File SKIP_SPECIES.TXT lists species and minerals omitted from the calculations due to given T, P, option switches, or suppression in CHIMRUN, or are suppressed in the SOLTHERM database. It also lists minerals for which density is not specified in SOLTHERM. This is an extended P(to 5 kB), T(to 600 C) run (CON_FLAG = 1). methanol,aq is suppressed in SOLTHERM data file. methanol,aq is suppressed in SOLTHERM data file. CuCl4-3 is suppressed in SOLTHERM data file. H2BO3- is suppressed in SOLTHERM data file. UO2CO3,aq is suppressed in SOLTHERM data file. UO2SO4,aq is suppressed in SOLTHERM data file. UO2Cl2,aq is suppressed in SOLTHERM data file. UO2F2,aq is suppressed in SOLTHERM data file. PO4-3 is suppressed in SOLTHERM data file. H2PO4- is suppressed in SOLTHERM data file. H3PO4 is suppressed in SOLTHERM data file. O2,gas is suppressed in THIS RUN. O2,gas is suppressed in THIS RUN. amesite is suppressed in SOLTHERM data file. antigorite is suppressed in SOLTHERM data file. goethite is suppressed in THIS RUN. goethite is suppressed in THIS RUN. riebeckite is suppressed in THIS RUN. riebeckite is suppressed in THIS RUN. sapphirine-Fe(221) is suppressed in SOLTHERM data file. sapphirine(221) is suppressed in SOLTHERM data file. talc-prl is suppressed in SOLTHERM data file. PrO1.833(s) is suppressed in SOLTHERM data file. niter-NH4 is suppressed in SOLTHERM data file. FMQ_HS-1 is suppressed in THIS RUN. kf-ab-equil is suppressed in THIS RUN. ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Species No. Charge Tot.moles Trial molality Gamma Mixing solution H+ 1 1. -0.20027E-01 0.88291E-10 0.8403 0.00000000E+00 H2O 2 0. 0.49846E+02 0.10000E+01 1.0000 0.00000000E+00 Cl- 3 -1. 0.13788E-03 0.15294E-03 0.8352 0.00000000E+00 SO4-- 4 -2. -0.14985E-04 0.72062E-12 0.5193 0.00000000E+00 HCO3- 5 -1. 0.13070E-04 0.26667E-06 0.8364 0.00000000E+00 HS- 6 -1. 0.40490E-04 0.28395E-04 0.8353 0.00000000E+00 Al+++ 7 3. 0.47754E-05 0.96913E-29 0.2310 0.00000000E+00 H4SiO4 8 0. 0.12153E-01 0.69592E-03 1.0000 0.00000000E+00 Ca++ 9 2. 0.20808E-06 0.13499E-06 0.5155 0.00000000E+00 Mg++ 10 2. 0.83683E-10 0.21118E-10 0.5131 0.00000000E+00 Fe++ 11 2. 0.32592E-07 0.58201E-13 0.5137 0.00000000E+00 K+ 12 1. 0.14123E-03 0.15651E-03 0.8366 0.00000000E+00 Na+ 13 1. 0.20032E-01 0.19860E-01 0.8350 0.00000000E+00 Mn++ 14 2. 0.22519E-08 0.18539E-10 0.5141 0.00000000E+00 F- 15 -1. 0.10000E-06 0.10000E-05 1.0000 0.00000000E+00 HPO4-- 16 -2. 0.41688E-07 0.45316E-07 0.5194 0.00000000E+00 Chg. balance for total moles = -.5508E-08 Max. difference allowed = 0.1379E-07 The following parameters were given: ERPC = 0.1000E-11 pH = 0.0000 PFLUID = 50.0000 SLIM = 0.400000E-03 TEMP = 100.0000 SINC = 0.1000E-04 TEMPC = 0.0000 TOTMIX = 0.000000E+00 ENTH = 0.0000 SENTH = 0.0000 DENTH = 0.0000 TOTWAT = 90.0000 SOLMIN = 0.0000E+00 RM = 0.0000 AQGRM = 1000.0103 SUPRNT = 0.1000E-19 VBOX-1 = 400.9996 RHOFRS = 0.0000 RHOROC = 2.5000 The following options were selected: CONFLG = 1 C = 3 IFRAC = 0 IPUNCH = 1 NLOOP = 400 ISTEP = 2 LIMSOL = 1 LOOC = 0 IENTH = 0 ITREF = 0 IDEAL = 0 IPSAT = 1 INCREM = 0 INCP = 0 MINSOL = 3 NEUT = 0 AWAT = 0 CHGF = 0 Of the derived species, only those with molality > 0.10E-19 will appear in the output Species No. Charge Log K(diss) Species No. Charge Log K(diss) SiF6-2 17 -2. -24.5019 Mn+3 70 3. 19.1453 HSiO3- 18 -1. 9.0298 MnF+ 71 1. -1.2264 Ca(HSiO3)+ 19 1. 7.6723 MnO,aq 72 0. 17.9848 Mg(HSiO3)+ 20 1. 7.5773 MnOH+ 73 1. 8.5194 NaHSiO3,aq 21 0. 7.8210 MnO2-2 74 -2. 40.4638 AlO+ 22 1. 6.8663 HMnO2- 75 -1. 29.1232 AlOH+2 23 2. 3.1691 MnO4- 76 -1. 83.3111 HAlO2,aq 24 0. 10.5671 MnO4-2 77 -2. 81.3005 AlO2- 25 -1. 16.2221 MnCl+ 78 1. -0.7894 CH4,aq 26 0. 6.0126 MnSO4,aq 79 0. -2.4604 C2H6,aq 27 0. 12.3733 NaCl,aq 80 0. 0.4796 C3H8,aq 28 0. 17.3707 NaF,aq 81 0. 0.6306 C4H10,aq 29 0. 22.3757 NaOH,aq 82 0. 12.3669 ethanol,aq 30 0. 15.3258 O2,aq 83 0. 53.5502 CO,aq 31 0. 4.6892 OH- 84 -1. 12.2382 CO2,aq 32 0. -6.3298 HO2- 85 -1. 50.8010 CO3-2 33 -2. 10.0588 H2O2,aq 86 0. 40.0166 CaCO3,aq 34 0. 5.9605 H3PO2,aq 87 0. 24.3066 Ca(HCO3)+ 35 1. -1.4070 H2PO2- 88 -1. 26.5366 CaCl+ 36 1. -0.2091 HPO3-2 89 -2. 11.9254 CaCl2,aq 37 0. 0.4151 H3PO3,aq 90 0. 3.5792 CaF+ 38 1. -1.1644 H2PO3- 91 -1. 5.6232 CaOH+ 39 1. 10.1471 H3PO4,aq 92 0. -9.8447 CaSO4,aq 40 0. -2.5018 H2PO4- 93 -1. -7.2659 HCl,aq 41 0. 0.7370 PO4-3 94 -3. 12.0884 HClO,aq 42 0. 32.4260 H4P2O7,aq 95 0. -17.8095 ClO- 43 -1. 39.6530 H3P2O7- 96 -1. -15.9156 HClO2,aq 44 0. 70.1812 H2P2O7-2 97 -2. -13.4262 HF,aq 45 0. -3.8354 HP2O7-3 98 -3. -6.7266 HF2- 46 -1. -3.3639 P2O7-4 99 -4. 2.8952 Fe+3 47 3. 8.3809 H2S,aq 100 0. -6.4900 FeCl+ 48 1. -0.1994 S2-2 101 -2. 1.2355 FeCl2,aq 49 0. 4.3001 S3-2 102 -2. -8.8031 FeCl+2 50 2. 6.5269 S3- 103 -1. -16.3389 FeF+ 51 1. -1.7084 S4-2 104 -2. -18.6615 FeF+2 52 2. 1.4309 S5-2 105 -2. -28.3439 FeO,aq 53 0. 16.4104 SO2,aq 106 0. -0.2309 FeOH+ 54 1. 7.4874 SO3-2 107 -2. 10.3052 HFeO2- 55 -1. 24.3908 HSO3- 108 -1. 2.5086 FeO+ 56 1. 11.4004 HSO4- 109 -1. -2.9839 FeOH+2 57 2. 9.1194 HSO5- 110 -1. 38.8366 FeO2- 58 -1. 24.0895 S2O3-2 111 -2. -4.5600 HFeO2,aq 59 0. 15.9850 HS2O3- 112 -1. -6.8123 H2,aq 60 0. 9.4190 H2S2O3,aq 113 0. -8.0173 KCl,aq 61 0. 1.7417 S2O4-2 114 -2. 10.5541 KHSO4,aq 62 0. -0.4514 HS2O4- 115 -1. 7.6551 KOH,aq 63 0. 12.3695 H2S2O4,aq 116 0. 6.6259 KSO4- 64 -1. -1.1908 S2O5-2 117 -2. 10.0741 MgCO3,aq 65 0. 6.5614 S2O6-2 118 -2. 11.5521 Mg(HCO3)+ 66 1. -1.4164 S2O8-2 119 -2. 42.0620 MgCl+ 67 1. -0.1664 S3O6-2 120 -2. 3.7866 MgF+ 68 1. -1.7331 S4O6-2 121 -2. -17.8657 MgOH+ 69 1. 9.4041 S5O6-2 122 -2. -14.1333 For mixed gases (JSOLS=6), log K(hydrol) = log (K*P) Log K Trial Log K Trial Mineral No. hydrol Moles Mineral No. hydrol Moles H2O,gas 1 1.696 0.0000E+00 osumilite(1) 126 21.717 0.0000E+00 CO2,gas 2 -6.660 0.0000E+00 osumilite(2) 127 20.667 0.0000E+00 CH4,gas 3 4.544 0.0000E+00 osumilite-Fe 128 14.390 0.0000E+00 H2,gas 4 8.000 0.0000E+00 pargasite 129 65.092 0.0000E+00 H2S,gas 5 -6.230 0.0000E+00 periclase 130 16.138 0.0000E+00 S2,gas 6 -7.335 0.0000E+00 periclase-Fe 131 11.627 0.0000E+00 CO,gas 7 3.215 0.0000E+00 perovskite-Al 132 12.344 0.0000E+00 SO3,gas 8 17.121 0.0000E+00 perovskite-Ca 133 23.807 0.0000E+00 SO2,gas 9 0.832 0.0000E+00 perovskite-Fe 134 21.143 0.0000E+00 HF,gas 10 0.473 0.0000E+00 perovskite-Mg 135 23.119 0.0000E+00 HCl,gas 11 5.189 0.0000E+00 phase_A 136 80.189 0.0000E+00 acmite 12 7.710 0.0000E+00 phlogopite-Na 137 29.647 0.0000E+00 akermanite 13 36.442 0.0000E+00 piemontite(ordered) 138 33.776 0.0000E+00 akimotoite 14 16.591 0.0000E+00 prehnite 139 19.372 0.0000E+00 akimotoite-Fe 15 13.067 0.0000E+00 prehnite-Fe 140 22.498 0.0000E+00 albite-high 16 0.693 0.0000E+00 pumpellyite-Fe 141 46.269 0.0000E+00 albite 17 -0.384 0.0000E+00 pumpellyite-Mg 142 48.995 0.0000E+00 almandine 18 24.442 0.0000E+00 px-Mg-tschermaks 143 19.616 0.0000E+00 pyrope 19 37.248 0.0000E+00 px-Ca-tschermaks 144 18.610 0.0000E+00 spessartine 20 24.457 0.0000E+00 pyrite 145 -21.247 0.0000E+00 analcite 21 3.322 0.0000E+00 pyrrhotite 146 -4.260 0.0000E+00 andalusite 22 5.002 0.0000E+00 pyrrhotiteFe0.875 147 -6.017 0.0000E+00 andradite 23 39.009 0.0000E+00 pyroxmangite 148 7.399 0.0000E+00 grossular 24 32.731 0.0000E+00 pyrophyllite 149 -6.176 0.0000E+00 anhydrite 25 -5.317 0.0000E+00 quartz 150 -2.989 0.0000E+00 ankerite 26 -2.135 0.0000E+00 rankinite 151 40.713 0.0000E+00 annite 27 20.123 0.0000E+00 ringwoodite-Fe 152 15.456 0.0000E+00 phlogopite 28 27.065 0.0000E+00 ringwoodite-Mg 153 27.575 0.0000E+00 biotite-Mn 29 32.960 0.0000E+00 rhodochrosite 154 -0.976 0.0000E+00 anorthite 30 12.710 0.0000E+00 rhodonite 155 7.446 0.0000E+00 anthophyllite 31 51.852 0.0000E+00 sanidine 156 -1.275 0.0000E+00 anthophyllite-Fe 32 29.306 0.0000E+00 sapphirine(351) 157 78.899 0.0000E+00 apatite-OH 33 -18.153 0.0000E+00 siderite 158 -2.608 0.0000E+00 apatite-F 34 -34.301 0.0000E+00 sillimanite 159 5.262 0.0000E+00 apatite-OH-zs 35 -12.736 0.0000E+00 sodalite 160 49.976 0.0000E+00 apatite-F-zs 36 -27.774 0.0000E+00 spinel 161 20.870 0.0000E+00 apatite-Cl-zs 37 -16.674 0.0000E+00 spurrite 162 59.482 0.0000E+00 aragonite 38 0.967 0.0000E+00 staurolite-Fe 163 73.598 0.0000E+00 brucite 39 12.569 0.0000E+00 staurolite-Mg 164 89.802 0.0000E+00 calcite 40 0.812 0.0000E+00 staurolite-Mn 165 83.909 0.0000E+00 carnegieite-low 41 9.023 0.0000E+00 stilbite 166 -7.522 0.0000E+00 carnegieite-high 42 10.093 0.0000E+00 stilpnomelane-Fe 167 13.017 0.0000E+00 carpholite-Mg 43 8.582 0.0000E+00 stilpnomelane-Mg 168 27.441 0.0000E+00 carpholite-Fe 44 6.713 0.0000E+00 stishovite 169 2.720 0.0000E+00 celadonite 45 5.342 0.0000E+00 sudoite-Fe 170 18.296 0.0000E+00 celadonite-Fe 46 3.877 0.0000E+00 sudoite 171 21.077 0.0000E+00 chrysotile 47 23.892 0.0000E+00 sulfur 172 -9.152 0.0000E+00 chondrodite 48 56.475 0.0000E+00 sylvite 173 1.338 0.0000E+00 clinochlore 49 39.070 0.0000E+00 talc 174 16.491 0.0000E+00 daphnite 50 28.965 0.0000E+00 talc-Fe 175 13.448 0.0000E+00 chlorite-Mn 51 46.869 0.0000E+00 talc-tschermaks 176 19.091 0.0000E+00 chlorite-Al-free 52 47.173 0.0000E+00 tephroite 177 18.086 0.0000E+00 chloritoid-Mg 53 13.198 0.0000E+00 tilleyite 178 41.377 0.0000E+00 chloritoid-Fe 54 9.174 0.0000E+00 titanite-CaSi 179 15.479 0.0000E+00 chloritoid-Mn 55 11.401 0.0000E+00 topaz-H 180 4.618 0.0000E+00 clinohumite 56 97.128 0.0000E+00 tridymite 181 -2.626 0.0000E+00 coesite 57 -2.376 0.0000E+00 tremolite 182 47.869 0.0000E+00 cordierite-H 58 23.715 0.0000E+00 ferroactinolite 183 38.452 0.0000E+00 cordierite 59 24.049 0.0000E+00 troilite-low 184 -4.411 0.0000E+00 cordierite-Fe 60 20.450 0.0000E+00 tschermakite 185 48.210 0.0000E+00 cordierite-Mn 61 25.066 0.0000E+00 vesuvianite 186 223.471 0.0000E+00 corundum 62 8.383 0.0000E+00 wadeite-Si 187 20.216 0.0000E+00 corundum-MgSi 63 18.891 0.0000E+00 wadsleyite-Fe 188 15.680 0.0000E+00 cristobalite 64 -2.560 0.0000E+00 wadsleyite-Mg 189 25.850 0.0000E+00 cummingtonite 65 52.099 0.0000E+00 wairakite 190 3.950 0.0000E+00 cymrite-K 66 1.685 0.0000E+00 walstromite 191 11.509 0.0000E+00 deerite 67 95.671 0.0000E+00 wollastonite 192 10.461 0.0000E+00 diaspore 68 2.874 0.0000E+00 pseudo-wollastonite 193 11.000 0.0000E+00 diamond 69 -3.102 0.0000E+00 zoisite 194 22.849 0.0000E+00 diopside 70 16.181 0.0000E+00 akaganeite 195 7.755 0.0000E+00 hedenbergite 71 14.208 0.0000E+00 beidellite-Ca 196 -1.646 0.0000E+00 dolomite,ordered 72 0.546 0.0000E+00 beidellite-H 197 -2.326 0.0000E+00 eastonite 73 28.489 0.0000E+00 beidellite-K 198 -1.520 0.0000E+00 enstatite 74 17.265 0.0000E+00 beidellite-Mg 199 -1.790 0.0000E+00 clinoenstatite-HiP 75 18.354 0.0000E+00 beidellite-Na 200 -1.342 0.0000E+00 clinoenstatite 76 17.166 0.0000E+00 calcium 201 84.026 0.0000E+00 protoenstatite 77 17.824 0.0000E+00 chalcedony 202 -2.802 0.0000E+00 epidote 78 24.670 0.0000E+00 dawsonite 203 1.682 0.0000E+00 clinozoisite 79 22.806 0.0000E+00 montmorillonite-Ca 204 -2.291 0.0000E+00 epidote-Fe 80 29.841 0.0000E+00 montmorillonite-K 205 -2.237 0.0000E+00 fayalite 81 14.046 0.0000E+00 montmorillonite-Mg 206 -2.480 0.0000E+00 ferrosilite 82 11.149 0.0000E+00 montmorillonite-Na 207 -2.038 0.0000E+00 forsterite 83 21.016 0.0000E+00 nontronite-Ca 208 3.215 0.0000E+00 gedrite 84 50.522 0.0000E+00 nontronite-H 209 2.533 0.0000E+00 gehlenite 85 36.628 0.0000E+00 nontronite-K 210 3.341 0.0000E+00 gibbsite 86 4.079 0.0000E+00 nontronite-Mg 211 3.075 0.0000E+00 glaucophane 87 22.975 0.0000E+00 nontronite-Na 212 3.520 0.0000E+00 glaucophane-Fe 88 17.276 0.0000E+00 sepiolite 213 24.118 0.0000E+00 graphite 89 -3.546 0.0000E+00 topaz 214 -16.546 0.0000E+00 greenalite 90 16.140 0.0000E+00 alite 215 57.999 0.0000E+00 grunerite 91 31.215 0.0000E+00 belite 216 30.433 0.0000E+00 halite 92 1.575 0.0000E+00 ettringite 217 43.232 0.0000E+00 hematite 93 12.566 0.0000E+00 gypsum 218 -4.955 0.0000E+00 heulandite 94 -5.827 0.0000E+00 hemicarboaluminate 219 70.954 0.0000E+00 hercynite 95 17.279 0.0000E+00 hydrogarnet 220 60.662 0.0000E+00 hollandite 96 25.673 0.0000E+00 hydrogarnet-Si 221 50.586 0.0000E+00 iron 97 19.086 0.0000E+00 jennite 222 24.367 0.0000E+00 jadeite 98 4.215 0.0000E+00 monosulfoaluminate 223 53.400 0.0000E+00 julgoldite 99 70.427 0.0000E+00 monocarboaluminate 224 61.898 0.0000E+00 kalsilite 100 7.584 0.0000E+00 portlandite 225 18.272 0.0000E+00 kaolinite 101 -1.333 0.0000E+00 stratlingite 226 36.502 0.0000E+00 kyanite 102 4.876 0.0000E+00 tricarboaluminate 227 70.370 0.0000E+00 larnite-bredigite 103 30.686 0.0000E+00 tobermorite 228 9.823 0.0000E+00 laumontite 104 2.883 0.0000E+00 C4AH13 229 81.816 0.0000E+00 lawsonite 105 9.616 0.0000E+00 C2AH8 230 45.203 0.0000E+00 leucite 106 4.119 0.0000E+00 C3A 231 86.953 0.0000E+00 lime 107 25.998 0.0000E+00 C4AF 232 117.416 0.0000E+00 lizardite 108 23.244 0.0000E+00 CAH10 233 28.335 0.0000E+00 magnesite 109 0.691 0.0000E+00 alabandite 234 -0.978 0.0000E+00 magnetite 110 20.087 0.0000E+00 alunite 235 -10.435 0.0000E+00 minnesotaite 111 10.388 0.0000E+00 artinite 236 15.121 0.0000E+00 minnesotaite-Mg 112 20.602 0.0000E+00 boehmite 237 4.406 0.0000E+00 magnesioferrite 113 26.212 0.0000E+00 dolomite,disordered 238 1.247 0.0000E+00 majorite 114 53.251 0.0000E+00 ferrous-oxide 239 9.812 0.0000E+00 manganosite 115 14.058 0.0000E+00 fluorite 240 -9.931 0.0000E+00 margarite 116 17.324 0.0000E+00 huntite 241 3.770 0.0000E+00 meionite 117 44.874 0.0000E+00 hydromagnesite 242 19.995 0.0000E+00 merwinite 118 55.930 0.0000E+00 nesquehonite 243 4.723 0.0000E+00 microcline 119 -2.486 0.0000E+00 potassium-oxide 244 69.038 0.0000E+00 monticellite 120 24.339 0.0000E+00 silica-amorphous 245 -2.091 0.0000E+00 mullite-Al 121 363.148 0.0000E+00 sodium-oxide 246 55.169 0.0000E+00 mullite-Si 122 7.264 0.0000E+00 an20ab80 247 2.018 0.0000E+00 muscovite 123 2.582 0.0000E+00 an25ab75 248 2.646 0.0000E+00 paragonite 124 4.239 0.0000E+00 an30ab70 249 3.279 0.0000E+00 nepheline 125 8.339 0.0000E+00 tr.625ac.25prg.125 250 45.165 0.0000E+00 Initial composition of reactant (mole%): H2O 88.87 HCl 0.5900 CO2 7.070 CO 0.1600 H2 1.540 S2 0.8000E-01 SO2 1.150 HF 0.4000E-01 H2S 1.120 0.000 Sum of wt% of reactants: 100.6200 Reactant consumed: 0.0000000 moles log =-100.0000 Original solution: 1000.0103000 g Original solution / Rock added: 0.00 (Water/Rock Ratio), log = 0.0000 The following minerals and/or gases with identical index are in solid solution: H2O,gas 6 CO2,gas 6 CH4,gas 6 H2,gas 6 H2S,gas 6 S2,gas 6 CO,gas 6 SO3,gas 6 SO2,gas 6 HF,gas 6 HCl,gas 6 almandine 16 pyrope 16 spessartine 16 andradite 8 grossular 8 annite 15 phlogopite 15 biotite-Mn 15 clinochlore 1 daphnite 1 chlorite-Mn 1 diopside 5 hedenbergite 5 epidote 3 clinozoisite 3 iron 9 magnetite 14 talc 7 talc-Fe 7 tremolite 2 ferroactinolite 2 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 10 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 0.0000000 Water: Moles liquid = 0.4985E+02 kg liquid = 0.8981E+00 Moles total = 0.4985E+02 kg total = 0.8980E+00 Activity = 1.0000 Stoichiometric ionic strength = .1133023E-01 Osmotic coef. = 0.9694 True ionic strength = .2001761E-01 Chg. balance for total moles = -.5508E-08 Max. difference allowed = 0.1379E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.88292E-10 -10.0541 0.74188E-10 -10.1297 0.84025E+00 -0.0756 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.15283E-03 -3.8158 0.12765E-03 -3.8940 0.83520E+00 -0.0782 4 SO4-- 0.72063E-12 -12.1423 0.37423E-12 -12.4269 0.51931E+00 -0.2846 5 HCO3- 0.26668E-06 -6.5740 0.22305E-06 -6.6516 0.83642E+00 -0.0776 6 HS- 0.28394E-04 -4.5468 0.23718E-04 -4.6249 0.83532E+00 -0.0781 7 Al+++ 0.96916E-29 -29.0136 0.22391E-29 -29.6499 0.23104E+00 -0.6363 8 H4SiO4 0.69592E-03 -3.1574 0.69592E-03 -3.1574 0.10000E+01 0.0000 9 Ca++ 0.13499E-06 -6.8697 0.69585E-07 -7.1575 0.51550E+00 -0.2878 10 Mg++ 0.21118E-10 -10.6754 0.10836E-10 -10.9651 0.51314E+00 -0.2898 11 Fe++ 0.58202E-13 -13.2351 0.29899E-13 -13.5243 0.51370E+00 -0.2893 12 K+ 0.15651E-03 -3.8055 0.13094E-03 -3.8829 0.83662E+00 -0.0775 13 Na+ 0.19860E-01 -1.7020 0.16584E-01 -1.7803 0.83505E+00 -0.0783 14 Mn++ 0.18539E-10 -10.7319 0.95314E-11 -11.0208 0.51413E+00 -0.2889 15 F- 0.11099E-06 -6.9547 0.92510E-07 -7.0338 0.83348E+00 -0.0791 16 HPO4-- 0.45315E-07 -7.3438 0.23536E-07 -7.6283 0.51939E+00 -0.2845 18 HSiO3- 0.10487E-01 -1.9793 0.87590E-02 -2.0575 0.83520E+00 -0.0782 19 Ca(HSiO3)+ 0.16588E-07 -7.7802 0.13880E-07 -7.8576 0.83680E+00 -0.0774 20 Mg(HSiO3)+ 0.32148E-11 -11.4928 0.26901E-11 -11.5702 0.83680E+00 -0.0774 21 NaHSiO3,aq 0.23494E-02 -2.6290 0.23494E-02 -2.6290 0.10000E+01 0.0000 22 AlO+ 0.66140E-16 -16.1795 0.55346E-16 -16.2569 0.83680E+00 -0.0774 24 HAlO2,aq 0.14857E-09 -9.8281 0.14857E-09 -9.8281 0.10000E+01 0.0000 25 AlO2- 0.53173E-05 -5.2743 0.44330E-05 -5.3533 0.83369E+00 -0.0790 26 CH4,aq 0.13780E-04 -4.8608 0.13732E-04 -4.8623 0.99654E+00 -0.0015 27 C2H6,aq 0.27925E-14 -14.5540 0.27828E-14 -14.5555 0.99654E+00 -0.0015 31 CO,aq 0.10290E-16 -16.9876 0.10290E-16 -16.9876 0.10000E+01 0.0000 32 CO2,aq 0.35482E-10 -10.4500 0.35359E-10 -10.4515 0.99654E+00 -0.0015 33 CO3-2 0.50678E-06 -6.2952 0.26262E-06 -6.5807 0.51821E+00 -0.2855 34 CaCO3,aq 0.22914E-09 -9.6399 0.22914E-09 -9.6399 0.10000E+01 0.0000 35 Ca(HCO3)+ 0.47347E-12 -12.3247 0.39620E-12 -12.4021 0.83680E+00 -0.0774 36 CaCl+ 0.17178E-10 -10.7650 0.14374E-10 -10.8424 0.83680E+00 -0.0774 37 CaCl2,aq 0.43592E-15 -15.3606 0.43592E-15 -15.3606 0.10000E+01 0.0000 38 CaF+ 0.11232E-12 -12.9496 0.93985E-13 -13.0269 0.83680E+00 -0.0774 39 CaOH+ 0.79885E-07 -7.0975 0.66848E-07 -7.1749 0.83680E+00 -0.0774 40 CaSO4,aq 0.82692E-17 -17.0825 0.82692E-17 -17.0825 0.10000E+01 0.0000 41 HCl,aq 0.17353E-14 -14.7606 0.17353E-14 -14.7606 0.10000E+01 0.0000 45 HF,aq 0.46983E-13 -13.3281 0.46983E-13 -13.3281 0.10000E+01 0.0000 48 FeCl+ 0.72191E-17 -17.1415 0.60409E-17 -17.2189 0.83680E+00 -0.0774 51 FeF+ 0.16891E-18 -18.7723 0.14134E-18 -18.8497 0.83680E+00 -0.0774 53 FeO,aq 0.21113E-09 -9.6754 0.21113E-09 -9.6754 0.10000E+01 0.0000 54 FeOH+ 0.15677E-10 -10.8047 0.13119E-10 -10.8821 0.83680E+00 -0.0774 55 HFeO2- 0.35653E-07 -7.4479 0.29777E-07 -7.5261 0.83520E+00 -0.0782 56 FeO+ 0.10986E-16 -16.9592 0.91933E-17 -17.0365 0.83680E+00 -0.0774 58 FeO2- 0.40923E-09 -9.3880 0.34179E-09 -9.4662 0.83520E+00 -0.0782 59 HFeO2,aq 0.32249E-11 -11.4915 0.32249E-11 -11.4915 0.10000E+01 0.0000 60 H2,aq 0.11625E-04 -4.9346 0.11585E-04 -4.9361 0.99654E+00 -0.0015 61 KCl,aq 0.30293E-09 -9.5187 0.30293E-09 -9.5187 0.10000E+01 0.0000 63 KOH,aq 0.75373E-06 -6.1228 0.75373E-06 -6.1228 0.10000E+01 0.0000 64 KSO4- 0.91041E-15 -15.0408 0.76037E-15 -15.1190 0.83520E+00 -0.0782 65 MgCO3,aq 0.89443E-14 -14.0485 0.89443E-14 -14.0485 0.10000E+01 0.0000 66 Mg(HCO3)+ 0.75341E-16 -16.1230 0.63045E-16 -16.2003 0.83680E+00 -0.0774 67 MgCl+ 0.24245E-14 -14.6154 0.20289E-14 -14.6927 0.83680E+00 -0.0774 68 MgF+ 0.64791E-16 -16.1885 0.54217E-16 -16.2659 0.83680E+00 -0.0774 69 MgOH+ 0.68839E-10 -10.1622 0.57604E-10 -10.2395 0.83680E+00 -0.0774 71 MnF+ 0.17748E-16 -16.7508 0.14852E-16 -16.8282 0.83680E+00 -0.0774 72 MnO,aq 0.17934E-08 -8.7463 0.17934E-08 -8.7463 0.10000E+01 0.0000 73 MnOH+ 0.46427E-09 -9.3332 0.38850E-09 -9.4106 0.83680E+00 -0.0774 74 MnO2-2 0.20868E-10 -10.6805 0.10814E-10 -10.9660 0.51821E+00 -0.2855 75 HMnO2- 0.21045E-09 -9.6769 0.17577E-09 -9.7551 0.83520E+00 -0.0782 78 MnCl+ 0.89533E-14 -14.0480 0.74922E-14 -14.1254 0.83680E+00 -0.0774 80 NaCl,aq 0.70155E-06 -6.1539 0.70155E-06 -6.1539 0.10000E+01 0.0000 81 NaF,aq 0.35918E-09 -9.4447 0.35918E-09 -9.4447 0.10000E+01 0.0000 82 NaOH,aq 0.96045E-04 -4.0175 0.96045E-04 -4.0175 0.10000E+01 0.0000 84 OH- 0.93416E-02 -2.0296 0.77880E-02 -2.1086 0.83369E+00 -0.0790 89 HPO3-2 0.16397E-14 -14.7852 0.84970E-15 -15.0707 0.51821E+00 -0.2855 91 H2PO3- 0.15135E-18 -18.8200 0.12641E-18 -18.8982 0.83520E+00 -0.0782 92 H3PO4,aq 0.90599E-18 -18.0429 0.90599E-18 -18.0429 0.10000E+01 0.0000 93 H2PO4- 0.38530E-10 -10.4142 0.32211E-10 -10.4920 0.83599E+00 -0.0778 94 PO4-3 0.10667E-08 -8.9720 0.25884E-09 -9.5870 0.24266E+00 -0.6150 98 HP2O7-3 0.94679E-18 -18.0237 0.21896E-18 -18.6596 0.23127E+00 -0.6359 99 P2O7-4 0.91439E-17 -17.0389 0.70509E-18 -18.1518 0.77111E-01 -1.1129 100 H2S,aq 0.54571E-08 -8.2630 0.54383E-08 -8.2645 0.99654E+00 -0.0015 101 S2-2 0.20764E-14 -14.6827 0.10760E-14 -14.9682 0.51821E+00 -0.2855 107 SO3-2 0.10717E-17 -17.9699 0.56338E-18 -18.2492 0.52570E+00 -0.2793 109 HSO4- 0.31943E-19 -19.4956 0.26756E-19 -19.5726 0.83761E+00 -0.0770 Charge balance for all species = -.6133E-08 Solid products produced: Mass = 0.000000 g Volume = 0.000000 cm3 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.0000000 moles log =-100.0000 Original solution: 1000.0103000 g Original solution / Rock added: 0.00 (Water/Rock Ratio), log = 0.0000 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0560 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9667E+00 0.9855 0.1006E+01 0.1021E+01 CO2,gas 0.3558E-08 1.0069 0.3783E-08 0.3757E-08 CH4,gas 0.1891E-01 1.0124 0.2021E-01 0.1996E-01 H2,gas 0.1440E-01 1.0006 0.1521E-01 0.1520E-01 H2S,gas 0.1422E-06 0.9959 0.1495E-06 0.1501E-06 S2,gas 0.3434E-29 1.0000 0.3626E-29 0.3626E-29 CO,gas 0.1452E-13 1.0000 0.1533E-13 0.1533E-13 SO3,gas 0.7375E-48 1.0000 0.7788E-48 0.7788E-48 SO2,gas 0.4364E-27 1.0000 0.4608E-27 0.4608E-27 HF,gas 0.1092E-15 1.0000 0.1154E-15 0.1154E-15 HCl,gas 0.2900E-17 1.0000 0.3062E-17 0.3062E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -16.78 -10.12 -3.374 0.17282E+05 -8.422 3 CH4,gas 4.54 1.15 -3.39 -0.848 0.57940E+04 -1.694 4 H2,gas 8.00 4.48 -3.52 -2.010 0.60049E+04 -1.818 5 H2S,gas -6.23 -14.75 -8.52 -4.262 0.14555E+05 -6.825 6 S2,gas -7.34 -38.47 -31.14 -4.791 0.53170E+05 -29.441 7 CO,gas 3.21 -12.30 -15.51 -4.773 0.26489E+05 -13.814 8 SO3,gas 17.12 -32.69 -49.81 -12.452 0.85045E+05 -48.109 9 SO2,gas 0.83 -28.20 -29.04 -7.743 0.49577E+05 -27.336 10 HF,gas 0.47 -17.16 -17.64 -8.818 0.30115E+05 -15.938 11 HCl,gas 5.19 -14.02 -19.21 -9.606 0.32806E+05 -17.514 12 acmite 7.71 6.53 -1.18 -0.123 0.20177E+04 16 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 17 albite -0.38 -0.38 0.00 0.000 0.19812E-01 20 spessartine 24.46 19.72 -4.74 -0.237 0.80866E+04 21 analcite 3.32 2.77 -0.55 -0.061 0.93621E+03 23 andradite 39.01 38.82 -0.19 -0.010 0.32175E+03 24 grossular 32.73 31.31 -1.42 -0.071 0.24247E+04 27 annite 20.12 17.72 -2.40 -0.134 0.41064E+04 28 phlogopite 27.06 25.40 -1.67 -0.093 0.28488E+04 30 anorthite 12.71 8.27 -4.45 -0.342 0.75900E+04 33 apatite-OH -18.15 -18.15 0.00 0.000 0.95485E-01 34 apatite-F -34.30 -35.32 -1.02 -0.085 0.17349E+04 38 aragonite 0.97 -3.68 -4.65 -1.549 0.79328E+04 39 brucite 12.57 9.29 -3.27 -0.655 0.55909E+04 40 calcite 0.81 -3.68 -4.49 -1.497 0.76686E+04 41 carnegieite-low 9.02 5.93 -3.09 -0.442 0.52800E+04 42 carnegieite-high 10.09 5.93 -4.16 -0.595 0.71070E+04 43 carpholite-Mg 8.58 4.46 -4.12 -0.275 0.70426E+04 44 carpholite-Fe 6.71 1.90 -4.81 -0.321 0.82204E+04 45 celadonite 5.34 3.65 -1.69 -0.099 0.28879E+04 46 celadonite-Fe 3.88 1.09 -2.79 -0.164 0.47561E+04 47 chrysotile 23.89 21.57 -2.32 -0.194 0.39692E+04 49 clinochlore 39.07 38.48 -0.59 -0.019 0.10118E+04 50 daphnite 28.97 25.68 -3.28 -0.103 0.56081E+04 52 chlorite-Al-free 47.17 43.14 -4.04 -0.168 0.68936E+04 54 chloritoid-Fe 9.17 5.06 -4.12 -0.275 0.70312E+04 55 chloritoid-Mn 11.40 7.56 -3.84 -0.256 0.65599E+04 57 coesite -2.38 -3.16 -0.78 -0.260 0.13342E+04 64 cristobalite -2.56 -3.16 -0.60 -0.199 0.10195E+04 66 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71234E+04 68 diaspore 2.87 0.74 -2.13 -0.356 0.36448E+04 69 diamond -3.10 -7.82 -4.71 -1.347 0.80474E+04 70 diopside 16.18 16.08 -0.10 -0.010 0.17103E+03 71 hedenbergite 14.21 13.52 -0.69 -0.069 0.11719E+04 74 enstatite 17.26 12.27 -4.99 -0.499 0.85226E+04 76 clinoenstatite 17.17 12.27 -4.89 -0.489 0.83542E+04 78 epidote 24.67 22.70 -1.97 -0.095 0.33583E+04 79 clinozoisite 22.81 18.95 -3.86 -0.175 0.65864E+04 80 epidote-Fe 29.84 26.46 -3.38 -0.176 0.57768E+04 81 fayalite 14.05 10.31 -3.73 -0.533 0.63743E+04 82 ferrosilite 11.15 7.16 -3.99 -0.399 0.68202E+04 86 gibbsite 4.08 0.74 -3.34 -0.477 0.57033E+04 87 glaucophane 22.97 20.80 -2.17 -0.059 0.37134E+04 88 glaucophane-Fe 17.28 13.12 -4.15 -0.112 0.70920E+04 89 graphite -3.55 -7.82 -4.27 -1.220 0.72897E+04 90 greenalite 16.14 13.89 -2.25 -0.187 0.38408E+04 93 hematite 12.57 8.99 -3.58 -0.434 0.61112E+04 94 heulandite -5.83 -7.52 -1.69 -0.077 0.28939E+04 98 jadeite 4.22 2.77 -1.44 -0.144 0.24617E+04 100 kalsilite 7.58 3.83 -3.76 -0.537 0.64125E+04 101 kaolinite -1.33 -4.84 -3.50 -0.319 0.59829E+04 104 laumontite 2.88 1.95 -0.93 -0.062 0.15933E+04 105 lawsonite 9.62 8.27 -1.35 -0.090 0.23067E+04 106 leucite 4.12 0.67 -3.45 -0.345 0.58872E+04 108 lizardite 23.24 21.57 -1.68 -0.140 0.28618E+04 110 magnetite 20.09 15.72 -4.37 -0.356 0.74537E+04 111 minnesotaite 10.39 7.58 -2.81 -0.165 0.48029E+04 115 manganosite 14.06 9.24 -4.82 -1.205 0.82294E+04 119 microcline -2.49 -2.49 0.00 0.000 0.20962E-01 123 muscovite 2.58 -1.01 -3.59 -0.211 0.61312E+04 124 paragonite 4.24 1.09 -3.15 -0.185 0.53703E+04 125 nepheline 8.34 5.93 -2.41 -0.344 0.41124E+04 131 periclase-Fe 11.63 6.73 -4.89 -1.223 0.83523E+04 137 phlogopite-Na 29.65 27.50 -2.15 -0.119 0.36676E+04 139 prehnite 19.37 18.21 -1.16 -0.068 0.19847E+04 140 prehnite-Fe 22.50 21.96 -0.53 -0.032 0.91155E+03 141 pumpellyite-Fe 46.27 43.89 -2.38 -0.053 0.40574E+04 142 pumpellyite-Mg 48.99 46.45 -2.54 -0.056 0.43412E+04 146 pyrrhotite -4.26 -8.02 -3.76 -1.253 0.64189E+04 147 pyrrhotiteFe0.875 -6.02 -9.42 -3.40 -1.251 0.58061E+04 148 pyroxmangite 7.40 6.08 -1.32 -0.264 0.22498E+04 149 pyrophyllite -6.18 -11.15 -4.98 -0.311 0.84960E+04 150 quartz -2.99 -3.16 -0.17 -0.056 0.28686E+03 155 rhodonite 7.45 6.08 -1.36 -0.273 0.23301E+04 156 sanidine -1.28 -2.49 -1.21 -0.093 0.20678E+04 166 stilbite -7.52 -7.52 0.00 0.000 0.25764E-01 167 stilpnomelane-Fe 13.02 13.02 0.00 0.000 0.13752E-01 168 stilpnomelane-Mg 27.44 25.81 -1.63 -0.049 0.27803E+04 174 talc 16.49 15.25 -1.24 -0.073 0.21141E+04 177 tephroite 18.09 15.32 -2.77 -0.395 0.47233E+04 181 tridymite -2.63 -3.16 -0.53 -0.177 0.90684E+03 182 tremolite 47.87 47.42 -0.45 -0.012 0.77514E+03 183 ferroactinolite 38.45 34.62 -3.83 -0.104 0.65451E+04 184 troilite-low -4.41 -8.02 -3.61 -1.203 0.61617E+04 186 vesuvianite 223.47 218.82 -4.65 -0.036 0.79421E+04 190 wairakite 3.95 1.95 -2.00 -0.118 0.34153E+04 191 walstromite 11.51 9.94 -1.56 -0.313 0.26719E+04 192 wollastonite 10.46 9.94 -0.52 -0.103 0.88231E+03 193 pseudo-wollastonite 11.00 9.94 -1.06 -0.211 0.18021E+04 194 zoisite 22.85 18.95 -3.90 -0.177 0.66605E+04 195 akaganeite 7.75 4.49 -3.26 -0.705 0.55681E+04 202 chalcedony -2.80 -3.16 -0.36 -0.118 0.60616E+03 204 montmorillonite-Ca -2.29 -6.17 -3.88 -0.240 0.66180E+04 205 montmorillonite-K -2.24 -6.27 -4.03 -0.247 0.68816E+04 206 montmorillonite-Mg -2.48 -6.79 -4.31 -0.267 0.73677E+04 207 montmorillonite-Na -2.04 -5.57 -3.54 -0.216 0.60365E+04 208 nontronite-Ca 3.21 -0.20 -3.41 -0.221 0.58217E+04 209 nontronite-H 2.53 -2.36 -4.89 -0.328 0.83487E+04 210 nontronite-K 3.34 -0.30 -3.64 -0.233 0.62086E+04 211 nontronite-Mg 3.07 -0.82 -3.90 -0.253 0.66556E+04 212 nontronite-Na 3.52 0.40 -3.12 -0.200 0.53294E+04 228 tobermorite 9.82 7.76 -2.07 -0.564 0.35287E+04 234 alabandite -0.98 -5.52 -4.54 -1.513 0.77489E+04 237 boehmite 4.41 0.74 -3.67 -0.611 0.62617E+04 239 ferrous-oxide 9.81 6.73 -3.08 -0.769 0.52532E+04 245 silica-amorphous -2.09 -3.16 -1.07 -0.355 0.18203E+04 247 an20ab80 2.02 1.35 -0.67 -0.052 0.11472E+04 248 an25ab75 2.65 1.78 -0.87 -0.067 0.14809E+04 249 an30ab70 3.28 2.21 -1.07 -0.082 0.18243E+04 250 tr.625ac.25prg.125 45.16 45.16 0.00 0.000 0.14362E+00 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 0.0000100 MOLES Current total amount of reactant added: 0.0000000 MOLES New total amount of reactant added: 0.0000100 MOLES Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.5508E-08 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 7 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 0.0000100 Water: Moles liquid = 0.4985E+02 kg liquid = 0.8981E+00 Moles total = 0.4985E+02 kg total = 0.8980E+00 Activity = 1.0000 Stoichiometric ionic strength = .1133088E-01 Osmotic coef. = 0.9693 True ionic strength = .2001797E-01 Chg. balance for total moles = -.5508E-08 Max. difference allowed = 0.1379E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.88303E-10 -10.0540 0.74197E-10 -10.1296 0.84025E+00 -0.0756 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.15290E-03 -3.8156 0.12770E-03 -3.8938 0.83520E+00 -0.0782 4 SO4-- 0.11923E-11 -11.9236 0.61920E-12 -12.2082 0.51931E+00 -0.2846 5 HCO3- 0.44610E-06 -6.3506 0.37313E-06 -6.4281 0.83642E+00 -0.0776 6 HS- 0.28665E-04 -4.5427 0.23944E-04 -4.6208 0.83532E+00 -0.0781 7 Al+++ 0.96964E-29 -29.0134 0.22402E-29 -29.6497 0.23103E+00 -0.6363 8 H4SiO4 0.69600E-03 -3.1574 0.69600E-03 -3.1574 0.10000E+01 0.0000 9 Ca++ 0.13490E-06 -6.8700 0.69541E-07 -7.1578 0.51550E+00 -0.2878 10 Mg++ 0.21118E-10 -10.6753 0.10837E-10 -10.9651 0.51314E+00 -0.2898 11 Fe++ 0.58182E-13 -13.2352 0.29888E-13 -13.5245 0.51370E+00 -0.2893 12 K+ 0.15651E-03 -3.8055 0.13094E-03 -3.8829 0.83662E+00 -0.0775 13 Na+ 0.19860E-01 -1.7020 0.16584E-01 -1.7803 0.83505E+00 -0.0783 14 Mn++ 0.18543E-10 -10.7318 0.95336E-11 -11.0207 0.51413E+00 -0.2889 15 F- 0.11543E-06 -6.9377 0.96210E-07 -7.0168 0.83348E+00 -0.0791 16 HPO4-- 0.45315E-07 -7.3438 0.23536E-07 -7.6283 0.51938E+00 -0.2845 18 HSiO3- 0.10487E-01 -1.9793 0.87589E-02 -2.0575 0.83520E+00 -0.0782 19 Ca(HSiO3)+ 0.16577E-07 -7.7805 0.13872E-07 -7.8579 0.83680E+00 -0.0774 20 Mg(HSiO3)+ 0.32148E-11 -11.4928 0.26902E-11 -11.5702 0.83680E+00 -0.0774 21 NaHSiO3,aq 0.23494E-02 -2.6290 0.23494E-02 -2.6290 0.10000E+01 0.0000 22 AlO+ 0.66156E-16 -16.1794 0.55360E-16 -16.2568 0.83680E+00 -0.0774 24 HAlO2,aq 0.14859E-09 -9.8280 0.14859E-09 -9.8280 0.10000E+01 0.0000 25 AlO2- 0.53173E-05 -5.2743 0.44330E-05 -5.3533 0.83369E+00 -0.0790 26 CH4,aq 0.14065E-04 -4.8519 0.14016E-04 -4.8534 0.99654E+00 -0.0015 27 C2H6,aq 0.32916E-14 -14.4826 0.32802E-14 -14.4841 0.99654E+00 -0.0015 31 CO,aq 0.15215E-16 -16.8177 0.15215E-16 -16.8177 0.10000E+01 0.0000 32 CO2,aq 0.59362E-10 -10.2265 0.59156E-10 -10.2280 0.99654E+00 -0.0015 33 CO3-2 0.84765E-06 -6.0718 0.43926E-06 -6.3573 0.51821E+00 -0.2855 34 CaCO3,aq 0.38302E-09 -9.4168 0.38302E-09 -9.4168 0.10000E+01 0.0000 35 Ca(HCO3)+ 0.79153E-12 -12.1015 0.66235E-12 -12.1789 0.83680E+00 -0.0774 36 CaCl+ 0.17174E-10 -10.7651 0.14372E-10 -10.8425 0.83680E+00 -0.0774 37 CaCl2,aq 0.43602E-15 -15.3605 0.43602E-15 -15.3605 0.10000E+01 0.0000 38 CaF+ 0.11673E-12 -12.9328 0.97683E-13 -13.0102 0.83680E+00 -0.0774 39 CaOH+ 0.79825E-07 -7.0979 0.66798E-07 -7.1752 0.83680E+00 -0.0774 40 CaSO4,aq 0.13674E-16 -16.8641 0.13674E-16 -16.8641 0.10000E+01 0.0000 41 HCl,aq 0.17363E-14 -14.7604 0.17363E-14 -14.7604 0.10000E+01 0.0000 45 HF,aq 0.48868E-13 -13.3110 0.48868E-13 -13.3110 0.10000E+01 0.0000 48 FeCl+ 0.72195E-17 -17.1415 0.60413E-17 -17.2189 0.83680E+00 -0.0774 51 FeF+ 0.17560E-18 -18.7555 0.14694E-18 -18.8328 0.83680E+00 -0.0774 53 FeO,aq 0.21100E-09 -9.6757 0.21100E-09 -9.6757 0.10000E+01 0.0000 54 FeOH+ 0.15670E-10 -10.8049 0.13112E-10 -10.8823 0.83680E+00 -0.0774 55 HFeO2- 0.35627E-07 -7.4482 0.29756E-07 -7.5264 0.83520E+00 -0.0782 56 FeO+ 0.11681E-16 -16.9325 0.97743E-17 -17.0099 0.83680E+00 -0.0774 58 FeO2- 0.43499E-09 -9.3615 0.36330E-09 -9.4397 0.83520E+00 -0.0782 59 HFeO2,aq 0.34284E-11 -11.4649 0.34284E-11 -11.4649 0.10000E+01 0.0000 60 H2,aq 0.10274E-04 -4.9883 0.10238E-04 -4.9898 0.99654E+00 -0.0015 61 KCl,aq 0.30305E-09 -9.5185 0.30305E-09 -9.5185 0.10000E+01 0.0000 63 KOH,aq 0.75364E-06 -6.1228 0.75364E-06 -6.1228 0.10000E+01 0.0000 64 KSO4- 0.15064E-14 -14.8221 0.12581E-14 -14.9003 0.83520E+00 -0.0782 65 MgCO3,aq 0.14961E-13 -13.8250 0.14961E-13 -13.8250 0.10000E+01 0.0000 66 Mg(HCO3)+ 0.12603E-15 -15.8995 0.10547E-15 -15.9769 0.83680E+00 -0.0774 67 MgCl+ 0.24256E-14 -14.6152 0.20298E-14 -14.6926 0.83680E+00 -0.0774 68 MgF+ 0.67384E-16 -16.1714 0.56387E-16 -16.2488 0.83680E+00 -0.0774 69 MgOH+ 0.68832E-10 -10.1622 0.57599E-10 -10.2396 0.83680E+00 -0.0774 71 MnF+ 0.18463E-16 -16.7337 0.15449E-16 -16.8111 0.83680E+00 -0.0774 72 MnO,aq 0.17934E-08 -8.7463 0.17934E-08 -8.7463 0.10000E+01 0.0000 73 MnOH+ 0.46432E-09 -9.3332 0.38854E-09 -9.4106 0.83680E+00 -0.0774 74 MnO2-2 0.20863E-10 -10.6806 0.10811E-10 -10.9661 0.51821E+00 -0.2855 75 HMnO2- 0.21042E-09 -9.6769 0.17574E-09 -9.7551 0.83520E+00 -0.0782 78 MnCl+ 0.89592E-14 -14.0477 0.74971E-14 -14.1251 0.83680E+00 -0.0774 80 NaCl,aq 0.70185E-06 -6.1538 0.70185E-06 -6.1538 0.10000E+01 0.0000 81 NaF,aq 0.37355E-09 -9.4277 0.37355E-09 -9.4277 0.10000E+01 0.0000 82 NaOH,aq 0.96033E-04 -4.0176 0.96033E-04 -4.0176 0.10000E+01 0.0000 84 OH- 0.93404E-02 -2.0296 0.77871E-02 -2.1086 0.83369E+00 -0.0790 89 HPO3-2 0.14491E-14 -14.8389 0.75095E-15 -15.1244 0.51821E+00 -0.2855 91 H2PO3- 0.13378E-18 -18.8736 0.11173E-18 -18.9518 0.83520E+00 -0.0782 92 H3PO4,aq 0.90620E-18 -18.0428 0.90620E-18 -18.0428 0.10000E+01 0.0000 93 H2PO4- 0.38534E-10 -10.4142 0.32214E-10 -10.4919 0.83599E+00 -0.0778 94 PO4-3 0.10666E-08 -8.9720 0.25881E-09 -9.5870 0.24265E+00 -0.6150 98 HP2O7-3 0.94690E-18 -18.0237 0.21899E-18 -18.6596 0.23127E+00 -0.6359 99 P2O7-4 0.91440E-17 -17.0389 0.70509E-18 -18.1518 0.77109E-01 -1.1129 100 H2S,aq 0.55098E-08 -8.2589 0.54908E-08 -8.2604 0.99654E+00 -0.0015 101 S2-2 0.23944E-14 -14.6208 0.12408E-14 -14.9063 0.51821E+00 -0.2855 107 SO3-2 0.15671E-17 -17.8049 0.82382E-18 -18.0842 0.52570E+00 -0.2793 109 HSO4- 0.52859E-19 -19.2769 0.44276E-19 -19.3538 0.83761E+00 -0.0770 Charge balance for all species = -.6133E-08 Solid products produced: Mass = 0.000000 g Volume = 0.000000 cm3 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.0000100 moles log = -5.0000 Original solution: 1000.0103000 g Original solution / Rock added: 100001030.00 (Water/Rock Ratio), log = 8.0000 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0546 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9679E+00 0.9855 0.1006E+01 0.1021E+01 CO2,gas 0.5960E-08 1.0069 0.6329E-08 0.6286E-08 CH4,gas 0.1932E-01 1.0124 0.2063E-01 0.2038E-01 H2,gas 0.1274E-01 1.0006 0.1344E-01 0.1343E-01 H2S,gas 0.1437E-06 0.9959 0.1509E-06 0.1516E-06 S2,gas 0.4488E-29 1.0000 0.4733E-29 0.4733E-29 CO,gas 0.2150E-13 1.0000 0.2267E-13 0.2267E-13 SO3,gas 0.1222E-47 1.0000 0.1289E-47 0.1289E-47 SO2,gas 0.6391E-27 1.0000 0.6740E-27 0.6740E-27 HF,gas 0.1138E-15 1.0000 0.1200E-15 0.1200E-15 HCl,gas 0.2905E-17 1.0000 0.3064E-17 0.3064E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 17 albite -0.38 -0.38 0.00 0.000 -0.23075E+00 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -16.56 -9.90 -3.299 0.16900E+05 -8.199 3 CH4,gas 4.54 1.16 -3.38 -0.846 0.57789E+04 -1.685 4 H2,gas 8.00 4.43 -3.57 -2.040 0.60966E+04 -1.872 5 H2S,gas -6.23 -14.75 -8.52 -4.260 0.14548E+05 -6.821 6 S2,gas -7.34 -38.36 -31.02 -4.773 0.52972E+05 -29.325 7 CO,gas 3.21 -12.13 -15.34 -4.721 0.26199E+05 -13.644 8 SO3,gas 17.12 -32.47 -49.59 -12.397 0.84671E+05 -47.890 9 SO2,gas 0.83 -28.04 -28.87 -7.699 0.49295E+05 -27.171 10 HF,gas 0.47 -17.15 -17.62 -8.810 0.30085E+05 -15.921 11 HCl,gas 5.19 -14.02 -19.21 -9.606 0.32805E+05 -17.514 12 acmite 7.71 6.55 -1.16 -0.120 0.19723E+04 16 albite-high 0.69 -0.38 -1.08 -0.083 0.18386E+04 20 spessartine 24.46 19.72 -4.74 -0.237 0.80862E+04 21 analcite 3.32 2.77 -0.55 -0.061 0.93604E+03 23 andradite 39.01 38.87 -0.14 -0.007 0.23271E+03 24 grossular 32.73 31.31 -1.42 -0.071 0.24262E+04 27 annite 20.12 17.72 -2.41 -0.134 0.41075E+04 28 phlogopite 27.06 25.40 -1.67 -0.093 0.28490E+04 30 anorthite 12.71 8.26 -4.45 -0.342 0.75903E+04 33 apatite-OH -18.15 -18.16 0.00 0.000 0.27859E+01 34 apatite-F -34.30 -35.30 -1.00 -0.083 0.17084E+04 38 aragonite 0.97 -3.46 -4.42 -1.474 0.75518E+04 39 brucite 12.57 9.29 -3.27 -0.655 0.55910E+04 40 calcite 0.81 -3.46 -4.27 -1.423 0.72876E+04 41 carnegieite-low 9.02 5.93 -3.09 -0.442 0.52799E+04 42 carnegieite-high 10.09 5.93 -4.16 -0.595 0.71069E+04 43 carpholite-Mg 8.58 4.46 -4.12 -0.275 0.70424E+04 44 carpholite-Fe 6.71 1.90 -4.81 -0.321 0.82205E+04 45 celadonite 5.34 3.65 -1.69 -0.099 0.28877E+04 46 celadonite-Fe 3.88 1.09 -2.79 -0.164 0.47562E+04 47 chrysotile 23.89 21.57 -2.32 -0.194 0.39695E+04 49 clinochlore 39.07 38.48 -0.59 -0.019 0.10122E+04 50 daphnite 28.97 25.68 -3.29 -0.103 0.56099E+04 52 chlorite-Al-free 47.17 43.14 -4.04 -0.168 0.68942E+04 54 chloritoid-Fe 9.17 5.06 -4.12 -0.275 0.70314E+04 55 chloritoid-Mn 11.40 7.56 -3.84 -0.256 0.65596E+04 57 coesite -2.38 -3.16 -0.78 -0.260 0.13341E+04 64 cristobalite -2.56 -3.16 -0.60 -0.199 0.10195E+04 66 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71232E+04 68 diaspore 2.87 0.74 -2.13 -0.356 0.36447E+04 69 diamond -3.10 -7.70 -4.60 -1.313 0.78490E+04 70 diopside 16.18 16.08 -0.10 -0.010 0.17167E+03 71 hedenbergite 14.21 13.52 -0.69 -0.069 0.11728E+04 74 enstatite 17.26 12.27 -4.99 -0.499 0.85227E+04 76 clinoenstatite 17.17 12.27 -4.89 -0.489 0.83543E+04 78 epidote 24.67 22.73 -1.94 -0.094 0.33138E+04 79 clinozoisite 22.81 18.95 -3.86 -0.175 0.65872E+04 80 epidote-Fe 29.84 26.51 -3.33 -0.173 0.56871E+04 81 fayalite 14.05 10.31 -3.73 -0.533 0.63751E+04 82 ferrosilite 11.15 7.15 -3.99 -0.399 0.68210E+04 86 gibbsite 4.08 0.74 -3.34 -0.477 0.57033E+04 87 glaucophane 22.97 20.80 -2.17 -0.059 0.37132E+04 88 glaucophane-Fe 17.28 13.12 -4.15 -0.112 0.70926E+04 89 graphite -3.55 -7.70 -4.15 -1.187 0.70913E+04 90 greenalite 16.14 13.89 -2.25 -0.188 0.38420E+04 93 hematite 12.57 9.04 -3.53 -0.427 0.60205E+04 94 heulandite -5.83 -7.52 -1.69 -0.077 0.28937E+04 98 jadeite 4.22 2.77 -1.44 -0.144 0.24615E+04 100 kalsilite 7.58 3.83 -3.76 -0.536 0.64124E+04 101 kaolinite -1.33 -4.84 -3.50 -0.319 0.59826E+04 104 laumontite 2.88 1.95 -0.93 -0.062 0.15935E+04 105 lawsonite 9.62 8.26 -1.35 -0.090 0.23070E+04 106 leucite 4.12 0.67 -3.45 -0.345 0.58871E+04 108 lizardite 23.24 21.57 -1.68 -0.140 0.28622E+04 110 magnetite 20.09 15.77 -4.31 -0.352 0.73634E+04 111 minnesotaite 10.39 7.57 -2.81 -0.165 0.48039E+04 115 manganosite 14.06 9.24 -4.82 -1.205 0.82294E+04 119 microcline -2.49 -2.49 0.00 0.000 -0.22901E+00 123 muscovite 2.58 -1.01 -3.59 -0.211 0.61307E+04 124 paragonite 4.24 1.09 -3.14 -0.185 0.53698E+04 125 nepheline 8.34 5.93 -2.41 -0.344 0.41123E+04 131 periclase-Fe 11.63 6.73 -4.89 -1.223 0.83527E+04 137 phlogopite-Na 29.65 27.50 -2.15 -0.119 0.36679E+04 139 prehnite 19.37 18.21 -1.16 -0.068 0.19855E+04 140 prehnite-Fe 22.50 21.99 -0.51 -0.031 0.86714E+03 141 pumpellyite-Fe 46.27 43.89 -2.38 -0.053 0.40595E+04 142 pumpellyite-Mg 48.99 46.45 -2.54 -0.057 0.43430E+04 146 pyrrhotite -4.26 -8.02 -3.76 -1.252 0.64122E+04 147 pyrrhotiteFe0.875 -6.02 -9.41 -3.39 -1.247 0.57880E+04 148 pyroxmangite 7.40 6.08 -1.32 -0.264 0.22497E+04 149 pyrophyllite -6.18 -11.15 -4.98 -0.311 0.84955E+04 150 quartz -2.99 -3.16 -0.17 -0.056 0.28678E+03 155 rhodonite 7.45 6.08 -1.36 -0.273 0.23300E+04 156 sanidine -1.28 -2.49 -1.21 -0.093 0.20675E+04 166 stilbite -7.52 -7.52 0.00 0.000 -0.93717E-01 167 stilpnomelane-Fe 13.02 13.02 0.00 0.000 0.14570E+01 168 stilpnomelane-Mg 27.44 25.81 -1.63 -0.049 0.27803E+04 174 talc 16.49 15.25 -1.24 -0.073 0.21143E+04 177 tephroite 18.09 15.32 -2.77 -0.395 0.47232E+04 181 tridymite -2.63 -3.16 -0.53 -0.177 0.90676E+03 182 tremolite 47.87 47.41 -0.45 -0.012 0.77657E+03 183 ferroactinolite 38.45 34.62 -3.83 -0.104 0.65480E+04 184 troilite-low -4.41 -8.02 -3.60 -1.202 0.61550E+04 186 vesuvianite 223.47 218.81 -4.66 -0.036 0.79522E+04 190 wairakite 3.95 1.95 -2.00 -0.118 0.34154E+04 191 walstromite 11.51 9.94 -1.57 -0.313 0.26724E+04 192 wollastonite 10.46 9.94 -0.52 -0.103 0.88287E+03 193 pseudo-wollastonite 11.00 9.94 -1.06 -0.211 0.18027E+04 194 zoisite 22.85 18.95 -3.90 -0.177 0.66612E+04 195 akaganeite 7.75 4.52 -3.23 -0.699 0.55228E+04 202 chalcedony -2.80 -3.16 -0.35 -0.118 0.60608E+03 204 montmorillonite-Ca -2.29 -6.17 -3.88 -0.240 0.66176E+04 205 montmorillonite-K -2.24 -6.27 -4.03 -0.247 0.68812E+04 206 montmorillonite-Mg -2.48 -6.79 -4.31 -0.267 0.73673E+04 207 montmorillonite-Na -2.04 -5.57 -3.54 -0.216 0.60361E+04 208 nontronite-Ca 3.21 -0.14 -3.36 -0.218 0.57308E+04 209 nontronite-H 2.53 -2.30 -4.84 -0.324 0.82577E+04 210 nontronite-K 3.34 -0.24 -3.58 -0.230 0.61175E+04 211 nontronite-Mg 3.07 -0.77 -3.84 -0.249 0.65645E+04 212 nontronite-Na 3.52 0.45 -3.07 -0.197 0.52384E+04 228 tobermorite 9.82 7.76 -2.07 -0.564 0.35292E+04 234 alabandite -0.98 -5.51 -4.53 -1.511 0.77418E+04 237 boehmite 4.41 0.74 -3.67 -0.611 0.62616E+04 239 ferrous-oxide 9.81 6.73 -3.08 -0.769 0.52536E+04 245 silica-amorphous -2.09 -3.16 -1.07 -0.355 0.18203E+04 247 an20ab80 2.02 1.35 -0.67 -0.052 0.11470E+04 248 an25ab75 2.65 1.78 -0.87 -0.067 0.14808E+04 249 an30ab70 3.28 2.21 -1.07 -0.082 0.18242E+04 250 tr.625ac.25prg.125 45.16 45.16 0.00 0.000 0.19102E+01 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 6 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 0.0000100 Water: Moles liquid = 0.4985E+02 kg liquid = 0.8981E+00 Moles total = 0.4985E+02 kg total = 0.8980E+00 Activity = 1.0000 Stoichiometric ionic strength = .1133088E-01 Osmotic coef. = 0.9693 True ionic strength = .2001797E-01 Chg. balance for total moles = -.5508E-08 Max. difference allowed = 0.1379E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.88303E-10 -10.0540 0.74197E-10 -10.1296 0.84025E+00 -0.0756 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.15290E-03 -3.8156 0.12770E-03 -3.8938 0.83520E+00 -0.0782 4 SO4-- 0.11923E-11 -11.9236 0.61920E-12 -12.2082 0.51931E+00 -0.2846 5 HCO3- 0.44610E-06 -6.3506 0.37313E-06 -6.4281 0.83642E+00 -0.0776 6 HS- 0.28665E-04 -4.5427 0.23944E-04 -4.6208 0.83532E+00 -0.0781 7 Al+++ 0.96933E-29 -29.0135 0.22395E-29 -29.6498 0.23103E+00 -0.6363 8 H4SiO4 0.69600E-03 -3.1574 0.69600E-03 -3.1574 0.10000E+01 0.0000 9 Ca++ 0.13490E-06 -6.8700 0.69541E-07 -7.1578 0.51550E+00 -0.2878 10 Mg++ 0.21118E-10 -10.6753 0.10837E-10 -10.9651 0.51314E+00 -0.2898 11 Fe++ 0.58181E-13 -13.2352 0.29888E-13 -13.5245 0.51370E+00 -0.2893 12 K+ 0.15651E-03 -3.8055 0.13094E-03 -3.8829 0.83662E+00 -0.0775 13 Na+ 0.19860E-01 -1.7020 0.16584E-01 -1.7803 0.83505E+00 -0.0783 14 Mn++ 0.18543E-10 -10.7318 0.95336E-11 -11.0207 0.51413E+00 -0.2889 15 F- 0.11543E-06 -6.9377 0.96210E-07 -7.0168 0.83348E+00 -0.0791 16 HPO4-- 0.45315E-07 -7.3438 0.23536E-07 -7.6283 0.51938E+00 -0.2845 18 HSiO3- 0.10487E-01 -1.9793 0.87589E-02 -2.0575 0.83520E+00 -0.0782 19 Ca(HSiO3)+ 0.16577E-07 -7.7805 0.13872E-07 -7.8579 0.83680E+00 -0.0774 20 Mg(HSiO3)+ 0.32148E-11 -11.4928 0.26902E-11 -11.5702 0.83680E+00 -0.0774 21 NaHSiO3,aq 0.23494E-02 -2.6290 0.23494E-02 -2.6290 0.10000E+01 0.0000 22 AlO+ 0.66136E-16 -16.1796 0.55342E-16 -16.2569 0.83680E+00 -0.0774 24 HAlO2,aq 0.14854E-09 -9.8282 0.14854E-09 -9.8282 0.10000E+01 0.0000 25 AlO2- 0.53157E-05 -5.2744 0.44316E-05 -5.3534 0.83369E+00 -0.0790 26 CH4,aq 0.14065E-04 -4.8519 0.14016E-04 -4.8534 0.99654E+00 -0.0015 27 C2H6,aq 0.32916E-14 -14.4826 0.32802E-14 -14.4841 0.99654E+00 -0.0015 31 CO,aq 0.15215E-16 -16.8177 0.15215E-16 -16.8177 0.10000E+01 0.0000 32 CO2,aq 0.59362E-10 -10.2265 0.59156E-10 -10.2280 0.99654E+00 -0.0015 33 CO3-2 0.84765E-06 -6.0718 0.43926E-06 -6.3573 0.51821E+00 -0.2855 34 CaCO3,aq 0.38302E-09 -9.4168 0.38302E-09 -9.4168 0.10000E+01 0.0000 35 Ca(HCO3)+ 0.79153E-12 -12.1015 0.66235E-12 -12.1789 0.83680E+00 -0.0774 36 CaCl+ 0.17174E-10 -10.7651 0.14372E-10 -10.8425 0.83680E+00 -0.0774 37 CaCl2,aq 0.43602E-15 -15.3605 0.43602E-15 -15.3605 0.10000E+01 0.0000 38 CaF+ 0.11673E-12 -12.9328 0.97683E-13 -13.0102 0.83680E+00 -0.0774 39 CaOH+ 0.79825E-07 -7.0979 0.66798E-07 -7.1752 0.83680E+00 -0.0774 40 CaSO4,aq 0.13674E-16 -16.8641 0.13674E-16 -16.8641 0.10000E+01 0.0000 41 HCl,aq 0.17363E-14 -14.7604 0.17363E-14 -14.7604 0.10000E+01 0.0000 45 HF,aq 0.48868E-13 -13.3110 0.48868E-13 -13.3110 0.10000E+01 0.0000 48 FeCl+ 0.72195E-17 -17.1415 0.60413E-17 -17.2189 0.83680E+00 -0.0774 51 FeF+ 0.17560E-18 -18.7555 0.14694E-18 -18.8328 0.83680E+00 -0.0774 53 FeO,aq 0.21100E-09 -9.6757 0.21100E-09 -9.6757 0.10000E+01 0.0000 54 FeOH+ 0.15669E-10 -10.8049 0.13112E-10 -10.8823 0.83680E+00 -0.0774 55 HFeO2- 0.35627E-07 -7.4482 0.29756E-07 -7.5264 0.83520E+00 -0.0782 56 FeO+ 0.11681E-16 -16.9325 0.97743E-17 -17.0099 0.83680E+00 -0.0774 58 FeO2- 0.43499E-09 -9.3615 0.36330E-09 -9.4397 0.83520E+00 -0.0782 59 HFeO2,aq 0.34284E-11 -11.4649 0.34284E-11 -11.4649 0.10000E+01 0.0000 60 H2,aq 0.10274E-04 -4.9883 0.10238E-04 -4.9898 0.99654E+00 -0.0015 61 KCl,aq 0.30305E-09 -9.5185 0.30305E-09 -9.5185 0.10000E+01 0.0000 63 KOH,aq 0.75364E-06 -6.1228 0.75364E-06 -6.1228 0.10000E+01 0.0000 64 KSO4- 0.15064E-14 -14.8221 0.12581E-14 -14.9003 0.83520E+00 -0.0782 65 MgCO3,aq 0.14961E-13 -13.8250 0.14961E-13 -13.8250 0.10000E+01 0.0000 66 Mg(HCO3)+ 0.12603E-15 -15.8995 0.10547E-15 -15.9769 0.83680E+00 -0.0774 67 MgCl+ 0.24256E-14 -14.6152 0.20298E-14 -14.6926 0.83680E+00 -0.0774 68 MgF+ 0.67384E-16 -16.1714 0.56387E-16 -16.2488 0.83680E+00 -0.0774 69 MgOH+ 0.68832E-10 -10.1622 0.57599E-10 -10.2396 0.83680E+00 -0.0774 71 MnF+ 0.18463E-16 -16.7337 0.15449E-16 -16.8111 0.83680E+00 -0.0774 72 MnO,aq 0.17934E-08 -8.7463 0.17934E-08 -8.7463 0.10000E+01 0.0000 73 MnOH+ 0.46432E-09 -9.3332 0.38854E-09 -9.4106 0.83680E+00 -0.0774 74 MnO2-2 0.20863E-10 -10.6806 0.10811E-10 -10.9661 0.51821E+00 -0.2855 75 HMnO2- 0.21042E-09 -9.6769 0.17574E-09 -9.7551 0.83520E+00 -0.0782 78 MnCl+ 0.89592E-14 -14.0477 0.74971E-14 -14.1251 0.83680E+00 -0.0774 80 NaCl,aq 0.70185E-06 -6.1538 0.70185E-06 -6.1538 0.10000E+01 0.0000 81 NaF,aq 0.37355E-09 -9.4277 0.37355E-09 -9.4277 0.10000E+01 0.0000 82 NaOH,aq 0.96033E-04 -4.0176 0.96033E-04 -4.0176 0.10000E+01 0.0000 84 OH- 0.93405E-02 -2.0296 0.77871E-02 -2.1086 0.83369E+00 -0.0790 89 HPO3-2 0.14491E-14 -14.8389 0.75095E-15 -15.1244 0.51821E+00 -0.2855 91 H2PO3- 0.13378E-18 -18.8736 0.11173E-18 -18.9518 0.83520E+00 -0.0782 92 H3PO4,aq 0.90620E-18 -18.0428 0.90620E-18 -18.0428 0.10000E+01 0.0000 93 H2PO4- 0.38534E-10 -10.4142 0.32214E-10 -10.4919 0.83599E+00 -0.0778 94 PO4-3 0.10666E-08 -8.9720 0.25881E-09 -9.5870 0.24265E+00 -0.6150 98 HP2O7-3 0.94690E-18 -18.0237 0.21899E-18 -18.6596 0.23127E+00 -0.6359 99 P2O7-4 0.91440E-17 -17.0389 0.70509E-18 -18.1518 0.77109E-01 -1.1129 100 H2S,aq 0.55098E-08 -8.2589 0.54908E-08 -8.2604 0.99654E+00 -0.0015 101 S2-2 0.23944E-14 -14.6208 0.12408E-14 -14.9063 0.51821E+00 -0.2855 107 SO3-2 0.15671E-17 -17.8049 0.82382E-18 -18.0842 0.52570E+00 -0.2793 109 HSO4- 0.52859E-19 -19.2769 0.44275E-19 -19.3538 0.83761E+00 -0.0770 Charge balance for all species = -.6133E-08 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.8830284E-10 -.2229871E-01 -.2243670E+02 0.0000 2 H2O 0.1000000E+01 0.5550489E+02 0.9981995E+06 0.0000 3 Cl- 0.1529001E-03 0.1536022E-03 0.5436197E+01 6.2358 4 SO4-- 0.1192349E-11 -.1663296E-04 -.1595013E+01 8.0511 5 HCO3- 0.4461041E-06 0.1535875E-04 0.9355197E+00 3.7015 6 HS- 0.2866476E-04 0.4530324E-04 0.1495665E+01 5.5088 7 Al+++ 0.9693342E-29 0.5315799E-05 0.1431790E+00 0.7390 8 H4SiO4 0.6959988E-03 0.1353260E-01 0.1298431E+04 -3.1574 9 Ca++ 0.1349012E-06 0.2317047E-06 0.9270125E-02 13.1015 10 Mg++ 0.2111825E-10 0.9318284E-10 0.2261524E-05 9.2941 11 Fe++ 0.5818143E-13 0.3629208E-07 0.2023282E-02 6.7347 12 K+ 0.1565075E-03 0.1572615E-03 0.6138553E+01 6.2467 13 Na+ 0.1986006E-01 0.2230616E-01 0.5119230E+03 8.3493 14 Mn++ 0.1854328E-10 0.2507575E-08 0.1375217E-03 9.2385 15 F- 0.1154322E-06 0.1158059E-06 0.2196257E-02 3.1128 16 HPO4-- 0.4531543E-07 0.4642055E-07 0.4447656E-02 12.6310 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.2002546E-01 -.2002546E-01 -.5896564E-08 0.0000000E+00 2 H2O 0.4984642E+02 0.4984642E+02 -.5896564E-08 0.0000000E+00 3 Cl- 0.1379432E-03 0.1379432E-03 0.0000000E+00 0.0000000E+00 4 SO4-- -.1493731E-04 -.1493731E-04 0.0000000E+00 0.0000000E+00 5 HCO3- 0.1379300E-04 0.1379300E-04 0.0000000E+00 0.0000000E+00 6 HS- 0.4068478E-04 0.4068478E-04 0.0000000E+00 0.0000000E+00 7 Al+++ 0.4775352E-05 0.4773878E-05 0.1474141E-08 0.0000000E+00 8 H4SiO4 0.1215302E-01 0.1215302E-01 0.4422423E-08 0.0000000E+00 9 Ca++ 0.2080835E-06 0.2080835E-06 0.0000000E+00 0.0000000E+00 10 Mg++ 0.8368328E-10 0.8368328E-10 0.0000000E+00 0.0000000E+00 11 Fe++ 0.3259227E-07 0.3259227E-07 0.0000000E+00 0.0000000E+00 12 K+ 0.1412294E-03 0.1412294E-03 0.0000000E+00 0.0000000E+00 13 Na+ 0.2003215E-01 0.2003215E-01 0.1474141E-08 0.0000000E+00 14 Mn++ 0.2251939E-08 0.2251939E-08 0.0000000E+00 0.0000000E+00 15 F- 0.1040000E-06 0.1040000E-06 0.0000000E+00 0.0000000E+00 16 HPO4-- 0.4168819E-07 0.4168819E-07 0.0000000E+00 0.0000000E+00 Chg. balance for solid moles: 0.4136E-24 Mass of aqueous solution: 0.899618E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 0.0000100 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 0.1474E-08 -8.831 0.3865E-06 -6.413 100.0 0.1484E-06 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 0.000000 g Volume = 0.000000 cm3 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.0000100 moles log = -5.0000 Original solution: 1000.0103000 g Original solution / Rock added: 100001030.00 (Water/Rock Ratio), log = 8.0000 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0546 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9679E+00 0.9855 0.1006E+01 0.1021E+01 CO2,gas 0.5960E-08 1.0069 0.6329E-08 0.6286E-08 CH4,gas 0.1932E-01 1.0124 0.2063E-01 0.2038E-01 H2,gas 0.1274E-01 1.0006 0.1344E-01 0.1343E-01 H2S,gas 0.1437E-06 0.9959 0.1509E-06 0.1516E-06 S2,gas 0.4488E-29 1.0000 0.4733E-29 0.4733E-29 CO,gas 0.2150E-13 1.0000 0.2267E-13 0.2267E-13 SO3,gas 0.1222E-47 1.0000 0.1289E-47 0.1289E-47 SO2,gas 0.6391E-27 1.0000 0.6740E-27 0.6740E-27 HF,gas 0.1138E-15 1.0000 0.1200E-15 0.1200E-15 HCl,gas 0.2905E-17 1.0000 0.3064E-17 0.3064E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 17 albite -0.38 -0.38 0.00 0.000 -0.94784E-12 23 andradite 39.01 38.87 -0.14 -0.007 0.23271E+03 24 grossular 32.73 31.31 -1.42 -0.071 0.24266E+04 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -16.56 -9.90 -3.299 0.16900E+05 -8.199 3 CH4,gas 4.54 1.16 -3.38 -0.846 0.57789E+04 -1.685 4 H2,gas 8.00 4.43 -3.57 -2.040 0.60966E+04 -1.872 5 H2S,gas -6.23 -14.75 -8.52 -4.260 0.14548E+05 -6.821 6 S2,gas -7.34 -38.36 -31.02 -4.773 0.52972E+05 -29.325 7 CO,gas 3.21 -12.13 -15.34 -4.721 0.26199E+05 -13.644 8 SO3,gas 17.12 -32.47 -49.59 -12.397 0.84671E+05 -47.890 9 SO2,gas 0.83 -28.04 -28.87 -7.699 0.49295E+05 -27.171 10 HF,gas 0.47 -17.15 -17.62 -8.810 0.30085E+05 -15.921 11 HCl,gas 5.19 -14.02 -19.21 -9.606 0.32805E+05 -17.514 12 acmite 7.71 6.55 -1.16 -0.120 0.19723E+04 16 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 20 spessartine 24.46 19.72 -4.74 -0.237 0.80867E+04 21 analcite 3.32 2.77 -0.55 -0.061 0.93627E+03 27 annite 20.12 17.72 -2.41 -0.134 0.41077E+04 28 phlogopite 27.06 25.40 -1.67 -0.093 0.28493E+04 30 anorthite 12.71 8.26 -4.45 -0.342 0.75908E+04 33 apatite-OH -18.15 -18.16 0.00 0.000 0.27850E+01 34 apatite-F -34.30 -35.30 -1.00 -0.083 0.17084E+04 38 aragonite 0.97 -3.46 -4.42 -1.474 0.75518E+04 39 brucite 12.57 9.29 -3.27 -0.655 0.55910E+04 40 calcite 0.81 -3.46 -4.27 -1.423 0.72876E+04 41 carnegieite-low 9.02 5.93 -3.09 -0.442 0.52802E+04 42 carnegieite-high 10.09 5.93 -4.16 -0.595 0.71072E+04 43 carpholite-Mg 8.58 4.46 -4.12 -0.275 0.70429E+04 44 carpholite-Fe 6.71 1.90 -4.81 -0.321 0.82210E+04 45 celadonite 5.34 3.65 -1.69 -0.099 0.28880E+04 46 celadonite-Fe 3.88 1.09 -2.79 -0.164 0.47565E+04 47 chrysotile 23.89 21.57 -2.32 -0.194 0.39695E+04 49 clinochlore 39.07 38.48 -0.59 -0.019 0.10126E+04 50 daphnite 28.97 25.68 -3.29 -0.103 0.56104E+04 52 chlorite-Al-free 47.17 43.14 -4.04 -0.168 0.68942E+04 54 chloritoid-Fe 9.17 5.06 -4.12 -0.275 0.70319E+04 55 chloritoid-Mn 11.40 7.56 -3.84 -0.256 0.65601E+04 57 coesite -2.38 -3.16 -0.78 -0.260 0.13341E+04 64 cristobalite -2.56 -3.16 -0.60 -0.199 0.10195E+04 66 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71234E+04 68 diaspore 2.87 0.74 -2.13 -0.356 0.36449E+04 69 diamond -3.10 -7.70 -4.60 -1.313 0.78490E+04 70 diopside 16.18 16.08 -0.10 -0.010 0.17167E+03 71 hedenbergite 14.21 13.52 -0.69 -0.069 0.11728E+04 74 enstatite 17.26 12.27 -4.99 -0.499 0.85227E+04 76 clinoenstatite 17.17 12.27 -4.89 -0.489 0.83543E+04 78 epidote 24.67 22.73 -1.94 -0.094 0.33143E+04 79 clinozoisite 22.81 18.95 -3.86 -0.175 0.65879E+04 80 epidote-Fe 29.84 26.51 -3.33 -0.173 0.56873E+04 81 fayalite 14.05 10.31 -3.73 -0.533 0.63751E+04 82 ferrosilite 11.15 7.15 -3.99 -0.399 0.68210E+04 86 gibbsite 4.08 0.74 -3.34 -0.477 0.57035E+04 87 glaucophane 22.97 20.80 -2.17 -0.059 0.37137E+04 88 glaucophane-Fe 17.28 13.12 -4.15 -0.112 0.70931E+04 89 graphite -3.55 -7.70 -4.15 -1.187 0.70913E+04 90 greenalite 16.14 13.89 -2.25 -0.188 0.38420E+04 93 hematite 12.57 9.04 -3.53 -0.427 0.60205E+04 94 heulandite -5.83 -7.52 -1.70 -0.077 0.28942E+04 98 jadeite 4.22 2.77 -1.44 -0.144 0.24618E+04 100 kalsilite 7.58 3.83 -3.76 -0.537 0.64126E+04 101 kaolinite -1.33 -4.84 -3.50 -0.319 0.59830E+04 104 laumontite 2.88 1.95 -0.93 -0.062 0.15939E+04 105 lawsonite 9.62 8.26 -1.35 -0.090 0.23075E+04 106 leucite 4.12 0.67 -3.45 -0.345 0.58873E+04 108 lizardite 23.24 21.57 -1.68 -0.140 0.28622E+04 110 magnetite 20.09 15.77 -4.31 -0.352 0.73634E+04 111 minnesotaite 10.39 7.57 -2.81 -0.165 0.48040E+04 115 manganosite 14.06 9.24 -4.82 -1.205 0.82294E+04 119 microcline -2.49 -2.49 0.00 0.000 0.17124E-02 123 muscovite 2.58 -1.01 -3.59 -0.211 0.61314E+04 124 paragonite 4.24 1.09 -3.15 -0.185 0.53705E+04 125 nepheline 8.34 5.93 -2.41 -0.344 0.41125E+04 131 periclase-Fe 11.63 6.73 -4.89 -1.223 0.83527E+04 137 phlogopite-Na 29.65 27.50 -2.15 -0.119 0.36681E+04 139 prehnite 19.37 18.21 -1.16 -0.068 0.19860E+04 140 prehnite-Fe 22.50 21.99 -0.51 -0.031 0.86737E+03 141 pumpellyite-Fe 46.27 43.89 -2.38 -0.053 0.40606E+04 142 pumpellyite-Mg 48.99 46.45 -2.54 -0.057 0.43442E+04 146 pyrrhotite -4.26 -8.02 -3.76 -1.252 0.64122E+04 147 pyrrhotiteFe0.875 -6.02 -9.41 -3.39 -1.247 0.57880E+04 148 pyroxmangite 7.40 6.08 -1.32 -0.264 0.22497E+04 149 pyrophyllite -6.18 -11.15 -4.98 -0.311 0.84960E+04 150 quartz -2.99 -3.16 -0.17 -0.056 0.28678E+03 155 rhodonite 7.45 6.08 -1.36 -0.273 0.23300E+04 156 sanidine -1.28 -2.49 -1.21 -0.093 0.20678E+04 166 stilbite -7.52 -7.52 0.00 0.000 0.36841E+00 167 stilpnomelane-Fe 13.02 13.02 0.00 0.000 0.19218E+01 168 stilpnomelane-Mg 27.44 25.81 -1.63 -0.049 0.27807E+04 174 talc 16.49 15.25 -1.24 -0.073 0.21143E+04 177 tephroite 18.09 15.32 -2.77 -0.395 0.47232E+04 181 tridymite -2.63 -3.16 -0.53 -0.177 0.90676E+03 182 tremolite 47.87 47.41 -0.45 -0.012 0.77657E+03 183 ferroactinolite 38.45 34.62 -3.83 -0.104 0.65480E+04 184 troilite-low -4.41 -8.02 -3.60 -1.202 0.61550E+04 186 vesuvianite 223.47 218.81 -4.66 -0.036 0.79547E+04 190 wairakite 3.95 1.95 -2.00 -0.118 0.34159E+04 191 walstromite 11.51 9.94 -1.57 -0.313 0.26724E+04 192 wollastonite 10.46 9.94 -0.52 -0.103 0.88287E+03 193 pseudo-wollastonite 11.00 9.94 -1.06 -0.211 0.18027E+04 194 zoisite 22.85 18.95 -3.90 -0.177 0.66619E+04 195 akaganeite 7.75 4.52 -3.23 -0.699 0.55228E+04 202 chalcedony -2.80 -3.16 -0.35 -0.118 0.60608E+03 204 montmorillonite-Ca -2.29 -6.17 -3.88 -0.240 0.66180E+04 205 montmorillonite-K -2.24 -6.27 -4.03 -0.247 0.68815E+04 206 montmorillonite-Mg -2.48 -6.79 -4.31 -0.267 0.73677E+04 207 montmorillonite-Na -2.04 -5.57 -3.54 -0.216 0.60364E+04 208 nontronite-Ca 3.21 -0.14 -3.36 -0.218 0.57309E+04 209 nontronite-H 2.53 -2.30 -4.84 -0.324 0.82578E+04 210 nontronite-K 3.34 -0.24 -3.58 -0.230 0.61176E+04 211 nontronite-Mg 3.07 -0.77 -3.84 -0.249 0.65646E+04 212 nontronite-Na 3.52 0.45 -3.07 -0.197 0.52385E+04 228 tobermorite 9.82 7.76 -2.07 -0.564 0.35292E+04 234 alabandite -0.98 -5.51 -4.53 -1.511 0.77418E+04 237 boehmite 4.41 0.74 -3.67 -0.611 0.62619E+04 239 ferrous-oxide 9.81 6.73 -3.08 -0.769 0.52536E+04 245 silica-amorphous -2.09 -3.16 -1.07 -0.355 0.18203E+04 247 an20ab80 2.02 1.35 -0.67 -0.052 0.11473E+04 248 an25ab75 2.65 1.78 -0.87 -0.067 0.14811E+04 249 an30ab70 3.28 2.21 -1.07 -0.082 0.18245E+04 250 tr.625ac.25prg.125 45.16 45.16 0.00 0.000 0.19983E+01 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 9 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 0.0000100 Water: Moles liquid = 0.4985E+02 kg liquid = 0.8981E+00 Moles total = 0.4985E+02 kg total = 0.8980E+00 Activity = 1.0000 Stoichiometric ionic strength = .1133087E-01 Osmotic coef. = 0.9693 True ionic strength = .2001796E-01 Chg. balance for total moles = -.5508E-08 Max. difference allowed = 0.1379E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.88303E-10 -10.0540 0.74197E-10 -10.1296 0.84025E+00 -0.0756 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.15290E-03 -3.8156 0.12770E-03 -3.8938 0.83520E+00 -0.0782 4 SO4-- 0.11922E-11 -11.9236 0.61914E-12 -12.2082 0.51931E+00 -0.2846 5 HCO3- 0.44607E-06 -6.3506 0.37310E-06 -6.4282 0.83642E+00 -0.0776 6 HS- 0.28665E-04 -4.5427 0.23944E-04 -4.6208 0.83532E+00 -0.0781 7 Al+++ 0.96933E-29 -29.0135 0.22395E-29 -29.6498 0.23103E+00 -0.6363 8 H4SiO4 0.69600E-03 -3.1574 0.69600E-03 -3.1574 0.10000E+01 0.0000 9 Ca++ 0.13341E-06 -6.8748 0.68770E-07 -7.1626 0.51550E+00 -0.2878 10 Mg++ 0.21118E-10 -10.6753 0.10837E-10 -10.9651 0.51314E+00 -0.2898 11 Fe++ 0.55961E-13 -13.2521 0.28747E-13 -13.5414 0.51370E+00 -0.2893 12 K+ 0.15651E-03 -3.8055 0.13094E-03 -3.8829 0.83662E+00 -0.0775 13 Na+ 0.19860E-01 -1.7020 0.16584E-01 -1.7803 0.83505E+00 -0.0783 14 Mn++ 0.18543E-10 -10.7318 0.95336E-11 -11.0207 0.51413E+00 -0.2889 15 F- 0.11543E-06 -6.9377 0.96210E-07 -7.0168 0.83348E+00 -0.0791 16 HPO4-- 0.45315E-07 -7.3438 0.23536E-07 -7.6283 0.51938E+00 -0.2845 18 HSiO3- 0.10487E-01 -1.9793 0.87589E-02 -2.0575 0.83520E+00 -0.0782 19 Ca(HSiO3)+ 0.16393E-07 -7.7853 0.13718E-07 -7.8627 0.83680E+00 -0.0774 20 Mg(HSiO3)+ 0.32148E-11 -11.4928 0.26902E-11 -11.5702 0.83680E+00 -0.0774 21 NaHSiO3,aq 0.23494E-02 -2.6290 0.23494E-02 -2.6290 0.10000E+01 0.0000 22 AlO+ 0.66136E-16 -16.1796 0.55342E-16 -16.2569 0.83680E+00 -0.0774 24 HAlO2,aq 0.14854E-09 -9.8282 0.14854E-09 -9.8282 0.10000E+01 0.0000 25 AlO2- 0.53157E-05 -5.2744 0.44316E-05 -5.3534 0.83369E+00 -0.0790 26 CH4,aq 0.14065E-04 -4.8519 0.14016E-04 -4.8534 0.99654E+00 -0.0015 27 C2H6,aq 0.32915E-14 -14.4826 0.32802E-14 -14.4841 0.99654E+00 -0.0015 31 CO,aq 0.15214E-16 -16.8178 0.15214E-16 -16.8178 0.10000E+01 0.0000 32 CO2,aq 0.59357E-10 -10.2265 0.59152E-10 -10.2280 0.99654E+00 -0.0015 33 CO3-2 0.84758E-06 -6.0718 0.43922E-06 -6.3573 0.51821E+00 -0.2855 34 CaCO3,aq 0.37874E-09 -9.4217 0.37874E-09 -9.4217 0.10000E+01 0.0000 35 Ca(HCO3)+ 0.78268E-12 -12.1064 0.65495E-12 -12.1838 0.83680E+00 -0.0774 36 CaCl+ 0.16984E-10 -10.7700 0.14212E-10 -10.8473 0.83680E+00 -0.0774 37 CaCl2,aq 0.43119E-15 -15.3653 0.43119E-15 -15.3653 0.10000E+01 0.0000 38 CaF+ 0.11544E-12 -12.9376 0.96600E-13 -13.0150 0.83680E+00 -0.0774 39 CaOH+ 0.78940E-07 -7.1027 0.66057E-07 -7.1801 0.83680E+00 -0.0774 40 CaSO4,aq 0.13521E-16 -16.8690 0.13521E-16 -16.8690 0.10000E+01 0.0000 41 HCl,aq 0.17363E-14 -14.7604 0.17363E-14 -14.7604 0.10000E+01 0.0000 45 HF,aq 0.48868E-13 -13.3110 0.48868E-13 -13.3110 0.10000E+01 0.0000 48 FeCl+ 0.69440E-17 -17.1584 0.58107E-17 -17.2358 0.83680E+00 -0.0774 51 FeF+ 0.16890E-18 -18.7724 0.14134E-18 -18.8497 0.83680E+00 -0.0774 53 FeO,aq 0.20295E-09 -9.6926 0.20295E-09 -9.6926 0.10000E+01 0.0000 54 FeOH+ 0.15071E-10 -10.8218 0.12612E-10 -10.8992 0.83680E+00 -0.0774 55 HFeO2- 0.34267E-07 -7.4651 0.28620E-07 -7.5433 0.83520E+00 -0.0782 56 FeO+ 0.11235E-16 -16.9494 0.94012E-17 -17.0268 0.83680E+00 -0.0774 58 FeO2- 0.41838E-09 -9.3784 0.34943E-09 -9.4566 0.83520E+00 -0.0782 59 HFeO2,aq 0.32975E-11 -11.4818 0.32975E-11 -11.4818 0.10000E+01 0.0000 60 H2,aq 0.10274E-04 -4.9883 0.10239E-04 -4.9898 0.99654E+00 -0.0015 61 KCl,aq 0.30305E-09 -9.5185 0.30305E-09 -9.5185 0.10000E+01 0.0000 63 KOH,aq 0.75364E-06 -6.1228 0.75364E-06 -6.1228 0.10000E+01 0.0000 64 KSO4- 0.15062E-14 -14.8221 0.12580E-14 -14.9003 0.83520E+00 -0.0782 65 MgCO3,aq 0.14959E-13 -13.8251 0.14959E-13 -13.8251 0.10000E+01 0.0000 66 Mg(HCO3)+ 0.12602E-15 -15.8995 0.10546E-15 -15.9769 0.83680E+00 -0.0774 67 MgCl+ 0.24256E-14 -14.6152 0.20298E-14 -14.6926 0.83680E+00 -0.0774 68 MgF+ 0.67384E-16 -16.1714 0.56387E-16 -16.2488 0.83680E+00 -0.0774 69 MgOH+ 0.68832E-10 -10.1622 0.57599E-10 -10.2396 0.83680E+00 -0.0774 71 MnF+ 0.18463E-16 -16.7337 0.15449E-16 -16.8111 0.83680E+00 -0.0774 72 MnO,aq 0.17934E-08 -8.7463 0.17934E-08 -8.7463 0.10000E+01 0.0000 73 MnOH+ 0.46432E-09 -9.3332 0.38854E-09 -9.4106 0.83680E+00 -0.0774 74 MnO2-2 0.20863E-10 -10.6806 0.10811E-10 -10.9661 0.51821E+00 -0.2855 75 HMnO2- 0.21042E-09 -9.6769 0.17574E-09 -9.7551 0.83520E+00 -0.0782 78 MnCl+ 0.89592E-14 -14.0477 0.74971E-14 -14.1251 0.83680E+00 -0.0774 80 NaCl,aq 0.70185E-06 -6.1538 0.70185E-06 -6.1538 0.10000E+01 0.0000 81 NaF,aq 0.37355E-09 -9.4277 0.37355E-09 -9.4277 0.10000E+01 0.0000 82 NaOH,aq 0.96033E-04 -4.0176 0.96033E-04 -4.0176 0.10000E+01 0.0000 84 OH- 0.93404E-02 -2.0296 0.77871E-02 -2.1086 0.83369E+00 -0.0790 89 HPO3-2 0.14492E-14 -14.8389 0.75096E-15 -15.1244 0.51821E+00 -0.2855 91 H2PO3- 0.13378E-18 -18.8736 0.11173E-18 -18.9518 0.83520E+00 -0.0782 92 H3PO4,aq 0.90620E-18 -18.0428 0.90620E-18 -18.0428 0.10000E+01 0.0000 93 H2PO4- 0.38534E-10 -10.4142 0.32214E-10 -10.4919 0.83599E+00 -0.0778 94 PO4-3 0.10666E-08 -8.9720 0.25881E-09 -9.5870 0.24265E+00 -0.6150 98 HP2O7-3 0.94690E-18 -18.0237 0.21899E-18 -18.6596 0.23127E+00 -0.6359 99 P2O7-4 0.91440E-17 -17.0389 0.70509E-18 -18.1518 0.77109E-01 -1.1129 100 H2S,aq 0.55098E-08 -8.2589 0.54908E-08 -8.2604 0.99654E+00 -0.0015 101 S2-2 0.23944E-14 -14.6208 0.12408E-14 -14.9063 0.51821E+00 -0.2855 107 SO3-2 0.15670E-17 -17.8049 0.82377E-18 -18.0842 0.52570E+00 -0.2793 109 HSO4- 0.52854E-19 -19.2769 0.44271E-19 -19.3539 0.83761E+00 -0.0770 Charge balance for all species = -.6133E-08 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.8830284E-10 -.2229870E-01 -.2243670E+02 0.0000 2 H2O 0.1000000E+01 0.5550489E+02 0.9981995E+06 0.0000 3 Cl- 0.1529001E-03 0.1536022E-03 0.5436197E+01 6.2358 4 SO4-- 0.1192240E-11 -.1663314E-04 -.1595029E+01 8.0510 5 HCO3- 0.4460669E-06 0.1535875E-04 0.9355197E+00 3.7014 6 HS- 0.2866476E-04 0.4530341E-04 0.1495671E+01 5.5088 7 Al+++ 0.9693344E-29 0.5315799E-05 0.1431790E+00 0.7390 8 H4SiO4 0.6959988E-03 0.1353260E-01 0.1298431E+04 -3.1574 9 Ca++ 0.1334052E-06 0.2291351E-06 0.9167319E-02 13.0966 10 Mg++ 0.2111825E-10 0.9318284E-10 0.2261524E-05 9.2941 11 Fe++ 0.5596104E-13 0.3490705E-07 0.1946066E-02 6.7178 12 K+ 0.1565075E-03 0.1572615E-03 0.6138553E+01 6.2467 13 Na+ 0.1986006E-01 0.2230616E-01 0.5119230E+03 8.3493 14 Mn++ 0.1854329E-10 0.2507575E-08 0.1375217E-03 9.2385 15 F- 0.1154322E-06 0.1158059E-06 0.2196257E-02 3.1128 16 HPO4-- 0.4531543E-07 0.4642055E-07 0.4447656E-02 12.6310 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.2002546E-01 -.2002545E-01 -.1254869E-07 0.0000000E+00 2 H2O 0.4984642E+02 0.4984642E+02 -.5339343E-08 0.0000000E+00 3 Cl- 0.1379432E-03 0.1379432E-03 0.0000000E+00 0.0000000E+00 4 SO4-- -.1493731E-04 -.1493747E-04 0.1554796E-09 0.0000000E+00 5 HCO3- 0.1379300E-04 0.1379300E-04 0.0000000E+00 0.0000000E+00 6 HS- 0.4068478E-04 0.4068494E-04 -.1554796E-09 0.0000000E+00 7 Al+++ 0.4775352E-05 0.4773878E-05 0.1473949E-08 0.0000000E+00 8 H4SiO4 0.1215302E-01 0.1215301E-01 0.5845713E-08 0.0000000E+00 9 Ca++ 0.2080835E-06 0.2057759E-06 0.2307645E-08 0.0000000E+00 10 Mg++ 0.8368328E-10 0.8368328E-10 0.0000000E+00 0.0000000E+00 11 Fe++ 0.3259227E-07 0.3134843E-07 0.1243837E-08 0.0000000E+00 12 K+ 0.1412294E-03 0.1412294E-03 0.0000000E+00 0.0000000E+00 13 Na+ 0.2003215E-01 0.2003215E-01 0.1179356E-08 0.0000000E+00 14 Mn++ 0.2251939E-08 0.2251939E-08 0.0000000E+00 0.0000000E+00 15 F- 0.1040000E-06 0.1040000E-06 0.0000000E+00 0.0000000E+00 16 HPO4-- 0.4168819E-07 0.4168819E-07 0.0000000E+00 0.0000000E+00 Chg. balance for solid moles: -.1241E-23 Mass of aqueous solution: 0.899618E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 0.0000100 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 0.1179E-08 -8.928 0.3093E-06 -6.510 44.71 0.1187E-06 andradite 0.6219E-09 -9.206 0.3160E-06 -6.500 45.69 0.8211E-07 grossular 0.1473E-09 -9.832 0.6635E-07 -7.178 9.593 0.1846E-07 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8085E+00 0.8085E+00 1.0000 -0.092 grossular 0.1915E+00 0.1915E+00 1.0000 -0.718 Solid products produced: Mass = 0.000001 g Volume = 0.000000 cm3 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.0000100 moles log = -5.0000 Original solution: 1000.0103000 g Original solution / Rock added: 100001030.00 (Water/Rock Ratio), log = 8.0000 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0546 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9679E+00 0.9855 0.1006E+01 0.1021E+01 CO2,gas 0.5960E-08 1.0069 0.6329E-08 0.6285E-08 CH4,gas 0.1932E-01 1.0124 0.2063E-01 0.2038E-01 H2,gas 0.1274E-01 1.0006 0.1344E-01 0.1343E-01 H2S,gas 0.1437E-06 0.9959 0.1509E-06 0.1516E-06 S2,gas 0.4488E-29 1.0000 0.4733E-29 0.4733E-29 CO,gas 0.2150E-13 1.0000 0.2267E-13 0.2267E-13 SO3,gas 0.1222E-47 1.0000 0.1289E-47 0.1289E-47 SO2,gas 0.6391E-27 1.0000 0.6740E-27 0.6740E-27 HF,gas 0.1138E-15 1.0000 0.1200E-15 0.1200E-15 HCl,gas 0.2905E-17 1.0000 0.3064E-17 0.3064E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 17 albite -0.38 -0.38 0.00 0.000 -0.94784E-12 23 andradite 39.01 39.01 0.00 0.000 -0.12132E-10 24 grossular 32.73 32.73 0.00 0.000 0.12132E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -16.56 -9.90 -3.299 0.16900E+05 -8.199 3 CH4,gas 4.54 1.16 -3.38 -0.846 0.57789E+04 -1.685 4 H2,gas 8.00 4.43 -3.57 -2.040 0.60965E+04 -1.872 5 H2S,gas -6.23 -14.75 -8.52 -4.260 0.14548E+05 -6.821 6 S2,gas -7.34 -38.36 -31.02 -4.773 0.52972E+05 -29.325 7 CO,gas 3.21 -12.13 -15.34 -4.721 0.26199E+05 -13.645 8 SO3,gas 17.12 -32.47 -49.59 -12.397 0.84672E+05 -47.890 9 SO2,gas 0.83 -28.04 -28.87 -7.699 0.49295E+05 -27.171 10 HF,gas 0.47 -17.15 -17.62 -8.810 0.30085E+05 -15.921 11 HCl,gas 5.19 -14.02 -19.21 -9.606 0.32805E+05 -17.514 12 acmite 7.71 6.54 -1.17 -0.122 0.20011E+04 16 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 20 spessartine 24.46 19.72 -4.74 -0.237 0.80867E+04 21 analcite 3.32 2.77 -0.55 -0.061 0.93627E+03 27 annite 20.12 17.67 -2.46 -0.136 0.41942E+04 28 phlogopite 27.06 25.40 -1.67 -0.093 0.28493E+04 30 anorthite 12.71 8.26 -4.45 -0.342 0.75991E+04 33 apatite-OH -18.15 -18.18 -0.03 -0.002 0.44133E+02 34 apatite-F -34.30 -35.33 -1.02 -0.085 0.17497E+04 38 aragonite 0.97 -3.46 -4.43 -1.476 0.75601E+04 39 brucite 12.57 9.29 -3.27 -0.655 0.55910E+04 40 calcite 0.81 -3.46 -4.27 -1.424 0.72959E+04 41 carnegieite-low 9.02 5.93 -3.09 -0.442 0.52802E+04 42 carnegieite-high 10.09 5.93 -4.16 -0.595 0.71072E+04 43 carpholite-Mg 8.58 4.46 -4.12 -0.275 0.70429E+04 44 carpholite-Fe 6.71 1.88 -4.83 -0.322 0.82498E+04 45 celadonite 5.34 3.65 -1.69 -0.099 0.28880E+04 46 celadonite-Fe 3.88 1.07 -2.80 -0.165 0.47853E+04 47 chrysotile 23.89 21.57 -2.32 -0.194 0.39695E+04 49 clinochlore 39.07 38.48 -0.59 -0.019 0.10126E+04 50 daphnite 28.97 25.59 -3.37 -0.105 0.57547E+04 52 chlorite-Al-free 47.17 43.14 -4.04 -0.168 0.68942E+04 54 chloritoid-Fe 9.17 5.04 -4.14 -0.276 0.70607E+04 55 chloritoid-Mn 11.40 7.56 -3.84 -0.256 0.65601E+04 57 coesite -2.38 -3.16 -0.78 -0.260 0.13341E+04 64 cristobalite -2.56 -3.16 -0.60 -0.199 0.10195E+04 66 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71234E+04 68 diaspore 2.87 0.74 -2.13 -0.356 0.36449E+04 69 diamond -3.10 -7.70 -4.60 -1.313 0.78491E+04 70 diopside 16.18 16.08 -0.11 -0.011 0.17994E+03 71 hedenbergite 14.21 13.50 -0.71 -0.071 0.12099E+04 74 enstatite 17.26 12.27 -4.99 -0.499 0.85227E+04 76 clinoenstatite 17.17 12.27 -4.89 -0.489 0.83543E+04 78 epidote 24.67 22.70 -1.97 -0.095 0.33597E+04 79 clinozoisite 22.81 18.94 -3.87 -0.176 0.66044E+04 80 epidote-Fe 29.84 26.47 -3.37 -0.175 0.57615E+04 81 fayalite 14.05 10.28 -3.77 -0.538 0.64328E+04 82 ferrosilite 11.15 7.12 -4.03 -0.403 0.68787E+04 86 gibbsite 4.08 0.74 -3.34 -0.477 0.57035E+04 87 glaucophane 22.97 20.80 -2.17 -0.059 0.37137E+04 88 glaucophane-Fe 17.28 13.07 -4.20 -0.114 0.71797E+04 89 graphite -3.55 -7.70 -4.15 -1.187 0.70913E+04 90 greenalite 16.14 13.84 -2.30 -0.192 0.39286E+04 93 hematite 12.57 9.01 -3.56 -0.431 0.60782E+04 94 heulandite -5.83 -7.53 -1.70 -0.077 0.29025E+04 98 jadeite 4.22 2.77 -1.44 -0.144 0.24618E+04 100 kalsilite 7.58 3.83 -3.76 -0.537 0.64126E+04 101 kaolinite -1.33 -4.84 -3.50 -0.319 0.59830E+04 104 laumontite 2.88 1.95 -0.94 -0.063 0.16022E+04 105 lawsonite 9.62 8.26 -1.36 -0.090 0.23157E+04 106 leucite 4.12 0.67 -3.45 -0.345 0.58873E+04 108 lizardite 23.24 21.57 -1.68 -0.140 0.28622E+04 110 magnetite 20.09 15.72 -4.36 -0.356 0.74500E+04 111 minnesotaite 10.39 7.52 -2.86 -0.168 0.48905E+04 115 manganosite 14.06 9.24 -4.82 -1.205 0.82294E+04 119 microcline -2.49 -2.49 0.00 0.000 0.17301E-02 123 muscovite 2.58 -1.01 -3.59 -0.211 0.61314E+04 124 paragonite 4.24 1.09 -3.15 -0.185 0.53705E+04 125 nepheline 8.34 5.93 -2.41 -0.344 0.41125E+04 131 periclase-Fe 11.63 6.72 -4.91 -1.227 0.83816E+04 137 phlogopite-Na 29.65 27.50 -2.15 -0.119 0.36681E+04 139 prehnite 19.37 18.20 -1.17 -0.069 0.20025E+04 140 prehnite-Fe 22.50 21.96 -0.53 -0.032 0.91277E+03 141 pumpellyite-Fe 46.27 43.85 -2.41 -0.054 0.41226E+04 142 pumpellyite-Mg 48.99 46.43 -2.56 -0.057 0.43772E+04 146 pyrrhotite -4.26 -8.03 -3.77 -1.257 0.64410E+04 147 pyrrhotiteFe0.875 -6.02 -9.42 -3.40 -1.252 0.58132E+04 148 pyroxmangite 7.40 6.08 -1.32 -0.264 0.22497E+04 149 pyrophyllite -6.18 -11.15 -4.98 -0.311 0.84960E+04 150 quartz -2.99 -3.16 -0.17 -0.056 0.28678E+03 155 rhodonite 7.45 6.08 -1.36 -0.273 0.23300E+04 156 sanidine -1.28 -2.49 -1.21 -0.093 0.20678E+04 166 stilbite -7.52 -7.53 -0.01 0.000 0.86380E+01 167 stilpnomelane-Fe 13.02 12.93 -0.09 -0.003 0.14619E+03 168 stilpnomelane-Mg 27.44 25.81 -1.63 -0.049 0.27807E+04 174 talc 16.49 15.25 -1.24 -0.073 0.21143E+04 177 tephroite 18.09 15.32 -2.77 -0.395 0.47232E+04 181 tridymite -2.63 -3.16 -0.53 -0.177 0.90676E+03 182 tremolite 47.87 47.40 -0.46 -0.013 0.79311E+03 183 ferroactinolite 38.45 34.52 -3.93 -0.106 0.67088E+04 184 troilite-low -4.41 -8.03 -3.62 -1.207 0.61838E+04 186 vesuvianite 223.47 218.72 -4.75 -0.036 0.81118E+04 190 wairakite 3.95 1.95 -2.01 -0.118 0.34242E+04 191 walstromite 11.51 9.94 -1.57 -0.314 0.26807E+04 192 wollastonite 10.46 9.94 -0.52 -0.104 0.89114E+03 193 pseudo-wollastonite 11.00 9.94 -1.06 -0.212 0.18110E+04 194 zoisite 22.85 18.94 -3.91 -0.178 0.66785E+04 195 akaganeite 7.75 4.50 -3.25 -0.703 0.55516E+04 202 chalcedony -2.80 -3.16 -0.35 -0.118 0.60608E+03 204 montmorillonite-Ca -2.29 -6.17 -3.88 -0.240 0.66194E+04 205 montmorillonite-K -2.24 -6.27 -4.03 -0.247 0.68815E+04 206 montmorillonite-Mg -2.48 -6.79 -4.31 -0.267 0.73677E+04 207 montmorillonite-Na -2.04 -5.57 -3.54 -0.216 0.60364E+04 208 nontronite-Ca 3.21 -0.18 -3.39 -0.220 0.57900E+04 209 nontronite-H 2.53 -2.34 -4.87 -0.326 0.83155E+04 210 nontronite-K 3.34 -0.28 -3.62 -0.232 0.61753E+04 211 nontronite-Mg 3.07 -0.80 -3.88 -0.252 0.66223E+04 212 nontronite-Na 3.52 0.42 -3.10 -0.199 0.52962E+04 228 tobermorite 9.82 7.75 -2.07 -0.565 0.35361E+04 234 alabandite -0.98 -5.51 -4.53 -1.511 0.77418E+04 237 boehmite 4.41 0.74 -3.67 -0.611 0.62619E+04 239 ferrous-oxide 9.81 6.72 -3.09 -0.773 0.52825E+04 245 silica-amorphous -2.09 -3.16 -1.07 -0.355 0.18203E+04 247 an20ab80 2.02 1.34 -0.67 -0.052 0.11490E+04 248 an25ab75 2.65 1.78 -0.87 -0.067 0.14832E+04 249 an30ab70 3.28 2.21 -1.07 -0.082 0.18270E+04 250 tr.625ac.25prg.125 45.16 45.13 -0.03 -0.001 0.54605E+02 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 0.0000100 MOLES Current total amount of reactant added: 0.0000100 MOLES New total amount of reactant added: 0.0000200 MOLES Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.5508E-08 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 7 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 0.0000200 Water: Moles liquid = 0.4985E+02 kg liquid = 0.8981E+00 Moles total = 0.4985E+02 kg total = 0.8980E+00 Activity = 1.0000 Stoichiometric ionic strength = .1133150E-01 Osmotic coef. = 0.9693 True ionic strength = .2001840E-01 Chg. balance for total moles = -.5508E-08 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.88315E-10 -10.0540 0.74207E-10 -10.1296 0.84025E+00 -0.0756 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.15297E-03 -3.8154 0.12776E-03 -3.8936 0.83520E+00 -0.0782 4 SO4-- 0.17619E-11 -11.7540 0.91497E-12 -12.0386 0.51931E+00 -0.2846 5 HCO3- 0.66142E-06 -6.1795 0.55322E-06 -6.2571 0.83642E+00 -0.0776 6 HS- 0.28935E-04 -4.5386 0.24170E-04 -4.6167 0.83532E+00 -0.0781 7 Al+++ 0.96951E-29 -29.0134 0.22399E-29 -29.6498 0.23103E+00 -0.6363 8 H4SiO4 0.69609E-03 -3.1573 0.69609E-03 -3.1573 0.10000E+01 0.0000 9 Ca++ 0.13220E-06 -6.8788 0.68148E-07 -7.1665 0.51550E+00 -0.2878 10 Mg++ 0.21119E-10 -10.6753 0.10837E-10 -10.9651 0.51314E+00 -0.2898 11 Fe++ 0.54295E-13 -13.2652 0.27891E-13 -13.5545 0.51370E+00 -0.2893 12 K+ 0.15651E-03 -3.8055 0.13094E-03 -3.8829 0.83662E+00 -0.0775 13 Na+ 0.19860E-01 -1.7020 0.16584E-01 -1.7803 0.83505E+00 -0.0783 14 Mn++ 0.18548E-10 -10.7317 0.95361E-11 -11.0206 0.51412E+00 -0.2889 15 F- 0.11987E-06 -6.9213 0.99910E-07 -7.0004 0.83348E+00 -0.0791 16 HPO4-- 0.45316E-07 -7.3438 0.23536E-07 -7.6283 0.51938E+00 -0.2845 18 HSiO3- 0.10487E-01 -1.9793 0.87588E-02 -2.0576 0.83520E+00 -0.0782 19 Ca(HSiO3)+ 0.16245E-07 -7.7893 0.13594E-07 -7.8667 0.83680E+00 -0.0774 20 Mg(HSiO3)+ 0.32149E-11 -11.4928 0.26902E-11 -11.5702 0.83680E+00 -0.0774 21 NaHSiO3,aq 0.23493E-02 -2.6291 0.23493E-02 -2.6291 0.10000E+01 0.0000 22 AlO+ 0.66129E-16 -16.1796 0.55336E-16 -16.2570 0.83680E+00 -0.0774 24 HAlO2,aq 0.14851E-09 -9.8283 0.14851E-09 -9.8283 0.10000E+01 0.0000 25 AlO2- 0.53136E-05 -5.2746 0.44299E-05 -5.3536 0.83369E+00 -0.0790 26 CH4,aq 0.14245E-04 -4.8463 0.14196E-04 -4.8478 0.99654E+00 -0.0015 27 C2H6,aq 0.37143E-14 -14.4301 0.37014E-14 -14.4316 0.99654E+00 -0.0015 31 CO,aq 0.20510E-16 -16.6880 0.20510E-16 -16.6880 0.10000E+01 0.0000 32 CO2,aq 0.88024E-10 -10.0554 0.87720E-10 -10.0569 0.99654E+00 -0.0015 33 CO3-2 0.12566E-05 -5.9008 0.65118E-06 -6.1863 0.51820E+00 -0.2855 34 CaCO3,aq 0.55643E-09 -9.2546 0.55643E-09 -9.2546 0.10000E+01 0.0000 35 Ca(HCO3)+ 0.11500E-11 -11.9393 0.96235E-12 -12.0167 0.83680E+00 -0.0774 36 CaCl+ 0.16837E-10 -10.7737 0.14090E-10 -10.8511 0.83680E+00 -0.0774 37 CaCl2,aq 0.42765E-15 -15.3689 0.42765E-15 -15.3689 0.10000E+01 0.0000 38 CaF+ 0.11879E-12 -12.9252 0.99407E-13 -13.0026 0.83680E+00 -0.0774 39 CaOH+ 0.78215E-07 -7.1067 0.65450E-07 -7.1841 0.83680E+00 -0.0774 40 CaSO4,aq 0.19800E-16 -16.7033 0.19800E-16 -16.7033 0.10000E+01 0.0000 41 HCl,aq 0.17372E-14 -14.7601 0.17372E-14 -14.7601 0.10000E+01 0.0000 45 HF,aq 0.50754E-13 -13.2945 0.50754E-13 -13.2945 0.10000E+01 0.0000 48 FeCl+ 0.67401E-17 -17.1713 0.56401E-17 -17.2487 0.83680E+00 -0.0774 51 FeF+ 0.17018E-18 -18.7691 0.14240E-18 -18.8465 0.83680E+00 -0.0774 53 FeO,aq 0.19686E-09 -9.7059 0.19686E-09 -9.7059 0.10000E+01 0.0000 54 FeOH+ 0.14621E-10 -10.8350 0.12235E-10 -10.9124 0.83680E+00 -0.0774 55 HFeO2- 0.33233E-07 -7.4784 0.27757E-07 -7.5566 0.83520E+00 -0.0782 56 FeO+ 0.11431E-16 -16.9419 0.95653E-17 -17.0193 0.83680E+00 -0.0774 58 FeO2- 0.42557E-09 -9.3710 0.35543E-09 -9.4492 0.83520E+00 -0.0782 59 HFeO2,aq 0.33546E-11 -11.4744 0.33546E-11 -11.4744 0.10000E+01 0.0000 60 H2,aq 0.93399E-05 -5.0297 0.93077E-05 -5.0312 0.99654E+00 -0.0015 61 KCl,aq 0.30318E-09 -9.5183 0.30318E-09 -9.5183 0.10000E+01 0.0000 63 KOH,aq 0.75354E-06 -6.1229 0.75354E-06 -6.1229 0.10000E+01 0.0000 64 KSO4- 0.22259E-14 -14.6525 0.18591E-14 -14.7307 0.83520E+00 -0.0782 65 MgCO3,aq 0.22179E-13 -13.6541 0.22179E-13 -13.6541 0.10000E+01 0.0000 66 Mg(HCO3)+ 0.18687E-15 -15.7285 0.15637E-15 -15.8058 0.83680E+00 -0.0774 67 MgCl+ 0.24267E-14 -14.6150 0.20307E-14 -14.6924 0.83680E+00 -0.0774 68 MgF+ 0.69977E-16 -16.1550 0.58557E-16 -16.2324 0.83680E+00 -0.0774 69 MgOH+ 0.68824E-10 -10.1623 0.57592E-10 -10.2396 0.83680E+00 -0.0774 71 MnF+ 0.19178E-16 -16.7172 0.16048E-16 -16.7946 0.83680E+00 -0.0774 72 MnO,aq 0.17934E-08 -8.7463 0.17934E-08 -8.7463 0.10000E+01 0.0000 73 MnOH+ 0.46438E-09 -9.3331 0.38859E-09 -9.4105 0.83680E+00 -0.0774 74 MnO2-2 0.20857E-10 -10.6807 0.10808E-10 -10.9662 0.51820E+00 -0.2855 75 HMnO2- 0.21039E-09 -9.6770 0.17572E-09 -9.7552 0.83520E+00 -0.0782 78 MnCl+ 0.89654E-14 -14.0474 0.75022E-14 -14.1248 0.83680E+00 -0.0774 80 NaCl,aq 0.70215E-06 -6.1536 0.70215E-06 -6.1536 0.10000E+01 0.0000 81 NaF,aq 0.38792E-09 -9.4113 0.38792E-09 -9.4113 0.10000E+01 0.0000 82 NaOH,aq 0.96020E-04 -4.0176 0.96020E-04 -4.0176 0.10000E+01 0.0000 84 OH- 0.93392E-02 -2.0297 0.77860E-02 -2.1087 0.83369E+00 -0.0790 89 HPO3-2 0.13174E-14 -14.8803 0.68268E-15 -15.1658 0.51820E+00 -0.2855 91 H2PO3- 0.12163E-18 -18.9149 0.10159E-18 -18.9932 0.83520E+00 -0.0782 92 H3PO4,aq 0.90645E-18 -18.0427 0.90645E-18 -18.0427 0.10000E+01 0.0000 93 H2PO4- 0.38540E-10 -10.4141 0.32219E-10 -10.4919 0.83599E+00 -0.0778 94 PO4-3 0.10665E-08 -8.9721 0.25877E-09 -9.5871 0.24265E+00 -0.6150 98 HP2O7-3 0.94704E-18 -18.0236 0.21902E-18 -18.6595 0.23126E+00 -0.6359 99 P2O7-4 0.91441E-17 -17.0389 0.70508E-18 -18.1518 0.77108E-01 -1.1129 100 H2S,aq 0.55626E-08 -8.2547 0.55433E-08 -8.2562 0.99654E+00 -0.0015 101 S2-2 0.26838E-14 -14.5712 0.13908E-14 -14.8567 0.51820E+00 -0.2855 107 SO3-2 0.21052E-17 -17.6767 0.11067E-17 -17.9560 0.52570E+00 -0.2793 109 HSO4- 0.78119E-19 -19.1072 0.65433E-19 -19.1842 0.83761E+00 -0.0770 Charge balance for all species = -.6133E-08 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.8831508E-10 -.2229748E-01 -.2243547E+02 0.0000 2 H2O 0.1000000E+01 0.5550488E+02 0.9981994E+06 0.0000 3 Cl- 0.1529654E-03 0.1536679E-03 0.5438521E+01 6.2359 4 SO4-- 0.1761901E-11 -.1658009E-04 -.1589942E+01 8.2205 5 HCO3- 0.6614162E-06 0.1616383E-04 0.9845574E+00 3.8725 6 HS- 0.2893529E-04 0.4552095E-04 0.1502853E+01 5.5128 7 Al+++ 0.9695057E-29 0.5313761E-05 0.1431241E+00 0.7389 8 H4SiO4 0.6960881E-03 0.1353259E-01 0.1298430E+04 -3.1573 9 Ca++ 0.1321988E-06 0.2272333E-06 0.9091228E-02 13.0926 10 Mg++ 0.2111882E-10 0.9318283E-10 0.2261524E-05 9.2940 11 Fe++ 0.5429535E-13 0.3387394E-07 0.1888471E-02 6.7046 12 K+ 0.1565076E-03 0.1572615E-03 0.6138551E+01 6.2466 13 Na+ 0.1986009E-01 0.2230615E-01 0.5119228E+03 8.3492 14 Mn++ 0.1854822E-10 0.2507574E-08 0.1375217E-03 9.2385 15 F- 0.1198718E-06 0.1202599E-06 0.2280728E-02 3.1292 16 HPO4-- 0.4531555E-07 0.4642054E-07 0.4447655E-02 12.6308 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.2002439E-01 -.2002436E-01 -.2481174E-07 0.0000000E+00 2 H2O 0.4984643E+02 0.4984643E+02 -.1227823E-07 0.0000000E+00 3 Cl- 0.1380022E-03 0.1380022E-03 0.0000000E+00 0.0000000E+00 4 SO4-- -.1488956E-04 -.1488983E-04 0.2714518E-09 0.0000000E+00 5 HCO3- 0.1451600E-04 0.1451600E-04 0.0000000E+00 0.0000000E+00 6 HS- 0.4088003E-04 0.4088030E-04 -.2714518E-09 0.0000000E+00 7 Al+++ 0.4775352E-05 0.4772048E-05 0.3303555E-08 0.0000000E+00 8 H4SiO4 0.1215302E-01 0.1215301E-01 0.1240991E-07 0.0000000E+00 9 Ca++ 0.2080835E-06 0.2040679E-06 0.4015598E-08 0.0000000E+00 10 Mg++ 0.8368328E-10 0.8368328E-10 0.0000000E+00 0.0000000E+00 11 Fe++ 0.3259227E-07 0.3042066E-07 0.2171615E-08 0.0000000E+00 12 K+ 0.1412294E-03 0.1412294E-03 0.0000000E+00 0.0000000E+00 13 Na+ 0.2003215E-01 0.2003215E-01 0.2798105E-08 0.0000000E+00 14 Mn++ 0.2251939E-08 0.2251939E-08 0.0000000E+00 0.0000000E+00 15 F- 0.1080000E-06 0.1080000E-06 0.0000000E+00 0.0000000E+00 16 HPO4-- 0.4168819E-07 0.4168819E-07 0.0000000E+00 0.0000000E+00 Chg. balance for solid moles: 0.1241E-23 Mass of aqueous solution: 0.899618E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 0.0000200 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 0.2798E-08 -8.553 0.7337E-06 -6.134 52.43 0.2817E-06 andradite 0.1086E-08 -8.964 0.5518E-06 -6.258 39.43 0.1434E-06 grossular 0.2527E-09 -9.597 0.1138E-06 -6.944 8.135 0.3168E-07 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8112E+00 0.8112E+00 1.0000 -0.091 grossular 0.1888E+00 0.1888E+00 1.0000 -0.724 Solid products produced: Mass = 0.000001 g Volume = 0.000000 cm3 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.0000200 moles log = -4.6990 Original solution: 1000.0103000 g Original solution / Rock added: 50000515.00 (Water/Rock Ratio), log = 7.6990 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0536 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9688E+00 0.9855 0.1006E+01 0.1021E+01 CO2,gas 0.8847E-08 1.0069 0.9385E-08 0.9321E-08 CH4,gas 0.1959E-01 1.0124 0.2090E-01 0.2064E-01 H2,gas 0.1159E-01 1.0006 0.1222E-01 0.1221E-01 H2S,gas 0.1452E-06 0.9959 0.1524E-06 0.1530E-06 S2,gas 0.5540E-29 1.0000 0.5837E-29 0.5837E-29 CO,gas 0.2901E-13 1.0000 0.3056E-13 0.3056E-13 SO3,gas 0.1808E-47 1.0000 0.1905E-47 0.1905E-47 SO2,gas 0.8596E-27 1.0000 0.9057E-27 0.9057E-27 HF,gas 0.1183E-15 1.0000 0.1246E-15 0.1246E-15 HCl,gas 0.2909E-17 1.0000 0.3065E-17 0.3065E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 17 albite -0.38 -0.38 0.00 0.000 -0.94784E-12 23 andradite 39.01 39.01 0.00 0.000 0.12132E-10 24 grossular 32.73 32.73 0.00 0.000 0.36397E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -16.39 -9.73 -3.242 0.16608E+05 -8.028 3 CH4,gas 4.54 1.16 -3.38 -0.845 0.57694E+04 -1.680 4 H2,gas 8.00 4.39 -3.61 -2.064 0.61672E+04 -1.913 5 H2S,gas -6.23 -14.75 -8.52 -4.258 0.14541E+05 -6.817 6 S2,gas -7.34 -38.27 -30.93 -4.759 0.52817E+05 -29.234 7 CO,gas 3.21 -12.00 -15.21 -4.681 0.25977E+05 -13.515 8 SO3,gas 17.12 -32.30 -49.42 -12.355 0.84382E+05 -47.720 9 SO2,gas 0.83 -27.91 -28.74 -7.665 0.49076E+05 -27.043 10 HF,gas 0.47 -17.13 -17.60 -8.802 0.30057E+05 -15.904 11 HCl,gas 5.19 -14.02 -19.21 -9.606 0.32805E+05 -17.514 12 acmite 7.71 6.55 -1.16 -0.121 0.19883E+04 16 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 20 spessartine 24.46 19.72 -4.74 -0.237 0.80868E+04 21 analcite 3.32 2.77 -0.55 -0.061 0.93637E+03 27 annite 20.12 17.63 -2.50 -0.139 0.42621E+04 28 phlogopite 27.06 25.40 -1.67 -0.093 0.28498E+04 30 anorthite 12.71 8.26 -4.45 -0.343 0.76062E+04 33 apatite-OH -18.15 -18.20 -0.05 -0.004 0.78249E+02 34 apatite-F -34.30 -35.33 -1.03 -0.086 0.17558E+04 38 aragonite 0.97 -3.29 -4.26 -1.420 0.72749E+04 39 brucite 12.57 9.29 -3.27 -0.655 0.55912E+04 40 calcite 0.81 -3.29 -4.11 -1.369 0.70107E+04 41 carnegieite-low 9.02 5.93 -3.09 -0.442 0.52803E+04 42 carnegieite-high 10.09 5.93 -4.16 -0.595 0.71073E+04 43 carpholite-Mg 8.58 4.46 -4.12 -0.275 0.70433E+04 44 carpholite-Fe 6.71 1.87 -4.84 -0.323 0.82726E+04 45 celadonite 5.34 3.65 -1.69 -0.099 0.28881E+04 46 celadonite-Fe 3.88 1.06 -2.82 -0.166 0.48079E+04 47 chrysotile 23.89 21.57 -2.33 -0.194 0.39699E+04 49 clinochlore 39.07 38.48 -0.59 -0.019 0.10137E+04 50 daphnite 28.97 25.53 -3.44 -0.107 0.58678E+04 52 chlorite-Al-free 47.17 43.13 -4.04 -0.168 0.68950E+04 54 chloritoid-Fe 9.17 5.03 -4.15 -0.277 0.70836E+04 55 chloritoid-Mn 11.40 7.56 -3.84 -0.256 0.65604E+04 57 coesite -2.38 -3.16 -0.78 -0.260 0.13340E+04 64 cristobalite -2.56 -3.16 -0.60 -0.199 0.10194E+04 66 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71234E+04 68 diaspore 2.87 0.74 -2.13 -0.356 0.36451E+04 69 diamond -3.10 -7.61 -4.51 -1.288 0.76982E+04 70 diopside 16.18 16.07 -0.11 -0.011 0.18688E+03 71 hedenbergite 14.21 13.48 -0.73 -0.073 0.12393E+04 74 enstatite 17.26 12.27 -4.99 -0.499 0.85229E+04 76 clinoenstatite 17.17 12.27 -4.89 -0.489 0.83545E+04 78 epidote 24.67 22.70 -1.97 -0.095 0.33609E+04 79 clinozoisite 22.81 18.93 -3.88 -0.176 0.66186E+04 80 epidote-Fe 29.84 26.47 -3.37 -0.175 0.57499E+04 81 fayalite 14.05 10.25 -3.79 -0.542 0.64780E+04 82 ferrosilite 11.15 7.09 -4.05 -0.405 0.69237E+04 86 gibbsite 4.08 0.74 -3.34 -0.477 0.57037E+04 87 glaucophane 22.97 20.80 -2.18 -0.059 0.37140E+04 88 glaucophane-Fe 17.28 13.03 -4.24 -0.115 0.72473E+04 89 graphite -3.55 -7.61 -4.06 -1.161 0.69405E+04 90 greenalite 16.14 13.80 -2.34 -0.195 0.39962E+04 93 hematite 12.57 9.02 -3.54 -0.430 0.60528E+04 94 heulandite -5.83 -7.53 -1.70 -0.077 0.29091E+04 98 jadeite 4.22 2.77 -1.44 -0.144 0.24619E+04 100 kalsilite 7.58 3.83 -3.76 -0.537 0.64128E+04 101 kaolinite -1.33 -4.84 -3.50 -0.319 0.59832E+04 104 laumontite 2.88 1.94 -0.94 -0.063 0.16091E+04 105 lawsonite 9.62 8.26 -1.36 -0.091 0.23228E+04 106 leucite 4.12 0.67 -3.45 -0.345 0.58874E+04 108 lizardite 23.24 21.57 -1.68 -0.140 0.28625E+04 110 magnetite 20.09 15.73 -4.36 -0.356 0.74471E+04 111 minnesotaite 10.39 7.48 -2.90 -0.171 0.49580E+04 115 manganosite 14.06 9.24 -4.82 -1.205 0.82294E+04 119 microcline -2.49 -2.49 0.00 0.000 0.23905E-02 123 muscovite 2.58 -1.01 -3.59 -0.211 0.61318E+04 124 paragonite 4.24 1.09 -3.15 -0.185 0.53709E+04 125 nepheline 8.34 5.93 -2.41 -0.344 0.41127E+04 131 periclase-Fe 11.63 6.70 -4.92 -1.230 0.84042E+04 137 phlogopite-Na 29.65 27.50 -2.15 -0.119 0.36687E+04 139 prehnite 19.37 18.19 -1.18 -0.069 0.20165E+04 140 prehnite-Fe 22.50 21.96 -0.54 -0.032 0.91383E+03 141 pumpellyite-Fe 46.27 43.83 -2.44 -0.054 0.41733E+04 142 pumpellyite-Mg 48.99 46.41 -2.58 -0.057 0.44056E+04 146 pyrrhotite -4.26 -8.04 -3.78 -1.260 0.64566E+04 147 pyrrhotiteFe0.875 -6.02 -9.42 -3.41 -1.253 0.58172E+04 148 pyroxmangite 7.40 6.08 -1.32 -0.264 0.22496E+04 149 pyrophyllite -6.18 -11.15 -4.98 -0.311 0.84960E+04 150 quartz -2.99 -3.16 -0.17 -0.056 0.28669E+03 155 rhodonite 7.45 6.08 -1.36 -0.273 0.23299E+04 156 sanidine -1.28 -2.49 -1.21 -0.093 0.20678E+04 166 stilbite -7.52 -7.53 -0.01 0.000 0.15283E+02 167 stilpnomelane-Fe 13.02 12.87 -0.15 -0.005 0.25893E+03 168 stilpnomelane-Mg 27.44 25.81 -1.63 -0.049 0.27813E+04 174 talc 16.49 15.25 -1.24 -0.073 0.21145E+04 177 tephroite 18.09 15.32 -2.77 -0.395 0.47231E+04 181 tridymite -2.63 -3.16 -0.53 -0.177 0.90666E+03 182 tremolite 47.87 47.40 -0.47 -0.013 0.80718E+03 183 ferroactinolite 38.45 34.45 -4.00 -0.108 0.68350E+04 184 troilite-low -4.41 -8.04 -3.63 -1.210 0.61994E+04 186 vesuvianite 223.47 218.64 -4.83 -0.037 0.82444E+04 190 wairakite 3.95 1.94 -2.01 -0.118 0.34311E+04 191 walstromite 11.51 9.94 -1.57 -0.315 0.26876E+04 192 wollastonite 10.46 9.94 -0.53 -0.105 0.89799E+03 193 pseudo-wollastonite 11.00 9.94 -1.06 -0.213 0.18178E+04 194 zoisite 22.85 18.93 -3.92 -0.178 0.66926E+04 195 akaganeite 7.75 4.51 -3.24 -0.701 0.55389E+04 202 chalcedony -2.80 -3.16 -0.35 -0.118 0.60598E+03 204 montmorillonite-Ca -2.29 -6.17 -3.88 -0.240 0.66205E+04 205 montmorillonite-K -2.24 -6.27 -4.03 -0.247 0.68816E+04 206 montmorillonite-Mg -2.48 -6.79 -4.31 -0.267 0.73677E+04 207 montmorillonite-Na -2.04 -5.57 -3.54 -0.216 0.60365E+04 208 nontronite-Ca 3.21 -0.16 -3.38 -0.219 0.57654E+04 209 nontronite-H 2.53 -2.32 -4.85 -0.325 0.82897E+04 210 nontronite-K 3.34 -0.26 -3.60 -0.231 0.61496E+04 211 nontronite-Mg 3.07 -0.79 -3.86 -0.251 0.65966E+04 212 nontronite-Na 3.52 0.43 -3.09 -0.198 0.52705E+04 228 tobermorite 9.82 7.75 -2.07 -0.566 0.35418E+04 234 alabandite -0.98 -5.51 -4.53 -1.510 0.77347E+04 237 boehmite 4.41 0.74 -3.67 -0.611 0.62620E+04 239 ferrous-oxide 9.81 6.70 -3.11 -0.777 0.53051E+04 245 silica-amorphous -2.09 -3.16 -1.07 -0.355 0.18202E+04 247 an20ab80 2.02 1.34 -0.67 -0.052 0.11504E+04 248 an25ab75 2.65 1.78 -0.87 -0.067 0.14850E+04 249 an30ab70 3.28 2.21 -1.07 -0.082 0.18291E+04 250 tr.625ac.25prg.125 45.16 45.11 -0.06 -0.002 0.96788E+02 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 0.0000100 MOLES Current total amount of reactant added: 0.0000200 MOLES New total amount of reactant added: 0.0000300 MOLES Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.5508E-08 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 7 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 0.0000300 Water: Moles liquid = 0.4985E+02 kg liquid = 0.8981E+00 Moles total = 0.4985E+02 kg total = 0.8980E+00 Activity = 1.0000 Stoichiometric ionic strength = .1133214E-01 Osmotic coef. = 0.9693 True ionic strength = .2001887E-01 Chg. balance for total moles = -.5508E-08 Max. difference allowed = 0.1381E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.88328E-10 -10.0539 0.74218E-10 -10.1295 0.84025E+00 -0.0756 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.15303E-03 -3.8152 0.12781E-03 -3.8934 0.83520E+00 -0.0782 4 SO4-- 0.23986E-11 -11.6200 0.12456E-11 -11.9046 0.51930E+00 -0.2846 5 HCO3- 0.89929E-06 -6.0461 0.75219E-06 -6.1237 0.83642E+00 -0.0776 6 HS- 0.29206E-04 -4.5345 0.24396E-04 -4.6127 0.83532E+00 -0.0781 7 Al+++ 0.96969E-29 -29.0134 0.22403E-29 -29.6497 0.23103E+00 -0.6363 8 H4SiO4 0.69618E-03 -3.1573 0.69618E-03 -3.1573 0.10000E+01 0.0000 9 Ca++ 0.13125E-06 -6.8819 0.67660E-07 -7.1697 0.51549E+00 -0.2878 10 Mg++ 0.21119E-10 -10.6753 0.10837E-10 -10.9651 0.51313E+00 -0.2898 11 Fe++ 0.53034E-13 -13.2754 0.27243E-13 -13.5647 0.51370E+00 -0.2893 12 K+ 0.15651E-03 -3.8055 0.13094E-03 -3.8829 0.83662E+00 -0.0775 13 Na+ 0.19860E-01 -1.7020 0.16584E-01 -1.7803 0.83505E+00 -0.0783 14 Mn++ 0.18554E-10 -10.7316 0.95388E-11 -11.0205 0.51412E+00 -0.2889 15 F- 0.12431E-06 -6.9055 0.10361E-06 -6.9846 0.83348E+00 -0.0791 16 HPO4-- 0.45316E-07 -7.3438 0.23536E-07 -7.6283 0.51938E+00 -0.2845 18 HSiO3- 0.10487E-01 -1.9793 0.87588E-02 -2.0576 0.83520E+00 -0.0782 19 Ca(HSiO3)+ 0.16128E-07 -7.7924 0.13496E-07 -7.8698 0.83680E+00 -0.0774 20 Mg(HSiO3)+ 0.32149E-11 -11.4928 0.26902E-11 -11.5702 0.83680E+00 -0.0774 21 NaHSiO3,aq 0.23493E-02 -2.6291 0.23493E-02 -2.6291 0.10000E+01 0.0000 22 AlO+ 0.66121E-16 -16.1797 0.55330E-16 -16.2570 0.83680E+00 -0.0774 24 HAlO2,aq 0.14847E-09 -9.8284 0.14847E-09 -9.8284 0.10000E+01 0.0000 25 AlO2- 0.53114E-05 -5.2748 0.44281E-05 -5.3538 0.83369E+00 -0.0790 26 CH4,aq 0.14360E-04 -4.8428 0.14311E-04 -4.8443 0.99654E+00 -0.0015 27 C2H6,aq 0.40679E-14 -14.3906 0.40539E-14 -14.3921 0.99654E+00 -0.0015 31 CO,aq 0.25880E-16 -16.5870 0.25880E-16 -16.5870 0.10000E+01 0.0000 32 CO2,aq 0.11970E-09 -9.9219 0.11929E-09 -9.9234 0.99654E+00 -0.0015 33 CO3-2 0.17083E-05 -5.7674 0.88524E-06 -6.0529 0.51820E+00 -0.2855 34 CaCO3,aq 0.75102E-09 -9.1243 0.75102E-09 -9.1243 0.10000E+01 0.0000 35 Ca(HCO3)+ 0.15525E-11 -11.8090 0.12991E-11 -11.8864 0.83680E+00 -0.0774 36 CaCl+ 0.16724E-10 -10.7767 0.13995E-10 -10.8540 0.83680E+00 -0.0774 37 CaCl2,aq 0.42495E-15 -15.3717 0.42495E-15 -15.3717 0.10000E+01 0.0000 38 CaF+ 0.12231E-12 -12.9125 0.10235E-12 -12.9899 0.83680E+00 -0.0774 39 CaOH+ 0.77644E-07 -7.1099 0.64972E-07 -7.1873 0.83680E+00 -0.0774 40 CaSO4,aq 0.26762E-16 -16.5725 0.26762E-16 -16.5725 0.10000E+01 0.0000 41 HCl,aq 0.17382E-14 -14.7599 0.17382E-14 -14.7599 0.10000E+01 0.0000 45 HF,aq 0.52642E-13 -13.2787 0.52642E-13 -13.2787 0.10000E+01 0.0000 48 FeCl+ 0.65864E-17 -17.1814 0.55114E-17 -17.2587 0.83680E+00 -0.0774 51 FeF+ 0.17238E-18 -18.7635 0.14425E-18 -18.8409 0.83680E+00 -0.0774 53 FeO,aq 0.19223E-09 -9.7162 0.19223E-09 -9.7162 0.10000E+01 0.0000 54 FeOH+ 0.14279E-10 -10.8453 0.11949E-10 -10.9227 0.83680E+00 -0.0774 55 HFeO2- 0.32447E-07 -7.4888 0.27100E-07 -7.5670 0.83520E+00 -0.0782 56 FeO+ 0.11589E-16 -16.9359 0.96978E-17 -17.0133 0.83680E+00 -0.0774 58 FeO2- 0.43134E-09 -9.3652 0.36025E-09 -9.4434 0.83520E+00 -0.0782 59 HFeO2,aq 0.34005E-11 -11.4685 0.34005E-11 -11.4685 0.10000E+01 0.0000 60 H2,aq 0.86666E-05 -5.0622 0.86366E-05 -5.0637 0.99654E+00 -0.0015 61 KCl,aq 0.30331E-09 -9.5181 0.30331E-09 -9.5181 0.10000E+01 0.0000 63 KOH,aq 0.75342E-06 -6.1230 0.75342E-06 -6.1230 0.10000E+01 0.0000 64 KSO4- 0.30302E-14 -14.5185 0.25308E-14 -14.5967 0.83520E+00 -0.0782 65 MgCO3,aq 0.30152E-13 -13.5207 0.30152E-13 -13.5207 0.10000E+01 0.0000 66 Mg(HCO3)+ 0.25408E-15 -15.5950 0.21261E-15 -15.6724 0.83680E+00 -0.0774 67 MgCl+ 0.24278E-14 -14.6148 0.20316E-14 -14.6922 0.83680E+00 -0.0774 68 MgF+ 0.72570E-16 -16.1392 0.60727E-16 -16.2166 0.83680E+00 -0.0774 69 MgOH+ 0.68816E-10 -10.1623 0.57585E-10 -10.2397 0.83680E+00 -0.0774 71 MnF+ 0.19894E-16 -16.7013 0.16647E-16 -16.7787 0.83680E+00 -0.0774 72 MnO,aq 0.17934E-08 -8.7463 0.17934E-08 -8.7463 0.10000E+01 0.0000 73 MnOH+ 0.46444E-09 -9.3331 0.38864E-09 -9.4105 0.83680E+00 -0.0774 74 MnO2-2 0.20851E-10 -10.6809 0.10805E-10 -10.9664 0.51820E+00 -0.2855 75 HMnO2- 0.21036E-09 -9.6770 0.17569E-09 -9.7553 0.83520E+00 -0.0782 78 MnCl+ 0.89717E-14 -14.0471 0.75075E-14 -14.1245 0.83680E+00 -0.0774 80 NaCl,aq 0.70245E-06 -6.1534 0.70245E-06 -6.1534 0.10000E+01 0.0000 81 NaF,aq 0.40228E-09 -9.3955 0.40228E-09 -9.3955 0.10000E+01 0.0000 82 NaOH,aq 0.96006E-04 -4.0177 0.96006E-04 -4.0177 0.10000E+01 0.0000 84 OH- 0.93378E-02 -2.0298 0.77848E-02 -2.1088 0.83369E+00 -0.0790 89 HPO3-2 0.12224E-14 -14.9128 0.63346E-15 -15.1983 0.51820E+00 -0.2855 91 H2PO3- 0.11288E-18 -18.9474 0.94277E-19 -19.0256 0.83520E+00 -0.0782 92 H3PO4,aq 0.90671E-18 -18.0425 0.90671E-18 -18.0425 0.10000E+01 0.0000 93 H2PO4- 0.38545E-10 -10.4140 0.32223E-10 -10.4918 0.83599E+00 -0.0778 94 PO4-3 0.10663E-08 -8.9721 0.25874E-09 -9.5871 0.24265E+00 -0.6150 98 HP2O7-3 0.94719E-18 -18.0236 0.21905E-18 -18.6595 0.23126E+00 -0.6359 99 P2O7-4 0.91443E-17 -17.0388 0.70508E-18 -18.1518 0.77106E-01 -1.1129 100 H2S,aq 0.56154E-08 -8.2506 0.55960E-08 -8.2521 0.99654E+00 -0.0015 101 S2-2 0.29467E-14 -14.5307 0.15270E-14 -14.8162 0.51820E+00 -0.2855 107 SO3-2 0.26592E-17 -17.5752 0.13979E-17 -17.8545 0.52570E+00 -0.2793 109 HSO4- 0.10636E-18 -18.9732 0.89090E-19 -19.0502 0.83761E+00 -0.0770 Charge balance for all species = -.6133E-08 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.8832828E-10 -.2229627E-01 -.2243425E+02 0.0000 2 H2O 0.1000000E+01 0.5550488E+02 0.9981994E+06 0.0000 3 Cl- 0.1530308E-03 0.1537336E-03 0.5440845E+01 6.2361 4 SO4-- 0.2398565E-11 -.1652702E-04 -.1584853E+01 8.3544 5 HCO3- 0.8992949E-06 0.1696890E-04 0.1033595E+01 4.0058 6 HS- 0.2920581E-04 0.4573845E-04 0.1510033E+01 5.5168 7 Al+++ 0.9696909E-29 0.5311563E-05 0.1430649E+00 0.7388 8 H4SiO4 0.6961845E-03 0.1353258E-01 0.1298429E+04 -3.1573 9 Ca++ 0.1312539E-06 0.2257959E-06 0.9033723E-02 13.0893 10 Mg++ 0.2111938E-10 0.9318281E-10 0.2261523E-05 9.2939 11 Fe++ 0.5303428E-13 0.3308833E-07 0.1844673E-02 6.6942 12 K+ 0.1565077E-03 0.1572614E-03 0.6138550E+01 6.2466 13 Na+ 0.1986012E-01 0.2230615E-01 0.5119227E+03 8.3492 14 Mn++ 0.1855354E-10 0.2507574E-08 0.1375217E-03 9.2385 15 F- 0.1243115E-06 0.1247140E-06 0.2365199E-02 3.1449 16 HPO4-- 0.4531568E-07 0.4642053E-07 0.4447654E-02 12.6307 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.2002331E-01 -.2002327E-01 -.3645170E-07 0.0000000E+00 2 H2O 0.4984643E+02 0.4984643E+02 -.1990166E-07 0.0000000E+00 3 Cl- 0.1380612E-03 0.1380612E-03 0.0000000E+00 0.0000000E+00 4 SO4-- -.1484181E-04 -.1484217E-04 0.3596414E-09 0.0000000E+00 5 HCO3- 0.1523900E-04 0.1523900E-04 0.0000000E+00 0.0000000E+00 6 HS- 0.4107528E-04 0.4107564E-04 -.3596414E-09 0.0000000E+00 7 Al+++ 0.4775352E-05 0.4770076E-05 0.5276205E-08 0.0000000E+00 8 H4SiO4 0.1215302E-01 0.1215300E-01 0.1915366E-07 0.0000000E+00 9 Ca++ 0.2080835E-06 0.2027772E-06 0.5306344E-08 0.0000000E+00 10 Mg++ 0.8368328E-10 0.8368328E-10 0.0000000E+00 0.0000000E+00 11 Fe++ 0.3259227E-07 0.2971514E-07 0.2877131E-08 0.0000000E+00 12 K+ 0.1412294E-03 0.1412294E-03 0.0000000E+00 0.0000000E+00 13 Na+ 0.2003215E-01 0.2003215E-01 0.4615773E-08 0.0000000E+00 14 Mn++ 0.2251939E-08 0.2251939E-08 0.0000000E+00 0.0000000E+00 15 F- 0.1120000E-06 0.1120000E-06 0.0000000E+00 0.0000000E+00 16 HPO4-- 0.4168819E-07 0.4168819E-07 0.0000000E+00 0.0000000E+00 Chg. balance for solid moles: -.4136E-23 Mass of aqueous solution: 0.899618E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 0.0000300 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 0.4616E-08 -8.336 0.1210E-05 -5.917 57.91 0.4646E-06 andradite 0.1439E-08 -8.842 0.7311E-06 -6.136 34.98 0.1899E-06 grossular 0.3302E-09 -9.481 0.1487E-06 -6.828 7.117 0.4139E-07 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8133E+00 0.8133E+00 1.0000 -0.090 grossular 0.1867E+00 0.1867E+00 1.0000 -0.729 Solid products produced: Mass = 0.000002 g Volume = 0.000001 cm3 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.0000300 moles log = -4.5229 Original solution: 1000.0103000 g Original solution / Rock added: 33333676.67 (Water/Rock Ratio), log = 7.5229 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0529 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9695E+00 0.9855 0.1006E+01 0.1021E+01 CO2,gas 0.1204E-07 1.0069 0.1276E-07 0.1268E-07 CH4,gas 0.1976E-01 1.0124 0.2106E-01 0.2081E-01 H2,gas 0.1076E-01 1.0006 0.1134E-01 0.1133E-01 H2S,gas 0.1467E-06 0.9959 0.1538E-06 0.1545E-06 S2,gas 0.6562E-29 1.0000 0.6909E-29 0.6909E-29 CO,gas 0.3663E-13 1.0000 0.3857E-13 0.3857E-13 SO3,gas 0.2464E-47 1.0000 0.2594E-47 0.2594E-47 SO2,gas 0.1087E-26 1.0000 0.1144E-26 0.1144E-26 HF,gas 0.1228E-15 1.0000 0.1293E-15 0.1293E-15 HCl,gas 0.2913E-17 1.0000 0.3067E-17 0.3067E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 17 albite -0.38 -0.38 0.00 0.000 0.11184E-10 23 andradite 39.01 39.01 0.00 0.000 0.12132E-10 24 grossular 32.73 32.73 0.00 0.000 0.00000E+00 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -16.25 -9.59 -3.198 0.16380E+05 -7.894 3 CH4,gas 4.54 1.17 -3.38 -0.844 0.57634E+04 -1.676 4 H2,gas 8.00 4.36 -3.64 -2.083 0.62227E+04 -1.945 5 H2S,gas -6.23 -14.74 -8.51 -4.256 0.14534E+05 -6.813 6 S2,gas -7.34 -38.20 -30.86 -4.748 0.52692E+05 -29.161 7 CO,gas 3.21 -11.90 -15.11 -4.650 0.25805E+05 -13.414 8 SO3,gas 17.12 -32.16 -49.28 -12.321 0.84153E+05 -47.586 9 SO2,gas 0.83 -27.81 -28.64 -7.637 0.48903E+05 -26.941 10 HF,gas 0.47 -17.11 -17.59 -8.794 0.30030E+05 -15.889 11 HCl,gas 5.19 -14.02 -19.21 -9.606 0.32804E+05 -17.513 12 acmite 7.71 6.55 -1.16 -0.120 0.19781E+04 16 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 20 spessartine 24.46 19.72 -4.74 -0.237 0.80869E+04 21 analcite 3.32 2.77 -0.55 -0.061 0.93647E+03 27 annite 20.12 17.60 -2.53 -0.140 0.43150E+04 28 phlogopite 27.06 25.40 -1.67 -0.093 0.28505E+04 30 anorthite 12.71 8.25 -4.46 -0.343 0.76119E+04 33 apatite-OH -18.15 -18.22 -0.06 -0.005 0.10532E+03 34 apatite-F -34.30 -35.33 -1.03 -0.086 0.17557E+04 38 aragonite 0.97 -3.16 -4.13 -1.377 0.70525E+04 39 brucite 12.57 9.29 -3.27 -0.655 0.55914E+04 40 calcite 0.81 -3.16 -3.98 -1.325 0.67883E+04 41 carnegieite-low 9.02 5.93 -3.09 -0.442 0.52806E+04 42 carnegieite-high 10.09 5.93 -4.16 -0.595 0.71075E+04 43 carpholite-Mg 8.58 4.46 -4.13 -0.275 0.70437E+04 44 carpholite-Fe 6.71 1.86 -4.86 -0.324 0.82904E+04 45 celadonite 5.34 3.65 -1.69 -0.099 0.28882E+04 46 celadonite-Fe 3.88 1.05 -2.83 -0.166 0.48254E+04 47 chrysotile 23.89 21.57 -2.33 -0.194 0.39703E+04 49 clinochlore 39.07 38.48 -0.59 -0.019 0.10148E+04 50 daphnite 28.97 25.48 -3.49 -0.109 0.59561E+04 52 chlorite-Al-free 47.17 43.13 -4.04 -0.168 0.68958E+04 54 chloritoid-Fe 9.17 5.01 -4.16 -0.277 0.71015E+04 55 chloritoid-Mn 11.40 7.56 -3.84 -0.256 0.65607E+04 57 coesite -2.38 -3.16 -0.78 -0.260 0.13339E+04 64 cristobalite -2.56 -3.16 -0.60 -0.199 0.10193E+04 66 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71234E+04 68 diaspore 2.87 0.74 -2.13 -0.356 0.36453E+04 69 diamond -3.10 -7.54 -4.44 -1.269 0.75813E+04 70 diopside 16.18 16.07 -0.11 -0.011 0.19242E+03 71 hedenbergite 14.21 13.47 -0.74 -0.074 0.12623E+04 74 enstatite 17.26 12.27 -4.99 -0.499 0.85231E+04 76 clinoenstatite 17.17 12.27 -4.89 -0.489 0.83547E+04 78 epidote 24.67 22.70 -1.97 -0.095 0.33620E+04 79 clinozoisite 22.81 18.92 -3.88 -0.176 0.66299E+04 80 epidote-Fe 29.84 26.48 -3.36 -0.175 0.57407E+04 81 fayalite 14.05 10.23 -3.81 -0.545 0.65132E+04 82 ferrosilite 11.15 7.07 -4.08 -0.408 0.69588E+04 86 gibbsite 4.08 0.74 -3.34 -0.477 0.57039E+04 87 glaucophane 22.97 20.80 -2.18 -0.059 0.37144E+04 88 glaucophane-Fe 17.28 13.00 -4.28 -0.116 0.73001E+04 89 graphite -3.55 -7.54 -4.00 -1.142 0.68235E+04 90 greenalite 16.14 13.77 -2.37 -0.198 0.40490E+04 93 hematite 12.57 9.03 -3.53 -0.428 0.60326E+04 94 heulandite -5.83 -7.53 -1.71 -0.078 0.29143E+04 98 jadeite 4.22 2.77 -1.44 -0.144 0.24620E+04 100 kalsilite 7.58 3.83 -3.76 -0.537 0.64130E+04 101 kaolinite -1.33 -4.84 -3.50 -0.319 0.59834E+04 104 laumontite 2.88 1.94 -0.95 -0.063 0.16147E+04 105 lawsonite 9.62 8.25 -1.36 -0.091 0.23286E+04 106 leucite 4.12 0.67 -3.45 -0.345 0.58875E+04 108 lizardite 23.24 21.57 -1.68 -0.140 0.28629E+04 110 magnetite 20.09 15.73 -4.36 -0.356 0.74446E+04 111 minnesotaite 10.39 7.45 -2.93 -0.173 0.50105E+04 115 manganosite 14.06 9.24 -4.82 -1.205 0.82294E+04 119 microcline -2.49 -2.49 0.00 0.000 0.31030E-02 123 muscovite 2.58 -1.01 -3.59 -0.211 0.61322E+04 124 paragonite 4.24 1.09 -3.15 -0.185 0.53713E+04 125 nepheline 8.34 5.93 -2.41 -0.344 0.41129E+04 131 periclase-Fe 11.63 6.69 -4.93 -1.233 0.84218E+04 137 phlogopite-Na 29.65 27.50 -2.15 -0.119 0.36693E+04 139 prehnite 19.37 18.18 -1.19 -0.070 0.20277E+04 140 prehnite-Fe 22.50 21.96 -0.54 -0.032 0.91471E+03 141 pumpellyite-Fe 46.27 43.80 -2.47 -0.055 0.42135E+04 142 pumpellyite-Mg 48.99 46.40 -2.59 -0.058 0.44283E+04 146 pyrrhotite -4.26 -8.05 -3.79 -1.263 0.64672E+04 147 pyrrhotiteFe0.875 -6.02 -9.42 -3.41 -1.253 0.58188E+04 148 pyroxmangite 7.40 6.08 -1.32 -0.263 0.22496E+04 149 pyrophyllite -6.18 -11.15 -4.98 -0.311 0.84960E+04 150 quartz -2.99 -3.16 -0.17 -0.056 0.28658E+03 155 rhodonite 7.45 6.08 -1.36 -0.273 0.23298E+04 156 sanidine -1.28 -2.49 -1.21 -0.093 0.20678E+04 166 stilbite -7.52 -7.53 -0.01 -0.001 0.20505E+02 167 stilpnomelane-Fe 13.02 12.81 -0.20 -0.006 0.34681E+03 168 stilpnomelane-Mg 27.44 25.81 -1.63 -0.049 0.27820E+04 174 talc 16.49 15.25 -1.24 -0.073 0.21147E+04 177 tephroite 18.09 15.32 -2.77 -0.395 0.47231E+04 181 tridymite -2.63 -3.16 -0.53 -0.177 0.90656E+03 182 tremolite 47.87 47.39 -0.48 -0.013 0.81846E+03 183 ferroactinolite 38.45 34.39 -4.06 -0.110 0.69335E+04 184 troilite-low -4.41 -8.05 -3.64 -1.212 0.62100E+04 186 vesuvianite 223.47 218.58 -4.89 -0.037 0.83505E+04 190 wairakite 3.95 1.94 -2.01 -0.118 0.34366E+04 191 walstromite 11.51 9.93 -1.58 -0.315 0.26930E+04 192 wollastonite 10.46 9.93 -0.53 -0.106 0.90343E+03 193 pseudo-wollastonite 11.00 9.93 -1.07 -0.214 0.18233E+04 194 zoisite 22.85 18.92 -3.93 -0.178 0.67040E+04 195 akaganeite 7.75 4.52 -3.24 -0.700 0.55288E+04 202 chalcedony -2.80 -3.16 -0.35 -0.118 0.60588E+03 204 montmorillonite-Ca -2.29 -6.17 -3.88 -0.240 0.66214E+04 205 montmorillonite-K -2.24 -6.27 -4.03 -0.247 0.68816E+04 206 montmorillonite-Mg -2.48 -6.79 -4.31 -0.267 0.73677E+04 207 montmorillonite-Na -2.04 -5.57 -3.54 -0.216 0.60365E+04 208 nontronite-Ca 3.21 -0.15 -3.37 -0.218 0.57458E+04 209 nontronite-H 2.53 -2.31 -4.84 -0.325 0.82692E+04 210 nontronite-K 3.34 -0.25 -3.59 -0.230 0.61292E+04 211 nontronite-Mg 3.07 -0.78 -3.85 -0.250 0.65762E+04 212 nontronite-Na 3.52 0.44 -3.07 -0.197 0.52500E+04 228 tobermorite 9.82 7.75 -2.08 -0.567 0.35463E+04 234 alabandite -0.98 -5.50 -4.53 -1.509 0.77277E+04 237 boehmite 4.41 0.74 -3.67 -0.611 0.62622E+04 239 ferrous-oxide 9.81 6.69 -3.12 -0.779 0.53228E+04 245 silica-amorphous -2.09 -3.16 -1.07 -0.355 0.18201E+04 247 an20ab80 2.02 1.34 -0.67 -0.052 0.11515E+04 248 an25ab75 2.65 1.78 -0.87 -0.067 0.14864E+04 249 an30ab70 3.28 2.21 -1.07 -0.082 0.18309E+04 250 tr.625ac.25prg.125 45.16 45.09 -0.08 -0.002 0.12997E+03 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 0.0000100 MOLES Current total amount of reactant added: 0.0000300 MOLES New total amount of reactant added: 0.0000400 MOLES Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.5508E-08 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 6 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 0.0000400 Water: Moles liquid = 0.4985E+02 kg liquid = 0.8981E+00 Moles total = 0.4985E+02 kg total = 0.8980E+00 Activity = 1.0000 Stoichiometric ionic strength = .1133277E-01 Osmotic coef. = 0.9692 True ionic strength = .2001938E-01 Chg. balance for total moles = -.5508E-08 Max. difference allowed = 0.1381E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.88342E-10 -10.0538 0.74229E-10 -10.1294 0.84025E+00 -0.0756 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.15310E-03 -3.8150 0.12787E-03 -3.8932 0.83520E+00 -0.0782 4 SO4-- 0.30835E-11 -11.5110 0.16013E-11 -11.7955 0.51930E+00 -0.2846 5 HCO3- 0.11514E-05 -5.9388 0.96305E-06 -6.0164 0.83642E+00 -0.0776 6 HS- 0.29476E-04 -4.5305 0.24622E-04 -4.6087 0.83532E+00 -0.0781 7 Al+++ 0.96988E-29 -29.0133 0.22407E-29 -29.6496 0.23102E+00 -0.6363 8 H4SiO4 0.69629E-03 -3.1572 0.69629E-03 -3.1572 0.10000E+01 0.0000 9 Ca++ 0.13049E-06 -6.8844 0.67264E-07 -7.1722 0.51549E+00 -0.2878 10 Mg++ 0.21120E-10 -10.6753 0.10837E-10 -10.9651 0.51313E+00 -0.2898 11 Fe++ 0.52048E-13 -13.2836 0.26737E-13 -13.5729 0.51369E+00 -0.2893 12 K+ 0.15651E-03 -3.8055 0.13094E-03 -3.8829 0.83662E+00 -0.0775 13 Na+ 0.19860E-01 -1.7020 0.16584E-01 -1.7803 0.83504E+00 -0.0783 14 Mn++ 0.18559E-10 -10.7314 0.95416E-11 -11.0204 0.51412E+00 -0.2889 15 F- 0.12875E-06 -6.8902 0.10731E-06 -6.9694 0.83347E+00 -0.0791 16 HPO4-- 0.45316E-07 -7.3438 0.23536E-07 -7.6283 0.51937E+00 -0.2845 18 HSiO3- 0.10487E-01 -1.9793 0.87587E-02 -2.0576 0.83520E+00 -0.0782 19 Ca(HSiO3)+ 0.16034E-07 -7.7950 0.13417E-07 -7.8723 0.83680E+00 -0.0774 20 Mg(HSiO3)+ 0.32150E-11 -11.4928 0.26903E-11 -11.5702 0.83680E+00 -0.0774 21 NaHSiO3,aq 0.23493E-02 -2.6291 0.23493E-02 -2.6291 0.10000E+01 0.0000 22 AlO+ 0.66113E-16 -16.1797 0.55323E-16 -16.2571 0.83680E+00 -0.0774 24 HAlO2,aq 0.14842E-09 -9.8285 0.14842E-09 -9.8285 0.10000E+01 0.0000 25 AlO2- 0.53091E-05 -5.2750 0.44261E-05 -5.3540 0.83369E+00 -0.0790 26 CH4,aq 0.14435E-04 -4.8406 0.14385E-04 -4.8421 0.99654E+00 -0.0015 27 C2H6,aq 0.43665E-14 -14.3599 0.43514E-14 -14.3614 0.99654E+00 -0.0015 31 CO,aq 0.31194E-16 -16.5059 0.31194E-16 -16.5059 0.10000E+01 0.0000 32 CO2,aq 0.15328E-09 -9.8145 0.15275E-09 -9.8160 0.99654E+00 -0.0015 33 CO3-2 0.21869E-05 -5.6602 0.11332E-05 -5.9457 0.51820E+00 -0.2855 34 CaCO3,aq 0.95578E-09 -9.0196 0.95578E-09 -9.0196 0.10000E+01 0.0000 35 Ca(HCO3)+ 0.19760E-11 -11.7042 0.16535E-11 -11.7816 0.83680E+00 -0.0774 36 CaCl+ 0.16633E-10 -10.7790 0.13919E-10 -10.8564 0.83680E+00 -0.0774 37 CaCl2,aq 0.42282E-15 -15.3738 0.42282E-15 -15.3738 0.10000E+01 0.0000 38 CaF+ 0.12594E-12 -12.8998 0.10539E-12 -12.9772 0.83680E+00 -0.0774 39 CaOH+ 0.77178E-07 -7.1125 0.64582E-07 -7.1899 0.83680E+00 -0.0774 40 CaSO4,aq 0.34202E-16 -16.4659 0.34202E-16 -16.4659 0.10000E+01 0.0000 41 HCl,aq 0.17392E-14 -14.7596 0.17392E-14 -14.7596 0.10000E+01 0.0000 45 HF,aq 0.54530E-13 -13.2634 0.54530E-13 -13.2634 0.10000E+01 0.0000 48 FeCl+ 0.64666E-17 -17.1893 0.54113E-17 -17.2667 0.83680E+00 -0.0774 51 FeF+ 0.17521E-18 -18.7564 0.14662E-18 -18.8338 0.83680E+00 -0.0774 53 FeO,aq 0.18859E-09 -9.7245 0.18859E-09 -9.7245 0.10000E+01 0.0000 54 FeOH+ 0.14011E-10 -10.8535 0.11725E-10 -10.9309 0.83680E+00 -0.0774 55 HFeO2- 0.31829E-07 -7.4972 0.26583E-07 -7.5754 0.83520E+00 -0.0782 56 FeO+ 0.11721E-16 -16.9310 0.98084E-17 -17.0084 0.83680E+00 -0.0774 58 FeO2- 0.43612E-09 -9.3604 0.36425E-09 -9.4386 0.83520E+00 -0.0782 59 HFeO2,aq 0.34388E-11 -11.4636 0.34388E-11 -11.4636 0.10000E+01 0.0000 60 H2,aq 0.81575E-05 -5.0884 0.81293E-05 -5.0899 0.99654E+00 -0.0015 61 KCl,aq 0.30344E-09 -9.5179 0.30344E-09 -9.5179 0.10000E+01 0.0000 63 KOH,aq 0.75331E-06 -6.1230 0.75331E-06 -6.1230 0.10000E+01 0.0000 64 KSO4- 0.38955E-14 -14.4094 0.32535E-14 -14.4877 0.83520E+00 -0.0782 65 MgCO3,aq 0.38599E-13 -13.4134 0.38599E-13 -13.4134 0.10000E+01 0.0000 66 Mg(HCO3)+ 0.32532E-15 -15.4877 0.27222E-15 -15.5651 0.83680E+00 -0.0774 67 MgCl+ 0.24289E-14 -14.6146 0.20325E-14 -14.6920 0.83680E+00 -0.0774 68 MgF+ 0.75164E-16 -16.1240 0.62897E-16 -16.2014 0.83680E+00 -0.0774 69 MgOH+ 0.68806E-10 -10.1624 0.57577E-10 -10.2398 0.83680E+00 -0.0774 71 MnF+ 0.20610E-16 -16.6859 0.17246E-16 -16.7633 0.83680E+00 -0.0774 72 MnO,aq 0.17933E-08 -8.7463 0.17933E-08 -8.7463 0.10000E+01 0.0000 73 MnOH+ 0.46450E-09 -9.3330 0.38870E-09 -9.4104 0.83680E+00 -0.0774 74 MnO2-2 0.20844E-10 -10.6810 0.10801E-10 -10.9665 0.51820E+00 -0.2855 75 HMnO2- 0.21032E-09 -9.6771 0.17566E-09 -9.7553 0.83520E+00 -0.0782 78 MnCl+ 0.89782E-14 -14.0468 0.75129E-14 -14.1242 0.83680E+00 -0.0774 80 NaCl,aq 0.70275E-06 -6.1532 0.70275E-06 -6.1532 0.10000E+01 0.0000 81 NaF,aq 0.41665E-09 -9.3802 0.41665E-09 -9.3802 0.10000E+01 0.0000 82 NaOH,aq 0.95991E-04 -4.0178 0.95991E-04 -4.0178 0.10000E+01 0.0000 84 OH- 0.93364E-02 -2.0298 0.77836E-02 -2.1088 0.83369E+00 -0.0790 89 HPO3-2 0.11506E-14 -14.9391 0.59625E-15 -15.2246 0.51820E+00 -0.2855 91 H2PO3- 0.10627E-18 -18.9736 0.88753E-19 -19.0518 0.83520E+00 -0.0782 92 H3PO4,aq 0.90699E-18 -18.0424 0.90699E-18 -18.0424 0.10000E+01 0.0000 93 H2PO4- 0.38551E-10 -10.4140 0.32228E-10 -10.4918 0.83599E+00 -0.0778 94 PO4-3 0.10661E-08 -8.9722 0.25869E-09 -9.5872 0.24264E+00 -0.6150 98 HP2O7-3 0.94734E-18 -18.0235 0.21908E-18 -18.6594 0.23126E+00 -0.6359 99 P2O7-4 0.91445E-17 -17.0388 0.70507E-18 -18.1518 0.77104E-01 -1.1129 100 H2S,aq 0.56683E-08 -8.2465 0.56487E-08 -8.2481 0.99654E+00 -0.0015 101 S2-2 0.31888E-14 -14.4964 0.16524E-14 -14.7819 0.51820E+00 -0.2855 107 SO3-2 0.32178E-17 -17.4924 0.16916E-17 -17.7717 0.52569E+00 -0.2793 109 HSO4- 0.13676E-18 -18.8641 0.11455E-18 -18.9410 0.83761E+00 -0.0770 Charge balance for all species = -.6133E-08 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.8834209E-10 -.2229505E-01 -.2243302E+02 0.0000 2 H2O 0.1000000E+01 0.5550488E+02 0.9981993E+06 0.0000 3 Cl- 0.1530962E-03 0.1537992E-03 0.5443169E+01 6.2362 4 SO4-- 0.3083496E-11 -.1647392E-04 -.1579761E+01 8.4633 5 HCO3- 0.1151398E-05 0.1777396E-04 0.1082633E+01 4.1131 6 HS- 0.2947634E-04 0.4595593E-04 0.1517213E+01 5.5208 7 Al+++ 0.9698849E-29 0.5309266E-05 0.1430030E+00 0.7387 8 H4SiO4 0.6962853E-03 0.1353257E-01 0.1298428E+04 -3.1572 9 Ca++ 0.1304864E-06 0.2246726E-06 0.8988780E-02 13.0866 10 Mg++ 0.2111996E-10 0.9318279E-10 0.2261523E-05 9.2938 11 Fe++ 0.5204841E-13 0.3247113E-07 0.1810264E-02 6.6860 12 K+ 0.1565078E-03 0.1572614E-03 0.6138549E+01 6.2465 13 Na+ 0.1986015E-01 0.2230614E-01 0.5119225E+03 8.3491 14 Mn++ 0.1855911E-10 0.2507573E-08 0.1375217E-03 9.2385 15 F- 0.1287512E-06 0.1291680E-06 0.2449669E-02 3.1601 16 HPO4-- 0.4531582E-07 0.4642053E-07 0.4447653E-02 12.6306 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.2002223E-01 -.2002219E-01 -.4764027E-07 0.0000000E+00 2 H2O 0.4984644E+02 0.4984644E+02 -.2795579E-07 0.0000000E+00 3 Cl- 0.1381202E-03 0.1381202E-03 0.0000000E+00 0.0000000E+00 4 SO4-- -.1479406E-04 -.1479449E-04 0.4289252E-09 0.0000000E+00 5 HCO3- 0.1596200E-04 0.1596200E-04 0.0000000E+00 0.0000000E+00 6 HS- 0.4127053E-04 0.4127096E-04 -.4289252E-09 0.0000000E+00 7 Al+++ 0.4775352E-05 0.4768013E-05 0.7338705E-08 0.0000000E+00 8 H4SiO4 0.1215302E-01 0.1215299E-01 0.2599519E-07 0.0000000E+00 9 Ca++ 0.2080835E-06 0.2017684E-06 0.6315129E-08 0.0000000E+00 10 Mg++ 0.8368328E-10 0.8368328E-10 0.0000000E+00 0.0000000E+00 11 Fe++ 0.3259227E-07 0.2916087E-07 0.3431402E-08 0.0000000E+00 12 K+ 0.1412294E-03 0.1412294E-03 0.0000000E+00 0.0000000E+00 13 Na+ 0.2003215E-01 0.2003214E-01 0.6560021E-08 0.0000000E+00 14 Mn++ 0.2251939E-08 0.2251939E-08 0.0000000E+00 0.0000000E+00 15 F- 0.1160000E-06 0.1160000E-06 0.0000000E+00 0.0000000E+00 16 HPO4-- 0.4168819E-07 0.4168819E-07 0.0000000E+00 0.0000000E+00 Chg. balance for solid moles: -.8272E-24 Mass of aqueous solution: 0.899619E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 0.0000400 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 0.6560E-08 -8.183 0.1720E-05 -5.764 62.16 0.6603E-06 andradite 0.1716E-08 -8.766 0.8719E-06 -6.060 31.51 0.2265E-06 grossular 0.3893E-09 -9.410 0.1754E-06 -6.756 6.337 0.4880E-07 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8150E+00 0.8150E+00 1.0000 -0.089 grossular 0.1850E+00 0.1850E+00 1.0000 -0.733 Solid products produced: Mass = 0.000003 g Volume = 0.000001 cm3 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.0000400 moles log = -4.3979 Original solution: 1000.0103000 g Original solution / Rock added: 25000257.50 (Water/Rock Ratio), log = 7.3979 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0523 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9700E+00 0.9855 0.1006E+01 0.1021E+01 CO2,gas 0.1542E-07 1.0069 0.1634E-07 0.1623E-07 CH4,gas 0.1987E-01 1.0124 0.2117E-01 0.2091E-01 H2,gas 0.1014E-01 1.0006 0.1067E-01 0.1067E-01 H2S,gas 0.1482E-06 0.9959 0.1553E-06 0.1559E-06 S2,gas 0.7550E-29 1.0000 0.7945E-29 0.7945E-29 CO,gas 0.4417E-13 1.0000 0.4649E-13 0.4649E-13 SO3,gas 0.3170E-47 1.0000 0.3336E-47 0.3336E-47 SO2,gas 0.1316E-26 1.0000 0.1385E-26 0.1385E-26 HF,gas 0.1272E-15 1.0000 0.1339E-15 0.1339E-15 HCl,gas 0.2916E-17 1.0000 0.3069E-17 0.3069E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 17 albite -0.38 -0.38 0.00 0.000 -0.94784E-12 23 andradite 39.01 39.01 0.00 0.000 -0.12132E-10 24 grossular 32.73 32.73 0.00 0.000 0.00000E+00 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -16.15 -9.49 -3.162 0.16196E+05 -7.787 3 CH4,gas 4.54 1.17 -3.37 -0.843 0.57596E+04 -1.674 4 H2,gas 8.00 4.33 -3.67 -2.098 0.62676E+04 -1.972 5 H2S,gas -6.23 -14.74 -8.51 -4.254 0.14527E+05 -6.809 6 S2,gas -7.34 -38.13 -30.80 -4.738 0.52588E+05 -29.100 7 CO,gas 3.21 -11.82 -15.03 -4.625 0.25666E+05 -13.333 8 SO3,gas 17.12 -32.05 -49.18 -12.294 0.83966E+05 -47.477 9 SO2,gas 0.83 -27.73 -28.56 -7.615 0.48761E+05 -26.858 10 HF,gas 0.47 -17.10 -17.57 -8.786 0.30004E+05 -15.873 11 HCl,gas 5.19 -14.02 -19.21 -9.606 0.32804E+05 -17.513 12 acmite 7.71 6.56 -1.15 -0.120 0.19697E+04 16 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 20 spessartine 24.46 19.72 -4.74 -0.237 0.80870E+04 21 analcite 3.32 2.77 -0.55 -0.061 0.93658E+03 27 annite 20.12 17.57 -2.55 -0.142 0.43575E+04 28 phlogopite 27.06 25.39 -1.67 -0.093 0.28511E+04 30 anorthite 12.71 8.25 -4.46 -0.343 0.76167E+04 33 apatite-OH -18.15 -18.23 -0.07 -0.006 0.12755E+03 34 apatite-F -34.30 -35.33 -1.03 -0.085 0.17518E+04 38 aragonite 0.97 -3.06 -4.03 -1.342 0.68737E+04 39 brucite 12.57 9.29 -3.27 -0.655 0.55916E+04 40 calcite 0.81 -3.06 -3.87 -1.290 0.66095E+04 41 carnegieite-low 9.02 5.93 -3.09 -0.442 0.52808E+04 42 carnegieite-high 10.09 5.93 -4.16 -0.595 0.71078E+04 43 carpholite-Mg 8.58 4.46 -4.13 -0.275 0.70441E+04 44 carpholite-Fe 6.71 1.85 -4.86 -0.324 0.83048E+04 45 celadonite 5.34 3.65 -1.69 -0.100 0.28883E+04 46 celadonite-Fe 3.88 1.04 -2.83 -0.167 0.48394E+04 47 chrysotile 23.89 21.57 -2.33 -0.194 0.39707E+04 49 clinochlore 39.07 38.47 -0.59 -0.019 0.10159E+04 50 daphnite 28.97 25.44 -3.53 -0.110 0.60270E+04 52 chlorite-Al-free 47.17 43.13 -4.04 -0.168 0.68966E+04 54 chloritoid-Fe 9.17 5.01 -4.17 -0.278 0.71160E+04 55 chloritoid-Mn 11.40 7.56 -3.84 -0.256 0.65610E+04 57 coesite -2.38 -3.16 -0.78 -0.260 0.13338E+04 64 cristobalite -2.56 -3.16 -0.60 -0.199 0.10191E+04 66 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71234E+04 68 diaspore 2.87 0.74 -2.14 -0.356 0.36455E+04 69 diamond -3.10 -7.49 -4.39 -1.253 0.74877E+04 70 diopside 16.18 16.07 -0.12 -0.012 0.19701E+03 71 hedenbergite 14.21 13.46 -0.75 -0.075 0.12808E+04 74 enstatite 17.26 12.27 -4.99 -0.499 0.85233E+04 76 clinoenstatite 17.17 12.27 -4.89 -0.489 0.83549E+04 78 epidote 24.67 22.70 -1.97 -0.095 0.33630E+04 79 clinozoisite 22.81 18.92 -3.89 -0.177 0.66394E+04 80 epidote-Fe 29.84 26.48 -3.36 -0.174 0.57331E+04 81 fayalite 14.05 10.21 -3.83 -0.547 0.65414E+04 82 ferrosilite 11.15 7.06 -4.09 -0.409 0.69869E+04 86 gibbsite 4.08 0.74 -3.34 -0.477 0.57041E+04 87 glaucophane 22.97 20.80 -2.18 -0.059 0.37149E+04 88 glaucophane-Fe 17.28 12.98 -4.30 -0.116 0.73423E+04 89 graphite -3.55 -7.49 -3.94 -1.126 0.67299E+04 90 greenalite 16.14 13.74 -2.40 -0.200 0.40912E+04 93 hematite 12.57 9.04 -3.52 -0.427 0.60160E+04 94 heulandite -5.83 -7.54 -1.71 -0.078 0.29186E+04 98 jadeite 4.22 2.77 -1.44 -0.144 0.24621E+04 100 kalsilite 7.58 3.83 -3.76 -0.537 0.64132E+04 101 kaolinite -1.33 -4.84 -3.50 -0.319 0.59836E+04 104 laumontite 2.88 1.94 -0.95 -0.063 0.16192E+04 105 lawsonite 9.62 8.25 -1.37 -0.091 0.23334E+04 106 leucite 4.12 0.67 -3.45 -0.345 0.58876E+04 108 lizardite 23.24 21.57 -1.68 -0.140 0.28634E+04 110 magnetite 20.09 15.73 -4.36 -0.356 0.74422E+04 111 minnesotaite 10.39 7.43 -2.96 -0.174 0.50525E+04 115 manganosite 14.06 9.24 -4.82 -1.205 0.82294E+04 119 microcline -2.49 -2.49 0.00 0.000 0.38482E-02 123 muscovite 2.58 -1.01 -3.59 -0.211 0.61326E+04 124 paragonite 4.24 1.09 -3.15 -0.185 0.53717E+04 125 nepheline 8.34 5.93 -2.41 -0.344 0.41131E+04 131 periclase-Fe 11.63 6.69 -4.94 -1.235 0.84360E+04 137 phlogopite-Na 29.65 27.50 -2.15 -0.119 0.36699E+04 139 prehnite 19.37 18.18 -1.19 -0.070 0.20369E+04 140 prehnite-Fe 22.50 21.96 -0.54 -0.032 0.91547E+03 141 pumpellyite-Fe 46.27 43.78 -2.49 -0.055 0.42464E+04 142 pumpellyite-Mg 48.99 46.39 -2.60 -0.058 0.44473E+04 146 pyrrhotite -4.26 -8.05 -3.79 -1.264 0.64744E+04 147 pyrrhotiteFe0.875 -6.02 -9.42 -3.41 -1.253 0.58186E+04 148 pyroxmangite 7.40 6.08 -1.32 -0.263 0.22495E+04 149 pyrophyllite -6.18 -11.15 -4.98 -0.311 0.84959E+04 150 quartz -2.99 -3.16 -0.17 -0.056 0.28648E+03 155 rhodonite 7.45 6.08 -1.36 -0.273 0.23297E+04 156 sanidine -1.28 -2.49 -1.21 -0.093 0.20678E+04 166 stilbite -7.52 -7.54 -0.01 -0.001 0.24751E+02 167 stilpnomelane-Fe 13.02 12.77 -0.24 -0.007 0.41717E+03 168 stilpnomelane-Mg 27.44 25.81 -1.63 -0.049 0.27827E+04 174 talc 16.49 15.25 -1.24 -0.073 0.21149E+04 177 tephroite 18.09 15.32 -2.77 -0.395 0.47230E+04 181 tridymite -2.63 -3.16 -0.53 -0.177 0.90645E+03 182 tremolite 47.87 47.38 -0.48 -0.013 0.82785E+03 183 ferroactinolite 38.45 34.35 -4.11 -0.111 0.70126E+04 184 troilite-low -4.41 -8.05 -3.64 -1.214 0.62172E+04 186 vesuvianite 223.47 218.53 -4.94 -0.038 0.84384E+04 190 wairakite 3.95 1.94 -2.02 -0.119 0.34412E+04 191 walstromite 11.51 9.93 -1.58 -0.316 0.26975E+04 192 wollastonite 10.46 9.93 -0.53 -0.106 0.90791E+03 193 pseudo-wollastonite 11.00 9.93 -1.07 -0.214 0.18277E+04 194 zoisite 22.85 18.92 -3.93 -0.179 0.67135E+04 195 akaganeite 7.75 4.52 -3.23 -0.699 0.55205E+04 202 chalcedony -2.80 -3.16 -0.35 -0.118 0.60577E+03 204 montmorillonite-Ca -2.29 -6.17 -3.88 -0.240 0.66222E+04 205 montmorillonite-K -2.24 -6.27 -4.03 -0.247 0.68816E+04 206 montmorillonite-Mg -2.48 -6.79 -4.32 -0.267 0.73678E+04 207 montmorillonite-Na -2.04 -5.57 -3.54 -0.216 0.60365E+04 208 nontronite-Ca 3.21 -0.14 -3.36 -0.218 0.57296E+04 209 nontronite-H 2.53 -2.30 -4.83 -0.324 0.82523E+04 210 nontronite-K 3.34 -0.24 -3.58 -0.230 0.61123E+04 211 nontronite-Mg 3.07 -0.77 -3.84 -0.249 0.65593E+04 212 nontronite-Na 3.52 0.45 -3.06 -0.197 0.52332E+04 228 tobermorite 9.82 7.74 -2.08 -0.567 0.35500E+04 234 alabandite -0.98 -5.50 -4.52 -1.507 0.77208E+04 237 boehmite 4.41 0.74 -3.67 -0.611 0.62624E+04 239 ferrous-oxide 9.81 6.69 -3.13 -0.781 0.53369E+04 245 silica-amorphous -2.09 -3.16 -1.07 -0.355 0.18200E+04 247 an20ab80 2.02 1.34 -0.67 -0.052 0.11525E+04 248 an25ab75 2.65 1.77 -0.87 -0.067 0.14876E+04 249 an30ab70 3.28 2.21 -1.07 -0.083 0.18323E+04 250 tr.625ac.25prg.125 45.16 45.07 -0.09 -0.002 0.15686E+03 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 0.0000100 MOLES Current total amount of reactant added: 0.0000400 MOLES New total amount of reactant added: 0.0000500 MOLES Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.5508E-08 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 6 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 0.0000500 Water: Moles liquid = 0.4985E+02 kg liquid = 0.8981E+00 Moles total = 0.4985E+02 kg total = 0.8980E+00 Activity = 1.0000 Stoichiometric ionic strength = .1133341E-01 Osmotic coef. = 0.9692 True ionic strength = .2001991E-01 Chg. balance for total moles = -.5508E-08 Max. difference allowed = 0.1382E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.88356E-10 -10.0538 0.74241E-10 -10.1294 0.84025E+00 -0.0756 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.15316E-03 -3.8149 0.12792E-03 -3.8931 0.83519E+00 -0.0782 4 SO4-- 0.38061E-11 -11.4195 0.19765E-11 -11.7041 0.51930E+00 -0.2846 5 HCO3- 0.14129E-05 -5.8499 0.11818E-05 -5.9275 0.83642E+00 -0.0776 6 HS- 0.29747E-04 -4.5266 0.24848E-04 -4.6047 0.83532E+00 -0.0781 7 Al+++ 0.97008E-29 -29.0132 0.22411E-29 -29.6495 0.23102E+00 -0.6363 8 H4SiO4 0.69639E-03 -3.1571 0.69639E-03 -3.1571 0.10000E+01 0.0000 9 Ca++ 0.12984E-06 -6.8866 0.66932E-07 -7.1744 0.51548E+00 -0.2878 10 Mg++ 0.21121E-10 -10.6753 0.10838E-10 -10.9651 0.51313E+00 -0.2898 11 Fe++ 0.51254E-13 -13.2903 0.26329E-13 -13.5796 0.51369E+00 -0.2893 12 K+ 0.15651E-03 -3.8055 0.13094E-03 -3.8829 0.83661E+00 -0.0775 13 Na+ 0.19860E-01 -1.7020 0.16584E-01 -1.7803 0.83504E+00 -0.0783 14 Mn++ 0.18565E-10 -10.7313 0.95445E-11 -11.0202 0.51411E+00 -0.2889 15 F- 0.13319E-06 -6.8755 0.11101E-06 -6.9546 0.83347E+00 -0.0791 16 HPO4-- 0.45316E-07 -7.3437 0.23536E-07 -7.6283 0.51937E+00 -0.2845 18 HSiO3- 0.10487E-01 -1.9794 0.87586E-02 -2.0576 0.83519E+00 -0.0782 19 Ca(HSiO3)+ 0.15954E-07 -7.7971 0.13351E-07 -7.8745 0.83679E+00 -0.0774 20 Mg(HSiO3)+ 0.32150E-11 -11.4928 0.26903E-11 -11.5702 0.83679E+00 -0.0774 21 NaHSiO3,aq 0.23493E-02 -2.6291 0.23493E-02 -2.6291 0.10000E+01 0.0000 22 AlO+ 0.66104E-16 -16.1798 0.55316E-16 -16.2572 0.83679E+00 -0.0774 24 HAlO2,aq 0.14838E-09 -9.8286 0.14838E-09 -9.8286 0.10000E+01 0.0000 25 AlO2- 0.53068E-05 -5.2752 0.44242E-05 -5.3542 0.83369E+00 -0.0790 26 CH4,aq 0.14482E-04 -4.8392 0.14432E-04 -4.8407 0.99654E+00 -0.0015 27 C2H6,aq 0.46222E-14 -14.3352 0.46062E-14 -14.3367 0.99654E+00 -0.0015 31 CO,aq 0.36403E-16 -16.4389 0.36403E-16 -16.4389 0.10000E+01 0.0000 32 CO2,aq 0.18812E-09 -9.7256 0.18747E-09 -9.7271 0.99654E+00 -0.0015 33 CO3-2 0.26831E-05 -5.5714 0.13904E-05 -5.8569 0.51819E+00 -0.2855 34 CaCO3,aq 0.11669E-08 -8.9330 0.11669E-08 -8.9330 0.10000E+01 0.0000 35 Ca(HCO3)+ 0.24128E-11 -11.6175 0.20190E-11 -11.6949 0.83679E+00 -0.0774 36 CaCl+ 0.16558E-10 -10.7810 0.13856E-10 -10.8584 0.83679E+00 -0.0774 37 CaCl2,aq 0.42109E-15 -15.3756 0.42109E-15 -15.3756 0.10000E+01 0.0000 38 CaF+ 0.12964E-12 -12.8873 0.10848E-12 -12.9646 0.83679E+00 -0.0774 39 CaOH+ 0.76784E-07 -7.1147 0.64253E-07 -7.1921 0.83679E+00 -0.0774 40 CaSO4,aq 0.42008E-16 -16.3767 0.42008E-16 -16.3767 0.10000E+01 0.0000 41 HCl,aq 0.17403E-14 -14.7594 0.17403E-14 -14.7594 0.10000E+01 0.0000 45 HF,aq 0.56419E-13 -13.2486 0.56419E-13 -13.2486 0.10000E+01 0.0000 48 FeCl+ 0.63706E-17 -17.1958 0.53309E-17 -17.2732 0.83679E+00 -0.0774 51 FeF+ 0.17849E-18 -18.7484 0.14936E-18 -18.8258 0.83679E+00 -0.0774 53 FeO,aq 0.18565E-09 -9.7313 0.18565E-09 -9.7313 0.10000E+01 0.0000 54 FeOH+ 0.13795E-10 -10.8603 0.11544E-10 -10.9377 0.83679E+00 -0.0774 55 HFeO2- 0.31328E-07 -7.5041 0.26165E-07 -7.5823 0.83519E+00 -0.0782 56 FeO+ 0.11835E-16 -16.9268 0.99035E-17 -17.0042 0.83679E+00 -0.0774 58 FeO2- 0.44021E-09 -9.3563 0.36766E-09 -9.4346 0.83519E+00 -0.0782 59 HFeO2,aq 0.34716E-11 -11.4595 0.34716E-11 -11.4595 0.10000E+01 0.0000 60 H2,aq 0.77567E-05 -5.1103 0.77299E-05 -5.1118 0.99654E+00 -0.0015 61 KCl,aq 0.30357E-09 -9.5177 0.30357E-09 -9.5177 0.10000E+01 0.0000 63 KOH,aq 0.75319E-06 -6.1231 0.75319E-06 -6.1231 0.10000E+01 0.0000 64 KSO4- 0.48083E-14 -14.3180 0.40159E-14 -14.3962 0.83519E+00 -0.0782 65 MgCO3,aq 0.47358E-13 -13.3246 0.47358E-13 -13.3246 0.10000E+01 0.0000 66 Mg(HCO3)+ 0.39920E-15 -15.3988 0.33405E-15 -15.4762 0.83679E+00 -0.0774 67 MgCl+ 0.24300E-14 -14.6144 0.20334E-14 -14.6918 0.83679E+00 -0.0774 68 MgF+ 0.77757E-16 -16.1093 0.65067E-16 -16.1866 0.83679E+00 -0.0774 69 MgOH+ 0.68797E-10 -10.1624 0.57569E-10 -10.2398 0.83679E+00 -0.0774 71 MnF+ 0.21327E-16 -16.6711 0.17846E-16 -16.7484 0.83679E+00 -0.0774 72 MnO,aq 0.17933E-08 -8.7463 0.17933E-08 -8.7463 0.10000E+01 0.0000 73 MnOH+ 0.46457E-09 -9.3329 0.38875E-09 -9.4103 0.83679E+00 -0.0774 74 MnO2-2 0.20837E-10 -10.6812 0.10798E-10 -10.9667 0.51819E+00 -0.2855 75 HMnO2- 0.21028E-09 -9.6772 0.17563E-09 -9.7554 0.83519E+00 -0.0782 78 MnCl+ 0.89847E-14 -14.0465 0.75184E-14 -14.1239 0.83679E+00 -0.0774 80 NaCl,aq 0.70305E-06 -6.1530 0.70305E-06 -6.1530 0.10000E+01 0.0000 81 NaF,aq 0.43102E-09 -9.3655 0.43102E-09 -9.3655 0.10000E+01 0.0000 82 NaOH,aq 0.95976E-04 -4.0178 0.95976E-04 -4.0178 0.10000E+01 0.0000 84 OH- 0.93349E-02 -2.0299 0.77824E-02 -2.1089 0.83369E+00 -0.0790 89 HPO3-2 0.10941E-14 -14.9609 0.56695E-15 -15.2465 0.51819E+00 -0.2855 91 H2PO3- 0.10106E-18 -18.9954 0.84405E-19 -19.0736 0.83519E+00 -0.0782 92 H3PO4,aq 0.90728E-18 -18.0423 0.90728E-18 -18.0423 0.10000E+01 0.0000 93 H2PO4- 0.38557E-10 -10.4139 0.32233E-10 -10.4917 0.83599E+00 -0.0778 94 PO4-3 0.10660E-08 -8.9722 0.25865E-09 -9.5873 0.24264E+00 -0.6150 98 HP2O7-3 0.94750E-18 -18.0234 0.21911E-18 -18.6593 0.23125E+00 -0.6359 99 P2O7-4 0.91447E-17 -17.0388 0.70507E-18 -18.1518 0.77102E-01 -1.1129 100 H2S,aq 0.57212E-08 -8.2425 0.57014E-08 -8.2440 0.99654E+00 -0.0015 101 S2-2 0.34155E-14 -14.4665 0.17699E-14 -14.7521 0.51819E+00 -0.2855 107 SO3-2 0.37767E-17 -17.4229 0.19854E-17 -17.7022 0.52569E+00 -0.2793 108 HSO3- 0.11050E-19 -19.9566 0.92288E-20 -20.0349 0.83519E+00 -0.0782 109 HSO4- 0.16883E-18 -18.7726 0.14141E-18 -18.8495 0.83761E+00 -0.0770 Charge balance for all species = -.6133E-08 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.8835631E-10 -.2229384E-01 -.2243180E+02 0.0000 2 H2O 0.1000000E+01 0.5550488E+02 0.9981993E+06 0.0000 3 Cl- 0.1531615E-03 0.1538649E-03 0.5445493E+01 6.2363 4 SO4-- 0.3806089E-11 -.1642081E-04 -.1574668E+01 8.5546 5 HCO3- 0.1412885E-05 0.1857903E-04 0.1131671E+01 4.2019 6 HS- 0.2974686E-04 0.4617340E-04 0.1524393E+01 5.5246 7 Al+++ 0.9700847E-29 0.5306903E-05 0.1429393E+00 0.7385 8 H4SiO4 0.6963891E-03 0.1353256E-01 0.1298427E+04 -3.1571 9 Ca++ 0.1298422E-06 0.2237668E-06 0.8952540E-02 13.0843 10 Mg++ 0.2112053E-10 0.9318277E-10 0.2261522E-05 9.2936 11 Fe++ 0.5125407E-13 0.3197120E-07 0.1782392E-02 6.6791 12 K+ 0.1565079E-03 0.1572614E-03 0.6138547E+01 6.2464 13 Na+ 0.1986018E-01 0.2230613E-01 0.5119223E+03 8.3490 14 Mn++ 0.1856485E-10 0.2507573E-08 0.1375216E-03 9.2385 15 F- 0.1331909E-06 0.1336221E-06 0.2534140E-02 3.1747 16 HPO4-- 0.4531597E-07 0.4642052E-07 0.4447652E-02 12.6304 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.2002116E-01 -.2002110E-01 -.5850097E-07 0.0000000E+00 2 H2O 0.4984645E+02 0.4984645E+02 -.3629237E-07 0.0000000E+00 3 Cl- 0.1381792E-03 0.1381792E-03 0.0000000E+00 0.0000000E+00 4 SO4-- -.1474631E-04 -.1474680E-04 0.4850459E-09 0.0000000E+00 5 HCO3- 0.1668500E-04 0.1668500E-04 0.0000000E+00 0.0000000E+00 6 HS- 0.4146578E-04 0.4146627E-04 -.4850459E-09 0.0000000E+00 7 Al+++ 0.4775352E-05 0.4765892E-05 0.9460046E-08 0.0000000E+00 8 H4SiO4 0.1215302E-01 0.1215299E-01 0.3289269E-07 0.0000000E+00 9 Ca++ 0.2080835E-06 0.2009550E-06 0.7128550E-08 0.0000000E+00 10 Mg++ 0.8368328E-10 0.8368328E-10 0.0000000E+00 0.0000000E+00 11 Fe++ 0.3259227E-07 0.2871190E-07 0.3880367E-08 0.0000000E+00 12 K+ 0.1412294E-03 0.1412294E-03 0.0000000E+00 0.0000000E+00 13 Na+ 0.2003215E-01 0.2003214E-01 0.8588047E-08 0.0000000E+00 14 Mn++ 0.2251939E-08 0.2251939E-08 0.0000000E+00 0.0000000E+00 15 F- 0.1200000E-06 0.1200000E-06 0.0000000E+00 0.0000000E+00 16 HPO4-- 0.4168819E-07 0.4168819E-07 0.0000000E+00 0.0000000E+00 Chg. balance for solid moles: -.1654E-23 Mass of aqueous solution: 0.899619E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 0.0000500 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 0.8588E-08 -8.066 0.2252E-05 -5.647 65.57 0.8645E-06 andradite 0.1940E-08 -8.712 0.9860E-06 -6.006 28.71 0.2562E-06 grossular 0.4360E-09 -9.361 0.1964E-06 -6.707 5.719 0.5465E-07 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8165E+00 0.8165E+00 1.0000 -0.088 grossular 0.1835E+00 0.1835E+00 1.0000 -0.736 Solid products produced: Mass = 0.000003 g Volume = 0.000001 cm3 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.0000500 moles log = -4.3010 Original solution: 1000.0103000 g Original solution / Rock added: 20000206.00 (Water/Rock Ratio), log = 7.3010 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0519 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9704E+00 0.9855 0.1006E+01 0.1021E+01 CO2,gas 0.1894E-07 1.0069 0.2006E-07 0.1992E-07 CH4,gas 0.1995E-01 1.0124 0.2124E-01 0.2098E-01 H2,gas 0.9643E-02 1.0006 0.1015E-01 0.1014E-01 H2S,gas 0.1496E-06 0.9959 0.1567E-06 0.1574E-06 S2,gas 0.8511E-29 1.0000 0.8953E-29 0.8953E-29 CO,gas 0.5157E-13 1.0000 0.5425E-13 0.5425E-13 SO3,gas 0.3916E-47 1.0000 0.4119E-47 0.4119E-47 SO2,gas 0.1546E-26 1.0000 0.1626E-26 0.1626E-26 HF,gas 0.1317E-15 1.0000 0.1385E-15 0.1385E-15 HCl,gas 0.2919E-17 1.0000 0.3071E-17 0.3071E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 17 albite -0.38 -0.38 0.00 0.000 -0.94784E-12 23 andradite 39.01 39.01 0.00 0.000 0.12132E-10 24 grossular 32.73 32.73 0.00 0.000 0.12132E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -16.06 -9.40 -3.132 0.16045E+05 -7.698 3 CH4,gas 4.54 1.17 -3.37 -0.843 0.57572E+04 -1.673 4 H2,gas 8.00 4.31 -3.69 -2.110 0.63050E+04 -1.994 5 H2S,gas -6.23 -14.73 -8.50 -4.252 0.14520E+05 -6.805 6 S2,gas -7.34 -38.08 -30.75 -4.730 0.52500E+05 -29.048 7 CO,gas 3.21 -11.75 -14.96 -4.604 0.25552E+05 -13.266 8 SO3,gas 17.12 -31.96 -49.08 -12.271 0.83810E+05 -47.385 9 SO2,gas 0.83 -27.66 -28.49 -7.597 0.48642E+05 -26.789 10 HF,gas 0.47 -17.08 -17.56 -8.779 0.29979E+05 -15.858 11 HCl,gas 5.19 -14.02 -19.21 -9.606 0.32804E+05 -17.513 12 acmite 7.71 6.56 -1.15 -0.119 0.19626E+04 16 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 20 spessartine 24.46 19.72 -4.74 -0.237 0.80872E+04 21 analcite 3.32 2.77 -0.55 -0.061 0.93669E+03 27 annite 20.12 17.55 -2.57 -0.143 0.43924E+04 28 phlogopite 27.06 25.39 -1.67 -0.093 0.28518E+04 30 anorthite 12.71 8.25 -4.46 -0.343 0.76208E+04 33 apatite-OH -18.15 -18.24 -0.09 -0.007 0.14641E+03 34 apatite-F -34.30 -35.32 -1.02 -0.085 0.17454E+04 38 aragonite 0.97 -2.97 -3.94 -1.313 0.67257E+04 39 brucite 12.57 9.29 -3.27 -0.655 0.55918E+04 40 calcite 0.81 -2.97 -3.78 -1.261 0.64615E+04 41 carnegieite-low 9.02 5.93 -3.09 -0.442 0.52810E+04 42 carnegieite-high 10.09 5.93 -4.16 -0.595 0.71080E+04 43 carpholite-Mg 8.58 4.46 -4.13 -0.275 0.70445E+04 44 carpholite-Fe 6.71 1.84 -4.87 -0.325 0.83167E+04 45 celadonite 5.34 3.65 -1.69 -0.100 0.28884E+04 46 celadonite-Fe 3.88 1.04 -2.84 -0.167 0.48510E+04 47 chrysotile 23.89 21.57 -2.33 -0.194 0.39712E+04 49 clinochlore 39.07 38.47 -0.60 -0.019 0.10171E+04 50 daphnite 28.97 25.40 -3.56 -0.111 0.60853E+04 52 chlorite-Al-free 47.17 43.13 -4.04 -0.168 0.68975E+04 54 chloritoid-Fe 9.17 5.00 -4.17 -0.278 0.71280E+04 55 chloritoid-Mn 11.40 7.56 -3.84 -0.256 0.65613E+04 57 coesite -2.38 -3.16 -0.78 -0.260 0.13337E+04 64 cristobalite -2.56 -3.16 -0.60 -0.199 0.10190E+04 66 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71234E+04 68 diaspore 2.87 0.74 -2.14 -0.356 0.36457E+04 69 diamond -3.10 -7.44 -4.34 -1.240 0.74105E+04 70 diopside 16.18 16.06 -0.12 -0.012 0.20092E+03 71 hedenbergite 14.21 13.45 -0.76 -0.076 0.12961E+04 74 enstatite 17.26 12.27 -4.99 -0.499 0.85236E+04 76 clinoenstatite 17.17 12.27 -4.89 -0.489 0.83552E+04 78 epidote 24.67 22.70 -1.97 -0.096 0.33638E+04 79 clinozoisite 22.81 18.91 -3.89 -0.177 0.66475E+04 80 epidote-Fe 29.84 26.49 -3.35 -0.174 0.57268E+04 81 fayalite 14.05 10.20 -3.84 -0.549 0.65645E+04 82 ferrosilite 11.15 7.04 -4.11 -0.411 0.70100E+04 86 gibbsite 4.08 0.74 -3.34 -0.477 0.57043E+04 87 glaucophane 22.97 20.80 -2.18 -0.059 0.37153E+04 88 glaucophane-Fe 17.28 12.96 -4.32 -0.117 0.73770E+04 89 graphite -3.55 -7.44 -3.90 -1.113 0.66528E+04 90 greenalite 16.14 13.72 -2.42 -0.201 0.41259E+04 93 hematite 12.57 9.05 -3.52 -0.426 0.60019E+04 94 heulandite -5.83 -7.54 -1.71 -0.078 0.29221E+04 98 jadeite 4.22 2.77 -1.44 -0.144 0.24622E+04 100 kalsilite 7.58 3.83 -3.76 -0.537 0.64135E+04 101 kaolinite -1.33 -4.84 -3.50 -0.319 0.59838E+04 104 laumontite 2.88 1.93 -0.95 -0.063 0.16231E+04 105 lawsonite 9.62 8.25 -1.37 -0.091 0.23375E+04 106 leucite 4.12 0.67 -3.45 -0.345 0.58877E+04 108 lizardite 23.24 21.57 -1.68 -0.140 0.28638E+04 110 magnetite 20.09 15.73 -4.36 -0.356 0.74397E+04 111 minnesotaite 10.39 7.41 -2.98 -0.175 0.50870E+04 115 manganosite 14.06 9.24 -4.82 -1.205 0.82294E+04 119 microcline -2.49 -2.49 0.00 0.000 0.46149E-02 123 muscovite 2.58 -1.01 -3.59 -0.211 0.61330E+04 124 paragonite 4.24 1.09 -3.15 -0.185 0.53721E+04 125 nepheline 8.34 5.93 -2.41 -0.344 0.41133E+04 131 periclase-Fe 11.63 6.68 -4.95 -1.237 0.84476E+04 137 phlogopite-Na 29.65 27.50 -2.15 -0.119 0.36706E+04 139 prehnite 19.37 18.17 -1.20 -0.070 0.20448E+04 140 prehnite-Fe 22.50 21.96 -0.54 -0.032 0.91614E+03 141 pumpellyite-Fe 46.27 43.77 -2.50 -0.056 0.42741E+04 142 pumpellyite-Mg 48.99 46.38 -2.61 -0.058 0.44635E+04 146 pyrrhotite -4.26 -8.05 -3.79 -1.265 0.64792E+04 147 pyrrhotiteFe0.875 -6.02 -9.42 -3.41 -1.253 0.58173E+04 148 pyroxmangite 7.40 6.08 -1.32 -0.263 0.22494E+04 149 pyrophyllite -6.18 -11.15 -4.98 -0.311 0.84959E+04 150 quartz -2.99 -3.16 -0.17 -0.056 0.28636E+03 155 rhodonite 7.45 6.08 -1.36 -0.273 0.23296E+04 156 sanidine -1.28 -2.49 -1.21 -0.093 0.20678E+04 166 stilbite -7.52 -7.54 -0.02 -0.001 0.28316E+02 167 stilpnomelane-Fe 13.02 12.74 -0.28 -0.008 0.47500E+03 168 stilpnomelane-Mg 27.44 25.81 -1.63 -0.049 0.27834E+04 174 talc 16.49 15.25 -1.24 -0.073 0.21151E+04 177 tephroite 18.09 15.32 -2.77 -0.395 0.47229E+04 181 tridymite -2.63 -3.16 -0.53 -0.177 0.90634E+03 182 tremolite 47.87 47.38 -0.49 -0.013 0.83589E+03 183 ferroactinolite 38.45 34.31 -4.15 -0.112 0.70778E+04 184 troilite-low -4.41 -8.05 -3.64 -1.215 0.62220E+04 186 vesuvianite 223.47 218.48 -4.99 -0.038 0.85135E+04 190 wairakite 3.95 1.93 -2.02 -0.119 0.34451E+04 191 walstromite 11.51 9.93 -1.58 -0.316 0.27013E+04 192 wollastonite 10.46 9.93 -0.53 -0.107 0.91171E+03 193 pseudo-wollastonite 11.00 9.93 -1.07 -0.215 0.18315E+04 194 zoisite 22.85 18.91 -3.94 -0.179 0.67216E+04 195 akaganeite 7.75 4.53 -3.23 -0.698 0.55135E+04 202 chalcedony -2.80 -3.16 -0.35 -0.118 0.60566E+03 204 montmorillonite-Ca -2.29 -6.17 -3.88 -0.240 0.66228E+04 205 montmorillonite-K -2.24 -6.27 -4.03 -0.247 0.68816E+04 206 montmorillonite-Mg -2.48 -6.79 -4.32 -0.267 0.73678E+04 207 montmorillonite-Na -2.04 -5.57 -3.54 -0.216 0.60365E+04 208 nontronite-Ca 3.21 -0.13 -3.35 -0.217 0.57159E+04 209 nontronite-H 2.53 -2.29 -4.82 -0.323 0.82379E+04 210 nontronite-K 3.34 -0.23 -3.57 -0.229 0.60979E+04 211 nontronite-Mg 3.07 -0.76 -3.83 -0.249 0.65449E+04 212 nontronite-Na 3.52 0.46 -3.06 -0.196 0.52188E+04 228 tobermorite 9.82 7.74 -2.08 -0.568 0.35532E+04 234 alabandite -0.98 -5.50 -4.52 -1.506 0.77139E+04 237 boehmite 4.41 0.74 -3.67 -0.611 0.62627E+04 239 ferrous-oxide 9.81 6.68 -3.13 -0.783 0.53486E+04 245 silica-amorphous -2.09 -3.16 -1.07 -0.355 0.18198E+04 247 an20ab80 2.02 1.34 -0.68 -0.052 0.11533E+04 248 an25ab75 2.65 1.77 -0.87 -0.067 0.14886E+04 249 an30ab70 3.28 2.21 -1.07 -0.083 0.18335E+04 250 tr.625ac.25prg.125 45.16 45.06 -0.10 -0.003 0.17928E+03 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 0.0000100 MOLES Current total amount of reactant added: 0.0000500 MOLES New total amount of reactant added: 0.0000600 MOLES Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.5508E-08 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 6 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 0.0000600 Water: Moles liquid = 0.4985E+02 kg liquid = 0.8981E+00 Moles total = 0.4985E+02 kg total = 0.8980E+00 Activity = 1.0000 Stoichiometric ionic strength = .1133405E-01 Osmotic coef. = 0.9692 True ionic strength = .2002045E-01 Chg. balance for total moles = -.5508E-08 Max. difference allowed = 0.1382E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.88371E-10 -10.0537 0.74253E-10 -10.1293 0.84025E+00 -0.0756 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.15323E-03 -3.8147 0.12797E-03 -3.8929 0.83519E+00 -0.0782 4 SO4-- 0.45602E-11 -11.3410 0.23681E-11 -11.6256 0.51929E+00 -0.2846 5 HCO3- 0.16809E-05 -5.7745 0.14059E-05 -5.8520 0.83641E+00 -0.0776 6 HS- 0.30017E-04 -4.5226 0.25074E-04 -4.6008 0.83532E+00 -0.0781 7 Al+++ 0.97029E-29 -29.0131 0.22415E-29 -29.6495 0.23102E+00 -0.6364 8 H4SiO4 0.69649E-03 -3.1571 0.69649E-03 -3.1571 0.10000E+01 0.0000 9 Ca++ 0.12929E-06 -6.8884 0.66645E-07 -7.1762 0.51548E+00 -0.2878 10 Mg++ 0.21121E-10 -10.6753 0.10838E-10 -10.9651 0.51312E+00 -0.2898 11 Fe++ 0.50598E-13 -13.2959 0.25991E-13 -13.5852 0.51368E+00 -0.2893 12 K+ 0.15651E-03 -3.8055 0.13094E-03 -3.8829 0.83661E+00 -0.0775 13 Na+ 0.19860E-01 -1.7020 0.16584E-01 -1.7803 0.83504E+00 -0.0783 14 Mn++ 0.18571E-10 -10.7312 0.95474E-11 -11.0201 0.51411E+00 -0.2889 15 F- 0.13763E-06 -6.8613 0.11471E-06 -6.9404 0.83347E+00 -0.0791 16 HPO4-- 0.45316E-07 -7.3437 0.23536E-07 -7.6283 0.51937E+00 -0.2845 18 HSiO3- 0.10487E-01 -1.9794 0.87585E-02 -2.0576 0.83519E+00 -0.0782 19 Ca(HSiO3)+ 0.15886E-07 -7.7990 0.13293E-07 -7.8764 0.83679E+00 -0.0774 20 Mg(HSiO3)+ 0.32150E-11 -11.4928 0.26903E-11 -11.5702 0.83679E+00 -0.0774 21 NaHSiO3,aq 0.23492E-02 -2.6291 0.23492E-02 -2.6291 0.10000E+01 0.0000 22 AlO+ 0.66096E-16 -16.1798 0.55309E-16 -16.2572 0.83679E+00 -0.0774 24 HAlO2,aq 0.14834E-09 -9.8287 0.14834E-09 -9.8287 0.10000E+01 0.0000 25 AlO2- 0.53043E-05 -5.2754 0.44222E-05 -5.3544 0.83368E+00 -0.0790 26 CH4,aq 0.14510E-04 -4.8383 0.14460E-04 -4.8398 0.99654E+00 -0.0015 27 C2H6,aq 0.48441E-14 -14.3148 0.48273E-14 -14.3163 0.99654E+00 -0.0015 31 CO,aq 0.41493E-16 -16.3820 0.41493E-16 -16.3820 0.10000E+01 0.0000 32 CO2,aq 0.22384E-09 -9.6501 0.22306E-09 -9.6516 0.99654E+00 -0.0015 33 CO3-2 0.31915E-05 -5.4960 0.16538E-05 -5.7815 0.51819E+00 -0.2855 34 CaCO3,aq 0.13820E-08 -8.8595 0.13820E-08 -8.8595 0.10000E+01 0.0000 35 Ca(HCO3)+ 0.28582E-11 -11.5439 0.23917E-11 -11.6213 0.83679E+00 -0.0774 36 CaCl+ 0.16494E-10 -10.7827 0.13802E-10 -10.8600 0.83679E+00 -0.0774 37 CaCl2,aq 0.41964E-15 -15.3771 0.41964E-15 -15.3771 0.10000E+01 0.0000 38 CaF+ 0.13339E-12 -12.8749 0.11162E-12 -12.9523 0.83679E+00 -0.0774 39 CaOH+ 0.76443E-07 -7.1167 0.63967E-07 -7.1940 0.83679E+00 -0.0774 40 CaSO4,aq 0.50116E-16 -16.3000 0.50116E-16 -16.3000 0.10000E+01 0.0000 41 HCl,aq 0.17413E-14 -14.7591 0.17413E-14 -14.7591 0.10000E+01 0.0000 45 HF,aq 0.58309E-13 -13.2343 0.58309E-13 -13.2343 0.10000E+01 0.0000 48 FeCl+ 0.62917E-17 -17.2012 0.52648E-17 -17.2786 0.83679E+00 -0.0774 51 FeF+ 0.18208E-18 -18.7397 0.15236E-18 -18.8171 0.83679E+00 -0.0774 53 FeO,aq 0.18322E-09 -9.7370 0.18322E-09 -9.7370 0.10000E+01 0.0000 54 FeOH+ 0.13616E-10 -10.8659 0.11394E-10 -10.9433 0.83679E+00 -0.0774 55 HFeO2- 0.30912E-07 -7.5099 0.25817E-07 -7.5881 0.83519E+00 -0.0782 56 FeO+ 0.11935E-16 -16.9232 0.99873E-17 -17.0006 0.83679E+00 -0.0774 58 FeO2- 0.44379E-09 -9.3528 0.37065E-09 -9.4310 0.83519E+00 -0.0782 59 HFeO2,aq 0.35004E-11 -11.4559 0.35004E-11 -11.4559 0.10000E+01 0.0000 60 H2,aq 0.74304E-05 -5.1290 0.74047E-05 -5.1305 0.99654E+00 -0.0015 61 KCl,aq 0.30370E-09 -9.5176 0.30370E-09 -9.5176 0.10000E+01 0.0000 63 KOH,aq 0.75306E-06 -6.1232 0.75306E-06 -6.1232 0.10000E+01 0.0000 64 KSO4- 0.57610E-14 -14.2395 0.48115E-14 -14.3177 0.83519E+00 -0.0782 65 MgCO3,aq 0.56333E-13 -13.2492 0.56333E-13 -13.2492 0.10000E+01 0.0000 66 Mg(HCO3)+ 0.47493E-15 -15.3234 0.39742E-15 -15.4008 0.83679E+00 -0.0774 67 MgCl+ 0.24311E-14 -14.6142 0.20343E-14 -14.6916 0.83679E+00 -0.0774 68 MgF+ 0.80350E-16 -16.0950 0.67237E-16 -16.1724 0.83679E+00 -0.0774 69 MgOH+ 0.68787E-10 -10.1625 0.57561E-10 -10.2399 0.83679E+00 -0.0774 71 MnF+ 0.22045E-16 -16.6567 0.18447E-16 -16.7341 0.83679E+00 -0.0774 72 MnO,aq 0.17933E-08 -8.7464 0.17933E-08 -8.7464 0.10000E+01 0.0000 73 MnOH+ 0.46464E-09 -9.3329 0.38881E-09 -9.4103 0.83679E+00 -0.0774 74 MnO2-2 0.20830E-10 -10.6813 0.10794E-10 -10.9668 0.51819E+00 -0.2855 75 HMnO2- 0.21025E-09 -9.6773 0.17560E-09 -9.7555 0.83519E+00 -0.0782 78 MnCl+ 0.89913E-14 -14.0462 0.75239E-14 -14.1236 0.83679E+00 -0.0774 80 NaCl,aq 0.70335E-06 -6.1528 0.70335E-06 -6.1528 0.10000E+01 0.0000 81 NaF,aq 0.44538E-09 -9.3513 0.44538E-09 -9.3513 0.10000E+01 0.0000 82 NaOH,aq 0.95960E-04 -4.0179 0.95960E-04 -4.0179 0.10000E+01 0.0000 84 OH- 0.93334E-02 -2.0300 0.77811E-02 -2.1090 0.83368E+00 -0.0790 89 HPO3-2 0.10481E-14 -14.9796 0.54310E-15 -15.2651 0.51819E+00 -0.2855 91 H2PO3- 0.96825E-19 -19.0140 0.80868E-19 -19.0922 0.83519E+00 -0.0782 92 H3PO4,aq 0.90757E-18 -18.0421 0.90757E-18 -18.0421 0.10000E+01 0.0000 93 H2PO4- 0.38563E-10 -10.4138 0.32238E-10 -10.4916 0.83598E+00 -0.0778 94 PO4-3 0.10658E-08 -8.9723 0.25861E-09 -9.5874 0.24264E+00 -0.6150 98 HP2O7-3 0.94766E-18 -18.0233 0.21915E-18 -18.6593 0.23125E+00 -0.6359 99 P2O7-4 0.91448E-17 -17.0388 0.70506E-18 -18.1518 0.77099E-01 -1.1129 100 H2S,aq 0.57741E-08 -8.2385 0.57542E-08 -8.2400 0.99654E+00 -0.0015 101 S2-2 0.36306E-14 -14.4400 0.18813E-14 -14.7255 0.51819E+00 -0.2855 107 SO3-2 0.43347E-17 -17.3630 0.22787E-17 -17.6423 0.52569E+00 -0.2793 108 HSO3- 0.12684E-19 -19.8967 0.10594E-19 -19.9749 0.83519E+00 -0.0782 109 HSO4- 0.20231E-18 -18.6940 0.16946E-18 -18.7709 0.83761E+00 -0.0770 Charge balance for all species = -.6133E-08 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.8837081E-10 -.2229262E-01 -.2243057E+02 0.0000 2 H2O 0.1000000E+01 0.5550488E+02 0.9981992E+06 0.0000 3 Cl- 0.1532269E-03 0.1539306E-03 0.5447817E+01 6.2364 4 SO4-- 0.4560229E-11 -.1636769E-04 -.1569574E+01 8.6330 5 HCO3- 0.1680866E-05 0.1938410E-04 0.1180708E+01 4.2772 6 HS- 0.3001739E-04 0.4639086E-04 0.1531572E+01 5.5285 7 Al+++ 0.9702885E-29 0.5304495E-05 0.1428745E+00 0.7384 8 H4SiO4 0.6964949E-03 0.1353255E-01 0.1298426E+04 -3.1571 9 Ca++ 0.1292868E-06 0.2230172E-06 0.8922551E-02 13.0823 10 Mg++ 0.2112110E-10 0.9318275E-10 0.2261522E-05 9.2935 11 Fe++ 0.5059774E-13 0.3155579E-07 0.1759234E-02 6.6734 12 K+ 0.1565080E-03 0.1572613E-03 0.6138546E+01 6.2463 13 Na+ 0.1986022E-01 0.2230613E-01 0.5119222E+03 8.3490 14 Mn++ 0.1857070E-10 0.2507572E-08 0.1375216E-03 9.2385 15 F- 0.1376305E-06 0.1380761E-06 0.2618611E-02 3.1889 16 HPO4-- 0.4531611E-07 0.4642051E-07 0.4447651E-02 12.6303 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.2002008E-01 -.2002001E-01 -.6911767E-07 0.0000000E+00 2 H2O 0.4984646E+02 0.4984646E+02 -.4482284E-07 0.0000000E+00 3 Cl- 0.1382382E-03 0.1382382E-03 0.0000000E+00 0.0000000E+00 4 SO4-- -.1469856E-04 -.1469909E-04 0.5316774E-09 0.0000000E+00 5 HCO3- 0.1740800E-04 0.1740800E-04 0.0000000E+00 0.0000000E+00 6 HS- 0.4166103E-04 0.4166156E-04 -.5316774E-09 0.0000000E+00 7 Al+++ 0.4775352E-05 0.4763730E-05 0.1162172E-07 0.0000000E+00 8 H4SiO4 0.1215302E-01 0.1215298E-01 0.3982376E-07 0.0000000E+00 9 Ca++ 0.2080835E-06 0.2002818E-06 0.7801659E-08 0.0000000E+00 10 Mg++ 0.8368328E-10 0.8368328E-10 0.0000000E+00 0.0000000E+00 11 Fe++ 0.3259227E-07 0.2833885E-07 0.4253419E-08 0.0000000E+00 12 K+ 0.1412294E-03 0.1412294E-03 0.0000000E+00 0.0000000E+00 13 Na+ 0.2003215E-01 0.2003214E-01 0.1067403E-07 0.0000000E+00 14 Mn++ 0.2251939E-08 0.2251939E-08 0.0000000E+00 0.0000000E+00 15 F- 0.1240000E-06 0.1240000E-06 0.0000000E+00 0.0000000E+00 16 HPO4-- 0.4168819E-07 0.4168819E-07 0.0000000E+00 0.0000000E+00 Chg. balance for solid moles: -.4963E-23 Mass of aqueous solution: 0.899619E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 0.0000600 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 0.1067E-07 -7.972 0.2799E-05 -5.553 68.38 0.1074E-05 andradite 0.2127E-08 -8.672 0.1081E-05 -5.966 26.40 0.2808E-06 grossular 0.4738E-09 -9.324 0.2134E-06 -6.671 5.215 0.5939E-07 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8178E+00 0.8178E+00 1.0000 -0.087 grossular 0.1822E+00 0.1822E+00 1.0000 -0.739 Solid products produced: Mass = 0.000004 g Volume = 0.000001 cm3 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.0000600 moles log = -4.2218 Original solution: 1000.0103000 g Original solution / Rock added: 16666838.33 (Water/Rock Ratio), log = 7.2219 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0515 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9708E+00 0.9855 0.1006E+01 0.1021E+01 CO2,gas 0.2254E-07 1.0069 0.2387E-07 0.2370E-07 CH4,gas 0.1999E-01 1.0124 0.2128E-01 0.2102E-01 H2,gas 0.9240E-02 1.0006 0.9722E-02 0.9716E-02 H2S,gas 0.1511E-06 0.9959 0.1582E-06 0.1588E-06 S2,gas 0.9451E-29 1.0000 0.9937E-29 0.9937E-29 CO,gas 0.5881E-13 1.0000 0.6183E-13 0.6183E-13 SO3,gas 0.4695E-47 1.0000 0.4937E-47 0.4937E-47 SO2,gas 0.1776E-26 1.0000 0.1867E-26 0.1867E-26 HF,gas 0.1362E-15 1.0000 0.1432E-15 0.1432E-15 HCl,gas 0.2922E-17 1.0000 0.3073E-17 0.3073E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 17 albite -0.38 -0.38 0.00 0.000 -0.13080E-10 23 andradite 39.01 39.01 0.00 0.000 0.00000E+00 24 grossular 32.73 32.73 0.00 0.000 0.00000E+00 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -15.98 -9.32 -3.107 0.15916E+05 -7.622 3 CH4,gas 4.54 1.17 -3.37 -0.843 0.57557E+04 -1.672 4 H2,gas 8.00 4.29 -3.71 -2.121 0.63368E+04 -2.012 5 H2S,gas -6.23 -14.73 -8.50 -4.250 0.14513E+05 -6.801 6 S2,gas -7.34 -38.04 -30.70 -4.723 0.52422E+05 -29.003 7 CO,gas 3.21 -11.69 -14.91 -4.587 0.25455E+05 -13.209 8 SO3,gas 17.12 -31.88 -49.01 -12.251 0.83676E+05 -47.307 9 SO2,gas 0.83 -27.60 -28.43 -7.581 0.48540E+05 -26.729 10 HF,gas 0.47 -17.07 -17.54 -8.772 0.29954E+05 -15.844 11 HCl,gas 5.19 -14.02 -19.21 -9.606 0.32803E+05 -17.513 12 acmite 7.71 6.56 -1.15 -0.119 0.19564E+04 16 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 20 spessartine 24.46 19.72 -4.74 -0.237 0.80873E+04 21 analcite 3.32 2.77 -0.55 -0.061 0.93680E+03 27 annite 20.12 17.53 -2.59 -0.144 0.44218E+04 28 phlogopite 27.06 25.39 -1.67 -0.093 0.28524E+04 30 anorthite 12.71 8.24 -4.47 -0.343 0.76244E+04 33 apatite-OH -18.15 -18.25 -0.10 -0.007 0.16282E+03 34 apatite-F -34.30 -35.32 -1.02 -0.085 0.17374E+04 38 aragonite 0.97 -2.90 -3.87 -1.289 0.66003E+04 39 brucite 12.57 9.29 -3.28 -0.655 0.55921E+04 40 calcite 0.81 -2.90 -3.71 -1.237 0.63360E+04 41 carnegieite-low 9.02 5.93 -3.09 -0.442 0.52812E+04 42 carnegieite-high 10.09 5.93 -4.16 -0.595 0.71082E+04 43 carpholite-Mg 8.58 4.46 -4.13 -0.275 0.70449E+04 44 carpholite-Fe 6.71 1.84 -4.88 -0.325 0.83267E+04 45 celadonite 5.34 3.65 -1.69 -0.100 0.28885E+04 46 celadonite-Fe 3.88 1.03 -2.85 -0.167 0.48607E+04 47 chrysotile 23.89 21.57 -2.33 -0.194 0.39716E+04 49 clinochlore 39.07 38.47 -0.60 -0.019 0.10184E+04 50 daphnite 28.97 25.37 -3.59 -0.112 0.61344E+04 52 chlorite-Al-free 47.17 43.13 -4.04 -0.168 0.68984E+04 54 chloritoid-Fe 9.17 4.99 -4.18 -0.279 0.71381E+04 55 chloritoid-Mn 11.40 7.56 -3.84 -0.256 0.65616E+04 57 coesite -2.38 -3.16 -0.78 -0.260 0.13336E+04 64 cristobalite -2.56 -3.16 -0.60 -0.199 0.10189E+04 66 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71234E+04 68 diaspore 2.87 0.74 -2.14 -0.356 0.36460E+04 69 diamond -3.10 -7.40 -4.30 -1.229 0.73454E+04 70 diopside 16.18 16.06 -0.12 -0.012 0.20434E+03 71 hedenbergite 14.21 13.44 -0.77 -0.077 0.13091E+04 74 enstatite 17.26 12.27 -4.99 -0.499 0.85238E+04 76 clinoenstatite 17.17 12.27 -4.89 -0.489 0.83554E+04 78 epidote 24.67 22.70 -1.97 -0.096 0.33647E+04 79 clinozoisite 22.81 18.91 -3.90 -0.177 0.66547E+04 80 epidote-Fe 29.84 26.49 -3.35 -0.174 0.57212E+04 81 fayalite 14.05 10.19 -3.86 -0.551 0.65840E+04 82 ferrosilite 11.15 7.03 -4.12 -0.412 0.70294E+04 86 gibbsite 4.08 0.74 -3.34 -0.477 0.57045E+04 87 glaucophane 22.97 20.80 -2.18 -0.059 0.37158E+04 88 glaucophane-Fe 17.28 12.94 -4.34 -0.117 0.74062E+04 89 graphite -3.55 -7.40 -3.86 -1.102 0.65876E+04 90 greenalite 16.14 13.71 -2.43 -0.203 0.41551E+04 93 hematite 12.57 9.06 -3.51 -0.425 0.59897E+04 94 heulandite -5.83 -7.54 -1.71 -0.078 0.29252E+04 98 jadeite 4.22 2.77 -1.44 -0.144 0.24623E+04 100 kalsilite 7.58 3.83 -3.76 -0.537 0.64137E+04 101 kaolinite -1.33 -4.84 -3.50 -0.319 0.59840E+04 104 laumontite 2.88 1.93 -0.95 -0.064 0.16265E+04 105 lawsonite 9.62 8.24 -1.37 -0.091 0.23411E+04 106 leucite 4.12 0.67 -3.45 -0.345 0.58878E+04 108 lizardite 23.24 21.57 -1.68 -0.140 0.28643E+04 110 magnetite 20.09 15.73 -4.36 -0.356 0.74373E+04 111 minnesotaite 10.39 7.39 -3.00 -0.176 0.51160E+04 115 manganosite 14.06 9.24 -4.82 -1.205 0.82294E+04 119 microcline -2.49 -2.49 0.00 0.000 0.53965E-02 123 muscovite 2.58 -1.01 -3.59 -0.211 0.61335E+04 124 paragonite 4.24 1.09 -3.15 -0.185 0.53726E+04 125 nepheline 8.34 5.93 -2.41 -0.344 0.41136E+04 131 periclase-Fe 11.63 6.67 -4.95 -1.238 0.84574E+04 137 phlogopite-Na 29.65 27.50 -2.15 -0.119 0.36713E+04 139 prehnite 19.37 18.17 -1.20 -0.071 0.20518E+04 140 prehnite-Fe 22.50 21.96 -0.54 -0.032 0.91674E+03 141 pumpellyite-Fe 46.27 43.75 -2.52 -0.056 0.42980E+04 142 pumpellyite-Mg 48.99 46.37 -2.62 -0.058 0.44779E+04 146 pyrrhotite -4.26 -8.06 -3.80 -1.265 0.64822E+04 147 pyrrhotiteFe0.875 -6.02 -9.42 -3.41 -1.253 0.58151E+04 148 pyroxmangite 7.40 6.08 -1.32 -0.263 0.22493E+04 149 pyrophyllite -6.18 -11.15 -4.98 -0.311 0.84959E+04 150 quartz -2.99 -3.16 -0.17 -0.056 0.28625E+03 155 rhodonite 7.45 6.08 -1.36 -0.273 0.23295E+04 156 sanidine -1.28 -2.49 -1.21 -0.093 0.20678E+04 166 stilbite -7.52 -7.54 -0.02 -0.001 0.31387E+02 167 stilpnomelane-Fe 13.02 12.71 -0.31 -0.009 0.52361E+03 168 stilpnomelane-Mg 27.44 25.81 -1.63 -0.049 0.27841E+04 174 talc 16.49 15.25 -1.24 -0.073 0.21153E+04 177 tephroite 18.09 15.32 -2.77 -0.395 0.47228E+04 181 tridymite -2.63 -3.16 -0.53 -0.177 0.90623E+03 182 tremolite 47.87 47.38 -0.49 -0.013 0.84297E+03 183 ferroactinolite 38.45 34.28 -4.18 -0.113 0.71327E+04 184 troilite-low -4.41 -8.06 -3.65 -1.215 0.62250E+04 190 wairakite 3.95 1.93 -2.02 -0.119 0.34485E+04 191 walstromite 11.51 9.93 -1.58 -0.317 0.27046E+04 192 wollastonite 10.46 9.93 -0.54 -0.107 0.91502E+03 193 pseudo-wollastonite 11.00 9.93 -1.07 -0.215 0.18348E+04 194 zoisite 22.85 18.91 -3.94 -0.179 0.67288E+04 195 akaganeite 7.75 4.53 -3.23 -0.697 0.55074E+04 202 chalcedony -2.80 -3.16 -0.35 -0.118 0.60555E+03 204 montmorillonite-Ca -2.29 -6.17 -3.88 -0.240 0.66233E+04 205 montmorillonite-K -2.24 -6.27 -4.03 -0.247 0.68817E+04 206 montmorillonite-Mg -2.48 -6.79 -4.32 -0.267 0.73678E+04 207 montmorillonite-Na -2.04 -5.57 -3.54 -0.216 0.60366E+04 208 nontronite-Ca 3.21 -0.13 -3.34 -0.217 0.57038E+04 209 nontronite-H 2.53 -2.28 -4.82 -0.323 0.82253E+04 210 nontronite-K 3.34 -0.22 -3.56 -0.229 0.60854E+04 211 nontronite-Mg 3.07 -0.75 -3.83 -0.248 0.65323E+04 212 nontronite-Na 3.52 0.47 -3.05 -0.196 0.52062E+04 228 tobermorite 9.82 7.74 -2.08 -0.568 0.35559E+04 234 alabandite -0.98 -5.49 -4.51 -1.505 0.77071E+04 237 boehmite 4.41 0.74 -3.67 -0.611 0.62629E+04 239 ferrous-oxide 9.81 6.67 -3.14 -0.785 0.53584E+04 245 silica-amorphous -2.09 -3.16 -1.07 -0.355 0.18197E+04 247 an20ab80 2.02 1.34 -0.68 -0.052 0.11540E+04 248 an25ab75 2.65 1.77 -0.87 -0.067 0.14895E+04 249 an30ab70 3.28 2.20 -1.07 -0.083 0.18346E+04 250 tr.625ac.25prg.125 45.16 45.05 -0.12 -0.003 0.19843E+03 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 0.0000100 MOLES Current total amount of reactant added: 0.0000600 MOLES New total amount of reactant added: 0.0000700 MOLES Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.5508E-08 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 6 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 0.0000700 Water: Moles liquid = 0.4985E+02 kg liquid = 0.8981E+00 Moles total = 0.4985E+02 kg total = 0.8980E+00 Activity = 1.0000 Stoichiometric ionic strength = .1133468E-01 Osmotic coef. = 0.9691 True ionic strength = .2002100E-01 Chg. balance for total moles = -.5508E-08 Max. difference allowed = 0.1383E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.88386E-10 -10.0536 0.74265E-10 -10.1292 0.84024E+00 -0.0756 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.15329E-03 -3.8145 0.12803E-03 -3.8927 0.83519E+00 -0.0782 4 SO4-- 0.53423E-11 -11.2723 0.27742E-11 -11.5569 0.51929E+00 -0.2846 5 HCO3- 0.19535E-05 -5.7092 0.16340E-05 -5.7868 0.83641E+00 -0.0776 6 HS- 0.30288E-04 -4.5187 0.25300E-04 -4.5969 0.83531E+00 -0.0782 7 Al+++ 0.97050E-29 -29.0130 0.22420E-29 -29.6494 0.23101E+00 -0.6364 8 H4SiO4 0.69660E-03 -3.1570 0.69660E-03 -3.1570 0.10000E+01 0.0000 9 Ca++ 0.12880E-06 -6.8901 0.66392E-07 -7.1779 0.51548E+00 -0.2878 10 Mg++ 0.21122E-10 -10.6753 0.10838E-10 -10.9651 0.51312E+00 -0.2898 11 Fe++ 0.50044E-13 -13.3006 0.25707E-13 -13.5900 0.51368E+00 -0.2893 12 K+ 0.15651E-03 -3.8055 0.13094E-03 -3.8829 0.83661E+00 -0.0775 13 Na+ 0.19860E-01 -1.7020 0.16584E-01 -1.7803 0.83504E+00 -0.0783 14 Mn++ 0.18577E-10 -10.7310 0.95504E-11 -11.0200 0.51411E+00 -0.2889 15 F- 0.14207E-06 -6.8475 0.11841E-06 -6.9266 0.83347E+00 -0.0791 16 HPO4-- 0.45316E-07 -7.3437 0.23536E-07 -7.6283 0.51936E+00 -0.2845 18 HSiO3- 0.10487E-01 -1.9794 0.87584E-02 -2.0576 0.83519E+00 -0.0782 19 Ca(HSiO3)+ 0.15826E-07 -7.8006 0.13243E-07 -7.8780 0.83679E+00 -0.0774 20 Mg(HSiO3)+ 0.32151E-11 -11.4928 0.26903E-11 -11.5702 0.83679E+00 -0.0774 21 NaHSiO3,aq 0.23492E-02 -2.6291 0.23492E-02 -2.6291 0.10000E+01 0.0000 22 AlO+ 0.66087E-16 -16.1799 0.55301E-16 -16.2573 0.83679E+00 -0.0774 24 HAlO2,aq 0.14829E-09 -9.8289 0.14829E-09 -9.8289 0.10000E+01 0.0000 25 AlO2- 0.53019E-05 -5.2756 0.44201E-05 -5.3546 0.83368E+00 -0.0790 26 CH4,aq 0.14525E-04 -4.8379 0.14475E-04 -4.8394 0.99654E+00 -0.0015 27 C2H6,aq 0.50389E-14 -14.2977 0.50215E-14 -14.2992 0.99654E+00 -0.0015 31 CO,aq 0.46463E-16 -16.3329 0.46463E-16 -16.3329 0.10000E+01 0.0000 32 CO2,aq 0.26019E-09 -9.5847 0.25929E-09 -9.5862 0.99654E+00 -0.0015 33 CO3-2 0.37086E-05 -5.4308 0.19218E-05 -5.7163 0.51819E+00 -0.2855 34 CaCO3,aq 0.15998E-08 -8.7959 0.15998E-08 -8.7959 0.10000E+01 0.0000 35 Ca(HCO3)+ 0.33092E-11 -11.4803 0.27691E-11 -11.5577 0.83679E+00 -0.0774 36 CaCl+ 0.16439E-10 -10.7841 0.13756E-10 -10.8615 0.83679E+00 -0.0774 37 CaCl2,aq 0.41841E-15 -15.3784 0.41841E-15 -15.3784 0.10000E+01 0.0000 38 CaF+ 0.13717E-12 -12.8628 0.11478E-12 -12.9401 0.83679E+00 -0.0774 39 CaOH+ 0.76141E-07 -7.1184 0.63714E-07 -7.1958 0.83679E+00 -0.0774 40 CaSO4,aq 0.58487E-16 -16.2329 0.58487E-16 -16.2329 0.10000E+01 0.0000 41 HCl,aq 0.17423E-14 -14.7589 0.17423E-14 -14.7589 0.10000E+01 0.0000 45 HF,aq 0.60200E-13 -13.2204 0.60200E-13 -13.2204 0.10000E+01 0.0000 48 FeCl+ 0.62255E-17 -17.2058 0.52094E-17 -17.2832 0.83679E+00 -0.0774 51 FeF+ 0.18589E-18 -18.7307 0.15555E-18 -18.8081 0.83679E+00 -0.0774 53 FeO,aq 0.18115E-09 -9.7420 0.18115E-09 -9.7420 0.10000E+01 0.0000 54 FeOH+ 0.13465E-10 -10.8708 0.11267E-10 -10.9482 0.83679E+00 -0.0774 55 HFeO2- 0.30558E-07 -7.5149 0.25522E-07 -7.5931 0.83519E+00 -0.0782 56 FeO+ 0.12025E-16 -16.9199 0.10063E-16 -16.9973 0.83679E+00 -0.0774 58 FeO2- 0.44699E-09 -9.3497 0.37332E-09 -9.4279 0.83519E+00 -0.0782 59 HFeO2,aq 0.35262E-11 -11.4527 0.35262E-11 -11.4527 0.10000E+01 0.0000 60 H2,aq 0.71579E-05 -5.1452 0.71332E-05 -5.1467 0.99654E+00 -0.0015 61 KCl,aq 0.30383E-09 -9.5174 0.30383E-09 -9.5174 0.10000E+01 0.0000 63 KOH,aq 0.75294E-06 -6.1232 0.75294E-06 -6.1232 0.10000E+01 0.0000 64 KSO4- 0.67489E-14 -14.1708 0.56366E-14 -14.2490 0.83519E+00 -0.0782 65 MgCO3,aq 0.65461E-13 -13.1840 0.65461E-13 -13.1840 0.10000E+01 0.0000 66 Mg(HCO3)+ 0.55199E-15 -15.2581 0.46190E-15 -15.3355 0.83679E+00 -0.0774 67 MgCl+ 0.24322E-14 -14.6140 0.20352E-14 -14.6914 0.83679E+00 -0.0774 68 MgF+ 0.82944E-16 -16.0812 0.69407E-16 -16.1586 0.83679E+00 -0.0774 69 MgOH+ 0.68777E-10 -10.1626 0.57552E-10 -10.2399 0.83679E+00 -0.0774 71 MnF+ 0.22763E-16 -16.6428 0.19048E-16 -16.7202 0.83679E+00 -0.0774 72 MnO,aq 0.17932E-08 -8.7464 0.17932E-08 -8.7464 0.10000E+01 0.0000 73 MnOH+ 0.46471E-09 -9.3328 0.38886E-09 -9.4102 0.83679E+00 -0.0774 74 MnO2-2 0.20823E-10 -10.6814 0.10790E-10 -10.9670 0.51819E+00 -0.2855 75 HMnO2- 0.21021E-09 -9.6774 0.17556E-09 -9.7556 0.83519E+00 -0.0782 78 MnCl+ 0.89980E-14 -14.0459 0.75294E-14 -14.1232 0.83679E+00 -0.0774 80 NaCl,aq 0.70365E-06 -6.1526 0.70365E-06 -6.1526 0.10000E+01 0.0000 81 NaF,aq 0.45975E-09 -9.3375 0.45975E-09 -9.3375 0.10000E+01 0.0000 82 NaOH,aq 0.95944E-04 -4.0180 0.95944E-04 -4.0180 0.10000E+01 0.0000 84 OH- 0.93319E-02 -2.0300 0.77798E-02 -2.1090 0.83368E+00 -0.0790 89 HPO3-2 0.10096E-14 -14.9958 0.52318E-15 -15.2813 0.51819E+00 -0.2855 91 H2PO3- 0.93289E-19 -19.0302 0.77915E-19 -19.1084 0.83519E+00 -0.0782 92 H3PO4,aq 0.90786E-18 -18.0420 0.90786E-18 -18.0420 0.10000E+01 0.0000 93 H2PO4- 0.38570E-10 -10.4138 0.32244E-10 -10.4916 0.83598E+00 -0.0778 94 PO4-3 0.10657E-08 -8.9724 0.25857E-09 -9.5874 0.24263E+00 -0.6151 98 HP2O7-3 0.94783E-18 -18.0233 0.21918E-18 -18.6592 0.23124E+00 -0.6359 99 P2O7-4 0.91450E-17 -17.0388 0.70506E-18 -18.1518 0.77097E-01 -1.1130 100 H2S,aq 0.58271E-08 -8.2345 0.58070E-08 -8.2360 0.99654E+00 -0.0015 101 S2-2 0.38371E-14 -14.4160 0.19883E-14 -14.7015 0.51819E+00 -0.2855 107 SO3-2 0.48918E-17 -17.3105 0.25715E-17 -17.5898 0.52568E+00 -0.2793 108 HSO3- 0.14317E-19 -19.8441 0.11957E-19 -19.9224 0.83519E+00 -0.0782 109 HSO4- 0.23704E-18 -18.6252 0.19855E-18 -18.7021 0.83761E+00 -0.0770 Charge balance for all species = -.6133E-08 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.8838551E-10 -.2229141E-01 -.2242935E+02 0.0000 2 H2O 0.1000000E+01 0.5550488E+02 0.9981991E+06 0.0000 3 Cl- 0.1532923E-03 0.1539962E-03 0.5450140E+01 6.2365 4 SO4-- 0.5342261E-11 -.1631456E-04 -.1564479E+01 8.7016 5 HCO3- 0.1953540E-05 0.2018917E-04 0.1229746E+01 4.3425 6 HS- 0.3028791E-04 0.4660831E-04 0.1538751E+01 5.5323 7 Al+++ 0.9704952E-29 0.5302054E-05 0.1428088E+00 0.7383 8 H4SiO4 0.6966022E-03 0.1353254E-01 0.1298425E+04 -3.1570 9 Ca++ 0.1287977E-06 0.2223838E-06 0.8897209E-02 13.0805 10 Mg++ 0.2112168E-10 0.9318273E-10 0.2261521E-05 9.2934 11 Fe++ 0.5004431E-13 0.3120343E-07 0.1739589E-02 6.6685 12 K+ 0.1565081E-03 0.1572613E-03 0.6138544E+01 6.2463 13 Na+ 0.1986025E-01 0.2230612E-01 0.5119220E+03 8.3489 14 Mn++ 0.1857663E-10 0.2507572E-08 0.1375216E-03 9.2384 15 F- 0.1420702E-06 0.1425301E-06 0.2703082E-02 3.2026 16 HPO4-- 0.4531626E-07 0.4642050E-07 0.4447650E-02 12.6302 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.2001900E-01 -.2001892E-01 -.7954764E-07 0.0000000E+00 2 H2O 0.4984647E+02 0.4984647E+02 -.5349190E-07 0.0000000E+00 3 Cl- 0.1382972E-03 0.1382972E-03 0.0000000E+00 0.0000000E+00 4 SO4-- -.1465081E-04 -.1465138E-04 0.5712323E-09 0.0000000E+00 5 HCO3- 0.1813100E-04 0.1813100E-04 0.0000000E+00 0.0000000E+00 6 HS- 0.4185628E-04 0.4185685E-04 -.5712323E-09 0.0000000E+00 7 Al+++ 0.4775352E-05 0.4761540E-05 0.1381218E-07 0.0000000E+00 8 H4SiO4 0.1215302E-01 0.1215297E-01 0.4677567E-07 0.0000000E+00 9 Ca++ 0.2080835E-06 0.1997131E-06 0.8370442E-08 0.0000000E+00 10 Mg++ 0.8368328E-10 0.8368328E-10 0.0000000E+00 0.0000000E+00 11 Fe++ 0.3259227E-07 0.2802241E-07 0.4569858E-08 0.0000000E+00 12 K+ 0.1412294E-03 0.1412294E-03 0.0000000E+00 0.0000000E+00 13 Na+ 0.2003215E-01 0.2003214E-01 0.1280174E-07 0.0000000E+00 14 Mn++ 0.2251939E-08 0.2251939E-08 0.0000000E+00 0.0000000E+00 15 F- 0.1280000E-06 0.1280000E-06 0.0000000E+00 0.0000000E+00 16 HPO4-- 0.4168819E-07 0.4168819E-07 0.0000000E+00 0.0000000E+00 Chg. balance for solid moles: -.1158E-22 Mass of aqueous solution: 0.899619E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 0.0000700 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 0.1280E-07 -7.893 0.3357E-05 -5.474 70.74 0.1289E-05 andradite 0.2285E-08 -8.641 0.1161E-05 -5.935 24.47 0.3017E-06 grossular 0.5052E-09 -9.297 0.2276E-06 -6.643 4.796 0.6332E-07 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8189E+00 0.8189E+00 1.0000 -0.087 grossular 0.1811E+00 0.1811E+00 1.0000 -0.742 Solid products produced: Mass = 0.000005 g Volume = 0.000002 cm3 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.0000700 moles log = -4.1549 Original solution: 1000.0103000 g Original solution / Rock added: 14285861.43 (Water/Rock Ratio), log = 7.1549 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0511 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9711E+00 0.9855 0.1006E+01 0.1021E+01 CO2,gas 0.2621E-07 1.0069 0.2774E-07 0.2755E-07 CH4,gas 0.2002E-01 1.0124 0.2131E-01 0.2105E-01 H2,gas 0.8904E-02 1.0006 0.9365E-02 0.9360E-02 H2S,gas 0.1525E-06 0.9959 0.1596E-06 0.1603E-06 S2,gas 0.1038E-28 1.0000 0.1091E-28 0.1091E-28 CO,gas 0.6587E-13 1.0000 0.6924E-13 0.6924E-13 SO3,gas 0.5504E-47 1.0000 0.5785E-47 0.5785E-47 SO2,gas 0.2005E-26 1.0000 0.2108E-26 0.2108E-26 HF,gas 0.1406E-15 1.0000 0.1478E-15 0.1478E-15 HCl,gas 0.2925E-17 1.0000 0.3074E-17 0.3074E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 17 albite -0.38 -0.38 0.00 0.000 -0.94784E-12 23 andradite 39.01 39.01 0.00 0.000 0.12132E-10 24 grossular 32.73 32.73 0.00 0.000 0.12132E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -15.92 -9.26 -3.085 0.15804E+05 -7.557 3 CH4,gas 4.54 1.17 -3.37 -0.843 0.57550E+04 -1.671 4 H2,gas 8.00 4.27 -3.73 -2.130 0.63645E+04 -2.028 5 H2S,gas -6.23 -14.73 -8.50 -4.248 0.14506E+05 -6.797 6 S2,gas -7.34 -38.00 -30.66 -4.717 0.52353E+05 -28.962 7 CO,gas 3.21 -11.64 -14.86 -4.572 0.25371E+05 -13.160 8 SO3,gas 17.12 -31.82 -48.94 -12.234 0.83558E+05 -47.238 9 SO2,gas 0.83 -27.54 -28.38 -7.567 0.48450E+05 -26.676 10 HF,gas 0.47 -17.06 -17.53 -8.765 0.29931E+05 -15.830 11 HCl,gas 5.19 -14.02 -19.21 -9.606 0.32803E+05 -17.512 12 acmite 7.71 6.57 -1.14 -0.119 0.19508E+04 16 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 20 spessartine 24.46 19.72 -4.74 -0.237 0.80874E+04 21 analcite 3.32 2.77 -0.55 -0.061 0.93691E+03 27 annite 20.12 17.52 -2.60 -0.145 0.44471E+04 28 phlogopite 27.06 25.39 -1.67 -0.093 0.28531E+04 30 anorthite 12.71 8.24 -4.47 -0.344 0.76277E+04 33 apatite-OH -18.15 -18.26 -0.10 -0.008 0.17740E+03 34 apatite-F -34.30 -35.31 -1.01 -0.084 0.17283E+04 38 aragonite 0.97 -2.84 -3.80 -1.267 0.64917E+04 39 brucite 12.57 9.29 -3.28 -0.655 0.55923E+04 40 calcite 0.81 -2.84 -3.65 -1.216 0.62275E+04 41 carnegieite-low 9.02 5.93 -3.09 -0.442 0.52814E+04 42 carnegieite-high 10.09 5.93 -4.16 -0.595 0.71084E+04 43 carpholite-Mg 8.58 4.46 -4.13 -0.275 0.70454E+04 44 carpholite-Fe 6.71 1.83 -4.88 -0.325 0.83353E+04 45 celadonite 5.34 3.65 -1.69 -0.100 0.28886E+04 46 celadonite-Fe 3.88 1.02 -2.85 -0.168 0.48690E+04 47 chrysotile 23.89 21.57 -2.33 -0.194 0.39721E+04 49 clinochlore 39.07 38.47 -0.60 -0.019 0.10196E+04 50 daphnite 28.97 25.35 -3.62 -0.113 0.61766E+04 52 chlorite-Al-free 47.17 43.13 -4.04 -0.168 0.68994E+04 54 chloritoid-Fe 9.17 4.99 -4.19 -0.279 0.71468E+04 55 chloritoid-Mn 11.40 7.56 -3.84 -0.256 0.65620E+04 57 coesite -2.38 -3.16 -0.78 -0.260 0.13335E+04 64 cristobalite -2.56 -3.16 -0.60 -0.199 0.10188E+04 66 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71234E+04 68 diaspore 2.87 0.74 -2.14 -0.356 0.36462E+04 69 diamond -3.10 -7.37 -4.27 -1.220 0.72892E+04 70 diopside 16.18 16.06 -0.12 -0.012 0.20741E+03 71 hedenbergite 14.21 13.43 -0.77 -0.077 0.13204E+04 74 enstatite 17.26 12.27 -4.99 -0.499 0.85240E+04 76 clinoenstatite 17.17 12.27 -4.89 -0.489 0.83556E+04 78 epidote 24.67 22.70 -1.97 -0.096 0.33654E+04 79 clinozoisite 22.81 18.90 -3.90 -0.177 0.66611E+04 80 epidote-Fe 29.84 26.49 -3.35 -0.174 0.57163E+04 81 fayalite 14.05 10.18 -3.87 -0.552 0.66007E+04 82 ferrosilite 11.15 7.02 -4.13 -0.413 0.70459E+04 86 gibbsite 4.08 0.74 -3.34 -0.477 0.57047E+04 87 glaucophane 22.97 20.80 -2.18 -0.059 0.37162E+04 88 glaucophane-Fe 17.28 12.92 -4.35 -0.118 0.74312E+04 89 graphite -3.55 -7.37 -3.83 -1.093 0.65314E+04 90 greenalite 16.14 13.69 -2.45 -0.204 0.41801E+04 93 hematite 12.57 9.06 -3.50 -0.424 0.59788E+04 94 heulandite -5.83 -7.54 -1.71 -0.078 0.29279E+04 98 jadeite 4.22 2.77 -1.44 -0.144 0.24624E+04 100 kalsilite 7.58 3.83 -3.76 -0.537 0.64139E+04 101 kaolinite -1.33 -4.84 -3.50 -0.319 0.59842E+04 104 laumontite 2.88 1.93 -0.95 -0.064 0.16296E+04 105 lawsonite 9.62 8.24 -1.37 -0.092 0.23444E+04 106 leucite 4.12 0.67 -3.45 -0.345 0.58880E+04 108 lizardite 23.24 21.57 -1.68 -0.140 0.28647E+04 110 magnetite 20.09 15.73 -4.35 -0.355 0.74348E+04 111 minnesotaite 10.39 7.38 -3.01 -0.177 0.51408E+04 115 manganosite 14.06 9.24 -4.82 -1.205 0.82294E+04 119 microcline -2.49 -2.49 0.00 0.000 0.61888E-02 123 muscovite 2.58 -1.01 -3.59 -0.211 0.61339E+04 124 paragonite 4.24 1.09 -3.15 -0.185 0.53730E+04 125 nepheline 8.34 5.93 -2.41 -0.344 0.41138E+04 131 periclase-Fe 11.63 6.67 -4.96 -1.240 0.84658E+04 137 phlogopite-Na 29.65 27.50 -2.15 -0.119 0.36719E+04 139 prehnite 19.37 18.17 -1.21 -0.071 0.20580E+04 140 prehnite-Fe 22.50 21.96 -0.54 -0.032 0.91729E+03 141 pumpellyite-Fe 46.27 43.74 -2.53 -0.056 0.43191E+04 142 pumpellyite-Mg 48.99 46.36 -2.63 -0.058 0.44907E+04 146 pyrrhotite -4.26 -8.06 -3.80 -1.266 0.64838E+04 147 pyrrhotiteFe0.875 -6.02 -9.42 -3.40 -1.252 0.58122E+04 148 pyroxmangite 7.40 6.08 -1.32 -0.263 0.22492E+04 149 pyrophyllite -6.18 -11.15 -4.98 -0.311 0.84959E+04 150 quartz -2.99 -3.16 -0.17 -0.056 0.28614E+03 155 rhodonite 7.45 6.08 -1.36 -0.273 0.23294E+04 156 sanidine -1.28 -2.49 -1.21 -0.093 0.20678E+04 166 stilbite -7.52 -7.54 -0.02 -0.001 0.34088E+02 167 stilpnomelane-Fe 13.02 12.69 -0.33 -0.010 0.56523E+03 168 stilpnomelane-Mg 27.44 25.81 -1.63 -0.049 0.27848E+04 174 talc 16.49 15.25 -1.24 -0.073 0.21156E+04 177 tephroite 18.09 15.32 -2.77 -0.395 0.47227E+04 181 tridymite -2.63 -3.16 -0.53 -0.177 0.90612E+03 182 tremolite 47.87 47.37 -0.50 -0.013 0.84932E+03 183 ferroactinolite 38.45 34.25 -4.21 -0.114 0.71800E+04 184 troilite-low -4.41 -8.06 -3.65 -1.216 0.62266E+04 190 wairakite 3.95 1.93 -2.02 -0.119 0.34515E+04 191 walstromite 11.51 9.92 -1.59 -0.317 0.27075E+04 192 wollastonite 10.46 9.92 -0.54 -0.108 0.91797E+03 193 pseudo-wollastonite 11.00 9.92 -1.08 -0.215 0.18378E+04 194 zoisite 22.85 18.90 -3.94 -0.179 0.67352E+04 195 akaganeite 7.75 4.53 -3.22 -0.697 0.55019E+04 202 chalcedony -2.80 -3.16 -0.35 -0.118 0.60544E+03 204 montmorillonite-Ca -2.29 -6.17 -3.88 -0.240 0.66238E+04 205 montmorillonite-K -2.24 -6.27 -4.03 -0.247 0.68817E+04 206 montmorillonite-Mg -2.48 -6.79 -4.32 -0.267 0.73678E+04 207 montmorillonite-Na -2.04 -5.57 -3.54 -0.216 0.60366E+04 208 nontronite-Ca 3.21 -0.12 -3.33 -0.216 0.56931E+04 209 nontronite-H 2.53 -2.28 -4.81 -0.322 0.82141E+04 210 nontronite-K 3.34 -0.22 -3.56 -0.228 0.60741E+04 211 nontronite-Mg 3.07 -0.74 -3.82 -0.248 0.65211E+04 212 nontronite-Na 3.52 0.48 -3.04 -0.195 0.51950E+04 228 tobermorite 9.82 7.74 -2.08 -0.569 0.35583E+04 234 alabandite -0.98 -5.49 -4.51 -1.503 0.77003E+04 237 boehmite 4.41 0.74 -3.67 -0.611 0.62631E+04 239 ferrous-oxide 9.81 6.67 -3.14 -0.786 0.53668E+04 245 silica-amorphous -2.09 -3.16 -1.07 -0.355 0.18196E+04 247 an20ab80 2.02 1.34 -0.68 -0.052 0.11547E+04 248 an25ab75 2.65 1.77 -0.87 -0.067 0.14903E+04 249 an30ab70 3.28 2.20 -1.08 -0.083 0.18356E+04 250 tr.625ac.25prg.125 45.16 45.04 -0.13 -0.003 0.21510E+03 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 0.0000100 MOLES Current total amount of reactant added: 0.0000700 MOLES New total amount of reactant added: 0.0000800 MOLES Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.5508E-08 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 6 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 0.0000800 Water: Moles liquid = 0.4985E+02 kg liquid = 0.8981E+00 Moles total = 0.4985E+02 kg total = 0.8980E+00 Activity = 1.0000 Stoichiometric ionic strength = .1133532E-01 Osmotic coef. = 0.9691 True ionic strength = .2002155E-01 Chg. balance for total moles = -.5508E-08 Max. difference allowed = 0.1384E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.88400E-10 -10.0535 0.74278E-10 -10.1291 0.84024E+00 -0.0756 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.15336E-03 -3.8143 0.12808E-03 -3.8925 0.83519E+00 -0.0782 4 SO4-- 0.61499E-11 -11.2111 0.31936E-11 -11.4957 0.51929E+00 -0.2846 5 HCO3- 0.22297E-05 -5.6517 0.18650E-05 -5.7293 0.83641E+00 -0.0776 6 HS- 0.30558E-04 -4.5149 0.25526E-04 -4.5930 0.83531E+00 -0.0782 7 Al+++ 0.97070E-29 -29.0129 0.22424E-29 -29.6493 0.23101E+00 -0.6364 8 H4SiO4 0.69671E-03 -3.1569 0.69671E-03 -3.1569 0.10000E+01 0.0000 9 Ca++ 0.12836E-06 -6.8916 0.66166E-07 -7.1794 0.51547E+00 -0.2878 10 Mg++ 0.21122E-10 -10.6753 0.10838E-10 -10.9650 0.51312E+00 -0.2898 11 Fe++ 0.49570E-13 -13.3048 0.25463E-13 -13.5941 0.51368E+00 -0.2893 12 K+ 0.15651E-03 -3.8055 0.13094E-03 -3.8829 0.83661E+00 -0.0775 13 Na+ 0.19860E-01 -1.7020 0.16584E-01 -1.7803 0.83504E+00 -0.0783 14 Mn++ 0.18583E-10 -10.7309 0.95534E-11 -11.0198 0.51410E+00 -0.2889 15 F- 0.14651E-06 -6.8341 0.12211E-06 -6.9132 0.83347E+00 -0.0791 16 HPO4-- 0.45316E-07 -7.3437 0.23535E-07 -7.6283 0.51936E+00 -0.2845 18 HSiO3- 0.10487E-01 -1.9794 0.87583E-02 -2.0576 0.83519E+00 -0.0782 19 Ca(HSiO3)+ 0.15772E-07 -7.8021 0.13197E-07 -7.8795 0.83679E+00 -0.0774 20 Mg(HSiO3)+ 0.32151E-11 -11.4928 0.26904E-11 -11.5702 0.83679E+00 -0.0774 21 NaHSiO3,aq 0.23492E-02 -2.6291 0.23492E-02 -2.6291 0.10000E+01 0.0000 22 AlO+ 0.66078E-16 -16.1799 0.55294E-16 -16.2573 0.83679E+00 -0.0774 24 HAlO2,aq 0.14825E-09 -9.8290 0.14825E-09 -9.8290 0.10000E+01 0.0000 25 AlO2- 0.52994E-05 -5.2758 0.44180E-05 -5.3548 0.83368E+00 -0.0790 26 CH4,aq 0.14530E-04 -4.8377 0.14480E-04 -4.8392 0.99654E+00 -0.0015 27 C2H6,aq 0.52116E-14 -14.2830 0.51936E-14 -14.2845 0.99654E+00 -0.0015 31 CO,aq 0.51318E-16 -16.2897 0.51318E-16 -16.2897 0.10000E+01 0.0000 32 CO2,aq 0.29702E-09 -9.5272 0.29600E-09 -9.5287 0.99654E+00 -0.0015 33 CO3-2 0.42323E-05 -5.3734 0.21931E-05 -5.6589 0.51818E+00 -0.2855 34 CaCO3,aq 0.18195E-08 -8.7401 0.18195E-08 -8.7401 0.10000E+01 0.0000 35 Ca(HCO3)+ 0.37642E-11 -11.4243 0.31498E-11 -11.5017 0.83679E+00 -0.0774 36 CaCl+ 0.16390E-10 -10.7854 0.13715E-10 -10.8628 0.83679E+00 -0.0774 37 CaCl2,aq 0.41734E-15 -15.3795 0.41734E-15 -15.3795 0.10000E+01 0.0000 38 CaF+ 0.14097E-12 -12.8509 0.11796E-12 -12.9283 0.83679E+00 -0.0774 39 CaOH+ 0.75869E-07 -7.1199 0.63486E-07 -7.1973 0.83679E+00 -0.0774 40 CaSO4,aq 0.67099E-16 -16.1733 0.67099E-16 -16.1733 0.10000E+01 0.0000 41 HCl,aq 0.17433E-14 -14.7586 0.17433E-14 -14.7586 0.10000E+01 0.0000 45 HF,aq 0.62092E-13 -13.2070 0.62092E-13 -13.2070 0.10000E+01 0.0000 48 FeCl+ 0.61690E-17 -17.2098 0.51622E-17 -17.2872 0.83679E+00 -0.0774 51 FeF+ 0.18988E-18 -18.7215 0.15889E-18 -18.7989 0.83679E+00 -0.0774 53 FeO,aq 0.17937E-09 -9.7462 0.17937E-09 -9.7462 0.10000E+01 0.0000 54 FeOH+ 0.13335E-10 -10.8750 0.11159E-10 -10.9524 0.83679E+00 -0.0774 55 HFeO2- 0.30253E-07 -7.5192 0.25267E-07 -7.5974 0.83519E+00 -0.0782 56 FeO+ 0.12107E-16 -16.9169 0.10131E-16 -16.9943 0.83679E+00 -0.0774 58 FeO2- 0.44990E-09 -9.3469 0.37575E-09 -9.4251 0.83519E+00 -0.0782 59 HFeO2,aq 0.35497E-11 -11.4498 0.35497E-11 -11.4498 0.10000E+01 0.0000 60 H2,aq 0.69255E-05 -5.1596 0.69015E-05 -5.1611 0.99654E+00 -0.0015 61 KCl,aq 0.30396E-09 -9.5172 0.30396E-09 -9.5172 0.10000E+01 0.0000 63 KOH,aq 0.75281E-06 -6.1233 0.75281E-06 -6.1233 0.10000E+01 0.0000 64 KSO4- 0.77692E-14 -14.1096 0.64887E-14 -14.1878 0.83519E+00 -0.0782 65 MgCO3,aq 0.74705E-13 -13.1266 0.74705E-13 -13.1266 0.10000E+01 0.0000 66 Mg(HCO3)+ 0.63004E-15 -15.2006 0.52721E-15 -15.2780 0.83679E+00 -0.0774 67 MgCl+ 0.24332E-14 -14.6138 0.20361E-14 -14.6912 0.83679E+00 -0.0774 68 MgF+ 0.85538E-16 -16.0678 0.71577E-16 -16.1452 0.83679E+00 -0.0774 69 MgOH+ 0.68768E-10 -10.1626 0.57544E-10 -10.2400 0.83679E+00 -0.0774 71 MnF+ 0.23482E-16 -16.6293 0.19649E-16 -16.7067 0.83679E+00 -0.0774 72 MnO,aq 0.17932E-08 -8.7464 0.17932E-08 -8.7464 0.10000E+01 0.0000 73 MnOH+ 0.46478E-09 -9.3328 0.38892E-09 -9.4101 0.83679E+00 -0.0774 74 MnO2-2 0.20816E-10 -10.6816 0.10787E-10 -10.9671 0.51818E+00 -0.2855 75 HMnO2- 0.21017E-09 -9.6774 0.17553E-09 -9.7556 0.83519E+00 -0.0782 78 MnCl+ 0.90046E-14 -14.0455 0.75350E-14 -14.1229 0.83679E+00 -0.0774 80 NaCl,aq 0.70394E-06 -6.1525 0.70394E-06 -6.1525 0.10000E+01 0.0000 81 NaF,aq 0.47411E-09 -9.3241 0.47411E-09 -9.3241 0.10000E+01 0.0000 82 NaOH,aq 0.95928E-04 -4.0181 0.95928E-04 -4.0181 0.10000E+01 0.0000 84 OH- 0.93304E-02 -2.0301 0.77786E-02 -2.1091 0.83368E+00 -0.0790 89 HPO3-2 0.97685E-15 -15.0102 0.50619E-15 -15.2957 0.51818E+00 -0.2855 91 H2PO3- 0.90275E-19 -19.0444 0.75396E-19 -19.1226 0.83519E+00 -0.0782 92 H3PO4,aq 0.90816E-18 -18.0418 0.90816E-18 -18.0418 0.10000E+01 0.0000 93 H2PO4- 0.38576E-10 -10.4137 0.32249E-10 -10.4915 0.83598E+00 -0.0778 94 PO4-3 0.10655E-08 -8.9724 0.25852E-09 -9.5875 0.24263E+00 -0.6151 98 HP2O7-3 0.94799E-18 -18.0232 0.21921E-18 -18.6591 0.23124E+00 -0.6359 99 P2O7-4 0.91452E-17 -17.0388 0.70505E-18 -18.1518 0.77095E-01 -1.1130 100 H2S,aq 0.58802E-08 -8.2306 0.58598E-08 -8.2321 0.99654E+00 -0.0015 101 S2-2 0.40370E-14 -14.3939 0.20919E-14 -14.6795 0.51818E+00 -0.2855 107 SO3-2 0.54485E-17 -17.2637 0.28641E-17 -17.5430 0.52568E+00 -0.2793 108 HSO3- 0.15949E-19 -19.7973 0.13320E-19 -19.8755 0.83519E+00 -0.0782 109 HSO4- 0.27293E-18 -18.5640 0.22860E-18 -18.6409 0.83760E+00 -0.0770 Charge balance for all species = -.6133E-08 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.8840036E-10 -.2229019E-01 -.2242813E+02 0.0000 2 H2O 0.1000000E+01 0.5550487E+02 0.9981991E+06 0.0000 3 Cl- 0.1533577E-03 0.1540619E-03 0.5452464E+01 6.2366 4 SO4-- 0.6149922E-11 -.1626142E-04 -.1559383E+01 8.7626 5 HCO3- 0.2229729E-05 0.2099424E-04 0.1278783E+01 4.3998 6 HS- 0.3055844E-04 0.4682575E-04 0.1545930E+01 5.5361 7 Al+++ 0.9707041E-29 0.5299591E-05 0.1427424E+00 0.7381 8 H4SiO4 0.6967106E-03 0.1353253E-01 0.1298424E+04 -3.1569 9 Ca++ 0.1283595E-06 0.2218395E-06 0.8875430E-02 13.0789 10 Mg++ 0.2112225E-10 0.9318272E-10 0.2261521E-05 9.2932 11 Fe++ 0.4956991E-13 0.3089950E-07 0.1722645E-02 6.6642 12 K+ 0.1565082E-03 0.1572613E-03 0.6138543E+01 6.2462 13 Na+ 0.1986028E-01 0.2230611E-01 0.5119218E+03 8.3488 14 Mn++ 0.1858263E-10 0.2507571E-08 0.1375215E-03 9.2384 15 F- 0.1465099E-06 0.1469842E-06 0.2787552E-02 3.2159 16 HPO4-- 0.4531641E-07 0.4642049E-07 0.4447649E-02 12.6300 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.2001793E-01 -.2001784E-01 -.8983094E-07 0.0000000E+00 2 H2O 0.4984647E+02 0.4984647E+02 -.6226343E-07 0.0000000E+00 3 Cl- 0.1383562E-03 0.1383562E-03 0.0000000E+00 0.0000000E+00 4 SO4-- -.1460306E-04 -.1460367E-04 0.6053499E-09 0.0000000E+00 5 HCO3- 0.1885400E-04 0.1885400E-04 0.0000000E+00 0.0000000E+00 6 HS- 0.4205153E-04 0.4205214E-04 -.6053499E-09 0.0000000E+00 7 Al+++ 0.4775352E-05 0.4759328E-05 0.1602389E-07 0.0000000E+00 8 H4SiO4 0.1215302E-01 0.1215297E-01 0.5374079E-07 0.0000000E+00 9 Ca++ 0.2080835E-06 0.1992242E-06 0.8859265E-08 0.0000000E+00 10 Mg++ 0.8368328E-10 0.8368328E-10 0.0000000E+00 0.0000000E+00 11 Fe++ 0.3259227E-07 0.2774947E-07 0.4842799E-08 0.0000000E+00 12 K+ 0.1412294E-03 0.1412294E-03 0.0000000E+00 0.0000000E+00 13 Na+ 0.2003215E-01 0.2003214E-01 0.1496051E-07 0.0000000E+00 14 Mn++ 0.2251939E-08 0.2251939E-08 0.0000000E+00 0.0000000E+00 15 F- 0.1320000E-06 0.1320000E-06 0.0000000E+00 0.0000000E+00 16 HPO4-- 0.4168819E-07 0.4168819E-07 0.0000000E+00 0.0000000E+00 Chg. balance for solid moles: 0.3309E-23 Mass of aqueous solution: 0.899619E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 0.0000800 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 0.1496E-07 -7.825 0.3923E-05 -5.406 72.74 0.1506E-05 andradite 0.2421E-08 -8.616 0.1231E-05 -5.910 22.82 0.3197E-06 grossular 0.5317E-09 -9.274 0.2395E-06 -6.621 4.441 0.6664E-07 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8200E+00 0.8200E+00 1.0000 -0.086 grossular 0.1800E+00 0.1800E+00 1.0000 -0.745 Solid products produced: Mass = 0.000005 g Volume = 0.000002 cm3 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.0000800 moles log = -4.0969 Original solution: 1000.0103000 g Original solution / Rock added: 12500128.75 (Water/Rock Ratio), log = 7.0969 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0508 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9713E+00 0.9855 0.1006E+01 0.1021E+01 CO2,gas 0.2993E-07 1.0069 0.3167E-07 0.3145E-07 CH4,gas 0.2003E-01 1.0124 0.2131E-01 0.2105E-01 H2,gas 0.8618E-02 1.0006 0.9061E-02 0.9056E-02 H2S,gas 0.1539E-06 0.9959 0.1611E-06 0.1617E-06 S2,gas 0.1129E-28 1.0000 0.1186E-28 0.1186E-28 CO,gas 0.7277E-13 1.0000 0.7647E-13 0.7647E-13 SO3,gas 0.6340E-47 1.0000 0.6662E-47 0.6662E-47 SO2,gas 0.2235E-26 1.0000 0.2348E-26 0.2348E-26 HF,gas 0.1451E-15 1.0000 0.1525E-15 0.1525E-15 HCl,gas 0.2927E-17 1.0000 0.3076E-17 0.3076E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 17 albite -0.38 -0.38 0.00 0.000 -0.94784E-12 23 andradite 39.01 39.01 0.00 0.000 0.00000E+00 24 grossular 32.73 32.73 0.00 0.000 -0.12132E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -15.86 -9.20 -3.066 0.15706E+05 -7.499 3 CH4,gas 4.54 1.17 -3.37 -0.843 0.57547E+04 -1.671 4 H2,gas 8.00 4.26 -3.74 -2.138 0.63890E+04 -2.043 5 H2S,gas -6.23 -14.72 -8.49 -4.246 0.14500E+05 -6.793 6 S2,gas -7.34 -37.96 -30.62 -4.712 0.52291E+05 -28.926 7 CO,gas 3.21 -11.60 -14.82 -4.559 0.25297E+05 -13.116 8 SO3,gas 17.12 -31.75 -48.88 -12.219 0.83453E+05 -47.176 9 SO2,gas 0.83 -27.50 -28.33 -7.554 0.48370E+05 -26.629 10 HF,gas 0.47 -17.04 -17.52 -8.758 0.29908E+05 -15.817 11 HCl,gas 5.19 -14.02 -19.21 -9.605 0.32802E+05 -17.512 12 acmite 7.71 6.57 -1.14 -0.118 0.19458E+04 16 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 20 spessartine 24.46 19.72 -4.74 -0.237 0.80876E+04 21 analcite 3.32 2.77 -0.55 -0.061 0.93703E+03 27 annite 20.12 17.51 -2.62 -0.145 0.44690E+04 28 phlogopite 27.06 25.39 -1.67 -0.093 0.28538E+04 30 anorthite 12.71 8.24 -4.47 -0.344 0.76307E+04 33 apatite-OH -18.15 -18.27 -0.11 -0.009 0.19056E+03 34 apatite-F -34.30 -35.31 -1.01 -0.084 0.17186E+04 38 aragonite 0.97 -2.78 -3.75 -1.249 0.63963E+04 39 brucite 12.57 9.29 -3.28 -0.655 0.55925E+04 40 calcite 0.81 -2.78 -3.59 -1.197 0.61321E+04 41 carnegieite-low 9.02 5.93 -3.09 -0.442 0.52817E+04 42 carnegieite-high 10.09 5.93 -4.16 -0.595 0.71087E+04 43 carpholite-Mg 8.58 4.46 -4.13 -0.275 0.70458E+04 44 carpholite-Fe 6.71 1.83 -4.89 -0.326 0.83428E+04 45 celadonite 5.34 3.65 -1.69 -0.100 0.28887E+04 46 celadonite-Fe 3.88 1.02 -2.86 -0.168 0.48762E+04 47 chrysotile 23.89 21.57 -2.33 -0.194 0.39726E+04 49 clinochlore 39.07 38.47 -0.60 -0.019 0.10209E+04 50 daphnite 28.97 25.33 -3.64 -0.114 0.62132E+04 52 chlorite-Al-free 47.17 43.13 -4.04 -0.168 0.69003E+04 54 chloritoid-Fe 9.17 4.98 -4.19 -0.279 0.71545E+04 55 chloritoid-Mn 11.40 7.56 -3.84 -0.256 0.65623E+04 57 coesite -2.38 -3.16 -0.78 -0.260 0.13333E+04 64 cristobalite -2.56 -3.16 -0.60 -0.199 0.10187E+04 66 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71234E+04 68 diaspore 2.87 0.74 -2.14 -0.356 0.36464E+04 69 diamond -3.10 -7.34 -4.24 -1.211 0.72400E+04 70 diopside 16.18 16.06 -0.12 -0.012 0.21019E+03 71 hedenbergite 14.21 13.43 -0.78 -0.078 0.13302E+04 74 enstatite 17.26 12.27 -4.99 -0.499 0.85243E+04 76 clinoenstatite 17.17 12.27 -4.89 -0.489 0.83559E+04 78 epidote 24.67 22.70 -1.97 -0.096 0.33662E+04 79 clinozoisite 22.81 18.90 -3.90 -0.177 0.66670E+04 80 epidote-Fe 29.84 26.50 -3.35 -0.174 0.57119E+04 81 fayalite 14.05 10.17 -3.87 -0.553 0.66153E+04 82 ferrosilite 11.15 7.01 -4.13 -0.413 0.70603E+04 86 gibbsite 4.08 0.74 -3.34 -0.477 0.57050E+04 87 glaucophane 22.97 20.80 -2.18 -0.059 0.37167E+04 88 glaucophane-Fe 17.28 12.91 -4.36 -0.118 0.74529E+04 89 graphite -3.55 -7.34 -3.80 -1.085 0.64822E+04 90 greenalite 16.14 13.68 -2.46 -0.205 0.42018E+04 93 hematite 12.57 9.07 -3.50 -0.424 0.59689E+04 94 heulandite -5.83 -7.54 -1.72 -0.078 0.29303E+04 98 jadeite 4.22 2.77 -1.44 -0.144 0.24625E+04 100 kalsilite 7.58 3.83 -3.76 -0.537 0.64141E+04 101 kaolinite -1.33 -4.84 -3.50 -0.319 0.59844E+04 104 laumontite 2.88 1.93 -0.96 -0.064 0.16323E+04 105 lawsonite 9.62 8.24 -1.37 -0.092 0.23474E+04 106 leucite 4.12 0.67 -3.45 -0.345 0.58881E+04 108 lizardite 23.24 21.57 -1.68 -0.140 0.28652E+04 110 magnetite 20.09 15.73 -4.35 -0.355 0.74323E+04 111 minnesotaite 10.39 7.36 -3.02 -0.178 0.51622E+04 115 manganosite 14.06 9.24 -4.82 -1.205 0.82295E+04 119 microcline -2.49 -2.49 0.00 0.000 0.69892E-02 123 muscovite 2.58 -1.01 -3.59 -0.211 0.61343E+04 124 paragonite 4.24 1.09 -3.15 -0.185 0.53734E+04 125 nepheline 8.34 5.93 -2.41 -0.344 0.41140E+04 131 periclase-Fe 11.63 6.66 -4.96 -1.241 0.84731E+04 137 phlogopite-Na 29.65 27.50 -2.15 -0.119 0.36726E+04 139 prehnite 19.37 18.16 -1.21 -0.071 0.20637E+04 140 prehnite-Fe 22.50 21.96 -0.54 -0.032 0.91780E+03 141 pumpellyite-Fe 46.27 43.73 -2.54 -0.056 0.43379E+04 142 pumpellyite-Mg 48.99 46.36 -2.64 -0.059 0.45025E+04 146 pyrrhotite -4.26 -8.06 -3.80 -1.266 0.64844E+04 147 pyrrhotiteFe0.875 -6.02 -9.42 -3.40 -1.251 0.58089E+04 148 pyroxmangite 7.40 6.08 -1.32 -0.263 0.22491E+04 149 pyrophyllite -6.18 -11.15 -4.98 -0.311 0.84959E+04 150 quartz -2.99 -3.16 -0.17 -0.056 0.28602E+03 155 rhodonite 7.45 6.08 -1.36 -0.273 0.23293E+04 156 sanidine -1.28 -2.49 -1.21 -0.093 0.20678E+04 166 stilbite -7.52 -7.54 -0.02 -0.001 0.36505E+02 167 stilpnomelane-Fe 13.02 12.66 -0.35 -0.011 0.60139E+03 168 stilpnomelane-Mg 27.44 25.81 -1.63 -0.049 0.27856E+04 174 talc 16.49 15.25 -1.24 -0.073 0.21158E+04 177 tephroite 18.09 15.32 -2.77 -0.395 0.47226E+04 181 tridymite -2.63 -3.16 -0.53 -0.177 0.90600E+03 182 tremolite 47.87 47.37 -0.50 -0.014 0.85512E+03 183 ferroactinolite 38.45 34.22 -4.23 -0.114 0.72212E+04 184 troilite-low -4.41 -8.06 -3.65 -1.216 0.62272E+04 190 wairakite 3.95 1.93 -2.02 -0.119 0.34543E+04 191 walstromite 11.51 9.92 -1.59 -0.317 0.27102E+04 192 wollastonite 10.46 9.92 -0.54 -0.108 0.92063E+03 193 pseudo-wollastonite 11.00 9.92 -1.08 -0.216 0.18405E+04 194 zoisite 22.85 18.90 -3.95 -0.179 0.67411E+04 195 akaganeite 7.75 4.54 -3.22 -0.696 0.54970E+04 202 chalcedony -2.80 -3.16 -0.35 -0.118 0.60532E+03 204 montmorillonite-Ca -2.29 -6.17 -3.88 -0.240 0.66243E+04 205 montmorillonite-K -2.24 -6.27 -4.03 -0.247 0.68817E+04 206 montmorillonite-Mg -2.48 -6.79 -4.32 -0.267 0.73679E+04 207 montmorillonite-Na -2.04 -5.57 -3.54 -0.216 0.60366E+04 208 nontronite-Ca 3.21 -0.11 -3.33 -0.216 0.56833E+04 209 nontronite-H 2.53 -2.27 -4.80 -0.322 0.82039E+04 210 nontronite-K 3.34 -0.21 -3.55 -0.228 0.60640E+04 211 nontronite-Mg 3.07 -0.74 -3.81 -0.247 0.65110E+04 212 nontronite-Na 3.52 0.48 -3.04 -0.195 0.51849E+04 228 tobermorite 9.82 7.74 -2.09 -0.569 0.35605E+04 234 alabandite -0.98 -5.48 -4.51 -1.502 0.76936E+04 237 boehmite 4.41 0.74 -3.67 -0.611 0.62633E+04 239 ferrous-oxide 9.81 6.66 -3.15 -0.787 0.53741E+04 245 silica-amorphous -2.09 -3.16 -1.07 -0.355 0.18195E+04 247 an20ab80 2.02 1.34 -0.68 -0.052 0.11553E+04 248 an25ab75 2.65 1.77 -0.87 -0.067 0.14911E+04 249 an30ab70 3.28 2.20 -1.08 -0.083 0.18365E+04 250 tr.625ac.25prg.125 45.16 45.03 -0.13 -0.004 0.22985E+03 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 0.0000100 MOLES Current total amount of reactant added: 0.0000800 MOLES New total amount of reactant added: 0.0000900 MOLES Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.5508E-08 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 6 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 0.0000900 Water: Moles liquid = 0.4985E+02 kg liquid = 0.8981E+00 Moles total = 0.4985E+02 kg total = 0.8980E+00 Activity = 1.0000 Stoichiometric ionic strength = .1133596E-01 Osmotic coef. = 0.9690 True ionic strength = .2002212E-01 Chg. balance for total moles = -.5508E-08 Max. difference allowed = 0.1384E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.88415E-10 -10.0535 0.74290E-10 -10.1291 0.84024E+00 -0.0756 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.15342E-03 -3.8141 0.12814E-03 -3.8923 0.83519E+00 -0.0782 4 SO4-- 0.69818E-11 -11.1560 0.36255E-11 -11.4406 0.51928E+00 -0.2846 5 HCO3- 0.25086E-05 -5.6006 0.20982E-05 -5.6781 0.83641E+00 -0.0776 6 HS- 0.30829E-04 -4.5110 0.25752E-04 -4.5892 0.83531E+00 -0.0782 7 Al+++ 0.97091E-29 -29.0128 0.22429E-29 -29.6492 0.23101E+00 -0.6364 8 H4SiO4 0.69682E-03 -3.1569 0.69682E-03 -3.1569 0.10000E+01 0.0000 9 Ca++ 0.12796E-06 -6.8929 0.65960E-07 -7.1807 0.51547E+00 -0.2878 10 Mg++ 0.21123E-10 -10.6752 0.10838E-10 -10.9650 0.51311E+00 -0.2898 11 Fe++ 0.49158E-13 -13.3084 0.25251E-13 -13.5977 0.51367E+00 -0.2893 12 K+ 0.15651E-03 -3.8055 0.13094E-03 -3.8829 0.83661E+00 -0.0775 13 Na+ 0.19860E-01 -1.7020 0.16584E-01 -1.7803 0.83504E+00 -0.0783 14 Mn++ 0.18589E-10 -10.7308 0.95564E-11 -11.0197 0.51410E+00 -0.2890 15 F- 0.15095E-06 -6.8212 0.12581E-06 -6.9003 0.83347E+00 -0.0791 16 HPO4-- 0.45317E-07 -7.3437 0.23535E-07 -7.6283 0.51936E+00 -0.2845 18 HSiO3- 0.10487E-01 -1.9794 0.87582E-02 -2.0576 0.83519E+00 -0.0782 19 Ca(HSiO3)+ 0.15722E-07 -7.8035 0.13156E-07 -7.8809 0.83679E+00 -0.0774 20 Mg(HSiO3)+ 0.32151E-11 -11.4928 0.26904E-11 -11.5702 0.83679E+00 -0.0774 21 NaHSiO3,aq 0.23492E-02 -2.6291 0.23492E-02 -2.6291 0.10000E+01 0.0000 22 AlO+ 0.66070E-16 -16.1800 0.55286E-16 -16.2574 0.83679E+00 -0.0774 24 HAlO2,aq 0.14820E-09 -9.8291 0.14820E-09 -9.8291 0.10000E+01 0.0000 25 AlO2- 0.52970E-05 -5.2760 0.44160E-05 -5.3550 0.83368E+00 -0.0790 26 CH4,aq 0.14527E-04 -4.8378 0.14477E-04 -4.8393 0.99654E+00 -0.0015 27 C2H6,aq 0.53659E-14 -14.2704 0.53474E-14 -14.2719 0.99654E+00 -0.0015 31 CO,aq 0.56065E-16 -16.2513 0.56065E-16 -16.2513 0.10000E+01 0.0000 32 CO2,aq 0.33423E-09 -9.4760 0.33308E-09 -9.4775 0.99654E+00 -0.0015 33 CO3-2 0.47609E-05 -5.3223 0.24670E-05 -5.6078 0.51818E+00 -0.2855 34 CaCO3,aq 0.20404E-08 -8.6903 0.20404E-08 -8.6903 0.10000E+01 0.0000 35 Ca(HCO3)+ 0.42219E-11 -11.3745 0.35328E-11 -11.4519 0.83679E+00 -0.0774 36 CaCl+ 0.16346E-10 -10.7866 0.13678E-10 -10.8640 0.83679E+00 -0.0774 37 CaCl2,aq 0.41639E-15 -15.3805 0.41639E-15 -15.3805 0.10000E+01 0.0000 38 CaF+ 0.14479E-12 -12.8393 0.12116E-12 -12.9166 0.83679E+00 -0.0774 39 CaOH+ 0.75620E-07 -7.1214 0.63278E-07 -7.1987 0.83679E+00 -0.0774 40 CaSO4,aq 0.75938E-16 -16.1195 0.75938E-16 -16.1195 0.10000E+01 0.0000 41 HCl,aq 0.17444E-14 -14.7584 0.17444E-14 -14.7584 0.10000E+01 0.0000 45 HF,aq 0.63984E-13 -13.1939 0.63984E-13 -13.1939 0.10000E+01 0.0000 48 FeCl+ 0.61203E-17 -17.2132 0.51214E-17 -17.2906 0.83679E+00 -0.0774 51 FeF+ 0.19401E-18 -18.7122 0.16234E-18 -18.7896 0.83679E+00 -0.0774 53 FeO,aq 0.17782E-09 -9.7500 0.17782E-09 -9.7500 0.10000E+01 0.0000 54 FeOH+ 0.13222E-10 -10.8787 0.11064E-10 -10.9561 0.83679E+00 -0.0774 55 HFeO2- 0.29987E-07 -7.5231 0.25044E-07 -7.6013 0.83519E+00 -0.0782 56 FeO+ 0.12183E-16 -16.9142 0.10195E-16 -16.9916 0.83679E+00 -0.0774 58 FeO2- 0.45257E-09 -9.3443 0.37798E-09 -9.4225 0.83519E+00 -0.0782 59 HFeO2,aq 0.35714E-11 -11.4472 0.35714E-11 -11.4472 0.10000E+01 0.0000 60 H2,aq 0.67238E-05 -5.1724 0.67005E-05 -5.1739 0.99654E+00 -0.0015 61 KCl,aq 0.30408E-09 -9.5170 0.30408E-09 -9.5170 0.10000E+01 0.0000 63 KOH,aq 0.75269E-06 -6.1234 0.75269E-06 -6.1234 0.10000E+01 0.0000 64 KSO4- 0.88200E-14 -14.0545 0.73664E-14 -14.1327 0.83519E+00 -0.0782 65 MgCO3,aq 0.84037E-13 -13.0755 0.84037E-13 -13.0755 0.10000E+01 0.0000 66 Mg(HCO3)+ 0.70886E-15 -15.1494 0.59317E-15 -15.2268 0.83679E+00 -0.0774 67 MgCl+ 0.24343E-14 -14.6136 0.20370E-14 -14.6910 0.83679E+00 -0.0774 68 MgF+ 0.88131E-16 -16.0549 0.73747E-16 -16.1323 0.83679E+00 -0.0774 69 MgOH+ 0.68757E-10 -10.1627 0.57535E-10 -10.2401 0.83679E+00 -0.0774 71 MnF+ 0.24201E-16 -16.6162 0.20251E-16 -16.6935 0.83679E+00 -0.0774 72 MnO,aq 0.17932E-08 -8.7464 0.17932E-08 -8.7464 0.10000E+01 0.0000 73 MnOH+ 0.46485E-09 -9.3327 0.38898E-09 -9.4101 0.83679E+00 -0.0774 74 MnO2-2 0.20809E-10 -10.6817 0.10783E-10 -10.9673 0.51818E+00 -0.2855 75 HMnO2- 0.21013E-09 -9.6775 0.17550E-09 -9.7557 0.83519E+00 -0.0782 78 MnCl+ 0.90113E-14 -14.0452 0.75406E-14 -14.1226 0.83679E+00 -0.0774 79 MnSO4,aq 0.10002E-19 -19.9999 0.10002E-19 -19.9999 0.10000E+01 0.0000 80 NaCl,aq 0.70424E-06 -6.1523 0.70424E-06 -6.1523 0.10000E+01 0.0000 81 NaF,aq 0.48848E-09 -9.3112 0.48848E-09 -9.3112 0.10000E+01 0.0000 82 NaOH,aq 0.95912E-04 -4.0181 0.95912E-04 -4.0181 0.10000E+01 0.0000 84 OH- 0.93288E-02 -2.0302 0.77772E-02 -2.1092 0.83368E+00 -0.0790 89 HPO3-2 0.94841E-15 -15.0230 0.49145E-15 -15.3085 0.51818E+00 -0.2855 91 H2PO3- 0.87660E-19 -19.0572 0.73213E-19 -19.1354 0.83519E+00 -0.0782 92 H3PO4,aq 0.90846E-18 -18.0417 0.90846E-18 -18.0417 0.10000E+01 0.0000 93 H2PO4- 0.38582E-10 -10.4136 0.32254E-10 -10.4914 0.83598E+00 -0.0778 94 PO4-3 0.10653E-08 -8.9725 0.25848E-09 -9.5876 0.24263E+00 -0.6151 98 HP2O7-3 0.94816E-18 -18.0231 0.21925E-18 -18.6591 0.23124E+00 -0.6359 99 P2O7-4 0.91454E-17 -17.0388 0.70505E-18 -18.1518 0.77093E-01 -1.1130 100 H2S,aq 0.59332E-08 -8.2267 0.59127E-08 -8.2282 0.99654E+00 -0.0015 101 S2-2 0.42321E-14 -14.3734 0.21930E-14 -14.6590 0.51818E+00 -0.2855 107 SO3-2 0.60053E-17 -17.2215 0.31568E-17 -17.5007 0.52567E+00 -0.2793 108 HSO3- 0.17582E-19 -19.7549 0.14684E-19 -19.8332 0.83519E+00 -0.0782 109 HSO4- 0.30989E-18 -18.5088 0.25957E-18 -18.5858 0.83760E+00 -0.0770 Charge balance for all species = -.6133E-08 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.8841533E-10 -.2228898E-01 -.2242691E+02 0.0000 2 H2O 0.1000000E+01 0.5550487E+02 0.9981990E+06 0.0000 3 Cl- 0.1534230E-03 0.1541276E-03 0.5454788E+01 6.2367 4 SO4-- 0.6981776E-11 -.1620828E-04 -.1554287E+01 8.8175 5 HCO3- 0.2508636E-05 0.2179931E-04 0.1327821E+01 4.4509 6 HS- 0.3082896E-04 0.4704319E-04 0.1553108E+01 5.5399 7 Al+++ 0.9709146E-29 0.5297109E-05 0.1426755E+00 0.7380 8 H4SiO4 0.6968199E-03 0.1353252E-01 0.1298423E+04 -3.1569 9 Ca++ 0.1279614E-06 0.2213652E-06 0.8856453E-02 13.0774 10 Mg++ 0.2112283E-10 0.9318270E-10 0.2261520E-05 9.2931 11 Fe++ 0.4915778E-13 0.3063374E-07 0.1707829E-02 6.6604 12 K+ 0.1565083E-03 0.1572612E-03 0.6138542E+01 6.2461 13 Na+ 0.1986032E-01 0.2230611E-01 0.5119217E+03 8.3488 14 Mn++ 0.1858867E-10 0.2507571E-08 0.1375215E-03 9.2384 15 F- 0.1509495E-06 0.1514382E-06 0.2872023E-02 3.2288 16 HPO4-- 0.4531656E-07 0.4642048E-07 0.4447648E-02 12.6299 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.2001685E-01 -.2001675E-01 -.9999633E-07 0.0000000E+00 2 H2O 0.4984648E+02 0.4984648E+02 -.7111289E-07 0.0000000E+00 3 Cl- 0.1384152E-03 0.1384152E-03 0.0000000E+00 0.0000000E+00 4 SO4-- -.1455531E-04 -.1455595E-04 0.6351820E-09 0.0000000E+00 5 HCO3- 0.1957700E-04 0.1957700E-04 0.0000000E+00 0.0000000E+00 6 HS- 0.4224678E-04 0.4224742E-04 -.6351820E-09 0.0000000E+00 7 Al+++ 0.4775352E-05 0.4757100E-05 0.1825172E-07 0.0000000E+00 8 H4SiO4 0.1215302E-01 0.1215296E-01 0.6071432E-07 0.0000000E+00 9 Ca++ 0.2080835E-06 0.1987983E-06 0.9285200E-08 0.0000000E+00 10 Mg++ 0.8368328E-10 0.8368328E-10 0.0000000E+00 0.0000000E+00 11 Fe++ 0.3259227E-07 0.2751081E-07 0.5081456E-08 0.0000000E+00 12 K+ 0.1412294E-03 0.1412294E-03 0.0000000E+00 0.0000000E+00 13 Na+ 0.2003215E-01 0.2003213E-01 0.1714304E-07 0.0000000E+00 14 Mn++ 0.2251939E-08 0.2251939E-08 0.0000000E+00 0.0000000E+00 15 F- 0.1360000E-06 0.1360000E-06 0.0000000E+00 0.0000000E+00 16 HPO4-- 0.4168819E-07 0.4168819E-07 0.0000000E+00 0.0000000E+00 Chg. balance for solid moles: 0.3309E-23 Mass of aqueous solution: 0.899620E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 0.0000900 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 0.1714E-07 -7.766 0.4495E-05 -5.347 74.47 0.1726E-05 andradite 0.2541E-08 -8.595 0.1291E-05 -5.889 21.39 0.3355E-06 grossular 0.5543E-09 -9.256 0.2497E-06 -6.603 4.137 0.6948E-07 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8209E+00 0.8209E+00 1.0000 -0.086 grossular 0.1791E+00 0.1791E+00 1.0000 -0.747 Solid products produced: Mass = 0.000006 g Volume = 0.000002 cm3 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.0000900 moles log = -4.0458 Original solution: 1000.0103000 g Original solution / Rock added: 11111225.56 (Water/Rock Ratio), log = 7.0458 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0506 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9716E+00 0.9855 0.1006E+01 0.1021E+01 CO2,gas 0.3369E-07 1.0069 0.3564E-07 0.3539E-07 CH4,gas 0.2004E-01 1.0124 0.2131E-01 0.2105E-01 H2,gas 0.8369E-02 1.0006 0.8797E-02 0.8792E-02 H2S,gas 0.1553E-06 0.9959 0.1625E-06 0.1632E-06 S2,gas 0.1220E-28 1.0000 0.1281E-28 0.1281E-28 CO,gas 0.7953E-13 1.0000 0.8355E-13 0.8355E-13 SO3,gas 0.7201E-47 1.0000 0.7566E-47 0.7566E-47 SO2,gas 0.2465E-26 1.0000 0.2589E-26 0.2589E-26 HF,gas 0.1495E-15 1.0000 0.1571E-15 0.1571E-15 HCl,gas 0.2930E-17 1.0000 0.3078E-17 0.3078E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 17 albite -0.38 -0.38 0.00 0.000 -0.13080E-10 23 andradite 39.01 39.01 0.00 0.000 -0.12132E-10 24 grossular 32.73 32.73 0.00 0.000 0.36397E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -15.81 -9.15 -3.049 0.15618E+05 -7.448 3 CH4,gas 4.54 1.17 -3.37 -0.843 0.57549E+04 -1.671 4 H2,gas 8.00 4.25 -3.75 -2.146 0.64109E+04 -2.056 5 H2S,gas -6.23 -14.72 -8.49 -4.244 0.14493E+05 -6.789 6 S2,gas -7.34 -37.93 -30.59 -4.706 0.52234E+05 -28.892 7 CO,gas 3.21 -11.56 -14.78 -4.547 0.25231E+05 -13.078 8 SO3,gas 17.12 -31.70 -48.82 -12.205 0.83359E+05 -47.121 9 SO2,gas 0.83 -27.45 -28.29 -7.543 0.48297E+05 -26.587 10 HF,gas 0.47 -17.03 -17.50 -8.751 0.29886E+05 -15.804 11 HCl,gas 5.19 -14.02 -19.21 -9.605 0.32802E+05 -17.512 12 acmite 7.71 6.57 -1.14 -0.118 0.19412E+04 16 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 20 spessartine 24.46 19.72 -4.74 -0.237 0.80877E+04 21 analcite 3.32 2.77 -0.55 -0.061 0.93714E+03 27 annite 20.12 17.49 -2.63 -0.146 0.44883E+04 28 phlogopite 27.06 25.39 -1.67 -0.093 0.28545E+04 30 anorthite 12.71 8.24 -4.47 -0.344 0.76335E+04 33 apatite-OH -18.15 -18.27 -0.12 -0.009 0.20261E+03 34 apatite-F -34.30 -35.30 -1.00 -0.083 0.17083E+04 38 aragonite 0.97 -2.73 -3.70 -1.232 0.63114E+04 39 brucite 12.57 9.29 -3.28 -0.655 0.55928E+04 40 calcite 0.81 -2.73 -3.54 -1.181 0.60471E+04 41 carnegieite-low 9.02 5.93 -3.09 -0.442 0.52819E+04 42 carnegieite-high 10.09 5.93 -4.16 -0.595 0.71089E+04 43 carpholite-Mg 8.58 4.46 -4.13 -0.275 0.70463E+04 44 carpholite-Fe 6.71 1.82 -4.89 -0.326 0.83495E+04 45 celadonite 5.34 3.65 -1.69 -0.100 0.28888E+04 46 celadonite-Fe 3.88 1.02 -2.86 -0.168 0.48825E+04 47 chrysotile 23.89 21.57 -2.33 -0.194 0.39730E+04 49 clinochlore 39.07 38.47 -0.60 -0.019 0.10221E+04 50 daphnite 28.97 25.31 -3.66 -0.114 0.62456E+04 52 chlorite-Al-free 47.17 43.13 -4.04 -0.168 0.69012E+04 54 chloritoid-Fe 9.17 4.98 -4.19 -0.280 0.71612E+04 55 chloritoid-Mn 11.40 7.56 -3.84 -0.256 0.65627E+04 57 coesite -2.38 -3.16 -0.78 -0.260 0.13332E+04 64 cristobalite -2.56 -3.16 -0.60 -0.199 0.10186E+04 66 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71234E+04 68 diaspore 2.87 0.74 -2.14 -0.356 0.36466E+04 69 diamond -3.10 -7.32 -4.21 -1.204 0.71963E+04 70 diopside 16.18 16.06 -0.12 -0.012 0.21274E+03 71 hedenbergite 14.21 13.42 -0.78 -0.078 0.13390E+04 74 enstatite 17.26 12.27 -4.99 -0.499 0.85245E+04 76 clinoenstatite 17.17 12.27 -4.89 -0.489 0.83561E+04 78 epidote 24.67 22.70 -1.97 -0.096 0.33669E+04 79 clinozoisite 22.81 18.90 -3.91 -0.178 0.66725E+04 80 epidote-Fe 29.84 26.50 -3.34 -0.174 0.57079E+04 81 fayalite 14.05 10.16 -3.88 -0.555 0.66280E+04 82 ferrosilite 11.15 7.01 -4.14 -0.414 0.70730E+04 86 gibbsite 4.08 0.74 -3.34 -0.477 0.57052E+04 87 glaucophane 22.97 20.80 -2.18 -0.059 0.37172E+04 88 glaucophane-Fe 17.28 12.90 -4.38 -0.118 0.74720E+04 89 graphite -3.55 -7.32 -3.77 -1.077 0.64385E+04 90 greenalite 16.14 13.67 -2.47 -0.206 0.42209E+04 93 hematite 12.57 9.08 -3.49 -0.423 0.59599E+04 94 heulandite -5.83 -7.54 -1.72 -0.078 0.29325E+04 98 jadeite 4.22 2.77 -1.44 -0.144 0.24626E+04 100 kalsilite 7.58 3.83 -3.76 -0.537 0.64144E+04 101 kaolinite -1.33 -4.84 -3.50 -0.319 0.59846E+04 104 laumontite 2.88 1.93 -0.96 -0.064 0.16349E+04 105 lawsonite 9.62 8.24 -1.38 -0.092 0.23502E+04 106 leucite 4.12 0.67 -3.45 -0.345 0.58882E+04 108 lizardite 23.24 21.57 -1.68 -0.140 0.28657E+04 110 magnetite 20.09 15.74 -4.35 -0.355 0.74297E+04 111 minnesotaite 10.39 7.35 -3.03 -0.178 0.51811E+04 115 manganosite 14.06 9.24 -4.82 -1.205 0.82295E+04 119 microcline -2.49 -2.49 0.00 0.000 0.77958E-02 123 muscovite 2.58 -1.01 -3.59 -0.211 0.61348E+04 124 paragonite 4.24 1.09 -3.15 -0.185 0.53739E+04 125 nepheline 8.34 5.93 -2.41 -0.344 0.41143E+04 131 periclase-Fe 11.63 6.66 -4.97 -1.242 0.84796E+04 137 phlogopite-Na 29.65 27.50 -2.15 -0.120 0.36733E+04 139 prehnite 19.37 18.16 -1.21 -0.071 0.20689E+04 140 prehnite-Fe 22.50 21.96 -0.54 -0.032 0.91828E+03 141 pumpellyite-Fe 46.27 43.72 -2.55 -0.057 0.43550E+04 142 pumpellyite-Mg 48.99 46.35 -2.64 -0.059 0.45134E+04 146 pyrrhotite -4.26 -8.06 -3.80 -1.266 0.64842E+04 147 pyrrhotiteFe0.875 -6.02 -9.42 -3.40 -1.250 0.58051E+04 148 pyroxmangite 7.40 6.08 -1.32 -0.263 0.22490E+04 149 pyrophyllite -6.18 -11.15 -4.98 -0.311 0.84959E+04 150 quartz -2.99 -3.16 -0.17 -0.056 0.28591E+03 155 rhodonite 7.45 6.08 -1.36 -0.273 0.23292E+04 156 sanidine -1.28 -2.49 -1.21 -0.093 0.20678E+04 166 stilbite -7.52 -7.54 -0.02 -0.001 0.38698E+02 167 stilpnomelane-Fe 13.02 12.65 -0.37 -0.011 0.63319E+03 168 stilpnomelane-Mg 27.44 25.81 -1.63 -0.049 0.27863E+04 174 talc 16.49 15.25 -1.24 -0.073 0.21160E+04 177 tephroite 18.09 15.32 -2.77 -0.395 0.47225E+04 181 tridymite -2.63 -3.16 -0.53 -0.177 0.90588E+03 182 tremolite 47.87 47.37 -0.50 -0.014 0.86047E+03 183 ferroactinolite 38.45 34.20 -4.25 -0.115 0.72576E+04 184 troilite-low -4.41 -8.06 -3.65 -1.216 0.62270E+04 190 wairakite 3.95 1.93 -2.02 -0.119 0.34568E+04 191 walstromite 11.51 9.92 -1.59 -0.318 0.27126E+04 192 wollastonite 10.46 9.92 -0.54 -0.108 0.92307E+03 193 pseudo-wollastonite 11.00 9.92 -1.08 -0.216 0.18429E+04 194 zoisite 22.85 18.90 -3.95 -0.180 0.67465E+04 195 akaganeite 7.75 4.54 -3.22 -0.696 0.54925E+04 202 chalcedony -2.80 -3.16 -0.35 -0.118 0.60520E+03 204 montmorillonite-Ca -2.29 -6.17 -3.88 -0.240 0.66247E+04 205 montmorillonite-K -2.24 -6.27 -4.03 -0.247 0.68818E+04 206 montmorillonite-Mg -2.48 -6.79 -4.32 -0.267 0.73679E+04 207 montmorillonite-Na -2.04 -5.57 -3.54 -0.216 0.60366E+04 208 nontronite-Ca 3.21 -0.11 -3.32 -0.216 0.56744E+04 209 nontronite-H 2.53 -2.27 -4.80 -0.322 0.81945E+04 210 nontronite-K 3.34 -0.21 -3.55 -0.228 0.60547E+04 211 nontronite-Mg 3.07 -0.73 -3.81 -0.247 0.65016E+04 212 nontronite-Na 3.52 0.49 -3.03 -0.195 0.51755E+04 228 tobermorite 9.82 7.74 -2.09 -0.569 0.35625E+04 234 alabandite -0.98 -5.48 -4.50 -1.501 0.76870E+04 237 boehmite 4.41 0.74 -3.67 -0.611 0.62635E+04 239 ferrous-oxide 9.81 6.66 -3.15 -0.788 0.53805E+04 245 silica-amorphous -2.09 -3.16 -1.07 -0.355 0.18194E+04 247 an20ab80 2.02 1.34 -0.68 -0.052 0.11558E+04 248 an25ab75 2.65 1.77 -0.87 -0.067 0.14918E+04 249 an30ab70 3.28 2.20 -1.08 -0.083 0.18373E+04 250 tr.625ac.25prg.125 45.16 45.02 -0.14 -0.004 0.24307E+03 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 0.0000100 MOLES Current total amount of reactant added: 0.0000900 MOLES New total amount of reactant added: 0.0001000 MOLES Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.5508E-08 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 6 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 0.0001000 Water: Moles liquid = 0.4985E+02 kg liquid = 0.8981E+00 Moles total = 0.4985E+02 kg total = 0.8980E+00 Activity = 1.0000 Stoichiometric ionic strength = .1133659E-01 Osmotic coef. = 0.9690 True ionic strength = .2002268E-01 Chg. balance for total moles = -.5508E-08 Max. difference allowed = 0.1385E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.88430E-10 -10.0534 0.74303E-10 -10.1290 0.84024E+00 -0.0756 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.15349E-03 -3.8139 0.12819E-03 -3.8921 0.83519E+00 -0.0782 4 SO4-- 0.78369E-11 -11.1059 0.40695E-11 -11.3905 0.51928E+00 -0.2846 5 HCO3- 0.27897E-05 -5.5544 0.23333E-05 -5.6320 0.83641E+00 -0.0776 6 HS- 0.31099E-04 -4.5072 0.25978E-04 -4.5854 0.83531E+00 -0.0782 7 Al+++ 0.97113E-29 -29.0127 0.22433E-29 -29.6491 0.23100E+00 -0.6364 8 H4SiO4 0.69693E-03 -3.1568 0.69693E-03 -3.1568 0.10000E+01 0.0000 9 Ca++ 0.12760E-06 -6.8942 0.65771E-07 -7.1820 0.51547E+00 -0.2878 10 Mg++ 0.21123E-10 -10.6752 0.10839E-10 -10.9650 0.51311E+00 -0.2898 11 Fe++ 0.48796E-13 -13.3116 0.25065E-13 -13.6009 0.51367E+00 -0.2893 12 K+ 0.15651E-03 -3.8055 0.13094E-03 -3.8829 0.83661E+00 -0.0775 13 Na+ 0.19860E-01 -1.7020 0.16584E-01 -1.7803 0.83504E+00 -0.0783 14 Mn++ 0.18595E-10 -10.7306 0.95595E-11 -11.0196 0.51410E+00 -0.2890 15 F- 0.15539E-06 -6.8086 0.12951E-06 -6.8877 0.83347E+00 -0.0791 16 HPO4-- 0.45317E-07 -7.3437 0.23535E-07 -7.6283 0.51935E+00 -0.2845 18 HSiO3- 0.10486E-01 -1.9794 0.87581E-02 -2.0576 0.83519E+00 -0.0782 19 Ca(HSiO3)+ 0.15677E-07 -7.8047 0.13118E-07 -7.8821 0.83679E+00 -0.0774 20 Mg(HSiO3)+ 0.32152E-11 -11.4928 0.26904E-11 -11.5702 0.83679E+00 -0.0774 21 NaHSiO3,aq 0.23491E-02 -2.6291 0.23491E-02 -2.6291 0.10000E+01 0.0000 22 AlO+ 0.66061E-16 -16.1801 0.55279E-16 -16.2574 0.83679E+00 -0.0774 24 HAlO2,aq 0.14816E-09 -9.8293 0.14816E-09 -9.8293 0.10000E+01 0.0000 25 AlO2- 0.52945E-05 -5.2762 0.44139E-05 -5.3552 0.83368E+00 -0.0790 26 CH4,aq 0.14519E-04 -4.8381 0.14468E-04 -4.8396 0.99654E+00 -0.0015 27 C2H6,aq 0.55047E-14 -14.2593 0.54857E-14 -14.2608 0.99654E+00 -0.0015 31 CO,aq 0.60711E-16 -16.2167 0.60711E-16 -16.2167 0.10000E+01 0.0000 32 CO2,aq 0.37174E-09 -9.4298 0.37046E-09 -9.4313 0.99654E+00 -0.0015 33 CO3-2 0.52934E-05 -5.2763 0.27429E-05 -5.5618 0.51818E+00 -0.2855 34 CaCO3,aq 0.22621E-08 -8.6455 0.22621E-08 -8.6455 0.10000E+01 0.0000 35 Ca(HCO3)+ 0.46814E-11 -11.3296 0.39174E-11 -11.4070 0.83679E+00 -0.0774 36 CaCl+ 0.16306E-10 -10.7877 0.13645E-10 -10.8650 0.83679E+00 -0.0774 37 CaCl2,aq 0.41555E-15 -15.3814 0.41555E-15 -15.3814 0.10000E+01 0.0000 38 CaF+ 0.14862E-12 -12.8279 0.12437E-12 -12.9053 0.83679E+00 -0.0774 39 CaOH+ 0.75391E-07 -7.1227 0.63086E-07 -7.2001 0.83679E+00 -0.0774 40 CaSO4,aq 0.84994E-16 -16.0706 0.84994E-16 -16.0706 0.10000E+01 0.0000 41 HCl,aq 0.17454E-14 -14.7581 0.17454E-14 -14.7581 0.10000E+01 0.0000 45 HF,aq 0.65877E-13 -13.1813 0.65877E-13 -13.1813 0.10000E+01 0.0000 48 FeCl+ 0.60778E-17 -17.2163 0.50858E-17 -17.2936 0.83679E+00 -0.0774 51 FeF+ 0.19824E-18 -18.7028 0.16589E-18 -18.7802 0.83679E+00 -0.0774 53 FeO,aq 0.17645E-09 -9.7534 0.17645E-09 -9.7534 0.10000E+01 0.0000 54 FeOH+ 0.13122E-10 -10.8820 0.10981E-10 -10.9594 0.83679E+00 -0.0774 55 HFeO2- 0.29750E-07 -7.5265 0.24847E-07 -7.6047 0.83519E+00 -0.0782 56 FeO+ 0.12254E-16 -16.9117 0.10254E-16 -16.9891 0.83679E+00 -0.0774 58 FeO2- 0.45505E-09 -9.3419 0.38005E-09 -9.4202 0.83519E+00 -0.0782 59 HFeO2,aq 0.35916E-11 -11.4447 0.35916E-11 -11.4447 0.10000E+01 0.0000 60 H2,aq 0.65464E-05 -5.1840 0.65237E-05 -5.1855 0.99654E+00 -0.0015 61 KCl,aq 0.30421E-09 -9.5168 0.30421E-09 -9.5168 0.10000E+01 0.0000 63 KOH,aq 0.75256E-06 -6.1235 0.75256E-06 -6.1235 0.10000E+01 0.0000 64 KSO4- 0.99002E-14 -14.0044 0.82685E-14 -14.0826 0.83519E+00 -0.0782 65 MgCO3,aq 0.93438E-13 -13.0295 0.93438E-13 -13.0295 0.10000E+01 0.0000 66 Mg(HCO3)+ 0.78829E-15 -15.1033 0.65963E-15 -15.1807 0.83679E+00 -0.0774 67 MgCl+ 0.24354E-14 -14.6134 0.20379E-14 -14.6908 0.83679E+00 -0.0774 68 MgF+ 0.90725E-16 -16.0423 0.75918E-16 -16.1197 0.83679E+00 -0.0774 69 MgOH+ 0.68747E-10 -10.1627 0.57527E-10 -10.2401 0.83679E+00 -0.0774 71 MnF+ 0.24921E-16 -16.6034 0.20853E-16 -16.6808 0.83679E+00 -0.0774 72 MnO,aq 0.17932E-08 -8.7464 0.17932E-08 -8.7464 0.10000E+01 0.0000 73 MnOH+ 0.46492E-09 -9.3326 0.38904E-09 -9.4100 0.83679E+00 -0.0774 74 MnO2-2 0.20802E-10 -10.6819 0.10779E-10 -10.9674 0.51818E+00 -0.2855 75 HMnO2- 0.21009E-09 -9.6776 0.17547E-09 -9.7558 0.83519E+00 -0.0782 78 MnCl+ 0.90181E-14 -14.0449 0.75462E-14 -14.1223 0.83679E+00 -0.0774 79 MnSO4,aq 0.11231E-19 -19.9496 0.11231E-19 -19.9496 0.10000E+01 0.0000 80 NaCl,aq 0.70454E-06 -6.1521 0.70454E-06 -6.1521 0.10000E+01 0.0000 81 NaF,aq 0.50285E-09 -9.2986 0.50285E-09 -9.2986 0.10000E+01 0.0000 82 NaOH,aq 0.95896E-04 -4.0182 0.95896E-04 -4.0182 0.10000E+01 0.0000 84 OH- 0.93273E-02 -2.0302 0.77759E-02 -2.1092 0.83368E+00 -0.0790 89 HPO3-2 0.92339E-15 -15.0346 0.47848E-15 -15.3201 0.51818E+00 -0.2855 91 H2PO3- 0.85361E-19 -19.0687 0.71293E-19 -19.1470 0.83519E+00 -0.0782 92 H3PO4,aq 0.90877E-18 -18.0415 0.90877E-18 -18.0415 0.10000E+01 0.0000 93 H2PO4- 0.38589E-10 -10.4135 0.32259E-10 -10.4913 0.83598E+00 -0.0778 94 PO4-3 0.10652E-08 -8.9726 0.25843E-09 -9.5877 0.24262E+00 -0.6151 98 HP2O7-3 0.94833E-18 -18.0230 0.21928E-18 -18.6590 0.23123E+00 -0.6360 99 P2O7-4 0.91456E-17 -17.0388 0.70504E-18 -18.1518 0.77090E-01 -1.1130 100 H2S,aq 0.59863E-08 -8.2228 0.59656E-08 -8.2243 0.99654E+00 -0.0015 101 S2-2 0.44234E-14 -14.3542 0.22921E-14 -14.6398 0.51818E+00 -0.2855 107 SO3-2 0.65630E-17 -17.1829 0.34500E-17 -17.4622 0.52567E+00 -0.2793 108 HSO3- 0.19217E-19 -19.7163 0.16050E-19 -19.7945 0.83519E+00 -0.0782 109 HSO4- 0.34791E-18 -18.4585 0.29141E-18 -18.5355 0.83760E+00 -0.0770 Charge balance for all species = -.6133E-08 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.8843039E-10 -.2228776E-01 -.2242568E+02 0.0000 2 H2O 0.1000000E+01 0.5550487E+02 0.9981989E+06 0.0000 3 Cl- 0.1534884E-03 0.1541933E-03 0.5457112E+01 6.2369 4 SO4-- 0.7836896E-11 -.1615514E-04 -.1549191E+01 8.8675 5 HCO3- 0.2789698E-05 0.2260438E-04 0.1376859E+01 4.4970 6 HS- 0.3109949E-04 0.4726062E-04 0.1560287E+01 5.5436 7 Al+++ 0.9711266E-29 0.5294613E-05 0.1426083E+00 0.7379 8 H4SiO4 0.6969298E-03 0.1353251E-01 0.1298422E+04 -3.1568 9 Ca++ 0.1275957E-06 0.2209471E-06 0.8839728E-02 13.0760 10 Mg++ 0.2112341E-10 0.9318268E-10 0.2261520E-05 9.2930 11 Fe++ 0.4879579E-13 0.3039873E-07 0.1694727E-02 6.6571 12 K+ 0.1565084E-03 0.1572612E-03 0.6138540E+01 6.2461 13 Na+ 0.1986035E-01 0.2230610E-01 0.5119215E+03 8.3487 14 Mn++ 0.1859476E-10 0.2507570E-08 0.1375215E-03 9.2384 15 F- 0.1553892E-06 0.1558923E-06 0.2956494E-02 3.2413 16 HPO4-- 0.4531671E-07 0.4642047E-07 0.4447647E-02 12.6297 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.2001577E-01 -.2001566E-01 -.1100650E-06 0.0000000E+00 2 H2O 0.4984649E+02 0.4984649E+02 -.8002299E-07 0.0000000E+00 3 Cl- 0.1384742E-03 0.1384742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- -.1450756E-04 -.1450822E-04 0.6615627E-09 0.0000000E+00 5 HCO3- 0.2030000E-04 0.2030000E-04 0.0000000E+00 0.0000000E+00 6 HS- 0.4244203E-04 0.4244269E-04 -.6615627E-09 0.0000000E+00 7 Al+++ 0.4775352E-05 0.4754860E-05 0.2049207E-07 0.0000000E+00 8 H4SiO4 0.1215302E-01 0.1215295E-01 0.6769313E-07 0.0000000E+00 9 Ca++ 0.2080835E-06 0.1984229E-06 0.9660581E-08 0.0000000E+00 10 Mg++ 0.8368328E-10 0.8368328E-10 0.0000000E+00 0.0000000E+00 11 Fe++ 0.3259227E-07 0.2729977E-07 0.5292502E-08 0.0000000E+00 12 K+ 0.1412294E-03 0.1412294E-03 0.0000000E+00 0.0000000E+00 13 Na+ 0.2003215E-01 0.2003213E-01 0.1934418E-07 0.0000000E+00 14 Mn++ 0.2251939E-08 0.2251939E-08 0.0000000E+00 0.0000000E+00 15 F- 0.1400000E-06 0.1400000E-06 0.0000000E+00 0.0000000E+00 16 HPO4-- 0.4168819E-07 0.4168819E-07 0.0000000E+00 0.0000000E+00 Chg. balance for solid moles: 0.1323E-22 Mass of aqueous solution: 0.899620E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 0.0001000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 0.1934E-07 -7.713 0.5072E-05 -5.295 75.98 0.1947E-05 andradite 0.2646E-08 -8.577 0.1345E-05 -5.871 20.14 0.3494E-06 grossular 0.5739E-09 -9.241 0.2585E-06 -6.587 3.873 0.7193E-07 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8218E+00 0.8218E+00 1.0000 -0.085 grossular 0.1782E+00 0.1782E+00 1.0000 -0.749 Solid products produced: Mass = 0.000007 g Volume = 0.000002 cm3 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.0001000 moles log = -4.0000 Original solution: 1000.0103000 g Original solution / Rock added: 10000103.00 (Water/Rock Ratio), log = 7.0000 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0503 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9718E+00 0.9855 0.1006E+01 0.1021E+01 CO2,gas 0.3748E-07 1.0069 0.3963E-07 0.3937E-07 CH4,gas 0.2003E-01 1.0124 0.2130E-01 0.2104E-01 H2,gas 0.8150E-02 1.0006 0.8565E-02 0.8560E-02 H2S,gas 0.1568E-06 0.9959 0.1640E-06 0.1647E-06 S2,gas 0.1310E-28 1.0000 0.1376E-28 0.1376E-28 CO,gas 0.8614E-13 1.0000 0.9047E-13 0.9047E-13 SO3,gas 0.8088E-47 1.0000 0.8495E-47 0.8495E-47 SO2,gas 0.2695E-26 1.0000 0.2831E-26 0.2831E-26 HF,gas 0.1540E-15 1.0000 0.1618E-15 0.1618E-15 HCl,gas 0.2932E-17 1.0000 0.3080E-17 0.3080E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 17 albite -0.38 -0.38 0.00 0.000 -0.94784E-12 23 andradite 39.01 39.01 0.00 0.000 -0.24265E-10 24 grossular 32.73 32.73 0.00 0.000 -0.24265E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -15.76 -9.10 -3.034 0.15540E+05 -7.402 3 CH4,gas 4.54 1.17 -3.37 -0.843 0.57553E+04 -1.672 4 H2,gas 8.00 4.23 -3.77 -2.152 0.64308E+04 -2.067 5 H2S,gas -6.23 -14.71 -8.48 -4.242 0.14486E+05 -6.785 6 S2,gas -7.34 -37.90 -30.56 -4.702 0.52181E+05 -28.861 7 CO,gas 3.21 -11.53 -14.74 -4.536 0.25172E+05 -13.043 8 SO3,gas 17.12 -31.65 -48.77 -12.192 0.83273E+05 -47.071 9 SO2,gas 0.83 -27.41 -28.25 -7.533 0.48231E+05 -26.548 10 HF,gas 0.47 -17.02 -17.49 -8.745 0.29864E+05 -15.791 11 HCl,gas 5.19 -14.02 -19.21 -9.605 0.32801E+05 -17.511 12 acmite 7.71 6.58 -1.13 -0.118 0.19369E+04 16 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 20 spessartine 24.46 19.72 -4.74 -0.237 0.80878E+04 21 analcite 3.32 2.77 -0.55 -0.061 0.93726E+03 27 annite 20.12 17.48 -2.64 -0.147 0.45056E+04 28 phlogopite 27.06 25.39 -1.67 -0.093 0.28552E+04 30 anorthite 12.71 8.24 -4.47 -0.344 0.76361E+04 33 apatite-OH -18.15 -18.28 -0.13 -0.010 0.21376E+03 34 apatite-F -34.30 -35.30 -0.99 -0.083 0.16979E+04 38 aragonite 0.97 -2.68 -3.65 -1.217 0.62349E+04 39 brucite 12.57 9.29 -3.28 -0.655 0.55930E+04 40 calcite 0.81 -2.68 -3.50 -1.166 0.59706E+04 41 carnegieite-low 9.02 5.93 -3.09 -0.442 0.52821E+04 42 carnegieite-high 10.09 5.93 -4.16 -0.595 0.71091E+04 43 carpholite-Mg 8.58 4.46 -4.13 -0.275 0.70467E+04 44 carpholite-Fe 6.71 1.82 -4.89 -0.326 0.83554E+04 45 celadonite 5.34 3.65 -1.69 -0.100 0.28890E+04 46 celadonite-Fe 3.88 1.01 -2.86 -0.168 0.48881E+04 47 chrysotile 23.89 21.57 -2.33 -0.194 0.39735E+04 49 clinochlore 39.07 38.47 -0.60 -0.019 0.10234E+04 50 daphnite 28.97 25.29 -3.67 -0.115 0.62743E+04 52 chlorite-Al-free 47.17 43.13 -4.04 -0.168 0.69022E+04 54 chloritoid-Fe 9.17 4.98 -4.20 -0.280 0.71673E+04 55 chloritoid-Mn 11.40 7.56 -3.84 -0.256 0.65630E+04 57 coesite -2.38 -3.16 -0.78 -0.260 0.13331E+04 64 cristobalite -2.56 -3.16 -0.60 -0.199 0.10185E+04 66 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71234E+04 68 diaspore 2.87 0.74 -2.14 -0.356 0.36469E+04 69 diamond -3.10 -7.29 -4.19 -1.198 0.71571E+04 70 diopside 16.18 16.06 -0.13 -0.013 0.21512E+03 71 hedenbergite 14.21 13.42 -0.79 -0.079 0.13469E+04 74 enstatite 17.26 12.27 -4.99 -0.499 0.85247E+04 76 clinoenstatite 17.17 12.27 -4.89 -0.489 0.83563E+04 78 epidote 24.67 22.70 -1.97 -0.096 0.33675E+04 79 clinozoisite 22.81 18.90 -3.91 -0.178 0.66775E+04 80 epidote-Fe 29.84 26.50 -3.34 -0.174 0.57042E+04 81 fayalite 14.05 10.16 -3.89 -0.555 0.66394E+04 82 ferrosilite 11.15 7.00 -4.15 -0.415 0.70842E+04 86 gibbsite 4.08 0.74 -3.34 -0.477 0.57054E+04 87 glaucophane 22.97 20.80 -2.18 -0.059 0.37176E+04 88 glaucophane-Fe 17.28 12.89 -4.39 -0.119 0.74890E+04 89 graphite -3.55 -7.29 -3.75 -1.071 0.63993E+04 90 greenalite 16.14 13.66 -2.48 -0.207 0.42379E+04 93 hematite 12.57 9.08 -3.49 -0.422 0.59515E+04 94 heulandite -5.83 -7.55 -1.72 -0.078 0.29345E+04 98 jadeite 4.22 2.77 -1.44 -0.144 0.24627E+04 100 kalsilite 7.58 3.83 -3.76 -0.537 0.64146E+04 101 kaolinite -1.33 -4.84 -3.51 -0.319 0.59849E+04 104 laumontite 2.88 1.92 -0.96 -0.064 0.16372E+04 105 lawsonite 9.62 8.24 -1.38 -0.092 0.23527E+04 106 leucite 4.12 0.67 -3.45 -0.345 0.58883E+04 108 lizardite 23.24 21.57 -1.68 -0.140 0.28661E+04 110 magnetite 20.09 15.74 -4.35 -0.355 0.74271E+04 111 minnesotaite 10.39 7.34 -3.04 -0.179 0.51978E+04 115 manganosite 14.06 9.24 -4.82 -1.205 0.82295E+04 119 microcline -2.49 -2.49 0.00 0.000 0.86072E-02 123 muscovite 2.58 -1.01 -3.59 -0.211 0.61352E+04 124 paragonite 4.24 1.09 -3.15 -0.185 0.53743E+04 125 nepheline 8.34 5.93 -2.41 -0.344 0.41145E+04 131 periclase-Fe 11.63 6.66 -4.97 -1.242 0.84853E+04 137 phlogopite-Na 29.65 27.50 -2.15 -0.120 0.36740E+04 139 prehnite 19.37 18.16 -1.21 -0.071 0.20737E+04 140 prehnite-Fe 22.50 21.96 -0.54 -0.032 0.91873E+03 141 pumpellyite-Fe 46.27 43.71 -2.56 -0.057 0.43707E+04 142 pumpellyite-Mg 48.99 46.35 -2.65 -0.059 0.45236E+04 146 pyrrhotite -4.26 -8.06 -3.80 -1.266 0.64833E+04 147 pyrrhotiteFe0.875 -6.02 -9.41 -3.40 -1.250 0.58011E+04 148 pyroxmangite 7.40 6.08 -1.32 -0.263 0.22489E+04 149 pyrophyllite -6.18 -11.15 -4.98 -0.311 0.84959E+04 150 quartz -2.99 -3.16 -0.17 -0.056 0.28579E+03 155 rhodonite 7.45 6.08 -1.36 -0.273 0.23291E+04 156 sanidine -1.28 -2.49 -1.21 -0.093 0.20678E+04 166 stilbite -7.52 -7.55 -0.02 -0.001 0.40709E+02 167 stilpnomelane-Fe 13.02 12.63 -0.39 -0.012 0.66146E+03 168 stilpnomelane-Mg 27.44 25.81 -1.63 -0.049 0.27871E+04 174 talc 16.49 15.25 -1.24 -0.073 0.21163E+04 177 tephroite 18.09 15.32 -2.77 -0.395 0.47224E+04 181 tridymite -2.63 -3.16 -0.53 -0.177 0.90577E+03 182 tremolite 47.87 47.36 -0.51 -0.014 0.86547E+03 183 ferroactinolite 38.45 34.18 -4.27 -0.115 0.72901E+04 184 troilite-low -4.41 -8.06 -3.65 -1.215 0.62261E+04 190 wairakite 3.95 1.92 -2.03 -0.119 0.34592E+04 191 walstromite 11.51 9.92 -1.59 -0.318 0.27149E+04 192 wollastonite 10.46 9.92 -0.54 -0.108 0.92533E+03 193 pseudo-wollastonite 11.00 9.92 -1.08 -0.216 0.18452E+04 194 zoisite 22.85 18.90 -3.95 -0.180 0.67516E+04 195 akaganeite 7.75 4.54 -3.21 -0.695 0.54883E+04 202 chalcedony -2.80 -3.16 -0.35 -0.118 0.60509E+03 204 montmorillonite-Ca -2.29 -6.17 -3.88 -0.240 0.66251E+04 205 montmorillonite-K -2.24 -6.27 -4.03 -0.247 0.68818E+04 206 montmorillonite-Mg -2.48 -6.79 -4.32 -0.267 0.73679E+04 207 montmorillonite-Na -2.04 -5.57 -3.54 -0.216 0.60367E+04 208 nontronite-Ca 3.21 -0.10 -3.32 -0.215 0.56661E+04 209 nontronite-H 2.53 -2.26 -4.79 -0.321 0.81858E+04 210 nontronite-K 3.34 -0.20 -3.54 -0.227 0.60460E+04 211 nontronite-Mg 3.07 -0.73 -3.80 -0.247 0.64930E+04 212 nontronite-Na 3.52 0.49 -3.03 -0.194 0.51669E+04 228 tobermorite 9.82 7.74 -2.09 -0.570 0.35644E+04 234 alabandite -0.98 -5.48 -4.50 -1.499 0.76804E+04 237 boehmite 4.41 0.74 -3.67 -0.611 0.62638E+04 239 ferrous-oxide 9.81 6.66 -3.15 -0.789 0.53863E+04 245 silica-amorphous -2.09 -3.16 -1.07 -0.355 0.18193E+04 247 an20ab80 2.02 1.34 -0.68 -0.052 0.11564E+04 248 an25ab75 2.65 1.77 -0.87 -0.067 0.14924E+04 249 an30ab70 3.28 2.20 -1.08 -0.083 0.18381E+04 250 tr.625ac.25prg.125 45.16 45.02 -0.15 -0.004 0.25504E+03 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 0.0000100 MOLES Current total amount of reactant added: 0.0001000 MOLES New total amount of reactant added: 0.0001100 MOLES Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.5508E-08 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 6 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 0.0001100 Water: Moles liquid = 0.4985E+02 kg liquid = 0.8981E+00 Moles total = 0.4985E+02 kg total = 0.8980E+00 Activity = 1.0000 Stoichiometric ionic strength = .1133723E-01 Osmotic coef. = 0.9690 True ionic strength = .2002325E-01 Chg. balance for total moles = -.5508E-08 Max. difference allowed = 0.1385E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.88446E-10 -10.0533 0.74315E-10 -10.1289 0.84024E+00 -0.0756 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.15355E-03 -3.8137 0.12825E-03 -3.8920 0.83519E+00 -0.0782 4 SO4-- 0.87147E-11 -11.0597 0.45253E-11 -11.3444 0.51927E+00 -0.2846 5 HCO3- 0.30725E-05 -5.5125 0.25699E-05 -5.5901 0.83641E+00 -0.0776 6 HS- 0.31370E-04 -4.5035 0.26204E-04 -4.5816 0.83531E+00 -0.0782 7 Al+++ 0.97134E-29 -29.0126 0.22438E-29 -29.6490 0.23100E+00 -0.6364 8 H4SiO4 0.69704E-03 -3.1567 0.69704E-03 -3.1567 0.10000E+01 0.0000 9 Ca++ 0.12726E-06 -6.8953 0.65596E-07 -7.1831 0.51546E+00 -0.2878 10 Mg++ 0.21124E-10 -10.6752 0.10839E-10 -10.9650 0.51310E+00 -0.2898 11 Fe++ 0.48475E-13 -13.3145 0.24900E-13 -13.6038 0.51367E+00 -0.2893 12 K+ 0.15651E-03 -3.8055 0.13094E-03 -3.8829 0.83661E+00 -0.0775 13 Na+ 0.19860E-01 -1.7020 0.16584E-01 -1.7803 0.83503E+00 -0.0783 14 Mn++ 0.18601E-10 -10.7305 0.95625E-11 -11.0194 0.51409E+00 -0.2890 15 F- 0.15983E-06 -6.7963 0.13321E-06 -6.8755 0.83346E+00 -0.0791 16 HPO4-- 0.45317E-07 -7.3437 0.23535E-07 -7.6283 0.51935E+00 -0.2845 18 HSiO3- 0.10486E-01 -1.9794 0.87580E-02 -2.0576 0.83519E+00 -0.0782 19 Ca(HSiO3)+ 0.15635E-07 -7.8059 0.13083E-07 -7.8833 0.83679E+00 -0.0774 20 Mg(HSiO3)+ 0.32152E-11 -11.4928 0.26904E-11 -11.5702 0.83679E+00 -0.0774 21 NaHSiO3,aq 0.23491E-02 -2.6291 0.23491E-02 -2.6291 0.10000E+01 0.0000 22 AlO+ 0.66052E-16 -16.1801 0.55271E-16 -16.2575 0.83679E+00 -0.0774 24 HAlO2,aq 0.14811E-09 -9.8294 0.14811E-09 -9.8294 0.10000E+01 0.0000 25 AlO2- 0.52920E-05 -5.2764 0.44118E-05 -5.3554 0.83368E+00 -0.0790 26 CH4,aq 0.14505E-04 -4.8385 0.14455E-04 -4.8400 0.99654E+00 -0.0015 27 C2H6,aq 0.56301E-14 -14.2495 0.56107E-14 -14.2510 0.99654E+00 -0.0015 31 CO,aq 0.65264E-16 -16.1853 0.65264E-16 -16.1853 0.10000E+01 0.0000 32 CO2,aq 0.40950E-09 -9.3878 0.40808E-09 -9.3893 0.99654E+00 -0.0015 33 CO3-2 0.58291E-05 -5.2344 0.30205E-05 -5.5199 0.51817E+00 -0.2855 34 CaCO3,aq 0.24843E-08 -8.6048 0.24843E-08 -8.6048 0.10000E+01 0.0000 35 Ca(HCO3)+ 0.51423E-11 -11.2888 0.43030E-11 -11.3662 0.83679E+00 -0.0774 36 CaCl+ 0.16269E-10 -10.7886 0.13614E-10 -10.8660 0.83679E+00 -0.0774 37 CaCl2,aq 0.41479E-15 -15.3822 0.41479E-15 -15.3822 0.10000E+01 0.0000 38 CaF+ 0.15246E-12 -12.8168 0.12758E-12 -12.8942 0.83679E+00 -0.0774 39 CaOH+ 0.75177E-07 -7.1239 0.62907E-07 -7.2013 0.83679E+00 -0.0774 40 CaSO4,aq 0.94261E-16 -16.0257 0.94261E-16 -16.0257 0.10000E+01 0.0000 41 HCl,aq 0.17464E-14 -14.7578 0.17464E-14 -14.7578 0.10000E+01 0.0000 45 HF,aq 0.67770E-13 -13.1690 0.67770E-13 -13.1690 0.10000E+01 0.0000 48 FeCl+ 0.60403E-17 -17.2189 0.50545E-17 -17.2963 0.83679E+00 -0.0774 51 FeF+ 0.20256E-18 -18.6934 0.16950E-18 -18.7708 0.83679E+00 -0.0774 53 FeO,aq 0.17523E-09 -9.7564 0.17523E-09 -9.7564 0.10000E+01 0.0000 54 FeOH+ 0.13034E-10 -10.8849 0.10906E-10 -10.9623 0.83679E+00 -0.0774 55 HFeO2- 0.29540E-07 -7.5296 0.24671E-07 -7.6078 0.83519E+00 -0.0782 56 FeO+ 0.12321E-16 -16.9094 0.10310E-16 -16.9867 0.83679E+00 -0.0774 58 FeO2- 0.45738E-09 -9.3397 0.38199E-09 -9.4179 0.83519E+00 -0.0782 59 HFeO2,aq 0.36105E-11 -11.4424 0.36105E-11 -11.4424 0.10000E+01 0.0000 60 H2,aq 0.63885E-05 -5.1946 0.63664E-05 -5.1961 0.99654E+00 -0.0015 61 KCl,aq 0.30434E-09 -9.5166 0.30434E-09 -9.5166 0.10000E+01 0.0000 63 KOH,aq 0.75243E-06 -6.1235 0.75243E-06 -6.1235 0.10000E+01 0.0000 64 KSO4- 0.11009E-13 -13.9583 0.91946E-14 -14.0365 0.83519E+00 -0.0782 65 MgCO3,aq 0.10290E-12 -12.9876 0.10290E-12 -12.9876 0.10000E+01 0.0000 66 Mg(HCO3)+ 0.86823E-15 -15.0614 0.72652E-15 -15.1388 0.83679E+00 -0.0774 67 MgCl+ 0.24365E-14 -14.6132 0.20388E-14 -14.6906 0.83679E+00 -0.0774 68 MgF+ 0.93319E-16 -16.0300 0.78088E-16 -16.1074 0.83679E+00 -0.0774 69 MgOH+ 0.68737E-10 -10.1628 0.57518E-10 -10.2402 0.83679E+00 -0.0774 71 MnF+ 0.25641E-16 -16.5911 0.21456E-16 -16.6684 0.83679E+00 -0.0774 72 MnO,aq 0.17931E-08 -8.7464 0.17931E-08 -8.7464 0.10000E+01 0.0000 73 MnOH+ 0.46499E-09 -9.3326 0.38910E-09 -9.4099 0.83679E+00 -0.0774 74 MnO2-2 0.20795E-10 -10.6821 0.10775E-10 -10.9676 0.51817E+00 -0.2855 75 HMnO2- 0.21005E-09 -9.6777 0.17543E-09 -9.7559 0.83519E+00 -0.0782 78 MnCl+ 0.90248E-14 -14.0446 0.75518E-14 -14.1219 0.83679E+00 -0.0774 79 MnSO4,aq 0.12493E-19 -19.9033 0.12493E-19 -19.9033 0.10000E+01 0.0000 80 NaCl,aq 0.70484E-06 -6.1519 0.70484E-06 -6.1519 0.10000E+01 0.0000 81 NaF,aq 0.51721E-09 -9.2863 0.51721E-09 -9.2863 0.10000E+01 0.0000 82 NaOH,aq 0.95880E-04 -4.0183 0.95880E-04 -4.0183 0.10000E+01 0.0000 84 OH- 0.93257E-02 -2.0303 0.77746E-02 -2.1093 0.83368E+00 -0.0790 89 HPO3-2 0.90112E-15 -15.0452 0.46693E-15 -15.3307 0.51817E+00 -0.2855 91 H2PO3- 0.83316E-19 -19.0793 0.69585E-19 -19.1575 0.83519E+00 -0.0782 92 H3PO4,aq 0.90907E-18 -18.0414 0.90907E-18 -18.0414 0.10000E+01 0.0000 93 H2PO4- 0.38595E-10 -10.4135 0.32265E-10 -10.4913 0.83598E+00 -0.0778 94 PO4-3 0.10650E-08 -8.9726 0.25839E-09 -9.5877 0.24262E+00 -0.6151 98 HP2O7-3 0.94850E-18 -18.0230 0.21932E-18 -18.6589 0.23123E+00 -0.6360 99 P2O7-4 0.91458E-17 -17.0388 0.70503E-18 -18.1518 0.77088E-01 -1.1130 100 H2S,aq 0.60393E-08 -8.2190 0.60185E-08 -8.2205 0.99654E+00 -0.0015 101 S2-2 0.46120E-14 -14.3361 0.23898E-14 -14.6216 0.51817E+00 -0.2855 107 SO3-2 0.71220E-17 -17.1474 0.37438E-17 -17.4267 0.52567E+00 -0.2793 108 HSO3- 0.20858E-19 -19.6807 0.17420E-19 -19.7589 0.83519E+00 -0.0782 109 HSO4- 0.38694E-18 -18.4124 0.32410E-18 -18.4893 0.83760E+00 -0.0770 Charge balance for all species = -.6133E-08 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.8844554E-10 -.2228655E-01 -.2242446E+02 0.0000 2 H2O 0.1000000E+01 0.5550487E+02 0.9981989E+06 0.0000 3 Cl- 0.1535538E-03 0.1542589E-03 0.5459436E+01 6.2370 4 SO4-- 0.8714686E-11 -.1610199E-04 -.1544095E+01 8.9135 5 HCO3- 0.3072505E-05 0.2340944E-04 0.1425896E+01 4.5388 6 HS- 0.3137001E-04 0.4747805E-04 0.1567465E+01 5.5473 7 Al+++ 0.9713396E-29 0.5292106E-05 0.1425408E+00 0.7377 8 H4SiO4 0.6970403E-03 0.1353250E-01 0.1298421E+04 -3.1567 9 Ca++ 0.1272566E-06 0.2205752E-06 0.8824847E-02 13.0747 10 Mg++ 0.2112399E-10 0.9318266E-10 0.2261519E-05 9.2928 11 Fe++ 0.4847493E-13 0.3018894E-07 0.1683032E-02 6.6540 12 K+ 0.1565084E-03 0.1572612E-03 0.6138539E+01 6.2460 13 Na+ 0.1986039E-01 0.2230609E-01 0.5119213E+03 8.3486 14 Mn++ 0.1860087E-10 0.2507570E-08 0.1375214E-03 9.2384 15 F- 0.1598289E-06 0.1603463E-06 0.3040964E-02 3.2535 16 HPO4-- 0.4531686E-07 0.4642046E-07 0.4447646E-02 12.6296 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.2001470E-01 -.2001458E-01 -.1200530E-06 0.0000000E+00 2 H2O 0.4984650E+02 0.4984650E+02 -.8898116E-07 0.0000000E+00 3 Cl- 0.1385332E-03 0.1385332E-03 0.0000000E+00 0.0000000E+00 4 SO4-- -.1445981E-04 -.1446050E-04 0.6851123E-09 0.0000000E+00 5 HCO3- 0.2102300E-04 0.2102300E-04 0.0000000E+00 0.0000000E+00 6 HS- 0.4263728E-04 0.4263797E-04 -.6851123E-09 0.0000000E+00 7 Al+++ 0.4775352E-05 0.4752610E-05 0.2274232E-07 0.0000000E+00 8 H4SiO4 0.1215302E-01 0.1215295E-01 0.7467510E-07 0.0000000E+00 9 Ca++ 0.2080835E-06 0.1980889E-06 0.9994562E-08 0.0000000E+00 10 Mg++ 0.8368328E-10 0.8368328E-10 0.0000000E+00 0.0000000E+00 11 Fe++ 0.3259227E-07 0.2711137E-07 0.5480898E-08 0.0000000E+00 12 K+ 0.1412294E-03 0.1412294E-03 0.0000000E+00 0.0000000E+00 13 Na+ 0.2003215E-01 0.2003213E-01 0.2156018E-07 0.0000000E+00 14 Mn++ 0.2251939E-08 0.2251939E-08 0.0000000E+00 0.0000000E+00 15 F- 0.1440000E-06 0.1440000E-06 0.0000000E+00 0.0000000E+00 16 HPO4-- 0.4168819E-07 0.4168819E-07 0.0000000E+00 0.0000000E+00 Chg. balance for solid moles: -.2647E-22 Mass of aqueous solution: 0.899620E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 0.0001100 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 0.2156E-07 -7.666 0.5654E-05 -5.248 77.31 0.2170E-05 andradite 0.2740E-08 -8.562 0.1393E-05 -5.856 19.04 0.3618E-06 grossular 0.5911E-09 -9.228 0.2662E-06 -6.575 3.641 0.7408E-07 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8226E+00 0.8226E+00 1.0000 -0.085 grossular 0.1774E+00 0.1774E+00 1.0000 -0.751 Solid products produced: Mass = 0.000007 g Volume = 0.000003 cm3 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.0001100 moles log = -3.9586 Original solution: 1000.0103000 g Original solution / Rock added: 9091002.73 (Water/Rock Ratio), log = 6.9586 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0501 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9720E+00 0.9855 0.1006E+01 0.1021E+01 CO2,gas 0.4129E-07 1.0069 0.4366E-07 0.4336E-07 CH4,gas 0.2001E-01 1.0123 0.2128E-01 0.2102E-01 H2,gas 0.7955E-02 1.0006 0.8358E-02 0.8354E-02 H2S,gas 0.1582E-06 0.9959 0.1654E-06 0.1661E-06 S2,gas 0.1401E-28 1.0000 0.1471E-28 0.1471E-28 CO,gas 0.9262E-13 1.0000 0.9726E-13 0.9726E-13 SO3,gas 0.8999E-47 1.0000 0.9450E-47 0.9450E-47 SO2,gas 0.2926E-26 1.0000 0.3073E-26 0.3073E-26 HF,gas 0.1585E-15 1.0000 0.1664E-15 0.1664E-15 HCl,gas 0.2935E-17 1.0000 0.3082E-17 0.3082E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 17 albite -0.38 -0.38 0.00 0.000 -0.13080E-10 23 andradite 39.01 39.01 0.00 0.000 0.00000E+00 24 grossular 32.73 32.73 0.00 0.000 -0.12132E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -15.72 -9.06 -3.020 0.15468E+05 -7.360 3 CH4,gas 4.54 1.17 -3.37 -0.843 0.57560E+04 -1.672 4 H2,gas 8.00 4.22 -3.78 -2.158 0.64489E+04 -2.078 5 H2S,gas -6.23 -14.71 -8.48 -4.240 0.14480E+05 -6.781 6 S2,gas -7.34 -37.87 -30.53 -4.697 0.52132E+05 -28.832 7 CO,gas 3.21 -11.50 -14.71 -4.526 0.25119E+05 -13.012 8 SO3,gas 17.12 -31.60 -48.72 -12.181 0.83194E+05 -47.025 9 SO2,gas 0.83 -27.38 -28.21 -7.523 0.48170E+05 -26.512 10 HF,gas 0.47 -17.00 -17.48 -8.739 0.29843E+05 -15.779 11 HCl,gas 5.19 -14.02 -19.21 -9.605 0.32801E+05 -17.511 12 acmite 7.71 6.58 -1.13 -0.118 0.19329E+04 16 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 20 spessartine 24.46 19.72 -4.74 -0.237 0.80880E+04 21 analcite 3.32 2.77 -0.55 -0.061 0.93738E+03 27 annite 20.12 17.48 -2.65 -0.147 0.45210E+04 28 phlogopite 27.06 25.39 -1.67 -0.093 0.28560E+04 30 anorthite 12.71 8.24 -4.47 -0.344 0.76385E+04 33 apatite-OH -18.15 -18.28 -0.13 -0.010 0.22417E+03 34 apatite-F -34.30 -35.29 -0.99 -0.082 0.16873E+04 38 aragonite 0.97 -2.64 -3.61 -1.204 0.61654E+04 39 brucite 12.57 9.29 -3.28 -0.655 0.55932E+04 40 calcite 0.81 -2.64 -3.46 -1.152 0.59011E+04 41 carnegieite-low 9.02 5.93 -3.09 -0.442 0.52824E+04 42 carnegieite-high 10.09 5.93 -4.16 -0.595 0.71094E+04 43 carpholite-Mg 8.58 4.45 -4.13 -0.275 0.70472E+04 44 carpholite-Fe 6.71 1.82 -4.90 -0.326 0.83608E+04 45 celadonite 5.34 3.65 -1.69 -0.100 0.28891E+04 46 celadonite-Fe 3.88 1.01 -2.87 -0.169 0.48931E+04 47 chrysotile 23.89 21.56 -2.33 -0.194 0.39740E+04 49 clinochlore 39.07 38.47 -0.60 -0.019 0.10247E+04 50 daphnite 28.97 25.28 -3.69 -0.115 0.63002E+04 52 chlorite-Al-free 47.17 43.13 -4.04 -0.168 0.69031E+04 54 chloritoid-Fe 9.17 4.97 -4.20 -0.280 0.71728E+04 55 chloritoid-Mn 11.40 7.56 -3.84 -0.256 0.65634E+04 57 coesite -2.38 -3.16 -0.78 -0.260 0.13330E+04 64 cristobalite -2.56 -3.16 -0.60 -0.199 0.10183E+04 66 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71234E+04 68 diaspore 2.87 0.74 -2.14 -0.356 0.36471E+04 69 diamond -3.10 -7.27 -4.17 -1.192 0.71215E+04 70 diopside 16.18 16.05 -0.13 -0.013 0.21736E+03 71 hedenbergite 14.21 13.42 -0.79 -0.079 0.13540E+04 74 enstatite 17.26 12.27 -4.99 -0.499 0.85250E+04 76 clinoenstatite 17.17 12.27 -4.89 -0.489 0.83566E+04 78 epidote 24.67 22.70 -1.97 -0.096 0.33682E+04 79 clinozoisite 22.81 18.89 -3.91 -0.178 0.66823E+04 80 epidote-Fe 29.84 26.50 -3.34 -0.173 0.57007E+04 81 fayalite 14.05 10.15 -3.89 -0.556 0.66496E+04 82 ferrosilite 11.15 6.99 -4.15 -0.415 0.70943E+04 86 gibbsite 4.08 0.74 -3.34 -0.477 0.57056E+04 87 glaucophane 22.97 20.80 -2.18 -0.059 0.37181E+04 88 glaucophane-Fe 17.28 12.88 -4.39 -0.119 0.75042E+04 89 graphite -3.55 -7.27 -3.73 -1.065 0.63638E+04 90 greenalite 16.14 13.65 -2.49 -0.208 0.42531E+04 93 hematite 12.57 9.09 -3.48 -0.422 0.59437E+04 94 heulandite -5.83 -7.55 -1.72 -0.078 0.29364E+04 98 jadeite 4.22 2.77 -1.44 -0.144 0.24629E+04 100 kalsilite 7.58 3.83 -3.76 -0.537 0.64148E+04 101 kaolinite -1.33 -4.84 -3.51 -0.319 0.59851E+04 104 laumontite 2.88 1.92 -0.96 -0.064 0.16395E+04 105 lawsonite 9.62 8.24 -1.38 -0.092 0.23552E+04 106 leucite 4.12 0.67 -3.45 -0.345 0.58884E+04 108 lizardite 23.24 21.56 -1.68 -0.140 0.28666E+04 110 magnetite 20.09 15.74 -4.35 -0.355 0.74244E+04 111 minnesotaite 10.39 7.34 -3.05 -0.180 0.52128E+04 115 manganosite 14.06 9.24 -4.82 -1.205 0.82295E+04 119 microcline -2.49 -2.49 0.00 0.000 0.94227E-02 123 muscovite 2.58 -1.01 -3.59 -0.211 0.61357E+04 124 paragonite 4.24 1.09 -3.15 -0.185 0.53748E+04 125 nepheline 8.34 5.93 -2.41 -0.344 0.41147E+04 131 periclase-Fe 11.63 6.65 -4.97 -1.243 0.84905E+04 137 phlogopite-Na 29.65 27.49 -2.15 -0.120 0.36748E+04 139 prehnite 19.37 18.15 -1.22 -0.072 0.20783E+04 140 prehnite-Fe 22.50 21.96 -0.54 -0.032 0.91916E+03 141 pumpellyite-Fe 46.27 43.70 -2.57 -0.057 0.43852E+04 142 pumpellyite-Mg 48.99 46.34 -2.65 -0.059 0.45332E+04 146 pyrrhotite -4.26 -8.06 -3.80 -1.265 0.64819E+04 147 pyrrhotiteFe0.875 -6.02 -9.41 -3.39 -1.249 0.57968E+04 148 pyroxmangite 7.40 6.08 -1.32 -0.263 0.22487E+04 149 pyrophyllite -6.18 -11.15 -4.98 -0.311 0.84958E+04 150 quartz -2.99 -3.16 -0.17 -0.056 0.28567E+03 155 rhodonite 7.45 6.08 -1.36 -0.273 0.23290E+04 156 sanidine -1.28 -2.49 -1.21 -0.093 0.20678E+04 166 stilbite -7.52 -7.55 -0.02 -0.001 0.42570E+02 167 stilpnomelane-Fe 13.02 12.61 -0.40 -0.012 0.68678E+03 168 stilpnomelane-Mg 27.44 25.81 -1.63 -0.049 0.27879E+04 174 talc 16.49 15.25 -1.24 -0.073 0.21165E+04 177 tephroite 18.09 15.32 -2.77 -0.395 0.47224E+04 181 tridymite -2.63 -3.16 -0.53 -0.177 0.90565E+03 182 tremolite 47.87 47.36 -0.51 -0.014 0.87018E+03 183 ferroactinolite 38.45 34.17 -4.29 -0.116 0.73194E+04 184 troilite-low -4.41 -8.06 -3.65 -1.215 0.62247E+04 190 wairakite 3.95 1.92 -2.03 -0.119 0.34614E+04 191 walstromite 11.51 9.92 -1.59 -0.318 0.27170E+04 192 wollastonite 10.46 9.92 -0.54 -0.109 0.92745E+03 193 pseudo-wollastonite 11.00 9.92 -1.08 -0.216 0.18473E+04 194 zoisite 22.85 18.89 -3.96 -0.180 0.67564E+04 195 akaganeite 7.75 4.54 -3.21 -0.694 0.54844E+04 202 chalcedony -2.80 -3.16 -0.35 -0.118 0.60497E+03 204 montmorillonite-Ca -2.29 -6.17 -3.88 -0.240 0.66254E+04 205 montmorillonite-K -2.24 -6.27 -4.03 -0.247 0.68818E+04 206 montmorillonite-Mg -2.48 -6.79 -4.32 -0.267 0.73679E+04 207 montmorillonite-Na -2.04 -5.57 -3.54 -0.217 0.60367E+04 208 nontronite-Ca 3.21 -0.10 -3.31 -0.215 0.56583E+04 209 nontronite-H 2.53 -2.26 -4.79 -0.321 0.81776E+04 210 nontronite-K 3.34 -0.20 -3.54 -0.227 0.60379E+04 211 nontronite-Mg 3.07 -0.72 -3.80 -0.246 0.64848E+04 212 nontronite-Na 3.52 0.50 -3.02 -0.194 0.51587E+04 228 tobermorite 9.82 7.73 -2.09 -0.570 0.35661E+04 234 alabandite -0.98 -5.47 -4.49 -1.498 0.76739E+04 237 boehmite 4.41 0.74 -3.67 -0.611 0.62640E+04 239 ferrous-oxide 9.81 6.65 -3.16 -0.789 0.53914E+04 245 silica-amorphous -2.09 -3.16 -1.07 -0.355 0.18191E+04 247 an20ab80 2.02 1.34 -0.68 -0.052 0.11569E+04 248 an25ab75 2.65 1.77 -0.87 -0.067 0.14930E+04 249 an30ab70 3.28 2.20 -1.08 -0.083 0.18388E+04 250 tr.625ac.25prg.125 45.16 45.01 -0.16 -0.004 0.26599E+03 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 0.0000100 MOLES Current total amount of reactant added: 0.0001100 MOLES New total amount of reactant added: 0.0001200 MOLES Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.5508E-08 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 6 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 0.0001200 Water: Moles liquid = 0.4985E+02 kg liquid = 0.8981E+00 Moles total = 0.4985E+02 kg total = 0.8980E+00 Activity = 1.0000 Stoichiometric ionic strength = .1133787E-01 Osmotic coef. = 0.9689 True ionic strength = .2002382E-01 Chg. balance for total moles = -.5508E-08 Max. difference allowed = 0.1386E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.88461E-10 -10.0532 0.74328E-10 -10.1288 0.84024E+00 -0.0756 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.15362E-03 -3.8136 0.12830E-03 -3.8918 0.83518E+00 -0.0782 4 SO4-- 0.96148E-11 -11.0171 0.49927E-11 -11.3017 0.51927E+00 -0.2846 5 HCO3- 0.33568E-05 -5.4741 0.28076E-05 -5.5517 0.83641E+00 -0.0776 6 HS- 0.31641E-04 -4.4998 0.26430E-04 -4.5779 0.83531E+00 -0.0782 7 Al+++ 0.97155E-29 -29.0125 0.22442E-29 -29.6489 0.23099E+00 -0.6364 8 H4SiO4 0.69715E-03 -3.1567 0.69715E-03 -3.1567 0.10000E+01 0.0000 9 Ca++ 0.12694E-06 -6.8964 0.65432E-07 -7.1842 0.51546E+00 -0.2878 10 Mg++ 0.21125E-10 -10.6752 0.10839E-10 -10.9650 0.51310E+00 -0.2898 11 Fe++ 0.48188E-13 -13.3171 0.24752E-13 -13.6064 0.51366E+00 -0.2893 12 K+ 0.15651E-03 -3.8055 0.13094E-03 -3.8829 0.83660E+00 -0.0775 13 Na+ 0.19860E-01 -1.7020 0.16584E-01 -1.7803 0.83503E+00 -0.0783 14 Mn++ 0.18607E-10 -10.7303 0.95656E-11 -11.0193 0.51409E+00 -0.2890 15 F- 0.16427E-06 -6.7844 0.13691E-06 -6.8636 0.83346E+00 -0.0791 16 HPO4-- 0.45317E-07 -7.3437 0.23535E-07 -7.6283 0.51934E+00 -0.2845 18 HSiO3- 0.10486E-01 -1.9794 0.87579E-02 -2.0576 0.83518E+00 -0.0782 19 Ca(HSiO3)+ 0.15596E-07 -7.8070 0.13050E-07 -7.8844 0.83678E+00 -0.0774 20 Mg(HSiO3)+ 0.32152E-11 -11.4928 0.26905E-11 -11.5702 0.83678E+00 -0.0774 21 NaHSiO3,aq 0.23491E-02 -2.6291 0.23491E-02 -2.6291 0.10000E+01 0.0000 22 AlO+ 0.66043E-16 -16.1802 0.55264E-16 -16.2576 0.83678E+00 -0.0774 24 HAlO2,aq 0.14807E-09 -9.8295 0.14807E-09 -9.8295 0.10000E+01 0.0000 25 AlO2- 0.52894E-05 -5.2766 0.44097E-05 -5.3556 0.83368E+00 -0.0790 26 CH4,aq 0.14487E-04 -4.8390 0.14437E-04 -4.8405 0.99654E+00 -0.0015 27 C2H6,aq 0.57441E-14 -14.2408 0.57242E-14 -14.2423 0.99654E+00 -0.0015 31 CO,aq 0.69729E-16 -16.1566 0.69729E-16 -16.1566 0.10000E+01 0.0000 32 CO2,aq 0.44746E-09 -9.3493 0.44591E-09 -9.3508 0.99654E+00 -0.0015 33 CO3-2 0.63673E-05 -5.1960 0.32993E-05 -5.4816 0.51817E+00 -0.2855 34 CaCO3,aq 0.27069E-08 -8.5675 0.27069E-08 -8.5675 0.10000E+01 0.0000 35 Ca(HCO3)+ 0.56040E-11 -11.2515 0.46893E-11 -11.3289 0.83678E+00 -0.0774 36 CaCl+ 0.16236E-10 -10.7895 0.13586E-10 -10.8669 0.83678E+00 -0.0774 37 CaCl2,aq 0.41411E-15 -15.3829 0.41411E-15 -15.3829 0.10000E+01 0.0000 38 CaF+ 0.15631E-12 -12.8060 0.13079E-12 -12.8834 0.83678E+00 -0.0774 39 CaOH+ 0.74977E-07 -7.1251 0.62740E-07 -7.2025 0.83678E+00 -0.0774 40 CaSO4,aq 0.10374E-15 -15.9841 0.10374E-15 -15.9841 0.10000E+01 0.0000 41 HCl,aq 0.17475E-14 -14.7576 0.17475E-14 -14.7576 0.10000E+01 0.0000 45 HF,aq 0.69664E-13 -13.1570 0.69664E-13 -13.1570 0.10000E+01 0.0000 48 FeCl+ 0.60071E-17 -17.2213 0.50267E-17 -17.2987 0.83678E+00 -0.0774 51 FeF+ 0.20696E-18 -18.6841 0.17318E-18 -18.7615 0.83678E+00 -0.0774 53 FeO,aq 0.17413E-09 -9.7591 0.17413E-09 -9.7591 0.10000E+01 0.0000 54 FeOH+ 0.12954E-10 -10.8876 0.10840E-10 -10.9650 0.83678E+00 -0.0774 55 HFeO2- 0.29350E-07 -7.5324 0.24513E-07 -7.6106 0.83518E+00 -0.0782 56 FeO+ 0.12384E-16 -16.9071 0.10363E-16 -16.9845 0.83678E+00 -0.0774 58 FeO2- 0.45957E-09 -9.3376 0.38383E-09 -9.4159 0.83518E+00 -0.0782 59 HFeO2,aq 0.36285E-11 -11.4403 0.36285E-11 -11.4403 0.10000E+01 0.0000 60 H2,aq 0.62465E-05 -5.2044 0.62249E-05 -5.2059 0.99654E+00 -0.0015 61 KCl,aq 0.30447E-09 -9.5165 0.30447E-09 -9.5165 0.10000E+01 0.0000 63 KOH,aq 0.75230E-06 -6.1236 0.75230E-06 -6.1236 0.10000E+01 0.0000 64 KSO4- 0.12146E-13 -13.9156 0.10144E-13 -13.9938 0.83518E+00 -0.0782 65 MgCO3,aq 0.11240E-12 -12.9492 0.11240E-12 -12.9492 0.10000E+01 0.0000 66 Mg(HCO3)+ 0.94857E-15 -15.0229 0.79374E-15 -15.1003 0.83678E+00 -0.0774 67 MgCl+ 0.24376E-14 -14.6130 0.20397E-14 -14.6904 0.83678E+00 -0.0774 68 MgF+ 0.95913E-16 -16.0181 0.80259E-16 -16.0955 0.83678E+00 -0.0774 69 MgOH+ 0.68727E-10 -10.1629 0.57510E-10 -10.2403 0.83678E+00 -0.0774 71 MnF+ 0.26362E-16 -16.5790 0.22059E-16 -16.6564 0.83678E+00 -0.0774 72 MnO,aq 0.17931E-08 -8.7464 0.17931E-08 -8.7464 0.10000E+01 0.0000 73 MnOH+ 0.46506E-09 -9.3325 0.38916E-09 -9.4099 0.83678E+00 -0.0774 74 MnO2-2 0.20787E-10 -10.6822 0.10771E-10 -10.9677 0.51817E+00 -0.2855 75 HMnO2- 0.21001E-09 -9.6778 0.17540E-09 -9.7560 0.83518E+00 -0.0782 78 MnCl+ 0.90316E-14 -14.0442 0.75575E-14 -14.1216 0.83678E+00 -0.0774 79 MnSO4,aq 0.13787E-19 -19.8605 0.13787E-19 -19.8605 0.10000E+01 0.0000 80 NaCl,aq 0.70514E-06 -6.1517 0.70514E-06 -6.1517 0.10000E+01 0.0000 81 NaF,aq 0.53158E-09 -9.2744 0.53158E-09 -9.2744 0.10000E+01 0.0000 82 NaOH,aq 0.95863E-04 -4.0183 0.95863E-04 -4.0183 0.10000E+01 0.0000 84 OH- 0.93241E-02 -2.0304 0.77733E-02 -2.1094 0.83368E+00 -0.0790 89 HPO3-2 0.88110E-15 -15.0550 0.45656E-15 -15.3405 0.51817E+00 -0.2855 91 H2PO3- 0.81479E-19 -19.0890 0.68050E-19 -19.1672 0.83518E+00 -0.0782 92 H3PO4,aq 0.90938E-18 -18.0413 0.90938E-18 -18.0413 0.10000E+01 0.0000 93 H2PO4- 0.38602E-10 -10.4134 0.32270E-10 -10.4912 0.83598E+00 -0.0778 94 PO4-3 0.10648E-08 -8.9727 0.25834E-09 -9.5878 0.24261E+00 -0.6151 98 HP2O7-3 0.94867E-18 -18.0229 0.21936E-18 -18.6589 0.23123E+00 -0.6360 99 P2O7-4 0.91460E-17 -17.0388 0.70503E-18 -18.1518 0.77086E-01 -1.1130 100 H2S,aq 0.60924E-08 -8.2152 0.60714E-08 -8.2167 0.99654E+00 -0.0015 101 S2-2 0.47985E-14 -14.3189 0.24864E-14 -14.6044 0.51817E+00 -0.2855 107 SO3-2 0.76830E-17 -17.1145 0.40387E-17 -17.3938 0.52566E+00 -0.2793 108 HSO3- 0.22505E-19 -19.6477 0.18795E-19 -19.7259 0.83518E+00 -0.0782 109 HSO4- 0.42697E-18 -18.3696 0.35763E-18 -18.4466 0.83760E+00 -0.0770 Charge balance for all species = -.6133E-08 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.8846074E-10 -.2228533E-01 -.2242324E+02 0.0000 2 H2O 0.1000000E+01 0.5550487E+02 0.9981988E+06 0.0000 3 Cl- 0.1536191E-03 0.1543246E-03 0.5461760E+01 6.2371 4 SO4-- 0.9614767E-11 -.1604884E-04 -.1538998E+01 8.9560 5 HCO3- 0.3356754E-05 0.2421451E-04 0.1474934E+01 4.5772 6 HS- 0.3164054E-04 0.4769548E-04 0.1574643E+01 5.5509 7 Al+++ 0.9715535E-29 0.5289591E-05 0.1424730E+00 0.7376 8 H4SiO4 0.6971513E-03 0.1353249E-01 0.1298420E+04 -3.1567 9 Ca++ 0.1269396E-06 0.2202416E-06 0.8811501E-02 13.0735 10 Mg++ 0.2112456E-10 0.9318264E-10 0.2261519E-05 9.2927 11 Fe++ 0.4818832E-13 0.3000017E-07 0.1672507E-02 6.6513 12 K+ 0.1565085E-03 0.1572612E-03 0.6138537E+01 6.2459 13 Na+ 0.1986042E-01 0.2230609E-01 0.5119211E+03 8.3485 14 Mn++ 0.1860701E-10 0.2507569E-08 0.1375214E-03 9.2384 15 F- 0.1642685E-06 0.1648003E-06 0.3125435E-02 3.2653 16 HPO4-- 0.4531702E-07 0.4642045E-07 0.4447645E-02 12.6294 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.2001362E-01 -.2001349E-01 -.1299725E-06 0.0000000E+00 2 H2O 0.4984651E+02 0.4984651E+02 -.9797806E-07 0.0000000E+00 3 Cl- 0.1385922E-03 0.1385922E-03 0.0000000E+00 0.0000000E+00 4 SO4-- -.1441206E-04 -.1441277E-04 0.7063027E-09 0.0000000E+00 5 HCO3- 0.2174600E-04 0.2174600E-04 0.0000000E+00 0.0000000E+00 6 HS- 0.4283253E-04 0.4283324E-04 -.7063027E-09 0.0000000E+00 7 Al+++ 0.4775352E-05 0.4750351E-05 0.2500052E-07 0.0000000E+00 8 H4SiO4 0.1215302E-01 0.1215294E-01 0.8165873E-07 0.0000000E+00 9 Ca++ 0.2080835E-06 0.1977894E-06 0.1029410E-07 0.0000000E+00 10 Mg++ 0.8368328E-10 0.8368328E-10 0.0000000E+00 0.0000000E+00 11 Fe++ 0.3259227E-07 0.2694185E-07 0.5650421E-08 0.0000000E+00 12 K+ 0.1412294E-03 0.1412294E-03 0.0000000E+00 0.0000000E+00 13 Na+ 0.2003215E-01 0.2003213E-01 0.2378821E-07 0.0000000E+00 14 Mn++ 0.2251939E-08 0.2251939E-08 0.0000000E+00 0.0000000E+00 15 F- 0.1480000E-06 0.1480000E-06 0.0000000E+00 0.0000000E+00 16 HPO4-- 0.4168819E-07 0.4168819E-07 0.0000000E+00 0.0000000E+00 Chg. balance for solid moles: -.6617E-23 Mass of aqueous solution: 0.899620E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 0.0001200 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 0.2379E-07 -7.624 0.6238E-05 -5.205 78.50 0.2395E-05 andradite 0.2825E-08 -8.549 0.1436E-05 -5.843 18.07 0.3730E-06 grossular 0.6062E-09 -9.217 0.2730E-06 -6.564 3.436 0.7597E-07 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8233E+00 0.8233E+00 1.0000 -0.084 grossular 0.1767E+00 0.1767E+00 1.0000 -0.753 Solid products produced: Mass = 0.000008 g Volume = 0.000003 cm3 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.0001200 moles log = -3.9208 Original solution: 1000.0103000 g Original solution / Rock added: 8333419.17 (Water/Rock Ratio), log = 6.9208 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0499 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9722E+00 0.9856 0.1006E+01 0.1021E+01 CO2,gas 0.4513E-07 1.0069 0.4771E-07 0.4738E-07 CH4,gas 0.1999E-01 1.0123 0.2125E-01 0.2099E-01 H2,gas 0.7780E-02 1.0006 0.8173E-02 0.8168E-02 H2S,gas 0.1596E-06 0.9959 0.1669E-06 0.1676E-06 S2,gas 0.1491E-28 1.0000 0.1565E-28 0.1565E-28 CO,gas 0.9897E-13 1.0000 0.1039E-12 0.1039E-12 SO3,gas 0.9934E-47 1.0000 0.1043E-46 0.1043E-46 SO2,gas 0.3158E-26 1.0000 0.3316E-26 0.3316E-26 HF,gas 0.1629E-15 1.0000 0.1711E-15 0.1711E-15 HCl,gas 0.2937E-17 1.0000 0.3083E-17 0.3083E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 17 albite -0.38 -0.38 0.00 0.000 -0.94784E-12 23 andradite 39.01 39.01 0.00 0.000 0.00000E+00 24 grossular 32.73 32.73 0.00 0.000 0.24265E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -15.68 -9.02 -3.007 0.15402E+05 -7.321 3 CH4,gas 4.54 1.17 -3.37 -0.843 0.57569E+04 -1.673 4 H2,gas 8.00 4.21 -3.79 -2.164 0.64655E+04 -2.088 5 H2S,gas -6.23 -14.71 -8.48 -4.238 0.14473E+05 -6.778 6 S2,gas -7.34 -37.84 -30.50 -4.693 0.52085E+05 -28.805 7 CO,gas 3.21 -11.47 -14.68 -4.518 0.25070E+05 -12.983 8 SO3,gas 17.12 -31.56 -48.68 -12.170 0.83121E+05 -46.982 9 SO2,gas 0.83 -27.35 -28.18 -7.514 0.48114E+05 -26.479 10 HF,gas 0.47 -16.99 -17.47 -8.733 0.29822E+05 -15.767 11 HCl,gas 5.19 -14.02 -19.21 -9.605 0.32800E+05 -17.511 12 acmite 7.71 6.58 -1.13 -0.117 0.19291E+04 16 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 20 spessartine 24.46 19.72 -4.74 -0.237 0.80881E+04 21 analcite 3.32 2.77 -0.55 -0.061 0.93750E+03 27 annite 20.12 17.47 -2.66 -0.148 0.45350E+04 28 phlogopite 27.06 25.39 -1.67 -0.093 0.28567E+04 30 anorthite 12.71 8.24 -4.47 -0.344 0.76409E+04 33 apatite-OH -18.15 -18.29 -0.14 -0.011 0.23396E+03 34 apatite-F -34.30 -35.28 -0.98 -0.082 0.16766E+04 38 aragonite 0.97 -2.61 -3.57 -1.191 0.61017E+04 39 brucite 12.57 9.29 -3.28 -0.655 0.55935E+04 40 calcite 0.81 -2.61 -3.42 -1.140 0.58375E+04 41 carnegieite-low 9.02 5.93 -3.09 -0.442 0.52826E+04 42 carnegieite-high 10.09 5.93 -4.16 -0.595 0.71096E+04 43 carpholite-Mg 8.58 4.45 -4.13 -0.275 0.70476E+04 44 carpholite-Fe 6.71 1.81 -4.90 -0.327 0.83657E+04 45 celadonite 5.34 3.65 -1.69 -0.100 0.28892E+04 46 celadonite-Fe 3.88 1.01 -2.87 -0.169 0.48977E+04 47 chrysotile 23.89 21.56 -2.33 -0.194 0.39745E+04 49 clinochlore 39.07 38.47 -0.60 -0.019 0.10260E+04 50 daphnite 28.97 25.26 -3.70 -0.116 0.63236E+04 52 chlorite-Al-free 47.17 43.13 -4.04 -0.168 0.69041E+04 54 chloritoid-Fe 9.17 4.97 -4.20 -0.280 0.71778E+04 55 chloritoid-Mn 11.40 7.56 -3.84 -0.256 0.65637E+04 57 coesite -2.38 -3.16 -0.78 -0.260 0.13329E+04 64 cristobalite -2.56 -3.16 -0.60 -0.199 0.10182E+04 66 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71234E+04 68 diaspore 2.87 0.74 -2.14 -0.356 0.36473E+04 69 diamond -3.10 -7.25 -4.15 -1.186 0.70891E+04 70 diopside 16.18 16.05 -0.13 -0.013 0.21947E+03 71 hedenbergite 14.21 13.41 -0.80 -0.080 0.13606E+04 74 enstatite 17.26 12.27 -4.99 -0.499 0.85252E+04 76 clinoenstatite 17.17 12.27 -4.89 -0.489 0.83568E+04 78 epidote 24.67 22.70 -1.97 -0.096 0.33688E+04 79 clinozoisite 22.81 18.89 -3.92 -0.178 0.66869E+04 80 epidote-Fe 29.84 26.50 -3.34 -0.173 0.56974E+04 81 fayalite 14.05 10.15 -3.90 -0.557 0.66588E+04 82 ferrosilite 11.15 6.99 -4.16 -0.416 0.71034E+04 86 gibbsite 4.08 0.74 -3.34 -0.477 0.57059E+04 87 glaucophane 22.97 20.80 -2.18 -0.059 0.37186E+04 88 glaucophane-Fe 17.28 12.87 -4.40 -0.119 0.75179E+04 89 graphite -3.55 -7.25 -3.71 -1.059 0.63314E+04 90 greenalite 16.14 13.64 -2.50 -0.208 0.42668E+04 93 hematite 12.57 9.09 -3.48 -0.421 0.59364E+04 94 heulandite -5.83 -7.55 -1.72 -0.078 0.29381E+04 98 jadeite 4.22 2.77 -1.44 -0.144 0.24630E+04 100 kalsilite 7.58 3.83 -3.76 -0.537 0.64151E+04 101 kaolinite -1.33 -4.84 -3.51 -0.319 0.59853E+04 104 laumontite 2.88 1.92 -0.96 -0.064 0.16416E+04 105 lawsonite 9.62 8.24 -1.38 -0.092 0.23575E+04 106 leucite 4.12 0.67 -3.45 -0.345 0.58885E+04 108 lizardite 23.24 21.56 -1.68 -0.140 0.28671E+04 110 magnetite 20.09 15.74 -4.35 -0.355 0.74217E+04 111 minnesotaite 10.39 7.33 -3.06 -0.180 0.52263E+04 115 manganosite 14.06 9.24 -4.82 -1.205 0.82295E+04 119 microcline -2.49 -2.49 0.00 0.000 0.10242E-01 123 muscovite 2.58 -1.01 -3.59 -0.211 0.61362E+04 124 paragonite 4.24 1.09 -3.15 -0.185 0.53753E+04 125 nepheline 8.34 5.93 -2.41 -0.344 0.41150E+04 131 periclase-Fe 11.63 6.65 -4.98 -1.244 0.84951E+04 137 phlogopite-Na 29.65 27.49 -2.15 -0.120 0.36755E+04 139 prehnite 19.37 18.15 -1.22 -0.072 0.20826E+04 140 prehnite-Fe 22.50 21.96 -0.54 -0.032 0.91958E+03 141 pumpellyite-Fe 46.27 43.69 -2.58 -0.057 0.43987E+04 142 pumpellyite-Mg 48.99 46.33 -2.66 -0.059 0.45423E+04 146 pyrrhotite -4.26 -8.06 -3.80 -1.265 0.64801E+04 147 pyrrhotiteFe0.875 -6.02 -9.41 -3.39 -1.248 0.57923E+04 148 pyroxmangite 7.40 6.08 -1.32 -0.263 0.22486E+04 149 pyrophyllite -6.18 -11.15 -4.98 -0.311 0.84958E+04 150 quartz -2.99 -3.16 -0.17 -0.056 0.28555E+03 155 rhodonite 7.45 6.08 -1.36 -0.273 0.23289E+04 156 sanidine -1.28 -2.49 -1.21 -0.093 0.20678E+04 166 stilbite -7.52 -7.55 -0.03 -0.001 0.44307E+02 167 stilpnomelane-Fe 13.02 12.60 -0.42 -0.012 0.70963E+03 168 stilpnomelane-Mg 27.44 25.81 -1.63 -0.049 0.27886E+04 174 talc 16.49 15.25 -1.24 -0.073 0.21168E+04 177 tephroite 18.09 15.32 -2.77 -0.395 0.47223E+04 181 tridymite -2.63 -3.16 -0.53 -0.177 0.90553E+03 182 tremolite 47.87 47.36 -0.51 -0.014 0.87463E+03 183 ferroactinolite 38.45 34.15 -4.30 -0.116 0.73459E+04 184 troilite-low -4.41 -8.06 -3.64 -1.215 0.62229E+04 190 wairakite 3.95 1.92 -2.03 -0.119 0.34635E+04 191 walstromite 11.51 9.92 -1.59 -0.318 0.27190E+04 192 wollastonite 10.46 9.92 -0.54 -0.109 0.92944E+03 193 pseudo-wollastonite 11.00 9.92 -1.08 -0.217 0.18493E+04 194 zoisite 22.85 18.89 -3.96 -0.180 0.67609E+04 195 akaganeite 7.75 4.54 -3.21 -0.694 0.54807E+04 202 chalcedony -2.80 -3.16 -0.35 -0.118 0.60485E+03 204 montmorillonite-Ca -2.29 -6.17 -3.88 -0.240 0.66258E+04 205 montmorillonite-K -2.24 -6.27 -4.03 -0.247 0.68818E+04 206 montmorillonite-Mg -2.48 -6.80 -4.32 -0.267 0.73680E+04 207 montmorillonite-Na -2.04 -5.57 -3.54 -0.217 0.60367E+04 208 nontronite-Ca 3.21 -0.09 -3.31 -0.215 0.56509E+04 209 nontronite-H 2.53 -2.25 -4.78 -0.321 0.81699E+04 210 nontronite-K 3.34 -0.19 -3.53 -0.227 0.60302E+04 211 nontronite-Mg 3.07 -0.72 -3.79 -0.246 0.64772E+04 212 nontronite-Na 3.52 0.50 -3.02 -0.194 0.51511E+04 228 tobermorite 9.82 7.73 -2.09 -0.570 0.35678E+04 234 alabandite -0.98 -5.47 -4.49 -1.497 0.76674E+04 237 boehmite 4.41 0.74 -3.67 -0.611 0.62642E+04 239 ferrous-oxide 9.81 6.65 -3.16 -0.790 0.53961E+04 245 silica-amorphous -2.09 -3.16 -1.07 -0.355 0.18190E+04 247 an20ab80 2.02 1.34 -0.68 -0.052 0.11573E+04 248 an25ab75 2.65 1.77 -0.87 -0.067 0.14936E+04 249 an30ab70 3.28 2.20 -1.08 -0.083 0.18395E+04 250 tr.625ac.25prg.125 45.16 45.00 -0.16 -0.004 0.27607E+03 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 0.0000100 MOLES Current total amount of reactant added: 0.0001200 MOLES New total amount of reactant added: 0.0001300 MOLES Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.5508E-08 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 6 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 0.0001300 Water: Moles liquid = 0.4985E+02 kg liquid = 0.8981E+00 Moles total = 0.4985E+02 kg total = 0.8980E+00 Activity = 1.0000 Stoichiometric ionic strength = .1133851E-01 Osmotic coef. = 0.9689 True ionic strength = .2002440E-01 Chg. balance for total moles = -.5508E-08 Max. difference allowed = 0.1387E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.88476E-10 -10.0532 0.74341E-10 -10.1288 0.84024E+00 -0.0756 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.15368E-03 -3.8134 0.12835E-03 -3.8916 0.83518E+00 -0.0782 4 SO4-- 0.10537E-10 -10.9773 0.54715E-11 -11.2619 0.51927E+00 -0.2846 5 HCO3- 0.36422E-05 -5.4386 0.30464E-05 -5.5162 0.83640E+00 -0.0776 6 HS- 0.31911E-04 -4.4961 0.26655E-04 -4.5742 0.83530E+00 -0.0782 7 Al+++ 0.97177E-29 -29.0124 0.22447E-29 -29.6488 0.23099E+00 -0.6364 8 H4SiO4 0.69726E-03 -3.1566 0.69726E-03 -3.1566 0.10000E+01 0.0000 9 Ca++ 0.12664E-06 -6.8974 0.65278E-07 -7.1852 0.51545E+00 -0.2878 10 Mg++ 0.21125E-10 -10.6752 0.10839E-10 -10.9650 0.51310E+00 -0.2898 11 Fe++ 0.47931E-13 -13.3194 0.24620E-13 -13.6087 0.51366E+00 -0.2893 12 K+ 0.15651E-03 -3.8055 0.13094E-03 -3.8829 0.83660E+00 -0.0775 13 Na+ 0.19860E-01 -1.7020 0.16584E-01 -1.7803 0.83503E+00 -0.0783 14 Mn++ 0.18613E-10 -10.7302 0.95687E-11 -11.0191 0.51408E+00 -0.2890 15 F- 0.16871E-06 -6.7729 0.14061E-06 -6.8520 0.83346E+00 -0.0791 16 HPO4-- 0.45317E-07 -7.3437 0.23535E-07 -7.6283 0.51934E+00 -0.2845 18 HSiO3- 0.10486E-01 -1.9794 0.87578E-02 -2.0576 0.83518E+00 -0.0782 19 Ca(HSiO3)+ 0.15559E-07 -7.8080 0.13020E-07 -7.8854 0.83678E+00 -0.0774 20 Mg(HSiO3)+ 0.32153E-11 -11.4928 0.26905E-11 -11.5702 0.83678E+00 -0.0774 21 NaHSiO3,aq 0.23491E-02 -2.6291 0.23491E-02 -2.6291 0.10000E+01 0.0000 22 AlO+ 0.66034E-16 -16.1802 0.55256E-16 -16.2576 0.83678E+00 -0.0774 24 HAlO2,aq 0.14802E-09 -9.8297 0.14802E-09 -9.8297 0.10000E+01 0.0000 25 AlO2- 0.52869E-05 -5.2768 0.44076E-05 -5.3558 0.83367E+00 -0.0790 26 CH4,aq 0.14466E-04 -4.8396 0.14416E-04 -4.8411 0.99654E+00 -0.0015 27 C2H6,aq 0.58478E-14 -14.2330 0.58276E-14 -14.2345 0.99654E+00 -0.0015 31 CO,aq 0.74113E-16 -16.1301 0.74113E-16 -16.1301 0.10000E+01 0.0000 32 CO2,aq 0.48559E-09 -9.3137 0.48391E-09 -9.3152 0.99654E+00 -0.0015 33 CO3-2 0.69077E-05 -5.1607 0.35793E-05 -5.4462 0.51816E+00 -0.2855 34 CaCO3,aq 0.29297E-08 -8.5332 0.29297E-08 -8.5332 0.10000E+01 0.0000 35 Ca(HCO3)+ 0.60662E-11 -11.2171 0.50761E-11 -11.2945 0.83678E+00 -0.0774 36 CaCl+ 0.16204E-10 -10.7904 0.13559E-10 -10.8678 0.83678E+00 -0.0774 37 CaCl2,aq 0.41348E-15 -15.3835 0.41348E-15 -15.3835 0.10000E+01 0.0000 38 CaF+ 0.16015E-12 -12.7955 0.13401E-12 -12.8729 0.83678E+00 -0.0774 39 CaOH+ 0.74788E-07 -7.1262 0.62581E-07 -7.2036 0.83678E+00 -0.0774 40 CaSO4,aq 0.11342E-15 -15.9453 0.11342E-15 -15.9453 0.10000E+01 0.0000 41 HCl,aq 0.17485E-14 -14.7573 0.17485E-14 -14.7573 0.10000E+01 0.0000 45 HF,aq 0.71559E-13 -13.1453 0.71559E-13 -13.1453 0.10000E+01 0.0000 48 FeCl+ 0.59775E-17 -17.2235 0.50019E-17 -17.3009 0.83678E+00 -0.0774 51 FeF+ 0.21141E-18 -18.6749 0.17691E-18 -18.7523 0.83678E+00 -0.0774 53 FeO,aq 0.17314E-09 -9.7616 0.17314E-09 -9.7616 0.10000E+01 0.0000 54 FeOH+ 0.12883E-10 -10.8900 0.10780E-10 -10.9674 0.83678E+00 -0.0774 55 HFeO2- 0.29178E-07 -7.5349 0.24369E-07 -7.6132 0.83518E+00 -0.0782 56 FeO+ 0.12445E-16 -16.9050 0.10414E-16 -16.9824 0.83678E+00 -0.0774 58 FeO2- 0.46165E-09 -9.3357 0.38557E-09 -9.4139 0.83518E+00 -0.0782 59 HFeO2,aq 0.36455E-11 -11.4382 0.36455E-11 -11.4382 0.10000E+01 0.0000 60 H2,aq 0.61179E-05 -5.2134 0.60967E-05 -5.2149 0.99654E+00 -0.0015 61 KCl,aq 0.30460E-09 -9.5163 0.30460E-09 -9.5163 0.10000E+01 0.0000 63 KOH,aq 0.75217E-06 -6.1237 0.75217E-06 -6.1237 0.10000E+01 0.0000 64 KSO4- 0.13311E-13 -13.8758 0.11117E-13 -13.9540 0.83518E+00 -0.0782 65 MgCO3,aq 0.12194E-12 -12.9139 0.12194E-12 -12.9139 0.10000E+01 0.0000 66 Mg(HCO3)+ 0.10293E-14 -14.9875 0.86126E-15 -15.0649 0.83678E+00 -0.0774 67 MgCl+ 0.24387E-14 -14.6128 0.20406E-14 -14.6902 0.83678E+00 -0.0774 68 MgF+ 0.98508E-16 -16.0065 0.82429E-16 -16.0839 0.83678E+00 -0.0774 69 MgOH+ 0.68717E-10 -10.1629 0.57501E-10 -10.2403 0.83678E+00 -0.0774 71 MnF+ 0.27083E-16 -16.5673 0.22663E-16 -16.6447 0.83678E+00 -0.0774 72 MnO,aq 0.17931E-08 -8.7464 0.17931E-08 -8.7464 0.10000E+01 0.0000 73 MnOH+ 0.46514E-09 -9.3324 0.38922E-09 -9.4098 0.83678E+00 -0.0774 74 MnO2-2 0.20780E-10 -10.6824 0.10767E-10 -10.9679 0.51816E+00 -0.2855 75 HMnO2- 0.20998E-09 -9.6778 0.17537E-09 -9.7561 0.83518E+00 -0.0782 78 MnCl+ 0.90383E-14 -14.0439 0.75631E-14 -14.1213 0.83678E+00 -0.0774 79 MnSO4,aq 0.15114E-19 -19.8206 0.15114E-19 -19.8206 0.10000E+01 0.0000 80 NaCl,aq 0.70544E-06 -6.1515 0.70544E-06 -6.1515 0.10000E+01 0.0000 81 NaF,aq 0.54594E-09 -9.2629 0.54594E-09 -9.2629 0.10000E+01 0.0000 82 NaOH,aq 0.95847E-04 -4.0184 0.95847E-04 -4.0184 0.10000E+01 0.0000 84 OH- 0.93226E-02 -2.0305 0.77720E-02 -2.1095 0.83367E+00 -0.0790 89 HPO3-2 0.86296E-15 -15.0640 0.44715E-15 -15.3495 0.51816E+00 -0.2855 91 H2PO3- 0.79814E-19 -19.0979 0.66660E-19 -19.1761 0.83518E+00 -0.0782 92 H3PO4,aq 0.90968E-18 -18.0411 0.90968E-18 -18.0411 0.10000E+01 0.0000 93 H2PO4- 0.38608E-10 -10.4133 0.32276E-10 -10.4911 0.83597E+00 -0.0778 94 PO4-3 0.10647E-08 -8.9728 0.25830E-09 -9.5879 0.24261E+00 -0.6151 98 HP2O7-3 0.94884E-18 -18.0228 0.21939E-18 -18.6588 0.23122E+00 -0.6360 99 P2O7-4 0.91462E-17 -17.0388 0.70502E-18 -18.1518 0.77084E-01 -1.1130 100 H2S,aq 0.61456E-08 -8.2114 0.61243E-08 -8.2129 0.99654E+00 -0.0015 101 S2-2 0.49836E-14 -14.3025 0.25823E-14 -14.5880 0.51816E+00 -0.2855 107 SO3-2 0.82465E-17 -17.0837 0.43349E-17 -17.3630 0.52566E+00 -0.2793 108 HSO3- 0.24159E-19 -19.6169 0.20177E-19 -19.6951 0.83518E+00 -0.0782 109 HSO4- 0.46800E-18 -18.3298 0.39199E-18 -18.4067 0.83760E+00 -0.0770 Charge balance for all species = -.6133E-08 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.8847600E-10 -.2228412E-01 -.2242201E+02 0.0000 2 H2O 0.1000000E+01 0.5550487E+02 0.9981987E+06 0.0000 3 Cl- 0.1536845E-03 0.1543903E-03 0.5464084E+01 6.2372 4 SO4-- 0.1053691E-10 -.1599569E-04 -.1533901E+01 8.9957 5 HCO3- 0.3642213E-05 0.2501958E-04 0.1523971E+01 4.6126 6 HS- 0.3191106E-04 0.4791291E-04 0.1581821E+01 5.5546 7 Al+++ 0.9717683E-29 0.5287068E-05 0.1424051E+00 0.7375 8 H4SiO4 0.6972626E-03 0.1353248E-01 0.1298419E+04 -3.1566 9 Ca++ 0.1266414E-06 0.2199404E-06 0.8799449E-02 13.0723 10 Mg++ 0.2112514E-10 0.9318263E-10 0.2261518E-05 9.2925 11 Fe++ 0.4793064E-13 0.2982915E-07 0.1662973E-02 6.6488 12 K+ 0.1565086E-03 0.1572611E-03 0.6138536E+01 6.2458 13 Na+ 0.1986046E-01 0.2230608E-01 0.5119210E+03 8.3485 14 Mn++ 0.1861318E-10 0.2507569E-08 0.1375214E-03 9.2384 15 F- 0.1687082E-06 0.1692544E-06 0.3209905E-02 3.2768 16 HPO4-- 0.4531717E-07 0.4642044E-07 0.4447644E-02 12.6293 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.2001254E-01 -.2001240E-01 -.1398334E-06 0.0000000E+00 2 H2O 0.4984652E+02 0.4984652E+02 -.1070066E-06 0.0000000E+00 3 Cl- 0.1386512E-03 0.1386512E-03 0.0000000E+00 0.0000000E+00 4 SO4-- -.1436431E-04 -.1436504E-04 0.7255005E-09 0.0000000E+00 5 HCO3- 0.2246900E-04 0.2246900E-04 0.0000000E+00 0.0000000E+00 6 HS- 0.4302778E-04 0.4302851E-04 -.7255005E-09 0.0000000E+00 7 Al+++ 0.4775352E-05 0.4748087E-05 0.2726519E-07 0.0000000E+00 8 H4SiO4 0.1215302E-01 0.1215293E-01 0.8864299E-07 0.0000000E+00 9 Ca++ 0.2080835E-06 0.1975189E-06 0.1056458E-07 0.0000000E+00 10 Mg++ 0.8368328E-10 0.8368328E-10 0.0000000E+00 0.0000000E+00 11 Fe++ 0.3259227E-07 0.2678827E-07 0.5804004E-08 0.0000000E+00 12 K+ 0.1412294E-03 0.1412294E-03 0.0000000E+00 0.0000000E+00 13 Na+ 0.2003215E-01 0.2003212E-01 0.2602614E-07 0.0000000E+00 14 Mn++ 0.2251939E-08 0.2251939E-08 0.0000000E+00 0.0000000E+00 15 F- 0.1520000E-06 0.1520000E-06 0.0000000E+00 0.0000000E+00 16 HPO4-- 0.4168819E-07 0.4168819E-07 0.0000000E+00 0.0000000E+00 Chg. balance for solid moles: -.1323E-22 Mass of aqueous solution: 0.899620E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 0.0001300 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 0.2603E-07 -7.585 0.6825E-05 -5.166 79.56 0.2620E-05 andradite 0.2902E-08 -8.537 0.1475E-05 -5.831 17.19 0.3831E-06 grossular 0.6195E-09 -9.208 0.2791E-06 -6.554 3.253 0.7765E-07 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8241E+00 0.8241E+00 1.0000 -0.084 grossular 0.1759E+00 0.1759E+00 1.0000 -0.755 Solid products produced: Mass = 0.000009 g Volume = 0.000003 cm3 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.0001300 moles log = -3.8861 Original solution: 1000.0103000 g Original solution / Rock added: 7692386.92 (Water/Rock Ratio), log = 6.8861 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0497 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9724E+00 0.9856 0.1006E+01 0.1021E+01 CO2,gas 0.4899E-07 1.0069 0.5177E-07 0.5142E-07 CH4,gas 0.1997E-01 1.0123 0.2122E-01 0.2096E-01 H2,gas 0.7621E-02 1.0006 0.8004E-02 0.8000E-02 H2S,gas 0.1610E-06 0.9959 0.1684E-06 0.1690E-06 S2,gas 0.1582E-28 1.0000 0.1661E-28 0.1661E-28 CO,gas 0.1052E-12 1.0000 0.1104E-12 0.1104E-12 SO3,gas 0.1089E-46 1.0000 0.1143E-46 0.1143E-46 SO2,gas 0.3392E-26 1.0000 0.3560E-26 0.3560E-26 HF,gas 0.1674E-15 1.0000 0.1757E-15 0.1757E-15 HCl,gas 0.2939E-17 1.0000 0.3085E-17 0.3085E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 17 albite -0.38 -0.38 0.00 0.000 -0.94784E-12 23 andradite 39.01 39.01 0.00 0.000 0.12132E-10 24 grossular 32.73 32.73 0.00 0.000 -0.12132E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -15.64 -8.98 -2.995 0.15341E+05 -7.286 3 CH4,gas 4.54 1.17 -3.37 -0.843 0.57580E+04 -1.673 4 H2,gas 8.00 4.20 -3.80 -2.169 0.64810E+04 -2.097 5 H2S,gas -6.23 -14.70 -8.47 -4.236 0.14467E+05 -6.774 6 S2,gas -7.34 -37.81 -30.48 -4.689 0.52042E+05 -28.780 7 CO,gas 3.21 -11.44 -14.66 -4.509 0.25024E+05 -12.957 8 SO3,gas 17.12 -31.52 -48.64 -12.160 0.83053E+05 -46.942 9 SO2,gas 0.83 -27.32 -28.15 -7.506 0.48061E+05 -26.449 10 HF,gas 0.47 -16.98 -17.45 -8.727 0.29803E+05 -15.755 11 HCl,gas 5.19 -14.02 -19.21 -9.605 0.32800E+05 -17.511 12 acmite 7.71 6.58 -1.13 -0.117 0.19255E+04 16 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 20 spessartine 24.46 19.72 -4.74 -0.237 0.80883E+04 21 analcite 3.32 2.77 -0.55 -0.061 0.93762E+03 27 annite 20.12 17.46 -2.66 -0.148 0.45477E+04 28 phlogopite 27.06 25.39 -1.67 -0.093 0.28574E+04 30 anorthite 12.71 8.23 -4.48 -0.344 0.76431E+04 33 apatite-OH -18.15 -18.30 -0.14 -0.011 0.24322E+03 34 apatite-F -34.30 -35.28 -0.98 -0.081 0.16660E+04 38 aragonite 0.97 -2.57 -3.54 -1.180 0.60431E+04 39 brucite 12.57 9.29 -3.28 -0.655 0.55937E+04 40 calcite 0.81 -2.57 -3.38 -1.128 0.57789E+04 41 carnegieite-low 9.02 5.93 -3.09 -0.442 0.52828E+04 42 carnegieite-high 10.09 5.93 -4.16 -0.595 0.71098E+04 43 carpholite-Mg 8.58 4.45 -4.13 -0.275 0.70481E+04 44 carpholite-Fe 6.71 1.81 -4.90 -0.327 0.83701E+04 45 celadonite 5.34 3.65 -1.69 -0.100 0.28893E+04 46 celadonite-Fe 3.88 1.01 -2.87 -0.169 0.49018E+04 47 chrysotile 23.89 21.56 -2.33 -0.194 0.39749E+04 49 clinochlore 39.07 38.47 -0.60 -0.019 0.10273E+04 50 daphnite 28.97 25.25 -3.72 -0.116 0.63448E+04 52 chlorite-Al-free 47.17 43.13 -4.04 -0.169 0.69050E+04 54 chloritoid-Fe 9.17 4.97 -4.21 -0.280 0.71824E+04 55 chloritoid-Mn 11.40 7.56 -3.84 -0.256 0.65641E+04 57 coesite -2.38 -3.16 -0.78 -0.260 0.13328E+04 64 cristobalite -2.56 -3.16 -0.60 -0.199 0.10181E+04 66 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71234E+04 68 diaspore 2.87 0.74 -2.14 -0.356 0.36475E+04 69 diamond -3.10 -7.24 -4.13 -1.181 0.70593E+04 70 diopside 16.18 16.05 -0.13 -0.013 0.22147E+03 71 hedenbergite 14.21 13.41 -0.80 -0.080 0.13666E+04 74 enstatite 17.26 12.27 -4.99 -0.499 0.85254E+04 76 clinoenstatite 17.17 12.27 -4.89 -0.489 0.83570E+04 78 epidote 24.67 22.70 -1.97 -0.096 0.33695E+04 79 clinozoisite 22.81 18.89 -3.92 -0.178 0.66912E+04 80 epidote-Fe 29.84 26.51 -3.33 -0.173 0.56943E+04 81 fayalite 14.05 10.14 -3.90 -0.558 0.66671E+04 82 ferrosilite 11.15 6.98 -4.16 -0.416 0.71116E+04 86 gibbsite 4.08 0.74 -3.34 -0.477 0.57061E+04 87 glaucophane 22.97 20.80 -2.18 -0.059 0.37191E+04 88 glaucophane-Fe 17.28 12.87 -4.41 -0.119 0.75304E+04 89 graphite -3.55 -7.24 -3.69 -1.054 0.63016E+04 90 greenalite 16.14 13.63 -2.51 -0.209 0.42793E+04 93 hematite 12.57 9.09 -3.47 -0.421 0.59294E+04 94 heulandite -5.83 -7.55 -1.72 -0.078 0.29398E+04 98 jadeite 4.22 2.77 -1.44 -0.144 0.24631E+04 100 kalsilite 7.58 3.83 -3.76 -0.537 0.64153E+04 101 kaolinite -1.33 -4.84 -3.51 -0.319 0.59855E+04 104 laumontite 2.88 1.92 -0.96 -0.064 0.16435E+04 105 lawsonite 9.62 8.23 -1.38 -0.092 0.23597E+04 106 leucite 4.12 0.67 -3.45 -0.345 0.58887E+04 108 lizardite 23.24 21.56 -1.68 -0.140 0.28676E+04 110 magnetite 20.09 15.74 -4.35 -0.355 0.74190E+04 111 minnesotaite 10.39 7.32 -3.07 -0.180 0.52386E+04 115 manganosite 14.06 9.24 -4.82 -1.205 0.82295E+04 119 microcline -2.49 -2.49 0.00 0.000 0.11063E-01 123 muscovite 2.58 -1.01 -3.59 -0.211 0.61366E+04 124 paragonite 4.24 1.09 -3.15 -0.185 0.53757E+04 125 nepheline 8.34 5.93 -2.41 -0.344 0.41152E+04 131 periclase-Fe 11.63 6.65 -4.98 -1.244 0.84994E+04 137 phlogopite-Na 29.65 27.49 -2.15 -0.120 0.36762E+04 139 prehnite 19.37 18.15 -1.22 -0.072 0.20867E+04 140 prehnite-Fe 22.50 21.96 -0.54 -0.032 0.91997E+03 141 pumpellyite-Fe 46.27 43.69 -2.58 -0.057 0.44114E+04 142 pumpellyite-Mg 48.99 46.33 -2.67 -0.059 0.45509E+04 146 pyrrhotite -4.26 -8.05 -3.79 -1.265 0.64779E+04 147 pyrrhotiteFe0.875 -6.02 -9.41 -3.39 -1.247 0.57877E+04 148 pyroxmangite 7.40 6.08 -1.32 -0.263 0.22485E+04 149 pyrophyllite -6.18 -11.15 -4.98 -0.311 0.84958E+04 150 quartz -2.99 -3.16 -0.17 -0.056 0.28544E+03 155 rhodonite 7.45 6.08 -1.36 -0.273 0.23288E+04 156 sanidine -1.28 -2.49 -1.21 -0.093 0.20678E+04 166 stilbite -7.52 -7.55 -0.03 -0.001 0.45938E+02 167 stilpnomelane-Fe 13.02 12.59 -0.43 -0.013 0.73038E+03 168 stilpnomelane-Mg 27.44 25.81 -1.63 -0.049 0.27894E+04 174 talc 16.49 15.25 -1.24 -0.073 0.21170E+04 177 tephroite 18.09 15.32 -2.77 -0.395 0.47222E+04 181 tridymite -2.63 -3.16 -0.53 -0.177 0.90541E+03 182 tremolite 47.87 47.35 -0.51 -0.014 0.87889E+03 183 ferroactinolite 38.45 34.14 -4.32 -0.117 0.73701E+04 184 troilite-low -4.41 -8.05 -3.64 -1.214 0.62207E+04 190 wairakite 3.95 1.92 -2.03 -0.119 0.34655E+04 191 walstromite 11.51 9.92 -1.59 -0.319 0.27209E+04 192 wollastonite 10.46 9.92 -0.55 -0.109 0.93132E+03 193 pseudo-wollastonite 11.00 9.92 -1.08 -0.217 0.18511E+04 194 zoisite 22.85 18.89 -3.96 -0.180 0.67653E+04 195 akaganeite 7.75 4.55 -3.21 -0.694 0.54772E+04 202 chalcedony -2.80 -3.16 -0.35 -0.118 0.60473E+03 204 montmorillonite-Ca -2.29 -6.17 -3.88 -0.240 0.66261E+04 205 montmorillonite-K -2.24 -6.27 -4.03 -0.247 0.68819E+04 206 montmorillonite-Mg -2.48 -6.80 -4.32 -0.267 0.73680E+04 207 montmorillonite-Na -2.04 -5.57 -3.54 -0.217 0.60368E+04 208 nontronite-Ca 3.21 -0.09 -3.31 -0.214 0.56439E+04 209 nontronite-H 2.53 -2.25 -4.78 -0.320 0.81626E+04 210 nontronite-K 3.34 -0.19 -3.53 -0.226 0.60229E+04 211 nontronite-Mg 3.07 -0.71 -3.79 -0.246 0.64699E+04 212 nontronite-Na 3.52 0.51 -3.01 -0.193 0.51438E+04 228 tobermorite 9.82 7.73 -2.09 -0.570 0.35693E+04 234 alabandite -0.98 -5.46 -4.49 -1.496 0.76609E+04 237 boehmite 4.41 0.74 -3.67 -0.611 0.62645E+04 239 ferrous-oxide 9.81 6.65 -3.16 -0.791 0.54003E+04 245 silica-amorphous -2.09 -3.16 -1.07 -0.355 0.18189E+04 247 an20ab80 2.02 1.34 -0.68 -0.052 0.11578E+04 248 an25ab75 2.65 1.77 -0.88 -0.067 0.14942E+04 249 an30ab70 3.28 2.20 -1.08 -0.083 0.18402E+04 250 tr.625ac.25prg.125 45.16 45.00 -0.17 -0.005 0.28542E+03 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 0.0000100 MOLES Current total amount of reactant added: 0.0001300 MOLES New total amount of reactant added: 0.0001400 MOLES Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.5508E-08 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 6 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 0.0001400 Water: Moles liquid = 0.4985E+02 kg liquid = 0.8981E+00 Moles total = 0.4985E+02 kg total = 0.8980E+00 Activity = 1.0000 Stoichiometric ionic strength = .1133914E-01 Osmotic coef. = 0.9689 True ionic strength = .2002498E-01 Chg. balance for total moles = -.5508E-08 Max. difference allowed = 0.1387E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.88491E-10 -10.0531 0.74353E-10 -10.1287 0.84023E+00 -0.0756 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.15375E-03 -3.8132 0.12841E-03 -3.8914 0.83518E+00 -0.0782 4 SO4-- 0.11481E-10 -10.9400 0.59617E-11 -11.2246 0.51926E+00 -0.2846 5 HCO3- 0.39287E-05 -5.4058 0.32860E-05 -5.4833 0.83640E+00 -0.0776 6 HS- 0.32182E-04 -4.4924 0.26881E-04 -4.5705 0.83530E+00 -0.0782 7 Al+++ 0.97198E-29 -29.0123 0.22451E-29 -29.6488 0.23099E+00 -0.6364 8 H4SiO4 0.69737E-03 -3.1565 0.69737E-03 -3.1565 0.10000E+01 0.0000 9 Ca++ 0.12636E-06 -6.8984 0.65132E-07 -7.1862 0.51545E+00 -0.2878 10 Mg++ 0.21126E-10 -10.6752 0.10839E-10 -10.9650 0.51309E+00 -0.2898 11 Fe++ 0.47698E-13 -13.3215 0.24500E-13 -13.6108 0.51365E+00 -0.2893 12 K+ 0.15651E-03 -3.8055 0.13094E-03 -3.8829 0.83660E+00 -0.0775 13 Na+ 0.19860E-01 -1.7020 0.16584E-01 -1.7803 0.83503E+00 -0.0783 14 Mn++ 0.18619E-10 -10.7300 0.95718E-11 -11.0190 0.51408E+00 -0.2890 15 F- 0.17315E-06 -6.7616 0.14431E-06 -6.8407 0.83346E+00 -0.0791 16 HPO4-- 0.45317E-07 -7.3437 0.23535E-07 -7.6283 0.51934E+00 -0.2846 18 HSiO3- 0.10486E-01 -1.9794 0.87577E-02 -2.0576 0.83518E+00 -0.0782 19 Ca(HSiO3)+ 0.15524E-07 -7.8090 0.12990E-07 -7.8864 0.83678E+00 -0.0774 20 Mg(HSiO3)+ 0.32153E-11 -11.4928 0.26905E-11 -11.5702 0.83678E+00 -0.0774 21 NaHSiO3,aq 0.23490E-02 -2.6291 0.23490E-02 -2.6291 0.10000E+01 0.0000 22 AlO+ 0.66025E-16 -16.1803 0.55248E-16 -16.2577 0.83678E+00 -0.0774 24 HAlO2,aq 0.14798E-09 -9.8298 0.14798E-09 -9.8298 0.10000E+01 0.0000 25 AlO2- 0.52844E-05 -5.2770 0.44055E-05 -5.3560 0.83367E+00 -0.0790 26 CH4,aq 0.14442E-04 -4.8404 0.14393E-04 -4.8419 0.99654E+00 -0.0015 27 C2H6,aq 0.59427E-14 -14.2260 0.59222E-14 -14.2275 0.99654E+00 -0.0015 31 CO,aq 0.78421E-16 -16.1056 0.78421E-16 -16.1056 0.10000E+01 0.0000 32 CO2,aq 0.52387E-09 -9.2808 0.52206E-09 -9.2823 0.99654E+00 -0.0015 33 CO3-2 0.74498E-05 -5.1279 0.38602E-05 -5.4134 0.51816E+00 -0.2855 34 CaCO3,aq 0.31525E-08 -8.5013 0.31525E-08 -8.5013 0.10000E+01 0.0000 35 Ca(HCO3)+ 0.65287E-11 -11.1852 0.54631E-11 -11.2626 0.83678E+00 -0.0774 36 CaCl+ 0.16175E-10 -10.7912 0.13535E-10 -10.8685 0.83678E+00 -0.0774 37 CaCl2,aq 0.41291E-15 -15.3841 0.41291E-15 -15.3841 0.10000E+01 0.0000 38 CaF+ 0.16400E-12 -12.7852 0.13723E-12 -12.8625 0.83678E+00 -0.0774 39 CaOH+ 0.74608E-07 -7.1272 0.62430E-07 -7.2046 0.83678E+00 -0.0774 40 CaSO4,aq 0.12330E-15 -15.9090 0.12330E-15 -15.9090 0.10000E+01 0.0000 41 HCl,aq 0.17496E-14 -14.7571 0.17496E-14 -14.7571 0.10000E+01 0.0000 45 HF,aq 0.73455E-13 -13.1340 0.73455E-13 -13.1340 0.10000E+01 0.0000 48 FeCl+ 0.59509E-17 -17.2254 0.49796E-17 -17.3028 0.83678E+00 -0.0774 51 FeF+ 0.21592E-18 -18.6657 0.18068E-18 -18.7431 0.83678E+00 -0.0774 53 FeO,aq 0.17224E-09 -9.7639 0.17224E-09 -9.7639 0.10000E+01 0.0000 54 FeOH+ 0.12818E-10 -10.8922 0.10726E-10 -10.9696 0.83678E+00 -0.0774 55 HFeO2- 0.29021E-07 -7.5373 0.24238E-07 -7.6155 0.83518E+00 -0.0782 56 FeO+ 0.12503E-16 -16.9030 0.10462E-16 -16.9804 0.83678E+00 -0.0774 58 FeO2- 0.46364E-09 -9.3338 0.38723E-09 -9.4120 0.83518E+00 -0.0782 59 HFeO2,aq 0.36619E-11 -11.4363 0.36619E-11 -11.4363 0.10000E+01 0.0000 60 H2,aq 0.60004E-05 -5.2218 0.59797E-05 -5.2233 0.99654E+00 -0.0015 61 KCl,aq 0.30473E-09 -9.5161 0.30473E-09 -9.5161 0.10000E+01 0.0000 63 KOH,aq 0.75204E-06 -6.1238 0.75204E-06 -6.1238 0.10000E+01 0.0000 64 KSO4- 0.14503E-13 -13.8385 0.12113E-13 -13.9168 0.83518E+00 -0.0782 65 MgCO3,aq 0.13151E-12 -12.8810 0.13151E-12 -12.8810 0.10000E+01 0.0000 66 Mg(HCO3)+ 0.11102E-14 -14.9546 0.92902E-15 -15.0320 0.83678E+00 -0.0774 67 MgCl+ 0.24398E-14 -14.6127 0.20415E-14 -14.6900 0.83678E+00 -0.0774 68 MgF+ 0.10110E-15 -15.9952 0.84600E-16 -16.0726 0.83678E+00 -0.0774 69 MgOH+ 0.68706E-10 -10.1630 0.57492E-10 -10.2404 0.83678E+00 -0.0774 71 MnF+ 0.27805E-16 -16.5559 0.23267E-16 -16.6333 0.83678E+00 -0.0774 72 MnO,aq 0.17930E-08 -8.7464 0.17930E-08 -8.7464 0.10000E+01 0.0000 73 MnOH+ 0.46521E-09 -9.3324 0.38928E-09 -9.4097 0.83678E+00 -0.0774 74 MnO2-2 0.20773E-10 -10.6825 0.10764E-10 -10.9680 0.51816E+00 -0.2855 75 HMnO2- 0.20994E-09 -9.6779 0.17533E-09 -9.7561 0.83518E+00 -0.0782 78 MnCl+ 0.90451E-14 -14.0436 0.75688E-14 -14.1210 0.83678E+00 -0.0774 79 MnSO4,aq 0.16474E-19 -19.7832 0.16474E-19 -19.7832 0.10000E+01 0.0000 80 NaCl,aq 0.70574E-06 -6.1514 0.70574E-06 -6.1514 0.10000E+01 0.0000 81 NaF,aq 0.56031E-09 -9.2516 0.56031E-09 -9.2516 0.10000E+01 0.0000 82 NaOH,aq 0.95831E-04 -4.0185 0.95831E-04 -4.0185 0.10000E+01 0.0000 84 OH- 0.93210E-02 -2.0305 0.77706E-02 -2.1095 0.83367E+00 -0.0790 89 HPO3-2 0.84639E-15 -15.0724 0.43857E-15 -15.3580 0.51816E+00 -0.2855 91 H2PO3- 0.78295E-19 -19.1063 0.65391E-19 -19.1845 0.83518E+00 -0.0782 92 H3PO4,aq 0.90999E-18 -18.0410 0.90999E-18 -18.0410 0.10000E+01 0.0000 93 H2PO4- 0.38615E-10 -10.4132 0.32281E-10 -10.4911 0.83597E+00 -0.0778 94 PO4-3 0.10645E-08 -8.9729 0.25825E-09 -9.5880 0.24261E+00 -0.6151 98 HP2O7-3 0.94901E-18 -18.0227 0.21943E-18 -18.6587 0.23122E+00 -0.6360 99 P2O7-4 0.91464E-17 -17.0387 0.70502E-18 -18.1518 0.77081E-01 -1.1131 100 H2S,aq 0.61987E-08 -8.2077 0.61773E-08 -8.2092 0.99654E+00 -0.0015 101 S2-2 0.51676E-14 -14.2867 0.26777E-14 -14.5722 0.51816E+00 -0.2855 107 SO3-2 0.88129E-17 -17.0549 0.46326E-17 -17.3342 0.52566E+00 -0.2793 108 HSO3- 0.25823E-19 -19.5880 0.21567E-19 -19.6662 0.83518E+00 -0.0782 109 HSO4- 0.51001E-18 -18.2924 0.42719E-18 -18.3694 0.83760E+00 -0.0770 Charge balance for all species = -.6133E-08 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.8849130E-10 -.2228291E-01 -.2242079E+02 0.0000 2 H2O 0.1000000E+01 0.5550486E+02 0.9981987E+06 0.0000 3 Cl- 0.1537499E-03 0.1544559E-03 0.5466408E+01 6.2373 4 SO4-- 0.1148100E-10 -.1594254E-04 -.1528803E+01 9.0328 5 HCO3- 0.3928701E-05 0.2582465E-04 0.1573009E+01 4.6454 6 HS- 0.3218158E-04 0.4813033E-04 0.1588999E+01 5.5582 7 Al+++ 0.9719837E-29 0.5284539E-05 0.1423370E+00 0.7373 8 H4SiO4 0.6973743E-03 0.1353247E-01 0.1298418E+04 -3.1565 9 Ca++ 0.1263593E-06 0.2196668E-06 0.8788502E-02 13.0712 10 Mg++ 0.2112572E-10 0.9318261E-10 0.2261518E-05 9.2924 11 Fe++ 0.4769768E-13 0.2967330E-07 0.1654284E-02 6.6466 12 K+ 0.1565087E-03 0.1572611E-03 0.6138535E+01 6.2458 13 Na+ 0.1986050E-01 0.2230607E-01 0.5119208E+03 8.3484 14 Mn++ 0.1861936E-10 0.2507568E-08 0.1375213E-03 9.2384 15 F- 0.1731478E-06 0.1737084E-06 0.3294376E-02 3.2880 16 HPO4-- 0.4531733E-07 0.4642044E-07 0.4447643E-02 12.6291 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.2001147E-01 -.2001132E-01 -.1496432E-06 0.0000000E+00 2 H2O 0.4984652E+02 0.4984652E+02 -.1160611E-06 0.0000000E+00 3 Cl- 0.1387102E-03 0.1387102E-03 0.0000000E+00 0.0000000E+00 4 SO4-- -.1431656E-04 -.1431730E-04 0.7429954E-09 0.0000000E+00 5 HCO3- 0.2319200E-04 0.2319200E-04 0.0000000E+00 0.0000000E+00 6 HS- 0.4322303E-04 0.4322377E-04 -.7429954E-09 0.0000000E+00 7 Al+++ 0.4775352E-05 0.4745817E-05 0.2953516E-07 0.0000000E+00 8 H4SiO4 0.1215302E-01 0.1215292E-01 0.9562709E-07 0.0000000E+00 9 Ca++ 0.2080835E-06 0.1972732E-06 0.1081026E-07 0.0000000E+00 10 Mg++ 0.8368328E-10 0.8368328E-10 0.0000000E+00 0.0000000E+00 11 Fe++ 0.3259227E-07 0.2664831E-07 0.5943963E-08 0.0000000E+00 12 K+ 0.1412294E-03 0.1412294E-03 0.0000000E+00 0.0000000E+00 13 Na+ 0.2003215E-01 0.2003212E-01 0.2827228E-07 0.0000000E+00 14 Mn++ 0.2251939E-08 0.2251939E-08 0.0000000E+00 0.0000000E+00 15 F- 0.1560000E-06 0.1560000E-06 0.0000000E+00 0.0000000E+00 16 HPO4-- 0.4168819E-07 0.4168819E-07 0.0000000E+00 0.0000000E+00 Chg. balance for solid moles: -.9926E-23 Mass of aqueous solution: 0.899621E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 0.0001400 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 0.2827E-07 -7.549 0.7414E-05 -5.130 80.51 0.2846E-05 andradite 0.2972E-08 -8.527 0.1510E-05 -5.821 16.40 0.3924E-06 grossular 0.6314E-09 -9.200 0.2844E-06 -6.546 3.089 0.7914E-07 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8248E+00 0.8248E+00 1.0000 -0.084 grossular 0.1752E+00 0.1752E+00 1.0000 -0.756 Solid products produced: Mass = 0.000009 g Volume = 0.000003 cm3 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.0001400 moles log = -3.8539 Original solution: 1000.0103000 g Original solution / Rock added: 7142930.71 (Water/Rock Ratio), log = 6.8539 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0495 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9726E+00 0.9856 0.1006E+01 0.1021E+01 CO2,gas 0.5286E-07 1.0069 0.5585E-07 0.5547E-07 CH4,gas 0.1994E-01 1.0123 0.2118E-01 0.2093E-01 H2,gas 0.7476E-02 1.0006 0.7851E-02 0.7846E-02 H2S,gas 0.1625E-06 0.9959 0.1698E-06 0.1705E-06 S2,gas 0.1673E-28 1.0000 0.1756E-28 0.1756E-28 CO,gas 0.1114E-12 1.0000 0.1169E-12 0.1169E-12 SO3,gas 0.1187E-46 1.0000 0.1246E-46 0.1246E-46 SO2,gas 0.3627E-26 1.0000 0.3806E-26 0.3806E-26 HF,gas 0.1719E-15 1.0000 0.1804E-15 0.1804E-15 HCl,gas 0.2942E-17 1.0000 0.3087E-17 0.3087E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 17 albite -0.38 -0.38 0.00 0.000 -0.13080E-10 23 andradite 39.01 39.01 0.00 0.000 0.00000E+00 24 grossular 32.73 32.73 0.00 0.000 -0.24265E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -15.61 -8.95 -2.984 0.15285E+05 -7.253 3 CH4,gas 4.54 1.17 -3.37 -0.843 0.57592E+04 -1.674 4 H2,gas 8.00 4.20 -3.80 -2.174 0.64953E+04 -2.105 5 H2S,gas -6.23 -14.70 -8.47 -4.235 0.14461E+05 -6.770 6 S2,gas -7.34 -37.79 -30.45 -4.685 0.52000E+05 -28.755 7 CO,gas 3.21 -11.42 -14.63 -4.502 0.24983E+05 -12.932 8 SO3,gas 17.12 -31.48 -48.60 -12.151 0.82989E+05 -46.904 9 SO2,gas 0.83 -27.29 -28.12 -7.498 0.48012E+05 -26.420 10 HF,gas 0.47 -16.97 -17.44 -8.721 0.29783E+05 -15.744 11 HCl,gas 5.19 -14.02 -19.21 -9.605 0.32800E+05 -17.510 12 acmite 7.71 6.58 -1.13 -0.117 0.19221E+04 16 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 20 spessartine 24.46 19.72 -4.74 -0.237 0.80884E+04 21 analcite 3.32 2.77 -0.55 -0.061 0.93773E+03 27 annite 20.12 17.45 -2.67 -0.148 0.45593E+04 28 phlogopite 27.06 25.39 -1.67 -0.093 0.28581E+04 30 anorthite 12.71 8.23 -4.48 -0.344 0.76452E+04 33 apatite-OH -18.15 -18.30 -0.15 -0.011 0.25204E+03 34 apatite-F -34.30 -35.27 -0.97 -0.081 0.16554E+04 38 aragonite 0.97 -2.54 -3.51 -1.169 0.59887E+04 39 brucite 12.57 9.29 -3.28 -0.655 0.55940E+04 40 calcite 0.81 -2.54 -3.35 -1.118 0.57245E+04 41 carnegieite-low 9.02 5.93 -3.09 -0.442 0.52831E+04 42 carnegieite-high 10.09 5.93 -4.16 -0.595 0.71101E+04 43 carpholite-Mg 8.58 4.45 -4.13 -0.275 0.70486E+04 44 carpholite-Fe 6.71 1.81 -4.90 -0.327 0.83742E+04 45 celadonite 5.34 3.65 -1.69 -0.100 0.28894E+04 46 celadonite-Fe 3.88 1.00 -2.87 -0.169 0.49056E+04 47 chrysotile 23.89 21.56 -2.33 -0.194 0.39754E+04 49 clinochlore 39.07 38.47 -0.60 -0.019 0.10286E+04 50 daphnite 28.97 25.24 -3.73 -0.116 0.63643E+04 52 chlorite-Al-free 47.17 43.13 -4.04 -0.169 0.69060E+04 54 chloritoid-Fe 9.17 4.96 -4.21 -0.281 0.71866E+04 55 chloritoid-Mn 11.40 7.56 -3.84 -0.256 0.65644E+04 57 coesite -2.38 -3.16 -0.78 -0.260 0.13326E+04 64 cristobalite -2.56 -3.16 -0.60 -0.199 0.10180E+04 66 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71234E+04 68 diaspore 2.87 0.74 -2.14 -0.356 0.36478E+04 69 diamond -3.10 -7.22 -4.12 -1.177 0.70318E+04 70 diopside 16.18 16.05 -0.13 -0.013 0.22339E+03 71 hedenbergite 14.21 13.40 -0.80 -0.080 0.13721E+04 74 enstatite 17.26 12.27 -4.99 -0.499 0.85257E+04 76 clinoenstatite 17.17 12.27 -4.89 -0.489 0.83573E+04 78 epidote 24.67 22.70 -1.97 -0.096 0.33701E+04 79 clinozoisite 22.81 18.88 -3.92 -0.178 0.66954E+04 80 epidote-Fe 29.84 26.51 -3.33 -0.173 0.56914E+04 81 fayalite 14.05 10.14 -3.91 -0.558 0.66747E+04 82 ferrosilite 11.15 6.98 -4.17 -0.417 0.71191E+04 86 gibbsite 4.08 0.74 -3.34 -0.477 0.57063E+04 87 glaucophane 22.97 20.80 -2.18 -0.059 0.37195E+04 88 glaucophane-Fe 17.28 12.86 -4.42 -0.119 0.75418E+04 89 graphite -3.55 -7.22 -3.67 -1.050 0.62741E+04 90 greenalite 16.14 13.63 -2.51 -0.209 0.42907E+04 93 hematite 12.57 9.10 -3.47 -0.420 0.59228E+04 94 heulandite -5.83 -7.55 -1.72 -0.078 0.29413E+04 98 jadeite 4.22 2.77 -1.44 -0.144 0.24632E+04 100 kalsilite 7.58 3.83 -3.76 -0.537 0.64156E+04 101 kaolinite -1.33 -4.84 -3.51 -0.319 0.59857E+04 104 laumontite 2.88 1.92 -0.96 -0.064 0.16454E+04 105 lawsonite 9.62 8.23 -1.38 -0.092 0.23619E+04 106 leucite 4.12 0.67 -3.45 -0.345 0.58888E+04 108 lizardite 23.24 21.56 -1.68 -0.140 0.28680E+04 110 magnetite 20.09 15.74 -4.34 -0.355 0.74162E+04 111 minnesotaite 10.39 7.31 -3.07 -0.181 0.52497E+04 115 manganosite 14.06 9.24 -4.82 -1.205 0.82295E+04 119 microcline -2.49 -2.49 0.00 0.000 0.11887E-01 123 muscovite 2.58 -1.01 -3.59 -0.211 0.61371E+04 124 paragonite 4.24 1.09 -3.15 -0.185 0.53762E+04 125 nepheline 8.34 5.93 -2.41 -0.344 0.41154E+04 131 periclase-Fe 11.63 6.65 -4.98 -1.245 0.85032E+04 137 phlogopite-Na 29.65 27.49 -2.15 -0.120 0.36769E+04 139 prehnite 19.37 18.15 -1.22 -0.072 0.20906E+04 140 prehnite-Fe 22.50 21.96 -0.54 -0.032 0.92036E+03 141 pumpellyite-Fe 46.27 43.68 -2.59 -0.058 0.44233E+04 142 pumpellyite-Mg 48.99 46.32 -2.67 -0.059 0.45593E+04 146 pyrrhotite -4.26 -8.05 -3.79 -1.264 0.64754E+04 147 pyrrhotiteFe0.875 -6.02 -9.40 -3.39 -1.246 0.57829E+04 148 pyroxmangite 7.40 6.08 -1.32 -0.263 0.22484E+04 149 pyrophyllite -6.18 -11.15 -4.98 -0.311 0.84958E+04 150 quartz -2.99 -3.16 -0.17 -0.056 0.28532E+03 155 rhodonite 7.45 6.08 -1.36 -0.273 0.23287E+04 156 sanidine -1.28 -2.49 -1.21 -0.093 0.20678E+04 166 stilbite -7.52 -7.55 -0.03 -0.001 0.47478E+02 167 stilpnomelane-Fe 13.02 12.58 -0.44 -0.013 0.74931E+03 168 stilpnomelane-Mg 27.44 25.81 -1.63 -0.049 0.27902E+04 174 talc 16.49 15.25 -1.24 -0.073 0.21173E+04 177 tephroite 18.09 15.32 -2.77 -0.395 0.47221E+04 181 tridymite -2.63 -3.16 -0.53 -0.177 0.90529E+03 182 tremolite 47.87 47.35 -0.52 -0.014 0.88296E+03 183 ferroactinolite 38.45 34.12 -4.33 -0.117 0.73924E+04 184 troilite-low -4.41 -8.05 -3.64 -1.214 0.62182E+04 190 wairakite 3.95 1.92 -2.03 -0.119 0.34674E+04 191 walstromite 11.51 9.91 -1.59 -0.319 0.27227E+04 192 wollastonite 10.46 9.91 -0.55 -0.109 0.93312E+03 193 pseudo-wollastonite 11.00 9.91 -1.09 -0.217 0.18529E+04 194 zoisite 22.85 18.88 -3.96 -0.180 0.67694E+04 195 akaganeite 7.75 4.55 -3.21 -0.693 0.54739E+04 202 chalcedony -2.80 -3.16 -0.35 -0.118 0.60461E+03 204 montmorillonite-Ca -2.29 -6.17 -3.88 -0.240 0.66264E+04 205 montmorillonite-K -2.24 -6.27 -4.03 -0.247 0.68819E+04 206 montmorillonite-Mg -2.48 -6.80 -4.32 -0.267 0.73680E+04 207 montmorillonite-Na -2.04 -5.57 -3.54 -0.217 0.60368E+04 208 nontronite-Ca 3.21 -0.09 -3.30 -0.214 0.56372E+04 209 nontronite-H 2.53 -2.24 -4.78 -0.320 0.81556E+04 210 nontronite-K 3.34 -0.18 -3.52 -0.226 0.60160E+04 211 nontronite-Mg 3.07 -0.71 -3.79 -0.246 0.64629E+04 212 nontronite-Na 3.52 0.51 -3.01 -0.193 0.51368E+04 228 tobermorite 9.82 7.73 -2.09 -0.571 0.35708E+04 234 alabandite -0.98 -5.46 -4.48 -1.494 0.76546E+04 237 boehmite 4.41 0.74 -3.67 -0.611 0.62647E+04 239 ferrous-oxide 9.81 6.65 -3.17 -0.791 0.54042E+04 245 silica-amorphous -2.09 -3.16 -1.07 -0.355 0.18188E+04 247 an20ab80 2.02 1.34 -0.68 -0.052 0.11582E+04 248 an25ab75 2.65 1.77 -0.88 -0.067 0.14947E+04 249 an30ab70 3.28 2.20 -1.08 -0.083 0.18408E+04 250 tr.625ac.25prg.125 45.16 44.99 -0.17 -0.005 0.29414E+03 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 0.0000100 MOLES Current total amount of reactant added: 0.0001400 MOLES New total amount of reactant added: 0.0001500 MOLES Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.5508E-08 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 6 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 0.0001500 Water: Moles liquid = 0.4985E+02 kg liquid = 0.8981E+00 Moles total = 0.4985E+02 kg total = 0.8980E+00 Activity = 1.0000 Stoichiometric ionic strength = .1133978E-01 Osmotic coef. = 0.9688 True ionic strength = .2002555E-01 Chg. balance for total moles = -.5508E-08 Max. difference allowed = 0.1388E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.88507E-10 -10.0530 0.74366E-10 -10.1286 0.84023E+00 -0.0756 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.15382E-03 -3.8130 0.12846E-03 -3.8912 0.83518E+00 -0.0782 4 SO4-- 0.12447E-10 -10.9049 0.64632E-11 -11.1896 0.51926E+00 -0.2846 5 HCO3- 0.42161E-05 -5.3751 0.35263E-05 -5.4527 0.83640E+00 -0.0776 6 HS- 0.32452E-04 -4.4888 0.27107E-04 -4.5669 0.83530E+00 -0.0782 7 Al+++ 0.97220E-29 -29.0122 0.22456E-29 -29.6487 0.23098E+00 -0.6364 8 H4SiO4 0.69749E-03 -3.1565 0.69749E-03 -3.1565 0.10000E+01 0.0000 9 Ca++ 0.12609E-06 -6.8993 0.64993E-07 -7.1871 0.51545E+00 -0.2878 10 Mg++ 0.21126E-10 -10.6752 0.10840E-10 -10.9650 0.51309E+00 -0.2898 11 Fe++ 0.47486E-13 -13.3234 0.24391E-13 -13.6128 0.51365E+00 -0.2893 12 K+ 0.15651E-03 -3.8055 0.13094E-03 -3.8829 0.83660E+00 -0.0775 13 Na+ 0.19861E-01 -1.7020 0.16584E-01 -1.7803 0.83503E+00 -0.0783 14 Mn++ 0.18626E-10 -10.7299 0.95749E-11 -11.0189 0.51408E+00 -0.2890 15 F- 0.17759E-06 -6.7506 0.14801E-06 -6.8297 0.83346E+00 -0.0791 16 HPO4-- 0.45317E-07 -7.3437 0.23535E-07 -7.6283 0.51933E+00 -0.2846 18 HSiO3- 0.10486E-01 -1.9794 0.87576E-02 -2.0576 0.83518E+00 -0.0782 19 Ca(HSiO3)+ 0.15491E-07 -7.8099 0.12963E-07 -7.8873 0.83678E+00 -0.0774 20 Mg(HSiO3)+ 0.32153E-11 -11.4928 0.26905E-11 -11.5702 0.83678E+00 -0.0774 21 NaHSiO3,aq 0.23490E-02 -2.6291 0.23490E-02 -2.6291 0.10000E+01 0.0000 22 AlO+ 0.66016E-16 -16.1804 0.55241E-16 -16.2577 0.83678E+00 -0.0774 24 HAlO2,aq 0.14793E-09 -9.8299 0.14793E-09 -9.8299 0.10000E+01 0.0000 25 AlO2- 0.52819E-05 -5.2772 0.44033E-05 -5.3562 0.83367E+00 -0.0790 26 CH4,aq 0.14416E-04 -4.8411 0.14366E-04 -4.8427 0.99654E+00 -0.0015 27 C2H6,aq 0.60296E-14 -14.2197 0.60087E-14 -14.2212 0.99654E+00 -0.0015 31 CO,aq 0.82659E-16 -16.0827 0.82659E-16 -16.0827 0.10000E+01 0.0000 32 CO2,aq 0.56229E-09 -9.2500 0.56034E-09 -9.2515 0.99654E+00 -0.0015 33 CO3-2 0.79934E-05 -5.0973 0.41418E-05 -5.3828 0.51816E+00 -0.2855 34 CaCO3,aq 0.33753E-08 -8.4717 0.33753E-08 -8.4717 0.10000E+01 0.0000 35 Ca(HCO3)+ 0.69914E-11 -11.1554 0.58502E-11 -11.2328 0.83678E+00 -0.0774 36 CaCl+ 0.16147E-10 -10.7919 0.13512E-10 -10.8693 0.83678E+00 -0.0774 37 CaCl2,aq 0.41238E-15 -15.3847 0.41238E-15 -15.3847 0.10000E+01 0.0000 38 CaF+ 0.16784E-12 -12.7751 0.14045E-12 -12.8525 0.83678E+00 -0.0774 39 CaOH+ 0.74436E-07 -7.1282 0.62287E-07 -7.2056 0.83678E+00 -0.0774 40 CaSO4,aq 0.13339E-15 -15.8749 0.13339E-15 -15.8749 0.10000E+01 0.0000 41 HCl,aq 0.17506E-14 -14.7568 0.17506E-14 -14.7568 0.10000E+01 0.0000 45 HF,aq 0.75351E-13 -13.1229 0.75351E-13 -13.1229 0.10000E+01 0.0000 48 FeCl+ 0.59270E-17 -17.2272 0.49596E-17 -17.3046 0.83678E+00 -0.0774 51 FeF+ 0.22047E-18 -18.6566 0.18449E-18 -18.7340 0.83678E+00 -0.0774 53 FeO,aq 0.17141E-09 -9.7660 0.17141E-09 -9.7660 0.10000E+01 0.0000 54 FeOH+ 0.12759E-10 -10.8942 0.10676E-10 -10.9716 0.83678E+00 -0.0774 55 HFeO2- 0.28877E-07 -7.5394 0.24118E-07 -7.6177 0.83518E+00 -0.0782 56 FeO+ 0.12559E-16 -16.9011 0.10509E-16 -16.9785 0.83678E+00 -0.0774 58 FeO2- 0.46555E-09 -9.3320 0.38882E-09 -9.4103 0.83518E+00 -0.0782 59 HFeO2,aq 0.36775E-11 -11.4344 0.36775E-11 -11.4344 0.10000E+01 0.0000 60 H2,aq 0.58925E-05 -5.2297 0.58722E-05 -5.2312 0.99654E+00 -0.0015 61 KCl,aq 0.30486E-09 -9.5159 0.30486E-09 -9.5159 0.10000E+01 0.0000 63 KOH,aq 0.75191E-06 -6.1238 0.75191E-06 -6.1238 0.10000E+01 0.0000 64 KSO4- 0.15723E-13 -13.8035 0.13132E-13 -13.8817 0.83518E+00 -0.0782 65 MgCO3,aq 0.14111E-12 -12.8505 0.14111E-12 -12.8505 0.10000E+01 0.0000 66 Mg(HCO3)+ 0.11915E-14 -14.9239 0.99700E-15 -15.0013 0.83678E+00 -0.0774 67 MgCl+ 0.24408E-14 -14.6125 0.20424E-14 -14.6899 0.83678E+00 -0.0774 68 MgF+ 0.10370E-15 -15.9842 0.86771E-16 -16.0616 0.83678E+00 -0.0774 69 MgOH+ 0.68696E-10 -10.1631 0.57483E-10 -10.2405 0.83678E+00 -0.0774 71 MnF+ 0.28527E-16 -16.5447 0.23871E-16 -16.6221 0.83678E+00 -0.0774 72 MnO,aq 0.17930E-08 -8.7464 0.17930E-08 -8.7464 0.10000E+01 0.0000 73 MnOH+ 0.46528E-09 -9.3323 0.38934E-09 -9.4097 0.83678E+00 -0.0774 74 MnO2-2 0.20765E-10 -10.6827 0.10760E-10 -10.9682 0.51816E+00 -0.2855 75 HMnO2- 0.20990E-09 -9.6780 0.17530E-09 -9.7562 0.83518E+00 -0.0782 78 MnCl+ 0.90519E-14 -14.0433 0.75744E-14 -14.1206 0.83678E+00 -0.0774 79 MnSO4,aq 0.17866E-19 -19.7480 0.17866E-19 -19.7480 0.10000E+01 0.0000 80 NaCl,aq 0.70603E-06 -6.1512 0.70603E-06 -6.1512 0.10000E+01 0.0000 81 NaF,aq 0.57467E-09 -9.2406 0.57467E-09 -9.2406 0.10000E+01 0.0000 82 NaOH,aq 0.95814E-04 -4.0186 0.95814E-04 -4.0186 0.10000E+01 0.0000 84 OH- 0.93194E-02 -2.0306 0.77693E-02 -2.1096 0.83367E+00 -0.0790 89 HPO3-2 0.83118E-15 -15.0803 0.43068E-15 -15.3658 0.51816E+00 -0.2855 91 H2PO3- 0.76901E-19 -19.1141 0.64226E-19 -19.1923 0.83518E+00 -0.0782 92 H3PO4,aq 0.91030E-18 -18.0408 0.91030E-18 -18.0408 0.10000E+01 0.0000 93 H2PO4- 0.38621E-10 -10.4132 0.32286E-10 -10.4910 0.83597E+00 -0.0778 94 PO4-3 0.10643E-08 -8.9729 0.25821E-09 -9.5880 0.24260E+00 -0.6151 98 HP2O7-3 0.94918E-18 -18.0227 0.21946E-18 -18.6586 0.23121E+00 -0.6360 99 P2O7-4 0.91466E-17 -17.0387 0.70501E-18 -18.1518 0.77079E-01 -1.1131 100 H2S,aq 0.62519E-08 -8.2040 0.62303E-08 -8.2055 0.99654E+00 -0.0015 101 S2-2 0.53511E-14 -14.2716 0.27727E-14 -14.5571 0.51816E+00 -0.2855 107 SO3-2 0.93826E-17 -17.0277 0.49320E-17 -17.3070 0.52565E+00 -0.2793 108 HSO3- 0.27497E-19 -19.5607 0.22965E-19 -19.6389 0.83518E+00 -0.0782 109 HSO4- 0.55302E-18 -18.2573 0.46320E-18 -18.3342 0.83759E+00 -0.0770 Charge balance for all species = -.6133E-08 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.8850665E-10 -.2228169E-01 -.2241957E+02 0.0000 2 H2O 0.1000000E+01 0.5550486E+02 0.9981986E+06 0.0000 3 Cl- 0.1538152E-03 0.1545216E-03 0.5468731E+01 6.2374 4 SO4-- 0.1244700E-10 -.1588938E-04 -.1523706E+01 9.0677 5 HCO3- 0.4216078E-05 0.2662971E-04 0.1622046E+01 4.6759 6 HS- 0.3245211E-04 0.4834775E-04 0.1596178E+01 5.5617 7 Al+++ 0.9721996E-29 0.5282006E-05 0.1422687E+00 0.7372 8 H4SiO4 0.6974863E-03 0.1353246E-01 0.1298417E+04 -3.1565 9 Ca++ 0.1260910E-06 0.2194170E-06 0.8778507E-02 13.0701 10 Mg++ 0.2112630E-10 0.9318259E-10 0.2261517E-05 9.2923 11 Fe++ 0.4748606E-13 0.2953054E-07 0.1646325E-02 6.6445 12 K+ 0.1565088E-03 0.1572611E-03 0.6138533E+01 6.2457 13 Na+ 0.1986053E-01 0.2230607E-01 0.5119206E+03 8.3483 14 Mn++ 0.1862556E-10 0.2507568E-08 0.1375213E-03 9.2384 15 F- 0.1775875E-06 0.1781624E-06 0.3378846E-02 3.2989 16 HPO4-- 0.4531748E-07 0.4642043E-07 0.4447642E-02 12.6290 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.2001039E-01 -.2001023E-01 -.1594083E-06 0.0000000E+00 2 H2O 0.4984653E+02 0.4984653E+02 -.1251373E-06 0.0000000E+00 3 Cl- 0.1387692E-03 0.1387692E-03 0.0000000E+00 0.0000000E+00 4 SO4-- -.1426881E-04 -.1426957E-04 0.7590199E-09 0.0000000E+00 5 HCO3- 0.2391500E-04 0.2391500E-04 0.0000000E+00 0.0000000E+00 6 HS- 0.4341828E-04 0.4341904E-04 -.7590199E-09 0.0000000E+00 7 Al+++ 0.4775352E-05 0.4743542E-05 0.3180952E-07 0.0000000E+00 8 H4SiO4 0.1215302E-01 0.1215292E-01 0.1026105E-06 0.0000000E+00 9 Ca++ 0.2080835E-06 0.1970489E-06 0.1103456E-07 0.0000000E+00 10 Mg++ 0.8368328E-10 0.8368328E-10 0.0000000E+00 0.0000000E+00 11 Fe++ 0.3259227E-07 0.2652011E-07 0.6072159E-08 0.0000000E+00 12 K+ 0.1412294E-03 0.1412294E-03 0.0000000E+00 0.0000000E+00 13 Na+ 0.2003215E-01 0.2003212E-01 0.3052531E-07 0.0000000E+00 14 Mn++ 0.2251939E-08 0.2251939E-08 0.0000000E+00 0.0000000E+00 15 F- 0.1600000E-06 0.1600000E-06 0.0000000E+00 0.0000000E+00 16 HPO4-- 0.4168819E-07 0.4168819E-07 0.0000000E+00 0.0000000E+00 Chg. balance for solid moles: -.1323E-22 Mass of aqueous solution: 0.899621E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 0.0001500 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 0.3053E-07 -7.515 0.8004E-05 -5.097 81.37 0.3073E-05 andradite 0.3036E-08 -8.518 0.1543E-05 -5.812 15.69 0.4009E-06 grossular 0.6421E-09 -9.192 0.2892E-06 -6.539 2.940 0.8048E-07 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8254E+00 0.8254E+00 1.0000 -0.083 grossular 0.1746E+00 0.1746E+00 1.0000 -0.758 Solid products produced: Mass = 0.000010 g Volume = 0.000004 cm3 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.0001500 moles log = -3.8239 Original solution: 1000.0103000 g Original solution / Rock added: 6666735.33 (Water/Rock Ratio), log = 6.8239 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0493 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9727E+00 0.9856 0.1006E+01 0.1021E+01 CO2,gas 0.5675E-07 1.0069 0.5995E-07 0.5954E-07 CH4,gas 0.1991E-01 1.0123 0.2115E-01 0.2089E-01 H2,gas 0.7343E-02 1.0006 0.7709E-02 0.7705E-02 H2S,gas 0.1639E-06 0.9959 0.1713E-06 0.1720E-06 S2,gas 0.1765E-28 1.0000 0.1852E-28 0.1852E-28 CO,gas 0.1174E-12 1.0000 0.1232E-12 0.1232E-12 SO3,gas 0.1288E-46 1.0000 0.1351E-46 0.1351E-46 SO2,gas 0.3863E-26 1.0000 0.4054E-26 0.4054E-26 HF,gas 0.1763E-15 1.0000 0.1850E-15 0.1850E-15 HCl,gas 0.2944E-17 1.0000 0.3089E-17 0.3089E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 17 albite -0.38 -0.38 0.00 0.000 -0.94784E-12 23 andradite 39.01 39.01 0.00 0.000 -0.12132E-10 24 grossular 32.73 32.73 0.00 0.000 -0.24265E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -15.58 -8.92 -2.974 0.15233E+05 -7.222 3 CH4,gas 4.54 1.17 -3.37 -0.843 0.57606E+04 -1.675 4 H2,gas 8.00 4.19 -3.81 -2.178 0.65088E+04 -2.113 5 H2S,gas -6.23 -14.70 -8.47 -4.233 0.14454E+05 -6.766 6 S2,gas -7.34 -37.77 -30.43 -4.682 0.51960E+05 -28.732 7 CO,gas 3.21 -11.39 -14.61 -4.495 0.24944E+05 -12.909 8 SO3,gas 17.12 -31.45 -48.57 -12.142 0.82929E+05 -46.869 9 SO2,gas 0.83 -27.26 -28.09 -7.491 0.47965E+05 -26.392 10 HF,gas 0.47 -16.96 -17.43 -8.716 0.29764E+05 -15.733 11 HCl,gas 5.19 -14.02 -19.21 -9.605 0.32799E+05 -17.510 12 acmite 7.71 6.59 -1.12 -0.117 0.19188E+04 16 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 20 spessartine 24.46 19.72 -4.74 -0.237 0.80886E+04 21 analcite 3.32 2.77 -0.55 -0.061 0.93785E+03 27 annite 20.12 17.45 -2.68 -0.149 0.45700E+04 28 phlogopite 27.06 25.39 -1.67 -0.093 0.28588E+04 30 anorthite 12.71 8.23 -4.48 -0.345 0.76473E+04 33 apatite-OH -18.15 -18.31 -0.15 -0.012 0.26046E+03 34 apatite-F -34.30 -35.26 -0.96 -0.080 0.16449E+04 38 aragonite 0.97 -2.51 -3.48 -1.159 0.59381E+04 39 brucite 12.57 9.29 -3.28 -0.655 0.55942E+04 40 calcite 0.81 -2.51 -3.32 -1.108 0.56739E+04 41 carnegieite-low 9.02 5.93 -3.09 -0.442 0.52833E+04 42 carnegieite-high 10.09 5.93 -4.16 -0.595 0.71103E+04 43 carpholite-Mg 8.58 4.45 -4.13 -0.275 0.70490E+04 44 carpholite-Fe 6.71 1.81 -4.91 -0.327 0.83780E+04 45 celadonite 5.34 3.65 -1.69 -0.100 0.28896E+04 46 celadonite-Fe 3.88 1.00 -2.88 -0.169 0.49090E+04 47 chrysotile 23.89 21.56 -2.33 -0.194 0.39759E+04 49 clinochlore 39.07 38.47 -0.60 -0.019 0.10299E+04 50 daphnite 28.97 25.23 -3.74 -0.117 0.63822E+04 52 chlorite-Al-free 47.17 43.13 -4.05 -0.169 0.69070E+04 54 chloritoid-Fe 9.17 4.96 -4.21 -0.281 0.71905E+04 55 chloritoid-Mn 11.40 7.56 -3.84 -0.256 0.65648E+04 57 coesite -2.38 -3.16 -0.78 -0.260 0.13325E+04 64 cristobalite -2.56 -3.16 -0.60 -0.199 0.10179E+04 66 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71234E+04 68 diaspore 2.87 0.74 -2.14 -0.356 0.36480E+04 69 diamond -3.10 -7.21 -4.10 -1.172 0.70062E+04 70 diopside 16.18 16.05 -0.13 -0.013 0.22522E+03 71 hedenbergite 14.21 13.40 -0.81 -0.081 0.13773E+04 74 enstatite 17.26 12.27 -4.99 -0.499 0.85259E+04 76 clinoenstatite 17.17 12.27 -4.89 -0.489 0.83575E+04 78 epidote 24.67 22.70 -1.97 -0.096 0.33707E+04 79 clinozoisite 22.81 18.88 -3.92 -0.178 0.66994E+04 80 epidote-Fe 29.84 26.51 -3.33 -0.173 0.56886E+04 81 fayalite 14.05 10.13 -3.91 -0.559 0.66817E+04 82 ferrosilite 11.15 6.98 -4.17 -0.417 0.71260E+04 86 gibbsite 4.08 0.74 -3.34 -0.477 0.57065E+04 87 glaucophane 22.97 20.80 -2.18 -0.059 0.37200E+04 88 glaucophane-Fe 17.28 12.85 -4.42 -0.120 0.75522E+04 89 graphite -3.55 -7.21 -3.66 -1.046 0.62485E+04 90 greenalite 16.14 13.62 -2.52 -0.210 0.43011E+04 93 hematite 12.57 9.10 -3.47 -0.420 0.59164E+04 94 heulandite -5.83 -7.55 -1.72 -0.078 0.29428E+04 98 jadeite 4.22 2.77 -1.44 -0.144 0.24633E+04 100 kalsilite 7.58 3.83 -3.76 -0.537 0.64158E+04 101 kaolinite -1.33 -4.84 -3.51 -0.319 0.59860E+04 104 laumontite 2.88 1.92 -0.96 -0.064 0.16473E+04 105 lawsonite 9.62 8.23 -1.38 -0.092 0.23639E+04 106 leucite 4.12 0.67 -3.45 -0.345 0.58889E+04 108 lizardite 23.24 21.56 -1.68 -0.140 0.28685E+04 110 magnetite 20.09 15.75 -4.34 -0.354 0.74134E+04 111 minnesotaite 10.39 7.31 -3.08 -0.181 0.52599E+04 115 manganosite 14.06 9.24 -4.82 -1.205 0.82296E+04 119 microcline -2.49 -2.49 0.00 0.000 0.12713E-01 123 muscovite 2.58 -1.01 -3.59 -0.211 0.61375E+04 124 paragonite 4.24 1.09 -3.15 -0.185 0.53766E+04 125 nepheline 8.34 5.93 -2.41 -0.344 0.41157E+04 131 periclase-Fe 11.63 6.64 -4.98 -1.246 0.85068E+04 137 phlogopite-Na 29.65 27.49 -2.15 -0.120 0.36776E+04 139 prehnite 19.37 18.15 -1.23 -0.072 0.20944E+04 140 prehnite-Fe 22.50 21.96 -0.54 -0.032 0.92073E+03 141 pumpellyite-Fe 46.27 43.67 -2.60 -0.058 0.44347E+04 142 pumpellyite-Mg 48.99 46.32 -2.67 -0.059 0.45673E+04 146 pyrrhotite -4.26 -8.05 -3.79 -1.264 0.64726E+04 147 pyrrhotiteFe0.875 -6.02 -9.40 -3.38 -1.245 0.57780E+04 148 pyroxmangite 7.40 6.08 -1.32 -0.263 0.22483E+04 149 pyrophyllite -6.18 -11.15 -4.98 -0.311 0.84958E+04 150 quartz -2.99 -3.16 -0.17 -0.056 0.28520E+03 155 rhodonite 7.45 6.08 -1.36 -0.273 0.23286E+04 156 sanidine -1.28 -2.49 -1.21 -0.093 0.20678E+04 166 stilbite -7.52 -7.55 -0.03 -0.001 0.48941E+02 167 stilpnomelane-Fe 13.02 12.57 -0.45 -0.013 0.76667E+03 168 stilpnomelane-Mg 27.44 25.81 -1.63 -0.049 0.27909E+04 174 talc 16.49 15.25 -1.24 -0.073 0.21175E+04 177 tephroite 18.09 15.32 -2.77 -0.395 0.47220E+04 181 tridymite -2.63 -3.16 -0.53 -0.177 0.90517E+03 182 tremolite 47.87 47.35 -0.52 -0.014 0.88688E+03 183 ferroactinolite 38.45 34.11 -4.34 -0.117 0.74129E+04 184 troilite-low -4.41 -8.05 -3.64 -1.213 0.62154E+04 190 wairakite 3.95 1.92 -2.03 -0.120 0.34692E+04 191 walstromite 11.51 9.91 -1.60 -0.319 0.27244E+04 192 wollastonite 10.46 9.91 -0.55 -0.109 0.93483E+03 193 pseudo-wollastonite 11.00 9.91 -1.09 -0.217 0.18547E+04 194 zoisite 22.85 18.88 -3.97 -0.180 0.67734E+04 195 akaganeite 7.75 4.55 -3.20 -0.693 0.54708E+04 202 chalcedony -2.80 -3.16 -0.35 -0.118 0.60450E+03 204 montmorillonite-Ca -2.29 -6.17 -3.88 -0.240 0.66267E+04 205 montmorillonite-K -2.24 -6.27 -4.03 -0.247 0.68819E+04 206 montmorillonite-Mg -2.48 -6.80 -4.32 -0.267 0.73680E+04 207 montmorillonite-Na -2.04 -5.57 -3.54 -0.217 0.60368E+04 208 nontronite-Ca 3.21 -0.08 -3.30 -0.214 0.56308E+04 209 nontronite-H 2.53 -2.24 -4.77 -0.320 0.81489E+04 210 nontronite-K 3.34 -0.18 -3.52 -0.226 0.60093E+04 211 nontronite-Mg 3.07 -0.71 -3.78 -0.245 0.64563E+04 212 nontronite-Na 3.52 0.52 -3.00 -0.193 0.51302E+04 228 tobermorite 9.82 7.73 -2.09 -0.571 0.35722E+04 234 alabandite -0.98 -5.46 -4.48 -1.493 0.76483E+04 237 boehmite 4.41 0.74 -3.67 -0.612 0.62649E+04 239 ferrous-oxide 9.81 6.64 -3.17 -0.792 0.54077E+04 245 silica-amorphous -2.09 -3.16 -1.07 -0.355 0.18187E+04 247 an20ab80 2.02 1.34 -0.68 -0.052 0.11586E+04 248 an25ab75 2.65 1.77 -0.88 -0.067 0.14952E+04 249 an30ab70 3.28 2.20 -1.08 -0.083 0.18415E+04 250 tr.625ac.25prg.125 45.16 44.99 -0.18 -0.005 0.30230E+03 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 0.0000100 MOLES Current total amount of reactant added: 0.0001500 MOLES New total amount of reactant added: 0.0001600 MOLES Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.5508E-08 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 6 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 0.0001600 Water: Moles liquid = 0.4985E+02 kg liquid = 0.8981E+00 Moles total = 0.4985E+02 kg total = 0.8980E+00 Activity = 1.0000 Stoichiometric ionic strength = .1134042E-01 Osmotic coef. = 0.9688 True ionic strength = .2002613E-01 Chg. balance for total moles = -.5508E-08 Max. difference allowed = 0.1388E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.88522E-10 -10.0529 0.74379E-10 -10.1285 0.84023E+00 -0.0756 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.15388E-03 -3.8128 0.12852E-03 -3.8910 0.83518E+00 -0.0782 4 SO4-- 0.13435E-10 -10.8718 0.69761E-11 -11.1564 0.51925E+00 -0.2846 5 HCO3- 0.45042E-05 -5.3464 0.37673E-05 -5.4240 0.83640E+00 -0.0776 6 HS- 0.32723E-04 -4.4852 0.27333E-04 -4.5633 0.83530E+00 -0.0782 7 Al+++ 0.97242E-29 -29.0121 0.22461E-29 -29.6486 0.23098E+00 -0.6364 8 H4SiO4 0.69760E-03 -3.1564 0.69760E-03 -3.1564 0.10000E+01 0.0000 9 Ca++ 0.12583E-06 -6.9002 0.64861E-07 -7.1880 0.51544E+00 -0.2878 10 Mg++ 0.21127E-10 -10.6752 0.10840E-10 -10.9650 0.51308E+00 -0.2898 11 Fe++ 0.47293E-13 -13.3252 0.24292E-13 -13.6145 0.51365E+00 -0.2893 12 K+ 0.15651E-03 -3.8055 0.13094E-03 -3.8829 0.83660E+00 -0.0775 13 Na+ 0.19861E-01 -1.7020 0.16584E-01 -1.7803 0.83503E+00 -0.0783 14 Mn++ 0.18632E-10 -10.7297 0.95781E-11 -11.0187 0.51407E+00 -0.2890 15 F- 0.18203E-06 -6.7399 0.15171E-06 -6.8190 0.83346E+00 -0.0791 16 HPO4-- 0.45318E-07 -7.3437 0.23535E-07 -7.6283 0.51933E+00 -0.2846 18 HSiO3- 0.10486E-01 -1.9794 0.87575E-02 -2.0576 0.83518E+00 -0.0782 19 Ca(HSiO3)+ 0.15459E-07 -7.8108 0.12936E-07 -7.8882 0.83678E+00 -0.0774 20 Mg(HSiO3)+ 0.32154E-11 -11.4928 0.26905E-11 -11.5702 0.83678E+00 -0.0774 21 NaHSiO3,aq 0.23490E-02 -2.6291 0.23490E-02 -2.6291 0.10000E+01 0.0000 22 AlO+ 0.66007E-16 -16.1804 0.55233E-16 -16.2578 0.83678E+00 -0.0774 24 HAlO2,aq 0.14789E-09 -9.8301 0.14789E-09 -9.8301 0.10000E+01 0.0000 25 AlO2- 0.52793E-05 -5.2774 0.44012E-05 -5.3564 0.83367E+00 -0.0790 26 CH4,aq 0.14388E-04 -4.8420 0.14338E-04 -4.8435 0.99654E+00 -0.0015 27 C2H6,aq 0.61093E-14 -14.2140 0.60882E-14 -14.2155 0.99654E+00 -0.0015 31 CO,aq 0.86829E-16 -16.0613 0.86829E-16 -16.0613 0.10000E+01 0.0000 32 CO2,aq 0.60082E-09 -9.2213 0.59874E-09 -9.2228 0.99654E+00 -0.0015 33 CO3-2 0.85383E-05 -5.0686 0.44241E-05 -5.3542 0.51815E+00 -0.2855 34 CaCO3,aq 0.35981E-08 -8.4439 0.35981E-08 -8.4439 0.10000E+01 0.0000 35 Ca(HCO3)+ 0.74540E-11 -11.1276 0.62373E-11 -11.2050 0.83678E+00 -0.0774 36 CaCl+ 0.16121E-10 -10.7926 0.13490E-10 -10.8700 0.83678E+00 -0.0774 37 CaCl2,aq 0.41189E-15 -15.3852 0.41189E-15 -15.3852 0.10000E+01 0.0000 38 CaF+ 0.17169E-12 -12.7653 0.14367E-12 -12.8426 0.83678E+00 -0.0774 39 CaOH+ 0.74272E-07 -7.1292 0.62149E-07 -7.2066 0.83678E+00 -0.0774 40 CaSO4,aq 0.14368E-15 -15.8426 0.14368E-15 -15.8426 0.10000E+01 0.0000 41 HCl,aq 0.17516E-14 -14.7566 0.17516E-14 -14.7566 0.10000E+01 0.0000 45 HF,aq 0.77248E-13 -13.1121 0.77248E-13 -13.1121 0.10000E+01 0.0000 48 FeCl+ 0.59054E-17 -17.2288 0.49415E-17 -17.3061 0.83678E+00 -0.0774 51 FeF+ 0.22506E-18 -18.6477 0.18833E-18 -18.7251 0.83678E+00 -0.0774 53 FeO,aq 0.17066E-09 -9.7679 0.17066E-09 -9.7679 0.10000E+01 0.0000 54 FeOH+ 0.12705E-10 -10.8960 0.10631E-10 -10.9734 0.83678E+00 -0.0774 55 HFeO2- 0.28745E-07 -7.5414 0.24007E-07 -7.6197 0.83518E+00 -0.0782 56 FeO+ 0.12612E-16 -16.8992 0.10554E-16 -16.9766 0.83678E+00 -0.0774 58 FeO2- 0.46739E-09 -9.3303 0.39035E-09 -9.4085 0.83518E+00 -0.0782 59 HFeO2,aq 0.36927E-11 -11.4327 0.36927E-11 -11.4327 0.10000E+01 0.0000 60 H2,aq 0.57929E-05 -5.2371 0.57728E-05 -5.2386 0.99654E+00 -0.0015 61 KCl,aq 0.30498E-09 -9.5157 0.30498E-09 -9.5157 0.10000E+01 0.0000 63 KOH,aq 0.75178E-06 -6.1239 0.75178E-06 -6.1239 0.10000E+01 0.0000 64 KSO4- 0.16971E-13 -13.7703 0.14174E-13 -13.8485 0.83518E+00 -0.0782 65 MgCO3,aq 0.15073E-12 -12.8218 0.15073E-12 -12.8218 0.10000E+01 0.0000 66 Mg(HCO3)+ 0.12729E-14 -14.8952 0.10652E-14 -14.9726 0.83678E+00 -0.0774 67 MgCl+ 0.24419E-14 -14.6123 0.20433E-14 -14.6897 0.83678E+00 -0.0774 68 MgF+ 0.10629E-15 -15.9735 0.88942E-16 -16.0509 0.83678E+00 -0.0774 69 MgOH+ 0.68686E-10 -10.1631 0.57475E-10 -10.2405 0.83678E+00 -0.0774 71 MnF+ 0.29250E-16 -16.5339 0.24475E-16 -16.6113 0.83678E+00 -0.0774 72 MnO,aq 0.17930E-08 -8.7464 0.17930E-08 -8.7464 0.10000E+01 0.0000 73 MnOH+ 0.46535E-09 -9.3322 0.38940E-09 -9.4096 0.83678E+00 -0.0774 74 MnO2-2 0.20758E-10 -10.6828 0.10756E-10 -10.9684 0.51815E+00 -0.2855 75 HMnO2- 0.20986E-09 -9.6781 0.17527E-09 -9.7563 0.83518E+00 -0.0782 78 MnCl+ 0.90587E-14 -14.0429 0.75801E-14 -14.1203 0.83678E+00 -0.0774 79 MnSO4,aq 0.19290E-19 -19.7147 0.19290E-19 -19.7147 0.10000E+01 0.0000 80 NaCl,aq 0.70633E-06 -6.1510 0.70633E-06 -6.1510 0.10000E+01 0.0000 81 NaF,aq 0.58904E-09 -9.2299 0.58904E-09 -9.2299 0.10000E+01 0.0000 82 NaOH,aq 0.95798E-04 -4.0186 0.95798E-04 -4.0186 0.10000E+01 0.0000 84 OH- 0.93178E-02 -2.0307 0.77680E-02 -2.1097 0.83367E+00 -0.0790 89 HPO3-2 0.81712E-15 -15.0877 0.42339E-15 -15.3733 0.51815E+00 -0.2855 91 H2PO3- 0.75613E-19 -19.1214 0.63150E-19 -19.1996 0.83518E+00 -0.0782 92 H3PO4,aq 0.91061E-18 -18.0407 0.91061E-18 -18.0407 0.10000E+01 0.0000 93 H2PO4- 0.38628E-10 -10.4131 0.32292E-10 -10.4909 0.83597E+00 -0.0778 94 PO4-3 0.10642E-08 -8.9730 0.25816E-09 -9.5881 0.24260E+00 -0.6151 98 HP2O7-3 0.94935E-18 -18.0226 0.21950E-18 -18.6586 0.23121E+00 -0.6360 99 P2O7-4 0.91468E-17 -17.0387 0.70501E-18 -18.1518 0.77077E-01 -1.1131 100 H2S,aq 0.63051E-08 -8.2003 0.62833E-08 -8.2018 0.99654E+00 -0.0015 101 S2-2 0.55343E-14 -14.2569 0.28676E-14 -14.5425 0.51815E+00 -0.2855 107 SO3-2 0.99560E-17 -17.0019 0.52333E-17 -17.2812 0.52565E+00 -0.2793 108 HSO3- 0.29182E-19 -19.5349 0.24372E-19 -19.6131 0.83518E+00 -0.0782 109 HSO4- 0.59701E-18 -18.2240 0.50005E-18 -18.3010 0.83759E+00 -0.0770 Charge balance for all species = -.6133E-08 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.8852203E-10 -.2228048E-01 -.2241835E+02 0.0000 2 H2O 0.1000000E+01 0.5550486E+02 0.9981986E+06 0.0000 3 Cl- 0.1538806E-03 0.1545873E-03 0.5471055E+01 6.2375 4 SO4-- 0.1343491E-10 -.1583622E-04 -.1518609E+01 9.1007 5 HCO3- 0.4504228E-05 0.2743478E-04 0.1671083E+01 4.7046 6 HS- 0.3272263E-04 0.4856517E-04 0.1603355E+01 5.5652 7 Al+++ 0.9724161E-29 0.5279468E-05 0.1422004E+00 0.7371 8 H4SiO4 0.6975985E-03 0.1353245E-01 0.1298416E+04 -3.1564 9 Ca++ 0.1258349E-06 0.2191879E-06 0.8769342E-02 13.0691 10 Mg++ 0.2112688E-10 0.9318257E-10 0.2261517E-05 9.2921 11 Fe++ 0.4729304E-13 0.2939920E-07 0.1639003E-02 6.6426 12 K+ 0.1565089E-03 0.1572610E-03 0.6138532E+01 6.2456 13 Na+ 0.1986057E-01 0.2230606E-01 0.5119204E+03 8.3482 14 Mn++ 0.1863178E-10 0.2507567E-08 0.1375213E-03 9.2384 15 F- 0.1820271E-06 0.1826164E-06 0.3463316E-02 3.3096 16 HPO4-- 0.4531763E-07 0.4642042E-07 0.4447641E-02 12.6288 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.2000931E-01 -.2000914E-01 -.1691337E-06 0.0000000E+00 2 H2O 0.4984654E+02 0.4984654E+02 -.1342317E-06 0.0000000E+00 3 Cl- 0.1388282E-03 0.1388282E-03 0.0000000E+00 0.0000000E+00 4 SO4-- -.1422106E-04 -.1422183E-04 0.7737634E-09 0.0000000E+00 5 HCO3- 0.2463800E-04 0.2463800E-04 0.0000000E+00 0.0000000E+00 6 HS- 0.4361353E-04 0.4361430E-04 -.7737634E-09 0.0000000E+00 7 Al+++ 0.4775352E-05 0.4741264E-05 0.3408755E-07 0.0000000E+00 8 H4SiO4 0.1215302E-01 0.1215291E-01 0.1095927E-06 0.0000000E+00 9 Ca++ 0.2080835E-06 0.1968433E-06 0.1124025E-07 0.0000000E+00 10 Mg++ 0.8368328E-10 0.8368328E-10 0.0000000E+00 0.0000000E+00 11 Fe++ 0.3259227E-07 0.2640216E-07 0.6190107E-08 0.0000000E+00 12 K+ 0.1412294E-03 0.1412294E-03 0.0000000E+00 0.0000000E+00 13 Na+ 0.2003215E-01 0.2003212E-01 0.3278416E-07 0.0000000E+00 14 Mn++ 0.2251939E-08 0.2251939E-08 0.0000000E+00 0.0000000E+00 15 F- 0.1640000E-06 0.1640000E-06 0.0000000E+00 0.0000000E+00 16 HPO4-- 0.4168819E-07 0.4168819E-07 0.0000000E+00 0.0000000E+00 Chg. balance for solid moles: 0.6617E-23 Mass of aqueous solution: 0.899621E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 0.0001600 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 0.3278E-07 -7.484 0.8597E-05 -5.066 82.16 0.3300E-05 andradite 0.3095E-08 -8.509 0.1573E-05 -5.803 15.03 0.4086E-06 grossular 0.6517E-09 -9.186 0.2936E-06 -6.532 2.806 0.8168E-07 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8261E+00 0.8261E+00 1.0000 -0.083 grossular 0.1739E+00 0.1739E+00 1.0000 -0.760 Solid products produced: Mass = 0.000010 g Volume = 0.000004 cm3 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.0001600 moles log = -3.7959 Original solution: 1000.0103000 g Original solution / Rock added: 6250064.38 (Water/Rock Ratio), log = 6.7959 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0491 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9729E+00 0.9856 0.1006E+01 0.1021E+01 CO2,gas 0.6064E-07 1.0069 0.6406E-07 0.6362E-07 CH4,gas 0.1987E-01 1.0123 0.2111E-01 0.2085E-01 H2,gas 0.7220E-02 1.0006 0.7579E-02 0.7575E-02 H2S,gas 0.1653E-06 0.9959 0.1727E-06 0.1734E-06 S2,gas 0.1858E-28 1.0000 0.1949E-28 0.1949E-28 CO,gas 0.1233E-12 1.0000 0.1294E-12 0.1294E-12 SO3,gas 0.1391E-46 1.0000 0.1459E-46 0.1459E-46 SO2,gas 0.4101E-26 1.0000 0.4303E-26 0.4303E-26 HF,gas 0.1808E-15 1.0000 0.1897E-15 0.1897E-15 HCl,gas 0.2946E-17 1.0000 0.3091E-17 0.3091E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 17 albite -0.38 -0.38 0.00 0.000 0.11184E-10 23 andradite 39.01 39.01 0.00 0.000 0.00000E+00 24 grossular 32.73 32.73 0.00 0.000 0.12132E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -15.55 -8.89 -2.964 0.15184E+05 -7.193 3 CH4,gas 4.54 1.17 -3.37 -0.844 0.57620E+04 -1.676 4 H2,gas 8.00 4.18 -3.82 -2.182 0.65214E+04 -2.120 5 H2S,gas -6.23 -14.69 -8.46 -4.231 0.14448E+05 -6.763 6 S2,gas -7.34 -37.74 -30.41 -4.678 0.51923E+05 -28.710 7 CO,gas 3.21 -11.37 -14.59 -4.488 0.24907E+05 -12.888 8 SO3,gas 17.12 -31.41 -48.53 -12.134 0.82872E+05 -46.836 9 SO2,gas 0.83 -27.23 -28.07 -7.484 0.47921E+05 -26.366 10 HF,gas 0.47 -16.95 -17.42 -8.710 0.29746E+05 -15.722 11 HCl,gas 5.19 -14.02 -19.21 -9.604 0.32799E+05 -17.510 12 acmite 7.71 6.59 -1.12 -0.117 0.19156E+04 16 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 20 spessartine 24.46 19.72 -4.74 -0.237 0.80887E+04 21 analcite 3.32 2.77 -0.55 -0.061 0.93797E+03 27 annite 20.12 17.44 -2.68 -0.149 0.45798E+04 28 phlogopite 27.06 25.39 -1.67 -0.093 0.28595E+04 30 anorthite 12.71 8.23 -4.48 -0.345 0.76493E+04 33 apatite-OH -18.15 -18.31 -0.16 -0.012 0.26855E+03 34 apatite-F -34.30 -35.26 -0.96 -0.080 0.16346E+04 38 aragonite 0.97 -2.48 -3.45 -1.150 0.58907E+04 39 brucite 12.57 9.29 -3.28 -0.655 0.55944E+04 40 calcite 0.81 -2.48 -3.30 -1.098 0.56265E+04 41 carnegieite-low 9.02 5.93 -3.09 -0.442 0.52836E+04 42 carnegieite-high 10.09 5.93 -4.16 -0.595 0.71106E+04 43 carpholite-Mg 8.58 4.45 -4.13 -0.275 0.70495E+04 44 carpholite-Fe 6.71 1.80 -4.91 -0.327 0.83815E+04 45 celadonite 5.34 3.65 -1.69 -0.100 0.28897E+04 46 celadonite-Fe 3.88 1.00 -2.88 -0.169 0.49122E+04 47 chrysotile 23.89 21.56 -2.33 -0.194 0.39764E+04 49 clinochlore 39.07 38.47 -0.60 -0.019 0.10312E+04 50 daphnite 28.97 25.22 -3.75 -0.117 0.63987E+04 52 chlorite-Al-free 47.17 43.13 -4.05 -0.169 0.69079E+04 54 chloritoid-Fe 9.17 4.96 -4.21 -0.281 0.71941E+04 55 chloritoid-Mn 11.40 7.56 -3.84 -0.256 0.65651E+04 57 coesite -2.38 -3.16 -0.78 -0.260 0.13324E+04 64 cristobalite -2.56 -3.16 -0.60 -0.199 0.10177E+04 66 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71234E+04 68 diaspore 2.87 0.74 -2.14 -0.356 0.36482E+04 69 diamond -3.10 -7.19 -4.09 -1.168 0.69824E+04 70 diopside 16.18 16.05 -0.13 -0.013 0.22699E+03 71 hedenbergite 14.21 13.40 -0.81 -0.081 0.13821E+04 74 enstatite 17.26 12.27 -4.99 -0.499 0.85262E+04 76 clinoenstatite 17.17 12.27 -4.89 -0.489 0.83578E+04 78 epidote 24.67 22.70 -1.97 -0.096 0.33713E+04 79 clinozoisite 22.81 18.88 -3.93 -0.178 0.67032E+04 80 epidote-Fe 29.84 26.51 -3.33 -0.173 0.56859E+04 81 fayalite 14.05 10.13 -3.92 -0.560 0.66882E+04 82 ferrosilite 11.15 6.97 -4.18 -0.418 0.71323E+04 86 gibbsite 4.08 0.74 -3.34 -0.477 0.57068E+04 87 glaucophane 22.97 20.80 -2.18 -0.059 0.37205E+04 88 glaucophane-Fe 17.28 12.85 -4.43 -0.120 0.75618E+04 89 graphite -3.55 -7.19 -3.65 -1.042 0.62246E+04 90 greenalite 16.14 13.61 -2.52 -0.210 0.43107E+04 93 hematite 12.57 9.10 -3.46 -0.420 0.59104E+04 94 heulandite -5.83 -7.55 -1.72 -0.078 0.29442E+04 98 jadeite 4.22 2.77 -1.44 -0.144 0.24635E+04 100 kalsilite 7.58 3.83 -3.76 -0.537 0.64160E+04 101 kaolinite -1.33 -4.84 -3.51 -0.319 0.59862E+04 104 laumontite 2.88 1.92 -0.97 -0.064 0.16490E+04 105 lawsonite 9.62 8.23 -1.39 -0.092 0.23659E+04 106 leucite 4.12 0.67 -3.45 -0.345 0.58890E+04 108 lizardite 23.24 21.56 -1.68 -0.140 0.28690E+04 110 magnetite 20.09 15.75 -4.34 -0.354 0.74106E+04 111 minnesotaite 10.39 7.30 -3.09 -0.182 0.52693E+04 115 manganosite 14.06 9.24 -4.82 -1.205 0.82296E+04 119 microcline -2.49 -2.49 0.00 0.000 0.13541E-01 123 muscovite 2.58 -1.01 -3.59 -0.211 0.61380E+04 124 paragonite 4.24 1.09 -3.15 -0.185 0.53771E+04 125 nepheline 8.34 5.93 -2.41 -0.344 0.41159E+04 131 periclase-Fe 11.63 6.64 -4.98 -1.246 0.85101E+04 137 phlogopite-Na 29.65 27.49 -2.15 -0.120 0.36783E+04 139 prehnite 19.37 18.14 -1.23 -0.072 0.20981E+04 140 prehnite-Fe 22.50 21.96 -0.54 -0.032 0.92110E+03 141 pumpellyite-Fe 46.27 43.67 -2.60 -0.058 0.44455E+04 142 pumpellyite-Mg 48.99 46.32 -2.68 -0.060 0.45750E+04 146 pyrrhotite -4.26 -8.05 -3.79 -1.263 0.64696E+04 147 pyrrhotiteFe0.875 -6.02 -9.40 -3.38 -1.243 0.57730E+04 148 pyroxmangite 7.40 6.08 -1.32 -0.263 0.22482E+04 149 pyrophyllite -6.18 -11.15 -4.98 -0.311 0.84958E+04 150 quartz -2.99 -3.16 -0.17 -0.056 0.28508E+03 155 rhodonite 7.45 6.08 -1.36 -0.273 0.23285E+04 156 sanidine -1.28 -2.49 -1.21 -0.093 0.20678E+04 166 stilbite -7.52 -7.55 -0.03 -0.001 0.50335E+02 167 stilpnomelane-Fe 13.02 12.56 -0.46 -0.014 0.78265E+03 168 stilpnomelane-Mg 27.44 25.81 -1.63 -0.049 0.27917E+04 174 talc 16.49 15.25 -1.24 -0.073 0.21177E+04 177 tephroite 18.09 15.32 -2.77 -0.395 0.47219E+04 181 tridymite -2.63 -3.16 -0.53 -0.177 0.90506E+03 182 tremolite 47.87 47.35 -0.52 -0.014 0.89066E+03 183 ferroactinolite 38.45 34.10 -4.35 -0.118 0.74319E+04 184 troilite-low -4.41 -8.05 -3.64 -1.213 0.62124E+04 190 wairakite 3.95 1.92 -2.03 -0.120 0.34710E+04 191 walstromite 11.51 9.91 -1.60 -0.319 0.27260E+04 192 wollastonite 10.46 9.91 -0.55 -0.110 0.93648E+03 193 pseudo-wollastonite 11.00 9.91 -1.09 -0.217 0.18563E+04 194 zoisite 22.85 18.88 -3.97 -0.180 0.67773E+04 195 akaganeite 7.75 4.55 -3.20 -0.692 0.54677E+04 202 chalcedony -2.80 -3.16 -0.35 -0.118 0.60438E+03 204 montmorillonite-Ca -2.29 -6.17 -3.88 -0.240 0.66269E+04 205 montmorillonite-K -2.24 -6.27 -4.03 -0.247 0.68820E+04 206 montmorillonite-Mg -2.48 -6.80 -4.32 -0.267 0.73681E+04 207 montmorillonite-Na -2.04 -5.57 -3.54 -0.217 0.60368E+04 208 nontronite-Ca 3.21 -0.08 -3.29 -0.214 0.56247E+04 209 nontronite-H 2.53 -2.24 -4.77 -0.320 0.81425E+04 210 nontronite-K 3.34 -0.17 -3.52 -0.226 0.60029E+04 211 nontronite-Mg 3.07 -0.70 -3.78 -0.245 0.64499E+04 212 nontronite-Na 3.52 0.52 -3.00 -0.193 0.51238E+04 228 tobermorite 9.82 7.73 -2.09 -0.571 0.35736E+04 234 alabandite -0.98 -5.45 -4.48 -1.492 0.76420E+04 237 boehmite 4.41 0.74 -3.67 -0.612 0.62651E+04 239 ferrous-oxide 9.81 6.64 -3.17 -0.792 0.54110E+04 245 silica-amorphous -2.09 -3.16 -1.07 -0.355 0.18186E+04 247 an20ab80 2.02 1.34 -0.68 -0.052 0.11590E+04 248 an25ab75 2.65 1.77 -0.88 -0.067 0.14957E+04 249 an30ab70 3.28 2.20 -1.08 -0.083 0.18421E+04 250 tr.625ac.25prg.125 45.16 44.98 -0.18 -0.005 0.30999E+03 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 0.0000100 MOLES Current total amount of reactant added: 0.0001600 MOLES New total amount of reactant added: 0.0001700 MOLES Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.5508E-08 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 6 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 0.0001700 Water: Moles liquid = 0.4985E+02 kg liquid = 0.8981E+00 Moles total = 0.4985E+02 kg total = 0.8980E+00 Activity = 1.0000 Stoichiometric ionic strength = .1134106E-01 Osmotic coef. = 0.9688 True ionic strength = .2002671E-01 Chg. balance for total moles = -.5508E-08 Max. difference allowed = 0.1389E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.88537E-10 -10.0529 0.74392E-10 -10.1285 0.84023E+00 -0.0756 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.15395E-03 -3.8126 0.12857E-03 -3.8909 0.83518E+00 -0.0782 4 SO4-- 0.14445E-10 -10.8403 0.75005E-11 -11.1249 0.51925E+00 -0.2846 5 HCO3- 0.47931E-05 -5.3194 0.40089E-05 -5.3970 0.83640E+00 -0.0776 6 HS- 0.32993E-04 -4.4816 0.27559E-04 -4.5597 0.83530E+00 -0.0782 7 Al+++ 0.97263E-29 -29.0121 0.22465E-29 -29.6485 0.23097E+00 -0.6364 8 H4SiO4 0.69771E-03 -3.1563 0.69771E-03 -3.1563 0.10000E+01 0.0000 9 Ca++ 0.12559E-06 -6.9010 0.64734E-07 -7.1889 0.51544E+00 -0.2878 10 Mg++ 0.21127E-10 -10.6752 0.10840E-10 -10.9650 0.51308E+00 -0.2898 11 Fe++ 0.47116E-13 -13.3268 0.24201E-13 -13.6162 0.51364E+00 -0.2893 12 K+ 0.15651E-03 -3.8055 0.13093E-03 -3.8829 0.83660E+00 -0.0775 13 Na+ 0.19861E-01 -1.7020 0.16584E-01 -1.7803 0.83502E+00 -0.0783 14 Mn++ 0.18638E-10 -10.7296 0.95812E-11 -11.0186 0.51407E+00 -0.2890 15 F- 0.18647E-06 -6.7294 0.15541E-06 -6.8085 0.83345E+00 -0.0791 16 HPO4-- 0.45318E-07 -7.3437 0.23535E-07 -7.6283 0.51932E+00 -0.2846 18 HSiO3- 0.10486E-01 -1.9794 0.87574E-02 -2.0576 0.83518E+00 -0.0782 19 Ca(HSiO3)+ 0.15429E-07 -7.8117 0.12910E-07 -7.8891 0.83678E+00 -0.0774 20 Mg(HSiO3)+ 0.32154E-11 -11.4928 0.26906E-11 -11.5702 0.83678E+00 -0.0774 21 NaHSiO3,aq 0.23490E-02 -2.6291 0.23490E-02 -2.6291 0.10000E+01 0.0000 22 AlO+ 0.65998E-16 -16.1805 0.55225E-16 -16.2579 0.83678E+00 -0.0774 24 HAlO2,aq 0.14784E-09 -9.8302 0.14784E-09 -9.8302 0.10000E+01 0.0000 25 AlO2- 0.52768E-05 -5.2776 0.43991E-05 -5.3566 0.83367E+00 -0.0790 26 CH4,aq 0.14358E-04 -4.8429 0.14308E-04 -4.8444 0.99654E+00 -0.0015 27 C2H6,aq 0.61826E-14 -14.2088 0.61613E-14 -14.2103 0.99654E+00 -0.0015 31 CO,aq 0.90936E-16 -16.0413 0.90936E-16 -16.0413 0.10000E+01 0.0000 32 CO2,aq 0.63946E-09 -9.1942 0.63725E-09 -9.1957 0.99654E+00 -0.0015 33 CO3-2 0.90843E-05 -5.0417 0.47070E-05 -5.3273 0.51815E+00 -0.2855 34 CaCO3,aq 0.38206E-08 -8.4179 0.38206E-08 -8.4179 0.10000E+01 0.0000 35 Ca(HCO3)+ 0.79164E-11 -11.1015 0.66243E-11 -11.1789 0.83678E+00 -0.0774 36 CaCl+ 0.16096E-10 -10.7933 0.13469E-10 -10.8707 0.83678E+00 -0.0774 37 CaCl2,aq 0.41143E-15 -15.3857 0.41143E-15 -15.3857 0.10000E+01 0.0000 38 CaF+ 0.17553E-12 -12.7556 0.14688E-12 -12.8330 0.83678E+00 -0.0774 39 CaOH+ 0.74114E-07 -7.1301 0.62017E-07 -7.2075 0.83678E+00 -0.0774 40 CaSO4,aq 0.15418E-15 -15.8120 0.15418E-15 -15.8120 0.10000E+01 0.0000 41 HCl,aq 0.17527E-14 -14.7563 0.17527E-14 -14.7563 0.10000E+01 0.0000 45 HF,aq 0.79146E-13 -13.1016 0.79146E-13 -13.1016 0.10000E+01 0.0000 48 FeCl+ 0.58858E-17 -17.2302 0.49251E-17 -17.3076 0.83678E+00 -0.0774 51 FeF+ 0.22969E-18 -18.6389 0.19220E-18 -18.7163 0.83678E+00 -0.0774 53 FeO,aq 0.16996E-09 -9.7697 0.16996E-09 -9.7697 0.10000E+01 0.0000 54 FeOH+ 0.12655E-10 -10.8977 0.10589E-10 -10.9751 0.83678E+00 -0.0774 55 HFeO2- 0.28622E-07 -7.5433 0.23905E-07 -7.6215 0.83518E+00 -0.0782 56 FeO+ 0.12665E-16 -16.8974 0.10597E-16 -16.9748 0.83678E+00 -0.0774 58 FeO2- 0.46916E-09 -9.3287 0.39183E-09 -9.4069 0.83518E+00 -0.0782 59 HFeO2,aq 0.37073E-11 -11.4309 0.37073E-11 -11.4309 0.10000E+01 0.0000 60 H2,aq 0.57003E-05 -5.2441 0.56806E-05 -5.2456 0.99654E+00 -0.0015 61 KCl,aq 0.30511E-09 -9.5155 0.30511E-09 -9.5155 0.10000E+01 0.0000 63 KOH,aq 0.75165E-06 -6.1240 0.75165E-06 -6.1240 0.10000E+01 0.0000 64 KSO4- 0.18247E-13 -13.7388 0.15239E-13 -13.8170 0.83518E+00 -0.0782 65 MgCO3,aq 0.16037E-12 -12.7949 0.16037E-12 -12.7949 0.10000E+01 0.0000 66 Mg(HCO3)+ 0.13546E-14 -14.8682 0.11335E-14 -14.9456 0.83678E+00 -0.0774 67 MgCl+ 0.24430E-14 -14.6121 0.20442E-14 -14.6895 0.83678E+00 -0.0774 68 MgF+ 0.10889E-15 -15.9630 0.91112E-16 -16.0404 0.83678E+00 -0.0774 69 MgOH+ 0.68675E-10 -10.1632 0.57466E-10 -10.2406 0.83678E+00 -0.0774 71 MnF+ 0.29973E-16 -16.5233 0.25081E-16 -16.6007 0.83678E+00 -0.0774 72 MnO,aq 0.17929E-08 -8.7464 0.17929E-08 -8.7464 0.10000E+01 0.0000 73 MnOH+ 0.46543E-09 -9.3321 0.38946E-09 -9.4095 0.83678E+00 -0.0774 74 MnO2-2 0.20751E-10 -10.6830 0.10752E-10 -10.9685 0.51815E+00 -0.2855 75 HMnO2- 0.20982E-09 -9.6782 0.17523E-09 -9.7564 0.83518E+00 -0.0782 78 MnCl+ 0.90655E-14 -14.0426 0.75858E-14 -14.1200 0.83678E+00 -0.0774 79 MnSO4,aq 0.20746E-19 -19.6831 0.20746E-19 -19.6831 0.10000E+01 0.0000 80 NaCl,aq 0.70663E-06 -6.1508 0.70663E-06 -6.1508 0.10000E+01 0.0000 81 NaF,aq 0.60341E-09 -9.2194 0.60341E-09 -9.2194 0.10000E+01 0.0000 82 NaOH,aq 0.95781E-04 -4.0187 0.95781E-04 -4.0187 0.10000E+01 0.0000 84 OH- 0.93162E-02 -2.0308 0.77666E-02 -2.1098 0.83367E+00 -0.0790 89 HPO3-2 0.80407E-15 -15.0947 0.41663E-15 -15.3803 0.51815E+00 -0.2855 91 H2PO3- 0.74417E-19 -19.1283 0.62152E-19 -19.2065 0.83518E+00 -0.0782 92 H3PO4,aq 0.91092E-18 -18.0405 0.91092E-18 -18.0405 0.10000E+01 0.0000 93 H2PO4- 0.38635E-10 -10.4130 0.32297E-10 -10.4908 0.83597E+00 -0.0778 94 PO4-3 0.10640E-08 -8.9731 0.25812E-09 -9.5882 0.24259E+00 -0.6151 98 HP2O7-3 0.94952E-18 -18.0225 0.21954E-18 -18.6585 0.23121E+00 -0.6360 99 P2O7-4 0.91470E-17 -17.0387 0.70500E-18 -18.1518 0.77074E-01 -1.1131 100 H2S,aq 0.63583E-08 -8.1967 0.63363E-08 -8.1982 0.99654E+00 -0.0015 101 S2-2 0.57176E-14 -14.2428 0.29626E-14 -14.5283 0.51815E+00 -0.2855 107 SO3-2 0.10533E-16 -16.9774 0.55368E-17 -17.2567 0.52564E+00 -0.2793 108 HSO3- 0.30879E-19 -19.5103 0.25790E-19 -19.5886 0.83518E+00 -0.0782 109 HSO4- 0.64199E-18 -18.1925 0.53773E-18 -18.2694 0.83759E+00 -0.0770 Charge balance for all species = -.6133E-08 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.8853743E-10 -.2227926E-01 -.2241712E+02 0.0000 2 H2O 0.1000000E+01 0.5550486E+02 0.9981985E+06 0.0000 3 Cl- 0.1539460E-03 0.1546529E-03 0.5473379E+01 6.2376 4 SO4-- 0.1444481E-10 -.1578306E-04 -.1513511E+01 9.1320 5 HCO3- 0.4793058E-05 0.2823984E-04 0.1720121E+01 4.7315 6 HS- 0.3299316E-04 0.4878259E-04 0.1610533E+01 5.5687 7 Al+++ 0.9726330E-29 0.5276927E-05 0.1421319E+00 0.7369 8 H4SiO4 0.6977110E-03 0.1353244E-01 0.1298414E+04 -3.1563 9 Ca++ 0.1255895E-06 0.2189770E-06 0.8760904E-02 13.0681 10 Mg++ 0.2112746E-10 0.9318255E-10 0.2261516E-05 9.2920 11 Fe++ 0.4711635E-13 0.2927788E-07 0.1632239E-02 6.6408 12 K+ 0.1565090E-03 0.1572610E-03 0.6138530E+01 6.2455 13 Na+ 0.1986060E-01 0.2230605E-01 0.5119203E+03 8.3482 14 Mn++ 0.1863800E-10 0.2507567E-08 0.1375212E-03 9.2384 15 F- 0.1864668E-06 0.1870705E-06 0.3547787E-02 3.3200 16 HPO4-- 0.4531779E-07 0.4642041E-07 0.4447640E-02 12.6287 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.2000824E-01 -.2000806E-01 -.1788238E-06 0.0000000E+00 2 H2O 0.4984655E+02 0.4984655E+02 -.1433414E-06 0.0000000E+00 3 Cl- 0.1388872E-03 0.1388872E-03 0.0000000E+00 0.0000000E+00 4 SO4-- -.1417331E-04 -.1417410E-04 0.7873818E-09 0.0000000E+00 5 HCO3- 0.2536100E-04 0.2536100E-04 0.0000000E+00 0.0000000E+00 6 HS- 0.4380878E-04 0.4380957E-04 -.7873818E-09 0.0000000E+00 7 Al+++ 0.4775352E-05 0.4738983E-05 0.3636864E-07 0.0000000E+00 8 H4SiO4 0.1215302E-01 0.1215290E-01 0.1165735E-06 0.0000000E+00 9 Ca++ 0.2080835E-06 0.1966539E-06 0.1142960E-07 0.0000000E+00 10 Mg++ 0.8368328E-10 0.8368328E-10 0.0000000E+00 0.0000000E+00 11 Fe++ 0.3259227E-07 0.2629322E-07 0.6299054E-08 0.0000000E+00 12 K+ 0.1412294E-03 0.1412294E-03 0.0000000E+00 0.0000000E+00 13 Na+ 0.2003215E-01 0.2003211E-01 0.3504796E-07 0.0000000E+00 14 Mn++ 0.2251939E-08 0.2251939E-08 0.0000000E+00 0.0000000E+00 15 F- 0.1680000E-06 0.1680000E-06 0.0000000E+00 0.0000000E+00 16 HPO4-- 0.4168819E-07 0.4168819E-07 0.0000000E+00 0.0000000E+00 Chg. balance for solid moles: 0.6617E-23 Mass of aqueous solution: 0.899621E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 0.0001700 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 0.3505E-07 -7.455 0.9190E-05 -5.037 82.88 0.3528E-05 andradite 0.3150E-08 -8.502 0.1601E-05 -5.796 14.43 0.4158E-06 grossular 0.6603E-09 -9.180 0.2975E-06 -6.527 2.683 0.8276E-07 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8267E+00 0.8267E+00 1.0000 -0.083 grossular 0.1733E+00 0.1733E+00 1.0000 -0.761 Solid products produced: Mass = 0.000011 g Volume = 0.000004 cm3 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.0001700 moles log = -3.7696 Original solution: 1000.0103000 g Original solution / Rock added: 5882413.53 (Water/Rock Ratio), log = 6.7696 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0490 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9731E+00 0.9856 0.1006E+01 0.1021E+01 CO2,gas 0.6455E-07 1.0068 0.6818E-07 0.6771E-07 CH4,gas 0.1983E-01 1.0123 0.2106E-01 0.2080E-01 H2,gas 0.7106E-02 1.0006 0.7458E-02 0.7454E-02 H2S,gas 0.1667E-06 0.9959 0.1742E-06 0.1749E-06 S2,gas 0.1952E-28 1.0000 0.2047E-28 0.2047E-28 CO,gas 0.1292E-12 1.0000 0.1355E-12 0.1355E-12 SO3,gas 0.1496E-46 1.0000 0.1569E-46 0.1569E-46 SO2,gas 0.4341E-26 1.0000 0.4554E-26 0.4554E-26 HF,gas 0.1853E-15 1.0000 0.1943E-15 0.1943E-15 HCl,gas 0.2948E-17 1.0000 0.3093E-17 0.3093E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 17 albite -0.38 -0.38 0.00 0.000 -0.13080E-10 23 andradite 39.01 39.01 0.00 0.000 0.00000E+00 24 grossular 32.73 32.73 0.00 0.000 0.00000E+00 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -15.53 -8.87 -2.955 0.15137E+05 -7.166 3 CH4,gas 4.54 1.17 -3.38 -0.844 0.57636E+04 -1.677 4 H2,gas 8.00 4.17 -3.83 -2.186 0.65334E+04 -2.127 5 H2S,gas -6.23 -14.69 -8.46 -4.229 0.14442E+05 -6.759 6 S2,gas -7.34 -37.72 -30.39 -4.675 0.51886E+05 -28.689 7 CO,gas 3.21 -11.35 -14.57 -4.482 0.24873E+05 -12.868 8 SO3,gas 17.12 -31.38 -48.50 -12.126 0.82818E+05 -46.804 9 SO2,gas 0.83 -27.21 -28.04 -7.477 0.47879E+05 -26.342 10 HF,gas 0.47 -16.94 -17.41 -8.705 0.29728E+05 -15.711 11 HCl,gas 5.19 -14.02 -19.21 -9.604 0.32798E+05 -17.510 12 acmite 7.71 6.59 -1.12 -0.116 0.19126E+04 16 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 20 spessartine 24.46 19.72 -4.74 -0.237 0.80888E+04 21 analcite 3.32 2.77 -0.55 -0.061 0.93809E+03 27 annite 20.12 17.44 -2.69 -0.149 0.45889E+04 28 phlogopite 27.06 25.39 -1.68 -0.093 0.28603E+04 30 anorthite 12.71 8.23 -4.48 -0.345 0.76512E+04 33 apatite-OH -18.15 -18.32 -0.16 -0.012 0.27634E+03 34 apatite-F -34.30 -35.25 -0.95 -0.079 0.16244E+04 38 aragonite 0.97 -2.46 -3.42 -1.141 0.58462E+04 39 brucite 12.57 9.29 -3.28 -0.655 0.55947E+04 40 calcite 0.81 -2.46 -3.27 -1.090 0.55820E+04 41 carnegieite-low 9.02 5.93 -3.09 -0.442 0.52838E+04 42 carnegieite-high 10.09 5.93 -4.16 -0.595 0.71108E+04 43 carpholite-Mg 8.58 4.45 -4.13 -0.275 0.70499E+04 44 carpholite-Fe 6.71 1.80 -4.91 -0.327 0.83848E+04 45 celadonite 5.34 3.65 -1.69 -0.100 0.28898E+04 46 celadonite-Fe 3.88 1.00 -2.88 -0.169 0.49151E+04 47 chrysotile 23.89 21.56 -2.33 -0.194 0.39769E+04 49 clinochlore 39.07 38.46 -0.60 -0.019 0.10325E+04 50 daphnite 28.97 25.21 -3.76 -0.117 0.64140E+04 52 chlorite-Al-free 47.17 43.13 -4.05 -0.169 0.69089E+04 54 chloritoid-Fe 9.17 4.96 -4.22 -0.281 0.71975E+04 55 chloritoid-Mn 11.40 7.56 -3.85 -0.256 0.65655E+04 57 coesite -2.38 -3.16 -0.78 -0.260 0.13323E+04 64 cristobalite -2.56 -3.16 -0.60 -0.199 0.10176E+04 66 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71234E+04 68 diaspore 2.87 0.74 -2.14 -0.356 0.36485E+04 69 diamond -3.10 -7.18 -4.08 -1.165 0.69601E+04 70 diopside 16.18 16.05 -0.13 -0.013 0.22870E+03 71 hedenbergite 14.21 13.40 -0.81 -0.081 0.13866E+04 74 enstatite 17.26 12.27 -4.99 -0.499 0.85264E+04 76 clinoenstatite 17.17 12.27 -4.89 -0.489 0.83580E+04 78 epidote 24.67 22.70 -1.97 -0.096 0.33719E+04 79 clinozoisite 22.81 18.88 -3.93 -0.179 0.67070E+04 80 epidote-Fe 29.84 26.51 -3.33 -0.173 0.56834E+04 81 fayalite 14.05 10.13 -3.92 -0.560 0.66941E+04 82 ferrosilite 11.15 6.97 -4.18 -0.418 0.71382E+04 86 gibbsite 4.08 0.74 -3.34 -0.477 0.57070E+04 87 glaucophane 22.97 20.80 -2.18 -0.059 0.37210E+04 88 glaucophane-Fe 17.28 12.84 -4.43 -0.120 0.75707E+04 89 graphite -3.55 -7.18 -3.63 -1.038 0.62023E+04 90 greenalite 16.14 13.61 -2.53 -0.211 0.43196E+04 93 hematite 12.57 9.11 -3.46 -0.419 0.59045E+04 94 heulandite -5.83 -7.55 -1.73 -0.078 0.29455E+04 98 jadeite 4.22 2.77 -1.44 -0.144 0.24636E+04 100 kalsilite 7.58 3.83 -3.76 -0.537 0.64163E+04 101 kaolinite -1.33 -4.84 -3.51 -0.319 0.59864E+04 104 laumontite 2.88 1.92 -0.97 -0.064 0.16507E+04 105 lawsonite 9.62 8.23 -1.39 -0.092 0.23679E+04 106 leucite 4.12 0.67 -3.45 -0.345 0.58891E+04 108 lizardite 23.24 21.56 -1.68 -0.140 0.28695E+04 110 magnetite 20.09 15.75 -4.34 -0.354 0.74078E+04 111 minnesotaite 10.39 7.30 -3.09 -0.182 0.52779E+04 115 manganosite 14.06 9.24 -4.82 -1.205 0.82296E+04 119 microcline -2.49 -2.49 0.00 0.000 0.14370E-01 123 muscovite 2.58 -1.01 -3.60 -0.211 0.61385E+04 124 paragonite 4.24 1.09 -3.15 -0.185 0.53775E+04 125 nepheline 8.34 5.93 -2.41 -0.344 0.41162E+04 131 periclase-Fe 11.63 6.64 -4.99 -1.246 0.85131E+04 137 phlogopite-Na 29.65 27.49 -2.15 -0.120 0.36791E+04 139 prehnite 19.37 18.14 -1.23 -0.072 0.21016E+04 140 prehnite-Fe 22.50 21.96 -0.54 -0.032 0.92146E+03 141 pumpellyite-Fe 46.27 43.66 -2.61 -0.058 0.44558E+04 142 pumpellyite-Mg 48.99 46.31 -2.68 -0.060 0.45826E+04 146 pyrrhotite -4.26 -8.05 -3.79 -1.262 0.64664E+04 147 pyrrhotiteFe0.875 -6.02 -9.40 -3.38 -1.242 0.57680E+04 148 pyroxmangite 7.40 6.08 -1.32 -0.263 0.22481E+04 149 pyrophyllite -6.18 -11.15 -4.98 -0.311 0.84957E+04 150 quartz -2.99 -3.16 -0.17 -0.056 0.28496E+03 155 rhodonite 7.45 6.08 -1.36 -0.273 0.23284E+04 156 sanidine -1.28 -2.49 -1.21 -0.093 0.20678E+04 166 stilbite -7.52 -7.55 -0.03 -0.001 0.51668E+02 167 stilpnomelane-Fe 13.02 12.55 -0.47 -0.014 0.79740E+03 168 stilpnomelane-Mg 27.44 25.81 -1.64 -0.049 0.27925E+04 174 talc 16.49 15.25 -1.24 -0.073 0.21180E+04 177 tephroite 18.09 15.32 -2.77 -0.395 0.47218E+04 181 tridymite -2.63 -3.16 -0.53 -0.177 0.90494E+03 182 tremolite 47.87 47.35 -0.52 -0.014 0.89433E+03 183 ferroactinolite 38.45 34.09 -4.36 -0.118 0.74495E+04 184 troilite-low -4.41 -8.05 -3.64 -1.212 0.62092E+04 190 wairakite 3.95 1.92 -2.03 -0.120 0.34727E+04 191 walstromite 11.51 9.91 -1.60 -0.319 0.27276E+04 192 wollastonite 10.46 9.91 -0.55 -0.110 0.93807E+03 193 pseudo-wollastonite 11.00 9.91 -1.09 -0.218 0.18579E+04 194 zoisite 22.85 18.88 -3.97 -0.181 0.67811E+04 195 akaganeite 7.75 4.55 -3.20 -0.692 0.54648E+04 202 chalcedony -2.80 -3.16 -0.35 -0.118 0.60426E+03 204 montmorillonite-Ca -2.29 -6.17 -3.88 -0.240 0.66272E+04 205 montmorillonite-K -2.24 -6.27 -4.03 -0.247 0.68820E+04 206 montmorillonite-Mg -2.48 -6.80 -4.32 -0.267 0.73681E+04 207 montmorillonite-Na -2.04 -5.57 -3.54 -0.217 0.60369E+04 208 nontronite-Ca 3.21 -0.08 -3.29 -0.213 0.56187E+04 209 nontronite-H 2.53 -2.23 -4.77 -0.319 0.81362E+04 210 nontronite-K 3.34 -0.17 -3.51 -0.225 0.59967E+04 211 nontronite-Mg 3.07 -0.70 -3.77 -0.245 0.64437E+04 212 nontronite-Na 3.52 0.52 -3.00 -0.192 0.51176E+04 228 tobermorite 9.82 7.73 -2.09 -0.571 0.35749E+04 234 alabandite -0.98 -5.45 -4.47 -1.491 0.76358E+04 237 boehmite 4.41 0.74 -3.67 -0.612 0.62654E+04 239 ferrous-oxide 9.81 6.64 -3.17 -0.793 0.54141E+04 245 silica-amorphous -2.09 -3.16 -1.06 -0.355 0.18184E+04 247 an20ab80 2.02 1.34 -0.68 -0.052 0.11594E+04 248 an25ab75 2.65 1.77 -0.88 -0.067 0.14962E+04 249 an30ab70 3.28 2.20 -1.08 -0.083 0.18426E+04 250 tr.625ac.25prg.125 45.16 44.98 -0.19 -0.005 0.31726E+03 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 0.0000100 MOLES Current total amount of reactant added: 0.0001700 MOLES New total amount of reactant added: 0.0001800 MOLES Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.5508E-08 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 6 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 0.0001800 Water: Moles liquid = 0.4985E+02 kg liquid = 0.8981E+00 Moles total = 0.4985E+02 kg total = 0.8980E+00 Activity = 1.0000 Stoichiometric ionic strength = .1134169E-01 Osmotic coef. = 0.9687 True ionic strength = .2002730E-01 Chg. balance for total moles = -.5508E-08 Max. difference allowed = 0.1389E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.88553E-10 -10.0528 0.74405E-10 -10.1284 0.84023E+00 -0.0756 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.15401E-03 -3.8124 0.12863E-03 -3.8907 0.83517E+00 -0.0782 4 SO4-- 0.15477E-10 -10.8103 0.80363E-11 -11.0949 0.51925E+00 -0.2846 5 HCO3- 0.50825E-05 -5.2939 0.42510E-05 -5.3715 0.83640E+00 -0.0776 6 HS- 0.33264E-04 -4.4780 0.27785E-04 -4.5562 0.83530E+00 -0.0782 7 Al+++ 0.97285E-29 -29.0120 0.22470E-29 -29.6484 0.23097E+00 -0.6364 8 H4SiO4 0.69782E-03 -3.1563 0.69782E-03 -3.1563 0.10000E+01 0.0000 9 Ca++ 0.12535E-06 -6.9019 0.64612E-07 -7.1897 0.51543E+00 -0.2878 10 Mg++ 0.21128E-10 -10.6751 0.10840E-10 -10.9650 0.51308E+00 -0.2898 11 Fe++ 0.46954E-13 -13.3283 0.24117E-13 -13.6177 0.51364E+00 -0.2893 12 K+ 0.15651E-03 -3.8055 0.13093E-03 -3.8829 0.83659E+00 -0.0775 13 Na+ 0.19861E-01 -1.7020 0.16584E-01 -1.7803 0.83502E+00 -0.0783 14 Mn++ 0.18644E-10 -10.7295 0.95843E-11 -11.0184 0.51406E+00 -0.2890 15 F- 0.19091E-06 -6.7192 0.15911E-06 -6.7983 0.83345E+00 -0.0791 16 HPO4-- 0.45318E-07 -7.3437 0.23535E-07 -7.6283 0.51932E+00 -0.2846 18 HSiO3- 0.10486E-01 -1.9794 0.87573E-02 -2.0576 0.83517E+00 -0.0782 19 Ca(HSiO3)+ 0.15400E-07 -7.8125 0.12886E-07 -7.8899 0.83677E+00 -0.0774 20 Mg(HSiO3)+ 0.32154E-11 -11.4928 0.26906E-11 -11.5702 0.83677E+00 -0.0774 21 NaHSiO3,aq 0.23489E-02 -2.6291 0.23489E-02 -2.6291 0.10000E+01 0.0000 22 AlO+ 0.65989E-16 -16.1805 0.55218E-16 -16.2579 0.83677E+00 -0.0774 24 HAlO2,aq 0.14779E-09 -9.8303 0.14779E-09 -9.8303 0.10000E+01 0.0000 25 AlO2- 0.52742E-05 -5.2778 0.43969E-05 -5.3568 0.83367E+00 -0.0790 26 CH4,aq 0.14326E-04 -4.8439 0.14277E-04 -4.8454 0.99654E+00 -0.0015 27 C2H6,aq 0.62501E-14 -14.2041 0.62284E-14 -14.2056 0.99654E+00 -0.0015 31 CO,aq 0.94984E-16 -16.0223 0.94984E-16 -16.0223 0.10000E+01 0.0000 32 CO2,aq 0.67819E-09 -9.1687 0.67584E-09 -9.1702 0.99654E+00 -0.0015 33 CO3-2 0.96312E-05 -5.0163 0.49904E-05 -5.3019 0.51814E+00 -0.2855 34 CaCO3,aq 0.40430E-08 -8.3933 0.40430E-08 -8.3933 0.10000E+01 0.0000 35 Ca(HCO3)+ 0.83786E-11 -11.0768 0.70110E-11 -11.1542 0.83677E+00 -0.0774 36 CaCl+ 0.16073E-10 -10.7939 0.13449E-10 -10.8713 0.83677E+00 -0.0774 37 CaCl2,aq 0.41100E-15 -15.3862 0.41100E-15 -15.3862 0.10000E+01 0.0000 38 CaF+ 0.17937E-12 -12.7462 0.15010E-12 -12.8236 0.83677E+00 -0.0774 39 CaOH+ 0.73961E-07 -7.1310 0.61889E-07 -7.2084 0.83677E+00 -0.0774 40 CaSO4,aq 0.16488E-15 -15.7828 0.16488E-15 -15.7828 0.10000E+01 0.0000 41 HCl,aq 0.17537E-14 -14.7560 0.17537E-14 -14.7560 0.10000E+01 0.0000 45 HF,aq 0.81044E-13 -13.0913 0.81044E-13 -13.0913 0.10000E+01 0.0000 48 FeCl+ 0.58680E-17 -17.2315 0.49102E-17 -17.3089 0.83677E+00 -0.0774 51 FeF+ 0.23435E-18 -18.6301 0.19610E-18 -18.7075 0.83677E+00 -0.0774 53 FeO,aq 0.16932E-09 -9.7713 0.16932E-09 -9.7713 0.10000E+01 0.0000 54 FeOH+ 0.12609E-10 -10.8993 0.10551E-10 -10.9767 0.83677E+00 -0.0774 55 HFeO2- 0.28509E-07 -7.5450 0.23810E-07 -7.6232 0.83517E+00 -0.0782 56 FeO+ 0.12715E-16 -16.8957 0.10640E-16 -16.9731 0.83677E+00 -0.0774 58 FeO2- 0.47088E-09 -9.3271 0.39326E-09 -9.4053 0.83517E+00 -0.0782 59 HFeO2,aq 0.37215E-11 -11.4293 0.37215E-11 -11.4293 0.10000E+01 0.0000 60 H2,aq 0.56141E-05 -5.2507 0.55946E-05 -5.2522 0.99654E+00 -0.0015 61 KCl,aq 0.30524E-09 -9.5154 0.30524E-09 -9.5154 0.10000E+01 0.0000 63 KOH,aq 0.75152E-06 -6.1241 0.75152E-06 -6.1241 0.10000E+01 0.0000 64 KSO4- 0.19550E-13 -13.7088 0.16328E-13 -13.7871 0.83517E+00 -0.0782 65 MgCO3,aq 0.17002E-12 -12.7695 0.17002E-12 -12.7695 0.10000E+01 0.0000 66 Mg(HCO3)+ 0.14364E-14 -14.8427 0.12019E-14 -14.9201 0.83677E+00 -0.0774 67 MgCl+ 0.24441E-14 -14.6119 0.20452E-14 -14.6893 0.83677E+00 -0.0774 68 MgF+ 0.11148E-15 -15.9528 0.93283E-16 -16.0302 0.83677E+00 -0.0774 69 MgOH+ 0.68665E-10 -10.1633 0.57457E-10 -10.2407 0.83677E+00 -0.0774 71 MnF+ 0.30697E-16 -16.5129 0.25686E-16 -16.5903 0.83677E+00 -0.0774 72 MnO,aq 0.17929E-08 -8.7464 0.17929E-08 -8.7464 0.10000E+01 0.0000 73 MnOH+ 0.46550E-09 -9.3321 0.38952E-09 -9.4095 0.83677E+00 -0.0774 74 MnO2-2 0.20743E-10 -10.6831 0.10748E-10 -10.9687 0.51814E+00 -0.2855 75 HMnO2- 0.20978E-09 -9.6782 0.17520E-09 -9.7565 0.83517E+00 -0.0782 78 MnCl+ 0.90723E-14 -14.0423 0.75915E-14 -14.1197 0.83677E+00 -0.0774 79 MnSO4,aq 0.22236E-19 -19.6529 0.22236E-19 -19.6529 0.10000E+01 0.0000 80 NaCl,aq 0.70693E-06 -6.1506 0.70693E-06 -6.1506 0.10000E+01 0.0000 81 NaF,aq 0.61777E-09 -9.2092 0.61777E-09 -9.2092 0.10000E+01 0.0000 82 NaOH,aq 0.95765E-04 -4.0188 0.95765E-04 -4.0188 0.10000E+01 0.0000 84 OH- 0.93146E-02 -2.0308 0.77653E-02 -2.1098 0.83367E+00 -0.0790 89 HPO3-2 0.79190E-15 -15.1013 0.41032E-15 -15.3869 0.51814E+00 -0.2855 91 H2PO3- 0.73304E-19 -19.1349 0.61221E-19 -19.2131 0.83517E+00 -0.0782 92 H3PO4,aq 0.91123E-18 -18.0404 0.91123E-18 -18.0404 0.10000E+01 0.0000 93 H2PO4- 0.38641E-10 -10.4130 0.32303E-10 -10.4908 0.83597E+00 -0.0778 94 PO4-3 0.10638E-08 -8.9731 0.25807E-09 -9.5883 0.24259E+00 -0.6151 98 HP2O7-3 0.94970E-18 -18.0224 0.21957E-18 -18.6584 0.23120E+00 -0.6360 99 P2O7-4 0.91472E-17 -17.0387 0.70499E-18 -18.1518 0.77072E-01 -1.1131 100 H2S,aq 0.64115E-08 -8.1930 0.63893E-08 -8.1945 0.99654E+00 -0.0015 101 S2-2 0.59011E-14 -14.2291 0.30576E-14 -14.5146 0.51814E+00 -0.2855 107 SO3-2 0.11115E-16 -16.9541 0.58425E-17 -17.2334 0.52564E+00 -0.2793 108 HSO3- 0.32590E-19 -19.4869 0.27218E-19 -19.5651 0.83517E+00 -0.0782 109 HSO4- 0.68797E-18 -18.1624 0.57624E-18 -18.2394 0.83759E+00 -0.0770 Charge balance for all species = -.6133E-08 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.8855287E-10 -.2227805E-01 -.2241590E+02 0.0000 2 H2O 0.1000000E+01 0.5550486E+02 0.9981984E+06 0.0000 3 Cl- 0.1540113E-03 0.1547186E-03 0.5475703E+01 6.2377 4 SO4-- 0.1547678E-10 -.1572991E-04 -.1508413E+01 9.1619 5 HCO3- 0.5082493E-05 0.2904491E-04 0.1769158E+01 4.7569 6 HS- 0.3326368E-04 0.4900001E-04 0.1617711E+01 5.5722 7 Al+++ 0.9728503E-29 0.5274383E-05 0.1420634E+00 0.7368 8 H4SiO4 0.6978236E-03 0.1353243E-01 0.1298413E+04 -3.1563 9 Ca++ 0.1253536E-06 0.2187822E-06 0.8753109E-02 13.0671 10 Mg++ 0.2112804E-10 0.9318254E-10 0.2261516E-05 9.2918 11 Fe++ 0.4695410E-13 0.2916543E-07 0.1625970E-02 6.6391 12 K+ 0.1565091E-03 0.1572610E-03 0.6138529E+01 6.2455 13 Na+ 0.1986064E-01 0.2230605E-01 0.5119201E+03 8.3481 14 Mn++ 0.1864424E-10 0.2507566E-08 0.1375212E-03 9.2384 15 F- 0.1909064E-06 0.1915245E-06 0.3632257E-02 3.3301 16 HPO4-- 0.4531794E-07 0.4642040E-07 0.4447639E-02 12.6285 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.2000716E-01 -.2000697E-01 -.1884821E-06 0.0000000E+00 2 H2O 0.4984656E+02 0.4984656E+02 -.1524640E-06 0.0000000E+00 3 Cl- 0.1389462E-03 0.1389462E-03 0.0000000E+00 0.0000000E+00 4 SO4-- -.1412556E-04 -.1412636E-04 0.8000049E-09 0.0000000E+00 5 HCO3- 0.2608400E-04 0.2608400E-04 0.0000000E+00 0.0000000E+00 6 HS- 0.4400403E-04 0.4400483E-04 -.8000049E-09 0.0000000E+00 7 Al+++ 0.4775352E-05 0.4736700E-05 0.3865231E-07 0.0000000E+00 8 H4SiO4 0.1215302E-01 0.1215290E-01 0.1235525E-06 0.0000000E+00 9 Ca++ 0.2080835E-06 0.1964790E-06 0.1160454E-07 0.0000000E+00 10 Mg++ 0.8368328E-10 0.8368328E-10 0.0000000E+00 0.0000000E+00 11 Fe++ 0.3259227E-07 0.2619223E-07 0.6400039E-08 0.0000000E+00 12 K+ 0.1412294E-03 0.1412294E-03 0.0000000E+00 0.0000000E+00 13 Na+ 0.2003215E-01 0.2003211E-01 0.3731599E-07 0.0000000E+00 14 Mn++ 0.2251939E-08 0.2251939E-08 0.0000000E+00 0.0000000E+00 15 F- 0.1720000E-06 0.1720000E-06 0.0000000E+00 0.0000000E+00 16 HPO4-- 0.4168819E-07 0.4168819E-07 0.0000000E+00 0.0000000E+00 Chg. balance for solid moles: 0.6617E-23 Mass of aqueous solution: 0.899621E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 0.0001800 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 0.3732E-07 -7.428 0.9785E-05 -5.009 83.55 0.3756E-05 andradite 0.3200E-08 -8.495 0.1626E-05 -5.789 13.88 0.4225E-06 grossular 0.6682E-09 -9.175 0.3010E-06 -6.521 2.570 0.8374E-07 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8273E+00 0.8273E+00 1.0000 -0.082 grossular 0.1727E+00 0.1727E+00 1.0000 -0.763 Solid products produced: Mass = 0.000012 g Volume = 0.000004 cm3 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.0001800 moles log = -3.7447 Original solution: 1000.0103000 g Original solution / Rock added: 5555612.78 (Water/Rock Ratio), log = 6.7447 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0488 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9732E+00 0.9856 0.1006E+01 0.1021E+01 CO2,gas 0.6847E-07 1.0068 0.7231E-07 0.7182E-07 CH4,gas 0.1979E-01 1.0123 0.2101E-01 0.2076E-01 H2,gas 0.6999E-02 1.0006 0.7345E-02 0.7341E-02 H2S,gas 0.1682E-06 0.9959 0.1756E-06 0.1764E-06 S2,gas 0.2046E-28 1.0000 0.2146E-28 0.2146E-28 CO,gas 0.1350E-12 1.0000 0.1415E-12 0.1415E-12 SO3,gas 0.1604E-46 1.0000 0.1682E-46 0.1682E-46 SO2,gas 0.4583E-26 1.0000 0.4807E-26 0.4807E-26 HF,gas 0.1897E-15 1.0000 0.1990E-15 0.1990E-15 HCl,gas 0.2951E-17 1.0000 0.3095E-17 0.3095E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 17 albite -0.38 -0.38 0.00 0.000 -0.13080E-10 23 andradite 39.01 39.01 0.00 0.000 0.00000E+00 24 grossular 32.73 32.73 0.00 0.000 0.12132E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -15.50 -8.84 -2.947 0.15094E+05 -7.141 3 CH4,gas 4.54 1.17 -3.38 -0.844 0.57652E+04 -1.677 4 H2,gas 8.00 4.17 -3.83 -2.190 0.65447E+04 -2.134 5 H2S,gas -6.23 -14.68 -8.45 -4.227 0.14436E+05 -6.755 6 S2,gas -7.34 -37.70 -30.37 -4.672 0.51851E+05 -28.668 7 CO,gas 3.21 -11.33 -14.55 -4.476 0.24840E+05 -12.849 8 SO3,gas 17.12 -31.35 -48.47 -12.118 0.82767E+05 -46.774 9 SO2,gas 0.83 -27.18 -28.02 -7.471 0.47838E+05 -26.318 10 HF,gas 0.47 -16.93 -17.40 -8.700 0.29710E+05 -15.701 11 HCl,gas 5.19 -14.02 -19.21 -9.604 0.32798E+05 -17.509 12 acmite 7.71 6.59 -1.12 -0.116 0.19096E+04 16 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 20 spessartine 24.46 19.72 -4.74 -0.237 0.80890E+04 21 analcite 3.32 2.77 -0.55 -0.061 0.93821E+03 27 annite 20.12 17.43 -2.69 -0.150 0.45974E+04 28 phlogopite 27.06 25.39 -1.68 -0.093 0.28610E+04 30 anorthite 12.71 8.23 -4.48 -0.345 0.76531E+04 33 apatite-OH -18.15 -18.32 -0.17 -0.013 0.28386E+03 34 apatite-F -34.30 -35.25 -0.95 -0.079 0.16143E+04 38 aragonite 0.97 -2.43 -3.40 -1.133 0.58042E+04 39 brucite 12.57 9.29 -3.28 -0.655 0.55949E+04 40 calcite 0.81 -2.43 -3.24 -1.082 0.55400E+04 41 carnegieite-low 9.02 5.93 -3.09 -0.442 0.52840E+04 42 carnegieite-high 10.09 5.93 -4.16 -0.595 0.71110E+04 43 carpholite-Mg 8.58 4.45 -4.13 -0.275 0.70504E+04 44 carpholite-Fe 6.71 1.80 -4.91 -0.327 0.83878E+04 45 celadonite 5.34 3.65 -1.69 -0.100 0.28899E+04 46 celadonite-Fe 3.88 1.00 -2.88 -0.169 0.49178E+04 47 chrysotile 23.89 21.56 -2.33 -0.194 0.39773E+04 49 clinochlore 39.07 38.46 -0.61 -0.019 0.10338E+04 50 daphnite 28.97 25.20 -3.76 -0.118 0.64282E+04 52 chlorite-Al-free 47.17 43.13 -4.05 -0.169 0.69099E+04 54 chloritoid-Fe 9.17 4.96 -4.22 -0.281 0.72006E+04 55 chloritoid-Mn 11.40 7.56 -3.85 -0.256 0.65658E+04 57 coesite -2.38 -3.16 -0.78 -0.260 0.13322E+04 64 cristobalite -2.56 -3.16 -0.60 -0.199 0.10175E+04 66 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71234E+04 68 diaspore 2.87 0.74 -2.14 -0.356 0.36487E+04 69 diamond -3.10 -7.17 -4.06 -1.161 0.69391E+04 70 diopside 16.18 16.05 -0.13 -0.013 0.23036E+03 71 hedenbergite 14.21 13.39 -0.81 -0.081 0.13908E+04 74 enstatite 17.26 12.27 -4.99 -0.499 0.85267E+04 76 clinoenstatite 17.17 12.27 -4.90 -0.490 0.83583E+04 78 epidote 24.67 22.69 -1.98 -0.096 0.33725E+04 79 clinozoisite 22.81 18.88 -3.93 -0.179 0.67106E+04 80 epidote-Fe 29.84 26.51 -3.33 -0.173 0.56809E+04 81 fayalite 14.05 10.12 -3.92 -0.561 0.66996E+04 82 ferrosilite 11.15 6.97 -4.18 -0.418 0.71436E+04 86 gibbsite 4.08 0.74 -3.34 -0.478 0.57072E+04 87 glaucophane 22.97 20.80 -2.18 -0.059 0.37215E+04 88 glaucophane-Fe 17.28 12.84 -4.44 -0.120 0.75789E+04 89 graphite -3.55 -7.17 -3.62 -1.034 0.61813E+04 90 greenalite 16.14 13.60 -2.53 -0.211 0.43278E+04 93 hematite 12.57 9.11 -3.45 -0.419 0.58988E+04 94 heulandite -5.83 -7.55 -1.73 -0.078 0.29468E+04 98 jadeite 4.22 2.77 -1.44 -0.144 0.24637E+04 100 kalsilite 7.58 3.83 -3.76 -0.537 0.64165E+04 101 kaolinite -1.33 -4.84 -3.51 -0.319 0.59866E+04 104 laumontite 2.88 1.92 -0.97 -0.065 0.16523E+04 105 lawsonite 9.62 8.23 -1.39 -0.093 0.23697E+04 106 leucite 4.12 0.67 -3.45 -0.345 0.58893E+04 108 lizardite 23.24 21.56 -1.68 -0.140 0.28700E+04 110 magnetite 20.09 15.75 -4.34 -0.354 0.74049E+04 111 minnesotaite 10.39 7.29 -3.10 -0.182 0.52859E+04 115 manganosite 14.06 9.24 -4.82 -1.205 0.82296E+04 119 microcline -2.49 -2.49 0.00 0.000 0.15201E-01 123 muscovite 2.58 -1.01 -3.60 -0.211 0.61389E+04 124 paragonite 4.24 1.09 -3.15 -0.185 0.53780E+04 125 nepheline 8.34 5.93 -2.41 -0.344 0.41164E+04 131 periclase-Fe 11.63 6.64 -4.99 -1.247 0.85159E+04 137 phlogopite-Na 29.65 27.49 -2.16 -0.120 0.36798E+04 139 prehnite 19.37 18.14 -1.23 -0.073 0.21050E+04 140 prehnite-Fe 22.50 21.96 -0.54 -0.032 0.92180E+03 141 pumpellyite-Fe 46.27 43.65 -2.62 -0.058 0.44657E+04 142 pumpellyite-Mg 48.99 46.31 -2.69 -0.060 0.45899E+04 146 pyrrhotite -4.26 -8.05 -3.79 -1.262 0.64630E+04 147 pyrrhotiteFe0.875 -6.02 -9.39 -3.38 -1.241 0.57629E+04 148 pyroxmangite 7.40 6.08 -1.32 -0.263 0.22480E+04 149 pyrophyllite -6.18 -11.15 -4.98 -0.311 0.84957E+04 150 quartz -2.99 -3.16 -0.17 -0.056 0.28484E+03 155 rhodonite 7.45 6.08 -1.36 -0.273 0.23283E+04 156 sanidine -1.28 -2.49 -1.21 -0.093 0.20678E+04 166 stilbite -7.52 -7.55 -0.03 -0.001 0.52949E+02 167 stilpnomelane-Fe 13.02 12.54 -0.48 -0.014 0.81107E+03 168 stilpnomelane-Mg 27.44 25.81 -1.64 -0.049 0.27932E+04 174 talc 16.49 15.25 -1.24 -0.073 0.21182E+04 177 tephroite 18.09 15.32 -2.77 -0.395 0.47217E+04 181 tridymite -2.63 -3.16 -0.53 -0.177 0.90482E+03 182 tremolite 47.87 47.34 -0.53 -0.014 0.89789E+03 183 ferroactinolite 38.45 34.08 -4.37 -0.118 0.74660E+04 184 troilite-low -4.41 -8.05 -3.63 -1.212 0.62058E+04 190 wairakite 3.95 1.92 -2.03 -0.120 0.34743E+04 191 walstromite 11.51 9.91 -1.60 -0.320 0.27292E+04 192 wollastonite 10.46 9.91 -0.55 -0.110 0.93961E+03 193 pseudo-wollastonite 11.00 9.91 -1.09 -0.218 0.18594E+04 194 zoisite 22.85 18.88 -3.97 -0.181 0.67847E+04 195 akaganeite 7.75 4.56 -3.20 -0.692 0.54619E+04 202 chalcedony -2.80 -3.16 -0.35 -0.118 0.60414E+03 204 montmorillonite-Ca -2.29 -6.17 -3.88 -0.240 0.66275E+04 205 montmorillonite-K -2.24 -6.27 -4.03 -0.247 0.68820E+04 206 montmorillonite-Mg -2.48 -6.80 -4.32 -0.267 0.73681E+04 207 montmorillonite-Na -2.04 -5.57 -3.54 -0.217 0.60369E+04 208 nontronite-Ca 3.21 -0.07 -3.29 -0.213 0.56130E+04 209 nontronite-H 2.53 -2.23 -4.76 -0.319 0.81302E+04 210 nontronite-K 3.34 -0.17 -3.51 -0.225 0.59907E+04 211 nontronite-Mg 3.07 -0.70 -3.77 -0.245 0.64377E+04 212 nontronite-Na 3.52 0.53 -2.99 -0.192 0.51116E+04 228 tobermorite 9.82 7.73 -2.09 -0.571 0.35761E+04 234 alabandite -0.98 -5.45 -4.47 -1.489 0.76296E+04 237 boehmite 4.41 0.74 -3.67 -0.612 0.62656E+04 239 ferrous-oxide 9.81 6.64 -3.17 -0.793 0.54169E+04 245 silica-amorphous -2.09 -3.16 -1.06 -0.355 0.18183E+04 247 an20ab80 2.02 1.34 -0.68 -0.052 0.11598E+04 248 an25ab75 2.65 1.77 -0.88 -0.067 0.14967E+04 249 an30ab70 3.28 2.20 -1.08 -0.083 0.18432E+04 250 tr.625ac.25prg.125 45.16 44.97 -0.19 -0.005 0.32414E+03 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 0.0000100 MOLES Current total amount of reactant added: 0.0001800 MOLES New total amount of reactant added: 0.0001900 MOLES Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.5508E-08 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 6 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 0.0001900 Water: Moles liquid = 0.4985E+02 kg liquid = 0.8981E+00 Moles total = 0.4985E+02 kg total = 0.8980E+00 Activity = 1.0000 Stoichiometric ionic strength = .1134233E-01 Osmotic coef. = 0.9687 True ionic strength = .2002788E-01 Chg. balance for total moles = -.5508E-08 Max. difference allowed = 0.1390E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.88568E-10 -10.0527 0.74417E-10 -10.1283 0.84023E+00 -0.0756 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.15408E-03 -3.8123 0.12868E-03 -3.8905 0.83517E+00 -0.0782 4 SO4-- 0.16531E-10 -10.7817 0.85836E-11 -11.0663 0.51924E+00 -0.2846 5 HCO3- 0.53725E-05 -5.2698 0.44935E-05 -5.3474 0.83639E+00 -0.0776 6 HS- 0.33534E-04 -4.4745 0.28011E-04 -4.5527 0.83529E+00 -0.0782 7 Al+++ 0.97307E-29 -29.0119 0.22475E-29 -29.6483 0.23097E+00 -0.6365 8 H4SiO4 0.69794E-03 -3.1562 0.69794E-03 -3.1562 0.10000E+01 0.0000 9 Ca++ 0.12513E-06 -6.9027 0.64494E-07 -7.1905 0.51543E+00 -0.2878 10 Mg++ 0.21129E-10 -10.6751 0.10840E-10 -10.9650 0.51307E+00 -0.2898 11 Fe++ 0.46805E-13 -13.3297 0.24040E-13 -13.6191 0.51363E+00 -0.2893 12 K+ 0.15651E-03 -3.8055 0.13093E-03 -3.8829 0.83659E+00 -0.0775 13 Na+ 0.19861E-01 -1.7020 0.16584E-01 -1.7803 0.83502E+00 -0.0783 14 Mn++ 0.18650E-10 -10.7293 0.95875E-11 -11.0183 0.51406E+00 -0.2890 15 F- 0.19535E-06 -6.7092 0.16281E-06 -6.7883 0.83345E+00 -0.0791 16 HPO4-- 0.45318E-07 -7.3437 0.23534E-07 -7.6283 0.51932E+00 -0.2846 18 HSiO3- 0.10486E-01 -1.9794 0.87572E-02 -2.0576 0.83517E+00 -0.0782 19 Ca(HSiO3)+ 0.15371E-07 -7.8133 0.12862E-07 -7.8907 0.83677E+00 -0.0774 20 Mg(HSiO3)+ 0.32155E-11 -11.4928 0.26906E-11 -11.5701 0.83677E+00 -0.0774 21 NaHSiO3,aq 0.23489E-02 -2.6291 0.23489E-02 -2.6291 0.10000E+01 0.0000 22 AlO+ 0.65980E-16 -16.1806 0.55210E-16 -16.2580 0.83677E+00 -0.0774 24 HAlO2,aq 0.14775E-09 -9.8305 0.14775E-09 -9.8305 0.10000E+01 0.0000 25 AlO2- 0.52717E-05 -5.2781 0.43948E-05 -5.3571 0.83366E+00 -0.0790 26 CH4,aq 0.14293E-04 -4.8449 0.14244E-04 -4.8464 0.99654E+00 -0.0015 27 C2H6,aq 0.63121E-14 -14.1998 0.62903E-14 -14.2013 0.99654E+00 -0.0015 31 CO,aq 0.98976E-16 -16.0045 0.98976E-16 -16.0045 0.10000E+01 0.0000 32 CO2,aq 0.71700E-09 -9.1445 0.71452E-09 -9.1460 0.99654E+00 -0.0015 33 CO3-2 0.10179E-04 -4.9923 0.52742E-05 -5.2778 0.51814E+00 -0.2856 34 CaCO3,aq 0.42651E-08 -8.3701 0.42651E-08 -8.3701 0.10000E+01 0.0000 35 Ca(HCO3)+ 0.88405E-11 -11.0535 0.73975E-11 -11.1309 0.83677E+00 -0.0774 36 CaCl+ 0.16050E-10 -10.7945 0.13431E-10 -10.8719 0.83677E+00 -0.0774 37 CaCl2,aq 0.41060E-15 -15.3866 0.41060E-15 -15.3866 0.10000E+01 0.0000 38 CaF+ 0.18321E-12 -12.7370 0.15331E-12 -12.8144 0.83677E+00 -0.0774 39 CaOH+ 0.73814E-07 -7.1319 0.61766E-07 -7.2093 0.83677E+00 -0.0774 40 CaSO4,aq 0.17579E-15 -15.7550 0.17579E-15 -15.7550 0.10000E+01 0.0000 41 HCl,aq 0.17548E-14 -14.7558 0.17548E-14 -14.7558 0.10000E+01 0.0000 45 HF,aq 0.82943E-13 -13.0812 0.82943E-13 -13.0812 0.10000E+01 0.0000 48 FeCl+ 0.58517E-17 -17.2327 0.48966E-17 -17.3101 0.83677E+00 -0.0774 51 FeF+ 0.23903E-18 -18.6215 0.20002E-18 -18.6989 0.83677E+00 -0.0774 53 FeO,aq 0.16872E-09 -9.7728 0.16872E-09 -9.7728 0.10000E+01 0.0000 54 FeOH+ 0.12567E-10 -10.9008 0.10516E-10 -10.9782 0.83677E+00 -0.0774 55 HFeO2- 0.28403E-07 -7.5466 0.23722E-07 -7.6249 0.83517E+00 -0.0782 56 FeO+ 0.12765E-16 -16.8940 0.10681E-16 -16.9714 0.83677E+00 -0.0774 58 FeO2- 0.47254E-09 -9.3256 0.39466E-09 -9.4038 0.83517E+00 -0.0782 59 HFeO2,aq 0.37353E-11 -11.4277 0.37353E-11 -11.4277 0.10000E+01 0.0000 60 H2,aq 0.55333E-05 -5.2570 0.55142E-05 -5.2585 0.99654E+00 -0.0015 61 KCl,aq 0.30537E-09 -9.5152 0.30537E-09 -9.5152 0.10000E+01 0.0000 63 KOH,aq 0.75139E-06 -6.1241 0.75139E-06 -6.1241 0.10000E+01 0.0000 64 KSO4- 0.20882E-13 -13.6802 0.17440E-13 -13.7585 0.83517E+00 -0.0782 65 MgCO3,aq 0.17970E-12 -12.7455 0.17970E-12 -12.7455 0.10000E+01 0.0000 66 Mg(HCO3)+ 0.15184E-14 -14.8186 0.12705E-14 -14.8960 0.83677E+00 -0.0774 67 MgCl+ 0.24452E-14 -14.6117 0.20461E-14 -14.6891 0.83677E+00 -0.0774 68 MgF+ 0.11407E-15 -15.9428 0.95454E-16 -16.0202 0.83677E+00 -0.0774 69 MgOH+ 0.68655E-10 -10.1633 0.57448E-10 -10.2407 0.83677E+00 -0.0774 71 MnF+ 0.31421E-16 -16.5028 0.26292E-16 -16.5802 0.83677E+00 -0.0774 72 MnO,aq 0.17929E-08 -8.7465 0.17929E-08 -8.7465 0.10000E+01 0.0000 73 MnOH+ 0.46557E-09 -9.3320 0.38958E-09 -9.4094 0.83677E+00 -0.0774 74 MnO2-2 0.20736E-10 -10.6833 0.10744E-10 -10.9688 0.51814E+00 -0.2856 75 HMnO2- 0.20974E-09 -9.6783 0.17517E-09 -9.7565 0.83517E+00 -0.0782 78 MnCl+ 0.90791E-14 -14.0420 0.75972E-14 -14.1193 0.83677E+00 -0.0774 79 MnSO4,aq 0.23758E-19 -19.6242 0.23758E-19 -19.6242 0.10000E+01 0.0000 80 NaCl,aq 0.70723E-06 -6.1504 0.70723E-06 -6.1504 0.10000E+01 0.0000 81 NaF,aq 0.63214E-09 -9.1992 0.63214E-09 -9.1992 0.10000E+01 0.0000 82 NaOH,aq 0.95748E-04 -4.0189 0.95748E-04 -4.0189 0.10000E+01 0.0000 84 OH- 0.93130E-02 -2.0309 0.77640E-02 -2.1099 0.83366E+00 -0.0790 89 HPO3-2 0.78051E-15 -15.1076 0.40442E-15 -15.3932 0.51814E+00 -0.2856 91 H2PO3- 0.72261E-19 -19.1411 0.60351E-19 -19.2193 0.83517E+00 -0.0782 92 H3PO4,aq 0.91154E-18 -18.0402 0.91154E-18 -18.0402 0.10000E+01 0.0000 93 H2PO4- 0.38648E-10 -10.4129 0.32308E-10 -10.4907 0.83596E+00 -0.0778 94 PO4-3 0.10636E-08 -8.9732 0.25802E-09 -9.5883 0.24259E+00 -0.6151 98 HP2O7-3 0.94987E-18 -18.0223 0.21961E-18 -18.6584 0.23120E+00 -0.6360 99 P2O7-4 0.91474E-17 -17.0387 0.70499E-18 -18.1518 0.77070E-01 -1.1131 100 H2S,aq 0.64648E-08 -8.1894 0.64424E-08 -8.1910 0.99654E+00 -0.0015 101 S2-2 0.60850E-14 -14.2157 0.31529E-14 -14.5013 0.51814E+00 -0.2856 107 SO3-2 0.11701E-16 -16.9318 0.61507E-17 -17.2111 0.52564E+00 -0.2793 108 HSO3- 0.34315E-19 -19.4645 0.28659E-19 -19.5427 0.83517E+00 -0.0782 109 HSO4- 0.73496E-18 -18.1337 0.61559E-18 -18.2107 0.83759E+00 -0.0770 Charge balance for all species = -.6133E-08 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.8856833E-10 -.2227683E-01 -.2241468E+02 0.0000 2 H2O 0.1000000E+01 0.5550486E+02 0.9981984E+06 0.0000 3 Cl- 0.1540767E-03 0.1547843E-03 0.5478027E+01 6.2378 4 SO4-- 0.1653094E-10 -.1567674E-04 -.1503315E+01 9.1903 5 HCO3- 0.5372468E-05 0.2984997E-04 0.1818196E+01 4.7809 6 HS- 0.3353420E-04 0.4921743E-04 0.1624889E+01 5.5757 7 Al+++ 0.9730680E-29 0.5271837E-05 0.1419948E+00 0.7367 8 H4SiO4 0.6979364E-03 0.1353241E-01 0.1298412E+04 -3.1562 9 Ca++ 0.1251261E-06 0.2186016E-06 0.8745885E-02 13.0662 10 Mg++ 0.2112862E-10 0.9318252E-10 0.2261515E-05 9.2917 11 Fe++ 0.4680471E-13 0.2906087E-07 0.1620141E-02 6.6376 12 K+ 0.1565092E-03 0.1572609E-03 0.6138528E+01 6.2454 13 Na+ 0.1986067E-01 0.2230604E-01 0.5119199E+03 8.3480 14 Mn++ 0.1865050E-10 0.2507566E-08 0.1375212E-03 9.2384 15 F- 0.1953461E-06 0.1959785E-06 0.3716727E-02 3.3400 16 HPO4-- 0.4531810E-07 0.4642039E-07 0.4447638E-02 12.6284 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.2000608E-01 -.2000588E-01 -.1981115E-06 0.0000000E+00 2 H2O 0.4984656E+02 0.4984656E+02 -.1615976E-06 0.0000000E+00 3 Cl- 0.1390052E-03 0.1390052E-03 0.0000000E+00 0.0000000E+00 4 SO4-- -.1407781E-04 -.1407862E-04 0.8117419E-09 0.0000000E+00 5 HCO3- 0.2680700E-04 0.2680700E-04 0.0000000E+00 0.0000000E+00 6 HS- 0.4419928E-04 0.4420009E-04 -.8117419E-09 0.0000000E+00 7 Al+++ 0.4775352E-05 0.4734414E-05 0.4093814E-07 0.0000000E+00 8 H4SiO4 0.1215302E-01 0.1215289E-01 0.1305296E-06 0.0000000E+00 9 Ca++ 0.2080835E-06 0.1963169E-06 0.1176663E-07 0.0000000E+00 10 Mg++ 0.8368328E-10 0.8368328E-10 0.0000000E+00 0.0000000E+00 11 Fe++ 0.3259227E-07 0.2609833E-07 0.6493936E-08 0.0000000E+00 12 K+ 0.1412294E-03 0.1412294E-03 0.0000000E+00 0.0000000E+00 13 Na+ 0.2003215E-01 0.2003211E-01 0.3958765E-07 0.0000000E+00 14 Mn++ 0.2251939E-08 0.2251939E-08 0.0000000E+00 0.0000000E+00 15 F- 0.1760000E-06 0.1760000E-06 0.0000000E+00 0.0000000E+00 16 HPO4-- 0.4168819E-07 0.4168819E-07 0.0000000E+00 0.0000000E+00 Chg. balance for solid moles: -.2647E-22 Mass of aqueous solution: 0.899622E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 0.0001900 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 0.3959E-07 -7.402 0.1038E-04 -4.984 84.16 0.3985E-05 andradite 0.3247E-08 -8.489 0.1650E-05 -5.783 13.38 0.4287E-06 grossular 0.6752E-09 -9.171 0.3042E-06 -6.517 2.466 0.8463E-07 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8278E+00 0.8278E+00 1.0000 -0.082 grossular 0.1722E+00 0.1722E+00 1.0000 -0.764 Solid products produced: Mass = 0.000012 g Volume = 0.000004 cm3 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.0001900 moles log = -3.7212 Original solution: 1000.0103000 g Original solution / Rock added: 5263212.11 (Water/Rock Ratio), log = 6.7213 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0486 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9733E+00 0.9856 0.1006E+01 0.1021E+01 CO2,gas 0.7240E-07 1.0068 0.7645E-07 0.7593E-07 CH4,gas 0.1975E-01 1.0123 0.2097E-01 0.2071E-01 H2,gas 0.6900E-02 1.0006 0.7239E-02 0.7235E-02 H2S,gas 0.1696E-06 0.9959 0.1771E-06 0.1778E-06 S2,gas 0.2142E-28 1.0000 0.2246E-28 0.2246E-28 CO,gas 0.1407E-12 1.0000 0.1475E-12 0.1475E-12 SO3,gas 0.1714E-46 1.0000 0.1797E-46 0.1797E-46 SO2,gas 0.4827E-26 1.0000 0.5062E-26 0.5062E-26 HF,gas 0.1942E-15 1.0000 0.2037E-15 0.2037E-15 HCl,gas 0.2953E-17 1.0000 0.3096E-17 0.3096E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 17 albite -0.38 -0.38 0.00 0.000 0.11184E-10 23 andradite 39.01 39.01 0.00 0.000 0.24265E-10 24 grossular 32.73 32.73 0.00 0.000 -0.12132E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -15.48 -8.82 -2.939 0.15052E+05 -7.117 3 CH4,gas 4.54 1.17 -3.38 -0.844 0.57669E+04 -1.678 4 H2,gas 8.00 4.16 -3.84 -2.194 0.65554E+04 -2.140 5 H2S,gas -6.23 -14.68 -8.45 -4.225 0.14429E+05 -6.752 6 S2,gas -7.34 -37.68 -30.35 -4.669 0.51818E+05 -28.649 7 CO,gas 3.21 -11.32 -14.53 -4.471 0.24810E+05 -12.831 8 SO3,gas 17.12 -31.32 -48.44 -12.111 0.82717E+05 -46.745 9 SO2,gas 0.83 -27.16 -27.99 -7.465 0.47800E+05 -26.296 10 HF,gas 0.47 -16.92 -17.39 -8.695 0.29693E+05 -15.691 11 HCl,gas 5.19 -14.02 -19.21 -9.604 0.32797E+05 -17.509 12 acmite 7.71 6.59 -1.12 -0.116 0.19068E+04 16 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 20 spessartine 24.46 19.72 -4.74 -0.237 0.80891E+04 21 analcite 3.32 2.77 -0.55 -0.061 0.93833E+03 27 annite 20.12 17.43 -2.70 -0.150 0.46053E+04 28 phlogopite 27.06 25.39 -1.68 -0.093 0.28617E+04 30 anorthite 12.71 8.23 -4.48 -0.345 0.76549E+04 33 apatite-OH -18.15 -18.32 -0.17 -0.013 0.29114E+03 34 apatite-F -34.30 -35.24 -0.94 -0.078 0.16044E+04 38 aragonite 0.97 -2.41 -3.38 -1.125 0.57646E+04 39 brucite 12.57 9.29 -3.28 -0.655 0.55952E+04 40 calcite 0.81 -2.41 -3.22 -1.074 0.55004E+04 41 carnegieite-low 9.02 5.93 -3.09 -0.442 0.52843E+04 42 carnegieite-high 10.09 5.93 -4.16 -0.595 0.71113E+04 43 carpholite-Mg 8.58 4.45 -4.13 -0.275 0.70509E+04 44 carpholite-Fe 6.71 1.80 -4.91 -0.328 0.83907E+04 45 celadonite 5.34 3.65 -1.69 -0.100 0.28901E+04 46 celadonite-Fe 3.88 0.99 -2.88 -0.170 0.49203E+04 47 chrysotile 23.89 21.56 -2.33 -0.194 0.39778E+04 49 clinochlore 39.07 38.46 -0.61 -0.019 0.10351E+04 50 daphnite 28.97 25.19 -3.77 -0.118 0.64414E+04 52 chlorite-Al-free 47.17 43.13 -4.05 -0.169 0.69108E+04 54 chloritoid-Fe 9.17 4.95 -4.22 -0.281 0.72036E+04 55 chloritoid-Mn 11.40 7.56 -3.85 -0.256 0.65662E+04 57 coesite -2.38 -3.16 -0.78 -0.260 0.13320E+04 64 cristobalite -2.56 -3.16 -0.60 -0.199 0.10174E+04 66 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71234E+04 68 diaspore 2.87 0.74 -2.14 -0.356 0.36489E+04 69 diamond -3.10 -7.15 -4.05 -1.158 0.69193E+04 70 diopside 16.18 16.05 -0.14 -0.014 0.23197E+03 71 hedenbergite 14.21 13.39 -0.82 -0.082 0.13948E+04 74 enstatite 17.26 12.27 -4.99 -0.499 0.85269E+04 76 clinoenstatite 17.17 12.27 -4.90 -0.490 0.83585E+04 78 epidote 24.67 22.69 -1.98 -0.096 0.33730E+04 79 clinozoisite 22.81 18.87 -3.93 -0.179 0.67142E+04 80 epidote-Fe 29.84 26.52 -3.33 -0.173 0.56785E+04 81 fayalite 14.05 10.12 -3.93 -0.561 0.67048E+04 82 ferrosilite 11.15 6.96 -4.19 -0.419 0.71486E+04 86 gibbsite 4.08 0.74 -3.34 -0.478 0.57075E+04 87 glaucophane 22.97 20.79 -2.18 -0.059 0.37220E+04 88 glaucophane-Fe 17.28 12.83 -4.44 -0.120 0.75865E+04 89 graphite -3.55 -7.15 -3.61 -1.031 0.61615E+04 90 greenalite 16.14 13.60 -2.54 -0.212 0.43354E+04 93 hematite 12.57 9.11 -3.45 -0.418 0.58933E+04 94 heulandite -5.83 -7.55 -1.73 -0.078 0.29480E+04 98 jadeite 4.22 2.77 -1.44 -0.144 0.24638E+04 100 kalsilite 7.58 3.83 -3.76 -0.537 0.64168E+04 101 kaolinite -1.33 -4.84 -3.51 -0.319 0.59868E+04 104 laumontite 2.88 1.91 -0.97 -0.065 0.16539E+04 105 lawsonite 9.62 8.23 -1.39 -0.093 0.23716E+04 106 leucite 4.12 0.67 -3.45 -0.345 0.58894E+04 108 lizardite 23.24 21.56 -1.68 -0.140 0.28705E+04 110 magnetite 20.09 15.75 -4.34 -0.354 0.74021E+04 111 minnesotaite 10.39 7.29 -3.10 -0.182 0.52933E+04 115 manganosite 14.06 9.24 -4.82 -1.205 0.82296E+04 119 microcline -2.49 -2.49 0.00 0.000 0.16033E-01 123 muscovite 2.58 -1.01 -3.60 -0.212 0.61394E+04 124 paragonite 4.24 1.09 -3.15 -0.185 0.53785E+04 125 nepheline 8.34 5.93 -2.41 -0.344 0.41166E+04 131 periclase-Fe 11.63 6.64 -4.99 -1.247 0.85186E+04 137 phlogopite-Na 29.65 27.49 -2.16 -0.120 0.36805E+04 139 prehnite 19.37 18.14 -1.23 -0.073 0.21083E+04 140 prehnite-Fe 22.50 21.96 -0.54 -0.032 0.92215E+03 141 pumpellyite-Fe 46.27 43.65 -2.62 -0.058 0.44752E+04 142 pumpellyite-Mg 48.99 46.30 -2.69 -0.060 0.45970E+04 146 pyrrhotite -4.26 -8.04 -3.78 -1.261 0.64595E+04 147 pyrrhotiteFe0.875 -6.02 -9.39 -3.37 -1.240 0.57577E+04 148 pyroxmangite 7.40 6.08 -1.32 -0.263 0.22479E+04 149 pyrophyllite -6.18 -11.15 -4.98 -0.311 0.84957E+04 150 quartz -2.99 -3.16 -0.17 -0.056 0.28472E+03 155 rhodonite 7.45 6.08 -1.36 -0.273 0.23282E+04 156 sanidine -1.28 -2.49 -1.21 -0.093 0.20678E+04 166 stilbite -7.52 -7.55 -0.03 -0.002 0.54181E+02 167 stilpnomelane-Fe 13.02 12.53 -0.48 -0.014 0.82377E+03 168 stilpnomelane-Mg 27.44 25.81 -1.64 -0.049 0.27940E+04 174 talc 16.49 15.25 -1.24 -0.073 0.21185E+04 177 tephroite 18.09 15.32 -2.77 -0.395 0.47216E+04 181 tridymite -2.63 -3.16 -0.53 -0.177 0.90470E+03 182 tremolite 47.87 47.34 -0.53 -0.014 0.90136E+03 183 ferroactinolite 38.45 34.07 -4.38 -0.118 0.74814E+04 184 troilite-low -4.41 -8.04 -3.63 -1.211 0.62023E+04 190 wairakite 3.95 1.91 -2.04 -0.120 0.34759E+04 191 walstromite 11.51 9.91 -1.60 -0.320 0.27307E+04 192 wollastonite 10.46 9.91 -0.55 -0.110 0.94110E+03 193 pseudo-wollastonite 11.00 9.91 -1.09 -0.218 0.18609E+04 194 zoisite 22.85 18.87 -3.98 -0.181 0.67883E+04 195 akaganeite 7.75 4.56 -3.20 -0.691 0.54592E+04 202 chalcedony -2.80 -3.16 -0.35 -0.118 0.60402E+03 204 montmorillonite-Ca -2.29 -6.17 -3.88 -0.240 0.66277E+04 205 montmorillonite-K -2.24 -6.27 -4.03 -0.247 0.68820E+04 206 montmorillonite-Mg -2.48 -6.80 -4.32 -0.267 0.73681E+04 207 montmorillonite-Na -2.04 -5.57 -3.54 -0.217 0.60369E+04 208 nontronite-Ca 3.21 -0.07 -3.28 -0.213 0.56074E+04 209 nontronite-H 2.53 -2.23 -4.76 -0.319 0.81243E+04 210 nontronite-K 3.34 -0.16 -3.51 -0.225 0.59849E+04 211 nontronite-Mg 3.07 -0.69 -3.77 -0.244 0.64319E+04 212 nontronite-Na 3.52 0.53 -2.99 -0.192 0.51058E+04 228 tobermorite 9.82 7.73 -2.10 -0.572 0.35774E+04 234 alabandite -0.98 -5.44 -4.46 -1.488 0.76235E+04 237 boehmite 4.41 0.74 -3.67 -0.612 0.62658E+04 239 ferrous-oxide 9.81 6.64 -3.17 -0.793 0.54195E+04 245 silica-amorphous -2.09 -3.16 -1.06 -0.355 0.18182E+04 247 an20ab80 2.02 1.34 -0.68 -0.052 0.11601E+04 248 an25ab75 2.65 1.77 -0.88 -0.067 0.14971E+04 249 an30ab70 3.28 2.20 -1.08 -0.083 0.18438E+04 250 tr.625ac.25prg.125 45.16 44.97 -0.19 -0.005 0.33069E+03 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 0.0000100 MOLES Current total amount of reactant added: 0.0001900 MOLES New total amount of reactant added: 0.0002000 MOLES Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.5508E-08 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 6 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 0.0002000 Water: Moles liquid = 0.4985E+02 kg liquid = 0.8981E+00 Moles total = 0.4985E+02 kg total = 0.8980E+00 Activity = 1.0000 Stoichiometric ionic strength = .1134297E-01 Osmotic coef. = 0.9687 True ionic strength = .2002846E-01 Chg. balance for total moles = -.5508E-08 Max. difference allowed = 0.1391E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.88584E-10 -10.0526 0.74430E-10 -10.1282 0.84023E+00 -0.0756 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.15414E-03 -3.8121 0.12873E-03 -3.8903 0.83517E+00 -0.0782 4 SO4-- 0.17607E-10 -10.7543 0.91425E-11 -11.0389 0.51924E+00 -0.2846 5 HCO3- 0.56629E-05 -5.2470 0.47364E-05 -5.3245 0.83639E+00 -0.0776 6 HS- 0.33805E-04 -4.4710 0.28237E-04 -4.5492 0.83529E+00 -0.0782 7 Al+++ 0.97329E-29 -29.0118 0.22479E-29 -29.6482 0.23096E+00 -0.6365 8 H4SiO4 0.69805E-03 -3.1561 0.69805E-03 -3.1561 0.10000E+01 0.0000 9 Ca++ 0.12491E-06 -6.9034 0.64380E-07 -7.1912 0.51543E+00 -0.2878 10 Mg++ 0.21129E-10 -10.6751 0.10841E-10 -10.9649 0.51307E+00 -0.2898 11 Fe++ 0.46667E-13 -13.3310 0.23969E-13 -13.6203 0.51363E+00 -0.2894 12 K+ 0.15651E-03 -3.8055 0.13093E-03 -3.8829 0.83659E+00 -0.0775 13 Na+ 0.19861E-01 -1.7020 0.16584E-01 -1.7803 0.83502E+00 -0.0783 14 Mn++ 0.18657E-10 -10.7292 0.95906E-11 -11.0182 0.51406E+00 -0.2890 15 F- 0.19979E-06 -6.6994 0.16651E-06 -6.7786 0.83345E+00 -0.0791 16 HPO4-- 0.45318E-07 -7.3437 0.23534E-07 -7.6283 0.51931E+00 -0.2846 18 HSiO3- 0.10485E-01 -1.9794 0.87571E-02 -2.0576 0.83517E+00 -0.0782 19 Ca(HSiO3)+ 0.15344E-07 -7.8141 0.12839E-07 -7.8915 0.83677E+00 -0.0774 20 Mg(HSiO3)+ 0.32155E-11 -11.4928 0.26906E-11 -11.5701 0.83677E+00 -0.0774 21 NaHSiO3,aq 0.23489E-02 -2.6291 0.23489E-02 -2.6291 0.10000E+01 0.0000 22 AlO+ 0.65971E-16 -16.1806 0.55202E-16 -16.2580 0.83677E+00 -0.0774 24 HAlO2,aq 0.14770E-09 -9.8306 0.14770E-09 -9.8306 0.10000E+01 0.0000 25 AlO2- 0.52691E-05 -5.2783 0.43927E-05 -5.3573 0.83366E+00 -0.0790 26 CH4,aq 0.14259E-04 -4.8459 0.14210E-04 -4.8474 0.99654E+00 -0.0015 27 C2H6,aq 0.63693E-14 -14.1959 0.63473E-14 -14.1974 0.99654E+00 -0.0015 31 CO,aq 0.10291E-15 -15.9875 0.10291E-15 -15.9875 0.10000E+01 0.0000 32 CO2,aq 0.75590E-09 -9.1215 0.75328E-09 -9.1230 0.99654E+00 -0.0015 33 CO3-2 0.10728E-04 -4.9695 0.55583E-05 -5.2551 0.51814E+00 -0.2856 34 CaCO3,aq 0.44870E-08 -8.3480 0.44870E-08 -8.3480 0.10000E+01 0.0000 35 Ca(HCO3)+ 0.93020E-11 -11.0314 0.77837E-11 -11.1088 0.83677E+00 -0.0774 36 CaCl+ 0.16029E-10 -10.7951 0.13412E-10 -10.8725 0.83677E+00 -0.0774 37 CaCl2,aq 0.41022E-15 -15.3870 0.41022E-15 -15.3870 0.10000E+01 0.0000 38 CaF+ 0.18704E-12 -12.7281 0.15651E-12 -12.8055 0.83677E+00 -0.0774 39 CaOH+ 0.73671E-07 -7.1327 0.61646E-07 -7.2101 0.83677E+00 -0.0774 40 CaSO4,aq 0.18691E-15 -15.7284 0.18691E-15 -15.7284 0.10000E+01 0.0000 41 HCl,aq 0.17558E-14 -14.7555 0.17558E-14 -14.7555 0.10000E+01 0.0000 45 HF,aq 0.84842E-13 -13.0714 0.84842E-13 -13.0714 0.10000E+01 0.0000 48 FeCl+ 0.58369E-17 -17.2338 0.48842E-17 -17.3112 0.83677E+00 -0.0774 51 FeF+ 0.24374E-18 -18.6131 0.20396E-18 -18.6905 0.83677E+00 -0.0774 53 FeO,aq 0.16816E-09 -9.7743 0.16816E-09 -9.7743 0.10000E+01 0.0000 54 FeOH+ 0.12528E-10 -10.9021 0.10483E-10 -10.9795 0.83677E+00 -0.0774 55 HFeO2- 0.28305E-07 -7.5481 0.23639E-07 -7.6264 0.83517E+00 -0.0782 56 FeO+ 0.12813E-16 -16.8924 0.10722E-16 -16.9697 0.83677E+00 -0.0774 58 FeO2- 0.47417E-09 -9.3241 0.39601E-09 -9.4023 0.83517E+00 -0.0782 59 HFeO2,aq 0.37488E-11 -11.4261 0.37488E-11 -11.4261 0.10000E+01 0.0000 60 H2,aq 0.54574E-05 -5.2630 0.54386E-05 -5.2645 0.99654E+00 -0.0015 61 KCl,aq 0.30550E-09 -9.5150 0.30550E-09 -9.5150 0.10000E+01 0.0000 63 KOH,aq 0.75126E-06 -6.1242 0.75126E-06 -6.1242 0.10000E+01 0.0000 64 KSO4- 0.22242E-13 -13.6528 0.18576E-13 -13.7311 0.83517E+00 -0.0782 65 MgCO3,aq 0.18938E-12 -12.7227 0.18938E-12 -12.7227 0.10000E+01 0.0000 66 Mg(HCO3)+ 0.16005E-14 -14.7957 0.13393E-14 -14.8731 0.83677E+00 -0.0774 67 MgCl+ 0.24463E-14 -14.6115 0.20470E-14 -14.6889 0.83677E+00 -0.0774 68 MgF+ 0.11667E-15 -15.9330 0.97626E-16 -16.0104 0.83677E+00 -0.0774 69 MgOH+ 0.68644E-10 -10.1634 0.57440E-10 -10.2408 0.83677E+00 -0.0774 71 MnF+ 0.32145E-16 -16.4929 0.26898E-16 -16.5703 0.83677E+00 -0.0774 72 MnO,aq 0.17928E-08 -8.7465 0.17928E-08 -8.7465 0.10000E+01 0.0000 73 MnOH+ 0.46564E-09 -9.3319 0.38964E-09 -9.4093 0.83677E+00 -0.0774 74 MnO2-2 0.20728E-10 -10.6834 0.10740E-10 -10.9690 0.51814E+00 -0.2856 75 HMnO2- 0.20970E-09 -9.6784 0.17513E-09 -9.7566 0.83517E+00 -0.0782 78 MnCl+ 0.90860E-14 -14.0416 0.76029E-14 -14.1190 0.83677E+00 -0.0774 79 MnSO4,aq 0.25313E-19 -19.5967 0.25313E-19 -19.5967 0.10000E+01 0.0000 80 NaCl,aq 0.70753E-06 -6.1503 0.70753E-06 -6.1503 0.10000E+01 0.0000 81 NaF,aq 0.64650E-09 -9.1894 0.64650E-09 -9.1894 0.10000E+01 0.0000 82 NaOH,aq 0.95731E-04 -4.0189 0.95731E-04 -4.0189 0.10000E+01 0.0000 84 OH- 0.93115E-02 -2.0310 0.77626E-02 -2.1100 0.83366E+00 -0.0790 89 HPO3-2 0.76982E-15 -15.1136 0.39887E-15 -15.3992 0.51814E+00 -0.2856 91 H2PO3- 0.71283E-19 -19.1470 0.59533E-19 -19.2252 0.83517E+00 -0.0782 92 H3PO4,aq 0.91185E-18 -18.0401 0.91185E-18 -18.0401 0.10000E+01 0.0000 93 H2PO4- 0.38654E-10 -10.4128 0.32314E-10 -10.4906 0.83596E+00 -0.0778 94 PO4-3 0.10635E-08 -8.9733 0.25798E-09 -9.5884 0.24258E+00 -0.6151 98 HP2O7-3 0.95004E-18 -18.0223 0.21964E-18 -18.6583 0.23119E+00 -0.6360 99 P2O7-4 0.91476E-17 -17.0387 0.70498E-18 -18.1518 0.77067E-01 -1.1131 100 H2S,aq 0.65180E-08 -8.1859 0.64955E-08 -8.1874 0.99654E+00 -0.0015 101 S2-2 0.62695E-14 -14.2028 0.32485E-14 -14.4883 0.51814E+00 -0.2856 107 SO3-2 0.12292E-16 -16.9104 0.64613E-17 -17.1897 0.52563E+00 -0.2793 108 HSO3- 0.36054E-19 -19.4430 0.30111E-19 -19.5213 0.83517E+00 -0.0782 109 HSO4- 0.78295E-18 -18.1063 0.65579E-18 -18.1832 0.83759E+00 -0.0770 Charge balance for all species = -.6133E-08 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.8858382E-10 -.2227562E-01 -.2241346E+02 0.0000 2 H2O 0.1000000E+01 0.5550485E+02 0.9981983E+06 0.0000 3 Cl- 0.1541421E-03 0.1548499E-03 0.5480351E+01 6.2379 4 SO4-- 0.1760745E-10 -.1562358E-04 -.1498217E+01 9.2176 5 HCO3- 0.5662931E-05 0.3065504E-04 0.1867233E+01 4.8037 6 HS- 0.3380473E-04 0.4943484E-04 0.1632067E+01 5.5791 7 Al+++ 0.9732861E-29 0.5269289E-05 0.1419262E+00 0.7365 8 H4SiO4 0.6980494E-03 0.1353240E-01 0.1298411E+04 -3.1561 9 Ca++ 0.1249062E-06 0.2184339E-06 0.8739173E-02 13.0653 10 Mg++ 0.2112920E-10 0.9318250E-10 0.2261515E-05 9.2916 11 Fe++ 0.4666683E-13 0.2896337E-07 0.1614706E-02 6.6362 12 K+ 0.1565093E-03 0.1572609E-03 0.6138526E+01 6.2453 13 Na+ 0.1986071E-01 0.2230603E-01 0.5119197E+03 8.3479 14 Mn++ 0.1865676E-10 0.2507566E-08 0.1375211E-03 9.2383 15 F- 0.1997857E-06 0.2004325E-06 0.3801197E-02 3.3497 16 HPO4-- 0.4531826E-07 0.4642038E-07 0.4447637E-02 12.6282 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.2000501E-01 -.2000480E-01 -.2077147E-06 0.0000000E+00 2 H2O 0.4984657E+02 0.4984657E+02 -.1707406E-06 0.0000000E+00 3 Cl- 0.1390642E-03 0.1390642E-03 0.0000000E+00 0.0000000E+00 4 SO4-- -.1403006E-04 -.1403088E-04 0.8226856E-09 0.0000000E+00 5 HCO3- 0.2753000E-04 0.2753000E-04 0.0000000E+00 0.0000000E+00 6 HS- 0.4439453E-04 0.4439535E-04 -.8226856E-09 0.0000000E+00 7 Al+++ 0.4775352E-05 0.4732126E-05 0.4322580E-07 0.0000000E+00 8 H4SiO4 0.1215302E-01 0.1215288E-01 0.1375046E-06 0.0000000E+00 9 Ca++ 0.2080835E-06 0.1961662E-06 0.1191725E-07 0.0000000E+00 10 Mg++ 0.8368328E-10 0.8368328E-10 0.0000000E+00 0.0000000E+00 11 Fe++ 0.3259227E-07 0.2601079E-07 0.6581485E-08 0.0000000E+00 12 K+ 0.1412294E-03 0.1412294E-03 0.0000000E+00 0.0000000E+00 13 Na+ 0.2003215E-01 0.2003211E-01 0.4186245E-07 0.0000000E+00 14 Mn++ 0.2251939E-08 0.2251939E-08 0.0000000E+00 0.0000000E+00 15 F- 0.1800000E-06 0.1800000E-06 0.0000000E+00 0.0000000E+00 16 HPO4-- 0.4168819E-07 0.4168819E-07 0.0000000E+00 0.0000000E+00 Chg. balance for solid moles: 0.1323E-22 Mass of aqueous solution: 0.899622E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 0.0002000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 0.4186E-07 -7.378 0.1098E-04 -4.960 84.72 0.4214E-05 andradite 0.3291E-08 -8.483 0.1672E-05 -5.777 12.91 0.4345E-06 grossular 0.6817E-09 -9.166 0.3071E-06 -6.513 2.370 0.8544E-07 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8284E+00 0.8284E+00 1.0000 -0.082 grossular 0.1716E+00 0.1716E+00 1.0000 -0.765 Solid products produced: Mass = 0.000013 g Volume = 0.000005 cm3 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.0002000 moles log = -3.6990 Original solution: 1000.0103000 g Original solution / Rock added: 5000051.50 (Water/Rock Ratio), log = 6.6990 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0485 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9735E+00 0.9856 0.1006E+01 0.1021E+01 CO2,gas 0.7634E-07 1.0068 0.8059E-07 0.8004E-07 CH4,gas 0.1971E-01 1.0123 0.2092E-01 0.2066E-01 H2,gas 0.6806E-02 1.0006 0.7140E-02 0.7136E-02 H2S,gas 0.1710E-06 0.9959 0.1786E-06 0.1793E-06 S2,gas 0.2239E-28 1.0000 0.2347E-28 0.2347E-28 CO,gas 0.1463E-12 1.0000 0.1534E-12 0.1534E-12 SO3,gas 0.1826E-46 1.0000 0.1915E-46 0.1915E-46 SO2,gas 0.5074E-26 1.0000 0.5320E-26 0.5320E-26 HF,gas 0.1987E-15 1.0000 0.2083E-15 0.2083E-15 HCl,gas 0.2955E-17 1.0000 0.3098E-17 0.3098E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 17 albite -0.38 -0.38 0.00 0.000 -0.94784E-12 23 andradite 39.01 39.01 0.00 0.000 0.00000E+00 24 grossular 32.73 32.73 0.00 0.000 0.12132E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -15.45 -8.79 -2.931 0.15013E+05 -7.094 3 CH4,gas 4.54 1.17 -3.38 -0.845 0.57687E+04 -1.680 4 H2,gas 8.00 4.15 -3.85 -2.197 0.65657E+04 -2.146 5 H2S,gas -6.23 -14.68 -8.45 -4.224 0.14423E+05 -6.748 6 S2,gas -7.34 -37.66 -30.33 -4.666 0.51785E+05 -28.629 7 CO,gas 3.21 -11.30 -14.51 -4.466 0.24781E+05 -12.814 8 SO3,gas 17.12 -31.30 -48.42 -12.104 0.82670E+05 -46.718 9 SO2,gas 0.83 -27.14 -27.97 -7.459 0.47763E+05 -26.274 10 HF,gas 0.47 -16.91 -17.38 -8.690 0.29676E+05 -15.681 11 HCl,gas 5.19 -14.02 -19.21 -9.604 0.32797E+05 -17.509 12 acmite 7.71 6.59 -1.12 -0.116 0.19040E+04 16 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 20 spessartine 24.46 19.72 -4.74 -0.237 0.80893E+04 21 analcite 3.32 2.77 -0.55 -0.061 0.93845E+03 27 annite 20.12 17.42 -2.70 -0.150 0.46126E+04 28 phlogopite 27.06 25.39 -1.68 -0.093 0.28624E+04 30 anorthite 12.71 8.23 -4.48 -0.345 0.76567E+04 33 apatite-OH -18.15 -18.33 -0.17 -0.013 0.29822E+03 34 apatite-F -34.30 -35.23 -0.93 -0.078 0.15947E+04 38 aragonite 0.97 -2.39 -3.35 -1.118 0.57270E+04 39 brucite 12.57 9.29 -3.28 -0.655 0.55954E+04 40 calcite 0.81 -2.39 -3.20 -1.066 0.54628E+04 41 carnegieite-low 9.02 5.93 -3.09 -0.442 0.52845E+04 42 carnegieite-high 10.09 5.93 -4.16 -0.595 0.71115E+04 43 carpholite-Mg 8.58 4.45 -4.13 -0.275 0.70513E+04 44 carpholite-Fe 6.71 1.80 -4.92 -0.328 0.83933E+04 45 celadonite 5.34 3.65 -1.69 -0.100 0.28902E+04 46 celadonite-Fe 3.88 0.99 -2.88 -0.170 0.49226E+04 47 chrysotile 23.89 21.56 -2.33 -0.194 0.39783E+04 49 clinochlore 39.07 38.46 -0.61 -0.019 0.10364E+04 50 daphnite 28.97 25.19 -3.78 -0.118 0.64538E+04 52 chlorite-Al-free 47.17 43.12 -4.05 -0.169 0.69118E+04 54 chloritoid-Fe 9.17 4.95 -4.22 -0.281 0.72064E+04 55 chloritoid-Mn 11.40 7.56 -3.85 -0.256 0.65666E+04 57 coesite -2.38 -3.16 -0.78 -0.260 0.13319E+04 64 cristobalite -2.56 -3.16 -0.60 -0.199 0.10173E+04 66 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71234E+04 68 diaspore 2.87 0.74 -2.14 -0.356 0.36492E+04 69 diamond -3.10 -7.14 -4.04 -1.155 0.69006E+04 70 diopside 16.18 16.04 -0.14 -0.014 0.23354E+03 71 hedenbergite 14.21 13.39 -0.82 -0.082 0.13986E+04 74 enstatite 17.26 12.27 -4.99 -0.499 0.85271E+04 76 clinoenstatite 17.17 12.27 -4.90 -0.490 0.83587E+04 78 epidote 24.67 22.69 -1.98 -0.096 0.33736E+04 79 clinozoisite 22.81 18.87 -3.93 -0.179 0.67177E+04 80 epidote-Fe 29.84 26.52 -3.32 -0.173 0.56761E+04 81 fayalite 14.05 10.12 -3.93 -0.561 0.67096E+04 82 ferrosilite 11.15 6.96 -4.19 -0.419 0.71532E+04 86 gibbsite 4.08 0.74 -3.34 -0.478 0.57077E+04 87 glaucophane 22.97 20.79 -2.18 -0.059 0.37224E+04 88 glaucophane-Fe 17.28 12.83 -4.45 -0.120 0.75937E+04 89 graphite -3.55 -7.14 -3.60 -1.028 0.61428E+04 90 greenalite 16.14 13.60 -2.54 -0.212 0.43425E+04 93 hematite 12.57 9.12 -3.45 -0.418 0.58880E+04 94 heulandite -5.83 -7.55 -1.73 -0.079 0.29492E+04 98 jadeite 4.22 2.77 -1.44 -0.144 0.24639E+04 100 kalsilite 7.58 3.83 -3.76 -0.537 0.64170E+04 101 kaolinite -1.33 -4.84 -3.51 -0.319 0.59871E+04 104 laumontite 2.88 1.91 -0.97 -0.065 0.16555E+04 105 lawsonite 9.62 8.23 -1.39 -0.093 0.23734E+04 106 leucite 4.12 0.67 -3.45 -0.345 0.58895E+04 108 lizardite 23.24 21.56 -1.68 -0.140 0.28709E+04 110 magnetite 20.09 15.75 -4.33 -0.354 0.73992E+04 111 minnesotaite 10.39 7.28 -3.10 -0.183 0.53001E+04 115 manganosite 14.06 9.24 -4.82 -1.205 0.82296E+04 119 microcline -2.49 -2.49 0.00 0.000 0.16866E-01 123 muscovite 2.58 -1.01 -3.60 -0.212 0.61399E+04 124 paragonite 4.24 1.09 -3.15 -0.185 0.53789E+04 125 nepheline 8.34 5.93 -2.41 -0.344 0.41169E+04 131 periclase-Fe 11.63 6.64 -4.99 -1.248 0.85210E+04 137 phlogopite-Na 29.65 27.49 -2.16 -0.120 0.36812E+04 139 prehnite 19.37 18.14 -1.24 -0.073 0.21116E+04 140 prehnite-Fe 22.50 21.96 -0.54 -0.032 0.92248E+03 141 pumpellyite-Fe 46.27 43.64 -2.63 -0.058 0.44843E+04 142 pumpellyite-Mg 48.99 46.30 -2.70 -0.060 0.46039E+04 146 pyrrhotite -4.26 -8.04 -3.78 -1.260 0.64559E+04 147 pyrrhotiteFe0.875 -6.02 -9.39 -3.37 -1.239 0.57525E+04 148 pyroxmangite 7.40 6.08 -1.32 -0.263 0.22478E+04 149 pyrophyllite -6.18 -11.15 -4.98 -0.311 0.84957E+04 150 quartz -2.99 -3.16 -0.17 -0.056 0.28460E+03 155 rhodonite 7.45 6.08 -1.36 -0.273 0.23280E+04 156 sanidine -1.28 -2.49 -1.21 -0.093 0.20678E+04 166 stilbite -7.52 -7.55 -0.03 -0.002 0.55371E+02 167 stilpnomelane-Fe 13.02 12.53 -0.49 -0.015 0.83558E+03 168 stilpnomelane-Mg 27.44 25.80 -1.64 -0.049 0.27948E+04 174 talc 16.49 15.25 -1.24 -0.073 0.21187E+04 177 tephroite 18.09 15.32 -2.77 -0.395 0.47215E+04 181 tridymite -2.63 -3.16 -0.53 -0.177 0.90458E+03 182 tremolite 47.87 47.34 -0.53 -0.014 0.90474E+03 183 ferroactinolite 38.45 34.06 -4.39 -0.119 0.74958E+04 184 troilite-low -4.41 -8.04 -3.63 -1.210 0.61987E+04 190 wairakite 3.95 1.91 -2.04 -0.120 0.34774E+04 191 walstromite 11.51 9.91 -1.60 -0.320 0.27321E+04 192 wollastonite 10.46 9.91 -0.55 -0.110 0.94254E+03 193 pseudo-wollastonite 11.00 9.91 -1.09 -0.218 0.18624E+04 194 zoisite 22.85 18.87 -3.98 -0.181 0.67917E+04 195 akaganeite 7.75 4.56 -3.20 -0.691 0.54565E+04 202 chalcedony -2.80 -3.16 -0.35 -0.118 0.60390E+03 204 montmorillonite-Ca -2.29 -6.17 -3.88 -0.240 0.66280E+04 205 montmorillonite-K -2.24 -6.27 -4.03 -0.247 0.68821E+04 206 montmorillonite-Mg -2.48 -6.80 -4.32 -0.267 0.73682E+04 207 montmorillonite-Na -2.04 -5.57 -3.54 -0.217 0.60370E+04 208 nontronite-Ca 3.21 -0.07 -3.28 -0.213 0.56019E+04 209 nontronite-H 2.53 -2.22 -4.75 -0.319 0.81186E+04 210 nontronite-K 3.34 -0.16 -3.50 -0.225 0.59792E+04 211 nontronite-Mg 3.07 -0.69 -3.76 -0.244 0.64262E+04 212 nontronite-Na 3.52 0.53 -2.99 -0.192 0.51001E+04 228 tobermorite 9.82 7.73 -2.10 -0.572 0.35785E+04 234 alabandite -0.98 -5.44 -4.46 -1.487 0.76174E+04 237 boehmite 4.41 0.74 -3.67 -0.612 0.62661E+04 239 ferrous-oxide 9.81 6.64 -3.18 -0.794 0.54220E+04 245 silica-amorphous -2.09 -3.16 -1.06 -0.355 0.18181E+04 247 an20ab80 2.02 1.34 -0.68 -0.052 0.11605E+04 248 an25ab75 2.65 1.77 -0.88 -0.067 0.14976E+04 249 an30ab70 3.28 2.20 -1.08 -0.083 0.18443E+04 250 tr.625ac.25prg.125 45.16 44.97 -0.20 -0.005 0.33694E+03 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 0.0000100 MOLES Current total amount of reactant added: 0.0002000 MOLES New total amount of reactant added: 0.0002100 MOLES Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.5508E-08 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 6 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 0.0002100 Water: Moles liquid = 0.4985E+02 kg liquid = 0.8981E+00 Moles total = 0.4985E+02 kg total = 0.8980E+00 Activity = 1.0000 Stoichiometric ionic strength = .1134361E-01 Osmotic coef. = 0.9686 True ionic strength = .2002905E-01 Chg. balance for total moles = -.5508E-08 Max. difference allowed = 0.1391E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.88599E-10 -10.0526 0.74443E-10 -10.1282 0.84022E+00 -0.0756 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.15421E-03 -3.8119 0.12879E-03 -3.8901 0.83517E+00 -0.0782 4 SO4-- 0.18706E-10 -10.7280 0.97130E-11 -11.0126 0.51923E+00 -0.2846 5 HCO3- 0.59538E-05 -5.2252 0.49797E-05 -5.3028 0.83639E+00 -0.0776 6 HS- 0.34075E-04 -4.4676 0.28463E-04 -4.5457 0.83529E+00 -0.0782 7 Al+++ 0.97350E-29 -29.0117 0.22484E-29 -29.6481 0.23096E+00 -0.6365 8 H4SiO4 0.69816E-03 -3.1560 0.69816E-03 -3.1560 0.10000E+01 0.0000 9 Ca++ 0.12469E-06 -6.9042 0.64270E-07 -7.1920 0.51542E+00 -0.2878 10 Mg++ 0.21130E-10 -10.6751 0.10841E-10 -10.9649 0.51306E+00 -0.2898 11 Fe++ 0.46539E-13 -13.3322 0.23904E-13 -13.6215 0.51363E+00 -0.2894 12 K+ 0.15651E-03 -3.8055 0.13093E-03 -3.8829 0.83659E+00 -0.0775 13 Na+ 0.19861E-01 -1.7020 0.16584E-01 -1.7803 0.83502E+00 -0.0783 14 Mn++ 0.18663E-10 -10.7290 0.95938E-11 -11.0180 0.51405E+00 -0.2890 15 F- 0.20423E-06 -6.6899 0.17021E-06 -6.7690 0.83345E+00 -0.0791 16 HPO4-- 0.45318E-07 -7.3437 0.23534E-07 -7.6283 0.51931E+00 -0.2846 18 HSiO3- 0.10485E-01 -1.9794 0.87571E-02 -2.0576 0.83517E+00 -0.0782 19 Ca(HSiO3)+ 0.15318E-07 -7.8148 0.12817E-07 -7.8922 0.83677E+00 -0.0774 20 Mg(HSiO3)+ 0.32155E-11 -11.4927 0.26907E-11 -11.5701 0.83677E+00 -0.0774 21 NaHSiO3,aq 0.23489E-02 -2.6291 0.23489E-02 -2.6291 0.10000E+01 0.0000 22 AlO+ 0.65962E-16 -16.1807 0.55195E-16 -16.2581 0.83677E+00 -0.0774 24 HAlO2,aq 0.14765E-09 -9.8308 0.14765E-09 -9.8308 0.10000E+01 0.0000 25 AlO2- 0.52666E-05 -5.2785 0.43906E-05 -5.3575 0.83366E+00 -0.0790 26 CH4,aq 0.14224E-04 -4.8470 0.14175E-04 -4.8485 0.99654E+00 -0.0015 27 C2H6,aq 0.64219E-14 -14.1923 0.63997E-14 -14.1938 0.99654E+00 -0.0015 31 CO,aq 0.10680E-15 -15.9714 0.10680E-15 -15.9714 0.10000E+01 0.0000 32 CO2,aq 0.79486E-09 -9.0997 0.79212E-09 -9.1012 0.99654E+00 -0.0015 33 CO3-2 0.11277E-04 -4.9478 0.58428E-05 -5.2334 0.51813E+00 -0.2856 34 CaCO3,aq 0.47086E-08 -8.3271 0.47086E-08 -8.3271 0.10000E+01 0.0000 35 Ca(HCO3)+ 0.97631E-11 -11.0104 0.81695E-11 -11.0878 0.83677E+00 -0.0774 36 CaCl+ 0.16008E-10 -10.7957 0.13395E-10 -10.8731 0.83677E+00 -0.0774 37 CaCl2,aq 0.40986E-15 -15.3874 0.40986E-15 -15.3874 0.10000E+01 0.0000 38 CaF+ 0.19087E-12 -12.7193 0.15972E-12 -12.7967 0.83677E+00 -0.0774 39 CaOH+ 0.73532E-07 -7.1335 0.61530E-07 -7.2109 0.83677E+00 -0.0774 40 CaSO4,aq 0.19823E-15 -15.7028 0.19823E-15 -15.7028 0.10000E+01 0.0000 41 HCl,aq 0.17569E-14 -14.7553 0.17569E-14 -14.7553 0.10000E+01 0.0000 45 HF,aq 0.86742E-13 -13.0618 0.86742E-13 -13.0618 0.10000E+01 0.0000 48 FeCl+ 0.58234E-17 -17.2348 0.48728E-17 -17.3122 0.83677E+00 -0.0774 51 FeF+ 0.24848E-18 -18.6047 0.20792E-18 -18.6821 0.83677E+00 -0.0774 53 FeO,aq 0.16764E-09 -9.7756 0.16764E-09 -9.7756 0.10000E+01 0.0000 54 FeOH+ 0.12491E-10 -10.9034 0.10452E-10 -10.9808 0.83677E+00 -0.0774 55 HFeO2- 0.28213E-07 -7.5496 0.23562E-07 -7.6278 0.83517E+00 -0.0782 56 FeO+ 0.12860E-16 -16.8908 0.10761E-16 -16.9681 0.83677E+00 -0.0774 58 FeO2- 0.47575E-09 -9.3226 0.39733E-09 -9.4008 0.83517E+00 -0.0782 59 HFeO2,aq 0.37619E-11 -11.4246 0.37619E-11 -11.4246 0.10000E+01 0.0000 60 H2,aq 0.53859E-05 -5.2687 0.53673E-05 -5.2702 0.99654E+00 -0.0015 61 KCl,aq 0.30563E-09 -9.5148 0.30563E-09 -9.5148 0.10000E+01 0.0000 63 KOH,aq 0.75113E-06 -6.1243 0.75113E-06 -6.1243 0.10000E+01 0.0000 64 KSO4- 0.23630E-13 -13.6265 0.19735E-13 -13.7048 0.83517E+00 -0.0782 65 MgCO3,aq 0.19908E-12 -12.7010 0.19908E-12 -12.7010 0.10000E+01 0.0000 66 Mg(HCO3)+ 0.16828E-14 -14.7740 0.14081E-14 -14.8514 0.83677E+00 -0.0774 67 MgCl+ 0.24473E-14 -14.6113 0.20479E-14 -14.6887 0.83677E+00 -0.0774 68 MgF+ 0.11926E-15 -15.9235 0.99797E-16 -16.0009 0.83677E+00 -0.0774 69 MgOH+ 0.68634E-10 -10.1635 0.57431E-10 -10.2409 0.83677E+00 -0.0774 71 MnF+ 0.32870E-16 -16.4832 0.27505E-16 -16.5606 0.83677E+00 -0.0774 72 MnO,aq 0.17928E-08 -8.7465 0.17928E-08 -8.7465 0.10000E+01 0.0000 73 MnOH+ 0.46572E-09 -9.3319 0.38970E-09 -9.4093 0.83677E+00 -0.0774 74 MnO2-2 0.20721E-10 -10.6836 0.10736E-10 -10.9691 0.51813E+00 -0.2856 75 HMnO2- 0.20966E-09 -9.6785 0.17510E-09 -9.7567 0.83517E+00 -0.0782 78 MnCl+ 0.90928E-14 -14.0413 0.76086E-14 -14.1187 0.83677E+00 -0.0774 79 MnSO4,aq 0.26902E-19 -19.5702 0.26902E-19 -19.5702 0.10000E+01 0.0000 80 NaCl,aq 0.70783E-06 -6.1501 0.70783E-06 -6.1501 0.10000E+01 0.0000 81 NaF,aq 0.66087E-09 -9.1799 0.66087E-09 -9.1799 0.10000E+01 0.0000 82 NaOH,aq 0.95715E-04 -4.0190 0.95715E-04 -4.0190 0.10000E+01 0.0000 84 OH- 0.93099E-02 -2.0311 0.77613E-02 -2.1101 0.83366E+00 -0.0790 89 HPO3-2 0.75973E-15 -15.1193 0.39364E-15 -15.4049 0.51813E+00 -0.2856 91 H2PO3- 0.70361E-19 -19.1527 0.58763E-19 -19.2309 0.83517E+00 -0.0782 92 H3PO4,aq 0.91217E-18 -18.0399 0.91217E-18 -18.0399 0.10000E+01 0.0000 93 H2PO4- 0.38661E-10 -10.4127 0.32319E-10 -10.4905 0.83596E+00 -0.0778 94 PO4-3 0.10633E-08 -8.9733 0.25793E-09 -9.5885 0.24258E+00 -0.6151 98 HP2O7-3 0.95022E-18 -18.0222 0.21968E-18 -18.6582 0.23119E+00 -0.6360 99 P2O7-4 0.91478E-17 -17.0387 0.70498E-18 -18.1518 0.77065E-01 -1.1131 100 H2S,aq 0.65713E-08 -8.1823 0.65486E-08 -8.1839 0.99654E+00 -0.0015 101 S2-2 0.64549E-14 -14.1901 0.33445E-14 -14.4757 0.51813E+00 -0.2856 107 SO3-2 0.12889E-16 -16.8898 0.67747E-17 -17.1691 0.52563E+00 -0.2793 108 HSO3- 0.37809E-19 -19.4224 0.31577E-19 -19.5006 0.83517E+00 -0.0782 109 HSO4- 0.83196E-18 -18.0799 0.69684E-18 -18.1569 0.83758E+00 -0.0770 Charge balance for all species = -.6133E-08 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.8859932E-10 -.2227441E-01 -.2241224E+02 0.0000 2 H2O 0.1000000E+01 0.5550485E+02 0.9981982E+06 0.0000 3 Cl- 0.1542074E-03 0.1549156E-03 0.5482675E+01 6.2381 4 SO4-- 0.1870645E-10 -.1557042E-04 -.1493119E+01 9.2437 5 HCO3- 0.5953837E-05 0.3146010E-04 0.1916270E+01 4.8254 6 HS- 0.3407525E-04 0.4965226E-04 0.1639245E+01 5.5825 7 Al+++ 0.9735044E-29 0.5266738E-05 0.1418575E+00 0.7364 8 H4SiO4 0.6981625E-03 0.1353239E-01 0.1298410E+04 -3.1560 9 Ca++ 0.1246931E-06 0.2182776E-06 0.8732921E-02 13.0644 10 Mg++ 0.2112978E-10 0.9318248E-10 0.2261514E-05 9.2914 11 Fe++ 0.4653932E-13 0.2887224E-07 0.1609625E-02 6.6348 12 K+ 0.1565094E-03 0.1572609E-03 0.6138525E+01 6.2452 13 Na+ 0.1986075E-01 0.2230603E-01 0.5119196E+03 8.3479 14 Mn++ 0.1866303E-10 0.2507565E-08 0.1375211E-03 9.2383 15 F- 0.2042254E-06 0.2048865E-06 0.3885667E-02 3.3592 16 HPO4-- 0.4531841E-07 0.4642037E-07 0.4447635E-02 12.6280 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.2000393E-01 -.2000371E-01 -.2172938E-06 0.0000000E+00 2 H2O 0.4984658E+02 0.4984658E+02 -.1798915E-06 0.0000000E+00 3 Cl- 0.1391232E-03 0.1391232E-03 0.0000000E+00 0.0000000E+00 4 SO4-- -.1398231E-04 -.1398314E-04 0.8329151E-09 0.0000000E+00 5 HCO3- 0.2825300E-04 0.2825300E-04 0.0000000E+00 0.0000000E+00 6 HS- 0.4458978E-04 0.4459061E-04 -.8329151E-09 0.0000000E+00 7 Al+++ 0.4775352E-05 0.4729837E-05 0.4551500E-07 0.0000000E+00 8 H4SiO4 0.1215302E-01 0.1215288E-01 0.1444774E-06 0.0000000E+00 9 Ca++ 0.2080835E-06 0.1960259E-06 0.1205755E-07 0.0000000E+00 10 Mg++ 0.8368328E-10 0.8368328E-10 0.0000000E+00 0.0000000E+00 11 Fe++ 0.3259227E-07 0.2592895E-07 0.6663321E-08 0.0000000E+00 12 K+ 0.1412294E-03 0.1412294E-03 0.0000000E+00 0.0000000E+00 13 Na+ 0.2003215E-01 0.2003211E-01 0.4413995E-07 0.0000000E+00 14 Mn++ 0.2251939E-08 0.2251939E-08 0.0000000E+00 0.0000000E+00 15 F- 0.1840000E-06 0.1840000E-06 0.0000000E+00 0.0000000E+00 16 HPO4-- 0.4168819E-07 0.4168819E-07 0.0000000E+00 0.0000000E+00 Chg. balance for solid moles: -.6617E-23 Mass of aqueous solution: 0.899622E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 0.0002100 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 0.4414E-07 -7.355 0.1157E-04 -4.937 85.25 0.4443E-05 andradite 0.3332E-08 -8.477 0.1693E-05 -5.771 12.47 0.4399E-06 grossular 0.6875E-09 -9.163 0.3097E-06 -6.509 2.281 0.8617E-07 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8289E+00 0.8289E+00 1.0000 -0.081 grossular 0.1711E+00 0.1711E+00 1.0000 -0.767 Solid products produced: Mass = 0.000014 g Volume = 0.000005 cm3 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.0002100 moles log = -3.6778 Original solution: 1000.0103000 g Original solution / Rock added: 4761953.81 (Water/Rock Ratio), log = 6.6778 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0483 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9736E+00 0.9856 0.1006E+01 0.1021E+01 CO2,gas 0.8029E-07 1.0068 0.8475E-07 0.8417E-07 CH4,gas 0.1966E-01 1.0123 0.2086E-01 0.2061E-01 H2,gas 0.6718E-02 1.0006 0.7047E-02 0.7043E-02 H2S,gas 0.1724E-06 0.9959 0.1800E-06 0.1808E-06 S2,gas 0.2337E-28 1.0000 0.2450E-28 0.2450E-28 CO,gas 0.1518E-12 1.0000 0.1592E-12 0.1592E-12 SO3,gas 0.1941E-46 1.0000 0.2035E-46 0.2035E-46 SO2,gas 0.5322E-26 1.0000 0.5580E-26 0.5580E-26 HF,gas 0.2032E-15 1.0000 0.2130E-15 0.2130E-15 HCl,gas 0.2957E-17 1.0000 0.3100E-17 0.3100E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 17 albite -0.38 -0.38 0.00 0.000 -0.94784E-12 23 andradite 39.01 39.01 0.00 0.000 0.00000E+00 24 grossular 32.73 32.73 0.00 0.000 0.12132E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -15.43 -8.77 -2.924 0.14976E+05 -7.072 3 CH4,gas 4.54 1.16 -3.38 -0.845 0.57705E+04 -1.681 4 H2,gas 8.00 4.15 -3.85 -2.201 0.65755E+04 -2.152 5 H2S,gas -6.23 -14.67 -8.44 -4.222 0.14417E+05 -6.745 6 S2,gas -7.34 -37.65 -30.31 -4.663 0.51753E+05 -28.611 7 CO,gas 3.21 -11.28 -14.50 -4.461 0.24753E+05 -12.798 8 SO3,gas 17.12 -31.27 -48.39 -12.098 0.82625E+05 -46.691 9 SO2,gas 0.83 -27.12 -27.95 -7.454 0.47728E+05 -26.253 10 HF,gas 0.47 -16.90 -17.37 -8.685 0.29660E+05 -15.672 11 HCl,gas 5.19 -14.02 -19.21 -9.604 0.32796E+05 -17.509 12 acmite 7.71 6.60 -1.11 -0.116 0.19013E+04 16 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 20 spessartine 24.46 19.72 -4.74 -0.237 0.80894E+04 21 analcite 3.32 2.77 -0.55 -0.061 0.93857E+03 27 annite 20.12 17.42 -2.71 -0.150 0.46195E+04 28 phlogopite 27.06 25.39 -1.68 -0.093 0.28632E+04 30 anorthite 12.71 8.23 -4.49 -0.345 0.76584E+04 33 apatite-OH -18.15 -18.33 -0.18 -0.014 0.30510E+03 34 apatite-F -34.30 -35.23 -0.93 -0.077 0.15852E+04 38 aragonite 0.97 -2.37 -3.33 -1.111 0.56912E+04 39 brucite 12.57 9.29 -3.28 -0.655 0.55956E+04 40 calcite 0.81 -2.37 -3.18 -1.059 0.54270E+04 41 carnegieite-low 9.02 5.93 -3.10 -0.442 0.52848E+04 42 carnegieite-high 10.09 5.93 -4.17 -0.595 0.71118E+04 43 carpholite-Mg 8.58 4.45 -4.13 -0.275 0.70518E+04 44 carpholite-Fe 6.71 1.80 -4.92 -0.328 0.83958E+04 45 celadonite 5.34 3.65 -1.69 -0.100 0.28903E+04 46 celadonite-Fe 3.88 0.99 -2.88 -0.170 0.49248E+04 47 chrysotile 23.89 21.56 -2.33 -0.194 0.39788E+04 49 clinochlore 39.07 38.46 -0.61 -0.019 0.10378E+04 50 daphnite 28.97 25.18 -3.79 -0.118 0.64653E+04 52 chlorite-Al-free 47.17 43.12 -4.05 -0.169 0.69128E+04 54 chloritoid-Fe 9.17 4.95 -4.22 -0.281 0.72090E+04 55 chloritoid-Mn 11.40 7.56 -3.85 -0.256 0.65669E+04 57 coesite -2.38 -3.16 -0.78 -0.260 0.13318E+04 64 cristobalite -2.56 -3.16 -0.60 -0.199 0.10171E+04 66 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71234E+04 68 diaspore 2.87 0.74 -2.14 -0.356 0.36494E+04 69 diamond -3.10 -7.13 -4.03 -1.152 0.68829E+04 70 diopside 16.18 16.04 -0.14 -0.014 0.23507E+03 71 hedenbergite 14.21 13.39 -0.82 -0.082 0.14022E+04 74 enstatite 17.26 12.27 -4.99 -0.499 0.85274E+04 76 clinoenstatite 17.17 12.27 -4.90 -0.490 0.83590E+04 78 epidote 24.67 22.69 -1.98 -0.096 0.33742E+04 79 clinozoisite 22.81 18.87 -3.94 -0.179 0.67211E+04 80 epidote-Fe 29.84 26.52 -3.32 -0.173 0.56739E+04 81 fayalite 14.05 10.11 -3.93 -0.562 0.67140E+04 82 ferrosilite 11.15 6.96 -4.19 -0.419 0.71576E+04 86 gibbsite 4.08 0.74 -3.34 -0.478 0.57079E+04 87 glaucophane 22.97 20.79 -2.18 -0.059 0.37229E+04 88 glaucophane-Fe 17.28 12.82 -4.45 -0.120 0.76003E+04 89 graphite -3.55 -7.13 -3.59 -1.025 0.61251E+04 90 greenalite 16.14 13.59 -2.55 -0.212 0.43492E+04 93 hematite 12.57 9.12 -3.45 -0.418 0.58828E+04 94 heulandite -5.83 -7.56 -1.73 -0.079 0.29504E+04 98 jadeite 4.22 2.77 -1.44 -0.144 0.24641E+04 100 kalsilite 7.58 3.83 -3.76 -0.537 0.64172E+04 101 kaolinite -1.33 -4.84 -3.51 -0.319 0.59873E+04 104 laumontite 2.88 1.91 -0.97 -0.065 0.16570E+04 105 lawsonite 9.62 8.23 -1.39 -0.093 0.23751E+04 106 leucite 4.12 0.67 -3.45 -0.345 0.58896E+04 108 lizardite 23.24 21.56 -1.68 -0.140 0.28714E+04 110 magnetite 20.09 15.76 -4.33 -0.354 0.73963E+04 111 minnesotaite 10.39 7.28 -3.11 -0.183 0.53065E+04 115 manganosite 14.06 9.24 -4.82 -1.205 0.82296E+04 119 microcline -2.49 -2.49 0.00 0.000 0.17700E-01 123 muscovite 2.58 -1.01 -3.60 -0.212 0.61403E+04 124 paragonite 4.24 1.09 -3.15 -0.185 0.53794E+04 125 nepheline 8.34 5.93 -2.41 -0.344 0.41171E+04 131 periclase-Fe 11.63 6.63 -4.99 -1.248 0.85233E+04 137 phlogopite-Na 29.65 27.49 -2.16 -0.120 0.36820E+04 139 prehnite 19.37 18.13 -1.24 -0.073 0.21147E+04 140 prehnite-Fe 22.50 21.96 -0.54 -0.033 0.92281E+03 141 pumpellyite-Fe 46.27 43.64 -2.63 -0.058 0.44932E+04 142 pumpellyite-Mg 48.99 46.29 -2.70 -0.060 0.46107E+04 146 pyrrhotite -4.26 -8.04 -3.78 -1.260 0.64521E+04 147 pyrrhotiteFe0.875 -6.02 -9.38 -3.37 -1.238 0.57472E+04 148 pyroxmangite 7.40 6.08 -1.32 -0.263 0.22477E+04 149 pyrophyllite -6.18 -11.15 -4.98 -0.311 0.84957E+04 150 quartz -2.99 -3.16 -0.17 -0.056 0.28448E+03 155 rhodonite 7.45 6.08 -1.36 -0.273 0.23279E+04 156 sanidine -1.28 -2.49 -1.21 -0.093 0.20678E+04 166 stilbite -7.52 -7.56 -0.03 -0.002 0.56523E+02 167 stilpnomelane-Fe 13.02 12.52 -0.50 -0.015 0.84661E+03 168 stilpnomelane-Mg 27.44 25.80 -1.64 -0.049 0.27956E+04 174 talc 16.49 15.25 -1.24 -0.073 0.21190E+04 177 tephroite 18.09 15.32 -2.77 -0.395 0.47214E+04 181 tridymite -2.63 -3.16 -0.53 -0.177 0.90446E+03 182 tremolite 47.87 47.34 -0.53 -0.014 0.90805E+03 183 ferroactinolite 38.45 34.05 -4.40 -0.119 0.75093E+04 184 troilite-low -4.41 -8.04 -3.63 -1.209 0.61949E+04 190 wairakite 3.95 1.91 -2.04 -0.120 0.34790E+04 191 walstromite 11.51 9.91 -1.60 -0.320 0.27335E+04 192 wollastonite 10.46 9.91 -0.55 -0.111 0.94395E+03 193 pseudo-wollastonite 11.00 9.91 -1.09 -0.218 0.18638E+04 194 zoisite 22.85 18.87 -3.98 -0.181 0.67951E+04 195 akaganeite 7.75 4.56 -3.19 -0.691 0.54539E+04 202 chalcedony -2.80 -3.16 -0.35 -0.118 0.60378E+03 204 montmorillonite-Ca -2.29 -6.17 -3.88 -0.240 0.66282E+04 205 montmorillonite-K -2.24 -6.27 -4.03 -0.247 0.68821E+04 206 montmorillonite-Mg -2.48 -6.80 -4.32 -0.267 0.73682E+04 207 montmorillonite-Na -2.04 -5.57 -3.54 -0.217 0.60370E+04 208 nontronite-Ca 3.21 -0.06 -3.28 -0.213 0.55966E+04 209 nontronite-H 2.53 -2.22 -4.75 -0.318 0.81131E+04 210 nontronite-K 3.34 -0.16 -3.50 -0.225 0.59737E+04 211 nontronite-Mg 3.07 -0.69 -3.76 -0.244 0.64207E+04 212 nontronite-Na 3.52 0.54 -2.98 -0.192 0.50946E+04 228 tobermorite 9.82 7.73 -2.10 -0.572 0.35797E+04 234 alabandite -0.98 -5.44 -4.46 -1.486 0.76114E+04 237 boehmite 4.41 0.74 -3.67 -0.612 0.62663E+04 239 ferrous-oxide 9.81 6.63 -3.18 -0.794 0.54242E+04 245 silica-amorphous -2.09 -3.16 -1.06 -0.355 0.18180E+04 247 an20ab80 2.02 1.34 -0.68 -0.052 0.11608E+04 248 an25ab75 2.65 1.77 -0.88 -0.067 0.14980E+04 249 an30ab70 3.28 2.20 -1.08 -0.083 0.18448E+04 250 tr.625ac.25prg.125 45.16 44.96 -0.20 -0.005 0.34291E+03 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 0.0000100 MOLES Current total amount of reactant added: 0.0002100 MOLES New total amount of reactant added: 0.0002200 MOLES Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.5508E-08 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 6 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 0.0002200 Water: Moles liquid = 0.4985E+02 kg liquid = 0.8981E+00 Moles total = 0.4985E+02 kg total = 0.8980E+00 Activity = 1.0000 Stoichiometric ionic strength = .1134424E-01 Osmotic coef. = 0.9686 True ionic strength = .2002963E-01 Chg. balance for total moles = -.5508E-08 Max. difference allowed = 0.1392E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.88615E-10 -10.0525 0.74456E-10 -10.1281 0.84022E+00 -0.0756 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.15427E-03 -3.8117 0.12884E-03 -3.8899 0.83517E+00 -0.0782 4 SO4-- 0.19828E-10 -10.7027 0.10295E-10 -10.9874 0.51923E+00 -0.2846 5 HCO3- 0.62451E-05 -5.2045 0.52234E-05 -5.2820 0.83639E+00 -0.0776 6 HS- 0.34346E-04 -4.4641 0.28689E-04 -4.5423 0.83529E+00 -0.0782 7 Al+++ 0.97372E-29 -29.0116 0.22489E-29 -29.6480 0.23095E+00 -0.6365 8 H4SiO4 0.69828E-03 -3.1560 0.69828E-03 -3.1560 0.10000E+01 0.0000 9 Ca++ 0.12449E-06 -6.9049 0.64163E-07 -7.1927 0.51542E+00 -0.2878 10 Mg++ 0.21130E-10 -10.6751 0.10841E-10 -10.9649 0.51306E+00 -0.2898 11 Fe++ 0.46421E-13 -13.3333 0.23843E-13 -13.6226 0.51362E+00 -0.2894 12 K+ 0.15651E-03 -3.8055 0.13093E-03 -3.8829 0.83659E+00 -0.0775 13 Na+ 0.19861E-01 -1.7020 0.16584E-01 -1.7803 0.83502E+00 -0.0783 14 Mn++ 0.18669E-10 -10.7289 0.95969E-11 -11.0179 0.51405E+00 -0.2890 15 F- 0.20867E-06 -6.6806 0.17391E-06 -6.7597 0.83345E+00 -0.0791 16 HPO4-- 0.45319E-07 -7.3437 0.23534E-07 -7.6283 0.51930E+00 -0.2846 18 HSiO3- 0.10485E-01 -1.9794 0.87570E-02 -2.0576 0.83517E+00 -0.0782 19 Ca(HSiO3)+ 0.15292E-07 -7.8155 0.12796E-07 -7.8929 0.83677E+00 -0.0774 20 Mg(HSiO3)+ 0.32156E-11 -11.4927 0.26907E-11 -11.5701 0.83677E+00 -0.0774 21 NaHSiO3,aq 0.23488E-02 -2.6291 0.23488E-02 -2.6291 0.10000E+01 0.0000 22 AlO+ 0.65953E-16 -16.1808 0.55187E-16 -16.2582 0.83677E+00 -0.0774 24 HAlO2,aq 0.14761E-09 -9.8309 0.14761E-09 -9.8309 0.10000E+01 0.0000 25 AlO2- 0.52640E-05 -5.2787 0.43884E-05 -5.3577 0.83366E+00 -0.0790 26 CH4,aq 0.14188E-04 -4.8481 0.14139E-04 -4.8496 0.99654E+00 -0.0015 27 C2H6,aq 0.64704E-14 -14.1891 0.64480E-14 -14.1906 0.99654E+00 -0.0015 31 CO,aq 0.11064E-15 -15.9561 0.11064E-15 -15.9561 0.10000E+01 0.0000 32 CO2,aq 0.83390E-09 -9.0789 0.83101E-09 -9.0804 0.99654E+00 -0.0015 33 CO3-2 0.11827E-04 -4.9271 0.61277E-05 -5.2127 0.51813E+00 -0.2856 34 CaCO3,aq 0.49299E-08 -8.3072 0.49299E-08 -8.3072 0.10000E+01 0.0000 35 Ca(HCO3)+ 0.10224E-10 -10.9904 0.85549E-11 -11.0678 0.83677E+00 -0.0774 36 CaCl+ 0.15988E-10 -10.7962 0.13378E-10 -10.8736 0.83677E+00 -0.0774 37 CaCl2,aq 0.40952E-15 -15.3877 0.40952E-15 -15.3877 0.10000E+01 0.0000 38 CaF+ 0.19470E-12 -12.7106 0.16292E-12 -12.7880 0.83677E+00 -0.0774 39 CaOH+ 0.73397E-07 -7.1343 0.61416E-07 -7.2117 0.83677E+00 -0.0774 40 CaSO4,aq 0.20976E-15 -15.6783 0.20976E-15 -15.6783 0.10000E+01 0.0000 41 HCl,aq 0.17579E-14 -14.7550 0.17579E-14 -14.7550 0.10000E+01 0.0000 45 HF,aq 0.88643E-13 -13.0524 0.88643E-13 -13.0524 0.10000E+01 0.0000 48 FeCl+ 0.58110E-17 -17.2357 0.48625E-17 -17.3131 0.83677E+00 -0.0774 51 FeF+ 0.25323E-18 -18.5965 0.21190E-18 -18.6739 0.83677E+00 -0.0774 53 FeO,aq 0.16716E-09 -9.7769 0.16716E-09 -9.7769 0.10000E+01 0.0000 54 FeOH+ 0.12457E-10 -10.9046 0.10424E-10 -10.9820 0.83677E+00 -0.0774 55 HFeO2- 0.28126E-07 -7.5509 0.23490E-07 -7.6291 0.83517E+00 -0.0782 56 FeO+ 0.12906E-16 -16.8892 0.10800E-16 -16.9666 0.83677E+00 -0.0774 58 FeO2- 0.47729E-09 -9.3212 0.39862E-09 -9.3994 0.83517E+00 -0.0782 59 HFeO2,aq 0.37748E-11 -11.4231 0.37748E-11 -11.4231 0.10000E+01 0.0000 60 H2,aq 0.53184E-05 -5.2742 0.53000E-05 -5.2757 0.99654E+00 -0.0015 61 KCl,aq 0.30576E-09 -9.5146 0.30576E-09 -9.5146 0.10000E+01 0.0000 63 KOH,aq 0.75100E-06 -6.1244 0.75100E-06 -6.1244 0.10000E+01 0.0000 64 KSO4- 0.25046E-13 -13.6013 0.20918E-13 -13.6795 0.83517E+00 -0.0782 65 MgCO3,aq 0.20879E-12 -12.6803 0.20879E-12 -12.6803 0.10000E+01 0.0000 66 Mg(HCO3)+ 0.17651E-14 -14.7532 0.14770E-14 -14.8306 0.83677E+00 -0.0774 67 MgCl+ 0.24484E-14 -14.6111 0.20488E-14 -14.6885 0.83677E+00 -0.0774 68 MgF+ 0.12186E-15 -15.9141 0.10197E-15 -15.9915 0.83677E+00 -0.0774 69 MgOH+ 0.68623E-10 -10.1635 0.57422E-10 -10.2409 0.83677E+00 -0.0774 71 MnF+ 0.33596E-16 -16.4737 0.28112E-16 -16.5511 0.83677E+00 -0.0774 72 MnO,aq 0.17928E-08 -8.7465 0.17928E-08 -8.7465 0.10000E+01 0.0000 73 MnOH+ 0.46579E-09 -9.3318 0.38976E-09 -9.4092 0.83677E+00 -0.0774 74 MnO2-2 0.20714E-10 -10.6837 0.10732E-10 -10.9693 0.51813E+00 -0.2856 75 HMnO2- 0.20962E-09 -9.6786 0.17507E-09 -9.7568 0.83517E+00 -0.0782 78 MnCl+ 0.90996E-14 -14.0410 0.76143E-14 -14.1184 0.83677E+00 -0.0774 79 MnSO4,aq 0.28524E-19 -19.5448 0.28524E-19 -19.5448 0.10000E+01 0.0000 80 NaCl,aq 0.70812E-06 -6.1499 0.70812E-06 -6.1499 0.10000E+01 0.0000 81 NaF,aq 0.67523E-09 -9.1705 0.67523E-09 -9.1705 0.10000E+01 0.0000 82 NaOH,aq 0.95698E-04 -4.0191 0.95698E-04 -4.0191 0.10000E+01 0.0000 84 OH- 0.93083E-02 -2.0311 0.77599E-02 -2.1101 0.83366E+00 -0.0790 89 HPO3-2 0.75021E-15 -15.1248 0.38870E-15 -15.4104 0.51813E+00 -0.2856 91 H2PO3- 0.69490E-19 -19.1581 0.58036E-19 -19.2363 0.83517E+00 -0.0782 92 H3PO4,aq 0.91248E-18 -18.0398 0.91248E-18 -18.0398 0.10000E+01 0.0000 93 H2PO4- 0.38668E-10 -10.4127 0.32324E-10 -10.4905 0.83596E+00 -0.0778 94 PO4-3 0.10631E-08 -8.9734 0.25789E-09 -9.5886 0.24257E+00 -0.6152 98 HP2O7-3 0.95039E-18 -18.0221 0.21972E-18 -18.6581 0.23119E+00 -0.6360 99 P2O7-4 0.91480E-17 -17.0387 0.70497E-18 -18.1518 0.77063E-01 -1.1132 100 H2S,aq 0.66246E-08 -8.1788 0.66017E-08 -8.1803 0.99654E+00 -0.0015 101 S2-2 0.66411E-14 -14.1778 0.34409E-14 -14.4633 0.51813E+00 -0.2856 107 SO3-2 0.13490E-16 -16.8700 0.70908E-17 -17.1493 0.52563E+00 -0.2793 108 HSO3- 0.39580E-19 -19.4025 0.33056E-19 -19.4807 0.83517E+00 -0.0782 109 HSO4- 0.88199E-18 -18.0545 0.73874E-18 -18.1315 0.83758E+00 -0.0770 Charge balance for all species = -.6133E-08 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.8861485E-10 -.2227319E-01 -.2241101E+02 0.0000 2 H2O 0.1000000E+01 0.5550485E+02 0.9981982E+06 0.0000 3 Cl- 0.1542728E-03 0.1549813E-03 0.5484999E+01 6.2382 4 SO4-- 0.1982814E-10 -.1551726E-04 -.1488021E+01 9.2688 5 HCO3- 0.6245146E-05 0.3226517E-04 0.1965308E+01 4.8461 6 HS- 0.3434577E-04 0.4986967E-04 0.1646423E+01 5.5858 7 Al+++ 0.9737230E-29 0.5264187E-05 0.1417887E+00 0.7363 8 H4SiO4 0.6982758E-03 0.1353238E-01 0.1298409E+04 -3.1560 9 Ca++ 0.1244863E-06 0.2181317E-06 0.8727084E-02 13.0635 10 Mg++ 0.2113036E-10 0.9318246E-10 0.2261514E-05 9.2913 11 Fe++ 0.4642118E-13 0.2878686E-07 0.1604865E-02 6.6336 12 K+ 0.1565095E-03 0.1572608E-03 0.6138523E+01 6.2452 13 Na+ 0.1986078E-01 0.2230602E-01 0.5119194E+03 8.3478 14 Mn++ 0.1866931E-10 0.2507565E-08 0.1375211E-03 9.2383 15 F- 0.2086650E-06 0.2093405E-06 0.3970138E-02 3.3684 16 HPO4-- 0.4531857E-07 0.4642036E-07 0.4447634E-02 12.6279 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.2000285E-01 -.2000262E-01 -.2268508E-06 0.0000000E+00 2 H2O 0.4984659E+02 0.4984659E+02 -.1890492E-06 0.0000000E+00 3 Cl- 0.1391822E-03 0.1391822E-03 0.0000000E+00 0.0000000E+00 4 SO4-- -.1393456E-04 -.1393540E-04 0.8424988E-09 0.0000000E+00 5 HCO3- 0.2897600E-04 0.2897600E-04 0.0000000E+00 0.0000000E+00 6 HS- 0.4478503E-04 0.4478587E-04 -.8424988E-09 0.0000000E+00 7 Al+++ 0.4775352E-05 0.4727547E-05 0.4780549E-07 0.0000000E+00 8 H4SiO4 0.1215302E-01 0.1215287E-01 0.1514479E-06 0.0000000E+00 9 Ca++ 0.2080835E-06 0.1958950E-06 0.1218852E-07 0.0000000E+00 10 Mg++ 0.8368328E-10 0.8368328E-10 0.0000000E+00 0.0000000E+00 11 Fe++ 0.3259227E-07 0.2585228E-07 0.6739990E-08 0.0000000E+00 12 K+ 0.1412294E-03 0.1412294E-03 0.0000000E+00 0.0000000E+00 13 Na+ 0.2003215E-01 0.2003210E-01 0.4641980E-07 0.0000000E+00 14 Mn++ 0.2251939E-08 0.2251939E-08 0.0000000E+00 0.0000000E+00 15 F- 0.1880000E-06 0.1880000E-06 0.0000000E+00 0.0000000E+00 16 HPO4-- 0.4168819E-07 0.4168819E-07 0.0000000E+00 0.0000000E+00 Chg. balance for solid moles: 0.6617E-23 Mass of aqueous solution: 0.899622E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 0.0002200 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 0.4642E-07 -7.333 0.1217E-04 -4.915 85.74 0.4673E-05 andradite 0.3370E-08 -8.472 0.1713E-05 -5.766 12.06 0.4449E-06 grossular 0.6928E-09 -9.159 0.3121E-06 -6.506 2.198 0.8684E-07 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8295E+00 0.8295E+00 1.0000 -0.081 grossular 0.1705E+00 0.1705E+00 1.0000 -0.768 Solid products produced: Mass = 0.000014 g Volume = 0.000005 cm3 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.0002200 moles log = -3.6576 Original solution: 1000.0103000 g Original solution / Rock added: 4545501.36 (Water/Rock Ratio), log = 6.6576 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0482 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9738E+00 0.9856 0.1006E+01 0.1021E+01 CO2,gas 0.8424E-07 1.0068 0.8891E-07 0.8830E-07 CH4,gas 0.1961E-01 1.0123 0.2081E-01 0.2056E-01 H2,gas 0.6635E-02 1.0006 0.6958E-02 0.6954E-02 H2S,gas 0.1738E-06 0.9959 0.1815E-06 0.1822E-06 S2,gas 0.2436E-28 1.0000 0.2553E-28 0.2553E-28 CO,gas 0.1573E-12 1.0000 0.1649E-12 0.1649E-12 SO3,gas 0.2059E-46 1.0000 0.2158E-46 0.2158E-46 SO2,gas 0.5573E-26 1.0000 0.5842E-26 0.5842E-26 HF,gas 0.2076E-15 1.0000 0.2177E-15 0.2177E-15 HCl,gas 0.2959E-17 1.0000 0.3102E-17 0.3102E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 17 albite -0.38 -0.38 0.00 0.000 -0.94784E-12 23 andradite 39.01 39.01 0.00 0.000 -0.24265E-10 24 grossular 32.73 32.73 0.00 0.000 0.12132E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -15.41 -8.75 -2.917 0.14940E+05 -7.051 3 CH4,gas 4.54 1.16 -3.38 -0.845 0.57724E+04 -1.682 4 H2,gas 8.00 4.14 -3.86 -2.204 0.65848E+04 -2.157 5 H2S,gas -6.23 -14.67 -8.44 -4.220 0.14411E+05 -6.741 6 S2,gas -7.34 -37.63 -30.29 -4.660 0.51723E+05 -28.593 7 CO,gas 3.21 -11.27 -14.48 -4.456 0.24727E+05 -12.783 8 SO3,gas 17.12 -31.24 -48.36 -12.091 0.82582E+05 -46.666 9 SO2,gas 0.83 -27.10 -27.93 -7.449 0.47694E+05 -26.233 10 HF,gas 0.47 -16.89 -17.36 -8.681 0.29644E+05 -15.662 11 HCl,gas 5.19 -14.02 -19.21 -9.604 0.32796E+05 -17.508 12 acmite 7.71 6.60 -1.11 -0.116 0.18986E+04 16 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 20 spessartine 24.46 19.72 -4.74 -0.237 0.80896E+04 21 analcite 3.32 2.77 -0.55 -0.061 0.93869E+03 27 annite 20.12 17.41 -2.71 -0.151 0.46259E+04 28 phlogopite 27.06 25.39 -1.68 -0.093 0.28639E+04 30 anorthite 12.71 8.22 -4.49 -0.345 0.76602E+04 33 apatite-OH -18.15 -18.34 -0.18 -0.014 0.31180E+03 34 apatite-F -34.30 -35.22 -0.92 -0.077 0.15758E+04 38 aragonite 0.97 -2.35 -3.31 -1.104 0.56572E+04 39 brucite 12.57 9.29 -3.28 -0.655 0.55959E+04 40 calcite 0.81 -2.35 -3.16 -1.053 0.53930E+04 41 carnegieite-low 9.02 5.93 -3.10 -0.442 0.52850E+04 42 carnegieite-high 10.09 5.93 -4.17 -0.595 0.71120E+04 43 carpholite-Mg 8.58 4.45 -4.13 -0.275 0.70523E+04 44 carpholite-Fe 6.71 1.79 -4.92 -0.328 0.83982E+04 45 celadonite 5.34 3.65 -1.69 -0.100 0.28904E+04 46 celadonite-Fe 3.88 0.99 -2.89 -0.170 0.49268E+04 47 chrysotile 23.89 21.56 -2.33 -0.194 0.39793E+04 49 clinochlore 39.07 38.46 -0.61 -0.019 0.10391E+04 50 daphnite 28.97 25.17 -3.79 -0.119 0.64762E+04 52 chlorite-Al-free 47.17 43.12 -4.05 -0.169 0.69138E+04 54 chloritoid-Fe 9.17 4.95 -4.22 -0.282 0.72115E+04 55 chloritoid-Mn 11.40 7.55 -3.85 -0.256 0.65673E+04 57 coesite -2.38 -3.16 -0.78 -0.260 0.13317E+04 64 cristobalite -2.56 -3.16 -0.60 -0.199 0.10170E+04 66 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71234E+04 68 diaspore 2.87 0.74 -2.14 -0.356 0.36496E+04 69 diamond -3.10 -7.12 -4.02 -1.149 0.68660E+04 70 diopside 16.18 16.04 -0.14 -0.014 0.23657E+03 71 hedenbergite 14.21 13.39 -0.82 -0.082 0.14056E+04 74 enstatite 17.26 12.27 -4.99 -0.499 0.85276E+04 76 clinoenstatite 17.17 12.27 -4.90 -0.490 0.83592E+04 78 epidote 24.67 22.69 -1.98 -0.096 0.33747E+04 79 clinozoisite 22.81 18.87 -3.94 -0.179 0.67244E+04 80 epidote-Fe 29.84 26.52 -3.32 -0.173 0.56717E+04 81 fayalite 14.05 10.11 -3.93 -0.562 0.67182E+04 82 ferrosilite 11.15 6.96 -4.19 -0.419 0.71616E+04 86 gibbsite 4.08 0.74 -3.34 -0.478 0.57082E+04 87 glaucophane 22.97 20.79 -2.18 -0.059 0.37234E+04 88 glaucophane-Fe 17.28 12.82 -4.45 -0.120 0.76065E+04 89 graphite -3.55 -7.12 -3.58 -1.022 0.61083E+04 90 greenalite 16.14 13.59 -2.55 -0.213 0.43554E+04 93 hematite 12.57 9.12 -3.44 -0.417 0.58777E+04 94 heulandite -5.83 -7.56 -1.73 -0.079 0.29515E+04 98 jadeite 4.22 2.77 -1.44 -0.144 0.24642E+04 100 kalsilite 7.58 3.83 -3.76 -0.537 0.64175E+04 101 kaolinite -1.33 -4.84 -3.51 -0.319 0.59875E+04 104 laumontite 2.88 1.91 -0.97 -0.065 0.16585E+04 105 lawsonite 9.62 8.22 -1.39 -0.093 0.23768E+04 106 leucite 4.12 0.67 -3.45 -0.345 0.58897E+04 108 lizardite 23.24 21.56 -1.68 -0.140 0.28719E+04 110 magnetite 20.09 15.76 -4.33 -0.353 0.73934E+04 111 minnesotaite 10.39 7.28 -3.11 -0.183 0.53125E+04 115 manganosite 14.06 9.24 -4.82 -1.205 0.82296E+04 119 microcline -2.49 -2.49 0.00 0.000 0.18535E-01 123 muscovite 2.58 -1.01 -3.60 -0.212 0.61408E+04 124 paragonite 4.24 1.09 -3.15 -0.185 0.53799E+04 125 nepheline 8.34 5.93 -2.41 -0.344 0.41174E+04 131 periclase-Fe 11.63 6.63 -4.99 -1.248 0.85255E+04 137 phlogopite-Na 29.65 27.49 -2.16 -0.120 0.36827E+04 139 prehnite 19.37 18.13 -1.24 -0.073 0.21178E+04 140 prehnite-Fe 22.50 21.96 -0.54 -0.033 0.92314E+03 141 pumpellyite-Fe 46.27 43.63 -2.64 -0.059 0.45017E+04 142 pumpellyite-Mg 48.99 46.29 -2.70 -0.060 0.46174E+04 146 pyrrhotite -4.26 -8.04 -3.78 -1.259 0.64483E+04 147 pyrrhotiteFe0.875 -6.02 -9.38 -3.36 -1.237 0.57420E+04 148 pyroxmangite 7.40 6.08 -1.32 -0.263 0.22476E+04 149 pyrophyllite -6.18 -11.15 -4.98 -0.311 0.84957E+04 150 quartz -2.99 -3.16 -0.17 -0.056 0.28436E+03 155 rhodonite 7.45 6.08 -1.36 -0.273 0.23278E+04 156 sanidine -1.28 -2.49 -1.21 -0.093 0.20678E+04 166 stilbite -7.52 -7.56 -0.03 -0.002 0.57639E+02 167 stilpnomelane-Fe 13.02 12.52 -0.50 -0.015 0.85691E+03 168 stilpnomelane-Mg 27.44 25.80 -1.64 -0.049 0.27964E+04 174 talc 16.49 15.25 -1.24 -0.073 0.21192E+04 177 tephroite 18.09 15.32 -2.77 -0.395 0.47213E+04 181 tridymite -2.63 -3.16 -0.53 -0.177 0.90434E+03 182 tremolite 47.87 47.34 -0.53 -0.014 0.91129E+03 183 ferroactinolite 38.45 34.05 -4.41 -0.119 0.75221E+04 184 troilite-low -4.41 -8.04 -3.63 -1.209 0.61911E+04 190 wairakite 3.95 1.91 -2.04 -0.120 0.34804E+04 191 walstromite 11.51 9.91 -1.60 -0.320 0.27349E+04 192 wollastonite 10.46 9.91 -0.55 -0.111 0.94532E+03 193 pseudo-wollastonite 11.00 9.91 -1.09 -0.218 0.18652E+04 194 zoisite 22.85 18.87 -3.98 -0.181 0.67984E+04 195 akaganeite 7.75 4.56 -3.19 -0.690 0.54514E+04 202 chalcedony -2.80 -3.16 -0.35 -0.118 0.60366E+03 204 montmorillonite-Ca -2.29 -6.17 -3.88 -0.240 0.66284E+04 205 montmorillonite-K -2.24 -6.27 -4.03 -0.247 0.68821E+04 206 montmorillonite-Mg -2.48 -6.80 -4.32 -0.267 0.73682E+04 207 montmorillonite-Na -2.04 -5.57 -3.54 -0.217 0.60370E+04 208 nontronite-Ca 3.21 -0.06 -3.27 -0.212 0.55915E+04 209 nontronite-H 2.53 -2.22 -4.75 -0.318 0.81076E+04 210 nontronite-K 3.34 -0.15 -3.50 -0.224 0.59683E+04 211 nontronite-Mg 3.07 -0.68 -3.76 -0.244 0.64153E+04 212 nontronite-Na 3.52 0.54 -2.98 -0.191 0.50892E+04 228 tobermorite 9.82 7.73 -2.10 -0.572 0.35808E+04 234 alabandite -0.98 -5.43 -4.45 -1.485 0.76054E+04 237 boehmite 4.41 0.74 -3.67 -0.612 0.62665E+04 239 ferrous-oxide 9.81 6.63 -3.18 -0.795 0.54264E+04 245 silica-amorphous -2.09 -3.16 -1.06 -0.355 0.18178E+04 247 an20ab80 2.02 1.34 -0.68 -0.052 0.11612E+04 248 an25ab75 2.65 1.77 -0.88 -0.068 0.14985E+04 249 an30ab70 3.28 2.20 -1.08 -0.083 0.18453E+04 250 tr.625ac.25prg.125 45.16 44.96 -0.20 -0.005 0.34863E+03 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 0.0000100 MOLES Current total amount of reactant added: 0.0002200 MOLES New total amount of reactant added: 0.0002300 MOLES Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.5508E-08 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 6 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 0.0002300 Water: Moles liquid = 0.4985E+02 kg liquid = 0.8981E+00 Moles total = 0.4985E+02 kg total = 0.8980E+00 Activity = 1.0000 Stoichiometric ionic strength = .1134488E-01 Osmotic coef. = 0.9686 True ionic strength = .2003022E-01 Chg. balance for total moles = -.5508E-08 Max. difference allowed = 0.1392E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.88630E-10 -10.0524 0.74469E-10 -10.1280 0.84022E+00 -0.0756 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.15434E-03 -3.8115 0.12890E-03 -3.8898 0.83517E+00 -0.0782 4 SO4-- 0.20973E-10 -10.6783 0.10890E-10 -10.9630 0.51923E+00 -0.2846 5 HCO3- 0.65368E-05 -5.1846 0.54673E-05 -5.2622 0.83639E+00 -0.0776 6 HS- 0.34616E-04 -4.4607 0.28915E-04 -4.5389 0.83529E+00 -0.0782 7 Al+++ 0.97394E-29 -29.0115 0.22493E-29 -29.6479 0.23095E+00 -0.6365 8 H4SiO4 0.69839E-03 -3.1559 0.69839E-03 -3.1559 0.10000E+01 0.0000 9 Ca++ 0.12429E-06 -6.9056 0.64058E-07 -7.1934 0.51541E+00 -0.2878 10 Mg++ 0.21131E-10 -10.6751 0.10841E-10 -10.9649 0.51306E+00 -0.2898 11 Fe++ 0.46312E-13 -13.3343 0.23786E-13 -13.6237 0.51362E+00 -0.2894 12 K+ 0.15651E-03 -3.8055 0.13093E-03 -3.8829 0.83659E+00 -0.0775 13 Na+ 0.19861E-01 -1.7020 0.16584E-01 -1.7803 0.83501E+00 -0.0783 14 Mn++ 0.18676E-10 -10.7287 0.96001E-11 -11.0177 0.51404E+00 -0.2890 15 F- 0.21310E-06 -6.6714 0.17761E-06 -6.7505 0.83344E+00 -0.0791 16 HPO4-- 0.45319E-07 -7.3437 0.23534E-07 -7.6283 0.51930E+00 -0.2846 18 HSiO3- 0.10485E-01 -1.9794 0.87569E-02 -2.0577 0.83517E+00 -0.0782 19 Ca(HSiO3)+ 0.15267E-07 -7.8162 0.12775E-07 -7.8936 0.83677E+00 -0.0774 20 Mg(HSiO3)+ 0.32156E-11 -11.4927 0.26907E-11 -11.5701 0.83677E+00 -0.0774 21 NaHSiO3,aq 0.23488E-02 -2.6292 0.23488E-02 -2.6292 0.10000E+01 0.0000 22 AlO+ 0.65943E-16 -16.1808 0.55179E-16 -16.2582 0.83677E+00 -0.0774 24 HAlO2,aq 0.14756E-09 -9.8310 0.14756E-09 -9.8310 0.10000E+01 0.0000 25 AlO2- 0.52615E-05 -5.2789 0.43863E-05 -5.3579 0.83366E+00 -0.0790 26 CH4,aq 0.14151E-04 -4.8492 0.14102E-04 -4.8507 0.99654E+00 -0.0015 27 C2H6,aq 0.65150E-14 -14.1861 0.64924E-14 -14.1876 0.99654E+00 -0.0015 31 CO,aq 0.11443E-15 -15.9414 0.11443E-15 -15.9414 0.10000E+01 0.0000 32 CO2,aq 0.87300E-09 -9.0590 0.86998E-09 -9.0605 0.99654E+00 -0.0015 33 CO3-2 0.12377E-04 -4.9074 0.64127E-05 -5.1930 0.51812E+00 -0.2856 34 CaCO3,aq 0.51508E-08 -8.2881 0.51508E-08 -8.2881 0.10000E+01 0.0000 35 Ca(HCO3)+ 0.10684E-10 -10.9713 0.89399E-11 -11.0487 0.83677E+00 -0.0774 36 CaCl+ 0.15969E-10 -10.7967 0.13362E-10 -10.8741 0.83677E+00 -0.0774 37 CaCl2,aq 0.40920E-15 -15.3881 0.40920E-15 -15.3881 0.10000E+01 0.0000 38 CaF+ 0.19852E-12 -12.7022 0.16611E-12 -12.7796 0.83677E+00 -0.0774 39 CaOH+ 0.73265E-07 -7.1351 0.61306E-07 -7.2125 0.83677E+00 -0.0774 40 CaSO4,aq 0.22151E-15 -15.6546 0.22151E-15 -15.6546 0.10000E+01 0.0000 41 HCl,aq 0.17590E-14 -14.7547 0.17590E-14 -14.7547 0.10000E+01 0.0000 45 HF,aq 0.90545E-13 -13.0431 0.90545E-13 -13.0431 0.10000E+01 0.0000 48 FeCl+ 0.57997E-17 -17.2366 0.48530E-17 -17.3140 0.83677E+00 -0.0774 51 FeF+ 0.25801E-18 -18.5884 0.21589E-18 -18.6658 0.83677E+00 -0.0774 53 FeO,aq 0.16670E-09 -9.7781 0.16670E-09 -9.7781 0.10000E+01 0.0000 54 FeOH+ 0.12426E-10 -10.9057 0.10397E-10 -10.9831 0.83677E+00 -0.0774 55 HFeO2- 0.28045E-07 -7.5521 0.23422E-07 -7.6304 0.83517E+00 -0.0782 56 FeO+ 0.12952E-16 -16.8877 0.10838E-16 -16.9651 0.83677E+00 -0.0774 58 FeO2- 0.47881E-09 -9.3198 0.39988E-09 -9.3981 0.83517E+00 -0.0782 59 HFeO2,aq 0.37874E-11 -11.4217 0.37874E-11 -11.4217 0.10000E+01 0.0000 60 H2,aq 0.52544E-05 -5.2795 0.52362E-05 -5.2810 0.99654E+00 -0.0015 61 KCl,aq 0.30588E-09 -9.5144 0.30588E-09 -9.5144 0.10000E+01 0.0000 63 KOH,aq 0.75086E-06 -6.1244 0.75086E-06 -6.1244 0.10000E+01 0.0000 64 KSO4- 0.26492E-13 -13.5769 0.22125E-13 -13.6551 0.83517E+00 -0.0782 65 MgCO3,aq 0.21851E-12 -12.6605 0.21851E-12 -12.6605 0.10000E+01 0.0000 66 Mg(HCO3)+ 0.18476E-14 -14.7334 0.15460E-14 -14.8108 0.83677E+00 -0.0774 67 MgCl+ 0.24495E-14 -14.6109 0.20497E-14 -14.6883 0.83677E+00 -0.0774 68 MgF+ 0.12445E-15 -15.9050 0.10414E-15 -15.9824 0.83677E+00 -0.0774 69 MgOH+ 0.68613E-10 -10.1636 0.57413E-10 -10.2410 0.83677E+00 -0.0774 71 MnF+ 0.34322E-16 -16.4644 0.28720E-16 -16.5418 0.83677E+00 -0.0774 72 MnO,aq 0.17927E-08 -8.7465 0.17927E-08 -8.7465 0.10000E+01 0.0000 73 MnOH+ 0.46586E-09 -9.3317 0.38982E-09 -9.4091 0.83677E+00 -0.0774 74 MnO2-2 0.20706E-10 -10.6839 0.10728E-10 -10.9695 0.51812E+00 -0.2856 75 HMnO2- 0.20958E-09 -9.6787 0.17503E-09 -9.7569 0.83517E+00 -0.0782 78 MnCl+ 0.91065E-14 -14.0406 0.76200E-14 -14.1180 0.83677E+00 -0.0774 79 MnSO4,aq 0.30180E-19 -19.5203 0.30180E-19 -19.5203 0.10000E+01 0.0000 80 NaCl,aq 0.70842E-06 -6.1497 0.70842E-06 -6.1497 0.10000E+01 0.0000 81 NaF,aq 0.68960E-09 -9.1614 0.68960E-09 -9.1614 0.10000E+01 0.0000 82 NaOH,aq 0.95682E-04 -4.0192 0.95682E-04 -4.0192 0.10000E+01 0.0000 84 OH- 0.93067E-02 -2.0312 0.77586E-02 -2.1102 0.83366E+00 -0.0790 89 HPO3-2 0.74118E-15 -15.1301 0.38402E-15 -15.4156 0.51812E+00 -0.2856 91 H2PO3- 0.68666E-19 -19.1633 0.57347E-19 -19.2415 0.83517E+00 -0.0782 92 H3PO4,aq 0.91279E-18 -18.0396 0.91279E-18 -18.0396 0.10000E+01 0.0000 93 H2PO4- 0.38674E-10 -10.4126 0.32330E-10 -10.4904 0.83596E+00 -0.0778 94 PO4-3 0.10630E-08 -8.9735 0.25784E-09 -9.5886 0.24257E+00 -0.6152 98 HP2O7-3 0.95056E-18 -18.0220 0.21975E-18 -18.6581 0.23118E+00 -0.6360 99 P2O7-4 0.91482E-17 -17.0387 0.70496E-18 -18.1518 0.77060E-01 -1.1132 100 H2S,aq 0.66780E-08 -8.1754 0.66549E-08 -8.1769 0.99654E+00 -0.0015 101 S2-2 0.68284E-14 -14.1657 0.35379E-14 -14.4512 0.51812E+00 -0.2856 107 SO3-2 0.14097E-16 -16.8509 0.74097E-17 -17.1302 0.52562E+00 -0.2793 108 HSO3- 0.41368E-19 -19.3833 0.34549E-19 -19.4616 0.83517E+00 -0.0782 109 HSO4- 0.93306E-18 -18.0301 0.78151E-18 -18.1071 0.83758E+00 -0.0770 Charge balance for all species = -.6133E-08 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.8863039E-10 -.2227198E-01 -.2240979E+02 0.0000 2 H2O 0.1000000E+01 0.5550485E+02 0.9981981E+06 0.0000 3 Cl- 0.1543382E-03 0.1550469E-03 0.5487322E+01 6.2383 4 SO4-- 0.2097269E-10 -.1546410E-04 -.1482923E+01 9.2931 5 HCO3- 0.6536826E-05 0.3307023E-04 0.2014345E+01 4.8658 6 HS- 0.3461629E-04 0.5008709E-04 0.1653600E+01 5.5891 7 Al+++ 0.9739418E-29 0.5261634E-05 0.1417200E+00 0.7361 8 H4SiO4 0.6983892E-03 0.1353237E-01 0.1298408E+04 -3.1559 9 Ca++ 0.1242852E-06 0.2179952E-06 0.8721624E-02 13.0626 10 Mg++ 0.2113094E-10 0.9318245E-10 0.2261513E-05 9.2911 11 Fe++ 0.4631156E-13 0.2870671E-07 0.1600397E-02 6.6324 12 K+ 0.1565096E-03 0.1572608E-03 0.6138522E+01 6.2451 13 Na+ 0.1986082E-01 0.2230601E-01 0.5119192E+03 8.3477 14 Mn++ 0.1867559E-10 0.2507564E-08 0.1375211E-03 9.2383 15 F- 0.2131047E-06 0.2137946E-06 0.4054608E-02 3.3775 16 HPO4-- 0.4531872E-07 0.4642035E-07 0.4447633E-02 12.6277 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.2000177E-01 -.2000154E-01 -.2363873E-06 0.0000000E+00 2 H2O 0.4984660E+02 0.4984660E+02 -.1982126E-06 0.0000000E+00 3 Cl- 0.1392412E-03 0.1392412E-03 0.0000000E+00 0.0000000E+00 4 SO4-- -.1388681E-04 -.1388766E-04 0.8514958E-09 0.0000000E+00 5 HCO3- 0.2969900E-04 0.2969900E-04 0.0000000E+00 0.0000000E+00 6 HS- 0.4498028E-04 0.4498113E-04 -.8514958E-09 0.0000000E+00 7 Al+++ 0.4775352E-05 0.4725255E-05 0.5009705E-07 0.0000000E+00 8 H4SiO4 0.1215302E-01 0.1215286E-01 0.1584160E-06 0.0000000E+00 9 Ca++ 0.2080835E-06 0.1957725E-06 0.1231103E-07 0.0000000E+00 10 Mg++ 0.8368328E-10 0.8368328E-10 0.0000000E+00 0.0000000E+00 11 Fe++ 0.3259227E-07 0.2578030E-07 0.6811967E-08 0.0000000E+00 12 K+ 0.1412294E-03 0.1412294E-03 0.0000000E+00 0.0000000E+00 13 Na+ 0.2003215E-01 0.2003210E-01 0.4870166E-07 0.0000000E+00 14 Mn++ 0.2251939E-08 0.2251939E-08 0.0000000E+00 0.0000000E+00 15 F- 0.1920000E-06 0.1920000E-06 0.0000000E+00 0.0000000E+00 16 HPO4-- 0.4168819E-07 0.4168819E-07 0.0000000E+00 0.0000000E+00 Chg. balance for solid moles: -.1323E-22 Mass of aqueous solution: 0.899622E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 0.0002300 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 0.4870E-07 -7.312 0.1277E-04 -4.894 86.20 0.4902E-05 andradite 0.3406E-08 -8.468 0.1731E-05 -5.762 11.68 0.4497E-06 grossular 0.6977E-09 -9.156 0.3143E-06 -6.503 2.121 0.8744E-07 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8300E+00 0.8300E+00 1.0000 -0.081 grossular 0.1700E+00 0.1700E+00 1.0000 -0.770 Solid products produced: Mass = 0.000015 g Volume = 0.000005 cm3 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.0002300 moles log = -3.6383 Original solution: 1000.0103000 g Original solution / Rock added: 4347870.87 (Water/Rock Ratio), log = 6.6383 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0481 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9739E+00 0.9856 0.1006E+01 0.1021E+01 CO2,gas 0.8821E-07 1.0069 0.9308E-07 0.9244E-07 CH4,gas 0.1956E-01 1.0123 0.2076E-01 0.2050E-01 H2,gas 0.6556E-02 1.0006 0.6875E-02 0.6871E-02 H2S,gas 0.1753E-06 0.9959 0.1829E-06 0.1837E-06 S2,gas 0.2536E-28 1.0000 0.2658E-28 0.2658E-28 CO,gas 0.1627E-12 1.0000 0.1705E-12 0.1705E-12 SO3,gas 0.2179E-46 1.0000 0.2283E-46 0.2283E-46 SO2,gas 0.5827E-26 1.0000 0.6107E-26 0.6107E-26 HF,gas 0.2121E-15 1.0000 0.2223E-15 0.2223E-15 HCl,gas 0.2961E-17 1.0000 0.3104E-17 0.3104E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 17 albite -0.38 -0.38 0.00 0.000 -0.94784E-12 23 andradite 39.01 39.01 0.00 0.000 0.12132E-10 24 grossular 32.73 32.73 0.00 0.000 0.00000E+00 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -15.39 -8.73 -2.910 0.14906E+05 -7.031 3 CH4,gas 4.54 1.16 -3.38 -0.845 0.57744E+04 -1.683 4 H2,gas 8.00 4.14 -3.86 -2.207 0.65938E+04 -2.163 5 H2S,gas -6.23 -14.67 -8.44 -4.218 0.14405E+05 -6.738 6 S2,gas -7.34 -37.61 -30.27 -4.658 0.51693E+05 -28.575 7 CO,gas 3.21 -11.25 -14.47 -4.451 0.24702E+05 -12.768 8 SO3,gas 17.12 -31.22 -48.34 -12.085 0.82540E+05 -46.641 9 SO2,gas 0.83 -27.08 -27.91 -7.444 0.47661E+05 -26.214 10 HF,gas 0.47 -16.88 -17.35 -8.676 0.29628E+05 -15.653 11 HCl,gas 5.19 -14.02 -19.21 -9.604 0.32796E+05 -17.508 12 acmite 7.71 6.60 -1.11 -0.115 0.18960E+04 16 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 20 spessartine 24.46 19.72 -4.74 -0.237 0.80897E+04 21 analcite 3.32 2.77 -0.55 -0.061 0.93881E+03 27 annite 20.12 17.41 -2.71 -0.151 0.46320E+04 28 phlogopite 27.06 25.39 -1.68 -0.093 0.28646E+04 30 anorthite 12.71 8.22 -4.49 -0.345 0.76619E+04 33 apatite-OH -18.15 -18.34 -0.19 -0.014 0.31835E+03 34 apatite-F -34.30 -35.22 -0.92 -0.076 0.15666E+04 38 aragonite 0.97 -2.33 -3.29 -1.098 0.56247E+04 39 brucite 12.57 9.29 -3.28 -0.655 0.55961E+04 40 calcite 0.81 -2.33 -3.14 -1.046 0.53604E+04 41 carnegieite-low 9.02 5.93 -3.10 -0.442 0.52852E+04 42 carnegieite-high 10.09 5.93 -4.17 -0.595 0.71122E+04 43 carpholite-Mg 8.58 4.45 -4.13 -0.275 0.70527E+04 44 carpholite-Fe 6.71 1.79 -4.92 -0.328 0.84005E+04 45 celadonite 5.34 3.65 -1.69 -0.100 0.28905E+04 46 celadonite-Fe 3.88 0.99 -2.89 -0.170 0.49287E+04 47 chrysotile 23.89 21.56 -2.33 -0.194 0.39798E+04 49 clinochlore 39.07 38.46 -0.61 -0.019 0.10404E+04 50 daphnite 28.97 25.17 -3.80 -0.119 0.64864E+04 52 chlorite-Al-free 47.17 43.12 -4.05 -0.169 0.69147E+04 54 chloritoid-Fe 9.17 4.95 -4.22 -0.282 0.72139E+04 55 chloritoid-Mn 11.40 7.55 -3.85 -0.256 0.65676E+04 57 coesite -2.38 -3.16 -0.78 -0.260 0.13316E+04 64 cristobalite -2.56 -3.16 -0.60 -0.199 0.10169E+04 66 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71234E+04 68 diaspore 2.87 0.74 -2.14 -0.356 0.36498E+04 69 diamond -3.10 -7.11 -4.01 -1.146 0.68500E+04 70 diopside 16.18 16.04 -0.14 -0.014 0.23803E+03 71 hedenbergite 14.21 13.38 -0.83 -0.083 0.14088E+04 74 enstatite 17.26 12.27 -4.99 -0.499 0.85279E+04 76 clinoenstatite 17.17 12.27 -4.90 -0.490 0.83595E+04 78 epidote 24.67 22.69 -1.98 -0.096 0.33753E+04 79 clinozoisite 22.81 18.87 -3.94 -0.179 0.67276E+04 80 epidote-Fe 29.84 26.52 -3.32 -0.172 0.56695E+04 81 fayalite 14.05 10.11 -3.94 -0.562 0.67221E+04 82 ferrosilite 11.15 6.95 -4.20 -0.420 0.71654E+04 86 gibbsite 4.08 0.74 -3.34 -0.478 0.57084E+04 87 glaucophane 22.97 20.79 -2.18 -0.059 0.37239E+04 88 glaucophane-Fe 17.28 12.82 -4.46 -0.120 0.76123E+04 89 graphite -3.55 -7.11 -3.57 -1.019 0.60923E+04 90 greenalite 16.14 13.59 -2.55 -0.213 0.43612E+04 93 hematite 12.57 9.13 -3.44 -0.417 0.58728E+04 94 heulandite -5.83 -7.56 -1.73 -0.079 0.29526E+04 98 jadeite 4.22 2.77 -1.44 -0.144 0.24643E+04 100 kalsilite 7.58 3.83 -3.76 -0.537 0.64177E+04 101 kaolinite -1.33 -4.84 -3.51 -0.319 0.59877E+04 104 laumontite 2.88 1.91 -0.97 -0.065 0.16599E+04 105 lawsonite 9.62 8.22 -1.39 -0.093 0.23785E+04 106 leucite 4.12 0.67 -3.45 -0.345 0.58899E+04 108 lizardite 23.24 21.56 -1.68 -0.140 0.28724E+04 110 magnetite 20.09 15.76 -4.33 -0.353 0.73904E+04 111 minnesotaite 10.39 7.27 -3.11 -0.183 0.53181E+04 115 manganosite 14.06 9.24 -4.82 -1.205 0.82297E+04 119 microcline -2.49 -2.49 0.00 0.000 0.19371E-01 123 muscovite 2.58 -1.01 -3.60 -0.212 0.61412E+04 124 paragonite 4.24 1.09 -3.15 -0.185 0.53803E+04 125 nepheline 8.34 5.93 -2.41 -0.345 0.41176E+04 131 periclase-Fe 11.63 6.63 -4.99 -1.249 0.85275E+04 137 phlogopite-Na 29.65 27.49 -2.16 -0.120 0.36834E+04 139 prehnite 19.37 18.13 -1.24 -0.073 0.21208E+04 140 prehnite-Fe 22.50 21.96 -0.54 -0.033 0.92346E+03 141 pumpellyite-Fe 46.27 43.63 -2.64 -0.059 0.45100E+04 142 pumpellyite-Mg 48.99 46.29 -2.71 -0.060 0.46239E+04 146 pyrrhotite -4.26 -8.03 -3.77 -1.258 0.64444E+04 147 pyrrhotiteFe0.875 -6.02 -9.38 -3.36 -1.236 0.57367E+04 148 pyroxmangite 7.40 6.08 -1.32 -0.263 0.22475E+04 149 pyrophyllite -6.18 -11.15 -4.98 -0.311 0.84956E+04 150 quartz -2.99 -3.16 -0.17 -0.055 0.28424E+03 155 rhodonite 7.45 6.08 -1.36 -0.273 0.23277E+04 156 sanidine -1.28 -2.49 -1.21 -0.093 0.20678E+04 166 stilbite -7.52 -7.56 -0.03 -0.002 0.58723E+02 167 stilpnomelane-Fe 13.02 12.51 -0.51 -0.015 0.86656E+03 168 stilpnomelane-Mg 27.44 25.80 -1.64 -0.049 0.27971E+04 174 talc 16.49 15.25 -1.24 -0.073 0.21195E+04 177 tephroite 18.09 15.32 -2.77 -0.395 0.47212E+04 181 tridymite -2.63 -3.16 -0.53 -0.177 0.90422E+03 182 tremolite 47.87 47.33 -0.54 -0.014 0.91447E+03 183 ferroactinolite 38.45 34.04 -4.41 -0.119 0.75341E+04 184 troilite-low -4.41 -8.03 -3.62 -1.208 0.61872E+04 190 wairakite 3.95 1.91 -2.04 -0.120 0.34819E+04 191 walstromite 11.51 9.91 -1.60 -0.321 0.27362E+04 192 wollastonite 10.46 9.91 -0.55 -0.111 0.94667E+03 193 pseudo-wollastonite 11.00 9.91 -1.09 -0.219 0.18665E+04 194 zoisite 22.85 18.87 -3.98 -0.181 0.68017E+04 195 akaganeite 7.75 4.56 -3.19 -0.690 0.54489E+04 202 chalcedony -2.80 -3.16 -0.35 -0.118 0.60354E+03 204 montmorillonite-Ca -2.29 -6.17 -3.88 -0.240 0.66287E+04 205 montmorillonite-K -2.24 -6.27 -4.03 -0.247 0.68822E+04 206 montmorillonite-Mg -2.48 -6.80 -4.32 -0.267 0.73682E+04 207 montmorillonite-Na -2.04 -5.57 -3.54 -0.217 0.60370E+04 208 nontronite-Ca 3.21 -0.06 -3.27 -0.212 0.55864E+04 209 nontronite-H 2.53 -2.21 -4.75 -0.318 0.81023E+04 210 nontronite-K 3.34 -0.15 -3.49 -0.224 0.59631E+04 211 nontronite-Mg 3.07 -0.68 -3.75 -0.244 0.64100E+04 212 nontronite-Na 3.52 0.54 -2.98 -0.191 0.50839E+04 228 tobermorite 9.82 7.73 -2.10 -0.572 0.35819E+04 234 alabandite -0.98 -5.43 -4.45 -1.484 0.75995E+04 237 boehmite 4.41 0.74 -3.67 -0.612 0.62668E+04 239 ferrous-oxide 9.81 6.63 -3.18 -0.795 0.54284E+04 245 silica-amorphous -2.09 -3.16 -1.06 -0.355 0.18177E+04 247 an20ab80 2.02 1.34 -0.68 -0.052 0.11615E+04 248 an25ab75 2.65 1.77 -0.88 -0.068 0.14989E+04 249 an30ab70 3.28 2.20 -1.08 -0.083 0.18458E+04 250 tr.625ac.25prg.125 45.16 44.96 -0.21 -0.006 0.35413E+03 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 0.0000100 MOLES Current total amount of reactant added: 0.0002300 MOLES New total amount of reactant added: 0.0002400 MOLES Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.5508E-08 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 6 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 0.0002400 Water: Moles liquid = 0.4985E+02 kg liquid = 0.8981E+00 Moles total = 0.4985E+02 kg total = 0.8980E+00 Activity = 1.0000 Stoichiometric ionic strength = .1134552E-01 Osmotic coef. = 0.9685 True ionic strength = .2003080E-01 Chg. balance for total moles = -.5508E-08 Max. difference allowed = 0.1393E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.88646E-10 -10.0523 0.74482E-10 -10.1279 0.84022E+00 -0.0756 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.15440E-03 -3.8113 0.12895E-03 -3.8896 0.83516E+00 -0.0782 4 SO4-- 0.22140E-10 -10.6548 0.11496E-10 -10.9395 0.51922E+00 -0.2846 5 HCO3- 0.68288E-05 -5.1657 0.57116E-05 -5.2432 0.83639E+00 -0.0776 6 HS- 0.34887E-04 -4.4573 0.29140E-04 -4.5355 0.83529E+00 -0.0782 7 Al+++ 0.97416E-29 -29.0114 0.22498E-29 -29.6479 0.23095E+00 -0.6365 8 H4SiO4 0.69850E-03 -3.1558 0.69850E-03 -3.1558 0.10000E+01 0.0000 9 Ca++ 0.12409E-06 -6.9063 0.63957E-07 -7.1941 0.51541E+00 -0.2878 10 Mg++ 0.21132E-10 -10.6751 0.10842E-10 -10.9649 0.51305E+00 -0.2898 11 Fe++ 0.46210E-13 -13.3353 0.23734E-13 -13.6246 0.51361E+00 -0.2894 12 K+ 0.15651E-03 -3.8055 0.13093E-03 -3.8829 0.83659E+00 -0.0775 13 Na+ 0.19861E-01 -1.7020 0.16584E-01 -1.7803 0.83501E+00 -0.0783 14 Mn++ 0.18682E-10 -10.7286 0.96032E-11 -11.0176 0.51404E+00 -0.2890 15 F- 0.21754E-06 -6.6625 0.18131E-06 -6.7416 0.83344E+00 -0.0791 16 HPO4-- 0.45319E-07 -7.3437 0.23534E-07 -7.6283 0.51930E+00 -0.2846 18 HSiO3- 0.10485E-01 -1.9794 0.87568E-02 -2.0577 0.83516E+00 -0.0782 19 Ca(HSiO3)+ 0.15243E-07 -7.8169 0.12755E-07 -7.8943 0.83676E+00 -0.0774 20 Mg(HSiO3)+ 0.32156E-11 -11.4927 0.26907E-11 -11.5701 0.83676E+00 -0.0774 21 NaHSiO3,aq 0.23488E-02 -2.6292 0.23488E-02 -2.6292 0.10000E+01 0.0000 22 AlO+ 0.65934E-16 -16.1809 0.55172E-16 -16.2583 0.83676E+00 -0.0774 24 HAlO2,aq 0.14752E-09 -9.8312 0.14752E-09 -9.8312 0.10000E+01 0.0000 25 AlO2- 0.52589E-05 -5.2791 0.43841E-05 -5.3581 0.83366E+00 -0.0790 26 CH4,aq 0.14113E-04 -4.8504 0.14064E-04 -4.8519 0.99654E+00 -0.0015 27 C2H6,aq 0.65559E-14 -14.1834 0.65332E-14 -14.1849 0.99654E+00 -0.0015 31 CO,aq 0.11818E-15 -15.9274 0.11818E-15 -15.9274 0.10000E+01 0.0000 32 CO2,aq 0.91215E-09 -9.0399 0.90900E-09 -9.0414 0.99654E+00 -0.0015 33 CO3-2 0.12928E-04 -4.8885 0.66980E-05 -5.1741 0.51812E+00 -0.2856 34 CaCO3,aq 0.53715E-08 -8.2699 0.53715E-08 -8.2699 0.10000E+01 0.0000 35 Ca(HCO3)+ 0.11143E-10 -10.9530 0.93245E-11 -11.0304 0.83676E+00 -0.0774 36 CaCl+ 0.15951E-10 -10.7972 0.13347E-10 -10.8746 0.83676E+00 -0.0774 37 CaCl2,aq 0.40890E-15 -15.3884 0.40890E-15 -15.3884 0.10000E+01 0.0000 38 CaF+ 0.20233E-12 -12.6939 0.16930E-12 -12.7713 0.83676E+00 -0.0774 39 CaOH+ 0.73137E-07 -7.1359 0.61198E-07 -7.2133 0.83676E+00 -0.0774 40 CaSO4,aq 0.23347E-15 -15.6318 0.23347E-15 -15.6318 0.10000E+01 0.0000 41 HCl,aq 0.17600E-14 -14.7545 0.17600E-14 -14.7545 0.10000E+01 0.0000 45 HF,aq 0.92447E-13 -13.0341 0.92447E-13 -13.0341 0.10000E+01 0.0000 48 FeCl+ 0.57894E-17 -17.2374 0.48443E-17 -17.3148 0.83676E+00 -0.0774 51 FeF+ 0.26280E-18 -18.5804 0.21990E-18 -18.6578 0.83676E+00 -0.0774 53 FeO,aq 0.16628E-09 -9.7792 0.16628E-09 -9.7792 0.10000E+01 0.0000 54 FeOH+ 0.12396E-10 -10.9067 0.10372E-10 -10.9841 0.83676E+00 -0.0774 55 HFeO2- 0.27969E-07 -7.5533 0.23358E-07 -7.6316 0.83516E+00 -0.0782 56 FeO+ 0.12996E-16 -16.8862 0.10875E-16 -16.9636 0.83676E+00 -0.0774 58 FeO2- 0.48029E-09 -9.3185 0.40112E-09 -9.3967 0.83516E+00 -0.0782 59 HFeO2,aq 0.37998E-11 -11.4202 0.37998E-11 -11.4202 0.10000E+01 0.0000 60 H2,aq 0.51936E-05 -5.2845 0.51756E-05 -5.2860 0.99654E+00 -0.0015 61 KCl,aq 0.30601E-09 -9.5143 0.30601E-09 -9.5143 0.10000E+01 0.0000 63 KOH,aq 0.75073E-06 -6.1245 0.75073E-06 -6.1245 0.10000E+01 0.0000 64 KSO4- 0.27967E-13 -13.5534 0.23357E-13 -13.6316 0.83516E+00 -0.0782 65 MgCO3,aq 0.22823E-12 -12.6416 0.22823E-12 -12.6416 0.10000E+01 0.0000 66 Mg(HCO3)+ 0.19302E-14 -14.7144 0.16151E-14 -14.7918 0.83676E+00 -0.0774 67 MgCl+ 0.24506E-14 -14.6107 0.20506E-14 -14.6881 0.83676E+00 -0.0774 68 MgF+ 0.12705E-15 -15.8960 0.10631E-15 -15.9734 0.83676E+00 -0.0774 69 MgOH+ 0.68603E-10 -10.1637 0.57404E-10 -10.2411 0.83676E+00 -0.0774 71 MnF+ 0.35049E-16 -16.4553 0.29328E-16 -16.5327 0.83676E+00 -0.0774 72 MnO,aq 0.17927E-08 -8.7465 0.17927E-08 -8.7465 0.10000E+01 0.0000 73 MnOH+ 0.46594E-09 -9.3317 0.38988E-09 -9.4091 0.83676E+00 -0.0774 74 MnO2-2 0.20699E-10 -10.6841 0.10724E-10 -10.9696 0.51812E+00 -0.2856 75 HMnO2- 0.20954E-09 -9.6787 0.17500E-09 -9.7570 0.83516E+00 -0.0782 78 MnCl+ 0.91134E-14 -14.0403 0.76257E-14 -14.1177 0.83676E+00 -0.0774 79 MnSO4,aq 0.31871E-19 -19.4966 0.31871E-19 -19.4966 0.10000E+01 0.0000 80 NaCl,aq 0.70872E-06 -6.1495 0.70872E-06 -6.1495 0.10000E+01 0.0000 81 NaF,aq 0.70396E-09 -9.1525 0.70396E-09 -9.1525 0.10000E+01 0.0000 82 NaOH,aq 0.95665E-04 -4.0192 0.95665E-04 -4.0192 0.10000E+01 0.0000 84 OH- 0.93051E-02 -2.0313 0.77572E-02 -2.1103 0.83366E+00 -0.0790 89 HPO3-2 0.73260E-15 -15.1351 0.37958E-15 -15.4207 0.51812E+00 -0.2856 91 H2PO3- 0.67883E-19 -19.1682 0.56693E-19 -19.2465 0.83516E+00 -0.0782 92 H3PO4,aq 0.91310E-18 -18.0395 0.91310E-18 -18.0395 0.10000E+01 0.0000 93 H2PO4- 0.38681E-10 -10.4125 0.32335E-10 -10.4903 0.83596E+00 -0.0778 94 PO4-3 0.10628E-08 -8.9736 0.25780E-09 -9.5887 0.24257E+00 -0.6152 98 HP2O7-3 0.95074E-18 -18.0219 0.21979E-18 -18.6580 0.23118E+00 -0.6361 99 P2O7-4 0.91484E-17 -17.0387 0.70496E-18 -18.1518 0.77058E-01 -1.1132 100 H2S,aq 0.67313E-08 -8.1719 0.67080E-08 -8.1734 0.99654E+00 -0.0015 101 S2-2 0.70167E-14 -14.1539 0.36355E-14 -14.4394 0.51812E+00 -0.2856 107 SO3-2 0.14710E-16 -16.8324 0.77317E-17 -17.1117 0.52562E+00 -0.2793 108 HSO3- 0.43173E-19 -19.3648 0.36057E-19 -19.4430 0.83516E+00 -0.0782 109 HSO4- 0.98517E-18 -18.0065 0.82516E-18 -18.0835 0.83758E+00 -0.0770 Charge balance for all species = -.6133E-08 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.8864595E-10 -.2227077E-01 -.2240857E+02 0.0000 2 H2O 0.1000000E+01 0.5550485E+02 0.9981980E+06 0.0000 3 Cl- 0.1544036E-03 0.1551126E-03 0.5489646E+01 6.2384 4 SO4-- 0.2214032E-10 -.1541093E-04 -.1477825E+01 9.3164 5 HCO3- 0.6828849E-05 0.3387530E-04 0.2063382E+01 4.8847 6 HS- 0.3488682E-04 0.5030450E-04 0.1660778E+01 5.5924 7 Al+++ 0.9741610E-29 0.5259081E-05 0.1416512E+00 0.7360 8 H4SiO4 0.6985027E-03 0.1353236E-01 0.1298407E+04 -3.1558 9 Ca++ 0.1240892E-06 0.2178674E-06 0.8716508E-02 13.0618 10 Mg++ 0.2113152E-10 0.9318243E-10 0.2261513E-05 9.2910 11 Fe++ 0.4620971E-13 0.2863132E-07 0.1596194E-02 6.6313 12 K+ 0.1565097E-03 0.1572608E-03 0.6138521E+01 6.2450 13 Na+ 0.1986085E-01 0.2230600E-01 0.5119190E+03 8.3476 14 Mn++ 0.1868189E-10 0.2507564E-08 0.1375210E-03 9.2383 15 F- 0.2175443E-06 0.2182486E-06 0.4139078E-02 3.3864 16 HPO4-- 0.4531888E-07 0.4642035E-07 0.4447632E-02 12.6276 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.2000070E-01 -.2000045E-01 -.2459048E-06 0.0000000E+00 2 H2O 0.4984661E+02 0.4984661E+02 -.2073810E-06 0.0000000E+00 3 Cl- 0.1393002E-03 0.1393002E-03 0.0000000E+00 0.0000000E+00 4 SO4-- -.1383906E-04 -.1383992E-04 0.8599579E-09 0.0000000E+00 5 HCO3- 0.3042200E-04 0.3042200E-04 0.0000000E+00 0.0000000E+00 6 HS- 0.4517553E-04 0.4517639E-04 -.8599579E-09 0.0000000E+00 7 Al+++ 0.4775352E-05 0.4722962E-05 0.5238951E-07 0.0000000E+00 8 H4SiO4 0.1215302E-01 0.1215285E-01 0.1653817E-06 0.0000000E+00 9 Ca++ 0.2080835E-06 0.1956577E-06 0.1242583E-07 0.0000000E+00 10 Mg++ 0.8368328E-10 0.8368328E-10 0.0000000E+00 0.0000000E+00 11 Fe++ 0.3259227E-07 0.2571261E-07 0.6879663E-08 0.0000000E+00 12 K+ 0.1412294E-03 0.1412294E-03 0.0000000E+00 0.0000000E+00 13 Na+ 0.2003215E-01 0.2003210E-01 0.5098528E-07 0.0000000E+00 14 Mn++ 0.2251939E-08 0.2251939E-08 0.0000000E+00 0.0000000E+00 15 F- 0.1960000E-06 0.1960000E-06 0.0000000E+00 0.0000000E+00 16 HPO4-- 0.4168819E-07 0.4168819E-07 0.0000000E+00 0.0000000E+00 Chg. balance for solid moles: 0.6617E-23 Mass of aqueous solution: 0.899623E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 0.0002400 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 0.5099E-07 -7.293 0.1337E-04 -4.874 86.62 0.5132E-05 andradite 0.3440E-08 -8.463 0.1748E-05 -5.757 11.33 0.4542E-06 grossular 0.7021E-09 -9.154 0.3163E-06 -6.500 2.049 0.8800E-07 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8305E+00 0.8305E+00 1.0000 -0.081 grossular 0.1695E+00 0.1695E+00 1.0000 -0.771 Solid products produced: Mass = 0.000015 g Volume = 0.000006 cm3 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.0002400 moles log = -3.6198 Original solution: 1000.0103000 g Original solution / Rock added: 4166709.58 (Water/Rock Ratio), log = 6.6198 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0479 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9740E+00 0.9856 0.1006E+01 0.1021E+01 CO2,gas 0.9217E-07 1.0069 0.9725E-07 0.9659E-07 CH4,gas 0.1951E-01 1.0123 0.2070E-01 0.2045E-01 H2,gas 0.6481E-02 1.0006 0.6795E-02 0.6791E-02 H2S,gas 0.1767E-06 0.9959 0.1844E-06 0.1852E-06 S2,gas 0.2638E-28 1.0000 0.2764E-28 0.2764E-28 CO,gas 0.1681E-12 1.0000 0.1761E-12 0.1761E-12 SO3,gas 0.2301E-46 1.0000 0.2411E-46 0.2411E-46 SO2,gas 0.6083E-26 1.0000 0.6374E-26 0.6374E-26 HF,gas 0.2166E-15 1.0000 0.2270E-15 0.2270E-15 HCl,gas 0.2964E-17 1.0000 0.3106E-17 0.3106E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 17 albite -0.38 -0.38 0.00 0.000 0.11184E-10 23 andradite 39.01 39.01 0.00 0.000 0.24265E-10 24 grossular 32.73 32.73 0.00 0.000 0.00000E+00 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -15.37 -8.71 -2.904 0.14874E+05 -7.012 3 CH4,gas 4.54 1.16 -3.38 -0.846 0.57763E+04 -1.684 4 H2,gas 8.00 4.13 -3.87 -2.210 0.66024E+04 -2.168 5 H2S,gas -6.23 -14.66 -8.43 -4.217 0.14399E+05 -6.734 6 S2,gas -7.34 -37.59 -30.26 -4.655 0.51664E+05 -28.558 7 CO,gas 3.21 -11.24 -14.45 -4.447 0.24678E+05 -12.754 8 SO3,gas 17.12 -31.20 -48.32 -12.079 0.82499E+05 -46.618 9 SO2,gas 0.83 -27.06 -27.89 -7.439 0.47629E+05 -26.196 10 HF,gas 0.47 -16.87 -17.34 -8.671 0.29613E+05 -15.644 11 HCl,gas 5.19 -14.02 -19.21 -9.603 0.32795E+05 -17.508 12 acmite 7.71 6.60 -1.11 -0.115 0.18935E+04 16 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 20 spessartine 24.46 19.72 -4.74 -0.237 0.80898E+04 21 analcite 3.32 2.77 -0.55 -0.061 0.93893E+03 27 annite 20.12 17.41 -2.72 -0.151 0.46377E+04 28 phlogopite 27.06 25.39 -1.68 -0.093 0.28654E+04 30 anorthite 12.71 8.22 -4.49 -0.345 0.76635E+04 33 apatite-OH -18.15 -18.34 -0.19 -0.015 0.32476E+03 34 apatite-F -34.30 -35.21 -0.91 -0.076 0.15576E+04 38 aragonite 0.97 -2.31 -3.28 -1.092 0.55936E+04 39 brucite 12.57 9.29 -3.28 -0.656 0.55964E+04 40 calcite 0.81 -2.31 -3.12 -1.040 0.53293E+04 41 carnegieite-low 9.02 5.93 -3.10 -0.442 0.52855E+04 42 carnegieite-high 10.09 5.93 -4.17 -0.595 0.71125E+04 43 carpholite-Mg 8.58 4.45 -4.13 -0.275 0.70532E+04 44 carpholite-Fe 6.71 1.79 -4.92 -0.328 0.84026E+04 45 celadonite 5.34 3.65 -1.69 -0.100 0.28907E+04 46 celadonite-Fe 3.88 0.99 -2.89 -0.170 0.49305E+04 47 chrysotile 23.89 21.56 -2.33 -0.194 0.39803E+04 49 clinochlore 39.07 38.46 -0.61 -0.019 0.10417E+04 50 daphnite 28.97 25.16 -3.80 -0.119 0.64959E+04 52 chlorite-Al-free 47.17 43.12 -4.05 -0.169 0.69157E+04 54 chloritoid-Fe 9.17 4.95 -4.23 -0.282 0.72161E+04 55 chloritoid-Mn 11.40 7.55 -3.85 -0.256 0.65680E+04 57 coesite -2.38 -3.16 -0.78 -0.260 0.13314E+04 64 cristobalite -2.56 -3.16 -0.60 -0.198 0.10168E+04 66 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71234E+04 68 diaspore 2.87 0.74 -2.14 -0.356 0.36501E+04 69 diamond -3.10 -7.11 -4.00 -1.144 0.68348E+04 70 diopside 16.18 16.04 -0.14 -0.014 0.23947E+03 71 hedenbergite 14.21 13.38 -0.83 -0.083 0.14119E+04 74 enstatite 17.26 12.27 -4.99 -0.499 0.85281E+04 76 clinoenstatite 17.17 12.27 -4.90 -0.490 0.83597E+04 78 epidote 24.67 22.69 -1.98 -0.096 0.33758E+04 79 clinozoisite 22.81 18.86 -3.94 -0.179 0.67308E+04 80 epidote-Fe 29.84 26.52 -3.32 -0.172 0.56674E+04 81 fayalite 14.05 10.11 -3.94 -0.563 0.67258E+04 82 ferrosilite 11.15 6.95 -4.20 -0.420 0.71690E+04 86 gibbsite 4.08 0.74 -3.34 -0.478 0.57086E+04 87 glaucophane 22.97 20.79 -2.18 -0.059 0.37244E+04 88 glaucophane-Fe 17.28 12.81 -4.46 -0.121 0.76177E+04 89 graphite -3.55 -7.11 -3.56 -1.017 0.60770E+04 90 greenalite 16.14 13.58 -2.56 -0.213 0.43666E+04 93 hematite 12.57 9.13 -3.44 -0.417 0.58679E+04 94 heulandite -5.83 -7.56 -1.73 -0.079 0.29536E+04 98 jadeite 4.22 2.77 -1.44 -0.144 0.24644E+04 100 kalsilite 7.58 3.83 -3.76 -0.537 0.64180E+04 101 kaolinite -1.33 -4.84 -3.51 -0.319 0.59880E+04 104 laumontite 2.88 1.91 -0.97 -0.065 0.16613E+04 105 lawsonite 9.62 8.22 -1.39 -0.093 0.23802E+04 106 leucite 4.12 0.67 -3.45 -0.345 0.58900E+04 108 lizardite 23.24 21.56 -1.68 -0.140 0.28729E+04 110 magnetite 20.09 15.76 -4.33 -0.353 0.73875E+04 111 minnesotaite 10.39 7.27 -3.12 -0.183 0.53233E+04 115 manganosite 14.06 9.24 -4.82 -1.205 0.82297E+04 119 microcline -2.49 -2.49 0.00 0.000 0.20207E-01 123 muscovite 2.58 -1.01 -3.60 -0.212 0.61417E+04 124 paragonite 4.24 1.09 -3.15 -0.185 0.53808E+04 125 nepheline 8.34 5.93 -2.41 -0.345 0.41178E+04 131 periclase-Fe 11.63 6.63 -5.00 -1.249 0.85294E+04 137 phlogopite-Na 29.65 27.49 -2.16 -0.120 0.36842E+04 139 prehnite 19.37 18.13 -1.24 -0.073 0.21238E+04 140 prehnite-Fe 22.50 21.96 -0.54 -0.033 0.92378E+03 141 pumpellyite-Fe 46.27 43.62 -2.65 -0.059 0.45181E+04 142 pumpellyite-Mg 48.99 46.28 -2.71 -0.060 0.46303E+04 146 pyrrhotite -4.26 -8.03 -3.77 -1.257 0.64404E+04 147 pyrrhotiteFe0.875 -6.02 -9.37 -3.36 -1.235 0.57314E+04 148 pyroxmangite 7.40 6.08 -1.32 -0.263 0.22474E+04 149 pyrophyllite -6.18 -11.15 -4.98 -0.311 0.84956E+04 150 quartz -2.99 -3.16 -0.17 -0.055 0.28412E+03 155 rhodonite 7.45 6.08 -1.36 -0.273 0.23276E+04 156 sanidine -1.28 -2.49 -1.21 -0.093 0.20678E+04 166 stilbite -7.52 -7.56 -0.04 -0.002 0.59778E+02 167 stilpnomelane-Fe 13.02 12.50 -0.51 -0.015 0.87561E+03 168 stilpnomelane-Mg 27.44 25.80 -1.64 -0.049 0.27979E+04 174 talc 16.49 15.25 -1.24 -0.073 0.21197E+04 177 tephroite 18.09 15.32 -2.76 -0.395 0.47212E+04 181 tridymite -2.63 -3.16 -0.53 -0.176 0.90410E+03 182 tremolite 47.87 47.33 -0.54 -0.015 0.91758E+03 183 ferroactinolite 38.45 34.03 -4.42 -0.119 0.75455E+04 184 troilite-low -4.41 -8.03 -3.62 -1.207 0.61832E+04 190 wairakite 3.95 1.91 -2.04 -0.120 0.34833E+04 191 walstromite 11.51 9.91 -1.60 -0.321 0.27375E+04 192 wollastonite 10.46 9.91 -0.56 -0.111 0.94798E+03 193 pseudo-wollastonite 11.00 9.91 -1.09 -0.219 0.18678E+04 194 zoisite 22.85 18.86 -3.99 -0.181 0.68049E+04 195 akaganeite 7.75 4.56 -3.19 -0.690 0.54465E+04 202 chalcedony -2.80 -3.16 -0.35 -0.118 0.60342E+03 204 montmorillonite-Ca -2.29 -6.17 -3.88 -0.240 0.66289E+04 205 montmorillonite-K -2.24 -6.27 -4.03 -0.247 0.68822E+04 206 montmorillonite-Mg -2.48 -6.80 -4.32 -0.267 0.73683E+04 207 montmorillonite-Na -2.04 -5.57 -3.54 -0.217 0.60371E+04 208 nontronite-Ca 3.21 -0.05 -3.27 -0.212 0.55814E+04 209 nontronite-H 2.53 -2.21 -4.74 -0.318 0.80971E+04 210 nontronite-K 3.34 -0.15 -3.49 -0.224 0.59579E+04 211 nontronite-Mg 3.07 -0.68 -3.75 -0.243 0.64049E+04 212 nontronite-Na 3.52 0.55 -2.97 -0.191 0.50788E+04 228 tobermorite 9.82 7.72 -2.10 -0.573 0.35830E+04 234 alabandite -0.98 -5.43 -4.45 -1.482 0.75936E+04 237 boehmite 4.41 0.74 -3.67 -0.612 0.62670E+04 239 ferrous-oxide 9.81 6.63 -3.18 -0.795 0.54303E+04 245 silica-amorphous -2.09 -3.16 -1.06 -0.355 0.18176E+04 247 an20ab80 2.02 1.34 -0.68 -0.052 0.11619E+04 248 an25ab75 2.65 1.77 -0.88 -0.068 0.14993E+04 249 an30ab70 3.28 2.20 -1.08 -0.083 0.18463E+04 250 tr.625ac.25prg.125 45.16 44.95 -0.21 -0.006 0.35942E+03 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 0.0000100 MOLES Current total amount of reactant added: 0.0002400 MOLES New total amount of reactant added: 0.0002500 MOLES Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.5508E-08 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 6 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 0.0002500 Water: Moles liquid = 0.4985E+02 kg liquid = 0.8981E+00 Moles total = 0.4985E+02 kg total = 0.8980E+00 Activity = 1.0000 Stoichiometric ionic strength = .1134616E-01 Osmotic coef. = 0.9685 True ionic strength = .2003139E-01 Chg. balance for total moles = -.5508E-08 Max. difference allowed = 0.1394E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.88662E-10 -10.0523 0.74495E-10 -10.1279 0.84022E+00 -0.0756 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.15447E-03 -3.8112 0.12901E-03 -3.8894 0.83516E+00 -0.0782 4 SO4-- 0.23331E-10 -10.6321 0.12114E-10 -10.9167 0.51922E+00 -0.2846 5 HCO3- 0.71212E-05 -5.1474 0.59561E-05 -5.2250 0.83638E+00 -0.0776 6 HS- 0.35157E-04 -4.4540 0.29366E-04 -4.5321 0.83529E+00 -0.0782 7 Al+++ 0.97438E-29 -29.0113 0.22503E-29 -29.6478 0.23094E+00 -0.6365 8 H4SiO4 0.69862E-03 -3.1558 0.69862E-03 -3.1558 0.10000E+01 0.0000 9 Ca++ 0.12390E-06 -6.9069 0.63858E-07 -7.1948 0.51541E+00 -0.2879 10 Mg++ 0.21132E-10 -10.6751 0.10842E-10 -10.9649 0.51305E+00 -0.2898 11 Fe++ 0.46115E-13 -13.3362 0.23685E-13 -13.6255 0.51361E+00 -0.2894 12 K+ 0.15651E-03 -3.8055 0.13093E-03 -3.8829 0.83658E+00 -0.0775 13 Na+ 0.19861E-01 -1.7020 0.16584E-01 -1.7803 0.83501E+00 -0.0783 14 Mn++ 0.18688E-10 -10.7284 0.96064E-11 -11.0174 0.51404E+00 -0.2890 15 F- 0.22198E-06 -6.6537 0.18501E-06 -6.7328 0.83344E+00 -0.0791 16 HPO4-- 0.45319E-07 -7.3437 0.23534E-07 -7.6283 0.51929E+00 -0.2846 18 HSiO3- 0.10485E-01 -1.9794 0.87567E-02 -2.0577 0.83516E+00 -0.0782 19 Ca(HSiO3)+ 0.15219E-07 -7.8176 0.12735E-07 -7.8950 0.83676E+00 -0.0774 20 Mg(HSiO3)+ 0.32157E-11 -11.4927 0.26908E-11 -11.5701 0.83676E+00 -0.0774 21 NaHSiO3,aq 0.23487E-02 -2.6292 0.23487E-02 -2.6292 0.10000E+01 0.0000 22 AlO+ 0.65925E-16 -16.1809 0.55164E-16 -16.2583 0.83676E+00 -0.0774 24 HAlO2,aq 0.14747E-09 -9.8313 0.14747E-09 -9.8313 0.10000E+01 0.0000 25 AlO2- 0.52564E-05 -5.2793 0.43820E-05 -5.3583 0.83365E+00 -0.0790 26 CH4,aq 0.14074E-04 -4.8516 0.14025E-04 -4.8531 0.99654E+00 -0.0015 27 C2H6,aq 0.65935E-14 -14.1809 0.65707E-14 -14.1824 0.99654E+00 -0.0015 31 CO,aq 0.12189E-15 -15.9140 0.12189E-15 -15.9140 0.10000E+01 0.0000 32 CO2,aq 0.95137E-09 -9.0217 0.94807E-09 -9.0232 0.99654E+00 -0.0015 33 CO3-2 0.13479E-04 -4.8704 0.69835E-05 -5.1559 0.51812E+00 -0.2856 34 CaCO3,aq 0.55918E-08 -8.2525 0.55918E-08 -8.2525 0.10000E+01 0.0000 35 Ca(HCO3)+ 0.11603E-10 -10.9354 0.97086E-11 -11.0128 0.83676E+00 -0.0774 36 CaCl+ 0.15933E-10 -10.7977 0.13332E-10 -10.8751 0.83676E+00 -0.0774 37 CaCl2,aq 0.40861E-15 -15.3887 0.40861E-15 -15.3887 0.10000E+01 0.0000 38 CaF+ 0.20614E-12 -12.6858 0.17249E-12 -12.7632 0.83676E+00 -0.0774 39 CaOH+ 0.73011E-07 -7.1366 0.61093E-07 -7.2140 0.83676E+00 -0.0774 40 CaSO4,aq 0.24565E-15 -15.6097 0.24565E-15 -15.6097 0.10000E+01 0.0000 41 HCl,aq 0.17611E-14 -14.7542 0.17611E-14 -14.7542 0.10000E+01 0.0000 45 HF,aq 0.94350E-13 -13.0253 0.94350E-13 -13.0253 0.10000E+01 0.0000 48 FeCl+ 0.57799E-17 -17.2381 0.48364E-17 -17.3155 0.83676E+00 -0.0774 51 FeF+ 0.26761E-18 -18.5725 0.22393E-18 -18.6499 0.83676E+00 -0.0774 53 FeO,aq 0.16588E-09 -9.7802 0.16588E-09 -9.7802 0.10000E+01 0.0000 54 FeOH+ 0.12368E-10 -10.9077 0.10349E-10 -10.9851 0.83676E+00 -0.0774 55 HFeO2- 0.27896E-07 -7.5545 0.23298E-07 -7.6327 0.83516E+00 -0.0782 56 FeO+ 0.13040E-16 -16.8847 0.10912E-16 -16.9621 0.83676E+00 -0.0774 58 FeO2- 0.48174E-09 -9.3172 0.40233E-09 -9.3954 0.83516E+00 -0.0782 59 HFeO2,aq 0.38120E-11 -11.4189 0.38120E-11 -11.4189 0.10000E+01 0.0000 60 H2,aq 0.51357E-05 -5.2894 0.51179E-05 -5.2909 0.99654E+00 -0.0015 61 KCl,aq 0.30614E-09 -9.5141 0.30614E-09 -9.5141 0.10000E+01 0.0000 63 KOH,aq 0.75060E-06 -6.1246 0.75060E-06 -6.1246 0.10000E+01 0.0000 64 KSO4- 0.29471E-13 -13.5306 0.24613E-13 -13.6088 0.83516E+00 -0.0782 65 MgCO3,aq 0.23797E-12 -12.6235 0.23797E-12 -12.6235 0.10000E+01 0.0000 66 Mg(HCO3)+ 0.20129E-14 -14.6962 0.16843E-14 -14.7736 0.83676E+00 -0.0774 67 MgCl+ 0.24517E-14 -14.6105 0.20515E-14 -14.6879 0.83676E+00 -0.0774 68 MgF+ 0.12965E-15 -15.8872 0.10848E-15 -15.9646 0.83676E+00 -0.0774 69 MgOH+ 0.68592E-10 -10.1637 0.57395E-10 -10.2411 0.83676E+00 -0.0774 71 MnF+ 0.35776E-16 -16.4464 0.29936E-16 -16.5238 0.83676E+00 -0.0774 72 MnO,aq 0.17927E-08 -8.7465 0.17927E-08 -8.7465 0.10000E+01 0.0000 73 MnOH+ 0.46601E-09 -9.3316 0.38994E-09 -9.4090 0.83676E+00 -0.0774 74 MnO2-2 0.20691E-10 -10.6842 0.10721E-10 -10.9698 0.51812E+00 -0.2856 75 HMnO2- 0.20950E-09 -9.6788 0.17497E-09 -9.7570 0.83516E+00 -0.0782 78 MnCl+ 0.91202E-14 -14.0400 0.76315E-14 -14.1174 0.83676E+00 -0.0774 79 MnSO4,aq 0.33596E-19 -19.4737 0.33596E-19 -19.4737 0.10000E+01 0.0000 80 NaCl,aq 0.70902E-06 -6.1493 0.70902E-06 -6.1493 0.10000E+01 0.0000 81 NaF,aq 0.71833E-09 -9.1437 0.71833E-09 -9.1437 0.10000E+01 0.0000 82 NaOH,aq 0.95648E-04 -4.0193 0.95648E-04 -4.0193 0.10000E+01 0.0000 84 OH- 0.93035E-02 -2.0314 0.77559E-02 -2.1104 0.83365E+00 -0.0790 89 HPO3-2 0.72444E-15 -15.1400 0.37534E-15 -15.4256 0.51812E+00 -0.2856 91 H2PO3- 0.67137E-19 -19.1730 0.56071E-19 -19.2513 0.83516E+00 -0.0782 92 H3PO4,aq 0.91342E-18 -18.0393 0.91342E-18 -18.0393 0.10000E+01 0.0000 93 H2PO4- 0.38687E-10 -10.4124 0.32341E-10 -10.4902 0.83595E+00 -0.0778 94 PO4-3 0.10626E-08 -8.9736 0.25775E-09 -9.5888 0.24256E+00 -0.6152 98 HP2O7-3 0.95091E-18 -18.0219 0.21983E-18 -18.6579 0.23117E+00 -0.6361 99 P2O7-4 0.91486E-17 -17.0386 0.70495E-18 -18.1518 0.77056E-01 -1.1132 100 H2S,aq 0.67847E-08 -8.1685 0.67612E-08 -8.1700 0.99654E+00 -0.0015 101 S2-2 0.72063E-14 -14.1423 0.37337E-14 -14.4279 0.51812E+00 -0.2856 107 SO3-2 0.15328E-16 -16.8145 0.80567E-17 -17.0938 0.52561E+00 -0.2793 108 HSO3- 0.44996E-19 -19.3468 0.37579E-19 -19.4251 0.83516E+00 -0.0782 109 HSO4- 0.10383E-17 -17.9837 0.86969E-18 -18.0606 0.83758E+00 -0.0770 Charge balance for all species = -.6133E-08 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.8866152E-10 -.2226955E-01 -.2240735E+02 0.0000 2 H2O 0.1000000E+01 0.5550485E+02 0.9981980E+06 0.0000 3 Cl- 0.1544689E-03 0.1551783E-03 0.5491970E+01 6.2385 4 SO4-- 0.2333122E-10 -.1535777E-04 -.1472727E+01 9.3390 5 HCO3- 0.7121188E-05 0.3468036E-04 0.2112419E+01 4.9028 6 HS- 0.3515734E-04 0.5052191E-04 0.1667956E+01 5.5957 7 Al+++ 0.9743803E-29 0.5256526E-05 0.1415824E+00 0.7359 8 H4SiO4 0.6986163E-03 0.1353235E-01 0.1298406E+04 -3.1558 9 Ca++ 0.1238980E-06 0.2177474E-06 0.8711706E-02 13.0610 10 Mg++ 0.2113210E-10 0.9318241E-10 0.2261512E-05 9.2908 11 Fe++ 0.4611497E-13 0.2856030E-07 0.1592234E-02 6.6302 12 K+ 0.1565098E-03 0.1572608E-03 0.6138519E+01 6.2449 13 Na+ 0.1986089E-01 0.2230600E-01 0.5119189E+03 8.3476 14 Mn++ 0.1868819E-10 0.2507563E-08 0.1375210E-03 9.2383 15 F- 0.2219839E-06 0.2227026E-06 0.4223548E-02 3.3951 16 HPO4-- 0.4531904E-07 0.4642034E-07 0.4447631E-02 12.6274 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.1999962E-01 -.1999937E-01 -.2554046E-06 0.0000000E+00 2 H2O 0.4984661E+02 0.4984661E+02 -.2165534E-06 0.0000000E+00 3 Cl- 0.1393592E-03 0.1393592E-03 0.0000000E+00 0.0000000E+00 4 SO4-- -.1379131E-04 -.1379218E-04 0.8679303E-09 0.0000000E+00 5 HCO3- 0.3114500E-04 0.3114500E-04 0.0000000E+00 0.0000000E+00 6 HS- 0.4537078E-04 0.4537165E-04 -.8679303E-09 0.0000000E+00 7 Al+++ 0.4775352E-05 0.4720669E-05 0.5468270E-07 0.0000000E+00 8 H4SiO4 0.1215302E-01 0.1215285E-01 0.1723448E-06 0.0000000E+00 9 Ca++ 0.2080835E-06 0.1955499E-06 0.1253358E-07 0.0000000E+00 10 Mg++ 0.8368328E-10 0.8368328E-10 0.0000000E+00 0.0000000E+00 11 Fe++ 0.3259227E-07 0.2564883E-07 0.6943443E-08 0.0000000E+00 12 K+ 0.1412294E-03 0.1412294E-03 0.0000000E+00 0.0000000E+00 13 Na+ 0.2003215E-01 0.2003210E-01 0.5327042E-07 0.0000000E+00 14 Mn++ 0.2251939E-08 0.2251939E-08 0.0000000E+00 0.0000000E+00 15 F- 0.2000000E-06 0.2000000E-06 0.0000000E+00 0.0000000E+00 16 HPO4-- 0.4168819E-07 0.4168819E-07 0.0000000E+00 0.0000000E+00 Chg. balance for solid moles: 0.2647E-22 Mass of aqueous solution: 0.899623E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 0.0002500 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 0.5327E-07 -7.274 0.1397E-04 -4.855 87.03 0.5362E-05 andradite 0.3472E-08 -8.459 0.1764E-05 -5.753 10.99 0.4584E-06 grossular 0.7061E-09 -9.151 0.3181E-06 -6.497 1.982 0.8850E-07 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8310E+00 0.8310E+00 1.0000 -0.080 grossular 0.1690E+00 0.1690E+00 1.0000 -0.772 Solid products produced: Mass = 0.000016 g Volume = 0.000006 cm3 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.0002500 moles log = -3.6021 Original solution: 1000.0103000 g Original solution / Rock added: 4000041.20 (Water/Rock Ratio), log = 6.6021 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0478 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9741E+00 0.9856 0.1006E+01 0.1021E+01 CO2,gas 0.9615E-07 1.0069 0.1014E-06 0.1007E-06 CH4,gas 0.1946E-01 1.0123 0.2064E-01 0.2039E-01 H2,gas 0.6409E-02 1.0006 0.6719E-02 0.6715E-02 H2S,gas 0.1781E-06 0.9959 0.1859E-06 0.1866E-06 S2,gas 0.2741E-28 1.0000 0.2872E-28 0.2872E-28 CO,gas 0.1734E-12 1.0000 0.1816E-12 0.1816E-12 SO3,gas 0.2426E-46 1.0000 0.2542E-46 0.2542E-46 SO2,gas 0.6342E-26 1.0000 0.6645E-26 0.6645E-26 HF,gas 0.2211E-15 1.0000 0.2317E-15 0.2317E-15 HCl,gas 0.2966E-17 1.0000 0.3107E-17 0.3107E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 17 albite -0.38 -0.38 0.00 0.000 0.11184E-10 23 andradite 39.01 39.01 0.00 0.000 0.12132E-10 24 grossular 32.73 32.73 0.00 0.000 0.24265E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -15.35 -8.69 -2.898 0.14843E+05 -6.994 3 CH4,gas 4.54 1.16 -3.38 -0.846 0.57784E+04 -1.685 4 H2,gas 8.00 4.13 -3.87 -2.212 0.66107E+04 -2.173 5 H2S,gas -6.23 -14.66 -8.43 -4.215 0.14394E+05 -6.731 6 S2,gas -7.34 -37.58 -30.24 -4.652 0.51635E+05 -28.542 7 CO,gas 3.21 -11.22 -14.44 -4.443 0.24655E+05 -12.741 8 SO3,gas 17.12 -31.17 -48.29 -12.073 0.82460E+05 -46.595 9 SO2,gas 0.83 -27.04 -27.88 -7.434 0.47598E+05 -26.178 10 HF,gas 0.47 -16.86 -17.33 -8.667 0.29598E+05 -15.635 11 HCl,gas 5.19 -14.02 -19.21 -9.603 0.32795E+05 -17.508 12 acmite 7.71 6.60 -1.11 -0.115 0.18910E+04 16 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 20 spessartine 24.46 19.72 -4.74 -0.237 0.80900E+04 21 analcite 3.32 2.77 -0.55 -0.061 0.93905E+03 27 annite 20.12 17.40 -2.72 -0.151 0.46430E+04 28 phlogopite 27.06 25.39 -1.68 -0.093 0.28661E+04 30 anorthite 12.71 8.22 -4.49 -0.345 0.76651E+04 33 apatite-OH -18.15 -18.35 -0.19 -0.015 0.33103E+03 34 apatite-F -34.30 -35.21 -0.91 -0.076 0.15488E+04 38 aragonite 0.97 -2.29 -3.26 -1.086 0.55638E+04 39 brucite 12.57 9.29 -3.28 -0.656 0.55966E+04 40 calcite 0.81 -2.29 -3.10 -1.035 0.52995E+04 41 carnegieite-low 9.02 5.93 -3.10 -0.442 0.52857E+04 42 carnegieite-high 10.09 5.93 -4.17 -0.595 0.71127E+04 43 carpholite-Mg 8.58 4.45 -4.13 -0.275 0.70537E+04 44 carpholite-Fe 6.71 1.79 -4.92 -0.328 0.84046E+04 45 celadonite 5.34 3.65 -1.69 -0.100 0.28908E+04 46 celadonite-Fe 3.88 0.99 -2.89 -0.170 0.49322E+04 47 chrysotile 23.89 21.56 -2.33 -0.194 0.39808E+04 49 clinochlore 39.07 38.46 -0.61 -0.019 0.10430E+04 50 daphnite 28.97 25.16 -3.81 -0.119 0.65050E+04 52 chlorite-Al-free 47.17 43.12 -4.05 -0.169 0.69167E+04 54 chloritoid-Fe 9.17 4.95 -4.23 -0.282 0.72183E+04 55 chloritoid-Mn 11.40 7.55 -3.85 -0.256 0.65683E+04 57 coesite -2.38 -3.16 -0.78 -0.260 0.13313E+04 64 cristobalite -2.56 -3.16 -0.60 -0.198 0.10167E+04 66 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71234E+04 68 diaspore 2.87 0.74 -2.14 -0.356 0.36503E+04 69 diamond -3.10 -7.10 -3.99 -1.141 0.68202E+04 70 diopside 16.18 16.04 -0.14 -0.014 0.24088E+03 71 hedenbergite 14.21 13.38 -0.83 -0.083 0.14148E+04 74 enstatite 17.26 12.27 -4.99 -0.499 0.85284E+04 76 clinoenstatite 17.17 12.27 -4.90 -0.490 0.83600E+04 78 epidote 24.67 22.69 -1.98 -0.096 0.33764E+04 79 clinozoisite 22.81 18.86 -3.94 -0.179 0.67340E+04 80 epidote-Fe 29.84 26.52 -3.32 -0.172 0.56654E+04 81 fayalite 14.05 10.10 -3.94 -0.563 0.67292E+04 82 ferrosilite 11.15 6.95 -4.20 -0.420 0.71723E+04 86 gibbsite 4.08 0.74 -3.34 -0.478 0.57089E+04 87 glaucophane 22.97 20.79 -2.18 -0.059 0.37249E+04 88 glaucophane-Fe 17.28 12.81 -4.46 -0.121 0.76229E+04 89 graphite -3.55 -7.10 -3.55 -1.014 0.60624E+04 90 greenalite 16.14 13.58 -2.56 -0.213 0.43718E+04 93 hematite 12.57 9.13 -3.43 -0.416 0.58632E+04 94 heulandite -5.83 -7.56 -1.73 -0.079 0.29546E+04 98 jadeite 4.22 2.77 -1.44 -0.144 0.24645E+04 100 kalsilite 7.58 3.83 -3.76 -0.537 0.64182E+04 101 kaolinite -1.33 -4.84 -3.51 -0.319 0.59882E+04 104 laumontite 2.88 1.91 -0.97 -0.065 0.16627E+04 105 lawsonite 9.62 8.22 -1.39 -0.093 0.23818E+04 106 leucite 4.12 0.67 -3.45 -0.345 0.58901E+04 108 lizardite 23.24 21.56 -1.68 -0.140 0.28734E+04 110 magnetite 20.09 15.76 -4.32 -0.353 0.73845E+04 111 minnesotaite 10.39 7.27 -3.12 -0.184 0.53281E+04 115 manganosite 14.06 9.24 -4.82 -1.205 0.82297E+04 119 microcline -2.49 -2.49 0.00 0.000 0.21045E-01 123 muscovite 2.58 -1.01 -3.60 -0.212 0.61422E+04 124 paragonite 4.24 1.09 -3.15 -0.185 0.53813E+04 125 nepheline 8.34 5.93 -2.41 -0.345 0.41181E+04 131 periclase-Fe 11.63 6.63 -5.00 -1.249 0.85312E+04 137 phlogopite-Na 29.65 27.49 -2.16 -0.120 0.36849E+04 139 prehnite 19.37 18.13 -1.25 -0.073 0.21267E+04 140 prehnite-Fe 22.50 21.96 -0.54 -0.033 0.92410E+03 141 pumpellyite-Fe 46.27 43.62 -2.65 -0.059 0.45259E+04 142 pumpellyite-Mg 48.99 46.28 -2.72 -0.060 0.46366E+04 146 pyrrhotite -4.26 -8.03 -3.77 -1.256 0.64363E+04 147 pyrrhotiteFe0.875 -6.02 -9.37 -3.35 -1.233 0.57260E+04 148 pyroxmangite 7.40 6.08 -1.32 -0.263 0.22473E+04 149 pyrophyllite -6.18 -11.15 -4.98 -0.311 0.84956E+04 150 quartz -2.99 -3.16 -0.17 -0.055 0.28400E+03 155 rhodonite 7.45 6.08 -1.36 -0.273 0.23275E+04 156 sanidine -1.28 -2.49 -1.21 -0.093 0.20678E+04 166 stilbite -7.52 -7.56 -0.04 -0.002 0.60807E+02 167 stilpnomelane-Fe 13.02 12.50 -0.52 -0.015 0.88410E+03 168 stilpnomelane-Mg 27.44 25.80 -1.64 -0.049 0.27987E+04 174 talc 16.49 15.25 -1.24 -0.073 0.21200E+04 177 tephroite 18.09 15.32 -2.76 -0.395 0.47211E+04 181 tridymite -2.63 -3.16 -0.53 -0.176 0.90397E+03 182 tremolite 47.87 47.33 -0.54 -0.015 0.92065E+03 183 ferroactinolite 38.45 34.03 -4.43 -0.120 0.75563E+04 184 troilite-low -4.41 -8.03 -3.62 -1.206 0.61791E+04 190 wairakite 3.95 1.91 -2.04 -0.120 0.34847E+04 191 walstromite 11.51 9.91 -1.60 -0.321 0.27388E+04 192 wollastonite 10.46 9.91 -0.56 -0.111 0.94927E+03 193 pseudo-wollastonite 11.00 9.91 -1.09 -0.219 0.18691E+04 194 zoisite 22.85 18.86 -3.99 -0.181 0.68081E+04 195 akaganeite 7.75 4.57 -3.19 -0.689 0.54441E+04 202 chalcedony -2.80 -3.16 -0.35 -0.118 0.60329E+03 204 montmorillonite-Ca -2.29 -6.17 -3.88 -0.240 0.66291E+04 205 montmorillonite-K -2.24 -6.27 -4.03 -0.247 0.68822E+04 206 montmorillonite-Mg -2.48 -6.80 -4.32 -0.267 0.73683E+04 207 montmorillonite-Na -2.04 -5.57 -3.54 -0.217 0.60371E+04 208 nontronite-Ca 3.21 -0.05 -3.27 -0.212 0.55765E+04 209 nontronite-H 2.53 -2.21 -4.74 -0.318 0.80920E+04 210 nontronite-K 3.34 -0.15 -3.49 -0.224 0.59529E+04 211 nontronite-Mg 3.07 -0.67 -3.75 -0.243 0.63998E+04 212 nontronite-Na 3.52 0.55 -2.97 -0.191 0.50737E+04 228 tobermorite 9.82 7.72 -2.10 -0.573 0.35840E+04 234 alabandite -0.98 -5.42 -4.44 -1.481 0.75877E+04 237 boehmite 4.41 0.74 -3.67 -0.612 0.62672E+04 239 ferrous-oxide 9.81 6.63 -3.18 -0.795 0.54321E+04 245 silica-amorphous -2.09 -3.16 -1.06 -0.355 0.18175E+04 247 an20ab80 2.02 1.34 -0.68 -0.052 0.11622E+04 248 an25ab75 2.65 1.77 -0.88 -0.068 0.14997E+04 249 an30ab70 3.28 2.20 -1.08 -0.083 0.18468E+04 250 tr.625ac.25prg.125 45.16 44.95 -0.21 -0.006 0.36452E+03 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 0.0000100 MOLES Current total amount of reactant added: 0.0002500 MOLES New total amount of reactant added: 0.0002600 MOLES Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.5508E-08 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 6 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 0.0002600 Water: Moles liquid = 0.4985E+02 kg liquid = 0.8981E+00 Moles total = 0.4985E+02 kg total = 0.8980E+00 Activity = 1.0000 Stoichiometric ionic strength = .1134679E-01 Osmotic coef. = 0.9685 True ionic strength = .2003198E-01 Chg. balance for total moles = -.5508E-08 Max. difference allowed = 0.1394E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.88677E-10 -10.0522 0.74508E-10 -10.1278 0.84022E+00 -0.0756 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.15453E-03 -3.8110 0.12906E-03 -3.8892 0.83516E+00 -0.0782 4 SO4-- 0.24546E-10 -10.6100 0.12744E-10 -10.8947 0.51922E+00 -0.2847 5 HCO3- 0.74138E-05 -5.1300 0.62008E-05 -5.2076 0.83638E+00 -0.0776 6 HS- 0.35428E-04 -4.4507 0.29592E-04 -4.5288 0.83528E+00 -0.0782 7 Al+++ 0.97460E-29 -29.0112 0.22507E-29 -29.6477 0.23094E+00 -0.6365 8 H4SiO4 0.69873E-03 -3.1557 0.69873E-03 -3.1557 0.10000E+01 0.0000 9 Ca++ 0.12371E-06 -6.9076 0.63761E-07 -7.1954 0.51540E+00 -0.2879 10 Mg++ 0.21133E-10 -10.6750 0.10842E-10 -10.9649 0.51304E+00 -0.2898 11 Fe++ 0.46027E-13 -13.3370 0.23640E-13 -13.6264 0.51361E+00 -0.2894 12 K+ 0.15651E-03 -3.8055 0.13093E-03 -3.8829 0.83658E+00 -0.0775 13 Na+ 0.19861E-01 -1.7020 0.16584E-01 -1.7803 0.83501E+00 -0.0783 14 Mn++ 0.18694E-10 -10.7283 0.96096E-11 -11.0173 0.51403E+00 -0.2890 15 F- 0.22642E-06 -6.6451 0.18871E-06 -6.7242 0.83344E+00 -0.0791 16 HPO4-- 0.45319E-07 -7.3437 0.23534E-07 -7.6283 0.51929E+00 -0.2846 18 HSiO3- 0.10485E-01 -1.9794 0.87566E-02 -2.0577 0.83516E+00 -0.0782 19 Ca(HSiO3)+ 0.15196E-07 -7.8183 0.12715E-07 -7.8957 0.83676E+00 -0.0774 20 Mg(HSiO3)+ 0.32157E-11 -11.4927 0.26908E-11 -11.5701 0.83676E+00 -0.0774 21 NaHSiO3,aq 0.23487E-02 -2.6292 0.23487E-02 -2.6292 0.10000E+01 0.0000 22 AlO+ 0.65916E-16 -16.1810 0.55156E-16 -16.2584 0.83676E+00 -0.0774 24 HAlO2,aq 0.14742E-09 -9.8314 0.14742E-09 -9.8314 0.10000E+01 0.0000 25 AlO2- 0.52538E-05 -5.2795 0.43799E-05 -5.3585 0.83365E+00 -0.0790 26 CH4,aq 0.14035E-04 -4.8528 0.13986E-04 -4.8543 0.99654E+00 -0.0015 27 C2H6,aq 0.66280E-14 -14.1786 0.66050E-14 -14.1801 0.99654E+00 -0.0015 31 CO,aq 0.12556E-15 -15.9012 0.12556E-15 -15.9012 0.10000E+01 0.0000 32 CO2,aq 0.99063E-09 -9.0041 0.98720E-09 -9.0056 0.99654E+00 -0.0015 33 CO3-2 0.14030E-04 -4.8529 0.72692E-05 -5.1385 0.51811E+00 -0.2856 34 CaCO3,aq 0.58117E-08 -8.2357 0.58117E-08 -8.2357 0.10000E+01 0.0000 35 Ca(HCO3)+ 0.12061E-10 -10.9186 0.10092E-10 -10.9960 0.83676E+00 -0.0774 36 CaCl+ 0.15915E-10 -10.7982 0.13317E-10 -10.8756 0.83676E+00 -0.0774 37 CaCl2,aq 0.40833E-15 -15.3890 0.40833E-15 -15.3890 0.10000E+01 0.0000 38 CaF+ 0.20994E-12 -12.6779 0.17567E-12 -12.7553 0.83676E+00 -0.0774 39 CaOH+ 0.72888E-07 -7.1373 0.60990E-07 -7.2147 0.83676E+00 -0.0774 40 CaSO4,aq 0.25804E-15 -15.5883 0.25804E-15 -15.5883 0.10000E+01 0.0000 41 HCl,aq 0.17621E-14 -14.7540 0.17621E-14 -14.7540 0.10000E+01 0.0000 45 HF,aq 0.96253E-13 -13.0166 0.96253E-13 -13.0166 0.10000E+01 0.0000 48 FeCl+ 0.57712E-17 -17.2387 0.48291E-17 -17.3161 0.83676E+00 -0.0774 51 FeF+ 0.27244E-18 -18.5647 0.22797E-18 -18.6421 0.83676E+00 -0.0774 53 FeO,aq 0.16550E-09 -9.7812 0.16550E-09 -9.7812 0.10000E+01 0.0000 54 FeOH+ 0.12342E-10 -10.9086 0.10328E-10 -10.9860 0.83676E+00 -0.0774 55 HFeO2- 0.27828E-07 -7.5555 0.23241E-07 -7.6337 0.83516E+00 -0.0782 56 FeO+ 0.13084E-16 -16.8833 0.10948E-16 -16.9607 0.83676E+00 -0.0774 58 FeO2- 0.48317E-09 -9.3159 0.40353E-09 -9.3941 0.83516E+00 -0.0782 59 HFeO2,aq 0.38239E-11 -11.4175 0.38239E-11 -11.4175 0.10000E+01 0.0000 60 H2,aq 0.50804E-05 -5.2941 0.50629E-05 -5.2956 0.99654E+00 -0.0015 61 KCl,aq 0.30627E-09 -9.5139 0.30627E-09 -9.5139 0.10000E+01 0.0000 63 KOH,aq 0.75047E-06 -6.1247 0.75047E-06 -6.1247 0.10000E+01 0.0000 64 KSO4- 0.31005E-13 -13.5086 0.25894E-13 -13.5868 0.83516E+00 -0.0782 65 MgCO3,aq 0.24771E-12 -12.6061 0.24771E-12 -12.6061 0.10000E+01 0.0000 66 Mg(HCO3)+ 0.20956E-14 -14.6787 0.17535E-14 -14.7561 0.83676E+00 -0.0774 67 MgCl+ 0.24528E-14 -14.6103 0.20524E-14 -14.6877 0.83676E+00 -0.0774 68 MgF+ 0.13224E-15 -15.8786 0.11065E-15 -15.9560 0.83676E+00 -0.0774 69 MgOH+ 0.68582E-10 -10.1638 0.57386E-10 -10.2412 0.83676E+00 -0.0774 71 MnF+ 0.36503E-16 -16.4377 0.30545E-16 -16.5151 0.83676E+00 -0.0774 72 MnO,aq 0.17926E-08 -8.7465 0.17926E-08 -8.7465 0.10000E+01 0.0000 73 MnOH+ 0.46608E-09 -9.3315 0.39000E-09 -9.4089 0.83676E+00 -0.0774 74 MnO2-2 0.20684E-10 -10.6844 0.10717E-10 -10.9699 0.51811E+00 -0.2856 75 HMnO2- 0.20946E-09 -9.6789 0.17493E-09 -9.7571 0.83516E+00 -0.0782 78 MnCl+ 0.91271E-14 -14.0397 0.76372E-14 -14.1171 0.83676E+00 -0.0774 79 MnSO4,aq 0.35356E-19 -19.4515 0.35356E-19 -19.4515 0.10000E+01 0.0000 80 NaCl,aq 0.70932E-06 -6.1492 0.70932E-06 -6.1492 0.10000E+01 0.0000 81 NaF,aq 0.73269E-09 -9.1351 0.73269E-09 -9.1351 0.10000E+01 0.0000 82 NaOH,aq 0.95632E-04 -4.0194 0.95632E-04 -4.0194 0.10000E+01 0.0000 84 OH- 0.93019E-02 -2.0314 0.77545E-02 -2.1104 0.83365E+00 -0.0790 89 HPO3-2 0.71665E-15 -15.1447 0.37131E-15 -15.4303 0.51811E+00 -0.2856 91 H2PO3- 0.66427E-19 -19.1777 0.55477E-19 -19.2559 0.83516E+00 -0.0782 92 H3PO4,aq 0.91373E-18 -18.0392 0.91373E-18 -18.0392 0.10000E+01 0.0000 93 H2PO4- 0.38694E-10 -10.4124 0.32346E-10 -10.4902 0.83595E+00 -0.0778 94 PO4-3 0.10624E-08 -8.9737 0.25770E-09 -9.5889 0.24256E+00 -0.6152 98 HP2O7-3 0.95109E-18 -18.0218 0.21986E-18 -18.6579 0.23117E+00 -0.6361 99 P2O7-4 0.91488E-17 -17.0386 0.70495E-18 -18.1518 0.77053E-01 -1.1132 100 H2S,aq 0.68381E-08 -8.1651 0.68144E-08 -8.1666 0.99654E+00 -0.0015 101 S2-2 0.73972E-14 -14.1309 0.38326E-14 -14.4165 0.51811E+00 -0.2856 107 SO3-2 0.15953E-16 -16.7972 0.83848E-17 -17.0765 0.52561E+00 -0.2793 108 HSO3- 0.46837E-19 -19.3294 0.39116E-19 -19.4076 0.83516E+00 -0.0782 109 HSO4- 0.10926E-17 -17.9616 0.91511E-18 -18.0385 0.83758E+00 -0.0770 Charge balance for all species = -.6133E-08 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.8867711E-10 -.2226834E-01 -.2240612E+02 0.0000 2 H2O 0.1000000E+01 0.5550484E+02 0.9981979E+06 0.0000 3 Cl- 0.1545343E-03 0.1552439E-03 0.5494294E+01 6.2386 4 SO4-- 0.2454562E-10 -.1530460E-04 -.1467629E+01 9.3609 5 HCO3- 0.7413823E-05 0.3548542E-04 0.2161457E+01 4.9202 6 HS- 0.3542786E-04 0.5073933E-04 0.1675134E+01 5.5990 7 Al+++ 0.9745998E-29 0.5253971E-05 0.1415135E+00 0.7357 8 H4SiO4 0.6987301E-03 0.1353234E-01 0.1298405E+04 -3.1557 9 Ca++ 0.1237112E-06 0.2176345E-06 0.8707192E-02 13.0602 10 Mg++ 0.2113268E-10 0.9318239E-10 0.2261512E-05 9.2907 11 Fe++ 0.4602675E-13 0.2849328E-07 0.1588498E-02 6.6292 12 K+ 0.1565099E-03 0.1572607E-03 0.6138518E+01 6.2448 13 Na+ 0.1986093E-01 0.2230599E-01 0.5119187E+03 8.3475 14 Mn++ 0.1869450E-10 0.2507563E-08 0.1375210E-03 9.2383 15 F- 0.2264236E-06 0.2271566E-06 0.4308018E-02 3.4036 16 HPO4-- 0.4531919E-07 0.4642033E-07 0.4447630E-02 12.6273 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.1999854E-01 -.1999828E-01 -.2648878E-06 0.0000000E+00 2 H2O 0.4984662E+02 0.4984662E+02 -.2257293E-06 0.0000000E+00 3 Cl- 0.1394182E-03 0.1394182E-03 0.0000000E+00 0.0000000E+00 4 SO4-- -.1374356E-04 -.1374444E-04 0.8754531E-09 0.0000000E+00 5 HCO3- 0.3186800E-04 0.3186800E-04 0.0000000E+00 0.0000000E+00 6 HS- 0.4556603E-04 0.4556691E-04 -.8754531E-09 0.0000000E+00 7 Al+++ 0.4775352E-05 0.4718376E-05 0.5697648E-07 0.0000000E+00 8 H4SiO4 0.1215302E-01 0.1215284E-01 0.1793054E-06 0.0000000E+00 9 Ca++ 0.2080835E-06 0.1954486E-06 0.1263486E-07 0.0000000E+00 10 Mg++ 0.8368328E-10 0.8368328E-10 0.0000000E+00 0.0000000E+00 11 Fe++ 0.3259227E-07 0.2558864E-07 0.7003625E-08 0.0000000E+00 12 K+ 0.1412294E-03 0.1412294E-03 0.0000000E+00 0.0000000E+00 13 Na+ 0.2003215E-01 0.2003209E-01 0.5555686E-07 0.0000000E+00 14 Mn++ 0.2251939E-08 0.2251939E-08 0.0000000E+00 0.0000000E+00 15 F- 0.2040000E-06 0.2040000E-06 0.0000000E+00 0.0000000E+00 16 HPO4-- 0.4168819E-07 0.4168819E-07 0.0000000E+00 0.0000000E+00 Chg. balance for solid moles: 0.5294E-22 Mass of aqueous solution: 0.899623E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 0.0002600 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 0.5556E-07 -7.255 0.1457E-04 -4.837 87.40 0.5592E-05 andradite 0.3502E-08 -8.456 0.1780E-05 -5.750 10.68 0.4623E-06 grossular 0.7098E-09 -9.149 0.3197E-06 -6.495 1.918 0.8896E-07 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8315E+00 0.8315E+00 1.0000 -0.080 grossular 0.1685E+00 0.1685E+00 1.0000 -0.773 Solid products produced: Mass = 0.000017 g Volume = 0.000006 cm3 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.0002600 moles log = -3.5850 Original solution: 1000.0103000 g Original solution / Rock added: 3846193.46 (Water/Rock Ratio), log = 6.5850 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0477 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9742E+00 0.9856 0.1006E+01 0.1021E+01 CO2,gas 0.1001E-06 1.0069 0.1056E-06 0.1049E-06 CH4,gas 0.1941E-01 1.0123 0.2059E-01 0.2034E-01 H2,gas 0.6341E-02 1.0006 0.6647E-02 0.6643E-02 H2S,gas 0.1795E-06 0.9959 0.1873E-06 0.1881E-06 S2,gas 0.2846E-28 1.0000 0.2981E-28 0.2981E-28 CO,gas 0.1786E-12 1.0000 0.1871E-12 0.1871E-12 SO3,gas 0.2553E-46 1.0000 0.2675E-46 0.2675E-46 SO2,gas 0.6603E-26 1.0000 0.6918E-26 0.6918E-26 HF,gas 0.2256E-15 1.0000 0.2363E-15 0.2363E-15 HCl,gas 0.2968E-17 1.0000 0.3109E-17 0.3109E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 17 albite -0.38 -0.38 0.00 0.000 -0.94784E-12 23 andradite 39.01 39.01 0.00 0.000 -0.12132E-10 24 grossular 32.73 32.73 0.00 0.000 0.00000E+00 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -15.34 -8.68 -2.892 0.14813E+05 -6.976 3 CH4,gas 4.54 1.16 -3.39 -0.846 0.57805E+04 -1.686 4 H2,gas 8.00 4.12 -3.88 -2.215 0.66188E+04 -2.177 5 H2S,gas -6.23 -14.66 -8.43 -4.213 0.14388E+05 -6.727 6 S2,gas -7.34 -37.56 -30.22 -4.650 0.51608E+05 -28.526 7 CO,gas 3.21 -11.21 -14.43 -4.439 0.24634E+05 -12.728 8 SO3,gas 17.12 -31.15 -48.27 -12.068 0.82423E+05 -46.573 9 SO2,gas 0.83 -27.03 -27.86 -7.429 0.47568E+05 -26.160 10 HF,gas 0.47 -16.85 -17.33 -8.663 0.29583E+05 -15.626 11 HCl,gas 5.19 -14.02 -19.21 -9.603 0.32794E+05 -17.507 12 acmite 7.71 6.60 -1.11 -0.115 0.18886E+04 16 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 20 spessartine 24.46 19.72 -4.74 -0.237 0.80901E+04 21 analcite 3.32 2.77 -0.55 -0.061 0.93917E+03 27 annite 20.12 17.40 -2.72 -0.151 0.46481E+04 28 phlogopite 27.06 25.39 -1.68 -0.093 0.28668E+04 30 anorthite 12.71 8.22 -4.49 -0.345 0.76667E+04 33 apatite-OH -18.15 -18.35 -0.20 -0.015 0.33718E+03 34 apatite-F -34.30 -35.20 -0.90 -0.075 0.15401E+04 38 aragonite 0.97 -2.28 -3.24 -1.081 0.55351E+04 39 brucite 12.57 9.29 -3.28 -0.656 0.55969E+04 40 calcite 0.81 -2.28 -3.09 -1.029 0.52709E+04 41 carnegieite-low 9.02 5.93 -3.10 -0.442 0.52860E+04 42 carnegieite-high 10.09 5.93 -4.17 -0.595 0.71130E+04 43 carpholite-Mg 8.58 4.45 -4.13 -0.275 0.70541E+04 44 carpholite-Fe 6.71 1.79 -4.92 -0.328 0.84065E+04 45 celadonite 5.34 3.65 -1.69 -0.100 0.28909E+04 46 celadonite-Fe 3.88 0.99 -2.89 -0.170 0.49337E+04 47 chrysotile 23.89 21.56 -2.33 -0.194 0.39812E+04 49 clinochlore 39.07 38.46 -0.61 -0.019 0.10444E+04 50 daphnite 28.97 25.15 -3.81 -0.119 0.65135E+04 52 chlorite-Al-free 47.17 43.12 -4.05 -0.169 0.69177E+04 54 chloritoid-Fe 9.17 4.94 -4.23 -0.282 0.72203E+04 55 chloritoid-Mn 11.40 7.55 -3.85 -0.256 0.65687E+04 57 coesite -2.38 -3.16 -0.78 -0.260 0.13312E+04 64 cristobalite -2.56 -3.16 -0.60 -0.198 0.10165E+04 66 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71234E+04 68 diaspore 2.87 0.74 -2.14 -0.356 0.36505E+04 69 diamond -3.10 -7.09 -3.99 -1.139 0.68062E+04 70 diopside 16.18 16.04 -0.14 -0.014 0.24226E+03 71 hedenbergite 14.21 13.38 -0.83 -0.083 0.14177E+04 74 enstatite 17.26 12.27 -4.99 -0.499 0.85286E+04 76 clinoenstatite 17.17 12.27 -4.90 -0.490 0.83602E+04 78 epidote 24.67 22.69 -1.98 -0.096 0.33769E+04 79 clinozoisite 22.81 18.86 -3.95 -0.179 0.67371E+04 80 epidote-Fe 29.84 26.52 -3.32 -0.172 0.56633E+04 81 fayalite 14.05 10.10 -3.94 -0.563 0.67325E+04 82 ferrosilite 11.15 6.95 -4.20 -0.420 0.71754E+04 86 gibbsite 4.08 0.74 -3.34 -0.478 0.57091E+04 87 glaucophane 22.97 20.79 -2.18 -0.059 0.37254E+04 88 glaucophane-Fe 17.28 12.81 -4.47 -0.121 0.76277E+04 89 graphite -3.55 -7.09 -3.54 -1.012 0.60485E+04 90 greenalite 16.14 13.58 -2.56 -0.214 0.43766E+04 93 hematite 12.57 9.14 -3.43 -0.416 0.58586E+04 94 heulandite -5.83 -7.56 -1.73 -0.079 0.29556E+04 98 jadeite 4.22 2.77 -1.44 -0.144 0.24647E+04 100 kalsilite 7.58 3.82 -3.76 -0.537 0.64184E+04 101 kaolinite -1.33 -4.84 -3.51 -0.319 0.59884E+04 104 laumontite 2.88 1.91 -0.97 -0.065 0.16641E+04 105 lawsonite 9.62 8.22 -1.40 -0.093 0.23834E+04 106 leucite 4.12 0.67 -3.45 -0.345 0.58902E+04 108 lizardite 23.24 21.56 -1.68 -0.140 0.28739E+04 110 magnetite 20.09 15.76 -4.32 -0.353 0.73816E+04 111 minnesotaite 10.39 7.26 -3.12 -0.184 0.53327E+04 115 manganosite 14.06 9.24 -4.82 -1.205 0.82297E+04 119 microcline -2.49 -2.49 0.00 0.000 0.21883E-01 123 muscovite 2.58 -1.02 -3.60 -0.212 0.61426E+04 124 paragonite 4.24 1.09 -3.15 -0.185 0.53817E+04 125 nepheline 8.34 5.93 -2.41 -0.345 0.41183E+04 131 periclase-Fe 11.63 6.63 -5.00 -1.249 0.85328E+04 137 phlogopite-Na 29.65 27.49 -2.16 -0.120 0.36856E+04 139 prehnite 19.37 18.12 -1.25 -0.073 0.21296E+04 140 prehnite-Fe 22.50 21.96 -0.54 -0.033 0.92441E+03 141 pumpellyite-Fe 46.27 43.61 -2.66 -0.059 0.45336E+04 142 pumpellyite-Mg 48.99 46.28 -2.72 -0.060 0.46429E+04 146 pyrrhotite -4.26 -8.03 -3.77 -1.256 0.64322E+04 147 pyrrhotiteFe0.875 -6.02 -9.37 -3.35 -1.232 0.57207E+04 148 pyroxmangite 7.40 6.08 -1.32 -0.263 0.22472E+04 149 pyrophyllite -6.18 -11.15 -4.98 -0.311 0.84956E+04 150 quartz -2.99 -3.16 -0.17 -0.055 0.28388E+03 155 rhodonite 7.45 6.08 -1.36 -0.273 0.23274E+04 156 sanidine -1.28 -2.49 -1.21 -0.093 0.20678E+04 166 stilbite -7.52 -7.56 -0.04 -0.002 0.61811E+02 167 stilpnomelane-Fe 13.02 12.49 -0.52 -0.016 0.89209E+03 168 stilpnomelane-Mg 27.44 25.80 -1.64 -0.049 0.27995E+04 174 talc 16.49 15.25 -1.24 -0.073 0.21202E+04 177 tephroite 18.09 15.32 -2.76 -0.395 0.47210E+04 181 tridymite -2.63 -3.16 -0.53 -0.176 0.90385E+03 182 tremolite 47.87 47.33 -0.54 -0.015 0.92367E+03 183 ferroactinolite 38.45 34.02 -4.43 -0.120 0.75665E+04 184 troilite-low -4.41 -8.03 -3.62 -1.205 0.61750E+04 190 wairakite 3.95 1.91 -2.04 -0.120 0.34860E+04 191 walstromite 11.51 9.90 -1.60 -0.321 0.27401E+04 192 wollastonite 10.46 9.90 -0.56 -0.111 0.95053E+03 193 pseudo-wollastonite 11.00 9.90 -1.10 -0.219 0.18704E+04 194 zoisite 22.85 18.86 -3.99 -0.181 0.68112E+04 195 akaganeite 7.75 4.57 -3.19 -0.689 0.54418E+04 202 chalcedony -2.80 -3.16 -0.35 -0.118 0.60317E+03 204 montmorillonite-Ca -2.29 -6.17 -3.88 -0.240 0.66293E+04 205 montmorillonite-K -2.24 -6.27 -4.03 -0.247 0.68823E+04 206 montmorillonite-Mg -2.48 -6.80 -4.32 -0.267 0.73683E+04 207 montmorillonite-Na -2.04 -5.57 -3.54 -0.217 0.60371E+04 208 nontronite-Ca 3.21 -0.05 -3.26 -0.212 0.55717E+04 209 nontronite-H 2.53 -2.20 -4.74 -0.317 0.80870E+04 210 nontronite-K 3.34 -0.14 -3.48 -0.224 0.59479E+04 211 nontronite-Mg 3.07 -0.67 -3.75 -0.243 0.63948E+04 212 nontronite-Na 3.52 0.55 -2.97 -0.191 0.50687E+04 228 tobermorite 9.82 7.72 -2.10 -0.573 0.35851E+04 234 alabandite -0.98 -5.42 -4.44 -1.480 0.75819E+04 237 boehmite 4.41 0.74 -3.67 -0.612 0.62675E+04 239 ferrous-oxide 9.81 6.63 -3.18 -0.796 0.54338E+04 245 silica-amorphous -2.09 -3.16 -1.06 -0.355 0.18174E+04 247 an20ab80 2.02 1.34 -0.68 -0.052 0.11625E+04 248 an25ab75 2.65 1.77 -0.88 -0.068 0.15001E+04 249 an30ab70 3.28 2.20 -1.08 -0.083 0.18473E+04 250 tr.625ac.25prg.125 45.16 44.95 -0.22 -0.006 0.36944E+03 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 0.0000100 MOLES Current total amount of reactant added: 0.0002600 MOLES New total amount of reactant added: 0.0002700 MOLES Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.5508E-08 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 6 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 0.0002700 Water: Moles liquid = 0.4985E+02 kg liquid = 0.8981E+00 Moles total = 0.4985E+02 kg total = 0.8980E+00 Activity = 1.0000 Stoichiometric ionic strength = .1134743E-01 Osmotic coef. = 0.9684 True ionic strength = .2003257E-01 Chg. balance for total moles = -.5508E-08 Max. difference allowed = 0.1395E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.88693E-10 -10.0521 0.74521E-10 -10.1277 0.84021E+00 -0.0756 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.15460E-03 -3.8108 0.12912E-03 -3.8890 0.83516E+00 -0.0782 4 SO4-- 0.25784E-10 -10.5887 0.13387E-10 -10.8733 0.51921E+00 -0.2847 5 HCO3- 0.77067E-05 -5.1131 0.64458E-05 -5.1907 0.83638E+00 -0.0776 6 HS- 0.35698E-04 -4.4474 0.29818E-04 -4.5255 0.83528E+00 -0.0782 7 Al+++ 0.97482E-29 -29.0111 0.22512E-29 -29.6476 0.23093E+00 -0.6365 8 H4SiO4 0.69884E-03 -3.1556 0.69884E-03 -3.1556 0.10000E+01 0.0000 9 Ca++ 0.12353E-06 -6.9082 0.63666E-07 -7.1961 0.51540E+00 -0.2879 10 Mg++ 0.21133E-10 -10.6750 0.10842E-10 -10.9649 0.51304E+00 -0.2898 11 Fe++ 0.45945E-13 -13.3378 0.23597E-13 -13.6271 0.51360E+00 -0.2894 12 K+ 0.15651E-03 -3.8055 0.13093E-03 -3.8830 0.83658E+00 -0.0775 13 Na+ 0.19861E-01 -1.7020 0.16584E-01 -1.7803 0.83501E+00 -0.0783 14 Mn++ 0.18701E-10 -10.7281 0.96127E-11 -11.0172 0.51403E+00 -0.2890 15 F- 0.23086E-06 -6.6366 0.19241E-06 -6.7158 0.83344E+00 -0.0791 16 HPO4-- 0.45319E-07 -7.3437 0.23534E-07 -7.6283 0.51929E+00 -0.2846 18 HSiO3- 0.10485E-01 -1.9794 0.87565E-02 -2.0577 0.83516E+00 -0.0782 19 Ca(HSiO3)+ 0.15173E-07 -7.8189 0.12696E-07 -7.8963 0.83676E+00 -0.0774 20 Mg(HSiO3)+ 0.32157E-11 -11.4927 0.26908E-11 -11.5701 0.83676E+00 -0.0774 21 NaHSiO3,aq 0.23487E-02 -2.6292 0.23487E-02 -2.6292 0.10000E+01 0.0000 22 AlO+ 0.65907E-16 -16.1811 0.55148E-16 -16.2585 0.83676E+00 -0.0774 24 HAlO2,aq 0.14738E-09 -9.8316 0.14738E-09 -9.8316 0.10000E+01 0.0000 25 AlO2- 0.52513E-05 -5.2797 0.43777E-05 -5.3588 0.83365E+00 -0.0790 26 CH4,aq 0.13995E-04 -4.8540 0.13946E-04 -4.8555 0.99654E+00 -0.0015 27 C2H6,aq 0.66594E-14 -14.1766 0.66364E-14 -14.1781 0.99654E+00 -0.0015 31 CO,aq 0.12918E-15 -15.8888 0.12918E-15 -15.8888 0.10000E+01 0.0000 32 CO2,aq 0.10299E-08 -8.9872 0.10264E-08 -8.9887 0.99654E+00 -0.0015 33 CO3-2 0.14582E-04 -4.8362 0.75551E-05 -5.1218 0.51811E+00 -0.2856 34 CaCO3,aq 0.60313E-08 -8.2196 0.60313E-08 -8.2196 0.10000E+01 0.0000 35 Ca(HCO3)+ 0.12519E-10 -10.9024 0.10475E-10 -10.9798 0.83676E+00 -0.0774 36 CaCl+ 0.15898E-10 -10.7987 0.13303E-10 -10.8760 0.83676E+00 -0.0774 37 CaCl2,aq 0.40807E-15 -15.3893 0.40807E-15 -15.3893 0.10000E+01 0.0000 38 CaF+ 0.21374E-12 -12.6701 0.17885E-12 -12.7475 0.83676E+00 -0.0774 39 CaOH+ 0.72767E-07 -7.1381 0.60888E-07 -7.2155 0.83676E+00 -0.0774 40 CaSO4,aq 0.27065E-15 -15.5676 0.27065E-15 -15.5676 0.10000E+01 0.0000 41 HCl,aq 0.17632E-14 -14.7537 0.17632E-14 -14.7537 0.10000E+01 0.0000 45 HF,aq 0.98158E-13 -13.0081 0.98158E-13 -13.0081 0.10000E+01 0.0000 48 FeCl+ 0.57633E-17 -17.2393 0.48225E-17 -17.3167 0.83676E+00 -0.0774 51 FeF+ 0.27728E-18 -18.5571 0.23202E-18 -18.6345 0.83676E+00 -0.0774 53 FeO,aq 0.16515E-09 -9.7821 0.16515E-09 -9.7821 0.10000E+01 0.0000 54 FeOH+ 0.12318E-10 -10.9095 0.10307E-10 -10.9869 0.83676E+00 -0.0774 55 HFeO2- 0.27764E-07 -7.5565 0.23187E-07 -7.6347 0.83516E+00 -0.0782 56 FeO+ 0.13126E-16 -16.8819 0.10984E-16 -16.9593 0.83676E+00 -0.0774 58 FeO2- 0.48458E-09 -9.3146 0.40470E-09 -9.3929 0.83516E+00 -0.0782 59 HFeO2,aq 0.38357E-11 -11.4162 0.38357E-11 -11.4162 0.10000E+01 0.0000 60 H2,aq 0.50277E-05 -5.2986 0.50103E-05 -5.3001 0.99654E+00 -0.0015 61 KCl,aq 0.30640E-09 -9.5137 0.30640E-09 -9.5137 0.10000E+01 0.0000 63 KOH,aq 0.75034E-06 -6.1247 0.75034E-06 -6.1247 0.10000E+01 0.0000 64 KSO4- 0.32568E-13 -13.4872 0.27200E-13 -13.5654 0.83516E+00 -0.0782 65 MgCO3,aq 0.25745E-12 -12.5893 0.25745E-12 -12.5893 0.10000E+01 0.0000 66 Mg(HCO3)+ 0.21784E-14 -14.6619 0.18228E-14 -14.7393 0.83676E+00 -0.0774 67 MgCl+ 0.24539E-14 -14.6102 0.20533E-14 -14.6875 0.83676E+00 -0.0774 68 MgF+ 0.13484E-15 -15.8702 0.11283E-15 -15.9476 0.83676E+00 -0.0774 69 MgOH+ 0.68571E-10 -10.1639 0.57378E-10 -10.2413 0.83676E+00 -0.0774 71 MnF+ 0.37231E-16 -16.4291 0.31154E-16 -16.5065 0.83676E+00 -0.0774 72 MnO,aq 0.17926E-08 -8.7465 0.17926E-08 -8.7465 0.10000E+01 0.0000 73 MnOH+ 0.46616E-09 -9.3315 0.39006E-09 -9.4089 0.83676E+00 -0.0774 74 MnO2-2 0.20676E-10 -10.6845 0.10713E-10 -10.9701 0.51811E+00 -0.2856 75 HMnO2- 0.20942E-09 -9.6790 0.17490E-09 -9.7572 0.83516E+00 -0.0782 78 MnCl+ 0.91340E-14 -14.0393 0.76429E-14 -14.1167 0.83676E+00 -0.0774 79 MnSO4,aq 0.37151E-19 -19.4300 0.37151E-19 -19.4300 0.10000E+01 0.0000 80 NaCl,aq 0.70962E-06 -6.1490 0.70962E-06 -6.1490 0.10000E+01 0.0000 81 NaF,aq 0.74706E-09 -9.1266 0.74706E-09 -9.1266 0.10000E+01 0.0000 82 NaOH,aq 0.95615E-04 -4.0195 0.95615E-04 -4.0195 0.10000E+01 0.0000 84 OH- 0.93003E-02 -2.0315 0.77532E-02 -2.1105 0.83365E+00 -0.0790 89 HPO3-2 0.70921E-15 -15.1492 0.36745E-15 -15.4348 0.51811E+00 -0.2856 91 H2PO3- 0.65748E-19 -19.1821 0.54910E-19 -19.2603 0.83516E+00 -0.0782 92 H3PO4,aq 0.91405E-18 -18.0390 0.91405E-18 -18.0390 0.10000E+01 0.0000 93 H2PO4- 0.38701E-10 -10.4123 0.32352E-10 -10.4901 0.83595E+00 -0.0778 94 PO4-3 0.10623E-08 -8.9738 0.25766E-09 -9.5890 0.24255E+00 -0.6152 98 HP2O7-3 0.95126E-18 -18.0217 0.21990E-18 -18.6578 0.23116E+00 -0.6361 99 P2O7-4 0.91490E-17 -17.0386 0.70494E-18 -18.1518 0.77051E-01 -1.1132 100 H2S,aq 0.68915E-08 -8.1617 0.68676E-08 -8.1632 0.99654E+00 -0.0015 101 S2-2 0.75895E-14 -14.1198 0.39322E-14 -14.4054 0.51811E+00 -0.2856 107 SO3-2 0.16583E-16 -16.7803 0.87162E-17 -17.0597 0.52561E+00 -0.2793 108 HSO3- 0.48696E-19 -19.3125 0.40669E-19 -19.3907 0.83516E+00 -0.0782 109 HSO4- 0.11479E-17 -17.9401 0.96143E-18 -18.0171 0.83757E+00 -0.0770 Charge balance for all species = -.6133E-08 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.8869271E-10 -.2226712E-01 -.2240490E+02 0.0000 2 H2O 0.1000000E+01 0.5550484E+02 0.9981979E+06 0.0000 3 Cl- 0.1545997E-03 0.1553096E-03 0.5496618E+01 6.2387 4 SO4-- 0.2578376E-10 -.1525144E-04 -.1462530E+01 9.3821 5 HCO3- 0.7706734E-05 0.3629048E-04 0.2210494E+01 4.9370 6 HS- 0.3569838E-04 0.5095674E-04 0.1682311E+01 5.6022 7 Al+++ 0.9748196E-29 0.5251415E-05 0.1414447E+00 0.7356 8 H4SiO4 0.6988439E-03 0.1353233E-01 0.1298404E+04 -3.1556 9 Ca++ 0.1235285E-06 0.2175284E-06 0.8702944E-02 13.0594 10 Mg++ 0.2113327E-10 0.9318237E-10 0.2261511E-05 9.2906 11 Fe++ 0.4594456E-13 0.2842995E-07 0.1584967E-02 6.6283 12 K+ 0.1565101E-03 0.1572607E-03 0.6138516E+01 6.2448 13 Na+ 0.1986096E-01 0.2230598E-01 0.5119185E+03 8.3474 14 Mn++ 0.1870081E-10 0.2507562E-08 0.1375209E-03 9.2383 15 F- 0.2308632E-06 0.2316106E-06 0.4392488E-02 3.4119 16 HPO4-- 0.4531935E-07 0.4642032E-07 0.4447629E-02 12.6271 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.1999747E-01 -.1999719E-01 -.2743554E-06 0.0000000E+00 2 H2O 0.4984663E+02 0.4984663E+02 -.2349080E-06 0.0000000E+00 3 Cl- 0.1394772E-03 0.1394772E-03 0.0000000E+00 0.0000000E+00 4 SO4-- -.1369581E-04 -.1369669E-04 0.8825618E-09 0.0000000E+00 5 HCO3- 0.3259100E-04 0.3259100E-04 0.0000000E+00 0.0000000E+00 6 HS- 0.4576128E-04 0.4576216E-04 -.8825618E-09 0.0000000E+00 7 Al+++ 0.4775352E-05 0.4716081E-05 0.5927072E-07 0.0000000E+00 8 H4SiO4 0.1215302E-01 0.1215283E-01 0.1862635E-06 0.0000000E+00 9 Ca++ 0.2080835E-06 0.1953533E-06 0.1273018E-07 0.0000000E+00 10 Mg++ 0.8368328E-10 0.8368328E-10 0.0000000E+00 0.0000000E+00 11 Fe++ 0.3259227E-07 0.2553178E-07 0.7060494E-08 0.0000000E+00 12 K+ 0.1412294E-03 0.1412294E-03 0.0000000E+00 0.0000000E+00 13 Na+ 0.2003215E-01 0.2003209E-01 0.5784443E-07 0.0000000E+00 14 Mn++ 0.2251939E-08 0.2251939E-08 0.0000000E+00 0.0000000E+00 15 F- 0.2080000E-06 0.2080000E-06 0.0000000E+00 0.0000000E+00 16 HPO4-- 0.4168819E-07 0.4168819E-07 0.0000000E+00 0.0000000E+00 Chg. balance for solid moles: 0.6617E-23 Mass of aqueous solution: 0.899623E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 0.0002700 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 0.5784E-07 -7.238 0.1517E-04 -4.819 87.76 0.5823E-05 andradite 0.3530E-08 -8.452 0.1794E-05 -5.746 10.38 0.4661E-06 grossular 0.7131E-09 -9.147 0.3212E-06 -6.493 1.859 0.8938E-07 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8319E+00 0.8319E+00 1.0000 -0.080 grossular 0.1681E+00 0.1681E+00 1.0000 -0.775 Solid products produced: Mass = 0.000017 g Volume = 0.000006 cm3 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.0002700 moles log = -3.5686 Original solution: 1000.0103000 g Original solution / Rock added: 3703741.85 (Water/Rock Ratio), log = 6.5686 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0475 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9744E+00 0.9856 0.1006E+01 0.1021E+01 CO2,gas 0.1041E-06 1.0069 0.1098E-06 0.1091E-06 CH4,gas 0.1936E-01 1.0123 0.2053E-01 0.2028E-01 H2,gas 0.6276E-02 1.0006 0.6578E-02 0.6574E-02 H2S,gas 0.1810E-06 0.9959 0.1888E-06 0.1896E-06 S2,gas 0.2952E-28 1.0000 0.3092E-28 0.3092E-28 CO,gas 0.1838E-12 1.0000 0.1925E-12 0.1925E-12 SO3,gas 0.2683E-46 1.0000 0.2811E-46 0.2811E-46 SO2,gas 0.6867E-26 1.0000 0.7194E-26 0.7194E-26 HF,gas 0.2301E-15 1.0000 0.2410E-15 0.2410E-15 HCl,gas 0.2970E-17 1.0000 0.3111E-17 0.3111E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 17 albite -0.38 -0.38 0.00 0.000 -0.13080E-10 23 andradite 39.01 39.01 0.00 0.000 0.00000E+00 24 grossular 32.73 32.73 0.00 0.000 0.24265E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -15.32 -8.66 -2.886 0.14784E+05 -6.959 3 CH4,gas 4.54 1.16 -3.39 -0.847 0.57826E+04 -1.688 4 H2,gas 8.00 4.12 -3.88 -2.218 0.66265E+04 -2.182 5 H2S,gas -6.23 -14.65 -8.42 -4.212 0.14382E+05 -6.724 6 S2,gas -7.34 -37.54 -30.21 -4.648 0.51581E+05 -28.510 7 CO,gas 3.21 -11.20 -14.41 -4.435 0.24612E+05 -12.716 8 SO3,gas 17.12 -31.13 -48.25 -12.063 0.82386E+05 -46.551 9 SO2,gas 0.83 -27.01 -27.84 -7.425 0.47539E+05 -26.143 10 HF,gas 0.47 -16.84 -17.32 -8.658 0.29568E+05 -15.618 11 HCl,gas 5.19 -14.02 -19.21 -9.603 0.32794E+05 -17.507 12 acmite 7.71 6.61 -1.10 -0.115 0.18862E+04 16 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 20 spessartine 24.46 19.72 -4.74 -0.237 0.80903E+04 21 analcite 3.32 2.77 -0.55 -0.061 0.93930E+03 27 annite 20.12 17.40 -2.72 -0.151 0.46528E+04 28 phlogopite 27.06 25.39 -1.68 -0.093 0.28676E+04 30 anorthite 12.71 8.22 -4.49 -0.345 0.76683E+04 33 apatite-OH -18.15 -18.35 -0.20 -0.015 0.34321E+03 34 apatite-F -34.30 -35.20 -0.90 -0.075 0.15316E+04 38 aragonite 0.97 -2.26 -3.23 -1.075 0.55076E+04 39 brucite 12.57 9.29 -3.28 -0.656 0.55971E+04 40 calcite 0.81 -2.26 -3.07 -1.024 0.52434E+04 41 carnegieite-low 9.02 5.93 -3.10 -0.442 0.52862E+04 42 carnegieite-high 10.09 5.93 -4.17 -0.595 0.71132E+04 43 carpholite-Mg 8.58 4.45 -4.13 -0.275 0.70546E+04 44 carpholite-Fe 6.71 1.79 -4.92 -0.328 0.84083E+04 45 celadonite 5.34 3.65 -1.69 -0.100 0.28910E+04 46 celadonite-Fe 3.88 0.99 -2.89 -0.170 0.49352E+04 47 chrysotile 23.89 21.56 -2.33 -0.194 0.39817E+04 49 clinochlore 39.07 38.46 -0.61 -0.019 0.10457E+04 50 daphnite 28.97 25.15 -3.82 -0.119 0.65216E+04 52 chlorite-Al-free 47.17 43.12 -4.05 -0.169 0.69186E+04 54 chloritoid-Fe 9.17 4.94 -4.23 -0.282 0.72222E+04 55 chloritoid-Mn 11.40 7.55 -3.85 -0.256 0.65691E+04 57 coesite -2.38 -3.16 -0.78 -0.260 0.13311E+04 64 cristobalite -2.56 -3.16 -0.60 -0.198 0.10164E+04 66 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71234E+04 68 diaspore 2.87 0.74 -2.14 -0.356 0.36508E+04 69 diamond -3.10 -7.08 -3.98 -1.137 0.67928E+04 70 diopside 16.18 16.04 -0.14 -0.014 0.24363E+03 71 hedenbergite 14.21 13.38 -0.83 -0.083 0.14204E+04 74 enstatite 17.26 12.27 -5.00 -0.500 0.85289E+04 76 clinoenstatite 17.17 12.27 -4.90 -0.490 0.83605E+04 78 epidote 24.67 22.69 -1.98 -0.096 0.33775E+04 79 clinozoisite 22.81 18.86 -3.95 -0.179 0.67402E+04 80 epidote-Fe 29.84 26.53 -3.32 -0.172 0.56614E+04 81 fayalite 14.05 10.10 -3.94 -0.564 0.67355E+04 82 ferrosilite 11.15 6.95 -4.20 -0.420 0.71784E+04 86 gibbsite 4.08 0.74 -3.34 -0.478 0.57093E+04 87 glaucophane 22.97 20.79 -2.18 -0.059 0.37259E+04 88 glaucophane-Fe 17.28 12.81 -4.47 -0.121 0.76322E+04 89 graphite -3.55 -7.08 -3.53 -1.010 0.60351E+04 90 greenalite 16.14 13.57 -2.57 -0.214 0.43811E+04 93 hematite 12.57 9.14 -3.43 -0.416 0.58540E+04 94 heulandite -5.83 -7.56 -1.73 -0.079 0.29566E+04 98 jadeite 4.22 2.77 -1.44 -0.144 0.24648E+04 100 kalsilite 7.58 3.82 -3.76 -0.537 0.64187E+04 101 kaolinite -1.33 -4.84 -3.51 -0.319 0.59886E+04 104 laumontite 2.88 1.91 -0.98 -0.065 0.16654E+04 105 lawsonite 9.62 8.22 -1.40 -0.093 0.23850E+04 106 leucite 4.12 0.67 -3.45 -0.345 0.58904E+04 108 lizardite 23.24 21.56 -1.68 -0.140 0.28744E+04 110 magnetite 20.09 15.77 -4.32 -0.353 0.73786E+04 111 minnesotaite 10.39 7.26 -3.13 -0.184 0.53370E+04 115 manganosite 14.06 9.24 -4.82 -1.205 0.82297E+04 119 microcline -2.49 -2.49 0.00 0.000 0.22722E-01 123 muscovite 2.58 -1.02 -3.60 -0.212 0.61431E+04 124 paragonite 4.24 1.09 -3.15 -0.185 0.53822E+04 125 nepheline 8.34 5.93 -2.41 -0.345 0.41186E+04 131 periclase-Fe 11.63 6.63 -5.00 -1.250 0.85344E+04 137 phlogopite-Na 29.65 27.49 -2.16 -0.120 0.36863E+04 139 prehnite 19.37 18.12 -1.25 -0.073 0.21324E+04 140 prehnite-Fe 22.50 21.96 -0.54 -0.033 0.92472E+03 141 pumpellyite-Fe 46.27 43.61 -2.66 -0.059 0.45411E+04 142 pumpellyite-Mg 48.99 46.27 -2.72 -0.061 0.46490E+04 146 pyrrhotite -4.26 -8.02 -3.76 -1.255 0.64280E+04 147 pyrrhotiteFe0.875 -6.02 -9.36 -3.35 -1.231 0.57154E+04 148 pyroxmangite 7.40 6.08 -1.32 -0.263 0.22470E+04 149 pyrophyllite -6.18 -11.15 -4.98 -0.311 0.84956E+04 150 quartz -2.99 -3.16 -0.17 -0.055 0.28376E+03 155 rhodonite 7.45 6.08 -1.36 -0.273 0.23273E+04 156 sanidine -1.28 -2.49 -1.21 -0.093 0.20678E+04 166 stilbite -7.52 -7.56 -0.04 -0.002 0.62792E+02 167 stilpnomelane-Fe 13.02 12.49 -0.53 -0.016 0.89960E+03 168 stilpnomelane-Mg 27.44 25.80 -1.64 -0.049 0.28003E+04 174 talc 16.49 15.25 -1.24 -0.073 0.21205E+04 177 tephroite 18.09 15.32 -2.76 -0.395 0.47209E+04 181 tridymite -2.63 -3.16 -0.53 -0.176 0.90373E+03 182 tremolite 47.87 47.33 -0.54 -0.015 0.92664E+03 183 ferroactinolite 38.45 34.02 -4.44 -0.120 0.75762E+04 184 troilite-low -4.41 -8.02 -3.61 -1.205 0.61708E+04 190 wairakite 3.95 1.91 -2.04 -0.120 0.34874E+04 191 walstromite 11.51 9.90 -1.61 -0.321 0.27413E+04 192 wollastonite 10.46 9.90 -0.56 -0.111 0.95177E+03 193 pseudo-wollastonite 11.00 9.90 -1.10 -0.219 0.18716E+04 194 zoisite 22.85 18.86 -3.99 -0.181 0.68142E+04 195 akaganeite 7.75 4.57 -3.19 -0.689 0.54395E+04 202 chalcedony -2.80 -3.16 -0.35 -0.118 0.60305E+03 204 montmorillonite-Ca -2.29 -6.17 -3.88 -0.240 0.66295E+04 205 montmorillonite-K -2.24 -6.27 -4.03 -0.247 0.68823E+04 206 montmorillonite-Mg -2.48 -6.80 -4.32 -0.267 0.73684E+04 207 montmorillonite-Na -2.04 -5.57 -3.54 -0.217 0.60372E+04 208 nontronite-Ca 3.21 -0.05 -3.26 -0.212 0.55670E+04 209 nontronite-H 2.53 -2.20 -4.73 -0.317 0.80821E+04 210 nontronite-K 3.34 -0.14 -3.48 -0.223 0.59430E+04 211 nontronite-Mg 3.07 -0.67 -3.74 -0.243 0.63899E+04 212 nontronite-Na 3.52 0.55 -2.97 -0.190 0.50639E+04 228 tobermorite 9.82 7.72 -2.10 -0.573 0.35861E+04 234 alabandite -0.98 -5.41 -4.44 -1.479 0.75762E+04 237 boehmite 4.41 0.74 -3.67 -0.612 0.62677E+04 239 ferrous-oxide 9.81 6.63 -3.18 -0.796 0.54354E+04 245 silica-amorphous -2.09 -3.16 -1.06 -0.355 0.18172E+04 247 an20ab80 2.02 1.34 -0.68 -0.052 0.11628E+04 248 an25ab75 2.65 1.77 -0.88 -0.068 0.15005E+04 249 an30ab70 3.28 2.20 -1.08 -0.083 0.18478E+04 250 tr.625ac.25prg.125 45.16 44.95 -0.22 -0.006 0.37419E+03 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 0.0000100 MOLES Current total amount of reactant added: 0.0002700 MOLES New total amount of reactant added: 0.0002800 MOLES Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.5508E-08 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 6 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 0.0002800 Water: Moles liquid = 0.4985E+02 kg liquid = 0.8981E+00 Moles total = 0.4985E+02 kg total = 0.8980E+00 Activity = 1.0000 Stoichiometric ionic strength = .1134807E-01 Osmotic coef. = 0.9684 True ionic strength = .2003315E-01 Chg. balance for total moles = -.5508E-08 Max. difference allowed = 0.1395E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.88708E-10 -10.0520 0.74534E-10 -10.1276 0.84021E+00 -0.0756 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.15467E-03 -3.8106 0.12917E-03 -3.8888 0.83516E+00 -0.0782 4 SO4-- 0.27046E-10 -10.5679 0.14042E-10 -10.8526 0.51921E+00 -0.2847 5 HCO3- 0.79999E-05 -5.0969 0.66910E-05 -5.1745 0.83638E+00 -0.0776 6 HS- 0.35969E-04 -4.4441 0.30044E-04 -4.5222 0.83528E+00 -0.0782 7 Al+++ 0.97504E-29 -29.0110 0.22517E-29 -29.6475 0.23093E+00 -0.6365 8 H4SiO4 0.69896E-03 -3.1555 0.69896E-03 -3.1555 0.10000E+01 0.0000 9 Ca++ 0.12335E-06 -6.9089 0.63574E-07 -7.1967 0.51539E+00 -0.2879 10 Mg++ 0.21134E-10 -10.6750 0.10842E-10 -10.9649 0.51304E+00 -0.2899 11 Fe++ 0.45868E-13 -13.3385 0.23558E-13 -13.6279 0.51360E+00 -0.2894 12 K+ 0.15651E-03 -3.8055 0.13093E-03 -3.8830 0.83658E+00 -0.0775 13 Na+ 0.19861E-01 -1.7020 0.16584E-01 -1.7803 0.83501E+00 -0.0783 14 Mn++ 0.18707E-10 -10.7280 0.96159E-11 -11.0170 0.51402E+00 -0.2890 15 F- 0.23530E-06 -6.6284 0.19611E-06 -6.7075 0.83344E+00 -0.0791 16 HPO4-- 0.45320E-07 -7.3437 0.23534E-07 -7.6283 0.51928E+00 -0.2846 18 HSiO3- 0.10485E-01 -1.9794 0.87564E-02 -2.0577 0.83516E+00 -0.0782 19 Ca(HSiO3)+ 0.15151E-07 -7.8196 0.12678E-07 -7.8970 0.83676E+00 -0.0774 20 Mg(HSiO3)+ 0.32158E-11 -11.4927 0.26908E-11 -11.5701 0.83676E+00 -0.0774 21 NaHSiO3,aq 0.23487E-02 -2.6292 0.23487E-02 -2.6292 0.10000E+01 0.0000 22 AlO+ 0.65898E-16 -16.1811 0.55141E-16 -16.2585 0.83676E+00 -0.0774 24 HAlO2,aq 0.14733E-09 -9.8317 0.14733E-09 -9.8317 0.10000E+01 0.0000 25 AlO2- 0.52487E-05 -5.2799 0.43756E-05 -5.3590 0.83365E+00 -0.0790 26 CH4,aq 0.13954E-04 -4.8553 0.13906E-04 -4.8568 0.99654E+00 -0.0015 27 C2H6,aq 0.66881E-14 -14.1747 0.66650E-14 -14.1762 0.99654E+00 -0.0015 31 CO,aq 0.13277E-15 -15.8769 0.13277E-15 -15.8769 0.10000E+01 0.0000 32 CO2,aq 0.10693E-08 -8.9709 0.10656E-08 -8.9724 0.99654E+00 -0.0015 33 CO3-2 0.15134E-04 -4.8200 0.78411E-05 -5.1056 0.51810E+00 -0.2856 34 CaCO3,aq 0.62505E-08 -8.2041 0.62505E-08 -8.2041 0.10000E+01 0.0000 35 Ca(HCO3)+ 0.12976E-10 -10.8869 0.10858E-10 -10.9643 0.83676E+00 -0.0774 36 CaCl+ 0.15882E-10 -10.7991 0.13289E-10 -10.8765 0.83676E+00 -0.0774 37 CaCl2,aq 0.40782E-15 -15.3895 0.40782E-15 -15.3895 0.10000E+01 0.0000 38 CaF+ 0.21754E-12 -12.6625 0.18203E-12 -12.7399 0.83676E+00 -0.0774 39 CaOH+ 0.72648E-07 -7.1388 0.60789E-07 -7.2162 0.83676E+00 -0.0774 40 CaSO4,aq 0.28348E-15 -15.5475 0.28348E-15 -15.5475 0.10000E+01 0.0000 41 HCl,aq 0.17642E-14 -14.7535 0.17642E-14 -14.7535 0.10000E+01 0.0000 45 HF,aq 0.10006E-12 -12.9997 0.10006E-12 -12.9997 0.10000E+01 0.0000 48 FeCl+ 0.57561E-17 -17.2399 0.48165E-17 -17.3173 0.83676E+00 -0.0774 51 FeF+ 0.28214E-18 -18.5495 0.23608E-18 -18.6269 0.83676E+00 -0.0774 53 FeO,aq 0.16481E-09 -9.7830 0.16481E-09 -9.7830 0.10000E+01 0.0000 54 FeOH+ 0.12295E-10 -10.9103 0.10288E-10 -10.9877 0.83676E+00 -0.0774 55 HFeO2- 0.27703E-07 -7.5575 0.23136E-07 -7.6357 0.83516E+00 -0.0782 56 FeO+ 0.13168E-16 -16.8805 0.11019E-16 -16.9579 0.83676E+00 -0.0774 58 FeO2- 0.48596E-09 -9.3134 0.40586E-09 -9.3916 0.83516E+00 -0.0782 59 HFeO2,aq 0.38473E-11 -11.4148 0.38473E-11 -11.4148 0.10000E+01 0.0000 60 H2,aq 0.49771E-05 -5.3030 0.49599E-05 -5.3045 0.99654E+00 -0.0015 61 KCl,aq 0.30653E-09 -9.5135 0.30653E-09 -9.5135 0.10000E+01 0.0000 63 KOH,aq 0.75021E-06 -6.1248 0.75021E-06 -6.1248 0.10000E+01 0.0000 64 KSO4- 0.34162E-13 -13.4665 0.28531E-13 -13.5447 0.83516E+00 -0.0782 65 MgCO3,aq 0.26720E-12 -12.5732 0.26720E-12 -12.5732 0.10000E+01 0.0000 66 Mg(HCO3)+ 0.22614E-14 -14.6456 0.18922E-14 -14.7230 0.83676E+00 -0.0774 67 MgCl+ 0.24549E-14 -14.6100 0.20542E-14 -14.6874 0.83676E+00 -0.0774 68 MgF+ 0.13743E-15 -15.8619 0.11500E-15 -15.9393 0.83676E+00 -0.0774 69 MgOH+ 0.68561E-10 -10.1639 0.57369E-10 -10.2413 0.83676E+00 -0.0774 71 MnF+ 0.37960E-16 -16.4207 0.31763E-16 -16.4981 0.83676E+00 -0.0774 72 MnO,aq 0.17926E-08 -8.7465 0.17926E-08 -8.7465 0.10000E+01 0.0000 73 MnOH+ 0.46623E-09 -9.3314 0.39012E-09 -9.4088 0.83676E+00 -0.0774 74 MnO2-2 0.20669E-10 -10.6847 0.10709E-10 -10.9703 0.51810E+00 -0.2856 75 HMnO2- 0.20938E-09 -9.6791 0.17487E-09 -9.7573 0.83516E+00 -0.0782 78 MnCl+ 0.91408E-14 -14.0390 0.76487E-14 -14.1164 0.83676E+00 -0.0774 79 MnSO4,aq 0.38982E-19 -19.4091 0.38982E-19 -19.4091 0.10000E+01 0.0000 80 NaCl,aq 0.70992E-06 -6.1488 0.70992E-06 -6.1488 0.10000E+01 0.0000 81 NaF,aq 0.76142E-09 -9.1184 0.76142E-09 -9.1184 0.10000E+01 0.0000 82 NaOH,aq 0.95598E-04 -4.0195 0.95598E-04 -4.0195 0.10000E+01 0.0000 84 OH- 0.92987E-02 -2.0316 0.77518E-02 -2.1106 0.83365E+00 -0.0790 89 HPO3-2 0.70208E-15 -15.1536 0.36375E-15 -15.4392 0.51810E+00 -0.2856 91 H2PO3- 0.65099E-19 -19.1864 0.54368E-19 -19.2647 0.83516E+00 -0.0782 92 H3PO4,aq 0.91436E-18 -18.0389 0.91436E-18 -18.0389 0.10000E+01 0.0000 93 H2PO4- 0.38707E-10 -10.4122 0.32357E-10 -10.4900 0.83595E+00 -0.0778 94 PO4-3 0.10621E-08 -8.9738 0.25761E-09 -9.5890 0.24255E+00 -0.6152 98 HP2O7-3 0.95143E-18 -18.0216 0.21993E-18 -18.6577 0.23116E+00 -0.6361 99 P2O7-4 0.91492E-17 -17.0386 0.70493E-18 -18.1519 0.77049E-01 -1.1132 100 H2S,aq 0.69449E-08 -8.1583 0.69208E-08 -8.1598 0.99654E+00 -0.0015 101 S2-2 0.77832E-14 -14.1088 0.40325E-14 -14.3944 0.51810E+00 -0.2856 107 SO3-2 0.17220E-16 -16.7640 0.90509E-17 -17.0433 0.52560E+00 -0.2793 108 HSO3- 0.50575E-19 -19.2961 0.42238E-19 -19.3743 0.83516E+00 -0.0782 109 HSO4- 0.12043E-17 -17.9193 0.10087E-17 -17.9963 0.83757E+00 -0.0770 Charge balance for all species = -.6133E-08 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.8870833E-10 -.2226591E-01 -.2240368E+02 0.0000 2 H2O 0.1000000E+01 0.5550484E+02 0.9981978E+06 0.0000 3 Cl- 0.1546650E-03 0.1553753E-03 0.5498942E+01 6.2388 4 SO4-- 0.2704585E-10 -.1519827E-04 -.1457432E+01 9.4027 5 HCO3- 0.7999904E-05 0.3709555E-04 0.2259531E+01 4.9531 6 HS- 0.3596890E-04 0.5117415E-04 0.1689489E+01 5.6054 7 Al+++ 0.9750395E-29 0.5248859E-05 0.1413759E+00 0.7354 8 H4SiO4 0.6989578E-03 0.1353232E-01 0.1298403E+04 -3.1555 9 Ca++ 0.1233495E-06 0.2174283E-06 0.8698940E-02 13.0586 10 Mg++ 0.2113385E-10 0.9318236E-10 0.2261511E-05 9.2904 11 Fe++ 0.4586792E-13 0.2837003E-07 0.1581626E-02 6.6274 12 K+ 0.1565102E-03 0.1572607E-03 0.6138515E+01 6.2447 13 Na+ 0.1986100E-01 0.2230598E-01 0.5119183E+03 8.3473 14 Mn++ 0.1870713E-10 0.2507562E-08 0.1375209E-03 9.2383 15 F- 0.2353029E-06 0.2360646E-06 0.4476958E-02 3.4201 16 HPO4-- 0.4531950E-07 0.4642031E-07 0.4447628E-02 12.6270 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.1999639E-01 -.1999611E-01 -.2838083E-06 0.0000000E+00 2 H2O 0.4984664E+02 0.4984664E+02 -.2440890E-06 0.0000000E+00 3 Cl- 0.1395362E-03 0.1395362E-03 0.0000000E+00 0.0000000E+00 4 SO4-- -.1364806E-04 -.1364895E-04 0.8892877E-09 0.0000000E+00 5 HCO3- 0.3331400E-04 0.3331400E-04 0.0000000E+00 0.0000000E+00 6 HS- 0.4595653E-04 0.4595742E-04 -.8892877E-09 0.0000000E+00 7 Al+++ 0.4775352E-05 0.4713787E-05 0.6156533E-07 0.0000000E+00 8 H4SiO4 0.1215302E-01 0.1215283E-01 0.1932189E-06 0.0000000E+00 9 Ca++ 0.2080835E-06 0.1952635E-06 0.1282001E-07 0.0000000E+00 10 Mg++ 0.8368328E-10 0.8368328E-10 0.0000000E+00 0.0000000E+00 11 Fe++ 0.3259227E-07 0.2547797E-07 0.7114302E-08 0.0000000E+00 12 K+ 0.1412294E-03 0.1412294E-03 0.0000000E+00 0.0000000E+00 13 Na+ 0.2003215E-01 0.2003209E-01 0.6013296E-07 0.0000000E+00 14 Mn++ 0.2251939E-08 0.2251939E-08 0.0000000E+00 0.0000000E+00 15 F- 0.2120000E-06 0.2120000E-06 0.0000000E+00 0.0000000E+00 16 HPO4-- 0.4168819E-07 0.4168819E-07 0.0000000E+00 0.0000000E+00 Chg. balance for solid moles: -.5294E-22 Mass of aqueous solution: 0.899623E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 0.0002800 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 0.6013E-07 -7.221 0.1577E-04 -4.802 88.10 0.6053E-05 andradite 0.3557E-08 -8.449 0.1808E-05 -5.743 10.10 0.4696E-06 grossular 0.7162E-09 -9.145 0.3226E-06 -6.491 1.802 0.8976E-07 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8324E+00 0.8324E+00 1.0000 -0.080 grossular 0.1676E+00 0.1676E+00 1.0000 -0.776 Solid products produced: Mass = 0.000018 g Volume = 0.000007 cm3 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.0002800 moles log = -3.5528 Original solution: 1000.0103000 g Original solution / Rock added: 3571465.36 (Water/Rock Ratio), log = 6.5528 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0474 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9745E+00 0.9856 0.1006E+01 0.1021E+01 CO2,gas 0.1081E-06 1.0069 0.1140E-06 0.1132E-06 CH4,gas 0.1930E-01 1.0123 0.2047E-01 0.2022E-01 H2,gas 0.6214E-02 1.0006 0.6512E-02 0.6508E-02 H2S,gas 0.1824E-06 0.9959 0.1902E-06 0.1910E-06 S2,gas 0.3059E-28 1.0000 0.3204E-28 0.3204E-28 CO,gas 0.1889E-12 1.0000 0.1979E-12 0.1979E-12 SO3,gas 0.2816E-46 1.0000 0.2950E-46 0.2950E-46 SO2,gas 0.7134E-26 1.0000 0.7472E-26 0.7472E-26 HF,gas 0.2346E-15 1.0000 0.2457E-15 0.2457E-15 HCl,gas 0.2972E-17 1.0000 0.3113E-17 0.3113E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 17 albite -0.38 -0.38 0.00 0.000 -0.94784E-12 23 andradite 39.01 39.01 0.00 0.000 -0.12132E-10 24 grossular 32.73 32.73 0.00 0.000 0.12132E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -15.30 -8.64 -2.881 0.14756E+05 -6.943 3 CH4,gas 4.54 1.16 -3.39 -0.847 0.57847E+04 -1.689 4 H2,gas 8.00 4.11 -3.89 -2.220 0.66340E+04 -2.186 5 H2S,gas -6.23 -14.65 -8.42 -4.210 0.14376E+05 -6.721 6 S2,gas -7.34 -37.53 -30.19 -4.645 0.51554E+05 -28.494 7 CO,gas 3.21 -11.19 -14.40 -4.432 0.24592E+05 -12.704 8 SO3,gas 17.12 -31.11 -48.23 -12.057 0.82350E+05 -46.530 9 SO2,gas 0.83 -26.99 -27.83 -7.420 0.47511E+05 -26.127 10 HF,gas 0.47 -16.84 -17.31 -8.654 0.29554E+05 -15.610 11 HCl,gas 5.19 -14.02 -19.21 -9.603 0.32793E+05 -17.507 12 acmite 7.71 6.61 -1.10 -0.115 0.18838E+04 16 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 20 spessartine 24.46 19.72 -4.74 -0.237 0.80904E+04 21 analcite 3.32 2.77 -0.55 -0.061 0.93942E+03 27 annite 20.12 17.40 -2.73 -0.152 0.46574E+04 28 phlogopite 27.06 25.38 -1.68 -0.093 0.28683E+04 30 anorthite 12.71 8.22 -4.49 -0.346 0.76699E+04 33 apatite-OH -18.15 -18.36 -0.20 -0.016 0.34914E+03 34 apatite-F -34.30 -35.19 -0.89 -0.074 0.15233E+04 38 aragonite 0.97 -2.24 -3.21 -1.070 0.54812E+04 39 brucite 12.57 9.29 -3.28 -0.656 0.55973E+04 40 calcite 0.81 -2.24 -3.06 -1.018 0.52170E+04 41 carnegieite-low 9.02 5.93 -3.10 -0.442 0.52864E+04 42 carnegieite-high 10.09 5.93 -4.17 -0.595 0.71134E+04 43 carpholite-Mg 8.58 4.45 -4.13 -0.275 0.70551E+04 44 carpholite-Fe 6.71 1.79 -4.93 -0.328 0.84100E+04 45 celadonite 5.34 3.65 -1.69 -0.100 0.28912E+04 46 celadonite-Fe 3.88 0.99 -2.89 -0.170 0.49366E+04 47 chrysotile 23.89 21.56 -2.33 -0.194 0.39822E+04 49 clinochlore 39.07 38.46 -0.61 -0.019 0.10470E+04 50 daphnite 28.97 25.14 -3.82 -0.119 0.65292E+04 52 chlorite-Al-free 47.17 43.12 -4.05 -0.169 0.69196E+04 54 chloritoid-Fe 9.17 4.94 -4.23 -0.282 0.72241E+04 55 chloritoid-Mn 11.40 7.55 -3.85 -0.256 0.65694E+04 57 coesite -2.38 -3.16 -0.78 -0.260 0.13310E+04 64 cristobalite -2.56 -3.16 -0.60 -0.198 0.10163E+04 66 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71234E+04 68 diaspore 2.87 0.74 -2.14 -0.356 0.36510E+04 69 diamond -3.10 -7.07 -3.97 -1.135 0.67800E+04 70 diopside 16.18 16.04 -0.14 -0.014 0.24497E+03 71 hedenbergite 14.21 13.37 -0.83 -0.083 0.14230E+04 74 enstatite 17.26 12.27 -5.00 -0.500 0.85291E+04 76 clinoenstatite 17.17 12.27 -4.90 -0.490 0.83607E+04 78 epidote 24.67 22.69 -1.98 -0.096 0.33780E+04 79 clinozoisite 22.81 18.86 -3.95 -0.180 0.67432E+04 80 epidote-Fe 29.84 26.53 -3.31 -0.172 0.56594E+04 81 fayalite 14.05 10.10 -3.95 -0.564 0.67384E+04 82 ferrosilite 11.15 6.94 -4.21 -0.421 0.71811E+04 86 gibbsite 4.08 0.74 -3.34 -0.478 0.57096E+04 87 glaucophane 22.97 20.79 -2.18 -0.059 0.37264E+04 88 glaucophane-Fe 17.28 12.80 -4.47 -0.121 0.76365E+04 89 graphite -3.55 -7.07 -3.53 -1.008 0.60223E+04 90 greenalite 16.14 13.57 -2.57 -0.214 0.43854E+04 93 hematite 12.57 9.14 -3.43 -0.415 0.58495E+04 94 heulandite -5.83 -7.56 -1.73 -0.079 0.29576E+04 98 jadeite 4.22 2.77 -1.44 -0.144 0.24649E+04 100 kalsilite 7.58 3.82 -3.76 -0.537 0.64189E+04 101 kaolinite -1.33 -4.84 -3.51 -0.319 0.59889E+04 104 laumontite 2.88 1.91 -0.98 -0.065 0.16668E+04 105 lawsonite 9.62 8.22 -1.40 -0.093 0.23866E+04 106 leucite 4.12 0.67 -3.45 -0.345 0.58905E+04 108 lizardite 23.24 21.56 -1.68 -0.140 0.28748E+04 110 magnetite 20.09 15.77 -4.32 -0.353 0.73756E+04 111 minnesotaite 10.39 7.26 -3.13 -0.184 0.53410E+04 115 manganosite 14.06 9.24 -4.82 -1.205 0.82297E+04 119 microcline -2.49 -2.49 0.00 0.000 0.23561E-01 123 muscovite 2.58 -1.02 -3.60 -0.212 0.61436E+04 124 paragonite 4.24 1.09 -3.15 -0.185 0.53827E+04 125 nepheline 8.34 5.93 -2.41 -0.345 0.41188E+04 131 periclase-Fe 11.63 6.63 -5.00 -1.250 0.85359E+04 137 phlogopite-Na 29.65 27.49 -2.16 -0.120 0.36871E+04 139 prehnite 19.37 18.12 -1.25 -0.074 0.21352E+04 140 prehnite-Fe 22.50 21.96 -0.54 -0.033 0.92502E+03 141 pumpellyite-Fe 46.27 43.61 -2.66 -0.059 0.45484E+04 142 pumpellyite-Mg 48.99 46.27 -2.73 -0.061 0.46550E+04 146 pyrrhotite -4.26 -8.02 -3.76 -1.254 0.64238E+04 147 pyrrhotiteFe0.875 -6.02 -9.36 -3.34 -1.230 0.57100E+04 148 pyroxmangite 7.40 6.08 -1.32 -0.263 0.22469E+04 149 pyrophyllite -6.18 -11.15 -4.98 -0.311 0.84956E+04 150 quartz -2.99 -3.16 -0.17 -0.055 0.28363E+03 155 rhodonite 7.45 6.08 -1.36 -0.273 0.23272E+04 156 sanidine -1.28 -2.49 -1.21 -0.093 0.20678E+04 166 stilbite -7.52 -7.56 -0.04 -0.002 0.63751E+02 167 stilpnomelane-Fe 13.02 12.49 -0.53 -0.016 0.90668E+03 168 stilpnomelane-Mg 27.44 25.80 -1.64 -0.049 0.28011E+04 174 talc 16.49 15.25 -1.24 -0.073 0.21207E+04 177 tephroite 18.09 15.32 -2.76 -0.395 0.47208E+04 181 tridymite -2.63 -3.16 -0.53 -0.176 0.90361E+03 182 tremolite 47.87 47.32 -0.54 -0.015 0.92957E+03 183 ferroactinolite 38.45 34.01 -4.44 -0.120 0.75854E+04 184 troilite-low -4.41 -8.02 -3.61 -1.204 0.61666E+04 190 wairakite 3.95 1.91 -2.04 -0.120 0.34887E+04 191 walstromite 11.51 9.90 -1.61 -0.321 0.27426E+04 192 wollastonite 10.46 9.90 -0.56 -0.112 0.95299E+03 193 pseudo-wollastonite 11.00 9.90 -1.10 -0.219 0.18728E+04 194 zoisite 22.85 18.86 -3.99 -0.181 0.68172E+04 195 akaganeite 7.75 4.57 -3.18 -0.689 0.54373E+04 202 chalcedony -2.80 -3.16 -0.35 -0.118 0.60293E+03 204 montmorillonite-Ca -2.29 -6.17 -3.88 -0.240 0.66298E+04 205 montmorillonite-K -2.24 -6.27 -4.03 -0.247 0.68823E+04 206 montmorillonite-Mg -2.48 -6.80 -4.32 -0.267 0.73684E+04 207 montmorillonite-Na -2.04 -5.57 -3.54 -0.217 0.60372E+04 208 nontronite-Ca 3.21 -0.04 -3.26 -0.211 0.55624E+04 209 nontronite-H 2.53 -2.20 -4.73 -0.317 0.80772E+04 210 nontronite-K 3.34 -0.14 -3.48 -0.223 0.59382E+04 211 nontronite-Mg 3.07 -0.66 -3.74 -0.243 0.63851E+04 212 nontronite-Na 3.52 0.56 -2.96 -0.190 0.50590E+04 228 tobermorite 9.82 7.72 -2.10 -0.573 0.35871E+04 234 alabandite -0.98 -5.41 -4.43 -1.478 0.75705E+04 237 boehmite 4.41 0.74 -3.67 -0.612 0.62679E+04 239 ferrous-oxide 9.81 6.63 -3.18 -0.796 0.54369E+04 245 silica-amorphous -2.09 -3.16 -1.06 -0.355 0.18171E+04 247 an20ab80 2.02 1.34 -0.68 -0.052 0.11631E+04 248 an25ab75 2.65 1.77 -0.88 -0.068 0.15009E+04 249 an30ab70 3.28 2.20 -1.08 -0.083 0.18482E+04 250 tr.625ac.25prg.125 45.16 44.94 -0.22 -0.006 0.37880E+03 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 0.0000100 MOLES Current total amount of reactant added: 0.0002800 MOLES New total amount of reactant added: 0.0002900 MOLES Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.5508E-08 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 6 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 0.0002900 Water: Moles liquid = 0.4985E+02 kg liquid = 0.8981E+00 Moles total = 0.4985E+02 kg total = 0.8980E+00 Activity = 1.0000 Stoichiometric ionic strength = .1134871E-01 Osmotic coef. = 0.9684 True ionic strength = .2003374E-01 Chg. balance for total moles = -.5508E-08 Max. difference allowed = 0.1396E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.88724E-10 -10.0520 0.74547E-10 -10.1276 0.84021E+00 -0.0756 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.15473E-03 -3.8104 0.12922E-03 -3.8887 0.83516E+00 -0.0782 4 SO4-- 0.28332E-10 -10.5477 0.14710E-10 -10.8324 0.51920E+00 -0.2847 5 HCO3- 0.82933E-05 -5.0813 0.69364E-05 -5.1589 0.83638E+00 -0.0776 6 HS- 0.36239E-04 -4.4408 0.30270E-04 -4.5190 0.83528E+00 -0.0782 7 Al+++ 0.97526E-29 -29.0109 0.22521E-29 -29.6474 0.23093E+00 -0.6365 8 H4SiO4 0.69907E-03 -3.1555 0.69907E-03 -3.1555 0.10000E+01 0.0000 9 Ca++ 0.12317E-06 -6.9095 0.63483E-07 -7.1973 0.51539E+00 -0.2879 10 Mg++ 0.21134E-10 -10.6750 0.10843E-10 -10.9649 0.51303E+00 -0.2899 11 Fe++ 0.45796E-13 -13.3392 0.23521E-13 -13.6285 0.51359E+00 -0.2894 12 K+ 0.15651E-03 -3.8055 0.13093E-03 -3.8830 0.83658E+00 -0.0775 13 Na+ 0.19861E-01 -1.7020 0.16584E-01 -1.7803 0.83500E+00 -0.0783 14 Mn++ 0.18713E-10 -10.7278 0.96191E-11 -11.0169 0.51402E+00 -0.2890 15 F- 0.23974E-06 -6.6203 0.19981E-06 -6.6994 0.83343E+00 -0.0791 16 HPO4-- 0.45320E-07 -7.3437 0.23533E-07 -7.6283 0.51928E+00 -0.2846 18 HSiO3- 0.10485E-01 -1.9794 0.87563E-02 -2.0577 0.83516E+00 -0.0782 19 Ca(HSiO3)+ 0.15129E-07 -7.8202 0.12659E-07 -7.8976 0.83676E+00 -0.0774 20 Mg(HSiO3)+ 0.32158E-11 -11.4927 0.26908E-11 -11.5701 0.83676E+00 -0.0774 21 NaHSiO3,aq 0.23486E-02 -2.6292 0.23486E-02 -2.6292 0.10000E+01 0.0000 22 AlO+ 0.65889E-16 -16.1812 0.55133E-16 -16.2586 0.83676E+00 -0.0774 24 HAlO2,aq 0.14728E-09 -9.8318 0.14728E-09 -9.8318 0.10000E+01 0.0000 25 AlO2- 0.52462E-05 -5.2802 0.43734E-05 -5.3592 0.83365E+00 -0.0790 26 CH4,aq 0.13913E-04 -4.8566 0.13865E-04 -4.8581 0.99654E+00 -0.0015 27 C2H6,aq 0.67142E-14 -14.1730 0.66910E-14 -14.1745 0.99654E+00 -0.0015 31 CO,aq 0.13633E-15 -15.8654 0.13633E-15 -15.8654 0.10000E+01 0.0000 32 CO2,aq 0.11087E-08 -8.9552 0.11049E-08 -8.9567 0.99654E+00 -0.0015 33 CO3-2 0.15687E-04 -4.8045 0.81273E-05 -5.0901 0.51810E+00 -0.2856 34 CaCO3,aq 0.64693E-08 -8.1891 0.64693E-08 -8.1891 0.10000E+01 0.0000 35 Ca(HCO3)+ 0.13433E-10 -10.8718 0.11240E-10 -10.9492 0.83676E+00 -0.0774 36 CaCl+ 0.15866E-10 -10.7995 0.13276E-10 -10.8769 0.83676E+00 -0.0774 37 CaCl2,aq 0.40758E-15 -15.3898 0.40758E-15 -15.3898 0.10000E+01 0.0000 38 CaF+ 0.22132E-12 -12.6550 0.18519E-12 -12.7324 0.83676E+00 -0.0774 39 CaOH+ 0.72532E-07 -7.1395 0.60692E-07 -7.2169 0.83676E+00 -0.0774 40 CaSO4,aq 0.29654E-15 -15.5279 0.29654E-15 -15.5279 0.10000E+01 0.0000 41 HCl,aq 0.17653E-14 -14.7532 0.17653E-14 -14.7532 0.10000E+01 0.0000 45 HF,aq 0.10197E-12 -12.9915 0.10197E-12 -12.9915 0.10000E+01 0.0000 48 FeCl+ 0.57495E-17 -17.2404 0.48109E-17 -17.3178 0.83676E+00 -0.0774 51 FeF+ 0.28701E-18 -18.5421 0.24016E-18 -18.6195 0.83676E+00 -0.0774 53 FeO,aq 0.16450E-09 -9.7838 0.16450E-09 -9.7838 0.10000E+01 0.0000 54 FeOH+ 0.12274E-10 -10.9110 0.10270E-10 -10.9884 0.83676E+00 -0.0774 55 HFeO2- 0.27645E-07 -7.5584 0.23088E-07 -7.6366 0.83516E+00 -0.0782 56 FeO+ 0.13210E-16 -16.8791 0.11053E-16 -16.9565 0.83676E+00 -0.0774 58 FeO2- 0.48733E-09 -9.3122 0.40700E-09 -9.3904 0.83516E+00 -0.0782 59 HFeO2,aq 0.38588E-11 -11.4135 0.38588E-11 -11.4135 0.10000E+01 0.0000 60 H2,aq 0.49287E-05 -5.3073 0.49116E-05 -5.3088 0.99654E+00 -0.0015 61 KCl,aq 0.30666E-09 -9.5133 0.30666E-09 -9.5133 0.10000E+01 0.0000 63 KOH,aq 0.75008E-06 -6.1249 0.75008E-06 -6.1249 0.10000E+01 0.0000 64 KSO4- 0.35787E-13 -13.4463 0.29888E-13 -13.5245 0.83516E+00 -0.0782 65 MgCO3,aq 0.27696E-12 -12.5576 0.27696E-12 -12.5576 0.10000E+01 0.0000 66 Mg(HCO3)+ 0.23443E-14 -14.6300 0.19616E-14 -14.7074 0.83676E+00 -0.0774 67 MgCl+ 0.24560E-14 -14.6098 0.20551E-14 -14.6872 0.83676E+00 -0.0774 68 MgF+ 0.14003E-15 -15.8538 0.11717E-15 -15.9312 0.83676E+00 -0.0774 69 MgOH+ 0.68550E-10 -10.1640 0.57360E-10 -10.2414 0.83676E+00 -0.0774 71 MnF+ 0.38689E-16 -16.4124 0.32373E-16 -16.4898 0.83676E+00 -0.0774 72 MnO,aq 0.17925E-08 -8.7465 0.17925E-08 -8.7465 0.10000E+01 0.0000 73 MnOH+ 0.46630E-09 -9.3313 0.39018E-09 -9.4087 0.83676E+00 -0.0774 74 MnO2-2 0.20662E-10 -10.6848 0.10705E-10 -10.9704 0.51810E+00 -0.2856 75 HMnO2- 0.20934E-09 -9.6791 0.17483E-09 -9.7574 0.83516E+00 -0.0782 78 MnCl+ 0.91477E-14 -14.0387 0.76544E-14 -14.1161 0.83676E+00 -0.0774 79 MnSO4,aq 0.40849E-19 -19.3888 0.40849E-19 -19.3888 0.10000E+01 0.0000 80 NaCl,aq 0.71021E-06 -6.1486 0.71021E-06 -6.1486 0.10000E+01 0.0000 81 NaF,aq 0.77579E-09 -9.1103 0.77579E-09 -9.1103 0.10000E+01 0.0000 82 NaOH,aq 0.95582E-04 -4.0196 0.95582E-04 -4.0196 0.10000E+01 0.0000 84 OH- 0.92971E-02 -2.0317 0.77505E-02 -2.1107 0.83365E+00 -0.0790 89 HPO3-2 0.69525E-15 -15.1579 0.36021E-15 -15.4434 0.51810E+00 -0.2856 91 H2PO3- 0.64476E-19 -19.1906 0.53847E-19 -19.2688 0.83516E+00 -0.0782 92 H3PO4,aq 0.91468E-18 -18.0387 0.91468E-18 -18.0387 0.10000E+01 0.0000 93 H2PO4- 0.38714E-10 -10.4121 0.32363E-10 -10.4900 0.83595E+00 -0.0778 94 PO4-3 0.10619E-08 -8.9739 0.25757E-09 -9.5891 0.24255E+00 -0.6152 98 HP2O7-3 0.95161E-18 -18.0215 0.21997E-18 -18.6576 0.23116E+00 -0.6361 99 P2O7-4 0.91494E-17 -17.0386 0.70493E-18 -18.1519 0.77046E-01 -1.1132 100 H2S,aq 0.69983E-08 -8.1550 0.69741E-08 -8.1565 0.99654E+00 -0.0015 101 S2-2 0.79784E-14 -14.0981 0.41336E-14 -14.3837 0.51810E+00 -0.2856 107 SO3-2 0.17863E-16 -16.7480 0.93889E-17 -17.0274 0.52560E+00 -0.2793 108 HSO3- 0.52473E-19 -19.2801 0.43823E-19 -19.3583 0.83516E+00 -0.0782 109 HSO4- 0.12618E-17 -17.8990 0.10568E-17 -17.9760 0.83757E+00 -0.0770 Charge balance for all species = -.6133E-08 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.8872395E-10 -.2226470E-01 -.2240246E+02 0.0000 2 H2O 0.1000000E+01 0.5550484E+02 0.9981977E+06 0.0000 3 Cl- 0.1547304E-03 0.1554409E-03 0.5501266E+01 6.2389 4 SO4-- 0.2833215E-10 -.1514511E-04 -.1452334E+01 9.4228 5 HCO3- 0.8293319E-05 0.3790061E-04 0.2308568E+01 4.9687 6 HS- 0.3623943E-04 0.5139156E-04 0.1696666E+01 5.6086 7 Al+++ 0.9752597E-29 0.5246303E-05 0.1413070E+00 0.7353 8 H4SiO4 0.6990718E-03 0.1353231E-01 0.1298402E+04 -3.1555 9 Ca++ 0.1231740E-06 0.2173339E-06 0.8695163E-02 13.0578 10 Mg++ 0.2113443E-10 0.9318234E-10 0.2261510E-05 9.2903 11 Fe++ 0.4579643E-13 0.2831327E-07 0.1578462E-02 6.6266 12 K+ 0.1565103E-03 0.1572606E-03 0.6138514E+01 6.2446 13 Na+ 0.1986103E-01 0.2230597E-01 0.5119182E+03 8.3473 14 Mn++ 0.1871346E-10 0.2507561E-08 0.1375209E-03 9.2383 15 F- 0.2397425E-06 0.2405186E-06 0.4561427E-02 3.4282 16 HPO4-- 0.4531966E-07 0.4642030E-07 0.4447627E-02 12.6268 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.1999531E-01 -.1999502E-01 -.2932473E-06 0.0000000E+00 2 H2O 0.4984665E+02 0.4984665E+02 -.2532719E-06 0.0000000E+00 3 Cl- 0.1395952E-03 0.1395952E-03 0.0000000E+00 0.0000000E+00 4 SO4-- -.1360031E-04 -.1360121E-04 0.8956593E-09 0.0000000E+00 5 HCO3- 0.3403700E-04 0.3403700E-04 0.0000000E+00 0.0000000E+00 6 HS- 0.4615178E-04 0.4615268E-04 -.8956593E-09 0.0000000E+00 7 Al+++ 0.4775352E-05 0.4711492E-05 0.6386020E-07 0.0000000E+00 8 H4SiO4 0.1215302E-01 0.1215282E-01 0.2001717E-06 0.0000000E+00 9 Ca++ 0.2080835E-06 0.1951787E-06 0.1290475E-07 0.0000000E+00 10 Mg++ 0.8368328E-10 0.8368328E-10 0.0000000E+00 0.0000000E+00 11 Fe++ 0.3259227E-07 0.2542700E-07 0.7165274E-08 0.0000000E+00 12 K+ 0.1412294E-03 0.1412294E-03 0.0000000E+00 0.0000000E+00 13 Na+ 0.2003215E-01 0.2003209E-01 0.6242231E-07 0.0000000E+00 14 Mn++ 0.2251939E-08 0.2251939E-08 0.0000000E+00 0.0000000E+00 15 F- 0.2160000E-06 0.2160000E-06 0.0000000E+00 0.0000000E+00 16 HPO4-- 0.4168819E-07 0.4168819E-07 0.0000000E+00 0.0000000E+00 Chg. balance for solid moles: 0.1323E-22 Mass of aqueous solution: 0.899624E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 0.0002900 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 0.6242E-07 -7.205 0.1637E-04 -4.786 88.42 0.6283E-05 andradite 0.3583E-08 -8.446 0.1821E-05 -5.740 9.834 0.4730E-06 grossular 0.7189E-09 -9.143 0.3238E-06 -6.490 1.749 0.9011E-07 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8329E+00 0.8329E+00 1.0000 -0.079 grossular 0.1671E+00 0.1671E+00 1.0000 -0.777 Solid products produced: Mass = 0.000019 g Volume = 0.000007 cm3 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.0002900 moles log = -3.5376 Original solution: 1000.0103000 g Original solution / Rock added: 3448311.38 (Water/Rock Ratio), log = 6.5376 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0473 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9746E+00 0.9856 0.1006E+01 0.1021E+01 CO2,gas 0.1121E-06 1.0069 0.1182E-06 0.1174E-06 CH4,gas 0.1925E-01 1.0123 0.2041E-01 0.2016E-01 H2,gas 0.6154E-02 1.0006 0.6448E-02 0.6445E-02 H2S,gas 0.1838E-06 0.9959 0.1917E-06 0.1925E-06 S2,gas 0.3168E-28 1.0000 0.3318E-28 0.3318E-28 CO,gas 0.1940E-12 1.0000 0.2032E-12 0.2032E-12 SO3,gas 0.2951E-46 1.0000 0.3091E-46 0.3091E-46 SO2,gas 0.7404E-26 1.0000 0.7754E-26 0.7754E-26 HF,gas 0.2391E-15 1.0000 0.2504E-15 0.2504E-15 HCl,gas 0.2974E-17 1.0000 0.3115E-17 0.3115E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 17 albite -0.38 -0.38 0.00 0.000 0.11184E-10 23 andradite 39.01 39.01 0.00 0.000 0.00000E+00 24 grossular 32.73 32.73 0.00 0.000 -0.36397E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -15.29 -8.63 -2.875 0.14729E+05 -6.927 3 CH4,gas 4.54 1.15 -3.39 -0.847 0.57869E+04 -1.690 4 H2,gas 8.00 4.11 -3.89 -2.223 0.66412E+04 -2.191 5 H2S,gas -6.23 -14.65 -8.42 -4.208 0.14371E+05 -6.717 6 S2,gas -7.34 -37.51 -30.18 -4.643 0.51528E+05 -28.479 7 CO,gas 3.21 -11.18 -14.39 -4.428 0.24572E+05 -12.692 8 SO3,gas 17.12 -31.09 -48.21 -12.052 0.82315E+05 -46.510 9 SO2,gas 0.83 -26.98 -27.81 -7.416 0.47484E+05 -26.110 10 HF,gas 0.47 -16.83 -17.30 -8.650 0.29540E+05 -15.601 11 HCl,gas 5.19 -14.02 -19.21 -9.603 0.32793E+05 -17.507 12 acmite 7.71 6.61 -1.10 -0.114 0.18815E+04 16 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 20 spessartine 24.46 19.72 -4.74 -0.237 0.80906E+04 21 analcite 3.32 2.77 -0.55 -0.061 0.93954E+03 27 annite 20.12 17.39 -2.73 -0.152 0.46616E+04 28 phlogopite 27.06 25.38 -1.68 -0.093 0.28690E+04 30 anorthite 12.71 8.22 -4.49 -0.346 0.76714E+04 33 apatite-OH -18.15 -18.36 -0.21 -0.016 0.35498E+03 34 apatite-F -34.30 -35.19 -0.89 -0.074 0.15151E+04 38 aragonite 0.97 -2.23 -3.20 -1.065 0.54557E+04 39 brucite 12.57 9.29 -3.28 -0.656 0.55976E+04 40 calcite 0.81 -2.23 -3.04 -1.013 0.51914E+04 41 carnegieite-low 9.02 5.93 -3.10 -0.442 0.52867E+04 42 carnegieite-high 10.09 5.93 -4.17 -0.595 0.71137E+04 43 carpholite-Mg 8.58 4.45 -4.13 -0.275 0.70555E+04 44 carpholite-Fe 6.71 1.79 -4.93 -0.328 0.84117E+04 45 celadonite 5.34 3.65 -1.69 -0.100 0.28913E+04 46 celadonite-Fe 3.88 0.98 -2.89 -0.170 0.49379E+04 47 chrysotile 23.89 21.56 -2.33 -0.194 0.39827E+04 49 clinochlore 39.07 38.46 -0.61 -0.019 0.10483E+04 50 daphnite 28.97 25.14 -3.83 -0.120 0.65364E+04 52 chlorite-Al-free 47.17 43.12 -4.05 -0.169 0.69206E+04 54 chloritoid-Fe 9.17 4.94 -4.23 -0.282 0.72258E+04 55 chloritoid-Mn 11.40 7.55 -3.85 -0.257 0.65698E+04 57 coesite -2.38 -3.16 -0.78 -0.260 0.13308E+04 64 cristobalite -2.56 -3.16 -0.60 -0.198 0.10162E+04 66 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71234E+04 68 diaspore 2.87 0.74 -2.14 -0.356 0.36512E+04 69 diamond -3.10 -7.07 -3.96 -1.132 0.67677E+04 70 diopside 16.18 16.04 -0.14 -0.014 0.24629E+03 71 hedenbergite 14.21 13.37 -0.83 -0.083 0.14255E+04 74 enstatite 17.26 12.27 -5.00 -0.500 0.85294E+04 76 clinoenstatite 17.17 12.27 -4.90 -0.490 0.83610E+04 78 epidote 24.67 22.69 -1.98 -0.096 0.33785E+04 79 clinozoisite 22.81 18.86 -3.95 -0.180 0.67461E+04 80 epidote-Fe 29.84 26.53 -3.31 -0.172 0.56575E+04 81 fayalite 14.05 10.10 -3.95 -0.564 0.67411E+04 82 ferrosilite 11.15 6.94 -4.21 -0.421 0.71837E+04 86 gibbsite 4.08 0.74 -3.34 -0.478 0.57098E+04 87 glaucophane 22.97 20.79 -2.18 -0.059 0.37268E+04 88 glaucophane-Fe 17.28 12.80 -4.47 -0.121 0.76405E+04 89 graphite -3.55 -7.07 -3.52 -1.006 0.60099E+04 90 greenalite 16.14 13.57 -2.57 -0.214 0.43894E+04 93 hematite 12.57 9.14 -3.42 -0.415 0.58451E+04 94 heulandite -5.83 -7.56 -1.73 -0.079 0.29585E+04 98 jadeite 4.22 2.77 -1.44 -0.144 0.24650E+04 100 kalsilite 7.58 3.82 -3.76 -0.537 0.64192E+04 101 kaolinite -1.33 -4.84 -3.51 -0.319 0.59891E+04 104 laumontite 2.88 1.91 -0.98 -0.065 0.16681E+04 105 lawsonite 9.62 8.22 -1.40 -0.093 0.23881E+04 106 leucite 4.12 0.67 -3.45 -0.345 0.58906E+04 108 lizardite 23.24 21.56 -1.68 -0.140 0.28753E+04 110 magnetite 20.09 15.77 -4.32 -0.352 0.73726E+04 111 minnesotaite 10.39 7.26 -3.13 -0.184 0.53448E+04 115 manganosite 14.06 9.24 -4.82 -1.205 0.82297E+04 119 microcline -2.49 -2.49 0.00 0.000 0.24401E-01 123 muscovite 2.58 -1.02 -3.60 -0.212 0.61440E+04 124 paragonite 4.24 1.09 -3.15 -0.185 0.53831E+04 125 nepheline 8.34 5.93 -2.41 -0.345 0.41190E+04 131 periclase-Fe 11.63 6.63 -5.00 -1.250 0.85373E+04 137 phlogopite-Na 29.65 27.49 -2.16 -0.120 0.36878E+04 139 prehnite 19.37 18.12 -1.25 -0.074 0.21379E+04 140 prehnite-Fe 22.50 21.96 -0.54 -0.033 0.92533E+03 141 pumpellyite-Fe 46.27 43.60 -2.67 -0.059 0.45555E+04 142 pumpellyite-Mg 48.99 46.27 -2.73 -0.061 0.46610E+04 146 pyrrhotite -4.26 -8.02 -3.76 -1.253 0.64195E+04 147 pyrrhotiteFe0.875 -6.02 -9.36 -3.34 -1.229 0.57047E+04 148 pyroxmangite 7.40 6.08 -1.32 -0.263 0.22468E+04 149 pyrophyllite -6.18 -11.15 -4.98 -0.311 0.84955E+04 150 quartz -2.99 -3.16 -0.17 -0.055 0.28351E+03 155 rhodonite 7.45 6.08 -1.36 -0.273 0.23271E+04 156 sanidine -1.28 -2.49 -1.21 -0.093 0.20678E+04 166 stilbite -7.52 -7.56 -0.04 -0.002 0.64692E+02 167 stilpnomelane-Fe 13.02 12.48 -0.53 -0.016 0.91335E+03 168 stilpnomelane-Mg 27.44 25.80 -1.64 -0.049 0.28018E+04 174 talc 16.49 15.25 -1.24 -0.073 0.21209E+04 177 tephroite 18.09 15.32 -2.76 -0.395 0.47207E+04 181 tridymite -2.63 -3.16 -0.53 -0.176 0.90349E+03 182 tremolite 47.87 47.32 -0.55 -0.015 0.93246E+03 183 ferroactinolite 38.45 34.00 -4.45 -0.120 0.75942E+04 184 troilite-low -4.41 -8.02 -3.61 -1.203 0.61623E+04 190 wairakite 3.95 1.91 -2.04 -0.120 0.34900E+04 191 walstromite 11.51 9.90 -1.61 -0.321 0.27438E+04 192 wollastonite 10.46 9.90 -0.56 -0.112 0.95419E+03 193 pseudo-wollastonite 11.00 9.90 -1.10 -0.220 0.18740E+04 194 zoisite 22.85 18.86 -3.99 -0.182 0.68202E+04 195 akaganeite 7.75 4.57 -3.18 -0.688 0.54351E+04 202 chalcedony -2.80 -3.16 -0.35 -0.118 0.60281E+03 204 montmorillonite-Ca -2.29 -6.17 -3.88 -0.240 0.66300E+04 205 montmorillonite-K -2.24 -6.27 -4.03 -0.247 0.68823E+04 206 montmorillonite-Mg -2.48 -6.80 -4.32 -0.267 0.73684E+04 207 montmorillonite-Na -2.04 -5.57 -3.54 -0.217 0.60372E+04 208 nontronite-Ca 3.21 -0.04 -3.26 -0.211 0.55578E+04 209 nontronite-H 2.53 -2.20 -4.73 -0.317 0.80724E+04 210 nontronite-K 3.34 -0.13 -3.47 -0.223 0.59334E+04 211 nontronite-Mg 3.07 -0.66 -3.74 -0.242 0.63804E+04 212 nontronite-Na 3.52 0.56 -2.96 -0.190 0.50543E+04 228 tobermorite 9.82 7.72 -2.10 -0.573 0.35881E+04 234 alabandite -0.98 -5.41 -4.43 -1.477 0.75648E+04 237 boehmite 4.41 0.74 -3.67 -0.612 0.62682E+04 239 ferrous-oxide 9.81 6.63 -3.18 -0.796 0.54383E+04 245 silica-amorphous -2.09 -3.16 -1.06 -0.355 0.18170E+04 247 an20ab80 2.02 1.34 -0.68 -0.052 0.11634E+04 248 an25ab75 2.65 1.77 -0.88 -0.068 0.15013E+04 249 an30ab70 3.28 2.20 -1.08 -0.083 0.18487E+04 250 tr.625ac.25prg.125 45.16 44.94 -0.22 -0.006 0.38327E+03 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 0.0000100 MOLES Current total amount of reactant added: 0.0002900 MOLES New total amount of reactant added: 0.0003000 MOLES Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.5508E-08 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 6 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 0.0003000 Water: Moles liquid = 0.4985E+02 kg liquid = 0.8981E+00 Moles total = 0.4985E+02 kg total = 0.8980E+00 Activity = 1.0000 Stoichiometric ionic strength = .1134934E-01 Osmotic coef. = 0.9684 True ionic strength = .2003433E-01 Chg. balance for total moles = -.5508E-08 Max. difference allowed = 0.1397E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.88740E-10 -10.0519 0.74560E-10 -10.1275 0.84021E+00 -0.0756 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.15480E-03 -3.8102 0.12928E-03 -3.8885 0.83515E+00 -0.0782 4 SO4-- 0.29643E-10 -10.5281 0.15391E-10 -10.8127 0.51920E+00 -0.2847 5 HCO3- 0.85870E-05 -5.0662 0.71819E-05 -5.1438 0.83638E+00 -0.0776 6 HS- 0.36510E-04 -4.4376 0.30496E-04 -4.5158 0.83528E+00 -0.0782 7 Al+++ 0.97548E-29 -29.0108 0.22526E-29 -29.6473 0.23092E+00 -0.6365 8 H4SiO4 0.69919E-03 -3.1554 0.69919E-03 -3.1554 0.10000E+01 0.0000 9 Ca++ 0.12300E-06 -6.9101 0.63393E-07 -7.1980 0.51539E+00 -0.2879 10 Mg++ 0.21135E-10 -10.6750 0.10843E-10 -10.9649 0.51303E+00 -0.2899 11 Fe++ 0.45730E-13 -13.3398 0.23486E-13 -13.6292 0.51359E+00 -0.2894 12 K+ 0.15651E-03 -3.8055 0.13093E-03 -3.8830 0.83658E+00 -0.0775 13 Na+ 0.19861E-01 -1.7020 0.16584E-01 -1.7803 0.83500E+00 -0.0783 14 Mn++ 0.18720E-10 -10.7277 0.96223E-11 -11.0167 0.51402E+00 -0.2890 15 F- 0.24418E-06 -6.6123 0.20351E-06 -6.6914 0.83343E+00 -0.0791 16 HPO4-- 0.45320E-07 -7.3437 0.23533E-07 -7.6283 0.51927E+00 -0.2846 18 HSiO3- 0.10484E-01 -1.9795 0.87562E-02 -2.0577 0.83515E+00 -0.0782 19 Ca(HSiO3)+ 0.15108E-07 -7.8208 0.12641E-07 -7.8982 0.83676E+00 -0.0774 20 Mg(HSiO3)+ 0.32158E-11 -11.4927 0.26909E-11 -11.5701 0.83676E+00 -0.0774 21 NaHSiO3,aq 0.23486E-02 -2.6292 0.23486E-02 -2.6292 0.10000E+01 0.0000 22 AlO+ 0.65880E-16 -16.1812 0.55125E-16 -16.2587 0.83676E+00 -0.0774 24 HAlO2,aq 0.14724E-09 -9.8320 0.14724E-09 -9.8320 0.10000E+01 0.0000 25 AlO2- 0.52436E-05 -5.2804 0.43713E-05 -5.3594 0.83365E+00 -0.0790 26 CH4,aq 0.13871E-04 -4.8579 0.13823E-04 -4.8594 0.99654E+00 -0.0015 27 C2H6,aq 0.67378E-14 -14.1715 0.67145E-14 -14.1730 0.99654E+00 -0.0015 31 CO,aq 0.13984E-15 -15.8544 0.13984E-15 -15.8544 0.10000E+01 0.0000 32 CO2,aq 0.11482E-08 -8.9400 0.11442E-08 -8.9415 0.99654E+00 -0.0015 33 CO3-2 0.16239E-04 -4.7894 0.84136E-05 -5.0750 0.51810E+00 -0.2856 34 CaCO3,aq 0.66878E-08 -8.1747 0.66878E-08 -8.1747 0.10000E+01 0.0000 35 Ca(HCO3)+ 0.13889E-10 -10.8573 0.11622E-10 -10.9347 0.83676E+00 -0.0774 36 CaCl+ 0.15850E-10 -10.8000 0.13263E-10 -10.8774 0.83676E+00 -0.0774 37 CaCl2,aq 0.40735E-15 -15.3900 0.40735E-15 -15.3900 0.10000E+01 0.0000 38 CaF+ 0.22511E-12 -12.6476 0.18836E-12 -12.7250 0.83676E+00 -0.0774 39 CaOH+ 0.72418E-07 -7.1402 0.60596E-07 -7.2176 0.83676E+00 -0.0774 40 CaSO4,aq 0.30982E-15 -15.5089 0.30982E-15 -15.5089 0.10000E+01 0.0000 41 HCl,aq 0.17663E-14 -14.7529 0.17663E-14 -14.7529 0.10000E+01 0.0000 45 HF,aq 0.10387E-12 -12.9835 0.10387E-12 -12.9835 0.10000E+01 0.0000 48 FeCl+ 0.57435E-17 -17.2408 0.48059E-17 -17.3182 0.83676E+00 -0.0774 51 FeF+ 0.29190E-18 -18.5348 0.24425E-18 -18.6122 0.83676E+00 -0.0774 53 FeO,aq 0.16420E-09 -9.7846 0.16420E-09 -9.7846 0.10000E+01 0.0000 54 FeOH+ 0.12254E-10 -10.9117 0.10254E-10 -10.9891 0.83676E+00 -0.0774 55 HFeO2- 0.27590E-07 -7.5592 0.23042E-07 -7.6375 0.83515E+00 -0.0782 56 FeO+ 0.13251E-16 -16.8778 0.11088E-16 -16.9552 0.83676E+00 -0.0774 58 FeO2- 0.48867E-09 -9.3110 0.40812E-09 -9.3892 0.83515E+00 -0.0782 59 HFeO2,aq 0.38701E-11 -11.4123 0.38701E-11 -11.4123 0.10000E+01 0.0000 60 H2,aq 0.48821E-05 -5.3114 0.48652E-05 -5.3129 0.99654E+00 -0.0015 61 KCl,aq 0.30678E-09 -9.5132 0.30678E-09 -9.5132 0.10000E+01 0.0000 63 KOH,aq 0.74994E-06 -6.1250 0.74994E-06 -6.1250 0.10000E+01 0.0000 64 KSO4- 0.37442E-13 -13.4266 0.31270E-13 -13.5049 0.83515E+00 -0.0782 65 MgCO3,aq 0.28672E-12 -12.5425 0.28672E-12 -12.5425 0.10000E+01 0.0000 66 Mg(HCO3)+ 0.24274E-14 -14.6149 0.20311E-14 -14.6923 0.83676E+00 -0.0774 67 MgCl+ 0.24571E-14 -14.6096 0.20560E-14 -14.6870 0.83676E+00 -0.0774 68 MgF+ 0.14262E-15 -15.8458 0.11934E-15 -15.9232 0.83676E+00 -0.0774 69 MgOH+ 0.68540E-10 -10.1641 0.57351E-10 -10.2415 0.83676E+00 -0.0774 71 MnF+ 0.39418E-16 -16.4043 0.32983E-16 -16.4817 0.83676E+00 -0.0774 72 MnO,aq 0.17925E-08 -8.7465 0.17925E-08 -8.7465 0.10000E+01 0.0000 73 MnOH+ 0.46638E-09 -9.3313 0.39024E-09 -9.4087 0.83676E+00 -0.0774 74 MnO2-2 0.20654E-10 -10.6850 0.10701E-10 -10.9706 0.51810E+00 -0.2856 75 HMnO2- 0.20930E-09 -9.6792 0.17480E-09 -9.7575 0.83515E+00 -0.0782 78 MnCl+ 0.91546E-14 -14.0384 0.76602E-14 -14.1158 0.83676E+00 -0.0774 79 MnSO4,aq 0.42753E-19 -19.3690 0.42753E-19 -19.3690 0.10000E+01 0.0000 80 NaCl,aq 0.71051E-06 -6.1484 0.71051E-06 -6.1484 0.10000E+01 0.0000 81 NaF,aq 0.79015E-09 -9.1023 0.79015E-09 -9.1023 0.10000E+01 0.0000 82 NaOH,aq 0.95565E-04 -4.0197 0.95565E-04 -4.0197 0.10000E+01 0.0000 84 OH- 0.92955E-02 -2.0317 0.77491E-02 -2.1107 0.83365E+00 -0.0790 89 HPO3-2 0.68869E-15 -15.1620 0.35681E-15 -15.4476 0.51810E+00 -0.2856 91 H2PO3- 0.63878E-19 -19.1946 0.53348E-19 -19.2729 0.83515E+00 -0.0782 92 H3PO4,aq 0.91499E-18 -18.0386 0.91499E-18 -18.0386 0.10000E+01 0.0000 93 H2PO4- 0.38721E-10 -10.4121 0.32368E-10 -10.4899 0.83595E+00 -0.0778 94 PO4-3 0.10618E-08 -8.9740 0.25752E-09 -9.5892 0.24254E+00 -0.6152 98 HP2O7-3 0.95178E-18 -18.0215 0.22001E-18 -18.6576 0.23115E+00 -0.6361 99 P2O7-4 0.91496E-17 -17.0386 0.70492E-18 -18.1519 0.77044E-01 -1.1133 100 H2S,aq 0.70518E-08 -8.1517 0.70274E-08 -8.1532 0.99654E+00 -0.0015 101 S2-2 0.81752E-14 -14.0875 0.42356E-14 -14.3731 0.51810E+00 -0.2856 107 SO3-2 0.18513E-16 -16.7325 0.97305E-17 -17.0119 0.52559E+00 -0.2793 108 HSO3- 0.54392E-19 -19.2645 0.45425E-19 -19.3427 0.83515E+00 -0.0782 109 HSO4- 0.13203E-17 -17.8793 0.11059E-17 -17.9563 0.83757E+00 -0.0770 Charge balance for all species = -.6133E-08 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.8873959E-10 -.2226348E-01 -.2240124E+02 0.0000 2 H2O 0.1000000E+01 0.5550484E+02 0.9981977E+06 0.0000 3 Cl- 0.1547958E-03 0.1555066E-03 0.5503589E+01 6.2390 4 SO4-- 0.2964290E-10 -.1509194E-04 -.1447235E+01 9.4422 5 HCO3- 0.8586964E-05 0.3870567E-04 0.2357605E+01 4.9837 6 HS- 0.3650995E-04 0.5160897E-04 0.1703844E+01 5.6117 7 Al+++ 0.9754800E-29 0.5243746E-05 0.1412381E+00 0.7352 8 H4SiO4 0.6991859E-03 0.1353230E-01 0.1298401E+04 -3.1554 9 Ca++ 0.1230018E-06 0.2172447E-06 0.8691596E-02 13.0570 10 Mg++ 0.2113501E-10 0.9318232E-10 0.2261509E-05 9.2901 11 Fe++ 0.4572973E-13 0.2825943E-07 0.1575460E-02 6.6258 12 K+ 0.1565104E-03 0.1572606E-03 0.6138512E+01 6.2445 13 Na+ 0.1986107E-01 0.2230596E-01 0.5119180E+03 8.3472 14 Mn++ 0.1871979E-10 0.2507561E-08 0.1375208E-03 9.2383 15 F- 0.2441821E-06 0.2449726E-06 0.4645897E-02 3.4361 16 HPO4-- 0.4531982E-07 0.4642029E-07 0.4447626E-02 12.6267 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.1999424E-01 -.1999393E-01 -.3026732E-06 0.0000000E+00 2 H2O 0.4984665E+02 0.4984665E+02 -.2624562E-06 0.0000000E+00 3 Cl- 0.1396542E-03 0.1396542E-03 0.0000000E+00 0.0000000E+00 4 SO4-- -.1355256E-04 -.1355346E-04 0.9017017E-09 0.0000000E+00 5 HCO3- 0.3476000E-04 0.3476000E-04 0.0000000E+00 0.0000000E+00 6 HS- 0.4634703E-04 0.4634793E-04 -.9017017E-09 0.0000000E+00 7 Al+++ 0.4775352E-05 0.4709197E-05 0.6615525E-07 0.0000000E+00 8 H4SiO4 0.1215302E-01 0.1215281E-01 0.2071218E-06 0.0000000E+00 9 Ca++ 0.2080835E-06 0.1950987E-06 0.1298478E-07 0.0000000E+00 10 Mg++ 0.8368328E-10 0.8368328E-10 0.0000000E+00 0.0000000E+00 11 Fe++ 0.3259227E-07 0.2537866E-07 0.7213613E-08 0.0000000E+00 12 K+ 0.1412294E-03 0.1412294E-03 0.0000000E+00 0.0000000E+00 13 Na+ 0.2003215E-01 0.2003209E-01 0.6471235E-07 0.0000000E+00 14 Mn++ 0.2251939E-08 0.2251939E-08 0.0000000E+00 0.0000000E+00 15 F- 0.2200000E-06 0.2200000E-06 0.0000000E+00 0.0000000E+00 16 HPO4-- 0.4168819E-07 0.4168819E-07 0.0000000E+00 0.0000000E+00 Chg. balance for solid moles: 0.3970E-22 Mass of aqueous solution: 0.899624E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 0.0003000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 0.6471E-07 -7.189 0.1697E-04 -4.770 88.72 0.6514E-05 andradite 0.3607E-08 -8.443 0.1833E-05 -5.737 9.583 0.4762E-06 grossular 0.7215E-09 -9.142 0.3250E-06 -6.488 1.699 0.9042E-07 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8333E+00 0.8333E+00 1.0000 -0.079 grossular 0.1667E+00 0.1667E+00 1.0000 -0.778 Solid products produced: Mass = 0.000019 g Volume = 0.000007 cm3 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.0003000 moles log = -3.5229 Original solution: 1000.0103000 g Original solution / Rock added: 3333367.67 (Water/Rock Ratio), log = 6.5229 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0472 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9747E+00 0.9856 0.1006E+01 0.1021E+01 CO2,gas 0.1161E-06 1.0069 0.1224E-06 0.1216E-06 CH4,gas 0.1919E-01 1.0123 0.2035E-01 0.2010E-01 H2,gas 0.6096E-02 1.0006 0.6387E-02 0.6384E-02 H2S,gas 0.1852E-06 0.9959 0.1932E-06 0.1940E-06 S2,gas 0.3279E-28 1.0000 0.3433E-28 0.3433E-28 CO,gas 0.1990E-12 1.0000 0.2084E-12 0.2084E-12 SO3,gas 0.3089E-46 1.0000 0.3235E-46 0.3235E-46 SO2,gas 0.7677E-26 1.0000 0.8039E-26 0.8039E-26 HF,gas 0.2436E-15 1.0000 0.2550E-15 0.2550E-15 HCl,gas 0.2976E-17 1.0000 0.3117E-17 0.3117E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 17 albite -0.38 -0.38 0.00 0.000 -0.94784E-12 23 andradite 39.01 39.01 0.00 0.000 -0.12132E-10 24 grossular 32.73 32.73 0.00 0.000 0.00000E+00 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -15.27 -8.61 -2.870 0.14703E+05 -6.912 3 CH4,gas 4.54 1.15 -3.39 -0.848 0.57891E+04 -1.691 4 H2,gas 8.00 4.11 -3.89 -2.225 0.66483E+04 -2.195 5 H2S,gas -6.23 -14.64 -8.41 -4.207 0.14365E+05 -6.714 6 S2,gas -7.34 -37.50 -30.16 -4.641 0.51503E+05 -28.464 7 CO,gas 3.21 -11.17 -14.38 -4.425 0.24554E+05 -12.681 8 SO3,gas 17.12 -31.07 -48.19 -12.047 0.82282E+05 -46.490 9 SO2,gas 0.83 -26.96 -27.79 -7.412 0.47457E+05 -26.095 10 HF,gas 0.47 -16.82 -17.29 -8.646 0.29526E+05 -15.593 11 HCl,gas 5.19 -14.02 -19.21 -9.603 0.32792E+05 -17.506 12 acmite 7.71 6.61 -1.10 -0.114 0.18792E+04 16 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 20 spessartine 24.46 19.72 -4.74 -0.237 0.80907E+04 21 analcite 3.32 2.77 -0.55 -0.061 0.93966E+03 27 annite 20.12 17.39 -2.73 -0.152 0.46657E+04 28 phlogopite 27.06 25.38 -1.68 -0.093 0.28698E+04 30 anorthite 12.71 8.22 -4.49 -0.346 0.76730E+04 33 apatite-OH -18.15 -18.36 -0.21 -0.016 0.36072E+03 34 apatite-F -34.30 -35.18 -0.88 -0.074 0.15071E+04 38 aragonite 0.97 -2.21 -3.18 -1.060 0.54310E+04 39 brucite 12.57 9.29 -3.28 -0.656 0.55978E+04 40 calcite 0.81 -2.21 -3.03 -1.009 0.51668E+04 41 carnegieite-low 9.02 5.93 -3.10 -0.442 0.52869E+04 42 carnegieite-high 10.09 5.93 -4.17 -0.595 0.71139E+04 43 carpholite-Mg 8.58 4.45 -4.13 -0.275 0.70560E+04 44 carpholite-Fe 6.71 1.79 -4.93 -0.328 0.84132E+04 45 celadonite 5.34 3.65 -1.69 -0.100 0.28914E+04 46 celadonite-Fe 3.88 0.98 -2.89 -0.170 0.49391E+04 47 chrysotile 23.89 21.56 -2.33 -0.194 0.39832E+04 49 clinochlore 39.07 38.45 -0.61 -0.019 0.10496E+04 50 daphnite 28.97 25.13 -3.83 -0.120 0.65432E+04 52 chlorite-Al-free 47.17 43.12 -4.05 -0.169 0.69216E+04 54 chloritoid-Fe 9.17 4.94 -4.23 -0.282 0.72275E+04 55 chloritoid-Mn 11.40 7.55 -3.85 -0.257 0.65701E+04 57 coesite -2.38 -3.16 -0.78 -0.260 0.13307E+04 64 cristobalite -2.56 -3.16 -0.60 -0.198 0.10161E+04 66 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71234E+04 68 diaspore 2.87 0.74 -2.14 -0.356 0.36515E+04 69 diamond -3.10 -7.06 -3.96 -1.130 0.67558E+04 70 diopside 16.18 16.04 -0.15 -0.015 0.24759E+03 71 hedenbergite 14.21 13.37 -0.84 -0.084 0.14279E+04 74 enstatite 17.26 12.27 -5.00 -0.500 0.85296E+04 76 clinoenstatite 17.17 12.27 -4.90 -0.490 0.83612E+04 78 epidote 24.67 22.69 -1.98 -0.096 0.33791E+04 79 clinozoisite 22.81 18.85 -3.95 -0.180 0.67491E+04 80 epidote-Fe 29.84 26.53 -3.31 -0.172 0.56557E+04 81 fayalite 14.05 10.10 -3.95 -0.564 0.67437E+04 82 ferrosilite 11.15 6.94 -4.21 -0.421 0.71862E+04 86 gibbsite 4.08 0.74 -3.34 -0.478 0.57100E+04 87 glaucophane 22.97 20.79 -2.18 -0.059 0.37273E+04 88 glaucophane-Fe 17.28 12.80 -4.48 -0.121 0.76443E+04 89 graphite -3.55 -7.06 -3.51 -1.004 0.59981E+04 90 greenalite 16.14 13.57 -2.57 -0.214 0.43932E+04 93 hematite 12.57 9.15 -3.42 -0.415 0.58407E+04 94 heulandite -5.83 -7.56 -1.73 -0.079 0.29594E+04 98 jadeite 4.22 2.77 -1.44 -0.144 0.24651E+04 100 kalsilite 7.58 3.82 -3.76 -0.537 0.64194E+04 101 kaolinite -1.33 -4.84 -3.51 -0.319 0.59893E+04 104 laumontite 2.88 1.91 -0.98 -0.065 0.16693E+04 105 lawsonite 9.62 8.22 -1.40 -0.093 0.23896E+04 106 leucite 4.12 0.67 -3.45 -0.345 0.58907E+04 108 lizardite 23.24 21.56 -1.68 -0.140 0.28758E+04 110 magnetite 20.09 15.77 -4.32 -0.352 0.73696E+04 111 minnesotaite 10.39 7.26 -3.13 -0.184 0.53484E+04 115 manganosite 14.06 9.24 -4.82 -1.205 0.82298E+04 119 microcline -2.49 -2.49 0.00 0.000 0.25242E-01 123 muscovite 2.58 -1.02 -3.60 -0.212 0.61445E+04 124 paragonite 4.24 1.09 -3.15 -0.185 0.53836E+04 125 nepheline 8.34 5.93 -2.41 -0.345 0.41193E+04 137 phlogopite-Na 29.65 27.49 -2.16 -0.120 0.36885E+04 139 prehnite 19.37 18.12 -1.25 -0.074 0.21407E+04 140 prehnite-Fe 22.50 21.96 -0.54 -0.033 0.92563E+03 141 pumpellyite-Fe 46.27 43.60 -2.67 -0.059 0.45625E+04 142 pumpellyite-Mg 48.99 46.26 -2.73 -0.061 0.46669E+04 146 pyrrhotite -4.26 -8.02 -3.76 -1.252 0.64152E+04 147 pyrrhotiteFe0.875 -6.02 -9.35 -3.34 -1.228 0.56993E+04 148 pyroxmangite 7.40 6.08 -1.32 -0.263 0.22467E+04 149 pyrophyllite -6.18 -11.15 -4.98 -0.311 0.84955E+04 150 quartz -2.99 -3.16 -0.17 -0.055 0.28339E+03 155 rhodonite 7.45 6.08 -1.36 -0.273 0.23270E+04 156 sanidine -1.28 -2.49 -1.21 -0.093 0.20678E+04 166 stilbite -7.52 -7.56 -0.04 -0.002 0.65614E+02 167 stilpnomelane-Fe 13.02 12.48 -0.54 -0.016 0.91964E+03 168 stilpnomelane-Mg 27.44 25.80 -1.64 -0.049 0.28026E+04 174 talc 16.49 15.25 -1.24 -0.073 0.21212E+04 177 tephroite 18.09 15.32 -2.76 -0.395 0.47206E+04 181 tridymite -2.63 -3.16 -0.53 -0.176 0.90337E+03 182 tremolite 47.87 47.32 -0.55 -0.015 0.93532E+03 183 ferroactinolite 38.45 34.00 -4.45 -0.120 0.76026E+04 184 troilite-low -4.41 -8.02 -3.61 -1.202 0.61580E+04 190 wairakite 3.95 1.91 -2.04 -0.120 0.34913E+04 191 walstromite 11.51 9.90 -1.61 -0.322 0.27449E+04 192 wollastonite 10.46 9.90 -0.56 -0.112 0.95537E+03 193 pseudo-wollastonite 11.00 9.90 -1.10 -0.220 0.18752E+04 194 zoisite 22.85 18.85 -4.00 -0.182 0.68231E+04 195 akaganeite 7.75 4.57 -3.18 -0.688 0.54329E+04 202 chalcedony -2.80 -3.16 -0.35 -0.118 0.60269E+03 204 montmorillonite-Ca -2.29 -6.17 -3.88 -0.240 0.66302E+04 205 montmorillonite-K -2.24 -6.27 -4.03 -0.247 0.68824E+04 206 montmorillonite-Mg -2.48 -6.80 -4.32 -0.267 0.73684E+04 207 montmorillonite-Na -2.04 -5.57 -3.54 -0.217 0.60373E+04 208 nontronite-Ca 3.21 -0.04 -3.25 -0.211 0.55533E+04 209 nontronite-H 2.53 -2.19 -4.72 -0.317 0.80677E+04 210 nontronite-K 3.34 -0.13 -3.47 -0.223 0.59288E+04 211 nontronite-Mg 3.07 -0.66 -3.73 -0.242 0.63757E+04 212 nontronite-Na 3.52 0.56 -2.96 -0.190 0.50496E+04 228 tobermorite 9.82 7.72 -2.10 -0.574 0.35890E+04 234 alabandite -0.98 -5.40 -4.43 -1.476 0.75592E+04 237 boehmite 4.41 0.74 -3.67 -0.612 0.62684E+04 239 ferrous-oxide 9.81 6.63 -3.19 -0.796 0.54396E+04 245 silica-amorphous -2.09 -3.16 -1.06 -0.355 0.18169E+04 247 an20ab80 2.02 1.34 -0.68 -0.052 0.11637E+04 248 an25ab75 2.65 1.77 -0.88 -0.068 0.15017E+04 249 an30ab70 3.28 2.20 -1.08 -0.083 0.18492E+04 250 tr.625ac.25prg.125 45.16 44.94 -0.23 -0.006 0.38761E+03 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 0.0000100 MOLES Current total amount of reactant added: 0.0003000 MOLES New total amount of reactant added: 0.0003100 MOLES Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.5508E-08 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 6 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 0.0003100 Water: Moles liquid = 0.4985E+02 kg liquid = 0.8981E+00 Moles total = 0.4985E+02 kg total = 0.8980E+00 Activity = 1.0000 Stoichiometric ionic strength = .1134998E-01 Osmotic coef. = 0.9683 True ionic strength = .2003492E-01 Chg. balance for total moles = -.5508E-08 Max. difference allowed = 0.1397E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.88755E-10 -10.0518 0.74573E-10 -10.1274 0.84021E+00 -0.0756 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.15486E-03 -3.8101 0.12933E-03 -3.8883 0.83515E+00 -0.0782 4 SO4-- 0.30978E-10 -10.5089 0.16084E-10 -10.7936 0.51920E+00 -0.2847 5 HCO3- 0.88808E-05 -5.0515 0.74277E-05 -5.1291 0.83638E+00 -0.0776 6 HS- 0.36780E-04 -4.4344 0.30722E-04 -4.5126 0.83528E+00 -0.0782 7 Al+++ 0.97570E-29 -29.0107 0.22531E-29 -29.6472 0.23092E+00 -0.6365 8 H4SiO4 0.69930E-03 -3.1553 0.69930E-03 -3.1553 0.10000E+01 0.0000 9 Ca++ 0.12283E-06 -6.9107 0.63306E-07 -7.1986 0.51538E+00 -0.2879 10 Mg++ 0.21136E-10 -10.6750 0.10843E-10 -10.9648 0.51302E+00 -0.2899 11 Fe++ 0.45667E-13 -13.3404 0.23454E-13 -13.6298 0.51359E+00 -0.2894 12 K+ 0.15651E-03 -3.8055 0.13093E-03 -3.8830 0.83657E+00 -0.0775 13 Na+ 0.19861E-01 -1.7020 0.16584E-01 -1.7803 0.83500E+00 -0.0783 14 Mn++ 0.18726E-10 -10.7276 0.96254E-11 -11.0166 0.51401E+00 -0.2890 15 F- 0.24862E-06 -6.6045 0.20721E-06 -6.6836 0.83343E+00 -0.0791 16 HPO4-- 0.45320E-07 -7.3437 0.23533E-07 -7.6283 0.51927E+00 -0.2846 18 HSiO3- 0.10484E-01 -1.9795 0.87561E-02 -2.0577 0.83515E+00 -0.0782 19 Ca(HSiO3)+ 0.15087E-07 -7.8214 0.12624E-07 -7.8988 0.83675E+00 -0.0774 20 Mg(HSiO3)+ 0.32159E-11 -11.4927 0.26909E-11 -11.5701 0.83675E+00 -0.0774 21 NaHSiO3,aq 0.23486E-02 -2.6292 0.23486E-02 -2.6292 0.10000E+01 0.0000 22 AlO+ 0.65870E-16 -16.1813 0.55117E-16 -16.2587 0.83675E+00 -0.0774 24 HAlO2,aq 0.14719E-09 -9.8321 0.14719E-09 -9.8321 0.10000E+01 0.0000 25 AlO2- 0.52410E-05 -5.2806 0.43692E-05 -5.3596 0.83364E+00 -0.0790 26 CH4,aq 0.13830E-04 -4.8592 0.13782E-04 -4.8607 0.99654E+00 -0.0015 27 C2H6,aq 0.67591E-14 -14.1701 0.67357E-14 -14.1716 0.99654E+00 -0.0015 31 CO,aq 0.14333E-15 -15.8437 0.14333E-15 -15.8437 0.10000E+01 0.0000 32 CO2,aq 0.11877E-08 -8.9253 0.11836E-08 -8.9268 0.99654E+00 -0.0015 33 CO3-2 0.16792E-04 -4.7749 0.87000E-05 -5.0605 0.51809E+00 -0.2856 34 CaCO3,aq 0.69059E-08 -8.1608 0.69059E-08 -8.1608 0.10000E+01 0.0000 35 Ca(HCO3)+ 0.14344E-10 -10.8433 0.12003E-10 -10.9207 0.83675E+00 -0.0774 36 CaCl+ 0.15835E-10 -10.8004 0.13250E-10 -10.8778 0.83675E+00 -0.0774 37 CaCl2,aq 0.40713E-15 -15.3903 0.40713E-15 -15.3903 0.10000E+01 0.0000 38 CaF+ 0.22888E-12 -12.6404 0.19152E-12 -12.7178 0.83675E+00 -0.0774 39 CaOH+ 0.72305E-07 -7.1408 0.60501E-07 -7.2182 0.83675E+00 -0.0774 40 CaSO4,aq 0.32333E-15 -15.4904 0.32333E-15 -15.4904 0.10000E+01 0.0000 41 HCl,aq 0.17674E-14 -14.7527 0.17674E-14 -14.7527 0.10000E+01 0.0000 45 HF,aq 0.10578E-12 -12.9756 0.10578E-12 -12.9756 0.10000E+01 0.0000 48 FeCl+ 0.57381E-17 -17.2412 0.48013E-17 -17.3186 0.83675E+00 -0.0774 51 FeF+ 0.29680E-18 -18.5275 0.24835E-18 -18.6049 0.83675E+00 -0.0774 53 FeO,aq 0.16392E-09 -9.7854 0.16392E-09 -9.7854 0.10000E+01 0.0000 54 FeOH+ 0.12235E-10 -10.9124 0.10238E-10 -10.9898 0.83675E+00 -0.0774 55 HFeO2- 0.27538E-07 -7.5601 0.22999E-07 -7.6383 0.83515E+00 -0.0782 56 FeO+ 0.13292E-16 -16.8764 0.11122E-16 -16.9538 0.83675E+00 -0.0774 58 FeO2- 0.49000E-09 -9.3098 0.40923E-09 -9.3880 0.83515E+00 -0.0782 59 HFeO2,aq 0.38813E-11 -11.4110 0.38813E-11 -11.4110 0.10000E+01 0.0000 60 H2,aq 0.48374E-05 -5.3154 0.48206E-05 -5.3169 0.99654E+00 -0.0015 61 KCl,aq 0.30691E-09 -9.5130 0.30691E-09 -9.5130 0.10000E+01 0.0000 63 KOH,aq 0.74981E-06 -6.1250 0.74981E-06 -6.1250 0.10000E+01 0.0000 64 KSO4- 0.39129E-13 -13.4075 0.32678E-13 -13.4857 0.83515E+00 -0.0782 65 MgCO3,aq 0.29649E-12 -12.5280 0.29649E-12 -12.5280 0.10000E+01 0.0000 66 Mg(HCO3)+ 0.25105E-14 -14.6002 0.21007E-14 -14.6776 0.83675E+00 -0.0774 67 MgCl+ 0.24582E-14 -14.6094 0.20569E-14 -14.6868 0.83675E+00 -0.0774 68 MgF+ 0.14522E-15 -15.8380 0.12151E-15 -15.9154 0.83675E+00 -0.0774 69 MgOH+ 0.68529E-10 -10.1641 0.57342E-10 -10.2415 0.83675E+00 -0.0774 71 MnF+ 0.40148E-16 -16.3963 0.33594E-16 -16.4737 0.83675E+00 -0.0774 72 MnO,aq 0.17925E-08 -8.7465 0.17925E-08 -8.7465 0.10000E+01 0.0000 73 MnOH+ 0.46645E-09 -9.3312 0.39031E-09 -9.4086 0.83675E+00 -0.0774 74 MnO2-2 0.20647E-10 -10.6851 0.10697E-10 -10.9707 0.51809E+00 -0.2856 75 HMnO2- 0.20926E-09 -9.6793 0.17476E-09 -9.7575 0.83515E+00 -0.0782 78 MnCl+ 0.91615E-14 -14.0380 0.76659E-14 -14.1154 0.83675E+00 -0.0774 79 MnSO4,aq 0.44694E-19 -19.3498 0.44694E-19 -19.3498 0.10000E+01 0.0000 80 NaCl,aq 0.71081E-06 -6.1482 0.71081E-06 -6.1482 0.10000E+01 0.0000 81 NaF,aq 0.80452E-09 -9.0945 0.80452E-09 -9.0945 0.10000E+01 0.0000 82 NaOH,aq 0.95548E-04 -4.0198 0.95548E-04 -4.0198 0.10000E+01 0.0000 84 OH- 0.92939E-02 -2.0318 0.77478E-02 -2.1108 0.83364E+00 -0.0790 89 HPO3-2 0.68237E-15 -15.1660 0.35353E-15 -15.4516 0.51809E+00 -0.2856 91 H2PO3- 0.63303E-19 -19.1986 0.52868E-19 -19.2768 0.83515E+00 -0.0782 92 H3PO4,aq 0.91531E-18 -18.0384 0.91531E-18 -18.0384 0.10000E+01 0.0000 93 H2PO4- 0.38727E-10 -10.4120 0.32374E-10 -10.4898 0.83594E+00 -0.0778 94 PO4-3 0.10616E-08 -8.9740 0.25747E-09 -9.5893 0.24254E+00 -0.6152 98 HP2O7-3 0.95196E-18 -18.0214 0.22004E-18 -18.6575 0.23115E+00 -0.6361 99 P2O7-4 0.91498E-17 -17.0386 0.70492E-18 -18.1519 0.77042E-01 -1.1133 100 H2S,aq 0.71053E-08 -8.1484 0.70807E-08 -8.1499 0.99654E+00 -0.0015 101 S2-2 0.83737E-14 -14.0771 0.43383E-14 -14.3627 0.51809E+00 -0.2856 107 SO3-2 0.19170E-16 -16.7174 0.10075E-16 -16.9967 0.52559E+00 -0.2794 108 HSO3- 0.56330E-19 -19.2493 0.47044E-19 -19.3275 0.83515E+00 -0.0782 109 HSO4- 0.13801E-17 -17.8601 0.11559E-17 -17.9371 0.83757E+00 -0.0770 Charge balance for all species = -.6133E-08 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.8875524E-10 -.2226227E-01 -.2240001E+02 0.0000 2 H2O 0.1000000E+01 0.5550484E+02 0.9981976E+06 0.0000 3 Cl- 0.1548611E-03 0.1555723E-03 0.5505913E+01 6.2391 4 SO4-- 0.3097835E-10 -.1503877E-04 -.1442137E+01 9.4612 5 HCO3- 0.8880828E-05 0.3951073E-04 0.2406642E+01 4.9983 6 HS- 0.3678047E-04 0.5182638E-04 0.1711022E+01 5.6149 7 Al+++ 0.9757004E-29 0.5241189E-05 0.1411693E+00 0.7350 8 H4SiO4 0.6993001E-03 0.1353229E-01 0.1298400E+04 -3.1553 9 Ca++ 0.1228327E-06 0.2171605E-06 0.8688224E-02 13.0563 10 Mg++ 0.2113559E-10 0.9318230E-10 0.2261509E-05 9.2900 11 Fe++ 0.4566749E-13 0.2820833E-07 0.1572611E-02 6.6251 12 K+ 0.1565105E-03 0.1572606E-03 0.6138511E+01 6.2445 13 Na+ 0.1986111E-01 0.2230596E-01 0.5119178E+03 8.3471 14 Mn++ 0.1872613E-10 0.2507560E-08 0.1375208E-03 9.2383 15 F- 0.2486217E-06 0.2494266E-06 0.4730367E-02 3.4438 16 HPO4-- 0.4531997E-07 0.4642028E-07 0.4447625E-02 12.6265 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.1999316E-01 -.1999285E-01 -.3120865E-06 0.0000000E+00 2 H2O 0.4984666E+02 0.4984666E+02 -.2716416E-06 0.0000000E+00 3 Cl- 0.1397132E-03 0.1397132E-03 0.0000000E+00 0.0000000E+00 4 SO4-- -.1350481E-04 -.1350572E-04 0.9074377E-09 0.0000000E+00 5 HCO3- 0.3548300E-04 0.3548300E-04 0.0000000E+00 0.0000000E+00 6 HS- 0.4654228E-04 0.4654319E-04 -.9074377E-09 0.0000000E+00 7 Al+++ 0.4775352E-05 0.4706902E-05 0.6845040E-07 0.0000000E+00 8 H4SiO4 0.1215302E-01 0.1215281E-01 0.2140693E-06 0.0000000E+00 9 Ca++ 0.2080835E-06 0.1950231E-06 0.1306041E-07 0.0000000E+00 10 Mg++ 0.8368328E-10 0.8368328E-10 0.0000000E+00 0.0000000E+00 11 Fe++ 0.3259227E-07 0.2533277E-07 0.7259502E-08 0.0000000E+00 12 K+ 0.1412294E-03 0.1412294E-03 0.0000000E+00 0.0000000E+00 13 Na+ 0.2003215E-01 0.2003208E-01 0.6700296E-07 0.0000000E+00 14 Mn++ 0.2251939E-08 0.2251939E-08 0.0000000E+00 0.0000000E+00 15 F- 0.2240000E-06 0.2240000E-06 0.0000000E+00 0.0000000E+00 16 HPO4-- 0.4168819E-07 0.4168819E-07 0.0000000E+00 0.0000000E+00 Chg. balance for solid moles: 0.2647E-22 Mass of aqueous solution: 0.899624E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 0.0003100 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 0.6700E-07 -7.174 0.1757E-04 -4.755 89.00 0.6745E-05 andradite 0.3630E-08 -8.440 0.1845E-05 -5.734 9.344 0.4792E-06 grossular 0.7237E-09 -9.140 0.3260E-06 -6.487 1.651 0.9071E-07 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8338E+00 0.8338E+00 1.0000 -0.079 grossular 0.1662E+00 0.1662E+00 1.0000 -0.779 Solid products produced: Mass = 0.000020 g Volume = 0.000007 cm3 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.0003100 moles log = -3.5086 Original solution: 1000.0103000 g Original solution / Rock added: 3225839.68 (Water/Rock Ratio), log = 6.5086 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0470 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9748E+00 0.9856 0.1006E+01 0.1021E+01 CO2,gas 0.1201E-06 1.0069 0.1266E-06 0.1258E-06 CH4,gas 0.1914E-01 1.0123 0.2029E-01 0.2004E-01 H2,gas 0.6041E-02 1.0006 0.6329E-02 0.6325E-02 H2S,gas 0.1867E-06 0.9959 0.1946E-06 0.1954E-06 S2,gas 0.3391E-28 1.0000 0.3550E-28 0.3550E-28 CO,gas 0.2040E-12 1.0000 0.2136E-12 0.2136E-12 SO3,gas 0.3230E-46 1.0000 0.3382E-46 0.3382E-46 SO2,gas 0.7953E-26 1.0000 0.8327E-26 0.8327E-26 HF,gas 0.2481E-15 1.0000 0.2597E-15 0.2597E-15 HCl,gas 0.2978E-17 1.0000 0.3119E-17 0.3119E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 17 albite -0.38 -0.38 0.00 0.000 0.11184E-10 23 andradite 39.01 39.01 0.00 0.000 0.00000E+00 24 grossular 32.73 32.73 0.00 0.000 0.24265E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -15.26 -8.60 -2.865 0.14678E+05 -6.897 3 CH4,gas 4.54 1.15 -3.39 -0.848 0.57914E+04 -1.693 4 H2,gas 8.00 4.10 -3.90 -2.227 0.66551E+04 -2.199 5 H2S,gas -6.23 -14.64 -8.41 -4.205 0.14359E+05 -6.711 6 S2,gas -7.34 -37.48 -30.15 -4.638 0.51478E+05 -28.450 7 CO,gas 3.21 -11.15 -14.37 -4.421 0.24535E+05 -12.670 8 SO3,gas 17.12 -31.05 -48.17 -12.042 0.82249E+05 -46.471 9 SO2,gas 0.83 -26.95 -27.78 -7.408 0.47431E+05 -26.080 10 HF,gas 0.47 -16.81 -17.28 -8.642 0.29513E+05 -15.585 11 HCl,gas 5.19 -14.02 -19.21 -9.603 0.32792E+05 -17.506 12 acmite 7.71 6.61 -1.10 -0.114 0.18770E+04 16 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 20 spessartine 24.46 19.72 -4.74 -0.237 0.80909E+04 21 analcite 3.32 2.77 -0.55 -0.061 0.93978E+03 27 annite 20.12 17.39 -2.73 -0.152 0.46695E+04 28 phlogopite 27.06 25.38 -1.68 -0.093 0.28705E+04 30 anorthite 12.71 8.22 -4.49 -0.346 0.76745E+04 33 apatite-OH -18.15 -18.37 -0.21 -0.017 0.36638E+03 34 apatite-F -34.30 -35.18 -0.88 -0.073 0.14993E+04 38 aragonite 0.97 -2.20 -3.17 -1.056 0.54072E+04 39 brucite 12.57 9.29 -3.28 -0.656 0.55981E+04 40 calcite 0.81 -2.20 -3.01 -1.004 0.51430E+04 41 carnegieite-low 9.02 5.93 -3.10 -0.442 0.52872E+04 42 carnegieite-high 10.09 5.93 -4.17 -0.595 0.71142E+04 43 carpholite-Mg 8.58 4.45 -4.13 -0.276 0.70565E+04 44 carpholite-Fe 6.71 1.78 -4.93 -0.329 0.84147E+04 45 celadonite 5.34 3.65 -1.69 -0.100 0.28915E+04 46 celadonite-Fe 3.88 0.98 -2.89 -0.170 0.49403E+04 47 chrysotile 23.89 21.56 -2.33 -0.194 0.39837E+04 49 clinochlore 39.07 38.45 -0.62 -0.019 0.10510E+04 50 daphnite 28.97 25.13 -3.84 -0.120 0.65497E+04 52 chlorite-Al-free 47.17 43.12 -4.05 -0.169 0.69226E+04 54 chloritoid-Fe 9.17 4.94 -4.23 -0.282 0.72292E+04 55 chloritoid-Mn 11.40 7.55 -3.85 -0.257 0.65705E+04 57 coesite -2.38 -3.16 -0.78 -0.260 0.13306E+04 64 cristobalite -2.56 -3.16 -0.59 -0.198 0.10159E+04 66 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71234E+04 68 diaspore 2.87 0.74 -2.14 -0.356 0.36517E+04 69 diamond -3.10 -7.05 -3.95 -1.129 0.67444E+04 70 diopside 16.18 16.04 -0.15 -0.015 0.24888E+03 71 hedenbergite 14.21 13.37 -0.84 -0.084 0.14302E+04 74 enstatite 17.26 12.27 -5.00 -0.500 0.85299E+04 76 clinoenstatite 17.17 12.27 -4.90 -0.490 0.83614E+04 78 epidote 24.67 22.69 -1.98 -0.096 0.33796E+04 79 clinozoisite 22.81 18.85 -3.95 -0.180 0.67520E+04 80 epidote-Fe 29.84 26.53 -3.31 -0.172 0.56538E+04 81 fayalite 14.05 10.09 -3.95 -0.564 0.67461E+04 82 ferrosilite 11.15 6.94 -4.21 -0.421 0.71885E+04 86 gibbsite 4.08 0.74 -3.34 -0.478 0.57103E+04 87 glaucophane 22.97 20.79 -2.18 -0.059 0.37278E+04 88 glaucophane-Fe 17.28 12.80 -4.48 -0.121 0.76479E+04 89 graphite -3.55 -7.05 -3.51 -1.002 0.59867E+04 90 greenalite 16.14 13.56 -2.58 -0.215 0.43968E+04 93 hematite 12.57 9.15 -3.42 -0.414 0.58365E+04 94 heulandite -5.83 -7.56 -1.73 -0.079 0.29603E+04 98 jadeite 4.22 2.77 -1.44 -0.144 0.24653E+04 100 kalsilite 7.58 3.82 -3.76 -0.537 0.64197E+04 101 kaolinite -1.33 -4.84 -3.51 -0.319 0.59895E+04 104 laumontite 2.88 1.90 -0.98 -0.065 0.16706E+04 105 lawsonite 9.62 8.22 -1.40 -0.093 0.23911E+04 106 leucite 4.12 0.67 -3.45 -0.345 0.58908E+04 108 lizardite 23.24 21.56 -1.68 -0.140 0.28763E+04 110 magnetite 20.09 15.77 -4.31 -0.352 0.73666E+04 111 minnesotaite 10.39 7.25 -3.13 -0.184 0.53517E+04 115 manganosite 14.06 9.24 -4.82 -1.205 0.82298E+04 119 microcline -2.49 -2.49 0.00 0.000 0.26083E-01 123 muscovite 2.58 -1.02 -3.60 -0.212 0.61450E+04 124 paragonite 4.24 1.09 -3.15 -0.185 0.53841E+04 125 nepheline 8.34 5.93 -2.41 -0.345 0.41195E+04 137 phlogopite-Na 29.65 27.49 -2.16 -0.120 0.36893E+04 139 prehnite 19.37 18.12 -1.26 -0.074 0.21433E+04 140 prehnite-Fe 22.50 21.96 -0.54 -0.033 0.92593E+03 141 pumpellyite-Fe 46.27 43.59 -2.68 -0.059 0.45694E+04 142 pumpellyite-Mg 48.99 46.26 -2.74 -0.061 0.46727E+04 146 pyrrhotite -4.26 -8.01 -3.75 -1.252 0.64109E+04 147 pyrrhotiteFe0.875 -6.02 -9.35 -3.33 -1.226 0.56940E+04 148 pyroxmangite 7.40 6.08 -1.32 -0.263 0.22466E+04 149 pyrophyllite -6.18 -11.15 -4.98 -0.311 0.84955E+04 150 quartz -2.99 -3.16 -0.17 -0.055 0.28327E+03 155 rhodonite 7.45 6.08 -1.36 -0.273 0.23269E+04 156 sanidine -1.28 -2.49 -1.21 -0.093 0.20678E+04 166 stilbite -7.52 -7.56 -0.04 -0.002 0.66519E+02 167 stilpnomelane-Fe 13.02 12.47 -0.54 -0.016 0.92558E+03 168 stilpnomelane-Mg 27.44 25.80 -1.64 -0.049 0.28034E+04 174 talc 16.49 15.25 -1.24 -0.073 0.21214E+04 177 tephroite 18.09 15.32 -2.76 -0.395 0.47205E+04 181 tridymite -2.63 -3.16 -0.53 -0.176 0.90325E+03 182 tremolite 47.87 47.32 -0.55 -0.015 0.93814E+03 183 ferroactinolite 38.45 34.00 -4.46 -0.120 0.76106E+04 184 troilite-low -4.41 -8.01 -3.60 -1.201 0.61537E+04 190 wairakite 3.95 1.90 -2.05 -0.120 0.34926E+04 191 walstromite 11.51 9.90 -1.61 -0.322 0.27461E+04 192 wollastonite 10.46 9.90 -0.56 -0.112 0.95653E+03 193 pseudo-wollastonite 11.00 9.90 -1.10 -0.220 0.18764E+04 194 zoisite 22.85 18.85 -4.00 -0.182 0.68261E+04 195 akaganeite 7.75 4.57 -3.18 -0.688 0.54308E+04 202 chalcedony -2.80 -3.16 -0.35 -0.118 0.60257E+03 204 montmorillonite-Ca -2.29 -6.17 -3.88 -0.240 0.66304E+04 205 montmorillonite-K -2.24 -6.27 -4.03 -0.247 0.68824E+04 206 montmorillonite-Mg -2.48 -6.80 -4.32 -0.267 0.73685E+04 207 montmorillonite-Na -2.04 -5.57 -3.54 -0.217 0.60373E+04 208 nontronite-Ca 3.21 -0.04 -3.25 -0.211 0.55489E+04 209 nontronite-H 2.53 -2.19 -4.72 -0.317 0.80631E+04 210 nontronite-K 3.34 -0.13 -3.47 -0.223 0.59242E+04 211 nontronite-Mg 3.07 -0.66 -3.73 -0.242 0.63711E+04 212 nontronite-Na 3.52 0.57 -2.95 -0.190 0.50450E+04 228 tobermorite 9.82 7.72 -2.10 -0.574 0.35900E+04 234 alabandite -0.98 -5.40 -4.42 -1.475 0.75536E+04 237 boehmite 4.41 0.74 -3.67 -0.612 0.62686E+04 239 ferrous-oxide 9.81 6.63 -3.19 -0.797 0.54409E+04 245 silica-amorphous -2.09 -3.16 -1.06 -0.355 0.18167E+04 247 an20ab80 2.02 1.34 -0.68 -0.052 0.11640E+04 248 an25ab75 2.65 1.77 -0.88 -0.068 0.15020E+04 249 an30ab70 3.28 2.20 -1.08 -0.083 0.18496E+04 250 tr.625ac.25prg.125 45.16 44.94 -0.23 -0.006 0.39182E+03 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 0.0000100 MOLES Current total amount of reactant added: 0.0003100 MOLES New total amount of reactant added: 0.0003200 MOLES Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.5508E-08 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 6 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 0.0003200 Water: Moles liquid = 0.4985E+02 kg liquid = 0.8981E+00 Moles total = 0.4985E+02 kg total = 0.8980E+00 Activity = 1.0000 Stoichiometric ionic strength = .1135062E-01 Osmotic coef. = 0.9683 True ionic strength = .2003551E-01 Chg. balance for total moles = -.5508E-08 Max. difference allowed = 0.1398E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.88771E-10 -10.0517 0.74586E-10 -10.1273 0.84021E+00 -0.0756 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.15493E-03 -3.8099 0.12939E-03 -3.8881 0.83515E+00 -0.0782 4 SO4-- 0.32339E-10 -10.4903 0.16790E-10 -10.7749 0.51919E+00 -0.2847 5 HCO3- 0.91749E-05 -5.0374 0.76736E-05 -5.1150 0.83637E+00 -0.0776 6 HS- 0.37051E-04 -4.4312 0.30948E-04 -4.5094 0.83527E+00 -0.0782 7 Al+++ 0.97592E-29 -29.0106 0.22535E-29 -29.6471 0.23091E+00 -0.6366 8 H4SiO4 0.69941E-03 -3.1553 0.69941E-03 -3.1553 0.10000E+01 0.0000 9 Ca++ 0.12267E-06 -6.9113 0.63220E-07 -7.1991 0.51538E+00 -0.2879 10 Mg++ 0.21136E-10 -10.6750 0.10843E-10 -10.9648 0.51302E+00 -0.2899 11 Fe++ 0.45609E-13 -13.3409 0.23424E-13 -13.6303 0.51358E+00 -0.2894 12 K+ 0.15651E-03 -3.8055 0.13093E-03 -3.8830 0.83657E+00 -0.0775 13 Na+ 0.19861E-01 -1.7020 0.16584E-01 -1.7803 0.83500E+00 -0.0783 14 Mn++ 0.18732E-10 -10.7274 0.96286E-11 -11.0164 0.51401E+00 -0.2890 15 F- 0.25306E-06 -6.5968 0.21091E-06 -6.6759 0.83343E+00 -0.0791 16 HPO4-- 0.45320E-07 -7.3437 0.23533E-07 -7.6283 0.51927E+00 -0.2846 18 HSiO3- 0.10484E-01 -1.9795 0.87560E-02 -2.0577 0.83515E+00 -0.0782 19 Ca(HSiO3)+ 0.15066E-07 -7.8220 0.12606E-07 -7.8994 0.83675E+00 -0.0774 20 Mg(HSiO3)+ 0.32159E-11 -11.4927 0.26909E-11 -11.5701 0.83675E+00 -0.0774 21 NaHSiO3,aq 0.23486E-02 -2.6292 0.23486E-02 -2.6292 0.10000E+01 0.0000 22 AlO+ 0.65861E-16 -16.1814 0.55110E-16 -16.2588 0.83675E+00 -0.0774 24 HAlO2,aq 0.14715E-09 -9.8323 0.14715E-09 -9.8323 0.10000E+01 0.0000 25 AlO2- 0.52385E-05 -5.2808 0.43670E-05 -5.3598 0.83364E+00 -0.0790 26 CH4,aq 0.13787E-04 -4.8605 0.13739E-04 -4.8620 0.99654E+00 -0.0015 27 C2H6,aq 0.67782E-14 -14.1689 0.67547E-14 -14.1704 0.99654E+00 -0.0015 31 CO,aq 0.14678E-15 -15.8333 0.14678E-15 -15.8333 0.10000E+01 0.0000 32 CO2,aq 0.12272E-08 -8.9111 0.12230E-08 -8.9126 0.99654E+00 -0.0015 33 CO3-2 0.17345E-04 -4.7608 0.89864E-05 -5.0464 0.51809E+00 -0.2856 34 CaCO3,aq 0.71236E-08 -8.1473 0.71236E-08 -8.1473 0.10000E+01 0.0000 35 Ca(HCO3)+ 0.14799E-10 -10.8298 0.12383E-10 -10.9072 0.83675E+00 -0.0774 36 CaCl+ 0.15820E-10 -10.8008 0.13237E-10 -10.8782 0.83675E+00 -0.0774 37 CaCl2,aq 0.40691E-15 -15.3905 0.40691E-15 -15.3905 0.10000E+01 0.0000 38 CaF+ 0.23265E-12 -12.6333 0.19467E-12 -12.7107 0.83675E+00 -0.0774 39 CaOH+ 0.72194E-07 -7.1415 0.60409E-07 -7.2189 0.83675E+00 -0.0774 40 CaSO4,aq 0.33706E-15 -15.4723 0.33706E-15 -15.4723 0.10000E+01 0.0000 41 HCl,aq 0.17684E-14 -14.7524 0.17684E-14 -14.7524 0.10000E+01 0.0000 45 HF,aq 0.10769E-12 -12.9678 0.10769E-12 -12.9678 0.10000E+01 0.0000 48 FeCl+ 0.57331E-17 -17.2416 0.47972E-17 -17.3190 0.83675E+00 -0.0774 51 FeF+ 0.30171E-18 -18.5204 0.25246E-18 -18.5978 0.83675E+00 -0.0774 53 FeO,aq 0.16365E-09 -9.7861 0.16365E-09 -9.7861 0.10000E+01 0.0000 54 FeOH+ 0.12217E-10 -10.9130 0.10223E-10 -10.9904 0.83675E+00 -0.0774 55 HFeO2- 0.27489E-07 -7.5608 0.22957E-07 -7.6391 0.83515E+00 -0.0782 56 FeO+ 0.13332E-16 -16.8751 0.11156E-16 -16.9525 0.83675E+00 -0.0774 58 FeO2- 0.49132E-09 -9.3086 0.41032E-09 -9.3869 0.83515E+00 -0.0782 59 HFeO2,aq 0.38924E-11 -11.4098 0.38924E-11 -11.4098 0.10000E+01 0.0000 60 H2,aq 0.47942E-05 -5.3193 0.47776E-05 -5.3208 0.99654E+00 -0.0015 61 KCl,aq 0.30704E-09 -9.5128 0.30704E-09 -9.5128 0.10000E+01 0.0000 63 KOH,aq 0.74968E-06 -6.1251 0.74968E-06 -6.1251 0.10000E+01 0.0000 64 KSO4- 0.40847E-13 -13.3888 0.34113E-13 -13.4671 0.83515E+00 -0.0782 65 MgCO3,aq 0.30626E-12 -12.5139 0.30626E-12 -12.5139 0.10000E+01 0.0000 66 Mg(HCO3)+ 0.25937E-14 -14.5861 0.21703E-14 -14.6635 0.83675E+00 -0.0774 67 MgCl+ 0.24593E-14 -14.6092 0.20578E-14 -14.6866 0.83675E+00 -0.0774 68 MgF+ 0.14782E-15 -15.8303 0.12369E-15 -15.9077 0.83675E+00 -0.0774 69 MgOH+ 0.68519E-10 -10.1642 0.57333E-10 -10.2416 0.83675E+00 -0.0774 71 MnF+ 0.40879E-16 -16.3885 0.34205E-16 -16.4659 0.83675E+00 -0.0774 72 MnO,aq 0.17924E-08 -8.7466 0.17924E-08 -8.7466 0.10000E+01 0.0000 73 MnOH+ 0.46653E-09 -9.3311 0.39037E-09 -9.4085 0.83675E+00 -0.0774 74 MnO2-2 0.20639E-10 -10.6853 0.10693E-10 -10.9709 0.51809E+00 -0.2856 75 HMnO2- 0.20922E-09 -9.6794 0.17473E-09 -9.7576 0.83515E+00 -0.0782 78 MnCl+ 0.91684E-14 -14.0377 0.76717E-14 -14.1151 0.83675E+00 -0.0774 79 MnSO4,aq 0.46671E-19 -19.3309 0.46671E-19 -19.3309 0.10000E+01 0.0000 80 NaCl,aq 0.71111E-06 -6.1481 0.71111E-06 -6.1481 0.10000E+01 0.0000 81 NaF,aq 0.81888E-09 -9.0868 0.81888E-09 -9.0868 0.10000E+01 0.0000 82 NaOH,aq 0.95532E-04 -4.0199 0.95532E-04 -4.0199 0.10000E+01 0.0000 84 OH- 0.92922E-02 -2.0319 0.77464E-02 -2.1109 0.83364E+00 -0.0790 89 HPO3-2 0.67629E-15 -15.1699 0.35038E-15 -15.4555 0.51809E+00 -0.2856 91 H2PO3- 0.62749E-19 -19.2024 0.52405E-19 -19.2806 0.83515E+00 -0.0782 92 H3PO4,aq 0.91562E-18 -18.0383 0.91562E-18 -18.0383 0.10000E+01 0.0000 93 H2PO4- 0.38734E-10 -10.4119 0.32379E-10 -10.4897 0.83594E+00 -0.0778 94 PO4-3 0.10614E-08 -8.9741 0.25743E-09 -9.5893 0.24253E+00 -0.6152 98 HP2O7-3 0.95213E-18 -18.0213 0.22008E-18 -18.6574 0.23114E+00 -0.6361 99 P2O7-4 0.91500E-17 -17.0386 0.70491E-18 -18.1519 0.77039E-01 -1.1133 100 H2S,aq 0.71588E-08 -8.1452 0.71340E-08 -8.1467 0.99654E+00 -0.0015 101 S2-2 0.85738E-14 -14.0668 0.44420E-14 -14.3524 0.51809E+00 -0.2856 107 SO3-2 0.19833E-16 -16.7026 0.10424E-16 -16.9820 0.52559E+00 -0.2794 108 HSO3- 0.58290E-19 -19.2344 0.48681E-19 -19.3126 0.83515E+00 -0.0782 109 HSO4- 0.14409E-17 -17.8414 0.12069E-17 -17.9183 0.83757E+00 -0.0770 Charge balance for all species = -.6133E-08 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.8877090E-10 -.2226105E-01 -.2239879E+02 0.0000 2 H2O 0.1000000E+01 0.5550484E+02 0.9981975E+06 0.0000 3 Cl- 0.1549265E-03 0.1556379E-03 0.5508237E+01 6.2392 4 SO4-- 0.3233878E-10 -.1498561E-04 -.1437038E+01 9.4797 5 HCO3- 0.9174901E-05 0.4031579E-04 0.2455679E+01 5.0123 6 HS- 0.3705099E-04 0.5204379E-04 0.1718199E+01 5.6180 7 Al+++ 0.9759211E-29 0.5238633E-05 0.1411004E+00 0.7349 8 H4SiO4 0.6994143E-03 0.1353228E-01 0.1298399E+04 -3.1553 9 Ca++ 0.1226664E-06 0.2170808E-06 0.8685035E-02 13.0555 10 Mg++ 0.2113618E-10 0.9318228E-10 0.2261508E-05 9.2898 11 Fe++ 0.4560940E-13 0.2815977E-07 0.1569904E-02 6.6243 12 K+ 0.1565106E-03 0.1572605E-03 0.6138509E+01 6.2444 13 Na+ 0.1986114E-01 0.2230595E-01 0.5119176E+03 8.3470 14 Mn++ 0.1873247E-10 0.2507560E-08 0.1375208E-03 9.2383 15 F- 0.2530614E-06 0.2538806E-06 0.4814837E-02 3.4514 16 HPO4-- 0.4532013E-07 0.4642027E-07 0.4447624E-02 12.6264 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.1999208E-01 -.1999176E-01 -.3214880E-06 0.0000000E+00 2 H2O 0.4984667E+02 0.4984667E+02 -.2808277E-06 0.0000000E+00 3 Cl- 0.1397722E-03 0.1397722E-03 0.0000000E+00 0.0000000E+00 4 SO4-- -.1345706E-04 -.1345797E-04 0.9128880E-09 0.0000000E+00 5 HCO3- 0.3620600E-04 0.3620600E-04 0.0000000E+00 0.0000000E+00 6 HS- 0.4673753E-04 0.4673844E-04 -.9128880E-09 0.0000000E+00 7 Al+++ 0.4775352E-05 0.4704606E-05 0.7074558E-07 0.0000000E+00 8 H4SiO4 0.1215302E-01 0.1215280E-01 0.2210141E-06 0.0000000E+00 9 Ca++ 0.2080835E-06 0.1949515E-06 0.1313196E-07 0.0000000E+00 10 Mg++ 0.8368328E-10 0.8368328E-10 0.0000000E+00 0.0000000E+00 11 Fe++ 0.3259227E-07 0.2528917E-07 0.7303104E-08 0.0000000E+00 12 K+ 0.1412294E-03 0.1412294E-03 0.0000000E+00 0.0000000E+00 13 Na+ 0.2003215E-01 0.2003208E-01 0.6929404E-07 0.0000000E+00 14 Mn++ 0.2251939E-08 0.2251939E-08 0.0000000E+00 0.0000000E+00 15 F- 0.2280000E-06 0.2280000E-06 0.0000000E+00 0.0000000E+00 16 HPO4-- 0.4168819E-07 0.4168819E-07 0.0000000E+00 0.0000000E+00 Chg. balance for solid moles: 0.1323E-22 Mass of aqueous solution: 0.899624E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 0.0003200 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 0.6929E-07 -7.159 0.1817E-04 -4.741 89.28 0.6975E-05 andradite 0.3652E-08 -8.438 0.1856E-05 -5.732 9.117 0.4821E-06 grossular 0.7258E-09 -9.139 0.3269E-06 -6.486 1.606 0.9096E-07 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8342E+00 0.8342E+00 1.0000 -0.079 grossular 0.1658E+00 0.1658E+00 1.0000 -0.780 Solid products produced: Mass = 0.000020 g Volume = 0.000008 cm3 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.0003200 moles log = -3.4949 Original solution: 1000.0103000 g Original solution / Rock added: 3125032.19 (Water/Rock Ratio), log = 6.4949 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0469 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9749E+00 0.9856 0.1006E+01 0.1021E+01 CO2,gas 0.1241E-06 1.0069 0.1308E-06 0.1300E-06 CH4,gas 0.1908E-01 1.0123 0.2022E-01 0.1998E-01 H2,gas 0.5988E-02 1.0006 0.6272E-02 0.6269E-02 H2S,gas 0.1881E-06 0.9959 0.1961E-06 0.1969E-06 S2,gas 0.3505E-28 1.0000 0.3669E-28 0.3669E-28 CO,gas 0.2089E-12 1.0000 0.2187E-12 0.2187E-12 SO3,gas 0.3373E-46 1.0000 0.3532E-46 0.3532E-46 SO2,gas 0.8232E-26 1.0000 0.8618E-26 0.8618E-26 HF,gas 0.2526E-15 1.0000 0.2644E-15 0.2644E-15 HCl,gas 0.2981E-17 1.0000 0.3120E-17 0.3120E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 17 albite -0.38 -0.38 0.00 0.000 -0.94784E-12 23 andradite 39.01 39.01 0.00 0.000 0.12132E-10 24 grossular 32.73 32.73 0.00 0.000 0.00000E+00 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -15.24 -8.58 -2.861 0.14654E+05 -6.883 3 CH4,gas 4.54 1.15 -3.39 -0.848 0.57936E+04 -1.694 4 H2,gas 8.00 4.10 -3.90 -2.229 0.66618E+04 -2.203 5 H2S,gas -6.23 -14.64 -8.41 -4.203 0.14354E+05 -6.708 6 S2,gas -7.34 -37.47 -30.13 -4.636 0.51454E+05 -28.435 7 CO,gas 3.21 -11.14 -14.36 -4.418 0.24518E+05 -12.660 8 SO3,gas 17.12 -31.03 -48.15 -12.038 0.82217E+05 -46.452 9 SO2,gas 0.83 -26.93 -27.76 -7.404 0.47406E+05 -26.065 10 HF,gas 0.47 -16.80 -17.28 -8.638 0.29499E+05 -15.578 11 HCl,gas 5.19 -14.02 -19.20 -9.602 0.32792E+05 -17.506 12 acmite 7.71 6.61 -1.10 -0.114 0.18748E+04 16 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 20 spessartine 24.46 19.72 -4.74 -0.237 0.80910E+04 21 analcite 3.32 2.77 -0.55 -0.061 0.93990E+03 27 annite 20.12 17.39 -2.74 -0.152 0.46731E+04 28 phlogopite 27.06 25.38 -1.68 -0.093 0.28712E+04 30 anorthite 12.71 8.21 -4.50 -0.346 0.76760E+04 33 apatite-OH -18.15 -18.37 -0.22 -0.017 0.37196E+03 34 apatite-F -34.30 -35.17 -0.87 -0.073 0.14916E+04 38 aragonite 0.97 -2.19 -3.15 -1.051 0.53842E+04 39 brucite 12.57 9.29 -3.28 -0.656 0.55983E+04 40 calcite 0.81 -2.19 -3.00 -1.000 0.51200E+04 41 carnegieite-low 9.02 5.93 -3.10 -0.442 0.52874E+04 42 carnegieite-high 10.09 5.93 -4.17 -0.595 0.71144E+04 43 carpholite-Mg 8.58 4.45 -4.13 -0.276 0.70570E+04 44 carpholite-Fe 6.71 1.78 -4.93 -0.329 0.84162E+04 45 celadonite 5.34 3.65 -1.69 -0.100 0.28917E+04 46 celadonite-Fe 3.88 0.98 -2.89 -0.170 0.49413E+04 47 chrysotile 23.89 21.56 -2.33 -0.194 0.39842E+04 49 clinochlore 39.07 38.45 -0.62 -0.019 0.10523E+04 50 daphnite 28.97 25.13 -3.84 -0.120 0.65558E+04 52 chlorite-Al-free 47.17 43.12 -4.05 -0.169 0.69235E+04 54 chloritoid-Fe 9.17 4.94 -4.23 -0.282 0.72307E+04 55 chloritoid-Mn 11.40 7.55 -3.85 -0.257 0.65709E+04 57 coesite -2.38 -3.16 -0.78 -0.260 0.13305E+04 64 cristobalite -2.56 -3.16 -0.59 -0.198 0.10158E+04 66 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71234E+04 68 diaspore 2.87 0.73 -2.14 -0.356 0.36519E+04 69 diamond -3.10 -7.05 -3.94 -1.127 0.67334E+04 70 diopside 16.18 16.03 -0.15 -0.015 0.25015E+03 71 hedenbergite 14.21 13.37 -0.84 -0.084 0.14324E+04 74 enstatite 17.26 12.27 -5.00 -0.500 0.85301E+04 76 clinoenstatite 17.17 12.27 -4.90 -0.490 0.83617E+04 78 epidote 24.67 22.69 -1.98 -0.096 0.33801E+04 79 clinozoisite 22.81 18.85 -3.96 -0.180 0.67549E+04 80 epidote-Fe 29.84 26.53 -3.31 -0.172 0.56520E+04 81 fayalite 14.05 10.09 -3.95 -0.565 0.67484E+04 82 ferrosilite 11.15 6.94 -4.21 -0.421 0.71907E+04 86 gibbsite 4.08 0.73 -3.34 -0.478 0.57105E+04 87 glaucophane 22.97 20.79 -2.18 -0.059 0.37283E+04 88 glaucophane-Fe 17.28 12.79 -4.48 -0.121 0.76512E+04 89 graphite -3.55 -7.05 -3.50 -1.000 0.59757E+04 90 greenalite 16.14 13.56 -2.58 -0.215 0.44001E+04 93 hematite 12.57 9.15 -3.42 -0.414 0.58322E+04 94 heulandite -5.83 -7.56 -1.73 -0.079 0.29612E+04 98 jadeite 4.22 2.77 -1.44 -0.144 0.24654E+04 100 kalsilite 7.58 3.82 -3.76 -0.537 0.64199E+04 101 kaolinite -1.33 -4.84 -3.51 -0.319 0.59898E+04 104 laumontite 2.88 1.90 -0.98 -0.065 0.16719E+04 105 lawsonite 9.62 8.21 -1.40 -0.093 0.23926E+04 106 leucite 4.12 0.67 -3.45 -0.345 0.58910E+04 108 lizardite 23.24 21.56 -1.68 -0.140 0.28768E+04 110 magnetite 20.09 15.77 -4.31 -0.352 0.73636E+04 111 minnesotaite 10.39 7.25 -3.14 -0.184 0.53548E+04 115 manganosite 14.06 9.24 -4.82 -1.205 0.82298E+04 119 microcline -2.49 -2.49 0.00 0.000 0.26924E-01 123 muscovite 2.58 -1.02 -3.60 -0.212 0.61455E+04 124 paragonite 4.24 1.09 -3.15 -0.186 0.53845E+04 125 nepheline 8.34 5.93 -2.41 -0.345 0.41198E+04 137 phlogopite-Na 29.65 27.49 -2.16 -0.120 0.36900E+04 139 prehnite 19.37 18.12 -1.26 -0.074 0.21460E+04 140 prehnite-Fe 22.50 21.96 -0.54 -0.033 0.92622E+03 141 pumpellyite-Fe 46.27 43.59 -2.68 -0.060 0.45761E+04 142 pumpellyite-Mg 48.99 46.25 -2.74 -0.061 0.46785E+04 146 pyrrhotite -4.26 -8.01 -3.75 -1.251 0.64065E+04 147 pyrrhotiteFe0.875 -6.02 -9.35 -3.33 -1.225 0.56887E+04 148 pyroxmangite 7.40 6.08 -1.32 -0.263 0.22465E+04 149 pyrophyllite -6.18 -11.15 -4.98 -0.311 0.84955E+04 150 quartz -2.99 -3.16 -0.17 -0.055 0.28315E+03 155 rhodonite 7.45 6.08 -1.36 -0.273 0.23268E+04 156 sanidine -1.28 -2.49 -1.21 -0.093 0.20678E+04 166 stilbite -7.52 -7.56 -0.04 -0.002 0.67407E+02 167 stilpnomelane-Fe 13.02 12.47 -0.55 -0.016 0.93118E+03 168 stilpnomelane-Mg 27.44 25.80 -1.64 -0.049 0.28042E+04 174 talc 16.49 15.25 -1.24 -0.073 0.21217E+04 177 tephroite 18.09 15.32 -2.76 -0.395 0.47204E+04 181 tridymite -2.63 -3.16 -0.53 -0.176 0.90313E+03 182 tremolite 47.87 47.32 -0.55 -0.015 0.94093E+03 183 ferroactinolite 38.45 33.99 -4.46 -0.121 0.76182E+04 184 troilite-low -4.41 -8.01 -3.60 -1.200 0.61493E+04 190 wairakite 3.95 1.90 -2.05 -0.120 0.34938E+04 191 walstromite 11.51 9.90 -1.61 -0.322 0.27472E+04 192 wollastonite 10.46 9.90 -0.56 -0.112 0.95768E+03 193 pseudo-wollastonite 11.00 9.90 -1.10 -0.220 0.18775E+04 194 zoisite 22.85 18.85 -4.00 -0.182 0.68289E+04 195 akaganeite 7.75 4.58 -3.18 -0.687 0.54287E+04 202 chalcedony -2.80 -3.16 -0.35 -0.118 0.60245E+03 204 montmorillonite-Ca -2.29 -6.17 -3.88 -0.240 0.66306E+04 205 montmorillonite-K -2.24 -6.27 -4.03 -0.247 0.68824E+04 206 montmorillonite-Mg -2.48 -6.80 -4.32 -0.267 0.73685E+04 207 montmorillonite-Na -2.04 -5.57 -3.54 -0.217 0.60373E+04 208 nontronite-Ca 3.21 -0.03 -3.25 -0.211 0.55445E+04 209 nontronite-H 2.53 -2.19 -4.72 -0.316 0.80585E+04 210 nontronite-K 3.34 -0.13 -3.47 -0.223 0.59196E+04 211 nontronite-Mg 3.07 -0.65 -3.73 -0.242 0.63665E+04 212 nontronite-Na 3.52 0.57 -2.95 -0.189 0.50405E+04 228 tobermorite 9.82 7.72 -2.10 -0.574 0.35909E+04 234 alabandite -0.98 -5.40 -4.42 -1.474 0.75480E+04 237 boehmite 4.41 0.73 -3.67 -0.612 0.62689E+04 239 ferrous-oxide 9.81 6.62 -3.19 -0.797 0.54421E+04 245 silica-amorphous -2.09 -3.16 -1.06 -0.355 0.18166E+04 247 an20ab80 2.02 1.34 -0.68 -0.052 0.11643E+04 248 an25ab75 2.65 1.77 -0.88 -0.068 0.15024E+04 249 an30ab70 3.28 2.20 -1.08 -0.083 0.18501E+04 250 tr.625ac.25prg.125 45.16 44.93 -0.23 -0.006 0.39592E+03 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 0.0000100 MOLES Current total amount of reactant added: 0.0003200 MOLES New total amount of reactant added: 0.0003300 MOLES Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.5508E-08 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 6 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 0.0003300 Water: Moles liquid = 0.4985E+02 kg liquid = 0.8981E+00 Moles total = 0.4985E+02 kg total = 0.8980E+00 Activity = 1.0000 Stoichiometric ionic strength = .1135126E-01 Osmotic coef. = 0.9683 True ionic strength = .2003610E-01 Chg. balance for total moles = -.5508E-08 Max. difference allowed = 0.1398E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.88787E-10 -10.0517 0.74599E-10 -10.1273 0.84021E+00 -0.0756 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.15499E-03 -3.8097 0.12944E-03 -3.8879 0.83515E+00 -0.0782 4 SO4-- 0.33724E-10 -10.4721 0.17509E-10 -10.7567 0.51919E+00 -0.2847 5 HCO3- 0.94692E-05 -5.0237 0.79197E-05 -5.1013 0.83637E+00 -0.0776 6 HS- 0.37322E-04 -4.4280 0.31174E-04 -4.5062 0.83527E+00 -0.0782 7 Al+++ 0.97614E-29 -29.0105 0.22540E-29 -29.6470 0.23091E+00 -0.6366 8 H4SiO4 0.69953E-03 -3.1552 0.69953E-03 -3.1552 0.10000E+01 0.0000 9 Ca++ 0.12250E-06 -6.9119 0.63135E-07 -7.1997 0.51537E+00 -0.2879 10 Mg++ 0.21137E-10 -10.6750 0.10843E-10 -10.9648 0.51301E+00 -0.2899 11 Fe++ 0.45555E-13 -13.3415 0.23396E-13 -13.6309 0.51358E+00 -0.2894 12 K+ 0.15651E-03 -3.8055 0.13093E-03 -3.8830 0.83657E+00 -0.0775 13 Na+ 0.19861E-01 -1.7020 0.16584E-01 -1.7803 0.83500E+00 -0.0783 14 Mn++ 0.18739E-10 -10.7273 0.96318E-11 -11.0163 0.51400E+00 -0.2890 15 F- 0.25750E-06 -6.5892 0.21461E-06 -6.6684 0.83343E+00 -0.0791 16 HPO4-- 0.45320E-07 -7.3437 0.23533E-07 -7.6283 0.51926E+00 -0.2846 18 HSiO3- 0.10484E-01 -1.9795 0.87559E-02 -2.0577 0.83515E+00 -0.0782 19 Ca(HSiO3)+ 0.15046E-07 -7.8226 0.12589E-07 -7.9000 0.83675E+00 -0.0774 20 Mg(HSiO3)+ 0.32159E-11 -11.4927 0.26909E-11 -11.5701 0.83675E+00 -0.0774 21 NaHSiO3,aq 0.23485E-02 -2.6292 0.23485E-02 -2.6292 0.10000E+01 0.0000 22 AlO+ 0.65852E-16 -16.1814 0.55102E-16 -16.2588 0.83675E+00 -0.0774 24 HAlO2,aq 0.14710E-09 -9.8324 0.14710E-09 -9.8324 0.10000E+01 0.0000 25 AlO2- 0.52359E-05 -5.2810 0.43649E-05 -5.3600 0.83364E+00 -0.0790 26 CH4,aq 0.13744E-04 -4.8619 0.13697E-04 -4.8634 0.99654E+00 -0.0015 27 C2H6,aq 0.67951E-14 -14.1678 0.67716E-14 -14.1693 0.99654E+00 -0.0015 31 CO,aq 0.15020E-15 -15.8233 0.15020E-15 -15.8233 0.10000E+01 0.0000 32 CO2,aq 0.12668E-08 -8.8973 0.12624E-08 -8.8988 0.99654E+00 -0.0015 33 CO3-2 0.17899E-04 -4.7472 0.92730E-05 -5.0328 0.51808E+00 -0.2856 34 CaCO3,aq 0.73409E-08 -8.1343 0.73409E-08 -8.1343 0.10000E+01 0.0000 35 Ca(HCO3)+ 0.15253E-10 -10.8166 0.12763E-10 -10.8940 0.83675E+00 -0.0774 36 CaCl+ 0.15806E-10 -10.8012 0.13225E-10 -10.8786 0.83675E+00 -0.0774 37 CaCl2,aq 0.40671E-15 -15.3907 0.40671E-15 -15.3907 0.10000E+01 0.0000 38 CaF+ 0.23641E-12 -12.6263 0.19782E-12 -12.7037 0.83675E+00 -0.0774 39 CaOH+ 0.72085E-07 -7.1422 0.60317E-07 -7.2196 0.83675E+00 -0.0774 40 CaSO4,aq 0.35103E-15 -15.4547 0.35103E-15 -15.4547 0.10000E+01 0.0000 41 HCl,aq 0.17695E-14 -14.7522 0.17695E-14 -14.7522 0.10000E+01 0.0000 45 HF,aq 0.10960E-12 -12.9602 0.10960E-12 -12.9602 0.10000E+01 0.0000 48 FeCl+ 0.57287E-17 -17.2419 0.47935E-17 -17.3193 0.83675E+00 -0.0774 51 FeF+ 0.30664E-18 -18.5134 0.25658E-18 -18.5908 0.83675E+00 -0.0774 53 FeO,aq 0.16340E-09 -9.7868 0.16340E-09 -9.7868 0.10000E+01 0.0000 54 FeOH+ 0.12201E-10 -10.9136 0.10209E-10 -10.9910 0.83675E+00 -0.0774 55 HFeO2- 0.27441E-07 -7.5616 0.22918E-07 -7.6398 0.83515E+00 -0.0782 56 FeO+ 0.13372E-16 -16.8738 0.11189E-16 -16.9512 0.83675E+00 -0.0774 58 FeO2- 0.49261E-09 -9.3075 0.41141E-09 -9.3857 0.83515E+00 -0.0782 59 HFeO2,aq 0.39034E-11 -11.4086 0.39034E-11 -11.4086 0.10000E+01 0.0000 60 H2,aq 0.47526E-05 -5.3231 0.47362E-05 -5.3246 0.99654E+00 -0.0015 61 KCl,aq 0.30717E-09 -9.5126 0.30717E-09 -9.5126 0.10000E+01 0.0000 63 KOH,aq 0.74955E-06 -6.1252 0.74955E-06 -6.1252 0.10000E+01 0.0000 64 KSO4- 0.42597E-13 -13.3706 0.35575E-13 -13.4489 0.83515E+00 -0.0782 65 MgCO3,aq 0.31603E-12 -12.5003 0.31603E-12 -12.5003 0.10000E+01 0.0000 66 Mg(HCO3)+ 0.26769E-14 -14.5724 0.22399E-14 -14.6498 0.83675E+00 -0.0774 67 MgCl+ 0.24604E-14 -14.6090 0.20587E-14 -14.6864 0.83675E+00 -0.0774 68 MgF+ 0.15041E-15 -15.8227 0.12586E-15 -15.9001 0.83675E+00 -0.0774 69 MgOH+ 0.68508E-10 -10.1643 0.57324E-10 -10.2417 0.83675E+00 -0.0774 71 MnF+ 0.41610E-16 -16.3808 0.34817E-16 -16.4582 0.83675E+00 -0.0774 72 MnO,aq 0.17924E-08 -8.7466 0.17924E-08 -8.7466 0.10000E+01 0.0000 73 MnOH+ 0.46660E-09 -9.3311 0.39043E-09 -9.4085 0.83675E+00 -0.0774 74 MnO2-2 0.20632E-10 -10.6855 0.10689E-10 -10.9711 0.51808E+00 -0.2856 75 HMnO2- 0.20918E-09 -9.6795 0.17470E-09 -9.7577 0.83515E+00 -0.0782 78 MnCl+ 0.91753E-14 -14.0374 0.76774E-14 -14.1148 0.83675E+00 -0.0774 79 MnSO4,aq 0.48687E-19 -19.3126 0.48687E-19 -19.3126 0.10000E+01 0.0000 80 NaCl,aq 0.71141E-06 -6.1479 0.71141E-06 -6.1479 0.10000E+01 0.0000 81 NaF,aq 0.83324E-09 -9.0792 0.83324E-09 -9.0792 0.10000E+01 0.0000 82 NaOH,aq 0.95515E-04 -4.0199 0.95515E-04 -4.0199 0.10000E+01 0.0000 84 OH- 0.92906E-02 -2.0320 0.77451E-02 -2.1110 0.83364E+00 -0.0790 89 HPO3-2 0.67043E-15 -15.1736 0.34734E-15 -15.4592 0.51808E+00 -0.2856 91 H2PO3- 0.62216E-19 -19.2061 0.51960E-19 -19.2843 0.83515E+00 -0.0782 92 H3PO4,aq 0.91594E-18 -18.0381 0.91594E-18 -18.0381 0.10000E+01 0.0000 93 H2PO4- 0.38741E-10 -10.4118 0.32385E-10 -10.4897 0.83594E+00 -0.0778 94 PO4-3 0.10612E-08 -8.9742 0.25738E-09 -9.5894 0.24253E+00 -0.6152 98 HP2O7-3 0.95231E-18 -18.0212 0.22012E-18 -18.6573 0.23114E+00 -0.6361 99 P2O7-4 0.91502E-17 -17.0386 0.70491E-18 -18.1519 0.77037E-01 -1.1133 100 H2S,aq 0.72123E-08 -8.1419 0.71873E-08 -8.1434 0.99654E+00 -0.0015 101 S2-2 0.87756E-14 -14.0567 0.45465E-14 -14.3423 0.51808E+00 -0.2856 107 SO3-2 0.20504E-16 -16.6882 0.10776E-16 -16.9675 0.52558E+00 -0.2794 108 HSO3- 0.60270E-19 -19.2199 0.50335E-19 -19.2981 0.83515E+00 -0.0782 109 HSO4- 0.15029E-17 -17.8231 0.12588E-17 -17.9000 0.83757E+00 -0.0770 Charge balance for all species = -.6133E-08 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.8878657E-10 -.2225984E-01 -.2239757E+02 0.0000 2 H2O 0.1000000E+01 0.5550483E+02 0.9981975E+06 0.0000 3 Cl- 0.1549919E-03 0.1557036E-03 0.5510561E+01 6.2393 4 SO4-- 0.3372443E-10 -.1493244E-04 -.1431940E+01 9.4978 5 HCO3- 0.9469171E-05 0.4112085E-04 0.2504716E+01 5.0260 6 HS- 0.3732151E-04 0.5226120E-04 0.1725377E+01 5.6211 7 Al+++ 0.9761419E-29 0.5236076E-05 0.1410315E+00 0.7348 8 H4SiO4 0.6995286E-03 0.1353227E-01 0.1298398E+04 -3.1552 9 Ca++ 0.1225029E-06 0.2170053E-06 0.8682015E-02 13.0548 10 Mg++ 0.2113676E-10 0.9318227E-10 0.2261508E-05 9.2897 11 Fe++ 0.4555520E-13 0.2811360E-07 0.1567330E-02 6.6237 12 K+ 0.1565107E-03 0.1572605E-03 0.6138508E+01 6.2443 13 Na+ 0.1986118E-01 0.2230594E-01 0.5119175E+03 8.3470 14 Mn++ 0.1873882E-10 0.2507559E-08 0.1375207E-03 9.2382 15 F- 0.2575010E-06 0.2583346E-06 0.4899306E-02 3.4589 16 HPO4-- 0.4532029E-07 0.4642026E-07 0.4447623E-02 12.6262 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.1999101E-01 -.1999068E-01 -.3308781E-06 0.0000000E+00 2 H2O 0.4984668E+02 0.4984668E+02 -.2900143E-06 0.0000000E+00 3 Cl- 0.1398312E-03 0.1398312E-03 0.0000000E+00 0.0000000E+00 4 SO4-- -.1340931E-04 -.1341023E-04 0.9180712E-09 0.0000000E+00 5 HCO3- 0.3692900E-04 0.3692900E-04 0.0000000E+00 0.0000000E+00 6 HS- 0.4693278E-04 0.4693370E-04 -.9180712E-09 0.0000000E+00 7 Al+++ 0.4775352E-05 0.4702311E-05 0.7304072E-07 0.0000000E+00 8 H4SiO4 0.1215302E-01 0.1215279E-01 0.2279562E-06 0.0000000E+00 9 Ca++ 0.2080835E-06 0.1948838E-06 0.1319969E-07 0.0000000E+00 10 Mg++ 0.8368328E-10 0.8368328E-10 0.0000000E+00 0.0000000E+00 11 Fe++ 0.3259227E-07 0.2524770E-07 0.7344570E-08 0.0000000E+00 12 K+ 0.1412294E-03 0.1412294E-03 0.0000000E+00 0.0000000E+00 13 Na+ 0.2003215E-01 0.2003208E-01 0.7158550E-07 0.0000000E+00 14 Mn++ 0.2251939E-08 0.2251939E-08 0.0000000E+00 0.0000000E+00 15 F- 0.2320000E-06 0.2320000E-06 0.0000000E+00 0.0000000E+00 16 HPO4-- 0.4168819E-07 0.4168819E-07 0.0000000E+00 0.0000000E+00 Chg. balance for solid moles: 0.1323E-22 Mass of aqueous solution: 0.899624E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 0.0003300 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 0.7159E-07 -7.145 0.1877E-04 -4.727 89.54 0.7206E-05 andradite 0.3672E-08 -8.435 0.1866E-05 -5.729 8.901 0.4848E-06 grossular 0.7276E-09 -9.138 0.3278E-06 -6.484 1.563 0.9119E-07 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8346E+00 0.8346E+00 1.0000 -0.079 grossular 0.1654E+00 0.1654E+00 1.0000 -0.782 Solid products produced: Mass = 0.000021 g Volume = 0.000008 cm3 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.0003300 moles log = -3.4815 Original solution: 1000.0103000 g Original solution / Rock added: 3030334.24 (Water/Rock Ratio), log = 6.4815 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0468 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9750E+00 0.9856 0.1006E+01 0.1021E+01 CO2,gas 0.1281E-06 1.0069 0.1351E-06 0.1341E-06 CH4,gas 0.1902E-01 1.0123 0.2016E-01 0.1992E-01 H2,gas 0.5937E-02 1.0006 0.6218E-02 0.6215E-02 H2S,gas 0.1895E-06 0.9959 0.1976E-06 0.1984E-06 S2,gas 0.3620E-28 1.0000 0.3790E-28 0.3790E-28 CO,gas 0.2138E-12 1.0000 0.2238E-12 0.2238E-12 SO3,gas 0.3520E-46 1.0000 0.3684E-46 0.3684E-46 SO2,gas 0.8514E-26 1.0000 0.8913E-26 0.8913E-26 HF,gas 0.2571E-15 1.0000 0.2691E-15 0.2691E-15 HCl,gas 0.2983E-17 1.0000 0.3122E-17 0.3122E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 17 albite -0.38 -0.38 0.00 0.000 -0.13080E-10 23 andradite 39.01 39.01 0.00 0.000 0.00000E+00 24 grossular 32.73 32.73 0.00 0.000 0.00000E+00 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -15.23 -8.57 -2.856 0.14630E+05 -6.869 3 CH4,gas 4.54 1.15 -3.39 -0.849 0.57960E+04 -1.695 4 H2,gas 8.00 4.09 -3.91 -2.232 0.66682E+04 -2.206 5 H2S,gas -6.23 -14.63 -8.40 -4.202 0.14348E+05 -6.704 6 S2,gas -7.34 -37.46 -30.12 -4.634 0.51430E+05 -28.421 7 CO,gas 3.21 -11.13 -14.35 -4.415 0.24501E+05 -12.650 8 SO3,gas 17.12 -31.01 -48.13 -12.033 0.82185E+05 -46.434 9 SO2,gas 0.83 -26.92 -27.75 -7.400 0.47381E+05 -26.050 10 HF,gas 0.47 -16.80 -17.27 -8.635 0.29486E+05 -15.570 11 HCl,gas 5.19 -14.02 -19.20 -9.602 0.32791E+05 -17.506 12 acmite 7.71 6.61 -1.10 -0.114 0.18726E+04 16 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 20 spessartine 24.46 19.72 -4.74 -0.237 0.80912E+04 21 analcite 3.32 2.77 -0.55 -0.061 0.94002E+03 27 annite 20.12 17.38 -2.74 -0.152 0.46765E+04 28 phlogopite 27.06 25.38 -1.68 -0.093 0.28720E+04 30 anorthite 12.71 8.21 -4.50 -0.346 0.76775E+04 33 apatite-OH -18.15 -18.37 -0.22 -0.017 0.37746E+03 34 apatite-F -34.30 -35.17 -0.87 -0.072 0.14841E+04 38 aragonite 0.97 -2.17 -3.14 -1.047 0.53619E+04 39 brucite 12.57 9.29 -3.28 -0.656 0.55986E+04 40 calcite 0.81 -2.17 -2.99 -0.995 0.50977E+04 41 carnegieite-low 9.02 5.93 -3.10 -0.442 0.52877E+04 42 carnegieite-high 10.09 5.93 -4.17 -0.595 0.71147E+04 43 carpholite-Mg 8.58 4.45 -4.13 -0.276 0.70574E+04 44 carpholite-Fe 6.71 1.78 -4.93 -0.329 0.84176E+04 45 celadonite 5.34 3.65 -1.69 -0.100 0.28918E+04 46 celadonite-Fe 3.88 0.98 -2.89 -0.170 0.49424E+04 47 chrysotile 23.89 21.56 -2.33 -0.194 0.39847E+04 49 clinochlore 39.07 38.45 -0.62 -0.019 0.10536E+04 50 daphnite 28.97 25.12 -3.84 -0.120 0.65617E+04 52 chlorite-Al-free 47.17 43.12 -4.06 -0.169 0.69245E+04 54 chloritoid-Fe 9.17 4.94 -4.24 -0.282 0.72322E+04 55 chloritoid-Mn 11.40 7.55 -3.85 -0.257 0.65712E+04 57 coesite -2.38 -3.16 -0.78 -0.260 0.13303E+04 64 cristobalite -2.56 -3.16 -0.59 -0.198 0.10157E+04 66 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71234E+04 68 diaspore 2.87 0.73 -2.14 -0.356 0.36522E+04 69 diamond -3.10 -7.04 -3.94 -1.125 0.67228E+04 70 diopside 16.18 16.03 -0.15 -0.015 0.25141E+03 71 hedenbergite 14.21 13.37 -0.84 -0.084 0.14346E+04 74 enstatite 17.26 12.27 -5.00 -0.500 0.85303E+04 76 clinoenstatite 17.17 12.27 -4.90 -0.490 0.83619E+04 78 epidote 24.67 22.69 -1.98 -0.096 0.33807E+04 79 clinozoisite 22.81 18.85 -3.96 -0.180 0.67577E+04 80 epidote-Fe 29.84 26.53 -3.31 -0.172 0.56502E+04 81 fayalite 14.05 10.09 -3.95 -0.565 0.67506E+04 82 ferrosilite 11.15 6.94 -4.21 -0.421 0.71927E+04 86 gibbsite 4.08 0.73 -3.34 -0.478 0.57107E+04 87 glaucophane 22.97 20.79 -2.18 -0.059 0.37288E+04 88 glaucophane-Fe 17.28 12.79 -4.48 -0.121 0.76544E+04 89 graphite -3.55 -7.04 -3.49 -0.998 0.59650E+04 90 greenalite 16.14 13.56 -2.58 -0.215 0.44033E+04 93 hematite 12.57 9.15 -3.41 -0.414 0.58281E+04 94 heulandite -5.83 -7.56 -1.73 -0.079 0.29621E+04 98 jadeite 4.22 2.77 -1.44 -0.144 0.24655E+04 100 kalsilite 7.58 3.82 -3.76 -0.537 0.64201E+04 101 kaolinite -1.33 -4.84 -3.51 -0.319 0.59900E+04 104 laumontite 2.88 1.90 -0.98 -0.065 0.16731E+04 105 lawsonite 9.62 8.21 -1.40 -0.093 0.23941E+04 106 leucite 4.12 0.67 -3.45 -0.345 0.58911E+04 108 lizardite 23.24 21.56 -1.69 -0.140 0.28773E+04 110 magnetite 20.09 15.78 -4.31 -0.352 0.73606E+04 111 minnesotaite 10.39 7.25 -3.14 -0.185 0.53578E+04 115 manganosite 14.06 9.24 -4.82 -1.205 0.82298E+04 119 microcline -2.49 -2.49 0.00 0.000 0.27766E-01 123 muscovite 2.58 -1.02 -3.60 -0.212 0.61459E+04 124 paragonite 4.24 1.09 -3.15 -0.186 0.53850E+04 125 nepheline 8.34 5.93 -2.41 -0.345 0.41200E+04 137 phlogopite-Na 29.65 27.49 -2.16 -0.120 0.36907E+04 139 prehnite 19.37 18.11 -1.26 -0.074 0.21486E+04 140 prehnite-Fe 22.50 21.96 -0.54 -0.033 0.92652E+03 141 pumpellyite-Fe 46.27 43.59 -2.68 -0.060 0.45827E+04 142 pumpellyite-Mg 48.99 46.25 -2.74 -0.061 0.46842E+04 146 pyrrhotite -4.26 -8.01 -3.75 -1.250 0.64021E+04 147 pyrrhotiteFe0.875 -6.02 -9.35 -3.33 -1.224 0.56834E+04 148 pyroxmangite 7.40 6.08 -1.32 -0.263 0.22464E+04 149 pyrophyllite -6.18 -11.15 -4.98 -0.311 0.84955E+04 150 quartz -2.99 -3.16 -0.17 -0.055 0.28303E+03 155 rhodonite 7.45 6.08 -1.36 -0.273 0.23267E+04 156 sanidine -1.28 -2.49 -1.21 -0.093 0.20678E+04 166 stilbite -7.52 -7.56 -0.04 -0.002 0.68281E+02 167 stilpnomelane-Fe 13.02 12.47 -0.55 -0.016 0.93648E+03 168 stilpnomelane-Mg 27.44 25.80 -1.64 -0.049 0.28050E+04 174 talc 16.49 15.25 -1.24 -0.073 0.21219E+04 177 tephroite 18.09 15.32 -2.76 -0.395 0.47203E+04 181 tridymite -2.63 -3.16 -0.53 -0.176 0.90301E+03 182 tremolite 47.87 47.32 -0.55 -0.015 0.94370E+03 183 ferroactinolite 38.45 33.99 -4.47 -0.121 0.76254E+04 184 troilite-low -4.41 -8.01 -3.60 -1.200 0.61449E+04 190 wairakite 3.95 1.90 -2.05 -0.120 0.34951E+04 191 walstromite 11.51 9.90 -1.61 -0.322 0.27484E+04 192 wollastonite 10.46 9.90 -0.56 -0.112 0.95881E+03 193 pseudo-wollastonite 11.00 9.90 -1.10 -0.220 0.18786E+04 194 zoisite 22.85 18.85 -4.00 -0.182 0.68318E+04 195 akaganeite 7.75 4.58 -3.18 -0.687 0.54266E+04 202 chalcedony -2.80 -3.16 -0.35 -0.118 0.60233E+03 204 montmorillonite-Ca -2.29 -6.17 -3.88 -0.240 0.66307E+04 205 montmorillonite-K -2.24 -6.27 -4.03 -0.247 0.68825E+04 206 montmorillonite-Mg -2.48 -6.80 -4.32 -0.267 0.73685E+04 207 montmorillonite-Na -2.04 -5.57 -3.54 -0.217 0.60373E+04 208 nontronite-Ca 3.21 -0.03 -3.24 -0.210 0.55402E+04 209 nontronite-H 2.53 -2.18 -4.72 -0.316 0.80539E+04 210 nontronite-K 3.34 -0.12 -3.46 -0.222 0.59151E+04 211 nontronite-Mg 3.07 -0.65 -3.73 -0.242 0.63620E+04 212 nontronite-Na 3.52 0.57 -2.95 -0.189 0.50360E+04 228 tobermorite 9.82 7.72 -2.10 -0.574 0.35918E+04 234 alabandite -0.98 -5.40 -4.42 -1.472 0.75425E+04 237 boehmite 4.41 0.73 -3.67 -0.612 0.62691E+04 239 ferrous-oxide 9.81 6.62 -3.19 -0.797 0.54433E+04 245 silica-amorphous -2.09 -3.16 -1.06 -0.355 0.18165E+04 247 an20ab80 2.02 1.34 -0.68 -0.052 0.11646E+04 248 an25ab75 2.65 1.77 -0.88 -0.068 0.15028E+04 249 an30ab70 3.28 2.20 -1.08 -0.083 0.18505E+04 250 tr.625ac.25prg.125 45.16 44.93 -0.23 -0.006 0.39991E+03 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 0.0000100 MOLES Current total amount of reactant added: 0.0003300 MOLES New total amount of reactant added: 0.0003400 MOLES Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.5508E-08 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 6 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 0.0003400 Water: Moles liquid = 0.4985E+02 kg liquid = 0.8981E+00 Moles total = 0.4985E+02 kg total = 0.8980E+00 Activity = 1.0000 Stoichiometric ionic strength = .1135190E-01 Osmotic coef. = 0.9682 True ionic strength = .2003669E-01 Chg. balance for total moles = -.5508E-08 Max. difference allowed = 0.1399E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.88802E-10 -10.0516 0.74612E-10 -10.1272 0.84020E+00 -0.0756 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.15506E-03 -3.8095 0.12950E-03 -3.8877 0.83515E+00 -0.0782 4 SO4-- 0.35136E-10 -10.4543 0.18242E-10 -10.7389 0.51918E+00 -0.2847 5 HCO3- 0.97636E-05 -5.0104 0.81660E-05 -5.0880 0.83637E+00 -0.0776 6 HS- 0.37592E-04 -4.4249 0.31400E-04 -4.5031 0.83527E+00 -0.0782 7 Al+++ 0.97636E-29 -29.0104 0.22545E-29 -29.6470 0.23091E+00 -0.6366 8 H4SiO4 0.69964E-03 -3.1551 0.69964E-03 -3.1551 0.10000E+01 0.0000 9 Ca++ 0.12234E-06 -6.9124 0.63051E-07 -7.2003 0.51537E+00 -0.2879 10 Mg++ 0.21137E-10 -10.6749 0.10844E-10 -10.9648 0.51301E+00 -0.2899 11 Fe++ 0.45505E-13 -13.3419 0.23370E-13 -13.6313 0.51357E+00 -0.2894 12 K+ 0.15651E-03 -3.8055 0.13093E-03 -3.8830 0.83657E+00 -0.0775 13 Na+ 0.19861E-01 -1.7020 0.16584E-01 -1.7803 0.83500E+00 -0.0783 14 Mn++ 0.18745E-10 -10.7271 0.96350E-11 -11.0161 0.51400E+00 -0.2890 15 F- 0.26194E-06 -6.5818 0.21831E-06 -6.6609 0.83343E+00 -0.0791 16 HPO4-- 0.45320E-07 -7.3437 0.23533E-07 -7.6283 0.51926E+00 -0.2846 18 HSiO3- 0.10484E-01 -1.9795 0.87558E-02 -2.0577 0.83515E+00 -0.0782 19 Ca(HSiO3)+ 0.15025E-07 -7.8232 0.12573E-07 -7.9006 0.83675E+00 -0.0774 20 Mg(HSiO3)+ 0.32160E-11 -11.4927 0.26910E-11 -11.5701 0.83675E+00 -0.0774 21 NaHSiO3,aq 0.23485E-02 -2.6292 0.23485E-02 -2.6292 0.10000E+01 0.0000 22 AlO+ 0.65843E-16 -16.1815 0.55094E-16 -16.2589 0.83675E+00 -0.0774 24 HAlO2,aq 0.14705E-09 -9.8325 0.14705E-09 -9.8325 0.10000E+01 0.0000 25 AlO2- 0.52334E-05 -5.2812 0.43627E-05 -5.3602 0.83364E+00 -0.0790 26 CH4,aq 0.13701E-04 -4.8632 0.13654E-04 -4.8647 0.99654E+00 -0.0015 27 C2H6,aq 0.68101E-14 -14.1668 0.67865E-14 -14.1684 0.99654E+00 -0.0015 31 CO,aq 0.15359E-15 -15.8136 0.15359E-15 -15.8136 0.10000E+01 0.0000 32 CO2,aq 0.13064E-08 -8.8839 0.13019E-08 -8.8854 0.99654E+00 -0.0015 33 CO3-2 0.18452E-04 -4.7340 0.95597E-05 -5.0196 0.51808E+00 -0.2856 34 CaCO3,aq 0.75578E-08 -8.1216 0.75578E-08 -8.1216 0.10000E+01 0.0000 35 Ca(HCO3)+ 0.15707E-10 -10.8039 0.13143E-10 -10.8813 0.83675E+00 -0.0774 36 CaCl+ 0.15791E-10 -10.8016 0.13213E-10 -10.8790 0.83675E+00 -0.0774 37 CaCl2,aq 0.40651E-15 -15.3909 0.40651E-15 -15.3909 0.10000E+01 0.0000 38 CaF+ 0.24017E-12 -12.6195 0.20096E-12 -12.6969 0.83675E+00 -0.0774 39 CaOH+ 0.71977E-07 -7.1428 0.60227E-07 -7.2202 0.83675E+00 -0.0774 40 CaSO4,aq 0.36523E-15 -15.4374 0.36523E-15 -15.4374 0.10000E+01 0.0000 41 HCl,aq 0.17705E-14 -14.7519 0.17705E-14 -14.7519 0.10000E+01 0.0000 45 HF,aq 0.11151E-12 -12.9527 0.11151E-12 -12.9527 0.10000E+01 0.0000 48 FeCl+ 0.57247E-17 -17.2422 0.47901E-17 -17.3197 0.83675E+00 -0.0774 51 FeF+ 0.31158E-18 -18.5064 0.26071E-18 -18.5838 0.83675E+00 -0.0774 53 FeO,aq 0.16316E-09 -9.7874 0.16316E-09 -9.7874 0.10000E+01 0.0000 54 FeOH+ 0.12185E-10 -10.9142 0.10196E-10 -10.9916 0.83675E+00 -0.0774 55 HFeO2- 0.27396E-07 -7.5623 0.22880E-07 -7.6405 0.83515E+00 -0.0782 56 FeO+ 0.13411E-16 -16.8725 0.11222E-16 -16.9499 0.83675E+00 -0.0774 58 FeO2- 0.49390E-09 -9.3064 0.41248E-09 -9.3846 0.83515E+00 -0.0782 59 HFeO2,aq 0.39142E-11 -11.4074 0.39142E-11 -11.4074 0.10000E+01 0.0000 60 H2,aq 0.47125E-05 -5.3267 0.46962E-05 -5.3283 0.99654E+00 -0.0015 61 KCl,aq 0.30730E-09 -9.5124 0.30730E-09 -9.5124 0.10000E+01 0.0000 63 KOH,aq 0.74942E-06 -6.1253 0.74942E-06 -6.1253 0.10000E+01 0.0000 64 KSO4- 0.44379E-13 -13.3528 0.37063E-13 -13.4311 0.83515E+00 -0.0782 65 MgCO3,aq 0.32581E-12 -12.4870 0.32581E-12 -12.4870 0.10000E+01 0.0000 66 Mg(HCO3)+ 0.27602E-14 -14.5591 0.23096E-14 -14.6365 0.83675E+00 -0.0774 67 MgCl+ 0.24615E-14 -14.6088 0.20596E-14 -14.6862 0.83675E+00 -0.0774 68 MgF+ 0.15301E-15 -15.8153 0.12803E-15 -15.8927 0.83675E+00 -0.0774 69 MgOH+ 0.68498E-10 -10.1643 0.57315E-10 -10.2417 0.83675E+00 -0.0774 71 MnF+ 0.42341E-16 -16.3732 0.35429E-16 -16.4506 0.83675E+00 -0.0774 72 MnO,aq 0.17924E-08 -8.7466 0.17924E-08 -8.7466 0.10000E+01 0.0000 73 MnOH+ 0.46667E-09 -9.3310 0.39049E-09 -9.4084 0.83675E+00 -0.0774 74 MnO2-2 0.20624E-10 -10.6856 0.10685E-10 -10.9712 0.51808E+00 -0.2856 75 HMnO2- 0.20914E-09 -9.6796 0.17466E-09 -9.7578 0.83515E+00 -0.0782 78 MnCl+ 0.91822E-14 -14.0371 0.76832E-14 -14.1145 0.83675E+00 -0.0774 79 MnSO4,aq 0.50740E-19 -19.2946 0.50740E-19 -19.2946 0.10000E+01 0.0000 80 NaCl,aq 0.71171E-06 -6.1477 0.71171E-06 -6.1477 0.10000E+01 0.0000 81 NaF,aq 0.84761E-09 -9.0718 0.84761E-09 -9.0718 0.10000E+01 0.0000 82 NaOH,aq 0.95498E-04 -4.0200 0.95498E-04 -4.0200 0.10000E+01 0.0000 84 OH- 0.92890E-02 -2.0320 0.77437E-02 -2.1111 0.83364E+00 -0.0790 89 HPO3-2 0.66477E-15 -15.1773 0.34440E-15 -15.4629 0.51808E+00 -0.2856 91 H2PO3- 0.61701E-19 -19.2097 0.51529E-19 -19.2879 0.83515E+00 -0.0782 92 H3PO4,aq 0.91626E-18 -18.0380 0.91626E-18 -18.0380 0.10000E+01 0.0000 93 H2PO4- 0.38747E-10 -10.4118 0.32391E-10 -10.4896 0.83594E+00 -0.0778 94 PO4-3 0.10611E-08 -8.9743 0.25734E-09 -9.5895 0.24253E+00 -0.6152 98 HP2O7-3 0.95248E-18 -18.0211 0.22015E-18 -18.6573 0.23114E+00 -0.6361 99 P2O7-4 0.91504E-17 -17.0386 0.70490E-18 -18.1519 0.77034E-01 -1.1133 100 H2S,aq 0.72658E-08 -8.1387 0.72406E-08 -8.1402 0.99654E+00 -0.0015 101 S2-2 0.89792E-14 -14.0468 0.46519E-14 -14.3324 0.51808E+00 -0.2856 107 SO3-2 0.21181E-16 -16.6741 0.11132E-16 -16.9534 0.52558E+00 -0.2794 108 HSO3- 0.62272E-19 -19.2057 0.52006E-19 -19.2839 0.83515E+00 -0.0782 109 HSO4- 0.15661E-17 -17.8052 0.13117E-17 -17.8822 0.83756E+00 -0.0770 Charge balance for all species = -.6133E-08 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.8880225E-10 -.2225863E-01 -.2239635E+02 0.0000 2 H2O 0.1000000E+01 0.5550483E+02 0.9981974E+06 0.0000 3 Cl- 0.1550572E-03 0.1557693E-03 0.5512885E+01 6.2394 4 SO4-- 0.3513559E-10 -.1487927E-04 -.1426841E+01 9.5155 5 HCO3- 0.9763631E-05 0.4192591E-04 0.2553753E+01 5.0392 6 HS- 0.3759203E-04 0.5247860E-04 0.1732554E+01 5.6241 7 Al+++ 0.9763628E-29 0.5233520E-05 0.1409627E+00 0.7346 8 H4SiO4 0.6996430E-03 0.1353226E-01 0.1298397E+04 -3.1551 9 Ca++ 0.1223418E-06 0.2169338E-06 0.8679155E-02 13.0541 10 Mg++ 0.2113734E-10 0.9318225E-10 0.2261507E-05 9.2896 11 Fe++ 0.4550464E-13 0.2806965E-07 0.1564880E-02 6.6230 12 K+ 0.1565108E-03 0.1572605E-03 0.6138507E+01 6.2442 13 Na+ 0.1986122E-01 0.2230594E-01 0.5119173E+03 8.3469 14 Mn++ 0.1874517E-10 0.2507559E-08 0.1375207E-03 9.2382 15 F- 0.2619406E-06 0.2627886E-06 0.4983776E-02 3.4663 16 HPO4-- 0.4532044E-07 0.4642026E-07 0.4447622E-02 12.6261 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.1998993E-01 -.1998959E-01 -.3402573E-06 0.0000000E+00 2 H2O 0.4984669E+02 0.4984669E+02 -.2992010E-06 0.0000000E+00 3 Cl- 0.1398902E-03 0.1398902E-03 0.0000000E+00 0.0000000E+00 4 SO4-- -.1336156E-04 -.1336248E-04 0.9230043E-09 0.0000000E+00 5 HCO3- 0.3765200E-04 0.3765200E-04 0.0000000E+00 0.0000000E+00 6 HS- 0.4712803E-04 0.4712895E-04 -.9230043E-09 0.0000000E+00 7 Al+++ 0.4775352E-05 0.4700016E-05 0.7533577E-07 0.0000000E+00 8 H4SiO4 0.1215302E-01 0.1215279E-01 0.2348956E-06 0.0000000E+00 9 Ca++ 0.2080835E-06 0.1948197E-06 0.1326384E-07 0.0000000E+00 10 Mg++ 0.8368328E-10 0.8368328E-10 0.0000000E+00 0.0000000E+00 11 Fe++ 0.3259227E-07 0.2520824E-07 0.7384035E-08 0.0000000E+00 12 K+ 0.1412294E-03 0.1412294E-03 0.0000000E+00 0.0000000E+00 13 Na+ 0.2003215E-01 0.2003208E-01 0.7387725E-07 0.0000000E+00 14 Mn++ 0.2251939E-08 0.2251939E-08 0.0000000E+00 0.0000000E+00 15 F- 0.2360000E-06 0.2360000E-06 0.0000000E+00 0.0000000E+00 16 HPO4-- 0.4168819E-07 0.4168819E-07 0.0000000E+00 0.0000000E+00 Chg. balance for solid moles: -.2647E-22 Mass of aqueous solution: 0.899625E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 0.0003400 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 0.7388E-07 -7.131 0.1937E-04 -4.713 89.78 0.7437E-05 andradite 0.3692E-08 -8.433 0.1876E-05 -5.727 8.695 0.4875E-06 grossular 0.7293E-09 -9.137 0.3285E-06 -6.483 1.522 0.9140E-07 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8351E+00 0.8351E+00 1.0000 -0.078 grossular 0.1649E+00 0.1649E+00 1.0000 -0.783 Solid products produced: Mass = 0.000022 g Volume = 0.000008 cm3 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.0003400 moles log = -3.4685 Original solution: 1000.0103000 g Original solution / Rock added: 2941206.76 (Water/Rock Ratio), log = 6.4685 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0467 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9751E+00 0.9856 0.1006E+01 0.1021E+01 CO2,gas 0.1322E-06 1.0069 0.1393E-06 0.1383E-06 CH4,gas 0.1897E-01 1.0123 0.2010E-01 0.1985E-01 H2,gas 0.5887E-02 1.0006 0.6166E-02 0.6162E-02 H2S,gas 0.1909E-06 0.9959 0.1990E-06 0.1999E-06 S2,gas 0.3737E-28 1.0000 0.3912E-28 0.3912E-28 CO,gas 0.2187E-12 1.0000 0.2289E-12 0.2289E-12 SO3,gas 0.3668E-46 1.0000 0.3840E-46 0.3840E-46 SO2,gas 0.8799E-26 1.0000 0.9210E-26 0.9210E-26 HF,gas 0.2616E-15 1.0000 0.2738E-15 0.2738E-15 HCl,gas 0.2985E-17 1.0000 0.3124E-17 0.3124E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 17 albite -0.38 -0.38 0.00 0.000 -0.94784E-12 23 andradite 39.01 39.01 0.00 0.000 0.00000E+00 24 grossular 32.73 32.73 0.00 0.000 -0.12132E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -15.22 -8.56 -2.852 0.14608E+05 -6.856 3 CH4,gas 4.54 1.15 -3.40 -0.849 0.57983E+04 -1.697 4 H2,gas 8.00 4.09 -3.91 -2.234 0.66745E+04 -2.210 5 H2S,gas -6.23 -14.63 -8.40 -4.200 0.14343E+05 -6.701 6 S2,gas -7.34 -37.44 -30.11 -4.632 0.51406E+05 -28.408 7 CO,gas 3.21 -11.12 -14.34 -4.412 0.24484E+05 -12.640 8 SO3,gas 17.12 -30.99 -48.11 -12.029 0.82154E+05 -46.416 9 SO2,gas 0.83 -26.90 -27.73 -7.396 0.47356E+05 -26.036 10 HF,gas 0.47 -16.79 -17.26 -8.631 0.29474E+05 -15.563 11 HCl,gas 5.19 -14.01 -19.20 -9.602 0.32791E+05 -17.505 12 acmite 7.71 6.61 -1.10 -0.114 0.18704E+04 16 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 20 spessartine 24.46 19.72 -4.74 -0.237 0.80913E+04 21 analcite 3.32 2.77 -0.55 -0.061 0.94014E+03 27 annite 20.12 17.38 -2.74 -0.152 0.46798E+04 28 phlogopite 27.06 25.38 -1.68 -0.093 0.28727E+04 30 anorthite 12.71 8.21 -4.50 -0.346 0.76789E+04 33 apatite-OH -18.15 -18.38 -0.22 -0.017 0.38289E+03 34 apatite-F -34.30 -35.17 -0.86 -0.072 0.14767E+04 38 aragonite 0.97 -2.16 -3.13 -1.043 0.53403E+04 39 brucite 12.57 9.29 -3.28 -0.656 0.55988E+04 40 calcite 0.81 -2.16 -2.97 -0.991 0.50761E+04 41 carnegieite-low 9.02 5.93 -3.10 -0.442 0.52879E+04 42 carnegieite-high 10.09 5.93 -4.17 -0.595 0.71149E+04 43 carpholite-Mg 8.58 4.45 -4.13 -0.276 0.70579E+04 44 carpholite-Fe 6.71 1.78 -4.93 -0.329 0.84189E+04 45 celadonite 5.34 3.65 -1.69 -0.100 0.28919E+04 46 celadonite-Fe 3.88 0.98 -2.90 -0.170 0.49433E+04 47 chrysotile 23.89 21.56 -2.33 -0.194 0.39852E+04 49 clinochlore 39.07 38.45 -0.62 -0.019 0.10550E+04 50 daphnite 28.97 25.12 -3.85 -0.120 0.65672E+04 52 chlorite-Al-free 47.17 43.12 -4.06 -0.169 0.69255E+04 54 chloritoid-Fe 9.17 4.94 -4.24 -0.282 0.72336E+04 55 chloritoid-Mn 11.40 7.55 -3.85 -0.257 0.65716E+04 57 coesite -2.38 -3.16 -0.78 -0.260 0.13302E+04 64 cristobalite -2.56 -3.16 -0.59 -0.198 0.10156E+04 66 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71234E+04 68 diaspore 2.87 0.73 -2.14 -0.357 0.36524E+04 69 diamond -3.10 -7.03 -3.93 -1.123 0.67125E+04 70 diopside 16.18 16.03 -0.15 -0.015 0.25265E+03 71 hedenbergite 14.21 13.37 -0.84 -0.084 0.14367E+04 74 enstatite 17.26 12.27 -5.00 -0.500 0.85306E+04 76 clinoenstatite 17.17 12.27 -4.90 -0.490 0.83622E+04 78 epidote 24.67 22.69 -1.98 -0.096 0.33812E+04 79 clinozoisite 22.81 18.85 -3.96 -0.180 0.67605E+04 80 epidote-Fe 29.84 26.53 -3.31 -0.172 0.56485E+04 81 fayalite 14.05 10.09 -3.95 -0.565 0.67527E+04 82 ferrosilite 11.15 6.94 -4.21 -0.421 0.71946E+04 86 gibbsite 4.08 0.73 -3.34 -0.478 0.57110E+04 87 glaucophane 22.97 20.79 -2.18 -0.059 0.37293E+04 88 glaucophane-Fe 17.28 12.79 -4.48 -0.121 0.76575E+04 89 graphite -3.55 -7.03 -3.49 -0.996 0.59548E+04 90 greenalite 16.14 13.56 -2.58 -0.215 0.44064E+04 93 hematite 12.57 9.16 -3.41 -0.413 0.58240E+04 94 heulandite -5.83 -7.56 -1.74 -0.079 0.29630E+04 98 jadeite 4.22 2.77 -1.44 -0.144 0.24656E+04 100 kalsilite 7.58 3.82 -3.76 -0.537 0.64204E+04 101 kaolinite -1.33 -4.84 -3.51 -0.319 0.59902E+04 104 laumontite 2.88 1.90 -0.98 -0.065 0.16743E+04 105 lawsonite 9.62 8.21 -1.40 -0.094 0.23956E+04 106 leucite 4.12 0.67 -3.45 -0.345 0.58912E+04 108 lizardite 23.24 21.56 -1.69 -0.140 0.28778E+04 110 magnetite 20.09 15.78 -4.31 -0.352 0.73576E+04 111 minnesotaite 10.39 7.25 -3.14 -0.185 0.53606E+04 115 manganosite 14.06 9.24 -4.82 -1.205 0.82298E+04 119 microcline -2.49 -2.49 0.00 0.000 0.28609E-01 123 muscovite 2.58 -1.02 -3.60 -0.212 0.61464E+04 124 paragonite 4.24 1.09 -3.15 -0.186 0.53855E+04 125 nepheline 8.34 5.93 -2.41 -0.345 0.41203E+04 137 phlogopite-Na 29.65 27.48 -2.16 -0.120 0.36915E+04 139 prehnite 19.37 18.11 -1.26 -0.074 0.21512E+04 140 prehnite-Fe 22.50 21.96 -0.54 -0.033 0.92681E+03 141 pumpellyite-Fe 46.27 43.58 -2.69 -0.060 0.45892E+04 142 pumpellyite-Mg 48.99 46.25 -2.75 -0.061 0.46898E+04 146 pyrrhotite -4.26 -8.01 -3.75 -1.249 0.63977E+04 147 pyrrhotiteFe0.875 -6.02 -9.34 -3.33 -1.223 0.56781E+04 148 pyroxmangite 7.40 6.08 -1.32 -0.263 0.22463E+04 149 pyrophyllite -6.18 -11.15 -4.98 -0.311 0.84955E+04 150 quartz -2.99 -3.16 -0.17 -0.055 0.28291E+03 155 rhodonite 7.45 6.08 -1.36 -0.273 0.23265E+04 156 sanidine -1.28 -2.49 -1.21 -0.093 0.20678E+04 166 stilbite -7.52 -7.56 -0.04 -0.002 0.69141E+02 167 stilpnomelane-Fe 13.02 12.47 -0.55 -0.016 0.94149E+03 168 stilpnomelane-Mg 27.44 25.80 -1.64 -0.049 0.28058E+04 174 talc 16.49 15.25 -1.24 -0.073 0.21222E+04 177 tephroite 18.09 15.32 -2.76 -0.395 0.47202E+04 181 tridymite -2.63 -3.16 -0.53 -0.176 0.90289E+03 182 tremolite 47.87 47.31 -0.55 -0.015 0.94643E+03 183 ferroactinolite 38.45 33.98 -4.47 -0.121 0.76324E+04 184 troilite-low -4.41 -8.01 -3.60 -1.199 0.61405E+04 190 wairakite 3.95 1.90 -2.05 -0.120 0.34963E+04 191 walstromite 11.51 9.90 -1.61 -0.322 0.27495E+04 192 wollastonite 10.46 9.90 -0.56 -0.112 0.95993E+03 193 pseudo-wollastonite 11.00 9.90 -1.10 -0.220 0.18798E+04 194 zoisite 22.85 18.85 -4.00 -0.182 0.68346E+04 195 akaganeite 7.75 4.58 -3.18 -0.687 0.54245E+04 202 chalcedony -2.80 -3.16 -0.35 -0.118 0.60221E+03 204 montmorillonite-Ca -2.29 -6.17 -3.88 -0.240 0.66309E+04 205 montmorillonite-K -2.24 -6.27 -4.03 -0.247 0.68825E+04 206 montmorillonite-Mg -2.48 -6.80 -4.32 -0.267 0.73685E+04 207 montmorillonite-Na -2.04 -5.57 -3.54 -0.217 0.60374E+04 208 nontronite-Ca 3.21 -0.03 -3.24 -0.210 0.55359E+04 209 nontronite-H 2.53 -2.18 -4.71 -0.316 0.80495E+04 210 nontronite-K 3.34 -0.12 -3.46 -0.222 0.59107E+04 211 nontronite-Mg 3.07 -0.65 -3.72 -0.242 0.63576E+04 212 nontronite-Na 3.52 0.57 -2.95 -0.189 0.50316E+04 228 tobermorite 9.82 7.72 -2.10 -0.574 0.35927E+04 234 alabandite -0.98 -5.39 -4.41 -1.471 0.75371E+04 237 boehmite 4.41 0.73 -3.67 -0.612 0.62693E+04 239 ferrous-oxide 9.81 6.62 -3.19 -0.797 0.54443E+04 245 silica-amorphous -2.09 -3.16 -1.06 -0.355 0.18164E+04 247 an20ab80 2.02 1.34 -0.68 -0.052 0.11649E+04 248 an25ab75 2.65 1.77 -0.88 -0.068 0.15031E+04 249 an30ab70 3.28 2.20 -1.08 -0.083 0.18510E+04 250 tr.625ac.25prg.125 45.16 44.93 -0.24 -0.006 0.40381E+03 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 0.0000100 MOLES Current total amount of reactant added: 0.0003400 MOLES New total amount of reactant added: 0.0003500 MOLES Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.5508E-08 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 6 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 0.0003500 Water: Moles liquid = 0.4985E+02 kg liquid = 0.8981E+00 Moles total = 0.4985E+02 kg total = 0.8980E+00 Activity = 1.0000 Stoichiometric ionic strength = .1135253E-01 Osmotic coef. = 0.9682 True ionic strength = .2003728E-01 Chg. balance for total moles = -.5508E-08 Max. difference allowed = 0.1399E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.88818E-10 -10.0515 0.74625E-10 -10.1271 0.84020E+00 -0.0756 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.15512E-03 -3.8093 0.12955E-03 -3.8876 0.83515E+00 -0.0782 4 SO4-- 0.36573E-10 -10.4368 0.18988E-10 -10.7215 0.51918E+00 -0.2847 5 HCO3- 0.10058E-04 -4.9975 0.84124E-05 -5.0751 0.83637E+00 -0.0776 6 HS- 0.37863E-04 -4.4218 0.31625E-04 -4.5000 0.83527E+00 -0.0782 7 Al+++ 0.97658E-29 -29.0103 0.22549E-29 -29.6469 0.23090E+00 -0.6366 8 H4SiO4 0.69976E-03 -3.1551 0.69976E-03 -3.1551 0.10000E+01 0.0000 9 Ca++ 0.12218E-06 -6.9130 0.62969E-07 -7.2009 0.51537E+00 -0.2879 10 Mg++ 0.21138E-10 -10.6749 0.10844E-10 -10.9648 0.51301E+00 -0.2899 11 Fe++ 0.45457E-13 -13.3424 0.23346E-13 -13.6318 0.51357E+00 -0.2894 12 K+ 0.15651E-03 -3.8055 0.13093E-03 -3.8830 0.83657E+00 -0.0775 13 Na+ 0.19861E-01 -1.7020 0.16584E-01 -1.7803 0.83499E+00 -0.0783 14 Mn++ 0.18752E-10 -10.7270 0.96382E-11 -11.0160 0.51399E+00 -0.2890 15 F- 0.26638E-06 -6.5745 0.22201E-06 -6.6536 0.83342E+00 -0.0791 16 HPO4-- 0.45321E-07 -7.3437 0.23533E-07 -7.6283 0.51925E+00 -0.2846 18 HSiO3- 0.10484E-01 -1.9795 0.87557E-02 -2.0577 0.83515E+00 -0.0782 19 Ca(HSiO3)+ 0.15006E-07 -7.8237 0.12556E-07 -7.9011 0.83675E+00 -0.0774 20 Mg(HSiO3)+ 0.32160E-11 -11.4927 0.26910E-11 -11.5701 0.83675E+00 -0.0774 21 NaHSiO3,aq 0.23485E-02 -2.6292 0.23485E-02 -2.6292 0.10000E+01 0.0000 22 AlO+ 0.65834E-16 -16.1816 0.55086E-16 -16.2590 0.83675E+00 -0.0774 24 HAlO2,aq 0.14701E-09 -9.8327 0.14701E-09 -9.8327 0.10000E+01 0.0000 25 AlO2- 0.52308E-05 -5.2814 0.43606E-05 -5.3605 0.83364E+00 -0.0790 26 CH4,aq 0.13658E-04 -4.8646 0.13610E-04 -4.8661 0.99654E+00 -0.0015 27 C2H6,aq 0.68231E-14 -14.1660 0.67995E-14 -14.1675 0.99654E+00 -0.0015 31 CO,aq 0.15695E-15 -15.8043 0.15695E-15 -15.8043 0.10000E+01 0.0000 32 CO2,aq 0.13461E-08 -8.8709 0.13414E-08 -8.8724 0.99654E+00 -0.0015 33 CO3-2 0.19006E-04 -4.7211 0.98465E-05 -5.0067 0.51808E+00 -0.2856 34 CaCO3,aq 0.77744E-08 -8.1093 0.77744E-08 -8.1093 0.10000E+01 0.0000 35 Ca(HCO3)+ 0.16160E-10 -10.7916 0.13522E-10 -10.8690 0.83675E+00 -0.0774 36 CaCl+ 0.15777E-10 -10.8020 0.13202E-10 -10.8794 0.83675E+00 -0.0774 37 CaCl2,aq 0.40632E-15 -15.3911 0.40632E-15 -15.3911 0.10000E+01 0.0000 38 CaF+ 0.24392E-12 -12.6127 0.20410E-12 -12.6901 0.83675E+00 -0.0774 39 CaOH+ 0.71871E-07 -7.1434 0.60138E-07 -7.2209 0.83675E+00 -0.0774 40 CaSO4,aq 0.37967E-15 -15.4206 0.37967E-15 -15.4206 0.10000E+01 0.0000 41 HCl,aq 0.17716E-14 -14.7516 0.17716E-14 -14.7516 0.10000E+01 0.0000 45 HF,aq 0.11342E-12 -12.9453 0.11342E-12 -12.9453 0.10000E+01 0.0000 46 HF2- 0.10179E-19 -19.9923 0.85011E-20 -20.0705 0.83515E+00 -0.0782 48 FeCl+ 0.57211E-17 -17.2425 0.47871E-17 -17.3199 0.83675E+00 -0.0774 51 FeF+ 0.31653E-18 -18.4996 0.26485E-18 -18.5770 0.83675E+00 -0.0774 53 FeO,aq 0.16293E-09 -9.7880 0.16293E-09 -9.7880 0.10000E+01 0.0000 54 FeOH+ 0.12170E-10 -10.9147 0.10183E-10 -10.9921 0.83675E+00 -0.0774 55 HFeO2- 0.27354E-07 -7.5630 0.22844E-07 -7.6412 0.83515E+00 -0.0782 56 FeO+ 0.13451E-16 -16.8713 0.11255E-16 -16.9487 0.83675E+00 -0.0774 58 FeO2- 0.49517E-09 -9.3052 0.41354E-09 -9.3835 0.83515E+00 -0.0782 59 HFeO2,aq 0.39249E-11 -11.4062 0.39249E-11 -11.4062 0.10000E+01 0.0000 60 H2,aq 0.46737E-05 -5.3303 0.46575E-05 -5.3318 0.99654E+00 -0.0015 61 KCl,aq 0.30743E-09 -9.5123 0.30743E-09 -9.5123 0.10000E+01 0.0000 63 KOH,aq 0.74928E-06 -6.1254 0.74928E-06 -6.1254 0.10000E+01 0.0000 64 KSO4- 0.46193E-13 -13.3354 0.38578E-13 -13.4137 0.83515E+00 -0.0782 65 MgCO3,aq 0.33559E-12 -12.4742 0.33559E-12 -12.4742 0.10000E+01 0.0000 66 Mg(HCO3)+ 0.28436E-14 -14.5461 0.23794E-14 -14.6235 0.83675E+00 -0.0774 67 MgCl+ 0.24625E-14 -14.6086 0.20605E-14 -14.6860 0.83675E+00 -0.0774 68 MgF+ 0.15560E-15 -15.8080 0.13020E-15 -15.8854 0.83675E+00 -0.0774 69 MgOH+ 0.68487E-10 -10.1644 0.57307E-10 -10.2418 0.83675E+00 -0.0774 71 MnF+ 0.43073E-16 -16.3658 0.36041E-16 -16.4432 0.83675E+00 -0.0774 72 MnO,aq 0.17923E-08 -8.7466 0.17923E-08 -8.7466 0.10000E+01 0.0000 73 MnOH+ 0.46675E-09 -9.3309 0.39055E-09 -9.4083 0.83675E+00 -0.0774 74 MnO2-2 0.20617E-10 -10.6858 0.10681E-10 -10.9714 0.51808E+00 -0.2856 75 HMnO2- 0.20910E-09 -9.6796 0.17463E-09 -9.7579 0.83515E+00 -0.0782 78 MnCl+ 0.91891E-14 -14.0367 0.76890E-14 -14.1141 0.83675E+00 -0.0774 79 MnSO4,aq 0.52833E-19 -19.2771 0.52833E-19 -19.2771 0.10000E+01 0.0000 80 NaCl,aq 0.71201E-06 -6.1475 0.71201E-06 -6.1475 0.10000E+01 0.0000 81 NaF,aq 0.86197E-09 -9.0645 0.86197E-09 -9.0645 0.10000E+01 0.0000 82 NaOH,aq 0.95481E-04 -4.0201 0.95481E-04 -4.0201 0.10000E+01 0.0000 84 OH- 0.92874E-02 -2.0321 0.77424E-02 -2.1111 0.83364E+00 -0.0790 89 HPO3-2 0.65929E-15 -15.1809 0.34156E-15 -15.4665 0.51808E+00 -0.2856 91 H2PO3- 0.61203E-19 -19.2132 0.51114E-19 -19.2915 0.83515E+00 -0.0782 92 H3PO4,aq 0.91657E-18 -18.0378 0.91657E-18 -18.0378 0.10000E+01 0.0000 93 H2PO4- 0.38754E-10 -10.4117 0.32396E-10 -10.4895 0.83594E+00 -0.0778 94 PO4-3 0.10609E-08 -8.9743 0.25729E-09 -9.5896 0.24252E+00 -0.6152 98 HP2O7-3 0.95266E-18 -18.0211 0.22019E-18 -18.6572 0.23113E+00 -0.6361 99 P2O7-4 0.91506E-17 -17.0385 0.70489E-18 -18.1519 0.77032E-01 -1.1133 100 H2S,aq 0.73194E-08 -8.1355 0.72940E-08 -8.1370 0.99654E+00 -0.0015 101 S2-2 0.91845E-14 -14.0369 0.47583E-14 -14.3225 0.51808E+00 -0.2856 107 SO3-2 0.21866E-16 -16.6602 0.11492E-16 -16.9396 0.52558E+00 -0.2794 108 HSO3- 0.64296E-19 -19.1918 0.53696E-19 -19.2701 0.83515E+00 -0.0782 109 HSO4- 0.16304E-17 -17.7877 0.13655E-17 -17.8647 0.83756E+00 -0.0770 Charge balance for all species = -.6133E-08 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.8881794E-10 -.2225741E-01 -.2239513E+02 0.0000 2 H2O 0.1000000E+01 0.5550483E+02 0.9981973E+06 0.0000 3 Cl- 0.1551226E-03 0.1558349E-03 0.5515209E+01 6.2396 4 SO4-- 0.3657252E-10 -.1482610E-04 -.1421743E+01 9.5327 5 HCO3- 0.1005827E-04 0.4273097E-04 0.2602790E+01 5.0520 6 HS- 0.3786255E-04 0.5269601E-04 0.1739732E+01 5.6272 7 Al+++ 0.9765839E-29 0.5230963E-05 0.1408938E+00 0.7345 8 H4SiO4 0.6997574E-03 0.1353225E-01 0.1298396E+04 -3.1551 9 Ca++ 0.1221831E-06 0.2168661E-06 0.8676444E-02 13.0534 10 Mg++ 0.2113792E-10 0.9318223E-10 0.2261507E-05 9.2894 11 Fe++ 0.4545750E-13 0.2802779E-07 0.1562546E-02 6.6224 12 K+ 0.1565109E-03 0.1572605E-03 0.6138505E+01 6.2442 13 Na+ 0.1986125E-01 0.2230593E-01 0.5119171E+03 8.3468 14 Mn++ 0.1875153E-10 0.2507558E-08 0.1375207E-03 9.2382 15 F- 0.2663802E-06 0.2672426E-06 0.5068246E-02 3.4735 16 HPO4-- 0.4532060E-07 0.4642025E-07 0.4447621E-02 12.6259 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.1998885E-01 -.1998850E-01 -.3496261E-06 0.0000000E+00 2 H2O 0.4984670E+02 0.4984670E+02 -.3083877E-06 0.0000000E+00 3 Cl- 0.1399492E-03 0.1399492E-03 0.0000000E+00 0.0000000E+00 4 SO4-- -.1331381E-04 -.1331474E-04 0.9277028E-09 0.0000000E+00 5 HCO3- 0.3837500E-04 0.3837500E-04 0.0000000E+00 0.0000000E+00 6 HS- 0.4732328E-04 0.4732421E-04 -.9277028E-09 0.0000000E+00 7 Al+++ 0.4775352E-05 0.4697721E-05 0.7763069E-07 0.0000000E+00 8 H4SiO4 0.1215302E-01 0.1215278E-01 0.2418323E-06 0.0000000E+00 9 Ca++ 0.2080835E-06 0.1947589E-06 0.1332465E-07 0.0000000E+00 10 Mg++ 0.8368328E-10 0.8368328E-10 0.0000000E+00 0.0000000E+00 11 Fe++ 0.3259227E-07 0.2517065E-07 0.7421623E-08 0.0000000E+00 12 K+ 0.1412294E-03 0.1412294E-03 0.0000000E+00 0.0000000E+00 13 Na+ 0.2003215E-01 0.2003207E-01 0.7616921E-07 0.0000000E+00 14 Mn++ 0.2251939E-08 0.2251939E-08 0.0000000E+00 0.0000000E+00 15 F- 0.2400000E-06 0.2400000E-06 0.0000000E+00 0.0000000E+00 16 HPO4-- 0.4168819E-07 0.4168819E-07 0.0000000E+00 0.0000000E+00 Chg. balance for solid moles: 0.1323E-22 Mass of aqueous solution: 0.899625E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 0.0003500 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 0.7617E-07 -7.118 0.1997E-04 -4.700 90.02 0.7667E-05 andradite 0.3711E-08 -8.431 0.1886E-05 -5.725 8.499 0.4899E-06 grossular 0.7307E-09 -9.136 0.3292E-06 -6.483 1.484 0.9159E-07 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8355E+00 0.8355E+00 1.0000 -0.078 grossular 0.1645E+00 0.1645E+00 1.0000 -0.784 Solid products produced: Mass = 0.000022 g Volume = 0.000008 cm3 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.0003500 moles log = -3.4559 Original solution: 1000.0103000 g Original solution / Rock added: 2857172.29 (Water/Rock Ratio), log = 6.4559 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0466 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9753E+00 0.9856 0.1006E+01 0.1021E+01 CO2,gas 0.1362E-06 1.0069 0.1435E-06 0.1425E-06 CH4,gas 0.1891E-01 1.0123 0.2003E-01 0.1979E-01 H2,gas 0.5839E-02 1.0006 0.6115E-02 0.6111E-02 H2S,gas 0.1924E-06 0.9959 0.2005E-06 0.2013E-06 S2,gas 0.3856E-28 1.0000 0.4036E-28 0.4036E-28 CO,gas 0.2235E-12 1.0000 0.2339E-12 0.2339E-12 SO3,gas 0.3820E-46 1.0000 0.3998E-46 0.3998E-46 SO2,gas 0.9088E-26 1.0000 0.9511E-26 0.9511E-26 HF,gas 0.2661E-15 1.0000 0.2785E-15 0.2785E-15 HCl,gas 0.2987E-17 1.0000 0.3126E-17 0.3126E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 17 albite -0.38 -0.38 0.00 0.000 0.11184E-10 23 andradite 39.01 39.01 0.00 0.000 0.00000E+00 24 grossular 32.73 32.73 0.00 0.000 0.12132E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -15.20 -8.54 -2.847 0.14585E+05 -6.843 3 CH4,gas 4.54 1.15 -3.40 -0.849 0.58006E+04 -1.698 4 H2,gas 8.00 4.09 -3.91 -2.236 0.66806E+04 -2.214 5 H2S,gas -6.23 -14.63 -8.40 -4.198 0.14337E+05 -6.698 6 S2,gas -7.34 -37.43 -30.09 -4.630 0.51383E+05 -28.394 7 CO,gas 3.21 -11.12 -14.33 -4.409 0.24468E+05 -12.631 8 SO3,gas 17.12 -30.98 -48.10 -12.024 0.82125E+05 -46.398 9 SO2,gas 0.83 -26.89 -27.72 -7.392 0.47332E+05 -26.022 10 HF,gas 0.47 -16.78 -17.25 -8.627 0.29461E+05 -15.555 11 HCl,gas 5.19 -14.01 -19.20 -9.602 0.32790E+05 -17.505 12 acmite 7.71 6.62 -1.09 -0.114 0.18682E+04 16 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 20 spessartine 24.46 19.72 -4.74 -0.237 0.80914E+04 21 analcite 3.32 2.77 -0.55 -0.061 0.94026E+03 27 annite 20.12 17.38 -2.74 -0.152 0.46829E+04 28 phlogopite 27.06 25.38 -1.68 -0.093 0.28734E+04 30 anorthite 12.71 8.21 -4.50 -0.346 0.76804E+04 33 apatite-OH -18.15 -18.38 -0.23 -0.017 0.38826E+03 34 apatite-F -34.30 -35.16 -0.86 -0.072 0.14695E+04 38 aragonite 0.97 -2.15 -3.12 -1.038 0.53194E+04 39 brucite 12.57 9.29 -3.28 -0.656 0.55991E+04 40 calcite 0.81 -2.15 -2.96 -0.987 0.50552E+04 41 carnegieite-low 9.02 5.93 -3.10 -0.442 0.52881E+04 42 carnegieite-high 10.09 5.93 -4.17 -0.595 0.71151E+04 43 carpholite-Mg 8.58 4.45 -4.13 -0.276 0.70584E+04 44 carpholite-Fe 6.71 1.78 -4.93 -0.329 0.84201E+04 45 celadonite 5.34 3.65 -1.69 -0.100 0.28920E+04 46 celadonite-Fe 3.88 0.98 -2.90 -0.170 0.49442E+04 47 chrysotile 23.89 21.56 -2.33 -0.195 0.39857E+04 49 clinochlore 39.07 38.45 -0.62 -0.019 0.10563E+04 50 daphnite 28.97 25.12 -3.85 -0.120 0.65725E+04 52 chlorite-Al-free 47.17 43.12 -4.06 -0.169 0.69265E+04 54 chloritoid-Fe 9.17 4.94 -4.24 -0.282 0.72350E+04 55 chloritoid-Mn 11.40 7.55 -3.85 -0.257 0.65719E+04 57 coesite -2.38 -3.16 -0.78 -0.260 0.13301E+04 64 cristobalite -2.56 -3.16 -0.59 -0.198 0.10155E+04 66 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71234E+04 68 diaspore 2.87 0.73 -2.14 -0.357 0.36526E+04 69 diamond -3.10 -7.03 -3.93 -1.122 0.67026E+04 70 diopside 16.18 16.03 -0.15 -0.015 0.25388E+03 71 hedenbergite 14.21 13.37 -0.84 -0.084 0.14387E+04 74 enstatite 17.26 12.27 -5.00 -0.500 0.85308E+04 76 clinoenstatite 17.17 12.27 -4.90 -0.490 0.83624E+04 78 epidote 24.67 22.69 -1.98 -0.096 0.33817E+04 79 clinozoisite 22.81 18.85 -3.96 -0.180 0.67633E+04 80 epidote-Fe 29.84 26.53 -3.31 -0.172 0.56467E+04 81 fayalite 14.05 10.09 -3.96 -0.565 0.67546E+04 82 ferrosilite 11.15 6.93 -4.21 -0.421 0.71965E+04 86 gibbsite 4.08 0.73 -3.34 -0.478 0.57112E+04 87 glaucophane 22.97 20.79 -2.18 -0.059 0.37298E+04 88 glaucophane-Fe 17.28 12.79 -4.49 -0.121 0.76603E+04 89 graphite -3.55 -7.03 -3.48 -0.995 0.59449E+04 90 greenalite 16.14 13.56 -2.58 -0.215 0.44092E+04 93 hematite 12.57 9.16 -3.41 -0.413 0.58199E+04 94 heulandite -5.83 -7.56 -1.74 -0.079 0.29638E+04 98 jadeite 4.22 2.77 -1.44 -0.144 0.24658E+04 100 kalsilite 7.58 3.82 -3.76 -0.537 0.64206E+04 101 kaolinite -1.33 -4.84 -3.51 -0.319 0.59904E+04 104 laumontite 2.88 1.90 -0.98 -0.065 0.16755E+04 105 lawsonite 9.62 8.21 -1.40 -0.094 0.23970E+04 106 leucite 4.12 0.67 -3.45 -0.345 0.58913E+04 108 lizardite 23.24 21.56 -1.69 -0.140 0.28783E+04 110 magnetite 20.09 15.78 -4.31 -0.352 0.73545E+04 111 minnesotaite 10.39 7.25 -3.14 -0.185 0.53632E+04 115 manganosite 14.06 9.24 -4.82 -1.205 0.82298E+04 119 microcline -2.49 -2.49 0.00 0.000 0.29452E-01 123 muscovite 2.58 -1.02 -3.60 -0.212 0.61469E+04 124 paragonite 4.24 1.09 -3.15 -0.186 0.53859E+04 125 nepheline 8.34 5.93 -2.41 -0.345 0.41205E+04 137 phlogopite-Na 29.65 27.48 -2.16 -0.120 0.36922E+04 139 prehnite 19.37 18.11 -1.26 -0.074 0.21537E+04 140 prehnite-Fe 22.50 21.95 -0.54 -0.033 0.92711E+03 141 pumpellyite-Fe 46.27 43.58 -2.69 -0.060 0.45956E+04 142 pumpellyite-Mg 48.99 46.24 -2.75 -0.061 0.46954E+04 146 pyrrhotite -4.26 -8.00 -3.74 -1.248 0.63933E+04 147 pyrrhotiteFe0.875 -6.02 -9.34 -3.32 -1.222 0.56728E+04 148 pyroxmangite 7.40 6.08 -1.32 -0.263 0.22462E+04 149 pyrophyllite -6.18 -11.15 -4.98 -0.311 0.84954E+04 150 quartz -2.99 -3.16 -0.17 -0.055 0.28279E+03 154 rhodochrosite -0.98 -5.96 -4.99 -1.663 0.85163E+04 155 rhodonite 7.45 6.08 -1.36 -0.273 0.23264E+04 156 sanidine -1.28 -2.49 -1.21 -0.093 0.20678E+04 166 stilbite -7.52 -7.56 -0.04 -0.002 0.69988E+02 167 stilpnomelane-Fe 13.02 12.46 -0.55 -0.017 0.94622E+03 168 stilpnomelane-Mg 27.44 25.80 -1.64 -0.049 0.28066E+04 174 talc 16.49 15.25 -1.24 -0.073 0.21224E+04 177 tephroite 18.09 15.32 -2.76 -0.395 0.47201E+04 181 tridymite -2.63 -3.16 -0.53 -0.176 0.90276E+03 182 tremolite 47.87 47.31 -0.56 -0.015 0.94914E+03 183 ferroactinolite 38.45 33.98 -4.47 -0.121 0.76391E+04 184 troilite-low -4.41 -8.00 -3.59 -1.198 0.61361E+04 190 wairakite 3.95 1.90 -2.05 -0.120 0.34975E+04 191 walstromite 11.51 9.90 -1.61 -0.322 0.27506E+04 192 wollastonite 10.46 9.90 -0.56 -0.113 0.96104E+03 193 pseudo-wollastonite 11.00 9.90 -1.10 -0.220 0.18809E+04 194 zoisite 22.85 18.85 -4.00 -0.182 0.68374E+04 195 akaganeite 7.75 4.58 -3.18 -0.687 0.54225E+04 202 chalcedony -2.80 -3.16 -0.35 -0.118 0.60208E+03 204 montmorillonite-Ca -2.29 -6.17 -3.88 -0.240 0.66311E+04 205 montmorillonite-K -2.24 -6.27 -4.03 -0.247 0.68825E+04 206 montmorillonite-Mg -2.48 -6.80 -4.32 -0.267 0.73686E+04 207 montmorillonite-Na -2.04 -5.57 -3.54 -0.217 0.60374E+04 208 nontronite-Ca 3.21 -0.03 -3.24 -0.210 0.55317E+04 209 nontronite-H 2.53 -2.18 -4.71 -0.316 0.80450E+04 210 nontronite-K 3.34 -0.12 -3.46 -0.222 0.59063E+04 211 nontronite-Mg 3.07 -0.65 -3.72 -0.241 0.63532E+04 212 nontronite-Na 3.52 0.58 -2.94 -0.189 0.50272E+04 228 tobermorite 9.82 7.72 -2.10 -0.574 0.35936E+04 234 alabandite -0.98 -5.39 -4.41 -1.470 0.75316E+04 237 boehmite 4.41 0.73 -3.67 -0.612 0.62696E+04 239 ferrous-oxide 9.81 6.62 -3.19 -0.797 0.54454E+04 245 silica-amorphous -2.09 -3.16 -1.06 -0.355 0.18163E+04 247 an20ab80 2.02 1.34 -0.68 -0.052 0.11652E+04 248 an25ab75 2.65 1.77 -0.88 -0.068 0.15035E+04 249 an30ab70 3.28 2.19 -1.08 -0.083 0.18514E+04 250 tr.625ac.25prg.125 45.16 44.93 -0.24 -0.006 0.40760E+03 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 0.0000100 MOLES Current total amount of reactant added: 0.0003500 MOLES New total amount of reactant added: 0.0003600 MOLES Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.5508E-08 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 6 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 0.0003600 Water: Moles liquid = 0.4985E+02 kg liquid = 0.8981E+00 Moles total = 0.4985E+02 kg total = 0.8980E+00 Activity = 1.0000 Stoichiometric ionic strength = .1135317E-01 Osmotic coef. = 0.9682 True ionic strength = .2003786E-01 Chg. balance for total moles = -.5508E-08 Max. difference allowed = 0.1400E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.88834E-10 -10.0514 0.74638E-10 -10.1270 0.84020E+00 -0.0756 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.15519E-03 -3.8091 0.12960E-03 -3.8874 0.83515E+00 -0.0782 4 SO4-- 0.38036E-10 -10.4198 0.19747E-10 -10.7045 0.51918E+00 -0.2847 5 HCO3- 0.10353E-04 -4.9849 0.86590E-05 -5.0625 0.83637E+00 -0.0776 6 HS- 0.38133E-04 -4.4187 0.31851E-04 -4.4969 0.83527E+00 -0.0782 7 Al+++ 0.97681E-29 -29.0102 0.22554E-29 -29.6468 0.23090E+00 -0.6366 8 H4SiO4 0.69987E-03 -3.1550 0.69987E-03 -3.1550 0.10000E+01 0.0000 9 Ca++ 0.12203E-06 -6.9135 0.62888E-07 -7.2014 0.51536E+00 -0.2879 10 Mg++ 0.21139E-10 -10.6749 0.10844E-10 -10.9648 0.51300E+00 -0.2899 11 Fe++ 0.45414E-13 -13.3428 0.23323E-13 -13.6322 0.51356E+00 -0.2894 12 K+ 0.15651E-03 -3.8055 0.13093E-03 -3.8830 0.83657E+00 -0.0775 13 Na+ 0.19861E-01 -1.7020 0.16584E-01 -1.7803 0.83499E+00 -0.0783 14 Mn++ 0.18758E-10 -10.7268 0.96414E-11 -11.0159 0.51399E+00 -0.2890 15 F- 0.27082E-06 -6.5673 0.22571E-06 -6.6465 0.83342E+00 -0.0791 16 HPO4-- 0.45321E-07 -7.3437 0.23533E-07 -7.6283 0.51925E+00 -0.2846 18 HSiO3- 0.10484E-01 -1.9795 0.87556E-02 -2.0577 0.83515E+00 -0.0782 19 Ca(HSiO3)+ 0.14986E-07 -7.8243 0.12540E-07 -7.9017 0.83675E+00 -0.0774 20 Mg(HSiO3)+ 0.32160E-11 -11.4927 0.26910E-11 -11.5701 0.83675E+00 -0.0774 21 NaHSiO3,aq 0.23485E-02 -2.6292 0.23485E-02 -2.6292 0.10000E+01 0.0000 22 AlO+ 0.65825E-16 -16.1816 0.55079E-16 -16.2590 0.83675E+00 -0.0774 24 HAlO2,aq 0.14696E-09 -9.8328 0.14696E-09 -9.8328 0.10000E+01 0.0000 25 AlO2- 0.52283E-05 -5.2816 0.43585E-05 -5.3607 0.83364E+00 -0.0790 26 CH4,aq 0.13614E-04 -4.8660 0.13567E-04 -4.8675 0.99654E+00 -0.0015 27 C2H6,aq 0.68344E-14 -14.1653 0.68107E-14 -14.1668 0.99654E+00 -0.0015 31 CO,aq 0.16028E-15 -15.7951 0.16028E-15 -15.7951 0.10000E+01 0.0000 32 CO2,aq 0.13858E-08 -8.8583 0.13810E-08 -8.8598 0.99654E+00 -0.0015 33 CO3-2 0.19560E-04 -4.7086 0.10133E-04 -4.9943 0.51807E+00 -0.2856 34 CaCO3,aq 0.79905E-08 -8.0974 0.79905E-08 -8.0974 0.10000E+01 0.0000 35 Ca(HCO3)+ 0.16612E-10 -10.7796 0.13900E-10 -10.8570 0.83675E+00 -0.0774 36 CaCl+ 0.15764E-10 -10.8023 0.13190E-10 -10.8798 0.83675E+00 -0.0774 37 CaCl2,aq 0.40614E-15 -15.3913 0.40614E-15 -15.3913 0.10000E+01 0.0000 38 CaF+ 0.24767E-12 -12.6061 0.20724E-12 -12.6835 0.83675E+00 -0.0774 39 CaOH+ 0.71766E-07 -7.1441 0.60050E-07 -7.2215 0.83675E+00 -0.0774 40 CaSO4,aq 0.39435E-15 -15.4041 0.39435E-15 -15.4041 0.10000E+01 0.0000 41 HCl,aq 0.17726E-14 -14.7514 0.17726E-14 -14.7514 0.10000E+01 0.0000 45 HF,aq 0.11533E-12 -12.9381 0.11533E-12 -12.9381 0.10000E+01 0.0000 46 HF2- 0.10523E-19 -19.9779 0.87883E-20 -20.0561 0.83515E+00 -0.0782 48 FeCl+ 0.57180E-17 -17.2428 0.47845E-17 -17.3202 0.83675E+00 -0.0774 51 FeF+ 0.32149E-18 -18.4928 0.26901E-18 -18.5702 0.83675E+00 -0.0774 53 FeO,aq 0.16271E-09 -9.7886 0.16271E-09 -9.7886 0.10000E+01 0.0000 54 FeOH+ 0.12156E-10 -10.9152 0.10172E-10 -10.9926 0.83675E+00 -0.0774 55 HFeO2- 0.27313E-07 -7.5636 0.22810E-07 -7.6419 0.83515E+00 -0.0782 56 FeO+ 0.13489E-16 -16.8700 0.11287E-16 -16.9474 0.83675E+00 -0.0774 58 FeO2- 0.49642E-09 -9.3041 0.41459E-09 -9.3824 0.83515E+00 -0.0782 59 HFeO2,aq 0.39356E-11 -11.4050 0.39356E-11 -11.4050 0.10000E+01 0.0000 60 H2,aq 0.46361E-05 -5.3338 0.46201E-05 -5.3354 0.99654E+00 -0.0015 61 KCl,aq 0.30756E-09 -9.5121 0.30756E-09 -9.5121 0.10000E+01 0.0000 63 KOH,aq 0.74915E-06 -6.1254 0.74915E-06 -6.1254 0.10000E+01 0.0000 64 KSO4- 0.48041E-13 -13.3184 0.40121E-13 -13.3966 0.83515E+00 -0.0782 65 MgCO3,aq 0.34537E-12 -12.4617 0.34537E-12 -12.4617 0.10000E+01 0.0000 66 Mg(HCO3)+ 0.29270E-14 -14.5336 0.24492E-14 -14.6110 0.83675E+00 -0.0774 67 MgCl+ 0.24636E-14 -14.6084 0.20614E-14 -14.6858 0.83675E+00 -0.0774 68 MgF+ 0.15820E-15 -15.8008 0.13237E-15 -15.8782 0.83675E+00 -0.0774 69 MgOH+ 0.68477E-10 -10.1645 0.57298E-10 -10.2419 0.83675E+00 -0.0774 71 MnF+ 0.43805E-16 -16.3585 0.36654E-16 -16.4359 0.83675E+00 -0.0774 72 MnO,aq 0.17923E-08 -8.7466 0.17923E-08 -8.7466 0.10000E+01 0.0000 73 MnOH+ 0.46682E-09 -9.3308 0.39061E-09 -9.4083 0.83675E+00 -0.0774 74 MnO2-2 0.20610E-10 -10.6859 0.10677E-10 -10.9715 0.51807E+00 -0.2856 75 HMnO2- 0.20906E-09 -9.6797 0.17460E-09 -9.7580 0.83515E+00 -0.0782 78 MnCl+ 0.91960E-14 -14.0364 0.76947E-14 -14.1138 0.83675E+00 -0.0774 79 MnSO4,aq 0.54964E-19 -19.2599 0.54964E-19 -19.2599 0.10000E+01 0.0000 80 NaCl,aq 0.71230E-06 -6.1473 0.71230E-06 -6.1473 0.10000E+01 0.0000 81 NaF,aq 0.87634E-09 -9.0573 0.87634E-09 -9.0573 0.10000E+01 0.0000 82 NaOH,aq 0.95465E-04 -4.0202 0.95465E-04 -4.0202 0.10000E+01 0.0000 84 OH- 0.92858E-02 -2.0322 0.77410E-02 -2.1112 0.83364E+00 -0.0790 89 HPO3-2 0.65400E-15 -15.1844 0.33882E-15 -15.4700 0.51807E+00 -0.2856 91 H2PO3- 0.60722E-19 -19.2167 0.50712E-19 -19.2949 0.83515E+00 -0.0782 92 H3PO4,aq 0.91689E-18 -18.0377 0.91689E-18 -18.0377 0.10000E+01 0.0000 93 H2PO4- 0.38761E-10 -10.4116 0.32402E-10 -10.4894 0.83594E+00 -0.0778 94 PO4-3 0.10607E-08 -8.9744 0.25724E-09 -9.5897 0.24252E+00 -0.6153 98 HP2O7-3 0.95283E-18 -18.0210 0.22023E-18 -18.6571 0.23113E+00 -0.6361 99 P2O7-4 0.91508E-17 -17.0385 0.70489E-18 -18.1519 0.77030E-01 -1.1133 100 H2S,aq 0.73729E-08 -8.1324 0.73474E-08 -8.1339 0.99654E+00 -0.0015 101 S2-2 0.93917E-14 -14.0273 0.48656E-14 -14.3129 0.51807E+00 -0.2856 107 SO3-2 0.22558E-16 -16.6467 0.11856E-16 -16.9261 0.52557E+00 -0.2794 108 HSO3- 0.66342E-19 -19.1782 0.55405E-19 -19.2565 0.83515E+00 -0.0782 109 HSO4- 0.16959E-17 -17.7706 0.14204E-17 -17.8476 0.83756E+00 -0.0770 Charge balance for all species = -.6133E-08 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.8883364E-10 -.2225620E-01 -.2239390E+02 0.0000 2 H2O 0.1000000E+01 0.5550483E+02 0.9981973E+06 0.0000 3 Cl- 0.1551880E-03 0.1559006E-03 0.5517533E+01 6.2397 4 SO4-- 0.3803552E-10 -.1477294E-04 -.1416644E+01 9.5496 5 HCO3- 0.1035309E-04 0.4353603E-04 0.2651827E+01 5.0645 6 HS- 0.3813307E-04 0.5291342E-04 0.1746910E+01 5.6302 7 Al+++ 0.9768051E-29 0.5228407E-05 0.1408249E+00 0.7343 8 H4SiO4 0.6998720E-03 0.1353224E-01 0.1298395E+04 -3.1550 9 Ca++ 0.1220267E-06 0.2168018E-06 0.8673873E-02 13.0526 10 Mg++ 0.2113851E-10 0.9318221E-10 0.2261506E-05 9.2893 11 Fe++ 0.4541357E-13 0.2798789E-07 0.1560322E-02 6.6219 12 K+ 0.1565110E-03 0.1572604E-03 0.6138504E+01 6.2441 13 Na+ 0.1986129E-01 0.2230592E-01 0.5119169E+03 8.3467 14 Mn++ 0.1875789E-10 0.2507558E-08 0.1375206E-03 9.2382 15 F- 0.2708199E-06 0.2716966E-06 0.5152715E-02 3.4806 16 HPO4-- 0.4532076E-07 0.4642024E-07 0.4447620E-02 12.6258 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.1998778E-01 -.1998742E-01 -.3589849E-06 0.0000000E+00 2 H2O 0.4984670E+02 0.4984670E+02 -.3175740E-06 0.0000000E+00 3 Cl- 0.1400082E-03 0.1400082E-03 0.0000000E+00 0.0000000E+00 4 SO4-- -.1326606E-04 -.1326699E-04 0.9321808E-09 0.0000000E+00 5 HCO3- 0.3909800E-04 0.3909800E-04 0.0000000E+00 0.0000000E+00 6 HS- 0.4751853E-04 0.4751946E-04 -.9321808E-09 0.0000000E+00 7 Al+++ 0.4775352E-05 0.4695427E-05 0.7992542E-07 0.0000000E+00 8 H4SiO4 0.1215302E-01 0.1215277E-01 0.2487663E-06 0.0000000E+00 9 Ca++ 0.2080835E-06 0.1947012E-06 0.1338231E-07 0.0000000E+00 10 Mg++ 0.8368328E-10 0.8368328E-10 0.0000000E+00 0.0000000E+00 11 Fe++ 0.3259227E-07 0.2513482E-07 0.7457446E-08 0.0000000E+00 12 K+ 0.1412294E-03 0.1412294E-03 0.0000000E+00 0.0000000E+00 13 Na+ 0.2003215E-01 0.2003207E-01 0.7846132E-07 0.0000000E+00 14 Mn++ 0.2251939E-08 0.2251939E-08 0.0000000E+00 0.0000000E+00 15 F- 0.2440000E-06 0.2440000E-06 0.0000000E+00 0.0000000E+00 16 HPO4-- 0.4168819E-07 0.4168819E-07 0.0000000E+00 0.0000000E+00 Chg. balance for solid moles: 0.3970E-22 Mass of aqueous solution: 0.899625E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 0.0003600 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 0.7846E-07 -7.105 0.2057E-04 -4.687 90.24 0.7898E-05 andradite 0.3729E-08 -8.428 0.1895E-05 -5.722 8.311 0.4923E-06 grossular 0.7320E-09 -9.135 0.3298E-06 -6.482 1.446 0.9175E-07 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8359E+00 0.8359E+00 1.0000 -0.078 grossular 0.1641E+00 0.1641E+00 1.0000 -0.785 Solid products produced: Mass = 0.000023 g Volume = 0.000008 cm3 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.0003600 moles log = -3.4437 Original solution: 1000.0103000 g Original solution / Rock added: 2777806.39 (Water/Rock Ratio), log = 6.4437 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0465 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9754E+00 0.9856 0.1006E+01 0.1021E+01 CO2,gas 0.1402E-06 1.0069 0.1477E-06 0.1467E-06 CH4,gas 0.1885E-01 1.0123 0.1997E-01 0.1973E-01 H2,gas 0.5793E-02 1.0006 0.6066E-02 0.6062E-02 H2S,gas 0.1938E-06 0.9959 0.2020E-06 0.2028E-06 S2,gas 0.3977E-28 1.0000 0.4162E-28 0.4162E-28 CO,gas 0.2282E-12 1.0000 0.2388E-12 0.2388E-12 SO3,gas 0.3975E-46 1.0000 0.4159E-46 0.4159E-46 SO2,gas 0.9380E-26 1.0000 0.9816E-26 0.9816E-26 HF,gas 0.2706E-15 1.0000 0.2832E-15 0.2832E-15 HCl,gas 0.2989E-17 1.0000 0.3128E-17 0.3128E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 17 albite -0.38 -0.38 0.00 0.000 -0.94784E-12 23 andradite 39.01 39.01 0.00 0.000 0.12132E-10 24 grossular 32.73 32.73 0.00 0.000 0.24265E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -15.19 -8.53 -2.843 0.14564E+05 -6.830 3 CH4,gas 4.54 1.15 -3.40 -0.850 0.58030E+04 -1.700 4 H2,gas 8.00 4.08 -3.92 -2.238 0.66866E+04 -2.217 5 H2S,gas -6.23 -14.62 -8.39 -4.197 0.14332E+05 -6.695 6 S2,gas -7.34 -37.42 -30.08 -4.628 0.51360E+05 -28.381 7 CO,gas 3.21 -11.11 -14.32 -4.406 0.24452E+05 -12.622 8 SO3,gas 17.12 -30.96 -48.08 -12.020 0.82095E+05 -46.381 9 SO2,gas 0.83 -26.87 -27.71 -7.389 0.47309E+05 -26.008 10 HF,gas 0.47 -16.77 -17.25 -8.623 0.29449E+05 -15.548 11 HCl,gas 5.19 -14.01 -19.20 -9.602 0.32790E+05 -17.505 12 acmite 7.71 6.62 -1.09 -0.114 0.18661E+04 16 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 20 spessartine 24.46 19.72 -4.74 -0.237 0.80916E+04 21 analcite 3.32 2.77 -0.55 -0.061 0.94039E+03 27 annite 20.12 17.38 -2.74 -0.152 0.46859E+04 28 phlogopite 27.06 25.38 -1.68 -0.094 0.28742E+04 30 anorthite 12.71 8.21 -4.50 -0.346 0.76818E+04 33 apatite-OH -18.15 -18.38 -0.23 -0.018 0.39357E+03 34 apatite-F -34.30 -35.16 -0.86 -0.071 0.14624E+04 38 aragonite 0.97 -2.14 -3.10 -1.034 0.52990E+04 39 brucite 12.57 9.29 -3.28 -0.656 0.55993E+04 40 calcite 0.81 -2.14 -2.95 -0.983 0.50348E+04 41 carnegieite-low 9.02 5.93 -3.10 -0.442 0.52884E+04 42 carnegieite-high 10.09 5.93 -4.17 -0.595 0.71154E+04 43 carpholite-Mg 8.58 4.45 -4.13 -0.276 0.70588E+04 44 carpholite-Fe 6.71 1.78 -4.93 -0.329 0.84213E+04 45 celadonite 5.34 3.65 -1.69 -0.100 0.28922E+04 46 celadonite-Fe 3.88 0.98 -2.90 -0.170 0.49451E+04 47 chrysotile 23.89 21.56 -2.33 -0.195 0.39862E+04 49 clinochlore 39.07 38.45 -0.62 -0.019 0.10576E+04 50 daphnite 28.97 25.11 -3.85 -0.120 0.65775E+04 52 chlorite-Al-free 47.17 43.12 -4.06 -0.169 0.69275E+04 54 chloritoid-Fe 9.17 4.94 -4.24 -0.283 0.72364E+04 55 chloritoid-Mn 11.40 7.55 -3.85 -0.257 0.65723E+04 57 coesite -2.38 -3.15 -0.78 -0.260 0.13300E+04 64 cristobalite -2.56 -3.15 -0.59 -0.198 0.10153E+04 66 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71234E+04 68 diaspore 2.87 0.73 -2.14 -0.357 0.36529E+04 69 diamond -3.10 -7.02 -3.92 -1.120 0.66930E+04 70 diopside 16.18 16.03 -0.15 -0.015 0.25510E+03 71 hedenbergite 14.21 13.36 -0.84 -0.084 0.14407E+04 74 enstatite 17.26 12.27 -5.00 -0.500 0.85311E+04 76 clinoenstatite 17.17 12.27 -4.90 -0.490 0.83627E+04 78 epidote 24.67 22.69 -1.98 -0.096 0.33822E+04 79 clinozoisite 22.81 18.84 -3.96 -0.180 0.67661E+04 80 epidote-Fe 29.84 26.53 -3.31 -0.172 0.56450E+04 81 fayalite 14.05 10.09 -3.96 -0.565 0.67565E+04 82 ferrosilite 11.15 6.93 -4.22 -0.422 0.71982E+04 86 gibbsite 4.08 0.73 -3.34 -0.478 0.57114E+04 87 glaucophane 22.97 20.79 -2.18 -0.059 0.37303E+04 88 glaucophane-Fe 17.28 12.79 -4.49 -0.121 0.76630E+04 89 graphite -3.55 -7.02 -3.48 -0.993 0.59353E+04 90 greenalite 16.14 13.56 -2.58 -0.215 0.44119E+04 93 hematite 12.57 9.16 -3.41 -0.413 0.58159E+04 94 heulandite -5.83 -7.56 -1.74 -0.079 0.29647E+04 98 jadeite 4.22 2.77 -1.44 -0.144 0.24659E+04 100 kalsilite 7.58 3.82 -3.76 -0.537 0.64209E+04 101 kaolinite -1.33 -4.84 -3.51 -0.319 0.59907E+04 104 laumontite 2.88 1.90 -0.98 -0.065 0.16767E+04 105 lawsonite 9.62 8.21 -1.40 -0.094 0.23985E+04 106 leucite 4.12 0.67 -3.45 -0.345 0.58915E+04 108 lizardite 23.24 21.56 -1.69 -0.140 0.28788E+04 110 magnetite 20.09 15.78 -4.31 -0.351 0.73515E+04 111 minnesotaite 10.39 7.25 -3.14 -0.185 0.53656E+04 115 manganosite 14.06 9.24 -4.82 -1.205 0.82298E+04 119 microcline -2.49 -2.49 0.00 0.000 0.30295E-01 123 muscovite 2.58 -1.02 -3.60 -0.212 0.61473E+04 124 paragonite 4.24 1.08 -3.15 -0.186 0.53864E+04 125 nepheline 8.34 5.93 -2.41 -0.345 0.41207E+04 137 phlogopite-Na 29.65 27.48 -2.16 -0.120 0.36929E+04 139 prehnite 19.37 18.11 -1.26 -0.074 0.21563E+04 140 prehnite-Fe 22.50 21.95 -0.54 -0.033 0.92740E+03 141 pumpellyite-Fe 46.27 43.57 -2.70 -0.060 0.46019E+04 142 pumpellyite-Mg 48.99 46.24 -2.75 -0.061 0.47010E+04 146 pyrrhotite -4.26 -8.00 -3.74 -1.247 0.63889E+04 147 pyrrhotiteFe0.875 -6.02 -9.34 -3.32 -1.221 0.56675E+04 148 pyroxmangite 7.40 6.08 -1.32 -0.263 0.22461E+04 149 pyrophyllite -6.18 -11.15 -4.98 -0.311 0.84954E+04 150 quartz -2.99 -3.15 -0.17 -0.055 0.28267E+03 154 rhodochrosite -0.98 -5.95 -4.98 -1.658 0.84947E+04 155 rhodonite 7.45 6.08 -1.36 -0.272 0.23263E+04 156 sanidine -1.28 -2.49 -1.21 -0.093 0.20678E+04 166 stilbite -7.52 -7.56 -0.04 -0.002 0.70822E+02 167 stilpnomelane-Fe 13.02 12.46 -0.56 -0.017 0.95069E+03 168 stilpnomelane-Mg 27.44 25.80 -1.64 -0.049 0.28073E+04 174 talc 16.49 15.25 -1.24 -0.073 0.21227E+04 177 tephroite 18.09 15.32 -2.76 -0.395 0.47200E+04 181 tridymite -2.63 -3.15 -0.53 -0.176 0.90264E+03 182 tremolite 47.87 47.31 -0.56 -0.015 0.95182E+03 183 ferroactinolite 38.45 33.97 -4.48 -0.121 0.76454E+04 184 troilite-low -4.41 -8.00 -3.59 -1.197 0.61317E+04 190 wairakite 3.95 1.90 -2.05 -0.121 0.34987E+04 191 walstromite 11.51 9.90 -1.61 -0.322 0.27517E+04 192 wollastonite 10.46 9.90 -0.56 -0.113 0.96213E+03 193 pseudo-wollastonite 11.00 9.90 -1.10 -0.220 0.18820E+04 194 zoisite 22.85 18.84 -4.01 -0.182 0.68402E+04 195 akaganeite 7.75 4.58 -3.17 -0.686 0.54205E+04 202 chalcedony -2.80 -3.15 -0.35 -0.118 0.60196E+03 204 montmorillonite-Ca -2.29 -6.17 -3.88 -0.240 0.66313E+04 205 montmorillonite-K -2.24 -6.27 -4.03 -0.247 0.68825E+04 206 montmorillonite-Mg -2.48 -6.80 -4.32 -0.267 0.73686E+04 207 montmorillonite-Na -2.04 -5.57 -3.54 -0.217 0.60374E+04 208 nontronite-Ca 3.21 -0.02 -3.24 -0.210 0.55275E+04 209 nontronite-H 2.53 -2.18 -4.71 -0.316 0.80406E+04 210 nontronite-K 3.34 -0.12 -3.46 -0.222 0.59020E+04 211 nontronite-Mg 3.07 -0.64 -3.72 -0.241 0.63489E+04 212 nontronite-Na 3.52 0.58 -2.94 -0.189 0.50228E+04 228 tobermorite 9.82 7.72 -2.11 -0.574 0.35945E+04 234 alabandite -0.98 -5.39 -4.41 -1.469 0.75262E+04 237 boehmite 4.41 0.73 -3.67 -0.612 0.62698E+04 239 ferrous-oxide 9.81 6.62 -3.19 -0.797 0.54464E+04 245 silica-amorphous -2.09 -3.15 -1.06 -0.355 0.18161E+04 247 an20ab80 2.02 1.34 -0.68 -0.053 0.11655E+04 248 an25ab75 2.65 1.76 -0.88 -0.068 0.15039E+04 249 an30ab70 3.28 2.19 -1.08 -0.083 0.18518E+04 250 tr.625ac.25prg.125 45.16 44.92 -0.24 -0.006 0.41131E+03 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 0.0000100 MOLES Current total amount of reactant added: 0.0003600 MOLES New total amount of reactant added: 0.0003700 MOLES Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.5508E-08 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 6 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 0.0003700 Water: Moles liquid = 0.4985E+02 kg liquid = 0.8981E+00 Moles total = 0.4985E+02 kg total = 0.8980E+00 Activity = 1.0000 Stoichiometric ionic strength = .1135381E-01 Osmotic coef. = 0.9681 True ionic strength = .2003845E-01 Chg. balance for total moles = -.5508E-08 Max. difference allowed = 0.1401E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.88849E-10 -10.0513 0.74651E-10 -10.1270 0.84020E+00 -0.0756 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.15525E-03 -3.8090 0.12966E-03 -3.8872 0.83514E+00 -0.0782 4 SO4-- 0.39525E-10 -10.4031 0.20520E-10 -10.6878 0.51917E+00 -0.2847 5 HCO3- 0.10648E-04 -4.9727 0.89057E-05 -5.0503 0.83637E+00 -0.0776 6 HS- 0.38404E-04 -4.4156 0.32077E-04 -4.4938 0.83527E+00 -0.0782 7 Al+++ 0.97703E-29 -29.0101 0.22559E-29 -29.6467 0.23089E+00 -0.6366 8 H4SiO4 0.69999E-03 -3.1549 0.69999E-03 -3.1549 0.10000E+01 0.0000 9 Ca++ 0.12187E-06 -6.9141 0.62808E-07 -7.2020 0.51536E+00 -0.2879 10 Mg++ 0.21139E-10 -10.6749 0.10844E-10 -10.9648 0.51300E+00 -0.2899 11 Fe++ 0.45373E-13 -13.3432 0.23302E-13 -13.6326 0.51356E+00 -0.2894 12 K+ 0.15651E-03 -3.8055 0.13093E-03 -3.8830 0.83656E+00 -0.0775 13 Na+ 0.19861E-01 -1.7020 0.16584E-01 -1.7803 0.83499E+00 -0.0783 14 Mn++ 0.18764E-10 -10.7267 0.96446E-11 -11.0157 0.51399E+00 -0.2890 15 F- 0.27526E-06 -6.5603 0.22941E-06 -6.6394 0.83342E+00 -0.0791 16 HPO4-- 0.45321E-07 -7.3437 0.23533E-07 -7.6283 0.51925E+00 -0.2846 18 HSiO3- 0.10484E-01 -1.9795 0.87555E-02 -2.0577 0.83514E+00 -0.0782 19 Ca(HSiO3)+ 0.14967E-07 -7.8249 0.12524E-07 -7.9023 0.83674E+00 -0.0774 20 Mg(HSiO3)+ 0.32161E-11 -11.4927 0.26910E-11 -11.5701 0.83674E+00 -0.0774 21 NaHSiO3,aq 0.23484E-02 -2.6292 0.23484E-02 -2.6292 0.10000E+01 0.0000 22 AlO+ 0.65816E-16 -16.1817 0.55071E-16 -16.2591 0.83674E+00 -0.0774 24 HAlO2,aq 0.14691E-09 -9.8329 0.14691E-09 -9.8329 0.10000E+01 0.0000 25 AlO2- 0.52257E-05 -5.2819 0.43563E-05 -5.3609 0.83363E+00 -0.0790 26 CH4,aq 0.13570E-04 -4.8674 0.13523E-04 -4.8689 0.99654E+00 -0.0015 27 C2H6,aq 0.68439E-14 -14.1647 0.68202E-14 -14.1662 0.99654E+00 -0.0015 31 CO,aq 0.16358E-15 -15.7863 0.16358E-15 -15.7863 0.10000E+01 0.0000 32 CO2,aq 0.14255E-08 -8.8460 0.14206E-08 -8.8475 0.99654E+00 -0.0015 33 CO3-2 0.20113E-04 -4.6965 0.10420E-04 -4.9821 0.51807E+00 -0.2856 34 CaCO3,aq 0.82063E-08 -8.0859 0.82063E-08 -8.0859 0.10000E+01 0.0000 35 Ca(HCO3)+ 0.17064E-10 -10.7679 0.14278E-10 -10.8453 0.83674E+00 -0.0774 36 CaCl+ 0.15750E-10 -10.8027 0.13179E-10 -10.8801 0.83674E+00 -0.0774 37 CaCl2,aq 0.40596E-15 -15.3915 0.40596E-15 -15.3915 0.10000E+01 0.0000 38 CaF+ 0.25141E-12 -12.5996 0.21037E-12 -12.6770 0.83674E+00 -0.0774 39 CaOH+ 0.71662E-07 -7.1447 0.59963E-07 -7.2221 0.83674E+00 -0.0774 40 CaSO4,aq 0.40926E-15 -15.3880 0.40926E-15 -15.3880 0.10000E+01 0.0000 41 HCl,aq 0.17737E-14 -14.7511 0.17737E-14 -14.7511 0.10000E+01 0.0000 45 HF,aq 0.11724E-12 -12.9309 0.11724E-12 -12.9309 0.10000E+01 0.0000 46 HF2- 0.10873E-19 -19.9637 0.90804E-20 -20.0419 0.83514E+00 -0.0782 48 FeCl+ 0.57152E-17 -17.2430 0.47821E-17 -17.3204 0.83674E+00 -0.0774 51 FeF+ 0.32646E-18 -18.4862 0.27317E-18 -18.5636 0.83674E+00 -0.0774 53 FeO,aq 0.16251E-09 -9.7891 0.16251E-09 -9.7891 0.10000E+01 0.0000 54 FeOH+ 0.12143E-10 -10.9157 0.10160E-10 -10.9931 0.83674E+00 -0.0774 55 HFeO2- 0.27274E-07 -7.5643 0.22777E-07 -7.6425 0.83514E+00 -0.0782 56 FeO+ 0.13528E-16 -16.8688 0.11319E-16 -16.9462 0.83674E+00 -0.0774 58 FeO2- 0.49767E-09 -9.3031 0.41563E-09 -9.3813 0.83514E+00 -0.0782 59 HFeO2,aq 0.39461E-11 -11.4038 0.39461E-11 -11.4038 0.10000E+01 0.0000 60 H2,aq 0.45997E-05 -5.3373 0.45838E-05 -5.3388 0.99654E+00 -0.0015 61 KCl,aq 0.30768E-09 -9.5119 0.30768E-09 -9.5119 0.10000E+01 0.0000 63 KOH,aq 0.74902E-06 -6.1255 0.74902E-06 -6.1255 0.10000E+01 0.0000 64 KSO4- 0.49922E-13 -13.3017 0.41692E-13 -13.3800 0.83514E+00 -0.0782 65 MgCO3,aq 0.35515E-12 -12.4496 0.35515E-12 -12.4496 0.10000E+01 0.0000 66 Mg(HCO3)+ 0.30105E-14 -14.5214 0.25190E-14 -14.5988 0.83674E+00 -0.0774 67 MgCl+ 0.24647E-14 -14.6082 0.20623E-14 -14.6856 0.83674E+00 -0.0774 68 MgF+ 0.16080E-15 -15.7937 0.13455E-15 -15.8711 0.83674E+00 -0.0774 69 MgOH+ 0.68466E-10 -10.1645 0.57289E-10 -10.2419 0.83674E+00 -0.0774 71 MnF+ 0.44538E-16 -16.3513 0.37267E-16 -16.4287 0.83674E+00 -0.0774 72 MnO,aq 0.17923E-08 -8.7466 0.17923E-08 -8.7466 0.10000E+01 0.0000 73 MnOH+ 0.46689E-09 -9.3308 0.39067E-09 -9.4082 0.83674E+00 -0.0774 74 MnO2-2 0.20602E-10 -10.6861 0.10673E-10 -10.9717 0.51807E+00 -0.2856 75 HMnO2- 0.20902E-09 -9.6798 0.17456E-09 -9.7581 0.83514E+00 -0.0782 78 MnCl+ 0.92030E-14 -14.0361 0.77005E-14 -14.1135 0.83674E+00 -0.0774 79 MnSO4,aq 0.57135E-19 -19.2431 0.57135E-19 -19.2431 0.10000E+01 0.0000 80 NaCl,aq 0.71260E-06 -6.1472 0.71260E-06 -6.1472 0.10000E+01 0.0000 81 NaF,aq 0.89070E-09 -9.0503 0.89070E-09 -9.0503 0.10000E+01 0.0000 82 NaOH,aq 0.95448E-04 -4.0202 0.95448E-04 -4.0202 0.10000E+01 0.0000 84 OH- 0.92842E-02 -2.0323 0.77396E-02 -2.1113 0.83363E+00 -0.0790 89 HPO3-2 0.64887E-15 -15.1878 0.33616E-15 -15.4735 0.51807E+00 -0.2856 91 H2PO3- 0.60256E-19 -19.2200 0.50322E-19 -19.2982 0.83514E+00 -0.0782 92 H3PO4,aq 0.91721E-18 -18.0375 0.91721E-18 -18.0375 0.10000E+01 0.0000 93 H2PO4- 0.38768E-10 -10.4115 0.32407E-10 -10.4894 0.83594E+00 -0.0778 94 PO4-3 0.10605E-08 -8.9745 0.25720E-09 -9.5897 0.24251E+00 -0.6153 98 HP2O7-3 0.95301E-18 -18.0209 0.22026E-18 -18.6571 0.23112E+00 -0.6362 99 P2O7-4 0.91511E-17 -17.0385 0.70488E-18 -18.1519 0.77027E-01 -1.1134 100 H2S,aq 0.74265E-08 -8.1292 0.74008E-08 -8.1307 0.99654E+00 -0.0015 101 S2-2 0.96008E-14 -14.0177 0.49739E-14 -14.3033 0.51807E+00 -0.2856 107 SO3-2 0.23257E-16 -16.6334 0.12223E-16 -16.9128 0.52557E+00 -0.2794 108 HSO3- 0.68410E-19 -19.1649 0.57132E-19 -19.2431 0.83514E+00 -0.0782 109 HSO4- 0.17626E-17 -17.7538 0.14763E-17 -17.8308 0.83756E+00 -0.0770 Charge balance for all species = -.6133E-08 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.8884934E-10 -.2225499E-01 -.2239268E+02 0.0000 2 H2O 0.1000000E+01 0.5550483E+02 0.9981972E+06 0.0000 3 Cl- 0.1552533E-03 0.1559663E-03 0.5519856E+01 6.2398 4 SO4-- 0.3952487E-10 -.1471977E-04 -.1411545E+01 9.5661 5 HCO3- 0.1064807E-04 0.4434109E-04 0.2700864E+01 5.0766 6 HS- 0.3840360E-04 0.5313083E-04 0.1754087E+01 5.6332 7 Al+++ 0.9770264E-29 0.5225851E-05 0.1407561E+00 0.7342 8 H4SiO4 0.6999865E-03 0.1353223E-01 0.1298394E+04 -3.1549 9 Ca++ 0.1218725E-06 0.2167409E-06 0.8671434E-02 13.0519 10 Mg++ 0.2113909E-10 0.9318219E-10 0.2261506E-05 9.2891 11 Fe++ 0.4537266E-13 0.2794984E-07 0.1558200E-02 6.6213 12 K+ 0.1565111E-03 0.1572604E-03 0.6138502E+01 6.2440 13 Na+ 0.1986133E-01 0.2230592E-01 0.5119168E+03 8.3467 14 Mn++ 0.1876426E-10 0.2507557E-08 0.1375206E-03 9.2382 15 F- 0.2752595E-06 0.2761506E-06 0.5237185E-02 3.4876 16 HPO4-- 0.4532092E-07 0.4642023E-07 0.4447619E-02 12.6256 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.1998670E-01 -.1998633E-01 -.3683341E-06 0.0000000E+00 2 H2O 0.4984671E+02 0.4984671E+02 -.3267599E-06 0.0000000E+00 3 Cl- 0.1400672E-03 0.1400672E-03 0.0000000E+00 0.0000000E+00 4 SO4-- -.1321831E-04 -.1321925E-04 0.9364513E-09 0.0000000E+00 5 HCO3- 0.3982100E-04 0.3982100E-04 0.0000000E+00 0.0000000E+00 6 HS- 0.4771378E-04 0.4771472E-04 -.9364513E-09 0.0000000E+00 7 Al+++ 0.4775352E-05 0.4693132E-05 0.8221992E-07 0.0000000E+00 8 H4SiO4 0.1215302E-01 0.1215276E-01 0.2556976E-06 0.0000000E+00 9 Ca++ 0.2080835E-06 0.1946465E-06 0.1343702E-07 0.0000000E+00 10 Mg++ 0.8368328E-10 0.8368328E-10 0.0000000E+00 0.0000000E+00 11 Fe++ 0.3259227E-07 0.2510066E-07 0.7491610E-08 0.0000000E+00 12 K+ 0.1412294E-03 0.1412294E-03 0.0000000E+00 0.0000000E+00 13 Na+ 0.2003215E-01 0.2003207E-01 0.8075351E-07 0.0000000E+00 14 Mn++ 0.2251939E-08 0.2251939E-08 0.0000000E+00 0.0000000E+00 15 F- 0.2480000E-06 0.2480000E-06 0.0000000E+00 0.0000000E+00 16 HPO4-- 0.4168819E-07 0.4168819E-07 0.0000000E+00 0.0000000E+00 Chg. balance for solid moles: -.1323E-22 Mass of aqueous solution: 0.899625E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 0.0003700 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 0.8075E-07 -7.093 0.2118E-04 -4.674 90.46 0.8129E-05 andradite 0.3746E-08 -8.426 0.1904E-05 -5.720 8.132 0.4946E-06 grossular 0.7332E-09 -9.135 0.3303E-06 -6.481 1.411 0.9190E-07 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8363E+00 0.8363E+00 1.0000 -0.078 grossular 0.1637E+00 0.1637E+00 1.0000 -0.786 Solid products produced: Mass = 0.000023 g Volume = 0.000009 cm3 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.0003700 moles log = -3.4318 Original solution: 1000.0103000 g Original solution / Rock added: 2702730.54 (Water/Rock Ratio), log = 6.4318 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0463 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9755E+00 0.9856 0.1006E+01 0.1021E+01 CO2,gas 0.1443E-06 1.0069 0.1520E-06 0.1509E-06 CH4,gas 0.1879E-01 1.0123 0.1990E-01 0.1966E-01 H2,gas 0.5748E-02 1.0006 0.6018E-02 0.6015E-02 H2S,gas 0.1952E-06 0.9959 0.2034E-06 0.2043E-06 S2,gas 0.4100E-28 1.0000 0.4290E-28 0.4290E-28 CO,gas 0.2330E-12 1.0000 0.2438E-12 0.2438E-12 SO3,gas 0.4132E-46 1.0000 0.4324E-46 0.4324E-46 SO2,gas 0.9675E-26 1.0000 0.1012E-25 0.1012E-25 HF,gas 0.2751E-15 1.0000 0.2879E-15 0.2879E-15 HCl,gas 0.2991E-17 1.0000 0.3130E-17 0.3130E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 17 albite -0.38 -0.38 0.00 0.000 0.11184E-10 23 andradite 39.01 39.01 0.00 0.000 0.24265E-10 24 grossular 32.73 32.73 0.00 0.000 0.24265E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -15.18 -8.52 -2.839 0.14543E+05 -6.818 3 CH4,gas 4.54 1.14 -3.40 -0.850 0.58054E+04 -1.701 4 H2,gas 8.00 4.08 -3.92 -2.240 0.66925E+04 -2.221 5 H2S,gas -6.23 -14.62 -8.39 -4.195 0.14327E+05 -6.692 6 S2,gas -7.34 -37.40 -30.07 -4.626 0.51338E+05 -28.368 7 CO,gas 3.21 -11.10 -14.31 -4.404 0.24437E+05 -12.613 8 SO3,gas 17.12 -30.94 -48.06 -12.016 0.82066E+05 -46.364 9 SO2,gas 0.83 -26.86 -27.69 -7.385 0.47286E+05 -25.995 10 HF,gas 0.47 -16.77 -17.24 -8.620 0.29436E+05 -15.541 11 HCl,gas 5.19 -14.01 -19.20 -9.602 0.32789E+05 -17.504 12 acmite 7.71 6.62 -1.09 -0.113 0.18640E+04 16 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 20 spessartine 24.46 19.72 -4.74 -0.237 0.80917E+04 21 analcite 3.32 2.77 -0.55 -0.061 0.94051E+03 27 annite 20.12 17.38 -2.75 -0.153 0.46887E+04 28 phlogopite 27.06 25.38 -1.68 -0.094 0.28749E+04 30 anorthite 12.71 8.21 -4.50 -0.346 0.76832E+04 33 apatite-OH -18.15 -18.39 -0.23 -0.018 0.39882E+03 34 apatite-F -34.30 -35.15 -0.85 -0.071 0.14555E+04 38 aragonite 0.97 -2.13 -3.09 -1.031 0.52793E+04 39 brucite 12.57 9.29 -3.28 -0.656 0.55995E+04 40 calcite 0.81 -2.13 -2.94 -0.979 0.50151E+04 41 carnegieite-low 9.02 5.93 -3.10 -0.442 0.52886E+04 42 carnegieite-high 10.09 5.93 -4.17 -0.595 0.71156E+04 43 carpholite-Mg 8.58 4.45 -4.13 -0.276 0.70593E+04 44 carpholite-Fe 6.71 1.78 -4.93 -0.329 0.84225E+04 45 celadonite 5.34 3.65 -1.69 -0.100 0.28923E+04 46 celadonite-Fe 3.88 0.98 -2.90 -0.170 0.49459E+04 47 chrysotile 23.89 21.56 -2.33 -0.195 0.39866E+04 49 clinochlore 39.07 38.45 -0.62 -0.019 0.10589E+04 50 daphnite 28.97 25.11 -3.85 -0.120 0.65823E+04 52 chlorite-Al-free 47.17 43.12 -4.06 -0.169 0.69285E+04 54 chloritoid-Fe 9.17 4.93 -4.24 -0.283 0.72376E+04 55 chloritoid-Mn 11.40 7.55 -3.85 -0.257 0.65727E+04 57 coesite -2.38 -3.15 -0.78 -0.260 0.13299E+04 64 cristobalite -2.56 -3.15 -0.59 -0.198 0.10152E+04 66 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71234E+04 68 diaspore 2.87 0.73 -2.14 -0.357 0.36531E+04 69 diamond -3.10 -7.02 -3.91 -1.118 0.66838E+04 70 diopside 16.18 16.03 -0.15 -0.015 0.25630E+03 71 hedenbergite 14.21 13.36 -0.84 -0.084 0.14425E+04 74 enstatite 17.26 12.27 -5.00 -0.500 0.85313E+04 76 clinoenstatite 17.17 12.27 -4.90 -0.490 0.83629E+04 78 epidote 24.67 22.69 -1.98 -0.096 0.33828E+04 79 clinozoisite 22.81 18.84 -3.96 -0.180 0.67688E+04 80 epidote-Fe 29.84 26.54 -3.31 -0.172 0.56433E+04 81 fayalite 14.05 10.09 -3.96 -0.565 0.67582E+04 82 ferrosilite 11.15 6.93 -4.22 -0.422 0.71998E+04 86 gibbsite 4.08 0.73 -3.35 -0.478 0.57117E+04 87 glaucophane 22.97 20.79 -2.18 -0.059 0.37308E+04 88 glaucophane-Fe 17.28 12.79 -4.49 -0.121 0.76656E+04 89 graphite -3.55 -7.02 -3.47 -0.992 0.59260E+04 90 greenalite 16.14 13.55 -2.59 -0.215 0.44145E+04 93 hematite 12.57 9.16 -3.40 -0.413 0.58119E+04 94 heulandite -5.83 -7.56 -1.74 -0.079 0.29655E+04 98 jadeite 4.22 2.77 -1.44 -0.144 0.24660E+04 100 kalsilite 7.58 3.82 -3.76 -0.537 0.64211E+04 101 kaolinite -1.33 -4.84 -3.51 -0.319 0.59909E+04 104 laumontite 2.88 1.90 -0.98 -0.066 0.16779E+04 105 lawsonite 9.62 8.21 -1.41 -0.094 0.23999E+04 106 leucite 4.12 0.67 -3.45 -0.345 0.58916E+04 108 lizardite 23.24 21.56 -1.69 -0.141 0.28793E+04 110 magnetite 20.09 15.78 -4.30 -0.351 0.73484E+04 111 minnesotaite 10.39 7.24 -3.14 -0.185 0.53680E+04 115 manganosite 14.06 9.24 -4.82 -1.205 0.82299E+04 119 microcline -2.49 -2.49 0.00 0.000 0.31139E-01 123 muscovite 2.58 -1.02 -3.60 -0.212 0.61478E+04 124 paragonite 4.24 1.08 -3.15 -0.186 0.53869E+04 125 nepheline 8.34 5.93 -2.41 -0.345 0.41210E+04 137 phlogopite-Na 29.65 27.48 -2.16 -0.120 0.36937E+04 139 prehnite 19.37 18.11 -1.26 -0.074 0.21588E+04 140 prehnite-Fe 22.50 21.95 -0.54 -0.033 0.92769E+03 141 pumpellyite-Fe 46.27 43.57 -2.70 -0.060 0.46081E+04 142 pumpellyite-Mg 48.99 46.24 -2.76 -0.061 0.47065E+04 146 pyrrhotite -4.26 -8.00 -3.74 -1.246 0.63845E+04 147 pyrrhotiteFe0.875 -6.02 -9.33 -3.32 -1.220 0.56622E+04 148 pyroxmangite 7.40 6.08 -1.32 -0.263 0.22460E+04 149 pyrophyllite -6.18 -11.15 -4.98 -0.311 0.84954E+04 150 quartz -2.99 -3.15 -0.17 -0.055 0.28254E+03 154 rhodochrosite -0.98 -5.94 -4.96 -1.654 0.84738E+04 155 rhodonite 7.45 6.08 -1.36 -0.272 0.23262E+04 156 sanidine -1.28 -2.49 -1.21 -0.093 0.20678E+04 166 stilbite -7.52 -7.56 -0.04 -0.002 0.71644E+02 167 stilpnomelane-Fe 13.02 12.46 -0.56 -0.017 0.95492E+03 168 stilpnomelane-Mg 27.44 25.80 -1.64 -0.049 0.28081E+04 174 talc 16.49 15.25 -1.24 -0.073 0.21229E+04 177 tephroite 18.09 15.32 -2.76 -0.395 0.47199E+04 181 tridymite -2.63 -3.15 -0.53 -0.176 0.90252E+03 182 tremolite 47.87 47.31 -0.56 -0.015 0.95448E+03 183 ferroactinolite 38.45 33.97 -4.48 -0.121 0.76515E+04 184 troilite-low -4.41 -8.00 -3.59 -1.196 0.61273E+04 190 wairakite 3.95 1.90 -2.05 -0.121 0.34999E+04 191 walstromite 11.51 9.90 -1.61 -0.322 0.27528E+04 192 wollastonite 10.46 9.90 -0.56 -0.113 0.96321E+03 193 pseudo-wollastonite 11.00 9.90 -1.10 -0.221 0.18830E+04 194 zoisite 22.85 18.84 -4.01 -0.182 0.68429E+04 195 akaganeite 7.75 4.58 -3.17 -0.686 0.54185E+04 202 chalcedony -2.80 -3.15 -0.35 -0.117 0.60184E+03 204 montmorillonite-Ca -2.29 -6.17 -3.88 -0.240 0.66315E+04 205 montmorillonite-K -2.24 -6.27 -4.03 -0.247 0.68826E+04 206 montmorillonite-Mg -2.48 -6.80 -4.32 -0.267 0.73686E+04 207 montmorillonite-Na -2.04 -5.57 -3.54 -0.217 0.60375E+04 208 nontronite-Ca 3.21 -0.02 -3.23 -0.210 0.55234E+04 209 nontronite-H 2.53 -2.17 -4.71 -0.315 0.80363E+04 210 nontronite-K 3.34 -0.11 -3.45 -0.222 0.58977E+04 211 nontronite-Mg 3.07 -0.64 -3.72 -0.241 0.63446E+04 212 nontronite-Na 3.52 0.58 -2.94 -0.189 0.50185E+04 228 tobermorite 9.82 7.72 -2.11 -0.575 0.35954E+04 234 alabandite -0.98 -5.38 -4.40 -1.468 0.75209E+04 237 boehmite 4.41 0.73 -3.67 -0.612 0.62700E+04 239 ferrous-oxide 9.81 6.62 -3.19 -0.798 0.54473E+04 245 silica-amorphous -2.09 -3.15 -1.06 -0.355 0.18160E+04 247 an20ab80 2.02 1.34 -0.68 -0.053 0.11658E+04 248 an25ab75 2.65 1.76 -0.88 -0.068 0.15042E+04 249 an30ab70 3.28 2.19 -1.08 -0.083 0.18523E+04 250 tr.625ac.25prg.125 45.16 44.92 -0.24 -0.007 0.41494E+03 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 0.0000100 MOLES Current total amount of reactant added: 0.0003700 MOLES New total amount of reactant added: 0.0003800 MOLES Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.5508E-08 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 6 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 0.0003800 Water: Moles liquid = 0.4985E+02 kg liquid = 0.8981E+00 Moles total = 0.4985E+02 kg total = 0.8980E+00 Activity = 1.0000 Stoichiometric ionic strength = .1135445E-01 Osmotic coef. = 0.9681 True ionic strength = .2003904E-01 Chg. balance for total moles = -.5508E-08 Max. difference allowed = 0.1401E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.88865E-10 -10.0513 0.74664E-10 -10.1269 0.84020E+00 -0.0756 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.15532E-03 -3.8088 0.12971E-03 -3.8870 0.83514E+00 -0.0782 4 SO4-- 0.41041E-10 -10.3868 0.21307E-10 -10.6715 0.51917E+00 -0.2847 5 HCO3- 0.10943E-04 -4.9609 0.91525E-05 -5.0385 0.83636E+00 -0.0776 6 HS- 0.38674E-04 -4.4126 0.32303E-04 -4.4908 0.83526E+00 -0.0782 7 Al+++ 0.97725E-29 -29.0100 0.22564E-29 -29.6466 0.23089E+00 -0.6366 8 H4SiO4 0.70010E-03 -3.1548 0.70010E-03 -3.1548 0.10000E+01 0.0000 9 Ca++ 0.12172E-06 -6.9146 0.62729E-07 -7.2025 0.51535E+00 -0.2879 10 Mg++ 0.21140E-10 -10.6749 0.10845E-10 -10.9648 0.51299E+00 -0.2899 11 Fe++ 0.45335E-13 -13.3436 0.23282E-13 -13.6330 0.51356E+00 -0.2894 12 K+ 0.15651E-03 -3.8055 0.13093E-03 -3.8830 0.83656E+00 -0.0775 13 Na+ 0.19861E-01 -1.7020 0.16584E-01 -1.7803 0.83499E+00 -0.0783 14 Mn++ 0.18771E-10 -10.7265 0.96478E-11 -11.0156 0.51398E+00 -0.2891 15 F- 0.27970E-06 -6.5533 0.23311E-06 -6.6324 0.83342E+00 -0.0791 16 HPO4-- 0.45321E-07 -7.3437 0.23533E-07 -7.6283 0.51924E+00 -0.2846 18 HSiO3- 0.10484E-01 -1.9795 0.87554E-02 -2.0577 0.83514E+00 -0.0782 19 Ca(HSiO3)+ 0.14948E-07 -7.8254 0.12508E-07 -7.9028 0.83674E+00 -0.0774 20 Mg(HSiO3)+ 0.32161E-11 -11.4927 0.26910E-11 -11.5701 0.83674E+00 -0.0774 21 NaHSiO3,aq 0.23484E-02 -2.6292 0.23484E-02 -2.6292 0.10000E+01 0.0000 22 AlO+ 0.65806E-16 -16.1817 0.55063E-16 -16.2591 0.83674E+00 -0.0774 24 HAlO2,aq 0.14687E-09 -9.8331 0.14687E-09 -9.8331 0.10000E+01 0.0000 25 AlO2- 0.52231E-05 -5.2821 0.43542E-05 -5.3611 0.83363E+00 -0.0790 26 CH4,aq 0.13526E-04 -4.8688 0.13479E-04 -4.8704 0.99654E+00 -0.0015 27 C2H6,aq 0.68518E-14 -14.1642 0.68281E-14 -14.1657 0.99654E+00 -0.0015 31 CO,aq 0.16685E-15 -15.7777 0.16685E-15 -15.7777 0.10000E+01 0.0000 32 CO2,aq 0.14653E-08 -8.8341 0.14602E-08 -8.8356 0.99654E+00 -0.0015 33 CO3-2 0.20667E-04 -4.6847 0.10707E-04 -4.9703 0.51806E+00 -0.2856 34 CaCO3,aq 0.84217E-08 -8.0746 0.84217E-08 -8.0746 0.10000E+01 0.0000 35 Ca(HCO3)+ 0.17515E-10 -10.7566 0.14655E-10 -10.8340 0.83674E+00 -0.0774 36 CaCl+ 0.15737E-10 -10.8031 0.13168E-10 -10.8805 0.83674E+00 -0.0774 37 CaCl2,aq 0.40579E-15 -15.3917 0.40579E-15 -15.3917 0.10000E+01 0.0000 38 CaF+ 0.25514E-12 -12.5932 0.21349E-12 -12.6706 0.83674E+00 -0.0774 39 CaOH+ 0.71559E-07 -7.1453 0.59877E-07 -7.2227 0.83674E+00 -0.0774 40 CaSO4,aq 0.42442E-15 -15.3722 0.42442E-15 -15.3722 0.10000E+01 0.0000 41 HCl,aq 0.17747E-14 -14.7509 0.17747E-14 -14.7509 0.10000E+01 0.0000 45 HF,aq 0.11915E-12 -12.9239 0.11915E-12 -12.9239 0.10000E+01 0.0000 46 HF2- 0.11228E-19 -19.9497 0.93772E-20 -20.0279 0.83514E+00 -0.0782 48 FeCl+ 0.57128E-17 -17.2432 0.47801E-17 -17.3206 0.83674E+00 -0.0774 51 FeF+ 0.33145E-18 -18.4796 0.27734E-18 -18.5570 0.83674E+00 -0.0774 53 FeO,aq 0.16231E-09 -9.7896 0.16231E-09 -9.7896 0.10000E+01 0.0000 54 FeOH+ 0.12130E-10 -10.9161 0.10150E-10 -10.9935 0.83674E+00 -0.0774 55 HFeO2- 0.27236E-07 -7.5649 0.22746E-07 -7.6431 0.83514E+00 -0.0782 56 FeO+ 0.13566E-16 -16.8675 0.11352E-16 -16.9449 0.83674E+00 -0.0774 58 FeO2- 0.49890E-09 -9.3020 0.41666E-09 -9.3802 0.83514E+00 -0.0782 59 HFeO2,aq 0.39566E-11 -11.4027 0.39566E-11 -11.4027 0.10000E+01 0.0000 60 H2,aq 0.45645E-05 -5.3406 0.45487E-05 -5.3421 0.99654E+00 -0.0015 61 KCl,aq 0.30781E-09 -9.5117 0.30781E-09 -9.5117 0.10000E+01 0.0000 63 KOH,aq 0.74889E-06 -6.1256 0.74889E-06 -6.1256 0.10000E+01 0.0000 64 KSO4- 0.51836E-13 -13.2854 0.43290E-13 -13.3636 0.83514E+00 -0.0782 65 MgCO3,aq 0.36494E-12 -12.4378 0.36494E-12 -12.4378 0.10000E+01 0.0000 66 Mg(HCO3)+ 0.30940E-14 -14.5095 0.25888E-14 -14.5869 0.83674E+00 -0.0774 67 MgCl+ 0.24658E-14 -14.6080 0.20632E-14 -14.6854 0.83674E+00 -0.0774 68 MgF+ 0.16339E-15 -15.7868 0.13672E-15 -15.8642 0.83674E+00 -0.0774 69 MgOH+ 0.68456E-10 -10.1646 0.57280E-10 -10.2420 0.83674E+00 -0.0774 71 MnF+ 0.45272E-16 -16.3442 0.37881E-16 -16.4216 0.83674E+00 -0.0774 72 MnO,aq 0.17922E-08 -8.7466 0.17922E-08 -8.7466 0.10000E+01 0.0000 73 MnOH+ 0.46697E-09 -9.3307 0.39073E-09 -9.4081 0.83674E+00 -0.0774 74 MnO2-2 0.20595E-10 -10.6862 0.10669E-10 -10.9719 0.51806E+00 -0.2856 75 HMnO2- 0.20898E-09 -9.6799 0.17453E-09 -9.7581 0.83514E+00 -0.0782 78 MnCl+ 0.92099E-14 -14.0357 0.77063E-14 -14.1132 0.83674E+00 -0.0774 79 MnSO4,aq 0.59345E-19 -19.2266 0.59345E-19 -19.2266 0.10000E+01 0.0000 80 NaCl,aq 0.71290E-06 -6.1470 0.71290E-06 -6.1470 0.10000E+01 0.0000 81 NaF,aq 0.90507E-09 -9.0433 0.90507E-09 -9.0433 0.10000E+01 0.0000 82 NaOH,aq 0.95431E-04 -4.0203 0.95431E-04 -4.0203 0.10000E+01 0.0000 84 OH- 0.92826E-02 -2.0323 0.77383E-02 -2.1114 0.83363E+00 -0.0790 89 HPO3-2 0.64389E-15 -15.1912 0.33358E-15 -15.4768 0.51806E+00 -0.2856 91 H2PO3- 0.59804E-19 -19.2233 0.49945E-19 -19.3015 0.83514E+00 -0.0782 92 H3PO4,aq 0.91752E-18 -18.0374 0.91752E-18 -18.0374 0.10000E+01 0.0000 93 H2PO4- 0.38774E-10 -10.4115 0.32413E-10 -10.4893 0.83593E+00 -0.0778 94 PO4-3 0.10604E-08 -8.9745 0.25715E-09 -9.5898 0.24251E+00 -0.6153 98 HP2O7-3 0.95319E-18 -18.0208 0.22030E-18 -18.6570 0.23112E+00 -0.6362 99 P2O7-4 0.91513E-17 -17.0385 0.70488E-18 -18.1519 0.77025E-01 -1.1134 100 H2S,aq 0.74801E-08 -8.1261 0.74542E-08 -8.1276 0.99654E+00 -0.0015 101 S2-2 0.98118E-14 -14.0082 0.50832E-14 -14.2939 0.51806E+00 -0.2856 107 SO3-2 0.23964E-16 -16.6204 0.12595E-16 -16.8998 0.52556E+00 -0.2794 108 HSO3- 0.70501E-19 -19.1518 0.58878E-19 -19.2300 0.83514E+00 -0.0782 109 HSO4- 0.18305E-17 -17.7374 0.15332E-17 -17.8144 0.83756E+00 -0.0770 Charge balance for all species = -.6133E-08 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.8886506E-10 -.2225377E-01 -.2239146E+02 0.0000 2 H2O 0.1000000E+01 0.5550483E+02 0.9981972E+06 0.0000 3 Cl- 0.1553187E-03 0.1560319E-03 0.5522180E+01 6.2399 4 SO4-- 0.4104086E-10 -.1466660E-04 -.1406447E+01 9.5823 5 HCO3- 0.1094322E-04 0.4514615E-04 0.2749901E+01 5.0884 6 HS- 0.3867412E-04 0.5334824E-04 0.1761265E+01 5.6361 7 Al+++ 0.9772479E-29 0.5223295E-05 0.1406873E+00 0.7341 8 H4SiO4 0.7001012E-03 0.1353222E-01 0.1298393E+04 -3.1548 9 Ca++ 0.1217202E-06 0.2166830E-06 0.8669119E-02 13.0512 10 Mg++ 0.2113967E-10 0.9318218E-10 0.2261505E-05 9.2890 11 Fe++ 0.4533461E-13 0.2791354E-07 0.1556176E-02 6.6208 12 K+ 0.1565112E-03 0.1572604E-03 0.6138501E+01 6.2439 13 Na+ 0.1986136E-01 0.2230591E-01 0.5119166E+03 8.3466 14 Mn++ 0.1877063E-10 0.2507557E-08 0.1375206E-03 9.2382 15 F- 0.2796991E-06 0.2806045E-06 0.5321654E-02 3.4944 16 HPO4-- 0.4532107E-07 0.4642022E-07 0.4447618E-02 12.6254 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.1998562E-01 -.1998525E-01 -.3776739E-06 0.0000000E+00 2 H2O 0.4984672E+02 0.4984672E+02 -.3359450E-06 0.0000000E+00 3 Cl- 0.1401262E-03 0.1401262E-03 0.0000000E+00 0.0000000E+00 4 SO4-- -.1317056E-04 -.1317150E-04 0.9405261E-09 0.0000000E+00 5 HCO3- 0.4054400E-04 0.4054400E-04 0.0000000E+00 0.0000000E+00 6 HS- 0.4790903E-04 0.4790997E-04 -.9405261E-09 0.0000000E+00 7 Al+++ 0.4775352E-05 0.4690838E-05 0.8451415E-07 0.0000000E+00 8 H4SiO4 0.1215302E-01 0.1215276E-01 0.2626261E-06 0.0000000E+00 9 Ca++ 0.2080835E-06 0.1945946E-06 0.1348894E-07 0.0000000E+00 10 Mg++ 0.8368328E-10 0.8368328E-10 0.0000000E+00 0.0000000E+00 11 Fe++ 0.3259227E-07 0.2506806E-07 0.7524209E-08 0.0000000E+00 12 K+ 0.1412294E-03 0.1412294E-03 0.0000000E+00 0.0000000E+00 13 Na+ 0.2003215E-01 0.2003207E-01 0.8304573E-07 0.0000000E+00 14 Mn++ 0.2251939E-08 0.2251939E-08 0.0000000E+00 0.0000000E+00 15 F- 0.2520000E-06 0.2520000E-06 0.0000000E+00 0.0000000E+00 16 HPO4-- 0.4168819E-07 0.4168819E-07 0.0000000E+00 0.0000000E+00 Chg. balance for solid moles: 0.1323E-22 Mass of aqueous solution: 0.899626E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 0.0003800 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 0.8305E-07 -7.081 0.2178E-04 -4.662 90.66 0.8359E-05 andradite 0.3762E-08 -8.425 0.1912E-05 -5.719 7.960 0.4967E-06 grossular 0.7342E-09 -9.134 0.3307E-06 -6.481 1.377 0.9202E-07 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8367E+00 0.8367E+00 1.0000 -0.077 grossular 0.1633E+00 0.1633E+00 1.0000 -0.787 Solid products produced: Mass = 0.000024 g Volume = 0.000009 cm3 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.0003800 moles log = -3.4202 Original solution: 1000.0103000 g Original solution / Rock added: 2631606.05 (Water/Rock Ratio), log = 6.4202 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0462 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9756E+00 0.9856 0.1006E+01 0.1021E+01 CO2,gas 0.1483E-06 1.0069 0.1562E-06 0.1552E-06 CH4,gas 0.1873E-01 1.0123 0.1984E-01 0.1960E-01 H2,gas 0.5705E-02 1.0006 0.5972E-02 0.5969E-02 H2S,gas 0.1967E-06 0.9959 0.2049E-06 0.2057E-06 S2,gas 0.4224E-28 1.0000 0.4419E-28 0.4419E-28 CO,gas 0.2377E-12 1.0000 0.2486E-12 0.2486E-12 SO3,gas 0.4293E-46 1.0000 0.4491E-46 0.4491E-46 SO2,gas 0.9974E-26 1.0000 0.1043E-25 0.1043E-25 HF,gas 0.2796E-15 1.0000 0.2925E-15 0.2925E-15 HCl,gas 0.2993E-17 1.0000 0.3132E-17 0.3132E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 17 albite -0.38 -0.38 0.00 0.000 -0.13080E-10 23 andradite 39.01 39.01 0.00 0.000 -0.12132E-10 24 grossular 32.73 32.73 0.00 0.000 0.00000E+00 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -15.17 -8.51 -2.835 0.14522E+05 -6.806 3 CH4,gas 4.54 1.14 -3.40 -0.850 0.58079E+04 -1.702 4 H2,gas 8.00 4.08 -3.92 -2.242 0.66982E+04 -2.224 5 H2S,gas -6.23 -14.62 -8.39 -4.194 0.14321E+05 -6.688 6 S2,gas -7.34 -37.39 -30.05 -4.624 0.51316E+05 -28.355 7 CO,gas 3.21 -11.09 -14.30 -4.401 0.24423E+05 -12.604 8 SO3,gas 17.12 -30.93 -48.05 -12.012 0.82038E+05 -46.348 9 SO2,gas 0.83 -26.85 -27.68 -7.381 0.47264E+05 -25.982 10 HF,gas 0.47 -16.76 -17.23 -8.616 0.29424E+05 -15.534 11 HCl,gas 5.19 -14.01 -19.20 -9.602 0.32789E+05 -17.504 12 acmite 7.71 6.62 -1.09 -0.113 0.18619E+04 16 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 20 spessartine 24.46 19.72 -4.74 -0.237 0.80919E+04 21 analcite 3.32 2.77 -0.55 -0.061 0.94063E+03 27 annite 20.12 17.38 -2.75 -0.153 0.46913E+04 28 phlogopite 27.06 25.38 -1.68 -0.094 0.28756E+04 30 anorthite 12.71 8.21 -4.50 -0.346 0.76847E+04 33 apatite-OH -18.15 -18.39 -0.24 -0.018 0.40401E+03 34 apatite-F -34.30 -35.15 -0.85 -0.071 0.14487E+04 38 aragonite 0.97 -2.11 -3.08 -1.027 0.52601E+04 39 brucite 12.57 9.29 -3.28 -0.656 0.55998E+04 40 calcite 0.81 -2.11 -2.93 -0.975 0.49959E+04 41 carnegieite-low 9.02 5.93 -3.10 -0.442 0.52889E+04 42 carnegieite-high 10.09 5.93 -4.17 -0.595 0.71159E+04 43 carpholite-Mg 8.58 4.45 -4.13 -0.276 0.70598E+04 44 carpholite-Fe 6.71 1.78 -4.93 -0.329 0.84236E+04 45 celadonite 5.34 3.65 -1.69 -0.100 0.28924E+04 46 celadonite-Fe 3.88 0.98 -2.90 -0.170 0.49467E+04 47 chrysotile 23.89 21.56 -2.34 -0.195 0.39871E+04 49 clinochlore 39.07 38.45 -0.62 -0.019 0.10603E+04 50 daphnite 28.97 25.11 -3.86 -0.121 0.65868E+04 52 chlorite-Al-free 47.17 43.11 -4.06 -0.169 0.69294E+04 54 chloritoid-Fe 9.17 4.93 -4.24 -0.283 0.72389E+04 55 chloritoid-Mn 11.40 7.55 -3.85 -0.257 0.65730E+04 57 coesite -2.38 -3.15 -0.78 -0.260 0.13297E+04 64 cristobalite -2.56 -3.15 -0.59 -0.198 0.10151E+04 66 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71234E+04 68 diaspore 2.87 0.73 -2.14 -0.357 0.36534E+04 69 diamond -3.10 -7.01 -3.91 -1.117 0.66748E+04 70 diopside 16.18 16.03 -0.15 -0.015 0.25750E+03 71 hedenbergite 14.21 13.36 -0.85 -0.085 0.14444E+04 74 enstatite 17.26 12.27 -5.00 -0.500 0.85316E+04 76 clinoenstatite 17.17 12.27 -4.90 -0.490 0.83632E+04 78 epidote 24.67 22.69 -1.98 -0.096 0.33833E+04 79 clinozoisite 22.81 18.84 -3.97 -0.180 0.67716E+04 80 epidote-Fe 29.84 26.54 -3.30 -0.172 0.56416E+04 81 fayalite 14.05 10.09 -3.96 -0.566 0.67599E+04 82 ferrosilite 11.15 6.93 -4.22 -0.422 0.72013E+04 86 gibbsite 4.08 0.73 -3.35 -0.478 0.57119E+04 87 glaucophane 22.97 20.79 -2.19 -0.059 0.37313E+04 88 glaucophane-Fe 17.28 12.78 -4.49 -0.121 0.76680E+04 89 graphite -3.55 -7.01 -3.47 -0.990 0.59170E+04 90 greenalite 16.14 13.55 -2.59 -0.216 0.44169E+04 93 hematite 12.57 9.16 -3.40 -0.412 0.58080E+04 94 heulandite -5.83 -7.56 -1.74 -0.079 0.29663E+04 98 jadeite 4.22 2.77 -1.44 -0.144 0.24661E+04 100 kalsilite 7.58 3.82 -3.76 -0.537 0.64214E+04 101 kaolinite -1.33 -4.84 -3.51 -0.319 0.59911E+04 104 laumontite 2.88 1.90 -0.98 -0.066 0.16791E+04 105 lawsonite 9.62 8.21 -1.41 -0.094 0.24013E+04 106 leucite 4.12 0.67 -3.45 -0.345 0.58917E+04 108 lizardite 23.24 21.56 -1.69 -0.141 0.28798E+04 110 magnetite 20.09 15.79 -4.30 -0.351 0.73454E+04 111 minnesotaite 10.39 7.24 -3.15 -0.185 0.53701E+04 115 manganosite 14.06 9.24 -4.82 -1.205 0.82299E+04 119 microcline -2.49 -2.49 0.00 0.000 0.31983E-01 123 muscovite 2.58 -1.02 -3.60 -0.212 0.61483E+04 124 paragonite 4.24 1.08 -3.16 -0.186 0.53873E+04 125 nepheline 8.34 5.93 -2.41 -0.345 0.41212E+04 137 phlogopite-Na 29.65 27.48 -2.16 -0.120 0.36944E+04 139 prehnite 19.37 18.11 -1.27 -0.074 0.21613E+04 140 prehnite-Fe 22.50 21.95 -0.54 -0.033 0.92798E+03 141 pumpellyite-Fe 46.27 43.57 -2.70 -0.060 0.46142E+04 142 pumpellyite-Mg 48.99 46.24 -2.76 -0.061 0.47119E+04 146 pyrrhotite -4.26 -8.00 -3.74 -1.246 0.63800E+04 147 pyrrhotiteFe0.875 -6.02 -9.33 -3.31 -1.218 0.56569E+04 148 pyroxmangite 7.40 6.08 -1.32 -0.263 0.22459E+04 149 pyrophyllite -6.18 -11.15 -4.98 -0.311 0.84954E+04 150 quartz -2.99 -3.15 -0.17 -0.055 0.28242E+03 154 rhodochrosite -0.98 -5.93 -4.95 -1.650 0.84534E+04 155 rhodonite 7.45 6.08 -1.36 -0.272 0.23261E+04 156 sanidine -1.28 -2.49 -1.21 -0.093 0.20678E+04 166 stilbite -7.52 -7.56 -0.04 -0.002 0.72455E+02 167 stilpnomelane-Fe 13.02 12.46 -0.56 -0.017 0.95892E+03 168 stilpnomelane-Mg 27.44 25.80 -1.65 -0.049 0.28089E+04 174 talc 16.49 15.25 -1.24 -0.073 0.21232E+04 177 tephroite 18.09 15.32 -2.76 -0.395 0.47198E+04 181 tridymite -2.63 -3.15 -0.53 -0.176 0.90240E+03 182 tremolite 47.87 47.31 -0.56 -0.015 0.95712E+03 183 ferroactinolite 38.45 33.97 -4.48 -0.121 0.76574E+04 184 troilite-low -4.41 -8.00 -3.59 -1.195 0.61228E+04 190 wairakite 3.95 1.90 -2.05 -0.121 0.35011E+04 191 walstromite 11.51 9.90 -1.61 -0.323 0.27539E+04 192 wollastonite 10.46 9.90 -0.56 -0.113 0.96428E+03 193 pseudo-wollastonite 11.00 9.90 -1.10 -0.221 0.18841E+04 194 zoisite 22.85 18.84 -4.01 -0.182 0.68456E+04 195 akaganeite 7.75 4.58 -3.17 -0.686 0.54165E+04 202 chalcedony -2.80 -3.15 -0.35 -0.117 0.60172E+03 204 montmorillonite-Ca -2.29 -6.17 -3.88 -0.240 0.66317E+04 205 montmorillonite-K -2.24 -6.27 -4.03 -0.247 0.68826E+04 206 montmorillonite-Mg -2.48 -6.80 -4.32 -0.267 0.73686E+04 207 montmorillonite-Na -2.04 -5.57 -3.54 -0.217 0.60375E+04 208 nontronite-Ca 3.21 -0.02 -3.23 -0.210 0.55193E+04 209 nontronite-H 2.53 -2.17 -4.70 -0.315 0.80320E+04 210 nontronite-K 3.34 -0.11 -3.45 -0.222 0.58934E+04 211 nontronite-Mg 3.07 -0.64 -3.71 -0.241 0.63403E+04 212 nontronite-Na 3.52 0.58 -2.94 -0.188 0.50143E+04 228 tobermorite 9.82 7.72 -2.11 -0.575 0.35963E+04 234 alabandite -0.98 -5.38 -4.40 -1.467 0.75156E+04 237 boehmite 4.41 0.73 -3.67 -0.612 0.62703E+04 239 ferrous-oxide 9.81 6.62 -3.19 -0.798 0.54482E+04 245 silica-amorphous -2.09 -3.15 -1.06 -0.355 0.18159E+04 247 an20ab80 2.02 1.33 -0.68 -0.053 0.11661E+04 248 an25ab75 2.65 1.76 -0.88 -0.068 0.15046E+04 249 an30ab70 3.28 2.19 -1.09 -0.083 0.18527E+04 250 tr.625ac.25prg.125 45.16 44.92 -0.25 -0.007 0.41848E+03 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 0.0000100 MOLES Current total amount of reactant added: 0.0003800 MOLES New total amount of reactant added: 0.0003900 MOLES Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.5508E-08 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 6 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 0.0003900 Water: Moles liquid = 0.4985E+02 kg liquid = 0.8981E+00 Moles total = 0.4985E+02 kg total = 0.8980E+00 Activity = 1.0000 Stoichiometric ionic strength = .1135509E-01 Osmotic coef. = 0.9681 True ionic strength = .2003963E-01 Chg. balance for total moles = -.5508E-08 Max. difference allowed = 0.1402E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.88881E-10 -10.0512 0.74677E-10 -10.1268 0.84020E+00 -0.0756 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.15538E-03 -3.8086 0.12977E-03 -3.8868 0.83514E+00 -0.0782 4 SO4-- 0.42584E-10 -10.3708 0.22108E-10 -10.6555 0.51916E+00 -0.2847 5 HCO3- 0.11239E-04 -4.9493 0.93995E-05 -5.0269 0.83636E+00 -0.0776 6 HS- 0.38945E-04 -4.4096 0.32529E-04 -4.4877 0.83526E+00 -0.0782 7 Al+++ 0.97747E-29 -29.0099 0.22568E-29 -29.6465 0.23089E+00 -0.6366 8 H4SiO4 0.70022E-03 -3.1548 0.70022E-03 -3.1548 0.10000E+01 0.0000 9 Ca++ 0.12157E-06 -6.9152 0.62651E-07 -7.2031 0.51535E+00 -0.2879 10 Mg++ 0.21140E-10 -10.6749 0.10845E-10 -10.9648 0.51299E+00 -0.2899 11 Fe++ 0.45299E-13 -13.3439 0.23264E-13 -13.6333 0.51355E+00 -0.2894 12 K+ 0.15651E-03 -3.8055 0.13093E-03 -3.8830 0.83656E+00 -0.0775 13 Na+ 0.19861E-01 -1.7020 0.16584E-01 -1.7803 0.83499E+00 -0.0783 14 Mn++ 0.18777E-10 -10.7264 0.96510E-11 -11.0154 0.51398E+00 -0.2891 15 F- 0.28414E-06 -6.5465 0.23681E-06 -6.6256 0.83342E+00 -0.0791 16 HPO4-- 0.45321E-07 -7.3437 0.23532E-07 -7.6283 0.51924E+00 -0.2846 18 HSiO3- 0.10484E-01 -1.9795 0.87553E-02 -2.0577 0.83514E+00 -0.0782 19 Ca(HSiO3)+ 0.14929E-07 -7.8260 0.12492E-07 -7.9034 0.83674E+00 -0.0774 20 Mg(HSiO3)+ 0.32161E-11 -11.4927 0.26911E-11 -11.5701 0.83674E+00 -0.0774 21 NaHSiO3,aq 0.23484E-02 -2.6292 0.23484E-02 -2.6292 0.10000E+01 0.0000 22 AlO+ 0.65797E-16 -16.1818 0.55055E-16 -16.2592 0.83674E+00 -0.0774 24 HAlO2,aq 0.14682E-09 -9.8332 0.14682E-09 -9.8332 0.10000E+01 0.0000 25 AlO2- 0.52206E-05 -5.2823 0.43520E-05 -5.3613 0.83363E+00 -0.0790 26 CH4,aq 0.13481E-04 -4.8703 0.13434E-04 -4.8718 0.99654E+00 -0.0015 27 C2H6,aq 0.68581E-14 -14.1638 0.68343E-14 -14.1653 0.99654E+00 -0.0015 31 CO,aq 0.17010E-15 -15.7693 0.17010E-15 -15.7693 0.10000E+01 0.0000 32 CO2,aq 0.15051E-08 -8.8224 0.14999E-08 -8.8240 0.99654E+00 -0.0015 33 CO3-2 0.21222E-04 -4.6732 0.10994E-04 -4.9588 0.51806E+00 -0.2856 34 CaCO3,aq 0.86367E-08 -8.0637 0.86367E-08 -8.0637 0.10000E+01 0.0000 35 Ca(HCO3)+ 0.17965E-10 -10.7456 0.15032E-10 -10.8230 0.83674E+00 -0.0774 36 CaCl+ 0.15724E-10 -10.8034 0.13157E-10 -10.8808 0.83674E+00 -0.0774 37 CaCl2,aq 0.40563E-15 -15.3919 0.40563E-15 -15.3919 0.10000E+01 0.0000 38 CaF+ 0.25887E-12 -12.5869 0.21661E-12 -12.6643 0.83674E+00 -0.0774 39 CaOH+ 0.71458E-07 -7.1459 0.59792E-07 -7.2234 0.83674E+00 -0.0774 40 CaSO4,aq 0.43983E-15 -15.3567 0.43983E-15 -15.3567 0.10000E+01 0.0000 41 HCl,aq 0.17758E-14 -14.7506 0.17758E-14 -14.7506 0.10000E+01 0.0000 45 HF,aq 0.12106E-12 -12.9170 0.12106E-12 -12.9170 0.10000E+01 0.0000 46 HF2- 0.11590E-19 -19.9359 0.96789E-20 -20.0142 0.83514E+00 -0.0782 48 FeCl+ 0.57107E-17 -17.2433 0.47783E-17 -17.3207 0.83674E+00 -0.0774 51 FeF+ 0.33644E-18 -18.4731 0.28152E-18 -18.5505 0.83674E+00 -0.0774 53 FeO,aq 0.16213E-09 -9.7901 0.16213E-09 -9.7901 0.10000E+01 0.0000 54 FeOH+ 0.12119E-10 -10.9165 0.10140E-10 -10.9939 0.83674E+00 -0.0774 55 HFeO2- 0.27200E-07 -7.5654 0.22716E-07 -7.6437 0.83514E+00 -0.0782 56 FeO+ 0.13604E-16 -16.8663 0.11383E-16 -16.9437 0.83674E+00 -0.0774 58 FeO2- 0.50013E-09 -9.3009 0.41768E-09 -9.3792 0.83514E+00 -0.0782 59 HFeO2,aq 0.39670E-11 -11.4015 0.39670E-11 -11.4015 0.10000E+01 0.0000 60 H2,aq 0.45303E-05 -5.3439 0.45146E-05 -5.3454 0.99654E+00 -0.0015 61 KCl,aq 0.30794E-09 -9.5115 0.30794E-09 -9.5115 0.10000E+01 0.0000 63 KOH,aq 0.74876E-06 -6.1257 0.74876E-06 -6.1257 0.10000E+01 0.0000 64 KSO4- 0.53784E-13 -13.2693 0.44918E-13 -13.3476 0.83514E+00 -0.0782 65 MgCO3,aq 0.37473E-12 -12.4263 0.37473E-12 -12.4263 0.10000E+01 0.0000 66 Mg(HCO3)+ 0.31775E-14 -14.4979 0.26588E-14 -14.5753 0.83674E+00 -0.0774 67 MgCl+ 0.24669E-14 -14.6079 0.20641E-14 -14.6853 0.83674E+00 -0.0774 68 MgF+ 0.16599E-15 -15.7799 0.13889E-15 -15.8573 0.83674E+00 -0.0774 69 MgOH+ 0.68445E-10 -10.1647 0.57271E-10 -10.2421 0.83674E+00 -0.0774 71 MnF+ 0.46005E-16 -16.3372 0.38495E-16 -16.4146 0.83674E+00 -0.0774 72 MnO,aq 0.17922E-08 -8.7466 0.17922E-08 -8.7466 0.10000E+01 0.0000 73 MnOH+ 0.46704E-09 -9.3306 0.39079E-09 -9.4081 0.83674E+00 -0.0774 74 MnO2-2 0.20587E-10 -10.6864 0.10665E-10 -10.9720 0.51806E+00 -0.2856 75 HMnO2- 0.20894E-09 -9.6800 0.17449E-09 -9.7582 0.83514E+00 -0.0782 78 MnCl+ 0.92168E-14 -14.0354 0.77121E-14 -14.1128 0.83674E+00 -0.0774 79 MnSO4,aq 0.61596E-19 -19.2104 0.61596E-19 -19.2104 0.10000E+01 0.0000 80 NaCl,aq 0.71320E-06 -6.1468 0.71320E-06 -6.1468 0.10000E+01 0.0000 81 NaF,aq 0.91943E-09 -9.0365 0.91943E-09 -9.0365 0.10000E+01 0.0000 82 NaOH,aq 0.95415E-04 -4.0204 0.95415E-04 -4.0204 0.10000E+01 0.0000 84 OH- 0.92810E-02 -2.0324 0.77369E-02 -2.1114 0.83363E+00 -0.0790 89 HPO3-2 0.63907E-15 -15.1945 0.33108E-15 -15.4801 0.51806E+00 -0.2856 91 H2PO3- 0.59366E-19 -19.2265 0.49579E-19 -19.3047 0.83514E+00 -0.0782 92 H3PO4,aq 0.91784E-18 -18.0372 0.91784E-18 -18.0372 0.10000E+01 0.0000 93 H2PO4- 0.38781E-10 -10.4114 0.32418E-10 -10.4892 0.83593E+00 -0.0778 94 PO4-3 0.10602E-08 -8.9746 0.25711E-09 -9.5899 0.24251E+00 -0.6153 98 HP2O7-3 0.95336E-18 -18.0207 0.22034E-18 -18.6569 0.23112E+00 -0.6362 99 P2O7-4 0.91515E-17 -17.0385 0.70487E-18 -18.1519 0.77023E-01 -1.1134 100 H2S,aq 0.75338E-08 -8.1230 0.75077E-08 -8.1245 0.99654E+00 -0.0015 101 S2-2 0.10025E-13 -13.9989 0.51935E-14 -14.2845 0.51806E+00 -0.2856 107 SO3-2 0.24678E-16 -16.6077 0.12970E-16 -16.8871 0.52556E+00 -0.2794 108 HSO3- 0.72615E-19 -19.1390 0.60644E-19 -19.2172 0.83514E+00 -0.0782 109 HSO4- 0.18996E-17 -17.7213 0.15911E-17 -17.7983 0.83756E+00 -0.0770 Charge balance for all species = -.6133E-08 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.8888078E-10 -.2225256E-01 -.2239024E+02 0.0000 2 H2O 0.1000000E+01 0.5550482E+02 0.9981971E+06 0.0000 3 Cl- 0.1553841E-03 0.1560976E-03 0.5524504E+01 6.2400 4 SO4-- 0.4258378E-10 -.1461343E-04 -.1401348E+01 9.5982 5 HCO3- 0.1123852E-04 0.4595121E-04 0.2798938E+01 5.0999 6 HS- 0.3894464E-04 0.5356564E-04 0.1768442E+01 5.6391 7 Al+++ 0.9774696E-29 0.5220740E-05 0.1406184E+00 0.7339 8 H4SiO4 0.7002159E-03 0.1353221E-01 0.1298392E+04 -3.1548 9 Ca++ 0.1215699E-06 0.2166281E-06 0.8666921E-02 13.0506 10 Mg++ 0.2114026E-10 0.9318216E-10 0.2261505E-05 9.2888 11 Fe++ 0.4529925E-13 0.2787888E-07 0.1554244E-02 6.6203 12 K+ 0.1565113E-03 0.1572603E-03 0.6138500E+01 6.2439 13 Na+ 0.1986140E-01 0.2230590E-01 0.5119164E+03 8.3465 14 Mn++ 0.1877700E-10 0.2507556E-08 0.1375206E-03 9.2382 15 F- 0.2841387E-06 0.2850585E-06 0.5406124E-02 3.5012 16 HPO4-- 0.4532123E-07 0.4642021E-07 0.4447617E-02 12.6253 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.1998455E-01 -.1998416E-01 -.3870049E-06 0.0000000E+00 2 H2O 0.4984673E+02 0.4984673E+02 -.3451293E-06 0.0000000E+00 3 Cl- 0.1401852E-03 0.1401852E-03 0.0000000E+00 0.0000000E+00 4 SO4-- -.1312281E-04 -.1312375E-04 0.9444164E-09 0.0000000E+00 5 HCO3- 0.4126700E-04 0.4126700E-04 0.0000000E+00 0.0000000E+00 6 HS- 0.4810428E-04 0.4810522E-04 -.9444164E-09 0.0000000E+00 7 Al+++ 0.4775352E-05 0.4688544E-05 0.8680807E-07 0.0000000E+00 8 H4SiO4 0.1215302E-01 0.1215275E-01 0.2695520E-06 0.0000000E+00 9 Ca++ 0.2080835E-06 0.1945453E-06 0.1353824E-07 0.0000000E+00 10 Mg++ 0.8368328E-10 0.8368328E-10 0.0000000E+00 0.0000000E+00 11 Fe++ 0.3259227E-07 0.2503694E-07 0.7555331E-08 0.0000000E+00 12 K+ 0.1412294E-03 0.1412294E-03 0.0000000E+00 0.0000000E+00 13 Na+ 0.2003215E-01 0.2003206E-01 0.8533791E-07 0.0000000E+00 14 Mn++ 0.2251939E-08 0.2251939E-08 0.0000000E+00 0.0000000E+00 15 F- 0.2560000E-06 0.2560000E-06 0.0000000E+00 0.0000000E+00 16 HPO4-- 0.4168819E-07 0.4168819E-07 0.0000000E+00 0.0000000E+00 Chg. balance for solid moles: -.2647E-22 Mass of aqueous solution: 0.899626E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 0.0003900 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 0.8534E-07 -7.069 0.2238E-04 -4.650 90.86 0.8590E-05 andradite 0.3778E-08 -8.423 0.1920E-05 -5.717 7.795 0.4988E-06 grossular 0.7351E-09 -9.134 0.3311E-06 -6.480 1.344 0.9213E-07 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8371E+00 0.8371E+00 1.0000 -0.077 grossular 0.1629E+00 0.1629E+00 1.0000 -0.788 Solid products produced: Mass = 0.000025 g Volume = 0.000009 cm3 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.0003900 moles log = -3.4089 Original solution: 1000.0103000 g Original solution / Rock added: 2564128.97 (Water/Rock Ratio), log = 6.4089 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0461 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9757E+00 0.9856 0.1006E+01 0.1021E+01 CO2,gas 0.1523E-06 1.0069 0.1605E-06 0.1594E-06 CH4,gas 0.1867E-01 1.0123 0.1977E-01 0.1953E-01 H2,gas 0.5663E-02 1.0006 0.5927E-02 0.5924E-02 H2S,gas 0.1981E-06 0.9959 0.2064E-06 0.2072E-06 S2,gas 0.4350E-28 1.0000 0.4551E-28 0.4551E-28 CO,gas 0.2423E-12 1.0000 0.2535E-12 0.2535E-12 SO3,gas 0.4456E-46 1.0000 0.4662E-46 0.4662E-46 SO2,gas 0.1028E-25 1.0000 0.1075E-25 0.1075E-25 HF,gas 0.2841E-15 1.0000 0.2972E-15 0.2972E-15 HCl,gas 0.2995E-17 1.0000 0.3133E-17 0.3133E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 17 albite -0.38 -0.38 0.00 0.000 -0.94784E-12 23 andradite 39.01 39.01 0.00 0.000 -0.12132E-10 24 grossular 32.73 32.73 0.00 0.000 0.00000E+00 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -15.15 -8.49 -2.831 0.14503E+05 -6.795 3 CH4,gas 4.54 1.14 -3.40 -0.851 0.58103E+04 -1.704 4 H2,gas 8.00 4.07 -3.93 -2.244 0.67038E+04 -2.227 5 H2S,gas -6.23 -14.61 -8.38 -4.192 0.14316E+05 -6.685 6 S2,gas -7.34 -37.38 -30.04 -4.622 0.51294E+05 -28.342 7 CO,gas 3.21 -11.08 -14.30 -4.398 0.24408E+05 -12.596 8 SO3,gas 17.12 -30.91 -48.03 -12.008 0.82011E+05 -46.331 9 SO2,gas 0.83 -26.84 -27.67 -7.378 0.47242E+05 -25.969 10 HF,gas 0.47 -16.75 -17.23 -8.613 0.29413E+05 -15.527 11 HCl,gas 5.19 -14.01 -19.20 -9.601 0.32789E+05 -17.504 12 acmite 7.71 6.62 -1.09 -0.113 0.18599E+04 16 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 20 spessartine 24.46 19.72 -4.74 -0.237 0.80920E+04 21 analcite 3.32 2.77 -0.55 -0.061 0.94075E+03 27 annite 20.12 17.37 -2.75 -0.153 0.46939E+04 28 phlogopite 27.06 25.38 -1.68 -0.094 0.28764E+04 30 anorthite 12.71 8.21 -4.50 -0.346 0.76861E+04 33 apatite-OH -18.15 -18.39 -0.24 -0.018 0.40915E+03 34 apatite-F -34.30 -35.15 -0.84 -0.070 0.14420E+04 38 aragonite 0.97 -2.10 -3.07 -1.023 0.52414E+04 39 brucite 12.57 9.29 -3.28 -0.656 0.56000E+04 40 calcite 0.81 -2.10 -2.91 -0.972 0.49772E+04 41 carnegieite-low 9.02 5.93 -3.10 -0.443 0.52891E+04 42 carnegieite-high 10.09 5.93 -4.17 -0.595 0.71161E+04 43 carpholite-Mg 8.58 4.45 -4.13 -0.276 0.70603E+04 44 carpholite-Fe 6.71 1.78 -4.93 -0.329 0.84247E+04 45 celadonite 5.34 3.65 -1.69 -0.100 0.28925E+04 46 celadonite-Fe 3.88 0.98 -2.90 -0.170 0.49474E+04 47 chrysotile 23.89 21.56 -2.34 -0.195 0.39876E+04 49 clinochlore 39.07 38.45 -0.62 -0.019 0.10616E+04 50 daphnite 28.97 25.11 -3.86 -0.121 0.65912E+04 52 chlorite-Al-free 47.17 43.11 -4.06 -0.169 0.69304E+04 54 chloritoid-Fe 9.17 4.93 -4.24 -0.283 0.72401E+04 55 chloritoid-Mn 11.40 7.55 -3.85 -0.257 0.65734E+04 57 coesite -2.38 -3.15 -0.78 -0.260 0.13296E+04 64 cristobalite -2.56 -3.15 -0.59 -0.198 0.10150E+04 66 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71234E+04 68 diaspore 2.87 0.73 -2.14 -0.357 0.36536E+04 69 diamond -3.10 -7.01 -3.90 -1.115 0.66661E+04 70 diopside 16.18 16.03 -0.15 -0.015 0.25868E+03 71 hedenbergite 14.21 13.36 -0.85 -0.085 0.14462E+04 74 enstatite 17.26 12.27 -5.00 -0.500 0.85318E+04 76 clinoenstatite 17.17 12.27 -4.90 -0.490 0.83634E+04 78 epidote 24.67 22.69 -1.98 -0.096 0.33838E+04 79 clinozoisite 22.81 18.84 -3.97 -0.180 0.67743E+04 80 epidote-Fe 29.84 26.54 -3.30 -0.172 0.56400E+04 81 fayalite 14.05 10.09 -3.96 -0.566 0.67614E+04 82 ferrosilite 11.15 6.93 -4.22 -0.422 0.72028E+04 86 gibbsite 4.08 0.73 -3.35 -0.478 0.57121E+04 87 glaucophane 22.97 20.79 -2.19 -0.059 0.37318E+04 88 glaucophane-Fe 17.28 12.78 -4.49 -0.121 0.76703E+04 89 graphite -3.55 -7.01 -3.46 -0.989 0.59083E+04 90 greenalite 16.14 13.55 -2.59 -0.216 0.44192E+04 93 hematite 12.57 9.17 -3.40 -0.412 0.58041E+04 94 heulandite -5.83 -7.56 -1.74 -0.079 0.29671E+04 98 jadeite 4.22 2.77 -1.44 -0.144 0.24662E+04 100 kalsilite 7.58 3.82 -3.76 -0.537 0.64216E+04 101 kaolinite -1.33 -4.84 -3.51 -0.319 0.59913E+04 104 laumontite 2.88 1.90 -0.98 -0.066 0.16803E+04 105 lawsonite 9.62 8.21 -1.41 -0.094 0.24027E+04 106 leucite 4.12 0.67 -3.45 -0.345 0.58918E+04 108 lizardite 23.24 21.56 -1.69 -0.141 0.28803E+04 110 magnetite 20.09 15.79 -4.30 -0.351 0.73424E+04 111 minnesotaite 10.39 7.24 -3.15 -0.185 0.53722E+04 115 manganosite 14.06 9.24 -4.82 -1.205 0.82299E+04 119 microcline -2.49 -2.49 0.00 0.000 0.32828E-01 123 muscovite 2.58 -1.02 -3.60 -0.212 0.61487E+04 124 paragonite 4.24 1.08 -3.16 -0.186 0.53878E+04 125 nepheline 8.34 5.93 -2.41 -0.345 0.41215E+04 137 phlogopite-Na 29.65 27.48 -2.16 -0.120 0.36952E+04 139 prehnite 19.37 18.10 -1.27 -0.075 0.21637E+04 140 prehnite-Fe 22.50 21.95 -0.54 -0.033 0.92826E+03 141 pumpellyite-Fe 46.27 43.56 -2.71 -0.060 0.46202E+04 142 pumpellyite-Mg 48.99 46.23 -2.76 -0.061 0.47173E+04 146 pyrrhotite -4.26 -7.99 -3.73 -1.245 0.63756E+04 147 pyrrhotiteFe0.875 -6.02 -9.33 -3.31 -1.217 0.56517E+04 148 pyroxmangite 7.40 6.08 -1.32 -0.263 0.22458E+04 149 pyrophyllite -6.18 -11.15 -4.98 -0.311 0.84954E+04 150 quartz -2.99 -3.15 -0.17 -0.055 0.28230E+03 154 rhodochrosite -0.98 -5.92 -4.94 -1.646 0.84335E+04 155 rhodonite 7.45 6.08 -1.36 -0.272 0.23260E+04 156 sanidine -1.28 -2.49 -1.21 -0.093 0.20678E+04 166 stilbite -7.52 -7.56 -0.04 -0.002 0.73256E+02 167 stilpnomelane-Fe 13.02 12.45 -0.56 -0.017 0.96271E+03 168 stilpnomelane-Mg 27.44 25.80 -1.65 -0.049 0.28097E+04 174 talc 16.49 15.25 -1.24 -0.073 0.21234E+04 177 tephroite 18.09 15.32 -2.76 -0.395 0.47197E+04 181 tridymite -2.63 -3.15 -0.53 -0.176 0.90228E+03 182 tremolite 47.87 47.31 -0.56 -0.015 0.95974E+03 183 ferroactinolite 38.45 33.96 -4.49 -0.121 0.76630E+04 184 troilite-low -4.41 -7.99 -3.58 -1.194 0.61184E+04 190 wairakite 3.95 1.90 -2.05 -0.121 0.35022E+04 191 walstromite 11.51 9.90 -1.61 -0.323 0.27549E+04 192 wollastonite 10.46 9.90 -0.57 -0.113 0.96534E+03 193 pseudo-wollastonite 11.00 9.90 -1.10 -0.221 0.18852E+04 194 zoisite 22.85 18.84 -4.01 -0.182 0.68483E+04 195 akaganeite 7.75 4.58 -3.17 -0.686 0.54146E+04 202 chalcedony -2.80 -3.15 -0.35 -0.117 0.60160E+03 204 montmorillonite-Ca -2.29 -6.17 -3.88 -0.240 0.66319E+04 205 montmorillonite-K -2.24 -6.27 -4.03 -0.247 0.68826E+04 206 montmorillonite-Mg -2.48 -6.80 -4.32 -0.267 0.73687E+04 207 montmorillonite-Na -2.04 -5.57 -3.54 -0.217 0.60375E+04 208 nontronite-Ca 3.21 -0.02 -3.23 -0.210 0.55152E+04 209 nontronite-H 2.53 -2.17 -4.70 -0.315 0.80277E+04 210 nontronite-K 3.34 -0.11 -3.45 -0.221 0.58892E+04 211 nontronite-Mg 3.07 -0.64 -3.71 -0.241 0.63361E+04 212 nontronite-Na 3.52 0.59 -2.93 -0.188 0.50100E+04 228 tobermorite 9.82 7.72 -2.11 -0.575 0.35971E+04 234 alabandite -0.98 -5.38 -4.40 -1.466 0.75103E+04 237 boehmite 4.41 0.73 -3.67 -0.612 0.62705E+04 239 ferrous-oxide 9.81 6.62 -3.19 -0.798 0.54490E+04 245 silica-amorphous -2.09 -3.15 -1.06 -0.354 0.18158E+04 247 an20ab80 2.02 1.33 -0.68 -0.053 0.11664E+04 248 an25ab75 2.65 1.76 -0.88 -0.068 0.15049E+04 249 an30ab70 3.28 2.19 -1.09 -0.083 0.18531E+04 250 tr.625ac.25prg.125 45.16 44.92 -0.25 -0.007 0.42196E+03 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 0.0000100 MOLES Current total amount of reactant added: 0.0003900 MOLES New total amount of reactant added: 0.0004000 MOLES Mixing fraction reached given limit of 0.4000E-03 TOTMIX = 0.4000E-03 Execution stopped.