0.0774 46 FeO,aq 0.21113E-09 -9.6755 0.21113E-09 -9.6755 0.10000E+01 0.0000 47 FeOH+ 0.15689E-10 -10.8044 0.13128E-10 -10.8818 0.83676E+00 -0.0774 48 HFeO2- 0.35628E-07 -7.4482 0.29755E-07 -7.5264 0.83516E+00 -0.0782 49 FeO+ 0.10995E-16 -16.9588 0.92002E-17 -17.0362 0.83676E+00 -0.0774 51 FeO2- 0.40897E-09 -9.3883 0.34156E-09 -9.4665 0.83516E+00 -0.0782 52 HFeO2,aq 0.32251E-11 -11.4915 0.32251E-11 -11.4915 0.10000E+01 0.0000 53 H2,aq 0.11624E-04 -4.9347 0.11583E-04 -4.9362 0.99654E+00 -0.0015 54 KCl,aq 0.35035E-09 -9.4555 0.35035E-09 -9.4555 0.10000E+01 0.0000 56 KOH,aq 0.75375E-06 -6.1228 0.75375E-06 -6.1228 0.10000E+01 0.0000 57 KSO4- 0.10521E-14 -14.9779 0.87866E-15 -15.0562 0.83516E+00 -0.0782 58 MgCO3,aq 0.10336E-13 -13.9857 0.10336E-13 -13.9857 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.87129E-16 -16.0598 0.72905E-16 -16.1372 0.83676E+00 -0.0774 60 MgCl+ 0.28061E-14 -14.5519 0.23480E-14 -14.6293 0.83676E+00 -0.0774 61 MgOH+ 0.68889E-10 -10.1618 0.57644E-10 -10.2392 0.83676E+00 -0.0774 63 MnO,aq 0.18021E-08 -8.7442 0.18021E-08 -8.7442 0.10000E+01 0.0000 64 MnOH+ 0.46687E-09 -9.3308 0.39066E-09 -9.4082 0.83676E+00 -0.0774 65 MnO2-2 0.20944E-10 -10.6789 0.10851E-10 -10.9645 0.51810E+00 -0.2856 66 HMnO2- 0.21133E-09 -9.6750 0.17649E-09 -9.7533 0.83516E+00 -0.0782 69 MnCl+ 0.10413E-13 -13.9824 0.87130E-14 -14.0598 0.83676E+00 -0.0774 71 NaCl,aq 0.81138E-06 -6.0908 0.81138E-06 -6.0908 0.10000E+01 0.0000 72 NaOH,aq 0.96047E-04 -4.0175 0.96047E-04 -4.0175 0.10000E+01 0.0000 74 OH- 0.93354E-02 -2.0299 0.77824E-02 -2.1089 0.83365E+00 -0.0790 79 HPO3-2 0.16376E-14 -14.7858 0.84846E-15 -15.0714 0.51810E+00 -0.2856 81 H2PO3- 0.15125E-18 -18.8203 0.12631E-18 -18.8985 0.83516E+00 -0.0782 82 H3PO4,aq 0.90606E-18 -18.0428 0.90606E-18 -18.0428 0.10000E+01 0.0000 83 H2PO4- 0.38508E-10 -10.4145 0.32190E-10 -10.4923 0.83595E+00 -0.0778 84 PO4-3 0.10650E-08 -8.9727 0.25831E-09 -9.5879 0.24255E+00 -0.6152 88 HP2O7-3 0.94537E-18 -18.0244 0.21853E-18 -18.6605 0.23116E+00 -0.6361 89 P2O7-4 0.91269E-17 -17.0397 0.70320E-18 -18.1529 0.77047E-01 -1.1132 90 H2S,aq 0.63073E-08 -8.2002 0.62854E-08 -8.2017 0.99654E+00 -0.0015 91 S2-2 0.27706E-14 -14.5574 0.14355E-14 -14.8430 0.51810E+00 -0.2856 97 SO3-2 0.12375E-17 -17.9074 0.65046E-18 -18.1868 0.52560E+00 -0.2793 99 HSO4- 0.36913E-19 -19.4328 0.30917E-19 -19.5098 0.83757E+00 -0.0770 Charge balance for all species = 0.6714E-10 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.8835943E-10 -.2228773E-01 -.2242564E+02 0.0000 2 H2O 0.1000000E+01 0.5550489E+02 0.9981988E+06 0.0000 3 Cl- 0.1766404E-03 0.1774522E-03 0.6280274E+01 6.2982 4 SO4-- 0.8322861E-12 -.1882229E-04 -.1804955E+01 7.8943 5 HCO3- 0.3079727E-06 0.1680967E-04 0.1023896E+01 3.5403 6 HS- 0.3279565E-04 0.5162425E-04 0.1704349E+01 5.5670 7 Al+++ 0.9715270E-29 0.5313034E-05 0.1431044E+00 0.7390 8 H4SiO4 0.6959606E-03 0.1352654E-01 0.1297849E+04 -3.1574 9 Ca++ 0.1352032E-06 0.2320333E-06 0.9283264E-02 13.1018 10 Mg++ 0.2115167E-10 0.9327155E-10 0.2263676E-05 9.2942 11 Fe++ 0.5829662E-13 0.3626757E-07 0.2021914E-02 6.7350 12 K+ 0.1566315E-03 0.1573856E-03 0.6143391E+01 6.2467 13 Na+ 0.1987576E-01 0.2232220E-01 0.5122907E+03 8.3494 14 Mn++ 0.1865924E-10 0.2519934E-08 0.1381994E-03 9.2406 15 HPO4-- 0.4526398E-07 0.4636749E-07 0.4442568E-02 12.6299 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.3642870E+02 -.1732935E-01 -.3641137E+02 0.0000000E+00 2 H2O 0.2793036E+02 0.4315665E+02 -.1522629E+02 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.6099498E-01 -.1463487E-04 0.6100961E-01 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.6096947E-01 0.4013934E-04 -.6100961E-01 0.0000000E+00 7 Al+++ 0.7173628E+01 0.4131037E-05 0.7173624E+01 0.0000000E+00 8 H4SiO4 0.2290811E+02 0.1051728E-01 0.2289759E+02 0.0000000E+00 9 Ca++ 0.2530327E+01 0.1804126E-06 0.2530327E+01 0.0000000E+00 10 Mg++ 0.1746031E+01 0.7252132E-10 0.1746031E+01 0.0000000E+00 11 Fe++ 0.1568618E+01 0.2819908E-07 0.1568618E+01 0.0000000E+00 12 K+ 0.4670911E+00 0.1223718E-03 0.4669687E+00 0.0000000E+00 13 Na+ 0.2761695E+01 0.1735615E-01 0.2744339E+01 0.0000000E+00 14 Mn++ 0.3814489E-01 0.1959321E-08 0.3814489E-01 0.0000000E+00 15 HPO4-- 0.1301866E-01 0.3605206E-07 0.1301863E-01 0.0000000E+00 Chg. balance for solid moles: -.9843E-14 Mass of aqueous solution: 0.778883E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 2199.9990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 2.742 0.438 719.0 2.857 29.92 276.0 andradite 0.2440 -0.613 124.0 2.093 5.160 32.22 grossular 0.5910E-01 -1.228 26.62 1.425 1.108 7.407 apatite-OH 0.4340E-02 -2.363 2.180 0.338 0.9070E-01 0.6927 clinochlore 0.3133 -0.504 174.1 2.241 7.245 66.23 daphnite 0.9068E-01 -1.042 64.70 1.811 2.692 19.61 chlorite-Mn 0.7629E-02 -2.118 5.409 0.733 0.2251 1.724 diopside 0.1104 -0.957 23.91 1.379 0.9948 7.307 hedenbergite 0.2863E-01 -1.543 7.103 0.851 0.2956 1.946 microcline 0.4095 -0.388 114.0 2.057 4.743 44.52 stilbite 1.422 0.153 1002. 3.001 41.69 467.4 stilpnomelane-Fe 0.1149 -0.940 123.9 2.093 5.154 42.79 tr.625ac.25prg.125 0.1914E-01 -1.718 16.36 1.214 0.6806 5.265 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8050E+00 0.8050E+00 1.0000 -0.094 grossular 0.1950E+00 0.1950E+00 1.0000 -0.710 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.7611E+00 0.7611E+00 1.0000 -0.119 daphnite 0.2203E+00 0.2203E+00 1.0000 -0.657 chlorite-Mn 0.1854E-01 0.1854E-01 1.0000 -1.732 diopside 0.7941E+00 0.7941E+00 1.0000 -0.100 hedenbergite 0.2059E+00 0.2059E+00 1.0000 -0.686 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 tr.625ac.25prg.125 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 2403.319254 g Volume = 973.092061 cm3 Porosity: -10.4532% V(tot) - V(min): -.92092E+02 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 2199.9990000 g log = 3.3424 Original solution: 1000.0103000 g Original solution / Rock added: 0.45 (Water/Rock Ratio), log = -0.3424 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0591 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9639E+00 0.9854 0.1006E+01 0.1021E+01 CO2,gas 0.4100E-08 1.0069 0.4372E-08 0.4342E-08 CH4,gas 0.2177E-01 1.0124 0.2335E-01 0.2306E-01 H2,gas 0.1435E-01 1.0006 0.1521E-01 0.1520E-01 H2S,gas 0.1638E-06 0.9959 0.1728E-06 0.1735E-06 S2,gas 0.4575E-29 1.0000 0.4845E-29 0.4845E-29 CO,gas 0.1673E-13 1.0000 0.1772E-13 0.1772E-13 SO3,gas 0.8503E-48 1.0000 0.9005E-48 0.9005E-48 SO2,gas 0.5031E-27 1.0000 0.5328E-27 0.5328E-27 HCl,gas 0.3344E-17 1.0000 0.3541E-17 0.3541E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 16 albite -0.38 -0.38 0.00 0.000 -0.13080E-10 22 andradite 39.01 39.01 0.00 0.000 0.12132E-10 23 grossular 32.73 32.73 0.00 0.000 0.00000E+00 32 apatite-OH -18.15 -18.15 0.00 0.000 -0.60662E-11 46 clinochlore 39.07 39.07 0.00 0.000 0.00000E+00 47 daphnite 28.97 28.97 0.00 0.000 -0.30331E-10 48 chlorite-Mn 46.87 46.87 0.00 0.000 0.00000E+00 67 diopside 16.18 16.18 0.00 0.000 0.60662E-11 68 hedenbergite 14.21 14.21 0.00 0.000 -0.30331E-11 116 microcline -2.49 -2.49 0.00 0.000 -0.10616E-10 163 stilbite -7.52 -7.52 0.00 0.000 -0.33364E-10 164 stilpnomelane-Fe 13.02 13.02 0.00 0.000 0.21232E-10 245 tr.625ac.25prg.125 45.16 45.16 0.00 0.000 0.48529E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -16.72 -10.06 -3.353 0.17174E+05 -8.359 3 CH4,gas 4.54 1.21 -3.33 -0.833 0.56872E+04 -1.632 4 H2,gas 8.00 4.48 -3.52 -2.010 0.60050E+04 -1.818 5 H2S,gas -6.23 -14.69 -8.46 -4.231 0.14448E+05 -6.763 6 S2,gas -7.34 -38.35 -31.01 -4.771 0.52955E+05 -29.315 7 CO,gas 3.21 -12.24 -15.45 -4.754 0.26381E+05 -13.752 8 SO3,gas 17.12 -32.62 -49.74 -12.436 0.84937E+05 -48.045 9 SO2,gas 0.83 -28.14 -28.97 -7.726 0.49470E+05 -27.273 10 HCl,gas 5.19 -13.96 -19.15 -9.575 0.32698E+05 -17.451 11 acmite 7.71 6.53 -1.18 -0.123 0.20176E+04 15 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 19 spessartine 24.46 19.73 -4.73 -0.236 0.80760E+04 20 analcite 3.32 2.77 -0.55 -0.061 0.93623E+03 26 annite 20.12 17.72 -2.40 -0.134 0.41064E+04 27 phlogopite 27.06 25.40 -1.67 -0.093 0.28489E+04 29 anorthite 12.71 8.27 -4.45 -0.342 0.75902E+04 35 aragonite 0.97 -3.62 -4.58 -1.528 0.78256E+04 36 brucite 12.57 9.29 -3.27 -0.655 0.55909E+04 37 calcite 0.81 -3.62 -4.43 -1.476 0.75613E+04 38 carnegieite-low 9.02 5.93 -3.09 -0.442 0.52801E+04 39 carnegieite-high 10.09 5.93 -4.16 -0.595 0.71071E+04 40 carpholite-Mg 8.58 4.46 -4.12 -0.275 0.70428E+04 41 carpholite-Fe 6.71 1.90 -4.81 -0.321 0.82206E+04 42 celadonite 5.34 3.65 -1.69 -0.099 0.28879E+04 43 celadonite-Fe 3.88 1.09 -2.79 -0.164 0.47561E+04 44 chrysotile 23.89 21.57 -2.32 -0.194 0.39692E+04 49 chlorite-Al-free 47.17 43.14 -4.04 -0.168 0.68936E+04 51 chloritoid-Fe 9.17 5.06 -4.12 -0.275 0.70314E+04 52 chloritoid-Mn 11.40 7.56 -3.84 -0.256 0.65565E+04 54 coesite -2.38 -3.16 -0.78 -0.260 0.13341E+04 61 cristobalite -2.56 -3.16 -0.60 -0.199 0.10195E+04 63 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71234E+04 65 diaspore 2.87 0.74 -2.13 -0.356 0.36449E+04 66 diamond -3.10 -7.75 -4.65 -1.329 0.79404E+04 71 enstatite 17.26 12.27 -4.99 -0.499 0.85225E+04 73 clinoenstatite 17.17 12.27 -4.89 -0.489 0.83541E+04 75 epidote 24.67 22.70 -1.97 -0.095 0.33584E+04 76 clinozoisite 22.81 18.95 -3.86 -0.175 0.65867E+04 77 epidote-Fe 29.84 26.46 -3.38 -0.176 0.57768E+04 78 fayalite 14.05 10.31 -3.73 -0.533 0.63743E+04 79 ferrosilite 11.15 7.16 -3.99 -0.399 0.68202E+04 83 gibbsite 4.08 0.74 -3.34 -0.477 0.57035E+04 84 glaucophane 22.97 20.80 -2.17 -0.059 0.37133E+04 85 glaucophane-Fe 17.28 13.12 -4.15 -0.112 0.70919E+04 86 graphite -3.55 -7.75 -4.21 -1.202 0.71826E+04 87 greenalite 16.14 13.89 -2.25 -0.187 0.38408E+04 90 hematite 12.57 8.99 -3.58 -0.434 0.61112E+04 91 heulandite -5.83 -7.52 -1.69 -0.077 0.28938E+04 95 jadeite 4.22 2.77 -1.44 -0.144 0.24617E+04 97 kalsilite 7.58 3.83 -3.76 -0.537 0.64125E+04 98 kaolinite -1.33 -4.84 -3.50 -0.319 0.59831E+04 101 laumontite 2.88 1.95 -0.93 -0.062 0.15934E+04 102 lawsonite 9.62 8.27 -1.35 -0.090 0.23069E+04 103 leucite 4.12 0.67 -3.45 -0.345 0.58873E+04 105 lizardite 23.24 21.57 -1.68 -0.140 0.28618E+04 107 magnetite 20.09 15.72 -4.37 -0.356 0.74536E+04 108 minnesotaite 10.39 7.58 -2.81 -0.165 0.48028E+04 112 manganosite 14.06 9.24 -4.82 -1.204 0.82258E+04 120 muscovite 2.58 -1.01 -3.59 -0.211 0.61314E+04 121 paragonite 4.24 1.09 -3.15 -0.185 0.53705E+04 122 nepheline 8.34 5.93 -2.41 -0.344 0.41124E+04 128 periclase-Fe 11.63 6.73 -4.89 -1.223 0.83523E+04 134 phlogopite-Na 29.65 27.50 -2.15 -0.119 0.36677E+04 136 prehnite 19.37 18.21 -1.16 -0.068 0.19848E+04 137 prehnite-Fe 22.50 21.96 -0.53 -0.032 0.91156E+03 138 pumpellyite-Fe 46.27 43.89 -2.38 -0.053 0.40579E+04 139 pumpellyite-Mg 48.99 46.45 -2.54 -0.057 0.43417E+04 143 pyrrhotite -4.26 -7.96 -3.70 -1.232 0.63115E+04 144 pyrrhotiteFe0.875 -6.02 -9.35 -3.34 -1.227 0.56987E+04 145 pyroxmangite 7.40 6.08 -1.32 -0.263 0.22462E+04 146 pyrophyllite -6.18 -11.15 -4.98 -0.311 0.84961E+04 147 quartz -2.99 -3.16 -0.17 -0.056 0.28682E+03 152 rhodonite 7.45 6.08 -1.36 -0.273 0.23264E+04 153 sanidine -1.28 -2.49 -1.21 -0.093 0.20677E+04 165 stilpnomelane-Mg 27.44 25.81 -1.63 -0.049 0.27803E+04 171 talc 16.49 15.25 -1.24 -0.073 0.21140E+04 174 tephroite 18.09 15.32 -2.76 -0.395 0.47161E+04 178 tridymite -2.63 -3.16 -0.53 -0.177 0.90680E+03 179 tremolite 47.87 47.42 -0.45 -0.012 0.77495E+03 180 ferroactinolite 38.45 34.62 -3.83 -0.104 0.65449E+04 181 troilite-low -4.41 -7.96 -3.55 -1.182 0.60543E+04 183 vesuvianite 223.47 218.82 -4.65 -0.036 0.79431E+04 187 wairakite 3.95 1.95 -2.00 -0.118 0.34154E+04 188 walstromite 11.51 9.94 -1.56 -0.313 0.26719E+04 189 wollastonite 10.46 9.94 -0.52 -0.103 0.88229E+03 190 pseudo-wollastonite 11.00 9.94 -1.06 -0.211 0.18021E+04 191 zoisite 22.85 18.95 -3.90 -0.177 0.66608E+04 192 akaganeite 7.75 4.49 -3.26 -0.705 0.55681E+04 199 chalcedony -2.80 -3.16 -0.35 -0.118 0.60612E+03 201 montmorillonite-Ca -2.29 -6.17 -3.88 -0.240 0.66180E+04 202 montmorillonite-K -2.24 -6.27 -4.03 -0.247 0.68816E+04 203 montmorillonite-Mg -2.48 -6.79 -4.32 -0.267 0.73678E+04 204 montmorillonite-Na -2.04 -5.57 -3.54 -0.216 0.60365E+04 205 nontronite-Ca 3.21 -0.19 -3.41 -0.221 0.58216E+04 206 nontronite-H 2.53 -2.36 -4.89 -0.328 0.83486E+04 207 nontronite-K 3.34 -0.30 -3.64 -0.233 0.62084E+04 208 nontronite-Mg 3.07 -0.82 -3.90 -0.253 0.66554E+04 209 nontronite-Na 3.52 0.40 -3.12 -0.200 0.53293E+04 224 tobermorite 9.82 7.76 -2.07 -0.564 0.35287E+04 230 alabandite -0.98 -5.45 -4.47 -1.491 0.76380E+04 233 boehmite 4.41 0.74 -3.67 -0.611 0.62618E+04 235 ferrous-oxide 9.81 6.73 -3.08 -0.769 0.52532E+04 240 silica-amorphous -2.09 -3.16 -1.07 -0.355 0.18203E+04 242 an20ab80 2.02 1.35 -0.67 -0.052 0.11472E+04 243 an25ab75 2.65 1.78 -0.87 -0.067 0.14810E+04 244 an30ab70 3.28 2.21 -1.07 -0.082 0.18243E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 100.0000000 g Current total amount of reactant added: 2199.9990000 g New total amount of reactant added: 2299.9990000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.5220E-10 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 11 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 2299.9990000 Water: Moles liquid = 0.4260E+02 kg liquid = 0.7675E+00 Moles total = 0.2668E+02 kg total = 0.4806E+00 Activity = 1.0000 Stoichiometric ionic strength = .1135225E-01 Osmotic coef. = 0.9691 True ionic strength = .2003504E-01 Chg. balance for total moles = 0.5220E-10 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.88366E-10 -10.0537 0.74246E-10 -10.1293 0.84021E+00 -0.0756 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.17895E-03 -3.7473 0.14945E-03 -3.8255 0.83515E+00 -0.0782 4 SO4-- 0.84315E-12 -12.0741 0.43776E-12 -12.3588 0.51919E+00 -0.2847 5 HCO3- 0.31199E-06 -6.5059 0.26094E-06 -6.5835 0.83637E+00 -0.0776 6 HS- 0.33225E-04 -4.4785 0.27752E-04 -4.5567 0.83527E+00 -0.0782 7 Al+++ 0.97177E-29 -29.0124 0.22440E-29 -29.6490 0.23092E+00 -0.6365 8 H4SiO4 0.69596E-03 -3.1574 0.69596E-03 -3.1574 0.10000E+01 0.0000 9 Ca++ 0.13522E-06 -6.8689 0.69692E-07 -7.1568 0.51538E+00 -0.2879 10 Mg++ 0.21155E-10 -10.6746 0.10853E-10 -10.9645 0.51302E+00 -0.2899 11 Fe++ 0.58306E-13 -13.2343 0.29945E-13 -13.5237 0.51358E+00 -0.2894 12 K+ 0.15664E-03 -3.8051 0.13104E-03 -3.8826 0.83657E+00 -0.0775 13 Na+ 0.19877E-01 -1.7016 0.16598E-01 -1.7800 0.83500E+00 -0.0783 14 Mn++ 0.18665E-10 -10.7290 0.95942E-11 -11.0180 0.51401E+00 -0.2890 15 HPO4-- 0.45259E-07 -7.3443 0.23501E-07 -7.6289 0.51927E+00 -0.2846 16 HSiO3- 0.10480E-01 -1.9796 0.87527E-02 -2.0579 0.83515E+00 -0.0782 17 Ca(HSiO3)+ 0.16602E-07 -7.7798 0.13892E-07 -7.8572 0.83675E+00 -0.0774 18 Mg(HSiO3)+ 0.32176E-11 -11.4925 0.26923E-11 -11.5699 0.83675E+00 -0.0774 19 NaHSiO3,aq 0.23496E-02 -2.6290 0.23496E-02 -2.6290 0.10000E+01 0.0000 20 AlO+ 0.66184E-16 -16.1792 0.55380E-16 -16.2566 0.83675E+00 -0.0774 22 HAlO2,aq 0.14854E-09 -9.8281 0.14854E-09 -9.8281 0.10000E+01 0.0000 23 AlO2- 0.53125E-05 -5.2747 0.44287E-05 -5.3537 0.83364E+00 -0.0790 24 CH4,aq 0.16125E-04 -4.7925 0.16069E-04 -4.7940 0.99654E+00 -0.0015 25 C2H6,aq 0.38242E-14 -14.4175 0.38109E-14 -14.4190 0.99654E+00 -0.0015 29 CO,aq 0.12046E-16 -16.9192 0.12046E-16 -16.9192 0.10000E+01 0.0000 30 CO2,aq 0.41541E-10 -10.3815 0.41397E-10 -10.3830 0.99654E+00 -0.0015 31 CO3-2 0.59252E-06 -6.2273 0.30698E-06 -6.5129 0.51809E+00 -0.2856 32 CaCO3,aq 0.26826E-09 -9.5714 0.26826E-09 -9.5714 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.55477E-12 -12.2559 0.46420E-12 -12.3333 0.83675E+00 -0.0774 34 CaCl+ 0.20144E-10 -10.6958 0.16856E-10 -10.7733 0.83675E+00 -0.0774 35 CaCl2,aq 0.59849E-15 -15.2229 0.59849E-15 -15.2229 0.10000E+01 0.0000 36 CaOH+ 0.79950E-07 -7.0972 0.66898E-07 -7.1746 0.83675E+00 -0.0774 37 CaSO4,aq 0.96878E-17 -17.0138 0.96878E-17 -17.0138 0.10000E+01 0.0000 38 HCl,aq 0.20333E-14 -14.6918 0.20333E-14 -14.6918 0.10000E+01 0.0000 43 FeCl+ 0.84657E-17 -17.0723 0.70837E-17 -17.1497 0.83675E+00 -0.0774 46 FeO,aq 0.21113E-09 -9.6755 0.21113E-09 -9.6755 0.10000E+01 0.0000 47 FeOH+ 0.15690E-10 -10.8044 0.13129E-10 -10.8818 0.83675E+00 -0.0774 48 HFeO2- 0.35626E-07 -7.4482 0.29753E-07 -7.5265 0.83515E+00 -0.0782 49 FeO+ 0.10996E-16 -16.9588 0.92008E-17 -17.0362 0.83675E+00 -0.0774 51 FeO2- 0.40895E-09 -9.3883 0.34153E-09 -9.4666 0.83515E+00 -0.0782 52 HFeO2,aq 0.32251E-11 -11.4915 0.32251E-11 -11.4915 0.10000E+01 0.0000 53 H2,aq 0.11623E-04 -4.9347 0.11583E-04 -4.9362 0.99654E+00 -0.0015 54 KCl,aq 0.35496E-09 -9.4498 0.35496E-09 -9.4498 0.10000E+01 0.0000 56 KOH,aq 0.75375E-06 -6.1228 0.75375E-06 -6.1228 0.10000E+01 0.0000 57 KSO4- 0.10659E-14 -14.9723 0.89017E-15 -15.0505 0.83515E+00 -0.0782 58 MgCO3,aq 0.10471E-13 -13.9800 0.10471E-13 -13.9800 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.88277E-16 -16.0542 0.73866E-16 -16.1316 0.83675E+00 -0.0774 60 MgCl+ 0.28432E-14 -14.5462 0.23791E-14 -14.6236 0.83675E+00 -0.0774 61 MgOH+ 0.68894E-10 -10.1618 0.57647E-10 -10.2392 0.83675E+00 -0.0774 63 MnO,aq 0.18024E-08 -8.7441 0.18024E-08 -8.7441 0.10000E+01 0.0000 64 MnOH+ 0.46699E-09 -9.3307 0.39075E-09 -9.4081 0.83675E+00 -0.0774 65 MnO2-2 0.20945E-10 -10.6789 0.10851E-10 -10.9645 0.51809E+00 -0.2856 66 HMnO2- 0.21135E-09 -9.6750 0.17651E-09 -9.7532 0.83515E+00 -0.0782 69 MnCl+ 0.10552E-13 -13.9767 0.88297E-14 -14.0541 0.83675E+00 -0.0774 71 NaCl,aq 0.82205E-06 -6.0851 0.82205E-06 -6.0851 0.10000E+01 0.0000 72 NaOH,aq 0.96047E-04 -4.0175 0.96047E-04 -4.0175 0.10000E+01 0.0000 74 OH- 0.93348E-02 -2.0299 0.77819E-02 -2.1089 0.83364E+00 -0.0790 79 HPO3-2 0.16374E-14 -14.7858 0.84834E-15 -15.0714 0.51809E+00 -0.2856 81 H2PO3- 0.15124E-18 -18.8203 0.12630E-18 -18.8986 0.83515E+00 -0.0782 82 H3PO4,aq 0.90607E-18 -18.0428 0.90607E-18 -18.0428 0.10000E+01 0.0000 83 H2PO4- 0.38505E-10 -10.4145 0.32188E-10 -10.4923 0.83594E+00 -0.0778 84 PO4-3 0.10648E-08 -8.9727 0.25826E-09 -9.5879 0.24254E+00 -0.6152 88 HP2O7-3 0.94522E-18 -18.0245 0.21849E-18 -18.6606 0.23115E+00 -0.6361 89 P2O7-4 0.91251E-17 -17.0398 0.70301E-18 -18.1530 0.77041E-01 -1.1133 90 H2S,aq 0.63902E-08 -8.1945 0.63681E-08 -8.1960 0.99654E+00 -0.0015 91 S2-2 0.28437E-14 -14.5461 0.14733E-14 -14.8317 0.51809E+00 -0.2856 97 SO3-2 0.12537E-17 -17.9018 0.65893E-18 -18.1812 0.52559E+00 -0.2794 99 HSO4- 0.37397E-19 -19.4272 0.31322E-19 -19.5041 0.83757E+00 -0.0770 Charge balance for all species = 0.6807E-10 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.8836601E-10 -.2228648E-01 -.2242438E+02 0.0000 2 H2O 0.1000000E+01 0.5550489E+02 0.9981987E+06 0.0000 3 Cl- 0.1789517E-03 0.1797741E-03 0.6362452E+01 6.3038 4 SO4-- 0.8431468E-12 -.1903061E-04 -.1824933E+01 7.8999 5 HCO3- 0.3119897E-06 0.1702962E-04 0.1037293E+01 3.5459 6 HS- 0.3322479E-04 0.5226179E-04 0.1725397E+01 5.5726 7 Al+++ 0.9717681E-29 0.5312658E-05 0.1430942E+00 0.7390 8 H4SiO4 0.6959620E-03 0.1352589E-01 0.1297786E+04 -3.1574 9 Ca++ 0.1352245E-06 0.2320654E-06 0.9284547E-02 13.1018 10 Mg++ 0.2115501E-10 0.9328008E-10 0.2263882E-05 9.2942 11 Fe++ 0.5830589E-13 0.3626521E-07 0.2021782E-02 6.7350 12 K+ 0.1566432E-03 0.1573973E-03 0.6143848E+01 6.2467 13 Na+ 0.1987725E-01 0.2232370E-01 0.5123251E+03 8.3494 14 Mn++ 0.1866548E-10 0.2520396E-08 0.1382248E-03 9.2407 15 HPO4-- 0.4525872E-07 0.4636204E-07 0.4442046E-02 12.6298 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.3808456E+02 -.1710457E-01 -.3806745E+02 0.0000000E+00 2 H2O 0.2667682E+02 0.4259924E+02 -.1592242E+02 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.6376632E-01 -.1460573E-04 0.6378092E-01 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.6374081E-01 0.4011020E-04 -.6378092E-01 0.0000000E+00 7 Al+++ 0.7499702E+01 0.4077391E-05 0.7499698E+01 0.0000000E+00 8 H4SiO4 0.2394939E+02 0.1038094E-01 0.2393901E+02 0.0000000E+00 9 Ca++ 0.2645341E+01 0.1781070E-06 0.2645341E+01 0.0000000E+00 10 Mg++ 0.1825396E+01 0.7159118E-10 0.1825396E+01 0.0000000E+00 11 Fe++ 0.1639919E+01 0.2783305E-07 0.1639919E+01 0.0000000E+00 12 K+ 0.4883225E+00 0.1208002E-03 0.4882017E+00 0.0000000E+00 13 Na+ 0.2887219E+01 0.1713313E-01 0.2870086E+01 0.0000000E+00 14 Mn++ 0.3987875E-01 0.1934369E-08 0.3987875E-01 0.0000000E+00 15 HPO4-- 0.1361042E-01 0.3558223E-07 0.1361038E-01 0.0000000E+00 Chg. balance for solid moles: -.7980E-14 Mass of aqueous solution: 0.768823E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 2299.9990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 2.868 0.458 751.9 2.876 29.93 288.7 andradite 0.2551 -0.593 129.6 2.113 5.160 33.68 grossular 0.6178E-01 -1.209 27.83 1.445 1.108 7.743 apatite-OH 0.4537E-02 -2.343 2.279 0.358 0.9070E-01 0.7242 clinochlore 0.3274 -0.485 182.0 2.260 7.243 69.23 daphnite 0.9479E-01 -1.023 67.63 1.830 2.692 20.49 chlorite-Mn 0.7976E-02 -2.098 5.655 0.752 0.2251 1.802 diopside 0.1158 -0.936 25.09 1.399 0.9984 7.667 hedenbergite 0.3004E-01 -1.522 7.453 0.872 0.2966 2.041 microcline 0.4281 -0.368 119.2 2.076 4.743 46.55 stilbite 1.486 0.172 1047. 3.020 41.68 488.5 stilpnomelane-Fe 0.1201 -0.920 129.5 2.112 5.155 44.74 tr.625ac.25prg.125 0.1997E-01 -1.700 17.07 1.232 0.6794 5.494 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8050E+00 0.8050E+00 1.0000 -0.094 grossular 0.1950E+00 0.1950E+00 1.0000 -0.710 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.7611E+00 0.7611E+00 1.0000 -0.119 daphnite 0.2203E+00 0.2203E+00 1.0000 -0.657 chlorite-Mn 0.1854E-01 0.1854E-01 1.0000 -1.732 diopside 0.7941E+00 0.7941E+00 1.0000 -0.100 hedenbergite 0.2059E+00 0.2059E+00 1.0000 -0.686 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 tr.625ac.25prg.125 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 2512.569918 g Volume = 1017.295125 cm3 Porosity: -10.4555% V(tot) - V(min): -.96296E+02 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 2299.9990000 g log = 3.3617 Original solution: 1000.0103000 g Original solution / Rock added: 0.43 (Water/Rock Ratio), log = -0.3617 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0594 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9636E+00 0.9854 0.1006E+01 0.1021E+01 CO2,gas 0.4152E-08 1.0069 0.4429E-08 0.4399E-08 CH4,gas 0.2205E-01 1.0124 0.2365E-01 0.2336E-01 H2,gas 0.1435E-01 1.0006 0.1521E-01 0.1520E-01 H2S,gas 0.1659E-06 0.9959 0.1751E-06 0.1758E-06 S2,gas 0.4695E-29 1.0000 0.4974E-29 0.4974E-29 CO,gas 0.1694E-13 1.0000 0.1795E-13 0.1795E-13 SO3,gas 0.8612E-48 1.0000 0.9124E-48 0.9124E-48 SO2,gas 0.5095E-27 1.0000 0.5398E-27 0.5398E-27 HCl,gas 0.3387E-17 1.0000 0.3588E-17 0.3588E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 16 albite -0.38 -0.38 0.00 0.000 0.11184E-10 22 andradite 39.01 39.01 0.00 0.000 0.24265E-10 23 grossular 32.73 32.73 0.00 0.000 0.12132E-10 32 apatite-OH -18.15 -18.15 0.00 0.000 0.60662E-11 46 clinochlore 39.07 39.07 0.00 0.000 0.12132E-10 47 daphnite 28.97 28.97 0.00 0.000 0.00000E+00 48 chlorite-Mn 46.87 46.87 0.00 0.000 0.00000E+00 67 diopside 16.18 16.18 0.00 0.000 0.00000E+00 68 hedenbergite 14.21 14.21 0.00 0.000 0.12132E-10 116 microcline -2.49 -2.49 0.00 0.000 0.15165E-11 163 stilbite -7.52 -7.52 0.00 0.000 0.15165E-10 164 stilpnomelane-Fe 13.02 13.02 0.00 0.000 0.21232E-10 245 tr.625ac.25prg.125 45.16 45.16 0.00 0.000 -0.12132E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -16.71 -10.05 -3.351 0.17165E+05 -8.354 3 CH4,gas 4.54 1.22 -3.33 -0.831 0.56775E+04 -1.626 4 H2,gas 8.00 4.48 -3.52 -2.010 0.60050E+04 -1.818 5 H2S,gas -6.23 -14.69 -8.46 -4.228 0.14438E+05 -6.757 6 S2,gas -7.34 -38.34 -31.00 -4.770 0.52936E+05 -29.303 7 CO,gas 3.21 -12.23 -15.44 -4.752 0.26372E+05 -13.746 8 SO3,gas 17.12 -32.62 -49.74 -12.435 0.84928E+05 -48.040 9 SO2,gas 0.83 -28.13 -28.97 -7.724 0.49460E+05 -27.268 10 HCl,gas 5.19 -13.95 -19.14 -9.572 0.32688E+05 -17.445 11 acmite 7.71 6.53 -1.18 -0.123 0.20176E+04 15 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 19 spessartine 24.46 19.73 -4.73 -0.236 0.80756E+04 20 analcite 3.32 2.77 -0.55 -0.061 0.93623E+03 26 annite 20.12 17.72 -2.40 -0.134 0.41064E+04 27 phlogopite 27.06 25.40 -1.67 -0.093 0.28489E+04 29 anorthite 12.71 8.27 -4.45 -0.342 0.75902E+04 35 aragonite 0.97 -3.61 -4.58 -1.526 0.78159E+04 36 brucite 12.57 9.29 -3.27 -0.655 0.55909E+04 37 calcite 0.81 -3.61 -4.42 -1.474 0.75517E+04 38 carnegieite-low 9.02 5.93 -3.09 -0.442 0.52801E+04 39 carnegieite-high 10.09 5.93 -4.16 -0.595 0.71071E+04 40 carpholite-Mg 8.58 4.46 -4.12 -0.275 0.70428E+04 41 carpholite-Fe 6.71 1.90 -4.81 -0.321 0.82206E+04 42 celadonite 5.34 3.65 -1.69 -0.099 0.28879E+04 43 celadonite-Fe 3.88 1.09 -2.79 -0.164 0.47561E+04 44 chrysotile 23.89 21.57 -2.32 -0.194 0.39692E+04 49 chlorite-Al-free 47.17 43.14 -4.04 -0.168 0.68936E+04 51 chloritoid-Fe 9.17 5.06 -4.12 -0.275 0.70315E+04 52 chloritoid-Mn 11.40 7.56 -3.84 -0.256 0.65564E+04 54 coesite -2.38 -3.16 -0.78 -0.260 0.13341E+04 61 cristobalite -2.56 -3.16 -0.60 -0.199 0.10195E+04 63 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71234E+04 65 diaspore 2.87 0.74 -2.13 -0.356 0.36449E+04 66 diamond -3.10 -7.75 -4.64 -1.327 0.79307E+04 71 enstatite 17.26 12.27 -4.99 -0.499 0.85225E+04 73 clinoenstatite 17.17 12.27 -4.89 -0.489 0.83541E+04 75 epidote 24.67 22.70 -1.97 -0.095 0.33584E+04 76 clinozoisite 22.81 18.95 -3.86 -0.175 0.65867E+04 77 epidote-Fe 29.84 26.46 -3.38 -0.176 0.57768E+04 78 fayalite 14.05 10.31 -3.73 -0.533 0.63743E+04 79 ferrosilite 11.15 7.16 -3.99 -0.399 0.68202E+04 83 gibbsite 4.08 0.74 -3.34 -0.477 0.57035E+04 84 glaucophane 22.97 20.80 -2.17 -0.059 0.37133E+04 85 glaucophane-Fe 17.28 13.12 -4.15 -0.112 0.70919E+04 86 graphite -3.55 -7.75 -4.20 -1.200 0.71730E+04 87 greenalite 16.14 13.89 -2.25 -0.187 0.38408E+04 90 hematite 12.57 8.99 -3.58 -0.434 0.61112E+04 91 heulandite -5.83 -7.52 -1.69 -0.077 0.28938E+04 95 jadeite 4.22 2.77 -1.44 -0.144 0.24617E+04 97 kalsilite 7.58 3.83 -3.76 -0.537 0.64125E+04 98 kaolinite -1.33 -4.84 -3.50 -0.319 0.59831E+04 101 laumontite 2.88 1.95 -0.93 -0.062 0.15934E+04 102 lawsonite 9.62 8.27 -1.35 -0.090 0.23069E+04 103 leucite 4.12 0.67 -3.45 -0.345 0.58873E+04 105 lizardite 23.24 21.57 -1.68 -0.140 0.28618E+04 107 magnetite 20.09 15.72 -4.37 -0.356 0.74536E+04 108 minnesotaite 10.39 7.58 -2.81 -0.165 0.48028E+04 112 manganosite 14.06 9.24 -4.82 -1.204 0.82257E+04 120 muscovite 2.58 -1.01 -3.59 -0.211 0.61314E+04 121 paragonite 4.24 1.09 -3.15 -0.185 0.53705E+04 122 nepheline 8.34 5.93 -2.41 -0.344 0.41124E+04 128 periclase-Fe 11.63 6.73 -4.89 -1.223 0.83523E+04 134 phlogopite-Na 29.65 27.50 -2.15 -0.119 0.36677E+04 136 prehnite 19.37 18.21 -1.16 -0.068 0.19848E+04 137 prehnite-Fe 22.50 21.96 -0.53 -0.032 0.91156E+03 138 pumpellyite-Fe 46.27 43.89 -2.38 -0.053 0.40579E+04 139 pumpellyite-Mg 48.99 46.45 -2.54 -0.057 0.43417E+04 143 pyrrhotite -4.26 -7.95 -3.69 -1.230 0.63018E+04 144 pyrrhotiteFe0.875 -6.02 -9.35 -3.33 -1.225 0.56890E+04 145 pyroxmangite 7.40 6.08 -1.32 -0.263 0.22461E+04 146 pyrophyllite -6.18 -11.15 -4.98 -0.311 0.84961E+04 147 quartz -2.99 -3.16 -0.17 -0.056 0.28682E+03 152 rhodonite 7.45 6.08 -1.36 -0.272 0.23263E+04 153 sanidine -1.28 -2.49 -1.21 -0.093 0.20677E+04 165 stilpnomelane-Mg 27.44 25.81 -1.63 -0.049 0.27803E+04 171 talc 16.49 15.25 -1.24 -0.073 0.21140E+04 174 tephroite 18.09 15.32 -2.76 -0.395 0.47158E+04 178 tridymite -2.63 -3.16 -0.53 -0.177 0.90680E+03 179 tremolite 47.87 47.42 -0.45 -0.012 0.77495E+03 180 ferroactinolite 38.45 34.62 -3.83 -0.104 0.65449E+04 181 troilite-low -4.41 -7.95 -3.54 -1.180 0.60446E+04 183 vesuvianite 223.47 218.82 -4.65 -0.036 0.79432E+04 187 wairakite 3.95 1.95 -2.00 -0.118 0.34154E+04 188 walstromite 11.51 9.94 -1.56 -0.313 0.26719E+04 189 wollastonite 10.46 9.94 -0.52 -0.103 0.88229E+03 190 pseudo-wollastonite 11.00 9.94 -1.06 -0.211 0.18021E+04 191 zoisite 22.85 18.95 -3.90 -0.177 0.66608E+04 192 akaganeite 7.75 4.49 -3.26 -0.705 0.55681E+04 199 chalcedony -2.80 -3.16 -0.35 -0.118 0.60612E+03 201 montmorillonite-Ca -2.29 -6.17 -3.88 -0.240 0.66180E+04 202 montmorillonite-K -2.24 -6.27 -4.03 -0.247 0.68816E+04 203 montmorillonite-Mg -2.48 -6.79 -4.32 -0.267 0.73678E+04 204 montmorillonite-Na -2.04 -5.57 -3.54 -0.216 0.60365E+04 205 nontronite-Ca 3.21 -0.19 -3.41 -0.221 0.58216E+04 206 nontronite-H 2.53 -2.36 -4.89 -0.328 0.83486E+04 207 nontronite-K 3.34 -0.30 -3.64 -0.233 0.62084E+04 208 nontronite-Mg 3.07 -0.82 -3.90 -0.253 0.66554E+04 209 nontronite-Na 3.52 0.40 -3.12 -0.200 0.53292E+04 224 tobermorite 9.82 7.76 -2.07 -0.564 0.35287E+04 230 alabandite -0.98 -5.45 -4.47 -1.489 0.76281E+04 233 boehmite 4.41 0.74 -3.67 -0.611 0.62619E+04 235 ferrous-oxide 9.81 6.73 -3.08 -0.769 0.52532E+04 240 silica-amorphous -2.09 -3.16 -1.07 -0.355 0.18203E+04 242 an20ab80 2.02 1.35 -0.67 -0.052 0.11472E+04 243 an25ab75 2.65 1.78 -0.87 -0.067 0.14810E+04 244 an30ab70 3.28 2.21 -1.07 -0.082 0.18243E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 100.0000000 g Current total amount of reactant added: 2299.9990000 g New total amount of reactant added: 2399.9990000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.5220E-10 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 11 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 2399.9990000 Water: Moles liquid = 0.4204E+02 kg liquid = 0.7574E+00 Moles total = 0.2542E+02 kg total = 0.4580E+00 Activity = 1.0000 Stoichiometric ionic strength = .1135423E-01 Osmotic coef. = 0.9691 True ionic strength = .2003658E-01 Chg. balance for total moles = 0.5220E-10 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.88373E-10 -10.0537 0.74251E-10 -10.1293 0.84020E+00 -0.0756 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.18132E-03 -3.7415 0.15143E-03 -3.8198 0.83515E+00 -0.0782 4 SO4-- 0.85429E-12 -12.0684 0.44353E-12 -12.3531 0.51918E+00 -0.2847 5 HCO3- 0.31611E-06 -6.5002 0.26439E-06 -6.5778 0.83637E+00 -0.0776 6 HS- 0.33665E-04 -4.4728 0.28120E-04 -4.5510 0.83527E+00 -0.0782 7 Al+++ 0.97202E-29 -29.0123 0.22444E-29 -29.6489 0.23091E+00 -0.6366 8 H4SiO4 0.69596E-03 -3.1574 0.69596E-03 -3.1574 0.10000E+01 0.0000 9 Ca++ 0.13525E-06 -6.8689 0.69702E-07 -7.1568 0.51537E+00 -0.2879 10 Mg++ 0.21158E-10 -10.6745 0.10855E-10 -10.9644 0.51301E+00 -0.2899 11 Fe++ 0.58315E-13 -13.2342 0.29949E-13 -13.5236 0.51357E+00 -0.2894 12 K+ 0.15666E-03 -3.8051 0.13105E-03 -3.8826 0.83657E+00 -0.0775 13 Na+ 0.19879E-01 -1.7016 0.16599E-01 -1.7799 0.83500E+00 -0.0783 14 Mn++ 0.18672E-10 -10.7288 0.95972E-11 -11.0179 0.51400E+00 -0.2890 15 HPO4-- 0.45253E-07 -7.3443 0.23498E-07 -7.6290 0.51926E+00 -0.2846 16 HSiO3- 0.10480E-01 -1.9797 0.87521E-02 -2.0579 0.83515E+00 -0.0782 17 Ca(HSiO3)+ 0.16603E-07 -7.7798 0.13893E-07 -7.8572 0.83675E+00 -0.0774 18 Mg(HSiO3)+ 0.32178E-11 -11.4924 0.26925E-11 -11.5698 0.83675E+00 -0.0774 19 NaHSiO3,aq 0.23496E-02 -2.6290 0.23496E-02 -2.6290 0.10000E+01 0.0000 20 AlO+ 0.66189E-16 -16.1792 0.55383E-16 -16.2566 0.83675E+00 -0.0774 22 HAlO2,aq 0.14854E-09 -9.8281 0.14854E-09 -9.8281 0.10000E+01 0.0000 23 AlO2- 0.53121E-05 -5.2747 0.44284E-05 -5.3538 0.83364E+00 -0.0790 24 CH4,aq 0.16339E-04 -4.7868 0.16282E-04 -4.7883 0.99654E+00 -0.0015 25 C2H6,aq 0.39263E-14 -14.4060 0.39127E-14 -14.4075 0.99654E+00 -0.0015 29 CO,aq 0.12206E-16 -16.9134 0.12206E-16 -16.9134 0.10000E+01 0.0000 30 CO2,aq 0.42093E-10 -10.3758 0.41947E-10 -10.3773 0.99654E+00 -0.0015 31 CO3-2 0.60032E-06 -6.2216 0.31101E-06 -6.5072 0.51808E+00 -0.2856 32 CaCO3,aq 0.27182E-09 -9.5657 0.27182E-09 -9.5657 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.56218E-12 -12.2501 0.47040E-12 -12.3275 0.83675E+00 -0.0774 34 CaCl+ 0.20414E-10 -10.6901 0.17082E-10 -10.7675 0.83675E+00 -0.0774 35 CaCl2,aq 0.61454E-15 -15.2114 0.61454E-15 -15.2114 0.10000E+01 0.0000 36 CaOH+ 0.79956E-07 -7.0971 0.66903E-07 -7.1746 0.83675E+00 -0.0774 37 CaSO4,aq 0.98170E-17 -17.0080 0.98170E-17 -17.0080 0.10000E+01 0.0000 38 HCl,aq 0.20604E-14 -14.6860 0.20604E-14 -14.6860 0.10000E+01 0.0000 43 FeCl+ 0.85792E-17 -17.0666 0.71786E-17 -17.1440 0.83675E+00 -0.0774 46 FeO,aq 0.21113E-09 -9.6755 0.21113E-09 -9.6755 0.10000E+01 0.0000 47 FeOH+ 0.15691E-10 -10.8043 0.13129E-10 -10.8818 0.83675E+00 -0.0774 48 HFeO2- 0.35624E-07 -7.4483 0.29751E-07 -7.5265 0.83515E+00 -0.0782 49 FeO+ 0.10997E-16 -16.9587 0.92015E-17 -17.0361 0.83675E+00 -0.0774 51 FeO2- 0.40892E-09 -9.3884 0.34151E-09 -9.4666 0.83515E+00 -0.0782 52 HFeO2,aq 0.32251E-11 -11.4915 0.32251E-11 -11.4915 0.10000E+01 0.0000 53 H2,aq 0.11623E-04 -4.9347 0.11583E-04 -4.9362 0.99654E+00 -0.0015 54 KCl,aq 0.35969E-09 -9.4441 0.35969E-09 -9.4441 0.10000E+01 0.0000 56 KOH,aq 0.75375E-06 -6.1228 0.75375E-06 -6.1228 0.10000E+01 0.0000 57 KSO4- 0.10800E-14 -14.9666 0.90198E-15 -15.0448 0.83515E+00 -0.0782 58 MgCO3,aq 0.10610E-13 -13.9743 0.10610E-13 -13.9743 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.89456E-16 -16.0484 0.74852E-16 -16.1258 0.83675E+00 -0.0774 60 MgCl+ 0.28813E-14 -14.5404 0.24109E-14 -14.6178 0.83675E+00 -0.0774 61 MgOH+ 0.68899E-10 -10.1618 0.57651E-10 -10.2392 0.83675E+00 -0.0774 63 MnO,aq 0.18027E-08 -8.7441 0.18027E-08 -8.7441 0.10000E+01 0.0000 64 MnOH+ 0.46710E-09 -9.3306 0.39084E-09 -9.4080 0.83675E+00 -0.0774 65 MnO2-2 0.20946E-10 -10.6789 0.10852E-10 -10.9645 0.51808E+00 -0.2856 66 HMnO2- 0.21137E-09 -9.6750 0.17653E-09 -9.7532 0.83515E+00 -0.0782 69 MnCl+ 0.10696E-13 -13.9708 0.89495E-14 -14.0482 0.83675E+00 -0.0774 71 NaCl,aq 0.83301E-06 -6.0794 0.83301E-06 -6.0794 0.10000E+01 0.0000 72 NaOH,aq 0.96047E-04 -4.0175 0.96047E-04 -4.0175 0.10000E+01 0.0000 74 OH- 0.93342E-02 -2.0299 0.77813E-02 -2.1089 0.83364E+00 -0.0790 79 HPO3-2 0.16372E-14 -14.7859 0.84821E-15 -15.0715 0.51808E+00 -0.2856 81 H2PO3- 0.15123E-18 -18.8204 0.12630E-18 -18.8986 0.83515E+00 -0.0782 82 H3PO4,aq 0.90607E-18 -18.0428 0.90607E-18 -18.0428 0.10000E+01 0.0000 83 H2PO4- 0.38503E-10 -10.4145 0.32186E-10 -10.4923 0.83594E+00 -0.0778 84 PO4-3 0.10646E-08 -8.9728 0.25820E-09 -9.5880 0.24253E+00 -0.6152 88 HP2O7-3 0.94507E-18 -18.0245 0.21844E-18 -18.6607 0.23114E+00 -0.6361 89 P2O7-4 0.91233E-17 -17.0398 0.70281E-18 -18.1532 0.77035E-01 -1.1133 90 H2S,aq 0.64754E-08 -8.1887 0.64529E-08 -8.1902 0.99654E+00 -0.0015 91 S2-2 0.29196E-14 -14.5347 0.15126E-14 -14.8203 0.51808E+00 -0.2856 97 SO3-2 0.12703E-17 -17.8961 0.66762E-18 -18.1755 0.52558E+00 -0.2794 99 HSO4- 0.37893E-19 -19.4214 0.31738E-19 -19.4984 0.83756E+00 -0.0770 Charge balance for all species = 0.6891E-10 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.8837276E-10 -.2228520E-01 -.2242309E+02 0.0000 2 H2O 0.1000000E+01 0.5550489E+02 0.9981986E+06 0.0000 3 Cl- 0.1813243E-03 0.1821577E-03 0.6446808E+01 6.3095 4 SO4-- 0.8542928E-12 -.1924447E-04 -.1845440E+01 7.9055 5 HCO3- 0.3161122E-06 0.1725541E-04 0.1051046E+01 3.5515 6 HS- 0.3366530E-04 0.5291624E-04 0.1747003E+01 5.5783 7 Al+++ 0.9720161E-29 0.5312275E-05 0.1430839E+00 0.7390 8 H4SiO4 0.6959634E-03 0.1352522E-01 0.1297722E+04 -3.1574 9 Ca++ 0.1352464E-06 0.2320984E-06 0.9285865E-02 13.1018 10 Mg++ 0.2115843E-10 0.9328913E-10 0.2264102E-05 9.2942 11 Fe++ 0.5831541E-13 0.3626279E-07 0.2021647E-02 6.7350 12 K+ 0.1566552E-03 0.1574093E-03 0.6144316E+01 6.2467 13 Na+ 0.1987878E-01 0.2232524E-01 0.5123605E+03 8.3494 14 Mn++ 0.1867153E-10 0.2520823E-08 0.1382482E-03 9.2407 15 HPO4-- 0.4525330E-07 0.4635644E-07 0.4441509E-02 12.6296 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.3974041E+02 -.1687978E-01 -.3972353E+02 0.0000000E+00 2 H2O 0.2542328E+02 0.4204182E+02 -.1661854E+02 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.6653766E-01 -.1457660E-04 0.6655223E-01 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.6651215E-01 0.4008107E-04 -.6655223E-01 0.0000000E+00 7 Al+++ 0.7825777E+01 0.4023748E-05 0.7825773E+01 0.0000000E+00 8 H4SiO4 0.2499067E+02 0.1024459E-01 0.2498042E+02 0.0000000E+00 9 Ca++ 0.2760356E+01 0.1758014E-06 0.2760356E+01 0.0000000E+00 10 Mg++ 0.1904761E+01 0.7066125E-10 0.1904761E+01 0.0000000E+00 11 Fe++ 0.1711220E+01 0.2746702E-07 0.1711220E+01 0.0000000E+00 12 K+ 0.5095539E+00 0.1192287E-03 0.5094347E+00 0.0000000E+00 13 Na+ 0.3012744E+01 0.1691011E-01 0.2995833E+01 0.0000000E+00 14 Mn++ 0.4161261E-01 0.1909381E-08 0.4161261E-01 0.0000000E+00 15 HPO4-- 0.1420218E-01 0.3511239E-07 0.1420214E-01 0.0000000E+00 Chg. balance for solid moles: -.1634E-14 Mass of aqueous solution: 0.758763E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 2399.9990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 2.993 0.476 784.9 2.895 29.94 301.3 andradite 0.2662 -0.575 135.3 2.131 5.160 35.15 grossular 0.6447E-01 -1.191 29.04 1.463 1.108 8.080 apatite-OH 0.4734E-02 -2.325 2.378 0.376 0.9070E-01 0.7556 clinochlore 0.3416 -0.466 189.9 2.278 7.242 72.22 daphnite 0.9889E-01 -1.005 70.56 1.849 2.691 21.38 chlorite-Mn 0.8323E-02 -2.080 5.900 0.771 0.2251 1.880 diopside 0.1213 -0.916 26.26 1.419 1.002 8.027 hedenbergite 0.3145E-01 -1.502 7.803 0.892 0.2976 2.137 microcline 0.4467 -0.350 124.3 2.095 4.743 48.57 stilbite 1.550 0.190 1093. 3.038 41.67 509.6 stilpnomelane-Fe 0.1254 -0.902 135.2 2.131 5.155 46.69 tr.625ac.25prg.125 0.2080E-01 -1.682 17.78 1.250 0.6783 5.723 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8050E+00 0.8050E+00 1.0000 -0.094 grossular 0.1950E+00 0.1950E+00 1.0000 -0.710 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.7611E+00 0.7611E+00 1.0000 -0.119 daphnite 0.2203E+00 0.2203E+00 1.0000 -0.657 chlorite-Mn 0.1854E-01 0.1854E-01 1.0000 -1.732 diopside 0.7941E+00 0.7941E+00 1.0000 -0.100 hedenbergite 0.2059E+00 0.2059E+00 1.0000 -0.686 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 tr.625ac.25prg.125 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 2621.820582 g Volume = 1061.498190 cm3 Porosity: -10.4577% V(tot) - V(min): -.10050E+03 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 2399.9990000 g log = 3.3802 Original solution: 1000.0103000 g Original solution / Rock added: 0.42 (Water/Rock Ratio), log = -0.3802 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0597 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9633E+00 0.9854 0.1006E+01 0.1021E+01 CO2,gas 0.4206E-08 1.0069 0.4488E-08 0.4457E-08 CH4,gas 0.2234E-01 1.0124 0.2397E-01 0.2367E-01 H2,gas 0.1434E-01 1.0006 0.1521E-01 0.1520E-01 H2S,gas 0.1681E-06 0.9959 0.1774E-06 0.1781E-06 S2,gas 0.4819E-29 1.0000 0.5107E-29 0.5107E-29 CO,gas 0.1716E-13 1.0000 0.1819E-13 0.1819E-13 SO3,gas 0.8725E-48 1.0000 0.9246E-48 0.9246E-48 SO2,gas 0.5162E-27 1.0000 0.5470E-27 0.5470E-27 HCl,gas 0.3431E-17 1.0000 0.3636E-17 0.3636E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 16 albite -0.38 -0.38 0.00 0.000 -0.94784E-12 22 andradite 39.01 39.01 0.00 0.000 0.12132E-10 23 grossular 32.73 32.73 0.00 0.000 0.00000E+00 32 apatite-OH -18.15 -18.15 0.00 0.000 0.60662E-11 46 clinochlore 39.07 39.07 0.00 0.000 0.36397E-10 47 daphnite 28.97 28.97 0.00 0.000 0.00000E+00 48 chlorite-Mn 46.87 46.87 0.00 0.000 0.24265E-10 67 diopside 16.18 16.18 0.00 0.000 0.12132E-10 68 hedenbergite 14.21 14.21 0.00 0.000 0.30331E-11 116 microcline -2.49 -2.49 0.00 0.000 0.13649E-10 163 stilbite -7.52 -7.52 0.00 0.000 0.15165E-10 164 stilpnomelane-Fe 13.02 13.02 0.00 0.000 0.21232E-10 245 tr.625ac.25prg.125 45.16 45.16 0.00 0.000 -0.24265E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -16.71 -10.05 -3.349 0.17155E+05 -8.348 3 CH4,gas 4.54 1.22 -3.32 -0.830 0.56677E+04 -1.620 4 H2,gas 8.00 4.48 -3.52 -2.010 0.60050E+04 -1.818 5 H2S,gas -6.23 -14.68 -8.45 -4.225 0.14428E+05 -6.751 6 S2,gas -7.34 -38.33 -30.99 -4.768 0.52916E+05 -29.292 7 CO,gas 3.21 -12.22 -15.44 -4.751 0.26362E+05 -13.740 8 SO3,gas 17.12 -32.61 -49.73 -12.433 0.84918E+05 -48.034 9 SO2,gas 0.83 -28.13 -28.96 -7.723 0.49450E+05 -27.262 10 HCl,gas 5.19 -13.95 -19.14 -9.569 0.32678E+05 -17.439 11 acmite 7.71 6.53 -1.18 -0.123 0.20176E+04 15 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 19 spessartine 24.46 19.73 -4.73 -0.236 0.80753E+04 20 analcite 3.32 2.77 -0.55 -0.061 0.93623E+03 26 annite 20.12 17.72 -2.40 -0.134 0.41064E+04 27 phlogopite 27.06 25.40 -1.67 -0.093 0.28489E+04 29 anorthite 12.71 8.27 -4.45 -0.342 0.75902E+04 35 aragonite 0.97 -3.61 -4.57 -1.524 0.78061E+04 36 brucite 12.57 9.29 -3.27 -0.655 0.55909E+04 37 calcite 0.81 -3.61 -4.42 -1.472 0.75419E+04 38 carnegieite-low 9.02 5.93 -3.09 -0.442 0.52801E+04 39 carnegieite-high 10.09 5.93 -4.16 -0.595 0.71071E+04 40 carpholite-Mg 8.58 4.46 -4.12 -0.275 0.70428E+04 41 carpholite-Fe 6.71 1.90 -4.81 -0.321 0.82206E+04 42 celadonite 5.34 3.65 -1.69 -0.099 0.28879E+04 43 celadonite-Fe 3.88 1.09 -2.79 -0.164 0.47561E+04 44 chrysotile 23.89 21.57 -2.32 -0.194 0.39692E+04 49 chlorite-Al-free 47.17 43.14 -4.04 -0.168 0.68936E+04 51 chloritoid-Fe 9.17 5.06 -4.12 -0.275 0.70315E+04 52 chloritoid-Mn 11.40 7.56 -3.84 -0.256 0.65563E+04 54 coesite -2.38 -3.16 -0.78 -0.260 0.13341E+04 61 cristobalite -2.56 -3.16 -0.60 -0.199 0.10195E+04 63 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71234E+04 65 diaspore 2.87 0.74 -2.13 -0.356 0.36449E+04 66 diamond -3.10 -7.74 -4.64 -1.325 0.79209E+04 71 enstatite 17.26 12.27 -4.99 -0.499 0.85225E+04 73 clinoenstatite 17.17 12.27 -4.89 -0.489 0.83541E+04 75 epidote 24.67 22.70 -1.97 -0.095 0.33585E+04 76 clinozoisite 22.81 18.95 -3.86 -0.175 0.65867E+04 77 epidote-Fe 29.84 26.46 -3.38 -0.176 0.57768E+04 78 fayalite 14.05 10.31 -3.73 -0.533 0.63743E+04 79 ferrosilite 11.15 7.16 -3.99 -0.399 0.68202E+04 83 gibbsite 4.08 0.74 -3.34 -0.477 0.57035E+04 84 glaucophane 22.97 20.80 -2.17 -0.059 0.37133E+04 85 glaucophane-Fe 17.28 13.12 -4.15 -0.112 0.70919E+04 86 graphite -3.55 -7.74 -4.20 -1.199 0.71632E+04 87 greenalite 16.14 13.89 -2.25 -0.187 0.38408E+04 90 hematite 12.57 8.99 -3.58 -0.434 0.61112E+04 91 heulandite -5.83 -7.52 -1.69 -0.077 0.28938E+04 95 jadeite 4.22 2.77 -1.44 -0.144 0.24617E+04 97 kalsilite 7.58 3.83 -3.76 -0.537 0.64125E+04 98 kaolinite -1.33 -4.84 -3.50 -0.319 0.59831E+04 101 laumontite 2.88 1.95 -0.93 -0.062 0.15935E+04 102 lawsonite 9.62 8.27 -1.35 -0.090 0.23069E+04 103 leucite 4.12 0.67 -3.45 -0.345 0.58873E+04 105 lizardite 23.24 21.57 -1.68 -0.140 0.28618E+04 107 magnetite 20.09 15.72 -4.37 -0.356 0.74536E+04 108 minnesotaite 10.39 7.58 -2.81 -0.165 0.48028E+04 112 manganosite 14.06 9.24 -4.82 -1.204 0.82255E+04 120 muscovite 2.58 -1.01 -3.59 -0.211 0.61314E+04 121 paragonite 4.24 1.09 -3.15 -0.185 0.53705E+04 122 nepheline 8.34 5.93 -2.41 -0.344 0.41124E+04 128 periclase-Fe 11.63 6.73 -4.89 -1.223 0.83523E+04 134 phlogopite-Na 29.65 27.50 -2.15 -0.119 0.36677E+04 136 prehnite 19.37 18.21 -1.16 -0.068 0.19848E+04 137 prehnite-Fe 22.50 21.96 -0.53 -0.032 0.91156E+03 138 pumpellyite-Fe 46.27 43.89 -2.38 -0.053 0.40579E+04 139 pumpellyite-Mg 48.99 46.45 -2.54 -0.057 0.43417E+04 143 pyrrhotite -4.26 -7.95 -3.68 -1.228 0.62920E+04 144 pyrrhotiteFe0.875 -6.02 -9.34 -3.33 -1.223 0.56792E+04 145 pyroxmangite 7.40 6.08 -1.32 -0.263 0.22459E+04 146 pyrophyllite -6.18 -11.15 -4.98 -0.311 0.84961E+04 147 quartz -2.99 -3.16 -0.17 -0.056 0.28682E+03 152 rhodonite 7.45 6.08 -1.36 -0.272 0.23262E+04 153 sanidine -1.28 -2.49 -1.21 -0.093 0.20677E+04 165 stilpnomelane-Mg 27.44 25.81 -1.63 -0.049 0.27803E+04 171 talc 16.49 15.25 -1.24 -0.073 0.21140E+04 174 tephroite 18.09 15.32 -2.76 -0.395 0.47156E+04 178 tridymite -2.63 -3.16 -0.53 -0.177 0.90680E+03 179 tremolite 47.87 47.42 -0.45 -0.012 0.77495E+03 180 ferroactinolite 38.45 34.62 -3.83 -0.104 0.65449E+04 181 troilite-low -4.41 -7.95 -3.53 -1.178 0.60348E+04 183 vesuvianite 223.47 218.82 -4.65 -0.036 0.79432E+04 187 wairakite 3.95 1.95 -2.00 -0.118 0.34154E+04 188 walstromite 11.51 9.94 -1.56 -0.313 0.26719E+04 189 wollastonite 10.46 9.94 -0.52 -0.103 0.88229E+03 190 pseudo-wollastonite 11.00 9.94 -1.06 -0.211 0.18021E+04 191 zoisite 22.85 18.95 -3.90 -0.177 0.66608E+04 192 akaganeite 7.75 4.49 -3.26 -0.705 0.55681E+04 199 chalcedony -2.80 -3.16 -0.35 -0.118 0.60612E+03 201 montmorillonite-Ca -2.29 -6.17 -3.88 -0.240 0.66180E+04 202 montmorillonite-K -2.24 -6.27 -4.03 -0.247 0.68816E+04 203 montmorillonite-Mg -2.48 -6.79 -4.32 -0.267 0.73678E+04 204 montmorillonite-Na -2.04 -5.57 -3.54 -0.216 0.60365E+04 205 nontronite-Ca 3.21 -0.19 -3.41 -0.221 0.58216E+04 206 nontronite-H 2.53 -2.36 -4.89 -0.328 0.83485E+04 207 nontronite-K 3.34 -0.30 -3.64 -0.233 0.62084E+04 208 nontronite-Mg 3.07 -0.82 -3.90 -0.253 0.66554E+04 209 nontronite-Na 3.52 0.40 -3.12 -0.200 0.53292E+04 224 tobermorite 9.82 7.76 -2.07 -0.564 0.35287E+04 230 alabandite -0.98 -5.44 -4.46 -1.487 0.76182E+04 233 boehmite 4.41 0.74 -3.67 -0.611 0.62619E+04 235 ferrous-oxide 9.81 6.73 -3.08 -0.769 0.52532E+04 240 silica-amorphous -2.09 -3.16 -1.07 -0.355 0.18203E+04 242 an20ab80 2.02 1.35 -0.67 -0.052 0.11472E+04 243 an25ab75 2.65 1.78 -0.87 -0.067 0.14810E+04 244 an30ab70 3.28 2.21 -1.07 -0.082 0.18243E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 100.0000000 g Current total amount of reactant added: 2399.9990000 g New total amount of reactant added: 2499.9990000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.5220E-10 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 11 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 2499.9990000 Water: Moles liquid = 0.4149E+02 kg liquid = 0.7474E+00 Moles total = 0.2417E+02 kg total = 0.4354E+00 Activity = 1.0000 Stoichiometric ionic strength = .1135626E-01 Osmotic coef. = 0.9691 True ionic strength = .2003817E-01 Chg. balance for total moles = 0.5220E-10 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.88380E-10 -10.0536 0.74257E-10 -10.1293 0.84020E+00 -0.0756 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.18376E-03 -3.7357 0.15347E-03 -3.8140 0.83514E+00 -0.0782 4 SO4-- 0.86574E-12 -12.0626 0.44947E-12 -12.3473 0.51917E+00 -0.2847 5 HCO3- 0.32034E-06 -6.4944 0.26793E-06 -6.5720 0.83637E+00 -0.0776 6 HS- 0.34118E-04 -4.4670 0.28497E-04 -4.5452 0.83527E+00 -0.0782 7 Al+++ 0.97227E-29 -29.0122 0.22449E-29 -29.6488 0.23090E+00 -0.6366 8 H4SiO4 0.69596E-03 -3.1574 0.69596E-03 -3.1574 0.10000E+01 0.0000 9 Ca++ 0.13527E-06 -6.8688 0.69712E-07 -7.1567 0.51536E+00 -0.2879 10 Mg++ 0.21162E-10 -10.6744 0.10856E-10 -10.9643 0.51300E+00 -0.2899 11 Fe++ 0.58325E-13 -13.2341 0.29954E-13 -13.5236 0.51356E+00 -0.2894 12 K+ 0.15667E-03 -3.8050 0.13106E-03 -3.8825 0.83656E+00 -0.0775 13 Na+ 0.19880E-01 -1.7016 0.16600E-01 -1.7799 0.83499E+00 -0.0783 14 Mn++ 0.18677E-10 -10.7287 0.96000E-11 -11.0177 0.51399E+00 -0.2890 15 HPO4-- 0.45248E-07 -7.3444 0.23495E-07 -7.6290 0.51925E+00 -0.2846 16 HSiO3- 0.10479E-01 -1.9797 0.87514E-02 -2.0579 0.83514E+00 -0.0782 17 Ca(HSiO3)+ 0.16605E-07 -7.7798 0.13894E-07 -7.8572 0.83674E+00 -0.0774 18 Mg(HSiO3)+ 0.32181E-11 -11.4924 0.26927E-11 -11.5698 0.83674E+00 -0.0774 19 NaHSiO3,aq 0.23496E-02 -2.6290 0.23496E-02 -2.6290 0.10000E+01 0.0000 20 AlO+ 0.66194E-16 -16.1792 0.55387E-16 -16.2566 0.83674E+00 -0.0774 22 HAlO2,aq 0.14854E-09 -9.8281 0.14854E-09 -9.8281 0.10000E+01 0.0000 23 AlO2- 0.53117E-05 -5.2748 0.44280E-05 -5.3538 0.83363E+00 -0.0790 24 CH4,aq 0.16558E-04 -4.7810 0.16501E-04 -4.7825 0.99654E+00 -0.0015 25 C2H6,aq 0.40326E-14 -14.3944 0.40186E-14 -14.3959 0.99654E+00 -0.0015 29 CO,aq 0.12370E-16 -16.9076 0.12370E-16 -16.9076 0.10000E+01 0.0000 30 CO2,aq 0.42659E-10 -10.3700 0.42511E-10 -10.3715 0.99654E+00 -0.0015 31 CO3-2 0.60832E-06 -6.2159 0.31515E-06 -6.5015 0.51807E+00 -0.2856 32 CaCO3,aq 0.27548E-09 -9.5599 0.27548E-09 -9.5599 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.56979E-12 -12.2443 0.47676E-12 -12.3217 0.83674E+00 -0.0774 34 CaCl+ 0.20691E-10 -10.6842 0.17313E-10 -10.7616 0.83674E+00 -0.0774 35 CaCl2,aq 0.63125E-15 -15.1998 0.63125E-15 -15.1998 0.10000E+01 0.0000 36 CaOH+ 0.79962E-07 -7.0971 0.66908E-07 -7.1745 0.83674E+00 -0.0774 37 CaSO4,aq 0.99498E-17 -17.0022 0.99498E-17 -17.0022 0.10000E+01 0.0000 38 HCl,aq 0.20882E-14 -14.6802 0.20882E-14 -14.6802 0.10000E+01 0.0000 43 FeCl+ 0.86957E-17 -17.0607 0.72761E-17 -17.1381 0.83674E+00 -0.0774 46 FeO,aq 0.21113E-09 -9.6755 0.21113E-09 -9.6755 0.10000E+01 0.0000 47 FeOH+ 0.15692E-10 -10.8043 0.13130E-10 -10.8817 0.83674E+00 -0.0774 48 HFeO2- 0.35621E-07 -7.4483 0.29749E-07 -7.5265 0.83514E+00 -0.0782 49 FeO+ 0.10998E-16 -16.9587 0.92022E-17 -17.0361 0.83674E+00 -0.0774 51 FeO2- 0.40889E-09 -9.3884 0.34148E-09 -9.4666 0.83514E+00 -0.0782 52 HFeO2,aq 0.32251E-11 -11.4915 0.32251E-11 -11.4915 0.10000E+01 0.0000 53 H2,aq 0.11623E-04 -4.9347 0.11583E-04 -4.9362 0.99654E+00 -0.0015 54 KCl,aq 0.36454E-09 -9.4382 0.36454E-09 -9.4382 0.10000E+01 0.0000 56 KOH,aq 0.75375E-06 -6.1228 0.75375E-06 -6.1228 0.10000E+01 0.0000 57 KSO4- 0.10946E-14 -14.9608 0.91411E-15 -15.0390 0.83514E+00 -0.0782 58 MgCO3,aq 0.10753E-13 -13.9685 0.10753E-13 -13.9685 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.90667E-16 -16.0426 0.75865E-16 -16.1200 0.83674E+00 -0.0774 60 MgCl+ 0.29204E-14 -14.5346 0.24437E-14 -14.6120 0.83674E+00 -0.0774 61 MgOH+ 0.68905E-10 -10.1618 0.57656E-10 -10.2392 0.83674E+00 -0.0774 63 MnO,aq 0.18030E-08 -8.7440 0.18030E-08 -8.7440 0.10000E+01 0.0000 64 MnOH+ 0.46721E-09 -9.3305 0.39093E-09 -9.4079 0.83674E+00 -0.0774 65 MnO2-2 0.20946E-10 -10.6789 0.10852E-10 -10.9645 0.51807E+00 -0.2856 66 HMnO2- 0.21139E-09 -9.6749 0.17654E-09 -9.7532 0.83514E+00 -0.0782 69 MnCl+ 0.10842E-13 -13.9649 0.90723E-14 -14.0423 0.83674E+00 -0.0774 71 NaCl,aq 0.84426E-06 -6.0735 0.84426E-06 -6.0735 0.10000E+01 0.0000 72 NaOH,aq 0.96047E-04 -4.0175 0.96047E-04 -4.0175 0.10000E+01 0.0000 74 OH- 0.93336E-02 -2.0300 0.77808E-02 -2.1090 0.83363E+00 -0.0790 79 HPO3-2 0.16370E-14 -14.7859 0.84809E-15 -15.0716 0.51807E+00 -0.2856 81 H2PO3- 0.15121E-18 -18.8204 0.12629E-18 -18.8986 0.83514E+00 -0.0782 82 H3PO4,aq 0.90607E-18 -18.0428 0.90607E-18 -18.0428 0.10000E+01 0.0000 83 H2PO4- 0.38500E-10 -10.4145 0.32184E-10 -10.4924 0.83593E+00 -0.0778 84 PO4-3 0.10645E-08 -8.9729 0.25815E-09 -9.5881 0.24252E+00 -0.6153 88 HP2O7-3 0.94491E-18 -18.0246 0.21839E-18 -18.6608 0.23113E+00 -0.6362 89 P2O7-4 0.91214E-17 -17.0399 0.70261E-18 -18.1533 0.77028E-01 -1.1133 90 H2S,aq 0.65628E-08 -8.1829 0.65401E-08 -8.1844 0.99654E+00 -0.0015 91 S2-2 0.29986E-14 -14.5231 0.15535E-14 -14.8087 0.51807E+00 -0.2856 97 SO3-2 0.12873E-17 -17.8903 0.67655E-18 -18.1697 0.52557E+00 -0.2794 99 HSO4- 0.38403E-19 -19.4156 0.32165E-19 -19.4926 0.83756E+00 -0.0770 Charge balance for all species = 0.6985E-10 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.8837969E-10 -.2228388E-01 -.2242176E+02 0.0000 2 H2O 0.1000000E+01 0.5550489E+02 0.9981986E+06 0.0000 3 Cl- 0.1837607E-03 0.1846053E-03 0.6533432E+01 6.3153 4 SO4-- 0.8657358E-12 -.1946407E-04 -.1866499E+01 7.9112 5 HCO3- 0.3203445E-06 0.1748727E-04 0.1065169E+01 3.5573 6 HS- 0.3411765E-04 0.5358829E-04 0.1769190E+01 5.5841 7 Al+++ 0.9722712E-29 0.5311885E-05 0.1430734E+00 0.7390 8 H4SiO4 0.6959646E-03 0.1352453E-01 0.1297655E+04 -3.1574 9 Ca++ 0.1352688E-06 0.2321322E-06 0.9287219E-02 13.1018 10 Mg++ 0.2116195E-10 0.9329843E-10 0.2264327E-05 9.2942 11 Fe++ 0.5832518E-13 0.3626031E-07 0.2021508E-02 6.7350 12 K+ 0.1566675E-03 0.1574216E-03 0.6144797E+01 6.2467 13 Na+ 0.1988034E-01 0.2232682E-01 0.5123967E+03 8.3494 14 Mn++ 0.1867743E-10 0.2521217E-08 0.1382698E-03 9.2408 15 HPO4-- 0.4524772E-07 0.4635068E-07 0.4440956E-02 12.6295 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.4139626E+02 -.1665499E-01 -.4137960E+02 0.0000000E+00 2 H2O 0.2416974E+02 0.4148441E+02 -.1731467E+02 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.6930900E-01 -.1454747E-04 0.6932355E-01 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.6928349E-01 0.4005194E-04 -.6932355E-01 0.0000000E+00 7 Al+++ 0.8151851E+01 0.3970108E-05 0.8151847E+01 0.0000000E+00 8 H4SiO4 0.2603195E+02 0.1010825E-01 0.2602184E+02 0.0000000E+00 9 Ca++ 0.2875370E+01 0.1734959E-06 0.2875370E+01 0.0000000E+00 10 Mg++ 0.1984126E+01 0.6973133E-10 0.1984126E+01 0.0000000E+00 11 Fe++ 0.1782521E+01 0.2710099E-07 0.1782521E+01 0.0000000E+00 12 K+ 0.5307854E+00 0.1176571E-03 0.5306677E+00 0.0000000E+00 13 Na+ 0.3138268E+01 0.1668709E-01 0.3121581E+01 0.0000000E+00 14 Mn++ 0.4334647E-01 0.1884360E-08 0.4334647E-01 0.0000000E+00 15 HPO4-- 0.1479394E-01 0.3464254E-07 0.1479390E-01 0.0000000E+00 Chg. balance for solid moles: -.1261E-13 Mass of aqueous solution: 0.748703E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 2499.9990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 3.119 0.494 817.8 2.913 29.95 313.9 andradite 0.2773 -0.557 140.9 2.149 5.160 36.61 grossular 0.6715E-01 -1.173 30.25 1.481 1.108 8.416 apatite-OH 0.4931E-02 -2.307 2.477 0.394 0.9070E-01 0.7871 clinochlore 0.3558 -0.449 197.8 2.296 7.241 75.22 daphnite 0.1030 -0.987 73.49 1.866 2.691 22.27 chlorite-Mn 0.8669E-02 -2.062 6.146 0.789 0.2250 1.959 diopside 0.1267 -0.897 27.44 1.438 1.005 8.387 hedenbergite 0.3286E-01 -1.483 8.153 0.911 0.2985 2.233 microcline 0.4654 -0.332 129.5 2.112 4.743 50.60 stilbite 1.615 0.208 1138. 3.056 41.66 530.7 stilpnomelane-Fe 0.1306 -0.884 140.8 2.149 5.155 48.63 tr.625ac.25prg.125 0.2164E-01 -1.665 18.50 1.267 0.6772 5.953 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8050E+00 0.8050E+00 1.0000 -0.094 grossular 0.1950E+00 0.1950E+00 1.0000 -0.710 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.7611E+00 0.7611E+00 1.0000 -0.119 daphnite 0.2203E+00 0.2203E+00 1.0000 -0.657 chlorite-Mn 0.1855E-01 0.1855E-01 1.0000 -1.732 diopside 0.7941E+00 0.7941E+00 1.0000 -0.100 hedenbergite 0.2059E+00 0.2059E+00 1.0000 -0.686 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 tr.625ac.25prg.125 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 2731.071247 g Volume = 1105.701254 cm3 Porosity: -10.4597% V(tot) - V(min): -.10470E+03 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 2499.9990000 g log = 3.3979 Original solution: 1000.0103000 g Original solution / Rock added: 0.40 (Water/Rock Ratio), log = -0.3979 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0600 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9630E+00 0.9854 0.1006E+01 0.1021E+01 CO2,gas 0.4261E-08 1.0069 0.4548E-08 0.4517E-08 CH4,gas 0.2263E-01 1.0124 0.2429E-01 0.2399E-01 H2,gas 0.1434E-01 1.0006 0.1521E-01 0.1520E-01 H2S,gas 0.1703E-06 0.9959 0.1798E-06 0.1805E-06 S2,gas 0.4949E-29 1.0000 0.5246E-29 0.5246E-29 CO,gas 0.1739E-13 1.0000 0.1843E-13 0.1843E-13 SO3,gas 0.8840E-48 1.0000 0.9371E-48 0.9371E-48 SO2,gas 0.5230E-27 1.0000 0.5544E-27 0.5544E-27 HCl,gas 0.3476E-17 1.0000 0.3685E-17 0.3685E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 16 albite -0.38 -0.38 0.00 0.000 -0.94784E-12 22 andradite 39.01 39.01 0.00 0.000 0.00000E+00 23 grossular 32.73 32.73 0.00 0.000 0.00000E+00 32 apatite-OH -18.15 -18.15 0.00 0.000 -0.60662E-11 46 clinochlore 39.07 39.07 0.00 0.000 -0.12132E-10 47 daphnite 28.97 28.97 0.00 0.000 -0.60662E-11 48 chlorite-Mn 46.87 46.87 0.00 0.000 -0.12132E-10 67 diopside 16.18 16.18 0.00 0.000 0.00000E+00 68 hedenbergite 14.21 14.21 0.00 0.000 0.00000E+00 116 microcline -2.49 -2.49 0.00 0.000 0.15165E-11 163 stilbite -7.52 -7.52 0.00 0.000 -0.33364E-10 164 stilpnomelane-Fe 13.02 13.02 0.00 0.000 -0.27298E-10 245 tr.625ac.25prg.125 45.16 45.16 0.00 0.000 0.12132E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -16.70 -10.04 -3.347 0.17145E+05 -8.342 3 CH4,gas 4.54 1.23 -3.31 -0.828 0.56578E+04 -1.615 4 H2,gas 8.00 4.48 -3.52 -2.010 0.60050E+04 -1.818 5 H2S,gas -6.23 -14.67 -8.44 -4.222 0.14418E+05 -6.745 6 S2,gas -7.34 -38.31 -30.98 -4.766 0.52896E+05 -29.280 7 CO,gas 3.21 -12.22 -15.43 -4.749 0.26352E+05 -13.734 8 SO3,gas 17.12 -32.61 -49.73 -12.432 0.84908E+05 -48.028 9 SO2,gas 0.83 -28.12 -28.96 -7.721 0.49440E+05 -27.256 10 HCl,gas 5.19 -13.94 -19.13 -9.566 0.32668E+05 -17.434 11 acmite 7.71 6.53 -1.18 -0.123 0.20176E+04 15 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 19 spessartine 24.46 19.73 -4.73 -0.236 0.80749E+04 20 analcite 3.32 2.77 -0.55 -0.061 0.93623E+03 26 annite 20.12 17.72 -2.40 -0.134 0.41064E+04 27 phlogopite 27.06 25.40 -1.67 -0.093 0.28489E+04 29 anorthite 12.71 8.27 -4.45 -0.342 0.75902E+04 35 aragonite 0.97 -3.60 -4.57 -1.522 0.77962E+04 36 brucite 12.57 9.29 -3.27 -0.655 0.55909E+04 37 calcite 0.81 -3.60 -4.41 -1.470 0.75320E+04 38 carnegieite-low 9.02 5.93 -3.09 -0.442 0.52801E+04 39 carnegieite-high 10.09 5.93 -4.16 -0.595 0.71071E+04 40 carpholite-Mg 8.58 4.46 -4.12 -0.275 0.70428E+04 41 carpholite-Fe 6.71 1.90 -4.81 -0.321 0.82206E+04 42 celadonite 5.34 3.65 -1.69 -0.099 0.28879E+04 43 celadonite-Fe 3.88 1.09 -2.79 -0.164 0.47561E+04 44 chrysotile 23.89 21.57 -2.32 -0.194 0.39692E+04 49 chlorite-Al-free 47.17 43.14 -4.04 -0.168 0.68936E+04 51 chloritoid-Fe 9.17 5.06 -4.12 -0.275 0.70315E+04 52 chloritoid-Mn 11.40 7.56 -3.84 -0.256 0.65562E+04 54 coesite -2.38 -3.16 -0.78 -0.260 0.13341E+04 61 cristobalite -2.56 -3.16 -0.60 -0.199 0.10195E+04 63 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71234E+04 65 diaspore 2.87 0.74 -2.13 -0.356 0.36449E+04 66 diamond -3.10 -7.74 -4.63 -1.324 0.79110E+04 71 enstatite 17.26 12.27 -4.99 -0.499 0.85225E+04 73 clinoenstatite 17.17 12.27 -4.89 -0.489 0.83541E+04 75 epidote 24.67 22.70 -1.97 -0.095 0.33585E+04 76 clinozoisite 22.81 18.95 -3.86 -0.175 0.65867E+04 77 epidote-Fe 29.84 26.46 -3.38 -0.176 0.57768E+04 78 fayalite 14.05 10.31 -3.73 -0.533 0.63743E+04 79 ferrosilite 11.15 7.16 -3.99 -0.399 0.68202E+04 83 gibbsite 4.08 0.74 -3.34 -0.477 0.57035E+04 84 glaucophane 22.97 20.80 -2.17 -0.059 0.37133E+04 85 glaucophane-Fe 17.28 13.12 -4.15 -0.112 0.70919E+04 86 graphite -3.55 -7.74 -4.19 -1.197 0.71533E+04 87 greenalite 16.14 13.89 -2.25 -0.187 0.38408E+04 90 hematite 12.57 8.99 -3.58 -0.434 0.61112E+04 91 heulandite -5.83 -7.52 -1.69 -0.077 0.28938E+04 95 jadeite 4.22 2.77 -1.44 -0.144 0.24617E+04 97 kalsilite 7.58 3.83 -3.76 -0.537 0.64125E+04 98 kaolinite -1.33 -4.84 -3.50 -0.319 0.59831E+04 101 laumontite 2.88 1.95 -0.93 -0.062 0.15935E+04 102 lawsonite 9.62 8.27 -1.35 -0.090 0.23069E+04 103 leucite 4.12 0.67 -3.45 -0.345 0.58873E+04 105 lizardite 23.24 21.57 -1.68 -0.140 0.28618E+04 107 magnetite 20.09 15.72 -4.37 -0.356 0.74536E+04 108 minnesotaite 10.39 7.58 -2.81 -0.165 0.48028E+04 112 manganosite 14.06 9.24 -4.82 -1.204 0.82254E+04 120 muscovite 2.58 -1.01 -3.59 -0.211 0.61314E+04 121 paragonite 4.24 1.09 -3.15 -0.185 0.53705E+04 122 nepheline 8.34 5.93 -2.41 -0.344 0.41124E+04 128 periclase-Fe 11.63 6.73 -4.89 -1.223 0.83523E+04 134 phlogopite-Na 29.65 27.50 -2.15 -0.119 0.36677E+04 136 prehnite 19.37 18.21 -1.16 -0.068 0.19848E+04 137 prehnite-Fe 22.50 21.96 -0.53 -0.032 0.91156E+03 138 pumpellyite-Fe 46.27 43.89 -2.38 -0.053 0.40579E+04 139 pumpellyite-Mg 48.99 46.45 -2.54 -0.057 0.43418E+04 143 pyrrhotite -4.26 -7.94 -3.68 -1.226 0.62821E+04 144 pyrrhotiteFe0.875 -6.02 -9.34 -3.32 -1.221 0.56693E+04 145 pyroxmangite 7.40 6.08 -1.32 -0.263 0.22458E+04 146 pyrophyllite -6.18 -11.15 -4.98 -0.311 0.84961E+04 147 quartz -2.99 -3.16 -0.17 -0.056 0.28682E+03 152 rhodonite 7.45 6.08 -1.36 -0.272 0.23261E+04 153 sanidine -1.28 -2.49 -1.21 -0.093 0.20677E+04 165 stilpnomelane-Mg 27.44 25.81 -1.63 -0.049 0.27803E+04 171 talc 16.49 15.25 -1.24 -0.073 0.21140E+04 174 tephroite 18.09 15.32 -2.76 -0.395 0.47154E+04 178 tridymite -2.63 -3.16 -0.53 -0.177 0.90679E+03 179 tremolite 47.87 47.42 -0.45 -0.012 0.77495E+03 180 ferroactinolite 38.45 34.62 -3.83 -0.104 0.65449E+04 181 troilite-low -4.41 -7.94 -3.53 -1.176 0.60249E+04 183 vesuvianite 223.47 218.82 -4.65 -0.036 0.79433E+04 187 wairakite 3.95 1.95 -2.00 -0.118 0.34154E+04 188 walstromite 11.51 9.94 -1.56 -0.313 0.26719E+04 189 wollastonite 10.46 9.94 -0.52 -0.103 0.88229E+03 190 pseudo-wollastonite 11.00 9.94 -1.06 -0.211 0.18021E+04 191 zoisite 22.85 18.95 -3.90 -0.177 0.66608E+04 192 akaganeite 7.75 4.49 -3.26 -0.705 0.55681E+04 199 chalcedony -2.80 -3.16 -0.35 -0.118 0.60611E+03 201 montmorillonite-Ca -2.29 -6.17 -3.88 -0.240 0.66180E+04 202 montmorillonite-K -2.24 -6.27 -4.03 -0.247 0.68816E+04 203 montmorillonite-Mg -2.48 -6.79 -4.32 -0.267 0.73678E+04 204 montmorillonite-Na -2.04 -5.57 -3.54 -0.216 0.60365E+04 205 nontronite-Ca 3.21 -0.19 -3.41 -0.221 0.58215E+04 206 nontronite-H 2.53 -2.36 -4.89 -0.328 0.83485E+04 207 nontronite-K 3.34 -0.30 -3.64 -0.233 0.62084E+04 208 nontronite-Mg 3.07 -0.82 -3.90 -0.253 0.66554E+04 209 nontronite-Na 3.52 0.40 -3.12 -0.200 0.53292E+04 224 tobermorite 9.82 7.76 -2.07 -0.564 0.35287E+04 230 alabandite -0.98 -5.43 -4.46 -1.485 0.76081E+04 233 boehmite 4.41 0.74 -3.67 -0.611 0.62619E+04 235 ferrous-oxide 9.81 6.73 -3.08 -0.769 0.52532E+04 240 silica-amorphous -2.09 -3.16 -1.07 -0.355 0.18203E+04 242 an20ab80 2.02 1.35 -0.67 -0.052 0.11472E+04 243 an25ab75 2.65 1.78 -0.87 -0.067 0.14810E+04 244 an30ab70 3.28 2.21 -1.07 -0.082 0.18243E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 100.0000000 g Current total amount of reactant added: 2499.9990000 g New total amount of reactant added: 2599.9990000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.5220E-10 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 11 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 2599.9990000 Water: Moles liquid = 0.4093E+02 kg liquid = 0.7374E+00 Moles total = 0.2292E+02 kg total = 0.4128E+00 Activity = 1.0000 Stoichiometric ionic strength = .1135835E-01 Osmotic coef. = 0.9690 True ionic strength = .2003980E-01 Chg. balance for total moles = 0.5220E-10 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.88387E-10 -10.0536 0.74262E-10 -10.1292 0.84019E+00 -0.0756 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.18626E-03 -3.7299 0.15556E-03 -3.8081 0.83514E+00 -0.0782 4 SO4-- 0.87749E-12 -12.0568 0.45556E-12 -12.3415 0.51916E+00 -0.2847 5 HCO3- 0.32469E-06 -6.4885 0.27156E-06 -6.5661 0.83636E+00 -0.0776 6 HS- 0.34582E-04 -4.4611 0.28885E-04 -4.5393 0.83526E+00 -0.0782 7 Al+++ 0.97253E-29 -29.0121 0.22454E-29 -29.6487 0.23088E+00 -0.6366 8 H4SiO4 0.69597E-03 -3.1574 0.69597E-03 -3.1574 0.10000E+01 0.0000 9 Ca++ 0.13529E-06 -6.8687 0.69722E-07 -7.1566 0.51535E+00 -0.2879 10 Mg++ 0.21166E-10 -10.6744 0.10858E-10 -10.9643 0.51299E+00 -0.2899 11 Fe++ 0.58335E-13 -13.2341 0.29958E-13 -13.5235 0.51355E+00 -0.2894 12 K+ 0.15668E-03 -3.8050 0.13107E-03 -3.8825 0.83656E+00 -0.0775 13 Na+ 0.19882E-01 -1.7015 0.16601E-01 -1.7799 0.83499E+00 -0.0783 14 Mn++ 0.18683E-10 -10.7285 0.96027E-11 -11.0176 0.51398E+00 -0.2891 15 HPO4-- 0.45242E-07 -7.3445 0.23491E-07 -7.6291 0.51924E+00 -0.2846 16 HSiO3- 0.10478E-01 -1.9797 0.87508E-02 -2.0580 0.83514E+00 -0.0782 17 Ca(HSiO3)+ 0.16606E-07 -7.7797 0.13895E-07 -7.8571 0.83674E+00 -0.0774 18 Mg(HSiO3)+ 0.32183E-11 -11.4924 0.26929E-11 -11.5698 0.83674E+00 -0.0774 19 NaHSiO3,aq 0.23496E-02 -2.6290 0.23496E-02 -2.6290 0.10000E+01 0.0000 20 AlO+ 0.66199E-16 -16.1792 0.55391E-16 -16.2566 0.83674E+00 -0.0774 22 HAlO2,aq 0.14854E-09 -9.8282 0.14854E-09 -9.8282 0.10000E+01 0.0000 23 AlO2- 0.53113E-05 -5.2748 0.44277E-05 -5.3538 0.83363E+00 -0.0790 24 CH4,aq 0.16784E-04 -4.7751 0.16726E-04 -4.7766 0.99654E+00 -0.0015 25 C2H6,aq 0.41432E-14 -14.3827 0.41289E-14 -14.3842 0.99654E+00 -0.0015 29 CO,aq 0.12539E-16 -16.9018 0.12539E-16 -16.9018 0.10000E+01 0.0000 30 CO2,aq 0.43241E-10 -10.3641 0.43091E-10 -10.3656 0.99654E+00 -0.0015 31 CO3-2 0.61654E-06 -6.2100 0.31940E-06 -6.4957 0.51806E+00 -0.2856 32 CaCO3,aq 0.27924E-09 -9.5540 0.27924E-09 -9.5540 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.57760E-12 -12.2384 0.48330E-12 -12.3158 0.83674E+00 -0.0774 34 CaCl+ 0.20976E-10 -10.6783 0.17552E-10 -10.7557 0.83674E+00 -0.0774 35 CaCl2,aq 0.64866E-15 -15.1880 0.64866E-15 -15.1880 0.10000E+01 0.0000 36 CaOH+ 0.79968E-07 -7.0971 0.66913E-07 -7.1745 0.83674E+00 -0.0774 37 CaSO4,aq 0.10086E-16 -16.9963 0.10086E-16 -16.9963 0.10000E+01 0.0000 38 HCl,aq 0.21168E-14 -14.6743 0.21168E-14 -14.6743 0.10000E+01 0.0000 43 FeCl+ 0.88155E-17 -17.0548 0.73762E-17 -17.1322 0.83674E+00 -0.0774 46 FeO,aq 0.21113E-09 -9.6755 0.21113E-09 -9.6755 0.10000E+01 0.0000 47 FeOH+ 0.15694E-10 -10.8043 0.13131E-10 -10.8817 0.83674E+00 -0.0774 48 HFeO2- 0.35619E-07 -7.4483 0.29747E-07 -7.5266 0.83514E+00 -0.0782 49 FeO+ 0.10999E-16 -16.9587 0.92029E-17 -17.0361 0.83674E+00 -0.0774 51 FeO2- 0.40887E-09 -9.3884 0.34146E-09 -9.4667 0.83514E+00 -0.0782 52 HFeO2,aq 0.32251E-11 -11.4915 0.32251E-11 -11.4915 0.10000E+01 0.0000 53 H2,aq 0.11623E-04 -4.9347 0.11583E-04 -4.9362 0.99654E+00 -0.0015 54 KCl,aq 0.36954E-09 -9.4323 0.36954E-09 -9.4323 0.10000E+01 0.0000 56 KOH,aq 0.75375E-06 -6.1228 0.75375E-06 -6.1228 0.10000E+01 0.0000 57 KSO4- 0.11095E-14 -14.9549 0.92657E-15 -15.0331 0.83514E+00 -0.0782 58 MgCO3,aq 0.10900E-13 -13.9626 0.10900E-13 -13.9626 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.91911E-16 -16.0366 0.76905E-16 -16.1140 0.83674E+00 -0.0774 60 MgCl+ 0.29607E-14 -14.5286 0.24773E-14 -14.6060 0.83674E+00 -0.0774 61 MgOH+ 0.68910E-10 -10.1617 0.57660E-10 -10.2391 0.83674E+00 -0.0774 63 MnO,aq 0.18032E-08 -8.7439 0.18032E-08 -8.7439 0.10000E+01 0.0000 64 MnOH+ 0.46731E-09 -9.3304 0.39101E-09 -9.4078 0.83674E+00 -0.0774 65 MnO2-2 0.20946E-10 -10.6789 0.10851E-10 -10.9645 0.51806E+00 -0.2856 66 HMnO2- 0.21140E-09 -9.6749 0.17655E-09 -9.7531 0.83514E+00 -0.0782 69 MnCl+ 0.10993E-13 -13.9589 0.91985E-14 -14.0363 0.83674E+00 -0.0774 71 NaCl,aq 0.85582E-06 -6.0676 0.85582E-06 -6.0676 0.10000E+01 0.0000 72 NaOH,aq 0.96047E-04 -4.0175 0.96047E-04 -4.0175 0.10000E+01 0.0000 74 OH- 0.93329E-02 -2.0300 0.77802E-02 -2.1090 0.83363E+00 -0.0790 79 HPO3-2 0.16368E-14 -14.7860 0.84796E-15 -15.0716 0.51806E+00 -0.2856 81 H2PO3- 0.15120E-18 -18.8204 0.12628E-18 -18.8987 0.83514E+00 -0.0782 82 H3PO4,aq 0.90607E-18 -18.0428 0.90607E-18 -18.0428 0.10000E+01 0.0000 83 H2PO4- 0.38498E-10 -10.4146 0.32181E-10 -10.4924 0.83593E+00 -0.0778 84 PO4-3 0.10643E-08 -8.9730 0.25809E-09 -9.5882 0.24251E+00 -0.6153 88 HP2O7-3 0.94475E-18 -18.0247 0.21835E-18 -18.6609 0.23111E+00 -0.6362 89 P2O7-4 0.91195E-17 -17.0400 0.70240E-18 -18.1534 0.77022E-01 -1.1134 90 H2S,aq 0.66527E-08 -8.1770 0.66296E-08 -8.1785 0.99654E+00 -0.0015 91 S2-2 0.30809E-14 -14.5113 0.15961E-14 -14.7969 0.51806E+00 -0.2856 97 SO3-2 0.13047E-17 -17.8845 0.68571E-18 -18.1639 0.52556E+00 -0.2794 99 HSO4- 0.38927E-19 -19.4098 0.32603E-19 -19.4867 0.83755E+00 -0.0770 Charge balance for all species = 0.7080E-10 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.8838680E-10 -.2228252E-01 -.2242039E+02 0.0000 2 H2O 0.1000000E+01 0.5550489E+02 0.9981985E+06 0.0000 3 Cl- 0.1862634E-03 0.1871196E-03 0.6622415E+01 6.3211 4 SO4-- 0.8774880E-12 -.1968967E-04 -.1888132E+01 7.9170 5 HCO3- 0.3246912E-06 0.1772544E-04 0.1079676E+01 3.5631 6 HS- 0.3458232E-04 0.5427865E-04 0.1791982E+01 5.5899 7 Al+++ 0.9725336E-29 0.5311488E-05 0.1430627E+00 0.7390 8 H4SiO4 0.6959657E-03 0.1352382E-01 0.1297587E+04 -3.1574 9 Ca++ 0.1352919E-06 0.2321671E-06 0.9288612E-02 13.1018 10 Mg++ 0.2116557E-10 0.9330797E-10 0.2264559E-05 9.2942 11 Fe++ 0.5833522E-13 0.3625777E-07 0.2021367E-02 6.7350 12 K+ 0.1566801E-03 0.1574343E-03 0.6145290E+01 6.2467 13 Na+ 0.1988195E-01 0.2232845E-01 0.5124339E+03 8.3494 14 Mn++ 0.1868319E-10 0.2521584E-08 0.1382899E-03 9.2409 15 HPO4-- 0.4524198E-07 0.4634475E-07 0.4440388E-02 12.6294 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.4305211E+02 -.1643020E-01 -.4303568E+02 0.0000000E+00 2 H2O 0.2291620E+02 0.4092699E+02 -.1801080E+02 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.7208034E-01 -.1451834E-04 0.7209486E-01 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.7205484E-01 0.4002281E-04 -.7209486E-01 0.0000000E+00 7 Al+++ 0.8477925E+01 0.3916470E-05 0.8477921E+01 0.0000000E+00 8 H4SiO4 0.2707323E+02 0.9971902E-02 0.2706325E+02 0.0000000E+00 9 Ca++ 0.2990384E+01 0.1711903E-06 0.2990384E+01 0.0000000E+00 10 Mg++ 0.2063491E+01 0.6880141E-10 0.2063491E+01 0.0000000E+00 11 Fe++ 0.1853822E+01 0.2673497E-07 0.1853822E+01 0.0000000E+00 12 K+ 0.5520168E+00 0.1160855E-03 0.5519007E+00 0.0000000E+00 13 Na+ 0.3263792E+01 0.1646407E-01 0.3247328E+01 0.0000000E+00 14 Mn++ 0.4508033E-01 0.1859311E-08 0.4508033E-01 0.0000000E+00 15 HPO4-- 0.1538569E-01 0.3417268E-07 0.1538566E-01 0.0000000E+00 Chg. balance for solid moles: 0.5287E-14 Mass of aqueous solution: 0.738643E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 2599.9990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 3.245 0.511 850.8 2.930 29.95 326.6 andradite 0.2884 -0.540 146.5 2.166 5.160 38.07 grossular 0.6983E-01 -1.156 31.46 1.498 1.107 8.752 apatite-OH 0.5129E-02 -2.290 2.576 0.411 0.9070E-01 0.8186 clinochlore 0.3700 -0.432 205.6 2.313 7.240 78.22 daphnite 0.1071 -0.970 76.42 1.883 2.691 23.16 chlorite-Mn 0.9016E-02 -2.045 6.392 0.806 0.2250 2.037 diopside 0.1322 -0.879 28.62 1.457 1.008 8.747 hedenbergite 0.3427E-01 -1.465 8.503 0.930 0.2994 2.329 microcline 0.4840 -0.315 134.7 2.129 4.743 52.62 stilbite 1.679 0.225 1183. 3.073 41.65 551.8 stilpnomelane-Fe 0.1358 -0.867 146.4 2.166 5.155 50.58 tr.625ac.25prg.125 0.2247E-01 -1.648 19.21 1.283 0.6763 6.182 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8051E+00 0.8051E+00 1.0000 -0.094 grossular 0.1949E+00 0.1949E+00 1.0000 -0.710 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.7611E+00 0.7611E+00 1.0000 -0.119 daphnite 0.2203E+00 0.2203E+00 1.0000 -0.657 chlorite-Mn 0.1855E-01 0.1855E-01 1.0000 -1.732 diopside 0.7941E+00 0.7941E+00 1.0000 -0.100 hedenbergite 0.2059E+00 0.2059E+00 1.0000 -0.686 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 tr.625ac.25prg.125 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 2840.321911 g Volume = 1149.904318 cm3 Porosity: -10.4616% V(tot) - V(min): -.10890E+03 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 2599.9990000 g log = 3.4150 Original solution: 1000.0103000 g Original solution / Rock added: 0.38 (Water/Rock Ratio), log = -0.4150 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0604 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9627E+00 0.9854 0.1006E+01 0.1021E+01 CO2,gas 0.4318E-08 1.0069 0.4610E-08 0.4579E-08 CH4,gas 0.2293E-01 1.0124 0.2462E-01 0.2432E-01 H2,gas 0.1433E-01 1.0006 0.1521E-01 0.1520E-01 H2S,gas 0.1726E-06 0.9959 0.1822E-06 0.1830E-06 S2,gas 0.5084E-29 1.0000 0.5391E-29 0.5391E-29 CO,gas 0.1762E-13 1.0000 0.1868E-13 0.1868E-13 SO3,gas 0.8958E-48 1.0000 0.9499E-48 0.9499E-48 SO2,gas 0.5300E-27 1.0000 0.5620E-27 0.5620E-27 HCl,gas 0.3523E-17 1.0000 0.3735E-17 0.3735E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 16 albite -0.38 -0.38 0.00 0.000 -0.94784E-12 22 andradite 39.01 39.01 0.00 0.000 -0.12132E-10 23 grossular 32.73 32.73 0.00 0.000 -0.12132E-10 32 apatite-OH -18.15 -18.15 0.00 0.000 -0.12132E-10 46 clinochlore 39.07 39.07 0.00 0.000 -0.24265E-10 47 daphnite 28.97 28.97 0.00 0.000 -0.12132E-10 48 chlorite-Mn 46.87 46.87 0.00 0.000 0.00000E+00 67 diopside 16.18 16.18 0.00 0.000 -0.12132E-10 68 hedenbergite 14.21 14.21 0.00 0.000 -0.60662E-11 116 microcline -2.49 -2.49 0.00 0.000 0.15165E-11 163 stilbite -7.52 -7.52 0.00 0.000 0.15165E-10 164 stilpnomelane-Fe 13.02 13.02 0.00 0.000 0.21232E-10 245 tr.625ac.25prg.125 45.16 45.16 0.00 0.000 -0.12132E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -16.70 -10.04 -3.345 0.17135E+05 -8.336 3 CH4,gas 4.54 1.24 -3.31 -0.827 0.56478E+04 -1.609 4 H2,gas 8.00 4.48 -3.52 -2.010 0.60050E+04 -1.818 5 H2S,gas -6.23 -14.67 -8.44 -4.219 0.14408E+05 -6.739 6 S2,gas -7.34 -38.30 -30.97 -4.764 0.52876E+05 -29.268 7 CO,gas 3.21 -12.21 -15.43 -4.747 0.26342E+05 -13.729 8 SO3,gas 17.12 -32.60 -49.72 -12.430 0.84898E+05 -48.022 9 SO2,gas 0.83 -28.12 -28.95 -7.720 0.49430E+05 -27.250 10 HCl,gas 5.19 -13.94 -19.13 -9.563 0.32658E+05 -17.428 11 acmite 7.71 6.53 -1.18 -0.123 0.20176E+04 15 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 19 spessartine 24.46 19.73 -4.73 -0.236 0.80746E+04 20 analcite 3.32 2.77 -0.55 -0.061 0.93624E+03 26 annite 20.12 17.72 -2.40 -0.134 0.41064E+04 27 phlogopite 27.06 25.40 -1.67 -0.093 0.28489E+04 29 anorthite 12.71 8.27 -4.45 -0.342 0.75902E+04 35 aragonite 0.97 -3.59 -4.56 -1.520 0.77862E+04 36 brucite 12.57 9.29 -3.27 -0.655 0.55909E+04 37 calcite 0.81 -3.59 -4.41 -1.468 0.75219E+04 38 carnegieite-low 9.02 5.93 -3.09 -0.442 0.52801E+04 39 carnegieite-high 10.09 5.93 -4.16 -0.595 0.71071E+04 40 carpholite-Mg 8.58 4.46 -4.12 -0.275 0.70428E+04 41 carpholite-Fe 6.71 1.90 -4.81 -0.321 0.82206E+04 42 celadonite 5.34 3.65 -1.69 -0.099 0.28879E+04 43 celadonite-Fe 3.88 1.09 -2.79 -0.164 0.47561E+04 44 chrysotile 23.89 21.57 -2.32 -0.194 0.39692E+04 49 chlorite-Al-free 47.17 43.14 -4.04 -0.168 0.68936E+04 51 chloritoid-Fe 9.17 5.06 -4.12 -0.275 0.70315E+04 52 chloritoid-Mn 11.40 7.56 -3.84 -0.256 0.65561E+04 54 coesite -2.38 -3.16 -0.78 -0.260 0.13341E+04 61 cristobalite -2.56 -3.16 -0.60 -0.199 0.10195E+04 63 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71234E+04 65 diaspore 2.87 0.74 -2.13 -0.356 0.36449E+04 66 diamond -3.10 -7.73 -4.63 -1.322 0.79010E+04 71 enstatite 17.26 12.27 -4.99 -0.499 0.85225E+04 73 clinoenstatite 17.17 12.27 -4.89 -0.489 0.83541E+04 75 epidote 24.67 22.70 -1.97 -0.095 0.33585E+04 76 clinozoisite 22.81 18.95 -3.86 -0.175 0.65867E+04 77 epidote-Fe 29.84 26.46 -3.38 -0.176 0.57768E+04 78 fayalite 14.05 10.31 -3.73 -0.533 0.63743E+04 79 ferrosilite 11.15 7.16 -3.99 -0.399 0.68202E+04 83 gibbsite 4.08 0.74 -3.34 -0.477 0.57035E+04 84 glaucophane 22.97 20.80 -2.17 -0.059 0.37133E+04 85 glaucophane-Fe 17.28 13.12 -4.15 -0.112 0.70919E+04 86 graphite -3.55 -7.73 -4.18 -1.195 0.71432E+04 87 greenalite 16.14 13.89 -2.25 -0.187 0.38408E+04 90 hematite 12.57 8.99 -3.58 -0.434 0.61112E+04 91 heulandite -5.83 -7.52 -1.69 -0.077 0.28938E+04 95 jadeite 4.22 2.77 -1.44 -0.144 0.24617E+04 97 kalsilite 7.58 3.83 -3.76 -0.537 0.64125E+04 98 kaolinite -1.33 -4.84 -3.50 -0.319 0.59831E+04 101 laumontite 2.88 1.95 -0.93 -0.062 0.15935E+04 102 lawsonite 9.62 8.27 -1.35 -0.090 0.23069E+04 103 leucite 4.12 0.67 -3.45 -0.345 0.58873E+04 105 lizardite 23.24 21.57 -1.68 -0.140 0.28618E+04 107 magnetite 20.09 15.72 -4.37 -0.356 0.74536E+04 108 minnesotaite 10.39 7.58 -2.81 -0.165 0.48028E+04 112 manganosite 14.06 9.24 -4.82 -1.204 0.82253E+04 120 muscovite 2.58 -1.01 -3.59 -0.211 0.61314E+04 121 paragonite 4.24 1.09 -3.15 -0.185 0.53705E+04 122 nepheline 8.34 5.93 -2.41 -0.344 0.41124E+04 128 periclase-Fe 11.63 6.73 -4.89 -1.223 0.83523E+04 134 phlogopite-Na 29.65 27.50 -2.15 -0.119 0.36677E+04 136 prehnite 19.37 18.21 -1.16 -0.068 0.19848E+04 137 prehnite-Fe 22.50 21.96 -0.53 -0.032 0.91156E+03 138 pumpellyite-Fe 46.27 43.89 -2.38 -0.053 0.40579E+04 139 pumpellyite-Mg 48.99 46.45 -2.54 -0.057 0.43418E+04 143 pyrrhotite -4.26 -7.93 -3.67 -1.224 0.62720E+04 144 pyrrhotiteFe0.875 -6.02 -9.33 -3.31 -1.219 0.56592E+04 145 pyroxmangite 7.40 6.08 -1.32 -0.263 0.22457E+04 146 pyrophyllite -6.18 -11.15 -4.98 -0.311 0.84961E+04 147 quartz -2.99 -3.16 -0.17 -0.056 0.28682E+03 152 rhodonite 7.45 6.08 -1.36 -0.272 0.23260E+04 153 sanidine -1.28 -2.49 -1.21 -0.093 0.20677E+04 165 stilpnomelane-Mg 27.44 25.81 -1.63 -0.049 0.27803E+04 171 talc 16.49 15.25 -1.24 -0.073 0.21140E+04 174 tephroite 18.09 15.32 -2.76 -0.394 0.47152E+04 178 tridymite -2.63 -3.16 -0.53 -0.177 0.90679E+03 179 tremolite 47.87 47.42 -0.45 -0.012 0.77495E+03 180 ferroactinolite 38.45 34.62 -3.83 -0.104 0.65449E+04 181 troilite-low -4.41 -7.93 -3.52 -1.174 0.60148E+04 183 vesuvianite 223.47 218.82 -4.65 -0.036 0.79433E+04 187 wairakite 3.95 1.95 -2.00 -0.118 0.34154E+04 188 walstromite 11.51 9.94 -1.56 -0.313 0.26719E+04 189 wollastonite 10.46 9.94 -0.52 -0.103 0.88229E+03 190 pseudo-wollastonite 11.00 9.94 -1.06 -0.211 0.18021E+04 191 zoisite 22.85 18.95 -3.90 -0.177 0.66608E+04 192 akaganeite 7.75 4.49 -3.26 -0.705 0.55681E+04 199 chalcedony -2.80 -3.16 -0.35 -0.118 0.60611E+03 201 montmorillonite-Ca -2.29 -6.17 -3.88 -0.240 0.66180E+04 202 montmorillonite-K -2.24 -6.27 -4.03 -0.247 0.68816E+04 203 montmorillonite-Mg -2.48 -6.79 -4.32 -0.267 0.73678E+04 204 montmorillonite-Na -2.04 -5.57 -3.54 -0.216 0.60365E+04 205 nontronite-Ca 3.21 -0.19 -3.41 -0.221 0.58215E+04 206 nontronite-H 2.53 -2.36 -4.89 -0.328 0.83485E+04 207 nontronite-K 3.34 -0.30 -3.64 -0.233 0.62083E+04 208 nontronite-Mg 3.07 -0.82 -3.90 -0.253 0.66554E+04 209 nontronite-Na 3.52 0.40 -3.12 -0.200 0.53292E+04 224 tobermorite 9.82 7.76 -2.07 -0.564 0.35287E+04 230 alabandite -0.98 -5.43 -4.45 -1.483 0.75980E+04 233 boehmite 4.41 0.74 -3.67 -0.611 0.62619E+04 235 ferrous-oxide 9.81 6.73 -3.08 -0.769 0.52532E+04 240 silica-amorphous -2.09 -3.16 -1.07 -0.355 0.18203E+04 242 an20ab80 2.02 1.35 -0.67 -0.052 0.11472E+04 243 an25ab75 2.65 1.78 -0.87 -0.067 0.14810E+04 244 an30ab70 3.28 2.21 -1.07 -0.082 0.18244E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 100.0000000 g Current total amount of reactant added: 2599.9990000 g New total amount of reactant added: 2699.9990000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.5221E-10 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 11 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 2699.9990000 Water: Moles liquid = 0.4037E+02 kg liquid = 0.7273E+00 Moles total = 0.2166E+02 kg total = 0.3903E+00 Activity = 1.0000 Stoichiometric ionic strength = .1136049E-01 Osmotic coef. = 0.9690 True ionic strength = .2004147E-01 Chg. balance for total moles = 0.5221E-10 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.88394E-10 -10.0536 0.74268E-10 -10.1292 0.84019E+00 -0.0756 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.18884E-03 -3.7239 0.15770E-03 -3.8022 0.83513E+00 -0.0782 4 SO4-- 0.88956E-12 -12.0508 0.46182E-12 -12.3355 0.51915E+00 -0.2847 5 HCO3- 0.32916E-06 -6.4826 0.27529E-06 -6.5602 0.83636E+00 -0.0776 6 HS- 0.35060E-04 -4.4552 0.29284E-04 -4.5334 0.83526E+00 -0.0782 7 Al+++ 0.97280E-29 -29.0120 0.22459E-29 -29.6486 0.23087E+00 -0.6366 8 H4SiO4 0.69597E-03 -3.1574 0.69597E-03 -3.1574 0.10000E+01 0.0000 9 Ca++ 0.13532E-06 -6.8687 0.69733E-07 -7.1566 0.51534E+00 -0.2879 10 Mg++ 0.21169E-10 -10.6743 0.10859E-10 -10.9642 0.51298E+00 -0.2899 11 Fe++ 0.58346E-13 -13.2340 0.29963E-13 -13.5234 0.51354E+00 -0.2894 12 K+ 0.15669E-03 -3.8050 0.13108E-03 -3.8825 0.83656E+00 -0.0775 13 Na+ 0.19884E-01 -1.7015 0.16602E-01 -1.7798 0.83498E+00 -0.0783 14 Mn++ 0.18689E-10 -10.7284 0.96054E-11 -11.0175 0.51397E+00 -0.2891 15 HPO4-- 0.45236E-07 -7.3445 0.23488E-07 -7.6292 0.51922E+00 -0.2846 16 HSiO3- 0.10478E-01 -1.9797 0.87501E-02 -2.0580 0.83513E+00 -0.0782 17 Ca(HSiO3)+ 0.16607E-07 -7.7797 0.13896E-07 -7.8571 0.83673E+00 -0.0774 18 Mg(HSiO3)+ 0.32186E-11 -11.4923 0.26931E-11 -11.5697 0.83673E+00 -0.0774 19 NaHSiO3,aq 0.23496E-02 -2.6290 0.23496E-02 -2.6290 0.10000E+01 0.0000 20 AlO+ 0.66204E-16 -16.1791 0.55395E-16 -16.2565 0.83673E+00 -0.0774 22 HAlO2,aq 0.14854E-09 -9.8282 0.14854E-09 -9.8282 0.10000E+01 0.0000 23 AlO2- 0.53109E-05 -5.2748 0.44273E-05 -5.3539 0.83362E+00 -0.0790 24 CH4,aq 0.17016E-04 -4.7691 0.16957E-04 -4.7707 0.99654E+00 -0.0015 25 C2H6,aq 0.42585E-14 -14.3707 0.42437E-14 -14.3723 0.99654E+00 -0.0015 29 CO,aq 0.12712E-16 -16.8958 0.12712E-16 -16.8958 0.10000E+01 0.0000 30 CO2,aq 0.43839E-10 -10.3581 0.43687E-10 -10.3596 0.99654E+00 -0.0015 31 CO3-2 0.62498E-06 -6.2041 0.32377E-06 -6.4898 0.51805E+00 -0.2856 32 CaCO3,aq 0.28310E-09 -9.5481 0.28310E-09 -9.5481 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.58564E-12 -12.2324 0.49002E-12 -12.3098 0.83673E+00 -0.0774 34 CaCl+ 0.21269E-10 -10.6722 0.17797E-10 -10.7497 0.83673E+00 -0.0774 35 CaCl2,aq 0.66679E-15 -15.1760 0.66679E-15 -15.1760 0.10000E+01 0.0000 36 CaOH+ 0.79975E-07 -7.0970 0.66918E-07 -7.1745 0.83673E+00 -0.0774 37 CaSO4,aq 0.10226E-16 -16.9903 0.10226E-16 -16.9903 0.10000E+01 0.0000 38 HCl,aq 0.21462E-14 -14.6683 0.21462E-14 -14.6683 0.10000E+01 0.0000 43 FeCl+ 0.89386E-17 -17.0487 0.74792E-17 -17.1261 0.83673E+00 -0.0774 46 FeO,aq 0.21113E-09 -9.6755 0.21113E-09 -9.6755 0.10000E+01 0.0000 47 FeOH+ 0.15695E-10 -10.8042 0.13132E-10 -10.8817 0.83673E+00 -0.0774 48 HFeO2- 0.35616E-07 -7.4484 0.29744E-07 -7.5266 0.83513E+00 -0.0782 49 FeO+ 0.10999E-16 -16.9586 0.92036E-17 -17.0360 0.83673E+00 -0.0774 51 FeO2- 0.40884E-09 -9.3885 0.34143E-09 -9.4667 0.83513E+00 -0.0782 52 HFeO2,aq 0.32251E-11 -11.4915 0.32251E-11 -11.4915 0.10000E+01 0.0000 53 H2,aq 0.11623E-04 -4.9347 0.11583E-04 -4.9362 0.99654E+00 -0.0015 54 KCl,aq 0.37466E-09 -9.4264 0.37466E-09 -9.4264 0.10000E+01 0.0000 56 KOH,aq 0.75375E-06 -6.1228 0.75375E-06 -6.1228 0.10000E+01 0.0000 57 KSO4- 0.11248E-14 -14.9489 0.93937E-15 -15.0272 0.83513E+00 -0.0782 58 MgCO3,aq 0.11050E-13 -13.9566 0.11050E-13 -13.9566 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.93189E-16 -16.0306 0.77975E-16 -16.1080 0.83673E+00 -0.0774 60 MgCl+ 0.30020E-14 -14.5226 0.25119E-14 -14.6000 0.83673E+00 -0.0774 61 MgOH+ 0.68916E-10 -10.1617 0.57664E-10 -10.2391 0.83673E+00 -0.0774 63 MnO,aq 0.18035E-08 -8.7439 0.18035E-08 -8.7439 0.10000E+01 0.0000 64 MnOH+ 0.46740E-09 -9.3303 0.39109E-09 -9.4077 0.83673E+00 -0.0774 65 MnO2-2 0.20946E-10 -10.6789 0.10851E-10 -10.9645 0.51805E+00 -0.2856 66 HMnO2- 0.21141E-09 -9.6749 0.17656E-09 -9.7531 0.83513E+00 -0.0782 69 MnCl+ 0.11148E-13 -13.9528 0.93281E-14 -14.0302 0.83673E+00 -0.0774 71 NaCl,aq 0.86769E-06 -6.0616 0.86769E-06 -6.0616 0.10000E+01 0.0000 72 NaOH,aq 0.96047E-04 -4.0175 0.96047E-04 -4.0175 0.10000E+01 0.0000 74 OH- 0.93322E-02 -2.0300 0.77796E-02 -2.1090 0.83362E+00 -0.0790 79 HPO3-2 0.16366E-14 -14.7861 0.84783E-15 -15.0717 0.51805E+00 -0.2856 81 H2PO3- 0.15119E-18 -18.8205 0.12627E-18 -18.8987 0.83513E+00 -0.0782 82 H3PO4,aq 0.90608E-18 -18.0428 0.90608E-18 -18.0428 0.10000E+01 0.0000 83 H2PO4- 0.38495E-10 -10.4146 0.32179E-10 -10.4924 0.83593E+00 -0.0778 84 PO4-3 0.10641E-08 -8.9730 0.25803E-09 -9.5883 0.24249E+00 -0.6153 88 HP2O7-3 0.94458E-18 -18.0248 0.21830E-18 -18.6610 0.23110E+00 -0.6362 89 P2O7-4 0.91175E-17 -17.0401 0.70219E-18 -18.1535 0.77015E-01 -1.1134 90 H2S,aq 0.67450E-08 -8.1710 0.67217E-08 -8.1725 0.99654E+00 -0.0015 91 S2-2 0.31666E-14 -14.4994 0.16405E-14 -14.7850 0.51805E+00 -0.2856 97 SO3-2 0.13227E-17 -17.8785 0.69513E-18 -18.1579 0.52555E+00 -0.2794 99 HSO4- 0.39465E-19 -19.4038 0.33054E-19 -19.4808 0.83755E+00 -0.0770 Charge balance for all species = 0.7178E-10 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.8839411E-10 -.2228112E-01 -.2241898E+02 0.0000 2 H2O 0.1000000E+01 0.5550489E+02 0.9981984E+06 0.0000 3 Cl- 0.1888352E-03 0.1897033E-03 0.6713855E+01 6.3270 4 SO4-- 0.8895623E-12 -.1992150E-04 -.1910363E+01 7.9229 5 HCO3- 0.3291570E-06 0.1797019E-04 0.1094584E+01 3.5690 6 HS- 0.3505983E-04 0.5498807E-04 0.1815403E+01 5.5958 7 Al+++ 0.9728038E-29 0.5311083E-05 0.1430518E+00 0.7390 8 H4SiO4 0.6959668E-03 0.1352309E-01 0.1297517E+04 -3.1574 9 Ca++ 0.1353157E-06 0.2322029E-06 0.9290043E-02 13.1018 10 Mg++ 0.2116929E-10 0.9331778E-10 0.2264797E-05 9.2942 11 Fe++ 0.5834553E-13 0.3625516E-07 0.2021221E-02 6.7350 12 K+ 0.1566931E-03 0.1574473E-03 0.6145797E+01 6.2467 13 Na+ 0.1988360E-01 0.2233011E-01 0.5124721E+03 8.3494 14 Mn++ 0.1868886E-10 0.2521926E-08 0.1383086E-03 9.2409 15 HPO4-- 0.4523608E-07 0.4633864E-07 0.4439803E-02 12.6292 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.4470796E+02 -.1620541E-01 -.4469176E+02 0.0000000E+00 2 H2O 0.2166265E+02 0.4036958E+02 -.1870692E+02 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.7485168E-01 -.1448922E-04 0.7486617E-01 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.7482618E-01 0.3999369E-04 -.7486617E-01 0.0000000E+00 7 Al+++ 0.8803999E+01 0.3862834E-05 0.8803995E+01 0.0000000E+00 8 H4SiO4 0.2811450E+02 0.9835554E-02 0.2810467E+02 0.0000000E+00 9 Ca++ 0.3105398E+01 0.1688848E-06 0.3105398E+01 0.0000000E+00 10 Mg++ 0.2142856E+01 0.6787149E-10 0.2142856E+01 0.0000000E+00 11 Fe++ 0.1925122E+01 0.2636895E-07 0.1925122E+01 0.0000000E+00 12 K+ 0.5732482E+00 0.1145139E-03 0.5731337E+00 0.0000000E+00 13 Na+ 0.3389317E+01 0.1624104E-01 0.3373076E+01 0.0000000E+00 14 Mn++ 0.4681419E-01 0.1834236E-08 0.4681419E-01 0.0000000E+00 15 HPO4-- 0.1597745E-01 0.3370282E-07 0.1597742E-01 0.0000000E+00 Chg. balance for solid moles: 0.5732E-14 Mass of aqueous solution: 0.728583E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 2699.9990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 3.370 0.528 883.7 2.946 29.96 339.2 andradite 0.2995 -0.524 152.2 2.182 5.159 39.54 grossular 0.7252E-01 -1.140 32.67 1.514 1.107 9.089 apatite-OH 0.5326E-02 -2.274 2.675 0.427 0.9070E-01 0.8501 clinochlore 0.3842 -0.415 213.5 2.329 7.239 81.22 daphnite 0.1112 -0.954 79.35 1.900 2.690 24.05 chlorite-Mn 0.9363E-02 -2.029 6.638 0.822 0.2250 2.115 diopside 0.1376 -0.861 29.80 1.474 1.010 9.107 hedenbergite 0.3568E-01 -1.448 8.853 0.947 0.3001 2.425 microcline 0.5026 -0.299 139.9 2.146 4.743 54.65 stilbite 1.743 0.241 1228. 3.089 41.64 572.9 stilpnomelane-Fe 0.1411 -0.851 152.1 2.182 5.156 52.53 tr.625ac.25prg.125 0.2331E-01 -1.633 19.92 1.299 0.6754 6.411 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8051E+00 0.8051E+00 1.0000 -0.094 grossular 0.1949E+00 0.1949E+00 1.0000 -0.710 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.7611E+00 0.7611E+00 1.0000 -0.119 daphnite 0.2203E+00 0.2203E+00 1.0000 -0.657 chlorite-Mn 0.1855E-01 0.1855E-01 1.0000 -1.732 diopside 0.7941E+00 0.7941E+00 1.0000 -0.100 hedenbergite 0.2059E+00 0.2059E+00 1.0000 -0.686 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 tr.625ac.25prg.125 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 2949.572575 g Volume = 1194.107382 cm3 Porosity: -10.4633% V(tot) - V(min): -.11311E+03 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 2699.9990000 g log = 3.4314 Original solution: 1000.0103000 g Original solution / Rock added: 0.37 (Water/Rock Ratio), log = -0.4314 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0607 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9624E+00 0.9854 0.1006E+01 0.1021E+01 CO2,gas 0.4377E-08 1.0068 0.4674E-08 0.4642E-08 CH4,gas 0.2324E-01 1.0124 0.2496E-01 0.2465E-01 H2,gas 0.1433E-01 1.0006 0.1521E-01 0.1520E-01 H2S,gas 0.1749E-06 0.9959 0.1848E-06 0.1855E-06 S2,gas 0.5224E-29 1.0000 0.5542E-29 0.5542E-29 CO,gas 0.1786E-13 1.0000 0.1894E-13 0.1894E-13 SO3,gas 0.9080E-48 1.0000 0.9631E-48 0.9631E-48 SO2,gas 0.5372E-27 1.0000 0.5698E-27 0.5698E-27 HCl,gas 0.3570E-17 1.0000 0.3787E-17 0.3787E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 16 albite -0.38 -0.38 0.00 0.000 -0.94784E-12 22 andradite 39.01 39.01 0.00 0.000 0.12132E-10 23 grossular 32.73 32.73 0.00 0.000 -0.24265E-10 32 apatite-OH -18.15 -18.15 0.00 0.000 0.00000E+00 46 clinochlore 39.07 39.07 0.00 0.000 -0.12132E-10 47 daphnite 28.97 28.97 0.00 0.000 -0.54595E-10 48 chlorite-Mn 46.87 46.87 0.00 0.000 -0.24265E-10 67 diopside 16.18 16.18 0.00 0.000 -0.60662E-11 68 hedenbergite 14.21 14.21 0.00 0.000 -0.30331E-11 116 microcline -2.49 -2.49 0.00 0.000 0.15165E-11 163 stilbite -7.52 -7.52 0.00 0.000 0.15165E-10 164 stilpnomelane-Fe 13.02 13.02 0.00 0.000 -0.27298E-10 245 tr.625ac.25prg.125 45.16 45.16 0.00 0.000 -0.36397E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -16.69 -10.03 -3.343 0.17125E+05 -8.330 3 CH4,gas 4.54 1.24 -3.30 -0.825 0.56376E+04 -1.603 4 H2,gas 8.00 4.48 -3.52 -2.010 0.60050E+04 -1.818 5 H2S,gas -6.23 -14.66 -8.43 -4.216 0.14398E+05 -6.733 6 S2,gas -7.34 -38.29 -30.96 -4.762 0.52855E+05 -29.256 7 CO,gas 3.21 -12.21 -15.42 -4.745 0.26332E+05 -13.723 8 SO3,gas 17.12 -32.59 -49.72 -12.429 0.84888E+05 -48.016 9 SO2,gas 0.83 -28.11 -28.94 -7.718 0.49420E+05 -27.244 10 HCl,gas 5.19 -13.93 -19.12 -9.560 0.32648E+05 -17.422 11 acmite 7.71 6.53 -1.18 -0.123 0.20176E+04 15 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 19 spessartine 24.46 19.73 -4.73 -0.236 0.80744E+04 20 analcite 3.32 2.77 -0.55 -0.061 0.93624E+03 26 annite 20.12 17.72 -2.40 -0.134 0.41064E+04 27 phlogopite 27.06 25.40 -1.67 -0.093 0.28489E+04 29 anorthite 12.71 8.27 -4.45 -0.342 0.75902E+04 35 aragonite 0.97 -3.59 -4.55 -1.518 0.77760E+04 36 brucite 12.57 9.29 -3.27 -0.655 0.55909E+04 37 calcite 0.81 -3.59 -4.40 -1.466 0.75118E+04 38 carnegieite-low 9.02 5.93 -3.09 -0.442 0.52801E+04 39 carnegieite-high 10.09 5.93 -4.16 -0.595 0.71071E+04 40 carpholite-Mg 8.58 4.46 -4.12 -0.275 0.70428E+04 41 carpholite-Fe 6.71 1.90 -4.81 -0.321 0.82206E+04 42 celadonite 5.34 3.65 -1.69 -0.099 0.28879E+04 43 celadonite-Fe 3.88 1.09 -2.79 -0.164 0.47561E+04 44 chrysotile 23.89 21.57 -2.32 -0.194 0.39692E+04 49 chlorite-Al-free 47.17 43.14 -4.04 -0.168 0.68936E+04 51 chloritoid-Fe 9.17 5.06 -4.12 -0.275 0.70315E+04 52 chloritoid-Mn 11.40 7.56 -3.84 -0.256 0.65560E+04 54 coesite -2.38 -3.16 -0.78 -0.260 0.13341E+04 61 cristobalite -2.56 -3.16 -0.60 -0.199 0.10195E+04 63 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71234E+04 65 diaspore 2.87 0.74 -2.13 -0.356 0.36449E+04 66 diamond -3.10 -7.72 -4.62 -1.320 0.78908E+04 71 enstatite 17.26 12.27 -4.99 -0.499 0.85225E+04 73 clinoenstatite 17.17 12.27 -4.89 -0.489 0.83541E+04 75 epidote 24.67 22.70 -1.97 -0.095 0.33585E+04 76 clinozoisite 22.81 18.95 -3.86 -0.175 0.65868E+04 77 epidote-Fe 29.84 26.46 -3.38 -0.176 0.57768E+04 78 fayalite 14.05 10.31 -3.73 -0.533 0.63743E+04 79 ferrosilite 11.15 7.16 -3.99 -0.399 0.68202E+04 83 gibbsite 4.08 0.74 -3.34 -0.477 0.57035E+04 84 glaucophane 22.97 20.80 -2.17 -0.059 0.37133E+04 85 glaucophane-Fe 17.28 13.12 -4.15 -0.112 0.70919E+04 86 graphite -3.55 -7.72 -4.18 -1.194 0.71331E+04 87 greenalite 16.14 13.89 -2.25 -0.187 0.38408E+04 90 hematite 12.57 8.99 -3.58 -0.434 0.61112E+04 91 heulandite -5.83 -7.52 -1.69 -0.077 0.28938E+04 95 jadeite 4.22 2.77 -1.44 -0.144 0.24617E+04 97 kalsilite 7.58 3.83 -3.76 -0.537 0.64125E+04 98 kaolinite -1.33 -4.84 -3.50 -0.319 0.59831E+04 101 laumontite 2.88 1.95 -0.93 -0.062 0.15935E+04 102 lawsonite 9.62 8.27 -1.35 -0.090 0.23069E+04 103 leucite 4.12 0.67 -3.45 -0.345 0.58873E+04 105 lizardite 23.24 21.57 -1.68 -0.140 0.28618E+04 107 magnetite 20.09 15.72 -4.37 -0.356 0.74536E+04 108 minnesotaite 10.39 7.58 -2.81 -0.165 0.48028E+04 112 manganosite 14.06 9.24 -4.82 -1.204 0.82252E+04 120 muscovite 2.58 -1.01 -3.59 -0.211 0.61314E+04 121 paragonite 4.24 1.09 -3.15 -0.185 0.53705E+04 122 nepheline 8.34 5.93 -2.41 -0.344 0.41124E+04 128 periclase-Fe 11.63 6.73 -4.89 -1.223 0.83523E+04 134 phlogopite-Na 29.65 27.50 -2.15 -0.119 0.36677E+04 136 prehnite 19.37 18.21 -1.16 -0.068 0.19849E+04 137 prehnite-Fe 22.50 21.96 -0.53 -0.032 0.91157E+03 138 pumpellyite-Fe 46.27 43.89 -2.38 -0.053 0.40580E+04 139 pumpellyite-Mg 48.99 46.45 -2.54 -0.057 0.43418E+04 143 pyrrhotite -4.26 -7.93 -3.67 -1.222 0.62618E+04 144 pyrrhotiteFe0.875 -6.02 -9.33 -3.31 -1.217 0.56490E+04 145 pyroxmangite 7.40 6.08 -1.32 -0.263 0.22456E+04 146 pyrophyllite -6.18 -11.15 -4.98 -0.311 0.84961E+04 147 quartz -2.99 -3.16 -0.17 -0.056 0.28681E+03 152 rhodonite 7.45 6.08 -1.36 -0.272 0.23259E+04 153 sanidine -1.28 -2.49 -1.21 -0.093 0.20677E+04 165 stilpnomelane-Mg 27.44 25.81 -1.63 -0.049 0.27803E+04 171 talc 16.49 15.25 -1.24 -0.073 0.21140E+04 174 tephroite 18.09 15.32 -2.76 -0.394 0.47150E+04 178 tridymite -2.63 -3.16 -0.53 -0.177 0.90679E+03 179 tremolite 47.87 47.42 -0.45 -0.012 0.77495E+03 180 ferroactinolite 38.45 34.62 -3.83 -0.104 0.65449E+04 181 troilite-low -4.41 -7.93 -3.52 -1.172 0.60046E+04 183 vesuvianite 223.47 218.82 -4.65 -0.036 0.79434E+04 187 wairakite 3.95 1.95 -2.00 -0.118 0.34154E+04 188 walstromite 11.51 9.94 -1.56 -0.313 0.26719E+04 189 wollastonite 10.46 9.94 -0.52 -0.103 0.88229E+03 190 pseudo-wollastonite 11.00 9.94 -1.06 -0.211 0.18021E+04 191 zoisite 22.85 18.95 -3.90 -0.177 0.66608E+04 192 akaganeite 7.75 4.49 -3.26 -0.705 0.55681E+04 199 chalcedony -2.80 -3.16 -0.35 -0.118 0.60611E+03 201 montmorillonite-Ca -2.29 -6.17 -3.88 -0.240 0.66180E+04 202 montmorillonite-K -2.24 -6.27 -4.03 -0.247 0.68816E+04 203 montmorillonite-Mg -2.48 -6.79 -4.32 -0.267 0.73678E+04 204 montmorillonite-Na -2.04 -5.57 -3.54 -0.216 0.60365E+04 205 nontronite-Ca 3.21 -0.19 -3.41 -0.221 0.58215E+04 206 nontronite-H 2.53 -2.36 -4.89 -0.328 0.83485E+04 207 nontronite-K 3.34 -0.30 -3.64 -0.233 0.62083E+04 208 nontronite-Mg 3.07 -0.82 -3.90 -0.253 0.66554E+04 209 nontronite-Na 3.52 0.40 -3.12 -0.200 0.53292E+04 224 tobermorite 9.82 7.76 -2.07 -0.564 0.35287E+04 230 alabandite -0.98 -5.42 -4.44 -1.481 0.75876E+04 233 boehmite 4.41 0.74 -3.67 -0.611 0.62619E+04 235 ferrous-oxide 9.81 6.73 -3.08 -0.769 0.52532E+04 240 silica-amorphous -2.09 -3.16 -1.07 -0.355 0.18203E+04 242 an20ab80 2.02 1.35 -0.67 -0.052 0.11472E+04 243 an25ab75 2.65 1.78 -0.87 -0.067 0.14810E+04 244 an30ab70 3.28 2.21 -1.07 -0.082 0.18244E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 100.0000000 g Current total amount of reactant added: 2699.9990000 g New total amount of reactant added: 2799.9990000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.5221E-10 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 11 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 2799.9990000 Water: Moles liquid = 0.3981E+02 kg liquid = 0.7173E+00 Moles total = 0.2041E+02 kg total = 0.3677E+00 Activity = 1.0000 Stoichiometric ionic strength = .1136269E-01 Osmotic coef. = 0.9690 True ionic strength = .2004319E-01 Chg. balance for total moles = 0.5221E-10 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.88402E-10 -10.0535 0.74274E-10 -10.1292 0.84019E+00 -0.0756 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.19148E-03 -3.7179 0.15991E-03 -3.7961 0.83513E+00 -0.0782 4 SO4-- 0.90197E-12 -12.0448 0.46825E-12 -12.3295 0.51914E+00 -0.2847 5 HCO3- 0.33375E-06 -6.4766 0.27913E-06 -6.5542 0.83635E+00 -0.0776 6 HS- 0.35551E-04 -4.4492 0.29694E-04 -4.5273 0.83525E+00 -0.0782 7 Al+++ 0.97308E-29 -29.0119 0.22465E-29 -29.6485 0.23086E+00 -0.6367 8 H4SiO4 0.69597E-03 -3.1574 0.69597E-03 -3.1574 0.10000E+01 0.0000 9 Ca++ 0.13534E-06 -6.8686 0.69744E-07 -7.1565 0.51532E+00 -0.2879 10 Mg++ 0.21173E-10 -10.6742 0.10861E-10 -10.9641 0.51297E+00 -0.2899 11 Fe++ 0.58356E-13 -13.2339 0.29967E-13 -13.5233 0.51353E+00 -0.2894 12 K+ 0.15671E-03 -3.8049 0.13109E-03 -3.8824 0.83655E+00 -0.0775 13 Na+ 0.19885E-01 -1.7015 0.16604E-01 -1.7798 0.83498E+00 -0.0783 14 Mn++ 0.18694E-10 -10.7283 0.96081E-11 -11.0174 0.51395E+00 -0.2891 15 HPO4-- 0.45230E-07 -7.3446 0.23484E-07 -7.6292 0.51921E+00 -0.2847 16 HSiO3- 0.10477E-01 -1.9798 0.87494E-02 -2.0580 0.83513E+00 -0.0782 17 Ca(HSiO3)+ 0.16609E-07 -7.7797 0.13897E-07 -7.8571 0.83673E+00 -0.0774 18 Mg(HSiO3)+ 0.32189E-11 -11.4923 0.26933E-11 -11.5697 0.83673E+00 -0.0774 19 NaHSiO3,aq 0.23496E-02 -2.6290 0.23496E-02 -2.6290 0.10000E+01 0.0000 20 AlO+ 0.66209E-16 -16.1791 0.55399E-16 -16.2565 0.83673E+00 -0.0774 22 HAlO2,aq 0.14854E-09 -9.8282 0.14854E-09 -9.8282 0.10000E+01 0.0000 23 AlO2- 0.53105E-05 -5.2749 0.44270E-05 -5.3539 0.83362E+00 -0.0790 24 CH4,aq 0.17254E-04 -4.7631 0.17194E-04 -4.7646 0.99653E+00 -0.0015 25 C2H6,aq 0.43786E-14 -14.3587 0.43634E-14 -14.3602 0.99653E+00 -0.0015 29 CO,aq 0.12890E-16 -16.8897 0.12890E-16 -16.8897 0.10000E+01 0.0000 30 CO2,aq 0.44454E-10 -10.3521 0.44299E-10 -10.3536 0.99653E+00 -0.0015 31 CO3-2 0.63366E-06 -6.1981 0.32826E-06 -6.4838 0.51804E+00 -0.2856 32 CaCO3,aq 0.28707E-09 -9.5420 0.28707E-09 -9.5420 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.59390E-12 -12.2263 0.49693E-12 -12.3037 0.83673E+00 -0.0774 34 CaCl+ 0.21570E-10 -10.6661 0.18049E-10 -10.7436 0.83673E+00 -0.0774 35 CaCl2,aq 0.68569E-15 -15.1639 0.68569E-15 -15.1639 0.10000E+01 0.0000 36 CaOH+ 0.79982E-07 -7.0970 0.66923E-07 -7.1744 0.83673E+00 -0.0774 37 CaSO4,aq 0.10370E-16 -16.9842 0.10370E-16 -16.9842 0.10000E+01 0.0000 38 HCl,aq 0.21764E-14 -14.6623 0.21764E-14 -14.6623 0.10000E+01 0.0000 43 FeCl+ 0.90651E-17 -17.0426 0.75851E-17 -17.1200 0.83673E+00 -0.0774 46 FeO,aq 0.21113E-09 -9.6755 0.21113E-09 -9.6755 0.10000E+01 0.0000 47 FeOH+ 0.15696E-10 -10.8042 0.13133E-10 -10.8816 0.83673E+00 -0.0774 48 HFeO2- 0.35614E-07 -7.4484 0.29742E-07 -7.5266 0.83513E+00 -0.0782 49 FeO+ 0.11000E-16 -16.9586 0.92044E-17 -17.0360 0.83673E+00 -0.0774 51 FeO2- 0.40881E-09 -9.3885 0.34141E-09 -9.4667 0.83513E+00 -0.0782 52 HFeO2,aq 0.32251E-11 -11.4915 0.32251E-11 -11.4915 0.10000E+01 0.0000 53 H2,aq 0.11623E-04 -4.9347 0.11583E-04 -4.9362 0.99653E+00 -0.0015 54 KCl,aq 0.37994E-09 -9.4203 0.37994E-09 -9.4203 0.10000E+01 0.0000 56 KOH,aq 0.75375E-06 -6.1228 0.75375E-06 -6.1228 0.10000E+01 0.0000 57 KSO4- 0.11406E-14 -14.9429 0.95253E-15 -15.0211 0.83513E+00 -0.0782 58 MgCO3,aq 0.11205E-13 -13.9506 0.11205E-13 -13.9506 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.94504E-16 -16.0246 0.79074E-16 -16.1020 0.83673E+00 -0.0774 60 MgCl+ 0.30445E-14 -14.5165 0.25474E-14 -14.5939 0.83673E+00 -0.0774 61 MgOH+ 0.68922E-10 -10.1616 0.57669E-10 -10.2391 0.83673E+00 -0.0774 63 MnO,aq 0.18037E-08 -8.7438 0.18037E-08 -8.7438 0.10000E+01 0.0000 64 MnOH+ 0.46750E-09 -9.3302 0.39117E-09 -9.4076 0.83673E+00 -0.0774 65 MnO2-2 0.20946E-10 -10.6789 0.10851E-10 -10.9645 0.51804E+00 -0.2856 66 HMnO2- 0.21142E-09 -9.6748 0.17656E-09 -9.7531 0.83513E+00 -0.0782 69 MnCl+ 0.11307E-13 -13.9466 0.94612E-14 -14.0241 0.83673E+00 -0.0774 71 NaCl,aq 0.87991E-06 -6.0556 0.87991E-06 -6.0556 0.10000E+01 0.0000 72 NaOH,aq 0.96047E-04 -4.0175 0.96047E-04 -4.0175 0.10000E+01 0.0000 74 OH- 0.93316E-02 -2.0300 0.77790E-02 -2.1091 0.83362E+00 -0.0790 79 HPO3-2 0.16364E-14 -14.7861 0.84769E-15 -15.0718 0.51804E+00 -0.2856 81 H2PO3- 0.15118E-18 -18.8205 0.12626E-18 -18.8987 0.83513E+00 -0.0782 82 H3PO4,aq 0.90608E-18 -18.0428 0.90608E-18 -18.0428 0.10000E+01 0.0000 83 H2PO4- 0.38492E-10 -10.4146 0.32177E-10 -10.4925 0.83592E+00 -0.0778 84 PO4-3 0.10639E-08 -8.9731 0.25797E-09 -9.5884 0.24248E+00 -0.6153 88 HP2O7-3 0.94441E-18 -18.0248 0.21824E-18 -18.6611 0.23109E+00 -0.6362 89 P2O7-4 0.91155E-17 -17.0402 0.70197E-18 -18.1537 0.77008E-01 -1.1135 90 H2S,aq 0.68400E-08 -8.1649 0.68163E-08 -8.1665 0.99653E+00 -0.0015 91 S2-2 0.32560E-14 -14.4873 0.16867E-14 -14.7730 0.51804E+00 -0.2856 97 SO3-2 0.13411E-17 -17.8725 0.70481E-18 -18.1519 0.52554E+00 -0.2794 99 HSO4- 0.40018E-19 -19.3977 0.33517E-19 -19.4747 0.83755E+00 -0.0770 Charge balance for all species = 0.7278E-10 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.8840161E-10 -.2227969E-01 -.2241754E+02 0.0000 2 H2O 0.1000000E+01 0.5550489E+02 0.9981983E+06 0.0000 3 Cl- 0.1914790E-03 0.1923594E-03 0.6807856E+01 6.3330 4 SO4-- 0.9019724E-12 -.2015982E-04 -.1933217E+01 7.9288 5 HCO3- 0.3337469E-06 0.1822179E-04 0.1109909E+01 3.5750 6 HS- 0.3555071E-04 0.5571737E-04 0.1839480E+01 5.6018 7 Al+++ 0.9730818E-29 0.5310670E-05 0.1430406E+00 0.7390 8 H4SiO4 0.6959678E-03 0.1352233E-01 0.1297444E+04 -3.1574 9 Ca++ 0.1353402E-06 0.2322397E-06 0.9291516E-02 13.1018 10 Mg++ 0.2117312E-10 0.9332787E-10 0.2265041E-05 9.2942 11 Fe++ 0.5835613E-13 0.3625248E-07 0.2021071E-02 6.7350 12 K+ 0.1567065E-03 0.1574606E-03 0.6146318E+01 6.2467 13 Na+ 0.1988530E-01 0.2233182E-01 0.5125114E+03 8.3494 14 Mn++ 0.1869446E-10 0.2522246E-08 0.1383262E-03 9.2410 15 HPO4-- 0.4523000E-07 0.4633236E-07 0.4439200E-02 12.6291 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.4636381E+02 -.1598062E-01 -.4634783E+02 0.0000000E+00 2 H2O 0.2040911E+02 0.3981216E+02 -.1940305E+02 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.7762302E-01 -.1446010E-04 0.7763748E-01 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.7759752E-01 0.3996457E-04 -.7763748E-01 0.0000000E+00 7 Al+++ 0.9130073E+01 0.3809200E-05 0.9130069E+01 0.0000000E+00 8 H4SiO4 0.2915578E+02 0.9699206E-02 0.2914608E+02 0.0000000E+00 9 Ca++ 0.3220413E+01 0.1665793E-06 0.3220413E+01 0.0000000E+00 10 Mg++ 0.2222221E+01 0.6694156E-10 0.2222221E+01 0.0000000E+00 11 Fe++ 0.1996423E+01 0.2600293E-07 0.1996423E+01 0.0000000E+00 12 K+ 0.5944796E+00 0.1129423E-03 0.5943667E+00 0.0000000E+00 13 Na+ 0.3514841E+01 0.1601802E-01 0.3498823E+01 0.0000000E+00 14 Mn++ 0.4854805E-01 0.1809139E-08 0.4854805E-01 0.0000000E+00 15 HPO4-- 0.1656921E-01 0.3323296E-07 0.1656918E-01 0.0000000E+00 Chg. balance for solid moles: -.1374E-13 Mass of aqueous solution: 0.718523E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 2799.9990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 3.496 0.544 916.7 2.962 29.97 351.9 andradite 0.3105 -0.508 157.8 2.198 5.159 41.00 grossular 0.7520E-01 -1.124 33.87 1.530 1.107 9.425 apatite-OH 0.5523E-02 -2.258 2.774 0.443 0.9070E-01 0.8816 clinochlore 0.3983 -0.400 221.4 2.345 7.238 84.22 daphnite 0.1153 -0.938 82.28 1.915 2.690 24.93 chlorite-Mn 0.9710E-02 -2.013 6.884 0.838 0.2250 2.194 diopside 0.1430 -0.845 30.98 1.491 1.013 9.467 hedenbergite 0.3709E-01 -1.431 9.203 0.964 0.3009 2.521 microcline 0.5212 -0.283 145.1 2.162 4.743 56.67 stilbite 1.807 0.257 1274. 3.105 41.63 594.0 stilpnomelane-Fe 0.1463 -0.835 157.7 2.198 5.156 54.48 tr.625ac.25prg.125 0.2414E-01 -1.617 20.63 1.315 0.6745 6.641 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8051E+00 0.8051E+00 1.0000 -0.094 grossular 0.1949E+00 0.1949E+00 1.0000 -0.710 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.7611E+00 0.7611E+00 1.0000 -0.119 daphnite 0.2203E+00 0.2203E+00 1.0000 -0.657 chlorite-Mn 0.1855E-01 0.1855E-01 1.0000 -1.732 diopside 0.7941E+00 0.7941E+00 1.0000 -0.100 hedenbergite 0.2059E+00 0.2059E+00 1.0000 -0.686 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 tr.625ac.25prg.125 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 3058.823240 g Volume = 1238.310446 cm3 Porosity: -10.4648% V(tot) - V(min): -.11731E+03 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 2799.9990000 g log = 3.4472 Original solution: 1000.0103000 g Original solution / Rock added: 0.36 (Water/Rock Ratio), log = -0.4472 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0611 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9621E+00 0.9854 0.1006E+01 0.1021E+01 CO2,gas 0.4436E-08 1.0068 0.4740E-08 0.4707E-08 CH4,gas 0.2356E-01 1.0124 0.2531E-01 0.2500E-01 H2,gas 0.1432E-01 1.0006 0.1521E-01 0.1520E-01 H2S,gas 0.1773E-06 0.9959 0.1874E-06 0.1882E-06 S2,gas 0.5371E-29 1.0000 0.5699E-29 0.5699E-29 CO,gas 0.1810E-13 1.0000 0.1921E-13 0.1921E-13 SO3,gas 0.9205E-48 1.0000 0.9767E-48 0.9767E-48 SO2,gas 0.5446E-27 1.0000 0.5778E-27 0.5778E-27 HCl,gas 0.3619E-17 1.0000 0.3840E-17 0.3840E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 16 albite -0.38 -0.38 0.00 0.000 -0.94784E-12 22 andradite 39.01 39.01 0.00 0.000 -0.12132E-10 23 grossular 32.73 32.73 0.00 0.000 -0.12132E-10 32 apatite-OH -18.15 -18.15 0.00 0.000 0.00000E+00 46 clinochlore 39.07 39.07 0.00 0.000 -0.24265E-10 47 daphnite 28.97 28.97 0.00 0.000 0.18198E-10 48 chlorite-Mn 46.87 46.87 0.00 0.000 -0.24265E-10 67 diopside 16.18 16.18 0.00 0.000 0.00000E+00 68 hedenbergite 14.21 14.21 0.00 0.000 -0.30331E-11 116 microcline -2.49 -2.49 0.00 0.000 0.15165E-11 163 stilbite -7.52 -7.52 0.00 0.000 0.15165E-10 164 stilpnomelane-Fe 13.02 13.02 0.00 0.000 0.21232E-10 245 tr.625ac.25prg.125 45.16 45.16 0.00 0.000 -0.48529E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -16.68 -10.02 -3.341 0.17114E+05 -8.324 3 CH4,gas 4.54 1.25 -3.30 -0.824 0.56273E+04 -1.597 4 H2,gas 8.00 4.48 -3.52 -2.010 0.60050E+04 -1.818 5 H2S,gas -6.23 -14.66 -8.43 -4.213 0.14388E+05 -6.727 6 S2,gas -7.34 -38.28 -30.94 -4.760 0.52835E+05 -29.244 7 CO,gas 3.21 -12.20 -15.42 -4.743 0.26322E+05 -13.717 8 SO3,gas 17.12 -32.59 -49.71 -12.427 0.84877E+05 -48.010 9 SO2,gas 0.83 -28.11 -28.94 -7.717 0.49409E+05 -27.238 10 HCl,gas 5.19 -13.93 -19.11 -9.557 0.32638E+05 -17.416 11 acmite 7.71 6.53 -1.18 -0.123 0.20176E+04 15 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 19 spessartine 24.46 19.73 -4.73 -0.236 0.80741E+04 20 analcite 3.32 2.77 -0.55 -0.061 0.93624E+03 26 annite 20.12 17.72 -2.40 -0.134 0.41064E+04 27 phlogopite 27.06 25.40 -1.67 -0.093 0.28489E+04 29 anorthite 12.71 8.26 -4.45 -0.342 0.75903E+04 35 aragonite 0.97 -3.58 -4.55 -1.516 0.77657E+04 36 brucite 12.57 9.29 -3.27 -0.655 0.55909E+04 37 calcite 0.81 -3.58 -4.39 -1.464 0.75014E+04 38 carnegieite-low 9.02 5.93 -3.09 -0.442 0.52801E+04 39 carnegieite-high 10.09 5.93 -4.16 -0.595 0.71071E+04 40 carpholite-Mg 8.58 4.46 -4.12 -0.275 0.70429E+04 41 carpholite-Fe 6.71 1.90 -4.81 -0.321 0.82206E+04 42 celadonite 5.34 3.65 -1.69 -0.099 0.28879E+04 43 celadonite-Fe 3.88 1.09 -2.79 -0.164 0.47561E+04 44 chrysotile 23.89 21.57 -2.32 -0.194 0.39692E+04 49 chlorite-Al-free 47.17 43.14 -4.04 -0.168 0.68936E+04 51 chloritoid-Fe 9.17 5.06 -4.12 -0.275 0.70315E+04 52 chloritoid-Mn 11.40 7.56 -3.84 -0.256 0.65559E+04 54 coesite -2.38 -3.16 -0.78 -0.260 0.13341E+04 61 cristobalite -2.56 -3.16 -0.60 -0.199 0.10195E+04 63 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71234E+04 65 diaspore 2.87 0.74 -2.13 -0.356 0.36449E+04 66 diamond -3.10 -7.72 -4.62 -1.319 0.78805E+04 71 enstatite 17.26 12.27 -4.99 -0.499 0.85225E+04 73 clinoenstatite 17.17 12.27 -4.89 -0.489 0.83541E+04 75 epidote 24.67 22.70 -1.97 -0.095 0.33585E+04 76 clinozoisite 22.81 18.95 -3.86 -0.175 0.65868E+04 77 epidote-Fe 29.84 26.46 -3.38 -0.176 0.57768E+04 78 fayalite 14.05 10.31 -3.73 -0.533 0.63743E+04 79 ferrosilite 11.15 7.16 -3.99 -0.399 0.68202E+04 83 gibbsite 4.08 0.74 -3.34 -0.477 0.57035E+04 84 glaucophane 22.97 20.80 -2.17 -0.059 0.37133E+04 85 glaucophane-Fe 17.28 13.12 -4.15 -0.112 0.70919E+04 86 graphite -3.55 -7.72 -4.17 -1.192 0.71227E+04 87 greenalite 16.14 13.89 -2.25 -0.187 0.38408E+04 90 hematite 12.57 8.99 -3.58 -0.434 0.61112E+04 91 heulandite -5.83 -7.52 -1.69 -0.077 0.28938E+04 95 jadeite 4.22 2.77 -1.44 -0.144 0.24617E+04 97 kalsilite 7.58 3.83 -3.76 -0.537 0.64126E+04 98 kaolinite -1.33 -4.84 -3.50 -0.319 0.59831E+04 101 laumontite 2.88 1.95 -0.93 -0.062 0.15935E+04 102 lawsonite 9.62 8.26 -1.35 -0.090 0.23069E+04 103 leucite 4.12 0.67 -3.45 -0.345 0.58873E+04 105 lizardite 23.24 21.57 -1.68 -0.140 0.28618E+04 107 magnetite 20.09 15.72 -4.37 -0.356 0.74536E+04 108 minnesotaite 10.39 7.58 -2.81 -0.165 0.48028E+04 112 manganosite 14.06 9.24 -4.82 -1.204 0.82251E+04 120 muscovite 2.58 -1.01 -3.59 -0.211 0.61314E+04 121 paragonite 4.24 1.09 -3.15 -0.185 0.53705E+04 122 nepheline 8.34 5.93 -2.41 -0.344 0.41124E+04 128 periclase-Fe 11.63 6.73 -4.89 -1.223 0.83523E+04 134 phlogopite-Na 29.65 27.50 -2.15 -0.119 0.36677E+04 136 prehnite 19.37 18.21 -1.16 -0.068 0.19849E+04 137 prehnite-Fe 22.50 21.96 -0.53 -0.032 0.91157E+03 138 pumpellyite-Fe 46.27 43.89 -2.38 -0.053 0.40580E+04 139 pumpellyite-Mg 48.99 46.45 -2.54 -0.057 0.43418E+04 143 pyrrhotite -4.26 -7.92 -3.66 -1.220 0.62514E+04 144 pyrrhotiteFe0.875 -6.02 -9.32 -3.30 -1.215 0.56386E+04 145 pyroxmangite 7.40 6.08 -1.32 -0.263 0.22455E+04 146 pyrophyllite -6.18 -11.15 -4.98 -0.311 0.84961E+04 147 quartz -2.99 -3.16 -0.17 -0.056 0.28681E+03 152 rhodonite 7.45 6.08 -1.36 -0.272 0.23258E+04 153 sanidine -1.28 -2.49 -1.21 -0.093 0.20677E+04 165 stilpnomelane-Mg 27.44 25.81 -1.63 -0.049 0.27803E+04 171 talc 16.49 15.25 -1.24 -0.073 0.21140E+04 174 tephroite 18.09 15.32 -2.76 -0.394 0.47148E+04 178 tridymite -2.63 -3.16 -0.53 -0.177 0.90679E+03 179 tremolite 47.87 47.42 -0.45 -0.012 0.77495E+03 180 ferroactinolite 38.45 34.62 -3.83 -0.104 0.65449E+04 181 troilite-low -4.41 -7.92 -3.51 -1.170 0.59942E+04 183 vesuvianite 223.47 218.82 -4.65 -0.036 0.79434E+04 187 wairakite 3.95 1.95 -2.00 -0.118 0.34154E+04 188 walstromite 11.51 9.94 -1.56 -0.313 0.26719E+04 189 wollastonite 10.46 9.94 -0.52 -0.103 0.88229E+03 190 pseudo-wollastonite 11.00 9.94 -1.06 -0.211 0.18021E+04 191 zoisite 22.85 18.95 -3.90 -0.177 0.66608E+04 192 akaganeite 7.75 4.49 -3.26 -0.705 0.55681E+04 199 chalcedony -2.80 -3.16 -0.35 -0.118 0.60611E+03 201 montmorillonite-Ca -2.29 -6.17 -3.88 -0.240 0.66180E+04 202 montmorillonite-K -2.24 -6.27 -4.03 -0.247 0.68816E+04 203 montmorillonite-Mg -2.48 -6.79 -4.32 -0.267 0.73678E+04 204 montmorillonite-Na -2.04 -5.57 -3.54 -0.216 0.60365E+04 205 nontronite-Ca 3.21 -0.19 -3.41 -0.221 0.58215E+04 206 nontronite-H 2.53 -2.36 -4.89 -0.328 0.83485E+04 207 nontronite-K 3.34 -0.30 -3.64 -0.233 0.62083E+04 208 nontronite-Mg 3.07 -0.82 -3.90 -0.253 0.66554E+04 209 nontronite-Na 3.52 0.40 -3.12 -0.200 0.53292E+04 224 tobermorite 9.82 7.76 -2.07 -0.564 0.35287E+04 230 alabandite -0.98 -5.42 -4.44 -1.479 0.75772E+04 233 boehmite 4.41 0.74 -3.67 -0.611 0.62619E+04 235 ferrous-oxide 9.81 6.73 -3.08 -0.769 0.52532E+04 240 silica-amorphous -2.09 -3.16 -1.07 -0.355 0.18203E+04 242 an20ab80 2.02 1.35 -0.67 -0.052 0.11472E+04 243 an25ab75 2.65 1.78 -0.87 -0.067 0.14810E+04 244 an30ab70 3.28 2.21 -1.07 -0.082 0.18244E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 100.0000000 g Current total amount of reactant added: 2799.9990000 g New total amount of reactant added: 2899.9990000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.5220E-10 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 11 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 2899.9990000 Water: Moles liquid = 0.3926E+02 kg liquid = 0.7072E+00 Moles total = 0.1916E+02 kg total = 0.3451E+00 Activity = 1.0000 Stoichiometric ionic strength = .1136496E-01 Osmotic coef. = 0.9690 True ionic strength = .2004495E-01 Chg. balance for total moles = 0.5220E-10 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.88409E-10 -10.0535 0.74280E-10 -10.1291 0.84018E+00 -0.0756 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.19420E-03 -3.7118 0.16218E-03 -3.7900 0.83512E+00 -0.0782 4 SO4-- 0.91473E-12 -12.0387 0.47486E-12 -12.3234 0.51913E+00 -0.2847 5 HCO3- 0.33847E-06 -6.4705 0.28308E-06 -6.5481 0.83635E+00 -0.0776 6 HS- 0.36056E-04 -4.4430 0.30115E-04 -4.5212 0.83525E+00 -0.0782 7 Al+++ 0.97337E-29 -29.0117 0.22470E-29 -29.6484 0.23085E+00 -0.6367 8 H4SiO4 0.69597E-03 -3.1574 0.69597E-03 -3.1574 0.10000E+01 0.0000 9 Ca++ 0.13537E-06 -6.8685 0.69755E-07 -7.1564 0.51531E+00 -0.2879 10 Mg++ 0.21177E-10 -10.6741 0.10863E-10 -10.9641 0.51295E+00 -0.2899 11 Fe++ 0.58367E-13 -13.2338 0.29972E-13 -13.5233 0.51352E+00 -0.2894 12 K+ 0.15672E-03 -3.8049 0.13110E-03 -3.8824 0.83655E+00 -0.0775 13 Na+ 0.19887E-01 -1.7014 0.16605E-01 -1.7798 0.83497E+00 -0.0783 14 Mn++ 0.18700E-10 -10.7282 0.96107E-11 -11.0172 0.51394E+00 -0.2891 15 HPO4-- 0.45224E-07 -7.3446 0.23480E-07 -7.6293 0.51920E+00 -0.2847 16 HSiO3- 0.10476E-01 -1.9798 0.87487E-02 -2.0581 0.83512E+00 -0.0782 17 Ca(HSiO3)+ 0.16610E-07 -7.7796 0.13898E-07 -7.8570 0.83673E+00 -0.0774 18 Mg(HSiO3)+ 0.32191E-11 -11.4923 0.26935E-11 -11.5697 0.83673E+00 -0.0774 19 NaHSiO3,aq 0.23496E-02 -2.6290 0.23496E-02 -2.6290 0.10000E+01 0.0000 20 AlO+ 0.66215E-16 -16.1790 0.55404E-16 -16.2565 0.83673E+00 -0.0774 22 HAlO2,aq 0.14854E-09 -9.8282 0.14854E-09 -9.8282 0.10000E+01 0.0000 23 AlO2- 0.53101E-05 -5.2749 0.44266E-05 -5.3539 0.83361E+00 -0.0790 24 CH4,aq 0.17499E-04 -4.7570 0.17439E-04 -4.7585 0.99653E+00 -0.0015 25 C2H6,aq 0.45039E-14 -14.3464 0.44883E-14 -14.3479 0.99653E+00 -0.0015 29 CO,aq 0.13073E-16 -16.8836 0.13073E-16 -16.8836 0.10000E+01 0.0000 30 CO2,aq 0.45086E-10 -10.3460 0.44929E-10 -10.3475 0.99653E+00 -0.0015 31 CO3-2 0.64258E-06 -6.1921 0.33287E-06 -6.4777 0.51802E+00 -0.2857 32 CaCO3,aq 0.29115E-09 -9.5359 0.29115E-09 -9.5359 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.60239E-12 -12.2201 0.50404E-12 -12.2975 0.83673E+00 -0.0774 34 CaCl+ 0.21880E-10 -10.6599 0.18308E-10 -10.7374 0.83673E+00 -0.0774 35 CaCl2,aq 0.70541E-15 -15.1516 0.70541E-15 -15.1516 0.10000E+01 0.0000 36 CaOH+ 0.79988E-07 -7.0970 0.66928E-07 -7.1744 0.83673E+00 -0.0774 37 CaSO4,aq 0.10518E-16 -16.9780 0.10518E-16 -16.9780 0.10000E+01 0.0000 38 HCl,aq 0.22075E-14 -14.6561 0.22075E-14 -14.6561 0.10000E+01 0.0000 43 FeCl+ 0.91954E-17 -17.0364 0.76940E-17 -17.1138 0.83673E+00 -0.0774 46 FeO,aq 0.21113E-09 -9.6755 0.21113E-09 -9.6755 0.10000E+01 0.0000 47 FeOH+ 0.15698E-10 -10.8042 0.13135E-10 -10.8816 0.83673E+00 -0.0774 48 HFeO2- 0.35611E-07 -7.4484 0.29739E-07 -7.5267 0.83512E+00 -0.0782 49 FeO+ 0.11001E-16 -16.9586 0.92051E-17 -17.0360 0.83673E+00 -0.0774 51 FeO2- 0.40878E-09 -9.3885 0.34138E-09 -9.4668 0.83512E+00 -0.0782 52 HFeO2,aq 0.32251E-11 -11.4915 0.32251E-11 -11.4915 0.10000E+01 0.0000 53 H2,aq 0.11623E-04 -4.9347 0.11583E-04 -4.9362 0.99653E+00 -0.0015 54 KCl,aq 0.38536E-09 -9.4141 0.38536E-09 -9.4141 0.10000E+01 0.0000 56 KOH,aq 0.75375E-06 -6.1228 0.75375E-06 -6.1228 0.10000E+01 0.0000 57 KSO4- 0.11568E-14 -14.9367 0.96606E-15 -15.0150 0.83512E+00 -0.0782 58 MgCO3,aq 0.11365E-13 -13.9444 0.11365E-13 -13.9444 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.95856E-16 -16.0184 0.80205E-16 -16.0958 0.83673E+00 -0.0774 60 MgCl+ 0.30882E-14 -14.5103 0.25840E-14 -14.5877 0.83673E+00 -0.0774 61 MgOH+ 0.68927E-10 -10.1616 0.57673E-10 -10.2390 0.83673E+00 -0.0774 63 MnO,aq 0.18039E-08 -8.7438 0.18039E-08 -8.7438 0.10000E+01 0.0000 64 MnOH+ 0.46759E-09 -9.3301 0.39124E-09 -9.4076 0.83673E+00 -0.0774 65 MnO2-2 0.20945E-10 -10.6789 0.10850E-10 -10.9646 0.51802E+00 -0.2857 66 HMnO2- 0.21143E-09 -9.6748 0.17657E-09 -9.7531 0.83512E+00 -0.0782 69 MnCl+ 0.11471E-13 -13.9404 0.95981E-14 -14.0178 0.83673E+00 -0.0774 71 NaCl,aq 0.89247E-06 -6.0494 0.89247E-06 -6.0494 0.10000E+01 0.0000 72 NaOH,aq 0.96047E-04 -4.0175 0.96047E-04 -4.0175 0.10000E+01 0.0000 74 OH- 0.93308E-02 -2.0301 0.77783E-02 -2.1091 0.83361E+00 -0.0790 79 HPO3-2 0.16361E-14 -14.7862 0.84755E-15 -15.0718 0.51802E+00 -0.2857 81 H2PO3- 0.15117E-18 -18.8205 0.12625E-18 -18.8988 0.83512E+00 -0.0782 82 H3PO4,aq 0.90608E-18 -18.0428 0.90608E-18 -18.0428 0.10000E+01 0.0000 83 H2PO4- 0.38490E-10 -10.4147 0.32174E-10 -10.4925 0.83592E+00 -0.0778 84 PO4-3 0.10637E-08 -8.9732 0.25791E-09 -9.5885 0.24247E+00 -0.6153 88 HP2O7-3 0.94423E-18 -18.0249 0.21819E-18 -18.6612 0.23108E+00 -0.6362 89 P2O7-4 0.91134E-17 -17.0403 0.70174E-18 -18.1538 0.77001E-01 -1.1135 90 H2S,aq 0.69376E-08 -8.1588 0.69136E-08 -8.1603 0.99653E+00 -0.0015 91 S2-2 0.33492E-14 -14.4751 0.17349E-14 -14.7607 0.51802E+00 -0.2857 97 SO3-2 0.13601E-17 -17.8664 0.71476E-18 -18.1458 0.52552E+00 -0.2794 99 HSO4- 0.40587E-19 -19.3916 0.33993E-19 -19.4686 0.83754E+00 -0.0770 Charge balance for all species = 0.7384E-10 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.8840933E-10 -.2227821E-01 -.2241605E+02 0.0000 2 H2O 0.1000000E+01 0.5550489E+02 0.9981983E+06 0.0000 3 Cl- 0.1941980E-03 0.1950908E-03 0.6904527E+01 6.3391 4 SO4-- 0.9147324E-12 -.2040492E-04 -.1956721E+01 7.9348 5 HCO3- 0.3384662E-06 0.1848054E-04 0.1125670E+01 3.5810 6 HS- 0.3605552E-04 0.5646738E-04 0.1864242E+01 5.6079 7 Al+++ 0.9733682E-29 0.5310246E-05 0.1430292E+00 0.7390 8 H4SiO4 0.6959687E-03 0.1352156E-01 0.1297370E+04 -3.1574 9 Ca++ 0.1353653E-06 0.2322776E-06 0.9293032E-02 13.1018 10 Mg++ 0.2117706E-10 0.9333824E-10 0.2265293E-05 9.2942 11 Fe++ 0.5836704E-13 0.3624973E-07 0.2020918E-02 6.7350 12 K+ 0.1567202E-03 0.1574743E-03 0.6146853E+01 6.2467 13 Na+ 0.1988704E-01 0.2233358E-01 0.5125517E+03 8.3494 14 Mn++ 0.1870000E-10 0.2522547E-08 0.1383427E-03 9.2410 15 HPO4-- 0.4522374E-07 0.4632590E-07 0.4438581E-02 12.6290 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.4801967E+02 -.1575583E-01 -.4800391E+02 0.0000000E+00 2 H2O 0.1915557E+02 0.3925475E+02 -.2009917E+02 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.8039436E-01 -.1443098E-04 0.8040879E-01 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.8036886E-01 0.3993545E-04 -.8040879E-01 0.0000000E+00 7 Al+++ 0.9456147E+01 0.3755568E-05 0.9456144E+01 0.0000000E+00 8 H4SiO4 0.3019706E+02 0.9562856E-02 0.3018750E+02 0.0000000E+00 9 Ca++ 0.3335427E+01 0.1642738E-06 0.3335427E+01 0.0000000E+00 10 Mg++ 0.2301587E+01 0.6601164E-10 0.2301587E+01 0.0000000E+00 11 Fe++ 0.2067724E+01 0.2563691E-07 0.2067724E+01 0.0000000E+00 12 K+ 0.6157110E+00 0.1113706E-03 0.6155997E+00 0.0000000E+00 13 Na+ 0.3640365E+01 0.1579499E-01 0.3624570E+01 0.0000000E+00 14 Mn++ 0.5028191E-01 0.1784022E-08 0.5028191E-01 0.0000000E+00 15 HPO4-- 0.1716097E-01 0.3276308E-07 0.1716093E-01 0.0000000E+00 Chg. balance for solid moles: -.5135E-15 Mass of aqueous solution: 0.708463E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 2899.9990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 3.621 0.559 949.6 2.978 29.97 364.5 andradite 0.3216 -0.493 163.4 2.213 5.159 42.47 grossular 0.7789E-01 -1.109 35.08 1.545 1.107 9.762 apatite-OH 0.5720E-02 -2.243 2.873 0.458 0.9070E-01 0.9131 clinochlore 0.4125 -0.385 229.3 2.360 7.238 87.22 daphnite 0.1194 -0.923 85.21 1.930 2.690 25.82 chlorite-Mn 0.1006E-01 -1.998 7.130 0.853 0.2250 2.272 diopside 0.1485 -0.828 32.15 1.507 1.015 9.827 hedenbergite 0.3850E-01 -1.414 9.553 0.980 0.3015 2.616 microcline 0.5398 -0.268 150.3 2.177 4.743 58.69 stilbite 1.871 0.272 1319. 3.120 41.63 615.1 stilpnomelane-Fe 0.1515 -0.820 163.3 2.213 5.156 56.42 tr.625ac.25prg.125 0.2497E-01 -1.603 21.35 1.329 0.6738 6.870 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8051E+00 0.8051E+00 1.0000 -0.094 grossular 0.1949E+00 0.1949E+00 1.0000 -0.710 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.7611E+00 0.7611E+00 1.0000 -0.119 daphnite 0.2203E+00 0.2203E+00 1.0000 -0.657 chlorite-Mn 0.1855E-01 0.1855E-01 1.0000 -1.732 diopside 0.7941E+00 0.7941E+00 1.0000 -0.100 hedenbergite 0.2059E+00 0.2059E+00 1.0000 -0.686 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 tr.625ac.25prg.125 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 3168.073904 g Volume = 1282.513511 cm3 Porosity: -10.4663% V(tot) - V(min): -.12151E+03 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 2899.9990000 g log = 3.4624 Original solution: 1000.0103000 g Original solution / Rock added: 0.34 (Water/Rock Ratio), log = -0.4624 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0614 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9618E+00 0.9854 0.1006E+01 0.1021E+01 CO2,gas 0.4498E-08 1.0068 0.4807E-08 0.4774E-08 CH4,gas 0.2389E-01 1.0124 0.2567E-01 0.2535E-01 H2,gas 0.1432E-01 1.0006 0.1521E-01 0.1520E-01 H2S,gas 0.1798E-06 0.9959 0.1900E-06 0.1908E-06 S2,gas 0.5523E-29 1.0000 0.5863E-29 0.5863E-29 CO,gas 0.1835E-13 1.0000 0.1948E-13 0.1948E-13 SO3,gas 0.9333E-48 1.0000 0.9907E-48 0.9907E-48 SO2,gas 0.5522E-27 1.0000 0.5861E-27 0.5861E-27 HCl,gas 0.3670E-17 1.0000 0.3895E-17 0.3895E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 16 albite -0.38 -0.38 0.00 0.000 -0.13080E-10 22 andradite 39.01 39.01 0.00 0.000 0.00000E+00 23 grossular 32.73 32.73 0.00 0.000 0.12132E-10 32 apatite-OH -18.15 -18.15 0.00 0.000 -0.60662E-11 46 clinochlore 39.07 39.07 0.00 0.000 0.12132E-10 47 daphnite 28.97 28.97 0.00 0.000 -0.66728E-10 48 chlorite-Mn 46.87 46.87 0.00 0.000 0.00000E+00 67 diopside 16.18 16.18 0.00 0.000 -0.60662E-11 68 hedenbergite 14.21 14.21 0.00 0.000 -0.60662E-11 116 microcline -2.49 -2.49 0.00 0.000 -0.10616E-10 163 stilbite -7.52 -7.52 0.00 0.000 -0.90992E-11 164 stilpnomelane-Fe 13.02 13.02 0.00 0.000 -0.27298E-10 245 tr.625ac.25prg.125 45.16 45.16 0.00 0.000 -0.24265E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -16.68 -10.02 -3.339 0.17104E+05 -8.318 3 CH4,gas 4.54 1.25 -3.29 -0.822 0.56169E+04 -1.591 4 H2,gas 8.00 4.48 -3.52 -2.010 0.60051E+04 -1.818 5 H2S,gas -6.23 -14.65 -8.42 -4.210 0.14377E+05 -6.721 6 S2,gas -7.34 -38.27 -30.93 -4.759 0.52814E+05 -29.232 7 CO,gas 3.21 -12.19 -15.41 -4.741 0.26311E+05 -13.710 8 SO3,gas 17.12 -32.58 -49.70 -12.426 0.84867E+05 -48.004 9 SO2,gas 0.83 -28.10 -28.93 -7.715 0.49399E+05 -27.232 10 HCl,gas 5.19 -13.92 -19.11 -9.554 0.32627E+05 -17.409 11 acmite 7.71 6.53 -1.18 -0.123 0.20176E+04 15 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 19 spessartine 24.46 19.73 -4.73 -0.236 0.80739E+04 20 analcite 3.32 2.77 -0.55 -0.061 0.93624E+03 26 annite 20.12 17.72 -2.40 -0.134 0.41064E+04 27 phlogopite 27.06 25.40 -1.67 -0.093 0.28489E+04 29 anorthite 12.71 8.26 -4.45 -0.342 0.75903E+04 35 aragonite 0.97 -3.58 -4.54 -1.514 0.77552E+04 36 brucite 12.57 9.29 -3.27 -0.655 0.55909E+04 37 calcite 0.81 -3.58 -4.39 -1.462 0.74910E+04 38 carnegieite-low 9.02 5.93 -3.09 -0.442 0.52801E+04 39 carnegieite-high 10.09 5.93 -4.16 -0.595 0.71071E+04 40 carpholite-Mg 8.58 4.46 -4.12 -0.275 0.70429E+04 41 carpholite-Fe 6.71 1.90 -4.81 -0.321 0.82206E+04 42 celadonite 5.34 3.65 -1.69 -0.099 0.28879E+04 43 celadonite-Fe 3.88 1.09 -2.79 -0.164 0.47561E+04 44 chrysotile 23.89 21.57 -2.32 -0.194 0.39692E+04 49 chlorite-Al-free 47.17 43.14 -4.04 -0.168 0.68936E+04 51 chloritoid-Fe 9.17 5.06 -4.12 -0.275 0.70315E+04 52 chloritoid-Mn 11.40 7.56 -3.84 -0.256 0.65558E+04 54 coesite -2.38 -3.16 -0.78 -0.260 0.13341E+04 61 cristobalite -2.56 -3.16 -0.60 -0.199 0.10195E+04 63 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71234E+04 65 diaspore 2.87 0.74 -2.13 -0.356 0.36450E+04 66 diamond -3.10 -7.71 -4.61 -1.317 0.78700E+04 71 enstatite 17.26 12.27 -4.99 -0.499 0.85225E+04 73 clinoenstatite 17.17 12.27 -4.89 -0.489 0.83541E+04 75 epidote 24.67 22.70 -1.97 -0.095 0.33585E+04 76 clinozoisite 22.81 18.95 -3.86 -0.175 0.65868E+04 77 epidote-Fe 29.84 26.46 -3.38 -0.176 0.57768E+04 78 fayalite 14.05 10.31 -3.73 -0.533 0.63743E+04 79 ferrosilite 11.15 7.16 -3.99 -0.399 0.68202E+04 83 gibbsite 4.08 0.74 -3.34 -0.477 0.57035E+04 84 glaucophane 22.97 20.80 -2.17 -0.059 0.37133E+04 85 glaucophane-Fe 17.28 13.12 -4.15 -0.112 0.70919E+04 86 graphite -3.55 -7.71 -4.17 -1.190 0.71123E+04 87 greenalite 16.14 13.89 -2.25 -0.187 0.38408E+04 90 hematite 12.57 8.99 -3.58 -0.434 0.61111E+04 91 heulandite -5.83 -7.52 -1.69 -0.077 0.28938E+04 95 jadeite 4.22 2.77 -1.44 -0.144 0.24617E+04 97 kalsilite 7.58 3.83 -3.76 -0.537 0.64126E+04 98 kaolinite -1.33 -4.84 -3.50 -0.319 0.59831E+04 101 laumontite 2.88 1.95 -0.93 -0.062 0.15935E+04 102 lawsonite 9.62 8.26 -1.35 -0.090 0.23069E+04 103 leucite 4.12 0.67 -3.45 -0.345 0.58873E+04 105 lizardite 23.24 21.57 -1.68 -0.140 0.28618E+04 107 magnetite 20.09 15.72 -4.37 -0.356 0.74536E+04 108 minnesotaite 10.39 7.58 -2.81 -0.165 0.48028E+04 112 manganosite 14.06 9.24 -4.82 -1.204 0.82251E+04 120 muscovite 2.58 -1.01 -3.59 -0.211 0.61314E+04 121 paragonite 4.24 1.09 -3.15 -0.185 0.53705E+04 122 nepheline 8.34 5.93 -2.41 -0.344 0.41125E+04 128 periclase-Fe 11.63 6.73 -4.89 -1.223 0.83523E+04 134 phlogopite-Na 29.65 27.50 -2.15 -0.119 0.36677E+04 136 prehnite 19.37 18.21 -1.16 -0.068 0.19849E+04 137 prehnite-Fe 22.50 21.96 -0.53 -0.032 0.91157E+03 138 pumpellyite-Fe 46.27 43.89 -2.38 -0.053 0.40580E+04 139 pumpellyite-Mg 48.99 46.45 -2.54 -0.057 0.43418E+04 143 pyrrhotite -4.26 -7.92 -3.66 -1.218 0.62409E+04 144 pyrrhotiteFe0.875 -6.02 -9.31 -3.30 -1.212 0.56281E+04 145 pyroxmangite 7.40 6.08 -1.32 -0.263 0.22455E+04 146 pyrophyllite -6.18 -11.15 -4.98 -0.311 0.84961E+04 147 quartz -2.99 -3.16 -0.17 -0.056 0.28681E+03 152 rhodonite 7.45 6.08 -1.36 -0.272 0.23257E+04 153 sanidine -1.28 -2.49 -1.21 -0.093 0.20677E+04 165 stilpnomelane-Mg 27.44 25.81 -1.63 -0.049 0.27803E+04 171 talc 16.49 15.25 -1.24 -0.073 0.21140E+04 174 tephroite 18.09 15.32 -2.76 -0.394 0.47146E+04 178 tridymite -2.63 -3.16 -0.53 -0.177 0.90679E+03 179 tremolite 47.87 47.42 -0.45 -0.012 0.77495E+03 180 ferroactinolite 38.45 34.62 -3.83 -0.104 0.65449E+04 181 troilite-low -4.41 -7.92 -3.50 -1.168 0.59837E+04 183 vesuvianite 223.47 218.82 -4.65 -0.036 0.79434E+04 187 wairakite 3.95 1.95 -2.00 -0.118 0.34154E+04 188 walstromite 11.51 9.94 -1.56 -0.313 0.26719E+04 189 wollastonite 10.46 9.94 -0.52 -0.103 0.88229E+03 190 pseudo-wollastonite 11.00 9.94 -1.06 -0.211 0.18021E+04 191 zoisite 22.85 18.95 -3.90 -0.177 0.66608E+04 192 akaganeite 7.75 4.49 -3.26 -0.705 0.55681E+04 199 chalcedony -2.80 -3.16 -0.35 -0.118 0.60611E+03 201 montmorillonite-Ca -2.29 -6.17 -3.88 -0.240 0.66180E+04 202 montmorillonite-K -2.24 -6.27 -4.03 -0.247 0.68816E+04 203 montmorillonite-Mg -2.48 -6.79 -4.32 -0.267 0.73678E+04 204 montmorillonite-Na -2.04 -5.57 -3.54 -0.216 0.60365E+04 205 nontronite-Ca 3.21 -0.19 -3.41 -0.221 0.58215E+04 206 nontronite-H 2.53 -2.36 -4.89 -0.328 0.83485E+04 207 nontronite-K 3.34 -0.30 -3.64 -0.233 0.62083E+04 208 nontronite-Mg 3.07 -0.82 -3.90 -0.253 0.66554E+04 209 nontronite-Na 3.52 0.40 -3.12 -0.200 0.53292E+04 224 tobermorite 9.82 7.76 -2.07 -0.564 0.35287E+04 230 alabandite -0.98 -5.41 -4.43 -1.477 0.75666E+04 233 boehmite 4.41 0.74 -3.67 -0.611 0.62619E+04 235 ferrous-oxide 9.81 6.73 -3.08 -0.769 0.52532E+04 240 silica-amorphous -2.09 -3.16 -1.07 -0.355 0.18203E+04 242 an20ab80 2.02 1.35 -0.67 -0.052 0.11472E+04 243 an25ab75 2.65 1.78 -0.87 -0.067 0.14810E+04 244 an30ab70 3.28 2.21 -1.07 -0.082 0.18244E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 100.0000000 g Current total amount of reactant added: 2899.9990000 g New total amount of reactant added: 2999.9990000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.5221E-10 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 11 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 2999.9990000 Water: Moles liquid = 0.3870E+02 kg liquid = 0.6972E+00 Moles total = 0.1790E+02 kg total = 0.3225E+00 Activity = 1.0000 Stoichiometric ionic strength = .1136729E-01 Osmotic coef. = 0.9689 True ionic strength = .2004677E-01 Chg. balance for total moles = 0.5221E-10 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.88417E-10 -10.0535 0.74286E-10 -10.1291 0.84018E+00 -0.0756 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.19700E-03 -3.7055 0.16451E-03 -3.7838 0.83512E+00 -0.0783 4 SO4-- 0.92786E-12 -12.0325 0.48166E-12 -12.3173 0.51911E+00 -0.2847 5 HCO3- 0.34332E-06 -6.4643 0.28713E-06 -6.5419 0.83634E+00 -0.0776 6 HS- 0.36575E-04 -4.4368 0.30549E-04 -4.5150 0.83524E+00 -0.0782 7 Al+++ 0.97366E-29 -29.0116 0.22476E-29 -29.6483 0.23084E+00 -0.6367 8 H4SiO4 0.69597E-03 -3.1574 0.69597E-03 -3.1574 0.10000E+01 0.0000 9 Ca++ 0.13539E-06 -6.8684 0.69767E-07 -7.1563 0.51530E+00 -0.2879 10 Mg++ 0.21181E-10 -10.6741 0.10865E-10 -10.9640 0.51294E+00 -0.2899 11 Fe++ 0.58378E-13 -13.2337 0.29977E-13 -13.5232 0.51350E+00 -0.2895 12 K+ 0.15673E-03 -3.8048 0.13111E-03 -3.8823 0.83654E+00 -0.0775 13 Na+ 0.19889E-01 -1.7014 0.16607E-01 -1.7797 0.83497E+00 -0.0783 14 Mn++ 0.18706E-10 -10.7280 0.96133E-11 -11.0171 0.51393E+00 -0.2891 15 HPO4-- 0.45217E-07 -7.3447 0.23476E-07 -7.6294 0.51919E+00 -0.2847 16 HSiO3- 0.10475E-01 -1.9798 0.87480E-02 -2.0581 0.83512E+00 -0.0783 17 Ca(HSiO3)+ 0.16612E-07 -7.7796 0.13899E-07 -7.8570 0.83672E+00 -0.0774 18 Mg(HSiO3)+ 0.32194E-11 -11.4922 0.26938E-11 -11.5696 0.83672E+00 -0.0774 19 NaHSiO3,aq 0.23496E-02 -2.6290 0.23496E-02 -2.6290 0.10000E+01 0.0000 20 AlO+ 0.66221E-16 -16.1790 0.55408E-16 -16.2564 0.83672E+00 -0.0774 22 HAlO2,aq 0.14854E-09 -9.8282 0.14854E-09 -9.8282 0.10000E+01 0.0000 23 AlO2- 0.53097E-05 -5.2749 0.44262E-05 -5.3540 0.83361E+00 -0.0790 24 CH4,aq 0.17751E-04 -4.7508 0.17690E-04 -4.7523 0.99653E+00 -0.0015 25 C2H6,aq 0.46347E-14 -14.3340 0.46186E-14 -14.3355 0.99653E+00 -0.0015 29 CO,aq 0.13262E-16 -16.8774 0.13262E-16 -16.8774 0.10000E+01 0.0000 30 CO2,aq 0.45736E-10 -10.3397 0.45577E-10 -10.3413 0.99653E+00 -0.0015 31 CO3-2 0.65175E-06 -6.1859 0.33761E-06 -6.4716 0.51801E+00 -0.2857 32 CaCO3,aq 0.29534E-09 -9.5297 0.29534E-09 -9.5297 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.61113E-12 -12.2139 0.51135E-12 -12.2913 0.83672E+00 -0.0774 34 CaCl+ 0.22199E-10 -10.6537 0.18575E-10 -10.7311 0.83672E+00 -0.0774 35 CaCl2,aq 0.72599E-15 -15.1391 0.72599E-15 -15.1391 0.10000E+01 0.0000 36 CaOH+ 0.79996E-07 -7.0969 0.66934E-07 -7.1744 0.83672E+00 -0.0774 37 CaSO4,aq 0.10671E-16 -16.9718 0.10671E-16 -16.9718 0.10000E+01 0.0000 38 HCl,aq 0.22395E-14 -14.6499 0.22395E-14 -14.6499 0.10000E+01 0.0000 43 FeCl+ 0.93294E-17 -17.0301 0.78061E-17 -17.1076 0.83672E+00 -0.0774 46 FeO,aq 0.21113E-09 -9.6755 0.21113E-09 -9.6755 0.10000E+01 0.0000 47 FeOH+ 0.15699E-10 -10.8041 0.13136E-10 -10.8815 0.83672E+00 -0.0774 48 HFeO2- 0.35608E-07 -7.4485 0.29737E-07 -7.5267 0.83512E+00 -0.0783 49 FeO+ 0.11002E-16 -16.9585 0.92059E-17 -17.0359 0.83672E+00 -0.0774 51 FeO2- 0.40874E-09 -9.3885 0.34135E-09 -9.4668 0.83512E+00 -0.0783 52 HFeO2,aq 0.32251E-11 -11.4915 0.32251E-11 -11.4915 0.10000E+01 0.0000 53 H2,aq 0.11623E-04 -4.9347 0.11583E-04 -4.9362 0.99653E+00 -0.0015 54 KCl,aq 0.39094E-09 -9.4079 0.39094E-09 -9.4079 0.10000E+01 0.0000 56 KOH,aq 0.75375E-06 -6.1228 0.75375E-06 -6.1228 0.10000E+01 0.0000 57 KSO4- 0.11735E-14 -14.9305 0.97999E-15 -15.0088 0.83512E+00 -0.0783 58 MgCO3,aq 0.11529E-13 -13.9382 0.11529E-13 -13.9382 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.97247E-16 -16.0121 0.81368E-16 -16.0895 0.83672E+00 -0.0774 60 MgCl+ 0.31332E-14 -14.5040 0.26217E-14 -14.5814 0.83672E+00 -0.0774 61 MgOH+ 0.68934E-10 -10.1616 0.57678E-10 -10.2390 0.83672E+00 -0.0774 63 MnO,aq 0.18041E-08 -8.7438 0.18041E-08 -8.7438 0.10000E+01 0.0000 64 MnOH+ 0.46768E-09 -9.3301 0.39132E-09 -9.4075 0.83672E+00 -0.0774 65 MnO2-2 0.20944E-10 -10.6789 0.10849E-10 -10.9646 0.51801E+00 -0.2857 66 HMnO2- 0.21143E-09 -9.6748 0.17657E-09 -9.7531 0.83512E+00 -0.0783 69 MnCl+ 0.11639E-13 -13.9341 0.97389E-14 -14.0115 0.83672E+00 -0.0774 71 NaCl,aq 0.90540E-06 -6.0432 0.90540E-06 -6.0432 0.10000E+01 0.0000 72 NaOH,aq 0.96047E-04 -4.0175 0.96047E-04 -4.0175 0.10000E+01 0.0000 74 OH- 0.93301E-02 -2.0301 0.77777E-02 -2.1092 0.83361E+00 -0.0790 79 HPO3-2 0.16359E-14 -14.7862 0.84741E-15 -15.0719 0.51801E+00 -0.2857 81 H2PO3- 0.15116E-18 -18.8206 0.12624E-18 -18.8988 0.83512E+00 -0.0783 82 H3PO4,aq 0.90608E-18 -18.0428 0.90608E-18 -18.0428 0.10000E+01 0.0000 83 H2PO4- 0.38487E-10 -10.4147 0.32171E-10 -10.4925 0.83591E+00 -0.0778 84 PO4-3 0.10635E-08 -8.9733 0.25784E-09 -9.5886 0.24246E+00 -0.6154 88 HP2O7-3 0.94405E-18 -18.0250 0.21814E-18 -18.6613 0.23107E+00 -0.6363 89 P2O7-4 0.91112E-17 -17.0404 0.70151E-18 -18.1540 0.76994E-01 -1.1135 90 H2S,aq 0.70381E-08 -8.1525 0.70137E-08 -8.1541 0.99653E+00 -0.0015 91 S2-2 0.34464E-14 -14.4626 0.17853E-14 -14.7483 0.51801E+00 -0.2857 97 SO3-2 0.13796E-17 -17.8602 0.72500E-18 -18.1397 0.52551E+00 -0.2794 99 HSO4- 0.41172E-19 -19.3854 0.34483E-19 -19.4624 0.83754E+00 -0.0770 Charge balance for all species = 0.7486E-10 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.8841727E-10 -.2227669E-01 -.2241451E+02 0.0000 2 H2O 0.1000000E+01 0.5550489E+02 0.9981982E+06 0.0000 3 Cl- 0.1969952E-03 0.1979010E-03 0.7003983E+01 6.3453 4 SO4-- 0.9278576E-12 -.2065709E-04 -.1980902E+01 7.9409 5 HCO3- 0.3433205E-06 0.1874674E-04 0.1141884E+01 3.5872 6 HS- 0.3657488E-04 0.5723901E-04 0.1889716E+01 5.6141 7 Al+++ 0.9736630E-29 0.5309813E-05 0.1430176E+00 0.7390 8 H4SiO4 0.6959695E-03 0.1352076E-01 0.1297293E+04 -3.1574 9 Ca++ 0.1353912E-06 0.2323166E-06 0.9294591E-02 13.1018 10 Mg++ 0.2118111E-10 0.9334891E-10 0.2265551E-05 9.2942 11 Fe++ 0.5837826E-13 0.3624690E-07 0.2020760E-02 6.7350 12 K+ 0.1567343E-03 0.1574885E-03 0.6147404E+01 6.2467 13 Na+ 0.1988883E-01 0.2233539E-01 0.5125932E+03 8.3494 14 Mn++ 0.1870550E-10 0.2522830E-08 0.1383582E-03 9.2411 15 HPO4-- 0.4521730E-07 0.4631924E-07 0.4437942E-02 12.6288 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.4967552E+02 -.1553104E-01 -.4965999E+02 0.0000000E+00 2 H2O 0.1790203E+02 0.3869733E+02 -.2079530E+02 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.8316570E-01 -.1440187E-04 0.8318011E-01 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.8314020E-01 0.3990634E-04 -.8318011E-01 0.0000000E+00 7 Al+++ 0.9782222E+01 0.3701937E-05 0.9782218E+01 0.0000000E+00 8 H4SiO4 0.3123834E+02 0.9426506E-02 0.3122891E+02 0.0000000E+00 9 Ca++ 0.3450441E+01 0.1619683E-06 0.3450441E+01 0.0000000E+00 10 Mg++ 0.2380952E+01 0.6508172E-10 0.2380952E+01 0.0000000E+00 11 Fe++ 0.2139025E+01 0.2527090E-07 0.2139025E+01 0.0000000E+00 12 K+ 0.6369425E+00 0.1097990E-03 0.6368327E+00 0.0000000E+00 13 Na+ 0.3765890E+01 0.1557196E-01 0.3750318E+01 0.0000000E+00 14 Mn++ 0.5201577E-01 0.1758886E-08 0.5201577E-01 0.0000000E+00 15 HPO4-- 0.1775272E-01 0.3229321E-07 0.1775269E-01 0.0000000E+00 Chg. balance for solid moles: 0.4337E-14 Mass of aqueous solution: 0.698402E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 2999.9990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 3.747 0.574 982.6 2.992 29.98 377.2 andradite 0.3327 -0.478 169.1 2.228 5.159 43.93 grossular 0.8057E-01 -1.094 36.29 1.560 1.107 10.10 apatite-OH 0.5918E-02 -2.228 2.973 0.473 0.9070E-01 0.9446 clinochlore 0.4267 -0.370 237.2 2.375 7.237 90.21 daphnite 0.1235 -0.908 88.14 1.945 2.689 26.71 chlorite-Mn 0.1040E-01 -1.983 7.376 0.868 0.2250 2.350 diopside 0.1539 -0.813 33.33 1.523 1.017 10.19 hedenbergite 0.3991E-01 -1.399 9.903 0.996 0.3022 2.712 microcline 0.5585 -0.253 155.4 2.192 4.743 60.72 stilbite 1.936 0.287 1364. 3.135 41.62 636.2 stilpnomelane-Fe 0.1568 -0.805 169.0 2.228 5.156 58.37 tr.625ac.25prg.125 0.2581E-01 -1.588 22.06 1.344 0.6731 7.100 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8051E+00 0.8051E+00 1.0000 -0.094 grossular 0.1949E+00 0.1949E+00 1.0000 -0.710 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.7611E+00 0.7611E+00 1.0000 -0.119 daphnite 0.2203E+00 0.2203E+00 1.0000 -0.657 chlorite-Mn 0.1856E-01 0.1856E-01 1.0000 -1.732 diopside 0.7941E+00 0.7941E+00 1.0000 -0.100 hedenbergite 0.2059E+00 0.2059E+00 1.0000 -0.686 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 tr.625ac.25prg.125 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 3277.324569 g Volume = 1326.716575 cm3 Porosity: -10.4677% V(tot) - V(min): -.12572E+03 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 2999.9990000 g log = 3.4771 Original solution: 1000.0103000 g Original solution / Rock added: 0.33 (Water/Rock Ratio), log = -0.4771 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0618 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9615E+00 0.9854 0.1006E+01 0.1021E+01 CO2,gas 0.4561E-08 1.0068 0.4876E-08 0.4843E-08 CH4,gas 0.2422E-01 1.0124 0.2604E-01 0.2572E-01 H2,gas 0.1431E-01 1.0006 0.1521E-01 0.1520E-01 H2S,gas 0.1823E-06 0.9959 0.1928E-06 0.1936E-06 S2,gas 0.5683E-29 1.0000 0.6034E-29 0.6034E-29 CO,gas 0.1861E-13 1.0000 0.1976E-13 0.1976E-13 SO3,gas 0.9465E-48 1.0000 0.1005E-47 0.1005E-47 SO2,gas 0.5600E-27 1.0000 0.5946E-27 0.5946E-27 HCl,gas 0.3722E-17 1.0000 0.3952E-17 0.3952E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 16 albite -0.38 -0.38 0.00 0.000 0.11184E-10 22 andradite 39.01 39.01 0.00 0.000 0.00000E+00 23 grossular 32.73 32.73 0.00 0.000 0.12132E-10 32 apatite-OH -18.15 -18.15 0.00 0.000 0.60662E-11 46 clinochlore 39.07 39.07 0.00 0.000 -0.12132E-10 47 daphnite 28.97 28.97 0.00 0.000 -0.12132E-10 48 chlorite-Mn 46.87 46.87 0.00 0.000 0.12132E-10 67 diopside 16.18 16.18 0.00 0.000 0.12132E-10 68 hedenbergite 14.21 14.21 0.00 0.000 0.30331E-11 116 microcline -2.49 -2.49 0.00 0.000 0.13649E-10 163 stilbite -7.52 -7.52 0.00 0.000 0.15165E-10 164 stilpnomelane-Fe 13.02 13.02 0.00 0.000 0.21232E-10 245 tr.625ac.25prg.125 45.16 45.16 0.00 0.000 0.00000E+00 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -16.67 -10.01 -3.337 0.17093E+05 -8.312 3 CH4,gas 4.54 1.26 -3.28 -0.821 0.56062E+04 -1.584 4 H2,gas 8.00 4.48 -3.52 -2.010 0.60051E+04 -1.818 5 H2S,gas -6.23 -14.64 -8.41 -4.207 0.14366E+05 -6.715 6 S2,gas -7.34 -38.25 -30.92 -4.757 0.52792E+05 -29.219 7 CO,gas 3.21 -12.19 -15.40 -4.739 0.26300E+05 -13.704 8 SO3,gas 17.12 -32.58 -49.70 -12.424 0.84856E+05 -47.998 9 SO2,gas 0.83 -28.09 -28.92 -7.713 0.49388E+05 -27.226 10 HCl,gas 5.19 -13.91 -19.10 -9.551 0.32616E+05 -17.403 11 acmite 7.71 6.53 -1.18 -0.123 0.20175E+04 15 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 19 spessartine 24.46 19.73 -4.73 -0.236 0.80736E+04 20 analcite 3.32 2.77 -0.55 -0.061 0.93624E+03 26 annite 20.12 17.72 -2.40 -0.134 0.41064E+04 27 phlogopite 27.06 25.40 -1.67 -0.093 0.28489E+04 29 anorthite 12.71 8.26 -4.45 -0.342 0.75903E+04 35 aragonite 0.97 -3.57 -4.54 -1.512 0.77446E+04 36 brucite 12.57 9.29 -3.27 -0.655 0.55909E+04 37 calcite 0.81 -3.57 -4.38 -1.460 0.74804E+04 38 carnegieite-low 9.02 5.93 -3.09 -0.442 0.52801E+04 39 carnegieite-high 10.09 5.93 -4.16 -0.595 0.71071E+04 40 carpholite-Mg 8.58 4.46 -4.12 -0.275 0.70429E+04 41 carpholite-Fe 6.71 1.90 -4.81 -0.321 0.82206E+04 42 celadonite 5.34 3.65 -1.69 -0.099 0.28879E+04 43 celadonite-Fe 3.88 1.09 -2.79 -0.164 0.47561E+04 44 chrysotile 23.89 21.57 -2.32 -0.194 0.39692E+04 49 chlorite-Al-free 47.17 43.14 -4.04 -0.168 0.68936E+04 51 chloritoid-Fe 9.17 5.06 -4.12 -0.275 0.70315E+04 52 chloritoid-Mn 11.40 7.56 -3.84 -0.256 0.65557E+04 54 coesite -2.38 -3.16 -0.78 -0.260 0.13341E+04 61 cristobalite -2.56 -3.16 -0.60 -0.199 0.10195E+04 63 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71234E+04 65 diaspore 2.87 0.74 -2.13 -0.356 0.36450E+04 66 diamond -3.10 -7.71 -4.60 -1.315 0.78594E+04 71 enstatite 17.26 12.27 -4.99 -0.499 0.85226E+04 73 clinoenstatite 17.17 12.27 -4.89 -0.489 0.83541E+04 75 epidote 24.67 22.70 -1.97 -0.095 0.33585E+04 76 clinozoisite 22.81 18.95 -3.86 -0.175 0.65868E+04 77 epidote-Fe 29.84 26.46 -3.38 -0.176 0.57768E+04 78 fayalite 14.05 10.31 -3.73 -0.533 0.63743E+04 79 ferrosilite 11.15 7.16 -3.99 -0.399 0.68202E+04 83 gibbsite 4.08 0.74 -3.34 -0.477 0.57035E+04 84 glaucophane 22.97 20.80 -2.17 -0.059 0.37133E+04 85 glaucophane-Fe 17.28 13.12 -4.15 -0.112 0.70919E+04 86 graphite -3.55 -7.71 -4.16 -1.188 0.71017E+04 87 greenalite 16.14 13.89 -2.25 -0.187 0.38408E+04 90 hematite 12.57 8.99 -3.58 -0.434 0.61111E+04 91 heulandite -5.83 -7.52 -1.69 -0.077 0.28938E+04 95 jadeite 4.22 2.77 -1.44 -0.144 0.24617E+04 97 kalsilite 7.58 3.83 -3.76 -0.537 0.64126E+04 98 kaolinite -1.33 -4.84 -3.50 -0.319 0.59831E+04 101 laumontite 2.88 1.95 -0.93 -0.062 0.15935E+04 102 lawsonite 9.62 8.26 -1.35 -0.090 0.23069E+04 103 leucite 4.12 0.67 -3.45 -0.345 0.58873E+04 105 lizardite 23.24 21.57 -1.68 -0.140 0.28618E+04 107 magnetite 20.09 15.72 -4.37 -0.356 0.74536E+04 108 minnesotaite 10.39 7.58 -2.81 -0.165 0.48028E+04 112 manganosite 14.06 9.24 -4.82 -1.204 0.82250E+04 120 muscovite 2.58 -1.01 -3.59 -0.211 0.61314E+04 121 paragonite 4.24 1.09 -3.15 -0.185 0.53705E+04 122 nepheline 8.34 5.93 -2.41 -0.344 0.41125E+04 128 periclase-Fe 11.63 6.73 -4.89 -1.223 0.83523E+04 134 phlogopite-Na 29.65 27.50 -2.15 -0.119 0.36677E+04 136 prehnite 19.37 18.21 -1.16 -0.068 0.19849E+04 137 prehnite-Fe 22.50 21.96 -0.53 -0.032 0.91157E+03 138 pumpellyite-Fe 46.27 43.89 -2.38 -0.053 0.40580E+04 139 pumpellyite-Mg 48.99 46.45 -2.54 -0.057 0.43418E+04 143 pyrrhotite -4.26 -7.91 -3.65 -1.216 0.62302E+04 144 pyrrhotiteFe0.875 -6.02 -9.31 -3.29 -1.210 0.56174E+04 145 pyroxmangite 7.40 6.08 -1.32 -0.263 0.22454E+04 146 pyrophyllite -6.18 -11.15 -4.98 -0.311 0.84961E+04 147 quartz -2.99 -3.16 -0.17 -0.056 0.28681E+03 152 rhodonite 7.45 6.08 -1.36 -0.272 0.23256E+04 153 sanidine -1.28 -2.49 -1.21 -0.093 0.20677E+04 165 stilpnomelane-Mg 27.44 25.81 -1.63 -0.049 0.27803E+04 171 talc 16.49 15.25 -1.24 -0.073 0.21140E+04 174 tephroite 18.09 15.32 -2.76 -0.394 0.47145E+04 178 tridymite -2.63 -3.16 -0.53 -0.177 0.90679E+03 179 tremolite 47.87 47.42 -0.45 -0.012 0.77495E+03 180 ferroactinolite 38.45 34.62 -3.83 -0.104 0.65449E+04 181 troilite-low -4.41 -7.91 -3.50 -1.166 0.59730E+04 183 vesuvianite 223.47 218.82 -4.65 -0.036 0.79435E+04 187 wairakite 3.95 1.95 -2.00 -0.118 0.34154E+04 188 walstromite 11.51 9.94 -1.56 -0.313 0.26719E+04 189 wollastonite 10.46 9.94 -0.52 -0.103 0.88229E+03 190 pseudo-wollastonite 11.00 9.94 -1.06 -0.211 0.18021E+04 191 zoisite 22.85 18.95 -3.90 -0.177 0.66608E+04 192 akaganeite 7.75 4.49 -3.26 -0.705 0.55681E+04 199 chalcedony -2.80 -3.16 -0.35 -0.118 0.60611E+03 201 montmorillonite-Ca -2.29 -6.17 -3.88 -0.240 0.66180E+04 202 montmorillonite-K -2.24 -6.27 -4.03 -0.247 0.68816E+04 203 montmorillonite-Mg -2.48 -6.79 -4.32 -0.267 0.73678E+04 204 montmorillonite-Na -2.04 -5.57 -3.54 -0.216 0.60365E+04 205 nontronite-Ca 3.21 -0.19 -3.41 -0.221 0.58215E+04 206 nontronite-H 2.53 -2.36 -4.89 -0.328 0.83485E+04 207 nontronite-K 3.34 -0.30 -3.64 -0.233 0.62083E+04 208 nontronite-Mg 3.07 -0.82 -3.90 -0.253 0.66554E+04 209 nontronite-Na 3.52 0.40 -3.12 -0.200 0.53292E+04 224 tobermorite 9.82 7.76 -2.07 -0.564 0.35287E+04 230 alabandite -0.98 -5.40 -4.43 -1.475 0.75559E+04 233 boehmite 4.41 0.74 -3.67 -0.611 0.62619E+04 235 ferrous-oxide 9.81 6.73 -3.08 -0.769 0.52532E+04 240 silica-amorphous -2.09 -3.16 -1.07 -0.355 0.18203E+04 242 an20ab80 2.02 1.35 -0.67 -0.052 0.11472E+04 243 an25ab75 2.65 1.78 -0.87 -0.067 0.14810E+04 244 an30ab70 3.28 2.21 -1.07 -0.082 0.18244E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 100.0000000 g Current total amount of reactant added: 2999.9990000 g New total amount of reactant added: 3099.9990000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.5221E-10 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 11 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 3099.9990000 Water: Moles liquid = 0.3814E+02 kg liquid = 0.6871E+00 Moles total = 0.1665E+02 kg total = 0.2999E+00 Activity = 1.0000 Stoichiometric ionic strength = .1136968E-01 Osmotic coef. = 0.9689 True ionic strength = .2004864E-01 Chg. balance for total moles = 0.5221E-10 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.88425E-10 -10.0534 0.74293E-10 -10.1291 0.84017E+00 -0.0756 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.19987E-03 -3.6992 0.16692E-03 -3.7775 0.83511E+00 -0.0783 4 SO4-- 0.94136E-12 -12.0262 0.48866E-12 -12.3110 0.51910E+00 -0.2847 5 HCO3- 0.34832E-06 -6.4580 0.29131E-06 -6.5356 0.83634E+00 -0.0776 6 HS- 0.37109E-04 -4.4305 0.30995E-04 -4.5087 0.83524E+00 -0.0782 7 Al+++ 0.97397E-29 -29.0115 0.22481E-29 -29.6482 0.23082E+00 -0.6367 8 H4SiO4 0.69597E-03 -3.1574 0.69597E-03 -3.1574 0.10000E+01 0.0000 9 Ca++ 0.13542E-06 -6.8683 0.69779E-07 -7.1563 0.51529E+00 -0.2880 10 Mg++ 0.21185E-10 -10.6740 0.10867E-10 -10.9639 0.51293E+00 -0.2899 11 Fe++ 0.58390E-13 -13.2337 0.29983E-13 -13.5231 0.51349E+00 -0.2895 12 K+ 0.15675E-03 -3.8048 0.13113E-03 -3.8823 0.83654E+00 -0.0775 13 Na+ 0.19891E-01 -1.7014 0.16608E-01 -1.7797 0.83496E+00 -0.0783 14 Mn++ 0.18711E-10 -10.7279 0.96159E-11 -11.0170 0.51392E+00 -0.2891 15 HPO4-- 0.45211E-07 -7.3448 0.23472E-07 -7.6294 0.51918E+00 -0.2847 16 HSiO3- 0.10474E-01 -1.9799 0.87473E-02 -2.0581 0.83511E+00 -0.0783 17 Ca(HSiO3)+ 0.16613E-07 -7.7795 0.13901E-07 -7.8570 0.83672E+00 -0.0774 18 Mg(HSiO3)+ 0.32197E-11 -11.4922 0.26940E-11 -11.5696 0.83672E+00 -0.0774 19 NaHSiO3,aq 0.23496E-02 -2.6290 0.23496E-02 -2.6290 0.10000E+01 0.0000 20 AlO+ 0.66226E-16 -16.1790 0.55413E-16 -16.2564 0.83672E+00 -0.0774 22 HAlO2,aq 0.14854E-09 -9.8282 0.14854E-09 -9.8282 0.10000E+01 0.0000 23 AlO2- 0.53092E-05 -5.2750 0.44258E-05 -5.3540 0.83360E+00 -0.0790 24 CH4,aq 0.18011E-04 -4.7445 0.17948E-04 -4.7460 0.99653E+00 -0.0015 25 C2H6,aq 0.47712E-14 -14.3214 0.47547E-14 -14.3229 0.99653E+00 -0.0015 29 CO,aq 0.13456E-16 -16.8711 0.13456E-16 -16.8711 0.10000E+01 0.0000 30 CO2,aq 0.46405E-10 -10.3334 0.46244E-10 -10.3349 0.99653E+00 -0.0015 31 CO3-2 0.66119E-06 -6.1797 0.34249E-06 -6.4653 0.51800E+00 -0.2857 32 CaCO3,aq 0.29967E-09 -9.5234 0.29967E-09 -9.5234 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.62013E-12 -12.2075 0.51887E-12 -12.2849 0.83672E+00 -0.0774 34 CaCl+ 0.22527E-10 -10.6473 0.18849E-10 -10.7247 0.83672E+00 -0.0774 35 CaCl2,aq 0.74748E-15 -15.1264 0.74748E-15 -15.1264 0.10000E+01 0.0000 36 CaOH+ 0.80003E-07 -7.0969 0.66940E-07 -7.1743 0.83672E+00 -0.0774 37 CaSO4,aq 0.10828E-16 -16.9655 0.10828E-16 -16.9655 0.10000E+01 0.0000 38 HCl,aq 0.22724E-14 -14.6435 0.22724E-14 -14.6435 0.10000E+01 0.0000 43 FeCl+ 0.94674E-17 -17.0238 0.79215E-17 -17.1012 0.83672E+00 -0.0774 46 FeO,aq 0.21113E-09 -9.6755 0.21113E-09 -9.6755 0.10000E+01 0.0000 47 FeOH+ 0.15700E-10 -10.8041 0.13137E-10 -10.8815 0.83672E+00 -0.0774 48 HFeO2- 0.35605E-07 -7.4485 0.29734E-07 -7.5267 0.83511E+00 -0.0783 49 FeO+ 0.11003E-16 -16.9585 0.92067E-17 -17.0359 0.83672E+00 -0.0774 51 FeO2- 0.40871E-09 -9.3886 0.34132E-09 -9.4668 0.83511E+00 -0.0783 52 HFeO2,aq 0.32251E-11 -11.4915 0.32251E-11 -11.4915 0.10000E+01 0.0000 53 H2,aq 0.11623E-04 -4.9347 0.11583E-04 -4.9362 0.99653E+00 -0.0015 54 KCl,aq 0.39669E-09 -9.4015 0.39669E-09 -9.4015 0.10000E+01 0.0000 56 KOH,aq 0.75375E-06 -6.1228 0.75375E-06 -6.1228 0.10000E+01 0.0000 57 KSO4- 0.11906E-14 -14.9242 0.99431E-15 -15.0025 0.83511E+00 -0.0783 58 MgCO3,aq 0.11697E-13 -13.9319 0.11697E-13 -13.9319 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.98678E-16 -16.0058 0.82566E-16 -16.0832 0.83672E+00 -0.0774 60 MgCl+ 0.31796E-14 -14.4976 0.26604E-14 -14.5751 0.83672E+00 -0.0774 61 MgOH+ 0.68940E-10 -10.1615 0.57683E-10 -10.2390 0.83672E+00 -0.0774 63 MnO,aq 0.18042E-08 -8.7437 0.18042E-08 -8.7437 0.10000E+01 0.0000 64 MnOH+ 0.46777E-09 -9.3300 0.39139E-09 -9.4074 0.83672E+00 -0.0774 65 MnO2-2 0.20943E-10 -10.6790 0.10849E-10 -10.9646 0.51800E+00 -0.2857 66 HMnO2- 0.21144E-09 -9.6748 0.17657E-09 -9.7531 0.83511E+00 -0.0783 69 MnCl+ 0.11813E-13 -13.9277 0.98839E-14 -14.0051 0.83672E+00 -0.0774 71 NaCl,aq 0.91870E-06 -6.0368 0.91870E-06 -6.0368 0.10000E+01 0.0000 72 NaOH,aq 0.96047E-04 -4.0175 0.96047E-04 -4.0175 0.10000E+01 0.0000 74 OH- 0.93294E-02 -2.0301 0.77770E-02 -2.1092 0.83360E+00 -0.0790 79 HPO3-2 0.16356E-14 -14.7863 0.84726E-15 -15.0720 0.51800E+00 -0.2857 81 H2PO3- 0.15115E-18 -18.8206 0.12622E-18 -18.8989 0.83511E+00 -0.0783 82 H3PO4,aq 0.90608E-18 -18.0428 0.90608E-18 -18.0428 0.10000E+01 0.0000 83 H2PO4- 0.38484E-10 -10.4147 0.32169E-10 -10.4926 0.83591E+00 -0.0778 84 PO4-3 0.10632E-08 -8.9734 0.25778E-09 -9.5888 0.24245E+00 -0.6154 88 HP2O7-3 0.94386E-18 -18.0251 0.21808E-18 -18.6614 0.23105E+00 -0.6363 89 P2O7-4 0.91090E-17 -17.0405 0.70127E-18 -18.1541 0.76987E-01 -1.1136 90 H2S,aq 0.71416E-08 -8.1462 0.71168E-08 -8.1477 0.99653E+00 -0.0015 91 S2-2 0.35479E-14 -14.4500 0.18378E-14 -14.7357 0.51800E+00 -0.2857 97 SO3-2 0.13997E-17 -17.8540 0.73553E-18 -18.1334 0.52550E+00 -0.2794 99 HSO4- 0.41774E-19 -19.3791 0.34987E-19 -19.4561 0.83753E+00 -0.0770 Charge balance for all species = 0.7599E-10 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.8842544E-10 -.2227512E-01 -.2241294E+02 0.0000 2 H2O 0.1000000E+01 0.5550489E+02 0.9981981E+06 0.0000 3 Cl- 0.1998742E-03 0.2007934E-03 0.7106345E+01 6.3516 4 SO4-- 0.9413639E-12 -.2091663E-04 -.2005790E+01 7.9471 5 HCO3- 0.3483158E-06 0.1902073E-04 0.1158573E+01 3.5934 6 HS- 0.3710943E-04 0.5803320E-04 0.1915936E+01 5.6203 7 Al+++ 0.9739669E-29 0.5309370E-05 0.1430056E+00 0.7390 8 H4SiO4 0.6959703E-03 0.1351993E-01 0.1297213E+04 -3.1574 9 Ca++ 0.1354178E-06 0.2323568E-06 0.9296198E-02 13.1018 10 Mg++ 0.2118528E-10 0.9335989E-10 0.2265818E-05 9.2942 11 Fe++ 0.5838981E-13 0.3624400E-07 0.2020598E-02 6.7350 12 K+ 0.1567488E-03 0.1575030E-03 0.6147970E+01 6.2467 13 Na+ 0.1989068E-01 0.2233726E-01 0.5126358E+03 8.3494 14 Mn++ 0.1871099E-10 0.2523097E-08 0.1383728E-03 9.2411 15 HPO4-- 0.4521066E-07 0.4631238E-07 0.4437285E-02 12.6287 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.5133137E+02 -.1530624E-01 -.5131606E+02 0.0000000E+00 2 H2O 0.1664849E+02 0.3813992E+02 -.2149143E+02 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.8593704E-01 -.1437276E-04 0.8595142E-01 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.8591154E-01 0.3987723E-04 -.8595142E-01 0.0000000E+00 7 Al+++ 0.1010830E+02 0.3648308E-05 0.1010829E+02 0.0000000E+00 8 H4SiO4 0.3227962E+02 0.9290154E-02 0.3227033E+02 0.0000000E+00 9 Ca++ 0.3565456E+01 0.1596628E-06 0.3565455E+01 0.0000000E+00 10 Mg++ 0.2460317E+01 0.6415179E-10 0.2460317E+01 0.0000000E+00 11 Fe++ 0.2210326E+01 0.2490489E-07 0.2210326E+01 0.0000000E+00 12 K+ 0.6581739E+00 0.1082274E-03 0.6580657E+00 0.0000000E+00 13 Na+ 0.3891414E+01 0.1534894E-01 0.3876065E+01 0.0000000E+00 14 Mn++ 0.5374963E-01 0.1733734E-08 0.5374963E-01 0.0000000E+00 15 HPO4-- 0.1834448E-01 0.3182333E-07 0.1834445E-01 0.0000000E+00 Chg. balance for solid moles: 0.2269E-14 Mass of aqueous solution: 0.688342E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 3099.9990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 3.873 0.588 1016. 3.007 29.99 389.8 andradite 0.3438 -0.464 174.7 2.242 5.159 45.39 grossular 0.8325E-01 -1.080 37.50 1.574 1.107 10.43 apatite-OH 0.6115E-02 -2.214 3.072 0.487 0.9070E-01 0.9760 clinochlore 0.4409 -0.356 245.1 2.389 7.236 93.21 daphnite 0.1276 -0.894 91.07 1.959 2.689 27.60 chlorite-Mn 0.1075E-01 -1.969 7.621 0.882 0.2250 2.429 diopside 0.1594 -0.798 34.51 1.538 1.019 10.55 hedenbergite 0.4133E-01 -1.384 10.25 1.011 0.3027 2.808 microcline 0.5771 -0.239 160.6 2.206 4.743 62.74 stilbite 2.000 0.301 1409. 3.149 41.61 657.3 stilpnomelane-Fe 0.1620 -0.791 174.6 2.242 5.156 60.32 tr.625ac.25prg.125 0.2664E-01 -1.574 22.77 1.357 0.6724 7.329 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8051E+00 0.8051E+00 1.0000 -0.094 grossular 0.1949E+00 0.1949E+00 1.0000 -0.710 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.7611E+00 0.7611E+00 1.0000 -0.119 daphnite 0.2203E+00 0.2203E+00 1.0000 -0.657 chlorite-Mn 0.1856E-01 0.1856E-01 1.0000 -1.731 diopside 0.7941E+00 0.7941E+00 1.0000 -0.100 hedenbergite 0.2059E+00 0.2059E+00 1.0000 -0.686 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 tr.625ac.25prg.125 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 3386.575233 g Volume = 1370.919639 cm3 Porosity: -10.4690% V(tot) - V(min): -.12992E+03 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 3099.9990000 g log = 3.4914 Original solution: 1000.0103000 g Original solution / Rock added: 0.32 (Water/Rock Ratio), log = -0.4914 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0622 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9611E+00 0.9854 0.1006E+01 0.1021E+01 CO2,gas 0.4626E-08 1.0068 0.4948E-08 0.4914E-08 CH4,gas 0.2457E-01 1.0124 0.2642E-01 0.2610E-01 H2,gas 0.1431E-01 1.0006 0.1521E-01 0.1520E-01 H2S,gas 0.1849E-06 0.9959 0.1956E-06 0.1964E-06 S2,gas 0.5849E-29 1.0000 0.6212E-29 0.6212E-29 CO,gas 0.1888E-13 1.0000 0.2005E-13 0.2005E-13 SO3,gas 0.9601E-48 1.0000 0.1020E-47 0.1020E-47 SO2,gas 0.5680E-27 1.0000 0.6033E-27 0.6033E-27 HCl,gas 0.3775E-17 1.0000 0.4010E-17 0.4010E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 16 albite -0.38 -0.38 0.00 0.000 0.11184E-10 22 andradite 39.01 39.01 0.00 0.000 -0.12132E-10 23 grossular 32.73 32.73 0.00 0.000 0.12132E-10 32 apatite-OH -18.15 -18.15 0.00 0.000 0.00000E+00 46 clinochlore 39.07 39.07 0.00 0.000 0.24265E-10 47 daphnite 28.97 28.97 0.00 0.000 0.00000E+00 48 chlorite-Mn 46.87 46.87 0.00 0.000 0.00000E+00 67 diopside 16.18 16.18 0.00 0.000 0.60662E-11 68 hedenbergite 14.21 14.21 0.00 0.000 -0.30331E-11 116 microcline -2.49 -2.49 0.00 0.000 0.15165E-11 163 stilbite -7.52 -7.52 0.00 0.000 0.15165E-10 164 stilpnomelane-Fe 13.02 13.02 0.00 0.000 0.21232E-10 245 tr.625ac.25prg.125 45.16 45.16 0.00 0.000 -0.24265E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -16.66 -10.00 -3.335 0.17083E+05 -8.306 3 CH4,gas 4.54 1.27 -3.28 -0.819 0.55955E+04 -1.578 4 H2,gas 8.00 4.48 -3.52 -2.010 0.60051E+04 -1.818 5 H2S,gas -6.23 -14.64 -8.41 -4.204 0.14356E+05 -6.709 6 S2,gas -7.34 -38.24 -30.91 -4.755 0.52771E+05 -29.207 7 CO,gas 3.21 -12.18 -15.40 -4.737 0.26290E+05 -13.698 8 SO3,gas 17.12 -32.57 -49.69 -12.423 0.84845E+05 -47.991 9 SO2,gas 0.83 -28.09 -28.92 -7.712 0.49377E+05 -27.219 10 HCl,gas 5.19 -13.91 -19.10 -9.548 0.32606E+05 -17.397 11 acmite 7.71 6.53 -1.18 -0.123 0.20175E+04 15 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 19 spessartine 24.46 19.73 -4.73 -0.236 0.80734E+04 20 analcite 3.32 2.77 -0.55 -0.061 0.93624E+03 26 annite 20.12 17.72 -2.40 -0.134 0.41064E+04 27 phlogopite 27.06 25.40 -1.67 -0.093 0.28489E+04 29 anorthite 12.71 8.26 -4.45 -0.342 0.75903E+04 35 aragonite 0.97 -3.56 -4.53 -1.510 0.77338E+04 36 brucite 12.57 9.29 -3.27 -0.655 0.55909E+04 37 calcite 0.81 -3.56 -4.37 -1.458 0.74696E+04 38 carnegieite-low 9.02 5.93 -3.09 -0.442 0.52801E+04 39 carnegieite-high 10.09 5.93 -4.16 -0.595 0.71071E+04 40 carpholite-Mg 8.58 4.46 -4.12 -0.275 0.70429E+04 41 carpholite-Fe 6.71 1.90 -4.81 -0.321 0.82206E+04 42 celadonite 5.34 3.65 -1.69 -0.099 0.28879E+04 43 celadonite-Fe 3.88 1.09 -2.79 -0.164 0.47561E+04 44 chrysotile 23.89 21.57 -2.32 -0.194 0.39692E+04 49 chlorite-Al-free 47.17 43.14 -4.04 -0.168 0.68936E+04 51 chloritoid-Fe 9.17 5.06 -4.12 -0.275 0.70315E+04 52 chloritoid-Mn 11.40 7.56 -3.84 -0.256 0.65557E+04 54 coesite -2.38 -3.16 -0.78 -0.260 0.13341E+04 61 cristobalite -2.56 -3.16 -0.60 -0.199 0.10195E+04 63 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71234E+04 65 diaspore 2.87 0.74 -2.13 -0.356 0.36450E+04 66 diamond -3.10 -7.70 -4.60 -1.313 0.78486E+04 71 enstatite 17.26 12.27 -4.99 -0.499 0.85226E+04 73 clinoenstatite 17.17 12.27 -4.89 -0.489 0.83541E+04 75 epidote 24.67 22.70 -1.97 -0.095 0.33585E+04 76 clinozoisite 22.81 18.95 -3.86 -0.175 0.65868E+04 77 epidote-Fe 29.84 26.46 -3.38 -0.176 0.57768E+04 78 fayalite 14.05 10.31 -3.73 -0.533 0.63743E+04 79 ferrosilite 11.15 7.16 -3.99 -0.399 0.68202E+04 83 gibbsite 4.08 0.74 -3.34 -0.477 0.57035E+04 84 glaucophane 22.97 20.80 -2.17 -0.059 0.37133E+04 85 glaucophane-Fe 17.28 13.12 -4.15 -0.112 0.70919E+04 86 graphite -3.55 -7.70 -4.15 -1.187 0.70909E+04 87 greenalite 16.14 13.89 -2.25 -0.187 0.38408E+04 90 hematite 12.57 8.99 -3.58 -0.434 0.61111E+04 91 heulandite -5.83 -7.52 -1.69 -0.077 0.28938E+04 95 jadeite 4.22 2.77 -1.44 -0.144 0.24617E+04 97 kalsilite 7.58 3.83 -3.76 -0.537 0.64126E+04 98 kaolinite -1.33 -4.84 -3.50 -0.319 0.59831E+04 101 laumontite 2.88 1.95 -0.93 -0.062 0.15935E+04 102 lawsonite 9.62 8.26 -1.35 -0.090 0.23069E+04 103 leucite 4.12 0.67 -3.45 -0.345 0.58873E+04 105 lizardite 23.24 21.57 -1.68 -0.140 0.28618E+04 107 magnetite 20.09 15.72 -4.37 -0.356 0.74536E+04 108 minnesotaite 10.39 7.58 -2.81 -0.165 0.48028E+04 112 manganosite 14.06 9.24 -4.82 -1.204 0.82249E+04 120 muscovite 2.58 -1.01 -3.59 -0.211 0.61314E+04 121 paragonite 4.24 1.09 -3.15 -0.185 0.53705E+04 122 nepheline 8.34 5.93 -2.41 -0.344 0.41125E+04 128 periclase-Fe 11.63 6.73 -4.89 -1.223 0.83523E+04 134 phlogopite-Na 29.65 27.50 -2.15 -0.119 0.36677E+04 136 prehnite 19.37 18.21 -1.16 -0.068 0.19849E+04 137 prehnite-Fe 22.50 21.96 -0.53 -0.032 0.91157E+03 138 pumpellyite-Fe 46.27 43.89 -2.38 -0.053 0.40580E+04 139 pumpellyite-Mg 48.99 46.45 -2.54 -0.057 0.43418E+04 143 pyrrhotite -4.26 -7.90 -3.64 -1.214 0.62194E+04 144 pyrrhotiteFe0.875 -6.02 -9.30 -3.28 -1.208 0.56066E+04 145 pyroxmangite 7.40 6.08 -1.31 -0.263 0.22453E+04 146 pyrophyllite -6.18 -11.15 -4.98 -0.311 0.84961E+04 147 quartz -2.99 -3.16 -0.17 -0.056 0.28681E+03 152 rhodonite 7.45 6.08 -1.36 -0.272 0.23256E+04 153 sanidine -1.28 -2.49 -1.21 -0.093 0.20677E+04 165 stilpnomelane-Mg 27.44 25.81 -1.63 -0.049 0.27803E+04 171 talc 16.49 15.25 -1.24 -0.073 0.21140E+04 174 tephroite 18.09 15.32 -2.76 -0.394 0.47143E+04 178 tridymite -2.63 -3.16 -0.53 -0.177 0.90679E+03 179 tremolite 47.87 47.42 -0.45 -0.012 0.77495E+03 180 ferroactinolite 38.45 34.62 -3.83 -0.104 0.65449E+04 181 troilite-low -4.41 -7.90 -3.49 -1.164 0.59622E+04 183 vesuvianite 223.47 218.82 -4.65 -0.036 0.79435E+04 187 wairakite 3.95 1.95 -2.00 -0.118 0.34154E+04 188 walstromite 11.51 9.94 -1.56 -0.313 0.26719E+04 189 wollastonite 10.46 9.94 -0.52 -0.103 0.88229E+03 190 pseudo-wollastonite 11.00 9.94 -1.06 -0.211 0.18021E+04 191 zoisite 22.85 18.95 -3.90 -0.177 0.66608E+04 192 akaganeite 7.75 4.49 -3.26 -0.705 0.55681E+04 199 chalcedony -2.80 -3.16 -0.35 -0.118 0.60611E+03 201 montmorillonite-Ca -2.29 -6.17 -3.88 -0.240 0.66180E+04 202 montmorillonite-K -2.24 -6.27 -4.03 -0.247 0.68816E+04 203 montmorillonite-Mg -2.48 -6.79 -4.32 -0.267 0.73678E+04 204 montmorillonite-Na -2.04 -5.57 -3.54 -0.216 0.60365E+04 205 nontronite-Ca 3.21 -0.19 -3.41 -0.221 0.58215E+04 206 nontronite-H 2.53 -2.36 -4.89 -0.328 0.83485E+04 207 nontronite-K 3.34 -0.30 -3.64 -0.233 0.62083E+04 208 nontronite-Mg 3.07 -0.82 -3.90 -0.253 0.66553E+04 209 nontronite-Na 3.52 0.40 -3.12 -0.200 0.53292E+04 224 tobermorite 9.82 7.76 -2.07 -0.564 0.35287E+04 230 alabandite -0.98 -5.40 -4.42 -1.473 0.75450E+04 233 boehmite 4.41 0.74 -3.67 -0.611 0.62619E+04 235 ferrous-oxide 9.81 6.73 -3.08 -0.769 0.52532E+04 240 silica-amorphous -2.09 -3.16 -1.07 -0.355 0.18203E+04 242 an20ab80 2.02 1.35 -0.67 -0.052 0.11472E+04 243 an25ab75 2.65 1.78 -0.87 -0.067 0.14810E+04 244 an30ab70 3.28 2.21 -1.07 -0.082 0.18244E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 100.0000000 g Current total amount of reactant added: 3099.9990000 g New total amount of reactant added: 3199.9990000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.5221E-10 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 11 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 3199.9990000 Water: Moles liquid = 0.3758E+02 kg liquid = 0.6771E+00 Moles total = 0.1539E+02 kg total = 0.2773E+00 Activity = 1.0000 Stoichiometric ionic strength = .1137215E-01 Osmotic coef. = 0.9689 True ionic strength = .2005057E-01 Chg. balance for total moles = 0.5221E-10 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.88434E-10 -10.0534 0.74299E-10 -10.1290 0.84017E+00 -0.0756 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.20284E-03 -3.6928 0.16939E-03 -3.7711 0.83511E+00 -0.0783 4 SO4-- 0.95527E-12 -12.0199 0.49587E-12 -12.3046 0.51909E+00 -0.2848 5 HCO3- 0.35346E-06 -6.4517 0.29561E-06 -6.5293 0.83633E+00 -0.0776 6 HS- 0.37660E-04 -4.4241 0.31455E-04 -4.5023 0.83523E+00 -0.0782 7 Al+++ 0.97428E-29 -29.0113 0.22487E-29 -29.6481 0.23081E+00 -0.6367 8 H4SiO4 0.69597E-03 -3.1574 0.69597E-03 -3.1574 0.10000E+01 0.0000 9 Ca++ 0.13545E-06 -6.8682 0.69791E-07 -7.1562 0.51527E+00 -0.2880 10 Mg++ 0.21190E-10 -10.6739 0.10868E-10 -10.9638 0.51291E+00 -0.2900 11 Fe++ 0.58402E-13 -13.2336 0.29988E-13 -13.5231 0.51348E+00 -0.2895 12 K+ 0.15676E-03 -3.8048 0.13114E-03 -3.8823 0.83653E+00 -0.0775 13 Na+ 0.19893E-01 -1.7013 0.16609E-01 -1.7796 0.83496E+00 -0.0783 14 Mn++ 0.18716E-10 -10.7278 0.96184E-11 -11.0169 0.51390E+00 -0.2891 15 HPO4-- 0.45204E-07 -7.3448 0.23468E-07 -7.6295 0.51916E+00 -0.2847 16 HSiO3- 0.10473E-01 -1.9799 0.87465E-02 -2.0582 0.83511E+00 -0.0783 17 Ca(HSiO3)+ 0.16615E-07 -7.7795 0.13902E-07 -7.8569 0.83671E+00 -0.0774 18 Mg(HSiO3)+ 0.32200E-11 -11.4921 0.26942E-11 -11.5696 0.83671E+00 -0.0774 19 NaHSiO3,aq 0.23496E-02 -2.6290 0.23496E-02 -2.6290 0.10000E+01 0.0000 20 AlO+ 0.66233E-16 -16.1789 0.55417E-16 -16.2564 0.83671E+00 -0.0774 22 HAlO2,aq 0.14854E-09 -9.8282 0.14854E-09 -9.8282 0.10000E+01 0.0000 23 AlO2- 0.53088E-05 -5.2750 0.44254E-05 -5.3540 0.83360E+00 -0.0790 24 CH4,aq 0.18278E-04 -4.7381 0.18215E-04 -4.7396 0.99653E+00 -0.0015 25 C2H6,aq 0.49138E-14 -14.3086 0.48968E-14 -14.3101 0.99653E+00 -0.0015 29 CO,aq 0.13655E-16 -16.8647 0.13655E-16 -16.8647 0.10000E+01 0.0000 30 CO2,aq 0.47094E-10 -10.3270 0.46931E-10 -10.3285 0.99653E+00 -0.0015 31 CO3-2 0.67090E-06 -6.1733 0.34752E-06 -6.4590 0.51799E+00 -0.2857 32 CaCO3,aq 0.30411E-09 -9.5170 0.30411E-09 -9.5170 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.62940E-12 -12.2011 0.52663E-12 -12.2785 0.83671E+00 -0.0774 34 CaCl+ 0.22866E-10 -10.6408 0.19132E-10 -10.7182 0.83671E+00 -0.0774 35 CaCl2,aq 0.76994E-15 -15.1135 0.76994E-15 -15.1135 0.10000E+01 0.0000 36 CaOH+ 0.80010E-07 -7.0969 0.66946E-07 -7.1743 0.83671E+00 -0.0774 37 CaSO4,aq 0.10989E-16 -16.9590 0.10989E-16 -16.9590 0.10000E+01 0.0000 38 HCl,aq 0.23063E-14 -14.6371 0.23063E-14 -14.6371 0.10000E+01 0.0000 43 FeCl+ 0.96095E-17 -17.0173 0.80403E-17 -17.0947 0.83671E+00 -0.0774 46 FeO,aq 0.21113E-09 -9.6755 0.21113E-09 -9.6755 0.10000E+01 0.0000 47 FeOH+ 0.15702E-10 -10.8040 0.13138E-10 -10.8815 0.83671E+00 -0.0774 48 HFeO2- 0.35602E-07 -7.4485 0.29732E-07 -7.5268 0.83511E+00 -0.0783 49 FeO+ 0.11004E-16 -16.9584 0.92075E-17 -17.0359 0.83671E+00 -0.0774 51 FeO2- 0.40868E-09 -9.3886 0.34129E-09 -9.4669 0.83511E+00 -0.0783 52 HFeO2,aq 0.32251E-11 -11.4915 0.32251E-11 -11.4915 0.10000E+01 0.0000 53 H2,aq 0.11623E-04 -4.9347 0.11583E-04 -4.9362 0.99653E+00 -0.0015 54 KCl,aq 0.40261E-09 -9.3951 0.40261E-09 -9.3951 0.10000E+01 0.0000 56 KOH,aq 0.75375E-06 -6.1228 0.75375E-06 -6.1228 0.10000E+01 0.0000 57 KSO4- 0.12083E-14 -14.9178 0.10091E-14 -14.9961 0.83511E+00 -0.0783 58 MgCO3,aq 0.11871E-13 -13.9255 0.11871E-13 -13.9255 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.10015E-15 -15.9993 0.83799E-16 -16.0768 0.83671E+00 -0.0774 60 MgCl+ 0.32273E-14 -14.4912 0.27003E-14 -14.5686 0.83671E+00 -0.0774 61 MgOH+ 0.68946E-10 -10.1615 0.57688E-10 -10.2389 0.83671E+00 -0.0774 63 MnO,aq 0.18044E-08 -8.7437 0.18044E-08 -8.7437 0.10000E+01 0.0000 64 MnOH+ 0.46785E-09 -9.3299 0.39146E-09 -9.4073 0.83671E+00 -0.0774 65 MnO2-2 0.20942E-10 -10.6790 0.10848E-10 -10.9647 0.51799E+00 -0.2857 66 HMnO2- 0.21144E-09 -9.6748 0.17657E-09 -9.7531 0.83511E+00 -0.0783 69 MnCl+ 0.11991E-13 -13.9211 0.10033E-13 -13.9986 0.83671E+00 -0.0774 71 NaCl,aq 0.93240E-06 -6.0304 0.93240E-06 -6.0304 0.10000E+01 0.0000 72 NaOH,aq 0.96047E-04 -4.0175 0.96047E-04 -4.0175 0.10000E+01 0.0000 74 OH- 0.93286E-02 -2.0302 0.77763E-02 -2.1092 0.83360E+00 -0.0790 79 HPO3-2 0.16354E-14 -14.7864 0.84711E-15 -15.0721 0.51799E+00 -0.2857 81 H2PO3- 0.15113E-18 -18.8206 0.12621E-18 -18.8989 0.83511E+00 -0.0783 82 H3PO4,aq 0.90609E-18 -18.0428 0.90609E-18 -18.0428 0.10000E+01 0.0000 83 H2PO4- 0.38480E-10 -10.4148 0.32166E-10 -10.4926 0.83590E+00 -0.0778 84 PO4-3 0.10630E-08 -8.9735 0.25771E-09 -9.5889 0.24243E+00 -0.6154 88 HP2O7-3 0.94366E-18 -18.0252 0.21802E-18 -18.6615 0.23104E+00 -0.6363 89 P2O7-4 0.91067E-17 -17.0406 0.70102E-18 -18.1543 0.76979E-01 -1.1136 90 H2S,aq 0.72481E-08 -8.1398 0.72230E-08 -8.1413 0.99653E+00 -0.0015 91 S2-2 0.36540E-14 -14.4372 0.18927E-14 -14.7229 0.51799E+00 -0.2857 97 SO3-2 0.14204E-17 -17.8476 0.74638E-18 -18.1270 0.52549E+00 -0.2794 99 HSO4- 0.42394E-19 -19.3727 0.35506E-19 -19.4497 0.83753E+00 -0.0770 Charge balance for all species = 0.7708E-10 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.8843384E-10 -.2227351E-01 -.2241131E+02 0.0000 2 H2O 0.1000000E+01 0.5550489E+02 0.9981980E+06 0.0000 3 Cl- 0.2028386E-03 0.2037715E-03 0.7211744E+01 6.3579 4 SO4-- 0.9552683E-12 -.2118387E-04 -.2031417E+01 7.9534 5 HCO3- 0.3534582E-06 0.1930284E-04 0.1175756E+01 3.5997 6 HS- 0.3765982E-04 0.5885094E-04 0.1942933E+01 5.6267 7 Al+++ 0.9742800E-29 0.5308915E-05 0.1429933E+00 0.7390 8 H4SiO4 0.6959711E-03 0.1351908E-01 0.1297132E+04 -3.1574 9 Ca++ 0.1354453E-06 0.2323982E-06 0.9297852E-02 13.1018 10 Mg++ 0.2118958E-10 0.9337120E-10 0.2266092E-05 9.2942 11 Fe++ 0.5840170E-13 0.3624101E-07 0.2020431E-02 6.7350 12 K+ 0.1567638E-03 0.1575179E-03 0.6148553E+01 6.2467 13 Na+ 0.1989258E-01 0.2233917E-01 0.5126798E+03 8.3494 14 Mn++ 0.1871648E-10 0.2523350E-08 0.1383867E-03 9.2411 15 HPO4-- 0.4520383E-07 0.4630532E-07 0.4436607E-02 12.6285 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.5298722E+02 -.1508145E-01 -.5297214E+02 0.0000000E+00 2 H2O 0.1539495E+02 0.3758250E+02 -.2218755E+02 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.8870839E-01 -.1434365E-04 0.8872273E-01 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.8868288E-01 0.3984812E-04 -.8872273E-01 0.0000000E+00 7 Al+++ 0.1043437E+02 0.3594679E-05 0.1043437E+02 0.0000000E+00 8 H4SiO4 0.3332090E+02 0.9153803E-02 0.3331174E+02 0.0000000E+00 9 Ca++ 0.3680470E+01 0.1573574E-06 0.3680470E+01 0.0000000E+00 10 Mg++ 0.2539682E+01 0.6322187E-10 0.2539682E+01 0.0000000E+00 11 Fe++ 0.2281627E+01 0.2453888E-07 0.2281627E+01 0.0000000E+00 12 K+ 0.6794053E+00 0.1066558E-03 0.6792987E+00 0.0000000E+00 13 Na+ 0.4016938E+01 0.1512591E-01 0.4001813E+01 0.0000000E+00 14 Mn++ 0.5548349E-01 0.1708567E-08 0.5548349E-01 0.0000000E+00 15 HPO4-- 0.1893624E-01 0.3135345E-07 0.1893621E-01 0.0000000E+00 Chg. balance for solid moles: 0.5405E-14 Mass of aqueous solution: 0.678282E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 3199.9990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 3.998 0.602 1048. 3.021 29.99 402.5 andradite 0.3549 -0.450 180.3 2.256 5.159 46.86 grossular 0.8594E-01 -1.066 38.71 1.588 1.107 10.77 apatite-OH 0.6312E-02 -2.200 3.171 0.501 0.9070E-01 1.008 clinochlore 0.4551 -0.342 252.9 2.403 7.235 96.21 daphnite 0.1317 -0.880 93.99 1.973 2.689 28.48 chlorite-Mn 0.1110E-01 -1.955 7.867 0.896 0.2250 2.507 diopside 0.1648 -0.783 35.69 1.553 1.021 10.91 hedenbergite 0.4274E-01 -1.369 10.60 1.025 0.3033 2.904 microcline 0.5957 -0.225 165.8 2.220 4.743 64.77 stilbite 2.064 0.315 1455. 3.163 41.61 678.4 stilpnomelane-Fe 0.1672 -0.777 180.3 2.256 5.156 62.27 tr.625ac.25prg.125 0.2747E-01 -1.561 23.48 1.371 0.6718 7.558 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8051E+00 0.8051E+00 1.0000 -0.094 grossular 0.1949E+00 0.1949E+00 1.0000 -0.710 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.7611E+00 0.7611E+00 1.0000 -0.119 daphnite 0.2203E+00 0.2203E+00 1.0000 -0.657 chlorite-Mn 0.1856E-01 0.1856E-01 1.0000 -1.731 diopside 0.7941E+00 0.7941E+00 1.0000 -0.100 hedenbergite 0.2059E+00 0.2059E+00 1.0000 -0.686 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 tr.625ac.25prg.125 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 3495.825898 g Volume = 1415.122703 cm3 Porosity: -10.4702% V(tot) - V(min): -.13412E+03 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 3199.9990000 g log = 3.5051 Original solution: 1000.0103000 g Original solution / Rock added: 0.31 (Water/Rock Ratio), log = -0.5051 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0626 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9608E+00 0.9854 0.1006E+01 0.1021E+01 CO2,gas 0.4693E-08 1.0068 0.5021E-08 0.4987E-08 CH4,gas 0.2492E-01 1.0124 0.2681E-01 0.2648E-01 H2,gas 0.1430E-01 1.0006 0.1521E-01 0.1520E-01 H2S,gas 0.1876E-06 0.9959 0.1986E-06 0.1994E-06 S2,gas 0.6022E-29 1.0000 0.6399E-29 0.6399E-29 CO,gas 0.1915E-13 1.0000 0.2035E-13 0.2035E-13 SO3,gas 0.9741E-48 1.0000 0.1035E-47 0.1035E-47 SO2,gas 0.5763E-27 1.0000 0.6123E-27 0.6123E-27 HCl,gas 0.3830E-17 1.0000 0.4069E-17 0.4069E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 16 albite -0.38 -0.38 0.00 0.000 -0.94784E-12 22 andradite 39.01 39.01 0.00 0.000 0.00000E+00 23 grossular 32.73 32.73 0.00 0.000 0.36397E-10 32 apatite-OH -18.15 -18.15 0.00 0.000 0.00000E+00 46 clinochlore 39.07 39.07 0.00 0.000 0.00000E+00 47 daphnite 28.97 28.97 0.00 0.000 0.12132E-10 48 chlorite-Mn 46.87 46.87 0.00 0.000 0.00000E+00 67 diopside 16.18 16.18 0.00 0.000 0.12132E-10 68 hedenbergite 14.21 14.21 0.00 0.000 0.90992E-11 116 microcline -2.49 -2.49 0.00 0.000 0.15165E-11 163 stilbite -7.52 -7.52 0.00 0.000 -0.90992E-11 164 stilpnomelane-Fe 13.02 13.02 0.00 0.000 -0.75827E-10 245 tr.625ac.25prg.125 45.16 45.16 0.00 0.000 0.72794E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -16.66 -10.00 -3.333 0.17072E+05 -8.299 3 CH4,gas 4.54 1.27 -3.27 -0.818 0.55846E+04 -1.572 4 H2,gas 8.00 4.48 -3.52 -2.010 0.60051E+04 -1.818 5 H2S,gas -6.23 -14.63 -8.40 -4.201 0.14345E+05 -6.702 6 S2,gas -7.34 -38.23 -30.89 -4.753 0.52749E+05 -29.194 7 CO,gas 3.21 -12.18 -15.39 -4.736 0.26279E+05 -13.691 8 SO3,gas 17.12 -32.56 -49.68 -12.421 0.84834E+05 -47.985 9 SO2,gas 0.83 -28.08 -28.91 -7.710 0.49366E+05 -27.213 10 HCl,gas 5.19 -13.90 -19.09 -9.545 0.32595E+05 -17.390 11 acmite 7.71 6.53 -1.18 -0.123 0.20175E+04 15 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 19 spessartine 24.46 19.73 -4.73 -0.236 0.80732E+04 20 analcite 3.32 2.77 -0.55 -0.061 0.93624E+03 26 annite 20.12 17.72 -2.40 -0.134 0.41064E+04 27 phlogopite 27.06 25.40 -1.67 -0.093 0.28489E+04 29 anorthite 12.71 8.26 -4.45 -0.342 0.75903E+04 35 aragonite 0.97 -3.56 -4.52 -1.508 0.77229E+04 36 brucite 12.57 9.29 -3.27 -0.655 0.55909E+04 37 calcite 0.81 -3.56 -4.37 -1.456 0.74587E+04 38 carnegieite-low 9.02 5.93 -3.09 -0.442 0.52801E+04 39 carnegieite-high 10.09 5.93 -4.16 -0.595 0.71071E+04 40 carpholite-Mg 8.58 4.46 -4.12 -0.275 0.70429E+04 41 carpholite-Fe 6.71 1.90 -4.81 -0.321 0.82206E+04 42 celadonite 5.34 3.65 -1.69 -0.099 0.28879E+04 43 celadonite-Fe 3.88 1.09 -2.79 -0.164 0.47561E+04 44 chrysotile 23.89 21.57 -2.32 -0.194 0.39692E+04 49 chlorite-Al-free 47.17 43.14 -4.04 -0.168 0.68936E+04 51 chloritoid-Fe 9.17 5.06 -4.12 -0.275 0.70315E+04 52 chloritoid-Mn 11.40 7.56 -3.84 -0.256 0.65556E+04 54 coesite -2.38 -3.16 -0.78 -0.260 0.13341E+04 61 cristobalite -2.56 -3.16 -0.60 -0.199 0.10195E+04 63 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71234E+04 65 diaspore 2.87 0.74 -2.13 -0.356 0.36450E+04 66 diamond -3.10 -7.69 -4.59 -1.311 0.78377E+04 71 enstatite 17.26 12.27 -4.99 -0.499 0.85226E+04 73 clinoenstatite 17.17 12.27 -4.89 -0.489 0.83541E+04 75 epidote 24.67 22.70 -1.97 -0.095 0.33585E+04 76 clinozoisite 22.81 18.95 -3.86 -0.175 0.65868E+04 77 epidote-Fe 29.84 26.46 -3.38 -0.176 0.57768E+04 78 fayalite 14.05 10.31 -3.73 -0.533 0.63743E+04 79 ferrosilite 11.15 7.16 -3.99 -0.399 0.68202E+04 83 gibbsite 4.08 0.74 -3.34 -0.477 0.57035E+04 84 glaucophane 22.97 20.80 -2.17 -0.059 0.37133E+04 85 glaucophane-Fe 17.28 13.12 -4.15 -0.112 0.70919E+04 86 graphite -3.55 -7.69 -4.15 -1.185 0.70800E+04 87 greenalite 16.14 13.89 -2.25 -0.187 0.38408E+04 90 hematite 12.57 8.99 -3.58 -0.434 0.61111E+04 91 heulandite -5.83 -7.52 -1.69 -0.077 0.28938E+04 95 jadeite 4.22 2.77 -1.44 -0.144 0.24617E+04 97 kalsilite 7.58 3.83 -3.76 -0.537 0.64126E+04 98 kaolinite -1.33 -4.84 -3.50 -0.319 0.59831E+04 101 laumontite 2.88 1.95 -0.93 -0.062 0.15935E+04 102 lawsonite 9.62 8.26 -1.35 -0.090 0.23069E+04 103 leucite 4.12 0.67 -3.45 -0.345 0.58873E+04 105 lizardite 23.24 21.57 -1.68 -0.140 0.28618E+04 107 magnetite 20.09 15.72 -4.37 -0.356 0.74536E+04 108 minnesotaite 10.39 7.58 -2.81 -0.165 0.48028E+04 112 manganosite 14.06 9.24 -4.82 -1.204 0.82249E+04 120 muscovite 2.58 -1.01 -3.59 -0.211 0.61315E+04 121 paragonite 4.24 1.09 -3.15 -0.185 0.53706E+04 122 nepheline 8.34 5.93 -2.41 -0.344 0.41125E+04 128 periclase-Fe 11.63 6.73 -4.89 -1.223 0.83523E+04 134 phlogopite-Na 29.65 27.50 -2.15 -0.119 0.36677E+04 136 prehnite 19.37 18.21 -1.16 -0.068 0.19849E+04 137 prehnite-Fe 22.50 21.96 -0.53 -0.032 0.91157E+03 138 pumpellyite-Fe 46.27 43.89 -2.38 -0.053 0.40580E+04 139 pumpellyite-Mg 48.99 46.45 -2.54 -0.057 0.43419E+04 143 pyrrhotite -4.26 -7.90 -3.64 -1.212 0.62084E+04 144 pyrrhotiteFe0.875 -6.02 -9.29 -3.28 -1.205 0.55956E+04 145 pyroxmangite 7.40 6.08 -1.31 -0.263 0.22452E+04 146 pyrophyllite -6.18 -11.15 -4.98 -0.311 0.84961E+04 147 quartz -2.99 -3.16 -0.17 -0.056 0.28681E+03 152 rhodonite 7.45 6.08 -1.36 -0.272 0.23255E+04 153 sanidine -1.28 -2.49 -1.21 -0.093 0.20677E+04 165 stilpnomelane-Mg 27.44 25.81 -1.63 -0.049 0.27803E+04 171 talc 16.49 15.25 -1.24 -0.073 0.21140E+04 174 tephroite 18.09 15.32 -2.76 -0.394 0.47142E+04 178 tridymite -2.63 -3.16 -0.53 -0.177 0.90679E+03 179 tremolite 47.87 47.42 -0.45 -0.012 0.77495E+03 180 ferroactinolite 38.45 34.62 -3.83 -0.104 0.65449E+04 181 troilite-low -4.41 -7.90 -3.49 -1.162 0.59512E+04 183 vesuvianite 223.47 218.82 -4.65 -0.036 0.79435E+04 187 wairakite 3.95 1.95 -2.00 -0.118 0.34154E+04 188 walstromite 11.51 9.94 -1.56 -0.313 0.26719E+04 189 wollastonite 10.46 9.94 -0.52 -0.103 0.88229E+03 190 pseudo-wollastonite 11.00 9.94 -1.06 -0.211 0.18021E+04 191 zoisite 22.85 18.95 -3.90 -0.177 0.66608E+04 192 akaganeite 7.75 4.49 -3.26 -0.705 0.55681E+04 199 chalcedony -2.80 -3.16 -0.35 -0.118 0.60611E+03 201 montmorillonite-Ca -2.29 -6.17 -3.88 -0.240 0.66180E+04 202 montmorillonite-K -2.24 -6.27 -4.03 -0.247 0.68816E+04 203 montmorillonite-Mg -2.48 -6.79 -4.32 -0.267 0.73678E+04 204 montmorillonite-Na -2.04 -5.57 -3.54 -0.216 0.60365E+04 205 nontronite-Ca 3.21 -0.19 -3.41 -0.221 0.58215E+04 206 nontronite-H 2.53 -2.36 -4.89 -0.328 0.83485E+04 207 nontronite-K 3.34 -0.30 -3.64 -0.233 0.62083E+04 208 nontronite-Mg 3.07 -0.82 -3.90 -0.253 0.66553E+04 209 nontronite-Na 3.52 0.40 -3.12 -0.200 0.53292E+04 224 tobermorite 9.82 7.76 -2.07 -0.564 0.35287E+04 230 alabandite -0.98 -5.39 -4.41 -1.471 0.75339E+04 233 boehmite 4.41 0.74 -3.67 -0.611 0.62619E+04 235 ferrous-oxide 9.81 6.73 -3.08 -0.769 0.52532E+04 240 silica-amorphous -2.09 -3.16 -1.07 -0.355 0.18203E+04 242 an20ab80 2.02 1.35 -0.67 -0.052 0.11472E+04 243 an25ab75 2.65 1.78 -0.87 -0.067 0.14810E+04 244 an30ab70 3.28 2.21 -1.07 -0.082 0.18244E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 100.0000000 g Current total amount of reactant added: 3199.9990000 g New total amount of reactant added: 3299.9990000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.5222E-10 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 11 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 3299.9990000 Water: Moles liquid = 0.3703E+02 kg liquid = 0.6671E+00 Moles total = 0.1414E+02 kg total = 0.2548E+00 Activity = 1.0000 Stoichiometric ionic strength = .1137469E-01 Osmotic coef. = 0.9689 True ionic strength = .2005255E-01 Chg. balance for total moles = 0.5222E-10 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.88443E-10 -10.0533 0.74306E-10 -10.1290 0.84016E+00 -0.0756 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.20589E-03 -3.6864 0.17194E-03 -3.7646 0.83510E+00 -0.0783 4 SO4-- 0.96959E-12 -12.0134 0.50329E-12 -12.2982 0.51908E+00 -0.2848 5 HCO3- 0.35875E-06 -6.4452 0.30004E-06 -6.5228 0.83633E+00 -0.0776 6 HS- 0.38227E-04 -4.4176 0.31928E-04 -4.4958 0.83523E+00 -0.0782 7 Al+++ 0.97460E-29 -29.0112 0.22493E-29 -29.6479 0.23080E+00 -0.6368 8 H4SiO4 0.69597E-03 -3.1574 0.69597E-03 -3.1574 0.10000E+01 0.0000 9 Ca++ 0.13547E-06 -6.8681 0.69804E-07 -7.1561 0.51526E+00 -0.2880 10 Mg++ 0.21194E-10 -10.6738 0.10870E-10 -10.9638 0.51290E+00 -0.2900 11 Fe++ 0.58414E-13 -13.2335 0.29993E-13 -13.5230 0.51346E+00 -0.2895 12 K+ 0.15678E-03 -3.8047 0.13115E-03 -3.8822 0.83652E+00 -0.0775 13 Na+ 0.19895E-01 -1.7013 0.16611E-01 -1.7796 0.83495E+00 -0.0783 14 Mn++ 0.18722E-10 -10.7276 0.96210E-11 -11.0168 0.51389E+00 -0.2891 15 HPO4-- 0.45197E-07 -7.3449 0.23464E-07 -7.6296 0.51915E+00 -0.2847 16 HSiO3- 0.10473E-01 -1.9799 0.87457E-02 -2.0582 0.83510E+00 -0.0783 17 Ca(HSiO3)+ 0.16616E-07 -7.7795 0.13903E-07 -7.8569 0.83670E+00 -0.0774 18 Mg(HSiO3)+ 0.32204E-11 -11.4921 0.26945E-11 -11.5695 0.83670E+00 -0.0774 19 NaHSiO3,aq 0.23496E-02 -2.6290 0.23496E-02 -2.6290 0.10000E+01 0.0000 20 AlO+ 0.66239E-16 -16.1789 0.55422E-16 -16.2563 0.83670E+00 -0.0774 22 HAlO2,aq 0.14854E-09 -9.8282 0.14854E-09 -9.8282 0.10000E+01 0.0000 23 AlO2- 0.53083E-05 -5.2750 0.44250E-05 -5.3541 0.83359E+00 -0.0790 24 CH4,aq 0.18553E-04 -4.7316 0.18489E-04 -4.7331 0.99653E+00 -0.0015 25 C2H6,aq 0.50630E-14 -14.2956 0.50454E-14 -14.2971 0.99653E+00 -0.0015 29 CO,aq 0.13861E-16 -16.8582 0.13861E-16 -16.8582 0.10000E+01 0.0000 30 CO2,aq 0.47804E-10 -10.3205 0.47638E-10 -10.3220 0.99653E+00 -0.0015 31 CO3-2 0.68090E-06 -6.1669 0.35269E-06 -6.4526 0.51797E+00 -0.2857 32 CaCO3,aq 0.30870E-09 -9.5105 0.30870E-09 -9.5105 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.63895E-12 -12.1945 0.53461E-12 -12.2720 0.83670E+00 -0.0774 34 CaCl+ 0.23214E-10 -10.6342 0.19423E-10 -10.7117 0.83670E+00 -0.0774 35 CaCl2,aq 0.79344E-15 -15.1005 0.79344E-15 -15.1005 0.10000E+01 0.0000 36 CaOH+ 0.80018E-07 -7.0968 0.66952E-07 -7.1742 0.83670E+00 -0.0774 37 CaSO4,aq 0.11156E-16 -16.9525 0.11156E-16 -16.9525 0.10000E+01 0.0000 38 HCl,aq 0.23412E-14 -14.6306 0.23412E-14 -14.6306 0.10000E+01 0.0000 43 FeCl+ 0.97559E-17 -17.0107 0.81628E-17 -17.0882 0.83670E+00 -0.0774 46 FeO,aq 0.21113E-09 -9.6755 0.21113E-09 -9.6755 0.10000E+01 0.0000 47 FeOH+ 0.15703E-10 -10.8040 0.13139E-10 -10.8814 0.83670E+00 -0.0774 48 HFeO2- 0.35599E-07 -7.4486 0.29729E-07 -7.5268 0.83510E+00 -0.0783 49 FeO+ 0.11006E-16 -16.9584 0.92084E-17 -17.0358 0.83670E+00 -0.0774 51 FeO2- 0.40864E-09 -9.3887 0.34126E-09 -9.4669 0.83510E+00 -0.0783 52 HFeO2,aq 0.32251E-11 -11.4915 0.32251E-11 -11.4915 0.10000E+01 0.0000 53 H2,aq 0.11623E-04 -4.9347 0.11583E-04 -4.9362 0.99653E+00 -0.0015 54 KCl,aq 0.40870E-09 -9.3886 0.40870E-09 -9.3886 0.10000E+01 0.0000 56 KOH,aq 0.75375E-06 -6.1228 0.75375E-06 -6.1228 0.10000E+01 0.0000 57 KSO4- 0.12265E-14 -14.9113 0.10243E-14 -14.9896 0.83510E+00 -0.0783 58 MgCO3,aq 0.12050E-13 -13.9190 0.12050E-13 -13.9190 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.10167E-15 -15.9928 0.85070E-16 -16.0702 0.83670E+00 -0.0774 60 MgCl+ 0.32765E-14 -14.4846 0.27415E-14 -14.5620 0.83670E+00 -0.0774 61 MgOH+ 0.68953E-10 -10.1614 0.57693E-10 -10.2389 0.83670E+00 -0.0774 63 MnO,aq 0.18045E-08 -8.7436 0.18045E-08 -8.7436 0.10000E+01 0.0000 64 MnOH+ 0.46794E-09 -9.3298 0.39153E-09 -9.4072 0.83670E+00 -0.0774 65 MnO2-2 0.20940E-10 -10.6790 0.10846E-10 -10.9647 0.51797E+00 -0.2857 66 HMnO2- 0.21144E-09 -9.6748 0.17657E-09 -9.7531 0.83510E+00 -0.0783 69 MnCl+ 0.12175E-13 -13.9145 0.10187E-13 -13.9920 0.83670E+00 -0.0774 71 NaCl,aq 0.94652E-06 -6.0239 0.94652E-06 -6.0239 0.10000E+01 0.0000 72 NaOH,aq 0.96047E-04 -4.0175 0.96047E-04 -4.0175 0.10000E+01 0.0000 74 OH- 0.93278E-02 -2.0302 0.77756E-02 -2.1093 0.83359E+00 -0.0790 79 HPO3-2 0.16351E-14 -14.7864 0.84695E-15 -15.0721 0.51797E+00 -0.2857 81 H2PO3- 0.15112E-18 -18.8207 0.12620E-18 -18.8989 0.83510E+00 -0.0783 82 H3PO4,aq 0.90609E-18 -18.0428 0.90609E-18 -18.0428 0.10000E+01 0.0000 83 H2PO4- 0.38477E-10 -10.4148 0.32163E-10 -10.4926 0.83590E+00 -0.0778 84 PO4-3 0.10628E-08 -8.9736 0.25764E-09 -9.5890 0.24242E+00 -0.6154 88 HP2O7-3 0.94346E-18 -18.0253 0.21797E-18 -18.6616 0.23103E+00 -0.6363 89 P2O7-4 0.91043E-17 -17.0408 0.70077E-18 -18.1544 0.76971E-01 -1.1137 90 H2S,aq 0.73578E-08 -8.1332 0.73323E-08 -8.1348 0.99653E+00 -0.0015 91 S2-2 0.37649E-14 -14.4242 0.19501E-14 -14.7099 0.51797E+00 -0.2857 97 SO3-2 0.14416E-17 -17.8411 0.75754E-18 -18.1206 0.52547E+00 -0.2794 99 HSO4- 0.43032E-19 -19.3662 0.36041E-19 -19.4432 0.83752E+00 -0.0770 Charge balance for all species = 0.7828E-10 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.8844250E-10 -.2227185E-01 -.2240963E+02 0.0000 2 H2O 0.1000000E+01 0.5550489E+02 0.9981979E+06 0.0000 3 Cl- 0.2058923E-03 0.2068393E-03 0.7320317E+01 6.3644 4 SO4-- 0.9695887E-12 -.2145917E-04 -.2057816E+01 7.9598 5 HCO3- 0.3587544E-06 0.1959344E-04 0.1193457E+01 3.6061 6 HS- 0.3822680E-04 0.5969332E-04 0.1970743E+01 5.6331 7 Al+++ 0.9746029E-29 0.5308448E-05 0.1429807E+00 0.7390 8 H4SiO4 0.6959717E-03 0.1351820E-01 0.1297047E+04 -3.1574 9 Ca++ 0.1354736E-06 0.2324408E-06 0.9299557E-02 13.1018 10 Mg++ 0.2119402E-10 0.9338218E-10 0.2266358E-05 9.2942 11 Fe++ 0.5841395E-13 0.3623793E-07 0.2020259E-02 6.7350 12 K+ 0.1567792E-03 0.1575334E-03 0.6149154E+01 6.2467 13 Na+ 0.1989454E-01 0.2234114E-01 0.5127250E+03 8.3494 14 Mn++ 0.1872198E-10 0.2523590E-08 0.1383998E-03 9.2412 15 HPO4-- 0.4519678E-07 0.4629803E-07 0.4435909E-02 12.6284 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.5464307E+02 -.1485665E-01 -.5462821E+02 0.0000000E+00 2 H2O 0.1414141E+02 0.3702509E+02 -.2288368E+02 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.9147973E-01 -.1431455E-04 0.9149404E-01 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.9145422E-01 0.3981902E-04 -.9149404E-01 0.0000000E+00 7 Al+++ 0.1076044E+02 0.3541052E-05 0.1076044E+02 0.0000000E+00 8 H4SiO4 0.3436217E+02 0.9017450E-02 0.3435316E+02 0.0000000E+00 9 Ca++ 0.3795484E+01 0.1550519E-06 0.3795484E+01 0.0000000E+00 10 Mg++ 0.2619047E+01 0.6229151E-10 0.2619047E+01 0.0000000E+00 11 Fe++ 0.2352928E+01 0.2417287E-07 0.2352928E+01 0.0000000E+00 12 K+ 0.7006367E+00 0.1050842E-03 0.7005316E+00 0.0000000E+00 13 Na+ 0.4142463E+01 0.1490288E-01 0.4127560E+01 0.0000000E+00 14 Mn++ 0.5721735E-01 0.1683386E-08 0.5721735E-01 0.0000000E+00 15 HPO4-- 0.1952800E-01 0.3088356E-07 0.1952797E-01 0.0000000E+00 Chg. balance for solid moles: -.8625E-14 Mass of aqueous solution: 0.668222E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 3299.9990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 4.124 0.615 1081. 3.034 30.00 415.1 andradite 0.3660 -0.437 186.0 2.269 5.159 48.32 grossular 0.8862E-01 -1.052 39.92 1.601 1.107 11.11 apatite-OH 0.6509E-02 -2.186 3.270 0.515 0.9070E-01 1.039 clinochlore 0.4692 -0.329 260.8 2.416 7.235 99.21 daphnite 0.1358 -0.867 96.92 1.986 2.689 29.37 chlorite-Mn 0.1144E-01 -1.941 8.113 0.909 0.2250 2.585 diopside 0.1702 -0.769 36.86 1.567 1.023 11.27 hedenbergite 0.4415E-01 -1.355 10.95 1.040 0.3038 3.000 microcline 0.6143 -0.212 171.0 2.233 4.743 66.79 stilbite 2.128 0.328 1500. 3.176 41.60 699.5 stilpnomelane-Fe 0.1724 -0.763 185.9 2.269 5.157 64.21 tr.625ac.25prg.125 0.2831E-01 -1.548 24.20 1.384 0.6712 7.788 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8051E+00 0.8051E+00 1.0000 -0.094 grossular 0.1949E+00 0.1949E+00 1.0000 -0.710 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.7611E+00 0.7611E+00 1.0000 -0.119 daphnite 0.2203E+00 0.2203E+00 1.0000 -0.657 chlorite-Mn 0.1856E-01 0.1856E-01 1.0000 -1.731 diopside 0.7941E+00 0.7941E+00 1.0000 -0.100 hedenbergite 0.2059E+00 0.2059E+00 1.0000 -0.686 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 tr.625ac.25prg.125 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 3605.076562 g Volume = 1459.325767 cm3 Porosity: -10.4713% V(tot) - V(min): -.13833E+03 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 3299.9990000 g log = 3.5185 Original solution: 1000.0103000 g Original solution / Rock added: 0.30 (Water/Rock Ratio), log = -0.5185 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0630 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9604E+00 0.9854 0.1006E+01 0.1021E+01 CO2,gas 0.4762E-08 1.0068 0.5097E-08 0.5062E-08 CH4,gas 0.2529E-01 1.0124 0.2721E-01 0.2688E-01 H2,gas 0.1430E-01 1.0006 0.1521E-01 0.1520E-01 H2S,gas 0.1904E-06 0.9959 0.2016E-06 0.2024E-06 S2,gas 0.6204E-29 1.0000 0.6594E-29 0.6594E-29 CO,gas 0.1943E-13 1.0000 0.2066E-13 0.2066E-13 SO3,gas 0.9885E-48 1.0000 0.1051E-47 0.1051E-47 SO2,gas 0.5848E-27 1.0000 0.6216E-27 0.6216E-27 HCl,gas 0.3886E-17 1.0000 0.4131E-17 0.4131E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 16 albite -0.38 -0.38 0.00 0.000 -0.94784E-12 22 andradite 39.01 39.01 0.00 0.000 0.12132E-10 23 grossular 32.73 32.73 0.00 0.000 0.24265E-10 32 apatite-OH -18.15 -18.15 0.00 0.000 0.00000E+00 46 clinochlore 39.07 39.07 0.00 0.000 0.24265E-10 47 daphnite 28.97 28.97 0.00 0.000 0.00000E+00 48 chlorite-Mn 46.87 46.87 0.00 0.000 0.00000E+00 67 diopside 16.18 16.18 0.00 0.000 -0.12132E-10 68 hedenbergite 14.21 14.21 0.00 0.000 -0.30331E-11 116 microcline -2.49 -2.49 0.00 0.000 0.15165E-11 163 stilbite -7.52 -7.52 0.00 0.000 -0.90992E-11 164 stilpnomelane-Fe 13.02 13.02 0.00 0.000 0.21232E-10 245 tr.625ac.25prg.125 45.16 45.16 0.00 0.000 0.00000E+00 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -16.65 -9.99 -3.331 0.17061E+05 -8.293 3 CH4,gas 4.54 1.28 -3.26 -0.816 0.55735E+04 -1.565 4 H2,gas 8.00 4.48 -3.52 -2.010 0.60051E+04 -1.818 5 H2S,gas -6.23 -14.62 -8.39 -4.197 0.14333E+05 -6.696 6 S2,gas -7.34 -38.22 -30.88 -4.751 0.52726E+05 -29.181 7 CO,gas 3.21 -12.17 -15.38 -4.734 0.26268E+05 -13.685 8 SO3,gas 17.12 -32.56 -49.68 -12.419 0.84823E+05 -47.979 9 SO2,gas 0.83 -28.07 -28.91 -7.708 0.49355E+05 -27.206 10 HCl,gas 5.19 -13.89 -19.08 -9.541 0.32584E+05 -17.384 11 acmite 7.71 6.53 -1.18 -0.123 0.20175E+04 15 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 19 spessartine 24.46 19.73 -4.73 -0.236 0.80730E+04 20 analcite 3.32 2.77 -0.55 -0.061 0.93624E+03 26 annite 20.12 17.72 -2.40 -0.134 0.41064E+04 27 phlogopite 27.06 25.40 -1.67 -0.093 0.28489E+04 29 anorthite 12.71 8.26 -4.45 -0.342 0.75903E+04 35 aragonite 0.97 -3.55 -4.52 -1.505 0.77118E+04 36 brucite 12.57 9.29 -3.27 -0.655 0.55909E+04 37 calcite 0.81 -3.55 -4.36 -1.454 0.74476E+04 38 carnegieite-low 9.02 5.93 -3.09 -0.442 0.52801E+04 39 carnegieite-high 10.09 5.93 -4.16 -0.595 0.71071E+04 40 carpholite-Mg 8.58 4.46 -4.12 -0.275 0.70429E+04 41 carpholite-Fe 6.71 1.90 -4.81 -0.321 0.82206E+04 42 celadonite 5.34 3.65 -1.69 -0.099 0.28879E+04 43 celadonite-Fe 3.88 1.09 -2.79 -0.164 0.47561E+04 44 chrysotile 23.89 21.57 -2.32 -0.194 0.39692E+04 49 chlorite-Al-free 47.17 43.14 -4.04 -0.168 0.68936E+04 51 chloritoid-Fe 9.17 5.06 -4.12 -0.275 0.70315E+04 52 chloritoid-Mn 11.40 7.56 -3.84 -0.256 0.65556E+04 54 coesite -2.38 -3.16 -0.78 -0.260 0.13341E+04 61 cristobalite -2.56 -3.16 -0.60 -0.199 0.10195E+04 63 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71234E+04 65 diaspore 2.87 0.74 -2.13 -0.356 0.36450E+04 66 diamond -3.10 -7.69 -4.58 -1.310 0.78266E+04 71 enstatite 17.26 12.27 -4.99 -0.499 0.85226E+04 73 clinoenstatite 17.17 12.27 -4.89 -0.489 0.83541E+04 75 epidote 24.67 22.70 -1.97 -0.095 0.33585E+04 76 clinozoisite 22.81 18.95 -3.86 -0.175 0.65868E+04 77 epidote-Fe 29.84 26.46 -3.38 -0.176 0.57768E+04 78 fayalite 14.05 10.31 -3.73 -0.533 0.63743E+04 79 ferrosilite 11.15 7.16 -3.99 -0.399 0.68202E+04 83 gibbsite 4.08 0.74 -3.34 -0.477 0.57035E+04 84 glaucophane 22.97 20.80 -2.17 -0.059 0.37133E+04 85 glaucophane-Fe 17.28 13.12 -4.15 -0.112 0.70919E+04 86 graphite -3.55 -7.69 -4.14 -1.183 0.70689E+04 87 greenalite 16.14 13.89 -2.25 -0.187 0.38408E+04 90 hematite 12.57 8.99 -3.58 -0.434 0.61111E+04 91 heulandite -5.83 -7.52 -1.69 -0.077 0.28938E+04 95 jadeite 4.22 2.77 -1.44 -0.144 0.24617E+04 97 kalsilite 7.58 3.83 -3.76 -0.537 0.64126E+04 98 kaolinite -1.33 -4.84 -3.50 -0.319 0.59831E+04 101 laumontite 2.88 1.95 -0.93 -0.062 0.15935E+04 102 lawsonite 9.62 8.26 -1.35 -0.090 0.23069E+04 103 leucite 4.12 0.67 -3.45 -0.345 0.58873E+04 105 lizardite 23.24 21.57 -1.68 -0.140 0.28618E+04 107 magnetite 20.09 15.72 -4.37 -0.356 0.74536E+04 108 minnesotaite 10.39 7.58 -2.81 -0.165 0.48028E+04 112 manganosite 14.06 9.24 -4.82 -1.204 0.82248E+04 120 muscovite 2.58 -1.01 -3.59 -0.211 0.61315E+04 121 paragonite 4.24 1.09 -3.15 -0.185 0.53706E+04 122 nepheline 8.34 5.93 -2.41 -0.344 0.41125E+04 128 periclase-Fe 11.63 6.73 -4.89 -1.223 0.83523E+04 134 phlogopite-Na 29.65 27.50 -2.15 -0.119 0.36677E+04 136 prehnite 19.37 18.21 -1.16 -0.068 0.19849E+04 137 prehnite-Fe 22.50 21.96 -0.53 -0.032 0.91157E+03 138 pumpellyite-Fe 46.27 43.89 -2.38 -0.053 0.40580E+04 139 pumpellyite-Mg 48.99 46.45 -2.54 -0.057 0.43419E+04 143 pyrrhotite -4.26 -7.89 -3.63 -1.210 0.61973E+04 144 pyrrhotiteFe0.875 -6.02 -9.29 -3.27 -1.203 0.55845E+04 145 pyroxmangite 7.40 6.08 -1.31 -0.263 0.22452E+04 146 pyrophyllite -6.18 -11.15 -4.98 -0.311 0.84962E+04 147 quartz -2.99 -3.16 -0.17 -0.056 0.28681E+03 152 rhodonite 7.45 6.08 -1.36 -0.272 0.23254E+04 153 sanidine -1.28 -2.49 -1.21 -0.093 0.20677E+04 165 stilpnomelane-Mg 27.44 25.81 -1.63 -0.049 0.27803E+04 171 talc 16.49 15.25 -1.24 -0.073 0.21140E+04 174 tephroite 18.09 15.32 -2.76 -0.394 0.47141E+04 178 tridymite -2.63 -3.16 -0.53 -0.177 0.90679E+03 179 tremolite 47.87 47.42 -0.45 -0.012 0.77495E+03 180 ferroactinolite 38.45 34.62 -3.83 -0.104 0.65449E+04 181 troilite-low -4.41 -7.89 -3.48 -1.160 0.59401E+04 183 vesuvianite 223.47 218.82 -4.65 -0.036 0.79436E+04 187 wairakite 3.95 1.95 -2.00 -0.118 0.34154E+04 188 walstromite 11.51 9.94 -1.56 -0.313 0.26719E+04 189 wollastonite 10.46 9.94 -0.52 -0.103 0.88229E+03 190 pseudo-wollastonite 11.00 9.94 -1.06 -0.211 0.18021E+04 191 zoisite 22.85 18.95 -3.90 -0.177 0.66609E+04 192 akaganeite 7.75 4.49 -3.26 -0.705 0.55681E+04 199 chalcedony -2.80 -3.16 -0.35 -0.118 0.60611E+03 201 montmorillonite-Ca -2.29 -6.17 -3.88 -0.240 0.66180E+04 202 montmorillonite-K -2.24 -6.27 -4.03 -0.247 0.68816E+04 203 montmorillonite-Mg -2.48 -6.79 -4.32 -0.267 0.73678E+04 204 montmorillonite-Na -2.04 -5.57 -3.54 -0.216 0.60365E+04 205 nontronite-Ca 3.21 -0.19 -3.41 -0.221 0.58215E+04 206 nontronite-H 2.53 -2.36 -4.89 -0.328 0.83485E+04 207 nontronite-K 3.34 -0.30 -3.64 -0.233 0.62083E+04 208 nontronite-Mg 3.07 -0.82 -3.90 -0.253 0.66553E+04 209 nontronite-Na 3.52 0.40 -3.12 -0.200 0.53292E+04 224 tobermorite 9.82 7.76 -2.07 -0.564 0.35287E+04 230 alabandite -0.98 -5.38 -4.41 -1.469 0.75227E+04 233 boehmite 4.41 0.74 -3.67 -0.611 0.62619E+04 235 ferrous-oxide 9.81 6.73 -3.08 -0.769 0.52532E+04 240 silica-amorphous -2.09 -3.16 -1.07 -0.355 0.18203E+04 242 an20ab80 2.02 1.35 -0.67 -0.052 0.11472E+04 243 an25ab75 2.65 1.78 -0.87 -0.067 0.14810E+04 244 an30ab70 3.28 2.21 -1.07 -0.082 0.18244E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 100.0000000 g Current total amount of reactant added: 3299.9990000 g New total amount of reactant added: 3399.9990000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.5221E-10 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 11 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 3399.9990000 Water: Moles liquid = 0.3647E+02 kg liquid = 0.6570E+00 Moles total = 0.1289E+02 kg total = 0.2322E+00 Activity = 1.0000 Stoichiometric ionic strength = .1137731E-01 Osmotic coef. = 0.9689 True ionic strength = .2005459E-01 Chg. balance for total moles = 0.5221E-10 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.88451E-10 -10.0533 0.74313E-10 -10.1289 0.84016E+00 -0.0756 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.20904E-03 -3.6798 0.17457E-03 -3.7580 0.83510E+00 -0.0783 4 SO4-- 0.98434E-12 -12.0069 0.51094E-12 -12.2916 0.51906E+00 -0.2848 5 HCO3- 0.36421E-06 -6.4386 0.30460E-06 -6.5163 0.83632E+00 -0.0776 6 HS- 0.38811E-04 -4.4110 0.32416E-04 -4.4892 0.83522E+00 -0.0782 7 Al+++ 0.97494E-29 -29.0110 0.22500E-29 -29.6478 0.23078E+00 -0.6368 8 H4SiO4 0.69597E-03 -3.1574 0.69597E-03 -3.1574 0.10000E+01 0.0000 9 Ca++ 0.13550E-06 -6.8681 0.69817E-07 -7.1560 0.51525E+00 -0.2880 10 Mg++ 0.21199E-10 -10.6737 0.10872E-10 -10.9637 0.51289E+00 -0.2900 11 Fe++ 0.58427E-13 -13.2334 0.29999E-13 -13.5229 0.51345E+00 -0.2895 12 K+ 0.15680E-03 -3.8047 0.13116E-03 -3.8822 0.83652E+00 -0.0775 13 Na+ 0.19897E-01 -1.7012 0.16613E-01 -1.7796 0.83495E+00 -0.0783 14 Mn++ 0.18728E-10 -10.7275 0.96236E-11 -11.0167 0.51387E+00 -0.2891 15 HPO4-- 0.45190E-07 -7.3450 0.23459E-07 -7.6297 0.51914E+00 -0.2847 16 HSiO3- 0.10472E-01 -1.9800 0.87449E-02 -2.0582 0.83510E+00 -0.0783 17 Ca(HSiO3)+ 0.16618E-07 -7.7794 0.13904E-07 -7.8568 0.83670E+00 -0.0774 18 Mg(HSiO3)+ 0.32207E-11 -11.4921 0.26947E-11 -11.5695 0.83670E+00 -0.0774 19 NaHSiO3,aq 0.23496E-02 -2.6290 0.23496E-02 -2.6290 0.10000E+01 0.0000 20 AlO+ 0.66245E-16 -16.1788 0.55427E-16 -16.2563 0.83670E+00 -0.0774 22 HAlO2,aq 0.14854E-09 -9.8282 0.14854E-09 -9.8282 0.10000E+01 0.0000 23 AlO2- 0.53078E-05 -5.2751 0.44245E-05 -5.3541 0.83359E+00 -0.0790 24 CH4,aq 0.18837E-04 -4.7250 0.18772E-04 -4.7265 0.99653E+00 -0.0015 25 C2H6,aq 0.52190E-14 -14.2824 0.52009E-14 -14.2839 0.99653E+00 -0.0015 29 CO,aq 0.14073E-16 -16.8516 0.14073E-16 -16.8516 0.10000E+01 0.0000 30 CO2,aq 0.48535E-10 -10.3139 0.48367E-10 -10.3155 0.99653E+00 -0.0015 31 CO3-2 0.69121E-06 -6.1604 0.35802E-06 -6.4461 0.51796E+00 -0.2857 32 CaCO3,aq 0.31342E-09 -9.5039 0.31342E-09 -9.5039 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.64879E-12 -12.1879 0.54284E-12 -12.2653 0.83670E+00 -0.0774 34 CaCl+ 0.23573E-10 -10.6276 0.19724E-10 -10.7050 0.83670E+00 -0.0774 35 CaCl2,aq 0.81802E-15 -15.0872 0.81802E-15 -15.0872 0.10000E+01 0.0000 36 CaOH+ 0.80026E-07 -7.0968 0.66958E-07 -7.1742 0.83670E+00 -0.0774 37 CaSO4,aq 0.11328E-16 -16.9459 0.11328E-16 -16.9459 0.10000E+01 0.0000 38 HCl,aq 0.23772E-14 -14.6239 0.23772E-14 -14.6239 0.10000E+01 0.0000 43 FeCl+ 0.99069E-17 -17.0041 0.82891E-17 -17.0815 0.83670E+00 -0.0774 46 FeO,aq 0.21113E-09 -9.6755 0.21113E-09 -9.6755 0.10000E+01 0.0000 47 FeOH+ 0.15705E-10 -10.8040 0.13140E-10 -10.8814 0.83670E+00 -0.0774 48 HFeO2- 0.35596E-07 -7.4486 0.29726E-07 -7.5269 0.83510E+00 -0.0783 49 FeO+ 0.11007E-16 -16.9583 0.92093E-17 -17.0358 0.83670E+00 -0.0774 51 FeO2- 0.40861E-09 -9.3887 0.34123E-09 -9.4670 0.83510E+00 -0.0783 52 HFeO2,aq 0.32251E-11 -11.4915 0.32251E-11 -11.4915 0.10000E+01 0.0000 53 H2,aq 0.11623E-04 -4.9347 0.11583E-04 -4.9362 0.99653E+00 -0.0015 54 KCl,aq 0.41499E-09 -9.3820 0.41499E-09 -9.3820 0.10000E+01 0.0000 56 KOH,aq 0.75375E-06 -6.1228 0.75375E-06 -6.1228 0.10000E+01 0.0000 57 KSO4- 0.12453E-14 -14.9047 0.10399E-14 -14.9830 0.83510E+00 -0.0783 58 MgCO3,aq 0.12234E-13 -13.9124 0.12234E-13 -13.9124 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.10324E-15 -15.9862 0.86379E-16 -16.0636 0.83670E+00 -0.0774 60 MgCl+ 0.33272E-14 -14.4779 0.27839E-14 -14.5554 0.83670E+00 -0.0774 61 MgOH+ 0.68960E-10 -10.1614 0.57699E-10 -10.2388 0.83670E+00 -0.0774 63 MnO,aq 0.18047E-08 -8.7436 0.18047E-08 -8.7436 0.10000E+01 0.0000 64 MnOH+ 0.46802E-09 -9.3297 0.39160E-09 -9.4072 0.83670E+00 -0.0774 65 MnO2-2 0.20939E-10 -10.6791 0.10845E-10 -10.9648 0.51796E+00 -0.2857 66 HMnO2- 0.21144E-09 -9.6748 0.17657E-09 -9.7531 0.83510E+00 -0.0783 69 MnCl+ 0.12364E-13 -13.9078 0.10345E-13 -13.9853 0.83670E+00 -0.0774 71 NaCl,aq 0.96107E-06 -6.0172 0.96107E-06 -6.0172 0.10000E+01 0.0000 72 NaOH,aq 0.96047E-04 -4.0175 0.96047E-04 -4.0175 0.10000E+01 0.0000 74 OH- 0.93270E-02 -2.0303 0.77749E-02 -2.1093 0.83359E+00 -0.0790 79 HPO3-2 0.16349E-14 -14.7865 0.84679E-15 -15.0722 0.51796E+00 -0.2857 81 H2PO3- 0.15111E-18 -18.8207 0.12619E-18 -18.8990 0.83510E+00 -0.0783 82 H3PO4,aq 0.90609E-18 -18.0428 0.90609E-18 -18.0428 0.10000E+01 0.0000 83 H2PO4- 0.38474E-10 -10.4148 0.32160E-10 -10.4927 0.83589E+00 -0.0779 84 PO4-3 0.10625E-08 -8.9737 0.25756E-09 -9.5891 0.24241E+00 -0.6155 88 HP2O7-3 0.94326E-18 -18.0254 0.21790E-18 -18.6617 0.23101E+00 -0.6364 89 P2O7-4 0.91018E-17 -17.0409 0.70050E-18 -18.1546 0.76963E-01 -1.1137 90 H2S,aq 0.74710E-08 -8.1266 0.74450E-08 -8.1281 0.99653E+00 -0.0015 91 S2-2 0.38809E-14 -14.4111 0.20102E-14 -14.6968 0.51796E+00 -0.2857 97 SO3-2 0.14636E-17 -17.8346 0.76905E-18 -18.1140 0.52546E+00 -0.2795 99 HSO4- 0.43691E-19 -19.3596 0.36592E-19 -19.4366 0.83751E+00 -0.0770 Charge balance for all species = 0.7949E-10 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.8845142E-10 -.2227013E-01 -.2240791E+02 0.0000 2 H2O 0.1000000E+01 0.5550489E+02 0.9981978E+06 0.0000 3 Cl- 0.2090393E-03 0.2100009E-03 0.7432208E+01 6.3709 4 SO4-- 0.9843442E-12 -.2174288E-04 -.2085023E+01 7.9662 5 HCO3- 0.3642115E-06 0.1989293E-04 0.1211700E+01 3.6127 6 HS- 0.3881110E-04 0.6056145E-04 0.1999404E+01 5.6397 7 Al+++ 0.9749359E-29 0.5307968E-05 0.1429678E+00 0.7390 8 H4SiO4 0.6959724E-03 0.1351730E-01 0.1296960E+04 -3.1574 9 Ca++ 0.1355027E-06 0.2324847E-06 0.9301315E-02 13.1018 10 Mg++ 0.2119858E-10 0.9339485E-10 0.2266666E-05 9.2942 11 Fe++ 0.5842657E-13 0.3623476E-07 0.2020082E-02 6.7350 12 K+ 0.1567951E-03 0.1575492E-03 0.6149773E+01 6.2467 13 Na+ 0.1989655E-01 0.2234318E-01 0.5127716E+03 8.3494 14 Mn++ 0.1872751E-10 0.2523819E-08 0.1384124E-03 9.2412 15 HPO4-- 0.4518951E-07 0.4629052E-07 0.4435189E-02 12.6282 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.5629892E+02 -.1463186E-01 -.5628429E+02 0.0000000E+00 2 H2O 0.1288787E+02 0.3646767E+02 -.2357980E+02 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.9425107E-01 -.1428545E-04 0.9426535E-01 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.9422556E-01 0.3978992E-04 -.9426535E-01 0.0000000E+00 7 Al+++ 0.1108652E+02 0.3487427E-05 0.1108651E+02 0.0000000E+00 8 H4SiO4 0.3540345E+02 0.8881097E-02 0.3539457E+02 0.0000000E+00 9 Ca++ 0.3910498E+01 0.1527465E-06 0.3910498E+01 0.0000000E+00 10 Mg++ 0.2698412E+01 0.6136203E-10 0.2698412E+01 0.0000000E+00 11 Fe++ 0.2424229E+01 0.2380686E-07 0.2424228E+01 0.0000000E+00 12 K+ 0.7218682E+00 0.1035126E-03 0.7217646E+00 0.0000000E+00 13 Na+ 0.4267987E+01 0.1467985E-01 0.4253307E+01 0.0000000E+00 14 Mn++ 0.5895121E-01 0.1658193E-08 0.5895121E-01 0.0000000E+00 15 HPO4-- 0.2011975E-01 0.3041367E-07 0.2011972E-01 0.0000000E+00 Chg. balance for solid moles: -.1971E-14 Mass of aqueous solution: 0.658162E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 3399.9990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 4.250 0.628 1114. 3.047 30.00 427.8 andradite 0.3771 -0.424 191.6 2.282 5.159 49.78 grossular 0.9130E-01 -1.040 41.13 1.614 1.107 11.44 apatite-OH 0.6707E-02 -2.173 3.369 0.527 0.9070E-01 1.070 clinochlore 0.4834 -0.316 268.7 2.429 7.234 102.2 daphnite 0.1399 -0.854 99.85 1.999 2.688 30.26 chlorite-Mn 0.1179E-01 -1.928 8.359 0.922 0.2250 2.664 diopside 0.1757 -0.755 38.04 1.580 1.024 11.63 hedenbergite 0.4556E-01 -1.341 11.30 1.053 0.3043 3.096 microcline 0.6329 -0.199 176.2 2.246 4.743 68.82 stilbite 2.192 0.341 1545. 3.189 41.60 720.6 stilpnomelane-Fe 0.1777 -0.750 191.5 2.282 5.157 66.16 tr.625ac.25prg.125 0.2914E-01 -1.535 24.91 1.396 0.6706 8.017 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8051E+00 0.8051E+00 1.0000 -0.094 grossular 0.1949E+00 0.1949E+00 1.0000 -0.710 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.7611E+00 0.7611E+00 1.0000 -0.119 daphnite 0.2203E+00 0.2203E+00 1.0000 -0.657 chlorite-Mn 0.1856E-01 0.1856E-01 1.0000 -1.731 diopside 0.7941E+00 0.7941E+00 1.0000 -0.100 hedenbergite 0.2059E+00 0.2059E+00 1.0000 -0.686 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 tr.625ac.25prg.125 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 3714.327227 g Volume = 1503.528832 cm3 Porosity: -10.4724% V(tot) - V(min): -.14253E+03 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 3399.9990000 g log = 3.5315 Original solution: 1000.0103000 g Original solution / Rock added: 0.29 (Water/Rock Ratio), log = -0.5315 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0634 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9600E+00 0.9854 0.1006E+01 0.1021E+01 CO2,gas 0.4833E-08 1.0068 0.5175E-08 0.5140E-08 CH4,gas 0.2567E-01 1.0123 0.2763E-01 0.2729E-01 H2,gas 0.1429E-01 1.0006 0.1521E-01 0.1520E-01 H2S,gas 0.1933E-06 0.9959 0.2047E-06 0.2055E-06 S2,gas 0.6394E-29 1.0000 0.6799E-29 0.6799E-29 CO,gas 0.1972E-13 1.0000 0.2097E-13 0.2097E-13 SO3,gas 0.1003E-47 1.0000 0.1067E-47 0.1067E-47 SO2,gas 0.5936E-27 1.0000 0.6312E-27 0.6312E-27 HCl,gas 0.3945E-17 1.0000 0.4195E-17 0.4195E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 16 albite -0.38 -0.38 0.00 0.000 -0.94784E-12 22 andradite 39.01 39.01 0.00 0.000 -0.12132E-10 23 grossular 32.73 32.73 0.00 0.000 -0.12132E-10 32 apatite-OH -18.15 -18.15 0.00 0.000 0.60662E-11 46 clinochlore 39.07 39.07 0.00 0.000 0.12132E-10 47 daphnite 28.97 28.97 0.00 0.000 0.36397E-10 48 chlorite-Mn 46.87 46.87 0.00 0.000 0.00000E+00 67 diopside 16.18 16.18 0.00 0.000 0.60662E-11 68 hedenbergite 14.21 14.21 0.00 0.000 0.60662E-11 116 microcline -2.49 -2.49 0.00 0.000 0.15165E-11 163 stilbite -7.52 -7.52 0.00 0.000 0.15165E-10 164 stilpnomelane-Fe 13.02 13.02 0.00 0.000 0.21232E-10 245 tr.625ac.25prg.125 45.16 45.16 0.00 0.000 0.36397E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -16.65 -9.99 -3.328 0.17049E+05 -8.286 3 CH4,gas 4.54 1.29 -3.26 -0.814 0.55622E+04 -1.559 4 H2,gas 8.00 4.48 -3.52 -2.010 0.60051E+04 -1.818 5 H2S,gas -6.23 -14.62 -8.39 -4.194 0.14322E+05 -6.689 6 S2,gas -7.34 -38.20 -30.87 -4.749 0.52704E+05 -29.168 7 CO,gas 3.21 -12.16 -15.38 -4.731 0.26256E+05 -13.678 8 SO3,gas 17.12 -32.55 -49.67 -12.418 0.84812E+05 -47.972 9 SO2,gas 0.83 -28.07 -28.90 -7.706 0.49344E+05 -27.200 10 HCl,gas 5.19 -13.89 -19.08 -9.538 0.32572E+05 -17.377 11 acmite 7.71 6.53 -1.18 -0.123 0.20175E+04 15 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 19 spessartine 24.46 19.73 -4.73 -0.236 0.80729E+04 20 analcite 3.32 2.77 -0.55 -0.061 0.93624E+03 26 annite 20.12 17.72 -2.40 -0.134 0.41064E+04 27 phlogopite 27.06 25.40 -1.67 -0.093 0.28489E+04 29 anorthite 12.71 8.26 -4.45 -0.342 0.75903E+04 35 aragonite 0.97 -3.54 -4.51 -1.503 0.77005E+04 36 brucite 12.57 9.29 -3.27 -0.655 0.55909E+04 37 calcite 0.81 -3.54 -4.36 -1.452 0.74363E+04 38 carnegieite-low 9.02 5.93 -3.09 -0.442 0.52801E+04 39 carnegieite-high 10.09 5.93 -4.16 -0.595 0.71071E+04 40 carpholite-Mg 8.58 4.46 -4.12 -0.275 0.70429E+04 41 carpholite-Fe 6.71 1.90 -4.81 -0.321 0.82206E+04 42 celadonite 5.34 3.65 -1.69 -0.099 0.28879E+04 43 celadonite-Fe 3.88 1.09 -2.79 -0.164 0.47561E+04 44 chrysotile 23.89 21.57 -2.32 -0.194 0.39692E+04 49 chlorite-Al-free 47.17 43.14 -4.04 -0.168 0.68936E+04 51 chloritoid-Fe 9.17 5.06 -4.12 -0.275 0.70315E+04 52 chloritoid-Mn 11.40 7.56 -3.84 -0.256 0.65555E+04 54 coesite -2.38 -3.16 -0.78 -0.260 0.13341E+04 61 cristobalite -2.56 -3.16 -0.60 -0.199 0.10195E+04 63 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71234E+04 65 diaspore 2.87 0.74 -2.13 -0.356 0.36450E+04 66 diamond -3.10 -7.68 -4.58 -1.308 0.78154E+04 71 enstatite 17.26 12.27 -4.99 -0.499 0.85226E+04 73 clinoenstatite 17.17 12.27 -4.89 -0.489 0.83541E+04 75 epidote 24.67 22.70 -1.97 -0.095 0.33585E+04 76 clinozoisite 22.81 18.95 -3.86 -0.175 0.65868E+04 77 epidote-Fe 29.84 26.46 -3.38 -0.176 0.57768E+04 78 fayalite 14.05 10.31 -3.73 -0.533 0.63743E+04 79 ferrosilite 11.15 7.16 -3.99 -0.399 0.68202E+04 83 gibbsite 4.08 0.74 -3.34 -0.477 0.57035E+04 84 glaucophane 22.97 20.80 -2.17 -0.059 0.37133E+04 85 glaucophane-Fe 17.28 13.12 -4.15 -0.112 0.70919E+04 86 graphite -3.55 -7.68 -4.13 -1.181 0.70576E+04 87 greenalite 16.14 13.89 -2.25 -0.187 0.38408E+04 90 hematite 12.57 8.99 -3.58 -0.434 0.61111E+04 91 heulandite -5.83 -7.52 -1.69 -0.077 0.28938E+04 95 jadeite 4.22 2.77 -1.44 -0.144 0.24617E+04 97 kalsilite 7.58 3.83 -3.76 -0.537 0.64126E+04 98 kaolinite -1.33 -4.84 -3.50 -0.319 0.59831E+04 101 laumontite 2.88 1.95 -0.93 -0.062 0.15935E+04 102 lawsonite 9.62 8.26 -1.35 -0.090 0.23069E+04 103 leucite 4.12 0.67 -3.45 -0.345 0.58873E+04 105 lizardite 23.24 21.57 -1.68 -0.140 0.28618E+04 107 magnetite 20.09 15.72 -4.37 -0.356 0.74536E+04 108 minnesotaite 10.39 7.58 -2.81 -0.165 0.48028E+04 112 manganosite 14.06 9.24 -4.82 -1.204 0.82247E+04 120 muscovite 2.58 -1.01 -3.59 -0.211 0.61315E+04 121 paragonite 4.24 1.09 -3.15 -0.185 0.53706E+04 122 nepheline 8.34 5.93 -2.41 -0.344 0.41125E+04 128 periclase-Fe 11.63 6.73 -4.89 -1.223 0.83523E+04 134 phlogopite-Na 29.65 27.50 -2.15 -0.119 0.36677E+04 136 prehnite 19.37 18.21 -1.16 -0.068 0.19849E+04 137 prehnite-Fe 22.50 21.96 -0.53 -0.032 0.91157E+03 138 pumpellyite-Fe 46.27 43.89 -2.38 -0.053 0.40580E+04 139 pumpellyite-Mg 48.99 46.45 -2.54 -0.057 0.43419E+04 143 pyrrhotite -4.26 -7.88 -3.62 -1.208 0.61860E+04 144 pyrrhotiteFe0.875 -6.02 -9.28 -3.26 -1.200 0.55732E+04 145 pyroxmangite 7.40 6.08 -1.31 -0.263 0.22451E+04 146 pyrophyllite -6.18 -11.15 -4.98 -0.311 0.84962E+04 147 quartz -2.99 -3.16 -0.17 -0.056 0.28681E+03 152 rhodonite 7.45 6.08 -1.36 -0.272 0.23254E+04 153 sanidine -1.28 -2.49 -1.21 -0.093 0.20677E+04 165 stilpnomelane-Mg 27.44 25.81 -1.63 -0.049 0.27803E+04 171 talc 16.49 15.25 -1.24 -0.073 0.21140E+04 174 tephroite 18.09 15.33 -2.76 -0.394 0.47140E+04 178 tridymite -2.63 -3.16 -0.53 -0.177 0.90679E+03 179 tremolite 47.87 47.42 -0.45 -0.012 0.77495E+03 180 ferroactinolite 38.45 34.62 -3.83 -0.104 0.65449E+04 181 troilite-low -4.41 -7.88 -3.47 -1.157 0.59288E+04 183 vesuvianite 223.47 218.82 -4.65 -0.036 0.79436E+04 187 wairakite 3.95 1.95 -2.00 -0.118 0.34154E+04 188 walstromite 11.51 9.94 -1.56 -0.313 0.26719E+04 189 wollastonite 10.46 9.94 -0.52 -0.103 0.88229E+03 190 pseudo-wollastonite 11.00 9.94 -1.06 -0.211 0.18021E+04 191 zoisite 22.85 18.95 -3.90 -0.177 0.66609E+04 192 akaganeite 7.75 4.49 -3.26 -0.705 0.55681E+04 199 chalcedony -2.80 -3.16 -0.35 -0.118 0.60611E+03 201 montmorillonite-Ca -2.29 -6.17 -3.88 -0.240 0.66180E+04 202 montmorillonite-K -2.24 -6.27 -4.03 -0.247 0.68816E+04 203 montmorillonite-Mg -2.48 -6.79 -4.32 -0.267 0.73678E+04 204 montmorillonite-Na -2.04 -5.57 -3.54 -0.216 0.60365E+04 205 nontronite-Ca 3.21 -0.19 -3.41 -0.221 0.58215E+04 206 nontronite-H 2.53 -2.36 -4.89 -0.328 0.83485E+04 207 nontronite-K 3.34 -0.30 -3.64 -0.233 0.62083E+04 208 nontronite-Mg 3.07 -0.82 -3.90 -0.253 0.66553E+04 209 nontronite-Na 3.52 0.40 -3.12 -0.200 0.53292E+04 224 tobermorite 9.82 7.76 -2.07 -0.564 0.35287E+04 230 alabandite -0.98 -5.38 -4.40 -1.466 0.75113E+04 233 boehmite 4.41 0.74 -3.67 -0.611 0.62619E+04 235 ferrous-oxide 9.81 6.73 -3.08 -0.769 0.52532E+04 240 silica-amorphous -2.09 -3.16 -1.07 -0.355 0.18203E+04 242 an20ab80 2.02 1.35 -0.67 -0.052 0.11472E+04 243 an25ab75 2.65 1.78 -0.87 -0.067 0.14810E+04 244 an30ab70 3.28 2.21 -1.07 -0.082 0.18244E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 100.0000000 g Current total amount of reactant added: 3399.9990000 g New total amount of reactant added: 3499.9990000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.5221E-10 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 11 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 3499.9990000 Water: Moles liquid = 0.3591E+02 kg liquid = 0.6470E+00 Moles total = 0.1163E+02 kg total = 0.2096E+00 Activity = 1.0000 Stoichiometric ionic strength = .1138002E-01 Osmotic coef. = 0.9688 True ionic strength = .2005670E-01 Chg. balance for total moles = 0.5221E-10 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.88461E-10 -10.0533 0.74320E-10 -10.1289 0.84015E+00 -0.0756 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.21228E-03 -3.6731 0.17728E-03 -3.7513 0.83509E+00 -0.0783 4 SO4-- 0.99956E-12 -12.0002 0.51882E-12 -12.2850 0.51905E+00 -0.2848 5 HCO3- 0.36984E-06 -6.4320 0.30930E-06 -6.5096 0.83631E+00 -0.0776 6 HS- 0.39414E-04 -4.4044 0.32919E-04 -4.4826 0.83521E+00 -0.0782 7 Al+++ 0.97528E-29 -29.0109 0.22506E-29 -29.6477 0.23077E+00 -0.6368 8 H4SiO4 0.69597E-03 -3.1574 0.69597E-03 -3.1574 0.10000E+01 0.0000 9 Ca++ 0.13553E-06 -6.8680 0.69831E-07 -7.1560 0.51523E+00 -0.2880 10 Mg++ 0.21203E-10 -10.6736 0.10875E-10 -10.9636 0.51287E+00 -0.2900 11 Fe++ 0.58440E-13 -13.2333 0.30005E-13 -13.5228 0.51343E+00 -0.2895 12 K+ 0.15681E-03 -3.8046 0.13117E-03 -3.8821 0.83651E+00 -0.0775 13 Na+ 0.19899E-01 -1.7012 0.16614E-01 -1.7795 0.83494E+00 -0.0783 14 Mn++ 0.18733E-10 -10.7274 0.96262E-11 -11.0165 0.51386E+00 -0.2892 15 HPO4-- 0.45182E-07 -7.3450 0.23455E-07 -7.6298 0.51912E+00 -0.2847 16 HSiO3- 0.10471E-01 -1.9800 0.87440E-02 -2.0583 0.83509E+00 -0.0783 17 Ca(HSiO3)+ 0.16620E-07 -7.7794 0.13906E-07 -7.8568 0.83669E+00 -0.0774 18 Mg(HSiO3)+ 0.32210E-11 -11.4920 0.26950E-11 -11.5694 0.83669E+00 -0.0774 19 NaHSiO3,aq 0.23496E-02 -2.6290 0.23496E-02 -2.6290 0.10000E+01 0.0000 20 AlO+ 0.66252E-16 -16.1788 0.55433E-16 -16.2562 0.83669E+00 -0.0774 22 HAlO2,aq 0.14854E-09 -9.8282 0.14854E-09 -9.8282 0.10000E+01 0.0000 23 AlO2- 0.53073E-05 -5.2751 0.44241E-05 -5.3542 0.83358E+00 -0.0791 24 CH4,aq 0.19130E-04 -4.7183 0.19063E-04 -4.7198 0.99653E+00 -0.0015 25 C2H6,aq 0.53824E-14 -14.2690 0.53637E-14 -14.2705 0.99653E+00 -0.0015 29 CO,aq 0.14292E-16 -16.8449 0.14292E-16 -16.8449 0.10000E+01 0.0000 30 CO2,aq 0.49289E-10 -10.3072 0.49118E-10 -10.3088 0.99653E+00 -0.0015 31 CO3-2 0.70183E-06 -6.1538 0.36351E-06 -6.4395 0.51794E+00 -0.2857 32 CaCO3,aq 0.31829E-09 -9.4972 0.31829E-09 -9.4972 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.65894E-12 -12.1812 0.55133E-12 -12.2586 0.83669E+00 -0.0774 34 CaCl+ 0.23944E-10 -10.6208 0.20034E-10 -10.6982 0.83669E+00 -0.0774 35 CaCl2,aq 0.84376E-15 -15.0738 0.84376E-15 -15.0738 0.10000E+01 0.0000 36 CaOH+ 0.80034E-07 -7.0967 0.66964E-07 -7.1742 0.83669E+00 -0.0774 37 CaSO4,aq 0.11505E-16 -16.9391 0.11505E-16 -16.9391 0.10000E+01 0.0000 38 HCl,aq 0.24143E-14 -14.6172 0.24143E-14 -14.6172 0.10000E+01 0.0000 43 FeCl+ 0.10063E-16 -16.9973 0.84193E-17 -17.0747 0.83669E+00 -0.0774 46 FeO,aq 0.21113E-09 -9.6755 0.21113E-09 -9.6755 0.10000E+01 0.0000 47 FeOH+ 0.15707E-10 -10.8039 0.13142E-10 -10.8814 0.83669E+00 -0.0774 48 HFeO2- 0.35593E-07 -7.4486 0.29723E-07 -7.5269 0.83509E+00 -0.0783 49 FeO+ 0.11008E-16 -16.9583 0.92102E-17 -17.0357 0.83669E+00 -0.0774 51 FeO2- 0.40857E-09 -9.3887 0.34120E-09 -9.4670 0.83509E+00 -0.0783 52 HFeO2,aq 0.32251E-11 -11.4915 0.32251E-11 -11.4915 0.10000E+01 0.0000 53 H2,aq 0.11623E-04 -4.9347 0.11583E-04 -4.9362 0.99653E+00 -0.0015 54 KCl,aq 0.42146E-09 -9.3752 0.42146E-09 -9.3752 0.10000E+01 0.0000 56 KOH,aq 0.75375E-06 -6.1228 0.75375E-06 -6.1228 0.10000E+01 0.0000 57 KSO4- 0.12646E-14 -14.8980 0.10561E-14 -14.9763 0.83509E+00 -0.0783 58 MgCO3,aq 0.12424E-13 -13.9057 0.12424E-13 -13.9057 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.10485E-15 -15.9794 0.87730E-16 -16.0569 0.83669E+00 -0.0774 60 MgCl+ 0.33795E-14 -14.4711 0.28276E-14 -14.5486 0.83669E+00 -0.0774 61 MgOH+ 0.68967E-10 -10.1614 0.57704E-10 -10.2388 0.83669E+00 -0.0774 63 MnO,aq 0.18048E-08 -8.7436 0.18048E-08 -8.7436 0.10000E+01 0.0000 64 MnOH+ 0.46811E-09 -9.3297 0.39166E-09 -9.4071 0.83669E+00 -0.0774 65 MnO2-2 0.20937E-10 -10.6791 0.10844E-10 -10.9648 0.51794E+00 -0.2857 66 HMnO2- 0.21143E-09 -9.6748 0.17657E-09 -9.7531 0.83509E+00 -0.0783 69 MnCl+ 0.12560E-13 -13.9010 0.10509E-13 -13.9785 0.83669E+00 -0.0774 71 NaCl,aq 0.97608E-06 -6.0105 0.97608E-06 -6.0105 0.10000E+01 0.0000 72 NaOH,aq 0.96047E-04 -4.0175 0.96047E-04 -4.0175 0.10000E+01 0.0000 74 OH- 0.93261E-02 -2.0303 0.77741E-02 -2.1093 0.83358E+00 -0.0791 79 HPO3-2 0.16346E-14 -14.7866 0.84663E-15 -15.0723 0.51794E+00 -0.2857 81 H2PO3- 0.15109E-18 -18.8208 0.12618E-18 -18.8990 0.83509E+00 -0.0783 82 H3PO4,aq 0.90609E-18 -18.0428 0.90609E-18 -18.0428 0.10000E+01 0.0000 83 H2PO4- 0.38471E-10 -10.4149 0.32157E-10 -10.4927 0.83588E+00 -0.0779 84 PO4-3 0.10623E-08 -8.9738 0.25749E-09 -9.5892 0.24239E+00 -0.6155 88 HP2O7-3 0.94304E-18 -18.0255 0.21784E-18 -18.6619 0.23100E+00 -0.6364 89 P2O7-4 0.90993E-17 -17.0410 0.70023E-18 -18.1548 0.76954E-01 -1.1138 90 H2S,aq 0.75876E-08 -8.1199 0.75613E-08 -8.1214 0.99653E+00 -0.0015 91 S2-2 0.40024E-14 -14.3977 0.20730E-14 -14.6834 0.51794E+00 -0.2857 97 SO3-2 0.14862E-17 -17.8279 0.78091E-18 -18.1074 0.52545E+00 -0.2795 99 HSO4- 0.44369E-19 -19.3529 0.37160E-19 -19.4299 0.83751E+00 -0.0770 Charge balance for all species = 0.8072E-10 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.8846062E-10 -.2226836E-01 -.2240613E+02 0.0000 2 H2O 0.1000000E+01 0.5550489E+02 0.9981977E+06 0.0000 3 Cl- 0.2122841E-03 0.2132606E-03 0.7547574E+01 6.3775 4 SO4-- 0.9995550E-12 -.2203541E-04 -.2113075E+01 7.9728 5 HCO3- 0.3698369E-06 0.2020172E-04 0.1230508E+01 3.6193 6 HS- 0.3941354E-04 0.6145654E-04 0.2028955E+01 5.6463 7 Al+++ 0.9752795E-29 0.5307475E-05 0.1429545E+00 0.7390 8 H4SiO4 0.6959730E-03 0.1351636E-01 0.1296870E+04 -3.1574 9 Ca++ 0.1355328E-06 0.2325301E-06 0.9303128E-02 13.1018 10 Mg++ 0.2120330E-10 0.9340723E-10 0.2266966E-05 9.2942 11 Fe++ 0.5843959E-13 0.3623150E-07 0.2019900E-02 6.7350 12 K+ 0.1568114E-03 0.1575656E-03 0.6150411E+01 6.2467 13 Na+ 0.1989863E-01 0.2234527E-01 0.5128197E+03 8.3494 14 Mn++ 0.1873308E-10 0.2524038E-08 0.1384243E-03 9.2412 15 HPO4-- 0.4518201E-07 0.4628278E-07 0.4434446E-02 12.6280 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.5795477E+02 -.1440707E-01 -.5794037E+02 0.0000000E+00 2 H2O 0.1163433E+02 0.3591026E+02 -.2427593E+02 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.9702241E-01 -.1425635E-04 0.9703666E-01 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.9699690E-01 0.3976082E-04 -.9703666E-01 0.0000000E+00 7 Al+++ 0.1141259E+02 0.3433802E-05 0.1141259E+02 0.0000000E+00 8 H4SiO4 0.3644473E+02 0.8744743E-02 0.3643599E+02 0.0000000E+00 9 Ca++ 0.4025513E+01 0.1504411E-06 0.4025512E+01 0.0000000E+00 10 Mg++ 0.2777777E+01 0.6043210E-10 0.2777777E+01 0.0000000E+00 11 Fe++ 0.2495529E+01 0.2344086E-07 0.2495529E+01 0.0000000E+00 12 K+ 0.7430996E+00 0.1019409E-03 0.7429976E+00 0.0000000E+00 13 Na+ 0.4393512E+01 0.1445682E-01 0.4379055E+01 0.0000000E+00 14 Mn++ 0.6068507E-01 0.1632988E-08 0.6068507E-01 0.0000000E+00 15 HPO4-- 0.2071151E-01 0.2994378E-07 0.2071148E-01 0.0000000E+00 Chg. balance for solid moles: 0.8604E-15 Mass of aqueous solution: 0.648102E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 3499.9990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 4.375 0.641 1147. 3.060 30.01 440.4 andradite 0.3881 -0.411 197.2 2.295 5.159 51.25 grossular 0.9399E-01 -1.027 42.34 1.627 1.107 11.78 apatite-OH 0.6904E-02 -2.161 3.468 0.540 0.9070E-01 1.102 clinochlore 0.4976 -0.303 276.6 2.442 7.234 105.2 daphnite 0.1441 -0.841 102.8 2.012 2.688 31.15 chlorite-Mn 0.1214E-01 -1.916 8.605 0.935 0.2250 2.742 diopside 0.1811 -0.742 39.22 1.594 1.026 11.99 hedenbergite 0.4697E-01 -1.328 11.65 1.066 0.3048 3.192 microcline 0.6515 -0.186 181.4 2.259 4.743 70.84 stilbite 2.257 0.353 1590. 3.201 41.59 741.7 stilpnomelane-Fe 0.1829 -0.738 197.2 2.295 5.157 68.11 tr.625ac.25prg.125 0.2998E-01 -1.523 25.62 1.409 0.6701 8.246 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8051E+00 0.8051E+00 1.0000 -0.094 grossular 0.1949E+00 0.1949E+00 1.0000 -0.710 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.7611E+00 0.7611E+00 1.0000 -0.119 daphnite 0.2203E+00 0.2203E+00 1.0000 -0.657 chlorite-Mn 0.1856E-01 0.1856E-01 1.0000 -1.731 diopside 0.7941E+00 0.7941E+00 1.0000 -0.100 hedenbergite 0.2059E+00 0.2059E+00 1.0000 -0.686 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 tr.625ac.25prg.125 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 3823.577892 g Volume = 1547.731896 cm3 Porosity: -10.4734% V(tot) - V(min): -.14673E+03 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 3499.9990000 g log = 3.5441 Original solution: 1000.0103000 g Original solution / Rock added: 0.29 (Water/Rock Ratio), log = -0.5441 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0638 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9597E+00 0.9854 0.1006E+01 0.1021E+01 CO2,gas 0.4906E-08 1.0068 0.5255E-08 0.5220E-08 CH4,gas 0.2605E-01 1.0123 0.2806E-01 0.2772E-01 H2,gas 0.1429E-01 1.0006 0.1521E-01 0.1520E-01 H2S,gas 0.1962E-06 0.9959 0.2079E-06 0.2087E-06 S2,gas 0.6592E-29 1.0000 0.7013E-29 0.7013E-29 CO,gas 0.2002E-13 1.0000 0.2130E-13 0.2130E-13 SO3,gas 0.1019E-47 1.0000 0.1084E-47 0.1084E-47 SO2,gas 0.6026E-27 1.0000 0.6410E-27 0.6410E-27 HCl,gas 0.4005E-17 1.0000 0.4260E-17 0.4260E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 16 albite -0.38 -0.38 0.00 0.000 -0.94784E-12 22 andradite 39.01 39.01 0.00 0.000 -0.24265E-10 23 grossular 32.73 32.73 0.00 0.000 -0.36397E-10 32 apatite-OH -18.15 -18.15 0.00 0.000 0.00000E+00 46 clinochlore 39.07 39.07 0.00 0.000 0.24265E-10 47 daphnite 28.97 28.97 0.00 0.000 0.18198E-10 48 chlorite-Mn 46.87 46.87 0.00 0.000 -0.24265E-10 67 diopside 16.18 16.18 0.00 0.000 0.60662E-11 68 hedenbergite 14.21 14.21 0.00 0.000 0.90992E-11 116 microcline -2.49 -2.49 0.00 0.000 0.15165E-11 163 stilbite -7.52 -7.52 0.00 0.000 -0.90992E-11 164 stilpnomelane-Fe 13.02 13.02 0.00 0.000 0.21232E-10 245 tr.625ac.25prg.125 45.16 45.16 0.00 0.000 -0.12132E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -16.64 -9.98 -3.326 0.17038E+05 -8.279 3 CH4,gas 4.54 1.29 -3.25 -0.813 0.55508E+04 -1.552 4 H2,gas 8.00 4.48 -3.52 -2.010 0.60051E+04 -1.818 5 H2S,gas -6.23 -14.61 -8.38 -4.191 0.14311E+05 -6.682 6 S2,gas -7.34 -38.19 -30.85 -4.747 0.52681E+05 -29.154 7 CO,gas 3.21 -12.16 -15.37 -4.729 0.26245E+05 -13.672 8 SO3,gas 17.12 -32.54 -49.66 -12.416 0.84800E+05 -47.965 9 SO2,gas 0.83 -28.06 -28.89 -7.705 0.49332E+05 -27.193 10 HCl,gas 5.19 -13.88 -19.07 -9.535 0.32561E+05 -17.371 11 acmite 7.71 6.53 -1.18 -0.123 0.20175E+04 15 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 19 spessartine 24.46 19.73 -4.73 -0.236 0.80727E+04 20 analcite 3.32 2.77 -0.55 -0.061 0.93624E+03 26 annite 20.12 17.72 -2.40 -0.134 0.41064E+04 27 phlogopite 27.06 25.40 -1.67 -0.093 0.28489E+04 29 anorthite 12.71 8.26 -4.45 -0.342 0.75903E+04 35 aragonite 0.97 -3.54 -4.50 -1.501 0.76891E+04 36 brucite 12.57 9.29 -3.27 -0.655 0.55909E+04 37 calcite 0.81 -3.54 -4.35 -1.449 0.74249E+04 38 carnegieite-low 9.02 5.93 -3.09 -0.442 0.52801E+04 39 carnegieite-high 10.09 5.93 -4.16 -0.595 0.71071E+04 40 carpholite-Mg 8.58 4.46 -4.12 -0.275 0.70429E+04 41 carpholite-Fe 6.71 1.90 -4.81 -0.321 0.82206E+04 42 celadonite 5.34 3.65 -1.69 -0.099 0.28879E+04 43 celadonite-Fe 3.88 1.09 -2.79 -0.164 0.47561E+04 44 chrysotile 23.89 21.57 -2.32 -0.194 0.39692E+04 49 chlorite-Al-free 47.17 43.14 -4.04 -0.168 0.68936E+04 51 chloritoid-Fe 9.17 5.06 -4.12 -0.275 0.70315E+04 52 chloritoid-Mn 11.40 7.56 -3.84 -0.256 0.65555E+04 54 coesite -2.38 -3.16 -0.78 -0.260 0.13341E+04 61 cristobalite -2.56 -3.16 -0.60 -0.199 0.10195E+04 63 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71234E+04 65 diaspore 2.87 0.74 -2.13 -0.356 0.36450E+04 66 diamond -3.10 -7.67 -4.57 -1.306 0.78039E+04 71 enstatite 17.26 12.27 -4.99 -0.499 0.85226E+04 73 clinoenstatite 17.17 12.27 -4.89 -0.489 0.83541E+04 75 epidote 24.67 22.70 -1.97 -0.095 0.33585E+04 76 clinozoisite 22.81 18.95 -3.86 -0.175 0.65868E+04 77 epidote-Fe 29.84 26.46 -3.38 -0.176 0.57768E+04 78 fayalite 14.05 10.31 -3.73 -0.533 0.63743E+04 79 ferrosilite 11.15 7.16 -3.99 -0.399 0.68202E+04 83 gibbsite 4.08 0.74 -3.34 -0.477 0.57035E+04 84 glaucophane 22.97 20.80 -2.17 -0.059 0.37133E+04 85 glaucophane-Fe 17.28 13.12 -4.15 -0.112 0.70919E+04 86 graphite -3.55 -7.67 -4.13 -1.179 0.70462E+04 87 greenalite 16.14 13.89 -2.25 -0.187 0.38408E+04 90 hematite 12.57 8.99 -3.58 -0.434 0.61111E+04 91 heulandite -5.83 -7.52 -1.69 -0.077 0.28938E+04 95 jadeite 4.22 2.77 -1.44 -0.144 0.24617E+04 97 kalsilite 7.58 3.83 -3.76 -0.537 0.64126E+04 98 kaolinite -1.33 -4.84 -3.50 -0.319 0.59831E+04 101 laumontite 2.88 1.95 -0.93 -0.062 0.15935E+04 102 lawsonite 9.62 8.26 -1.35 -0.090 0.23069E+04 103 leucite 4.12 0.67 -3.45 -0.345 0.58873E+04 105 lizardite 23.24 21.57 -1.68 -0.140 0.28618E+04 107 magnetite 20.09 15.72 -4.37 -0.356 0.74536E+04 108 minnesotaite 10.39 7.58 -2.81 -0.165 0.48028E+04 112 manganosite 14.06 9.24 -4.82 -1.204 0.82247E+04 120 muscovite 2.58 -1.01 -3.59 -0.211 0.61315E+04 121 paragonite 4.24 1.09 -3.15 -0.185 0.53706E+04 122 nepheline 8.34 5.93 -2.41 -0.344 0.41125E+04 128 periclase-Fe 11.63 6.73 -4.89 -1.223 0.83523E+04 134 phlogopite-Na 29.65 27.50 -2.15 -0.119 0.36677E+04 136 prehnite 19.37 18.21 -1.16 -0.068 0.19849E+04 137 prehnite-Fe 22.50 21.96 -0.53 -0.032 0.91157E+03 138 pumpellyite-Fe 46.27 43.89 -2.38 -0.053 0.40581E+04 139 pumpellyite-Mg 48.99 46.45 -2.54 -0.057 0.43419E+04 143 pyrrhotite -4.26 -7.88 -3.62 -1.205 0.61745E+04 144 pyrrhotiteFe0.875 -6.02 -9.27 -3.26 -1.198 0.55617E+04 145 pyroxmangite 7.40 6.08 -1.31 -0.263 0.22451E+04 146 pyrophyllite -6.18 -11.15 -4.98 -0.311 0.84962E+04 147 quartz -2.99 -3.16 -0.17 -0.056 0.28681E+03 152 rhodonite 7.45 6.08 -1.36 -0.272 0.23253E+04 153 sanidine -1.28 -2.49 -1.21 -0.093 0.20677E+04 165 stilpnomelane-Mg 27.44 25.81 -1.63 -0.049 0.27803E+04 171 talc 16.49 15.25 -1.24 -0.073 0.21140E+04 174 tephroite 18.09 15.33 -2.76 -0.394 0.47139E+04 178 tridymite -2.63 -3.16 -0.53 -0.177 0.90679E+03 179 tremolite 47.87 47.42 -0.45 -0.012 0.77495E+03 180 ferroactinolite 38.45 34.62 -3.83 -0.104 0.65449E+04 181 troilite-low -4.41 -7.88 -3.47 -1.155 0.59173E+04 183 vesuvianite 223.47 218.82 -4.65 -0.036 0.79436E+04 187 wairakite 3.95 1.95 -2.00 -0.118 0.34154E+04 188 walstromite 11.51 9.94 -1.56 -0.313 0.26719E+04 189 wollastonite 10.46 9.94 -0.52 -0.103 0.88229E+03 190 pseudo-wollastonite 11.00 9.94 -1.06 -0.211 0.18021E+04 191 zoisite 22.85 18.95 -3.90 -0.177 0.66609E+04 192 akaganeite 7.75 4.49 -3.26 -0.705 0.55681E+04 199 chalcedony -2.80 -3.16 -0.35 -0.118 0.60611E+03 201 montmorillonite-Ca -2.29 -6.17 -3.88 -0.240 0.66180E+04 202 montmorillonite-K -2.24 -6.27 -4.03 -0.247 0.68816E+04 203 montmorillonite-Mg -2.48 -6.79 -4.32 -0.267 0.73678E+04 204 montmorillonite-Na -2.04 -5.57 -3.54 -0.216 0.60365E+04 205 nontronite-Ca 3.21 -0.19 -3.41 -0.221 0.58215E+04 206 nontronite-H 2.53 -2.36 -4.89 -0.328 0.83485E+04 207 nontronite-K 3.34 -0.30 -3.64 -0.233 0.62083E+04 208 nontronite-Mg 3.07 -0.82 -3.90 -0.253 0.66553E+04 209 nontronite-Na 3.52 0.40 -3.12 -0.200 0.53292E+04 224 tobermorite 9.82 7.76 -2.07 -0.564 0.35287E+04 230 alabandite -0.98 -5.37 -4.39 -1.464 0.74998E+04 233 boehmite 4.41 0.74 -3.67 -0.611 0.62619E+04 235 ferrous-oxide 9.81 6.73 -3.08 -0.769 0.52532E+04 240 silica-amorphous -2.09 -3.16 -1.07 -0.355 0.18203E+04 242 an20ab80 2.02 1.35 -0.67 -0.052 0.11472E+04 243 an25ab75 2.65 1.78 -0.87 -0.067 0.14810E+04 244 an30ab70 3.28 2.21 -1.07 -0.082 0.18244E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 100.0000000 g Current total amount of reactant added: 3499.9990000 g New total amount of reactant added: 3599.9990000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.5221E-10 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 11 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 3599.9990000 Water: Moles liquid = 0.3535E+02 kg liquid = 0.6369E+00 Moles total = 0.1038E+02 kg total = 0.1870E+00 Activity = 1.0000 Stoichiometric ionic strength = .1138280E-01 Osmotic coef. = 0.9688 True ionic strength = .2005887E-01 Chg. balance for total moles = 0.5221E-10 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.88470E-10 -10.0532 0.74328E-10 -10.1288 0.84015E+00 -0.0756 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.21563E-03 -3.6663 0.18007E-03 -3.7446 0.83509E+00 -0.0783 4 SO4-- 0.10152E-11 -11.9934 0.52694E-12 -12.2782 0.51903E+00 -0.2848 5 HCO3- 0.37564E-06 -6.4252 0.31415E-06 -6.5029 0.83631E+00 -0.0776 6 HS- 0.40035E-04 -4.3976 0.33438E-04 -4.4758 0.83521E+00 -0.0782 7 Al+++ 0.97563E-29 -29.0107 0.22513E-29 -29.6476 0.23075E+00 -0.6369 8 H4SiO4 0.69597E-03 -3.1574 0.69597E-03 -3.1574 0.10000E+01 0.0000 9 Ca++ 0.13556E-06 -6.8679 0.69845E-07 -7.1559 0.51522E+00 -0.2880 10 Mg++ 0.21208E-10 -10.6735 0.10877E-10 -10.9635 0.51286E+00 -0.2900 11 Fe++ 0.58453E-13 -13.2332 0.30011E-13 -13.5227 0.51342E+00 -0.2895 12 K+ 0.15683E-03 -3.8046 0.13119E-03 -3.8821 0.83651E+00 -0.0775 13 Na+ 0.19901E-01 -1.7011 0.16616E-01 -1.7795 0.83493E+00 -0.0783 14 Mn++ 0.18739E-10 -10.7273 0.96288E-11 -11.0164 0.51385E+00 -0.2892 15 HPO4-- 0.45174E-07 -7.3451 0.23450E-07 -7.6299 0.51911E+00 -0.2847 16 HSiO3- 0.10470E-01 -1.9801 0.87432E-02 -2.0583 0.83509E+00 -0.0783 17 Ca(HSiO3)+ 0.16622E-07 -7.7793 0.13907E-07 -7.8568 0.83669E+00 -0.0774 18 Mg(HSiO3)+ 0.32214E-11 -11.4920 0.26953E-11 -11.5694 0.83669E+00 -0.0774 19 NaHSiO3,aq 0.23496E-02 -2.6290 0.23496E-02 -2.6290 0.10000E+01 0.0000 20 AlO+ 0.66259E-16 -16.1788 0.55438E-16 -16.2562 0.83669E+00 -0.0774 22 HAlO2,aq 0.14854E-09 -9.8282 0.14854E-09 -9.8282 0.10000E+01 0.0000 23 AlO2- 0.53068E-05 -5.2752 0.44236E-05 -5.3542 0.83358E+00 -0.0791 24 CH4,aq 0.19431E-04 -4.7115 0.19364E-04 -4.7130 0.99653E+00 -0.0015 25 C2H6,aq 0.55536E-14 -14.2554 0.55343E-14 -14.2569 0.99653E+00 -0.0015 29 CO,aq 0.14517E-16 -16.8381 0.14517E-16 -16.8381 0.10000E+01 0.0000 30 CO2,aq 0.50067E-10 -10.3004 0.49894E-10 -10.3020 0.99653E+00 -0.0015 31 CO3-2 0.71278E-06 -6.1470 0.36917E-06 -6.4328 0.51793E+00 -0.2857 32 CaCO3,aq 0.32331E-09 -9.4904 0.32331E-09 -9.4904 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.66941E-12 -12.1743 0.56008E-12 -12.2517 0.83669E+00 -0.0774 34 CaCl+ 0.24326E-10 -10.6139 0.20353E-10 -10.6914 0.83669E+00 -0.0774 35 CaCl2,aq 0.87074E-15 -15.0601 0.87074E-15 -15.0601 0.10000E+01 0.0000 36 CaOH+ 0.80043E-07 -7.0967 0.66971E-07 -7.1741 0.83669E+00 -0.0774 37 CaSO4,aq 0.11687E-16 -16.9323 0.11687E-16 -16.9323 0.10000E+01 0.0000 38 HCl,aq 0.24526E-14 -14.6104 0.24526E-14 -14.6104 0.10000E+01 0.0000 43 FeCl+ 0.10223E-16 -16.9904 0.85537E-17 -17.0678 0.83669E+00 -0.0774 46 FeO,aq 0.21113E-09 -9.6755 0.21113E-09 -9.6755 0.10000E+01 0.0000 47 FeOH+ 0.15708E-10 -10.8039 0.13143E-10 -10.8813 0.83669E+00 -0.0774 48 HFeO2- 0.35589E-07 -7.4487 0.29720E-07 -7.5269 0.83509E+00 -0.0783 49 FeO+ 0.11009E-16 -16.9583 0.92111E-17 -17.0357 0.83669E+00 -0.0774 51 FeO2- 0.40853E-09 -9.3888 0.34116E-09 -9.4670 0.83509E+00 -0.0783 52 HFeO2,aq 0.32251E-11 -11.4915 0.32251E-11 -11.4915 0.10000E+01 0.0000 53 H2,aq 0.11623E-04 -4.9347 0.11583E-04 -4.9362 0.99653E+00 -0.0015 54 KCl,aq 0.42815E-09 -9.3684 0.42815E-09 -9.3684 0.10000E+01 0.0000 56 KOH,aq 0.75375E-06 -6.1228 0.75375E-06 -6.1228 0.10000E+01 0.0000 57 KSO4- 0.12846E-14 -14.8912 0.10727E-14 -14.9695 0.83509E+00 -0.0783 58 MgCO3,aq 0.12620E-13 -13.8989 0.12620E-13 -13.8989 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.10652E-15 -15.9726 0.89123E-16 -16.0500 0.83669E+00 -0.0774 60 MgCl+ 0.34335E-14 -14.4643 0.28727E-14 -14.5417 0.83669E+00 -0.0774 61 MgOH+ 0.68974E-10 -10.1613 0.57710E-10 -10.2387 0.83669E+00 -0.0774 63 MnO,aq 0.18049E-08 -8.7435 0.18049E-08 -8.7435 0.10000E+01 0.0000 64 MnOH+ 0.46819E-09 -9.3296 0.39173E-09 -9.4070 0.83669E+00 -0.0774 65 MnO2-2 0.20934E-10 -10.6791 0.10843E-10 -10.9649 0.51793E+00 -0.2857 66 HMnO2- 0.21143E-09 -9.6748 0.17656E-09 -9.7531 0.83509E+00 -0.0783 69 MnCl+ 0.12761E-13 -13.8941 0.10677E-13 -13.9716 0.83669E+00 -0.0774 71 NaCl,aq 0.99156E-06 -6.0037 0.99156E-06 -6.0037 0.10000E+01 0.0000 72 NaOH,aq 0.96047E-04 -4.0175 0.96047E-04 -4.0175 0.10000E+01 0.0000 74 OH- 0.93253E-02 -2.0303 0.77733E-02 -2.1094 0.83358E+00 -0.0791 79 HPO3-2 0.16343E-14 -14.7867 0.84646E-15 -15.0724 0.51793E+00 -0.2857 81 H2PO3- 0.15108E-18 -18.8208 0.12616E-18 -18.8991 0.83509E+00 -0.0783 82 H3PO4,aq 0.90609E-18 -18.0428 0.90609E-18 -18.0428 0.10000E+01 0.0000 83 H2PO4- 0.38467E-10 -10.4149 0.32154E-10 -10.4928 0.83588E+00 -0.0779 84 PO4-3 0.10620E-08 -8.9739 0.25741E-09 -9.5894 0.24238E+00 -0.6155 88 HP2O7-3 0.94282E-18 -18.0256 0.21778E-18 -18.6620 0.23098E+00 -0.6364 89 P2O7-4 0.90967E-17 -17.0411 0.69995E-18 -18.1549 0.76946E-01 -1.1138 90 H2S,aq 0.77080E-08 -8.1131 0.76812E-08 -8.1146 0.99653E+00 -0.0015 91 S2-2 0.41297E-14 -14.3841 0.21389E-14 -14.6698 0.51793E+00 -0.2857 97 SO3-2 0.15095E-17 -17.8212 0.79314E-18 -18.1006 0.52543E+00 -0.2795 99 HSO4- 0.45069E-19 -19.3461 0.37745E-19 -19.4231 0.83750E+00 -0.0770 Charge balance for all species = 0.8201E-10 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.8847011E-10 -.2226654E-01 -.2240429E+02 0.0000 2 H2O 0.1000000E+01 0.5550489E+02 0.9981976E+06 0.0000 3 Cl- 0.2156311E-03 0.2166231E-03 0.7666577E+01 6.3843 4 SO4-- 0.1015243E-11 -.2233717E-04 -.2142011E+01 7.9795 5 HCO3- 0.3756386E-06 0.2052024E-04 0.1249909E+01 3.6260 6 HS- 0.4003498E-04 0.6237986E-04 0.2059438E+01 5.6531 7 Al+++ 0.9756343E-29 0.5306968E-05 0.1429408E+00 0.7390 8 H4SiO4 0.6959736E-03 0.1351540E-01 0.1296778E+04 -3.1574 9 Ca++ 0.1355639E-06 0.2325769E-06 0.9304999E-02 13.1018 10 Mg++ 0.2120816E-10 0.9341999E-10 0.2267275E-05 9.2942 11 Fe++ 0.5845303E-13 0.3622813E-07 0.2019712E-02 6.7350 12 K+ 0.1568283E-03 0.1575825E-03 0.6151069E+01 6.2467 13 Na+ 0.1990078E-01 0.2234743E-01 0.5128692E+03 8.3494 14 Mn++ 0.1873871E-10 0.2524247E-08 0.1384358E-03 9.2413 15 HPO4-- 0.4517428E-07 0.4627478E-07 0.4433680E-02 12.6278 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.5961063E+02 -.1418227E-01 -.5959644E+02 0.0000000E+00 2 H2O 0.1038079E+02 0.3535284E+02 -.2497206E+02 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.9979375E-01 -.1422726E-04 0.9980798E-01 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.9976824E-01 0.3973173E-04 -.9980798E-01 0.0000000E+00 7 Al+++ 0.1173867E+02 0.3380177E-05 0.1173866E+02 0.0000000E+00 8 H4SiO4 0.3748601E+02 0.8608389E-02 0.3747740E+02 0.0000000E+00 9 Ca++ 0.4140527E+01 0.1481356E-06 0.4140527E+01 0.0000000E+00 10 Mg++ 0.2857142E+01 0.5950218E-10 0.2857142E+01 0.0000000E+00 11 Fe++ 0.2566830E+01 0.2307486E-07 0.2566830E+01 0.0000000E+00 12 K+ 0.7643310E+00 0.1003693E-03 0.7642306E+00 0.0000000E+00 13 Na+ 0.4519036E+01 0.1423380E-01 0.4504802E+01 0.0000000E+00 14 Mn++ 0.6241893E-01 0.1607773E-08 0.6241893E-01 0.0000000E+00 15 HPO4-- 0.2130327E-01 0.2947389E-07 0.2130324E-01 0.0000000E+00 Chg. balance for solid moles: 0.4802E-14 Mass of aqueous solution: 0.638042E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 3599.9990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 4.501 0.653 1180. 3.072 30.01 453.1 andradite 0.3992 -0.399 202.9 2.307 5.159 52.71 grossular 0.9667E-01 -1.015 43.55 1.639 1.107 12.12 apatite-OH 0.7101E-02 -2.149 3.567 0.552 0.9070E-01 1.133 clinochlore 0.5118 -0.291 284.5 2.454 7.233 108.2 daphnite 0.1482 -0.829 105.7 2.024 2.688 32.03 chlorite-Mn 0.1248E-01 -1.904 8.851 0.947 0.2250 2.820 diopside 0.1865 -0.729 40.40 1.606 1.027 12.35 hedenbergite 0.4838E-01 -1.315 12.00 1.079 0.3052 3.287 microcline 0.6702 -0.174 186.5 2.271 4.743 72.86 stilbite 2.321 0.366 1635. 3.214 41.59 762.8 stilpnomelane-Fe 0.1881 -0.726 202.8 2.307 5.157 70.06 tr.625ac.25prg.125 0.3081E-01 -1.511 26.33 1.421 0.6696 8.476 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8051E+00 0.8051E+00 1.0000 -0.094 grossular 0.1949E+00 0.1949E+00 1.0000 -0.710 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.7611E+00 0.7611E+00 1.0000 -0.119 daphnite 0.2203E+00 0.2203E+00 1.0000 -0.657 chlorite-Mn 0.1857E-01 0.1857E-01 1.0000 -1.731 diopside 0.7941E+00 0.7941E+00 1.0000 -0.100 hedenbergite 0.2059E+00 0.2059E+00 1.0000 -0.686 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 tr.625ac.25prg.125 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 3932.828556 g Volume = 1591.934960 cm3 Porosity: -10.4744% V(tot) - V(min): -.15094E+03 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 3599.9990000 g log = 3.5563 Original solution: 1000.0103000 g Original solution / Rock added: 0.28 (Water/Rock Ratio), log = -0.5563 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0643 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9593E+00 0.9854 0.1006E+01 0.1021E+01 CO2,gas 0.4982E-08 1.0068 0.5338E-08 0.5302E-08 CH4,gas 0.2646E-01 1.0123 0.2850E-01 0.2816E-01 H2,gas 0.1428E-01 1.0006 0.1521E-01 0.1520E-01 H2S,gas 0.1992E-06 0.9959 0.2112E-06 0.2120E-06 S2,gas 0.6800E-29 1.0000 0.7237E-29 0.7237E-29 CO,gas 0.2033E-13 1.0000 0.2163E-13 0.2163E-13 SO3,gas 0.1034E-47 1.0000 0.1101E-47 0.1101E-47 SO2,gas 0.6119E-27 1.0000 0.6512E-27 0.6512E-27 HCl,gas 0.4066E-17 1.0000 0.4328E-17 0.4328E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 16 albite -0.38 -0.38 0.00 0.000 -0.13080E-10 22 andradite 39.01 39.01 0.00 0.000 -0.12132E-10 23 grossular 32.73 32.73 0.00 0.000 0.36397E-10 32 apatite-OH -18.15 -18.15 0.00 0.000 0.00000E+00 46 clinochlore 39.07 39.07 0.00 0.000 -0.36397E-10 47 daphnite 28.97 28.97 0.00 0.000 -0.36397E-10 48 chlorite-Mn 46.87 46.87 0.00 0.000 -0.24265E-10 67 diopside 16.18 16.18 0.00 0.000 -0.60662E-11 68 hedenbergite 14.21 14.21 0.00 0.000 -0.15165E-10 116 microcline -2.49 -2.49 0.00 0.000 -0.10616E-10 163 stilbite -7.52 -7.52 0.00 0.000 -0.90992E-11 164 stilpnomelane-Fe 13.02 13.02 0.00 0.000 -0.27298E-10 245 tr.625ac.25prg.125 45.16 45.16 0.00 0.000 -0.60662E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -16.63 -9.97 -3.324 0.17026E+05 -8.273 3 CH4,gas 4.54 1.30 -3.24 -0.811 0.55392E+04 -1.545 4 H2,gas 8.00 4.48 -3.52 -2.010 0.60051E+04 -1.818 5 H2S,gas -6.23 -14.60 -8.37 -4.187 0.14299E+05 -6.675 6 S2,gas -7.34 -38.17 -30.84 -4.745 0.52657E+05 -29.140 7 CO,gas 3.21 -12.15 -15.36 -4.727 0.26233E+05 -13.665 8 SO3,gas 17.12 -32.54 -49.66 -12.414 0.84788E+05 -47.958 9 SO2,gas 0.83 -28.05 -28.89 -7.703 0.49321E+05 -27.186 10 HCl,gas 5.19 -13.87 -19.06 -9.531 0.32549E+05 -17.364 11 acmite 7.71 6.53 -1.18 -0.123 0.20175E+04 15 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 19 spessartine 24.46 19.73 -4.73 -0.236 0.80726E+04 20 analcite 3.32 2.77 -0.55 -0.061 0.93624E+03 26 annite 20.12 17.72 -2.40 -0.134 0.41064E+04 27 phlogopite 27.06 25.40 -1.67 -0.093 0.28489E+04 29 anorthite 12.71 8.26 -4.45 -0.342 0.75903E+04 35 aragonite 0.97 -3.53 -4.50 -1.499 0.76775E+04 36 brucite 12.57 9.29 -3.27 -0.655 0.55909E+04 37 calcite 0.81 -3.53 -4.34 -1.447 0.74133E+04 38 carnegieite-low 9.02 5.93 -3.09 -0.442 0.52801E+04 39 carnegieite-high 10.09 5.93 -4.16 -0.595 0.71071E+04 40 carpholite-Mg 8.58 4.46 -4.12 -0.275 0.70429E+04 41 carpholite-Fe 6.71 1.90 -4.81 -0.321 0.82206E+04 42 celadonite 5.34 3.65 -1.69 -0.099 0.28879E+04 43 celadonite-Fe 3.88 1.09 -2.79 -0.164 0.47561E+04 44 chrysotile 23.89 21.57 -2.32 -0.194 0.39692E+04 49 chlorite-Al-free 47.17 43.14 -4.04 -0.168 0.68936E+04 51 chloritoid-Fe 9.17 5.06 -4.12 -0.275 0.70315E+04 52 chloritoid-Mn 11.40 7.56 -3.84 -0.256 0.65554E+04 54 coesite -2.38 -3.16 -0.78 -0.260 0.13341E+04 61 cristobalite -2.56 -3.16 -0.60 -0.199 0.10195E+04 63 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71234E+04 65 diaspore 2.87 0.74 -2.13 -0.356 0.36450E+04 66 diamond -3.10 -7.67 -4.56 -1.304 0.77923E+04 71 enstatite 17.26 12.27 -4.99 -0.499 0.85226E+04 73 clinoenstatite 17.17 12.27 -4.89 -0.489 0.83541E+04 75 epidote 24.67 22.70 -1.97 -0.095 0.33585E+04 76 clinozoisite 22.81 18.95 -3.86 -0.175 0.65868E+04 77 epidote-Fe 29.84 26.46 -3.38 -0.176 0.57768E+04 78 fayalite 14.05 10.31 -3.73 -0.533 0.63743E+04 79 ferrosilite 11.15 7.16 -3.99 -0.399 0.68202E+04 83 gibbsite 4.08 0.74 -3.34 -0.477 0.57035E+04 84 glaucophane 22.97 20.80 -2.17 -0.059 0.37133E+04 85 glaucophane-Fe 17.28 13.12 -4.15 -0.112 0.70919E+04 86 graphite -3.55 -7.67 -4.12 -1.177 0.70346E+04 87 greenalite 16.14 13.89 -2.25 -0.187 0.38408E+04 90 hematite 12.57 8.99 -3.58 -0.434 0.61111E+04 91 heulandite -5.83 -7.52 -1.69 -0.077 0.28938E+04 95 jadeite 4.22 2.77 -1.44 -0.144 0.24617E+04 97 kalsilite 7.58 3.83 -3.76 -0.537 0.64126E+04 98 kaolinite -1.33 -4.84 -3.50 -0.319 0.59831E+04 101 laumontite 2.88 1.95 -0.93 -0.062 0.15935E+04 102 lawsonite 9.62 8.26 -1.35 -0.090 0.23069E+04 103 leucite 4.12 0.67 -3.45 -0.345 0.58873E+04 105 lizardite 23.24 21.57 -1.68 -0.140 0.28618E+04 107 magnetite 20.09 15.72 -4.37 -0.356 0.74536E+04 108 minnesotaite 10.39 7.58 -2.81 -0.165 0.48028E+04 112 manganosite 14.06 9.24 -4.82 -1.204 0.82246E+04 120 muscovite 2.58 -1.01 -3.59 -0.211 0.61315E+04 121 paragonite 4.24 1.09 -3.15 -0.185 0.53706E+04 122 nepheline 8.34 5.93 -2.41 -0.344 0.41125E+04 128 periclase-Fe 11.63 6.73 -4.89 -1.223 0.83523E+04 134 phlogopite-Na 29.65 27.50 -2.15 -0.119 0.36677E+04 136 prehnite 19.37 18.21 -1.16 -0.068 0.19849E+04 137 prehnite-Fe 22.50 21.96 -0.53 -0.032 0.91157E+03 138 pumpellyite-Fe 46.27 43.89 -2.38 -0.053 0.40581E+04 139 pumpellyite-Mg 48.99 46.45 -2.54 -0.057 0.43419E+04 143 pyrrhotite -4.26 -7.87 -3.61 -1.203 0.61628E+04 144 pyrrhotiteFe0.875 -6.02 -9.27 -3.25 -1.195 0.55500E+04 145 pyroxmangite 7.40 6.08 -1.31 -0.263 0.22450E+04 146 pyrophyllite -6.18 -11.15 -4.98 -0.311 0.84962E+04 147 quartz -2.99 -3.16 -0.17 -0.056 0.28681E+03 152 rhodonite 7.45 6.08 -1.36 -0.272 0.23253E+04 153 sanidine -1.28 -2.49 -1.21 -0.093 0.20677E+04 165 stilpnomelane-Mg 27.44 25.81 -1.63 -0.049 0.27803E+04 171 talc 16.49 15.25 -1.24 -0.073 0.21140E+04 174 tephroite 18.09 15.33 -2.76 -0.394 0.47137E+04 178 tridymite -2.63 -3.16 -0.53 -0.177 0.90678E+03 179 tremolite 47.87 47.42 -0.45 -0.012 0.77495E+03 180 ferroactinolite 38.45 34.62 -3.83 -0.104 0.65449E+04 181 troilite-low -4.41 -7.87 -3.46 -1.153 0.59056E+04 183 vesuvianite 223.47 218.82 -4.65 -0.036 0.79436E+04 187 wairakite 3.95 1.95 -2.00 -0.118 0.34154E+04 188 walstromite 11.51 9.94 -1.56 -0.313 0.26719E+04 189 wollastonite 10.46 9.94 -0.52 -0.103 0.88229E+03 190 pseudo-wollastonite 11.00 9.94 -1.06 -0.211 0.18021E+04 191 zoisite 22.85 18.95 -3.90 -0.177 0.66609E+04 192 akaganeite 7.75 4.49 -3.26 -0.705 0.55681E+04 199 chalcedony -2.80 -3.16 -0.35 -0.118 0.60610E+03 201 montmorillonite-Ca -2.29 -6.17 -3.88 -0.240 0.66180E+04 202 montmorillonite-K -2.24 -6.27 -4.03 -0.247 0.68816E+04 203 montmorillonite-Mg -2.48 -6.79 -4.32 -0.267 0.73678E+04 204 montmorillonite-Na -2.04 -5.57 -3.54 -0.216 0.60365E+04 205 nontronite-Ca 3.21 -0.19 -3.41 -0.221 0.58215E+04 206 nontronite-H 2.53 -2.36 -4.89 -0.328 0.83485E+04 207 nontronite-K 3.34 -0.30 -3.64 -0.233 0.62083E+04 208 nontronite-Mg 3.07 -0.82 -3.90 -0.253 0.66553E+04 209 nontronite-Na 3.52 0.40 -3.12 -0.200 0.53292E+04 224 tobermorite 9.82 7.76 -2.07 -0.564 0.35287E+04 230 alabandite -0.98 -5.36 -4.39 -1.462 0.74881E+04 233 boehmite 4.41 0.74 -3.67 -0.611 0.62619E+04 235 ferrous-oxide 9.81 6.73 -3.08 -0.769 0.52532E+04 240 silica-amorphous -2.09 -3.16 -1.07 -0.355 0.18203E+04 242 an20ab80 2.02 1.35 -0.67 -0.052 0.11472E+04 243 an25ab75 2.65 1.78 -0.87 -0.067 0.14810E+04 244 an30ab70 3.28 2.21 -1.07 -0.082 0.18244E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 100.0000000 g Current total amount of reactant added: 3599.9990000 g New total amount of reactant added: 3699.9990000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.5222E-10 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 11 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 3699.9990000 Water: Moles liquid = 0.3480E+02 kg liquid = 0.6269E+00 Moles total = 0.9127E+01 kg total = 0.1644E+00 Activity = 1.0000 Stoichiometric ionic strength = .1138568E-01 Osmotic coef. = 0.9688 True ionic strength = .2006111E-01 Chg. balance for total moles = 0.5222E-10 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.88480E-10 -10.0532 0.74335E-10 -10.1288 0.84014E+00 -0.0756 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.21909E-03 -3.6594 0.18295E-03 -3.7377 0.83508E+00 -0.0783 4 SO4-- 0.10314E-11 -11.9866 0.53533E-12 -12.2714 0.51902E+00 -0.2848 5 HCO3- 0.38162E-06 -6.4184 0.31915E-06 -6.4960 0.83630E+00 -0.0776 6 HS- 0.40676E-04 -4.3907 0.33973E-04 -4.4689 0.83520E+00 -0.0782 7 Al+++ 0.97600E-29 -29.0105 0.22520E-29 -29.6474 0.23074E+00 -0.6369 8 H4SiO4 0.69597E-03 -3.1574 0.69597E-03 -3.1574 0.10000E+01 0.0000 9 Ca++ 0.13560E-06 -6.8678 0.69859E-07 -7.1558 0.51520E+00 -0.2880 10 Mg++ 0.21213E-10 -10.6734 0.10879E-10 -10.9634 0.51284E+00 -0.2900 11 Fe++ 0.58467E-13 -13.2331 0.30017E-13 -13.5226 0.51340E+00 -0.2895 12 K+ 0.15685E-03 -3.8045 0.13120E-03 -3.8821 0.83650E+00 -0.0775 13 Na+ 0.19903E-01 -1.7011 0.16618E-01 -1.7794 0.83493E+00 -0.0784 14 Mn++ 0.18744E-10 -10.7271 0.96314E-11 -11.0163 0.51383E+00 -0.2892 15 HPO4-- 0.45166E-07 -7.3452 0.23445E-07 -7.6299 0.51909E+00 -0.2848 16 HSiO3- 0.10469E-01 -1.9801 0.87423E-02 -2.0584 0.83508E+00 -0.0783 17 Ca(HSiO3)+ 0.16624E-07 -7.7793 0.13909E-07 -7.8567 0.83668E+00 -0.0774 18 Mg(HSiO3)+ 0.32217E-11 -11.4919 0.26956E-11 -11.5694 0.83668E+00 -0.0774 19 NaHSiO3,aq 0.23496E-02 -2.6290 0.23496E-02 -2.6290 0.10000E+01 0.0000 20 AlO+ 0.66266E-16 -16.1787 0.55444E-16 -16.2561 0.83668E+00 -0.0774 22 HAlO2,aq 0.14854E-09 -9.8282 0.14854E-09 -9.8282 0.10000E+01 0.0000 23 AlO2- 0.53063E-05 -5.2752 0.44232E-05 -5.3543 0.83357E+00 -0.0791 24 CH4,aq 0.19743E-04 -4.7046 0.19674E-04 -4.7061 0.99653E+00 -0.0015 25 C2H6,aq 0.57330E-14 -14.2416 0.57131E-14 -14.2431 0.99653E+00 -0.0015 29 CO,aq 0.14750E-16 -16.8312 0.14750E-16 -16.8312 0.10000E+01 0.0000 30 CO2,aq 0.50870E-10 -10.2935 0.50694E-10 -10.2950 0.99653E+00 -0.0015 31 CO3-2 0.72408E-06 -6.1402 0.37501E-06 -6.4260 0.51791E+00 -0.2857 32 CaCO3,aq 0.32850E-09 -9.4835 0.32850E-09 -9.4835 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.68022E-12 -12.1674 0.56912E-12 -12.2448 0.83668E+00 -0.0774 34 CaCl+ 0.24721E-10 -10.6069 0.20684E-10 -10.6844 0.83668E+00 -0.0774 35 CaCl2,aq 0.89903E-15 -15.0462 0.89903E-15 -15.0462 0.10000E+01 0.0000 36 CaOH+ 0.80052E-07 -7.0966 0.66978E-07 -7.1741 0.83668E+00 -0.0774 37 CaSO4,aq 0.11876E-16 -16.9253 0.11876E-16 -16.9253 0.10000E+01 0.0000 38 HCl,aq 0.24921E-14 -14.6034 0.24921E-14 -14.6034 0.10000E+01 0.0000 43 FeCl+ 0.10389E-16 -16.9834 0.86925E-17 -17.0609 0.83668E+00 -0.0774 46 FeO,aq 0.21113E-09 -9.6755 0.21113E-09 -9.6755 0.10000E+01 0.0000 47 FeOH+ 0.15710E-10 -10.8038 0.13144E-10 -10.8813 0.83668E+00 -0.0774 48 HFeO2- 0.35586E-07 -7.4487 0.29717E-07 -7.5270 0.83508E+00 -0.0783 49 FeO+ 0.11010E-16 -16.9582 0.92121E-17 -17.0356 0.83668E+00 -0.0774 51 FeO2- 0.40850E-09 -9.3888 0.34113E-09 -9.4671 0.83508E+00 -0.0783 52 HFeO2,aq 0.32251E-11 -11.4915 0.32251E-11 -11.4915 0.10000E+01 0.0000 53 H2,aq 0.11623E-04 -4.9347 0.11583E-04 -4.9362 0.99653E+00 -0.0015 54 KCl,aq 0.43505E-09 -9.3615 0.43505E-09 -9.3615 0.10000E+01 0.0000 56 KOH,aq 0.75375E-06 -6.1228 0.75375E-06 -6.1228 0.10000E+01 0.0000 57 KSO4- 0.13051E-14 -14.8843 0.10899E-14 -14.9626 0.83508E+00 -0.0783 58 MgCO3,aq 0.12823E-13 -13.8920 0.12823E-13 -13.8920 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.10824E-15 -15.9656 0.90562E-16 -16.0431 0.83668E+00 -0.0774 60 MgCl+ 0.34892E-14 -14.4573 0.29193E-14 -14.5347 0.83668E+00 -0.0774 61 MgOH+ 0.68982E-10 -10.1613 0.57716E-10 -10.2387 0.83668E+00 -0.0774 63 MnO,aq 0.18051E-08 -8.7435 0.18051E-08 -8.7435 0.10000E+01 0.0000 64 MnOH+ 0.46827E-09 -9.3295 0.39180E-09 -9.4069 0.83668E+00 -0.0774 65 MnO2-2 0.20932E-10 -10.6792 0.10841E-10 -10.9649 0.51791E+00 -0.2857 66 HMnO2- 0.21142E-09 -9.6748 0.17655E-09 -9.7531 0.83508E+00 -0.0783 69 MnCl+ 0.12969E-13 -13.8871 0.10851E-13 -13.9645 0.83668E+00 -0.0774 71 NaCl,aq 0.10075E-05 -5.9967 0.10075E-05 -5.9967 0.10000E+01 0.0000 72 NaOH,aq 0.96047E-04 -4.0175 0.96047E-04 -4.0175 0.10000E+01 0.0000 74 OH- 0.93244E-02 -2.0304 0.77725E-02 -2.1094 0.83357E+00 -0.0791 79 HPO3-2 0.16340E-14 -14.7867 0.84628E-15 -15.0725 0.51791E+00 -0.2857 81 H2PO3- 0.15106E-18 -18.8208 0.12615E-18 -18.8991 0.83508E+00 -0.0783 82 H3PO4,aq 0.90609E-18 -18.0428 0.90609E-18 -18.0428 0.10000E+01 0.0000 83 H2PO4- 0.38463E-10 -10.4150 0.32150E-10 -10.4928 0.83587E+00 -0.0779 84 PO4-3 0.10618E-08 -8.9740 0.25733E-09 -9.5895 0.24236E+00 -0.6155 88 HP2O7-3 0.94259E-18 -18.0257 0.21771E-18 -18.6621 0.23097E+00 -0.6364 89 P2O7-4 0.90940E-17 -17.0412 0.69967E-18 -18.1551 0.76937E-01 -1.1139 90 H2S,aq 0.78322E-08 -8.1061 0.78050E-08 -8.1076 0.99653E+00 -0.0015 91 S2-2 0.42631E-14 -14.3703 0.22079E-14 -14.6560 0.51791E+00 -0.2857 97 SO3-2 0.15336E-17 -17.8143 0.80577E-18 -18.0938 0.52542E+00 -0.2795 99 HSO4- 0.45791E-19 -19.3392 0.38350E-19 -19.4162 0.83750E+00 -0.0770 Charge balance for all species = 0.8330E-10 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.8847990E-10 -.2226466E-01 -.2240239E+02 0.0000 2 H2O 0.1000000E+01 0.5550490E+02 0.9981975E+06 0.0000 3 Cl- 0.2190854E-03 0.2200934E-03 0.7789393E+01 6.3911 4 SO4-- 0.1031430E-11 -.2264861E-04 -.2171876E+01 7.9862 5 HCO3- 0.3816249E-06 0.2084897E-04 0.1269933E+01 3.6328 6 HS- 0.4067633E-04 0.6333277E-04 0.2090897E+01 5.6599 7 Al+++ 0.9760007E-29 0.5306446E-05 0.1429267E+00 0.7390 8 H4SiO4 0.6959742E-03 0.1351440E-01 0.1296682E+04 -3.1574 9 Ca++ 0.1355959E-06 0.2326252E-06 0.9306930E-02 13.1018 10 Mg++ 0.2121318E-10 0.9343246E-10 0.2267578E-05 9.2942 11 Fe++ 0.5846689E-13 0.3622466E-07 0.2019519E-02 6.7350 12 K+ 0.1568457E-03 0.1575999E-03 0.6151748E+01 6.2467 13 Na+ 0.1990299E-01 0.2234967E-01 0.5129203E+03 8.3494 14 Mn++ 0.1874441E-10 0.2524447E-08 0.1384468E-03 9.2413 15 HPO4-- 0.4516629E-07 0.4626653E-07 0.4432889E-02 12.6277 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.6126648E+02 -.1395748E-01 -.6125252E+02 0.0000000E+00 2 H2O 0.9127245E+01 0.3479543E+02 -.2566818E+02 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.1025651E+00 -.1419817E-04 0.1025793E+00 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.1025396E+00 0.3970264E-04 -.1025793E+00 0.0000000E+00 7 Al+++ 0.1206474E+02 0.3326554E-05 0.1206474E+02 0.0000000E+00 8 H4SiO4 0.3852729E+02 0.8472034E-02 0.3851881E+02 0.0000000E+00 9 Ca++ 0.4255541E+01 0.1458302E-06 0.4255541E+01 0.0000000E+00 10 Mg++ 0.2936507E+01 0.5857181E-10 0.2936507E+01 0.0000000E+00 11 Fe++ 0.2638131E+01 0.2270885E-07 0.2638131E+01 0.0000000E+00 12 K+ 0.7855624E+00 0.9879768E-04 0.7854636E+00 0.0000000E+00 13 Na+ 0.4644560E+01 0.1401077E-01 0.4630549E+01 0.0000000E+00 14 Mn++ 0.6415279E-01 0.1582549E-08 0.6415279E-01 0.0000000E+00 15 HPO4-- 0.2189503E-01 0.2900399E-07 0.2189500E-01 0.0000000E+00 Chg. balance for solid moles: -.7279E-14 Mass of aqueous solution: 0.627982E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 3699.9990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 4.627 0.665 1213. 3.084 30.01 465.7 andradite 0.4103 -0.387 208.5 2.319 5.159 54.17 grossular 0.9936E-01 -1.003 44.76 1.651 1.107 12.45 apatite-OH 0.7298E-02 -2.137 3.666 0.564 0.9070E-01 1.165 clinochlore 0.5260 -0.279 292.3 2.466 7.233 111.2 daphnite 0.1523 -0.817 108.6 2.036 2.688 32.92 chlorite-Mn 0.1283E-01 -1.892 9.096 0.959 0.2250 2.899 diopside 0.1920 -0.717 41.58 1.619 1.029 12.71 hedenbergite 0.4979E-01 -1.303 12.35 1.092 0.3056 3.383 microcline 0.6888 -0.162 191.7 2.283 4.743 74.89 stilbite 2.385 0.377 1681. 3.225 41.58 783.9 stilpnomelane-Fe 0.1934 -0.714 208.4 2.319 5.157 72.00 tr.625ac.25prg.125 0.3164E-01 -1.500 27.05 1.432 0.6691 8.705 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8051E+00 0.8051E+00 1.0000 -0.094 grossular 0.1949E+00 0.1949E+00 1.0000 -0.710 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.7611E+00 0.7611E+00 1.0000 -0.119 daphnite 0.2203E+00 0.2203E+00 1.0000 -0.657 chlorite-Mn 0.1857E-01 0.1857E-01 1.0000 -1.731 diopside 0.7941E+00 0.7941E+00 1.0000 -0.100 hedenbergite 0.2059E+00 0.2059E+00 1.0000 -0.686 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 tr.625ac.25prg.125 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 4042.079221 g Volume = 1636.138024 cm3 Porosity: -10.4753% V(tot) - V(min): -.15514E+03 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 3699.9990000 g log = 3.5682 Original solution: 1000.0103000 g Original solution / Rock added: 0.27 (Water/Rock Ratio), log = -0.5682 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0647 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9589E+00 0.9854 0.1006E+01 0.1021E+01 CO2,gas 0.5060E-08 1.0068 0.5424E-08 0.5387E-08 CH4,gas 0.2687E-01 1.0123 0.2896E-01 0.2861E-01 H2,gas 0.1427E-01 1.0006 0.1521E-01 0.1520E-01 H2S,gas 0.2023E-06 0.9959 0.2146E-06 0.2154E-06 S2,gas 0.7018E-29 1.0000 0.7472E-29 0.7472E-29 CO,gas 0.2064E-13 1.0000 0.2198E-13 0.2198E-13 SO3,gas 0.1050E-47 1.0000 0.1118E-47 0.1118E-47 SO2,gas 0.6215E-27 1.0000 0.6617E-27 0.6617E-27 HCl,gas 0.4130E-17 1.0000 0.4397E-17 0.4397E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 16 albite -0.38 -0.38 0.00 0.000 0.11184E-10 22 andradite 39.01 39.01 0.00 0.000 0.24265E-10 23 grossular 32.73 32.73 0.00 0.000 -0.12132E-10 32 apatite-OH -18.15 -18.15 0.00 0.000 0.60662E-11 46 clinochlore 39.07 39.07 0.00 0.000 0.36397E-10 47 daphnite 28.97 28.97 0.00 0.000 0.00000E+00 48 chlorite-Mn 46.87 46.87 0.00 0.000 0.36397E-10 67 diopside 16.18 16.18 0.00 0.000 0.12132E-10 68 hedenbergite 14.21 14.21 0.00 0.000 0.90992E-11 116 microcline -2.49 -2.49 0.00 0.000 0.15165E-11 163 stilbite -7.52 -7.52 0.00 0.000 0.15165E-10 164 stilpnomelane-Fe 13.02 13.02 0.00 0.000 0.21232E-10 245 tr.625ac.25prg.125 45.16 45.16 0.00 0.000 -0.36397E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -16.62 -9.96 -3.322 0.17014E+05 -8.266 3 CH4,gas 4.54 1.31 -3.24 -0.809 0.55274E+04 -1.538 4 H2,gas 8.00 4.48 -3.52 -2.010 0.60051E+04 -1.818 5 H2S,gas -6.23 -14.60 -8.37 -4.184 0.14287E+05 -6.668 6 S2,gas -7.34 -38.16 -30.83 -4.742 0.52634E+05 -29.127 7 CO,gas 3.21 -12.14 -15.36 -4.725 0.26222E+05 -13.658 8 SO3,gas 17.12 -32.53 -49.65 -12.413 0.84777E+05 -47.951 9 SO2,gas 0.83 -28.05 -28.88 -7.701 0.49309E+05 -27.179 10 HCl,gas 5.19 -13.87 -19.06 -9.528 0.32537E+05 -17.357 11 acmite 7.71 6.53 -1.18 -0.123 0.20175E+04 15 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 19 spessartine 24.46 19.73 -4.73 -0.236 0.80724E+04 20 analcite 3.32 2.77 -0.55 -0.061 0.93624E+03 26 annite 20.12 17.72 -2.40 -0.134 0.41064E+04 27 phlogopite 27.06 25.40 -1.67 -0.093 0.28489E+04 29 anorthite 12.71 8.26 -4.45 -0.342 0.75903E+04 35 aragonite 0.97 -3.52 -4.49 -1.496 0.76657E+04 36 brucite 12.57 9.29 -3.27 -0.655 0.55909E+04 37 calcite 0.81 -3.52 -4.33 -1.445 0.74015E+04 38 carnegieite-low 9.02 5.93 -3.09 -0.442 0.52801E+04 39 carnegieite-high 10.09 5.93 -4.16 -0.595 0.71071E+04 40 carpholite-Mg 8.58 4.46 -4.12 -0.275 0.70429E+04 41 carpholite-Fe 6.71 1.90 -4.81 -0.321 0.82206E+04 42 celadonite 5.34 3.65 -1.69 -0.099 0.28879E+04 43 celadonite-Fe 3.88 1.09 -2.79 -0.164 0.47561E+04 44 chrysotile 23.89 21.57 -2.32 -0.194 0.39692E+04 49 chlorite-Al-free 47.17 43.14 -4.04 -0.168 0.68936E+04 51 chloritoid-Fe 9.17 5.06 -4.12 -0.275 0.70315E+04 52 chloritoid-Mn 11.40 7.56 -3.84 -0.256 0.65554E+04 54 coesite -2.38 -3.16 -0.78 -0.260 0.13341E+04 61 cristobalite -2.56 -3.16 -0.60 -0.199 0.10195E+04 63 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71234E+04 65 diaspore 2.87 0.74 -2.13 -0.356 0.36450E+04 66 diamond -3.10 -7.66 -4.56 -1.302 0.77805E+04 71 enstatite 17.26 12.27 -4.99 -0.499 0.85226E+04 73 clinoenstatite 17.17 12.27 -4.89 -0.489 0.83541E+04 75 epidote 24.67 22.70 -1.97 -0.095 0.33585E+04 76 clinozoisite 22.81 18.95 -3.86 -0.175 0.65868E+04 77 epidote-Fe 29.84 26.46 -3.38 -0.176 0.57768E+04 78 fayalite 14.05 10.31 -3.73 -0.533 0.63743E+04 79 ferrosilite 11.15 7.16 -3.99 -0.399 0.68202E+04 83 gibbsite 4.08 0.74 -3.34 -0.477 0.57035E+04 84 glaucophane 22.97 20.80 -2.17 -0.059 0.37133E+04 85 glaucophane-Fe 17.28 13.12 -4.15 -0.112 0.70919E+04 86 graphite -3.55 -7.66 -4.11 -1.175 0.70228E+04 87 greenalite 16.14 13.89 -2.25 -0.187 0.38408E+04 90 hematite 12.57 8.99 -3.58 -0.434 0.61111E+04 91 heulandite -5.83 -7.52 -1.69 -0.077 0.28938E+04 95 jadeite 4.22 2.77 -1.44 -0.144 0.24617E+04 97 kalsilite 7.58 3.83 -3.76 -0.537 0.64126E+04 98 kaolinite -1.33 -4.84 -3.50 -0.319 0.59831E+04 101 laumontite 2.88 1.95 -0.93 -0.062 0.15935E+04 102 lawsonite 9.62 8.26 -1.35 -0.090 0.23070E+04 103 leucite 4.12 0.67 -3.45 -0.345 0.58873E+04 105 lizardite 23.24 21.57 -1.68 -0.140 0.28618E+04 107 magnetite 20.09 15.72 -4.37 -0.356 0.74536E+04 108 minnesotaite 10.39 7.58 -2.81 -0.165 0.48028E+04 112 manganosite 14.06 9.24 -4.82 -1.204 0.82246E+04 120 muscovite 2.58 -1.01 -3.59 -0.211 0.61315E+04 121 paragonite 4.24 1.09 -3.15 -0.185 0.53706E+04 122 nepheline 8.34 5.93 -2.41 -0.344 0.41125E+04 128 periclase-Fe 11.63 6.73 -4.89 -1.223 0.83523E+04 134 phlogopite-Na 29.65 27.50 -2.15 -0.119 0.36677E+04 136 prehnite 19.37 18.21 -1.16 -0.068 0.19849E+04 137 prehnite-Fe 22.50 21.96 -0.53 -0.032 0.91158E+03 138 pumpellyite-Fe 46.27 43.89 -2.38 -0.053 0.40581E+04 139 pumpellyite-Mg 48.99 46.45 -2.54 -0.057 0.43419E+04 143 pyrrhotite -4.26 -7.86 -3.60 -1.201 0.61510E+04 144 pyrrhotiteFe0.875 -6.02 -9.26 -3.24 -1.193 0.55382E+04 145 pyroxmangite 7.40 6.08 -1.31 -0.263 0.22450E+04 146 pyrophyllite -6.18 -11.15 -4.98 -0.311 0.84962E+04 147 quartz -2.99 -3.16 -0.17 -0.056 0.28681E+03 152 rhodonite 7.45 6.08 -1.36 -0.272 0.23252E+04 153 sanidine -1.28 -2.49 -1.21 -0.093 0.20677E+04 165 stilpnomelane-Mg 27.44 25.81 -1.63 -0.049 0.27803E+04 171 talc 16.49 15.25 -1.24 -0.073 0.21140E+04 174 tephroite 18.09 15.33 -2.76 -0.394 0.47136E+04 178 tridymite -2.63 -3.16 -0.53 -0.177 0.90678E+03 179 tremolite 47.87 47.42 -0.45 -0.012 0.77495E+03 180 ferroactinolite 38.45 34.62 -3.83 -0.104 0.65449E+04 181 troilite-low -4.41 -7.86 -3.45 -1.151 0.58938E+04 183 vesuvianite 223.47 218.82 -4.65 -0.036 0.79436E+04 187 wairakite 3.95 1.95 -2.00 -0.118 0.34154E+04 188 walstromite 11.51 9.94 -1.56 -0.313 0.26719E+04 189 wollastonite 10.46 9.94 -0.52 -0.103 0.88229E+03 190 pseudo-wollastonite 11.00 9.94 -1.06 -0.211 0.18021E+04 191 zoisite 22.85 18.95 -3.90 -0.177 0.66609E+04 192 akaganeite 7.75 4.49 -3.26 -0.705 0.55681E+04 199 chalcedony -2.80 -3.16 -0.35 -0.118 0.60610E+03 201 montmorillonite-Ca -2.29 -6.17 -3.88 -0.240 0.66180E+04 202 montmorillonite-K -2.24 -6.27 -4.03 -0.247 0.68816E+04 203 montmorillonite-Mg -2.48 -6.79 -4.32 -0.267 0.73678E+04 204 montmorillonite-Na -2.04 -5.57 -3.54 -0.216 0.60365E+04 205 nontronite-Ca 3.21 -0.19 -3.41 -0.221 0.58215E+04 206 nontronite-H 2.53 -2.36 -4.89 -0.328 0.83485E+04 207 nontronite-K 3.34 -0.30 -3.64 -0.233 0.62083E+04 208 nontronite-Mg 3.07 -0.82 -3.90 -0.253 0.66553E+04 209 nontronite-Na 3.52 0.40 -3.12 -0.200 0.53292E+04 224 tobermorite 9.82 7.76 -2.07 -0.564 0.35287E+04 230 alabandite -0.98 -5.36 -4.38 -1.460 0.74762E+04 233 boehmite 4.41 0.74 -3.67 -0.611 0.62619E+04 235 ferrous-oxide 9.81 6.73 -3.08 -0.769 0.52532E+04 240 silica-amorphous -2.09 -3.16 -1.07 -0.355 0.18203E+04 242 an20ab80 2.02 1.35 -0.67 -0.052 0.11472E+04 243 an25ab75 2.65 1.78 -0.87 -0.067 0.14810E+04 244 an30ab70 3.28 2.21 -1.07 -0.082 0.18244E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 100.0000000 g Current total amount of reactant added: 3699.9990000 g New total amount of reactant added: 3799.9990000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.5222E-10 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 11 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 3799.9990000 Water: Moles liquid = 0.3424E+02 kg liquid = 0.6168E+00 Moles total = 0.7874E+01 kg total = 0.1418E+00 Activity = 1.0000 Stoichiometric ionic strength = .1138864E-01 Osmotic coef. = 0.9688 True ionic strength = .2006342E-01 Chg. balance for total moles = 0.5222E-10 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.88490E-10 -10.0531 0.74343E-10 -10.1288 0.84013E+00 -0.0757 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.22265E-03 -3.6524 0.18593E-03 -3.7306 0.83507E+00 -0.0783 4 SO4-- 0.10481E-11 -11.9796 0.54399E-12 -12.2644 0.51900E+00 -0.2848 5 HCO3- 0.38780E-06 -6.4114 0.32432E-06 -6.4890 0.83630E+00 -0.0776 6 HS- 0.41339E-04 -4.3836 0.34526E-04 -4.4619 0.83520E+00 -0.0782 7 Al+++ 0.97638E-29 -29.0104 0.22527E-29 -29.6473 0.23072E+00 -0.6369 8 H4SiO4 0.69597E-03 -3.1574 0.69597E-03 -3.1574 0.10000E+01 0.0000 9 Ca++ 0.13563E-06 -6.8676 0.69874E-07 -7.1557 0.51519E+00 -0.2880 10 Mg++ 0.21218E-10 -10.6733 0.10881E-10 -10.9633 0.51282E+00 -0.2900 11 Fe++ 0.58481E-13 -13.2330 0.30024E-13 -13.5225 0.51339E+00 -0.2896 12 K+ 0.15686E-03 -3.8045 0.13122E-03 -3.8820 0.83649E+00 -0.0775 13 Na+ 0.19905E-01 -1.7010 0.16619E-01 -1.7794 0.83492E+00 -0.0784 14 Mn++ 0.18750E-10 -10.7270 0.96341E-11 -11.0162 0.51381E+00 -0.2892 15 HPO4-- 0.45158E-07 -7.3453 0.23440E-07 -7.6300 0.51908E+00 -0.2848 16 HSiO3- 0.10468E-01 -1.9801 0.87413E-02 -2.0584 0.83507E+00 -0.0783 17 Ca(HSiO3)+ 0.16625E-07 -7.7792 0.13910E-07 -7.8567 0.83667E+00 -0.0774 18 Mg(HSiO3)+ 0.32221E-11 -11.4919 0.26958E-11 -11.5693 0.83667E+00 -0.0774 19 NaHSiO3,aq 0.23496E-02 -2.6290 0.23496E-02 -2.6290 0.10000E+01 0.0000 20 AlO+ 0.66274E-16 -16.1787 0.55450E-16 -16.2561 0.83667E+00 -0.0774 22 HAlO2,aq 0.14854E-09 -9.8282 0.14854E-09 -9.8282 0.10000E+01 0.0000 23 AlO2- 0.53058E-05 -5.2753 0.44227E-05 -5.3543 0.83356E+00 -0.0791 24 CH4,aq 0.20064E-04 -4.6976 0.19995E-04 -4.6991 0.99653E+00 -0.0015 25 C2H6,aq 0.59213E-14 -14.2276 0.59007E-14 -14.2291 0.99653E+00 -0.0015 29 CO,aq 0.14991E-16 -16.8242 0.14991E-16 -16.8242 0.10000E+01 0.0000 30 CO2,aq 0.51699E-10 -10.2865 0.51520E-10 -10.2880 0.99653E+00 -0.0015 31 CO3-2 0.73575E-06 -6.1333 0.38104E-06 -6.4190 0.51790E+00 -0.2858 32 CaCO3,aq 0.33385E-09 -9.4765 0.33385E-09 -9.4765 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.69138E-12 -12.1603 0.57846E-12 -12.2377 0.83667E+00 -0.0774 34 CaCl+ 0.25129E-10 -10.5998 0.21025E-10 -10.6773 0.83667E+00 -0.0774 35 CaCl2,aq 0.92873E-15 -15.0321 0.92873E-15 -15.0321 0.10000E+01 0.0000 36 CaOH+ 0.80061E-07 -7.0966 0.66985E-07 -7.1740 0.83667E+00 -0.0774 37 CaSO4,aq 0.12070E-16 -16.9183 0.12070E-16 -16.9183 0.10000E+01 0.0000 38 HCl,aq 0.25330E-14 -14.5964 0.25330E-14 -14.5964 0.10000E+01 0.0000 43 FeCl+ 0.10561E-16 -16.9763 0.88358E-17 -17.0538 0.83667E+00 -0.0774 46 FeO,aq 0.21113E-09 -9.6755 0.21113E-09 -9.6755 0.10000E+01 0.0000 47 FeOH+ 0.15712E-10 -10.8038 0.13146E-10 -10.8812 0.83667E+00 -0.0774 48 HFeO2- 0.35583E-07 -7.4488 0.29714E-07 -7.5270 0.83507E+00 -0.0783 49 FeO+ 0.11012E-16 -16.9582 0.92131E-17 -17.0356 0.83667E+00 -0.0774 51 FeO2- 0.40845E-09 -9.3889 0.34109E-09 -9.4671 0.83507E+00 -0.0783 52 HFeO2,aq 0.32251E-11 -11.4915 0.32251E-11 -11.4915 0.10000E+01 0.0000 53 H2,aq 0.11623E-04 -4.9347 0.11583E-04 -4.9362 0.99653E+00 -0.0015 54 KCl,aq 0.44218E-09 -9.3544 0.44218E-09 -9.3544 0.10000E+01 0.0000 56 KOH,aq 0.75375E-06 -6.1228 0.75375E-06 -6.1228 0.10000E+01 0.0000 57 KSO4- 0.13264E-14 -14.8773 0.11076E-14 -14.9556 0.83507E+00 -0.0783 58 MgCO3,aq 0.13031E-13 -13.8850 0.13031E-13 -13.8850 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.11002E-15 -15.9585 0.92047E-16 -16.0360 0.83667E+00 -0.0774 60 MgCl+ 0.35468E-14 -14.4502 0.29675E-14 -14.5276 0.83667E+00 -0.0774 61 MgOH+ 0.68990E-10 -10.1612 0.57722E-10 -10.2387 0.83667E+00 -0.0774 63 MnO,aq 0.18052E-08 -8.7435 0.18052E-08 -8.7435 0.10000E+01 0.0000 64 MnOH+ 0.46836E-09 -9.3294 0.39186E-09 -9.4069 0.83667E+00 -0.0774 65 MnO2-2 0.20930E-10 -10.6792 0.10839E-10 -10.9650 0.51790E+00 -0.2858 66 HMnO2- 0.21141E-09 -9.6749 0.17655E-09 -9.7531 0.83507E+00 -0.0783 69 MnCl+ 0.13184E-13 -13.8800 0.11031E-13 -13.9574 0.83667E+00 -0.0774 71 NaCl,aq 0.10240E-05 -5.9897 0.10240E-05 -5.9897 0.10000E+01 0.0000 72 NaOH,aq 0.96047E-04 -4.0175 0.96047E-04 -4.0175 0.10000E+01 0.0000 74 OH- 0.93235E-02 -2.0304 0.77717E-02 -2.1095 0.83356E+00 -0.0791 79 HPO3-2 0.16337E-14 -14.7868 0.84610E-15 -15.0726 0.51790E+00 -0.2858 81 H2PO3- 0.15105E-18 -18.8209 0.12614E-18 -18.8992 0.83507E+00 -0.0783 82 H3PO4,aq 0.90609E-18 -18.0428 0.90609E-18 -18.0428 0.10000E+01 0.0000 83 H2PO4- 0.38460E-10 -10.4150 0.32147E-10 -10.4929 0.83587E+00 -0.0779 84 PO4-3 0.10615E-08 -8.9741 0.25725E-09 -9.5896 0.24235E+00 -0.6156 88 HP2O7-3 0.94236E-18 -18.0258 0.21764E-18 -18.6623 0.23095E+00 -0.6365 89 P2O7-4 0.90912E-17 -17.0414 0.69937E-18 -18.1553 0.76928E-01 -1.1139 90 H2S,aq 0.79605E-08 -8.0991 0.79329E-08 -8.1006 0.99653E+00 -0.0015 91 S2-2 0.44031E-14 -14.3562 0.22804E-14 -14.6420 0.51790E+00 -0.2858 97 SO3-2 0.15584E-17 -17.8073 0.81879E-18 -18.0868 0.52540E+00 -0.2795 99 HSO4- 0.46537E-19 -19.3322 0.38974E-19 -19.4092 0.83749E+00 -0.0770 Charge balance for all species = 0.8466E-10 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.8849000E-10 -.2226271E-01 -.2240043E+02 0.0000 2 H2O 0.1000000E+01 0.5550490E+02 0.9981974E+06 0.0000 3 Cl- 0.2226521E-03 0.2236766E-03 0.7916208E+01 6.3981 4 SO4-- 0.1048141E-11 -.2297019E-04 -.2202714E+01 7.9931 5 HCO3- 0.3878049E-06 0.2118841E-04 0.1290608E+01 3.6397 6 HS- 0.4133857E-04 0.6431672E-04 0.2123381E+01 5.6669 7 Al+++ 0.9763793E-29 0.5305908E-05 0.1429122E+00 0.7390 8 H4SiO4 0.6959747E-03 0.1351337E-01 0.1296583E+04 -3.1574 9 Ca++ 0.1356290E-06 0.2326751E-06 0.9308925E-02 13.1018 10 Mg++ 0.2121836E-10 0.9344749E-10 0.2267942E-05 9.2942 11 Fe++ 0.5848121E-13 0.3622108E-07 0.2019319E-02 6.7350 12 K+ 0.1568637E-03 0.1576179E-03 0.6152449E+01 6.2467 13 Na+ 0.1990527E-01 0.2235197E-01 0.5129731E+03 8.3494 14 Mn++ 0.1875018E-10 0.2524640E-08 0.1384573E-03 9.2413 15 HPO4-- 0.4515804E-07 0.4625801E-07 0.4432072E-02 12.6275 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.6292233E+02 -.1373268E-01 -.6290860E+02 0.0000000E+00 2 H2O 0.7873704E+01 0.3423801E+02 -.2636431E+02 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.1053364E+00 -.1416909E-04 0.1053506E+00 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.1053109E+00 0.3967356E-04 -.1053506E+00 0.0000000E+00 7 Al+++ 0.1239081E+02 0.3272932E-05 0.1239081E+02 0.0000000E+00 8 H4SiO4 0.3956856E+02 0.8335679E-02 0.3956023E+02 0.0000000E+00 9 Ca++ 0.4370555E+01 0.1435248E-06 0.4370555E+01 0.0000000E+00 10 Mg++ 0.3015872E+01 0.5764278E-10 0.3015872E+01 0.0000000E+00 11 Fe++ 0.2709432E+01 0.2234285E-07 0.2709432E+01 0.0000000E+00 12 K+ 0.8067938E+00 0.9722606E-04 0.8066966E+00 0.0000000E+00 13 Na+ 0.4770085E+01 0.1378774E-01 0.4756297E+01 0.0000000E+00 14 Mn++ 0.6588665E-01 0.1557316E-08 0.6588665E-01 0.0000000E+00 15 HPO4-- 0.2248679E-01 0.2853410E-07 0.2248676E-01 0.0000000E+00 Chg. balance for solid moles: -.1953E-13 Mass of aqueous solution: 0.617922E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 3799.9990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 4.752 0.677 1246. 3.096 30.02 478.4 andradite 0.4214 -0.375 214.1 2.331 5.159 55.64 grossular 0.1020 -0.991 45.96 1.662 1.107 12.79 apatite-OH 0.7496E-02 -2.125 3.765 0.576 0.9070E-01 1.196 clinochlore 0.5401 -0.267 300.2 2.477 7.232 114.2 daphnite 0.1564 -0.806 111.6 2.048 2.688 33.81 chlorite-Mn 0.1318E-01 -1.880 9.342 0.970 0.2250 2.977 diopside 0.1974 -0.705 42.75 1.631 1.030 13.07 hedenbergite 0.5120E-01 -1.291 12.70 1.104 0.3060 3.479 microcline 0.7074 -0.150 196.9 2.294 4.743 76.91 stilbite 2.449 0.389 1726. 3.237 41.58 805.0 stilpnomelane-Fe 0.1986 -0.702 214.1 2.331 5.157 73.95 tr.625ac.25prg.125 0.3248E-01 -1.488 27.76 1.443 0.6687 8.935 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8051E+00 0.8051E+00 1.0000 -0.094 grossular 0.1949E+00 0.1949E+00 1.0000 -0.710 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.7611E+00 0.7611E+00 1.0000 -0.119 daphnite 0.2203E+00 0.2203E+00 1.0000 -0.657 chlorite-Mn 0.1857E-01 0.1857E-01 1.0000 -1.731 diopside 0.7941E+00 0.7941E+00 1.0000 -0.100 hedenbergite 0.2059E+00 0.2059E+00 1.0000 -0.686 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 tr.625ac.25prg.125 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 4151.329885 g Volume = 1680.341088 cm3 Porosity: -10.4761% V(tot) - V(min): -.15934E+03 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 3799.9990000 g log = 3.5798 Original solution: 1000.0103000 g Original solution / Rock added: 0.26 (Water/Rock Ratio), log = -0.5798 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0652 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9584E+00 0.9853 0.1006E+01 0.1021E+01 CO2,gas 0.5140E-08 1.0068 0.5512E-08 0.5475E-08 CH4,gas 0.2729E-01 1.0123 0.2943E-01 0.2907E-01 H2,gas 0.1427E-01 1.0006 0.1521E-01 0.1520E-01 H2S,gas 0.2056E-06 0.9959 0.2181E-06 0.2190E-06 S2,gas 0.7247E-29 1.0000 0.7719E-29 0.7719E-29 CO,gas 0.2097E-13 1.0000 0.2234E-13 0.2234E-13 SO3,gas 0.1067E-47 1.0000 0.1137E-47 0.1137E-47 SO2,gas 0.6314E-27 1.0000 0.6726E-27 0.6726E-27 HCl,gas 0.4196E-17 1.0000 0.4469E-17 0.4469E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 16 albite -0.38 -0.38 0.00 0.000 -0.94784E-12 22 andradite 39.01 39.01 0.00 0.000 0.00000E+00 23 grossular 32.73 32.73 0.00 0.000 0.24265E-10 32 apatite-OH -18.15 -18.15 0.00 0.000 0.00000E+00 46 clinochlore 39.07 39.07 0.00 0.000 0.00000E+00 47 daphnite 28.97 28.97 0.00 0.000 0.12132E-10 48 chlorite-Mn 46.87 46.87 0.00 0.000 0.12132E-10 67 diopside 16.18 16.18 0.00 0.000 0.00000E+00 68 hedenbergite 14.21 14.21 0.00 0.000 0.30331E-11 116 microcline -2.49 -2.49 0.00 0.000 -0.10616E-10 163 stilbite -7.52 -7.52 0.00 0.000 -0.33364E-10 164 stilpnomelane-Fe 13.02 13.02 0.00 0.000 0.69761E-10 245 tr.625ac.25prg.125 45.16 45.16 0.00 0.000 -0.60662E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -16.62 -9.96 -3.319 0.17002E+05 -8.259 3 CH4,gas 4.54 1.31 -3.23 -0.808 0.55154E+04 -1.531 4 H2,gas 8.00 4.48 -3.52 -2.010 0.60051E+04 -1.818 5 H2S,gas -6.23 -14.59 -8.36 -4.180 0.14275E+05 -6.661 6 S2,gas -7.34 -38.15 -30.81 -4.740 0.52610E+05 -29.112 7 CO,gas 3.21 -12.13 -15.35 -4.723 0.26210E+05 -13.651 8 SO3,gas 17.12 -32.52 -49.64 -12.411 0.84765E+05 -47.944 9 SO2,gas 0.83 -28.04 -28.87 -7.699 0.49297E+05 -27.172 10 HCl,gas 5.19 -13.86 -19.05 -9.524 0.32525E+05 -17.350 11 acmite 7.71 6.53 -1.18 -0.123 0.20175E+04 15 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 19 spessartine 24.46 19.73 -4.73 -0.236 0.80723E+04 20 analcite 3.32 2.77 -0.55 -0.061 0.93624E+03 26 annite 20.12 17.72 -2.40 -0.134 0.41064E+04 27 phlogopite 27.06 25.40 -1.67 -0.093 0.28489E+04 29 anorthite 12.71 8.26 -4.45 -0.342 0.75903E+04 35 aragonite 0.97 -3.52 -4.48 -1.494 0.76537E+04 36 brucite 12.57 9.29 -3.27 -0.655 0.55909E+04 37 calcite 0.81 -3.52 -4.33 -1.443 0.73895E+04 38 carnegieite-low 9.02 5.93 -3.09 -0.442 0.52801E+04 39 carnegieite-high 10.09 5.93 -4.16 -0.595 0.71071E+04 40 carpholite-Mg 8.58 4.46 -4.12 -0.275 0.70429E+04 41 carpholite-Fe 6.71 1.90 -4.81 -0.321 0.82206E+04 42 celadonite 5.34 3.65 -1.69 -0.099 0.28879E+04 43 celadonite-Fe 3.88 1.09 -2.79 -0.164 0.47561E+04 44 chrysotile 23.89 21.57 -2.32 -0.194 0.39692E+04 49 chlorite-Al-free 47.17 43.14 -4.04 -0.168 0.68936E+04 51 chloritoid-Fe 9.17 5.06 -4.12 -0.275 0.70315E+04 52 chloritoid-Mn 11.40 7.56 -3.84 -0.256 0.65553E+04 54 coesite -2.38 -3.16 -0.78 -0.260 0.13341E+04 61 cristobalite -2.56 -3.16 -0.60 -0.199 0.10195E+04 63 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71234E+04 65 diaspore 2.87 0.74 -2.13 -0.356 0.36450E+04 66 diamond -3.10 -7.65 -4.55 -1.300 0.77686E+04 71 enstatite 17.26 12.27 -4.99 -0.499 0.85226E+04 73 clinoenstatite 17.17 12.27 -4.89 -0.489 0.83541E+04 75 epidote 24.67 22.70 -1.97 -0.095 0.33585E+04 76 clinozoisite 22.81 18.95 -3.86 -0.175 0.65868E+04 77 epidote-Fe 29.84 26.46 -3.38 -0.176 0.57768E+04 78 fayalite 14.05 10.31 -3.73 -0.533 0.63743E+04 79 ferrosilite 11.15 7.16 -3.99 -0.399 0.68202E+04 83 gibbsite 4.08 0.74 -3.34 -0.477 0.57035E+04 84 glaucophane 22.97 20.80 -2.17 -0.059 0.37133E+04 85 glaucophane-Fe 17.28 13.12 -4.15 -0.112 0.70919E+04 86 graphite -3.55 -7.65 -4.11 -1.173 0.70108E+04 87 greenalite 16.14 13.89 -2.25 -0.187 0.38408E+04 90 hematite 12.57 8.99 -3.58 -0.434 0.61111E+04 91 heulandite -5.83 -7.52 -1.69 -0.077 0.28938E+04 95 jadeite 4.22 2.77 -1.44 -0.144 0.24617E+04 97 kalsilite 7.58 3.83 -3.76 -0.537 0.64126E+04 98 kaolinite -1.33 -4.84 -3.50 -0.319 0.59831E+04 101 laumontite 2.88 1.95 -0.93 -0.062 0.15935E+04 102 lawsonite 9.62 8.26 -1.35 -0.090 0.23070E+04 103 leucite 4.12 0.67 -3.45 -0.345 0.58873E+04 105 lizardite 23.24 21.57 -1.68 -0.140 0.28618E+04 107 magnetite 20.09 15.72 -4.37 -0.356 0.74536E+04 108 minnesotaite 10.39 7.58 -2.81 -0.165 0.48028E+04 112 manganosite 14.06 9.24 -4.82 -1.204 0.82245E+04 120 muscovite 2.58 -1.01 -3.59 -0.211 0.61315E+04 121 paragonite 4.24 1.09 -3.15 -0.185 0.53706E+04 122 nepheline 8.34 5.93 -2.41 -0.344 0.41125E+04 128 periclase-Fe 11.63 6.73 -4.89 -1.223 0.83523E+04 134 phlogopite-Na 29.65 27.50 -2.15 -0.119 0.36677E+04 136 prehnite 19.37 18.21 -1.16 -0.068 0.19849E+04 137 prehnite-Fe 22.50 21.96 -0.53 -0.032 0.91158E+03 138 pumpellyite-Fe 46.27 43.89 -2.38 -0.053 0.40581E+04 139 pumpellyite-Mg 48.99 46.45 -2.54 -0.057 0.43419E+04 143 pyrrhotite -4.26 -7.86 -3.60 -1.198 0.61389E+04 144 pyrrhotiteFe0.875 -6.02 -9.25 -3.24 -1.190 0.55261E+04 145 pyroxmangite 7.40 6.08 -1.31 -0.263 0.22449E+04 146 pyrophyllite -6.18 -11.15 -4.98 -0.311 0.84962E+04 147 quartz -2.99 -3.16 -0.17 -0.056 0.28681E+03 152 rhodonite 7.45 6.08 -1.36 -0.272 0.23252E+04 153 sanidine -1.28 -2.49 -1.21 -0.093 0.20677E+04 165 stilpnomelane-Mg 27.44 25.81 -1.63 -0.049 0.27803E+04 171 talc 16.49 15.25 -1.24 -0.073 0.21140E+04 174 tephroite 18.09 15.33 -2.76 -0.394 0.47136E+04 178 tridymite -2.63 -3.16 -0.53 -0.177 0.90678E+03 179 tremolite 47.87 47.42 -0.45 -0.012 0.77495E+03 180 ferroactinolite 38.45 34.62 -3.83 -0.104 0.65449E+04 181 troilite-low -4.41 -7.86 -3.44 -1.148 0.58817E+04 183 vesuvianite 223.47 218.82 -4.65 -0.036 0.79437E+04 187 wairakite 3.95 1.95 -2.00 -0.118 0.34154E+04 188 walstromite 11.51 9.94 -1.56 -0.313 0.26719E+04 189 wollastonite 10.46 9.94 -0.52 -0.103 0.88229E+03 190 pseudo-wollastonite 11.00 9.94 -1.06 -0.211 0.18021E+04 191 zoisite 22.85 18.95 -3.90 -0.177 0.66609E+04 192 akaganeite 7.75 4.49 -3.26 -0.705 0.55681E+04 199 chalcedony -2.80 -3.16 -0.35 -0.118 0.60610E+03 201 montmorillonite-Ca -2.29 -6.17 -3.88 -0.240 0.66180E+04 202 montmorillonite-K -2.24 -6.27 -4.03 -0.247 0.68816E+04 203 montmorillonite-Mg -2.48 -6.79 -4.32 -0.267 0.73678E+04 204 montmorillonite-Na -2.04 -5.57 -3.54 -0.216 0.60365E+04 205 nontronite-Ca 3.21 -0.19 -3.41 -0.221 0.58215E+04 206 nontronite-H 2.53 -2.36 -4.89 -0.328 0.83485E+04 207 nontronite-K 3.34 -0.30 -3.64 -0.233 0.62083E+04 208 nontronite-Mg 3.07 -0.82 -3.90 -0.253 0.66553E+04 209 nontronite-Na 3.52 0.40 -3.12 -0.200 0.53292E+04 224 tobermorite 9.82 7.76 -2.07 -0.564 0.35287E+04 230 alabandite -0.98 -5.35 -4.37 -1.457 0.74641E+04 233 boehmite 4.41 0.74 -3.67 -0.611 0.62619E+04 235 ferrous-oxide 9.81 6.73 -3.08 -0.769 0.52532E+04 240 silica-amorphous -2.09 -3.16 -1.07 -0.355 0.18203E+04 242 an20ab80 2.02 1.35 -0.67 -0.052 0.11472E+04 243 an25ab75 2.65 1.78 -0.87 -0.067 0.14810E+04 244 an30ab70 3.28 2.21 -1.07 -0.082 0.18244E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 100.0000000 g Current total amount of reactant added: 3799.9990000 g New total amount of reactant added: 3899.9990000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.5221E-10 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 11 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 3899.9990000 Water: Moles liquid = 0.3368E+02 kg liquid = 0.6068E+00 Moles total = 0.6620E+01 kg total = 0.1193E+00 Activity = 1.0000 Stoichiometric ionic strength = .1139171E-01 Osmotic coef. = 0.9688 True ionic strength = .2006581E-01 Chg. balance for total moles = 0.5221E-10 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.88500E-10 -10.0531 0.74352E-10 -10.1287 0.84013E+00 -0.0757 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.22634E-03 -3.6452 0.18901E-03 -3.7235 0.83507E+00 -0.0783 4 SO4-- 0.10654E-11 -11.9725 0.55293E-12 -12.2573 0.51899E+00 -0.2848 5 HCO3- 0.39419E-06 -6.4043 0.32966E-06 -6.4819 0.83629E+00 -0.0776 6 HS- 0.42023E-04 -4.3765 0.35097E-04 -4.4547 0.83519E+00 -0.0782 7 Al+++ 0.97677E-29 -29.0102 0.22535E-29 -29.6472 0.23070E+00 -0.6369 8 H4SiO4 0.69598E-03 -3.1574 0.69598E-03 -3.1574 0.10000E+01 0.0000 9 Ca++ 0.13566E-06 -6.8675 0.69890E-07 -7.1556 0.51517E+00 -0.2880 10 Mg++ 0.21224E-10 -10.6732 0.10884E-10 -10.9632 0.51281E+00 -0.2900 11 Fe++ 0.58496E-13 -13.2329 0.30030E-13 -13.5224 0.51337E+00 -0.2896 12 K+ 0.15688E-03 -3.8044 0.13123E-03 -3.8820 0.83649E+00 -0.0775 13 Na+ 0.19908E-01 -1.7010 0.16621E-01 -1.7793 0.83491E+00 -0.0784 14 Mn++ 0.18756E-10 -10.7269 0.96368E-11 -11.0161 0.51380E+00 -0.2892 15 HPO4-- 0.45150E-07 -7.3453 0.23435E-07 -7.6301 0.51906E+00 -0.2848 16 HSiO3- 0.10467E-01 -1.9802 0.87404E-02 -2.0585 0.83507E+00 -0.0783 17 Ca(HSiO3)+ 0.16627E-07 -7.7792 0.13912E-07 -7.8566 0.83667E+00 -0.0774 18 Mg(HSiO3)+ 0.32225E-11 -11.4918 0.26961E-11 -11.5693 0.83667E+00 -0.0774 19 NaHSiO3,aq 0.23496E-02 -2.6290 0.23496E-02 -2.6290 0.10000E+01 0.0000 20 AlO+ 0.66281E-16 -16.1786 0.55456E-16 -16.2561 0.83667E+00 -0.0774 22 HAlO2,aq 0.14854E-09 -9.8282 0.14854E-09 -9.8282 0.10000E+01 0.0000 23 AlO2- 0.53052E-05 -5.2753 0.44222E-05 -5.3544 0.83356E+00 -0.0791 24 CH4,aq 0.20397E-04 -4.6904 0.20326E-04 -4.6920 0.99653E+00 -0.0015 25 C2H6,aq 0.61190E-14 -14.2133 0.60978E-14 -14.2148 0.99653E+00 -0.0015 29 CO,aq 0.15239E-16 -16.8170 0.15239E-16 -16.8170 0.10000E+01 0.0000 30 CO2,aq 0.52556E-10 -10.2794 0.52373E-10 -10.2809 0.99653E+00 -0.0015 31 CO3-2 0.74779E-06 -6.1262 0.38727E-06 -6.4120 0.51788E+00 -0.2858 32 CaCO3,aq 0.33938E-09 -9.4693 0.33938E-09 -9.4693 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.70291E-12 -12.1531 0.58811E-12 -12.2305 0.83667E+00 -0.0774 34 CaCl+ 0.25550E-10 -10.5926 0.21377E-10 -10.6700 0.83667E+00 -0.0774 35 CaCl2,aq 0.95992E-15 -15.0178 0.95992E-15 -15.0178 0.10000E+01 0.0000 36 CaOH+ 0.80070E-07 -7.0965 0.66992E-07 -7.1740 0.83667E+00 -0.0774 37 CaSO4,aq 0.12271E-16 -16.9111 0.12271E-16 -16.9111 0.10000E+01 0.0000 38 HCl,aq 0.25751E-14 -14.5892 0.25751E-14 -14.5892 0.10000E+01 0.0000 43 FeCl+ 0.10738E-16 -16.9691 0.89840E-17 -17.0465 0.83667E+00 -0.0774 46 FeO,aq 0.21113E-09 -9.6755 0.21113E-09 -9.6755 0.10000E+01 0.0000 47 FeOH+ 0.15714E-10 -10.8037 0.13147E-10 -10.8812 0.83667E+00 -0.0774 48 HFeO2- 0.35579E-07 -7.4488 0.29711E-07 -7.5271 0.83507E+00 -0.0783 49 FeO+ 0.11013E-16 -16.9581 0.92141E-17 -17.0355 0.83667E+00 -0.0774 51 FeO2- 0.40841E-09 -9.3889 0.34105E-09 -9.4672 0.83507E+00 -0.0783 52 HFeO2,aq 0.32251E-11 -11.4915 0.32251E-11 -11.4915 0.10000E+01 0.0000 53 H2,aq 0.11623E-04 -4.9347 0.11583E-04 -4.9362 0.99653E+00 -0.0015 54 KCl,aq 0.44954E-09 -9.3472 0.44954E-09 -9.3472 0.10000E+01 0.0000 56 KOH,aq 0.75375E-06 -6.1228 0.75375E-06 -6.1228 0.10000E+01 0.0000 57 KSO4- 0.13484E-14 -14.8702 0.11260E-14 -14.9485 0.83507E+00 -0.0783 58 MgCO3,aq 0.13247E-13 -13.8779 0.13247E-13 -13.8779 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.11185E-15 -15.9514 0.93582E-16 -16.0288 0.83667E+00 -0.0774 60 MgCl+ 0.36062E-14 -14.4429 0.30172E-14 -14.5204 0.83667E+00 -0.0774 61 MgOH+ 0.68998E-10 -10.1612 0.57728E-10 -10.2386 0.83667E+00 -0.0774 63 MnO,aq 0.18053E-08 -8.7435 0.18053E-08 -8.7435 0.10000E+01 0.0000 64 MnOH+ 0.46844E-09 -9.3293 0.39193E-09 -9.4068 0.83667E+00 -0.0774 65 MnO2-2 0.20927E-10 -10.6793 0.10838E-10 -10.9651 0.51788E+00 -0.2858 66 HMnO2- 0.21141E-09 -9.6749 0.17654E-09 -9.7532 0.83507E+00 -0.0783 69 MnCl+ 0.13406E-13 -13.8727 0.11216E-13 -13.9502 0.83667E+00 -0.0774 71 NaCl,aq 0.10411E-05 -5.9825 0.10411E-05 -5.9825 0.10000E+01 0.0000 72 NaOH,aq 0.96047E-04 -4.0175 0.96047E-04 -4.0175 0.10000E+01 0.0000 74 OH- 0.93225E-02 -2.0305 0.77708E-02 -2.1095 0.83356E+00 -0.0791 79 HPO3-2 0.16334E-14 -14.7869 0.84591E-15 -15.0727 0.51788E+00 -0.2858 81 H2PO3- 0.15103E-18 -18.8209 0.12612E-18 -18.8992 0.83507E+00 -0.0783 82 H3PO4,aq 0.90610E-18 -18.0428 0.90610E-18 -18.0428 0.10000E+01 0.0000 83 H2PO4- 0.38456E-10 -10.4150 0.32144E-10 -10.4929 0.83586E+00 -0.0779 84 PO4-3 0.10612E-08 -8.9742 0.25717E-09 -9.5898 0.24233E+00 -0.6156 88 HP2O7-3 0.94211E-18 -18.0259 0.21757E-18 -18.6624 0.23094E+00 -0.6365 89 P2O7-4 0.90884E-17 -17.0415 0.69906E-18 -18.1555 0.76918E-01 -1.1140 90 H2S,aq 0.80931E-08 -8.0919 0.80650E-08 -8.0934 0.99653E+00 -0.0015 91 S2-2 0.45502E-14 -14.3420 0.23565E-14 -14.6277 0.51788E+00 -0.2858 97 SO3-2 0.15841E-17 -17.8002 0.83225E-18 -18.0797 0.52539E+00 -0.2795 99 HSO4- 0.47308E-19 -19.3251 0.39619E-19 -19.4021 0.83748E+00 -0.0770 Charge balance for all species = 0.8600E-10 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.8850044E-10 -.2226070E-01 -.2239841E+02 0.0000 2 H2O 0.1000000E+01 0.5550490E+02 0.9981973E+06 0.0000 3 Cl- 0.2263369E-03 0.2273785E-03 0.8047221E+01 6.4052 4 SO4-- 0.1065402E-11 -.2330242E-04 -.2234573E+01 8.0001 5 HCO3- 0.3941881E-06 0.2153908E-04 0.1311967E+01 3.6468 6 HS- 0.4202272E-04 0.6533324E-04 0.2156941E+01 5.6740 7 Al+++ 0.9767706E-29 0.5305353E-05 0.1428973E+00 0.7390 8 H4SiO4 0.6959752E-03 0.1351231E-01 0.1296481E+04 -3.1574 9 Ca++ 0.1356632E-06 0.2327266E-06 0.9310987E-02 13.1018 10 Mg++ 0.2122372E-10 0.9346083E-10 0.2268266E-05 9.2942 11 Fe++ 0.5849601E-13 0.3621738E-07 0.2019112E-02 6.7350 12 K+ 0.1568822E-03 0.1576364E-03 0.6153174E+01 6.2467 13 Na+ 0.1990763E-01 0.2235435E-01 0.5130276E+03 8.3494 14 Mn++ 0.1875605E-10 0.2524825E-08 0.1384675E-03 9.2414 15 HPO4-- 0.4514952E-07 0.4624920E-07 0.4431227E-02 12.6273 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.6457818E+02 -.1350789E-01 -.6456467E+02 0.0000000E+00 2 H2O 0.6620163E+01 0.3368060E+02 -.2706043E+02 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.1081078E+00 -.1414000E-04 0.1081219E+00 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.1080823E+00 0.3964447E-04 -.1081219E+00 0.0000000E+00 7 Al+++ 0.1271689E+02 0.3219310E-05 0.1271689E+02 0.0000000E+00 8 H4SiO4 0.4060984E+02 0.8199324E-02 0.4060164E+02 0.0000000E+00 9 Ca++ 0.4485570E+01 0.1412195E-06 0.4485570E+01 0.0000000E+00 10 Mg++ 0.3095237E+01 0.5671241E-10 0.3095237E+01 0.0000000E+00 11 Fe++ 0.2780733E+01 0.2197685E-07 0.2780733E+01 0.0000000E+00 12 K+ 0.8280253E+00 0.9565443E-04 0.8279296E+00 0.0000000E+00 13 Na+ 0.4895609E+01 0.1356471E-01 0.4882044E+01 0.0000000E+00 14 Mn++ 0.6762051E-01 0.1532074E-08 0.6762051E-01 0.0000000E+00 15 HPO4-- 0.2307854E-01 0.2806420E-07 0.2307851E-01 0.0000000E+00 Chg. balance for solid moles: 0.1665E-15 Mass of aqueous solution: 0.607862E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 3899.9990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 4.878 0.688 1279. 3.107 30.02 491.0 andradite 0.4325 -0.364 219.8 2.342 5.158 57.10 grossular 0.1047 -0.980 47.17 1.674 1.107 13.13 apatite-OH 0.7693E-02 -2.114 3.864 0.587 0.9070E-01 1.228 clinochlore 0.5543 -0.256 308.1 2.489 7.232 117.2 daphnite 0.1605 -0.795 114.5 2.059 2.687 34.70 chlorite-Mn 0.1352E-01 -1.869 9.588 0.982 0.2250 3.056 diopside 0.2029 -0.693 43.93 1.643 1.031 13.43 hedenbergite 0.5261E-01 -1.279 13.05 1.116 0.3064 3.575 microcline 0.7260 -0.139 202.1 2.306 4.743 78.94 stilbite 2.513 0.400 1771. 3.248 41.57 826.1 stilpnomelane-Fe 0.2038 -0.691 219.7 2.342 5.157 75.90 tr.625ac.25prg.125 0.3331E-01 -1.477 28.47 1.454 0.6683 9.164 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8051E+00 0.8051E+00 1.0000 -0.094 grossular 0.1949E+00 0.1949E+00 1.0000 -0.710 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.7611E+00 0.7611E+00 1.0000 -0.119 daphnite 0.2203E+00 0.2203E+00 1.0000 -0.657 chlorite-Mn 0.1857E-01 0.1857E-01 1.0000 -1.731 diopside 0.7941E+00 0.7941E+00 1.0000 -0.100 hedenbergite 0.2059E+00 0.2059E+00 1.0000 -0.686 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 tr.625ac.25prg.125 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 4260.580550 g Volume = 1724.544153 cm3 Porosity: -10.4769% V(tot) - V(min): -.16354E+03 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 3899.9990000 g log = 3.5911 Original solution: 1000.0103000 g Original solution / Rock added: 0.26 (Water/Rock Ratio), log = -0.5911 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0657 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9580E+00 0.9853 0.1006E+01 0.1021E+01 CO2,gas 0.5223E-08 1.0068 0.5603E-08 0.5566E-08 CH4,gas 0.2773E-01 1.0123 0.2992E-01 0.2955E-01 H2,gas 0.1426E-01 1.0006 0.1521E-01 0.1520E-01 H2S,gas 0.2089E-06 0.9959 0.2217E-06 0.2226E-06 S2,gas 0.7487E-29 1.0000 0.7978E-29 0.7978E-29 CO,gas 0.2131E-13 1.0000 0.2271E-13 0.2271E-13 SO3,gas 0.1085E-47 1.0000 0.1156E-47 0.1156E-47 SO2,gas 0.6416E-27 1.0000 0.6838E-27 0.6838E-27 HCl,gas 0.4264E-17 1.0000 0.4544E-17 0.4544E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 16 albite -0.38 -0.38 0.00 0.000 0.11184E-10 22 andradite 39.01 39.01 0.00 0.000 0.00000E+00 23 grossular 32.73 32.73 0.00 0.000 0.12132E-10 32 apatite-OH -18.15 -18.15 0.00 0.000 0.60662E-11 46 clinochlore 39.07 39.07 0.00 0.000 0.36397E-10 47 daphnite 28.97 28.97 0.00 0.000 0.30331E-10 48 chlorite-Mn 46.87 46.87 0.00 0.000 0.36397E-10 67 diopside 16.18 16.18 0.00 0.000 0.60662E-11 68 hedenbergite 14.21 14.21 0.00 0.000 0.60662E-11 116 microcline -2.49 -2.49 0.00 0.000 0.15165E-11 163 stilbite -7.52 -7.52 0.00 0.000 0.15165E-10 164 stilpnomelane-Fe 13.02 13.02 0.00 0.000 0.21232E-10 245 tr.625ac.25prg.125 45.16 45.16 0.00 0.000 -0.36397E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -16.61 -9.95 -3.317 0.16990E+05 -8.252 3 CH4,gas 4.54 1.32 -3.22 -0.806 0.55032E+04 -1.524 4 H2,gas 8.00 4.48 -3.52 -2.010 0.60051E+04 -1.818 5 H2S,gas -6.23 -14.58 -8.35 -4.177 0.14263E+05 -6.654 6 S2,gas -7.34 -38.13 -30.80 -4.738 0.52585E+05 -29.098 7 CO,gas 3.21 -12.13 -15.34 -4.721 0.26197E+05 -13.644 8 SO3,gas 17.12 -32.51 -49.64 -12.409 0.84752E+05 -47.937 9 SO2,gas 0.83 -28.03 -28.86 -7.697 0.49285E+05 -27.165 10 HCl,gas 5.19 -13.85 -19.04 -9.521 0.32513E+05 -17.343 11 acmite 7.71 6.53 -1.18 -0.123 0.20175E+04 15 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 19 spessartine 24.46 19.73 -4.73 -0.236 0.80721E+04 20 analcite 3.32 2.77 -0.55 -0.061 0.93625E+03 26 annite 20.12 17.72 -2.40 -0.134 0.41064E+04 27 phlogopite 27.06 25.40 -1.67 -0.093 0.28489E+04 29 anorthite 12.71 8.26 -4.45 -0.342 0.75903E+04 35 aragonite 0.97 -3.51 -4.48 -1.492 0.76415E+04 36 brucite 12.57 9.29 -3.27 -0.655 0.55909E+04 37 calcite 0.81 -3.51 -4.32 -1.440 0.73773E+04 38 carnegieite-low 9.02 5.93 -3.09 -0.442 0.52801E+04 39 carnegieite-high 10.09 5.93 -4.16 -0.595 0.71071E+04 40 carpholite-Mg 8.58 4.46 -4.12 -0.275 0.70429E+04 41 carpholite-Fe 6.71 1.90 -4.81 -0.321 0.82207E+04 42 celadonite 5.34 3.65 -1.69 -0.099 0.28879E+04 43 celadonite-Fe 3.88 1.09 -2.79 -0.164 0.47561E+04 44 chrysotile 23.89 21.57 -2.32 -0.194 0.39692E+04 49 chlorite-Al-free 47.17 43.14 -4.04 -0.168 0.68936E+04 51 chloritoid-Fe 9.17 5.06 -4.12 -0.275 0.70315E+04 52 chloritoid-Mn 11.40 7.56 -3.84 -0.256 0.65553E+04 54 coesite -2.38 -3.16 -0.78 -0.260 0.13341E+04 61 cristobalite -2.56 -3.16 -0.60 -0.199 0.10195E+04 63 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71234E+04 65 diaspore 2.87 0.74 -2.13 -0.356 0.36450E+04 66 diamond -3.10 -7.64 -4.54 -1.298 0.77564E+04 71 enstatite 17.26 12.27 -4.99 -0.499 0.85226E+04 73 clinoenstatite 17.17 12.27 -4.89 -0.489 0.83541E+04 75 epidote 24.67 22.70 -1.97 -0.095 0.33585E+04 76 clinozoisite 22.81 18.95 -3.86 -0.175 0.65868E+04 77 epidote-Fe 29.84 26.46 -3.38 -0.176 0.57768E+04 78 fayalite 14.05 10.31 -3.73 -0.533 0.63743E+04 79 ferrosilite 11.15 7.16 -3.99 -0.399 0.68202E+04 83 gibbsite 4.08 0.74 -3.34 -0.477 0.57035E+04 84 glaucophane 22.97 20.80 -2.17 -0.059 0.37133E+04 85 glaucophane-Fe 17.28 13.12 -4.15 -0.112 0.70919E+04 86 graphite -3.55 -7.64 -4.10 -1.171 0.69986E+04 87 greenalite 16.14 13.89 -2.25 -0.187 0.38408E+04 90 hematite 12.57 8.99 -3.58 -0.434 0.61111E+04 91 heulandite -5.83 -7.52 -1.69 -0.077 0.28938E+04 95 jadeite 4.22 2.77 -1.44 -0.144 0.24617E+04 97 kalsilite 7.58 3.83 -3.76 -0.537 0.64126E+04 98 kaolinite -1.33 -4.84 -3.50 -0.319 0.59831E+04 101 laumontite 2.88 1.95 -0.93 -0.062 0.15935E+04 102 lawsonite 9.62 8.26 -1.35 -0.090 0.23070E+04 103 leucite 4.12 0.67 -3.45 -0.345 0.58873E+04 105 lizardite 23.24 21.57 -1.68 -0.140 0.28618E+04 107 magnetite 20.09 15.72 -4.37 -0.356 0.74536E+04 108 minnesotaite 10.39 7.58 -2.81 -0.165 0.48028E+04 112 manganosite 14.06 9.24 -4.82 -1.204 0.82245E+04 120 muscovite 2.58 -1.01 -3.59 -0.211 0.61315E+04 121 paragonite 4.24 1.09 -3.15 -0.185 0.53706E+04 122 nepheline 8.34 5.93 -2.41 -0.344 0.41125E+04 128 periclase-Fe 11.63 6.73 -4.89 -1.223 0.83523E+04 134 phlogopite-Na 29.65 27.50 -2.15 -0.119 0.36677E+04 136 prehnite 19.37 18.21 -1.16 -0.068 0.19849E+04 137 prehnite-Fe 22.50 21.96 -0.53 -0.032 0.91158E+03 138 pumpellyite-Fe 46.27 43.89 -2.38 -0.053 0.40581E+04 139 pumpellyite-Mg 48.99 46.45 -2.54 -0.057 0.43419E+04 143 pyrrhotite -4.26 -7.85 -3.59 -1.196 0.61267E+04 144 pyrrhotiteFe0.875 -6.02 -9.25 -3.23 -1.188 0.55139E+04 145 pyroxmangite 7.40 6.08 -1.31 -0.263 0.22449E+04 146 pyrophyllite -6.18 -11.15 -4.98 -0.311 0.84962E+04 147 quartz -2.99 -3.16 -0.17 -0.056 0.28681E+03 152 rhodonite 7.45 6.08 -1.36 -0.272 0.23251E+04 153 sanidine -1.28 -2.49 -1.21 -0.093 0.20677E+04 165 stilpnomelane-Mg 27.44 25.81 -1.63 -0.049 0.27803E+04 171 talc 16.49 15.25 -1.24 -0.073 0.21140E+04 174 tephroite 18.09 15.33 -2.76 -0.394 0.47135E+04 178 tridymite -2.63 -3.16 -0.53 -0.177 0.90678E+03 179 tremolite 47.87 47.42 -0.45 -0.012 0.77495E+03 180 ferroactinolite 38.45 34.62 -3.83 -0.104 0.65449E+04 181 troilite-low -4.41 -7.85 -3.44 -1.146 0.58695E+04 183 vesuvianite 223.47 218.82 -4.65 -0.036 0.79437E+04 187 wairakite 3.95 1.95 -2.00 -0.118 0.34155E+04 188 walstromite 11.51 9.94 -1.56 -0.313 0.26719E+04 189 wollastonite 10.46 9.94 -0.52 -0.103 0.88229E+03 190 pseudo-wollastonite 11.00 9.94 -1.06 -0.211 0.18021E+04 191 zoisite 22.85 18.95 -3.90 -0.177 0.66609E+04 192 akaganeite 7.75 4.49 -3.26 -0.705 0.55681E+04 199 chalcedony -2.80 -3.16 -0.35 -0.118 0.60610E+03 201 montmorillonite-Ca -2.29 -6.17 -3.88 -0.240 0.66180E+04 202 montmorillonite-K -2.24 -6.27 -4.03 -0.247 0.68816E+04 203 montmorillonite-Mg -2.48 -6.79 -4.32 -0.267 0.73678E+04 204 montmorillonite-Na -2.04 -5.57 -3.54 -0.216 0.60365E+04 205 nontronite-Ca 3.21 -0.19 -3.41 -0.221 0.58215E+04 206 nontronite-H 2.53 -2.36 -4.89 -0.328 0.83485E+04 207 nontronite-K 3.34 -0.30 -3.64 -0.233 0.62083E+04 208 nontronite-Mg 3.07 -0.82 -3.90 -0.253 0.66553E+04 209 nontronite-Na 3.52 0.40 -3.12 -0.200 0.53292E+04 224 tobermorite 9.82 7.76 -2.07 -0.564 0.35287E+04 230 alabandite -0.98 -5.34 -4.36 -1.455 0.74518E+04 233 boehmite 4.41 0.74 -3.67 -0.611 0.62619E+04 235 ferrous-oxide 9.81 6.73 -3.08 -0.769 0.52532E+04 240 silica-amorphous -2.09 -3.16 -1.07 -0.355 0.18203E+04 242 an20ab80 2.02 1.35 -0.67 -0.052 0.11472E+04 243 an25ab75 2.65 1.78 -0.87 -0.067 0.14810E+04 244 an30ab70 3.28 2.21 -1.07 -0.082 0.18244E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 100.0000000 g Current total amount of reactant added: 3899.9990000 g New total amount of reactant added: 3999.9990000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.5221E-10 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 11 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 3999.9990000 Water: Moles liquid = 0.3313E+02 kg liquid = 0.5968E+00 Moles total = 0.5367E+01 kg total = 0.9668E-01 Activity = 1.0000 Stoichiometric ionic strength = .1139488E-01 Osmotic coef. = 0.9687 True ionic strength = .2006829E-01 Chg. balance for total moles = 0.5221E-10 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.88511E-10 -10.0530 0.74360E-10 -10.1287 0.84012E+00 -0.0757 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.23015E-03 -3.6380 0.19219E-03 -3.7163 0.83506E+00 -0.0783 4 SO4-- 0.10832E-11 -11.9653 0.56217E-12 -12.2501 0.51897E+00 -0.2849 5 HCO3- 0.40078E-06 -6.3971 0.33517E-06 -6.4747 0.83628E+00 -0.0776 6 HS- 0.42730E-04 -4.3693 0.35687E-04 -4.4475 0.83518E+00 -0.0782 7 Al+++ 0.97718E-29 -29.0100 0.22542E-29 -29.6470 0.23069E+00 -0.6370 8 H4SiO4 0.69598E-03 -3.1574 0.69598E-03 -3.1574 0.10000E+01 0.0000 9 Ca++ 0.13570E-06 -6.8674 0.69905E-07 -7.1555 0.51515E+00 -0.2881 10 Mg++ 0.21229E-10 -10.6731 0.10886E-10 -10.9631 0.51279E+00 -0.2901 11 Fe++ 0.58511E-13 -13.2328 0.30037E-13 -13.5223 0.51335E+00 -0.2896 12 K+ 0.15690E-03 -3.8044 0.13125E-03 -3.8819 0.83648E+00 -0.0775 13 Na+ 0.19910E-01 -1.7009 0.16623E-01 -1.7793 0.83491E+00 -0.0784 14 Mn++ 0.18762E-10 -10.7267 0.96396E-11 -11.0159 0.51378E+00 -0.2892 15 HPO4-- 0.45141E-07 -7.3454 0.23430E-07 -7.6302 0.51904E+00 -0.2848 16 HSiO3- 0.10466E-01 -1.9802 0.87394E-02 -2.0585 0.83506E+00 -0.0783 17 Ca(HSiO3)+ 0.16629E-07 -7.7791 0.13913E-07 -7.8566 0.83666E+00 -0.0775 18 Mg(HSiO3)+ 0.32229E-11 -11.4918 0.26964E-11 -11.5692 0.83666E+00 -0.0775 19 NaHSiO3,aq 0.23496E-02 -2.6290 0.23496E-02 -2.6290 0.10000E+01 0.0000 20 AlO+ 0.66289E-16 -16.1786 0.55462E-16 -16.2560 0.83666E+00 -0.0775 22 HAlO2,aq 0.14854E-09 -9.8282 0.14854E-09 -9.8282 0.10000E+01 0.0000 23 AlO2- 0.53046E-05 -5.2753 0.44217E-05 -5.3544 0.83355E+00 -0.0791 24 CH4,aq 0.20740E-04 -4.6832 0.20668E-04 -4.6847 0.99653E+00 -0.0015 25 C2H6,aq 0.63268E-14 -14.1988 0.63048E-14 -14.2003 0.99653E+00 -0.0015 29 CO,aq 0.15495E-16 -16.8098 0.15495E-16 -16.8098 0.10000E+01 0.0000 30 CO2,aq 0.53441E-10 -10.2721 0.53255E-10 -10.2736 0.99653E+00 -0.0015 31 CO3-2 0.76024E-06 -6.1190 0.39370E-06 -6.4048 0.51787E+00 -0.2858 32 CaCO3,aq 0.34509E-09 -9.4621 0.34509E-09 -9.4621 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.71484E-12 -12.1458 0.59808E-12 -12.2232 0.83666E+00 -0.0775 34 CaCl+ 0.25986E-10 -10.5853 0.21742E-10 -10.6627 0.83666E+00 -0.0775 35 CaCl2,aq 0.99271E-15 -15.0032 0.99271E-15 -15.0032 0.10000E+01 0.0000 36 CaOH+ 0.80080E-07 -7.0965 0.67000E-07 -7.1739 0.83666E+00 -0.0775 37 CaSO4,aq 0.12479E-16 -16.9038 0.12479E-16 -16.9038 0.10000E+01 0.0000 38 HCl,aq 0.26187E-14 -14.5819 0.26187E-14 -14.5819 0.10000E+01 0.0000 43 FeCl+ 0.10921E-16 -16.9617 0.91372E-17 -17.0392 0.83666E+00 -0.0775 46 FeO,aq 0.21113E-09 -9.6755 0.21113E-09 -9.6755 0.10000E+01 0.0000 47 FeOH+ 0.15716E-10 -10.8037 0.13149E-10 -10.8811 0.83666E+00 -0.0775 48 HFeO2- 0.35575E-07 -7.4489 0.29707E-07 -7.5271 0.83506E+00 -0.0783 49 FeO+ 0.11014E-16 -16.9580 0.92151E-17 -17.0355 0.83666E+00 -0.0775 51 FeO2- 0.40837E-09 -9.3889 0.34101E-09 -9.4672 0.83506E+00 -0.0783 52 HFeO2,aq 0.32251E-11 -11.4915 0.32251E-11 -11.4915 0.10000E+01 0.0000 53 H2,aq 0.11623E-04 -4.9347 0.11583E-04 -4.9362 0.99653E+00 -0.0015 54 KCl,aq 0.45715E-09 -9.3399 0.45715E-09 -9.3399 0.10000E+01 0.0000 56 KOH,aq 0.75375E-06 -6.1228 0.75375E-06 -6.1228 0.10000E+01 0.0000 57 KSO4- 0.13711E-14 -14.8629 0.11449E-14 -14.9412 0.83506E+00 -0.0783 58 MgCO3,aq 0.13470E-13 -13.8706 0.13470E-13 -13.8706 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.11375E-15 -15.9441 0.95169E-16 -16.0215 0.83666E+00 -0.0775 60 MgCl+ 0.36678E-14 -14.4356 0.30687E-14 -14.5130 0.83666E+00 -0.0775 61 MgOH+ 0.69006E-10 -10.1611 0.57735E-10 -10.2386 0.83666E+00 -0.0775 63 MnO,aq 0.18054E-08 -8.7434 0.18054E-08 -8.7434 0.10000E+01 0.0000 64 MnOH+ 0.46852E-09 -9.3293 0.39200E-09 -9.4067 0.83666E+00 -0.0775 65 MnO2-2 0.20924E-10 -10.6794 0.10836E-10 -10.9651 0.51787E+00 -0.2858 66 HMnO2- 0.21139E-09 -9.6749 0.17653E-09 -9.7532 0.83506E+00 -0.0783 69 MnCl+ 0.13635E-13 -13.8653 0.11408E-13 -13.9428 0.83666E+00 -0.0775 71 NaCl,aq 0.10587E-05 -5.9752 0.10587E-05 -5.9752 0.10000E+01 0.0000 72 NaOH,aq 0.96047E-04 -4.0175 0.96047E-04 -4.0175 0.10000E+01 0.0000 74 OH- 0.93215E-02 -2.0305 0.77699E-02 -2.1096 0.83355E+00 -0.0791 79 HPO3-2 0.16331E-14 -14.7870 0.84572E-15 -15.0728 0.51787E+00 -0.2858 81 H2PO3- 0.15102E-18 -18.8210 0.12611E-18 -18.8993 0.83506E+00 -0.0783 82 H3PO4,aq 0.90610E-18 -18.0428 0.90610E-18 -18.0428 0.10000E+01 0.0000 83 H2PO4- 0.38452E-10 -10.4151 0.32140E-10 -10.4930 0.83585E+00 -0.0779 84 PO4-3 0.10609E-08 -8.9743 0.25708E-09 -9.5899 0.24231E+00 -0.6156 88 HP2O7-3 0.94186E-18 -18.0260 0.21749E-18 -18.6626 0.23092E+00 -0.6365 89 P2O7-4 0.90854E-17 -17.0417 0.69874E-18 -18.1557 0.76908E-01 -1.1140 90 H2S,aq 0.82302E-08 -8.0846 0.82016E-08 -8.0861 0.99653E+00 -0.0015 91 S2-2 0.47047E-14 -14.3275 0.24364E-14 -14.6133 0.51787E+00 -0.2858 97 SO3-2 0.16106E-17 -17.7930 0.84616E-18 -18.0725 0.52537E+00 -0.2795 99 HSO4- 0.48104E-19 -19.3178 0.40286E-19 -19.3948 0.83748E+00 -0.0770 Charge balance for all species = 0.8749E-10 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.8851124E-10 -.2225863E-01 -.2239632E+02 0.0000 2 H2O 0.1000000E+01 0.5550490E+02 0.9981972E+06 0.0000 3 Cl- 0.2301457E-03 0.2312049E-03 0.8182643E+01 6.4124 4 SO4-- 0.1083240E-11 -.2364584E-04 -.2267504E+01 8.0072 5 HCO3- 0.4007848E-06 0.2190155E-04 0.1334046E+01 3.6539 6 HS- 0.4272990E-04 0.6638398E-04 0.2191630E+01 5.6812 7 Al+++ 0.9771755E-29 0.5304781E-05 0.1428819E+00 0.7390 8 H4SiO4 0.6959756E-03 0.1351121E-01 0.1296375E+04 -3.1574 9 Ca++ 0.1356986E-06 0.2327799E-06 0.9313118E-02 13.1018 10 Mg++ 0.2122927E-10 0.9347610E-10 0.2268636E-05 9.2942 11 Fe++ 0.5851130E-13 0.3621356E-07 0.2018899E-02 6.7350 12 K+ 0.1569014E-03 0.1576556E-03 0.6153922E+01 6.2467 13 Na+ 0.1991007E-01 0.2235680E-01 0.5130840E+03 8.3494 14 Mn++ 0.1876203E-10 0.2525005E-08 0.1384773E-03 9.2414 15 HPO4-- 0.4514071E-07 0.4624009E-07 0.4430354E-02 12.6271 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.6623403E+02 -.1328309E-01 -.6622075E+02 0.0000000E+00 2 H2O 0.5366622E+01 0.3312318E+02 -.2775656E+02 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.1108791E+00 -.1411093E-04 0.1108932E+00 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.1108536E+00 0.3961540E-04 -.1108932E+00 0.0000000E+00 7 Al+++ 0.1304296E+02 0.3165689E-05 0.1304296E+02 0.0000000E+00 8 H4SiO4 0.4165112E+02 0.8062968E-02 0.4164306E+02 0.0000000E+00 9 Ca++ 0.4600584E+01 0.1389141E-06 0.4600584E+01 0.0000000E+00 10 Mg++ 0.3174602E+01 0.5578293E-10 0.3174602E+01 0.0000000E+00 11 Fe++ 0.2852034E+01 0.2161085E-07 0.2852034E+01 0.0000000E+00 12 K+ 0.8492567E+00 0.9408281E-04 0.8491626E+00 0.0000000E+00 13 Na+ 0.5021133E+01 0.1334168E-01 0.5007792E+01 0.0000000E+00 14 Mn++ 0.6935437E-01 0.1506825E-08 0.6935437E-01 0.0000000E+00 15 HPO4-- 0.2367030E-01 0.2759431E-07 0.2367027E-01 0.0000000E+00 Chg. balance for solid moles: 0.1098E-13 Mass of aqueous solution: 0.597802E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 3999.9990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 5.004 0.699 1312. 3.118 30.02 503.7 andradite 0.4436 -0.353 225.4 2.353 5.158 58.56 grossular 0.1074 -0.969 48.38 1.685 1.107 13.46 apatite-OH 0.7890E-02 -2.103 3.963 0.598 0.9070E-01 1.259 clinochlore 0.5685 -0.245 316.0 2.500 7.231 120.2 daphnite 0.1646 -0.784 117.4 2.070 2.687 35.58 chlorite-Mn 0.1387E-01 -1.858 9.834 0.993 0.2250 3.134 diopside 0.2083 -0.681 45.11 1.654 1.032 13.79 hedenbergite 0.5402E-01 -1.267 13.40 1.127 0.3067 3.671 microcline 0.7446 -0.128 207.3 2.317 4.743 80.96 stilbite 2.578 0.411 1816. 3.259 41.57 847.2 stilpnomelane-Fe 0.2091 -0.680 225.4 2.353 5.157 77.85 tr.625ac.25prg.125 0.3414E-01 -1.467 29.18 1.465 0.6679 9.393 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8051E+00 0.8051E+00 1.0000 -0.094 grossular 0.1949E+00 0.1949E+00 1.0000 -0.710 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.7611E+00 0.7611E+00 1.0000 -0.119 daphnite 0.2203E+00 0.2203E+00 1.0000 -0.657 chlorite-Mn 0.1857E-01 0.1857E-01 1.0000 -1.731 diopside 0.7941E+00 0.7941E+00 1.0000 -0.100 hedenbergite 0.2059E+00 0.2059E+00 1.0000 -0.686 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 tr.625ac.25prg.125 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 4369.831215 g Volume = 1768.747217 cm3 Porosity: -10.4777% V(tot) - V(min): -.16775E+03 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 3999.9990000 g log = 3.6021 Original solution: 1000.0103000 g Original solution / Rock added: 0.25 (Water/Rock Ratio), log = -0.6021 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0662 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9576E+00 0.9853 0.1006E+01 0.1021E+01 CO2,gas 0.5308E-08 1.0068 0.5698E-08 0.5659E-08 CH4,gas 0.2819E-01 1.0123 0.3042E-01 0.3005E-01 H2,gas 0.1425E-01 1.0006 0.1521E-01 0.1520E-01 H2S,gas 0.2123E-06 0.9959 0.2255E-06 0.2264E-06 S2,gas 0.7739E-29 1.0000 0.8251E-29 0.8251E-29 CO,gas 0.2166E-13 1.0000 0.2309E-13 0.2309E-13 SO3,gas 0.1102E-47 1.0000 0.1175E-47 0.1175E-47 SO2,gas 0.6522E-27 1.0000 0.6953E-27 0.6953E-27 HCl,gas 0.4334E-17 1.0000 0.4621E-17 0.4621E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 16 albite -0.38 -0.38 0.00 0.000 -0.94784E-12 22 andradite 39.01 39.01 0.00 0.000 -0.36397E-10 23 grossular 32.73 32.73 0.00 0.000 0.12132E-10 32 apatite-OH -18.15 -18.15 0.00 0.000 -0.60662E-11 46 clinochlore 39.07 39.07 0.00 0.000 -0.12132E-10 47 daphnite 28.97 28.97 0.00 0.000 -0.60662E-11 48 chlorite-Mn 46.87 46.87 0.00 0.000 0.00000E+00 67 diopside 16.18 16.18 0.00 0.000 -0.60662E-11 68 hedenbergite 14.21 14.21 0.00 0.000 0.00000E+00 116 microcline -2.49 -2.49 0.00 0.000 0.15165E-11 163 stilbite -7.52 -7.52 0.00 0.000 -0.90992E-11 164 stilpnomelane-Fe 13.02 13.02 0.00 0.000 0.21232E-10 245 tr.625ac.25prg.125 45.16 45.16 0.00 0.000 -0.36397E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -16.60 -9.94 -3.314 0.16978E+05 -8.244 3 CH4,gas 4.54 1.33 -3.22 -0.804 0.54909E+04 -1.517 4 H2,gas 8.00 4.48 -3.52 -2.010 0.60051E+04 -1.818 5 H2S,gas -6.23 -14.58 -8.35 -4.173 0.14250E+05 -6.647 6 S2,gas -7.34 -38.12 -30.78 -4.736 0.52560E+05 -29.083 7 CO,gas 3.21 -12.12 -15.34 -4.719 0.26185E+05 -13.637 8 SO3,gas 17.12 -32.51 -49.63 -12.407 0.84740E+05 -47.930 9 SO2,gas 0.83 -28.02 -28.86 -7.695 0.49272E+05 -27.158 10 HCl,gas 5.19 -13.84 -19.03 -9.517 0.32500E+05 -17.335 11 acmite 7.71 6.53 -1.18 -0.123 0.20175E+04 15 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 19 spessartine 24.46 19.73 -4.73 -0.236 0.80720E+04 20 analcite 3.32 2.77 -0.55 -0.061 0.93625E+03 26 annite 20.12 17.72 -2.40 -0.134 0.41064E+04 27 phlogopite 27.06 25.40 -1.67 -0.093 0.28489E+04 29 anorthite 12.71 8.26 -4.45 -0.342 0.75903E+04 35 aragonite 0.97 -3.50 -4.47 -1.489 0.76291E+04 36 brucite 12.57 9.29 -3.27 -0.655 0.55909E+04 37 calcite 0.81 -3.50 -4.31 -1.438 0.73649E+04 38 carnegieite-low 9.02 5.93 -3.09 -0.442 0.52801E+04 39 carnegieite-high 10.09 5.93 -4.16 -0.595 0.71071E+04 40 carpholite-Mg 8.58 4.46 -4.12 -0.275 0.70429E+04 41 carpholite-Fe 6.71 1.90 -4.81 -0.321 0.82207E+04 42 celadonite 5.34 3.65 -1.69 -0.099 0.28879E+04 43 celadonite-Fe 3.88 1.09 -2.79 -0.164 0.47561E+04 44 chrysotile 23.89 21.57 -2.32 -0.194 0.39692E+04 49 chlorite-Al-free 47.17 43.14 -4.04 -0.168 0.68936E+04 51 chloritoid-Fe 9.17 5.06 -4.12 -0.275 0.70315E+04 52 chloritoid-Mn 11.40 7.56 -3.84 -0.256 0.65552E+04 54 coesite -2.38 -3.16 -0.78 -0.260 0.13341E+04 61 cristobalite -2.56 -3.16 -0.60 -0.199 0.10195E+04 63 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71234E+04 65 diaspore 2.87 0.74 -2.13 -0.356 0.36450E+04 66 diamond -3.10 -7.64 -4.54 -1.296 0.77440E+04 71 enstatite 17.26 12.27 -4.99 -0.499 0.85226E+04 73 clinoenstatite 17.17 12.27 -4.89 -0.489 0.83541E+04 75 epidote 24.67 22.70 -1.97 -0.095 0.33585E+04 76 clinozoisite 22.81 18.95 -3.86 -0.175 0.65868E+04 77 epidote-Fe 29.84 26.46 -3.38 -0.176 0.57768E+04 78 fayalite 14.05 10.31 -3.73 -0.533 0.63743E+04 79 ferrosilite 11.15 7.16 -3.99 -0.399 0.68202E+04 83 gibbsite 4.08 0.74 -3.34 -0.477 0.57035E+04 84 glaucophane 22.97 20.80 -2.17 -0.059 0.37133E+04 85 glaucophane-Fe 17.28 13.12 -4.15 -0.112 0.70919E+04 86 graphite -3.55 -7.64 -4.09 -1.169 0.69862E+04 87 greenalite 16.14 13.89 -2.25 -0.187 0.38408E+04 90 hematite 12.57 8.99 -3.58 -0.434 0.61111E+04 91 heulandite -5.83 -7.52 -1.69 -0.077 0.28938E+04 95 jadeite 4.22 2.77 -1.44 -0.144 0.24617E+04 97 kalsilite 7.58 3.83 -3.76 -0.537 0.64126E+04 98 kaolinite -1.33 -4.84 -3.50 -0.319 0.59831E+04 101 laumontite 2.88 1.95 -0.93 -0.062 0.15935E+04 102 lawsonite 9.62 8.26 -1.35 -0.090 0.23070E+04 103 leucite 4.12 0.67 -3.45 -0.345 0.58873E+04 105 lizardite 23.24 21.57 -1.68 -0.140 0.28618E+04 107 magnetite 20.09 15.72 -4.37 -0.356 0.74536E+04 108 minnesotaite 10.39 7.58 -2.81 -0.165 0.48028E+04 112 manganosite 14.06 9.24 -4.82 -1.204 0.82244E+04 120 muscovite 2.58 -1.01 -3.59 -0.211 0.61315E+04 121 paragonite 4.24 1.09 -3.15 -0.185 0.53706E+04 122 nepheline 8.34 5.93 -2.41 -0.344 0.41125E+04 128 periclase-Fe 11.63 6.73 -4.89 -1.223 0.83523E+04 134 phlogopite-Na 29.65 27.50 -2.15 -0.119 0.36677E+04 136 prehnite 19.37 18.21 -1.16 -0.068 0.19849E+04 137 prehnite-Fe 22.50 21.96 -0.53 -0.032 0.91158E+03 138 pumpellyite-Fe 46.27 43.89 -2.38 -0.053 0.40581E+04 139 pumpellyite-Mg 48.99 46.45 -2.54 -0.057 0.43419E+04 143 pyrrhotite -4.26 -7.84 -3.58 -1.194 0.61142E+04 144 pyrrhotiteFe0.875 -6.02 -9.24 -3.22 -1.185 0.55014E+04 145 pyroxmangite 7.40 6.08 -1.31 -0.263 0.22448E+04 146 pyrophyllite -6.18 -11.15 -4.98 -0.311 0.84962E+04 147 quartz -2.99 -3.16 -0.17 -0.056 0.28681E+03 152 rhodonite 7.45 6.08 -1.36 -0.272 0.23251E+04 153 sanidine -1.28 -2.49 -1.21 -0.093 0.20677E+04 165 stilpnomelane-Mg 27.44 25.81 -1.63 -0.049 0.27803E+04 171 talc 16.49 15.25 -1.24 -0.073 0.21140E+04 174 tephroite 18.09 15.33 -2.76 -0.394 0.47134E+04 178 tridymite -2.63 -3.16 -0.53 -0.177 0.90678E+03 179 tremolite 47.87 47.42 -0.45 -0.012 0.77495E+03 180 ferroactinolite 38.45 34.62 -3.83 -0.104 0.65449E+04 181 troilite-low -4.41 -7.84 -3.43 -1.143 0.58570E+04 183 vesuvianite 223.47 218.82 -4.65 -0.036 0.79437E+04 187 wairakite 3.95 1.95 -2.00 -0.118 0.34155E+04 188 walstromite 11.51 9.94 -1.56 -0.313 0.26719E+04 189 wollastonite 10.46 9.94 -0.52 -0.103 0.88229E+03 190 pseudo-wollastonite 11.00 9.94 -1.06 -0.211 0.18021E+04 191 zoisite 22.85 18.95 -3.90 -0.177 0.66609E+04 192 akaganeite 7.75 4.49 -3.26 -0.705 0.55681E+04 199 chalcedony -2.80 -3.16 -0.35 -0.118 0.60610E+03 201 montmorillonite-Ca -2.29 -6.17 -3.88 -0.240 0.66180E+04 202 montmorillonite-K -2.24 -6.27 -4.03 -0.247 0.68816E+04 203 montmorillonite-Mg -2.48 -6.79 -4.32 -0.267 0.73678E+04 204 montmorillonite-Na -2.04 -5.57 -3.54 -0.216 0.60365E+04 205 nontronite-Ca 3.21 -0.19 -3.41 -0.221 0.58215E+04 206 nontronite-H 2.53 -2.36 -4.89 -0.328 0.83485E+04 207 nontronite-K 3.34 -0.30 -3.64 -0.233 0.62083E+04 208 nontronite-Mg 3.07 -0.82 -3.90 -0.253 0.66553E+04 209 nontronite-Na 3.52 0.40 -3.12 -0.200 0.53292E+04 224 tobermorite 9.82 7.76 -2.07 -0.564 0.35287E+04 230 alabandite -0.98 -5.33 -4.36 -1.452 0.74393E+04 233 boehmite 4.41 0.74 -3.67 -0.611 0.62619E+04 235 ferrous-oxide 9.81 6.73 -3.08 -0.769 0.52532E+04 240 silica-amorphous -2.09 -3.16 -1.07 -0.355 0.18203E+04 242 an20ab80 2.02 1.35 -0.67 -0.052 0.11472E+04 243 an25ab75 2.65 1.78 -0.87 -0.067 0.14810E+04 244 an30ab70 3.28 2.21 -1.07 -0.082 0.18244E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 100.0000000 g Current total amount of reactant added: 3999.9990000 g New total amount of reactant added: 4099.9990000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.5221E-10 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 11 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 4099.9990000 Water: Moles liquid = 0.3257E+02 kg liquid = 0.5867E+00 Moles total = 0.4113E+01 kg total = 0.7410E-01 Activity = 1.0000 Stoichiometric ionic strength = .1139816E-01 Osmotic coef. = 0.9687 True ionic strength = .2007084E-01 Chg. balance for total moles = 0.5221E-10 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.88522E-10 -10.0529 0.74369E-10 -10.1286 0.84011E+00 -0.0757 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.23408E-03 -3.6306 0.19547E-03 -3.7089 0.83505E+00 -0.0783 4 SO4-- 0.11017E-11 -11.9579 0.57172E-12 -12.2428 0.51895E+00 -0.2849 5 HCO3- 0.40761E-06 -6.3898 0.34087E-06 -6.4674 0.83628E+00 -0.0777 6 HS- 0.43461E-04 -4.3619 0.36298E-04 -4.4401 0.83517E+00 -0.0782 7 Al+++ 0.97759E-29 -29.0098 0.22550E-29 -29.6468 0.23067E+00 -0.6370 8 H4SiO4 0.69598E-03 -3.1574 0.69598E-03 -3.1574 0.10000E+01 0.0000 9 Ca++ 0.13574E-06 -6.8673 0.69922E-07 -7.1554 0.51513E+00 -0.2881 10 Mg++ 0.21235E-10 -10.6729 0.10889E-10 -10.9630 0.51277E+00 -0.2901 11 Fe++ 0.58527E-13 -13.2326 0.30044E-13 -13.5222 0.51334E+00 -0.2896 12 K+ 0.15692E-03 -3.8043 0.13126E-03 -3.8819 0.83647E+00 -0.0775 13 Na+ 0.19913E-01 -1.7009 0.16625E-01 -1.7792 0.83490E+00 -0.0784 14 Mn++ 0.18768E-10 -10.7266 0.96424E-11 -11.0158 0.51376E+00 -0.2892 15 HPO4-- 0.45132E-07 -7.3455 0.23424E-07 -7.6303 0.51903E+00 -0.2848 16 HSiO3- 0.10464E-01 -1.9803 0.87384E-02 -2.0586 0.83505E+00 -0.0783 17 Ca(HSiO3)+ 0.16632E-07 -7.7791 0.13915E-07 -7.8565 0.83665E+00 -0.0775 18 Mg(HSiO3)+ 0.32233E-11 -11.4917 0.26968E-11 -11.5692 0.83665E+00 -0.0775 19 NaHSiO3,aq 0.23496E-02 -2.6290 0.23496E-02 -2.6290 0.10000E+01 0.0000 20 AlO+ 0.66298E-16 -16.1785 0.55468E-16 -16.2560 0.83665E+00 -0.0775 22 HAlO2,aq 0.14854E-09 -9.8282 0.14854E-09 -9.8282 0.10000E+01 0.0000 23 AlO2- 0.53040E-05 -5.2754 0.44211E-05 -5.3545 0.83354E+00 -0.0791 24 CH4,aq 0.21095E-04 -4.6758 0.21022E-04 -4.6773 0.99652E+00 -0.0015 25 C2H6,aq 0.65454E-14 -14.1841 0.65226E-14 -14.1856 0.99652E+00 -0.0015 29 CO,aq 0.15761E-16 -16.8024 0.15761E-16 -16.8024 0.10000E+01 0.0000 30 CO2,aq 0.54356E-10 -10.2648 0.54167E-10 -10.2663 0.99652E+00 -0.0015 31 CO3-2 0.77311E-06 -6.1118 0.40035E-06 -6.3976 0.51785E+00 -0.2858 32 CaCO3,aq 0.35101E-09 -9.4547 0.35101E-09 -9.4547 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.72718E-12 -12.1384 0.60840E-12 -12.2158 0.83665E+00 -0.0775 34 CaCl+ 0.26437E-10 -10.5778 0.22119E-10 -10.6552 0.83665E+00 -0.0775 35 CaCl2,aq 0.10272E-14 -14.9883 0.10272E-14 -14.9883 0.10000E+01 0.0000 36 CaOH+ 0.80090E-07 -7.0964 0.67008E-07 -7.1739 0.83665E+00 -0.0775 37 CaSO4,aq 0.12694E-16 -16.8964 0.12694E-16 -16.8964 0.10000E+01 0.0000 38 HCl,aq 0.26639E-14 -14.5745 0.26639E-14 -14.5745 0.10000E+01 0.0000 43 FeCl+ 0.11111E-16 -16.9543 0.92957E-17 -17.0317 0.83665E+00 -0.0775 46 FeO,aq 0.21113E-09 -9.6755 0.21113E-09 -9.6755 0.10000E+01 0.0000 47 FeOH+ 0.15718E-10 -10.8036 0.13150E-10 -10.8811 0.83665E+00 -0.0775 48 HFeO2- 0.35571E-07 -7.4489 0.29704E-07 -7.5272 0.83505E+00 -0.0783 49 FeO+ 0.11016E-16 -16.9580 0.92162E-17 -17.0354 0.83665E+00 -0.0775 51 FeO2- 0.40833E-09 -9.3890 0.34097E-09 -9.4673 0.83505E+00 -0.0783 52 HFeO2,aq 0.32251E-11 -11.4915 0.32251E-11 -11.4915 0.10000E+01 0.0000 53 H2,aq 0.11623E-04 -4.9347 0.11583E-04 -4.9362 0.99652E+00 -0.0015 54 KCl,aq 0.46503E-09 -9.3325 0.46503E-09 -9.3325 0.10000E+01 0.0000 56 KOH,aq 0.75375E-06 -6.1228 0.75375E-06 -6.1228 0.10000E+01 0.0000 57 KSO4- 0.13945E-14 -14.8556 0.11645E-14 -14.9339 0.83505E+00 -0.0783 58 MgCO3,aq 0.13701E-13 -13.8632 0.13701E-13 -13.8632 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.11571E-15 -15.9366 0.96811E-16 -16.0141 0.83665E+00 -0.0775 60 MgCl+ 0.37314E-14 -14.4281 0.31219E-14 -14.5056 0.83665E+00 -0.0775 61 MgOH+ 0.69015E-10 -10.1611 0.57742E-10 -10.2385 0.83665E+00 -0.0775 63 MnO,aq 0.18055E-08 -8.7434 0.18055E-08 -8.7434 0.10000E+01 0.0000 64 MnOH+ 0.46861E-09 -9.3292 0.39206E-09 -9.4066 0.83665E+00 -0.0775 65 MnO2-2 0.20921E-10 -10.6794 0.10834E-10 -10.9652 0.51785E+00 -0.2858 66 HMnO2- 0.21138E-09 -9.6749 0.17652E-09 -9.7532 0.83505E+00 -0.0783 69 MnCl+ 0.13873E-13 -13.8578 0.11607E-13 -13.9353 0.83665E+00 -0.0775 71 NaCl,aq 0.10770E-05 -5.9678 0.10770E-05 -5.9678 0.10000E+01 0.0000 72 NaOH,aq 0.96047E-04 -4.0175 0.96047E-04 -4.0175 0.10000E+01 0.0000 74 OH- 0.93205E-02 -2.0306 0.77690E-02 -2.1096 0.83354E+00 -0.0791 79 HPO3-2 0.16328E-14 -14.7871 0.84552E-15 -15.0729 0.51785E+00 -0.2858 81 H2PO3- 0.15100E-18 -18.8210 0.12609E-18 -18.8993 0.83505E+00 -0.0783 82 H3PO4,aq 0.90610E-18 -18.0428 0.90610E-18 -18.0428 0.10000E+01 0.0000 83 H2PO4- 0.38447E-10 -10.4151 0.32136E-10 -10.4930 0.83584E+00 -0.0779 84 PO4-3 0.10606E-08 -8.9744 0.25699E-09 -9.5901 0.24230E+00 -0.6157 88 HP2O7-3 0.94160E-18 -18.0261 0.21742E-18 -18.6627 0.23090E+00 -0.6366 89 P2O7-4 0.90823E-17 -17.0418 0.69841E-18 -18.1559 0.76898E-01 -1.1141 90 H2S,aq 0.83720E-08 -8.0772 0.83429E-08 -8.0787 0.99652E+00 -0.0015 91 S2-2 0.48672E-14 -14.3127 0.25205E-14 -14.5985 0.51785E+00 -0.2858 97 SO3-2 0.16380E-17 -17.7857 0.86053E-18 -18.0652 0.52535E+00 -0.2795 99 HSO4- 0.48928E-19 -19.3104 0.40976E-19 -19.3875 0.83747E+00 -0.0770 Charge balance for all species = 0.8902E-10 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.8852240E-10 -.2225648E-01 -.2239415E+02 0.0000 2 H2O 0.1000000E+01 0.5550490E+02 0.9981971E+06 0.0000 3 Cl- 0.2340849E-03 0.2351624E-03 0.8322701E+01 6.4197 4 SO4-- 0.1101685E-11 -.2400103E-04 -.2301564E+01 8.0144 5 HCO3- 0.4076058E-06 0.2227643E-04 0.1356880E+01 3.6612 6 HS- 0.4346129E-04 0.6747069E-04 0.2227507E+01 5.6885 7 Al+++ 0.9775945E-29 0.5304190E-05 0.1428659E+00 0.7390 8 H4SiO4 0.6959761E-03 0.1351007E-01 0.1296266E+04 -3.1574 9 Ca++ 0.1357352E-06 0.2328351E-06 0.9315324E-02 13.1018 10 Mg++ 0.2123500E-10 0.9349038E-10 0.2268982E-05 9.2942 11 Fe++ 0.5852713E-13 0.3620961E-07 0.2018678E-02 6.7350 12 K+ 0.1569213E-03 0.1576755E-03 0.6154697E+01 6.2467 13 Na+ 0.1991259E-01 0.2235935E-01 0.5131423E+03 8.3494 14 Mn++ 0.1876812E-10 0.2525178E-08 0.1384868E-03 9.2414 15 HPO4-- 0.4513159E-07 0.4623068E-07 0.4429452E-02 12.6269 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.6788988E+02 -.1305829E-01 -.6787683E+02 0.0000000E+00 2 H2O 0.4113081E+01 0.3256577E+02 -.2845269E+02 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.1136505E+00 -.1408185E-04 0.1136645E+00 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.1136249E+00 0.3958632E-04 -.1136645E+00 0.0000000E+00 7 Al+++ 0.1336904E+02 0.3112068E-05 0.1336903E+02 0.0000000E+00 8 H4SiO4 0.4269240E+02 0.7926612E-02 0.4268447E+02 0.0000000E+00 9 Ca++ 0.4715598E+01 0.1366087E-06 0.4715598E+01 0.0000000E+00 10 Mg++ 0.3253967E+01 0.5485257E-10 0.3253967E+01 0.0000000E+00 11 Fe++ 0.2923335E+01 0.2124486E-07 0.2923334E+01 0.0000000E+00 12 K+ 0.8704881E+00 0.9251118E-04 0.8703956E+00 0.0000000E+00 13 Na+ 0.5146658E+01 0.1311865E-01 0.5133539E+01 0.0000000E+00 14 Mn++ 0.7108823E-01 0.1481570E-08 0.7108822E-01 0.0000000E+00 15 HPO4-- 0.2426206E-01 0.2712441E-07 0.2426203E-01 0.0000000E+00 Chg. balance for solid moles: 0.2368E-13 Mass of aqueous solution: 0.587742E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 4099.9990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 5.129 0.710 1345. 3.129 30.03 516.3 andradite 0.4547 -0.342 231.0 2.364 5.158 60.03 grossular 0.1101 -0.958 49.59 1.695 1.107 13.80 apatite-OH 0.8087E-02 -2.092 4.062 0.609 0.9070E-01 1.291 clinochlore 0.5827 -0.235 323.9 2.510 7.231 123.2 daphnite 0.1687 -0.773 120.4 2.080 2.687 36.47 chlorite-Mn 0.1422E-01 -1.847 10.08 1.003 0.2250 3.212 diopside 0.2137 -0.670 46.29 1.665 1.033 14.15 hedenbergite 0.5543E-01 -1.256 13.75 1.138 0.3070 3.767 microcline 0.7633 -0.117 212.4 2.327 4.743 82.99 stilbite 2.642 0.422 1862. 3.270 41.56 868.3 stilpnomelane-Fe 0.2143 -0.669 231.0 2.364 5.157 79.79 tr.625ac.25prg.125 0.3498E-01 -1.456 29.90 1.476 0.6675 9.623 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8051E+00 0.8051E+00 1.0000 -0.094 grossular 0.1949E+00 0.1949E+00 1.0000 -0.710 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.7611E+00 0.7611E+00 1.0000 -0.119 daphnite 0.2203E+00 0.2203E+00 1.0000 -0.657 chlorite-Mn 0.1857E-01 0.1857E-01 1.0000 -1.731 diopside 0.7941E+00 0.7941E+00 1.0000 -0.100 hedenbergite 0.2059E+00 0.2059E+00 1.0000 -0.686 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 tr.625ac.25prg.125 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 4479.081879 g Volume = 1812.950281 cm3 Porosity: -10.4784% V(tot) - V(min): -.17195E+03 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 4099.9990000 g log = 3.6128 Original solution: 1000.0103000 g Original solution / Rock added: 0.24 (Water/Rock Ratio), log = -0.6128 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0667 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9571E+00 0.9853 0.1006E+01 0.1021E+01 CO2,gas 0.5396E-08 1.0068 0.5795E-08 0.5756E-08 CH4,gas 0.2866E-01 1.0123 0.3094E-01 0.3057E-01 H2,gas 0.1425E-01 1.0006 0.1521E-01 0.1520E-01 H2S,gas 0.2159E-06 0.9959 0.2293E-06 0.2303E-06 S2,gas 0.8004E-29 1.0000 0.8538E-29 0.8538E-29 CO,gas 0.2202E-13 1.0000 0.2349E-13 0.2349E-13 SO3,gas 0.1121E-47 1.0000 0.1196E-47 0.1196E-47 SO2,gas 0.6631E-27 1.0000 0.7073E-27 0.7073E-27 HCl,gas 0.4407E-17 1.0000 0.4700E-17 0.4700E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 16 albite -0.38 -0.38 0.00 0.000 -0.94784E-12 22 andradite 39.01 39.01 0.00 0.000 0.24265E-10 23 grossular 32.73 32.73 0.00 0.000 -0.24265E-10 32 apatite-OH -18.15 -18.15 0.00 0.000 0.60662E-11 46 clinochlore 39.07 39.07 0.00 0.000 -0.12132E-10 47 daphnite 28.97 28.97 0.00 0.000 -0.12132E-10 48 chlorite-Mn 46.87 46.87 0.00 0.000 0.12132E-10 67 diopside 16.18 16.18 0.00 0.000 0.60662E-11 68 hedenbergite 14.21 14.21 0.00 0.000 -0.30331E-11 116 microcline -2.49 -2.49 0.00 0.000 -0.10616E-10 163 stilbite -7.52 -7.52 0.00 0.000 -0.90992E-11 164 stilpnomelane-Fe 13.02 13.02 0.00 0.000 0.21232E-10 245 tr.625ac.25prg.125 45.16 45.16 0.00 0.000 0.36397E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -16.60 -9.94 -3.312 0.16965E+05 -8.237 3 CH4,gas 4.54 1.34 -3.21 -0.802 0.54783E+04 -1.509 4 H2,gas 8.00 4.48 -3.52 -2.010 0.60051E+04 -1.818 5 H2S,gas -6.23 -14.57 -8.34 -4.169 0.14238E+05 -6.640 6 S2,gas -7.34 -38.10 -30.77 -4.733 0.52535E+05 -29.069 7 CO,gas 3.21 -12.11 -15.33 -4.716 0.26172E+05 -13.629 8 SO3,gas 17.12 -32.50 -49.62 -12.405 0.84727E+05 -47.922 9 SO2,gas 0.83 -28.02 -28.85 -7.693 0.49259E+05 -27.150 10 HCl,gas 5.19 -13.84 -19.03 -9.513 0.32488E+05 -17.328 11 acmite 7.71 6.53 -1.18 -0.123 0.20175E+04 15 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 19 spessartine 24.46 19.73 -4.73 -0.236 0.80719E+04 20 analcite 3.32 2.77 -0.55 -0.061 0.93625E+03 26 annite 20.12 17.72 -2.40 -0.134 0.41064E+04 27 phlogopite 27.06 25.40 -1.67 -0.093 0.28489E+04 29 anorthite 12.71 8.26 -4.45 -0.342 0.75903E+04 35 aragonite 0.97 -3.49 -4.46 -1.487 0.76165E+04 36 brucite 12.57 9.29 -3.27 -0.655 0.55909E+04 37 calcite 0.81 -3.49 -4.31 -1.435 0.73523E+04 38 carnegieite-low 9.02 5.93 -3.09 -0.442 0.52801E+04 39 carnegieite-high 10.09 5.93 -4.16 -0.595 0.71071E+04 40 carpholite-Mg 8.58 4.46 -4.12 -0.275 0.70429E+04 41 carpholite-Fe 6.71 1.90 -4.81 -0.321 0.82207E+04 42 celadonite 5.34 3.65 -1.69 -0.099 0.28879E+04 43 celadonite-Fe 3.88 1.09 -2.79 -0.164 0.47561E+04 44 chrysotile 23.89 21.57 -2.32 -0.194 0.39692E+04 49 chlorite-Al-free 47.17 43.14 -4.04 -0.168 0.68936E+04 51 chloritoid-Fe 9.17 5.06 -4.12 -0.275 0.70315E+04 52 chloritoid-Mn 11.40 7.56 -3.84 -0.256 0.65552E+04 54 coesite -2.38 -3.16 -0.78 -0.260 0.13341E+04 61 cristobalite -2.56 -3.16 -0.60 -0.199 0.10195E+04 63 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71234E+04 65 diaspore 2.87 0.74 -2.13 -0.356 0.36450E+04 66 diamond -3.10 -7.63 -4.53 -1.294 0.77314E+04 71 enstatite 17.26 12.27 -4.99 -0.499 0.85226E+04 73 clinoenstatite 17.17 12.27 -4.89 -0.489 0.83541E+04 75 epidote 24.67 22.70 -1.97 -0.095 0.33585E+04 76 clinozoisite 22.81 18.95 -3.86 -0.175 0.65868E+04 77 epidote-Fe 29.84 26.46 -3.38 -0.176 0.57768E+04 78 fayalite 14.05 10.31 -3.73 -0.533 0.63743E+04 79 ferrosilite 11.15 7.16 -3.99 -0.399 0.68202E+04 83 gibbsite 4.08 0.74 -3.34 -0.477 0.57035E+04 84 glaucophane 22.97 20.80 -2.17 -0.059 0.37133E+04 85 glaucophane-Fe 17.28 13.12 -4.15 -0.112 0.70919E+04 86 graphite -3.55 -7.63 -4.08 -1.167 0.69736E+04 87 greenalite 16.14 13.89 -2.25 -0.187 0.38408E+04 90 hematite 12.57 8.99 -3.58 -0.434 0.61111E+04 91 heulandite -5.83 -7.52 -1.69 -0.077 0.28938E+04 95 jadeite 4.22 2.77 -1.44 -0.144 0.24617E+04 97 kalsilite 7.58 3.83 -3.76 -0.537 0.64126E+04 98 kaolinite -1.33 -4.84 -3.50 -0.319 0.59831E+04 101 laumontite 2.88 1.95 -0.93 -0.062 0.15935E+04 102 lawsonite 9.62 8.26 -1.35 -0.090 0.23070E+04 103 leucite 4.12 0.67 -3.45 -0.345 0.58873E+04 105 lizardite 23.24 21.57 -1.68 -0.140 0.28618E+04 107 magnetite 20.09 15.72 -4.37 -0.356 0.74536E+04 108 minnesotaite 10.39 7.58 -2.81 -0.165 0.48028E+04 112 manganosite 14.06 9.24 -4.82 -1.204 0.82244E+04 120 muscovite 2.58 -1.01 -3.59 -0.211 0.61315E+04 121 paragonite 4.24 1.09 -3.15 -0.185 0.53706E+04 122 nepheline 8.34 5.93 -2.41 -0.344 0.41125E+04 128 periclase-Fe 11.63 6.73 -4.89 -1.223 0.83523E+04 134 phlogopite-Na 29.65 27.50 -2.15 -0.119 0.36677E+04 136 prehnite 19.37 18.21 -1.16 -0.068 0.19849E+04 137 prehnite-Fe 22.50 21.96 -0.53 -0.032 0.91158E+03 138 pumpellyite-Fe 46.27 43.89 -2.38 -0.053 0.40581E+04 139 pumpellyite-Mg 48.99 46.45 -2.54 -0.057 0.43419E+04 143 pyrrhotite -4.26 -7.83 -3.57 -1.191 0.61015E+04 144 pyrrhotiteFe0.875 -6.02 -9.23 -3.21 -1.182 0.54887E+04 145 pyroxmangite 7.40 6.08 -1.31 -0.263 0.22448E+04 146 pyrophyllite -6.18 -11.15 -4.98 -0.311 0.84962E+04 147 quartz -2.99 -3.16 -0.17 -0.056 0.28680E+03 152 rhodonite 7.45 6.08 -1.36 -0.272 0.23250E+04 153 sanidine -1.28 -2.49 -1.21 -0.093 0.20677E+04 165 stilpnomelane-Mg 27.44 25.81 -1.63 -0.049 0.27803E+04 171 talc 16.49 15.25 -1.24 -0.073 0.21140E+04 174 tephroite 18.09 15.33 -2.76 -0.394 0.47133E+04 178 tridymite -2.63 -3.16 -0.53 -0.177 0.90678E+03 179 tremolite 47.87 47.42 -0.45 -0.012 0.77495E+03 180 ferroactinolite 38.45 34.62 -3.83 -0.104 0.65448E+04 181 troilite-low -4.41 -7.83 -3.42 -1.141 0.58443E+04 183 vesuvianite 223.47 218.82 -4.65 -0.036 0.79437E+04 187 wairakite 3.95 1.95 -2.00 -0.118 0.34155E+04 188 walstromite 11.51 9.94 -1.56 -0.313 0.26719E+04 189 wollastonite 10.46 9.94 -0.52 -0.103 0.88229E+03 190 pseudo-wollastonite 11.00 9.94 -1.06 -0.211 0.18021E+04 191 zoisite 22.85 18.95 -3.90 -0.177 0.66609E+04 192 akaganeite 7.75 4.49 -3.26 -0.705 0.55681E+04 199 chalcedony -2.80 -3.16 -0.35 -0.118 0.60610E+03 201 montmorillonite-Ca -2.29 -6.17 -3.88 -0.240 0.66180E+04 202 montmorillonite-K -2.24 -6.27 -4.03 -0.247 0.68816E+04 203 montmorillonite-Mg -2.48 -6.79 -4.32 -0.267 0.73678E+04 204 montmorillonite-Na -2.04 -5.57 -3.54 -0.216 0.60365E+04 205 nontronite-Ca 3.21 -0.19 -3.41 -0.221 0.58215E+04 206 nontronite-H 2.53 -2.36 -4.89 -0.328 0.83485E+04 207 nontronite-K 3.34 -0.30 -3.64 -0.233 0.62083E+04 208 nontronite-Mg 3.07 -0.82 -3.90 -0.253 0.66553E+04 209 nontronite-Na 3.52 0.40 -3.12 -0.200 0.53292E+04 224 tobermorite 9.82 7.76 -2.07 -0.564 0.35287E+04 230 alabandite -0.98 -5.33 -4.35 -1.450 0.74266E+04 233 boehmite 4.41 0.74 -3.67 -0.611 0.62619E+04 235 ferrous-oxide 9.81 6.73 -3.08 -0.769 0.52532E+04 240 silica-amorphous -2.09 -3.16 -1.07 -0.355 0.18203E+04 242 an20ab80 2.02 1.35 -0.67 -0.052 0.11472E+04 243 an25ab75 2.65 1.78 -0.87 -0.067 0.14810E+04 244 an30ab70 3.28 2.21 -1.07 -0.082 0.18244E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 100.0000000 g Current total amount of reactant added: 4099.9990000 g New total amount of reactant added: 4199.9990000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.5220E-10 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 11 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 4199.9990000 Water: Moles liquid = 0.3201E+02 kg liquid = 0.5767E+00 Moles total = 0.2860E+01 kg total = 0.5152E-01 Activity = 1.0000 Stoichiometric ionic strength = .1140155E-01 Osmotic coef. = 0.9687 True ionic strength = .2007349E-01 Chg. balance for total moles = 0.5220E-10 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.88534E-10 -10.0529 0.74378E-10 -10.1286 0.84011E+00 -0.0757 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.23816E-03 -3.6231 0.19888E-03 -3.7014 0.83504E+00 -0.0783 4 SO4-- 0.11208E-11 -11.9505 0.58160E-12 -12.2354 0.51893E+00 -0.2849 5 HCO3- 0.41466E-06 -6.3823 0.34677E-06 -6.4600 0.83627E+00 -0.0777 6 HS- 0.44218E-04 -4.3544 0.36930E-04 -4.4326 0.83517E+00 -0.0782 7 Al+++ 0.97803E-29 -29.0096 0.22558E-29 -29.6467 0.23065E+00 -0.6370 8 H4SiO4 0.69598E-03 -3.1574 0.69598E-03 -3.1574 0.10000E+01 0.0000 9 Ca++ 0.13577E-06 -6.8672 0.69939E-07 -7.1553 0.51512E+00 -0.2881 10 Mg++ 0.21241E-10 -10.6728 0.10891E-10 -10.9629 0.51276E+00 -0.2901 11 Fe++ 0.58544E-13 -13.2325 0.30051E-13 -13.5221 0.51332E+00 -0.2896 12 K+ 0.15694E-03 -3.8043 0.13128E-03 -3.8818 0.83647E+00 -0.0776 13 Na+ 0.19915E-01 -1.7008 0.16627E-01 -1.7792 0.83489E+00 -0.0784 14 Mn++ 0.18774E-10 -10.7264 0.96452E-11 -11.0157 0.51374E+00 -0.2893 15 HPO4-- 0.45122E-07 -7.3456 0.23419E-07 -7.6304 0.51901E+00 -0.2848 16 HSiO3- 0.10463E-01 -1.9803 0.87373E-02 -2.0586 0.83504E+00 -0.0783 17 Ca(HSiO3)+ 0.16634E-07 -7.7790 0.13917E-07 -7.8565 0.83665E+00 -0.0775 18 Mg(HSiO3)+ 0.32237E-11 -11.4916 0.26971E-11 -11.5691 0.83665E+00 -0.0775 19 NaHSiO3,aq 0.23496E-02 -2.6290 0.23496E-02 -2.6290 0.10000E+01 0.0000 20 AlO+ 0.66306E-16 -16.1784 0.55475E-16 -16.2559 0.83665E+00 -0.0775 22 HAlO2,aq 0.14853E-09 -9.8282 0.14853E-09 -9.8282 0.10000E+01 0.0000 23 AlO2- 0.53034E-05 -5.2754 0.44206E-05 -5.3545 0.83353E+00 -0.0791 24 CH4,aq 0.21463E-04 -4.6683 0.21388E-04 -4.6698 0.99652E+00 -0.0015 25 C2H6,aq 0.67754E-14 -14.1691 0.67519E-14 -14.1706 0.99652E+00 -0.0015 29 CO,aq 0.16036E-16 -16.7949 0.16036E-16 -16.7949 0.10000E+01 0.0000 30 CO2,aq 0.55304E-10 -10.2572 0.55111E-10 -10.2588 0.99652E+00 -0.0015 31 CO3-2 0.78642E-06 -6.1043 0.40723E-06 -6.3902 0.51783E+00 -0.2858 32 CaCO3,aq 0.35712E-09 -9.4472 0.35712E-09 -9.4472 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.73995E-12 -12.1308 0.61907E-12 -12.2083 0.83665E+00 -0.0775 34 CaCl+ 0.26904E-10 -10.5702 0.22509E-10 -10.6476 0.83665E+00 -0.0775 35 CaCl2,aq 0.10635E-14 -14.9732 0.10635E-14 -14.9732 0.10000E+01 0.0000 36 CaOH+ 0.80101E-07 -7.0964 0.67016E-07 -7.1738 0.83665E+00 -0.0775 37 CaSO4,aq 0.12917E-16 -16.8888 0.12917E-16 -16.8888 0.10000E+01 0.0000 38 HCl,aq 0.27106E-14 -14.5669 0.27106E-14 -14.5669 0.10000E+01 0.0000 43 FeCl+ 0.11307E-16 -16.9467 0.94598E-17 -17.0241 0.83665E+00 -0.0775 46 FeO,aq 0.21113E-09 -9.6755 0.21113E-09 -9.6755 0.10000E+01 0.0000 47 FeOH+ 0.15720E-10 -10.8036 0.13152E-10 -10.8810 0.83665E+00 -0.0775 48 HFeO2- 0.35567E-07 -7.4490 0.29700E-07 -7.5272 0.83504E+00 -0.0783 49 FeO+ 0.11017E-16 -16.9579 0.92174E-17 -17.0354 0.83665E+00 -0.0775 51 FeO2- 0.40828E-09 -9.3890 0.34093E-09 -9.4673 0.83504E+00 -0.0783 52 HFeO2,aq 0.32251E-11 -11.4915 0.32251E-11 -11.4915 0.10000E+01 0.0000 53 H2,aq 0.11623E-04 -4.9347 0.11583E-04 -4.9362 0.99652E+00 -0.0015 54 KCl,aq 0.47318E-09 -9.3250 0.47318E-09 -9.3250 0.10000E+01 0.0000 56 KOH,aq 0.75375E-06 -6.1228 0.75375E-06 -6.1228 0.10000E+01 0.0000 57 KSO4- 0.14188E-14 -14.8481 0.11848E-14 -14.9264 0.83504E+00 -0.0783 58 MgCO3,aq 0.13940E-13 -13.8557 0.13940E-13 -13.8557 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.11774E-15 -15.9291 0.98510E-16 -16.0065 0.83665E+00 -0.0775 60 MgCl+ 0.37973E-14 -14.4205 0.31770E-14 -14.4980 0.83665E+00 -0.0775 61 MgOH+ 0.69024E-10 -10.1610 0.57749E-10 -10.2385 0.83665E+00 -0.0775 63 MnO,aq 0.18056E-08 -8.7434 0.18056E-08 -8.7434 0.10000E+01 0.0000 64 MnOH+ 0.46869E-09 -9.3291 0.39213E-09 -9.4066 0.83665E+00 -0.0775 65 MnO2-2 0.20918E-10 -10.6795 0.10832E-10 -10.9653 0.51783E+00 -0.2858 66 HMnO2- 0.21137E-09 -9.6750 0.17650E-09 -9.7532 0.83504E+00 -0.0783 69 MnCl+ 0.14118E-13 -13.8502 0.11812E-13 -13.9277 0.83665E+00 -0.0775 71 NaCl,aq 0.10959E-05 -5.9602 0.10959E-05 -5.9602 0.10000E+01 0.0000 72 NaOH,aq 0.96047E-04 -4.0175 0.96047E-04 -4.0175 0.10000E+01 0.0000 74 OH- 0.93194E-02 -2.0306 0.77681E-02 -2.1097 0.83353E+00 -0.0791 79 HPO3-2 0.16324E-14 -14.7872 0.84531E-15 -15.0730 0.51783E+00 -0.2858 81 H2PO3- 0.15098E-18 -18.8211 0.12608E-18 -18.8994 0.83504E+00 -0.0783 82 H3PO4,aq 0.90610E-18 -18.0428 0.90610E-18 -18.0428 0.10000E+01 0.0000 83 H2PO4- 0.38443E-10 -10.4152 0.32132E-10 -10.4931 0.83584E+00 -0.0779 84 PO4-3 0.10603E-08 -8.9746 0.25689E-09 -9.5902 0.24228E+00 -0.6157 88 HP2O7-3 0.94133E-18 -18.0263 0.21734E-18 -18.6629 0.23088E+00 -0.6366 89 P2O7-4 0.90792E-17 -17.0420 0.69807E-18 -18.1561 0.76888E-01 -1.1141 90 H2S,aq 0.85188E-08 -8.0696 0.84891E-08 -8.0711 0.99652E+00 -0.0015 91 S2-2 0.50383E-14 -14.2977 0.26090E-14 -14.5835 0.51783E+00 -0.2858 97 SO3-2 0.16664E-17 -17.7782 0.87541E-18 -18.0578 0.52534E+00 -0.2796 99 HSO4- 0.49780E-19 -19.3029 0.41689E-19 -19.3800 0.83746E+00 -0.0770 Charge balance for all species = 0.9053E-10 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.8853395E-10 -.2225425E-01 -.2239191E+02 0.0000 2 H2O 0.1000000E+01 0.5550490E+02 0.9981969E+06 0.0000 3 Cl- 0.2381613E-03 0.2392576E-03 0.8467637E+01 6.4271 4 SO4-- 0.1120768E-11 -.2436859E-04 -.2336811E+01 8.0217 5 HCO3- 0.4146628E-06 0.2266437E-04 0.1380509E+01 3.6686 6 HS- 0.4421816E-04 0.6859526E-04 0.2264634E+01 5.6959 7 Al+++ 0.9780284E-29 0.5303580E-05 0.1428495E+00 0.7390 8 H4SiO4 0.6959765E-03 0.1350889E-01 0.1296153E+04 -3.1574 9 Ca++ 0.1357731E-06 0.2328922E-06 0.9317606E-02 13.1018 10 Mg++ 0.2124093E-10 0.9350747E-10 0.2269397E-05 9.2942 11 Fe++ 0.5854351E-13 0.3620552E-07 0.2018450E-02 6.7350 12 K+ 0.1569418E-03 0.1576960E-03 0.6155498E+01 6.2467 13 Na+ 0.1991520E-01 0.2236198E-01 0.5132026E+03 8.3494 14 Mn++ 0.1877434E-10 0.2525347E-08 0.1384960E-03 9.2414 15 HPO4-- 0.4512216E-07 0.4622093E-07 0.4428517E-02 12.6267 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.6954574E+02 -.1283350E-01 -.6953290E+02 0.0000000E+00 2 H2O 0.2859539E+01 0.3200835E+02 -.2914881E+02 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.1164218E+00 -.1405278E-04 0.1164358E+00 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.1163963E+00 0.3955725E-04 -.1164358E+00 0.0000000E+00 7 Al+++ 0.1369511E+02 0.3058448E-05 0.1369511E+02 0.0000000E+00 8 H4SiO4 0.4373368E+02 0.7790256E-02 0.4372589E+02 0.0000000E+00 9 Ca++ 0.4830612E+01 0.1343034E-06 0.4830612E+01 0.0000000E+00 10 Mg++ 0.3333333E+01 0.5392353E-10 0.3333333E+01 0.0000000E+00 11 Fe++ 0.2994635E+01 0.2087886E-07 0.2994635E+01 0.0000000E+00 12 K+ 0.8917195E+00 0.9093955E-04 0.8916286E+00 0.0000000E+00 13 Na+ 0.5272182E+01 0.1289562E-01 0.5259286E+01 0.0000000E+00 14 Mn++ 0.7282209E-01 0.1456307E-08 0.7282208E-01 0.0000000E+00 15 HPO4-- 0.2485382E-01 0.2665451E-07 0.2485379E-01 0.0000000E+00 Chg. balance for solid moles: -.1629E-13 Mass of aqueous solution: 0.577682E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 4199.9990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 5.255 0.721 1378. 3.139 30.03 529.0 andradite 0.4657 -0.332 236.7 2.374 5.158 61.49 grossular 0.1128 -0.948 50.80 1.706 1.107 14.13 apatite-OH 0.8285E-02 -2.082 4.162 0.619 0.9070E-01 1.322 clinochlore 0.5969 -0.224 331.8 2.521 7.230 126.2 daphnite 0.1728 -0.762 123.3 2.091 2.687 37.36 chlorite-Mn 0.1456E-01 -1.837 10.33 1.014 0.2250 3.291 diopside 0.2192 -0.659 47.47 1.676 1.034 14.51 hedenbergite 0.5684E-01 -1.245 14.10 1.149 0.3074 3.863 microcline 0.7819 -0.107 217.6 2.338 4.743 85.01 stilbite 2.706 0.432 1907. 3.280 41.56 889.4 stilpnomelane-Fe 0.2195 -0.659 236.6 2.374 5.157 81.74 tr.625ac.25prg.125 0.3581E-01 -1.446 30.61 1.486 0.6671 9.852 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8051E+00 0.8051E+00 1.0000 -0.094 grossular 0.1949E+00 0.1949E+00 1.0000 -0.710 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.7611E+00 0.7611E+00 1.0000 -0.119 daphnite 0.2203E+00 0.2203E+00 1.0000 -0.657 chlorite-Mn 0.1857E-01 0.1857E-01 1.0000 -1.731 diopside 0.7941E+00 0.7941E+00 1.0000 -0.100 hedenbergite 0.2059E+00 0.2059E+00 1.0000 -0.686 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 tr.625ac.25prg.125 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 4588.332544 g Volume = 1857.153345 cm3 Porosity: -10.4791% V(tot) - V(min): -.17615E+03 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 4199.9990000 g log = 3.6232 Original solution: 1000.0103000 g Original solution / Rock added: 0.24 (Water/Rock Ratio), log = -0.6232 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0672 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9566E+00 0.9853 0.1006E+01 0.1021E+01 CO2,gas 0.5488E-08 1.0068 0.5896E-08 0.5857E-08 CH4,gas 0.2914E-01 1.0123 0.3148E-01 0.3110E-01 H2,gas 0.1424E-01 1.0006 0.1521E-01 0.1520E-01 H2S,gas 0.2196E-06 0.9959 0.2334E-06 0.2343E-06 S2,gas 0.8283E-29 1.0000 0.8840E-29 0.8840E-29 CO,gas 0.2239E-13 1.0000 0.2390E-13 0.2390E-13 SO3,gas 0.1140E-47 1.0000 0.1217E-47 0.1217E-47 SO2,gas 0.6744E-27 1.0000 0.7197E-27 0.7197E-27 HCl,gas 0.4481E-17 1.0000 0.4783E-17 0.4783E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 16 albite -0.38 -0.38 0.00 0.000 0.11184E-10 22 andradite 39.01 39.01 0.00 0.000 0.00000E+00 23 grossular 32.73 32.73 0.00 0.000 0.00000E+00 32 apatite-OH -18.15 -18.15 0.00 0.000 0.12132E-10 46 clinochlore 39.07 39.07 0.00 0.000 0.60662E-10 47 daphnite 28.97 28.97 0.00 0.000 0.36397E-10 48 chlorite-Mn 46.87 46.87 0.00 0.000 0.84926E-10 67 diopside 16.18 16.18 0.00 0.000 0.12132E-10 68 hedenbergite 14.21 14.21 0.00 0.000 0.18198E-10 116 microcline -2.49 -2.49 0.00 0.000 0.15165E-11 163 stilbite -7.52 -7.52 0.00 0.000 0.15165E-10 164 stilpnomelane-Fe 13.02 13.02 0.00 0.000 0.21232E-10 245 tr.625ac.25prg.125 45.16 45.16 0.00 0.000 0.48529E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -16.59 -9.93 -3.309 0.16952E+05 -8.229 3 CH4,gas 4.54 1.34 -3.20 -0.800 0.54655E+04 -1.502 4 H2,gas 8.00 4.48 -3.52 -2.010 0.60051E+04 -1.818 5 H2S,gas -6.23 -14.56 -8.33 -4.165 0.14225E+05 -6.632 6 S2,gas -7.34 -38.09 -30.75 -4.731 0.52509E+05 -29.054 7 CO,gas 3.21 -12.11 -15.32 -4.714 0.26160E+05 -13.622 8 SO3,gas 17.12 -32.49 -49.61 -12.403 0.84714E+05 -47.915 9 SO2,gas 0.83 -28.01 -28.84 -7.691 0.49247E+05 -27.143 10 HCl,gas 5.19 -13.83 -19.02 -9.510 0.32475E+05 -17.320 11 acmite 7.71 6.53 -1.18 -0.123 0.20175E+04 15 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 19 spessartine 24.46 19.73 -4.73 -0.236 0.80718E+04 20 analcite 3.32 2.77 -0.55 -0.061 0.93625E+03 26 annite 20.12 17.72 -2.40 -0.134 0.41064E+04 27 phlogopite 27.06 25.40 -1.67 -0.093 0.28489E+04 29 anorthite 12.71 8.26 -4.45 -0.342 0.75903E+04 35 aragonite 0.97 -3.49 -4.45 -1.484 0.76037E+04 36 brucite 12.57 9.29 -3.27 -0.655 0.55909E+04 37 calcite 0.81 -3.49 -4.30 -1.433 0.73395E+04 38 carnegieite-low 9.02 5.93 -3.09 -0.442 0.52801E+04 39 carnegieite-high 10.09 5.93 -4.16 -0.595 0.71071E+04 40 carpholite-Mg 8.58 4.46 -4.12 -0.275 0.70429E+04 41 carpholite-Fe 6.71 1.90 -4.81 -0.321 0.82207E+04 42 celadonite 5.34 3.65 -1.69 -0.099 0.28879E+04 43 celadonite-Fe 3.88 1.09 -2.79 -0.164 0.47561E+04 44 chrysotile 23.89 21.57 -2.32 -0.194 0.39692E+04 49 chlorite-Al-free 47.17 43.14 -4.04 -0.168 0.68936E+04 51 chloritoid-Fe 9.17 5.06 -4.12 -0.275 0.70315E+04 52 chloritoid-Mn 11.40 7.56 -3.84 -0.256 0.65552E+04 54 coesite -2.38 -3.16 -0.78 -0.260 0.13341E+04 61 cristobalite -2.56 -3.16 -0.60 -0.199 0.10195E+04 63 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71234E+04 65 diaspore 2.87 0.74 -2.13 -0.356 0.36450E+04 66 diamond -3.10 -7.62 -4.52 -1.292 0.77186E+04 71 enstatite 17.26 12.27 -4.99 -0.499 0.85226E+04 73 clinoenstatite 17.17 12.27 -4.89 -0.489 0.83541E+04 75 epidote 24.67 22.70 -1.97 -0.095 0.33585E+04 76 clinozoisite 22.81 18.95 -3.86 -0.175 0.65868E+04 77 epidote-Fe 29.84 26.46 -3.38 -0.176 0.57768E+04 78 fayalite 14.05 10.31 -3.73 -0.533 0.63743E+04 79 ferrosilite 11.15 7.16 -3.99 -0.399 0.68202E+04 83 gibbsite 4.08 0.74 -3.34 -0.477 0.57035E+04 84 glaucophane 22.97 20.80 -2.17 -0.059 0.37133E+04 85 glaucophane-Fe 17.28 13.12 -4.15 -0.112 0.70919E+04 86 graphite -3.55 -7.62 -4.08 -1.165 0.69608E+04 87 greenalite 16.14 13.89 -2.25 -0.187 0.38408E+04 90 hematite 12.57 8.99 -3.58 -0.434 0.61111E+04 91 heulandite -5.83 -7.52 -1.69 -0.077 0.28938E+04 95 jadeite 4.22 2.77 -1.44 -0.144 0.24617E+04 97 kalsilite 7.58 3.83 -3.76 -0.537 0.64126E+04 98 kaolinite -1.33 -4.84 -3.50 -0.319 0.59831E+04 101 laumontite 2.88 1.95 -0.93 -0.062 0.15935E+04 102 lawsonite 9.62 8.26 -1.35 -0.090 0.23070E+04 103 leucite 4.12 0.67 -3.45 -0.345 0.58873E+04 105 lizardite 23.24 21.57 -1.68 -0.140 0.28618E+04 107 magnetite 20.09 15.72 -4.37 -0.356 0.74536E+04 108 minnesotaite 10.39 7.58 -2.81 -0.165 0.48028E+04 112 manganosite 14.06 9.24 -4.82 -1.204 0.82244E+04 120 muscovite 2.58 -1.01 -3.59 -0.211 0.61315E+04 121 paragonite 4.24 1.09 -3.15 -0.185 0.53706E+04 122 nepheline 8.34 5.93 -2.41 -0.344 0.41125E+04 128 periclase-Fe 11.63 6.73 -4.89 -1.223 0.83523E+04 134 phlogopite-Na 29.65 27.50 -2.15 -0.119 0.36677E+04 136 prehnite 19.37 18.21 -1.16 -0.068 0.19849E+04 137 prehnite-Fe 22.50 21.96 -0.53 -0.032 0.91158E+03 138 pumpellyite-Fe 46.27 43.89 -2.38 -0.053 0.40581E+04 139 pumpellyite-Mg 48.99 46.45 -2.54 -0.057 0.43419E+04 143 pyrrhotite -4.26 -7.83 -3.57 -1.189 0.60886E+04 144 pyrrhotiteFe0.875 -6.02 -9.22 -3.21 -1.179 0.54759E+04 145 pyroxmangite 7.40 6.08 -1.31 -0.263 0.22447E+04 146 pyrophyllite -6.18 -11.15 -4.98 -0.311 0.84962E+04 147 quartz -2.99 -3.16 -0.17 -0.056 0.28680E+03 152 rhodonite 7.45 6.08 -1.36 -0.272 0.23250E+04 153 sanidine -1.28 -2.49 -1.21 -0.093 0.20677E+04 165 stilpnomelane-Mg 27.44 25.81 -1.63 -0.049 0.27804E+04 171 talc 16.49 15.25 -1.24 -0.073 0.21140E+04 174 tephroite 18.09 15.33 -2.76 -0.394 0.47132E+04 178 tridymite -2.63 -3.16 -0.53 -0.177 0.90678E+03 179 tremolite 47.87 47.42 -0.45 -0.012 0.77495E+03 180 ferroactinolite 38.45 34.62 -3.83 -0.104 0.65448E+04 181 troilite-low -4.41 -7.83 -3.42 -1.138 0.58315E+04 183 vesuvianite 223.47 218.82 -4.65 -0.036 0.79437E+04 187 wairakite 3.95 1.95 -2.00 -0.118 0.34155E+04 188 walstromite 11.51 9.94 -1.56 -0.313 0.26719E+04 189 wollastonite 10.46 9.94 -0.52 -0.103 0.88229E+03 190 pseudo-wollastonite 11.00 9.94 -1.06 -0.211 0.18021E+04 191 zoisite 22.85 18.95 -3.90 -0.177 0.66609E+04 192 akaganeite 7.75 4.49 -3.26 -0.705 0.55681E+04 199 chalcedony -2.80 -3.16 -0.35 -0.118 0.60610E+03 201 montmorillonite-Ca -2.29 -6.17 -3.88 -0.240 0.66180E+04 202 montmorillonite-K -2.24 -6.27 -4.03 -0.247 0.68816E+04 203 montmorillonite-Mg -2.48 -6.79 -4.32 -0.267 0.73678E+04 204 montmorillonite-Na -2.04 -5.57 -3.54 -0.216 0.60365E+04 205 nontronite-Ca 3.21 -0.19 -3.41 -0.221 0.58215E+04 206 nontronite-H 2.53 -2.36 -4.89 -0.328 0.83485E+04 207 nontronite-K 3.34 -0.30 -3.64 -0.233 0.62083E+04 208 nontronite-Mg 3.07 -0.82 -3.90 -0.253 0.66553E+04 209 nontronite-Na 3.52 0.40 -3.12 -0.200 0.53292E+04 224 tobermorite 9.82 7.76 -2.07 -0.564 0.35287E+04 230 alabandite -0.98 -5.32 -4.34 -1.447 0.74137E+04 233 boehmite 4.41 0.74 -3.67 -0.611 0.62619E+04 235 ferrous-oxide 9.81 6.73 -3.08 -0.769 0.52532E+04 240 silica-amorphous -2.09 -3.16 -1.07 -0.355 0.18203E+04 242 an20ab80 2.02 1.35 -0.67 -0.052 0.11472E+04 243 an25ab75 2.65 1.78 -0.87 -0.067 0.14810E+04 244 an30ab70 3.28 2.21 -1.07 -0.082 0.18244E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 100.0000000 g Current total amount of reactant added: 4199.9990000 g New total amount of reactant added: 4299.9990000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.5222E-10 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 11 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 4299.9990000 Water: Moles liquid = 0.3145E+02 kg liquid = 0.5666E+00 Moles total = 0.1606E+01 kg total = 0.2893E-01 Activity = 1.0000 Stoichiometric ionic strength = .1140506E-01 Osmotic coef. = 0.9687 True ionic strength = .2007622E-01 Chg. balance for total moles = 0.5222E-10 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.88546E-10 -10.0528 0.74387E-10 -10.1285 0.84010E+00 -0.0757 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.24238E-03 -3.6155 0.20240E-03 -3.6938 0.83504E+00 -0.0783 4 SO4-- 0.11405E-11 -11.9429 0.59184E-12 -12.2278 0.51892E+00 -0.2849 5 HCO3- 0.42197E-06 -6.3747 0.35288E-06 -6.4524 0.83626E+00 -0.0777 6 HS- 0.45002E-04 -4.3468 0.37584E-04 -4.4250 0.83516E+00 -0.0782 7 Al+++ 0.97848E-29 -29.0094 0.22567E-29 -29.6465 0.23063E+00 -0.6371 8 H4SiO4 0.69598E-03 -3.1574 0.69598E-03 -3.1574 0.10000E+01 0.0000 9 Ca++ 0.13581E-06 -6.8671 0.69957E-07 -7.1552 0.51510E+00 -0.2881 10 Mg++ 0.21247E-10 -10.6727 0.10894E-10 -10.9628 0.51274E+00 -0.2901 11 Fe++ 0.58560E-13 -13.2324 0.30059E-13 -13.5220 0.51330E+00 -0.2896 12 K+ 0.15696E-03 -3.8042 0.13129E-03 -3.8818 0.83646E+00 -0.0776 13 Na+ 0.19918E-01 -1.7008 0.16629E-01 -1.7791 0.83488E+00 -0.0784 14 Mn++ 0.18781E-10 -10.7263 0.96481E-11 -11.0156 0.51373E+00 -0.2893 15 HPO4-- 0.45112E-07 -7.3457 0.23413E-07 -7.6305 0.51899E+00 -0.2848 16 HSiO3- 0.10462E-01 -1.9804 0.87362E-02 -2.0587 0.83504E+00 -0.0783 17 Ca(HSiO3)+ 0.16636E-07 -7.7790 0.13918E-07 -7.8564 0.83664E+00 -0.0775 18 Mg(HSiO3)+ 0.32241E-11 -11.4916 0.26974E-11 -11.5690 0.83664E+00 -0.0775 19 NaHSiO3,aq 0.23496E-02 -2.6290 0.23496E-02 -2.6290 0.10000E+01 0.0000 20 AlO+ 0.66315E-16 -16.1784 0.55482E-16 -16.2558 0.83664E+00 -0.0775 22 HAlO2,aq 0.14853E-09 -9.8282 0.14853E-09 -9.8282 0.10000E+01 0.0000 23 AlO2- 0.53028E-05 -5.2755 0.44200E-05 -5.3546 0.83353E+00 -0.0791 24 CH4,aq 0.21843E-04 -4.6607 0.21768E-04 -4.6622 0.99652E+00 -0.0015 25 C2H6,aq 0.70179E-14 -14.1538 0.69935E-14 -14.1553 0.99652E+00 -0.0015 29 CO,aq 0.16320E-16 -16.7873 0.16320E-16 -16.7873 0.10000E+01 0.0000 30 CO2,aq 0.56285E-10 -10.2496 0.56089E-10 -10.2511 0.99652E+00 -0.0015 31 CO3-2 0.80019E-06 -6.0968 0.41435E-06 -6.3826 0.51781E+00 -0.2858 32 CaCO3,aq 0.36346E-09 -9.4395 0.36346E-09 -9.4395 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.75317E-12 -12.1231 0.63013E-12 -12.2006 0.83664E+00 -0.0775 34 CaCl+ 0.27388E-10 -10.5624 0.22914E-10 -10.6399 0.83664E+00 -0.0775 35 CaCl2,aq 0.11018E-14 -14.9579 0.11018E-14 -14.9579 0.10000E+01 0.0000 36 CaOH+ 0.80111E-07 -7.0963 0.67024E-07 -7.1738 0.83664E+00 -0.0775 37 CaSO4,aq 0.13147E-16 -16.8812 0.13147E-16 -16.8812 0.10000E+01 0.0000 38 HCl,aq 0.27589E-14 -14.5593 0.27589E-14 -14.5593 0.10000E+01 0.0000 43 FeCl+ 0.11510E-16 -16.9389 0.96298E-17 -17.0164 0.83664E+00 -0.0775 46 FeO,aq 0.21113E-09 -9.6755 0.21113E-09 -9.6755 0.10000E+01 0.0000 47 FeOH+ 0.15722E-10 -10.8035 0.13153E-10 -10.8810 0.83664E+00 -0.0775 48 HFeO2- 0.35563E-07 -7.4490 0.29696E-07 -7.5273 0.83504E+00 -0.0783 49 FeO+ 0.11019E-16 -16.9579 0.92185E-17 -17.0353 0.83664E+00 -0.0775 51 FeO2- 0.40823E-09 -9.3891 0.34089E-09 -9.4674 0.83504E+00 -0.0783 52 HFeO2,aq 0.32251E-11 -11.4915 0.32251E-11 -11.4915 0.10000E+01 0.0000 53 H2,aq 0.11623E-04 -4.9347 0.11583E-04 -4.9362 0.99652E+00 -0.0015 54 KCl,aq 0.48162E-09 -9.3173 0.48162E-09 -9.3173 0.10000E+01 0.0000 56 KOH,aq 0.75375E-06 -6.1228 0.75375E-06 -6.1228 0.10000E+01 0.0000 57 KSO4- 0.14440E-14 -14.8404 0.12058E-14 -14.9187 0.83504E+00 -0.0783 58 MgCO3,aq 0.14187E-13 -13.8481 0.14187E-13 -13.8481 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.11985E-15 -15.9214 0.10027E-15 -15.9988 0.83664E+00 -0.0775 60 MgCl+ 0.38656E-14 -14.4128 0.32341E-14 -14.4902 0.83664E+00 -0.0775 61 MgOH+ 0.69033E-10 -10.1609 0.57756E-10 -10.2384 0.83664E+00 -0.0775 63 MnO,aq 0.18057E-08 -8.7434 0.18057E-08 -8.7434 0.10000E+01 0.0000 64 MnOH+ 0.46878E-09 -9.3290 0.39220E-09 -9.4065 0.83664E+00 -0.0775 65 MnO2-2 0.20914E-10 -10.6796 0.10830E-10 -10.9654 0.51781E+00 -0.2858 66 HMnO2- 0.21136E-09 -9.6750 0.17649E-09 -9.7533 0.83504E+00 -0.0783 69 MnCl+ 0.14373E-13 -13.8425 0.12025E-13 -13.9199 0.83664E+00 -0.0775 71 NaCl,aq 0.11154E-05 -5.9526 0.11154E-05 -5.9526 0.10000E+01 0.0000 72 NaOH,aq 0.96047E-04 -4.0175 0.96047E-04 -4.0175 0.10000E+01 0.0000 74 OH- 0.93184E-02 -2.0307 0.77671E-02 -2.1097 0.83353E+00 -0.0791 79 HPO3-2 0.16321E-14 -14.7873 0.84510E-15 -15.0731 0.51781E+00 -0.2858 81 H2PO3- 0.15097E-18 -18.8211 0.12606E-18 -18.8994 0.83504E+00 -0.0783 82 H3PO4,aq 0.90610E-18 -18.0428 0.90610E-18 -18.0428 0.10000E+01 0.0000 83 H2PO4- 0.38439E-10 -10.4152 0.32128E-10 -10.4931 0.83583E+00 -0.0779 84 PO4-3 0.10600E-08 -8.9747 0.25680E-09 -9.5904 0.24226E+00 -0.6157 88 HP2O7-3 0.94106E-18 -18.0264 0.21726E-18 -18.6630 0.23086E+00 -0.6366 89 P2O7-4 0.90759E-17 -17.0421 0.69772E-18 -18.1563 0.76877E-01 -1.1142 90 H2S,aq 0.86708E-08 -8.0619 0.86406E-08 -8.0635 0.99652E+00 -0.0015 91 S2-2 0.52186E-14 -14.2824 0.27022E-14 -14.5683 0.51781E+00 -0.2858 97 SO3-2 0.16957E-17 -17.7706 0.89081E-18 -18.0502 0.52532E+00 -0.2796 99 HSO4- 0.50663E-19 -19.2953 0.42428E-19 -19.3723 0.83746E+00 -0.0770 Charge balance for all species = 0.9224E-10 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.8854591E-10 -.2225195E-01 -.2238959E+02 0.0000 2 H2O 0.1000000E+01 0.5550490E+02 0.9981968E+06 0.0000 3 Cl- 0.2423822E-03 0.2434981E-03 0.8617711E+01 6.4347 4 SO4-- 0.1140524E-11 -.2474919E-04 -.2373308E+01 8.0292 5 HCO3- 0.4219683E-06 0.2306605E-04 0.1404976E+01 3.6761 6 HS- 0.4500185E-04 0.6975971E-04 0.2303077E+01 5.7035 7 Al+++ 0.9784779E-29 0.5302949E-05 0.1428325E+00 0.7390 8 H4SiO4 0.6959769E-03 0.1350767E-01 0.1296035E+04 -3.1574 9 Ca++ 0.1358123E-06 0.2329513E-06 0.9319971E-02 13.1018 10 Mg++ 0.2124708E-10 0.9352282E-10 0.2269769E-05 9.2942 11 Fe++ 0.5856047E-13 0.3620129E-07 0.2018214E-02 6.7350 12 K+ 0.1569631E-03 0.1577173E-03 0.6156328E+01 6.2467 13 Na+ 0.1991791E-01 0.2236470E-01 0.5132650E+03 8.3494 14 Mn++ 0.1878070E-10 0.2525510E-08 0.1385050E-03 9.2414 15 HPO4-- 0.4511239E-07 0.4621084E-07 0.4427550E-02 12.6265 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.7120159E+02 -.1260870E-01 -.7118898E+02 0.0000000E+00 2 H2O 0.1605998E+01 0.3145094E+02 -.2984494E+02 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.1191931E+00 -.1402372E-04 0.1192072E+00 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.1191676E+00 0.3952819E-04 -.1192072E+00 0.0000000E+00 7 Al+++ 0.1402119E+02 0.3004829E-05 0.1402118E+02 0.0000000E+00 8 H4SiO4 0.4477496E+02 0.7653900E-02 0.4476730E+02 0.0000000E+00 9 Ca++ 0.4945627E+01 0.1319980E-06 0.4945627E+01 0.0000000E+00 10 Mg++ 0.3412698E+01 0.5299317E-10 0.3412698E+01 0.0000000E+00 11 Fe++ 0.3065936E+01 0.2051287E-07 0.3065936E+01 0.0000000E+00 12 K+ 0.9129510E+00 0.8936792E-04 0.9128616E+00 0.0000000E+00 13 Na+ 0.5397706E+01 0.1267259E-01 0.5385034E+01 0.0000000E+00 14 Mn++ 0.7455595E-01 0.1431039E-08 0.7455594E-01 0.0000000E+00 15 HPO4-- 0.2544557E-01 0.2618461E-07 0.2544555E-01 0.0000000E+00 Chg. balance for solid moles: 0.4982E-14 Mass of aqueous solution: 0.567622E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 4299.9990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 5.380 0.731 1411. 3.149 30.03 541.6 andradite 0.4768 -0.322 242.3 2.384 5.158 62.96 grossular 0.1155 -0.938 52.01 1.716 1.107 14.47 apatite-OH 0.8482E-02 -2.072 4.261 0.629 0.9070E-01 1.354 clinochlore 0.6110 -0.214 339.6 2.531 7.230 129.2 daphnite 0.1769 -0.752 126.2 2.101 2.687 38.25 chlorite-Mn 0.1491E-01 -1.826 10.57 1.024 0.2250 3.369 diopside 0.2246 -0.649 48.64 1.687 1.036 14.87 hedenbergite 0.5825E-01 -1.235 14.45 1.160 0.3077 3.958 microcline 0.8005 -0.097 222.8 2.348 4.743 87.03 stilbite 2.770 0.443 1952. 3.291 41.56 910.5 stilpnomelane-Fe 0.2248 -0.648 242.3 2.384 5.158 83.69 tr.625ac.25prg.125 0.3665E-01 -1.436 31.32 1.496 0.6668 10.08 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8051E+00 0.8051E+00 1.0000 -0.094 grossular 0.1949E+00 0.1949E+00 1.0000 -0.710 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.7611E+00 0.7611E+00 1.0000 -0.119 daphnite 0.2203E+00 0.2203E+00 1.0000 -0.657 chlorite-Mn 0.1857E-01 0.1857E-01 1.0000 -1.731 diopside 0.7941E+00 0.7941E+00 1.0000 -0.100 hedenbergite 0.2059E+00 0.2059E+00 1.0000 -0.686 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 tr.625ac.25prg.125 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 4697.583209 g Volume = 1901.356409 cm3 Porosity: -10.4798% V(tot) - V(min): -.18036E+03 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 4299.9990000 g log = 3.6335 Original solution: 1000.0103000 g Original solution / Rock added: 0.23 (Water/Rock Ratio), log = -0.6335 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0678 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9561E+00 0.9853 0.1006E+01 0.1021E+01 CO2,gas 0.5582E-08 1.0067 0.6001E-08 0.5961E-08 CH4,gas 0.2964E-01 1.0123 0.3204E-01 0.3165E-01 H2,gas 0.1423E-01 1.0006 0.1521E-01 0.1520E-01 H2S,gas 0.2234E-06 0.9959 0.2375E-06 0.2385E-06 S2,gas 0.8576E-29 1.0000 0.9158E-29 0.9158E-29 CO,gas 0.2278E-13 1.0000 0.2432E-13 0.2432E-13 SO3,gas 0.1160E-47 1.0000 0.1238E-47 0.1238E-47 SO2,gas 0.6861E-27 1.0000 0.7326E-27 0.7326E-27 HCl,gas 0.4559E-17 1.0000 0.4868E-17 0.4868E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 16 albite -0.38 -0.38 0.00 0.000 0.11184E-10 22 andradite 39.01 39.01 0.00 0.000 -0.12132E-10 23 grossular 32.73 32.73 0.00 0.000 0.12132E-10 32 apatite-OH -18.15 -18.15 0.00 0.000 -0.60662E-11 46 clinochlore 39.07 39.07 0.00 0.000 0.00000E+00 47 daphnite 28.97 28.97 0.00 0.000 0.60662E-11 48 chlorite-Mn 46.87 46.87 0.00 0.000 0.00000E+00 67 diopside 16.18 16.18 0.00 0.000 0.60662E-11 68 hedenbergite 14.21 14.21 0.00 0.000 -0.30331E-11 116 microcline -2.49 -2.49 0.00 0.000 0.15165E-11 163 stilbite -7.52 -7.52 0.00 0.000 -0.90992E-11 164 stilpnomelane-Fe 13.02 13.02 0.00 0.000 -0.75827E-10 245 tr.625ac.25prg.125 45.16 45.16 0.00 0.000 0.00000E+00 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -16.58 -9.92 -3.307 0.16939E+05 -8.222 3 CH4,gas 4.54 1.35 -3.19 -0.798 0.54524E+04 -1.494 4 H2,gas 8.00 4.48 -3.52 -2.010 0.60051E+04 -1.818 5 H2S,gas -6.23 -14.55 -8.32 -4.162 0.14212E+05 -6.624 6 S2,gas -7.34 -38.07 -30.74 -4.729 0.52483E+05 -29.038 7 CO,gas 3.21 -12.10 -15.31 -4.712 0.26147E+05 -13.614 8 SO3,gas 17.12 -32.48 -49.61 -12.402 0.84701E+05 -47.907 9 SO2,gas 0.83 -28.00 -28.83 -7.689 0.49233E+05 -27.135 10 HCl,gas 5.19 -13.82 -19.01 -9.506 0.32462E+05 -17.313 11 acmite 7.71 6.53 -1.18 -0.123 0.20175E+04 15 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 19 spessartine 24.46 19.73 -4.73 -0.236 0.80717E+04 20 analcite 3.32 2.77 -0.55 -0.061 0.93625E+03 26 annite 20.12 17.72 -2.40 -0.134 0.41064E+04 27 phlogopite 27.06 25.40 -1.67 -0.093 0.28489E+04 29 anorthite 12.71 8.26 -4.45 -0.342 0.75903E+04 35 aragonite 0.97 -3.48 -4.45 -1.482 0.75907E+04 36 brucite 12.57 9.29 -3.27 -0.655 0.55909E+04 37 calcite 0.81 -3.48 -4.29 -1.430 0.73265E+04 38 carnegieite-low 9.02 5.93 -3.09 -0.442 0.52801E+04 39 carnegieite-high 10.09 5.93 -4.16 -0.595 0.71071E+04 40 carpholite-Mg 8.58 4.46 -4.12 -0.275 0.70429E+04 41 carpholite-Fe 6.71 1.90 -4.81 -0.321 0.82207E+04 42 celadonite 5.34 3.65 -1.69 -0.099 0.28879E+04 43 celadonite-Fe 3.88 1.09 -2.79 -0.164 0.47561E+04 44 chrysotile 23.89 21.57 -2.32 -0.194 0.39692E+04 49 chlorite-Al-free 47.17 43.14 -4.04 -0.168 0.68936E+04 51 chloritoid-Fe 9.17 5.06 -4.12 -0.275 0.70315E+04 52 chloritoid-Mn 11.40 7.56 -3.84 -0.256 0.65551E+04 54 coesite -2.38 -3.16 -0.78 -0.260 0.13341E+04 61 cristobalite -2.56 -3.16 -0.60 -0.199 0.10195E+04 63 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71234E+04 65 diaspore 2.87 0.74 -2.13 -0.356 0.36450E+04 66 diamond -3.10 -7.62 -4.51 -1.289 0.77056E+04 71 enstatite 17.26 12.27 -4.99 -0.499 0.85226E+04 73 clinoenstatite 17.17 12.27 -4.89 -0.489 0.83541E+04 75 epidote 24.67 22.70 -1.97 -0.095 0.33585E+04 76 clinozoisite 22.81 18.95 -3.86 -0.175 0.65868E+04 77 epidote-Fe 29.84 26.46 -3.38 -0.176 0.57768E+04 78 fayalite 14.05 10.31 -3.73 -0.533 0.63743E+04 79 ferrosilite 11.15 7.16 -3.99 -0.399 0.68202E+04 83 gibbsite 4.08 0.74 -3.34 -0.477 0.57035E+04 84 glaucophane 22.97 20.80 -2.17 -0.059 0.37133E+04 85 glaucophane-Fe 17.28 13.12 -4.15 -0.112 0.70919E+04 86 graphite -3.55 -7.62 -4.07 -1.163 0.69478E+04 87 greenalite 16.14 13.89 -2.25 -0.187 0.38408E+04 90 hematite 12.57 8.99 -3.58 -0.434 0.61111E+04 91 heulandite -5.83 -7.52 -1.69 -0.077 0.28938E+04 95 jadeite 4.22 2.77 -1.44 -0.144 0.24617E+04 97 kalsilite 7.58 3.83 -3.76 -0.537 0.64126E+04 98 kaolinite -1.33 -4.84 -3.50 -0.319 0.59831E+04 101 laumontite 2.88 1.95 -0.93 -0.062 0.15935E+04 102 lawsonite 9.62 8.26 -1.35 -0.090 0.23070E+04 103 leucite 4.12 0.67 -3.45 -0.345 0.58873E+04 105 lizardite 23.24 21.57 -1.68 -0.140 0.28618E+04 107 magnetite 20.09 15.72 -4.37 -0.356 0.74536E+04 108 minnesotaite 10.39 7.58 -2.81 -0.165 0.48028E+04 112 manganosite 14.06 9.24 -4.82 -1.204 0.82243E+04 120 muscovite 2.58 -1.01 -3.59 -0.211 0.61315E+04 121 paragonite 4.24 1.09 -3.15 -0.185 0.53706E+04 122 nepheline 8.34 5.93 -2.41 -0.344 0.41125E+04 128 periclase-Fe 11.63 6.73 -4.89 -1.223 0.83523E+04 134 phlogopite-Na 29.65 27.50 -2.15 -0.119 0.36677E+04 136 prehnite 19.37 18.21 -1.16 -0.068 0.19849E+04 137 prehnite-Fe 22.50 21.96 -0.53 -0.032 0.91158E+03 138 pumpellyite-Fe 46.27 43.89 -2.38 -0.053 0.40581E+04 139 pumpellyite-Mg 48.99 46.45 -2.54 -0.057 0.43419E+04 143 pyrrhotite -4.26 -7.82 -3.56 -1.186 0.60755E+04 144 pyrrhotiteFe0.875 -6.02 -9.22 -3.20 -1.177 0.54627E+04 145 pyroxmangite 7.40 6.08 -1.31 -0.263 0.22447E+04 146 pyrophyllite -6.18 -11.15 -4.98 -0.311 0.84962E+04 147 quartz -2.99 -3.16 -0.17 -0.056 0.28680E+03 152 rhodonite 7.45 6.08 -1.36 -0.272 0.23250E+04 153 sanidine -1.28 -2.49 -1.21 -0.093 0.20677E+04 165 stilpnomelane-Mg 27.44 25.81 -1.63 -0.049 0.27804E+04 171 talc 16.49 15.25 -1.24 -0.073 0.21140E+04 174 tephroite 18.09 15.33 -2.76 -0.394 0.47132E+04 178 tridymite -2.63 -3.16 -0.53 -0.177 0.90678E+03 179 tremolite 47.87 47.42 -0.45 -0.012 0.77495E+03 180 ferroactinolite 38.45 34.62 -3.83 -0.104 0.65448E+04 181 troilite-low -4.41 -7.82 -3.41 -1.136 0.58183E+04 183 vesuvianite 223.47 218.82 -4.65 -0.036 0.79438E+04 187 wairakite 3.95 1.95 -2.00 -0.118 0.34155E+04 188 walstromite 11.51 9.94 -1.56 -0.313 0.26719E+04 189 wollastonite 10.46 9.94 -0.52 -0.103 0.88229E+03 190 pseudo-wollastonite 11.00 9.94 -1.06 -0.211 0.18021E+04 191 zoisite 22.85 18.95 -3.90 -0.177 0.66609E+04 192 akaganeite 7.75 4.49 -3.26 -0.705 0.55681E+04 199 chalcedony -2.80 -3.16 -0.35 -0.118 0.60610E+03 201 montmorillonite-Ca -2.29 -6.17 -3.88 -0.240 0.66180E+04 202 montmorillonite-K -2.24 -6.27 -4.03 -0.247 0.68816E+04 203 montmorillonite-Mg -2.48 -6.79 -4.32 -0.267 0.73678E+04 204 montmorillonite-Na -2.04 -5.57 -3.54 -0.216 0.60365E+04 205 nontronite-Ca 3.21 -0.19 -3.41 -0.221 0.58215E+04 206 nontronite-H 2.53 -2.36 -4.89 -0.328 0.83485E+04 207 nontronite-K 3.34 -0.30 -3.64 -0.233 0.62083E+04 208 nontronite-Mg 3.07 -0.82 -3.90 -0.253 0.66553E+04 209 nontronite-Na 3.52 0.40 -3.12 -0.200 0.53292E+04 224 tobermorite 9.82 7.76 -2.07 -0.564 0.35287E+04 230 alabandite -0.98 -5.31 -4.33 -1.445 0.74005E+04 233 boehmite 4.41 0.74 -3.67 -0.611 0.62619E+04 235 ferrous-oxide 9.81 6.73 -3.08 -0.769 0.52532E+04 240 silica-amorphous -2.09 -3.16 -1.07 -0.355 0.18203E+04 242 an20ab80 2.02 1.35 -0.67 -0.052 0.11472E+04 243 an25ab75 2.65 1.78 -0.87 -0.067 0.14810E+04 244 an30ab70 3.28 2.21 -1.07 -0.082 0.18244E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 100.0000000 g Current total amount of reactant added: 4299.9990000 g New total amount of reactant added: 4399.9990000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.5221E-10 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 11 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 4399.9990000 Water: Moles liquid = 0.3090E+02 kg liquid = 0.5566E+00 Moles total = 0.3525E+00 kg total = 0.6350E-02 Activity = 1.0000 Stoichiometric ionic strength = .1140870E-01 Osmotic coef. = 0.9687 True ionic strength = .2007906E-01 Chg. balance for total moles = 0.5221E-10 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.88558E-10 -10.0528 0.74397E-10 -10.1284 0.84009E+00 -0.0757 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.24676E-03 -3.6077 0.20605E-03 -3.6860 0.83503E+00 -0.0783 4 SO4-- 0.11610E-11 -11.9352 0.60243E-12 -12.2201 0.51890E+00 -0.2849 5 HCO3- 0.42954E-06 -6.3670 0.35920E-06 -6.4447 0.83625E+00 -0.0777 6 HS- 0.45814E-04 -4.3390 0.38261E-04 -4.4172 0.83515E+00 -0.0782 7 Al+++ 0.97894E-29 -29.0092 0.22576E-29 -29.6464 0.23061E+00 -0.6371 8 H4SiO4 0.69598E-03 -3.1574 0.69598E-03 -3.1574 0.10000E+01 0.0000 9 Ca++ 0.13585E-06 -6.8669 0.69975E-07 -7.1551 0.51508E+00 -0.2881 10 Mg++ 0.21253E-10 -10.6726 0.10897E-10 -10.9627 0.51272E+00 -0.2901 11 Fe++ 0.58578E-13 -13.2323 0.30067E-13 -13.5219 0.51328E+00 -0.2896 12 K+ 0.15699E-03 -3.8041 0.13131E-03 -3.8817 0.83645E+00 -0.0776 13 Na+ 0.19921E-01 -1.7007 0.16631E-01 -1.7791 0.83488E+00 -0.0784 14 Mn++ 0.18787E-10 -10.7261 0.96511E-11 -11.0154 0.51371E+00 -0.2893 15 HPO4-- 0.45102E-07 -7.3458 0.23407E-07 -7.6307 0.51897E+00 -0.2849 16 HSiO3- 0.10461E-01 -1.9804 0.87351E-02 -2.0587 0.83503E+00 -0.0783 17 Ca(HSiO3)+ 0.16638E-07 -7.7789 0.13920E-07 -7.8564 0.83663E+00 -0.0775 18 Mg(HSiO3)+ 0.32246E-11 -11.4915 0.26978E-11 -11.5690 0.83663E+00 -0.0775 19 NaHSiO3,aq 0.23496E-02 -2.6290 0.23496E-02 -2.6290 0.10000E+01 0.0000 20 AlO+ 0.66324E-16 -16.1783 0.55489E-16 -16.2558 0.83663E+00 -0.0775 22 HAlO2,aq 0.14853E-09 -9.8282 0.14853E-09 -9.8282 0.10000E+01 0.0000 23 AlO2- 0.53021E-05 -5.2755 0.44194E-05 -5.3546 0.83352E+00 -0.0791 24 CH4,aq 0.22238E-04 -4.6529 0.22160E-04 -4.6544 0.99652E+00 -0.0015 25 C2H6,aq 0.72736E-14 -14.1383 0.72483E-14 -14.1398 0.99652E+00 -0.0015 29 CO,aq 0.16615E-16 -16.7795 0.16615E-16 -16.7795 0.10000E+01 0.0000 30 CO2,aq 0.57301E-10 -10.2418 0.57102E-10 -10.2434 0.99652E+00 -0.0015 31 CO3-2 0.81446E-06 -6.0891 0.42172E-06 -6.3750 0.51779E+00 -0.2858 32 CaCO3,aq 0.37002E-09 -9.4318 0.37002E-09 -9.4318 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.76688E-12 -12.1153 0.64160E-12 -12.1927 0.83663E+00 -0.0775 34 CaCl+ 0.27889E-10 -10.5546 0.23333E-10 -10.6320 0.83663E+00 -0.0775 35 CaCl2,aq 0.11422E-14 -14.9423 0.11422E-14 -14.9423 0.10000E+01 0.0000 36 CaOH+ 0.80123E-07 -7.0962 0.67033E-07 -7.1737 0.83663E+00 -0.0775 37 CaSO4,aq 0.13386E-16 -16.8733 0.13386E-16 -16.8733 0.10000E+01 0.0000 38 HCl,aq 0.28090E-14 -14.5514 0.28090E-14 -14.5514 0.10000E+01 0.0000 43 FeCl+ 0.11721E-16 -16.9310 0.98060E-17 -17.0085 0.83663E+00 -0.0775 46 FeO,aq 0.21113E-09 -9.6755 0.21113E-09 -9.6755 0.10000E+01 0.0000 47 FeOH+ 0.15724E-10 -10.8034 0.13155E-10 -10.8809 0.83663E+00 -0.0775 48 HFeO2- 0.35559E-07 -7.4491 0.29692E-07 -7.5274 0.83503E+00 -0.0783 49 FeO+ 0.11020E-16 -16.9578 0.92198E-17 -17.0353 0.83663E+00 -0.0775 51 FeO2- 0.40818E-09 -9.3891 0.34084E-09 -9.4674 0.83503E+00 -0.0783 52 HFeO2,aq 0.32251E-11 -11.4915 0.32251E-11 -11.4915 0.10000E+01 0.0000 53 H2,aq 0.11623E-04 -4.9347 0.11583E-04 -4.9362 0.99652E+00 -0.0015 54 KCl,aq 0.49037E-09 -9.3095 0.49037E-09 -9.3095 0.10000E+01 0.0000 56 KOH,aq 0.75375E-06 -6.1228 0.75375E-06 -6.1228 0.10000E+01 0.0000 57 KSO4- 0.14700E-14 -14.8327 0.12275E-14 -14.9110 0.83503E+00 -0.0783 58 MgCO3,aq 0.14443E-13 -13.8403 0.14443E-13 -13.8403 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.12203E-15 -15.9135 0.10209E-15 -15.9910 0.83663E+00 -0.0775 60 MgCl+ 0.39364E-14 -14.4049 0.32933E-14 -14.4824 0.83663E+00 -0.0775 61 MgOH+ 0.69043E-10 -10.1609 0.57764E-10 -10.2383 0.83663E+00 -0.0775 63 MnO,aq 0.18057E-08 -8.7433 0.18057E-08 -8.7433 0.10000E+01 0.0000 64 MnOH+ 0.46887E-09 -9.3289 0.39227E-09 -9.4064 0.83663E+00 -0.0775 65 MnO2-2 0.20910E-10 -10.6796 0.10827E-10 -10.9655 0.51779E+00 -0.2858 66 HMnO2- 0.21134E-09 -9.6750 0.17647E-09 -9.7533 0.83503E+00 -0.0783 69 MnCl+ 0.14637E-13 -13.8346 0.12246E-13 -13.9120 0.83663E+00 -0.0775 71 NaCl,aq 0.11357E-05 -5.9447 0.11357E-05 -5.9447 0.10000E+01 0.0000 72 NaOH,aq 0.96047E-04 -4.0175 0.96047E-04 -4.0175 0.10000E+01 0.0000 74 OH- 0.93172E-02 -2.0307 0.77661E-02 -2.1098 0.83352E+00 -0.0791 79 HPO3-2 0.16317E-14 -14.7874 0.84488E-15 -15.0732 0.51779E+00 -0.2858 81 H2PO3- 0.15095E-18 -18.8212 0.12605E-18 -18.8995 0.83503E+00 -0.0783 82 H3PO4,aq 0.90610E-18 -18.0428 0.90610E-18 -18.0428 0.10000E+01 0.0000 83 H2PO4- 0.38434E-10 -10.4153 0.32124E-10 -10.4932 0.83582E+00 -0.0779 84 PO4-3 0.10597E-08 -8.9748 0.25669E-09 -9.5906 0.24224E+00 -0.6158 88 HP2O7-3 0.94077E-18 -18.0265 0.21717E-18 -18.6632 0.23085E+00 -0.6367 89 P2O7-4 0.90725E-17 -17.0423 0.69736E-18 -18.1565 0.76865E-01 -1.1143 90 H2S,aq 0.88283E-08 -8.0541 0.87976E-08 -8.0556 0.99652E+00 -0.0015 91 S2-2 0.54087E-14 -14.2669 0.28006E-14 -14.5528 0.51779E+00 -0.2858 97 SO3-2 0.17262E-17 -17.7629 0.90676E-18 -18.0425 0.52530E+00 -0.2796 99 HSO4- 0.51577E-19 -19.2875 0.43193E-19 -19.3646 0.83745E+00 -0.0770 Charge balance for all species = 0.9383E-10 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.8855830E-10 -.2224957E-01 -.2238719E+02 0.0000 2 H2O 0.1000000E+01 0.5550490E+02 0.9981967E+06 0.0000 3 Cl- 0.2467554E-03 0.2478915E-03 0.8773200E+01 6.4424 4 SO4-- 0.1160989E-11 -.2514353E-04 -.2411123E+01 8.0368 5 HCO3- 0.4295356E-06 0.2348224E-04 0.1430326E+01 3.6838 6 HS- 0.4581382E-04 0.7096618E-04 0.2342908E+01 5.7112 7 Al+++ 0.9789440E-29 0.5302297E-05 0.1428149E+00 0.7390 8 H4SiO4 0.6959773E-03 0.1350641E-01 0.1295914E+04 -3.1574 9 Ca++ 0.1358530E-06 0.2330126E-06 0.9322422E-02 13.1018 10 Mg++ 0.2125345E-10 0.9353871E-10 0.2270154E-05 9.2942 11 Fe++ 0.5857805E-13 0.3619691E-07 0.2017970E-02 6.7350 12 K+ 0.1569851E-03 0.1577394E-03 0.6157187E+01 6.2467 13 Na+ 0.1992071E-01 0.2236752E-01 0.5133297E+03 8.3494 14 Mn++ 0.1878722E-10 0.2525670E-08 0.1385137E-03 9.2415 15 HPO4-- 0.4510227E-07 0.4620038E-07 0.4426547E-02 12.6262 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.7285744E+02 -.1238391E-01 -.7284505E+02 0.0000000E+00 2 H2O 0.3524574E+00 0.3089352E+02 -.3054106E+02 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.1219645E+00 -.1399466E-04 0.1219785E+00 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.1219390E+00 0.3949913E-04 -.1219785E+00 0.0000000E+00 7 Al+++ 0.1434726E+02 0.2951210E-05 0.1434726E+02 0.0000000E+00 8 H4SiO4 0.4581623E+02 0.7517543E-02 0.4580872E+02 0.0000000E+00 9 Ca++ 0.5060641E+01 0.1296927E-06 0.5060641E+01 0.0000000E+00 10 Mg++ 0.3492063E+01 0.5206280E-10 0.3492063E+01 0.0000000E+00 11 Fe++ 0.3137237E+01 0.2014687E-07 0.3137237E+01 0.0000000E+00 12 K+ 0.9341824E+00 0.8779630E-04 0.9340946E+00 0.0000000E+00 13 Na+ 0.5523231E+01 0.1244956E-01 0.5510781E+01 0.0000000E+00 14 Mn++ 0.7628981E-01 0.1405765E-08 0.7628980E-01 0.0000000E+00 15 HPO4-- 0.2603733E-01 0.2571471E-07 0.2603731E-01 0.0000000E+00 Chg. balance for solid moles: -.2623E-14 Mass of aqueous solution: 0.557562E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 4399.9990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 5.506 0.741 1444. 3.160 30.04 554.2 andradite 0.4879 -0.312 247.9 2.394 5.158 64.42 grossular 0.1181 -0.928 53.22 1.726 1.107 14.81 apatite-OH 0.8679E-02 -2.062 4.360 0.639 0.9070E-01 1.385 clinochlore 0.6252 -0.204 347.5 2.541 7.230 132.2 daphnite 0.1810 -0.742 129.1 2.111 2.687 39.13 chlorite-Mn 0.1526E-01 -1.817 10.82 1.034 0.2250 3.447 diopside 0.2301 -0.638 49.82 1.697 1.036 15.23 hedenbergite 0.5966E-01 -1.224 14.80 1.170 0.3079 4.054 microcline 0.8191 -0.087 228.0 2.358 4.743 89.06 stilbite 2.834 0.452 1997. 3.300 41.55 931.6 stilpnomelane-Fe 0.2300 -0.638 247.9 2.394 5.158 85.64 tr.625ac.25prg.125 0.3748E-01 -1.426 32.04 1.506 0.6665 10.31 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8051E+00 0.8051E+00 1.0000 -0.094 grossular 0.1949E+00 0.1949E+00 1.0000 -0.710 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.7611E+00 0.7611E+00 1.0000 -0.119 daphnite 0.2203E+00 0.2203E+00 1.0000 -0.657 chlorite-Mn 0.1857E-01 0.1857E-01 1.0000 -1.731 diopside 0.7941E+00 0.7941E+00 1.0000 -0.100 hedenbergite 0.2059E+00 0.2059E+00 1.0000 -0.686 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 tr.625ac.25prg.125 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 4806.833873 g Volume = 1945.559473 cm3 Porosity: -10.4804% V(tot) - V(min): -.18456E+03 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 4399.9990000 g log = 3.6435 Original solution: 1000.0103000 g Original solution / Rock added: 0.23 (Water/Rock Ratio), log = -0.6434 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0684 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9556E+00 0.9853 0.1006E+01 0.1021E+01 CO2,gas 0.5680E-08 1.0067 0.6109E-08 0.6068E-08 CH4,gas 0.3016E-01 1.0123 0.3262E-01 0.3222E-01 H2,gas 0.1423E-01 1.0006 0.1521E-01 0.1520E-01 H2S,gas 0.2273E-06 0.9958 0.2418E-06 0.2428E-06 S2,gas 0.8886E-29 1.0000 0.9494E-29 0.9494E-29 CO,gas 0.2317E-13 1.0000 0.2476E-13 0.2476E-13 SO3,gas 0.1180E-47 1.0000 0.1261E-47 0.1261E-47 SO2,gas 0.6981E-27 1.0000 0.7459E-27 0.7459E-27 HCl,gas 0.4639E-17 1.0000 0.4957E-17 0.4957E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 16 albite -0.38 -0.38 0.00 0.000 -0.94784E-12 22 andradite 39.01 39.01 0.00 0.000 0.12132E-10 23 grossular 32.73 32.73 0.00 0.000 0.00000E+00 32 apatite-OH -18.15 -18.15 0.00 0.000 -0.60662E-11 46 clinochlore 39.07 39.07 0.00 0.000 -0.24265E-10 47 daphnite 28.97 28.97 0.00 0.000 0.60662E-11 48 chlorite-Mn 46.87 46.87 0.00 0.000 0.00000E+00 67 diopside 16.18 16.18 0.00 0.000 -0.60662E-11 68 hedenbergite 14.21 14.21 0.00 0.000 0.30331E-11 116 microcline -2.49 -2.49 0.00 0.000 -0.10616E-10 163 stilbite -7.52 -7.52 0.00 0.000 -0.90992E-11 164 stilpnomelane-Fe 13.02 13.02 0.00 0.000 -0.75827E-10 245 tr.625ac.25prg.125 45.16 45.16 0.00 0.000 -0.12132E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -16.57 -9.91 -3.304 0.16926E+05 -8.214 3 CH4,gas 4.54 1.36 -3.19 -0.796 0.54392E+04 -1.487 4 H2,gas 8.00 4.48 -3.52 -2.010 0.60051E+04 -1.818 5 H2S,gas -6.23 -14.55 -8.32 -4.158 0.14198E+05 -6.616 6 S2,gas -7.34 -38.06 -30.72 -4.726 0.52456E+05 -29.023 7 CO,gas 3.21 -12.09 -15.31 -4.709 0.26133E+05 -13.606 8 SO3,gas 17.12 -32.48 -49.60 -12.400 0.84688E+05 -47.899 9 SO2,gas 0.83 -27.99 -28.83 -7.687 0.49220E+05 -27.127 10 HCl,gas 5.19 -13.81 -19.00 -9.502 0.32448E+05 -17.305 11 acmite 7.71 6.53 -1.18 -0.123 0.20175E+04 15 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 19 spessartine 24.46 19.73 -4.73 -0.236 0.80716E+04 20 analcite 3.32 2.77 -0.55 -0.061 0.93625E+03 26 annite 20.12 17.72 -2.40 -0.134 0.41064E+04 27 phlogopite 27.06 25.40 -1.67 -0.093 0.28489E+04 29 anorthite 12.71 8.26 -4.45 -0.342 0.75903E+04 35 aragonite 0.97 -3.47 -4.44 -1.479 0.75774E+04 36 brucite 12.57 9.29 -3.27 -0.655 0.55909E+04 37 calcite 0.81 -3.47 -4.28 -1.428 0.73132E+04 38 carnegieite-low 9.02 5.93 -3.09 -0.442 0.52801E+04 39 carnegieite-high 10.09 5.93 -4.16 -0.595 0.71071E+04 40 carpholite-Mg 8.58 4.46 -4.12 -0.275 0.70429E+04 41 carpholite-Fe 6.71 1.90 -4.81 -0.321 0.82207E+04 42 celadonite 5.34 3.65 -1.69 -0.099 0.28879E+04 43 celadonite-Fe 3.88 1.09 -2.79 -0.164 0.47561E+04 44 chrysotile 23.89 21.57 -2.32 -0.194 0.39692E+04 49 chlorite-Al-free 47.17 43.14 -4.04 -0.168 0.68936E+04 51 chloritoid-Fe 9.17 5.06 -4.12 -0.275 0.70315E+04 52 chloritoid-Mn 11.40 7.56 -3.84 -0.256 0.65551E+04 54 coesite -2.38 -3.16 -0.78 -0.260 0.13341E+04 61 cristobalite -2.56 -3.16 -0.60 -0.199 0.10195E+04 63 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71234E+04 65 diaspore 2.87 0.74 -2.13 -0.356 0.36450E+04 66 diamond -3.10 -7.61 -4.51 -1.287 0.76923E+04 71 enstatite 17.26 12.27 -4.99 -0.499 0.85226E+04 73 clinoenstatite 17.17 12.27 -4.89 -0.489 0.83541E+04 75 epidote 24.67 22.70 -1.97 -0.095 0.33585E+04 76 clinozoisite 22.81 18.95 -3.86 -0.175 0.65868E+04 77 epidote-Fe 29.84 26.46 -3.38 -0.176 0.57768E+04 78 fayalite 14.05 10.31 -3.73 -0.533 0.63743E+04 79 ferrosilite 11.15 7.16 -3.99 -0.399 0.68202E+04 83 gibbsite 4.08 0.74 -3.34 -0.477 0.57035E+04 84 glaucophane 22.97 20.80 -2.17 -0.059 0.37133E+04 85 glaucophane-Fe 17.28 13.12 -4.15 -0.112 0.70919E+04 86 graphite -3.55 -7.61 -4.06 -1.160 0.69345E+04 87 greenalite 16.14 13.89 -2.25 -0.187 0.38408E+04 90 hematite 12.57 8.99 -3.58 -0.434 0.61111E+04 91 heulandite -5.83 -7.52 -1.69 -0.077 0.28938E+04 95 jadeite 4.22 2.77 -1.44 -0.144 0.24617E+04 97 kalsilite 7.58 3.83 -3.76 -0.537 0.64126E+04 98 kaolinite -1.33 -4.84 -3.50 -0.319 0.59831E+04 101 laumontite 2.88 1.95 -0.93 -0.062 0.15935E+04 102 lawsonite 9.62 8.26 -1.35 -0.090 0.23070E+04 103 leucite 4.12 0.67 -3.45 -0.345 0.58873E+04 105 lizardite 23.24 21.57 -1.68 -0.140 0.28618E+04 107 magnetite 20.09 15.72 -4.37 -0.356 0.74536E+04 108 minnesotaite 10.39 7.58 -2.81 -0.165 0.48028E+04 112 manganosite 14.06 9.24 -4.82 -1.204 0.82243E+04 120 muscovite 2.58 -1.01 -3.59 -0.211 0.61315E+04 121 paragonite 4.24 1.09 -3.15 -0.185 0.53706E+04 122 nepheline 8.34 5.93 -2.41 -0.344 0.41125E+04 128 periclase-Fe 11.63 6.73 -4.89 -1.223 0.83523E+04 134 phlogopite-Na 29.65 27.50 -2.15 -0.119 0.36677E+04 136 prehnite 19.37 18.21 -1.16 -0.068 0.19849E+04 137 prehnite-Fe 22.50 21.96 -0.53 -0.032 0.91158E+03 138 pumpellyite-Fe 46.27 43.89 -2.38 -0.053 0.40581E+04 139 pumpellyite-Mg 48.99 46.45 -2.54 -0.057 0.43420E+04 143 pyrrhotite -4.26 -7.81 -3.55 -1.183 0.60622E+04 144 pyrrhotiteFe0.875 -6.02 -9.21 -3.19 -1.174 0.54494E+04 145 pyroxmangite 7.40 6.08 -1.31 -0.263 0.22447E+04 146 pyrophyllite -6.18 -11.15 -4.98 -0.311 0.84962E+04 147 quartz -2.99 -3.16 -0.17 -0.056 0.28680E+03 152 rhodonite 7.45 6.08 -1.36 -0.272 0.23249E+04 153 sanidine -1.28 -2.49 -1.21 -0.093 0.20677E+04 165 stilpnomelane-Mg 27.44 25.81 -1.63 -0.049 0.27804E+04 171 talc 16.49 15.25 -1.24 -0.073 0.21140E+04 174 tephroite 18.09 15.33 -2.76 -0.394 0.47131E+04 178 tridymite -2.63 -3.16 -0.53 -0.177 0.90678E+03 179 tremolite 47.87 47.42 -0.45 -0.012 0.77495E+03 180 ferroactinolite 38.45 34.62 -3.83 -0.104 0.65448E+04 181 troilite-low -4.41 -7.81 -3.40 -1.133 0.58050E+04 183 vesuvianite 223.47 218.82 -4.65 -0.036 0.79438E+04 187 wairakite 3.95 1.95 -2.00 -0.118 0.34155E+04 188 walstromite 11.51 9.94 -1.56 -0.313 0.26719E+04 189 wollastonite 10.46 9.94 -0.52 -0.103 0.88229E+03 190 pseudo-wollastonite 11.00 9.94 -1.06 -0.211 0.18021E+04 191 zoisite 22.85 18.95 -3.90 -0.177 0.66609E+04 192 akaganeite 7.75 4.49 -3.26 -0.705 0.55681E+04 199 chalcedony -2.80 -3.16 -0.35 -0.118 0.60610E+03 201 montmorillonite-Ca -2.29 -6.17 -3.88 -0.240 0.66180E+04 202 montmorillonite-K -2.24 -6.27 -4.03 -0.247 0.68816E+04 203 montmorillonite-Mg -2.48 -6.79 -4.32 -0.267 0.73678E+04 204 montmorillonite-Na -2.04 -5.57 -3.54 -0.216 0.60365E+04 205 nontronite-Ca 3.21 -0.19 -3.41 -0.221 0.58215E+04 206 nontronite-H 2.53 -2.36 -4.89 -0.328 0.83485E+04 207 nontronite-K 3.34 -0.30 -3.64 -0.233 0.62083E+04 208 nontronite-Mg 3.07 -0.82 -3.90 -0.253 0.66553E+04 209 nontronite-Na 3.52 0.40 -3.12 -0.200 0.53292E+04 224 tobermorite 9.82 7.76 -2.07 -0.564 0.35287E+04 230 alabandite -0.98 -5.30 -4.33 -1.442 0.73871E+04 233 boehmite 4.41 0.74 -3.67 -0.611 0.62619E+04 235 ferrous-oxide 9.81 6.73 -3.08 -0.769 0.52532E+04 240 silica-amorphous -2.09 -3.16 -1.07 -0.355 0.18203E+04 242 an20ab80 2.02 1.35 -0.67 -0.052 0.11472E+04 243 an25ab75 2.65 1.78 -0.87 -0.067 0.14810E+04 244 an30ab70 3.28 2.21 -1.07 -0.082 0.18244E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 100.0000000 g Current total amount of reactant added: 4399.9990000 g New total amount of reactant added: 4499.9990000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.5222E-10 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 12 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 4499.9990000 Water: Moles liquid = 0.3034E+02 kg liquid = 0.5465E+00 Moles total = -.9011E+00 kg total = -.1623E-01 Activity = 1.0000 Stoichiometric ionic strength = .1141247E-01 Osmotic coef. = 0.9686 True ionic strength = .2008200E-01 Chg. balance for total moles = 0.5222E-10 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.88571E-10 -10.0527 0.74407E-10 -10.1284 0.84008E+00 -0.0757 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.25129E-03 -3.5998 0.20983E-03 -3.6781 0.83502E+00 -0.0783 4 SO4-- 0.11822E-11 -11.9273 0.61342E-12 -12.2122 0.51888E+00 -0.2849 5 HCO3- 0.43738E-06 -6.3591 0.36576E-06 -6.4368 0.83624E+00 -0.0777 6 HS- 0.46656E-04 -4.3311 0.38964E-04 -4.4093 0.83514E+00 -0.0782 7 Al+++ 0.97943E-29 -29.0090 0.22585E-29 -29.6462 0.23059E+00 -0.6372 8 H4SiO4 0.69598E-03 -3.1574 0.69598E-03 -3.1574 0.10000E+01 0.0000 9 Ca++ 0.13590E-06 -6.8668 0.69994E-07 -7.1549 0.51506E+00 -0.2881 10 Mg++ 0.21260E-10 -10.6724 0.10900E-10 -10.9626 0.51270E+00 -0.2901 11 Fe++ 0.58596E-13 -13.2321 0.30075E-13 -13.5218 0.51326E+00 -0.2897 12 K+ 0.15701E-03 -3.8041 0.13133E-03 -3.8816 0.83644E+00 -0.0776 13 Na+ 0.19924E-01 -1.7006 0.16634E-01 -1.7790 0.83487E+00 -0.0784 14 Mn++ 0.18794E-10 -10.7260 0.96542E-11 -11.0153 0.51369E+00 -0.2893 15 HPO4-- 0.45092E-07 -7.3459 0.23400E-07 -7.6308 0.51895E+00 -0.2849 16 HSiO3- 0.10459E-01 -1.9805 0.87339E-02 -2.0588 0.83502E+00 -0.0783 17 Ca(HSiO3)+ 0.16641E-07 -7.7788 0.13922E-07 -7.8563 0.83662E+00 -0.0775 18 Mg(HSiO3)+ 0.32250E-11 -11.4915 0.26982E-11 -11.5689 0.83662E+00 -0.0775 19 NaHSiO3,aq 0.23496E-02 -2.6290 0.23496E-02 -2.6290 0.10000E+01 0.0000 20 AlO+ 0.66334E-16 -16.1783 0.55496E-16 -16.2557 0.83662E+00 -0.0775 22 HAlO2,aq 0.14853E-09 -9.8282 0.14853E-09 -9.8282 0.10000E+01 0.0000 23 AlO2- 0.53015E-05 -5.2756 0.44188E-05 -5.3547 0.83351E+00 -0.0791 24 CH4,aq 0.22647E-04 -4.6450 0.22568E-04 -4.6465 0.99652E+00 -0.0015 25 C2H6,aq 0.75435E-14 -14.1224 0.75172E-14 -14.1239 0.99652E+00 -0.0015 29 CO,aq 0.16920E-16 -16.7716 0.16920E-16 -16.7716 0.10000E+01 0.0000 30 CO2,aq 0.58355E-10 -10.2339 0.58152E-10 -10.2354 0.99652E+00 -0.0015 31 CO3-2 0.82924E-06 -6.0813 0.42936E-06 -6.3672 0.51777E+00 -0.2859 32 CaCO3,aq 0.37682E-09 -9.4239 0.37682E-09 -9.4239 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.78110E-12 -12.1073 0.65348E-12 -12.1848 0.83662E+00 -0.0775 34 CaCl+ 0.28410E-10 -10.5465 0.23768E-10 -10.6240 0.83662E+00 -0.0775 35 CaCl2,aq 0.11849E-14 -14.9263 0.11849E-14 -14.9263 0.10000E+01 0.0000 36 CaOH+ 0.80134E-07 -7.0962 0.67042E-07 -7.1737 0.83662E+00 -0.0775 37 CaSO4,aq 0.13634E-16 -16.8654 0.13634E-16 -16.8654 0.10000E+01 0.0000 38 HCl,aq 0.28610E-14 -14.5435 0.28610E-14 -14.5435 0.10000E+01 0.0000 43 FeCl+ 0.11939E-16 -16.9230 0.99888E-17 -17.0005 0.83662E+00 -0.0775 46 FeO,aq 0.21113E-09 -9.6755 0.21113E-09 -9.6755 0.10000E+01 0.0000 47 FeOH+ 0.15726E-10 -10.8034 0.13157E-10 -10.8808 0.83662E+00 -0.0775 48 HFeO2- 0.35554E-07 -7.4491 0.29688E-07 -7.5274 0.83502E+00 -0.0783 49 FeO+ 0.11022E-16 -16.9578 0.92210E-17 -17.0352 0.83662E+00 -0.0775 51 FeO2- 0.40813E-09 -9.3892 0.34080E-09 -9.4675 0.83502E+00 -0.0783 52 HFeO2,aq 0.32251E-11 -11.4915 0.32251E-11 -11.4915 0.10000E+01 0.0000 53 H2,aq 0.11623E-04 -4.9347 0.11583E-04 -4.9362 0.99652E+00 -0.0015 54 KCl,aq 0.49945E-09 -9.3015 0.49945E-09 -9.3015 0.10000E+01 0.0000 56 KOH,aq 0.75375E-06 -6.1228 0.75375E-06 -6.1228 0.10000E+01 0.0000 57 KSO4- 0.14971E-14 -14.8248 0.12501E-14 -14.9031 0.83502E+00 -0.0783 58 MgCO3,aq 0.14709E-13 -13.8324 0.14709E-13 -13.8324 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.12429E-15 -15.9056 0.10399E-15 -15.9830 0.83662E+00 -0.0775 60 MgCl+ 0.40098E-14 -14.3969 0.33547E-14 -14.4743 0.83662E+00 -0.0775 61 MgOH+ 0.69053E-10 -10.1608 0.57771E-10 -10.2383 0.83662E+00 -0.0775 63 MnO,aq 0.18058E-08 -8.7433 0.18058E-08 -8.7433 0.10000E+01 0.0000 64 MnOH+ 0.46896E-09 -9.3289 0.39234E-09 -9.4063 0.83662E+00 -0.0775 65 MnO2-2 0.20906E-10 -10.6797 0.10825E-10 -10.9656 0.51777E+00 -0.2859 66 HMnO2- 0.21132E-09 -9.6751 0.17646E-09 -9.7534 0.83502E+00 -0.0783 69 MnCl+ 0.14910E-13 -13.8265 0.12474E-13 -13.9040 0.83662E+00 -0.0775 71 NaCl,aq 0.11567E-05 -5.9368 0.11567E-05 -5.9368 0.10000E+01 0.0000 72 NaOH,aq 0.96047E-04 -4.0175 0.96047E-04 -4.0175 0.10000E+01 0.0000 74 OH- 0.93160E-02 -2.0308 0.77650E-02 -2.1099 0.83351E+00 -0.0791 79 HPO3-2 0.16313E-14 -14.7875 0.84465E-15 -15.0733 0.51777E+00 -0.2859 81 H2PO3- 0.15093E-18 -18.8212 0.12603E-18 -18.8995 0.83502E+00 -0.0783 82 H3PO4,aq 0.90610E-18 -18.0428 0.90610E-18 -18.0428 0.10000E+01 0.0000 83 H2PO4- 0.38429E-10 -10.4153 0.32120E-10 -10.4932 0.83581E+00 -0.0779 84 PO4-3 0.10593E-08 -8.9750 0.25659E-09 -9.5908 0.24222E+00 -0.6158 88 HP2O7-3 0.94047E-18 -18.0267 0.21708E-18 -18.6634 0.23082E+00 -0.6367 89 P2O7-4 0.90689E-17 -17.0424 0.69698E-18 -18.1568 0.76854E-01 -1.1143 90 H2S,aq 0.89917E-08 -8.0462 0.89604E-08 -8.0477 0.99652E+00 -0.0015 91 S2-2 0.56094E-14 -14.2511 0.29044E-14 -14.5369 0.51777E+00 -0.2859 97 SO3-2 0.17577E-17 -17.7551 0.92329E-18 -18.0347 0.52528E+00 -0.2796 99 HSO4- 0.52525E-19 -19.2796 0.43987E-19 -19.3567 0.83744E+00 -0.0770 Charge balance for all species = 0.9551E-10 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.8857115E-10 -.2224710E-01 -.2238470E+02 0.0000 2 H2O 0.1000000E+01 0.5550490E+02 0.9981966E+06 0.0000 3 Cl- 0.2512893E-03 0.2524465E-03 0.8934403E+01 6.4503 4 SO4-- 0.1182200E-11 -.2555237E-04 -.2450328E+01 8.0445 5 HCO3- 0.4373791E-06 0.2391372E-04 0.1456608E+01 3.6916 6 HS- 0.4665563E-04 0.7221700E-04 0.2384202E+01 5.7190 7 Al+++ 0.9794275E-29 0.5301621E-05 0.1427966E+00 0.7390 8 H4SiO4 0.6959777E-03 0.1350510E-01 0.1295788E+04 -3.1574 9 Ca++ 0.1358952E-06 0.2330761E-06 0.9324963E-02 13.1018 10 Mg++ 0.2126006E-10 0.9355601E-10 0.2270574E-05 9.2942 11 Fe++ 0.5859628E-13 0.3619237E-07 0.2017716E-02 6.7350 12 K+ 0.1570080E-03 0.1577622E-03 0.6158079E+01 6.2467 13 Na+ 0.1992361E-01 0.2237045E-01 0.5133968E+03 8.3494 14 Mn++ 0.1879391E-10 0.2525826E-08 0.1385222E-03 9.2415 15 HPO4-- 0.4509178E-07 0.4618954E-07 0.4425508E-02 12.6260 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.7451329E+02 -.1215911E-01 -.7450113E+02 0.0000000E+00 2 H2O -.9010836E+00 0.3033611E+02 -.3123719E+02 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.1247358E+00 -.1396561E-04 0.1247498E+00 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.1247103E+00 0.3947008E-04 -.1247498E+00 0.0000000E+00 7 Al+++ 0.1467333E+02 0.2897592E-05 0.1467333E+02 0.0000000E+00 8 H4SiO4 0.4685751E+02 0.7381187E-02 0.4685013E+02 0.0000000E+00 9 Ca++ 0.5175655E+01 0.1273874E-06 0.5175655E+01 0.0000000E+00 10 Mg++ 0.3571428E+01 0.5113288E-10 0.3571428E+01 0.0000000E+00 11 Fe++ 0.3208538E+01 0.1978088E-07 0.3208538E+01 0.0000000E+00 12 K+ 0.9554138E+00 0.8622467E-04 0.9553276E+00 0.0000000E+00 13 Na+ 0.5648755E+01 0.1222653E-01 0.5636529E+01 0.0000000E+00 14 Mn++ 0.7802366E-01 0.1380486E-08 0.7802366E-01 0.0000000E+00 15 HPO4-- 0.2662909E-01 0.2524481E-07 0.2662906E-01 0.0000000E+00 Chg. balance for solid moles: 0.2630E-13 Mass of aqueous solution: 0.547501E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 4499.9990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 5.632 0.751 1477. 3.169 30.04 566.9 andradite 0.4990 -0.302 253.6 2.404 5.158 65.88 grossular 0.1208 -0.918 54.43 1.736 1.107 15.14 apatite-OH 0.8876E-02 -2.052 4.459 0.649 0.9070E-01 1.417 clinochlore 0.6394 -0.194 355.4 2.551 7.229 135.2 daphnite 0.1851 -0.733 132.1 2.121 2.687 40.02 chlorite-Mn 0.1560E-01 -1.807 11.06 1.044 0.2250 3.526 diopside 0.2355 -0.628 51.00 1.708 1.037 15.59 hedenbergite 0.6107E-01 -1.214 15.15 1.180 0.3082 4.150 microcline 0.8377 -0.077 233.2 2.368 4.743 91.08 stilbite 2.899 0.462 2043. 3.310 41.55 952.8 stilpnomelane-Fe 0.2352 -0.629 253.6 2.404 5.158 87.58 tr.625ac.25prg.125 0.3831E-01 -1.417 32.75 1.515 0.6661 10.54 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8051E+00 0.8051E+00 1.0000 -0.094 grossular 0.1949E+00 0.1949E+00 1.0000 -0.710 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.7611E+00 0.7611E+00 1.0000 -0.119 daphnite 0.2203E+00 0.2203E+00 1.0000 -0.657 chlorite-Mn 0.1857E-01 0.1857E-01 1.0000 -1.731 diopside 0.7941E+00 0.7941E+00 1.0000 -0.100 hedenbergite 0.2059E+00 0.2059E+00 1.0000 -0.686 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 tr.625ac.25prg.125 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 4916.084538 g Volume = 1989.762537 cm3 Porosity: -10.4810% V(tot) - V(min): -.18876E+03 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 4499.9990000 g log = 3.6532 Original solution: 1000.0103000 g Original solution / Rock added: 0.22 (Water/Rock Ratio), log = -0.6532 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0690 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9551E+00 0.9853 0.1006E+01 0.1021E+01 CO2,gas 0.5781E-08 1.0067 0.6222E-08 0.6180E-08 CH4,gas 0.3070E-01 1.0123 0.3322E-01 0.3282E-01 H2,gas 0.1422E-01 1.0006 0.1521E-01 0.1520E-01 H2S,gas 0.2314E-06 0.9958 0.2463E-06 0.2473E-06 S2,gas 0.9213E-29 1.0000 0.9848E-29 0.9848E-29 CO,gas 0.2359E-13 1.0000 0.2521E-13 0.2521E-13 SO3,gas 0.1201E-47 1.0000 0.1284E-47 0.1284E-47 SO2,gas 0.7107E-27 1.0000 0.7597E-27 0.7597E-27 HCl,gas 0.4723E-17 1.0000 0.5048E-17 0.5048E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 16 albite -0.38 -0.38 0.00 0.000 -0.94784E-12 22 andradite 39.01 39.01 0.00 0.000 -0.24265E-10 23 grossular 32.73 32.73 0.00 0.000 0.12132E-10 32 apatite-OH -18.15 -18.15 0.00 0.000 -0.12132E-10 46 clinochlore 39.07 39.07 0.00 0.000 -0.36397E-10 47 daphnite 28.97 28.97 0.00 0.000 -0.66728E-10 48 chlorite-Mn 46.87 46.87 0.00 0.000 -0.24265E-10 67 diopside 16.18 16.18 0.00 0.000 -0.12132E-10 68 hedenbergite 14.21 14.21 0.00 0.000 -0.12132E-10 116 microcline -2.49 -2.49 0.00 0.000 -0.10616E-10 163 stilbite -7.52 -7.52 0.00 0.000 -0.90992E-11 164 stilpnomelane-Fe 13.02 13.02 0.00 0.000 -0.27298E-10 245 tr.625ac.25prg.125 45.16 45.16 0.00 0.000 0.24265E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -16.57 -9.91 -3.302 0.16913E+05 -8.206 3 CH4,gas 4.54 1.37 -3.18 -0.794 0.54257E+04 -1.479 4 H2,gas 8.00 4.48 -3.52 -2.010 0.60051E+04 -1.818 5 H2S,gas -6.23 -14.54 -8.31 -4.154 0.14185E+05 -6.609 6 S2,gas -7.34 -38.04 -30.71 -4.724 0.52429E+05 -29.007 7 CO,gas 3.21 -12.08 -15.30 -4.707 0.26120E+05 -13.598 8 SO3,gas 17.12 -32.47 -49.59 -12.398 0.84674E+05 -47.891 9 SO2,gas 0.83 -27.99 -28.82 -7.685 0.49207E+05 -27.119 10 HCl,gas 5.19 -13.81 -19.00 -9.498 0.32435E+05 -17.297 11 acmite 7.71 6.53 -1.18 -0.123 0.20175E+04 15 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 19 spessartine 24.46 19.73 -4.73 -0.236 0.80715E+04 20 analcite 3.32 2.77 -0.55 -0.061 0.93625E+03 26 annite 20.12 17.72 -2.40 -0.134 0.41064E+04 27 phlogopite 27.06 25.40 -1.67 -0.093 0.28489E+04 29 anorthite 12.71 8.26 -4.45 -0.342 0.75903E+04 35 aragonite 0.97 -3.46 -4.43 -1.477 0.75639E+04 36 brucite 12.57 9.29 -3.27 -0.655 0.55909E+04 37 calcite 0.81 -3.46 -4.28 -1.425 0.72997E+04 38 carnegieite-low 9.02 5.93 -3.09 -0.442 0.52801E+04 39 carnegieite-high 10.09 5.93 -4.16 -0.595 0.71071E+04 40 carpholite-Mg 8.58 4.46 -4.12 -0.275 0.70429E+04 41 carpholite-Fe 6.71 1.90 -4.81 -0.321 0.82207E+04 42 celadonite 5.34 3.65 -1.69 -0.099 0.28879E+04 43 celadonite-Fe 3.88 1.09 -2.79 -0.164 0.47561E+04 44 chrysotile 23.89 21.57 -2.32 -0.194 0.39692E+04 49 chlorite-Al-free 47.17 43.14 -4.04 -0.168 0.68936E+04 51 chloritoid-Fe 9.17 5.06 -4.12 -0.275 0.70315E+04 52 chloritoid-Mn 11.40 7.56 -3.84 -0.256 0.65551E+04 54 coesite -2.38 -3.16 -0.78 -0.260 0.13341E+04 61 cristobalite -2.56 -3.16 -0.60 -0.199 0.10195E+04 63 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71234E+04 65 diaspore 2.87 0.74 -2.13 -0.356 0.36450E+04 66 diamond -3.10 -7.60 -4.50 -1.285 0.76788E+04 71 enstatite 17.26 12.27 -4.99 -0.499 0.85226E+04 73 clinoenstatite 17.17 12.27 -4.89 -0.489 0.83541E+04 75 epidote 24.67 22.70 -1.97 -0.095 0.33585E+04 76 clinozoisite 22.81 18.95 -3.86 -0.175 0.65868E+04 77 epidote-Fe 29.84 26.46 -3.38 -0.176 0.57768E+04 78 fayalite 14.05 10.31 -3.73 -0.533 0.63743E+04 79 ferrosilite 11.15 7.16 -3.99 -0.399 0.68202E+04 83 gibbsite 4.08 0.74 -3.34 -0.477 0.57035E+04 84 glaucophane 22.97 20.80 -2.17 -0.059 0.37133E+04 85 glaucophane-Fe 17.28 13.12 -4.15 -0.112 0.70919E+04 86 graphite -3.55 -7.60 -4.05 -1.158 0.69210E+04 87 greenalite 16.14 13.89 -2.25 -0.187 0.38408E+04 90 hematite 12.57 8.99 -3.58 -0.434 0.61111E+04 91 heulandite -5.83 -7.52 -1.69 -0.077 0.28938E+04 95 jadeite 4.22 2.77 -1.44 -0.144 0.24617E+04 97 kalsilite 7.58 3.83 -3.76 -0.537 0.64126E+04 98 kaolinite -1.33 -4.84 -3.50 -0.319 0.59831E+04 101 laumontite 2.88 1.95 -0.93 -0.062 0.15935E+04 102 lawsonite 9.62 8.26 -1.35 -0.090 0.23070E+04 103 leucite 4.12 0.67 -3.45 -0.345 0.58873E+04 105 lizardite 23.24 21.57 -1.68 -0.140 0.28618E+04 107 magnetite 20.09 15.72 -4.37 -0.356 0.74536E+04 108 minnesotaite 10.39 7.58 -2.81 -0.165 0.48028E+04 112 manganosite 14.06 9.24 -4.82 -1.204 0.82243E+04 120 muscovite 2.58 -1.01 -3.59 -0.211 0.61315E+04 121 paragonite 4.24 1.09 -3.15 -0.185 0.53706E+04 122 nepheline 8.34 5.93 -2.41 -0.344 0.41125E+04 128 periclase-Fe 11.63 6.73 -4.89 -1.223 0.83523E+04 134 phlogopite-Na 29.65 27.50 -2.15 -0.119 0.36677E+04 136 prehnite 19.37 18.21 -1.16 -0.068 0.19849E+04 137 prehnite-Fe 22.50 21.96 -0.53 -0.032 0.91158E+03 138 pumpellyite-Fe 46.27 43.89 -2.38 -0.053 0.40581E+04 139 pumpellyite-Mg 48.99 46.45 -2.54 -0.057 0.43420E+04 143 pyrrhotite -4.26 -7.80 -3.54 -1.181 0.60486E+04 144 pyrrhotiteFe0.875 -6.02 -9.20 -3.18 -1.171 0.54358E+04 145 pyroxmangite 7.40 6.08 -1.31 -0.263 0.22446E+04 146 pyrophyllite -6.18 -11.15 -4.98 -0.311 0.84962E+04 147 quartz -2.99 -3.16 -0.17 -0.056 0.28680E+03 152 rhodonite 7.45 6.08 -1.36 -0.272 0.23249E+04 153 sanidine -1.28 -2.49 -1.21 -0.093 0.20677E+04 165 stilpnomelane-Mg 27.44 25.81 -1.63 -0.049 0.27804E+04 171 talc 16.49 15.25 -1.24 -0.073 0.21140E+04 174 tephroite 18.09 15.33 -2.76 -0.394 0.47130E+04 178 tridymite -2.63 -3.16 -0.53 -0.177 0.90678E+03 179 tremolite 47.87 47.42 -0.45 -0.012 0.77495E+03 180 ferroactinolite 38.45 34.62 -3.83 -0.104 0.65448E+04 181 troilite-low -4.41 -7.80 -3.39 -1.131 0.57914E+04 183 vesuvianite 223.47 218.82 -4.65 -0.036 0.79438E+04 187 wairakite 3.95 1.95 -2.00 -0.118 0.34155E+04 188 walstromite 11.51 9.94 -1.56 -0.313 0.26719E+04 189 wollastonite 10.46 9.94 -0.52 -0.103 0.88229E+03 190 pseudo-wollastonite 11.00 9.94 -1.06 -0.211 0.18021E+04 191 zoisite 22.85 18.95 -3.90 -0.177 0.66609E+04 192 akaganeite 7.75 4.49 -3.26 -0.705 0.55681E+04 199 chalcedony -2.80 -3.16 -0.35 -0.118 0.60610E+03 201 montmorillonite-Ca -2.29 -6.17 -3.88 -0.240 0.66180E+04 202 montmorillonite-K -2.24 -6.27 -4.03 -0.247 0.68816E+04 203 montmorillonite-Mg -2.48 -6.79 -4.32 -0.267 0.73678E+04 204 montmorillonite-Na -2.04 -5.57 -3.54 -0.216 0.60365E+04 205 nontronite-Ca 3.21 -0.19 -3.41 -0.221 0.58215E+04 206 nontronite-H 2.53 -2.36 -4.89 -0.328 0.83485E+04 207 nontronite-K 3.34 -0.30 -3.64 -0.233 0.62083E+04 208 nontronite-Mg 3.07 -0.82 -3.90 -0.253 0.66553E+04 209 nontronite-Na 3.52 0.40 -3.12 -0.200 0.53292E+04 224 tobermorite 9.82 7.76 -2.07 -0.564 0.35287E+04 230 alabandite -0.98 -5.30 -4.32 -1.439 0.73735E+04 233 boehmite 4.41 0.74 -3.67 -0.611 0.62619E+04 235 ferrous-oxide 9.81 6.73 -3.08 -0.769 0.52532E+04 240 silica-amorphous -2.09 -3.16 -1.07 -0.355 0.18203E+04 242 an20ab80 2.02 1.35 -0.67 -0.052 0.11472E+04 243 an25ab75 2.65 1.78 -0.87 -0.067 0.14810E+04 244 an30ab70 3.28 2.21 -1.07 -0.082 0.18244E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 100.0000000 g Current total amount of reactant added: 4499.9990000 g New total amount of reactant added: 4599.9990000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.5221E-10 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 12 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 4599.9990000 Water: Moles liquid = 0.2978E+02 kg liquid = 0.5365E+00 Moles total = -.2155E+01 kg total = -.3882E-01 Activity = 1.0000 Stoichiometric ionic strength = .1141639E-01 Osmotic coef. = 0.9686 True ionic strength = .2008505E-01 Chg. balance for total moles = 0.5221E-10 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.88584E-10 -10.0526 0.74418E-10 -10.1283 0.84008E+00 -0.0757 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.25599E-03 -3.5918 0.21376E-03 -3.6701 0.83501E+00 -0.0783 4 SO4-- 0.12042E-11 -11.9193 0.62481E-12 -12.2043 0.51886E+00 -0.2850 5 HCO3- 0.44551E-06 -6.3511 0.37256E-06 -6.4288 0.83624E+00 -0.0777 6 HS- 0.47529E-04 -4.3230 0.39693E-04 -4.4013 0.83513E+00 -0.0782 7 Al+++ 0.97993E-29 -29.0088 0.22594E-29 -29.6460 0.23057E+00 -0.6372 8 H4SiO4 0.69598E-03 -3.1574 0.69598E-03 -3.1574 0.10000E+01 0.0000 9 Ca++ 0.13594E-06 -6.8667 0.70014E-07 -7.1548 0.51504E+00 -0.2882 10 Mg++ 0.21267E-10 -10.6723 0.10903E-10 -10.9625 0.51268E+00 -0.2902 11 Fe++ 0.58615E-13 -13.2320 0.30084E-13 -13.5217 0.51324E+00 -0.2897 12 K+ 0.15703E-03 -3.8040 0.13135E-03 -3.8816 0.83644E+00 -0.0776 13 Na+ 0.19927E-01 -1.7006 0.16636E-01 -1.7790 0.83486E+00 -0.0784 14 Mn++ 0.18801E-10 -10.7258 0.96573E-11 -11.0151 0.51366E+00 -0.2893 15 HPO4-- 0.45081E-07 -7.3460 0.23394E-07 -7.6309 0.51893E+00 -0.2849 16 HSiO3- 0.10458E-01 -1.9805 0.87326E-02 -2.0589 0.83501E+00 -0.0783 17 Ca(HSiO3)+ 0.16643E-07 -7.7788 0.13924E-07 -7.8562 0.83662E+00 -0.0775 18 Mg(HSiO3)+ 0.32255E-11 -11.4914 0.26985E-11 -11.5689 0.83662E+00 -0.0775 19 NaHSiO3,aq 0.23496E-02 -2.6290 0.23496E-02 -2.6290 0.10000E+01 0.0000 20 AlO+ 0.66344E-16 -16.1782 0.55504E-16 -16.2557 0.83662E+00 -0.0775 22 HAlO2,aq 0.14853E-09 -9.8282 0.14853E-09 -9.8282 0.10000E+01 0.0000 23 AlO2- 0.53008E-05 -5.2757 0.44182E-05 -5.3548 0.83350E+00 -0.0791 24 CH4,aq 0.23071E-04 -4.6369 0.22991E-04 -4.6385 0.99652E+00 -0.0015 25 C2H6,aq 0.78287E-14 -14.1063 0.78014E-14 -14.1078 0.99652E+00 -0.0015 29 CO,aq 0.17237E-16 -16.7635 0.17237E-16 -16.7635 0.10000E+01 0.0000 30 CO2,aq 0.59448E-10 -10.2259 0.59241E-10 -10.2274 0.99652E+00 -0.0015 31 CO3-2 0.84457E-06 -6.0734 0.43728E-06 -6.3592 0.51775E+00 -0.2859 32 CaCO3,aq 0.38388E-09 -9.4158 0.38388E-09 -9.4158 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.79585E-12 -12.0992 0.66582E-12 -12.1766 0.83662E+00 -0.0775 34 CaCl+ 0.28949E-10 -10.5384 0.24220E-10 -10.6158 0.83662E+00 -0.0775 35 CaCl2,aq 0.12300E-14 -14.9101 0.12300E-14 -14.9101 0.10000E+01 0.0000 36 CaOH+ 0.80146E-07 -7.0961 0.67052E-07 -7.1736 0.83662E+00 -0.0775 37 CaSO4,aq 0.13891E-16 -16.8573 0.13891E-16 -16.8573 0.10000E+01 0.0000 38 HCl,aq 0.29149E-14 -14.5354 0.29149E-14 -14.5354 0.10000E+01 0.0000 43 FeCl+ 0.12166E-16 -16.9148 0.10179E-16 -16.9923 0.83662E+00 -0.0775 46 FeO,aq 0.21113E-09 -9.6755 0.21113E-09 -9.6755 0.10000E+01 0.0000 47 FeOH+ 0.15729E-10 -10.8033 0.13159E-10 -10.8808 0.83662E+00 -0.0775 48 HFeO2- 0.35549E-07 -7.4492 0.29684E-07 -7.5275 0.83501E+00 -0.0783 49 FeO+ 0.11023E-16 -16.9577 0.92223E-17 -17.0352 0.83662E+00 -0.0775 51 FeO2- 0.40808E-09 -9.3893 0.34075E-09 -9.4676 0.83501E+00 -0.0783 52 HFeO2,aq 0.32251E-11 -11.4915 0.32251E-11 -11.4915 0.10000E+01 0.0000 53 H2,aq 0.11623E-04 -4.9347 0.11583E-04 -4.9362 0.99652E+00 -0.0015 54 KCl,aq 0.50886E-09 -9.2934 0.50886E-09 -9.2934 0.10000E+01 0.0000 56 KOH,aq 0.75375E-06 -6.1228 0.75375E-06 -6.1228 0.10000E+01 0.0000 57 KSO4- 0.15251E-14 -14.8167 0.12735E-14 -14.8950 0.83501E+00 -0.0783 58 MgCO3,aq 0.14985E-13 -13.8244 0.14985E-13 -13.8244 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.12664E-15 -15.8974 0.10595E-15 -15.9749 0.83662E+00 -0.0775 60 MgCl+ 0.40860E-14 -14.3887 0.34184E-14 -14.4662 0.83662E+00 -0.0775 61 MgOH+ 0.69063E-10 -10.1608 0.57780E-10 -10.2382 0.83662E+00 -0.0775 63 MnO,aq 0.18059E-08 -8.7433 0.18059E-08 -8.7433 0.10000E+01 0.0000 64 MnOH+ 0.46905E-09 -9.3288 0.39241E-09 -9.4063 0.83662E+00 -0.0775 65 MnO2-2 0.20902E-10 -10.6798 0.10822E-10 -10.9657 0.51775E+00 -0.2859 66 HMnO2- 0.21130E-09 -9.6751 0.17644E-09 -9.7534 0.83501E+00 -0.0783 69 MnCl+ 0.15194E-13 -13.8183 0.12712E-13 -13.8958 0.83662E+00 -0.0775 71 NaCl,aq 0.11785E-05 -5.9287 0.11785E-05 -5.9287 0.10000E+01 0.0000 72 NaOH,aq 0.96047E-04 -4.0175 0.96047E-04 -4.0175 0.10000E+01 0.0000 74 OH- 0.93148E-02 -2.0308 0.77639E-02 -2.1099 0.83350E+00 -0.0791 79 HPO3-2 0.16309E-14 -14.7876 0.84441E-15 -15.0734 0.51775E+00 -0.2859 81 H2PO3- 0.15091E-18 -18.8213 0.12601E-18 -18.8996 0.83501E+00 -0.0783 82 H3PO4,aq 0.90610E-18 -18.0428 0.90610E-18 -18.0428 0.10000E+01 0.0000 83 H2PO4- 0.38424E-10 -10.4154 0.32115E-10 -10.4933 0.83581E+00 -0.0779 84 PO4-3 0.10590E-08 -8.9751 0.25648E-09 -9.5909 0.24220E+00 -0.6158 88 HP2O7-3 0.94016E-18 -18.0268 0.21699E-18 -18.6636 0.23080E+00 -0.6368 89 P2O7-4 0.90653E-17 -17.0426 0.69659E-18 -18.1570 0.76841E-01 -1.1144 90 H2S,aq 0.91612E-08 -8.0380 0.91293E-08 -8.0396 0.99652E+00 -0.0015 91 S2-2 0.58215E-14 -14.2350 0.30141E-14 -14.5208 0.51775E+00 -0.2859 97 SO3-2 0.17904E-17 -17.7470 0.94043E-18 -18.0267 0.52526E+00 -0.2796 99 HSO4- 0.53508E-19 -19.2716 0.44810E-19 -19.3486 0.83743E+00 -0.0771 Charge balance for all species = 0.9734E-10 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.8858447E-10 -.2224453E-01 -.2238211E+02 0.0000 2 H2O 0.1000000E+01 0.5550490E+02 0.9981964E+06 0.0000 3 Cl- 0.2559929E-03 0.2571719E-03 0.9101641E+01 6.4582 4 SO4-- 0.1204201E-11 -.2597653E-04 -.2491002E+01 8.0524 5 HCO3- 0.4455142E-06 0.2436135E-04 0.1483873E+01 3.6995 6 HS- 0.4752896E-04 0.7351465E-04 0.2427043E+01 5.7270 7 Al+++ 0.9799295E-29 0.5300921E-05 0.1427778E+00 0.7390 8 H4SiO4 0.6959780E-03 0.1350373E-01 0.1295657E+04 -3.1574 9 Ca++ 0.1359389E-06 0.2331421E-06 0.9327600E-02 13.1018 10 Mg++ 0.2126692E-10 0.9357561E-10 0.2271049E-05 9.2942 11 Fe++ 0.5861519E-13 0.3618766E-07 0.2017454E-02 6.7350 12 K+ 0.1570317E-03 0.1577859E-03 0.6159003E+01 6.2467 13 Na+ 0.1992662E-01 0.2237348E-01 0.5134664E+03 8.3494 14 Mn++ 0.1880079E-10 0.2525978E-08 0.1385306E-03 9.2415 15 HPO4-- 0.4508090E-07 0.4617829E-07 0.4424430E-02 12.6257 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.7616914E+02 -.1193432E-01 -.7615721E+02 0.0000000E+00 2 H2O -.2154625E+01 0.2977869E+02 -.3193332E+02 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.1275072E+00 -.1393656E-04 0.1275211E+00 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.1274817E+00 0.3944103E-04 -.1275211E+00 0.0000000E+00 7 Al+++ 0.1499941E+02 0.2843974E-05 0.1499941E+02 0.0000000E+00 8 H4SiO4 0.4789879E+02 0.7244830E-02 0.4789155E+02 0.0000000E+00 9 Ca++ 0.5290670E+01 0.1250821E-06 0.5290669E+01 0.0000000E+00 10 Mg++ 0.3650793E+01 0.5020384E-10 0.3650793E+01 0.0000000E+00 11 Fe++ 0.3279839E+01 0.1941489E-07 0.3279839E+01 0.0000000E+00 12 K+ 0.9766452E+00 0.8465305E-04 0.9765606E+00 0.0000000E+00 13 Na+ 0.5774279E+01 0.1200350E-01 0.5762276E+01 0.0000000E+00 14 Mn++ 0.7975752E-01 0.1355202E-08 0.7975752E-01 0.0000000E+00 15 HPO4-- 0.2722085E-01 0.2477492E-07 0.2722082E-01 0.0000000E+00 Chg. balance for solid moles: -.1522E-13 Mass of aqueous solution: 0.537441E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 4599.9990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 5.757 0.760 1510. 3.179 30.04 579.5 andradite 0.5101 -0.292 259.2 2.414 5.158 67.35 grossular 0.1235 -0.908 55.64 1.745 1.107 15.48 apatite-OH 0.9074E-02 -2.042 4.558 0.659 0.9070E-01 1.448 clinochlore 0.6536 -0.185 363.3 2.560 7.229 138.2 daphnite 0.1892 -0.723 135.0 2.130 2.686 40.91 chlorite-Mn 0.1595E-01 -1.797 11.31 1.053 0.2250 3.604 diopside 0.2409 -0.618 52.18 1.717 1.038 15.95 hedenbergite 0.6248E-01 -1.204 15.50 1.190 0.3085 4.246 microcline 0.8563 -0.067 238.4 2.377 4.743 93.11 stilbite 2.963 0.472 2088. 3.320 41.55 973.9 stilpnomelane-Fe 0.2404 -0.619 259.2 2.414 5.158 89.53 tr.625ac.25prg.125 0.3915E-01 -1.407 33.46 1.525 0.6658 10.77 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8051E+00 0.8051E+00 1.0000 -0.094 grossular 0.1949E+00 0.1949E+00 1.0000 -0.710 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.7611E+00 0.7611E+00 1.0000 -0.119 daphnite 0.2203E+00 0.2203E+00 1.0000 -0.657 chlorite-Mn 0.1858E-01 0.1858E-01 1.0000 -1.731 diopside 0.7941E+00 0.7941E+00 1.0000 -0.100 hedenbergite 0.2059E+00 0.2059E+00 1.0000 -0.686 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 tr.625ac.25prg.125 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 5025.335203 g Volume = 2033.965602 cm3 Porosity: -10.4816% V(tot) - V(min): -.19297E+03 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 4599.9990000 g log = 3.6628 Original solution: 1000.0103000 g Original solution / Rock added: 0.22 (Water/Rock Ratio), log = -0.6628 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0696 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9545E+00 0.9853 0.1006E+01 0.1021E+01 CO2,gas 0.5886E-08 1.0067 0.6338E-08 0.6296E-08 CH4,gas 0.3125E-01 1.0123 0.3384E-01 0.3343E-01 H2,gas 0.1421E-01 1.0006 0.1521E-01 0.1520E-01 H2S,gas 0.2356E-06 0.9958 0.2510E-06 0.2520E-06 S2,gas 0.9558E-29 1.0000 0.1022E-28 0.1022E-28 CO,gas 0.2401E-13 1.0000 0.2569E-13 0.2569E-13 SO3,gas 0.1223E-47 1.0000 0.1308E-47 0.1308E-47 SO2,gas 0.7236E-27 1.0000 0.7740E-27 0.7740E-27 HCl,gas 0.4809E-17 1.0000 0.5143E-17 0.5143E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 16 albite -0.38 -0.38 0.00 0.000 -0.13080E-10 22 andradite 39.01 39.01 0.00 0.000 0.12132E-10 23 grossular 32.73 32.73 0.00 0.000 0.24265E-10 32 apatite-OH -18.15 -18.15 0.00 0.000 -0.60662E-11 46 clinochlore 39.07 39.07 0.00 0.000 -0.12132E-10 47 daphnite 28.97 28.97 0.00 0.000 0.00000E+00 48 chlorite-Mn 46.87 46.87 0.00 0.000 0.00000E+00 67 diopside 16.18 16.18 0.00 0.000 0.60662E-11 68 hedenbergite 14.21 14.21 0.00 0.000 -0.60662E-11 116 microcline -2.49 -2.49 0.00 0.000 0.13649E-10 163 stilbite -7.52 -7.52 0.00 0.000 -0.90992E-11 164 stilpnomelane-Fe 13.02 13.02 0.00 0.000 0.21232E-10 245 tr.625ac.25prg.125 45.16 45.16 0.00 0.000 0.12132E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -16.56 -9.90 -3.299 0.16899E+05 -8.198 3 CH4,gas 4.54 1.37 -3.17 -0.792 0.54119E+04 -1.471 4 H2,gas 8.00 4.48 -3.52 -2.010 0.60051E+04 -1.818 5 H2S,gas -6.23 -14.53 -8.30 -4.150 0.14171E+05 -6.600 6 S2,gas -7.34 -38.02 -30.69 -4.721 0.52401E+05 -28.990 7 CO,gas 3.21 -12.07 -15.29 -4.704 0.26106E+05 -13.590 8 SO3,gas 17.12 -32.46 -49.58 -12.396 0.84660E+05 -47.883 9 SO2,gas 0.83 -27.98 -28.81 -7.683 0.49193E+05 -27.111 10 HCl,gas 5.19 -13.80 -18.99 -9.494 0.32421E+05 -17.289 11 acmite 7.71 6.53 -1.18 -0.123 0.20175E+04 15 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 19 spessartine 24.46 19.73 -4.73 -0.236 0.80714E+04 20 analcite 3.32 2.77 -0.55 -0.061 0.93625E+03 26 annite 20.12 17.72 -2.40 -0.134 0.41064E+04 27 phlogopite 27.06 25.40 -1.67 -0.093 0.28489E+04 29 anorthite 12.71 8.26 -4.45 -0.342 0.75903E+04 35 aragonite 0.97 -3.46 -4.42 -1.474 0.75501E+04 36 brucite 12.57 9.29 -3.27 -0.655 0.55909E+04 37 calcite 0.81 -3.46 -4.27 -1.422 0.72859E+04 38 carnegieite-low 9.02 5.93 -3.09 -0.442 0.52801E+04 39 carnegieite-high 10.09 5.93 -4.16 -0.595 0.71071E+04 40 carpholite-Mg 8.58 4.46 -4.12 -0.275 0.70429E+04 41 carpholite-Fe 6.71 1.90 -4.81 -0.321 0.82207E+04 42 celadonite 5.34 3.65 -1.69 -0.099 0.28879E+04 43 celadonite-Fe 3.88 1.09 -2.79 -0.164 0.47561E+04 44 chrysotile 23.89 21.57 -2.32 -0.194 0.39692E+04 49 chlorite-Al-free 47.17 43.14 -4.04 -0.168 0.68936E+04 51 chloritoid-Fe 9.17 5.06 -4.12 -0.275 0.70315E+04 52 chloritoid-Mn 11.40 7.56 -3.84 -0.256 0.65550E+04 54 coesite -2.38 -3.16 -0.78 -0.260 0.13341E+04 61 cristobalite -2.56 -3.16 -0.60 -0.199 0.10195E+04 63 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71234E+04 65 diaspore 2.87 0.74 -2.13 -0.356 0.36450E+04 66 diamond -3.10 -7.59 -4.49 -1.283 0.76650E+04 71 enstatite 17.26 12.27 -4.99 -0.499 0.85226E+04 73 clinoenstatite 17.17 12.27 -4.89 -0.489 0.83541E+04 75 epidote 24.67 22.70 -1.97 -0.095 0.33585E+04 76 clinozoisite 22.81 18.95 -3.86 -0.175 0.65869E+04 77 epidote-Fe 29.84 26.46 -3.38 -0.176 0.57768E+04 78 fayalite 14.05 10.31 -3.73 -0.533 0.63743E+04 79 ferrosilite 11.15 7.16 -3.99 -0.399 0.68202E+04 83 gibbsite 4.08 0.74 -3.34 -0.477 0.57035E+04 84 glaucophane 22.97 20.80 -2.17 -0.059 0.37133E+04 85 glaucophane-Fe 17.28 13.12 -4.15 -0.112 0.70919E+04 86 graphite -3.55 -7.59 -4.05 -1.156 0.69073E+04 87 greenalite 16.14 13.89 -2.25 -0.187 0.38408E+04 90 hematite 12.57 8.99 -3.58 -0.434 0.61111E+04 91 heulandite -5.83 -7.52 -1.69 -0.077 0.28938E+04 95 jadeite 4.22 2.77 -1.44 -0.144 0.24617E+04 97 kalsilite 7.58 3.83 -3.76 -0.537 0.64126E+04 98 kaolinite -1.33 -4.84 -3.50 -0.319 0.59831E+04 101 laumontite 2.88 1.95 -0.93 -0.062 0.15935E+04 102 lawsonite 9.62 8.26 -1.35 -0.090 0.23070E+04 103 leucite 4.12 0.67 -3.45 -0.345 0.58873E+04 105 lizardite 23.24 21.57 -1.68 -0.140 0.28618E+04 107 magnetite 20.09 15.72 -4.37 -0.356 0.74536E+04 108 minnesotaite 10.39 7.58 -2.81 -0.165 0.48028E+04 112 manganosite 14.06 9.24 -4.82 -1.204 0.82242E+04 120 muscovite 2.58 -1.01 -3.59 -0.211 0.61315E+04 121 paragonite 4.24 1.09 -3.15 -0.185 0.53706E+04 122 nepheline 8.34 5.93 -2.41 -0.344 0.41125E+04 128 periclase-Fe 11.63 6.73 -4.89 -1.223 0.83523E+04 134 phlogopite-Na 29.65 27.50 -2.15 -0.119 0.36677E+04 136 prehnite 19.37 18.21 -1.16 -0.068 0.19849E+04 137 prehnite-Fe 22.50 21.96 -0.53 -0.032 0.91158E+03 138 pumpellyite-Fe 46.27 43.89 -2.38 -0.053 0.40581E+04 139 pumpellyite-Mg 48.99 46.45 -2.54 -0.057 0.43420E+04 143 pyrrhotite -4.26 -7.79 -3.53 -1.178 0.60347E+04 144 pyrrhotiteFe0.875 -6.02 -9.19 -3.18 -1.168 0.54220E+04 145 pyroxmangite 7.40 6.08 -1.31 -0.263 0.22446E+04 146 pyrophyllite -6.18 -11.15 -4.98 -0.311 0.84962E+04 147 quartz -2.99 -3.16 -0.17 -0.056 0.28680E+03 152 rhodonite 7.45 6.08 -1.36 -0.272 0.23249E+04 153 sanidine -1.28 -2.49 -1.21 -0.093 0.20677E+04 165 stilpnomelane-Mg 27.44 25.81 -1.63 -0.049 0.27804E+04 171 talc 16.49 15.25 -1.24 -0.073 0.21140E+04 174 tephroite 18.09 15.33 -2.76 -0.394 0.47129E+04 178 tridymite -2.63 -3.16 -0.53 -0.177 0.90678E+03 179 tremolite 47.87 47.42 -0.45 -0.012 0.77494E+03 180 ferroactinolite 38.45 34.62 -3.83 -0.104 0.65448E+04 181 troilite-low -4.41 -7.79 -3.38 -1.128 0.57775E+04 183 vesuvianite 223.47 218.82 -4.65 -0.036 0.79438E+04 187 wairakite 3.95 1.95 -2.00 -0.118 0.34155E+04 188 walstromite 11.51 9.94 -1.56 -0.313 0.26719E+04 189 wollastonite 10.46 9.94 -0.52 -0.103 0.88229E+03 190 pseudo-wollastonite 11.00 9.94 -1.06 -0.211 0.18021E+04 191 zoisite 22.85 18.95 -3.90 -0.177 0.66609E+04 192 akaganeite 7.75 4.49 -3.26 -0.705 0.55681E+04 199 chalcedony -2.80 -3.16 -0.35 -0.118 0.60610E+03 201 montmorillonite-Ca -2.29 -6.17 -3.88 -0.240 0.66180E+04 202 montmorillonite-K -2.24 -6.27 -4.03 -0.247 0.68816E+04 203 montmorillonite-Mg -2.48 -6.79 -4.32 -0.267 0.73678E+04 204 montmorillonite-Na -2.04 -5.57 -3.54 -0.216 0.60365E+04 205 nontronite-Ca 3.21 -0.19 -3.41 -0.221 0.58215E+04 206 nontronite-H 2.53 -2.36 -4.89 -0.328 0.83485E+04 207 nontronite-K 3.34 -0.30 -3.64 -0.233 0.62083E+04 208 nontronite-Mg 3.07 -0.82 -3.90 -0.253 0.66553E+04 209 nontronite-Na 3.52 0.40 -3.12 -0.200 0.53292E+04 224 tobermorite 9.82 7.76 -2.07 -0.564 0.35287E+04 230 alabandite -0.98 -5.29 -4.31 -1.437 0.73596E+04 233 boehmite 4.41 0.74 -3.67 -0.611 0.62619E+04 235 ferrous-oxide 9.81 6.73 -3.08 -0.769 0.52532E+04 240 silica-amorphous -2.09 -3.16 -1.07 -0.355 0.18203E+04 242 an20ab80 2.02 1.35 -0.67 -0.052 0.11472E+04 243 an25ab75 2.65 1.78 -0.87 -0.067 0.14810E+04 244 an30ab70 3.28 2.21 -1.07 -0.082 0.18244E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 100.0000000 g Current total amount of reactant added: 4599.9990000 g New total amount of reactant added: 4699.9990000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.5221E-10 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 12 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 4699.9990000 Water: Moles liquid = 0.2922E+02 kg liquid = 0.5265E+00 Moles total = -.3408E+01 kg total = -.6140E-01 Activity = 1.0000 Stoichiometric ionic strength = .1142045E-01 Osmotic coef. = 0.9686 True ionic strength = .2008822E-01 Chg. balance for total moles = 0.5221E-10 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.88598E-10 -10.0526 0.74429E-10 -10.1283 0.84007E+00 -0.0757 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.26088E-03 -3.5836 0.21783E-03 -3.6619 0.83500E+00 -0.0783 4 SO4-- 0.12270E-11 -11.9111 0.63663E-12 -12.1961 0.51883E+00 -0.2850 5 HCO3- 0.45396E-06 -6.3430 0.37961E-06 -6.4207 0.83623E+00 -0.0777 6 HS- 0.48436E-04 -4.3148 0.40450E-04 -4.3931 0.83513E+00 -0.0782 7 Al+++ 0.98045E-29 -29.0086 0.22604E-29 -29.6458 0.23055E+00 -0.6372 8 H4SiO4 0.69598E-03 -3.1574 0.69598E-03 -3.1574 0.10000E+01 0.0000 9 Ca++ 0.13598E-06 -6.8665 0.70034E-07 -7.1547 0.51502E+00 -0.2882 10 Mg++ 0.21274E-10 -10.6721 0.10906E-10 -10.9623 0.51265E+00 -0.2902 11 Fe++ 0.58635E-13 -13.2318 0.30092E-13 -13.5215 0.51322E+00 -0.2897 12 K+ 0.15706E-03 -3.8039 0.13137E-03 -3.8815 0.83643E+00 -0.0776 13 Na+ 0.19930E-01 -1.7005 0.16638E-01 -1.7789 0.83485E+00 -0.0784 14 Mn++ 0.18808E-10 -10.7257 0.96605E-11 -11.0150 0.51364E+00 -0.2893 15 HPO4-- 0.45070E-07 -7.3461 0.23387E-07 -7.6310 0.51891E+00 -0.2849 16 HSiO3- 0.10457E-01 -1.9806 0.87314E-02 -2.0589 0.83500E+00 -0.0783 17 Ca(HSiO3)+ 0.16646E-07 -7.7787 0.13926E-07 -7.8562 0.83661E+00 -0.0775 18 Mg(HSiO3)+ 0.32260E-11 -11.4913 0.26989E-11 -11.5688 0.83661E+00 -0.0775 19 NaHSiO3,aq 0.23496E-02 -2.6290 0.23496E-02 -2.6290 0.10000E+01 0.0000 20 AlO+ 0.66354E-16 -16.1781 0.55512E-16 -16.2556 0.83661E+00 -0.0775 22 HAlO2,aq 0.14853E-09 -9.8282 0.14853E-09 -9.8282 0.10000E+01 0.0000 23 AlO2- 0.53000E-05 -5.2757 0.44175E-05 -5.3548 0.83349E+00 -0.0791 24 CH4,aq 0.23511E-04 -4.6287 0.23429E-04 -4.6302 0.99652E+00 -0.0015 25 C2H6,aq 0.81304E-14 -14.0899 0.81021E-14 -14.0914 0.99652E+00 -0.0015 29 CO,aq 0.17566E-16 -16.7553 0.17566E-16 -16.7553 0.10000E+01 0.0000 30 CO2,aq 0.60583E-10 -10.2176 0.60372E-10 -10.2192 0.99652E+00 -0.0015 31 CO3-2 0.86048E-06 -6.0653 0.44550E-06 -6.3512 0.51773E+00 -0.2859 32 CaCO3,aq 0.39121E-09 -9.4076 0.39121E-09 -9.4076 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.81117E-12 -12.0909 0.67863E-12 -12.1684 0.83661E+00 -0.0775 34 CaCl+ 0.29510E-10 -10.5300 0.24688E-10 -10.6075 0.83661E+00 -0.0775 35 CaCl2,aq 0.12777E-14 -14.8936 0.12777E-14 -14.8936 0.10000E+01 0.0000 36 CaOH+ 0.80159E-07 -7.0960 0.67061E-07 -7.1735 0.83661E+00 -0.0775 37 CaSO4,aq 0.14158E-16 -16.8490 0.14158E-16 -16.8490 0.10000E+01 0.0000 38 HCl,aq 0.29710E-14 -14.5271 0.29710E-14 -14.5271 0.10000E+01 0.0000 43 FeCl+ 0.12402E-16 -16.9065 0.10376E-16 -16.9840 0.83661E+00 -0.0775 46 FeO,aq 0.21113E-09 -9.6755 0.21113E-09 -9.6755 0.10000E+01 0.0000 47 FeOH+ 0.15731E-10 -10.8032 0.13161E-10 -10.8807 0.83661E+00 -0.0775 48 HFeO2- 0.35545E-07 -7.4492 0.29680E-07 -7.5275 0.83500E+00 -0.0783 49 FeO+ 0.11025E-16 -16.9576 0.92237E-17 -17.0351 0.83661E+00 -0.0775 51 FeO2- 0.40802E-09 -9.3893 0.34070E-09 -9.4676 0.83500E+00 -0.0783 52 HFeO2,aq 0.32251E-11 -11.4915 0.32251E-11 -11.4915 0.10000E+01 0.0000 53 H2,aq 0.11623E-04 -4.9347 0.11583E-04 -4.9362 0.99652E+00 -0.0015 54 KCl,aq 0.51864E-09 -9.2851 0.51864E-09 -9.2851 0.10000E+01 0.0000 56 KOH,aq 0.75375E-06 -6.1228 0.75375E-06 -6.1228 0.10000E+01 0.0000 57 KSO4- 0.15542E-14 -14.8085 0.12978E-14 -14.8868 0.83500E+00 -0.0783 58 MgCO3,aq 0.15271E-13 -13.8161 0.15271E-13 -13.8161 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.12908E-15 -15.8892 0.10799E-15 -15.9666 0.83661E+00 -0.0775 60 MgCl+ 0.41651E-14 -14.3804 0.34846E-14 -14.4578 0.83661E+00 -0.0775 61 MgOH+ 0.69074E-10 -10.1607 0.57788E-10 -10.2382 0.83661E+00 -0.0775 63 MnO,aq 0.18060E-08 -8.7433 0.18060E-08 -8.7433 0.10000E+01 0.0000 64 MnOH+ 0.46914E-09 -9.3287 0.39249E-09 -9.4062 0.83661E+00 -0.0775 65 MnO2-2 0.20898E-10 -10.6799 0.10819E-10 -10.9658 0.51773E+00 -0.2859 66 HMnO2- 0.21128E-09 -9.6751 0.17642E-09 -9.7534 0.83500E+00 -0.0783 69 MnCl+ 0.15489E-13 -13.8100 0.12959E-13 -13.8874 0.83661E+00 -0.0775 71 NaCl,aq 0.12011E-05 -5.9204 0.12011E-05 -5.9204 0.10000E+01 0.0000 72 NaOH,aq 0.96047E-04 -4.0175 0.96047E-04 -4.0175 0.10000E+01 0.0000 74 OH- 0.93136E-02 -2.0309 0.77628E-02 -2.1100 0.83349E+00 -0.0791 79 HPO3-2 0.16305E-14 -14.7877 0.84416E-15 -15.0736 0.51773E+00 -0.2859 81 H2PO3- 0.15089E-18 -18.8213 0.12599E-18 -18.8997 0.83500E+00 -0.0783 82 H3PO4,aq 0.90610E-18 -18.0428 0.90610E-18 -18.0428 0.10000E+01 0.0000 83 H2PO4- 0.38419E-10 -10.4155 0.32111E-10 -10.4934 0.83580E+00 -0.0779 84 PO4-3 0.10586E-08 -8.9753 0.25637E-09 -9.5911 0.24218E+00 -0.6159 88 HP2O7-3 0.93983E-18 -18.0269 0.21690E-18 -18.6637 0.23078E+00 -0.6368 89 P2O7-4 0.90615E-17 -17.0428 0.69618E-18 -18.1573 0.76829E-01 -1.1145 90 H2S,aq 0.93372E-08 -8.0298 0.93047E-08 -8.0313 0.99652E+00 -0.0015 91 S2-2 0.60458E-14 -14.2185 0.31301E-14 -14.5044 0.51773E+00 -0.2859 97 SO3-2 0.18244E-17 -17.7389 0.95822E-18 -18.0185 0.52524E+00 -0.2796 99 HSO4- 0.54529E-19 -19.2634 0.45664E-19 -19.3404 0.83742E+00 -0.0771 Charge balance for all species = 0.9925E-10 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.8859831E-10 -.2224187E-01 -.2237943E+02 0.0000 2 H2O 0.1000000E+01 0.5550490E+02 0.9981963E+06 0.0000 3 Cl- 0.2608760E-03 0.2620776E-03 0.9275259E+01 6.4664 4 SO4-- 0.1227036E-11 -.2641688E-04 -.2533229E+01 8.0604 5 HCO3- 0.4539575E-06 0.2482606E-04 0.1512179E+01 3.7076 6 HS- 0.4843560E-04 0.7486182E-04 0.2471519E+01 5.7352 7 Al+++ 0.9804509E-29 0.5300195E-05 0.1427582E+00 0.7390 8 H4SiO4 0.6959784E-03 0.1350232E-01 0.1295521E+04 -3.1574 9 Ca++ 0.1359844E-06 0.2332106E-06 0.9330339E-02 13.1018 10 Mg++ 0.2127404E-10 0.9359342E-10 0.2271481E-05 9.2942 11 Fe++ 0.5863484E-13 0.3618278E-07 0.2017181E-02 6.7350 12 K+ 0.1570563E-03 0.1578106E-03 0.6159964E+01 6.2467 13 Na+ 0.1992975E-01 0.2237664E-01 0.5135386E+03 8.3494 14 Mn++ 0.1880786E-10 0.2526128E-08 0.1385388E-03 9.2415 15 HPO4-- 0.4506960E-07 0.4616662E-07 0.4423311E-02 12.6255 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.7782499E+02 -.1170952E-01 -.7781328E+02 0.0000000E+00 2 H2O -.3408166E+01 0.2922128E+02 -.3262944E+02 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.1302785E+00 -.1390751E-04 0.1302924E+00 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.1302530E+00 0.3941198E-04 -.1302924E+00 0.0000000E+00 7 Al+++ 0.1532548E+02 0.2790356E-05 0.1532548E+02 0.0000000E+00 8 H4SiO4 0.4894007E+02 0.7108473E-02 0.4893296E+02 0.0000000E+00 9 Ca++ 0.5405684E+01 0.1227767E-06 0.5405684E+01 0.0000000E+00 10 Mg++ 0.3730158E+01 0.4927347E-10 0.3730158E+01 0.0000000E+00 11 Fe++ 0.3351140E+01 0.1904889E-07 0.3351140E+01 0.0000000E+00 12 K+ 0.9978766E+00 0.8308142E-04 0.9977936E+00 0.0000000E+00 13 Na+ 0.5899804E+01 0.1178047E-01 0.5888023E+01 0.0000000E+00 14 Mn++ 0.8149138E-01 0.1329913E-08 0.8149138E-01 0.0000000E+00 15 HPO4-- 0.2781260E-01 0.2430502E-07 0.2781258E-01 0.0000000E+00 Chg. balance for solid moles: -.4441E-15 Mass of aqueous solution: 0.527381E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 4699.9990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 5.883 0.770 1543. 3.188 30.04 592.2 andradite 0.5212 -0.283 264.8 2.423 5.158 68.81 grossular 0.1262 -0.899 56.85 1.755 1.107 15.82 apatite-OH 0.9271E-02 -2.033 4.657 0.668 0.9070E-01 1.480 clinochlore 0.6678 -0.175 371.2 2.570 7.229 141.2 daphnite 0.1933 -0.714 137.9 2.140 2.686 41.80 chlorite-Mn 0.1630E-01 -1.788 11.55 1.063 0.2250 3.682 diopside 0.2464 -0.608 53.36 1.727 1.039 16.31 hedenbergite 0.6389E-01 -1.195 15.85 1.200 0.3087 4.342 microcline 0.8750 -0.058 243.5 2.387 4.743 95.13 stilbite 3.027 0.481 2133. 3.329 41.55 995.0 stilpnomelane-Fe 0.2457 -0.610 264.8 2.423 5.158 91.48 tr.625ac.25prg.125 0.3998E-01 -1.398 34.17 1.534 0.6656 11.00 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8051E+00 0.8051E+00 1.0000 -0.094 grossular 0.1949E+00 0.1949E+00 1.0000 -0.710 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.7611E+00 0.7611E+00 1.0000 -0.119 daphnite 0.2203E+00 0.2203E+00 1.0000 -0.657 chlorite-Mn 0.1858E-01 0.1858E-01 1.0000 -1.731 diopside 0.7941E+00 0.7941E+00 1.0000 -0.100 hedenbergite 0.2059E+00 0.2059E+00 1.0000 -0.686 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 tr.625ac.25prg.125 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 5134.585867 g Volume = 2078.168666 cm3 Porosity: -10.4821% V(tot) - V(min): -.19717E+03 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 4699.9990000 g log = 3.6721 Original solution: 1000.0103000 g Original solution / Rock added: 0.21 (Water/Rock Ratio), log = -0.6721 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0703 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9540E+00 0.9853 0.1006E+01 0.1021E+01 CO2,gas 0.5995E-08 1.0067 0.6459E-08 0.6416E-08 CH4,gas 0.3183E-01 1.0123 0.3449E-01 0.3407E-01 H2,gas 0.1420E-01 1.0006 0.1521E-01 0.1520E-01 H2S,gas 0.2400E-06 0.9958 0.2558E-06 0.2568E-06 S2,gas 0.9923E-29 1.0000 0.1062E-28 0.1062E-28 CO,gas 0.2446E-13 1.0000 0.2618E-13 0.2618E-13 SO3,gas 0.1246E-47 1.0000 0.1333E-47 0.1333E-47 SO2,gas 0.7371E-27 1.0000 0.7889E-27 0.7889E-27 HCl,gas 0.4898E-17 1.0000 0.5242E-17 0.5242E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 16 albite -0.38 -0.38 0.00 0.000 -0.13080E-10 22 andradite 39.01 39.01 0.00 0.000 0.00000E+00 23 grossular 32.73 32.73 0.00 0.000 -0.36397E-10 32 apatite-OH -18.15 -18.15 0.00 0.000 0.00000E+00 46 clinochlore 39.07 39.07 0.00 0.000 0.00000E+00 47 daphnite 28.97 28.97 0.00 0.000 0.18198E-10 48 chlorite-Mn 46.87 46.87 0.00 0.000 -0.24265E-10 67 diopside 16.18 16.18 0.00 0.000 0.00000E+00 68 hedenbergite 14.21 14.21 0.00 0.000 -0.30331E-11 116 microcline -2.49 -2.49 0.00 0.000 0.15165E-11 163 stilbite -7.52 -7.52 0.00 0.000 -0.33364E-10 164 stilpnomelane-Fe 13.02 13.02 0.00 0.000 0.69761E-10 245 tr.625ac.25prg.125 45.16 45.16 0.00 0.000 0.24265E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -16.55 -9.89 -3.296 0.16885E+05 -8.190 3 CH4,gas 4.54 1.38 -3.16 -0.790 0.53979E+04 -1.462 4 H2,gas 8.00 4.48 -3.52 -2.010 0.60051E+04 -1.818 5 H2S,gas -6.23 -14.52 -8.29 -4.146 0.14157E+05 -6.592 6 S2,gas -7.34 -38.01 -30.67 -4.719 0.52373E+05 -28.974 7 CO,gas 3.21 -12.07 -15.28 -4.702 0.26092E+05 -13.582 8 SO3,gas 17.12 -32.45 -49.57 -12.393 0.84646E+05 -47.875 9 SO2,gas 0.83 -27.97 -28.80 -7.681 0.49179E+05 -27.103 10 HCl,gas 5.19 -13.79 -18.98 -9.490 0.32407E+05 -17.280 11 acmite 7.71 6.53 -1.18 -0.123 0.20175E+04 15 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 19 spessartine 24.46 19.73 -4.73 -0.236 0.80713E+04 20 analcite 3.32 2.77 -0.55 -0.061 0.93625E+03 26 annite 20.12 17.72 -2.40 -0.134 0.41064E+04 27 phlogopite 27.06 25.40 -1.67 -0.093 0.28489E+04 29 anorthite 12.71 8.26 -4.45 -0.342 0.75903E+04 35 aragonite 0.97 -3.45 -4.41 -1.471 0.75361E+04 36 brucite 12.57 9.29 -3.27 -0.655 0.55909E+04 37 calcite 0.81 -3.45 -4.26 -1.420 0.72719E+04 38 carnegieite-low 9.02 5.93 -3.09 -0.442 0.52801E+04 39 carnegieite-high 10.09 5.93 -4.16 -0.595 0.71071E+04 40 carpholite-Mg 8.58 4.46 -4.12 -0.275 0.70429E+04 41 carpholite-Fe 6.71 1.90 -4.81 -0.321 0.82207E+04 42 celadonite 5.34 3.65 -1.69 -0.099 0.28879E+04 43 celadonite-Fe 3.88 1.09 -2.79 -0.164 0.47561E+04 44 chrysotile 23.89 21.57 -2.32 -0.194 0.39692E+04 49 chlorite-Al-free 47.17 43.14 -4.04 -0.168 0.68936E+04 51 chloritoid-Fe 9.17 5.06 -4.12 -0.275 0.70315E+04 52 chloritoid-Mn 11.40 7.56 -3.84 -0.256 0.65550E+04 54 coesite -2.38 -3.16 -0.78 -0.260 0.13341E+04 61 cristobalite -2.56 -3.16 -0.60 -0.199 0.10195E+04 63 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71234E+04 65 diaspore 2.87 0.74 -2.13 -0.356 0.36450E+04 66 diamond -3.10 -7.58 -4.48 -1.280 0.76510E+04 71 enstatite 17.26 12.27 -4.99 -0.499 0.85226E+04 73 clinoenstatite 17.17 12.27 -4.89 -0.489 0.83541E+04 75 epidote 24.67 22.70 -1.97 -0.095 0.33585E+04 76 clinozoisite 22.81 18.95 -3.86 -0.175 0.65869E+04 77 epidote-Fe 29.84 26.46 -3.38 -0.176 0.57768E+04 78 fayalite 14.05 10.31 -3.73 -0.533 0.63743E+04 79 ferrosilite 11.15 7.16 -3.99 -0.399 0.68202E+04 83 gibbsite 4.08 0.74 -3.34 -0.477 0.57035E+04 84 glaucophane 22.97 20.80 -2.17 -0.059 0.37133E+04 85 glaucophane-Fe 17.28 13.12 -4.15 -0.112 0.70919E+04 86 graphite -3.55 -7.58 -4.04 -1.153 0.68932E+04 87 greenalite 16.14 13.89 -2.25 -0.187 0.38408E+04 90 hematite 12.57 8.99 -3.58 -0.434 0.61111E+04 91 heulandite -5.83 -7.52 -1.69 -0.077 0.28938E+04 95 jadeite 4.22 2.77 -1.44 -0.144 0.24617E+04 97 kalsilite 7.58 3.83 -3.76 -0.537 0.64126E+04 98 kaolinite -1.33 -4.84 -3.50 -0.319 0.59831E+04 101 laumontite 2.88 1.95 -0.93 -0.062 0.15935E+04 102 lawsonite 9.62 8.26 -1.35 -0.090 0.23070E+04 103 leucite 4.12 0.67 -3.45 -0.345 0.58873E+04 105 lizardite 23.24 21.57 -1.68 -0.140 0.28618E+04 107 magnetite 20.09 15.72 -4.37 -0.356 0.74536E+04 108 minnesotaite 10.39 7.58 -2.81 -0.165 0.48028E+04 112 manganosite 14.06 9.24 -4.82 -1.204 0.82242E+04 120 muscovite 2.58 -1.01 -3.59 -0.211 0.61315E+04 121 paragonite 4.24 1.09 -3.15 -0.185 0.53706E+04 122 nepheline 8.34 5.93 -2.41 -0.344 0.41125E+04 128 periclase-Fe 11.63 6.73 -4.89 -1.223 0.83523E+04 134 phlogopite-Na 29.65 27.50 -2.15 -0.119 0.36677E+04 136 prehnite 19.37 18.21 -1.16 -0.068 0.19849E+04 137 prehnite-Fe 22.50 21.96 -0.53 -0.032 0.91158E+03 138 pumpellyite-Fe 46.27 43.89 -2.38 -0.053 0.40581E+04 139 pumpellyite-Mg 48.99 46.45 -2.54 -0.057 0.43420E+04 143 pyrrhotite -4.26 -7.79 -3.53 -1.175 0.60206E+04 144 pyrrhotiteFe0.875 -6.02 -9.18 -3.17 -1.165 0.54078E+04 145 pyroxmangite 7.40 6.08 -1.31 -0.263 0.22446E+04 146 pyrophyllite -6.18 -11.15 -4.98 -0.311 0.84962E+04 147 quartz -2.99 -3.16 -0.17 -0.056 0.28680E+03 152 rhodonite 7.45 6.08 -1.36 -0.272 0.23248E+04 153 sanidine -1.28 -2.49 -1.21 -0.093 0.20677E+04 165 stilpnomelane-Mg 27.44 25.81 -1.63 -0.049 0.27804E+04 171 talc 16.49 15.25 -1.24 -0.073 0.21140E+04 174 tephroite 18.09 15.33 -2.76 -0.394 0.47129E+04 178 tridymite -2.63 -3.16 -0.53 -0.177 0.90678E+03 179 tremolite 47.87 47.42 -0.45 -0.012 0.77494E+03 180 ferroactinolite 38.45 34.62 -3.83 -0.104 0.65448E+04 181 troilite-low -4.41 -7.79 -3.38 -1.125 0.57634E+04 183 vesuvianite 223.47 218.82 -4.65 -0.036 0.79438E+04 187 wairakite 3.95 1.95 -2.00 -0.118 0.34155E+04 188 walstromite 11.51 9.94 -1.56 -0.313 0.26719E+04 189 wollastonite 10.46 9.94 -0.52 -0.103 0.88229E+03 190 pseudo-wollastonite 11.00 9.94 -1.06 -0.211 0.18021E+04 191 zoisite 22.85 18.95 -3.90 -0.177 0.66609E+04 192 akaganeite 7.75 4.49 -3.26 -0.705 0.55681E+04 199 chalcedony -2.80 -3.16 -0.35 -0.118 0.60610E+03 201 montmorillonite-Ca -2.29 -6.17 -3.88 -0.240 0.66180E+04 202 montmorillonite-K -2.24 -6.27 -4.03 -0.247 0.68816E+04 203 montmorillonite-Mg -2.48 -6.79 -4.32 -0.267 0.73678E+04 204 montmorillonite-Na -2.04 -5.57 -3.54 -0.216 0.60365E+04 205 nontronite-Ca 3.21 -0.19 -3.41 -0.221 0.58215E+04 206 nontronite-H 2.53 -2.36 -4.89 -0.328 0.83485E+04 207 nontronite-K 3.34 -0.30 -3.64 -0.233 0.62083E+04 208 nontronite-Mg 3.07 -0.82 -3.90 -0.253 0.66553E+04 209 nontronite-Na 3.52 0.40 -3.12 -0.200 0.53292E+04 224 tobermorite 9.82 7.76 -2.07 -0.564 0.35287E+04 230 alabandite -0.98 -5.28 -4.30 -1.434 0.73455E+04 233 boehmite 4.41 0.74 -3.67 -0.611 0.62619E+04 235 ferrous-oxide 9.81 6.73 -3.08 -0.769 0.52532E+04 240 silica-amorphous -2.09 -3.16 -1.07 -0.355 0.18203E+04 242 an20ab80 2.02 1.35 -0.67 -0.052 0.11472E+04 243 an25ab75 2.65 1.78 -0.87 -0.067 0.14810E+04 244 an30ab70 3.28 2.21 -1.07 -0.082 0.18244E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 100.0000000 g Current total amount of reactant added: 4699.9990000 g New total amount of reactant added: 4799.9990000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.5222E-10 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 12 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 4799.9990000 Water: Moles liquid = 0.2867E+02 kg liquid = 0.5164E+00 Moles total = -.4662E+01 kg total = -.8398E-01 Activity = 1.0000 Stoichiometric ionic strength = .1142467E-01 Osmotic coef. = 0.9686 True ionic strength = .2009151E-01 Chg. balance for total moles = 0.5222E-10 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.88613E-10 -10.0525 0.74440E-10 -10.1282 0.84006E+00 -0.0757 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.26595E-03 -3.5752 0.22207E-03 -3.6535 0.83499E+00 -0.0783 4 SO4-- 0.12508E-11 -11.9028 0.64891E-12 -12.1878 0.51881E+00 -0.2850 5 HCO3- 0.46273E-06 -6.3347 0.38694E-06 -6.4124 0.83622E+00 -0.0777 6 HS- 0.49378E-04 -4.3065 0.41236E-04 -4.3847 0.83512E+00 -0.0783 7 Al+++ 0.98099E-29 -29.0083 0.22615E-29 -29.6456 0.23053E+00 -0.6373 8 H4SiO4 0.69598E-03 -3.1574 0.69598E-03 -3.1574 0.10000E+01 0.0000 9 Ca++ 0.13603E-06 -6.8664 0.70055E-07 -7.1546 0.51499E+00 -0.2882 10 Mg++ 0.21281E-10 -10.6720 0.10910E-10 -10.9622 0.51263E+00 -0.2902 11 Fe++ 0.58655E-13 -13.2317 0.30102E-13 -13.5214 0.51319E+00 -0.2897 12 K+ 0.15708E-03 -3.8039 0.13139E-03 -3.8815 0.83642E+00 -0.0776 13 Na+ 0.19933E-01 -1.7004 0.16641E-01 -1.7788 0.83484E+00 -0.0784 14 Mn++ 0.18815E-10 -10.7255 0.96638E-11 -11.0149 0.51362E+00 -0.2894 15 HPO4-- 0.45058E-07 -7.3462 0.23380E-07 -7.6312 0.51889E+00 -0.2849 16 HSiO3- 0.10455E-01 -1.9807 0.87300E-02 -2.0590 0.83499E+00 -0.0783 17 Ca(HSiO3)+ 0.16649E-07 -7.7786 0.13928E-07 -7.8561 0.83660E+00 -0.0775 18 Mg(HSiO3)+ 0.32266E-11 -11.4913 0.26993E-11 -11.5687 0.83660E+00 -0.0775 19 NaHSiO3,aq 0.23496E-02 -2.6290 0.23496E-02 -2.6290 0.10000E+01 0.0000 20 AlO+ 0.66365E-16 -16.1781 0.55521E-16 -16.2555 0.83660E+00 -0.0775 22 HAlO2,aq 0.14853E-09 -9.8282 0.14853E-09 -9.8282 0.10000E+01 0.0000 23 AlO2- 0.52993E-05 -5.2758 0.44169E-05 -5.3549 0.83348E+00 -0.0791 24 CH4,aq 0.23969E-04 -4.6204 0.23885E-04 -4.6219 0.99652E+00 -0.0015 25 C2H6,aq 0.84499E-14 -14.0732 0.84204E-14 -14.0747 0.99652E+00 -0.0015 29 CO,aq 0.17908E-16 -16.7470 0.17908E-16 -16.7470 0.10000E+01 0.0000 30 CO2,aq 0.61762E-10 -10.2093 0.61547E-10 -10.2108 0.99652E+00 -0.0015 31 CO3-2 0.87699E-06 -6.0570 0.45403E-06 -6.3429 0.51771E+00 -0.2859 32 CaCO3,aq 0.39882E-09 -9.3992 0.39882E-09 -9.3992 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.82709E-12 -12.0824 0.69194E-12 -12.1599 0.83660E+00 -0.0775 34 CaCl+ 0.30093E-10 -10.5215 0.25176E-10 -10.5990 0.83660E+00 -0.0775 35 CaCl2,aq 0.13282E-14 -14.8767 0.13282E-14 -14.8767 0.10000E+01 0.0000 36 CaOH+ 0.80172E-07 -7.0960 0.67072E-07 -7.1735 0.83660E+00 -0.0775 37 CaSO4,aq 0.14435E-16 -16.8406 0.14435E-16 -16.8406 0.10000E+01 0.0000 38 HCl,aq 0.30292E-14 -14.5187 0.30292E-14 -14.5187 0.10000E+01 0.0000 43 FeCl+ 0.12647E-16 -16.8980 0.10580E-16 -16.9755 0.83660E+00 -0.0775 46 FeO,aq 0.21113E-09 -9.6755 0.21113E-09 -9.6755 0.10000E+01 0.0000 47 FeOH+ 0.15734E-10 -10.8032 0.13163E-10 -10.8807 0.83660E+00 -0.0775 48 HFeO2- 0.35540E-07 -7.4493 0.29675E-07 -7.5276 0.83499E+00 -0.0783 49 FeO+ 0.11027E-16 -16.9575 0.92251E-17 -17.0350 0.83660E+00 -0.0775 51 FeO2- 0.40797E-09 -9.3894 0.34065E-09 -9.4677 0.83499E+00 -0.0783 52 HFeO2,aq 0.32251E-11 -11.4915 0.32251E-11 -11.4915 0.10000E+01 0.0000 53 H2,aq 0.11623E-04 -4.9347 0.11583E-04 -4.9362 0.99652E+00 -0.0015 54 KCl,aq 0.52880E-09 -9.2767 0.52880E-09 -9.2767 0.10000E+01 0.0000 56 KOH,aq 0.75375E-06 -6.1228 0.75375E-06 -6.1228 0.10000E+01 0.0000 57 KSO4- 0.15844E-14 -14.8001 0.13230E-14 -14.8784 0.83499E+00 -0.0783 58 MgCO3,aq 0.15568E-13 -13.8078 0.15568E-13 -13.8078 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.13161E-15 -15.8807 0.11010E-15 -15.9582 0.83660E+00 -0.0775 60 MgCl+ 0.42474E-14 -14.3719 0.35534E-14 -14.4494 0.83660E+00 -0.0775 61 MgOH+ 0.69085E-10 -10.1606 0.57797E-10 -10.2381 0.83660E+00 -0.0775 63 MnO,aq 0.18061E-08 -8.7433 0.18061E-08 -8.7433 0.10000E+01 0.0000 64 MnOH+ 0.46924E-09 -9.3286 0.39256E-09 -9.4061 0.83660E+00 -0.0775 65 MnO2-2 0.20893E-10 -10.6800 0.10817E-10 -10.9659 0.51771E+00 -0.2859 66 HMnO2- 0.21126E-09 -9.6752 0.17640E-09 -9.7535 0.83499E+00 -0.0783 69 MnCl+ 0.15796E-13 -13.8015 0.13215E-13 -13.8789 0.83660E+00 -0.0775 71 NaCl,aq 0.12247E-05 -5.9120 0.12247E-05 -5.9120 0.10000E+01 0.0000 72 NaOH,aq 0.96047E-04 -4.0175 0.96047E-04 -4.0175 0.10000E+01 0.0000 74 OH- 0.93123E-02 -2.0309 0.77616E-02 -2.1100 0.83348E+00 -0.0791 79 HPO3-2 0.16301E-14 -14.7878 0.84390E-15 -15.0737 0.51771E+00 -0.2859 81 H2PO3- 0.15087E-18 -18.8214 0.12597E-18 -18.8997 0.83499E+00 -0.0783 82 H3PO4,aq 0.90610E-18 -18.0428 0.90610E-18 -18.0428 0.10000E+01 0.0000 83 H2PO4- 0.38414E-10 -10.4155 0.32106E-10 -10.4934 0.83579E+00 -0.0779 84 PO4-3 0.10582E-08 -8.9754 0.25625E-09 -9.5913 0.24216E+00 -0.6159 88 HP2O7-3 0.93950E-18 -18.0271 0.21680E-18 -18.6639 0.23076E+00 -0.6368 89 P2O7-4 0.90575E-17 -17.0430 0.69576E-18 -18.1575 0.76816E-01 -1.1145 90 H2S,aq 0.95201E-08 -8.0214 0.94870E-08 -8.0229 0.99652E+00 -0.0015 91 S2-2 0.62834E-14 -14.2018 0.32530E-14 -14.4877 0.51771E+00 -0.2859 97 SO3-2 0.18596E-17 -17.7306 0.97670E-18 -18.0102 0.52522E+00 -0.2797 99 HSO4- 0.55590E-19 -19.2550 0.46552E-19 -19.3321 0.83741E+00 -0.0771 Charge balance for all species = 0.1012E-09 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.8861269E-10 -.2223910E-01 -.2237664E+02 0.0000 2 H2O 0.1000000E+01 0.5550490E+02 0.9981961E+06 0.0000 3 Cl- 0.2659489E-03 0.2671742E-03 0.9455630E+01 6.4747 4 SO4-- 0.1250752E-11 -.2687437E-04 -.2577099E+01 8.0686 5 HCO3- 0.4627269E-06 0.2530884E-04 0.1541585E+01 3.7158 6 HS- 0.4937751E-04 0.7626140E-04 0.2517725E+01 5.7435 7 Al+++ 0.9809930E-29 0.5299441E-05 0.1427379E+00 0.7390 8 H4SiO4 0.6959787E-03 0.1350085E-01 0.1295380E+04 -3.1574 9 Ca++ 0.1360316E-06 0.2332818E-06 0.9333185E-02 13.1018 10 Mg++ 0.2128145E-10 0.9361365E-10 0.2271972E-05 9.2942 11 Fe++ 0.5865525E-13 0.3617770E-07 0.2016898E-02 6.7350 12 K+ 0.1570819E-03 0.1578361E-03 0.6160961E+01 6.2467 13 Na+ 0.1993300E-01 0.2237991E-01 0.5136137E+03 8.3494 14 Mn++ 0.1881515E-10 0.2526275E-08 0.1385468E-03 9.2415 15 HPO4-- 0.4505786E-07 0.4615449E-07 0.4422148E-02 12.6252 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.7948084E+02 -.1148472E-01 -.7946936E+02 0.0000000E+00 2 H2O -.4661707E+01 0.2866386E+02 -.3332557E+02 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.1330498E+00 -.1387847E-04 0.1330637E+00 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.1330243E+00 0.3938294E-04 -.1330637E+00 0.0000000E+00 7 Al+++ 0.1565156E+02 0.2736739E-05 0.1565155E+02 0.0000000E+00 8 H4SiO4 0.4998135E+02 0.6972116E-02 0.4997438E+02 0.0000000E+00 9 Ca++ 0.5520698E+01 0.1204715E-06 0.5520698E+01 0.0000000E+00 10 Mg++ 0.3809523E+01 0.4834400E-10 0.3809523E+01 0.0000000E+00 11 Fe++ 0.3422441E+01 0.1868290E-07 0.3422441E+01 0.0000000E+00 12 K+ 0.1019108E+01 0.8150980E-04 0.1019027E+01 0.0000000E+00 13 Na+ 0.6025328E+01 0.1155744E-01 0.6013771E+01 0.0000000E+00 14 Mn++ 0.8322524E-01 0.1304620E-08 0.8322524E-01 0.0000000E+00 15 HPO4-- 0.2840436E-01 0.2383512E-07 0.2840434E-01 0.0000000E+00 Chg. balance for solid moles: -.8583E-14 Mass of aqueous solution: 0.517321E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 4799.9990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 6.009 0.779 1576. 3.197 30.05 604.8 andradite 0.5323 -0.274 270.5 2.432 5.158 70.27 grossular 0.1289 -0.890 58.05 1.764 1.107 16.15 apatite-OH 0.9468E-02 -2.024 4.756 0.677 0.9070E-01 1.511 clinochlore 0.6820 -0.166 379.0 2.579 7.228 144.2 daphnite 0.1974 -0.705 140.9 2.149 2.686 42.69 chlorite-Mn 0.1665E-01 -1.779 11.80 1.072 0.2250 3.761 diopside 0.2518 -0.599 54.53 1.737 1.040 16.67 hedenbergite 0.6530E-01 -1.185 16.20 1.210 0.3090 4.438 microcline 0.8936 -0.049 248.7 2.396 4.743 97.16 stilbite 3.091 0.490 2178. 3.338 41.54 1016. stilpnomelane-Fe 0.2509 -0.600 270.5 2.432 5.158 93.43 tr.625ac.25prg.125 0.4081E-01 -1.389 34.89 1.543 0.6653 11.23 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8051E+00 0.8051E+00 1.0000 -0.094 grossular 0.1949E+00 0.1949E+00 1.0000 -0.710 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.7611E+00 0.7611E+00 1.0000 -0.119 daphnite 0.2203E+00 0.2203E+00 1.0000 -0.657 chlorite-Mn 0.1858E-01 0.1858E-01 1.0000 -1.731 diopside 0.7941E+00 0.7941E+00 1.0000 -0.100 hedenbergite 0.2059E+00 0.2059E+00 1.0000 -0.686 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 tr.625ac.25prg.125 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 5243.836532 g Volume = 2122.371730 cm3 Porosity: -10.4827% V(tot) - V(min): -.20137E+03 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 4799.9990000 g log = 3.6812 Original solution: 1000.0103000 g Original solution / Rock added: 0.21 (Water/Rock Ratio), log = -0.6812 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0709 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9534E+00 0.9853 0.1006E+01 0.1021E+01 CO2,gas 0.6108E-08 1.0067 0.6585E-08 0.6541E-08 CH4,gas 0.3243E-01 1.0123 0.3516E-01 0.3473E-01 H2,gas 0.1419E-01 1.0006 0.1521E-01 0.1520E-01 H2S,gas 0.2445E-06 0.9958 0.2608E-06 0.2619E-06 S2,gas 0.1031E-28 1.0000 0.1104E-28 0.1104E-28 CO,gas 0.2492E-13 1.0000 0.2669E-13 0.2669E-13 SO3,gas 0.1270E-47 1.0000 0.1360E-47 0.1360E-47 SO2,gas 0.7511E-27 1.0000 0.8043E-27 0.8043E-27 HCl,gas 0.4991E-17 1.0000 0.5345E-17 0.5345E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 16 albite -0.38 -0.38 0.00 0.000 0.11184E-10 22 andradite 39.01 39.01 0.00 0.000 0.12132E-10 23 grossular 32.73 32.73 0.00 0.000 -0.12132E-10 32 apatite-OH -18.15 -18.15 0.00 0.000 0.60662E-11 46 clinochlore 39.07 39.07 0.00 0.000 0.12132E-10 47 daphnite 28.97 28.97 0.00 0.000 -0.60662E-11 48 chlorite-Mn 46.87 46.87 0.00 0.000 0.24265E-10 67 diopside 16.18 16.18 0.00 0.000 0.60662E-11 68 hedenbergite 14.21 14.21 0.00 0.000 0.60662E-11 116 microcline -2.49 -2.49 0.00 0.000 0.15165E-11 163 stilbite -7.52 -7.52 0.00 0.000 0.15165E-10 164 stilpnomelane-Fe 13.02 13.02 0.00 0.000 -0.27298E-10 245 tr.625ac.25prg.125 45.16 45.16 0.00 0.000 0.84926E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -16.54 -9.88 -3.293 0.16871E+05 -8.181 3 CH4,gas 4.54 1.39 -3.15 -0.788 0.53836E+04 -1.454 4 H2,gas 8.00 4.48 -3.52 -2.010 0.60051E+04 -1.818 5 H2S,gas -6.23 -14.51 -8.28 -4.141 0.14142E+05 -6.584 6 S2,gas -7.34 -37.99 -30.66 -4.716 0.52344E+05 -28.957 7 CO,gas 3.21 -12.06 -15.27 -4.699 0.26078E+05 -13.574 8 SO3,gas 17.12 -32.44 -49.57 -12.391 0.84632E+05 -47.867 9 SO2,gas 0.83 -27.96 -28.79 -7.678 0.49164E+05 -27.095 10 HCl,gas 5.19 -13.78 -18.97 -9.486 0.32393E+05 -17.272 11 acmite 7.71 6.53 -1.18 -0.123 0.20175E+04 15 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 19 spessartine 24.46 19.73 -4.73 -0.236 0.80712E+04 20 analcite 3.32 2.77 -0.55 -0.061 0.93625E+03 26 annite 20.12 17.72 -2.40 -0.134 0.41064E+04 27 phlogopite 27.06 25.40 -1.67 -0.093 0.28489E+04 29 anorthite 12.71 8.26 -4.45 -0.342 0.75903E+04 35 aragonite 0.97 -3.44 -4.41 -1.468 0.75218E+04 36 brucite 12.57 9.29 -3.27 -0.655 0.55909E+04 37 calcite 0.81 -3.44 -4.25 -1.417 0.72576E+04 38 carnegieite-low 9.02 5.93 -3.09 -0.442 0.52801E+04 39 carnegieite-high 10.09 5.93 -4.16 -0.595 0.71071E+04 40 carpholite-Mg 8.58 4.46 -4.12 -0.275 0.70429E+04 41 carpholite-Fe 6.71 1.90 -4.81 -0.321 0.82207E+04 42 celadonite 5.34 3.65 -1.69 -0.099 0.28879E+04 43 celadonite-Fe 3.88 1.09 -2.79 -0.164 0.47561E+04 44 chrysotile 23.89 21.57 -2.32 -0.194 0.39692E+04 49 chlorite-Al-free 47.17 43.14 -4.04 -0.168 0.68936E+04 51 chloritoid-Fe 9.17 5.06 -4.12 -0.275 0.70315E+04 52 chloritoid-Mn 11.40 7.56 -3.84 -0.256 0.65550E+04 54 coesite -2.38 -3.16 -0.78 -0.260 0.13341E+04 61 cristobalite -2.56 -3.16 -0.60 -0.199 0.10195E+04 63 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71234E+04 65 diaspore 2.87 0.74 -2.13 -0.356 0.36450E+04 66 diamond -3.10 -7.57 -4.47 -1.278 0.76367E+04 71 enstatite 17.26 12.27 -4.99 -0.499 0.85226E+04 73 clinoenstatite 17.17 12.27 -4.89 -0.489 0.83541E+04 75 epidote 24.67 22.70 -1.97 -0.095 0.33585E+04 76 clinozoisite 22.81 18.95 -3.86 -0.175 0.65869E+04 77 epidote-Fe 29.84 26.46 -3.38 -0.176 0.57768E+04 78 fayalite 14.05 10.31 -3.73 -0.533 0.63743E+04 79 ferrosilite 11.15 7.16 -3.99 -0.399 0.68202E+04 83 gibbsite 4.08 0.74 -3.34 -0.477 0.57035E+04 84 glaucophane 22.97 20.80 -2.17 -0.059 0.37133E+04 85 glaucophane-Fe 17.28 13.12 -4.15 -0.112 0.70919E+04 86 graphite -3.55 -7.57 -4.03 -1.151 0.68789E+04 87 greenalite 16.14 13.89 -2.25 -0.187 0.38408E+04 90 hematite 12.57 8.99 -3.58 -0.434 0.61111E+04 91 heulandite -5.83 -7.52 -1.69 -0.077 0.28938E+04 95 jadeite 4.22 2.77 -1.44 -0.144 0.24617E+04 97 kalsilite 7.58 3.83 -3.76 -0.537 0.64126E+04 98 kaolinite -1.33 -4.84 -3.50 -0.319 0.59831E+04 101 laumontite 2.88 1.95 -0.93 -0.062 0.15935E+04 102 lawsonite 9.62 8.26 -1.35 -0.090 0.23070E+04 103 leucite 4.12 0.67 -3.45 -0.345 0.58873E+04 105 lizardite 23.24 21.57 -1.68 -0.140 0.28618E+04 107 magnetite 20.09 15.72 -4.37 -0.356 0.74536E+04 108 minnesotaite 10.39 7.58 -2.81 -0.165 0.48028E+04 112 manganosite 14.06 9.24 -4.82 -1.204 0.82242E+04 120 muscovite 2.58 -1.01 -3.59 -0.211 0.61315E+04 121 paragonite 4.24 1.09 -3.15 -0.185 0.53706E+04 122 nepheline 8.34 5.93 -2.41 -0.344 0.41125E+04 128 periclase-Fe 11.63 6.73 -4.89 -1.223 0.83523E+04 134 phlogopite-Na 29.65 27.50 -2.15 -0.119 0.36677E+04 136 prehnite 19.37 18.21 -1.16 -0.068 0.19849E+04 137 prehnite-Fe 22.50 21.96 -0.53 -0.032 0.91158E+03 138 pumpellyite-Fe 46.27 43.89 -2.38 -0.053 0.40581E+04 139 pumpellyite-Mg 48.99 46.45 -2.54 -0.057 0.43420E+04 143 pyrrhotite -4.26 -7.78 -3.52 -1.173 0.60062E+04 144 pyrrhotiteFe0.875 -6.02 -9.18 -3.16 -1.162 0.53935E+04 145 pyroxmangite 7.40 6.08 -1.31 -0.263 0.22445E+04 146 pyrophyllite -6.18 -11.15 -4.98 -0.311 0.84962E+04 147 quartz -2.99 -3.16 -0.17 -0.056 0.28680E+03 152 rhodonite 7.45 6.08 -1.36 -0.272 0.23248E+04 153 sanidine -1.28 -2.49 -1.21 -0.093 0.20677E+04 165 stilpnomelane-Mg 27.44 25.81 -1.63 -0.049 0.27804E+04 171 talc 16.49 15.25 -1.24 -0.073 0.21140E+04 174 tephroite 18.09 15.33 -2.76 -0.394 0.47128E+04 178 tridymite -2.63 -3.16 -0.53 -0.177 0.90678E+03 179 tremolite 47.87 47.42 -0.45 -0.012 0.77494E+03 180 ferroactinolite 38.45 34.62 -3.83 -0.104 0.65448E+04 181 troilite-low -4.41 -7.78 -3.37 -1.122 0.57490E+04 183 vesuvianite 223.47 218.82 -4.65 -0.036 0.79438E+04 187 wairakite 3.95 1.95 -2.00 -0.118 0.34155E+04 188 walstromite 11.51 9.94 -1.56 -0.313 0.26719E+04 189 wollastonite 10.46 9.94 -0.52 -0.103 0.88229E+03 190 pseudo-wollastonite 11.00 9.94 -1.06 -0.211 0.18021E+04 191 zoisite 22.85 18.95 -3.90 -0.177 0.66609E+04 192 akaganeite 7.75 4.49 -3.26 -0.705 0.55681E+04 199 chalcedony -2.80 -3.16 -0.35 -0.118 0.60610E+03 201 montmorillonite-Ca -2.29 -6.17 -3.88 -0.240 0.66180E+04 202 montmorillonite-K -2.24 -6.27 -4.03 -0.247 0.68816E+04 203 montmorillonite-Mg -2.48 -6.79 -4.32 -0.267 0.73678E+04 204 montmorillonite-Na -2.04 -5.57 -3.54 -0.216 0.60365E+04 205 nontronite-Ca 3.21 -0.19 -3.41 -0.221 0.58215E+04 206 nontronite-H 2.53 -2.36 -4.89 -0.328 0.83485E+04 207 nontronite-K 3.34 -0.30 -3.64 -0.233 0.62083E+04 208 nontronite-Mg 3.07 -0.82 -3.90 -0.253 0.66553E+04 209 nontronite-Na 3.52 0.40 -3.12 -0.200 0.53292E+04 224 tobermorite 9.82 7.76 -2.07 -0.564 0.35287E+04 230 alabandite -0.98 -5.27 -4.29 -1.431 0.73311E+04 233 boehmite 4.41 0.74 -3.67 -0.611 0.62619E+04 235 ferrous-oxide 9.81 6.73 -3.08 -0.769 0.52532E+04 240 silica-amorphous -2.09 -3.16 -1.07 -0.355 0.18203E+04 242 an20ab80 2.02 1.35 -0.67 -0.052 0.11472E+04 243 an25ab75 2.65 1.78 -0.87 -0.067 0.14810E+04 244 an30ab70 3.28 2.21 -1.07 -0.082 0.18244E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 100.0000000 g Current total amount of reactant added: 4799.9990000 g New total amount of reactant added: 4899.9990000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.5222E-10 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 12 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 4899.9990000 Water: Moles liquid = 0.2811E+02 kg liquid = 0.5064E+00 Moles total = -.5915E+01 kg total = -.1066E+00 Activity = 1.0000 Stoichiometric ionic strength = .1142906E-01 Osmotic coef. = 0.9685 True ionic strength = .2009494E-01 Chg. balance for total moles = 0.5222E-10 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.88628E-10 -10.0524 0.74452E-10 -10.1281 0.84005E+00 -0.0757 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.27122E-03 -3.5667 0.22647E-03 -3.6450 0.83498E+00 -0.0783 4 SO4-- 0.12754E-11 -11.8944 0.66167E-12 -12.1794 0.51879E+00 -0.2850 5 HCO3- 0.47184E-06 -6.3262 0.39456E-06 -6.4039 0.83621E+00 -0.0777 6 HS- 0.50357E-04 -4.2979 0.42053E-04 -4.3762 0.83511E+00 -0.0783 7 Al+++ 0.98156E-29 -29.0081 0.22625E-29 -29.6454 0.23050E+00 -0.6373 8 H4SiO4 0.69598E-03 -3.1574 0.69598E-03 -3.1574 0.10000E+01 0.0000 9 Ca++ 0.13608E-06 -6.8662 0.70077E-07 -7.1544 0.51497E+00 -0.2882 10 Mg++ 0.21289E-10 -10.6718 0.10913E-10 -10.9621 0.51261E+00 -0.2902 11 Fe++ 0.58676E-13 -13.2315 0.30111E-13 -13.5213 0.51317E+00 -0.2897 12 K+ 0.15711E-03 -3.8038 0.13141E-03 -3.8814 0.83641E+00 -0.0776 13 Na+ 0.19936E-01 -1.7004 0.16644E-01 -1.7788 0.83483E+00 -0.0784 14 Mn++ 0.18823E-10 -10.7253 0.96673E-11 -11.0147 0.51360E+00 -0.2894 15 HPO4-- 0.45046E-07 -7.3463 0.23373E-07 -7.6313 0.51886E+00 -0.2849 16 HSiO3- 0.10454E-01 -1.9807 0.87287E-02 -2.0591 0.83498E+00 -0.0783 17 Ca(HSiO3)+ 0.16651E-07 -7.7786 0.13930E-07 -7.8560 0.83659E+00 -0.0775 18 Mg(HSiO3)+ 0.32271E-11 -11.4912 0.26998E-11 -11.5687 0.83659E+00 -0.0775 19 NaHSiO3,aq 0.23496E-02 -2.6290 0.23496E-02 -2.6290 0.10000E+01 0.0000 20 AlO+ 0.66376E-16 -16.1780 0.55529E-16 -16.2555 0.83659E+00 -0.0775 22 HAlO2,aq 0.14853E-09 -9.8282 0.14853E-09 -9.8282 0.10000E+01 0.0000 23 AlO2- 0.52985E-05 -5.2758 0.44162E-05 -5.3550 0.83347E+00 -0.0791 24 CH4,aq 0.24444E-04 -4.6118 0.24359E-04 -4.6133 0.99652E+00 -0.0015 25 C2H6,aq 0.87886E-14 -14.0561 0.87579E-14 -14.0576 0.99652E+00 -0.0015 29 CO,aq 0.18263E-16 -16.7384 0.18263E-16 -16.7384 0.10000E+01 0.0000 30 CO2,aq 0.62988E-10 -10.2007 0.62769E-10 -10.2023 0.99652E+00 -0.0015 31 CO3-2 0.89416E-06 -6.0486 0.46289E-06 -6.3345 0.51769E+00 -0.2859 32 CaCO3,aq 0.40674E-09 -9.3907 0.40674E-09 -9.3907 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.84365E-12 -12.0738 0.70579E-12 -12.1513 0.83659E+00 -0.0775 34 CaCl+ 0.30700E-10 -10.5129 0.25683E-10 -10.5904 0.83659E+00 -0.0775 35 CaCl2,aq 0.13818E-14 -14.8595 0.13818E-14 -14.8595 0.10000E+01 0.0000 36 CaOH+ 0.80185E-07 -7.0959 0.67082E-07 -7.1734 0.83659E+00 -0.0775 37 CaSO4,aq 0.14724E-16 -16.8320 0.14724E-16 -16.8320 0.10000E+01 0.0000 38 HCl,aq 0.30897E-14 -14.5101 0.30897E-14 -14.5101 0.10000E+01 0.0000 43 FeCl+ 0.12902E-16 -16.8893 0.10794E-16 -16.9668 0.83659E+00 -0.0775 46 FeO,aq 0.21113E-09 -9.6755 0.21113E-09 -9.6755 0.10000E+01 0.0000 47 FeOH+ 0.15736E-10 -10.8031 0.13165E-10 -10.8806 0.83659E+00 -0.0775 48 HFeO2- 0.35534E-07 -7.4494 0.29671E-07 -7.5277 0.83498E+00 -0.0783 49 FeO+ 0.11029E-16 -16.9575 0.92265E-17 -17.0350 0.83659E+00 -0.0775 51 FeO2- 0.40791E-09 -9.3894 0.34059E-09 -9.4678 0.83498E+00 -0.0783 52 HFeO2,aq 0.32251E-11 -11.4915 0.32251E-11 -11.4915 0.10000E+01 0.0000 53 H2,aq 0.11623E-04 -4.9347 0.11583E-04 -4.9362 0.99652E+00 -0.0015 54 KCl,aq 0.53936E-09 -9.2681 0.53936E-09 -9.2681 0.10000E+01 0.0000 56 KOH,aq 0.75375E-06 -6.1228 0.75375E-06 -6.1228 0.10000E+01 0.0000 57 KSO4- 0.16159E-14 -14.7916 0.13492E-14 -14.8699 0.83498E+00 -0.0783 58 MgCO3,aq 0.15877E-13 -13.7992 0.15877E-13 -13.7992 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.13424E-15 -15.8721 0.11231E-15 -15.9496 0.83659E+00 -0.0775 60 MgCl+ 0.43330E-14 -14.3632 0.36250E-14 -14.4407 0.83659E+00 -0.0775 61 MgOH+ 0.69097E-10 -10.1605 0.57806E-10 -10.2380 0.83659E+00 -0.0775 63 MnO,aq 0.18061E-08 -8.7433 0.18061E-08 -8.7433 0.10000E+01 0.0000 64 MnOH+ 0.46933E-09 -9.3285 0.39264E-09 -9.4060 0.83659E+00 -0.0775 65 MnO2-2 0.20888E-10 -10.6801 0.10814E-10 -10.9660 0.51769E+00 -0.2859 66 HMnO2- 0.21124E-09 -9.6752 0.17638E-09 -9.7535 0.83498E+00 -0.0783 69 MnCl+ 0.16115E-13 -13.7928 0.13482E-13 -13.8703 0.83659E+00 -0.0775 71 NaCl,aq 0.12491E-05 -5.9034 0.12491E-05 -5.9034 0.10000E+01 0.0000 72 NaOH,aq 0.96047E-04 -4.0175 0.96047E-04 -4.0175 0.10000E+01 0.0000 74 OH- 0.93109E-02 -2.0310 0.77604E-02 -2.1101 0.83347E+00 -0.0791 79 HPO3-2 0.16296E-14 -14.7879 0.84364E-15 -15.0738 0.51769E+00 -0.2859 81 H2PO3- 0.15085E-18 -18.8215 0.12595E-18 -18.8998 0.83498E+00 -0.0783 82 H3PO4,aq 0.90610E-18 -18.0428 0.90610E-18 -18.0428 0.10000E+01 0.0000 83 H2PO4- 0.38408E-10 -10.4156 0.32101E-10 -10.4935 0.83578E+00 -0.0779 84 PO4-3 0.10578E-08 -8.9756 0.25613E-09 -9.5915 0.24213E+00 -0.6159 88 HP2O7-3 0.93915E-18 -18.0273 0.21670E-18 -18.6641 0.23074E+00 -0.6369 89 P2O7-4 0.90534E-17 -17.0432 0.69532E-18 -18.1578 0.76802E-01 -1.1146 90 H2S,aq 0.97104E-08 -8.0128 0.96766E-08 -8.0143 0.99652E+00 -0.0015 91 S2-2 0.65352E-14 -14.1847 0.33832E-14 -14.4707 0.51769E+00 -0.2859 97 SO3-2 0.18963E-17 -17.7221 0.99591E-18 -18.0018 0.52519E+00 -0.2797 99 HSO4- 0.56693E-19 -19.2465 0.47475E-19 -19.3235 0.83741E+00 -0.0771 Charge balance for all species = 0.1031E-09 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.8862764E-10 -.2223622E-01 -.2237375E+02 0.0000 2 H2O 0.1000000E+01 0.5550490E+02 0.9981960E+06 0.0000 3 Cl- 0.2712231E-03 0.2724728E-03 0.9643156E+01 6.4831 4 SO4-- 0.1275404E-11 -.2735001E-04 -.2622710E+01 8.0769 5 HCO3- 0.4718416E-06 0.2581077E-04 0.1572158E+01 3.7242 6 HS- 0.5035678E-04 0.7771650E-04 0.2565764E+01 5.7519 7 Al+++ 0.9815570E-29 0.5298658E-05 0.1427168E+00 0.7390 8 H4SiO4 0.6959790E-03 0.1349933E-01 0.1295233E+04 -3.1574 9 Ca++ 0.1360808E-06 0.2333558E-06 0.9336145E-02 13.1018 10 Mg++ 0.2128915E-10 0.9363292E-10 0.2272439E-05 9.2942 11 Fe++ 0.5867649E-13 0.3617243E-07 0.2016603E-02 6.7350 12 K+ 0.1571084E-03 0.1578627E-03 0.6161998E+01 6.2467 13 Na+ 0.1993638E-01 0.2238331E-01 0.5136917E+03 8.3494 14 Mn++ 0.1882267E-10 0.2526420E-08 0.1385548E-03 9.2416 15 HPO4-- 0.4504566E-07 0.4614189E-07 0.4420939E-02 12.6250 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.8113670E+02 -.1125993E-01 -.8112544E+02 0.0000000E+00 2 H2O -.5915248E+01 0.2810645E+02 -.3402169E+02 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.1358212E+00 -.1384944E-04 0.1358350E+00 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.1357957E+00 0.3935391E-04 -.1358350E+00 0.0000000E+00 7 Al+++ 0.1597763E+02 0.2683123E-05 0.1597763E+02 0.0000000E+00 8 H4SiO4 0.5102263E+02 0.6835759E-02 0.5101579E+02 0.0000000E+00 9 Ca++ 0.5635712E+01 0.1181662E-06 0.5635712E+01 0.0000000E+00 10 Mg++ 0.3888888E+01 0.4741363E-10 0.3888888E+01 0.0000000E+00 11 Fe++ 0.3493741E+01 0.1831691E-07 0.3493741E+01 0.0000000E+00 12 K+ 0.1040339E+01 0.7993817E-04 0.1040260E+01 0.0000000E+00 13 Na+ 0.6150853E+01 0.1133441E-01 0.6139518E+01 0.0000000E+00 14 Mn++ 0.8495910E-01 0.1279323E-08 0.8495910E-01 0.0000000E+00 15 HPO4-- 0.2899612E-01 0.2336523E-07 0.2899610E-01 0.0000000E+00 Chg. balance for solid moles: 0.2887E-14 Mass of aqueous solution: 0.507261E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 4899.9990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 6.134 0.788 1609. 3.206 30.05 617.5 andradite 0.5433 -0.265 276.1 2.441 5.158 71.74 grossular 0.1316 -0.881 59.26 1.773 1.107 16.49 apatite-OH 0.9665E-02 -2.015 4.855 0.686 0.9070E-01 1.543 clinochlore 0.6961 -0.157 386.9 2.588 7.228 147.2 daphnite 0.2015 -0.696 143.8 2.158 2.686 43.57 chlorite-Mn 0.1699E-01 -1.770 12.05 1.081 0.2250 3.839 diopside 0.2573 -0.590 55.71 1.746 1.041 17.03 hedenbergite 0.6672E-01 -1.176 16.55 1.219 0.3092 4.534 microcline 0.9122 -0.040 253.9 2.405 4.743 99.18 stilbite 3.155 0.499 2224. 3.347 41.54 1037. stilpnomelane-Fe 0.2561 -0.592 276.1 2.441 5.158 95.37 tr.625ac.25prg.125 0.4165E-01 -1.380 35.60 1.551 0.6650 11.46 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8051E+00 0.8051E+00 1.0000 -0.094 grossular 0.1949E+00 0.1949E+00 1.0000 -0.710 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.7611E+00 0.7611E+00 1.0000 -0.119 daphnite 0.2203E+00 0.2203E+00 1.0000 -0.657 chlorite-Mn 0.1858E-01 0.1858E-01 1.0000 -1.731 diopside 0.7941E+00 0.7941E+00 1.0000 -0.100 hedenbergite 0.2059E+00 0.2059E+00 1.0000 -0.686 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 tr.625ac.25prg.125 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 5353.087197 g Volume = 2166.574794 cm3 Porosity: -10.4832% V(tot) - V(min): -.20558E+03 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 4899.9990000 g log = 3.6902 Original solution: 1000.0103000 g Original solution / Rock added: 0.20 (Water/Rock Ratio), log = -0.6902 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0716 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9528E+00 0.9853 0.1006E+01 0.1021E+01 CO2,gas 0.6225E-08 1.0067 0.6716E-08 0.6671E-08 CH4,gas 0.3305E-01 1.0122 0.3585E-01 0.3542E-01 H2,gas 0.1418E-01 1.0006 0.1521E-01 0.1520E-01 H2S,gas 0.2493E-06 0.9958 0.2660E-06 0.2671E-06 S2,gas 0.1072E-28 1.0000 0.1149E-28 0.1149E-28 CO,gas 0.2540E-13 1.0000 0.2722E-13 0.2722E-13 SO3,gas 0.1294E-47 1.0000 0.1387E-47 0.1387E-47 SO2,gas 0.7656E-27 1.0000 0.8204E-27 0.8204E-27 HCl,gas 0.5087E-17 1.0000 0.5452E-17 0.5452E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 16 albite -0.38 -0.38 0.00 0.000 -0.94784E-12 22 andradite 39.01 39.01 0.00 0.000 0.12132E-10 23 grossular 32.73 32.73 0.00 0.000 -0.12132E-10 32 apatite-OH -18.15 -18.15 0.00 0.000 0.00000E+00 46 clinochlore 39.07 39.07 0.00 0.000 -0.24265E-10 47 daphnite 28.97 28.97 0.00 0.000 -0.42463E-10 48 chlorite-Mn 46.87 46.87 0.00 0.000 0.00000E+00 67 diopside 16.18 16.18 0.00 0.000 0.60662E-11 68 hedenbergite 14.21 14.21 0.00 0.000 -0.60662E-11 116 microcline -2.49 -2.49 0.00 0.000 0.13649E-10 163 stilbite -7.52 -7.52 0.00 0.000 0.15165E-10 164 stilpnomelane-Fe 13.02 13.02 0.00 0.000 -0.27298E-10 245 tr.625ac.25prg.125 45.16 45.16 0.00 0.000 0.12132E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -16.53 -9.87 -3.291 0.16856E+05 -8.173 3 CH4,gas 4.54 1.40 -3.14 -0.786 0.53690E+04 -1.445 4 H2,gas 8.00 4.48 -3.52 -2.010 0.60051E+04 -1.818 5 H2S,gas -6.23 -14.50 -8.27 -4.137 0.14128E+05 -6.575 6 S2,gas -7.34 -37.97 -30.64 -4.714 0.52315E+05 -28.940 7 CO,gas 3.21 -12.05 -15.26 -4.697 0.26063E+05 -13.565 8 SO3,gas 17.12 -32.44 -49.56 -12.389 0.84617E+05 -47.858 9 SO2,gas 0.83 -27.95 -28.78 -7.676 0.49149E+05 -27.086 10 HCl,gas 5.19 -13.77 -18.96 -9.481 0.32378E+05 -17.263 11 acmite 7.71 6.53 -1.18 -0.123 0.20175E+04 15 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 19 spessartine 24.46 19.73 -4.73 -0.236 0.80711E+04 20 analcite 3.32 2.77 -0.55 -0.061 0.93625E+03 26 annite 20.12 17.72 -2.40 -0.134 0.41064E+04 27 phlogopite 27.06 25.40 -1.67 -0.093 0.28489E+04 29 anorthite 12.71 8.26 -4.45 -0.342 0.75903E+04 35 aragonite 0.97 -3.43 -4.40 -1.466 0.75073E+04 36 brucite 12.57 9.29 -3.27 -0.655 0.55909E+04 37 calcite 0.81 -3.43 -4.24 -1.414 0.72430E+04 38 carnegieite-low 9.02 5.93 -3.09 -0.442 0.52801E+04 39 carnegieite-high 10.09 5.93 -4.16 -0.595 0.71071E+04 40 carpholite-Mg 8.58 4.46 -4.12 -0.275 0.70429E+04 41 carpholite-Fe 6.71 1.90 -4.81 -0.321 0.82207E+04 42 celadonite 5.34 3.65 -1.69 -0.099 0.28879E+04 43 celadonite-Fe 3.88 1.09 -2.79 -0.164 0.47561E+04 44 chrysotile 23.89 21.57 -2.32 -0.194 0.39692E+04 49 chlorite-Al-free 47.17 43.14 -4.04 -0.168 0.68936E+04 51 chloritoid-Fe 9.17 5.06 -4.12 -0.275 0.70316E+04 52 chloritoid-Mn 11.40 7.56 -3.84 -0.256 0.65549E+04 54 coesite -2.38 -3.16 -0.78 -0.260 0.13341E+04 61 cristobalite -2.56 -3.16 -0.60 -0.199 0.10195E+04 63 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71234E+04 65 diaspore 2.87 0.74 -2.13 -0.356 0.36450E+04 66 diamond -3.10 -7.57 -4.46 -1.275 0.76221E+04 71 enstatite 17.26 12.27 -4.99 -0.499 0.85226E+04 73 clinoenstatite 17.17 12.27 -4.89 -0.489 0.83541E+04 75 epidote 24.67 22.70 -1.97 -0.095 0.33585E+04 76 clinozoisite 22.81 18.95 -3.86 -0.175 0.65869E+04 77 epidote-Fe 29.84 26.46 -3.38 -0.176 0.57768E+04 78 fayalite 14.05 10.31 -3.73 -0.533 0.63743E+04 79 ferrosilite 11.15 7.16 -3.99 -0.399 0.68202E+04 83 gibbsite 4.08 0.74 -3.34 -0.477 0.57035E+04 84 glaucophane 22.97 20.80 -2.17 -0.059 0.37134E+04 85 glaucophane-Fe 17.28 13.12 -4.15 -0.112 0.70919E+04 86 graphite -3.55 -7.57 -4.02 -1.149 0.68644E+04 87 greenalite 16.14 13.89 -2.25 -0.187 0.38408E+04 90 hematite 12.57 8.99 -3.58 -0.434 0.61111E+04 91 heulandite -5.83 -7.52 -1.69 -0.077 0.28938E+04 95 jadeite 4.22 2.77 -1.44 -0.144 0.24617E+04 97 kalsilite 7.58 3.83 -3.76 -0.537 0.64126E+04 98 kaolinite -1.33 -4.84 -3.50 -0.319 0.59831E+04 101 laumontite 2.88 1.95 -0.93 -0.062 0.15935E+04 102 lawsonite 9.62 8.26 -1.35 -0.090 0.23070E+04 103 leucite 4.12 0.67 -3.45 -0.345 0.58873E+04 105 lizardite 23.24 21.57 -1.68 -0.140 0.28618E+04 107 magnetite 20.09 15.72 -4.37 -0.356 0.74536E+04 108 minnesotaite 10.39 7.58 -2.81 -0.165 0.48028E+04 112 manganosite 14.06 9.24 -4.82 -1.204 0.82241E+04 120 muscovite 2.58 -1.01 -3.59 -0.211 0.61315E+04 121 paragonite 4.24 1.09 -3.15 -0.185 0.53706E+04 122 nepheline 8.34 5.93 -2.41 -0.344 0.41125E+04 128 periclase-Fe 11.63 6.73 -4.89 -1.223 0.83523E+04 134 phlogopite-Na 29.65 27.50 -2.15 -0.119 0.36677E+04 136 prehnite 19.37 18.21 -1.16 -0.068 0.19849E+04 137 prehnite-Fe 22.50 21.96 -0.53 -0.032 0.91158E+03 138 pumpellyite-Fe 46.27 43.89 -2.38 -0.053 0.40581E+04 139 pumpellyite-Mg 48.99 46.45 -2.54 -0.057 0.43420E+04 143 pyrrhotite -4.26 -7.77 -3.51 -1.170 0.59916E+04 144 pyrrhotiteFe0.875 -6.02 -9.17 -3.15 -1.159 0.53788E+04 145 pyroxmangite 7.40 6.08 -1.31 -0.263 0.22445E+04 146 pyrophyllite -6.18 -11.15 -4.98 -0.311 0.84962E+04 147 quartz -2.99 -3.16 -0.17 -0.056 0.28680E+03 152 rhodonite 7.45 6.08 -1.36 -0.272 0.23248E+04 153 sanidine -1.28 -2.49 -1.21 -0.093 0.20677E+04 165 stilpnomelane-Mg 27.44 25.81 -1.63 -0.049 0.27804E+04 171 talc 16.49 15.25 -1.24 -0.073 0.21140E+04 174 tephroite 18.09 15.33 -2.76 -0.394 0.47128E+04 178 tridymite -2.63 -3.16 -0.53 -0.177 0.90678E+03 179 tremolite 47.87 47.42 -0.45 -0.012 0.77494E+03 180 ferroactinolite 38.45 34.62 -3.83 -0.104 0.65448E+04 181 troilite-low -4.41 -7.77 -3.36 -1.119 0.57344E+04 183 vesuvianite 223.47 218.82 -4.65 -0.036 0.79438E+04 187 wairakite 3.95 1.95 -2.00 -0.118 0.34155E+04 188 walstromite 11.51 9.94 -1.56 -0.313 0.26719E+04 189 wollastonite 10.46 9.94 -0.52 -0.103 0.88229E+03 190 pseudo-wollastonite 11.00 9.94 -1.06 -0.211 0.18021E+04 191 zoisite 22.85 18.95 -3.90 -0.177 0.66609E+04 192 akaganeite 7.75 4.49 -3.26 -0.705 0.55681E+04 199 chalcedony -2.80 -3.16 -0.35 -0.118 0.60610E+03 201 montmorillonite-Ca -2.29 -6.17 -3.88 -0.240 0.66180E+04 202 montmorillonite-K -2.24 -6.27 -4.03 -0.247 0.68816E+04 203 montmorillonite-Mg -2.48 -6.79 -4.32 -0.267 0.73678E+04 204 montmorillonite-Na -2.04 -5.57 -3.54 -0.216 0.60365E+04 205 nontronite-Ca 3.21 -0.19 -3.41 -0.221 0.58215E+04 206 nontronite-H 2.53 -2.36 -4.89 -0.328 0.83485E+04 207 nontronite-K 3.34 -0.30 -3.64 -0.233 0.62083E+04 208 nontronite-Mg 3.07 -0.82 -3.90 -0.253 0.66553E+04 209 nontronite-Na 3.52 0.40 -3.12 -0.200 0.53292E+04 224 tobermorite 9.82 7.76 -2.07 -0.564 0.35287E+04 230 alabandite -0.98 -5.26 -4.28 -1.428 0.73164E+04 233 boehmite 4.41 0.74 -3.67 -0.611 0.62619E+04 235 ferrous-oxide 9.81 6.73 -3.08 -0.769 0.52532E+04 240 silica-amorphous -2.09 -3.16 -1.07 -0.355 0.18203E+04 242 an20ab80 2.02 1.35 -0.67 -0.052 0.11472E+04 243 an25ab75 2.65 1.78 -0.87 -0.067 0.14810E+04 244 an30ab70 3.28 2.21 -1.07 -0.082 0.18244E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 100.0000000 g Current total amount of reactant added: 4899.9990000 g New total amount of reactant added: 4999.9990000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.5221E-10 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 12 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 4999.9990000 Water: Moles liquid = 0.2755E+02 kg liquid = 0.4963E+00 Moles total = -.7169E+01 kg total = -.1291E+00 Activity = 1.0000 Stoichiometric ionic strength = .1143362E-01 Osmotic coef. = 0.9685 True ionic strength = .2009850E-01 Chg. balance for total moles = 0.5221E-10 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.88643E-10 -10.0524 0.74464E-10 -10.1281 0.84004E+00 -0.0757 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.27671E-03 -3.5580 0.23105E-03 -3.6363 0.83497E+00 -0.0783 4 SO4-- 0.13010E-11 -11.8857 0.67494E-12 -12.1707 0.51877E+00 -0.2850 5 HCO3- 0.48132E-06 -6.3176 0.40248E-06 -6.3953 0.83620E+00 -0.0777 6 HS- 0.51376E-04 -4.2892 0.42904E-04 -4.3675 0.83510E+00 -0.0783 7 Al+++ 0.98214E-29 -29.0078 0.22636E-29 -29.6452 0.23048E+00 -0.6374 8 H4SiO4 0.69598E-03 -3.1574 0.69598E-03 -3.1574 0.10000E+01 0.0000 9 Ca++ 0.13613E-06 -6.8660 0.70100E-07 -7.1543 0.51495E+00 -0.2882 10 Mg++ 0.21297E-10 -10.6717 0.10917E-10 -10.9619 0.51258E+00 -0.2902 11 Fe++ 0.58699E-13 -13.2314 0.30121E-13 -13.5211 0.51315E+00 -0.2898 12 K+ 0.15714E-03 -3.8037 0.13143E-03 -3.8813 0.83640E+00 -0.0776 13 Na+ 0.19940E-01 -1.7003 0.16646E-01 -1.7787 0.83482E+00 -0.0784 14 Mn++ 0.18830E-10 -10.7251 0.96708E-11 -11.0145 0.51357E+00 -0.2894 15 HPO4-- 0.45033E-07 -7.3465 0.23365E-07 -7.6314 0.51884E+00 -0.2850 16 HSiO3- 0.10452E-01 -1.9808 0.87272E-02 -2.0591 0.83497E+00 -0.0783 17 Ca(HSiO3)+ 0.16654E-07 -7.7785 0.13933E-07 -7.8560 0.83658E+00 -0.0775 18 Mg(HSiO3)+ 0.32277E-11 -11.4911 0.27002E-11 -11.5686 0.83658E+00 -0.0775 19 NaHSiO3,aq 0.23496E-02 -2.6290 0.23496E-02 -2.6290 0.10000E+01 0.0000 20 AlO+ 0.66388E-16 -16.1779 0.55538E-16 -16.2554 0.83658E+00 -0.0775 22 HAlO2,aq 0.14853E-09 -9.8282 0.14853E-09 -9.8282 0.10000E+01 0.0000 23 AlO2- 0.52977E-05 -5.2759 0.44154E-05 -5.3550 0.83346E+00 -0.0791 24 CH4,aq 0.24939E-04 -4.6031 0.24852E-04 -4.6046 0.99651E+00 -0.0015 25 C2H6,aq 0.91480E-14 -14.0387 0.91161E-14 -14.0402 0.99651E+00 -0.0015 29 CO,aq 0.18633E-16 -16.7297 0.18633E-16 -16.7297 0.10000E+01 0.0000 30 CO2,aq 0.64264E-10 -10.1920 0.64040E-10 -10.1936 0.99651E+00 -0.0015 31 CO3-2 0.91201E-06 -6.0400 0.47211E-06 -6.3260 0.51766E+00 -0.2860 32 CaCO3,aq 0.41498E-09 -9.3820 0.41498E-09 -9.3820 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.86088E-12 -12.0651 0.72020E-12 -12.1425 0.83658E+00 -0.0775 34 CaCl+ 0.31331E-10 -10.5040 0.26211E-10 -10.5815 0.83658E+00 -0.0775 35 CaCl2,aq 0.14388E-14 -14.8420 0.14388E-14 -14.8420 0.10000E+01 0.0000 36 CaOH+ 0.80199E-07 -7.0958 0.67093E-07 -7.1733 0.83658E+00 -0.0775 37 CaSO4,aq 0.15024E-16 -16.8232 0.15024E-16 -16.8232 0.10000E+01 0.0000 38 HCl,aq 0.31527E-14 -14.5013 0.31527E-14 -14.5013 0.10000E+01 0.0000 43 FeCl+ 0.13167E-16 -16.8805 0.11015E-16 -16.9580 0.83658E+00 -0.0775 46 FeO,aq 0.21113E-09 -9.6755 0.21113E-09 -9.6755 0.10000E+01 0.0000 47 FeOH+ 0.15739E-10 -10.8030 0.13167E-10 -10.8805 0.83658E+00 -0.0775 48 HFeO2- 0.35529E-07 -7.4494 0.29666E-07 -7.5277 0.83497E+00 -0.0783 49 FeO+ 0.11031E-16 -16.9574 0.92281E-17 -17.0349 0.83658E+00 -0.0775 51 FeO2- 0.40784E-09 -9.3895 0.34054E-09 -9.4678 0.83497E+00 -0.0783 52 HFeO2,aq 0.32251E-11 -11.4915 0.32251E-11 -11.4915 0.10000E+01 0.0000 53 H2,aq 0.11623E-04 -4.9347 0.11583E-04 -4.9362 0.99651E+00 -0.0015 54 KCl,aq 0.55036E-09 -9.2594 0.55036E-09 -9.2594 0.10000E+01 0.0000 56 KOH,aq 0.75375E-06 -6.1228 0.75375E-06 -6.1228 0.10000E+01 0.0000 57 KSO4- 0.16486E-14 -14.7829 0.13765E-14 -14.8612 0.83497E+00 -0.0783 58 MgCO3,aq 0.16198E-13 -13.7905 0.16198E-13 -13.7905 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.13699E-15 -15.8633 0.11460E-15 -15.9408 0.83658E+00 -0.0775 60 MgCl+ 0.44221E-14 -14.3544 0.36995E-14 -14.4319 0.83658E+00 -0.0775 61 MgOH+ 0.69109E-10 -10.1605 0.57815E-10 -10.2380 0.83658E+00 -0.0775 63 MnO,aq 0.18062E-08 -8.7432 0.18062E-08 -8.7432 0.10000E+01 0.0000 64 MnOH+ 0.46943E-09 -9.3284 0.39272E-09 -9.4059 0.83658E+00 -0.0775 65 MnO2-2 0.20883E-10 -10.6802 0.10810E-10 -10.9662 0.51766E+00 -0.2860 66 HMnO2- 0.21121E-09 -9.6753 0.17636E-09 -9.7536 0.83497E+00 -0.0783 69 MnCl+ 0.16447E-13 -13.7839 0.13759E-13 -13.8614 0.83658E+00 -0.0775 71 NaCl,aq 0.12746E-05 -5.8946 0.12746E-05 -5.8946 0.10000E+01 0.0000 72 NaOH,aq 0.96047E-04 -4.0175 0.96047E-04 -4.0175 0.10000E+01 0.0000 74 OH- 0.93095E-02 -2.0311 0.77591E-02 -2.1102 0.83346E+00 -0.0791 79 HPO3-2 0.16292E-14 -14.7880 0.84336E-15 -15.0740 0.51766E+00 -0.2860 81 H2PO3- 0.15082E-18 -18.8215 0.12593E-18 -18.8999 0.83497E+00 -0.0783 82 H3PO4,aq 0.90611E-18 -18.0428 0.90611E-18 -18.0428 0.10000E+01 0.0000 83 H2PO4- 0.38402E-10 -10.4156 0.32095E-10 -10.4936 0.83577E+00 -0.0779 84 PO4-3 0.10574E-08 -8.9758 0.25601E-09 -9.5918 0.24211E+00 -0.6160 88 HP2O7-3 0.93879E-18 -18.0274 0.21659E-18 -18.6644 0.23071E+00 -0.6369 89 P2O7-4 0.90491E-17 -17.0434 0.69487E-18 -18.1581 0.76788E-01 -1.1147 90 H2S,aq 0.99084E-08 -8.0040 0.98738E-08 -8.0055 0.99651E+00 -0.0015 91 S2-2 0.68025E-14 -14.1673 0.35214E-14 -14.4533 0.51766E+00 -0.2860 97 SO3-2 0.19344E-17 -17.7135 0.10159E-17 -17.9932 0.52517E+00 -0.2797 99 HSO4- 0.57840E-19 -19.2378 0.48435E-19 -19.3148 0.83740E+00 -0.0771 Charge balance for all species = 0.1053E-09 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.8864319E-10 -.2223323E-01 -.2237073E+02 0.0000 2 H2O 0.1000000E+01 0.5550490E+02 0.9981958E+06 0.0000 3 Cl- 0.2767108E-03 0.2779859E-03 0.9838269E+01 6.4918 4 SO4-- 0.1301046E-11 -.2784492E-04 -.2670169E+01 8.0854 5 HCO3- 0.4813224E-06 0.2633301E-04 0.1603968E+01 3.7328 6 HS- 0.5137567E-04 0.7923050E-04 0.2615747E+01 5.7605 7 Al+++ 0.9821442E-29 0.5297845E-05 0.1426948E+00 0.7390 8 H4SiO4 0.6959793E-03 0.1349774E-01 0.1295081E+04 -3.1574 9 Ca++ 0.1361319E-06 0.2334328E-06 0.9339226E-02 13.1018 10 Mg++ 0.2129716E-10 0.9365477E-10 0.2272969E-05 9.2942 11 Fe++ 0.5869858E-13 0.3616694E-07 0.2016297E-02 6.7350 12 K+ 0.1571361E-03 0.1578904E-03 0.6163077E+01 6.2467 13 Na+ 0.1993990E-01 0.2238686E-01 0.5137729E+03 8.3494 14 Mn++ 0.1883044E-10 0.2526564E-08 0.1385626E-03 9.2416 15 HPO4-- 0.4503297E-07 0.4612877E-07 0.4419682E-02 12.6247 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.8279255E+02 -.1103513E-01 -.8278151E+02 0.0000000E+00 2 H2O -.7168789E+01 0.2754903E+02 -.3471782E+02 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.1385925E+00 -.1382041E-04 0.1386063E+00 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.1385670E+00 0.3932488E-04 -.1386063E+00 0.0000000E+00 7 Al+++ 0.1630370E+02 0.2629506E-05 0.1630370E+02 0.0000000E+00 8 H4SiO4 0.5206390E+02 0.6699401E-02 0.5205720E+02 0.0000000E+00 9 Ca++ 0.5750727E+01 0.1158609E-06 0.5750726E+01 0.0000000E+00 10 Mg++ 0.3968253E+01 0.4648415E-10 0.3968253E+01 0.0000000E+00 11 Fe++ 0.3565042E+01 0.1795092E-07 0.3565042E+01 0.0000000E+00 12 K+ 0.1061571E+01 0.7836655E-04 0.1061493E+01 0.0000000E+00 13 Na+ 0.6276377E+01 0.1111138E-01 0.6265266E+01 0.0000000E+00 14 Mn++ 0.8669296E-01 0.1254022E-08 0.8669296E-01 0.0000000E+00 15 HPO4-- 0.2958788E-01 0.2289533E-07 0.2958785E-01 0.0000000E+00 Chg. balance for solid moles: -.2734E-14 Mass of aqueous solution: 0.497201E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 4999.9990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 6.260 0.797 1641. 3.215 30.05 630.1 andradite 0.5544 -0.256 281.7 2.450 5.158 73.20 grossular 0.1342 -0.872 60.47 1.782 1.107 16.83 apatite-OH 0.9863E-02 -2.006 4.954 0.695 0.9070E-01 1.574 clinochlore 0.7103 -0.149 394.8 2.596 7.228 150.2 daphnite 0.2056 -0.687 146.7 2.166 2.686 44.46 chlorite-Mn 0.1734E-01 -1.761 12.29 1.090 0.2250 3.917 diopside 0.2627 -0.581 56.89 1.755 1.041 17.39 hedenbergite 0.6813E-01 -1.167 16.90 1.228 0.3094 4.629 microcline 0.9308 -0.031 259.1 2.413 4.743 101.2 stilbite 3.220 0.508 2269. 3.356 41.54 1058. stilpnomelane-Fe 0.2614 -0.583 281.7 2.450 5.158 97.32 tr.625ac.25prg.125 0.4248E-01 -1.372 36.31 1.560 0.6648 11.69 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8051E+00 0.8051E+00 1.0000 -0.094 grossular 0.1949E+00 0.1949E+00 1.0000 -0.710 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.7611E+00 0.7611E+00 1.0000 -0.119 daphnite 0.2203E+00 0.2203E+00 1.0000 -0.657 chlorite-Mn 0.1858E-01 0.1858E-01 1.0000 -1.731 diopside 0.7941E+00 0.7941E+00 1.0000 -0.100 hedenbergite 0.2059E+00 0.2059E+00 1.0000 -0.686 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 tr.625ac.25prg.125 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 5462.337861 g Volume = 2210.777858 cm3 Porosity: -10.4837% V(tot) - V(min): -.20978E+03 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 4999.9990000 g log = 3.6990 Original solution: 1000.0103000 g Original solution / Rock added: 0.20 (Water/Rock Ratio), log = -0.6990 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0724 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9521E+00 0.9853 0.1006E+01 0.1021E+01 CO2,gas 0.6347E-08 1.0067 0.6852E-08 0.6806E-08 CH4,gas 0.3370E-01 1.0122 0.3658E-01 0.3614E-01 H2,gas 0.1417E-01 1.0006 0.1521E-01 0.1520E-01 H2S,gas 0.2542E-06 0.9958 0.2714E-06 0.2726E-06 S2,gas 0.1115E-28 1.0000 0.1196E-28 0.1196E-28 CO,gas 0.2589E-13 1.0000 0.2777E-13 0.2777E-13 SO3,gas 0.1320E-47 1.0000 0.1415E-47 0.1415E-47 SO2,gas 0.7807E-27 1.0000 0.8371E-27 0.8371E-27 HCl,gas 0.5188E-17 1.0000 0.5563E-17 0.5563E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 16 albite -0.38 -0.38 0.00 0.000 0.11184E-10 22 andradite 39.01 39.01 0.00 0.000 -0.24265E-10 23 grossular 32.73 32.73 0.00 0.000 0.12132E-10 32 apatite-OH -18.15 -18.15 0.00 0.000 0.00000E+00 46 clinochlore 39.07 39.07 0.00 0.000 0.48529E-10 47 daphnite 28.97 28.97 0.00 0.000 0.36397E-10 48 chlorite-Mn 46.87 46.87 0.00 0.000 0.36397E-10 67 diopside 16.18 16.18 0.00 0.000 0.00000E+00 68 hedenbergite 14.21 14.21 0.00 0.000 0.60662E-11 116 microcline -2.49 -2.49 0.00 0.000 0.15165E-11 163 stilbite -7.52 -7.52 0.00 0.000 0.15165E-10 164 stilpnomelane-Fe 13.02 13.02 0.00 0.000 -0.27298E-10 245 tr.625ac.25prg.125 45.16 45.16 0.00 0.000 0.12132E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -16.52 -9.86 -3.288 0.16841E+05 -8.164 3 CH4,gas 4.54 1.41 -3.14 -0.784 0.53542E+04 -1.437 4 H2,gas 8.00 4.48 -3.52 -2.010 0.60051E+04 -1.818 5 H2S,gas -6.23 -14.50 -8.27 -4.133 0.14113E+05 -6.566 6 S2,gas -7.34 -37.96 -30.62 -4.711 0.52285E+05 -28.922 7 CO,gas 3.21 -12.04 -15.26 -4.694 0.26048E+05 -13.556 8 SO3,gas 17.12 -32.43 -49.55 -12.387 0.84602E+05 -47.849 9 SO2,gas 0.83 -27.94 -28.78 -7.674 0.49135E+05 -27.077 10 HCl,gas 5.19 -13.76 -18.95 -9.477 0.32363E+05 -17.255 11 acmite 7.71 6.53 -1.18 -0.123 0.20175E+04 15 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 19 spessartine 24.46 19.73 -4.73 -0.236 0.80710E+04 20 analcite 3.32 2.77 -0.55 -0.061 0.93625E+03 26 annite 20.12 17.72 -2.40 -0.134 0.41064E+04 27 phlogopite 27.06 25.40 -1.67 -0.093 0.28489E+04 29 anorthite 12.71 8.26 -4.45 -0.342 0.75903E+04 35 aragonite 0.97 -3.42 -4.39 -1.463 0.74924E+04 36 brucite 12.57 9.29 -3.27 -0.655 0.55909E+04 37 calcite 0.81 -3.42 -4.23 -1.411 0.72282E+04 38 carnegieite-low 9.02 5.93 -3.09 -0.442 0.52801E+04 39 carnegieite-high 10.09 5.93 -4.16 -0.595 0.71071E+04 40 carpholite-Mg 8.58 4.46 -4.12 -0.275 0.70429E+04 41 carpholite-Fe 6.71 1.90 -4.81 -0.321 0.82207E+04 42 celadonite 5.34 3.65 -1.69 -0.099 0.28879E+04 43 celadonite-Fe 3.88 1.09 -2.79 -0.164 0.47561E+04 44 chrysotile 23.89 21.57 -2.32 -0.194 0.39692E+04 49 chlorite-Al-free 47.17 43.14 -4.04 -0.168 0.68936E+04 51 chloritoid-Fe 9.17 5.06 -4.12 -0.275 0.70316E+04 52 chloritoid-Mn 11.40 7.56 -3.84 -0.256 0.65549E+04 54 coesite -2.38 -3.16 -0.78 -0.260 0.13341E+04 61 cristobalite -2.56 -3.16 -0.60 -0.199 0.10195E+04 63 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71234E+04 65 diaspore 2.87 0.74 -2.13 -0.356 0.36450E+04 66 diamond -3.10 -7.56 -4.46 -1.273 0.76073E+04 71 enstatite 17.26 12.27 -4.99 -0.499 0.85226E+04 73 clinoenstatite 17.17 12.27 -4.89 -0.489 0.83541E+04 75 epidote 24.67 22.70 -1.97 -0.095 0.33585E+04 76 clinozoisite 22.81 18.95 -3.86 -0.175 0.65869E+04 77 epidote-Fe 29.84 26.46 -3.38 -0.176 0.57768E+04 78 fayalite 14.05 10.31 -3.73 -0.533 0.63743E+04 79 ferrosilite 11.15 7.16 -3.99 -0.399 0.68202E+04 83 gibbsite 4.08 0.74 -3.34 -0.477 0.57035E+04 84 glaucophane 22.97 20.80 -2.17 -0.059 0.37134E+04 85 glaucophane-Fe 17.28 13.12 -4.15 -0.112 0.70919E+04 86 graphite -3.55 -7.56 -4.01 -1.146 0.68495E+04 87 greenalite 16.14 13.89 -2.25 -0.187 0.38408E+04 90 hematite 12.57 8.99 -3.58 -0.434 0.61111E+04 91 heulandite -5.83 -7.52 -1.69 -0.077 0.28938E+04 95 jadeite 4.22 2.77 -1.44 -0.144 0.24617E+04 97 kalsilite 7.58 3.83 -3.76 -0.537 0.64126E+04 98 kaolinite -1.33 -4.84 -3.50 -0.319 0.59831E+04 101 laumontite 2.88 1.95 -0.93 -0.062 0.15935E+04 102 lawsonite 9.62 8.26 -1.35 -0.090 0.23070E+04 103 leucite 4.12 0.67 -3.45 -0.345 0.58873E+04 105 lizardite 23.24 21.57 -1.68 -0.140 0.28618E+04 107 magnetite 20.09 15.72 -4.37 -0.356 0.74536E+04 108 minnesotaite 10.39 7.58 -2.81 -0.165 0.48028E+04 112 manganosite 14.06 9.24 -4.82 -1.204 0.82241E+04 120 muscovite 2.58 -1.01 -3.59 -0.211 0.61315E+04 121 paragonite 4.24 1.09 -3.15 -0.185 0.53706E+04 122 nepheline 8.34 5.93 -2.41 -0.344 0.41125E+04 128 periclase-Fe 11.63 6.73 -4.89 -1.223 0.83523E+04 134 phlogopite-Na 29.65 27.50 -2.15 -0.119 0.36677E+04 136 prehnite 19.37 18.21 -1.16 -0.068 0.19849E+04 137 prehnite-Fe 22.50 21.96 -0.53 -0.032 0.91158E+03 138 pumpellyite-Fe 46.27 43.89 -2.38 -0.053 0.40581E+04 139 pumpellyite-Mg 48.99 46.45 -2.54 -0.057 0.43420E+04 143 pyrrhotite -4.26 -7.76 -3.50 -1.167 0.59766E+04 144 pyrrhotiteFe0.875 -6.02 -9.16 -3.14 -1.155 0.53638E+04 145 pyroxmangite 7.40 6.08 -1.31 -0.263 0.22445E+04 146 pyrophyllite -6.18 -11.15 -4.98 -0.311 0.84962E+04 147 quartz -2.99 -3.16 -0.17 -0.056 0.28680E+03 152 rhodonite 7.45 6.08 -1.36 -0.272 0.23247E+04 153 sanidine -1.28 -2.49 -1.21 -0.093 0.20677E+04 165 stilpnomelane-Mg 27.44 25.81 -1.63 -0.049 0.27804E+04 171 talc 16.49 15.25 -1.24 -0.073 0.21140E+04 174 tephroite 18.09 15.33 -2.76 -0.394 0.47127E+04 178 tridymite -2.63 -3.16 -0.53 -0.177 0.90678E+03 179 tremolite 47.87 47.42 -0.45 -0.012 0.77494E+03 180 ferroactinolite 38.45 34.62 -3.83 -0.104 0.65448E+04 181 troilite-low -4.41 -7.76 -3.35 -1.117 0.57194E+04 183 vesuvianite 223.47 218.82 -4.65 -0.036 0.79438E+04 187 wairakite 3.95 1.95 -2.00 -0.118 0.34155E+04 188 walstromite 11.51 9.94 -1.56 -0.313 0.26719E+04 189 wollastonite 10.46 9.94 -0.52 -0.103 0.88229E+03 190 pseudo-wollastonite 11.00 9.94 -1.06 -0.211 0.18021E+04 191 zoisite 22.85 18.95 -3.90 -0.177 0.66609E+04 192 akaganeite 7.75 4.49 -3.26 -0.705 0.55681E+04 199 chalcedony -2.80 -3.16 -0.35 -0.118 0.60610E+03 201 montmorillonite-Ca -2.29 -6.17 -3.88 -0.240 0.66180E+04 202 montmorillonite-K -2.24 -6.27 -4.03 -0.247 0.68816E+04 203 montmorillonite-Mg -2.48 -6.79 -4.32 -0.267 0.73678E+04 204 montmorillonite-Na -2.04 -5.57 -3.54 -0.216 0.60365E+04 205 nontronite-Ca 3.21 -0.19 -3.41 -0.221 0.58215E+04 206 nontronite-H 2.53 -2.36 -4.89 -0.328 0.83485E+04 207 nontronite-K 3.34 -0.30 -3.64 -0.233 0.62083E+04 208 nontronite-Mg 3.07 -0.82 -3.90 -0.253 0.66553E+04 209 nontronite-Na 3.52 0.40 -3.12 -0.200 0.53292E+04 224 tobermorite 9.82 7.76 -2.07 -0.564 0.35287E+04 230 alabandite -0.98 -5.25 -4.28 -1.425 0.73014E+04 233 boehmite 4.41 0.74 -3.67 -0.611 0.62619E+04 235 ferrous-oxide 9.81 6.73 -3.08 -0.769 0.52532E+04 240 silica-amorphous -2.09 -3.16 -1.07 -0.355 0.18203E+04 242 an20ab80 2.02 1.35 -0.67 -0.052 0.11472E+04 243 an25ab75 2.65 1.78 -0.87 -0.067 0.14810E+04 244 an30ab70 3.28 2.21 -1.07 -0.082 0.18244E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 100.0000000 g Current total amount of reactant added: 4999.9990000 g New total amount of reactant added: 5099.9990000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.5222E-10 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 12 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 5099.9990000 Water: Moles liquid = 0.2699E+02 kg liquid = 0.4863E+00 Moles total = -.8422E+01 kg total = -.1517E+00 Activity = 1.0000 Stoichiometric ionic strength = .1143838E-01 Osmotic coef. = 0.9685 True ionic strength = .2010221E-01 Chg. balance for total moles = 0.5222E-10 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.88659E-10 -10.0523 0.74477E-10 -10.1280 0.84003E+00 -0.0757 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.28243E-03 -3.5491 0.23581E-03 -3.6274 0.83496E+00 -0.0783 4 SO4-- 0.13277E-11 -11.8769 0.68875E-12 -12.1619 0.51874E+00 -0.2851 5 HCO3- 0.49119E-06 -6.3087 0.41073E-06 -6.3864 0.83619E+00 -0.0777 6 HS- 0.52437E-04 -4.2804 0.43789E-04 -4.3586 0.83509E+00 -0.0783 7 Al+++ 0.98276E-29 -29.0076 0.22648E-29 -29.6450 0.23045E+00 -0.6374 8 H4SiO4 0.69598E-03 -3.1574 0.69598E-03 -3.1574 0.10000E+01 0.0000 9 Ca++ 0.13619E-06 -6.8659 0.70124E-07 -7.1541 0.51492E+00 -0.2883 10 Mg++ 0.21306E-10 -10.6715 0.10920E-10 -10.9618 0.51256E+00 -0.2903 11 Fe++ 0.58722E-13 -13.2312 0.30131E-13 -13.5210 0.51312E+00 -0.2898 12 K+ 0.15716E-03 -3.8036 0.13145E-03 -3.8812 0.83639E+00 -0.0776 13 Na+ 0.19944E-01 -1.7002 0.16649E-01 -1.7786 0.83481E+00 -0.0784 14 Mn++ 0.18838E-10 -10.7250 0.96744E-11 -11.0144 0.51355E+00 -0.2894 15 HPO4-- 0.45020E-07 -7.3466 0.23357E-07 -7.6316 0.51881E+00 -0.2850 16 HSiO3- 0.10450E-01 -1.9809 0.87258E-02 -2.0592 0.83496E+00 -0.0783 17 Ca(HSiO3)+ 0.16657E-07 -7.7784 0.13935E-07 -7.8559 0.83657E+00 -0.0775 18 Mg(HSiO3)+ 0.32283E-11 -11.4910 0.27007E-11 -11.5685 0.83657E+00 -0.0775 19 NaHSiO3,aq 0.23496E-02 -2.6290 0.23496E-02 -2.6290 0.10000E+01 0.0000 20 AlO+ 0.66400E-16 -16.1778 0.55548E-16 -16.2553 0.83657E+00 -0.0775 22 HAlO2,aq 0.14853E-09 -9.8282 0.14853E-09 -9.8282 0.10000E+01 0.0000 23 AlO2- 0.52968E-05 -5.2760 0.44147E-05 -5.3551 0.83345E+00 -0.0791 24 CH4,aq 0.25455E-04 -4.5942 0.25366E-04 -4.5958 0.99651E+00 -0.0015 25 C2H6,aq 0.95300E-14 -14.0209 0.94968E-14 -14.0224 0.99651E+00 -0.0015 29 CO,aq 0.19018E-16 -16.7208 0.19018E-16 -16.7208 0.10000E+01 0.0000 30 CO2,aq 0.65592E-10 -10.1831 0.65363E-10 -10.1847 0.99651E+00 -0.0015 31 CO3-2 0.93058E-06 -6.0312 0.48170E-06 -6.3172 0.51764E+00 -0.2860 32 CaCO3,aq 0.42355E-09 -9.3731 0.42355E-09 -9.3731 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.87883E-12 -12.0561 0.73520E-12 -12.1336 0.83657E+00 -0.0775 34 CaCl+ 0.31989E-10 -10.4950 0.26761E-10 -10.5725 0.83657E+00 -0.0775 35 CaCl2,aq 0.14993E-14 -14.8241 0.14993E-14 -14.8241 0.10000E+01 0.0000 36 CaOH+ 0.80214E-07 -7.0957 0.67105E-07 -7.1732 0.83657E+00 -0.0775 37 CaSO4,aq 0.15337E-16 -16.8143 0.15337E-16 -16.8143 0.10000E+01 0.0000 38 HCl,aq 0.32183E-14 -14.4924 0.32183E-14 -14.4924 0.10000E+01 0.0000 43 FeCl+ 0.13444E-16 -16.8715 0.11247E-16 -16.9490 0.83657E+00 -0.0775 46 FeO,aq 0.21113E-09 -9.6755 0.21113E-09 -9.6755 0.10000E+01 0.0000 47 FeOH+ 0.15742E-10 -10.8029 0.13169E-10 -10.8804 0.83657E+00 -0.0775 48 HFeO2- 0.35523E-07 -7.4495 0.29661E-07 -7.5278 0.83496E+00 -0.0783 49 FeO+ 0.11033E-16 -16.9573 0.92296E-17 -17.0348 0.83657E+00 -0.0775 51 FeO2- 0.40778E-09 -9.3896 0.34048E-09 -9.4679 0.83496E+00 -0.0783 52 HFeO2,aq 0.32251E-11 -11.4915 0.32251E-11 -11.4915 0.10000E+01 0.0000 53 H2,aq 0.11623E-04 -4.9347 0.11583E-04 -4.9362 0.99651E+00 -0.0015 54 KCl,aq 0.56182E-09 -9.2504 0.56182E-09 -9.2504 0.10000E+01 0.0000 56 KOH,aq 0.75375E-06 -6.1228 0.75375E-06 -6.1228 0.10000E+01 0.0000 57 KSO4- 0.16826E-14 -14.7740 0.14049E-14 -14.8523 0.83496E+00 -0.0783 58 MgCO3,aq 0.16533E-13 -13.7816 0.16533E-13 -13.7816 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.13984E-15 -15.8544 0.11699E-15 -15.9319 0.83657E+00 -0.0775 60 MgCl+ 0.45150E-14 -14.3453 0.37771E-14 -14.4228 0.83657E+00 -0.0775 61 MgOH+ 0.69122E-10 -10.1604 0.57825E-10 -10.2379 0.83657E+00 -0.0775 63 MnO,aq 0.18062E-08 -8.7432 0.18062E-08 -8.7432 0.10000E+01 0.0000 64 MnOH+ 0.46954E-09 -9.3283 0.39280E-09 -9.4058 0.83657E+00 -0.0775 65 MnO2-2 0.20878E-10 -10.6803 0.10807E-10 -10.9663 0.51764E+00 -0.2860 66 HMnO2- 0.21119E-09 -9.6753 0.17634E-09 -9.7537 0.83496E+00 -0.0783 69 MnCl+ 0.16793E-13 -13.7749 0.14049E-13 -13.8524 0.83657E+00 -0.0775 71 NaCl,aq 0.13011E-05 -5.8857 0.13011E-05 -5.8857 0.10000E+01 0.0000 72 NaOH,aq 0.96047E-04 -4.0175 0.96047E-04 -4.0175 0.10000E+01 0.0000 74 OH- 0.93080E-02 -2.0311 0.77578E-02 -2.1103 0.83345E+00 -0.0791 79 HPO3-2 0.16287E-14 -14.7882 0.84307E-15 -15.0741 0.51764E+00 -0.2860 81 H2PO3- 0.15080E-18 -18.8216 0.12591E-18 -18.8999 0.83496E+00 -0.0783 82 H3PO4,aq 0.90611E-18 -18.0428 0.90611E-18 -18.0428 0.10000E+01 0.0000 83 H2PO4- 0.38396E-10 -10.4157 0.32090E-10 -10.4936 0.83576E+00 -0.0779 84 PO4-3 0.10570E-08 -8.9759 0.25587E-09 -9.5920 0.24208E+00 -0.6160 88 HP2O7-3 0.93841E-18 -18.0276 0.21648E-18 -18.6646 0.23069E+00 -0.6370 89 P2O7-4 0.90447E-17 -17.0436 0.69439E-18 -18.1584 0.76773E-01 -1.1148 90 H2S,aq 0.10115E-07 -7.9950 0.10079E-07 -7.9966 0.99651E+00 -0.0015 91 S2-2 0.70866E-14 -14.1496 0.36683E-14 -14.4355 0.51764E+00 -0.2860 97 SO3-2 0.19741E-17 -17.7046 0.10367E-17 -17.9844 0.52515E+00 -0.2797 99 HSO4- 0.59035E-19 -19.2289 0.49435E-19 -19.3060 0.83739E+00 -0.0771 Charge balance for all species = 0.1073E-09 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.8865939E-10 -.2223012E-01 -.2236759E+02 0.0000 2 H2O 0.1000000E+01 0.5550490E+02 0.9981956E+06 0.0000 3 Cl- 0.2824250E-03 0.2837267E-03 0.1004144E+02 6.5006 4 SO4-- 0.1327740E-11 -.2836028E-04 -.2719588E+01 8.0940 5 HCO3- 0.4911918E-06 0.2687683E-04 0.1637092E+01 3.7415 6 HS- 0.5243665E-04 0.8080705E-04 0.2667796E+01 5.7693 7 Al+++ 0.9827561E-29 0.5296999E-05 0.1426720E+00 0.7390 8 H4SiO4 0.6959796E-03 0.1349608E-01 0.1294922E+04 -3.1574 9 Ca++ 0.1361852E-06 0.2335131E-06 0.9342435E-02 13.1018 10 Mg++ 0.2130551E-10 0.9367569E-10 0.2273476E-05 9.2942 11 Fe++ 0.5872160E-13 0.3616123E-07 0.2015979E-02 6.7350 12 K+ 0.1571649E-03 0.1579192E-03 0.6164201E+01 6.2467 13 Na+ 0.1994356E-01 0.2239054E-01 0.5138575E+03 8.3494 14 Mn++ 0.1883848E-10 0.2526706E-08 0.1385703E-03 9.2416 15 HPO4-- 0.4501976E-07 0.4611512E-07 0.4418373E-02 12.6244 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.8444840E+02 -.1081034E-01 -.8443759E+02 0.0000000E+00 2 H2O -.8422330E+01 0.2699162E+02 -.3541395E+02 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.1413639E+00 -.1379139E-04 0.1413777E+00 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.1413384E+00 0.3929586E-04 -.1413777E+00 0.0000000E+00 7 Al+++ 0.1662978E+02 0.2575891E-05 0.1662978E+02 0.0000000E+00 8 H4SiO4 0.5310518E+02 0.6563044E-02 0.5309862E+02 0.0000000E+00 9 Ca++ 0.5865741E+01 0.1135557E-06 0.5865741E+01 0.0000000E+00 10 Mg++ 0.4047618E+01 0.4555378E-10 0.4047618E+01 0.0000000E+00 11 Fe++ 0.3636343E+01 0.1758494E-07 0.3636343E+01 0.0000000E+00 12 K+ 0.1082802E+01 0.7679493E-04 0.1082726E+01 0.0000000E+00 13 Na+ 0.6401901E+01 0.1088835E-01 0.6391013E+01 0.0000000E+00 14 Mn++ 0.8842682E-01 0.1228718E-08 0.8842682E-01 0.0000000E+00 15 HPO4-- 0.3017963E-01 0.2242544E-07 0.3017961E-01 0.0000000E+00 Chg. balance for solid moles: 0.3969E-14 Mass of aqueous solution: 0.487141E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 5099.9990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 6.386 0.805 1674. 3.224 30.05 642.8 andradite 0.5655 -0.248 287.4 2.458 5.158 74.66 grossular 0.1369 -0.863 61.68 1.790 1.107 17.16 apatite-OH 0.1006E-01 -1.997 5.053 0.704 0.9070E-01 1.606 clinochlore 0.7245 -0.140 402.7 2.605 7.228 153.2 daphnite 0.2097 -0.678 149.6 2.175 2.686 45.35 chlorite-Mn 0.1769E-01 -1.752 12.54 1.098 0.2250 3.996 diopside 0.2681 -0.572 58.07 1.764 1.042 17.75 hedenbergite 0.6954E-01 -1.158 17.25 1.237 0.3096 4.725 microcline 0.9494 -0.023 264.3 2.422 4.743 103.2 stilbite 3.284 0.516 2314. 3.364 41.54 1079. stilpnomelane-Fe 0.2666 -0.574 287.4 2.458 5.158 99.27 tr.625ac.25prg.125 0.4332E-01 -1.363 37.02 1.568 0.6645 11.92 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8051E+00 0.8051E+00 1.0000 -0.094 grossular 0.1949E+00 0.1949E+00 1.0000 -0.710 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.7611E+00 0.7611E+00 1.0000 -0.119 daphnite 0.2203E+00 0.2203E+00 1.0000 -0.657 chlorite-Mn 0.1858E-01 0.1858E-01 1.0000 -1.731 diopside 0.7941E+00 0.7941E+00 1.0000 -0.100 hedenbergite 0.2059E+00 0.2059E+00 1.0000 -0.686 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 tr.625ac.25prg.125 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 5571.588526 g Volume = 2254.980922 cm3 Porosity: -10.4841% V(tot) - V(min): -.21398E+03 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 5099.9990000 g log = 3.7076 Original solution: 1000.0103000 g Original solution / Rock added: 0.20 (Water/Rock Ratio), log = -0.7076 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0731 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9515E+00 0.9852 0.1006E+01 0.1021E+01 CO2,gas 0.6473E-08 1.0067 0.6993E-08 0.6947E-08 CH4,gas 0.3437E-01 1.0122 0.3734E-01 0.3689E-01 H2,gas 0.1416E-01 1.0006 0.1521E-01 0.1520E-01 H2S,gas 0.2593E-06 0.9958 0.2771E-06 0.2782E-06 S2,gas 0.1161E-28 1.0000 0.1246E-28 0.1246E-28 CO,gas 0.2641E-13 1.0000 0.2834E-13 0.2834E-13 SO3,gas 0.1346E-47 1.0000 0.1444E-47 0.1444E-47 SO2,gas 0.7964E-27 1.0000 0.8546E-27 0.8546E-27 HCl,gas 0.5292E-17 1.0000 0.5679E-17 0.5679E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 16 albite -0.38 -0.38 0.00 0.000 -0.13080E-10 22 andradite 39.01 39.01 0.00 0.000 0.00000E+00 23 grossular 32.73 32.73 0.00 0.000 -0.12132E-10 32 apatite-OH -18.15 -18.15 0.00 0.000 0.60662E-11 46 clinochlore 39.07 39.07 0.00 0.000 -0.48529E-10 47 daphnite 28.97 28.97 0.00 0.000 -0.24265E-10 48 chlorite-Mn 46.87 46.87 0.00 0.000 -0.48529E-10 67 diopside 16.18 16.18 0.00 0.000 0.00000E+00 68 hedenbergite 14.21 14.21 0.00 0.000 -0.15165E-10 116 microcline -2.49 -2.49 0.00 0.000 0.15165E-11 163 stilbite -7.52 -7.52 0.00 0.000 -0.90992E-11 164 stilpnomelane-Fe 13.02 13.02 0.00 0.000 0.21232E-10 245 tr.625ac.25prg.125 45.16 45.16 0.00 0.000 0.24265E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -16.51 -9.85 -3.285 0.16826E+05 -8.155 3 CH4,gas 4.54 1.42 -3.13 -0.782 0.53390E+04 -1.428 4 H2,gas 8.00 4.48 -3.52 -2.010 0.60051E+04 -1.818 5 H2S,gas -6.23 -14.49 -8.26 -4.128 0.14098E+05 -6.557 6 S2,gas -7.34 -37.94 -30.60 -4.708 0.52254E+05 -28.904 7 CO,gas 3.21 -12.03 -15.25 -4.691 0.26033E+05 -13.548 8 SO3,gas 17.12 -32.42 -49.54 -12.385 0.84587E+05 -47.840 9 SO2,gas 0.83 -27.94 -28.77 -7.671 0.49119E+05 -27.068 10 HCl,gas 5.19 -13.76 -18.94 -9.472 0.32348E+05 -17.246 11 acmite 7.71 6.53 -1.18 -0.123 0.20175E+04 15 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 19 spessartine 24.46 19.73 -4.73 -0.236 0.80710E+04 20 analcite 3.32 2.77 -0.55 -0.061 0.93625E+03 26 annite 20.12 17.72 -2.40 -0.134 0.41064E+04 27 phlogopite 27.06 25.40 -1.67 -0.093 0.28489E+04 29 anorthite 12.71 8.26 -4.45 -0.342 0.75903E+04 35 aragonite 0.97 -3.41 -4.38 -1.460 0.74772E+04 36 brucite 12.57 9.29 -3.27 -0.655 0.55909E+04 37 calcite 0.81 -3.41 -4.22 -1.408 0.72130E+04 38 carnegieite-low 9.02 5.93 -3.09 -0.442 0.52801E+04 39 carnegieite-high 10.09 5.93 -4.16 -0.595 0.71071E+04 40 carpholite-Mg 8.58 4.46 -4.12 -0.275 0.70429E+04 41 carpholite-Fe 6.71 1.90 -4.81 -0.321 0.82207E+04 42 celadonite 5.34 3.65 -1.69 -0.099 0.28879E+04 43 celadonite-Fe 3.88 1.09 -2.79 -0.164 0.47561E+04 44 chrysotile 23.89 21.57 -2.32 -0.194 0.39692E+04 49 chlorite-Al-free 47.17 43.14 -4.04 -0.168 0.68936E+04 51 chloritoid-Fe 9.17 5.06 -4.12 -0.275 0.70316E+04 52 chloritoid-Mn 11.40 7.56 -3.84 -0.256 0.65549E+04 54 coesite -2.38 -3.16 -0.78 -0.260 0.13341E+04 61 cristobalite -2.56 -3.16 -0.60 -0.199 0.10195E+04 63 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71234E+04 65 diaspore 2.87 0.74 -2.13 -0.356 0.36450E+04 66 diamond -3.10 -7.55 -4.45 -1.270 0.75921E+04 71 enstatite 17.26 12.27 -4.99 -0.499 0.85226E+04 73 clinoenstatite 17.17 12.27 -4.89 -0.489 0.83541E+04 75 epidote 24.67 22.70 -1.97 -0.095 0.33585E+04 76 clinozoisite 22.81 18.95 -3.86 -0.175 0.65869E+04 77 epidote-Fe 29.84 26.46 -3.38 -0.176 0.57768E+04 78 fayalite 14.05 10.31 -3.73 -0.533 0.63743E+04 79 ferrosilite 11.15 7.16 -3.99 -0.399 0.68202E+04 83 gibbsite 4.08 0.74 -3.34 -0.477 0.57035E+04 84 glaucophane 22.97 20.80 -2.17 -0.059 0.37134E+04 85 glaucophane-Fe 17.28 13.12 -4.15 -0.112 0.70919E+04 86 graphite -3.55 -7.55 -4.00 -1.144 0.68343E+04 87 greenalite 16.14 13.89 -2.25 -0.187 0.38408E+04 90 hematite 12.57 8.99 -3.58 -0.434 0.61111E+04 91 heulandite -5.83 -7.52 -1.69 -0.077 0.28938E+04 95 jadeite 4.22 2.77 -1.44 -0.144 0.24617E+04 97 kalsilite 7.58 3.83 -3.76 -0.537 0.64126E+04 98 kaolinite -1.33 -4.84 -3.50 -0.319 0.59831E+04 101 laumontite 2.88 1.95 -0.93 -0.062 0.15935E+04 102 lawsonite 9.62 8.26 -1.35 -0.090 0.23070E+04 103 leucite 4.12 0.67 -3.45 -0.345 0.58873E+04 105 lizardite 23.24 21.57 -1.68 -0.140 0.28618E+04 107 magnetite 20.09 15.72 -4.37 -0.356 0.74536E+04 108 minnesotaite 10.39 7.58 -2.81 -0.165 0.48028E+04 112 manganosite 14.06 9.24 -4.82 -1.204 0.82241E+04 120 muscovite 2.58 -1.01 -3.59 -0.211 0.61315E+04 121 paragonite 4.24 1.09 -3.15 -0.185 0.53706E+04 122 nepheline 8.34 5.93 -2.41 -0.344 0.41125E+04 128 periclase-Fe 11.63 6.73 -4.89 -1.223 0.83523E+04 134 phlogopite-Na 29.65 27.50 -2.15 -0.119 0.36677E+04 136 prehnite 19.37 18.21 -1.16 -0.068 0.19849E+04 137 prehnite-Fe 22.50 21.96 -0.53 -0.032 0.91158E+03 138 pumpellyite-Fe 46.27 43.89 -2.38 -0.053 0.40581E+04 139 pumpellyite-Mg 48.99 46.45 -2.54 -0.057 0.43420E+04 143 pyrrhotite -4.26 -7.75 -3.49 -1.164 0.59613E+04 144 pyrrhotiteFe0.875 -6.02 -9.15 -3.13 -1.152 0.53485E+04 145 pyroxmangite 7.40 6.08 -1.31 -0.263 0.22445E+04 146 pyrophyllite -6.18 -11.15 -4.98 -0.311 0.84962E+04 147 quartz -2.99 -3.16 -0.17 -0.056 0.28680E+03 152 rhodonite 7.45 6.08 -1.36 -0.272 0.23247E+04 153 sanidine -1.28 -2.49 -1.21 -0.093 0.20677E+04 165 stilpnomelane-Mg 27.44 25.81 -1.63 -0.049 0.27804E+04 171 talc 16.49 15.25 -1.24 -0.073 0.21140E+04 174 tephroite 18.09 15.33 -2.76 -0.394 0.47127E+04 178 tridymite -2.63 -3.16 -0.53 -0.177 0.90678E+03 179 tremolite 47.87 47.42 -0.45 -0.012 0.77494E+03 180 ferroactinolite 38.45 34.62 -3.83 -0.104 0.65448E+04 181 troilite-low -4.41 -7.75 -3.34 -1.114 0.57041E+04 183 vesuvianite 223.47 218.82 -4.65 -0.036 0.79439E+04 187 wairakite 3.95 1.95 -2.00 -0.118 0.34155E+04 188 walstromite 11.51 9.94 -1.56 -0.313 0.26719E+04 189 wollastonite 10.46 9.94 -0.52 -0.103 0.88229E+03 190 pseudo-wollastonite 11.00 9.94 -1.06 -0.211 0.18021E+04 191 zoisite 22.85 18.95 -3.90 -0.177 0.66609E+04 192 akaganeite 7.75 4.49 -3.26 -0.705 0.55681E+04 199 chalcedony -2.80 -3.16 -0.35 -0.118 0.60610E+03 201 montmorillonite-Ca -2.29 -6.17 -3.88 -0.240 0.66180E+04 202 montmorillonite-K -2.24 -6.27 -4.03 -0.247 0.68816E+04 203 montmorillonite-Mg -2.48 -6.79 -4.32 -0.267 0.73678E+04 204 montmorillonite-Na -2.04 -5.57 -3.54 -0.216 0.60365E+04 205 nontronite-Ca 3.21 -0.19 -3.41 -0.221 0.58215E+04 206 nontronite-H 2.53 -2.36 -4.89 -0.328 0.83485E+04 207 nontronite-K 3.34 -0.30 -3.64 -0.233 0.62083E+04 208 nontronite-Mg 3.07 -0.82 -3.90 -0.253 0.66553E+04 209 nontronite-Na 3.52 0.40 -3.12 -0.200 0.53292E+04 224 tobermorite 9.82 7.76 -2.07 -0.564 0.35287E+04 230 alabandite -0.98 -5.25 -4.27 -1.422 0.72861E+04 233 boehmite 4.41 0.74 -3.67 -0.611 0.62619E+04 235 ferrous-oxide 9.81 6.73 -3.08 -0.769 0.52532E+04 240 silica-amorphous -2.09 -3.16 -1.07 -0.355 0.18203E+04 242 an20ab80 2.02 1.35 -0.67 -0.052 0.11472E+04 243 an25ab75 2.65 1.78 -0.87 -0.067 0.14810E+04 244 an30ab70 3.28 2.21 -1.07 -0.082 0.18244E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 100.0000000 g Current total amount of reactant added: 5099.9990000 g New total amount of reactant added: 5199.9990000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.5222E-10 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 12 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 5199.9990000 Water: Moles liquid = 0.2644E+02 kg liquid = 0.4762E+00 Moles total = -.9676E+01 kg total = -.1743E+00 Activity = 1.0000 Stoichiometric ionic strength = .1144334E-01 Osmotic coef. = 0.9685 True ionic strength = .2010607E-01 Chg. balance for total moles = 0.5222E-10 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.88676E-10 -10.0522 0.74490E-10 -10.1279 0.84002E+00 -0.0757 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.28838E-03 -3.5400 0.24078E-03 -3.6184 0.83495E+00 -0.0783 4 SO4-- 0.13556E-11 -11.8679 0.70314E-12 -12.1530 0.51871E+00 -0.2851 5 HCO3- 0.50147E-06 -6.2998 0.41932E-06 -6.3775 0.83618E+00 -0.0777 6 HS- 0.53542E-04 -4.2713 0.44712E-04 -4.3496 0.83508E+00 -0.0783 7 Al+++ 0.98339E-29 -29.0073 0.22660E-29 -29.6447 0.23043E+00 -0.6375 8 H4SiO4 0.69598E-03 -3.1574 0.69598E-03 -3.1574 0.10000E+01 0.0000 9 Ca++ 0.13624E-06 -6.8657 0.70149E-07 -7.1540 0.51489E+00 -0.2883 10 Mg++ 0.21314E-10 -10.6713 0.10924E-10 -10.9616 0.51253E+00 -0.2903 11 Fe++ 0.58746E-13 -13.2310 0.30142E-13 -13.5208 0.51309E+00 -0.2898 12 K+ 0.15719E-03 -3.8036 0.13147E-03 -3.8812 0.83638E+00 -0.0776 13 Na+ 0.19947E-01 -1.7001 0.16652E-01 -1.7785 0.83480E+00 -0.0784 14 Mn++ 0.18847E-10 -10.7248 0.96782E-11 -11.0142 0.51352E+00 -0.2894 15 HPO4-- 0.45006E-07 -7.3467 0.23349E-07 -7.6317 0.51879E+00 -0.2850 16 HSiO3- 0.10449E-01 -1.9809 0.87242E-02 -2.0593 0.83495E+00 -0.0783 17 Ca(HSiO3)+ 0.16661E-07 -7.7783 0.13937E-07 -7.8558 0.83656E+00 -0.0775 18 Mg(HSiO3)+ 0.32289E-11 -11.4909 0.27012E-11 -11.5685 0.83656E+00 -0.0775 19 NaHSiO3,aq 0.23496E-02 -2.6290 0.23496E-02 -2.6290 0.10000E+01 0.0000 20 AlO+ 0.66412E-16 -16.1778 0.55558E-16 -16.2553 0.83656E+00 -0.0775 22 HAlO2,aq 0.14853E-09 -9.8282 0.14853E-09 -9.8282 0.10000E+01 0.0000 23 AlO2- 0.52960E-05 -5.2761 0.44139E-05 -5.3552 0.83344E+00 -0.0791 24 CH4,aq 0.25992E-04 -4.5852 0.25901E-04 -4.5867 0.99651E+00 -0.0015 25 C2H6,aq 0.99364E-14 -14.0028 0.99018E-14 -14.0043 0.99651E+00 -0.0015 29 CO,aq 0.19420E-16 -16.7118 0.19420E-16 -16.7118 0.10000E+01 0.0000 30 CO2,aq 0.66976E-10 -10.1741 0.66743E-10 -10.1756 0.99651E+00 -0.0015 31 CO3-2 0.94993E-06 -6.0223 0.49169E-06 -6.3083 0.51761E+00 -0.2860 32 CaCO3,aq 0.43249E-09 -9.3640 0.43249E-09 -9.3640 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.89755E-12 -12.0469 0.75085E-12 -12.1244 0.83656E+00 -0.0775 34 CaCl+ 0.32675E-10 -10.4858 0.27335E-10 -10.5633 0.83656E+00 -0.0775 35 CaCl2,aq 0.15637E-14 -14.8059 0.15637E-14 -14.8059 0.10000E+01 0.0000 36 CaOH+ 0.80229E-07 -7.0957 0.67117E-07 -7.1732 0.83656E+00 -0.0775 37 CaSO4,aq 0.15663E-16 -16.8051 0.15663E-16 -16.8051 0.10000E+01 0.0000 38 HCl,aq 0.32867E-14 -14.4832 0.32867E-14 -14.4832 0.10000E+01 0.0000 43 FeCl+ 0.13732E-16 -16.8623 0.11488E-16 -16.9398 0.83656E+00 -0.0775 46 FeO,aq 0.21113E-09 -9.6755 0.21113E-09 -9.6755 0.10000E+01 0.0000 47 FeOH+ 0.15745E-10 -10.8029 0.13172E-10 -10.8804 0.83656E+00 -0.0775 48 HFeO2- 0.35517E-07 -7.4496 0.29655E-07 -7.5279 0.83495E+00 -0.0783 49 FeO+ 0.11035E-16 -16.9572 0.92313E-17 -17.0347 0.83656E+00 -0.0775 51 FeO2- 0.40771E-09 -9.3896 0.34042E-09 -9.4680 0.83495E+00 -0.0783 52 HFeO2,aq 0.32251E-11 -11.4915 0.32251E-11 -11.4915 0.10000E+01 0.0000 53 H2,aq 0.11623E-04 -4.9347 0.11583E-04 -4.9362 0.99651E+00 -0.0015 54 KCl,aq 0.57376E-09 -9.2413 0.57376E-09 -9.2413 0.10000E+01 0.0000 56 KOH,aq 0.75375E-06 -6.1228 0.75375E-06 -6.1228 0.10000E+01 0.0000 57 KSO4- 0.17181E-14 -14.7650 0.14345E-14 -14.8433 0.83495E+00 -0.0783 58 MgCO3,aq 0.16882E-13 -13.7726 0.16882E-13 -13.7726 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.14282E-15 -15.8452 0.11948E-15 -15.9227 0.83656E+00 -0.0775 60 MgCl+ 0.46119E-14 -14.3361 0.38581E-14 -14.4136 0.83656E+00 -0.0775 61 MgOH+ 0.69135E-10 -10.1603 0.57835E-10 -10.2378 0.83656E+00 -0.0775 63 MnO,aq 0.18063E-08 -8.7432 0.18063E-08 -8.7432 0.10000E+01 0.0000 64 MnOH+ 0.46964E-09 -9.3282 0.39288E-09 -9.4057 0.83656E+00 -0.0775 65 MnO2-2 0.20872E-10 -10.6804 0.10804E-10 -10.9664 0.51761E+00 -0.2860 66 HMnO2- 0.21116E-09 -9.6754 0.17631E-09 -9.7537 0.83495E+00 -0.0783 69 MnCl+ 0.17154E-13 -13.7656 0.14350E-13 -13.8431 0.83656E+00 -0.0775 71 NaCl,aq 0.13288E-05 -5.8765 0.13288E-05 -5.8765 0.10000E+01 0.0000 72 NaOH,aq 0.96047E-04 -4.0175 0.96047E-04 -4.0175 0.10000E+01 0.0000 74 OH- 0.93065E-02 -2.0312 0.77564E-02 -2.1103 0.83344E+00 -0.0791 79 HPO3-2 0.16282E-14 -14.7883 0.84277E-15 -15.0743 0.51761E+00 -0.2860 81 H2PO3- 0.15077E-18 -18.8217 0.12589E-18 -18.9000 0.83495E+00 -0.0783 82 H3PO4,aq 0.90611E-18 -18.0428 0.90611E-18 -18.0428 0.10000E+01 0.0000 83 H2PO4- 0.38390E-10 -10.4158 0.32084E-10 -10.4937 0.83575E+00 -0.0779 84 PO4-3 0.10565E-08 -8.9761 0.25574E-09 -9.5922 0.24206E+00 -0.6161 88 HP2O7-3 0.93802E-18 -18.0278 0.21636E-18 -18.6648 0.23066E+00 -0.6370 89 P2O7-4 0.90401E-17 -17.0438 0.69390E-18 -18.1587 0.76758E-01 -1.1149 90 H2S,aq 0.10330E-07 -7.9859 0.10294E-07 -7.9874 0.99651E+00 -0.0015 91 S2-2 0.73888E-14 -14.1314 0.38245E-14 -14.4174 0.51761E+00 -0.2860 97 SO3-2 0.20154E-17 -17.6956 0.10583E-17 -17.9754 0.52512E+00 -0.2797 99 HSO4- 0.60280E-19 -19.2198 0.50477E-19 -19.2969 0.83738E+00 -0.0771 Charge balance for all species = 0.1096E-09 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.8867627E-10 -.2222687E-01 -.2236432E+02 0.0000 2 H2O 0.1000000E+01 0.5550490E+02 0.9981955E+06 0.0000 3 Cl- 0.2883803E-03 0.2897097E-03 0.1025318E+02 6.5095 4 SO4-- 0.1355551E-11 -.2889739E-04 -.2771094E+01 8.1028 5 HCO3- 0.5014743E-06 0.2744358E-04 0.1671613E+01 3.7504 6 HS- 0.5354238E-04 0.8245010E-04 0.2722039E+01 5.7783 7 Al+++ 0.9833943E-29 0.5296117E-05 0.1426482E+00 0.7390 8 H4SiO4 0.6959798E-03 0.1349436E-01 0.1294756E+04 -3.1574 9 Ca++ 0.1362407E-06 0.2335967E-06 0.9345780E-02 13.1018 10 Mg++ 0.2131421E-10 0.9369842E-10 0.2274027E-05 9.2942 11 Fe++ 0.5874560E-13 0.3615529E-07 0.2015647E-02 6.7350 12 K+ 0.1571949E-03 0.1579493E-03 0.6165372E+01 6.2467 13 Na+ 0.1994737E-01 0.2239439E-01 0.5139456E+03 8.3494 14 Mn++ 0.1884681E-10 0.2526847E-08 0.1385781E-03 9.2416 15 HPO4-- 0.4500599E-07 0.4610089E-07 0.4417009E-02 12.6241 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.8610425E+02 -.1058554E-01 -.8609366E+02 0.0000000E+00 2 H2O -.9675871E+01 0.2643420E+02 -.3611007E+02 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.1441352E+00 -.1376238E-04 0.1441490E+00 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.1441097E+00 0.3926685E-04 -.1441490E+00 0.0000000E+00 7 Al+++ 0.1695585E+02 0.2522275E-05 0.1695585E+02 0.0000000E+00 8 H4SiO4 0.5414646E+02 0.6426687E-02 0.5414003E+02 0.0000000E+00 9 Ca++ 0.5980755E+01 0.1112504E-06 0.5980755E+01 0.0000000E+00 10 Mg++ 0.4126983E+01 0.4462386E-10 0.4126983E+01 0.0000000E+00 11 Fe++ 0.3707644E+01 0.1721895E-07 0.3707644E+01 0.0000000E+00 12 K+ 0.1104034E+01 0.7522331E-04 0.1103959E+01 0.0000000E+00 13 Na+ 0.6527426E+01 0.1066532E-01 0.6516760E+01 0.0000000E+00 14 Mn++ 0.9016068E-01 0.1203410E-08 0.9016068E-01 0.0000000E+00 15 HPO4-- 0.3077139E-01 0.2195554E-07 0.3077137E-01 0.0000000E+00 Chg. balance for solid moles: -.8313E-14 Mass of aqueous solution: 0.477081E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 5199.9990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 6.511 0.814 1707. 3.232 30.06 655.4 andradite 0.5766 -0.239 293.0 2.467 5.158 76.13 grossular 0.1396 -0.855 62.89 1.799 1.107 17.50 apatite-OH 0.1026E-01 -1.989 5.152 0.712 0.9070E-01 1.637 clinochlore 0.7387 -0.132 410.6 2.613 7.227 156.2 daphnite 0.2138 -0.670 152.6 2.183 2.686 46.24 chlorite-Mn 0.1803E-01 -1.744 12.78 1.107 0.2250 4.074 diopside 0.2736 -0.563 59.24 1.773 1.043 18.11 hedenbergite 0.7095E-01 -1.149 17.60 1.246 0.3098 4.821 microcline 0.9680 -0.014 269.4 2.430 4.743 105.3 stilbite 3.348 0.525 2359. 3.373 41.53 1100. stilpnomelane-Fe 0.2718 -0.566 293.0 2.467 5.158 101.2 tr.625ac.25prg.125 0.4415E-01 -1.355 37.74 1.577 0.6643 12.15 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8051E+00 0.8051E+00 1.0000 -0.094 grossular 0.1949E+00 0.1949E+00 1.0000 -0.710 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.7611E+00 0.7611E+00 1.0000 -0.119 daphnite 0.2203E+00 0.2203E+00 1.0000 -0.657 chlorite-Mn 0.1858E-01 0.1858E-01 1.0000 -1.731 diopside 0.7941E+00 0.7941E+00 1.0000 -0.100 hedenbergite 0.2059E+00 0.2059E+00 1.0000 -0.686 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 tr.625ac.25prg.125 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 5680.839190 g Volume = 2299.183986 cm3 Porosity: -10.4846% V(tot) - V(min): -.21818E+03 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 5199.9990000 g log = 3.7160 Original solution: 1000.0103000 g Original solution / Rock added: 0.19 (Water/Rock Ratio), log = -0.7160 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0739 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9508E+00 0.9852 0.1006E+01 0.1021E+01 CO2,gas 0.6605E-08 1.0067 0.7141E-08 0.7093E-08 CH4,gas 0.3507E-01 1.0122 0.3812E-01 0.3766E-01 H2,gas 0.1415E-01 1.0006 0.1521E-01 0.1520E-01 H2S,gas 0.2646E-06 0.9958 0.2830E-06 0.2841E-06 S2,gas 0.1210E-28 1.0000 0.1300E-28 0.1300E-28 CO,gas 0.2695E-13 1.0000 0.2894E-13 0.2894E-13 SO3,gas 0.1374E-47 1.0000 0.1475E-47 0.1475E-47 SO2,gas 0.8127E-27 1.0000 0.8727E-27 0.8727E-27 HCl,gas 0.5400E-17 1.0000 0.5799E-17 0.5799E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 16 albite -0.38 -0.38 0.00 0.000 -0.13080E-10 22 andradite 39.01 39.01 0.00 0.000 0.24265E-10 23 grossular 32.73 32.73 0.00 0.000 0.00000E+00 32 apatite-OH -18.15 -18.15 0.00 0.000 -0.60662E-11 46 clinochlore 39.07 39.07 0.00 0.000 -0.24265E-10 47 daphnite 28.97 28.97 0.00 0.000 -0.24265E-10 48 chlorite-Mn 46.87 46.87 0.00 0.000 -0.36397E-10 67 diopside 16.18 16.18 0.00 0.000 0.00000E+00 68 hedenbergite 14.21 14.21 0.00 0.000 -0.60662E-11 116 microcline -2.49 -2.49 0.00 0.000 -0.10616E-10 163 stilbite -7.52 -7.52 0.00 0.000 -0.33364E-10 164 stilpnomelane-Fe 13.02 13.02 0.00 0.000 0.21232E-10 245 tr.625ac.25prg.125 45.16 45.16 0.00 0.000 0.12132E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -16.51 -9.85 -3.282 0.16810E+05 -8.146 3 CH4,gas 4.54 1.43 -3.12 -0.779 0.53235E+04 -1.419 4 H2,gas 8.00 4.48 -3.52 -2.010 0.60051E+04 -1.818 5 H2S,gas -6.23 -14.48 -8.25 -4.124 0.14082E+05 -6.548 6 S2,gas -7.34 -37.92 -30.59 -4.705 0.52223E+05 -28.886 7 CO,gas 3.21 -12.02 -15.24 -4.688 0.26018E+05 -13.539 8 SO3,gas 17.12 -32.41 -49.53 -12.383 0.84571E+05 -47.831 9 SO2,gas 0.83 -27.93 -28.76 -7.669 0.49104E+05 -27.059 10 HCl,gas 5.19 -13.75 -18.94 -9.468 0.32332E+05 -17.237 11 acmite 7.71 6.53 -1.18 -0.123 0.20175E+04 15 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 19 spessartine 24.46 19.73 -4.73 -0.236 0.80709E+04 20 analcite 3.32 2.77 -0.55 -0.061 0.93625E+03 26 annite 20.12 17.72 -2.40 -0.134 0.41064E+04 27 phlogopite 27.06 25.40 -1.67 -0.093 0.28489E+04 29 anorthite 12.71 8.26 -4.45 -0.342 0.75903E+04 35 aragonite 0.97 -3.40 -4.37 -1.457 0.74617E+04 36 brucite 12.57 9.29 -3.27 -0.655 0.55909E+04 37 calcite 0.81 -3.40 -4.22 -1.405 0.71975E+04 38 carnegieite-low 9.02 5.93 -3.09 -0.442 0.52801E+04 39 carnegieite-high 10.09 5.93 -4.16 -0.595 0.71071E+04 40 carpholite-Mg 8.58 4.46 -4.12 -0.275 0.70429E+04 41 carpholite-Fe 6.71 1.90 -4.81 -0.321 0.82207E+04 42 celadonite 5.34 3.65 -1.69 -0.099 0.28879E+04 43 celadonite-Fe 3.88 1.09 -2.79 -0.164 0.47561E+04 44 chrysotile 23.89 21.57 -2.32 -0.194 0.39692E+04 49 chlorite-Al-free 47.17 43.14 -4.04 -0.168 0.68936E+04 51 chloritoid-Fe 9.17 5.06 -4.12 -0.275 0.70316E+04 52 chloritoid-Mn 11.40 7.56 -3.84 -0.256 0.65549E+04 54 coesite -2.38 -3.16 -0.78 -0.260 0.13341E+04 61 cristobalite -2.56 -3.16 -0.60 -0.199 0.10195E+04 63 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71234E+04 65 diaspore 2.87 0.74 -2.13 -0.356 0.36450E+04 66 diamond -3.10 -7.54 -4.44 -1.268 0.75766E+04 71 enstatite 17.26 12.27 -4.99 -0.499 0.85226E+04 73 clinoenstatite 17.17 12.27 -4.89 -0.489 0.83541E+04 75 epidote 24.67 22.70 -1.97 -0.095 0.33585E+04 76 clinozoisite 22.81 18.95 -3.86 -0.175 0.65869E+04 77 epidote-Fe 29.84 26.46 -3.38 -0.176 0.57768E+04 78 fayalite 14.05 10.31 -3.73 -0.533 0.63743E+04 79 ferrosilite 11.15 7.16 -3.99 -0.399 0.68202E+04 83 gibbsite 4.08 0.74 -3.34 -0.477 0.57035E+04 84 glaucophane 22.97 20.80 -2.17 -0.059 0.37134E+04 85 glaucophane-Fe 17.28 13.12 -4.15 -0.112 0.70919E+04 86 graphite -3.55 -7.54 -3.99 -1.141 0.68189E+04 87 greenalite 16.14 13.89 -2.25 -0.187 0.38408E+04 90 hematite 12.57 8.99 -3.58 -0.434 0.61111E+04 91 heulandite -5.83 -7.52 -1.69 -0.077 0.28938E+04 95 jadeite 4.22 2.77 -1.44 -0.144 0.24617E+04 97 kalsilite 7.58 3.83 -3.76 -0.537 0.64126E+04 98 kaolinite -1.33 -4.84 -3.50 -0.319 0.59831E+04 101 laumontite 2.88 1.95 -0.93 -0.062 0.15935E+04 102 lawsonite 9.62 8.26 -1.35 -0.090 0.23070E+04 103 leucite 4.12 0.67 -3.45 -0.345 0.58873E+04 105 lizardite 23.24 21.57 -1.68 -0.140 0.28618E+04 107 magnetite 20.09 15.72 -4.37 -0.356 0.74536E+04 108 minnesotaite 10.39 7.58 -2.81 -0.165 0.48028E+04 112 manganosite 14.06 9.24 -4.82 -1.204 0.82241E+04 120 muscovite 2.58 -1.01 -3.59 -0.211 0.61315E+04 121 paragonite 4.24 1.09 -3.15 -0.185 0.53706E+04 122 nepheline 8.34 5.93 -2.41 -0.344 0.41125E+04 128 periclase-Fe 11.63 6.73 -4.89 -1.223 0.83523E+04 134 phlogopite-Na 29.65 27.50 -2.15 -0.119 0.36677E+04 136 prehnite 19.37 18.21 -1.16 -0.068 0.19849E+04 137 prehnite-Fe 22.50 21.96 -0.53 -0.032 0.91158E+03 138 pumpellyite-Fe 46.27 43.89 -2.38 -0.053 0.40582E+04 139 pumpellyite-Mg 48.99 46.45 -2.54 -0.057 0.43420E+04 143 pyrrhotite -4.26 -7.74 -3.48 -1.161 0.59457E+04 144 pyrrhotiteFe0.875 -6.02 -9.14 -3.12 -1.149 0.53329E+04 145 pyroxmangite 7.40 6.08 -1.31 -0.263 0.22444E+04 146 pyrophyllite -6.18 -11.15 -4.98 -0.311 0.84962E+04 147 quartz -2.99 -3.16 -0.17 -0.056 0.28680E+03 152 rhodonite 7.45 6.08 -1.36 -0.272 0.23247E+04 153 sanidine -1.28 -2.49 -1.21 -0.093 0.20677E+04 165 stilpnomelane-Mg 27.44 25.81 -1.63 -0.049 0.27804E+04 171 talc 16.49 15.25 -1.24 -0.073 0.21140E+04 174 tephroite 18.09 15.33 -2.76 -0.394 0.47126E+04 178 tridymite -2.63 -3.16 -0.53 -0.177 0.90678E+03 179 tremolite 47.87 47.42 -0.45 -0.012 0.77494E+03 180 ferroactinolite 38.45 34.62 -3.83 -0.104 0.65448E+04 181 troilite-low -4.41 -7.74 -3.33 -1.111 0.56885E+04 183 vesuvianite 223.47 218.82 -4.65 -0.036 0.79439E+04 187 wairakite 3.95 1.95 -2.00 -0.118 0.34155E+04 188 walstromite 11.51 9.94 -1.56 -0.313 0.26719E+04 189 wollastonite 10.46 9.94 -0.52 -0.103 0.88229E+03 190 pseudo-wollastonite 11.00 9.94 -1.06 -0.211 0.18021E+04 191 zoisite 22.85 18.95 -3.90 -0.177 0.66609E+04 192 akaganeite 7.75 4.49 -3.26 -0.705 0.55681E+04 199 chalcedony -2.80 -3.16 -0.35 -0.118 0.60610E+03 201 montmorillonite-Ca -2.29 -6.17 -3.88 -0.240 0.66180E+04 202 montmorillonite-K -2.24 -6.27 -4.03 -0.247 0.68816E+04 203 montmorillonite-Mg -2.48 -6.79 -4.32 -0.267 0.73678E+04 204 montmorillonite-Na -2.04 -5.57 -3.54 -0.216 0.60365E+04 205 nontronite-Ca 3.21 -0.19 -3.41 -0.221 0.58215E+04 206 nontronite-H 2.53 -2.36 -4.89 -0.328 0.83485E+04 207 nontronite-K 3.34 -0.30 -3.64 -0.233 0.62083E+04 208 nontronite-Mg 3.07 -0.82 -3.90 -0.253 0.66553E+04 209 nontronite-Na 3.52 0.40 -3.12 -0.200 0.53292E+04 224 tobermorite 9.82 7.76 -2.07 -0.564 0.35287E+04 230 alabandite -0.98 -5.24 -4.26 -1.419 0.72704E+04 233 boehmite 4.41 0.74 -3.67 -0.611 0.62619E+04 235 ferrous-oxide 9.81 6.73 -3.08 -0.769 0.52532E+04 240 silica-amorphous -2.09 -3.16 -1.07 -0.355 0.18203E+04 242 an20ab80 2.02 1.35 -0.67 -0.052 0.11472E+04 243 an25ab75 2.65 1.78 -0.87 -0.067 0.14810E+04 244 an30ab70 3.28 2.21 -1.07 -0.082 0.18244E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 100.0000000 g Current total amount of reactant added: 5199.9990000 g New total amount of reactant added: 5299.9990000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.5223E-10 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 12 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 5299.9990000 Water: Moles liquid = 0.2588E+02 kg liquid = 0.4662E+00 Moles total = -.1093E+02 kg total = -.1969E+00 Activity = 1.0000 Stoichiometric ionic strength = .1144851E-01 Osmotic coef. = 0.9685 True ionic strength = .2011010E-01 Chg. balance for total moles = 0.5223E-10 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.88694E-10 -10.0521 0.74504E-10 -10.1278 0.84001E+00 -0.0757 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.29459E-03 -3.5308 0.24597E-03 -3.6091 0.83494E+00 -0.0783 4 SO4-- 0.13846E-11 -11.8587 0.71815E-12 -12.1438 0.51869E+00 -0.2851 5 HCO3- 0.51220E-06 -6.2906 0.42828E-06 -6.3683 0.83617E+00 -0.0777 6 HS- 0.54696E-04 -4.2620 0.45674E-04 -4.3403 0.83506E+00 -0.0783 7 Al+++ 0.98406E-29 -29.0070 0.22673E-29 -29.6445 0.23040E+00 -0.6375 8 H4SiO4 0.69598E-03 -3.1574 0.69598E-03 -3.1574 0.10000E+01 0.0000 9 Ca++ 0.13630E-06 -6.8655 0.70176E-07 -7.1538 0.51487E+00 -0.2883 10 Mg++ 0.21323E-10 -10.6711 0.10928E-10 -10.9614 0.51250E+00 -0.2903 11 Fe++ 0.58771E-13 -13.2308 0.30153E-13 -13.5207 0.51307E+00 -0.2898 12 K+ 0.15723E-03 -3.8035 0.13150E-03 -3.8811 0.83637E+00 -0.0776 13 Na+ 0.19951E-01 -1.7000 0.16655E-01 -1.7785 0.83479E+00 -0.0784 14 Mn++ 0.18855E-10 -10.7246 0.96821E-11 -11.0140 0.51349E+00 -0.2895 15 HPO4-- 0.44992E-07 -7.3469 0.23340E-07 -7.6319 0.51876E+00 -0.2850 16 HSiO3- 0.10447E-01 -1.9810 0.87226E-02 -2.0594 0.83494E+00 -0.0783 17 Ca(HSiO3)+ 0.16664E-07 -7.7782 0.13940E-07 -7.8557 0.83655E+00 -0.0775 18 Mg(HSiO3)+ 0.32295E-11 -11.4909 0.27017E-11 -11.5684 0.83655E+00 -0.0775 19 NaHSiO3,aq 0.23496E-02 -2.6290 0.23496E-02 -2.6290 0.10000E+01 0.0000 20 AlO+ 0.66425E-16 -16.1777 0.55568E-16 -16.2552 0.83655E+00 -0.0775 22 HAlO2,aq 0.14853E-09 -9.8282 0.14853E-09 -9.8282 0.10000E+01 0.0000 23 AlO2- 0.52951E-05 -5.2761 0.44131E-05 -5.3553 0.83343E+00 -0.0791 24 CH4,aq 0.26552E-04 -4.5759 0.26459E-04 -4.5774 0.99651E+00 -0.0015 25 C2H6,aq 0.10369E-13 -13.9842 0.10333E-13 -13.9858 0.99651E+00 -0.0015 29 CO,aq 0.19838E-16 -16.7025 0.19838E-16 -16.7025 0.10000E+01 0.0000 30 CO2,aq 0.68420E-10 -10.1648 0.68181E-10 -10.1663 0.99651E+00 -0.0015 31 CO3-2 0.97010E-06 -6.0132 0.50210E-06 -6.2992 0.51758E+00 -0.2860 32 CaCO3,aq 0.44181E-09 -9.3548 0.44181E-09 -9.3548 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.91708E-12 -12.0376 0.76718E-12 -12.1151 0.83655E+00 -0.0775 34 CaCl+ 0.33391E-10 -10.4764 0.27934E-10 -10.5539 0.83655E+00 -0.0775 35 CaCl2,aq 0.16323E-14 -14.7872 0.16323E-14 -14.7872 0.10000E+01 0.0000 36 CaOH+ 0.80245E-07 -7.0956 0.67129E-07 -7.1731 0.83655E+00 -0.0775 37 CaSO4,aq 0.16003E-16 -16.7958 0.16003E-16 -16.7958 0.10000E+01 0.0000 38 HCl,aq 0.33581E-14 -14.4739 0.33581E-14 -14.4739 0.10000E+01 0.0000 43 FeCl+ 0.14033E-16 -16.8528 0.11739E-16 -16.9304 0.83655E+00 -0.0775 46 FeO,aq 0.21113E-09 -9.6755 0.21113E-09 -9.6755 0.10000E+01 0.0000 47 FeOH+ 0.15748E-10 -10.8028 0.13174E-10 -10.8803 0.83655E+00 -0.0775 48 HFeO2- 0.35511E-07 -7.4496 0.29650E-07 -7.5280 0.83494E+00 -0.0783 49 FeO+ 0.11037E-16 -16.9571 0.92330E-17 -17.0347 0.83655E+00 -0.0775 51 FeO2- 0.40764E-09 -9.3897 0.34036E-09 -9.4681 0.83494E+00 -0.0783 52 HFeO2,aq 0.32251E-11 -11.4915 0.32251E-11 -11.4915 0.10000E+01 0.0000 53 H2,aq 0.11623E-04 -4.9347 0.11583E-04 -4.9362 0.99651E+00 -0.0015 54 KCl,aq 0.58622E-09 -9.2319 0.58622E-09 -9.2319 0.10000E+01 0.0000 56 KOH,aq 0.75375E-06 -6.1228 0.75375E-06 -6.1228 0.10000E+01 0.0000 57 KSO4- 0.17551E-14 -14.7557 0.14654E-14 -14.8340 0.83494E+00 -0.0783 58 MgCO3,aq 0.17246E-13 -13.7633 0.17246E-13 -13.7633 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.14593E-15 -15.8359 0.12208E-15 -15.9134 0.83655E+00 -0.0775 60 MgCl+ 0.47129E-14 -14.3267 0.39426E-14 -14.4042 0.83655E+00 -0.0775 61 MgOH+ 0.69149E-10 -10.1602 0.57846E-10 -10.2377 0.83655E+00 -0.0775 63 MnO,aq 0.18064E-08 -8.7432 0.18064E-08 -8.7432 0.10000E+01 0.0000 64 MnOH+ 0.46975E-09 -9.3281 0.39297E-09 -9.4056 0.83655E+00 -0.0775 65 MnO2-2 0.20866E-10 -10.6806 0.10800E-10 -10.9666 0.51758E+00 -0.2860 66 HMnO2- 0.21113E-09 -9.6754 0.17628E-09 -9.7538 0.83494E+00 -0.0783 69 MnCl+ 0.17530E-13 -13.7562 0.14665E-13 -13.8337 0.83655E+00 -0.0775 71 NaCl,aq 0.13576E-05 -5.8672 0.13576E-05 -5.8672 0.10000E+01 0.0000 72 NaOH,aq 0.96047E-04 -4.0175 0.96047E-04 -4.0175 0.10000E+01 0.0000 74 OH- 0.93049E-02 -2.0313 0.77549E-02 -2.1104 0.83343E+00 -0.0791 79 HPO3-2 0.16277E-14 -14.7884 0.84246E-15 -15.0745 0.51758E+00 -0.2860 81 H2PO3- 0.15075E-18 -18.8218 0.12587E-18 -18.9001 0.83494E+00 -0.0783 82 H3PO4,aq 0.90611E-18 -18.0428 0.90611E-18 -18.0428 0.10000E+01 0.0000 83 H2PO4- 0.38383E-10 -10.4159 0.32078E-10 -10.4938 0.83574E+00 -0.0779 84 PO4-3 0.10560E-08 -8.9763 0.25560E-09 -9.5924 0.24203E+00 -0.6161 88 HP2O7-3 0.93761E-18 -18.0280 0.21624E-18 -18.6651 0.23063E+00 -0.6371 89 P2O7-4 0.90352E-17 -17.0441 0.69338E-18 -18.1590 0.76742E-01 -1.1150 90 H2S,aq 0.10554E-07 -7.9766 0.10517E-07 -7.9781 0.99651E+00 -0.0015 91 S2-2 0.77107E-14 -14.1129 0.39909E-14 -14.3989 0.51758E+00 -0.2860 97 SO3-2 0.20585E-17 -17.6864 0.10809E-17 -17.9662 0.52509E+00 -0.2798 99 HSO4- 0.61578E-19 -19.2106 0.51564E-19 -19.2877 0.83736E+00 -0.0771 Charge balance for all species = 0.1120E-09 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.8869389E-10 -.2222349E-01 -.2236091E+02 0.0000 2 H2O 0.1000000E+01 0.5550490E+02 0.9981953E+06 0.0000 3 Cl- 0.2945921E-03 0.2959503E-03 0.1047405E+02 6.5187 4 SO4-- 0.1384553E-11 -.2945766E-04 -.2824819E+01 8.1119 5 HCO3- 0.5121964E-06 0.2803474E-04 0.1707621E+01 3.7596 6 HS- 0.5469574E-04 0.8416395E-04 0.2778621E+01 5.7875 7 Al+++ 0.9840604E-29 0.5295199E-05 0.1426235E+00 0.7390 8 H4SiO4 0.6959801E-03 0.1349256E-01 0.1294583E+04 -3.1574 9 Ca++ 0.1362987E-06 0.2336840E-06 0.9349271E-02 13.1018 10 Mg++ 0.2132330E-10 0.9372214E-10 0.2274603E-05 9.2942 11 Fe++ 0.5877064E-13 0.3614908E-07 0.2015300E-02 6.7350 12 K+ 0.1572263E-03 0.1579806E-03 0.6166594E+01 6.2467 13 Na+ 0.1995135E-01 0.2239840E-01 0.5140376E+03 8.3494 14 Mn++ 0.1885545E-10 0.2526987E-08 0.1385857E-03 9.2416 15 HPO4-- 0.4499163E-07 0.4608606E-07 0.4415587E-02 12.6237 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.8776010E+02 -.1036075E-01 -.8774974E+02 0.0000000E+00 2 H2O -.1092941E+02 0.2587679E+02 -.3680620E+02 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.1469065E+00 -.1373337E-04 0.1469203E+00 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.1468810E+00 0.3923784E-04 -.1469203E+00 0.0000000E+00 7 Al+++ 0.1728193E+02 0.2468660E-05 0.1728192E+02 0.0000000E+00 8 H4SiO4 0.5518774E+02 0.6290330E-02 0.5518145E+02 0.0000000E+00 9 Ca++ 0.6095769E+01 0.1089452E-06 0.6095769E+01 0.0000000E+00 10 Mg++ 0.4206348E+01 0.4369394E-10 0.4206348E+01 0.0000000E+00 11 Fe++ 0.3778945E+01 0.1685296E-07 0.3778945E+01 0.0000000E+00 12 K+ 0.1125265E+01 0.7365170E-04 0.1125192E+01 0.0000000E+00 13 Na+ 0.6652950E+01 0.1044230E-01 0.6642508E+01 0.0000000E+00 14 Mn++ 0.9189454E-01 0.1178099E-08 0.9189454E-01 0.0000000E+00 15 HPO4-- 0.3136315E-01 0.2148565E-07 0.3136313E-01 0.0000000E+00 Chg. balance for solid moles: -.1187E-13 Mass of aqueous solution: 0.467021E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 5299.9990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 6.637 0.822 1740. 3.241 30.06 668.1 andradite 0.5877 -0.231 298.6 2.475 5.158 77.59 grossular 0.1423 -0.847 64.10 1.807 1.107 17.84 apatite-OH 0.1045E-01 -1.981 5.251 0.720 0.9070E-01 1.669 clinochlore 0.7529 -0.123 418.5 2.622 7.227 159.2 daphnite 0.2179 -0.662 155.5 2.192 2.686 47.12 chlorite-Mn 0.1838E-01 -1.736 13.03 1.115 0.2250 4.152 diopside 0.2790 -0.554 60.42 1.781 1.044 18.47 hedenbergite 0.7236E-01 -1.141 17.95 1.254 0.3100 4.917 microcline 0.9867 -0.006 274.6 2.439 4.743 107.3 stilbite 3.412 0.533 2405. 3.381 41.53 1122. stilpnomelane-Fe 0.2771 -0.557 298.7 2.475 5.158 103.2 tr.625ac.25prg.125 0.4498E-01 -1.347 38.45 1.585 0.6641 12.38 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8051E+00 0.8051E+00 1.0000 -0.094 grossular 0.1949E+00 0.1949E+00 1.0000 -0.710 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.7611E+00 0.7611E+00 1.0000 -0.119 daphnite 0.2203E+00 0.2203E+00 1.0000 -0.657 chlorite-Mn 0.1858E-01 0.1858E-01 1.0000 -1.731 diopside 0.7941E+00 0.7941E+00 1.0000 -0.100 hedenbergite 0.2059E+00 0.2059E+00 1.0000 -0.686 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 tr.625ac.25prg.125 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 5790.089855 g Volume = 2343.387050 cm3 Porosity: -10.4850% V(tot) - V(min): -.22239E+03 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 5299.9990000 g log = 3.7243 Original solution: 1000.0103000 g Original solution / Rock added: 0.19 (Water/Rock Ratio), log = -0.7243 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0747 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9501E+00 0.9852 0.1006E+01 0.1021E+01 CO2,gas 0.6743E-08 1.0067 0.7295E-08 0.7246E-08 CH4,gas 0.3580E-01 1.0122 0.3895E-01 0.3848E-01 H2,gas 0.1414E-01 1.0006 0.1521E-01 0.1520E-01 H2S,gas 0.2701E-06 0.9958 0.2891E-06 0.2903E-06 S2,gas 0.1262E-28 1.0000 0.1357E-28 0.1357E-28 CO,gas 0.2751E-13 1.0000 0.2956E-13 0.2956E-13 SO3,gas 0.1402E-47 1.0000 0.1507E-47 0.1507E-47 SO2,gas 0.8297E-27 1.0000 0.8917E-27 0.8917E-27 HCl,gas 0.5513E-17 1.0000 0.5925E-17 0.5925E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 16 albite -0.38 -0.38 0.00 0.000 0.11184E-10 22 andradite 39.01 39.01 0.00 0.000 -0.12132E-10 23 grossular 32.73 32.73 0.00 0.000 0.24265E-10 32 apatite-OH -18.15 -18.15 0.00 0.000 0.60662E-11 46 clinochlore 39.07 39.07 0.00 0.000 0.48529E-10 47 daphnite 28.97 28.97 0.00 0.000 0.12132E-10 48 chlorite-Mn 46.87 46.87 0.00 0.000 0.24265E-10 67 diopside 16.18 16.18 0.00 0.000 0.00000E+00 68 hedenbergite 14.21 14.21 0.00 0.000 0.30331E-11 116 microcline -2.49 -2.49 0.00 0.000 0.15165E-11 163 stilbite -7.52 -7.52 0.00 0.000 0.15165E-10 164 stilpnomelane-Fe 13.02 13.02 0.00 0.000 0.69761E-10 245 tr.625ac.25prg.125 45.16 45.16 0.00 0.000 0.36397E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -16.50 -9.84 -3.279 0.16795E+05 -8.137 3 CH4,gas 4.54 1.44 -3.11 -0.777 0.53077E+04 -1.410 4 H2,gas 8.00 4.48 -3.52 -2.010 0.60051E+04 -1.818 5 H2S,gas -6.23 -14.47 -8.24 -4.119 0.14066E+05 -6.539 6 S2,gas -7.34 -37.90 -30.57 -4.703 0.52191E+05 -28.867 7 CO,gas 3.21 -12.01 -15.23 -4.686 0.26002E+05 -13.529 8 SO3,gas 17.12 -32.40 -49.52 -12.380 0.84555E+05 -47.822 9 SO2,gas 0.83 -27.92 -28.75 -7.666 0.49088E+05 -27.050 10 HCl,gas 5.19 -13.74 -18.93 -9.463 0.32316E+05 -17.227 11 acmite 7.71 6.53 -1.18 -0.123 0.20175E+04 15 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 19 spessartine 24.46 19.73 -4.73 -0.236 0.80708E+04 20 analcite 3.32 2.77 -0.55 -0.061 0.93625E+03 26 annite 20.12 17.72 -2.40 -0.134 0.41064E+04 27 phlogopite 27.06 25.40 -1.67 -0.093 0.28489E+04 29 anorthite 12.71 8.26 -4.45 -0.342 0.75903E+04 35 aragonite 0.97 -3.39 -4.36 -1.454 0.74459E+04 36 brucite 12.57 9.29 -3.27 -0.655 0.55909E+04 37 calcite 0.81 -3.39 -4.21 -1.402 0.71817E+04 38 carnegieite-low 9.02 5.93 -3.09 -0.442 0.52801E+04 39 carnegieite-high 10.09 5.93 -4.16 -0.595 0.71071E+04 40 carpholite-Mg 8.58 4.46 -4.12 -0.275 0.70429E+04 41 carpholite-Fe 6.71 1.90 -4.81 -0.321 0.82207E+04 42 celadonite 5.34 3.65 -1.69 -0.099 0.28879E+04 43 celadonite-Fe 3.88 1.09 -2.79 -0.164 0.47561E+04 44 chrysotile 23.89 21.57 -2.32 -0.194 0.39692E+04 49 chlorite-Al-free 47.17 43.14 -4.04 -0.168 0.68936E+04 51 chloritoid-Fe 9.17 5.06 -4.12 -0.275 0.70316E+04 52 chloritoid-Mn 11.40 7.56 -3.84 -0.256 0.65549E+04 54 coesite -2.38 -3.16 -0.78 -0.260 0.13341E+04 61 cristobalite -2.56 -3.16 -0.60 -0.199 0.10195E+04 63 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71234E+04 65 diaspore 2.87 0.74 -2.13 -0.356 0.36450E+04 66 diamond -3.10 -7.53 -4.43 -1.265 0.75608E+04 71 enstatite 17.26 12.27 -4.99 -0.499 0.85226E+04 73 clinoenstatite 17.17 12.27 -4.89 -0.489 0.83541E+04 75 epidote 24.67 22.70 -1.97 -0.095 0.33585E+04 76 clinozoisite 22.81 18.95 -3.86 -0.175 0.65869E+04 77 epidote-Fe 29.84 26.46 -3.38 -0.176 0.57768E+04 78 fayalite 14.05 10.31 -3.73 -0.533 0.63743E+04 79 ferrosilite 11.15 7.16 -3.99 -0.399 0.68202E+04 83 gibbsite 4.08 0.74 -3.34 -0.477 0.57035E+04 84 glaucophane 22.97 20.80 -2.17 -0.059 0.37134E+04 85 glaucophane-Fe 17.28 13.12 -4.15 -0.112 0.70919E+04 86 graphite -3.55 -7.53 -3.98 -1.138 0.68030E+04 87 greenalite 16.14 13.89 -2.25 -0.187 0.38408E+04 90 hematite 12.57 8.99 -3.58 -0.434 0.61111E+04 91 heulandite -5.83 -7.52 -1.69 -0.077 0.28938E+04 95 jadeite 4.22 2.77 -1.44 -0.144 0.24617E+04 97 kalsilite 7.58 3.83 -3.76 -0.537 0.64126E+04 98 kaolinite -1.33 -4.84 -3.50 -0.319 0.59831E+04 101 laumontite 2.88 1.95 -0.93 -0.062 0.15935E+04 102 lawsonite 9.62 8.26 -1.35 -0.090 0.23070E+04 103 leucite 4.12 0.67 -3.45 -0.345 0.58873E+04 105 lizardite 23.24 21.57 -1.68 -0.140 0.28618E+04 107 magnetite 20.09 15.72 -4.37 -0.356 0.74536E+04 108 minnesotaite 10.39 7.58 -2.81 -0.165 0.48028E+04 112 manganosite 14.06 9.24 -4.82 -1.204 0.82240E+04 120 muscovite 2.58 -1.01 -3.59 -0.211 0.61315E+04 121 paragonite 4.24 1.09 -3.15 -0.185 0.53706E+04 122 nepheline 8.34 5.93 -2.41 -0.344 0.41125E+04 128 periclase-Fe 11.63 6.73 -4.89 -1.223 0.83523E+04 134 phlogopite-Na 29.65 27.50 -2.15 -0.119 0.36677E+04 136 prehnite 19.37 18.21 -1.16 -0.068 0.19849E+04 137 prehnite-Fe 22.50 21.96 -0.53 -0.032 0.91158E+03 138 pumpellyite-Fe 46.27 43.89 -2.38 -0.053 0.40582E+04 139 pumpellyite-Mg 48.99 46.45 -2.54 -0.057 0.43420E+04 143 pyrrhotite -4.26 -7.73 -3.47 -1.158 0.59298E+04 144 pyrrhotiteFe0.875 -6.02 -9.13 -3.11 -1.145 0.53170E+04 145 pyroxmangite 7.40 6.08 -1.31 -0.263 0.22444E+04 146 pyrophyllite -6.18 -11.15 -4.98 -0.311 0.84962E+04 147 quartz -2.99 -3.16 -0.17 -0.056 0.28680E+03 152 rhodonite 7.45 6.08 -1.36 -0.272 0.23247E+04 153 sanidine -1.28 -2.49 -1.21 -0.093 0.20677E+04 165 stilpnomelane-Mg 27.44 25.81 -1.63 -0.049 0.27804E+04 171 talc 16.49 15.25 -1.24 -0.073 0.21140E+04 174 tephroite 18.09 15.33 -2.76 -0.394 0.47126E+04 178 tridymite -2.63 -3.16 -0.53 -0.177 0.90678E+03 179 tremolite 47.87 47.42 -0.45 -0.012 0.77494E+03 180 ferroactinolite 38.45 34.62 -3.83 -0.104 0.65448E+04 181 troilite-low -4.41 -7.73 -3.32 -1.107 0.56726E+04 183 vesuvianite 223.47 218.82 -4.65 -0.036 0.79439E+04 187 wairakite 3.95 1.95 -2.00 -0.118 0.34155E+04 188 walstromite 11.51 9.94 -1.56 -0.313 0.26719E+04 189 wollastonite 10.46 9.94 -0.52 -0.103 0.88229E+03 190 pseudo-wollastonite 11.00 9.94 -1.06 -0.211 0.18021E+04 191 zoisite 22.85 18.95 -3.90 -0.177 0.66609E+04 192 akaganeite 7.75 4.49 -3.26 -0.705 0.55681E+04 199 chalcedony -2.80 -3.16 -0.35 -0.118 0.60610E+03 201 montmorillonite-Ca -2.29 -6.17 -3.88 -0.240 0.66180E+04 202 montmorillonite-K -2.24 -6.27 -4.03 -0.247 0.68816E+04 203 montmorillonite-Mg -2.48 -6.79 -4.32 -0.267 0.73678E+04 204 montmorillonite-Na -2.04 -5.57 -3.54 -0.216 0.60365E+04 205 nontronite-Ca 3.21 -0.19 -3.41 -0.221 0.58215E+04 206 nontronite-H 2.53 -2.36 -4.89 -0.328 0.83485E+04 207 nontronite-K 3.34 -0.30 -3.64 -0.233 0.62083E+04 208 nontronite-Mg 3.07 -0.82 -3.90 -0.253 0.66553E+04 209 nontronite-Na 3.52 0.40 -3.12 -0.200 0.53292E+04 224 tobermorite 9.82 7.76 -2.07 -0.564 0.35287E+04 230 alabandite -0.98 -5.23 -4.25 -1.416 0.72545E+04 233 boehmite 4.41 0.74 -3.67 -0.611 0.62619E+04 235 ferrous-oxide 9.81 6.73 -3.08 -0.769 0.52532E+04 240 silica-amorphous -2.09 -3.16 -1.07 -0.355 0.18203E+04 242 an20ab80 2.02 1.35 -0.67 -0.052 0.11472E+04 243 an25ab75 2.65 1.78 -0.87 -0.067 0.14810E+04 244 an30ab70 3.28 2.21 -1.07 -0.082 0.18244E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 100.0000000 g Current total amount of reactant added: 5299.9990000 g New total amount of reactant added: 5399.9990000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.5222E-10 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 12 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 5399.9990000 Water: Moles liquid = 0.2532E+02 kg liquid = 0.4562E+00 Moles total = -.1218E+02 kg total = -.2195E+00 Activity = 1.0000 Stoichiometric ionic strength = .1145390E-01 Osmotic coef. = 0.9684 True ionic strength = .2011432E-01 Chg. balance for total moles = 0.5222E-10 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.88712E-10 -10.0520 0.74518E-10 -10.1277 0.84000E+00 -0.0757 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.30108E-03 -3.5213 0.25138E-03 -3.5997 0.83493E+00 -0.0783 4 SO4-- 0.14148E-11 -11.8493 0.73381E-12 -12.1344 0.51866E+00 -0.2851 5 HCO3- 0.52339E-06 -6.2812 0.43763E-06 -6.3589 0.83616E+00 -0.0777 6 HS- 0.55900E-04 -4.2526 0.46679E-04 -4.3309 0.83505E+00 -0.0783 7 Al+++ 0.98476E-29 -29.0067 0.22686E-29 -29.6442 0.23037E+00 -0.6376 8 H4SiO4 0.69598E-03 -3.1574 0.69598E-03 -3.1574 0.10000E+01 0.0000 9 Ca++ 0.13636E-06 -6.8653 0.70203E-07 -7.1536 0.51484E+00 -0.2883 10 Mg++ 0.21333E-10 -10.6710 0.10932E-10 -10.9613 0.51247E+00 -0.2903 11 Fe++ 0.58797E-13 -13.2306 0.30165E-13 -13.5205 0.51304E+00 -0.2899 12 K+ 0.15726E-03 -3.8034 0.13152E-03 -3.8810 0.83636E+00 -0.0776 13 Na+ 0.19956E-01 -1.6999 0.16658E-01 -1.7784 0.83478E+00 -0.0784 14 Mn++ 0.18864E-10 -10.7244 0.96862E-11 -11.0138 0.51346E+00 -0.2895 15 HPO4-- 0.44977E-07 -7.3470 0.23331E-07 -7.6321 0.51873E+00 -0.2851 16 HSiO3- 0.10445E-01 -1.9811 0.87209E-02 -2.0594 0.83493E+00 -0.0783 17 Ca(HSiO3)+ 0.16667E-07 -7.7781 0.13943E-07 -7.8556 0.83654E+00 -0.0775 18 Mg(HSiO3)+ 0.32302E-11 -11.4908 0.27022E-11 -11.5683 0.83654E+00 -0.0775 19 NaHSiO3,aq 0.23496E-02 -2.6290 0.23496E-02 -2.6290 0.10000E+01 0.0000 20 AlO+ 0.66439E-16 -16.1776 0.55579E-16 -16.2551 0.83654E+00 -0.0775 22 HAlO2,aq 0.14853E-09 -9.8282 0.14853E-09 -9.8282 0.10000E+01 0.0000 23 AlO2- 0.52941E-05 -5.2762 0.44122E-05 -5.3553 0.83342E+00 -0.0791 24 CH4,aq 0.27137E-04 -4.5664 0.27042E-04 -4.5680 0.99651E+00 -0.0015 25 C2H6,aq 0.10831E-13 -13.9653 0.10793E-13 -13.9668 0.99651E+00 -0.0015 29 CO,aq 0.20275E-16 -16.6930 0.20275E-16 -16.6930 0.10000E+01 0.0000 30 CO2,aq 0.69928E-10 -10.1554 0.69684E-10 -10.1569 0.99651E+00 -0.0015 31 CO3-2 0.99114E-06 -6.0039 0.51297E-06 -6.2899 0.51755E+00 -0.2860 32 CaCO3,aq 0.45155E-09 -9.3453 0.45155E-09 -9.3453 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.93748E-12 -12.0280 0.78424E-12 -12.1056 0.83654E+00 -0.0775 34 CaCl+ 0.34140E-10 -10.4667 0.28559E-10 -10.5443 0.83654E+00 -0.0775 35 CaCl2,aq 0.17056E-14 -14.7681 0.17056E-14 -14.7681 0.10000E+01 0.0000 36 CaOH+ 0.80262E-07 -7.0955 0.67142E-07 -7.1730 0.83654E+00 -0.0775 37 CaSO4,aq 0.16359E-16 -16.7863 0.16359E-16 -16.7863 0.10000E+01 0.0000 38 HCl,aq 0.34326E-14 -14.4644 0.34326E-14 -14.4644 0.10000E+01 0.0000 43 FeCl+ 0.14348E-16 -16.8432 0.12002E-16 -16.9207 0.83654E+00 -0.0775 46 FeO,aq 0.21113E-09 -9.6755 0.21113E-09 -9.6755 0.10000E+01 0.0000 47 FeOH+ 0.15751E-10 -10.8027 0.13177E-10 -10.8802 0.83654E+00 -0.0775 48 HFeO2- 0.35505E-07 -7.4497 0.29644E-07 -7.5281 0.83493E+00 -0.0783 49 FeO+ 0.11039E-16 -16.9571 0.92348E-17 -17.0346 0.83654E+00 -0.0775 51 FeO2- 0.40757E-09 -9.3898 0.34029E-09 -9.4681 0.83493E+00 -0.0783 52 HFeO2,aq 0.32251E-11 -11.4915 0.32251E-11 -11.4915 0.10000E+01 0.0000 53 H2,aq 0.11623E-04 -4.9347 0.11583E-04 -4.9362 0.99651E+00 -0.0015 54 KCl,aq 0.59923E-09 -9.2224 0.59923E-09 -9.2224 0.10000E+01 0.0000 56 KOH,aq 0.75375E-06 -6.1228 0.75375E-06 -6.1228 0.10000E+01 0.0000 57 KSO4- 0.17938E-14 -14.7462 0.14977E-14 -14.8246 0.83493E+00 -0.0783 58 MgCO3,aq 0.17626E-13 -13.7539 0.17626E-13 -13.7539 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.14918E-15 -15.8263 0.12479E-15 -15.9038 0.83654E+00 -0.0775 60 MgCl+ 0.48186E-14 -14.3171 0.40309E-14 -14.3946 0.83654E+00 -0.0775 61 MgOH+ 0.69163E-10 -10.1601 0.57857E-10 -10.2376 0.83654E+00 -0.0775 63 MnO,aq 0.18064E-08 -8.7432 0.18064E-08 -8.7432 0.10000E+01 0.0000 64 MnOH+ 0.46986E-09 -9.3280 0.39306E-09 -9.4055 0.83654E+00 -0.0775 65 MnO2-2 0.20860E-10 -10.6807 0.10796E-10 -10.9667 0.51755E+00 -0.2860 66 HMnO2- 0.21110E-09 -9.6755 0.17625E-09 -9.7539 0.83493E+00 -0.0783 69 MnCl+ 0.17924E-13 -13.7466 0.14994E-13 -13.8241 0.83654E+00 -0.0775 71 NaCl,aq 0.13878E-05 -5.8577 0.13878E-05 -5.8577 0.10000E+01 0.0000 72 NaOH,aq 0.96047E-04 -4.0175 0.96047E-04 -4.0175 0.10000E+01 0.0000 74 OH- 0.93032E-02 -2.0314 0.77534E-02 -2.1105 0.83342E+00 -0.0791 79 HPO3-2 0.16271E-14 -14.7886 0.84213E-15 -15.0746 0.51755E+00 -0.2860 81 H2PO3- 0.15072E-18 -18.8218 0.12584E-18 -18.9002 0.83493E+00 -0.0783 82 H3PO4,aq 0.90611E-18 -18.0428 0.90611E-18 -18.0428 0.10000E+01 0.0000 83 H2PO4- 0.38376E-10 -10.4159 0.32072E-10 -10.4939 0.83572E+00 -0.0779 84 PO4-3 0.10556E-08 -8.9765 0.25545E-09 -9.5927 0.24200E+00 -0.6162 88 HP2O7-3 0.93718E-18 -18.0282 0.21612E-18 -18.6653 0.23060E+00 -0.6371 89 P2O7-4 0.90302E-17 -17.0443 0.69284E-18 -18.1594 0.76725E-01 -1.1151 90 H2S,aq 0.10788E-07 -7.9670 0.10751E-07 -7.9686 0.99651E+00 -0.0015 91 S2-2 0.80542E-14 -14.0940 0.41685E-14 -14.3800 0.51755E+00 -0.2860 97 SO3-2 0.21035E-17 -17.6771 0.11045E-17 -17.9568 0.52507E+00 -0.2798 99 HSO4- 0.62934E-19 -19.2011 0.52698E-19 -19.2782 0.83735E+00 -0.0771 Charge balance for all species = 0.1145E-09 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.8871228E-10 -.2221995E-01 -.2235735E+02 0.0000 2 H2O 0.1000000E+01 0.5550490E+02 0.9981951E+06 0.0000 3 Cl- 0.3010774E-03 0.3024658E-03 0.1070463E+02 6.5281 4 SO4-- 0.1414822E-11 -.3004261E-04 -.2880912E+01 8.1211 5 HCO3- 0.5233868E-06 0.2865194E-04 0.1745215E+01 3.7688 6 HS- 0.5589989E-04 0.8595329E-04 0.2837694E+01 5.7969 7 Al+++ 0.9847564E-29 0.5294240E-05 0.1425976E+00 0.7390 8 H4SiO4 0.6959803E-03 0.1349068E-01 0.1294403E+04 -3.1574 9 Ca++ 0.1363592E-06 0.2337752E-06 0.9352917E-02 13.1018 10 Mg++ 0.2133278E-10 0.9374690E-10 0.2275203E-05 9.2942 11 Fe++ 0.5879679E-13 0.3614261E-07 0.2014939E-02 6.7350 12 K+ 0.1572590E-03 0.1580133E-03 0.6167870E+01 6.2467 13 Na+ 0.1995551E-01 0.2240259E-01 0.5141336E+03 8.3494 14 Mn++ 0.1886443E-10 0.2527126E-08 0.1385933E-03 9.2416 15 HPO4-- 0.4497664E-07 0.4607057E-07 0.4414102E-02 12.6234 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.8941595E+02 -.1013595E-01 -.8940582E+02 0.0000000E+00 2 H2O -.1218295E+02 0.2531937E+02 -.3750232E+02 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.1496779E+00 -.1370438E-04 0.1496916E+00 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.1496524E+00 0.3920885E-04 -.1496916E+00 0.0000000E+00 7 Al+++ 0.1760800E+02 0.2415045E-05 0.1760800E+02 0.0000000E+00 8 H4SiO4 0.5622902E+02 0.6153973E-02 0.5622286E+02 0.0000000E+00 9 Ca++ 0.6210784E+01 0.1066400E-06 0.6210784E+01 0.0000000E+00 10 Mg++ 0.4285713E+01 0.4276401E-10 0.4285713E+01 0.0000000E+00 11 Fe++ 0.3850246E+01 0.1648698E-07 0.3850246E+01 0.0000000E+00 12 K+ 0.1146497E+01 0.7208008E-04 0.1146425E+01 0.0000000E+00 13 Na+ 0.6778474E+01 0.1021927E-01 0.6768255E+01 0.0000000E+00 14 Mn++ 0.9362840E-01 0.1152786E-08 0.9362840E-01 0.0000000E+00 15 HPO4-- 0.3195491E-01 0.2101576E-07 0.3195489E-01 0.0000000E+00 Chg. balance for solid moles: 0.2805E-13 Mass of aqueous solution: 0.456961E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 5399.9990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 6.763 0.830 1773. 3.249 30.06 680.7 andradite 0.5988 -0.223 304.3 2.483 5.158 79.05 grossular 0.1450 -0.839 65.31 1.815 1.107 18.17 apatite-OH 0.1065E-01 -1.973 5.351 0.728 0.9070E-01 1.700 clinochlore 0.7670 -0.115 426.3 2.630 7.227 162.2 daphnite 0.2221 -0.654 158.4 2.200 2.686 48.01 chlorite-Mn 0.1873E-01 -1.728 13.28 1.123 0.2250 4.231 diopside 0.2844 -0.546 61.60 1.790 1.044 18.83 hedenbergite 0.7377E-01 -1.132 18.30 1.262 0.3102 5.013 microcline 1.005 0.002 279.8 2.447 4.743 109.3 stilbite 3.476 0.541 2450. 3.389 41.53 1143. stilpnomelane-Fe 0.2823 -0.549 304.3 2.483 5.158 105.1 tr.625ac.25prg.125 0.4582E-01 -1.339 39.16 1.593 0.6638 12.60 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8051E+00 0.8051E+00 1.0000 -0.094 grossular 0.1949E+00 0.1949E+00 1.0000 -0.710 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.7611E+00 0.7611E+00 1.0000 -0.119 daphnite 0.2203E+00 0.2203E+00 1.0000 -0.657 chlorite-Mn 0.1858E-01 0.1858E-01 1.0000 -1.731 diopside 0.7941E+00 0.7941E+00 1.0000 -0.100 hedenbergite 0.2059E+00 0.2059E+00 1.0000 -0.686 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 tr.625ac.25prg.125 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 5899.340519 g Volume = 2387.590114 cm3 Porosity: -10.4854% V(tot) - V(min): -.22659E+03 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 5399.9990000 g log = 3.7324 Original solution: 1000.0103000 g Original solution / Rock added: 0.19 (Water/Rock Ratio), log = -0.7324 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0756 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9493E+00 0.9852 0.1006E+01 0.1021E+01 CO2,gas 0.6886E-08 1.0066 0.7455E-08 0.7406E-08 CH4,gas 0.3656E-01 1.0122 0.3980E-01 0.3932E-01 H2,gas 0.1413E-01 1.0006 0.1521E-01 0.1520E-01 H2S,gas 0.2759E-06 0.9958 0.2955E-06 0.2968E-06 S2,gas 0.1318E-28 1.0000 0.1418E-28 0.1418E-28 CO,gas 0.2809E-13 1.0000 0.3021E-13 0.3021E-13 SO3,gas 0.1432E-47 1.0000 0.1541E-47 0.1541E-47 SO2,gas 0.8474E-27 1.0000 0.9115E-27 0.9115E-27 HCl,gas 0.5631E-17 1.0000 0.6057E-17 0.6057E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 16 albite -0.38 -0.38 0.00 0.000 -0.94784E-12 22 andradite 39.01 39.01 0.00 0.000 -0.24265E-10 23 grossular 32.73 32.73 0.00 0.000 0.24265E-10 32 apatite-OH -18.15 -18.15 0.00 0.000 0.00000E+00 46 clinochlore 39.07 39.07 0.00 0.000 -0.12132E-10 47 daphnite 28.97 28.97 0.00 0.000 -0.18198E-10 48 chlorite-Mn 46.87 46.87 0.00 0.000 -0.12132E-10 67 diopside 16.18 16.18 0.00 0.000 0.00000E+00 68 hedenbergite 14.21 14.21 0.00 0.000 0.30331E-11 116 microcline -2.49 -2.49 0.00 0.000 0.13649E-10 163 stilbite -7.52 -7.52 0.00 0.000 -0.90992E-11 164 stilpnomelane-Fe 13.02 13.02 0.00 0.000 -0.27298E-10 245 tr.625ac.25prg.125 45.16 45.16 0.00 0.000 0.48529E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -16.49 -9.83 -3.276 0.16778E+05 -8.128 3 CH4,gas 4.54 1.44 -3.10 -0.775 0.52915E+04 -1.400 4 H2,gas 8.00 4.48 -3.52 -2.010 0.60051E+04 -1.818 5 H2S,gas -6.23 -14.46 -8.23 -4.114 0.14050E+05 -6.529 6 S2,gas -7.34 -37.88 -30.55 -4.700 0.52159E+05 -28.848 7 CO,gas 3.21 -12.00 -15.22 -4.683 0.25986E+05 -13.520 8 SO3,gas 17.12 -32.39 -49.51 -12.378 0.84539E+05 -47.812 9 SO2,gas 0.83 -27.91 -28.74 -7.664 0.49071E+05 -27.040 10 HCl,gas 5.19 -13.73 -18.92 -9.458 0.32300E+05 -17.218 11 acmite 7.71 6.53 -1.18 -0.123 0.20175E+04 15 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 19 spessartine 24.46 19.73 -4.73 -0.236 0.80707E+04 20 analcite 3.32 2.77 -0.55 -0.061 0.93625E+03 26 annite 20.12 17.72 -2.40 -0.134 0.41064E+04 27 phlogopite 27.06 25.40 -1.67 -0.093 0.28489E+04 29 anorthite 12.71 8.26 -4.45 -0.342 0.75903E+04 35 aragonite 0.97 -3.38 -4.35 -1.450 0.74298E+04 36 brucite 12.57 9.29 -3.27 -0.655 0.55909E+04 37 calcite 0.81 -3.38 -4.20 -1.399 0.71655E+04 38 carnegieite-low 9.02 5.93 -3.09 -0.442 0.52801E+04 39 carnegieite-high 10.09 5.93 -4.16 -0.595 0.71071E+04 40 carpholite-Mg 8.58 4.46 -4.12 -0.275 0.70429E+04 41 carpholite-Fe 6.71 1.90 -4.81 -0.321 0.82207E+04 42 celadonite 5.34 3.65 -1.69 -0.099 0.28879E+04 43 celadonite-Fe 3.88 1.09 -2.79 -0.164 0.47561E+04 44 chrysotile 23.89 21.57 -2.32 -0.194 0.39692E+04 49 chlorite-Al-free 47.17 43.14 -4.04 -0.168 0.68936E+04 51 chloritoid-Fe 9.17 5.06 -4.12 -0.275 0.70316E+04 52 chloritoid-Mn 11.40 7.56 -3.84 -0.256 0.65548E+04 54 coesite -2.38 -3.16 -0.78 -0.260 0.13341E+04 61 cristobalite -2.56 -3.16 -0.60 -0.199 0.10195E+04 63 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71234E+04 65 diaspore 2.87 0.74 -2.13 -0.356 0.36450E+04 66 diamond -3.10 -7.52 -4.42 -1.262 0.75446E+04 71 enstatite 17.26 12.27 -4.99 -0.499 0.85226E+04 73 clinoenstatite 17.17 12.27 -4.89 -0.489 0.83541E+04 75 epidote 24.67 22.70 -1.97 -0.095 0.33585E+04 76 clinozoisite 22.81 18.95 -3.86 -0.175 0.65869E+04 77 epidote-Fe 29.84 26.46 -3.38 -0.176 0.57768E+04 78 fayalite 14.05 10.31 -3.73 -0.533 0.63743E+04 79 ferrosilite 11.15 7.16 -3.99 -0.399 0.68202E+04 83 gibbsite 4.08 0.74 -3.34 -0.477 0.57035E+04 84 glaucophane 22.97 20.80 -2.17 -0.059 0.37134E+04 85 glaucophane-Fe 17.28 13.12 -4.15 -0.112 0.70919E+04 86 graphite -3.55 -7.52 -3.97 -1.136 0.67869E+04 87 greenalite 16.14 13.89 -2.25 -0.187 0.38408E+04 90 hematite 12.57 8.99 -3.58 -0.434 0.61111E+04 91 heulandite -5.83 -7.52 -1.69 -0.077 0.28938E+04 95 jadeite 4.22 2.77 -1.44 -0.144 0.24617E+04 97 kalsilite 7.58 3.83 -3.76 -0.537 0.64126E+04 98 kaolinite -1.33 -4.84 -3.50 -0.319 0.59832E+04 101 laumontite 2.88 1.95 -0.93 -0.062 0.15935E+04 102 lawsonite 9.62 8.26 -1.35 -0.090 0.23070E+04 103 leucite 4.12 0.67 -3.45 -0.345 0.58873E+04 105 lizardite 23.24 21.57 -1.68 -0.140 0.28618E+04 107 magnetite 20.09 15.72 -4.37 -0.356 0.74536E+04 108 minnesotaite 10.39 7.58 -2.81 -0.165 0.48028E+04 112 manganosite 14.06 9.24 -4.82 -1.204 0.82240E+04 120 muscovite 2.58 -1.01 -3.59 -0.211 0.61315E+04 121 paragonite 4.24 1.09 -3.15 -0.185 0.53706E+04 122 nepheline 8.34 5.93 -2.41 -0.344 0.41125E+04 128 periclase-Fe 11.63 6.73 -4.89 -1.223 0.83523E+04 134 phlogopite-Na 29.65 27.50 -2.15 -0.119 0.36677E+04 136 prehnite 19.37 18.21 -1.16 -0.068 0.19849E+04 137 prehnite-Fe 22.50 21.96 -0.53 -0.032 0.91158E+03 138 pumpellyite-Fe 46.27 43.89 -2.38 -0.053 0.40582E+04 139 pumpellyite-Mg 48.99 46.45 -2.54 -0.057 0.43420E+04 143 pyrrhotite -4.26 -7.72 -3.46 -1.154 0.59135E+04 144 pyrrhotiteFe0.875 -6.02 -9.12 -3.10 -1.142 0.53007E+04 145 pyroxmangite 7.40 6.08 -1.31 -0.263 0.22444E+04 146 pyrophyllite -6.18 -11.15 -4.98 -0.311 0.84962E+04 147 quartz -2.99 -3.16 -0.17 -0.056 0.28680E+03 152 rhodonite 7.45 6.08 -1.36 -0.272 0.23246E+04 153 sanidine -1.28 -2.49 -1.21 -0.093 0.20677E+04 165 stilpnomelane-Mg 27.44 25.81 -1.63 -0.049 0.27804E+04 171 talc 16.49 15.25 -1.24 -0.073 0.21140E+04 174 tephroite 18.09 15.33 -2.76 -0.394 0.47125E+04 178 tridymite -2.63 -3.16 -0.53 -0.177 0.90678E+03 179 tremolite 47.87 47.42 -0.45 -0.012 0.77494E+03 180 ferroactinolite 38.45 34.62 -3.83 -0.104 0.65448E+04 181 troilite-low -4.41 -7.72 -3.31 -1.104 0.56563E+04 183 vesuvianite 223.47 218.82 -4.65 -0.036 0.79439E+04 187 wairakite 3.95 1.95 -2.00 -0.118 0.34155E+04 188 walstromite 11.51 9.94 -1.56 -0.313 0.26719E+04 189 wollastonite 10.46 9.94 -0.52 -0.103 0.88229E+03 190 pseudo-wollastonite 11.00 9.94 -1.06 -0.211 0.18021E+04 191 zoisite 22.85 18.95 -3.90 -0.177 0.66609E+04 192 akaganeite 7.75 4.49 -3.26 -0.705 0.55681E+04 199 chalcedony -2.80 -3.16 -0.35 -0.118 0.60610E+03 201 montmorillonite-Ca -2.29 -6.17 -3.88 -0.240 0.66180E+04 202 montmorillonite-K -2.24 -6.27 -4.03 -0.247 0.68816E+04 203 montmorillonite-Mg -2.48 -6.79 -4.32 -0.267 0.73678E+04 204 montmorillonite-Na -2.04 -5.57 -3.54 -0.216 0.60365E+04 205 nontronite-Ca 3.21 -0.19 -3.41 -0.221 0.58215E+04 206 nontronite-H 2.53 -2.36 -4.89 -0.328 0.83485E+04 207 nontronite-K 3.34 -0.30 -3.64 -0.233 0.62083E+04 208 nontronite-Mg 3.07 -0.82 -3.90 -0.253 0.66553E+04 209 nontronite-Na 3.52 0.40 -3.12 -0.200 0.53292E+04 224 tobermorite 9.82 7.76 -2.07 -0.564 0.35287E+04 230 alabandite -0.98 -5.22 -4.24 -1.413 0.72382E+04 233 boehmite 4.41 0.74 -3.67 -0.611 0.62619E+04 235 ferrous-oxide 9.81 6.73 -3.08 -0.769 0.52532E+04 240 silica-amorphous -2.09 -3.16 -1.07 -0.355 0.18203E+04 242 an20ab80 2.02 1.35 -0.67 -0.052 0.11472E+04 243 an25ab75 2.65 1.78 -0.87 -0.067 0.14810E+04 244 an30ab70 3.28 2.21 -1.07 -0.082 0.18244E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 100.0000000 g Current total amount of reactant added: 5399.9990000 g New total amount of reactant added: 5499.9990000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.5221E-10 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 12 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 5499.9990000 Water: Moles liquid = 0.2476E+02 kg liquid = 0.4461E+00 Moles total = -.1344E+02 kg total = -.2421E+00 Activity = 1.0000 Stoichiometric ionic strength = .1145954E-01 Osmotic coef. = 0.9684 True ionic strength = .2011872E-01 Chg. balance for total moles = 0.5221E-10 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.88731E-10 -10.0519 0.74533E-10 -10.1276 0.83999E+00 -0.0757 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.30785E-03 -3.5117 0.25703E-03 -3.5900 0.83492E+00 -0.0784 4 SO4-- 0.14464E-11 -11.8397 0.75017E-12 -12.1248 0.51863E+00 -0.2851 5 HCO3- 0.53508E-06 -6.2716 0.44740E-06 -6.3493 0.83614E+00 -0.0777 6 HS- 0.57158E-04 -4.2429 0.47729E-04 -4.3212 0.83504E+00 -0.0783 7 Al+++ 0.98548E-29 -29.0064 0.22700E-29 -29.6440 0.23034E+00 -0.6376 8 H4SiO4 0.69598E-03 -3.1574 0.69598E-03 -3.1574 0.10000E+01 0.0000 9 Ca++ 0.13642E-06 -6.8651 0.70231E-07 -7.1535 0.51481E+00 -0.2884 10 Mg++ 0.21343E-10 -10.6708 0.10937E-10 -10.9611 0.51244E+00 -0.2904 11 Fe++ 0.58824E-13 -13.2304 0.30177E-13 -13.5203 0.51301E+00 -0.2899 12 K+ 0.15729E-03 -3.8033 0.13155E-03 -3.8809 0.83634E+00 -0.0776 13 Na+ 0.19960E-01 -1.6998 0.16662E-01 -1.7783 0.83477E+00 -0.0784 14 Mn++ 0.18874E-10 -10.7241 0.96904E-11 -11.0137 0.51343E+00 -0.2895 15 HPO4-- 0.44961E-07 -7.3472 0.23321E-07 -7.6322 0.51870E+00 -0.2851 16 HSiO3- 0.10443E-01 -1.9812 0.87191E-02 -2.0595 0.83492E+00 -0.0784 17 Ca(HSiO3)+ 0.16671E-07 -7.7780 0.13946E-07 -7.8556 0.83652E+00 -0.0775 18 Mg(HSiO3)+ 0.32309E-11 -11.4907 0.27027E-11 -11.5682 0.83652E+00 -0.0775 19 NaHSiO3,aq 0.23496E-02 -2.6290 0.23496E-02 -2.6290 0.10000E+01 0.0000 20 AlO+ 0.66454E-16 -16.1775 0.55590E-16 -16.2550 0.83652E+00 -0.0775 22 HAlO2,aq 0.14853E-09 -9.8282 0.14853E-09 -9.8282 0.10000E+01 0.0000 23 AlO2- 0.52931E-05 -5.2763 0.44113E-05 -5.3554 0.83340E+00 -0.0791 24 CH4,aq 0.27748E-04 -4.5568 0.27651E-04 -4.5583 0.99651E+00 -0.0015 25 C2H6,aq 0.11325E-13 -13.9460 0.11285E-13 -13.9475 0.99651E+00 -0.0015 29 CO,aq 0.20732E-16 -16.6834 0.20732E-16 -16.6834 0.10000E+01 0.0000 30 CO2,aq 0.71503E-10 -10.1457 0.71253E-10 -10.1472 0.99651E+00 -0.0015 31 CO3-2 0.10131E-05 -5.9943 0.52431E-06 -6.2804 0.51752E+00 -0.2861 32 CaCO3,aq 0.46172E-09 -9.3356 0.46172E-09 -9.3356 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.95881E-12 -12.0183 0.80207E-12 -12.0958 0.83652E+00 -0.0775 34 CaCl+ 0.34922E-10 -10.4569 0.29213E-10 -10.5344 0.83652E+00 -0.0775 35 CaCl2,aq 0.17839E-14 -14.7486 0.17839E-14 -14.7486 0.10000E+01 0.0000 36 CaOH+ 0.80279E-07 -7.0954 0.67156E-07 -7.1729 0.83652E+00 -0.0775 37 CaSO4,aq 0.16730E-16 -16.7765 0.16730E-16 -16.7765 0.10000E+01 0.0000 38 HCl,aq 0.35105E-14 -14.4546 0.35105E-14 -14.4546 0.10000E+01 0.0000 43 FeCl+ 0.14677E-16 -16.8334 0.12277E-16 -16.9109 0.83652E+00 -0.0775 46 FeO,aq 0.21113E-09 -9.6755 0.21113E-09 -9.6755 0.10000E+01 0.0000 47 FeOH+ 0.15755E-10 -10.8026 0.13179E-10 -10.8801 0.83652E+00 -0.0775 48 HFeO2- 0.35498E-07 -7.4498 0.29638E-07 -7.5281 0.83492E+00 -0.0784 49 FeO+ 0.11042E-16 -16.9570 0.92367E-17 -17.0345 0.83652E+00 -0.0775 51 FeO2- 0.40749E-09 -9.3899 0.34022E-09 -9.4682 0.83492E+00 -0.0784 52 HFeO2,aq 0.32251E-11 -11.4915 0.32251E-11 -11.4915 0.10000E+01 0.0000 53 H2,aq 0.11623E-04 -4.9347 0.11582E-04 -4.9362 0.99651E+00 -0.0015 54 KCl,aq 0.61283E-09 -9.2127 0.61283E-09 -9.2127 0.10000E+01 0.0000 56 KOH,aq 0.75375E-06 -6.1228 0.75375E-06 -6.1228 0.10000E+01 0.0000 57 KSO4- 0.18341E-14 -14.7366 0.15314E-14 -14.8149 0.83492E+00 -0.0784 58 MgCO3,aq 0.18023E-13 -13.7442 0.18023E-13 -13.7442 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.15257E-15 -15.8165 0.12763E-15 -15.8941 0.83652E+00 -0.0775 60 MgCl+ 0.49290E-14 -14.3072 0.41233E-14 -14.3848 0.83652E+00 -0.0775 61 MgOH+ 0.69178E-10 -10.1600 0.57869E-10 -10.2376 0.83652E+00 -0.0775 63 MnO,aq 0.18065E-08 -8.7432 0.18065E-08 -8.7432 0.10000E+01 0.0000 64 MnOH+ 0.46998E-09 -9.3279 0.39315E-09 -9.4054 0.83652E+00 -0.0775 65 MnO2-2 0.20853E-10 -10.6808 0.10792E-10 -10.9669 0.51752E+00 -0.2861 66 HMnO2- 0.21107E-09 -9.6756 0.17622E-09 -9.7539 0.83492E+00 -0.0784 69 MnCl+ 0.18335E-13 -13.7367 0.15338E-13 -13.8142 0.83652E+00 -0.0775 71 NaCl,aq 0.14193E-05 -5.8479 0.14193E-05 -5.8479 0.10000E+01 0.0000 72 NaOH,aq 0.96047E-04 -4.0175 0.96047E-04 -4.0175 0.10000E+01 0.0000 74 OH- 0.93014E-02 -2.0314 0.77519E-02 -2.1106 0.83340E+00 -0.0791 79 HPO3-2 0.16266E-14 -14.7887 0.84179E-15 -15.0748 0.51752E+00 -0.2861 81 H2PO3- 0.15069E-18 -18.8219 0.12581E-18 -18.9003 0.83492E+00 -0.0784 82 H3PO4,aq 0.90611E-18 -18.0428 0.90611E-18 -18.0428 0.10000E+01 0.0000 83 H2PO4- 0.38369E-10 -10.4160 0.32066E-10 -10.4940 0.83571E+00 -0.0779 84 PO4-3 0.10550E-08 -8.9767 0.25529E-09 -9.5930 0.24197E+00 -0.6162 88 HP2O7-3 0.93673E-18 -18.0284 0.21599E-18 -18.6656 0.23057E+00 -0.6372 89 P2O7-4 0.90249E-17 -17.0446 0.69228E-18 -18.1597 0.76708E-01 -1.1152 90 H2S,aq 0.11033E-07 -7.9573 0.10995E-07 -7.9588 0.99651E+00 -0.0015 91 S2-2 0.84212E-14 -14.0746 0.43582E-14 -14.3607 0.51752E+00 -0.2861 97 SO3-2 0.21505E-17 -17.6675 0.11291E-17 -17.9473 0.52504E+00 -0.2798 99 HSO4- 0.64351E-19 -19.1914 0.53884E-19 -19.2685 0.83734E+00 -0.0771 Charge balance for all species = 0.1171E-09 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.8873150E-10 -.2221626E-01 -.2235363E+02 0.0000 2 H2O 0.1000000E+01 0.5550491E+02 0.9981949E+06 0.0000 3 Cl- 0.3078547E-03 0.3092746E-03 0.1094560E+02 6.5376 4 SO4-- 0.1446443E-11 -.3065392E-04 -.2939533E+01 8.1305 5 HCO3- 0.5350770E-06 0.2929692E-04 0.1784501E+01 3.7783 6 HS- 0.5715824E-04 0.8782320E-04 0.2899427E+01 5.8064 7 Al+++ 0.9854843E-29 0.5293240E-05 0.1425707E+00 0.7390 8 H4SiO4 0.6959806E-03 0.1348872E-01 0.1294215E+04 -3.1574 9 Ca++ 0.1364225E-06 0.2338705E-06 0.9356728E-02 13.1018 10 Mg++ 0.2134270E-10 0.9377476E-10 0.2275879E-05 9.2942 11 Fe++ 0.5882414E-13 0.3613585E-07 0.2014562E-02 6.7350 12 K+ 0.1572932E-03 0.1580475E-03 0.6169204E+01 6.2467 13 Na+ 0.1995985E-01 0.2240696E-01 0.5142339E+03 8.3494 14 Mn++ 0.1887376E-10 0.2527266E-08 0.1386010E-03 9.2416 15 HPO4-- 0.4496098E-07 0.4605440E-07 0.4412552E-02 12.6231 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.9107181E+02 -.9911160E-02 -.9106189E+02 0.0000000E+00 2 H2O -.1343649E+02 0.2476196E+02 -.3819845E+02 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.1524492E+00 -.1367539E-04 0.1524629E+00 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.1524237E+00 0.3917986E-04 -.1524629E+00 0.0000000E+00 7 Al+++ 0.1793408E+02 0.2361430E-05 0.1793407E+02 0.0000000E+00 8 H4SiO4 0.5727030E+02 0.6017615E-02 0.5726428E+02 0.0000000E+00 9 Ca++ 0.6325798E+01 0.1043348E-06 0.6325798E+01 0.0000000E+00 10 Mg++ 0.4365079E+01 0.4183498E-10 0.4365079E+01 0.0000000E+00 11 Fe++ 0.3921547E+01 0.1612100E-07 0.3921547E+01 0.0000000E+00 12 K+ 0.1167728E+01 0.7050847E-04 0.1167658E+01 0.0000000E+00 13 Na+ 0.6903999E+01 0.9996239E-02 0.6894003E+01 0.0000000E+00 14 Mn++ 0.9536226E-01 0.1127469E-08 0.9536226E-01 0.0000000E+00 15 HPO4-- 0.3254667E-01 0.2054588E-07 0.3254664E-01 0.0000000E+00 Chg. balance for solid moles: 0.3067E-14 Mass of aqueous solution: 0.446901E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 5499.9990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 6.888 0.838 1806. 3.257 30.06 693.4 andradite 0.6099 -0.215 309.9 2.491 5.158 80.52 grossular 0.1477 -0.831 66.52 1.823 1.107 18.51 apatite-OH 0.1085E-01 -1.965 5.450 0.736 0.9070E-01 1.732 clinochlore 0.7812 -0.107 434.2 2.638 7.227 165.2 daphnite 0.2262 -0.646 161.4 2.208 2.686 48.90 chlorite-Mn 0.1907E-01 -1.720 13.52 1.131 0.2250 4.309 diopside 0.2899 -0.538 62.78 1.798 1.045 19.19 hedenbergite 0.7518E-01 -1.124 18.65 1.271 0.3104 5.109 microcline 1.024 0.010 285.0 2.455 4.743 111.3 stilbite 3.541 0.549 2495. 3.397 41.53 1164. stilpnomelane-Fe 0.2875 -0.541 309.9 2.491 5.158 107.1 tr.625ac.25prg.125 0.4665E-01 -1.331 39.87 1.601 0.6636 12.83 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8051E+00 0.8051E+00 1.0000 -0.094 grossular 0.1949E+00 0.1949E+00 1.0000 -0.710 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.7611E+00 0.7611E+00 1.0000 -0.119 daphnite 0.2203E+00 0.2203E+00 1.0000 -0.657 chlorite-Mn 0.1858E-01 0.1858E-01 1.0000 -1.731 diopside 0.7941E+00 0.7941E+00 1.0000 -0.100 hedenbergite 0.2059E+00 0.2059E+00 1.0000 -0.686 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 tr.625ac.25prg.125 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 6008.591184 g Volume = 2431.793178 cm3 Porosity: -10.4859% V(tot) - V(min): -.23079E+03 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 5499.9990000 g log = 3.7404 Original solution: 1000.0103000 g Original solution / Rock added: 0.18 (Water/Rock Ratio), log = -0.7404 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0765 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9485E+00 0.9852 0.1006E+01 0.1021E+01 CO2,gas 0.7035E-08 1.0066 0.7623E-08 0.7573E-08 CH4,gas 0.3735E-01 1.0122 0.4070E-01 0.4021E-01 H2,gas 0.1412E-01 1.0006 0.1521E-01 0.1520E-01 H2S,gas 0.2819E-06 0.9958 0.3022E-06 0.3035E-06 S2,gas 0.1377E-28 1.0000 0.1483E-28 0.1483E-28 CO,gas 0.2870E-13 1.0000 0.3089E-13 0.3089E-13 SO3,gas 0.1464E-47 1.0000 0.1576E-47 0.1576E-47 SO2,gas 0.8660E-27 1.0000 0.9322E-27 0.9322E-27 HCl,gas 0.5754E-17 1.0000 0.6194E-17 0.6194E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 16 albite -0.38 -0.38 0.00 0.000 0.11184E-10 22 andradite 39.01 39.01 0.00 0.000 -0.12132E-10 23 grossular 32.73 32.73 0.00 0.000 -0.12132E-10 32 apatite-OH -18.15 -18.15 0.00 0.000 0.12132E-10 46 clinochlore 39.07 39.07 0.00 0.000 0.00000E+00 47 daphnite 28.97 28.97 0.00 0.000 0.36397E-10 48 chlorite-Mn 46.87 46.87 0.00 0.000 -0.24265E-10 67 diopside 16.18 16.18 0.00 0.000 0.60662E-11 68 hedenbergite 14.21 14.21 0.00 0.000 0.30331E-11 116 microcline -2.49 -2.49 0.00 0.000 0.15165E-11 163 stilbite -7.52 -7.52 0.00 0.000 0.15165E-10 164 stilpnomelane-Fe 13.02 13.02 0.00 0.000 0.21232E-10 245 tr.625ac.25prg.125 45.16 45.16 0.00 0.000 0.24265E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -16.48 -9.82 -3.272 0.16762E+05 -8.118 3 CH4,gas 4.54 1.45 -3.09 -0.772 0.52750E+04 -1.390 4 H2,gas 8.00 4.48 -3.52 -2.010 0.60051E+04 -1.818 5 H2S,gas -6.23 -14.45 -8.22 -4.109 0.14033E+05 -6.520 6 S2,gas -7.34 -37.86 -30.53 -4.697 0.52126E+05 -28.829 7 CO,gas 3.21 -11.99 -15.21 -4.680 0.25969E+05 -13.510 8 SO3,gas 17.12 -32.38 -49.50 -12.375 0.84522E+05 -47.803 9 SO2,gas 0.83 -27.90 -28.73 -7.661 0.49055E+05 -27.030 10 HCl,gas 5.19 -13.72 -18.91 -9.453 0.32283E+05 -17.208 11 acmite 7.71 6.53 -1.18 -0.123 0.20175E+04 15 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 19 spessartine 24.46 19.73 -4.73 -0.236 0.80707E+04 20 analcite 3.32 2.77 -0.55 -0.061 0.93625E+03 26 annite 20.12 17.72 -2.40 -0.134 0.41064E+04 27 phlogopite 27.06 25.40 -1.67 -0.093 0.28489E+04 29 anorthite 12.71 8.26 -4.45 -0.342 0.75903E+04 35 aragonite 0.97 -3.38 -4.34 -1.447 0.74132E+04 36 brucite 12.57 9.29 -3.27 -0.655 0.55909E+04 37 calcite 0.81 -3.38 -4.19 -1.396 0.71490E+04 38 carnegieite-low 9.02 5.93 -3.09 -0.442 0.52801E+04 39 carnegieite-high 10.09 5.93 -4.16 -0.595 0.71071E+04 40 carpholite-Mg 8.58 4.46 -4.12 -0.275 0.70429E+04 41 carpholite-Fe 6.71 1.90 -4.81 -0.321 0.82207E+04 42 celadonite 5.34 3.65 -1.69 -0.099 0.28879E+04 43 celadonite-Fe 3.88 1.09 -2.79 -0.164 0.47561E+04 44 chrysotile 23.89 21.57 -2.32 -0.194 0.39692E+04 49 chlorite-Al-free 47.17 43.14 -4.04 -0.168 0.68936E+04 51 chloritoid-Fe 9.17 5.06 -4.12 -0.275 0.70316E+04 52 chloritoid-Mn 11.40 7.56 -3.84 -0.256 0.65548E+04 54 coesite -2.38 -3.16 -0.78 -0.260 0.13341E+04 61 cristobalite -2.56 -3.16 -0.60 -0.199 0.10195E+04 63 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71234E+04 65 diaspore 2.87 0.74 -2.13 -0.356 0.36450E+04 66 diamond -3.10 -7.51 -4.41 -1.260 0.75281E+04 71 enstatite 17.26 12.27 -4.99 -0.499 0.85226E+04 73 clinoenstatite 17.17 12.27 -4.89 -0.489 0.83541E+04 75 epidote 24.67 22.70 -1.97 -0.095 0.33585E+04 76 clinozoisite 22.81 18.95 -3.86 -0.175 0.65869E+04 77 epidote-Fe 29.84 26.46 -3.38 -0.176 0.57768E+04 78 fayalite 14.05 10.31 -3.73 -0.533 0.63743E+04 79 ferrosilite 11.15 7.16 -3.99 -0.399 0.68202E+04 83 gibbsite 4.08 0.74 -3.34 -0.477 0.57035E+04 84 glaucophane 22.97 20.80 -2.17 -0.059 0.37134E+04 85 glaucophane-Fe 17.28 13.12 -4.15 -0.112 0.70919E+04 86 graphite -3.55 -7.51 -3.97 -1.133 0.67704E+04 87 greenalite 16.14 13.89 -2.25 -0.187 0.38408E+04 90 hematite 12.57 8.99 -3.58 -0.434 0.61111E+04 91 heulandite -5.83 -7.52 -1.69 -0.077 0.28938E+04 95 jadeite 4.22 2.77 -1.44 -0.144 0.24617E+04 97 kalsilite 7.58 3.83 -3.76 -0.537 0.64126E+04 98 kaolinite -1.33 -4.84 -3.50 -0.319 0.59832E+04 101 laumontite 2.88 1.95 -0.93 -0.062 0.15935E+04 102 lawsonite 9.62 8.26 -1.35 -0.090 0.23070E+04 103 leucite 4.12 0.67 -3.45 -0.345 0.58873E+04 105 lizardite 23.24 21.57 -1.68 -0.140 0.28618E+04 107 magnetite 20.09 15.72 -4.37 -0.356 0.74536E+04 108 minnesotaite 10.39 7.58 -2.81 -0.165 0.48028E+04 112 manganosite 14.06 9.24 -4.82 -1.204 0.82240E+04 120 muscovite 2.58 -1.01 -3.59 -0.211 0.61315E+04 121 paragonite 4.24 1.09 -3.15 -0.185 0.53706E+04 122 nepheline 8.34 5.93 -2.41 -0.344 0.41125E+04 128 periclase-Fe 11.63 6.73 -4.89 -1.223 0.83523E+04 134 phlogopite-Na 29.65 27.50 -2.15 -0.119 0.36677E+04 136 prehnite 19.37 18.21 -1.16 -0.068 0.19849E+04 137 prehnite-Fe 22.50 21.96 -0.53 -0.032 0.91158E+03 138 pumpellyite-Fe 46.27 43.89 -2.38 -0.053 0.40582E+04 139 pumpellyite-Mg 48.99 46.45 -2.54 -0.057 0.43420E+04 143 pyrrhotite -4.26 -7.71 -3.45 -1.151 0.58969E+04 144 pyrrhotiteFe0.875 -6.02 -9.11 -3.09 -1.138 0.52841E+04 145 pyroxmangite 7.40 6.08 -1.31 -0.263 0.22444E+04 146 pyrophyllite -6.18 -11.15 -4.98 -0.311 0.84962E+04 147 quartz -2.99 -3.16 -0.17 -0.056 0.28680E+03 152 rhodonite 7.45 6.08 -1.36 -0.272 0.23246E+04 153 sanidine -1.28 -2.49 -1.21 -0.093 0.20677E+04 165 stilpnomelane-Mg 27.44 25.81 -1.63 -0.049 0.27804E+04 171 talc 16.49 15.25 -1.24 -0.073 0.21140E+04 174 tephroite 18.09 15.33 -2.76 -0.394 0.47125E+04 178 tridymite -2.63 -3.16 -0.53 -0.177 0.90678E+03 179 tremolite 47.87 47.42 -0.45 -0.012 0.77494E+03 180 ferroactinolite 38.45 34.62 -3.83 -0.104 0.65448E+04 181 troilite-low -4.41 -7.71 -3.30 -1.101 0.56397E+04 183 vesuvianite 223.47 218.82 -4.65 -0.036 0.79439E+04 187 wairakite 3.95 1.95 -2.00 -0.118 0.34155E+04 188 walstromite 11.51 9.94 -1.56 -0.313 0.26719E+04 189 wollastonite 10.46 9.94 -0.52 -0.103 0.88229E+03 190 pseudo-wollastonite 11.00 9.94 -1.06 -0.211 0.18021E+04 191 zoisite 22.85 18.95 -3.90 -0.177 0.66609E+04 192 akaganeite 7.75 4.49 -3.26 -0.705 0.55681E+04 199 chalcedony -2.80 -3.16 -0.35 -0.118 0.60610E+03 201 montmorillonite-Ca -2.29 -6.17 -3.88 -0.240 0.66180E+04 202 montmorillonite-K -2.24 -6.27 -4.03 -0.247 0.68816E+04 203 montmorillonite-Mg -2.48 -6.79 -4.32 -0.267 0.73678E+04 204 montmorillonite-Na -2.04 -5.57 -3.54 -0.216 0.60365E+04 205 nontronite-Ca 3.21 -0.19 -3.41 -0.221 0.58215E+04 206 nontronite-H 2.53 -2.36 -4.89 -0.328 0.83485E+04 207 nontronite-K 3.34 -0.30 -3.64 -0.233 0.62083E+04 208 nontronite-Mg 3.07 -0.82 -3.90 -0.253 0.66553E+04 209 nontronite-Na 3.52 0.40 -3.12 -0.200 0.53292E+04 224 tobermorite 9.82 7.76 -2.07 -0.564 0.35287E+04 230 alabandite -0.98 -5.21 -4.23 -1.410 0.72215E+04 233 boehmite 4.41 0.74 -3.67 -0.611 0.62619E+04 235 ferrous-oxide 9.81 6.73 -3.08 -0.769 0.52532E+04 240 silica-amorphous -2.09 -3.16 -1.07 -0.355 0.18203E+04 242 an20ab80 2.02 1.35 -0.67 -0.052 0.11472E+04 243 an25ab75 2.65 1.78 -0.87 -0.067 0.14810E+04 244 an30ab70 3.28 2.21 -1.07 -0.082 0.18244E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 100.0000000 g Current total amount of reactant added: 5499.9990000 g New total amount of reactant added: 5599.9990000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.5222E-10 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 12 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 5599.9990000 Water: Moles liquid = 0.2421E+02 kg liquid = 0.4361E+00 Moles total = -.1469E+02 kg total = -.2646E+00 Activity = 1.0000 Stoichiometric ionic strength = .1146544E-01 Osmotic coef. = 0.9684 True ionic strength = .2012332E-01 Chg. balance for total moles = 0.5222E-10 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.88752E-10 -10.0518 0.74549E-10 -10.1276 0.83998E+00 -0.0757 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.31494E-03 -3.5018 0.26295E-03 -3.5801 0.83491E+00 -0.0784 4 SO4-- 0.14795E-11 -11.8299 0.76727E-12 -12.1151 0.51860E+00 -0.2852 5 HCO3- 0.54730E-06 -6.2618 0.45762E-06 -6.3395 0.83613E+00 -0.0777 6 HS- 0.58475E-04 -4.2330 0.48828E-04 -4.3113 0.83503E+00 -0.0783 7 Al+++ 0.98625E-29 -29.0060 0.22714E-29 -29.6437 0.23031E+00 -0.6377 8 H4SiO4 0.69598E-03 -3.1574 0.69598E-03 -3.1574 0.10000E+01 0.0000 9 Ca++ 0.13649E-06 -6.8649 0.70261E-07 -7.1533 0.51478E+00 -0.2884 10 Mg++ 0.21353E-10 -10.6705 0.10942E-10 -10.9609 0.51241E+00 -0.2904 11 Fe++ 0.58853E-13 -13.2302 0.30190E-13 -13.5201 0.51297E+00 -0.2899 12 K+ 0.15733E-03 -3.8032 0.13158E-03 -3.8808 0.83633E+00 -0.0776 13 Na+ 0.19964E-01 -1.6997 0.16665E-01 -1.7782 0.83475E+00 -0.0784 14 Mn++ 0.18883E-10 -10.7239 0.96948E-11 -11.0135 0.51340E+00 -0.2895 15 HPO4-- 0.44945E-07 -7.3473 0.23312E-07 -7.6324 0.51867E+00 -0.2851 16 HSiO3- 0.10441E-01 -1.9813 0.87173E-02 -2.0596 0.83491E+00 -0.0784 17 Ca(HSiO3)+ 0.16675E-07 -7.7779 0.13949E-07 -7.8555 0.83651E+00 -0.0775 18 Mg(HSiO3)+ 0.32316E-11 -11.4906 0.27033E-11 -11.5681 0.83651E+00 -0.0775 19 NaHSiO3,aq 0.23496E-02 -2.6290 0.23496E-02 -2.6290 0.10000E+01 0.0000 20 AlO+ 0.66469E-16 -16.1774 0.55602E-16 -16.2549 0.83651E+00 -0.0775 22 HAlO2,aq 0.14853E-09 -9.8282 0.14853E-09 -9.8282 0.10000E+01 0.0000 23 AlO2- 0.52920E-05 -5.2764 0.44103E-05 -5.3555 0.83339E+00 -0.0792 24 CH4,aq 0.28388E-04 -4.5469 0.28288E-04 -4.5484 0.99650E+00 -0.0015 25 C2H6,aq 0.11853E-13 -13.9262 0.11811E-13 -13.9277 0.99650E+00 -0.0015 29 CO,aq 0.21210E-16 -16.6735 0.21210E-16 -16.6735 0.10000E+01 0.0000 30 CO2,aq 0.73151E-10 -10.1358 0.72896E-10 -10.1373 0.99650E+00 -0.0015 31 CO3-2 0.10361E-05 -5.9846 0.53617E-06 -6.2707 0.51749E+00 -0.2861 32 CaCO3,aq 0.47236E-09 -9.3257 0.47236E-09 -9.3257 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.98113E-12 -12.0083 0.82073E-12 -12.0858 0.83651E+00 -0.0775 34 CaCl+ 0.35742E-10 -10.4468 0.29898E-10 -10.5244 0.83651E+00 -0.0775 35 CaCl2,aq 0.18678E-14 -14.7287 0.18678E-14 -14.7287 0.10000E+01 0.0000 36 CaOH+ 0.80298E-07 -7.0953 0.67170E-07 -7.1728 0.83651E+00 -0.0775 37 CaSO4,aq 0.17119E-16 -16.7665 0.17119E-16 -16.7665 0.10000E+01 0.0000 38 HCl,aq 0.35921E-14 -14.4447 0.35921E-14 -14.4447 0.10000E+01 0.0000 43 FeCl+ 0.15021E-16 -16.8233 0.12565E-16 -16.9008 0.83651E+00 -0.0775 46 FeO,aq 0.21113E-09 -9.6755 0.21113E-09 -9.6755 0.10000E+01 0.0000 47 FeOH+ 0.15758E-10 -10.8025 0.13182E-10 -10.8800 0.83651E+00 -0.0775 48 HFeO2- 0.35491E-07 -7.4499 0.29632E-07 -7.5282 0.83491E+00 -0.0784 49 FeO+ 0.11044E-16 -16.9569 0.92386E-17 -17.0344 0.83651E+00 -0.0775 51 FeO2- 0.40741E-09 -9.3900 0.34015E-09 -9.4683 0.83491E+00 -0.0784 52 HFeO2,aq 0.32251E-11 -11.4915 0.32251E-11 -11.4915 0.10000E+01 0.0000 53 H2,aq 0.11623E-04 -4.9347 0.11582E-04 -4.9362 0.99650E+00 -0.0015 54 KCl,aq 0.62707E-09 -9.2027 0.62707E-09 -9.2027 0.10000E+01 0.0000 56 KOH,aq 0.75375E-06 -6.1228 0.75375E-06 -6.1228 0.10000E+01 0.0000 57 KSO4- 0.18764E-14 -14.7267 0.15666E-14 -14.8050 0.83491E+00 -0.0784 58 MgCO3,aq 0.18438E-13 -13.7343 0.18438E-13 -13.7343 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.15612E-15 -15.8065 0.13060E-15 -15.8841 0.83651E+00 -0.0775 60 MgCl+ 0.50447E-14 -14.2972 0.42199E-14 -14.3747 0.83651E+00 -0.0775 61 MgOH+ 0.69194E-10 -10.1599 0.57881E-10 -10.2375 0.83651E+00 -0.0775 63 MnO,aq 0.18065E-08 -8.7432 0.18065E-08 -8.7432 0.10000E+01 0.0000 64 MnOH+ 0.47010E-09 -9.3278 0.39324E-09 -9.4053 0.83651E+00 -0.0775 65 MnO2-2 0.20846E-10 -10.6810 0.10788E-10 -10.9671 0.51749E+00 -0.2861 66 HMnO2- 0.21103E-09 -9.6757 0.17619E-09 -9.7540 0.83491E+00 -0.0784 69 MnCl+ 0.18766E-13 -13.7266 0.15698E-13 -13.8042 0.83651E+00 -0.0775 71 NaCl,aq 0.14522E-05 -5.8380 0.14522E-05 -5.8380 0.10000E+01 0.0000 72 NaOH,aq 0.96047E-04 -4.0175 0.96047E-04 -4.0175 0.10000E+01 0.0000 74 OH- 0.92996E-02 -2.0315 0.77502E-02 -2.1107 0.83339E+00 -0.0792 79 HPO3-2 0.16260E-14 -14.7889 0.84143E-15 -15.0750 0.51749E+00 -0.2861 81 H2PO3- 0.15066E-18 -18.8220 0.12579E-18 -18.9004 0.83491E+00 -0.0784 82 H3PO4,aq 0.90611E-18 -18.0428 0.90611E-18 -18.0428 0.10000E+01 0.0000 83 H2PO4- 0.38362E-10 -10.4161 0.32059E-10 -10.4941 0.83570E+00 -0.0779 84 PO4-3 0.10545E-08 -8.9770 0.25513E-09 -9.5932 0.24194E+00 -0.6163 88 HP2O7-3 0.93627E-18 -18.0286 0.21585E-18 -18.6659 0.23054E+00 -0.6373 89 P2O7-4 0.90194E-17 -17.0448 0.69169E-18 -18.1601 0.76689E-01 -1.1153 90 H2S,aq 0.11290E-07 -7.9473 0.11250E-07 -7.9488 0.99650E+00 -0.0015 91 S2-2 0.88138E-14 -14.0548 0.45611E-14 -14.3409 0.51749E+00 -0.2861 97 SO3-2 0.21997E-17 -17.6576 0.11548E-17 -17.9375 0.52501E+00 -0.2798 99 HSO4- 0.65833E-19 -19.1816 0.55124E-19 -19.2587 0.83733E+00 -0.0771 Charge balance for all species = 0.1198E-09 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.8875161E-10 -.2221240E-01 -.2234974E+02 0.0000 2 H2O 0.1000000E+01 0.5550491E+02 0.9981947E+06 0.0000 3 Cl- 0.3149441E-03 0.3163970E-03 0.1119767E+02 6.5474 4 SO4-- 0.1479510E-11 -.3129340E-04 -.3000855E+01 8.1401 5 HCO3- 0.5473012E-06 0.2997161E-04 0.1825596E+01 3.7881 6 HS- 0.5847456E-04 0.8977925E-04 0.2964004E+01 5.8162 7 Al+++ 0.9862464E-29 0.5292194E-05 0.1425424E+00 0.7390 8 H4SiO4 0.6959808E-03 0.1348667E-01 0.1294017E+04 -3.1574 9 Ca++ 0.1364888E-06 0.2339703E-06 0.9360717E-02 13.1018 10 Mg++ 0.2135308E-10 0.9380187E-10 0.2276536E-05 9.2942 11 Fe++ 0.5885275E-13 0.3612877E-07 0.2014167E-02 6.7350 12 K+ 0.1573289E-03 0.1580833E-03 0.6170599E+01 6.2467 13 Na+ 0.1996440E-01 0.2241154E-01 0.5143389E+03 8.3494 14 Mn++ 0.1888349E-10 0.2527406E-08 0.1386086E-03 9.2417 15 HPO4-- 0.4494461E-07 0.4603748E-07 0.4410930E-02 12.6227 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.9272766E+02 -.9686367E-02 -.9271797E+02 0.0000000E+00 2 H2O -.1469003E+02 0.2420454E+02 -.3889458E+02 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.1552206E+00 -.1364641E-04 0.1552342E+00 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.1551951E+00 0.3915088E-04 -.1552342E+00 0.0000000E+00 7 Al+++ 0.1826015E+02 0.2307816E-05 0.1826015E+02 0.0000000E+00 8 H4SiO4 0.5831157E+02 0.5881258E-02 0.5830569E+02 0.0000000E+00 9 Ca++ 0.6440812E+01 0.1020296E-06 0.6440812E+01 0.0000000E+00 10 Mg++ 0.4444444E+01 0.4090506E-10 0.4444444E+01 0.0000000E+00 11 Fe++ 0.3992847E+01 0.1575501E-07 0.3992847E+01 0.0000000E+00 12 K+ 0.1188959E+01 0.6893686E-04 0.1188891E+01 0.0000000E+00 13 Na+ 0.7029523E+01 0.9773211E-02 0.7019750E+01 0.0000000E+00 14 Mn++ 0.9709612E-01 0.1102150E-08 0.9709612E-01 0.0000000E+00 15 HPO4-- 0.3313842E-01 0.2007599E-07 0.3313840E-01 0.0000000E+00 Chg. balance for solid moles: -.3123E-14 Mass of aqueous solution: 0.436841E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 5599.9990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 7.014 0.846 1839. 3.265 30.06 706.0 andradite 0.6209 -0.207 315.5 2.499 5.158 81.98 grossular 0.1504 -0.823 67.73 1.831 1.107 18.84 apatite-OH 0.1105E-01 -1.957 5.549 0.744 0.9070E-01 1.763 clinochlore 0.7954 -0.099 442.1 2.646 7.226 168.2 daphnite 0.2303 -0.638 164.3 2.216 2.685 49.79 chlorite-Mn 0.1942E-01 -1.712 13.77 1.139 0.2250 4.387 diopside 0.2953 -0.530 63.96 1.806 1.045 19.55 hedenbergite 0.7659E-01 -1.116 19.00 1.279 0.3106 5.205 microcline 1.043 0.018 290.2 2.463 4.743 113.3 stilbite 3.605 0.557 2540. 3.405 41.52 1185. stilpnomelane-Fe 0.2927 -0.534 315.6 2.499 5.158 109.0 tr.625ac.25prg.125 0.4748E-01 -1.323 40.59 1.608 0.6634 13.06 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8051E+00 0.8051E+00 1.0000 -0.094 grossular 0.1949E+00 0.1949E+00 1.0000 -0.710 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.7611E+00 0.7611E+00 1.0000 -0.119 daphnite 0.2203E+00 0.2203E+00 1.0000 -0.657 chlorite-Mn 0.1858E-01 0.1858E-01 1.0000 -1.731 diopside 0.7941E+00 0.7941E+00 1.0000 -0.100 hedenbergite 0.2059E+00 0.2059E+00 1.0000 -0.686 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 tr.625ac.25prg.125 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 6117.841848 g Volume = 2475.996242 cm3 Porosity: -10.4862% V(tot) - V(min): -.23500E+03 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 5599.9990000 g log = 3.7482 Original solution: 1000.0103000 g Original solution / Rock added: 0.18 (Water/Rock Ratio), log = -0.7482 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0774 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9477E+00 0.9852 0.1006E+01 0.1021E+01 CO2,gas 0.7191E-08 1.0066 0.7799E-08 0.7748E-08 CH4,gas 0.3818E-01 1.0122 0.4164E-01 0.4114E-01 H2,gas 0.1411E-01 1.0006 0.1521E-01 0.1520E-01 H2S,gas 0.2882E-06 0.9958 0.3093E-06 0.3106E-06 S2,gas 0.1441E-28 1.0000 0.1553E-28 0.1553E-28 CO,gas 0.2934E-13 1.0000 0.3161E-13 0.3161E-13 SO3,gas 0.1496E-47 1.0000 0.1612E-47 0.1612E-47 SO2,gas 0.8853E-27 1.0000 0.9538E-27 0.9538E-27 HCl,gas 0.5883E-17 1.0000 0.6338E-17 0.6338E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 16 albite -0.38 -0.38 0.00 0.000 -0.94784E-12 22 andradite 39.01 39.01 0.00 0.000 0.00000E+00 23 grossular 32.73 32.73 0.00 0.000 -0.48529E-10 32 apatite-OH -18.15 -18.15 0.00 0.000 0.00000E+00 46 clinochlore 39.07 39.07 0.00 0.000 0.00000E+00 47 daphnite 28.97 28.97 0.00 0.000 -0.54595E-10 48 chlorite-Mn 46.87 46.87 0.00 0.000 -0.48529E-10 67 diopside 16.18 16.18 0.00 0.000 -0.60662E-11 68 hedenbergite 14.21 14.21 0.00 0.000 -0.90992E-11 116 microcline -2.49 -2.49 0.00 0.000 -0.10616E-10 163 stilbite -7.52 -7.52 0.00 0.000 -0.33364E-10 164 stilpnomelane-Fe 13.02 13.02 0.00 0.000 -0.27298E-10 245 tr.625ac.25prg.125 45.16 45.16 0.00 0.000 -0.24265E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -16.47 -9.81 -3.269 0.16745E+05 -8.108 3 CH4,gas 4.54 1.46 -3.08 -0.770 0.52581E+04 -1.381 4 H2,gas 8.00 4.48 -3.52 -2.010 0.60051E+04 -1.818 5 H2S,gas -6.23 -14.44 -8.21 -4.104 0.14016E+05 -6.510 6 S2,gas -7.34 -37.84 -30.51 -4.694 0.52091E+05 -28.809 7 CO,gas 3.21 -11.98 -15.20 -4.677 0.25952E+05 -13.500 8 SO3,gas 17.12 -32.37 -49.49 -12.373 0.84505E+05 -47.793 9 SO2,gas 0.83 -27.89 -28.72 -7.659 0.49038E+05 -27.021 10 HCl,gas 5.19 -13.71 -18.90 -9.448 0.32266E+05 -17.198 11 acmite 7.71 6.53 -1.18 -0.123 0.20175E+04 15 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 19 spessartine 24.46 19.73 -4.73 -0.236 0.80706E+04 20 analcite 3.32 2.77 -0.55 -0.061 0.93625E+03 26 annite 20.12 17.72 -2.40 -0.134 0.41064E+04 27 phlogopite 27.06 25.40 -1.67 -0.093 0.28489E+04 29 anorthite 12.71 8.26 -4.45 -0.342 0.75903E+04 35 aragonite 0.97 -3.37 -4.33 -1.444 0.73963E+04 36 brucite 12.57 9.29 -3.27 -0.655 0.55909E+04 37 calcite 0.81 -3.37 -4.18 -1.392 0.71321E+04 38 carnegieite-low 9.02 5.93 -3.09 -0.442 0.52801E+04 39 carnegieite-high 10.09 5.93 -4.16 -0.595 0.71071E+04 40 carpholite-Mg 8.58 4.46 -4.12 -0.275 0.70429E+04 41 carpholite-Fe 6.71 1.90 -4.81 -0.321 0.82207E+04 42 celadonite 5.34 3.65 -1.69 -0.099 0.28879E+04 43 celadonite-Fe 3.88 1.09 -2.79 -0.164 0.47561E+04 44 chrysotile 23.89 21.57 -2.32 -0.194 0.39692E+04 49 chlorite-Al-free 47.17 43.14 -4.04 -0.168 0.68936E+04 51 chloritoid-Fe 9.17 5.06 -4.12 -0.275 0.70316E+04 52 chloritoid-Mn 11.40 7.56 -3.84 -0.256 0.65548E+04 54 coesite -2.38 -3.16 -0.78 -0.260 0.13341E+04 61 cristobalite -2.56 -3.16 -0.60 -0.199 0.10195E+04 63 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71234E+04 65 diaspore 2.87 0.74 -2.13 -0.356 0.36450E+04 66 diamond -3.10 -7.50 -4.40 -1.257 0.75112E+04 71 enstatite 17.26 12.27 -4.99 -0.499 0.85226E+04 73 clinoenstatite 17.17 12.27 -4.89 -0.489 0.83541E+04 75 epidote 24.67 22.70 -1.97 -0.095 0.33585E+04 76 clinozoisite 22.81 18.95 -3.86 -0.175 0.65869E+04 77 epidote-Fe 29.84 26.46 -3.38 -0.176 0.57768E+04 78 fayalite 14.05 10.31 -3.73 -0.533 0.63743E+04 79 ferrosilite 11.15 7.16 -3.99 -0.399 0.68202E+04 83 gibbsite 4.08 0.74 -3.34 -0.477 0.57035E+04 84 glaucophane 22.97 20.80 -2.17 -0.059 0.37134E+04 85 glaucophane-Fe 17.28 13.12 -4.15 -0.112 0.70919E+04 86 graphite -3.55 -7.50 -3.96 -1.130 0.67535E+04 87 greenalite 16.14 13.89 -2.25 -0.187 0.38408E+04 90 hematite 12.57 8.99 -3.58 -0.434 0.61111E+04 91 heulandite -5.83 -7.52 -1.69 -0.077 0.28938E+04 95 jadeite 4.22 2.77 -1.44 -0.144 0.24617E+04 97 kalsilite 7.58 3.83 -3.76 -0.537 0.64126E+04 98 kaolinite -1.33 -4.84 -3.50 -0.319 0.59832E+04 101 laumontite 2.88 1.95 -0.93 -0.062 0.15935E+04 102 lawsonite 9.62 8.26 -1.35 -0.090 0.23070E+04 103 leucite 4.12 0.67 -3.45 -0.345 0.58873E+04 105 lizardite 23.24 21.57 -1.68 -0.140 0.28618E+04 107 magnetite 20.09 15.72 -4.37 -0.356 0.74536E+04 108 minnesotaite 10.39 7.58 -2.81 -0.165 0.48028E+04 112 manganosite 14.06 9.24 -4.82 -1.204 0.82240E+04 120 muscovite 2.58 -1.01 -3.59 -0.211 0.61315E+04 121 paragonite 4.24 1.09 -3.15 -0.185 0.53706E+04 122 nepheline 8.34 5.93 -2.41 -0.344 0.41125E+04 128 periclase-Fe 11.63 6.73 -4.89 -1.223 0.83523E+04 134 phlogopite-Na 29.65 27.50 -2.15 -0.119 0.36678E+04 136 prehnite 19.37 18.21 -1.16 -0.068 0.19849E+04 137 prehnite-Fe 22.50 21.96 -0.53 -0.032 0.91158E+03 138 pumpellyite-Fe 46.27 43.89 -2.38 -0.053 0.40582E+04 139 pumpellyite-Mg 48.99 46.45 -2.54 -0.057 0.43420E+04 143 pyrrhotite -4.26 -7.70 -3.44 -1.148 0.58798E+04 144 pyrrhotiteFe0.875 -6.02 -9.10 -3.08 -1.134 0.52671E+04 145 pyroxmangite 7.40 6.08 -1.31 -0.263 0.22444E+04 146 pyrophyllite -6.18 -11.15 -4.98 -0.311 0.84962E+04 147 quartz -2.99 -3.16 -0.17 -0.056 0.28680E+03 152 rhodonite 7.45 6.08 -1.36 -0.272 0.23246E+04 153 sanidine -1.28 -2.49 -1.21 -0.093 0.20677E+04 165 stilpnomelane-Mg 27.44 25.81 -1.63 -0.049 0.27804E+04 171 talc 16.49 15.25 -1.24 -0.073 0.21140E+04 174 tephroite 18.09 15.33 -2.76 -0.394 0.47124E+04 178 tridymite -2.63 -3.16 -0.53 -0.177 0.90678E+03 179 tremolite 47.87 47.42 -0.45 -0.012 0.77494E+03 180 ferroactinolite 38.45 34.62 -3.83 -0.104 0.65448E+04 181 troilite-low -4.41 -7.70 -3.29 -1.098 0.56226E+04 183 vesuvianite 223.47 218.82 -4.65 -0.036 0.79439E+04 187 wairakite 3.95 1.95 -2.00 -0.118 0.34155E+04 188 walstromite 11.51 9.94 -1.56 -0.313 0.26719E+04 189 wollastonite 10.46 9.94 -0.52 -0.103 0.88229E+03 190 pseudo-wollastonite 11.00 9.94 -1.06 -0.211 0.18021E+04 191 zoisite 22.85 18.95 -3.90 -0.177 0.66609E+04 192 akaganeite 7.75 4.49 -3.26 -0.705 0.55681E+04 199 chalcedony -2.80 -3.16 -0.35 -0.118 0.60610E+03 201 montmorillonite-Ca -2.29 -6.17 -3.88 -0.240 0.66180E+04 202 montmorillonite-K -2.24 -6.27 -4.03 -0.247 0.68816E+04 203 montmorillonite-Mg -2.48 -6.79 -4.32 -0.267 0.73678E+04 204 montmorillonite-Na -2.04 -5.57 -3.54 -0.216 0.60365E+04 205 nontronite-Ca 3.21 -0.19 -3.41 -0.221 0.58215E+04 206 nontronite-H 2.53 -2.36 -4.89 -0.328 0.83485E+04 207 nontronite-K 3.34 -0.30 -3.64 -0.233 0.62083E+04 208 nontronite-Mg 3.07 -0.82 -3.90 -0.253 0.66553E+04 209 nontronite-Na 3.52 0.40 -3.12 -0.200 0.53292E+04 224 tobermorite 9.82 7.76 -2.07 -0.564 0.35287E+04 230 alabandite -0.98 -5.20 -4.22 -1.406 0.72045E+04 233 boehmite 4.41 0.74 -3.67 -0.611 0.62619E+04 235 ferrous-oxide 9.81 6.73 -3.08 -0.769 0.52532E+04 240 silica-amorphous -2.09 -3.16 -1.07 -0.355 0.18203E+04 242 an20ab80 2.02 1.35 -0.67 -0.052 0.11472E+04 243 an25ab75 2.65 1.78 -0.87 -0.067 0.14810E+04 244 an30ab70 3.28 2.21 -1.07 -0.082 0.18244E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 100.0000000 g Current total amount of reactant added: 5599.9990000 g New total amount of reactant added: 5699.9990000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.5222E-10 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 12 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 5699.9990000 Water: Moles liquid = 0.2365E+02 kg liquid = 0.4260E+00 Moles total = -.1594E+02 kg total = -.2872E+00 Activity = 1.0000 Stoichiometric ionic strength = .1147162E-01 Osmotic coef. = 0.9684 True ionic strength = .2012814E-01 Chg. balance for total moles = 0.5222E-10 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.88773E-10 -10.0517 0.74566E-10 -10.1275 0.83996E+00 -0.0757 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.32237E-03 -3.4916 0.26914E-03 -3.5700 0.83489E+00 -0.0784 4 SO4-- 0.15141E-11 -11.8198 0.78517E-12 -12.1050 0.51857E+00 -0.2852 5 HCO3- 0.56010E-06 -6.2517 0.46831E-06 -6.3295 0.83612E+00 -0.0777 6 HS- 0.59853E-04 -4.2229 0.49978E-04 -4.3012 0.83501E+00 -0.0783 7 Al+++ 0.98704E-29 -29.0057 0.22729E-29 -29.6434 0.23028E+00 -0.6377 8 H4SiO4 0.69598E-03 -3.1574 0.69598E-03 -3.1574 0.10000E+01 0.0000 9 Ca++ 0.13656E-06 -6.8647 0.70292E-07 -7.1531 0.51474E+00 -0.2884 10 Mg++ 0.21364E-10 -10.6703 0.10946E-10 -10.9607 0.51238E+00 -0.2904 11 Fe++ 0.58883E-13 -13.2300 0.30203E-13 -13.5199 0.51294E+00 -0.2899 12 K+ 0.15737E-03 -3.8031 0.13161E-03 -3.8807 0.83632E+00 -0.0776 13 Na+ 0.19969E-01 -1.6996 0.16669E-01 -1.7781 0.83474E+00 -0.0784 14 Mn++ 0.18894E-10 -10.7237 0.96994E-11 -11.0133 0.51337E+00 -0.2896 15 HPO4-- 0.44927E-07 -7.3475 0.23301E-07 -7.6326 0.51864E+00 -0.2851 16 HSiO3- 0.10439E-01 -1.9813 0.87153E-02 -2.0597 0.83489E+00 -0.0784 17 Ca(HSiO3)+ 0.16679E-07 -7.7778 0.13952E-07 -7.8554 0.83650E+00 -0.0775 18 Mg(HSiO3)+ 0.32324E-11 -11.4905 0.27039E-11 -11.5680 0.83650E+00 -0.0775 19 NaHSiO3,aq 0.23496E-02 -2.6290 0.23496E-02 -2.6290 0.10000E+01 0.0000 20 AlO+ 0.66484E-16 -16.1773 0.55614E-16 -16.2548 0.83650E+00 -0.0775 22 HAlO2,aq 0.14853E-09 -9.8282 0.14853E-09 -9.8282 0.10000E+01 0.0000 23 AlO2- 0.52910E-05 -5.2765 0.44094E-05 -5.3556 0.83338E+00 -0.0792 24 CH4,aq 0.29057E-04 -4.5367 0.28956E-04 -4.5383 0.99650E+00 -0.0015 25 C2H6,aq 0.12419E-13 -13.9059 0.12375E-13 -13.9075 0.99650E+00 -0.0015 29 CO,aq 0.21710E-16 -16.6633 0.21710E-16 -16.6633 0.10000E+01 0.0000 30 CO2,aq 0.74877E-10 -10.1257 0.74615E-10 -10.1272 0.99650E+00 -0.0015 31 CO3-2 0.10601E-05 -5.9746 0.54857E-06 -6.2608 0.51746E+00 -0.2861 32 CaCO3,aq 0.48350E-09 -9.3156 0.48350E-09 -9.3156 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.10045E-11 -11.9980 0.84028E-12 -12.0756 0.83650E+00 -0.0775 34 CaCl+ 0.36601E-10 -10.4365 0.30616E-10 -10.5140 0.83650E+00 -0.0775 35 CaCl2,aq 0.19577E-14 -14.7083 0.19577E-14 -14.7083 0.10000E+01 0.0000 36 CaOH+ 0.80317E-07 -7.0952 0.67185E-07 -7.1727 0.83650E+00 -0.0775 37 CaSO4,aq 0.17526E-16 -16.7563 0.17526E-16 -16.7563 0.10000E+01 0.0000 38 HCl,aq 0.36775E-14 -14.4344 0.36775E-14 -14.4344 0.10000E+01 0.0000 43 FeCl+ 0.15382E-16 -16.8130 0.12867E-16 -16.8905 0.83650E+00 -0.0775 46 FeO,aq 0.21113E-09 -9.6755 0.21113E-09 -9.6755 0.10000E+01 0.0000 47 FeOH+ 0.15762E-10 -10.8024 0.13185E-10 -10.8799 0.83650E+00 -0.0775 48 HFeO2- 0.35484E-07 -7.4500 0.29625E-07 -7.5283 0.83489E+00 -0.0784 49 FeO+ 0.11047E-16 -16.9568 0.92407E-17 -17.0343 0.83650E+00 -0.0775 51 FeO2- 0.40733E-09 -9.3901 0.34007E-09 -9.4684 0.83489E+00 -0.0784 52 HFeO2,aq 0.32251E-11 -11.4915 0.32251E-11 -11.4915 0.10000E+01 0.0000 53 H2,aq 0.11623E-04 -4.9347 0.11582E-04 -4.9362 0.99650E+00 -0.0015 54 KCl,aq 0.64198E-09 -9.1925 0.64198E-09 -9.1925 0.10000E+01 0.0000 56 KOH,aq 0.75375E-06 -6.1228 0.75375E-06 -6.1228 0.10000E+01 0.0000 57 KSO4- 0.19206E-14 -14.7166 0.16035E-14 -14.7949 0.83489E+00 -0.0784 58 MgCO3,aq 0.18873E-13 -13.7242 0.18873E-13 -13.7242 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.15984E-15 -15.7963 0.13371E-15 -15.8738 0.83650E+00 -0.0775 60 MgCl+ 0.51659E-14 -14.2869 0.43212E-14 -14.3644 0.83650E+00 -0.0775 61 MgOH+ 0.69210E-10 -10.1598 0.57894E-10 -10.2374 0.83650E+00 -0.0775 63 MnO,aq 0.18066E-08 -8.7431 0.18066E-08 -8.7431 0.10000E+01 0.0000 64 MnOH+ 0.47022E-09 -9.3277 0.39334E-09 -9.4052 0.83650E+00 -0.0775 65 MnO2-2 0.20839E-10 -10.6811 0.10783E-10 -10.9673 0.51746E+00 -0.2861 66 HMnO2- 0.21099E-09 -9.6757 0.17616E-09 -9.7541 0.83489E+00 -0.0784 69 MnCl+ 0.19217E-13 -13.7163 0.16075E-13 -13.7938 0.83650E+00 -0.0775 71 NaCl,aq 0.14868E-05 -5.8278 0.14868E-05 -5.8278 0.10000E+01 0.0000 72 NaOH,aq 0.96047E-04 -4.0175 0.96047E-04 -4.0175 0.10000E+01 0.0000 74 OH- 0.92977E-02 -2.0316 0.77485E-02 -2.1108 0.83338E+00 -0.0792 79 HPO3-2 0.16254E-14 -14.7891 0.84105E-15 -15.0752 0.51746E+00 -0.2861 81 H2PO3- 0.15063E-18 -18.8221 0.12576E-18 -18.9005 0.83489E+00 -0.0784 82 H3PO4,aq 0.90611E-18 -18.0428 0.90611E-18 -18.0428 0.10000E+01 0.0000 83 H2PO4- 0.38354E-10 -10.4162 0.32052E-10 -10.4941 0.83569E+00 -0.0780 84 PO4-3 0.10539E-08 -8.9772 0.25496E-09 -9.5935 0.24191E+00 -0.6163 88 HP2O7-3 0.93578E-18 -18.0288 0.21570E-18 -18.6661 0.23051E+00 -0.6373 89 P2O7-4 0.90137E-17 -17.0451 0.69108E-18 -18.1605 0.76670E-01 -1.1154 90 H2S,aq 0.11558E-07 -7.9371 0.11518E-07 -7.9386 0.99650E+00 -0.0015 91 S2-2 0.92345E-14 -14.0346 0.47785E-14 -14.3207 0.51746E+00 -0.2861 97 SO3-2 0.22511E-17 -17.6476 0.11818E-17 -17.9275 0.52498E+00 -0.2799 99 HSO4- 0.67385E-19 -19.1714 0.56423E-19 -19.2485 0.83732E+00 -0.0771 Charge balance for all species = 0.1226E-09 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.8877267E-10 -.2220835E-01 -.2234567E+02 0.0000 2 H2O 0.1000000E+01 0.5550491E+02 0.9981945E+06 0.0000 3 Cl- 0.3223677E-03 0.3238552E-03 0.1146162E+02 6.5574 4 SO4-- 0.1514124E-11 -.3196306E-04 -.3065070E+01 8.1499 5 HCO3- 0.5600968E-06 0.3067811E-04 0.1868629E+01 3.7980 6 HS- 0.5985293E-04 0.9182755E-04 0.3031627E+01 5.8262 7 Al+++ 0.9870450E-29 0.5291099E-05 0.1425129E+00 0.7390 8 H4SiO4 0.6959810E-03 0.1348452E-01 0.1293811E+04 -3.1574 9 Ca++ 0.1365582E-06 0.2340748E-06 0.9364895E-02 13.1018 10 Mg++ 0.2136396E-10 0.9383026E-10 0.2277225E-05 9.2942 11 Fe++ 0.5888273E-13 0.3612137E-07 0.2013754E-02 6.7350 12 K+ 0.1573664E-03 0.1581208E-03 0.6172061E+01 6.2467 13 Na+ 0.1996916E-01 0.2241634E-01 0.5144488E+03 8.3494 14 Mn++ 0.1889363E-10 0.2527547E-08 0.1386163E-03 9.2417 15 HPO4-- 0.4492747E-07 0.4601977E-07 0.4409232E-02 12.6223 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.9438351E+02 -.9461573E-02 -.9437405E+02 0.0000000E+00 2 H2O -.1594358E+02 0.2364713E+02 -.3959070E+02 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.1579919E+00 -.1361744E-04 0.1580055E+00 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.1579664E+00 0.3912191E-04 -.1580055E+00 0.0000000E+00 7 Al+++ 0.1858622E+02 0.2254202E-05 0.1858622E+02 0.0000000E+00 8 H4SiO4 0.5935285E+02 0.5744901E-02 0.5934711E+02 0.0000000E+00 9 Ca++ 0.6555826E+01 0.9972444E-07 0.6555826E+01 0.0000000E+00 10 Mg++ 0.4523809E+01 0.3997513E-10 0.4523809E+01 0.0000000E+00 11 Fe++ 0.4064148E+01 0.1538903E-07 0.4064148E+01 0.0000000E+00 12 K+ 0.1210191E+01 0.6736525E-04 0.1210124E+01 0.0000000E+00 13 Na+ 0.7155047E+01 0.9550183E-02 0.7145497E+01 0.0000000E+00 14 Mn++ 0.9882998E-01 0.1076828E-08 0.9882998E-01 0.0000000E+00 15 HPO4-- 0.3373018E-01 0.1960611E-07 0.3373016E-01 0.0000000E+00 Chg. balance for solid moles: 0.5315E-14 Mass of aqueous solution: 0.426781E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 5699.9990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 7.139 0.854 1872. 3.272 30.06 718.7 andradite 0.6320 -0.199 321.2 2.507 5.158 83.45 grossular 0.1530 -0.815 68.94 1.838 1.107 19.18 apatite-OH 0.1124E-01 -1.949 5.648 0.752 0.9070E-01 1.795 clinochlore 0.8096 -0.092 450.0 2.653 7.226 171.2 daphnite 0.2344 -0.630 167.2 2.223 2.685 50.67 chlorite-Mn 0.1977E-01 -1.704 14.01 1.147 0.2250 4.466 diopside 0.3008 -0.522 65.13 1.814 1.046 19.91 hedenbergite 0.7800E-01 -1.108 19.35 1.287 0.3108 5.300 microcline 1.061 0.026 295.4 2.470 4.743 115.4 stilbite 3.669 0.565 2586. 3.413 41.52 1206. stilpnomelane-Fe 0.2980 -0.526 321.2 2.507 5.158 111.0 tr.625ac.25prg.125 0.4832E-01 -1.316 41.30 1.616 0.6632 13.29 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8051E+00 0.8051E+00 1.0000 -0.094 grossular 0.1949E+00 0.1949E+00 1.0000 -0.710 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.7611E+00 0.7611E+00 1.0000 -0.119 daphnite 0.2203E+00 0.2203E+00 1.0000 -0.657 chlorite-Mn 0.1858E-01 0.1858E-01 1.0000 -1.731 diopside 0.7941E+00 0.7941E+00 1.0000 -0.100 hedenbergite 0.2059E+00 0.2059E+00 1.0000 -0.686 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 tr.625ac.25prg.125 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 6227.092513 g Volume = 2520.199306 cm3 Porosity: -10.4866% V(tot) - V(min): -.23920E+03 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 5699.9990000 g log = 3.7559 Original solution: 1000.0103000 g Original solution / Rock added: 0.18 (Water/Rock Ratio), log = -0.7559 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0784 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9469E+00 0.9852 0.1006E+01 0.1021E+01 CO2,gas 0.7354E-08 1.0066 0.7983E-08 0.7931E-08 CH4,gas 0.3905E-01 1.0122 0.4262E-01 0.4211E-01 H2,gas 0.1409E-01 1.0006 0.1521E-01 0.1520E-01 H2S,gas 0.2948E-06 0.9958 0.3166E-06 0.3179E-06 S2,gas 0.1509E-28 1.0000 0.1627E-28 0.1627E-28 CO,gas 0.3000E-13 1.0000 0.3235E-13 0.3235E-13 SO3,gas 0.1531E-47 1.0000 0.1651E-47 0.1651E-47 SO2,gas 0.9055E-27 1.0000 0.9765E-27 0.9765E-27 HCl,gas 0.6017E-17 1.0000 0.6489E-17 0.6489E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 16 albite -0.38 -0.38 0.00 0.000 0.11184E-10 22 andradite 39.01 39.01 0.00 0.000 -0.12132E-10 23 grossular 32.73 32.73 0.00 0.000 -0.12132E-10 32 apatite-OH -18.15 -18.15 0.00 0.000 0.60662E-11 46 clinochlore 39.07 39.07 0.00 0.000 0.24265E-10 47 daphnite 28.97 28.97 0.00 0.000 0.42463E-10 48 chlorite-Mn 46.87 46.87 0.00 0.000 0.00000E+00 67 diopside 16.18 16.18 0.00 0.000 0.12132E-10 68 hedenbergite 14.21 14.21 0.00 0.000 0.90992E-11 116 microcline -2.49 -2.49 0.00 0.000 0.13649E-10 163 stilbite -7.52 -7.52 0.00 0.000 -0.90992E-11 164 stilpnomelane-Fe 13.02 13.02 0.00 0.000 0.21232E-10 245 tr.625ac.25prg.125 45.16 45.16 0.00 0.000 -0.12132E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -16.46 -9.80 -3.266 0.16728E+05 -8.098 3 CH4,gas 4.54 1.47 -3.07 -0.767 0.52408E+04 -1.370 4 H2,gas 8.00 4.48 -3.52 -2.010 0.60051E+04 -1.818 5 H2S,gas -6.23 -14.43 -8.20 -4.099 0.13999E+05 -6.499 6 S2,gas -7.34 -37.82 -30.49 -4.690 0.52057E+05 -28.789 7 CO,gas 3.21 -11.97 -15.19 -4.674 0.25935E+05 -13.490 8 SO3,gas 17.12 -32.36 -49.48 -12.370 0.84488E+05 -47.782 9 SO2,gas 0.83 -27.88 -28.71 -7.656 0.49020E+05 -27.010 10 HCl,gas 5.19 -13.70 -18.89 -9.443 0.32249E+05 -17.188 11 acmite 7.71 6.53 -1.18 -0.123 0.20175E+04 15 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 19 spessartine 24.46 19.73 -4.73 -0.236 0.80706E+04 20 analcite 3.32 2.77 -0.55 -0.061 0.93625E+03 26 annite 20.12 17.72 -2.40 -0.134 0.41064E+04 27 phlogopite 27.06 25.40 -1.67 -0.093 0.28489E+04 29 anorthite 12.71 8.26 -4.45 -0.342 0.75903E+04 35 aragonite 0.97 -3.36 -4.32 -1.441 0.73791E+04 36 brucite 12.57 9.29 -3.27 -0.655 0.55909E+04 37 calcite 0.81 -3.36 -4.17 -1.389 0.71148E+04 38 carnegieite-low 9.02 5.93 -3.09 -0.442 0.52801E+04 39 carnegieite-high 10.09 5.93 -4.16 -0.595 0.71071E+04 40 carpholite-Mg 8.58 4.46 -4.12 -0.275 0.70429E+04 41 carpholite-Fe 6.71 1.90 -4.81 -0.321 0.82207E+04 42 celadonite 5.34 3.65 -1.69 -0.099 0.28879E+04 43 celadonite-Fe 3.88 1.09 -2.79 -0.164 0.47561E+04 44 chrysotile 23.89 21.57 -2.32 -0.194 0.39692E+04 49 chlorite-Al-free 47.17 43.14 -4.04 -0.168 0.68936E+04 51 chloritoid-Fe 9.17 5.06 -4.12 -0.275 0.70316E+04 52 chloritoid-Mn 11.40 7.56 -3.84 -0.256 0.65548E+04 54 coesite -2.38 -3.16 -0.78 -0.260 0.13341E+04 61 cristobalite -2.56 -3.16 -0.60 -0.199 0.10195E+04 63 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71234E+04 65 diaspore 2.87 0.74 -2.13 -0.356 0.36450E+04 66 diamond -3.10 -7.49 -4.39 -1.254 0.74939E+04 71 enstatite 17.26 12.27 -4.99 -0.499 0.85226E+04 73 clinoenstatite 17.17 12.27 -4.89 -0.489 0.83541E+04 75 epidote 24.67 22.70 -1.97 -0.095 0.33585E+04 76 clinozoisite 22.81 18.95 -3.86 -0.175 0.65869E+04 77 epidote-Fe 29.84 26.46 -3.38 -0.176 0.57768E+04 78 fayalite 14.05 10.31 -3.73 -0.533 0.63743E+04 79 ferrosilite 11.15 7.16 -3.99 -0.399 0.68202E+04 83 gibbsite 4.08 0.74 -3.34 -0.477 0.57035E+04 84 glaucophane 22.97 20.80 -2.17 -0.059 0.37134E+04 85 glaucophane-Fe 17.28 13.12 -4.15 -0.112 0.70919E+04 86 graphite -3.55 -7.49 -3.95 -1.127 0.67362E+04 87 greenalite 16.14 13.89 -2.25 -0.187 0.38408E+04 90 hematite 12.57 8.99 -3.58 -0.434 0.61111E+04 91 heulandite -5.83 -7.52 -1.69 -0.077 0.28938E+04 95 jadeite 4.22 2.77 -1.44 -0.144 0.24617E+04 97 kalsilite 7.58 3.83 -3.76 -0.537 0.64126E+04 98 kaolinite -1.33 -4.84 -3.50 -0.319 0.59832E+04 101 laumontite 2.88 1.95 -0.93 -0.062 0.15935E+04 102 lawsonite 9.62 8.26 -1.35 -0.090 0.23070E+04 103 leucite 4.12 0.67 -3.45 -0.345 0.58873E+04 105 lizardite 23.24 21.57 -1.68 -0.140 0.28618E+04 107 magnetite 20.09 15.72 -4.37 -0.356 0.74536E+04 108 minnesotaite 10.39 7.58 -2.81 -0.165 0.48028E+04 112 manganosite 14.06 9.24 -4.82 -1.204 0.82240E+04 120 muscovite 2.58 -1.01 -3.59 -0.211 0.61315E+04 121 paragonite 4.24 1.09 -3.15 -0.185 0.53706E+04 122 nepheline 8.34 5.93 -2.41 -0.344 0.41125E+04 128 periclase-Fe 11.63 6.73 -4.89 -1.223 0.83523E+04 134 phlogopite-Na 29.65 27.50 -2.15 -0.119 0.36678E+04 136 prehnite 19.37 18.21 -1.16 -0.068 0.19849E+04 137 prehnite-Fe 22.50 21.96 -0.53 -0.032 0.91158E+03 138 pumpellyite-Fe 46.27 43.89 -2.38 -0.053 0.40582E+04 139 pumpellyite-Mg 48.99 46.45 -2.54 -0.057 0.43420E+04 143 pyrrhotite -4.26 -7.69 -3.43 -1.144 0.58624E+04 144 pyrrhotiteFe0.875 -6.02 -9.09 -3.07 -1.131 0.52496E+04 145 pyroxmangite 7.40 6.08 -1.31 -0.263 0.22443E+04 146 pyrophyllite -6.18 -11.15 -4.98 -0.311 0.84962E+04 147 quartz -2.99 -3.16 -0.17 -0.056 0.28680E+03 152 rhodonite 7.45 6.08 -1.36 -0.272 0.23246E+04 153 sanidine -1.28 -2.49 -1.21 -0.093 0.20677E+04 165 stilpnomelane-Mg 27.44 25.81 -1.63 -0.049 0.27804E+04 171 talc 16.49 15.25 -1.24 -0.073 0.21140E+04 174 tephroite 18.09 15.33 -2.76 -0.394 0.47124E+04 178 tridymite -2.63 -3.16 -0.53 -0.177 0.90678E+03 179 tremolite 47.87 47.42 -0.45 -0.012 0.77494E+03 180 ferroactinolite 38.45 34.62 -3.83 -0.104 0.65448E+04 181 troilite-low -4.41 -7.69 -3.28 -1.094 0.56052E+04 183 vesuvianite 223.47 218.82 -4.65 -0.036 0.79439E+04 187 wairakite 3.95 1.95 -2.00 -0.118 0.34155E+04 188 walstromite 11.51 9.94 -1.56 -0.313 0.26719E+04 189 wollastonite 10.46 9.94 -0.52 -0.103 0.88229E+03 190 pseudo-wollastonite 11.00 9.94 -1.06 -0.211 0.18021E+04 191 zoisite 22.85 18.95 -3.90 -0.177 0.66609E+04 192 akaganeite 7.75 4.49 -3.26 -0.705 0.55681E+04 199 chalcedony -2.80 -3.16 -0.35 -0.118 0.60610E+03 201 montmorillonite-Ca -2.29 -6.17 -3.88 -0.240 0.66180E+04 202 montmorillonite-K -2.24 -6.27 -4.03 -0.247 0.68816E+04 203 montmorillonite-Mg -2.48 -6.79 -4.32 -0.267 0.73678E+04 204 montmorillonite-Na -2.04 -5.57 -3.54 -0.216 0.60365E+04 205 nontronite-Ca 3.21 -0.19 -3.41 -0.221 0.58215E+04 206 nontronite-H 2.53 -2.36 -4.89 -0.328 0.83485E+04 207 nontronite-K 3.34 -0.30 -3.64 -0.233 0.62083E+04 208 nontronite-Mg 3.07 -0.82 -3.90 -0.253 0.66553E+04 209 nontronite-Na 3.52 0.40 -3.12 -0.200 0.53292E+04 224 tobermorite 9.82 7.76 -2.07 -0.564 0.35287E+04 230 alabandite -0.98 -5.19 -4.21 -1.403 0.71870E+04 233 boehmite 4.41 0.74 -3.67 -0.611 0.62619E+04 235 ferrous-oxide 9.81 6.73 -3.08 -0.769 0.52532E+04 240 silica-amorphous -2.09 -3.16 -1.07 -0.355 0.18203E+04 242 an20ab80 2.02 1.35 -0.67 -0.052 0.11472E+04 243 an25ab75 2.65 1.78 -0.87 -0.067 0.14810E+04 244 an30ab70 3.28 2.21 -1.07 -0.082 0.18244E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 100.0000000 g Current total amount of reactant added: 5699.9990000 g New total amount of reactant added: 5799.9990000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.5223E-10 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 12 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 5799.9990000 Water: Moles liquid = 0.2309E+02 kg liquid = 0.4160E+00 Moles total = -.1720E+02 kg total = -.3098E+00 Activity = 1.0000 Stoichiometric ionic strength = .1147810E-01 Osmotic coef. = 0.9683 True ionic strength = .2013320E-01 Chg. balance for total moles = 0.5223E-10 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.88795E-10 -10.0516 0.74583E-10 -10.1274 0.83995E+00 -0.0757 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.33015E-03 -3.4813 0.27563E-03 -3.5597 0.83488E+00 -0.0784 4 SO4-- 0.15504E-11 -11.8096 0.80393E-12 -12.0948 0.51853E+00 -0.2852 5 HCO3- 0.57350E-06 -6.2415 0.47951E-06 -6.3192 0.83610E+00 -0.0777 6 HS- 0.61298E-04 -4.2126 0.51184E-04 -4.2909 0.83500E+00 -0.0783 7 Al+++ 0.98788E-29 -29.0053 0.22745E-29 -29.6431 0.23024E+00 -0.6378 8 H4SiO4 0.69598E-03 -3.1574 0.69598E-03 -3.1574 0.10000E+01 0.0000 9 Ca++ 0.13663E-06 -6.8645 0.70325E-07 -7.1529 0.51471E+00 -0.2884 10 Mg++ 0.21375E-10 -10.6701 0.10952E-10 -10.9605 0.51234E+00 -0.2904 11 Fe++ 0.58914E-13 -13.2298 0.30217E-13 -13.5197 0.51291E+00 -0.2900 12 K+ 0.15741E-03 -3.8030 0.13164E-03 -3.8806 0.83630E+00 -0.0776 13 Na+ 0.19974E-01 -1.6995 0.16673E-01 -1.7780 0.83473E+00 -0.0785 14 Mn++ 0.18904E-10 -10.7234 0.97042E-11 -11.0130 0.51333E+00 -0.2896 15 HPO4-- 0.44910E-07 -7.3477 0.23290E-07 -7.6328 0.51861E+00 -0.2852 16 HSiO3- 0.10437E-01 -1.9814 0.87133E-02 -2.0598 0.83488E+00 -0.0784 17 Ca(HSiO3)+ 0.16683E-07 -7.7777 0.13955E-07 -7.8553 0.83648E+00 -0.0775 18 Mg(HSiO3)+ 0.32332E-11 -11.4904 0.27045E-11 -11.5679 0.83648E+00 -0.0775 19 NaHSiO3,aq 0.23496E-02 -2.6290 0.23496E-02 -2.6290 0.10000E+01 0.0000 20 AlO+ 0.66501E-16 -16.1772 0.55627E-16 -16.2547 0.83648E+00 -0.0775 22 HAlO2,aq 0.14853E-09 -9.8282 0.14853E-09 -9.8282 0.10000E+01 0.0000 23 AlO2- 0.52898E-05 -5.2766 0.44083E-05 -5.3557 0.83336E+00 -0.0792 24 CH4,aq 0.29759E-04 -4.5264 0.29655E-04 -4.5279 0.99650E+00 -0.0015 25 C2H6,aq 0.13026E-13 -13.8852 0.12980E-13 -13.8867 0.99650E+00 -0.0015 29 CO,aq 0.22235E-16 -16.6530 0.22235E-16 -16.6530 0.10000E+01 0.0000 30 CO2,aq 0.76686E-10 -10.1153 0.76418E-10 -10.1168 0.99650E+00 -0.0015 31 CO3-2 0.10853E-05 -5.9644 0.56156E-06 -6.2506 0.51743E+00 -0.2862 32 CaCO3,aq 0.49519E-09 -9.3052 0.49519E-09 -9.3052 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.10290E-11 -11.9876 0.86078E-12 -12.0651 0.83648E+00 -0.0775 34 CaCl+ 0.37502E-10 -10.4260 0.31369E-10 -10.5035 0.83648E+00 -0.0775 35 CaCl2,aq 0.20542E-14 -14.6874 0.20542E-14 -14.6874 0.10000E+01 0.0000 36 CaOH+ 0.80337E-07 -7.0951 0.67200E-07 -7.1726 0.83648E+00 -0.0775 37 CaSO4,aq 0.17953E-16 -16.7459 0.17953E-16 -16.7459 0.10000E+01 0.0000 38 HCl,aq 0.37671E-14 -14.4240 0.37671E-14 -14.4240 0.10000E+01 0.0000 43 FeCl+ 0.15760E-16 -16.8024 0.13183E-16 -16.8800 0.83648E+00 -0.0775 46 FeO,aq 0.21113E-09 -9.6755 0.21113E-09 -9.6755 0.10000E+01 0.0000 47 FeOH+ 0.15766E-10 -10.8023 0.13188E-10 -10.8798 0.83648E+00 -0.0775 48 HFeO2- 0.35476E-07 -7.4501 0.29618E-07 -7.5284 0.83488E+00 -0.0784 49 FeO+ 0.11050E-16 -16.9567 0.92429E-17 -17.0342 0.83648E+00 -0.0775 51 FeO2- 0.40724E-09 -9.3902 0.34000E-09 -9.4685 0.83488E+00 -0.0784 52 HFeO2,aq 0.32251E-11 -11.4915 0.32251E-11 -11.4915 0.10000E+01 0.0000 53 H2,aq 0.11623E-04 -4.9347 0.11582E-04 -4.9362 0.99650E+00 -0.0015 54 KCl,aq 0.65762E-09 -9.1820 0.65762E-09 -9.1820 0.10000E+01 0.0000 56 KOH,aq 0.75375E-06 -6.1228 0.75375E-06 -6.1228 0.10000E+01 0.0000 57 KSO4- 0.19670E-14 -14.7062 0.16422E-14 -14.7846 0.83488E+00 -0.0784 58 MgCO3,aq 0.19329E-13 -13.7138 0.19329E-13 -13.7138 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.16375E-15 -15.7858 0.13697E-15 -15.8634 0.83648E+00 -0.0775 60 MgCl+ 0.52930E-14 -14.2763 0.44276E-14 -14.3538 0.83648E+00 -0.0775 61 MgOH+ 0.69227E-10 -10.1597 0.57908E-10 -10.2373 0.83648E+00 -0.0775 63 MnO,aq 0.18066E-08 -8.7431 0.18066E-08 -8.7431 0.10000E+01 0.0000 64 MnOH+ 0.47035E-09 -9.3276 0.39344E-09 -9.4051 0.83648E+00 -0.0775 65 MnO2-2 0.20831E-10 -10.6813 0.10778E-10 -10.9674 0.51743E+00 -0.2862 66 HMnO2- 0.21095E-09 -9.6758 0.17612E-09 -9.7542 0.83488E+00 -0.0784 69 MnCl+ 0.19691E-13 -13.7057 0.16471E-13 -13.7833 0.83648E+00 -0.0775 71 NaCl,aq 0.15230E-05 -5.8173 0.15230E-05 -5.8173 0.10000E+01 0.0000 72 NaOH,aq 0.96047E-04 -4.0175 0.96047E-04 -4.0175 0.10000E+01 0.0000 74 OH- 0.92957E-02 -2.0317 0.77467E-02 -2.1109 0.83336E+00 -0.0792 79 HPO3-2 0.16247E-14 -14.7892 0.84066E-15 -15.0754 0.51743E+00 -0.2862 81 H2PO3- 0.15060E-18 -18.8222 0.12573E-18 -18.9006 0.83488E+00 -0.0784 82 H3PO4,aq 0.90611E-18 -18.0428 0.90611E-18 -18.0428 0.10000E+01 0.0000 83 H2PO4- 0.38345E-10 -10.4163 0.32044E-10 -10.4943 0.83567E+00 -0.0780 84 PO4-3 0.10534E-08 -8.9774 0.25478E-09 -9.5938 0.24188E+00 -0.6164 88 HP2O7-3 0.93526E-18 -18.0291 0.21555E-18 -18.6664 0.23047E+00 -0.6374 89 P2O7-4 0.90076E-17 -17.0454 0.69044E-18 -18.1609 0.76650E-01 -1.1155 90 H2S,aq 0.11840E-07 -7.9267 0.11798E-07 -7.9282 0.99650E+00 -0.0015 91 S2-2 0.96860E-14 -14.0139 0.50118E-14 -14.3000 0.51743E+00 -0.2862 97 SO3-2 0.23051E-17 -17.6373 0.12100E-17 -17.9172 0.52494E+00 -0.2799 99 HSO4- 0.69012E-19 -19.1611 0.57784E-19 -19.2382 0.83730E+00 -0.0771 Charge balance for all species = 0.1256E-09 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.8879475E-10 -.2220411E-01 -.2234140E+02 0.0000 2 H2O 0.1000000E+01 0.5550491E+02 0.9981942E+06 0.0000 3 Cl- 0.3301497E-03 0.3316734E-03 0.1173832E+02 6.5677 4 SO4-- 0.1550396E-11 -.3266507E-04 -.3132388E+01 8.1599 5 HCO3- 0.5735049E-06 0.3141872E-04 0.1913740E+01 3.8082 6 HS- 0.6129786E-04 0.9397477E-04 0.3102515E+01 5.8365 7 Al+++ 0.9878829E-29 0.5289953E-05 0.1424820E+00 0.7390 8 H4SiO4 0.6959812E-03 0.1348227E-01 0.1293595E+04 -3.1574 9 Ca++ 0.1366310E-06 0.2341843E-06 0.9369276E-02 13.1018 10 Mg++ 0.2137536E-10 0.9386002E-10 0.2277946E-05 9.2942 11 Fe++ 0.5891417E-13 0.3611362E-07 0.2013321E-02 6.7350 12 K+ 0.1574057E-03 0.1581601E-03 0.6173593E+01 6.2467 13 Na+ 0.1997415E-01 0.2242137E-01 0.5145641E+03 8.3494 14 Mn++ 0.1890422E-10 0.2527689E-08 0.1386241E-03 9.2417 15 HPO4-- 0.4490951E-07 0.4600121E-07 0.4407453E-02 12.6219 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.9603936E+02 -.9236780E-02 -.9603012E+02 0.0000000E+00 2 H2O -.1719712E+02 0.2308971E+02 -.4028683E+02 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.1607632E+00 -.1358847E-04 0.1607768E+00 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.1607377E+00 0.3909294E-04 -.1607768E+00 0.0000000E+00 7 Al+++ 0.1891230E+02 0.2200589E-05 0.1891230E+02 0.0000000E+00 8 H4SiO4 0.6039413E+02 0.5608545E-02 0.6038852E+02 0.0000000E+00 9 Ca++ 0.6670841E+01 0.9741929E-07 0.6670841E+01 0.0000000E+00 10 Mg++ 0.4603174E+01 0.3904521E-10 0.4603174E+01 0.0000000E+00 11 Fe++ 0.4135449E+01 0.1502305E-07 0.4135449E+01 0.0000000E+00 12 K+ 0.1231422E+01 0.6579365E-04 0.1231356E+01 0.0000000E+00 13 Na+ 0.7280572E+01 0.9327156E-02 0.7271245E+01 0.0000000E+00 14 Mn++ 0.1005638E+00 0.1051503E-08 0.1005638E+00 0.0000000E+00 15 HPO4-- 0.3432194E-01 0.1913623E-07 0.3432192E-01 0.0000000E+00 Chg. balance for solid moles: 0.6439E-14 Mass of aqueous solution: 0.416721E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 5799.9990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 7.265 0.861 1905. 3.280 30.07 731.3 andradite 0.6431 -0.192 326.8 2.514 5.158 84.91 grossular 0.1557 -0.808 70.14 1.846 1.107 19.52 apatite-OH 0.1144E-01 -1.942 5.747 0.759 0.9070E-01 1.826 clinochlore 0.8238 -0.084 457.9 2.661 7.226 174.2 daphnite 0.2385 -0.623 170.2 2.231 2.685 51.56 chlorite-Mn 0.2011E-01 -1.697 14.26 1.154 0.2250 4.544 diopside 0.3062 -0.514 66.31 1.822 1.047 20.27 hedenbergite 0.7941E-01 -1.100 19.70 1.295 0.3109 5.396 microcline 1.080 0.033 300.5 2.478 4.743 117.4 stilbite 3.733 0.572 2631. 3.420 41.52 1227. stilpnomelane-Fe 0.3032 -0.518 326.9 2.514 5.158 112.9 tr.625ac.25prg.125 0.4915E-01 -1.308 42.01 1.623 0.6630 13.52 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8051E+00 0.8051E+00 1.0000 -0.094 grossular 0.1949E+00 0.1949E+00 1.0000 -0.710 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.7611E+00 0.7611E+00 1.0000 -0.119 daphnite 0.2203E+00 0.2203E+00 1.0000 -0.657 chlorite-Mn 0.1858E-01 0.1858E-01 1.0000 -1.731 diopside 0.7941E+00 0.7941E+00 1.0000 -0.100 hedenbergite 0.2059E+00 0.2059E+00 1.0000 -0.686 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 tr.625ac.25prg.125 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 6336.343177 g Volume = 2564.402370 cm3 Porosity: -10.4870% V(tot) - V(min): -.24340E+03 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 5799.9990000 g log = 3.7634 Original solution: 1000.0103000 g Original solution / Rock added: 0.17 (Water/Rock Ratio), log = -0.7634 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0794 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9460E+00 0.9852 0.1006E+01 0.1021E+01 CO2,gas 0.7525E-08 1.0066 0.8176E-08 0.8122E-08 CH4,gas 0.3995E-01 1.0121 0.4365E-01 0.4313E-01 H2,gas 0.1408E-01 1.0006 0.1521E-01 0.1520E-01 H2S,gas 0.3017E-06 0.9958 0.3243E-06 0.3257E-06 S2,gas 0.1582E-28 1.0000 0.1708E-28 0.1708E-28 CO,gas 0.3070E-13 1.0000 0.3313E-13 0.3313E-13 SO3,gas 0.1566E-47 1.0000 0.1691E-47 0.1691E-47 SO2,gas 0.9267E-27 1.0000 0.1000E-26 0.1000E-26 HCl,gas 0.6158E-17 1.0000 0.6647E-17 0.6647E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 16 albite -0.38 -0.38 0.00 0.000 0.11184E-10 22 andradite 39.01 39.01 0.00 0.000 0.12132E-10 23 grossular 32.73 32.73 0.00 0.000 0.00000E+00 32 apatite-OH -18.15 -18.15 0.00 0.000 0.00000E+00 46 clinochlore 39.07 39.07 0.00 0.000 0.24265E-10 47 daphnite 28.97 28.97 0.00 0.000 -0.12132E-10 48 chlorite-Mn 46.87 46.87 0.00 0.000 0.12132E-10 67 diopside 16.18 16.18 0.00 0.000 0.60662E-11 68 hedenbergite 14.21 14.21 0.00 0.000 -0.60662E-11 116 microcline -2.49 -2.49 0.00 0.000 0.13649E-10 163 stilbite -7.52 -7.52 0.00 0.000 -0.90992E-11 164 stilpnomelane-Fe 13.02 13.02 0.00 0.000 0.21232E-10 245 tr.625ac.25prg.125 45.16 45.16 0.00 0.000 0.24265E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -16.45 -9.79 -3.262 0.16710E+05 -8.087 3 CH4,gas 4.54 1.48 -3.06 -0.765 0.52231E+04 -1.360 4 H2,gas 8.00 4.48 -3.52 -2.010 0.60051E+04 -1.818 5 H2S,gas -6.23 -14.42 -8.19 -4.094 0.13981E+05 -6.489 6 S2,gas -7.34 -37.80 -30.47 -4.687 0.52021E+05 -28.768 7 CO,gas 3.21 -11.96 -15.18 -4.670 0.25917E+05 -13.480 8 SO3,gas 17.12 -32.35 -49.47 -12.368 0.84470E+05 -47.772 9 SO2,gas 0.83 -27.87 -28.70 -7.653 0.49002E+05 -27.000 10 HCl,gas 5.19 -13.69 -18.88 -9.438 0.32231E+05 -17.177 11 acmite 7.71 6.53 -1.18 -0.123 0.20175E+04 15 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 19 spessartine 24.46 19.73 -4.73 -0.236 0.80705E+04 20 analcite 3.32 2.77 -0.55 -0.061 0.93625E+03 26 annite 20.12 17.72 -2.40 -0.134 0.41064E+04 27 phlogopite 27.06 25.40 -1.67 -0.093 0.28489E+04 29 anorthite 12.71 8.26 -4.45 -0.342 0.75903E+04 35 aragonite 0.97 -3.34 -4.31 -1.437 0.73613E+04 36 brucite 12.57 9.29 -3.27 -0.655 0.55909E+04 37 calcite 0.81 -3.34 -4.16 -1.386 0.70971E+04 38 carnegieite-low 9.02 5.93 -3.09 -0.442 0.52801E+04 39 carnegieite-high 10.09 5.93 -4.16 -0.595 0.71071E+04 40 carpholite-Mg 8.58 4.46 -4.12 -0.275 0.70429E+04 41 carpholite-Fe 6.71 1.90 -4.81 -0.321 0.82207E+04 42 celadonite 5.34 3.65 -1.69 -0.099 0.28879E+04 43 celadonite-Fe 3.88 1.09 -2.79 -0.164 0.47561E+04 44 chrysotile 23.89 21.57 -2.32 -0.194 0.39692E+04 49 chlorite-Al-free 47.17 43.14 -4.04 -0.168 0.68936E+04 51 chloritoid-Fe 9.17 5.06 -4.12 -0.275 0.70316E+04 52 chloritoid-Mn 11.40 7.56 -3.84 -0.256 0.65548E+04 54 coesite -2.38 -3.16 -0.78 -0.260 0.13341E+04 61 cristobalite -2.56 -3.16 -0.60 -0.199 0.10195E+04 63 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71234E+04 65 diaspore 2.87 0.74 -2.13 -0.356 0.36450E+04 66 diamond -3.10 -7.48 -4.38 -1.251 0.74762E+04 71 enstatite 17.26 12.27 -4.99 -0.499 0.85226E+04 73 clinoenstatite 17.17 12.27 -4.89 -0.489 0.83541E+04 75 epidote 24.67 22.70 -1.97 -0.095 0.33585E+04 76 clinozoisite 22.81 18.95 -3.86 -0.175 0.65869E+04 77 epidote-Fe 29.84 26.46 -3.38 -0.176 0.57768E+04 78 fayalite 14.05 10.31 -3.73 -0.533 0.63743E+04 79 ferrosilite 11.15 7.16 -3.99 -0.399 0.68202E+04 83 gibbsite 4.08 0.74 -3.34 -0.477 0.57035E+04 84 glaucophane 22.97 20.80 -2.17 -0.059 0.37134E+04 85 glaucophane-Fe 17.28 13.12 -4.15 -0.112 0.70919E+04 86 graphite -3.55 -7.48 -3.93 -1.124 0.67185E+04 87 greenalite 16.14 13.89 -2.25 -0.187 0.38408E+04 90 hematite 12.57 8.99 -3.58 -0.434 0.61111E+04 91 heulandite -5.83 -7.52 -1.69 -0.077 0.28938E+04 95 jadeite 4.22 2.77 -1.44 -0.144 0.24617E+04 97 kalsilite 7.58 3.83 -3.76 -0.537 0.64126E+04 98 kaolinite -1.33 -4.84 -3.50 -0.319 0.59832E+04 101 laumontite 2.88 1.95 -0.93 -0.062 0.15935E+04 102 lawsonite 9.62 8.26 -1.35 -0.090 0.23070E+04 103 leucite 4.12 0.67 -3.45 -0.345 0.58873E+04 105 lizardite 23.24 21.57 -1.68 -0.140 0.28618E+04 107 magnetite 20.09 15.72 -4.37 -0.356 0.74536E+04 108 minnesotaite 10.39 7.58 -2.81 -0.165 0.48028E+04 112 manganosite 14.06 9.24 -4.82 -1.204 0.82239E+04 120 muscovite 2.58 -1.01 -3.59 -0.211 0.61315E+04 121 paragonite 4.24 1.09 -3.15 -0.185 0.53706E+04 122 nepheline 8.34 5.93 -2.41 -0.344 0.41125E+04 128 periclase-Fe 11.63 6.73 -4.89 -1.223 0.83523E+04 134 phlogopite-Na 29.65 27.50 -2.15 -0.119 0.36678E+04 136 prehnite 19.37 18.21 -1.16 -0.068 0.19849E+04 137 prehnite-Fe 22.50 21.96 -0.53 -0.032 0.91158E+03 138 pumpellyite-Fe 46.27 43.89 -2.38 -0.053 0.40582E+04 139 pumpellyite-Mg 48.99 46.45 -2.54 -0.057 0.43420E+04 143 pyrrhotite -4.26 -7.68 -3.42 -1.141 0.58446E+04 144 pyrrhotiteFe0.875 -6.02 -9.08 -3.06 -1.127 0.52318E+04 145 pyroxmangite 7.40 6.08 -1.31 -0.263 0.22443E+04 146 pyrophyllite -6.18 -11.15 -4.98 -0.311 0.84962E+04 147 quartz -2.99 -3.16 -0.17 -0.056 0.28680E+03 152 rhodonite 7.45 6.08 -1.36 -0.272 0.23246E+04 153 sanidine -1.28 -2.49 -1.21 -0.093 0.20677E+04 165 stilpnomelane-Mg 27.44 25.81 -1.63 -0.049 0.27804E+04 171 talc 16.49 15.25 -1.24 -0.073 0.21140E+04 174 tephroite 18.09 15.33 -2.76 -0.394 0.47124E+04 178 tridymite -2.63 -3.16 -0.53 -0.177 0.90678E+03 179 tremolite 47.87 47.42 -0.45 -0.012 0.77494E+03 180 ferroactinolite 38.45 34.62 -3.83 -0.104 0.65448E+04 181 troilite-low -4.41 -7.68 -3.27 -1.091 0.55874E+04 183 vesuvianite 223.47 218.82 -4.65 -0.036 0.79439E+04 187 wairakite 3.95 1.95 -2.00 -0.118 0.34155E+04 188 walstromite 11.51 9.94 -1.56 -0.313 0.26719E+04 189 wollastonite 10.46 9.94 -0.52 -0.103 0.88229E+03 190 pseudo-wollastonite 11.00 9.94 -1.06 -0.211 0.18021E+04 191 zoisite 22.85 18.95 -3.90 -0.177 0.66609E+04 192 akaganeite 7.75 4.49 -3.26 -0.705 0.55681E+04 199 chalcedony -2.80 -3.16 -0.35 -0.118 0.60610E+03 201 montmorillonite-Ca -2.29 -6.17 -3.88 -0.240 0.66180E+04 202 montmorillonite-K -2.24 -6.27 -4.03 -0.247 0.68816E+04 203 montmorillonite-Mg -2.48 -6.79 -4.32 -0.267 0.73678E+04 204 montmorillonite-Na -2.04 -5.57 -3.54 -0.216 0.60365E+04 205 nontronite-Ca 3.21 -0.19 -3.41 -0.221 0.58215E+04 206 nontronite-H 2.53 -2.36 -4.89 -0.328 0.83485E+04 207 nontronite-K 3.34 -0.30 -3.64 -0.233 0.62083E+04 208 nontronite-Mg 3.07 -0.82 -3.90 -0.253 0.66553E+04 209 nontronite-Na 3.52 0.40 -3.12 -0.200 0.53292E+04 224 tobermorite 9.82 7.76 -2.07 -0.564 0.35287E+04 230 alabandite -0.98 -5.18 -4.20 -1.400 0.71691E+04 233 boehmite 4.41 0.74 -3.67 -0.611 0.62619E+04 235 ferrous-oxide 9.81 6.73 -3.08 -0.769 0.52532E+04 240 silica-amorphous -2.09 -3.16 -1.07 -0.355 0.18203E+04 242 an20ab80 2.02 1.35 -0.67 -0.052 0.11472E+04 243 an25ab75 2.65 1.78 -0.87 -0.067 0.14810E+04 244 an30ab70 3.28 2.21 -1.07 -0.082 0.18244E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 100.0000000 g Current total amount of reactant added: 5799.9990000 g New total amount of reactant added: 5899.9990000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.5223E-10 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 12 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 5899.9990000 Water: Moles liquid = 0.2253E+02 kg liquid = 0.4060E+00 Moles total = -.1845E+02 kg total = -.3324E+00 Activity = 1.0000 Stoichiometric ionic strength = .1148490E-01 Osmotic coef. = 0.9683 True ionic strength = .2013851E-01 Chg. balance for total moles = 0.5223E-10 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.88818E-10 -10.0515 0.74601E-10 -10.1273 0.83994E+00 -0.0758 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.33832E-03 -3.4707 0.28245E-03 -3.5491 0.83486E+00 -0.0784 4 SO4-- 0.15884E-11 -11.7990 0.82360E-12 -12.0843 0.51850E+00 -0.2853 5 HCO3- 0.58757E-06 -6.2309 0.49126E-06 -6.3087 0.83609E+00 -0.0777 6 HS- 0.62814E-04 -4.2019 0.52449E-04 -4.2803 0.83499E+00 -0.0783 7 Al+++ 0.98876E-29 -29.0049 0.22762E-29 -29.6428 0.23021E+00 -0.6379 8 H4SiO4 0.69598E-03 -3.1574 0.69598E-03 -3.1574 0.10000E+01 0.0000 9 Ca++ 0.13671E-06 -6.8642 0.70359E-07 -7.1527 0.51467E+00 -0.2885 10 Mg++ 0.21387E-10 -10.6698 0.10957E-10 -10.9603 0.51231E+00 -0.2905 11 Fe++ 0.58947E-13 -13.2295 0.30232E-13 -13.5195 0.51287E+00 -0.2900 12 K+ 0.15745E-03 -3.8029 0.13167E-03 -3.8805 0.83629E+00 -0.0776 13 Na+ 0.19979E-01 -1.6994 0.16677E-01 -1.7779 0.83471E+00 -0.0785 14 Mn++ 0.18915E-10 -10.7232 0.97092E-11 -11.0128 0.51330E+00 -0.2896 15 HPO4-- 0.44891E-07 -7.3478 0.23279E-07 -7.6330 0.51857E+00 -0.2852 16 HSiO3- 0.10434E-01 -1.9815 0.87112E-02 -2.0599 0.83486E+00 -0.0784 17 Ca(HSiO3)+ 0.16687E-07 -7.7776 0.13958E-07 -7.8552 0.83647E+00 -0.0775 18 Mg(HSiO3)+ 0.32341E-11 -11.4903 0.27052E-11 -11.5678 0.83647E+00 -0.0775 19 NaHSiO3,aq 0.23496E-02 -2.6290 0.23496E-02 -2.6290 0.10000E+01 0.0000 20 AlO+ 0.66518E-16 -16.1771 0.55640E-16 -16.2546 0.83647E+00 -0.0775 22 HAlO2,aq 0.14853E-09 -9.8282 0.14853E-09 -9.8282 0.10000E+01 0.0000 23 AlO2- 0.52886E-05 -5.2767 0.44072E-05 -5.3558 0.83335E+00 -0.0792 24 CH4,aq 0.30496E-04 -4.5158 0.30389E-04 -4.5173 0.99650E+00 -0.0015 25 C2H6,aq 0.13679E-13 -13.8640 0.13631E-13 -13.8655 0.99650E+00 -0.0015 29 CO,aq 0.22785E-16 -16.6423 0.22785E-16 -16.6423 0.10000E+01 0.0000 30 CO2,aq 0.78585E-10 -10.1047 0.78310E-10 -10.1062 0.99650E+00 -0.0015 31 CO3-2 0.11117E-05 -5.9540 0.57519E-06 -6.2402 0.51739E+00 -0.2862 32 CaCO3,aq 0.50745E-09 -9.2946 0.50745E-09 -9.2946 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.10548E-11 -11.9768 0.88230E-12 -12.0544 0.83647E+00 -0.0775 34 CaCl+ 0.38448E-10 -10.4151 0.32161E-10 -10.4927 0.83647E+00 -0.0775 35 CaCl2,aq 0.21581E-14 -14.6659 0.21581E-14 -14.6659 0.10000E+01 0.0000 36 CaOH+ 0.80358E-07 -7.0950 0.67217E-07 -7.1725 0.83647E+00 -0.0775 37 CaSO4,aq 0.18401E-16 -16.7352 0.18401E-16 -16.7352 0.10000E+01 0.0000 38 HCl,aq 0.38612E-14 -14.4133 0.38612E-14 -14.4133 0.10000E+01 0.0000 43 FeCl+ 0.16158E-16 -16.7916 0.13516E-16 -16.8692 0.83647E+00 -0.0775 46 FeO,aq 0.21113E-09 -9.6755 0.21113E-09 -9.6755 0.10000E+01 0.0000 47 FeOH+ 0.15770E-10 -10.8022 0.13191E-10 -10.8797 0.83647E+00 -0.0775 48 HFeO2- 0.35468E-07 -7.4502 0.29611E-07 -7.5285 0.83486E+00 -0.0784 49 FeO+ 0.11053E-16 -16.9565 0.92451E-17 -17.0341 0.83647E+00 -0.0775 51 FeO2- 0.40715E-09 -9.3902 0.33991E-09 -9.4686 0.83486E+00 -0.0784 52 HFeO2,aq 0.32251E-11 -11.4915 0.32251E-11 -11.4915 0.10000E+01 0.0000 53 H2,aq 0.11623E-04 -4.9347 0.11582E-04 -4.9362 0.99650E+00 -0.0015 54 KCl,aq 0.67404E-09 -9.1713 0.67404E-09 -9.1713 0.10000E+01 0.0000 56 KOH,aq 0.75375E-06 -6.1228 0.75375E-06 -6.1228 0.10000E+01 0.0000 57 KSO4- 0.20157E-14 -14.6956 0.16828E-14 -14.7740 0.83486E+00 -0.0784 58 MgCO3,aq 0.19808E-13 -13.7032 0.19808E-13 -13.7032 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.16784E-15 -15.7751 0.14040E-15 -15.8526 0.83647E+00 -0.0775 60 MgCl+ 0.54266E-14 -14.2655 0.45392E-14 -14.3430 0.83647E+00 -0.0775 61 MgOH+ 0.69246E-10 -10.1596 0.57922E-10 -10.2372 0.83647E+00 -0.0775 63 MnO,aq 0.18067E-08 -8.7431 0.18067E-08 -8.7431 0.10000E+01 0.0000 64 MnOH+ 0.47049E-09 -9.3275 0.39355E-09 -9.4050 0.83647E+00 -0.0775 65 MnO2-2 0.20823E-10 -10.6815 0.10773E-10 -10.9676 0.51739E+00 -0.2862 66 HMnO2- 0.21091E-09 -9.6759 0.17608E-09 -9.7543 0.83486E+00 -0.0784 69 MnCl+ 0.20189E-13 -13.6949 0.16887E-13 -13.7724 0.83647E+00 -0.0775 71 NaCl,aq 0.15610E-05 -5.8066 0.15610E-05 -5.8066 0.10000E+01 0.0000 72 NaOH,aq 0.96047E-04 -4.0175 0.96047E-04 -4.0175 0.10000E+01 0.0000 74 OH- 0.92936E-02 -2.0318 0.77448E-02 -2.1110 0.83335E+00 -0.0792 79 HPO3-2 0.16240E-14 -14.7894 0.84025E-15 -15.0756 0.51739E+00 -0.2862 81 H2PO3- 0.15056E-18 -18.8223 0.12570E-18 -18.9007 0.83486E+00 -0.0784 82 H3PO4,aq 0.90611E-18 -18.0428 0.90611E-18 -18.0428 0.10000E+01 0.0000 83 H2PO4- 0.38337E-10 -10.4164 0.32036E-10 -10.4944 0.83566E+00 -0.0780 84 PO4-3 0.10527E-08 -8.9777 0.25459E-09 -9.5942 0.24184E+00 -0.6165 88 HP2O7-3 0.93473E-18 -18.0293 0.21540E-18 -18.6668 0.23044E+00 -0.6374 89 P2O7-4 0.90013E-17 -17.0457 0.68976E-18 -18.1613 0.76629E-01 -1.1156 90 H2S,aq 0.12135E-07 -7.9159 0.12093E-07 -7.9175 0.99650E+00 -0.0015 91 S2-2 0.10172E-13 -13.9926 0.52627E-14 -14.2788 0.51739E+00 -0.2862 97 SO3-2 0.23616E-17 -17.6268 0.12396E-17 -17.9067 0.52491E+00 -0.2799 99 HSO4- 0.70720E-19 -19.1505 0.59213E-19 -19.2276 0.83729E+00 -0.0771 Charge balance for all species = 0.1287E-09 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.8881793E-10 -.2219967E-01 -.2233692E+02 0.0000 2 H2O 0.1000000E+01 0.5550491E+02 0.9981940E+06 0.0000 3 Cl- 0.3383168E-03 0.3398785E-03 0.1202870E+02 6.5782 4 SO4-- 0.1588448E-11 -.3340184E-04 -.3203039E+01 8.1702 5 HCO3- 0.5875705E-06 0.3219597E-04 0.1961082E+01 3.8186 6 HS- 0.6281427E-04 0.9622825E-04 0.3176911E+01 5.8470 7 Al+++ 0.9887631E-29 0.5288750E-05 0.1424496E+00 0.7390 8 H4SiO4 0.6959814E-03 0.1347991E-01 0.1293368E+04 -3.1574 9 Ca++ 0.1367074E-06 0.2342994E-06 0.9373877E-02 13.1018 10 Mg++ 0.2138734E-10 0.9388688E-10 0.2278598E-05 9.2942 11 Fe++ 0.5894718E-13 0.3610548E-07 0.2012867E-02 6.7350 12 K+ 0.1574469E-03 0.1582013E-03 0.6175201E+01 6.2467 13 Na+ 0.1997939E-01 0.2242665E-01 0.5146851E+03 8.3494 14 Mn++ 0.1891531E-10 0.2527832E-08 0.1386319E-03 9.2417 15 HPO4-- 0.4489067E-07 0.4598175E-07 0.4405587E-02 12.6215 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.9769521E+02 -.9011987E-02 -.9768620E+02 0.0000000E+00 2 H2O -.1845066E+02 0.2253230E+02 -.4098296E+02 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.1635346E+00 -.1355953E-04 0.1635481E+00 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.1635091E+00 0.3906400E-04 -.1635481E+00 0.0000000E+00 7 Al+++ 0.1923837E+02 0.2146976E-05 0.1923837E+02 0.0000000E+00 8 H4SiO4 0.6143541E+02 0.5472188E-02 0.6142994E+02 0.0000000E+00 9 Ca++ 0.6785855E+01 0.9511417E-07 0.6785855E+01 0.0000000E+00 10 Mg++ 0.4682539E+01 0.3811351E-10 0.4682539E+01 0.0000000E+00 11 Fe++ 0.4206750E+01 0.1465707E-07 0.4206750E+01 0.0000000E+00 12 K+ 0.1252654E+01 0.6422204E-04 0.1252589E+01 0.0000000E+00 13 Na+ 0.7406096E+01 0.9104129E-02 0.7396992E+01 0.0000000E+00 14 Mn++ 0.1022977E+00 0.1026177E-08 0.1022977E+00 0.0000000E+00 15 HPO4-- 0.3491370E-01 0.1866636E-07 0.3491368E-01 0.0000000E+00 Chg. balance for solid moles: -.2109E-14 Mass of aqueous solution: 0.406661E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 5899.9990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 7.391 0.869 1938. 3.287 30.07 744.0 andradite 0.6542 -0.184 332.4 2.522 5.158 86.37 grossular 0.1584 -0.800 71.35 1.853 1.107 19.85 apatite-OH 0.1164E-01 -1.934 5.846 0.767 0.9070E-01 1.858 clinochlore 0.8379 -0.077 465.8 2.668 7.226 177.2 daphnite 0.2426 -0.615 173.1 2.238 2.685 52.45 chlorite-Mn 0.2046E-01 -1.689 14.51 1.162 0.2250 4.622 diopside 0.3116 -0.506 67.49 1.829 1.047 20.63 hedenbergite 0.8082E-01 -1.092 20.05 1.302 0.3111 5.492 microcline 1.098 0.041 305.7 2.485 4.743 119.4 stilbite 3.797 0.579 2676. 3.428 41.52 1248. stilpnomelane-Fe 0.3084 -0.511 332.5 2.522 5.158 114.8 tr.625ac.25prg.125 0.4999E-01 -1.301 42.73 1.631 0.6629 13.75 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8051E+00 0.8051E+00 1.0000 -0.094 grossular 0.1949E+00 0.1949E+00 1.0000 -0.710 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.7611E+00 0.7611E+00 1.0000 -0.119 daphnite 0.2203E+00 0.2203E+00 1.0000 -0.657 chlorite-Mn 0.1858E-01 0.1858E-01 1.0000 -1.731 diopside 0.7941E+00 0.7941E+00 1.0000 -0.100 hedenbergite 0.2059E+00 0.2059E+00 1.0000 -0.686 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 tr.625ac.25prg.125 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 6445.593841 g Volume = 2608.605434 cm3 Porosity: -10.4873% V(tot) - V(min): -.24761E+03 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 5899.9990000 g log = 3.7709 Original solution: 1000.0103000 g Original solution / Rock added: 0.17 (Water/Rock Ratio), log = -0.7708 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0805 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9450E+00 0.9851 0.1006E+01 0.1021E+01 CO2,gas 0.7703E-08 1.0066 0.8378E-08 0.8324E-08 CH4,gas 0.4090E-01 1.0121 0.4473E-01 0.4419E-01 H2,gas 0.1407E-01 1.0006 0.1521E-01 0.1520E-01 H2S,gas 0.3090E-06 0.9958 0.3324E-06 0.3338E-06 S2,gas 0.1660E-28 1.0000 0.1794E-28 0.1794E-28 CO,gas 0.3142E-13 1.0000 0.3395E-13 0.3395E-13 SO3,gas 0.1604E-47 1.0000 0.1733E-47 0.1733E-47 SO2,gas 0.9489E-27 1.0000 0.1025E-26 0.1025E-26 HCl,gas 0.6305E-17 1.0000 0.6813E-17 0.6813E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 16 albite -0.38 -0.38 0.00 0.000 0.11184E-10 22 andradite 39.01 39.01 0.00 0.000 -0.12132E-10 23 grossular 32.73 32.73 0.00 0.000 0.00000E+00 32 apatite-OH -18.15 -18.15 0.00 0.000 0.00000E+00 46 clinochlore 39.07 39.07 0.00 0.000 0.24265E-10 47 daphnite 28.97 28.97 0.00 0.000 0.60662E-10 48 chlorite-Mn 46.87 46.87 0.00 0.000 0.36397E-10 67 diopside 16.18 16.18 0.00 0.000 0.60662E-11 68 hedenbergite 14.21 14.21 0.00 0.000 0.00000E+00 116 microcline -2.49 -2.49 0.00 0.000 0.13649E-10 163 stilbite -7.52 -7.52 0.00 0.000 0.15165E-10 164 stilpnomelane-Fe 13.02 13.02 0.00 0.000 -0.75827E-10 245 tr.625ac.25prg.125 45.16 45.16 0.00 0.000 -0.60662E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -16.44 -9.78 -3.259 0.16692E+05 -8.077 3 CH4,gas 4.54 1.50 -3.05 -0.762 0.52050E+04 -1.349 4 H2,gas 8.00 4.48 -3.52 -2.010 0.60051E+04 -1.818 5 H2S,gas -6.23 -14.41 -8.18 -4.089 0.13962E+05 -6.478 6 S2,gas -7.34 -37.78 -30.45 -4.684 0.51984E+05 -28.746 7 CO,gas 3.21 -11.95 -15.17 -4.667 0.25899E+05 -13.469 8 SO3,gas 17.12 -32.34 -49.46 -12.365 0.84452E+05 -47.761 9 SO2,gas 0.83 -27.86 -28.69 -7.650 0.48984E+05 -26.989 10 HCl,gas 5.19 -13.68 -18.87 -9.433 0.32213E+05 -17.167 11 acmite 7.71 6.53 -1.18 -0.123 0.20175E+04 15 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 19 spessartine 24.46 19.73 -4.73 -0.236 0.80704E+04 20 analcite 3.32 2.77 -0.55 -0.061 0.93625E+03 26 annite 20.12 17.72 -2.40 -0.134 0.41064E+04 27 phlogopite 27.06 25.40 -1.67 -0.093 0.28489E+04 29 anorthite 12.71 8.26 -4.45 -0.342 0.75903E+04 35 aragonite 0.97 -3.33 -4.30 -1.434 0.73432E+04 36 brucite 12.57 9.29 -3.27 -0.655 0.55909E+04 37 calcite 0.81 -3.33 -4.15 -1.382 0.70790E+04 38 carnegieite-low 9.02 5.93 -3.09 -0.442 0.52801E+04 39 carnegieite-high 10.09 5.93 -4.16 -0.595 0.71071E+04 40 carpholite-Mg 8.58 4.46 -4.12 -0.275 0.70429E+04 41 carpholite-Fe 6.71 1.90 -4.81 -0.321 0.82207E+04 42 celadonite 5.34 3.65 -1.69 -0.099 0.28879E+04 43 celadonite-Fe 3.88 1.09 -2.79 -0.164 0.47561E+04 44 chrysotile 23.89 21.57 -2.32 -0.194 0.39692E+04 49 chlorite-Al-free 47.17 43.14 -4.04 -0.168 0.68936E+04 51 chloritoid-Fe 9.17 5.06 -4.12 -0.275 0.70316E+04 52 chloritoid-Mn 11.40 7.56 -3.84 -0.256 0.65547E+04 54 coesite -2.38 -3.16 -0.78 -0.260 0.13341E+04 61 cristobalite -2.56 -3.16 -0.60 -0.199 0.10195E+04 63 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71234E+04 65 diaspore 2.87 0.74 -2.13 -0.356 0.36450E+04 66 diamond -3.10 -7.47 -4.37 -1.248 0.74581E+04 71 enstatite 17.26 12.27 -4.99 -0.499 0.85226E+04 73 clinoenstatite 17.17 12.27 -4.89 -0.489 0.83541E+04 75 epidote 24.67 22.70 -1.97 -0.095 0.33585E+04 76 clinozoisite 22.81 18.95 -3.86 -0.175 0.65869E+04 77 epidote-Fe 29.84 26.46 -3.38 -0.176 0.57768E+04 78 fayalite 14.05 10.31 -3.73 -0.533 0.63743E+04 79 ferrosilite 11.15 7.16 -3.99 -0.399 0.68202E+04 83 gibbsite 4.08 0.74 -3.34 -0.477 0.57035E+04 84 glaucophane 22.97 20.80 -2.17 -0.059 0.37134E+04 85 glaucophane-Fe 17.28 13.12 -4.15 -0.112 0.70919E+04 86 graphite -3.55 -7.47 -3.92 -1.121 0.67003E+04 87 greenalite 16.14 13.89 -2.25 -0.187 0.38408E+04 90 hematite 12.57 8.99 -3.58 -0.434 0.61111E+04 91 heulandite -5.83 -7.52 -1.69 -0.077 0.28938E+04 95 jadeite 4.22 2.77 -1.44 -0.144 0.24617E+04 97 kalsilite 7.58 3.83 -3.76 -0.537 0.64126E+04 98 kaolinite -1.33 -4.84 -3.50 -0.319 0.59832E+04 101 laumontite 2.88 1.95 -0.93 -0.062 0.15935E+04 102 lawsonite 9.62 8.26 -1.35 -0.090 0.23070E+04 103 leucite 4.12 0.67 -3.45 -0.345 0.58873E+04 105 lizardite 23.24 21.57 -1.68 -0.140 0.28618E+04 107 magnetite 20.09 15.72 -4.37 -0.356 0.74536E+04 108 minnesotaite 10.39 7.58 -2.81 -0.165 0.48028E+04 112 manganosite 14.06 9.24 -4.82 -1.204 0.82239E+04 120 muscovite 2.58 -1.01 -3.59 -0.211 0.61315E+04 121 paragonite 4.24 1.09 -3.15 -0.185 0.53706E+04 122 nepheline 8.34 5.93 -2.41 -0.344 0.41125E+04 128 periclase-Fe 11.63 6.73 -4.89 -1.223 0.83523E+04 134 phlogopite-Na 29.65 27.50 -2.15 -0.119 0.36678E+04 136 prehnite 19.37 18.21 -1.16 -0.068 0.19849E+04 137 prehnite-Fe 22.50 21.96 -0.53 -0.032 0.91159E+03 138 pumpellyite-Fe 46.27 43.89 -2.38 -0.053 0.40582E+04 139 pumpellyite-Mg 48.99 46.45 -2.54 -0.057 0.43420E+04 143 pyrrhotite -4.26 -7.67 -3.41 -1.137 0.58263E+04 144 pyrrhotiteFe0.875 -6.02 -9.07 -3.05 -1.123 0.52135E+04 145 pyroxmangite 7.40 6.08 -1.31 -0.263 0.22443E+04 146 pyrophyllite -6.18 -11.15 -4.98 -0.311 0.84962E+04 147 quartz -2.99 -3.16 -0.17 -0.056 0.28680E+03 152 rhodonite 7.45 6.08 -1.36 -0.272 0.23245E+04 153 sanidine -1.28 -2.49 -1.21 -0.093 0.20677E+04 165 stilpnomelane-Mg 27.44 25.81 -1.63 -0.049 0.27804E+04 171 talc 16.49 15.25 -1.24 -0.073 0.21140E+04 174 tephroite 18.09 15.33 -2.76 -0.394 0.47123E+04 178 tridymite -2.63 -3.16 -0.53 -0.177 0.90678E+03 179 tremolite 47.87 47.42 -0.45 -0.012 0.77494E+03 180 ferroactinolite 38.45 34.62 -3.83 -0.104 0.65448E+04 181 troilite-low -4.41 -7.67 -3.26 -1.087 0.55691E+04 183 vesuvianite 223.47 218.82 -4.65 -0.036 0.79439E+04 187 wairakite 3.95 1.95 -2.00 -0.118 0.34155E+04 188 walstromite 11.51 9.94 -1.56 -0.313 0.26719E+04 189 wollastonite 10.46 9.94 -0.52 -0.103 0.88229E+03 190 pseudo-wollastonite 11.00 9.94 -1.06 -0.211 0.18021E+04 191 zoisite 22.85 18.95 -3.90 -0.177 0.66609E+04 192 akaganeite 7.75 4.49 -3.26 -0.705 0.55681E+04 199 chalcedony -2.80 -3.16 -0.35 -0.118 0.60610E+03 201 montmorillonite-Ca -2.29 -6.17 -3.88 -0.240 0.66180E+04 202 montmorillonite-K -2.24 -6.27 -4.03 -0.247 0.68816E+04 203 montmorillonite-Mg -2.48 -6.79 -4.32 -0.267 0.73678E+04 204 montmorillonite-Na -2.04 -5.57 -3.54 -0.216 0.60365E+04 205 nontronite-Ca 3.21 -0.19 -3.41 -0.221 0.58215E+04 206 nontronite-H 2.53 -2.36 -4.89 -0.328 0.83485E+04 207 nontronite-K 3.34 -0.30 -3.64 -0.233 0.62083E+04 208 nontronite-Mg 3.07 -0.82 -3.90 -0.253 0.66553E+04 209 nontronite-Na 3.52 0.40 -3.12 -0.200 0.53292E+04 224 tobermorite 9.82 7.76 -2.07 -0.564 0.35287E+04 230 alabandite -0.98 -5.17 -4.19 -1.396 0.71508E+04 233 boehmite 4.41 0.74 -3.67 -0.611 0.62619E+04 235 ferrous-oxide 9.81 6.73 -3.08 -0.769 0.52532E+04 240 silica-amorphous -2.09 -3.16 -1.07 -0.355 0.18203E+04 242 an20ab80 2.02 1.35 -0.67 -0.052 0.11472E+04 243 an25ab75 2.65 1.78 -0.87 -0.067 0.14810E+04 244 an30ab70 3.28 2.21 -1.07 -0.082 0.18244E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 100.0000000 g Current total amount of reactant added: 5899.9990000 g New total amount of reactant added: 5999.9990000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.5222E-10 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 12 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 5999.9990000 Water: Moles liquid = 0.2198E+02 kg liquid = 0.3959E+00 Moles total = -.1970E+02 kg total = -.3550E+00 Activity = 1.0000 Stoichiometric ionic strength = .1149204E-01 Osmotic coef. = 0.9683 True ionic strength = .2014408E-01 Chg. balance for total moles = 0.5222E-10 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.88842E-10 -10.0514 0.74621E-10 -10.1271 0.83992E+00 -0.0758 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.34690E-03 -3.4598 0.28961E-03 -3.5382 0.83485E+00 -0.0784 4 SO4-- 0.16284E-11 -11.7882 0.84426E-12 -12.0735 0.51846E+00 -0.2853 5 HCO3- 0.60234E-06 -6.2202 0.50360E-06 -6.2979 0.83607E+00 -0.0778 6 HS- 0.64408E-04 -4.1911 0.53778E-04 -4.2694 0.83497E+00 -0.0783 7 Al+++ 0.98969E-29 -29.0045 0.22779E-29 -29.6425 0.23017E+00 -0.6380 8 H4SiO4 0.69598E-03 -3.1574 0.69598E-03 -3.1574 0.10000E+01 0.0000 9 Ca++ 0.13679E-06 -6.8640 0.70396E-07 -7.1525 0.51463E+00 -0.2885 10 Mg++ 0.21400E-10 -10.6696 0.10962E-10 -10.9601 0.51227E+00 -0.2905 11 Fe++ 0.58982E-13 -13.2293 0.30248E-13 -13.5193 0.51283E+00 -0.2900 12 K+ 0.15749E-03 -3.8027 0.13170E-03 -3.8804 0.83627E+00 -0.0777 13 Na+ 0.19985E-01 -1.6993 0.16681E-01 -1.7778 0.83470E+00 -0.0785 14 Mn++ 0.18927E-10 -10.7229 0.97144E-11 -11.0126 0.51326E+00 -0.2897 15 HPO4-- 0.44871E-07 -7.3480 0.23267E-07 -7.6333 0.51853E+00 -0.2852 16 HSiO3- 0.10432E-01 -1.9816 0.87089E-02 -2.0600 0.83485E+00 -0.0784 17 Ca(HSiO3)+ 0.16692E-07 -7.7775 0.13962E-07 -7.8551 0.83645E+00 -0.0776 18 Mg(HSiO3)+ 0.32350E-11 -11.4901 0.27059E-11 -11.5677 0.83645E+00 -0.0776 19 NaHSiO3,aq 0.23496E-02 -2.6290 0.23496E-02 -2.6290 0.10000E+01 0.0000 20 AlO+ 0.66536E-16 -16.1769 0.55655E-16 -16.2545 0.83645E+00 -0.0776 22 HAlO2,aq 0.14853E-09 -9.8282 0.14853E-09 -9.8282 0.10000E+01 0.0000 23 AlO2- 0.52873E-05 -5.2768 0.44061E-05 -5.3559 0.83333E+00 -0.0792 24 CH4,aq 0.31270E-04 -4.5049 0.31161E-04 -4.5064 0.99650E+00 -0.0015 25 C2H6,aq 0.14382E-13 -13.8422 0.14332E-13 -13.8437 0.99650E+00 -0.0015 29 CO,aq 0.23364E-16 -16.6315 0.23364E-16 -16.6315 0.10000E+01 0.0000 30 CO2,aq 0.80580E-10 -10.0938 0.80298E-10 -10.0953 0.99650E+00 -0.0015 31 CO3-2 0.11394E-05 -5.9433 0.58949E-06 -6.2295 0.51735E+00 -0.2862 32 CaCO3,aq 0.52033E-09 -9.2837 0.52033E-09 -9.2837 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.10819E-11 -11.9658 0.90493E-12 -12.0434 0.83645E+00 -0.0776 34 CaCl+ 0.39443E-10 -10.4040 0.32993E-10 -10.4816 0.83645E+00 -0.0776 35 CaCl2,aq 0.22700E-14 -14.6440 0.22700E-14 -14.6440 0.10000E+01 0.0000 36 CaOH+ 0.80380E-07 -7.0949 0.67234E-07 -7.1724 0.83645E+00 -0.0776 37 CaSO4,aq 0.18873E-16 -16.7242 0.18873E-16 -16.7242 0.10000E+01 0.0000 38 HCl,aq 0.39601E-14 -14.4023 0.39601E-14 -14.4023 0.10000E+01 0.0000 43 FeCl+ 0.16577E-16 -16.7805 0.13866E-16 -16.8581 0.83645E+00 -0.0776 46 FeO,aq 0.21113E-09 -9.6755 0.21113E-09 -9.6755 0.10000E+01 0.0000 47 FeOH+ 0.15775E-10 -10.8020 0.13195E-10 -10.8796 0.83645E+00 -0.0776 48 HFeO2- 0.35460E-07 -7.4503 0.29603E-07 -7.5287 0.83485E+00 -0.0784 49 FeO+ 0.11056E-16 -16.9564 0.92475E-17 -17.0340 0.83645E+00 -0.0776 51 FeO2- 0.40705E-09 -9.3904 0.33982E-09 -9.4687 0.83485E+00 -0.0784 52 HFeO2,aq 0.32251E-11 -11.4915 0.32251E-11 -11.4915 0.10000E+01 0.0000 53 H2,aq 0.11623E-04 -4.9347 0.11582E-04 -4.9362 0.99650E+00 -0.0015 54 KCl,aq 0.69131E-09 -9.1603 0.69131E-09 -9.1603 0.10000E+01 0.0000 56 KOH,aq 0.75375E-06 -6.1228 0.75375E-06 -6.1228 0.10000E+01 0.0000 57 KSO4- 0.20668E-14 -14.6847 0.17255E-14 -14.7631 0.83485E+00 -0.0784 58 MgCO3,aq 0.20311E-13 -13.6923 0.20311E-13 -13.6923 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.17215E-15 -15.7641 0.14400E-15 -15.8416 0.83645E+00 -0.0776 60 MgCl+ 0.55671E-14 -14.2544 0.46567E-14 -14.3319 0.83645E+00 -0.0776 61 MgOH+ 0.69265E-10 -10.1595 0.57937E-10 -10.2370 0.83645E+00 -0.0776 63 MnO,aq 0.18067E-08 -8.7431 0.18067E-08 -8.7431 0.10000E+01 0.0000 64 MnOH+ 0.47063E-09 -9.3273 0.39366E-09 -9.4049 0.83645E+00 -0.0776 65 MnO2-2 0.20814E-10 -10.6816 0.10768E-10 -10.9679 0.51735E+00 -0.2862 66 HMnO2- 0.21087E-09 -9.6760 0.17604E-09 -9.7544 0.83485E+00 -0.0784 69 MnCl+ 0.20712E-13 -13.6838 0.17324E-13 -13.7613 0.83645E+00 -0.0776 71 NaCl,aq 0.16010E-05 -5.7956 0.16010E-05 -5.7956 0.10000E+01 0.0000 72 NaOH,aq 0.96047E-04 -4.0175 0.96047E-04 -4.0175 0.10000E+01 0.0000 74 OH- 0.92914E-02 -2.0319 0.77428E-02 -2.1111 0.83333E+00 -0.0792 79 HPO3-2 0.16233E-14 -14.7896 0.83982E-15 -15.0758 0.51735E+00 -0.2862 81 H2PO3- 0.15053E-18 -18.8224 0.12567E-18 -18.9008 0.83485E+00 -0.0784 82 H3PO4,aq 0.90611E-18 -18.0428 0.90611E-18 -18.0428 0.10000E+01 0.0000 83 H2PO4- 0.38328E-10 -10.4165 0.32028E-10 -10.4945 0.83564E+00 -0.0780 84 PO4-3 0.10521E-08 -8.9779 0.25440E-09 -9.5945 0.24180E+00 -0.6165 88 HP2O7-3 0.93416E-18 -18.0296 0.21523E-18 -18.6671 0.23040E+00 -0.6375 89 P2O7-4 0.89947E-17 -17.0460 0.68906E-18 -18.1617 0.76607E-01 -1.1157 90 H2S,aq 0.12446E-07 -7.9050 0.12403E-07 -7.9065 0.99650E+00 -0.0015 91 S2-2 0.10695E-13 -13.9708 0.55328E-14 -14.2571 0.51735E+00 -0.2862 97 SO3-2 0.24210E-17 -17.6160 0.12707E-17 -17.8959 0.52487E+00 -0.2799 99 HSO4- 0.72514E-19 -19.1396 0.60714E-19 -19.2167 0.83727E+00 -0.0771 Charge balance for all species = 0.1319E-09 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.8884229E-10 -.2219500E-01 -.2233221E+02 0.0000 2 H2O 0.1000000E+01 0.5550491E+02 0.9981937E+06 0.0000 3 Cl- 0.3468982E-03 0.3484999E-03 0.1233382E+02 6.5890 4 SO4-- 0.1628414E-11 -.3417602E-04 -.3277278E+01 8.1808 5 HCO3- 0.6023432E-06 0.3301265E-04 0.2010827E+01 3.8292 6 HS- 0.6440762E-04 0.9859609E-04 0.3255083E+01 5.8577 7 Al+++ 0.9896888E-29 0.5287488E-05 0.1424155E+00 0.7390 8 H4SiO4 0.6959816E-03 0.1347743E-01 0.1293129E+04 -3.1574 9 Ca++ 0.1367878E-06 0.2344203E-06 0.9378713E-02 13.1018 10 Mg++ 0.2139993E-10 0.9392183E-10 0.2279445E-05 9.2942 11 Fe++ 0.5898188E-13 0.3609693E-07 0.2012390E-02 6.7350 12 K+ 0.1574902E-03 0.1582446E-03 0.6176891E+01 6.2467 13 Na+ 0.1998490E-01 0.2243219E-01 0.5148122E+03 8.3494 14 Mn++ 0.1892691E-10 0.2527977E-08 0.1386398E-03 9.2417 15 HPO4-- 0.4487088E-07 0.4596130E-07 0.4403626E-02 12.6210 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.9935106E+02 -.8787194E-02 -.9934228E+02 0.0000000E+00 2 H2O -.1970420E+02 0.2197488E+02 -.4167908E+02 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.1663059E+00 -.1353059E-04 0.1663195E+00 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.1662804E+00 0.3903506E-04 -.1663195E+00 0.0000000E+00 7 Al+++ 0.1956445E+02 0.2093363E-05 0.1956444E+02 0.0000000E+00 8 H4SiO4 0.6247669E+02 0.5335831E-02 0.6247135E+02 0.0000000E+00 9 Ca++ 0.6900869E+01 0.9280907E-07 0.6900869E+01 0.0000000E+00 10 Mg++ 0.4761904E+01 0.3718448E-10 0.4761904E+01 0.0000000E+00 11 Fe++ 0.4278051E+01 0.1429109E-07 0.4278051E+01 0.0000000E+00 12 K+ 0.1273885E+01 0.6265045E-04 0.1273822E+01 0.0000000E+00 13 Na+ 0.7531621E+01 0.8881102E-02 0.7522739E+01 0.0000000E+00 14 Mn++ 0.1040316E+00 0.1000848E-08 0.1040316E+00 0.0000000E+00 15 HPO4-- 0.3550545E-01 0.1819648E-07 0.3550544E-01 0.0000000E+00 Chg. balance for solid moles: 0.2276E-14 Mass of aqueous solution: 0.396600E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 5999.9990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 7.516 0.876 1971. 3.295 30.07 756.6 andradite 0.6653 -0.177 338.1 2.529 5.158 87.84 grossular 0.1611 -0.793 72.56 1.861 1.107 20.19 apatite-OH 0.1184E-01 -1.927 5.945 0.774 0.9070E-01 1.889 clinochlore 0.8521 -0.069 473.6 2.675 7.226 180.2 daphnite 0.2467 -0.608 176.0 2.246 2.685 53.34 chlorite-Mn 0.2081E-01 -1.682 14.75 1.169 0.2250 4.701 diopside 0.3171 -0.499 68.67 1.837 1.048 20.99 hedenbergite 0.8223E-01 -1.085 20.40 1.310 0.3112 5.588 microcline 1.117 0.048 310.9 2.493 4.743 121.4 stilbite 3.862 0.587 2721. 3.435 41.52 1269. stilpnomelane-Fe 0.3137 -0.504 338.1 2.529 5.158 116.8 tr.625ac.25prg.125 0.5082E-01 -1.294 43.44 1.638 0.6627 13.98 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8051E+00 0.8051E+00 1.0000 -0.094 grossular 0.1949E+00 0.1949E+00 1.0000 -0.710 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.7611E+00 0.7611E+00 1.0000 -0.119 daphnite 0.2203E+00 0.2203E+00 1.0000 -0.657 chlorite-Mn 0.1858E-01 0.1858E-01 1.0000 -1.731 diopside 0.7941E+00 0.7941E+00 1.0000 -0.100 hedenbergite 0.2059E+00 0.2059E+00 1.0000 -0.686 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 tr.625ac.25prg.125 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 6554.844506 g Volume = 2652.808498 cm3 Porosity: -10.4877% V(tot) - V(min): -.25181E+03 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 5999.9990000 g log = 3.7782 Original solution: 1000.0103000 g Original solution / Rock added: 0.17 (Water/Rock Ratio), log = -0.7781 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0817 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9441E+00 0.9851 0.1006E+01 0.1021E+01 CO2,gas 0.7891E-08 1.0066 0.8591E-08 0.8535E-08 CH4,gas 0.4190E-01 1.0121 0.4587E-01 0.4532E-01 H2,gas 0.1405E-01 1.0006 0.1521E-01 0.1520E-01 H2S,gas 0.3165E-06 0.9958 0.3409E-06 0.3424E-06 S2,gas 0.1744E-28 1.0000 0.1887E-28 0.1887E-28 CO,gas 0.3219E-13 1.0000 0.3482E-13 0.3482E-13 SO3,gas 0.1643E-47 1.0000 0.1777E-47 0.1777E-47 SO2,gas 0.9722E-27 1.0000 0.1052E-26 0.1052E-26 HCl,gas 0.6460E-17 1.0000 0.6988E-17 0.6988E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 16 albite -0.38 -0.38 0.00 0.000 -0.94784E-12 22 andradite 39.01 39.01 0.00 0.000 -0.12132E-10 23 grossular 32.73 32.73 0.00 0.000 -0.36397E-10 32 apatite-OH -18.15 -18.15 0.00 0.000 0.00000E+00 46 clinochlore 39.07 39.07 0.00 0.000 0.12132E-10 47 daphnite 28.97 28.97 0.00 0.000 0.18198E-10 48 chlorite-Mn 46.87 46.87 0.00 0.000 -0.24265E-10 67 diopside 16.18 16.18 0.00 0.000 0.60662E-11 68 hedenbergite 14.21 14.21 0.00 0.000 0.00000E+00 116 microcline -2.49 -2.49 0.00 0.000 0.15165E-11 163 stilbite -7.52 -7.52 0.00 0.000 -0.90992E-11 164 stilpnomelane-Fe 13.02 13.02 0.00 0.000 0.21232E-10 245 tr.625ac.25prg.125 45.16 45.16 0.00 0.000 0.24265E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -16.43 -9.76 -3.255 0.16673E+05 -8.066 3 CH4,gas 4.54 1.51 -3.04 -0.759 0.51864E+04 -1.339 4 H2,gas 8.00 4.48 -3.52 -2.010 0.60051E+04 -1.818 5 H2S,gas -6.23 -14.40 -8.17 -4.083 0.13944E+05 -6.467 6 S2,gas -7.34 -37.76 -30.42 -4.680 0.51947E+05 -28.724 7 CO,gas 3.21 -11.94 -15.16 -4.664 0.25880E+05 -13.458 8 SO3,gas 17.12 -32.33 -49.45 -12.362 0.84433E+05 -47.750 9 SO2,gas 0.83 -27.84 -28.68 -7.647 0.48965E+05 -26.978 10 HCl,gas 5.19 -13.67 -18.85 -9.427 0.32194E+05 -17.156 11 acmite 7.71 6.53 -1.18 -0.123 0.20175E+04 15 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 19 spessartine 24.46 19.73 -4.73 -0.236 0.80704E+04 20 analcite 3.32 2.77 -0.55 -0.061 0.93625E+03 26 annite 20.12 17.72 -2.40 -0.134 0.41064E+04 27 phlogopite 27.06 25.40 -1.67 -0.093 0.28489E+04 29 anorthite 12.71 8.26 -4.45 -0.342 0.75903E+04 35 aragonite 0.97 -3.32 -4.29 -1.430 0.73246E+04 36 brucite 12.57 9.29 -3.27 -0.655 0.55909E+04 37 calcite 0.81 -3.32 -4.13 -1.378 0.70604E+04 38 carnegieite-low 9.02 5.93 -3.09 -0.442 0.52801E+04 39 carnegieite-high 10.09 5.93 -4.16 -0.595 0.71071E+04 40 carpholite-Mg 8.58 4.46 -4.12 -0.275 0.70429E+04 41 carpholite-Fe 6.71 1.90 -4.81 -0.321 0.82207E+04 42 celadonite 5.34 3.65 -1.69 -0.099 0.28879E+04 43 celadonite-Fe 3.88 1.09 -2.79 -0.164 0.47561E+04 44 chrysotile 23.89 21.57 -2.32 -0.194 0.39692E+04 49 chlorite-Al-free 47.17 43.14 -4.04 -0.168 0.68936E+04 51 chloritoid-Fe 9.17 5.06 -4.12 -0.275 0.70316E+04 52 chloritoid-Mn 11.40 7.56 -3.84 -0.256 0.65547E+04 54 coesite -2.38 -3.16 -0.78 -0.260 0.13341E+04 61 cristobalite -2.56 -3.16 -0.60 -0.199 0.10195E+04 63 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71234E+04 65 diaspore 2.87 0.74 -2.13 -0.356 0.36450E+04 66 diamond -3.10 -7.46 -4.36 -1.245 0.74395E+04 71 enstatite 17.26 12.27 -4.99 -0.499 0.85226E+04 73 clinoenstatite 17.17 12.27 -4.89 -0.489 0.83541E+04 75 epidote 24.67 22.70 -1.97 -0.095 0.33585E+04 76 clinozoisite 22.81 18.95 -3.86 -0.175 0.65869E+04 77 epidote-Fe 29.84 26.46 -3.38 -0.176 0.57768E+04 78 fayalite 14.05 10.31 -3.73 -0.533 0.63743E+04 79 ferrosilite 11.15 7.16 -3.99 -0.399 0.68202E+04 83 gibbsite 4.08 0.74 -3.34 -0.477 0.57035E+04 84 glaucophane 22.97 20.80 -2.17 -0.059 0.37134E+04 85 glaucophane-Fe 17.28 13.12 -4.15 -0.112 0.70919E+04 86 graphite -3.55 -7.46 -3.91 -1.118 0.66818E+04 87 greenalite 16.14 13.89 -2.25 -0.187 0.38408E+04 90 hematite 12.57 8.99 -3.58 -0.434 0.61111E+04 91 heulandite -5.83 -7.52 -1.69 -0.077 0.28938E+04 95 jadeite 4.22 2.77 -1.44 -0.144 0.24617E+04 97 kalsilite 7.58 3.83 -3.76 -0.537 0.64126E+04 98 kaolinite -1.33 -4.84 -3.50 -0.319 0.59832E+04 101 laumontite 2.88 1.95 -0.93 -0.062 0.15935E+04 102 lawsonite 9.62 8.26 -1.35 -0.090 0.23070E+04 103 leucite 4.12 0.67 -3.45 -0.345 0.58873E+04 105 lizardite 23.24 21.57 -1.68 -0.140 0.28618E+04 107 magnetite 20.09 15.72 -4.37 -0.356 0.74536E+04 108 minnesotaite 10.39 7.58 -2.81 -0.165 0.48028E+04 112 manganosite 14.06 9.24 -4.82 -1.204 0.82239E+04 120 muscovite 2.58 -1.01 -3.59 -0.211 0.61315E+04 121 paragonite 4.24 1.09 -3.15 -0.185 0.53706E+04 122 nepheline 8.34 5.93 -2.41 -0.344 0.41125E+04 128 periclase-Fe 11.63 6.73 -4.89 -1.223 0.83523E+04 134 phlogopite-Na 29.65 27.50 -2.15 -0.119 0.36678E+04 136 prehnite 19.37 18.21 -1.16 -0.068 0.19849E+04 137 prehnite-Fe 22.50 21.96 -0.53 -0.032 0.91159E+03 138 pumpellyite-Fe 46.27 43.89 -2.38 -0.053 0.40582E+04 139 pumpellyite-Mg 48.99 46.45 -2.54 -0.057 0.43420E+04 143 pyrrhotite -4.26 -7.66 -3.40 -1.134 0.58075E+04 144 pyrrhotiteFe0.875 -6.02 -9.06 -3.04 -1.119 0.51947E+04 145 pyroxmangite 7.40 6.08 -1.31 -0.263 0.22443E+04 146 pyrophyllite -6.18 -11.15 -4.98 -0.311 0.84962E+04 147 quartz -2.99 -3.16 -0.17 -0.056 0.28680E+03 152 rhodonite 7.45 6.08 -1.36 -0.272 0.23245E+04 153 sanidine -1.28 -2.49 -1.21 -0.093 0.20677E+04 165 stilpnomelane-Mg 27.44 25.81 -1.63 -0.049 0.27804E+04 171 talc 16.49 15.25 -1.24 -0.073 0.21140E+04 174 tephroite 18.09 15.33 -2.76 -0.394 0.47123E+04 178 tridymite -2.63 -3.16 -0.53 -0.177 0.90678E+03 179 tremolite 47.87 47.42 -0.45 -0.012 0.77494E+03 180 ferroactinolite 38.45 34.62 -3.83 -0.104 0.65448E+04 181 troilite-low -4.41 -7.66 -3.25 -1.084 0.55503E+04 183 vesuvianite 223.47 218.82 -4.65 -0.036 0.79439E+04 187 wairakite 3.95 1.95 -2.00 -0.118 0.34155E+04 188 walstromite 11.51 9.94 -1.56 -0.313 0.26719E+04 189 wollastonite 10.46 9.94 -0.52 -0.103 0.88229E+03 190 pseudo-wollastonite 11.00 9.94 -1.06 -0.211 0.18021E+04 191 zoisite 22.85 18.95 -3.90 -0.177 0.66609E+04 192 akaganeite 7.75 4.49 -3.26 -0.705 0.55681E+04 199 chalcedony -2.80 -3.16 -0.35 -0.118 0.60610E+03 201 montmorillonite-Ca -2.29 -6.17 -3.88 -0.240 0.66180E+04 202 montmorillonite-K -2.24 -6.27 -4.03 -0.247 0.68816E+04 203 montmorillonite-Mg -2.48 -6.79 -4.32 -0.267 0.73678E+04 204 montmorillonite-Na -2.04 -5.57 -3.54 -0.216 0.60365E+04 205 nontronite-Ca 3.21 -0.19 -3.41 -0.221 0.58215E+04 206 nontronite-H 2.53 -2.36 -4.89 -0.328 0.83485E+04 207 nontronite-K 3.34 -0.30 -3.64 -0.233 0.62083E+04 208 nontronite-Mg 3.07 -0.82 -3.90 -0.253 0.66553E+04 209 nontronite-Na 3.52 0.40 -3.12 -0.200 0.53292E+04 224 tobermorite 9.82 7.76 -2.07 -0.564 0.35287E+04 230 alabandite -0.98 -5.15 -4.18 -1.392 0.71321E+04 233 boehmite 4.41 0.74 -3.67 -0.611 0.62619E+04 235 ferrous-oxide 9.81 6.73 -3.08 -0.769 0.52532E+04 240 silica-amorphous -2.09 -3.16 -1.07 -0.355 0.18203E+04 242 an20ab80 2.02 1.35 -0.67 -0.052 0.11472E+04 243 an25ab75 2.65 1.78 -0.87 -0.067 0.14810E+04 244 an30ab70 3.28 2.21 -1.07 -0.082 0.18244E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 100.0000000 g Current total amount of reactant added: 5999.9990000 g New total amount of reactant added: 6099.9990000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.5222E-10 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 12 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 6099.9990000 Water: Moles liquid = 0.2142E+02 kg liquid = 0.3859E+00 Moles total = -.2096E+02 kg total = -.3776E+00 Activity = 1.0000 Stoichiometric ionic strength = .1149956E-01 Osmotic coef. = 0.9683 True ionic strength = .2014995E-01 Chg. balance for total moles = 0.5222E-10 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.88868E-10 -10.0513 0.74641E-10 -10.1270 0.83991E+00 -0.0758 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.35593E-03 -3.4486 0.29714E-03 -3.5270 0.83483E+00 -0.0784 4 SO4-- 0.16704E-11 -11.7772 0.86599E-12 -12.0625 0.51842E+00 -0.2853 5 HCO3- 0.61788E-06 -6.2091 0.51658E-06 -6.2869 0.83606E+00 -0.0778 6 HS- 0.66084E-04 -4.1799 0.55177E-04 -4.2582 0.83495E+00 -0.0783 7 Al+++ 0.99066E-29 -29.0041 0.22798E-29 -29.6421 0.23013E+00 -0.6380 8 H4SiO4 0.69598E-03 -3.1574 0.69598E-03 -3.1574 0.10000E+01 0.0000 9 Ca++ 0.13687E-06 -6.8637 0.70434E-07 -7.1522 0.51459E+00 -0.2885 10 Mg++ 0.21413E-10 -10.6693 0.10968E-10 -10.9599 0.51223E+00 -0.2905 11 Fe++ 0.59018E-13 -13.2290 0.30264E-13 -13.5191 0.51279E+00 -0.2901 12 K+ 0.15754E-03 -3.8026 0.13174E-03 -3.8803 0.83626E+00 -0.0777 13 Na+ 0.19991E-01 -1.6992 0.16686E-01 -1.7777 0.83468E+00 -0.0785 14 Mn++ 0.18939E-10 -10.7226 0.97199E-11 -11.0123 0.51322E+00 -0.2897 15 HPO4-- 0.44850E-07 -7.3482 0.23254E-07 -7.6335 0.51849E+00 -0.2853 16 HSiO3- 0.10429E-01 -1.9818 0.87066E-02 -2.0602 0.83483E+00 -0.0784 17 Ca(HSiO3)+ 0.16697E-07 -7.7774 0.13966E-07 -7.8549 0.83644E+00 -0.0776 18 Mg(HSiO3)+ 0.32359E-11 -11.4900 0.27066E-11 -11.5676 0.83644E+00 -0.0776 19 NaHSiO3,aq 0.23496E-02 -2.6290 0.23496E-02 -2.6290 0.10000E+01 0.0000 20 AlO+ 0.66556E-16 -16.1768 0.55670E-16 -16.2544 0.83644E+00 -0.0776 22 HAlO2,aq 0.14853E-09 -9.8282 0.14853E-09 -9.8282 0.10000E+01 0.0000 23 AlO2- 0.52860E-05 -5.2769 0.44049E-05 -5.3561 0.83332E+00 -0.0792 24 CH4,aq 0.32085E-04 -4.4937 0.31972E-04 -4.4952 0.99649E+00 -0.0015 25 C2H6,aq 0.15141E-13 -13.8198 0.15088E-13 -13.8214 0.99649E+00 -0.0015 29 CO,aq 0.23972E-16 -16.6203 0.23972E-16 -16.6203 0.10000E+01 0.0000 30 CO2,aq 0.82679E-10 -10.0826 0.82390E-10 -10.0841 0.99649E+00 -0.0015 31 CO3-2 0.11686E-05 -5.9323 0.60451E-06 -6.2186 0.51731E+00 -0.2862 32 CaCO3,aq 0.53388E-09 -9.2726 0.53388E-09 -9.2726 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.11104E-11 -11.9545 0.92876E-12 -12.0321 0.83644E+00 -0.0776 34 CaCl+ 0.40492E-10 -10.3926 0.33869E-10 -10.4702 0.83644E+00 -0.0776 35 CaCl2,aq 0.23909E-14 -14.6214 0.23909E-14 -14.6214 0.10000E+01 0.0000 36 CaOH+ 0.80403E-07 -7.0947 0.67252E-07 -7.1723 0.83644E+00 -0.0776 37 CaSO4,aq 0.19369E-16 -16.7129 0.19369E-16 -16.7129 0.10000E+01 0.0000 38 HCl,aq 0.40641E-14 -14.3910 0.40641E-14 -14.3910 0.10000E+01 0.0000 43 FeCl+ 0.17017E-16 -16.7691 0.14234E-16 -16.8467 0.83644E+00 -0.0776 46 FeO,aq 0.21113E-09 -9.6755 0.21113E-09 -9.6755 0.10000E+01 0.0000 47 FeOH+ 0.15779E-10 -10.8019 0.13198E-10 -10.8795 0.83644E+00 -0.0776 48 HFeO2- 0.35451E-07 -7.4504 0.29595E-07 -7.5288 0.83483E+00 -0.0784 49 FeO+ 0.11059E-16 -16.9563 0.92500E-17 -17.0339 0.83644E+00 -0.0776 51 FeO2- 0.40695E-09 -9.3905 0.33973E-09 -9.4689 0.83483E+00 -0.0784 52 HFeO2,aq 0.32251E-11 -11.4915 0.32251E-11 -11.4915 0.10000E+01 0.0000 53 H2,aq 0.11623E-04 -4.9347 0.11582E-04 -4.9362 0.99649E+00 -0.0015 54 KCl,aq 0.70947E-09 -9.1491 0.70947E-09 -9.1491 0.10000E+01 0.0000 56 KOH,aq 0.75375E-06 -6.1228 0.75375E-06 -6.1228 0.10000E+01 0.0000 57 KSO4- 0.21206E-14 -14.6735 0.17703E-14 -14.7519 0.83483E+00 -0.0784 58 MgCO3,aq 0.20840E-13 -13.6811 0.20840E-13 -13.6811 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.17669E-15 -15.7528 0.14779E-15 -15.8304 0.83644E+00 -0.0776 60 MgCl+ 0.57151E-14 -14.2430 0.47803E-14 -14.3205 0.83644E+00 -0.0776 61 MgOH+ 0.69285E-10 -10.1594 0.57952E-10 -10.2369 0.83644E+00 -0.0776 63 MnO,aq 0.18068E-08 -8.7431 0.18068E-08 -8.7431 0.10000E+01 0.0000 64 MnOH+ 0.47078E-09 -9.3272 0.39378E-09 -9.4048 0.83644E+00 -0.0776 65 MnO2-2 0.20805E-10 -10.6818 0.10763E-10 -10.9681 0.51731E+00 -0.2862 66 HMnO2- 0.21082E-09 -9.6761 0.17600E-09 -9.7545 0.83483E+00 -0.0784 69 MnCl+ 0.21263E-13 -13.6724 0.17785E-13 -13.7499 0.83644E+00 -0.0776 71 NaCl,aq 0.16431E-05 -5.7843 0.16431E-05 -5.7843 0.10000E+01 0.0000 72 NaOH,aq 0.96047E-04 -4.0175 0.96047E-04 -4.0175 0.10000E+01 0.0000 74 OH- 0.92890E-02 -2.0320 0.77407E-02 -2.1112 0.83332E+00 -0.0792 79 HPO3-2 0.16225E-14 -14.7898 0.83936E-15 -15.0760 0.51731E+00 -0.2862 81 H2PO3- 0.15049E-18 -18.8225 0.12563E-18 -18.9009 0.83483E+00 -0.0784 82 H3PO4,aq 0.90611E-18 -18.0428 0.90611E-18 -18.0428 0.10000E+01 0.0000 83 H2PO4- 0.38318E-10 -10.4166 0.32020E-10 -10.4946 0.83563E+00 -0.0780 84 PO4-3 0.10514E-08 -8.9782 0.25419E-09 -9.5948 0.24176E+00 -0.6166 88 HP2O7-3 0.93357E-18 -18.0299 0.21506E-18 -18.6674 0.23036E+00 -0.6376 89 P2O7-4 0.89877E-17 -17.0464 0.68831E-18 -18.1622 0.76584E-01 -1.1159 90 H2S,aq 0.12773E-07 -7.8937 0.12729E-07 -7.8952 0.99649E+00 -0.0015 91 S2-2 0.11259E-13 -13.9485 0.58244E-14 -14.2348 0.51731E+00 -0.2862 97 SO3-2 0.24835E-17 -17.6049 0.13034E-17 -17.8849 0.52483E+00 -0.2800 99 HSO4- 0.74401E-19 -19.1284 0.62293E-19 -19.2056 0.83726E+00 -0.0771 Charge balance for all species = 0.1354E-09 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.8886792E-10 -.2219008E-01 -.2232726E+02 0.0000 2 H2O 0.1000000E+01 0.5550491E+02 0.9981935E+06 0.0000 3 Cl- 0.3559262E-03 0.3575700E-03 0.1265482E+02 6.6000 4 SO4-- 0.1670443E-11 -.3499053E-04 -.3355384E+01 8.1916 5 HCO3- 0.6178778E-06 0.3387185E-04 0.2063160E+01 3.8402 6 HS- 0.6608390E-04 0.1010872E-03 0.3337325E+01 5.8688 7 Al+++ 0.9906636E-29 0.5286160E-05 0.1423797E+00 0.7390 8 H4SiO4 0.6959818E-03 0.1347481E-01 0.1292878E+04 -3.1574 9 Ca++ 0.1368723E-06 0.2345476E-06 0.9383803E-02 13.1018 10 Mg++ 0.2141319E-10 0.9395860E-10 0.2280337E-05 9.2942 11 Fe++ 0.5901842E-13 0.3608794E-07 0.2011888E-02 6.7350 12 K+ 0.1575358E-03 0.1582903E-03 0.6178669E+01 6.2467 13 Na+ 0.1999069E-01 0.2243803E-01 0.5149460E+03 8.3494 14 Mn++ 0.1893909E-10 0.2528124E-08 0.1386478E-03 9.2417 15 HPO4-- 0.4485007E-07 0.4593980E-07 0.4401565E-02 12.6206 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.1010069E+03 -.8562402E-02 -.1009984E+03 0.0000000E+00 2 H2O -.2095774E+02 0.2141747E+02 -.4237521E+02 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.1690773E+00 -.1350166E-04 0.1690908E+00 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.1690518E+00 0.3900613E-04 -.1690908E+00 0.0000000E+00 7 Al+++ 0.1989052E+02 0.2039750E-05 0.1989052E+02 0.0000000E+00 8 H4SiO4 0.6351797E+02 0.5199475E-02 0.6351277E+02 0.0000000E+00 9 Ca++ 0.7015884E+01 0.9050399E-07 0.7015883E+01 0.0000000E+00 10 Mg++ 0.4841269E+01 0.3625544E-10 0.4841269E+01 0.0000000E+00 11 Fe++ 0.4349352E+01 0.1392511E-07 0.4349352E+01 0.0000000E+00 12 K+ 0.1295117E+01 0.6107885E-04 0.1295055E+01 0.0000000E+00 13 Na+ 0.7657145E+01 0.8658076E-02 0.7648487E+01 0.0000000E+00 14 Mn++ 0.1057654E+00 0.9755175E-09 0.1057654E+00 0.0000000E+00 15 HPO4-- 0.3609721E-01 0.1772661E-07 0.3609719E-01 0.0000000E+00 Chg. balance for solid moles: 0.1475E-13 Mass of aqueous solution: 0.386540E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 6099.9990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 7.642 0.883 2004. 3.302 30.07 769.2 andradite 0.6764 -0.170 343.7 2.536 5.158 89.30 grossular 0.1638 -0.786 73.77 1.868 1.107 20.53 apatite-OH 0.1203E-01 -1.920 6.044 0.781 0.9070E-01 1.921 clinochlore 0.8663 -0.062 481.5 2.683 7.226 183.2 daphnite 0.2508 -0.601 178.9 2.253 2.685 54.22 chlorite-Mn 0.2115E-01 -1.675 15.00 1.176 0.2250 4.779 diopside 0.3225 -0.491 69.85 1.844 1.048 21.35 hedenbergite 0.8364E-01 -1.078 20.75 1.317 0.3114 5.684 microcline 1.136 0.055 316.1 2.500 4.743 123.5 stilbite 3.926 0.594 2767. 3.442 41.52 1290. stilpnomelane-Fe 0.3189 -0.496 343.8 2.536 5.158 118.7 tr.625ac.25prg.125 0.5165E-01 -1.287 44.15 1.645 0.6625 14.21 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8051E+00 0.8051E+00 1.0000 -0.094 grossular 0.1949E+00 0.1949E+00 1.0000 -0.710 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.7611E+00 0.7611E+00 1.0000 -0.119 daphnite 0.2203E+00 0.2203E+00 1.0000 -0.657 chlorite-Mn 0.1858E-01 0.1858E-01 1.0000 -1.731 diopside 0.7941E+00 0.7941E+00 1.0000 -0.100 hedenbergite 0.2059E+00 0.2059E+00 1.0000 -0.686 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 tr.625ac.25prg.125 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 6664.095170 g Volume = 2697.011562 cm3 Porosity: -10.4880% V(tot) - V(min): -.25601E+03 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 6099.9990000 g log = 3.7853 Original solution: 1000.0103000 g Original solution / Rock added: 0.16 (Water/Rock Ratio), log = -0.7853 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0829 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9430E+00 0.9851 0.1006E+01 0.1021E+01 CO2,gas 0.8087E-08 1.0065 0.8815E-08 0.8757E-08 CH4,gas 0.4294E-01 1.0121 0.4706E-01 0.4650E-01 H2,gas 0.1403E-01 1.0006 0.1521E-01 0.1520E-01 H2S,gas 0.3245E-06 0.9958 0.3499E-06 0.3514E-06 S2,gas 0.1835E-28 1.0000 0.1987E-28 0.1987E-28 CO,gas 0.3299E-13 1.0000 0.3572E-13 0.3572E-13 SO3,gas 0.1685E-47 1.0000 0.1824E-47 0.1824E-47 SO2,gas 0.9966E-27 1.0000 0.1079E-26 0.1079E-26 HCl,gas 0.6623E-17 1.0000 0.7171E-17 0.7171E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 16 albite -0.38 -0.38 0.00 0.000 -0.13080E-10 22 andradite 39.01 39.01 0.00 0.000 -0.12132E-10 23 grossular 32.73 32.73 0.00 0.000 0.12132E-10 32 apatite-OH -18.15 -18.15 0.00 0.000 -0.12132E-10 46 clinochlore 39.07 39.07 0.00 0.000 -0.24265E-10 47 daphnite 28.97 28.97 0.00 0.000 -0.54595E-10 48 chlorite-Mn 46.87 46.87 0.00 0.000 -0.36397E-10 67 diopside 16.18 16.18 0.00 0.000 -0.60662E-11 68 hedenbergite 14.21 14.21 0.00 0.000 -0.12132E-10 116 microcline -2.49 -2.49 0.00 0.000 -0.10616E-10 163 stilbite -7.52 -7.52 0.00 0.000 -0.33364E-10 164 stilpnomelane-Fe 13.02 13.02 0.00 0.000 0.21232E-10 245 tr.625ac.25prg.125 45.16 45.16 0.00 0.000 0.36397E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -16.41 -9.75 -3.251 0.16654E+05 -8.055 3 CH4,gas 4.54 1.52 -3.03 -0.757 0.51673E+04 -1.327 4 H2,gas 8.00 4.48 -3.52 -2.010 0.60051E+04 -1.818 5 H2S,gas -6.23 -14.39 -8.16 -4.078 0.13924E+05 -6.456 6 S2,gas -7.34 -37.74 -30.40 -4.677 0.51908E+05 -28.702 7 CO,gas 3.21 -11.93 -15.15 -4.660 0.25861E+05 -13.447 8 SO3,gas 17.12 -32.32 -49.44 -12.359 0.84414E+05 -47.739 9 SO2,gas 0.83 -27.83 -28.67 -7.644 0.48946E+05 -26.967 10 HCl,gas 5.19 -13.65 -18.84 -9.422 0.32175E+05 -17.144 11 acmite 7.71 6.53 -1.18 -0.123 0.20175E+04 15 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 19 spessartine 24.46 19.73 -4.73 -0.236 0.80703E+04 20 analcite 3.32 2.77 -0.55 -0.061 0.93625E+03 26 annite 20.12 17.72 -2.40 -0.134 0.41064E+04 27 phlogopite 27.06 25.40 -1.67 -0.093 0.28489E+04 29 anorthite 12.71 8.26 -4.45 -0.342 0.75903E+04 35 aragonite 0.97 -3.31 -4.28 -1.426 0.73056E+04 36 brucite 12.57 9.29 -3.27 -0.655 0.55909E+04 37 calcite 0.81 -3.31 -4.12 -1.375 0.70413E+04 38 carnegieite-low 9.02 5.93 -3.09 -0.442 0.52801E+04 39 carnegieite-high 10.09 5.93 -4.16 -0.595 0.71071E+04 40 carpholite-Mg 8.58 4.46 -4.12 -0.275 0.70429E+04 41 carpholite-Fe 6.71 1.90 -4.81 -0.321 0.82207E+04 42 celadonite 5.34 3.65 -1.69 -0.099 0.28879E+04 43 celadonite-Fe 3.88 1.09 -2.79 -0.164 0.47561E+04 44 chrysotile 23.89 21.57 -2.32 -0.194 0.39692E+04 49 chlorite-Al-free 47.17 43.14 -4.04 -0.168 0.68936E+04 51 chloritoid-Fe 9.17 5.06 -4.12 -0.275 0.70316E+04 52 chloritoid-Mn 11.40 7.56 -3.84 -0.256 0.65547E+04 54 coesite -2.38 -3.16 -0.78 -0.260 0.13341E+04 61 cristobalite -2.56 -3.16 -0.60 -0.199 0.10195E+04 63 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71234E+04 65 diaspore 2.87 0.74 -2.13 -0.356 0.36450E+04 66 diamond -3.10 -7.45 -4.35 -1.242 0.74204E+04 71 enstatite 17.26 12.27 -4.99 -0.499 0.85226E+04 73 clinoenstatite 17.17 12.27 -4.89 -0.489 0.83541E+04 75 epidote 24.67 22.70 -1.97 -0.095 0.33585E+04 76 clinozoisite 22.81 18.95 -3.86 -0.175 0.65869E+04 77 epidote-Fe 29.84 26.46 -3.38 -0.176 0.57768E+04 78 fayalite 14.05 10.31 -3.73 -0.533 0.63743E+04 79 ferrosilite 11.15 7.16 -3.99 -0.399 0.68202E+04 83 gibbsite 4.08 0.74 -3.34 -0.477 0.57035E+04 84 glaucophane 22.97 20.80 -2.17 -0.059 0.37134E+04 85 glaucophane-Fe 17.28 13.12 -4.15 -0.112 0.70919E+04 86 graphite -3.55 -7.45 -3.90 -1.115 0.66627E+04 87 greenalite 16.14 13.89 -2.25 -0.187 0.38408E+04 90 hematite 12.57 8.99 -3.58 -0.434 0.61111E+04 91 heulandite -5.83 -7.52 -1.69 -0.077 0.28938E+04 95 jadeite 4.22 2.77 -1.44 -0.144 0.24617E+04 97 kalsilite 7.58 3.83 -3.76 -0.537 0.64126E+04 98 kaolinite -1.33 -4.84 -3.50 -0.319 0.59832E+04 101 laumontite 2.88 1.95 -0.93 -0.062 0.15935E+04 102 lawsonite 9.62 8.26 -1.35 -0.090 0.23070E+04 103 leucite 4.12 0.67 -3.45 -0.345 0.58873E+04 105 lizardite 23.24 21.57 -1.68 -0.140 0.28618E+04 107 magnetite 20.09 15.72 -4.37 -0.356 0.74536E+04 108 minnesotaite 10.39 7.58 -2.81 -0.165 0.48028E+04 112 manganosite 14.06 9.24 -4.82 -1.204 0.82239E+04 120 muscovite 2.58 -1.01 -3.59 -0.211 0.61315E+04 121 paragonite 4.24 1.09 -3.15 -0.185 0.53706E+04 122 nepheline 8.34 5.93 -2.41 -0.344 0.41125E+04 128 periclase-Fe 11.63 6.73 -4.89 -1.223 0.83523E+04 134 phlogopite-Na 29.65 27.50 -2.15 -0.119 0.36678E+04 136 prehnite 19.37 18.21 -1.16 -0.068 0.19849E+04 137 prehnite-Fe 22.50 21.96 -0.53 -0.032 0.91159E+03 138 pumpellyite-Fe 46.27 43.89 -2.38 -0.053 0.40582E+04 139 pumpellyite-Mg 48.99 46.45 -2.54 -0.057 0.43420E+04 143 pyrrhotite -4.26 -7.65 -3.39 -1.130 0.57883E+04 144 pyrrhotiteFe0.875 -6.02 -9.05 -3.03 -1.115 0.51755E+04 145 pyroxmangite 7.40 6.08 -1.31 -0.263 0.22443E+04 146 pyrophyllite -6.18 -11.15 -4.98 -0.311 0.84962E+04 147 quartz -2.99 -3.16 -0.17 -0.056 0.28680E+03 152 rhodonite 7.45 6.08 -1.36 -0.272 0.23245E+04 153 sanidine -1.28 -2.49 -1.21 -0.093 0.20677E+04 165 stilpnomelane-Mg 27.44 25.81 -1.63 -0.049 0.27804E+04 171 talc 16.49 15.25 -1.24 -0.073 0.21140E+04 174 tephroite 18.09 15.33 -2.76 -0.394 0.47122E+04 178 tridymite -2.63 -3.16 -0.53 -0.177 0.90678E+03 179 tremolite 47.87 47.42 -0.45 -0.012 0.77494E+03 180 ferroactinolite 38.45 34.62 -3.83 -0.104 0.65448E+04 181 troilite-low -4.41 -7.65 -3.24 -1.080 0.55311E+04 183 vesuvianite 223.47 218.82 -4.65 -0.036 0.79440E+04 187 wairakite 3.95 1.95 -2.00 -0.118 0.34155E+04 188 walstromite 11.51 9.94 -1.56 -0.313 0.26719E+04 189 wollastonite 10.46 9.94 -0.52 -0.103 0.88229E+03 190 pseudo-wollastonite 11.00 9.94 -1.06 -0.211 0.18021E+04 191 zoisite 22.85 18.95 -3.90 -0.177 0.66609E+04 192 akaganeite 7.75 4.49 -3.26 -0.705 0.55681E+04 199 chalcedony -2.80 -3.16 -0.35 -0.118 0.60610E+03 201 montmorillonite-Ca -2.29 -6.17 -3.88 -0.240 0.66180E+04 202 montmorillonite-K -2.24 -6.27 -4.03 -0.247 0.68816E+04 203 montmorillonite-Mg -2.48 -6.79 -4.32 -0.267 0.73678E+04 204 montmorillonite-Na -2.04 -5.57 -3.54 -0.216 0.60365E+04 205 nontronite-Ca 3.21 -0.19 -3.41 -0.221 0.58215E+04 206 nontronite-H 2.53 -2.36 -4.89 -0.328 0.83485E+04 207 nontronite-K 3.34 -0.30 -3.64 -0.233 0.62083E+04 208 nontronite-Mg 3.07 -0.82 -3.90 -0.253 0.66553E+04 209 nontronite-Na 3.52 0.40 -3.12 -0.200 0.53292E+04 224 tobermorite 9.82 7.76 -2.07 -0.564 0.35287E+04 230 alabandite -0.98 -5.14 -4.17 -1.389 0.71128E+04 233 boehmite 4.41 0.74 -3.67 -0.611 0.62619E+04 235 ferrous-oxide 9.81 6.73 -3.08 -0.769 0.52532E+04 240 silica-amorphous -2.09 -3.16 -1.07 -0.355 0.18203E+04 242 an20ab80 2.02 1.35 -0.67 -0.052 0.11472E+04 243 an25ab75 2.65 1.78 -0.87 -0.067 0.14810E+04 244 an30ab70 3.28 2.21 -1.07 -0.082 0.18244E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 100.0000000 g Current total amount of reactant added: 6099.9990000 g New total amount of reactant added: 6199.9990000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.5221E-10 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 12 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 6199.9990000 Water: Moles liquid = 0.2086E+02 kg liquid = 0.3758E+00 Moles total = -.2221E+02 kg total = -.4001E+00 Activity = 1.0000 Stoichiometric ionic strength = .1150748E-01 Osmotic coef. = 0.9682 True ionic strength = .2015614E-01 Chg. balance for total moles = 0.5221E-10 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.88895E-10 -10.0511 0.74662E-10 -10.1269 0.83989E+00 -0.0758 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.36544E-03 -3.4372 0.30507E-03 -3.5156 0.83481E+00 -0.0784 4 SO4-- 0.17147E-11 -11.7658 0.88886E-12 -12.0512 0.51838E+00 -0.2854 5 HCO3- 0.63423E-06 -6.1977 0.53025E-06 -6.2755 0.83604E+00 -0.0778 6 HS- 0.67850E-04 -4.1685 0.56650E-04 -4.2468 0.83494E+00 -0.0783 7 Al+++ 0.99169E-29 -29.0036 0.22817E-29 -29.6417 0.23009E+00 -0.6381 8 H4SiO4 0.69598E-03 -3.1574 0.69598E-03 -3.1574 0.10000E+01 0.0000 9 Ca++ 0.13696E-06 -6.8634 0.70474E-07 -7.1520 0.51455E+00 -0.2886 10 Mg++ 0.21427E-10 -10.6690 0.10975E-10 -10.9596 0.51218E+00 -0.2906 11 Fe++ 0.59057E-13 -13.2287 0.30281E-13 -13.5188 0.51275E+00 -0.2901 12 K+ 0.15758E-03 -3.8025 0.13178E-03 -3.8802 0.83624E+00 -0.0777 13 Na+ 0.19997E-01 -1.6990 0.16691E-01 -1.7775 0.83466E+00 -0.0785 14 Mn++ 0.18952E-10 -10.7223 0.97257E-11 -11.0121 0.51318E+00 -0.2897 15 HPO4-- 0.44828E-07 -7.3484 0.23241E-07 -7.6337 0.51845E+00 -0.2853 16 HSiO3- 0.10426E-01 -1.9819 0.87041E-02 -2.0603 0.83481E+00 -0.0784 17 Ca(HSiO3)+ 0.16702E-07 -7.7772 0.13970E-07 -7.8548 0.83642E+00 -0.0776 18 Mg(HSiO3)+ 0.32369E-11 -11.4899 0.27074E-11 -11.5674 0.83642E+00 -0.0776 19 NaHSiO3,aq 0.23496E-02 -2.6290 0.23496E-02 -2.6290 0.10000E+01 0.0000 20 AlO+ 0.66576E-16 -16.1767 0.55685E-16 -16.2543 0.83642E+00 -0.0776 22 HAlO2,aq 0.14853E-09 -9.8282 0.14853E-09 -9.8282 0.10000E+01 0.0000 23 AlO2- 0.52846E-05 -5.2770 0.44037E-05 -5.3562 0.83330E+00 -0.0792 24 CH4,aq 0.32943E-04 -4.4822 0.32827E-04 -4.4838 0.99649E+00 -0.0015 25 C2H6,aq 0.15962E-13 -13.7969 0.15906E-13 -13.7984 0.99649E+00 -0.0015 29 CO,aq 0.24613E-16 -16.6088 0.24613E-16 -16.6088 0.10000E+01 0.0000 30 CO2,aq 0.84891E-10 -10.0711 0.84593E-10 -10.0727 0.99649E+00 -0.0015 31 CO3-2 0.11992E-05 -5.9211 0.62033E-06 -6.2074 0.51727E+00 -0.2863 32 CaCO3,aq 0.54816E-09 -9.2611 0.54816E-09 -9.2611 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.11404E-11 -11.9429 0.95387E-12 -12.0205 0.83642E+00 -0.0776 34 CaCl+ 0.41597E-10 -10.3809 0.34793E-10 -10.4585 0.83642E+00 -0.0776 35 CaCl2,aq 0.25217E-14 -14.5983 0.25217E-14 -14.5983 0.10000E+01 0.0000 36 CaOH+ 0.80428E-07 -7.0946 0.67271E-07 -7.1722 0.83642E+00 -0.0776 37 CaSO4,aq 0.19892E-16 -16.7013 0.19892E-16 -16.7013 0.10000E+01 0.0000 38 HCl,aq 0.41738E-14 -14.3795 0.41738E-14 -14.3795 0.10000E+01 0.0000 43 FeCl+ 0.17482E-16 -16.7574 0.14622E-16 -16.8350 0.83642E+00 -0.0776 46 FeO,aq 0.21113E-09 -9.6755 0.21113E-09 -9.6755 0.10000E+01 0.0000 47 FeOH+ 0.15784E-10 -10.8018 0.13202E-10 -10.8794 0.83642E+00 -0.0776 48 HFeO2- 0.35441E-07 -7.4505 0.29587E-07 -7.5289 0.83481E+00 -0.0784 49 FeO+ 0.11062E-16 -16.9562 0.92526E-17 -17.0337 0.83642E+00 -0.0776 51 FeO2- 0.40684E-09 -9.3906 0.33964E-09 -9.4690 0.83481E+00 -0.0784 52 HFeO2,aq 0.32251E-11 -11.4915 0.32251E-11 -11.4915 0.10000E+01 0.0000 53 H2,aq 0.11623E-04 -4.9347 0.11582E-04 -4.9362 0.99649E+00 -0.0015 54 KCl,aq 0.72862E-09 -9.1375 0.72862E-09 -9.1375 0.10000E+01 0.0000 56 KOH,aq 0.75375E-06 -6.1228 0.75375E-06 -6.1228 0.10000E+01 0.0000 57 KSO4- 0.21773E-14 -14.6621 0.18176E-14 -14.7405 0.83481E+00 -0.0784 58 MgCO3,aq 0.21397E-13 -13.6696 0.21397E-13 -13.6696 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.18147E-15 -15.7412 0.15178E-15 -15.8188 0.83642E+00 -0.0776 60 MgCl+ 0.58712E-14 -14.2313 0.49108E-14 -14.3089 0.83642E+00 -0.0776 61 MgOH+ 0.69306E-10 -10.1592 0.57969E-10 -10.2368 0.83642E+00 -0.0776 63 MnO,aq 0.18068E-08 -8.7431 0.18068E-08 -8.7431 0.10000E+01 0.0000 64 MnOH+ 0.47093E-09 -9.3270 0.39390E-09 -9.4046 0.83642E+00 -0.0776 65 MnO2-2 0.20795E-10 -10.6820 0.10757E-10 -10.9683 0.51727E+00 -0.2863 66 HMnO2- 0.21077E-09 -9.6762 0.17595E-09 -9.7546 0.83481E+00 -0.0784 69 MnCl+ 0.21844E-13 -13.6607 0.18271E-13 -13.7382 0.83642E+00 -0.0776 71 NaCl,aq 0.16874E-05 -5.7728 0.16874E-05 -5.7728 0.10000E+01 0.0000 72 NaOH,aq 0.96047E-04 -4.0175 0.96047E-04 -4.0175 0.10000E+01 0.0000 74 OH- 0.92866E-02 -2.0321 0.77385E-02 -2.1113 0.83330E+00 -0.0792 79 HPO3-2 0.16218E-14 -14.7900 0.83889E-15 -15.0763 0.51727E+00 -0.2863 81 H2PO3- 0.15045E-18 -18.8226 0.12560E-18 -18.9010 0.83481E+00 -0.0784 82 H3PO4,aq 0.90611E-18 -18.0428 0.90611E-18 -18.0428 0.10000E+01 0.0000 83 H2PO4- 0.38308E-10 -10.4167 0.32010E-10 -10.4947 0.83561E+00 -0.0780 84 PO4-3 0.10507E-08 -8.9785 0.25398E-09 -9.5952 0.24172E+00 -0.6167 88 HP2O7-3 0.93294E-18 -18.0301 0.21487E-18 -18.6678 0.23032E+00 -0.6377 89 P2O7-4 0.89803E-17 -17.0467 0.68753E-18 -18.1627 0.76559E-01 -1.1160 90 H2S,aq 0.13118E-07 -7.8821 0.13072E-07 -7.8837 0.99649E+00 -0.0015 91 S2-2 0.11869E-13 -13.9256 0.61395E-14 -14.2119 0.51727E+00 -0.2863 97 SO3-2 0.25493E-17 -17.5936 0.13379E-17 -17.8736 0.52479E+00 -0.2800 99 HSO4- 0.76389E-19 -19.1170 0.63956E-19 -19.1941 0.83724E+00 -0.0772 Charge balance for all species = 0.1389E-09 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.8889493E-10 -.2218491E-01 -.2232205E+02 0.0000 2 H2O 0.1000000E+01 0.5550491E+02 0.9981932E+06 0.0000 3 Cl- 0.3654367E-03 0.3671249E-03 0.1299297E+02 6.6113 4 SO4-- 0.1714699E-11 -.3584861E-04 -.3437667E+01 8.2026 5 HCO3- 0.6342347E-06 0.3477696E-04 0.2118291E+01 3.8514 6 HS- 0.6784977E-04 0.1037115E-03 0.3423963E+01 5.8801 7 Al+++ 0.9916916E-29 0.5284762E-05 0.1423421E+00 0.7390 8 H4SiO4 0.6959820E-03 0.1347206E-01 0.1292614E+04 -3.1574 9 Ca++ 0.1369615E-06 0.2346818E-06 0.9389168E-02 13.1018 10 Mg++ 0.2142716E-10 0.9399497E-10 0.2281219E-05 9.2942 11 Fe++ 0.5905692E-13 0.3607847E-07 0.2011359E-02 6.7350 12 K+ 0.1575838E-03 0.1583383E-03 0.6180543E+01 6.2467 13 Na+ 0.1999680E-01 0.2244418E-01 0.5150870E+03 8.3494 14 Mn++ 0.1895189E-10 0.2528274E-08 0.1386560E-03 9.2417 15 HPO4-- 0.4482815E-07 0.4591716E-07 0.4399395E-02 12.6201 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.1026628E+03 -.8337611E-02 -.1026544E+03 0.0000000E+00 2 H2O -.2221128E+02 0.2086005E+02 -.4307133E+02 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.1718486E+00 -.1347275E-04 0.1718621E+00 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.1718231E+00 0.3897722E-04 -.1718621E+00 0.0000000E+00 7 Al+++ 0.2021659E+02 0.1986138E-05 0.2021659E+02 0.0000000E+00 8 H4SiO4 0.6455924E+02 0.5063119E-02 0.6455418E+02 0.0000000E+00 9 Ca++ 0.7130898E+01 0.8819893E-07 0.7130898E+01 0.0000000E+00 10 Mg++ 0.4920634E+01 0.3532552E-10 0.4920634E+01 0.0000000E+00 11 Fe++ 0.4420653E+01 0.1355914E-07 0.4420653E+01 0.0000000E+00 12 K+ 0.1316348E+01 0.5950726E-04 0.1316288E+01 0.0000000E+00 13 Na+ 0.7782669E+01 0.8435050E-02 0.7774234E+01 0.0000000E+00 14 Mn++ 0.1074993E+00 0.9501848E-09 0.1074993E+00 0.0000000E+00 15 HPO4-- 0.3668897E-01 0.1725675E-07 0.3668895E-01 0.0000000E+00 Chg. balance for solid moles: 0.2900E-14 Mass of aqueous solution: 0.376480E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 6199.9990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 7.768 0.890 2037. 3.309 30.07 781.9 andradite 0.6874 -0.163 349.3 2.543 5.158 90.76 grossular 0.1665 -0.779 74.98 1.875 1.107 20.86 apatite-OH 0.1223E-01 -1.913 6.143 0.788 0.9070E-01 1.952 clinochlore 0.8805 -0.055 489.4 2.690 7.225 186.2 daphnite 0.2549 -0.594 181.9 2.260 2.685 55.11 chlorite-Mn 0.2150E-01 -1.668 15.24 1.183 0.2250 4.857 diopside 0.3280 -0.484 71.02 1.851 1.049 21.71 hedenbergite 0.8505E-01 -1.070 21.10 1.324 0.3115 5.780 microcline 1.154 0.062 321.3 2.507 4.743 125.5 stilbite 3.990 0.601 2812. 3.449 41.51 1312. stilpnomelane-Fe 0.3241 -0.489 349.4 2.543 5.158 120.7 tr.625ac.25prg.125 0.5249E-01 -1.280 44.86 1.652 0.6624 14.44 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8051E+00 0.8051E+00 1.0000 -0.094 grossular 0.1949E+00 0.1949E+00 1.0000 -0.710 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.7611E+00 0.7611E+00 1.0000 -0.119 daphnite 0.2203E+00 0.2203E+00 1.0000 -0.657 chlorite-Mn 0.1858E-01 0.1858E-01 1.0000 -1.731 diopside 0.7941E+00 0.7941E+00 1.0000 -0.100 hedenbergite 0.2059E+00 0.2059E+00 1.0000 -0.686 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 tr.625ac.25prg.125 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 6773.345834 g Volume = 2741.214625 cm3 Porosity: -10.4883% V(tot) - V(min): -.26022E+03 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 6199.9990000 g log = 3.7924 Original solution: 1000.0103000 g Original solution / Rock added: 0.16 (Water/Rock Ratio), log = -0.7924 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0841 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9419E+00 0.9851 0.1006E+01 0.1021E+01 CO2,gas 0.8294E-08 1.0065 0.9051E-08 0.8992E-08 CH4,gas 0.4404E-01 1.0121 0.4832E-01 0.4774E-01 H2,gas 0.1402E-01 1.0006 0.1521E-01 0.1520E-01 H2S,gas 0.3329E-06 0.9958 0.3593E-06 0.3609E-06 S2,gas 0.1934E-28 1.0000 0.2096E-28 0.2096E-28 CO,gas 0.3383E-13 1.0000 0.3668E-13 0.3668E-13 SO3,gas 0.1728E-47 1.0000 0.1873E-47 0.1873E-47 SO2,gas 0.1022E-26 1.0000 0.1108E-26 0.1108E-26 HCl,gas 0.6793E-17 1.0000 0.7365E-17 0.7365E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 16 albite -0.38 -0.38 0.00 0.000 -0.94784E-12 22 andradite 39.01 39.01 0.00 0.000 0.12132E-10 23 grossular 32.73 32.73 0.00 0.000 0.00000E+00 32 apatite-OH -18.15 -18.15 0.00 0.000 -0.60662E-11 46 clinochlore 39.07 39.07 0.00 0.000 0.12132E-10 47 daphnite 28.97 28.97 0.00 0.000 -0.36397E-10 48 chlorite-Mn 46.87 46.87 0.00 0.000 -0.24265E-10 67 diopside 16.18 16.18 0.00 0.000 -0.60662E-11 68 hedenbergite 14.21 14.21 0.00 0.000 -0.60662E-11 116 microcline -2.49 -2.49 0.00 0.000 0.15165E-11 163 stilbite -7.52 -7.52 0.00 0.000 -0.90992E-11 164 stilpnomelane-Fe 13.02 13.02 0.00 0.000 0.21232E-10 245 tr.625ac.25prg.125 45.16 45.16 0.00 0.000 0.12132E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -16.40 -9.74 -3.247 0.16635E+05 -8.043 3 CH4,gas 4.54 1.53 -3.01 -0.754 0.51478E+04 -1.316 4 H2,gas 8.00 4.48 -3.52 -2.010 0.60051E+04 -1.818 5 H2S,gas -6.23 -14.37 -8.14 -4.072 0.13905E+05 -6.444 6 S2,gas -7.34 -37.71 -30.38 -4.673 0.51869E+05 -28.679 7 CO,gas 3.21 -11.92 -15.13 -4.657 0.25842E+05 -13.436 8 SO3,gas 17.12 -32.30 -49.43 -12.357 0.84394E+05 -47.727 9 SO2,gas 0.83 -27.82 -28.65 -7.641 0.48926E+05 -26.955 10 HCl,gas 5.19 -13.64 -18.83 -9.416 0.32155E+05 -17.133 11 acmite 7.71 6.53 -1.18 -0.123 0.20175E+04 15 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 19 spessartine 24.46 19.73 -4.73 -0.236 0.80703E+04 20 analcite 3.32 2.77 -0.55 -0.061 0.93625E+03 26 annite 20.12 17.72 -2.40 -0.134 0.41064E+04 27 phlogopite 27.06 25.40 -1.67 -0.093 0.28489E+04 29 anorthite 12.71 8.26 -4.45 -0.342 0.75903E+04 35 aragonite 0.97 -3.30 -4.27 -1.422 0.72860E+04 36 brucite 12.57 9.29 -3.27 -0.655 0.55909E+04 37 calcite 0.81 -3.30 -4.11 -1.371 0.70218E+04 38 carnegieite-low 9.02 5.93 -3.09 -0.442 0.52801E+04 39 carnegieite-high 10.09 5.93 -4.16 -0.595 0.71071E+04 40 carpholite-Mg 8.58 4.46 -4.12 -0.275 0.70429E+04 41 carpholite-Fe 6.71 1.90 -4.81 -0.321 0.82207E+04 42 celadonite 5.34 3.65 -1.69 -0.099 0.28879E+04 43 celadonite-Fe 3.88 1.09 -2.79 -0.164 0.47561E+04 44 chrysotile 23.89 21.57 -2.32 -0.194 0.39692E+04 49 chlorite-Al-free 47.17 43.14 -4.04 -0.168 0.68936E+04 51 chloritoid-Fe 9.17 5.06 -4.12 -0.275 0.70316E+04 52 chloritoid-Mn 11.40 7.56 -3.84 -0.256 0.65547E+04 54 coesite -2.38 -3.16 -0.78 -0.260 0.13341E+04 61 cristobalite -2.56 -3.16 -0.60 -0.199 0.10195E+04 63 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71234E+04 65 diaspore 2.87 0.74 -2.13 -0.356 0.36450E+04 66 diamond -3.10 -7.44 -4.33 -1.238 0.74009E+04 71 enstatite 17.26 12.27 -4.99 -0.499 0.85226E+04 73 clinoenstatite 17.17 12.27 -4.89 -0.489 0.83541E+04 75 epidote 24.67 22.70 -1.97 -0.095 0.33585E+04 76 clinozoisite 22.81 18.95 -3.86 -0.175 0.65869E+04 77 epidote-Fe 29.84 26.46 -3.38 -0.176 0.57768E+04 78 fayalite 14.05 10.31 -3.73 -0.533 0.63743E+04 79 ferrosilite 11.15 7.16 -3.99 -0.399 0.68202E+04 83 gibbsite 4.08 0.74 -3.34 -0.477 0.57035E+04 84 glaucophane 22.97 20.80 -2.17 -0.059 0.37134E+04 85 glaucophane-Fe 17.28 13.12 -4.15 -0.112 0.70919E+04 86 graphite -3.55 -7.44 -3.89 -1.112 0.66431E+04 87 greenalite 16.14 13.89 -2.25 -0.187 0.38408E+04 90 hematite 12.57 8.99 -3.58 -0.434 0.61111E+04 91 heulandite -5.83 -7.52 -1.69 -0.077 0.28938E+04 95 jadeite 4.22 2.77 -1.44 -0.144 0.24617E+04 97 kalsilite 7.58 3.83 -3.76 -0.537 0.64126E+04 98 kaolinite -1.33 -4.84 -3.50 -0.319 0.59832E+04 101 laumontite 2.88 1.95 -0.93 -0.062 0.15935E+04 102 lawsonite 9.62 8.26 -1.35 -0.090 0.23070E+04 103 leucite 4.12 0.67 -3.45 -0.345 0.58873E+04 105 lizardite 23.24 21.57 -1.68 -0.140 0.28618E+04 107 magnetite 20.09 15.72 -4.37 -0.356 0.74536E+04 108 minnesotaite 10.39 7.58 -2.81 -0.165 0.48028E+04 112 manganosite 14.06 9.24 -4.82 -1.204 0.82239E+04 120 muscovite 2.58 -1.01 -3.59 -0.211 0.61315E+04 121 paragonite 4.24 1.09 -3.15 -0.185 0.53706E+04 122 nepheline 8.34 5.93 -2.41 -0.344 0.41125E+04 128 periclase-Fe 11.63 6.73 -4.89 -1.223 0.83523E+04 134 phlogopite-Na 29.65 27.50 -2.15 -0.119 0.36678E+04 136 prehnite 19.37 18.21 -1.16 -0.068 0.19849E+04 137 prehnite-Fe 22.50 21.96 -0.53 -0.032 0.91159E+03 138 pumpellyite-Fe 46.27 43.89 -2.38 -0.053 0.40582E+04 139 pumpellyite-Mg 48.99 46.45 -2.54 -0.057 0.43420E+04 143 pyrrhotite -4.26 -7.64 -3.38 -1.126 0.57685E+04 144 pyrrhotiteFe0.875 -6.02 -9.04 -3.02 -1.111 0.51557E+04 145 pyroxmangite 7.40 6.08 -1.31 -0.263 0.22442E+04 146 pyrophyllite -6.18 -11.15 -4.98 -0.311 0.84962E+04 147 quartz -2.99 -3.16 -0.17 -0.056 0.28680E+03 152 rhodonite 7.45 6.08 -1.36 -0.272 0.23245E+04 153 sanidine -1.28 -2.49 -1.21 -0.093 0.20677E+04 165 stilpnomelane-Mg 27.44 25.81 -1.63 -0.049 0.27804E+04 171 talc 16.49 15.25 -1.24 -0.073 0.21140E+04 174 tephroite 18.09 15.33 -2.76 -0.394 0.47122E+04 178 tridymite -2.63 -3.16 -0.53 -0.177 0.90678E+03 179 tremolite 47.87 47.42 -0.45 -0.012 0.77494E+03 180 ferroactinolite 38.45 34.62 -3.83 -0.104 0.65448E+04 181 troilite-low -4.41 -7.64 -3.23 -1.076 0.55113E+04 183 vesuvianite 223.47 218.82 -4.65 -0.036 0.79440E+04 187 wairakite 3.95 1.95 -2.00 -0.118 0.34155E+04 188 walstromite 11.51 9.94 -1.56 -0.313 0.26719E+04 189 wollastonite 10.46 9.94 -0.52 -0.103 0.88229E+03 190 pseudo-wollastonite 11.00 9.94 -1.06 -0.211 0.18021E+04 191 zoisite 22.85 18.95 -3.90 -0.177 0.66609E+04 192 akaganeite 7.75 4.49 -3.26 -0.705 0.55681E+04 199 chalcedony -2.80 -3.16 -0.35 -0.118 0.60610E+03 201 montmorillonite-Ca -2.29 -6.17 -3.88 -0.240 0.66180E+04 202 montmorillonite-K -2.24 -6.27 -4.03 -0.247 0.68816E+04 203 montmorillonite-Mg -2.48 -6.79 -4.32 -0.267 0.73678E+04 204 montmorillonite-Na -2.04 -5.57 -3.54 -0.216 0.60365E+04 205 nontronite-Ca 3.21 -0.19 -3.41 -0.221 0.58215E+04 206 nontronite-H 2.53 -2.36 -4.89 -0.328 0.83485E+04 207 nontronite-K 3.34 -0.30 -3.64 -0.233 0.62083E+04 208 nontronite-Mg 3.07 -0.82 -3.90 -0.253 0.66553E+04 209 nontronite-Na 3.52 0.40 -3.12 -0.200 0.53292E+04 224 tobermorite 9.82 7.76 -2.07 -0.564 0.35287E+04 230 alabandite -0.98 -5.13 -4.15 -1.385 0.70930E+04 233 boehmite 4.41 0.74 -3.67 -0.611 0.62619E+04 235 ferrous-oxide 9.81 6.73 -3.08 -0.769 0.52532E+04 240 silica-amorphous -2.09 -3.16 -1.07 -0.355 0.18203E+04 242 an20ab80 2.02 1.35 -0.67 -0.052 0.11472E+04 243 an25ab75 2.65 1.78 -0.87 -0.067 0.14810E+04 244 an30ab70 3.28 2.21 -1.07 -0.082 0.18244E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 100.0000000 g Current total amount of reactant added: 6199.9990000 g New total amount of reactant added: 6299.9990000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.5223E-10 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 12 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 6299.9990000 Water: Moles liquid = 0.2030E+02 kg liquid = 0.3658E+00 Moles total = -.2346E+02 kg total = -.4227E+00 Activity = 1.0000 Stoichiometric ionic strength = .1151583E-01 Osmotic coef. = 0.9682 True ionic strength = .2016266E-01 Chg. balance for total moles = 0.5223E-10 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.88923E-10 -10.0510 0.74684E-10 -10.1268 0.83987E+00 -0.0758 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.37547E-03 -3.4254 0.31344E-03 -3.5038 0.83480E+00 -0.0784 4 SO4-- 0.17614E-11 -11.7542 0.91297E-12 -12.0395 0.51833E+00 -0.2854 5 HCO3- 0.65148E-06 -6.1861 0.54465E-06 -6.2639 0.83602E+00 -0.0778 6 HS- 0.69713E-04 -4.1567 0.58204E-04 -4.2350 0.83492E+00 -0.0784 7 Al+++ 0.99278E-29 -29.0031 0.22838E-29 -29.6413 0.23004E+00 -0.6382 8 H4SiO4 0.69598E-03 -3.1574 0.69598E-03 -3.1574 0.10000E+01 0.0000 9 Ca++ 0.13706E-06 -6.8631 0.70516E-07 -7.1517 0.51451E+00 -0.2886 10 Mg++ 0.21442E-10 -10.6687 0.10981E-10 -10.9593 0.51214E+00 -0.2906 11 Fe++ 0.59098E-13 -13.2284 0.30300E-13 -13.5186 0.51270E+00 -0.2901 12 K+ 0.15763E-03 -3.8023 0.13182E-03 -3.8800 0.83622E+00 -0.0777 13 Na+ 0.20003E-01 -1.6989 0.16696E-01 -1.7774 0.83464E+00 -0.0785 14 Mn++ 0.18965E-10 -10.7220 0.97317E-11 -11.0118 0.51313E+00 -0.2898 15 HPO4-- 0.44805E-07 -7.3487 0.23227E-07 -7.6340 0.51841E+00 -0.2853 16 HSiO3- 0.10424E-01 -1.9820 0.87015E-02 -2.0604 0.83480E+00 -0.0784 17 Ca(HSiO3)+ 0.16707E-07 -7.7771 0.13974E-07 -7.8547 0.83640E+00 -0.0776 18 Mg(HSiO3)+ 0.32379E-11 -11.4897 0.27082E-11 -11.5673 0.83640E+00 -0.0776 19 NaHSiO3,aq 0.23496E-02 -2.6290 0.23496E-02 -2.6290 0.10000E+01 0.0000 20 AlO+ 0.66597E-16 -16.1765 0.55702E-16 -16.2541 0.83640E+00 -0.0776 22 HAlO2,aq 0.14853E-09 -9.8282 0.14853E-09 -9.8282 0.10000E+01 0.0000 23 AlO2- 0.52831E-05 -5.2771 0.44023E-05 -5.3563 0.83328E+00 -0.0792 24 CH4,aq 0.33848E-04 -4.4705 0.33729E-04 -4.4720 0.99649E+00 -0.0015 25 C2H6,aq 0.16851E-13 -13.7734 0.16792E-13 -13.7749 0.99649E+00 -0.0015 29 CO,aq 0.25290E-16 -16.5971 0.25290E-16 -16.5971 0.10000E+01 0.0000 30 CO2,aq 0.87224E-10 -10.0594 0.86918E-10 -10.0609 0.99649E+00 -0.0015 31 CO3-2 0.12315E-05 -5.9095 0.63699E-06 -6.1959 0.51723E+00 -0.2863 32 CaCO3,aq 0.56322E-09 -9.2493 0.56322E-09 -9.2493 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.11721E-11 -11.9310 0.98037E-12 -12.0086 0.83640E+00 -0.0776 34 CaCl+ 0.42765E-10 -10.3689 0.35769E-10 -10.4465 0.83640E+00 -0.0776 35 CaCl2,aq 0.26636E-14 -14.5745 0.26636E-14 -14.5745 0.10000E+01 0.0000 36 CaOH+ 0.80453E-07 -7.0945 0.67292E-07 -7.1720 0.83640E+00 -0.0776 37 CaSO4,aq 0.20443E-16 -16.6894 0.20443E-16 -16.6894 0.10000E+01 0.0000 38 HCl,aq 0.42896E-14 -14.3676 0.42896E-14 -14.3676 0.10000E+01 0.0000 43 FeCl+ 0.17973E-16 -16.7454 0.15032E-16 -16.8230 0.83640E+00 -0.0776 46 FeO,aq 0.21113E-09 -9.6755 0.21113E-09 -9.6755 0.10000E+01 0.0000 47 FeOH+ 0.15789E-10 -10.8016 0.13206E-10 -10.8792 0.83640E+00 -0.0776 48 HFeO2- 0.35432E-07 -7.4506 0.29578E-07 -7.5290 0.83480E+00 -0.0784 49 FeO+ 0.11066E-16 -16.9560 0.92554E-17 -17.0336 0.83640E+00 -0.0776 51 FeO2- 0.40673E-09 -9.3907 0.33953E-09 -9.4691 0.83480E+00 -0.0784 52 HFeO2,aq 0.32251E-11 -11.4915 0.32251E-11 -11.4915 0.10000E+01 0.0000 53 H2,aq 0.11623E-04 -4.9347 0.11582E-04 -4.9362 0.99649E+00 -0.0015 54 KCl,aq 0.74884E-09 -9.1256 0.74884E-09 -9.1256 0.10000E+01 0.0000 56 KOH,aq 0.75375E-06 -6.1228 0.75375E-06 -6.1228 0.10000E+01 0.0000 57 KSO4- 0.22370E-14 -14.6503 0.18675E-14 -14.7287 0.83480E+00 -0.0784 58 MgCO3,aq 0.21985E-13 -13.6579 0.21985E-13 -13.6579 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.18651E-15 -15.7293 0.15600E-15 -15.8069 0.83640E+00 -0.0776 60 MgCl+ 0.60360E-14 -14.2193 0.50485E-14 -14.2968 0.83640E+00 -0.0776 61 MgOH+ 0.69328E-10 -10.1591 0.57986E-10 -10.2367 0.83640E+00 -0.0776 63 MnO,aq 0.18068E-08 -8.7431 0.18068E-08 -8.7431 0.10000E+01 0.0000 64 MnOH+ 0.47109E-09 -9.3269 0.39403E-09 -9.4045 0.83640E+00 -0.0776 65 MnO2-2 0.20785E-10 -10.6823 0.10751E-10 -10.9686 0.51723E+00 -0.2863 66 HMnO2- 0.21071E-09 -9.6763 0.17590E-09 -9.7547 0.83480E+00 -0.0784 69 MnCl+ 0.22458E-13 -13.6486 0.18784E-13 -13.7262 0.83640E+00 -0.0776 71 NaCl,aq 0.17342E-05 -5.7609 0.17342E-05 -5.7609 0.10000E+01 0.0000 72 NaOH,aq 0.96047E-04 -4.0175 0.96047E-04 -4.0175 0.10000E+01 0.0000 74 OH- 0.92840E-02 -2.0323 0.77362E-02 -2.1115 0.83328E+00 -0.0792 79 HPO3-2 0.16209E-14 -14.7902 0.83838E-15 -15.0766 0.51723E+00 -0.2863 81 H2PO3- 0.15041E-18 -18.8227 0.12556E-18 -18.9011 0.83480E+00 -0.0784 82 H3PO4,aq 0.90611E-18 -18.0428 0.90611E-18 -18.0428 0.10000E+01 0.0000 83 H2PO4- 0.38297E-10 -10.4168 0.32001E-10 -10.4948 0.83559E+00 -0.0780 84 PO4-3 0.10499E-08 -8.9788 0.25375E-09 -9.5956 0.24168E+00 -0.6168 88 HP2O7-3 0.93228E-18 -18.0305 0.21468E-18 -18.6682 0.23027E+00 -0.6378 89 P2O7-4 0.89726E-17 -17.0471 0.68670E-18 -18.1632 0.76534E-01 -1.1161 90 H2S,aq 0.13482E-07 -7.8702 0.13435E-07 -7.8718 0.99649E+00 -0.0015 91 S2-2 0.12530E-13 -13.9020 0.64810E-14 -14.1884 0.51723E+00 -0.2863 97 SO3-2 0.26187E-17 -17.5819 0.13741E-17 -17.8620 0.52475E+00 -0.2800 99 HSO4- 0.78487E-19 -19.1052 0.65711E-19 -19.1824 0.83722E+00 -0.0772 Charge balance for all species = 0.1428E-09 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.8892343E-10 -.2217945E-01 -.2231655E+02 0.0000 2 H2O 0.1000000E+01 0.5550491E+02 0.9981929E+06 0.0000 3 Cl- 0.3754694E-03 0.3772044E-03 0.1334969E+02 6.6229 4 SO4-- 0.1761363E-11 -.3675385E-04 -.3524473E+01 8.2140 5 HCO3- 0.6514810E-06 0.3573177E-04 0.2176448E+01 3.8629 6 HS- 0.6971260E-04 0.1064799E-03 0.3515360E+01 5.8917 7 Al+++ 0.9927772E-29 0.5283289E-05 0.1423023E+00 0.7390 8 H4SiO4 0.6959822E-03 0.1346916E-01 0.1292335E+04 -3.1574 9 Ca++ 0.1370556E-06 0.2348234E-06 0.9394830E-02 13.1018 10 Mg++ 0.2144191E-10 0.9403334E-10 0.2282149E-05 9.2942 11 Fe++ 0.5909757E-13 0.3606849E-07 0.2010802E-02 6.7350 12 K+ 0.1576345E-03 0.1583890E-03 0.6182521E+01 6.2467 13 Na+ 0.2000324E-01 0.2245067E-01 0.5152357E+03 8.3494 14 Mn++ 0.1896537E-10 0.2528427E-08 0.1386643E-03 9.2417 15 HPO4-- 0.4480505E-07 0.4589329E-07 0.4397106E-02 12.6195 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.1043186E+03 -.8112820E-02 -.1043105E+03 0.0000000E+00 2 H2O -.2346482E+02 0.2030264E+02 -.4376746E+02 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.1746200E+00 -.1344385E-04 0.1746334E+00 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.1745944E+00 0.3894832E-04 -.1746334E+00 0.0000000E+00 7 Al+++ 0.2054267E+02 0.1932526E-05 0.2054267E+02 0.0000000E+00 8 H4SiO4 0.6560052E+02 0.4926763E-02 0.6559560E+02 0.0000000E+00 9 Ca++ 0.7245912E+01 0.8589390E-07 0.7245912E+01 0.0000000E+00 10 Mg++ 0.4999999E+01 0.3439560E-10 0.4999999E+01 0.0000000E+00 11 Fe++ 0.4491953E+01 0.1319316E-07 0.4491953E+01 0.0000000E+00 12 K+ 0.1337579E+01 0.5793568E-04 0.1337521E+01 0.0000000E+00 13 Na+ 0.7908194E+01 0.8212025E-02 0.7899982E+01 0.0000000E+00 14 Mn++ 0.1092331E+00 0.9248503E-09 0.1092331E+00 0.0000000E+00 15 HPO4-- 0.3728073E-01 0.1678689E-07 0.3728071E-01 0.0000000E+00 Chg. balance for solid moles: -.2362E-13 Mass of aqueous solution: 0.366420E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 6299.9990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 7.893 0.897 2070. 3.316 30.07 794.5 andradite 0.6985 -0.156 355.0 2.550 5.158 92.23 grossular 0.1691 -0.772 76.19 1.882 1.107 21.20 apatite-OH 0.1243E-01 -1.906 6.242 0.795 0.9070E-01 1.984 clinochlore 0.8947 -0.048 497.3 2.697 7.225 189.2 daphnite 0.2590 -0.587 184.8 2.267 2.685 56.00 chlorite-Mn 0.2185E-01 -1.661 15.49 1.190 0.2250 4.936 diopside 0.3334 -0.477 72.20 1.859 1.049 22.07 hedenbergite 0.8646E-01 -1.063 21.45 1.331 0.3117 5.876 microcline 1.173 0.069 326.4 2.514 4.743 127.5 stilbite 4.054 0.608 2857. 3.456 41.51 1333. stilpnomelane-Fe 0.3294 -0.482 355.0 2.550 5.159 122.6 tr.625ac.25prg.125 0.5332E-01 -1.273 45.58 1.659 0.6622 14.67 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8051E+00 0.8051E+00 1.0000 -0.094 grossular 0.1949E+00 0.1949E+00 1.0000 -0.710 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.7611E+00 0.7611E+00 1.0000 -0.119 daphnite 0.2203E+00 0.2203E+00 1.0000 -0.657 chlorite-Mn 0.1858E-01 0.1858E-01 1.0000 -1.731 diopside 0.7941E+00 0.7941E+00 1.0000 -0.100 hedenbergite 0.2059E+00 0.2059E+00 1.0000 -0.686 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 tr.625ac.25prg.125 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 6882.596498 g Volume = 2785.417689 cm3 Porosity: -10.4886% V(tot) - V(min): -.26442E+03 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 6299.9990000 g log = 3.7993 Original solution: 1000.0103000 g Original solution / Rock added: 0.16 (Water/Rock Ratio), log = -0.7993 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0854 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9408E+00 0.9851 0.1006E+01 0.1021E+01 CO2,gas 0.8512E-08 1.0065 0.9299E-08 0.9239E-08 CH4,gas 0.4519E-01 1.0121 0.4965E-01 0.4906E-01 H2,gas 0.1400E-01 1.0006 0.1521E-01 0.1520E-01 H2S,gas 0.3417E-06 0.9958 0.3693E-06 0.3709E-06 S2,gas 0.2040E-28 1.0000 0.2214E-28 0.2214E-28 CO,gas 0.3472E-13 1.0000 0.3769E-13 0.3769E-13 SO3,gas 0.1774E-47 1.0000 0.1925E-47 0.1925E-47 SO2,gas 0.1049E-26 1.0000 0.1139E-26 0.1139E-26 HCl,gas 0.6973E-17 1.0000 0.7569E-17 0.7569E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 16 albite -0.38 -0.38 0.00 0.000 -0.94784E-12 22 andradite 39.01 39.01 0.00 0.000 0.00000E+00 23 grossular 32.73 32.73 0.00 0.000 0.12132E-10 32 apatite-OH -18.15 -18.15 0.00 0.000 0.00000E+00 46 clinochlore 39.07 39.07 0.00 0.000 -0.12132E-10 47 daphnite 28.97 28.97 0.00 0.000 -0.24265E-10 48 chlorite-Mn 46.87 46.87 0.00 0.000 0.00000E+00 67 diopside 16.18 16.18 0.00 0.000 0.00000E+00 68 hedenbergite 14.21 14.21 0.00 0.000 -0.30331E-11 116 microcline -2.49 -2.49 0.00 0.000 0.15165E-11 163 stilbite -7.52 -7.52 0.00 0.000 0.15165E-10 164 stilpnomelane-Fe 13.02 13.02 0.00 0.000 -0.75827E-10 245 tr.625ac.25prg.125 45.16 45.16 0.00 0.000 -0.24265E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -16.39 -9.73 -3.244 0.16615E+05 -8.032 3 CH4,gas 4.54 1.54 -3.00 -0.751 0.51277E+04 -1.304 4 H2,gas 8.00 4.48 -3.52 -2.010 0.60051E+04 -1.818 5 H2S,gas -6.23 -14.36 -8.13 -4.066 0.13884E+05 -6.433 6 S2,gas -7.34 -37.69 -30.35 -4.670 0.51828E+05 -28.655 7 CO,gas 3.21 -11.91 -15.12 -4.653 0.25822E+05 -13.424 8 SO3,gas 17.12 -32.29 -49.41 -12.354 0.84374E+05 -47.715 9 SO2,gas 0.83 -27.81 -28.64 -7.638 0.48906E+05 -26.943 10 HCl,gas 5.19 -13.63 -18.82 -9.410 0.32135E+05 -17.121 11 acmite 7.71 6.53 -1.18 -0.123 0.20175E+04 15 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 19 spessartine 24.46 19.73 -4.73 -0.236 0.80702E+04 20 analcite 3.32 2.77 -0.55 -0.061 0.93625E+03 26 annite 20.12 17.72 -2.40 -0.134 0.41064E+04 27 phlogopite 27.06 25.40 -1.67 -0.093 0.28489E+04 29 anorthite 12.71 8.26 -4.45 -0.342 0.75903E+04 35 aragonite 0.97 -3.29 -4.26 -1.418 0.72659E+04 36 brucite 12.57 9.29 -3.27 -0.655 0.55909E+04 37 calcite 0.81 -3.29 -4.10 -1.367 0.70017E+04 38 carnegieite-low 9.02 5.93 -3.09 -0.442 0.52801E+04 39 carnegieite-high 10.09 5.93 -4.16 -0.595 0.71071E+04 40 carpholite-Mg 8.58 4.46 -4.12 -0.275 0.70429E+04 41 carpholite-Fe 6.71 1.90 -4.81 -0.321 0.82207E+04 42 celadonite 5.34 3.65 -1.69 -0.099 0.28879E+04 43 celadonite-Fe 3.88 1.09 -2.79 -0.164 0.47561E+04 44 chrysotile 23.89 21.57 -2.32 -0.194 0.39692E+04 49 chlorite-Al-free 47.17 43.14 -4.04 -0.168 0.68936E+04 51 chloritoid-Fe 9.17 5.06 -4.12 -0.275 0.70316E+04 52 chloritoid-Mn 11.40 7.56 -3.84 -0.256 0.65547E+04 54 coesite -2.38 -3.16 -0.78 -0.260 0.13341E+04 61 cristobalite -2.56 -3.16 -0.60 -0.199 0.10195E+04 63 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71234E+04 65 diaspore 2.87 0.74 -2.13 -0.356 0.36450E+04 66 diamond -3.10 -7.43 -4.32 -1.235 0.73808E+04 71 enstatite 17.26 12.27 -4.99 -0.499 0.85226E+04 73 clinoenstatite 17.17 12.27 -4.89 -0.489 0.83541E+04 75 epidote 24.67 22.70 -1.97 -0.095 0.33585E+04 76 clinozoisite 22.81 18.95 -3.86 -0.175 0.65869E+04 77 epidote-Fe 29.84 26.46 -3.38 -0.176 0.57768E+04 78 fayalite 14.05 10.31 -3.73 -0.533 0.63743E+04 79 ferrosilite 11.15 7.16 -3.99 -0.399 0.68202E+04 83 gibbsite 4.08 0.74 -3.34 -0.477 0.57035E+04 84 glaucophane 22.97 20.80 -2.17 -0.059 0.37134E+04 85 glaucophane-Fe 17.28 13.12 -4.15 -0.112 0.70919E+04 86 graphite -3.55 -7.43 -3.88 -1.108 0.66230E+04 87 greenalite 16.14 13.89 -2.25 -0.187 0.38408E+04 90 hematite 12.57 8.99 -3.58 -0.434 0.61111E+04 91 heulandite -5.83 -7.52 -1.69 -0.077 0.28938E+04 95 jadeite 4.22 2.77 -1.44 -0.144 0.24617E+04 97 kalsilite 7.58 3.83 -3.76 -0.537 0.64126E+04 98 kaolinite -1.33 -4.84 -3.50 -0.319 0.59832E+04 101 laumontite 2.88 1.95 -0.93 -0.062 0.15935E+04 102 lawsonite 9.62 8.26 -1.35 -0.090 0.23070E+04 103 leucite 4.12 0.67 -3.45 -0.345 0.58873E+04 105 lizardite 23.24 21.57 -1.68 -0.140 0.28618E+04 107 magnetite 20.09 15.72 -4.37 -0.356 0.74536E+04 108 minnesotaite 10.39 7.58 -2.81 -0.165 0.48028E+04 112 manganosite 14.06 9.24 -4.82 -1.204 0.82238E+04 120 muscovite 2.58 -1.01 -3.59 -0.211 0.61315E+04 121 paragonite 4.24 1.09 -3.15 -0.185 0.53706E+04 122 nepheline 8.34 5.93 -2.41 -0.344 0.41125E+04 128 periclase-Fe 11.63 6.73 -4.89 -1.223 0.83523E+04 134 phlogopite-Na 29.65 27.50 -2.15 -0.119 0.36678E+04 136 prehnite 19.37 18.21 -1.16 -0.068 0.19849E+04 137 prehnite-Fe 22.50 21.96 -0.53 -0.032 0.91159E+03 138 pumpellyite-Fe 46.27 43.89 -2.38 -0.053 0.40582E+04 139 pumpellyite-Mg 48.99 46.45 -2.54 -0.057 0.43420E+04 143 pyrrhotite -4.26 -7.63 -3.37 -1.122 0.57482E+04 144 pyrrhotiteFe0.875 -6.02 -9.02 -3.01 -1.106 0.51354E+04 145 pyroxmangite 7.40 6.08 -1.31 -0.263 0.22442E+04 146 pyrophyllite -6.18 -11.15 -4.98 -0.311 0.84962E+04 147 quartz -2.99 -3.16 -0.17 -0.056 0.28680E+03 152 rhodonite 7.45 6.08 -1.36 -0.272 0.23245E+04 153 sanidine -1.28 -2.49 -1.21 -0.093 0.20677E+04 165 stilpnomelane-Mg 27.44 25.81 -1.63 -0.049 0.27804E+04 171 talc 16.49 15.25 -1.24 -0.073 0.21140E+04 174 tephroite 18.09 15.33 -2.76 -0.394 0.47122E+04 178 tridymite -2.63 -3.16 -0.53 -0.177 0.90678E+03 179 tremolite 47.87 47.42 -0.45 -0.012 0.77494E+03 180 ferroactinolite 38.45 34.62 -3.83 -0.104 0.65448E+04 181 troilite-low -4.41 -7.63 -3.22 -1.072 0.54910E+04 183 vesuvianite 223.47 218.82 -4.65 -0.036 0.79440E+04 187 wairakite 3.95 1.95 -2.00 -0.118 0.34155E+04 188 walstromite 11.51 9.94 -1.56 -0.313 0.26719E+04 189 wollastonite 10.46 9.94 -0.52 -0.103 0.88229E+03 190 pseudo-wollastonite 11.00 9.94 -1.06 -0.211 0.18021E+04 191 zoisite 22.85 18.95 -3.90 -0.177 0.66609E+04 192 akaganeite 7.75 4.49 -3.26 -0.705 0.55681E+04 199 chalcedony -2.80 -3.16 -0.35 -0.118 0.60610E+03 201 montmorillonite-Ca -2.29 -6.17 -3.88 -0.240 0.66180E+04 202 montmorillonite-K -2.24 -6.27 -4.03 -0.247 0.68816E+04 203 montmorillonite-Mg -2.48 -6.79 -4.32 -0.267 0.73678E+04 204 montmorillonite-Na -2.04 -5.57 -3.54 -0.216 0.60365E+04 205 nontronite-Ca 3.21 -0.19 -3.41 -0.221 0.58215E+04 206 nontronite-H 2.53 -2.36 -4.89 -0.328 0.83485E+04 207 nontronite-K 3.34 -0.30 -3.64 -0.233 0.62083E+04 208 nontronite-Mg 3.07 -0.82 -3.90 -0.253 0.66553E+04 209 nontronite-Na 3.52 0.40 -3.12 -0.200 0.53292E+04 224 tobermorite 9.82 7.76 -2.07 -0.564 0.35287E+04 230 alabandite -0.98 -5.12 -4.14 -1.381 0.70727E+04 233 boehmite 4.41 0.74 -3.67 -0.611 0.62619E+04 235 ferrous-oxide 9.81 6.73 -3.08 -0.769 0.52532E+04 240 silica-amorphous -2.09 -3.16 -1.07 -0.355 0.18203E+04 242 an20ab80 2.02 1.35 -0.67 -0.052 0.11472E+04 243 an25ab75 2.65 1.78 -0.87 -0.067 0.14810E+04 244 an30ab70 3.28 2.21 -1.07 -0.082 0.18244E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 100.0000000 g Current total amount of reactant added: 6299.9990000 g New total amount of reactant added: 6399.9990000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.5222E-10 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 12 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 6399.9990000 Water: Moles liquid = 0.1975E+02 kg liquid = 0.3557E+00 Moles total = -.2472E+02 kg total = -.4453E+00 Activity = 1.0000 Stoichiometric ionic strength = .1152466E-01 Osmotic coef. = 0.9682 True ionic strength = .2016956E-01 Chg. balance for total moles = 0.5222E-10 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.88954E-10 -10.0508 0.74708E-10 -10.1266 0.83986E+00 -0.0758 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.38607E-03 -3.4133 0.32228E-03 -3.4918 0.83478E+00 -0.0784 4 SO4-- 0.18106E-11 -11.7422 0.93843E-12 -12.0276 0.51829E+00 -0.2854 5 HCO3- 0.66969E-06 -6.1741 0.55986E-06 -6.2519 0.83600E+00 -0.0778 6 HS- 0.71681E-04 -4.1446 0.59846E-04 -4.2230 0.83490E+00 -0.0784 7 Al+++ 0.99393E-29 -29.0026 0.22860E-29 -29.6409 0.22999E+00 -0.6383 8 H4SiO4 0.69598E-03 -3.1574 0.69598E-03 -3.1574 0.10000E+01 0.0000 9 Ca++ 0.13716E-06 -6.8628 0.70561E-07 -7.1514 0.51446E+00 -0.2886 10 Mg++ 0.21458E-10 -10.6684 0.10988E-10 -10.9591 0.51209E+00 -0.2907 11 Fe++ 0.59141E-13 -13.2281 0.30319E-13 -13.5183 0.51266E+00 -0.2902 12 K+ 0.15769E-03 -3.8022 0.13186E-03 -3.8799 0.83620E+00 -0.0777 13 Na+ 0.20010E-01 -1.6988 0.16701E-01 -1.7773 0.83462E+00 -0.0785 14 Mn++ 0.18980E-10 -10.7217 0.97381E-11 -11.0115 0.51308E+00 -0.2898 15 HPO4-- 0.44781E-07 -7.3489 0.23213E-07 -7.6343 0.51836E+00 -0.2854 16 HSiO3- 0.10420E-01 -1.9821 0.86988E-02 -2.0605 0.83478E+00 -0.0784 17 Ca(HSiO3)+ 0.16713E-07 -7.7770 0.13978E-07 -7.8545 0.83638E+00 -0.0776 18 Mg(HSiO3)+ 0.32390E-11 -11.4896 0.27091E-11 -11.5672 0.83638E+00 -0.0776 19 NaHSiO3,aq 0.23496E-02 -2.6290 0.23496E-02 -2.6290 0.10000E+01 0.0000 20 AlO+ 0.66620E-16 -16.1764 0.55720E-16 -16.2540 0.83638E+00 -0.0776 22 HAlO2,aq 0.14853E-09 -9.8282 0.14853E-09 -9.8282 0.10000E+01 0.0000 23 AlO2- 0.52816E-05 -5.2772 0.44009E-05 -5.3565 0.83326E+00 -0.0792 24 CH4,aq 0.34804E-04 -4.4584 0.34682E-04 -4.4599 0.99649E+00 -0.0015 25 C2H6,aq 0.17817E-13 -13.7492 0.17754E-13 -13.7507 0.99649E+00 -0.0015 29 CO,aq 0.26004E-16 -16.5850 0.26004E-16 -16.5850 0.10000E+01 0.0000 30 CO2,aq 0.89689E-10 -10.0473 0.89373E-10 -10.0488 0.99649E+00 -0.0015 31 CO3-2 0.12657E-05 -5.8977 0.65457E-06 -6.1840 0.51718E+00 -0.2864 32 CaCO3,aq 0.57914E-09 -9.2372 0.57914E-09 -9.2372 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.12057E-11 -11.9188 0.10084E-11 -11.9964 0.83638E+00 -0.0776 34 CaCl+ 0.44000E-10 -10.3565 0.36801E-10 -10.4341 0.83638E+00 -0.0776 35 CaCl2,aq 0.28178E-14 -14.5501 0.28178E-14 -14.5501 0.10000E+01 0.0000 36 CaOH+ 0.80481E-07 -7.0943 0.67313E-07 -7.1719 0.83638E+00 -0.0776 37 CaSO4,aq 0.21027E-16 -16.6772 0.21027E-16 -16.6772 0.10000E+01 0.0000 38 HCl,aq 0.44120E-14 -14.3554 0.44120E-14 -14.3554 0.10000E+01 0.0000 43 FeCl+ 0.18492E-16 -16.7330 0.15466E-16 -16.8106 0.83638E+00 -0.0776 46 FeO,aq 0.21113E-09 -9.6755 0.21113E-09 -9.6755 0.10000E+01 0.0000 47 FeOH+ 0.15794E-10 -10.8015 0.13210E-10 -10.8791 0.83638E+00 -0.0776 48 HFeO2- 0.35421E-07 -7.4507 0.29569E-07 -7.5292 0.83478E+00 -0.0784 49 FeO+ 0.11069E-16 -16.9559 0.92584E-17 -17.0335 0.83638E+00 -0.0776 51 FeO2- 0.40661E-09 -9.3908 0.33943E-09 -9.4693 0.83478E+00 -0.0784 52 HFeO2,aq 0.32251E-11 -11.4915 0.32251E-11 -11.4915 0.10000E+01 0.0000 53 H2,aq 0.11623E-04 -4.9347 0.11582E-04 -4.9362 0.99649E+00 -0.0015 54 KCl,aq 0.77020E-09 -9.1134 0.77020E-09 -9.1134 0.10000E+01 0.0000 56 KOH,aq 0.75375E-06 -6.1228 0.75375E-06 -6.1228 0.10000E+01 0.0000 57 KSO4- 0.23002E-14 -14.6382 0.19202E-14 -14.7167 0.83478E+00 -0.0784 58 MgCO3,aq 0.22606E-13 -13.6458 0.22606E-13 -13.6458 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.19185E-15 -15.7170 0.16046E-15 -15.7946 0.83638E+00 -0.0776 60 MgCl+ 0.62103E-14 -14.2069 0.51942E-14 -14.2845 0.83638E+00 -0.0776 61 MgOH+ 0.69352E-10 -10.1589 0.58005E-10 -10.2365 0.83638E+00 -0.0776 63 MnO,aq 0.18069E-08 -8.7431 0.18069E-08 -8.7431 0.10000E+01 0.0000 64 MnOH+ 0.47127E-09 -9.3267 0.39416E-09 -9.4043 0.83638E+00 -0.0776 65 MnO2-2 0.20774E-10 -10.6825 0.10744E-10 -10.9688 0.51718E+00 -0.2864 66 HMnO2- 0.21066E-09 -9.6764 0.17585E-09 -9.7549 0.83478E+00 -0.0784 69 MnCl+ 0.23107E-13 -13.6363 0.19326E-13 -13.7139 0.83638E+00 -0.0776 71 NaCl,aq 0.17837E-05 -5.7487 0.17837E-05 -5.7487 0.10000E+01 0.0000 72 NaOH,aq 0.96047E-04 -4.0175 0.96047E-04 -4.0175 0.10000E+01 0.0000 74 OH- 0.92813E-02 -2.0324 0.77337E-02 -2.1116 0.83326E+00 -0.0792 79 HPO3-2 0.16200E-14 -14.7905 0.83785E-15 -15.0768 0.51718E+00 -0.2864 81 H2PO3- 0.15036E-18 -18.8229 0.12552E-18 -18.9013 0.83478E+00 -0.0784 82 H3PO4,aq 0.90611E-18 -18.0428 0.90611E-18 -18.0428 0.10000E+01 0.0000 83 H2PO4- 0.38286E-10 -10.4170 0.31991E-10 -10.4950 0.83557E+00 -0.0780 84 PO4-3 0.10491E-08 -8.9792 0.25351E-09 -9.5960 0.24163E+00 -0.6168 88 HP2O7-3 0.93159E-18 -18.0308 0.21448E-18 -18.6686 0.23023E+00 -0.6378 89 P2O7-4 0.89644E-17 -17.0475 0.68583E-18 -18.1638 0.76506E-01 -1.1163 90 H2S,aq 0.13867E-07 -7.8580 0.13818E-07 -7.8596 0.99649E+00 -0.0015 91 S2-2 0.13248E-13 -13.8778 0.68518E-14 -14.1642 0.51718E+00 -0.2864 97 SO3-2 0.26919E-17 -17.5699 0.14125E-17 -17.8500 0.52470E+00 -0.2801 99 HSO4- 0.80703E-19 -19.0931 0.67565E-19 -19.1703 0.83720E+00 -0.0772 Charge balance for all species = 0.1467E-09 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.8895355E-10 -.2217369E-01 -.2231074E+02 0.0000 2 H2O 0.1000000E+01 0.5550492E+02 0.9981926E+06 0.0000 3 Cl- 0.3860685E-03 0.3878531E-03 0.1372656E+02 6.6349 4 SO4-- 0.1810637E-11 -.3771024E-04 -.3616184E+01 8.2257 5 HCO3- 0.6696912E-06 0.3674050E-04 0.2237890E+01 3.8747 6 HS- 0.7168061E-04 0.1094047E-03 0.3611918E+01 5.9037 7 Al+++ 0.9939254E-29 0.5281733E-05 0.1422604E+00 0.7390 8 H4SiO4 0.6959823E-03 0.1346610E-01 0.1292041E+04 -3.1574 9 Ca++ 0.1371551E-06 0.2349730E-06 0.9400814E-02 13.1018 10 Mg++ 0.2145750E-10 0.9407387E-10 0.2283132E-05 9.2942 11 Fe++ 0.5914054E-13 0.3605795E-07 0.2010214E-02 6.7350 12 K+ 0.1576881E-03 0.1584426E-03 0.6184610E+01 6.2467 13 Na+ 0.2001004E-01 0.2245752E-01 0.5153929E+03 8.3494 14 Mn++ 0.1897957E-10 0.2528584E-08 0.1386729E-03 9.2417 15 HPO4-- 0.4478066E-07 0.4586809E-07 0.4394690E-02 12.6190 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.1059745E+03 -.7888030E-02 -.1059666E+03 0.0000000E+00 2 H2O -.2471836E+02 0.1974522E+02 -.4446359E+02 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.1773913E+00 -.1341497E-04 0.1774047E+00 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.1773658E+00 0.3891944E-04 -.1774047E+00 0.0000000E+00 7 Al+++ 0.2086874E+02 0.1878914E-05 0.2086874E+02 0.0000000E+00 8 H4SiO4 0.6664180E+02 0.4790407E-02 0.6663701E+02 0.0000000E+00 9 Ca++ 0.7360926E+01 0.8358890E-07 0.7360926E+01 0.0000000E+00 10 Mg++ 0.5079364E+01 0.3346567E-10 0.5079364E+01 0.0000000E+00 11 Fe++ 0.4563254E+01 0.1282719E-07 0.4563254E+01 0.0000000E+00 12 K+ 0.1358811E+01 0.5636410E-04 0.1358754E+01 0.0000000E+00 13 Na+ 0.8033718E+01 0.7989001E-02 0.8025729E+01 0.0000000E+00 14 Mn++ 0.1109670E+00 0.8995140E-09 0.1109670E+00 0.0000000E+00 15 HPO4-- 0.3787248E-01 0.1631703E-07 0.3787247E-01 0.0000000E+00 Chg. balance for solid moles: 0.1310E-13 Mass of aqueous solution: 0.356360E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 6399.9990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 8.019 0.904 2103. 3.323 30.07 807.2 andradite 0.7096 -0.149 360.6 2.557 5.158 93.69 grossular 0.1718 -0.765 77.40 1.889 1.107 21.54 apatite-OH 0.1262E-01 -1.899 6.341 0.802 0.9070E-01 2.015 clinochlore 0.9088 -0.042 505.2 2.703 7.225 192.1 daphnite 0.2631 -0.580 187.7 2.274 2.685 56.89 chlorite-Mn 0.2219E-01 -1.654 15.73 1.197 0.2250 5.014 diopside 0.3388 -0.470 73.38 1.866 1.049 22.43 hedenbergite 0.8787E-01 -1.056 21.80 1.338 0.3118 5.971 microcline 1.191 0.076 331.6 2.521 4.743 129.5 stilbite 4.118 0.615 2902. 3.463 41.51 1354. stilpnomelane-Fe 0.3346 -0.475 360.7 2.557 5.159 124.6 tr.625ac.25prg.125 0.5415E-01 -1.266 46.29 1.665 0.6620 14.90 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8051E+00 0.8051E+00 1.0000 -0.094 grossular 0.1949E+00 0.1949E+00 1.0000 -0.710 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.7611E+00 0.7611E+00 1.0000 -0.119 daphnite 0.2203E+00 0.2203E+00 1.0000 -0.657 chlorite-Mn 0.1859E-01 0.1859E-01 1.0000 -1.731 diopside 0.7941E+00 0.7941E+00 1.0000 -0.100 hedenbergite 0.2059E+00 0.2059E+00 1.0000 -0.686 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 tr.625ac.25prg.125 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 6991.847162 g Volume = 2829.620753 cm3 Porosity: -10.4889% V(tot) - V(min): -.26862E+03 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 6399.9990000 g log = 3.8062 Original solution: 1000.0103000 g Original solution / Rock added: 0.16 (Water/Rock Ratio), log = -0.8062 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0868 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9396E+00 0.9851 0.1006E+01 0.1021E+01 CO2,gas 0.8741E-08 1.0065 0.9562E-08 0.9500E-08 CH4,gas 0.4641E-01 1.0121 0.5105E-01 0.5044E-01 H2,gas 0.1398E-01 1.0006 0.1521E-01 0.1520E-01 H2S,gas 0.3510E-06 0.9958 0.3799E-06 0.3815E-06 S2,gas 0.2155E-28 1.0000 0.2342E-28 0.2342E-28 CO,gas 0.3565E-13 1.0000 0.3875E-13 0.3875E-13 SO3,gas 0.1822E-47 1.0000 0.1980E-47 0.1980E-47 SO2,gas 0.1078E-26 1.0000 0.1172E-26 0.1172E-26 HCl,gas 0.7163E-17 1.0000 0.7785E-17 0.7785E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 16 albite -0.38 -0.38 0.00 0.000 -0.94784E-12 22 andradite 39.01 39.01 0.00 0.000 -0.12132E-10 23 grossular 32.73 32.73 0.00 0.000 0.12132E-10 32 apatite-OH -18.15 -18.15 0.00 0.000 0.60662E-11 46 clinochlore 39.07 39.07 0.00 0.000 0.36397E-10 47 daphnite 28.97 28.97 0.00 0.000 0.24265E-10 48 chlorite-Mn 46.87 46.87 0.00 0.000 -0.24265E-10 67 diopside 16.18 16.18 0.00 0.000 -0.60662E-11 68 hedenbergite 14.21 14.21 0.00 0.000 -0.60662E-11 116 microcline -2.49 -2.49 0.00 0.000 -0.10616E-10 163 stilbite -7.52 -7.52 0.00 0.000 -0.90992E-11 164 stilpnomelane-Fe 13.02 13.02 0.00 0.000 -0.27298E-10 245 tr.625ac.25prg.125 45.16 45.16 0.00 0.000 -0.24265E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -16.38 -9.72 -3.239 0.16594E+05 -8.019 3 CH4,gas 4.54 1.55 -2.99 -0.748 0.51070E+04 -1.292 4 H2,gas 8.00 4.48 -3.52 -2.010 0.60051E+04 -1.818 5 H2S,gas -6.23 -14.35 -8.12 -4.060 0.13864E+05 -6.420 6 S2,gas -7.34 -37.66 -30.33 -4.666 0.51787E+05 -28.630 7 CO,gas 3.21 -11.90 -15.11 -4.649 0.25801E+05 -13.412 8 SO3,gas 17.12 -32.28 -49.40 -12.351 0.84353E+05 -47.703 9 SO2,gas 0.83 -27.80 -28.63 -7.635 0.48885E+05 -26.931 10 HCl,gas 5.19 -13.62 -18.81 -9.404 0.32114E+05 -17.109 11 acmite 7.71 6.53 -1.18 -0.123 0.20175E+04 15 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 19 spessartine 24.46 19.73 -4.73 -0.236 0.80702E+04 20 analcite 3.32 2.77 -0.55 -0.061 0.93625E+03 26 annite 20.12 17.72 -2.40 -0.134 0.41064E+04 27 phlogopite 27.06 25.40 -1.67 -0.093 0.28489E+04 29 anorthite 12.71 8.26 -4.45 -0.342 0.75903E+04 35 aragonite 0.97 -3.28 -4.24 -1.414 0.72452E+04 36 brucite 12.57 9.29 -3.27 -0.655 0.55909E+04 37 calcite 0.81 -3.28 -4.09 -1.363 0.69810E+04 38 carnegieite-low 9.02 5.93 -3.09 -0.442 0.52801E+04 39 carnegieite-high 10.09 5.93 -4.16 -0.595 0.71071E+04 40 carpholite-Mg 8.58 4.46 -4.12 -0.275 0.70429E+04 41 carpholite-Fe 6.71 1.90 -4.81 -0.321 0.82207E+04 42 celadonite 5.34 3.65 -1.69 -0.099 0.28879E+04 43 celadonite-Fe 3.88 1.09 -2.79 -0.164 0.47561E+04 44 chrysotile 23.89 21.57 -2.32 -0.194 0.39692E+04 49 chlorite-Al-free 47.17 43.14 -4.04 -0.168 0.68936E+04 51 chloritoid-Fe 9.17 5.06 -4.12 -0.275 0.70316E+04 52 chloritoid-Mn 11.40 7.56 -3.84 -0.256 0.65547E+04 54 coesite -2.38 -3.16 -0.78 -0.260 0.13341E+04 61 cristobalite -2.56 -3.16 -0.60 -0.199 0.10195E+04 63 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71234E+04 65 diaspore 2.87 0.74 -2.13 -0.356 0.36450E+04 66 diamond -3.10 -7.41 -4.31 -1.232 0.73601E+04 71 enstatite 17.26 12.27 -4.99 -0.499 0.85226E+04 73 clinoenstatite 17.17 12.27 -4.89 -0.489 0.83541E+04 75 epidote 24.67 22.70 -1.97 -0.095 0.33585E+04 76 clinozoisite 22.81 18.95 -3.86 -0.175 0.65869E+04 77 epidote-Fe 29.84 26.46 -3.38 -0.176 0.57768E+04 78 fayalite 14.05 10.31 -3.73 -0.533 0.63743E+04 79 ferrosilite 11.15 7.16 -3.99 -0.399 0.68202E+04 83 gibbsite 4.08 0.74 -3.34 -0.477 0.57035E+04 84 glaucophane 22.97 20.80 -2.17 -0.059 0.37134E+04 85 glaucophane-Fe 17.28 13.12 -4.15 -0.112 0.70919E+04 86 graphite -3.55 -7.41 -3.87 -1.105 0.66024E+04 87 greenalite 16.14 13.89 -2.25 -0.187 0.38408E+04 90 hematite 12.57 8.99 -3.58 -0.434 0.61111E+04 91 heulandite -5.83 -7.52 -1.69 -0.077 0.28938E+04 95 jadeite 4.22 2.77 -1.44 -0.144 0.24617E+04 97 kalsilite 7.58 3.83 -3.76 -0.537 0.64126E+04 98 kaolinite -1.33 -4.84 -3.50 -0.319 0.59832E+04 101 laumontite 2.88 1.95 -0.93 -0.062 0.15935E+04 102 lawsonite 9.62 8.26 -1.35 -0.090 0.23070E+04 103 leucite 4.12 0.67 -3.45 -0.345 0.58873E+04 105 lizardite 23.24 21.57 -1.68 -0.140 0.28618E+04 107 magnetite 20.09 15.72 -4.37 -0.356 0.74536E+04 108 minnesotaite 10.39 7.58 -2.81 -0.165 0.48028E+04 112 manganosite 14.06 9.24 -4.82 -1.204 0.82238E+04 120 muscovite 2.58 -1.01 -3.59 -0.211 0.61315E+04 121 paragonite 4.24 1.09 -3.15 -0.185 0.53706E+04 122 nepheline 8.34 5.93 -2.41 -0.344 0.41125E+04 128 periclase-Fe 11.63 6.73 -4.89 -1.223 0.83523E+04 134 phlogopite-Na 29.65 27.50 -2.15 -0.119 0.36678E+04 136 prehnite 19.37 18.21 -1.16 -0.068 0.19849E+04 137 prehnite-Fe 22.50 21.96 -0.53 -0.032 0.91159E+03 138 pumpellyite-Fe 46.27 43.89 -2.38 -0.053 0.40582E+04 139 pumpellyite-Mg 48.99 46.45 -2.54 -0.057 0.43420E+04 143 pyrrhotite -4.26 -7.61 -3.35 -1.118 0.57274E+04 144 pyrrhotiteFe0.875 -6.02 -9.01 -3.00 -1.102 0.51146E+04 145 pyroxmangite 7.40 6.08 -1.31 -0.263 0.22442E+04 146 pyrophyllite -6.18 -11.15 -4.98 -0.311 0.84962E+04 147 quartz -2.99 -3.16 -0.17 -0.056 0.28680E+03 152 rhodonite 7.45 6.08 -1.36 -0.272 0.23245E+04 153 sanidine -1.28 -2.49 -1.21 -0.093 0.20677E+04 165 stilpnomelane-Mg 27.44 25.81 -1.63 -0.049 0.27804E+04 171 talc 16.49 15.25 -1.24 -0.073 0.21140E+04 174 tephroite 18.09 15.33 -2.76 -0.394 0.47121E+04 178 tridymite -2.63 -3.16 -0.53 -0.177 0.90677E+03 179 tremolite 47.87 47.42 -0.45 -0.012 0.77494E+03 180 ferroactinolite 38.45 34.62 -3.83 -0.104 0.65448E+04 181 troilite-low -4.41 -7.61 -3.20 -1.068 0.54702E+04 183 vesuvianite 223.47 218.82 -4.65 -0.036 0.79440E+04 187 wairakite 3.95 1.95 -2.00 -0.118 0.34155E+04 188 walstromite 11.51 9.94 -1.56 -0.313 0.26719E+04 189 wollastonite 10.46 9.94 -0.52 -0.103 0.88229E+03 190 pseudo-wollastonite 11.00 9.94 -1.06 -0.211 0.18021E+04 191 zoisite 22.85 18.95 -3.90 -0.177 0.66609E+04 192 akaganeite 7.75 4.49 -3.26 -0.705 0.55681E+04 199 chalcedony -2.80 -3.16 -0.35 -0.118 0.60610E+03 201 montmorillonite-Ca -2.29 -6.17 -3.88 -0.240 0.66180E+04 202 montmorillonite-K -2.24 -6.27 -4.03 -0.247 0.68816E+04 203 montmorillonite-Mg -2.48 -6.79 -4.32 -0.267 0.73678E+04 204 montmorillonite-Na -2.04 -5.57 -3.54 -0.216 0.60365E+04 205 nontronite-Ca 3.21 -0.19 -3.41 -0.221 0.58215E+04 206 nontronite-H 2.53 -2.36 -4.89 -0.328 0.83485E+04 207 nontronite-K 3.34 -0.30 -3.64 -0.233 0.62083E+04 208 nontronite-Mg 3.07 -0.82 -3.90 -0.253 0.66553E+04 209 nontronite-Na 3.52 0.40 -3.12 -0.200 0.53292E+04 224 tobermorite 9.82 7.76 -2.07 -0.564 0.35287E+04 230 alabandite -0.98 -5.11 -4.13 -1.377 0.70518E+04 233 boehmite 4.41 0.74 -3.67 -0.611 0.62619E+04 235 ferrous-oxide 9.81 6.73 -3.08 -0.769 0.52532E+04 240 silica-amorphous -2.09 -3.16 -1.07 -0.355 0.18203E+04 242 an20ab80 2.02 1.35 -0.67 -0.052 0.11472E+04 243 an25ab75 2.65 1.78 -0.87 -0.067 0.14810E+04 244 an30ab70 3.28 2.21 -1.07 -0.082 0.18244E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 100.0000000 g Current total amount of reactant added: 6399.9990000 g New total amount of reactant added: 6499.9990000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.5222E-10 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 12 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 6499.9990000 Water: Moles liquid = 0.1919E+02 kg liquid = 0.3457E+00 Moles total = -.2597E+02 kg total = -.4679E+00 Activity = 1.0000 Stoichiometric ionic strength = .1153400E-01 Osmotic coef. = 0.9682 True ionic strength = .2017685E-01 Chg. balance for total moles = 0.5222E-10 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.88985E-10 -10.0507 0.74733E-10 -10.1265 0.83984E+00 -0.0758 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.39728E-03 -3.4009 0.33163E-03 -3.4793 0.83476E+00 -0.0784 4 SO4-- 0.18627E-11 -11.7298 0.96535E-12 -12.0153 0.51824E+00 -0.2855 5 HCO3- 0.68895E-06 -6.1618 0.57595E-06 -6.2396 0.83598E+00 -0.0778 6 HS- 0.73763E-04 -4.1322 0.61583E-04 -4.2105 0.83488E+00 -0.0784 7 Al+++ 0.99514E-29 -29.0021 0.22883E-29 -29.6405 0.22994E+00 -0.6384 8 H4SiO4 0.69598E-03 -3.1574 0.69598E-03 -3.1574 0.10000E+01 0.0000 9 Ca++ 0.13726E-06 -6.8625 0.70608E-07 -7.1511 0.51441E+00 -0.2887 10 Mg++ 0.21474E-10 -10.6681 0.10996E-10 -10.9588 0.51204E+00 -0.2907 11 Fe++ 0.59186E-13 -13.2278 0.30339E-13 -13.5180 0.51261E+00 -0.2902 12 K+ 0.15774E-03 -3.8020 0.13190E-03 -3.8797 0.83618E+00 -0.0777 13 Na+ 0.20017E-01 -1.6986 0.16706E-01 -1.7771 0.83460E+00 -0.0785 14 Mn++ 0.18995E-10 -10.7214 0.97449E-11 -11.0112 0.51303E+00 -0.2899 15 HPO4-- 0.44755E-07 -7.3492 0.23197E-07 -7.6346 0.51831E+00 -0.2854 16 HSiO3- 0.10417E-01 -1.9822 0.86958E-02 -2.0607 0.83476E+00 -0.0784 17 Ca(HSiO3)+ 0.16719E-07 -7.7768 0.13983E-07 -7.8544 0.83636E+00 -0.0776 18 Mg(HSiO3)+ 0.32402E-11 -11.4894 0.27100E-11 -11.5670 0.83636E+00 -0.0776 19 NaHSiO3,aq 0.23496E-02 -2.6290 0.23496E-02 -2.6290 0.10000E+01 0.0000 20 AlO+ 0.66644E-16 -16.1762 0.55738E-16 -16.2538 0.83636E+00 -0.0776 22 HAlO2,aq 0.14853E-09 -9.8282 0.14853E-09 -9.8282 0.10000E+01 0.0000 23 AlO2- 0.52799E-05 -5.2774 0.43995E-05 -5.3566 0.83324E+00 -0.0792 24 CH4,aq 0.35816E-04 -4.4459 0.35691E-04 -4.4474 0.99648E+00 -0.0015 25 C2H6,aq 0.18868E-13 -13.7243 0.18801E-13 -13.7258 0.99648E+00 -0.0015 29 CO,aq 0.26760E-16 -16.5725 0.26760E-16 -16.5725 0.10000E+01 0.0000 30 CO2,aq 0.92297E-10 -10.0348 0.91972E-10 -10.0363 0.99648E+00 -0.0015 31 CO3-2 0.13017E-05 -5.8855 0.67315E-06 -6.1719 0.51713E+00 -0.2864 32 CaCO3,aq 0.59598E-09 -9.2248 0.59598E-09 -9.2248 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.12412E-11 -11.9062 0.10381E-11 -11.9838 0.83636E+00 -0.0776 34 CaCl+ 0.45309E-10 -10.3438 0.37895E-10 -10.4214 0.83636E+00 -0.0776 35 CaCl2,aq 0.29857E-14 -14.5250 0.29857E-14 -14.5250 0.10000E+01 0.0000 36 CaOH+ 0.80510E-07 -7.0942 0.67335E-07 -7.1718 0.83636E+00 -0.0776 37 CaSO4,aq 0.21644E-16 -16.6647 0.21644E-16 -16.6647 0.10000E+01 0.0000 38 HCl,aq 0.45416E-14 -14.3428 0.45416E-14 -14.3428 0.10000E+01 0.0000 43 FeCl+ 0.19042E-16 -16.7203 0.15926E-16 -16.7979 0.83636E+00 -0.0776 46 FeO,aq 0.21113E-09 -9.6755 0.21113E-09 -9.6755 0.10000E+01 0.0000 47 FeOH+ 0.15800E-10 -10.8013 0.13215E-10 -10.8789 0.83636E+00 -0.0776 48 HFeO2- 0.35410E-07 -7.4509 0.29559E-07 -7.5293 0.83476E+00 -0.0784 49 FeO+ 0.11073E-16 -16.9557 0.92615E-17 -17.0333 0.83636E+00 -0.0776 51 FeO2- 0.40648E-09 -9.3910 0.33931E-09 -9.4694 0.83476E+00 -0.0784 52 HFeO2,aq 0.32251E-11 -11.4915 0.32251E-11 -11.4915 0.10000E+01 0.0000 53 H2,aq 0.11623E-04 -4.9347 0.11582E-04 -4.9362 0.99648E+00 -0.0015 54 KCl,aq 0.79282E-09 -9.1008 0.79282E-09 -9.1008 0.10000E+01 0.0000 56 KOH,aq 0.75375E-06 -6.1228 0.75375E-06 -6.1228 0.10000E+01 0.0000 57 KSO4- 0.23670E-14 -14.6258 0.19759E-14 -14.7042 0.83476E+00 -0.0784 58 MgCO3,aq 0.23263E-13 -13.6333 0.23263E-13 -13.6333 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.19750E-15 -15.7044 0.16518E-15 -15.7820 0.83636E+00 -0.0776 60 MgCl+ 0.63950E-14 -14.1942 0.53485E-14 -14.2718 0.83636E+00 -0.0776 61 MgOH+ 0.69376E-10 -10.1588 0.58024E-10 -10.2364 0.83636E+00 -0.0776 63 MnO,aq 0.18069E-08 -8.7431 0.18069E-08 -8.7431 0.10000E+01 0.0000 64 MnOH+ 0.47144E-09 -9.3266 0.39430E-09 -9.4042 0.83636E+00 -0.0776 65 MnO2-2 0.20763E-10 -10.6827 0.10737E-10 -10.9691 0.51713E+00 -0.2864 66 HMnO2- 0.21059E-09 -9.6766 0.17580E-09 -9.7550 0.83476E+00 -0.0784 69 MnCl+ 0.23794E-13 -13.6235 0.19901E-13 -13.7011 0.83636E+00 -0.0776 71 NaCl,aq 0.18361E-05 -5.7361 0.18361E-05 -5.7361 0.10000E+01 0.0000 72 NaOH,aq 0.96047E-04 -4.0175 0.96047E-04 -4.0175 0.10000E+01 0.0000 74 OH- 0.92784E-02 -2.0325 0.77311E-02 -2.1118 0.83324E+00 -0.0792 79 HPO3-2 0.16191E-14 -14.7907 0.83729E-15 -15.0771 0.51713E+00 -0.2864 81 H2PO3- 0.15032E-18 -18.8230 0.12548E-18 -18.9014 0.83476E+00 -0.0784 82 H3PO4,aq 0.90611E-18 -18.0428 0.90611E-18 -18.0428 0.10000E+01 0.0000 83 H2PO4- 0.38274E-10 -10.4171 0.31980E-10 -10.4951 0.83555E+00 -0.0780 84 PO4-3 0.10483E-08 -8.9795 0.25325E-09 -9.5965 0.24158E+00 -0.6169 88 HP2O7-3 0.93085E-18 -18.0311 0.21426E-18 -18.6691 0.23018E+00 -0.6379 89 P2O7-4 0.89558E-17 -17.0479 0.68491E-18 -18.1644 0.76477E-01 -1.1165 90 H2S,aq 0.14274E-07 -7.8454 0.14224E-07 -7.8470 0.99648E+00 -0.0015 91 S2-2 0.14030E-13 -13.8529 0.72553E-14 -14.1393 0.51713E+00 -0.2864 97 SO3-2 0.27694E-17 -17.5576 0.14530E-17 -17.8377 0.52466E+00 -0.2801 99 HSO4- 0.83047E-19 -19.0807 0.69526E-19 -19.1579 0.83718E+00 -0.0772 Charge balance for all species = 0.1511E-09 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.8898542E-10 -.2216759E-01 -.2230460E+02 0.0000 2 H2O 0.1000000E+01 0.5550492E+02 0.9981922E+06 0.0000 3 Cl- 0.3972835E-03 0.3991204E-03 0.1412532E+02 6.6471 4 SO4-- 0.1862747E-11 -.3872225E-04 -.3713228E+01 8.2377 5 HCO3- 0.6889486E-06 0.3780783E-04 0.2302901E+01 3.8869 6 HS- 0.7376297E-04 0.1124995E-03 0.3714088E+01 5.9159 7 Al+++ 0.9951418E-29 0.5280088E-05 0.1422160E+00 0.7390 8 H4SiO4 0.6959825E-03 0.1346286E-01 0.1291729E+04 -3.1574 9 Ca++ 0.1372605E-06 0.2351315E-06 0.9407151E-02 13.1018 10 Mg++ 0.2147401E-10 0.9411933E-10 0.2284235E-05 9.2942 11 Fe++ 0.5918604E-13 0.3604680E-07 0.2009591E-02 6.7350 12 K+ 0.1577448E-03 0.1584993E-03 0.6186822E+01 6.2467 13 Na+ 0.2001725E-01 0.2246478E-01 0.5155593E+03 8.3494 14 Mn++ 0.1899457E-10 0.2528745E-08 0.1386817E-03 9.2417 15 HPO4-- 0.4475486E-07 0.4584144E-07 0.4392135E-02 12.6184 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.1076303E+03 -.7663240E-02 -.1076227E+03 0.0000000E+00 2 H2O -.2597190E+02 0.1918781E+02 -.4515971E+02 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.1801626E+00 -.1338611E-04 0.1801760E+00 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.1801371E+00 0.3889058E-04 -.1801760E+00 0.0000000E+00 7 Al+++ 0.2119482E+02 0.1825303E-05 0.2119482E+02 0.0000000E+00 8 H4SiO4 0.6768308E+02 0.4654052E-02 0.6767842E+02 0.0000000E+00 9 Ca++ 0.7475941E+01 0.8128393E-07 0.7475940E+01 0.0000000E+00 10 Mg++ 0.5158729E+01 0.3253664E-10 0.5158729E+01 0.0000000E+00 11 Fe++ 0.4634555E+01 0.1246122E-07 0.4634555E+01 0.0000000E+00 12 K+ 0.1380042E+01 0.5479252E-04 0.1379987E+01 0.0000000E+00 13 Na+ 0.8159242E+01 0.7765977E-02 0.8151476E+01 0.0000000E+00 14 Mn++ 0.1127009E+00 0.8741761E-09 0.1127009E+00 0.0000000E+00 15 HPO4-- 0.3846424E-01 0.1584718E-07 0.3846423E-01 0.0000000E+00 Chg. balance for solid moles: 0.6412E-14 Mass of aqueous solution: 0.346300E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 6499.9990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 8.145 0.911 2136. 3.330 30.08 819.8 andradite 0.7207 -0.142 366.2 2.564 5.158 95.15 grossular 0.1745 -0.758 78.61 1.895 1.107 21.87 apatite-OH 0.1282E-01 -1.892 6.440 0.809 0.9070E-01 2.047 clinochlore 0.9230 -0.035 513.0 2.710 7.225 195.1 daphnite 0.2672 -0.573 190.7 2.280 2.685 57.77 chlorite-Mn 0.2254E-01 -1.647 15.98 1.204 0.2250 5.093 diopside 0.3443 -0.463 74.56 1.872 1.050 22.79 hedenbergite 0.8928E-01 -1.049 22.15 1.345 0.3119 6.067 microcline 1.210 0.083 336.8 2.527 4.743 131.6 stilbite 4.183 0.621 2948. 3.469 41.51 1375. stilpnomelane-Fe 0.3398 -0.469 366.3 2.564 5.159 126.5 tr.625ac.25prg.125 0.5499E-01 -1.260 47.00 1.672 0.6619 15.13 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8051E+00 0.8051E+00 1.0000 -0.094 grossular 0.1949E+00 0.1949E+00 1.0000 -0.710 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.7611E+00 0.7611E+00 1.0000 -0.119 daphnite 0.2203E+00 0.2203E+00 1.0000 -0.657 chlorite-Mn 0.1859E-01 0.1859E-01 1.0000 -1.731 diopside 0.7941E+00 0.7941E+00 1.0000 -0.100 hedenbergite 0.2059E+00 0.2059E+00 1.0000 -0.686 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 tr.625ac.25prg.125 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 7101.097826 g Volume = 2873.823817 cm3 Porosity: -10.4892% V(tot) - V(min): -.27282E+03 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 6499.9990000 g log = 3.8129 Original solution: 1000.0103000 g Original solution / Rock added: 0.15 (Water/Rock Ratio), log = -0.8129 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0883 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9383E+00 0.9851 0.1006E+01 0.1021E+01 CO2,gas 0.8983E-08 1.0065 0.9840E-08 0.9777E-08 CH4,gas 0.4770E-01 1.0120 0.5253E-01 0.5191E-01 H2,gas 0.1396E-01 1.0006 0.1521E-01 0.1520E-01 H2S,gas 0.3608E-06 0.9958 0.3910E-06 0.3927E-06 S2,gas 0.2280E-28 1.0000 0.2482E-28 0.2482E-28 CO,gas 0.3664E-13 1.0000 0.3988E-13 0.3988E-13 SO3,gas 0.1873E-47 1.0000 0.2039E-47 0.2039E-47 SO2,gas 0.1108E-26 1.0000 0.1206E-26 0.1206E-26 HCl,gas 0.7363E-17 1.0000 0.8014E-17 0.8014E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 16 albite -0.38 -0.38 0.00 0.000 -0.94784E-12 22 andradite 39.01 39.01 0.00 0.000 0.12132E-10 23 grossular 32.73 32.73 0.00 0.000 -0.24265E-10 32 apatite-OH -18.15 -18.15 0.00 0.000 -0.60662E-11 46 clinochlore 39.07 39.07 0.00 0.000 0.24265E-10 47 daphnite 28.97 28.97 0.00 0.000 0.24265E-10 48 chlorite-Mn 46.87 46.87 0.00 0.000 0.24265E-10 67 diopside 16.18 16.18 0.00 0.000 -0.60662E-11 68 hedenbergite 14.21 14.21 0.00 0.000 -0.30331E-11 116 microcline -2.49 -2.49 0.00 0.000 0.15165E-11 163 stilbite -7.52 -7.52 0.00 0.000 0.15165E-10 164 stilpnomelane-Fe 13.02 13.02 0.00 0.000 0.69761E-10 245 tr.625ac.25prg.125 45.16 45.16 0.00 0.000 0.24265E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -16.37 -9.71 -3.235 0.16573E+05 -8.007 3 CH4,gas 4.54 1.57 -2.98 -0.745 0.50858E+04 -1.280 4 H2,gas 8.00 4.48 -3.52 -2.010 0.60051E+04 -1.818 5 H2S,gas -6.23 -14.34 -8.11 -4.053 0.13842E+05 -6.408 6 S2,gas -7.34 -37.64 -30.30 -4.662 0.51744E+05 -28.605 7 CO,gas 3.21 -11.88 -15.10 -4.646 0.25780E+05 -13.399 8 SO3,gas 17.12 -32.27 -49.39 -12.347 0.84331E+05 -47.691 9 SO2,gas 0.83 -27.79 -28.62 -7.631 0.48864E+05 -26.919 10 HCl,gas 5.19 -13.61 -18.80 -9.398 0.32092E+05 -17.096 11 acmite 7.71 6.53 -1.18 -0.123 0.20175E+04 15 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 19 spessartine 24.46 19.73 -4.73 -0.236 0.80701E+04 20 analcite 3.32 2.77 -0.55 -0.061 0.93625E+03 26 annite 20.12 17.72 -2.40 -0.134 0.41064E+04 27 phlogopite 27.06 25.40 -1.67 -0.093 0.28489E+04 29 anorthite 12.71 8.26 -4.45 -0.342 0.75903E+04 35 aragonite 0.97 -3.26 -4.23 -1.410 0.72240E+04 36 brucite 12.57 9.29 -3.27 -0.655 0.55909E+04 37 calcite 0.81 -3.26 -4.08 -1.359 0.69597E+04 38 carnegieite-low 9.02 5.93 -3.09 -0.442 0.52801E+04 39 carnegieite-high 10.09 5.93 -4.16 -0.595 0.71071E+04 40 carpholite-Mg 8.58 4.46 -4.12 -0.275 0.70429E+04 41 carpholite-Fe 6.71 1.90 -4.81 -0.321 0.82207E+04 42 celadonite 5.34 3.65 -1.69 -0.099 0.28879E+04 43 celadonite-Fe 3.88 1.09 -2.79 -0.164 0.47561E+04 44 chrysotile 23.89 21.57 -2.32 -0.194 0.39692E+04 49 chlorite-Al-free 47.17 43.14 -4.04 -0.168 0.68936E+04 51 chloritoid-Fe 9.17 5.06 -4.12 -0.275 0.70316E+04 52 chloritoid-Mn 11.40 7.56 -3.84 -0.256 0.65546E+04 54 coesite -2.38 -3.16 -0.78 -0.260 0.13341E+04 61 cristobalite -2.56 -3.16 -0.60 -0.199 0.10195E+04 63 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71234E+04 65 diaspore 2.87 0.74 -2.13 -0.356 0.36450E+04 66 diamond -3.10 -7.40 -4.30 -1.228 0.73389E+04 71 enstatite 17.26 12.27 -4.99 -0.499 0.85226E+04 73 clinoenstatite 17.17 12.27 -4.89 -0.489 0.83541E+04 75 epidote 24.67 22.70 -1.97 -0.095 0.33585E+04 76 clinozoisite 22.81 18.95 -3.86 -0.175 0.65869E+04 77 epidote-Fe 29.84 26.46 -3.38 -0.176 0.57768E+04 78 fayalite 14.05 10.31 -3.73 -0.533 0.63743E+04 79 ferrosilite 11.15 7.16 -3.99 -0.399 0.68202E+04 83 gibbsite 4.08 0.74 -3.34 -0.477 0.57035E+04 84 glaucophane 22.97 20.80 -2.17 -0.059 0.37134E+04 85 glaucophane-Fe 17.28 13.12 -4.15 -0.112 0.70919E+04 86 graphite -3.55 -7.40 -3.85 -1.101 0.65811E+04 87 greenalite 16.14 13.89 -2.25 -0.187 0.38408E+04 90 hematite 12.57 8.99 -3.58 -0.434 0.61111E+04 91 heulandite -5.83 -7.52 -1.69 -0.077 0.28938E+04 95 jadeite 4.22 2.77 -1.44 -0.144 0.24617E+04 97 kalsilite 7.58 3.83 -3.76 -0.537 0.64126E+04 98 kaolinite -1.33 -4.84 -3.50 -0.319 0.59832E+04 101 laumontite 2.88 1.95 -0.93 -0.062 0.15935E+04 102 lawsonite 9.62 8.26 -1.35 -0.090 0.23070E+04 103 leucite 4.12 0.67 -3.45 -0.345 0.58873E+04 105 lizardite 23.24 21.57 -1.68 -0.140 0.28619E+04 107 magnetite 20.09 15.72 -4.37 -0.356 0.74536E+04 108 minnesotaite 10.39 7.58 -2.81 -0.165 0.48027E+04 112 manganosite 14.06 9.24 -4.82 -1.204 0.82238E+04 120 muscovite 2.58 -1.01 -3.59 -0.211 0.61315E+04 121 paragonite 4.24 1.09 -3.15 -0.185 0.53706E+04 122 nepheline 8.34 5.93 -2.41 -0.344 0.41125E+04 128 periclase-Fe 11.63 6.73 -4.89 -1.223 0.83523E+04 134 phlogopite-Na 29.65 27.50 -2.15 -0.119 0.36678E+04 136 prehnite 19.37 18.21 -1.16 -0.068 0.19849E+04 137 prehnite-Fe 22.50 21.96 -0.53 -0.032 0.91159E+03 138 pumpellyite-Fe 46.27 43.89 -2.38 -0.053 0.40582E+04 139 pumpellyite-Mg 48.99 46.45 -2.54 -0.057 0.43420E+04 143 pyrrhotite -4.26 -7.60 -3.34 -1.114 0.57059E+04 144 pyrrhotiteFe0.875 -6.02 -9.00 -2.98 -1.097 0.50931E+04 145 pyroxmangite 7.40 6.08 -1.31 -0.263 0.22442E+04 146 pyrophyllite -6.18 -11.15 -4.98 -0.311 0.84962E+04 147 quartz -2.99 -3.16 -0.17 -0.056 0.28680E+03 152 rhodonite 7.45 6.08 -1.36 -0.272 0.23244E+04 153 sanidine -1.28 -2.49 -1.21 -0.093 0.20677E+04 165 stilpnomelane-Mg 27.44 25.81 -1.63 -0.049 0.27804E+04 171 talc 16.49 15.25 -1.24 -0.073 0.21140E+04 174 tephroite 18.09 15.33 -2.76 -0.394 0.47121E+04 178 tridymite -2.63 -3.16 -0.53 -0.177 0.90677E+03 179 tremolite 47.87 47.42 -0.45 -0.012 0.77494E+03 180 ferroactinolite 38.45 34.62 -3.83 -0.104 0.65448E+04 181 troilite-low -4.41 -7.60 -3.19 -1.064 0.54487E+04 183 vesuvianite 223.47 218.82 -4.65 -0.036 0.79440E+04 187 wairakite 3.95 1.95 -2.00 -0.118 0.34155E+04 188 walstromite 11.51 9.94 -1.56 -0.313 0.26719E+04 189 wollastonite 10.46 9.94 -0.52 -0.103 0.88229E+03 190 pseudo-wollastonite 11.00 9.94 -1.06 -0.211 0.18021E+04 191 zoisite 22.85 18.95 -3.90 -0.177 0.66609E+04 192 akaganeite 7.75 4.49 -3.26 -0.705 0.55681E+04 199 chalcedony -2.80 -3.16 -0.35 -0.118 0.60609E+03 201 montmorillonite-Ca -2.29 -6.17 -3.88 -0.240 0.66180E+04 202 montmorillonite-K -2.24 -6.27 -4.03 -0.247 0.68816E+04 203 montmorillonite-Mg -2.48 -6.79 -4.32 -0.267 0.73678E+04 204 montmorillonite-Na -2.04 -5.57 -3.54 -0.216 0.60365E+04 205 nontronite-Ca 3.21 -0.19 -3.41 -0.221 0.58215E+04 206 nontronite-H 2.53 -2.36 -4.89 -0.328 0.83485E+04 207 nontronite-K 3.34 -0.30 -3.64 -0.233 0.62083E+04 208 nontronite-Mg 3.07 -0.82 -3.90 -0.253 0.66553E+04 209 nontronite-Na 3.52 0.40 -3.12 -0.200 0.53292E+04 224 tobermorite 9.82 7.76 -2.07 -0.564 0.35287E+04 230 alabandite -0.98 -5.10 -4.12 -1.372 0.70304E+04 233 boehmite 4.41 0.74 -3.67 -0.611 0.62619E+04 235 ferrous-oxide 9.81 6.73 -3.08 -0.769 0.52532E+04 240 silica-amorphous -2.09 -3.16 -1.07 -0.355 0.18203E+04 242 an20ab80 2.02 1.35 -0.67 -0.052 0.11472E+04 243 an25ab75 2.65 1.78 -0.87 -0.067 0.14810E+04 244 an30ab70 3.28 2.21 -1.07 -0.082 0.18244E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 100.0000000 g Current total amount of reactant added: 6499.9990000 g New total amount of reactant added: 6599.9990000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.5221E-10 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 12 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 6599.9990000 Water: Moles liquid = 0.1863E+02 kg liquid = 0.3357E+00 Moles total = -.2723E+02 kg total = -.4905E+00 Activity = 1.0000 Stoichiometric ionic strength = .1154390E-01 Osmotic coef. = 0.9681 True ionic strength = .2018459E-01 Chg. balance for total moles = 0.5221E-10 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.89019E-10 -10.0505 0.74760E-10 -10.1263 0.83982E+00 -0.0758 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.40917E-03 -3.3881 0.34155E-03 -3.4665 0.83473E+00 -0.0785 4 SO4-- 0.19179E-11 -11.7172 0.99385E-12 -12.0027 0.51819E+00 -0.2855 5 HCO3- 0.70935E-06 -6.1491 0.59299E-06 -6.2270 0.83596E+00 -0.0778 6 HS- 0.75970E-04 -4.1194 0.63424E-04 -4.1977 0.83486E+00 -0.0784 7 Al+++ 0.99643E-29 -29.0016 0.22907E-29 -29.6400 0.22989E+00 -0.6385 8 H4SiO4 0.69598E-03 -3.1574 0.69598E-03 -3.1574 0.10000E+01 0.0000 9 Ca++ 0.13737E-06 -6.8621 0.70658E-07 -7.1508 0.51436E+00 -0.2887 10 Mg++ 0.21492E-10 -10.6677 0.11003E-10 -10.9585 0.51199E+00 -0.2907 11 Fe++ 0.59234E-13 -13.2274 0.30361E-13 -13.5177 0.51255E+00 -0.2903 12 K+ 0.15780E-03 -3.8019 0.13195E-03 -3.8796 0.83616E+00 -0.0777 13 Na+ 0.20025E-01 -1.6984 0.16712E-01 -1.7770 0.83458E+00 -0.0785 14 Mn++ 0.19010E-10 -10.7210 0.97520E-11 -11.0109 0.51298E+00 -0.2899 15 HPO4-- 0.44728E-07 -7.3494 0.23180E-07 -7.6349 0.51826E+00 -0.2855 16 HSiO3- 0.10414E-01 -1.9824 0.86927E-02 -2.0608 0.83473E+00 -0.0785 17 Ca(HSiO3)+ 0.16725E-07 -7.7766 0.13988E-07 -7.8542 0.83634E+00 -0.0776 18 Mg(HSiO3)+ 0.32414E-11 -11.4893 0.27109E-11 -11.5669 0.83634E+00 -0.0776 19 NaHSiO3,aq 0.23496E-02 -2.6290 0.23496E-02 -2.6290 0.10000E+01 0.0000 20 AlO+ 0.66669E-16 -16.1761 0.55758E-16 -16.2537 0.83634E+00 -0.0776 22 HAlO2,aq 0.14853E-09 -9.8282 0.14853E-09 -9.8282 0.10000E+01 0.0000 23 AlO2- 0.52782E-05 -5.2775 0.43979E-05 -5.3568 0.83322E+00 -0.0792 24 CH4,aq 0.36889E-04 -4.4331 0.36759E-04 -4.4346 0.99648E+00 -0.0015 25 C2H6,aq 0.20015E-13 -13.6987 0.19944E-13 -13.7002 0.99648E+00 -0.0015 29 CO,aq 0.27562E-16 -16.5597 0.27562E-16 -16.5597 0.10000E+01 0.0000 30 CO2,aq 0.95061E-10 -10.0220 0.94726E-10 -10.0235 0.99648E+00 -0.0015 31 CO3-2 0.13399E-05 -5.8729 0.69282E-06 -6.1594 0.51708E+00 -0.2864 32 CaCO3,aq 0.61382E-09 -9.2120 0.61382E-09 -9.2120 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.12788E-11 -11.8932 0.10695E-11 -11.9708 0.83634E+00 -0.0776 34 CaCl+ 0.46697E-10 -10.3307 0.39055E-10 -10.4083 0.83634E+00 -0.0776 35 CaCl2,aq 0.31691E-14 -14.4991 0.31691E-14 -14.4991 0.10000E+01 0.0000 36 CaOH+ 0.80540E-07 -7.0940 0.67359E-07 -7.1716 0.83634E+00 -0.0776 37 CaSO4,aq 0.22299E-16 -16.6517 0.22299E-16 -16.6517 0.10000E+01 0.0000 38 HCl,aq 0.46790E-14 -14.3298 0.46790E-14 -14.3298 0.10000E+01 0.0000 43 FeCl+ 0.19625E-16 -16.7072 0.16413E-16 -16.7848 0.83634E+00 -0.0776 46 FeO,aq 0.21113E-09 -9.6755 0.21113E-09 -9.6755 0.10000E+01 0.0000 47 FeOH+ 0.15806E-10 -10.8012 0.13219E-10 -10.8788 0.83634E+00 -0.0776 48 HFeO2- 0.35398E-07 -7.4510 0.29548E-07 -7.5295 0.83473E+00 -0.0785 49 FeO+ 0.11078E-16 -16.9556 0.92648E-17 -17.0332 0.83634E+00 -0.0776 51 FeO2- 0.40635E-09 -9.3911 0.33919E-09 -9.4696 0.83473E+00 -0.0785 52 HFeO2,aq 0.32251E-11 -11.4915 0.32251E-11 -11.4915 0.10000E+01 0.0000 53 H2,aq 0.11623E-04 -4.9347 0.11582E-04 -4.9362 0.99648E+00 -0.0015 54 KCl,aq 0.81681E-09 -9.0879 0.81681E-09 -9.0879 0.10000E+01 0.0000 56 KOH,aq 0.75375E-06 -6.1228 0.75375E-06 -6.1228 0.10000E+01 0.0000 57 KSO4- 0.24379E-14 -14.6130 0.20350E-14 -14.6914 0.83473E+00 -0.0785 58 MgCO3,aq 0.23960E-13 -13.6205 0.23960E-13 -13.6205 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.20349E-15 -15.6915 0.17019E-15 -15.7691 0.83634E+00 -0.0776 60 MgCl+ 0.65910E-14 -14.1811 0.55123E-14 -14.2587 0.83634E+00 -0.0776 61 MgOH+ 0.69403E-10 -10.1586 0.58045E-10 -10.2362 0.83634E+00 -0.0776 63 MnO,aq 0.18070E-08 -8.7431 0.18070E-08 -8.7431 0.10000E+01 0.0000 64 MnOH+ 0.47163E-09 -9.3264 0.39445E-09 -9.4040 0.83634E+00 -0.0776 65 MnO2-2 0.20750E-10 -10.6830 0.10730E-10 -10.9694 0.51708E+00 -0.2864 66 HMnO2- 0.21053E-09 -9.6767 0.17574E-09 -9.7551 0.83473E+00 -0.0785 69 MnCl+ 0.24524E-13 -13.6104 0.20511E-13 -13.6880 0.83634E+00 -0.0776 71 NaCl,aq 0.18917E-05 -5.7232 0.18917E-05 -5.7232 0.10000E+01 0.0000 72 NaOH,aq 0.96047E-04 -4.0175 0.96047E-04 -4.0175 0.10000E+01 0.0000 74 OH- 0.92754E-02 -2.0327 0.77284E-02 -2.1119 0.83322E+00 -0.0792 79 HPO3-2 0.16181E-14 -14.7910 0.83669E-15 -15.0774 0.51708E+00 -0.2864 81 H2PO3- 0.15027E-18 -18.8231 0.12543E-18 -18.9016 0.83473E+00 -0.0785 82 H3PO4,aq 0.90611E-18 -18.0428 0.90611E-18 -18.0428 0.10000E+01 0.0000 83 H2PO4- 0.38261E-10 -10.4172 0.31969E-10 -10.4953 0.83553E+00 -0.0780 84 PO4-3 0.10474E-08 -8.9799 0.25298E-09 -9.5969 0.24153E+00 -0.6170 88 HP2O7-3 0.93007E-18 -18.0315 0.21403E-18 -18.6695 0.23012E+00 -0.6380 89 P2O7-4 0.89466E-17 -17.0483 0.68394E-18 -18.1650 0.76447E-01 -1.1166 90 H2S,aq 0.14706E-07 -7.8325 0.14654E-07 -7.8340 0.99648E+00 -0.0015 91 S2-2 0.14883E-13 -13.8273 0.76956E-14 -14.1138 0.51708E+00 -0.2864 97 SO3-2 0.28514E-17 -17.5449 0.14959E-17 -17.8251 0.52461E+00 -0.2802 99 HSO4- 0.85532E-19 -19.0679 0.71604E-19 -19.1451 0.83716E+00 -0.0772 Charge balance for all species = 0.1556E-09 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.8901921E-10 -.2216114E-01 -.2229810E+02 0.0000 2 H2O 0.1000000E+01 0.5550492E+02 0.9981919E+06 0.0000 3 Cl- 0.4091694E-03 0.4110620E-03 0.1454794E+02 6.6598 4 SO4-- 0.1917944E-11 -.3979487E-04 -.3816084E+01 8.2500 5 HCO3- 0.7093461E-06 0.3893902E-04 0.2371802E+01 3.8994 6 HS- 0.7596993E-04 0.1157795E-03 0.3822374E+01 5.9286 7 Al+++ 0.9964325E-29 0.5278345E-05 0.1421690E+00 0.7390 8 H4SiO4 0.6959827E-03 0.1345943E-01 0.1291400E+04 -3.1574 9 Ca++ 0.1373722E-06 0.2352996E-06 0.9413870E-02 13.1018 10 Mg++ 0.2149152E-10 0.9416486E-10 0.2285339E-05 9.2942 11 Fe++ 0.5923429E-13 0.3603498E-07 0.2008932E-02 6.7350 12 K+ 0.1578049E-03 0.1585594E-03 0.6189166E+01 6.2467 13 Na+ 0.2002489E-01 0.2247248E-01 0.5157357E+03 8.3494 14 Mn++ 0.1901045E-10 0.2528911E-08 0.1386907E-03 9.2418 15 HPO4-- 0.4472754E-07 0.4581321E-07 0.4389429E-02 12.6178 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.1092862E+03 -.7438452E-02 -.1092787E+03 0.0000000E+00 2 H2O -.2722545E+02 0.1863039E+02 -.4585584E+02 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.1829340E+00 -.1335727E-04 0.1829473E+00 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.1829085E+00 0.3886174E-04 -.1829473E+00 0.0000000E+00 7 Al+++ 0.2152089E+02 0.1771692E-05 0.2152089E+02 0.0000000E+00 8 H4SiO4 0.6872436E+02 0.4517697E-02 0.6871984E+02 0.0000000E+00 9 Ca++ 0.7590955E+01 0.7897900E-07 0.7590955E+01 0.0000000E+00 10 Mg++ 0.5238094E+01 0.3160672E-10 0.5238094E+01 0.0000000E+00 11 Fe++ 0.4705856E+01 0.1209525E-07 0.4705856E+01 0.0000000E+00 12 K+ 0.1401274E+01 0.5322095E-04 0.1401220E+01 0.0000000E+00 13 Na+ 0.8284767E+01 0.7542954E-02 0.8277224E+01 0.0000000E+00 14 Mn++ 0.1144347E+00 0.8488365E-09 0.1144347E+00 0.0000000E+00 15 HPO4-- 0.3905600E-01 0.1537734E-07 0.3905598E-01 0.0000000E+00 Chg. balance for solid moles: 0.2923E-13 Mass of aqueous solution: 0.336240E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 6599.9990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 8.270 0.918 2169. 3.336 30.08 832.5 andradite 0.7318 -0.136 371.9 2.570 5.158 96.62 grossular 0.1772 -0.752 79.82 1.902 1.107 22.21 apatite-OH 0.1302E-01 -1.885 6.540 0.816 0.9070E-01 2.078 clinochlore 0.9372 -0.028 520.9 2.717 7.225 198.1 daphnite 0.2713 -0.567 193.6 2.287 2.685 58.66 chlorite-Mn 0.2289E-01 -1.640 16.23 1.210 0.2250 5.171 diopside 0.3497 -0.456 75.73 1.879 1.050 23.15 hedenbergite 0.9069E-01 -1.042 22.50 1.352 0.3121 6.163 microcline 1.229 0.089 342.0 2.534 4.743 133.6 stilbite 4.247 0.628 2993. 3.476 41.51 1396. stilpnomelane-Fe 0.3450 -0.462 372.0 2.570 5.159 128.5 tr.625ac.25prg.125 0.5582E-01 -1.253 47.71 1.679 0.6617 15.36 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8051E+00 0.8051E+00 1.0000 -0.094 grossular 0.1949E+00 0.1949E+00 1.0000 -0.710 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.7611E+00 0.7611E+00 1.0000 -0.119 daphnite 0.2203E+00 0.2203E+00 1.0000 -0.657 chlorite-Mn 0.1859E-01 0.1859E-01 1.0000 -1.731 diopside 0.7941E+00 0.7941E+00 1.0000 -0.100 hedenbergite 0.2059E+00 0.2059E+00 1.0000 -0.686 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 tr.625ac.25prg.125 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 7210.348490 g Volume = 2918.026880 cm3 Porosity: -10.4895% V(tot) - V(min): -.27703E+03 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 6599.9990000 g log = 3.8195 Original solution: 1000.0103000 g Original solution / Rock added: 0.15 (Water/Rock Ratio), log = -0.8195 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0899 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9370E+00 0.9850 0.1006E+01 0.1021E+01 CO2,gas 0.9239E-08 1.0064 0.1013E-07 0.1007E-07 CH4,gas 0.4905E-01 1.0120 0.5411E-01 0.5346E-01 H2,gas 0.1394E-01 1.0006 0.1521E-01 0.1520E-01 H2S,gas 0.3712E-06 0.9958 0.4028E-06 0.4046E-06 S2,gas 0.2417E-28 1.0000 0.2634E-28 0.2634E-28 CO,gas 0.3768E-13 1.0000 0.4107E-13 0.4107E-13 SO3,gas 0.1927E-47 1.0000 0.2100E-47 0.2100E-47 SO2,gas 0.1140E-26 1.0000 0.1243E-26 0.1243E-26 HCl,gas 0.7575E-17 1.0000 0.8256E-17 0.8256E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 16 albite -0.38 -0.38 0.00 0.000 -0.13080E-10 22 andradite 39.01 39.01 0.00 0.000 -0.12132E-10 23 grossular 32.73 32.73 0.00 0.000 0.12132E-10 32 apatite-OH -18.15 -18.15 0.00 0.000 -0.60662E-11 46 clinochlore 39.07 39.07 0.00 0.000 -0.12132E-10 47 daphnite 28.97 28.97 0.00 0.000 -0.42463E-10 48 chlorite-Mn 46.87 46.87 0.00 0.000 -0.24265E-10 67 diopside 16.18 16.18 0.00 0.000 -0.60662E-11 68 hedenbergite 14.21 14.21 0.00 0.000 -0.60662E-11 116 microcline -2.49 -2.49 0.00 0.000 0.15165E-11 163 stilbite -7.52 -7.52 0.00 0.000 0.15165E-10 164 stilpnomelane-Fe 13.02 13.02 0.00 0.000 -0.75827E-10 245 tr.625ac.25prg.125 45.16 45.16 0.00 0.000 -0.36397E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -16.35 -9.69 -3.231 0.16551E+05 -7.994 3 CH4,gas 4.54 1.58 -2.97 -0.741 0.50639E+04 -1.267 4 H2,gas 8.00 4.48 -3.52 -2.010 0.60051E+04 -1.818 5 H2S,gas -6.23 -14.32 -8.09 -4.047 0.13820E+05 -6.395 6 S2,gas -7.34 -37.61 -30.28 -4.658 0.51699E+05 -28.579 7 CO,gas 3.21 -11.87 -15.09 -4.642 0.25758E+05 -13.386 8 SO3,gas 17.12 -32.26 -49.38 -12.344 0.84309E+05 -47.678 9 SO2,gas 0.83 -27.77 -28.60 -7.628 0.48842E+05 -26.906 10 HCl,gas 5.19 -13.59 -18.78 -9.391 0.32070E+05 -17.083 11 acmite 7.71 6.53 -1.18 -0.123 0.20175E+04 15 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 19 spessartine 24.46 19.73 -4.73 -0.236 0.80701E+04 20 analcite 3.32 2.77 -0.55 -0.061 0.93625E+03 26 annite 20.12 17.72 -2.40 -0.134 0.41064E+04 27 phlogopite 27.06 25.40 -1.67 -0.093 0.28489E+04 29 anorthite 12.71 8.26 -4.45 -0.342 0.75903E+04 35 aragonite 0.97 -3.25 -4.22 -1.406 0.72021E+04 36 brucite 12.57 9.29 -3.27 -0.655 0.55909E+04 37 calcite 0.81 -3.25 -4.06 -1.354 0.69379E+04 38 carnegieite-low 9.02 5.93 -3.09 -0.442 0.52801E+04 39 carnegieite-high 10.09 5.93 -4.16 -0.595 0.71071E+04 40 carpholite-Mg 8.58 4.46 -4.12 -0.275 0.70429E+04 41 carpholite-Fe 6.71 1.90 -4.81 -0.321 0.82207E+04 42 celadonite 5.34 3.65 -1.69 -0.099 0.28879E+04 43 celadonite-Fe 3.88 1.09 -2.79 -0.164 0.47561E+04 44 chrysotile 23.89 21.57 -2.32 -0.194 0.39692E+04 49 chlorite-Al-free 47.17 43.14 -4.04 -0.168 0.68936E+04 51 chloritoid-Fe 9.17 5.06 -4.12 -0.275 0.70316E+04 52 chloritoid-Mn 11.40 7.56 -3.84 -0.256 0.65546E+04 54 coesite -2.38 -3.16 -0.78 -0.260 0.13341E+04 61 cristobalite -2.56 -3.16 -0.60 -0.199 0.10195E+04 63 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71234E+04 65 diaspore 2.87 0.74 -2.13 -0.356 0.36450E+04 66 diamond -3.10 -7.39 -4.29 -1.224 0.73170E+04 71 enstatite 17.26 12.27 -4.99 -0.499 0.85226E+04 73 clinoenstatite 17.17 12.27 -4.89 -0.489 0.83541E+04 75 epidote 24.67 22.70 -1.97 -0.095 0.33585E+04 76 clinozoisite 22.81 18.95 -3.86 -0.175 0.65869E+04 77 epidote-Fe 29.84 26.46 -3.38 -0.176 0.57768E+04 78 fayalite 14.05 10.31 -3.73 -0.533 0.63743E+04 79 ferrosilite 11.15 7.16 -3.99 -0.399 0.68202E+04 83 gibbsite 4.08 0.74 -3.34 -0.477 0.57035E+04 84 glaucophane 22.97 20.80 -2.17 -0.059 0.37134E+04 85 glaucophane-Fe 17.28 13.12 -4.15 -0.112 0.70919E+04 86 graphite -3.55 -7.39 -3.84 -1.098 0.65592E+04 87 greenalite 16.14 13.89 -2.25 -0.187 0.38408E+04 90 hematite 12.57 8.99 -3.58 -0.434 0.61111E+04 91 heulandite -5.83 -7.52 -1.69 -0.077 0.28938E+04 95 jadeite 4.22 2.77 -1.44 -0.144 0.24617E+04 97 kalsilite 7.58 3.83 -3.76 -0.537 0.64126E+04 98 kaolinite -1.33 -4.84 -3.50 -0.319 0.59832E+04 101 laumontite 2.88 1.95 -0.93 -0.062 0.15935E+04 102 lawsonite 9.62 8.26 -1.35 -0.090 0.23070E+04 103 leucite 4.12 0.67 -3.45 -0.345 0.58873E+04 105 lizardite 23.24 21.57 -1.68 -0.140 0.28619E+04 107 magnetite 20.09 15.72 -4.37 -0.356 0.74536E+04 108 minnesotaite 10.39 7.58 -2.81 -0.165 0.48027E+04 112 manganosite 14.06 9.24 -4.82 -1.204 0.82238E+04 120 muscovite 2.58 -1.01 -3.59 -0.211 0.61315E+04 121 paragonite 4.24 1.09 -3.15 -0.185 0.53706E+04 122 nepheline 8.34 5.93 -2.41 -0.344 0.41125E+04 128 periclase-Fe 11.63 6.73 -4.89 -1.223 0.83523E+04 134 phlogopite-Na 29.65 27.50 -2.15 -0.119 0.36678E+04 136 prehnite 19.37 18.21 -1.16 -0.068 0.19849E+04 137 prehnite-Fe 22.50 21.96 -0.53 -0.032 0.91159E+03 138 pumpellyite-Fe 46.27 43.89 -2.38 -0.053 0.40582E+04 139 pumpellyite-Mg 48.99 46.45 -2.54 -0.057 0.43420E+04 143 pyrrhotite -4.26 -7.59 -3.33 -1.110 0.56838E+04 144 pyrrhotiteFe0.875 -6.02 -8.99 -2.97 -1.092 0.50710E+04 145 pyroxmangite 7.40 6.08 -1.31 -0.263 0.22442E+04 146 pyrophyllite -6.18 -11.15 -4.98 -0.311 0.84962E+04 147 quartz -2.99 -3.16 -0.17 -0.056 0.28680E+03 152 rhodonite 7.45 6.08 -1.36 -0.272 0.23244E+04 153 sanidine -1.28 -2.49 -1.21 -0.093 0.20677E+04 165 stilpnomelane-Mg 27.44 25.81 -1.63 -0.049 0.27804E+04 171 talc 16.49 15.25 -1.24 -0.073 0.21140E+04 174 tephroite 18.09 15.33 -2.76 -0.394 0.47121E+04 178 tridymite -2.63 -3.16 -0.53 -0.177 0.90677E+03 179 tremolite 47.87 47.42 -0.45 -0.012 0.77494E+03 180 ferroactinolite 38.45 34.62 -3.83 -0.104 0.65448E+04 181 troilite-low -4.41 -7.59 -3.18 -1.059 0.54266E+04 183 vesuvianite 223.47 218.82 -4.65 -0.036 0.79440E+04 187 wairakite 3.95 1.95 -2.00 -0.118 0.34155E+04 188 walstromite 11.51 9.94 -1.56 -0.313 0.26719E+04 189 wollastonite 10.46 9.94 -0.52 -0.103 0.88229E+03 190 pseudo-wollastonite 11.00 9.94 -1.06 -0.211 0.18021E+04 191 zoisite 22.85 18.95 -3.90 -0.177 0.66609E+04 192 akaganeite 7.75 4.49 -3.26 -0.705 0.55681E+04 199 chalcedony -2.80 -3.16 -0.35 -0.118 0.60609E+03 201 montmorillonite-Ca -2.29 -6.17 -3.88 -0.240 0.66180E+04 202 montmorillonite-K -2.24 -6.27 -4.03 -0.247 0.68816E+04 203 montmorillonite-Mg -2.48 -6.79 -4.32 -0.267 0.73678E+04 204 montmorillonite-Na -2.04 -5.57 -3.54 -0.216 0.60365E+04 205 nontronite-Ca 3.21 -0.19 -3.41 -0.221 0.58215E+04 206 nontronite-H 2.53 -2.36 -4.89 -0.328 0.83485E+04 207 nontronite-K 3.34 -0.30 -3.64 -0.233 0.62083E+04 208 nontronite-Mg 3.07 -0.82 -3.90 -0.253 0.66553E+04 209 nontronite-Na 3.52 0.40 -3.12 -0.200 0.53291E+04 224 tobermorite 9.82 7.76 -2.07 -0.564 0.35287E+04 230 alabandite -0.98 -5.08 -4.10 -1.368 0.70082E+04 233 boehmite 4.41 0.74 -3.67 -0.611 0.62619E+04 235 ferrous-oxide 9.81 6.73 -3.08 -0.769 0.52532E+04 240 silica-amorphous -2.09 -3.16 -1.07 -0.355 0.18203E+04 242 an20ab80 2.02 1.35 -0.67 -0.052 0.11472E+04 243 an25ab75 2.65 1.78 -0.87 -0.067 0.14810E+04 244 an30ab70 3.28 2.21 -1.07 -0.082 0.18244E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 100.0000000 g Current total amount of reactant added: 6599.9990000 g New total amount of reactant added: 6699.9990000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.5222E-10 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 12 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 6699.9990000 Water: Moles liquid = 0.1807E+02 kg liquid = 0.3256E+00 Moles total = -.2848E+02 kg total = -.5131E+00 Activity = 1.0000 Stoichiometric ionic strength = .1155442E-01 Osmotic coef. = 0.9681 True ionic strength = .2019281E-01 Chg. balance for total moles = 0.5222E-10 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.89055E-10 -10.0503 0.74788E-10 -10.1262 0.83980E+00 -0.0758 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.42179E-03 -3.3749 0.35207E-03 -3.4534 0.83471E+00 -0.0785 4 SO4-- 0.19765E-11 -11.7041 0.10241E-11 -11.9897 0.51813E+00 -0.2856 5 HCO3- 0.73099E-06 -6.1361 0.61106E-06 -6.2139 0.83594E+00 -0.0778 6 HS- 0.78313E-04 -4.1062 0.65378E-04 -4.1846 0.83483E+00 -0.0784 7 Al+++ 0.99780E-29 -29.0010 0.22933E-29 -29.6395 0.22983E+00 -0.6386 8 H4SiO4 0.69598E-03 -3.1574 0.69598E-03 -3.1574 0.10000E+01 0.0000 9 Ca++ 0.13749E-06 -6.8617 0.70712E-07 -7.1505 0.51430E+00 -0.2888 10 Mg++ 0.21510E-10 -10.6674 0.11012E-10 -10.9581 0.51193E+00 -0.2908 11 Fe++ 0.59286E-13 -13.2271 0.30384E-13 -13.5174 0.51250E+00 -0.2903 12 K+ 0.15787E-03 -3.8017 0.13200E-03 -3.8794 0.83614E+00 -0.0777 13 Na+ 0.20033E-01 -1.6983 0.16719E-01 -1.7768 0.83456E+00 -0.0785 14 Mn++ 0.19027E-10 -10.7206 0.97596E-11 -11.0106 0.51292E+00 -0.2899 15 HPO4-- 0.44699E-07 -7.3497 0.23163E-07 -7.6352 0.51820E+00 -0.2855 16 HSiO3- 0.10410E-01 -1.9825 0.86895E-02 -2.0610 0.83471E+00 -0.0785 17 Ca(HSiO3)+ 0.16732E-07 -7.7765 0.13993E-07 -7.8541 0.83632E+00 -0.0776 18 Mg(HSiO3)+ 0.32427E-11 -11.4891 0.27120E-11 -11.5667 0.83632E+00 -0.0776 19 NaHSiO3,aq 0.23497E-02 -2.6290 0.23497E-02 -2.6290 0.10000E+01 0.0000 20 AlO+ 0.66696E-16 -16.1759 0.55779E-16 -16.2535 0.83632E+00 -0.0776 22 HAlO2,aq 0.14853E-09 -9.8282 0.14853E-09 -9.8282 0.10000E+01 0.0000 23 AlO2- 0.52763E-05 -5.2777 0.43962E-05 -5.3569 0.83319E+00 -0.0793 24 CH4,aq 0.38028E-04 -4.4199 0.37894E-04 -4.4214 0.99648E+00 -0.0015 25 C2H6,aq 0.21270E-13 -13.6722 0.21195E-13 -13.6738 0.99648E+00 -0.0015 29 CO,aq 0.28412E-16 -16.5465 0.28412E-16 -16.5465 0.10000E+01 0.0000 30 CO2,aq 0.97996E-10 -10.0088 0.97651E-10 -10.0103 0.99648E+00 -0.0015 31 CO3-2 0.13803E-05 -5.8600 0.71367E-06 -6.1465 0.51702E+00 -0.2865 32 CaCO3,aq 0.63277E-09 -9.1988 0.63277E-09 -9.1988 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.13188E-11 -11.8798 0.11030E-11 -11.9574 0.83632E+00 -0.0776 34 CaCl+ 0.48174E-10 -10.3172 0.40289E-10 -10.3948 0.83632E+00 -0.0776 35 CaCl2,aq 0.33700E-14 -14.4724 0.33700E-14 -14.4724 0.10000E+01 0.0000 36 CaOH+ 0.80573E-07 -7.0938 0.67385E-07 -7.1714 0.83632E+00 -0.0776 37 CaSO4,aq 0.22995E-16 -16.6384 0.22995E-16 -16.6384 0.10000E+01 0.0000 38 HCl,aq 0.48250E-14 -14.3165 0.48250E-14 -14.3165 0.10000E+01 0.0000 43 FeCl+ 0.20246E-16 -16.6937 0.16932E-16 -16.7713 0.83632E+00 -0.0776 46 FeO,aq 0.21113E-09 -9.6755 0.21113E-09 -9.6755 0.10000E+01 0.0000 47 FeOH+ 0.15812E-10 -10.8010 0.13224E-10 -10.8786 0.83632E+00 -0.0776 48 HFeO2- 0.35386E-07 -7.4512 0.29537E-07 -7.5296 0.83471E+00 -0.0785 49 FeO+ 0.11082E-16 -16.9554 0.92683E-17 -17.0330 0.83632E+00 -0.0776 51 FeO2- 0.40621E-09 -9.3913 0.33906E-09 -9.4697 0.83471E+00 -0.0785 52 HFeO2,aq 0.32251E-11 -11.4915 0.32251E-11 -11.4915 0.10000E+01 0.0000 53 H2,aq 0.11623E-04 -4.9347 0.11582E-04 -4.9362 0.99648E+00 -0.0015 54 KCl,aq 0.84230E-09 -9.0745 0.84230E-09 -9.0745 0.10000E+01 0.0000 56 KOH,aq 0.75375E-06 -6.1228 0.75375E-06 -6.1228 0.10000E+01 0.0000 57 KSO4- 0.25131E-14 -14.5998 0.20977E-14 -14.6783 0.83471E+00 -0.0785 58 MgCO3,aq 0.24700E-13 -13.6073 0.24700E-13 -13.6073 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.20986E-15 -15.6781 0.17551E-15 -15.7557 0.83632E+00 -0.0776 60 MgCl+ 0.67994E-14 -14.1675 0.56865E-14 -14.2452 0.83632E+00 -0.0776 61 MgOH+ 0.69431E-10 -10.1584 0.58067E-10 -10.2361 0.83632E+00 -0.0776 63 MnO,aq 0.18070E-08 -8.7430 0.18070E-08 -8.7430 0.10000E+01 0.0000 64 MnOH+ 0.47183E-09 -9.3262 0.39460E-09 -9.4038 0.83632E+00 -0.0776 65 MnO2-2 0.20737E-10 -10.6832 0.10722E-10 -10.9697 0.51702E+00 -0.2865 66 HMnO2- 0.21046E-09 -9.6768 0.17567E-09 -9.7553 0.83471E+00 -0.0785 69 MnCl+ 0.25300E-13 -13.5969 0.21159E-13 -13.6745 0.83632E+00 -0.0776 71 NaCl,aq 0.19507E-05 -5.7098 0.19507E-05 -5.7098 0.10000E+01 0.0000 72 NaOH,aq 0.96047E-04 -4.0175 0.96047E-04 -4.0175 0.10000E+01 0.0000 74 OH- 0.92721E-02 -2.0328 0.77255E-02 -2.1121 0.83319E+00 -0.0793 79 HPO3-2 0.16171E-14 -14.7913 0.83606E-15 -15.0778 0.51702E+00 -0.2865 81 H2PO3- 0.15022E-18 -18.8233 0.12539E-18 -18.9017 0.83471E+00 -0.0785 82 H3PO4,aq 0.90611E-18 -18.0428 0.90611E-18 -18.0428 0.10000E+01 0.0000 83 H2PO4- 0.38248E-10 -10.4174 0.31957E-10 -10.4954 0.83551E+00 -0.0780 84 PO4-3 0.10465E-08 -8.9803 0.25269E-09 -9.5974 0.24147E+00 -0.6171 88 HP2O7-3 0.92925E-18 -18.0319 0.21379E-18 -18.6700 0.23007E+00 -0.6381 89 P2O7-4 0.89369E-17 -17.0488 0.68291E-18 -18.1656 0.76414E-01 -1.1168 90 H2S,aq 0.15165E-07 -7.8192 0.15112E-07 -7.8207 0.99648E+00 -0.0015 91 S2-2 0.15816E-13 -13.8009 0.81771E-14 -14.0874 0.51702E+00 -0.2865 97 SO3-2 0.29385E-17 -17.5319 0.15414E-17 -17.8121 0.52455E+00 -0.2802 99 HSO4- 0.88170E-19 -19.0547 0.73811E-19 -19.1319 0.83714E+00 -0.0772 Charge balance for all species = 0.1604E-09 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.8905510E-10 -.2215428E-01 -.2229119E+02 0.0000 2 H2O 0.1000000E+01 0.5550492E+02 0.9981915E+06 0.0000 3 Cl- 0.4217885E-03 0.4237401E-03 0.1499662E+02 6.6728 4 SO4-- 0.1976513E-11 -.4093372E-04 -.3925292E+01 8.2627 5 HCO3- 0.7309880E-06 0.4014000E-04 0.2444953E+01 3.9123 6 HS- 0.7831302E-04 0.1192619E-03 0.3937342E+01 5.9416 7 Al+++ 0.9978047E-29 0.5276496E-05 0.1421192E+00 0.7390 8 H4SiO4 0.6959828E-03 0.1345578E-01 0.1291049E+04 -3.1574 9 Ca++ 0.1374910E-06 0.2354781E-06 0.9421009E-02 13.1018 10 Mg++ 0.2151013E-10 0.9421320E-10 0.2286511E-05 9.2942 11 Fe++ 0.5928557E-13 0.3602245E-07 0.2008232E-02 6.7350 12 K+ 0.1578687E-03 0.1586233E-03 0.6191656E+01 6.2467 13 Na+ 0.2003300E-01 0.2248065E-01 0.5159230E+03 8.3494 14 Mn++ 0.1902728E-10 0.2529082E-08 0.1387001E-03 9.2418 15 HPO4-- 0.4469855E-07 0.4578326E-07 0.4386557E-02 12.6171 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.1109420E+03 -.7213664E-02 -.1109348E+03 0.0000000E+00 2 H2O -.2847899E+02 0.1807298E+02 -.4655196E+02 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.1857053E+00 -.1332844E-04 0.1857186E+00 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.1856798E+00 0.3883291E-04 -.1857186E+00 0.0000000E+00 7 Al+++ 0.2184697E+02 0.1718082E-05 0.2184696E+02 0.0000000E+00 8 H4SiO4 0.6976564E+02 0.4381343E-02 0.6976125E+02 0.0000000E+00 9 Ca++ 0.7705969E+01 0.7667410E-07 0.7705969E+01 0.0000000E+00 10 Mg++ 0.5317460E+01 0.3067679E-10 0.5317460E+01 0.0000000E+00 11 Fe++ 0.4777157E+01 0.1172928E-07 0.4777157E+01 0.0000000E+00 12 K+ 0.1422505E+01 0.5164939E-04 0.1422453E+01 0.0000000E+00 13 Na+ 0.8410291E+01 0.7319932E-02 0.8402971E+01 0.0000000E+00 14 Mn++ 0.1161686E+00 0.8234954E-09 0.1161686E+00 0.0000000E+00 15 HPO4-- 0.3964776E-01 0.1490750E-07 0.3964774E-01 0.0000000E+00 Chg. balance for solid moles: -.9742E-14 Mass of aqueous solution: 0.326180E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 6699.9990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 8.396 0.924 2202. 3.343 30.08 845.1 andradite 0.7429 -0.129 377.5 2.577 5.158 98.08 grossular 0.1799 -0.745 81.03 1.909 1.107 22.54 apatite-OH 0.1322E-01 -1.879 6.639 0.822 0.9070E-01 2.110 clinochlore 0.9514 -0.022 528.8 2.723 7.225 201.1 daphnite 0.2754 -0.560 196.5 2.293 2.685 59.55 chlorite-Mn 0.2323E-01 -1.634 16.47 1.217 0.2250 5.249 diopside 0.3552 -0.450 76.91 1.886 1.051 23.51 hedenbergite 0.9211E-01 -1.036 22.85 1.359 0.3122 6.259 microcline 1.247 0.096 347.2 2.541 4.743 135.6 stilbite 4.311 0.635 3038. 3.483 41.51 1417. stilpnomelane-Fe 0.3503 -0.456 377.6 2.577 5.159 130.4 tr.625ac.25prg.125 0.5666E-01 -1.247 48.43 1.685 0.6616 15.59 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8051E+00 0.8051E+00 1.0000 -0.094 grossular 0.1949E+00 0.1949E+00 1.0000 -0.710 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.7611E+00 0.7611E+00 1.0000 -0.119 daphnite 0.2203E+00 0.2203E+00 1.0000 -0.657 chlorite-Mn 0.1859E-01 0.1859E-01 1.0000 -1.731 diopside 0.7941E+00 0.7941E+00 1.0000 -0.100 hedenbergite 0.2059E+00 0.2059E+00 1.0000 -0.686 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 tr.625ac.25prg.125 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 7319.599154 g Volume = 2962.229944 cm3 Porosity: -10.4898% V(tot) - V(min): -.28123E+03 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 6699.9990000 g log = 3.8261 Original solution: 1000.0103000 g Original solution / Rock added: 0.15 (Water/Rock Ratio), log = -0.8261 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0916 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9356E+00 0.9850 0.1006E+01 0.1021E+01 CO2,gas 0.9510E-08 1.0064 0.1045E-07 0.1038E-07 CH4,gas 0.5049E-01 1.0120 0.5578E-01 0.5512E-01 H2,gas 0.1392E-01 1.0006 0.1521E-01 0.1520E-01 H2S,gas 0.3822E-06 0.9958 0.4154E-06 0.4172E-06 S2,gas 0.2566E-28 1.0000 0.2801E-28 0.2801E-28 CO,gas 0.3879E-13 1.0000 0.4234E-13 0.4234E-13 SO3,gas 0.1984E-47 1.0000 0.2166E-47 0.2166E-47 SO2,gas 0.1174E-26 1.0000 0.1281E-26 0.1281E-26 HCl,gas 0.7800E-17 1.0000 0.8514E-17 0.8514E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 16 albite -0.38 -0.38 0.00 0.000 0.11184E-10 22 andradite 39.01 39.01 0.00 0.000 0.36397E-10 23 grossular 32.73 32.73 0.00 0.000 0.24265E-10 32 apatite-OH -18.15 -18.15 0.00 0.000 0.00000E+00 46 clinochlore 39.07 39.07 0.00 0.000 0.00000E+00 47 daphnite 28.97 28.97 0.00 0.000 -0.36397E-10 48 chlorite-Mn 46.87 46.87 0.00 0.000 0.00000E+00 67 diopside 16.18 16.18 0.00 0.000 0.00000E+00 68 hedenbergite 14.21 14.21 0.00 0.000 0.60662E-11 116 microcline -2.49 -2.49 0.00 0.000 0.13649E-10 163 stilbite -7.52 -7.52 0.00 0.000 0.15165E-10 164 stilpnomelane-Fe 13.02 13.02 0.00 0.000 0.21232E-10 245 tr.625ac.25prg.125 45.16 45.16 0.00 0.000 -0.24265E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -16.34 -9.68 -3.227 0.16528E+05 -7.981 3 CH4,gas 4.54 1.59 -2.95 -0.738 0.50413E+04 -1.254 4 H2,gas 8.00 4.48 -3.52 -2.010 0.60051E+04 -1.818 5 H2S,gas -6.23 -14.31 -8.08 -4.040 0.13797E+05 -6.382 6 S2,gas -7.34 -37.59 -30.25 -4.654 0.51654E+05 -28.553 7 CO,gas 3.21 -11.86 -15.07 -4.638 0.25735E+05 -13.373 8 SO3,gas 17.12 -32.24 -49.36 -12.341 0.84287E+05 -47.664 9 SO2,gas 0.83 -27.76 -28.59 -7.624 0.48819E+05 -26.892 10 HCl,gas 5.19 -13.58 -18.77 -9.384 0.32047E+05 -17.070 11 acmite 7.71 6.53 -1.18 -0.123 0.20175E+04 15 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 19 spessartine 24.46 19.73 -4.73 -0.236 0.80700E+04 20 analcite 3.32 2.77 -0.55 -0.061 0.93625E+03 26 annite 20.12 17.72 -2.40 -0.134 0.41064E+04 27 phlogopite 27.06 25.40 -1.67 -0.093 0.28489E+04 29 anorthite 12.71 8.26 -4.45 -0.342 0.75903E+04 35 aragonite 0.97 -3.24 -4.20 -1.402 0.71795E+04 36 brucite 12.57 9.29 -3.27 -0.655 0.55909E+04 37 calcite 0.81 -3.24 -4.05 -1.350 0.69153E+04 38 carnegieite-low 9.02 5.93 -3.09 -0.442 0.52801E+04 39 carnegieite-high 10.09 5.93 -4.16 -0.595 0.71071E+04 40 carpholite-Mg 8.58 4.46 -4.12 -0.275 0.70429E+04 41 carpholite-Fe 6.71 1.90 -4.81 -0.321 0.82207E+04 42 celadonite 5.34 3.65 -1.69 -0.099 0.28879E+04 43 celadonite-Fe 3.88 1.09 -2.79 -0.164 0.47561E+04 44 chrysotile 23.89 21.57 -2.32 -0.194 0.39692E+04 49 chlorite-Al-free 47.17 43.14 -4.04 -0.168 0.68936E+04 51 chloritoid-Fe 9.17 5.06 -4.12 -0.275 0.70316E+04 52 chloritoid-Mn 11.40 7.56 -3.84 -0.256 0.65546E+04 54 coesite -2.38 -3.16 -0.78 -0.260 0.13341E+04 61 cristobalite -2.56 -3.16 -0.60 -0.199 0.10195E+04 63 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71234E+04 65 diaspore 2.87 0.74 -2.13 -0.356 0.36450E+04 66 diamond -3.10 -7.37 -4.27 -1.221 0.72944E+04 71 enstatite 17.26 12.27 -4.99 -0.499 0.85226E+04 73 clinoenstatite 17.17 12.27 -4.89 -0.489 0.83541E+04 75 epidote 24.67 22.70 -1.97 -0.095 0.33585E+04 76 clinozoisite 22.81 18.95 -3.86 -0.175 0.65869E+04 77 epidote-Fe 29.84 26.46 -3.38 -0.176 0.57768E+04 78 fayalite 14.05 10.31 -3.73 -0.533 0.63743E+04 79 ferrosilite 11.15 7.16 -3.99 -0.399 0.68202E+04 83 gibbsite 4.08 0.74 -3.34 -0.477 0.57035E+04 84 glaucophane 22.97 20.80 -2.17 -0.059 0.37134E+04 85 glaucophane-Fe 17.28 13.12 -4.15 -0.112 0.70919E+04 86 graphite -3.55 -7.37 -3.83 -1.094 0.65367E+04 87 greenalite 16.14 13.89 -2.25 -0.187 0.38408E+04 90 hematite 12.57 8.99 -3.58 -0.434 0.61111E+04 91 heulandite -5.83 -7.52 -1.69 -0.077 0.28938E+04 95 jadeite 4.22 2.77 -1.44 -0.144 0.24617E+04 97 kalsilite 7.58 3.83 -3.76 -0.537 0.64126E+04 98 kaolinite -1.33 -4.84 -3.50 -0.319 0.59832E+04 101 laumontite 2.88 1.95 -0.93 -0.062 0.15935E+04 102 lawsonite 9.62 8.26 -1.35 -0.090 0.23070E+04 103 leucite 4.12 0.67 -3.45 -0.345 0.58873E+04 105 lizardite 23.24 21.57 -1.68 -0.140 0.28619E+04 107 magnetite 20.09 15.72 -4.37 -0.356 0.74536E+04 108 minnesotaite 10.39 7.58 -2.81 -0.165 0.48027E+04 112 manganosite 14.06 9.24 -4.82 -1.204 0.82238E+04 120 muscovite 2.58 -1.01 -3.59 -0.211 0.61315E+04 121 paragonite 4.24 1.09 -3.15 -0.185 0.53706E+04 122 nepheline 8.34 5.93 -2.41 -0.344 0.41125E+04 128 periclase-Fe 11.63 6.73 -4.89 -1.223 0.83523E+04 134 phlogopite-Na 29.65 27.50 -2.15 -0.119 0.36678E+04 136 prehnite 19.37 18.21 -1.16 -0.068 0.19849E+04 137 prehnite-Fe 22.50 21.96 -0.53 -0.032 0.91159E+03 138 pumpellyite-Fe 46.27 43.89 -2.38 -0.053 0.40582E+04 139 pumpellyite-Mg 48.99 46.45 -2.54 -0.057 0.43420E+04 143 pyrrhotite -4.26 -7.58 -3.32 -1.105 0.56610E+04 144 pyrrhotiteFe0.875 -6.02 -8.97 -2.96 -1.087 0.50482E+04 145 pyroxmangite 7.40 6.08 -1.31 -0.263 0.22442E+04 146 pyrophyllite -6.18 -11.15 -4.98 -0.311 0.84962E+04 147 quartz -2.99 -3.16 -0.17 -0.056 0.28680E+03 152 rhodonite 7.45 6.08 -1.36 -0.272 0.23244E+04 153 sanidine -1.28 -2.49 -1.21 -0.093 0.20677E+04 165 stilpnomelane-Mg 27.44 25.81 -1.63 -0.049 0.27804E+04 171 talc 16.49 15.25 -1.24 -0.073 0.21140E+04 174 tephroite 18.09 15.33 -2.76 -0.394 0.47120E+04 178 tridymite -2.63 -3.16 -0.53 -0.177 0.90677E+03 179 tremolite 47.87 47.42 -0.45 -0.012 0.77494E+03 180 ferroactinolite 38.45 34.62 -3.83 -0.104 0.65448E+04 181 troilite-low -4.41 -7.58 -3.16 -1.055 0.54038E+04 183 vesuvianite 223.47 218.82 -4.65 -0.036 0.79440E+04 187 wairakite 3.95 1.95 -2.00 -0.118 0.34155E+04 188 walstromite 11.51 9.94 -1.56 -0.313 0.26719E+04 189 wollastonite 10.46 9.94 -0.52 -0.103 0.88229E+03 190 pseudo-wollastonite 11.00 9.94 -1.06 -0.211 0.18021E+04 191 zoisite 22.85 18.95 -3.90 -0.177 0.66609E+04 192 akaganeite 7.75 4.49 -3.26 -0.705 0.55681E+04 199 chalcedony -2.80 -3.16 -0.35 -0.118 0.60609E+03 201 montmorillonite-Ca -2.29 -6.17 -3.88 -0.240 0.66180E+04 202 montmorillonite-K -2.24 -6.27 -4.03 -0.247 0.68816E+04 203 montmorillonite-Mg -2.48 -6.79 -4.32 -0.267 0.73678E+04 204 montmorillonite-Na -2.04 -5.57 -3.54 -0.216 0.60365E+04 205 nontronite-Ca 3.21 -0.19 -3.41 -0.221 0.58215E+04 206 nontronite-H 2.53 -2.36 -4.89 -0.328 0.83485E+04 207 nontronite-K 3.34 -0.30 -3.64 -0.233 0.62083E+04 208 nontronite-Mg 3.07 -0.82 -3.90 -0.253 0.66553E+04 209 nontronite-Na 3.52 0.40 -3.12 -0.200 0.53291E+04 224 tobermorite 9.82 7.76 -2.07 -0.564 0.35287E+04 230 alabandite -0.98 -5.07 -4.09 -1.364 0.69854E+04 233 boehmite 4.41 0.74 -3.67 -0.611 0.62619E+04 235 ferrous-oxide 9.81 6.73 -3.08 -0.769 0.52532E+04 240 silica-amorphous -2.09 -3.16 -1.07 -0.355 0.18203E+04 242 an20ab80 2.02 1.35 -0.67 -0.052 0.11472E+04 243 an25ab75 2.65 1.78 -0.87 -0.067 0.14810E+04 244 an30ab70 3.28 2.21 -1.07 -0.082 0.18244E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 100.0000000 g Current total amount of reactant added: 6699.9990000 g New total amount of reactant added: 6799.9990000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.5221E-10 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 12 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 6799.9990000 Water: Moles liquid = 0.1752E+02 kg liquid = 0.3156E+00 Moles total = -.2973E+02 kg total = -.5356E+00 Activity = 1.0000 Stoichiometric ionic strength = .1156560E-01 Osmotic coef. = 0.9681 True ionic strength = .2020155E-01 Chg. balance for total moles = 0.5221E-10 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.89093E-10 -10.0502 0.74818E-10 -10.1260 0.83977E+00 -0.0758 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.43521E-03 -3.3613 0.36327E-03 -3.4398 0.83469E+00 -0.0785 4 SO4-- 0.20388E-11 -11.6906 0.10562E-11 -11.9762 0.51807E+00 -0.2856 5 HCO3- 0.75399E-06 -6.1226 0.63027E-06 -6.2005 0.83592E+00 -0.0778 6 HS- 0.80805E-04 -4.0926 0.67457E-04 -4.1710 0.83481E+00 -0.0784 7 Al+++ 0.99927E-29 -29.0003 0.22961E-29 -29.6390 0.22978E+00 -0.6387 8 H4SiO4 0.69598E-03 -3.1574 0.69598E-03 -3.1574 0.10000E+01 0.0000 9 Ca++ 0.13762E-06 -6.8613 0.70769E-07 -7.1502 0.51424E+00 -0.2888 10 Mg++ 0.21530E-10 -10.6670 0.11021E-10 -10.9578 0.51187E+00 -0.2908 11 Fe++ 0.59340E-13 -13.2267 0.30408E-13 -13.5170 0.51244E+00 -0.2904 12 K+ 0.15794E-03 -3.8015 0.13205E-03 -3.8793 0.83612E+00 -0.0777 13 Na+ 0.20042E-01 -1.6981 0.16725E-01 -1.7766 0.83453E+00 -0.0786 14 Mn++ 0.19045E-10 -10.7202 0.97676E-11 -11.0102 0.51286E+00 -0.2900 15 HPO4-- 0.44668E-07 -7.3500 0.23144E-07 -7.6356 0.51815E+00 -0.2855 16 HSiO3- 0.10406E-01 -1.9827 0.86860E-02 -2.0612 0.83469E+00 -0.0785 17 Ca(HSiO3)+ 0.16739E-07 -7.7763 0.13999E-07 -7.8539 0.83630E+00 -0.0776 18 Mg(HSiO3)+ 0.32441E-11 -11.4889 0.27130E-11 -11.5665 0.83630E+00 -0.0776 19 NaHSiO3,aq 0.23497E-02 -2.6290 0.23497E-02 -2.6290 0.10000E+01 0.0000 20 AlO+ 0.66725E-16 -16.1757 0.55802E-16 -16.2534 0.83630E+00 -0.0776 22 HAlO2,aq 0.14853E-09 -9.8282 0.14853E-09 -9.8282 0.10000E+01 0.0000 23 AlO2- 0.52744E-05 -5.2778 0.43945E-05 -5.3571 0.83317E+00 -0.0793 24 CH4,aq 0.39239E-04 -4.4063 0.39101E-04 -4.4078 0.99647E+00 -0.0015 25 C2H6,aq 0.22646E-13 -13.6450 0.22566E-13 -13.6465 0.99647E+00 -0.0015 29 CO,aq 0.29317E-16 -16.5329 0.29317E-16 -16.5329 0.10000E+01 0.0000 30 CO2,aq 0.10112E-09 -9.9952 0.10076E-09 -9.9967 0.99647E+00 -0.0015 31 CO3-2 0.14233E-05 -5.8467 0.73581E-06 -6.1332 0.51696E+00 -0.2865 32 CaCO3,aq 0.65293E-09 -9.1851 0.65293E-09 -9.1851 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.13614E-11 -11.8660 0.11386E-11 -11.9436 0.83630E+00 -0.0776 34 CaCl+ 0.49747E-10 -10.3032 0.41603E-10 -10.3809 0.83630E+00 -0.0776 35 CaCl2,aq 0.35905E-14 -14.4448 0.35905E-14 -14.4448 0.10000E+01 0.0000 36 CaOH+ 0.80608E-07 -7.0936 0.67412E-07 -7.1713 0.83630E+00 -0.0776 37 CaSO4,aq 0.23736E-16 -16.6246 0.23736E-16 -16.6246 0.10000E+01 0.0000 38 HCl,aq 0.49804E-14 -14.3027 0.49804E-14 -14.3027 0.10000E+01 0.0000 43 FeCl+ 0.20907E-16 -16.6797 0.17484E-16 -16.7574 0.83630E+00 -0.0776 46 FeO,aq 0.21113E-09 -9.6755 0.21113E-09 -9.6755 0.10000E+01 0.0000 47 FeOH+ 0.15819E-10 -10.8008 0.13230E-10 -10.8785 0.83630E+00 -0.0776 48 HFeO2- 0.35373E-07 -7.4513 0.29525E-07 -7.5298 0.83469E+00 -0.0785 49 FeO+ 0.11087E-16 -16.9552 0.92720E-17 -17.0328 0.83630E+00 -0.0776 51 FeO2- 0.40605E-09 -9.3914 0.33893E-09 -9.4699 0.83469E+00 -0.0785 52 HFeO2,aq 0.32251E-11 -11.4915 0.32251E-11 -11.4915 0.10000E+01 0.0000 53 H2,aq 0.11623E-04 -4.9347 0.11582E-04 -4.9362 0.99647E+00 -0.0015 54 KCl,aq 0.86943E-09 -9.0608 0.86943E-09 -9.0608 0.10000E+01 0.0000 56 KOH,aq 0.75375E-06 -6.1228 0.75375E-06 -6.1228 0.10000E+01 0.0000 57 KSO4- 0.25930E-14 -14.5862 0.21644E-14 -14.6647 0.83469E+00 -0.0785 58 MgCO3,aq 0.25486E-13 -13.5937 0.25486E-13 -13.5937 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.21663E-15 -15.6643 0.18117E-15 -15.7419 0.83630E+00 -0.0776 60 MgCl+ 0.70214E-14 -14.1536 0.58720E-14 -14.2312 0.83630E+00 -0.0776 61 MgOH+ 0.69461E-10 -10.1583 0.58090E-10 -10.2359 0.83630E+00 -0.0776 63 MnO,aq 0.18070E-08 -8.7430 0.18070E-08 -8.7430 0.10000E+01 0.0000 64 MnOH+ 0.47205E-09 -9.3260 0.39477E-09 -9.4037 0.83630E+00 -0.0776 65 MnO2-2 0.20723E-10 -10.6835 0.10713E-10 -10.9701 0.51696E+00 -0.2865 66 HMnO2- 0.21039E-09 -9.6770 0.17561E-09 -9.7555 0.83469E+00 -0.0785 69 MnCl+ 0.26127E-13 -13.5829 0.21850E-13 -13.6606 0.83630E+00 -0.0776 71 NaCl,aq 0.20135E-05 -5.6960 0.20135E-05 -5.6960 0.10000E+01 0.0000 72 NaOH,aq 0.96047E-04 -4.0175 0.96047E-04 -4.0175 0.10000E+01 0.0000 74 OH- 0.92687E-02 -2.0330 0.77224E-02 -2.1122 0.83317E+00 -0.0793 79 HPO3-2 0.16160E-14 -14.7916 0.83539E-15 -15.0781 0.51696E+00 -0.2865 81 H2PO3- 0.15016E-18 -18.8234 0.12534E-18 -18.9019 0.83469E+00 -0.0785 82 H3PO4,aq 0.90611E-18 -18.0428 0.90611E-18 -18.0428 0.10000E+01 0.0000 83 H2PO4- 0.38234E-10 -10.4176 0.31944E-10 -10.4956 0.83548E+00 -0.0781 84 PO4-3 0.10455E-08 -8.9807 0.25239E-09 -9.5979 0.24142E+00 -0.6172 88 HP2O7-3 0.92837E-18 -18.0323 0.21353E-18 -18.6705 0.23001E+00 -0.6383 89 P2O7-4 0.89266E-17 -17.0493 0.68181E-18 -18.1663 0.76380E-01 -1.1170 90 H2S,aq 0.15654E-07 -7.8054 0.15598E-07 -7.8069 0.99647E+00 -0.0015 91 S2-2 0.16839E-13 -13.7737 0.87054E-14 -14.0602 0.51696E+00 -0.2865 97 SO3-2 0.30310E-17 -17.5184 0.15898E-17 -17.7987 0.52449E+00 -0.2803 99 HSO4- 0.90976E-19 -19.0411 0.76158E-19 -19.1183 0.83712E+00 -0.0772 Charge balance for all species = 0.1656E-09 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.8909329E-10 -.2214700E-01 -.2228385E+02 0.0000 2 H2O 0.1000000E+01 0.5550492E+02 0.9981911E+06 0.0000 3 Cl- 0.4352108E-03 0.4372252E-03 0.1547387E+02 6.6862 4 SO4-- 0.2038770E-11 -.4214513E-04 -.4041457E+01 8.2757 5 HCO3- 0.7539918E-06 0.4141742E-04 0.2522760E+01 3.9255 6 HS- 0.8080525E-04 0.1229660E-03 0.4059629E+01 5.9550 7 Al+++ 0.9992663E-29 0.5274531E-05 0.1420662E+00 0.7390 8 H4SiO4 0.6959829E-03 0.1345191E-01 0.1290677E+04 -3.1574 9 Ca++ 0.1376174E-06 0.2356681E-06 0.9428606E-02 13.1018 10 Mg++ 0.2152994E-10 0.9426743E-10 0.2287826E-05 9.2942 11 Fe++ 0.5934015E-13 0.3600912E-07 0.2007489E-02 6.7350 12 K+ 0.1579366E-03 0.1586912E-03 0.6194306E+01 6.2467 13 Na+ 0.2004163E-01 0.2248934E-01 0.5161223E+03 8.3494 14 Mn++ 0.1904517E-10 0.2529260E-08 0.1387098E-03 9.2418 15 HPO4-- 0.4466773E-07 0.4575143E-07 0.4383506E-02 12.6164 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.1125979E+03 -.6988877E-02 -.1125909E+03 0.0000000E+00 2 H2O -.2973253E+02 0.1751556E+02 -.4724809E+02 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.1884767E+00 -.1329964E-04 0.1884900E+00 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.1884512E+00 0.3880411E-04 -.1884900E+00 0.0000000E+00 7 Al+++ 0.2217304E+02 0.1664472E-05 0.2217304E+02 0.0000000E+00 8 H4SiO4 0.7080691E+02 0.4244989E-02 0.7080267E+02 0.0000000E+00 9 Ca++ 0.7820983E+01 0.7436924E-07 0.7820983E+01 0.0000000E+00 10 Mg++ 0.5396825E+01 0.2974776E-10 0.5396825E+01 0.0000000E+00 11 Fe++ 0.4848458E+01 0.1136332E-07 0.4848458E+01 0.0000000E+00 12 K+ 0.1443737E+01 0.5007783E-04 0.1443686E+01 0.0000000E+00 13 Na+ 0.8535815E+01 0.7096911E-02 0.8528719E+01 0.0000000E+00 14 Mn++ 0.1179024E+00 0.7981529E-09 0.1179024E+00 0.0000000E+00 15 HPO4-- 0.4023952E-01 0.1443767E-07 0.4023950E-01 0.0000000E+00 Chg. balance for solid moles: -.1517E-13 Mass of aqueous solution: 0.316120E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 6799.9990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 8.522 0.931 2235. 3.349 30.08 857.8 andradite 0.7540 -0.123 383.1 2.583 5.158 99.54 grossular 0.1826 -0.739 82.23 1.915 1.107 22.88 apatite-OH 0.1341E-01 -1.872 6.738 0.829 0.9070E-01 2.141 clinochlore 0.9656 -0.015 536.7 2.730 7.224 204.1 daphnite 0.2795 -0.554 199.4 2.300 2.685 60.44 chlorite-Mn 0.2358E-01 -1.627 16.72 1.223 0.2250 5.328 diopside 0.3606 -0.443 78.09 1.893 1.051 23.87 hedenbergite 0.9352E-01 -1.029 23.20 1.366 0.3123 6.355 microcline 1.266 0.102 352.4 2.547 4.743 137.6 stilbite 4.375 0.641 3083. 3.489 41.50 1438. stilpnomelane-Fe 0.3555 -0.449 383.2 2.583 5.159 132.4 tr.625ac.25prg.125 0.5749E-01 -1.240 49.14 1.691 0.6615 15.82 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8051E+00 0.8051E+00 1.0000 -0.094 grossular 0.1949E+00 0.1949E+00 1.0000 -0.710 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.7611E+00 0.7611E+00 1.0000 -0.119 daphnite 0.2203E+00 0.2203E+00 1.0000 -0.657 chlorite-Mn 0.1859E-01 0.1859E-01 1.0000 -1.731 diopside 0.7941E+00 0.7941E+00 1.0000 -0.100 hedenbergite 0.2059E+00 0.2059E+00 1.0000 -0.686 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 tr.625ac.25prg.125 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 7428.849818 g Volume = 3006.433008 cm3 Porosity: -10.4900% V(tot) - V(min): -.28543E+03 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 6799.9990000 g log = 3.8325 Original solution: 1000.0103000 g Original solution / Rock added: 0.15 (Water/Rock Ratio), log = -0.8325 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0934 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9341E+00 0.9850 0.1006E+01 0.1021E+01 CO2,gas 0.9797E-08 1.0064 0.1078E-07 0.1071E-07 CH4,gas 0.5202E-01 1.0120 0.5755E-01 0.5687E-01 H2,gas 0.1390E-01 1.0006 0.1521E-01 0.1520E-01 H2S,gas 0.3938E-06 0.9958 0.4288E-06 0.4306E-06 S2,gas 0.2730E-28 1.0000 0.2985E-28 0.2985E-28 CO,gas 0.3996E-13 1.0000 0.4369E-13 0.4369E-13 SO3,gas 0.2045E-47 1.0000 0.2236E-47 0.2236E-47 SO2,gas 0.1210E-26 1.0000 0.1323E-26 0.1323E-26 HCl,gas 0.8038E-17 1.0000 0.8788E-17 0.8788E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 16 albite -0.38 -0.38 0.00 0.000 -0.94784E-12 22 andradite 39.01 39.01 0.00 0.000 0.00000E+00 23 grossular 32.73 32.73 0.00 0.000 0.12132E-10 32 apatite-OH -18.15 -18.15 0.00 0.000 0.00000E+00 46 clinochlore 39.07 39.07 0.00 0.000 0.00000E+00 47 daphnite 28.97 28.97 0.00 0.000 0.60662E-11 48 chlorite-Mn 46.87 46.87 0.00 0.000 0.24265E-10 67 diopside 16.18 16.18 0.00 0.000 0.00000E+00 68 hedenbergite 14.21 14.21 0.00 0.000 -0.90992E-11 116 microcline -2.49 -2.49 0.00 0.000 -0.10616E-10 163 stilbite -7.52 -7.52 0.00 0.000 -0.90992E-11 164 stilpnomelane-Fe 13.02 13.02 0.00 0.000 0.21232E-10 245 tr.625ac.25prg.125 45.16 45.16 0.00 0.000 -0.24265E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -16.33 -9.67 -3.222 0.16505E+05 -7.967 3 CH4,gas 4.54 1.60 -2.94 -0.735 0.50181E+04 -1.240 4 H2,gas 8.00 4.48 -3.52 -2.010 0.60051E+04 -1.818 5 H2S,gas -6.23 -14.30 -8.07 -4.033 0.13774E+05 -6.368 6 S2,gas -7.34 -37.56 -30.22 -4.650 0.51607E+05 -28.525 7 CO,gas 3.21 -11.84 -15.06 -4.633 0.25712E+05 -13.360 8 SO3,gas 17.12 -32.23 -49.35 -12.337 0.84263E+05 -47.651 9 SO2,gas 0.83 -27.75 -28.58 -7.621 0.48795E+05 -26.879 10 HCl,gas 5.19 -13.57 -18.76 -9.378 0.32024E+05 -17.056 11 acmite 7.71 6.53 -1.18 -0.123 0.20175E+04 15 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 19 spessartine 24.46 19.73 -4.73 -0.236 0.80700E+04 20 analcite 3.32 2.77 -0.55 -0.061 0.93625E+03 26 annite 20.12 17.72 -2.40 -0.134 0.41064E+04 27 phlogopite 27.06 25.40 -1.67 -0.093 0.28489E+04 29 anorthite 12.71 8.26 -4.45 -0.342 0.75903E+04 35 aragonite 0.97 -3.22 -4.19 -1.397 0.71563E+04 36 brucite 12.57 9.29 -3.27 -0.655 0.55909E+04 37 calcite 0.81 -3.22 -4.04 -1.345 0.68921E+04 38 carnegieite-low 9.02 5.93 -3.09 -0.442 0.52801E+04 39 carnegieite-high 10.09 5.93 -4.16 -0.595 0.71071E+04 40 carpholite-Mg 8.58 4.46 -4.12 -0.275 0.70429E+04 41 carpholite-Fe 6.71 1.90 -4.81 -0.321 0.82207E+04 42 celadonite 5.34 3.65 -1.69 -0.099 0.28879E+04 43 celadonite-Fe 3.88 1.09 -2.79 -0.164 0.47561E+04 44 chrysotile 23.89 21.57 -2.32 -0.194 0.39692E+04 49 chlorite-Al-free 47.17 43.14 -4.04 -0.168 0.68936E+04 51 chloritoid-Fe 9.17 5.06 -4.12 -0.275 0.70316E+04 52 chloritoid-Mn 11.40 7.56 -3.84 -0.256 0.65546E+04 54 coesite -2.38 -3.16 -0.78 -0.260 0.13341E+04 61 cristobalite -2.56 -3.16 -0.60 -0.199 0.10195E+04 63 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71234E+04 65 diaspore 2.87 0.74 -2.13 -0.356 0.36450E+04 66 diamond -3.10 -7.36 -4.26 -1.217 0.72712E+04 71 enstatite 17.26 12.27 -4.99 -0.499 0.85226E+04 73 clinoenstatite 17.17 12.27 -4.89 -0.489 0.83541E+04 75 epidote 24.67 22.70 -1.97 -0.095 0.33585E+04 76 clinozoisite 22.81 18.95 -3.86 -0.175 0.65869E+04 77 epidote-Fe 29.84 26.46 -3.38 -0.176 0.57768E+04 78 fayalite 14.05 10.31 -3.73 -0.533 0.63743E+04 79 ferrosilite 11.15 7.16 -3.99 -0.399 0.68202E+04 83 gibbsite 4.08 0.74 -3.34 -0.477 0.57035E+04 84 glaucophane 22.97 20.80 -2.17 -0.059 0.37134E+04 85 glaucophane-Fe 17.28 13.12 -4.15 -0.112 0.70919E+04 86 graphite -3.55 -7.36 -3.81 -1.090 0.65134E+04 87 greenalite 16.14 13.89 -2.25 -0.187 0.38408E+04 90 hematite 12.57 8.99 -3.58 -0.434 0.61111E+04 91 heulandite -5.83 -7.52 -1.69 -0.077 0.28938E+04 95 jadeite 4.22 2.77 -1.44 -0.144 0.24617E+04 97 kalsilite 7.58 3.83 -3.76 -0.537 0.64126E+04 98 kaolinite -1.33 -4.84 -3.50 -0.319 0.59832E+04 101 laumontite 2.88 1.95 -0.93 -0.062 0.15935E+04 102 lawsonite 9.62 8.26 -1.35 -0.090 0.23070E+04 103 leucite 4.12 0.67 -3.45 -0.345 0.58873E+04 105 lizardite 23.24 21.57 -1.68 -0.140 0.28619E+04 107 magnetite 20.09 15.72 -4.37 -0.356 0.74536E+04 108 minnesotaite 10.39 7.58 -2.81 -0.165 0.48027E+04 112 manganosite 14.06 9.24 -4.82 -1.204 0.82238E+04 120 muscovite 2.58 -1.01 -3.59 -0.211 0.61315E+04 121 paragonite 4.24 1.09 -3.15 -0.185 0.53706E+04 122 nepheline 8.34 5.93 -2.41 -0.344 0.41125E+04 128 periclase-Fe 11.63 6.73 -4.89 -1.223 0.83523E+04 134 phlogopite-Na 29.65 27.50 -2.15 -0.119 0.36678E+04 136 prehnite 19.37 18.21 -1.16 -0.068 0.19849E+04 137 prehnite-Fe 22.50 21.96 -0.53 -0.032 0.91159E+03 138 pumpellyite-Fe 46.27 43.89 -2.38 -0.053 0.40582E+04 139 pumpellyite-Mg 48.99 46.45 -2.54 -0.057 0.43420E+04 143 pyrrhotite -4.26 -7.56 -3.30 -1.101 0.56375E+04 144 pyrrhotiteFe0.875 -6.02 -8.96 -2.94 -1.082 0.50247E+04 145 pyroxmangite 7.40 6.08 -1.31 -0.263 0.22441E+04 146 pyrophyllite -6.18 -11.15 -4.98 -0.311 0.84962E+04 147 quartz -2.99 -3.16 -0.17 -0.056 0.28680E+03 152 rhodonite 7.45 6.08 -1.36 -0.272 0.23244E+04 153 sanidine -1.28 -2.49 -1.21 -0.093 0.20677E+04 165 stilpnomelane-Mg 27.44 25.81 -1.63 -0.049 0.27804E+04 171 talc 16.49 15.25 -1.24 -0.073 0.21140E+04 174 tephroite 18.09 15.33 -2.76 -0.394 0.47120E+04 178 tridymite -2.63 -3.16 -0.53 -0.177 0.90677E+03 179 tremolite 47.87 47.42 -0.45 -0.012 0.77494E+03 180 ferroactinolite 38.45 34.62 -3.83 -0.104 0.65448E+04 181 troilite-low -4.41 -7.56 -3.15 -1.050 0.53803E+04 183 vesuvianite 223.47 218.82 -4.65 -0.036 0.79440E+04 187 wairakite 3.95 1.95 -2.00 -0.118 0.34155E+04 188 walstromite 11.51 9.94 -1.56 -0.313 0.26719E+04 189 wollastonite 10.46 9.94 -0.52 -0.103 0.88229E+03 190 pseudo-wollastonite 11.00 9.94 -1.06 -0.211 0.18021E+04 191 zoisite 22.85 18.95 -3.90 -0.177 0.66610E+04 192 akaganeite 7.75 4.49 -3.26 -0.705 0.55681E+04 199 chalcedony -2.80 -3.16 -0.35 -0.118 0.60609E+03 201 montmorillonite-Ca -2.29 -6.17 -3.88 -0.240 0.66180E+04 202 montmorillonite-K -2.24 -6.27 -4.03 -0.247 0.68816E+04 203 montmorillonite-Mg -2.48 -6.79 -4.32 -0.267 0.73678E+04 204 montmorillonite-Na -2.04 -5.57 -3.54 -0.216 0.60365E+04 205 nontronite-Ca 3.21 -0.19 -3.41 -0.221 0.58215E+04 206 nontronite-H 2.53 -2.36 -4.89 -0.328 0.83485E+04 207 nontronite-K 3.34 -0.30 -3.64 -0.233 0.62083E+04 208 nontronite-Mg 3.07 -0.82 -3.90 -0.253 0.66553E+04 209 nontronite-Na 3.52 0.40 -3.12 -0.200 0.53291E+04 224 tobermorite 9.82 7.76 -2.07 -0.564 0.35287E+04 230 alabandite -0.98 -5.06 -4.08 -1.359 0.69619E+04 233 boehmite 4.41 0.74 -3.67 -0.611 0.62619E+04 235 ferrous-oxide 9.81 6.73 -3.08 -0.769 0.52532E+04 240 silica-amorphous -2.09 -3.16 -1.07 -0.355 0.18203E+04 242 an20ab80 2.02 1.35 -0.67 -0.052 0.11472E+04 243 an25ab75 2.65 1.78 -0.87 -0.067 0.14810E+04 244 an30ab70 3.28 2.21 -1.07 -0.082 0.18244E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 100.0000000 g Current total amount of reactant added: 6799.9990000 g New total amount of reactant added: 6899.9990000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.5222E-10 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 12 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 6899.9990000 Water: Moles liquid = 0.1696E+02 kg liquid = 0.3055E+00 Moles total = -.3099E+02 kg total = -.5582E+00 Activity = 1.0000 Stoichiometric ionic strength = .1157752E-01 Osmotic coef. = 0.9680 True ionic strength = .2021087E-01 Chg. balance for total moles = 0.5222E-10 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.89134E-10 -10.0500 0.74850E-10 -10.1258 0.83975E+00 -0.0759 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.44952E-03 -3.3473 0.37519E-03 -3.4257 0.83466E+00 -0.0785 4 SO4-- 0.21051E-11 -11.6767 0.10904E-11 -11.9624 0.51801E+00 -0.2857 5 HCO3- 0.77849E-06 -6.1087 0.65073E-06 -6.1866 0.83589E+00 -0.0779 6 HS- 0.83461E-04 -4.0785 0.69672E-04 -4.1569 0.83478E+00 -0.0784 7 Al+++ 0.10008E-28 -28.9996 0.22990E-29 -29.6385 0.22971E+00 -0.6388 8 H4SiO4 0.69598E-03 -3.1574 0.69598E-03 -3.1574 0.10000E+01 0.0000 9 Ca++ 0.13775E-06 -6.8609 0.70829E-07 -7.1498 0.51418E+00 -0.2889 10 Mg++ 0.21551E-10 -10.6665 0.11030E-10 -10.9574 0.51181E+00 -0.2909 11 Fe++ 0.59398E-13 -13.2262 0.30434E-13 -13.5166 0.51237E+00 -0.2904 12 K+ 0.15801E-03 -3.8013 0.13211E-03 -3.8791 0.83609E+00 -0.0777 13 Na+ 0.20051E-01 -1.6979 0.16733E-01 -1.7764 0.83451E+00 -0.0786 14 Mn++ 0.19064E-10 -10.7198 0.97761E-11 -11.0098 0.51280E+00 -0.2901 15 HPO4-- 0.44635E-07 -7.3503 0.23125E-07 -7.6359 0.51808E+00 -0.2856 16 HSiO3- 0.10402E-01 -1.9829 0.86823E-02 -2.0614 0.83466E+00 -0.0785 17 Ca(HSiO3)+ 0.16747E-07 -7.7761 0.14005E-07 -7.8537 0.83627E+00 -0.0777 18 Mg(HSiO3)+ 0.32456E-11 -11.4887 0.27142E-11 -11.5664 0.83627E+00 -0.0777 19 NaHSiO3,aq 0.23497E-02 -2.6290 0.23497E-02 -2.6290 0.10000E+01 0.0000 20 AlO+ 0.66755E-16 -16.1755 0.55826E-16 -16.2532 0.83627E+00 -0.0777 22 HAlO2,aq 0.14853E-09 -9.8282 0.14853E-09 -9.8282 0.10000E+01 0.0000 23 AlO2- 0.52723E-05 -5.2780 0.43926E-05 -5.3573 0.83314E+00 -0.0793 24 CH4,aq 0.40530E-04 -4.3922 0.40387E-04 -4.3938 0.99647E+00 -0.0015 25 C2H6,aq 0.24161E-13 -13.6169 0.24076E-13 -13.6184 0.99647E+00 -0.0015 29 CO,aq 0.30282E-16 -16.5188 0.30282E-16 -16.5188 0.10000E+01 0.0000 30 CO2,aq 0.10445E-09 -9.9811 0.10408E-09 -9.9826 0.99647E+00 -0.0015 31 CO3-2 0.14691E-05 -5.8330 0.75937E-06 -6.1195 0.51690E+00 -0.2866 32 CaCO3,aq 0.67441E-09 -9.1711 0.67441E-09 -9.1711 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.14069E-11 -11.8517 0.11765E-11 -11.9294 0.83627E+00 -0.0777 34 CaCl+ 0.51426E-10 -10.2888 0.43006E-10 -10.3665 0.83627E+00 -0.0777 35 CaCl2,aq 0.38335E-14 -14.4164 0.38335E-14 -14.4164 0.10000E+01 0.0000 36 CaOH+ 0.80644E-07 -7.0934 0.67441E-07 -7.1711 0.83627E+00 -0.0777 37 CaSO4,aq 0.24526E-16 -16.6104 0.24526E-16 -16.6104 0.10000E+01 0.0000 38 HCl,aq 0.51461E-14 -14.2885 0.51461E-14 -14.2885 0.10000E+01 0.0000 43 FeCl+ 0.21612E-16 -16.6653 0.18074E-16 -16.7429 0.83627E+00 -0.0777 46 FeO,aq 0.21112E-09 -9.6755 0.21112E-09 -9.6755 0.10000E+01 0.0000 47 FeOH+ 0.15826E-10 -10.8006 0.13235E-10 -10.8783 0.83627E+00 -0.0777 48 HFeO2- 0.35359E-07 -7.4515 0.29513E-07 -7.5300 0.83466E+00 -0.0785 49 FeO+ 0.11092E-16 -16.9550 0.92760E-17 -17.0326 0.83627E+00 -0.0777 51 FeO2- 0.40589E-09 -9.3916 0.33878E-09 -9.4701 0.83466E+00 -0.0785 52 HFeO2,aq 0.32251E-11 -11.4915 0.32251E-11 -11.4915 0.10000E+01 0.0000 53 H2,aq 0.11623E-04 -4.9347 0.11582E-04 -4.9362 0.99647E+00 -0.0015 54 KCl,aq 0.89836E-09 -9.0466 0.89836E-09 -9.0466 0.10000E+01 0.0000 56 KOH,aq 0.75375E-06 -6.1228 0.75375E-06 -6.1228 0.10000E+01 0.0000 57 KSO4- 0.26783E-14 -14.5721 0.22355E-14 -14.6506 0.83466E+00 -0.0785 58 MgCO3,aq 0.26325E-13 -13.5796 0.26325E-13 -13.5796 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.22387E-15 -15.6500 0.18721E-15 -15.7277 0.83627E+00 -0.0777 60 MgCl+ 0.72584E-14 -14.1392 0.60700E-14 -14.2168 0.83627E+00 -0.0777 61 MgOH+ 0.69493E-10 -10.1581 0.58115E-10 -10.2357 0.83627E+00 -0.0777 63 MnO,aq 0.18071E-08 -8.7430 0.18071E-08 -8.7430 0.10000E+01 0.0000 64 MnOH+ 0.47227E-09 -9.3258 0.39495E-09 -9.4035 0.83627E+00 -0.0777 65 MnO2-2 0.20709E-10 -10.6838 0.10704E-10 -10.9704 0.51690E+00 -0.2866 66 HMnO2- 0.21031E-09 -9.6771 0.17553E-09 -9.7556 0.83466E+00 -0.0785 69 MnCl+ 0.27009E-13 -13.5685 0.22587E-13 -13.6461 0.83627E+00 -0.0777 71 NaCl,aq 0.20805E-05 -5.6818 0.20805E-05 -5.6818 0.10000E+01 0.0000 72 NaOH,aq 0.96047E-04 -4.0175 0.96047E-04 -4.0175 0.10000E+01 0.0000 74 OH- 0.92650E-02 -2.0332 0.77191E-02 -2.1124 0.83314E+00 -0.0793 79 HPO3-2 0.16148E-14 -14.7919 0.83468E-15 -15.0785 0.51690E+00 -0.2866 81 H2PO3- 0.15010E-18 -18.8236 0.12528E-18 -18.9021 0.83466E+00 -0.0785 82 H3PO4,aq 0.90611E-18 -18.0428 0.90611E-18 -18.0428 0.10000E+01 0.0000 83 H2PO4- 0.38219E-10 -10.4177 0.31930E-10 -10.4958 0.83546E+00 -0.0781 84 PO4-3 0.10444E-08 -8.9811 0.25207E-09 -9.5985 0.24135E+00 -0.6173 88 HP2O7-3 0.92744E-18 -18.0327 0.21326E-18 -18.6711 0.22994E+00 -0.6384 89 P2O7-4 0.89156E-17 -17.0498 0.68065E-18 -18.1671 0.76343E-01 -1.1172 90 H2S,aq 0.16175E-07 -7.7912 0.16118E-07 -7.7927 0.99647E+00 -0.0015 91 S2-2 0.17966E-13 -13.7456 0.92865E-14 -14.0321 0.51690E+00 -0.2866 97 SO3-2 0.31296E-17 -17.5045 0.16413E-17 -17.7848 0.52443E+00 -0.2803 99 HSO4- 0.93967E-19 -19.0270 0.78659E-19 -19.1043 0.83709E+00 -0.0772 Charge balance for all species = 0.1710E-09 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.8913400E-10 -.2213923E-01 -.2227603E+02 0.0000 2 H2O 0.1000000E+01 0.5550492E+02 0.9981907E+06 0.0000 3 Cl- 0.4495154E-03 0.4515969E-03 0.1598249E+02 6.7001 4 SO4-- 0.2105077E-11 -.4343626E-04 -.4165266E+01 8.2892 5 HCO3- 0.7784902E-06 0.4277881E-04 0.2605682E+01 3.9392 6 HS- 0.8346132E-04 0.1269138E-03 0.4189958E+01 5.9689 7 Al+++ 0.1000826E-28 0.5272438E-05 0.1420097E+00 0.7390 8 H4SiO4 0.6959831E-03 0.1344778E-01 0.1290281E+04 -3.1574 9 Ca++ 0.1377522E-06 0.2358707E-06 0.9436709E-02 13.1018 10 Mg++ 0.2155107E-10 0.9431942E-10 0.2289087E-05 9.2942 11 Fe++ 0.5939837E-13 0.3599492E-07 0.2006696E-02 6.7350 12 K+ 0.1580090E-03 0.1587637E-03 0.6197130E+01 6.2467 13 Na+ 0.2005083E-01 0.2249861E-01 0.5163348E+03 8.3494 14 Mn++ 0.1906421E-10 0.2529445E-08 0.1387199E-03 9.2418 15 HPO4-- 0.4463492E-07 0.4571753E-07 0.4380256E-02 12.6157 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.1142537E+03 -.6764091E-02 -.1142470E+03 0.0000000E+00 2 H2O -.3098607E+02 0.1695815E+02 -.4794422E+02 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.1912480E+00 -.1327087E-04 0.1912613E+00 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.1912225E+00 0.3877534E-04 -.1912613E+00 0.0000000E+00 7 Al+++ 0.2249911E+02 0.1610862E-05 0.2249911E+02 0.0000000E+00 8 H4SiO4 0.7184819E+02 0.4108635E-02 0.7184408E+02 0.0000000E+00 9 Ca++ 0.7935998E+01 0.7206442E-07 0.7935998E+01 0.0000000E+00 10 Mg++ 0.5476190E+01 0.2881695E-10 0.5476190E+01 0.0000000E+00 11 Fe++ 0.4919759E+01 0.1099735E-07 0.4919759E+01 0.0000000E+00 12 K+ 0.1464968E+01 0.4850629E-04 0.1464919E+01 0.0000000E+00 13 Na+ 0.8661340E+01 0.6873890E-02 0.8654466E+01 0.0000000E+00 14 Mn++ 0.1196363E+00 0.7728090E-09 0.1196363E+00 0.0000000E+00 15 HPO4-- 0.4083127E-01 0.1396785E-07 0.4083126E-01 0.0000000E+00 Chg. balance for solid moles: -.1928E-13 Mass of aqueous solution: 0.306060E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 6899.9990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 8.647 0.937 2267. 3.356 30.08 870.4 andradite 0.7650 -0.116 388.8 2.590 5.158 101.0 grossular 0.1852 -0.732 83.44 1.921 1.107 23.22 apatite-OH 0.1361E-01 -1.866 6.837 0.835 0.9070E-01 2.172 clinochlore 0.9797 -0.009 544.6 2.736 7.224 207.1 daphnite 0.2836 -0.547 202.4 2.306 2.685 61.33 chlorite-Mn 0.2393E-01 -1.621 16.96 1.230 0.2250 5.406 diopside 0.3660 -0.436 79.27 1.899 1.052 24.23 hedenbergite 0.9493E-01 -1.023 23.55 1.372 0.3124 6.451 microcline 1.285 0.109 357.5 2.553 4.743 139.7 stilbite 4.439 0.647 3129. 3.495 41.50 1459. stilpnomelane-Fe 0.3607 -0.443 388.9 2.590 5.159 134.3 tr.625ac.25prg.125 0.5832E-01 -1.234 49.85 1.698 0.6613 16.05 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8051E+00 0.8051E+00 1.0000 -0.094 grossular 0.1949E+00 0.1949E+00 1.0000 -0.710 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.7611E+00 0.7611E+00 1.0000 -0.119 daphnite 0.2203E+00 0.2203E+00 1.0000 -0.657 chlorite-Mn 0.1859E-01 0.1859E-01 1.0000 -1.731 diopside 0.7941E+00 0.7941E+00 1.0000 -0.100 hedenbergite 0.2059E+00 0.2059E+00 1.0000 -0.686 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 tr.625ac.25prg.125 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 7538.100482 g Volume = 3050.636071 cm3 Porosity: -10.4903% V(tot) - V(min): -.28964E+03 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 6899.9990000 g log = 3.8388 Original solution: 1000.0103000 g Original solution / Rock added: 0.14 (Water/Rock Ratio), log = -0.8388 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0953 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9325E+00 0.9850 0.1006E+01 0.1021E+01 CO2,gas 0.1010E-07 1.0064 0.1114E-07 0.1106E-07 CH4,gas 0.5364E-01 1.0119 0.5945E-01 0.5875E-01 H2,gas 0.1388E-01 1.0006 0.1521E-01 0.1520E-01 H2S,gas 0.4063E-06 0.9957 0.4431E-06 0.4450E-06 S2,gas 0.2909E-28 1.0000 0.3187E-28 0.3187E-28 CO,gas 0.4120E-13 1.0000 0.4513E-13 0.4513E-13 SO3,gas 0.2109E-47 1.0000 0.2310E-47 0.2310E-47 SO2,gas 0.1248E-26 1.0000 0.1367E-26 0.1367E-26 HCl,gas 0.8291E-17 1.0000 0.9080E-17 0.9080E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 16 albite -0.38 -0.38 0.00 0.000 0.11184E-10 22 andradite 39.01 39.01 0.00 0.000 0.12132E-10 23 grossular 32.73 32.73 0.00 0.000 0.00000E+00 32 apatite-OH -18.15 -18.15 0.00 0.000 0.60662E-11 46 clinochlore 39.07 39.07 0.00 0.000 0.36397E-10 47 daphnite 28.97 28.97 0.00 0.000 -0.12132E-10 48 chlorite-Mn 46.87 46.87 0.00 0.000 0.00000E+00 67 diopside 16.18 16.18 0.00 0.000 0.60662E-11 68 hedenbergite 14.21 14.21 0.00 0.000 0.00000E+00 116 microcline -2.49 -2.49 0.00 0.000 0.15165E-11 163 stilbite -7.52 -7.52 0.00 0.000 0.15165E-10 164 stilpnomelane-Fe 13.02 13.02 0.00 0.000 -0.75827E-10 245 tr.625ac.25prg.125 45.16 45.16 0.00 0.000 0.12132E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -16.31 -9.65 -3.217 0.16481E+05 -7.953 3 CH4,gas 4.54 1.62 -2.92 -0.731 0.49941E+04 -1.226 4 H2,gas 8.00 4.48 -3.52 -2.010 0.60051E+04 -1.818 5 H2S,gas -6.23 -14.28 -8.05 -4.026 0.13749E+05 -6.354 6 S2,gas -7.34 -37.53 -30.20 -4.645 0.51558E+05 -28.497 7 CO,gas 3.21 -11.83 -15.04 -4.629 0.25688E+05 -13.346 8 SO3,gas 17.12 -32.21 -49.34 -12.334 0.84239E+05 -47.636 9 SO2,gas 0.83 -27.73 -28.56 -7.617 0.48771E+05 -26.864 10 HCl,gas 5.19 -13.55 -18.74 -9.370 0.32000E+05 -17.042 11 acmite 7.71 6.53 -1.18 -0.123 0.20175E+04 15 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 19 spessartine 24.46 19.73 -4.73 -0.236 0.80700E+04 20 analcite 3.32 2.77 -0.55 -0.061 0.93625E+03 26 annite 20.12 17.72 -2.40 -0.134 0.41064E+04 27 phlogopite 27.06 25.40 -1.67 -0.093 0.28489E+04 29 anorthite 12.71 8.26 -4.45 -0.342 0.75903E+04 35 aragonite 0.97 -3.21 -4.18 -1.392 0.71323E+04 36 brucite 12.57 9.29 -3.27 -0.655 0.55909E+04 37 calcite 0.81 -3.21 -4.02 -1.341 0.68681E+04 38 carnegieite-low 9.02 5.93 -3.09 -0.442 0.52801E+04 39 carnegieite-high 10.09 5.93 -4.16 -0.595 0.71071E+04 40 carpholite-Mg 8.58 4.46 -4.12 -0.275 0.70429E+04 41 carpholite-Fe 6.71 1.90 -4.81 -0.321 0.82207E+04 42 celadonite 5.34 3.65 -1.69 -0.099 0.28879E+04 43 celadonite-Fe 3.88 1.09 -2.79 -0.164 0.47561E+04 44 chrysotile 23.89 21.57 -2.32 -0.194 0.39692E+04 49 chlorite-Al-free 47.17 43.14 -4.04 -0.168 0.68936E+04 51 chloritoid-Fe 9.17 5.06 -4.12 -0.275 0.70316E+04 52 chloritoid-Mn 11.40 7.56 -3.84 -0.256 0.65546E+04 54 coesite -2.38 -3.16 -0.78 -0.260 0.13341E+04 61 cristobalite -2.56 -3.16 -0.60 -0.199 0.10195E+04 63 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71234E+04 65 diaspore 2.87 0.74 -2.13 -0.356 0.36450E+04 66 diamond -3.10 -7.35 -4.24 -1.213 0.72472E+04 71 enstatite 17.26 12.27 -4.99 -0.499 0.85226E+04 73 clinoenstatite 17.17 12.27 -4.89 -0.489 0.83541E+04 75 epidote 24.67 22.70 -1.97 -0.095 0.33585E+04 76 clinozoisite 22.81 18.95 -3.86 -0.175 0.65869E+04 77 epidote-Fe 29.84 26.46 -3.38 -0.176 0.57768E+04 78 fayalite 14.05 10.31 -3.73 -0.533 0.63743E+04 79 ferrosilite 11.15 7.16 -3.99 -0.399 0.68202E+04 83 gibbsite 4.08 0.74 -3.34 -0.477 0.57035E+04 84 glaucophane 22.97 20.80 -2.17 -0.059 0.37134E+04 85 glaucophane-Fe 17.28 13.12 -4.15 -0.112 0.70919E+04 86 graphite -3.55 -7.35 -3.80 -1.086 0.64894E+04 87 greenalite 16.14 13.89 -2.25 -0.187 0.38408E+04 90 hematite 12.57 8.99 -3.58 -0.434 0.61111E+04 91 heulandite -5.83 -7.52 -1.69 -0.077 0.28938E+04 95 jadeite 4.22 2.77 -1.44 -0.144 0.24617E+04 97 kalsilite 7.58 3.83 -3.76 -0.537 0.64126E+04 98 kaolinite -1.33 -4.84 -3.50 -0.319 0.59832E+04 101 laumontite 2.88 1.95 -0.93 -0.062 0.15935E+04 102 lawsonite 9.62 8.26 -1.35 -0.090 0.23070E+04 103 leucite 4.12 0.67 -3.45 -0.345 0.58873E+04 105 lizardite 23.24 21.57 -1.68 -0.140 0.28619E+04 107 magnetite 20.09 15.72 -4.37 -0.356 0.74536E+04 108 minnesotaite 10.39 7.58 -2.81 -0.165 0.48027E+04 112 manganosite 14.06 9.24 -4.82 -1.204 0.82238E+04 120 muscovite 2.58 -1.01 -3.59 -0.211 0.61315E+04 121 paragonite 4.24 1.09 -3.15 -0.185 0.53706E+04 122 nepheline 8.34 5.93 -2.41 -0.344 0.41125E+04 128 periclase-Fe 11.63 6.73 -4.89 -1.223 0.83523E+04 134 phlogopite-Na 29.65 27.50 -2.15 -0.119 0.36678E+04 136 prehnite 19.37 18.21 -1.16 -0.068 0.19849E+04 137 prehnite-Fe 22.50 21.96 -0.53 -0.032 0.91159E+03 138 pumpellyite-Fe 46.27 43.89 -2.38 -0.053 0.40582E+04 139 pumpellyite-Mg 48.99 46.45 -2.54 -0.057 0.43420E+04 143 pyrrhotite -4.26 -7.55 -3.29 -1.096 0.56132E+04 144 pyrrhotiteFe0.875 -6.02 -8.95 -2.93 -1.077 0.50004E+04 145 pyroxmangite 7.40 6.08 -1.31 -0.263 0.22441E+04 146 pyrophyllite -6.18 -11.15 -4.98 -0.311 0.84962E+04 147 quartz -2.99 -3.16 -0.17 -0.056 0.28680E+03 152 rhodonite 7.45 6.08 -1.36 -0.272 0.23244E+04 153 sanidine -1.28 -2.49 -1.21 -0.093 0.20677E+04 165 stilpnomelane-Mg 27.44 25.81 -1.63 -0.049 0.27804E+04 171 talc 16.49 15.25 -1.24 -0.073 0.21140E+04 174 tephroite 18.09 15.33 -2.76 -0.394 0.47120E+04 178 tridymite -2.63 -3.16 -0.53 -0.177 0.90677E+03 179 tremolite 47.87 47.42 -0.45 -0.012 0.77494E+03 180 ferroactinolite 38.45 34.62 -3.83 -0.104 0.65448E+04 181 troilite-low -4.41 -7.55 -3.14 -1.046 0.53560E+04 183 vesuvianite 223.47 218.82 -4.65 -0.036 0.79440E+04 187 wairakite 3.95 1.95 -2.00 -0.118 0.34155E+04 188 walstromite 11.51 9.94 -1.56 -0.313 0.26719E+04 189 wollastonite 10.46 9.94 -0.52 -0.103 0.88229E+03 190 pseudo-wollastonite 11.00 9.94 -1.06 -0.211 0.18021E+04 191 zoisite 22.85 18.95 -3.90 -0.177 0.66610E+04 192 akaganeite 7.75 4.49 -3.26 -0.705 0.55681E+04 199 chalcedony -2.80 -3.16 -0.35 -0.118 0.60609E+03 201 montmorillonite-Ca -2.29 -6.17 -3.88 -0.240 0.66180E+04 202 montmorillonite-K -2.24 -6.27 -4.03 -0.247 0.68816E+04 203 montmorillonite-Mg -2.48 -6.79 -4.32 -0.267 0.73678E+04 204 montmorillonite-Na -2.04 -5.57 -3.54 -0.216 0.60365E+04 205 nontronite-Ca 3.21 -0.19 -3.41 -0.221 0.58215E+04 206 nontronite-H 2.53 -2.36 -4.89 -0.328 0.83485E+04 207 nontronite-K 3.34 -0.30 -3.64 -0.233 0.62083E+04 208 nontronite-Mg 3.07 -0.82 -3.90 -0.253 0.66553E+04 209 nontronite-Na 3.52 0.40 -3.12 -0.200 0.53291E+04 224 tobermorite 9.82 7.76 -2.07 -0.564 0.35287E+04 230 alabandite -0.98 -5.04 -4.06 -1.354 0.69376E+04 233 boehmite 4.41 0.74 -3.67 -0.611 0.62619E+04 235 ferrous-oxide 9.81 6.73 -3.08 -0.769 0.52532E+04 240 silica-amorphous -2.09 -3.16 -1.07 -0.355 0.18203E+04 242 an20ab80 2.02 1.35 -0.67 -0.052 0.11472E+04 243 an25ab75 2.65 1.78 -0.87 -0.067 0.14810E+04 244 an30ab70 3.28 2.21 -1.07 -0.082 0.18244E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 100.0000000 g Current total amount of reactant added: 6899.9990000 g New total amount of reactant added: 6999.9990000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.5222E-10 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 12 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 6999.9990000 Water: Moles liquid = 0.1640E+02 kg liquid = 0.2955E+00 Moles total = -.3224E+02 kg total = -.5808E+00 Activity = 1.0000 Stoichiometric ionic strength = .1159025E-01 Osmotic coef. = 0.9680 True ionic strength = .2022083E-01 Chg. balance for total moles = 0.5222E-10 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.89177E-10 -10.0497 0.74884E-10 -10.1256 0.83972E+00 -0.0759 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.46479E-03 -3.3327 0.38793E-03 -3.4112 0.83463E+00 -0.0785 4 SO4-- 0.21758E-11 -11.6624 0.11270E-11 -11.9481 0.51794E+00 -0.2857 5 HCO3- 0.80463E-06 -6.0944 0.67256E-06 -6.1723 0.83586E+00 -0.0779 6 HS- 0.86298E-04 -4.0640 0.72038E-04 -4.1424 0.83476E+00 -0.0784 7 Al+++ 0.10025E-28 -28.9989 0.23022E-29 -29.6379 0.22964E+00 -0.6389 8 H4SiO4 0.69598E-03 -3.1574 0.69598E-03 -3.1574 0.10000E+01 0.0000 9 Ca++ 0.13790E-06 -6.8604 0.70894E-07 -7.1494 0.51411E+00 -0.2889 10 Mg++ 0.21574E-10 -10.6661 0.11040E-10 -10.9570 0.51174E+00 -0.2910 11 Fe++ 0.59461E-13 -13.2258 0.30462E-13 -13.5162 0.51230E+00 -0.2905 12 K+ 0.15809E-03 -3.8011 0.13217E-03 -3.8789 0.83606E+00 -0.0778 13 Na+ 0.20061E-01 -1.6977 0.16740E-01 -1.7762 0.83448E+00 -0.0786 14 Mn++ 0.19085E-10 -10.7193 0.97853E-11 -11.0094 0.51273E+00 -0.2901 15 HPO4-- 0.44600E-07 -7.3507 0.23103E-07 -7.6363 0.51802E+00 -0.2857 16 HSiO3- 0.10398E-01 -1.9831 0.86783E-02 -2.0616 0.83463E+00 -0.0785 17 Ca(HSiO3)+ 0.16755E-07 -7.7759 0.14011E-07 -7.8535 0.83624E+00 -0.0777 18 Mg(HSiO3)+ 0.32472E-11 -11.4885 0.27155E-11 -11.5662 0.83624E+00 -0.0777 19 NaHSiO3,aq 0.23497E-02 -2.6290 0.23497E-02 -2.6290 0.10000E+01 0.0000 20 AlO+ 0.66788E-16 -16.1753 0.55851E-16 -16.2530 0.83624E+00 -0.0777 22 HAlO2,aq 0.14853E-09 -9.8282 0.14853E-09 -9.8282 0.10000E+01 0.0000 23 AlO2- 0.52701E-05 -5.2782 0.43906E-05 -5.3575 0.83312E+00 -0.0793 24 CH4,aq 0.41909E-04 -4.3777 0.41761E-04 -4.3792 0.99647E+00 -0.0015 25 C2H6,aq 0.25833E-13 -13.5878 0.25742E-13 -13.5894 0.99647E+00 -0.0015 29 CO,aq 0.31312E-16 -16.5043 0.31312E-16 -16.5043 0.10000E+01 0.0000 30 CO2,aq 0.10800E-09 -9.9666 0.10762E-09 -9.9681 0.99647E+00 -0.0015 31 CO3-2 0.15179E-05 -5.8188 0.78449E-06 -6.1054 0.51683E+00 -0.2866 32 CaCO3,aq 0.69735E-09 -9.1565 0.69735E-09 -9.1565 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.14554E-11 -11.8370 0.12171E-11 -11.9147 0.83624E+00 -0.0777 34 CaCl+ 0.53222E-10 -10.2739 0.44507E-10 -10.3516 0.83624E+00 -0.0777 35 CaCl2,aq 0.41019E-14 -14.3870 0.41019E-14 -14.3870 0.10000E+01 0.0000 36 CaOH+ 0.80684E-07 -7.0932 0.67472E-07 -7.1709 0.83624E+00 -0.0777 37 CaSO4,aq 0.25370E-16 -16.5957 0.25370E-16 -16.5957 0.10000E+01 0.0000 38 HCl,aq 0.53233E-14 -14.2738 0.53233E-14 -14.2738 0.10000E+01 0.0000 43 FeCl+ 0.22367E-16 -16.6504 0.18705E-16 -16.7281 0.83624E+00 -0.0777 46 FeO,aq 0.21112E-09 -9.6755 0.21112E-09 -9.6755 0.10000E+01 0.0000 47 FeOH+ 0.15834E-10 -10.8004 0.13241E-10 -10.8781 0.83624E+00 -0.0777 48 HFeO2- 0.35344E-07 -7.4517 0.29499E-07 -7.5302 0.83463E+00 -0.0785 49 FeO+ 0.11097E-16 -16.9548 0.92802E-17 -17.0324 0.83624E+00 -0.0777 51 FeO2- 0.40572E-09 -9.3918 0.33863E-09 -9.4703 0.83463E+00 -0.0785 52 HFeO2,aq 0.32251E-11 -11.4915 0.32251E-11 -11.4915 0.10000E+01 0.0000 53 H2,aq 0.11623E-04 -4.9347 0.11582E-04 -4.9362 0.99647E+00 -0.0015 54 KCl,aq 0.92928E-09 -9.0319 0.92928E-09 -9.0319 0.10000E+01 0.0000 56 KOH,aq 0.75375E-06 -6.1228 0.75375E-06 -6.1228 0.10000E+01 0.0000 57 KSO4- 0.27693E-14 -14.5576 0.23114E-14 -14.6361 0.83463E+00 -0.0785 58 MgCO3,aq 0.27221E-13 -13.5651 0.27221E-13 -13.5651 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.23159E-15 -15.6353 0.19367E-15 -15.7129 0.83624E+00 -0.0777 60 MgCl+ 0.75119E-14 -14.1243 0.62818E-14 -14.2019 0.83624E+00 -0.0777 61 MgOH+ 0.69527E-10 -10.1578 0.58141E-10 -10.2355 0.83624E+00 -0.0777 63 MnO,aq 0.18071E-08 -8.7430 0.18071E-08 -8.7430 0.10000E+01 0.0000 64 MnOH+ 0.47251E-09 -9.3256 0.39514E-09 -9.4033 0.83624E+00 -0.0777 65 MnO2-2 0.20693E-10 -10.6842 0.10695E-10 -10.9708 0.51683E+00 -0.2866 66 HMnO2- 0.21022E-09 -9.6773 0.17546E-09 -9.7558 0.83463E+00 -0.0785 69 MnCl+ 0.27953E-13 -13.5536 0.23376E-13 -13.6312 0.83624E+00 -0.0777 71 NaCl,aq 0.21521E-05 -5.6671 0.21521E-05 -5.6671 0.10000E+01 0.0000 72 NaOH,aq 0.96047E-04 -4.0175 0.96047E-04 -4.0175 0.10000E+01 0.0000 74 OH- 0.92611E-02 -2.0333 0.77155E-02 -2.1126 0.83312E+00 -0.0793 79 HPO3-2 0.16135E-14 -14.7922 0.83391E-15 -15.0789 0.51683E+00 -0.2866 81 H2PO3- 0.15004E-18 -18.8238 0.12523E-18 -18.9023 0.83463E+00 -0.0785 82 H3PO4,aq 0.90611E-18 -18.0428 0.90611E-18 -18.0428 0.10000E+01 0.0000 83 H2PO4- 0.38202E-10 -10.4179 0.31915E-10 -10.4960 0.83543E+00 -0.0781 84 PO4-3 0.10432E-08 -8.9816 0.25172E-09 -9.5991 0.24129E+00 -0.6175 88 HP2O7-3 0.92644E-18 -18.0332 0.21297E-18 -18.6717 0.22988E+00 -0.6385 89 P2O7-4 0.89039E-17 -17.0504 0.67941E-18 -18.1679 0.76304E-01 -1.1175 90 H2S,aq 0.16731E-07 -7.7765 0.16672E-07 -7.7780 0.99647E+00 -0.0015 91 S2-2 0.19209E-13 -13.7165 0.99278E-14 -14.0031 0.51683E+00 -0.2866 97 SO3-2 0.32348E-17 -17.4902 0.16962E-17 -17.7705 0.52437E+00 -0.2804 99 HSO4- 0.97160E-19 -19.0125 0.81330E-19 -19.0898 0.83707E+00 -0.0772 Charge balance for all species = 0.1768E-09 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.8917749E-10 -.2213095E-01 -.2226768E+02 0.0000 2 H2O 0.1000000E+01 0.5550492E+02 0.9981902E+06 0.0000 3 Cl- 0.4647923E-03 0.4669454E-03 0.1652568E+02 6.7144 4 SO4-- 0.2175841E-11 -.4481524E-04 -.4297500E+01 8.3031 5 HCO3- 0.8046339E-06 0.4423274E-04 0.2694241E+01 3.9533 6 HS- 0.8629793E-04 0.1311299E-03 0.4329149E+01 5.9832 7 Al+++ 0.1002495E-28 0.5270204E-05 0.1419495E+00 0.7390 8 H4SiO4 0.6959832E-03 0.1344338E-01 0.1289857E+04 -3.1574 9 Ca++ 0.1378963E-06 0.2360873E-06 0.9445370E-02 13.1018 10 Mg++ 0.2157365E-10 0.9437794E-10 0.2290506E-05 9.2942 11 Fe++ 0.5946061E-13 0.3597978E-07 0.2005851E-02 6.7350 12 K+ 0.1580864E-03 0.1588411E-03 0.6200148E+01 6.2467 13 Na+ 0.2006066E-01 0.2250851E-01 0.5165618E+03 8.3494 14 Mn++ 0.1908453E-10 0.2529639E-08 0.1387304E-03 9.2418 15 HPO4-- 0.4459991E-07 0.4568136E-07 0.4376788E-02 12.6149 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.1159096E+03 -.6539307E-02 -.1159030E+03 0.0000000E+00 2 H2O -.3223961E+02 0.1640073E+02 -.4864034E+02 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.1940193E+00 -.1324212E-04 0.1940326E+00 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.1939938E+00 0.3874659E-04 -.1940326E+00 0.0000000E+00 7 Al+++ 0.2282519E+02 0.1557253E-05 0.2282519E+02 0.0000000E+00 8 H4SiO4 0.7288947E+02 0.3972282E-02 0.7288550E+02 0.0000000E+00 9 Ca++ 0.8051012E+01 0.6975966E-07 0.8051012E+01 0.0000000E+00 10 Mg++ 0.5555555E+01 0.2788703E-10 0.5555555E+01 0.0000000E+00 11 Fe++ 0.4991059E+01 0.1063139E-07 0.4991059E+01 0.0000000E+00 12 K+ 0.1486199E+01 0.4693475E-04 0.1486152E+01 0.0000000E+00 13 Na+ 0.8786864E+01 0.6650871E-02 0.8780213E+01 0.0000000E+00 14 Mn++ 0.1213702E+00 0.7474638E-09 0.1213702E+00 0.0000000E+00 15 HPO4-- 0.4142303E-01 0.1349804E-07 0.4142302E-01 0.0000000E+00 Chg. balance for solid moles: 0.9645E-14 Mass of aqueous solution: 0.296000E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 6999.9990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 8.773 0.943 2300. 3.362 30.08 883.1 andradite 0.7761 -0.110 394.4 2.596 5.158 102.5 grossular 0.1879 -0.726 84.65 1.928 1.107 23.55 apatite-OH 0.1381E-01 -1.860 6.936 0.841 0.9070E-01 2.204 clinochlore 0.9939 -0.003 552.5 2.742 7.224 210.1 daphnite 0.2877 -0.541 205.3 2.312 2.685 62.21 chlorite-Mn 0.2427E-01 -1.615 17.21 1.236 0.2250 5.484 diopside 0.3715 -0.430 80.45 1.906 1.052 24.59 hedenbergite 0.9634E-01 -1.016 23.90 1.378 0.3125 6.546 microcline 1.303 0.115 362.7 2.560 4.743 141.7 stilbite 4.504 0.654 3174. 3.502 41.50 1480. stilpnomelane-Fe 0.3660 -0.437 394.5 2.596 5.159 136.3 tr.625ac.25prg.125 0.5916E-01 -1.228 50.56 1.704 0.6612 16.27 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8051E+00 0.8051E+00 1.0000 -0.094 grossular 0.1949E+00 0.1949E+00 1.0000 -0.710 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.7611E+00 0.7611E+00 1.0000 -0.119 daphnite 0.2203E+00 0.2203E+00 1.0000 -0.657 chlorite-Mn 0.1859E-01 0.1859E-01 1.0000 -1.731 diopside 0.7941E+00 0.7941E+00 1.0000 -0.100 hedenbergite 0.2059E+00 0.2059E+00 1.0000 -0.686 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 tr.625ac.25prg.125 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 7647.351145 g Volume = 3094.839135 cm3 Porosity: -10.4905% V(tot) - V(min): -.29384E+03 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 6999.9990000 g log = 3.8451 Original solution: 1000.0103000 g Original solution / Rock added: 0.14 (Water/Rock Ratio), log = -0.8451 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0973 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9308E+00 0.9849 0.1006E+01 0.1021E+01 CO2,gas 0.1043E-07 1.0064 0.1151E-07 0.1144E-07 CH4,gas 0.5536E-01 1.0119 0.6147E-01 0.6075E-01 H2,gas 0.1385E-01 1.0006 0.1521E-01 0.1520E-01 H2S,gas 0.4195E-06 0.9957 0.4583E-06 0.4603E-06 S2,gas 0.3107E-28 1.0000 0.3410E-28 0.3410E-28 CO,gas 0.4252E-13 1.0000 0.4666E-13 0.4666E-13 SO3,gas 0.2178E-47 1.0000 0.2389E-47 0.2389E-47 SO2,gas 0.1288E-26 1.0000 0.1414E-26 0.1414E-26 HCl,gas 0.8560E-17 1.0000 0.9393E-17 0.9393E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 16 albite -0.38 -0.38 0.00 0.000 -0.13080E-10 22 andradite 39.01 39.01 0.00 0.000 0.00000E+00 23 grossular 32.73 32.73 0.00 0.000 0.12132E-10 32 apatite-OH -18.15 -18.15 0.00 0.000 -0.60662E-11 46 clinochlore 39.07 39.07 0.00 0.000 -0.72794E-10 47 daphnite 28.97 28.97 0.00 0.000 -0.60662E-10 48 chlorite-Mn 46.87 46.87 0.00 0.000 -0.24265E-10 67 diopside 16.18 16.18 0.00 0.000 -0.60662E-11 68 hedenbergite 14.21 14.21 0.00 0.000 -0.60662E-11 116 microcline -2.49 -2.49 0.00 0.000 -0.10616E-10 163 stilbite -7.52 -7.52 0.00 0.000 -0.33364E-10 164 stilpnomelane-Fe 13.02 13.02 0.00 0.000 0.69761E-10 245 tr.625ac.25prg.125 45.16 45.16 0.00 0.000 0.72794E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -16.30 -9.64 -3.213 0.16456E+05 -7.939 3 CH4,gas 4.54 1.63 -2.91 -0.728 0.49693E+04 -1.211 4 H2,gas 8.00 4.48 -3.52 -2.010 0.60051E+04 -1.818 5 H2S,gas -6.23 -14.27 -8.04 -4.019 0.13724E+05 -6.339 6 S2,gas -7.34 -37.50 -30.17 -4.641 0.51508E+05 -28.467 7 CO,gas 3.21 -11.82 -15.03 -4.625 0.25663E+05 -13.331 8 SO3,gas 17.12 -32.20 -49.32 -12.330 0.84214E+05 -47.622 9 SO2,gas 0.83 -27.72 -28.55 -7.613 0.48746E+05 -26.850 10 HCl,gas 5.19 -13.54 -18.73 -9.363 0.31974E+05 -17.027 11 acmite 7.71 6.53 -1.18 -0.123 0.20175E+04 15 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 19 spessartine 24.46 19.73 -4.73 -0.236 0.80699E+04 20 analcite 3.32 2.77 -0.55 -0.061 0.93625E+03 26 annite 20.12 17.72 -2.40 -0.134 0.41064E+04 27 phlogopite 27.06 25.40 -1.67 -0.093 0.28489E+04 29 anorthite 12.71 8.26 -4.45 -0.342 0.75903E+04 35 aragonite 0.97 -3.20 -4.16 -1.388 0.71075E+04 36 brucite 12.57 9.29 -3.27 -0.655 0.55909E+04 37 calcite 0.81 -3.20 -4.01 -1.336 0.68432E+04 38 carnegieite-low 9.02 5.93 -3.09 -0.442 0.52801E+04 39 carnegieite-high 10.09 5.93 -4.16 -0.595 0.71071E+04 40 carpholite-Mg 8.58 4.46 -4.12 -0.275 0.70429E+04 41 carpholite-Fe 6.71 1.90 -4.81 -0.321 0.82207E+04 42 celadonite 5.34 3.65 -1.69 -0.099 0.28879E+04 43 celadonite-Fe 3.88 1.09 -2.79 -0.164 0.47561E+04 44 chrysotile 23.89 21.57 -2.32 -0.194 0.39692E+04 49 chlorite-Al-free 47.17 43.14 -4.04 -0.168 0.68936E+04 51 chloritoid-Fe 9.17 5.06 -4.12 -0.275 0.70316E+04 52 chloritoid-Mn 11.40 7.56 -3.84 -0.256 0.65546E+04 54 coesite -2.38 -3.16 -0.78 -0.260 0.13341E+04 61 cristobalite -2.56 -3.16 -0.60 -0.199 0.10195E+04 63 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71234E+04 65 diaspore 2.87 0.74 -2.13 -0.356 0.36450E+04 66 diamond -3.10 -7.33 -4.23 -1.209 0.72224E+04 71 enstatite 17.26 12.27 -4.99 -0.499 0.85226E+04 73 clinoenstatite 17.17 12.27 -4.89 -0.489 0.83541E+04 75 epidote 24.67 22.70 -1.97 -0.095 0.33585E+04 76 clinozoisite 22.81 18.95 -3.86 -0.175 0.65869E+04 77 epidote-Fe 29.84 26.46 -3.38 -0.176 0.57768E+04 78 fayalite 14.05 10.31 -3.73 -0.533 0.63743E+04 79 ferrosilite 11.15 7.16 -3.99 -0.399 0.68202E+04 83 gibbsite 4.08 0.74 -3.34 -0.477 0.57035E+04 84 glaucophane 22.97 20.80 -2.17 -0.059 0.37134E+04 85 glaucophane-Fe 17.28 13.12 -4.15 -0.112 0.70919E+04 86 graphite -3.55 -7.33 -3.79 -1.082 0.64646E+04 87 greenalite 16.14 13.89 -2.25 -0.187 0.38408E+04 90 hematite 12.57 8.99 -3.58 -0.434 0.61111E+04 91 heulandite -5.83 -7.52 -1.69 -0.077 0.28938E+04 95 jadeite 4.22 2.77 -1.44 -0.144 0.24617E+04 97 kalsilite 7.58 3.83 -3.76 -0.537 0.64126E+04 98 kaolinite -1.33 -4.84 -3.50 -0.319 0.59832E+04 101 laumontite 2.88 1.95 -0.93 -0.062 0.15935E+04 102 lawsonite 9.62 8.26 -1.35 -0.090 0.23070E+04 103 leucite 4.12 0.67 -3.45 -0.345 0.58873E+04 105 lizardite 23.24 21.57 -1.68 -0.140 0.28619E+04 107 magnetite 20.09 15.72 -4.37 -0.356 0.74536E+04 108 minnesotaite 10.39 7.58 -2.81 -0.165 0.48027E+04 112 manganosite 14.06 9.24 -4.82 -1.204 0.82237E+04 120 muscovite 2.58 -1.01 -3.59 -0.211 0.61315E+04 121 paragonite 4.24 1.09 -3.15 -0.185 0.53706E+04 122 nepheline 8.34 5.93 -2.41 -0.344 0.41125E+04 128 periclase-Fe 11.63 6.73 -4.89 -1.223 0.83523E+04 134 phlogopite-Na 29.65 27.50 -2.15 -0.119 0.36678E+04 136 prehnite 19.37 18.21 -1.16 -0.068 0.19849E+04 137 prehnite-Fe 22.50 21.96 -0.53 -0.032 0.91159E+03 138 pumpellyite-Fe 46.27 43.89 -2.38 -0.053 0.40582E+04 139 pumpellyite-Mg 48.99 46.45 -2.54 -0.057 0.43420E+04 143 pyrrhotite -4.26 -7.53 -3.27 -1.091 0.55881E+04 144 pyrrhotiteFe0.875 -6.02 -8.93 -2.91 -1.072 0.49753E+04 145 pyroxmangite 7.40 6.08 -1.31 -0.263 0.22441E+04 146 pyrophyllite -6.18 -11.15 -4.98 -0.311 0.84962E+04 147 quartz -2.99 -3.16 -0.17 -0.056 0.28680E+03 152 rhodonite 7.45 6.08 -1.36 -0.272 0.23244E+04 153 sanidine -1.28 -2.49 -1.21 -0.093 0.20677E+04 165 stilpnomelane-Mg 27.44 25.81 -1.63 -0.049 0.27804E+04 171 talc 16.49 15.25 -1.24 -0.073 0.21140E+04 174 tephroite 18.09 15.33 -2.76 -0.394 0.47120E+04 178 tridymite -2.63 -3.16 -0.53 -0.177 0.90677E+03 179 tremolite 47.87 47.42 -0.45 -0.012 0.77494E+03 180 ferroactinolite 38.45 34.62 -3.83 -0.104 0.65448E+04 181 troilite-low -4.41 -7.53 -3.12 -1.041 0.53309E+04 183 vesuvianite 223.47 218.82 -4.65 -0.036 0.79440E+04 187 wairakite 3.95 1.95 -2.00 -0.118 0.34155E+04 188 walstromite 11.51 9.94 -1.56 -0.313 0.26719E+04 189 wollastonite 10.46 9.94 -0.52 -0.103 0.88229E+03 190 pseudo-wollastonite 11.00 9.94 -1.06 -0.211 0.18021E+04 191 zoisite 22.85 18.95 -3.90 -0.177 0.66610E+04 192 akaganeite 7.75 4.49 -3.26 -0.705 0.55681E+04 199 chalcedony -2.80 -3.16 -0.35 -0.118 0.60609E+03 201 montmorillonite-Ca -2.29 -6.17 -3.88 -0.240 0.66180E+04 202 montmorillonite-K -2.24 -6.27 -4.03 -0.247 0.68816E+04 203 montmorillonite-Mg -2.48 -6.79 -4.32 -0.267 0.73678E+04 204 montmorillonite-Na -2.04 -5.57 -3.54 -0.216 0.60365E+04 205 nontronite-Ca 3.21 -0.19 -3.41 -0.221 0.58215E+04 206 nontronite-H 2.53 -2.36 -4.89 -0.328 0.83485E+04 207 nontronite-K 3.34 -0.30 -3.64 -0.233 0.62083E+04 208 nontronite-Mg 3.07 -0.82 -3.90 -0.253 0.66553E+04 209 nontronite-Na 3.52 0.40 -3.12 -0.200 0.53291E+04 224 tobermorite 9.82 7.76 -2.07 -0.564 0.35287E+04 230 alabandite -0.98 -5.03 -4.05 -1.349 0.69125E+04 233 boehmite 4.41 0.74 -3.67 -0.611 0.62619E+04 235 ferrous-oxide 9.81 6.73 -3.08 -0.769 0.52532E+04 240 silica-amorphous -2.09 -3.16 -1.07 -0.355 0.18203E+04 242 an20ab80 2.02 1.35 -0.67 -0.052 0.11472E+04 243 an25ab75 2.65 1.78 -0.87 -0.067 0.14810E+04 244 an30ab70 3.28 2.21 -1.07 -0.082 0.18244E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 100.0000000 g Current total amount of reactant added: 6999.9990000 g New total amount of reactant added: 7099.9990000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.5222E-10 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 12 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 7099.9990000 Water: Moles liquid = 0.1584E+02 kg liquid = 0.2854E+00 Moles total = -.3349E+02 kg total = -.6034E+00 Activity = 1.0000 Stoichiometric ionic strength = .1160388E-01 Osmotic coef. = 0.9680 True ionic strength = .2023149E-01 Chg. balance for total moles = 0.5222E-10 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.89224E-10 -10.0495 0.74921E-10 -10.1254 0.83970E+00 -0.0759 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.48114E-03 -3.3177 0.40156E-03 -3.3962 0.83460E+00 -0.0785 4 SO4-- 0.22515E-11 -11.6475 0.11660E-11 -11.9333 0.51787E+00 -0.2858 5 HCO3- 0.83259E-06 -6.0796 0.69591E-06 -6.1574 0.83583E+00 -0.0779 6 HS- 0.89334E-04 -4.0490 0.74570E-04 -4.1274 0.83473E+00 -0.0785 7 Al+++ 0.10043E-28 -28.9981 0.23055E-29 -29.6372 0.22957E+00 -0.6391 8 H4SiO4 0.69598E-03 -3.1574 0.69598E-03 -3.1574 0.10000E+01 0.0000 9 Ca++ 0.13805E-06 -6.8600 0.70963E-07 -7.1490 0.51404E+00 -0.2890 10 Mg++ 0.21598E-10 -10.6656 0.11051E-10 -10.9566 0.51167E+00 -0.2910 11 Fe++ 0.59527E-13 -13.2253 0.30492E-13 -13.5158 0.51223E+00 -0.2905 12 K+ 0.15817E-03 -3.8009 0.13223E-03 -3.8787 0.83603E+00 -0.0778 13 Na+ 0.20071E-01 -1.6974 0.16748E-01 -1.7760 0.83445E+00 -0.0786 14 Mn++ 0.19106E-10 -10.7188 0.97950E-11 -11.0090 0.51266E+00 -0.2902 15 HPO4-- 0.44562E-07 -7.3510 0.23081E-07 -7.6367 0.51795E+00 -0.2857 16 HSiO3- 0.10393E-01 -1.9833 0.86741E-02 -2.0618 0.83460E+00 -0.0785 17 Ca(HSiO3)+ 0.16764E-07 -7.7756 0.14018E-07 -7.8533 0.83622E+00 -0.0777 18 Mg(HSiO3)+ 0.32489E-11 -11.4883 0.27168E-11 -11.5659 0.83622E+00 -0.0777 19 NaHSiO3,aq 0.23497E-02 -2.6290 0.23497E-02 -2.6290 0.10000E+01 0.0000 20 AlO+ 0.66823E-16 -16.1751 0.55878E-16 -16.2528 0.83622E+00 -0.0777 22 HAlO2,aq 0.14853E-09 -9.8282 0.14853E-09 -9.8282 0.10000E+01 0.0000 23 AlO2- 0.52677E-05 -5.2784 0.43884E-05 -5.3577 0.83309E+00 -0.0793 24 CH4,aq 0.43386E-04 -4.3627 0.43232E-04 -4.3642 0.99646E+00 -0.0015 25 C2H6,aq 0.27684E-13 -13.5578 0.27587E-13 -13.5593 0.99646E+00 -0.0015 29 CO,aq 0.32415E-16 -16.4893 0.32415E-16 -16.4893 0.10000E+01 0.0000 30 CO2,aq 0.11180E-09 -9.9515 0.11141E-09 -9.9531 0.99646E+00 -0.0015 31 CO3-2 0.15700E-05 -5.8041 0.81132E-06 -6.0908 0.51676E+00 -0.2867 32 CaCO3,aq 0.72192E-09 -9.1415 0.72192E-09 -9.1415 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.15075E-11 -11.8217 0.12606E-11 -11.8994 0.83622E+00 -0.0777 34 CaCl+ 0.55148E-10 -10.2585 0.46116E-10 -10.3361 0.83622E+00 -0.0777 35 CaCl2,aq 0.43996E-14 -14.3566 0.43996E-14 -14.3566 0.10000E+01 0.0000 36 CaOH+ 0.80726E-07 -7.0930 0.67505E-07 -7.1707 0.83622E+00 -0.0777 37 CaSO4,aq 0.26275E-16 -16.5805 0.26275E-16 -16.5805 0.10000E+01 0.0000 38 HCl,aq 0.55131E-14 -14.2586 0.55131E-14 -14.2586 0.10000E+01 0.0000 43 FeCl+ 0.23177E-16 -16.6349 0.19381E-16 -16.7126 0.83622E+00 -0.0777 46 FeO,aq 0.21112E-09 -9.6755 0.21112E-09 -9.6755 0.10000E+01 0.0000 47 FeOH+ 0.15843E-10 -10.8002 0.13248E-10 -10.8779 0.83622E+00 -0.0777 48 HFeO2- 0.35328E-07 -7.4519 0.29485E-07 -7.5304 0.83460E+00 -0.0785 49 FeO+ 0.11103E-16 -16.9545 0.92847E-17 -17.0322 0.83622E+00 -0.0777 51 FeO2- 0.40554E-09 -9.3920 0.33846E-09 -9.4705 0.83460E+00 -0.0785 52 HFeO2,aq 0.32252E-11 -11.4915 0.32252E-11 -11.4915 0.10000E+01 0.0000 53 H2,aq 0.11623E-04 -4.9347 0.11582E-04 -4.9362 0.99646E+00 -0.0015 54 KCl,aq 0.96241E-09 -9.0166 0.96241E-09 -9.0166 0.10000E+01 0.0000 56 KOH,aq 0.75375E-06 -6.1228 0.75375E-06 -6.1228 0.10000E+01 0.0000 57 KSO4- 0.28667E-14 -14.5426 0.23926E-14 -14.6211 0.83460E+00 -0.0785 58 MgCO3,aq 0.28179E-13 -13.5501 0.28179E-13 -13.5501 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.23988E-15 -15.6200 0.20059E-15 -15.6977 0.83622E+00 -0.0777 60 MgCl+ 0.77838E-14 -14.1088 0.65089E-14 -14.1865 0.83622E+00 -0.0777 61 MgOH+ 0.69563E-10 -10.1576 0.58170E-10 -10.2353 0.83622E+00 -0.0777 63 MnO,aq 0.18071E-08 -8.7430 0.18071E-08 -8.7430 0.10000E+01 0.0000 64 MnOH+ 0.47277E-09 -9.3254 0.39534E-09 -9.4030 0.83622E+00 -0.0777 65 MnO2-2 0.20676E-10 -10.6845 0.10684E-10 -10.9712 0.51676E+00 -0.2867 66 HMnO2- 0.21013E-09 -9.6775 0.17538E-09 -9.7560 0.83460E+00 -0.0785 69 MnCl+ 0.28965E-13 -13.5381 0.24221E-13 -13.6158 0.83622E+00 -0.0777 71 NaCl,aq 0.22289E-05 -5.6519 0.22289E-05 -5.6519 0.10000E+01 0.0000 72 NaOH,aq 0.96047E-04 -4.0175 0.96047E-04 -4.0175 0.10000E+01 0.0000 74 OH- 0.92569E-02 -2.0335 0.77118E-02 -2.1128 0.83309E+00 -0.0793 79 HPO3-2 0.16121E-14 -14.7926 0.83310E-15 -15.0793 0.51676E+00 -0.2867 81 H2PO3- 0.14997E-18 -18.8240 0.12516E-18 -18.9025 0.83460E+00 -0.0785 82 H3PO4,aq 0.90611E-18 -18.0428 0.90611E-18 -18.0428 0.10000E+01 0.0000 83 H2PO4- 0.38185E-10 -10.4181 0.31900E-10 -10.4962 0.83540E+00 -0.0781 84 PO4-3 0.10420E-08 -8.9821 0.25135E-09 -9.5997 0.24122E+00 -0.6176 88 HP2O7-3 0.92537E-18 -18.0337 0.21265E-18 -18.6723 0.22980E+00 -0.6386 89 P2O7-4 0.88914E-17 -17.0510 0.67808E-18 -18.1687 0.76262E-01 -1.1177 90 H2S,aq 0.17328E-07 -7.7612 0.17267E-07 -7.7628 0.99646E+00 -0.0015 91 S2-2 0.20586E-13 -13.6864 0.10638E-13 -13.9731 0.51676E+00 -0.2867 97 SO3-2 0.33473E-17 -17.4753 0.17550E-17 -17.7557 0.52430E+00 -0.2804 99 HSO4- 0.10058E-18 -18.9975 0.84188E-19 -19.0747 0.83704E+00 -0.0773 Charge balance for all species = 0.1829E-09 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.8922406E-10 -.2212208E-01 -.2225875E+02 0.0000 2 H2O 0.1000000E+01 0.5550493E+02 0.9981898E+06 0.0000 3 Cl- 0.4811441E-03 0.4833739E-03 0.1710710E+02 6.7292 4 SO4-- 0.2251527E-11 -.4629136E-04 -.4439048E+01 8.3175 5 HCO3- 0.8325942E-06 0.4578898E-04 0.2789031E+01 3.9680 6 HS- 0.8933414E-04 0.1356428E-03 0.4478137E+01 5.9980 7 Al+++ 0.1004284E-28 0.5267815E-05 0.1418851E+00 0.7390 8 H4SiO4 0.6959833E-03 0.1343866E-01 0.1289404E+04 -3.1574 9 Ca++ 0.1380507E-06 0.2363193E-06 0.9454647E-02 13.1018 10 Mg++ 0.2159786E-10 0.9444680E-10 0.2292176E-05 9.2942 11 Fe++ 0.5952729E-13 0.3596356E-07 0.2004946E-02 6.7350 12 K+ 0.1581692E-03 0.1589239E-03 0.6203379E+01 6.2467 13 Na+ 0.2007119E-01 0.2251912E-01 0.5168049E+03 8.3494 14 Mn++ 0.1910627E-10 0.2529841E-08 0.1387414E-03 9.2418 15 HPO4-- 0.4456247E-07 0.4564267E-07 0.4373079E-02 12.6140 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.1175654E+03 -.6314523E-02 -.1175591E+03 0.0000000E+00 2 H2O -.3349315E+02 0.1584332E+02 -.4933647E+02 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.1967907E+00 -.1321340E-04 0.1968039E+00 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.1967652E+00 0.3871787E-04 -.1968039E+00 0.0000000E+00 7 Al+++ 0.2315126E+02 0.1503644E-05 0.2315126E+02 0.0000000E+00 8 H4SiO4 0.7393075E+02 0.3835930E-02 0.7392691E+02 0.0000000E+00 9 Ca++ 0.8166026E+01 0.6745494E-07 0.8166026E+01 0.0000000E+00 10 Mg++ 0.5634920E+01 0.2695888E-10 0.5634920E+01 0.0000000E+00 11 Fe++ 0.5062360E+01 0.1026543E-07 0.5062360E+01 0.0000000E+00 12 K+ 0.1507431E+01 0.4536322E-04 0.1507385E+01 0.0000000E+00 13 Na+ 0.8912389E+01 0.6427854E-02 0.8905961E+01 0.0000000E+00 14 Mn++ 0.1231040E+00 0.7221174E-09 0.1231040E+00 0.0000000E+00 15 HPO4-- 0.4201479E-01 0.1302824E-07 0.4201477E-01 0.0000000E+00 Chg. balance for solid moles: 0.1489E-13 Mass of aqueous solution: 0.285940E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 7099.9990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 8.898 0.949 2333. 3.368 30.08 895.7 andradite 0.7872 -0.104 400.0 2.602 5.158 103.9 grossular 0.1906 -0.720 85.86 1.934 1.107 23.89 apatite-OH 0.1400E-01 -1.854 7.035 0.847 0.9070E-01 2.235 clinochlore 1.008 0.004 560.3 2.748 7.224 213.1 daphnite 0.2918 -0.535 208.2 2.319 2.685 63.10 chlorite-Mn 0.2462E-01 -1.609 17.46 1.242 0.2250 5.563 diopside 0.3769 -0.424 81.62 1.912 1.052 24.95 hedenbergite 0.9775E-01 -1.010 24.25 1.385 0.3127 6.642 microcline 1.322 0.121 367.9 2.566 4.743 143.7 stilbite 4.568 0.660 3219. 3.508 41.50 1501. stilpnomelane-Fe 0.3712 -0.430 400.1 2.602 5.159 138.2 tr.625ac.25prg.125 0.5999E-01 -1.222 51.28 1.710 0.6611 16.50 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8051E+00 0.8051E+00 1.0000 -0.094 grossular 0.1949E+00 0.1949E+00 1.0000 -0.710 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.7611E+00 0.7611E+00 1.0000 -0.119 daphnite 0.2203E+00 0.2203E+00 1.0000 -0.657 chlorite-Mn 0.1859E-01 0.1859E-01 1.0000 -1.731 diopside 0.7941E+00 0.7941E+00 1.0000 -0.100 hedenbergite 0.2059E+00 0.2059E+00 1.0000 -0.686 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 tr.625ac.25prg.125 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 7756.601809 g Volume = 3139.042198 cm3 Porosity: -10.4908% V(tot) - V(min): -.29804E+03 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 7099.9990000 g log = 3.8513 Original solution: 1000.0103000 g Original solution / Rock added: 0.14 (Water/Rock Ratio), log = -0.8513 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0995 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9290E+00 0.9849 0.1006E+01 0.1021E+01 CO2,gas 0.1077E-07 1.0063 0.1192E-07 0.1184E-07 CH4,gas 0.5720E-01 1.0119 0.6363E-01 0.6289E-01 H2,gas 0.1382E-01 1.0006 0.1521E-01 0.1520E-01 H2S,gas 0.4336E-06 0.9957 0.4747E-06 0.4767E-06 S2,gas 0.3326E-28 1.0000 0.3657E-28 0.3657E-28 CO,gas 0.4394E-13 1.0000 0.4830E-13 0.4830E-13 SO3,gas 0.2251E-47 1.0000 0.2475E-47 0.2475E-47 SO2,gas 0.1332E-26 1.0000 0.1464E-26 0.1464E-26 HCl,gas 0.8848E-17 1.0000 0.9728E-17 0.9728E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 16 albite -0.38 -0.38 0.00 0.000 -0.94784E-12 22 andradite 39.01 39.01 0.00 0.000 -0.24265E-10 23 grossular 32.73 32.73 0.00 0.000 -0.12132E-10 32 apatite-OH -18.15 -18.15 0.00 0.000 0.12132E-10 46 clinochlore 39.07 39.07 0.00 0.000 0.24265E-10 47 daphnite 28.97 28.97 0.00 0.000 0.24265E-10 48 chlorite-Mn 46.87 46.87 0.00 0.000 0.24265E-10 67 diopside 16.18 16.18 0.00 0.000 0.00000E+00 68 hedenbergite 14.21 14.21 0.00 0.000 0.30331E-11 116 microcline -2.49 -2.49 0.00 0.000 0.13649E-10 163 stilbite -7.52 -7.52 0.00 0.000 -0.90992E-11 164 stilpnomelane-Fe 13.02 13.02 0.00 0.000 -0.12436E-09 245 tr.625ac.25prg.125 45.16 45.16 0.00 0.000 0.12132E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -16.28 -9.62 -3.208 0.16431E+05 -7.924 3 CH4,gas 4.54 1.65 -2.90 -0.724 0.49436E+04 -1.196 4 H2,gas 8.00 4.48 -3.52 -2.010 0.60051E+04 -1.818 5 H2S,gas -6.23 -14.25 -8.02 -4.011 0.13698E+05 -6.324 6 S2,gas -7.34 -37.47 -30.14 -4.636 0.51456E+05 -28.437 7 CO,gas 3.21 -11.80 -15.01 -4.620 0.25638E+05 -13.316 8 SO3,gas 17.12 -32.18 -49.31 -12.326 0.84188E+05 -47.606 9 SO2,gas 0.83 -27.70 -28.53 -7.609 0.48720E+05 -26.834 10 HCl,gas 5.19 -13.52 -18.71 -9.355 0.31948E+05 -17.012 11 acmite 7.71 6.53 -1.18 -0.123 0.20175E+04 15 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 19 spessartine 24.46 19.73 -4.73 -0.236 0.80699E+04 20 analcite 3.32 2.77 -0.55 -0.061 0.93625E+03 26 annite 20.12 17.72 -2.40 -0.134 0.41064E+04 27 phlogopite 27.06 25.40 -1.67 -0.093 0.28489E+04 29 anorthite 12.71 8.26 -4.45 -0.342 0.75903E+04 35 aragonite 0.97 -3.18 -4.15 -1.383 0.70818E+04 36 brucite 12.57 9.29 -3.27 -0.655 0.55909E+04 37 calcite 0.81 -3.18 -3.99 -1.331 0.68176E+04 38 carnegieite-low 9.02 5.93 -3.09 -0.442 0.52801E+04 39 carnegieite-high 10.09 5.93 -4.16 -0.595 0.71071E+04 40 carpholite-Mg 8.58 4.46 -4.12 -0.275 0.70429E+04 41 carpholite-Fe 6.71 1.90 -4.81 -0.321 0.82207E+04 42 celadonite 5.34 3.65 -1.69 -0.099 0.28879E+04 43 celadonite-Fe 3.88 1.09 -2.79 -0.164 0.47561E+04 44 chrysotile 23.89 21.57 -2.32 -0.194 0.39692E+04 49 chlorite-Al-free 47.17 43.14 -4.04 -0.168 0.68936E+04 51 chloritoid-Fe 9.17 5.06 -4.12 -0.275 0.70316E+04 52 chloritoid-Mn 11.40 7.56 -3.84 -0.256 0.65546E+04 54 coesite -2.38 -3.16 -0.78 -0.260 0.13341E+04 61 cristobalite -2.56 -3.16 -0.60 -0.199 0.10195E+04 63 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71234E+04 65 diaspore 2.87 0.74 -2.13 -0.356 0.36450E+04 66 diamond -3.10 -7.32 -4.21 -1.204 0.71967E+04 71 enstatite 17.26 12.27 -4.99 -0.499 0.85226E+04 73 clinoenstatite 17.17 12.27 -4.89 -0.489 0.83541E+04 75 epidote 24.67 22.70 -1.97 -0.095 0.33585E+04 76 clinozoisite 22.81 18.95 -3.86 -0.175 0.65869E+04 77 epidote-Fe 29.84 26.46 -3.38 -0.176 0.57768E+04 78 fayalite 14.05 10.31 -3.73 -0.533 0.63743E+04 79 ferrosilite 11.15 7.16 -3.99 -0.399 0.68202E+04 83 gibbsite 4.08 0.74 -3.34 -0.477 0.57035E+04 84 glaucophane 22.97 20.80 -2.17 -0.059 0.37134E+04 85 glaucophane-Fe 17.28 13.12 -4.15 -0.112 0.70919E+04 86 graphite -3.55 -7.32 -3.77 -1.077 0.64389E+04 87 greenalite 16.14 13.89 -2.25 -0.187 0.38408E+04 90 hematite 12.57 8.99 -3.58 -0.434 0.61111E+04 91 heulandite -5.83 -7.52 -1.69 -0.077 0.28938E+04 95 jadeite 4.22 2.77 -1.44 -0.144 0.24617E+04 97 kalsilite 7.58 3.83 -3.76 -0.537 0.64126E+04 98 kaolinite -1.33 -4.84 -3.50 -0.319 0.59832E+04 101 laumontite 2.88 1.95 -0.93 -0.062 0.15935E+04 102 lawsonite 9.62 8.26 -1.35 -0.090 0.23070E+04 103 leucite 4.12 0.67 -3.45 -0.345 0.58873E+04 105 lizardite 23.24 21.57 -1.68 -0.140 0.28619E+04 107 magnetite 20.09 15.72 -4.37 -0.356 0.74536E+04 108 minnesotaite 10.39 7.58 -2.81 -0.165 0.48027E+04 112 manganosite 14.06 9.24 -4.82 -1.204 0.82237E+04 120 muscovite 2.58 -1.01 -3.59 -0.211 0.61315E+04 121 paragonite 4.24 1.09 -3.15 -0.185 0.53706E+04 122 nepheline 8.34 5.93 -2.41 -0.344 0.41125E+04 128 periclase-Fe 11.63 6.73 -4.89 -1.223 0.83523E+04 134 phlogopite-Na 29.65 27.50 -2.15 -0.119 0.36678E+04 136 prehnite 19.37 18.21 -1.16 -0.068 0.19849E+04 137 prehnite-Fe 22.50 21.96 -0.53 -0.032 0.91159E+03 138 pumpellyite-Fe 46.27 43.89 -2.38 -0.053 0.40582E+04 139 pumpellyite-Mg 48.99 46.45 -2.54 -0.057 0.43420E+04 143 pyrrhotite -4.26 -7.52 -3.26 -1.086 0.55622E+04 144 pyrrhotiteFe0.875 -6.02 -8.92 -2.90 -1.066 0.49494E+04 145 pyroxmangite 7.40 6.08 -1.31 -0.263 0.22441E+04 146 pyrophyllite -6.18 -11.15 -4.98 -0.311 0.84962E+04 147 quartz -2.99 -3.16 -0.17 -0.056 0.28680E+03 152 rhodonite 7.45 6.08 -1.36 -0.272 0.23244E+04 153 sanidine -1.28 -2.49 -1.21 -0.093 0.20677E+04 165 stilpnomelane-Mg 27.44 25.81 -1.63 -0.049 0.27804E+04 171 talc 16.49 15.25 -1.24 -0.073 0.21140E+04 174 tephroite 18.09 15.33 -2.76 -0.394 0.47119E+04 178 tridymite -2.63 -3.16 -0.53 -0.177 0.90677E+03 179 tremolite 47.87 47.42 -0.45 -0.012 0.77494E+03 180 ferroactinolite 38.45 34.62 -3.83 -0.104 0.65448E+04 181 troilite-low -4.41 -7.52 -3.11 -1.036 0.53050E+04 183 vesuvianite 223.47 218.82 -4.65 -0.036 0.79440E+04 187 wairakite 3.95 1.95 -2.00 -0.118 0.34155E+04 188 walstromite 11.51 9.94 -1.56 -0.313 0.26719E+04 189 wollastonite 10.46 9.94 -0.52 -0.103 0.88229E+03 190 pseudo-wollastonite 11.00 9.94 -1.06 -0.211 0.18021E+04 191 zoisite 22.85 18.95 -3.90 -0.177 0.66610E+04 192 akaganeite 7.75 4.49 -3.26 -0.705 0.55681E+04 199 chalcedony -2.80 -3.16 -0.35 -0.118 0.60609E+03 201 montmorillonite-Ca -2.29 -6.17 -3.88 -0.240 0.66180E+04 202 montmorillonite-K -2.24 -6.27 -4.03 -0.247 0.68816E+04 203 montmorillonite-Mg -2.48 -6.79 -4.32 -0.267 0.73678E+04 204 montmorillonite-Na -2.04 -5.57 -3.54 -0.216 0.60365E+04 205 nontronite-Ca 3.21 -0.19 -3.41 -0.221 0.58215E+04 206 nontronite-H 2.53 -2.36 -4.89 -0.328 0.83485E+04 207 nontronite-K 3.34 -0.30 -3.64 -0.233 0.62083E+04 208 nontronite-Mg 3.07 -0.82 -3.90 -0.253 0.66553E+04 209 nontronite-Na 3.52 0.40 -3.12 -0.200 0.53291E+04 224 tobermorite 9.82 7.76 -2.07 -0.564 0.35287E+04 230 alabandite -0.98 -5.01 -4.03 -1.344 0.68865E+04 233 boehmite 4.41 0.74 -3.67 -0.611 0.62619E+04 235 ferrous-oxide 9.81 6.73 -3.08 -0.769 0.52532E+04 240 silica-amorphous -2.09 -3.16 -1.07 -0.355 0.18203E+04 242 an20ab80 2.02 1.35 -0.67 -0.052 0.11472E+04 243 an25ab75 2.65 1.78 -0.87 -0.067 0.14810E+04 244 an30ab70 3.28 2.21 -1.07 -0.082 0.18244E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 100.0000000 g Current total amount of reactant added: 7099.9990000 g New total amount of reactant added: 7199.9990000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.5222E-10 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 12 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 7199.9990000 Water: Moles liquid = 0.1529E+02 kg liquid = 0.2754E+00 Moles total = -.3475E+02 kg total = -.6260E+00 Activity = 1.0000 Stoichiometric ionic strength = .1161851E-01 Osmotic coef. = 0.9679 True ionic strength = .2024294E-01 Chg. balance for total moles = 0.5222E-10 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.89274E-10 -10.0493 0.74960E-10 -10.1252 0.83967E+00 -0.0759 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.49869E-03 -3.3022 0.41619E-03 -3.3807 0.83457E+00 -0.0785 4 SO4-- 0.23327E-11 -11.6321 0.12078E-11 -11.9180 0.51779E+00 -0.2858 5 HCO3- 0.86257E-06 -6.0642 0.72094E-06 -6.1421 0.83580E+00 -0.0779 6 HS- 0.92592E-04 -4.0334 0.77286E-04 -4.1119 0.83470E+00 -0.0785 7 Al+++ 0.10062E-28 -28.9973 0.23092E-29 -29.6365 0.22949E+00 -0.6392 8 H4SiO4 0.69598E-03 -3.1574 0.69598E-03 -3.1574 0.10000E+01 0.0000 9 Ca++ 0.13822E-06 -6.8594 0.71038E-07 -7.1485 0.51396E+00 -0.2891 10 Mg++ 0.21624E-10 -10.6651 0.11062E-10 -10.9561 0.51159E+00 -0.2911 11 Fe++ 0.59599E-13 -13.2248 0.30524E-13 -13.5154 0.51215E+00 -0.2906 12 K+ 0.15826E-03 -3.8006 0.13230E-03 -3.8784 0.83600E+00 -0.0778 13 Na+ 0.20082E-01 -1.6972 0.16757E-01 -1.7758 0.83442E+00 -0.0786 14 Mn++ 0.19130E-10 -10.7183 0.98055E-11 -11.0085 0.51258E+00 -0.2902 15 HPO4-- 0.44522E-07 -7.3514 0.23057E-07 -7.6372 0.51787E+00 -0.2858 16 HSiO3- 0.10388E-01 -1.9835 0.86695E-02 -2.0620 0.83457E+00 -0.0785 17 Ca(HSiO3)+ 0.16773E-07 -7.7754 0.14026E-07 -7.8531 0.83618E+00 -0.0777 18 Mg(HSiO3)+ 0.32507E-11 -11.4880 0.27182E-11 -11.5657 0.83618E+00 -0.0777 19 NaHSiO3,aq 0.23497E-02 -2.6290 0.23497E-02 -2.6290 0.10000E+01 0.0000 20 AlO+ 0.66860E-16 -16.1748 0.55908E-16 -16.2525 0.83618E+00 -0.0777 22 HAlO2,aq 0.14853E-09 -9.8282 0.14853E-09 -9.8282 0.10000E+01 0.0000 23 AlO2- 0.52651E-05 -5.2786 0.43861E-05 -5.3579 0.83305E+00 -0.0793 24 CH4,aq 0.44969E-04 -4.3471 0.44810E-04 -4.3486 0.99646E+00 -0.0015 25 C2H6,aq 0.29743E-13 -13.5266 0.29637E-13 -13.5282 0.99646E+00 -0.0015 29 CO,aq 0.33598E-16 -16.4737 0.33598E-16 -16.4737 0.10000E+01 0.0000 30 CO2,aq 0.11588E-09 -9.9360 0.11547E-09 -9.9375 0.99646E+00 -0.0015 31 CO3-2 0.16259E-05 -5.7889 0.84006E-06 -6.0757 0.51669E+00 -0.2868 32 CaCO3,aq 0.74827E-09 -9.1259 0.74827E-09 -9.1259 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.15634E-11 -11.8059 0.13073E-11 -11.8836 0.83618E+00 -0.0777 34 CaCl+ 0.57219E-10 -10.2425 0.47846E-10 -10.3202 0.83618E+00 -0.0777 35 CaCl2,aq 0.47309E-14 -14.3251 0.47309E-14 -14.3251 0.10000E+01 0.0000 36 CaOH+ 0.80772E-07 -7.0927 0.67540E-07 -7.1704 0.83618E+00 -0.0777 37 CaSO4,aq 0.27246E-16 -16.5647 0.27246E-16 -16.5647 0.10000E+01 0.0000 38 HCl,aq 0.57169E-14 -14.2428 0.57169E-14 -14.2428 0.10000E+01 0.0000 43 FeCl+ 0.24047E-16 -16.6189 0.20108E-16 -16.6966 0.83618E+00 -0.0777 46 FeO,aq 0.21112E-09 -9.6755 0.21112E-09 -9.6755 0.10000E+01 0.0000 47 FeOH+ 0.15851E-10 -10.7999 0.13255E-10 -10.8776 0.83618E+00 -0.0777 48 HFeO2- 0.35311E-07 -7.4521 0.29469E-07 -7.5306 0.83457E+00 -0.0785 49 FeO+ 0.11110E-16 -16.9543 0.92896E-17 -17.0320 0.83618E+00 -0.0777 51 FeO2- 0.40534E-09 -9.3922 0.33829E-09 -9.4707 0.83457E+00 -0.0785 52 HFeO2,aq 0.32252E-11 -11.4915 0.32252E-11 -11.4915 0.10000E+01 0.0000 53 H2,aq 0.11624E-04 -4.9347 0.11582E-04 -4.9362 0.99646E+00 -0.0015 54 KCl,aq 0.99799E-09 -9.0009 0.99799E-09 -9.0009 0.10000E+01 0.0000 56 KOH,aq 0.75375E-06 -6.1228 0.75375E-06 -6.1228 0.10000E+01 0.0000 57 KSO4- 0.29713E-14 -14.5271 0.24798E-14 -14.6056 0.83457E+00 -0.0785 58 MgCO3,aq 0.29208E-13 -13.5345 0.29208E-13 -13.5345 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.24877E-15 -15.6042 0.20802E-15 -15.6819 0.83618E+00 -0.0777 60 MgCl+ 0.80761E-14 -14.0928 0.67531E-14 -14.1705 0.83618E+00 -0.0777 61 MgOH+ 0.69602E-10 -10.1574 0.58200E-10 -10.2351 0.83618E+00 -0.0777 63 MnO,aq 0.18072E-08 -8.7430 0.18072E-08 -8.7430 0.10000E+01 0.0000 64 MnOH+ 0.47304E-09 -9.3251 0.39555E-09 -9.4028 0.83618E+00 -0.0777 65 MnO2-2 0.20658E-10 -10.6849 0.10673E-10 -10.9717 0.51669E+00 -0.2868 66 HMnO2- 0.21003E-09 -9.6777 0.17529E-09 -9.7563 0.83457E+00 -0.0785 69 MnCl+ 0.30053E-13 -13.5221 0.25130E-13 -13.5998 0.83618E+00 -0.0777 71 NaCl,aq 0.23113E-05 -5.6361 0.23113E-05 -5.6361 0.10000E+01 0.0000 72 NaOH,aq 0.96047E-04 -4.0175 0.96047E-04 -4.0175 0.10000E+01 0.0000 74 OH- 0.92524E-02 -2.0337 0.77077E-02 -2.1131 0.83305E+00 -0.0793 79 HPO3-2 0.16107E-14 -14.7930 0.83222E-15 -15.0798 0.51669E+00 -0.2868 81 H2PO3- 0.14989E-18 -18.8242 0.12510E-18 -18.9027 0.83457E+00 -0.0785 82 H3PO4,aq 0.90612E-18 -18.0428 0.90612E-18 -18.0428 0.10000E+01 0.0000 83 H2PO4- 0.38167E-10 -10.4183 0.31883E-10 -10.4964 0.83537E+00 -0.0781 84 PO4-3 0.10407E-08 -8.9827 0.25096E-09 -9.6004 0.24114E+00 -0.6177 88 HP2O7-3 0.92423E-18 -18.0342 0.21232E-18 -18.6730 0.22973E+00 -0.6388 89 P2O7-4 0.88780E-17 -17.0517 0.67666E-18 -18.1696 0.76217E-01 -1.1179 90 H2S,aq 0.17969E-07 -7.7455 0.17905E-07 -7.7470 0.99646E+00 -0.0015 91 S2-2 0.22116E-13 -13.6553 0.11427E-13 -13.9421 0.51669E+00 -0.2868 97 SO3-2 0.34679E-17 -17.4599 0.18180E-17 -17.7404 0.52422E+00 -0.2805 98 HSO3- 0.10224E-19 -19.9904 0.85325E-20 -20.0689 0.83457E+00 -0.0785 99 HSO4- 0.10425E-18 -18.9819 0.87255E-19 -19.0592 0.83701E+00 -0.0773 Charge balance for all species = 0.1894E-09 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.8927406E-10 -.2211258E-01 -.2224917E+02 0.0000 2 H2O 0.1000000E+01 0.5550493E+02 0.9981892E+06 0.0000 3 Cl- 0.4986883E-03 0.5010007E-03 0.1773091E+02 6.7445 4 SO4-- 0.2332668E-11 -.4787526E-04 -.4590932E+01 8.3323 5 HCO3- 0.8625673E-06 0.4745872E-04 0.2890734E+01 3.9831 6 HS- 0.9259179E-04 0.1404850E-03 0.4637996E+01 6.0133 7 Al+++ 0.1006207E-28 0.5265253E-05 0.1418160E+00 0.7390 8 H4SiO4 0.6959834E-03 0.1343361E-01 0.1288919E+04 -3.1574 9 Ca++ 0.1382166E-06 0.2365684E-06 0.9464609E-02 13.1018 10 Mg++ 0.2162385E-10 0.9452069E-10 0.2293968E-05 9.2942 11 Fe++ 0.5959892E-13 0.3594618E-07 0.2003976E-02 6.7350 12 K+ 0.1582581E-03 0.1590129E-03 0.6206848E+01 6.2467 13 Na+ 0.2008249E-01 0.2253050E-01 0.5170659E+03 8.3494 14 Mn++ 0.1912959E-10 0.2530054E-08 0.1387530E-03 9.2418 15 HPO4-- 0.4452233E-07 0.4560121E-07 0.4369104E-02 12.6131 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.1192213E+03 -.6089741E-02 -.1192152E+03 0.0000000E+00 2 H2O -.3474669E+02 0.1528590E+02 -.5003259E+02 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.1995620E+00 -.1318471E-04 0.1995752E+00 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.1995365E+00 0.3868918E-04 -.1995752E+00 0.0000000E+00 7 Al+++ 0.2347734E+02 0.1450036E-05 0.2347733E+02 0.0000000E+00 8 H4SiO4 0.7497203E+02 0.3699579E-02 0.7496833E+02 0.0000000E+00 9 Ca++ 0.8281040E+01 0.6515029E-07 0.8281040E+01 0.0000000E+00 10 Mg++ 0.5714285E+01 0.2603073E-10 0.5714285E+01 0.0000000E+00 11 Fe++ 0.5133661E+01 0.9899478E-08 0.5133661E+01 0.0000000E+00 12 K+ 0.1528662E+01 0.4379170E-04 0.1528618E+01 0.0000000E+00 13 Na+ 0.9037913E+01 0.6204837E-02 0.9031708E+01 0.0000000E+00 14 Mn++ 0.1248379E+00 0.6967697E-09 0.1248379E+00 0.0000000E+00 15 HPO4-- 0.4260655E-01 0.1255845E-07 0.4260653E-01 0.0000000E+00 Chg. balance for solid moles: -.3109E-14 Mass of aqueous solution: 0.275880E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 7199.9990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 9.024 0.955 2366. 3.374 30.08 908.4 andradite 0.7983 -0.098 405.7 2.608 5.157 105.4 grossular 0.1933 -0.714 87.07 1.940 1.107 24.23 apatite-OH 0.1420E-01 -1.848 7.134 0.853 0.9070E-01 2.267 clinochlore 1.022 0.010 568.2 2.755 7.224 216.1 daphnite 0.2959 -0.529 211.2 2.325 2.685 63.99 chlorite-Mn 0.2497E-01 -1.603 17.70 1.248 0.2250 5.641 diopside 0.3824 -0.418 82.80 1.918 1.053 25.31 hedenbergite 0.9916E-01 -1.004 24.60 1.391 0.3128 6.738 microcline 1.340 0.127 373.1 2.572 4.743 145.7 stilbite 4.632 0.666 3264. 3.514 41.50 1523. stilpnomelane-Fe 0.3764 -0.424 405.8 2.608 5.159 140.2 tr.625ac.25prg.125 0.6082E-01 -1.216 51.99 1.716 0.6610 16.73 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8051E+00 0.8051E+00 1.0000 -0.094 grossular 0.1949E+00 0.1949E+00 1.0000 -0.710 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.7611E+00 0.7611E+00 1.0000 -0.119 daphnite 0.2203E+00 0.2203E+00 1.0000 -0.657 chlorite-Mn 0.1859E-01 0.1859E-01 1.0000 -1.731 diopside 0.7941E+00 0.7941E+00 1.0000 -0.100 hedenbergite 0.2059E+00 0.2059E+00 1.0000 -0.686 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 tr.625ac.25prg.125 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 7865.852472 g Volume = 3183.245262 cm3 Porosity: -10.4910% V(tot) - V(min): -.30225E+03 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 7199.9990000 g log = 3.8573 Original solution: 1000.0103000 g Original solution / Rock added: 0.14 (Water/Rock Ratio), log = -0.8573 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.1018 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9270E+00 0.9849 0.1006E+01 0.1021E+01 CO2,gas 0.1114E-07 1.0063 0.1235E-07 0.1228E-07 CH4,gas 0.5916E-01 1.0119 0.6596E-01 0.6518E-01 H2,gas 0.1379E-01 1.0006 0.1521E-01 0.1520E-01 H2S,gas 0.4487E-06 0.9957 0.4922E-06 0.4943E-06 S2,gas 0.3569E-28 1.0000 0.3933E-28 0.3933E-28 CO,gas 0.4544E-13 1.0000 0.5007E-13 0.5007E-13 SO3,gas 0.2329E-47 1.0000 0.2566E-47 0.2566E-47 SO2,gas 0.1378E-26 1.0000 0.1518E-26 0.1518E-26 HCl,gas 0.9156E-17 1.0000 0.1009E-16 0.1009E-16 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 16 albite -0.38 -0.38 0.00 0.000 -0.13080E-10 22 andradite 39.01 39.01 0.00 0.000 0.00000E+00 23 grossular 32.73 32.73 0.00 0.000 0.00000E+00 32 apatite-OH -18.15 -18.15 0.00 0.000 0.00000E+00 46 clinochlore 39.07 39.07 0.00 0.000 -0.12132E-10 47 daphnite 28.97 28.97 0.00 0.000 -0.60662E-11 48 chlorite-Mn 46.87 46.87 0.00 0.000 -0.24265E-10 67 diopside 16.18 16.18 0.00 0.000 -0.60662E-11 68 hedenbergite 14.21 14.21 0.00 0.000 0.00000E+00 116 microcline -2.49 -2.49 0.00 0.000 0.15165E-11 163 stilbite -7.52 -7.52 0.00 0.000 -0.33364E-10 164 stilpnomelane-Fe 13.02 13.02 0.00 0.000 0.21232E-10 245 tr.625ac.25prg.125 45.16 45.16 0.00 0.000 0.72794E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -16.27 -9.61 -3.202 0.16404E+05 -7.908 3 CH4,gas 4.54 1.66 -2.88 -0.720 0.49170E+04 -1.181 4 H2,gas 8.00 4.48 -3.52 -2.010 0.60051E+04 -1.818 5 H2S,gas -6.23 -14.24 -8.01 -4.003 0.13671E+05 -6.308 6 S2,gas -7.34 -37.44 -30.10 -4.631 0.51402E+05 -28.405 7 CO,gas 3.21 -11.78 -15.00 -4.615 0.25611E+05 -13.300 8 SO3,gas 17.12 -32.17 -49.29 -12.322 0.84161E+05 -47.591 9 SO2,gas 0.83 -27.69 -28.52 -7.605 0.48693E+05 -26.819 10 HCl,gas 5.19 -13.51 -18.70 -9.348 0.31922E+05 -16.996 11 acmite 7.71 6.53 -1.18 -0.123 0.20175E+04 15 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 19 spessartine 24.46 19.73 -4.73 -0.236 0.80698E+04 20 analcite 3.32 2.77 -0.55 -0.061 0.93626E+03 26 annite 20.12 17.72 -2.40 -0.134 0.41064E+04 27 phlogopite 27.06 25.40 -1.67 -0.093 0.28489E+04 29 anorthite 12.71 8.26 -4.45 -0.342 0.75903E+04 35 aragonite 0.97 -3.17 -4.13 -1.377 0.70552E+04 36 brucite 12.57 9.29 -3.27 -0.655 0.55909E+04 37 calcite 0.81 -3.17 -3.98 -1.326 0.67910E+04 38 carnegieite-low 9.02 5.93 -3.09 -0.442 0.52801E+04 39 carnegieite-high 10.09 5.93 -4.16 -0.595 0.71071E+04 40 carpholite-Mg 8.58 4.46 -4.12 -0.275 0.70429E+04 41 carpholite-Fe 6.71 1.90 -4.81 -0.321 0.82207E+04 42 celadonite 5.34 3.65 -1.69 -0.099 0.28879E+04 43 celadonite-Fe 3.88 1.09 -2.79 -0.164 0.47561E+04 44 chrysotile 23.89 21.57 -2.32 -0.194 0.39692E+04 49 chlorite-Al-free 47.17 43.14 -4.04 -0.168 0.68936E+04 51 chloritoid-Fe 9.17 5.06 -4.12 -0.275 0.70316E+04 52 chloritoid-Mn 11.40 7.56 -3.84 -0.256 0.65545E+04 54 coesite -2.38 -3.16 -0.78 -0.260 0.13341E+04 61 cristobalite -2.56 -3.16 -0.60 -0.199 0.10195E+04 63 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71234E+04 65 diaspore 2.87 0.74 -2.13 -0.356 0.36450E+04 66 diamond -3.10 -7.30 -4.20 -1.200 0.71701E+04 71 enstatite 17.26 12.27 -4.99 -0.499 0.85226E+04 73 clinoenstatite 17.17 12.27 -4.89 -0.489 0.83541E+04 75 epidote 24.67 22.70 -1.97 -0.095 0.33585E+04 76 clinozoisite 22.81 18.95 -3.86 -0.175 0.65869E+04 77 epidote-Fe 29.84 26.46 -3.38 -0.176 0.57768E+04 78 fayalite 14.05 10.31 -3.73 -0.533 0.63743E+04 79 ferrosilite 11.15 7.16 -3.99 -0.399 0.68202E+04 83 gibbsite 4.08 0.74 -3.34 -0.477 0.57035E+04 84 glaucophane 22.97 20.80 -2.17 -0.059 0.37134E+04 85 glaucophane-Fe 17.28 13.12 -4.15 -0.112 0.70919E+04 86 graphite -3.55 -7.30 -3.76 -1.073 0.64124E+04 87 greenalite 16.14 13.89 -2.25 -0.187 0.38408E+04 90 hematite 12.57 8.99 -3.58 -0.434 0.61111E+04 91 heulandite -5.83 -7.52 -1.69 -0.077 0.28938E+04 95 jadeite 4.22 2.77 -1.44 -0.144 0.24617E+04 97 kalsilite 7.58 3.83 -3.76 -0.537 0.64126E+04 98 kaolinite -1.33 -4.84 -3.50 -0.319 0.59832E+04 101 laumontite 2.88 1.95 -0.93 -0.062 0.15935E+04 102 lawsonite 9.62 8.26 -1.35 -0.090 0.23070E+04 103 leucite 4.12 0.67 -3.45 -0.345 0.58873E+04 105 lizardite 23.24 21.57 -1.68 -0.140 0.28619E+04 107 magnetite 20.09 15.72 -4.37 -0.356 0.74536E+04 108 minnesotaite 10.39 7.58 -2.81 -0.165 0.48027E+04 112 manganosite 14.06 9.24 -4.82 -1.204 0.82237E+04 120 muscovite 2.58 -1.01 -3.59 -0.211 0.61315E+04 121 paragonite 4.24 1.09 -3.15 -0.185 0.53706E+04 122 nepheline 8.34 5.93 -2.41 -0.344 0.41125E+04 128 periclase-Fe 11.63 6.73 -4.89 -1.223 0.83523E+04 134 phlogopite-Na 29.65 27.50 -2.15 -0.119 0.36678E+04 136 prehnite 19.37 18.21 -1.16 -0.068 0.19849E+04 137 prehnite-Fe 22.50 21.96 -0.53 -0.032 0.91159E+03 138 pumpellyite-Fe 46.27 43.89 -2.38 -0.053 0.40582E+04 139 pumpellyite-Mg 48.99 46.45 -2.54 -0.057 0.43421E+04 142 pyrite -21.25 -26.22 -4.98 -1.171 0.84947E+04 143 pyrrhotite -4.26 -7.50 -3.24 -1.081 0.55352E+04 144 pyrrhotiteFe0.875 -6.02 -8.90 -2.88 -1.060 0.49224E+04 145 pyroxmangite 7.40 6.08 -1.31 -0.263 0.22441E+04 146 pyrophyllite -6.18 -11.15 -4.98 -0.311 0.84962E+04 147 quartz -2.99 -3.16 -0.17 -0.056 0.28680E+03 152 rhodonite 7.45 6.08 -1.36 -0.272 0.23243E+04 153 sanidine -1.28 -2.49 -1.21 -0.093 0.20677E+04 165 stilpnomelane-Mg 27.44 25.81 -1.63 -0.049 0.27804E+04 171 talc 16.49 15.25 -1.24 -0.073 0.21140E+04 174 tephroite 18.09 15.33 -2.76 -0.394 0.47119E+04 178 tridymite -2.63 -3.16 -0.53 -0.177 0.90677E+03 179 tremolite 47.87 47.42 -0.45 -0.012 0.77494E+03 180 ferroactinolite 38.45 34.62 -3.83 -0.104 0.65448E+04 181 troilite-low -4.41 -7.50 -3.09 -1.030 0.52780E+04 183 vesuvianite 223.47 218.82 -4.65 -0.036 0.79440E+04 187 wairakite 3.95 1.95 -2.00 -0.118 0.34155E+04 188 walstromite 11.51 9.94 -1.56 -0.313 0.26719E+04 189 wollastonite 10.46 9.94 -0.52 -0.103 0.88229E+03 190 pseudo-wollastonite 11.00 9.94 -1.06 -0.211 0.18021E+04 191 zoisite 22.85 18.95 -3.90 -0.177 0.66610E+04 192 akaganeite 7.75 4.49 -3.26 -0.705 0.55681E+04 199 chalcedony -2.80 -3.16 -0.35 -0.118 0.60609E+03 201 montmorillonite-Ca -2.29 -6.17 -3.88 -0.240 0.66180E+04 202 montmorillonite-K -2.24 -6.27 -4.03 -0.247 0.68816E+04 203 montmorillonite-Mg -2.48 -6.79 -4.32 -0.267 0.73678E+04 204 montmorillonite-Na -2.04 -5.57 -3.54 -0.216 0.60365E+04 205 nontronite-Ca 3.21 -0.19 -3.41 -0.221 0.58215E+04 206 nontronite-H 2.53 -2.36 -4.89 -0.328 0.83485E+04 207 nontronite-K 3.34 -0.30 -3.64 -0.233 0.62083E+04 208 nontronite-Mg 3.07 -0.82 -3.90 -0.253 0.66553E+04 209 nontronite-Na 3.52 0.40 -3.12 -0.200 0.53291E+04 224 tobermorite 9.82 7.76 -2.07 -0.564 0.35287E+04 230 alabandite -0.98 -5.00 -4.02 -1.339 0.68596E+04 233 boehmite 4.41 0.74 -3.67 -0.611 0.62619E+04 235 ferrous-oxide 9.81 6.73 -3.08 -0.769 0.52532E+04 240 silica-amorphous -2.09 -3.16 -1.07 -0.355 0.18203E+04 242 an20ab80 2.02 1.35 -0.67 -0.052 0.11472E+04 243 an25ab75 2.65 1.78 -0.87 -0.067 0.14810E+04 244 an30ab70 3.28 2.21 -1.07 -0.082 0.18244E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 100.0000000 g Current total amount of reactant added: 7199.9990000 g New total amount of reactant added: 7299.9990000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.5221E-10 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 12 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 7299.9990000 Water: Moles liquid = 0.1473E+02 kg liquid = 0.2654E+00 Moles total = -.3600E+02 kg total = -.6486E+00 Activity = 1.0000 Stoichiometric ionic strength = .1163425E-01 Osmotic coef. = 0.9679 True ionic strength = .2025525E-01 Chg. balance for total moles = 0.5221E-10 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.89328E-10 -10.0490 0.75003E-10 -10.1249 0.83963E+00 -0.0759 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.51756E-03 -3.2860 0.43192E-03 -3.3646 0.83454E+00 -0.0786 4 SO4-- 0.24199E-11 -11.6162 0.12528E-11 -11.9021 0.51771E+00 -0.2859 5 HCO3- 0.89478E-06 -6.0483 0.74783E-06 -6.1262 0.83577E+00 -0.0779 6 HS- 0.96096E-04 -4.0173 0.80208E-04 -4.0958 0.83466E+00 -0.0785 7 Al+++ 0.10083E-28 -28.9964 0.23131E-29 -29.6358 0.22941E+00 -0.6394 8 H4SiO4 0.69598E-03 -3.1574 0.69598E-03 -3.1574 0.10000E+01 0.0000 9 Ca++ 0.13840E-06 -6.8589 0.71118E-07 -7.1480 0.51388E+00 -0.2891 10 Mg++ 0.21652E-10 -10.6645 0.11075E-10 -10.9557 0.51150E+00 -0.2912 11 Fe++ 0.59676E-13 -13.2242 0.30558E-13 -13.5149 0.51207E+00 -0.2907 12 K+ 0.15835E-03 -3.8004 0.13238E-03 -3.8782 0.83597E+00 -0.0778 13 Na+ 0.20095E-01 -1.6969 0.16767E-01 -1.7756 0.83439E+00 -0.0786 14 Mn++ 0.19155E-10 -10.7177 0.98167E-11 -11.0080 0.51250E+00 -0.2903 15 HPO4-- 0.44479E-07 -7.3518 0.23031E-07 -7.6377 0.51779E+00 -0.2858 16 HSiO3- 0.10383E-01 -1.9837 0.86646E-02 -2.0623 0.83454E+00 -0.0786 17 Ca(HSiO3)+ 0.16783E-07 -7.7751 0.14033E-07 -7.8528 0.83615E+00 -0.0777 18 Mg(HSiO3)+ 0.32527E-11 -11.4878 0.27197E-11 -11.5655 0.83615E+00 -0.0777 19 NaHSiO3,aq 0.23497E-02 -2.6290 0.23497E-02 -2.6290 0.10000E+01 0.0000 20 AlO+ 0.66901E-16 -16.1746 0.55939E-16 -16.2523 0.83615E+00 -0.0777 22 HAlO2,aq 0.14853E-09 -9.8282 0.14853E-09 -9.8282 0.10000E+01 0.0000 23 AlO2- 0.52624E-05 -5.2788 0.43836E-05 -5.3582 0.83302E+00 -0.0793 24 CH4,aq 0.46673E-04 -4.3309 0.46508E-04 -4.3325 0.99645E+00 -0.0015 25 C2H6,aq 0.32039E-13 -13.4943 0.31926E-13 -13.4959 0.99645E+00 -0.0015 29 CO,aq 0.34871E-16 -16.4575 0.34871E-16 -16.4575 0.10000E+01 0.0000 30 CO2,aq 0.12028E-09 -9.9198 0.11985E-09 -9.9214 0.99645E+00 -0.0015 31 CO3-2 0.16858E-05 -5.7732 0.87090E-06 -6.0600 0.51660E+00 -0.2868 32 CaCO3,aq 0.77662E-09 -9.1098 0.77662E-09 -9.1098 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.16236E-11 -11.7895 0.13576E-11 -11.8672 0.83615E+00 -0.0777 34 CaCl+ 0.59452E-10 -10.2258 0.49711E-10 -10.3036 0.83615E+00 -0.0777 35 CaCl2,aq 0.51011E-14 -14.2923 0.51011E-14 -14.2923 0.10000E+01 0.0000 36 CaOH+ 0.80820E-07 -7.0925 0.67578E-07 -7.1702 0.83615E+00 -0.0777 37 CaSO4,aq 0.28292E-16 -16.5483 0.28292E-16 -16.5483 0.10000E+01 0.0000 38 HCl,aq 0.59363E-14 -14.2265 0.59363E-14 -14.2265 0.10000E+01 0.0000 43 FeCl+ 0.24985E-16 -16.6023 0.20892E-16 -16.6800 0.83615E+00 -0.0777 46 FeO,aq 0.21112E-09 -9.6755 0.21112E-09 -9.6755 0.10000E+01 0.0000 47 FeOH+ 0.15861E-10 -10.7997 0.13262E-10 -10.8774 0.83615E+00 -0.0777 48 HFeO2- 0.35292E-07 -7.4523 0.29453E-07 -7.5309 0.83454E+00 -0.0786 49 FeO+ 0.11116E-16 -16.9540 0.92949E-17 -17.0318 0.83615E+00 -0.0777 51 FeO2- 0.40513E-09 -9.3924 0.33809E-09 -9.4710 0.83454E+00 -0.0786 52 HFeO2,aq 0.32252E-11 -11.4914 0.32252E-11 -11.4914 0.10000E+01 0.0000 53 H2,aq 0.11624E-04 -4.9347 0.11582E-04 -4.9362 0.99645E+00 -0.0015 54 KCl,aq 0.10363E-08 -8.9845 0.10363E-08 -8.9845 0.10000E+01 0.0000 56 KOH,aq 0.75375E-06 -6.1228 0.75375E-06 -6.1228 0.10000E+01 0.0000 57 KSO4- 0.30837E-14 -14.5109 0.25735E-14 -14.5895 0.83454E+00 -0.0786 58 MgCO3,aq 0.30315E-13 -13.5183 0.30315E-13 -13.5183 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.25835E-15 -15.5878 0.21602E-15 -15.6655 0.83615E+00 -0.0777 60 MgCl+ 0.83911E-14 -14.0762 0.70163E-14 -14.1539 0.83615E+00 -0.0777 61 MgOH+ 0.69644E-10 -10.1571 0.58233E-10 -10.2348 0.83615E+00 -0.0777 63 MnO,aq 0.18072E-08 -8.7430 0.18072E-08 -8.7430 0.10000E+01 0.0000 64 MnOH+ 0.47334E-09 -9.3248 0.39578E-09 -9.4025 0.83615E+00 -0.0777 65 MnO2-2 0.20638E-10 -10.6853 0.10662E-10 -10.9722 0.51660E+00 -0.2868 66 HMnO2- 0.20992E-09 -9.6779 0.17519E-09 -9.7565 0.83454E+00 -0.0786 69 MnCl+ 0.31227E-13 -13.5055 0.26110E-13 -13.5832 0.83615E+00 -0.0777 71 NaCl,aq 0.24000E-05 -5.6198 0.24000E-05 -5.6198 0.10000E+01 0.0000 72 NaOH,aq 0.96047E-04 -4.0175 0.96047E-04 -4.0175 0.10000E+01 0.0000 74 OH- 0.92475E-02 -2.0340 0.77034E-02 -2.1133 0.83302E+00 -0.0793 79 HPO3-2 0.16091E-14 -14.7934 0.83128E-15 -15.0803 0.51660E+00 -0.2868 81 H2PO3- 0.14982E-18 -18.8244 0.12503E-18 -18.9030 0.83454E+00 -0.0786 82 H3PO4,aq 0.90612E-18 -18.0428 0.90612E-18 -18.0428 0.10000E+01 0.0000 83 H2PO4- 0.38147E-10 -10.4185 0.31865E-10 -10.4967 0.83534E+00 -0.0781 84 PO4-3 0.10393E-08 -8.9833 0.25053E-09 -9.6011 0.24106E+00 -0.6179 88 HP2O7-3 0.92301E-18 -18.0348 0.21196E-18 -18.6737 0.22964E+00 -0.6389 89 P2O7-4 0.88636E-17 -17.0524 0.67513E-18 -18.1706 0.76169E-01 -1.1182 90 H2S,aq 0.18659E-07 -7.7291 0.18593E-07 -7.7307 0.99645E+00 -0.0015 91 S2-2 0.23824E-13 -13.6230 0.12307E-13 -13.9098 0.51660E+00 -0.2868 97 SO3-2 0.35975E-17 -17.4440 0.18856E-17 -17.7245 0.52414E+00 -0.2805 98 HSO3- 0.10611E-19 -19.9743 0.88550E-20 -20.0528 0.83454E+00 -0.0786 99 HSO4- 0.10819E-18 -18.9658 0.90554E-19 -19.0431 0.83697E+00 -0.0773 Charge balance for all species = 0.1968E-09 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.8932786E-10 -.2210236E-01 -.2223887E+02 0.0000 2 H2O 0.1000000E+01 0.5550493E+02 0.9981887E+06 0.0000 3 Cl- 0.5175605E-03 0.5199616E-03 0.1840195E+02 6.7603 4 SO4-- 0.2419875E-11 -.4957919E-04 -.4754325E+01 8.3477 5 HCO3- 0.8947788E-06 0.4925485E-04 0.3000135E+01 3.9987 6 HS- 0.9609602E-04 0.1456939E-03 0.4809958E+01 6.0291 7 Al+++ 0.1008280E-28 0.5262500E-05 0.1417417E+00 0.7390 8 H4SiO4 0.6959835E-03 0.1342818E-01 0.1288397E+04 -3.1574 9 Ca++ 0.1383952E-06 0.2368367E-06 0.9475335E-02 13.1018 10 Mg++ 0.2165185E-10 0.9459347E-10 0.2295733E-05 9.2942 11 Fe++ 0.5967606E-13 0.3592750E-07 0.2002933E-02 6.7350 12 K+ 0.1583538E-03 0.1591086E-03 0.6210581E+01 6.2467 13 Na+ 0.2009465E-01 0.2254275E-01 0.5173467E+03 8.3494 14 Mn++ 0.1915466E-10 0.2530278E-08 0.1387653E-03 9.2418 15 HPO4-- 0.4447920E-07 0.4555666E-07 0.4364833E-02 12.6122 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.1208771E+03 -.5864961E-02 -.1208713E+03 0.0000000E+00 2 H2O -.3600023E+02 0.1472849E+02 -.5072872E+02 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.2023334E+00 -.1315607E-04 0.2023465E+00 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.2023079E+00 0.3866054E-04 -.2023465E+00 0.0000000E+00 7 Al+++ 0.2380341E+02 0.1396428E-05 0.2380341E+02 0.0000000E+00 8 H4SiO4 0.7601331E+02 0.3563228E-02 0.7600974E+02 0.0000000E+00 9 Ca++ 0.8396055E+01 0.6284569E-07 0.8396055E+01 0.0000000E+00 10 Mg++ 0.5793650E+01 0.2510081E-10 0.5793650E+01 0.0000000E+00 11 Fe++ 0.5204962E+01 0.9533527E-08 0.5204962E+01 0.0000000E+00 12 K+ 0.1549894E+01 0.4222020E-04 0.1549851E+01 0.0000000E+00 13 Na+ 0.9163437E+01 0.5981822E-02 0.9157455E+01 0.0000000E+00 14 Mn++ 0.1265717E+00 0.6714209E-09 0.1265717E+00 0.0000000E+00 15 HPO4-- 0.4319830E-01 0.1208867E-07 0.4319829E-01 0.0000000E+00 Chg. balance for solid moles: 0.1484E-13 Mass of aqueous solution: 0.265820E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 7299.9990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 9.150 0.961 2399. 3.380 30.08 921.0 andradite 0.8094 -0.092 411.3 2.614 5.157 106.9 grossular 0.1960 -0.708 88.28 1.946 1.107 24.56 apatite-OH 0.1440E-01 -1.842 7.233 0.859 0.9070E-01 2.298 clinochlore 1.036 0.016 576.1 2.760 7.224 219.1 daphnite 0.3001 -0.523 214.1 2.331 2.684 64.88 chlorite-Mn 0.2531E-01 -1.597 17.95 1.254 0.2250 5.719 diopside 0.3878 -0.411 83.98 1.924 1.053 25.67 hedenbergite 0.1006 -0.998 24.95 1.397 0.3129 6.834 microcline 1.359 0.133 378.3 2.578 4.743 147.8 stilbite 4.696 0.672 3310. 3.520 41.50 1544. stilpnomelane-Fe 0.3817 -0.418 411.4 2.614 5.159 142.1 tr.625ac.25prg.125 0.6166E-01 -1.210 52.70 1.722 0.6608 16.96 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8051E+00 0.8051E+00 1.0000 -0.094 grossular 0.1949E+00 0.1949E+00 1.0000 -0.710 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.7611E+00 0.7611E+00 1.0000 -0.119 daphnite 0.2203E+00 0.2203E+00 1.0000 -0.657 chlorite-Mn 0.1859E-01 0.1859E-01 1.0000 -1.731 diopside 0.7941E+00 0.7941E+00 1.0000 -0.100 hedenbergite 0.2059E+00 0.2059E+00 1.0000 -0.686 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 tr.625ac.25prg.125 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 7975.103135 g Volume = 3227.448325 cm3 Porosity: -10.4912% V(tot) - V(min): -.30645E+03 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 7299.9990000 g log = 3.8633 Original solution: 1000.0103000 g Original solution / Rock added: 0.14 (Water/Rock Ratio), log = -0.8633 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.1043 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9250E+00 0.9849 0.1006E+01 0.1021E+01 CO2,gas 0.1154E-07 1.0063 0.1282E-07 0.1274E-07 CH4,gas 0.6127E-01 1.0118 0.6846E-01 0.6766E-01 H2,gas 0.1376E-01 1.0006 0.1521E-01 0.1520E-01 H2S,gas 0.4648E-06 0.9957 0.5111E-06 0.5133E-06 S2,gas 0.3840E-28 1.0000 0.4240E-28 0.4240E-28 CO,gas 0.4706E-13 1.0000 0.5197E-13 0.5197E-13 SO3,gas 0.2413E-47 1.0000 0.2665E-47 0.2665E-47 SO2,gas 0.1428E-26 1.0000 0.1576E-26 0.1576E-26 HCl,gas 0.9486E-17 1.0000 0.1047E-16 0.1047E-16 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 16 albite -0.38 -0.38 0.00 0.000 0.11184E-10 22 andradite 39.01 39.01 0.00 0.000 0.00000E+00 23 grossular 32.73 32.73 0.00 0.000 -0.12132E-10 32 apatite-OH -18.15 -18.15 0.00 0.000 -0.60662E-11 46 clinochlore 39.07 39.07 0.00 0.000 0.00000E+00 47 daphnite 28.97 28.97 0.00 0.000 0.30331E-10 48 chlorite-Mn 46.87 46.87 0.00 0.000 -0.24265E-10 67 diopside 16.18 16.18 0.00 0.000 0.00000E+00 68 hedenbergite 14.21 14.21 0.00 0.000 0.00000E+00 116 microcline -2.49 -2.49 0.00 0.000 0.13649E-10 163 stilbite -7.52 -7.52 0.00 0.000 0.39430E-10 164 stilpnomelane-Fe 13.02 13.02 0.00 0.000 0.21232E-10 245 tr.625ac.25prg.125 45.16 45.16 0.00 0.000 0.60662E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -16.25 -9.59 -3.197 0.16376E+05 -7.892 3 CH4,gas 4.54 1.68 -2.86 -0.716 0.48894E+04 -1.165 4 H2,gas 8.00 4.48 -3.52 -2.010 0.60051E+04 -1.818 5 H2S,gas -6.23 -14.22 -7.99 -3.995 0.13644E+05 -6.291 6 S2,gas -7.34 -37.41 -30.07 -4.626 0.51346E+05 -28.373 7 CO,gas 3.21 -11.77 -14.98 -4.610 0.25584E+05 -13.284 8 SO3,gas 17.12 -32.15 -49.27 -12.318 0.84133E+05 -47.574 9 SO2,gas 0.83 -27.67 -28.50 -7.600 0.48665E+05 -26.802 10 HCl,gas 5.19 -13.49 -18.68 -9.339 0.31894E+05 -16.980 11 acmite 7.71 6.53 -1.18 -0.123 0.20175E+04 15 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 19 spessartine 24.46 19.73 -4.73 -0.236 0.80698E+04 20 analcite 3.32 2.77 -0.55 -0.061 0.93626E+03 26 annite 20.12 17.72 -2.40 -0.134 0.41064E+04 27 phlogopite 27.06 25.40 -1.67 -0.093 0.28489E+04 29 anorthite 12.71 8.26 -4.45 -0.342 0.75903E+04 35 aragonite 0.97 -3.15 -4.12 -1.372 0.70276E+04 36 brucite 12.57 9.29 -3.27 -0.655 0.55909E+04 37 calcite 0.81 -3.15 -3.96 -1.320 0.67634E+04 38 carnegieite-low 9.02 5.93 -3.09 -0.442 0.52801E+04 39 carnegieite-high 10.09 5.93 -4.16 -0.595 0.71071E+04 40 carpholite-Mg 8.58 4.46 -4.12 -0.275 0.70429E+04 41 carpholite-Fe 6.71 1.90 -4.81 -0.321 0.82207E+04 42 celadonite 5.34 3.65 -1.69 -0.099 0.28879E+04 43 celadonite-Fe 3.88 1.09 -2.79 -0.164 0.47561E+04 44 chrysotile 23.89 21.57 -2.32 -0.194 0.39692E+04 49 chlorite-Al-free 47.17 43.14 -4.04 -0.168 0.68936E+04 51 chloritoid-Fe 9.17 5.06 -4.12 -0.275 0.70316E+04 52 chloritoid-Mn 11.40 7.56 -3.84 -0.256 0.65545E+04 54 coesite -2.38 -3.16 -0.78 -0.260 0.13341E+04 61 cristobalite -2.56 -3.16 -0.60 -0.199 0.10195E+04 63 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71234E+04 65 diaspore 2.87 0.74 -2.13 -0.356 0.36450E+04 66 diamond -3.10 -7.29 -4.18 -1.195 0.71425E+04 71 enstatite 17.26 12.27 -4.99 -0.499 0.85226E+04 73 clinoenstatite 17.17 12.27 -4.89 -0.489 0.83541E+04 75 epidote 24.67 22.70 -1.97 -0.095 0.33585E+04 76 clinozoisite 22.81 18.95 -3.86 -0.175 0.65869E+04 77 epidote-Fe 29.84 26.46 -3.38 -0.176 0.57768E+04 78 fayalite 14.05 10.31 -3.73 -0.533 0.63743E+04 79 ferrosilite 11.15 7.16 -3.99 -0.399 0.68202E+04 83 gibbsite 4.08 0.74 -3.34 -0.477 0.57035E+04 84 glaucophane 22.97 20.80 -2.17 -0.059 0.37134E+04 85 glaucophane-Fe 17.28 13.12 -4.15 -0.112 0.70919E+04 86 graphite -3.55 -7.29 -3.74 -1.068 0.63848E+04 87 greenalite 16.14 13.89 -2.25 -0.187 0.38408E+04 90 hematite 12.57 8.99 -3.58 -0.434 0.61111E+04 91 heulandite -5.83 -7.52 -1.69 -0.077 0.28938E+04 95 jadeite 4.22 2.77 -1.44 -0.144 0.24617E+04 97 kalsilite 7.58 3.83 -3.76 -0.537 0.64126E+04 98 kaolinite -1.33 -4.84 -3.50 -0.319 0.59832E+04 101 laumontite 2.88 1.95 -0.93 -0.062 0.15935E+04 102 lawsonite 9.62 8.26 -1.35 -0.090 0.23070E+04 103 leucite 4.12 0.67 -3.45 -0.345 0.58873E+04 105 lizardite 23.24 21.57 -1.68 -0.140 0.28619E+04 107 magnetite 20.09 15.72 -4.37 -0.356 0.74536E+04 108 minnesotaite 10.39 7.58 -2.81 -0.165 0.48027E+04 112 manganosite 14.06 9.24 -4.82 -1.204 0.82237E+04 120 muscovite 2.58 -1.01 -3.59 -0.211 0.61315E+04 121 paragonite 4.24 1.09 -3.15 -0.185 0.53706E+04 122 nepheline 8.34 5.93 -2.41 -0.344 0.41125E+04 128 periclase-Fe 11.63 6.73 -4.89 -1.223 0.83523E+04 134 phlogopite-Na 29.65 27.50 -2.15 -0.119 0.36678E+04 136 prehnite 19.37 18.21 -1.16 -0.068 0.19849E+04 137 prehnite-Fe 22.50 21.96 -0.53 -0.032 0.91159E+03 138 pumpellyite-Fe 46.27 43.89 -2.38 -0.053 0.40582E+04 139 pumpellyite-Mg 48.99 46.45 -2.54 -0.057 0.43421E+04 142 pyrite -21.25 -26.19 -4.94 -1.163 0.84389E+04 143 pyrrhotite -4.26 -7.49 -3.23 -1.075 0.55073E+04 144 pyrrhotiteFe0.875 -6.02 -8.88 -2.87 -1.054 0.48945E+04 145 pyroxmangite 7.40 6.08 -1.31 -0.263 0.22441E+04 146 pyrophyllite -6.18 -11.15 -4.98 -0.311 0.84962E+04 147 quartz -2.99 -3.16 -0.17 -0.056 0.28680E+03 152 rhodonite 7.45 6.08 -1.36 -0.272 0.23243E+04 153 sanidine -1.28 -2.49 -1.21 -0.093 0.20677E+04 165 stilpnomelane-Mg 27.44 25.81 -1.63 -0.049 0.27804E+04 171 talc 16.49 15.25 -1.24 -0.073 0.21140E+04 174 tephroite 18.09 15.33 -2.76 -0.394 0.47119E+04 178 tridymite -2.63 -3.16 -0.53 -0.177 0.90677E+03 179 tremolite 47.87 47.42 -0.45 -0.012 0.77494E+03 180 ferroactinolite 38.45 34.62 -3.83 -0.104 0.65448E+04 181 troilite-low -4.41 -7.49 -3.07 -1.025 0.52501E+04 183 vesuvianite 223.47 218.82 -4.65 -0.036 0.79440E+04 187 wairakite 3.95 1.95 -2.00 -0.118 0.34155E+04 188 walstromite 11.51 9.94 -1.56 -0.313 0.26719E+04 189 wollastonite 10.46 9.94 -0.52 -0.103 0.88229E+03 190 pseudo-wollastonite 11.00 9.94 -1.06 -0.211 0.18021E+04 191 zoisite 22.85 18.95 -3.90 -0.177 0.66610E+04 192 akaganeite 7.75 4.49 -3.26 -0.705 0.55681E+04 199 chalcedony -2.80 -3.16 -0.35 -0.118 0.60609E+03 201 montmorillonite-Ca -2.29 -6.17 -3.88 -0.240 0.66180E+04 202 montmorillonite-K -2.24 -6.27 -4.03 -0.247 0.68816E+04 203 montmorillonite-Mg -2.48 -6.79 -4.32 -0.267 0.73678E+04 204 montmorillonite-Na -2.04 -5.57 -3.54 -0.216 0.60365E+04 205 nontronite-Ca 3.21 -0.19 -3.41 -0.221 0.58215E+04 206 nontronite-H 2.53 -2.36 -4.89 -0.328 0.83485E+04 207 nontronite-K 3.34 -0.30 -3.64 -0.233 0.62083E+04 208 nontronite-Mg 3.07 -0.82 -3.90 -0.253 0.66553E+04 209 nontronite-Na 3.52 0.40 -3.12 -0.200 0.53291E+04 224 tobermorite 9.82 7.76 -2.07 -0.564 0.35287E+04 230 alabandite -0.98 -4.98 -4.00 -1.334 0.68316E+04 233 boehmite 4.41 0.74 -3.67 -0.611 0.62619E+04 235 ferrous-oxide 9.81 6.73 -3.08 -0.769 0.52532E+04 240 silica-amorphous -2.09 -3.16 -1.07 -0.355 0.18203E+04 242 an20ab80 2.02 1.35 -0.67 -0.052 0.11472E+04 243 an25ab75 2.65 1.78 -0.87 -0.067 0.14810E+04 244 an30ab70 3.28 2.21 -1.07 -0.082 0.18244E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 100.0000000 g Current total amount of reactant added: 7299.9990000 g New total amount of reactant added: 7399.9990000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.5222E-10 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 12 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 7399.9990000 Water: Moles liquid = 0.1417E+02 kg liquid = 0.2553E+00 Moles total = -.3725E+02 kg total = -.6711E+00 Activity = 1.0000 Stoichiometric ionic strength = .1165122E-01 Osmotic coef. = 0.9679 True ionic strength = .2026855E-01 Chg. balance for total moles = 0.5222E-10 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.89386E-10 -10.0487 0.75048E-10 -10.1247 0.83960E+00 -0.0759 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.53792E-03 -3.2693 0.44889E-03 -3.3479 0.83450E+00 -0.0786 4 SO4-- 0.25139E-11 -11.5997 0.13012E-11 -11.8856 0.51762E+00 -0.2860 5 HCO3- 0.92949E-06 -6.0318 0.77681E-06 -6.1097 0.83573E+00 -0.0779 6 HS- 0.99876E-04 -4.0005 0.83359E-04 -4.0790 0.83462E+00 -0.0785 7 Al+++ 0.10105E-28 -28.9955 0.23173E-29 -29.6350 0.22932E+00 -0.6396 8 H4SiO4 0.69598E-03 -3.1574 0.69598E-03 -3.1574 0.10000E+01 0.0000 9 Ca++ 0.13859E-06 -6.8583 0.71205E-07 -7.1475 0.51379E+00 -0.2892 10 Mg++ 0.21682E-10 -10.6639 0.11088E-10 -10.9551 0.51141E+00 -0.2912 11 Fe++ 0.59759E-13 -13.2236 0.30595E-13 -13.5143 0.51198E+00 -0.2907 12 K+ 0.15846E-03 -3.8001 0.13246E-03 -3.8779 0.83593E+00 -0.0778 13 Na+ 0.20108E-01 -1.6966 0.16777E-01 -1.7753 0.83435E+00 -0.0787 14 Mn++ 0.19182E-10 -10.7171 0.98288E-11 -11.0075 0.51241E+00 -0.2904 15 HPO4-- 0.44433E-07 -7.3523 0.23003E-07 -7.6382 0.51770E+00 -0.2859 16 HSiO3- 0.10377E-01 -1.9839 0.86593E-02 -2.0625 0.83450E+00 -0.0786 17 Ca(HSiO3)+ 0.16794E-07 -7.7748 0.14042E-07 -7.8526 0.83612E+00 -0.0777 18 Mg(HSiO3)+ 0.32548E-11 -11.4875 0.27214E-11 -11.5652 0.83612E+00 -0.0777 19 NaHSiO3,aq 0.23497E-02 -2.6290 0.23497E-02 -2.6290 0.10000E+01 0.0000 20 AlO+ 0.66944E-16 -16.1743 0.55973E-16 -16.2520 0.83612E+00 -0.0777 22 HAlO2,aq 0.14853E-09 -9.8282 0.14853E-09 -9.8282 0.10000E+01 0.0000 23 AlO2- 0.52594E-05 -5.2791 0.43810E-05 -5.3584 0.83298E+00 -0.0794 24 CH4,aq 0.48511E-04 -4.3142 0.48339E-04 -4.3157 0.99645E+00 -0.0015 25 C2H6,aq 0.34612E-13 -13.4608 0.34489E-13 -13.4623 0.99645E+00 -0.0015 29 CO,aq 0.36244E-16 -16.4408 0.36244E-16 -16.4408 0.10000E+01 0.0000 30 CO2,aq 0.12501E-09 -9.9030 0.12457E-09 -9.9046 0.99645E+00 -0.0015 31 CO3-2 0.17504E-05 -5.7569 0.90410E-06 -6.0438 0.51651E+00 -0.2869 32 CaCO3,aq 0.80720E-09 -9.0930 0.80720E-09 -9.0930 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.16886E-11 -11.7725 0.14119E-11 -11.8502 0.83612E+00 -0.0777 34 CaCl+ 0.61865E-10 -10.2086 0.51727E-10 -10.2863 0.83612E+00 -0.0777 35 CaCl2,aq 0.55165E-14 -14.2583 0.55165E-14 -14.2583 0.10000E+01 0.0000 36 CaOH+ 0.80873E-07 -7.0922 0.67619E-07 -7.1699 0.83612E+00 -0.0777 37 CaSO4,aq 0.29422E-16 -16.5313 0.29422E-16 -16.5313 0.10000E+01 0.0000 38 HCl,aq 0.61733E-14 -14.2095 0.61733E-14 -14.2095 0.10000E+01 0.0000 43 FeCl+ 0.26000E-16 -16.5850 0.21739E-16 -16.6628 0.83612E+00 -0.0777 46 FeO,aq 0.21112E-09 -9.6755 0.21112E-09 -9.6755 0.10000E+01 0.0000 47 FeOH+ 0.15871E-10 -10.7994 0.13270E-10 -10.8771 0.83612E+00 -0.0777 48 HFeO2- 0.35272E-07 -7.4526 0.29435E-07 -7.5311 0.83450E+00 -0.0786 49 FeO+ 0.11123E-16 -16.9538 0.93005E-17 -17.0315 0.83612E+00 -0.0777 51 FeO2- 0.40490E-09 -9.3927 0.33789E-09 -9.4712 0.83450E+00 -0.0786 52 HFeO2,aq 0.32252E-11 -11.4914 0.32252E-11 -11.4914 0.10000E+01 0.0000 53 H2,aq 0.11624E-04 -4.9347 0.11582E-04 -4.9362 0.99645E+00 -0.0015 54 KCl,aq 0.10777E-08 -8.9675 0.10777E-08 -8.9675 0.10000E+01 0.0000 56 KOH,aq 0.75375E-06 -6.1228 0.75375E-06 -6.1228 0.10000E+01 0.0000 57 KSO4- 0.32050E-14 -14.4942 0.26746E-14 -14.5727 0.83450E+00 -0.0786 58 MgCO3,aq 0.31508E-13 -13.5016 0.31508E-13 -13.5016 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.26870E-15 -15.5707 0.22467E-15 -15.6485 0.83612E+00 -0.0777 60 MgCl+ 0.87318E-14 -14.0589 0.73008E-14 -14.1366 0.83612E+00 -0.0777 61 MgOH+ 0.69690E-10 -10.1568 0.58269E-10 -10.2346 0.83612E+00 -0.0777 63 MnO,aq 0.18072E-08 -8.7430 0.18072E-08 -8.7430 0.10000E+01 0.0000 64 MnOH+ 0.47365E-09 -9.3245 0.39603E-09 -9.4023 0.83612E+00 -0.0777 65 MnO2-2 0.20617E-10 -10.6858 0.10649E-10 -10.9727 0.51651E+00 -0.2869 66 HMnO2- 0.20981E-09 -9.6782 0.17509E-09 -9.7567 0.83450E+00 -0.0786 69 MnCl+ 0.32495E-13 -13.4882 0.27169E-13 -13.5659 0.83612E+00 -0.0777 71 NaCl,aq 0.24958E-05 -5.6028 0.24958E-05 -5.6028 0.10000E+01 0.0000 72 NaOH,aq 0.96047E-04 -4.0175 0.96047E-04 -4.0175 0.10000E+01 0.0000 74 OH- 0.92423E-02 -2.0342 0.76987E-02 -2.1136 0.83298E+00 -0.0794 79 HPO3-2 0.16075E-14 -14.7939 0.83027E-15 -15.0808 0.51651E+00 -0.2869 81 H2PO3- 0.14973E-18 -18.8247 0.12495E-18 -18.9033 0.83450E+00 -0.0786 82 H3PO4,aq 0.90612E-18 -18.0428 0.90612E-18 -18.0428 0.10000E+01 0.0000 83 H2PO4- 0.38125E-10 -10.4188 0.31846E-10 -10.4969 0.83530E+00 -0.0782 84 PO4-3 0.10378E-08 -8.9839 0.25007E-09 -9.6019 0.24097E+00 -0.6180 88 HP2O7-3 0.92168E-18 -18.0354 0.21157E-18 -18.6745 0.22955E+00 -0.6391 89 P2O7-4 0.88481E-17 -17.0531 0.67349E-18 -18.1717 0.76117E-01 -1.1185 90 H2S,aq 0.19404E-07 -7.7121 0.19335E-07 -7.7137 0.99645E+00 -0.0015 91 S2-2 0.25737E-13 -13.5894 0.13293E-13 -13.8764 0.51651E+00 -0.2869 97 SO3-2 0.37372E-17 -17.4275 0.19585E-17 -17.7081 0.52406E+00 -0.2806 98 HSO3- 0.11028E-19 -19.9575 0.92029E-20 -20.0361 0.83450E+00 -0.0786 99 HSO4- 0.11245E-18 -18.9490 0.94112E-19 -19.0264 0.83694E+00 -0.0773 Charge balance for all species = 0.2045E-09 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.8938592E-10 -.2209134E-01 -.2222778E+02 0.0000 2 H2O 0.1000000E+01 0.5550493E+02 0.9981881E+06 0.0000 3 Cl- 0.5379172E-03 0.5404141E-03 0.1912577E+02 6.7768 4 SO4-- 0.2513855E-11 -.5141733E-04 -.4930587E+01 8.3637 5 HCO3- 0.9294889E-06 0.5119228E-04 0.3118143E+01 4.0150 6 HS- 0.9987592E-04 0.1513127E-03 0.4995455E+01 6.0456 7 Al+++ 0.1010520E-28 0.5259532E-05 0.1416617E+00 0.7390 8 H4SiO4 0.6959836E-03 0.1342232E-01 0.1287834E+04 -3.1574 9 Ca++ 0.1385882E-06 0.2371263E-06 0.9486916E-02 13.1018 10 Mg++ 0.2168208E-10 0.9467198E-10 0.2297637E-05 9.2942 11 Fe++ 0.5975937E-13 0.3590736E-07 0.2001809E-02 6.7350 12 K+ 0.1584571E-03 0.1592119E-03 0.6214609E+01 6.2467 13 Na+ 0.2010778E-01 0.2255597E-01 0.5176498E+03 8.3494 14 Mn++ 0.1918171E-10 0.2530517E-08 0.1387782E-03 9.2418 15 HPO4-- 0.4443273E-07 0.4550865E-07 0.4360231E-02 12.6111 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.1225330E+03 -.5640183E-02 -.1225273E+03 0.0000000E+00 2 H2O -.3725377E+02 0.1417107E+02 -.5142485E+02 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.2051047E+00 -.1312746E-04 0.2051178E+00 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.2050792E+00 0.3863193E-04 -.2051178E+00 0.0000000E+00 7 Al+++ 0.2412948E+02 0.1342821E-05 0.2412948E+02 0.0000000E+00 8 H4SiO4 0.7705458E+02 0.3426878E-02 0.7705116E+02 0.0000000E+00 9 Ca++ 0.8511069E+01 0.6054118E-07 0.8511069E+01 0.0000000E+00 10 Mg++ 0.5873015E+01 0.2417089E-10 0.5873015E+01 0.0000000E+00 11 Fe++ 0.5276263E+01 0.9167578E-08 0.5276263E+01 0.0000000E+00 12 K+ 0.1571125E+01 0.4064870E-04 0.1571084E+01 0.0000000E+00 13 Na+ 0.9288962E+01 0.5758809E-02 0.9283203E+01 0.0000000E+00 14 Mn++ 0.1283056E+00 0.6460711E-09 0.1283056E+00 0.0000000E+00 15 HPO4-- 0.4379006E-01 0.1161890E-07 0.4379005E-01 0.0000000E+00 Chg. balance for solid moles: 0.4399E-14 Mass of aqueous solution: 0.255760E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 7399.9990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 9.275 0.967 2432. 3.386 30.09 933.7 andradite 0.8205 -0.086 416.9 2.620 5.157 108.3 grossular 0.1987 -0.702 89.49 1.952 1.107 24.90 apatite-OH 0.1460E-01 -1.836 7.332 0.865 0.9070E-01 2.330 clinochlore 1.051 0.021 584.0 2.766 7.224 222.1 daphnite 0.3042 -0.517 217.0 2.336 2.684 65.76 chlorite-Mn 0.2566E-01 -1.591 18.19 1.260 0.2250 5.798 diopside 0.3932 -0.405 85.16 1.930 1.053 26.03 hedenbergite 0.1020 -0.991 25.30 1.403 0.3130 6.930 microcline 1.378 0.139 383.5 2.584 4.743 149.8 stilbite 4.760 0.678 3355. 3.526 41.50 1565. stilpnomelane-Fe 0.3869 -0.412 417.1 2.620 5.159 144.1 tr.625ac.25prg.125 0.6249E-01 -1.204 53.42 1.728 0.6607 17.19 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8051E+00 0.8051E+00 1.0000 -0.094 grossular 0.1949E+00 0.1949E+00 1.0000 -0.710 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.7611E+00 0.7611E+00 1.0000 -0.119 daphnite 0.2203E+00 0.2203E+00 1.0000 -0.657 chlorite-Mn 0.1859E-01 0.1859E-01 1.0000 -1.731 diopside 0.7941E+00 0.7941E+00 1.0000 -0.100 hedenbergite 0.2059E+00 0.2059E+00 1.0000 -0.686 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 tr.625ac.25prg.125 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 8084.353798 g Volume = 3271.651388 cm3 Porosity: -10.4914% V(tot) - V(min): -.31065E+03 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 7399.9990000 g log = 3.8692 Original solution: 1000.0103000 g Original solution / Rock added: 0.14 (Water/Rock Ratio), log = -0.8692 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.1070 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9227E+00 0.9848 0.1006E+01 0.1021E+01 CO2,gas 0.1197E-07 1.0062 0.1333E-07 0.1325E-07 CH4,gas 0.6353E-01 1.0118 0.7115E-01 0.7032E-01 H2,gas 0.1373E-01 1.0006 0.1521E-01 0.1520E-01 H2S,gas 0.4822E-06 0.9957 0.5315E-06 0.5338E-06 S2,gas 0.4143E-28 1.0000 0.4586E-28 0.4586E-28 CO,gas 0.4879E-13 1.0000 0.5401E-13 0.5401E-13 SO3,gas 0.2503E-47 1.0000 0.2771E-47 0.2771E-47 SO2,gas 0.1481E-26 1.0000 0.1639E-26 0.1639E-26 HCl,gas 0.9840E-17 1.0000 0.1089E-16 0.1089E-16 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 16 albite -0.38 -0.38 0.00 0.000 -0.94784E-12 22 andradite 39.01 39.01 0.00 0.000 -0.12132E-10 23 grossular 32.73 32.73 0.00 0.000 0.00000E+00 32 apatite-OH -18.15 -18.15 0.00 0.000 -0.60662E-11 46 clinochlore 39.07 39.07 0.00 0.000 -0.12132E-10 47 daphnite 28.97 28.97 0.00 0.000 -0.30331E-10 48 chlorite-Mn 46.87 46.87 0.00 0.000 -0.24265E-10 67 diopside 16.18 16.18 0.00 0.000 -0.60662E-11 68 hedenbergite 14.21 14.21 0.00 0.000 -0.60662E-11 116 microcline -2.49 -2.49 0.00 0.000 -0.10616E-10 163 stilbite -7.52 -7.52 0.00 0.000 -0.90992E-11 164 stilpnomelane-Fe 13.02 13.02 0.00 0.000 -0.75827E-10 245 tr.625ac.25prg.125 45.16 45.16 0.00 0.000 -0.60662E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -16.23 -9.57 -3.191 0.16348E+05 -7.875 3 CH4,gas 4.54 1.70 -2.85 -0.712 0.48608E+04 -1.148 4 H2,gas 8.00 4.48 -3.52 -2.010 0.60051E+04 -1.818 5 H2S,gas -6.23 -14.20 -7.97 -3.987 0.13614E+05 -6.274 6 S2,gas -7.34 -37.37 -30.04 -4.621 0.51288E+05 -28.339 7 CO,gas 3.21 -11.75 -14.97 -4.605 0.25555E+05 -13.268 8 SO3,gas 17.12 -32.13 -49.26 -12.314 0.84104E+05 -47.557 9 SO2,gas 0.83 -27.65 -28.48 -7.596 0.48636E+05 -26.785 10 HCl,gas 5.19 -13.47 -18.66 -9.331 0.31865E+05 -16.963 11 acmite 7.71 6.53 -1.18 -0.123 0.20175E+04 15 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 19 spessartine 24.46 19.73 -4.73 -0.236 0.80698E+04 20 analcite 3.32 2.77 -0.55 -0.061 0.93626E+03 26 annite 20.12 17.72 -2.40 -0.134 0.41064E+04 27 phlogopite 27.06 25.40 -1.67 -0.093 0.28489E+04 29 anorthite 12.71 8.26 -4.45 -0.342 0.75903E+04 35 aragonite 0.97 -3.13 -4.10 -1.366 0.69990E+04 36 brucite 12.57 9.29 -3.27 -0.655 0.55909E+04 37 calcite 0.81 -3.13 -3.94 -1.315 0.67348E+04 38 carnegieite-low 9.02 5.93 -3.09 -0.442 0.52801E+04 39 carnegieite-high 10.09 5.93 -4.16 -0.595 0.71071E+04 40 carpholite-Mg 8.58 4.46 -4.12 -0.275 0.70429E+04 41 carpholite-Fe 6.71 1.90 -4.81 -0.321 0.82207E+04 42 celadonite 5.34 3.65 -1.69 -0.099 0.28879E+04 43 celadonite-Fe 3.88 1.09 -2.79 -0.164 0.47561E+04 44 chrysotile 23.89 21.57 -2.32 -0.194 0.39692E+04 49 chlorite-Al-free 47.17 43.14 -4.04 -0.168 0.68936E+04 51 chloritoid-Fe 9.17 5.06 -4.12 -0.275 0.70316E+04 52 chloritoid-Mn 11.40 7.56 -3.84 -0.256 0.65545E+04 54 coesite -2.38 -3.16 -0.78 -0.260 0.13341E+04 61 cristobalite -2.56 -3.16 -0.60 -0.199 0.10195E+04 63 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71234E+04 65 diaspore 2.87 0.74 -2.13 -0.356 0.36450E+04 66 diamond -3.10 -7.27 -4.17 -1.190 0.71139E+04 71 enstatite 17.26 12.27 -4.99 -0.499 0.85226E+04 73 clinoenstatite 17.17 12.27 -4.89 -0.489 0.83541E+04 75 epidote 24.67 22.70 -1.97 -0.095 0.33585E+04 76 clinozoisite 22.81 18.95 -3.86 -0.175 0.65869E+04 77 epidote-Fe 29.84 26.46 -3.38 -0.176 0.57768E+04 78 fayalite 14.05 10.31 -3.73 -0.533 0.63743E+04 79 ferrosilite 11.15 7.16 -3.99 -0.399 0.68202E+04 83 gibbsite 4.08 0.74 -3.34 -0.477 0.57035E+04 84 glaucophane 22.97 20.80 -2.17 -0.059 0.37134E+04 85 glaucophane-Fe 17.28 13.12 -4.15 -0.112 0.70919E+04 86 graphite -3.55 -7.27 -3.72 -1.064 0.63561E+04 87 greenalite 16.14 13.89 -2.25 -0.187 0.38408E+04 90 hematite 12.57 8.99 -3.58 -0.434 0.61111E+04 91 heulandite -5.83 -7.52 -1.69 -0.077 0.28938E+04 95 jadeite 4.22 2.77 -1.44 -0.144 0.24617E+04 97 kalsilite 7.58 3.83 -3.76 -0.537 0.64126E+04 98 kaolinite -1.33 -4.84 -3.50 -0.319 0.59832E+04 101 laumontite 2.88 1.95 -0.93 -0.062 0.15935E+04 102 lawsonite 9.62 8.26 -1.35 -0.090 0.23070E+04 103 leucite 4.12 0.67 -3.45 -0.345 0.58873E+04 105 lizardite 23.24 21.57 -1.68 -0.140 0.28619E+04 107 magnetite 20.09 15.72 -4.37 -0.356 0.74536E+04 108 minnesotaite 10.39 7.58 -2.81 -0.165 0.48027E+04 112 manganosite 14.06 9.24 -4.82 -1.204 0.82237E+04 120 muscovite 2.58 -1.01 -3.59 -0.211 0.61315E+04 121 paragonite 4.24 1.09 -3.15 -0.185 0.53706E+04 122 nepheline 8.34 5.93 -2.41 -0.344 0.41125E+04 128 periclase-Fe 11.63 6.73 -4.89 -1.223 0.83523E+04 134 phlogopite-Na 29.65 27.50 -2.15 -0.119 0.36678E+04 136 prehnite 19.37 18.21 -1.16 -0.068 0.19849E+04 137 prehnite-Fe 22.50 21.96 -0.53 -0.032 0.91159E+03 138 pumpellyite-Fe 46.27 43.89 -2.38 -0.053 0.40582E+04 139 pumpellyite-Mg 48.99 46.45 -2.54 -0.057 0.43421E+04 142 pyrite -21.25 -26.16 -4.91 -1.155 0.83808E+04 143 pyrrhotite -4.26 -7.47 -3.21 -1.069 0.54783E+04 144 pyrrhotiteFe0.875 -6.02 -8.87 -2.85 -1.048 0.48655E+04 145 pyroxmangite 7.40 6.08 -1.31 -0.263 0.22441E+04 146 pyrophyllite -6.18 -11.15 -4.98 -0.311 0.84962E+04 147 quartz -2.99 -3.16 -0.17 -0.056 0.28680E+03 152 rhodonite 7.45 6.08 -1.36 -0.272 0.23243E+04 153 sanidine -1.28 -2.49 -1.21 -0.093 0.20677E+04 165 stilpnomelane-Mg 27.44 25.81 -1.63 -0.049 0.27804E+04 171 talc 16.49 15.25 -1.24 -0.073 0.21140E+04 174 tephroite 18.09 15.33 -2.76 -0.394 0.47119E+04 178 tridymite -2.63 -3.16 -0.53 -0.177 0.90677E+03 179 tremolite 47.87 47.42 -0.45 -0.012 0.77494E+03 180 ferroactinolite 38.45 34.62 -3.83 -0.104 0.65448E+04 181 troilite-low -4.41 -7.47 -3.06 -1.019 0.52211E+04 183 vesuvianite 223.47 218.82 -4.65 -0.036 0.79440E+04 187 wairakite 3.95 1.95 -2.00 -0.118 0.34155E+04 188 walstromite 11.51 9.94 -1.56 -0.313 0.26719E+04 189 wollastonite 10.46 9.94 -0.52 -0.103 0.88229E+03 190 pseudo-wollastonite 11.00 9.94 -1.06 -0.211 0.18021E+04 191 zoisite 22.85 18.95 -3.90 -0.177 0.66610E+04 192 akaganeite 7.75 4.49 -3.26 -0.705 0.55681E+04 199 chalcedony -2.80 -3.16 -0.35 -0.118 0.60609E+03 201 montmorillonite-Ca -2.29 -6.17 -3.88 -0.240 0.66180E+04 202 montmorillonite-K -2.24 -6.27 -4.03 -0.247 0.68816E+04 203 montmorillonite-Mg -2.48 -6.79 -4.32 -0.267 0.73678E+04 204 montmorillonite-Na -2.04 -5.57 -3.54 -0.216 0.60365E+04 205 nontronite-Ca 3.21 -0.19 -3.41 -0.221 0.58215E+04 206 nontronite-H 2.53 -2.36 -4.89 -0.328 0.83485E+04 207 nontronite-K 3.34 -0.30 -3.64 -0.233 0.62083E+04 208 nontronite-Mg 3.07 -0.82 -3.90 -0.253 0.66553E+04 209 nontronite-Na 3.52 0.40 -3.12 -0.200 0.53291E+04 224 tobermorite 9.82 7.76 -2.07 -0.564 0.35287E+04 230 alabandite -0.98 -4.96 -3.98 -1.328 0.68026E+04 233 boehmite 4.41 0.74 -3.67 -0.611 0.62619E+04 235 ferrous-oxide 9.81 6.73 -3.08 -0.769 0.52532E+04 240 silica-amorphous -2.09 -3.16 -1.07 -0.355 0.18203E+04 242 an20ab80 2.02 1.35 -0.67 -0.052 0.11472E+04 243 an25ab75 2.65 1.78 -0.87 -0.067 0.14810E+04 244 an30ab70 3.28 2.21 -1.07 -0.082 0.18244E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 100.0000000 g Current total amount of reactant added: 7399.9990000 g New total amount of reactant added: 7499.9990000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.5222E-10 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 12 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 7499.9990000 Water: Moles liquid = 0.1361E+02 kg liquid = 0.2453E+00 Moles total = -.3851E+02 kg total = -.6937E+00 Activity = 1.0000 Stoichiometric ionic strength = .1166960E-01 Osmotic coef. = 0.9678 True ionic strength = .2028294E-01 Chg. balance for total moles = 0.5222E-10 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.89449E-10 -10.0484 0.75098E-10 -10.1244 0.83956E+00 -0.0759 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.55994E-03 -3.2519 0.46725E-03 -3.3305 0.83446E+00 -0.0786 4 SO4-- 0.26154E-11 -11.5825 0.13536E-11 -11.8685 0.51753E+00 -0.2861 5 HCO3- 0.96700E-06 -6.0146 0.80812E-06 -6.0925 0.83569E+00 -0.0780 6 HS- 0.10397E-03 -3.9831 0.86768E-04 -4.0616 0.83458E+00 -0.0785 7 Al+++ 0.10129E-28 -28.9944 0.23219E-29 -29.6342 0.22922E+00 -0.6397 8 H4SiO4 0.69598E-03 -3.1574 0.69598E-03 -3.1574 0.10000E+01 0.0000 9 Ca++ 0.13880E-06 -6.8576 0.71298E-07 -7.1469 0.51369E+00 -0.2893 10 Mg++ 0.21715E-10 -10.6632 0.11103E-10 -10.9546 0.51131E+00 -0.2913 11 Fe++ 0.59850E-13 -13.2229 0.30636E-13 -13.5138 0.51188E+00 -0.2908 12 K+ 0.15857E-03 -3.7998 0.13255E-03 -3.8776 0.83589E+00 -0.0778 13 Na+ 0.20122E-01 -1.6963 0.16788E-01 -1.7750 0.83431E+00 -0.0787 14 Mn++ 0.19211E-10 -10.7165 0.98419E-11 -11.0069 0.51231E+00 -0.2905 15 HPO4-- 0.44383E-07 -7.3528 0.22972E-07 -7.6388 0.51760E+00 -0.2860 16 HSiO3- 0.10370E-01 -1.9842 0.86536E-02 -2.0628 0.83446E+00 -0.0786 17 Ca(HSiO3)+ 0.16806E-07 -7.7745 0.14051E-07 -7.8523 0.83608E+00 -0.0778 18 Mg(HSiO3)+ 0.32571E-11 -11.4872 0.27232E-11 -11.5649 0.83608E+00 -0.0778 19 NaHSiO3,aq 0.23497E-02 -2.6290 0.23497E-02 -2.6290 0.10000E+01 0.0000 20 AlO+ 0.66992E-16 -16.1740 0.56010E-16 -16.2517 0.83608E+00 -0.0778 22 HAlO2,aq 0.14853E-09 -9.8282 0.14853E-09 -9.8282 0.10000E+01 0.0000 23 AlO2- 0.52562E-05 -5.2793 0.43781E-05 -5.3587 0.83294E+00 -0.0794 24 CH4,aq 0.50500E-04 -4.2967 0.50321E-04 -4.2983 0.99644E+00 -0.0015 25 C2H6,aq 0.37508E-13 -13.4259 0.37375E-13 -13.4274 0.99644E+00 -0.0015 29 CO,aq 0.37730E-16 -16.4233 0.37730E-16 -16.4233 0.10000E+01 0.0000 30 CO2,aq 0.13014E-09 -9.8856 0.12968E-09 -9.8871 0.99644E+00 -0.0015 31 CO3-2 0.18201E-05 -5.7399 0.93992E-06 -6.0269 0.51642E+00 -0.2870 32 CaCO3,aq 0.84029E-09 -9.0756 0.84029E-09 -9.0756 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.17591E-11 -11.7547 0.14707E-11 -11.8325 0.83608E+00 -0.0778 34 CaCl+ 0.64483E-10 -10.1906 0.53913E-10 -10.2683 0.83608E+00 -0.0778 35 CaCl2,aq 0.59848E-14 -14.2230 0.59848E-14 -14.2230 0.10000E+01 0.0000 36 CaOH+ 0.80930E-07 -7.0919 0.67664E-07 -7.1696 0.83608E+00 -0.0778 37 CaSO4,aq 0.30645E-16 -16.5136 0.30645E-16 -16.5136 0.10000E+01 0.0000 38 HCl,aq 0.64300E-14 -14.1918 0.64300E-14 -14.1918 0.10000E+01 0.0000 43 FeCl+ 0.27100E-16 -16.5670 0.22658E-16 -16.6448 0.83608E+00 -0.0778 46 FeO,aq 0.21112E-09 -9.6755 0.21112E-09 -9.6755 0.10000E+01 0.0000 47 FeOH+ 0.15883E-10 -10.7991 0.13279E-10 -10.8768 0.83608E+00 -0.0778 48 HFeO2- 0.35251E-07 -7.4528 0.29415E-07 -7.5314 0.83446E+00 -0.0786 49 FeO+ 0.11131E-16 -16.9535 0.93066E-17 -17.0312 0.83608E+00 -0.0778 51 FeO2- 0.40465E-09 -9.3929 0.33767E-09 -9.4715 0.83446E+00 -0.0786 52 HFeO2,aq 0.32252E-11 -11.4914 0.32252E-11 -11.4914 0.10000E+01 0.0000 53 H2,aq 0.11624E-04 -4.9347 0.11582E-04 -4.9362 0.99644E+00 -0.0015 54 KCl,aq 0.11225E-08 -8.9498 0.11225E-08 -8.9498 0.10000E+01 0.0000 56 KOH,aq 0.75375E-06 -6.1228 0.75375E-06 -6.1228 0.10000E+01 0.0000 57 KSO4- 0.33363E-14 -14.4767 0.27840E-14 -14.5553 0.83446E+00 -0.0786 58 MgCO3,aq 0.32800E-13 -13.4841 0.32800E-13 -13.4841 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.27992E-15 -15.5530 0.23403E-15 -15.6307 0.83608E+00 -0.0778 60 MgCl+ 0.91013E-14 -14.0409 0.76094E-14 -14.1187 0.83608E+00 -0.0778 61 MgOH+ 0.69739E-10 -10.1565 0.58307E-10 -10.2343 0.83608E+00 -0.0778 63 MnO,aq 0.18073E-08 -8.7430 0.18073E-08 -8.7430 0.10000E+01 0.0000 64 MnOH+ 0.47399E-09 -9.3242 0.39629E-09 -9.4020 0.83608E+00 -0.0778 65 MnO2-2 0.20594E-10 -10.6863 0.10635E-10 -10.9733 0.51642E+00 -0.2870 66 HMnO2- 0.20968E-09 -9.6784 0.17497E-09 -9.7570 0.83446E+00 -0.0786 69 MnCl+ 0.33870E-13 -13.4702 0.28318E-13 -13.5479 0.83608E+00 -0.0778 71 NaCl,aq 0.25996E-05 -5.5851 0.25996E-05 -5.5851 0.10000E+01 0.0000 72 NaOH,aq 0.96047E-04 -4.0175 0.96047E-04 -4.0175 0.10000E+01 0.0000 74 OH- 0.92367E-02 -2.0345 0.76936E-02 -2.1139 0.83294E+00 -0.0794 79 HPO3-2 0.16056E-14 -14.7944 0.82918E-15 -15.0814 0.51642E+00 -0.2870 81 H2PO3- 0.14964E-18 -18.8250 0.12487E-18 -18.9035 0.83446E+00 -0.0786 82 H3PO4,aq 0.90612E-18 -18.0428 0.90612E-18 -18.0428 0.10000E+01 0.0000 83 H2PO4- 0.38102E-10 -10.4191 0.31825E-10 -10.4972 0.83526E+00 -0.0782 84 PO4-3 0.10362E-08 -8.9846 0.24958E-09 -9.6028 0.24087E+00 -0.6182 88 HP2O7-3 0.92026E-18 -18.0361 0.21116E-18 -18.6754 0.22945E+00 -0.6393 89 P2O7-4 0.88314E-17 -17.0540 0.67172E-18 -18.1728 0.76060E-01 -1.1188 90 H2S,aq 0.20211E-07 -7.6944 0.20139E-07 -7.6960 0.99644E+00 -0.0015 91 S2-2 0.27890E-13 -13.5545 0.14403E-13 -13.8415 0.51642E+00 -0.2870 97 SO3-2 0.38882E-17 -17.4103 0.20373E-17 -17.6910 0.52396E+00 -0.2807 98 HSO3- 0.11480E-19 -19.9401 0.95793E-20 -20.0187 0.83446E+00 -0.0786 99 HSO4- 0.11705E-18 -18.9316 0.97961E-19 -19.0089 0.83690E+00 -0.0773 Charge balance for all species = 0.2130E-09 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.8944878E-10 -.2207943E-01 -.2221578E+02 0.0000 2 H2O 0.1000000E+01 0.5550494E+02 0.9981874E+06 0.0000 3 Cl- 0.5599408E-03 0.5625416E-03 0.1990887E+02 6.7939 4 SO4-- 0.2615429E-11 -.5340618E-04 -.5121301E+01 8.3802 5 HCO3- 0.9670002E-06 0.5328836E-04 0.3245814E+01 4.0318 6 HS- 0.1039654E-03 0.1573918E-03 0.5196147E+01 6.0627 7 Al+++ 0.1012949E-28 0.5256324E-05 0.1415752E+00 0.7390 8 H4SiO4 0.6959837E-03 0.1341599E-01 0.1287225E+04 -3.1574 9 Ca++ 0.1387972E-06 0.2374400E-06 0.9499460E-02 13.1018 10 Mg++ 0.2171484E-10 0.9475330E-10 0.2299609E-05 9.2942 11 Fe++ 0.5984962E-13 0.3588559E-07 0.2000594E-02 6.7350 12 K+ 0.1585689E-03 0.1593238E-03 0.6218970E+01 6.2467 13 Na+ 0.2012199E-01 0.2257029E-01 0.5179779E+03 8.3494 14 Mn++ 0.1921098E-10 0.2530770E-08 0.1387920E-03 9.2418 15 HPO4-- 0.4438252E-07 0.4545678E-07 0.4355258E-02 12.6100 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.1241888E+03 -.5415406E-02 -.1241834E+03 0.0000000E+00 2 H2O -.3850731E+02 0.1361366E+02 -.5212097E+02 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.2078760E+00 -.1309890E-04 0.2078891E+00 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.2078505E+00 0.3860337E-04 -.2078891E+00 0.0000000E+00 7 Al+++ 0.2445556E+02 0.1289215E-05 0.2445556E+02 0.0000000E+00 8 H4SiO4 0.7809586E+02 0.3290530E-02 0.7809257E+02 0.0000000E+00 9 Ca++ 0.8626083E+01 0.5823674E-07 0.8626083E+01 0.0000000E+00 10 Mg++ 0.5952380E+01 0.2324008E-10 0.5952380E+01 0.0000000E+00 11 Fe++ 0.5347564E+01 0.8801634E-08 0.5347564E+01 0.0000000E+00 12 K+ 0.1592356E+01 0.3907723E-04 0.1592317E+01 0.0000000E+00 13 Na+ 0.9414486E+01 0.5535798E-02 0.9408950E+01 0.0000000E+00 14 Mn++ 0.1300395E+00 0.6207202E-09 0.1300395E+00 0.0000000E+00 15 HPO4-- 0.4438182E-01 0.1114915E-07 0.4438181E-01 0.0000000E+00 Chg. balance for solid moles: 0.1321E-13 Mass of aqueous solution: 0.245699E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 7499.9990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 9.401 0.973 2465. 3.392 30.09 946.3 andradite 0.8316 -0.080 422.6 2.626 5.157 109.8 grossular 0.2013 -0.696 90.70 1.958 1.107 25.24 apatite-OH 0.1479E-01 -1.830 7.431 0.871 0.9070E-01 2.361 clinochlore 1.065 0.027 591.9 2.772 7.224 225.1 daphnite 0.3083 -0.511 219.9 2.342 2.684 66.65 chlorite-Mn 0.2601E-01 -1.585 18.44 1.266 0.2250 5.876 diopside 0.3987 -0.399 86.34 1.936 1.054 26.39 hedenbergite 0.1034 -0.986 25.65 1.409 0.3131 7.026 microcline 1.396 0.145 388.6 2.590 4.743 151.8 stilbite 4.825 0.683 3400. 3.531 41.50 1586. stilpnomelane-Fe 0.3921 -0.407 422.7 2.626 5.159 146.0 tr.625ac.25prg.125 0.6333E-01 -1.198 54.13 1.733 0.6606 17.42 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8051E+00 0.8051E+00 1.0000 -0.094 grossular 0.1949E+00 0.1949E+00 1.0000 -0.710 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.7611E+00 0.7611E+00 1.0000 -0.119 daphnite 0.2203E+00 0.2203E+00 1.0000 -0.657 chlorite-Mn 0.1859E-01 0.1859E-01 1.0000 -1.731 diopside 0.7941E+00 0.7941E+00 1.0000 -0.100 hedenbergite 0.2059E+00 0.2059E+00 1.0000 -0.686 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 tr.625ac.25prg.125 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 8193.604461 g Volume = 3315.854451 cm3 Porosity: -10.4917% V(tot) - V(min): -.31485E+03 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 7499.9990000 g log = 3.8751 Original solution: 1000.0103000 g Original solution / Rock added: 0.13 (Water/Rock Ratio), log = -0.8751 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.1099 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9203E+00 0.9848 0.1006E+01 0.1022E+01 CO2,gas 0.1242E-07 1.0062 0.1387E-07 0.1379E-07 CH4,gas 0.6596E-01 1.0118 0.7407E-01 0.7321E-01 H2,gas 0.1369E-01 1.0006 0.1521E-01 0.1520E-01 H2S,gas 0.5009E-06 0.9957 0.5536E-06 0.5560E-06 S2,gas 0.4482E-28 1.0000 0.4975E-28 0.4975E-28 CO,gas 0.5066E-13 1.0000 0.5623E-13 0.5623E-13 SO3,gas 0.2600E-47 1.0000 0.2886E-47 0.2886E-47 SO2,gas 0.1538E-26 1.0000 0.1708E-26 0.1708E-26 HCl,gas 0.1022E-16 1.0000 0.1135E-16 0.1135E-16 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 16 albite -0.38 -0.38 0.00 0.000 -0.94784E-12 22 andradite 39.01 39.01 0.00 0.000 0.00000E+00 23 grossular 32.73 32.73 0.00 0.000 0.12132E-10 32 apatite-OH -18.15 -18.15 0.00 0.000 0.12132E-10 46 clinochlore 39.07 39.07 0.00 0.000 0.24265E-10 47 daphnite 28.97 28.97 0.00 0.000 -0.48529E-10 48 chlorite-Mn 46.87 46.87 0.00 0.000 0.12132E-10 67 diopside 16.18 16.18 0.00 0.000 0.60662E-11 68 hedenbergite 14.21 14.21 0.00 0.000 0.30331E-11 116 microcline -2.49 -2.49 0.00 0.000 0.15165E-11 163 stilbite -7.52 -7.52 0.00 0.000 -0.90992E-11 164 stilpnomelane-Fe 13.02 13.02 0.00 0.000 0.21232E-10 245 tr.625ac.25prg.125 45.16 45.16 0.00 0.000 -0.72794E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -16.22 -9.56 -3.186 0.16318E+05 -7.858 3 CH4,gas 4.54 1.71 -2.83 -0.707 0.48310E+04 -1.130 4 H2,gas 8.00 4.48 -3.52 -2.010 0.60051E+04 -1.818 5 H2S,gas -6.23 -14.19 -7.96 -3.978 0.13584E+05 -6.257 6 S2,gas -7.34 -37.34 -30.00 -4.616 0.51228E+05 -28.303 7 CO,gas 3.21 -11.73 -14.95 -4.600 0.25525E+05 -13.250 8 SO3,gas 17.12 -32.12 -49.24 -12.310 0.84074E+05 -47.540 9 SO2,gas 0.83 -27.63 -28.47 -7.591 0.48606E+05 -26.768 10 HCl,gas 5.19 -13.45 -18.64 -9.322 0.31834E+05 -16.945 11 acmite 7.71 6.53 -1.18 -0.123 0.20175E+04 15 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 19 spessartine 24.46 19.73 -4.73 -0.236 0.80697E+04 20 analcite 3.32 2.77 -0.55 -0.061 0.93626E+03 26 annite 20.12 17.72 -2.40 -0.134 0.41064E+04 27 phlogopite 27.06 25.40 -1.67 -0.093 0.28489E+04 29 anorthite 12.71 8.26 -4.45 -0.342 0.75903E+04 35 aragonite 0.97 -3.12 -4.08 -1.361 0.69692E+04 36 brucite 12.57 9.29 -3.27 -0.655 0.55909E+04 37 calcite 0.81 -3.12 -3.93 -1.309 0.67050E+04 38 carnegieite-low 9.02 5.93 -3.09 -0.442 0.52801E+04 39 carnegieite-high 10.09 5.93 -4.16 -0.595 0.71071E+04 40 carpholite-Mg 8.58 4.46 -4.12 -0.275 0.70429E+04 41 carpholite-Fe 6.71 1.90 -4.81 -0.321 0.82207E+04 42 celadonite 5.34 3.65 -1.69 -0.099 0.28879E+04 43 celadonite-Fe 3.88 1.09 -2.79 -0.164 0.47561E+04 44 chrysotile 23.89 21.57 -2.32 -0.194 0.39692E+04 49 chlorite-Al-free 47.17 43.14 -4.04 -0.168 0.68936E+04 51 chloritoid-Fe 9.17 5.06 -4.12 -0.275 0.70316E+04 52 chloritoid-Mn 11.40 7.56 -3.84 -0.256 0.65545E+04 54 coesite -2.38 -3.16 -0.78 -0.260 0.13341E+04 61 cristobalite -2.56 -3.16 -0.60 -0.199 0.10195E+04 63 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71234E+04 65 diaspore 2.87 0.74 -2.13 -0.356 0.36450E+04 66 diamond -3.10 -7.25 -4.15 -1.185 0.70841E+04 71 enstatite 17.26 12.27 -4.99 -0.499 0.85226E+04 73 clinoenstatite 17.17 12.27 -4.89 -0.489 0.83541E+04 75 epidote 24.67 22.70 -1.97 -0.095 0.33585E+04 76 clinozoisite 22.81 18.95 -3.86 -0.175 0.65869E+04 77 epidote-Fe 29.84 26.46 -3.38 -0.176 0.57768E+04 78 fayalite 14.05 10.31 -3.73 -0.533 0.63743E+04 79 ferrosilite 11.15 7.16 -3.99 -0.399 0.68202E+04 83 gibbsite 4.08 0.74 -3.34 -0.477 0.57035E+04 84 glaucophane 22.97 20.80 -2.17 -0.059 0.37134E+04 85 glaucophane-Fe 17.28 13.12 -4.15 -0.112 0.70919E+04 86 graphite -3.55 -7.25 -3.71 -1.059 0.63263E+04 87 greenalite 16.14 13.89 -2.25 -0.187 0.38408E+04 90 hematite 12.57 8.99 -3.58 -0.434 0.61111E+04 91 heulandite -5.83 -7.52 -1.69 -0.077 0.28938E+04 95 jadeite 4.22 2.77 -1.44 -0.144 0.24617E+04 97 kalsilite 7.58 3.83 -3.76 -0.537 0.64126E+04 98 kaolinite -1.33 -4.84 -3.50 -0.319 0.59832E+04 101 laumontite 2.88 1.95 -0.93 -0.062 0.15935E+04 102 lawsonite 9.62 8.26 -1.35 -0.090 0.23070E+04 103 leucite 4.12 0.67 -3.45 -0.345 0.58873E+04 105 lizardite 23.24 21.57 -1.68 -0.140 0.28619E+04 107 magnetite 20.09 15.72 -4.37 -0.356 0.74536E+04 108 minnesotaite 10.39 7.58 -2.81 -0.165 0.48027E+04 112 manganosite 14.06 9.24 -4.82 -1.204 0.82237E+04 120 muscovite 2.58 -1.01 -3.59 -0.211 0.61315E+04 121 paragonite 4.24 1.09 -3.15 -0.185 0.53706E+04 122 nepheline 8.34 5.93 -2.41 -0.344 0.41125E+04 128 periclase-Fe 11.63 6.73 -4.89 -1.223 0.83523E+04 134 phlogopite-Na 29.65 27.50 -2.15 -0.119 0.36678E+04 136 prehnite 19.37 18.21 -1.16 -0.068 0.19849E+04 137 prehnite-Fe 22.50 21.96 -0.53 -0.032 0.91159E+03 138 pumpellyite-Fe 46.27 43.89 -2.38 -0.053 0.40582E+04 139 pumpellyite-Mg 48.99 46.45 -2.54 -0.057 0.43421E+04 142 pyrite -21.25 -26.12 -4.87 -1.147 0.83204E+04 143 pyrrhotite -4.26 -7.45 -3.19 -1.064 0.54481E+04 144 pyrrhotiteFe0.875 -6.02 -8.85 -2.83 -1.041 0.48353E+04 145 pyroxmangite 7.40 6.08 -1.31 -0.263 0.22440E+04 146 pyrophyllite -6.18 -11.15 -4.98 -0.311 0.84962E+04 147 quartz -2.99 -3.16 -0.17 -0.056 0.28680E+03 152 rhodonite 7.45 6.08 -1.36 -0.272 0.23243E+04 153 sanidine -1.28 -2.49 -1.21 -0.093 0.20677E+04 165 stilpnomelane-Mg 27.44 25.81 -1.63 -0.049 0.27804E+04 171 talc 16.49 15.25 -1.24 -0.073 0.21140E+04 174 tephroite 18.09 15.33 -2.76 -0.394 0.47118E+04 178 tridymite -2.63 -3.16 -0.53 -0.177 0.90677E+03 179 tremolite 47.87 47.42 -0.45 -0.012 0.77494E+03 180 ferroactinolite 38.45 34.62 -3.83 -0.104 0.65448E+04 181 troilite-low -4.41 -7.45 -3.04 -1.013 0.51909E+04 183 vesuvianite 223.47 218.82 -4.65 -0.036 0.79440E+04 187 wairakite 3.95 1.95 -2.00 -0.118 0.34155E+04 188 walstromite 11.51 9.94 -1.56 -0.313 0.26719E+04 189 wollastonite 10.46 9.94 -0.52 -0.103 0.88229E+03 190 pseudo-wollastonite 11.00 9.94 -1.06 -0.211 0.18021E+04 191 zoisite 22.85 18.95 -3.90 -0.177 0.66610E+04 192 akaganeite 7.75 4.49 -3.26 -0.705 0.55681E+04 199 chalcedony -2.80 -3.16 -0.35 -0.118 0.60609E+03 201 montmorillonite-Ca -2.29 -6.17 -3.88 -0.240 0.66180E+04 202 montmorillonite-K -2.24 -6.27 -4.03 -0.247 0.68816E+04 203 montmorillonite-Mg -2.48 -6.79 -4.32 -0.267 0.73678E+04 204 montmorillonite-Na -2.04 -5.57 -3.54 -0.216 0.60365E+04 205 nontronite-Ca 3.21 -0.19 -3.41 -0.221 0.58215E+04 206 nontronite-H 2.53 -2.36 -4.89 -0.328 0.83485E+04 207 nontronite-K 3.34 -0.30 -3.64 -0.233 0.62083E+04 208 nontronite-Mg 3.07 -0.82 -3.90 -0.253 0.66553E+04 209 nontronite-Na 3.52 0.40 -3.12 -0.200 0.53291E+04 224 tobermorite 9.82 7.76 -2.07 -0.564 0.35287E+04 230 alabandite -0.98 -4.94 -3.97 -1.322 0.67724E+04 233 boehmite 4.41 0.74 -3.67 -0.611 0.62619E+04 235 ferrous-oxide 9.81 6.73 -3.08 -0.769 0.52532E+04 240 silica-amorphous -2.09 -3.16 -1.07 -0.355 0.18203E+04 242 an20ab80 2.02 1.35 -0.67 -0.052 0.11472E+04 243 an25ab75 2.65 1.78 -0.87 -0.067 0.14810E+04 244 an30ab70 3.28 2.21 -1.07 -0.082 0.18244E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 100.0000000 g Current total amount of reactant added: 7499.9990000 g New total amount of reactant added: 7599.9990000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.5222E-10 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 13 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 7599.9990000 Water: Moles liquid = 0.1306E+02 kg liquid = 0.2352E+00 Moles total = -.3976E+02 kg total = -.7163E+00 Activity = 1.0000 Stoichiometric ionic strength = .1168954E-01 Osmotic coef. = 0.9678 True ionic strength = .2029857E-01 Chg. balance for total moles = 0.5222E-10 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.89517E-10 -10.0481 0.75151E-10 -10.1241 0.83952E+00 -0.0760 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.58384E-03 -3.2337 0.48717E-03 -3.3123 0.83442E+00 -0.0786 4 SO4-- 0.27256E-11 -11.5645 0.14103E-11 -11.8507 0.51742E+00 -0.2862 5 HCO3- 0.10077E-05 -5.9967 0.84206E-06 -6.0747 0.83565E+00 -0.0780 6 HS- 0.10840E-03 -3.9650 0.90468E-04 -4.0435 0.83454E+00 -0.0786 7 Al+++ 0.10156E-28 -28.9933 0.23269E-29 -29.6332 0.22912E+00 -0.6399 8 H4SiO4 0.69598E-03 -3.1574 0.69598E-03 -3.1574 0.10000E+01 0.0000 9 Ca++ 0.13902E-06 -6.8569 0.71400E-07 -7.1463 0.51358E+00 -0.2894 10 Mg++ 0.21750E-10 -10.6625 0.11119E-10 -10.9539 0.51121E+00 -0.2914 11 Fe++ 0.59948E-13 -13.2222 0.30680E-13 -13.5132 0.51177E+00 -0.2909 12 K+ 0.15869E-03 -3.7994 0.13264E-03 -3.8773 0.83585E+00 -0.0779 13 Na+ 0.20137E-01 -1.6960 0.16800E-01 -1.7747 0.83426E+00 -0.0787 14 Mn++ 0.19243E-10 -10.7157 0.98562E-11 -11.0063 0.51220E+00 -0.2906 15 HPO4-- 0.44328E-07 -7.3533 0.22940E-07 -7.6394 0.51750E+00 -0.2861 16 HSiO3- 0.10363E-01 -1.9845 0.86475E-02 -2.0631 0.83442E+00 -0.0786 17 Ca(HSiO3)+ 0.16819E-07 -7.7742 0.14061E-07 -7.8520 0.83603E+00 -0.0778 18 Mg(HSiO3)+ 0.32596E-11 -11.4868 0.27251E-11 -11.5646 0.83603E+00 -0.0778 19 NaHSiO3,aq 0.23497E-02 -2.6290 0.23497E-02 -2.6290 0.10000E+01 0.0000 20 AlO+ 0.67043E-16 -16.1736 0.56050E-16 -16.2514 0.83603E+00 -0.0778 22 HAlO2,aq 0.14853E-09 -9.8282 0.14853E-09 -9.8282 0.10000E+01 0.0000 23 AlO2- 0.52527E-05 -5.2796 0.43749E-05 -5.3590 0.83290E+00 -0.0794 24 CH4,aq 0.52659E-04 -4.2785 0.52472E-04 -4.2801 0.99644E+00 -0.0016 25 C2H6,aq 0.40784E-13 -13.3895 0.40638E-13 -13.3911 0.99644E+00 -0.0016 29 CO,aq 0.39343E-16 -16.4051 0.39343E-16 -16.4051 0.10000E+01 0.0000 30 CO2,aq 0.13570E-09 -9.8674 0.13522E-09 -9.8690 0.99644E+00 -0.0016 31 CO3-2 0.18956E-05 -5.7223 0.97870E-06 -6.0094 0.51631E+00 -0.2871 32 CaCO3,aq 0.87621E-09 -9.0574 0.87621E-09 -9.0574 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.18357E-11 -11.7362 0.15347E-11 -11.8140 0.83603E+00 -0.0778 34 CaCl+ 0.67332E-10 -10.1718 0.56292E-10 -10.2496 0.83603E+00 -0.0778 35 CaCl2,aq 0.65153E-14 -14.1861 0.65153E-14 -14.1861 0.10000E+01 0.0000 36 CaOH+ 0.80992E-07 -7.0916 0.67712E-07 -7.1693 0.83603E+00 -0.0778 37 CaSO4,aq 0.31975E-16 -16.4952 0.31975E-16 -16.4952 0.10000E+01 0.0000 38 HCl,aq 0.67089E-14 -14.1733 0.67089E-14 -14.1733 0.10000E+01 0.0000 43 FeCl+ 0.28297E-16 -16.5483 0.23657E-16 -16.6260 0.83603E+00 -0.0778 46 FeO,aq 0.21112E-09 -9.6755 0.21112E-09 -9.6755 0.10000E+01 0.0000 47 FeOH+ 0.15895E-10 -10.7987 0.13289E-10 -10.8765 0.83603E+00 -0.0778 48 HFeO2- 0.35227E-07 -7.4531 0.29394E-07 -7.5317 0.83442E+00 -0.0786 49 FeO+ 0.11140E-16 -16.9531 0.93133E-17 -17.0309 0.83603E+00 -0.0778 51 FeO2- 0.40438E-09 -9.3932 0.33743E-09 -9.4718 0.83442E+00 -0.0786 52 HFeO2,aq 0.32252E-11 -11.4914 0.32252E-11 -11.4914 0.10000E+01 0.0000 53 H2,aq 0.11624E-04 -4.9347 0.11582E-04 -4.9362 0.99644E+00 -0.0016 54 KCl,aq 0.11712E-08 -8.9314 0.11712E-08 -8.9314 0.10000E+01 0.0000 56 KOH,aq 0.75375E-06 -6.1228 0.75375E-06 -6.1228 0.10000E+01 0.0000 57 KSO4- 0.34787E-14 -14.4586 0.29027E-14 -14.5372 0.83442E+00 -0.0786 58 MgCO3,aq 0.34202E-13 -13.4659 0.34202E-13 -13.4659 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.29210E-15 -15.5345 0.24421E-15 -15.6122 0.83603E+00 -0.0778 60 MgCl+ 0.95034E-14 -14.0221 0.79451E-14 -14.0999 0.83603E+00 -0.0778 61 MgOH+ 0.69792E-10 -10.1562 0.58349E-10 -10.2340 0.83603E+00 -0.0778 63 MnO,aq 0.18073E-08 -8.7430 0.18073E-08 -8.7430 0.10000E+01 0.0000 64 MnOH+ 0.47436E-09 -9.3239 0.39658E-09 -9.4017 0.83603E+00 -0.0778 65 MnO2-2 0.20569E-10 -10.6868 0.10620E-10 -10.9739 0.51631E+00 -0.2871 66 HMnO2- 0.20955E-09 -9.6787 0.17485E-09 -9.7573 0.83442E+00 -0.0786 69 MnCl+ 0.35367E-13 -13.4514 0.29568E-13 -13.5292 0.83603E+00 -0.0778 71 NaCl,aq 0.27123E-05 -5.5667 0.27123E-05 -5.5667 0.10000E+01 0.0000 72 NaOH,aq 0.96047E-04 -4.0175 0.96047E-04 -4.0175 0.10000E+01 0.0000 74 OH- 0.92306E-02 -2.0348 0.76881E-02 -2.1142 0.83290E+00 -0.0794 79 HPO3-2 0.16037E-14 -14.7949 0.82800E-15 -15.0820 0.51631E+00 -0.2871 81 H2PO3- 0.14954E-18 -18.8252 0.12478E-18 -18.9039 0.83442E+00 -0.0786 82 H3PO4,aq 0.90612E-18 -18.0428 0.90612E-18 -18.0428 0.10000E+01 0.0000 83 H2PO4- 0.38076E-10 -10.4193 0.31802E-10 -10.4975 0.83522E+00 -0.0782 84 PO4-3 0.10344E-08 -8.9853 0.24905E-09 -9.6037 0.24077E+00 -0.6184 88 HP2O7-3 0.91871E-18 -18.0368 0.21070E-18 -18.6763 0.22935E+00 -0.6395 89 P2O7-4 0.88133E-17 -17.0549 0.66980E-18 -18.1741 0.75999E-01 -1.1192 90 H2S,aq 0.21088E-07 -7.6760 0.21012E-07 -7.6775 0.99644E+00 -0.0016 91 S2-2 0.30326E-13 -13.5182 0.15657E-13 -13.8053 0.51631E+00 -0.2871 97 SO3-2 0.40519E-17 -17.3923 0.21226E-17 -17.6731 0.52386E+00 -0.2808 98 HSO3- 0.11970E-19 -19.9219 0.99878E-20 -20.0005 0.83442E+00 -0.0786 99 HSO4- 0.12205E-18 -18.9135 0.10214E-18 -18.9908 0.83686E+00 -0.0773 Charge balance for all species = 0.2221E-09 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.8951704E-10 -.2206651E-01 -.2220276E+02 0.0000 2 H2O 0.1000000E+01 0.5550494E+02 0.9981867E+06 0.0000 3 Cl- 0.5838448E-03 0.5865584E-03 0.2075883E+02 6.8117 4 SO4-- 0.2725555E-11 -.5556508E-04 -.5328321E+01 8.3974 5 HCO3- 0.1007666E-05 0.5556343E-04 0.3384386E+01 4.0494 6 HS- 0.1084040E-03 0.1639902E-03 0.5413983E+01 6.0806 7 Al+++ 0.1015592E-28 0.5252845E-05 0.1414814E+00 0.7390 8 H4SiO4 0.6959838E-03 0.1340912E-01 0.1286565E+04 -3.1574 9 Ca++ 0.1390244E-06 0.2377809E-06 0.9513089E-02 13.1018 10 Mg++ 0.2175044E-10 0.9484534E-10 0.2301841E-05 9.2942 11 Fe++ 0.5994773E-13 0.3586197E-07 0.1999276E-02 6.7350 12 K+ 0.1586903E-03 0.1594452E-03 0.6223707E+01 6.2467 13 Na+ 0.2013742E-01 0.2258583E-01 0.5183342E+03 8.3494 14 Mn++ 0.1924276E-10 0.2531041E-08 0.1388068E-03 9.2418 15 HPO4-- 0.4432809E-07 0.4540055E-07 0.4349867E-02 12.6087 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.1258447E+03 -.5190632E-02 -.1258395E+03 0.0000000E+00 2 H2O -.3976086E+02 0.1305624E+02 -.5281710E+02 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.2106474E+00 -.1307039E-04 0.2106605E+00 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.2106219E+00 0.3857486E-04 -.2106605E+00 0.0000000E+00 7 Al+++ 0.2478163E+02 0.1235609E-05 0.2478163E+02 0.0000000E+00 8 H4SiO4 0.7913714E+02 0.3154182E-02 0.7913399E+02 0.0000000E+00 9 Ca++ 0.8741097E+01 0.5593240E-07 0.8741097E+01 0.0000000E+00 10 Mg++ 0.6031745E+01 0.2231015E-10 0.6031745E+01 0.0000000E+00 11 Fe++ 0.5418865E+01 0.8435693E-08 0.5418865E+01 0.0000000E+00 12 K+ 0.1613588E+01 0.3750577E-04 0.1613550E+01 0.0000000E+00 13 Na+ 0.9540010E+01 0.5312789E-02 0.9534698E+01 0.0000000E+00 14 Mn++ 0.1317733E+00 0.5953684E-09 0.1317733E+00 0.0000000E+00 15 HPO4-- 0.4497358E-01 0.1067942E-07 0.4497357E-01 0.0000000E+00 Chg. balance for solid moles: 0.7216E-15 Mass of aqueous solution: 0.235639E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 7599.9990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 9.527 0.979 2498. 3.398 30.09 959.0 andradite 0.8426 -0.074 428.2 2.632 5.157 111.3 grossular 0.2040 -0.690 91.91 1.963 1.107 25.57 apatite-OH 0.1499E-01 -1.824 7.530 0.877 0.9070E-01 2.393 clinochlore 1.079 0.033 599.7 2.778 7.223 228.1 daphnite 0.3124 -0.505 222.9 2.348 2.684 67.54 chlorite-Mn 0.2635E-01 -1.579 18.68 1.271 0.2250 5.954 diopside 0.4041 -0.394 87.51 1.942 1.054 26.75 hedenbergite 0.1048 -0.980 26.00 1.415 0.3132 7.122 microcline 1.415 0.151 393.8 2.595 4.743 153.8 stilbite 4.889 0.689 3445. 3.537 41.50 1607. stilpnomelane-Fe 0.3973 -0.401 428.3 2.632 5.159 148.0 tr.625ac.25prg.125 0.6416E-01 -1.193 54.84 1.739 0.6605 17.65 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8051E+00 0.8051E+00 1.0000 -0.094 grossular 0.1949E+00 0.1949E+00 1.0000 -0.710 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.7611E+00 0.7611E+00 1.0000 -0.119 daphnite 0.2203E+00 0.2203E+00 1.0000 -0.657 chlorite-Mn 0.1859E-01 0.1859E-01 1.0000 -1.731 diopside 0.7941E+00 0.7941E+00 1.0000 -0.100 hedenbergite 0.2059E+00 0.2059E+00 1.0000 -0.686 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 tr.625ac.25prg.125 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 8302.855123 g Volume = 3360.057514 cm3 Porosity: -10.4919% V(tot) - V(min): -.31906E+03 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 7599.9990000 g log = 3.8808 Original solution: 1000.0103000 g Original solution / Rock added: 0.13 (Water/Rock Ratio), log = -0.8808 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.1131 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9178E+00 0.9847 0.1006E+01 0.1022E+01 CO2,gas 0.1292E-07 1.0061 0.1447E-07 0.1438E-07 CH4,gas 0.6858E-01 1.0117 0.7723E-01 0.7634E-01 H2,gas 0.1365E-01 1.0006 0.1521E-01 0.1520E-01 H2S,gas 0.5212E-06 0.9957 0.5776E-06 0.5801E-06 S2,gas 0.4866E-28 1.0000 0.5416E-28 0.5416E-28 CO,gas 0.5267E-13 1.0000 0.5863E-13 0.5863E-13 SO3,gas 0.2706E-47 1.0000 0.3012E-47 0.3012E-47 SO2,gas 0.1601E-26 1.0000 0.1782E-26 0.1782E-26 HCl,gas 0.1064E-16 1.0000 0.1184E-16 0.1184E-16 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 16 albite -0.38 -0.38 0.00 0.000 -0.94784E-12 22 andradite 39.01 39.01 0.00 0.000 0.00000E+00 23 grossular 32.73 32.73 0.00 0.000 -0.24265E-10 32 apatite-OH -18.15 -18.15 0.00 0.000 0.60662E-11 46 clinochlore 39.07 39.07 0.00 0.000 -0.24265E-10 47 daphnite 28.97 28.97 0.00 0.000 0.60662E-11 48 chlorite-Mn 46.87 46.87 0.00 0.000 -0.24265E-10 67 diopside 16.18 16.18 0.00 0.000 -0.60662E-11 68 hedenbergite 14.21 14.21 0.00 0.000 0.00000E+00 116 microcline -2.49 -2.49 0.00 0.000 0.15165E-11 163 stilbite -7.52 -7.52 0.00 0.000 -0.90992E-11 164 stilpnomelane-Fe 13.02 13.02 0.00 0.000 0.21232E-10 245 tr.625ac.25prg.125 45.16 45.16 0.00 0.000 -0.12132E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -16.20 -9.54 -3.180 0.16287E+05 -7.840 3 CH4,gas 4.54 1.73 -2.81 -0.703 0.48000E+04 -1.112 4 H2,gas 8.00 4.48 -3.52 -2.010 0.60051E+04 -1.818 5 H2S,gas -6.23 -14.17 -7.94 -3.969 0.13553E+05 -6.238 6 S2,gas -7.34 -37.30 -29.97 -4.610 0.51165E+05 -28.266 7 CO,gas 3.21 -11.72 -14.93 -4.594 0.25494E+05 -13.232 8 SO3,gas 17.12 -32.10 -49.22 -12.305 0.84042E+05 -47.521 9 SO2,gas 0.83 -27.62 -28.45 -7.586 0.48574E+05 -26.749 10 HCl,gas 5.19 -13.44 -18.63 -9.313 0.31803E+05 -16.927 11 acmite 7.71 6.53 -1.18 -0.123 0.20175E+04 15 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 19 spessartine 24.46 19.73 -4.73 -0.236 0.80697E+04 20 analcite 3.32 2.77 -0.55 -0.061 0.93626E+03 26 annite 20.12 17.72 -2.40 -0.134 0.41064E+04 27 phlogopite 27.06 25.40 -1.67 -0.093 0.28489E+04 29 anorthite 12.71 8.26 -4.45 -0.342 0.75903E+04 35 aragonite 0.97 -3.10 -4.06 -1.354 0.69382E+04 36 brucite 12.57 9.29 -3.27 -0.655 0.55909E+04 37 calcite 0.81 -3.10 -3.91 -1.303 0.66739E+04 38 carnegieite-low 9.02 5.93 -3.09 -0.442 0.52801E+04 39 carnegieite-high 10.09 5.93 -4.16 -0.595 0.71071E+04 40 carpholite-Mg 8.58 4.46 -4.12 -0.275 0.70429E+04 41 carpholite-Fe 6.71 1.90 -4.81 -0.321 0.82207E+04 42 celadonite 5.34 3.65 -1.69 -0.099 0.28879E+04 43 celadonite-Fe 3.88 1.09 -2.79 -0.164 0.47561E+04 44 chrysotile 23.89 21.57 -2.32 -0.194 0.39692E+04 49 chlorite-Al-free 47.17 43.14 -4.04 -0.168 0.68936E+04 51 chloritoid-Fe 9.17 5.06 -4.12 -0.275 0.70316E+04 52 chloritoid-Mn 11.40 7.56 -3.84 -0.256 0.65545E+04 54 coesite -2.38 -3.16 -0.78 -0.260 0.13341E+04 61 cristobalite -2.56 -3.16 -0.60 -0.199 0.10195E+04 63 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71234E+04 65 diaspore 2.87 0.74 -2.13 -0.356 0.36450E+04 66 diamond -3.10 -7.23 -4.13 -1.180 0.70531E+04 71 enstatite 17.26 12.27 -4.99 -0.499 0.85226E+04 73 clinoenstatite 17.17 12.27 -4.89 -0.489 0.83541E+04 75 epidote 24.67 22.70 -1.97 -0.095 0.33585E+04 76 clinozoisite 22.81 18.95 -3.86 -0.175 0.65869E+04 77 epidote-Fe 29.84 26.46 -3.38 -0.176 0.57768E+04 78 fayalite 14.05 10.31 -3.73 -0.533 0.63743E+04 79 ferrosilite 11.15 7.16 -3.99 -0.399 0.68202E+04 83 gibbsite 4.08 0.74 -3.34 -0.477 0.57035E+04 84 glaucophane 22.97 20.80 -2.17 -0.059 0.37134E+04 85 glaucophane-Fe 17.28 13.12 -4.15 -0.112 0.70919E+04 86 graphite -3.55 -7.23 -3.69 -1.053 0.62953E+04 87 greenalite 16.14 13.89 -2.25 -0.187 0.38408E+04 90 hematite 12.57 8.99 -3.58 -0.434 0.61111E+04 91 heulandite -5.83 -7.52 -1.69 -0.077 0.28938E+04 95 jadeite 4.22 2.77 -1.44 -0.144 0.24617E+04 97 kalsilite 7.58 3.83 -3.76 -0.537 0.64126E+04 98 kaolinite -1.33 -4.84 -3.50 -0.319 0.59832E+04 101 laumontite 2.88 1.95 -0.93 -0.062 0.15935E+04 102 lawsonite 9.62 8.26 -1.35 -0.090 0.23070E+04 103 leucite 4.12 0.67 -3.45 -0.345 0.58873E+04 105 lizardite 23.24 21.57 -1.68 -0.140 0.28619E+04 107 magnetite 20.09 15.72 -4.37 -0.356 0.74536E+04 108 minnesotaite 10.39 7.58 -2.81 -0.165 0.48027E+04 112 manganosite 14.06 9.24 -4.82 -1.204 0.82237E+04 120 muscovite 2.58 -1.01 -3.59 -0.211 0.61315E+04 121 paragonite 4.24 1.09 -3.15 -0.185 0.53706E+04 122 nepheline 8.34 5.93 -2.41 -0.344 0.41125E+04 128 periclase-Fe 11.63 6.73 -4.89 -1.223 0.83523E+04 134 phlogopite-Na 29.65 27.50 -2.15 -0.119 0.36678E+04 136 prehnite 19.37 18.21 -1.16 -0.068 0.19849E+04 137 prehnite-Fe 22.50 21.96 -0.53 -0.032 0.91159E+03 138 pumpellyite-Fe 46.27 43.89 -2.38 -0.053 0.40582E+04 139 pumpellyite-Mg 48.99 46.45 -2.54 -0.057 0.43421E+04 142 pyrite -21.25 -26.08 -4.84 -1.138 0.82574E+04 143 pyrrhotite -4.26 -7.43 -3.17 -1.057 0.54166E+04 144 pyrrhotiteFe0.875 -6.02 -8.83 -2.81 -1.035 0.48038E+04 145 pyroxmangite 7.40 6.08 -1.31 -0.263 0.22440E+04 146 pyrophyllite -6.18 -11.15 -4.98 -0.311 0.84962E+04 147 quartz -2.99 -3.16 -0.17 -0.056 0.28680E+03 152 rhodonite 7.45 6.08 -1.36 -0.272 0.23243E+04 153 sanidine -1.28 -2.49 -1.21 -0.093 0.20677E+04 165 stilpnomelane-Mg 27.44 25.81 -1.63 -0.049 0.27804E+04 171 talc 16.49 15.25 -1.24 -0.073 0.21140E+04 174 tephroite 18.09 15.33 -2.76 -0.394 0.47118E+04 178 tridymite -2.63 -3.16 -0.53 -0.177 0.90677E+03 179 tremolite 47.87 47.42 -0.45 -0.012 0.77494E+03 180 ferroactinolite 38.45 34.62 -3.83 -0.104 0.65448E+04 181 troilite-low -4.41 -7.43 -3.02 -1.007 0.51594E+04 183 vesuvianite 223.47 218.82 -4.65 -0.036 0.79440E+04 187 wairakite 3.95 1.95 -2.00 -0.118 0.34155E+04 188 walstromite 11.51 9.94 -1.56 -0.313 0.26719E+04 189 wollastonite 10.46 9.94 -0.52 -0.103 0.88229E+03 190 pseudo-wollastonite 11.00 9.94 -1.06 -0.211 0.18021E+04 191 zoisite 22.85 18.95 -3.90 -0.177 0.66610E+04 192 akaganeite 7.75 4.49 -3.26 -0.705 0.55681E+04 199 chalcedony -2.80 -3.16 -0.35 -0.118 0.60609E+03 201 montmorillonite-Ca -2.29 -6.17 -3.88 -0.240 0.66180E+04 202 montmorillonite-K -2.24 -6.27 -4.03 -0.247 0.68816E+04 203 montmorillonite-Mg -2.48 -6.79 -4.32 -0.267 0.73678E+04 204 montmorillonite-Na -2.04 -5.57 -3.54 -0.216 0.60365E+04 205 nontronite-Ca 3.21 -0.19 -3.41 -0.221 0.58215E+04 206 nontronite-H 2.53 -2.36 -4.89 -0.328 0.83485E+04 207 nontronite-K 3.34 -0.30 -3.64 -0.233 0.62083E+04 208 nontronite-Mg 3.07 -0.82 -3.90 -0.253 0.66553E+04 209 nontronite-Na 3.52 0.40 -3.12 -0.200 0.53291E+04 224 tobermorite 9.82 7.76 -2.07 -0.564 0.35287E+04 230 alabandite -0.98 -4.93 -3.95 -1.316 0.67409E+04 233 boehmite 4.41 0.74 -3.67 -0.611 0.62619E+04 235 ferrous-oxide 9.81 6.73 -3.08 -0.769 0.52532E+04 240 silica-amorphous -2.09 -3.16 -1.07 -0.355 0.18203E+04 242 an20ab80 2.02 1.35 -0.67 -0.052 0.11472E+04 243 an25ab75 2.65 1.78 -0.87 -0.067 0.14810E+04 244 an30ab70 3.28 2.21 -1.07 -0.082 0.18244E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 100.0000000 g Current total amount of reactant added: 7599.9990000 g New total amount of reactant added: 7699.9990000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.5221E-10 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 13 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 7699.9990000 Water: Moles liquid = 0.1250E+02 kg liquid = 0.2252E+00 Moles total = -.4101E+02 kg total = -.7389E+00 Activity = 1.0000 Stoichiometric ionic strength = .1171127E-01 Osmotic coef. = 0.9678 True ionic strength = .2031560E-01 Chg. balance for total moles = 0.5221E-10 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.89591E-10 -10.0477 0.75210E-10 -10.1237 0.83948E+00 -0.0760 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.60988E-03 -3.2148 0.50887E-03 -3.2934 0.83437E+00 -0.0786 4 SO4-- 0.28454E-11 -11.5459 0.14719E-11 -11.8321 0.51731E+00 -0.2863 5 HCO3- 0.10519E-05 -5.9780 0.87897E-06 -6.0560 0.83561E+00 -0.0780 6 HS- 0.11324E-03 -3.9460 0.94497E-04 -4.0246 0.83449E+00 -0.0786 7 Al+++ 0.10185E-28 -28.9920 0.23323E-29 -29.6322 0.22900E+00 -0.6402 8 H4SiO4 0.69598E-03 -3.1574 0.69598E-03 -3.1574 0.10000E+01 0.0000 9 Ca++ 0.13927E-06 -6.8561 0.71512E-07 -7.1456 0.51347E+00 -0.2895 10 Mg++ 0.21789E-10 -10.6618 0.11136E-10 -10.9533 0.51109E+00 -0.2915 11 Fe++ 0.60055E-13 -13.2215 0.30727E-13 -13.5125 0.51166E+00 -0.2910 12 K+ 0.15882E-03 -3.7991 0.13274E-03 -3.8770 0.83581E+00 -0.0779 13 Na+ 0.20154E-01 -1.6956 0.16813E-01 -1.7744 0.83422E+00 -0.0787 14 Mn++ 0.19277E-10 -10.7150 0.98717E-11 -11.0056 0.51209E+00 -0.2907 15 HPO4-- 0.44269E-07 -7.3539 0.22904E-07 -7.6401 0.51738E+00 -0.2862 16 HSiO3- 0.10356E-01 -1.9848 0.86407E-02 -2.0634 0.83437E+00 -0.0786 17 Ca(HSiO3)+ 0.16833E-07 -7.7738 0.14072E-07 -7.8516 0.83599E+00 -0.0778 18 Mg(HSiO3)+ 0.32623E-11 -11.4865 0.27273E-11 -11.5643 0.83599E+00 -0.0778 19 NaHSiO3,aq 0.23497E-02 -2.6290 0.23497E-02 -2.6290 0.10000E+01 0.0000 20 AlO+ 0.67099E-16 -16.1733 0.56094E-16 -16.2511 0.83599E+00 -0.0778 22 HAlO2,aq 0.14853E-09 -9.8282 0.14853E-09 -9.8282 0.10000E+01 0.0000 23 AlO2- 0.52489E-05 -5.2799 0.43715E-05 -5.3594 0.83285E+00 -0.0794 24 CH4,aq 0.55011E-04 -4.2596 0.54815E-04 -4.2611 0.99643E+00 -0.0016 25 C2H6,aq 0.44507E-13 -13.3516 0.44348E-13 -13.3531 0.99643E+00 -0.0016 29 CO,aq 0.41100E-16 -16.3862 0.41100E-16 -16.3862 0.10000E+01 0.0000 30 CO2,aq 0.14176E-09 -9.8484 0.14126E-09 -9.8500 0.99643E+00 -0.0016 31 CO3-2 0.19776E-05 -5.7039 0.10208E-05 -5.9911 0.51620E+00 -0.2872 32 CaCO3,aq 0.91533E-09 -9.0384 0.91533E-09 -9.0384 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.19193E-11 -11.7169 0.16045E-11 -11.7947 0.83599E+00 -0.0778 34 CaCl+ 0.70444E-10 -10.1522 0.58890E-10 -10.2300 0.83599E+00 -0.0778 35 CaCl2,aq 0.71196E-14 -14.1475 0.71196E-14 -14.1475 0.10000E+01 0.0000 36 CaOH+ 0.81060E-07 -7.0912 0.67765E-07 -7.1690 0.83599E+00 -0.0778 37 CaSO4,aq 0.33425E-16 -16.4759 0.33425E-16 -16.4759 0.10000E+01 0.0000 38 HCl,aq 0.70132E-14 -14.1541 0.70132E-14 -14.1541 0.10000E+01 0.0000 43 FeCl+ 0.29605E-16 -16.5286 0.24749E-16 -16.6064 0.83599E+00 -0.0778 46 FeO,aq 0.21112E-09 -9.6755 0.21112E-09 -9.6755 0.10000E+01 0.0000 47 FeOH+ 0.15908E-10 -10.7984 0.13299E-10 -10.8762 0.83599E+00 -0.0778 48 HFeO2- 0.35202E-07 -7.4534 0.29371E-07 -7.5321 0.83437E+00 -0.0786 49 FeO+ 0.11149E-16 -16.9528 0.93206E-17 -17.0306 0.83599E+00 -0.0778 51 FeO2- 0.40409E-09 -9.3935 0.33716E-09 -9.4722 0.83437E+00 -0.0786 52 HFeO2,aq 0.32252E-11 -11.4914 0.32252E-11 -11.4914 0.10000E+01 0.0000 53 H2,aq 0.11624E-04 -4.9347 0.11582E-04 -4.9362 0.99643E+00 -0.0016 54 KCl,aq 0.12243E-08 -8.9121 0.12243E-08 -8.9121 0.10000E+01 0.0000 56 KOH,aq 0.75375E-06 -6.1228 0.75375E-06 -6.1228 0.10000E+01 0.0000 57 KSO4- 0.36339E-14 -14.4396 0.30320E-14 -14.5183 0.83437E+00 -0.0786 58 MgCO3,aq 0.35729E-13 -13.4470 0.35729E-13 -13.4470 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.30540E-15 -15.5151 0.25531E-15 -15.5929 0.83599E+00 -0.0778 60 MgCl+ 0.99426E-14 -14.0025 0.83119E-14 -14.0803 0.83599E+00 -0.0778 61 MgOH+ 0.69850E-10 -10.1558 0.58394E-10 -10.2336 0.83599E+00 -0.0778 63 MnO,aq 0.18073E-08 -8.7430 0.18073E-08 -8.7430 0.10000E+01 0.0000 64 MnOH+ 0.47477E-09 -9.3235 0.39690E-09 -9.4013 0.83599E+00 -0.0778 65 MnO2-2 0.20542E-10 -10.6874 0.10604E-10 -10.9745 0.51620E+00 -0.2872 66 HMnO2- 0.20940E-09 -9.6790 0.17472E-09 -9.7577 0.83437E+00 -0.0786 69 MnCl+ 0.37002E-13 -13.4318 0.30934E-13 -13.5096 0.83599E+00 -0.0778 71 NaCl,aq 0.28353E-05 -5.5474 0.28353E-05 -5.5474 0.10000E+01 0.0000 72 NaOH,aq 0.96047E-04 -4.0175 0.96047E-04 -4.0175 0.10000E+01 0.0000 74 OH- 0.92239E-02 -2.0351 0.76821E-02 -2.1145 0.83285E+00 -0.0794 79 HPO3-2 0.16015E-14 -14.7955 0.82671E-15 -15.0826 0.51620E+00 -0.2872 81 H2PO3- 0.14943E-18 -18.8256 0.12468E-18 -18.9042 0.83437E+00 -0.0786 82 H3PO4,aq 0.90612E-18 -18.0428 0.90612E-18 -18.0428 0.10000E+01 0.0000 83 H2PO4- 0.38049E-10 -10.4197 0.31777E-10 -10.4979 0.83517E+00 -0.0782 84 PO4-3 0.10325E-08 -8.9861 0.24847E-09 -9.6047 0.24065E+00 -0.6186 88 HP2O7-3 0.91703E-18 -18.0376 0.21021E-18 -18.6773 0.22923E+00 -0.6397 89 P2O7-4 0.87936E-17 -17.0558 0.66772E-18 -18.1754 0.75933E-01 -1.1196 90 H2S,aq 0.22044E-07 -7.6567 0.21965E-07 -7.6583 0.99643E+00 -0.0016 91 S2-2 0.33094E-13 -13.4802 0.17083E-13 -13.7674 0.51620E+00 -0.2872 97 SO3-2 0.42299E-17 -17.3737 0.22154E-17 -17.6545 0.52375E+00 -0.2809 98 HSO3- 0.12504E-19 -19.9030 0.10433E-19 -19.9816 0.83437E+00 -0.0786 99 HSO4- 0.12749E-18 -18.8945 0.10669E-18 -18.9719 0.83681E+00 -0.0774 Charge balance for all species = 0.2320E-09 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.8959144E-10 -.2205245E-01 -.2218860E+02 0.0000 2 H2O 0.1000000E+01 0.5550494E+02 0.9981859E+06 0.0000 3 Cl- 0.6098808E-03 0.6127174E-03 0.2168460E+02 6.8303 4 SO4-- 0.2845363E-11 -.5791680E-04 -.5553831E+01 8.4153 5 HCO3- 0.1051902E-05 0.5804141E-04 0.3535318E+01 4.0677 6 HS- 0.1132385E-03 0.1711774E-03 0.5651257E+01 6.0991 7 Al+++ 0.1018479E-28 0.5249059E-05 0.1413793E+00 0.7390 8 H4SiO4 0.6959839E-03 0.1340164E-01 0.1285847E+04 -3.1574 9 Ca++ 0.1392723E-06 0.2381526E-06 0.9527953E-02 13.1018 10 Mg++ 0.2178929E-10 0.9494559E-10 0.2304272E-05 9.2942 11 Fe++ 0.6005476E-13 0.3583628E-07 0.1997841E-02 6.7350 12 K+ 0.1588226E-03 0.1595776E-03 0.6228869E+01 6.2467 13 Na+ 0.2015424E-01 0.2260277E-01 0.5187226E+03 8.3494 14 Mn++ 0.1927740E-10 0.2531333E-08 0.1388227E-03 9.2418 15 HPO4-- 0.4426889E-07 0.4533940E-07 0.4344005E-02 12.6074 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.1275005E+03 -.4965861E-02 -.1274956E+03 0.0000000E+00 2 H2O -.4101440E+02 0.1249883E+02 -.5351322E+02 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.2134187E+00 -.1304194E-04 0.2134318E+00 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.2133932E+00 0.3854641E-04 -.2134318E+00 0.0000000E+00 7 Al+++ 0.2510771E+02 0.1182004E-05 0.2510771E+02 0.0000000E+00 8 H4SiO4 0.8017842E+02 0.3017836E-02 0.8017540E+02 0.0000000E+00 9 Ca++ 0.8856112E+01 0.5362816E-07 0.8856112E+01 0.0000000E+00 10 Mg++ 0.6111110E+01 0.2138023E-10 0.6111110E+01 0.0000000E+00 11 Fe++ 0.5490165E+01 0.8069757E-08 0.5490165E+01 0.0000000E+00 12 K+ 0.1634819E+01 0.3593433E-04 0.1634783E+01 0.0000000E+00 13 Na+ 0.9665535E+01 0.5089783E-02 0.9660445E+01 0.0000000E+00 14 Mn++ 0.1335072E+00 0.5700157E-09 0.1335072E+00 0.0000000E+00 15 HPO4-- 0.4556533E-01 0.1020971E-07 0.4556532E-01 0.0000000E+00 Chg. balance for solid moles: 0.7258E-14 Mass of aqueous solution: 0.225579E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 7699.9990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 9.652 0.985 2531. 3.403 30.09 971.6 andradite 0.8537 -0.069 433.8 2.637 5.157 112.7 grossular 0.2067 -0.685 93.12 1.969 1.107 25.91 apatite-OH 0.1519E-01 -1.818 7.629 0.882 0.9070E-01 2.424 clinochlore 1.093 0.039 607.6 2.784 7.223 231.1 daphnite 0.3165 -0.500 225.8 2.354 2.684 68.43 chlorite-Mn 0.2670E-01 -1.573 18.93 1.277 0.2250 6.033 diopside 0.4095 -0.388 88.69 1.948 1.054 27.11 hedenbergite 0.1062 -0.974 26.35 1.421 0.3132 7.217 microcline 1.433 0.156 399.0 2.601 4.743 155.9 stilbite 4.953 0.695 3491. 3.543 41.49 1628. stilpnomelane-Fe 0.4026 -0.395 434.0 2.637 5.159 149.9 tr.625ac.25prg.125 0.6499E-01 -1.187 55.55 1.745 0.6604 17.88 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8051E+00 0.8051E+00 1.0000 -0.094 grossular 0.1949E+00 0.1949E+00 1.0000 -0.710 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.7611E+00 0.7611E+00 1.0000 -0.119 daphnite 0.2203E+00 0.2203E+00 1.0000 -0.657 chlorite-Mn 0.1859E-01 0.1859E-01 1.0000 -1.731 diopside 0.7941E+00 0.7941E+00 1.0000 -0.100 hedenbergite 0.2059E+00 0.2059E+00 1.0000 -0.686 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 tr.625ac.25prg.125 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 8412.105786 g Volume = 3404.260577 cm3 Porosity: -10.4921% V(tot) - V(min): -.32326E+03 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 7699.9990000 g log = 3.8865 Original solution: 1000.0103000 g Original solution / Rock added: 0.13 (Water/Rock Ratio), log = -0.8865 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.1165 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9150E+00 0.9847 0.1006E+01 0.1022E+01 CO2,gas 0.1345E-07 1.0061 0.1511E-07 0.1502E-07 CH4,gas 0.7143E-01 1.0117 0.8068E-01 0.7975E-01 H2,gas 0.1361E-01 1.0006 0.1521E-01 0.1520E-01 H2S,gas 0.5431E-06 0.9957 0.6038E-06 0.6064E-06 S2,gas 0.5301E-28 1.0000 0.5918E-28 0.5918E-28 CO,gas 0.5485E-13 1.0000 0.6125E-13 0.6125E-13 SO3,gas 0.2820E-47 1.0000 0.3148E-47 0.3148E-47 SO2,gas 0.1668E-26 1.0000 0.1862E-26 0.1862E-26 HCl,gas 0.1108E-16 1.0000 0.1237E-16 0.1237E-16 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 16 albite -0.38 -0.38 0.00 0.000 0.11184E-10 22 andradite 39.01 39.01 0.00 0.000 0.00000E+00 23 grossular 32.73 32.73 0.00 0.000 -0.48529E-10 32 apatite-OH -18.15 -18.15 0.00 0.000 0.60662E-11 46 clinochlore 39.07 39.07 0.00 0.000 -0.12132E-10 47 daphnite 28.97 28.97 0.00 0.000 0.30331E-10 48 chlorite-Mn 46.87 46.87 0.00 0.000 0.24265E-10 67 diopside 16.18 16.18 0.00 0.000 0.60662E-11 68 hedenbergite 14.21 14.21 0.00 0.000 0.12132E-10 116 microcline -2.49 -2.49 0.00 0.000 0.13649E-10 163 stilbite -7.52 -7.52 0.00 0.000 0.15165E-10 164 stilpnomelane-Fe 13.02 13.02 0.00 0.000 -0.27298E-10 245 tr.625ac.25prg.125 45.16 45.16 0.00 0.000 -0.48529E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -16.18 -9.52 -3.173 0.16254E+05 -7.821 3 CH4,gas 4.54 1.75 -2.79 -0.698 0.47676E+04 -1.093 4 H2,gas 8.00 4.48 -3.52 -2.010 0.60051E+04 -1.818 5 H2S,gas -6.23 -14.15 -7.92 -3.959 0.13520E+05 -6.219 6 S2,gas -7.34 -37.26 -29.93 -4.604 0.51099E+05 -28.228 7 CO,gas 3.21 -11.70 -14.91 -4.588 0.25462E+05 -13.213 8 SO3,gas 17.12 -32.08 -49.20 -12.300 0.84009E+05 -47.502 9 SO2,gas 0.83 -27.60 -28.43 -7.581 0.48542E+05 -26.730 10 HCl,gas 5.19 -13.42 -18.61 -9.303 0.31770E+05 -16.907 11 acmite 7.71 6.53 -1.18 -0.123 0.20175E+04 15 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 19 spessartine 24.46 19.73 -4.73 -0.236 0.80697E+04 20 analcite 3.32 2.77 -0.55 -0.061 0.93626E+03 26 annite 20.12 17.72 -2.40 -0.134 0.41064E+04 27 phlogopite 27.06 25.40 -1.67 -0.093 0.28489E+04 29 anorthite 12.71 8.26 -4.45 -0.342 0.75903E+04 35 aragonite 0.97 -3.08 -4.04 -1.348 0.69058E+04 36 brucite 12.57 9.29 -3.27 -0.655 0.55909E+04 37 calcite 0.81 -3.08 -3.89 -1.297 0.66416E+04 38 carnegieite-low 9.02 5.93 -3.09 -0.442 0.52801E+04 39 carnegieite-high 10.09 5.93 -4.16 -0.595 0.71071E+04 40 carpholite-Mg 8.58 4.46 -4.12 -0.275 0.70429E+04 41 carpholite-Fe 6.71 1.90 -4.81 -0.321 0.82207E+04 42 celadonite 5.34 3.65 -1.69 -0.099 0.28879E+04 43 celadonite-Fe 3.88 1.09 -2.79 -0.164 0.47561E+04 44 chrysotile 23.89 21.57 -2.32 -0.194 0.39692E+04 49 chlorite-Al-free 47.17 43.14 -4.04 -0.168 0.68936E+04 51 chloritoid-Fe 9.17 5.06 -4.12 -0.275 0.70316E+04 52 chloritoid-Mn 11.40 7.56 -3.84 -0.256 0.65545E+04 54 coesite -2.38 -3.16 -0.78 -0.260 0.13341E+04 61 cristobalite -2.56 -3.16 -0.60 -0.199 0.10195E+04 63 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71234E+04 65 diaspore 2.87 0.74 -2.13 -0.356 0.36450E+04 66 diamond -3.10 -7.21 -4.11 -1.175 0.70207E+04 71 enstatite 17.26 12.27 -4.99 -0.499 0.85226E+04 73 clinoenstatite 17.17 12.27 -4.89 -0.489 0.83541E+04 75 epidote 24.67 22.70 -1.97 -0.095 0.33586E+04 76 clinozoisite 22.81 18.95 -3.86 -0.175 0.65869E+04 77 epidote-Fe 29.84 26.46 -3.38 -0.176 0.57768E+04 78 fayalite 14.05 10.31 -3.73 -0.533 0.63743E+04 79 ferrosilite 11.15 7.16 -3.99 -0.399 0.68202E+04 83 gibbsite 4.08 0.74 -3.34 -0.477 0.57036E+04 84 glaucophane 22.97 20.80 -2.17 -0.059 0.37134E+04 85 glaucophane-Fe 17.28 13.12 -4.15 -0.112 0.70919E+04 86 graphite -3.55 -7.21 -3.67 -1.048 0.62629E+04 87 greenalite 16.14 13.89 -2.25 -0.187 0.38408E+04 90 hematite 12.57 8.99 -3.58 -0.434 0.61111E+04 91 heulandite -5.83 -7.52 -1.69 -0.077 0.28938E+04 95 jadeite 4.22 2.77 -1.44 -0.144 0.24617E+04 97 kalsilite 7.58 3.83 -3.76 -0.537 0.64126E+04 98 kaolinite -1.33 -4.84 -3.50 -0.319 0.59832E+04 101 laumontite 2.88 1.95 -0.93 -0.062 0.15935E+04 102 lawsonite 9.62 8.26 -1.35 -0.090 0.23070E+04 103 leucite 4.12 0.67 -3.45 -0.345 0.58873E+04 105 lizardite 23.24 21.57 -1.68 -0.140 0.28619E+04 107 magnetite 20.09 15.72 -4.37 -0.356 0.74536E+04 108 minnesotaite 10.39 7.58 -2.81 -0.165 0.48027E+04 112 manganosite 14.06 9.24 -4.82 -1.204 0.82237E+04 120 muscovite 2.58 -1.01 -3.59 -0.211 0.61315E+04 121 paragonite 4.24 1.09 -3.15 -0.185 0.53706E+04 122 nepheline 8.34 5.93 -2.41 -0.344 0.41125E+04 128 periclase-Fe 11.63 6.73 -4.89 -1.223 0.83523E+04 134 phlogopite-Na 29.65 27.50 -2.15 -0.119 0.36678E+04 136 prehnite 19.37 18.21 -1.16 -0.068 0.19849E+04 137 prehnite-Fe 22.50 21.96 -0.53 -0.032 0.91159E+03 138 pumpellyite-Fe 46.27 43.89 -2.38 -0.053 0.40582E+04 139 pumpellyite-Mg 48.99 46.45 -2.54 -0.057 0.43421E+04 142 pyrite -21.25 -26.04 -4.80 -1.129 0.81916E+04 143 pyrrhotite -4.26 -7.41 -3.15 -1.051 0.53837E+04 144 pyrrhotiteFe0.875 -6.02 -8.81 -2.79 -1.028 0.47709E+04 145 pyroxmangite 7.40 6.08 -1.31 -0.263 0.22440E+04 146 pyrophyllite -6.18 -11.15 -4.98 -0.311 0.84962E+04 147 quartz -2.99 -3.16 -0.17 -0.056 0.28680E+03 152 rhodonite 7.45 6.08 -1.36 -0.272 0.23243E+04 153 sanidine -1.28 -2.49 -1.21 -0.093 0.20677E+04 165 stilpnomelane-Mg 27.44 25.81 -1.63 -0.049 0.27804E+04 171 talc 16.49 15.25 -1.24 -0.073 0.21140E+04 174 tephroite 18.09 15.33 -2.76 -0.394 0.47118E+04 178 tridymite -2.63 -3.16 -0.53 -0.177 0.90677E+03 179 tremolite 47.87 47.42 -0.45 -0.012 0.77494E+03 180 ferroactinolite 38.45 34.62 -3.83 -0.104 0.65448E+04 181 troilite-low -4.41 -7.41 -3.00 -1.001 0.51265E+04 183 vesuvianite 223.47 218.82 -4.65 -0.036 0.79440E+04 187 wairakite 3.95 1.95 -2.00 -0.118 0.34155E+04 188 walstromite 11.51 9.94 -1.56 -0.313 0.26719E+04 189 wollastonite 10.46 9.94 -0.52 -0.103 0.88229E+03 190 pseudo-wollastonite 11.00 9.94 -1.06 -0.211 0.18021E+04 191 zoisite 22.85 18.95 -3.90 -0.177 0.66610E+04 192 akaganeite 7.75 4.49 -3.26 -0.705 0.55681E+04 199 chalcedony -2.80 -3.16 -0.35 -0.118 0.60609E+03 201 montmorillonite-Ca -2.29 -6.17 -3.88 -0.240 0.66180E+04 202 montmorillonite-K -2.24 -6.27 -4.03 -0.247 0.68816E+04 203 montmorillonite-Mg -2.48 -6.79 -4.32 -0.267 0.73678E+04 204 montmorillonite-Na -2.04 -5.57 -3.54 -0.216 0.60365E+04 205 nontronite-Ca 3.21 -0.19 -3.41 -0.221 0.58215E+04 206 nontronite-H 2.53 -2.36 -4.89 -0.328 0.83485E+04 207 nontronite-K 3.34 -0.30 -3.64 -0.233 0.62083E+04 208 nontronite-Mg 3.07 -0.82 -3.90 -0.253 0.66553E+04 209 nontronite-Na 3.52 0.40 -3.12 -0.200 0.53291E+04 224 tobermorite 9.82 7.76 -2.07 -0.564 0.35287E+04 230 alabandite -0.98 -4.91 -3.93 -1.310 0.67080E+04 233 boehmite 4.41 0.74 -3.67 -0.611 0.62619E+04 235 ferrous-oxide 9.81 6.73 -3.08 -0.769 0.52532E+04 240 silica-amorphous -2.09 -3.16 -1.07 -0.355 0.18203E+04 242 an20ab80 2.02 1.35 -0.67 -0.052 0.11472E+04 243 an25ab75 2.65 1.78 -0.87 -0.067 0.14810E+04 244 an30ab70 3.28 2.21 -1.07 -0.082 0.18244E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 100.0000000 g Current total amount of reactant added: 7699.9990000 g New total amount of reactant added: 7799.9990000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.5219E-10 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 13 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 7799.9990000 Water: Moles liquid = 0.1194E+02 kg liquid = 0.2151E+00 Moles total = -.4227E+02 kg total = -.7615E+00 Activity = 1.0000 Stoichiometric ionic strength = .1173504E-01 Osmotic coef. = 0.9677 True ionic strength = .2033424E-01 Chg. balance for total moles = 0.5219E-10 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.89673E-10 -10.0473 0.75274E-10 -10.1234 0.83943E+00 -0.0760 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.63835E-03 -3.1949 0.53259E-03 -3.2736 0.83432E+00 -0.0787 4 SO4-- 0.29762E-11 -11.5263 0.15392E-11 -11.8127 0.51718E+00 -0.2864 5 HCO3- 0.11002E-05 -5.9585 0.91928E-06 -6.0366 0.83555E+00 -0.0780 6 HS- 0.11852E-03 -3.9262 0.98902E-04 -4.0048 0.83444E+00 -0.0786 7 Al+++ 0.10216E-28 -28.9907 0.23383E-29 -29.6311 0.22887E+00 -0.6404 8 H4SiO4 0.69598E-03 -3.1574 0.69598E-03 -3.1574 0.10000E+01 0.0000 9 Ca++ 0.13954E-06 -6.8553 0.71633E-07 -7.1449 0.51334E+00 -0.2896 10 Mg++ 0.21832E-10 -10.6609 0.11155E-10 -10.9525 0.51096E+00 -0.2916 11 Fe++ 0.60172E-13 -13.2206 0.30780E-13 -13.5117 0.51153E+00 -0.2911 12 K+ 0.15897E-03 -3.7987 0.13286E-03 -3.8766 0.83576E+00 -0.0779 13 Na+ 0.20173E-01 -1.6952 0.16827E-01 -1.7740 0.83417E+00 -0.0787 14 Mn++ 0.19315E-10 -10.7141 0.98886E-11 -11.0049 0.51196E+00 -0.2908 15 HPO4-- 0.44204E-07 -7.3545 0.22865E-07 -7.6408 0.51726E+00 -0.2863 16 HSiO3- 0.10348E-01 -1.9852 0.86334E-02 -2.0638 0.83432E+00 -0.0787 17 Ca(HSiO3)+ 0.16848E-07 -7.7734 0.14084E-07 -7.8513 0.83594E+00 -0.0778 18 Mg(HSiO3)+ 0.32653E-11 -11.4861 0.27296E-11 -11.5639 0.83594E+00 -0.0778 19 NaHSiO3,aq 0.23497E-02 -2.6290 0.23497E-02 -2.6290 0.10000E+01 0.0000 20 AlO+ 0.67160E-16 -16.1729 0.56141E-16 -16.2507 0.83594E+00 -0.0778 22 HAlO2,aq 0.14853E-09 -9.8282 0.14853E-09 -9.8282 0.10000E+01 0.0000 23 AlO2- 0.52448E-05 -5.2803 0.43678E-05 -5.3597 0.83279E+00 -0.0795 24 CH4,aq 0.57582E-04 -4.2397 0.57377E-04 -4.2413 0.99642E+00 -0.0016 25 C2H6,aq 0.48765E-13 -13.3119 0.48591E-13 -13.3134 0.99642E+00 -0.0016 29 CO,aq 0.43021E-16 -16.3663 0.43021E-16 -16.3663 0.10000E+01 0.0000 30 CO2,aq 0.14839E-09 -9.8286 0.14786E-09 -9.8302 0.99642E+00 -0.0016 31 CO3-2 0.20670E-05 -5.6847 0.10667E-05 -5.9720 0.51607E+00 -0.2873 32 CaCO3,aq 0.95812E-09 -9.0186 0.95812E-09 -9.0186 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.20108E-11 -11.6966 0.16809E-11 -11.7745 0.83594E+00 -0.0778 34 CaCl+ 0.73857E-10 -10.1316 0.61740E-10 -10.2094 0.83594E+00 -0.0778 35 CaCl2,aq 0.78120E-14 -14.1072 0.78120E-14 -14.1072 0.10000E+01 0.0000 36 CaOH+ 0.81133E-07 -7.0908 0.67822E-07 -7.1686 0.83594E+00 -0.0778 37 CaSO4,aq 0.35013E-16 -16.4558 0.35013E-16 -16.4558 0.10000E+01 0.0000 38 HCl,aq 0.73463E-14 -14.1339 0.73463E-14 -14.1339 0.10000E+01 0.0000 43 FeCl+ 0.31040E-16 -16.5081 0.25947E-16 -16.5859 0.83594E+00 -0.0778 46 FeO,aq 0.21112E-09 -9.6755 0.21112E-09 -9.6755 0.10000E+01 0.0000 47 FeOH+ 0.15922E-10 -10.7980 0.13310E-10 -10.8758 0.83594E+00 -0.0778 48 HFeO2- 0.35174E-07 -7.4538 0.29346E-07 -7.5324 0.83432E+00 -0.0787 49 FeO+ 0.11159E-16 -16.9524 0.93285E-17 -17.0302 0.83594E+00 -0.0778 51 FeO2- 0.40377E-09 -9.3939 0.33688E-09 -9.4725 0.83432E+00 -0.0787 52 HFeO2,aq 0.32252E-11 -11.4914 0.32252E-11 -11.4914 0.10000E+01 0.0000 53 H2,aq 0.11624E-04 -4.9346 0.11582E-04 -4.9362 0.99642E+00 -0.0016 54 KCl,aq 0.12824E-08 -8.8920 0.12824E-08 -8.8920 0.10000E+01 0.0000 56 KOH,aq 0.75375E-06 -6.1228 0.75375E-06 -6.1228 0.10000E+01 0.0000 57 KSO4- 0.38035E-14 -14.4198 0.31733E-14 -14.4985 0.83432E+00 -0.0787 58 MgCO3,aq 0.37399E-13 -13.4271 0.37399E-13 -13.4271 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.31997E-15 -15.4949 0.26747E-15 -15.5727 0.83594E+00 -0.0778 60 MgCl+ 0.10424E-13 -13.9819 0.87141E-14 -14.0598 0.83594E+00 -0.0778 61 MgOH+ 0.69914E-10 -10.1554 0.58444E-10 -10.2333 0.83594E+00 -0.0778 63 MnO,aq 0.18073E-08 -8.7430 0.18073E-08 -8.7430 0.10000E+01 0.0000 64 MnOH+ 0.47521E-09 -9.3231 0.39724E-09 -9.4009 0.83594E+00 -0.0778 65 MnO2-2 0.20512E-10 -10.6880 0.10586E-10 -10.9753 0.51607E+00 -0.2873 66 HMnO2- 0.20924E-09 -9.6794 0.17457E-09 -9.7580 0.83432E+00 -0.0787 69 MnCl+ 0.38796E-13 -13.4112 0.32431E-13 -13.4890 0.83594E+00 -0.0778 71 NaCl,aq 0.29700E-05 -5.5272 0.29700E-05 -5.5272 0.10000E+01 0.0000 72 NaOH,aq 0.96047E-04 -4.0175 0.96047E-04 -4.0175 0.10000E+01 0.0000 74 OH- 0.92167E-02 -2.0354 0.76756E-02 -2.1149 0.83279E+00 -0.0795 79 HPO3-2 0.15992E-14 -14.7961 0.82530E-15 -15.0834 0.51607E+00 -0.2873 81 H2PO3- 0.14932E-18 -18.8259 0.12458E-18 -18.9046 0.83432E+00 -0.0787 82 H3PO4,aq 0.90612E-18 -18.0428 0.90612E-18 -18.0428 0.10000E+01 0.0000 83 H2PO4- 0.38019E-10 -10.4200 0.31750E-10 -10.4983 0.83512E+00 -0.0783 84 PO4-3 0.10304E-08 -8.9870 0.24783E-09 -9.6058 0.24053E+00 -0.6188 88 HP2O7-3 0.91520E-18 -18.0385 0.20968E-18 -18.6784 0.22911E+00 -0.6400 89 P2O7-4 0.87721E-17 -17.0569 0.66545E-18 -18.1769 0.75860E-01 -1.1200 90 H2S,aq 0.23091E-07 -7.6365 0.23009E-07 -7.6381 0.99642E+00 -0.0016 91 S2-2 0.36260E-13 -13.4406 0.18713E-13 -13.7279 0.51607E+00 -0.2873 97 SO3-2 0.44244E-17 -17.3541 0.23167E-17 -17.6351 0.52363E+00 -0.2810 98 HSO3- 0.13087E-19 -19.8832 0.10919E-19 -19.9618 0.83432E+00 -0.0787 99 HSO4- 0.13344E-18 -18.8747 0.11166E-18 -18.9521 0.83676E+00 -0.0774 Charge balance for all species = 0.2428E-09 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.8967285E-10 -.2203710E-01 -.2217313E+02 0.0000 2 H2O 0.1000000E+01 0.5550495E+02 0.9981851E+06 0.0000 3 Cl- 0.6383472E-03 0.6413186E-03 0.2269680E+02 6.8497 4 SO4-- 0.2976185E-11 -.6048839E-04 -.5800424E+01 8.4340 5 HCO3- 0.1100199E-05 0.6075074E-04 0.3700341E+01 4.0868 6 HS- 0.1185244E-03 0.1790359E-03 0.5910693E+01 6.1186 7 Al+++ 0.1021644E-28 0.5244924E-05 0.1412678E+00 0.7390 8 H4SiO4 0.6959840E-03 0.1339348E-01 0.1285062E+04 -3.1574 9 Ca++ 0.1395437E-06 0.2385596E-06 0.9544228E-02 13.1018 10 Mg++ 0.2183183E-10 0.9505932E-10 0.2307030E-05 9.2942 11 Fe++ 0.6017198E-13 0.3580821E-07 0.1996275E-02 6.7350 12 K+ 0.1589674E-03 0.1597225E-03 0.6234517E+01 6.2467 13 Na+ 0.2017264E-01 0.2262131E-01 0.5191475E+03 8.3494 14 Mn++ 0.1931531E-10 0.2531647E-08 0.1388398E-03 9.2418 15 HPO4-- 0.4420427E-07 0.4527265E-07 0.4337605E-02 12.6059 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.1291564E+03 -.4741092E-02 -.1291516E+03 0.0000000E+00 2 H2O -.4226794E+02 0.1194141E+02 -.5420935E+02 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.2161901E+00 -.1301356E-04 0.2162031E+00 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.2161646E+00 0.3851803E-04 -.2162031E+00 0.0000000E+00 7 Al+++ 0.2543378E+02 0.1128400E-05 0.2543378E+02 0.0000000E+00 8 H4SiO4 0.8121970E+02 0.2881492E-02 0.8121682E+02 0.0000000E+00 9 Ca++ 0.8971126E+01 0.5132405E-07 0.8971126E+01 0.0000000E+00 10 Mg++ 0.6190475E+01 0.2045120E-10 0.6190475E+01 0.0000000E+00 11 Fe++ 0.5561466E+01 0.7703829E-08 0.5561466E+01 0.0000000E+00 12 K+ 0.1656051E+01 0.3436291E-04 0.1656016E+01 0.0000000E+00 13 Na+ 0.9791059E+01 0.4866780E-02 0.9786192E+01 0.0000000E+00 14 Mn++ 0.1352410E+00 0.5446621E-09 0.1352410E+00 0.0000000E+00 15 HPO4-- 0.4615709E-01 0.9740021E-08 0.4615708E-01 0.0000000E+00 Chg. balance for solid moles: -.5412E-15 Mass of aqueous solution: 0.215519E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 7799.9990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 9.778 0.990 2564. 3.409 30.09 984.3 andradite 0.8648 -0.063 439.5 2.643 5.157 114.2 grossular 0.2094 -0.679 94.32 1.975 1.107 26.24 apatite-OH 0.1539E-01 -1.813 7.729 0.888 0.9070E-01 2.456 clinochlore 1.107 0.044 615.5 2.789 7.223 234.1 daphnite 0.3206 -0.494 228.7 2.359 2.684 69.31 chlorite-Mn 0.2705E-01 -1.568 19.18 1.283 0.2250 6.111 diopside 0.4150 -0.382 89.87 1.954 1.055 27.47 hedenbergite 0.1076 -0.968 26.70 1.427 0.3133 7.313 microcline 1.452 0.162 404.2 2.607 4.743 157.9 stilbite 5.017 0.700 3536. 3.548 41.49 1649. stilpnomelane-Fe 0.4078 -0.390 439.6 2.643 5.159 151.9 tr.625ac.25prg.125 0.6583E-01 -1.182 56.27 1.750 0.6603 18.11 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8051E+00 0.8051E+00 1.0000 -0.094 grossular 0.1949E+00 0.1949E+00 1.0000 -0.710 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.7611E+00 0.7611E+00 1.0000 -0.119 daphnite 0.2203E+00 0.2203E+00 1.0000 -0.657 chlorite-Mn 0.1859E-01 0.1859E-01 1.0000 -1.731 diopside 0.7941E+00 0.7941E+00 1.0000 -0.100 hedenbergite 0.2059E+00 0.2059E+00 1.0000 -0.686 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 tr.625ac.25prg.125 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 8521.356448 g Volume = 3448.463640 cm3 Porosity: -10.4923% V(tot) - V(min): -.32746E+03 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 7799.9990000 g log = 3.8921 Original solution: 1000.0103000 g Original solution / Rock added: 0.13 (Water/Rock Ratio), log = -0.8921 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.1203 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9119E+00 0.9847 0.1006E+01 0.1022E+01 CO2,gas 0.1404E-07 1.0061 0.1582E-07 0.1572E-07 CH4,gas 0.7452E-01 1.0116 0.8445E-01 0.8348E-01 H2,gas 0.1357E-01 1.0006 0.1521E-01 0.1520E-01 H2S,gas 0.5670E-06 0.9956 0.6325E-06 0.6353E-06 S2,gas 0.5797E-28 1.0000 0.6494E-28 0.6494E-28 CO,gas 0.5722E-13 1.0000 0.6411E-13 0.6411E-13 SO3,gas 0.2944E-47 1.0000 0.3298E-47 0.3298E-47 SO2,gas 0.1741E-26 1.0000 0.1951E-26 0.1951E-26 HCl,gas 0.1157E-16 1.0000 0.1296E-16 0.1296E-16 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 16 albite -0.38 -0.38 0.00 0.000 -0.13080E-10 22 andradite 39.01 39.01 0.00 0.000 0.24265E-10 23 grossular 32.73 32.73 0.00 0.000 0.00000E+00 32 apatite-OH -18.15 -18.15 0.00 0.000 -0.60662E-11 46 clinochlore 39.07 39.07 0.00 0.000 -0.36397E-10 47 daphnite 28.97 28.97 0.00 0.000 -0.12132E-10 48 chlorite-Mn 46.87 46.87 0.00 0.000 -0.24265E-10 67 diopside 16.18 16.18 0.00 0.000 -0.12132E-10 68 hedenbergite 14.21 14.21 0.00 0.000 -0.12132E-10 116 microcline -2.49 -2.49 0.00 0.000 -0.10616E-10 163 stilbite -7.52 -7.52 0.00 0.000 -0.90992E-11 164 stilpnomelane-Fe 13.02 13.02 0.00 0.000 -0.27298E-10 245 tr.625ac.25prg.125 45.16 45.16 0.00 0.000 -0.24265E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -16.16 -9.50 -3.167 0.16221E+05 -7.801 3 CH4,gas 4.54 1.77 -2.77 -0.693 0.47337E+04 -1.073 4 H2,gas 8.00 4.48 -3.52 -2.010 0.60051E+04 -1.818 5 H2S,gas -6.23 -14.13 -7.90 -3.949 0.13485E+05 -6.199 6 S2,gas -7.34 -37.22 -29.89 -4.598 0.51030E+05 -28.187 7 CO,gas 3.21 -11.68 -14.89 -4.582 0.25428E+05 -13.193 8 SO3,gas 17.12 -32.06 -49.18 -12.295 0.83975E+05 -47.482 9 SO2,gas 0.83 -27.58 -28.41 -7.576 0.48507E+05 -26.710 10 HCl,gas 5.19 -13.40 -18.59 -9.293 0.31736E+05 -16.887 11 acmite 7.71 6.53 -1.18 -0.123 0.20175E+04 15 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 19 spessartine 24.46 19.73 -4.73 -0.236 0.80696E+04 20 analcite 3.32 2.77 -0.55 -0.061 0.93626E+03 26 annite 20.12 17.72 -2.40 -0.134 0.41064E+04 27 phlogopite 27.06 25.40 -1.67 -0.093 0.28489E+04 29 anorthite 12.71 8.26 -4.45 -0.342 0.75903E+04 35 aragonite 0.97 -3.06 -4.02 -1.342 0.68719E+04 36 brucite 12.57 9.29 -3.27 -0.655 0.55909E+04 37 calcite 0.81 -3.06 -3.87 -1.290 0.66077E+04 38 carnegieite-low 9.02 5.93 -3.09 -0.442 0.52801E+04 39 carnegieite-high 10.09 5.93 -4.16 -0.595 0.71071E+04 40 carpholite-Mg 8.58 4.46 -4.12 -0.275 0.70429E+04 41 carpholite-Fe 6.71 1.90 -4.81 -0.321 0.82207E+04 42 celadonite 5.34 3.65 -1.69 -0.099 0.28879E+04 43 celadonite-Fe 3.88 1.09 -2.79 -0.164 0.47561E+04 44 chrysotile 23.89 21.57 -2.32 -0.194 0.39692E+04 49 chlorite-Al-free 47.17 43.14 -4.04 -0.168 0.68936E+04 51 chloritoid-Fe 9.17 5.06 -4.12 -0.275 0.70316E+04 52 chloritoid-Mn 11.40 7.56 -3.84 -0.256 0.65545E+04 54 coesite -2.38 -3.16 -0.78 -0.260 0.13341E+04 61 cristobalite -2.56 -3.16 -0.60 -0.199 0.10195E+04 63 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71234E+04 65 diaspore 2.87 0.74 -2.13 -0.356 0.36450E+04 66 diamond -3.10 -7.19 -4.09 -1.169 0.69868E+04 71 enstatite 17.26 12.27 -4.99 -0.499 0.85226E+04 73 clinoenstatite 17.17 12.27 -4.89 -0.489 0.83541E+04 75 epidote 24.67 22.70 -1.97 -0.095 0.33586E+04 76 clinozoisite 22.81 18.95 -3.86 -0.175 0.65869E+04 77 epidote-Fe 29.84 26.46 -3.38 -0.176 0.57768E+04 78 fayalite 14.05 10.31 -3.73 -0.533 0.63743E+04 79 ferrosilite 11.15 7.16 -3.99 -0.399 0.68202E+04 83 gibbsite 4.08 0.74 -3.34 -0.477 0.57036E+04 84 glaucophane 22.97 20.80 -2.17 -0.059 0.37134E+04 85 glaucophane-Fe 17.28 13.12 -4.15 -0.112 0.70919E+04 86 graphite -3.55 -7.19 -3.65 -1.042 0.62290E+04 87 greenalite 16.14 13.89 -2.25 -0.187 0.38408E+04 90 hematite 12.57 8.99 -3.58 -0.434 0.61111E+04 91 heulandite -5.83 -7.52 -1.69 -0.077 0.28938E+04 95 jadeite 4.22 2.77 -1.44 -0.144 0.24617E+04 97 kalsilite 7.58 3.83 -3.76 -0.537 0.64126E+04 98 kaolinite -1.33 -4.84 -3.50 -0.319 0.59832E+04 101 laumontite 2.88 1.95 -0.93 -0.062 0.15935E+04 102 lawsonite 9.62 8.26 -1.35 -0.090 0.23070E+04 103 leucite 4.12 0.67 -3.45 -0.345 0.58873E+04 105 lizardite 23.24 21.57 -1.68 -0.140 0.28619E+04 107 magnetite 20.09 15.72 -4.37 -0.356 0.74536E+04 108 minnesotaite 10.39 7.58 -2.81 -0.165 0.48027E+04 112 manganosite 14.06 9.24 -4.82 -1.204 0.82236E+04 120 muscovite 2.58 -1.01 -3.59 -0.211 0.61315E+04 121 paragonite 4.24 1.09 -3.15 -0.185 0.53706E+04 122 nepheline 8.34 5.93 -2.41 -0.344 0.41125E+04 128 periclase-Fe 11.63 6.73 -4.89 -1.223 0.83523E+04 134 phlogopite-Na 29.65 27.50 -2.15 -0.119 0.36678E+04 136 prehnite 19.37 18.21 -1.16 -0.068 0.19849E+04 137 prehnite-Fe 22.50 21.96 -0.53 -0.032 0.91159E+03 138 pumpellyite-Fe 46.27 43.89 -2.38 -0.053 0.40582E+04 139 pumpellyite-Mg 48.99 46.45 -2.54 -0.057 0.43421E+04 142 pyrite -21.25 -26.00 -4.76 -1.119 0.81228E+04 143 pyrrhotite -4.26 -7.39 -3.13 -1.044 0.53493E+04 144 pyrrhotiteFe0.875 -6.02 -8.79 -2.77 -1.020 0.47365E+04 145 pyroxmangite 7.40 6.08 -1.31 -0.263 0.22440E+04 146 pyrophyllite -6.18 -11.15 -4.98 -0.311 0.84962E+04 147 quartz -2.99 -3.16 -0.17 -0.056 0.28680E+03 152 rhodonite 7.45 6.08 -1.36 -0.272 0.23243E+04 153 sanidine -1.28 -2.49 -1.21 -0.093 0.20677E+04 165 stilpnomelane-Mg 27.44 25.81 -1.63 -0.049 0.27804E+04 171 talc 16.49 15.25 -1.24 -0.073 0.21140E+04 174 tephroite 18.09 15.33 -2.76 -0.394 0.47118E+04 178 tridymite -2.63 -3.16 -0.53 -0.177 0.90677E+03 179 tremolite 47.87 47.42 -0.45 -0.012 0.77494E+03 180 ferroactinolite 38.45 34.62 -3.83 -0.104 0.65448E+04 181 troilite-low -4.41 -7.39 -2.98 -0.994 0.50921E+04 183 vesuvianite 223.47 218.82 -4.65 -0.036 0.79440E+04 187 wairakite 3.95 1.95 -2.00 -0.118 0.34155E+04 188 walstromite 11.51 9.94 -1.56 -0.313 0.26719E+04 189 wollastonite 10.46 9.94 -0.52 -0.103 0.88229E+03 190 pseudo-wollastonite 11.00 9.94 -1.06 -0.211 0.18021E+04 191 zoisite 22.85 18.95 -3.90 -0.177 0.66610E+04 192 akaganeite 7.75 4.49 -3.26 -0.705 0.55681E+04 199 chalcedony -2.80 -3.16 -0.35 -0.118 0.60609E+03 201 montmorillonite-Ca -2.29 -6.17 -3.88 -0.240 0.66180E+04 202 montmorillonite-K -2.24 -6.27 -4.03 -0.247 0.68816E+04 203 montmorillonite-Mg -2.48 -6.79 -4.32 -0.267 0.73678E+04 204 montmorillonite-Na -2.04 -5.57 -3.54 -0.216 0.60365E+04 205 nontronite-Ca 3.21 -0.19 -3.41 -0.221 0.58215E+04 206 nontronite-H 2.53 -2.36 -4.89 -0.328 0.83485E+04 207 nontronite-K 3.34 -0.30 -3.64 -0.233 0.62083E+04 208 nontronite-Mg 3.07 -0.82 -3.90 -0.253 0.66553E+04 209 nontronite-Na 3.52 0.40 -3.12 -0.200 0.53291E+04 224 tobermorite 9.82 7.76 -2.07 -0.564 0.35287E+04 230 alabandite -0.98 -4.89 -3.91 -1.303 0.66735E+04 233 boehmite 4.41 0.74 -3.67 -0.611 0.62619E+04 235 ferrous-oxide 9.81 6.73 -3.08 -0.769 0.52532E+04 240 silica-amorphous -2.09 -3.16 -1.07 -0.355 0.18203E+04 242 an20ab80 2.02 1.35 -0.67 -0.052 0.11472E+04 243 an25ab75 2.65 1.78 -0.87 -0.067 0.14810E+04 244 an30ab70 3.28 2.21 -1.07 -0.082 0.18244E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 100.0000000 g Current total amount of reactant added: 7799.9990000 g New total amount of reactant added: 7899.9990000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.5216E-10 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 13 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 7899.9990000 Water: Moles liquid = 0.1138E+02 kg liquid = 0.2051E+00 Moles total = -.4352E+02 kg total = -.7841E+00 Activity = 1.0000 Stoichiometric ionic strength = .1176114E-01 Osmotic coef. = 0.9677 True ionic strength = .2035471E-01 Chg. balance for total moles = 0.5216E-10 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.89762E-10 -10.0469 0.75344E-10 -10.1229 0.83938E+00 -0.0760 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.66960E-03 -3.1742 0.55862E-03 -3.2529 0.83426E+00 -0.0787 4 SO4-- 0.31196E-11 -11.5059 0.16130E-11 -11.7924 0.51705E+00 -0.2865 5 HCO3- 0.11531E-05 -5.9381 0.96345E-06 -6.0162 0.83550E+00 -0.0781 6 HS- 0.12433E-03 -3.9054 0.10374E-03 -3.9841 0.83439E+00 -0.0786 7 Al+++ 0.10251E-28 -28.9892 0.23448E-29 -29.6299 0.22874E+00 -0.6407 8 H4SiO4 0.69598E-03 -3.1574 0.69598E-03 -3.1574 0.10000E+01 0.0000 9 Ca++ 0.13984E-06 -6.8544 0.71767E-07 -7.1441 0.51320E+00 -0.2897 10 Mg++ 0.21879E-10 -10.6600 0.11176E-10 -10.9517 0.51082E+00 -0.2917 11 Fe++ 0.60301E-13 -13.2197 0.30837E-13 -13.5109 0.51139E+00 -0.2912 12 K+ 0.15913E-03 -3.7983 0.13298E-03 -3.8762 0.83570E+00 -0.0779 13 Na+ 0.20193E-01 -1.6948 0.16843E-01 -1.7736 0.83411E+00 -0.0788 14 Mn++ 0.19357E-10 -10.7132 0.99073E-11 -11.0040 0.51182E+00 -0.2909 15 HPO4-- 0.44133E-07 -7.3552 0.22822E-07 -7.6416 0.51712E+00 -0.2864 16 HSiO3- 0.10339E-01 -1.9855 0.86253E-02 -2.0642 0.83426E+00 -0.0787 17 Ca(HSiO3)+ 0.16865E-07 -7.7730 0.14097E-07 -7.8509 0.83588E+00 -0.0779 18 Mg(HSiO3)+ 0.32686E-11 -11.4856 0.27321E-11 -11.5635 0.83588E+00 -0.0779 19 NaHSiO3,aq 0.23497E-02 -2.6290 0.23497E-02 -2.6290 0.10000E+01 0.0000 20 AlO+ 0.67227E-16 -16.1725 0.56194E-16 -16.2503 0.83588E+00 -0.0779 22 HAlO2,aq 0.14853E-09 -9.8282 0.14853E-09 -9.8282 0.10000E+01 0.0000 23 AlO2- 0.52402E-05 -5.2806 0.43637E-05 -5.3601 0.83274E+00 -0.0795 24 CH4,aq 0.60406E-04 -4.2189 0.60190E-04 -4.2205 0.99642E+00 -0.0016 25 C2H6,aq 0.53665E-13 -13.2703 0.53473E-13 -13.2719 0.99642E+00 -0.0016 29 CO,aq 0.45130E-16 -16.3455 0.45130E-16 -16.3455 0.10000E+01 0.0000 30 CO2,aq 0.15567E-09 -9.8078 0.15511E-09 -9.8094 0.99642E+00 -0.0016 31 CO3-2 0.21648E-05 -5.6646 0.11169E-05 -5.9520 0.51594E+00 -0.2874 32 CaCO3,aq 0.10051E-08 -8.9978 0.10051E-08 -8.9978 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.21115E-11 -11.6754 0.17650E-11 -11.7533 0.83588E+00 -0.0779 34 CaCl+ 0.77618E-10 -10.1100 0.64880E-10 -10.1879 0.83588E+00 -0.0779 35 CaCl2,aq 0.86106E-14 -14.0650 0.86106E-14 -14.0650 0.10000E+01 0.0000 36 CaOH+ 0.81215E-07 -7.0904 0.67886E-07 -7.1682 0.83588E+00 -0.0779 37 CaSO4,aq 0.36759E-16 -16.4346 0.36759E-16 -16.4346 0.10000E+01 0.0000 38 HCl,aq 0.77126E-14 -14.1128 0.77126E-14 -14.1128 0.10000E+01 0.0000 43 FeCl+ 0.32620E-16 -16.4865 0.27267E-16 -16.5644 0.83588E+00 -0.0779 46 FeO,aq 0.21112E-09 -9.6755 0.21112E-09 -9.6755 0.10000E+01 0.0000 47 FeOH+ 0.15938E-10 -10.7976 0.13323E-10 -10.8754 0.83588E+00 -0.0779 48 HFeO2- 0.35144E-07 -7.4542 0.29319E-07 -7.5329 0.83426E+00 -0.0787 49 FeO+ 0.11170E-16 -16.9519 0.93372E-17 -17.0298 0.83588E+00 -0.0779 51 FeO2- 0.40342E-09 -9.3942 0.33656E-09 -9.4729 0.83426E+00 -0.0787 52 HFeO2,aq 0.32252E-11 -11.4914 0.32252E-11 -11.4914 0.10000E+01 0.0000 53 H2,aq 0.11624E-04 -4.9346 0.11582E-04 -4.9362 0.99642E+00 -0.0016 54 KCl,aq 0.13464E-08 -8.8708 0.13464E-08 -8.8708 0.10000E+01 0.0000 56 KOH,aq 0.75375E-06 -6.1228 0.75375E-06 -6.1228 0.10000E+01 0.0000 57 KSO4- 0.39897E-14 -14.3991 0.33285E-14 -14.4778 0.83426E+00 -0.0787 58 MgCO3,aq 0.39233E-13 -13.4063 0.39233E-13 -13.4063 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.33599E-15 -15.4737 0.28085E-15 -15.5515 0.83588E+00 -0.0779 60 MgCl+ 0.10955E-13 -13.9604 0.91572E-14 -14.0382 0.83588E+00 -0.0779 61 MgOH+ 0.69984E-10 -10.1550 0.58498E-10 -10.2329 0.83588E+00 -0.0779 63 MnO,aq 0.18074E-08 -8.7430 0.18074E-08 -8.7430 0.10000E+01 0.0000 64 MnOH+ 0.47569E-09 -9.3227 0.39762E-09 -9.4005 0.83588E+00 -0.0779 65 MnO2-2 0.20479E-10 -10.6887 0.10566E-10 -10.9761 0.51594E+00 -0.2874 66 HMnO2- 0.20906E-09 -9.6797 0.17441E-09 -9.7584 0.83426E+00 -0.0787 69 MnCl+ 0.40772E-13 -13.3896 0.34081E-13 -13.4675 0.83588E+00 -0.0779 71 NaCl,aq 0.31181E-05 -5.5061 0.31181E-05 -5.5061 0.10000E+01 0.0000 72 NaOH,aq 0.96047E-04 -4.0175 0.96047E-04 -4.0175 0.10000E+01 0.0000 74 OH- 0.92087E-02 -2.0358 0.76684E-02 -2.1153 0.83274E+00 -0.0795 79 HPO3-2 0.15966E-14 -14.7968 0.82376E-15 -15.0842 0.51594E+00 -0.2874 81 H2PO3- 0.14919E-18 -18.8263 0.12446E-18 -18.9050 0.83426E+00 -0.0787 82 H3PO4,aq 0.90612E-18 -18.0428 0.90612E-18 -18.0428 0.10000E+01 0.0000 83 H2PO4- 0.37986E-10 -10.4204 0.31721E-10 -10.4987 0.83506E+00 -0.0783 84 PO4-3 0.10281E-08 -8.9880 0.24714E-09 -9.6071 0.24039E+00 -0.6191 88 HP2O7-3 0.91319E-18 -18.0394 0.20909E-18 -18.6797 0.22897E+00 -0.6402 89 P2O7-4 0.87486E-17 -17.0581 0.66297E-18 -18.1785 0.75780E-01 -1.1204 90 H2S,aq 0.24243E-07 -7.6154 0.24156E-07 -7.6170 0.99642E+00 -0.0016 91 S2-2 0.39904E-13 -13.3990 0.20588E-13 -13.6864 0.51594E+00 -0.2874 97 SO3-2 0.46376E-17 -17.3337 0.24277E-17 -17.6148 0.52350E+00 -0.2811 98 HSO3- 0.13728E-19 -19.8624 0.11453E-19 -19.9411 0.83426E+00 -0.0787 99 HSO4- 0.13998E-18 -18.8539 0.11712E-18 -18.9314 0.83671E+00 -0.0774 Charge balance for all species = 0.2544E-09 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.8976230E-10 -.2202026E-01 -.2215616E+02 0.0000 2 H2O 0.1000000E+01 0.5550495E+02 0.9981841E+06 0.0000 3 Cl- 0.6696011E-03 0.6727206E-03 0.2380812E+02 6.8701 4 SO4-- 0.3119616E-11 -.6331219E-04 -.6071200E+01 8.4535 5 HCO3- 0.1153143E-05 0.6372539E-04 0.3881524E+01 4.1068 6 HS- 0.1243279E-03 0.1876643E-03 0.6195546E+01 6.1389 7 Al+++ 0.1025130E-28 0.5240389E-05 0.1411455E+00 0.7390 8 H4SiO4 0.6959840E-03 0.1338452E-01 0.1284202E+04 -3.1574 9 Ca++ 0.1398424E-06 0.2390071E-06 0.9562123E-02 13.1018 10 Mg++ 0.2187864E-10 0.9518419E-10 0.2310058E-05 9.2942 11 Fe++ 0.6030093E-13 0.3577743E-07 0.1994557E-02 6.7350 12 K+ 0.1591265E-03 0.1598816E-03 0.6240724E+01 6.2467 13 Na+ 0.2019286E-01 0.2264167E-01 0.5196144E+03 8.3494 14 Mn++ 0.1935697E-10 0.2531989E-08 0.1388584E-03 9.2419 15 HPO4-- 0.4413344E-07 0.4519949E-07 0.4330591E-02 12.6043 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.1308122E+03 -.4516327E-02 -.1308077E+03 0.0000000E+00 2 H2O -.4352148E+02 0.1138400E+02 -.5490548E+02 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.2189614E+00 -.1298525E-04 0.2189744E+00 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.2189359E+00 0.3848972E-04 -.2189744E+00 0.0000000E+00 7 Al+++ 0.2575986E+02 0.1074797E-05 0.2575985E+02 0.0000000E+00 8 H4SiO4 0.8226097E+02 0.2745149E-02 0.8225823E+02 0.0000000E+00 9 Ca++ 0.9086140E+01 0.4902007E-07 0.9086140E+01 0.0000000E+00 10 Mg++ 0.6269840E+01 0.1952216E-10 0.6269840E+01 0.0000000E+00 11 Fe++ 0.5632767E+01 0.7337907E-08 0.5632767E+01 0.0000000E+00 12 K+ 0.1677282E+01 0.3279152E-04 0.1677249E+01 0.0000000E+00 13 Na+ 0.9916583E+01 0.4643780E-02 0.9911940E+01 0.0000000E+00 14 Mn++ 0.1369749E+00 0.5193078E-09 0.1369749E+00 0.0000000E+00 15 HPO4-- 0.4674885E-01 0.9270359E-08 0.4674884E-01 0.0000000E+00 Chg. balance for solid moles: -.3568E-13 Mass of aqueous solution: 0.205459E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 7899.9990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 9.904 0.996 2597. 3.414 30.09 996.9 andradite 0.8759 -0.058 445.1 2.648 5.157 115.6 grossular 0.2121 -0.673 95.53 1.980 1.107 26.58 apatite-OH 0.1558E-01 -1.807 7.828 0.894 0.9070E-01 2.487 clinochlore 1.122 0.050 623.4 2.795 7.223 237.1 daphnite 0.3247 -0.489 231.7 2.365 2.684 70.20 chlorite-Mn 0.2739E-01 -1.562 19.42 1.288 0.2250 6.189 diopside 0.4204 -0.376 91.05 1.959 1.055 27.83 hedenbergite 0.1090 -0.962 27.05 1.432 0.3134 7.409 microcline 1.471 0.168 409.4 2.612 4.743 159.9 stilbite 5.082 0.706 3581. 3.554 41.49 1670. stilpnomelane-Fe 0.4130 -0.384 445.3 2.649 5.159 153.8 tr.625ac.25prg.125 0.6666E-01 -1.176 56.98 1.756 0.6602 18.34 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8051E+00 0.8051E+00 1.0000 -0.094 grossular 0.1949E+00 0.1949E+00 1.0000 -0.710 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.7611E+00 0.7611E+00 1.0000 -0.119 daphnite 0.2203E+00 0.2203E+00 1.0000 -0.657 chlorite-Mn 0.1859E-01 0.1859E-01 1.0000 -1.731 diopside 0.7941E+00 0.7941E+00 1.0000 -0.100 hedenbergite 0.2059E+00 0.2059E+00 1.0000 -0.686 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 tr.625ac.25prg.125 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 8630.607109 g Volume = 3492.666702 cm3 Porosity: -10.4925% V(tot) - V(min): -.33167E+03 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 7899.9990000 g log = 3.8976 Original solution: 1000.0103000 g Original solution / Rock added: 0.13 (Water/Rock Ratio), log = -0.8976 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.1245 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9086E+00 0.9846 0.1006E+01 0.1022E+01 CO2,gas 0.1467E-07 1.0060 0.1659E-07 0.1650E-07 CH4,gas 0.7789E-01 1.0116 0.8860E-01 0.8758E-01 H2,gas 0.1352E-01 1.0006 0.1521E-01 0.1520E-01 H2S,gas 0.5931E-06 0.9956 0.6640E-06 0.6670E-06 S2,gas 0.6366E-28 1.0000 0.7158E-28 0.7158E-28 CO,gas 0.5981E-13 1.0000 0.6725E-13 0.6725E-13 SO3,gas 0.3079E-47 1.0000 0.3462E-47 0.3462E-47 SO2,gas 0.1821E-26 1.0000 0.2048E-26 0.2048E-26 HCl,gas 0.1210E-16 1.0000 0.1361E-16 0.1361E-16 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 16 albite -0.38 -0.38 0.00 0.000 -0.13080E-10 22 andradite 39.01 39.01 0.00 0.000 0.24265E-10 23 grossular 32.73 32.73 0.00 0.000 -0.12132E-10 32 apatite-OH -18.15 -18.15 0.00 0.000 0.00000E+00 46 clinochlore 39.07 39.07 0.00 0.000 0.00000E+00 47 daphnite 28.97 28.97 0.00 0.000 -0.30331E-10 48 chlorite-Mn 46.87 46.87 0.00 0.000 -0.24265E-10 67 diopside 16.18 16.18 0.00 0.000 -0.60662E-11 68 hedenbergite 14.21 14.21 0.00 0.000 -0.30331E-11 116 microcline -2.49 -2.49 0.00 0.000 -0.10616E-10 163 stilbite -7.52 -7.52 0.00 0.000 0.15165E-10 164 stilpnomelane-Fe 13.02 13.02 0.00 0.000 0.21232E-10 245 tr.625ac.25prg.125 45.16 45.16 0.00 0.000 -0.24265E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -16.14 -9.48 -3.160 0.16185E+05 -7.780 3 CH4,gas 4.54 1.79 -2.75 -0.688 0.46982E+04 -1.053 4 H2,gas 8.00 4.48 -3.52 -2.010 0.60051E+04 -1.818 5 H2S,gas -6.23 -14.11 -7.88 -3.938 0.13449E+05 -6.178 6 S2,gas -7.34 -37.18 -29.84 -4.591 0.50958E+05 -28.145 7 CO,gas 3.21 -11.66 -14.87 -4.576 0.25392E+05 -13.172 8 SO3,gas 17.12 -32.04 -49.16 -12.290 0.83939E+05 -47.461 9 SO2,gas 0.83 -27.56 -28.39 -7.570 0.48471E+05 -26.689 10 HCl,gas 5.19 -13.38 -18.57 -9.283 0.31699E+05 -16.866 11 acmite 7.71 6.53 -1.18 -0.123 0.20175E+04 15 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 19 spessartine 24.46 19.73 -4.73 -0.236 0.80696E+04 20 analcite 3.32 2.77 -0.55 -0.061 0.93626E+03 26 annite 20.12 17.72 -2.40 -0.134 0.41064E+04 27 phlogopite 27.06 25.40 -1.67 -0.093 0.28489E+04 29 anorthite 12.71 8.26 -4.45 -0.342 0.75903E+04 35 aragonite 0.97 -3.04 -4.00 -1.335 0.68364E+04 36 brucite 12.57 9.29 -3.27 -0.655 0.55909E+04 37 calcite 0.81 -3.04 -3.85 -1.283 0.65722E+04 38 carnegieite-low 9.02 5.93 -3.09 -0.442 0.52801E+04 39 carnegieite-high 10.09 5.93 -4.16 -0.595 0.71071E+04 40 carpholite-Mg 8.58 4.46 -4.12 -0.275 0.70429E+04 41 carpholite-Fe 6.71 1.90 -4.81 -0.321 0.82207E+04 42 celadonite 5.34 3.65 -1.69 -0.099 0.28879E+04 43 celadonite-Fe 3.88 1.09 -2.79 -0.164 0.47561E+04 44 chrysotile 23.89 21.57 -2.32 -0.194 0.39692E+04 49 chlorite-Al-free 47.17 43.14 -4.04 -0.168 0.68936E+04 51 chloritoid-Fe 9.17 5.06 -4.12 -0.275 0.70316E+04 52 chloritoid-Mn 11.40 7.56 -3.84 -0.256 0.65545E+04 54 coesite -2.38 -3.16 -0.78 -0.260 0.13341E+04 61 cristobalite -2.56 -3.16 -0.60 -0.199 0.10195E+04 63 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71234E+04 65 diaspore 2.87 0.74 -2.13 -0.356 0.36450E+04 66 diamond -3.10 -7.17 -4.07 -1.163 0.69513E+04 71 enstatite 17.26 12.27 -4.99 -0.499 0.85226E+04 73 clinoenstatite 17.17 12.27 -4.89 -0.489 0.83542E+04 75 epidote 24.67 22.70 -1.97 -0.095 0.33586E+04 76 clinozoisite 22.81 18.95 -3.86 -0.175 0.65869E+04 77 epidote-Fe 29.84 26.46 -3.38 -0.176 0.57768E+04 78 fayalite 14.05 10.31 -3.73 -0.533 0.63743E+04 79 ferrosilite 11.15 7.16 -3.99 -0.399 0.68202E+04 83 gibbsite 4.08 0.74 -3.34 -0.477 0.57036E+04 84 glaucophane 22.97 20.80 -2.17 -0.059 0.37134E+04 85 glaucophane-Fe 17.28 13.12 -4.15 -0.112 0.70919E+04 86 graphite -3.55 -7.17 -3.63 -1.036 0.61935E+04 87 greenalite 16.14 13.89 -2.25 -0.187 0.38408E+04 90 hematite 12.57 8.99 -3.58 -0.434 0.61111E+04 91 heulandite -5.83 -7.52 -1.69 -0.077 0.28938E+04 95 jadeite 4.22 2.77 -1.44 -0.144 0.24617E+04 97 kalsilite 7.58 3.83 -3.76 -0.537 0.64126E+04 98 kaolinite -1.33 -4.84 -3.50 -0.319 0.59832E+04 101 laumontite 2.88 1.95 -0.93 -0.062 0.15935E+04 102 lawsonite 9.62 8.26 -1.35 -0.090 0.23070E+04 103 leucite 4.12 0.67 -3.45 -0.345 0.58873E+04 105 lizardite 23.24 21.57 -1.68 -0.140 0.28619E+04 107 magnetite 20.09 15.72 -4.37 -0.356 0.74536E+04 108 minnesotaite 10.39 7.58 -2.81 -0.165 0.48027E+04 112 manganosite 14.06 9.24 -4.82 -1.204 0.82236E+04 120 muscovite 2.58 -1.01 -3.59 -0.211 0.61315E+04 121 paragonite 4.24 1.09 -3.15 -0.185 0.53706E+04 122 nepheline 8.34 5.93 -2.41 -0.344 0.41125E+04 128 periclase-Fe 11.63 6.73 -4.89 -1.223 0.83523E+04 134 phlogopite-Na 29.65 27.50 -2.15 -0.119 0.36678E+04 136 prehnite 19.37 18.21 -1.16 -0.068 0.19849E+04 137 prehnite-Fe 22.50 21.96 -0.53 -0.032 0.91159E+03 138 pumpellyite-Fe 46.27 43.89 -2.38 -0.053 0.40582E+04 139 pumpellyite-Mg 48.99 46.45 -2.54 -0.057 0.43421E+04 142 pyrite -21.25 -25.96 -4.71 -1.109 0.80506E+04 143 pyrrhotite -4.26 -7.37 -3.11 -1.037 0.53132E+04 144 pyrrhotiteFe0.875 -6.02 -8.77 -2.75 -1.012 0.47004E+04 145 pyroxmangite 7.40 6.08 -1.31 -0.263 0.22440E+04 146 pyrophyllite -6.18 -11.15 -4.98 -0.311 0.84962E+04 147 quartz -2.99 -3.16 -0.17 -0.056 0.28680E+03 152 rhodonite 7.45 6.08 -1.36 -0.272 0.23243E+04 153 sanidine -1.28 -2.49 -1.21 -0.093 0.20677E+04 165 stilpnomelane-Mg 27.44 25.81 -1.63 -0.049 0.27804E+04 171 talc 16.49 15.25 -1.24 -0.073 0.21140E+04 174 tephroite 18.09 15.33 -2.76 -0.394 0.47117E+04 178 tridymite -2.63 -3.16 -0.53 -0.177 0.90677E+03 179 tremolite 47.87 47.42 -0.45 -0.012 0.77494E+03 180 ferroactinolite 38.45 34.62 -3.83 -0.104 0.65448E+04 181 troilite-low -4.41 -7.37 -2.96 -0.987 0.50560E+04 183 vesuvianite 223.47 218.82 -4.65 -0.036 0.79441E+04 187 wairakite 3.95 1.95 -2.00 -0.118 0.34155E+04 188 walstromite 11.51 9.94 -1.56 -0.313 0.26719E+04 189 wollastonite 10.46 9.94 -0.52 -0.103 0.88229E+03 190 pseudo-wollastonite 11.00 9.94 -1.06 -0.211 0.18021E+04 191 zoisite 22.85 18.95 -3.90 -0.177 0.66610E+04 192 akaganeite 7.75 4.49 -3.26 -0.705 0.55681E+04 199 chalcedony -2.80 -3.16 -0.35 -0.118 0.60609E+03 201 montmorillonite-Ca -2.29 -6.17 -3.88 -0.240 0.66180E+04 202 montmorillonite-K -2.24 -6.27 -4.03 -0.247 0.68816E+04 203 montmorillonite-Mg -2.48 -6.79 -4.32 -0.267 0.73678E+04 204 montmorillonite-Na -2.04 -5.57 -3.54 -0.216 0.60365E+04 205 nontronite-Ca 3.21 -0.19 -3.41 -0.221 0.58215E+04 206 nontronite-H 2.53 -2.36 -4.89 -0.328 0.83485E+04 207 nontronite-K 3.34 -0.30 -3.64 -0.233 0.62083E+04 208 nontronite-Mg 3.07 -0.82 -3.90 -0.253 0.66553E+04 209 nontronite-Na 3.52 0.40 -3.12 -0.200 0.53291E+04 224 tobermorite 9.82 7.76 -2.07 -0.564 0.35287E+04 230 alabandite -0.98 -4.87 -3.89 -1.296 0.66374E+04 233 boehmite 4.41 0.74 -3.67 -0.611 0.62619E+04 235 ferrous-oxide 9.81 6.73 -3.08 -0.769 0.52532E+04 240 silica-amorphous -2.09 -3.16 -1.07 -0.355 0.18203E+04 242 an20ab80 2.02 1.35 -0.67 -0.052 0.11472E+04 243 an25ab75 2.65 1.78 -0.87 -0.067 0.14810E+04 244 an30ab70 3.28 2.21 -1.07 -0.082 0.18244E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 100.0000000 g Current total amount of reactant added: 7899.9990000 g New total amount of reactant added: 7999.9990000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.5219E-10 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 13 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 7999.9990000 Water: Moles liquid = 0.1083E+02 kg liquid = 0.1951E+00 Moles total = -.4478E+02 kg total = -.8066E+00 Activity = 1.0000 Stoichiometric ionic strength = .1178993E-01 Osmotic coef. = 0.9676 True ionic strength = .2037732E-01 Chg. balance for total moles = 0.5219E-10 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.89861E-10 -10.0464 0.75422E-10 -10.1225 0.83932E+00 -0.0761 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.70407E-03 -3.1524 0.58734E-03 -3.2311 0.83420E+00 -0.0787 4 SO4-- 0.32776E-11 -11.4844 0.16942E-11 -11.7710 0.51690E+00 -0.2866 5 HCO3- 0.12114E-05 -5.9167 0.10121E-05 -5.9948 0.83544E+00 -0.0781 6 HS- 0.13073E-03 -3.8836 0.10907E-03 -3.9623 0.83432E+00 -0.0787 7 Al+++ 0.10290E-28 -28.9876 0.23521E-29 -29.6285 0.22858E+00 -0.6410 8 H4SiO4 0.69598E-03 -3.1574 0.69598E-03 -3.1574 0.10000E+01 0.0000 9 Ca++ 0.14017E-06 -6.8533 0.71915E-07 -7.1432 0.51305E+00 -0.2898 10 Mg++ 0.21930E-10 -10.6590 0.11199E-10 -10.9508 0.51067E+00 -0.2919 11 Fe++ 0.60443E-13 -13.2187 0.30901E-13 -13.5100 0.51124E+00 -0.2914 12 K+ 0.15930E-03 -3.7978 0.13312E-03 -3.8758 0.83564E+00 -0.0780 13 Na+ 0.20215E-01 -1.6943 0.16860E-01 -1.7731 0.83405E+00 -0.0788 14 Mn++ 0.19403E-10 -10.7121 0.99278E-11 -11.0031 0.51167E+00 -0.2910 15 HPO4-- 0.44055E-07 -7.3560 0.22775E-07 -7.6425 0.51697E+00 -0.2865 16 HSiO3- 0.10329E-01 -1.9859 0.86165E-02 -2.0647 0.83420E+00 -0.0787 17 Ca(HSiO3)+ 0.16884E-07 -7.7725 0.14112E-07 -7.8504 0.83582E+00 -0.0779 18 Mg(HSiO3)+ 0.32722E-11 -11.4852 0.27349E-11 -11.5631 0.83582E+00 -0.0779 19 NaHSiO3,aq 0.23497E-02 -2.6290 0.23497E-02 -2.6290 0.10000E+01 0.0000 20 AlO+ 0.67301E-16 -16.1720 0.56252E-16 -16.2499 0.83582E+00 -0.0779 22 HAlO2,aq 0.14853E-09 -9.8282 0.14853E-09 -9.8282 0.10000E+01 0.0000 23 AlO2- 0.52352E-05 -5.2811 0.43592E-05 -5.3606 0.83267E+00 -0.0795 24 CH4,aq 0.63521E-04 -4.1971 0.63293E-04 -4.1986 0.99641E+00 -0.0016 25 C2H6,aq 0.59342E-13 -13.2266 0.59129E-13 -13.2282 0.99641E+00 -0.0016 29 CO,aq 0.47457E-16 -16.3237 0.47457E-16 -16.3237 0.10000E+01 0.0000 30 CO2,aq 0.16369E-09 -9.7860 0.16311E-09 -9.7875 0.99641E+00 -0.0016 31 CO3-2 0.22724E-05 -5.6435 0.11721E-05 -5.9310 0.51578E+00 -0.2875 32 CaCO3,aq 0.10569E-08 -8.9760 0.10569E-08 -8.9760 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.22228E-11 -11.6531 0.18579E-11 -11.7310 0.83582E+00 -0.0779 34 CaCl+ 0.81782E-10 -10.0873 0.68355E-10 -10.1652 0.83582E+00 -0.0779 35 CaCl2,aq 0.95382E-14 -14.0205 0.95382E-14 -14.0205 0.10000E+01 0.0000 36 CaOH+ 0.81304E-07 -7.0899 0.67956E-07 -7.1678 0.83582E+00 -0.0779 37 CaSO4,aq 0.38689E-16 -16.4124 0.38689E-16 -16.4124 0.10000E+01 0.0000 38 HCl,aq 0.81174E-14 -14.0906 0.81174E-14 -14.0906 0.10000E+01 0.0000 43 FeCl+ 0.34370E-16 -16.4638 0.28727E-16 -16.5417 0.83582E+00 -0.0779 46 FeO,aq 0.21112E-09 -9.6755 0.21112E-09 -9.6755 0.10000E+01 0.0000 47 FeOH+ 0.15956E-10 -10.7971 0.13336E-10 -10.8750 0.83582E+00 -0.0779 48 HFeO2- 0.35110E-07 -7.4546 0.29289E-07 -7.5333 0.83420E+00 -0.0787 49 FeO+ 0.11183E-16 -16.9514 0.93468E-17 -17.0293 0.83582E+00 -0.0779 51 FeO2- 0.40304E-09 -9.3947 0.33622E-09 -9.4734 0.83420E+00 -0.0787 52 HFeO2,aq 0.32252E-11 -11.4914 0.32252E-11 -11.4914 0.10000E+01 0.0000 53 H2,aq 0.11624E-04 -4.9346 0.11582E-04 -4.9362 0.99641E+00 -0.0016 54 KCl,aq 0.14171E-08 -8.8486 0.14171E-08 -8.8486 0.10000E+01 0.0000 56 KOH,aq 0.75375E-06 -6.1228 0.75375E-06 -6.1228 0.10000E+01 0.0000 57 KSO4- 0.41952E-14 -14.3773 0.34996E-14 -14.4560 0.83420E+00 -0.0787 58 MgCO3,aq 0.41256E-13 -13.3845 0.41256E-13 -13.3845 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.35371E-15 -15.4514 0.29564E-15 -15.5292 0.83582E+00 -0.0779 60 MgCl+ 0.11543E-13 -13.9377 0.96478E-14 -14.0156 0.83582E+00 -0.0779 61 MgOH+ 0.70061E-10 -10.1545 0.58559E-10 -10.2324 0.83582E+00 -0.0779 63 MnO,aq 0.18074E-08 -8.7429 0.18074E-08 -8.7429 0.10000E+01 0.0000 64 MnOH+ 0.47622E-09 -9.3222 0.39803E-09 -9.4001 0.83582E+00 -0.0779 65 MnO2-2 0.20444E-10 -10.6894 0.10545E-10 -10.9770 0.51578E+00 -0.2875 66 HMnO2- 0.20886E-09 -9.6801 0.17423E-09 -9.7589 0.83420E+00 -0.0787 69 MnCl+ 0.42960E-13 -13.3669 0.35907E-13 -13.4448 0.83582E+00 -0.0779 71 NaCl,aq 0.32818E-05 -5.4839 0.32818E-05 -5.4839 0.10000E+01 0.0000 72 NaOH,aq 0.96047E-04 -4.0175 0.96047E-04 -4.0175 0.10000E+01 0.0000 74 OH- 0.91999E-02 -2.0362 0.76605E-02 -2.1157 0.83267E+00 -0.0795 79 HPO3-2 0.15938E-14 -14.7976 0.82207E-15 -15.0851 0.51578E+00 -0.2875 81 H2PO3- 0.14904E-18 -18.8267 0.12433E-18 -18.9054 0.83420E+00 -0.0787 82 H3PO4,aq 0.90612E-18 -18.0428 0.90612E-18 -18.0428 0.10000E+01 0.0000 83 H2PO4- 0.37950E-10 -10.4208 0.31688E-10 -10.4991 0.83500E+00 -0.0783 84 PO4-3 0.10255E-08 -8.9891 0.24638E-09 -9.6084 0.24024E+00 -0.6193 88 HP2O7-3 0.91098E-18 -18.0405 0.20845E-18 -18.6810 0.22882E+00 -0.6405 89 P2O7-4 0.87228E-17 -17.0593 0.66025E-18 -18.1803 0.75692E-01 -1.1209 90 H2S,aq 0.25516E-07 -7.5932 0.25424E-07 -7.5947 0.99641E+00 -0.0016 91 S2-2 0.44125E-13 -13.3553 0.22759E-13 -13.6429 0.51578E+00 -0.2875 97 SO3-2 0.48723E-17 -17.3123 0.25499E-17 -17.5935 0.52335E+00 -0.2812 98 HSO3- 0.14435E-19 -19.8406 0.12042E-19 -19.9193 0.83420E+00 -0.0787 99 HSO4- 0.14718E-18 -18.8321 0.12314E-18 -18.9096 0.83665E+00 -0.0775 Charge balance for all species = 0.2675E-09 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.8986104E-10 -.2200170E-01 -.2213746E+02 0.0000 2 H2O 0.1000000E+01 0.5550495E+02 0.9981831E+06 0.0000 3 Cl- 0.7040729E-03 0.7073562E-03 0.2503388E+02 6.8914 4 SO4-- 0.3277569E-11 -.6642721E-04 -.6369902E+01 8.4740 5 HCO3- 0.1211440E-05 0.6700635E-04 0.4081363E+01 4.1277 6 HS- 0.1307290E-03 0.1971817E-03 0.6509746E+01 6.1602 7 Al+++ 0.1028988E-28 0.5235393E-05 0.1410108E+00 0.7390 8 H4SiO4 0.6959841E-03 0.1337466E-01 0.1283254E+04 -3.1574 9 Ca++ 0.1401725E-06 0.2395015E-06 0.9581891E-02 13.1018 10 Mg++ 0.2193037E-10 0.9531282E-10 0.2313177E-05 9.2942 11 Fe++ 0.6044346E-13 0.3574350E-07 0.1992663E-02 6.7350 12 K+ 0.1593022E-03 0.1600573E-03 0.6247575E+01 6.2467 13 Na+ 0.2021518E-01 0.2266416E-01 0.5201298E+03 8.3494 14 Mn++ 0.1940298E-10 0.2532361E-08 0.1388786E-03 9.2419 15 HPO4-- 0.4405547E-07 0.4511895E-07 0.4322870E-02 12.6025 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.1324681E+03 -.4291567E-02 -.1324638E+03 0.0000000E+00 2 H2O -.4477502E+02 0.1082658E+02 -.5560160E+02 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.2217327E+00 -.1295704E-04 0.2217457E+00 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.2217072E+00 0.3846151E-04 -.2217457E+00 0.0000000E+00 7 Al+++ 0.2608593E+02 0.1021196E-05 0.2608593E+02 0.0000000E+00 8 H4SiO4 0.8330225E+02 0.2608809E-02 0.8329964E+02 0.0000000E+00 9 Ca++ 0.9201155E+01 0.4671624E-07 0.9201155E+01 0.0000000E+00 10 Mg++ 0.6349206E+01 0.1859135E-10 0.6349206E+01 0.0000000E+00 11 Fe++ 0.5704068E+01 0.6971990E-08 0.5704068E+01 0.0000000E+00 12 K+ 0.1698514E+01 0.3122016E-04 0.1698482E+01 0.0000000E+00 13 Na+ 0.1004211E+02 0.4420784E-02 0.1003769E+02 0.0000000E+00 14 Mn++ 0.1387088E+00 0.4939526E-09 0.1387088E+00 0.0000000E+00 15 HPO4-- 0.4734061E-01 0.8800728E-08 0.4734060E-01 0.0000000E+00 Chg. balance for solid moles: 0.2165E-14 Mass of aqueous solution: 0.195399E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 7999.9990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 10.03 1.001 2630. 3.420 30.09 1010. andradite 0.8870 -0.052 450.7 2.654 5.157 117.1 grossular 0.2148 -0.668 96.74 1.986 1.107 26.92 apatite-OH 0.1578E-01 -1.802 7.927 0.899 0.9070E-01 2.519 clinochlore 1.136 0.055 631.3 2.800 7.223 240.1 daphnite 0.3288 -0.483 234.6 2.370 2.684 71.09 chlorite-Mn 0.2774E-01 -1.557 19.67 1.294 0.2250 6.268 diopside 0.4259 -0.371 92.22 1.965 1.055 28.19 hedenbergite 0.1104 -0.957 27.40 1.438 0.3135 7.505 microcline 1.489 0.173 414.5 2.618 4.743 161.9 stilbite 5.146 0.711 3626. 3.559 41.49 1691. stilpnomelane-Fe 0.4183 -0.379 450.9 2.654 5.159 155.7 tr.625ac.25prg.125 0.6750E-01 -1.171 57.69 1.761 0.6601 18.57 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8051E+00 0.8051E+00 1.0000 -0.094 grossular 0.1949E+00 0.1949E+00 1.0000 -0.710 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.7611E+00 0.7611E+00 1.0000 -0.119 daphnite 0.2203E+00 0.2203E+00 1.0000 -0.657 chlorite-Mn 0.1859E-01 0.1859E-01 1.0000 -1.731 diopside 0.7941E+00 0.7941E+00 1.0000 -0.100 hedenbergite 0.2059E+00 0.2059E+00 1.0000 -0.686 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 tr.625ac.25prg.125 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 8739.857771 g Volume = 3536.869765 cm3 Porosity: -10.4927% V(tot) - V(min): -.33587E+03 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 7999.9990000 g log = 3.9031 Original solution: 1000.0103000 g Original solution / Rock added: 0.13 (Water/Rock Ratio), log = -0.9031 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.1290 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9050E+00 0.9846 0.1006E+01 0.1022E+01 CO2,gas 0.1536E-07 1.0059 0.1745E-07 0.1735E-07 CH4,gas 0.8157E-01 1.0115 0.9316E-01 0.9210E-01 H2,gas 0.1346E-01 1.0006 0.1521E-01 0.1520E-01 H2S,gas 0.6217E-06 0.9956 0.6989E-06 0.7020E-06 S2,gas 0.7023E-28 1.0000 0.7929E-28 0.7929E-28 CO,gas 0.6264E-13 1.0000 0.7072E-13 0.7072E-13 SO3,gas 0.3227E-47 1.0000 0.3644E-47 0.3644E-47 SO2,gas 0.1909E-26 1.0000 0.2156E-26 0.2156E-26 HCl,gas 0.1269E-16 1.0000 0.1432E-16 0.1432E-16 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 16 albite -0.38 -0.38 0.00 0.000 -0.94784E-12 22 andradite 39.01 39.01 0.00 0.000 -0.12132E-10 23 grossular 32.73 32.73 0.00 0.000 0.12132E-10 32 apatite-OH -18.15 -18.15 0.00 0.000 -0.60662E-11 46 clinochlore 39.07 39.07 0.00 0.000 -0.24265E-10 47 daphnite 28.97 28.97 0.00 0.000 0.12132E-10 48 chlorite-Mn 46.87 46.87 0.00 0.000 -0.24265E-10 67 diopside 16.18 16.18 0.00 0.000 0.00000E+00 68 hedenbergite 14.21 14.21 0.00 0.000 0.30331E-11 116 microcline -2.49 -2.49 0.00 0.000 0.15165E-11 163 stilbite -7.52 -7.52 0.00 0.000 -0.33364E-10 164 stilpnomelane-Fe 13.02 13.02 0.00 0.000 0.21232E-10 245 tr.625ac.25prg.125 45.16 45.16 0.00 0.000 0.60662E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -16.12 -9.46 -3.152 0.16148E+05 -7.758 3 CH4,gas 4.54 1.81 -2.73 -0.682 0.46609E+04 -1.031 4 H2,gas 8.00 4.48 -3.52 -2.010 0.60051E+04 -1.818 5 H2S,gas -6.23 -14.08 -7.85 -3.927 0.13411E+05 -6.156 6 S2,gas -7.34 -37.14 -29.80 -4.585 0.50882E+05 -28.101 7 CO,gas 3.21 -11.63 -14.85 -4.569 0.25355E+05 -13.150 8 SO3,gas 17.12 -32.02 -49.14 -12.284 0.83901E+05 -47.438 9 SO2,gas 0.83 -27.53 -28.37 -7.564 0.48433E+05 -26.666 10 HCl,gas 5.19 -13.35 -18.54 -9.271 0.31662E+05 -16.844 11 acmite 7.71 6.53 -1.18 -0.123 0.20175E+04 15 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 19 spessartine 24.46 19.73 -4.73 -0.236 0.80696E+04 20 analcite 3.32 2.77 -0.55 -0.061 0.93626E+03 26 annite 20.12 17.72 -2.40 -0.134 0.41064E+04 27 phlogopite 27.06 25.40 -1.67 -0.093 0.28490E+04 29 anorthite 12.71 8.26 -4.45 -0.342 0.75903E+04 35 aragonite 0.97 -3.02 -3.98 -1.327 0.67991E+04 36 brucite 12.57 9.29 -3.27 -0.655 0.55909E+04 37 calcite 0.81 -3.02 -3.83 -1.276 0.65349E+04 38 carnegieite-low 9.02 5.93 -3.09 -0.442 0.52801E+04 39 carnegieite-high 10.09 5.93 -4.16 -0.595 0.71071E+04 40 carpholite-Mg 8.58 4.46 -4.12 -0.275 0.70429E+04 41 carpholite-Fe 6.71 1.90 -4.81 -0.321 0.82207E+04 42 celadonite 5.34 3.65 -1.69 -0.099 0.28879E+04 43 celadonite-Fe 3.88 1.09 -2.79 -0.164 0.47561E+04 44 chrysotile 23.89 21.57 -2.32 -0.194 0.39692E+04 49 chlorite-Al-free 47.17 43.14 -4.04 -0.168 0.68936E+04 51 chloritoid-Fe 9.17 5.06 -4.12 -0.275 0.70316E+04 52 chloritoid-Mn 11.40 7.56 -3.84 -0.256 0.65545E+04 54 coesite -2.38 -3.16 -0.78 -0.260 0.13341E+04 61 cristobalite -2.56 -3.16 -0.60 -0.199 0.10195E+04 63 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71234E+04 65 diaspore 2.87 0.74 -2.13 -0.356 0.36450E+04 66 diamond -3.10 -7.15 -4.05 -1.157 0.69140E+04 71 enstatite 17.26 12.27 -4.99 -0.499 0.85226E+04 73 clinoenstatite 17.17 12.27 -4.89 -0.489 0.83542E+04 75 epidote 24.67 22.70 -1.97 -0.095 0.33586E+04 76 clinozoisite 22.81 18.95 -3.86 -0.175 0.65869E+04 77 epidote-Fe 29.84 26.46 -3.38 -0.176 0.57768E+04 78 fayalite 14.05 10.31 -3.73 -0.533 0.63743E+04 79 ferrosilite 11.15 7.16 -3.99 -0.399 0.68202E+04 83 gibbsite 4.08 0.74 -3.34 -0.477 0.57036E+04 84 glaucophane 22.97 20.80 -2.17 -0.059 0.37134E+04 85 glaucophane-Fe 17.28 13.12 -4.15 -0.112 0.70919E+04 86 graphite -3.55 -7.15 -3.61 -1.030 0.61563E+04 87 greenalite 16.14 13.89 -2.25 -0.187 0.38408E+04 90 hematite 12.57 8.99 -3.58 -0.434 0.61111E+04 91 heulandite -5.83 -7.52 -1.69 -0.077 0.28938E+04 95 jadeite 4.22 2.77 -1.44 -0.144 0.24617E+04 97 kalsilite 7.58 3.83 -3.76 -0.537 0.64126E+04 98 kaolinite -1.33 -4.84 -3.50 -0.319 0.59832E+04 101 laumontite 2.88 1.95 -0.93 -0.062 0.15935E+04 102 lawsonite 9.62 8.26 -1.35 -0.090 0.23070E+04 103 leucite 4.12 0.67 -3.45 -0.345 0.58873E+04 105 lizardite 23.24 21.57 -1.68 -0.140 0.28619E+04 107 magnetite 20.09 15.72 -4.37 -0.356 0.74536E+04 108 minnesotaite 10.39 7.58 -2.81 -0.165 0.48027E+04 112 manganosite 14.06 9.24 -4.82 -1.204 0.82236E+04 120 muscovite 2.58 -1.01 -3.59 -0.211 0.61315E+04 121 paragonite 4.24 1.09 -3.15 -0.185 0.53706E+04 122 nepheline 8.34 5.93 -2.41 -0.344 0.41125E+04 128 periclase-Fe 11.63 6.73 -4.89 -1.223 0.83523E+04 134 phlogopite-Na 29.65 27.50 -2.15 -0.119 0.36678E+04 136 prehnite 19.37 18.21 -1.16 -0.068 0.19849E+04 137 prehnite-Fe 22.50 21.96 -0.53 -0.032 0.91159E+03 138 pumpellyite-Fe 46.27 43.89 -2.38 -0.053 0.40582E+04 139 pumpellyite-Mg 48.99 46.45 -2.54 -0.057 0.43421E+04 142 pyrite -21.25 -25.92 -4.67 -1.099 0.79747E+04 143 pyrrhotite -4.26 -7.35 -3.09 -1.030 0.52752E+04 144 pyrrhotiteFe0.875 -6.02 -8.75 -2.73 -1.004 0.46624E+04 145 pyroxmangite 7.40 6.08 -1.31 -0.263 0.22440E+04 146 pyrophyllite -6.18 -11.15 -4.98 -0.311 0.84962E+04 147 quartz -2.99 -3.16 -0.17 -0.056 0.28679E+03 152 rhodonite 7.45 6.08 -1.36 -0.272 0.23242E+04 153 sanidine -1.28 -2.49 -1.21 -0.093 0.20677E+04 165 stilpnomelane-Mg 27.44 25.81 -1.63 -0.049 0.27804E+04 171 talc 16.49 15.25 -1.24 -0.073 0.21140E+04 174 tephroite 18.09 15.33 -2.76 -0.394 0.47117E+04 178 tridymite -2.63 -3.16 -0.53 -0.177 0.90677E+03 179 tremolite 47.87 47.42 -0.45 -0.012 0.77494E+03 180 ferroactinolite 38.45 34.62 -3.83 -0.104 0.65448E+04 181 troilite-low -4.41 -7.35 -2.94 -0.980 0.50180E+04 183 vesuvianite 223.47 218.82 -4.65 -0.036 0.79441E+04 187 wairakite 3.95 1.95 -2.00 -0.118 0.34155E+04 188 walstromite 11.51 9.94 -1.56 -0.313 0.26719E+04 189 wollastonite 10.46 9.94 -0.52 -0.103 0.88229E+03 190 pseudo-wollastonite 11.00 9.94 -1.06 -0.211 0.18021E+04 191 zoisite 22.85 18.95 -3.90 -0.177 0.66610E+04 192 akaganeite 7.75 4.49 -3.26 -0.705 0.55681E+04 199 chalcedony -2.80 -3.16 -0.35 -0.118 0.60609E+03 201 montmorillonite-Ca -2.29 -6.17 -3.88 -0.240 0.66180E+04 202 montmorillonite-K -2.24 -6.27 -4.03 -0.247 0.68816E+04 203 montmorillonite-Mg -2.48 -6.79 -4.32 -0.267 0.73678E+04 204 montmorillonite-Na -2.04 -5.57 -3.54 -0.216 0.60365E+04 205 nontronite-Ca 3.21 -0.19 -3.41 -0.221 0.58215E+04 206 nontronite-H 2.53 -2.36 -4.89 -0.328 0.83485E+04 207 nontronite-K 3.34 -0.30 -3.64 -0.233 0.62083E+04 208 nontronite-Mg 3.07 -0.82 -3.90 -0.253 0.66553E+04 209 nontronite-Na 3.52 0.40 -3.12 -0.200 0.53291E+04 224 tobermorite 9.82 7.76 -2.07 -0.564 0.35287E+04 230 alabandite -0.98 -4.84 -3.87 -1.288 0.65995E+04 233 boehmite 4.41 0.74 -3.67 -0.611 0.62619E+04 235 ferrous-oxide 9.81 6.73 -3.08 -0.769 0.52532E+04 240 silica-amorphous -2.09 -3.16 -1.07 -0.355 0.18203E+04 242 an20ab80 2.02 1.35 -0.67 -0.052 0.11472E+04 243 an25ab75 2.65 1.78 -0.87 -0.067 0.14810E+04 244 an30ab70 3.28 2.21 -1.07 -0.082 0.18244E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 100.0000000 g Current total amount of reactant added: 7999.9990000 g New total amount of reactant added: 8099.9990000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.5216E-10 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 13 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 8099.9990000 Water: Moles liquid = 0.1027E+02 kg liquid = 0.1850E+00 Moles total = -.4603E+02 kg total = -.8292E+00 Activity = 1.0000 Stoichiometric ionic strength = .1182187E-01 Osmotic coef. = 0.9676 True ionic strength = .2040240E-01 Chg. balance for total moles = 0.5216E-10 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.89971E-10 -10.0459 0.75508E-10 -10.1220 0.83925E+00 -0.0761 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.74229E-03 -3.1294 0.61916E-03 -3.2082 0.83413E+00 -0.0788 4 SO4-- 0.34524E-11 -11.4619 0.17839E-11 -11.7486 0.51673E+00 -0.2867 5 HCO3- 0.12759E-05 -5.8942 0.10659E-05 -5.9723 0.83537E+00 -0.0781 6 HS- 0.13782E-03 -3.8607 0.11498E-03 -3.9394 0.83425E+00 -0.0787 7 Al+++ 0.10333E-28 -28.9858 0.23602E-29 -29.6271 0.22841E+00 -0.6413 8 H4SiO4 0.69598E-03 -3.1574 0.69598E-03 -3.1574 0.10000E+01 0.0000 9 Ca++ 0.14054E-06 -6.8522 0.72080E-07 -7.1422 0.51288E+00 -0.2900 10 Mg++ 0.21988E-10 -10.6578 0.11225E-10 -10.9498 0.51050E+00 -0.2920 11 Fe++ 0.60602E-13 -13.2175 0.30971E-13 -13.5090 0.51106E+00 -0.2915 12 K+ 0.15950E-03 -3.7972 0.13327E-03 -3.8753 0.83557E+00 -0.0780 13 Na+ 0.20240E-01 -1.6938 0.16880E-01 -1.7726 0.83398E+00 -0.0788 14 Mn++ 0.19454E-10 -10.7110 0.99507E-11 -11.0021 0.51149E+00 -0.2912 15 HPO4-- 0.43969E-07 -7.3569 0.22723E-07 -7.6435 0.51680E+00 -0.2867 16 HSiO3- 0.10318E-01 -1.9864 0.86066E-02 -2.0652 0.83413E+00 -0.0788 17 Ca(HSiO3)+ 0.16905E-07 -7.7720 0.14128E-07 -7.8499 0.83575E+00 -0.0779 18 Mg(HSiO3)+ 0.32762E-11 -11.4846 0.27381E-11 -11.5626 0.83575E+00 -0.0779 19 NaHSiO3,aq 0.23497E-02 -2.6290 0.23497E-02 -2.6290 0.10000E+01 0.0000 20 AlO+ 0.67383E-16 -16.1714 0.56316E-16 -16.2494 0.83575E+00 -0.0779 22 HAlO2,aq 0.14853E-09 -9.8282 0.14853E-09 -9.8282 0.10000E+01 0.0000 23 AlO2- 0.52297E-05 -5.2815 0.43543E-05 -5.3611 0.83260E+00 -0.0796 24 CH4,aq 0.66975E-04 -4.1741 0.66734E-04 -4.1757 0.99640E+00 -0.0016 25 C2H6,aq 0.65970E-13 -13.1807 0.65732E-13 -13.1822 0.99640E+00 -0.0016 29 CO,aq 0.50037E-16 -16.3007 0.50037E-16 -16.3007 0.10000E+01 0.0000 30 CO2,aq 0.17259E-09 -9.7630 0.17197E-09 -9.7645 0.99640E+00 -0.0016 31 CO3-2 0.23913E-05 -5.6214 0.12330E-05 -5.9090 0.51562E+00 -0.2877 32 CaCO3,aq 0.11144E-08 -8.9530 0.11144E-08 -8.9530 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.23465E-11 -11.6296 0.19611E-11 -11.7075 0.83575E+00 -0.0779 34 CaCl+ 0.86418E-10 -10.0634 0.72224E-10 -10.1413 0.83575E+00 -0.0779 35 CaCl2,aq 0.10624E-13 -13.9737 0.10624E-13 -13.9737 0.10000E+01 0.0000 36 CaOH+ 0.81404E-07 -7.0894 0.68033E-07 -7.1673 0.83575E+00 -0.0779 37 CaSO4,aq 0.40832E-16 -16.3890 0.40832E-16 -16.3890 0.10000E+01 0.0000 38 HCl,aq 0.85671E-14 -14.0672 0.85671E-14 -14.0672 0.10000E+01 0.0000 43 FeCl+ 0.36318E-16 -16.4399 0.30353E-16 -16.5178 0.83575E+00 -0.0779 46 FeO,aq 0.21112E-09 -9.6755 0.21112E-09 -9.6755 0.10000E+01 0.0000 47 FeOH+ 0.15976E-10 -10.7965 0.13352E-10 -10.8745 0.83575E+00 -0.0779 48 HFeO2- 0.35073E-07 -7.4550 0.29255E-07 -7.5338 0.83413E+00 -0.0788 49 FeO+ 0.11197E-16 -16.9509 0.93575E-17 -17.0288 0.83575E+00 -0.0779 51 FeO2- 0.40261E-09 -9.3951 0.33583E-09 -9.4739 0.83413E+00 -0.0788 52 HFeO2,aq 0.32252E-11 -11.4914 0.32252E-11 -11.4914 0.10000E+01 0.0000 53 H2,aq 0.11624E-04 -4.9346 0.11582E-04 -4.9362 0.99640E+00 -0.0016 54 KCl,aq 0.14955E-08 -8.8252 0.14955E-08 -8.8252 0.10000E+01 0.0000 56 KOH,aq 0.75375E-06 -6.1228 0.75375E-06 -6.1228 0.10000E+01 0.0000 57 KSO4- 0.44229E-14 -14.3543 0.36893E-14 -14.4331 0.83413E+00 -0.0788 58 MgCO3,aq 0.43499E-13 -13.3615 0.43499E-13 -13.3615 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.37339E-15 -15.4278 0.31206E-15 -15.5058 0.83575E+00 -0.0779 60 MgCl+ 0.12197E-13 -13.9137 0.10194E-13 -13.9917 0.83575E+00 -0.0779 61 MgOH+ 0.70147E-10 -10.1540 0.58625E-10 -10.2319 0.83575E+00 -0.0779 63 MnO,aq 0.18074E-08 -8.7429 0.18074E-08 -8.7429 0.10000E+01 0.0000 64 MnOH+ 0.47681E-09 -9.3217 0.39849E-09 -9.3996 0.83575E+00 -0.0779 65 MnO2-2 0.20404E-10 -10.6903 0.10521E-10 -10.9780 0.51562E+00 -0.2877 66 HMnO2- 0.20865E-09 -9.6806 0.17404E-09 -9.7594 0.83413E+00 -0.0788 69 MnCl+ 0.45396E-13 -13.3430 0.37940E-13 -13.4209 0.83575E+00 -0.0779 71 NaCl,aq 0.34636E-05 -5.4605 0.34636E-05 -5.4605 0.10000E+01 0.0000 72 NaOH,aq 0.96047E-04 -4.0175 0.96047E-04 -4.0175 0.10000E+01 0.0000 74 OH- 0.91902E-02 -2.0367 0.76518E-02 -2.1162 0.83260E+00 -0.0796 79 HPO3-2 0.15907E-14 -14.7984 0.82019E-15 -15.0861 0.51562E+00 -0.2877 81 H2PO3- 0.14889E-18 -18.8271 0.12419E-18 -18.9059 0.83413E+00 -0.0788 82 H3PO4,aq 0.90612E-18 -18.0428 0.90612E-18 -18.0428 0.10000E+01 0.0000 83 H2PO4- 0.37910E-10 -10.4213 0.31652E-10 -10.4996 0.83493E+00 -0.0783 84 PO4-3 0.10227E-08 -8.9902 0.24554E-09 -9.6099 0.24008E+00 -0.6196 88 HP2O7-3 0.90853E-18 -18.0417 0.20773E-18 -18.6825 0.22865E+00 -0.6408 89 P2O7-4 0.86942E-17 -17.0608 0.65724E-18 -18.1823 0.75595E-01 -1.1215 90 H2S,aq 0.26930E-07 -7.5698 0.26833E-07 -7.5713 0.99640E+00 -0.0016 91 S2-2 0.49053E-13 -13.3093 0.25292E-13 -13.5970 0.51562E+00 -0.2877 97 SO3-2 0.51321E-17 -17.2897 0.26850E-17 -17.5710 0.52319E+00 -0.2813 98 HSO3- 0.15218E-19 -19.8176 0.12694E-19 -19.8964 0.83413E+00 -0.0788 99 HSO4- 0.15517E-18 -18.8092 0.12981E-18 -18.8867 0.83658E+00 -0.0775 Charge balance for all species = 0.2819E-09 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.8997061E-10 -.2198115E-01 -.2211676E+02 0.0000 2 H2O 0.1000000E+01 0.5550496E+02 0.9981819E+06 0.0000 3 Cl- 0.7422867E-03 0.7457519E-03 0.2639270E+02 6.9138 4 SO4-- 0.3452368E-11 -.6988096E-04 -.6701084E+01 8.4954 5 HCO3- 0.1275944E-05 0.7064349E-04 0.4302896E+01 4.1497 6 HS- 0.1378250E-03 0.2077329E-03 0.6858074E+01 6.1826 7 Al+++ 0.1033282E-28 0.5229862E-05 0.1408617E+00 0.7390 8 H4SiO4 0.6959841E-03 0.1336373E-01 0.1282204E+04 -3.1574 9 Ca++ 0.1405392E-06 0.2400506E-06 0.9603849E-02 13.1018 10 Mg++ 0.2198785E-10 0.9546500E-10 0.2316868E-05 9.2942 11 Fe++ 0.6060183E-13 0.3570596E-07 0.1990568E-02 6.7350 12 K+ 0.1594970E-03 0.1602523E-03 0.6255178E+01 6.2467 13 Na+ 0.2023995E-01 0.2268911E-01 0.5207018E+03 8.3494 14 Mn++ 0.1945407E-10 0.2532771E-08 0.1389009E-03 9.2419 15 HPO4-- 0.4396922E-07 0.4502986E-07 0.4314329E-02 12.6005 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.1341239E+03 -.4066810E-02 -.1341199E+03 0.0000000E+00 2 H2O -.4602856E+02 0.1026917E+02 -.5629773E+02 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.2245041E+00 -.1292892E-04 0.2245170E+00 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.2244786E+00 0.3843339E-04 -.2245170E+00 0.0000000E+00 7 Al+++ 0.2641200E+02 0.9675952E-06 0.2641200E+02 0.0000000E+00 8 H4SiO4 0.8434353E+02 0.2472471E-02 0.8434106E+02 0.0000000E+00 9 Ca++ 0.9316169E+01 0.4441261E-07 0.9316169E+01 0.0000000E+00 10 Mg++ 0.6428571E+01 0.1766232E-10 0.6428571E+01 0.0000000E+00 11 Fe++ 0.5775369E+01 0.6606085E-08 0.5775369E+01 0.0000000E+00 12 K+ 0.1719745E+01 0.2964884E-04 0.1719715E+01 0.0000000E+00 13 Na+ 0.1016763E+02 0.4197792E-02 0.1016343E+02 0.0000000E+00 14 Mn++ 0.1404426E+00 0.4685968E-09 0.1404426E+00 0.0000000E+00 15 HPO4-- 0.4793236E-01 0.8331132E-08 0.4793236E-01 0.0000000E+00 Chg. balance for solid moles: 0.6242E-13 Mass of aqueous solution: 0.185339E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 8099.9990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 10.15 1.007 2663. 3.425 30.09 1022. andradite 0.8981 -0.047 456.4 2.659 5.157 118.6 grossular 0.2175 -0.663 97.95 1.991 1.107 27.25 apatite-OH 0.1598E-01 -1.796 8.026 0.904 0.9070E-01 2.550 clinochlore 1.150 0.061 639.2 2.806 7.223 243.1 daphnite 0.3329 -0.478 237.5 2.376 2.684 71.98 chlorite-Mn 0.2809E-01 -1.551 19.91 1.299 0.2250 6.346 diopside 0.4313 -0.365 93.40 1.970 1.056 28.55 hedenbergite 0.1119 -0.951 27.75 1.443 0.3136 7.601 microcline 1.508 0.178 419.7 2.623 4.743 164.0 stilbite 5.210 0.717 3672. 3.565 41.49 1712. stilpnomelane-Fe 0.4235 -0.373 456.5 2.659 5.159 157.7 tr.625ac.25prg.125 0.6833E-01 -1.165 58.40 1.766 0.6600 18.80 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8051E+00 0.8051E+00 1.0000 -0.094 grossular 0.1949E+00 0.1949E+00 1.0000 -0.710 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.7611E+00 0.7611E+00 1.0000 -0.119 daphnite 0.2203E+00 0.2203E+00 1.0000 -0.657 chlorite-Mn 0.1859E-01 0.1859E-01 1.0000 -1.731 diopside 0.7941E+00 0.7941E+00 1.0000 -0.100 hedenbergite 0.2059E+00 0.2059E+00 1.0000 -0.686 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 tr.625ac.25prg.125 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 8849.108432 g Volume = 3581.072827 cm3 Porosity: -10.4929% V(tot) - V(min): -.34007E+03 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 8099.9990000 g log = 3.9085 Original solution: 1000.0103000 g Original solution / Rock added: 0.12 (Water/Rock Ratio), log = -0.9085 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.1341 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9010E+00 0.9845 0.1006E+01 0.1022E+01 CO2,gas 0.1613E-07 1.0059 0.1840E-07 0.1829E-07 CH4,gas 0.8563E-01 1.0115 0.9823E-01 0.9711E-01 H2,gas 0.1340E-01 1.0006 0.1521E-01 0.1520E-01 H2S,gas 0.6533E-06 0.9956 0.7376E-06 0.7409E-06 S2,gas 0.7788E-28 1.0000 0.8832E-28 0.8832E-28 CO,gas 0.6575E-13 1.0000 0.7456E-13 0.7456E-13 SO3,gas 0.3391E-47 1.0000 0.3846E-47 0.3846E-47 SO2,gas 0.2006E-26 1.0000 0.2275E-26 0.2275E-26 HCl,gas 0.1333E-16 1.0000 0.1512E-16 0.1512E-16 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 16 albite -0.38 -0.38 0.00 0.000 -0.94784E-12 22 andradite 39.01 39.01 0.00 0.000 0.00000E+00 23 grossular 32.73 32.73 0.00 0.000 0.12132E-10 32 apatite-OH -18.15 -18.15 0.00 0.000 0.60662E-11 46 clinochlore 39.07 39.07 0.00 0.000 0.48529E-10 47 daphnite 28.97 28.97 0.00 0.000 -0.60662E-11 48 chlorite-Mn 46.87 46.87 0.00 0.000 0.24265E-10 67 diopside 16.18 16.18 0.00 0.000 0.60662E-11 68 hedenbergite 14.21 14.21 0.00 0.000 0.90992E-11 116 microcline -2.49 -2.49 0.00 0.000 0.15165E-11 163 stilbite -7.52 -7.52 0.00 0.000 0.15165E-10 164 stilpnomelane-Fe 13.02 13.02 0.00 0.000 0.21232E-10 245 tr.625ac.25prg.125 45.16 45.16 0.00 0.000 0.24265E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -16.09 -9.43 -3.145 0.16109E+05 -7.735 3 CH4,gas 4.54 1.84 -2.71 -0.677 0.46217E+04 -1.008 4 H2,gas 8.00 4.48 -3.52 -2.010 0.60051E+04 -1.818 5 H2S,gas -6.23 -14.06 -7.83 -3.916 0.13371E+05 -6.132 6 S2,gas -7.34 -37.09 -29.75 -4.577 0.50802E+05 -28.054 7 CO,gas 3.21 -11.61 -14.83 -4.562 0.25316E+05 -13.127 8 SO3,gas 17.12 -31.99 -49.11 -12.278 0.83861E+05 -47.415 9 SO2,gas 0.83 -27.51 -28.34 -7.558 0.48393E+05 -26.643 10 HCl,gas 5.19 -13.33 -18.52 -9.260 0.31622E+05 -16.821 11 acmite 7.71 6.53 -1.18 -0.123 0.20175E+04 15 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 19 spessartine 24.46 19.73 -4.73 -0.236 0.80695E+04 20 analcite 3.32 2.77 -0.55 -0.061 0.93626E+03 26 annite 20.12 17.72 -2.40 -0.134 0.41064E+04 27 phlogopite 27.06 25.40 -1.67 -0.093 0.28490E+04 29 anorthite 12.71 8.26 -4.45 -0.342 0.75903E+04 35 aragonite 0.97 -2.99 -3.96 -1.320 0.67599E+04 36 brucite 12.57 9.29 -3.27 -0.655 0.55909E+04 37 calcite 0.81 -2.99 -3.80 -1.268 0.64956E+04 38 carnegieite-low 9.02 5.93 -3.09 -0.442 0.52801E+04 39 carnegieite-high 10.09 5.93 -4.16 -0.595 0.71071E+04 40 carpholite-Mg 8.58 4.46 -4.12 -0.275 0.70429E+04 41 carpholite-Fe 6.71 1.90 -4.81 -0.321 0.82207E+04 42 celadonite 5.34 3.65 -1.69 -0.099 0.28879E+04 43 celadonite-Fe 3.88 1.09 -2.79 -0.164 0.47561E+04 44 chrysotile 23.89 21.57 -2.32 -0.194 0.39692E+04 49 chlorite-Al-free 47.17 43.14 -4.04 -0.168 0.68936E+04 51 chloritoid-Fe 9.17 5.06 -4.12 -0.275 0.70316E+04 52 chloritoid-Mn 11.40 7.56 -3.84 -0.256 0.65544E+04 54 coesite -2.38 -3.16 -0.78 -0.260 0.13341E+04 61 cristobalite -2.56 -3.16 -0.60 -0.199 0.10195E+04 63 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71234E+04 65 diaspore 2.87 0.74 -2.13 -0.356 0.36450E+04 66 diamond -3.10 -7.13 -4.03 -1.150 0.68748E+04 71 enstatite 17.26 12.27 -4.99 -0.499 0.85226E+04 73 clinoenstatite 17.17 12.27 -4.89 -0.489 0.83542E+04 75 epidote 24.67 22.70 -1.97 -0.095 0.33586E+04 76 clinozoisite 22.81 18.95 -3.86 -0.175 0.65869E+04 77 epidote-Fe 29.84 26.46 -3.38 -0.176 0.57768E+04 78 fayalite 14.05 10.31 -3.73 -0.533 0.63743E+04 79 ferrosilite 11.15 7.16 -3.99 -0.399 0.68202E+04 83 gibbsite 4.08 0.74 -3.34 -0.477 0.57036E+04 84 glaucophane 22.97 20.80 -2.17 -0.059 0.37134E+04 85 glaucophane-Fe 17.28 13.12 -4.15 -0.112 0.70919E+04 86 graphite -3.55 -7.13 -3.58 -1.024 0.61170E+04 87 greenalite 16.14 13.89 -2.25 -0.187 0.38408E+04 90 hematite 12.57 8.99 -3.58 -0.434 0.61111E+04 91 heulandite -5.83 -7.52 -1.69 -0.077 0.28938E+04 95 jadeite 4.22 2.77 -1.44 -0.144 0.24617E+04 97 kalsilite 7.58 3.83 -3.76 -0.537 0.64126E+04 98 kaolinite -1.33 -4.84 -3.50 -0.319 0.59832E+04 101 laumontite 2.88 1.95 -0.93 -0.062 0.15935E+04 102 lawsonite 9.62 8.26 -1.35 -0.090 0.23070E+04 103 leucite 4.12 0.67 -3.45 -0.345 0.58873E+04 105 lizardite 23.24 21.57 -1.68 -0.140 0.28619E+04 107 magnetite 20.09 15.72 -4.37 -0.356 0.74536E+04 108 minnesotaite 10.39 7.58 -2.81 -0.165 0.48027E+04 112 manganosite 14.06 9.24 -4.82 -1.204 0.82236E+04 120 muscovite 2.58 -1.01 -3.59 -0.211 0.61315E+04 121 paragonite 4.24 1.09 -3.15 -0.185 0.53706E+04 122 nepheline 8.34 5.93 -2.41 -0.344 0.41125E+04 128 periclase-Fe 11.63 6.73 -4.89 -1.223 0.83523E+04 134 phlogopite-Na 29.65 27.50 -2.15 -0.119 0.36678E+04 136 prehnite 19.37 18.21 -1.16 -0.068 0.19849E+04 137 prehnite-Fe 22.50 21.96 -0.53 -0.032 0.91159E+03 138 pumpellyite-Fe 46.27 43.89 -2.38 -0.053 0.40582E+04 139 pumpellyite-Mg 48.99 46.45 -2.54 -0.057 0.43421E+04 142 pyrite -21.25 -25.87 -4.62 -1.088 0.78948E+04 143 pyrrhotite -4.26 -7.33 -3.07 -1.022 0.52353E+04 144 pyrrhotiteFe0.875 -6.02 -8.72 -2.71 -0.996 0.46225E+04 145 pyroxmangite 7.40 6.08 -1.31 -0.263 0.22440E+04 146 pyrophyllite -6.18 -11.15 -4.98 -0.311 0.84962E+04 147 quartz -2.99 -3.16 -0.17 -0.056 0.28679E+03 152 rhodonite 7.45 6.08 -1.36 -0.272 0.23242E+04 153 sanidine -1.28 -2.49 -1.21 -0.093 0.20677E+04 165 stilpnomelane-Mg 27.44 25.81 -1.63 -0.049 0.27804E+04 171 talc 16.49 15.25 -1.24 -0.073 0.21140E+04 174 tephroite 18.09 15.33 -2.76 -0.394 0.47117E+04 178 tridymite -2.63 -3.16 -0.53 -0.177 0.90677E+03 179 tremolite 47.87 47.42 -0.45 -0.012 0.77494E+03 180 ferroactinolite 38.45 34.62 -3.83 -0.104 0.65448E+04 181 troilite-low -4.41 -7.33 -2.92 -0.972 0.49781E+04 183 vesuvianite 223.47 218.82 -4.65 -0.036 0.79441E+04 187 wairakite 3.95 1.95 -2.00 -0.118 0.34155E+04 188 walstromite 11.51 9.94 -1.56 -0.313 0.26719E+04 189 wollastonite 10.46 9.94 -0.52 -0.103 0.88229E+03 190 pseudo-wollastonite 11.00 9.94 -1.06 -0.211 0.18021E+04 191 zoisite 22.85 18.95 -3.90 -0.177 0.66610E+04 192 akaganeite 7.75 4.49 -3.26 -0.705 0.55681E+04 199 chalcedony -2.80 -3.16 -0.35 -0.118 0.60609E+03 201 montmorillonite-Ca -2.29 -6.17 -3.88 -0.240 0.66180E+04 202 montmorillonite-K -2.24 -6.27 -4.03 -0.247 0.68816E+04 203 montmorillonite-Mg -2.48 -6.79 -4.32 -0.267 0.73678E+04 204 montmorillonite-Na -2.04 -5.57 -3.54 -0.216 0.60365E+04 205 nontronite-Ca 3.21 -0.19 -3.41 -0.221 0.58215E+04 206 nontronite-H 2.53 -2.36 -4.89 -0.328 0.83485E+04 207 nontronite-K 3.34 -0.30 -3.64 -0.233 0.62083E+04 208 nontronite-Mg 3.07 -0.82 -3.90 -0.253 0.66553E+04 209 nontronite-Na 3.52 0.40 -3.12 -0.200 0.53291E+04 224 tobermorite 9.82 7.76 -2.07 -0.564 0.35287E+04 230 alabandite -0.98 -4.82 -3.84 -1.281 0.65595E+04 233 boehmite 4.41 0.74 -3.67 -0.611 0.62619E+04 235 ferrous-oxide 9.81 6.73 -3.08 -0.769 0.52532E+04 240 silica-amorphous -2.09 -3.16 -1.07 -0.355 0.18203E+04 242 an20ab80 2.02 1.35 -0.67 -0.052 0.11472E+04 243 an25ab75 2.65 1.78 -0.87 -0.067 0.14810E+04 244 an30ab70 3.28 2.21 -1.07 -0.082 0.18244E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 100.0000000 g Current total amount of reactant added: 8099.9990000 g New total amount of reactant added: 8199.9990000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.5215E-10 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 13 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 8199.9990000 Water: Moles liquid = 0.9712E+01 kg liquid = 0.1750E+00 Moles total = -.4728E+02 kg total = -.8518E+00 Activity = 1.0000 Stoichiometric ionic strength = .1185748E-01 Osmotic coef. = 0.9675 True ionic strength = .2043040E-01 Chg. balance for total moles = 0.5215E-10 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.90093E-10 -10.0453 0.75604E-10 -10.1215 0.83918E+00 -0.0761 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.78489E-03 -3.1052 0.65464E-03 -3.1840 0.83405E+00 -0.0788 4 SO4-- 0.36469E-11 -11.4381 0.18838E-11 -11.7250 0.51654E+00 -0.2869 5 HCO3- 0.13477E-05 -5.8704 0.11257E-05 -5.9486 0.83529E+00 -0.0782 6 HS- 0.14574E-03 -3.8364 0.12157E-03 -3.9152 0.83418E+00 -0.0787 7 Al+++ 0.10381E-28 -28.9838 0.23692E-29 -29.6254 0.22823E+00 -0.6416 8 H4SiO4 0.69598E-03 -3.1574 0.69598E-03 -3.1574 0.10000E+01 0.0000 9 Ca++ 0.14095E-06 -6.8509 0.72263E-07 -7.1411 0.51269E+00 -0.2901 10 Mg++ 0.22052E-10 -10.6566 0.11253E-10 -10.9487 0.51031E+00 -0.2922 11 Fe++ 0.60779E-13 -13.2162 0.31050E-13 -13.5079 0.51087E+00 -0.2917 12 K+ 0.15971E-03 -3.7967 0.13344E-03 -3.8747 0.83549E+00 -0.0781 13 Na+ 0.20268E-01 -1.6932 0.16901E-01 -1.7721 0.83390E+00 -0.0789 14 Mn++ 0.19511E-10 -10.7097 0.99761E-11 -11.0010 0.51131E+00 -0.2913 15 HPO4-- 0.43873E-07 -7.3578 0.22666E-07 -7.6446 0.51662E+00 -0.2868 16 HSiO3- 0.10306E-01 -1.9869 0.85957E-02 -2.0657 0.83405E+00 -0.0788 17 Ca(HSiO3)+ 0.16928E-07 -7.7714 0.14146E-07 -7.8494 0.83568E+00 -0.0780 18 Mg(HSiO3)+ 0.32806E-11 -11.4840 0.27416E-11 -11.5620 0.83568E+00 -0.0780 19 NaHSiO3,aq 0.23497E-02 -2.6290 0.23497E-02 -2.6290 0.10000E+01 0.0000 20 AlO+ 0.67475E-16 -16.1709 0.56388E-16 -16.2488 0.83568E+00 -0.0780 22 HAlO2,aq 0.14853E-09 -9.8282 0.14853E-09 -9.8282 0.10000E+01 0.0000 23 AlO2- 0.52236E-05 -5.2820 0.43487E-05 -5.3616 0.83252E+00 -0.0796 24 CH4,aq 0.70826E-04 -4.1498 0.70570E-04 -4.1514 0.99639E+00 -0.0016 25 C2H6,aq 0.73773E-13 -13.1321 0.73507E-13 -13.1337 0.99639E+00 -0.0016 29 CO,aq 0.52913E-16 -16.2764 0.52913E-16 -16.2764 0.10000E+01 0.0000 30 CO2,aq 0.18252E-09 -9.7387 0.18186E-09 -9.7403 0.99639E+00 -0.0016 31 CO3-2 0.25233E-05 -5.5980 0.13006E-05 -5.8859 0.51543E+00 -0.2878 32 CaCO3,aq 0.11784E-08 -8.9287 0.11784E-08 -8.9287 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.24848E-11 -11.6047 0.20765E-11 -11.6827 0.83568E+00 -0.0780 34 CaCl+ 0.91610E-10 -10.0381 0.76556E-10 -10.1160 0.83568E+00 -0.0780 35 CaCl2,aq 0.11907E-13 -13.9242 0.11907E-13 -13.9242 0.10000E+01 0.0000 36 CaOH+ 0.81515E-07 -7.0888 0.68120E-07 -7.1667 0.83568E+00 -0.0780 37 CaSO4,aq 0.43227E-16 -16.3642 0.43227E-16 -16.3642 0.10000E+01 0.0000 38 HCl,aq 0.90694E-14 -14.0424 0.90694E-14 -14.0424 0.10000E+01 0.0000 43 FeCl+ 0.38500E-16 -16.4145 0.32174E-16 -16.4925 0.83568E+00 -0.0780 46 FeO,aq 0.21112E-09 -9.6755 0.21112E-09 -9.6755 0.10000E+01 0.0000 47 FeOH+ 0.15997E-10 -10.7960 0.13369E-10 -10.8739 0.83568E+00 -0.0780 48 HFeO2- 0.35032E-07 -7.4555 0.29218E-07 -7.5343 0.83405E+00 -0.0788 49 FeO+ 0.11212E-16 -16.9503 0.93694E-17 -17.0283 0.83568E+00 -0.0780 51 FeO2- 0.40214E-09 -9.3956 0.33541E-09 -9.4744 0.83405E+00 -0.0788 52 HFeO2,aq 0.32252E-11 -11.4914 0.32252E-11 -11.4914 0.10000E+01 0.0000 53 H2,aq 0.11624E-04 -4.9346 0.11582E-04 -4.9362 0.99639E+00 -0.0016 54 KCl,aq 0.15832E-08 -8.8005 0.15832E-08 -8.8005 0.10000E+01 0.0000 56 KOH,aq 0.75375E-06 -6.1228 0.75375E-06 -6.1228 0.10000E+01 0.0000 57 KSO4- 0.46767E-14 -14.3301 0.39007E-14 -14.4089 0.83405E+00 -0.0788 58 MgCO3,aq 0.45999E-13 -13.3373 0.45999E-13 -13.3373 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.39539E-15 -15.4030 0.33042E-15 -15.4809 0.83568E+00 -0.0780 60 MgCl+ 0.12930E-13 -13.8884 0.10805E-13 -13.9664 0.83568E+00 -0.0780 61 MgOH+ 0.70242E-10 -10.1534 0.58700E-10 -10.2314 0.83568E+00 -0.0780 63 MnO,aq 0.18074E-08 -8.7429 0.18074E-08 -8.7429 0.10000E+01 0.0000 64 MnOH+ 0.47747E-09 -9.3211 0.39901E-09 -9.3990 0.83568E+00 -0.0780 65 MnO2-2 0.20360E-10 -10.6912 0.10494E-10 -10.9791 0.51543E+00 -0.2878 66 HMnO2- 0.20840E-09 -9.6811 0.17382E-09 -9.7599 0.83405E+00 -0.0788 69 MnCl+ 0.48124E-13 -13.3176 0.40216E-13 -13.3956 0.83568E+00 -0.0780 71 NaCl,aq 0.36667E-05 -5.4357 0.36667E-05 -5.4357 0.10000E+01 0.0000 72 NaOH,aq 0.96047E-04 -4.0175 0.96047E-04 -4.0175 0.10000E+01 0.0000 74 OH- 0.91794E-02 -2.0372 0.76421E-02 -2.1168 0.83252E+00 -0.0796 79 HPO3-2 0.15872E-14 -14.7994 0.81811E-15 -15.0872 0.51543E+00 -0.2878 81 H2PO3- 0.14871E-18 -18.8277 0.12403E-18 -18.9065 0.83405E+00 -0.0788 82 H3PO4,aq 0.90612E-18 -18.0428 0.90612E-18 -18.0428 0.10000E+01 0.0000 83 H2PO4- 0.37865E-10 -10.4218 0.31612E-10 -10.5002 0.83486E+00 -0.0784 84 PO4-3 0.10196E-08 -8.9916 0.24460E-09 -9.6115 0.23989E+00 -0.6200 88 HP2O7-3 0.90582E-18 -18.0430 0.20694E-18 -18.6841 0.22846E+00 -0.6412 89 P2O7-4 0.86625E-17 -17.0624 0.65390E-18 -18.1845 0.75487E-01 -1.1221 90 H2S,aq 0.28509E-07 -7.5450 0.28406E-07 -7.5466 0.99639E+00 -0.0016 91 S2-2 0.54855E-13 -13.2608 0.28274E-13 -13.5486 0.51543E+00 -0.2878 97 SO3-2 0.54211E-17 -17.2659 0.28353E-17 -17.5474 0.52300E+00 -0.2815 98 HSO3- 0.16092E-19 -19.7934 0.13422E-19 -19.8722 0.83405E+00 -0.0788 99 HSO4- 0.16408E-18 -18.7849 0.13725E-18 -18.8625 0.83650E+00 -0.0775 Charge balance for all species = 0.2976E-09 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.9009289E-10 -.2195828E-01 -.2209372E+02 0.0000 2 H2O 0.1000000E+01 0.5550496E+02 0.9981807E+06 0.0000 3 Cl- 0.7848867E-03 0.7885551E-03 0.2790750E+02 6.9375 4 SO4-- 0.3646858E-11 -.7373185E-04 -.7070348E+01 8.5179 5 HCO3- 0.1347702E-05 0.7469814E-04 0.4549859E+01 4.1729 6 HS- 0.1457356E-03 0.2194959E-03 0.7246408E+01 6.2063 7 Al+++ 0.1038088E-28 0.5223706E-05 0.1406956E+00 0.7390 8 H4SiO4 0.6959842E-03 0.1335157E-01 0.1281035E+04 -3.1574 9 Ca++ 0.1409492E-06 0.2406640E-06 0.9628375E-02 13.1018 10 Mg++ 0.2205209E-10 0.9563466E-10 0.2320982E-05 9.2942 11 Fe++ 0.6077883E-13 0.3566415E-07 0.1988234E-02 6.7350 12 K+ 0.1597145E-03 0.1604699E-03 0.6263662E+01 6.2467 13 Na+ 0.2026759E-01 0.2271696E-01 0.5213401E+03 8.3494 14 Mn++ 0.1951113E-10 0.2533224E-08 0.1389256E-03 9.2419 15 HPO4-- 0.4387329E-07 0.4493078E-07 0.4304830E-02 12.5983 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.1357798E+03 -.3842059E-02 -.1357760E+03 0.0000000E+00 2 H2O -.4728210E+02 0.9711753E+01 -.5699385E+02 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.2272754E+00 -.1290093E-04 0.2272883E+00 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.2272499E+00 0.3840540E-04 -.2272883E+00 0.0000000E+00 7 Al+++ 0.2673808E+02 0.9139964E-06 0.2673808E+02 0.0000000E+00 8 H4SiO4 0.8538481E+02 0.2336136E-02 0.8538247E+02 0.0000000E+00 9 Ca++ 0.9431183E+01 0.4210919E-07 0.9431183E+01 0.0000000E+00 10 Mg++ 0.6507936E+01 0.1673328E-10 0.6507936E+01 0.0000000E+00 11 Fe++ 0.5846670E+01 0.6240188E-08 0.5846670E+01 0.0000000E+00 12 K+ 0.1740976E+01 0.2807756E-04 0.1740948E+01 0.0000000E+00 13 Na+ 0.1029316E+02 0.3974806E-02 0.1028918E+02 0.0000000E+00 14 Mn++ 0.1421765E+00 0.4432404E-09 0.1421765E+00 0.0000000E+00 15 HPO4-- 0.4852412E-01 0.7861577E-08 0.4852411E-01 0.0000000E+00 Chg. balance for solid moles: 0.2226E-13 Mass of aqueous solution: 0.175279E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 8199.9990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 10.28 1.012 2696. 3.431 30.09 1035. andradite 0.9092 -0.041 462.0 2.665 5.157 120.0 grossular 0.2201 -0.657 99.16 1.996 1.107 27.59 apatite-OH 0.1617E-01 -1.791 8.125 0.910 0.9070E-01 2.582 clinochlore 1.164 0.066 647.0 2.811 7.223 246.1 daphnite 0.3370 -0.472 240.5 2.381 2.684 72.86 chlorite-Mn 0.2844E-01 -1.546 20.16 1.304 0.2250 6.424 diopside 0.4367 -0.360 94.58 1.976 1.056 28.91 hedenbergite 0.1133 -0.946 28.10 1.449 0.3137 7.697 microcline 1.527 0.184 424.9 2.628 4.743 166.0 stilbite 5.274 0.722 3717. 3.570 41.49 1734. stilpnomelane-Fe 0.4287 -0.368 462.2 2.665 5.159 159.6 tr.625ac.25prg.125 0.6916E-01 -1.160 59.12 1.772 0.6599 19.03 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8051E+00 0.8051E+00 1.0000 -0.094 grossular 0.1949E+00 0.1949E+00 1.0000 -0.710 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.7611E+00 0.7611E+00 1.0000 -0.119 daphnite 0.2203E+00 0.2203E+00 1.0000 -0.657 chlorite-Mn 0.1859E-01 0.1859E-01 1.0000 -1.731 diopside 0.7941E+00 0.7941E+00 1.0000 -0.100 hedenbergite 0.2059E+00 0.2059E+00 1.0000 -0.686 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 tr.625ac.25prg.125 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 8958.359092 g Volume = 3625.275889 cm3 Porosity: -10.4930% V(tot) - V(min): -.34428E+03 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 8199.9990000 g log = 3.9138 Original solution: 1000.0103000 g Original solution / Rock added: 0.12 (Water/Rock Ratio), log = -0.9138 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.1398 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.8966E+00 0.9844 0.1006E+01 0.1022E+01 CO2,gas 0.1697E-07 1.0058 0.1946E-07 0.1934E-07 CH4,gas 0.9011E-01 1.0114 0.1039E+00 0.1027E+00 H2,gas 0.1333E-01 1.0006 0.1521E-01 0.1520E-01 H2S,gas 0.6882E-06 0.9956 0.7809E-06 0.7843E-06 S2,gas 0.8685E-28 1.0000 0.9898E-28 0.9898E-28 CO,gas 0.6918E-13 1.0000 0.7885E-13 0.7885E-13 SO3,gas 0.3572E-47 1.0000 0.4071E-47 0.4071E-47 SO2,gas 0.2113E-26 1.0000 0.2409E-26 0.2409E-26 HCl,gas 0.1404E-16 1.0000 0.1600E-16 0.1600E-16 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 16 albite -0.38 -0.38 0.00 0.000 -0.94784E-12 22 andradite 39.01 39.01 0.00 0.000 0.00000E+00 23 grossular 32.73 32.73 0.00 0.000 0.48529E-10 32 apatite-OH -18.15 -18.15 0.00 0.000 0.00000E+00 46 clinochlore 39.07 39.07 0.00 0.000 -0.12132E-10 47 daphnite 28.97 28.97 0.00 0.000 -0.12132E-10 48 chlorite-Mn 46.87 46.87 0.00 0.000 0.48529E-10 67 diopside 16.18 16.18 0.00 0.000 0.60662E-11 68 hedenbergite 14.21 14.21 0.00 0.000 -0.30331E-11 116 microcline -2.49 -2.49 0.00 0.000 0.15165E-11 163 stilbite -7.52 -7.52 0.00 0.000 0.15165E-10 164 stilpnomelane-Fe 13.02 13.02 0.00 0.000 -0.75827E-10 245 tr.625ac.25prg.125 45.16 45.16 0.00 0.000 0.24265E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -16.07 -9.41 -3.137 0.16067E+05 -7.711 3 CH4,gas 4.54 1.86 -2.68 -0.671 0.45802E+04 -0.983 4 H2,gas 8.00 4.48 -3.52 -2.010 0.60051E+04 -1.818 5 H2S,gas -6.23 -14.04 -7.81 -3.903 0.13329E+05 -6.107 6 S2,gas -7.34 -37.04 -29.70 -4.570 0.50718E+05 -28.004 7 CO,gas 3.21 -11.59 -14.80 -4.555 0.25274E+05 -13.103 8 SO3,gas 17.12 -31.97 -49.09 -12.272 0.83819E+05 -47.390 9 SO2,gas 0.83 -27.49 -28.32 -7.551 0.48351E+05 -26.618 10 HCl,gas 5.19 -13.31 -18.49 -9.247 0.31579E+05 -16.796 11 acmite 7.71 6.53 -1.18 -0.123 0.20175E+04 15 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 19 spessartine 24.46 19.73 -4.73 -0.236 0.80695E+04 20 analcite 3.32 2.77 -0.55 -0.061 0.93626E+03 26 annite 20.12 17.72 -2.40 -0.134 0.41064E+04 27 phlogopite 27.06 25.40 -1.67 -0.093 0.28490E+04 29 anorthite 12.71 8.26 -4.45 -0.342 0.75903E+04 35 aragonite 0.97 -2.97 -3.93 -1.312 0.67184E+04 36 brucite 12.57 9.29 -3.27 -0.655 0.55909E+04 37 calcite 0.81 -2.97 -3.78 -1.260 0.64542E+04 38 carnegieite-low 9.02 5.93 -3.09 -0.442 0.52801E+04 39 carnegieite-high 10.09 5.93 -4.16 -0.595 0.71071E+04 40 carpholite-Mg 8.58 4.46 -4.12 -0.275 0.70429E+04 41 carpholite-Fe 6.71 1.90 -4.81 -0.321 0.82207E+04 42 celadonite 5.34 3.65 -1.69 -0.099 0.28879E+04 43 celadonite-Fe 3.88 1.09 -2.79 -0.164 0.47561E+04 44 chrysotile 23.89 21.57 -2.32 -0.194 0.39692E+04 49 chlorite-Al-free 47.17 43.14 -4.04 -0.168 0.68936E+04 51 chloritoid-Fe 9.17 5.06 -4.12 -0.275 0.70316E+04 52 chloritoid-Mn 11.40 7.56 -3.84 -0.256 0.65544E+04 54 coesite -2.38 -3.16 -0.78 -0.260 0.13341E+04 61 cristobalite -2.56 -3.16 -0.60 -0.199 0.10195E+04 63 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71234E+04 65 diaspore 2.87 0.74 -2.13 -0.356 0.36450E+04 66 diamond -3.10 -7.10 -4.00 -1.143 0.68333E+04 71 enstatite 17.26 12.27 -4.99 -0.499 0.85226E+04 73 clinoenstatite 17.17 12.27 -4.89 -0.489 0.83542E+04 75 epidote 24.67 22.70 -1.97 -0.095 0.33586E+04 76 clinozoisite 22.81 18.95 -3.86 -0.175 0.65869E+04 77 epidote-Fe 29.84 26.46 -3.38 -0.176 0.57768E+04 78 fayalite 14.05 10.31 -3.73 -0.533 0.63743E+04 79 ferrosilite 11.15 7.16 -3.99 -0.399 0.68202E+04 83 gibbsite 4.08 0.74 -3.34 -0.477 0.57036E+04 84 glaucophane 22.97 20.80 -2.17 -0.059 0.37134E+04 85 glaucophane-Fe 17.28 13.12 -4.15 -0.112 0.70919E+04 86 graphite -3.55 -7.10 -3.56 -1.017 0.60756E+04 87 greenalite 16.14 13.89 -2.25 -0.187 0.38408E+04 90 hematite 12.57 8.99 -3.58 -0.434 0.61111E+04 91 heulandite -5.83 -7.52 -1.69 -0.077 0.28938E+04 95 jadeite 4.22 2.77 -1.44 -0.144 0.24617E+04 97 kalsilite 7.58 3.83 -3.76 -0.537 0.64126E+04 98 kaolinite -1.33 -4.84 -3.50 -0.319 0.59832E+04 101 laumontite 2.88 1.95 -0.93 -0.062 0.15935E+04 102 lawsonite 9.62 8.26 -1.35 -0.090 0.23070E+04 103 leucite 4.12 0.67 -3.45 -0.345 0.58873E+04 105 lizardite 23.24 21.57 -1.68 -0.140 0.28619E+04 107 magnetite 20.09 15.72 -4.37 -0.356 0.74536E+04 108 minnesotaite 10.39 7.58 -2.81 -0.165 0.48027E+04 112 manganosite 14.06 9.24 -4.82 -1.204 0.82236E+04 120 muscovite 2.58 -1.01 -3.59 -0.211 0.61315E+04 121 paragonite 4.24 1.09 -3.15 -0.185 0.53706E+04 122 nepheline 8.34 5.93 -2.41 -0.344 0.41125E+04 128 periclase-Fe 11.63 6.73 -4.89 -1.223 0.83523E+04 134 phlogopite-Na 29.65 27.50 -2.15 -0.119 0.36678E+04 136 prehnite 19.37 18.21 -1.16 -0.068 0.19849E+04 137 prehnite-Fe 22.50 21.96 -0.53 -0.032 0.91159E+03 138 pumpellyite-Fe 46.27 43.89 -2.38 -0.053 0.40582E+04 139 pumpellyite-Mg 48.99 46.45 -2.54 -0.057 0.43421E+04 142 pyrite -21.25 -25.82 -4.57 -1.076 0.78103E+04 143 pyrrhotite -4.26 -7.30 -3.04 -1.014 0.51930E+04 144 pyrrhotiteFe0.875 -6.02 -8.70 -2.68 -0.987 0.45802E+04 145 pyroxmangite 7.40 6.08 -1.31 -0.263 0.22440E+04 146 pyrophyllite -6.18 -11.15 -4.98 -0.311 0.84962E+04 147 quartz -2.99 -3.16 -0.17 -0.056 0.28679E+03 152 rhodonite 7.45 6.08 -1.36 -0.272 0.23242E+04 153 sanidine -1.28 -2.49 -1.21 -0.093 0.20677E+04 165 stilpnomelane-Mg 27.44 25.81 -1.63 -0.049 0.27804E+04 171 talc 16.49 15.25 -1.24 -0.073 0.21140E+04 174 tephroite 18.09 15.33 -2.76 -0.394 0.47117E+04 178 tridymite -2.63 -3.16 -0.53 -0.177 0.90677E+03 179 tremolite 47.87 47.42 -0.45 -0.012 0.77494E+03 180 ferroactinolite 38.45 34.62 -3.83 -0.104 0.65448E+04 181 troilite-low -4.41 -7.30 -2.89 -0.964 0.49358E+04 183 vesuvianite 223.47 218.82 -4.65 -0.036 0.79441E+04 187 wairakite 3.95 1.95 -2.00 -0.118 0.34155E+04 188 walstromite 11.51 9.94 -1.56 -0.313 0.26719E+04 189 wollastonite 10.46 9.94 -0.52 -0.103 0.88229E+03 190 pseudo-wollastonite 11.00 9.94 -1.06 -0.211 0.18021E+04 191 zoisite 22.85 18.95 -3.90 -0.177 0.66610E+04 192 akaganeite 7.75 4.49 -3.26 -0.705 0.55681E+04 199 chalcedony -2.80 -3.16 -0.35 -0.118 0.60609E+03 201 montmorillonite-Ca -2.29 -6.17 -3.88 -0.240 0.66180E+04 202 montmorillonite-K -2.24 -6.27 -4.03 -0.247 0.68816E+04 203 montmorillonite-Mg -2.48 -6.79 -4.32 -0.267 0.73678E+04 204 montmorillonite-Na -2.04 -5.57 -3.54 -0.216 0.60365E+04 205 nontronite-Ca 3.21 -0.19 -3.41 -0.221 0.58215E+04 206 nontronite-H 2.53 -2.36 -4.89 -0.328 0.83485E+04 207 nontronite-K 3.34 -0.30 -3.64 -0.233 0.62083E+04 208 nontronite-Mg 3.07 -0.82 -3.90 -0.253 0.66553E+04 209 nontronite-Na 3.52 0.40 -3.12 -0.200 0.53291E+04 224 tobermorite 9.82 7.76 -2.07 -0.564 0.35287E+04 230 alabandite -0.98 -4.79 -3.82 -1.272 0.65172E+04 233 boehmite 4.41 0.74 -3.67 -0.611 0.62619E+04 235 ferrous-oxide 9.81 6.73 -3.08 -0.769 0.52532E+04 240 silica-amorphous -2.09 -3.16 -1.07 -0.355 0.18203E+04 242 an20ab80 2.02 1.35 -0.67 -0.052 0.11472E+04 243 an25ab75 2.65 1.78 -0.87 -0.067 0.14810E+04 244 an30ab70 3.28 2.21 -1.07 -0.082 0.18244E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 100.0000000 g Current total amount of reactant added: 8199.9990000 g New total amount of reactant added: 8299.9990000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.5212E-10 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 13 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 8299.9990000 Water: Moles liquid = 0.9155E+01 kg liquid = 0.1649E+00 Moles total = -.4854E+02 kg total = -.8744E+00 Activity = 1.0000 Stoichiometric ionic strength = .1189745E-01 Osmotic coef. = 0.9675 True ionic strength = .2046184E-01 Chg. balance for total moles = 0.5212E-10 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.90230E-10 -10.0446 0.75712E-10 -10.1208 0.83910E+00 -0.0762 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.83267E-03 -3.0795 0.69442E-03 -3.1584 0.83397E+00 -0.0789 4 SO4-- 0.38646E-11 -11.4129 0.19954E-11 -11.7000 0.51633E+00 -0.2871 5 HCO3- 0.14280E-05 -5.8453 0.11927E-05 -5.9235 0.83521E+00 -0.0782 6 HS- 0.15461E-03 -3.8108 0.12896E-03 -3.8896 0.83409E+00 -0.0788 7 Al+++ 0.10435E-28 -28.9815 0.23793E-29 -29.6235 0.22801E+00 -0.6420 8 H4SiO4 0.69598E-03 -3.1574 0.69598E-03 -3.1574 0.10000E+01 0.0000 9 Ca++ 0.14141E-06 -6.8495 0.72470E-07 -7.1398 0.51248E+00 -0.2903 10 Mg++ 0.22124E-10 -10.6551 0.11285E-10 -10.9475 0.51009E+00 -0.2924 11 Fe++ 0.60978E-13 -13.2148 0.31139E-13 -13.5067 0.51066E+00 -0.2919 12 K+ 0.15996E-03 -3.7960 0.13363E-03 -3.8741 0.83541E+00 -0.0781 13 Na+ 0.20299E-01 -1.6925 0.16925E-01 -1.7715 0.83381E+00 -0.0789 14 Mn++ 0.19575E-10 -10.7083 0.10005E-10 -10.9998 0.51109E+00 -0.2915 15 HPO4-- 0.43766E-07 -7.3589 0.22601E-07 -7.6459 0.51641E+00 -0.2870 16 HSiO3- 0.10292E-01 -1.9875 0.85834E-02 -2.0663 0.83397E+00 -0.0789 17 Ca(HSiO3)+ 0.16953E-07 -7.7707 0.14166E-07 -7.8487 0.83559E+00 -0.0780 18 Mg(HSiO3)+ 0.32857E-11 -11.4834 0.27455E-11 -11.5614 0.83559E+00 -0.0780 19 NaHSiO3,aq 0.23497E-02 -2.6290 0.23497E-02 -2.6290 0.10000E+01 0.0000 20 AlO+ 0.67579E-16 -16.1702 0.56468E-16 -16.2482 0.83559E+00 -0.0780 22 HAlO2,aq 0.14853E-09 -9.8282 0.14853E-09 -9.8282 0.10000E+01 0.0000 23 AlO2- 0.52167E-05 -5.2826 0.43425E-05 -5.3623 0.83244E+00 -0.0796 24 CH4,aq 0.75147E-04 -4.1241 0.74874E-04 -4.1257 0.99637E+00 -0.0016 25 C2H6,aq 0.83048E-13 -13.0807 0.82747E-13 -13.0822 0.99637E+00 -0.0016 29 CO,aq 0.56141E-16 -16.2507 0.56141E-16 -16.2507 0.10000E+01 0.0000 30 CO2,aq 0.19365E-09 -9.7130 0.19295E-09 -9.7146 0.99637E+00 -0.0016 31 CO3-2 0.26706E-05 -5.5734 0.13760E-05 -5.8614 0.51522E+00 -0.2880 32 CaCO3,aq 0.12503E-08 -8.9030 0.12503E-08 -8.9030 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.26404E-11 -11.5783 0.22063E-11 -11.6563 0.83559E+00 -0.0780 34 CaCl+ 0.97465E-10 -10.0112 0.81441E-10 -10.0892 0.83559E+00 -0.0780 35 CaCl2,aq 0.13436E-13 -13.8717 0.13436E-13 -13.8717 0.10000E+01 0.0000 36 CaOH+ 0.81639E-07 -7.0881 0.68217E-07 -7.1661 0.83559E+00 -0.0780 37 CaSO4,aq 0.45919E-16 -16.3380 0.45919E-16 -16.3380 0.10000E+01 0.0000 38 HCl,aq 0.96344E-14 -14.0162 0.96344E-14 -14.0162 0.10000E+01 0.0000 43 FeCl+ 0.40961E-16 -16.3876 0.34227E-16 -16.4656 0.83559E+00 -0.0780 46 FeO,aq 0.21112E-09 -9.6755 0.21112E-09 -9.6755 0.10000E+01 0.0000 47 FeOH+ 0.16022E-10 -10.7953 0.13388E-10 -10.8733 0.83559E+00 -0.0780 48 HFeO2- 0.34985E-07 -7.4561 0.29177E-07 -7.5350 0.83397E+00 -0.0789 49 FeO+ 0.11229E-16 -16.9497 0.93828E-17 -17.0277 0.83559E+00 -0.0780 51 FeO2- 0.40161E-09 -9.3962 0.33493E-09 -9.4751 0.83397E+00 -0.0789 52 HFeO2,aq 0.32252E-11 -11.4914 0.32252E-11 -11.4914 0.10000E+01 0.0000 53 H2,aq 0.11624E-04 -4.9346 0.11582E-04 -4.9362 0.99637E+00 -0.0016 54 KCl,aq 0.16819E-08 -8.7742 0.16819E-08 -8.7742 0.10000E+01 0.0000 56 KOH,aq 0.75375E-06 -6.1228 0.75375E-06 -6.1228 0.10000E+01 0.0000 57 KSO4- 0.49615E-14 -14.3044 0.41377E-14 -14.3832 0.83397E+00 -0.0789 58 MgCO3,aq 0.48805E-13 -13.3115 0.48805E-13 -13.3115 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.42015E-15 -15.3766 0.35108E-15 -15.4546 0.83559E+00 -0.0780 60 MgCl+ 0.13756E-13 -13.8615 0.11495E-13 -13.9395 0.83559E+00 -0.0780 61 MgOH+ 0.70350E-10 -10.1527 0.58784E-10 -10.2307 0.83559E+00 -0.0780 63 MnO,aq 0.18075E-08 -8.7429 0.18075E-08 -8.7429 0.10000E+01 0.0000 64 MnOH+ 0.47820E-09 -9.3204 0.39958E-09 -9.3984 0.83559E+00 -0.0780 65 MnO2-2 0.20310E-10 -10.6923 0.10464E-10 -10.9803 0.51522E+00 -0.2880 66 HMnO2- 0.20813E-09 -9.6817 0.17357E-09 -9.7605 0.83397E+00 -0.0789 69 MnCl+ 0.51200E-13 -13.2907 0.42783E-13 -13.3687 0.83559E+00 -0.0780 71 NaCl,aq 0.38951E-05 -5.4095 0.38951E-05 -5.4095 0.10000E+01 0.0000 72 NaOH,aq 0.96047E-04 -4.0175 0.96047E-04 -4.0175 0.10000E+01 0.0000 74 OH- 0.91673E-02 -2.0378 0.76312E-02 -2.1174 0.83244E+00 -0.0796 79 HPO3-2 0.15834E-14 -14.8004 0.81578E-15 -15.0884 0.51522E+00 -0.2880 81 H2PO3- 0.14851E-18 -18.8282 0.12386E-18 -18.9071 0.83397E+00 -0.0789 82 H3PO4,aq 0.90612E-18 -18.0428 0.90612E-18 -18.0428 0.10000E+01 0.0000 83 H2PO4- 0.37815E-10 -10.4223 0.31567E-10 -10.5008 0.83477E+00 -0.0784 84 PO4-3 0.10161E-08 -8.9930 0.24356E-09 -9.6134 0.23969E+00 -0.6204 88 HP2O7-3 0.90278E-18 -18.0444 0.20606E-18 -18.6860 0.22825E+00 -0.6416 89 P2O7-4 0.86271E-17 -17.0641 0.65018E-18 -18.1870 0.75365E-01 -1.1228 90 H2S,aq 0.30286E-07 -7.5188 0.30176E-07 -7.5203 0.99637E+00 -0.0016 91 S2-2 0.61751E-13 -13.2094 0.31815E-13 -13.4974 0.51522E+00 -0.2880 97 SO3-2 0.57447E-17 -17.2407 0.30033E-17 -17.5224 0.52280E+00 -0.2817 98 HSO3- 0.17072E-19 -19.7677 0.14237E-19 -19.8466 0.83397E+00 -0.0789 99 HSO4- 0.17407E-18 -18.7593 0.14560E-18 -18.8369 0.83642E+00 -0.0776 Charge balance for all species = 0.3163E-09 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.9023023E-10 -.2193266E-01 -.2206791E+02 0.0000 2 H2O 0.1000000E+01 0.5550497E+02 0.9981792E+06 0.0000 3 Cl- 0.8326741E-03 0.8365709E-03 0.2960676E+02 6.9625 4 SO4-- 0.3864567E-11 -.7805257E-04 -.7484662E+01 8.5417 5 HCO3- 0.1428009E-05 0.7924658E-04 0.4826896E+01 4.1974 6 HS- 0.1546095E-03 0.2326924E-03 0.7682061E+01 6.2313 7 Al+++ 0.1043506E-28 0.5216810E-05 0.1405097E+00 0.7390 8 H4SiO4 0.6959842E-03 0.1333795E-01 0.1279726E+04 -3.1574 9 Ca++ 0.1414103E-06 0.2413536E-06 0.9655948E-02 13.1018 10 Mg++ 0.2212437E-10 0.9581960E-10 0.2325467E-05 9.2942 11 Fe++ 0.6097797E-13 0.3561733E-07 0.1985621E-02 6.7350 12 K+ 0.1599588E-03 0.1607143E-03 0.6273191E+01 6.2467 13 Na+ 0.2029864E-01 0.2274823E-01 0.5220570E+03 8.3494 14 Mn++ 0.1957529E-10 0.2533729E-08 0.1389531E-03 9.2419 15 HPO4-- 0.4376597E-07 0.4481993E-07 0.4294202E-02 12.5958 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.1374356E+03 -.3617315E-02 -.1374320E+03 0.0000000E+00 2 H2O -.4853564E+02 0.9154338E+01 -.5768998E+02 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.2300468E+00 -.1287307E-04 0.2300596E+00 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.2300213E+00 0.3837754E-04 -.2300596E+00 0.0000000E+00 7 Al+++ 0.2706415E+02 0.8603994E-06 0.2706415E+02 0.0000000E+00 8 H4SiO4 0.8642609E+02 0.2199804E-02 0.8642389E+02 0.0000000E+00 9 Ca++ 0.9546197E+01 0.3980602E-07 0.9546197E+01 0.0000000E+00 10 Mg++ 0.6587301E+01 0.1580336E-10 0.6587301E+01 0.0000000E+00 11 Fe++ 0.5917971E+01 0.5874304E-08 0.5917971E+01 0.0000000E+00 12 K+ 0.1762208E+01 0.2650632E-04 0.1762181E+01 0.0000000E+00 13 Na+ 0.1041868E+02 0.3751826E-02 0.1041493E+02 0.0000000E+00 14 Mn++ 0.1439103E+00 0.4178835E-09 0.1439103E+00 0.0000000E+00 15 HPO4-- 0.4911588E-01 0.7392072E-08 0.4911587E-01 0.0000000E+00 Chg. balance for solid moles: -.5751E-13 Mass of aqueous solution: 0.165219E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 8299.9990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 10.41 1.017 2729. 3.436 30.09 1047. andradite 0.9202 -0.036 467.6 2.670 5.157 121.5 grossular 0.2228 -0.652 100.4 2.002 1.107 27.93 apatite-OH 0.1637E-01 -1.786 8.224 0.915 0.9070E-01 2.613 clinochlore 1.178 0.071 654.9 2.816 7.223 249.1 daphnite 0.3411 -0.467 243.4 2.386 2.684 73.75 chlorite-Mn 0.2878E-01 -1.541 20.41 1.310 0.2250 6.503 diopside 0.4422 -0.354 95.76 1.981 1.056 29.27 hedenbergite 0.1147 -0.941 28.45 1.454 0.3138 7.793 microcline 1.545 0.189 430.1 2.634 4.743 168.0 stilbite 5.338 0.727 3762. 3.575 41.49 1755. stilpnomelane-Fe 0.4340 -0.363 467.8 2.670 5.159 161.6 tr.625ac.25prg.125 0.7000E-01 -1.155 59.83 1.777 0.6598 19.26 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8051E+00 0.8051E+00 1.0000 -0.094 grossular 0.1949E+00 0.1949E+00 1.0000 -0.710 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.7611E+00 0.7611E+00 1.0000 -0.119 daphnite 0.2203E+00 0.2203E+00 1.0000 -0.657 chlorite-Mn 0.1859E-01 0.1859E-01 1.0000 -1.731 diopside 0.7941E+00 0.7941E+00 1.0000 -0.100 hedenbergite 0.2059E+00 0.2059E+00 1.0000 -0.686 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 tr.625ac.25prg.125 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 9067.609752 g Volume = 3669.478950 cm3 Porosity: -10.4932% V(tot) - V(min): -.34848E+03 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 8299.9990000 g log = 3.9191 Original solution: 1000.0103000 g Original solution / Rock added: 0.12 (Water/Rock Ratio), log = -0.9191 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.1461 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.8917E+00 0.9844 0.1006E+01 0.1022E+01 CO2,gas 0.1791E-07 1.0057 0.2064E-07 0.2053E-07 CH4,gas 0.9508E-01 1.0113 0.1102E+00 0.1090E+00 H2,gas 0.1326E-01 1.0006 0.1521E-01 0.1520E-01 H2S,gas 0.7270E-06 0.9955 0.8295E-06 0.8332E-06 S2,gas 0.9746E-28 1.0000 0.1117E-27 0.1117E-27 CO,gas 0.7300E-13 1.0000 0.8366E-13 0.8366E-13 SO3,gas 0.3774E-47 1.0000 0.4325E-47 0.4325E-47 SO2,gas 0.2232E-26 1.0000 0.2559E-26 0.2559E-26 HCl,gas 0.1483E-16 1.0000 0.1700E-16 0.1700E-16 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 16 albite -0.38 -0.38 0.00 0.000 0.11184E-10 22 andradite 39.01 39.01 0.00 0.000 0.12132E-10 23 grossular 32.73 32.73 0.00 0.000 0.00000E+00 32 apatite-OH -18.15 -18.15 0.00 0.000 0.00000E+00 46 clinochlore 39.07 39.07 0.00 0.000 0.00000E+00 47 daphnite 28.97 28.97 0.00 0.000 0.36397E-10 48 chlorite-Mn 46.87 46.87 0.00 0.000 0.12132E-10 67 diopside 16.18 16.18 0.00 0.000 0.60662E-11 68 hedenbergite 14.21 14.21 0.00 0.000 -0.60662E-11 116 microcline -2.49 -2.49 0.00 0.000 0.13649E-10 163 stilbite -7.52 -7.52 0.00 0.000 0.15165E-10 164 stilpnomelane-Fe 13.02 13.02 0.00 0.000 0.69761E-10 245 tr.625ac.25prg.125 45.16 45.16 0.00 0.000 0.00000E+00 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -16.04 -9.38 -3.128 0.16023E+05 -7.685 3 CH4,gas 4.54 1.89 -2.66 -0.664 0.45363E+04 -0.958 4 H2,gas 8.00 4.48 -3.52 -2.010 0.60051E+04 -1.818 5 H2S,gas -6.23 -14.01 -7.78 -3.890 0.13284E+05 -6.081 6 S2,gas -7.34 -36.99 -29.65 -4.562 0.50628E+05 -27.952 7 CO,gas 3.21 -11.56 -14.78 -4.547 0.25230E+05 -13.077 8 SO3,gas 17.12 -31.94 -49.06 -12.266 0.83774E+05 -47.364 9 SO2,gas 0.83 -27.46 -28.29 -7.544 0.48306E+05 -26.592 10 HCl,gas 5.19 -13.28 -18.47 -9.234 0.31534E+05 -16.770 11 acmite 7.71 6.53 -1.18 -0.123 0.20175E+04 15 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 19 spessartine 24.46 19.73 -4.73 -0.236 0.80695E+04 20 analcite 3.32 2.77 -0.55 -0.061 0.93626E+03 26 annite 20.12 17.72 -2.40 -0.134 0.41064E+04 27 phlogopite 27.06 25.40 -1.67 -0.093 0.28490E+04 29 anorthite 12.71 8.26 -4.45 -0.342 0.75903E+04 35 aragonite 0.97 -2.94 -3.91 -1.303 0.66745E+04 36 brucite 12.57 9.29 -3.27 -0.655 0.55909E+04 37 calcite 0.81 -2.94 -3.75 -1.251 0.64103E+04 38 carnegieite-low 9.02 5.93 -3.09 -0.442 0.52801E+04 39 carnegieite-high 10.09 5.93 -4.16 -0.595 0.71071E+04 40 carpholite-Mg 8.58 4.46 -4.12 -0.275 0.70429E+04 41 carpholite-Fe 6.71 1.90 -4.81 -0.321 0.82207E+04 42 celadonite 5.34 3.65 -1.69 -0.099 0.28879E+04 43 celadonite-Fe 3.88 1.09 -2.79 -0.164 0.47561E+04 44 chrysotile 23.89 21.57 -2.32 -0.194 0.39692E+04 49 chlorite-Al-free 47.17 43.14 -4.04 -0.168 0.68936E+04 51 chloritoid-Fe 9.17 5.06 -4.12 -0.275 0.70316E+04 52 chloritoid-Mn 11.40 7.56 -3.84 -0.256 0.65544E+04 54 coesite -2.38 -3.16 -0.78 -0.260 0.13341E+04 61 cristobalite -2.56 -3.16 -0.60 -0.199 0.10195E+04 63 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71234E+04 65 diaspore 2.87 0.74 -2.13 -0.356 0.36450E+04 66 diamond -3.10 -7.08 -3.98 -1.136 0.67894E+04 71 enstatite 17.26 12.27 -4.99 -0.499 0.85226E+04 73 clinoenstatite 17.17 12.27 -4.89 -0.489 0.83542E+04 75 epidote 24.67 22.70 -1.97 -0.095 0.33586E+04 76 clinozoisite 22.81 18.95 -3.86 -0.175 0.65869E+04 77 epidote-Fe 29.84 26.46 -3.38 -0.176 0.57768E+04 78 fayalite 14.05 10.31 -3.73 -0.533 0.63743E+04 79 ferrosilite 11.15 7.16 -3.99 -0.399 0.68202E+04 83 gibbsite 4.08 0.74 -3.34 -0.477 0.57036E+04 84 glaucophane 22.97 20.80 -2.17 -0.059 0.37134E+04 85 glaucophane-Fe 17.28 13.12 -4.15 -0.112 0.70919E+04 86 graphite -3.55 -7.08 -3.53 -1.009 0.60317E+04 87 greenalite 16.14 13.89 -2.25 -0.187 0.38408E+04 90 hematite 12.57 8.99 -3.58 -0.434 0.61111E+04 91 heulandite -5.83 -7.52 -1.69 -0.077 0.28938E+04 95 jadeite 4.22 2.77 -1.44 -0.144 0.24617E+04 97 kalsilite 7.58 3.83 -3.76 -0.537 0.64126E+04 98 kaolinite -1.33 -4.84 -3.50 -0.319 0.59832E+04 101 laumontite 2.88 1.95 -0.93 -0.062 0.15935E+04 102 lawsonite 9.62 8.26 -1.35 -0.090 0.23070E+04 103 leucite 4.12 0.67 -3.45 -0.345 0.58873E+04 105 lizardite 23.24 21.57 -1.68 -0.140 0.28619E+04 107 magnetite 20.09 15.72 -4.37 -0.356 0.74536E+04 108 minnesotaite 10.39 7.58 -2.81 -0.165 0.48027E+04 112 manganosite 14.06 9.24 -4.82 -1.204 0.82236E+04 120 muscovite 2.58 -1.01 -3.59 -0.211 0.61315E+04 121 paragonite 4.24 1.09 -3.15 -0.185 0.53706E+04 122 nepheline 8.34 5.93 -2.41 -0.344 0.41125E+04 128 periclase-Fe 11.63 6.73 -4.89 -1.223 0.83523E+04 134 phlogopite-Na 29.65 27.50 -2.15 -0.119 0.36678E+04 136 prehnite 19.37 18.21 -1.16 -0.068 0.19849E+04 137 prehnite-Fe 22.50 21.96 -0.53 -0.032 0.91159E+03 138 pumpellyite-Fe 46.27 43.89 -2.38 -0.053 0.40582E+04 139 pumpellyite-Mg 48.99 46.45 -2.54 -0.057 0.43421E+04 142 pyrite -21.25 -25.77 -4.52 -1.064 0.77206E+04 143 pyrrhotite -4.26 -7.28 -3.02 -1.005 0.51482E+04 144 pyrrhotiteFe0.875 -6.02 -8.67 -2.66 -0.977 0.45354E+04 145 pyroxmangite 7.40 6.08 -1.31 -0.263 0.22440E+04 146 pyrophyllite -6.18 -11.15 -4.98 -0.311 0.84962E+04 147 quartz -2.99 -3.16 -0.17 -0.056 0.28679E+03 152 rhodonite 7.45 6.08 -1.36 -0.272 0.23242E+04 153 sanidine -1.28 -2.49 -1.21 -0.093 0.20677E+04 165 stilpnomelane-Mg 27.44 25.81 -1.63 -0.049 0.27804E+04 171 talc 16.49 15.25 -1.24 -0.073 0.21140E+04 174 tephroite 18.09 15.33 -2.76 -0.394 0.47117E+04 178 tridymite -2.63 -3.16 -0.53 -0.177 0.90677E+03 179 tremolite 47.87 47.42 -0.45 -0.012 0.77494E+03 180 ferroactinolite 38.45 34.62 -3.83 -0.104 0.65448E+04 181 troilite-low -4.41 -7.28 -2.86 -0.955 0.48910E+04 183 vesuvianite 223.47 218.82 -4.65 -0.036 0.79441E+04 187 wairakite 3.95 1.95 -2.00 -0.118 0.34155E+04 188 walstromite 11.51 9.94 -1.56 -0.313 0.26719E+04 189 wollastonite 10.46 9.94 -0.52 -0.103 0.88229E+03 190 pseudo-wollastonite 11.00 9.94 -1.06 -0.211 0.18021E+04 191 zoisite 22.85 18.95 -3.90 -0.177 0.66610E+04 192 akaganeite 7.75 4.49 -3.26 -0.705 0.55681E+04 199 chalcedony -2.80 -3.16 -0.35 -0.118 0.60609E+03 201 montmorillonite-Ca -2.29 -6.17 -3.88 -0.240 0.66180E+04 202 montmorillonite-K -2.24 -6.27 -4.03 -0.247 0.68816E+04 203 montmorillonite-Mg -2.48 -6.79 -4.32 -0.267 0.73678E+04 204 montmorillonite-Na -2.04 -5.57 -3.54 -0.216 0.60365E+04 205 nontronite-Ca 3.21 -0.19 -3.41 -0.221 0.58215E+04 206 nontronite-H 2.53 -2.36 -4.89 -0.328 0.83485E+04 207 nontronite-K 3.34 -0.30 -3.64 -0.233 0.62083E+04 208 nontronite-Mg 3.07 -0.82 -3.90 -0.253 0.66553E+04 209 nontronite-Na 3.52 0.40 -3.12 -0.200 0.53291E+04 224 tobermorite 9.82 7.76 -2.07 -0.564 0.35287E+04 230 alabandite -0.98 -4.77 -3.79 -1.264 0.64724E+04 233 boehmite 4.41 0.74 -3.67 -0.611 0.62619E+04 235 ferrous-oxide 9.81 6.73 -3.08 -0.769 0.52532E+04 240 silica-amorphous -2.09 -3.16 -1.07 -0.355 0.18203E+04 242 an20ab80 2.02 1.35 -0.67 -0.052 0.11472E+04 243 an25ab75 2.65 1.78 -0.87 -0.067 0.14810E+04 244 an30ab70 3.28 2.21 -1.07 -0.082 0.18244E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 100.0000000 g Current total amount of reactant added: 8299.9990000 g New total amount of reactant added: 8399.9990000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.5209E-10 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 13 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 8399.9990000 Water: Moles liquid = 0.8597E+01 kg liquid = 0.1549E+00 Moles total = -.4979E+02 kg total = -.8970E+00 Activity = 1.0000 Stoichiometric ionic strength = .1194262E-01 Osmotic coef. = 0.9674 True ionic strength = .2049740E-01 Chg. balance for total moles = 0.5209E-10 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.90386E-10 -10.0439 0.75834E-10 -10.1201 0.83901E+00 -0.0762 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.88666E-03 -3.0522 0.73936E-03 -3.1311 0.83387E+00 -0.0789 4 SO4-- 0.41099E-11 -11.3862 0.21211E-11 -11.6734 0.51610E+00 -0.2873 5 HCO3- 0.15185E-05 -5.8186 0.12681E-05 -5.8968 0.83511E+00 -0.0783 6 HS- 0.16463E-03 -3.7835 0.13730E-03 -3.8623 0.83399E+00 -0.0788 7 Al+++ 0.10497E-28 -28.9790 0.23909E-29 -29.6214 0.22778E+00 -0.6425 8 H4SiO4 0.69598E-03 -3.1574 0.69598E-03 -3.1574 0.10000E+01 0.0000 9 Ca++ 0.14193E-06 -6.8479 0.72704E-07 -7.1384 0.51224E+00 -0.2905 10 Mg++ 0.22206E-10 -10.6535 0.11322E-10 -10.9461 0.50985E+00 -0.2926 11 Fe++ 0.61204E-13 -13.2132 0.31240E-13 -13.5053 0.51042E+00 -0.2921 12 K+ 0.16024E-03 -3.7952 0.13385E-03 -3.8734 0.83531E+00 -0.0782 13 Na+ 0.20334E-01 -1.6918 0.16953E-01 -1.7708 0.83371E+00 -0.0790 14 Mn++ 0.19648E-10 -10.7067 0.10037E-10 -10.9984 0.51085E+00 -0.2917 15 HPO4-- 0.43645E-07 -7.3601 0.22528E-07 -7.6473 0.51617E+00 -0.2872 16 HSiO3- 0.10277E-01 -1.9881 0.85696E-02 -2.0670 0.83387E+00 -0.0789 17 Ca(HSiO3)+ 0.16983E-07 -7.7700 0.14189E-07 -7.8480 0.83550E+00 -0.0781 18 Mg(HSiO3)+ 0.32913E-11 -11.4826 0.27499E-11 -11.5607 0.83550E+00 -0.0781 19 NaHSiO3,aq 0.23497E-02 -2.6290 0.23497E-02 -2.6290 0.10000E+01 0.0000 20 AlO+ 0.67695E-16 -16.1694 0.56559E-16 -16.2475 0.83550E+00 -0.0781 22 HAlO2,aq 0.14853E-09 -9.8282 0.14853E-09 -9.8282 0.10000E+01 0.0000 23 AlO2- 0.52089E-05 -5.2833 0.43355E-05 -5.3630 0.83234E+00 -0.0797 24 CH4,aq 0.80029E-04 -4.0968 0.79737E-04 -4.0983 0.99636E+00 -0.0016 25 C2H6,aq 0.94188E-13 -13.0260 0.93845E-13 -13.0276 0.99636E+00 -0.0016 29 CO,aq 0.59787E-16 -16.2234 0.59787E-16 -16.2234 0.10000E+01 0.0000 30 CO2,aq 0.20624E-09 -9.6856 0.20548E-09 -9.6872 0.99636E+00 -0.0016 31 CO3-2 0.28362E-05 -5.5473 0.14606E-05 -5.8355 0.51498E+00 -0.2882 32 CaCO3,aq 0.13315E-08 -8.8757 0.13315E-08 -8.8757 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.28168E-11 -11.5502 0.23534E-11 -11.6283 0.83550E+00 -0.0781 34 CaCl+ 0.10412E-09 -9.9825 0.86991E-10 -10.0605 0.83550E+00 -0.0781 35 CaCl2,aq 0.15280E-13 -13.8159 0.15280E-13 -13.8159 0.10000E+01 0.0000 36 CaOH+ 0.81780E-07 -7.0874 0.68327E-07 -7.1654 0.83550E+00 -0.0781 37 CaSO4,aq 0.48970E-16 -16.3101 0.48970E-16 -16.3101 0.10000E+01 0.0000 38 HCl,aq 0.10274E-13 -13.9882 0.10274E-13 -13.9882 0.10000E+01 0.0000 43 FeCl+ 0.43757E-16 -16.3590 0.36559E-16 -16.4370 0.83550E+00 -0.0781 46 FeO,aq 0.21112E-09 -9.6755 0.21112E-09 -9.6755 0.10000E+01 0.0000 47 FeOH+ 0.16049E-10 -10.7945 0.13409E-10 -10.8726 0.83550E+00 -0.0781 48 HFeO2- 0.34933E-07 -7.4568 0.29130E-07 -7.5357 0.83387E+00 -0.0789 49 FeO+ 0.11248E-16 -16.9489 0.93979E-17 -17.0270 0.83550E+00 -0.0781 51 FeO2- 0.40101E-09 -9.3968 0.33439E-09 -9.4757 0.83387E+00 -0.0789 52 HFeO2,aq 0.32252E-11 -11.4914 0.32252E-11 -11.4914 0.10000E+01 0.0000 53 H2,aq 0.11625E-04 -4.9346 0.11582E-04 -4.9362 0.99636E+00 -0.0016 54 KCl,aq 0.17936E-08 -8.7463 0.17936E-08 -8.7463 0.10000E+01 0.0000 56 KOH,aq 0.75375E-06 -6.1228 0.75375E-06 -6.1228 0.10000E+01 0.0000 57 KSO4- 0.52832E-14 -14.2771 0.44055E-14 -14.3560 0.83387E+00 -0.0789 58 MgCO3,aq 0.51975E-13 -13.2842 0.51975E-13 -13.2842 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.44822E-15 -15.3485 0.37448E-15 -15.4266 0.83550E+00 -0.0781 60 MgCl+ 0.14696E-13 -13.8328 0.12278E-13 -13.9109 0.83550E+00 -0.0781 61 MgOH+ 0.70471E-10 -10.1520 0.58879E-10 -10.2300 0.83550E+00 -0.0781 63 MnO,aq 0.18075E-08 -8.7429 0.18075E-08 -8.7429 0.10000E+01 0.0000 64 MnOH+ 0.47904E-09 -9.3196 0.40023E-09 -9.3977 0.83550E+00 -0.0781 65 MnO2-2 0.20254E-10 -10.6935 0.10431E-10 -10.9817 0.51498E+00 -0.2882 66 HMnO2- 0.20782E-09 -9.6823 0.17330E-09 -9.7612 0.83387E+00 -0.0789 69 MnCl+ 0.54696E-13 -13.2620 0.45698E-13 -13.3401 0.83550E+00 -0.0781 71 NaCl,aq 0.41538E-05 -5.3816 0.41538E-05 -5.3816 0.10000E+01 0.0000 72 NaOH,aq 0.96047E-04 -4.0175 0.96047E-04 -4.0175 0.10000E+01 0.0000 74 OH- 0.91536E-02 -2.0384 0.76189E-02 -2.1181 0.83234E+00 -0.0797 79 HPO3-2 0.15790E-14 -14.8016 0.81315E-15 -15.0898 0.51498E+00 -0.2882 81 H2PO3- 0.14829E-18 -18.8289 0.12366E-18 -18.9078 0.83387E+00 -0.0789 82 H3PO4,aq 0.90612E-18 -18.0428 0.90612E-18 -18.0428 0.10000E+01 0.0000 83 H2PO4- 0.37758E-10 -10.4230 0.31516E-10 -10.5015 0.83467E+00 -0.0785 84 PO4-3 0.10122E-08 -8.9947 0.24238E-09 -9.6155 0.23945E+00 -0.6208 88 HP2O7-3 0.89937E-18 -18.0461 0.20507E-18 -18.6881 0.22801E+00 -0.6420 89 P2O7-4 0.85873E-17 -17.0661 0.64601E-18 -18.1898 0.75229E-01 -1.1236 90 H2S,aq 0.32298E-07 -7.4908 0.32181E-07 -7.4924 0.99636E+00 -0.0016 91 S2-2 0.70034E-13 -13.1547 0.36066E-13 -13.4429 0.51498E+00 -0.2882 97 SO3-2 0.61093E-17 -17.2140 0.31925E-17 -17.4959 0.52257E+00 -0.2819 98 HSO3- 0.18179E-19 -19.7404 0.15159E-19 -19.8193 0.83387E+00 -0.0789 99 HSO4- 0.18536E-18 -18.7320 0.15502E-18 -18.8096 0.83632E+00 -0.0776 Charge balance for all species = 0.3366E-09 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.9038558E-10 -.2190377E-01 -.2203880E+02 0.0000 2 H2O 0.1000000E+01 0.5550498E+02 0.9981776E+06 0.0000 3 Cl- 0.8866577E-03 0.8908134E-03 0.3152638E+02 6.9890 4 SO4-- 0.4109915E-11 -.8293468E-04 -.7952806E+01 8.5668 5 HCO3- 0.1518491E-05 0.8438485E-04 0.5139858E+01 4.2233 6 HS- 0.1646342E-03 0.2476012E-03 0.8174243E+01 6.2578 7 Al+++ 0.1049659E-28 0.5209034E-05 0.1403000E+00 0.7390 8 H4SiO4 0.6959842E-03 0.1332258E-01 0.1278250E+04 -3.1574 9 Ca++ 0.1419330E-06 0.2421346E-06 0.9687178E-02 13.1018 10 Mg++ 0.2220629E-10 0.9603425E-10 0.2330672E-05 9.2942 11 Fe++ 0.6120366E-13 0.3556453E-07 0.1982674E-02 6.7350 12 K+ 0.1602352E-03 0.1609907E-03 0.6283971E+01 6.2467 13 Na+ 0.2033376E-01 0.2278361E-01 0.5228680E+03 8.3494 14 Mn++ 0.1964797E-10 0.2534296E-08 0.1389839E-03 9.2419 15 HPO4-- 0.4364508E-07 0.4469508E-07 0.4282233E-02 12.5930 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.1390915E+03 -.3392578E-02 -.1390881E+03 0.0000000E+00 2 H2O -.4978918E+02 0.8596923E+01 -.5838611E+02 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.2328181E+00 -.1284539E-04 0.2328310E+00 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.2327926E+00 0.3834986E-04 -.2328310E+00 0.0000000E+00 7 Al+++ 0.2739023E+02 0.8068045E-06 0.2739023E+02 0.0000000E+00 8 H4SiO4 0.8746737E+02 0.2063476E-02 0.8746530E+02 0.0000000E+00 9 Ca++ 0.9661212E+01 0.3750317E-07 0.9661212E+01 0.0000000E+00 10 Mg++ 0.6666666E+01 0.1487432E-10 0.6666666E+01 0.0000000E+00 11 Fe++ 0.5989271E+01 0.5508435E-08 0.5989271E+01 0.0000000E+00 12 K+ 0.1783439E+01 0.2493514E-04 0.1783414E+01 0.0000000E+00 13 Na+ 0.1054421E+02 0.3528853E-02 0.1054068E+02 0.0000000E+00 14 Mn++ 0.1456442E+00 0.3925260E-09 0.1456442E+00 0.0000000E+00 15 HPO4-- 0.4970764E-01 0.6922625E-08 0.4970763E-01 0.0000000E+00 Chg. balance for solid moles: -.1527E-14 Mass of aqueous solution: 0.155159E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 8399.9990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 10.53 1.023 2762. 3.441 30.09 1060. andradite 0.9313 -0.031 473.3 2.675 5.157 123.0 grossular 0.2255 -0.647 101.6 2.007 1.107 28.26 apatite-OH 0.1657E-01 -1.781 8.323 0.920 0.9070E-01 2.645 clinochlore 1.192 0.076 662.8 2.821 7.223 252.1 daphnite 0.3452 -0.462 246.3 2.391 2.684 74.64 chlorite-Mn 0.2913E-01 -1.536 20.65 1.315 0.2250 6.581 diopside 0.4476 -0.349 96.94 1.986 1.056 29.63 hedenbergite 0.1161 -0.935 28.80 1.459 0.3138 7.888 microcline 1.564 0.194 435.3 2.639 4.743 170.0 stilbite 5.403 0.733 3807. 3.581 41.49 1776. stilpnomelane-Fe 0.4392 -0.357 473.4 2.675 5.159 163.5 tr.625ac.25prg.125 0.7083E-01 -1.150 60.54 1.782 0.6597 19.49 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8051E+00 0.8051E+00 1.0000 -0.094 grossular 0.1949E+00 0.1949E+00 1.0000 -0.710 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.7611E+00 0.7611E+00 1.0000 -0.119 daphnite 0.2203E+00 0.2203E+00 1.0000 -0.657 chlorite-Mn 0.1859E-01 0.1859E-01 1.0000 -1.731 diopside 0.7941E+00 0.7941E+00 1.0000 -0.100 hedenbergite 0.2059E+00 0.2059E+00 1.0000 -0.686 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 tr.625ac.25prg.125 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 9176.860411 g Volume = 3713.682012 cm3 Porosity: -10.4934% V(tot) - V(min): -.35268E+03 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 8399.9990000 g log = 3.9243 Original solution: 1000.0103000 g Original solution / Rock added: 0.12 (Water/Rock Ratio), log = -0.9243 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.1533 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.8862E+00 0.9843 0.1006E+01 0.1022E+01 CO2,gas 0.1896E-07 1.0056 0.2198E-07 0.2186E-07 CH4,gas 0.1006E+00 1.0113 0.1174E+00 0.1161E+00 H2,gas 0.1318E-01 1.0006 0.1521E-01 0.1520E-01 H2S,gas 0.7705E-06 0.9955 0.8846E-06 0.8886E-06 S2,gas 0.1102E-27 1.0000 0.1270E-27 0.1270E-27 CO,gas 0.7725E-13 1.0000 0.8909E-13 0.8909E-13 SO3,gas 0.3999E-47 1.0000 0.4612E-47 0.4612E-47 SO2,gas 0.2366E-26 1.0000 0.2729E-26 0.2729E-26 HCl,gas 0.1572E-16 1.0000 0.1813E-16 0.1813E-16 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 16 albite -0.38 -0.38 0.00 0.000 -0.94784E-12 22 andradite 39.01 39.01 0.00 0.000 0.12132E-10 23 grossular 32.73 32.73 0.00 0.000 0.24265E-10 32 apatite-OH -18.15 -18.15 0.00 0.000 -0.60662E-11 46 clinochlore 39.07 39.07 0.00 0.000 0.00000E+00 47 daphnite 28.97 28.97 0.00 0.000 -0.18198E-10 48 chlorite-Mn 46.87 46.87 0.00 0.000 0.00000E+00 67 diopside 16.18 16.18 0.00 0.000 0.00000E+00 68 hedenbergite 14.21 14.21 0.00 0.000 0.30331E-11 116 microcline -2.49 -2.49 0.00 0.000 0.13649E-10 163 stilbite -7.52 -7.52 0.00 0.000 0.39430E-10 164 stilpnomelane-Fe 13.02 13.02 0.00 0.000 0.69761E-10 245 tr.625ac.25prg.125 45.16 45.16 0.00 0.000 0.24265E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -16.02 -9.36 -3.119 0.15977E+05 -7.658 3 CH4,gas 4.54 1.91 -2.63 -0.657 0.44897E+04 -0.930 4 H2,gas 8.00 4.48 -3.52 -2.010 0.60051E+04 -1.818 5 H2S,gas -6.23 -13.98 -7.75 -3.876 0.13237E+05 -6.053 6 S2,gas -7.34 -36.93 -29.60 -4.553 0.50533E+05 -27.896 7 CO,gas 3.21 -11.53 -14.75 -4.538 0.25184E+05 -13.050 8 SO3,gas 17.12 -31.91 -49.04 -12.259 0.83726E+05 -47.336 9 SO2,gas 0.83 -27.43 -28.26 -7.537 0.48258E+05 -26.564 10 HCl,gas 5.19 -13.25 -18.44 -9.220 0.31487E+05 -16.742 11 acmite 7.71 6.53 -1.18 -0.123 0.20175E+04 15 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 19 spessartine 24.46 19.73 -4.73 -0.236 0.80695E+04 20 analcite 3.32 2.77 -0.55 -0.061 0.93626E+03 26 annite 20.12 17.72 -2.40 -0.134 0.41064E+04 27 phlogopite 27.06 25.40 -1.67 -0.093 0.28490E+04 29 anorthite 12.71 8.26 -4.45 -0.342 0.75903E+04 35 aragonite 0.97 -2.92 -3.88 -1.294 0.66278E+04 36 brucite 12.57 9.29 -3.27 -0.655 0.55909E+04 37 calcite 0.81 -2.92 -3.73 -1.242 0.63636E+04 38 carnegieite-low 9.02 5.93 -3.09 -0.442 0.52801E+04 39 carnegieite-high 10.09 5.93 -4.16 -0.595 0.71071E+04 40 carpholite-Mg 8.58 4.46 -4.12 -0.275 0.70429E+04 41 carpholite-Fe 6.71 1.90 -4.81 -0.321 0.82207E+04 42 celadonite 5.34 3.65 -1.69 -0.099 0.28879E+04 43 celadonite-Fe 3.88 1.09 -2.79 -0.164 0.47561E+04 44 chrysotile 23.89 21.57 -2.32 -0.194 0.39692E+04 49 chlorite-Al-free 47.17 43.14 -4.04 -0.168 0.68936E+04 51 chloritoid-Fe 9.17 5.06 -4.12 -0.275 0.70316E+04 52 chloritoid-Mn 11.40 7.56 -3.84 -0.256 0.65544E+04 54 coesite -2.38 -3.16 -0.78 -0.260 0.13341E+04 61 cristobalite -2.56 -3.16 -0.60 -0.199 0.10195E+04 63 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71234E+04 65 diaspore 2.87 0.74 -2.13 -0.356 0.36450E+04 66 diamond -3.10 -7.05 -3.95 -1.128 0.67427E+04 71 enstatite 17.26 12.27 -4.99 -0.499 0.85226E+04 73 clinoenstatite 17.17 12.27 -4.89 -0.489 0.83542E+04 75 epidote 24.67 22.70 -1.97 -0.095 0.33586E+04 76 clinozoisite 22.81 18.95 -3.86 -0.175 0.65869E+04 77 epidote-Fe 29.84 26.46 -3.38 -0.176 0.57768E+04 78 fayalite 14.05 10.31 -3.73 -0.533 0.63743E+04 79 ferrosilite 11.15 7.16 -3.99 -0.399 0.68202E+04 83 gibbsite 4.08 0.74 -3.34 -0.477 0.57036E+04 84 glaucophane 22.97 20.80 -2.17 -0.059 0.37134E+04 85 glaucophane-Fe 17.28 13.12 -4.15 -0.112 0.70919E+04 86 graphite -3.55 -7.05 -3.51 -1.001 0.59850E+04 87 greenalite 16.14 13.89 -2.25 -0.187 0.38408E+04 90 hematite 12.57 8.99 -3.58 -0.434 0.61111E+04 91 heulandite -5.83 -7.52 -1.69 -0.077 0.28938E+04 95 jadeite 4.22 2.77 -1.44 -0.144 0.24617E+04 97 kalsilite 7.58 3.83 -3.76 -0.537 0.64126E+04 98 kaolinite -1.33 -4.84 -3.50 -0.319 0.59832E+04 101 laumontite 2.88 1.95 -0.93 -0.062 0.15935E+04 102 lawsonite 9.62 8.26 -1.35 -0.090 0.23070E+04 103 leucite 4.12 0.67 -3.45 -0.345 0.58873E+04 105 lizardite 23.24 21.57 -1.68 -0.140 0.28619E+04 107 magnetite 20.09 15.72 -4.37 -0.356 0.74536E+04 108 minnesotaite 10.39 7.58 -2.81 -0.165 0.48027E+04 112 manganosite 14.06 9.24 -4.82 -1.204 0.82236E+04 120 muscovite 2.58 -1.01 -3.59 -0.211 0.61315E+04 121 paragonite 4.24 1.09 -3.15 -0.185 0.53706E+04 122 nepheline 8.34 5.93 -2.41 -0.344 0.41125E+04 128 periclase-Fe 11.63 6.73 -4.89 -1.223 0.83523E+04 134 phlogopite-Na 29.65 27.50 -2.15 -0.119 0.36678E+04 136 prehnite 19.37 18.21 -1.16 -0.068 0.19849E+04 137 prehnite-Fe 22.50 21.96 -0.53 -0.032 0.91159E+03 138 pumpellyite-Fe 46.27 43.89 -2.38 -0.053 0.40582E+04 139 pumpellyite-Mg 48.99 46.45 -2.54 -0.057 0.43421E+04 142 pyrite -21.25 -25.71 -4.47 -1.051 0.76252E+04 143 pyrrhotite -4.26 -7.25 -2.99 -0.996 0.51005E+04 144 pyrrhotiteFe0.875 -6.02 -8.65 -2.63 -0.967 0.44877E+04 145 pyroxmangite 7.40 6.08 -1.31 -0.263 0.22440E+04 146 pyrophyllite -6.18 -11.15 -4.98 -0.311 0.84962E+04 147 quartz -2.99 -3.16 -0.17 -0.056 0.28679E+03 152 rhodonite 7.45 6.08 -1.36 -0.272 0.23242E+04 153 sanidine -1.28 -2.49 -1.21 -0.093 0.20677E+04 165 stilpnomelane-Mg 27.44 25.81 -1.63 -0.049 0.27804E+04 171 talc 16.49 15.25 -1.24 -0.073 0.21140E+04 174 tephroite 18.09 15.33 -2.76 -0.394 0.47116E+04 178 tridymite -2.63 -3.16 -0.53 -0.177 0.90677E+03 179 tremolite 47.87 47.42 -0.45 -0.012 0.77494E+03 180 ferroactinolite 38.45 34.62 -3.83 -0.104 0.65448E+04 181 troilite-low -4.41 -7.25 -2.84 -0.946 0.48433E+04 183 vesuvianite 223.47 218.82 -4.65 -0.036 0.79441E+04 187 wairakite 3.95 1.95 -2.00 -0.118 0.34155E+04 188 walstromite 11.51 9.94 -1.56 -0.313 0.26719E+04 189 wollastonite 10.46 9.94 -0.52 -0.103 0.88229E+03 190 pseudo-wollastonite 11.00 9.94 -1.06 -0.211 0.18021E+04 191 zoisite 22.85 18.95 -3.90 -0.177 0.66610E+04 192 akaganeite 7.75 4.49 -3.26 -0.705 0.55681E+04 199 chalcedony -2.80 -3.16 -0.35 -0.118 0.60609E+03 201 montmorillonite-Ca -2.29 -6.17 -3.88 -0.240 0.66180E+04 202 montmorillonite-K -2.24 -6.27 -4.03 -0.247 0.68816E+04 203 montmorillonite-Mg -2.48 -6.79 -4.32 -0.267 0.73678E+04 204 montmorillonite-Na -2.04 -5.57 -3.54 -0.216 0.60365E+04 205 nontronite-Ca 3.21 -0.19 -3.41 -0.221 0.58215E+04 206 nontronite-H 2.53 -2.36 -4.89 -0.328 0.83484E+04 207 nontronite-K 3.34 -0.30 -3.64 -0.233 0.62083E+04 208 nontronite-Mg 3.07 -0.82 -3.90 -0.253 0.66553E+04 209 nontronite-Na 3.52 0.40 -3.12 -0.200 0.53291E+04 224 tobermorite 9.82 7.76 -2.07 -0.564 0.35287E+04 230 alabandite -0.98 -4.74 -3.76 -1.254 0.64247E+04 233 boehmite 4.41 0.74 -3.67 -0.611 0.62619E+04 235 ferrous-oxide 9.81 6.73 -3.08 -0.769 0.52532E+04 240 silica-amorphous -2.09 -3.16 -1.07 -0.355 0.18203E+04 242 an20ab80 2.02 1.35 -0.67 -0.052 0.11472E+04 243 an25ab75 2.65 1.78 -0.87 -0.067 0.14810E+04 244 an30ab70 3.28 2.21 -1.07 -0.082 0.18244E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 100.0000000 g Current total amount of reactant added: 8399.9990000 g New total amount of reactant added: 8499.9990000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.5212E-10 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 13 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 8499.9990000 Water: Moles liquid = 0.8040E+01 kg liquid = 0.1448E+00 Moles total = -.5104E+02 kg total = -.9196E+00 Activity = 1.0000 Stoichiometric ionic strength = .1199409E-01 Osmotic coef. = 0.9673 True ionic strength = .2053796E-01 Chg. balance for total moles = 0.5212E-10 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.90563E-10 -10.0431 0.75973E-10 -10.1193 0.83890E+00 -0.0763 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.94813E-03 -3.0231 0.79051E-03 -3.1021 0.83376E+00 -0.0790 4 SO4-- 0.43885E-11 -11.3577 0.22637E-11 -11.6452 0.51583E+00 -0.2875 5 HCO3- 0.16212E-05 -5.7902 0.13537E-05 -5.8685 0.83500E+00 -0.0783 6 HS- 0.17605E-03 -3.7544 0.14680E-03 -3.8333 0.83388E+00 -0.0789 7 Al+++ 0.10567E-28 -28.9760 0.24041E-29 -29.6191 0.22751E+00 -0.6430 8 H4SiO4 0.69598E-03 -3.1574 0.69598E-03 -3.1574 0.10000E+01 0.0000 9 Ca++ 0.14253E-06 -6.8461 0.72971E-07 -7.1369 0.51197E+00 -0.2908 10 Mg++ 0.22300E-10 -10.6517 0.11364E-10 -10.9445 0.50958E+00 -0.2928 11 Fe++ 0.61462E-13 -13.2114 0.31354E-13 -13.5037 0.51015E+00 -0.2923 12 K+ 0.16055E-03 -3.7944 0.13409E-03 -3.8726 0.83520E+00 -0.0782 13 Na+ 0.20374E-01 -1.6909 0.16984E-01 -1.7700 0.83360E+00 -0.0790 14 Mn++ 0.19731E-10 -10.7049 0.10074E-10 -10.9968 0.51058E+00 -0.2919 15 HPO4-- 0.43508E-07 -7.3614 0.22446E-07 -7.6489 0.51591E+00 -0.2874 16 HSiO3- 0.10259E-01 -1.9889 0.85539E-02 -2.0678 0.83376E+00 -0.0790 17 Ca(HSiO3)+ 0.17016E-07 -7.7691 0.14215E-07 -7.8473 0.83539E+00 -0.0781 18 Mg(HSiO3)+ 0.32978E-11 -11.4818 0.27549E-11 -11.5599 0.83539E+00 -0.0781 19 NaHSiO3,aq 0.23497E-02 -2.6290 0.23497E-02 -2.6290 0.10000E+01 0.0000 20 AlO+ 0.67828E-16 -16.1686 0.56663E-16 -16.2467 0.83539E+00 -0.0781 22 HAlO2,aq 0.14853E-09 -9.8282 0.14853E-09 -9.8282 0.10000E+01 0.0000 23 AlO2- 0.52000E-05 -5.2840 0.43276E-05 -5.3638 0.83222E+00 -0.0798 24 CH4,aq 0.85589E-04 -4.0676 0.85276E-04 -4.0692 0.99635E+00 -0.0016 25 C2H6,aq 0.10773E-12 -12.9677 0.10734E-12 -12.9693 0.99635E+00 -0.0016 29 CO,aq 0.63940E-16 -16.1942 0.63940E-16 -16.1942 0.10000E+01 0.0000 30 CO2,aq 0.22056E-09 -9.6565 0.21976E-09 -9.6581 0.99635E+00 -0.0016 31 CO3-2 0.30237E-05 -5.5195 0.15564E-05 -5.8079 0.51471E+00 -0.2884 32 CaCO3,aq 0.14240E-08 -8.8465 0.14240E-08 -8.8465 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.30184E-11 -11.5202 0.25215E-11 -11.5983 0.83539E+00 -0.0781 34 CaCl+ 0.11175E-09 -9.9518 0.93351E-10 -10.0299 0.83539E+00 -0.0781 35 CaCl2,aq 0.17532E-13 -13.7562 0.17532E-13 -13.7562 0.10000E+01 0.0000 36 CaOH+ 0.81941E-07 -7.0865 0.68453E-07 -7.1646 0.83539E+00 -0.0781 37 CaSO4,aq 0.52454E-16 -16.2802 0.52454E-16 -16.2802 0.10000E+01 0.0000 38 HCl,aq 0.11005E-13 -13.9584 0.11005E-13 -13.9584 0.10000E+01 0.0000 43 FeCl+ 0.46963E-16 -16.3282 0.39232E-16 -16.4064 0.83539E+00 -0.0781 46 FeO,aq 0.21112E-09 -9.6755 0.21112E-09 -9.6755 0.10000E+01 0.0000 47 FeOH+ 0.16081E-10 -10.7937 0.13434E-10 -10.8718 0.83539E+00 -0.0781 48 HFeO2- 0.34874E-07 -7.4575 0.29076E-07 -7.5365 0.83376E+00 -0.0790 49 FeO+ 0.11270E-16 -16.9481 0.94152E-17 -17.0262 0.83539E+00 -0.0781 51 FeO2- 0.40033E-09 -9.3976 0.33377E-09 -9.4765 0.83376E+00 -0.0790 52 HFeO2,aq 0.32252E-11 -11.4914 0.32252E-11 -11.4914 0.10000E+01 0.0000 53 H2,aq 0.11625E-04 -4.9346 0.11582E-04 -4.9362 0.99635E+00 -0.0016 54 KCl,aq 0.19212E-08 -8.7164 0.19212E-08 -8.7164 0.10000E+01 0.0000 56 KOH,aq 0.75375E-06 -6.1228 0.75375E-06 -6.1228 0.10000E+01 0.0000 57 KSO4- 0.56495E-14 -14.2480 0.47103E-14 -14.3269 0.83376E+00 -0.0790 58 MgCO3,aq 0.55585E-13 -13.2550 0.55585E-13 -13.2550 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.48029E-15 -15.3185 0.40123E-15 -15.3966 0.83539E+00 -0.0781 60 MgCl+ 0.15772E-13 -13.8021 0.13176E-13 -13.8802 0.83539E+00 -0.0781 61 MgOH+ 0.70610E-10 -10.1511 0.58987E-10 -10.2292 0.83539E+00 -0.0781 63 MnO,aq 0.18075E-08 -8.7429 0.18075E-08 -8.7429 0.10000E+01 0.0000 64 MnOH+ 0.47998E-09 -9.3188 0.40097E-09 -9.3969 0.83539E+00 -0.0781 65 MnO2-2 0.20191E-10 -10.6948 0.10393E-10 -10.9833 0.51471E+00 -0.2884 66 HMnO2- 0.20747E-09 -9.6830 0.17298E-09 -9.7620 0.83376E+00 -0.0790 69 MnCl+ 0.58704E-13 -13.2313 0.49040E-13 -13.3094 0.83539E+00 -0.0781 71 NaCl,aq 0.44493E-05 -5.3517 0.44493E-05 -5.3517 0.10000E+01 0.0000 72 NaOH,aq 0.96047E-04 -4.0175 0.96047E-04 -4.0175 0.10000E+01 0.0000 74 OH- 0.91381E-02 -2.0391 0.76049E-02 -2.1189 0.83222E+00 -0.0798 79 HPO3-2 0.15740E-14 -14.8030 0.81018E-15 -15.0914 0.51471E+00 -0.2884 81 H2PO3- 0.14804E-18 -18.8296 0.12343E-18 -18.9086 0.83376E+00 -0.0790 82 H3PO4,aq 0.90612E-18 -18.0428 0.90612E-18 -18.0428 0.10000E+01 0.0000 83 H2PO4- 0.37694E-10 -10.4237 0.31458E-10 -10.5023 0.83456E+00 -0.0785 84 PO4-3 0.10078E-08 -8.9966 0.24105E-09 -9.6179 0.23919E+00 -0.6213 88 HP2O7-3 0.89550E-18 -18.0479 0.20394E-18 -18.6905 0.22774E+00 -0.6426 89 P2O7-4 0.85422E-17 -17.0684 0.64128E-18 -18.1929 0.75073E-01 -1.1245 90 H2S,aq 0.34597E-07 -7.4610 0.34470E-07 -7.4626 0.99635E+00 -0.0016 91 S2-2 0.80103E-13 -13.0964 0.41230E-13 -13.3848 0.51471E+00 -0.2884 97 SO3-2 0.65233E-17 -17.1855 0.34072E-17 -17.4676 0.52231E+00 -0.2821 98 HSO3- 0.19439E-19 -19.7113 0.16208E-19 -19.7903 0.83376E+00 -0.0790 99 HSO4- 0.19821E-18 -18.7029 0.16574E-18 -18.7806 0.83622E+00 -0.0777 Charge balance for all species = 0.3598E-09 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.9056275E-10 -.2187093E-01 -.2200572E+02 0.0000 2 H2O 0.1000000E+01 0.5550498E+02 0.9981757E+06 0.0000 3 Cl- 0.9481262E-03 0.9525776E-03 0.3371218E+02 7.0172 4 SO4-- 0.4388520E-11 -.8849519E-04 -.8486000E+01 8.5935 5 HCO3- 0.1621212E-05 0.9023564E-04 0.5496218E+01 4.2509 6 HS- 0.1760490E-03 0.2645788E-03 0.8734720E+01 6.2861 7 Al+++ 0.1056708E-28 0.5200198E-05 0.1400617E+00 0.7390 8 H4SiO4 0.6959842E-03 0.1330512E-01 0.1276572E+04 -3.1574 9 Ca++ 0.1425304E-06 0.2430265E-06 0.9722841E-02 13.1018 10 Mg++ 0.2229991E-10 0.9628480E-10 0.2336748E-05 9.2942 11 Fe++ 0.6146159E-13 0.3550453E-07 0.1979325E-02 6.7350 12 K+ 0.1605503E-03 0.1613060E-03 0.6296264E+01 6.2467 13 Na+ 0.2037381E-01 0.2282395E-01 0.5237929E+03 8.3494 14 Mn++ 0.1973100E-10 0.2534940E-08 0.1390190E-03 9.2419 15 HPO4-- 0.4350791E-07 0.4455340E-07 0.4268651E-02 12.5898 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.1407474E+03 -.3167851E-02 -.1407442E+03 0.0000000E+00 2 H2O -.5104272E+02 0.8039508E+01 -.5908223E+02 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.2355895E+00 -.1281791E-04 0.2356023E+00 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.2355639E+00 0.3832238E-04 -.2356023E+00 0.0000000E+00 7 Al+++ 0.2771630E+02 0.7532123E-06 0.2771630E+02 0.0000000E+00 8 H4SiO4 0.8850864E+02 0.1927154E-02 0.8850672E+02 0.0000000E+00 9 Ca++ 0.9776226E+01 0.3520068E-07 0.9776226E+01 0.0000000E+00 10 Mg++ 0.6746031E+01 0.1394618E-10 0.6746031E+01 0.0000000E+00 11 Fe++ 0.6060572E+01 0.5142582E-08 0.6060572E+01 0.0000000E+00 12 K+ 0.1804671E+01 0.2336404E-04 0.1804647E+01 0.0000000E+00 13 Na+ 0.1066973E+02 0.3305890E-02 0.1066642E+02 0.0000000E+00 14 Mn++ 0.1473780E+00 0.3671683E-09 0.1473780E+00 0.0000000E+00 15 HPO4-- 0.5029940E-01 0.6453248E-08 0.5029939E-01 0.0000000E+00 Chg. balance for solid moles: -.6661E-14 Mass of aqueous solution: 0.145099E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 8499.9990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 10.66 1.028 2795. 3.446 30.09 1073. andradite 0.9424 -0.026 478.9 2.680 5.157 124.4 grossular 0.2282 -0.642 102.8 2.012 1.107 28.60 apatite-OH 0.1677E-01 -1.776 8.422 0.925 0.9070E-01 2.676 clinochlore 1.207 0.082 670.7 2.827 7.222 255.1 daphnite 0.3493 -0.457 249.2 2.397 2.684 75.53 chlorite-Mn 0.2948E-01 -1.531 20.90 1.320 0.2250 6.659 diopside 0.4531 -0.344 98.11 1.992 1.057 29.99 hedenbergite 0.1175 -0.930 29.15 1.465 0.3139 7.984 microcline 1.582 0.199 440.5 2.644 4.743 172.1 stilbite 5.467 0.738 3853. 3.586 41.49 1797. stilpnomelane-Fe 0.4444 -0.352 479.1 2.680 5.159 165.5 tr.625ac.25prg.125 0.7166E-01 -1.145 61.26 1.787 0.6597 19.72 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8051E+00 0.8051E+00 1.0000 -0.094 grossular 0.1949E+00 0.1949E+00 1.0000 -0.710 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.7611E+00 0.7611E+00 1.0000 -0.119 daphnite 0.2203E+00 0.2203E+00 1.0000 -0.657 chlorite-Mn 0.1859E-01 0.1859E-01 1.0000 -1.731 diopside 0.7941E+00 0.7941E+00 1.0000 -0.100 hedenbergite 0.2059E+00 0.2059E+00 1.0000 -0.686 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 tr.625ac.25prg.125 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 9286.111069 g Volume = 3757.885072 cm3 Porosity: -10.4935% V(tot) - V(min): -.35689E+03 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 8499.9990000 g log = 3.9294 Original solution: 1000.0103000 g Original solution / Rock added: 0.12 (Water/Rock Ratio), log = -0.9294 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.1615 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.8800E+00 0.9842 0.1006E+01 0.1022E+01 CO2,gas 0.2013E-07 1.0055 0.2351E-07 0.2338E-07 CH4,gas 0.1069E+00 1.0112 0.1255E+00 0.1241E+00 H2,gas 0.1308E-01 1.0006 0.1521E-01 0.1520E-01 H2S,gas 0.8195E-06 0.9955 0.9476E-06 0.9519E-06 S2,gas 0.1255E-27 1.0000 0.1458E-27 0.1458E-27 CO,gas 0.8204E-13 1.0000 0.9528E-13 0.9528E-13 SO3,gas 0.4254E-47 1.0000 0.4940E-47 0.4940E-47 SO2,gas 0.2516E-26 1.0000 0.2923E-26 0.2923E-26 HCl,gas 0.1672E-16 1.0000 0.1942E-16 0.1942E-16 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 16 albite -0.38 -0.38 0.00 0.000 -0.13080E-10 22 andradite 39.01 39.01 0.00 0.000 -0.12132E-10 23 grossular 32.73 32.73 0.00 0.000 -0.36397E-10 32 apatite-OH -18.15 -18.15 0.00 0.000 -0.12132E-10 46 clinochlore 39.07 39.07 0.00 0.000 -0.36397E-10 47 daphnite 28.97 28.97 0.00 0.000 0.18198E-10 48 chlorite-Mn 46.87 46.87 0.00 0.000 -0.36397E-10 67 diopside 16.18 16.18 0.00 0.000 -0.60662E-11 68 hedenbergite 14.21 14.21 0.00 0.000 -0.30331E-11 116 microcline -2.49 -2.49 0.00 0.000 -0.10616E-10 163 stilbite -7.52 -7.52 0.00 0.000 -0.90992E-11 164 stilpnomelane-Fe 13.02 13.02 0.00 0.000 -0.27298E-10 245 tr.625ac.25prg.125 45.16 45.16 0.00 0.000 -0.24265E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -15.99 -9.33 -3.109 0.15927E+05 -7.629 3 CH4,gas 4.54 1.94 -2.60 -0.650 0.44399E+04 -0.901 4 H2,gas 8.00 4.48 -3.52 -2.010 0.60051E+04 -1.818 5 H2S,gas -6.23 -13.95 -7.72 -3.861 0.13186E+05 -6.023 6 S2,gas -7.34 -36.87 -29.54 -4.544 0.50431E+05 -27.836 7 CO,gas 3.21 -11.50 -14.72 -4.529 0.25134E+05 -13.021 8 SO3,gas 17.12 -31.88 -49.01 -12.251 0.83675E+05 -47.306 9 SO2,gas 0.83 -27.40 -28.23 -7.529 0.48207E+05 -26.534 10 HCl,gas 5.19 -13.22 -18.41 -9.205 0.31436E+05 -16.712 11 acmite 7.71 6.53 -1.18 -0.123 0.20175E+04 15 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 19 spessartine 24.46 19.73 -4.73 -0.236 0.80694E+04 20 analcite 3.32 2.77 -0.55 -0.061 0.93626E+03 26 annite 20.12 17.72 -2.40 -0.134 0.41064E+04 27 phlogopite 27.06 25.40 -1.67 -0.093 0.28490E+04 29 anorthite 12.71 8.26 -4.45 -0.342 0.75903E+04 35 aragonite 0.97 -2.89 -3.85 -1.284 0.65780E+04 36 brucite 12.57 9.29 -3.27 -0.655 0.55909E+04 37 calcite 0.81 -2.89 -3.70 -1.233 0.63138E+04 38 carnegieite-low 9.02 5.93 -3.09 -0.442 0.52801E+04 39 carnegieite-high 10.09 5.93 -4.16 -0.595 0.71071E+04 40 carpholite-Mg 8.58 4.46 -4.12 -0.275 0.70429E+04 41 carpholite-Fe 6.71 1.90 -4.81 -0.321 0.82207E+04 42 celadonite 5.34 3.65 -1.69 -0.099 0.28879E+04 43 celadonite-Fe 3.88 1.09 -2.79 -0.164 0.47561E+04 44 chrysotile 23.89 21.57 -2.32 -0.194 0.39692E+04 49 chlorite-Al-free 47.17 43.14 -4.04 -0.168 0.68936E+04 51 chloritoid-Fe 9.17 5.06 -4.12 -0.275 0.70316E+04 52 chloritoid-Mn 11.40 7.56 -3.84 -0.256 0.65544E+04 54 coesite -2.38 -3.16 -0.78 -0.260 0.13341E+04 61 cristobalite -2.56 -3.16 -0.60 -0.199 0.10195E+04 63 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71234E+04 65 diaspore 2.87 0.74 -2.13 -0.356 0.36450E+04 66 diamond -3.10 -7.02 -3.92 -1.120 0.66929E+04 71 enstatite 17.26 12.27 -4.99 -0.499 0.85226E+04 73 clinoenstatite 17.17 12.27 -4.89 -0.489 0.83542E+04 75 epidote 24.67 22.70 -1.97 -0.095 0.33586E+04 76 clinozoisite 22.81 18.95 -3.86 -0.175 0.65869E+04 77 epidote-Fe 29.84 26.46 -3.38 -0.176 0.57768E+04 78 fayalite 14.05 10.31 -3.73 -0.533 0.63743E+04 79 ferrosilite 11.15 7.16 -3.99 -0.399 0.68202E+04 83 gibbsite 4.08 0.74 -3.34 -0.477 0.57036E+04 84 glaucophane 22.97 20.80 -2.17 -0.059 0.37134E+04 85 glaucophane-Fe 17.28 13.12 -4.15 -0.112 0.70919E+04 86 graphite -3.55 -7.02 -3.48 -0.993 0.59352E+04 87 greenalite 16.14 13.89 -2.25 -0.187 0.38408E+04 90 hematite 12.57 8.99 -3.58 -0.434 0.61111E+04 91 heulandite -5.83 -7.52 -1.69 -0.077 0.28938E+04 95 jadeite 4.22 2.77 -1.44 -0.144 0.24617E+04 97 kalsilite 7.58 3.83 -3.76 -0.537 0.64126E+04 98 kaolinite -1.33 -4.84 -3.50 -0.319 0.59832E+04 101 laumontite 2.88 1.95 -0.93 -0.062 0.15935E+04 102 lawsonite 9.62 8.26 -1.35 -0.090 0.23070E+04 103 leucite 4.12 0.67 -3.45 -0.345 0.58873E+04 105 lizardite 23.24 21.57 -1.68 -0.140 0.28619E+04 107 magnetite 20.09 15.72 -4.37 -0.356 0.74536E+04 108 minnesotaite 10.39 7.58 -2.81 -0.165 0.48027E+04 112 manganosite 14.06 9.24 -4.82 -1.204 0.82236E+04 120 muscovite 2.58 -1.01 -3.59 -0.211 0.61315E+04 121 paragonite 4.24 1.09 -3.15 -0.185 0.53706E+04 122 nepheline 8.34 5.93 -2.41 -0.344 0.41125E+04 128 periclase-Fe 11.63 6.73 -4.89 -1.223 0.83523E+04 134 phlogopite-Na 29.65 27.50 -2.15 -0.119 0.36678E+04 136 prehnite 19.37 18.21 -1.16 -0.068 0.19849E+04 137 prehnite-Fe 22.50 21.96 -0.53 -0.032 0.91159E+03 138 pumpellyite-Fe 46.27 43.89 -2.38 -0.053 0.40582E+04 139 pumpellyite-Mg 48.99 46.45 -2.54 -0.057 0.43421E+04 142 pyrite -21.25 -25.65 -4.41 -1.037 0.75233E+04 143 pyrrhotite -4.26 -7.22 -2.96 -0.986 0.50495E+04 144 pyrrhotiteFe0.875 -6.02 -8.62 -2.60 -0.956 0.44367E+04 145 pyroxmangite 7.40 6.08 -1.31 -0.263 0.22439E+04 146 pyrophyllite -6.18 -11.15 -4.98 -0.311 0.84962E+04 147 quartz -2.99 -3.16 -0.17 -0.056 0.28679E+03 152 rhodonite 7.45 6.08 -1.36 -0.272 0.23242E+04 153 sanidine -1.28 -2.49 -1.21 -0.093 0.20677E+04 165 stilpnomelane-Mg 27.44 25.81 -1.63 -0.049 0.27804E+04 171 talc 16.49 15.25 -1.24 -0.073 0.21140E+04 174 tephroite 18.09 15.33 -2.76 -0.394 0.47116E+04 178 tridymite -2.63 -3.16 -0.53 -0.177 0.90677E+03 179 tremolite 47.87 47.42 -0.45 -0.012 0.77494E+03 180 ferroactinolite 38.45 34.62 -3.83 -0.104 0.65448E+04 181 troilite-low -4.41 -7.22 -2.81 -0.936 0.47923E+04 183 vesuvianite 223.47 218.82 -4.65 -0.036 0.79441E+04 187 wairakite 3.95 1.95 -2.00 -0.118 0.34155E+04 188 walstromite 11.51 9.94 -1.56 -0.313 0.26719E+04 189 wollastonite 10.46 9.94 -0.52 -0.103 0.88229E+03 190 pseudo-wollastonite 11.00 9.94 -1.06 -0.211 0.18021E+04 191 zoisite 22.85 18.95 -3.90 -0.177 0.66610E+04 192 akaganeite 7.75 4.49 -3.26 -0.705 0.55681E+04 199 chalcedony -2.80 -3.16 -0.35 -0.118 0.60609E+03 201 montmorillonite-Ca -2.29 -6.17 -3.88 -0.240 0.66180E+04 202 montmorillonite-K -2.24 -6.27 -4.03 -0.247 0.68816E+04 203 montmorillonite-Mg -2.48 -6.79 -4.32 -0.267 0.73678E+04 204 montmorillonite-Na -2.04 -5.57 -3.54 -0.216 0.60365E+04 205 nontronite-Ca 3.21 -0.19 -3.41 -0.221 0.58215E+04 206 nontronite-H 2.53 -2.36 -4.89 -0.328 0.83484E+04 207 nontronite-K 3.34 -0.30 -3.64 -0.233 0.62083E+04 208 nontronite-Mg 3.07 -0.82 -3.90 -0.253 0.66553E+04 209 nontronite-Na 3.52 0.40 -3.12 -0.200 0.53291E+04 224 tobermorite 9.82 7.76 -2.07 -0.564 0.35287E+04 230 alabandite -0.98 -4.71 -3.73 -1.244 0.63737E+04 233 boehmite 4.41 0.74 -3.67 -0.611 0.62619E+04 235 ferrous-oxide 9.81 6.73 -3.08 -0.769 0.52532E+04 240 silica-amorphous -2.09 -3.16 -1.07 -0.355 0.18203E+04 242 an20ab80 2.02 1.35 -0.67 -0.052 0.11472E+04 243 an25ab75 2.65 1.78 -0.87 -0.067 0.14810E+04 244 an30ab70 3.28 2.21 -1.07 -0.082 0.18244E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 100.0000000 g Current total amount of reactant added: 8499.9990000 g New total amount of reactant added: 8599.9990000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.5208E-10 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 13 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 8599.9990000 Water: Moles liquid = 0.7483E+01 kg liquid = 0.1348E+00 Moles total = -.5230E+02 kg total = -.9421E+00 Activity = 1.0000 Stoichiometric ionic strength = .1205327E-01 Osmotic coef. = 0.9673 True ionic strength = .2058463E-01 Chg. balance for total moles = 0.5208E-10 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.90767E-10 -10.0421 0.76134E-10 -10.1184 0.83878E+00 -0.0763 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.10188E-02 -2.9919 0.84926E-03 -3.0710 0.83363E+00 -0.0790 4 SO4-- 0.47076E-11 -11.3272 0.24269E-11 -11.6149 0.51552E+00 -0.2878 5 HCO3- 0.17388E-05 -5.7597 0.14517E-05 -5.8381 0.83488E+00 -0.0784 6 HS- 0.18916E-03 -3.7232 0.15772E-03 -3.8021 0.83375E+00 -0.0790 7 Al+++ 0.10649E-28 -28.9727 0.24193E-29 -29.6163 0.22719E+00 -0.6436 8 H4SiO4 0.69598E-03 -3.1574 0.69598E-03 -3.1574 0.10000E+01 0.0000 9 Ca++ 0.14322E-06 -6.8440 0.73279E-07 -7.1350 0.51165E+00 -0.2910 10 Mg++ 0.22408E-10 -10.6496 0.11411E-10 -10.9427 0.50926E+00 -0.2931 11 Fe++ 0.61759E-13 -13.2093 0.31487E-13 -13.5019 0.50983E+00 -0.2926 12 K+ 0.16091E-03 -3.7934 0.13437E-03 -3.8717 0.83508E+00 -0.0783 13 Na+ 0.20420E-01 -1.6899 0.17019E-01 -1.7691 0.83347E+00 -0.0791 14 Mn++ 0.19827E-10 -10.7027 0.10117E-10 -10.9950 0.51026E+00 -0.2922 15 HPO4-- 0.43351E-07 -7.3630 0.22352E-07 -7.6507 0.51560E+00 -0.2877 16 HSiO3- 0.10239E-01 -1.9897 0.85359E-02 -2.0687 0.83363E+00 -0.0790 17 Ca(HSiO3)+ 0.17055E-07 -7.7682 0.14245E-07 -7.8463 0.83526E+00 -0.0782 18 Mg(HSiO3)+ 0.33053E-11 -11.4808 0.27608E-11 -11.5590 0.83526E+00 -0.0782 19 NaHSiO3,aq 0.23497E-02 -2.6290 0.23497E-02 -2.6290 0.10000E+01 0.0000 20 AlO+ 0.67982E-16 -16.1676 0.56782E-16 -16.2458 0.83526E+00 -0.0782 22 HAlO2,aq 0.14853E-09 -9.8282 0.14853E-09 -9.8282 0.10000E+01 0.0000 23 AlO2- 0.51899E-05 -5.2848 0.43185E-05 -5.3647 0.83209E+00 -0.0798 24 CH4,aq 0.91980E-04 -4.0363 0.91642E-04 -4.0379 0.99633E+00 -0.0016 25 C2H6,aq 0.12442E-12 -12.9051 0.12396E-12 -12.9067 0.99633E+00 -0.0016 29 CO,aq 0.68714E-16 -16.1630 0.68714E-16 -16.1630 0.10000E+01 0.0000 30 CO2,aq 0.23703E-09 -9.6252 0.23616E-09 -9.6268 0.99633E+00 -0.0016 31 CO3-2 0.32377E-05 -5.4898 0.16655E-05 -5.7785 0.51440E+00 -0.2887 32 CaCO3,aq 0.15303E-08 -8.8152 0.15303E-08 -8.8152 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.32510E-11 -11.4880 0.27154E-11 -11.5662 0.83526E+00 -0.0782 34 CaCl+ 0.12058E-09 -9.9187 0.10071E-09 -9.9969 0.83526E+00 -0.0782 35 CaCl2,aq 0.20320E-13 -13.6921 0.20320E-13 -13.6921 0.10000E+01 0.0000 36 CaOH+ 0.82126E-07 -7.0855 0.68597E-07 -7.1637 0.83526E+00 -0.0782 37 CaSO4,aq 0.56472E-16 -16.2482 0.56472E-16 -16.2482 0.10000E+01 0.0000 38 HCl,aq 0.11848E-13 -13.9263 0.11848E-13 -13.9263 0.10000E+01 0.0000 43 FeCl+ 0.50674E-16 -16.2952 0.42326E-16 -16.3734 0.83526E+00 -0.0782 46 FeO,aq 0.21112E-09 -9.6755 0.21112E-09 -9.6755 0.10000E+01 0.0000 47 FeOH+ 0.16117E-10 -10.7927 0.13462E-10 -10.8709 0.83526E+00 -0.0782 48 HFeO2- 0.34806E-07 -7.4583 0.29015E-07 -7.5374 0.83363E+00 -0.0790 49 FeO+ 0.11296E-16 -16.9471 0.94350E-17 -17.0253 0.83526E+00 -0.0782 51 FeO2- 0.39955E-09 -9.3984 0.33307E-09 -9.4775 0.83363E+00 -0.0790 52 HFeO2,aq 0.32252E-11 -11.4914 0.32252E-11 -11.4914 0.10000E+01 0.0000 53 H2,aq 0.11625E-04 -4.9346 0.11582E-04 -4.9362 0.99633E+00 -0.0016 54 KCl,aq 0.20683E-08 -8.6844 0.20683E-08 -8.6844 0.10000E+01 0.0000 56 KOH,aq 0.75375E-06 -6.1228 0.75375E-06 -6.1228 0.10000E+01 0.0000 57 KSO4- 0.60704E-14 -14.2168 0.50605E-14 -14.2958 0.83363E+00 -0.0790 58 MgCO3,aq 0.59735E-13 -13.2238 0.59735E-13 -13.2238 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.51731E-15 -15.2862 0.43209E-15 -15.3644 0.83526E+00 -0.0782 60 MgCl+ 0.17018E-13 -13.7691 0.14215E-13 -13.8473 0.83526E+00 -0.0782 61 MgOH+ 0.70770E-10 -10.1502 0.59111E-10 -10.2283 0.83526E+00 -0.0782 63 MnO,aq 0.18075E-08 -8.7429 0.18075E-08 -8.7429 0.10000E+01 0.0000 64 MnOH+ 0.48107E-09 -9.3178 0.40182E-09 -9.3960 0.83526E+00 -0.0782 65 MnO2-2 0.20119E-10 -10.6964 0.10349E-10 -10.9851 0.51440E+00 -0.2887 66 HMnO2- 0.20707E-09 -9.6839 0.17262E-09 -9.7629 0.83363E+00 -0.0790 69 MnCl+ 0.63343E-13 -13.1983 0.52908E-13 -13.2765 0.83526E+00 -0.0782 71 NaCl,aq 0.47901E-05 -5.3197 0.47901E-05 -5.3197 0.10000E+01 0.0000 72 NaOH,aq 0.96047E-04 -4.0175 0.96047E-04 -4.0175 0.10000E+01 0.0000 74 OH- 0.91203E-02 -2.0400 0.75889E-02 -2.1198 0.83209E+00 -0.0798 79 HPO3-2 0.15684E-14 -14.8046 0.80677E-15 -15.0933 0.51440E+00 -0.2887 81 H2PO3- 0.14775E-18 -18.8305 0.12317E-18 -18.9095 0.83363E+00 -0.0790 82 H3PO4,aq 0.90612E-18 -18.0428 0.90612E-18 -18.0428 0.10000E+01 0.0000 83 H2PO4- 0.37620E-10 -10.4246 0.31392E-10 -10.5032 0.83444E+00 -0.0786 84 PO4-3 0.10027E-08 -8.9988 0.23953E-09 -9.6206 0.23888E+00 -0.6218 88 HP2O7-3 0.89108E-18 -18.0501 0.20266E-18 -18.6932 0.22743E+00 -0.6432 89 P2O7-4 0.84907E-17 -17.0711 0.63590E-18 -18.1966 0.74894E-01 -1.1256 90 H2S,aq 0.37248E-07 -7.4289 0.37111E-07 -7.4305 0.99633E+00 -0.0016 91 S2-2 0.92510E-13 -13.0338 0.47587E-13 -13.3225 0.51440E+00 -0.2887 97 SO3-2 0.69975E-17 -17.1551 0.36528E-17 -17.4374 0.52201E+00 -0.2823 98 HSO3- 0.20887E-19 -19.6801 0.17412E-19 -19.7591 0.83363E+00 -0.0790 99 HSO4- 0.21297E-18 -18.6717 0.17806E-18 -18.7494 0.83609E+00 -0.0777 Charge balance for all species = 0.3872E-09 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.9076667E-10 -.2183329E-01 -.2196779E+02 0.0000 2 H2O 0.1000000E+01 0.5550499E+02 0.9981736E+06 0.0000 3 Cl- 0.1018752E-02 0.1023545E-02 0.3622366E+02 7.0475 4 SO4-- 0.4707637E-11 -.9488605E-04 -.9098812E+01 8.6219 5 HCO3- 0.1738833E-05 0.9695820E-04 0.5905672E+01 4.2803 6 HS- 0.1891645E-03 0.2840878E-03 0.9378765E+01 6.3163 7 Al+++ 0.1064864E-28 0.5190070E-05 0.1397886E+00 0.7390 8 H4SiO4 0.6959842E-03 0.1328511E-01 0.1274649E+04 -3.1574 9 Ca++ 0.1432196E-06 0.2440547E-06 0.9763953E-02 13.1018 10 Mg++ 0.2240793E-10 0.9656609E-10 0.2343570E-05 9.2942 11 Fe++ 0.6175921E-13 0.3543575E-07 0.1975486E-02 6.7350 12 K+ 0.1609130E-03 0.1616688E-03 0.6310413E+01 6.2467 13 Na+ 0.2041991E-01 0.2287039E-01 0.5248575E+03 8.3494 14 Mn++ 0.1982675E-10 0.2535678E-08 0.1390591E-03 9.2419 15 HPO4-- 0.4335090E-07 0.4439126E-07 0.4253106E-02 12.5862 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.1424032E+03 -.2943135E-02 -.1424003E+03 0.0000000E+00 2 H2O -.5229627E+02 0.7482093E+01 -.5977836E+02 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.2383608E+00 -.1279067E-04 0.2383736E+00 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.2383353E+00 0.3829514E-04 -.2383736E+00 0.0000000E+00 7 Al+++ 0.2804237E+02 0.6996232E-06 0.2804237E+02 0.0000000E+00 8 H4SiO4 0.8954992E+02 0.1790838E-02 0.8954813E+02 0.0000000E+00 9 Ca++ 0.9891240E+01 0.3289866E-07 0.9891240E+01 0.0000000E+00 10 Mg++ 0.6825396E+01 0.1301714E-10 0.6825396E+01 0.0000000E+00 11 Fe++ 0.6131873E+01 0.4776752E-08 0.6131873E+01 0.0000000E+00 12 K+ 0.1825902E+01 0.2179302E-04 0.1825880E+01 0.0000000E+00 13 Na+ 0.1079525E+02 0.3082937E-02 0.1079217E+02 0.0000000E+00 14 Mn++ 0.1491119E+00 0.3418102E-09 0.1491119E+00 0.0000000E+00 15 HPO4-- 0.5089115E-01 0.5983957E-08 0.5089115E-01 0.0000000E+00 Chg. balance for solid moles: -.2609E-14 Mass of aqueous solution: 0.135039E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 8599.9990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 10.78 1.033 2828. 3.451 30.10 1085. andradite 0.9535 -0.021 484.5 2.685 5.157 125.9 grossular 0.2309 -0.637 104.0 2.017 1.107 28.94 apatite-OH 0.1696E-01 -1.770 8.521 0.931 0.9070E-01 2.708 clinochlore 1.221 0.087 678.6 2.832 7.222 258.1 daphnite 0.3534 -0.452 252.2 2.402 2.684 76.41 chlorite-Mn 0.2982E-01 -1.525 21.14 1.325 0.2250 6.738 diopside 0.4585 -0.339 99.29 1.997 1.057 30.35 hedenbergite 0.1189 -0.925 29.50 1.470 0.3140 8.080 microcline 1.601 0.204 445.6 2.649 4.743 174.1 stilbite 5.531 0.743 3898. 3.591 41.49 1818. stilpnomelane-Fe 0.4497 -0.347 484.7 2.685 5.159 167.4 tr.625ac.25prg.125 0.7250E-01 -1.140 61.97 1.792 0.6596 19.94 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8051E+00 0.8051E+00 1.0000 -0.094 grossular 0.1949E+00 0.1949E+00 1.0000 -0.710 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.7611E+00 0.7611E+00 1.0000 -0.119 daphnite 0.2203E+00 0.2203E+00 1.0000 -0.657 chlorite-Mn 0.1859E-01 0.1859E-01 1.0000 -1.731 diopside 0.7941E+00 0.7941E+00 1.0000 -0.100 hedenbergite 0.2059E+00 0.2059E+00 1.0000 -0.686 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 tr.625ac.25prg.125 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 9395.361726 g Volume = 3802.088133 cm3 Porosity: -10.4937% V(tot) - V(min): -.36109E+03 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 8599.9990000 g log = 3.9345 Original solution: 1000.0103000 g Original solution / Rock added: 0.12 (Water/Rock Ratio), log = -0.9345 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.1708 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.8731E+00 0.9841 0.1006E+01 0.1022E+01 CO2,gas 0.2146E-07 1.0054 0.2527E-07 0.2513E-07 CH4,gas 0.1139E+00 1.0111 0.1349E+00 0.1334E+00 H2,gas 0.1298E-01 1.0006 0.1521E-01 0.1520E-01 H2S,gas 0.8753E-06 0.9955 0.1020E-05 0.1025E-05 S2,gas 0.1443E-27 1.0000 0.1689E-27 0.1689E-27 CO,gas 0.8746E-13 1.0000 0.1024E-12 0.1024E-12 SO3,gas 0.4543E-47 1.0000 0.5319E-47 0.5319E-47 SO2,gas 0.2687E-26 1.0000 0.3147E-26 0.3147E-26 HCl,gas 0.1786E-16 1.0000 0.2091E-16 0.2091E-16 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 16 albite -0.38 -0.38 0.00 0.000 -0.13080E-10 22 andradite 39.01 39.01 0.00 0.000 0.00000E+00 23 grossular 32.73 32.73 0.00 0.000 -0.36397E-10 32 apatite-OH -18.15 -18.15 0.00 0.000 0.00000E+00 46 clinochlore 39.07 39.07 0.00 0.000 -0.60662E-10 47 daphnite 28.97 28.97 0.00 0.000 -0.84926E-10 48 chlorite-Mn 46.87 46.87 0.00 0.000 -0.48529E-10 67 diopside 16.18 16.18 0.00 0.000 -0.60662E-11 68 hedenbergite 14.21 14.21 0.00 0.000 -0.30331E-11 116 microcline -2.49 -2.49 0.00 0.000 -0.22748E-10 163 stilbite -7.52 -7.52 0.00 0.000 -0.90992E-11 164 stilpnomelane-Fe 13.02 13.02 0.00 0.000 -0.27298E-10 245 tr.625ac.25prg.125 45.16 45.16 0.00 0.000 0.60662E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -15.96 -9.30 -3.099 0.15873E+05 -7.597 3 CH4,gas 4.54 1.97 -2.57 -0.642 0.43865E+04 -0.870 4 H2,gas 8.00 4.48 -3.52 -2.010 0.60051E+04 -1.818 5 H2S,gas -6.23 -13.92 -7.69 -3.845 0.13131E+05 -5.991 6 S2,gas -7.34 -36.81 -29.47 -4.534 0.50321E+05 -27.772 7 CO,gas 3.21 -11.47 -14.69 -4.520 0.25081E+05 -12.990 8 SO3,gas 17.12 -31.85 -48.97 -12.243 0.83620E+05 -47.274 9 SO2,gas 0.83 -27.37 -28.20 -7.520 0.48153E+05 -26.502 10 HCl,gas 5.19 -13.19 -18.38 -9.189 0.31381E+05 -16.680 11 acmite 7.71 6.53 -1.18 -0.123 0.20175E+04 15 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 19 spessartine 24.46 19.73 -4.73 -0.236 0.80694E+04 20 analcite 3.32 2.77 -0.55 -0.061 0.93626E+03 26 annite 20.12 17.72 -2.40 -0.134 0.41064E+04 27 phlogopite 27.06 25.40 -1.67 -0.093 0.28490E+04 29 anorthite 12.71 8.26 -4.45 -0.342 0.75903E+04 35 aragonite 0.97 -2.85 -3.82 -1.274 0.65247E+04 36 brucite 12.57 9.29 -3.27 -0.655 0.55909E+04 37 calcite 0.81 -2.85 -3.67 -1.222 0.62604E+04 38 carnegieite-low 9.02 5.93 -3.09 -0.442 0.52801E+04 39 carnegieite-high 10.09 5.93 -4.16 -0.595 0.71071E+04 40 carpholite-Mg 8.58 4.46 -4.12 -0.275 0.70429E+04 41 carpholite-Fe 6.71 1.90 -4.81 -0.321 0.82207E+04 42 celadonite 5.34 3.65 -1.69 -0.099 0.28879E+04 43 celadonite-Fe 3.88 1.09 -2.79 -0.164 0.47561E+04 44 chrysotile 23.89 21.57 -2.32 -0.194 0.39692E+04 49 chlorite-Al-free 47.17 43.14 -4.04 -0.168 0.68936E+04 51 chloritoid-Fe 9.17 5.06 -4.12 -0.275 0.70316E+04 52 chloritoid-Mn 11.40 7.56 -3.84 -0.256 0.65544E+04 54 coesite -2.38 -3.16 -0.78 -0.260 0.13341E+04 61 cristobalite -2.56 -3.16 -0.60 -0.199 0.10195E+04 63 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71234E+04 65 diaspore 2.87 0.74 -2.13 -0.356 0.36450E+04 66 diamond -3.10 -6.99 -3.89 -1.111 0.66396E+04 71 enstatite 17.26 12.27 -4.99 -0.499 0.85226E+04 73 clinoenstatite 17.17 12.27 -4.89 -0.489 0.83542E+04 75 epidote 24.67 22.70 -1.97 -0.095 0.33586E+04 76 clinozoisite 22.81 18.95 -3.86 -0.175 0.65869E+04 77 epidote-Fe 29.84 26.46 -3.38 -0.176 0.57768E+04 78 fayalite 14.05 10.31 -3.73 -0.533 0.63743E+04 79 ferrosilite 11.15 7.16 -3.99 -0.399 0.68202E+04 83 gibbsite 4.08 0.74 -3.34 -0.477 0.57036E+04 84 glaucophane 22.97 20.80 -2.17 -0.059 0.37134E+04 85 glaucophane-Fe 17.28 13.12 -4.15 -0.112 0.70919E+04 86 graphite -3.55 -6.99 -3.44 -0.984 0.58818E+04 87 greenalite 16.14 13.89 -2.25 -0.187 0.38408E+04 90 hematite 12.57 8.99 -3.58 -0.434 0.61111E+04 91 heulandite -5.83 -7.52 -1.69 -0.077 0.28938E+04 95 jadeite 4.22 2.77 -1.44 -0.144 0.24617E+04 97 kalsilite 7.58 3.83 -3.76 -0.537 0.64126E+04 98 kaolinite -1.33 -4.84 -3.50 -0.319 0.59832E+04 101 laumontite 2.88 1.95 -0.93 -0.062 0.15935E+04 102 lawsonite 9.62 8.26 -1.35 -0.090 0.23070E+04 103 leucite 4.12 0.67 -3.45 -0.345 0.58873E+04 105 lizardite 23.24 21.57 -1.68 -0.140 0.28619E+04 107 magnetite 20.09 15.72 -4.37 -0.356 0.74536E+04 108 minnesotaite 10.39 7.58 -2.81 -0.165 0.48027E+04 112 manganosite 14.06 9.24 -4.82 -1.204 0.82236E+04 120 muscovite 2.58 -1.01 -3.59 -0.211 0.61315E+04 121 paragonite 4.24 1.09 -3.15 -0.185 0.53706E+04 122 nepheline 8.34 5.93 -2.41 -0.344 0.41125E+04 128 periclase-Fe 11.63 6.73 -4.89 -1.223 0.83523E+04 134 phlogopite-Na 29.65 27.50 -2.15 -0.119 0.36678E+04 136 prehnite 19.37 18.21 -1.16 -0.068 0.19849E+04 137 prehnite-Fe 22.50 21.96 -0.53 -0.032 0.91159E+03 138 pumpellyite-Fe 46.27 43.89 -2.38 -0.053 0.40582E+04 139 pumpellyite-Mg 48.99 46.45 -2.54 -0.057 0.43421E+04 142 pyrite -21.25 -25.59 -4.34 -1.022 0.74138E+04 143 pyrrhotite -4.26 -7.19 -2.93 -0.975 0.49948E+04 144 pyrrhotiteFe0.875 -6.02 -8.58 -2.57 -0.944 0.43820E+04 145 pyroxmangite 7.40 6.08 -1.31 -0.263 0.22439E+04 146 pyrophyllite -6.18 -11.15 -4.98 -0.311 0.84962E+04 147 quartz -2.99 -3.16 -0.17 -0.056 0.28679E+03 152 rhodonite 7.45 6.08 -1.36 -0.272 0.23242E+04 153 sanidine -1.28 -2.49 -1.21 -0.093 0.20677E+04 165 stilpnomelane-Mg 27.44 25.81 -1.63 -0.049 0.27804E+04 171 talc 16.49 15.25 -1.24 -0.073 0.21140E+04 174 tephroite 18.09 15.33 -2.76 -0.394 0.47116E+04 178 tridymite -2.63 -3.16 -0.53 -0.177 0.90677E+03 179 tremolite 47.87 47.42 -0.45 -0.012 0.77494E+03 180 ferroactinolite 38.45 34.62 -3.83 -0.104 0.65448E+04 181 troilite-low -4.41 -7.19 -2.77 -0.925 0.47376E+04 183 vesuvianite 223.47 218.82 -4.65 -0.036 0.79441E+04 187 wairakite 3.95 1.95 -2.00 -0.118 0.34155E+04 188 walstromite 11.51 9.94 -1.56 -0.313 0.26719E+04 189 wollastonite 10.46 9.94 -0.52 -0.103 0.88229E+03 190 pseudo-wollastonite 11.00 9.94 -1.06 -0.211 0.18021E+04 191 zoisite 22.85 18.95 -3.90 -0.177 0.66610E+04 192 akaganeite 7.75 4.49 -3.26 -0.705 0.55681E+04 199 chalcedony -2.80 -3.16 -0.35 -0.118 0.60609E+03 201 montmorillonite-Ca -2.29 -6.17 -3.88 -0.240 0.66180E+04 202 montmorillonite-K -2.24 -6.27 -4.03 -0.247 0.68816E+04 203 montmorillonite-Mg -2.48 -6.79 -4.32 -0.267 0.73678E+04 204 montmorillonite-Na -2.04 -5.57 -3.54 -0.216 0.60365E+04 205 nontronite-Ca 3.21 -0.19 -3.41 -0.221 0.58215E+04 206 nontronite-H 2.53 -2.36 -4.89 -0.328 0.83484E+04 207 nontronite-K 3.34 -0.30 -3.64 -0.233 0.62083E+04 208 nontronite-Mg 3.07 -0.82 -3.90 -0.253 0.66553E+04 209 nontronite-Na 3.52 0.40 -3.12 -0.200 0.53291E+04 224 tobermorite 9.82 7.76 -2.07 -0.564 0.35287E+04 230 alabandite -0.98 -4.68 -3.70 -1.234 0.63190E+04 233 boehmite 4.41 0.74 -3.67 -0.611 0.62619E+04 235 ferrous-oxide 9.81 6.73 -3.08 -0.769 0.52532E+04 240 silica-amorphous -2.09 -3.16 -1.07 -0.355 0.18203E+04 242 an20ab80 2.02 1.35 -0.67 -0.052 0.11472E+04 243 an25ab75 2.65 1.78 -0.87 -0.067 0.14810E+04 244 an30ab70 3.28 2.21 -1.07 -0.082 0.18244E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 100.0000000 g Current total amount of reactant added: 8599.9990000 g New total amount of reactant added: 8699.9990000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.5208E-10 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 13 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 8699.9990000 Water: Moles liquid = 0.6925E+01 kg liquid = 0.1248E+00 Moles total = -.5355E+02 kg total = -.9647E+00 Activity = 1.0000 Stoichiometric ionic strength = .1212203E-01 Osmotic coef. = 0.9672 True ionic strength = .2063894E-01 Chg. balance for total moles = 0.5208E-10 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.91004E-10 -10.0409 0.76320E-10 -10.1174 0.83865E+00 -0.0764 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.11007E-02 -2.9583 0.91745E-03 -3.0374 0.83348E+00 -0.0791 4 SO4-- 0.50768E-11 -11.2944 0.26154E-11 -11.5825 0.51516E+00 -0.2881 5 HCO3- 0.18748E-05 -5.7270 0.15650E-05 -5.8055 0.83473E+00 -0.0785 6 HS- 0.20439E-03 -3.6895 0.17038E-03 -3.7686 0.83361E+00 -0.0790 7 Al+++ 0.10744E-28 -28.9688 0.24371E-29 -29.6131 0.22683E+00 -0.6443 8 H4SiO4 0.69598E-03 -3.1574 0.69598E-03 -3.1574 0.10000E+01 0.0000 9 Ca++ 0.14402E-06 -6.8416 0.73638E-07 -7.1329 0.51129E+00 -0.2913 10 Mg++ 0.22534E-10 -10.6472 0.11467E-10 -10.9405 0.50889E+00 -0.2934 11 Fe++ 0.62106E-13 -13.2069 0.31641E-13 -13.4997 0.50947E+00 -0.2929 12 K+ 0.16133E-03 -3.7923 0.13470E-03 -3.8706 0.83493E+00 -0.0783 13 Na+ 0.20474E-01 -1.6888 0.17061E-01 -1.7680 0.83332E+00 -0.0792 14 Mn++ 0.19938E-10 -10.7003 0.10167E-10 -10.9928 0.50990E+00 -0.2925 15 HPO4-- 0.43169E-07 -7.3648 0.22243E-07 -7.6528 0.51524E+00 -0.2880 16 HSiO3- 0.10216E-01 -1.9907 0.85151E-02 -2.0698 0.83348E+00 -0.0791 17 Ca(HSiO3)+ 0.17099E-07 -7.7670 0.14280E-07 -7.8453 0.83512E+00 -0.0783 18 Mg(HSiO3)+ 0.33139E-11 -11.4797 0.27675E-11 -11.5579 0.83512E+00 -0.0783 19 NaHSiO3,aq 0.23496E-02 -2.6290 0.23496E-02 -2.6290 0.10000E+01 0.0000 20 AlO+ 0.68160E-16 -16.1665 0.56921E-16 -16.2447 0.83512E+00 -0.0783 22 HAlO2,aq 0.14853E-09 -9.8282 0.14853E-09 -9.8282 0.10000E+01 0.0000 23 AlO2- 0.51782E-05 -5.2858 0.43079E-05 -5.3657 0.83194E+00 -0.0799 24 CH4,aq 0.99402E-04 -4.0026 0.99035E-04 -4.0042 0.99631E+00 -0.0016 25 C2H6,aq 0.14530E-12 -12.8377 0.14477E-12 -12.8393 0.99631E+00 -0.0016 29 CO,aq 0.74257E-16 -16.1293 0.74257E-16 -16.1293 0.10000E+01 0.0000 30 CO2,aq 0.25616E-09 -9.5915 0.25522E-09 -9.5931 0.99631E+00 -0.0016 31 CO3-2 0.34843E-05 -5.4579 0.17911E-05 -5.7469 0.51405E+00 -0.2890 32 CaCO3,aq 0.16538E-08 -8.7815 0.16538E-08 -8.7815 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.35225E-11 -11.4532 0.29417E-11 -11.5314 0.83512E+00 -0.0783 34 CaCl+ 0.13092E-09 -9.8830 0.10933E-09 -9.9613 0.83512E+00 -0.0783 35 CaCl2,aq 0.23831E-13 -13.6229 0.23831E-13 -13.6229 0.10000E+01 0.0000 36 CaOH+ 0.82342E-07 -7.0844 0.68765E-07 -7.1626 0.83512E+00 -0.0783 37 CaSO4,aq 0.61157E-16 -16.2136 0.61157E-16 -16.2136 0.10000E+01 0.0000 38 HCl,aq 0.12831E-13 -13.8917 0.12831E-13 -13.8917 0.10000E+01 0.0000 43 FeCl+ 0.55020E-16 -16.2595 0.45948E-16 -16.3377 0.83512E+00 -0.0783 46 FeO,aq 0.21112E-09 -9.6755 0.21112E-09 -9.6755 0.10000E+01 0.0000 47 FeOH+ 0.16160E-10 -10.7916 0.13495E-10 -10.8698 0.83512E+00 -0.0783 48 HFeO2- 0.34727E-07 -7.4593 0.28944E-07 -7.5384 0.83348E+00 -0.0791 49 FeO+ 0.11326E-16 -16.9459 0.94581E-17 -17.0242 0.83512E+00 -0.0783 51 FeO2- 0.39864E-09 -9.3994 0.33226E-09 -9.4785 0.83348E+00 -0.0791 52 HFeO2,aq 0.32252E-11 -11.4914 0.32252E-11 -11.4914 0.10000E+01 0.0000 53 H2,aq 0.11625E-04 -4.9346 0.11582E-04 -4.9362 0.99631E+00 -0.0016 54 KCl,aq 0.22399E-08 -8.6498 0.22399E-08 -8.6498 0.10000E+01 0.0000 56 KOH,aq 0.75375E-06 -6.1228 0.75375E-06 -6.1228 0.10000E+01 0.0000 57 KSO4- 0.65591E-14 -14.1832 0.54669E-14 -14.2623 0.83348E+00 -0.0791 58 MgCO3,aq 0.64554E-13 -13.1901 0.64554E-13 -13.1901 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.56051E-15 -15.2514 0.46809E-15 -15.3297 0.83512E+00 -0.0783 60 MgCl+ 0.18478E-13 -13.7333 0.15431E-13 -13.8116 0.83512E+00 -0.0783 61 MgOH+ 0.70955E-10 -10.1490 0.59256E-10 -10.2273 0.83512E+00 -0.0783 63 MnO,aq 0.18075E-08 -8.7429 0.18075E-08 -8.7429 0.10000E+01 0.0000 64 MnOH+ 0.48234E-09 -9.3166 0.40281E-09 -9.3949 0.83512E+00 -0.0783 65 MnO2-2 0.20035E-10 -10.6982 0.10299E-10 -10.9872 0.51405E+00 -0.2890 66 HMnO2- 0.20660E-09 -9.6849 0.17220E-09 -9.7640 0.83348E+00 -0.0791 69 MnCl+ 0.68777E-13 -13.1626 0.57437E-13 -13.2408 0.83512E+00 -0.0783 71 NaCl,aq 0.51874E-05 -5.2851 0.51874E-05 -5.2851 0.10000E+01 0.0000 72 NaOH,aq 0.96046E-04 -4.0175 0.96046E-04 -4.0175 0.10000E+01 0.0000 74 OH- 0.90997E-02 -2.0410 0.75704E-02 -2.1209 0.83194E+00 -0.0799 79 HPO3-2 0.15618E-14 -14.8064 0.80283E-15 -15.0954 0.51405E+00 -0.2890 81 H2PO3- 0.14742E-18 -18.8315 0.12287E-18 -18.9106 0.83348E+00 -0.0791 82 H3PO4,aq 0.90612E-18 -18.0428 0.90612E-18 -18.0428 0.10000E+01 0.0000 83 H2PO4- 0.37535E-10 -10.4256 0.31315E-10 -10.5042 0.83429E+00 -0.0787 84 PO4-3 0.99689E-09 -9.0014 0.23778E-09 -9.6238 0.23852E+00 -0.6225 88 HP2O7-3 0.88597E-18 -18.0526 0.20118E-18 -18.6964 0.22707E+00 -0.6438 89 P2O7-4 0.84313E-17 -17.0741 0.62972E-18 -18.2009 0.74688E-01 -1.1268 90 H2S,aq 0.40338E-07 -7.3943 0.40189E-07 -7.3959 0.99631E+00 -0.0016 91 S2-2 0.10804E-12 -12.9664 0.55537E-13 -13.2554 0.51405E+00 -0.2890 97 SO3-2 0.75460E-17 -17.1223 0.39365E-17 -17.4049 0.52166E+00 -0.2826 98 HSO3- 0.22569E-19 -19.6465 0.18811E-19 -19.7256 0.83348E+00 -0.0791 99 HSO4- 0.23011E-18 -18.6381 0.19236E-18 -18.7159 0.83595E+00 -0.0778 Charge balance for all species = 0.4176E-09 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.9100389E-10 -.2178970E-01 -.2192388E+02 0.0000 2 H2O 0.1000000E+01 0.5550500E+02 0.9981711E+06 0.0000 3 Cl- 0.1100747E-02 0.1105937E-02 0.3913945E+02 7.0799 4 SO4-- 0.5076790E-11 -.1023082E-03 -.9810514E+01 8.6523 5 HCO3- 0.1874848E-05 0.1047630E-03 0.6381044E+01 4.3119 6 HS- 0.2043916E-03 0.3067402E-03 0.1012657E+02 6.3488 7 Al+++ 0.1074408E-28 0.5178341E-05 0.1394724E+00 0.7390 8 H4SiO4 0.6959841E-03 0.1326193E-01 0.1272422E+04 -3.1574 9 Ca++ 0.1440237E-06 0.2452529E-06 0.9811865E-02 13.1018 10 Mg++ 0.2253396E-10 0.9689266E-10 0.2351489E-05 9.2942 11 Fe++ 0.6210642E-13 0.3535610E-07 0.1971041E-02 6.7350 12 K+ 0.1613350E-03 0.1620910E-03 0.6326873E+01 6.2467 13 Na+ 0.2047354E-01 0.2292442E-01 0.5260959E+03 8.3494 14 Mn++ 0.1993842E-10 0.2536533E-08 0.1391056E-03 9.2419 15 HPO4-- 0.4316943E-07 0.4420386E-07 0.4235140E-02 12.5819 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.1440591E+03 -.2718434E-02 -.1440563E+03 0.0000000E+00 2 H2O -.5354981E+02 0.6924678E+01 -.6047448E+02 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.2411321E+00 -.1276374E-04 0.2411449E+00 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.2411066E+00 0.3826821E-04 -.2411449E+00 0.0000000E+00 7 Al+++ 0.2836845E+02 0.6460381E-06 0.2836845E+02 0.0000000E+00 8 H4SiO4 0.9059120E+02 0.1654529E-02 0.9058955E+02 0.0000000E+00 9 Ca++ 0.1000625E+02 0.3059719E-07 0.1000625E+02 0.0000000E+00 10 Mg++ 0.6904761E+01 0.1208811E-10 0.6904761E+01 0.0000000E+00 11 Fe++ 0.6203174E+01 0.4410947E-08 0.6203174E+01 0.0000000E+00 12 K+ 0.1847134E+01 0.2022210E-04 0.1847113E+01 0.0000000E+00 13 Na+ 0.1092078E+02 0.2859999E-02 0.1091792E+02 0.0000000E+00 14 Mn++ 0.1508458E+00 0.3164521E-09 0.1508458E+00 0.0000000E+00 15 HPO4-- 0.5148291E-01 0.5514773E-08 0.5148291E-01 0.0000000E+00 Chg. balance for solid moles: -.3605E-13 Mass of aqueous solution: 0.124979E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 8699.9990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 10.91 1.038 2860. 3.456 30.10 1098. andradite 0.9646 -0.016 490.2 2.690 5.157 127.4 grossular 0.2336 -0.632 105.2 2.022 1.107 29.27 apatite-OH 0.1716E-01 -1.765 8.620 0.936 0.9070E-01 2.739 clinochlore 1.235 0.092 686.4 2.837 7.222 261.1 daphnite 0.3575 -0.447 255.1 2.407 2.684 77.30 chlorite-Mn 0.3017E-01 -1.520 21.39 1.330 0.2250 6.816 diopside 0.4639 -0.334 100.5 2.002 1.057 30.71 hedenbergite 0.1203 -0.920 29.85 1.475 0.3141 8.176 microcline 1.620 0.209 450.8 2.654 4.743 176.1 stilbite 5.595 0.748 3943. 3.596 41.49 1839. stilpnomelane-Fe 0.4549 -0.342 490.4 2.691 5.159 169.4 tr.625ac.25prg.125 0.7333E-01 -1.135 62.68 1.797 0.6595 20.17 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8051E+00 0.8051E+00 1.0000 -0.094 grossular 0.1949E+00 0.1949E+00 1.0000 -0.710 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.7611E+00 0.7611E+00 1.0000 -0.119 daphnite 0.2203E+00 0.2203E+00 1.0000 -0.657 chlorite-Mn 0.1859E-01 0.1859E-01 1.0000 -1.731 diopside 0.7941E+00 0.7941E+00 1.0000 -0.100 hedenbergite 0.2059E+00 0.2059E+00 1.0000 -0.686 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 tr.625ac.25prg.125 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 9504.612382 g Volume = 3846.291192 cm3 Porosity: -10.4939% V(tot) - V(min): -.36529E+03 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 8699.9990000 g log = 3.9395 Original solution: 1000.0103000 g Original solution / Rock added: 0.11 (Water/Rock Ratio), log = -0.9395 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.1817 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.8651E+00 0.9840 0.1006E+01 0.1022E+01 CO2,gas 0.2298E-07 1.0053 0.2731E-07 0.2716E-07 CH4,gas 0.1220E+00 1.0110 0.1458E+00 0.1442E+00 H2,gas 0.1286E-01 1.0006 0.1521E-01 0.1520E-01 H2S,gas 0.9392E-06 0.9954 0.1105E-05 0.1110E-05 S2,gas 0.1677E-27 1.0000 0.1981E-27 0.1981E-27 CO,gas 0.9364E-13 1.0000 0.1107E-12 0.1107E-12 SO3,gas 0.4874E-47 1.0000 0.5760E-47 0.5760E-47 SO2,gas 0.2884E-26 1.0000 0.3408E-26 0.3408E-26 HCl,gas 0.1916E-16 1.0000 0.2264E-16 0.2264E-16 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 16 albite -0.38 -0.38 0.00 0.000 -0.94784E-12 22 andradite 39.01 39.01 0.00 0.000 0.12132E-10 23 grossular 32.73 32.73 0.00 0.000 0.24265E-10 32 apatite-OH -18.15 -18.15 0.00 0.000 0.60662E-11 46 clinochlore 39.07 39.07 0.00 0.000 -0.36397E-10 47 daphnite 28.97 28.97 0.00 0.000 -0.60662E-10 48 chlorite-Mn 46.87 46.87 0.00 0.000 -0.36397E-10 67 diopside 16.18 16.18 0.00 0.000 0.60662E-11 68 hedenbergite 14.21 14.21 0.00 0.000 0.00000E+00 116 microcline -2.49 -2.49 0.00 0.000 0.15165E-11 163 stilbite -7.52 -7.52 0.00 0.000 0.15165E-10 164 stilpnomelane-Fe 13.02 13.02 0.00 0.000 0.21232E-10 245 tr.625ac.25prg.125 45.16 45.16 0.00 0.000 0.48529E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -15.92 -9.26 -3.088 0.15816E+05 -7.564 3 CH4,gas 4.54 2.01 -2.54 -0.634 0.43289E+04 -0.836 4 H2,gas 8.00 4.48 -3.52 -2.010 0.60051E+04 -1.818 5 H2S,gas -6.23 -13.89 -7.66 -3.828 0.13072E+05 -5.957 6 S2,gas -7.34 -36.74 -29.40 -4.523 0.50203E+05 -27.703 7 CO,gas 3.21 -11.44 -14.65 -4.509 0.25023E+05 -12.956 8 SO3,gas 17.12 -31.82 -48.94 -12.235 0.83561E+05 -47.240 9 SO2,gas 0.83 -27.33 -28.17 -7.511 0.48094E+05 -26.468 10 HCl,gas 5.19 -13.15 -18.34 -9.172 0.31322E+05 -16.645 11 acmite 7.71 6.53 -1.18 -0.123 0.20175E+04 15 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 19 spessartine 24.46 19.73 -4.73 -0.236 0.80694E+04 20 analcite 3.32 2.77 -0.55 -0.061 0.93626E+03 26 annite 20.12 17.72 -2.40 -0.134 0.41064E+04 27 phlogopite 27.06 25.40 -1.67 -0.093 0.28490E+04 29 anorthite 12.71 8.26 -4.45 -0.342 0.75903E+04 35 aragonite 0.97 -2.82 -3.79 -1.263 0.64671E+04 36 brucite 12.57 9.29 -3.27 -0.655 0.55909E+04 37 calcite 0.81 -2.82 -3.63 -1.211 0.62029E+04 38 carnegieite-low 9.02 5.93 -3.09 -0.442 0.52801E+04 39 carnegieite-high 10.09 5.93 -4.16 -0.595 0.71071E+04 40 carpholite-Mg 8.58 4.46 -4.12 -0.275 0.70429E+04 41 carpholite-Fe 6.71 1.90 -4.81 -0.321 0.82207E+04 42 celadonite 5.34 3.65 -1.69 -0.099 0.28879E+04 43 celadonite-Fe 3.88 1.09 -2.79 -0.164 0.47561E+04 44 chrysotile 23.89 21.57 -2.32 -0.194 0.39692E+04 49 chlorite-Al-free 47.17 43.14 -4.04 -0.168 0.68936E+04 51 chloritoid-Fe 9.17 5.06 -4.12 -0.275 0.70316E+04 52 chloritoid-Mn 11.40 7.56 -3.84 -0.256 0.65544E+04 54 coesite -2.38 -3.16 -0.78 -0.260 0.13341E+04 61 cristobalite -2.56 -3.16 -0.60 -0.199 0.10195E+04 63 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71234E+04 65 diaspore 2.87 0.74 -2.13 -0.356 0.36450E+04 66 diamond -3.10 -6.96 -3.85 -1.101 0.65820E+04 71 enstatite 17.26 12.27 -4.99 -0.499 0.85226E+04 73 clinoenstatite 17.17 12.27 -4.89 -0.489 0.83542E+04 75 epidote 24.67 22.70 -1.97 -0.095 0.33586E+04 76 clinozoisite 22.81 18.95 -3.86 -0.175 0.65869E+04 77 epidote-Fe 29.84 26.46 -3.38 -0.176 0.57768E+04 78 fayalite 14.05 10.31 -3.73 -0.533 0.63743E+04 79 ferrosilite 11.15 7.16 -3.99 -0.399 0.68202E+04 83 gibbsite 4.08 0.74 -3.34 -0.477 0.57036E+04 84 glaucophane 22.97 20.80 -2.17 -0.059 0.37134E+04 85 glaucophane-Fe 17.28 13.12 -4.15 -0.112 0.70919E+04 86 graphite -3.55 -6.96 -3.41 -0.975 0.58243E+04 87 greenalite 16.14 13.89 -2.25 -0.187 0.38408E+04 90 hematite 12.57 8.99 -3.58 -0.434 0.61111E+04 91 heulandite -5.83 -7.52 -1.69 -0.077 0.28938E+04 95 jadeite 4.22 2.77 -1.44 -0.144 0.24617E+04 97 kalsilite 7.58 3.83 -3.76 -0.537 0.64126E+04 98 kaolinite -1.33 -4.84 -3.50 -0.319 0.59832E+04 101 laumontite 2.88 1.95 -0.93 -0.062 0.15935E+04 102 lawsonite 9.62 8.26 -1.35 -0.090 0.23070E+04 103 leucite 4.12 0.67 -3.45 -0.345 0.58873E+04 105 lizardite 23.24 21.57 -1.68 -0.140 0.28619E+04 107 magnetite 20.09 15.72 -4.37 -0.356 0.74536E+04 108 minnesotaite 10.39 7.58 -2.81 -0.165 0.48027E+04 112 manganosite 14.06 9.24 -4.82 -1.204 0.82236E+04 120 muscovite 2.58 -1.01 -3.59 -0.211 0.61315E+04 121 paragonite 4.24 1.09 -3.15 -0.185 0.53706E+04 122 nepheline 8.34 5.93 -2.41 -0.344 0.41125E+04 128 periclase-Fe 11.63 6.73 -4.89 -1.223 0.83523E+04 134 phlogopite-Na 29.65 27.50 -2.15 -0.119 0.36678E+04 136 prehnite 19.37 18.21 -1.16 -0.068 0.19849E+04 137 prehnite-Fe 22.50 21.96 -0.53 -0.032 0.91159E+03 138 pumpellyite-Fe 46.27 43.89 -2.38 -0.053 0.40582E+04 139 pumpellyite-Mg 48.99 46.45 -2.54 -0.057 0.43421E+04 142 pyrite -21.25 -25.52 -4.27 -1.005 0.72957E+04 143 pyrrhotite -4.26 -7.15 -2.89 -0.964 0.49357E+04 144 pyrrhotiteFe0.875 -6.02 -8.55 -2.53 -0.931 0.43229E+04 145 pyroxmangite 7.40 6.08 -1.31 -0.263 0.22439E+04 146 pyrophyllite -6.18 -11.15 -4.98 -0.311 0.84962E+04 147 quartz -2.99 -3.16 -0.17 -0.056 0.28679E+03 152 rhodonite 7.45 6.08 -1.36 -0.272 0.23242E+04 153 sanidine -1.28 -2.49 -1.21 -0.093 0.20677E+04 165 stilpnomelane-Mg 27.44 25.81 -1.63 -0.049 0.27804E+04 171 talc 16.49 15.25 -1.24 -0.073 0.21140E+04 174 tephroite 18.09 15.33 -2.76 -0.394 0.47116E+04 178 tridymite -2.63 -3.16 -0.53 -0.177 0.90677E+03 179 tremolite 47.87 47.42 -0.45 -0.012 0.77494E+03 180 ferroactinolite 38.45 34.62 -3.83 -0.104 0.65448E+04 181 troilite-low -4.41 -7.15 -2.74 -0.913 0.46785E+04 183 vesuvianite 223.47 218.82 -4.65 -0.036 0.79441E+04 187 wairakite 3.95 1.95 -2.00 -0.118 0.34155E+04 188 walstromite 11.51 9.94 -1.56 -0.313 0.26719E+04 189 wollastonite 10.46 9.94 -0.52 -0.103 0.88229E+03 190 pseudo-wollastonite 11.00 9.94 -1.06 -0.211 0.18021E+04 191 zoisite 22.85 18.95 -3.90 -0.177 0.66610E+04 192 akaganeite 7.75 4.49 -3.26 -0.705 0.55681E+04 199 chalcedony -2.80 -3.16 -0.35 -0.118 0.60609E+03 201 montmorillonite-Ca -2.29 -6.17 -3.88 -0.240 0.66180E+04 202 montmorillonite-K -2.24 -6.27 -4.03 -0.247 0.68816E+04 203 montmorillonite-Mg -2.48 -6.79 -4.32 -0.267 0.73678E+04 204 montmorillonite-Na -2.04 -5.57 -3.54 -0.216 0.60365E+04 205 nontronite-Ca 3.21 -0.19 -3.41 -0.221 0.58215E+04 206 nontronite-H 2.53 -2.36 -4.89 -0.328 0.83484E+04 207 nontronite-K 3.34 -0.30 -3.64 -0.233 0.62083E+04 208 nontronite-Mg 3.07 -0.82 -3.90 -0.253 0.66553E+04 209 nontronite-Na 3.52 0.40 -3.12 -0.200 0.53291E+04 224 tobermorite 9.82 7.76 -2.07 -0.564 0.35287E+04 230 alabandite -0.98 -4.64 -3.67 -1.222 0.62599E+04 233 boehmite 4.41 0.74 -3.67 -0.611 0.62619E+04 235 ferrous-oxide 9.81 6.73 -3.08 -0.769 0.52532E+04 240 silica-amorphous -2.09 -3.16 -1.07 -0.355 0.18203E+04 242 an20ab80 2.02 1.35 -0.67 -0.052 0.11472E+04 243 an25ab75 2.65 1.78 -0.87 -0.067 0.14810E+04 244 an30ab70 3.28 2.21 -1.07 -0.082 0.18244E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 100.0000000 g Current total amount of reactant added: 8699.9990000 g New total amount of reactant added: 8799.9990000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.5205E-10 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 13 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 8799.9990000 Water: Moles liquid = 0.6368E+01 kg liquid = 0.1147E+00 Moles total = -.5480E+02 kg total = -.9873E+00 Activity = 1.0000 Stoichiometric ionic strength = .1220289E-01 Osmotic coef. = 0.9671 True ionic strength = .2070289E-01 Chg. balance for total moles = 0.5205E-10 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.91283E-10 -10.0396 0.76539E-10 -10.1161 0.83848E+00 -0.0765 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.11971E-02 -2.9219 0.99755E-03 -3.0011 0.83331E+00 -0.0792 4 SO4-- 0.55087E-11 -11.2589 0.28356E-11 -11.5474 0.51474E+00 -0.2884 5 HCO3- 0.20339E-05 -5.6917 0.16974E-05 -5.7702 0.83456E+00 -0.0785 6 HS- 0.22228E-03 -3.6531 0.18526E-03 -3.7322 0.83343E+00 -0.0791 7 Al+++ 0.10857E-28 -28.9643 0.24582E-29 -29.6094 0.22641E+00 -0.6451 8 H4SiO4 0.69598E-03 -3.1574 0.69598E-03 -3.1574 0.10000E+01 0.0000 9 Ca++ 0.14497E-06 -6.8387 0.74062E-07 -7.1304 0.51086E+00 -0.2917 10 Mg++ 0.22683E-10 -10.6443 0.11533E-10 -10.9380 0.50846E+00 -0.2937 11 Fe++ 0.62517E-13 -13.2040 0.31823E-13 -13.4973 0.50904E+00 -0.2933 12 K+ 0.16183E-03 -3.7909 0.13509E-03 -3.8694 0.83476E+00 -0.0784 13 Na+ 0.20537E-01 -1.6875 0.17110E-01 -1.7667 0.83315E+00 -0.0793 14 Mn++ 0.20070E-10 -10.6974 0.10225E-10 -10.9903 0.50947E+00 -0.2929 15 HPO4-- 0.42957E-07 -7.3670 0.22115E-07 -7.6553 0.51482E+00 -0.2883 16 HSiO3- 0.10189E-01 -1.9919 0.84907E-02 -2.0711 0.83331E+00 -0.0792 17 Ca(HSiO3)+ 0.17152E-07 -7.7657 0.14321E-07 -7.8440 0.83494E+00 -0.0783 18 Mg(HSiO3)+ 0.33241E-11 -11.4783 0.27755E-11 -11.5567 0.83494E+00 -0.0783 19 NaHSiO3,aq 0.23496E-02 -2.6290 0.23496E-02 -2.6290 0.10000E+01 0.0000 20 AlO+ 0.68370E-16 -16.1651 0.57085E-16 -16.2435 0.83494E+00 -0.0783 22 HAlO2,aq 0.14853E-09 -9.8282 0.14853E-09 -9.8282 0.10000E+01 0.0000 23 AlO2- 0.51645E-05 -5.2870 0.42956E-05 -5.3670 0.83176E+00 -0.0800 24 CH4,aq 0.10813E-03 -3.9661 0.10773E-03 -3.9677 0.99628E+00 -0.0016 25 C2H6,aq 0.17193E-12 -12.7647 0.17129E-12 -12.7663 0.99628E+00 -0.0016 29 CO,aq 0.80773E-16 -16.0927 0.80773E-16 -16.0927 0.10000E+01 0.0000 30 CO2,aq 0.27865E-09 -9.5549 0.27761E-09 -9.5566 0.99628E+00 -0.0016 31 CO3-2 0.37714E-05 -5.4235 0.19371E-05 -5.7128 0.51362E+00 -0.2894 32 CaCO3,aq 0.17989E-08 -8.7450 0.17989E-08 -8.7450 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.38434E-11 -11.4153 0.32090E-11 -11.4936 0.83494E+00 -0.0783 34 CaCl+ 0.14320E-09 -9.8441 0.11956E-09 -9.9224 0.83494E+00 -0.0783 35 CaCl2,aq 0.28336E-13 -13.5477 0.28336E-13 -13.5477 0.10000E+01 0.0000 36 CaOH+ 0.82595E-07 -7.0830 0.68962E-07 -7.1614 0.83494E+00 -0.0783 37 CaSO4,aq 0.66688E-16 -16.1760 0.66688E-16 -16.1760 0.10000E+01 0.0000 38 HCl,aq 0.13991E-13 -13.8541 0.13991E-13 -13.8541 0.10000E+01 0.0000 43 FeCl+ 0.60181E-16 -16.2205 0.50247E-16 -16.2989 0.83494E+00 -0.0783 46 FeO,aq 0.21112E-09 -9.6755 0.21112E-09 -9.6755 0.10000E+01 0.0000 47 FeOH+ 0.16209E-10 -10.7902 0.13534E-10 -10.8686 0.83494E+00 -0.0783 48 HFeO2- 0.34635E-07 -7.4605 0.28861E-07 -7.5397 0.83331E+00 -0.0792 49 FeO+ 0.11360E-16 -16.9446 0.94853E-17 -17.0229 0.83494E+00 -0.0783 51 FeO2- 0.39758E-09 -9.4006 0.33131E-09 -9.4798 0.83331E+00 -0.0792 52 HFeO2,aq 0.32252E-11 -11.4914 0.32252E-11 -11.4914 0.10000E+01 0.0000 53 H2,aq 0.11626E-04 -4.9346 0.11582E-04 -4.9362 0.99628E+00 -0.0016 54 KCl,aq 0.24424E-08 -8.6122 0.24424E-08 -8.6122 0.10000E+01 0.0000 56 KOH,aq 0.75375E-06 -6.1228 0.75375E-06 -6.1228 0.10000E+01 0.0000 57 KSO4- 0.71333E-14 -14.1467 0.59442E-14 -14.2259 0.83331E+00 -0.0792 58 MgCO3,aq 0.70218E-13 -13.1536 0.70218E-13 -13.1536 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.61158E-15 -15.2135 0.51063E-15 -15.2919 0.83494E+00 -0.0783 60 MgCl+ 0.20211E-13 -13.6944 0.16875E-13 -13.7728 0.83494E+00 -0.0783 61 MgOH+ 0.71174E-10 -10.1477 0.59426E-10 -10.2260 0.83494E+00 -0.0783 63 MnO,aq 0.18076E-08 -8.7429 0.18076E-08 -8.7429 0.10000E+01 0.0000 64 MnOH+ 0.48383E-09 -9.3153 0.40397E-09 -9.3936 0.83494E+00 -0.0783 65 MnO2-2 0.19937E-10 -10.7003 0.10240E-10 -10.9897 0.51362E+00 -0.2894 66 HMnO2- 0.20606E-09 -9.6860 0.17171E-09 -9.7652 0.83331E+00 -0.0792 69 MnCl+ 0.75229E-13 -13.1236 0.62812E-13 -13.2020 0.83494E+00 -0.0783 71 NaCl,aq 0.56564E-05 -5.2475 0.56564E-05 -5.2475 0.10000E+01 0.0000 72 NaOH,aq 0.96046E-04 -4.0175 0.96046E-04 -4.0175 0.10000E+01 0.0000 74 OH- 0.90755E-02 -2.0421 0.75487E-02 -2.1221 0.83176E+00 -0.0800 79 HPO3-2 0.15541E-14 -14.8085 0.79824E-15 -15.0979 0.51362E+00 -0.2894 81 H2PO3- 0.14703E-18 -18.8326 0.12252E-18 -18.9118 0.83331E+00 -0.0792 82 H3PO4,aq 0.90612E-18 -18.0428 0.90612E-18 -18.0428 0.10000E+01 0.0000 83 H2PO4- 0.37435E-10 -10.4267 0.31226E-10 -10.5055 0.83412E+00 -0.0788 84 PO4-3 0.99007E-09 -9.0043 0.23574E-09 -9.6276 0.23811E+00 -0.6232 88 HP2O7-3 0.88001E-18 -18.0555 0.19945E-18 -18.7002 0.22664E+00 -0.6447 89 P2O7-4 0.83622E-17 -17.0777 0.62253E-18 -18.2058 0.74446E-01 -1.1282 90 H2S,aq 0.43987E-07 -7.3567 0.43824E-07 -7.3583 0.99628E+00 -0.0016 91 S2-2 0.12784E-12 -12.8933 0.65659E-13 -13.1827 0.51362E+00 -0.2894 97 SO3-2 0.81878E-17 -17.0868 0.42679E-17 -17.3698 0.52125E+00 -0.2830 98 HSO3- 0.24545E-19 -19.6100 0.20453E-19 -19.6892 0.83331E+00 -0.0792 99 HSO4- 0.25026E-18 -18.6016 0.20916E-18 -18.6795 0.83578E+00 -0.0779 Charge balance for all species = 0.4533E-09 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.9128330E-10 -.2173864E-01 -.2187243E+02 0.0000 2 H2O 0.1000000E+01 0.5550501E+02 0.9981681E+06 0.0000 3 Cl- 0.1197096E-02 0.1202755E-02 0.4256574E+02 7.1150 4 SO4-- 0.5508746E-11 -.1110333E-03 -.1064714E+02 8.6849 5 HCO3- 0.2033938E-05 0.1139344E-03 0.6939645E+01 4.3459 6 HS- 0.2222848E-03 0.3333621E-03 0.1100542E+02 6.3839 7 Al+++ 0.1085729E-28 0.5164603E-05 0.1391019E+00 0.7390 8 H4SiO4 0.6959841E-03 0.1323478E-01 0.1269813E+04 -3.1574 9 Ca++ 0.1449739E-06 0.2466671E-06 0.9868414E-02 13.1018 10 Mg++ 0.2268289E-10 0.9726867E-10 0.2360607E-05 9.2942 11 Fe++ 0.6251674E-13 0.3526280E-07 0.1965833E-02 6.7350 12 K+ 0.1618320E-03 0.1625882E-03 0.6346261E+01 6.2467 13 Na+ 0.2053671E-01 0.2298806E-01 0.5275547E+03 8.3494 14 Mn++ 0.2007034E-10 0.2537539E-08 0.1391604E-03 9.2419 15 HPO4-- 0.4295731E-07 0.4398482E-07 0.4214140E-02 12.5769 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.1457149E+03 -.2493750E-02 -.1457124E+03 0.0000000E+00 2 H2O -.5480335E+02 0.6367263E+01 -.6117061E+02 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.2439035E+00 -.1273720E-04 0.2439162E+00 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.2438780E+00 0.3824167E-04 -.2439162E+00 0.0000000E+00 7 Al+++ 0.2869452E+02 0.5924579E-06 0.2869452E+02 0.0000000E+00 8 H4SiO4 0.9163248E+02 0.1518230E-02 0.9163096E+02 0.0000000E+00 9 Ca++ 0.1012127E+02 0.2829645E-07 0.1012127E+02 0.0000000E+00 10 Mg++ 0.6984126E+01 0.1115819E-10 0.6984126E+01 0.0000000E+00 11 Fe++ 0.6274475E+01 0.4045176E-08 0.6274475E+01 0.0000000E+00 12 K+ 0.1868365E+01 0.1865132E-04 0.1868346E+01 0.0000000E+00 13 Na+ 0.1104630E+02 0.2637077E-02 0.1104367E+02 0.0000000E+00 14 Mn++ 0.1525796E+00 0.2910941E-09 0.1525796E+00 0.0000000E+00 15 HPO4-- 0.5207467E-01 0.5045723E-08 0.5207466E-01 0.0000000E+00 Chg. balance for solid moles: 0.2212E-13 Mass of aqueous solution: 0.114919E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 8799.9990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 11.03 1.043 2893. 3.461 30.10 1111. andradite 0.9757 -0.011 495.8 2.695 5.157 128.8 grossular 0.2362 -0.627 106.4 2.027 1.107 29.61 apatite-OH 0.1736E-01 -1.760 8.719 0.940 0.9070E-01 2.771 clinochlore 1.249 0.097 694.3 2.842 7.222 264.1 daphnite 0.3616 -0.442 258.0 2.412 2.684 78.19 chlorite-Mn 0.3052E-01 -1.515 21.63 1.335 0.2250 6.894 diopside 0.4694 -0.328 101.6 2.007 1.057 31.07 hedenbergite 0.1217 -0.915 30.20 1.480 0.3141 8.272 microcline 1.638 0.214 456.0 2.659 4.743 178.1 stilbite 5.659 0.753 3988. 3.601 41.48 1860. stilpnomelane-Fe 0.4601 -0.337 496.0 2.695 5.159 171.3 tr.625ac.25prg.125 0.7417E-01 -1.130 63.39 1.802 0.6594 20.40 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8051E+00 0.8051E+00 1.0000 -0.094 grossular 0.1949E+00 0.1949E+00 1.0000 -0.710 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.7611E+00 0.7611E+00 1.0000 -0.119 daphnite 0.2203E+00 0.2203E+00 1.0000 -0.657 chlorite-Mn 0.1859E-01 0.1859E-01 1.0000 -1.731 diopside 0.7941E+00 0.7941E+00 1.0000 -0.100 hedenbergite 0.2059E+00 0.2059E+00 1.0000 -0.686 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 tr.625ac.25prg.125 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 9613.863036 g Volume = 3890.494251 cm3 Porosity: -10.4940% V(tot) - V(min): -.36949E+03 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 8799.9990000 g log = 3.9445 Original solution: 1000.0103000 g Original solution / Rock added: 0.11 (Water/Rock Ratio), log = -0.9445 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.1946 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.8560E+00 0.9838 0.1006E+01 0.1022E+01 CO2,gas 0.2474E-07 1.0052 0.2970E-07 0.2955E-07 CH4,gas 0.1313E+00 1.0108 0.1586E+00 0.1569E+00 H2,gas 0.1272E-01 1.0006 0.1521E-01 0.1520E-01 H2S,gas 0.1013E-05 0.9954 0.1205E-05 0.1210E-05 S2,gas 0.1972E-27 1.0000 0.2356E-27 0.2356E-27 CO,gas 0.1008E-12 1.0000 0.1204E-12 0.1204E-12 SO3,gas 0.5258E-47 1.0000 0.6281E-47 0.6281E-47 SO2,gas 0.3111E-26 1.0000 0.3716E-26 0.3716E-26 HCl,gas 0.2067E-16 1.0000 0.2469E-16 0.2469E-16 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 16 albite -0.38 -0.38 0.00 0.000 -0.13080E-10 22 andradite 39.01 39.01 0.00 0.000 0.12132E-10 23 grossular 32.73 32.73 0.00 0.000 -0.12132E-10 32 apatite-OH -18.15 -18.15 0.00 0.000 0.00000E+00 46 clinochlore 39.07 39.07 0.00 0.000 -0.12132E-10 47 daphnite 28.97 28.97 0.00 0.000 0.00000E+00 48 chlorite-Mn 46.87 46.87 0.00 0.000 0.12132E-10 67 diopside 16.18 16.18 0.00 0.000 -0.60662E-11 68 hedenbergite 14.21 14.21 0.00 0.000 -0.60662E-11 116 microcline -2.49 -2.49 0.00 0.000 0.15165E-11 163 stilbite -7.52 -7.52 0.00 0.000 -0.90992E-11 164 stilpnomelane-Fe 13.02 13.02 0.00 0.000 -0.27298E-10 245 tr.625ac.25prg.125 45.16 45.16 0.00 0.000 -0.97059E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -15.89 -9.23 -3.075 0.15753E+05 -7.527 3 CH4,gas 4.54 2.04 -2.50 -0.625 0.42666E+04 -0.800 4 H2,gas 8.00 4.48 -3.52 -2.010 0.60051E+04 -1.818 5 H2S,gas -6.23 -13.85 -7.62 -3.809 0.13008E+05 -5.919 6 S2,gas -7.34 -36.66 -29.33 -4.512 0.50075E+05 -27.628 7 CO,gas 3.21 -11.40 -14.62 -4.498 0.24961E+05 -12.919 8 SO3,gas 17.12 -31.78 -48.90 -12.225 0.83497E+05 -47.202 9 SO2,gas 0.83 -27.30 -28.13 -7.501 0.48029E+05 -26.430 10 HCl,gas 5.19 -13.12 -18.31 -9.153 0.31258E+05 -16.608 11 acmite 7.71 6.53 -1.18 -0.123 0.20175E+04 15 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 19 spessartine 24.46 19.73 -4.73 -0.236 0.80693E+04 20 analcite 3.32 2.77 -0.55 -0.061 0.93626E+03 26 annite 20.12 17.72 -2.40 -0.134 0.41064E+04 27 phlogopite 27.06 25.40 -1.67 -0.093 0.28490E+04 29 anorthite 12.71 8.26 -4.45 -0.342 0.75903E+04 35 aragonite 0.97 -2.78 -3.75 -1.250 0.64048E+04 36 brucite 12.57 9.29 -3.27 -0.655 0.55909E+04 37 calcite 0.81 -2.78 -3.60 -1.199 0.61405E+04 38 carnegieite-low 9.02 5.93 -3.09 -0.442 0.52801E+04 39 carnegieite-high 10.09 5.93 -4.16 -0.595 0.71071E+04 40 carpholite-Mg 8.58 4.46 -4.12 -0.275 0.70429E+04 41 carpholite-Fe 6.71 1.90 -4.81 -0.321 0.82207E+04 42 celadonite 5.34 3.65 -1.69 -0.099 0.28879E+04 43 celadonite-Fe 3.88 1.09 -2.79 -0.164 0.47561E+04 44 chrysotile 23.89 21.57 -2.32 -0.194 0.39692E+04 49 chlorite-Al-free 47.17 43.14 -4.04 -0.168 0.68936E+04 51 chloritoid-Fe 9.17 5.06 -4.12 -0.275 0.70316E+04 52 chloritoid-Mn 11.40 7.56 -3.84 -0.256 0.65544E+04 54 coesite -2.38 -3.16 -0.78 -0.260 0.13341E+04 61 cristobalite -2.56 -3.16 -0.60 -0.199 0.10195E+04 63 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71234E+04 65 diaspore 2.87 0.74 -2.13 -0.356 0.36450E+04 66 diamond -3.10 -6.92 -3.82 -1.091 0.65197E+04 71 enstatite 17.26 12.27 -4.99 -0.499 0.85226E+04 73 clinoenstatite 17.17 12.27 -4.89 -0.489 0.83542E+04 75 epidote 24.67 22.70 -1.97 -0.095 0.33586E+04 76 clinozoisite 22.81 18.95 -3.86 -0.175 0.65869E+04 77 epidote-Fe 29.84 26.46 -3.38 -0.176 0.57768E+04 78 fayalite 14.05 10.31 -3.73 -0.533 0.63743E+04 79 ferrosilite 11.15 7.16 -3.99 -0.399 0.68202E+04 83 gibbsite 4.08 0.74 -3.34 -0.477 0.57036E+04 84 glaucophane 22.97 20.80 -2.17 -0.059 0.37134E+04 85 glaucophane-Fe 17.28 13.12 -4.15 -0.112 0.70919E+04 86 graphite -3.55 -6.92 -3.37 -0.964 0.57619E+04 87 greenalite 16.14 13.89 -2.25 -0.187 0.38408E+04 90 hematite 12.57 8.99 -3.58 -0.434 0.61111E+04 91 heulandite -5.83 -7.52 -1.69 -0.077 0.28938E+04 95 jadeite 4.22 2.77 -1.44 -0.144 0.24617E+04 97 kalsilite 7.58 3.83 -3.76 -0.537 0.64126E+04 98 kaolinite -1.33 -4.84 -3.50 -0.319 0.59832E+04 101 laumontite 2.88 1.95 -0.93 -0.062 0.15935E+04 102 lawsonite 9.62 8.26 -1.35 -0.090 0.23070E+04 103 leucite 4.12 0.67 -3.45 -0.345 0.58873E+04 105 lizardite 23.24 21.57 -1.68 -0.140 0.28619E+04 107 magnetite 20.09 15.72 -4.37 -0.356 0.74536E+04 108 minnesotaite 10.39 7.58 -2.81 -0.165 0.48027E+04 112 manganosite 14.06 9.24 -4.82 -1.204 0.82235E+04 120 muscovite 2.58 -1.01 -3.59 -0.211 0.61315E+04 121 paragonite 4.24 1.09 -3.15 -0.185 0.53706E+04 122 nepheline 8.34 5.93 -2.41 -0.344 0.41125E+04 128 periclase-Fe 11.63 6.73 -4.89 -1.223 0.83523E+04 134 phlogopite-Na 29.65 27.50 -2.15 -0.119 0.36678E+04 136 prehnite 19.37 18.21 -1.16 -0.068 0.19849E+04 137 prehnite-Fe 22.50 21.96 -0.53 -0.032 0.91159E+03 138 pumpellyite-Fe 46.27 43.89 -2.38 -0.053 0.40582E+04 139 pumpellyite-Mg 48.99 46.45 -2.54 -0.057 0.43421E+04 142 pyrite -21.25 -25.44 -4.20 -0.988 0.71672E+04 143 pyrrhotite -4.26 -7.11 -2.85 -0.951 0.48715E+04 144 pyrrhotiteFe0.875 -6.02 -8.51 -2.49 -0.917 0.42587E+04 145 pyroxmangite 7.40 6.08 -1.31 -0.263 0.22439E+04 146 pyrophyllite -6.18 -11.15 -4.98 -0.311 0.84962E+04 147 quartz -2.99 -3.16 -0.17 -0.056 0.28679E+03 152 rhodonite 7.45 6.08 -1.36 -0.272 0.23242E+04 153 sanidine -1.28 -2.49 -1.21 -0.093 0.20677E+04 165 stilpnomelane-Mg 27.44 25.81 -1.63 -0.049 0.27804E+04 171 talc 16.49 15.25 -1.24 -0.073 0.21140E+04 174 tephroite 18.09 15.33 -2.76 -0.394 0.47116E+04 178 tridymite -2.63 -3.16 -0.53 -0.177 0.90677E+03 179 tremolite 47.87 47.42 -0.45 -0.012 0.77494E+03 180 ferroactinolite 38.45 34.62 -3.83 -0.104 0.65448E+04 181 troilite-low -4.41 -7.11 -2.70 -0.901 0.46143E+04 183 vesuvianite 223.47 218.82 -4.65 -0.036 0.79441E+04 187 wairakite 3.95 1.95 -2.00 -0.118 0.34155E+04 188 walstromite 11.51 9.94 -1.56 -0.313 0.26719E+04 189 wollastonite 10.46 9.94 -0.52 -0.103 0.88229E+03 190 pseudo-wollastonite 11.00 9.94 -1.06 -0.211 0.18021E+04 191 zoisite 22.85 18.95 -3.90 -0.177 0.66610E+04 192 akaganeite 7.75 4.49 -3.26 -0.705 0.55681E+04 199 chalcedony -2.80 -3.16 -0.35 -0.118 0.60609E+03 201 montmorillonite-Ca -2.29 -6.17 -3.88 -0.240 0.66180E+04 202 montmorillonite-K -2.24 -6.27 -4.03 -0.247 0.68816E+04 203 montmorillonite-Mg -2.48 -6.79 -4.32 -0.267 0.73678E+04 204 montmorillonite-Na -2.04 -5.57 -3.54 -0.216 0.60365E+04 205 nontronite-Ca 3.21 -0.19 -3.41 -0.221 0.58215E+04 206 nontronite-H 2.53 -2.36 -4.89 -0.328 0.83484E+04 207 nontronite-K 3.34 -0.30 -3.64 -0.233 0.62083E+04 208 nontronite-Mg 3.07 -0.82 -3.90 -0.253 0.66553E+04 209 nontronite-Na 3.52 0.40 -3.12 -0.200 0.53291E+04 224 tobermorite 9.82 7.76 -2.07 -0.564 0.35287E+04 230 alabandite -0.98 -4.61 -3.63 -1.210 0.61957E+04 233 boehmite 4.41 0.74 -3.67 -0.611 0.62619E+04 235 ferrous-oxide 9.81 6.73 -3.08 -0.769 0.52532E+04 240 silica-amorphous -2.09 -3.16 -1.07 -0.355 0.18203E+04 242 an20ab80 2.02 1.35 -0.67 -0.052 0.11472E+04 243 an25ab75 2.65 1.78 -0.87 -0.067 0.14810E+04 244 an30ab70 3.28 2.21 -1.07 -0.082 0.18244E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 100.0000000 g Current total amount of reactant added: 8799.9990000 g New total amount of reactant added: 8899.9990000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.5202E-10 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 13 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 8899.9990000 Water: Moles liquid = 0.5810E+01 kg liquid = 0.1047E+00 Moles total = -.5606E+02 kg total = -.1010E+01 Activity = 1.0000 Stoichiometric ionic strength = .1229938E-01 Osmotic coef. = 0.9670 True ionic strength = .2077933E-01 Chg. balance for total moles = 0.5202E-10 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.91617E-10 -10.0380 0.76802E-10 -10.1146 0.83829E+00 -0.0766 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13119E-02 -2.8821 0.10930E-02 -2.9614 0.83310E+00 -0.0793 4 SO4-- 0.60210E-11 -11.2203 0.30963E-11 -11.5092 0.51424E+00 -0.2888 5 HCO3- 0.22225E-05 -5.6532 0.18544E-05 -5.7318 0.83435E+00 -0.0787 6 HS- 0.24361E-03 -3.6133 0.20298E-03 -3.6925 0.83322E+00 -0.0792 7 Al+++ 0.10994E-28 -28.9589 0.24835E-29 -29.6049 0.22591E+00 -0.6461 8 H4SiO4 0.69598E-03 -3.1574 0.69598E-03 -3.1574 0.10000E+01 0.0000 9 Ca++ 0.14611E-06 -6.8353 0.74570E-07 -7.1274 0.51036E+00 -0.2921 10 Mg++ 0.22862E-10 -10.6409 0.11613E-10 -10.9351 0.50795E+00 -0.2942 11 Fe++ 0.63009E-13 -13.2006 0.32042E-13 -13.4943 0.50852E+00 -0.2937 12 K+ 0.16243E-03 -3.7893 0.13555E-03 -3.8679 0.83456E+00 -0.0785 13 Na+ 0.20612E-01 -1.6859 0.17169E-01 -1.7653 0.83294E+00 -0.0794 14 Mn++ 0.20229E-10 -10.6940 0.10296E-10 -10.9874 0.50896E+00 -0.2933 15 HPO4-- 0.42706E-07 -7.3695 0.21965E-07 -7.6583 0.51432E+00 -0.2888 16 HSiO3- 0.10157E-01 -1.9932 0.84617E-02 -2.0725 0.83310E+00 -0.0793 17 Ca(HSiO3)+ 0.17215E-07 -7.7641 0.14370E-07 -7.8425 0.83474E+00 -0.0784 18 Mg(HSiO3)+ 0.33363E-11 -11.4767 0.27850E-11 -11.5552 0.83474E+00 -0.0784 19 NaHSiO3,aq 0.23496E-02 -2.6290 0.23496E-02 -2.6290 0.10000E+01 0.0000 20 AlO+ 0.68621E-16 -16.1635 0.57281E-16 -16.2420 0.83474E+00 -0.0784 22 HAlO2,aq 0.14853E-09 -9.8282 0.14853E-09 -9.8282 0.10000E+01 0.0000 23 AlO2- 0.51481E-05 -5.2883 0.42809E-05 -5.3685 0.83155E+00 -0.0801 24 CH4,aq 0.11853E-03 -3.9262 0.11809E-03 -3.9278 0.99625E+00 -0.0016 25 C2H6,aq 0.20660E-12 -12.6849 0.20582E-12 -12.6865 0.99625E+00 -0.0016 29 CO,aq 0.88542E-16 -16.0528 0.88542E-16 -16.0528 0.10000E+01 0.0000 30 CO2,aq 0.30546E-09 -9.5150 0.30431E-09 -9.5167 0.99625E+00 -0.0016 31 CO3-2 0.41101E-05 -5.3862 0.21090E-05 -5.6759 0.51312E+00 -0.2898 32 CaCO3,aq 0.19719E-08 -8.7051 0.19719E-08 -8.7051 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.42285E-11 -11.3738 0.35297E-11 -11.4523 0.83474E+00 -0.0784 34 CaCl+ 0.15801E-09 -9.8013 0.13190E-09 -9.8798 0.83474E+00 -0.0784 35 CaCl2,aq 0.34249E-13 -13.4654 0.34249E-13 -13.4654 0.10000E+01 0.0000 36 CaOH+ 0.82898E-07 -7.0815 0.69199E-07 -7.1599 0.83474E+00 -0.0784 37 CaSO4,aq 0.73318E-16 -16.1348 0.73318E-16 -16.1348 0.10000E+01 0.0000 38 HCl,aq 0.15382E-13 -13.8130 0.15382E-13 -13.8130 0.10000E+01 0.0000 43 FeCl+ 0.66406E-16 -16.1778 0.55431E-16 -16.2562 0.83474E+00 -0.0784 46 FeO,aq 0.21112E-09 -9.6755 0.21112E-09 -9.6755 0.10000E+01 0.0000 47 FeOH+ 0.16269E-10 -10.7886 0.13580E-10 -10.8671 0.83474E+00 -0.0784 48 HFeO2- 0.34525E-07 -7.4619 0.28763E-07 -7.5412 0.83310E+00 -0.0793 49 FeO+ 0.11402E-16 -16.9430 0.95178E-17 -17.0215 0.83474E+00 -0.0784 51 FeO2- 0.39632E-09 -9.4020 0.33018E-09 -9.4813 0.83310E+00 -0.0793 52 HFeO2,aq 0.32252E-11 -11.4914 0.32252E-11 -11.4914 0.10000E+01 0.0000 53 H2,aq 0.11626E-04 -4.9346 0.11582E-04 -4.9362 0.99625E+00 -0.0016 54 KCl,aq 0.26852E-08 -8.5710 0.26852E-08 -8.5710 0.10000E+01 0.0000 56 KOH,aq 0.75375E-06 -6.1228 0.75375E-06 -6.1228 0.10000E+01 0.0000 57 KSO4- 0.78177E-14 -14.1069 0.65129E-14 -14.1862 0.83310E+00 -0.0793 58 MgCO3,aq 0.76972E-13 -13.1137 0.76972E-13 -13.1137 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.67286E-15 -15.1721 0.56167E-15 -15.2505 0.83474E+00 -0.0784 60 MgCl+ 0.22302E-13 -13.6517 0.18616E-13 -13.7301 0.83474E+00 -0.0784 61 MgOH+ 0.71435E-10 -10.1461 0.59630E-10 -10.2245 0.83474E+00 -0.0784 63 MnO,aq 0.18076E-08 -8.7429 0.18076E-08 -8.7429 0.10000E+01 0.0000 64 MnOH+ 0.48561E-09 -9.3137 0.40536E-09 -9.3922 0.83474E+00 -0.0784 65 MnO2-2 0.19820E-10 -10.7029 0.10170E-10 -10.9927 0.51312E+00 -0.2898 66 HMnO2- 0.20541E-09 -9.6874 0.17112E-09 -9.7667 0.83310E+00 -0.0793 69 MnCl+ 0.83011E-13 -13.0809 0.69293E-13 -13.1593 0.83474E+00 -0.0784 71 NaCl,aq 0.62187E-05 -5.2063 0.62187E-05 -5.2063 0.10000E+01 0.0000 72 NaOH,aq 0.96046E-04 -4.0175 0.96046E-04 -4.0175 0.10000E+01 0.0000 74 OH- 0.90469E-02 -2.0435 0.75229E-02 -2.1236 0.83155E+00 -0.0801 79 HPO3-2 0.15451E-14 -14.8111 0.79280E-15 -15.1008 0.51312E+00 -0.2898 81 H2PO3- 0.14656E-18 -18.8340 0.12210E-18 -18.9133 0.83310E+00 -0.0793 82 H3PO4,aq 0.90612E-18 -18.0428 0.90612E-18 -18.0428 0.10000E+01 0.0000 83 H2PO4- 0.37317E-10 -10.4281 0.31119E-10 -10.5070 0.83391E+00 -0.0789 84 PO4-3 0.98201E-09 -9.0079 0.23334E-09 -9.6320 0.23761E+00 -0.6241 88 HP2O7-3 0.87297E-18 -18.0590 0.19741E-18 -18.7046 0.22614E+00 -0.6456 89 P2O7-4 0.82806E-17 -17.0819 0.61407E-18 -18.2118 0.74158E-01 -1.1298 90 H2S,aq 0.48362E-07 -7.3155 0.48181E-07 -7.3171 0.99625E+00 -0.0016 91 S2-2 0.15362E-12 -12.8136 0.78823E-13 -13.1033 0.51312E+00 -0.2898 97 SO3-2 0.89489E-17 -17.0482 0.46603E-17 -17.3316 0.52076E+00 -0.2834 98 HSO3- 0.26899E-19 -19.5703 0.22410E-19 -19.6496 0.83310E+00 -0.0793 99 HSO4- 0.27427E-18 -18.5618 0.22917E-18 -18.6398 0.83558E+00 -0.0780 Charge balance for all species = 0.4976E-09 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.9161725E-10 -.2167799E-01 -.2181133E+02 0.0000 2 H2O 0.1000000E+01 0.5550503E+02 0.9981646E+06 0.0000 3 Cl- 0.1311930E-02 0.1318152E-02 0.4664947E+02 7.1532 4 SO4-- 0.6021017E-11 -.1214372E-03 -.1164475E+02 8.7201 5 HCO3- 0.2222514E-05 0.1248657E-03 0.7605429E+01 4.3828 6 HS- 0.2436114E-03 0.3650970E-03 0.1205305E+02 6.4221 7 Al+++ 0.1099372E-28 0.5148288E-05 0.1386619E+00 0.7390 8 H4SiO4 0.6959839E-03 0.1320254E-01 0.1266715E+04 -3.1574 9 Ca++ 0.1461141E-06 0.2483617E-06 0.9936170E-02 13.1018 10 Mg++ 0.2286160E-10 0.9774229E-10 0.2372092E-05 9.2942 11 Fe++ 0.6300909E-13 0.3515198E-07 0.1959648E-02 6.7350 12 K+ 0.1624260E-03 0.1631825E-03 0.6369434E+01 6.2467 13 Na+ 0.2061221E-01 0.2306412E-01 0.5292982E+03 8.3494 14 Mn++ 0.2022858E-10 0.2538742E-08 0.1392258E-03 9.2419 15 HPO4-- 0.4270606E-07 0.4372538E-07 0.4189268E-02 12.5710 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.1473708E+03 -.2269089E-02 -.1473685E+03 0.0000000E+00 2 H2O -.5605689E+02 0.5809848E+01 -.6186674E+02 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.2466748E+00 -.1271114E-04 0.2466875E+00 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.2466493E+00 0.3821561E-04 -.2466875E+00 0.0000000E+00 7 Al+++ 0.2902060E+02 0.5388840E-06 0.2902060E+02 0.0000000E+00 8 H4SiO4 0.9267376E+02 0.1381943E-02 0.9267238E+02 0.0000000E+00 9 Ca++ 0.1023628E+02 0.2599663E-07 0.1023628E+02 0.0000000E+00 10 Mg++ 0.7063491E+01 0.1023093E-10 0.7063491E+01 0.0000000E+00 11 Fe++ 0.6345776E+01 0.3679444E-08 0.6345776E+01 0.0000000E+00 12 K+ 0.1889596E+01 0.1708071E-04 0.1889579E+01 0.0000000E+00 13 Na+ 0.1117183E+02 0.2414179E-02 0.1116941E+02 0.0000000E+00 14 Mn++ 0.1543135E+00 0.2657363E-09 0.1543135E+00 0.0000000E+00 15 HPO4-- 0.5266643E-01 0.4576844E-08 0.5266642E-01 0.0000000E+00 Chg. balance for solid moles: 0.1055E-13 Mass of aqueous solution: 0.104859E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 8899.9990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 11.16 1.048 2926. 3.466 30.10 1123. andradite 0.9868 -0.006 501.4 2.700 5.157 130.3 grossular 0.2389 -0.622 107.6 2.032 1.107 29.95 apatite-OH 0.1756E-01 -1.756 8.818 0.945 0.9070E-01 2.802 clinochlore 1.263 0.102 702.2 2.846 7.222 267.1 daphnite 0.3657 -0.437 261.0 2.417 2.684 79.08 chlorite-Mn 0.3086E-01 -1.511 21.88 1.340 0.2250 6.973 diopside 0.4748 -0.323 102.8 2.012 1.058 31.43 hedenbergite 0.1231 -0.910 30.55 1.485 0.3142 8.368 microcline 1.657 0.219 461.2 2.664 4.743 180.2 stilbite 5.724 0.758 4033. 3.606 41.48 1881. stilpnomelane-Fe 0.4653 -0.332 501.6 2.700 5.159 173.3 tr.625ac.25prg.125 0.7500E-01 -1.125 64.11 1.807 0.6593 20.63 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8051E+00 0.8051E+00 1.0000 -0.094 grossular 0.1949E+00 0.1949E+00 1.0000 -0.710 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.7611E+00 0.7611E+00 1.0000 -0.119 daphnite 0.2203E+00 0.2203E+00 1.0000 -0.657 chlorite-Mn 0.1859E-01 0.1859E-01 1.0000 -1.731 diopside 0.7941E+00 0.7941E+00 1.0000 -0.100 hedenbergite 0.2059E+00 0.2059E+00 1.0000 -0.686 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 tr.625ac.25prg.125 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 9723.113688 g Volume = 3934.697309 cm3 Porosity: -10.4942% V(tot) - V(min): -.37370E+03 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 8899.9990000 g log = 3.9494 Original solution: 1000.0103000 g Original solution / Rock added: 0.11 (Water/Rock Ratio), log = -0.9494 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.2098 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.8453E+00 0.9837 0.1006E+01 0.1023E+01 CO2,gas 0.2678E-07 1.0050 0.3256E-07 0.3240E-07 CH4,gas 0.1422E+00 1.0107 0.1738E+00 0.1720E+00 H2,gas 0.1256E-01 1.0006 0.1521E-01 0.1520E-01 H2S,gas 0.1100E-05 0.9953 0.1324E-05 0.1331E-05 S2,gas 0.2354E-27 1.0000 0.2848E-27 0.2848E-27 CO,gas 0.1091E-12 1.0000 0.1319E-12 0.1319E-12 SO3,gas 0.5708E-47 1.0000 0.6905E-47 0.6905E-47 SO2,gas 0.3377E-26 1.0000 0.4085E-26 0.4085E-26 HCl,gas 0.2243E-16 1.0000 0.2714E-16 0.2714E-16 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 16 albite -0.38 -0.38 0.00 0.000 -0.94784E-12 22 andradite 39.01 39.01 0.00 0.000 -0.12132E-10 23 grossular 32.73 32.73 0.00 0.000 0.36397E-10 32 apatite-OH -18.15 -18.15 0.00 0.000 -0.60662E-11 46 clinochlore 39.07 39.07 0.00 0.000 -0.12132E-10 47 daphnite 28.97 28.97 0.00 0.000 0.00000E+00 48 chlorite-Mn 46.87 46.87 0.00 0.000 -0.24265E-10 67 diopside 16.18 16.18 0.00 0.000 0.60662E-11 68 hedenbergite 14.21 14.21 0.00 0.000 0.00000E+00 116 microcline -2.49 -2.49 0.00 0.000 -0.10616E-10 163 stilbite -7.52 -7.52 0.00 0.000 -0.90992E-11 164 stilpnomelane-Fe 13.02 13.02 0.00 0.000 -0.75827E-10 245 tr.625ac.25prg.125 45.16 45.16 0.00 0.000 0.00000E+00 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -15.85 -9.19 -3.062 0.15685E+05 -7.487 3 CH4,gas 4.54 2.08 -2.46 -0.615 0.41985E+04 -0.760 4 H2,gas 8.00 4.48 -3.52 -2.010 0.60051E+04 -1.818 5 H2S,gas -6.23 -13.81 -7.58 -3.788 0.12937E+05 -5.878 6 S2,gas -7.34 -36.58 -29.24 -4.499 0.49934E+05 -27.546 7 CO,gas 3.21 -11.36 -14.58 -4.486 0.24893E+05 -12.880 8 SO3,gas 17.12 -31.74 -48.86 -12.215 0.83427E+05 -47.161 9 SO2,gas 0.83 -27.26 -28.09 -7.490 0.47959E+05 -26.389 10 HCl,gas 5.19 -13.08 -18.27 -9.133 0.31188E+05 -16.566 11 acmite 7.71 6.53 -1.18 -0.123 0.20175E+04 15 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 19 spessartine 24.46 19.73 -4.73 -0.236 0.80693E+04 20 analcite 3.32 2.77 -0.55 -0.061 0.93626E+03 26 annite 20.12 17.72 -2.40 -0.134 0.41064E+04 27 phlogopite 27.06 25.40 -1.67 -0.093 0.28490E+04 29 anorthite 12.71 8.26 -4.45 -0.342 0.75903E+04 35 aragonite 0.97 -2.74 -3.71 -1.237 0.63367E+04 36 brucite 12.57 9.29 -3.27 -0.655 0.55909E+04 37 calcite 0.81 -2.74 -3.56 -1.185 0.60724E+04 38 carnegieite-low 9.02 5.93 -3.09 -0.442 0.52801E+04 39 carnegieite-high 10.09 5.93 -4.16 -0.595 0.71071E+04 40 carpholite-Mg 8.58 4.46 -4.12 -0.275 0.70429E+04 41 carpholite-Fe 6.71 1.90 -4.81 -0.321 0.82207E+04 42 celadonite 5.34 3.65 -1.69 -0.099 0.28879E+04 43 celadonite-Fe 3.88 1.09 -2.79 -0.164 0.47561E+04 44 chrysotile 23.89 21.57 -2.32 -0.194 0.39692E+04 49 chlorite-Al-free 47.17 43.14 -4.04 -0.168 0.68936E+04 51 chloritoid-Fe 9.17 5.06 -4.12 -0.275 0.70316E+04 52 chloritoid-Mn 11.40 7.56 -3.84 -0.256 0.65544E+04 54 coesite -2.38 -3.16 -0.78 -0.260 0.13341E+04 61 cristobalite -2.56 -3.16 -0.60 -0.199 0.10195E+04 63 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71234E+04 65 diaspore 2.87 0.74 -2.13 -0.356 0.36450E+04 66 diamond -3.10 -6.88 -3.78 -1.080 0.64516E+04 71 enstatite 17.26 12.27 -4.99 -0.499 0.85226E+04 73 clinoenstatite 17.17 12.27 -4.89 -0.489 0.83542E+04 75 epidote 24.67 22.70 -1.97 -0.095 0.33586E+04 76 clinozoisite 22.81 18.95 -3.86 -0.175 0.65869E+04 77 epidote-Fe 29.84 26.46 -3.38 -0.176 0.57768E+04 78 fayalite 14.05 10.31 -3.73 -0.533 0.63743E+04 79 ferrosilite 11.15 7.16 -3.99 -0.399 0.68202E+04 83 gibbsite 4.08 0.74 -3.34 -0.477 0.57036E+04 84 glaucophane 22.97 20.80 -2.17 -0.059 0.37134E+04 85 glaucophane-Fe 17.28 13.12 -4.15 -0.112 0.70919E+04 86 graphite -3.55 -6.88 -3.33 -0.953 0.56938E+04 87 greenalite 16.14 13.89 -2.25 -0.187 0.38408E+04 90 hematite 12.57 8.99 -3.58 -0.434 0.61111E+04 91 heulandite -5.83 -7.52 -1.69 -0.077 0.28938E+04 95 jadeite 4.22 2.77 -1.44 -0.144 0.24617E+04 97 kalsilite 7.58 3.83 -3.76 -0.537 0.64126E+04 98 kaolinite -1.33 -4.84 -3.50 -0.319 0.59832E+04 101 laumontite 2.88 1.95 -0.93 -0.062 0.15935E+04 102 lawsonite 9.62 8.26 -1.35 -0.090 0.23070E+04 103 leucite 4.12 0.67 -3.45 -0.345 0.58873E+04 105 lizardite 23.24 21.57 -1.68 -0.140 0.28619E+04 107 magnetite 20.09 15.72 -4.37 -0.356 0.74536E+04 108 minnesotaite 10.39 7.58 -2.81 -0.165 0.48027E+04 112 manganosite 14.06 9.24 -4.82 -1.204 0.82235E+04 120 muscovite 2.58 -1.01 -3.59 -0.211 0.61315E+04 121 paragonite 4.24 1.09 -3.15 -0.185 0.53706E+04 122 nepheline 8.34 5.93 -2.41 -0.344 0.41125E+04 128 periclase-Fe 11.63 6.73 -4.89 -1.223 0.83523E+04 134 phlogopite-Na 29.65 27.50 -2.15 -0.119 0.36678E+04 136 prehnite 19.37 18.21 -1.16 -0.068 0.19849E+04 137 prehnite-Fe 22.50 21.96 -0.53 -0.032 0.91159E+03 138 pumpellyite-Fe 46.27 43.89 -2.38 -0.053 0.40582E+04 139 pumpellyite-Mg 48.99 46.45 -2.54 -0.057 0.43421E+04 142 pyrite -21.25 -25.36 -4.12 -0.968 0.70267E+04 143 pyrrhotite -4.26 -7.07 -2.81 -0.937 0.48012E+04 144 pyrrhotiteFe0.875 -6.02 -8.47 -2.45 -0.902 0.41884E+04 145 pyroxmangite 7.40 6.08 -1.31 -0.263 0.22439E+04 146 pyrophyllite -6.18 -11.15 -4.98 -0.311 0.84962E+04 147 quartz -2.99 -3.16 -0.17 -0.056 0.28679E+03 152 rhodonite 7.45 6.08 -1.36 -0.272 0.23242E+04 153 sanidine -1.28 -2.49 -1.21 -0.093 0.20677E+04 165 stilpnomelane-Mg 27.44 25.81 -1.63 -0.049 0.27804E+04 171 talc 16.49 15.25 -1.24 -0.073 0.21140E+04 174 tephroite 18.09 15.33 -2.76 -0.394 0.47116E+04 178 tridymite -2.63 -3.16 -0.53 -0.177 0.90677E+03 179 tremolite 47.87 47.42 -0.45 -0.012 0.77494E+03 180 ferroactinolite 38.45 34.62 -3.83 -0.104 0.65448E+04 181 troilite-low -4.41 -7.07 -2.66 -0.887 0.45440E+04 183 vesuvianite 223.47 218.82 -4.65 -0.036 0.79441E+04 187 wairakite 3.95 1.95 -2.00 -0.118 0.34155E+04 188 walstromite 11.51 9.94 -1.56 -0.313 0.26719E+04 189 wollastonite 10.46 9.94 -0.52 -0.103 0.88229E+03 190 pseudo-wollastonite 11.00 9.94 -1.06 -0.211 0.18021E+04 191 zoisite 22.85 18.95 -3.90 -0.177 0.66610E+04 192 akaganeite 7.75 4.49 -3.26 -0.705 0.55681E+04 199 chalcedony -2.80 -3.16 -0.35 -0.118 0.60609E+03 201 montmorillonite-Ca -2.29 -6.17 -3.88 -0.240 0.66180E+04 202 montmorillonite-K -2.24 -6.27 -4.03 -0.247 0.68816E+04 203 montmorillonite-Mg -2.48 -6.79 -4.32 -0.267 0.73678E+04 204 montmorillonite-Na -2.04 -5.57 -3.54 -0.216 0.60365E+04 205 nontronite-Ca 3.21 -0.19 -3.41 -0.221 0.58215E+04 206 nontronite-H 2.53 -2.36 -4.89 -0.328 0.83484E+04 207 nontronite-K 3.34 -0.30 -3.64 -0.233 0.62083E+04 208 nontronite-Mg 3.07 -0.82 -3.90 -0.253 0.66553E+04 209 nontronite-Na 3.52 0.40 -3.12 -0.200 0.53291E+04 224 tobermorite 9.82 7.76 -2.07 -0.564 0.35287E+04 230 alabandite -0.98 -4.57 -3.59 -1.196 0.61254E+04 233 boehmite 4.41 0.74 -3.67 -0.611 0.62619E+04 235 ferrous-oxide 9.81 6.73 -3.08 -0.769 0.52532E+04 240 silica-amorphous -2.09 -3.16 -1.07 -0.355 0.18203E+04 242 an20ab80 2.02 1.35 -0.67 -0.052 0.11472E+04 243 an25ab75 2.65 1.78 -0.87 -0.067 0.14810E+04 244 an30ab70 3.28 2.21 -1.07 -0.082 0.18244E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 100.0000000 g Current total amount of reactant added: 8899.9990000 g New total amount of reactant added: 8999.9990000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.5204E-10 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 14 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 8999.9990000 Water: Moles liquid = 0.5253E+01 kg liquid = 0.9463E-01 Moles total = -.5731E+02 kg total = -.1032E+01 Activity = 1.0000 Stoichiometric ionic strength = .1241648E-01 Osmotic coef. = 0.9668 True ionic strength = .2087229E-01 Chg. balance for total moles = 0.5204E-10 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.92023E-10 -10.0361 0.77120E-10 -10.1128 0.83805E+00 -0.0767 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.14511E-02 -2.8383 0.12086E-02 -2.9177 0.83284E+00 -0.0794 4 SO4-- 0.66383E-11 -11.1779 0.34097E-11 -11.4673 0.51364E+00 -0.2893 5 HCO3- 0.24496E-05 -5.6109 0.20432E-05 -5.6897 0.83410E+00 -0.0788 6 HS- 0.26946E-03 -3.5695 0.22446E-03 -3.6489 0.83297E+00 -0.0794 7 Al+++ 0.11161E-28 -28.9523 0.25146E-29 -29.5995 0.22530E+00 -0.6472 8 H4SiO4 0.69598E-03 -3.1574 0.69598E-03 -3.1574 0.10000E+01 0.0000 9 Ca++ 0.14751E-06 -6.8312 0.75190E-07 -7.1238 0.50974E+00 -0.2927 10 Mg++ 0.23080E-10 -10.6368 0.11709E-10 -10.9315 0.50733E+00 -0.2947 11 Fe++ 0.63611E-13 -13.1965 0.32308E-13 -13.4907 0.50790E+00 -0.2942 12 K+ 0.16315E-03 -3.7874 0.13612E-03 -3.8661 0.83431E+00 -0.0787 13 Na+ 0.20704E-01 -1.6839 0.17240E-01 -1.7635 0.83269E+00 -0.0795 14 Mn++ 0.20422E-10 -10.6899 0.10381E-10 -10.9837 0.50834E+00 -0.2938 15 HPO4-- 0.42404E-07 -7.3726 0.21783E-07 -7.6619 0.51371E+00 -0.2893 16 HSiO3- 0.10118E-01 -1.9949 0.84267E-02 -2.0743 0.83284E+00 -0.0794 17 Ca(HSiO3)+ 0.17292E-07 -7.7622 0.14430E-07 -7.8407 0.83449E+00 -0.0786 18 Mg(HSiO3)+ 0.33512E-11 -11.4748 0.27965E-11 -11.5534 0.83449E+00 -0.0786 19 NaHSiO3,aq 0.23496E-02 -2.6290 0.23496E-02 -2.6290 0.10000E+01 0.0000 20 AlO+ 0.68926E-16 -16.1616 0.57518E-16 -16.2402 0.83449E+00 -0.0786 22 HAlO2,aq 0.14853E-09 -9.8282 0.14853E-09 -9.8282 0.10000E+01 0.0000 23 AlO2- 0.51284E-05 -5.2900 0.42632E-05 -5.3703 0.83129E+00 -0.0802 24 CH4,aq 0.13115E-03 -3.8822 0.13065E-03 -3.8839 0.99622E+00 -0.0016 25 C2H6,aq 0.25292E-12 -12.5970 0.25196E-12 -12.5987 0.99622E+00 -0.0016 26 C3H8,aq 0.11261E-19 -19.9484 0.11218E-19 -19.9501 0.99622E+00 -0.0016 29 CO,aq 0.97965E-16 -16.0089 0.97965E-16 -16.0089 0.10000E+01 0.0000 30 CO2,aq 0.33798E-09 -9.4711 0.33670E-09 -9.4728 0.99622E+00 -0.0016 31 CO3-2 0.45153E-05 -5.3453 0.23141E-05 -5.6356 0.51251E+00 -0.2903 32 CaCO3,aq 0.21818E-08 -8.6612 0.21818E-08 -8.6612 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.46994E-11 -11.3280 0.39216E-11 -11.4065 0.83449E+00 -0.0786 34 CaCl+ 0.17623E-09 -9.7539 0.14706E-09 -9.8325 0.83449E+00 -0.0786 35 CaCl2,aq 0.42226E-13 -13.3744 0.42226E-13 -13.3744 0.10000E+01 0.0000 36 CaOH+ 0.83267E-07 -7.0795 0.69486E-07 -7.1581 0.83449E+00 -0.0786 37 CaSO4,aq 0.81411E-16 -16.0893 0.81411E-16 -16.0893 0.10000E+01 0.0000 38 HCl,aq 0.17079E-13 -13.7675 0.17079E-13 -13.7675 0.10000E+01 0.0000 43 FeCl+ 0.74062E-16 -16.1304 0.61804E-16 -16.2090 0.83449E+00 -0.0786 46 FeO,aq 0.21112E-09 -9.6755 0.21112E-09 -9.6755 0.10000E+01 0.0000 47 FeOH+ 0.16341E-10 -10.7867 0.13637E-10 -10.8653 0.83449E+00 -0.0786 48 HFeO2- 0.34393E-07 -7.4635 0.28644E-07 -7.5430 0.83284E+00 -0.0794 49 FeO+ 0.11453E-16 -16.9411 0.95573E-17 -17.0197 0.83449E+00 -0.0786 51 FeO2- 0.39480E-09 -9.4036 0.32881E-09 -9.4831 0.83284E+00 -0.0794 52 HFeO2,aq 0.32252E-11 -11.4914 0.32252E-11 -11.4914 0.10000E+01 0.0000 53 H2,aq 0.11626E-04 -4.9346 0.11582E-04 -4.9362 0.99622E+00 -0.0016 54 KCl,aq 0.29815E-08 -8.5256 0.29815E-08 -8.5256 0.10000E+01 0.0000 56 KOH,aq 0.75375E-06 -6.1228 0.75375E-06 -6.1228 0.10000E+01 0.0000 57 KSO4- 0.86473E-14 -14.0631 0.72019E-14 -14.1426 0.83284E+00 -0.0794 58 MgCO3,aq 0.85164E-13 -13.0697 0.85164E-13 -13.0697 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.74778E-15 -15.1262 0.62402E-15 -15.2048 0.83449E+00 -0.0786 60 MgCl+ 0.24873E-13 -13.6043 0.20756E-13 -13.6828 0.83449E+00 -0.0786 61 MgOH+ 0.71753E-10 -10.1442 0.59877E-10 -10.2227 0.83449E+00 -0.0786 63 MnO,aq 0.18076E-08 -8.7429 0.18076E-08 -8.7429 0.10000E+01 0.0000 64 MnOH+ 0.48778E-09 -9.3118 0.40705E-09 -9.3904 0.83449E+00 -0.0786 65 MnO2-2 0.19680E-10 -10.7060 0.10086E-10 -10.9963 0.51251E+00 -0.2903 66 HMnO2- 0.20462E-09 -9.6890 0.17042E-09 -9.7685 0.83284E+00 -0.0794 69 MnCl+ 0.92584E-13 -13.0335 0.77260E-13 -13.1120 0.83449E+00 -0.0786 70 MnSO4,aq 0.10219E-19 -19.9906 0.10219E-19 -19.9906 0.10000E+01 0.0000 71 NaCl,aq 0.69050E-05 -5.1608 0.69050E-05 -5.1608 0.10000E+01 0.0000 72 NaOH,aq 0.96046E-04 -4.0175 0.96046E-04 -4.0175 0.10000E+01 0.0000 74 OH- 0.90123E-02 -2.0452 0.74918E-02 -2.1254 0.83129E+00 -0.0802 79 HPO3-2 0.15341E-14 -14.8141 0.78626E-15 -15.1044 0.51251E+00 -0.2903 81 H2PO3- 0.14600E-18 -18.8357 0.12159E-18 -18.9151 0.83284E+00 -0.0794 82 H3PO4,aq 0.90612E-18 -18.0428 0.90612E-18 -18.0428 0.10000E+01 0.0000 83 H2PO4- 0.37174E-10 -10.4298 0.30990E-10 -10.5088 0.83366E+00 -0.0790 84 PO4-3 0.97233E-09 -9.0122 0.23046E-09 -9.6374 0.23701E+00 -0.6252 88 HP2O7-3 0.86452E-18 -18.0632 0.19498E-18 -18.7100 0.22553E+00 -0.6468 89 P2O7-4 0.81829E-17 -17.0871 0.60398E-18 -18.2190 0.73810E-01 -1.1319 90 H2S,aq 0.53702E-07 -7.2700 0.53499E-07 -7.2717 0.99622E+00 -0.0016 91 S2-2 0.18806E-12 -12.7257 0.96383E-13 -13.0160 0.51251E+00 -0.2903 97 SO3-2 0.98659E-17 -17.0059 0.51320E-17 -17.2897 0.52017E+00 -0.2839 98 HSO3- 0.29754E-19 -19.5265 0.24781E-19 -19.6059 0.83284E+00 -0.0794 99 HSO4- 0.30337E-18 -18.5180 0.25341E-18 -18.5962 0.83533E+00 -0.0781 Charge balance for all species = 0.5501E-09 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.9202342E-10 -.2160480E-01 -.2173758E+02 0.0000 2 H2O 0.1000000E+01 0.5550504E+02 0.9981603E+06 0.0000 3 Cl- 0.1451133E-02 0.1458041E-02 0.5159992E+02 7.1951 4 SO4-- 0.6638290E-11 -.1340562E-03 -.1285473E+02 8.7584 5 HCO3- 0.2449605E-05 0.1381171E-03 0.8412520E+01 4.4231 6 HS- 0.2694646E-03 0.4035744E-03 0.1332326E+02 6.4640 7 Al+++ 0.1116130E-28 0.5128598E-05 0.1381310E+00 0.7390 8 H4SiO4 0.6959838E-03 0.1316363E-01 0.1262976E+04 -3.1574 9 Ca++ 0.1475075E-06 0.2504289E-06 0.1001883E-01 13.1018 10 Mg++ 0.2307999E-10 0.9829767E-10 0.2385559E-05 9.2942 11 Fe++ 0.6361075E-13 0.3501830E-07 0.1952186E-02 6.7350 12 K+ 0.1631486E-03 0.1639053E-03 0.6397618E+01 6.2467 13 Na+ 0.2070404E-01 0.2315664E-01 0.5314190E+03 8.3494 14 Mn++ 0.2042191E-10 0.2540205E-08 0.1393054E-03 9.2419 15 HPO4-- 0.4240375E-07 0.4341326E-07 0.4159345E-02 12.5638 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.1490266E+03 -.2044459E-02 -.1490246E+03 0.0000000E+00 2 H2O -.5731043E+02 0.5252433E+01 -.6256286E+02 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.2494462E+00 -.1268571E-04 0.2494588E+00 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.2494207E+00 0.3819018E-04 -.2494588E+00 0.0000000E+00 7 Al+++ 0.2934667E+02 0.4853184E-06 0.2934667E+02 0.0000000E+00 8 H4SiO4 0.9371504E+02 0.1245672E-02 0.9371379E+02 0.0000000E+00 9 Ca++ 0.1035130E+02 0.2369805E-07 0.1035130E+02 0.0000000E+00 10 Mg++ 0.7142856E+01 0.9301893E-11 0.7142856E+01 0.0000000E+00 11 Fe++ 0.6417077E+01 0.3313776E-08 0.6417077E+01 0.0000000E+00 12 K+ 0.1910828E+01 0.1551033E-04 0.1910812E+01 0.0000000E+00 13 Na+ 0.1129735E+02 0.2191309E-02 0.1129516E+02 0.0000000E+00 14 Mn++ 0.1560473E+00 0.2403792E-09 0.1560473E+00 0.0000000E+00 15 HPO4-- 0.5325818E-01 0.4108190E-08 0.5325818E-01 0.0000000E+00 Chg. balance for solid moles: -.7189E-14 Mass of aqueous solution: 0.947986E+02 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 8999.9990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 11.29 1.053 2959. 3.471 30.10 1136. andradite 0.9978 -0.001 507.1 2.705 5.157 131.7 grossular 0.2416 -0.617 108.8 2.037 1.107 30.28 apatite-OH 0.1775E-01 -1.751 8.918 0.950 0.9070E-01 2.834 clinochlore 1.278 0.106 710.1 2.851 7.222 270.1 daphnite 0.3698 -0.432 263.9 2.421 2.684 79.97 chlorite-Mn 0.3121E-01 -1.506 22.13 1.345 0.2250 7.051 diopside 0.4802 -0.319 104.0 2.017 1.058 31.79 hedenbergite 0.1245 -0.905 30.90 1.490 0.3143 8.463 microcline 1.676 0.224 466.4 2.669 4.743 182.2 stilbite 5.788 0.763 4079. 3.611 41.48 1902. stilpnomelane-Fe 0.4706 -0.327 507.3 2.705 5.159 175.2 tr.625ac.25prg.125 0.7584E-01 -1.120 64.82 1.812 0.6593 20.86 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8051E+00 0.8051E+00 1.0000 -0.094 grossular 0.1949E+00 0.1949E+00 1.0000 -0.710 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.7611E+00 0.7611E+00 1.0000 -0.119 daphnite 0.2203E+00 0.2203E+00 1.0000 -0.657 chlorite-Mn 0.1859E-01 0.1859E-01 1.0000 -1.731 diopside 0.7941E+00 0.7941E+00 1.0000 -0.100 hedenbergite 0.2059E+00 0.2059E+00 1.0000 -0.686 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 tr.625ac.25prg.125 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 9832.364337 g Volume = 3978.900365 cm3 Porosity: -10.4943% V(tot) - V(min): -.37790E+03 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 8999.9990000 g log = 3.9542 Original solution: 1000.0103000 g Original solution / Rock added: 0.11 (Water/Rock Ratio), log = -0.9542 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.2284 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.8327E+00 0.9835 0.1006E+01 0.1023E+01 CO2,gas 0.2919E-07 1.0048 0.3602E-07 0.3585E-07 CH4,gas 0.1549E+00 1.0105 0.1923E+00 0.1903E+00 H2,gas 0.1237E-01 1.0007 0.1521E-01 0.1520E-01 H2S,gas 0.1203E-05 0.9952 0.1471E-05 0.1478E-05 S2,gas 0.2858E-27 1.0000 0.3511E-27 0.3511E-27 CO,gas 0.1188E-12 1.0000 0.1460E-12 0.1460E-12 SO3,gas 0.6242E-47 1.0000 0.7668E-47 0.7668E-47 SO2,gas 0.3693E-26 1.0000 0.4536E-26 0.4536E-26 HCl,gas 0.2453E-16 1.0000 0.3014E-16 0.3014E-16 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 16 albite -0.38 -0.38 0.00 0.000 0.11184E-10 22 andradite 39.01 39.01 0.00 0.000 -0.36397E-10 23 grossular 32.73 32.73 0.00 0.000 -0.12132E-10 32 apatite-OH -18.15 -18.15 0.00 0.000 0.60662E-11 46 clinochlore 39.07 39.07 0.00 0.000 -0.12132E-10 47 daphnite 28.97 28.97 0.00 0.000 -0.60662E-11 48 chlorite-Mn 46.87 46.87 0.00 0.000 0.48529E-10 67 diopside 16.18 16.18 0.00 0.000 0.60662E-11 68 hedenbergite 14.21 14.21 0.00 0.000 0.60662E-11 116 microcline -2.49 -2.49 0.00 0.000 -0.10616E-10 163 stilbite -7.52 -7.52 0.00 0.000 -0.90992E-11 164 stilpnomelane-Fe 13.02 13.02 0.00 0.000 0.21232E-10 245 tr.625ac.25prg.125 45.16 45.16 0.00 0.000 -0.12132E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -15.80 -9.14 -3.047 0.15610E+05 -7.443 3 CH4,gas 4.54 2.13 -2.41 -0.604 0.41235E+04 -0.716 4 H2,gas 8.00 4.48 -3.52 -2.010 0.60051E+04 -1.818 5 H2S,gas -6.23 -13.76 -7.53 -3.766 0.12860E+05 -5.832 6 S2,gas -7.34 -36.49 -29.15 -4.485 0.49779E+05 -27.455 7 CO,gas 3.21 -11.32 -14.53 -4.472 0.24818E+05 -12.836 8 SO3,gas 17.12 -31.69 -48.81 -12.204 0.83349E+05 -47.115 9 SO2,gas 0.83 -27.21 -28.04 -7.478 0.47881E+05 -26.343 10 HCl,gas 5.19 -13.03 -18.22 -9.110 0.31110E+05 -16.521 11 acmite 7.71 6.53 -1.18 -0.123 0.20175E+04 15 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 19 spessartine 24.46 19.73 -4.73 -0.236 0.80693E+04 20 analcite 3.32 2.77 -0.55 -0.061 0.93626E+03 26 annite 20.12 17.72 -2.40 -0.134 0.41064E+04 27 phlogopite 27.06 25.40 -1.67 -0.093 0.28490E+04 29 anorthite 12.71 8.26 -4.45 -0.342 0.75903E+04 35 aragonite 0.97 -2.70 -3.67 -1.222 0.62617E+04 36 brucite 12.57 9.29 -3.27 -0.655 0.55909E+04 37 calcite 0.81 -2.70 -3.51 -1.171 0.59974E+04 38 carnegieite-low 9.02 5.93 -3.09 -0.442 0.52801E+04 39 carnegieite-high 10.09 5.93 -4.16 -0.595 0.71071E+04 40 carpholite-Mg 8.58 4.46 -4.12 -0.275 0.70429E+04 41 carpholite-Fe 6.71 1.90 -4.81 -0.321 0.82207E+04 42 celadonite 5.34 3.65 -1.69 -0.099 0.28879E+04 43 celadonite-Fe 3.88 1.09 -2.79 -0.164 0.47561E+04 44 chrysotile 23.89 21.57 -2.32 -0.194 0.39692E+04 49 chlorite-Al-free 47.17 43.14 -4.04 -0.168 0.68936E+04 51 chloritoid-Fe 9.17 5.06 -4.12 -0.275 0.70316E+04 52 chloritoid-Mn 11.40 7.56 -3.84 -0.256 0.65544E+04 54 coesite -2.38 -3.16 -0.78 -0.260 0.13341E+04 61 cristobalite -2.56 -3.16 -0.60 -0.199 0.10195E+04 63 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71234E+04 65 diaspore 2.87 0.74 -2.13 -0.356 0.36450E+04 66 diamond -3.10 -6.84 -3.73 -1.067 0.63766E+04 71 enstatite 17.26 12.27 -4.99 -0.499 0.85226E+04 73 clinoenstatite 17.17 12.27 -4.89 -0.489 0.83542E+04 75 epidote 24.67 22.70 -1.97 -0.095 0.33586E+04 76 clinozoisite 22.81 18.95 -3.86 -0.175 0.65869E+04 77 epidote-Fe 29.84 26.46 -3.38 -0.176 0.57768E+04 78 fayalite 14.05 10.31 -3.73 -0.533 0.63743E+04 79 ferrosilite 11.15 7.16 -3.99 -0.399 0.68202E+04 83 gibbsite 4.08 0.74 -3.34 -0.477 0.57036E+04 84 glaucophane 22.97 20.80 -2.17 -0.059 0.37134E+04 85 glaucophane-Fe 17.28 13.12 -4.15 -0.112 0.70919E+04 86 graphite -3.55 -6.84 -3.29 -0.940 0.56188E+04 87 greenalite 16.14 13.89 -2.25 -0.187 0.38408E+04 90 hematite 12.57 8.99 -3.58 -0.434 0.61111E+04 91 heulandite -5.83 -7.52 -1.69 -0.077 0.28938E+04 95 jadeite 4.22 2.77 -1.44 -0.144 0.24617E+04 97 kalsilite 7.58 3.83 -3.76 -0.537 0.64126E+04 98 kaolinite -1.33 -4.84 -3.50 -0.319 0.59832E+04 101 laumontite 2.88 1.95 -0.93 -0.062 0.15935E+04 102 lawsonite 9.62 8.26 -1.35 -0.090 0.23070E+04 103 leucite 4.12 0.67 -3.45 -0.345 0.58873E+04 105 lizardite 23.24 21.57 -1.68 -0.140 0.28619E+04 107 magnetite 20.09 15.72 -4.37 -0.356 0.74536E+04 108 minnesotaite 10.39 7.58 -2.81 -0.165 0.48027E+04 112 manganosite 14.06 9.24 -4.82 -1.204 0.82235E+04 120 muscovite 2.58 -1.01 -3.59 -0.211 0.61315E+04 121 paragonite 4.24 1.09 -3.15 -0.185 0.53706E+04 122 nepheline 8.34 5.93 -2.41 -0.344 0.41125E+04 128 periclase-Fe 11.63 6.73 -4.89 -1.223 0.83523E+04 134 phlogopite-Na 29.65 27.50 -2.15 -0.119 0.36678E+04 136 prehnite 19.37 18.21 -1.16 -0.068 0.19849E+04 137 prehnite-Fe 22.50 21.96 -0.53 -0.032 0.91159E+03 138 pumpellyite-Fe 46.27 43.89 -2.38 -0.053 0.40582E+04 139 pumpellyite-Mg 48.99 46.45 -2.54 -0.057 0.43421E+04 142 pyrite -21.25 -25.27 -4.02 -0.947 0.68714E+04 143 pyrrhotite -4.26 -7.03 -2.77 -0.922 0.47236E+04 144 pyrrhotiteFe0.875 -6.02 -8.42 -2.41 -0.885 0.41108E+04 145 pyroxmangite 7.40 6.08 -1.31 -0.263 0.22439E+04 146 pyrophyllite -6.18 -11.15 -4.98 -0.311 0.84962E+04 147 quartz -2.99 -3.16 -0.17 -0.056 0.28679E+03 152 rhodonite 7.45 6.08 -1.36 -0.272 0.23242E+04 153 sanidine -1.28 -2.49 -1.21 -0.093 0.20677E+04 165 stilpnomelane-Mg 27.44 25.81 -1.63 -0.049 0.27804E+04 171 talc 16.49 15.25 -1.24 -0.073 0.21140E+04 174 tephroite 18.09 15.33 -2.76 -0.394 0.47115E+04 178 tridymite -2.63 -3.16 -0.53 -0.177 0.90677E+03 179 tremolite 47.87 47.42 -0.45 -0.012 0.77494E+03 180 ferroactinolite 38.45 34.62 -3.83 -0.104 0.65448E+04 181 troilite-low -4.41 -7.03 -2.62 -0.872 0.44664E+04 183 vesuvianite 223.47 218.82 -4.65 -0.036 0.79441E+04 187 wairakite 3.95 1.95 -2.00 -0.118 0.34155E+04 188 walstromite 11.51 9.94 -1.56 -0.313 0.26719E+04 189 wollastonite 10.46 9.94 -0.52 -0.103 0.88229E+03 190 pseudo-wollastonite 11.00 9.94 -1.06 -0.211 0.18021E+04 191 zoisite 22.85 18.95 -3.90 -0.177 0.66610E+04 192 akaganeite 7.75 4.49 -3.26 -0.705 0.55681E+04 199 chalcedony -2.80 -3.16 -0.35 -0.118 0.60609E+03 201 montmorillonite-Ca -2.29 -6.17 -3.88 -0.240 0.66180E+04 202 montmorillonite-K -2.24 -6.27 -4.03 -0.247 0.68816E+04 203 montmorillonite-Mg -2.48 -6.79 -4.32 -0.267 0.73678E+04 204 montmorillonite-Na -2.04 -5.57 -3.54 -0.216 0.60365E+04 205 nontronite-Ca 3.21 -0.19 -3.41 -0.221 0.58215E+04 206 nontronite-H 2.53 -2.36 -4.89 -0.328 0.83484E+04 207 nontronite-K 3.34 -0.30 -3.64 -0.233 0.62083E+04 208 nontronite-Mg 3.07 -0.82 -3.90 -0.253 0.66553E+04 209 nontronite-Na 3.52 0.40 -3.12 -0.200 0.53291E+04 224 tobermorite 9.82 7.76 -2.07 -0.564 0.35287E+04 230 alabandite -0.98 -4.52 -3.54 -1.181 0.60477E+04 233 boehmite 4.41 0.74 -3.67 -0.611 0.62619E+04 235 ferrous-oxide 9.81 6.73 -3.08 -0.769 0.52532E+04 240 silica-amorphous -2.09 -3.16 -1.07 -0.355 0.18203E+04 242 an20ab80 2.02 1.35 -0.67 -0.052 0.11472E+04 243 an25ab75 2.65 1.78 -0.87 -0.067 0.14810E+04 244 an30ab70 3.28 2.21 -1.07 -0.082 0.18244E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 100.0000000 g Current total amount of reactant added: 8999.9990000 g New total amount of reactant added: 9099.9990000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.5201E-10 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 14 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 9099.9990000 Water: Moles liquid = 0.4695E+01 kg liquid = 0.8459E-01 Moles total = -.5856E+02 kg total = -.1055E+01 Activity = 1.0000 Stoichiometric ionic strength = .1256162E-01 Osmotic coef. = 0.9667 True ionic strength = .2098779E-01 Chg. balance for total moles = 0.5201E-10 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.92528E-10 -10.0337 0.77516E-10 -10.1106 0.83776E+00 -0.0769 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.16234E-02 -2.7896 0.13515E-02 -2.8692 0.83253E+00 -0.0796 4 SO4-- 0.73965E-11 -11.1310 0.37936E-11 -11.4210 0.51289E+00 -0.2900 5 HCO3- 0.27283E-05 -5.5641 0.22749E-05 -5.6430 0.83380E+00 -0.0789 6 HS- 0.30146E-03 -3.5208 0.25101E-03 -3.6003 0.83266E+00 -0.0795 7 Al+++ 0.11372E-28 -28.9442 0.25535E-29 -29.5929 0.22454E+00 -0.6487 8 H4SiO4 0.69598E-03 -3.1574 0.69598E-03 -3.1574 0.10000E+01 0.0000 9 Ca++ 0.14925E-06 -6.8261 0.75964E-07 -7.1194 0.50898E+00 -0.2933 10 Mg++ 0.23353E-10 -10.6317 0.11830E-10 -10.9270 0.50656E+00 -0.2954 11 Fe++ 0.64363E-13 -13.1914 0.32641E-13 -13.4862 0.50714E+00 -0.2949 12 K+ 0.16405E-03 -3.7850 0.13681E-03 -3.8639 0.83400E+00 -0.0788 13 Na+ 0.20818E-01 -1.6816 0.17328E-01 -1.7612 0.83237E+00 -0.0797 14 Mn++ 0.20663E-10 -10.6848 0.10488E-10 -10.9793 0.50757E+00 -0.2945 15 HPO4-- 0.42033E-07 -7.3764 0.21561E-07 -7.6663 0.51296E+00 -0.2899 16 HSiO3- 0.10070E-01 -1.9970 0.83837E-02 -2.0766 0.83253E+00 -0.0796 17 Ca(HSiO3)+ 0.17387E-07 -7.7598 0.14504E-07 -7.8385 0.83419E+00 -0.0787 18 Mg(HSiO3)+ 0.33696E-11 -11.4724 0.28109E-11 -11.5512 0.83419E+00 -0.0787 19 NaHSiO3,aq 0.23496E-02 -2.6290 0.23496E-02 -2.6290 0.10000E+01 0.0000 20 AlO+ 0.69305E-16 -16.1592 0.57814E-16 -16.2380 0.83419E+00 -0.0787 22 HAlO2,aq 0.14853E-09 -9.8282 0.14853E-09 -9.8282 0.10000E+01 0.0000 23 AlO2- 0.51042E-05 -5.2921 0.42415E-05 -5.3725 0.83097E+00 -0.0804 24 CH4,aq 0.14677E-03 -3.8333 0.14621E-03 -3.8350 0.99618E+00 -0.0017 25 C2H6,aq 0.31676E-12 -12.4993 0.31555E-12 -12.5009 0.99618E+00 -0.0017 26 C3H8,aq 0.15783E-19 -19.8018 0.15722E-19 -19.8035 0.99618E+00 -0.0017 28 ethanol,aq 0.11626E-19 -19.9346 0.11582E-19 -19.9362 0.99618E+00 -0.0017 29 CO,aq 0.10963E-15 -15.9601 0.10963E-15 -15.9601 0.10000E+01 0.0000 30 CO2,aq 0.37824E-09 -9.4222 0.37680E-09 -9.4239 0.99618E+00 -0.0017 31 CO3-2 0.50089E-05 -5.3003 0.25634E-05 -5.5912 0.51176E+00 -0.2909 32 CaCO3,aq 0.24416E-08 -8.6123 0.24416E-08 -8.6123 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.52880E-11 -11.2767 0.44111E-11 -11.3554 0.83419E+00 -0.0787 34 CaCl+ 0.19917E-09 -9.7008 0.16615E-09 -9.7795 0.83419E+00 -0.0787 35 CaCl2,aq 0.53349E-13 -13.2729 0.53349E-13 -13.2729 0.10000E+01 0.0000 36 CaOH+ 0.83725E-07 -7.0771 0.69843E-07 -7.1559 0.83419E+00 -0.0787 37 CaSO4,aq 0.91510E-16 -16.0385 0.91510E-16 -16.0385 0.10000E+01 0.0000 38 HCl,aq 0.19198E-13 -13.7168 0.19198E-13 -13.7168 0.10000E+01 0.0000 43 FeCl+ 0.83705E-16 -16.0772 0.69826E-16 -16.1560 0.83419E+00 -0.0787 46 FeO,aq 0.21112E-09 -9.6755 0.21112E-09 -9.6755 0.10000E+01 0.0000 47 FeOH+ 0.16431E-10 -10.7843 0.13707E-10 -10.8631 0.83419E+00 -0.0787 48 HFeO2- 0.34230E-07 -7.4656 0.28498E-07 -7.5452 0.83253E+00 -0.0796 49 FeO+ 0.11516E-16 -16.9387 0.96064E-17 -17.0174 0.83419E+00 -0.0787 51 FeO2- 0.39294E-09 -9.4057 0.32713E-09 -9.4853 0.83253E+00 -0.0796 52 HFeO2,aq 0.32252E-11 -11.4914 0.32252E-11 -11.4914 0.10000E+01 0.0000 53 H2,aq 0.11627E-04 -4.9345 0.11582E-04 -4.9362 0.99618E+00 -0.0017 54 KCl,aq 0.33513E-08 -8.4748 0.33513E-08 -8.4748 0.10000E+01 0.0000 56 KOH,aq 0.75375E-06 -6.1228 0.75375E-06 -6.1228 0.10000E+01 0.0000 57 KSO4- 0.96740E-14 -14.0144 0.80539E-14 -14.0940 0.83253E+00 -0.0796 58 MgCO3,aq 0.95306E-13 -13.0209 0.95306E-13 -13.0209 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.84144E-15 -15.0750 0.70192E-15 -15.1537 0.83419E+00 -0.0787 60 MgCl+ 0.28112E-13 -13.5511 0.23450E-13 -13.6298 0.83419E+00 -0.0787 61 MgOH+ 0.72147E-10 -10.1418 0.60184E-10 -10.2205 0.83419E+00 -0.0787 63 MnO,aq 0.18076E-08 -8.7429 0.18076E-08 -8.7429 0.10000E+01 0.0000 64 MnOH+ 0.49047E-09 -9.3094 0.40914E-09 -9.3881 0.83419E+00 -0.0787 65 MnO2-2 0.19509E-10 -10.7098 0.99838E-11 -11.0007 0.51176E+00 -0.2909 66 HMnO2- 0.20366E-09 -9.6911 0.16955E-09 -9.7707 0.83253E+00 -0.0796 69 MnCl+ 0.10464E-12 -12.9803 0.87289E-13 -13.0590 0.83419E+00 -0.0787 70 MnSO4,aq 0.11486E-19 -19.9398 0.11486E-19 -19.9398 0.10000E+01 0.0000 71 NaCl,aq 0.77614E-05 -5.1101 0.77614E-05 -5.1101 0.10000E+01 0.0000 72 NaOH,aq 0.96046E-04 -4.0175 0.96046E-04 -4.0175 0.10000E+01 0.0000 74 OH- 0.89697E-02 -2.0472 0.74536E-02 -2.1276 0.83097E+00 -0.0804 79 HPO3-2 0.15207E-14 -14.8179 0.77825E-15 -15.1089 0.51176E+00 -0.2909 81 H2PO3- 0.14531E-18 -18.8377 0.12097E-18 -18.9173 0.83253E+00 -0.0796 82 H3PO4,aq 0.90612E-18 -18.0428 0.90612E-18 -18.0428 0.10000E+01 0.0000 83 H2PO4- 0.36998E-10 -10.4318 0.30832E-10 -10.5110 0.83335E+00 -0.0792 84 PO4-3 0.96051E-09 -9.0175 0.22694E-09 -9.6441 0.23627E+00 -0.6266 88 HP2O7-3 0.85419E-18 -18.0684 0.19201E-18 -18.7167 0.22478E+00 -0.6482 89 P2O7-4 0.80638E-17 -17.0935 0.59174E-18 -18.2279 0.73382E-01 -1.1344 90 H2S,aq 0.60366E-07 -7.2192 0.60135E-07 -7.2209 0.99618E+00 -0.0017 91 S2-2 0.23553E-12 -12.6279 0.12054E-12 -12.9189 0.51176E+00 -0.2909 97 SO3-2 0.10992E-16 -16.9589 0.57098E-17 -17.2434 0.51944E+00 -0.2845 98 HSO3- 0.33287E-19 -19.4777 0.27712E-19 -19.5573 0.83253E+00 -0.0796 99 HSO4- 0.33938E-18 -18.4693 0.28339E-18 -18.5476 0.83503E+00 -0.0783 Charge balance for all species = 0.6150E-09 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.9252806E-10 -.2151471E-01 -.2164681E+02 0.0000 2 H2O 0.1000000E+01 0.5550507E+02 0.9981550E+06 0.0000 3 Cl- 0.1623382E-02 0.1631147E-02 0.5772580E+02 7.2414 4 SO4-- 0.7396517E-11 -.1496816E-03 -.1435298E+02 8.8003 5 HCO3- 0.2728342E-05 0.1545151E-03 0.9411243E+01 4.4676 6 HS- 0.3014565E-03 0.4511985E-03 0.1489539E+02 6.5103 7 Al+++ 0.1137207E-28 0.5104365E-05 0.1374775E+00 0.7390 8 H4SiO4 0.6959836E-03 0.1311574E-01 0.1258373E+04 -3.1574 9 Ca++ 0.1492486E-06 0.2530068E-06 0.1012190E-01 13.1018 10 Mg++ 0.2335290E-10 0.9899541E-10 0.2402479E-05 9.2942 11 Fe++ 0.6436264E-13 0.3485370E-07 0.1942999E-02 6.7350 12 K+ 0.1640463E-03 0.1648034E-03 0.6432635E+01 6.2467 13 Na+ 0.2081814E-01 0.2327159E-01 0.5340540E+03 8.3494 14 Mn++ 0.2066344E-10 0.2542029E-08 0.1394046E-03 9.2419 15 HPO4-- 0.4203308E-07 0.4303060E-07 0.4122659E-02 12.5549 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.1506825E+03 -.1819869E-02 -.1506806E+03 0.0000000E+00 2 H2O -.5856397E+02 0.4695019E+01 -.6325899E+02 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.2522175E+00 -.1266115E-04 0.2522302E+00 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.2521920E+00 0.3816562E-04 -.2522302E+00 0.0000000E+00 7 Al+++ 0.2967275E+02 0.4317640E-06 0.2967274E+02 0.0000000E+00 8 H4SiO4 0.9475631E+02 0.1109424E-02 0.9475521E+02 0.0000000E+00 9 Ca++ 0.1046631E+02 0.2140114E-07 0.1046631E+02 0.0000000E+00 10 Mg++ 0.7222221E+01 0.8373746E-11 0.7222221E+01 0.0000000E+00 11 Fe++ 0.6488377E+01 0.2948178E-08 0.6488377E+01 0.0000000E+00 12 K+ 0.1932059E+01 0.1394026E-04 0.1932045E+01 0.0000000E+00 13 Na+ 0.1142288E+02 0.1968479E-02 0.1142091E+02 0.0000000E+00 14 Mn++ 0.1577812E+00 0.2150231E-09 0.1577812E+00 0.0000000E+00 15 HPO4-- 0.5384994E-01 0.3639838E-08 0.5384994E-01 0.0000000E+00 Chg. balance for solid moles: -.1332E-13 Mass of aqueous solution: 0.847385E+02 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 9099.9990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 11.41 1.057 2992. 3.476 30.10 1149. andradite 1.009 0.004 512.7 2.710 5.157 133.2 grossular 0.2443 -0.612 110.0 2.042 1.107 30.62 apatite-OH 0.1795E-01 -1.746 9.017 0.955 0.9070E-01 2.865 clinochlore 1.292 0.111 718.0 2.856 7.222 273.1 daphnite 0.3739 -0.427 266.8 2.426 2.684 80.85 chlorite-Mn 0.3156E-01 -1.501 22.37 1.350 0.2250 7.130 diopside 0.4857 -0.314 105.2 2.022 1.058 32.15 hedenbergite 0.1260 -0.900 31.25 1.495 0.3143 8.559 microcline 1.694 0.229 471.5 2.674 4.743 184.2 stilbite 5.852 0.767 4124. 3.615 41.48 1923. stilpnomelane-Fe 0.4758 -0.323 512.9 2.710 5.159 177.2 tr.625ac.25prg.125 0.7667E-01 -1.115 65.53 1.816 0.6592 21.09 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8051E+00 0.8051E+00 1.0000 -0.094 grossular 0.1949E+00 0.1949E+00 1.0000 -0.710 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.7611E+00 0.7611E+00 1.0000 -0.119 daphnite 0.2203E+00 0.2203E+00 1.0000 -0.657 chlorite-Mn 0.1859E-01 0.1859E-01 1.0000 -1.731 diopside 0.7941E+00 0.7941E+00 1.0000 -0.100 hedenbergite 0.2059E+00 0.2059E+00 1.0000 -0.686 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 tr.625ac.25prg.125 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 9941.614982 g Volume = 4023.103419 cm3 Porosity: -10.4945% V(tot) - V(min): -.38210E+03 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 9099.9990000 g log = 3.9590 Original solution: 1000.0103000 g Original solution / Rock added: 0.11 (Water/Rock Ratio), log = -0.9590 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.2513 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.8176E+00 0.9833 0.1006E+01 0.1023E+01 CO2,gas 0.3207E-07 1.0045 0.4031E-07 0.4013E-07 CH4,gas 0.1702E+00 1.0103 0.2152E+00 0.2130E+00 H2,gas 0.1214E-01 1.0007 0.1521E-01 0.1520E-01 H2S,gas 0.1328E-05 0.9951 0.1653E-05 0.1661E-05 S2,gas 0.3545E-27 1.0000 0.4436E-27 0.4436E-27 CO,gas 0.1306E-12 1.0000 0.1634E-12 0.1634E-12 SO3,gas 0.6888E-47 1.0000 0.8619E-47 0.8619E-47 SO2,gas 0.4075E-26 1.0000 0.5099E-26 0.5099E-26 HCl,gas 0.2707E-16 1.0000 0.3387E-16 0.3387E-16 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 16 albite -0.38 -0.38 0.00 0.000 -0.94784E-12 22 andradite 39.01 39.01 0.00 0.000 0.12132E-10 23 grossular 32.73 32.73 0.00 0.000 0.12132E-10 32 apatite-OH -18.15 -18.15 0.00 0.000 -0.12132E-10 46 clinochlore 39.07 39.07 0.00 0.000 -0.36397E-10 47 daphnite 28.97 28.97 0.00 0.000 -0.24265E-10 48 chlorite-Mn 46.87 46.87 0.00 0.000 -0.48529E-10 67 diopside 16.18 16.18 0.00 0.000 -0.60662E-11 68 hedenbergite 14.21 14.21 0.00 0.000 -0.60662E-11 116 microcline -2.49 -2.49 0.00 0.000 -0.10616E-10 163 stilbite -7.52 -7.52 0.00 0.000 0.15165E-10 164 stilpnomelane-Fe 13.02 13.02 0.00 0.000 0.21232E-10 245 tr.625ac.25prg.125 45.16 45.16 0.00 0.000 -0.60662E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -15.75 -9.09 -3.031 0.15527E+05 -7.395 3 CH4,gas 4.54 2.18 -2.37 -0.592 0.40400E+04 -0.667 4 H2,gas 8.00 4.48 -3.52 -2.010 0.60051E+04 -1.818 5 H2S,gas -6.23 -13.71 -7.48 -3.740 0.12773E+05 -5.782 6 S2,gas -7.34 -36.39 -29.05 -4.470 0.49605E+05 -27.353 7 CO,gas 3.21 -11.27 -14.49 -4.457 0.24734E+05 -12.787 8 SO3,gas 17.12 -31.64 -48.76 -12.191 0.83262E+05 -47.065 9 SO2,gas 0.83 -27.16 -27.99 -7.464 0.47795E+05 -26.293 10 HCl,gas 5.19 -12.98 -18.17 -9.085 0.31023E+05 -16.470 11 acmite 7.71 6.53 -1.18 -0.123 0.20175E+04 15 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 19 spessartine 24.46 19.73 -4.73 -0.236 0.80693E+04 20 analcite 3.32 2.77 -0.55 -0.061 0.93626E+03 26 annite 20.12 17.72 -2.40 -0.134 0.41064E+04 27 phlogopite 27.06 25.40 -1.67 -0.093 0.28490E+04 29 anorthite 12.71 8.26 -4.45 -0.342 0.75903E+04 35 aragonite 0.97 -2.65 -3.62 -1.206 0.61782E+04 36 brucite 12.57 9.29 -3.27 -0.655 0.55909E+04 37 calcite 0.81 -2.65 -3.46 -1.155 0.59140E+04 38 carnegieite-low 9.02 5.93 -3.09 -0.442 0.52801E+04 39 carnegieite-high 10.09 5.93 -4.16 -0.595 0.71071E+04 40 carpholite-Mg 8.58 4.46 -4.12 -0.275 0.70429E+04 41 carpholite-Fe 6.71 1.90 -4.81 -0.321 0.82207E+04 42 celadonite 5.34 3.65 -1.69 -0.099 0.28879E+04 43 celadonite-Fe 3.88 1.09 -2.79 -0.164 0.47561E+04 44 chrysotile 23.89 21.57 -2.32 -0.194 0.39692E+04 49 chlorite-Al-free 47.17 43.14 -4.04 -0.168 0.68936E+04 51 chloritoid-Fe 9.17 5.06 -4.12 -0.275 0.70316E+04 52 chloritoid-Mn 11.40 7.56 -3.84 -0.256 0.65544E+04 54 coesite -2.38 -3.16 -0.78 -0.260 0.13341E+04 61 cristobalite -2.56 -3.16 -0.60 -0.199 0.10195E+04 63 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71234E+04 65 diaspore 2.87 0.74 -2.13 -0.356 0.36450E+04 66 diamond -3.10 -6.79 -3.69 -1.053 0.62931E+04 71 enstatite 17.26 12.27 -4.99 -0.499 0.85226E+04 73 clinoenstatite 17.17 12.27 -4.89 -0.489 0.83542E+04 75 epidote 24.67 22.70 -1.97 -0.095 0.33586E+04 76 clinozoisite 22.81 18.95 -3.86 -0.175 0.65869E+04 77 epidote-Fe 29.84 26.46 -3.38 -0.176 0.57768E+04 78 fayalite 14.05 10.31 -3.73 -0.533 0.63743E+04 79 ferrosilite 11.15 7.16 -3.99 -0.399 0.68202E+04 83 gibbsite 4.08 0.74 -3.34 -0.477 0.57036E+04 84 glaucophane 22.97 20.80 -2.17 -0.059 0.37134E+04 85 glaucophane-Fe 17.28 13.12 -4.15 -0.112 0.70919E+04 86 graphite -3.55 -6.79 -3.24 -0.926 0.55354E+04 87 greenalite 16.14 13.89 -2.25 -0.187 0.38408E+04 90 hematite 12.57 8.99 -3.58 -0.434 0.61111E+04 91 heulandite -5.83 -7.52 -1.69 -0.077 0.28938E+04 95 jadeite 4.22 2.77 -1.44 -0.144 0.24617E+04 97 kalsilite 7.58 3.83 -3.76 -0.537 0.64126E+04 98 kaolinite -1.33 -4.84 -3.50 -0.319 0.59832E+04 101 laumontite 2.88 1.95 -0.93 -0.062 0.15935E+04 102 lawsonite 9.62 8.26 -1.35 -0.090 0.23070E+04 103 leucite 4.12 0.67 -3.45 -0.345 0.58873E+04 105 lizardite 23.24 21.57 -1.68 -0.140 0.28619E+04 107 magnetite 20.09 15.72 -4.37 -0.356 0.74536E+04 108 minnesotaite 10.39 7.58 -2.81 -0.165 0.48027E+04 112 manganosite 14.06 9.24 -4.82 -1.204 0.82235E+04 120 muscovite 2.58 -1.01 -3.59 -0.211 0.61315E+04 121 paragonite 4.24 1.09 -3.15 -0.185 0.53706E+04 122 nepheline 8.34 5.93 -2.41 -0.344 0.41125E+04 128 periclase-Fe 11.63 6.73 -4.89 -1.223 0.83523E+04 134 phlogopite-Na 29.65 27.50 -2.15 -0.119 0.36678E+04 136 prehnite 19.37 18.21 -1.16 -0.068 0.19849E+04 137 prehnite-Fe 22.50 21.96 -0.53 -0.032 0.91159E+03 138 pumpellyite-Fe 46.27 43.89 -2.38 -0.053 0.40582E+04 139 pumpellyite-Mg 48.99 46.45 -2.54 -0.057 0.43421E+04 142 pyrite -21.25 -25.17 -3.92 -0.923 0.66980E+04 143 pyrrhotite -4.26 -6.98 -2.72 -0.905 0.46368E+04 144 pyrrhotiteFe0.875 -6.02 -8.37 -2.36 -0.867 0.40241E+04 145 pyroxmangite 7.40 6.08 -1.31 -0.263 0.22439E+04 146 pyrophyllite -6.18 -11.15 -4.98 -0.311 0.84962E+04 147 quartz -2.99 -3.16 -0.17 -0.056 0.28679E+03 152 rhodonite 7.45 6.08 -1.36 -0.272 0.23241E+04 153 sanidine -1.28 -2.49 -1.21 -0.093 0.20677E+04 165 stilpnomelane-Mg 27.44 25.81 -1.63 -0.049 0.27804E+04 171 talc 16.49 15.25 -1.24 -0.073 0.21140E+04 174 tephroite 18.09 15.33 -2.76 -0.394 0.47115E+04 178 tridymite -2.63 -3.16 -0.53 -0.177 0.90677E+03 179 tremolite 47.87 47.42 -0.45 -0.012 0.77494E+03 180 ferroactinolite 38.45 34.62 -3.83 -0.104 0.65448E+04 181 troilite-low -4.41 -6.98 -2.56 -0.855 0.43797E+04 183 vesuvianite 223.47 218.82 -4.65 -0.036 0.79441E+04 187 wairakite 3.95 1.95 -2.00 -0.118 0.34155E+04 188 walstromite 11.51 9.94 -1.56 -0.313 0.26719E+04 189 wollastonite 10.46 9.94 -0.52 -0.103 0.88229E+03 190 pseudo-wollastonite 11.00 9.94 -1.06 -0.211 0.18021E+04 191 zoisite 22.85 18.95 -3.90 -0.177 0.66610E+04 192 akaganeite 7.75 4.49 -3.26 -0.705 0.55681E+04 199 chalcedony -2.80 -3.16 -0.35 -0.118 0.60609E+03 201 montmorillonite-Ca -2.29 -6.17 -3.88 -0.240 0.66180E+04 202 montmorillonite-K -2.24 -6.27 -4.03 -0.247 0.68816E+04 203 montmorillonite-Mg -2.48 -6.79 -4.32 -0.267 0.73678E+04 204 montmorillonite-Na -2.04 -5.57 -3.54 -0.216 0.60365E+04 205 nontronite-Ca 3.21 -0.19 -3.41 -0.221 0.58215E+04 206 nontronite-H 2.53 -2.36 -4.89 -0.328 0.83484E+04 207 nontronite-K 3.34 -0.30 -3.64 -0.233 0.62083E+04 208 nontronite-Mg 3.07 -0.82 -3.90 -0.253 0.66553E+04 209 nontronite-Na 3.52 0.40 -3.12 -0.200 0.53291E+04 224 tobermorite 9.82 7.76 -2.07 -0.564 0.35287E+04 230 alabandite -0.98 -4.47 -3.49 -1.164 0.59610E+04 233 boehmite 4.41 0.74 -3.67 -0.611 0.62619E+04 235 ferrous-oxide 9.81 6.73 -3.08 -0.769 0.52532E+04 240 silica-amorphous -2.09 -3.16 -1.07 -0.355 0.18203E+04 242 an20ab80 2.02 1.35 -0.67 -0.052 0.11472E+04 243 an25ab75 2.65 1.78 -0.87 -0.067 0.14810E+04 244 an30ab70 3.28 2.21 -1.07 -0.082 0.18244E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 100.0000000 g Current total amount of reactant added: 9099.9990000 g New total amount of reactant added: 9199.9990000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.5201E-10 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 14 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 9199.9990000 Water: Moles liquid = 0.4138E+01 kg liquid = 0.7454E-01 Moles total = -.5982E+02 kg total = -.1078E+01 Activity = 1.0000 Stoichiometric ionic strength = .1274622E-01 Osmotic coef. = 0.9665 True ionic strength = .2113514E-01 Chg. balance for total moles = 0.5201E-10 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.93172E-10 -10.0307 0.78021E-10 -10.1078 0.83739E+00 -0.0771 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.18420E-02 -2.7347 0.15328E-02 -2.8145 0.83213E+00 -0.0798 4 SO4-- 0.83502E-11 -11.0783 0.42748E-11 -11.3691 0.51194E+00 -0.2908 5 HCO3- 0.30786E-05 -5.5116 0.25657E-05 -5.5908 0.83340E+00 -0.0791 6 HS- 0.34207E-03 -3.4659 0.28469E-03 -3.5456 0.83226E+00 -0.0797 7 Al+++ 0.11645E-28 -28.9339 0.26037E-29 -29.5844 0.22359E+00 -0.6505 8 H4SiO4 0.69598E-03 -3.1574 0.69598E-03 -3.1574 0.10000E+01 0.0000 9 Ca++ 0.15149E-06 -6.8196 0.76957E-07 -7.1138 0.50801E+00 -0.2941 10 Mg++ 0.23704E-10 -10.6252 0.11984E-10 -10.9214 0.50559E+00 -0.2962 11 Fe++ 0.65329E-13 -13.1849 0.33067E-13 -13.4806 0.50617E+00 -0.2957 12 K+ 0.16519E-03 -3.7820 0.13771E-03 -3.8610 0.83361E+00 -0.0790 13 Na+ 0.20964E-01 -1.6785 0.17441E-01 -1.7584 0.83198E+00 -0.0799 14 Mn++ 0.20974E-10 -10.6783 0.10625E-10 -10.9737 0.50660E+00 -0.2953 15 HPO4-- 0.41568E-07 -7.3812 0.21283E-07 -7.6720 0.51201E+00 -0.2907 16 HSiO3- 0.10010E-01 -1.9996 0.83294E-02 -2.0794 0.83213E+00 -0.0798 17 Ca(HSiO3)+ 0.17508E-07 -7.7568 0.14598E-07 -7.8357 0.83380E+00 -0.0789 18 Mg(HSiO3)+ 0.33931E-11 -11.4694 0.28292E-11 -11.5483 0.83380E+00 -0.0789 19 NaHSiO3,aq 0.23496E-02 -2.6290 0.23496E-02 -2.6290 0.10000E+01 0.0000 20 AlO+ 0.69789E-16 -16.1562 0.58190E-16 -16.2352 0.83380E+00 -0.0789 22 HAlO2,aq 0.14853E-09 -9.8282 0.14853E-09 -9.8282 0.10000E+01 0.0000 23 AlO2- 0.50737E-05 -5.2947 0.42140E-05 -5.3753 0.83057E+00 -0.0806 24 CH4,aq 0.16663E-03 -3.7783 0.16598E-03 -3.7799 0.99612E+00 -0.0017 25 C2H6,aq 0.40821E-12 -12.3891 0.40663E-12 -12.3908 0.99612E+00 -0.0017 26 C3H8,aq 0.23089E-19 -19.6366 0.22999E-19 -19.6383 0.99612E+00 -0.0017 28 ethanol,aq 0.14983E-19 -19.8244 0.14925E-19 -19.8261 0.99612E+00 -0.0017 29 CO,aq 0.12445E-15 -15.9050 0.12445E-15 -15.9050 0.10000E+01 0.0000 30 CO2,aq 0.42940E-09 -9.3671 0.42774E-09 -9.3688 0.99612E+00 -0.0017 31 CO3-2 0.56232E-05 -5.2500 0.28724E-05 -5.5418 0.51080E+00 -0.2917 32 CaCO3,aq 0.27717E-08 -8.5573 0.27717E-08 -8.5573 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.60447E-11 -11.2186 0.50401E-11 -11.2976 0.83380E+00 -0.0789 34 CaCl+ 0.22895E-09 -9.6403 0.19090E-09 -9.7192 0.83380E+00 -0.0789 35 CaCl2,aq 0.69518E-13 -13.1579 0.69518E-13 -13.1579 0.10000E+01 0.0000 36 CaOH+ 0.84310E-07 -7.0741 0.70297E-07 -7.1531 0.83380E+00 -0.0789 37 CaSO4,aq 0.10446E-15 -15.9810 0.10446E-15 -15.9810 0.10000E+01 0.0000 38 HCl,aq 0.21915E-13 -13.6593 0.21915E-13 -13.6593 0.10000E+01 0.0000 43 FeCl+ 0.96220E-16 -16.0167 0.80228E-16 -16.0957 0.83380E+00 -0.0789 46 FeO,aq 0.21112E-09 -9.6755 0.21112E-09 -9.6755 0.10000E+01 0.0000 47 FeOH+ 0.16546E-10 -10.7813 0.13796E-10 -10.8602 0.83380E+00 -0.0789 48 HFeO2- 0.34025E-07 -7.4682 0.28313E-07 -7.5480 0.83213E+00 -0.0798 49 FeO+ 0.11596E-16 -16.9357 0.96689E-17 -17.0146 0.83380E+00 -0.0789 51 FeO2- 0.39058E-09 -9.4083 0.32502E-09 -9.4881 0.83213E+00 -0.0798 52 HFeO2,aq 0.32252E-11 -11.4914 0.32252E-11 -11.4914 0.10000E+01 0.0000 53 H2,aq 0.11627E-04 -4.9345 0.11582E-04 -4.9362 0.99612E+00 -0.0017 54 KCl,aq 0.38256E-08 -8.4173 0.38256E-08 -8.4173 0.10000E+01 0.0000 56 KOH,aq 0.75374E-06 -6.1228 0.75374E-06 -6.1228 0.10000E+01 0.0000 57 KSO4- 0.10977E-13 -13.9595 0.91345E-14 -14.0393 0.83213E+00 -0.0798 58 MgCO3,aq 0.10819E-12 -12.9658 0.10819E-12 -12.9658 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.96186E-15 -15.0169 0.80200E-15 -15.0958 0.83380E+00 -0.0789 60 MgCl+ 0.32315E-13 -13.4906 0.26944E-13 -13.5695 0.83380E+00 -0.0789 61 MgOH+ 0.72651E-10 -10.1388 0.60576E-10 -10.2177 0.83380E+00 -0.0789 63 MnO,aq 0.18076E-08 -8.7429 0.18076E-08 -8.7429 0.10000E+01 0.0000 64 MnOH+ 0.49390E-09 -9.3064 0.41181E-09 -9.3853 0.83380E+00 -0.0789 65 MnO2-2 0.19293E-10 -10.7146 0.98551E-11 -11.0063 0.51080E+00 -0.2917 66 HMnO2- 0.20244E-09 -9.6937 0.16845E-09 -9.7735 0.83213E+00 -0.0798 69 MnCl+ 0.12028E-12 -12.9198 0.10029E-12 -12.9987 0.83380E+00 -0.0789 70 MnSO4,aq 0.13113E-19 -19.8823 0.13113E-19 -19.8823 0.10000E+01 0.0000 71 NaCl,aq 0.88598E-05 -5.0526 0.88598E-05 -5.0526 0.10000E+01 0.0000 72 NaOH,aq 0.96046E-04 -4.0175 0.96046E-04 -4.0175 0.10000E+01 0.0000 74 OH- 0.89160E-02 -2.0498 0.74053E-02 -2.1305 0.83057E+00 -0.0806 79 HPO3-2 0.15039E-14 -14.8228 0.76821E-15 -15.1145 0.51080E+00 -0.2917 81 H2PO3- 0.14444E-18 -18.8403 0.12019E-18 -18.9201 0.83213E+00 -0.0798 82 H3PO4,aq 0.90612E-18 -18.0428 0.90612E-18 -18.0428 0.10000E+01 0.0000 83 H2PO4- 0.36776E-10 -10.4344 0.30633E-10 -10.5138 0.83296E+00 -0.0794 84 PO4-3 0.94574E-09 -9.0242 0.22257E-09 -9.6525 0.23534E+00 -0.6283 88 HP2O7-3 0.84128E-18 -18.0751 0.18830E-18 -18.7251 0.22383E+00 -0.6501 89 P2O7-4 0.79154E-17 -17.1015 0.57657E-18 -18.2391 0.72842E-01 -1.1376 90 H2S,aq 0.68916E-07 -7.1617 0.68648E-07 -7.1634 0.99612E+00 -0.0017 91 S2-2 0.30355E-12 -12.5178 0.15505E-12 -12.8095 0.51080E+00 -0.2917 97 SO3-2 0.12409E-16 -16.9063 0.64340E-17 -17.1915 0.51851E+00 -0.2852 98 HSO3- 0.37771E-19 -19.4228 0.31431E-19 -19.5026 0.83213E+00 -0.0798 99 HSO4- 0.38510E-18 -18.4144 0.32142E-18 -18.4929 0.83465E+00 -0.0785 Charge balance for all species = 0.6979E-09 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.9317189E-10 -.2140111E-01 -.2153236E+02 0.0000 2 H2O 0.1000000E+01 0.5550509E+02 0.9981481E+06 0.0000 3 Cl- 0.1842031E-02 0.1850895E-02 0.6550212E+02 7.2933 4 SO4-- 0.8350169E-11 -.1695331E-03 -.1625642E+02 8.8465 5 HCO3- 0.3078582E-05 0.1753313E-03 0.1067904E+02 4.5170 6 HS- 0.3420682E-03 0.5116702E-03 0.1689162E+02 6.5622 7 Al+++ 0.1164512E-28 0.5073812E-05 0.1366536E+00 0.7390 8 H4SiO4 0.6959833E-03 0.1305535E-01 0.1252571E+04 -3.1574 9 Ca++ 0.1514863E-06 0.2563110E-06 0.1025401E-01 13.1018 10 Mg++ 0.2370364E-10 0.9988116E-10 0.2423957E-05 9.2942 11 Fe++ 0.6532892E-13 0.3464622E-07 0.1931418E-02 6.7350 12 K+ 0.1651917E-03 0.1659492E-03 0.6477313E+01 6.2467 13 Na+ 0.2096372E-01 0.2341827E-01 0.5374161E+03 8.3494 14 Mn++ 0.2097379E-10 0.2544369E-08 0.1395319E-03 9.2419 15 HPO4-- 0.4156797E-07 0.4255048E-07 0.4076630E-02 12.5436 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.1523383E+03 -.1595337E-02 -.1523367E+03 0.0000000E+00 2 H2O -.5981751E+02 0.4137604E+01 -.6395512E+02 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.2549888E+00 -.1263777E-04 0.2550015E+00 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.2549633E+00 0.3814224E-04 -.2550015E+00 0.0000000E+00 7 Al+++ 0.2999882E+02 0.3782252E-06 0.2999882E+02 0.0000000E+00 8 H4SiO4 0.9579759E+02 0.9732058E-03 0.9579662E+02 0.0000000E+00 9 Ca++ 0.1058133E+02 0.1910659E-07 0.1058133E+02 0.0000000E+00 10 Mg++ 0.7301587E+01 0.7445600E-11 0.7301587E+01 0.0000000E+00 11 Fe++ 0.6559678E+01 0.2582688E-08 0.6559678E+01 0.0000000E+00 12 K+ 0.1953291E+01 0.1237062E-04 0.1953278E+01 0.0000000E+00 13 Na+ 0.1154840E+02 0.1745705E-02 0.1154665E+02 0.0000000E+00 14 Mn++ 0.1595151E+00 0.1896689E-09 0.1595151E+00 0.0000000E+00 15 HPO4-- 0.5444170E-01 0.3171908E-08 0.5444170E-01 0.0000000E+00 Chg. balance for solid moles: 0.4460E-13 Mass of aqueous solution: 0.746785E+02 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 9199.9990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 11.54 1.062 3025. 3.481 30.10 1161. andradite 1.020 0.009 518.3 2.715 5.157 134.7 grossular 0.2470 -0.607 111.3 2.046 1.107 30.95 apatite-OH 0.1815E-01 -1.741 9.116 0.960 0.9070E-01 2.897 clinochlore 1.306 0.116 725.9 2.861 7.222 276.1 daphnite 0.3781 -0.422 269.7 2.431 2.684 81.74 chlorite-Mn 0.3190E-01 -1.496 22.62 1.354 0.2250 7.208 diopside 0.4911 -0.309 106.4 2.027 1.058 32.51 hedenbergite 0.1274 -0.895 31.60 1.500 0.3144 8.655 microcline 1.713 0.234 476.7 2.678 4.743 186.2 stilbite 5.916 0.772 4169. 3.620 41.48 1945. stilpnomelane-Fe 0.4810 -0.318 518.5 2.715 5.159 179.1 tr.625ac.25prg.125 0.7750E-01 -1.111 66.25 1.821 0.6591 21.32 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8051E+00 0.8051E+00 1.0000 -0.094 grossular 0.1949E+00 0.1949E+00 1.0000 -0.710 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.7611E+00 0.7611E+00 1.0000 -0.119 daphnite 0.2203E+00 0.2203E+00 1.0000 -0.657 chlorite-Mn 0.1859E-01 0.1859E-01 1.0000 -1.731 diopside 0.7941E+00 0.7941E+00 1.0000 -0.100 hedenbergite 0.2059E+00 0.2059E+00 1.0000 -0.686 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 tr.625ac.25prg.125 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass =10050.865622 g Volume = 4067.306471 cm3 Porosity: -10.4946% V(tot) - V(min): -.38631E+03 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 9199.9990000 g log = 3.9638 Original solution: 1000.0103000 g Original solution / Rock added: 0.11 (Water/Rock Ratio), log = -0.9638 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.2805 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.7992E+00 0.9830 0.1006E+01 0.1023E+01 CO2,gas 0.3559E-07 1.0042 0.4576E-07 0.4557E-07 CH4,gas 0.1889E+00 1.0100 0.2443E+00 0.2419E+00 H2,gas 0.1187E-01 1.0007 0.1521E-01 0.1520E-01 H2S,gas 0.1481E-05 0.9950 0.1887E-05 0.1897E-05 S2,gas 0.4515E-27 1.0000 0.5781E-27 0.5781E-27 CO,gas 0.1448E-12 1.0000 0.1855E-12 0.1855E-12 SO3,gas 0.7684E-47 1.0000 0.9839E-47 0.9839E-47 SO2,gas 0.4546E-26 1.0000 0.5821E-26 0.5821E-26 HCl,gas 0.3020E-16 1.0000 0.3867E-16 0.3867E-16 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 16 albite -0.38 -0.38 0.00 0.000 0.11184E-10 22 andradite 39.01 39.01 0.00 0.000 0.12132E-10 23 grossular 32.73 32.73 0.00 0.000 0.00000E+00 32 apatite-OH -18.15 -18.15 0.00 0.000 0.12132E-10 46 clinochlore 39.07 39.07 0.00 0.000 0.12132E-10 47 daphnite 28.97 28.97 0.00 0.000 0.00000E+00 48 chlorite-Mn 46.87 46.87 0.00 0.000 0.24265E-10 67 diopside 16.18 16.18 0.00 0.000 0.60662E-11 68 hedenbergite 14.21 14.21 0.00 0.000 0.60662E-11 116 microcline -2.49 -2.49 0.00 0.000 0.13649E-10 163 stilbite -7.52 -7.52 0.00 0.000 0.39430E-10 164 stilpnomelane-Fe 13.02 13.02 0.00 0.000 -0.27298E-10 245 tr.625ac.25prg.125 45.16 45.16 0.00 0.000 -0.24265E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -15.70 -9.04 -3.013 0.15433E+05 -7.339 3 CH4,gas 4.54 2.23 -2.31 -0.578 0.39460E+04 -0.612 4 H2,gas 8.00 4.48 -3.52 -2.010 0.60051E+04 -1.818 5 H2S,gas -6.23 -13.65 -7.42 -3.712 0.12675E+05 -5.724 6 S2,gas -7.34 -36.27 -28.94 -4.452 0.49409E+05 -27.238 7 CO,gas 3.21 -11.22 -14.43 -4.440 0.24640E+05 -12.732 8 SO3,gas 17.12 -31.58 -48.71 -12.177 0.83164E+05 -47.007 9 SO2,gas 0.83 -27.10 -27.93 -7.449 0.47697E+05 -26.235 10 HCl,gas 5.19 -12.92 -18.11 -9.056 0.30925E+05 -16.413 11 acmite 7.71 6.53 -1.18 -0.123 0.20175E+04 15 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 19 spessartine 24.46 19.73 -4.73 -0.236 0.80692E+04 20 analcite 3.32 2.77 -0.55 -0.061 0.93626E+03 26 annite 20.12 17.72 -2.40 -0.134 0.41064E+04 27 phlogopite 27.06 25.40 -1.67 -0.093 0.28490E+04 29 anorthite 12.71 8.26 -4.45 -0.342 0.75903E+04 35 aragonite 0.97 -2.60 -3.56 -1.188 0.60842E+04 36 brucite 12.57 9.29 -3.27 -0.655 0.55909E+04 37 calcite 0.81 -2.60 -3.41 -1.136 0.58200E+04 38 carnegieite-low 9.02 5.93 -3.09 -0.442 0.52801E+04 39 carnegieite-high 10.09 5.93 -4.16 -0.595 0.71071E+04 40 carpholite-Mg 8.58 4.46 -4.12 -0.275 0.70429E+04 41 carpholite-Fe 6.71 1.90 -4.81 -0.321 0.82207E+04 42 celadonite 5.34 3.65 -1.69 -0.099 0.28879E+04 43 celadonite-Fe 3.88 1.09 -2.79 -0.164 0.47561E+04 44 chrysotile 23.89 21.57 -2.32 -0.194 0.39692E+04 49 chlorite-Al-free 47.17 43.14 -4.04 -0.168 0.68936E+04 51 chloritoid-Fe 9.17 5.06 -4.12 -0.275 0.70316E+04 52 chloritoid-Mn 11.40 7.56 -3.84 -0.256 0.65544E+04 54 coesite -2.38 -3.16 -0.78 -0.260 0.13341E+04 61 cristobalite -2.56 -3.16 -0.60 -0.199 0.10195E+04 63 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71234E+04 65 diaspore 2.87 0.74 -2.13 -0.356 0.36450E+04 66 diamond -3.10 -6.73 -3.63 -1.037 0.61991E+04 71 enstatite 17.26 12.27 -4.99 -0.499 0.85226E+04 73 clinoenstatite 17.17 12.27 -4.89 -0.489 0.83542E+04 75 epidote 24.67 22.70 -1.97 -0.095 0.33586E+04 76 clinozoisite 22.81 18.95 -3.86 -0.175 0.65869E+04 77 epidote-Fe 29.84 26.46 -3.38 -0.176 0.57768E+04 78 fayalite 14.05 10.31 -3.73 -0.533 0.63743E+04 79 ferrosilite 11.15 7.16 -3.99 -0.399 0.68202E+04 83 gibbsite 4.08 0.74 -3.34 -0.477 0.57036E+04 84 glaucophane 22.97 20.80 -2.17 -0.059 0.37134E+04 85 glaucophane-Fe 17.28 13.12 -4.15 -0.112 0.70919E+04 86 graphite -3.55 -6.73 -3.19 -0.911 0.54413E+04 87 greenalite 16.14 13.89 -2.25 -0.187 0.38408E+04 90 hematite 12.57 8.99 -3.58 -0.434 0.61111E+04 91 heulandite -5.83 -7.52 -1.69 -0.077 0.28938E+04 95 jadeite 4.22 2.77 -1.44 -0.144 0.24617E+04 97 kalsilite 7.58 3.83 -3.76 -0.537 0.64126E+04 98 kaolinite -1.33 -4.84 -3.50 -0.319 0.59832E+04 101 laumontite 2.88 1.95 -0.93 -0.062 0.15935E+04 102 lawsonite 9.62 8.26 -1.35 -0.090 0.23070E+04 103 leucite 4.12 0.67 -3.45 -0.345 0.58873E+04 105 lizardite 23.24 21.57 -1.68 -0.140 0.28619E+04 107 magnetite 20.09 15.72 -4.37 -0.356 0.74536E+04 108 minnesotaite 10.39 7.58 -2.81 -0.165 0.48027E+04 112 manganosite 14.06 9.24 -4.82 -1.204 0.82235E+04 120 muscovite 2.58 -1.01 -3.59 -0.211 0.61315E+04 121 paragonite 4.24 1.09 -3.15 -0.185 0.53706E+04 122 nepheline 8.34 5.93 -2.41 -0.344 0.41125E+04 128 periclase-Fe 11.63 6.73 -4.89 -1.223 0.83523E+04 134 phlogopite-Na 29.65 27.50 -2.15 -0.119 0.36678E+04 136 prehnite 19.37 18.21 -1.16 -0.068 0.19849E+04 137 prehnite-Fe 22.50 21.96 -0.53 -0.032 0.91159E+03 138 pumpellyite-Fe 46.27 43.89 -2.38 -0.053 0.40582E+04 139 pumpellyite-Mg 48.99 46.45 -2.54 -0.057 0.43421E+04 142 pyrite -21.25 -25.05 -3.81 -0.896 0.65016E+04 143 pyrrhotite -4.26 -6.92 -2.66 -0.886 0.45387E+04 144 pyrrhotiteFe0.875 -6.02 -8.32 -2.30 -0.846 0.39259E+04 145 pyroxmangite 7.40 6.08 -1.31 -0.263 0.22439E+04 146 pyrophyllite -6.18 -11.15 -4.98 -0.311 0.84962E+04 147 quartz -2.99 -3.16 -0.17 -0.056 0.28679E+03 152 rhodonite 7.45 6.08 -1.36 -0.272 0.23241E+04 153 sanidine -1.28 -2.49 -1.21 -0.093 0.20677E+04 165 stilpnomelane-Mg 27.44 25.81 -1.63 -0.049 0.27804E+04 171 talc 16.49 15.25 -1.24 -0.073 0.21140E+04 174 tephroite 18.09 15.33 -2.76 -0.394 0.47115E+04 178 tridymite -2.63 -3.16 -0.53 -0.177 0.90677E+03 179 tremolite 47.87 47.42 -0.45 -0.012 0.77494E+03 180 ferroactinolite 38.45 34.62 -3.83 -0.104 0.65448E+04 181 troilite-low -4.41 -6.92 -2.51 -0.836 0.42815E+04 183 vesuvianite 223.47 218.82 -4.65 -0.036 0.79441E+04 187 wairakite 3.95 1.95 -2.00 -0.118 0.34155E+04 188 walstromite 11.51 9.94 -1.56 -0.313 0.26719E+04 189 wollastonite 10.46 9.94 -0.52 -0.103 0.88229E+03 190 pseudo-wollastonite 11.00 9.94 -1.06 -0.211 0.18021E+04 191 zoisite 22.85 18.95 -3.90 -0.177 0.66610E+04 192 akaganeite 7.75 4.49 -3.26 -0.705 0.55681E+04 199 chalcedony -2.80 -3.16 -0.35 -0.118 0.60609E+03 201 montmorillonite-Ca -2.29 -6.17 -3.88 -0.240 0.66180E+04 202 montmorillonite-K -2.24 -6.27 -4.03 -0.247 0.68816E+04 203 montmorillonite-Mg -2.48 -6.79 -4.32 -0.267 0.73678E+04 204 montmorillonite-Na -2.04 -5.57 -3.54 -0.216 0.60365E+04 205 nontronite-Ca 3.21 -0.19 -3.41 -0.221 0.58215E+04 206 nontronite-H 2.53 -2.36 -4.89 -0.328 0.83484E+04 207 nontronite-K 3.34 -0.30 -3.64 -0.233 0.62083E+04 208 nontronite-Mg 3.07 -0.82 -3.90 -0.253 0.66553E+04 209 nontronite-Na 3.52 0.40 -3.12 -0.200 0.53291E+04 224 tobermorite 9.82 7.76 -2.07 -0.564 0.35287E+04 230 alabandite -0.98 -4.41 -3.43 -1.145 0.58628E+04 233 boehmite 4.41 0.74 -3.67 -0.611 0.62619E+04 235 ferrous-oxide 9.81 6.73 -3.08 -0.769 0.52532E+04 240 silica-amorphous -2.09 -3.16 -1.07 -0.355 0.18203E+04 242 an20ab80 2.02 1.35 -0.67 -0.052 0.11472E+04 243 an25ab75 2.65 1.78 -0.87 -0.067 0.14810E+04 244 an30ab70 3.28 2.21 -1.07 -0.082 0.18244E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 100.0000000 g Current total amount of reactant added: 9199.9990000 g New total amount of reactant added: 9299.9990000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.5198E-10 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 14 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 9299.9990000 Water: Moles liquid = 0.3580E+01 kg liquid = 0.6450E-01 Moles total = -.6107E+02 kg total = -.1100E+01 Activity = 1.0000 Stoichiometric ionic strength = .1298890E-01 Osmotic coef. = 0.9662 True ionic strength = .2132960E-01 Chg. balance for total moles = 0.5198E-10 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.94022E-10 -10.0268 0.78687E-10 -10.1041 0.83690E+00 -0.0773 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.21287E-02 -2.6719 0.17703E-02 -2.7520 0.83161E+00 -0.0801 4 SO4-- 0.95859E-11 -11.0184 0.48954E-11 -11.3102 0.51069E+00 -0.2918 5 HCO3- 0.35318E-05 -5.4520 0.29416E-05 -5.5314 0.83289E+00 -0.0794 6 HS- 0.39533E-03 -3.4030 0.32881E-03 -3.4831 0.83174E+00 -0.0800 7 Al+++ 0.12013E-28 -28.9204 0.26710E-29 -29.5733 0.22235E+00 -0.6530 8 H4SiO4 0.69598E-03 -3.1574 0.69598E-03 -3.1574 0.10000E+01 0.0000 9 Ca++ 0.15447E-06 -6.8112 0.78276E-07 -7.1064 0.50675E+00 -0.2952 10 Mg++ 0.24171E-10 -10.6167 0.12190E-10 -10.9140 0.50431E+00 -0.2973 11 Fe++ 0.66616E-13 -13.1764 0.33634E-13 -13.4732 0.50489E+00 -0.2968 12 K+ 0.16670E-03 -3.7781 0.13888E-03 -3.8574 0.83310E+00 -0.0793 13 Na+ 0.21156E-01 -1.6746 0.17590E-01 -1.7547 0.83145E+00 -0.0802 14 Mn++ 0.21387E-10 -10.6698 0.10808E-10 -10.9663 0.50533E+00 -0.2964 15 HPO4-- 0.40967E-07 -7.3876 0.20925E-07 -7.6793 0.51077E+00 -0.2918 16 HSiO3- 0.99312E-02 -2.0030 0.82589E-02 -2.0831 0.83161E+00 -0.0801 17 Ca(HSiO3)+ 0.17668E-07 -7.7528 0.14723E-07 -7.8320 0.83329E+00 -0.0792 18 Mg(HSiO3)+ 0.34242E-11 -11.4654 0.28533E-11 -11.5446 0.83329E+00 -0.0792 19 NaHSiO3,aq 0.23496E-02 -2.6290 0.23496E-02 -2.6290 0.10000E+01 0.0000 20 AlO+ 0.70428E-16 -16.1523 0.58687E-16 -16.2315 0.83329E+00 -0.0792 22 HAlO2,aq 0.14853E-09 -9.8282 0.14853E-09 -9.8282 0.10000E+01 0.0000 23 AlO2- 0.50340E-05 -5.2981 0.41784E-05 -5.3790 0.83004E+00 -0.0809 24 CH4,aq 0.19269E-03 -3.7152 0.19192E-03 -3.7169 0.99605E+00 -0.0017 25 C2H6,aq 0.54584E-12 -12.2629 0.54369E-12 -12.2647 0.99605E+00 -0.0017 26 C3H8,aq 0.35699E-19 -19.4473 0.35558E-19 -19.4491 0.99605E+00 -0.0017 28 ethanol,aq 0.20035E-19 -19.6982 0.19956E-19 -19.6999 0.99605E+00 -0.0017 29 CO,aq 0.14391E-15 -15.8419 0.14391E-15 -15.8419 0.10000E+01 0.0000 30 CO2,aq 0.49656E-09 -9.3040 0.49460E-09 -9.3057 0.99605E+00 -0.0017 31 CO3-2 0.64083E-05 -5.1933 0.32654E-05 -5.4861 0.50955E+00 -0.2928 32 CaCO3,aq 0.32049E-08 -8.4942 0.32049E-08 -8.4942 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.70536E-11 -11.1516 0.58776E-11 -11.2308 0.83329E+00 -0.0792 34 CaCl+ 0.26912E-09 -9.5701 0.22425E-09 -9.6493 0.83329E+00 -0.0792 35 CaCl2,aq 0.94317E-13 -13.0254 0.94317E-13 -13.0254 0.10000E+01 0.0000 36 CaOH+ 0.85081E-07 -7.0702 0.70897E-07 -7.1494 0.83329E+00 -0.0792 37 CaSO4,aq 0.12168E-15 -15.9148 0.12168E-15 -15.9148 0.10000E+01 0.0000 38 HCl,aq 0.25526E-13 -13.5930 0.25526E-13 -13.5930 0.10000E+01 0.0000 43 FeCl+ 0.11310E-15 -15.9465 0.94245E-16 -16.0257 0.83329E+00 -0.0792 46 FeO,aq 0.21112E-09 -9.6755 0.21112E-09 -9.6755 0.10000E+01 0.0000 47 FeOH+ 0.16697E-10 -10.7774 0.13914E-10 -10.8566 0.83329E+00 -0.0792 48 HFeO2- 0.33758E-07 -7.4716 0.28074E-07 -7.5517 0.83161E+00 -0.0801 49 FeO+ 0.11702E-16 -16.9317 0.97515E-17 -17.0109 0.83329E+00 -0.0792 51 FeO2- 0.38752E-09 -9.4117 0.32226E-09 -9.4918 0.83161E+00 -0.0801 52 HFeO2,aq 0.32252E-11 -11.4915 0.32252E-11 -11.4915 0.10000E+01 0.0000 53 H2,aq 0.11628E-04 -4.9345 0.11582E-04 -4.9362 0.99605E+00 -0.0017 54 KCl,aq 0.44560E-08 -8.3511 0.44560E-08 -8.3511 0.10000E+01 0.0000 56 KOH,aq 0.75374E-06 -6.1228 0.75374E-06 -6.1228 0.10000E+01 0.0000 57 KSO4- 0.12686E-13 -13.8967 0.10550E-13 -13.9767 0.83161E+00 -0.0801 58 MgCO3,aq 0.12510E-12 -12.9027 0.12510E-12 -12.9027 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.11224E-14 -14.9499 0.93527E-15 -15.0291 0.83329E+00 -0.0792 60 MgCl+ 0.37984E-13 -13.4204 0.31651E-13 -13.4996 0.83329E+00 -0.0792 61 MgOH+ 0.73316E-10 -10.1348 0.61093E-10 -10.2140 0.83329E+00 -0.0792 63 MnO,aq 0.18077E-08 -8.7429 0.18077E-08 -8.7429 0.10000E+01 0.0000 64 MnOH+ 0.49842E-09 -9.3024 0.41533E-09 -9.3816 0.83329E+00 -0.0792 65 MnO2-2 0.19015E-10 -10.7209 0.96891E-11 -11.0137 0.50955E+00 -0.2928 66 HMnO2- 0.20085E-09 -9.6971 0.16703E-09 -9.7772 0.83161E+00 -0.0801 69 MnCl+ 0.14139E-12 -12.8496 0.11782E-12 -12.9288 0.83329E+00 -0.0792 70 MnSO4,aq 0.15274E-19 -19.8160 0.15274E-19 -19.8160 0.10000E+01 0.0000 71 NaCl,aq 0.10320E-04 -4.9863 0.10320E-04 -4.9863 0.10000E+01 0.0000 72 NaOH,aq 0.96046E-04 -4.0175 0.96046E-04 -4.0175 0.10000E+01 0.0000 74 OH- 0.88462E-02 -2.0532 0.73427E-02 -2.1341 0.83004E+00 -0.0809 79 HPO3-2 0.14822E-14 -14.8291 0.75526E-15 -15.1219 0.50955E+00 -0.2928 81 H2PO3- 0.14330E-18 -18.8437 0.11917E-18 -18.9238 0.83161E+00 -0.0801 82 H3PO4,aq 0.90612E-18 -18.0428 0.90612E-18 -18.0428 0.10000E+01 0.0000 83 H2PO4- 0.36487E-10 -10.4379 0.30373E-10 -10.5175 0.83244E+00 -0.0796 84 PO4-3 0.92675E-09 -9.0330 0.21696E-09 -9.6636 0.23411E+00 -0.6306 88 HP2O7-3 0.82469E-18 -18.0837 0.18356E-18 -18.7362 0.22258E+00 -0.6525 89 P2O7-4 0.77254E-17 -17.1121 0.55730E-18 -18.2539 0.72139E-01 -1.1418 90 H2S,aq 0.80281E-07 -7.0954 0.79963E-07 -7.0971 0.99605E+00 -0.0017 91 S2-2 0.40592E-12 -12.3916 0.20684E-12 -12.6844 0.50955E+00 -0.2928 97 SO3-2 0.14244E-16 -16.8464 0.73682E-17 -17.1326 0.51730E+00 -0.2863 98 HSO3- 0.43652E-19 -19.3600 0.36301E-19 -19.4401 0.83161E+00 -0.0801 99 HSO4- 0.44504E-18 -18.3516 0.37123E-18 -18.4304 0.83414E+00 -0.0788 Charge balance for all species = 0.8054E-09 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.9402166E-10 -.2125345E-01 -.2138358E+02 0.0000 2 H2O 0.1000000E+01 0.5550513E+02 0.9981390E+06 0.0000 3 Cl- 0.2128745E-02 0.2139070E-02 0.7569973E+02 7.3521 4 SO4-- 0.9585908E-11 -.1955926E-03 -.1875507E+02 8.8980 5 HCO3- 0.3531844E-05 0.2026295E-03 0.1234160E+02 4.5727 6 HS- 0.3953258E-03 0.5909988E-03 0.1951028E+02 6.6210 7 Al+++ 0.1201267E-28 0.5034101E-05 0.1355828E+00 0.7390 8 H4SiO4 0.6959828E-03 0.1297686E-01 0.1245028E+04 -3.1574 9 Ca++ 0.1544674E-06 0.2606983E-06 0.1042943E-01 13.1018 10 Mg++ 0.2417094E-10 0.1010840E-09 0.2453125E-05 9.2942 11 Fe++ 0.6661631E-13 0.3437653E-07 0.1916365E-02 6.7350 12 K+ 0.1667035E-03 0.1674617E-03 0.6536282E+01 6.2467 13 Na+ 0.2115588E-01 0.2361188E-01 0.5418540E+03 8.3494 14 Mn++ 0.2138719E-10 0.2547484E-08 0.1397014E-03 9.2419 15 HPO4-- 0.4096709E-07 0.4193033E-07 0.4017176E-02 12.5289 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.1539942E+03 -.1370889E-02 -.1539928E+03 0.0000000E+00 2 H2O -.6107105E+02 0.3580190E+01 -.6465124E+02 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.2577602E+00 -.1261611E-04 0.2577728E+00 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.2577347E+00 0.3812058E-04 -.2577728E+00 0.0000000E+00 7 Al+++ 0.3032489E+02 0.3247094E-06 0.3032489E+02 0.0000000E+00 8 H4SiO4 0.9683887E+02 0.8370332E-03 0.9683803E+02 0.0000000E+00 9 Ca++ 0.1069634E+02 0.1681555E-07 0.1069634E+02 0.0000000E+00 10 Mg++ 0.7380952E+01 0.6520118E-11 0.7380952E+01 0.0000000E+00 11 Fe++ 0.6630979E+01 0.2217353E-08 0.6630979E+01 0.0000000E+00 12 K+ 0.1974522E+01 0.1080161E-04 0.1974511E+01 0.0000000E+00 13 Na+ 0.1167392E+02 0.1523013E-02 0.1167240E+02 0.0000000E+00 14 Mn++ 0.1612489E+00 0.1643177E-09 0.1612489E+00 0.0000000E+00 15 HPO4-- 0.5503346E-01 0.2704588E-08 0.5503345E-01 0.0000000E+00 Chg. balance for solid moles: 0.2325E-13 Mass of aqueous solution: 0.646184E+02 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 9299.9990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 11.66 1.067 3058. 3.485 30.10 1174. andradite 1.031 0.013 524.0 2.719 5.157 136.1 grossular 0.2497 -0.603 112.5 2.051 1.107 31.29 apatite-OH 0.1834E-01 -1.736 9.215 0.964 0.9070E-01 2.928 clinochlore 1.320 0.121 733.7 2.866 7.222 279.1 daphnite 0.3822 -0.418 272.7 2.436 2.684 82.63 chlorite-Mn 0.3225E-01 -1.491 22.86 1.359 0.2250 7.286 diopside 0.4966 -0.304 107.5 2.032 1.058 32.87 hedenbergite 0.1288 -0.890 31.95 1.504 0.3145 8.751 microcline 1.731 0.238 481.9 2.683 4.743 188.2 stilbite 5.980 0.777 4214. 3.625 41.48 1966. stilpnomelane-Fe 0.4863 -0.313 524.2 2.719 5.159 181.1 tr.625ac.25prg.125 0.7834E-01 -1.106 66.96 1.826 0.6591 21.55 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8051E+00 0.8051E+00 1.0000 -0.094 grossular 0.1949E+00 0.1949E+00 1.0000 -0.710 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.7611E+00 0.7611E+00 1.0000 -0.119 daphnite 0.2203E+00 0.2203E+00 1.0000 -0.657 chlorite-Mn 0.1859E-01 0.1859E-01 1.0000 -1.731 diopside 0.7941E+00 0.7941E+00 1.0000 -0.100 hedenbergite 0.2059E+00 0.2059E+00 1.0000 -0.686 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 tr.625ac.25prg.125 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass =10160.116253 g Volume = 4111.509518 cm3 Porosity: -10.4948% V(tot) - V(min): -.39051E+03 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 9299.9990000 g log = 3.9685 Original solution: 1000.0103000 g Original solution / Rock added: 0.11 (Water/Rock Ratio), log = -0.9685 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.3187 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.7763E+00 0.9826 0.1006E+01 0.1024E+01 CO2,gas 0.3997E-07 1.0039 0.5292E-07 0.5271E-07 CH4,gas 0.2122E+00 1.0096 0.2825E+00 0.2798E+00 H2,gas 0.1152E-01 1.0007 0.1521E-01 0.1520E-01 H2S,gas 0.1675E-05 0.9949 0.2198E-05 0.2209E-05 S2,gas 0.5948E-27 1.0000 0.7844E-27 0.7844E-27 CO,gas 0.1626E-12 1.0000 0.2144E-12 0.2144E-12 SO3,gas 0.8691E-47 1.0000 0.1146E-46 0.1146E-46 SO2,gas 0.5141E-26 1.0000 0.6780E-26 0.6780E-26 HCl,gas 0.3415E-16 1.0000 0.4504E-16 0.4504E-16 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 16 albite -0.38 -0.38 0.00 0.000 -0.13080E-10 22 andradite 39.01 39.01 0.00 0.000 -0.12132E-10 23 grossular 32.73 32.73 0.00 0.000 0.00000E+00 32 apatite-OH -18.15 -18.15 0.00 0.000 -0.60662E-11 46 clinochlore 39.07 39.07 0.00 0.000 -0.12132E-10 47 daphnite 28.97 28.97 0.00 0.000 -0.36397E-10 48 chlorite-Mn 46.87 46.87 0.00 0.000 -0.60662E-10 67 diopside 16.18 16.18 0.00 0.000 -0.12132E-10 68 hedenbergite 14.21 14.21 0.00 0.000 -0.12132E-10 116 microcline -2.49 -2.49 0.00 0.000 -0.10616E-10 163 stilbite -7.52 -7.52 0.00 0.000 -0.57629E-10 164 stilpnomelane-Fe 13.02 13.02 0.00 0.000 -0.27298E-10 245 tr.625ac.25prg.125 45.16 45.16 0.00 0.000 0.48529E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -15.64 -8.98 -2.992 0.15325E+05 -7.276 3 CH4,gas 4.54 2.30 -2.25 -0.562 0.38383E+04 -0.549 4 H2,gas 8.00 4.48 -3.52 -2.010 0.60051E+04 -1.818 5 H2S,gas -6.23 -13.59 -7.36 -3.678 0.12562E+05 -5.658 6 S2,gas -7.34 -36.14 -28.80 -4.431 0.49183E+05 -27.105 7 CO,gas 3.21 -11.15 -14.37 -4.421 0.24532E+05 -12.669 8 SO3,gas 17.12 -31.52 -48.64 -12.160 0.83051E+05 -46.941 9 SO2,gas 0.83 -27.04 -27.87 -7.431 0.47583E+05 -26.169 10 HCl,gas 5.19 -12.86 -18.05 -9.023 0.30812E+05 -16.346 11 acmite 7.71 6.53 -1.18 -0.123 0.20175E+04 15 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 19 spessartine 24.46 19.73 -4.73 -0.236 0.80692E+04 20 analcite 3.32 2.77 -0.55 -0.061 0.93626E+03 26 annite 20.12 17.72 -2.40 -0.134 0.41064E+04 27 phlogopite 27.06 25.40 -1.67 -0.093 0.28490E+04 29 anorthite 12.71 8.26 -4.45 -0.342 0.75903E+04 35 aragonite 0.97 -2.53 -3.50 -1.167 0.59765E+04 36 brucite 12.57 9.29 -3.27 -0.655 0.55909E+04 37 calcite 0.81 -2.53 -3.35 -1.115 0.57123E+04 38 carnegieite-low 9.02 5.93 -3.09 -0.442 0.52801E+04 39 carnegieite-high 10.09 5.93 -4.16 -0.595 0.71071E+04 40 carpholite-Mg 8.58 4.46 -4.12 -0.275 0.70429E+04 41 carpholite-Fe 6.71 1.90 -4.81 -0.321 0.82207E+04 42 celadonite 5.34 3.65 -1.69 -0.099 0.28879E+04 43 celadonite-Fe 3.88 1.09 -2.79 -0.164 0.47561E+04 44 chrysotile 23.89 21.57 -2.32 -0.194 0.39692E+04 49 chlorite-Al-free 47.17 43.14 -4.04 -0.168 0.68936E+04 51 chloritoid-Fe 9.17 5.06 -4.12 -0.275 0.70316E+04 52 chloritoid-Mn 11.40 7.56 -3.84 -0.256 0.65543E+04 54 coesite -2.38 -3.16 -0.78 -0.260 0.13341E+04 61 cristobalite -2.56 -3.16 -0.60 -0.199 0.10195E+04 63 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71234E+04 65 diaspore 2.87 0.74 -2.13 -0.356 0.36450E+04 66 diamond -3.10 -6.67 -3.57 -1.019 0.60914E+04 71 enstatite 17.26 12.27 -4.99 -0.499 0.85226E+04 73 clinoenstatite 17.17 12.27 -4.89 -0.489 0.83542E+04 75 epidote 24.67 22.70 -1.97 -0.095 0.33586E+04 76 clinozoisite 22.81 18.95 -3.86 -0.175 0.65869E+04 77 epidote-Fe 29.84 26.46 -3.38 -0.176 0.57768E+04 78 fayalite 14.05 10.31 -3.73 -0.533 0.63743E+04 79 ferrosilite 11.15 7.16 -3.99 -0.399 0.68202E+04 83 gibbsite 4.08 0.74 -3.34 -0.477 0.57036E+04 84 glaucophane 22.97 20.80 -2.17 -0.059 0.37134E+04 85 glaucophane-Fe 17.28 13.12 -4.15 -0.112 0.70919E+04 86 graphite -3.55 -6.67 -3.12 -0.892 0.53336E+04 87 greenalite 16.14 13.89 -2.25 -0.187 0.38408E+04 90 hematite 12.57 8.99 -3.58 -0.434 0.61111E+04 91 heulandite -5.83 -7.52 -1.69 -0.077 0.28938E+04 95 jadeite 4.22 2.77 -1.44 -0.144 0.24617E+04 97 kalsilite 7.58 3.83 -3.76 -0.537 0.64126E+04 98 kaolinite -1.33 -4.84 -3.50 -0.319 0.59832E+04 101 laumontite 2.88 1.95 -0.93 -0.062 0.15935E+04 102 lawsonite 9.62 8.26 -1.35 -0.090 0.23070E+04 103 leucite 4.12 0.67 -3.45 -0.345 0.58873E+04 105 lizardite 23.24 21.57 -1.68 -0.140 0.28619E+04 107 magnetite 20.09 15.72 -4.37 -0.356 0.74536E+04 108 minnesotaite 10.39 7.58 -2.81 -0.165 0.48027E+04 112 manganosite 14.06 9.24 -4.82 -1.204 0.82235E+04 120 muscovite 2.58 -1.01 -3.59 -0.211 0.61315E+04 121 paragonite 4.24 1.09 -3.15 -0.185 0.53706E+04 122 nepheline 8.34 5.93 -2.41 -0.344 0.41125E+04 128 periclase-Fe 11.63 6.73 -4.89 -1.223 0.83523E+04 134 phlogopite-Na 29.65 27.50 -2.15 -0.119 0.36678E+04 136 prehnite 19.37 18.21 -1.16 -0.068 0.19849E+04 137 prehnite-Fe 22.50 21.96 -0.53 -0.032 0.91159E+03 138 pumpellyite-Fe 46.27 43.89 -2.38 -0.053 0.40582E+04 139 pumpellyite-Mg 48.99 46.45 -2.54 -0.057 0.43421E+04 142 pyrite -21.25 -24.92 -3.68 -0.865 0.62753E+04 143 pyrrhotite -4.26 -6.85 -2.59 -0.864 0.44255E+04 144 pyrrhotiteFe0.875 -6.02 -8.25 -2.23 -0.821 0.38127E+04 145 pyroxmangite 7.40 6.08 -1.31 -0.263 0.22439E+04 146 pyrophyllite -6.18 -11.15 -4.98 -0.311 0.84962E+04 147 quartz -2.99 -3.16 -0.17 -0.056 0.28679E+03 152 rhodonite 7.45 6.08 -1.36 -0.272 0.23241E+04 153 sanidine -1.28 -2.49 -1.21 -0.093 0.20677E+04 165 stilpnomelane-Mg 27.44 25.81 -1.63 -0.049 0.27804E+04 171 talc 16.49 15.25 -1.24 -0.073 0.21140E+04 174 tephroite 18.09 15.33 -2.76 -0.394 0.47115E+04 178 tridymite -2.63 -3.16 -0.53 -0.177 0.90677E+03 179 tremolite 47.87 47.42 -0.45 -0.012 0.77494E+03 180 ferroactinolite 38.45 34.62 -3.83 -0.104 0.65448E+04 181 troilite-low -4.41 -6.85 -2.44 -0.814 0.41683E+04 183 vesuvianite 223.47 218.82 -4.65 -0.036 0.79441E+04 187 wairakite 3.95 1.95 -2.00 -0.118 0.34155E+04 188 walstromite 11.51 9.94 -1.56 -0.313 0.26719E+04 189 wollastonite 10.46 9.94 -0.52 -0.103 0.88229E+03 190 pseudo-wollastonite 11.00 9.94 -1.06 -0.211 0.18021E+04 191 zoisite 22.85 18.95 -3.90 -0.177 0.66610E+04 192 akaganeite 7.75 4.49 -3.26 -0.705 0.55681E+04 199 chalcedony -2.80 -3.16 -0.35 -0.118 0.60609E+03 201 montmorillonite-Ca -2.29 -6.17 -3.88 -0.240 0.66180E+04 202 montmorillonite-K -2.24 -6.27 -4.03 -0.247 0.68816E+04 203 montmorillonite-Mg -2.48 -6.79 -4.32 -0.267 0.73678E+04 204 montmorillonite-Na -2.04 -5.57 -3.54 -0.216 0.60365E+04 205 nontronite-Ca 3.21 -0.19 -3.41 -0.221 0.58215E+04 206 nontronite-H 2.53 -2.36 -4.89 -0.328 0.83484E+04 207 nontronite-K 3.34 -0.30 -3.64 -0.233 0.62083E+04 208 nontronite-Mg 3.07 -0.82 -3.90 -0.253 0.66553E+04 209 nontronite-Na 3.52 0.40 -3.12 -0.200 0.53291E+04 224 tobermorite 9.82 7.76 -2.07 -0.564 0.35287E+04 230 alabandite -0.98 -4.35 -3.37 -1.122 0.57497E+04 233 boehmite 4.41 0.74 -3.67 -0.611 0.62619E+04 235 ferrous-oxide 9.81 6.73 -3.08 -0.769 0.52532E+04 240 silica-amorphous -2.09 -3.16 -1.07 -0.355 0.18203E+04 242 an20ab80 2.02 1.35 -0.67 -0.052 0.11472E+04 243 an25ab75 2.65 1.78 -0.87 -0.067 0.14810E+04 244 an30ab70 3.28 2.21 -1.07 -0.082 0.18244E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 100.0000000 g Current total amount of reactant added: 9299.9990000 g New total amount of reactant added: 9399.9990000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.5194E-10 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 14 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 9399.9990000 Water: Moles liquid = 0.3023E+01 kg liquid = 0.5446E-01 Moles total = -.6232E+02 kg total = -.1123E+01 Activity = 1.0000 Stoichiometric ionic strength = .1332218E-01 Osmotic coef. = 0.9659 True ionic strength = .2159805E-01 Chg. balance for total moles = 0.5194E-10 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.95195E-10 -10.0214 0.79605E-10 -10.0991 0.83623E+00 -0.0777 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.25212E-02 -2.5984 0.20948E-02 -2.6788 0.83090E+00 -0.0805 4 SO4-- 0.11250E-10 -10.9488 0.57264E-11 -11.2421 0.50899E+00 -0.2933 5 HCO3- 0.41413E-05 -5.3829 0.34464E-05 -5.4626 0.83219E+00 -0.0798 6 HS- 0.46823E-03 -3.3295 0.38911E-03 -3.4099 0.83103E+00 -0.0804 7 Al+++ 0.12534E-28 -28.9019 0.27656E-29 -29.5582 0.22065E+00 -0.6563 8 H4SiO4 0.69598E-03 -3.1574 0.69598E-03 -3.1574 0.10000E+01 0.0000 9 Ca++ 0.15864E-06 -6.7996 0.80114E-07 -7.0963 0.50502E+00 -0.2967 10 Mg++ 0.24824E-10 -10.6051 0.12476E-10 -10.9039 0.50257E+00 -0.2988 11 Fe++ 0.68416E-13 -13.1648 0.34424E-13 -13.4631 0.50315E+00 -0.2983 12 K+ 0.16879E-03 -3.7727 0.14050E-03 -3.8523 0.83240E+00 -0.0797 13 Na+ 0.21421E-01 -1.6692 0.17795E-01 -1.7497 0.83074E+00 -0.0805 14 Mn++ 0.21965E-10 -10.6583 0.11062E-10 -10.9562 0.50360E+00 -0.2979 15 HPO4-- 0.40161E-07 -7.3962 0.20445E-07 -7.6894 0.50907E+00 -0.2932 16 HSiO3- 0.98251E-02 -2.0077 0.81637E-02 -2.0881 0.83090E+00 -0.0805 17 Ca(HSiO3)+ 0.17889E-07 -7.7474 0.14895E-07 -7.8270 0.83259E+00 -0.0796 18 Mg(HSiO3)+ 0.34671E-11 -11.4600 0.28866E-11 -11.5396 0.83259E+00 -0.0796 19 NaHSiO3,aq 0.23496E-02 -2.6290 0.23496E-02 -2.6290 0.10000E+01 0.0000 20 AlO+ 0.71310E-16 -16.1469 0.59372E-16 -16.2264 0.83259E+00 -0.0796 22 HAlO2,aq 0.14853E-09 -9.8282 0.14853E-09 -9.8282 0.10000E+01 0.0000 23 AlO2- 0.49802E-05 -5.3027 0.41302E-05 -5.3840 0.82931E+00 -0.0813 24 CH4,aq 0.22840E-03 -3.6413 0.22748E-03 -3.6431 0.99595E+00 -0.0018 25 C2H6,aq 0.76689E-12 -12.1153 0.76378E-12 -12.1170 0.99595E+00 -0.0018 26 C3H8,aq 0.59448E-19 -19.2259 0.59207E-19 -19.2276 0.99595E+00 -0.0018 28 ethanol,aq 0.28148E-19 -19.5505 0.28034E-19 -19.5523 0.99595E+00 -0.0018 29 CO,aq 0.17057E-15 -15.7681 0.17057E-15 -15.7681 0.10000E+01 0.0000 30 CO2,aq 0.58860E-09 -9.2302 0.58622E-09 -9.2319 0.99595E+00 -0.0018 31 CO3-2 0.74462E-05 -5.1281 0.37815E-05 -5.4223 0.50784E+00 -0.2943 32 CaCO3,aq 0.37987E-08 -8.4204 0.37987E-08 -8.4204 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.84649E-11 -11.0724 0.70478E-11 -11.1519 0.83259E+00 -0.0796 34 CaCl+ 0.32621E-09 -9.4865 0.27159E-09 -9.5661 0.83259E+00 -0.0796 35 CaCl2,aq 0.13517E-12 -12.8691 0.13517E-12 -12.8691 0.10000E+01 0.0000 36 CaOH+ 0.86147E-07 -7.0648 0.71725E-07 -7.1443 0.83259E+00 -0.0796 37 CaSO4,aq 0.14568E-15 -15.8366 0.14568E-15 -15.8366 0.10000E+01 0.0000 38 HCl,aq 0.30558E-13 -13.5149 0.30558E-13 -13.5149 0.10000E+01 0.0000 43 FeCl+ 0.13709E-15 -15.8630 0.11414E-15 -15.9426 0.83259E+00 -0.0796 46 FeO,aq 0.21112E-09 -9.6755 0.21112E-09 -9.6755 0.10000E+01 0.0000 47 FeOH+ 0.16906E-10 -10.7719 0.14076E-10 -10.8515 0.83259E+00 -0.0796 48 HFeO2- 0.33397E-07 -7.4763 0.27750E-07 -7.5567 0.83090E+00 -0.0805 49 FeO+ 0.11849E-16 -16.9263 0.98653E-17 -17.0059 0.83259E+00 -0.0796 51 FeO2- 0.38338E-09 -9.4164 0.31855E-09 -9.4968 0.83090E+00 -0.0805 52 HFeO2,aq 0.32251E-11 -11.4915 0.32251E-11 -11.4915 0.10000E+01 0.0000 53 H2,aq 0.11629E-04 -4.9344 0.11582E-04 -4.9362 0.99595E+00 -0.0018 54 KCl,aq 0.53344E-08 -8.2729 0.53344E-08 -8.2729 0.10000E+01 0.0000 56 KOH,aq 0.75374E-06 -6.1228 0.75374E-06 -6.1228 0.10000E+01 0.0000 57 KSO4- 0.15026E-13 -13.8232 0.12485E-13 -13.9036 0.83090E+00 -0.0805 58 MgCO3,aq 0.14828E-12 -12.8289 0.14828E-12 -12.8289 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.13470E-14 -14.8706 0.11215E-14 -14.9502 0.83259E+00 -0.0796 60 MgCl+ 0.46041E-13 -13.3369 0.38333E-13 -13.4164 0.83259E+00 -0.0796 61 MgOH+ 0.74234E-10 -10.1294 0.61806E-10 -10.2090 0.83259E+00 -0.0796 63 MnO,aq 0.18077E-08 -8.7429 0.18077E-08 -8.7429 0.10000E+01 0.0000 64 MnOH+ 0.50467E-09 -9.2970 0.42018E-09 -9.3766 0.83259E+00 -0.0796 65 MnO2-2 0.18641E-10 -10.7295 0.94669E-11 -11.0238 0.50784E+00 -0.2943 66 HMnO2- 0.19871E-09 -9.7018 0.16511E-09 -9.7822 0.83090E+00 -0.0805 69 MnCl+ 0.17138E-12 -12.7660 0.14269E-12 -12.8456 0.83259E+00 -0.0796 70 MnSO4,aq 0.18286E-19 -19.7379 0.18286E-19 -19.7379 0.10000E+01 0.0000 71 NaCl,aq 0.12354E-04 -4.9082 0.12354E-04 -4.9082 0.10000E+01 0.0000 72 NaOH,aq 0.96046E-04 -4.0175 0.96046E-04 -4.0175 0.10000E+01 0.0000 74 OH- 0.87518E-02 -2.0579 0.72580E-02 -2.1392 0.82931E+00 -0.0813 79 HPO3-2 0.14531E-14 -14.8377 0.73794E-15 -15.1320 0.50784E+00 -0.2943 81 H2PO3- 0.14177E-18 -18.8484 0.11780E-18 -18.9289 0.83090E+00 -0.0805 82 H3PO4,aq 0.90612E-18 -18.0428 0.90612E-18 -18.0428 0.10000E+01 0.0000 83 H2PO4- 0.36097E-10 -10.4425 0.30023E-10 -10.5225 0.83174E+00 -0.0800 84 PO4-3 0.90146E-09 -9.0451 0.20954E-09 -9.6787 0.23245E+00 -0.6337 88 HP2O7-3 0.80257E-18 -18.0955 0.17728E-18 -18.7513 0.22089E+00 -0.6558 89 P2O7-4 0.74737E-17 -17.1265 0.53203E-18 -18.2741 0.71187E-01 -1.1476 90 H2S,aq 0.96122E-07 -7.0172 0.95732E-07 -7.0189 0.99595E+00 -0.0018 91 S2-2 0.57036E-12 -12.2438 0.28965E-12 -12.5381 0.50784E+00 -0.2943 97 SO3-2 0.16715E-16 -16.7769 0.86189E-17 -17.0646 0.51564E+00 -0.2877 98 HSO3- 0.51701E-19 -19.2865 0.42959E-19 -19.3669 0.83090E+00 -0.0805 99 HSO4- 0.52710E-18 -18.2781 0.43931E-18 -18.3572 0.83345E+00 -0.0791 101 S2O3-2 0.12680E-19 -19.8969 0.64396E-20 -20.1911 0.50784E+00 -0.2943 Charge balance for all species = 0.9544E-09 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.9519480E-10 -.2105370E-01 -.2118233E+02 0.0000 2 H2O 0.1000000E+01 0.5550517E+02 0.9981264E+06 0.0000 3 Cl- 0.2521167E-02 0.2533526E-02 0.8965799E+02 7.4202 4 SO4-- 0.1125046E-10 -.2313110E-03 -.2217975E+02 8.9560 5 HCO3- 0.4141315E-05 0.2399956E-03 0.1461726E+02 4.6364 6 HS- 0.4682252E-03 0.6996323E-03 0.2309622E+02 6.6891 7 Al+++ 0.1253373E-28 0.4980391E-05 0.1341344E+00 0.7390 8 H4SiO4 0.6959822E-03 0.1287071E-01 0.1234827E+04 -3.1574 9 Ca++ 0.1586351E-06 0.2668048E-06 0.1067358E-01 13.1018 10 Mg++ 0.2482428E-10 0.1027468E-09 0.2493444E-05 9.2942 11 Fe++ 0.6841619E-13 0.3401176E-07 0.1896005E-02 6.7350 12 K+ 0.1687907E-03 0.1695498E-03 0.6617696E+01 6.2467 13 Na+ 0.2142119E-01 0.2387922E-01 0.5479815E+03 8.3494 14 Mn++ 0.2196508E-10 0.2551837E-08 0.1399382E-03 9.2419 15 HPO4-- 0.4016104E-07 0.4109859E-07 0.3937438E-02 12.5087 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.1556500E+03 -.1146571E-02 -.1556489E+03 0.0000000E+00 2 H2O -.6232459E+02 0.3022775E+01 -.6534737E+02 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.2605315E+00 -.1259704E-04 0.2605441E+00 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.2605060E+00 0.3810151E-04 -.2605441E+00 0.0000000E+00 7 Al+++ 0.3065097E+02 0.2712288E-06 0.3065097E+02 0.0000000E+00 8 H4SiO4 0.9788015E+02 0.7009303E-03 0.9787945E+02 0.0000000E+00 9 Ca++ 0.1081135E+02 0.1453001E-07 0.1081135E+02 0.0000000E+00 10 Mg++ 0.7460317E+01 0.5595524E-11 0.7460317E+01 0.0000000E+00 11 Fe++ 0.6702280E+01 0.1852258E-08 0.6702280E+01 0.0000000E+00 12 K+ 0.1995754E+01 0.9233569E-05 0.1995744E+01 0.0000000E+00 13 Na+ 0.1179945E+02 0.1300447E-02 0.1179815E+02 0.0000000E+00 14 Mn++ 0.1629828E+00 0.1389713E-09 0.1629828E+00 0.0000000E+00 15 HPO4-- 0.5562521E-01 0.2238202E-08 0.5562521E-01 0.0000000E+00 Chg. balance for solid moles: 0.2756E-13 Mass of aqueous solution: 0.545584E+02 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 9399.9990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 11.79 1.071 3091. 3.490 30.10 1187. andradite 1.042 0.018 529.6 2.724 5.157 137.6 grossular 0.2523 -0.598 113.7 2.056 1.107 31.63 apatite-OH 0.1854E-01 -1.732 9.314 0.969 0.9070E-01 2.960 clinochlore 1.334 0.125 741.6 2.870 7.222 282.1 daphnite 0.3863 -0.413 275.6 2.440 2.684 83.52 chlorite-Mn 0.3260E-01 -1.487 23.11 1.364 0.2250 7.365 diopside 0.5020 -0.299 108.7 2.036 1.059 33.22 hedenbergite 0.1302 -0.885 32.30 1.509 0.3145 8.847 microcline 1.750 0.243 487.1 2.688 4.743 190.3 stilbite 6.045 0.781 4260. 3.629 41.48 1987. stilpnomelane-Fe 0.4915 -0.308 529.8 2.724 5.159 183.0 tr.625ac.25prg.125 0.7917E-01 -1.101 67.67 1.830 0.6590 21.78 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8051E+00 0.8051E+00 1.0000 -0.094 grossular 0.1949E+00 0.1949E+00 1.0000 -0.710 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.7611E+00 0.7611E+00 1.0000 -0.119 daphnite 0.2203E+00 0.2203E+00 1.0000 -0.657 chlorite-Mn 0.1859E-01 0.1859E-01 1.0000 -1.731 diopside 0.7941E+00 0.7941E+00 1.0000 -0.100 hedenbergite 0.2059E+00 0.2059E+00 1.0000 -0.686 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 tr.625ac.25prg.125 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass =10269.366873 g Volume = 4155.712559 cm3 Porosity: -10.4949% V(tot) - V(min): -.39471E+03 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 9399.9990000 g log = 3.9731 Original solution: 1000.0103000 g Original solution / Rock added: 0.11 (Water/Rock Ratio), log = -0.9731 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.3712 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.7470E+00 0.9822 0.1006E+01 0.1024E+01 CO2,gas 0.4559E-07 1.0034 0.6272E-07 0.6251E-07 CH4,gas 0.2420E+00 1.0092 0.3348E+00 0.3318E+00 H2,gas 0.1108E-01 1.0007 0.1521E-01 0.1520E-01 H2S,gas 0.1929E-05 0.9947 0.2632E-05 0.2646E-05 S2,gas 0.8199E-27 1.0000 0.1124E-26 0.1124E-26 CO,gas 0.1854E-12 1.0000 0.2542E-12 0.2542E-12 SO3,gas 0.1001E-46 1.0000 0.1372E-46 0.1372E-46 SO2,gas 0.5920E-26 1.0000 0.8117E-26 0.8117E-26 HCl,gas 0.3932E-16 1.0000 0.5392E-16 0.5392E-16 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 16 albite -0.38 -0.38 0.00 0.000 -0.94784E-12 22 andradite 39.01 39.01 0.00 0.000 0.00000E+00 23 grossular 32.73 32.73 0.00 0.000 -0.24265E-10 32 apatite-OH -18.15 -18.15 0.00 0.000 0.00000E+00 46 clinochlore 39.07 39.07 0.00 0.000 0.12132E-10 47 daphnite 28.97 28.97 0.00 0.000 0.60662E-11 48 chlorite-Mn 46.87 46.87 0.00 0.000 0.24265E-10 67 diopside 16.18 16.18 0.00 0.000 0.12132E-10 68 hedenbergite 14.21 14.21 0.00 0.000 0.30331E-11 116 microcline -2.49 -2.49 0.00 0.000 0.15165E-11 163 stilbite -7.52 -7.52 0.00 0.000 0.15165E-10 164 stilpnomelane-Fe 13.02 13.02 0.00 0.000 -0.27298E-10 245 tr.625ac.25prg.125 45.16 45.16 0.00 0.000 0.24265E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -15.56 -8.90 -2.967 0.15199E+05 -7.203 3 CH4,gas 4.54 2.37 -2.17 -0.544 0.37123E+04 -0.475 4 H2,gas 8.00 4.48 -3.52 -2.010 0.60051E+04 -1.818 5 H2S,gas -6.23 -13.51 -7.28 -3.639 0.12428E+05 -5.580 6 S2,gas -7.34 -35.98 -28.65 -4.407 0.48916E+05 -26.949 7 CO,gas 3.21 -11.08 -14.29 -4.398 0.24406E+05 -12.595 8 SO3,gas 17.12 -31.44 -48.56 -12.140 0.82918E+05 -46.863 9 SO2,gas 0.83 -26.96 -27.79 -7.411 0.47450E+05 -26.091 10 HCl,gas 5.19 -12.78 -17.97 -8.984 0.30679E+05 -16.268 11 acmite 7.71 6.53 -1.18 -0.123 0.20175E+04 15 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 19 spessartine 24.46 19.73 -4.73 -0.236 0.80692E+04 20 analcite 3.32 2.77 -0.55 -0.061 0.93626E+03 26 annite 20.12 17.72 -2.40 -0.134 0.41064E+04 27 phlogopite 27.06 25.40 -1.67 -0.093 0.28490E+04 29 anorthite 12.71 8.26 -4.45 -0.342 0.75903E+04 35 aragonite 0.97 -2.46 -3.43 -1.142 0.58505E+04 36 brucite 12.57 9.29 -3.27 -0.655 0.55909E+04 37 calcite 0.81 -2.46 -3.27 -1.091 0.55862E+04 38 carnegieite-low 9.02 5.93 -3.09 -0.442 0.52801E+04 39 carnegieite-high 10.09 5.93 -4.16 -0.595 0.71071E+04 40 carpholite-Mg 8.58 4.46 -4.12 -0.275 0.70429E+04 41 carpholite-Fe 6.71 1.90 -4.81 -0.321 0.82207E+04 42 celadonite 5.34 3.65 -1.69 -0.099 0.28879E+04 43 celadonite-Fe 3.88 1.09 -2.79 -0.164 0.47561E+04 44 chrysotile 23.89 21.57 -2.32 -0.194 0.39692E+04 49 chlorite-Al-free 47.17 43.14 -4.04 -0.168 0.68936E+04 51 chloritoid-Fe 9.17 5.06 -4.12 -0.275 0.70316E+04 52 chloritoid-Mn 11.40 7.56 -3.84 -0.256 0.65543E+04 54 coesite -2.38 -3.16 -0.78 -0.260 0.13341E+04 61 cristobalite -2.56 -3.16 -0.60 -0.199 0.10195E+04 63 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71234E+04 65 diaspore 2.87 0.74 -2.13 -0.356 0.36450E+04 66 diamond -3.10 -6.60 -3.49 -0.998 0.59654E+04 71 enstatite 17.26 12.27 -4.99 -0.499 0.85226E+04 73 clinoenstatite 17.17 12.27 -4.89 -0.489 0.83542E+04 75 epidote 24.67 22.70 -1.97 -0.095 0.33585E+04 76 clinozoisite 22.81 18.95 -3.86 -0.175 0.65869E+04 77 epidote-Fe 29.84 26.46 -3.38 -0.176 0.57768E+04 78 fayalite 14.05 10.31 -3.73 -0.533 0.63743E+04 79 ferrosilite 11.15 7.16 -3.99 -0.399 0.68202E+04 83 gibbsite 4.08 0.74 -3.34 -0.477 0.57036E+04 84 glaucophane 22.97 20.80 -2.17 -0.059 0.37134E+04 85 glaucophane-Fe 17.28 13.12 -4.15 -0.112 0.70919E+04 86 graphite -3.55 -6.60 -3.05 -0.871 0.52076E+04 87 greenalite 16.14 13.89 -2.25 -0.187 0.38408E+04 90 hematite 12.57 8.99 -3.58 -0.434 0.61111E+04 91 heulandite -5.83 -7.52 -1.69 -0.077 0.28938E+04 95 jadeite 4.22 2.77 -1.44 -0.144 0.24617E+04 97 kalsilite 7.58 3.83 -3.76 -0.537 0.64126E+04 98 kaolinite -1.33 -4.84 -3.50 -0.319 0.59832E+04 101 laumontite 2.88 1.95 -0.93 -0.062 0.15935E+04 102 lawsonite 9.62 8.26 -1.35 -0.090 0.23070E+04 103 leucite 4.12 0.67 -3.45 -0.345 0.58873E+04 105 lizardite 23.24 21.57 -1.68 -0.140 0.28619E+04 107 magnetite 20.09 15.72 -4.37 -0.356 0.74536E+04 108 minnesotaite 10.39 7.58 -2.81 -0.165 0.48027E+04 112 manganosite 14.06 9.24 -4.82 -1.204 0.82235E+04 120 muscovite 2.58 -1.01 -3.59 -0.211 0.61315E+04 121 paragonite 4.24 1.09 -3.15 -0.185 0.53706E+04 122 nepheline 8.34 5.93 -2.41 -0.344 0.41125E+04 128 periclase-Fe 11.63 6.73 -4.89 -1.223 0.83523E+04 134 phlogopite-Na 29.65 27.50 -2.15 -0.119 0.36678E+04 136 prehnite 19.37 18.21 -1.16 -0.068 0.19849E+04 137 prehnite-Fe 22.50 21.96 -0.53 -0.032 0.91159E+03 138 pumpellyite-Fe 46.27 43.89 -2.38 -0.053 0.40582E+04 139 pumpellyite-Mg 48.99 46.45 -2.54 -0.057 0.43421E+04 142 pyrite -21.25 -24.77 -3.52 -0.828 0.60084E+04 143 pyrrhotite -4.26 -6.77 -2.51 -0.838 0.42921E+04 144 pyrrhotiteFe0.875 -6.02 -8.17 -2.15 -0.792 0.36793E+04 145 pyroxmangite 7.40 6.08 -1.31 -0.263 0.22439E+04 146 pyrophyllite -6.18 -11.15 -4.98 -0.311 0.84962E+04 147 quartz -2.99 -3.16 -0.17 -0.056 0.28679E+03 152 rhodonite 7.45 6.08 -1.36 -0.272 0.23241E+04 153 sanidine -1.28 -2.49 -1.21 -0.093 0.20677E+04 165 stilpnomelane-Mg 27.44 25.81 -1.63 -0.049 0.27804E+04 171 talc 16.49 15.25 -1.24 -0.073 0.21140E+04 174 tephroite 18.09 15.33 -2.76 -0.394 0.47115E+04 178 tridymite -2.63 -3.16 -0.53 -0.177 0.90677E+03 179 tremolite 47.87 47.42 -0.45 -0.012 0.77494E+03 180 ferroactinolite 38.45 34.62 -3.83 -0.104 0.65448E+04 181 troilite-low -4.41 -6.77 -2.36 -0.788 0.40349E+04 183 vesuvianite 223.47 218.82 -4.65 -0.036 0.79441E+04 187 wairakite 3.95 1.95 -2.00 -0.118 0.34155E+04 188 walstromite 11.51 9.94 -1.56 -0.313 0.26719E+04 189 wollastonite 10.46 9.94 -0.52 -0.103 0.88229E+03 190 pseudo-wollastonite 11.00 9.94 -1.06 -0.211 0.18021E+04 191 zoisite 22.85 18.95 -3.90 -0.177 0.66610E+04 192 akaganeite 7.75 4.49 -3.26 -0.705 0.55681E+04 199 chalcedony -2.80 -3.16 -0.35 -0.118 0.60609E+03 201 montmorillonite-Ca -2.29 -6.17 -3.88 -0.240 0.66180E+04 202 montmorillonite-K -2.24 -6.27 -4.03 -0.247 0.68816E+04 203 montmorillonite-Mg -2.48 -6.79 -4.32 -0.267 0.73678E+04 204 montmorillonite-Na -2.04 -5.57 -3.54 -0.216 0.60365E+04 205 nontronite-Ca 3.21 -0.19 -3.41 -0.221 0.58215E+04 206 nontronite-H 2.53 -2.36 -4.89 -0.328 0.83484E+04 207 nontronite-K 3.34 -0.30 -3.64 -0.233 0.62083E+04 208 nontronite-Mg 3.07 -0.82 -3.90 -0.253 0.66553E+04 209 nontronite-Na 3.52 0.40 -3.12 -0.200 0.53291E+04 224 tobermorite 9.82 7.76 -2.07 -0.564 0.35287E+04 230 alabandite -0.98 -4.27 -3.29 -1.096 0.56162E+04 233 boehmite 4.41 0.74 -3.67 -0.611 0.62619E+04 235 ferrous-oxide 9.81 6.73 -3.08 -0.769 0.52532E+04 240 silica-amorphous -2.09 -3.16 -1.07 -0.355 0.18203E+04 242 an20ab80 2.02 1.35 -0.67 -0.052 0.11472E+04 243 an25ab75 2.65 1.78 -0.87 -0.067 0.14810E+04 244 an30ab70 3.28 2.21 -1.07 -0.082 0.18244E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 100.0000000 g Current total amount of reactant added: 9399.9990000 g New total amount of reactant added: 9499.9990000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.5197E-10 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 14 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 9499.9990000 Water: Moles liquid = 0.2465E+01 kg liquid = 0.4442E-01 Moles total = -.6358E+02 kg total = -.1145E+01 Activity = 1.0000 Stoichiometric ionic strength = .1380841E-01 Osmotic coef. = 0.9654 True ionic strength = .2199251E-01 Chg. balance for total moles = 0.5197E-10 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.96919E-10 -10.0136 0.80953E-10 -10.0918 0.83527E+00 -0.0782 2 H2O 0.99999E+00 0.0000 0.99999E+00 0.0000 3 Cl- 0.30910E-02 -2.5099 0.25651E-02 -2.5909 0.82986E+00 -0.0810 4 SO4-- 0.13613E-10 -10.8660 0.68955E-11 -11.1614 0.50652E+00 -0.2954 5 HCO3- 0.50043E-05 -5.3007 0.41594E-05 -5.3810 0.83117E+00 -0.0803 6 HS- 0.57409E-03 -3.2410 0.47649E-03 -3.3219 0.83000E+00 -0.0809 7 Al+++ 0.13329E-28 -28.8752 0.29085E-29 -29.5363 0.21821E+00 -0.6611 8 H4SiO4 0.69598E-03 -3.1574 0.69598E-03 -3.1574 0.10000E+01 0.0000 9 Ca++ 0.16487E-06 -6.7829 0.82850E-07 -7.0817 0.50252E+00 -0.2988 10 Mg++ 0.25802E-10 -10.5884 0.12902E-10 -10.8893 0.50004E+00 -0.3010 11 Fe++ 0.71109E-13 -13.1481 0.35599E-13 -13.4486 0.50063E+00 -0.3005 12 K+ 0.17186E-03 -3.7648 0.14288E-03 -3.8450 0.83138E+00 -0.0802 13 Na+ 0.21811E-01 -1.6613 0.18097E-01 -1.7424 0.82970E+00 -0.0811 14 Mn++ 0.22830E-10 -10.6415 0.11439E-10 -10.9416 0.50108E+00 -0.3001 15 HPO4-- 0.39024E-07 -7.4087 0.19769E-07 -7.7040 0.50660E+00 -0.2953 16 HSiO3- 0.96735E-02 -2.0144 0.80277E-02 -2.0954 0.82986E+00 -0.0810 17 Ca(HSiO3)+ 0.18215E-07 -7.7396 0.15147E-07 -7.8197 0.83157E+00 -0.0801 18 Mg(HSiO3)+ 0.35301E-11 -11.4522 0.29355E-11 -11.5323 0.83157E+00 -0.0801 19 NaHSiO3,aq 0.23496E-02 -2.6290 0.23496E-02 -2.6290 0.10000E+01 0.0000 20 AlO+ 0.72606E-16 -16.1390 0.60377E-16 -16.2191 0.83157E+00 -0.0801 22 HAlO2,aq 0.14853E-09 -9.8282 0.14853E-09 -9.8282 0.10000E+01 0.0000 23 AlO2- 0.49036E-05 -5.3095 0.40614E-05 -5.3913 0.82825E+00 -0.0818 24 CH4,aq 0.28037E-03 -3.5523 0.27919E-03 -3.5541 0.99581E+00 -0.0018 25 C2H6,aq 0.11554E-11 -11.9373 0.11505E-11 -11.9391 0.99581E+00 -0.0018 26 C3H8,aq 0.10992E-18 -18.9589 0.10946E-18 -18.9607 0.99581E+00 -0.0018 28 ethanol,aq 0.42407E-19 -19.3726 0.42229E-19 -19.3744 0.99581E+00 -0.0018 29 CO,aq 0.20934E-15 -15.6791 0.20934E-15 -15.6791 0.10000E+01 0.0000 30 CO2,aq 0.72252E-09 -9.1412 0.71949E-09 -9.1430 0.99581E+00 -0.0018 31 CO3-2 0.88804E-05 -5.0516 0.44879E-05 -5.3480 0.50537E+00 -0.2964 32 CaCO3,aq 0.46622E-08 -8.3314 0.46622E-08 -8.3314 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.10578E-10 -10.9756 0.87964E-11 -11.0557 0.83157E+00 -0.0801 34 CaCl+ 0.41358E-09 -9.3834 0.34392E-09 -9.4635 0.83157E+00 -0.0801 35 CaCl2,aq 0.20959E-12 -12.6786 0.20959E-12 -12.6786 0.10000E+01 0.0000 36 CaOH+ 0.87712E-07 -7.0569 0.72939E-07 -7.1370 0.83157E+00 -0.0801 37 CaSO4,aq 0.18141E-15 -15.7413 0.18141E-15 -15.7413 0.10000E+01 0.0000 38 HCl,aq 0.38051E-13 -13.4196 0.38051E-13 -13.4196 0.10000E+01 0.0000 43 FeCl+ 0.17381E-15 -15.7599 0.14454E-15 -15.8400 0.83157E+00 -0.0801 46 FeO,aq 0.21112E-09 -9.6755 0.21112E-09 -9.6755 0.10000E+01 0.0000 47 FeOH+ 0.17214E-10 -10.7641 0.14314E-10 -10.8442 0.83157E+00 -0.0801 48 HFeO2- 0.32882E-07 -7.4830 0.27288E-07 -7.5640 0.82986E+00 -0.0810 49 FeO+ 0.12064E-16 -16.9185 0.10032E-16 -16.9986 0.83157E+00 -0.0801 51 FeO2- 0.37746E-09 -9.4231 0.31324E-09 -9.5041 0.82986E+00 -0.0810 52 HFeO2,aq 0.32251E-11 -11.4915 0.32251E-11 -11.4915 0.10000E+01 0.0000 53 H2,aq 0.11631E-04 -4.9344 0.11582E-04 -4.9362 0.99581E+00 -0.0018 54 KCl,aq 0.66425E-08 -8.1777 0.66425E-08 -8.1777 0.10000E+01 0.0000 56 KOH,aq 0.75374E-06 -6.1228 0.75374E-06 -6.1228 0.10000E+01 0.0000 57 KSO4- 0.18423E-13 -13.7346 0.15288E-13 -13.8156 0.82986E+00 -0.0810 58 MgCO3,aq 0.18199E-12 -12.7400 0.18199E-12 -12.7400 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.16832E-14 -14.7739 0.13997E-14 -14.8540 0.83157E+00 -0.0801 60 MgCl+ 0.58373E-13 -13.2338 0.48542E-13 -13.3139 0.83157E+00 -0.0801 61 MgOH+ 0.75583E-10 -10.1216 0.62853E-10 -10.2017 0.83157E+00 -0.0801 63 MnO,aq 0.18077E-08 -8.7429 0.18077E-08 -8.7429 0.10000E+01 0.0000 64 MnOH+ 0.51385E-09 -9.2892 0.42730E-09 -9.3693 0.83157E+00 -0.0801 65 MnO2-2 0.18114E-10 -10.7420 0.91544E-11 -11.0384 0.50537E+00 -0.2964 66 HMnO2- 0.19564E-09 -9.7085 0.16236E-09 -9.7895 0.82986E+00 -0.0810 69 MnCl+ 0.21729E-12 -12.6630 0.18069E-12 -12.7431 0.83157E+00 -0.0801 70 MnSO4,aq 0.22772E-19 -19.6426 0.22772E-19 -19.6426 0.10000E+01 0.0000 71 NaCl,aq 0.15384E-04 -4.8129 0.15384E-04 -4.8129 0.10000E+01 0.0000 72 NaOH,aq 0.96045E-04 -4.0175 0.96045E-04 -4.0175 0.10000E+01 0.0000 74 OH- 0.86170E-02 -2.0646 0.71371E-02 -2.1465 0.82825E+00 -0.0818 79 HPO3-2 0.14120E-14 -14.8502 0.71357E-15 -15.1466 0.50537E+00 -0.2964 81 H2PO3- 0.13959E-18 -18.8552 0.11584E-18 -18.9362 0.82986E+00 -0.0810 82 H3PO4,aq 0.90612E-18 -18.0428 0.90612E-18 -18.0428 0.10000E+01 0.0000 83 H2PO4- 0.35539E-10 -10.4493 0.29523E-10 -10.5298 0.83071E+00 -0.0806 84 PO4-3 0.86612E-09 -9.0624 0.19925E-09 -9.7006 0.23005E+00 -0.6382 88 HP2O7-3 0.77166E-18 -18.1126 0.16857E-18 -18.7732 0.21845E+00 -0.6606 89 P2O7-4 0.71246E-17 -17.1472 0.49747E-18 -18.3032 0.69824E-01 -1.1560 90 H2S,aq 0.11972E-06 -6.9218 0.11922E-06 -6.9237 0.99581E+00 -0.0018 91 S2-2 0.85949E-12 -12.0658 0.43436E-12 -12.3622 0.50537E+00 -0.2964 92 S3-2 0.11919E-19 -19.9238 0.60234E-20 -20.2202 0.50537E+00 -0.2964 97 SO3-2 0.20222E-16 -16.6942 0.10379E-16 -16.9839 0.51324E+00 -0.2897 98 HSO3- 0.63391E-19 -19.1980 0.52606E-19 -19.2790 0.82986E+00 -0.0810 99 HSO4- 0.64624E-18 -18.1896 0.53796E-18 -18.2692 0.83245E+00 -0.0796 101 S2O3-2 0.19108E-19 -19.7188 0.96566E-20 -20.0152 0.50537E+00 -0.2964 Charge balance for all species = 0.1170E-08 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.9691882E-10 -.2076850E-01 -.2089497E+02 0.0000 2 H2O 0.1000000E+01 0.5550524E+02 0.9981078E+06 0.0000 3 Cl- 0.3090966E-02 0.3106356E-02 0.1099275E+03 7.5009 4 SO4-- 0.1361345E-10 -.2832762E-03 -.2716200E+02 9.0221 5 HCO3- 0.5004267E-05 0.2942585E-03 0.1792187E+02 4.7108 6 HS- 0.5740890E-03 0.8574849E-03 0.2830668E+02 6.7698 7 Al+++ 0.1332872E-28 0.4903718E-05 0.1320667E+00 0.7390 8 H4SiO4 0.6959812E-03 0.1271916E-01 0.1220263E+04 -3.1574 9 Ca++ 0.1648698E-06 0.2758831E-06 0.1103654E-01 13.1018 10 Mg++ 0.2580171E-10 0.1051415E-09 0.2551508E-05 9.2942 11 Fe++ 0.7110888E-13 0.3349104E-07 0.1866940E-02 6.7350 12 K+ 0.1718583E-03 0.1726187E-03 0.6737344E+01 6.2467 13 Na+ 0.2181112E-01 0.2427218E-01 0.5569880E+03 8.3494 14 Mn++ 0.2282951E-10 0.2558352E-08 0.1402927E-03 9.2419 15 HPO4-- 0.3902358E-07 0.3992524E-07 0.3824949E-02 12.4795 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.1573059E+03 -.9224689E-03 -.1573049E+03 0.0000000E+00 2 H2O -.6357814E+02 0.2465361E+01 -.6604350E+02 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.2633029E+00 -.1258220E-04 0.2633154E+00 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.2632774E+00 0.3808667E-04 -.2633154E+00 0.0000000E+00 7 Al+++ 0.3097704E+02 0.2178071E-06 0.3097704E+02 0.0000000E+00 8 H4SiO4 0.9892143E+02 0.5649435E-03 0.9892086E+02 0.0000000E+00 9 Ca++ 0.1092637E+02 0.1225382E-07 0.1092637E+02 0.0000000E+00 10 Mg++ 0.7539682E+01 0.4670042E-11 0.7539682E+01 0.0000000E+00 11 Fe++ 0.6773581E+01 0.1487562E-08 0.6773581E+01 0.0000000E+00 12 K+ 0.2016985E+01 0.7667157E-05 0.2016977E+01 0.0000000E+00 13 Na+ 0.1192497E+02 0.1078091E-02 0.1192390E+02 0.0000000E+00 14 Mn++ 0.1647166E+00 0.1136336E-09 0.1647166E+00 0.0000000E+00 15 HPO4-- 0.5621697E-01 0.1773348E-08 0.5621697E-01 0.0000000E+00 Chg. balance for solid moles: -.2084E-13 Mass of aqueous solution: 0.444984E+02 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 9499.9990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 11.91 1.076 3124. 3.495 30.10 1199. andradite 1.053 0.023 535.2 2.729 5.157 139.1 grossular 0.2550 -0.593 114.9 2.060 1.107 31.96 apatite-OH 0.1874E-01 -1.727 9.413 0.974 0.9070E-01 2.991 clinochlore 1.348 0.130 749.5 2.875 7.222 285.1 daphnite 0.3904 -0.409 278.5 2.445 2.684 84.40 chlorite-Mn 0.3294E-01 -1.482 23.36 1.368 0.2250 7.443 diopside 0.5074 -0.295 109.9 2.041 1.059 33.58 hedenbergite 0.1316 -0.881 32.65 1.514 0.3146 8.942 microcline 1.769 0.248 492.3 2.692 4.743 192.3 stilbite 6.109 0.786 4305. 3.634 41.48 2008. stilpnomelane-Fe 0.4967 -0.304 535.5 2.729 5.159 185.0 tr.625ac.25prg.125 0.8001E-01 -1.097 68.39 1.835 0.6589 22.01 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8051E+00 0.8051E+00 1.0000 -0.094 grossular 0.1949E+00 0.1949E+00 1.0000 -0.710 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.7611E+00 0.7611E+00 1.0000 -0.119 daphnite 0.2203E+00 0.2203E+00 1.0000 -0.657 chlorite-Mn 0.1859E-01 0.1859E-01 1.0000 -1.731 diopside 0.7941E+00 0.7941E+00 1.0000 -0.100 hedenbergite 0.2059E+00 0.2059E+00 1.0000 -0.686 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 tr.625ac.25prg.125 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass =10378.617471 g Volume = 4199.915589 cm3 Porosity: -10.4950% V(tot) - V(min): -.39892E+03 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 9499.9990000 g log = 3.9777 Original solution: 1000.0103000 g Original solution / Rock added: 0.11 (Water/Rock Ratio), log = -0.9777 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.4475 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.7080E+00 0.9816 0.1006E+01 0.1025E+01 CO2,gas 0.5304E-07 1.0027 0.7698E-07 0.7677E-07 CH4,gas 0.2815E+00 1.0086 0.4110E+00 0.4074E+00 H2,gas 0.1050E-01 1.0008 0.1521E-01 0.1519E-01 H2S,gas 0.2277E-05 0.9944 0.3277E-05 0.3296E-05 S2,gas 0.1204E-26 1.0000 0.1743E-26 0.1743E-26 CO,gas 0.2155E-12 1.0000 0.3120E-12 0.3120E-12 SO3,gas 0.1180E-46 1.0000 0.1709E-46 0.1709E-46 SO2,gas 0.6983E-26 1.0000 0.1011E-25 0.1011E-25 HCl,gas 0.4639E-16 1.0000 0.6714E-16 0.6714E-16 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 16 albite -0.38 -0.38 0.00 0.000 -0.94784E-12 22 andradite 39.01 39.01 0.00 0.000 -0.24265E-10 23 grossular 32.73 32.73 0.00 0.000 0.00000E+00 32 apatite-OH -18.15 -18.15 0.00 0.000 0.60662E-11 46 clinochlore 39.07 39.07 0.00 0.000 0.24265E-10 47 daphnite 28.97 28.97 0.00 0.000 0.12132E-10 48 chlorite-Mn 46.87 46.87 0.00 0.000 0.12132E-10 67 diopside 16.18 16.18 0.00 0.000 0.60662E-11 68 hedenbergite 14.21 14.21 0.00 0.000 0.12132E-10 116 microcline -2.49 -2.49 0.00 0.000 0.15165E-11 163 stilbite -7.52 -7.52 0.00 0.000 -0.90992E-11 164 stilpnomelane-Fe 13.02 13.02 0.00 0.000 0.21232E-10 245 tr.625ac.25prg.125 45.16 45.16 0.00 0.000 -0.36397E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -15.47 -8.81 -2.938 0.15047E+05 -7.114 3 CH4,gas 4.54 2.46 -2.09 -0.521 0.35604E+04 -0.386 4 H2,gas 8.00 4.48 -3.52 -2.010 0.60051E+04 -1.818 5 H2S,gas -6.23 -13.41 -7.18 -3.592 0.12266E+05 -5.485 6 S2,gas -7.34 -35.79 -28.46 -4.378 0.48591E+05 -26.759 7 CO,gas 3.21 -10.99 -14.20 -4.371 0.24254E+05 -12.506 8 SO3,gas 17.12 -31.34 -48.47 -12.117 0.82755E+05 -46.767 9 SO2,gas 0.83 -26.86 -27.69 -7.385 0.47287E+05 -25.995 10 HCl,gas 5.19 -12.68 -17.87 -8.936 0.30516E+05 -16.173 11 acmite 7.71 6.53 -1.18 -0.123 0.20175E+04 15 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 19 spessartine 24.46 19.73 -4.73 -0.236 0.80692E+04 20 analcite 3.32 2.77 -0.55 -0.061 0.93626E+03 26 annite 20.12 17.72 -2.40 -0.134 0.41064E+04 27 phlogopite 27.06 25.40 -1.67 -0.093 0.28490E+04 29 anorthite 12.71 8.26 -4.45 -0.342 0.75903E+04 35 aragonite 0.97 -2.37 -3.34 -1.112 0.56986E+04 36 brucite 12.57 9.29 -3.27 -0.655 0.55909E+04 37 calcite 0.81 -2.37 -3.18 -1.061 0.54343E+04 38 carnegieite-low 9.02 5.93 -3.09 -0.442 0.52801E+04 39 carnegieite-high 10.09 5.93 -4.16 -0.595 0.71071E+04 40 carpholite-Mg 8.58 4.46 -4.12 -0.275 0.70429E+04 41 carpholite-Fe 6.71 1.90 -4.81 -0.321 0.82207E+04 42 celadonite 5.34 3.65 -1.69 -0.099 0.28879E+04 43 celadonite-Fe 3.88 1.09 -2.79 -0.164 0.47561E+04 44 chrysotile 23.89 21.57 -2.32 -0.194 0.39692E+04 49 chlorite-Al-free 47.17 43.14 -4.04 -0.168 0.68936E+04 51 chloritoid-Fe 9.17 5.06 -4.12 -0.275 0.70316E+04 52 chloritoid-Mn 11.40 7.56 -3.84 -0.256 0.65543E+04 54 coesite -2.38 -3.16 -0.78 -0.260 0.13341E+04 61 cristobalite -2.56 -3.16 -0.60 -0.199 0.10195E+04 63 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71234E+04 65 diaspore 2.87 0.74 -2.13 -0.356 0.36450E+04 66 diamond -3.10 -6.51 -3.40 -0.973 0.58135E+04 71 enstatite 17.26 12.27 -4.99 -0.499 0.85226E+04 73 clinoenstatite 17.17 12.27 -4.89 -0.489 0.83542E+04 75 epidote 24.67 22.70 -1.97 -0.095 0.33585E+04 76 clinozoisite 22.81 18.95 -3.86 -0.175 0.65869E+04 77 epidote-Fe 29.84 26.46 -3.38 -0.176 0.57768E+04 78 fayalite 14.05 10.31 -3.73 -0.533 0.63743E+04 79 ferrosilite 11.15 7.16 -3.99 -0.399 0.68202E+04 83 gibbsite 4.08 0.74 -3.34 -0.477 0.57036E+04 84 glaucophane 22.97 20.80 -2.17 -0.059 0.37134E+04 85 glaucophane-Fe 17.28 13.12 -4.15 -0.112 0.70919E+04 86 graphite -3.55 -6.51 -2.96 -0.846 0.50557E+04 87 greenalite 16.14 13.89 -2.25 -0.187 0.38408E+04 90 hematite 12.57 8.99 -3.58 -0.434 0.61111E+04 91 heulandite -5.83 -7.52 -1.69 -0.077 0.28938E+04 95 jadeite 4.22 2.77 -1.44 -0.144 0.24617E+04 97 kalsilite 7.58 3.83 -3.76 -0.537 0.64126E+04 98 kaolinite -1.33 -4.84 -3.50 -0.319 0.59832E+04 101 laumontite 2.88 1.95 -0.93 -0.062 0.15935E+04 102 lawsonite 9.62 8.26 -1.35 -0.090 0.23070E+04 103 leucite 4.12 0.67 -3.45 -0.345 0.58873E+04 105 lizardite 23.24 21.57 -1.68 -0.140 0.28619E+04 107 magnetite 20.09 15.72 -4.37 -0.356 0.74536E+04 108 minnesotaite 10.39 7.58 -2.81 -0.165 0.48027E+04 112 manganosite 14.06 9.24 -4.82 -1.204 0.82235E+04 120 muscovite 2.58 -1.01 -3.59 -0.211 0.61315E+04 121 paragonite 4.24 1.09 -3.15 -0.185 0.53706E+04 122 nepheline 8.34 5.93 -2.41 -0.344 0.41125E+04 128 periclase-Fe 11.63 6.73 -4.89 -1.223 0.83523E+04 134 phlogopite-Na 29.65 27.50 -2.15 -0.119 0.36678E+04 136 prehnite 19.37 18.21 -1.16 -0.068 0.19849E+04 137 prehnite-Fe 22.50 21.96 -0.53 -0.032 0.91159E+03 138 pumpellyite-Fe 46.27 43.89 -2.38 -0.053 0.40582E+04 139 pumpellyite-Mg 48.99 46.45 -2.54 -0.057 0.43421E+04 142 pyrite -21.25 -24.58 -3.33 -0.783 0.56830E+04 143 pyrrhotite -4.26 -6.68 -2.42 -0.806 0.41294E+04 144 pyrrhotiteFe0.875 -6.02 -8.08 -2.06 -0.757 0.35166E+04 145 pyroxmangite 7.40 6.08 -1.31 -0.263 0.22439E+04 146 pyrophyllite -6.18 -11.15 -4.98 -0.311 0.84962E+04 147 quartz -2.99 -3.16 -0.17 -0.056 0.28679E+03 152 rhodonite 7.45 6.08 -1.36 -0.272 0.23241E+04 153 sanidine -1.28 -2.49 -1.21 -0.093 0.20677E+04 165 stilpnomelane-Mg 27.44 25.81 -1.63 -0.049 0.27804E+04 171 talc 16.49 15.25 -1.24 -0.073 0.21140E+04 174 tephroite 18.09 15.33 -2.76 -0.394 0.47115E+04 178 tridymite -2.63 -3.16 -0.53 -0.177 0.90677E+03 179 tremolite 47.87 47.42 -0.45 -0.012 0.77495E+03 180 ferroactinolite 38.45 34.62 -3.83 -0.104 0.65448E+04 181 troilite-low -4.41 -6.68 -2.27 -0.756 0.38722E+04 183 vesuvianite 223.47 218.82 -4.65 -0.036 0.79441E+04 187 wairakite 3.95 1.95 -2.00 -0.118 0.34155E+04 188 walstromite 11.51 9.94 -1.56 -0.313 0.26719E+04 189 wollastonite 10.46 9.94 -0.52 -0.103 0.88229E+03 190 pseudo-wollastonite 11.00 9.94 -1.06 -0.211 0.18021E+04 191 zoisite 22.85 18.95 -3.90 -0.177 0.66610E+04 192 akaganeite 7.75 4.49 -3.26 -0.705 0.55681E+04 199 chalcedony -2.80 -3.16 -0.35 -0.118 0.60609E+03 201 montmorillonite-Ca -2.29 -6.17 -3.88 -0.240 0.66180E+04 202 montmorillonite-K -2.24 -6.27 -4.03 -0.247 0.68816E+04 203 montmorillonite-Mg -2.48 -6.79 -4.32 -0.267 0.73678E+04 204 montmorillonite-Na -2.04 -5.57 -3.54 -0.216 0.60365E+04 205 nontronite-Ca 3.21 -0.19 -3.41 -0.221 0.58215E+04 206 nontronite-H 2.53 -2.36 -4.89 -0.328 0.83484E+04 207 nontronite-K 3.34 -0.30 -3.64 -0.233 0.62083E+04 208 nontronite-Mg 3.07 -0.82 -3.90 -0.253 0.66553E+04 209 nontronite-Na 3.52 0.40 -3.12 -0.200 0.53291E+04 224 tobermorite 9.82 7.76 -2.07 -0.564 0.35287E+04 230 alabandite -0.98 -4.17 -3.19 -1.065 0.54535E+04 233 boehmite 4.41 0.74 -3.67 -0.611 0.62619E+04 235 ferrous-oxide 9.81 6.73 -3.08 -0.769 0.52532E+04 240 silica-amorphous -2.09 -3.16 -1.07 -0.355 0.18203E+04 242 an20ab80 2.02 1.35 -0.67 -0.052 0.11472E+04 243 an25ab75 2.65 1.78 -0.87 -0.067 0.14810E+04 244 an30ab70 3.28 2.21 -1.07 -0.082 0.18244E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 100.0000000 g Current total amount of reactant added: 9499.9990000 g New total amount of reactant added: 9599.9990000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.5194E-10 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 14 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 9599.9990000 Water: Moles liquid = 0.1908E+01 kg liquid = 0.3437E-01 Moles total = -.6483E+02 kg total = -.1168E+01 Activity = 1.0000 Stoichiometric ionic strength = .1458417E-01 Osmotic coef. = 0.9647 True ionic strength = .2262854E-01 Chg. balance for total moles = 0.5194E-10 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.99699E-10 -10.0013 0.83123E-10 -10.0803 0.83374E+00 -0.0790 2 H2O 0.99999E+00 0.0000 0.99999E+00 0.0000 3 Cl- 0.39935E-02 -2.3986 0.33075E-02 -2.4805 0.82822E+00 -0.0819 4 SO4-- 0.17230E-10 -10.7637 0.86603E-11 -11.0625 0.50264E+00 -0.2987 5 HCO3- 0.63194E-05 -5.1993 0.52423E-05 -5.2805 0.82956E+00 -0.0812 6 HS- 0.74181E-03 -3.1297 0.61448E-03 -3.2115 0.82836E+00 -0.0818 7 Al+++ 0.14686E-28 -28.8331 0.31487E-29 -29.5019 0.21439E+00 -0.6688 8 H4SiO4 0.69598E-03 -3.1574 0.69598E-03 -3.1574 0.10000E+01 0.0000 9 Ca++ 0.17520E-06 -6.7565 0.87350E-07 -7.0587 0.49857E+00 -0.3023 10 Mg++ 0.27422E-10 -10.5619 0.13603E-10 -10.8664 0.49606E+00 -0.3045 11 Fe++ 0.75571E-13 -13.1216 0.37533E-13 -13.4256 0.49666E+00 -0.3039 12 K+ 0.17681E-03 -3.7525 0.14671E-03 -3.8335 0.82977E+00 -0.0810 13 Na+ 0.22440E-01 -1.6490 0.18582E-01 -1.7309 0.82805E+00 -0.0819 14 Mn++ 0.24262E-10 -10.6151 0.12061E-10 -10.9186 0.49711E+00 -0.3035 15 HPO4-- 0.37299E-07 -7.4283 0.18751E-07 -7.7270 0.50272E+00 -0.2987 16 HSiO3- 0.94397E-02 -2.0250 0.78182E-02 -2.1069 0.82822E+00 -0.0819 17 Ca(HSiO3)+ 0.18739E-07 -7.7273 0.15553E-07 -7.8082 0.82997E+00 -0.0809 18 Mg(HSiO3)+ 0.36317E-11 -11.4399 0.30142E-11 -11.5208 0.82997E+00 -0.0809 19 NaHSiO3,aq 0.23496E-02 -2.6290 0.23496E-02 -2.6290 0.10000E+01 0.0000 20 AlO+ 0.74697E-16 -16.1267 0.61996E-16 -16.2076 0.82997E+00 -0.0809 22 HAlO2,aq 0.14853E-09 -9.8282 0.14853E-09 -9.8282 0.10000E+01 0.0000 23 AlO2- 0.47853E-05 -5.3201 0.39554E-05 -5.4028 0.82658E+00 -0.0827 24 CH4,aq 0.36292E-03 -3.4402 0.36131E-03 -3.4421 0.99557E+00 -0.0019 25 C2H6,aq 0.19354E-11 -11.7132 0.19269E-11 -11.7151 0.99557E+00 -0.0019 26 C3H8,aq 0.23830E-18 -18.6229 0.23724E-18 -18.6248 0.99557E+00 -0.0019 28 ethanol,aq 0.71039E-19 -19.1485 0.70724E-19 -19.1504 0.99557E+00 -0.0019 29 CO,aq 0.27091E-15 -15.5672 0.27091E-15 -15.5672 0.10000E+01 0.0000 30 CO2,aq 0.93525E-09 -9.0291 0.93111E-09 -9.0310 0.99557E+00 -0.0019 31 CO3-2 0.10985E-04 -4.9592 0.55086E-05 -5.2590 0.50147E+00 -0.2998 32 CaCO3,aq 0.60335E-08 -8.2194 0.60335E-08 -8.2194 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.14083E-10 -10.8513 0.11689E-10 -10.9322 0.82997E+00 -0.0809 34 CaCl+ 0.56334E-09 -9.2492 0.46755E-09 -9.3302 0.82997E+00 -0.0809 35 CaCl2,aq 0.36740E-12 -12.4349 0.36740E-12 -12.4349 0.10000E+01 0.0000 36 CaOH+ 0.90237E-07 -7.0446 0.74894E-07 -7.1256 0.82997E+00 -0.0809 37 CaSO4,aq 0.24022E-15 -15.6194 0.24022E-15 -15.6194 0.10000E+01 0.0000 38 HCl,aq 0.50380E-13 -13.2977 0.50380E-13 -13.2977 0.10000E+01 0.0000 43 FeCl+ 0.23675E-15 -15.6257 0.19650E-15 -15.7066 0.82997E+00 -0.0809 46 FeO,aq 0.21112E-09 -9.6755 0.21112E-09 -9.6755 0.10000E+01 0.0000 47 FeOH+ 0.17709E-10 -10.7518 0.14698E-10 -10.8327 0.82997E+00 -0.0809 48 HFeO2- 0.32087E-07 -7.4937 0.26575E-07 -7.5755 0.82822E+00 -0.0819 49 FeO+ 0.12412E-16 -16.9062 0.10301E-16 -16.9871 0.82997E+00 -0.0809 51 FeO2- 0.36834E-09 -9.4338 0.30507E-09 -9.5156 0.82822E+00 -0.0819 52 HFeO2,aq 0.32251E-11 -11.4915 0.32251E-11 -11.4915 0.10000E+01 0.0000 53 H2,aq 0.11634E-04 -4.9343 0.11582E-04 -4.9362 0.99557E+00 -0.0019 54 KCl,aq 0.87946E-08 -8.0558 0.87946E-08 -8.0558 0.10000E+01 0.0000 56 KOH,aq 0.75373E-06 -6.1228 0.75373E-06 -6.1228 0.10000E+01 0.0000 57 KSO4- 0.23805E-13 -13.6233 0.19716E-13 -13.7052 0.82822E+00 -0.0819 58 MgCO3,aq 0.23551E-12 -12.6280 0.23551E-12 -12.6280 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.22410E-14 -14.6496 0.18600E-14 -14.7305 0.82997E+00 -0.0809 60 MgCl+ 0.79511E-13 -13.0996 0.65991E-13 -13.1805 0.82997E+00 -0.0809 61 MgOH+ 0.77759E-10 -10.1093 0.64537E-10 -10.1902 0.82997E+00 -0.0809 63 MnO,aq 0.18077E-08 -8.7429 0.18077E-08 -8.7429 0.10000E+01 0.0000 64 MnOH+ 0.52864E-09 -9.2768 0.43876E-09 -9.3578 0.82997E+00 -0.0809 65 MnO2-2 0.17315E-10 -10.7616 0.86828E-11 -11.0613 0.50147E+00 -0.2998 66 HMnO2- 0.19092E-09 -9.7192 0.15812E-09 -9.8010 0.82822E+00 -0.0819 69 MnCl+ 0.29598E-12 -12.5287 0.24565E-12 -12.6097 0.82997E+00 -0.0809 70 MnSO4,aq 0.30154E-19 -19.5206 0.30154E-19 -19.5206 0.10000E+01 0.0000 71 NaCl,aq 0.20368E-04 -4.6911 0.20368E-04 -4.6911 0.10000E+01 0.0000 72 NaOH,aq 0.96045E-04 -4.0175 0.96045E-04 -4.0175 0.10000E+01 0.0000 74 OH- 0.84091E-02 -2.0752 0.69508E-02 -2.1580 0.82658E+00 -0.0827 79 HPO3-2 0.13497E-14 -14.8698 0.67681E-15 -15.1695 0.50147E+00 -0.2998 81 H2PO3- 0.13621E-18 -18.8658 0.11281E-18 -18.9476 0.82822E+00 -0.0819 82 H3PO4,aq 0.90612E-18 -18.0428 0.90612E-18 -18.0428 0.10000E+01 0.0000 83 H2PO4- 0.34680E-10 -10.4599 0.28752E-10 -10.5413 0.82909E+00 -0.0814 84 PO4-3 0.81334E-09 -9.0897 0.18405E-09 -9.7351 0.22629E+00 -0.6453 88 HP2O7-3 0.72547E-18 -18.1394 0.15572E-18 -18.8077 0.21464E+00 -0.6683 89 P2O7-4 0.66089E-17 -17.1799 0.44753E-18 -18.3492 0.67716E-01 -1.1693 90 H2S,aq 0.15856E-06 -6.7998 0.15786E-06 -6.8017 0.99557E+00 -0.0019 91 S2-2 0.14405E-11 -11.8415 0.72236E-12 -12.1412 0.50147E+00 -0.2998 92 S3-2 0.26451E-19 -19.5776 0.13264E-19 -19.8773 0.50147E+00 -0.2998 97 SO3-2 0.25586E-16 -16.5920 0.13035E-16 -16.8849 0.50945E+00 -0.2929 98 HSO3- 0.81910E-19 -19.0867 0.67840E-19 -19.1685 0.82822E+00 -0.0819 99 HSO4- 0.83498E-18 -18.0783 0.69375E-18 -18.1588 0.83086E+00 -0.0805 101 S2O3-2 0.32025E-19 -19.4945 0.16060E-19 -19.7943 0.50147E+00 -0.2998 Charge balance for all species = 0.1510E-08 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.9969904E-10 -.2032833E-01 -.2045146E+02 0.0000 2 H2O 0.1000000E+01 0.5550535E+02 0.9980774E+06 0.0000 3 Cl- 0.3993520E-02 0.4013897E-02 0.1420388E+03 7.5998 4 SO4-- 0.1722975E-10 -.3658249E-03 -.3507607E+02 9.0981 5 HCO3- 0.6319382E-05 0.3802279E-03 0.2315710E+02 4.7998 6 HS- 0.7418086E-03 0.1107792E-02 0.3656845E+02 6.8688 7 Al+++ 0.1468633E-28 0.4785411E-05 0.1288763E+00 0.7390 8 H4SiO4 0.6959797E-03 0.1248533E-01 0.1197790E+04 -3.1574 9 Ca++ 0.1752011E-06 0.2907885E-06 0.1163245E-01 13.1018 10 Mg++ 0.2742156E-10 0.1091163E-09 0.2647880E-05 9.2942 11 Fe++ 0.7557122E-13 0.3268759E-07 0.1822093E-02 6.7350 12 K+ 0.1768060E-03 0.1775685E-03 0.6930311E+01 6.2467 13 Na+ 0.2244008E-01 0.2490610E-01 0.5715165E+03 8.3494 14 Mn++ 0.2426189E-10 0.2569151E-08 0.1408803E-03 9.2419 15 HPO4-- 0.3729910E-07 0.3814711E-07 0.3654481E-02 12.4336 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.1589617E+03 -.6987685E-03 -.1589610E+03 0.0000000E+00 2 H2O -.6483168E+02 0.1907948E+01 -.6673962E+02 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.2660742E+00 -.1257491E-04 0.2660868E+00 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.2660487E+00 0.3807938E-04 -.2660868E+00 0.0000000E+00 7 Al+++ 0.3130312E+02 0.1644943E-06 0.3130312E+02 0.0000000E+00 8 H4SiO4 0.9996271E+02 0.4291722E-03 0.9996228E+02 0.0000000E+00 9 Ca++ 0.1104138E+02 0.9995599E-08 0.1104138E+02 0.0000000E+00 10 Mg++ 0.7619047E+01 0.3750777E-11 0.7619047E+01 0.0000000E+00 11 Fe++ 0.6844882E+01 0.1123607E-08 0.6844882E+01 0.0000000E+00 12 K+ 0.2038216E+01 0.6103760E-05 0.2038210E+01 0.0000000E+00 13 Na+ 0.1205050E+02 0.8561253E-03 0.1204964E+02 0.0000000E+00 14 Mn++ 0.1664505E+00 0.8831230E-10 0.1664505E+00 0.0000000E+00 15 HPO4-- 0.5680873E-01 0.1311273E-08 0.5680873E-01 0.0000000E+00 Chg. balance for solid moles: 0.7855E-14 Mass of aqueous solution: 0.344385E+02 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 9599.9990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 12.04 1.081 3157. 3.499 30.10 1212. andradite 1.064 0.027 540.9 2.733 5.157 140.5 grossular 0.2577 -0.589 116.1 2.065 1.107 32.30 apatite-OH 0.1894E-01 -1.723 9.512 0.978 0.9070E-01 3.023 clinochlore 1.363 0.134 757.4 2.879 7.222 288.1 daphnite 0.3945 -0.404 281.5 2.449 2.684 85.29 chlorite-Mn 0.3329E-01 -1.478 23.60 1.373 0.2250 7.521 diopside 0.5129 -0.290 111.1 2.046 1.059 33.94 hedenbergite 0.1330 -0.876 33.00 1.518 0.3146 9.038 microcline 1.787 0.252 497.5 2.697 4.743 194.3 stilbite 6.173 0.790 4350. 3.639 41.48 2029. stilpnomelane-Fe 0.5020 -0.299 541.1 2.733 5.159 186.9 tr.625ac.25prg.125 0.8085E-01 -1.092 69.10 1.840 0.6589 22.24 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8051E+00 0.8051E+00 1.0000 -0.094 grossular 0.1949E+00 0.1949E+00 1.0000 -0.710 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.7611E+00 0.7611E+00 1.0000 -0.119 daphnite 0.2203E+00 0.2203E+00 1.0000 -0.657 chlorite-Mn 0.1859E-01 0.1859E-01 1.0000 -1.731 diopside 0.7941E+00 0.7941E+00 1.0000 -0.100 hedenbergite 0.2059E+00 0.2059E+00 1.0000 -0.686 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 tr.625ac.25prg.125 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass =10487.868029 g Volume = 4244.118599 cm3 Porosity: -10.4952% V(tot) - V(min): -.40312E+03 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 9599.9990000 g log = 3.9823 Original solution: 1000.0103000 g Original solution / Rock added: 0.10 (Water/Rock Ratio), log = -0.9823 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.5686 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.6539E+00 0.9807 0.1006E+01 0.1026E+01 CO2,gas 0.6339E-07 1.0018 0.9962E-07 0.9944E-07 CH4,gas 0.3364E+00 1.0078 0.5318E+00 0.5277E+00 H2,gas 0.9686E-02 1.0008 0.1521E-01 0.1519E-01 H2S,gas 0.2783E-05 0.9939 0.4339E-05 0.4366E-05 S2,gas 0.1949E-26 1.0000 0.3057E-26 0.3057E-26 CO,gas 0.2574E-12 1.0000 0.4037E-12 0.4037E-12 SO3,gas 0.1442E-46 1.0000 0.2262E-46 0.2262E-46 SO2,gas 0.8533E-26 1.0000 0.1338E-25 0.1338E-25 HCl,gas 0.5667E-16 1.0000 0.8890E-16 0.8890E-16 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 16 albite -0.38 -0.38 0.00 0.000 -0.94784E-12 22 andradite 39.01 39.01 0.00 0.000 0.12132E-10 23 grossular 32.73 32.73 0.00 0.000 -0.12132E-10 32 apatite-OH -18.15 -18.15 0.00 0.000 0.00000E+00 46 clinochlore 39.07 39.07 0.00 0.000 -0.12132E-10 47 daphnite 28.97 28.97 0.00 0.000 0.60662E-11 48 chlorite-Mn 46.87 46.87 0.00 0.000 0.00000E+00 67 diopside 16.18 16.18 0.00 0.000 0.00000E+00 68 hedenbergite 14.21 14.21 0.00 0.000 0.60662E-11 116 microcline -2.49 -2.49 0.00 0.000 0.15165E-11 163 stilbite -7.52 -7.52 0.00 0.000 -0.90992E-11 164 stilpnomelane-Fe 13.02 13.02 0.00 0.000 -0.75827E-10 245 tr.625ac.25prg.125 45.16 45.16 0.00 0.000 0.24265E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -15.36 -8.70 -2.900 0.14856E+05 -7.002 3 CH4,gas 4.54 2.57 -1.97 -0.493 0.33692E+04 -0.274 4 H2,gas 8.00 4.48 -3.52 -2.010 0.60051E+04 -1.818 5 H2S,gas -6.23 -13.29 -7.06 -3.531 0.12057E+05 -5.363 6 S2,gas -7.34 -35.55 -28.21 -4.341 0.48174E+05 -26.515 7 CO,gas 3.21 -10.88 -14.09 -4.336 0.24063E+05 -12.394 8 SO3,gas 17.12 -31.22 -48.34 -12.086 0.82547E+05 -46.645 9 SO2,gas 0.83 -26.74 -27.57 -7.353 0.47079E+05 -25.873 10 HCl,gas 5.19 -12.56 -17.75 -8.875 0.30308E+05 -16.051 11 acmite 7.71 6.53 -1.18 -0.123 0.20175E+04 15 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 19 spessartine 24.46 19.73 -4.73 -0.236 0.80691E+04 20 analcite 3.32 2.77 -0.55 -0.061 0.93626E+03 26 annite 20.12 17.72 -2.40 -0.134 0.41064E+04 27 phlogopite 27.06 25.40 -1.67 -0.093 0.28490E+04 29 anorthite 12.71 8.26 -4.45 -0.342 0.75903E+04 35 aragonite 0.97 -2.26 -3.23 -1.075 0.55074E+04 36 brucite 12.57 9.29 -3.27 -0.655 0.55909E+04 37 calcite 0.81 -2.26 -3.07 -1.024 0.52432E+04 38 carnegieite-low 9.02 5.93 -3.09 -0.442 0.52801E+04 39 carnegieite-high 10.09 5.93 -4.16 -0.595 0.71071E+04 40 carpholite-Mg 8.58 4.46 -4.12 -0.275 0.70429E+04 41 carpholite-Fe 6.71 1.90 -4.81 -0.321 0.82207E+04 42 celadonite 5.34 3.65 -1.69 -0.099 0.28879E+04 43 celadonite-Fe 3.88 1.09 -2.79 -0.164 0.47561E+04 44 chrysotile 23.89 21.57 -2.32 -0.194 0.39692E+04 49 chlorite-Al-free 47.17 43.14 -4.04 -0.168 0.68937E+04 51 chloritoid-Fe 9.17 5.06 -4.12 -0.275 0.70316E+04 52 chloritoid-Mn 11.40 7.56 -3.84 -0.256 0.65543E+04 54 coesite -2.38 -3.16 -0.78 -0.260 0.13341E+04 61 cristobalite -2.56 -3.16 -0.60 -0.199 0.10195E+04 63 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71234E+04 65 diaspore 2.87 0.74 -2.13 -0.356 0.36450E+04 66 diamond -3.10 -6.40 -3.29 -0.941 0.56223E+04 71 enstatite 17.26 12.27 -4.99 -0.499 0.85226E+04 73 clinoenstatite 17.17 12.27 -4.89 -0.489 0.83542E+04 75 epidote 24.67 22.70 -1.97 -0.095 0.33585E+04 76 clinozoisite 22.81 18.95 -3.86 -0.175 0.65869E+04 77 epidote-Fe 29.84 26.46 -3.38 -0.176 0.57768E+04 78 fayalite 14.05 10.31 -3.73 -0.533 0.63743E+04 79 ferrosilite 11.15 7.16 -3.99 -0.399 0.68202E+04 83 gibbsite 4.08 0.74 -3.34 -0.477 0.57036E+04 84 glaucophane 22.97 20.80 -2.17 -0.059 0.37134E+04 85 glaucophane-Fe 17.28 13.12 -4.15 -0.112 0.70919E+04 86 graphite -3.55 -6.40 -2.85 -0.814 0.48645E+04 87 greenalite 16.14 13.89 -2.25 -0.187 0.38408E+04 90 hematite 12.57 8.99 -3.58 -0.434 0.61111E+04 91 heulandite -5.83 -7.52 -1.69 -0.077 0.28938E+04 95 jadeite 4.22 2.77 -1.44 -0.144 0.24617E+04 97 kalsilite 7.58 3.83 -3.76 -0.537 0.64126E+04 98 kaolinite -1.33 -4.84 -3.50 -0.319 0.59832E+04 101 laumontite 2.88 1.95 -0.93 -0.062 0.15935E+04 102 lawsonite 9.62 8.26 -1.35 -0.090 0.23070E+04 103 leucite 4.12 0.67 -3.45 -0.345 0.58873E+04 105 lizardite 23.24 21.57 -1.68 -0.140 0.28619E+04 107 magnetite 20.09 15.72 -4.37 -0.356 0.74536E+04 108 minnesotaite 10.39 7.58 -2.81 -0.165 0.48027E+04 112 manganosite 14.06 9.24 -4.82 -1.204 0.82235E+04 120 muscovite 2.58 -1.01 -3.59 -0.211 0.61315E+04 121 paragonite 4.24 1.09 -3.15 -0.185 0.53706E+04 122 nepheline 8.34 5.93 -2.41 -0.344 0.41125E+04 128 periclase-Fe 11.63 6.73 -4.89 -1.223 0.83523E+04 134 phlogopite-Na 29.65 27.50 -2.15 -0.119 0.36678E+04 136 prehnite 19.37 18.21 -1.16 -0.068 0.19849E+04 137 prehnite-Fe 22.50 21.96 -0.53 -0.032 0.91159E+03 138 pumpellyite-Fe 46.27 43.89 -2.38 -0.053 0.40582E+04 139 pumpellyite-Mg 48.99 46.45 -2.54 -0.057 0.43421E+04 142 pyrite -21.25 -24.33 -3.08 -0.726 0.52666E+04 143 pyrrhotite -4.26 -6.56 -2.30 -0.765 0.39212E+04 144 pyrrhotiteFe0.875 -6.02 -7.95 -1.94 -0.713 0.33084E+04 145 pyroxmangite 7.40 6.08 -1.31 -0.263 0.22439E+04 146 pyrophyllite -6.18 -11.15 -4.98 -0.311 0.84962E+04 147 quartz -2.99 -3.16 -0.17 -0.056 0.28679E+03 152 rhodonite 7.45 6.08 -1.36 -0.272 0.23241E+04 153 sanidine -1.28 -2.49 -1.21 -0.093 0.20677E+04 165 stilpnomelane-Mg 27.44 25.81 -1.63 -0.049 0.27804E+04 171 talc 16.49 15.25 -1.24 -0.073 0.21140E+04 174 tephroite 18.09 15.33 -2.76 -0.394 0.47115E+04 178 tridymite -2.63 -3.16 -0.53 -0.177 0.90677E+03 179 tremolite 47.87 47.42 -0.45 -0.012 0.77495E+03 180 ferroactinolite 38.45 34.62 -3.83 -0.104 0.65448E+04 181 troilite-low -4.41 -6.56 -2.15 -0.715 0.36640E+04 183 vesuvianite 223.47 218.82 -4.65 -0.036 0.79440E+04 187 wairakite 3.95 1.95 -2.00 -0.118 0.34155E+04 188 walstromite 11.51 9.94 -1.56 -0.313 0.26719E+04 189 wollastonite 10.46 9.94 -0.52 -0.103 0.88229E+03 190 pseudo-wollastonite 11.00 9.94 -1.06 -0.211 0.18021E+04 191 zoisite 22.85 18.95 -3.90 -0.177 0.66609E+04 192 akaganeite 7.75 4.49 -3.26 -0.705 0.55681E+04 199 chalcedony -2.80 -3.16 -0.35 -0.118 0.60609E+03 201 montmorillonite-Ca -2.29 -6.17 -3.88 -0.240 0.66180E+04 202 montmorillonite-K -2.24 -6.27 -4.03 -0.247 0.68816E+04 203 montmorillonite-Mg -2.48 -6.79 -4.32 -0.267 0.73678E+04 204 montmorillonite-Na -2.04 -5.57 -3.54 -0.216 0.60365E+04 205 nontronite-Ca 3.21 -0.19 -3.41 -0.221 0.58215E+04 206 nontronite-H 2.53 -2.36 -4.89 -0.328 0.83484E+04 207 nontronite-K 3.34 -0.30 -3.64 -0.233 0.62083E+04 208 nontronite-Mg 3.07 -0.82 -3.90 -0.253 0.66553E+04 209 nontronite-Na 3.52 0.40 -3.12 -0.200 0.53291E+04 224 tobermorite 9.82 7.76 -2.07 -0.564 0.35287E+04 230 alabandite -0.98 -4.05 -3.07 -1.024 0.52453E+04 233 boehmite 4.41 0.74 -3.67 -0.611 0.62619E+04 235 ferrous-oxide 9.81 6.73 -3.08 -0.769 0.52532E+04 240 silica-amorphous -2.09 -3.16 -1.07 -0.355 0.18203E+04 242 an20ab80 2.02 1.35 -0.67 -0.052 0.11472E+04 243 an25ab75 2.65 1.78 -0.87 -0.067 0.14810E+04 244 an30ab70 3.28 2.21 -1.07 -0.082 0.18244E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 100.0000000 g Current total amount of reactant added: 9599.9990000 g New total amount of reactant added: 9699.9990000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.5194E-10 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 14 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 9699.9990000 Water: Moles liquid = 0.1351E+01 kg liquid = 0.2433E-01 Moles total = -.6609E+02 kg total = -.1191E+01 Activity = 1.0000 Stoichiometric ionic strength = .1601710E-01 Osmotic coef. = 0.9635 True ionic strength = .2382400E-01 Chg. balance for total moles = 0.5194E-10 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.10493E-09 -9.9791 0.87187E-10 -10.0595 0.83095E+00 -0.0804 2 H2O 0.99999E+00 0.0000 0.99999E+00 0.0000 3 Cl- 0.56405E-02 -2.2487 0.46547E-02 -2.3321 0.82523E+00 -0.0834 4 SO4-- 0.23450E-10 -10.6299 0.11622E-10 -10.9347 0.49561E+00 -0.3049 5 HCO3- 0.85637E-05 -5.0673 0.70788E-05 -5.1500 0.82661E+00 -0.0827 6 HS- 0.10480E-02 -2.9797 0.86496E-03 -3.0630 0.82537E+00 -0.0834 7 Al+++ 0.17504E-28 -28.7569 0.36336E-29 -29.4397 0.20758E+00 -0.6828 8 H4SiO4 0.69598E-03 -3.1574 0.69598E-03 -3.1574 0.10000E+01 0.0000 9 Ca++ 0.19555E-06 -6.7087 0.96102E-07 -7.0173 0.49144E+00 -0.3085 10 Mg++ 0.30613E-10 -10.5141 0.14966E-10 -10.8249 0.48886E+00 -0.3108 11 Fe++ 0.84364E-13 -13.0738 0.41294E-13 -13.3841 0.48947E+00 -0.3103 12 K+ 0.18611E-03 -3.7302 0.15388E-03 -3.8128 0.82683E+00 -0.0826 13 Na+ 0.23623E-01 -1.6267 0.19490E-01 -1.7102 0.82505E+00 -0.0835 14 Mn++ 0.27084E-10 -10.5673 0.13269E-10 -10.8771 0.48994E+00 -0.3099 15 HPO4-- 0.34383E-07 -7.4637 0.17043E-07 -7.7684 0.49569E+00 -0.3048 16 HSiO3- 0.90323E-02 -2.0442 0.74537E-02 -2.1276 0.82523E+00 -0.0834 17 Ca(HSiO3)+ 0.19725E-07 -7.7050 0.16313E-07 -7.7875 0.82704E+00 -0.0825 18 Mg(HSiO3)+ 0.38228E-11 -11.4176 0.31616E-11 -11.5001 0.82704E+00 -0.0825 19 NaHSiO3,aq 0.23496E-02 -2.6290 0.23496E-02 -2.6290 0.10000E+01 0.0000 20 AlO+ 0.78627E-16 -16.1044 0.65028E-16 -16.1869 0.82704E+00 -0.0825 22 HAlO2,aq 0.14853E-09 -9.8282 0.14853E-09 -9.8282 0.10000E+01 0.0000 23 AlO2- 0.45791E-05 -5.3392 0.37710E-05 -5.4235 0.82353E+00 -0.0843 24 CH4,aq 0.51425E-03 -3.2888 0.51175E-03 -3.2909 0.99515E+00 -0.0021 25 C2H6,aq 0.38844E-11 -11.4107 0.38655E-11 -11.4128 0.99515E+00 -0.0021 26 C3H8,aq 0.67739E-18 -18.1692 0.67411E-18 -18.1713 0.99515E+00 -0.0021 28 ethanol,aq 0.14257E-18 -18.8460 0.14188E-18 -18.8481 0.99515E+00 -0.0021 29 CO,aq 0.38371E-15 -15.4160 0.38371E-15 -15.4160 0.10000E+01 0.0000 30 CO2,aq 0.13252E-08 -8.8777 0.13188E-08 -8.8798 0.99515E+00 -0.0021 31 CO3-2 0.14344E-04 -4.8433 0.70917E-05 -5.1492 0.49441E+00 -0.3059 32 CaCO3,aq 0.85456E-08 -8.0683 0.85456E-08 -8.0683 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.20997E-10 -10.6778 0.17365E-10 -10.7603 0.82704E+00 -0.0825 34 CaCl+ 0.87532E-09 -9.0578 0.72392E-09 -9.1403 0.82704E+00 -0.0825 35 CaCl2,aq 0.80056E-12 -12.0966 0.80056E-12 -12.0966 0.10000E+01 0.0000 36 CaOH+ 0.94985E-07 -7.0223 0.78556E-07 -7.1048 0.82704E+00 -0.0825 37 CaSO4,aq 0.35467E-15 -15.4502 0.35467E-15 -15.4502 0.10000E+01 0.0000 38 HCl,aq 0.74367E-13 -13.1286 0.74367E-13 -13.1286 0.10000E+01 0.0000 43 FeCl+ 0.36787E-15 -15.4343 0.30424E-15 -15.5168 0.82704E+00 -0.0825 46 FeO,aq 0.21112E-09 -9.6755 0.21112E-09 -9.6755 0.10000E+01 0.0000 47 FeOH+ 0.18641E-10 -10.7295 0.15417E-10 -10.8120 0.82704E+00 -0.0825 48 HFeO2- 0.30702E-07 -7.5128 0.25336E-07 -7.5963 0.82523E+00 -0.0834 49 FeO+ 0.13065E-16 -16.8839 0.10805E-16 -16.9664 0.82704E+00 -0.0825 51 FeO2- 0.35244E-09 -9.4529 0.29084E-09 -9.5363 0.82523E+00 -0.0834 52 HFeO2,aq 0.32251E-11 -11.4915 0.32251E-11 -11.4915 0.10000E+01 0.0000 53 H2,aq 0.11639E-04 -4.9341 0.11582E-04 -4.9362 0.99515E+00 -0.0021 54 KCl,aq 0.12982E-07 -7.8867 0.12982E-07 -7.8867 0.10000E+01 0.0000 56 KOH,aq 0.75373E-06 -6.1228 0.75373E-06 -6.1228 0.10000E+01 0.0000 57 KSO4- 0.33629E-13 -13.4733 0.27752E-13 -13.5567 0.82523E+00 -0.0834 58 MgCO3,aq 0.33357E-12 -12.4768 0.33357E-12 -12.4768 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.33411E-14 -14.4761 0.27632E-14 -14.5586 0.82704E+00 -0.0825 60 MgCl+ 0.12354E-12 -12.9082 0.10218E-12 -12.9907 0.82704E+00 -0.0825 61 MgOH+ 0.81850E-10 -10.0870 0.67693E-10 -10.1695 0.82704E+00 -0.0825 63 MnO,aq 0.18077E-08 -8.7429 0.18077E-08 -8.7429 0.10000E+01 0.0000 64 MnOH+ 0.55646E-09 -9.2546 0.46022E-09 -9.3370 0.82704E+00 -0.0825 65 MnO2-2 0.15963E-10 -10.7969 0.78921E-11 -11.1028 0.49441E+00 -0.3059 66 HMnO2- 0.18268E-09 -9.7383 0.15075E-09 -9.8217 0.82523E+00 -0.0834 69 MnCl+ 0.45989E-12 -12.3373 0.38035E-12 -12.4198 0.82704E+00 -0.0825 70 MnSO4,aq 0.44522E-19 -19.3514 0.44522E-19 -19.3514 0.10000E+01 0.0000 71 NaCl,aq 0.30065E-04 -4.5219 0.30065E-04 -4.5219 0.10000E+01 0.0000 72 NaOH,aq 0.96044E-04 -4.0175 0.96044E-04 -4.0175 0.10000E+01 0.0000 74 OH- 0.80468E-02 -2.0944 0.66267E-02 -2.1787 0.82353E+00 -0.0843 79 HPO3-2 0.12443E-14 -14.9051 0.61517E-15 -15.2110 0.49441E+00 -0.3059 81 H2PO3- 0.13033E-18 -18.8849 0.10755E-18 -18.9684 0.82523E+00 -0.0834 82 H3PO4,aq 0.90612E-18 -18.0428 0.90612E-18 -18.0428 0.10000E+01 0.0000 83 H2PO4- 0.33181E-10 -10.4791 0.27412E-10 -10.5621 0.82613E+00 -0.0830 84 PO4-3 0.72632E-09 -9.1389 0.15949E-09 -9.7973 0.21958E+00 -0.6584 88 HP2O7-3 0.64924E-18 -18.1876 0.13494E-18 -18.8699 0.20784E+00 -0.6823 89 P2O7-4 0.57747E-17 -17.2385 0.36973E-18 -18.4321 0.64026E-01 -1.1936 90 H2S,aq 0.23421E-06 -6.6304 0.23308E-06 -6.6325 0.99515E+00 -0.0021 91 S2-2 0.28950E-11 -11.5384 0.14313E-11 -11.8443 0.49441E+00 -0.3059 92 S3-2 0.78488E-19 -19.1052 0.38805E-19 -19.4111 0.49441E+00 -0.3059 97 SO3-2 0.34805E-16 -16.4584 0.17493E-16 -16.7571 0.50260E+00 -0.2988 98 HSO3- 0.11572E-18 -18.9366 0.95493E-19 -19.0200 0.82523E+00 -0.0834 99 HSO4- 0.11794E-17 -17.9283 0.97654E-18 -18.0103 0.82796E+00 -0.0820 101 S2O3-2 0.64361E-19 -19.1914 0.31821E-19 -19.4973 0.49441E+00 -0.3059 Charge balance for all species = 0.2130E-08 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.1049254E-09 -.1956095E-01 -.1967822E+02 0.0000 2 H2O 0.1000000E+01 0.5550555E+02 0.9980193E+06 0.0000 3 Cl- 0.5640511E-02 0.5670590E-02 0.2006514E+03 7.7274 4 SO4-- 0.2345007E-10 -.5171551E-03 -.4958287E+02 9.1844 5 HCO3- 0.8563660E-05 0.5371629E-03 0.3271292E+02 4.9095 6 HS- 0.1047972E-02 0.1565361E-02 0.5166972E+02 6.9965 7 Al+++ 0.1750400E-28 0.4579244E-05 0.1233164E+00 0.7390 8 H4SiO4 0.6959767E-03 0.1207784E-01 0.1158626E+04 -3.1574 9 Ca++ 0.1955543E-06 0.3197069E-06 0.1278849E-01 13.1018 10 Mg++ 0.3061341E-10 0.1167371E-09 0.2832636E-05 9.2942 11 Fe++ 0.8436364E-13 0.3128753E-07 0.1743942E-02 6.7350 12 K+ 0.1861089E-03 0.1868756E-03 0.7293108E+01 6.2467 13 Na+ 0.2362281E-01 0.2609851E-01 0.5988416E+03 8.3494 14 Mn++ 0.2708392E-10 0.2590383E-08 0.1420358E-03 9.2419 15 HPO4-- 0.3438284E-07 0.3514235E-07 0.3366418E-02 12.3506 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.1606176E+03 -.4759481E-03 -.1606171E+03 0.0000000E+00 2 H2O -.6608522E+02 0.1350535E+01 -.6743575E+02 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.2688455E+00 -.1258318E-04 0.2688581E+00 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.2688200E+00 0.3808765E-04 -.2688581E+00 0.0000000E+00 7 Al+++ 0.3162919E+02 0.1114201E-06 0.3162919E+02 0.0000000E+00 8 H4SiO4 0.1010040E+03 0.2938725E-03 0.1010037E+03 0.0000000E+00 9 Ca++ 0.1115640E+02 0.7778961E-08 0.1115640E+02 0.0000000E+00 10 Mg++ 0.7698412E+01 0.2840395E-11 0.7698412E+01 0.0000000E+00 11 Fe++ 0.6916183E+01 0.7612737E-09 0.6916183E+01 0.0000000E+00 12 K+ 0.2059448E+01 0.4546971E-05 0.2059443E+01 0.0000000E+00 13 Na+ 0.1217602E+02 0.6350169E-03 0.1217539E+02 0.0000000E+00 14 Mn++ 0.1681844E+00 0.6302800E-10 0.1681844E+00 0.0000000E+00 15 HPO4-- 0.5740049E-01 0.8550674E-09 0.5740049E-01 0.0000000E+00 Chg. balance for solid moles: 0.5823E-13 Mass of aqueous solution: 0.243786E+02 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 9699.9990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 12.17 1.085 3190. 3.504 30.10 1225. andradite 1.075 0.032 546.5 2.738 5.157 142.0 grossular 0.2604 -0.584 117.3 2.069 1.107 32.64 apatite-OH 0.1913E-01 -1.718 9.611 0.983 0.9070E-01 3.054 clinochlore 1.377 0.139 765.3 2.884 7.221 291.1 daphnite 0.3986 -0.399 284.4 2.454 2.684 86.18 chlorite-Mn 0.3364E-01 -1.473 23.85 1.377 0.2250 7.600 diopside 0.5183 -0.285 112.2 2.050 1.059 34.30 hedenbergite 0.1344 -0.872 33.35 1.523 0.3147 9.134 microcline 1.806 0.257 502.6 2.701 4.743 196.3 stilbite 6.237 0.795 4395. 3.643 41.48 2050. stilpnomelane-Fe 0.5072 -0.295 546.7 2.738 5.159 188.9 tr.625ac.25prg.125 0.8169E-01 -1.088 69.82 1.844 0.6589 22.47 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8051E+00 0.8051E+00 1.0000 -0.094 grossular 0.1949E+00 0.1949E+00 1.0000 -0.710 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.7611E+00 0.7611E+00 1.0000 -0.119 daphnite 0.2203E+00 0.2203E+00 1.0000 -0.657 chlorite-Mn 0.1859E-01 0.1859E-01 1.0000 -1.731 diopside 0.7941E+00 0.7941E+00 1.0000 -0.100 hedenbergite 0.2059E+00 0.2059E+00 1.0000 -0.686 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 tr.625ac.25prg.125 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass =10597.118500 g Volume = 4288.321562 cm3 Porosity: -10.4953% V(tot) - V(min): -.40732E+03 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 9699.9990000 g log = 3.9868 Original solution: 1000.0103000 g Original solution / Rock added: 0.10 (Water/Rock Ratio), log = -0.9868 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.7906 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.5736E+00 0.9794 0.1006E+01 0.1027E+01 CO2,gas 0.7877E-07 1.0003 0.1411E-06 0.1411E-06 CH4,gas 0.4179E+00 1.0066 0.7533E+00 0.7483E+00 H2,gas 0.8484E-02 1.0010 0.1521E-01 0.1519E-01 H2S,gas 0.3603E-05 0.9931 0.6407E-05 0.6452E-05 S2,gas 0.3722E-26 1.0000 0.6664E-26 0.6664E-26 CO,gas 0.3193E-12 1.0000 0.5718E-12 0.5718E-12 SO3,gas 0.1866E-46 1.0000 0.3340E-46 0.3340E-46 SO2,gas 0.1104E-25 1.0000 0.1976E-25 0.1976E-25 HCl,gas 0.7328E-16 1.0000 0.1312E-15 0.1312E-15 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 16 albite -0.38 -0.38 0.00 0.000 0.11184E-10 22 andradite 39.01 39.01 0.00 0.000 0.00000E+00 23 grossular 32.73 32.73 0.00 0.000 -0.12132E-10 32 apatite-OH -18.15 -18.15 0.00 0.000 0.60662E-11 46 clinochlore 39.07 39.07 0.00 0.000 0.12132E-10 47 daphnite 28.97 28.97 0.00 0.000 0.18198E-10 48 chlorite-Mn 46.87 46.87 0.00 0.000 0.24265E-10 67 diopside 16.18 16.18 0.00 0.000 0.18198E-10 68 hedenbergite 14.21 14.21 0.00 0.000 0.30331E-11 116 microcline -2.49 -2.49 0.00 0.000 0.15165E-11 163 stilbite -7.52 -7.52 0.00 0.000 0.15165E-10 164 stilpnomelane-Fe 13.02 13.02 0.00 0.000 0.21232E-10 245 tr.625ac.25prg.125 45.16 45.16 0.00 0.000 -0.48529E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -15.21 -8.55 -2.850 0.14598E+05 -6.850 3 CH4,gas 4.54 2.72 -1.82 -0.456 0.31111E+04 -0.123 4 H2,gas 8.00 4.48 -3.52 -2.010 0.60051E+04 -1.818 5 H2S,gas -6.23 -13.12 -6.89 -3.446 0.11768E+05 -5.193 6 S2,gas -7.34 -35.21 -27.88 -4.288 0.47596E+05 -26.176 7 CO,gas 3.21 -10.73 -13.94 -4.290 0.23805E+05 -12.243 8 SO3,gas 17.12 -31.05 -48.18 -12.044 0.82258E+05 -46.476 9 SO2,gas 0.83 -26.57 -27.40 -7.308 0.46790E+05 -25.704 10 HCl,gas 5.19 -12.39 -17.58 -8.790 0.30019E+05 -15.882 11 acmite 7.71 6.53 -1.18 -0.123 0.20175E+04 15 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 19 spessartine 24.46 19.73 -4.73 -0.236 0.80691E+04 20 analcite 3.32 2.77 -0.55 -0.061 0.93627E+03 26 annite 20.12 17.72 -2.40 -0.134 0.41064E+04 27 phlogopite 27.06 25.40 -1.67 -0.093 0.28490E+04 29 anorthite 12.71 8.26 -4.45 -0.342 0.75903E+04 35 aragonite 0.97 -2.11 -3.07 -1.025 0.52492E+04 36 brucite 12.57 9.29 -3.27 -0.655 0.55909E+04 37 calcite 0.81 -2.11 -2.92 -0.973 0.49850E+04 38 carnegieite-low 9.02 5.93 -3.09 -0.442 0.52801E+04 39 carnegieite-high 10.09 5.93 -4.16 -0.595 0.71071E+04 40 carpholite-Mg 8.58 4.46 -4.12 -0.275 0.70429E+04 41 carpholite-Fe 6.71 1.90 -4.81 -0.321 0.82207E+04 42 celadonite 5.34 3.65 -1.69 -0.099 0.28879E+04 43 celadonite-Fe 3.88 1.09 -2.79 -0.164 0.47561E+04 44 chrysotile 23.89 21.57 -2.32 -0.194 0.39693E+04 49 chlorite-Al-free 47.17 43.14 -4.04 -0.168 0.68937E+04 51 chloritoid-Fe 9.17 5.06 -4.12 -0.275 0.70316E+04 52 chloritoid-Mn 11.40 7.56 -3.84 -0.256 0.65543E+04 54 coesite -2.38 -3.16 -0.78 -0.260 0.13341E+04 61 cristobalite -2.56 -3.16 -0.60 -0.199 0.10195E+04 63 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71234E+04 65 diaspore 2.87 0.74 -2.13 -0.356 0.36450E+04 66 diamond -3.10 -6.24 -3.14 -0.898 0.53641E+04 71 enstatite 17.26 12.27 -4.99 -0.499 0.85226E+04 73 clinoenstatite 17.17 12.27 -4.89 -0.489 0.83542E+04 75 epidote 24.67 22.70 -1.97 -0.095 0.33585E+04 76 clinozoisite 22.81 18.95 -3.86 -0.175 0.65869E+04 77 epidote-Fe 29.84 26.46 -3.38 -0.176 0.57768E+04 78 fayalite 14.05 10.31 -3.73 -0.533 0.63743E+04 79 ferrosilite 11.15 7.16 -3.99 -0.399 0.68202E+04 83 gibbsite 4.08 0.74 -3.34 -0.477 0.57036E+04 84 glaucophane 22.97 20.80 -2.17 -0.059 0.37134E+04 85 glaucophane-Fe 17.28 13.12 -4.15 -0.112 0.70919E+04 86 graphite -3.55 -6.24 -2.70 -0.771 0.46064E+04 87 greenalite 16.14 13.89 -2.25 -0.187 0.38408E+04 90 hematite 12.57 8.99 -3.58 -0.434 0.61111E+04 91 heulandite -5.83 -7.52 -1.69 -0.077 0.28938E+04 95 jadeite 4.22 2.77 -1.44 -0.144 0.24617E+04 97 kalsilite 7.58 3.83 -3.76 -0.537 0.64126E+04 98 kaolinite -1.33 -4.84 -3.50 -0.319 0.59832E+04 101 laumontite 2.88 1.95 -0.93 -0.062 0.15935E+04 102 lawsonite 9.62 8.26 -1.35 -0.090 0.23070E+04 103 leucite 4.12 0.67 -3.45 -0.345 0.58873E+04 105 lizardite 23.24 21.57 -1.68 -0.140 0.28619E+04 107 magnetite 20.09 15.72 -4.37 -0.356 0.74536E+04 108 minnesotaite 10.39 7.58 -2.81 -0.165 0.48027E+04 112 manganosite 14.06 9.24 -4.82 -1.204 0.82235E+04 120 muscovite 2.58 -1.01 -3.59 -0.211 0.61315E+04 121 paragonite 4.24 1.09 -3.15 -0.185 0.53706E+04 122 nepheline 8.34 5.93 -2.41 -0.344 0.41125E+04 128 periclase-Fe 11.63 6.73 -4.89 -1.223 0.83523E+04 134 phlogopite-Na 29.65 27.50 -2.15 -0.119 0.36678E+04 136 prehnite 19.37 18.21 -1.16 -0.068 0.19849E+04 137 prehnite-Fe 22.50 21.96 -0.53 -0.032 0.91158E+03 138 pumpellyite-Fe 46.27 43.89 -2.38 -0.053 0.40582E+04 139 pumpellyite-Mg 48.99 46.45 -2.54 -0.057 0.43420E+04 142 pyrite -21.25 -23.99 -2.75 -0.646 0.46887E+04 143 pyrrhotite -4.26 -6.39 -2.13 -0.709 0.36322E+04 144 pyrrhotiteFe0.875 -6.02 -7.79 -1.77 -0.650 0.30194E+04 145 pyroxmangite 7.40 6.08 -1.31 -0.263 0.22438E+04 146 pyrophyllite -6.18 -11.15 -4.98 -0.311 0.84961E+04 147 quartz -2.99 -3.16 -0.17 -0.056 0.28679E+03 151 rhodochrosite -0.98 -5.97 -4.99 -1.664 0.85225E+04 152 rhodonite 7.45 6.08 -1.36 -0.272 0.23241E+04 153 sanidine -1.28 -2.49 -1.21 -0.093 0.20677E+04 165 stilpnomelane-Mg 27.44 25.81 -1.63 -0.049 0.27804E+04 171 talc 16.49 15.25 -1.24 -0.073 0.21140E+04 174 tephroite 18.09 15.33 -2.76 -0.394 0.47114E+04 178 tridymite -2.63 -3.16 -0.53 -0.177 0.90677E+03 179 tremolite 47.87 47.42 -0.45 -0.012 0.77495E+03 180 ferroactinolite 38.45 34.62 -3.83 -0.104 0.65448E+04 181 troilite-low -4.41 -6.39 -1.98 -0.659 0.33750E+04 183 vesuvianite 223.47 218.82 -4.65 -0.036 0.79440E+04 187 wairakite 3.95 1.95 -2.00 -0.118 0.34155E+04 188 walstromite 11.51 9.94 -1.56 -0.313 0.26719E+04 189 wollastonite 10.46 9.94 -0.52 -0.103 0.88229E+03 190 pseudo-wollastonite 11.00 9.94 -1.06 -0.211 0.18021E+04 191 zoisite 22.85 18.95 -3.90 -0.177 0.66609E+04 192 akaganeite 7.75 4.49 -3.26 -0.705 0.55681E+04 199 chalcedony -2.80 -3.16 -0.35 -0.118 0.60609E+03 201 montmorillonite-Ca -2.29 -6.17 -3.88 -0.240 0.66180E+04 202 montmorillonite-K -2.24 -6.27 -4.03 -0.247 0.68816E+04 203 montmorillonite-Mg -2.48 -6.79 -4.32 -0.267 0.73678E+04 204 montmorillonite-Na -2.04 -5.57 -3.54 -0.216 0.60365E+04 205 nontronite-Ca 3.21 -0.19 -3.41 -0.221 0.58215E+04 206 nontronite-H 2.53 -2.36 -4.89 -0.328 0.83484E+04 207 nontronite-K 3.34 -0.30 -3.64 -0.233 0.62083E+04 208 nontronite-Mg 3.07 -0.82 -3.90 -0.253 0.66553E+04 209 nontronite-Na 3.52 0.40 -3.12 -0.200 0.53291E+04 224 tobermorite 9.82 7.76 -2.07 -0.564 0.35287E+04 230 alabandite -0.98 -3.88 -2.90 -0.968 0.49563E+04 233 boehmite 4.41 0.74 -3.67 -0.611 0.62619E+04 235 ferrous-oxide 9.81 6.73 -3.08 -0.769 0.52532E+04 240 silica-amorphous -2.09 -3.16 -1.07 -0.355 0.18203E+04 242 an20ab80 2.02 1.35 -0.67 -0.052 0.11472E+04 243 an25ab75 2.65 1.78 -0.87 -0.067 0.14810E+04 244 an30ab70 3.28 2.21 -1.07 -0.082 0.18244E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 100.0000000 g Current total amount of reactant added: 9699.9990000 g New total amount of reactant added: 9799.9990000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.5190E-10 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 14 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 9799.9990000 Water: Moles liquid = 0.7932E+00 kg liquid = 0.1429E-01 Moles total = -.6734E+02 kg total = -.1213E+01 Activity = 1.0000 Stoichiometric ionic strength = .1954937E-01 Osmotic coef. = 0.9609 True ionic strength = .2687292E-01 Chg. balance for total moles = 0.5190E-10 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.11826E-09 -9.9272 0.97479E-10 -10.0111 0.82430E+00 -0.0839 2 H2O 0.99998E+00 0.0000 0.99998E+00 0.0000 3 Cl- 0.95992E-02 -2.0178 0.78530E-02 -2.1050 0.81809E+00 -0.0872 4 SO4-- 0.36623E-10 -10.4362 0.17547E-10 -10.7558 0.47913E+00 -0.3195 5 HCO3- 0.13223E-04 -4.8787 0.10837E-04 -4.9651 0.81959E+00 -0.0864 6 HS- 0.17845E-02 -2.7485 0.14601E-02 -2.8356 0.81824E+00 -0.0871 7 Al+++ 0.26436E-28 -28.5778 0.50782E-29 -29.2943 0.19209E+00 -0.7165 8 H4SiO4 0.69597E-03 -3.1574 0.69597E-03 -3.1574 0.10000E+01 0.0000 9 Ca++ 0.25306E-06 -6.5968 0.12013E-06 -6.9204 0.47470E+00 -0.3236 10 Mg++ 0.39636E-10 -10.4019 0.18707E-10 -10.7280 0.47197E+00 -0.3261 11 Fe++ 0.10922E-12 -12.9617 0.51618E-13 -13.2872 0.47262E+00 -0.3255 12 K+ 0.20985E-03 -3.6781 0.17204E-03 -3.7644 0.81983E+00 -0.0863 13 Na+ 0.26642E-01 -1.5744 0.21790E-01 -1.6617 0.81789E+00 -0.0873 14 Mn++ 0.35059E-10 -10.4552 0.16587E-10 -10.7802 0.47311E+00 -0.3250 15 HPO4-- 0.28452E-07 -7.5459 0.13635E-07 -7.8654 0.47922E+00 -0.3195 16 HSiO3- 0.81492E-02 -2.0889 0.66668E-02 -2.1761 0.81809E+00 -0.0872 17 Ca(HSiO3)+ 0.22241E-07 -7.6528 0.18239E-07 -7.7390 0.82005E+00 -0.0862 18 Mg(HSiO3)+ 0.43104E-11 -11.3655 0.35348E-11 -11.4516 0.82005E+00 -0.0862 19 NaHSiO3,aq 0.23495E-02 -2.6290 0.23495E-02 -2.6290 0.10000E+01 0.0000 20 AlO+ 0.88658E-16 -16.0523 0.72705E-16 -16.1384 0.82005E+00 -0.0862 22 HAlO2,aq 0.14853E-09 -9.8282 0.14853E-09 -9.8282 0.10000E+01 0.0000 23 AlO2- 0.41323E-05 -5.3838 0.33729E-05 -5.4720 0.81625E+00 -0.0882 24 CH4,aq 0.88113E-03 -3.0550 0.87594E-03 -3.0575 0.99411E+00 -0.0026 25 C2H6,aq 0.11392E-10 -10.9434 0.11325E-10 -10.9460 0.99411E+00 -0.0026 26 C3H8,aq 0.34005E-17 -17.4685 0.33804E-17 -17.4710 0.99411E+00 -0.0026 28 ethanol,aq 0.41813E-18 -18.3787 0.41567E-18 -18.3812 0.99411E+00 -0.0026 29 CO,aq 0.65678E-15 -15.1826 0.65678E-15 -15.1826 0.10000E+01 0.0000 30 CO2,aq 0.22706E-08 -8.6439 0.22573E-08 -8.6464 0.99411E+00 -0.0026 31 CO3-2 0.20321E-04 -4.6921 0.97106E-05 -5.0128 0.47786E+00 -0.3207 32 CaCO3,aq 0.14627E-07 -7.8348 0.14627E-07 -7.8348 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.40523E-10 -10.3923 0.33231E-10 -10.4785 0.82005E+00 -0.0862 34 CaCl+ 0.18617E-08 -8.7301 0.15267E-08 -8.8163 0.82005E+00 -0.0862 35 CaCl2,aq 0.28483E-11 -11.5454 0.28483E-11 -11.5454 0.10000E+01 0.0000 36 CaOH+ 0.10710E-06 -6.9702 0.87828E-07 -7.0564 0.82005E+00 -0.0862 37 CaSO4,aq 0.66936E-15 -15.1743 0.66936E-15 -15.1743 0.10000E+01 0.0000 38 HCl,aq 0.14027E-12 -12.8530 0.14027E-12 -12.8530 0.10000E+01 0.0000 43 FeCl+ 0.78240E-15 -15.1066 0.64161E-15 -15.1927 0.82005E+00 -0.0862 46 FeO,aq 0.21112E-09 -9.6755 0.21112E-09 -9.6755 0.10000E+01 0.0000 47 FeOH+ 0.21019E-10 -10.6774 0.17236E-10 -10.7636 0.82005E+00 -0.0862 48 HFeO2- 0.27700E-07 -7.5575 0.22661E-07 -7.6447 0.81809E+00 -0.0872 49 FeO+ 0.14731E-16 -16.8318 0.12080E-16 -16.9179 0.82005E+00 -0.0862 51 FeO2- 0.31798E-09 -9.4976 0.26014E-09 -9.5848 0.81809E+00 -0.0872 52 HFeO2,aq 0.32251E-11 -11.4915 0.32251E-11 -11.4915 0.10000E+01 0.0000 53 H2,aq 0.11651E-04 -4.9336 0.11582E-04 -4.9362 0.99411E+00 -0.0026 54 KCl,aq 0.24487E-07 -7.6111 0.24487E-07 -7.6111 0.10000E+01 0.0000 56 KOH,aq 0.75371E-06 -6.1228 0.75371E-06 -6.1228 0.10000E+01 0.0000 57 KSO4- 0.57261E-13 -13.2421 0.46845E-13 -13.3293 0.81809E+00 -0.0872 58 MgCO3,aq 0.57095E-12 -12.2434 0.57095E-12 -12.2434 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.64482E-14 -14.1906 0.52878E-14 -14.2767 0.82005E+00 -0.0862 60 MgCl+ 0.26276E-12 -12.5804 0.21548E-12 -12.6666 0.82005E+00 -0.0862 61 MgOH+ 0.92290E-10 -10.0348 0.75683E-10 -10.1210 0.82005E+00 -0.0862 63 MnO,aq 0.18078E-08 -8.7429 0.18078E-08 -8.7429 0.10000E+01 0.0000 64 MnOH+ 0.62745E-09 -9.2024 0.51454E-09 -9.2886 0.82005E+00 -0.0862 65 MnO2-2 0.13213E-10 -10.8790 0.63137E-11 -11.1997 0.47786E+00 -0.3207 66 HMnO2- 0.16482E-09 -9.7830 0.13484E-09 -9.8702 0.81809E+00 -0.0872 69 MnCl+ 0.97814E-12 -12.0096 0.80213E-12 -12.0958 0.82005E+00 -0.0862 70 MnSO4,aq 0.84026E-19 -19.0756 0.84026E-19 -19.0756 0.10000E+01 0.0000 71 NaCl,aq 0.56709E-04 -4.2463 0.56709E-04 -4.2463 0.10000E+01 0.0000 72 NaOH,aq 0.96041E-04 -4.0175 0.96041E-04 -4.0175 0.10000E+01 0.0000 74 OH- 0.72614E-02 -2.1390 0.59271E-02 -2.2272 0.81625E+00 -0.0882 79 HPO3-2 0.10299E-14 -14.9872 0.49214E-15 -15.3079 0.47786E+00 -0.3207 81 H2PO3- 0.11759E-18 -18.9296 0.96200E-19 -19.0168 0.81809E+00 -0.0872 82 H3PO4,aq 0.90611E-18 -18.0428 0.90611E-18 -18.0428 0.10000E+01 0.0000 83 H2PO4- 0.29934E-10 -10.5238 0.24518E-10 -10.6105 0.81906E+00 -0.0867 84 PO4-3 0.55859E-09 -9.2529 0.11412E-09 -9.9426 0.20430E+00 -0.6897 88 HP2O7-3 0.50193E-18 -18.2994 0.96552E-19 -19.0152 0.19236E+00 -0.7159 89 P2O7-4 0.42281E-17 -17.3739 0.23663E-18 -18.6259 0.55965E-01 -1.2521 90 H2S,aq 0.44249E-06 -6.3541 0.43989E-06 -6.3567 0.99411E+00 -0.0026 91 S2-2 0.85352E-11 -11.0688 0.40786E-11 -11.3895 0.47786E+00 -0.3207 92 S3-2 0.43673E-18 -18.3598 0.20869E-18 -18.6805 0.47786E+00 -0.3207 97 SO3-2 0.54284E-16 -16.2653 0.26411E-16 -16.5782 0.48653E+00 -0.3129 98 HSO3- 0.19704E-18 -18.7054 0.16120E-18 -18.7926 0.81809E+00 -0.0872 99 HSO4- 0.20077E-17 -17.6973 0.16484E-17 -17.7829 0.82106E+00 -0.0856 101 S2O3-2 0.18975E-18 -18.7218 0.90673E-19 -19.0425 0.47786E+00 -0.3207 Charge balance for all species = 0.3640E-08 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.1182558E-09 -.1789646E-01 -.1800084E+02 0.0000 2 H2O 0.1000000E+01 0.5550601E+02 0.9978667E+06 0.0000 3 Cl- 0.9599201E-02 0.9655936E-02 0.3416161E+03 7.9061 4 SO4-- 0.3662281E-10 -.8840383E-03 -.8474457E+02 9.2664 5 HCO3- 0.1322251E-04 0.9146863E-03 0.5569490E+02 5.0460 6 HS- 0.1784453E-02 0.2668934E-02 0.8808243E+02 7.1755 7 Al+++ 0.2643599E-28 0.4132407E-05 0.1112654E+00 0.7390 8 H4SiO4 0.6959695E-03 0.1119469E-01 0.1073733E+04 -3.1574 9 Ca++ 0.2530625E-06 0.3989359E-06 0.1595512E-01 13.1018 10 Mg++ 0.3963619E-10 0.1370583E-09 0.3325195E-05 9.2942 11 Fe++ 0.1092156E-12 0.2825365E-07 0.1574583E-02 6.7350 12 K+ 0.2098496E-03 0.2106278E-03 0.8218746E+01 6.2467 13 Na+ 0.2664183E-01 0.2914411E-01 0.6686164E+03 8.3494 14 Mn++ 0.3505942E-10 0.2649270E-08 0.1452413E-03 9.2420 15 HPO4-- 0.2845173E-07 0.2904025E-07 0.2781426E-02 12.1568 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.1622734E+03 -.2557234E-03 -.1622732E+03 0.0000000E+00 2 H2O -.6733876E+02 0.7931283E+00 -.6813189E+02 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.2716169E+00 -.1263207E-04 0.2716295E+00 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.2715914E+00 0.3813654E-04 -.2716295E+00 0.0000000E+00 7 Al+++ 0.3195526E+02 0.5904818E-07 0.3195526E+02 0.0000000E+00 8 H4SiO4 0.1020453E+03 0.1599616E-03 0.1020451E+03 0.0000000E+00 9 Ca++ 0.1127141E+02 0.5700416E-08 0.1127141E+02 0.0000000E+00 10 Mg++ 0.7777777E+01 0.1958433E-11 0.7777777E+01 0.0000000E+00 11 Fe++ 0.6987484E+01 0.4037179E-09 0.6987484E+01 0.0000000E+00 12 K+ 0.2080679E+01 0.3009671E-05 0.2080676E+01 0.0000000E+00 13 Na+ 0.1230155E+02 0.4164417E-03 0.1230113E+02 0.0000000E+00 14 Mn++ 0.1699182E+00 0.3785555E-10 0.1699182E+00 0.0000000E+00 15 HPO4-- 0.5799224E-01 0.4149577E-09 0.5799224E-01 0.0000000E+00 Chg. balance for solid moles: 0.2828E-13 Mass of aqueous solution: 0.143190E+02 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 9799.9990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 12.29 1.090 3223. 3.508 30.10 1237. andradite 1.087 0.036 552.1 2.742 5.157 143.5 grossular 0.2631 -0.580 118.5 2.074 1.107 32.97 apatite-OH 0.1933E-01 -1.714 9.710 0.987 0.9070E-01 3.086 clinochlore 1.391 0.143 773.1 2.888 7.221 294.1 daphnite 0.4027 -0.395 287.3 2.458 2.684 87.07 chlorite-Mn 0.3398E-01 -1.469 24.09 1.382 0.2250 7.678 diopside 0.5237 -0.281 113.4 2.055 1.059 34.66 hedenbergite 0.1358 -0.867 33.69 1.528 0.3147 9.229 microcline 1.824 0.261 507.8 2.706 4.743 198.4 stilbite 6.301 0.799 4441. 3.647 41.48 2071. stilpnomelane-Fe 0.5124 -0.290 552.4 2.742 5.159 190.8 tr.625ac.25prg.125 0.8254E-01 -1.083 70.55 1.848 0.6589 22.71 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8051E+00 0.8051E+00 1.0000 -0.094 grossular 0.1949E+00 0.1949E+00 1.0000 -0.710 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.7611E+00 0.7611E+00 1.0000 -0.119 daphnite 0.2203E+00 0.2203E+00 1.0000 -0.657 chlorite-Mn 0.1859E-01 0.1859E-01 1.0000 -1.731 diopside 0.7941E+00 0.7941E+00 1.0000 -0.100 hedenbergite 0.2059E+00 0.2059E+00 1.0000 -0.686 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 tr.625ac.25prg.125 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass =10706.368694 g Volume = 4332.524375 cm3 Porosity: -10.4954% V(tot) - V(min): -.41152E+03 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 9799.9990000 g log = 3.9912 Original solution: 1000.0103000 g Original solution / Rock added: 0.10 (Water/Rock Ratio), log = -0.9912 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 2.3283 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.4422E+00 0.9771 0.1006E+01 0.1030E+01 CO2,gas 0.1040E-06 0.9977 0.2415E-06 0.2421E-06 CH4,gas 0.5513E+00 1.0045 0.1289E+01 0.1284E+01 H2,gas 0.6523E-02 1.0012 0.1521E-01 0.1519E-01 H2S,gas 0.5241E-05 0.9910 0.1209E-04 0.1220E-04 S2,gas 0.1019E-25 1.0000 0.2374E-25 0.2374E-25 CO,gas 0.4204E-12 1.0000 0.9787E-12 0.9787E-12 SO3,gas 0.2708E-46 1.0000 0.6304E-46 0.6304E-46 SO2,gas 0.1602E-25 1.0000 0.3730E-25 0.3730E-25 HCl,gas 0.1063E-15 1.0000 0.2475E-15 0.2475E-15 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 16 albite -0.38 -0.38 0.00 0.000 -0.94784E-12 22 andradite 39.01 39.01 0.00 0.000 0.00000E+00 23 grossular 32.73 32.73 0.00 0.000 0.12132E-10 32 apatite-OH -18.15 -18.15 0.00 0.000 0.12132E-10 46 clinochlore 39.07 39.07 0.00 0.000 0.36397E-10 47 daphnite 28.97 28.97 0.00 0.000 0.60662E-11 48 chlorite-Mn 46.87 46.87 0.00 0.000 0.48529E-10 67 diopside 16.18 16.18 0.00 0.000 0.12132E-10 68 hedenbergite 14.21 14.21 0.00 0.000 0.90992E-11 116 microcline -2.49 -2.49 0.00 0.000 0.15165E-11 163 stilbite -7.52 -7.52 0.00 0.000 0.15165E-10 164 stilpnomelane-Fe 13.02 13.02 0.00 0.000 0.21232E-10 245 tr.625ac.25prg.125 45.16 45.16 0.00 0.000 0.00000E+00 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -14.98 -8.32 -2.772 0.14199E+05 -6.617 3 CH4,gas 4.54 2.96 -1.59 -0.397 0.27125E+04 0.110 4 H2,gas 8.00 4.48 -3.52 -2.010 0.60051E+04 -1.818 5 H2S,gas -6.23 -12.85 -6.62 -3.308 0.11297E+05 -4.917 6 S2,gas -7.34 -34.66 -27.32 -4.204 0.46654E+05 -25.625 7 CO,gas 3.21 -10.49 -13.71 -4.218 0.23407E+05 -12.009 8 SO3,gas 17.12 -30.78 -47.90 -11.975 0.81787E+05 -46.200 9 SO2,gas 0.83 -26.30 -27.13 -7.234 0.46319E+05 -25.428 10 HCl,gas 5.19 -12.12 -17.31 -8.653 0.29548E+05 -15.606 11 acmite 7.71 6.53 -1.18 -0.123 0.20175E+04 15 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 19 spessartine 24.46 19.73 -4.73 -0.236 0.80691E+04 20 analcite 3.32 2.77 -0.55 -0.061 0.93627E+03 26 annite 20.12 17.72 -2.40 -0.134 0.41064E+04 27 phlogopite 27.06 25.40 -1.67 -0.093 0.28490E+04 29 anorthite 12.71 8.26 -4.45 -0.342 0.75903E+04 35 aragonite 0.97 -1.87 -2.84 -0.947 0.48507E+04 36 brucite 12.57 9.29 -3.27 -0.655 0.55909E+04 37 calcite 0.81 -1.87 -2.69 -0.895 0.45865E+04 38 carnegieite-low 9.02 5.93 -3.09 -0.442 0.52801E+04 39 carnegieite-high 10.09 5.93 -4.16 -0.595 0.71071E+04 40 carpholite-Mg 8.58 4.46 -4.12 -0.275 0.70429E+04 41 carpholite-Fe 6.71 1.90 -4.81 -0.321 0.82207E+04 42 celadonite 5.34 3.65 -1.69 -0.099 0.28879E+04 43 celadonite-Fe 3.88 1.09 -2.79 -0.164 0.47561E+04 44 chrysotile 23.89 21.57 -2.32 -0.194 0.39693E+04 49 chlorite-Al-free 47.17 43.14 -4.04 -0.168 0.68937E+04 51 chloritoid-Fe 9.17 5.06 -4.12 -0.275 0.70315E+04 52 chloritoid-Mn 11.40 7.56 -3.84 -0.256 0.65543E+04 54 coesite -2.38 -3.16 -0.78 -0.260 0.13341E+04 61 cristobalite -2.56 -3.16 -0.60 -0.199 0.10195E+04 63 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71234E+04 65 diaspore 2.87 0.74 -2.13 -0.356 0.36450E+04 66 diamond -3.10 -6.01 -2.91 -0.831 0.49656E+04 71 enstatite 17.26 12.27 -4.99 -0.499 0.85226E+04 73 clinoenstatite 17.17 12.27 -4.89 -0.489 0.83542E+04 75 epidote 24.67 22.70 -1.97 -0.095 0.33585E+04 76 clinozoisite 22.81 18.95 -3.86 -0.175 0.65868E+04 77 epidote-Fe 29.84 26.46 -3.38 -0.176 0.57768E+04 78 fayalite 14.05 10.31 -3.73 -0.533 0.63743E+04 79 ferrosilite 11.15 7.16 -3.99 -0.399 0.68202E+04 83 gibbsite 4.08 0.74 -3.34 -0.477 0.57035E+04 84 glaucophane 22.97 20.80 -2.17 -0.059 0.37134E+04 85 glaucophane-Fe 17.28 13.12 -4.15 -0.112 0.70919E+04 86 graphite -3.55 -6.01 -2.46 -0.704 0.42078E+04 87 greenalite 16.14 13.89 -2.25 -0.187 0.38408E+04 90 hematite 12.57 8.99 -3.58 -0.434 0.61111E+04 91 heulandite -5.83 -7.52 -1.69 -0.077 0.28938E+04 95 jadeite 4.22 2.77 -1.44 -0.144 0.24617E+04 97 kalsilite 7.58 3.83 -3.76 -0.537 0.64126E+04 98 kaolinite -1.33 -4.84 -3.50 -0.319 0.59831E+04 101 laumontite 2.88 1.95 -0.93 -0.062 0.15935E+04 102 lawsonite 9.62 8.26 -1.35 -0.090 0.23070E+04 103 leucite 4.12 0.67 -3.45 -0.345 0.58873E+04 105 lizardite 23.24 21.57 -1.68 -0.140 0.28619E+04 107 magnetite 20.09 15.72 -4.37 -0.356 0.74536E+04 108 minnesotaite 10.39 7.58 -2.81 -0.165 0.48027E+04 112 manganosite 14.06 9.24 -4.82 -1.204 0.82235E+04 120 muscovite 2.58 -1.01 -3.59 -0.211 0.61315E+04 121 paragonite 4.24 1.09 -3.15 -0.185 0.53706E+04 122 nepheline 8.34 5.93 -2.41 -0.344 0.41125E+04 128 periclase-Fe 11.63 6.73 -4.89 -1.223 0.83523E+04 134 phlogopite-Na 29.65 27.50 -2.15 -0.119 0.36678E+04 136 prehnite 19.37 18.21 -1.16 -0.068 0.19849E+04 137 prehnite-Fe 22.50 21.96 -0.53 -0.032 0.91158E+03 138 pumpellyite-Fe 46.27 43.89 -2.38 -0.053 0.40581E+04 139 pumpellyite-Mg 48.99 46.45 -2.54 -0.057 0.43420E+04 142 pyrite -21.25 -23.44 -2.19 -0.516 0.37467E+04 143 pyrrhotite -4.26 -6.11 -1.85 -0.617 0.31612E+04 144 pyrrhotiteFe0.875 -6.02 -7.51 -1.49 -0.549 0.25484E+04 145 pyroxmangite 7.40 6.08 -1.31 -0.263 0.22438E+04 146 pyrophyllite -6.18 -11.15 -4.98 -0.311 0.84961E+04 147 quartz -2.99 -3.16 -0.17 -0.056 0.28679E+03 151 rhodochrosite -0.98 -5.73 -4.76 -1.586 0.81240E+04 152 rhodonite 7.45 6.08 -1.36 -0.272 0.23241E+04 153 sanidine -1.28 -2.49 -1.21 -0.093 0.20677E+04 165 stilpnomelane-Mg 27.44 25.81 -1.63 -0.049 0.27804E+04 171 talc 16.49 15.25 -1.24 -0.073 0.21140E+04 174 tephroite 18.09 15.33 -2.76 -0.394 0.47114E+04 178 tridymite -2.63 -3.16 -0.53 -0.177 0.90677E+03 179 tremolite 47.87 47.42 -0.45 -0.012 0.77495E+03 180 ferroactinolite 38.45 34.62 -3.83 -0.104 0.65448E+04 181 troilite-low -4.41 -6.11 -1.70 -0.567 0.29040E+04 183 vesuvianite 223.47 218.82 -4.65 -0.036 0.79439E+04 187 wairakite 3.95 1.95 -2.00 -0.118 0.34154E+04 188 walstromite 11.51 9.94 -1.56 -0.313 0.26719E+04 189 wollastonite 10.46 9.94 -0.52 -0.103 0.88229E+03 190 pseudo-wollastonite 11.00 9.94 -1.06 -0.211 0.18021E+04 191 zoisite 22.85 18.95 -3.90 -0.177 0.66609E+04 192 akaganeite 7.75 4.49 -3.26 -0.705 0.55681E+04 199 chalcedony -2.80 -3.16 -0.35 -0.118 0.60609E+03 201 montmorillonite-Ca -2.29 -6.17 -3.88 -0.240 0.66180E+04 202 montmorillonite-K -2.24 -6.27 -4.03 -0.247 0.68816E+04 203 montmorillonite-Mg -2.48 -6.79 -4.32 -0.267 0.73678E+04 204 montmorillonite-Na -2.04 -5.57 -3.54 -0.216 0.60365E+04 205 nontronite-Ca 3.21 -0.19 -3.41 -0.221 0.58215E+04 206 nontronite-H 2.53 -2.36 -4.89 -0.328 0.83484E+04 207 nontronite-K 3.34 -0.30 -3.64 -0.233 0.62083E+04 208 nontronite-Mg 3.07 -0.82 -3.90 -0.253 0.66553E+04 209 nontronite-Na 3.52 0.40 -3.12 -0.200 0.53291E+04 224 tobermorite 9.82 7.76 -2.07 -0.564 0.35287E+04 230 alabandite -0.98 -3.60 -2.63 -0.876 0.44853E+04 233 boehmite 4.41 0.74 -3.67 -0.611 0.62619E+04 235 ferrous-oxide 9.81 6.73 -3.08 -0.769 0.52532E+04 240 silica-amorphous -2.09 -3.16 -1.07 -0.355 0.18203E+04 242 an20ab80 2.02 1.35 -0.67 -0.052 0.11472E+04 243 an25ab75 2.65 1.78 -0.87 -0.067 0.14810E+04 244 an30ab70 3.28 2.21 -1.07 -0.082 0.18244E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 100.0000000 g Current total amount of reactant added: 9799.9990000 g New total amount of reactant added: 9899.9990000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.5187E-10 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 23 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 9899.9990000 Water: Moles liquid = 0.2358E+00 kg liquid = 0.4248E-02 Moles total = -.6859E+02 kg total = -.1236E+01 Activity = 0.9999 Stoichiometric ionic strength = .4151807E-01 Osmotic coef. = 0.9505 True ionic strength = .4779262E-01 Chg. balance for total moles = 0.5187E-10 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.20951E-09 -9.6788 0.16562E-09 -9.7809 0.79047E+00 -0.1021 2 H2O 0.99995E+00 0.0000 0.99995E+00 0.0000 3 Cl- 0.32173E-01 -1.4925 0.25143E-01 -1.5996 0.78148E+00 -0.1071 4 SO4-- 0.82805E-10 -10.0819 0.33181E-10 -10.4791 0.40071E+00 -0.3972 5 HCO3- 0.27724E-04 -4.5571 0.21726E-04 -4.6630 0.78366E+00 -0.1059 6 HS- 0.60019E-02 -2.2217 0.46917E-02 -2.3287 0.78170E+00 -0.1070 7 Al+++ 0.19557E-27 -27.7087 0.24909E-28 -28.6036 0.12737E+00 -0.8949 8 H4SiO4 0.69593E-03 -3.1574 0.69593E-03 -3.1574 0.10000E+01 0.0000 9 Ca++ 0.87786E-06 -6.0566 0.34677E-06 -6.4600 0.39502E+00 -0.4034 10 Mg++ 0.13790E-09 -9.8604 0.54001E-10 -10.2676 0.39158E+00 -0.4072 11 Fe++ 0.37973E-12 -12.4205 0.14901E-12 -12.8268 0.39240E+00 -0.4063 12 K+ 0.37280E-03 -3.4285 0.29226E-03 -3.5342 0.78397E+00 -0.1057 13 Na+ 0.47388E-01 -1.3243 0.37017E-01 -1.4316 0.78114E+00 -0.1073 14 Mn++ 0.12183E-09 -9.9142 0.47882E-10 -10.3198 0.39302E+00 -0.4056 15 HPO4-- 0.11784E-07 -7.9287 0.47233E-08 -8.3258 0.40081E+00 -0.3971 16 HSiO3- 0.50210E-02 -2.2992 0.39238E-02 -2.4063 0.78148E+00 -0.1071 17 Ca(HSiO3)+ 0.39510E-07 -7.4033 0.30988E-07 -7.5088 0.78430E+00 -0.1055 18 Mg(HSiO3)+ 0.76572E-11 -11.1159 0.60055E-11 -11.2214 0.78430E+00 -0.1055 19 NaHSiO3,aq 0.23492E-02 -2.6291 0.23492E-02 -2.6291 0.10000E+01 0.0000 20 AlO+ 0.15751E-15 -15.8027 0.12354E-15 -15.9082 0.78430E+00 -0.1055 22 HAlO2,aq 0.14854E-09 -9.8281 0.14854E-09 -9.8281 0.10000E+01 0.0000 23 AlO2- 0.25491E-05 -5.5936 0.19854E-05 -5.7022 0.77886E+00 -0.1085 24 CH4,aq 0.30205E-02 -2.5199 0.29840E-02 -2.5252 0.98792E+00 -0.0053 25 C2H6,aq 0.13303E-09 -9.8760 0.13142E-09 -9.8813 0.98792E+00 -0.0053 26 C3H8,aq 0.13527E-15 -15.8688 0.13364E-15 -15.8741 0.98792E+00 -0.0053 28 ethanol,aq 0.48826E-17 -17.3113 0.48236E-17 -17.3166 0.98792E+00 -0.0053 29 CO,aq 0.22373E-14 -14.6503 0.22373E-14 -14.6503 0.10000E+01 0.0000 30 CO2,aq 0.77830E-08 -8.1089 0.76890E-08 -8.1141 0.98792E+00 -0.0053 31 CO3-2 0.28711E-04 -4.5419 0.11459E-04 -4.9409 0.39909E+00 -0.3989 32 CaCO3,aq 0.49823E-07 -7.3026 0.49823E-07 -7.3026 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.24521E-09 -9.6105 0.19231E-09 -9.7160 0.78430E+00 -0.1055 34 CaCl+ 0.17990E-07 -7.7450 0.14110E-07 -7.8505 0.78430E+00 -0.1055 35 CaCl2,aq 0.84284E-10 -10.0743 0.84284E-10 -10.0743 0.10000E+01 0.0000 36 CaOH+ 0.19026E-06 -6.7207 0.14922E-06 -6.8262 0.78430E+00 -0.1055 37 CaSO4,aq 0.36537E-14 -14.4373 0.36537E-14 -14.4373 0.10000E+01 0.0000 38 HCl,aq 0.76305E-12 -12.1174 0.76305E-12 -12.1174 0.10000E+01 0.0000 43 FeCl+ 0.75609E-14 -14.1214 0.59300E-14 -14.2269 0.78430E+00 -0.1055 46 FeO,aq 0.21112E-09 -9.6755 0.21112E-09 -9.6755 0.10000E+01 0.0000 47 FeOH+ 0.37339E-10 -10.4278 0.29285E-10 -10.5334 0.78430E+00 -0.1055 48 HFeO2- 0.17067E-07 -7.7678 0.13338E-07 -7.8749 0.78148E+00 -0.1071 49 FeO+ 0.26169E-16 -16.5822 0.20524E-16 -16.6877 0.78430E+00 -0.1055 51 FeO2- 0.19592E-09 -9.7079 0.15311E-09 -9.8150 0.78148E+00 -0.1071 52 HFeO2,aq 0.32250E-11 -11.4915 0.32250E-11 -11.4915 0.10000E+01 0.0000 53 H2,aq 0.11724E-04 -4.9309 0.11582E-04 -4.9362 0.98792E+00 -0.0053 54 KCl,aq 0.13318E-06 -6.8755 0.13318E-06 -6.8755 0.10000E+01 0.0000 56 KOH,aq 0.75359E-06 -6.1229 0.75359E-06 -6.1229 0.10000E+01 0.0000 57 KSO4- 0.19256E-12 -12.7154 0.15048E-12 -12.8225 0.78148E+00 -0.1071 58 MgCO3,aq 0.19448E-11 -11.7111 0.19448E-11 -11.7111 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.39018E-13 -13.4087 0.30602E-13 -13.5143 0.78430E+00 -0.1055 60 MgCl+ 0.25392E-11 -11.5953 0.19915E-11 -11.7008 0.78430E+00 -0.1055 61 MgOH+ 0.16395E-09 -9.7853 0.12858E-09 -9.8908 0.78430E+00 -0.1055 63 MnO,aq 0.18078E-08 -8.7429 0.18078E-08 -8.7429 0.10000E+01 0.0000 64 MnOH+ 0.11146E-08 -8.9529 0.87421E-09 -9.0584 0.78430E+00 -0.1055 65 MnO2-2 0.54804E-11 -11.2612 0.21872E-11 -11.6601 0.39909E+00 -0.3989 66 HMnO2- 0.10155E-09 -9.9933 0.79359E-10 -10.1004 0.78148E+00 -0.1071 69 MnCl+ 0.94525E-11 -11.0245 0.74136E-11 -11.1300 0.78430E+00 -0.1055 70 MnSO4,aq 0.45866E-18 -18.3385 0.45866E-18 -18.3385 0.10000E+01 0.0000 71 NaCl,aq 0.30844E-03 -3.5108 0.30844E-03 -3.5108 0.10000E+01 0.0000 72 NaOH,aq 0.96026E-04 -4.0176 0.96026E-04 -4.0176 0.10000E+01 0.0000 74 OH- 0.44789E-02 -2.3488 0.34884E-02 -2.4574 0.77886E+00 -0.1085 79 HPO3-2 0.42720E-15 -15.3694 0.17049E-15 -15.7683 0.39909E+00 -0.3989 81 H2PO3- 0.72455E-19 -19.1399 0.56623E-19 -19.2470 0.78148E+00 -0.1071 82 H3PO4,aq 0.90609E-18 -18.0428 0.90609E-18 -18.0428 0.10000E+01 0.0000 83 H2PO4- 0.18432E-10 -10.7344 0.14430E-10 -10.8407 0.78289E+00 -0.1063 84 PO4-3 0.16635E-09 -9.7790 0.23269E-10 -10.6332 0.13988E+00 -0.8542 88 HP2O7-3 0.15415E-18 -18.8121 0.19687E-19 -19.7058 0.12772E+00 -0.8938 89 P2O7-4 0.10323E-17 -17.9862 0.28398E-19 -19.5467 0.27509E-01 -1.5605 90 H2S,aq 0.24308E-05 -5.6142 0.24015E-05 -5.6195 0.98792E+00 -0.0053 91 S2-2 0.10552E-09 -9.9767 0.42110E-10 -10.3756 0.39909E+00 -0.3989 92 S3-2 0.29475E-16 -16.5306 0.11763E-16 -16.9295 0.39909E+00 -0.3989 97 SO3-2 0.12178E-15 -15.9144 0.49943E-16 -16.3015 0.41011E+00 -0.3871 98 HSO3- 0.66270E-18 -18.1787 0.51789E-18 -18.2858 0.78148E+00 -0.1071 99 HSO4- 0.67394E-17 -17.1714 0.52959E-17 -17.2761 0.78580E+00 -0.1047 101 S2O3-2 0.23455E-17 -17.6298 0.93606E-18 -18.0287 0.39909E+00 -0.3989 Charge balance for all species = 0.1222E-07 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.2095145E-09 -.1198565E-01 -.1204132E+02 0.0000 2 H2O 0.1000000E+01 0.5550849E+02 0.9967326E+06 0.0000 3 Cl- 0.3217348E-01 0.3248207E-01 0.1147822E+04 8.1813 4 SO4-- 0.8280550E-10 -.3023395E-02 -.2894826E+03 9.0827 5 HCO3- 0.2772412E-04 0.3076958E-02 0.1871335E+03 5.1179 6 HS- 0.6001867E-02 0.9027693E-02 0.2975877E+03 7.4522 7 Al+++ 0.1955663E-27 0.2549241E-05 0.6855745E-01 0.7390 8 H4SiO4 0.6959269E-03 0.8066195E-02 0.7727507E+03 -3.1574 9 Ca++ 0.8778560E-06 0.1175766E-05 0.4696826E-01 13.1018 10 Mg++ 0.1379047E-09 0.3138534E-09 0.7605456E-05 9.2942 11 Fe++ 0.3797287E-12 0.1751473E-07 0.9749472E-03 6.7350 12 K+ 0.3727984E-03 0.3736851E-03 0.1456406E+02 6.2467 13 Na+ 0.4738822E-01 0.5014190E-01 0.1148983E+04 8.3493 14 Mn++ 0.1218322E-09 0.3160718E-08 0.1730758E-03 9.2420 15 HPO4-- 0.1178427E-07 0.1196905E-07 0.1145022E-02 11.2360 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.1639293E+03 -.5091149E-04 -.1639292E+03 0.0000000E+00 2 H2O -.6859230E+02 0.2357836E+00 -.6882808E+02 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.2743882E+00 -.1284248E-04 0.2744011E+00 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.2743627E+00 0.3834695E-04 -.2744011E+00 0.0000000E+00 7 Al+++ 0.3228134E+02 0.1082842E-07 0.3228134E+02 0.0000000E+00 8 H4SiO4 0.1030865E+03 0.3426280E-04 0.1030865E+03 0.0000000E+00 9 Ca++ 0.1138643E+02 0.4994302E-08 0.1138643E+02 0.0000000E+00 10 Mg++ 0.7857142E+01 0.1333156E-11 0.7857142E+01 0.0000000E+00 11 Fe++ 0.7058784E+01 0.7439738E-10 0.7058784E+01 0.0000000E+00 12 K+ 0.2101911E+01 0.1587303E-05 0.2101909E+01 0.0000000E+00 13 Na+ 0.1242707E+02 0.2129879E-03 0.1242686E+02 0.0000000E+00 14 Mn++ 0.1716521E+00 0.1342579E-10 0.1716521E+00 0.0000000E+00 15 HPO4-- 0.5858400E-01 0.5084097E-10 0.5858400E-01 0.0000000E+00 Chg. balance for solid moles: 0.7910E-14 Mass of aqueous solution: 0.426164E+01 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 9899.9990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 12.42 1.094 3256. 3.513 30.10 1250. andradite 1.098 0.040 557.8 2.746 5.157 144.9 grossular 0.2658 -0.575 119.7 2.078 1.107 33.31 apatite-OH 0.1953E-01 -1.709 9.809 0.992 0.9070E-01 3.117 clinochlore 1.405 0.148 781.0 2.893 7.221 297.1 daphnite 0.4068 -0.391 290.3 2.463 2.684 87.95 chlorite-Mn 0.3433E-01 -1.464 24.34 1.386 0.2250 7.756 diopside 0.5289 -0.277 114.5 2.059 1.059 35.01 hedenbergite 0.1372 -0.863 34.03 1.532 0.3147 9.321 microcline 1.843 0.266 513.0 2.710 4.743 200.4 stilbite 6.366 0.804 4486. 3.652 41.48 2092. stilpnomelane-Fe 0.5176 -0.286 558.0 2.747 5.159 192.7 tr.625ac.25prg.125 0.8345E-01 -1.079 71.33 1.853 0.6595 22.96 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8050E+00 0.8050E+00 1.0000 -0.094 grossular 0.1950E+00 0.1950E+00 1.0000 -0.710 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.7611E+00 0.7611E+00 1.0000 -0.119 daphnite 0.2203E+00 0.2203E+00 1.0000 -0.657 chlorite-Mn 0.1859E-01 0.1859E-01 1.0000 -1.731 diopside 0.7941E+00 0.7941E+00 1.0000 -0.100 hedenbergite 0.2059E+00 0.2059E+00 1.0000 -0.686 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 tr.625ac.25prg.125 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass =10815.616647 g Volume = 4376.725773 cm3 Porosity: -10.4955% V(tot) - V(min): -.41573E+03 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 9899.9990000 g log = 3.9956 Original solution: 1000.0103000 g Original solution / Rock added: 0.10 (Water/Rock Ratio), log = -0.9956 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 5.4480 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.1903E+00 0.9704 0.1006E+01 0.1037E+01 CO2,gas 0.1527E-06 0.9892 0.8226E-06 0.8317E-06 CH4,gas 0.8069E+00 0.9991 0.4392E+01 0.4396E+01 H2,gas 0.2783E-02 1.0029 0.1521E-01 0.1516E-01 H2S,gas 0.1238E-04 0.9791 0.6601E-04 0.6742E-04 S2,gas 0.1299E-24 1.0000 0.7074E-24 0.7074E-24 CO,gas 0.6120E-12 1.0000 0.3334E-11 0.3334E-11 SO3,gas 0.6317E-46 1.0000 0.3441E-45 0.3441E-45 SO2,gas 0.3737E-25 1.0000 0.2036E-24 0.2036E-24 HCl,gas 0.2471E-15 1.0000 0.1346E-14 0.1346E-14 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 16 albite -0.38 -0.38 0.00 0.000 -0.94784E-12 22 andradite 39.01 39.01 0.00 0.000 -0.24265E-10 23 grossular 32.73 32.73 0.00 0.000 0.00000E+00 32 apatite-OH -18.15 -18.15 0.00 0.000 0.60662E-11 46 clinochlore 39.07 39.07 0.00 0.000 -0.12132E-10 47 daphnite 28.97 28.97 0.00 0.000 0.60662E-11 48 chlorite-Mn 46.87 46.87 0.00 0.000 -0.12132E-10 67 diopside 16.18 16.18 0.00 0.000 0.60662E-11 68 hedenbergite 14.21 14.21 0.00 0.000 0.90992E-11 116 microcline -2.49 -2.49 0.00 0.000 0.15165E-11 163 stilbite -7.52 -7.52 0.00 0.000 -0.90992E-11 164 stilpnomelane-Fe 13.02 13.02 0.00 0.000 0.69761E-10 245 tr.625ac.25prg.125 45.16 45.16 0.00 0.000 0.24265E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28966E+04 0.003 2 CO2,gas -6.66 -14.44 -7.78 -2.595 0.13291E+05 -6.085 3 CH4,gas 4.54 3.49 -1.06 -0.264 0.18036E+04 0.643 4 H2,gas 8.00 4.48 -3.52 -2.010 0.60051E+04 -1.818 5 H2S,gas -6.23 -12.11 -5.88 -2.940 0.10039E+05 -4.180 6 S2,gas -7.34 -33.18 -25.85 -3.977 0.44137E+05 -24.150 7 CO,gas 3.21 -9.96 -13.18 -4.054 0.22498E+05 -11.477 8 SO3,gas 17.12 -30.04 -47.16 -11.791 0.80528E+05 -45.463 9 SO2,gas 0.83 -25.56 -26.39 -7.037 0.45061E+05 -24.691 10 HCl,gas 5.19 -11.38 -16.57 -8.285 0.28292E+05 -14.871 11 acmite 7.71 6.53 -1.18 -0.123 0.20176E+04 15 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 19 spessartine 24.46 19.73 -4.73 -0.236 0.80689E+04 20 analcite 3.32 2.77 -0.55 -0.061 0.93631E+03 26 annite 20.12 17.72 -2.40 -0.134 0.41065E+04 27 phlogopite 27.06 25.40 -1.67 -0.093 0.28491E+04 29 anorthite 12.71 8.27 -4.45 -0.342 0.75902E+04 35 aragonite 0.97 -1.34 -2.31 -0.770 0.39419E+04 36 brucite 12.57 9.29 -3.27 -0.655 0.55910E+04 37 calcite 0.81 -1.34 -2.15 -0.718 0.36776E+04 38 carnegieite-low 9.02 5.93 -3.09 -0.442 0.52802E+04 39 carnegieite-high 10.09 5.93 -4.16 -0.595 0.71072E+04 40 carpholite-Mg 8.58 4.46 -4.12 -0.275 0.70428E+04 41 carpholite-Fe 6.71 1.90 -4.81 -0.321 0.82206E+04 42 celadonite 5.34 3.65 -1.69 -0.099 0.28879E+04 43 celadonite-Fe 3.88 1.09 -2.79 -0.164 0.47561E+04 44 chrysotile 23.89 21.57 -2.32 -0.194 0.39693E+04 49 chlorite-Al-free 47.17 43.14 -4.04 -0.168 0.68938E+04 51 chloritoid-Fe 9.17 5.06 -4.12 -0.275 0.70314E+04 52 chloritoid-Mn 11.40 7.56 -3.84 -0.256 0.65542E+04 54 coesite -2.38 -3.16 -0.78 -0.260 0.13341E+04 61 cristobalite -2.56 -3.16 -0.60 -0.199 0.10194E+04 63 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71234E+04 65 diaspore 2.87 0.74 -2.13 -0.356 0.36449E+04 66 diamond -3.10 -5.48 -2.38 -0.679 0.40567E+04 71 enstatite 17.26 12.27 -4.99 -0.499 0.85226E+04 73 clinoenstatite 17.17 12.27 -4.89 -0.489 0.83542E+04 75 epidote 24.67 22.70 -1.97 -0.095 0.33584E+04 76 clinozoisite 22.81 18.95 -3.86 -0.175 0.65867E+04 77 epidote-Fe 29.84 26.46 -3.38 -0.176 0.57768E+04 78 fayalite 14.05 10.31 -3.73 -0.533 0.63743E+04 79 ferrosilite 11.15 7.16 -3.99 -0.399 0.68201E+04 83 gibbsite 4.08 0.74 -3.34 -0.477 0.57035E+04 84 glaucophane 22.97 20.80 -2.17 -0.059 0.37134E+04 85 glaucophane-Fe 17.28 13.12 -4.15 -0.112 0.70919E+04 86 graphite -3.55 -5.48 -1.93 -0.552 0.32989E+04 87 greenalite 16.14 13.89 -2.25 -0.187 0.38408E+04 89 halite 1.57 -3.03 -4.61 -2.303 0.78642E+04 90 hematite 12.57 8.99 -3.58 -0.434 0.61112E+04 91 heulandite -5.83 -7.52 -1.69 -0.077 0.28938E+04 95 jadeite 4.22 2.77 -1.44 -0.144 0.24618E+04 97 kalsilite 7.58 3.83 -3.76 -0.537 0.64126E+04 98 kaolinite -1.33 -4.84 -3.50 -0.319 0.59830E+04 101 laumontite 2.88 1.95 -0.93 -0.062 0.15935E+04 102 lawsonite 9.62 8.27 -1.35 -0.090 0.23069E+04 103 leucite 4.12 0.67 -3.45 -0.345 0.58873E+04 105 lizardite 23.24 21.57 -1.68 -0.140 0.28620E+04 107 magnetite 20.09 15.72 -4.37 -0.356 0.74536E+04 108 minnesotaite 10.39 7.58 -2.81 -0.165 0.48027E+04 112 manganosite 14.06 9.24 -4.82 -1.204 0.82235E+04 120 muscovite 2.58 -1.01 -3.59 -0.211 0.61314E+04 121 paragonite 4.24 1.09 -3.15 -0.185 0.53705E+04 122 nepheline 8.34 5.93 -2.41 -0.344 0.41125E+04 128 periclase-Fe 11.63 6.73 -4.89 -1.223 0.83523E+04 134 phlogopite-Na 29.65 27.50 -2.15 -0.119 0.36679E+04 136 prehnite 19.37 18.21 -1.16 -0.068 0.19848E+04 137 prehnite-Fe 22.50 21.96 -0.53 -0.032 0.91155E+03 138 pumpellyite-Fe 46.27 43.89 -2.38 -0.053 0.40579E+04 139 pumpellyite-Mg 48.99 46.45 -2.54 -0.057 0.43418E+04 142 pyrite -21.25 -21.97 -0.72 -0.169 0.12294E+04 143 pyrrhotite -4.26 -5.37 -1.11 -0.371 0.19026E+04 144 pyrrhotiteFe0.875 -6.02 -6.77 -0.76 -0.278 0.12898E+04 145 pyroxmangite 7.40 6.08 -1.31 -0.263 0.22438E+04 146 pyrophyllite -6.18 -11.15 -4.98 -0.311 0.84960E+04 147 quartz -2.99 -3.16 -0.17 -0.056 0.28678E+03 151 rhodochrosite -0.98 -5.20 -4.23 -1.409 0.72151E+04 152 rhodonite 7.45 6.08 -1.36 -0.272 0.23241E+04 153 sanidine -1.28 -2.49 -1.21 -0.093 0.20677E+04 165 stilpnomelane-Mg 27.44 25.81 -1.63 -0.049 0.27805E+04 171 talc 16.49 15.25 -1.24 -0.073 0.21141E+04 174 tephroite 18.09 15.33 -2.76 -0.394 0.47114E+04 178 tridymite -2.63 -3.16 -0.53 -0.177 0.90675E+03 179 tremolite 47.87 47.42 -0.45 -0.012 0.77498E+03 180 ferroactinolite 38.45 34.62 -3.83 -0.104 0.65447E+04 181 troilite-low -4.41 -5.37 -0.96 -0.321 0.16454E+04 183 vesuvianite 223.47 218.82 -4.65 -0.036 0.79434E+04 187 wairakite 3.95 1.95 -2.00 -0.118 0.34153E+04 188 walstromite 11.51 9.94 -1.56 -0.313 0.26719E+04 189 wollastonite 10.46 9.94 -0.52 -0.103 0.88229E+03 190 pseudo-wollastonite 11.00 9.94 -1.06 -0.211 0.18021E+04 191 zoisite 22.85 18.95 -3.90 -0.177 0.66607E+04 192 akaganeite 7.75 4.49 -3.26 -0.705 0.55681E+04 199 chalcedony -2.80 -3.16 -0.35 -0.118 0.60607E+03 201 montmorillonite-Ca -2.29 -6.17 -3.88 -0.240 0.66179E+04 202 montmorillonite-K -2.24 -6.27 -4.03 -0.247 0.68815E+04 203 montmorillonite-Mg -2.48 -6.79 -4.31 -0.267 0.73676E+04 204 montmorillonite-Na -2.04 -5.57 -3.54 -0.216 0.60364E+04 205 nontronite-Ca 3.21 -0.19 -3.41 -0.221 0.58214E+04 206 nontronite-H 2.53 -2.36 -4.89 -0.328 0.83484E+04 207 nontronite-K 3.34 -0.30 -3.64 -0.233 0.62083E+04 208 nontronite-Mg 3.07 -0.82 -3.90 -0.253 0.66553E+04 209 nontronite-Na 3.52 0.40 -3.12 -0.200 0.53292E+04 224 tobermorite 9.82 7.76 -2.07 -0.564 0.35288E+04 230 alabandite -0.98 -2.87 -1.89 -0.630 0.32267E+04 233 boehmite 4.41 0.74 -3.67 -0.611 0.62619E+04 235 ferrous-oxide 9.81 6.73 -3.08 -0.769 0.52532E+04 240 silica-amorphous -2.09 -3.16 -1.07 -0.355 0.18203E+04 242 an20ab80 2.02 1.35 -0.67 -0.052 0.11472E+04 243 an25ab75 2.65 1.78 -0.87 -0.067 0.14809E+04 244 an30ab70 3.28 2.21 -1.07 -0.082 0.18243E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 100.0000000 g Current total amount of reactant added: 9899.9990000 g New total amount of reactant added: 9999.9990000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.5187E-10 ******** WARNING ******** Computational singularity, IV(N) = 0.0