File SKIP_SPECIES.TXT lists species and minerals omitted from the calculations due to given T, P, option switches, or suppression in CHIMRUN, or are suppressed in the SOLTHERM database. It also lists minerals for which density is not specified in SOLTHERM. This is an extended P(to 5 kB), T(to 600 C) run (CON_FLAG = 1). methanol,aq is suppressed in SOLTHERM data file. methanol,aq is suppressed in SOLTHERM data file. CuCl4-3 is suppressed in SOLTHERM data file. H2BO3- is suppressed in SOLTHERM data file. UO2CO3,aq is suppressed in SOLTHERM data file. UO2SO4,aq is suppressed in SOLTHERM data file. UO2Cl2,aq is suppressed in SOLTHERM data file. UO2F2,aq is suppressed in SOLTHERM data file. PO4-3 is suppressed in SOLTHERM data file. H2PO4- is suppressed in SOLTHERM data file. H3PO4 is suppressed in SOLTHERM data file. O2,gas is suppressed in THIS RUN. O2,gas is suppressed in THIS RUN. amesite is suppressed in SOLTHERM data file. antigorite is suppressed in SOLTHERM data file. goethite is suppressed in THIS RUN. goethite is suppressed in THIS RUN. riebeckite is suppressed in THIS RUN. riebeckite is suppressed in THIS RUN. sapphirine-Fe(221) is suppressed in SOLTHERM data file. sapphirine(221) is suppressed in SOLTHERM data file. talc-prl is suppressed in SOLTHERM data file. PrO1.833(s) is suppressed in SOLTHERM data file. niter-NH4 is suppressed in SOLTHERM data file. FMQ_HS-1 is suppressed in THIS RUN. kf-ab-equil is suppressed in THIS RUN. ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Species No. Charge Tot.moles Trial molality Gamma Mixing solution H+ 1 1. -0.19985E-01 0.88881E-10 0.8402 0.00000000E+00 H2O 2 0. 0.49847E+02 0.10000E+01 1.0000 0.00000000E+00 Cl- 3 -1. 0.14019E-03 0.15538E-03 0.8351 0.00000000E+00 SO4-- 4 -2. -0.13123E-04 0.42584E-10 0.5192 0.00000000E+00 HCO3- 5 -1. 0.41267E-04 0.11239E-04 0.8364 0.00000000E+00 HS- 6 -1. 0.48104E-04 0.38945E-04 0.8353 0.00000000E+00 Al+++ 7 3. 0.47754E-05 0.97747E-29 0.2309 0.00000000E+00 H4SiO4 8 0. 0.12153E-01 0.70022E-03 1.0000 0.00000000E+00 Ca++ 9 2. 0.20808E-06 0.12157E-06 0.5153 0.00000000E+00 Mg++ 10 2. 0.83683E-10 0.21140E-10 0.5130 0.00000000E+00 Fe++ 11 2. 0.32592E-07 0.45299E-13 0.5136 0.00000000E+00 K+ 12 1. 0.14123E-03 0.15651E-03 0.8366 0.00000000E+00 Na+ 13 1. 0.20032E-01 0.19861E-01 0.8350 0.00000000E+00 Mn++ 14 2. 0.22519E-08 0.18777E-10 0.5140 0.00000000E+00 F- 15 -1. 0.25600E-06 0.28414E-06 0.8334 0.00000000E+00 HPO4-- 16 -2. 0.41688E-07 0.45321E-07 0.5192 0.00000000E+00 Chg. balance for total moles = -.5508E-08 Max. difference allowed = 0.1402E-07 The following parameters were given: ERPC = 0.1000E-11 pH = 0.0000 PFLUID = 50.0000 SLIM = 0.800000E-03 TEMP = 100.0000 SINC = 0.2000E-04 TEMPC = 0.0000 TOTMIX = 0.390000E-03 ENTH = 0.0000 SENTH = 0.0000 DENTH = 0.0000 TOTWAT = 90.0000 SOLMIN = 0.0000E+00 RM = 0.0000 AQGRM = 1000.0103 SUPRNT = 0.1000E-19 VBOX-1 = 400.9996 RHOFRS = 0.0000 RHOROC = 2.5000 The following options were selected: CONFLG = 1 C = 3 IFRAC = 0 IPUNCH = 2 NLOOP = 400 ISTEP = 2 LIMSOL = 1 LOOC = 0 IENTH = 0 ITREF = 0 IDEAL = 0 IPSAT = 1 INCREM = 0 INCP = 0 MINSOL = 3 NEUT = 0 AWAT = 0 CHGF = 0 Of the derived species, only those with molality > 0.10E-19 will appear in the output Species No. Charge Log K(diss) Species No. Charge Log K(diss) SiF6-2 17 -2. -24.5019 Mn+3 70 3. 19.1453 HSiO3- 18 -1. 9.0298 MnF+ 71 1. -1.2264 Ca(HSiO3)+ 19 1. 7.6723 MnO,aq 72 0. 17.9848 Mg(HSiO3)+ 20 1. 7.5773 MnOH+ 73 1. 8.5194 NaHSiO3,aq 21 0. 7.8210 MnO2-2 74 -2. 40.4638 AlO+ 22 1. 6.8663 HMnO2- 75 -1. 29.1232 AlOH+2 23 2. 3.1691 MnO4- 76 -1. 83.3111 HAlO2,aq 24 0. 10.5671 MnO4-2 77 -2. 81.3005 AlO2- 25 -1. 16.2221 MnCl+ 78 1. -0.7894 CH4,aq 26 0. 6.0126 MnSO4,aq 79 0. -2.4604 C2H6,aq 27 0. 12.3733 NaCl,aq 80 0. 0.4796 C3H8,aq 28 0. 17.3707 NaF,aq 81 0. 0.6306 C4H10,aq 29 0. 22.3757 NaOH,aq 82 0. 12.3669 ethanol,aq 30 0. 15.3258 O2,aq 83 0. 53.5502 CO,aq 31 0. 4.6892 OH- 84 -1. 12.2382 CO2,aq 32 0. -6.3298 HO2- 85 -1. 50.8010 CO3-2 33 -2. 10.0588 H2O2,aq 86 0. 40.0166 CaCO3,aq 34 0. 5.9605 H3PO2,aq 87 0. 24.3066 Ca(HCO3)+ 35 1. -1.4070 H2PO2- 88 -1. 26.5366 CaCl+ 36 1. -0.2091 HPO3-2 89 -2. 11.9254 CaCl2,aq 37 0. 0.4151 H3PO3,aq 90 0. 3.5792 CaF+ 38 1. -1.1644 H2PO3- 91 -1. 5.6232 CaOH+ 39 1. 10.1471 H3PO4,aq 92 0. -9.8447 CaSO4,aq 40 0. -2.5018 H2PO4- 93 -1. -7.2659 HCl,aq 41 0. 0.7370 PO4-3 94 -3. 12.0884 HClO,aq 42 0. 32.4260 H4P2O7,aq 95 0. -17.8095 ClO- 43 -1. 39.6530 H3P2O7- 96 -1. -15.9156 HClO2,aq 44 0. 70.1812 H2P2O7-2 97 -2. -13.4262 HF,aq 45 0. -3.8354 HP2O7-3 98 -3. -6.7266 HF2- 46 -1. -3.3639 P2O7-4 99 -4. 2.8952 Fe+3 47 3. 8.3809 H2S,aq 100 0. -6.4900 FeCl+ 48 1. -0.1994 S2-2 101 -2. 1.2355 FeCl2,aq 49 0. 4.3001 S3-2 102 -2. -8.8031 FeCl+2 50 2. 6.5269 S3- 103 -1. -16.3389 FeF+ 51 1. -1.7084 S4-2 104 -2. -18.6615 FeF+2 52 2. 1.4309 S5-2 105 -2. -28.3439 FeO,aq 53 0. 16.4104 SO2,aq 106 0. -0.2309 FeOH+ 54 1. 7.4874 SO3-2 107 -2. 10.3052 HFeO2- 55 -1. 24.3908 HSO3- 108 -1. 2.5086 FeO+ 56 1. 11.4004 HSO4- 109 -1. -2.9839 FeOH+2 57 2. 9.1194 HSO5- 110 -1. 38.8366 FeO2- 58 -1. 24.0895 S2O3-2 111 -2. -4.5600 HFeO2,aq 59 0. 15.9850 HS2O3- 112 -1. -6.8123 H2,aq 60 0. 9.4190 H2S2O3,aq 113 0. -8.0173 KCl,aq 61 0. 1.7417 S2O4-2 114 -2. 10.5541 KHSO4,aq 62 0. -0.4514 HS2O4- 115 -1. 7.6551 KOH,aq 63 0. 12.3695 H2S2O4,aq 116 0. 6.6259 KSO4- 64 -1. -1.1908 S2O5-2 117 -2. 10.0741 MgCO3,aq 65 0. 6.5614 S2O6-2 118 -2. 11.5521 Mg(HCO3)+ 66 1. -1.4164 S2O8-2 119 -2. 42.0620 MgCl+ 67 1. -0.1664 S3O6-2 120 -2. 3.7866 MgF+ 68 1. -1.7331 S4O6-2 121 -2. -17.8657 MgOH+ 69 1. 9.4041 S5O6-2 122 -2. -14.1333 For mixed gases (JSOLS=6), log K(hydrol) = log (K*P) Log K Trial Log K Trial Mineral No. hydrol Moles Mineral No. hydrol Moles H2O,gas 1 1.696 0.0000E+00 osumilite(1) 126 21.717 0.0000E+00 CO2,gas 2 -6.660 0.0000E+00 osumilite(2) 127 20.667 0.0000E+00 CH4,gas 3 4.544 0.0000E+00 osumilite-Fe 128 14.390 0.0000E+00 H2,gas 4 8.000 0.0000E+00 pargasite 129 65.092 0.0000E+00 H2S,gas 5 -6.230 0.0000E+00 periclase 130 16.138 0.0000E+00 S2,gas 6 -7.335 0.0000E+00 periclase-Fe 131 11.627 0.0000E+00 CO,gas 7 3.215 0.0000E+00 perovskite-Al 132 12.344 0.0000E+00 SO3,gas 8 17.121 0.0000E+00 perovskite-Ca 133 23.807 0.0000E+00 SO2,gas 9 0.832 0.0000E+00 perovskite-Fe 134 21.143 0.0000E+00 HF,gas 10 0.473 0.0000E+00 perovskite-Mg 135 23.119 0.0000E+00 HCl,gas 11 5.189 0.0000E+00 phase_A 136 80.189 0.0000E+00 acmite 12 7.710 0.0000E+00 phlogopite-Na 137 29.647 0.0000E+00 akermanite 13 36.442 0.0000E+00 piemontite(ordered) 138 33.776 0.0000E+00 akimotoite 14 16.591 0.0000E+00 prehnite 139 19.372 0.0000E+00 akimotoite-Fe 15 13.067 0.0000E+00 prehnite-Fe 140 22.498 0.0000E+00 albite-high 16 0.693 0.0000E+00 pumpellyite-Fe 141 46.269 0.0000E+00 albite 17 -0.384 0.8534E-07 pumpellyite-Mg 142 48.995 0.0000E+00 almandine 18 24.442 0.0000E+00 px-Mg-tschermaks 143 19.616 0.0000E+00 pyrope 19 37.248 0.0000E+00 px-Ca-tschermaks 144 18.610 0.0000E+00 spessartine 20 24.457 0.0000E+00 pyrite 145 -21.247 0.0000E+00 analcite 21 3.322 0.0000E+00 pyrrhotite 146 -4.260 0.0000E+00 andalusite 22 5.002 0.0000E+00 pyrrhotiteFe0.875 147 -6.017 0.0000E+00 andradite 23 39.009 0.3778E-08 pyroxmangite 148 7.399 0.0000E+00 grossular 24 32.731 0.7351E-09 pyrophyllite 149 -6.176 0.0000E+00 anhydrite 25 -5.317 0.0000E+00 quartz 150 -2.989 0.0000E+00 ankerite 26 -2.135 0.0000E+00 rankinite 151 40.713 0.0000E+00 annite 27 20.123 0.0000E+00 ringwoodite-Fe 152 15.456 0.0000E+00 phlogopite 28 27.065 0.0000E+00 ringwoodite-Mg 153 27.575 0.0000E+00 biotite-Mn 29 32.960 0.0000E+00 rhodochrosite 154 -0.976 0.0000E+00 anorthite 30 12.710 0.0000E+00 rhodonite 155 7.446 0.0000E+00 anthophyllite 31 51.852 0.0000E+00 sanidine 156 -1.275 0.0000E+00 anthophyllite-Fe 32 29.306 0.0000E+00 sapphirine(351) 157 78.899 0.0000E+00 apatite-OH 33 -18.153 0.0000E+00 siderite 158 -2.608 0.0000E+00 apatite-F 34 -34.301 0.0000E+00 sillimanite 159 5.262 0.0000E+00 apatite-OH-zs 35 -12.736 0.0000E+00 sodalite 160 49.976 0.0000E+00 apatite-F-zs 36 -27.774 0.0000E+00 spinel 161 20.870 0.0000E+00 apatite-Cl-zs 37 -16.674 0.0000E+00 spurrite 162 59.482 0.0000E+00 aragonite 38 0.967 0.0000E+00 staurolite-Fe 163 73.598 0.0000E+00 brucite 39 12.569 0.0000E+00 staurolite-Mg 164 89.802 0.0000E+00 calcite 40 0.812 0.0000E+00 staurolite-Mn 165 83.909 0.0000E+00 carnegieite-low 41 9.023 0.0000E+00 stilbite 166 -7.522 0.0000E+00 carnegieite-high 42 10.093 0.0000E+00 stilpnomelane-Fe 167 13.017 0.0000E+00 carpholite-Mg 43 8.582 0.0000E+00 stilpnomelane-Mg 168 27.441 0.0000E+00 carpholite-Fe 44 6.713 0.0000E+00 stishovite 169 2.720 0.0000E+00 celadonite 45 5.342 0.0000E+00 sudoite-Fe 170 18.296 0.0000E+00 celadonite-Fe 46 3.877 0.0000E+00 sudoite 171 21.077 0.0000E+00 chrysotile 47 23.892 0.0000E+00 sulfur 172 -9.152 0.0000E+00 chondrodite 48 56.475 0.0000E+00 sylvite 173 1.338 0.0000E+00 clinochlore 49 39.070 0.0000E+00 talc 174 16.491 0.0000E+00 daphnite 50 28.965 0.0000E+00 talc-Fe 175 13.448 0.0000E+00 chlorite-Mn 51 46.869 0.0000E+00 talc-tschermaks 176 19.091 0.0000E+00 chlorite-Al-free 52 47.173 0.0000E+00 tephroite 177 18.086 0.0000E+00 chloritoid-Mg 53 13.198 0.0000E+00 tilleyite 178 41.377 0.0000E+00 chloritoid-Fe 54 9.174 0.0000E+00 titanite-CaSi 179 15.479 0.0000E+00 chloritoid-Mn 55 11.401 0.0000E+00 topaz-H 180 4.618 0.0000E+00 clinohumite 56 97.128 0.0000E+00 tridymite 181 -2.626 0.0000E+00 coesite 57 -2.376 0.0000E+00 tremolite 182 47.869 0.0000E+00 cordierite-H 58 23.715 0.0000E+00 ferroactinolite 183 38.452 0.0000E+00 cordierite 59 24.049 0.0000E+00 troilite-low 184 -4.411 0.0000E+00 cordierite-Fe 60 20.450 0.0000E+00 tschermakite 185 48.210 0.0000E+00 cordierite-Mn 61 25.066 0.0000E+00 vesuvianite 186 223.471 0.0000E+00 corundum 62 8.383 0.0000E+00 wadeite-Si 187 20.216 0.0000E+00 corundum-MgSi 63 18.891 0.0000E+00 wadsleyite-Fe 188 15.680 0.0000E+00 cristobalite 64 -2.560 0.0000E+00 wadsleyite-Mg 189 25.850 0.0000E+00 cummingtonite 65 52.099 0.0000E+00 wairakite 190 3.950 0.0000E+00 cymrite-K 66 1.685 0.0000E+00 walstromite 191 11.509 0.0000E+00 deerite 67 95.671 0.0000E+00 wollastonite 192 10.461 0.0000E+00 diaspore 68 2.874 0.0000E+00 pseudo-wollastonite 193 11.000 0.0000E+00 diamond 69 -3.102 0.0000E+00 zoisite 194 22.849 0.0000E+00 diopside 70 16.181 0.0000E+00 akaganeite 195 7.755 0.0000E+00 hedenbergite 71 14.208 0.0000E+00 beidellite-Ca 196 -1.646 0.0000E+00 dolomite,ordered 72 0.546 0.0000E+00 beidellite-H 197 -2.326 0.0000E+00 eastonite 73 28.489 0.0000E+00 beidellite-K 198 -1.520 0.0000E+00 enstatite 74 17.265 0.0000E+00 beidellite-Mg 199 -1.790 0.0000E+00 clinoenstatite-HiP 75 18.354 0.0000E+00 beidellite-Na 200 -1.342 0.0000E+00 clinoenstatite 76 17.166 0.0000E+00 calcium 201 84.026 0.0000E+00 protoenstatite 77 17.824 0.0000E+00 chalcedony 202 -2.802 0.0000E+00 epidote 78 24.670 0.0000E+00 dawsonite 203 1.682 0.0000E+00 clinozoisite 79 22.806 0.0000E+00 montmorillonite-Ca 204 -2.291 0.0000E+00 epidote-Fe 80 29.841 0.0000E+00 montmorillonite-K 205 -2.237 0.0000E+00 fayalite 81 14.046 0.0000E+00 montmorillonite-Mg 206 -2.480 0.0000E+00 ferrosilite 82 11.149 0.0000E+00 montmorillonite-Na 207 -2.038 0.0000E+00 forsterite 83 21.016 0.0000E+00 nontronite-Ca 208 3.215 0.0000E+00 gedrite 84 50.522 0.0000E+00 nontronite-H 209 2.533 0.0000E+00 gehlenite 85 36.628 0.0000E+00 nontronite-K 210 3.341 0.0000E+00 gibbsite 86 4.079 0.0000E+00 nontronite-Mg 211 3.075 0.0000E+00 glaucophane 87 22.975 0.0000E+00 nontronite-Na 212 3.520 0.0000E+00 glaucophane-Fe 88 17.276 0.0000E+00 sepiolite 213 24.118 0.0000E+00 graphite 89 -3.546 0.0000E+00 topaz 214 -16.546 0.0000E+00 greenalite 90 16.140 0.0000E+00 alite 215 57.999 0.0000E+00 grunerite 91 31.215 0.0000E+00 belite 216 30.433 0.0000E+00 halite 92 1.575 0.0000E+00 ettringite 217 43.232 0.0000E+00 hematite 93 12.566 0.0000E+00 gypsum 218 -4.955 0.0000E+00 heulandite 94 -5.827 0.0000E+00 hemicarboaluminate 219 70.954 0.0000E+00 hercynite 95 17.279 0.0000E+00 hydrogarnet 220 60.662 0.0000E+00 hollandite 96 25.673 0.0000E+00 hydrogarnet-Si 221 50.586 0.0000E+00 iron 97 19.086 0.0000E+00 jennite 222 24.367 0.0000E+00 jadeite 98 4.215 0.0000E+00 monosulfoaluminate 223 53.400 0.0000E+00 julgoldite 99 70.427 0.0000E+00 monocarboaluminate 224 61.898 0.0000E+00 kalsilite 100 7.584 0.0000E+00 portlandite 225 18.272 0.0000E+00 kaolinite 101 -1.333 0.0000E+00 stratlingite 226 36.502 0.0000E+00 kyanite 102 4.876 0.0000E+00 tricarboaluminate 227 70.370 0.0000E+00 larnite-bredigite 103 30.686 0.0000E+00 tobermorite 228 9.823 0.0000E+00 laumontite 104 2.883 0.0000E+00 C4AH13 229 81.816 0.0000E+00 lawsonite 105 9.616 0.0000E+00 C2AH8 230 45.203 0.0000E+00 leucite 106 4.119 0.0000E+00 C3A 231 86.953 0.0000E+00 lime 107 25.998 0.0000E+00 C4AF 232 117.416 0.0000E+00 lizardite 108 23.244 0.0000E+00 CAH10 233 28.335 0.0000E+00 magnesite 109 0.691 0.0000E+00 alabandite 234 -0.978 0.0000E+00 magnetite 110 20.087 0.0000E+00 alunite 235 -10.435 0.0000E+00 minnesotaite 111 10.388 0.0000E+00 artinite 236 15.121 0.0000E+00 minnesotaite-Mg 112 20.602 0.0000E+00 boehmite 237 4.406 0.0000E+00 magnesioferrite 113 26.212 0.0000E+00 dolomite,disordered 238 1.247 0.0000E+00 majorite 114 53.251 0.0000E+00 ferrous-oxide 239 9.812 0.0000E+00 manganosite 115 14.058 0.0000E+00 fluorite 240 -9.931 0.0000E+00 margarite 116 17.324 0.0000E+00 huntite 241 3.770 0.0000E+00 meionite 117 44.874 0.0000E+00 hydromagnesite 242 19.995 0.0000E+00 merwinite 118 55.930 0.0000E+00 nesquehonite 243 4.723 0.0000E+00 microcline 119 -2.486 0.0000E+00 potassium-oxide 244 69.038 0.0000E+00 monticellite 120 24.339 0.0000E+00 silica-amorphous 245 -2.091 0.0000E+00 mullite-Al 121 363.148 0.0000E+00 sodium-oxide 246 55.169 0.0000E+00 mullite-Si 122 7.264 0.0000E+00 an20ab80 247 2.018 0.0000E+00 muscovite 123 2.582 0.0000E+00 an25ab75 248 2.646 0.0000E+00 paragonite 124 4.239 0.0000E+00 an30ab70 249 3.279 0.0000E+00 nepheline 125 8.339 0.0000E+00 tr.625ac.25prg.125 250 45.165 0.0000E+00 Initial composition of reactant (mole%): H2O 88.87 HCl 0.5900 CO2 7.070 CO 0.1600 H2 1.540 S2 0.8000E-01 SO2 1.150 HF 0.4000E-01 H2S 1.120 0.000 Sum of wt% of reactants: 100.6200 Reactant consumed: 0.0003900 moles log = -3.4089 Original solution: 1000.0103000 g Original solution / Rock added: 2564128.97 (Water/Rock Ratio), log = 6.4089 The following minerals and/or gases with identical index are in solid solution: H2O,gas 6 CO2,gas 6 CH4,gas 6 H2,gas 6 H2S,gas 6 S2,gas 6 CO,gas 6 SO3,gas 6 SO2,gas 6 HF,gas 6 HCl,gas 6 almandine 16 pyrope 16 spessartine 16 andradite 8 grossular 8 annite 15 phlogopite 15 biotite-Mn 15 clinochlore 1 daphnite 1 chlorite-Mn 1 diopside 5 hedenbergite 5 epidote 3 clinozoisite 3 iron 9 magnetite 14 talc 7 talc-Fe 7 tremolite 2 ferroactinolite 2 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 10 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 0.0003900 Water: Moles liquid = 0.4985E+02 kg liquid = 0.8981E+00 Moles total = 0.4985E+02 kg total = 0.8980E+00 Activity = 1.0000 Stoichiometric ionic strength = .1135509E-01 Osmotic coef. = 0.9681 True ionic strength = .2003963E-01 Chg. balance for total moles = -.5508E-08 Max. difference allowed = 0.1402E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.88881E-10 -10.0512 0.74677E-10 -10.1268 0.84020E+00 -0.0756 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.15538E-03 -3.8086 0.12977E-03 -3.8868 0.83514E+00 -0.0782 4 SO4-- 0.42584E-10 -10.3708 0.22108E-10 -10.6555 0.51916E+00 -0.2847 5 HCO3- 0.11239E-04 -4.9493 0.93995E-05 -5.0269 0.83636E+00 -0.0776 6 HS- 0.38945E-04 -4.4096 0.32529E-04 -4.4877 0.83526E+00 -0.0782 7 Al+++ 0.97747E-29 -29.0099 0.22568E-29 -29.6465 0.23089E+00 -0.6366 8 H4SiO4 0.70022E-03 -3.1548 0.70022E-03 -3.1548 0.10000E+01 0.0000 9 Ca++ 0.12157E-06 -6.9152 0.62651E-07 -7.2031 0.51535E+00 -0.2879 10 Mg++ 0.21140E-10 -10.6749 0.10845E-10 -10.9648 0.51299E+00 -0.2899 11 Fe++ 0.45299E-13 -13.3439 0.23264E-13 -13.6333 0.51355E+00 -0.2894 12 K+ 0.15651E-03 -3.8055 0.13093E-03 -3.8830 0.83656E+00 -0.0775 13 Na+ 0.19861E-01 -1.7020 0.16584E-01 -1.7803 0.83499E+00 -0.0783 14 Mn++ 0.18777E-10 -10.7264 0.96510E-11 -11.0154 0.51398E+00 -0.2891 15 F- 0.28414E-06 -6.5465 0.23681E-06 -6.6256 0.83342E+00 -0.0791 16 HPO4-- 0.45321E-07 -7.3437 0.23532E-07 -7.6283 0.51924E+00 -0.2846 18 HSiO3- 0.10484E-01 -1.9795 0.87553E-02 -2.0577 0.83514E+00 -0.0782 19 Ca(HSiO3)+ 0.14929E-07 -7.8260 0.12492E-07 -7.9034 0.83674E+00 -0.0774 20 Mg(HSiO3)+ 0.32161E-11 -11.4927 0.26911E-11 -11.5701 0.83674E+00 -0.0774 21 NaHSiO3,aq 0.23484E-02 -2.6292 0.23484E-02 -2.6292 0.10000E+01 0.0000 22 AlO+ 0.65797E-16 -16.1818 0.55055E-16 -16.2592 0.83674E+00 -0.0774 24 HAlO2,aq 0.14682E-09 -9.8332 0.14682E-09 -9.8332 0.10000E+01 0.0000 25 AlO2- 0.52206E-05 -5.2823 0.43520E-05 -5.3613 0.83363E+00 -0.0790 26 CH4,aq 0.13481E-04 -4.8703 0.13434E-04 -4.8718 0.99654E+00 -0.0015 27 C2H6,aq 0.68581E-14 -14.1638 0.68343E-14 -14.1653 0.99654E+00 -0.0015 31 CO,aq 0.17010E-15 -15.7693 0.17010E-15 -15.7693 0.10000E+01 0.0000 32 CO2,aq 0.15051E-08 -8.8224 0.14999E-08 -8.8240 0.99654E+00 -0.0015 33 CO3-2 0.21222E-04 -4.6732 0.10994E-04 -4.9588 0.51806E+00 -0.2856 34 CaCO3,aq 0.86367E-08 -8.0637 0.86367E-08 -8.0637 0.10000E+01 0.0000 35 Ca(HCO3)+ 0.17965E-10 -10.7456 0.15032E-10 -10.8230 0.83674E+00 -0.0774 36 CaCl+ 0.15724E-10 -10.8034 0.13157E-10 -10.8808 0.83674E+00 -0.0774 37 CaCl2,aq 0.40563E-15 -15.3919 0.40563E-15 -15.3919 0.10000E+01 0.0000 38 CaF+ 0.25887E-12 -12.5869 0.21661E-12 -12.6643 0.83674E+00 -0.0774 39 CaOH+ 0.71458E-07 -7.1459 0.59792E-07 -7.2234 0.83674E+00 -0.0774 40 CaSO4,aq 0.43983E-15 -15.3567 0.43983E-15 -15.3567 0.10000E+01 0.0000 41 HCl,aq 0.17758E-14 -14.7506 0.17758E-14 -14.7506 0.10000E+01 0.0000 45 HF,aq 0.12106E-12 -12.9170 0.12106E-12 -12.9170 0.10000E+01 0.0000 46 HF2- 0.11590E-19 -19.9359 0.96789E-20 -20.0142 0.83514E+00 -0.0782 48 FeCl+ 0.57107E-17 -17.2433 0.47783E-17 -17.3207 0.83674E+00 -0.0774 51 FeF+ 0.33644E-18 -18.4731 0.28152E-18 -18.5505 0.83674E+00 -0.0774 53 FeO,aq 0.16213E-09 -9.7901 0.16213E-09 -9.7901 0.10000E+01 0.0000 54 FeOH+ 0.12119E-10 -10.9165 0.10140E-10 -10.9939 0.83674E+00 -0.0774 55 HFeO2- 0.27200E-07 -7.5654 0.22716E-07 -7.6437 0.83514E+00 -0.0782 56 FeO+ 0.13604E-16 -16.8663 0.11383E-16 -16.9437 0.83674E+00 -0.0774 58 FeO2- 0.50013E-09 -9.3009 0.41768E-09 -9.3792 0.83514E+00 -0.0782 59 HFeO2,aq 0.39670E-11 -11.4015 0.39670E-11 -11.4015 0.10000E+01 0.0000 60 H2,aq 0.45303E-05 -5.3439 0.45146E-05 -5.3454 0.99654E+00 -0.0015 61 KCl,aq 0.30794E-09 -9.5115 0.30794E-09 -9.5115 0.10000E+01 0.0000 63 KOH,aq 0.74876E-06 -6.1257 0.74876E-06 -6.1257 0.10000E+01 0.0000 64 KSO4- 0.53784E-13 -13.2693 0.44918E-13 -13.3476 0.83514E+00 -0.0782 65 MgCO3,aq 0.37473E-12 -12.4263 0.37473E-12 -12.4263 0.10000E+01 0.0000 66 Mg(HCO3)+ 0.31775E-14 -14.4979 0.26588E-14 -14.5753 0.83674E+00 -0.0774 67 MgCl+ 0.24669E-14 -14.6079 0.20641E-14 -14.6853 0.83674E+00 -0.0774 68 MgF+ 0.16599E-15 -15.7799 0.13889E-15 -15.8573 0.83674E+00 -0.0774 69 MgOH+ 0.68445E-10 -10.1647 0.57271E-10 -10.2421 0.83674E+00 -0.0774 71 MnF+ 0.46005E-16 -16.3372 0.38495E-16 -16.4146 0.83674E+00 -0.0774 72 MnO,aq 0.17922E-08 -8.7466 0.17922E-08 -8.7466 0.10000E+01 0.0000 73 MnOH+ 0.46704E-09 -9.3306 0.39079E-09 -9.4081 0.83674E+00 -0.0774 74 MnO2-2 0.20587E-10 -10.6864 0.10665E-10 -10.9720 0.51806E+00 -0.2856 75 HMnO2- 0.20894E-09 -9.6800 0.17449E-09 -9.7582 0.83514E+00 -0.0782 78 MnCl+ 0.92168E-14 -14.0354 0.77121E-14 -14.1128 0.83674E+00 -0.0774 79 MnSO4,aq 0.61596E-19 -19.2104 0.61596E-19 -19.2104 0.10000E+01 0.0000 80 NaCl,aq 0.71320E-06 -6.1468 0.71320E-06 -6.1468 0.10000E+01 0.0000 81 NaF,aq 0.91943E-09 -9.0365 0.91943E-09 -9.0365 0.10000E+01 0.0000 82 NaOH,aq 0.95415E-04 -4.0204 0.95415E-04 -4.0204 0.10000E+01 0.0000 84 OH- 0.92810E-02 -2.0324 0.77369E-02 -2.1114 0.83363E+00 -0.0790 89 HPO3-2 0.63907E-15 -15.1945 0.33108E-15 -15.4801 0.51806E+00 -0.2856 91 H2PO3- 0.59366E-19 -19.2265 0.49579E-19 -19.3047 0.83514E+00 -0.0782 92 H3PO4,aq 0.91784E-18 -18.0372 0.91784E-18 -18.0372 0.10000E+01 0.0000 93 H2PO4- 0.38781E-10 -10.4114 0.32418E-10 -10.4892 0.83593E+00 -0.0778 94 PO4-3 0.10602E-08 -8.9746 0.25711E-09 -9.5899 0.24251E+00 -0.6153 98 HP2O7-3 0.95336E-18 -18.0207 0.22034E-18 -18.6569 0.23112E+00 -0.6362 99 P2O7-4 0.91515E-17 -17.0385 0.70487E-18 -18.1519 0.77023E-01 -1.1134 100 H2S,aq 0.75338E-08 -8.1230 0.75077E-08 -8.1245 0.99654E+00 -0.0015 101 S2-2 0.10025E-13 -13.9989 0.51935E-14 -14.2845 0.51806E+00 -0.2856 107 SO3-2 0.24678E-16 -16.6077 0.12970E-16 -16.8871 0.52556E+00 -0.2794 108 HSO3- 0.72615E-19 -19.1390 0.60644E-19 -19.2172 0.83514E+00 -0.0782 109 HSO4- 0.18996E-17 -17.7213 0.15911E-17 -17.7983 0.83756E+00 -0.0770 Charge balance for all species = -.6133E-08 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.8888078E-10 -.2225256E-01 -.2239024E+02 0.0000 2 H2O 0.1000000E+01 0.5550482E+02 0.9981971E+06 0.0000 3 Cl- 0.1553841E-03 0.1560976E-03 0.5524504E+01 6.2400 4 SO4-- 0.4258378E-10 -.1461343E-04 -.1401348E+01 9.5982 5 HCO3- 0.1123852E-04 0.4595121E-04 0.2798938E+01 5.0999 6 HS- 0.3894464E-04 0.5356564E-04 0.1768442E+01 5.6391 7 Al+++ 0.9774696E-29 0.5220740E-05 0.1406184E+00 0.7339 8 H4SiO4 0.7002159E-03 0.1353221E-01 0.1298392E+04 -3.1548 9 Ca++ 0.1215699E-06 0.2166281E-06 0.8666921E-02 13.0506 10 Mg++ 0.2114026E-10 0.9318216E-10 0.2261505E-05 9.2888 11 Fe++ 0.4529925E-13 0.2787888E-07 0.1554244E-02 6.6203 12 K+ 0.1565113E-03 0.1572603E-03 0.6138500E+01 6.2439 13 Na+ 0.1986140E-01 0.2230590E-01 0.5119164E+03 8.3465 14 Mn++ 0.1877700E-10 0.2507556E-08 0.1375206E-03 9.2382 15 F- 0.2841387E-06 0.2850585E-06 0.5406124E-02 3.5012 16 HPO4-- 0.4532123E-07 0.4642021E-07 0.4447617E-02 12.6253 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.1998455E-01 -.1998416E-01 -.3870049E-06 0.0000000E+00 2 H2O 0.4984673E+02 0.4984673E+02 -.3451293E-06 0.0000000E+00 3 Cl- 0.1401852E-03 0.1401852E-03 0.0000000E+00 0.0000000E+00 4 SO4-- -.1312281E-04 -.1312375E-04 0.9444164E-09 0.0000000E+00 5 HCO3- 0.4126700E-04 0.4126700E-04 0.0000000E+00 0.0000000E+00 6 HS- 0.4810428E-04 0.4810522E-04 -.9444164E-09 0.0000000E+00 7 Al+++ 0.4775352E-05 0.4688544E-05 0.8680807E-07 0.0000000E+00 8 H4SiO4 0.1215302E-01 0.1215275E-01 0.2695520E-06 0.0000000E+00 9 Ca++ 0.2080835E-06 0.1945453E-06 0.1353824E-07 0.0000000E+00 10 Mg++ 0.8368328E-10 0.8368328E-10 0.0000000E+00 0.0000000E+00 11 Fe++ 0.3259227E-07 0.2503694E-07 0.7555331E-08 0.0000000E+00 12 K+ 0.1412294E-03 0.1412294E-03 0.0000000E+00 0.0000000E+00 13 Na+ 0.2003215E-01 0.2003206E-01 0.8533791E-07 0.0000000E+00 14 Mn++ 0.2251939E-08 0.2251939E-08 0.0000000E+00 0.0000000E+00 15 F- 0.2560000E-06 0.2560000E-06 0.0000000E+00 0.0000000E+00 16 HPO4-- 0.4168819E-07 0.4168819E-07 0.0000000E+00 0.0000000E+00 Chg. balance for solid moles: -.1323E-22 Mass of aqueous solution: 0.899626E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 0.0003900 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 0.8534E-07 -7.069 0.2238E-04 -4.650 90.86 0.8590E-05 andradite 0.3778E-08 -8.423 0.1920E-05 -5.717 7.795 0.4988E-06 grossular 0.7351E-09 -9.134 0.3311E-06 -6.480 1.344 0.9213E-07 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8371E+00 0.8371E+00 1.0000 -0.077 grossular 0.1629E+00 0.1629E+00 1.0000 -0.788 Solid products produced: Mass = 0.000025 g Volume = 0.000009 cm3 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.0003900 moles log = -3.4089 Original solution: 1000.0103000 g Original solution / Rock added: 2564128.97 (Water/Rock Ratio), log = 6.4089 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0461 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9757E+00 0.9856 0.1006E+01 0.1021E+01 CO2,gas 0.1523E-06 1.0069 0.1605E-06 0.1594E-06 CH4,gas 0.1867E-01 1.0123 0.1977E-01 0.1953E-01 H2,gas 0.5663E-02 1.0006 0.5927E-02 0.5924E-02 H2S,gas 0.1981E-06 0.9959 0.2064E-06 0.2072E-06 S2,gas 0.4350E-28 1.0000 0.4551E-28 0.4551E-28 CO,gas 0.2423E-12 1.0000 0.2535E-12 0.2535E-12 SO3,gas 0.4456E-46 1.0000 0.4662E-46 0.4662E-46 SO2,gas 0.1028E-25 1.0000 0.1075E-25 0.1075E-25 HF,gas 0.2841E-15 1.0000 0.2972E-15 0.2972E-15 HCl,gas 0.2995E-17 1.0000 0.3133E-17 0.3133E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 17 albite -0.38 -0.38 0.00 0.000 -0.94784E-12 23 andradite 39.01 39.01 0.00 0.000 -0.36397E-10 24 grossular 32.73 32.73 0.00 0.000 0.00000E+00 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -15.15 -8.49 -2.831 0.14503E+05 -6.795 3 CH4,gas 4.54 1.14 -3.40 -0.851 0.58103E+04 -1.704 4 H2,gas 8.00 4.07 -3.93 -2.244 0.67038E+04 -2.227 5 H2S,gas -6.23 -14.61 -8.38 -4.192 0.14316E+05 -6.685 6 S2,gas -7.34 -37.38 -30.04 -4.622 0.51294E+05 -28.342 7 CO,gas 3.21 -11.08 -14.30 -4.398 0.24408E+05 -12.596 8 SO3,gas 17.12 -30.91 -48.03 -12.008 0.82011E+05 -46.331 9 SO2,gas 0.83 -26.84 -27.67 -7.378 0.47242E+05 -25.969 10 HF,gas 0.47 -16.75 -17.23 -8.613 0.29413E+05 -15.527 11 HCl,gas 5.19 -14.01 -19.20 -9.601 0.32789E+05 -17.504 12 acmite 7.71 6.62 -1.09 -0.113 0.18599E+04 16 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 20 spessartine 24.46 19.72 -4.74 -0.237 0.80920E+04 21 analcite 3.32 2.77 -0.55 -0.061 0.94075E+03 27 annite 20.12 17.37 -2.75 -0.153 0.46939E+04 28 phlogopite 27.06 25.38 -1.68 -0.094 0.28764E+04 30 anorthite 12.71 8.21 -4.50 -0.346 0.76861E+04 33 apatite-OH -18.15 -18.39 -0.24 -0.018 0.40915E+03 34 apatite-F -34.30 -35.15 -0.84 -0.070 0.14420E+04 38 aragonite 0.97 -2.10 -3.07 -1.023 0.52414E+04 39 brucite 12.57 9.29 -3.28 -0.656 0.56000E+04 40 calcite 0.81 -2.10 -2.91 -0.972 0.49772E+04 41 carnegieite-low 9.02 5.93 -3.10 -0.443 0.52891E+04 42 carnegieite-high 10.09 5.93 -4.17 -0.595 0.71161E+04 43 carpholite-Mg 8.58 4.45 -4.13 -0.276 0.70603E+04 44 carpholite-Fe 6.71 1.78 -4.93 -0.329 0.84247E+04 45 celadonite 5.34 3.65 -1.69 -0.100 0.28925E+04 46 celadonite-Fe 3.88 0.98 -2.90 -0.170 0.49474E+04 47 chrysotile 23.89 21.56 -2.34 -0.195 0.39876E+04 49 clinochlore 39.07 38.45 -0.62 -0.019 0.10616E+04 50 daphnite 28.97 25.11 -3.86 -0.121 0.65912E+04 52 chlorite-Al-free 47.17 43.11 -4.06 -0.169 0.69304E+04 54 chloritoid-Fe 9.17 4.93 -4.24 -0.283 0.72401E+04 55 chloritoid-Mn 11.40 7.55 -3.85 -0.257 0.65734E+04 57 coesite -2.38 -3.15 -0.78 -0.260 0.13296E+04 64 cristobalite -2.56 -3.15 -0.59 -0.198 0.10150E+04 66 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71234E+04 68 diaspore 2.87 0.73 -2.14 -0.357 0.36536E+04 69 diamond -3.10 -7.01 -3.90 -1.115 0.66661E+04 70 diopside 16.18 16.03 -0.15 -0.015 0.25868E+03 71 hedenbergite 14.21 13.36 -0.85 -0.085 0.14462E+04 74 enstatite 17.26 12.27 -5.00 -0.500 0.85318E+04 76 clinoenstatite 17.17 12.27 -4.90 -0.490 0.83634E+04 78 epidote 24.67 22.69 -1.98 -0.096 0.33838E+04 79 clinozoisite 22.81 18.84 -3.97 -0.180 0.67743E+04 80 epidote-Fe 29.84 26.54 -3.30 -0.172 0.56400E+04 81 fayalite 14.05 10.09 -3.96 -0.566 0.67614E+04 82 ferrosilite 11.15 6.93 -4.22 -0.422 0.72028E+04 86 gibbsite 4.08 0.73 -3.35 -0.478 0.57121E+04 87 glaucophane 22.97 20.79 -2.19 -0.059 0.37318E+04 88 glaucophane-Fe 17.28 12.78 -4.49 -0.121 0.76703E+04 89 graphite -3.55 -7.01 -3.46 -0.989 0.59083E+04 90 greenalite 16.14 13.55 -2.59 -0.216 0.44192E+04 93 hematite 12.57 9.17 -3.40 -0.412 0.58041E+04 94 heulandite -5.83 -7.56 -1.74 -0.079 0.29671E+04 98 jadeite 4.22 2.77 -1.44 -0.144 0.24662E+04 100 kalsilite 7.58 3.82 -3.76 -0.537 0.64216E+04 101 kaolinite -1.33 -4.84 -3.51 -0.319 0.59913E+04 104 laumontite 2.88 1.90 -0.98 -0.066 0.16803E+04 105 lawsonite 9.62 8.21 -1.41 -0.094 0.24027E+04 106 leucite 4.12 0.67 -3.45 -0.345 0.58918E+04 108 lizardite 23.24 21.56 -1.69 -0.141 0.28803E+04 110 magnetite 20.09 15.79 -4.30 -0.351 0.73424E+04 111 minnesotaite 10.39 7.24 -3.15 -0.185 0.53722E+04 115 manganosite 14.06 9.24 -4.82 -1.205 0.82299E+04 119 microcline -2.49 -2.49 0.00 0.000 0.32828E-01 123 muscovite 2.58 -1.02 -3.60 -0.212 0.61487E+04 124 paragonite 4.24 1.08 -3.16 -0.186 0.53878E+04 125 nepheline 8.34 5.93 -2.41 -0.345 0.41215E+04 137 phlogopite-Na 29.65 27.48 -2.16 -0.120 0.36952E+04 139 prehnite 19.37 18.10 -1.27 -0.075 0.21637E+04 140 prehnite-Fe 22.50 21.95 -0.54 -0.033 0.92826E+03 141 pumpellyite-Fe 46.27 43.56 -2.71 -0.060 0.46202E+04 142 pumpellyite-Mg 48.99 46.23 -2.76 -0.061 0.47173E+04 146 pyrrhotite -4.26 -7.99 -3.73 -1.245 0.63756E+04 147 pyrrhotiteFe0.875 -6.02 -9.33 -3.31 -1.217 0.56517E+04 148 pyroxmangite 7.40 6.08 -1.32 -0.263 0.22458E+04 149 pyrophyllite -6.18 -11.15 -4.98 -0.311 0.84954E+04 150 quartz -2.99 -3.15 -0.17 -0.055 0.28230E+03 154 rhodochrosite -0.98 -5.92 -4.94 -1.646 0.84335E+04 155 rhodonite 7.45 6.08 -1.36 -0.272 0.23260E+04 156 sanidine -1.28 -2.49 -1.21 -0.093 0.20678E+04 166 stilbite -7.52 -7.56 -0.04 -0.002 0.73256E+02 167 stilpnomelane-Fe 13.02 12.45 -0.56 -0.017 0.96271E+03 168 stilpnomelane-Mg 27.44 25.80 -1.65 -0.049 0.28097E+04 174 talc 16.49 15.25 -1.24 -0.073 0.21234E+04 177 tephroite 18.09 15.32 -2.76 -0.395 0.47197E+04 181 tridymite -2.63 -3.15 -0.53 -0.176 0.90228E+03 182 tremolite 47.87 47.31 -0.56 -0.015 0.95974E+03 183 ferroactinolite 38.45 33.96 -4.49 -0.121 0.76630E+04 184 troilite-low -4.41 -7.99 -3.58 -1.194 0.61184E+04 190 wairakite 3.95 1.90 -2.05 -0.121 0.35022E+04 191 walstromite 11.51 9.90 -1.61 -0.323 0.27549E+04 192 wollastonite 10.46 9.90 -0.57 -0.113 0.96534E+03 193 pseudo-wollastonite 11.00 9.90 -1.10 -0.221 0.18852E+04 194 zoisite 22.85 18.84 -4.01 -0.182 0.68483E+04 195 akaganeite 7.75 4.58 -3.17 -0.686 0.54146E+04 202 chalcedony -2.80 -3.15 -0.35 -0.117 0.60160E+03 204 montmorillonite-Ca -2.29 -6.17 -3.88 -0.240 0.66319E+04 205 montmorillonite-K -2.24 -6.27 -4.03 -0.247 0.68826E+04 206 montmorillonite-Mg -2.48 -6.80 -4.32 -0.267 0.73687E+04 207 montmorillonite-Na -2.04 -5.57 -3.54 -0.217 0.60375E+04 208 nontronite-Ca 3.21 -0.02 -3.23 -0.210 0.55152E+04 209 nontronite-H 2.53 -2.17 -4.70 -0.315 0.80277E+04 210 nontronite-K 3.34 -0.11 -3.45 -0.221 0.58892E+04 211 nontronite-Mg 3.07 -0.64 -3.71 -0.241 0.63361E+04 212 nontronite-Na 3.52 0.59 -2.93 -0.188 0.50100E+04 228 tobermorite 9.82 7.72 -2.11 -0.575 0.35971E+04 234 alabandite -0.98 -5.38 -4.40 -1.466 0.75103E+04 237 boehmite 4.41 0.73 -3.67 -0.612 0.62705E+04 239 ferrous-oxide 9.81 6.62 -3.19 -0.798 0.54490E+04 245 silica-amorphous -2.09 -3.15 -1.06 -0.354 0.18158E+04 247 an20ab80 2.02 1.33 -0.68 -0.053 0.11664E+04 248 an25ab75 2.65 1.76 -0.88 -0.068 0.15049E+04 249 an30ab70 3.28 2.19 -1.09 -0.083 0.18531E+04 250 tr.625ac.25prg.125 45.16 44.92 -0.25 -0.007 0.42196E+03 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 0.0000200 MOLES Current total amount of reactant added: 0.0003900 MOLES New total amount of reactant added: 0.0004100 MOLES Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.5508E-08 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 6 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 0.0004100 Water: Moles liquid = 0.4985E+02 kg liquid = 0.8981E+00 Moles total = 0.4985E+02 kg total = 0.8980E+00 Activity = 1.0000 Stoichiometric ionic strength = .1135636E-01 Osmotic coef. = 0.9680 True ionic strength = .2004081E-01 Chg. balance for total moles = -.5508E-08 Max. difference allowed = 0.1403E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.88912E-10 -10.0510 0.74703E-10 -10.1267 0.84019E+00 -0.0756 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.15551E-03 -3.8082 0.12988E-03 -3.8865 0.83514E+00 -0.0782 4 SO4-- 0.45752E-10 -10.3396 0.23752E-10 -10.6243 0.51916E+00 -0.2847 5 HCO3- 0.11830E-04 -4.9270 0.98938E-05 -5.0046 0.83636E+00 -0.0776 6 HS- 0.39486E-04 -4.4036 0.32981E-04 -4.4817 0.83526E+00 -0.0782 7 Al+++ 0.97791E-29 -29.0097 0.22578E-29 -29.6463 0.23088E+00 -0.6366 8 H4SiO4 0.70045E-03 -3.1546 0.70045E-03 -3.1546 0.10000E+01 0.0000 9 Ca++ 0.12127E-06 -6.9162 0.62498E-07 -7.2041 0.51534E+00 -0.2879 10 Mg++ 0.21141E-10 -10.6749 0.10845E-10 -10.9648 0.51298E+00 -0.2899 11 Fe++ 0.45236E-13 -13.3445 0.23231E-13 -13.6339 0.51354E+00 -0.2894 12 K+ 0.15651E-03 -3.8055 0.13093E-03 -3.8830 0.83656E+00 -0.0775 13 Na+ 0.19861E-01 -1.7020 0.16584E-01 -1.7803 0.83499E+00 -0.0783 14 Mn++ 0.18790E-10 -10.7261 0.96574E-11 -11.0151 0.51397E+00 -0.2891 15 F- 0.29302E-06 -6.5331 0.24421E-06 -6.6122 0.83341E+00 -0.0791 16 HPO4-- 0.45322E-07 -7.3437 0.23532E-07 -7.6283 0.51923E+00 -0.2846 18 HSiO3- 0.10483E-01 -1.9795 0.87551E-02 -2.0577 0.83514E+00 -0.0782 19 Ca(HSiO3)+ 0.14893E-07 -7.8270 0.12461E-07 -7.9044 0.83674E+00 -0.0774 20 Mg(HSiO3)+ 0.32162E-11 -11.4927 0.26911E-11 -11.5701 0.83674E+00 -0.0774 21 NaHSiO3,aq 0.23483E-02 -2.6292 0.23483E-02 -2.6292 0.10000E+01 0.0000 22 AlO+ 0.65779E-16 -16.1819 0.55040E-16 -16.2593 0.83674E+00 -0.0774 24 HAlO2,aq 0.14673E-09 -9.8335 0.14673E-09 -9.8335 0.10000E+01 0.0000 25 AlO2- 0.52155E-05 -5.2827 0.43478E-05 -5.3617 0.83363E+00 -0.0790 26 CH4,aq 0.13391E-04 -4.8732 0.13345E-04 -4.8747 0.99654E+00 -0.0015 27 C2H6,aq 0.68662E-14 -14.1633 0.68424E-14 -14.1648 0.99654E+00 -0.0015 31 CO,aq 0.17651E-15 -15.7532 0.17651E-15 -15.7532 0.10000E+01 0.0000 32 CO2,aq 0.15848E-08 -8.8000 0.15793E-08 -8.8015 0.99654E+00 -0.0015 33 CO3-2 0.22330E-04 -4.6511 0.11568E-04 -4.9367 0.51805E+00 -0.2856 34 CaCO3,aq 0.90654E-08 -8.0426 0.90654E-08 -8.0426 0.10000E+01 0.0000 35 Ca(HCO3)+ 0.18863E-10 -10.7244 0.15784E-10 -10.8018 0.83674E+00 -0.0774 36 CaCl+ 0.15699E-10 -10.8041 0.13136E-10 -10.8815 0.83674E+00 -0.0774 37 CaCl2,aq 0.40532E-15 -15.3922 0.40532E-15 -15.3922 0.10000E+01 0.0000 38 CaF+ 0.26631E-12 -12.5746 0.22283E-12 -12.6520 0.83674E+00 -0.0774 39 CaOH+ 0.71259E-07 -7.1472 0.59625E-07 -7.2246 0.83674E+00 -0.0774 40 CaSO4,aq 0.47139E-15 -15.3266 0.47139E-15 -15.3266 0.10000E+01 0.0000 41 HCl,aq 0.17779E-14 -14.7501 0.17779E-14 -14.7501 0.10000E+01 0.0000 45 HF,aq 0.12489E-12 -12.9035 0.12489E-12 -12.9035 0.10000E+01 0.0000 46 HF2- 0.12330E-19 -19.9091 0.10297E-19 -19.9873 0.83514E+00 -0.0782 48 FeCl+ 0.57074E-17 -17.2436 0.47756E-17 -17.3210 0.83674E+00 -0.0774 51 FeF+ 0.34647E-18 -18.4603 0.28990E-18 -18.5377 0.83674E+00 -0.0774 53 FeO,aq 0.16179E-09 -9.7911 0.16179E-09 -9.7911 0.10000E+01 0.0000 54 FeOH+ 0.12098E-10 -10.9173 0.10122E-10 -10.9947 0.83674E+00 -0.0774 55 HFeO2- 0.27134E-07 -7.5665 0.22660E-07 -7.6447 0.83514E+00 -0.0782 56 FeO+ 0.13680E-16 -16.8639 0.11446E-16 -16.9413 0.83674E+00 -0.0774 58 FeO2- 0.50255E-09 -9.2988 0.41970E-09 -9.3771 0.83514E+00 -0.0782 59 HFeO2,aq 0.39876E-11 -11.3993 0.39876E-11 -11.3993 0.10000E+01 0.0000 60 H2,aq 0.44647E-05 -5.3502 0.44493E-05 -5.3517 0.99654E+00 -0.0015 61 KCl,aq 0.30820E-09 -9.5112 0.30820E-09 -9.5112 0.10000E+01 0.0000 63 KOH,aq 0.74849E-06 -6.1258 0.74849E-06 -6.1258 0.10000E+01 0.0000 64 KSO4- 0.57785E-13 -13.2382 0.48258E-13 -13.3164 0.83514E+00 -0.0782 65 MgCO3,aq 0.39431E-12 -12.4042 0.39431E-12 -12.4042 0.10000E+01 0.0000 66 Mg(HCO3)+ 0.33448E-14 -14.4756 0.27987E-14 -14.5530 0.83674E+00 -0.0774 67 MgCl+ 0.24691E-14 -14.6075 0.20660E-14 -14.6849 0.83674E+00 -0.0774 68 MgF+ 0.17118E-15 -15.7665 0.14324E-15 -15.8439 0.83674E+00 -0.0774 69 MgOH+ 0.68424E-10 -10.1648 0.57253E-10 -10.2422 0.83674E+00 -0.0774 71 MnF+ 0.47475E-16 -16.3235 0.39724E-16 -16.4010 0.83674E+00 -0.0774 72 MnO,aq 0.17921E-08 -8.7466 0.17921E-08 -8.7466 0.10000E+01 0.0000 73 MnOH+ 0.46719E-09 -9.3305 0.39092E-09 -9.4079 0.83674E+00 -0.0774 74 MnO2-2 0.20572E-10 -10.6867 0.10658E-10 -10.9723 0.51805E+00 -0.2856 75 HMnO2- 0.20886E-09 -9.6801 0.17443E-09 -9.7584 0.83514E+00 -0.0782 78 MnCl+ 0.92307E-14 -14.0348 0.77237E-14 -14.1122 0.83674E+00 -0.0774 79 MnSO4,aq 0.66221E-19 -19.1790 0.66221E-19 -19.1790 0.10000E+01 0.0000 80 NaCl,aq 0.71380E-06 -6.1464 0.71380E-06 -6.1464 0.10000E+01 0.0000 81 NaF,aq 0.94816E-09 -9.0231 0.94816E-09 -9.0231 0.10000E+01 0.0000 82 NaOH,aq 0.95381E-04 -4.0205 0.95381E-04 -4.0205 0.10000E+01 0.0000 84 OH- 0.92778E-02 -2.0326 0.77342E-02 -2.1116 0.83363E+00 -0.0790 89 HPO3-2 0.62983E-15 -15.2008 0.32628E-15 -15.4864 0.51805E+00 -0.2856 91 H2PO3- 0.58527E-19 -19.2326 0.48878E-19 -19.3109 0.83514E+00 -0.0782 92 H3PO4,aq 0.91848E-18 -18.0369 0.91848E-18 -18.0369 0.10000E+01 0.0000 93 H2PO4- 0.38794E-10 -10.4112 0.32429E-10 -10.4891 0.83593E+00 -0.0778 94 PO4-3 0.10599E-08 -8.9748 0.25701E-09 -9.5900 0.24250E+00 -0.6153 98 HP2O7-3 0.95371E-18 -18.0206 0.22041E-18 -18.6568 0.23111E+00 -0.6362 99 P2O7-4 0.91519E-17 -17.0385 0.70486E-18 -18.1519 0.77018E-01 -1.1134 100 H2S,aq 0.76411E-08 -8.1168 0.76146E-08 -8.1184 0.99654E+00 -0.0015 101 S2-2 0.10457E-13 -13.9806 0.54171E-14 -14.2662 0.51805E+00 -0.2856 107 SO3-2 0.26131E-16 -16.5828 0.13733E-16 -16.8622 0.52555E+00 -0.2794 108 HSO3- 0.76915E-19 -19.1140 0.64234E-19 -19.1922 0.83514E+00 -0.0782 109 HSO4- 0.20417E-17 -17.6900 0.17100E-17 -17.7670 0.83755E+00 -0.0770 Charge balance for all species = -.6133E-08 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.8891226E-10 -.2225013E-01 -.2238779E+02 0.0000 2 H2O 0.1000000E+01 0.5550482E+02 0.9981970E+06 0.0000 3 Cl- 0.1555148E-03 0.1562289E-03 0.5529152E+01 6.2402 4 SO4-- 0.4575166E-10 -.1450709E-04 -.1391151E+01 9.6290 5 HCO3- 0.1182957E-04 0.4756133E-04 0.2897012E+01 5.1220 6 HS- 0.3948568E-04 0.5400046E-04 0.1782797E+01 5.6449 7 Al+++ 0.9779132E-29 0.5215630E-05 0.1404808E+00 0.7337 8 H4SiO4 0.7004455E-03 0.1353219E-01 0.1298390E+04 -3.1546 9 Ca++ 0.1212747E-06 0.2165263E-06 0.8662850E-02 13.0492 10 Mg++ 0.2114143E-10 0.9318212E-10 0.2261504E-05 9.2886 11 Fe++ 0.4523605E-13 0.2781414E-07 0.1550635E-02 6.6194 12 K+ 0.1565115E-03 0.1572603E-03 0.6138497E+01 6.2437 13 Na+ 0.1986147E-01 0.2230589E-01 0.5119161E+03 8.3463 14 Mn++ 0.1878976E-10 0.2507555E-08 0.1375205E-03 9.2382 15 F- 0.2930179E-06 0.2939665E-06 0.5575063E-02 3.5144 16 HPO4-- 0.4532154E-07 0.4642019E-07 0.4447615E-02 12.6250 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.1998239E-01 -.1998199E-01 -.4056410E-06 0.0000000E+00 2 H2O 0.4984674E+02 0.4984674E+02 -.3634947E-06 0.0000000E+00 3 Cl- 0.1403032E-03 0.1403032E-03 0.0000000E+00 0.0000000E+00 4 SO4-- -.1302731E-04 -.1302826E-04 0.9516826E-09 0.0000000E+00 5 HCO3- 0.4271300E-04 0.4271300E-04 0.0000000E+00 0.0000000E+00 6 HS- 0.4849478E-04 0.4849573E-04 -.9516826E-09 0.0000000E+00 7 Al+++ 0.4775352E-05 0.4683957E-05 0.9139489E-07 0.0000000E+00 8 H4SiO4 0.1215302E-01 0.1215274E-01 0.2833955E-06 0.0000000E+00 9 Ca++ 0.2080835E-06 0.1944540E-06 0.1362954E-07 0.0000000E+00 10 Mg++ 0.8368328E-10 0.8368328E-10 0.0000000E+00 0.0000000E+00 11 Fe++ 0.3259227E-07 0.2497881E-07 0.7613461E-08 0.0000000E+00 12 K+ 0.1412294E-03 0.1412294E-03 0.0000000E+00 0.0000000E+00 13 Na+ 0.2003215E-01 0.2003206E-01 0.8992199E-07 0.0000000E+00 14 Mn++ 0.2251939E-08 0.2251939E-08 0.0000000E+00 0.0000000E+00 15 F- 0.2640000E-06 0.2640000E-06 0.0000000E+00 0.0000000E+00 16 HPO4-- 0.4168819E-07 0.4168819E-07 0.0000000E+00 0.0000000E+00 Chg. balance for solid moles: -.7941E-22 Mass of aqueous solution: 0.899626E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 0.0004100 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 0.8992E-07 -7.046 0.2358E-04 -4.627 91.23 0.9052E-05 andradite 0.3807E-08 -8.419 0.1935E-05 -5.713 7.485 0.5026E-06 grossular 0.7364E-09 -9.133 0.3317E-06 -6.479 1.284 0.9230E-07 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8379E+00 0.8379E+00 1.0000 -0.077 grossular 0.1621E+00 0.1621E+00 1.0000 -0.790 Solid products produced: Mass = 0.000026 g Volume = 0.000010 cm3 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.0004100 moles log = -3.3872 Original solution: 1000.0103000 g Original solution / Rock added: 2439049.51 (Water/Rock Ratio), log = 6.3872 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0459 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9759E+00 0.9856 0.1006E+01 0.1021E+01 CO2,gas 0.1605E-06 1.0069 0.1690E-06 0.1678E-06 CH4,gas 0.1855E-01 1.0123 0.1964E-01 0.1940E-01 H2,gas 0.5582E-02 1.0006 0.5841E-02 0.5838E-02 H2S,gas 0.2010E-06 0.9959 0.2093E-06 0.2102E-06 S2,gas 0.4609E-28 1.0000 0.4820E-28 0.4820E-28 CO,gas 0.2515E-12 1.0000 0.2630E-12 0.2630E-12 SO3,gas 0.4792E-46 1.0000 0.5012E-46 0.5012E-46 SO2,gas 0.1089E-25 1.0000 0.1139E-25 0.1139E-25 HF,gas 0.2932E-15 1.0000 0.3066E-15 0.3066E-15 HCl,gas 0.2999E-17 1.0000 0.3137E-17 0.3137E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 17 albite -0.38 -0.38 0.00 0.000 -0.94784E-12 23 andradite 39.01 39.01 0.00 0.000 0.00000E+00 24 grossular 32.73 32.73 0.00 0.000 -0.48529E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -15.13 -8.47 -2.824 0.14464E+05 -6.772 3 CH4,gas 4.54 1.14 -3.41 -0.851 0.58153E+04 -1.707 4 H2,gas 8.00 4.07 -3.93 -2.247 0.67146E+04 -2.233 5 H2S,gas -6.23 -14.61 -8.38 -4.189 0.14305E+05 -6.679 6 S2,gas -7.34 -37.35 -30.02 -4.618 0.51251E+05 -28.317 7 CO,gas 3.21 -11.06 -14.28 -4.394 0.24381E+05 -12.580 8 SO3,gas 17.12 -30.88 -48.00 -12.000 0.81957E+05 -46.300 9 SO2,gas 0.83 -26.81 -27.64 -7.371 0.47199E+05 -25.943 10 HF,gas 0.47 -16.74 -17.21 -8.606 0.29390E+05 -15.513 11 HCl,gas 5.19 -14.01 -19.20 -9.601 0.32788E+05 -17.503 12 acmite 7.71 6.62 -1.09 -0.113 0.18558E+04 16 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 20 spessartine 24.46 19.72 -4.74 -0.237 0.80923E+04 21 analcite 3.32 2.77 -0.55 -0.061 0.94099E+03 27 annite 20.12 17.37 -2.75 -0.153 0.46986E+04 28 phlogopite 27.06 25.38 -1.69 -0.094 0.28778E+04 30 anorthite 12.71 8.21 -4.50 -0.346 0.76889E+04 33 apatite-OH -18.15 -18.40 -0.25 -0.019 0.41928E+03 34 apatite-F -34.30 -35.14 -0.84 -0.070 0.14291E+04 38 aragonite 0.97 -2.08 -3.05 -1.016 0.52055E+04 39 brucite 12.57 9.29 -3.28 -0.656 0.56005E+04 40 calcite 0.81 -2.08 -2.89 -0.965 0.49412E+04 41 carnegieite-low 9.02 5.93 -3.10 -0.443 0.52896E+04 42 carnegieite-high 10.09 5.93 -4.17 -0.595 0.71166E+04 43 carpholite-Mg 8.58 4.45 -4.14 -0.276 0.70612E+04 44 carpholite-Fe 6.71 1.78 -4.94 -0.329 0.84267E+04 45 celadonite 5.34 3.65 -1.69 -0.100 0.28928E+04 46 celadonite-Fe 3.88 0.98 -2.90 -0.170 0.49487E+04 47 chrysotile 23.89 21.56 -2.34 -0.195 0.39886E+04 49 clinochlore 39.07 38.45 -0.62 -0.019 0.10643E+04 50 daphnite 28.97 25.10 -3.86 -0.121 0.65992E+04 52 chlorite-Al-free 47.17 43.11 -4.06 -0.169 0.69324E+04 54 chloritoid-Fe 9.17 4.93 -4.24 -0.283 0.72423E+04 55 chloritoid-Mn 11.40 7.55 -3.85 -0.257 0.65741E+04 57 coesite -2.38 -3.15 -0.78 -0.260 0.13294E+04 64 cristobalite -2.56 -3.15 -0.59 -0.198 0.10147E+04 66 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71234E+04 68 diaspore 2.87 0.73 -2.14 -0.357 0.36541E+04 69 diamond -3.10 -7.00 -3.89 -1.113 0.66494E+04 70 diopside 16.18 16.03 -0.15 -0.015 0.26102E+03 71 hedenbergite 14.21 13.36 -0.85 -0.085 0.14496E+04 74 enstatite 17.26 12.27 -5.00 -0.500 0.85323E+04 76 clinoenstatite 17.17 12.27 -4.90 -0.490 0.83639E+04 78 epidote 24.67 22.69 -1.98 -0.096 0.33849E+04 79 clinozoisite 22.81 18.84 -3.97 -0.180 0.67796E+04 80 epidote-Fe 29.84 26.54 -3.30 -0.171 0.56367E+04 81 fayalite 14.05 10.08 -3.96 -0.566 0.67643E+04 82 ferrosilite 11.15 6.93 -4.22 -0.422 0.72054E+04 86 gibbsite 4.08 0.73 -3.35 -0.478 0.57126E+04 87 glaucophane 22.97 20.79 -2.19 -0.059 0.37327E+04 88 glaucophane-Fe 17.28 12.78 -4.49 -0.121 0.76745E+04 89 graphite -3.55 -7.00 -3.45 -0.986 0.58917E+04 90 greenalite 16.14 13.55 -2.59 -0.216 0.44234E+04 93 hematite 12.57 9.17 -3.39 -0.411 0.57964E+04 94 heulandite -5.83 -7.57 -1.74 -0.079 0.29687E+04 98 jadeite 4.22 2.77 -1.44 -0.144 0.24665E+04 100 kalsilite 7.58 3.82 -3.76 -0.537 0.64221E+04 101 kaolinite -1.33 -4.84 -3.51 -0.319 0.59918E+04 104 laumontite 2.88 1.90 -0.99 -0.066 0.16826E+04 105 lawsonite 9.62 8.21 -1.41 -0.094 0.24055E+04 106 leucite 4.12 0.67 -3.45 -0.345 0.58921E+04 108 lizardite 23.24 21.56 -1.69 -0.141 0.28812E+04 110 magnetite 20.09 15.79 -4.30 -0.351 0.73362E+04 111 minnesotaite 10.39 7.24 -3.15 -0.185 0.53759E+04 115 manganosite 14.06 9.24 -4.82 -1.205 0.82299E+04 119 microcline -2.49 -2.49 0.00 0.000 0.34518E-01 123 muscovite 2.58 -1.02 -3.60 -0.212 0.61497E+04 124 paragonite 4.24 1.08 -3.16 -0.186 0.53887E+04 125 nepheline 8.34 5.93 -2.41 -0.345 0.41220E+04 137 phlogopite-Na 29.65 27.48 -2.16 -0.120 0.36966E+04 139 prehnite 19.37 18.10 -1.27 -0.075 0.21686E+04 140 prehnite-Fe 22.50 21.95 -0.54 -0.033 0.92884E+03 141 pumpellyite-Fe 46.27 43.56 -2.71 -0.060 0.46320E+04 142 pumpellyite-Mg 48.99 46.23 -2.77 -0.062 0.47281E+04 146 pyrrhotite -4.26 -7.99 -3.73 -1.243 0.63666E+04 147 pyrrhotiteFe0.875 -6.02 -9.32 -3.30 -1.215 0.56412E+04 148 pyroxmangite 7.40 6.08 -1.32 -0.263 0.22455E+04 149 pyrophyllite -6.18 -11.15 -4.98 -0.311 0.84953E+04 150 quartz -2.99 -3.15 -0.17 -0.055 0.28206E+03 154 rhodochrosite -0.98 -5.89 -4.92 -1.639 0.83953E+04 155 rhodonite 7.45 6.08 -1.36 -0.272 0.23258E+04 156 sanidine -1.28 -2.49 -1.21 -0.093 0.20678E+04 166 stilbite -7.52 -7.57 -0.04 -0.002 0.74827E+02 167 stilpnomelane-Fe 13.02 12.45 -0.57 -0.017 0.96967E+03 168 stilpnomelane-Mg 27.44 25.79 -1.65 -0.049 0.28113E+04 174 talc 16.49 15.25 -1.24 -0.073 0.21239E+04 177 tephroite 18.09 15.32 -2.76 -0.395 0.47196E+04 181 tridymite -2.63 -3.15 -0.53 -0.176 0.90204E+03 182 tremolite 47.87 47.30 -0.57 -0.015 0.96492E+03 183 ferroactinolite 38.45 33.96 -4.49 -0.121 0.76735E+04 184 troilite-low -4.41 -7.99 -3.58 -1.193 0.61095E+04 190 wairakite 3.95 1.90 -2.05 -0.121 0.35045E+04 191 walstromite 11.51 9.89 -1.61 -0.323 0.27570E+04 192 wollastonite 10.46 9.89 -0.57 -0.113 0.96744E+03 193 pseudo-wollastonite 11.00 9.89 -1.11 -0.221 0.18873E+04 194 zoisite 22.85 18.84 -4.01 -0.182 0.68537E+04 195 akaganeite 7.75 4.59 -3.17 -0.685 0.54107E+04 202 chalcedony -2.80 -3.15 -0.35 -0.117 0.60136E+03 204 montmorillonite-Ca -2.29 -6.17 -3.88 -0.240 0.66322E+04 205 montmorillonite-K -2.24 -6.27 -4.03 -0.247 0.68827E+04 206 montmorillonite-Mg -2.48 -6.80 -4.32 -0.267 0.73687E+04 207 montmorillonite-Na -2.04 -5.57 -3.54 -0.217 0.60376E+04 208 nontronite-Ca 3.21 -0.01 -3.23 -0.209 0.55072E+04 209 nontronite-H 2.53 -2.16 -4.70 -0.315 0.80193E+04 210 nontronite-K 3.34 -0.10 -3.44 -0.221 0.58809E+04 211 nontronite-Mg 3.07 -0.63 -3.71 -0.240 0.63278E+04 212 nontronite-Na 3.52 0.59 -2.93 -0.188 0.50017E+04 228 tobermorite 9.82 7.72 -2.11 -0.575 0.35989E+04 234 alabandite -0.98 -5.37 -4.39 -1.464 0.74998E+04 237 boehmite 4.41 0.73 -3.67 -0.612 0.62710E+04 239 ferrous-oxide 9.81 6.62 -3.19 -0.798 0.54506E+04 245 silica-amorphous -2.09 -3.15 -1.06 -0.354 0.18155E+04 247 an20ab80 2.02 1.33 -0.68 -0.053 0.11669E+04 248 an25ab75 2.65 1.76 -0.88 -0.068 0.15056E+04 249 an30ab70 3.28 2.19 -1.09 -0.084 0.18539E+04 250 tr.625ac.25prg.125 45.16 44.91 -0.25 -0.007 0.42869E+03 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 0.0000200 MOLES Current total amount of reactant added: 0.0004100 MOLES New total amount of reactant added: 0.0004300 MOLES Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.5508E-08 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 6 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 0.0004300 Water: Moles liquid = 0.4985E+02 kg liquid = 0.8981E+00 Moles total = 0.4985E+02 kg total = 0.8980E+00 Activity = 1.0000 Stoichiometric ionic strength = .1135764E-01 Osmotic coef. = 0.9679 True ionic strength = .2004200E-01 Chg. balance for total moles = -.5508E-08 Max. difference allowed = 0.1404E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.88944E-10 -10.0509 0.74730E-10 -10.1265 0.84019E+00 -0.0756 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.15565E-03 -3.8079 0.12998E-03 -3.8861 0.83513E+00 -0.0782 4 SO4-- 0.49031E-10 -10.3095 0.25454E-10 -10.5942 0.51915E+00 -0.2847 5 HCO3- 0.12421E-04 -4.9058 0.10389E-04 -4.9834 0.83636E+00 -0.0776 6 HS- 0.40027E-04 -4.3977 0.33433E-04 -4.4758 0.83526E+00 -0.0782 7 Al+++ 0.97836E-29 -29.0095 0.22587E-29 -29.6461 0.23087E+00 -0.6366 8 H4SiO4 0.70068E-03 -3.1545 0.70068E-03 -3.1545 0.10000E+01 0.0000 9 Ca++ 0.12099E-06 -6.9173 0.62348E-07 -7.2052 0.51533E+00 -0.2879 10 Mg++ 0.21143E-10 -10.6748 0.10846E-10 -10.9647 0.51297E+00 -0.2899 11 Fe++ 0.45182E-13 -13.3450 0.23203E-13 -13.6345 0.51354E+00 -0.2894 12 K+ 0.15651E-03 -3.8055 0.13093E-03 -3.8830 0.83655E+00 -0.0775 13 Na+ 0.19862E-01 -1.7020 0.16584E-01 -1.7803 0.83498E+00 -0.0783 14 Mn++ 0.18803E-10 -10.7258 0.96638E-11 -11.0149 0.51396E+00 -0.2891 15 F- 0.30190E-06 -6.5201 0.25160E-06 -6.5993 0.83341E+00 -0.0791 16 HPO4-- 0.45322E-07 -7.3437 0.23532E-07 -7.6283 0.51922E+00 -0.2846 18 HSiO3- 0.10483E-01 -1.9795 0.87549E-02 -2.0577 0.83513E+00 -0.0782 19 Ca(HSiO3)+ 0.14857E-07 -7.8281 0.12431E-07 -7.9055 0.83673E+00 -0.0774 20 Mg(HSiO3)+ 0.32163E-11 -11.4926 0.26912E-11 -11.5701 0.83673E+00 -0.0774 21 NaHSiO3,aq 0.23483E-02 -2.6293 0.23483E-02 -2.6293 0.10000E+01 0.0000 22 AlO+ 0.65761E-16 -16.1820 0.55024E-16 -16.2594 0.83673E+00 -0.0774 24 HAlO2,aq 0.14663E-09 -9.8338 0.14663E-09 -9.8338 0.10000E+01 0.0000 25 AlO2- 0.52104E-05 -5.2831 0.43435E-05 -5.3622 0.83362E+00 -0.0790 26 CH4,aq 0.13300E-04 -4.8761 0.13254E-04 -4.8776 0.99654E+00 -0.0015 27 C2H6,aq 0.68688E-14 -14.1631 0.68450E-14 -14.1646 0.99654E+00 -0.0015 31 CO,aq 0.18283E-15 -15.7380 0.18283E-15 -15.7380 0.10000E+01 0.0000 32 CO2,aq 0.16646E-08 -8.7787 0.16588E-08 -8.7802 0.99654E+00 -0.0015 33 CO3-2 0.23439E-04 -4.6301 0.12142E-04 -4.9157 0.51804E+00 -0.2856 34 CaCO3,aq 0.94926E-08 -8.0226 0.94926E-08 -8.0226 0.10000E+01 0.0000 35 Ca(HCO3)+ 0.19759E-10 -10.7042 0.16533E-10 -10.7816 0.83673E+00 -0.0774 36 CaCl+ 0.15674E-10 -10.8048 0.13115E-10 -10.8822 0.83673E+00 -0.0774 37 CaCl2,aq 0.40502E-15 -15.3925 0.40502E-15 -15.3925 0.10000E+01 0.0000 38 CaF+ 0.27372E-12 -12.5627 0.22903E-12 -12.6401 0.83673E+00 -0.0774 39 CaOH+ 0.71063E-07 -7.1484 0.59461E-07 -7.2258 0.83673E+00 -0.0774 40 CaSO4,aq 0.50396E-15 -15.2976 0.50396E-15 -15.2976 0.10000E+01 0.0000 41 HCl,aq 0.17800E-14 -14.7496 0.17800E-14 -14.7496 0.10000E+01 0.0000 45 HF,aq 0.12872E-12 -12.8904 0.12872E-12 -12.8904 0.10000E+01 0.0000 46 HF2- 0.13093E-19 -19.8830 0.10934E-19 -19.9612 0.83513E+00 -0.0782 48 FeCl+ 0.57053E-17 -17.2437 0.47738E-17 -17.3211 0.83673E+00 -0.0774 51 FeF+ 0.35654E-18 -18.4479 0.29833E-18 -18.5253 0.83673E+00 -0.0774 53 FeO,aq 0.16148E-09 -9.7919 0.16148E-09 -9.7919 0.10000E+01 0.0000 54 FeOH+ 0.12079E-10 -10.9180 0.10107E-10 -10.9954 0.83673E+00 -0.0774 55 HFeO2- 0.27072E-07 -7.5675 0.22609E-07 -7.6457 0.83513E+00 -0.0782 56 FeO+ 0.13754E-16 -16.8616 0.11509E-16 -16.9390 0.83673E+00 -0.0774 58 FeO2- 0.50493E-09 -9.2968 0.42169E-09 -9.3750 0.83513E+00 -0.0782 59 HFeO2,aq 0.40079E-11 -11.3971 0.40079E-11 -11.3971 0.10000E+01 0.0000 60 H2,aq 0.44027E-05 -5.3563 0.43874E-05 -5.3578 0.99654E+00 -0.0015 61 KCl,aq 0.30846E-09 -9.5108 0.30846E-09 -9.5108 0.10000E+01 0.0000 63 KOH,aq 0.74823E-06 -6.1260 0.74823E-06 -6.1260 0.10000E+01 0.0000 64 KSO4- 0.61926E-13 -13.2081 0.51716E-13 -13.2864 0.83513E+00 -0.0782 65 MgCO3,aq 0.41390E-12 -12.3831 0.41390E-12 -12.3831 0.10000E+01 0.0000 66 Mg(HCO3)+ 0.35122E-14 -14.4544 0.29388E-14 -14.5318 0.83673E+00 -0.0774 67 MgCl+ 0.24712E-14 -14.6071 0.20678E-14 -14.6845 0.83673E+00 -0.0774 68 MgF+ 0.17638E-15 -15.7536 0.14758E-15 -15.8310 0.83673E+00 -0.0774 69 MgOH+ 0.68403E-10 -10.1649 0.57235E-10 -10.2423 0.83673E+00 -0.0774 71 MnF+ 0.48946E-16 -16.3103 0.40954E-16 -16.3877 0.83673E+00 -0.0774 72 MnO,aq 0.17921E-08 -8.7466 0.17921E-08 -8.7466 0.10000E+01 0.0000 73 MnOH+ 0.46734E-09 -9.3304 0.39104E-09 -9.4078 0.83673E+00 -0.0774 74 MnO2-2 0.20558E-10 -10.6870 0.10650E-10 -10.9727 0.51804E+00 -0.2856 75 HMnO2- 0.20878E-09 -9.6803 0.17436E-09 -9.7586 0.83513E+00 -0.0782 78 MnCl+ 0.92446E-14 -14.0341 0.77353E-14 -14.1115 0.83673E+00 -0.0774 79 MnSO4,aq 0.71014E-19 -19.1487 0.71014E-19 -19.1487 0.10000E+01 0.0000 80 NaCl,aq 0.71439E-06 -6.1461 0.71439E-06 -6.1461 0.10000E+01 0.0000 81 NaF,aq 0.97688E-09 -9.0102 0.97688E-09 -9.0102 0.10000E+01 0.0000 82 NaOH,aq 0.95348E-04 -4.0207 0.95348E-04 -4.0207 0.10000E+01 0.0000 84 OH- 0.92746E-02 -2.0327 0.77315E-02 -2.1117 0.83362E+00 -0.0790 89 HPO3-2 0.62108E-15 -15.2069 0.32175E-15 -15.4925 0.51804E+00 -0.2856 91 H2PO3- 0.57734E-19 -19.2386 0.48216E-19 -19.3168 0.83513E+00 -0.0782 92 H3PO4,aq 0.91911E-18 -18.0366 0.91911E-18 -18.0366 0.10000E+01 0.0000 93 H2PO4- 0.38808E-10 -10.4111 0.32440E-10 -10.4889 0.83593E+00 -0.0778 94 PO4-3 0.10595E-08 -8.9749 0.25692E-09 -9.5902 0.24249E+00 -0.6153 98 HP2O7-3 0.95406E-18 -18.0204 0.22048E-18 -18.6566 0.23110E+00 -0.6362 99 P2O7-4 0.91523E-17 -17.0385 0.70485E-18 -18.1519 0.77013E-01 -1.1134 100 H2S,aq 0.77485E-08 -8.1108 0.77216E-08 -8.1123 0.99654E+00 -0.0015 101 S2-2 0.10897E-13 -13.9627 0.56449E-14 -14.2483 0.51804E+00 -0.2856 107 SO3-2 0.27615E-16 -16.5589 0.14513E-16 -16.8383 0.52554E+00 -0.2794 108 HSO3- 0.81310E-19 -19.0899 0.67905E-19 -19.1681 0.83513E+00 -0.0782 109 HSO4- 0.21887E-17 -17.6598 0.18332E-17 -17.7368 0.83755E+00 -0.0770 Charge balance for all species = -.6133E-08 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.8894376E-10 -.2224770E-01 -.2238535E+02 0.0000 2 H2O 0.1000000E+01 0.5550482E+02 0.9981968E+06 0.0000 3 Cl- 0.1556456E-03 0.1563603E-03 0.5533799E+01 6.2404 4 SO4-- 0.4903100E-10 -.1440075E-04 -.1380954E+01 9.6588 5 HCO3- 0.1242119E-04 0.4917144E-04 0.2995086E+01 5.1431 6 HS- 0.4002672E-04 0.5443527E-04 0.1797152E+01 5.6507 7 Al+++ 0.9783573E-29 0.5210523E-05 0.1403432E+00 0.7334 8 H4SiO4 0.7006752E-03 0.1353217E-01 0.1298387E+04 -3.1545 9 Ca++ 0.1209860E-06 0.2164345E-06 0.8659174E-02 13.0478 10 Mg++ 0.2114259E-10 0.9318209E-10 0.2261503E-05 9.2883 11 Fe++ 0.4518201E-13 0.2775498E-07 0.1547337E-02 6.6186 12 K+ 0.1565117E-03 0.1572602E-03 0.6138494E+01 6.2435 13 Na+ 0.1986154E-01 0.2230587E-01 0.5119157E+03 8.3462 14 Mn++ 0.1880254E-10 0.2507554E-08 0.1375204E-03 9.2382 15 F- 0.3018972E-06 0.3028745E-06 0.5744001E-02 3.5272 16 HPO4-- 0.4532186E-07 0.4642018E-07 0.4447613E-02 12.6247 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.1998024E-01 -.1997982E-01 -.4242445E-06 0.0000000E+00 2 H2O 0.4984676E+02 0.4984676E+02 -.3818549E-06 0.0000000E+00 3 Cl- 0.1404212E-03 0.1404212E-03 0.0000000E+00 0.0000000E+00 4 SO4-- -.1293181E-04 -.1293277E-04 0.9583222E-09 0.0000000E+00 5 HCO3- 0.4415900E-04 0.4415900E-04 0.0000000E+00 0.0000000E+00 6 HS- 0.4888528E-04 0.4888624E-04 -.9583222E-09 0.0000000E+00 7 Al+++ 0.4775352E-05 0.4679372E-05 0.9598012E-07 0.0000000E+00 8 H4SiO4 0.1215302E-01 0.1215272E-01 0.2972282E-06 0.0000000E+00 9 Ca++ 0.2080835E-06 0.1943716E-06 0.1371195E-07 0.0000000E+00 10 Mg++ 0.8368328E-10 0.8368328E-10 0.0000000E+00 0.0000000E+00 11 Fe++ 0.3259227E-07 0.2492569E-07 0.7666577E-08 0.0000000E+00 12 K+ 0.1412294E-03 0.1412294E-03 0.0000000E+00 0.0000000E+00 13 Na+ 0.2003215E-01 0.2003206E-01 0.9450540E-07 0.0000000E+00 14 Mn++ 0.2251939E-08 0.2251939E-08 0.0000000E+00 0.0000000E+00 15 F- 0.2720000E-06 0.2720000E-06 0.0000000E+00 0.0000000E+00 16 HPO4-- 0.4168819E-07 0.4168819E-07 0.0000000E+00 0.0000000E+00 Chg. balance for solid moles: -.5294E-22 Mass of aqueous solution: 0.899627E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 0.0004300 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 0.9451E-07 -7.025 0.2478E-04 -4.606 91.57 0.9513E-05 andradite 0.3833E-08 -8.416 0.1948E-05 -5.710 7.198 0.5061E-06 grossular 0.7374E-09 -9.132 0.3321E-06 -6.479 1.227 0.9242E-07 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8387E+00 0.8387E+00 1.0000 -0.076 grossular 0.1613E+00 0.1613E+00 1.0000 -0.792 Solid products produced: Mass = 0.000027 g Volume = 0.000010 cm3 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.0004300 moles log = -3.3665 Original solution: 1000.0103000 g Original solution / Rock added: 2325605.35 (Water/Rock Ratio), log = 6.3665 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0457 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9761E+00 0.9856 0.1006E+01 0.1021E+01 CO2,gas 0.1686E-06 1.0069 0.1775E-06 0.1763E-06 CH4,gas 0.1843E-01 1.0123 0.1951E-01 0.1927E-01 H2,gas 0.5506E-02 1.0006 0.5760E-02 0.5757E-02 H2S,gas 0.2038E-06 0.9959 0.2123E-06 0.2131E-06 S2,gas 0.4874E-28 1.0000 0.5097E-28 0.5097E-28 CO,gas 0.2606E-12 1.0000 0.2725E-12 0.2725E-12 SO3,gas 0.5140E-46 1.0000 0.5375E-46 0.5375E-46 SO2,gas 0.1152E-25 1.0000 0.1204E-25 0.1204E-25 HF,gas 0.3022E-15 1.0000 0.3160E-15 0.3160E-15 HCl,gas 0.3004E-17 1.0000 0.3141E-17 0.3141E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 17 albite -0.38 -0.38 0.00 0.000 -0.94784E-12 23 andradite 39.01 39.01 0.00 0.000 0.12132E-10 24 grossular 32.73 32.73 0.00 0.000 0.24265E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -15.11 -8.45 -2.817 0.14428E+05 -6.751 3 CH4,gas 4.54 1.13 -3.41 -0.852 0.58203E+04 -1.710 4 H2,gas 8.00 4.06 -3.94 -2.251 0.67249E+04 -2.240 5 H2S,gas -6.23 -14.60 -8.37 -4.186 0.14295E+05 -6.673 6 S2,gas -7.34 -37.33 -29.99 -4.614 0.51210E+05 -28.293 7 CO,gas 3.21 -11.05 -14.26 -4.389 0.24355E+05 -12.565 8 SO3,gas 17.12 -30.85 -47.97 -11.992 0.81905E+05 -46.270 9 SO2,gas 0.83 -26.79 -27.62 -7.365 0.47157E+05 -25.919 10 HF,gas 0.47 -16.73 -17.20 -8.600 0.29367E+05 -15.500 11 HCl,gas 5.19 -14.01 -19.20 -9.601 0.32787E+05 -17.503 12 acmite 7.71 6.63 -1.08 -0.113 0.18518E+04 16 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 20 spessartine 24.46 19.72 -4.74 -0.237 0.80926E+04 21 analcite 3.32 2.77 -0.55 -0.061 0.94124E+03 27 annite 20.12 17.37 -2.75 -0.153 0.47028E+04 28 phlogopite 27.06 25.38 -1.69 -0.094 0.28793E+04 30 anorthite 12.71 8.21 -4.50 -0.347 0.76916E+04 33 apatite-OH -18.15 -18.40 -0.25 -0.019 0.42923E+03 34 apatite-F -34.30 -35.13 -0.83 -0.069 0.14166E+04 38 aragonite 0.97 -2.06 -3.03 -1.010 0.51713E+04 39 brucite 12.57 9.29 -3.28 -0.656 0.56010E+04 40 calcite 0.81 -2.06 -2.87 -0.958 0.49071E+04 41 carnegieite-low 9.02 5.93 -3.10 -0.443 0.52901E+04 42 carnegieite-high 10.09 5.93 -4.17 -0.595 0.71171E+04 43 carpholite-Mg 8.58 4.45 -4.14 -0.276 0.70621E+04 44 carpholite-Fe 6.71 1.78 -4.94 -0.329 0.84286E+04 45 celadonite 5.34 3.65 -1.69 -0.100 0.28930E+04 46 celadonite-Fe 3.88 0.98 -2.90 -0.171 0.49499E+04 47 chrysotile 23.89 21.56 -2.34 -0.195 0.39896E+04 49 clinochlore 39.07 38.44 -0.62 -0.020 0.10669E+04 50 daphnite 28.97 25.10 -3.87 -0.121 0.66065E+04 52 chlorite-Al-free 47.17 43.11 -4.06 -0.169 0.69344E+04 54 chloritoid-Fe 9.17 4.93 -4.24 -0.283 0.72444E+04 55 chloritoid-Mn 11.40 7.55 -3.85 -0.257 0.65748E+04 57 coesite -2.38 -3.15 -0.78 -0.259 0.13291E+04 64 cristobalite -2.56 -3.15 -0.59 -0.198 0.10145E+04 66 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71234E+04 68 diaspore 2.87 0.73 -2.14 -0.357 0.36545E+04 69 diamond -3.10 -6.99 -3.89 -1.110 0.66337E+04 70 diopside 16.18 16.03 -0.15 -0.015 0.26332E+03 71 hedenbergite 14.21 13.36 -0.85 -0.085 0.14528E+04 74 enstatite 17.26 12.27 -5.00 -0.500 0.85328E+04 76 clinoenstatite 17.17 12.27 -4.90 -0.490 0.83644E+04 78 epidote 24.67 22.69 -1.98 -0.096 0.33859E+04 79 clinozoisite 22.81 18.83 -3.97 -0.181 0.67849E+04 80 epidote-Fe 29.84 26.54 -3.30 -0.171 0.56335E+04 81 fayalite 14.05 10.08 -3.96 -0.566 0.67669E+04 82 ferrosilite 11.15 6.93 -4.22 -0.422 0.72078E+04 86 gibbsite 4.08 0.73 -3.35 -0.478 0.57131E+04 87 glaucophane 22.97 20.79 -2.19 -0.059 0.37337E+04 88 glaucophane-Fe 17.28 12.78 -4.50 -0.122 0.76783E+04 89 graphite -3.55 -6.99 -3.44 -0.983 0.58760E+04 90 greenalite 16.14 13.55 -2.59 -0.216 0.44272E+04 93 hematite 12.57 9.18 -3.39 -0.411 0.57889E+04 94 heulandite -5.83 -7.57 -1.74 -0.079 0.29702E+04 98 jadeite 4.22 2.77 -1.44 -0.144 0.24667E+04 100 kalsilite 7.58 3.82 -3.76 -0.537 0.64226E+04 101 kaolinite -1.33 -4.84 -3.51 -0.319 0.59923E+04 104 laumontite 2.88 1.90 -0.99 -0.066 0.16848E+04 105 lawsonite 9.62 8.21 -1.41 -0.094 0.24083E+04 106 leucite 4.12 0.67 -3.45 -0.345 0.58923E+04 108 lizardite 23.24 21.56 -1.69 -0.141 0.28822E+04 110 magnetite 20.09 15.79 -4.29 -0.350 0.73301E+04 111 minnesotaite 10.39 7.24 -3.15 -0.185 0.53792E+04 115 manganosite 14.06 9.24 -4.82 -1.205 0.82299E+04 119 microcline -2.49 -2.49 0.00 0.000 0.36210E-01 123 muscovite 2.58 -1.02 -3.60 -0.212 0.61506E+04 124 paragonite 4.24 1.08 -3.16 -0.186 0.53897E+04 125 nepheline 8.34 5.93 -2.41 -0.345 0.41224E+04 137 phlogopite-Na 29.65 27.48 -2.17 -0.120 0.36981E+04 139 prehnite 19.37 18.10 -1.27 -0.075 0.21734E+04 140 prehnite-Fe 22.50 21.95 -0.54 -0.033 0.92940E+03 141 pumpellyite-Fe 46.27 43.55 -2.72 -0.060 0.46435E+04 142 pumpellyite-Mg 48.99 46.22 -2.78 -0.062 0.47386E+04 146 pyrrhotite -4.26 -7.98 -3.72 -1.241 0.63577E+04 147 pyrrhotiteFe0.875 -6.02 -9.31 -3.30 -1.213 0.56308E+04 148 pyroxmangite 7.40 6.08 -1.31 -0.263 0.22453E+04 149 pyrophyllite -6.18 -11.15 -4.98 -0.311 0.84953E+04 150 quartz -2.99 -3.15 -0.17 -0.055 0.28182E+03 154 rhodochrosite -0.98 -5.87 -4.90 -1.632 0.83589E+04 155 rhodonite 7.45 6.08 -1.36 -0.272 0.23256E+04 156 sanidine -1.28 -2.49 -1.21 -0.093 0.20678E+04 166 stilbite -7.52 -7.57 -0.04 -0.002 0.76362E+02 167 stilpnomelane-Fe 13.02 12.45 -0.57 -0.017 0.97588E+03 168 stilpnomelane-Mg 27.44 25.79 -1.65 -0.049 0.28129E+04 174 talc 16.49 15.25 -1.24 -0.073 0.21244E+04 177 tephroite 18.09 15.32 -2.76 -0.395 0.47194E+04 181 tridymite -2.63 -3.15 -0.53 -0.176 0.90179E+03 182 tremolite 47.87 47.30 -0.57 -0.015 0.97002E+03 183 ferroactinolite 38.45 33.95 -4.50 -0.122 0.76833E+04 184 troilite-low -4.41 -7.98 -3.57 -1.191 0.61005E+04 190 wairakite 3.95 1.90 -2.05 -0.121 0.35068E+04 191 walstromite 11.51 9.89 -1.62 -0.323 0.27591E+04 192 wollastonite 10.46 9.89 -0.57 -0.114 0.96949E+03 193 pseudo-wollastonite 11.00 9.89 -1.11 -0.221 0.18893E+04 194 zoisite 22.85 18.83 -4.02 -0.183 0.68590E+04 195 akaganeite 7.75 4.59 -3.17 -0.685 0.54070E+04 202 chalcedony -2.80 -3.15 -0.35 -0.117 0.60111E+03 204 montmorillonite-Ca -2.29 -6.18 -3.88 -0.240 0.66326E+04 205 montmorillonite-K -2.24 -6.27 -4.03 -0.247 0.68828E+04 206 montmorillonite-Mg -2.48 -6.80 -4.32 -0.267 0.73688E+04 207 montmorillonite-Na -2.04 -5.57 -3.54 -0.217 0.60376E+04 208 nontronite-Ca 3.21 -0.01 -3.22 -0.209 0.54993E+04 209 nontronite-H 2.53 -2.16 -4.69 -0.314 0.80111E+04 210 nontronite-K 3.34 -0.10 -3.44 -0.221 0.58727E+04 211 nontronite-Mg 3.07 -0.63 -3.70 -0.240 0.63196E+04 212 nontronite-Na 3.52 0.60 -2.92 -0.188 0.49935E+04 228 tobermorite 9.82 7.71 -2.11 -0.575 0.36005E+04 234 alabandite -0.98 -5.36 -4.39 -1.462 0.74895E+04 237 boehmite 4.41 0.73 -3.67 -0.612 0.62714E+04 239 ferrous-oxide 9.81 6.62 -3.19 -0.798 0.54520E+04 245 silica-amorphous -2.09 -3.15 -1.06 -0.354 0.18153E+04 247 an20ab80 2.02 1.33 -0.68 -0.053 0.11675E+04 248 an25ab75 2.65 1.76 -0.88 -0.068 0.15063E+04 249 an30ab70 3.28 2.19 -1.09 -0.084 0.18548E+04 250 tr.625ac.25prg.125 45.16 44.91 -0.25 -0.007 0.43516E+03 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 0.0000200 MOLES Current total amount of reactant added: 0.0004300 MOLES New total amount of reactant added: 0.0004500 MOLES Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.5508E-08 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 6 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 0.0004500 Water: Moles liquid = 0.4985E+02 kg liquid = 0.8981E+00 Moles total = 0.4985E+02 kg total = 0.8980E+00 Activity = 1.0000 Stoichiometric ionic strength = .1135891E-01 Osmotic coef. = 0.9679 True ionic strength = .2004318E-01 Chg. balance for total moles = -.5508E-08 Max. difference allowed = 0.1405E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.88975E-10 -10.0507 0.74756E-10 -10.1264 0.84019E+00 -0.0756 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.15578E-03 -3.8075 0.13009E-03 -3.8857 0.83513E+00 -0.0782 4 SO4-- 0.52424E-10 -10.2805 0.27216E-10 -10.5652 0.51914E+00 -0.2847 5 HCO3- 0.13013E-04 -4.8856 0.10884E-04 -4.9632 0.83635E+00 -0.0776 6 HS- 0.40568E-04 -4.3918 0.33884E-04 -4.4700 0.83525E+00 -0.0782 7 Al+++ 0.97880E-29 -29.0093 0.22597E-29 -29.6460 0.23086E+00 -0.6366 8 H4SiO4 0.70091E-03 -3.1543 0.70091E-03 -3.1543 0.10000E+01 0.0000 9 Ca++ 0.12070E-06 -6.9183 0.62202E-07 -7.2062 0.51533E+00 -0.2879 10 Mg++ 0.21144E-10 -10.6748 0.10846E-10 -10.9647 0.51297E+00 -0.2899 11 Fe++ 0.45136E-13 -13.3455 0.23179E-13 -13.6349 0.51353E+00 -0.2894 12 K+ 0.15651E-03 -3.8055 0.13093E-03 -3.8830 0.83655E+00 -0.0775 13 Na+ 0.19862E-01 -1.7020 0.16584E-01 -1.7803 0.83498E+00 -0.0783 14 Mn++ 0.18815E-10 -10.7255 0.96702E-11 -11.0146 0.51395E+00 -0.2891 15 F- 0.31078E-06 -6.5076 0.25900E-06 -6.5867 0.83341E+00 -0.0791 16 HPO4-- 0.45322E-07 -7.3437 0.23532E-07 -7.6283 0.51921E+00 -0.2847 18 HSiO3- 0.10483E-01 -1.9795 0.87547E-02 -2.0578 0.83513E+00 -0.0782 19 Ca(HSiO3)+ 0.14821E-07 -7.8291 0.12402E-07 -7.9065 0.83673E+00 -0.0774 20 Mg(HSiO3)+ 0.32163E-11 -11.4926 0.26912E-11 -11.5701 0.83673E+00 -0.0774 21 NaHSiO3,aq 0.23482E-02 -2.6293 0.23482E-02 -2.6293 0.10000E+01 0.0000 22 AlO+ 0.65742E-16 -16.1822 0.55009E-16 -16.2596 0.83673E+00 -0.0774 24 HAlO2,aq 0.14654E-09 -9.8340 0.14654E-09 -9.8340 0.10000E+01 0.0000 25 AlO2- 0.52053E-05 -5.2836 0.43392E-05 -5.3626 0.83362E+00 -0.0790 26 CH4,aq 0.13209E-04 -4.8791 0.13163E-04 -4.8807 0.99654E+00 -0.0015 27 C2H6,aq 0.68663E-14 -14.1633 0.68425E-14 -14.1648 0.99654E+00 -0.0015 31 CO,aq 0.18905E-15 -15.7234 0.18905E-15 -15.7234 0.10000E+01 0.0000 32 CO2,aq 0.17446E-08 -8.7583 0.17385E-08 -8.7598 0.99654E+00 -0.0015 33 CO3-2 0.24548E-04 -4.6100 0.12717E-04 -4.8956 0.51804E+00 -0.2856 34 CaCO3,aq 0.99183E-08 -8.0036 0.99183E-08 -8.0036 0.10000E+01 0.0000 35 Ca(HCO3)+ 0.20653E-10 -10.6850 0.17281E-10 -10.7624 0.83673E+00 -0.0774 36 CaCl+ 0.15651E-10 -10.8055 0.13095E-10 -10.8829 0.83673E+00 -0.0774 37 CaCl2,aq 0.40475E-15 -15.3928 0.40475E-15 -15.3928 0.10000E+01 0.0000 38 CaF+ 0.28111E-12 -12.5511 0.23521E-12 -12.6285 0.83673E+00 -0.0774 39 CaOH+ 0.70872E-07 -7.1495 0.59301E-07 -7.2269 0.83673E+00 -0.0774 40 CaSO4,aq 0.53756E-15 -15.2696 0.53756E-15 -15.2696 0.10000E+01 0.0000 41 HCl,aq 0.17821E-14 -14.7491 0.17821E-14 -14.7491 0.10000E+01 0.0000 45 HF,aq 0.13255E-12 -12.8776 0.13255E-12 -12.8776 0.10000E+01 0.0000 46 HF2- 0.13879E-19 -19.8576 0.11591E-19 -19.9359 0.83513E+00 -0.0782 48 FeCl+ 0.57042E-17 -17.2438 0.47729E-17 -17.3212 0.83673E+00 -0.0774 51 FeF+ 0.36664E-18 -18.4358 0.30678E-18 -18.5132 0.83673E+00 -0.0774 53 FeO,aq 0.16120E-09 -9.7926 0.16120E-09 -9.7926 0.10000E+01 0.0000 54 FeOH+ 0.12062E-10 -10.9186 0.10093E-10 -10.9960 0.83673E+00 -0.0774 55 HFeO2- 0.27016E-07 -7.5684 0.22562E-07 -7.6466 0.83513E+00 -0.0782 56 FeO+ 0.13828E-16 -16.8592 0.11570E-16 -16.9366 0.83673E+00 -0.0774 58 FeO2- 0.50729E-09 -9.2947 0.42365E-09 -9.3730 0.83513E+00 -0.0782 59 HFeO2,aq 0.40280E-11 -11.3949 0.40280E-11 -11.3949 0.10000E+01 0.0000 60 H2,aq 0.43438E-05 -5.3621 0.43288E-05 -5.3636 0.99654E+00 -0.0015 61 KCl,aq 0.30871E-09 -9.5104 0.30871E-09 -9.5104 0.10000E+01 0.0000 63 KOH,aq 0.74796E-06 -6.1261 0.74796E-06 -6.1261 0.10000E+01 0.0000 64 KSO4- 0.66211E-13 -13.1791 0.55294E-13 -13.2573 0.83513E+00 -0.0782 65 MgCO3,aq 0.43350E-12 -12.3630 0.43350E-12 -12.3630 0.10000E+01 0.0000 66 Mg(HCO3)+ 0.36798E-14 -14.4342 0.30790E-14 -14.5116 0.83673E+00 -0.0774 67 MgCl+ 0.24734E-14 -14.6067 0.20696E-14 -14.6841 0.83673E+00 -0.0774 68 MgF+ 0.18157E-15 -15.7409 0.15193E-15 -15.8184 0.83673E+00 -0.0774 69 MgOH+ 0.68382E-10 -10.1651 0.57217E-10 -10.2425 0.83673E+00 -0.0774 71 MnF+ 0.50419E-16 -16.2974 0.42187E-16 -16.3748 0.83673E+00 -0.0774 72 MnO,aq 0.17920E-08 -8.7467 0.17920E-08 -8.7467 0.10000E+01 0.0000 73 MnOH+ 0.46749E-09 -9.3302 0.39116E-09 -9.4076 0.83673E+00 -0.0774 74 MnO2-2 0.20543E-10 -10.6873 0.10642E-10 -10.9730 0.51804E+00 -0.2856 75 HMnO2- 0.20870E-09 -9.6805 0.17429E-09 -9.7587 0.83513E+00 -0.0782 78 MnCl+ 0.92585E-14 -14.0335 0.77469E-14 -14.1109 0.83673E+00 -0.0774 79 MnSO4,aq 0.75978E-19 -19.1193 0.75978E-19 -19.1193 0.10000E+01 0.0000 80 NaCl,aq 0.71499E-06 -6.1457 0.71499E-06 -6.1457 0.10000E+01 0.0000 81 NaF,aq 0.10056E-08 -8.9976 0.10056E-08 -8.9976 0.10000E+01 0.0000 82 NaOH,aq 0.95314E-04 -4.0208 0.95314E-04 -4.0208 0.10000E+01 0.0000 84 OH- 0.92714E-02 -2.0329 0.77288E-02 -2.1119 0.83362E+00 -0.0790 89 HPO3-2 0.61278E-15 -15.2127 0.31745E-15 -15.4983 0.51804E+00 -0.2856 91 H2PO3- 0.56982E-19 -19.2443 0.47588E-19 -19.3225 0.83513E+00 -0.0782 92 H3PO4,aq 0.91975E-18 -18.0363 0.91975E-18 -18.0363 0.10000E+01 0.0000 93 H2PO4- 0.38821E-10 -10.4109 0.32452E-10 -10.4888 0.83592E+00 -0.0778 94 PO4-3 0.10592E-08 -8.9750 0.25683E-09 -9.5904 0.24248E+00 -0.6153 98 HP2O7-3 0.95442E-18 -18.0203 0.22056E-18 -18.6565 0.23109E+00 -0.6362 99 P2O7-4 0.91527E-17 -17.0385 0.70483E-18 -18.1519 0.77009E-01 -1.1135 100 H2S,aq 0.78559E-08 -8.1048 0.78287E-08 -8.1063 0.99654E+00 -0.0015 101 S2-2 0.11345E-13 -13.9452 0.58771E-14 -14.2308 0.51804E+00 -0.2856 107 SO3-2 0.29131E-16 -16.5356 0.15309E-16 -16.8150 0.52554E+00 -0.2794 108 HSO3- 0.85805E-19 -19.0665 0.71658E-19 -19.1447 0.83513E+00 -0.0782 109 HSO4- 0.23410E-17 -17.6306 0.19607E-17 -17.7076 0.83755E+00 -0.0770 Charge balance for all species = -.6133E-08 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.8897530E-10 -.2224528E-01 -.2238291E+02 0.0000 2 H2O 0.1000000E+01 0.5550481E+02 0.9981967E+06 0.0000 3 Cl- 0.1557763E-03 0.1564916E-03 0.5538447E+01 6.2406 4 SO4-- 0.5242436E-10 -.1429442E-04 -.1370756E+01 9.6875 5 HCO3- 0.1301334E-04 0.5078156E-04 0.3093159E+01 5.1631 6 HS- 0.4056775E-04 0.5487008E-04 0.1811507E+01 5.6564 7 Al+++ 0.9788018E-29 0.5205417E-05 0.1402057E+00 0.7331 8 H4SiO4 0.7009052E-03 0.1353215E-01 0.1298385E+04 -3.1543 9 Ca++ 0.1207035E-06 0.2163515E-06 0.8655855E-02 13.0465 10 Mg++ 0.2114376E-10 0.9318205E-10 0.2261502E-05 9.2880 11 Fe++ 0.4513623E-13 0.2770085E-07 0.1544319E-02 6.6178 12 K+ 0.1565119E-03 0.1572601E-03 0.6138491E+01 6.2434 13 Na+ 0.1986162E-01 0.2230586E-01 0.5119154E+03 8.3460 14 Mn++ 0.1881533E-10 0.2507553E-08 0.1375204E-03 9.2381 15 F- 0.3107764E-06 0.3117824E-06 0.5912940E-02 3.5397 16 HPO4-- 0.4532217E-07 0.4642016E-07 0.4447611E-02 12.6244 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.1997809E-01 -.1997764E-01 -.4428173E-06 0.0000000E+00 2 H2O 0.4984678E+02 0.4984678E+02 -.4002090E-06 0.0000000E+00 3 Cl- 0.1405392E-03 0.1405392E-03 0.0000000E+00 0.0000000E+00 4 SO4-- -.1283631E-04 -.1283727E-04 0.9643973E-09 0.0000000E+00 5 HCO3- 0.4560500E-04 0.4560500E-04 0.0000000E+00 0.0000000E+00 6 HS- 0.4927578E-04 0.4927674E-04 -.9643973E-09 0.0000000E+00 7 Al+++ 0.4775352E-05 0.4674788E-05 0.1005636E-06 0.0000000E+00 8 H4SiO4 0.1215302E-01 0.1215271E-01 0.3110499E-06 0.0000000E+00 9 Ca++ 0.2080835E-06 0.1942971E-06 0.1378637E-07 0.0000000E+00 10 Mg++ 0.8368328E-10 0.8368328E-10 0.0000000E+00 0.0000000E+00 11 Fe++ 0.3259227E-07 0.2487709E-07 0.7715178E-08 0.0000000E+00 12 K+ 0.1412294E-03 0.1412294E-03 0.0000000E+00 0.0000000E+00 13 Na+ 0.2003215E-01 0.2003205E-01 0.9908785E-07 0.0000000E+00 14 Mn++ 0.2251939E-08 0.2251939E-08 0.0000000E+00 0.0000000E+00 15 F- 0.2800000E-06 0.2800000E-06 0.0000000E+00 0.0000000E+00 16 HPO4-- 0.4168819E-07 0.4168819E-07 0.0000000E+00 0.0000000E+00 Chg. balance for solid moles: 0.1323E-22 Mass of aqueous solution: 0.899627E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 0.0004500 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 0.9909E-07 -7.004 0.2598E-04 -4.585 91.89 0.9974E-05 andradite 0.3858E-08 -8.414 0.1960E-05 -5.708 6.933 0.5093E-06 grossular 0.7379E-09 -9.132 0.3324E-06 -6.478 1.175 0.9248E-07 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8394E+00 0.8394E+00 1.0000 -0.076 grossular 0.1606E+00 0.1606E+00 1.0000 -0.794 Solid products produced: Mass = 0.000028 g Volume = 0.000011 cm3 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.0004500 moles log = -3.3468 Original solution: 1000.0103000 g Original solution / Rock added: 2222245.11 (Water/Rock Ratio), log = 6.3468 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0455 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9763E+00 0.9856 0.1006E+01 0.1021E+01 CO2,gas 0.1767E-06 1.0069 0.1860E-06 0.1847E-06 CH4,gas 0.1831E-01 1.0123 0.1937E-01 0.1914E-01 H2,gas 0.5433E-02 1.0006 0.5683E-02 0.5680E-02 H2S,gas 0.2067E-06 0.9959 0.2152E-06 0.2161E-06 S2,gas 0.5148E-28 1.0000 0.5382E-28 0.5382E-28 CO,gas 0.2695E-12 1.0000 0.2817E-12 0.2817E-12 SO3,gas 0.5501E-46 1.0000 0.5751E-46 0.5751E-46 SO2,gas 0.1216E-25 1.0000 0.1272E-25 0.1272E-25 HF,gas 0.3113E-15 1.0000 0.3254E-15 0.3254E-15 HCl,gas 0.3008E-17 1.0000 0.3145E-17 0.3145E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 17 albite -0.38 -0.38 0.00 0.000 -0.94784E-12 23 andradite 39.01 39.01 0.00 0.000 -0.12132E-10 24 grossular 32.73 32.73 0.00 0.000 0.12132E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -15.09 -8.43 -2.810 0.14393E+05 -6.730 3 CH4,gas 4.54 1.13 -3.41 -0.853 0.58254E+04 -1.713 4 H2,gas 8.00 4.06 -3.94 -2.254 0.67349E+04 -2.245 5 H2S,gas -6.23 -14.60 -8.37 -4.183 0.14285E+05 -6.667 6 S2,gas -7.34 -37.30 -29.97 -4.610 0.51170E+05 -28.269 7 CO,gas 3.21 -11.03 -14.25 -4.384 0.24330E+05 -12.550 8 SO3,gas 17.12 -30.82 -47.94 -11.985 0.81855E+05 -46.240 9 SO2,gas 0.83 -26.76 -27.59 -7.359 0.47117E+05 -25.896 10 HF,gas 0.47 -16.71 -17.19 -8.593 0.29345E+05 -15.488 11 HCl,gas 5.19 -14.01 -19.20 -9.601 0.32786E+05 -17.502 12 acmite 7.71 6.63 -1.08 -0.112 0.18479E+04 16 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 20 spessartine 24.46 19.72 -4.74 -0.237 0.80929E+04 21 analcite 3.32 2.77 -0.55 -0.061 0.94148E+03 27 annite 20.12 17.37 -2.76 -0.153 0.47067E+04 28 phlogopite 27.06 25.38 -1.69 -0.094 0.28808E+04 30 anorthite 12.71 8.20 -4.51 -0.347 0.76943E+04 33 apatite-OH -18.15 -18.41 -0.26 -0.020 0.43902E+03 34 apatite-F -34.30 -35.12 -0.82 -0.069 0.14047E+04 38 aragonite 0.97 -2.04 -3.01 -1.003 0.51388E+04 39 brucite 12.57 9.29 -3.28 -0.656 0.56015E+04 40 calcite 0.81 -2.04 -2.85 -0.952 0.48746E+04 41 carnegieite-low 9.02 5.92 -3.10 -0.443 0.52906E+04 42 carnegieite-high 10.09 5.92 -4.17 -0.595 0.71176E+04 43 carpholite-Mg 8.58 4.45 -4.14 -0.276 0.70631E+04 44 carpholite-Fe 6.71 1.78 -4.94 -0.329 0.84303E+04 45 celadonite 5.34 3.65 -1.69 -0.100 0.28933E+04 46 celadonite-Fe 3.88 0.98 -2.90 -0.171 0.49510E+04 47 chrysotile 23.89 21.56 -2.34 -0.195 0.39906E+04 49 clinochlore 39.07 38.44 -0.63 -0.020 0.10696E+04 50 daphnite 28.97 25.09 -3.87 -0.121 0.66131E+04 52 chlorite-Al-free 47.17 43.11 -4.06 -0.169 0.69363E+04 54 chloritoid-Fe 9.17 4.93 -4.24 -0.283 0.72464E+04 55 chloritoid-Mn 11.40 7.55 -3.85 -0.257 0.65756E+04 57 coesite -2.38 -3.15 -0.78 -0.259 0.13289E+04 64 cristobalite -2.56 -3.15 -0.59 -0.198 0.10142E+04 66 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71234E+04 68 diaspore 2.87 0.73 -2.14 -0.357 0.36550E+04 69 diamond -3.10 -6.98 -3.88 -1.108 0.66189E+04 70 diopside 16.18 16.03 -0.16 -0.016 0.26559E+03 71 hedenbergite 14.21 13.36 -0.85 -0.085 0.14559E+04 74 enstatite 17.26 12.27 -5.00 -0.500 0.85333E+04 76 clinoenstatite 17.17 12.27 -4.90 -0.490 0.83649E+04 78 epidote 24.67 22.69 -1.98 -0.096 0.33869E+04 79 clinozoisite 22.81 18.83 -3.98 -0.181 0.67901E+04 80 epidote-Fe 29.84 26.54 -3.30 -0.171 0.56304E+04 81 fayalite 14.05 10.08 -3.96 -0.566 0.67692E+04 82 ferrosilite 11.15 6.93 -4.22 -0.422 0.72099E+04 86 gibbsite 4.08 0.73 -3.35 -0.478 0.57135E+04 87 glaucophane 22.97 20.79 -2.19 -0.059 0.37347E+04 88 glaucophane-Fe 17.28 12.78 -4.50 -0.122 0.76816E+04 89 graphite -3.55 -6.98 -3.43 -0.981 0.58611E+04 90 greenalite 16.14 13.54 -2.59 -0.216 0.44305E+04 93 hematite 12.57 9.18 -3.39 -0.410 0.57814E+04 94 heulandite -5.83 -7.57 -1.74 -0.079 0.29717E+04 98 jadeite 4.22 2.77 -1.44 -0.144 0.24670E+04 100 kalsilite 7.58 3.82 -3.76 -0.537 0.64231E+04 101 kaolinite -1.33 -4.84 -3.51 -0.319 0.59927E+04 104 laumontite 2.88 1.90 -0.99 -0.066 0.16871E+04 105 lawsonite 9.62 8.20 -1.41 -0.094 0.24110E+04 106 leucite 4.12 0.67 -3.45 -0.345 0.58926E+04 108 lizardite 23.24 21.56 -1.69 -0.141 0.28832E+04 110 magnetite 20.09 15.80 -4.29 -0.350 0.73240E+04 111 minnesotaite 10.39 7.24 -3.15 -0.185 0.53821E+04 115 manganosite 14.06 9.24 -4.82 -1.205 0.82300E+04 119 microcline -2.49 -2.49 0.00 0.000 0.37903E-01 123 muscovite 2.58 -1.02 -3.60 -0.212 0.61516E+04 124 paragonite 4.24 1.08 -3.16 -0.186 0.53906E+04 125 nepheline 8.34 5.92 -2.41 -0.345 0.41229E+04 137 phlogopite-Na 29.65 27.48 -2.17 -0.120 0.36996E+04 139 prehnite 19.37 18.10 -1.28 -0.075 0.21782E+04 140 prehnite-Fe 22.50 21.95 -0.54 -0.033 0.92997E+03 141 pumpellyite-Fe 46.27 43.54 -2.73 -0.061 0.46547E+04 142 pumpellyite-Mg 48.99 46.21 -2.78 -0.062 0.47491E+04 146 pyrrhotite -4.26 -7.98 -3.72 -1.239 0.63488E+04 147 pyrrhotiteFe0.875 -6.02 -9.31 -3.29 -1.211 0.56205E+04 148 pyroxmangite 7.40 6.08 -1.31 -0.263 0.22451E+04 149 pyrophyllite -6.18 -11.15 -4.98 -0.311 0.84953E+04 150 quartz -2.99 -3.15 -0.16 -0.055 0.28157E+03 154 rhodochrosite -0.98 -5.85 -4.88 -1.625 0.83241E+04 155 rhodonite 7.45 6.08 -1.36 -0.272 0.23254E+04 156 sanidine -1.28 -2.49 -1.21 -0.093 0.20678E+04 166 stilbite -7.52 -7.57 -0.05 -0.002 0.77864E+02 167 stilpnomelane-Fe 13.02 12.44 -0.57 -0.017 0.98142E+03 168 stilpnomelane-Mg 27.44 25.79 -1.65 -0.049 0.28144E+04 174 talc 16.49 15.25 -1.24 -0.073 0.21249E+04 177 tephroite 18.09 15.32 -2.76 -0.395 0.47192E+04 181 tridymite -2.63 -3.15 -0.53 -0.176 0.90155E+03 182 tremolite 47.87 47.30 -0.57 -0.015 0.97506E+03 183 ferroactinolite 38.45 33.95 -4.51 -0.122 0.76923E+04 184 troilite-low -4.41 -7.98 -3.57 -1.189 0.60916E+04 190 wairakite 3.95 1.90 -2.06 -0.121 0.35090E+04 191 walstromite 11.51 9.89 -1.62 -0.323 0.27611E+04 192 wollastonite 10.46 9.89 -0.57 -0.114 0.97151E+03 193 pseudo-wollastonite 11.00 9.89 -1.11 -0.222 0.18913E+04 194 zoisite 22.85 18.83 -4.02 -0.183 0.68642E+04 195 akaganeite 7.75 4.59 -3.16 -0.684 0.54033E+04 202 chalcedony -2.80 -3.15 -0.35 -0.117 0.60087E+03 204 montmorillonite-Ca -2.29 -6.18 -3.88 -0.240 0.66329E+04 205 montmorillonite-K -2.24 -6.27 -4.03 -0.247 0.68828E+04 206 montmorillonite-Mg -2.48 -6.80 -4.32 -0.267 0.73688E+04 207 montmorillonite-Na -2.04 -5.57 -3.54 -0.217 0.60377E+04 208 nontronite-Ca 3.21 0.00 -3.22 -0.209 0.54915E+04 209 nontronite-H 2.53 -2.15 -4.69 -0.314 0.80029E+04 210 nontronite-K 3.34 -0.09 -3.43 -0.220 0.58646E+04 211 nontronite-Mg 3.07 -0.62 -3.70 -0.240 0.63115E+04 212 nontronite-Na 3.52 0.60 -2.92 -0.187 0.49855E+04 228 tobermorite 9.82 7.71 -2.11 -0.576 0.36022E+04 234 alabandite -0.98 -5.36 -4.38 -1.460 0.74793E+04 237 boehmite 4.41 0.73 -3.67 -0.612 0.62719E+04 239 ferrous-oxide 9.81 6.62 -3.19 -0.798 0.54533E+04 245 silica-amorphous -2.09 -3.15 -1.06 -0.354 0.18150E+04 247 an20ab80 2.02 1.33 -0.68 -0.053 0.11680E+04 248 an25ab75 2.65 1.76 -0.88 -0.068 0.15070E+04 249 an30ab70 3.28 2.19 -1.09 -0.084 0.18556E+04 250 tr.625ac.25prg.125 45.16 44.91 -0.26 -0.007 0.44140E+03 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 0.0000200 MOLES Current total amount of reactant added: 0.0004500 MOLES New total amount of reactant added: 0.0004700 MOLES Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.5508E-08 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 6 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 0.0004700 Water: Moles liquid = 0.4985E+02 kg liquid = 0.8981E+00 Moles total = 0.4985E+02 kg total = 0.8980E+00 Activity = 1.0000 Stoichiometric ionic strength = .1136019E-01 Osmotic coef. = 0.9678 True ionic strength = .2004436E-01 Chg. balance for total moles = -.5508E-08 Max. difference allowed = 0.1407E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.89007E-10 -10.0506 0.74782E-10 -10.1262 0.84018E+00 -0.0756 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.15591E-03 -3.8071 0.13020E-03 -3.8854 0.83513E+00 -0.0782 4 SO4-- 0.55934E-10 -10.2523 0.29037E-10 -10.5370 0.51913E+00 -0.2847 5 HCO3- 0.13606E-04 -4.8663 0.11379E-04 -4.9439 0.83635E+00 -0.0776 6 HS- 0.41109E-04 -4.3861 0.34336E-04 -4.4642 0.83525E+00 -0.0782 7 Al+++ 0.97925E-29 -29.0091 0.22606E-29 -29.6458 0.23085E+00 -0.6367 8 H4SiO4 0.70114E-03 -3.1542 0.70114E-03 -3.1542 0.10000E+01 0.0000 9 Ca++ 0.12043E-06 -6.9193 0.62058E-07 -7.2072 0.51532E+00 -0.2879 10 Mg++ 0.21145E-10 -10.6748 0.10846E-10 -10.9647 0.51296E+00 -0.2899 11 Fe++ 0.45098E-13 -13.3458 0.23159E-13 -13.6353 0.51352E+00 -0.2894 12 K+ 0.15651E-03 -3.8055 0.13093E-03 -3.8830 0.83655E+00 -0.0775 13 Na+ 0.19862E-01 -1.7020 0.16584E-01 -1.7803 0.83498E+00 -0.0783 14 Mn++ 0.18828E-10 -10.7252 0.96767E-11 -11.0143 0.51395E+00 -0.2891 15 F- 0.31966E-06 -6.4953 0.26640E-06 -6.5745 0.83340E+00 -0.0791 16 HPO4-- 0.45322E-07 -7.3437 0.23532E-07 -7.6283 0.51921E+00 -0.2847 18 HSiO3- 0.10483E-01 -1.9795 0.87545E-02 -2.0578 0.83513E+00 -0.0782 19 Ca(HSiO3)+ 0.14787E-07 -7.8301 0.12373E-07 -7.9075 0.83673E+00 -0.0774 20 Mg(HSiO3)+ 0.32164E-11 -11.4926 0.26912E-11 -11.5700 0.83673E+00 -0.0774 21 NaHSiO3,aq 0.23482E-02 -2.6293 0.23482E-02 -2.6293 0.10000E+01 0.0000 22 AlO+ 0.65724E-16 -16.1823 0.54993E-16 -16.2597 0.83673E+00 -0.0774 24 HAlO2,aq 0.14645E-09 -9.8343 0.14645E-09 -9.8343 0.10000E+01 0.0000 25 AlO2- 0.52002E-05 -5.2840 0.43350E-05 -5.3630 0.83362E+00 -0.0790 26 CH4,aq 0.13116E-04 -4.8822 0.13071E-04 -4.8837 0.99654E+00 -0.0015 27 C2H6,aq 0.68590E-14 -14.1637 0.68353E-14 -14.1652 0.99654E+00 -0.0015 31 CO,aq 0.19518E-15 -15.7096 0.19518E-15 -15.7096 0.10000E+01 0.0000 32 CO2,aq 0.18247E-08 -8.7388 0.18183E-08 -8.7403 0.99654E+00 -0.0015 33 CO3-2 0.25657E-04 -4.5908 0.13291E-04 -4.8764 0.51803E+00 -0.2856 34 CaCO3,aq 0.10342E-07 -7.9854 0.10342E-07 -7.9854 0.10000E+01 0.0000 35 Ca(HCO3)+ 0.21543E-10 -10.6667 0.18026E-10 -10.7441 0.83673E+00 -0.0774 36 CaCl+ 0.15628E-10 -10.8061 0.13076E-10 -10.8835 0.83673E+00 -0.0774 37 CaCl2,aq 0.40449E-15 -15.3931 0.40449E-15 -15.3931 0.10000E+01 0.0000 38 CaF+ 0.28847E-12 -12.5399 0.24137E-12 -12.6173 0.83673E+00 -0.0774 39 CaOH+ 0.70683E-07 -7.1507 0.59143E-07 -7.2281 0.83673E+00 -0.0774 40 CaSO4,aq 0.57222E-15 -15.2424 0.57222E-15 -15.2424 0.10000E+01 0.0000 41 HCl,aq 0.17842E-14 -14.7485 0.17842E-14 -14.7485 0.10000E+01 0.0000 45 HF,aq 0.13638E-12 -12.8652 0.13638E-12 -12.8652 0.10000E+01 0.0000 46 HF2- 0.14688E-19 -19.8330 0.12267E-19 -19.9113 0.83513E+00 -0.0782 48 FeCl+ 0.57040E-17 -17.2438 0.47727E-17 -17.3212 0.83673E+00 -0.0774 51 FeF+ 0.37679E-18 -18.4239 0.31527E-18 -18.5013 0.83673E+00 -0.0774 53 FeO,aq 0.16095E-09 -9.7933 0.16095E-09 -9.7933 0.10000E+01 0.0000 54 FeOH+ 0.12047E-10 -10.9191 0.10080E-10 -10.9965 0.83673E+00 -0.0774 55 HFeO2- 0.26965E-07 -7.5692 0.22519E-07 -7.6475 0.83513E+00 -0.0782 56 FeO+ 0.13901E-16 -16.8569 0.11632E-16 -16.9344 0.83673E+00 -0.0774 58 FeO2- 0.50961E-09 -9.2928 0.42559E-09 -9.3710 0.83513E+00 -0.0782 59 HFeO2,aq 0.40479E-11 -11.3928 0.40479E-11 -11.3928 0.10000E+01 0.0000 60 H2,aq 0.42878E-05 -5.3678 0.42730E-05 -5.3693 0.99654E+00 -0.0015 61 KCl,aq 0.30897E-09 -9.5101 0.30897E-09 -9.5101 0.10000E+01 0.0000 63 KOH,aq 0.74770E-06 -6.1263 0.74770E-06 -6.1263 0.10000E+01 0.0000 64 KSO4- 0.70643E-13 -13.1509 0.58996E-13 -13.2292 0.83513E+00 -0.0782 65 MgCO3,aq 0.45310E-12 -12.3438 0.45310E-12 -12.3438 0.10000E+01 0.0000 66 Mg(HCO3)+ 0.38475E-14 -14.4148 0.32193E-14 -14.4922 0.83673E+00 -0.0774 67 MgCl+ 0.24756E-14 -14.6063 0.20714E-14 -14.6837 0.83673E+00 -0.0774 68 MgF+ 0.18677E-15 -15.7287 0.15627E-15 -15.8061 0.83673E+00 -0.0774 69 MgOH+ 0.68361E-10 -10.1652 0.57200E-10 -10.2426 0.83673E+00 -0.0774 71 MnF+ 0.51894E-16 -16.2849 0.43421E-16 -16.3623 0.83673E+00 -0.0774 72 MnO,aq 0.17919E-08 -8.7467 0.17919E-08 -8.7467 0.10000E+01 0.0000 73 MnOH+ 0.46764E-09 -9.3301 0.39128E-09 -9.4075 0.83673E+00 -0.0774 74 MnO2-2 0.20528E-10 -10.6877 0.10634E-10 -10.9733 0.51803E+00 -0.2856 75 HMnO2- 0.20862E-09 -9.6806 0.17422E-09 -9.7589 0.83513E+00 -0.0782 78 MnCl+ 0.92724E-14 -14.0328 0.77585E-14 -14.1102 0.83673E+00 -0.0774 79 MnSO4,aq 0.81118E-19 -19.0909 0.81118E-19 -19.0909 0.10000E+01 0.0000 80 NaCl,aq 0.71559E-06 -6.1453 0.71559E-06 -6.1453 0.10000E+01 0.0000 81 NaF,aq 0.10343E-08 -8.9853 0.10343E-08 -8.9853 0.10000E+01 0.0000 82 NaOH,aq 0.95281E-04 -4.0210 0.95281E-04 -4.0210 0.10000E+01 0.0000 84 OH- 0.92681E-02 -2.0330 0.77261E-02 -2.1120 0.83362E+00 -0.0790 89 HPO3-2 0.60489E-15 -15.2183 0.31335E-15 -15.5040 0.51803E+00 -0.2856 91 H2PO3- 0.56267E-19 -19.2497 0.46990E-19 -19.3280 0.83513E+00 -0.0782 92 H3PO4,aq 0.92039E-18 -18.0360 0.92039E-18 -18.0360 0.10000E+01 0.0000 93 H2PO4- 0.38835E-10 -10.4108 0.32463E-10 -10.4886 0.83592E+00 -0.0778 94 PO4-3 0.10588E-08 -8.9752 0.25674E-09 -9.5905 0.24247E+00 -0.6153 98 HP2O7-3 0.95477E-18 -18.0201 0.22063E-18 -18.6563 0.23108E+00 -0.6362 99 P2O7-4 0.91531E-17 -17.0384 0.70482E-18 -18.1519 0.77004E-01 -1.1135 100 H2S,aq 0.79635E-08 -8.0989 0.79359E-08 -8.1004 0.99654E+00 -0.0015 101 S2-2 0.11802E-13 -13.9281 0.61137E-14 -14.2137 0.51803E+00 -0.2856 107 SO3-2 0.30681E-16 -16.5131 0.16124E-16 -16.7925 0.52553E+00 -0.2794 108 HSO3- 0.90400E-19 -19.0438 0.75496E-19 -19.1221 0.83513E+00 -0.0782 109 HSO4- 0.24986E-17 -17.6023 0.20927E-17 -17.6793 0.83754E+00 -0.0770 Charge balance for all species = -.6133E-08 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.8900686E-10 -.2224285E-01 -.2238046E+02 0.0000 2 H2O 0.1000000E+01 0.5550481E+02 0.9981966E+06 0.0000 3 Cl- 0.1559070E-03 0.1566229E-03 0.5543095E+01 6.2408 4 SO4-- 0.5593440E-10 -.1418808E-04 -.1360559E+01 9.7154 5 HCO3- 0.1360601E-04 0.5239167E-04 0.3191233E+01 5.1823 6 HS- 0.4110879E-04 0.5530489E-04 0.1825862E+01 5.6620 7 Al+++ 0.9792468E-29 0.5200313E-05 0.1400682E+00 0.7328 8 H4SiO4 0.7011354E-03 0.1353213E-01 0.1298383E+04 -3.1542 9 Ca++ 0.1204264E-06 0.2162766E-06 0.8652857E-02 13.0452 10 Mg++ 0.2114493E-10 0.9318201E-10 0.2261501E-05 9.2877 11 Fe++ 0.4509793E-13 0.2765127E-07 0.1541555E-02 6.6171 12 K+ 0.1565121E-03 0.1572601E-03 0.6138488E+01 6.2432 13 Na+ 0.1986169E-01 0.2230585E-01 0.5119150E+03 8.3459 14 Mn++ 0.1882814E-10 0.2507552E-08 0.1375203E-03 9.2381 15 F- 0.3196556E-06 0.3206903E-06 0.6081878E-02 3.5517 16 HPO4-- 0.4532249E-07 0.4642014E-07 0.4447609E-02 12.6241 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.1997593E-01 -.1997547E-01 -.4613610E-06 0.0000000E+00 2 H2O 0.4984679E+02 0.4984679E+02 -.4185562E-06 0.0000000E+00 3 Cl- 0.1406572E-03 0.1406572E-03 0.0000000E+00 0.0000000E+00 4 SO4-- -.1274081E-04 -.1274178E-04 0.9699620E-09 0.0000000E+00 5 HCO3- 0.4705100E-04 0.4705100E-04 0.0000000E+00 0.0000000E+00 6 HS- 0.4966628E-04 0.4966725E-04 -.9699620E-09 0.0000000E+00 7 Al+++ 0.4775352E-05 0.4670207E-05 0.1051451E-06 0.0000000E+00 8 H4SiO4 0.1215302E-01 0.1215270E-01 0.3248608E-06 0.0000000E+00 9 Ca++ 0.2080835E-06 0.1942299E-06 0.1385359E-07 0.0000000E+00 10 Mg++ 0.8368328E-10 0.8368328E-10 0.0000000E+00 0.0000000E+00 11 Fe++ 0.3259227E-07 0.2483257E-07 0.7759696E-08 0.0000000E+00 12 K+ 0.1412294E-03 0.1412294E-03 0.0000000E+00 0.0000000E+00 13 Na+ 0.2003215E-01 0.2003205E-01 0.1036691E-06 0.0000000E+00 14 Mn++ 0.2251939E-08 0.2251939E-08 0.0000000E+00 0.0000000E+00 15 F- 0.2880000E-06 0.2880000E-06 0.0000000E+00 0.0000000E+00 16 HPO4-- 0.4168819E-07 0.4168819E-07 0.0000000E+00 0.0000000E+00 Chg. balance for solid moles: 0.0000E+00 Mass of aqueous solution: 0.899627E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 0.0004700 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 0.1037E-06 -6.984 0.2718E-04 -4.566 92.19 0.1044E-04 andradite 0.3880E-08 -8.411 0.1972E-05 -5.705 6.686 0.5123E-06 grossular 0.7380E-09 -9.132 0.3324E-06 -6.478 1.127 0.9250E-07 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8402E+00 0.8402E+00 1.0000 -0.076 grossular 0.1598E+00 0.1598E+00 1.0000 -0.796 Solid products produced: Mass = 0.000029 g Volume = 0.000011 cm3 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.0004700 moles log = -3.3279 Original solution: 1000.0103000 g Original solution / Rock added: 2127681.49 (Water/Rock Ratio), log = 6.3279 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0453 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9765E+00 0.9856 0.1006E+01 0.1021E+01 CO2,gas 0.1849E-06 1.0069 0.1945E-06 0.1932E-06 CH4,gas 0.1818E-01 1.0123 0.1924E-01 0.1900E-01 H2,gas 0.5364E-02 1.0006 0.5610E-02 0.5607E-02 H2S,gas 0.2096E-06 0.9959 0.2182E-06 0.2190E-06 S2,gas 0.5430E-28 1.0000 0.5676E-28 0.5676E-28 CO,gas 0.2783E-12 1.0000 0.2909E-12 0.2909E-12 SO3,gas 0.5874E-46 1.0000 0.6140E-46 0.6140E-46 SO2,gas 0.1282E-25 1.0000 0.1340E-25 0.1340E-25 HF,gas 0.3204E-15 1.0000 0.3349E-15 0.3349E-15 HCl,gas 0.3012E-17 1.0000 0.3148E-17 0.3148E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 17 albite -0.38 -0.38 0.00 0.000 -0.94784E-12 23 andradite 39.01 39.01 0.00 0.000 -0.12132E-10 24 grossular 32.73 32.73 0.00 0.000 -0.12132E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -15.07 -8.41 -2.803 0.14360E+05 -6.711 3 CH4,gas 4.54 1.13 -3.41 -0.854 0.58306E+04 -1.716 4 H2,gas 8.00 4.05 -3.95 -2.257 0.67445E+04 -2.251 5 H2S,gas -6.23 -14.59 -8.36 -4.180 0.14275E+05 -6.661 6 S2,gas -7.34 -37.28 -29.94 -4.607 0.51130E+05 -28.246 7 CO,gas 3.21 -11.02 -14.24 -4.380 0.24306E+05 -12.536 8 SO3,gas 17.12 -30.79 -47.91 -11.978 0.81806E+05 -46.212 9 SO2,gas 0.83 -26.74 -27.57 -7.352 0.47078E+05 -25.873 10 HF,gas 0.47 -16.70 -17.17 -8.587 0.29324E+05 -15.475 11 HCl,gas 5.19 -14.01 -19.20 -9.600 0.32785E+05 -17.502 12 acmite 7.71 6.63 -1.08 -0.112 0.18440E+04 16 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 20 spessartine 24.46 19.72 -4.74 -0.237 0.80932E+04 21 analcite 3.32 2.77 -0.55 -0.061 0.94172E+03 27 annite 20.12 17.36 -2.76 -0.153 0.47102E+04 28 phlogopite 27.06 25.38 -1.69 -0.094 0.28823E+04 30 anorthite 12.71 8.20 -4.51 -0.347 0.76970E+04 33 apatite-OH -18.15 -18.42 -0.26 -0.020 0.44866E+03 34 apatite-F -34.30 -35.12 -0.82 -0.068 0.13932E+04 38 aragonite 0.97 -2.02 -2.99 -0.997 0.51077E+04 39 brucite 12.57 9.29 -3.28 -0.656 0.56020E+04 40 calcite 0.81 -2.02 -2.84 -0.946 0.48435E+04 41 carnegieite-low 9.02 5.92 -3.10 -0.443 0.52911E+04 42 carnegieite-high 10.09 5.92 -4.17 -0.596 0.71181E+04 43 carpholite-Mg 8.58 4.44 -4.14 -0.276 0.70640E+04 44 carpholite-Fe 6.71 1.77 -4.94 -0.329 0.84319E+04 45 celadonite 5.34 3.65 -1.69 -0.100 0.28935E+04 46 celadonite-Fe 3.88 0.98 -2.90 -0.171 0.49519E+04 47 chrysotile 23.89 21.55 -2.34 -0.195 0.39916E+04 49 clinochlore 39.07 38.44 -0.63 -0.020 0.10723E+04 50 daphnite 28.97 25.09 -3.88 -0.121 0.66191E+04 52 chlorite-Al-free 47.17 43.11 -4.06 -0.169 0.69383E+04 54 chloritoid-Fe 9.17 4.93 -4.25 -0.283 0.72483E+04 55 chloritoid-Mn 11.40 7.55 -3.85 -0.257 0.65763E+04 57 coesite -2.38 -3.15 -0.78 -0.259 0.13286E+04 64 cristobalite -2.56 -3.15 -0.59 -0.198 0.10140E+04 66 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71234E+04 68 diaspore 2.87 0.73 -2.14 -0.357 0.36555E+04 69 diamond -3.10 -6.97 -3.87 -1.105 0.66048E+04 70 diopside 16.18 16.02 -0.16 -0.016 0.26783E+03 71 hedenbergite 14.21 13.35 -0.85 -0.085 0.14588E+04 74 enstatite 17.26 12.27 -5.00 -0.500 0.85338E+04 76 clinoenstatite 17.17 12.27 -4.90 -0.490 0.83654E+04 78 epidote 24.67 22.69 -1.98 -0.096 0.33880E+04 79 clinozoisite 22.81 18.83 -3.98 -0.181 0.67953E+04 80 epidote-Fe 29.84 26.55 -3.30 -0.171 0.56273E+04 81 fayalite 14.05 10.08 -3.97 -0.567 0.67713E+04 82 ferrosilite 11.15 6.93 -4.22 -0.422 0.72117E+04 86 gibbsite 4.08 0.73 -3.35 -0.478 0.57140E+04 87 glaucophane 22.97 20.79 -2.19 -0.059 0.37357E+04 88 glaucophane-Fe 17.28 12.78 -4.50 -0.122 0.76846E+04 89 graphite -3.55 -6.97 -3.42 -0.978 0.58471E+04 90 greenalite 16.14 13.54 -2.60 -0.216 0.44335E+04 93 hematite 12.57 9.18 -3.38 -0.410 0.57742E+04 94 heulandite -5.83 -7.57 -1.74 -0.079 0.29732E+04 98 jadeite 4.22 2.77 -1.44 -0.144 0.24672E+04 100 kalsilite 7.58 3.82 -3.76 -0.537 0.64236E+04 101 kaolinite -1.33 -4.84 -3.51 -0.319 0.59932E+04 104 laumontite 2.88 1.89 -0.99 -0.066 0.16893E+04 105 lawsonite 9.62 8.20 -1.41 -0.094 0.24137E+04 106 leucite 4.12 0.67 -3.45 -0.345 0.58928E+04 108 lizardite 23.24 21.55 -1.69 -0.141 0.28842E+04 110 magnetite 20.09 15.80 -4.29 -0.350 0.73179E+04 111 minnesotaite 10.39 7.23 -3.15 -0.186 0.53846E+04 115 manganosite 14.06 9.24 -4.82 -1.205 0.82300E+04 119 microcline -2.49 -2.49 0.00 0.000 0.39597E-01 123 muscovite 2.58 -1.02 -3.60 -0.212 0.61525E+04 124 paragonite 4.24 1.08 -3.16 -0.186 0.53916E+04 125 nepheline 8.34 5.92 -2.41 -0.345 0.41234E+04 137 phlogopite-Na 29.65 27.48 -2.17 -0.120 0.37010E+04 139 prehnite 19.37 18.09 -1.28 -0.075 0.21828E+04 140 prehnite-Fe 22.50 21.95 -0.54 -0.033 0.93053E+03 141 pumpellyite-Fe 46.27 43.54 -2.73 -0.061 0.46657E+04 142 pumpellyite-Mg 48.99 46.21 -2.79 -0.062 0.47594E+04 146 pyrrhotite -4.26 -7.97 -3.71 -1.238 0.63399E+04 147 pyrrhotiteFe0.875 -6.02 -9.30 -3.29 -1.208 0.56102E+04 148 pyroxmangite 7.40 6.08 -1.31 -0.263 0.22449E+04 149 pyrophyllite -6.18 -11.15 -4.98 -0.311 0.84952E+04 150 quartz -2.99 -3.15 -0.16 -0.055 0.28133E+03 154 rhodochrosite -0.98 -5.83 -4.86 -1.619 0.82909E+04 155 rhodonite 7.45 6.08 -1.36 -0.272 0.23251E+04 156 sanidine -1.28 -2.49 -1.21 -0.093 0.20678E+04 166 stilbite -7.52 -7.57 -0.05 -0.002 0.79336E+02 167 stilpnomelane-Fe 13.02 12.44 -0.58 -0.017 0.98636E+03 168 stilpnomelane-Mg 27.44 25.79 -1.65 -0.049 0.28160E+04 174 talc 16.49 15.25 -1.24 -0.073 0.21254E+04 177 tephroite 18.09 15.32 -2.76 -0.395 0.47190E+04 181 tridymite -2.63 -3.15 -0.53 -0.176 0.90131E+03 182 tremolite 47.87 47.30 -0.57 -0.016 0.98004E+03 183 ferroactinolite 38.45 33.94 -4.51 -0.122 0.77006E+04 184 troilite-low -4.41 -7.97 -3.56 -1.187 0.60827E+04 190 wairakite 3.95 1.89 -2.06 -0.121 0.35112E+04 191 walstromite 11.51 9.89 -1.62 -0.324 0.27631E+04 192 wollastonite 10.46 9.89 -0.57 -0.114 0.97351E+03 193 pseudo-wollastonite 11.00 9.89 -1.11 -0.222 0.18933E+04 194 zoisite 22.85 18.83 -4.02 -0.183 0.68693E+04 195 akaganeite 7.75 4.59 -3.16 -0.684 0.53996E+04 202 chalcedony -2.80 -3.15 -0.35 -0.117 0.60063E+03 204 montmorillonite-Ca -2.29 -6.18 -3.88 -0.240 0.66333E+04 205 montmorillonite-K -2.24 -6.27 -4.03 -0.247 0.68829E+04 206 montmorillonite-Mg -2.48 -6.80 -4.32 -0.267 0.73689E+04 207 montmorillonite-Na -2.04 -5.57 -3.54 -0.217 0.60378E+04 208 nontronite-Ca 3.21 0.00 -3.21 -0.208 0.54838E+04 209 nontronite-H 2.53 -2.15 -4.68 -0.314 0.79949E+04 210 nontronite-K 3.34 -0.09 -3.43 -0.220 0.58567E+04 211 nontronite-Mg 3.07 -0.62 -3.69 -0.239 0.63035E+04 212 nontronite-Na 3.52 0.60 -2.92 -0.187 0.49775E+04 228 tobermorite 9.82 7.71 -2.11 -0.576 0.36038E+04 234 alabandite -0.98 -5.35 -4.37 -1.458 0.74693E+04 237 boehmite 4.41 0.73 -3.67 -0.612 0.62724E+04 239 ferrous-oxide 9.81 6.62 -3.19 -0.799 0.54545E+04 245 silica-amorphous -2.09 -3.15 -1.06 -0.354 0.18148E+04 247 an20ab80 2.02 1.33 -0.68 -0.053 0.11686E+04 248 an25ab75 2.65 1.76 -0.88 -0.068 0.15077E+04 249 an30ab70 3.28 2.19 -1.09 -0.084 0.18564E+04 250 tr.625ac.25prg.125 45.16 44.90 -0.26 -0.007 0.44743E+03 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 0.0000200 MOLES Current total amount of reactant added: 0.0004700 MOLES New total amount of reactant added: 0.0004900 MOLES Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.5508E-08 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 6 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 0.0004900 Water: Moles liquid = 0.4985E+02 kg liquid = 0.8981E+00 Moles total = 0.4985E+02 kg total = 0.8980E+00 Activity = 1.0000 Stoichiometric ionic strength = .1136146E-01 Osmotic coef. = 0.9677 True ionic strength = .2004554E-01 Chg. balance for total moles = -.5508E-08 Max. difference allowed = 0.1408E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.89038E-10 -10.0504 0.74808E-10 -10.1260 0.84018E+00 -0.0756 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.15604E-03 -3.8068 0.13031E-03 -3.8850 0.83512E+00 -0.0782 4 SO4-- 0.59564E-10 -10.2250 0.30921E-10 -10.5097 0.51912E+00 -0.2847 5 HCO3- 0.14199E-04 -4.8477 0.11875E-04 -4.9254 0.83635E+00 -0.0776 6 HS- 0.41650E-04 -4.3804 0.34788E-04 -4.4586 0.83525E+00 -0.0782 7 Al+++ 0.97969E-29 -29.0089 0.22616E-29 -29.6456 0.23084E+00 -0.6367 8 H4SiO4 0.70137E-03 -3.1541 0.70137E-03 -3.1541 0.10000E+01 0.0000 9 Ca++ 0.12015E-06 -6.9203 0.61917E-07 -7.2082 0.51531E+00 -0.2879 10 Mg++ 0.21146E-10 -10.6748 0.10847E-10 -10.9647 0.51295E+00 -0.2899 11 Fe++ 0.45066E-13 -13.3461 0.23142E-13 -13.6356 0.51351E+00 -0.2894 12 K+ 0.15651E-03 -3.8055 0.13093E-03 -3.8830 0.83655E+00 -0.0775 13 Na+ 0.19862E-01 -1.7020 0.16584E-01 -1.7803 0.83497E+00 -0.0783 14 Mn++ 0.18841E-10 -10.7249 0.96831E-11 -11.0140 0.51394E+00 -0.2891 15 F- 0.32853E-06 -6.4834 0.27380E-06 -6.5626 0.83340E+00 -0.0791 16 HPO4-- 0.45323E-07 -7.3437 0.23531E-07 -7.6284 0.51920E+00 -0.2847 18 HSiO3- 0.10483E-01 -1.9795 0.87543E-02 -2.0578 0.83512E+00 -0.0782 19 Ca(HSiO3)+ 0.14753E-07 -7.8311 0.12344E-07 -7.9085 0.83673E+00 -0.0774 20 Mg(HSiO3)+ 0.32165E-11 -11.4926 0.26913E-11 -11.5700 0.83673E+00 -0.0774 21 NaHSiO3,aq 0.23481E-02 -2.6293 0.23481E-02 -2.6293 0.10000E+01 0.0000 22 AlO+ 0.65706E-16 -16.1824 0.54978E-16 -16.2598 0.83673E+00 -0.0774 24 HAlO2,aq 0.14636E-09 -9.8346 0.14636E-09 -9.8346 0.10000E+01 0.0000 25 AlO2- 0.51951E-05 -5.2844 0.43307E-05 -5.3634 0.83361E+00 -0.0790 26 CH4,aq 0.13023E-04 -4.8853 0.12978E-04 -4.8868 0.99654E+00 -0.0015 27 C2H6,aq 0.68474E-14 -14.1645 0.68237E-14 -14.1660 0.99654E+00 -0.0015 31 CO,aq 0.20122E-15 -15.6963 0.20122E-15 -15.6963 0.10000E+01 0.0000 32 CO2,aq 0.19049E-08 -8.7201 0.18983E-08 -8.7216 0.99654E+00 -0.0015 33 CO3-2 0.26767E-04 -4.5724 0.13866E-04 -4.8581 0.51802E+00 -0.2857 34 CaCO3,aq 0.10765E-07 -7.9680 0.10765E-07 -7.9680 0.10000E+01 0.0000 35 Ca(HCO3)+ 0.22431E-10 -10.6491 0.18769E-10 -10.7266 0.83673E+00 -0.0774 36 CaCl+ 0.15605E-10 -10.8067 0.13057E-10 -10.8841 0.83673E+00 -0.0774 37 CaCl2,aq 0.40424E-15 -15.3934 0.40424E-15 -15.3934 0.10000E+01 0.0000 38 CaF+ 0.29581E-12 -12.5290 0.24751E-12 -12.6064 0.83673E+00 -0.0774 39 CaOH+ 0.70498E-07 -7.1518 0.58988E-07 -7.2292 0.83673E+00 -0.0774 40 CaSO4,aq 0.60795E-15 -15.2161 0.60795E-15 -15.2161 0.10000E+01 0.0000 41 HCl,aq 0.17863E-14 -14.7480 0.17863E-14 -14.7480 0.10000E+01 0.0000 45 HF,aq 0.14022E-12 -12.8532 0.14022E-12 -12.8532 0.10000E+01 0.0000 46 HF2- 0.15521E-19 -19.8091 0.12962E-19 -19.8873 0.83512E+00 -0.0782 48 FeCl+ 0.57047E-17 -17.2438 0.47733E-17 -17.3212 0.83673E+00 -0.0774 51 FeF+ 0.38698E-18 -18.4123 0.32380E-18 -18.4897 0.83673E+00 -0.0774 53 FeO,aq 0.16072E-09 -9.7939 0.16072E-09 -9.7939 0.10000E+01 0.0000 54 FeOH+ 0.12035E-10 -10.9196 0.10070E-10 -10.9970 0.83673E+00 -0.0774 55 HFeO2- 0.26917E-07 -7.5700 0.22479E-07 -7.6482 0.83512E+00 -0.0782 56 FeO+ 0.13974E-16 -16.8547 0.11692E-16 -16.9321 0.83673E+00 -0.0774 58 FeO2- 0.51191E-09 -9.2908 0.42751E-09 -9.3691 0.83512E+00 -0.0782 59 HFeO2,aq 0.40675E-11 -11.3907 0.40675E-11 -11.3907 0.10000E+01 0.0000 60 H2,aq 0.42344E-05 -5.3732 0.42198E-05 -5.3747 0.99654E+00 -0.0015 61 KCl,aq 0.30923E-09 -9.5097 0.30923E-09 -9.5097 0.10000E+01 0.0000 63 KOH,aq 0.74743E-06 -6.1264 0.74743E-06 -6.1264 0.10000E+01 0.0000 64 KSO4- 0.75225E-13 -13.1236 0.62823E-13 -13.2019 0.83512E+00 -0.0782 65 MgCO3,aq 0.47270E-12 -12.3254 0.47270E-12 -12.3254 0.10000E+01 0.0000 66 Mg(HCO3)+ 0.40154E-14 -14.3963 0.33598E-14 -14.4737 0.83673E+00 -0.0774 67 MgCl+ 0.24778E-14 -14.6059 0.20732E-14 -14.6834 0.83673E+00 -0.0774 68 MgF+ 0.19196E-15 -15.7168 0.16062E-15 -15.7942 0.83673E+00 -0.0774 69 MgOH+ 0.68340E-10 -10.1653 0.57182E-10 -10.2427 0.83673E+00 -0.0774 71 MnF+ 0.53371E-16 -16.2727 0.44656E-16 -16.3501 0.83673E+00 -0.0774 72 MnO,aq 0.17919E-08 -8.7467 0.17919E-08 -8.7467 0.10000E+01 0.0000 73 MnOH+ 0.46778E-09 -9.3300 0.39141E-09 -9.4074 0.83673E+00 -0.0774 74 MnO2-2 0.20513E-10 -10.6880 0.10626E-10 -10.9736 0.51802E+00 -0.2857 75 HMnO2- 0.20854E-09 -9.6808 0.17416E-09 -9.7591 0.83512E+00 -0.0782 78 MnCl+ 0.92864E-14 -14.0322 0.77702E-14 -14.1096 0.83673E+00 -0.0774 79 MnSO4,aq 0.86438E-19 -19.0633 0.86438E-19 -19.0633 0.10000E+01 0.0000 80 NaCl,aq 0.71619E-06 -6.1450 0.71619E-06 -6.1450 0.10000E+01 0.0000 81 NaF,aq 0.10631E-08 -8.9734 0.10631E-08 -8.9734 0.10000E+01 0.0000 82 NaOH,aq 0.95247E-04 -4.0211 0.95247E-04 -4.0211 0.10000E+01 0.0000 84 OH- 0.92649E-02 -2.0332 0.77234E-02 -2.1122 0.83361E+00 -0.0790 89 HPO3-2 0.59736E-15 -15.2238 0.30944E-15 -15.5094 0.51802E+00 -0.2857 91 H2PO3- 0.55586E-19 -19.2550 0.46421E-19 -19.3333 0.83512E+00 -0.0782 92 H3PO4,aq 0.92103E-18 -18.0357 0.92103E-18 -18.0357 0.10000E+01 0.0000 93 H2PO4- 0.38848E-10 -10.4106 0.32474E-10 -10.4885 0.83592E+00 -0.0778 94 PO4-3 0.10585E-08 -8.9753 0.25664E-09 -9.5907 0.24247E+00 -0.6153 98 HP2O7-3 0.95512E-18 -18.0199 0.22071E-18 -18.6562 0.23108E+00 -0.6362 99 P2O7-4 0.91535E-17 -17.0384 0.70481E-18 -18.1519 0.76999E-01 -1.1135 100 H2S,aq 0.80711E-08 -8.0931 0.80431E-08 -8.0946 0.99654E+00 -0.0015 101 S2-2 0.12267E-13 -13.9112 0.63547E-14 -14.1969 0.51802E+00 -0.2857 107 SO3-2 0.32265E-16 -16.4913 0.16956E-16 -16.7707 0.52552E+00 -0.2794 108 HSO3- 0.95099E-19 -19.0218 0.79420E-19 -19.1001 0.83512E+00 -0.0782 109 HSO4- 0.26616E-17 -17.5749 0.22292E-17 -17.6518 0.83754E+00 -0.0770 Charge balance for all species = -.6133E-08 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.8903845E-10 -.2224042E-01 -.2237802E+02 0.0000 2 H2O 0.1000000E+01 0.5550481E+02 0.9981965E+06 0.0000 3 Cl- 0.1560378E-03 0.1567543E-03 0.5547743E+01 6.2410 4 SO4-- 0.5956385E-10 -.1408174E-04 -.1350361E+01 9.7424 5 HCO3- 0.1419916E-04 0.5400178E-04 0.3289306E+01 5.2007 6 HS- 0.4164983E-04 0.5573970E-04 0.1840217E+01 5.6675 7 Al+++ 0.9796923E-29 0.5195212E-05 0.1399308E+00 0.7326 8 H4SiO4 0.7013658E-03 0.1353210E-01 0.1298381E+04 -3.1541 9 Ca++ 0.1201545E-06 0.2162089E-06 0.8650149E-02 13.0439 10 Mg++ 0.2114610E-10 0.9318198E-10 0.2261500E-05 9.2874 11 Fe++ 0.4506643E-13 0.2760582E-07 0.1539021E-02 6.6165 12 K+ 0.1565123E-03 0.1572600E-03 0.6138486E+01 6.2431 13 Na+ 0.1986176E-01 0.2230583E-01 0.5119147E+03 8.3457 14 Mn++ 0.1884096E-10 0.2507551E-08 0.1375202E-03 9.2381 15 F- 0.3285348E-06 0.3295983E-06 0.6250816E-02 3.5635 16 HPO4-- 0.4532280E-07 0.4642012E-07 0.4447607E-02 12.6237 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.1997378E-01 -.1997330E-01 -.4798770E-06 0.0000000E+00 2 H2O 0.4984681E+02 0.4984681E+02 -.4368957E-06 0.0000000E+00 3 Cl- 0.1407752E-03 0.1407752E-03 0.0000000E+00 0.0000000E+00 4 SO4-- -.1264531E-04 -.1264629E-04 0.9750632E-09 0.0000000E+00 5 HCO3- 0.4849700E-04 0.4849700E-04 0.0000000E+00 0.0000000E+00 6 HS- 0.5005678E-04 0.5005776E-04 -.9750632E-09 0.0000000E+00 7 Al+++ 0.4775352E-05 0.4665627E-05 0.1097245E-06 0.0000000E+00 8 H4SiO4 0.1215302E-01 0.1215268E-01 0.3386609E-06 0.0000000E+00 9 Ca++ 0.2080835E-06 0.1941692E-06 0.1391428E-07 0.0000000E+00 10 Mg++ 0.8368328E-10 0.8368328E-10 0.0000000E+00 0.0000000E+00 11 Fe++ 0.3259227E-07 0.2479176E-07 0.7800506E-08 0.0000000E+00 12 K+ 0.1412294E-03 0.1412294E-03 0.0000000E+00 0.0000000E+00 13 Na+ 0.2003215E-01 0.2003204E-01 0.1082489E-06 0.0000000E+00 14 Mn++ 0.2251939E-08 0.2251939E-08 0.0000000E+00 0.0000000E+00 15 F- 0.2960000E-06 0.2960000E-06 0.0000000E+00 0.0000000E+00 16 HPO4-- 0.4168819E-07 0.4168819E-07 0.0000000E+00 0.0000000E+00 Chg. balance for solid moles: -.1191E-21 Mass of aqueous solution: 0.899628E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 0.0004900 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 0.1082E-06 -6.966 0.2839E-04 -4.547 92.46 0.1090E-04 andradite 0.3900E-08 -8.409 0.1982E-05 -5.703 6.456 0.5149E-06 grossular 0.7378E-09 -9.132 0.3324E-06 -6.478 1.083 0.9248E-07 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8409E+00 0.8409E+00 1.0000 -0.075 grossular 0.1591E+00 0.1591E+00 1.0000 -0.798 Solid products produced: Mass = 0.000031 g Volume = 0.000012 cm3 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.0004900 moles log = -3.3098 Original solution: 1000.0103000 g Original solution / Rock added: 2040837.35 (Water/Rock Ratio), log = 6.3098 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0450 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9766E+00 0.9856 0.1006E+01 0.1021E+01 CO2,gas 0.1930E-06 1.0069 0.2031E-06 0.2017E-06 CH4,gas 0.1806E-01 1.0123 0.1910E-01 0.1887E-01 H2,gas 0.5298E-02 1.0006 0.5540E-02 0.5537E-02 H2S,gas 0.2124E-06 0.9959 0.2211E-06 0.2220E-06 S2,gas 0.5721E-28 1.0000 0.5979E-28 0.5979E-28 CO,gas 0.2869E-12 1.0000 0.2999E-12 0.2999E-12 SO3,gas 0.6261E-46 1.0000 0.6543E-46 0.6543E-46 SO2,gas 0.1349E-25 1.0000 0.1410E-25 0.1410E-25 HF,gas 0.3294E-15 1.0000 0.3443E-15 0.3443E-15 HCl,gas 0.3016E-17 1.0000 0.3152E-17 0.3152E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 17 albite -0.38 -0.38 0.00 0.000 -0.94784E-12 23 andradite 39.01 39.01 0.00 0.000 0.12132E-10 24 grossular 32.73 32.73 0.00 0.000 0.12132E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -15.05 -8.39 -2.797 0.14328E+05 -6.692 3 CH4,gas 4.54 1.13 -3.42 -0.854 0.58359E+04 -1.719 4 H2,gas 8.00 4.04 -3.96 -2.260 0.67538E+04 -2.256 5 H2S,gas -6.23 -14.58 -8.35 -4.177 0.14265E+05 -6.655 6 S2,gas -7.34 -37.26 -29.92 -4.603 0.51092E+05 -28.223 7 CO,gas 3.21 -11.01 -14.22 -4.376 0.24284E+05 -12.523 8 SO3,gas 17.12 -30.76 -47.88 -11.971 0.81759E+05 -46.184 9 SO2,gas 0.83 -26.72 -27.55 -7.347 0.47040E+05 -25.851 10 HF,gas 0.47 -16.69 -17.16 -8.581 0.29304E+05 -15.463 11 HCl,gas 5.19 -14.01 -19.20 -9.600 0.32784E+05 -17.501 12 acmite 7.71 6.63 -1.08 -0.112 0.18402E+04 16 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 20 spessartine 24.46 19.72 -4.74 -0.237 0.80935E+04 21 analcite 3.32 2.77 -0.55 -0.061 0.94197E+03 27 annite 20.12 17.36 -2.76 -0.153 0.47133E+04 28 phlogopite 27.06 25.38 -1.69 -0.094 0.28837E+04 30 anorthite 12.71 8.20 -4.51 -0.347 0.76997E+04 33 apatite-OH -18.15 -18.42 -0.27 -0.021 0.45816E+03 34 apatite-F -34.30 -35.11 -0.81 -0.067 0.13821E+04 38 aragonite 0.97 -2.01 -2.97 -0.991 0.50780E+04 39 brucite 12.57 9.29 -3.28 -0.656 0.56025E+04 40 calcite 0.81 -2.01 -2.82 -0.940 0.48138E+04 41 carnegieite-low 9.02 5.92 -3.10 -0.443 0.52915E+04 42 carnegieite-high 10.09 5.92 -4.17 -0.596 0.71185E+04 43 carpholite-Mg 8.58 4.44 -4.14 -0.276 0.70650E+04 44 carpholite-Fe 6.71 1.77 -4.94 -0.329 0.84334E+04 45 celadonite 5.34 3.65 -1.69 -0.100 0.28938E+04 46 celadonite-Fe 3.88 0.98 -2.90 -0.171 0.49527E+04 47 chrysotile 23.89 21.55 -2.34 -0.195 0.39926E+04 49 clinochlore 39.07 38.44 -0.63 -0.020 0.10749E+04 50 daphnite 28.97 25.09 -3.88 -0.121 0.66246E+04 52 chlorite-Al-free 47.17 43.11 -4.06 -0.169 0.69403E+04 54 chloritoid-Fe 9.17 4.93 -4.25 -0.283 0.72500E+04 55 chloritoid-Mn 11.40 7.55 -3.85 -0.257 0.65770E+04 57 coesite -2.38 -3.15 -0.78 -0.259 0.13284E+04 64 cristobalite -2.56 -3.15 -0.59 -0.198 0.10138E+04 66 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71234E+04 68 diaspore 2.87 0.73 -2.14 -0.357 0.36559E+04 69 diamond -3.10 -6.96 -3.86 -1.103 0.65915E+04 70 diopside 16.18 16.02 -0.16 -0.016 0.27005E+03 71 hedenbergite 14.21 13.35 -0.86 -0.086 0.14616E+04 74 enstatite 17.26 12.27 -5.00 -0.500 0.85343E+04 76 clinoenstatite 17.17 12.27 -4.90 -0.490 0.83659E+04 78 epidote 24.67 22.69 -1.98 -0.096 0.33890E+04 79 clinozoisite 22.81 18.82 -3.98 -0.181 0.68004E+04 80 epidote-Fe 29.84 26.55 -3.29 -0.171 0.56242E+04 81 fayalite 14.05 10.08 -3.97 -0.567 0.67732E+04 82 ferrosilite 11.15 6.92 -4.22 -0.422 0.72133E+04 86 gibbsite 4.08 0.73 -3.35 -0.478 0.57145E+04 87 glaucophane 22.97 20.79 -2.19 -0.059 0.37367E+04 88 glaucophane-Fe 17.28 12.77 -4.50 -0.122 0.76873E+04 89 graphite -3.55 -6.96 -3.42 -0.976 0.58338E+04 90 greenalite 16.14 13.54 -2.60 -0.217 0.44362E+04 93 hematite 12.57 9.19 -3.38 -0.409 0.57670E+04 94 heulandite -5.83 -7.57 -1.74 -0.079 0.29746E+04 98 jadeite 4.22 2.77 -1.45 -0.145 0.24675E+04 100 kalsilite 7.58 3.82 -3.76 -0.537 0.64241E+04 101 kaolinite -1.33 -4.84 -3.51 -0.319 0.59936E+04 104 laumontite 2.88 1.89 -0.99 -0.066 0.16914E+04 105 lawsonite 9.62 8.20 -1.42 -0.094 0.24163E+04 106 leucite 4.12 0.67 -3.45 -0.345 0.58930E+04 108 lizardite 23.24 21.55 -1.69 -0.141 0.28852E+04 110 magnetite 20.09 15.81 -4.28 -0.350 0.73117E+04 111 minnesotaite 10.39 7.23 -3.15 -0.186 0.53868E+04 115 manganosite 14.06 9.24 -4.82 -1.205 0.82300E+04 119 microcline -2.49 -2.49 0.00 0.000 0.41292E-01 123 muscovite 2.58 -1.02 -3.60 -0.212 0.61534E+04 124 paragonite 4.24 1.08 -3.16 -0.186 0.53925E+04 125 nepheline 8.34 5.92 -2.42 -0.345 0.41239E+04 137 phlogopite-Na 29.65 27.48 -2.17 -0.120 0.37025E+04 139 prehnite 19.37 18.09 -1.28 -0.075 0.21875E+04 140 prehnite-Fe 22.50 21.95 -0.55 -0.033 0.93109E+03 141 pumpellyite-Fe 46.27 43.53 -2.74 -0.061 0.46765E+04 142 pumpellyite-Mg 48.99 46.20 -2.79 -0.062 0.47696E+04 146 pyrrhotite -4.26 -7.97 -3.71 -1.236 0.63310E+04 147 pyrrhotiteFe0.875 -6.02 -9.30 -3.28 -1.206 0.56000E+04 148 pyroxmangite 7.40 6.08 -1.31 -0.263 0.22447E+04 149 pyrophyllite -6.18 -11.15 -4.98 -0.311 0.84952E+04 150 quartz -2.99 -3.15 -0.16 -0.055 0.28108E+03 154 rhodochrosite -0.98 -5.81 -4.84 -1.612 0.82590E+04 155 rhodonite 7.45 6.08 -1.36 -0.272 0.23249E+04 156 sanidine -1.28 -2.49 -1.21 -0.093 0.20678E+04 166 stilbite -7.52 -7.57 -0.05 -0.002 0.80780E+02 167 stilpnomelane-Fe 13.02 12.44 -0.58 -0.017 0.99073E+03 168 stilpnomelane-Mg 27.44 25.79 -1.65 -0.049 0.28176E+04 174 talc 16.49 15.25 -1.25 -0.073 0.21259E+04 177 tephroite 18.09 15.32 -2.76 -0.395 0.47188E+04 181 tridymite -2.63 -3.15 -0.53 -0.176 0.90106E+03 182 tremolite 47.87 47.29 -0.58 -0.016 0.98497E+03 183 ferroactinolite 38.45 33.94 -4.51 -0.122 0.77084E+04 184 troilite-low -4.41 -7.97 -3.56 -1.186 0.60738E+04 190 wairakite 3.95 1.89 -2.06 -0.121 0.35134E+04 191 walstromite 11.51 9.89 -1.62 -0.324 0.27650E+04 192 wollastonite 10.46 9.89 -0.57 -0.114 0.97547E+03 193 pseudo-wollastonite 11.00 9.89 -1.11 -0.222 0.18953E+04 194 zoisite 22.85 18.82 -4.03 -0.183 0.68744E+04 195 akaganeite 7.75 4.59 -3.16 -0.683 0.53960E+04 202 chalcedony -2.80 -3.15 -0.35 -0.117 0.60038E+03 204 montmorillonite-Ca -2.29 -6.18 -3.89 -0.240 0.66336E+04 205 montmorillonite-K -2.24 -6.27 -4.03 -0.247 0.68829E+04 206 montmorillonite-Mg -2.48 -6.80 -4.32 -0.267 0.73689E+04 207 montmorillonite-Na -2.04 -5.57 -3.54 -0.217 0.60378E+04 208 nontronite-Ca 3.21 0.01 -3.21 -0.208 0.54763E+04 209 nontronite-H 2.53 -2.14 -4.68 -0.314 0.79869E+04 210 nontronite-K 3.34 -0.08 -3.43 -0.220 0.58488E+04 211 nontronite-Mg 3.07 -0.61 -3.69 -0.239 0.62957E+04 212 nontronite-Na 3.52 0.61 -2.91 -0.187 0.49697E+04 228 tobermorite 9.82 7.71 -2.11 -0.576 0.36054E+04 234 alabandite -0.98 -5.35 -4.37 -1.456 0.74593E+04 237 boehmite 4.41 0.73 -3.67 -0.612 0.62729E+04 239 ferrous-oxide 9.81 6.62 -3.20 -0.799 0.54555E+04 245 silica-amorphous -2.09 -3.15 -1.06 -0.354 0.18146E+04 247 an20ab80 2.02 1.33 -0.68 -0.053 0.11691E+04 248 an25ab75 2.65 1.76 -0.88 -0.068 0.15083E+04 249 an30ab70 3.28 2.19 -1.09 -0.084 0.18572E+04 250 tr.625ac.25prg.125 45.16 44.90 -0.27 -0.007 0.45326E+03 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 0.0000200 MOLES Current total amount of reactant added: 0.0004900 MOLES New total amount of reactant added: 0.0005100 MOLES Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.5508E-08 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 6 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 0.0005100 Water: Moles liquid = 0.4985E+02 kg liquid = 0.8981E+00 Moles total = 0.4985E+02 kg total = 0.8980E+00 Activity = 1.0000 Stoichiometric ionic strength = .1136274E-01 Osmotic coef. = 0.9677 True ionic strength = .2004672E-01 Chg. balance for total moles = -.5508E-08 Max. difference allowed = 0.1409E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.89070E-10 -10.0503 0.74835E-10 -10.1259 0.84018E+00 -0.0756 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.15617E-03 -3.8064 0.13042E-03 -3.8847 0.83512E+00 -0.0783 4 SO4-- 0.63316E-10 -10.1985 0.32868E-10 -10.4832 0.51912E+00 -0.2847 5 HCO3- 0.14793E-04 -4.8299 0.12372E-04 -4.9076 0.83634E+00 -0.0776 6 HS- 0.42191E-04 -4.3748 0.35240E-04 -4.4530 0.83524E+00 -0.0782 7 Al+++ 0.98014E-29 -29.0087 0.22625E-29 -29.6454 0.23084E+00 -0.6367 8 H4SiO4 0.70160E-03 -3.1539 0.70160E-03 -3.1539 0.10000E+01 0.0000 9 Ca++ 0.11989E-06 -6.9212 0.61778E-07 -7.2092 0.51530E+00 -0.2879 10 Mg++ 0.21147E-10 -10.6747 0.10847E-10 -10.9647 0.51294E+00 -0.2899 11 Fe++ 0.45041E-13 -13.3464 0.23129E-13 -13.6358 0.51350E+00 -0.2895 12 K+ 0.15651E-03 -3.8055 0.13093E-03 -3.8830 0.83654E+00 -0.0775 13 Na+ 0.19862E-01 -1.7020 0.16584E-01 -1.7803 0.83497E+00 -0.0783 14 Mn++ 0.18854E-10 -10.7246 0.96895E-11 -11.0137 0.51393E+00 -0.2891 15 F- 0.33741E-06 -6.4718 0.28120E-06 -6.5510 0.83340E+00 -0.0791 16 HPO4-- 0.45323E-07 -7.3437 0.23531E-07 -7.6284 0.51919E+00 -0.2847 18 HSiO3- 0.10482E-01 -1.9795 0.87541E-02 -2.0578 0.83512E+00 -0.0783 19 Ca(HSiO3)+ 0.14720E-07 -7.8321 0.12316E-07 -7.9095 0.83672E+00 -0.0774 20 Mg(HSiO3)+ 0.32165E-11 -11.4926 0.26913E-11 -11.5700 0.83672E+00 -0.0774 21 NaHSiO3,aq 0.23481E-02 -2.6293 0.23481E-02 -2.6293 0.10000E+01 0.0000 22 AlO+ 0.65687E-16 -16.1825 0.54962E-16 -16.2599 0.83672E+00 -0.0774 24 HAlO2,aq 0.14626E-09 -9.8349 0.14626E-09 -9.8349 0.10000E+01 0.0000 25 AlO2- 0.51900E-05 -5.2848 0.43264E-05 -5.3639 0.83361E+00 -0.0790 26 CH4,aq 0.12930E-04 -4.8884 0.12885E-04 -4.8899 0.99653E+00 -0.0015 27 C2H6,aq 0.68317E-14 -14.1655 0.68080E-14 -14.1670 0.99653E+00 -0.0015 31 CO,aq 0.20718E-15 -15.6837 0.20718E-15 -15.6837 0.10000E+01 0.0000 32 CO2,aq 0.19852E-08 -8.7022 0.19783E-08 -8.7037 0.99653E+00 -0.0015 33 CO3-2 0.27876E-04 -4.5548 0.14440E-04 -4.8404 0.51801E+00 -0.2857 34 CaCO3,aq 0.11186E-07 -7.9513 0.11186E-07 -7.9513 0.10000E+01 0.0000 35 Ca(HCO3)+ 0.23317E-10 -10.6323 0.19510E-10 -10.7097 0.83672E+00 -0.0774 36 CaCl+ 0.15583E-10 -10.8073 0.13039E-10 -10.8848 0.83672E+00 -0.0774 37 CaCl2,aq 0.40401E-15 -15.3936 0.40401E-15 -15.3936 0.10000E+01 0.0000 38 CaF+ 0.30313E-12 -12.5184 0.25363E-12 -12.5958 0.83672E+00 -0.0774 39 CaOH+ 0.70316E-07 -7.1529 0.58835E-07 -7.2304 0.83672E+00 -0.0774 40 CaSO4,aq 0.64479E-15 -15.1906 0.64479E-15 -15.1906 0.10000E+01 0.0000 41 HCl,aq 0.17885E-14 -14.7475 0.17885E-14 -14.7475 0.10000E+01 0.0000 45 HF,aq 0.14406E-12 -12.8415 0.14406E-12 -12.8415 0.10000E+01 0.0000 46 HF2- 0.16377E-19 -19.7858 0.13677E-19 -19.8640 0.83512E+00 -0.0783 48 FeCl+ 0.57062E-17 -17.2437 0.47745E-17 -17.3211 0.83672E+00 -0.0774 51 FeF+ 0.39721E-18 -18.4010 0.33236E-18 -18.4784 0.83672E+00 -0.0774 53 FeO,aq 0.16051E-09 -9.7945 0.16051E-09 -9.7945 0.10000E+01 0.0000 54 FeOH+ 0.12024E-10 -10.9200 0.10060E-10 -10.9974 0.83672E+00 -0.0774 55 HFeO2- 0.26873E-07 -7.5707 0.22442E-07 -7.6489 0.83512E+00 -0.0783 56 FeO+ 0.14046E-16 -16.8525 0.11752E-16 -16.9299 0.83672E+00 -0.0774 58 FeO2- 0.51419E-09 -9.2889 0.42941E-09 -9.3671 0.83512E+00 -0.0783 59 HFeO2,aq 0.40871E-11 -11.3886 0.40871E-11 -11.3886 0.10000E+01 0.0000 60 H2,aq 0.41834E-05 -5.3785 0.41689E-05 -5.3800 0.99653E+00 -0.0015 61 KCl,aq 0.30948E-09 -9.5094 0.30948E-09 -9.5094 0.10000E+01 0.0000 63 KOH,aq 0.74717E-06 -6.1266 0.74717E-06 -6.1266 0.10000E+01 0.0000 64 KSO4- 0.79963E-13 -13.0971 0.66778E-13 -13.1754 0.83512E+00 -0.0783 65 MgCO3,aq 0.49231E-12 -12.3078 0.49231E-12 -12.3078 0.10000E+01 0.0000 66 Mg(HCO3)+ 0.41834E-14 -14.3785 0.35004E-14 -14.4559 0.83672E+00 -0.0774 67 MgCl+ 0.24799E-14 -14.6056 0.20750E-14 -14.6830 0.83672E+00 -0.0774 68 MgF+ 0.19716E-15 -15.7052 0.16497E-15 -15.7826 0.83672E+00 -0.0774 69 MgOH+ 0.68319E-10 -10.1655 0.57164E-10 -10.2429 0.83672E+00 -0.0774 71 MnF+ 0.54849E-16 -16.2608 0.45894E-16 -16.3382 0.83672E+00 -0.0774 72 MnO,aq 0.17918E-08 -8.7467 0.17918E-08 -8.7467 0.10000E+01 0.0000 73 MnOH+ 0.46793E-09 -9.3298 0.39153E-09 -9.4072 0.83672E+00 -0.0774 74 MnO2-2 0.20498E-10 -10.6883 0.10618E-10 -10.9739 0.51801E+00 -0.2857 75 HMnO2- 0.20846E-09 -9.6810 0.17409E-09 -9.7592 0.83512E+00 -0.0783 78 MnCl+ 0.93004E-14 -14.0315 0.77818E-14 -14.1089 0.83672E+00 -0.0774 79 MnSO4,aq 0.91942E-19 -19.0365 0.91942E-19 -19.0365 0.10000E+01 0.0000 80 NaCl,aq 0.71678E-06 -6.1446 0.71678E-06 -6.1446 0.10000E+01 0.0000 81 NaF,aq 0.10918E-08 -8.9619 0.10918E-08 -8.9619 0.10000E+01 0.0000 82 NaOH,aq 0.95214E-04 -4.0213 0.95214E-04 -4.0213 0.10000E+01 0.0000 84 OH- 0.92617E-02 -2.0333 0.77207E-02 -2.1123 0.83361E+00 -0.0790 89 HPO3-2 0.59016E-15 -15.2290 0.30571E-15 -15.5147 0.51801E+00 -0.2857 91 H2PO3- 0.54935E-19 -19.2602 0.45877E-19 -19.3384 0.83512E+00 -0.0783 92 H3PO4,aq 0.92167E-18 -18.0354 0.92167E-18 -18.0354 0.10000E+01 0.0000 93 H2PO4- 0.38862E-10 -10.4105 0.32485E-10 -10.4883 0.83591E+00 -0.0778 94 PO4-3 0.10581E-08 -8.9755 0.25655E-09 -9.5908 0.24246E+00 -0.6154 98 HP2O7-3 0.95548E-18 -18.0198 0.22078E-18 -18.6560 0.23107E+00 -0.6363 99 P2O7-4 0.91539E-17 -17.0384 0.70480E-18 -18.1519 0.76994E-01 -1.1135 100 H2S,aq 0.81788E-08 -8.0873 0.81504E-08 -8.0888 0.99653E+00 -0.0015 101 S2-2 0.12742E-13 -13.8948 0.66004E-14 -14.1804 0.51801E+00 -0.2857 107 SO3-2 0.33883E-16 -16.4700 0.17806E-16 -16.7494 0.52551E+00 -0.2794 108 HSO3- 0.99905E-19 -19.0004 0.83432E-19 -19.0787 0.83512E+00 -0.0783 109 HSO4- 0.28302E-17 -17.5482 0.23704E-17 -17.6252 0.83754E+00 -0.0770 Charge balance for all species = -.6133E-08 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.8907007E-10 -.2223800E-01 -.2237558E+02 0.0000 2 H2O 0.1000000E+01 0.5550480E+02 0.9981963E+06 0.0000 3 Cl- 0.1561685E-03 0.1568856E-03 0.5552390E+01 6.2412 4 SO4-- 0.6331556E-10 -.1397540E-04 -.1340164E+01 9.7686 5 HCO3- 0.1479279E-04 0.5561189E-04 0.3387379E+01 5.2183 6 HS- 0.4219087E-04 0.5617451E-04 0.1854572E+01 5.6729 7 Al+++ 0.9801381E-29 0.5190113E-05 0.1397935E+00 0.7323 8 H4SiO4 0.7015964E-03 0.1353208E-01 0.1298379E+04 -3.1539 9 Ca++ 0.1198873E-06 0.2161479E-06 0.8647706E-02 13.0426 10 Mg++ 0.2114727E-10 0.9318194E-10 0.2261499E-05 9.2871 11 Fe++ 0.4504115E-13 0.2756413E-07 0.1536696E-02 6.6159 12 K+ 0.1565125E-03 0.1572600E-03 0.6138483E+01 6.2429 13 Na+ 0.1986184E-01 0.2230582E-01 0.5119143E+03 8.3456 14 Mn++ 0.1885380E-10 0.2507550E-08 0.1375202E-03 9.2381 15 F- 0.3374140E-06 0.3385062E-06 0.6419755E-02 3.5749 16 HPO4-- 0.4532312E-07 0.4642010E-07 0.4447605E-02 12.6234 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.1997163E-01 -.1997113E-01 -.4983665E-06 0.0000000E+00 2 H2O 0.4984683E+02 0.4984683E+02 -.4552270E-06 0.0000000E+00 3 Cl- 0.1408932E-03 0.1408932E-03 0.0000000E+00 0.0000000E+00 4 SO4-- -.1254981E-04 -.1255079E-04 0.9797423E-09 0.0000000E+00 5 HCO3- 0.4994300E-04 0.4994300E-04 0.0000000E+00 0.0000000E+00 6 HS- 0.5044728E-04 0.5044826E-04 -.9797423E-09 0.0000000E+00 7 Al+++ 0.4775352E-05 0.4661050E-05 0.1143018E-06 0.0000000E+00 8 H4SiO4 0.1215302E-01 0.1215267E-01 0.3524501E-06 0.0000000E+00 9 Ca++ 0.2080835E-06 0.1941145E-06 0.1396903E-07 0.0000000E+00 10 Mg++ 0.8368328E-10 0.8368328E-10 0.0000000E+00 0.0000000E+00 11 Fe++ 0.3259227E-07 0.2475433E-07 0.7837938E-08 0.0000000E+00 12 K+ 0.1412294E-03 0.1412294E-03 0.0000000E+00 0.0000000E+00 13 Na+ 0.2003215E-01 0.2003204E-01 0.1128270E-06 0.0000000E+00 14 Mn++ 0.2251939E-08 0.2251939E-08 0.0000000E+00 0.0000000E+00 15 F- 0.3040000E-06 0.3040000E-06 0.0000000E+00 0.0000000E+00 16 HPO4-- 0.4168819E-07 0.4168819E-07 0.0000000E+00 0.0000000E+00 Chg. balance for solid moles: -.5294E-22 Mass of aqueous solution: 0.899628E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 0.0005100 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 0.1128E-06 -6.948 0.2959E-04 -4.529 92.72 0.1136E-04 andradite 0.3919E-08 -8.407 0.1992E-05 -5.701 6.241 0.5174E-06 grossular 0.7374E-09 -9.132 0.3321E-06 -6.479 1.041 0.9242E-07 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8416E+00 0.8416E+00 1.0000 -0.075 grossular 0.1584E+00 0.1584E+00 1.0000 -0.800 Solid products produced: Mass = 0.000032 g Volume = 0.000012 cm3 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.0005100 moles log = -3.2924 Original solution: 1000.0103000 g Original solution / Rock added: 1960804.51 (Water/Rock Ratio), log = 6.2924 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0448 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9768E+00 0.9856 0.1006E+01 0.1021E+01 CO2,gas 0.2012E-06 1.0069 0.2117E-06 0.2102E-06 CH4,gas 0.1793E-01 1.0123 0.1897E-01 0.1873E-01 H2,gas 0.5235E-02 1.0006 0.5473E-02 0.5470E-02 H2S,gas 0.2153E-06 0.9959 0.2240E-06 0.2250E-06 S2,gas 0.6020E-28 1.0000 0.6290E-28 0.6290E-28 CO,gas 0.2955E-12 1.0000 0.3087E-12 0.3087E-12 SO3,gas 0.6661E-46 1.0000 0.6960E-46 0.6960E-46 SO2,gas 0.1418E-25 1.0000 0.1482E-25 0.1482E-25 HF,gas 0.3385E-15 1.0000 0.3537E-15 0.3537E-15 HCl,gas 0.3020E-17 1.0000 0.3156E-17 0.3156E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 17 albite -0.38 -0.38 0.00 0.000 -0.94784E-12 23 andradite 39.01 39.01 0.00 0.000 -0.36397E-10 24 grossular 32.73 32.73 0.00 0.000 0.00000E+00 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -15.03 -8.37 -2.791 0.14297E+05 -6.674 3 CH4,gas 4.54 1.12 -3.42 -0.855 0.58413E+04 -1.722 4 H2,gas 8.00 4.04 -3.96 -2.263 0.67628E+04 -2.262 5 H2S,gas -6.23 -14.58 -8.35 -4.174 0.14255E+05 -6.650 6 S2,gas -7.34 -37.24 -29.90 -4.600 0.51054E+05 -28.201 7 CO,gas 3.21 -10.99 -14.21 -4.372 0.24262E+05 -12.510 8 SO3,gas 17.12 -30.74 -47.86 -11.964 0.81713E+05 -46.157 9 SO2,gas 0.83 -26.70 -27.53 -7.341 0.47004E+05 -25.829 10 HF,gas 0.47 -16.68 -17.15 -8.575 0.29284E+05 -15.451 11 HCl,gas 5.19 -14.01 -19.20 -9.600 0.32783E+05 -17.501 12 acmite 7.71 6.63 -1.08 -0.112 0.18364E+04 16 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 20 spessartine 24.46 19.72 -4.74 -0.237 0.80938E+04 21 analcite 3.32 2.77 -0.55 -0.061 0.94221E+03 27 annite 20.12 17.36 -2.76 -0.153 0.47162E+04 28 phlogopite 27.06 25.37 -1.69 -0.094 0.28852E+04 30 anorthite 12.71 8.20 -4.51 -0.347 0.77023E+04 33 apatite-OH -18.15 -18.43 -0.27 -0.021 0.46753E+03 34 apatite-F -34.30 -35.10 -0.80 -0.067 0.13714E+04 38 aragonite 0.97 -1.99 -2.96 -0.986 0.50496E+04 39 brucite 12.57 9.29 -3.28 -0.656 0.56030E+04 40 calcite 0.81 -1.99 -2.80 -0.934 0.47854E+04 41 carnegieite-low 9.02 5.92 -3.10 -0.443 0.52920E+04 42 carnegieite-high 10.09 5.92 -4.17 -0.596 0.71190E+04 43 carpholite-Mg 8.58 4.44 -4.14 -0.276 0.70659E+04 44 carpholite-Fe 6.71 1.77 -4.94 -0.329 0.84348E+04 45 celadonite 5.34 3.65 -1.69 -0.100 0.28940E+04 46 celadonite-Fe 3.88 0.98 -2.90 -0.171 0.49534E+04 47 chrysotile 23.89 21.55 -2.34 -0.195 0.39936E+04 49 clinochlore 39.07 38.44 -0.63 -0.020 0.10776E+04 50 daphnite 28.97 25.08 -3.88 -0.121 0.66296E+04 52 chlorite-Al-free 47.17 43.11 -4.07 -0.169 0.69423E+04 54 chloritoid-Fe 9.17 4.93 -4.25 -0.283 0.72517E+04 55 chloritoid-Mn 11.40 7.55 -3.85 -0.257 0.65777E+04 57 coesite -2.38 -3.15 -0.78 -0.259 0.13282E+04 64 cristobalite -2.56 -3.15 -0.59 -0.198 0.10135E+04 66 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71234E+04 68 diaspore 2.87 0.73 -2.14 -0.357 0.36564E+04 69 diamond -3.10 -6.96 -3.85 -1.101 0.65789E+04 70 diopside 16.18 16.02 -0.16 -0.016 0.27224E+03 71 hedenbergite 14.21 13.35 -0.86 -0.086 0.14642E+04 74 enstatite 17.26 12.27 -5.00 -0.500 0.85348E+04 76 clinoenstatite 17.17 12.27 -4.90 -0.490 0.83664E+04 78 epidote 24.67 22.68 -1.99 -0.096 0.33900E+04 79 clinozoisite 22.81 18.82 -3.99 -0.181 0.68054E+04 80 epidote-Fe 29.84 26.55 -3.29 -0.171 0.56212E+04 81 fayalite 14.05 10.08 -3.97 -0.567 0.67748E+04 82 ferrosilite 11.15 6.92 -4.23 -0.423 0.72147E+04 86 gibbsite 4.08 0.73 -3.35 -0.478 0.57150E+04 87 glaucophane 22.97 20.79 -2.19 -0.059 0.37377E+04 88 glaucophane-Fe 17.28 12.77 -4.50 -0.122 0.76897E+04 89 graphite -3.55 -6.96 -3.41 -0.974 0.58211E+04 90 greenalite 16.14 13.54 -2.60 -0.217 0.44386E+04 93 hematite 12.57 9.19 -3.37 -0.409 0.57599E+04 94 heulandite -5.83 -7.57 -1.74 -0.079 0.29760E+04 98 jadeite 4.22 2.77 -1.45 -0.145 0.24677E+04 100 kalsilite 7.58 3.82 -3.76 -0.538 0.64245E+04 101 kaolinite -1.33 -4.84 -3.51 -0.319 0.59941E+04 104 laumontite 2.88 1.89 -0.99 -0.066 0.16936E+04 105 lawsonite 9.62 8.20 -1.42 -0.094 0.24190E+04 106 leucite 4.12 0.67 -3.45 -0.345 0.58933E+04 108 lizardite 23.24 21.55 -1.69 -0.141 0.28862E+04 110 magnetite 20.09 15.81 -4.28 -0.349 0.73056E+04 111 minnesotaite 10.39 7.23 -3.16 -0.186 0.53886E+04 115 manganosite 14.06 9.24 -4.82 -1.205 0.82300E+04 119 microcline -2.49 -2.49 0.00 0.000 0.42989E-01 123 muscovite 2.58 -1.02 -3.60 -0.212 0.61544E+04 124 paragonite 4.24 1.08 -3.16 -0.186 0.53934E+04 125 nepheline 8.34 5.92 -2.42 -0.345 0.41244E+04 137 phlogopite-Na 29.65 27.48 -2.17 -0.121 0.37040E+04 139 prehnite 19.37 18.09 -1.28 -0.076 0.21920E+04 140 prehnite-Fe 22.50 21.95 -0.55 -0.033 0.93165E+03 141 pumpellyite-Fe 46.27 43.52 -2.75 -0.061 0.46871E+04 142 pumpellyite-Mg 48.99 46.20 -2.80 -0.062 0.47797E+04 146 pyrrhotite -4.26 -7.96 -3.70 -1.234 0.63221E+04 147 pyrrhotiteFe0.875 -6.02 -9.29 -3.27 -1.204 0.55899E+04 148 pyroxmangite 7.40 6.08 -1.31 -0.263 0.22445E+04 149 pyrophyllite -6.18 -11.15 -4.98 -0.311 0.84952E+04 150 quartz -2.99 -3.15 -0.16 -0.055 0.28084E+03 154 rhodochrosite -0.98 -5.80 -4.82 -1.606 0.82284E+04 155 rhodonite 7.45 6.08 -1.36 -0.272 0.23247E+04 156 sanidine -1.28 -2.49 -1.21 -0.093 0.20678E+04 166 stilbite -7.52 -7.57 -0.05 -0.002 0.82198E+02 167 stilpnomelane-Fe 13.02 12.43 -0.58 -0.017 0.99460E+03 168 stilpnomelane-Mg 27.44 25.79 -1.65 -0.049 0.28192E+04 174 talc 16.49 15.25 -1.25 -0.073 0.21264E+04 177 tephroite 18.09 15.32 -2.76 -0.395 0.47186E+04 181 tridymite -2.63 -3.15 -0.53 -0.176 0.90082E+03 182 tremolite 47.87 47.29 -0.58 -0.016 0.98985E+03 183 ferroactinolite 38.45 33.93 -4.52 -0.122 0.77155E+04 184 troilite-low -4.41 -7.96 -3.55 -1.184 0.60649E+04 190 wairakite 3.95 1.89 -2.06 -0.121 0.35155E+04 191 walstromite 11.51 9.89 -1.62 -0.324 0.27670E+04 192 wollastonite 10.46 9.89 -0.57 -0.114 0.97741E+03 193 pseudo-wollastonite 11.00 9.89 -1.11 -0.222 0.18972E+04 194 zoisite 22.85 18.82 -4.03 -0.183 0.68795E+04 195 akaganeite 7.75 4.60 -3.16 -0.683 0.53925E+04 202 chalcedony -2.80 -3.15 -0.35 -0.117 0.60014E+03 204 montmorillonite-Ca -2.29 -6.18 -3.89 -0.240 0.66339E+04 205 montmorillonite-K -2.24 -6.27 -4.03 -0.247 0.68830E+04 206 montmorillonite-Mg -2.48 -6.80 -4.32 -0.267 0.73690E+04 207 montmorillonite-Na -2.04 -5.57 -3.54 -0.217 0.60379E+04 208 nontronite-Ca 3.21 0.01 -3.20 -0.208 0.54688E+04 209 nontronite-H 2.53 -2.14 -4.67 -0.313 0.79791E+04 210 nontronite-K 3.34 -0.08 -3.42 -0.220 0.58411E+04 211 nontronite-Mg 3.07 -0.61 -3.68 -0.239 0.62879E+04 212 nontronite-Na 3.52 0.61 -2.91 -0.187 0.49619E+04 228 tobermorite 9.82 7.71 -2.11 -0.576 0.36070E+04 234 alabandite -0.98 -5.34 -4.36 -1.454 0.74495E+04 237 boehmite 4.41 0.73 -3.67 -0.612 0.62733E+04 239 ferrous-oxide 9.81 6.62 -3.20 -0.799 0.54565E+04 245 silica-amorphous -2.09 -3.15 -1.06 -0.354 0.18143E+04 247 an20ab80 2.02 1.33 -0.68 -0.053 0.11696E+04 248 an25ab75 2.65 1.76 -0.88 -0.068 0.15090E+04 249 an30ab70 3.28 2.19 -1.09 -0.084 0.18580E+04 250 tr.625ac.25prg.125 45.16 44.90 -0.27 -0.007 0.45892E+03 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 0.0000200 MOLES Current total amount of reactant added: 0.0005100 MOLES New total amount of reactant added: 0.0005300 MOLES Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.5508E-08 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 6 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 0.0005300 Water: Moles liquid = 0.4985E+02 kg liquid = 0.8981E+00 Moles total = 0.4985E+02 kg total = 0.8980E+00 Activity = 1.0000 Stoichiometric ionic strength = .1136402E-01 Osmotic coef. = 0.9676 True ionic strength = .2004790E-01 Chg. balance for total moles = -.5508E-08 Max. difference allowed = 0.1410E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.89102E-10 -10.0501 0.74861E-10 -10.1257 0.84018E+00 -0.0756 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.15630E-03 -3.8060 0.13053E-03 -3.8843 0.83512E+00 -0.0783 4 SO4-- 0.67192E-10 -10.1727 0.34880E-10 -10.4574 0.51911E+00 -0.2847 5 HCO3- 0.15387E-04 -4.8128 0.12869E-04 -4.8905 0.83634E+00 -0.0776 6 HS- 0.42732E-04 -4.3692 0.35691E-04 -4.4474 0.83524E+00 -0.0782 7 Al+++ 0.98058E-29 -29.0085 0.22635E-29 -29.6452 0.23083E+00 -0.6367 8 H4SiO4 0.70183E-03 -3.1538 0.70183E-03 -3.1538 0.10000E+01 0.0000 9 Ca++ 0.11962E-06 -6.9222 0.61642E-07 -7.2101 0.51529E+00 -0.2879 10 Mg++ 0.21148E-10 -10.6747 0.10848E-10 -10.9647 0.51293E+00 -0.2899 11 Fe++ 0.45022E-13 -13.3466 0.23118E-13 -13.6360 0.51350E+00 -0.2895 12 K+ 0.15651E-03 -3.8055 0.13093E-03 -3.8830 0.83654E+00 -0.0775 13 Na+ 0.19862E-01 -1.7020 0.16584E-01 -1.7803 0.83497E+00 -0.0783 14 Mn++ 0.18867E-10 -10.7243 0.96960E-11 -11.0134 0.51392E+00 -0.2891 15 F- 0.34629E-06 -6.4606 0.28860E-06 -6.5397 0.83339E+00 -0.0791 16 HPO4-- 0.45323E-07 -7.3437 0.23531E-07 -7.6284 0.51918E+00 -0.2847 18 HSiO3- 0.10482E-01 -1.9795 0.87539E-02 -2.0578 0.83512E+00 -0.0783 19 Ca(HSiO3)+ 0.14687E-07 -7.8331 0.12289E-07 -7.9105 0.83672E+00 -0.0774 20 Mg(HSiO3)+ 0.32166E-11 -11.4926 0.26914E-11 -11.5700 0.83672E+00 -0.0774 21 NaHSiO3,aq 0.23480E-02 -2.6293 0.23480E-02 -2.6293 0.10000E+01 0.0000 22 AlO+ 0.65669E-16 -16.1826 0.54946E-16 -16.2601 0.83672E+00 -0.0774 24 HAlO2,aq 0.14617E-09 -9.8351 0.14617E-09 -9.8351 0.10000E+01 0.0000 25 AlO2- 0.51849E-05 -5.2853 0.43221E-05 -5.3643 0.83361E+00 -0.0790 26 CH4,aq 0.12836E-04 -4.8916 0.12791E-04 -4.8931 0.99653E+00 -0.0015 27 C2H6,aq 0.68122E-14 -14.1667 0.67886E-14 -14.1682 0.99653E+00 -0.0015 31 CO,aq 0.21306E-15 -15.6715 0.21306E-15 -15.6715 0.10000E+01 0.0000 32 CO2,aq 0.20656E-08 -8.6849 0.20585E-08 -8.6865 0.99653E+00 -0.0015 33 CO3-2 0.28986E-04 -4.5378 0.15015E-04 -4.8235 0.51800E+00 -0.2857 34 CaCO3,aq 0.11605E-07 -7.9353 0.11605E-07 -7.9353 0.10000E+01 0.0000 35 Ca(HCO3)+ 0.24200E-10 -10.6162 0.20248E-10 -10.6936 0.83672E+00 -0.0774 36 CaCl+ 0.15562E-10 -10.8079 0.13021E-10 -10.8854 0.83672E+00 -0.0774 37 CaCl2,aq 0.40379E-15 -15.3938 0.40379E-15 -15.3938 0.10000E+01 0.0000 38 CaF+ 0.31042E-12 -12.5081 0.25973E-12 -12.5855 0.83672E+00 -0.0774 39 CaOH+ 0.70136E-07 -7.1541 0.58684E-07 -7.2315 0.83672E+00 -0.0774 40 CaSO4,aq 0.68275E-15 -15.1657 0.68275E-15 -15.1657 0.10000E+01 0.0000 41 HCl,aq 0.17906E-14 -14.7470 0.17906E-14 -14.7470 0.10000E+01 0.0000 45 HF,aq 0.14790E-12 -12.8300 0.14790E-12 -12.8300 0.10000E+01 0.0000 46 HF2- 0.17256E-19 -19.7630 0.14411E-19 -19.8413 0.83512E+00 -0.0783 48 FeCl+ 0.57084E-17 -17.2435 0.47764E-17 -17.3209 0.83672E+00 -0.0774 51 FeF+ 0.40748E-18 -18.3899 0.34095E-18 -18.4673 0.83672E+00 -0.0774 53 FeO,aq 0.16033E-09 -9.7950 0.16033E-09 -9.7950 0.10000E+01 0.0000 54 FeOH+ 0.12014E-10 -10.9203 0.10052E-10 -10.9977 0.83672E+00 -0.0774 55 HFeO2- 0.26833E-07 -7.5713 0.22409E-07 -7.6496 0.83512E+00 -0.0783 56 FeO+ 0.14117E-16 -16.8502 0.11812E-16 -16.9277 0.83672E+00 -0.0774 58 FeO2- 0.51644E-09 -9.2870 0.43129E-09 -9.3652 0.83512E+00 -0.0783 59 HFeO2,aq 0.41064E-11 -11.3865 0.41064E-11 -11.3865 0.10000E+01 0.0000 60 H2,aq 0.41345E-05 -5.3836 0.41202E-05 -5.3851 0.99653E+00 -0.0015 61 KCl,aq 0.30974E-09 -9.5090 0.30974E-09 -9.5090 0.10000E+01 0.0000 63 KOH,aq 0.74690E-06 -6.1267 0.74690E-06 -6.1267 0.10000E+01 0.0000 64 KSO4- 0.84858E-13 -13.0713 0.70866E-13 -13.1496 0.83512E+00 -0.0783 65 MgCO3,aq 0.51192E-12 -12.2908 0.51192E-12 -12.2908 0.10000E+01 0.0000 66 Mg(HCO3)+ 0.43516E-14 -14.3614 0.36411E-14 -14.4388 0.83672E+00 -0.0774 67 MgCl+ 0.24821E-14 -14.6052 0.20768E-14 -14.6826 0.83672E+00 -0.0774 68 MgF+ 0.20236E-15 -15.6939 0.16932E-15 -15.7713 0.83672E+00 -0.0774 69 MgOH+ 0.68298E-10 -10.1656 0.57146E-10 -10.2430 0.83672E+00 -0.0774 71 MnF+ 0.56330E-16 -16.2493 0.47133E-16 -16.3267 0.83672E+00 -0.0774 72 MnO,aq 0.17917E-08 -8.7467 0.17917E-08 -8.7467 0.10000E+01 0.0000 73 MnOH+ 0.46808E-09 -9.3297 0.39165E-09 -9.4071 0.83672E+00 -0.0774 74 MnO2-2 0.20483E-10 -10.6886 0.10610E-10 -10.9743 0.51800E+00 -0.2857 75 HMnO2- 0.20838E-09 -9.6811 0.17402E-09 -9.7594 0.83512E+00 -0.0783 78 MnCl+ 0.93143E-14 -14.0308 0.77935E-14 -14.1083 0.83672E+00 -0.0774 79 MnSO4,aq 0.97635E-19 -19.0104 0.97635E-19 -19.0104 0.10000E+01 0.0000 80 NaCl,aq 0.71738E-06 -6.1443 0.71738E-06 -6.1443 0.10000E+01 0.0000 81 NaF,aq 0.11205E-08 -8.9506 0.11205E-08 -8.9506 0.10000E+01 0.0000 82 NaOH,aq 0.95180E-04 -4.0215 0.95180E-04 -4.0215 0.10000E+01 0.0000 84 OH- 0.92585E-02 -2.0335 0.77179E-02 -2.1125 0.83361E+00 -0.0790 89 HPO3-2 0.58327E-15 -15.2341 0.30214E-15 -15.5198 0.51800E+00 -0.2857 91 H2PO3- 0.54311E-19 -19.2651 0.45356E-19 -19.3434 0.83512E+00 -0.0783 92 H3PO4,aq 0.92231E-18 -18.0351 0.92231E-18 -18.0351 0.10000E+01 0.0000 93 H2PO4- 0.38875E-10 -10.4103 0.32496E-10 -10.4882 0.83591E+00 -0.0778 94 PO4-3 0.10578E-08 -8.9756 0.25646E-09 -9.5910 0.24245E+00 -0.6154 98 HP2O7-3 0.95583E-18 -18.0196 0.22085E-18 -18.6559 0.23106E+00 -0.6363 99 P2O7-4 0.91543E-17 -17.0384 0.70479E-18 -18.1519 0.76990E-01 -1.1136 100 H2S,aq 0.82865E-08 -8.0816 0.82578E-08 -8.0831 0.99653E+00 -0.0015 101 S2-2 0.13225E-13 -13.8786 0.68508E-14 -14.1643 0.51800E+00 -0.2857 107 SO3-2 0.35538E-16 -16.4493 0.18675E-16 -16.7287 0.52551E+00 -0.2794 108 HSO3- 0.10482E-18 -18.9796 0.87536E-19 -19.0578 0.83512E+00 -0.0783 109 HSO4- 0.30046E-17 -17.5222 0.25164E-17 -17.5992 0.83753E+00 -0.0770 Charge balance for all species = -.6133E-08 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.8910172E-10 -.2223557E-01 -.2237313E+02 0.0000 2 H2O 0.1000000E+01 0.5550480E+02 0.9981962E+06 0.0000 3 Cl- 0.1562992E-03 0.1570169E-03 0.5557038E+01 6.2414 4 SO4-- 0.6719245E-10 -.1386906E-04 -.1329966E+01 9.7941 5 HCO3- 0.1538686E-04 0.5722200E-04 0.3485453E+01 5.2353 6 HS- 0.4273190E-04 0.5660931E-04 0.1868926E+01 5.6783 7 Al+++ 0.9805844E-29 0.5185017E-05 0.1396562E+00 0.7320 8 H4SiO4 0.7018272E-03 0.1353206E-01 0.1298377E+04 -3.1538 9 Ca++ 0.1196244E-06 0.2160929E-06 0.8645504E-02 13.0414 10 Mg++ 0.2114845E-10 0.9318191E-10 0.2261498E-05 9.2868 11 Fe++ 0.4502154E-13 0.2752587E-07 0.1534563E-02 6.6154 12 K+ 0.1565127E-03 0.1572599E-03 0.6138480E+01 6.2428 13 Na+ 0.1986191E-01 0.2230581E-01 0.5119140E+03 8.3454 14 Mn++ 0.1886665E-10 0.2507550E-08 0.1375201E-03 9.2381 15 F- 0.3462932E-06 0.3474141E-06 0.6588692E-02 3.5860 16 HPO4-- 0.4532343E-07 0.4642009E-07 0.4447603E-02 12.6231 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.1996947E-01 -.1996896E-01 -.5168306E-06 0.0000000E+00 2 H2O 0.4984684E+02 0.4984684E+02 -.4735496E-06 0.0000000E+00 3 Cl- 0.1410112E-03 0.1410112E-03 0.0000000E+00 0.0000000E+00 4 SO4-- -.1245431E-04 -.1245529E-04 0.9840357E-09 0.0000000E+00 5 HCO3- 0.5138900E-04 0.5138900E-04 0.0000000E+00 0.0000000E+00 6 HS- 0.5083778E-04 0.5083876E-04 -.9840357E-09 0.0000000E+00 7 Al+++ 0.4775352E-05 0.4656475E-05 0.1188767E-06 0.0000000E+00 8 H4SiO4 0.1215302E-01 0.1215265E-01 0.3662285E-06 0.0000000E+00 9 Ca++ 0.2080835E-06 0.1940651E-06 0.1401837E-07 0.0000000E+00 10 Mg++ 0.8368328E-10 0.8368328E-10 0.0000000E+00 0.0000000E+00 11 Fe++ 0.3259227E-07 0.2471998E-07 0.7872286E-08 0.0000000E+00 12 K+ 0.1412294E-03 0.1412294E-03 0.0000000E+00 0.0000000E+00 13 Na+ 0.2003215E-01 0.2003203E-01 0.1174034E-06 0.0000000E+00 14 Mn++ 0.2251939E-08 0.2251939E-08 0.0000000E+00 0.0000000E+00 15 F- 0.3120000E-06 0.3120000E-06 0.0000000E+00 0.0000000E+00 16 HPO4-- 0.4168819E-07 0.4168819E-07 0.0000000E+00 0.0000000E+00 Chg. balance for solid moles: 0.6617E-22 Mass of aqueous solution: 0.899629E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 0.0005300 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 0.1174E-06 -6.930 0.3079E-04 -4.512 92.96 0.1182E-04 andradite 0.3936E-08 -8.405 0.2000E-05 -5.699 6.040 0.5197E-06 grossular 0.7366E-09 -9.133 0.3318E-06 -6.479 1.002 0.9233E-07 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8424E+00 0.8424E+00 1.0000 -0.075 grossular 0.1576E+00 0.1576E+00 1.0000 -0.802 Solid products produced: Mass = 0.000033 g Volume = 0.000012 cm3 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.0005300 moles log = -3.2757 Original solution: 1000.0103000 g Original solution / Rock added: 1886811.89 (Water/Rock Ratio), log = 6.2757 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0446 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9770E+00 0.9856 0.1006E+01 0.1021E+01 CO2,gas 0.2094E-06 1.0069 0.2202E-06 0.2187E-06 CH4,gas 0.1780E-01 1.0123 0.1883E-01 0.1860E-01 H2,gas 0.5175E-02 1.0006 0.5409E-02 0.5406E-02 H2S,gas 0.2182E-06 0.9959 0.2270E-06 0.2279E-06 S2,gas 0.6328E-28 1.0000 0.6610E-28 0.6610E-28 CO,gas 0.3039E-12 1.0000 0.3175E-12 0.3175E-12 SO3,gas 0.7075E-46 1.0000 0.7391E-46 0.7391E-46 SO2,gas 0.1489E-25 1.0000 0.1555E-25 0.1555E-25 HF,gas 0.3476E-15 1.0000 0.3631E-15 0.3631E-15 HCl,gas 0.3025E-17 1.0000 0.3160E-17 0.3160E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 17 albite -0.38 -0.38 0.00 0.000 0.11184E-10 23 andradite 39.01 39.01 0.00 0.000 -0.24265E-10 24 grossular 32.73 32.73 0.00 0.000 0.12132E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -15.02 -8.36 -2.785 0.14268E+05 -6.657 3 CH4,gas 4.54 1.12 -3.42 -0.856 0.58467E+04 -1.725 4 H2,gas 8.00 4.03 -3.97 -2.266 0.67715E+04 -2.267 5 H2S,gas -6.23 -14.57 -8.34 -4.171 0.14245E+05 -6.644 6 S2,gas -7.34 -37.21 -29.88 -4.597 0.51017E+05 -28.180 7 CO,gas 3.21 -10.98 -14.20 -4.368 0.24241E+05 -12.498 8 SO3,gas 17.12 -30.71 -47.83 -11.958 0.81669E+05 -46.131 9 SO2,gas 0.83 -26.67 -27.51 -7.335 0.46968E+05 -25.808 10 HF,gas 0.47 -16.67 -17.14 -8.569 0.29264E+05 -15.440 11 HCl,gas 5.19 -14.01 -19.20 -9.600 0.32782E+05 -17.500 12 acmite 7.71 6.64 -1.07 -0.112 0.18327E+04 16 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 20 spessartine 24.46 19.72 -4.74 -0.237 0.80941E+04 21 analcite 3.32 2.77 -0.55 -0.061 0.94245E+03 27 annite 20.12 17.36 -2.76 -0.154 0.47187E+04 28 phlogopite 27.06 25.37 -1.69 -0.094 0.28867E+04 30 anorthite 12.71 8.20 -4.51 -0.347 0.77049E+04 33 apatite-OH -18.15 -18.43 -0.28 -0.021 0.47679E+03 34 apatite-F -34.30 -35.10 -0.80 -0.066 0.13612E+04 38 aragonite 0.97 -1.97 -2.94 -0.980 0.50223E+04 39 brucite 12.57 9.29 -3.28 -0.656 0.56035E+04 40 calcite 0.81 -1.97 -2.79 -0.929 0.47581E+04 41 carnegieite-low 9.02 5.92 -3.10 -0.443 0.52925E+04 42 carnegieite-high 10.09 5.92 -4.17 -0.596 0.71195E+04 43 carpholite-Mg 8.58 4.44 -4.14 -0.276 0.70669E+04 44 carpholite-Fe 6.71 1.77 -4.94 -0.329 0.84361E+04 45 celadonite 5.34 3.65 -1.70 -0.100 0.28943E+04 46 celadonite-Fe 3.88 0.98 -2.90 -0.171 0.49540E+04 47 chrysotile 23.89 21.55 -2.34 -0.195 0.39945E+04 49 clinochlore 39.07 38.44 -0.63 -0.020 0.10803E+04 50 daphnite 28.97 25.08 -3.89 -0.121 0.66341E+04 52 chlorite-Al-free 47.17 43.11 -4.07 -0.169 0.69442E+04 54 chloritoid-Fe 9.17 4.93 -4.25 -0.283 0.72532E+04 55 chloritoid-Mn 11.40 7.55 -3.85 -0.257 0.65785E+04 57 coesite -2.38 -3.15 -0.78 -0.259 0.13279E+04 64 cristobalite -2.56 -3.15 -0.59 -0.198 0.10133E+04 66 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71234E+04 68 diaspore 2.87 0.73 -2.14 -0.357 0.36569E+04 69 diamond -3.10 -6.95 -3.85 -1.099 0.65669E+04 70 diopside 16.18 16.02 -0.16 -0.016 0.27440E+03 71 hedenbergite 14.21 13.35 -0.86 -0.086 0.14667E+04 74 enstatite 17.26 12.27 -5.00 -0.500 0.85353E+04 76 clinoenstatite 17.17 12.27 -4.90 -0.490 0.83669E+04 78 epidote 24.67 22.68 -1.99 -0.096 0.33910E+04 79 clinozoisite 22.81 18.82 -3.99 -0.181 0.68104E+04 80 epidote-Fe 29.84 26.55 -3.29 -0.171 0.56183E+04 81 fayalite 14.05 10.08 -3.97 -0.567 0.67763E+04 82 ferrosilite 11.15 6.92 -4.23 -0.423 0.72160E+04 86 gibbsite 4.08 0.73 -3.35 -0.478 0.57154E+04 87 glaucophane 22.97 20.79 -2.19 -0.059 0.37387E+04 88 glaucophane-Fe 17.28 12.77 -4.50 -0.122 0.76917E+04 89 graphite -3.55 -6.95 -3.40 -0.972 0.58091E+04 90 greenalite 16.14 13.54 -2.60 -0.217 0.44406E+04 93 hematite 12.57 9.20 -3.37 -0.408 0.57529E+04 94 heulandite -5.83 -7.57 -1.74 -0.079 0.29774E+04 98 jadeite 4.22 2.77 -1.45 -0.145 0.24679E+04 100 kalsilite 7.58 3.82 -3.76 -0.538 0.64250E+04 101 kaolinite -1.33 -4.84 -3.51 -0.319 0.59945E+04 104 laumontite 2.88 1.89 -0.99 -0.066 0.16957E+04 105 lawsonite 9.62 8.20 -1.42 -0.095 0.24216E+04 106 leucite 4.12 0.67 -3.45 -0.345 0.58935E+04 108 lizardite 23.24 21.55 -1.69 -0.141 0.28872E+04 110 magnetite 20.09 15.81 -4.27 -0.349 0.72994E+04 111 minnesotaite 10.39 7.23 -3.16 -0.186 0.53902E+04 115 manganosite 14.06 9.24 -4.82 -1.205 0.82301E+04 119 microcline -2.49 -2.49 0.00 0.000 0.44687E-01 123 muscovite 2.58 -1.02 -3.60 -0.212 0.61553E+04 124 paragonite 4.24 1.08 -3.16 -0.186 0.53944E+04 125 nepheline 8.34 5.92 -2.42 -0.345 0.41249E+04 137 phlogopite-Na 29.65 27.48 -2.17 -0.121 0.37055E+04 139 prehnite 19.37 18.09 -1.29 -0.076 0.21966E+04 140 prehnite-Fe 22.50 21.95 -0.55 -0.033 0.93221E+03 141 pumpellyite-Fe 46.27 43.52 -2.75 -0.061 0.46974E+04 142 pumpellyite-Mg 48.99 46.19 -2.81 -0.062 0.47898E+04 146 pyrrhotite -4.26 -7.96 -3.70 -1.232 0.63132E+04 147 pyrrhotiteFe0.875 -6.02 -9.28 -3.27 -1.202 0.55799E+04 148 pyroxmangite 7.40 6.08 -1.31 -0.263 0.22442E+04 149 pyrophyllite -6.18 -11.15 -4.98 -0.311 0.84951E+04 150 quartz -2.99 -3.15 -0.16 -0.055 0.28060E+03 154 rhodochrosite -0.98 -5.78 -4.80 -1.601 0.81990E+04 155 rhodonite 7.45 6.08 -1.36 -0.272 0.23245E+04 156 sanidine -1.28 -2.49 -1.21 -0.093 0.20678E+04 166 stilbite -7.52 -7.57 -0.05 -0.002 0.83593E+02 167 stilpnomelane-Fe 13.02 12.43 -0.58 -0.017 0.99800E+03 168 stilpnomelane-Mg 27.44 25.79 -1.65 -0.049 0.28208E+04 174 talc 16.49 15.25 -1.25 -0.073 0.21269E+04 177 tephroite 18.09 15.32 -2.76 -0.395 0.47184E+04 181 tridymite -2.63 -3.15 -0.53 -0.176 0.90057E+03 182 tremolite 47.87 47.29 -0.58 -0.016 0.99468E+03 183 ferroactinolite 38.45 33.93 -4.52 -0.122 0.77222E+04 184 troilite-low -4.41 -7.96 -3.55 -1.182 0.60560E+04 190 wairakite 3.95 1.89 -2.06 -0.121 0.35177E+04 191 walstromite 11.51 9.89 -1.62 -0.324 0.27689E+04 192 wollastonite 10.46 9.89 -0.57 -0.115 0.97933E+03 193 pseudo-wollastonite 11.00 9.89 -1.11 -0.222 0.18992E+04 194 zoisite 22.85 18.82 -4.03 -0.183 0.68845E+04 195 akaganeite 7.75 4.60 -3.16 -0.682 0.53890E+04 202 chalcedony -2.80 -3.15 -0.35 -0.117 0.59989E+03 204 montmorillonite-Ca -2.29 -6.18 -3.89 -0.240 0.66343E+04 205 montmorillonite-K -2.24 -6.27 -4.03 -0.247 0.68831E+04 206 montmorillonite-Mg -2.48 -6.80 -4.32 -0.267 0.73691E+04 207 montmorillonite-Na -2.04 -5.57 -3.54 -0.217 0.60379E+04 208 nontronite-Ca 3.21 0.02 -3.20 -0.207 0.54614E+04 209 nontronite-H 2.53 -2.14 -4.67 -0.313 0.79714E+04 210 nontronite-K 3.34 -0.08 -3.42 -0.219 0.58334E+04 211 nontronite-Mg 3.07 -0.60 -3.68 -0.239 0.62803E+04 212 nontronite-Na 3.52 0.62 -2.90 -0.186 0.49543E+04 228 tobermorite 9.82 7.71 -2.11 -0.577 0.36085E+04 234 alabandite -0.98 -5.34 -4.36 -1.452 0.74399E+04 237 boehmite 4.41 0.73 -3.67 -0.612 0.62738E+04 239 ferrous-oxide 9.81 6.62 -3.20 -0.799 0.54573E+04 245 silica-amorphous -2.09 -3.15 -1.06 -0.354 0.18141E+04 247 an20ab80 2.02 1.33 -0.69 -0.053 0.11701E+04 248 an25ab75 2.65 1.76 -0.88 -0.068 0.15096E+04 249 an30ab70 3.28 2.19 -1.09 -0.084 0.18588E+04 250 tr.625ac.25prg.125 45.16 44.89 -0.27 -0.007 0.46441E+03 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 0.0000200 MOLES Current total amount of reactant added: 0.0005300 MOLES New total amount of reactant added: 0.0005500 MOLES Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.5508E-08 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 6 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 0.0005500 Water: Moles liquid = 0.4985E+02 kg liquid = 0.8981E+00 Moles total = 0.4985E+02 kg total = 0.8980E+00 Activity = 1.0000 Stoichiometric ionic strength = .1136529E-01 Osmotic coef. = 0.9676 True ionic strength = .2004909E-01 Chg. balance for total moles = -.5508E-08 Max. difference allowed = 0.1411E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.89133E-10 -10.0500 0.74887E-10 -10.1256 0.84017E+00 -0.0756 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.15643E-03 -3.8057 0.13064E-03 -3.8839 0.83511E+00 -0.0783 4 SO4-- 0.71198E-10 -10.1475 0.36959E-10 -10.4323 0.51910E+00 -0.2847 5 HCO3- 0.15981E-04 -4.7964 0.13366E-04 -4.8740 0.83634E+00 -0.0776 6 HS- 0.43273E-04 -4.3638 0.36143E-04 -4.4420 0.83524E+00 -0.0782 7 Al+++ 0.98103E-29 -29.0083 0.22644E-29 -29.6450 0.23082E+00 -0.6367 8 H4SiO4 0.70206E-03 -3.1536 0.70206E-03 -3.1536 0.10000E+01 0.0000 9 Ca++ 0.11937E-06 -6.9231 0.61507E-07 -7.2111 0.51529E+00 -0.2880 10 Mg++ 0.21150E-10 -10.6747 0.10848E-10 -10.9646 0.51293E+00 -0.2899 11 Fe++ 0.45007E-13 -13.3467 0.23111E-13 -13.6362 0.51349E+00 -0.2895 12 K+ 0.15651E-03 -3.8054 0.13093E-03 -3.8830 0.83654E+00 -0.0775 13 Na+ 0.19862E-01 -1.7020 0.16584E-01 -1.7803 0.83496E+00 -0.0783 14 Mn++ 0.18880E-10 -10.7240 0.97024E-11 -11.0131 0.51391E+00 -0.2891 15 F- 0.35517E-06 -6.4496 0.29600E-06 -6.5287 0.83339E+00 -0.0792 16 HPO4-- 0.45324E-07 -7.3437 0.23531E-07 -7.6284 0.51917E+00 -0.2847 18 HSiO3- 0.10482E-01 -1.9796 0.87537E-02 -2.0578 0.83511E+00 -0.0783 19 Ca(HSiO3)+ 0.14655E-07 -7.8340 0.12262E-07 -7.9114 0.83672E+00 -0.0774 20 Mg(HSiO3)+ 0.32167E-11 -11.4926 0.26914E-11 -11.5700 0.83672E+00 -0.0774 21 NaHSiO3,aq 0.23479E-02 -2.6293 0.23479E-02 -2.6293 0.10000E+01 0.0000 22 AlO+ 0.65651E-16 -16.1828 0.54931E-16 -16.2602 0.83672E+00 -0.0774 24 HAlO2,aq 0.14608E-09 -9.8354 0.14608E-09 -9.8354 0.10000E+01 0.0000 25 AlO2- 0.51798E-05 -5.2857 0.43179E-05 -5.3647 0.83360E+00 -0.0790 26 CH4,aq 0.12741E-04 -4.8948 0.12697E-04 -4.8963 0.99653E+00 -0.0015 27 C2H6,aq 0.67892E-14 -14.1682 0.67657E-14 -14.1697 0.99653E+00 -0.0015 31 CO,aq 0.21885E-15 -15.6598 0.21885E-15 -15.6598 0.10000E+01 0.0000 32 CO2,aq 0.21462E-08 -8.6683 0.21388E-08 -8.6698 0.99653E+00 -0.0015 33 CO3-2 0.30096E-04 -4.5215 0.15589E-04 -4.8072 0.51800E+00 -0.2857 34 CaCO3,aq 0.12023E-07 -7.9200 0.12023E-07 -7.9200 0.10000E+01 0.0000 35 Ca(HCO3)+ 0.25080E-10 -10.6007 0.20985E-10 -10.6781 0.83672E+00 -0.0774 36 CaCl+ 0.15541E-10 -10.8085 0.13003E-10 -10.8859 0.83672E+00 -0.0774 37 CaCl2,aq 0.40358E-15 -15.3941 0.40358E-15 -15.3941 0.10000E+01 0.0000 38 CaF+ 0.31768E-12 -12.4980 0.26581E-12 -12.5754 0.83672E+00 -0.0774 39 CaOH+ 0.69959E-07 -7.1552 0.58536E-07 -7.2326 0.83672E+00 -0.0774 40 CaSO4,aq 0.72186E-15 -15.1415 0.72186E-15 -15.1415 0.10000E+01 0.0000 41 HCl,aq 0.17927E-14 -14.7465 0.17927E-14 -14.7465 0.10000E+01 0.0000 45 HF,aq 0.15175E-12 -12.8189 0.15175E-12 -12.8189 0.10000E+01 0.0000 46 HF2- 0.18159E-19 -19.7409 0.15165E-19 -19.8192 0.83511E+00 -0.0783 48 FeCl+ 0.57113E-17 -17.2433 0.47787E-17 -17.3207 0.83672E+00 -0.0774 51 FeF+ 0.41779E-18 -18.3790 0.34957E-18 -18.4565 0.83672E+00 -0.0774 53 FeO,aq 0.16016E-09 -9.7954 0.16016E-09 -9.7954 0.10000E+01 0.0000 54 FeOH+ 0.12006E-10 -10.9206 0.10045E-10 -10.9980 0.83672E+00 -0.0774 55 HFeO2- 0.26796E-07 -7.5719 0.22378E-07 -7.6502 0.83511E+00 -0.0783 56 FeO+ 0.14188E-16 -16.8481 0.11872E-16 -16.9255 0.83672E+00 -0.0774 58 FeO2- 0.51868E-09 -9.2851 0.43316E-09 -9.3634 0.83511E+00 -0.0783 59 HFeO2,aq 0.41256E-11 -11.3845 0.41256E-11 -11.3845 0.10000E+01 0.0000 60 H2,aq 0.40876E-05 -5.3885 0.40734E-05 -5.3900 0.99653E+00 -0.0015 61 KCl,aq 0.31000E-09 -9.5086 0.31000E-09 -9.5086 0.10000E+01 0.0000 63 KOH,aq 0.74664E-06 -6.1269 0.74664E-06 -6.1269 0.10000E+01 0.0000 64 KSO4- 0.89914E-13 -13.0462 0.75089E-13 -13.1244 0.83511E+00 -0.0783 65 MgCO3,aq 0.53153E-12 -12.2745 0.53153E-12 -12.2745 0.10000E+01 0.0000 66 Mg(HCO3)+ 0.45199E-14 -14.3449 0.37819E-14 -14.4223 0.83672E+00 -0.0774 67 MgCl+ 0.24843E-14 -14.6048 0.20786E-14 -14.6822 0.83672E+00 -0.0774 68 MgF+ 0.20755E-15 -15.6829 0.17366E-15 -15.7603 0.83672E+00 -0.0774 69 MgOH+ 0.68277E-10 -10.1657 0.57128E-10 -10.2431 0.83672E+00 -0.0774 71 MnF+ 0.57813E-16 -16.2380 0.48373E-16 -16.3154 0.83672E+00 -0.0774 72 MnO,aq 0.17917E-08 -8.7467 0.17917E-08 -8.7467 0.10000E+01 0.0000 73 MnOH+ 0.46823E-09 -9.3295 0.39178E-09 -9.4070 0.83672E+00 -0.0774 74 MnO2-2 0.20468E-10 -10.6889 0.10603E-10 -10.9746 0.51800E+00 -0.2857 75 HMnO2- 0.20830E-09 -9.6813 0.17395E-09 -9.7596 0.83511E+00 -0.0783 78 MnCl+ 0.93283E-14 -14.0302 0.78052E-14 -14.1076 0.83672E+00 -0.0774 79 MnSO4,aq 0.10352E-18 -18.9850 0.10352E-18 -18.9850 0.10000E+01 0.0000 80 NaCl,aq 0.71798E-06 -6.1439 0.71798E-06 -6.1439 0.10000E+01 0.0000 81 NaF,aq 0.11492E-08 -8.9396 0.11492E-08 -8.9396 0.10000E+01 0.0000 82 NaOH,aq 0.95147E-04 -4.0216 0.95147E-04 -4.0216 0.10000E+01 0.0000 84 OH- 0.92553E-02 -2.0336 0.77152E-02 -2.1127 0.83360E+00 -0.0790 89 HPO3-2 0.57665E-15 -15.2391 0.29870E-15 -15.5248 0.51800E+00 -0.2857 91 H2PO3- 0.53714E-19 -19.2699 0.44857E-19 -19.3482 0.83511E+00 -0.0783 92 H3PO4,aq 0.92295E-18 -18.0348 0.92295E-18 -18.0348 0.10000E+01 0.0000 93 H2PO4- 0.38889E-10 -10.4102 0.32507E-10 -10.4880 0.83591E+00 -0.0778 94 PO4-3 0.10574E-08 -8.9757 0.25637E-09 -9.5911 0.24244E+00 -0.6154 98 HP2O7-3 0.95618E-18 -18.0195 0.22093E-18 -18.6558 0.23105E+00 -0.6363 99 P2O7-4 0.91547E-17 -17.0384 0.70478E-18 -18.1519 0.76985E-01 -1.1136 100 H2S,aq 0.83944E-08 -8.0760 0.83653E-08 -8.0775 0.99653E+00 -0.0015 101 S2-2 0.13718E-13 -13.8627 0.71060E-14 -14.1484 0.51800E+00 -0.2857 107 SO3-2 0.37229E-16 -16.4291 0.19564E-16 -16.7086 0.52550E+00 -0.2794 108 HSO3- 0.10984E-18 -18.9592 0.91731E-19 -19.0375 0.83511E+00 -0.0783 109 HSO4- 0.31847E-17 -17.4969 0.26673E-17 -17.5739 0.83753E+00 -0.0770 Charge balance for all species = -.6133E-08 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.8913339E-10 -.2223314E-01 -.2237069E+02 0.0000 2 H2O 0.1000000E+01 0.5550480E+02 0.9981961E+06 0.0000 3 Cl- 0.1564300E-03 0.1571483E-03 0.5561686E+01 6.2417 4 SO4-- 0.7119755E-10 -.1376271E-04 -.1319768E+01 9.8189 5 HCO3- 0.1598137E-04 0.5883211E-04 0.3583526E+01 5.2516 6 HS- 0.4327294E-04 0.5704412E-04 0.1883281E+01 5.6836 7 Al+++ 0.9810311E-29 0.5179924E-05 0.1395190E+00 0.7317 8 H4SiO4 0.7020582E-03 0.1353204E-01 0.1298375E+04 -3.1536 9 Ca++ 0.1193656E-06 0.2160433E-06 0.8643522E-02 13.0401 10 Mg++ 0.2114962E-10 0.9318187E-10 0.2261497E-05 9.2865 11 Fe++ 0.4500715E-13 0.2749076E-07 0.1532606E-02 6.6150 12 K+ 0.1565129E-03 0.1572598E-03 0.6138477E+01 6.2426 13 Na+ 0.1986198E-01 0.2230579E-01 0.5119136E+03 8.3453 14 Mn++ 0.1887952E-10 0.2507549E-08 0.1375201E-03 9.2381 15 F- 0.3551723E-06 0.3563221E-06 0.6757630E-02 3.5969 16 HPO4-- 0.4532375E-07 0.4642007E-07 0.4447601E-02 12.6228 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.1996732E-01 -.1996678E-01 -.5352703E-06 0.0000000E+00 2 H2O 0.4984686E+02 0.4984686E+02 -.4918629E-06 0.0000000E+00 3 Cl- 0.1411292E-03 0.1411292E-03 0.0000000E+00 0.0000000E+00 4 SO4-- -.1235881E-04 -.1235980E-04 0.9879758E-09 0.0000000E+00 5 HCO3- 0.5283500E-04 0.5283500E-04 0.0000000E+00 0.0000000E+00 6 HS- 0.5122828E-04 0.5122927E-04 -.9879758E-09 0.0000000E+00 7 Al+++ 0.4775352E-05 0.4651903E-05 0.1234491E-06 0.0000000E+00 8 H4SiO4 0.1215302E-01 0.1215264E-01 0.3799960E-06 0.0000000E+00 9 Ca++ 0.2080835E-06 0.1940207E-06 0.1406276E-07 0.0000000E+00 10 Mg++ 0.8368328E-10 0.8368328E-10 0.0000000E+00 0.0000000E+00 11 Fe++ 0.3259227E-07 0.2468846E-07 0.7903807E-08 0.0000000E+00 12 K+ 0.1412294E-03 0.1412294E-03 0.0000000E+00 0.0000000E+00 13 Na+ 0.2003215E-01 0.2003203E-01 0.1219777E-06 0.0000000E+00 14 Mn++ 0.2251939E-08 0.2251939E-08 0.0000000E+00 0.0000000E+00 15 F- 0.3200000E-06 0.3200000E-06 0.0000000E+00 0.0000000E+00 16 HPO4-- 0.4168819E-07 0.4168819E-07 0.0000000E+00 0.0000000E+00 Chg. balance for solid moles: 0.2647E-22 Mass of aqueous solution: 0.899629E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 0.0005500 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 0.1220E-06 -6.914 0.3199E-04 -4.495 93.18 0.1228E-04 andradite 0.3952E-08 -8.403 0.2008E-05 -5.697 5.851 0.5218E-06 grossular 0.7357E-09 -9.133 0.3314E-06 -6.480 0.9655 0.9221E-07 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8431E+00 0.8431E+00 1.0000 -0.074 grossular 0.1569E+00 0.1569E+00 1.0000 -0.804 Solid products produced: Mass = 0.000034 g Volume = 0.000013 cm3 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.0005500 moles log = -3.2596 Original solution: 1000.0103000 g Original solution / Rock added: 1818200.55 (Water/Rock Ratio), log = 6.2596 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0444 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9772E+00 0.9856 0.1006E+01 0.1021E+01 CO2,gas 0.2176E-06 1.0069 0.2288E-06 0.2273E-06 CH4,gas 0.1768E-01 1.0123 0.1869E-01 0.1846E-01 H2,gas 0.5118E-02 1.0006 0.5348E-02 0.5345E-02 H2S,gas 0.2211E-06 0.9959 0.2300E-06 0.2309E-06 S2,gas 0.6645E-28 1.0000 0.6940E-28 0.6940E-28 CO,gas 0.3123E-12 1.0000 0.3261E-12 0.3261E-12 SO3,gas 0.7503E-46 1.0000 0.7837E-46 0.7837E-46 SO2,gas 0.1561E-25 1.0000 0.1631E-25 0.1631E-25 HF,gas 0.3567E-15 1.0000 0.3726E-15 0.3726E-15 HCl,gas 0.3029E-17 1.0000 0.3163E-17 0.3163E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 17 albite -0.38 -0.38 0.00 0.000 -0.13080E-10 23 andradite 39.01 39.01 0.00 0.000 -0.12132E-10 24 grossular 32.73 32.73 0.00 0.000 0.00000E+00 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -15.00 -8.34 -2.780 0.14239E+05 -6.640 3 CH4,gas 4.54 1.12 -3.43 -0.857 0.58522E+04 -1.728 4 H2,gas 8.00 4.03 -3.97 -2.269 0.67800E+04 -2.272 5 H2S,gas -6.23 -14.57 -8.34 -4.169 0.14236E+05 -6.638 6 S2,gas -7.34 -37.19 -29.86 -4.593 0.50981E+05 -28.159 7 CO,gas 3.21 -10.97 -14.19 -4.365 0.24221E+05 -12.487 8 SO3,gas 17.12 -30.68 -47.80 -11.951 0.81625E+05 -46.106 9 SO2,gas 0.83 -26.65 -27.49 -7.330 0.46933E+05 -25.788 10 HF,gas 0.47 -16.65 -17.13 -8.564 0.29245E+05 -15.429 11 HCl,gas 5.19 -14.01 -19.20 -9.599 0.32781E+05 -17.500 12 acmite 7.71 6.64 -1.07 -0.111 0.18290E+04 16 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 20 spessartine 24.46 19.72 -4.74 -0.237 0.80944E+04 21 analcite 3.32 2.77 -0.55 -0.061 0.94270E+03 27 annite 20.12 17.36 -2.76 -0.154 0.47210E+04 28 phlogopite 27.06 25.37 -1.69 -0.094 0.28882E+04 30 anorthite 12.71 8.20 -4.51 -0.347 0.77075E+04 33 apatite-OH -18.15 -18.44 -0.28 -0.022 0.48594E+03 34 apatite-F -34.30 -35.09 -0.79 -0.066 0.13513E+04 38 aragonite 0.97 -1.96 -2.93 -0.975 0.49961E+04 39 brucite 12.57 9.29 -3.28 -0.656 0.56040E+04 40 calcite 0.81 -1.96 -2.77 -0.924 0.47319E+04 41 carnegieite-low 9.02 5.92 -3.10 -0.443 0.52930E+04 42 carnegieite-high 10.09 5.92 -4.17 -0.596 0.71200E+04 43 carpholite-Mg 8.58 4.44 -4.14 -0.276 0.70678E+04 44 carpholite-Fe 6.71 1.77 -4.94 -0.329 0.84374E+04 45 celadonite 5.34 3.65 -1.70 -0.100 0.28945E+04 46 celadonite-Fe 3.88 0.97 -2.90 -0.171 0.49545E+04 47 chrysotile 23.89 21.55 -2.34 -0.195 0.39955E+04 49 clinochlore 39.07 38.44 -0.63 -0.020 0.10829E+04 50 daphnite 28.97 25.08 -3.89 -0.121 0.66381E+04 52 chlorite-Al-free 47.17 43.10 -4.07 -0.170 0.69462E+04 54 chloritoid-Fe 9.17 4.92 -4.25 -0.283 0.72547E+04 55 chloritoid-Mn 11.40 7.55 -3.85 -0.257 0.65792E+04 57 coesite -2.38 -3.15 -0.78 -0.259 0.13277E+04 64 cristobalite -2.56 -3.15 -0.59 -0.198 0.10130E+04 66 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71234E+04 68 diaspore 2.87 0.73 -2.14 -0.357 0.36573E+04 69 diamond -3.10 -6.94 -3.84 -1.097 0.65554E+04 70 diopside 16.18 16.02 -0.16 -0.016 0.27654E+03 71 hedenbergite 14.21 13.35 -0.86 -0.086 0.14692E+04 74 enstatite 17.26 12.27 -5.00 -0.500 0.85358E+04 76 clinoenstatite 17.17 12.27 -4.90 -0.490 0.83674E+04 78 epidote 24.67 22.68 -1.99 -0.096 0.33921E+04 79 clinozoisite 22.81 18.81 -3.99 -0.181 0.68154E+04 80 epidote-Fe 29.84 26.55 -3.29 -0.171 0.56154E+04 81 fayalite 14.05 10.08 -3.97 -0.567 0.67776E+04 82 ferrosilite 11.15 6.92 -4.23 -0.423 0.72170E+04 86 gibbsite 4.08 0.73 -3.35 -0.478 0.57159E+04 87 glaucophane 22.97 20.78 -2.19 -0.059 0.37397E+04 88 glaucophane-Fe 17.28 12.77 -4.51 -0.122 0.76936E+04 89 graphite -3.55 -6.94 -3.40 -0.970 0.57977E+04 90 greenalite 16.14 13.54 -2.60 -0.217 0.44425E+04 93 hematite 12.57 9.20 -3.37 -0.408 0.57459E+04 94 heulandite -5.83 -7.57 -1.74 -0.079 0.29788E+04 98 jadeite 4.22 2.77 -1.45 -0.145 0.24682E+04 100 kalsilite 7.58 3.82 -3.76 -0.538 0.64255E+04 101 kaolinite -1.33 -4.84 -3.51 -0.319 0.59950E+04 104 laumontite 2.88 1.89 -0.99 -0.066 0.16978E+04 105 lawsonite 9.62 8.20 -1.42 -0.095 0.24242E+04 106 leucite 4.12 0.67 -3.45 -0.345 0.58938E+04 108 lizardite 23.24 21.55 -1.69 -0.141 0.28882E+04 110 magnetite 20.09 15.82 -4.27 -0.349 0.72933E+04 111 minnesotaite 10.39 7.23 -3.16 -0.186 0.53916E+04 115 manganosite 14.06 9.24 -4.82 -1.205 0.82301E+04 119 microcline -2.49 -2.49 0.00 0.000 0.46386E-01 123 muscovite 2.58 -1.02 -3.61 -0.212 0.61563E+04 124 paragonite 4.24 1.08 -3.16 -0.186 0.53953E+04 125 nepheline 8.34 5.92 -2.42 -0.345 0.41254E+04 137 phlogopite-Na 29.65 27.48 -2.17 -0.121 0.37070E+04 139 prehnite 19.37 18.08 -1.29 -0.076 0.22011E+04 140 prehnite-Fe 22.50 21.95 -0.55 -0.033 0.93277E+03 141 pumpellyite-Fe 46.27 43.51 -2.76 -0.061 0.47077E+04 142 pumpellyite-Mg 48.99 46.18 -2.81 -0.062 0.47997E+04 146 pyrrhotite -4.26 -7.95 -3.69 -1.231 0.63044E+04 147 pyrrhotiteFe0.875 -6.02 -9.28 -3.26 -1.200 0.55699E+04 148 pyroxmangite 7.40 6.08 -1.31 -0.263 0.22440E+04 149 pyrophyllite -6.18 -11.15 -4.98 -0.311 0.84951E+04 150 quartz -2.99 -3.15 -0.16 -0.055 0.28035E+03 154 rhodochrosite -0.98 -5.76 -4.79 -1.595 0.81706E+04 155 rhodonite 7.45 6.08 -1.36 -0.272 0.23243E+04 156 sanidine -1.28 -2.49 -1.21 -0.093 0.20678E+04 166 stilbite -7.52 -7.57 -0.05 -0.002 0.84967E+02 167 stilpnomelane-Fe 13.02 12.43 -0.59 -0.017 0.10010E+04 168 stilpnomelane-Mg 27.44 25.79 -1.65 -0.049 0.28224E+04 174 talc 16.49 15.25 -1.25 -0.073 0.21274E+04 177 tephroite 18.09 15.32 -2.76 -0.395 0.47182E+04 181 tridymite -2.63 -3.15 -0.53 -0.176 0.90033E+03 182 tremolite 47.87 47.28 -0.59 -0.016 0.99947E+03 183 ferroactinolite 38.45 33.93 -4.53 -0.122 0.77283E+04 184 troilite-low -4.41 -7.95 -3.54 -1.181 0.60472E+04 190 wairakite 3.95 1.89 -2.06 -0.121 0.35198E+04 191 walstromite 11.51 9.89 -1.62 -0.325 0.27708E+04 192 wollastonite 10.46 9.89 -0.57 -0.115 0.98122E+03 193 pseudo-wollastonite 11.00 9.89 -1.11 -0.223 0.19011E+04 194 zoisite 22.85 18.81 -4.03 -0.183 0.68894E+04 195 akaganeite 7.75 4.60 -3.15 -0.682 0.53855E+04 202 chalcedony -2.80 -3.15 -0.35 -0.117 0.59965E+03 204 montmorillonite-Ca -2.29 -6.18 -3.89 -0.240 0.66346E+04 205 montmorillonite-K -2.24 -6.27 -4.03 -0.247 0.68831E+04 206 montmorillonite-Mg -2.48 -6.80 -4.32 -0.267 0.73691E+04 207 montmorillonite-Na -2.04 -5.57 -3.54 -0.217 0.60380E+04 208 nontronite-Ca 3.21 0.02 -3.19 -0.207 0.54541E+04 209 nontronite-H 2.53 -2.13 -4.66 -0.313 0.79637E+04 210 nontronite-K 3.34 -0.07 -3.41 -0.219 0.58258E+04 211 nontronite-Mg 3.07 -0.60 -3.67 -0.238 0.62727E+04 212 nontronite-Na 3.52 0.62 -2.90 -0.186 0.49467E+04 228 tobermorite 9.82 7.71 -2.11 -0.577 0.36101E+04 234 alabandite -0.98 -5.33 -4.35 -1.451 0.74303E+04 237 boehmite 4.41 0.73 -3.67 -0.612 0.62743E+04 239 ferrous-oxide 9.81 6.61 -3.20 -0.799 0.54581E+04 245 silica-amorphous -2.09 -3.15 -1.06 -0.354 0.18138E+04 247 an20ab80 2.02 1.33 -0.69 -0.053 0.11707E+04 248 an25ab75 2.65 1.76 -0.88 -0.068 0.15103E+04 249 an30ab70 3.28 2.19 -1.09 -0.084 0.18595E+04 250 tr.625ac.25prg.125 45.16 44.89 -0.28 -0.007 0.46976E+03 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 0.0000200 MOLES Current total amount of reactant added: 0.0005500 MOLES New total amount of reactant added: 0.0005700 MOLES Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.5508E-08 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 6 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 0.0005700 Water: Moles liquid = 0.4985E+02 kg liquid = 0.8981E+00 Moles total = 0.4985E+02 kg total = 0.8980E+00 Activity = 1.0000 Stoichiometric ionic strength = .1136657E-01 Osmotic coef. = 0.9675 True ionic strength = .2005027E-01 Chg. balance for total moles = -.5508E-08 Max. difference allowed = 0.1412E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.89165E-10 -10.0498 0.74914E-10 -10.1254 0.84017E+00 -0.0756 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.15656E-03 -3.8053 0.13075E-03 -3.8836 0.83511E+00 -0.0783 4 SO4-- 0.75334E-10 -10.1230 0.39105E-10 -10.4078 0.51909E+00 -0.2848 5 HCO3- 0.16576E-04 -4.7805 0.13863E-04 -4.8581 0.83633E+00 -0.0776 6 HS- 0.43814E-04 -4.3584 0.36595E-04 -4.4366 0.83523E+00 -0.0782 7 Al+++ 0.98148E-29 -29.0081 0.22654E-29 -29.6449 0.23081E+00 -0.6367 8 H4SiO4 0.70229E-03 -3.1535 0.70229E-03 -3.1535 0.10000E+01 0.0000 9 Ca++ 0.11911E-06 -6.9240 0.61375E-07 -7.2120 0.51528E+00 -0.2880 10 Mg++ 0.21151E-10 -10.6747 0.10849E-10 -10.9646 0.51292E+00 -0.2900 11 Fe++ 0.44998E-13 -13.3468 0.23105E-13 -13.6363 0.51348E+00 -0.2895 12 K+ 0.15651E-03 -3.8054 0.13093E-03 -3.8830 0.83653E+00 -0.0775 13 Na+ 0.19862E-01 -1.7020 0.16584E-01 -1.7803 0.83496E+00 -0.0783 14 Mn++ 0.18892E-10 -10.7237 0.97089E-11 -11.0128 0.51391E+00 -0.2891 15 F- 0.36405E-06 -6.4388 0.30340E-06 -6.5180 0.83339E+00 -0.0792 16 HPO4-- 0.45324E-07 -7.3437 0.23531E-07 -7.6284 0.51917E+00 -0.2847 18 HSiO3- 0.10482E-01 -1.9796 0.87535E-02 -2.0578 0.83511E+00 -0.0783 19 Ca(HSiO3)+ 0.14623E-07 -7.8350 0.12235E-07 -7.9124 0.83671E+00 -0.0774 20 Mg(HSiO3)+ 0.32167E-11 -11.4926 0.26915E-11 -11.5700 0.83671E+00 -0.0774 21 NaHSiO3,aq 0.23479E-02 -2.6293 0.23479E-02 -2.6293 0.10000E+01 0.0000 22 AlO+ 0.65632E-16 -16.1829 0.54915E-16 -16.2603 0.83671E+00 -0.0774 24 HAlO2,aq 0.14598E-09 -9.8357 0.14598E-09 -9.8357 0.10000E+01 0.0000 25 AlO2- 0.51747E-05 -5.2861 0.43136E-05 -5.3652 0.83360E+00 -0.0790 26 CH4,aq 0.12646E-04 -4.8981 0.12602E-04 -4.8996 0.99653E+00 -0.0015 27 C2H6,aq 0.67629E-14 -14.1699 0.67395E-14 -14.1714 0.99653E+00 -0.0015 31 CO,aq 0.22457E-15 -15.6486 0.22457E-15 -15.6486 0.10000E+01 0.0000 32 CO2,aq 0.22269E-08 -8.6523 0.22191E-08 -8.6538 0.99653E+00 -0.0015 33 CO3-2 0.31205E-04 -4.5058 0.16164E-04 -4.7915 0.51799E+00 -0.2857 34 CaCO3,aq 0.12439E-07 -7.9052 0.12439E-07 -7.9052 0.10000E+01 0.0000 35 Ca(HCO3)+ 0.25958E-10 -10.5857 0.21719E-10 -10.6632 0.83671E+00 -0.0774 36 CaCl+ 0.15520E-10 -10.8091 0.12986E-10 -10.8865 0.83671E+00 -0.0774 37 CaCl2,aq 0.40338E-15 -15.3943 0.40338E-15 -15.3943 0.10000E+01 0.0000 38 CaF+ 0.32492E-12 -12.4882 0.27187E-12 -12.5656 0.83671E+00 -0.0774 39 CaOH+ 0.69784E-07 -7.1562 0.58389E-07 -7.2337 0.83671E+00 -0.0774 40 CaSO4,aq 0.76214E-15 -15.1180 0.76214E-15 -15.1180 0.10000E+01 0.0000 41 HCl,aq 0.17948E-14 -14.7460 0.17948E-14 -14.7460 0.10000E+01 0.0000 45 HF,aq 0.15559E-12 -12.8080 0.15559E-12 -12.8080 0.10000E+01 0.0000 46 HF2- 0.19085E-19 -19.7193 0.15938E-19 -19.7976 0.83511E+00 -0.0783 48 FeCl+ 0.57148E-17 -17.2430 0.47816E-17 -17.3204 0.83671E+00 -0.0774 51 FeF+ 0.42814E-18 -18.3684 0.35823E-18 -18.4458 0.83671E+00 -0.0774 53 FeO,aq 0.16001E-09 -9.7958 0.16001E-09 -9.7958 0.10000E+01 0.0000 54 FeOH+ 0.11999E-10 -10.9209 0.10040E-10 -10.9983 0.83671E+00 -0.0774 55 HFeO2- 0.26761E-07 -7.5725 0.22349E-07 -7.6507 0.83511E+00 -0.0783 56 FeO+ 0.14259E-16 -16.8459 0.11931E-16 -16.9233 0.83671E+00 -0.0774 58 FeO2- 0.52090E-09 -9.2832 0.43501E-09 -9.3615 0.83511E+00 -0.0783 59 HFeO2,aq 0.41447E-11 -11.3825 0.41447E-11 -11.3825 0.10000E+01 0.0000 60 H2,aq 0.40425E-05 -5.3934 0.40285E-05 -5.3949 0.99653E+00 -0.0015 61 KCl,aq 0.31026E-09 -9.5083 0.31026E-09 -9.5083 0.10000E+01 0.0000 63 KOH,aq 0.74638E-06 -6.1270 0.74638E-06 -6.1270 0.10000E+01 0.0000 64 KSO4- 0.95137E-13 -13.0217 0.79450E-13 -13.0999 0.83511E+00 -0.0783 65 MgCO3,aq 0.55114E-12 -12.2587 0.55114E-12 -12.2587 0.10000E+01 0.0000 66 Mg(HCO3)+ 0.46884E-14 -14.3290 0.39228E-14 -14.4064 0.83671E+00 -0.0774 67 MgCl+ 0.24865E-14 -14.6044 0.20804E-14 -14.6818 0.83671E+00 -0.0774 68 MgF+ 0.21275E-15 -15.6721 0.17801E-15 -15.7496 0.83671E+00 -0.0774 69 MgOH+ 0.68256E-10 -10.1659 0.57110E-10 -10.2433 0.83671E+00 -0.0774 71 MnF+ 0.59298E-16 -16.2270 0.49615E-16 -16.3044 0.83671E+00 -0.0774 72 MnO,aq 0.17916E-08 -8.7468 0.17916E-08 -8.7468 0.10000E+01 0.0000 73 MnOH+ 0.46838E-09 -9.3294 0.39190E-09 -9.4068 0.83671E+00 -0.0774 74 MnO2-2 0.20453E-10 -10.6892 0.10595E-10 -10.9749 0.51799E+00 -0.2857 75 HMnO2- 0.20822E-09 -9.6815 0.17388E-09 -9.7597 0.83511E+00 -0.0783 78 MnCl+ 0.93424E-14 -14.0295 0.78169E-14 -14.1070 0.83671E+00 -0.0774 79 MnSO4,aq 0.10961E-18 -18.9602 0.10961E-18 -18.9602 0.10000E+01 0.0000 80 NaCl,aq 0.71857E-06 -6.1435 0.71857E-06 -6.1435 0.10000E+01 0.0000 81 NaF,aq 0.11780E-08 -8.9289 0.11780E-08 -8.9289 0.10000E+01 0.0000 82 NaOH,aq 0.95113E-04 -4.0218 0.95113E-04 -4.0218 0.10000E+01 0.0000 84 OH- 0.92520E-02 -2.0338 0.77125E-02 -2.1128 0.83360E+00 -0.0790 89 HPO3-2 0.57029E-15 -15.2439 0.29541E-15 -15.5296 0.51799E+00 -0.2857 91 H2PO3- 0.53139E-19 -19.2746 0.44377E-19 -19.3528 0.83511E+00 -0.0783 92 H3PO4,aq 0.92359E-18 -18.0345 0.92359E-18 -18.0345 0.10000E+01 0.0000 93 H2PO4- 0.38902E-10 -10.4100 0.32518E-10 -10.4879 0.83590E+00 -0.0778 94 PO4-3 0.10571E-08 -8.9759 0.25627E-09 -9.5913 0.24243E+00 -0.6154 98 HP2O7-3 0.95654E-18 -18.0193 0.22100E-18 -18.6556 0.23104E+00 -0.6363 99 P2O7-4 0.91551E-17 -17.0383 0.70476E-18 -18.1520 0.76980E-01 -1.1136 100 H2S,aq 0.85023E-08 -8.0705 0.84728E-08 -8.0720 0.99653E+00 -0.0015 101 S2-2 0.14220E-13 -13.8471 0.73660E-14 -14.1328 0.51799E+00 -0.2857 107 SO3-2 0.38957E-16 -16.4094 0.20471E-16 -16.6889 0.52549E+00 -0.2794 108 HSO3- 0.11498E-18 -18.9394 0.96022E-19 -19.0176 0.83511E+00 -0.0783 109 HSO4- 0.33709E-17 -17.4723 0.28232E-17 -17.5493 0.83753E+00 -0.0770 Charge balance for all species = -.6133E-08 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.8916508E-10 -.2223071E-01 -.2236824E+02 0.0000 2 H2O 0.1000000E+01 0.5550480E+02 0.9981959E+06 0.0000 3 Cl- 0.1565607E-03 0.1572796E-03 0.5566333E+01 6.2419 4 SO4-- 0.7533396E-10 -.1365637E-04 -.1309571E+01 9.8431 5 HCO3- 0.1657631E-04 0.6044222E-04 0.3681599E+01 5.2673 6 HS- 0.4381397E-04 0.5747893E-04 0.1897636E+01 5.6889 7 Al+++ 0.9814781E-29 0.5174833E-05 0.1393819E+00 0.7315 8 H4SiO4 0.7022893E-03 0.1353202E-01 0.1298373E+04 -3.1535 9 Ca++ 0.1191106E-06 0.2159989E-06 0.8641742E-02 13.0389 10 Mg++ 0.2115079E-10 0.9318183E-10 0.2261496E-05 9.2863 11 Fe++ 0.4499756E-13 0.2745854E-07 0.1530810E-02 6.6146 12 K+ 0.1565131E-03 0.1572598E-03 0.6138474E+01 6.2425 13 Na+ 0.1986205E-01 0.2230578E-01 0.5119133E+03 8.3451 14 Mn++ 0.1889240E-10 0.2507548E-08 0.1375200E-03 9.2380 15 F- 0.3640515E-06 0.3652300E-06 0.6926568E-02 3.6074 16 HPO4-- 0.4532406E-07 0.4642005E-07 0.4447599E-02 12.6225 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.1996517E-01 -.1996461E-01 -.5536864E-06 0.0000000E+00 2 H2O 0.4984688E+02 0.4984688E+02 -.5101665E-06 0.0000000E+00 3 Cl- 0.1412472E-03 0.1412472E-03 0.0000000E+00 0.0000000E+00 4 SO4-- -.1226331E-04 -.1226430E-04 0.9915914E-09 0.0000000E+00 5 HCO3- 0.5428100E-04 0.5428100E-04 0.0000000E+00 0.0000000E+00 6 HS- 0.5161878E-04 0.5161977E-04 -.9915914E-09 0.0000000E+00 7 Al+++ 0.4775352E-05 0.4647333E-05 0.1280191E-06 0.0000000E+00 8 H4SiO4 0.1215302E-01 0.1215263E-01 0.3937528E-06 0.0000000E+00 9 Ca++ 0.2080835E-06 0.1939809E-06 0.1410263E-07 0.0000000E+00 10 Mg++ 0.8368328E-10 0.8368328E-10 0.0000000E+00 0.0000000E+00 11 Fe++ 0.3259227E-07 0.2465954E-07 0.7932731E-08 0.0000000E+00 12 K+ 0.1412294E-03 0.1412294E-03 0.0000000E+00 0.0000000E+00 13 Na+ 0.2003215E-01 0.2003202E-01 0.1265500E-06 0.0000000E+00 14 Mn++ 0.2251939E-08 0.2251939E-08 0.0000000E+00 0.0000000E+00 15 F- 0.3280000E-06 0.3280000E-06 0.0000000E+00 0.0000000E+00 16 HPO4-- 0.4168819E-07 0.4168819E-07 0.0000000E+00 0.0000000E+00 Chg. balance for solid moles: -.7941E-22 Mass of aqueous solution: 0.899629E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 0.0005700 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 0.1266E-06 -6.898 0.3318E-04 -4.479 93.40 0.1274E-04 andradite 0.3966E-08 -8.402 0.2016E-05 -5.696 5.673 0.5237E-06 grossular 0.7345E-09 -9.134 0.3309E-06 -6.480 0.9312 0.9206E-07 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8438E+00 0.8438E+00 1.0000 -0.074 grossular 0.1562E+00 0.1562E+00 1.0000 -0.806 Solid products produced: Mass = 0.000036 g Volume = 0.000013 cm3 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.0005700 moles log = -3.2441 Original solution: 1000.0103000 g Original solution / Rock added: 1754404.04 (Water/Rock Ratio), log = 6.2441 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0442 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9774E+00 0.9856 0.1006E+01 0.1021E+01 CO2,gas 0.2258E-06 1.0069 0.2374E-06 0.2358E-06 CH4,gas 0.1755E-01 1.0123 0.1855E-01 0.1832E-01 H2,gas 0.5062E-02 1.0006 0.5289E-02 0.5286E-02 H2S,gas 0.2240E-06 0.9959 0.2329E-06 0.2339E-06 S2,gas 0.6971E-28 1.0000 0.7280E-28 0.7280E-28 CO,gas 0.3205E-12 1.0000 0.3347E-12 0.3347E-12 SO3,gas 0.7946E-46 1.0000 0.8298E-46 0.8298E-46 SO2,gas 0.1635E-25 1.0000 0.1707E-25 0.1707E-25 HF,gas 0.3658E-15 1.0000 0.3820E-15 0.3820E-15 HCl,gas 0.3033E-17 1.0000 0.3167E-17 0.3167E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 17 albite -0.38 -0.38 0.00 0.000 -0.94784E-12 23 andradite 39.01 39.01 0.00 0.000 0.24265E-10 24 grossular 32.73 32.73 0.00 0.000 -0.24265E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -14.98 -8.32 -2.774 0.14212E+05 -6.624 3 CH4,gas 4.54 1.11 -3.43 -0.858 0.58577E+04 -1.732 4 H2,gas 8.00 4.02 -3.98 -2.272 0.67882E+04 -2.277 5 H2S,gas -6.23 -14.56 -8.33 -4.166 0.14226E+05 -6.633 6 S2,gas -7.34 -37.17 -29.84 -4.590 0.50946E+05 -28.138 7 CO,gas 3.21 -10.96 -14.17 -4.361 0.24202E+05 -12.475 8 SO3,gas 17.12 -30.66 -47.78 -11.945 0.81583E+05 -46.081 9 SO2,gas 0.83 -26.63 -27.47 -7.324 0.46899E+05 -25.768 10 HF,gas 0.47 -16.64 -17.12 -8.558 0.29227E+05 -15.418 11 HCl,gas 5.19 -14.01 -19.20 -9.599 0.32781E+05 -17.499 12 acmite 7.71 6.64 -1.07 -0.111 0.18254E+04 16 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 20 spessartine 24.46 19.72 -4.74 -0.237 0.80947E+04 21 analcite 3.32 2.77 -0.55 -0.061 0.94294E+03 27 annite 20.12 17.36 -2.77 -0.154 0.47231E+04 28 phlogopite 27.06 25.37 -1.69 -0.094 0.28897E+04 30 anorthite 12.71 8.19 -4.52 -0.347 0.77101E+04 33 apatite-OH -18.15 -18.44 -0.29 -0.022 0.49499E+03 34 apatite-F -34.30 -35.09 -0.79 -0.065 0.13418E+04 38 aragonite 0.97 -1.94 -2.91 -0.970 0.49708E+04 39 brucite 12.57 9.29 -3.28 -0.656 0.56045E+04 40 calcite 0.81 -1.94 -2.76 -0.919 0.47066E+04 41 carnegieite-low 9.02 5.92 -3.10 -0.443 0.52935E+04 42 carnegieite-high 10.09 5.92 -4.17 -0.596 0.71205E+04 43 carpholite-Mg 8.58 4.44 -4.14 -0.276 0.70688E+04 44 carpholite-Fe 6.71 1.77 -4.94 -0.329 0.84385E+04 45 celadonite 5.34 3.65 -1.70 -0.100 0.28948E+04 46 celadonite-Fe 3.88 0.97 -2.90 -0.171 0.49550E+04 47 chrysotile 23.89 21.55 -2.34 -0.195 0.39965E+04 49 clinochlore 39.07 38.43 -0.64 -0.020 0.10856E+04 50 daphnite 28.97 25.08 -3.89 -0.122 0.66418E+04 52 chlorite-Al-free 47.17 43.10 -4.07 -0.170 0.69482E+04 54 chloritoid-Fe 9.17 4.92 -4.25 -0.283 0.72561E+04 55 chloritoid-Mn 11.40 7.55 -3.85 -0.257 0.65799E+04 57 coesite -2.38 -3.15 -0.78 -0.259 0.13274E+04 64 cristobalite -2.56 -3.15 -0.59 -0.198 0.10128E+04 66 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71234E+04 68 diaspore 2.87 0.73 -2.14 -0.357 0.36578E+04 69 diamond -3.10 -6.94 -3.83 -1.095 0.65445E+04 70 diopside 16.18 16.02 -0.16 -0.016 0.27867E+03 71 hedenbergite 14.21 13.35 -0.86 -0.086 0.14715E+04 74 enstatite 17.26 12.27 -5.00 -0.500 0.85363E+04 76 clinoenstatite 17.17 12.27 -4.90 -0.490 0.83679E+04 78 epidote 24.67 22.68 -1.99 -0.096 0.33931E+04 79 clinozoisite 22.81 18.81 -3.99 -0.182 0.68203E+04 80 epidote-Fe 29.84 26.55 -3.29 -0.171 0.56125E+04 81 fayalite 14.05 10.08 -3.97 -0.567 0.67787E+04 82 ferrosilite 11.15 6.92 -4.23 -0.423 0.72179E+04 86 gibbsite 4.08 0.73 -3.35 -0.478 0.57164E+04 87 glaucophane 22.97 20.78 -2.19 -0.059 0.37406E+04 88 glaucophane-Fe 17.28 12.77 -4.51 -0.122 0.76952E+04 89 graphite -3.55 -6.94 -3.39 -0.968 0.57868E+04 90 greenalite 16.14 13.54 -2.60 -0.217 0.44440E+04 93 hematite 12.57 9.21 -3.36 -0.407 0.57391E+04 94 heulandite -5.83 -7.57 -1.75 -0.079 0.29802E+04 98 jadeite 4.22 2.77 -1.45 -0.145 0.24684E+04 100 kalsilite 7.58 3.82 -3.76 -0.538 0.64260E+04 101 kaolinite -1.33 -4.84 -3.51 -0.319 0.59954E+04 104 laumontite 2.88 1.89 -1.00 -0.066 0.16999E+04 105 lawsonite 9.62 8.19 -1.42 -0.095 0.24268E+04 106 leucite 4.12 0.67 -3.45 -0.345 0.58940E+04 108 lizardite 23.24 21.55 -1.69 -0.141 0.28891E+04 110 magnetite 20.09 15.82 -4.27 -0.348 0.72871E+04 111 minnesotaite 10.39 7.23 -3.16 -0.186 0.53927E+04 115 manganosite 14.06 9.24 -4.82 -1.205 0.82301E+04 119 microcline -2.49 -2.49 0.00 0.000 0.48086E-01 123 muscovite 2.58 -1.02 -3.61 -0.212 0.61572E+04 124 paragonite 4.24 1.08 -3.16 -0.186 0.53963E+04 125 nepheline 8.34 5.92 -2.42 -0.345 0.41259E+04 137 phlogopite-Na 29.65 27.47 -2.17 -0.121 0.37084E+04 139 prehnite 19.37 18.08 -1.29 -0.076 0.22055E+04 140 prehnite-Fe 22.50 21.95 -0.55 -0.033 0.93332E+03 141 pumpellyite-Fe 46.27 43.51 -2.76 -0.061 0.47177E+04 142 pumpellyite-Mg 48.99 46.18 -2.82 -0.063 0.48096E+04 146 pyrrhotite -4.26 -7.95 -3.69 -1.229 0.62956E+04 147 pyrrhotiteFe0.875 -6.02 -9.27 -3.26 -1.198 0.55600E+04 148 pyroxmangite 7.40 6.08 -1.31 -0.263 0.22438E+04 149 pyrophyllite -6.18 -11.15 -4.98 -0.311 0.84951E+04 150 quartz -2.99 -3.15 -0.16 -0.055 0.28011E+03 154 rhodochrosite -0.98 -5.75 -4.77 -1.590 0.81433E+04 155 rhodonite 7.45 6.08 -1.36 -0.272 0.23241E+04 156 sanidine -1.28 -2.49 -1.21 -0.093 0.20678E+04 166 stilbite -7.52 -7.57 -0.05 -0.002 0.86320E+02 167 stilpnomelane-Fe 13.02 12.43 -0.59 -0.018 0.10036E+04 168 stilpnomelane-Mg 27.44 25.79 -1.65 -0.049 0.28239E+04 174 talc 16.49 15.24 -1.25 -0.073 0.21279E+04 177 tephroite 18.09 15.32 -2.76 -0.395 0.47181E+04 181 tridymite -2.63 -3.15 -0.53 -0.176 0.90009E+03 182 tremolite 47.87 47.28 -0.59 -0.016 0.10042E+04 183 ferroactinolite 38.45 33.92 -4.53 -0.122 0.77341E+04 184 troilite-low -4.41 -7.95 -3.54 -1.179 0.60384E+04 190 wairakite 3.95 1.89 -2.06 -0.121 0.35219E+04 191 walstromite 11.51 9.89 -1.62 -0.325 0.27727E+04 192 wollastonite 10.46 9.89 -0.58 -0.115 0.98310E+03 193 pseudo-wollastonite 11.00 9.89 -1.11 -0.223 0.19029E+04 194 zoisite 22.85 18.81 -4.04 -0.184 0.68943E+04 195 akaganeite 7.75 4.60 -3.15 -0.682 0.53821E+04 202 chalcedony -2.80 -3.15 -0.35 -0.117 0.59941E+03 204 montmorillonite-Ca -2.29 -6.18 -3.89 -0.240 0.66349E+04 205 montmorillonite-K -2.24 -6.27 -4.03 -0.247 0.68832E+04 206 montmorillonite-Mg -2.48 -6.80 -4.32 -0.267 0.73692E+04 207 montmorillonite-Na -2.04 -5.57 -3.54 -0.217 0.60381E+04 208 nontronite-Ca 3.21 0.02 -3.19 -0.207 0.54469E+04 209 nontronite-H 2.53 -2.13 -4.66 -0.312 0.79561E+04 210 nontronite-K 3.34 -0.07 -3.41 -0.219 0.58183E+04 211 nontronite-Mg 3.07 -0.59 -3.67 -0.238 0.62652E+04 212 nontronite-Na 3.52 0.63 -2.89 -0.186 0.49392E+04 228 tobermorite 9.82 7.71 -2.12 -0.577 0.36116E+04 234 alabandite -0.98 -5.32 -4.35 -1.449 0.74208E+04 237 boehmite 4.41 0.73 -3.67 -0.612 0.62747E+04 239 ferrous-oxide 9.81 6.61 -3.20 -0.799 0.54588E+04 245 silica-amorphous -2.09 -3.15 -1.06 -0.354 0.18136E+04 247 an20ab80 2.02 1.33 -0.69 -0.053 0.11712E+04 248 an25ab75 2.65 1.76 -0.88 -0.068 0.15109E+04 249 an30ab70 3.28 2.19 -1.09 -0.084 0.18603E+04 250 tr.625ac.25prg.125 45.16 44.89 -0.28 -0.007 0.47496E+03 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 0.0000200 MOLES Current total amount of reactant added: 0.0005700 MOLES New total amount of reactant added: 0.0005900 MOLES Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.5508E-08 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 6 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 0.0005900 Water: Moles liquid = 0.4985E+02 kg liquid = 0.8981E+00 Moles total = 0.4985E+02 kg total = 0.8980E+00 Activity = 1.0000 Stoichiometric ionic strength = .1136784E-01 Osmotic coef. = 0.9674 True ionic strength = .2005145E-01 Chg. balance for total moles = -.5508E-08 Max. difference allowed = 0.1414E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.89197E-10 -10.0497 0.74940E-10 -10.1253 0.84017E+00 -0.0756 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.15669E-03 -3.8050 0.13085E-03 -3.8832 0.83511E+00 -0.0783 4 SO4-- 0.79605E-10 -10.0991 0.41322E-10 -10.3838 0.51908E+00 -0.2848 5 HCO3- 0.17172E-04 -4.7652 0.14361E-04 -4.8428 0.83633E+00 -0.0776 6 HS- 0.44355E-04 -4.3531 0.37047E-04 -4.4313 0.83523E+00 -0.0782 7 Al+++ 0.98193E-29 -29.0079 0.22663E-29 -29.6447 0.23080E+00 -0.6368 8 H4SiO4 0.70252E-03 -3.1533 0.70252E-03 -3.1533 0.10000E+01 0.0000 9 Ca++ 0.11886E-06 -6.9250 0.61244E-07 -7.2129 0.51527E+00 -0.2880 10 Mg++ 0.21152E-10 -10.6746 0.10849E-10 -10.9646 0.51291E+00 -0.2900 11 Fe++ 0.44992E-13 -13.3469 0.23102E-13 -13.6363 0.51347E+00 -0.2895 12 K+ 0.15651E-03 -3.8054 0.13093E-03 -3.8830 0.83653E+00 -0.0775 13 Na+ 0.19862E-01 -1.7020 0.16584E-01 -1.7803 0.83496E+00 -0.0783 14 Mn++ 0.18905E-10 -10.7234 0.97154E-11 -11.0125 0.51390E+00 -0.2891 15 F- 0.37293E-06 -6.4284 0.31079E-06 -6.5075 0.83338E+00 -0.0792 16 HPO4-- 0.45324E-07 -7.3437 0.23531E-07 -7.6284 0.51916E+00 -0.2847 18 HSiO3- 0.10482E-01 -1.9796 0.87533E-02 -2.0578 0.83511E+00 -0.0783 19 Ca(HSiO3)+ 0.14591E-07 -7.8359 0.12209E-07 -7.9133 0.83671E+00 -0.0774 20 Mg(HSiO3)+ 0.32168E-11 -11.4926 0.26915E-11 -11.5700 0.83671E+00 -0.0774 21 NaHSiO3,aq 0.23478E-02 -2.6293 0.23478E-02 -2.6293 0.10000E+01 0.0000 22 AlO+ 0.65614E-16 -16.1830 0.54900E-16 -16.2604 0.83671E+00 -0.0774 24 HAlO2,aq 0.14589E-09 -9.8360 0.14589E-09 -9.8360 0.10000E+01 0.0000 25 AlO2- 0.51696E-05 -5.2865 0.43094E-05 -5.3656 0.83360E+00 -0.0790 26 CH4,aq 0.12550E-04 -4.9013 0.12507E-04 -4.9028 0.99653E+00 -0.0015 27 C2H6,aq 0.67336E-14 -14.1718 0.67102E-14 -14.1733 0.99653E+00 -0.0015 31 CO,aq 0.23022E-15 -15.6379 0.23022E-15 -15.6379 0.10000E+01 0.0000 32 CO2,aq 0.23076E-08 -8.6368 0.22996E-08 -8.6383 0.99653E+00 -0.0015 33 CO3-2 0.32315E-04 -4.4906 0.16739E-04 -4.7763 0.51798E+00 -0.2857 34 CaCO3,aq 0.12854E-07 -7.8910 0.12854E-07 -7.8910 0.10000E+01 0.0000 35 Ca(HCO3)+ 0.26833E-10 -10.5713 0.22451E-10 -10.6488 0.83671E+00 -0.0774 36 CaCl+ 0.15500E-10 -10.8097 0.12969E-10 -10.8871 0.83671E+00 -0.0774 37 CaCl2,aq 0.40319E-15 -15.3945 0.40319E-15 -15.3945 0.10000E+01 0.0000 38 CaF+ 0.33214E-12 -12.4787 0.27790E-12 -12.5561 0.83671E+00 -0.0774 39 CaOH+ 0.69612E-07 -7.1573 0.58245E-07 -7.2347 0.83671E+00 -0.0774 40 CaSO4,aq 0.80362E-15 -15.0949 0.80362E-15 -15.0949 0.10000E+01 0.0000 41 HCl,aq 0.17969E-14 -14.7455 0.17969E-14 -14.7455 0.10000E+01 0.0000 45 HF,aq 0.15944E-12 -12.7974 0.15944E-12 -12.7974 0.10000E+01 0.0000 46 HF2- 0.20034E-19 -19.6982 0.16731E-19 -19.7765 0.83511E+00 -0.0783 48 FeCl+ 0.57188E-17 -17.2427 0.47850E-17 -17.3201 0.83671E+00 -0.0774 51 FeF+ 0.43852E-18 -18.3580 0.36691E-18 -18.4354 0.83671E+00 -0.0774 53 FeO,aq 0.15988E-09 -9.7962 0.15988E-09 -9.7962 0.10000E+01 0.0000 54 FeOH+ 0.11993E-10 -10.9211 0.10035E-10 -10.9985 0.83671E+00 -0.0774 55 HFeO2- 0.26730E-07 -7.5730 0.22322E-07 -7.6513 0.83511E+00 -0.0783 56 FeO+ 0.14330E-16 -16.8438 0.11990E-16 -16.9212 0.83671E+00 -0.0774 58 FeO2- 0.52310E-09 -9.2814 0.43685E-09 -9.3597 0.83511E+00 -0.0783 59 HFeO2,aq 0.41637E-11 -11.3805 0.41637E-11 -11.3805 0.10000E+01 0.0000 60 H2,aq 0.39990E-05 -5.3980 0.39852E-05 -5.3996 0.99653E+00 -0.0015 61 KCl,aq 0.31051E-09 -9.5079 0.31051E-09 -9.5079 0.10000E+01 0.0000 63 KOH,aq 0.74611E-06 -6.1272 0.74611E-06 -6.1272 0.10000E+01 0.0000 64 KSO4- 0.10053E-12 -12.9977 0.83953E-13 -13.0760 0.83511E+00 -0.0783 65 MgCO3,aq 0.57075E-12 -12.2436 0.57075E-12 -12.2436 0.10000E+01 0.0000 66 Mg(HCO3)+ 0.48569E-14 -14.3136 0.40638E-14 -14.3911 0.83671E+00 -0.0774 67 MgCl+ 0.24886E-14 -14.6040 0.20823E-14 -14.6815 0.83671E+00 -0.0774 68 MgF+ 0.21795E-15 -15.6616 0.18236E-15 -15.7391 0.83671E+00 -0.0774 69 MgOH+ 0.68235E-10 -10.1660 0.57093E-10 -10.2434 0.83671E+00 -0.0774 71 MnF+ 0.60785E-16 -16.2162 0.50859E-16 -16.2936 0.83671E+00 -0.0774 72 MnO,aq 0.17915E-08 -8.7468 0.17915E-08 -8.7468 0.10000E+01 0.0000 73 MnOH+ 0.46853E-09 -9.3293 0.39202E-09 -9.4067 0.83671E+00 -0.0774 74 MnO2-2 0.20439E-10 -10.6895 0.10587E-10 -10.9752 0.51798E+00 -0.2857 75 HMnO2- 0.20814E-09 -9.6817 0.17382E-09 -9.7599 0.83511E+00 -0.0783 78 MnCl+ 0.93564E-14 -14.0289 0.78286E-14 -14.1063 0.83671E+00 -0.0774 79 MnSO4,aq 0.11590E-18 -18.9359 0.11590E-18 -18.9359 0.10000E+01 0.0000 80 NaCl,aq 0.71917E-06 -6.1432 0.71917E-06 -6.1432 0.10000E+01 0.0000 81 NaF,aq 0.12067E-08 -8.9184 0.12067E-08 -8.9184 0.10000E+01 0.0000 82 NaOH,aq 0.95080E-04 -4.0219 0.95080E-04 -4.0219 0.10000E+01 0.0000 84 OH- 0.92488E-02 -2.0339 0.77098E-02 -2.1130 0.83360E+00 -0.0790 89 HPO3-2 0.56417E-15 -15.2486 0.29223E-15 -15.5343 0.51798E+00 -0.2857 91 H2PO3- 0.52587E-19 -19.2791 0.43915E-19 -19.3574 0.83511E+00 -0.0783 92 H3PO4,aq 0.92424E-18 -18.0342 0.92424E-18 -18.0342 0.10000E+01 0.0000 93 H2PO4- 0.38916E-10 -10.4099 0.32530E-10 -10.4877 0.83590E+00 -0.0778 94 PO4-3 0.10567E-08 -8.9760 0.25618E-09 -9.5915 0.24243E+00 -0.6154 98 HP2O7-3 0.95689E-18 -18.0191 0.22108E-18 -18.6555 0.23104E+00 -0.6363 99 P2O7-4 0.91555E-17 -17.0383 0.70475E-18 -18.1520 0.76976E-01 -1.1136 100 H2S,aq 0.86103E-08 -8.0650 0.85804E-08 -8.0665 0.99653E+00 -0.0015 101 S2-2 0.14732E-13 -13.8317 0.76310E-14 -14.1174 0.51798E+00 -0.2857 107 SO3-2 0.40723E-16 -16.3902 0.21399E-16 -16.6696 0.52548E+00 -0.2794 108 HSO3- 0.12024E-18 -18.9200 0.10041E-18 -18.9982 0.83511E+00 -0.0783 109 HSO4- 0.35632E-17 -17.4482 0.29843E-17 -17.5252 0.83752E+00 -0.0770 Charge balance for all species = -.6133E-08 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.8919680E-10 -.2222829E-01 -.2236580E+02 0.0000 2 H2O 0.1000000E+01 0.5550479E+02 0.9981958E+06 0.0000 3 Cl- 0.1566914E-03 0.1574109E-03 0.5570981E+01 6.2421 4 SO4-- 0.7960493E-10 -.1355003E-04 -.1299373E+01 9.8667 5 HCO3- 0.1717165E-04 0.6205233E-04 0.3779672E+01 5.2825 6 HS- 0.4435501E-04 0.5791373E-04 0.1911991E+01 5.6940 7 Al+++ 0.9819256E-29 0.5169745E-05 0.1392448E+00 0.7312 8 H4SiO4 0.7025206E-03 0.1353200E-01 0.1298371E+04 -3.1533 9 Ca++ 0.1188592E-06 0.2159590E-06 0.8640148E-02 13.0376 10 Mg++ 0.2115196E-10 0.9318180E-10 0.2261495E-05 9.2860 11 Fe++ 0.4499239E-13 0.2742899E-07 0.1529162E-02 6.6142 12 K+ 0.1565133E-03 0.1572597E-03 0.6138472E+01 6.2423 13 Na+ 0.1986213E-01 0.2230576E-01 0.5119129E+03 8.3450 14 Mn++ 0.1890529E-10 0.2507547E-08 0.1375199E-03 9.2380 15 F- 0.3729307E-06 0.3741379E-06 0.7095505E-02 3.6178 16 HPO4-- 0.4532437E-07 0.4642003E-07 0.4447597E-02 12.6222 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.1996301E-01 -.1996244E-01 -.5720797E-06 0.0000000E+00 2 H2O 0.4984689E+02 0.4984689E+02 -.5284602E-06 0.0000000E+00 3 Cl- 0.1413652E-03 0.1413652E-03 0.0000000E+00 0.0000000E+00 4 SO4-- -.1216781E-04 -.1216880E-04 0.9949082E-09 0.0000000E+00 5 HCO3- 0.5572700E-04 0.5572700E-04 0.0000000E+00 0.0000000E+00 6 HS- 0.5200928E-04 0.5201027E-04 -.9949082E-09 0.0000000E+00 7 Al+++ 0.4775352E-05 0.4642766E-05 0.1325864E-06 0.0000000E+00 8 H4SiO4 0.1215302E-01 0.1215261E-01 0.4074987E-06 0.0000000E+00 9 Ca++ 0.2080835E-06 0.1939452E-06 0.1413833E-07 0.0000000E+00 10 Mg++ 0.8368328E-10 0.8368328E-10 0.0000000E+00 0.0000000E+00 11 Fe++ 0.3259227E-07 0.2463300E-07 0.7959266E-08 0.0000000E+00 12 K+ 0.1412294E-03 0.1412294E-03 0.0000000E+00 0.0000000E+00 13 Na+ 0.2003215E-01 0.2003202E-01 0.1311201E-06 0.0000000E+00 14 Mn++ 0.2251939E-08 0.2251939E-08 0.0000000E+00 0.0000000E+00 15 F- 0.3360000E-06 0.3360000E-06 0.0000000E+00 0.0000000E+00 16 HPO4-- 0.4168819E-07 0.4168819E-07 0.0000000E+00 0.0000000E+00 Chg. balance for solid moles: 0.5294E-22 Mass of aqueous solution: 0.899630E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 0.0005900 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 0.1311E-06 -6.882 0.3438E-04 -4.464 93.60 0.1320E-04 andradite 0.3980E-08 -8.400 0.2022E-05 -5.694 5.505 0.5254E-06 grossular 0.7331E-09 -9.135 0.3302E-06 -6.481 0.8990 0.9189E-07 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8444E+00 0.8444E+00 1.0000 -0.073 grossular 0.1556E+00 0.1556E+00 1.0000 -0.808 Solid products produced: Mass = 0.000037 g Volume = 0.000014 cm3 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.0005900 moles log = -3.2291 Original solution: 1000.0103000 g Original solution / Rock added: 1694932.71 (Water/Rock Ratio), log = 6.2292 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0440 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9776E+00 0.9856 0.1006E+01 0.1021E+01 CO2,gas 0.2340E-06 1.0069 0.2460E-06 0.2444E-06 CH4,gas 0.1742E-01 1.0123 0.1841E-01 0.1818E-01 H2,gas 0.5009E-02 1.0006 0.5232E-02 0.5229E-02 H2S,gas 0.2268E-06 0.9959 0.2359E-06 0.2368E-06 S2,gas 0.7307E-28 1.0000 0.7629E-28 0.7629E-28 CO,gas 0.3286E-12 1.0000 0.3431E-12 0.3431E-12 SO3,gas 0.8404E-46 1.0000 0.8774E-46 0.8774E-46 SO2,gas 0.1711E-25 1.0000 0.1786E-25 0.1786E-25 HF,gas 0.3750E-15 1.0000 0.3915E-15 0.3915E-15 HCl,gas 0.3037E-17 1.0000 0.3171E-17 0.3171E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 17 albite -0.38 -0.38 0.00 0.000 -0.94784E-12 23 andradite 39.01 39.01 0.00 0.000 -0.12132E-10 24 grossular 32.73 32.73 0.00 0.000 0.00000E+00 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -14.97 -8.31 -2.769 0.14186E+05 -6.609 3 CH4,gas 4.54 1.11 -3.43 -0.858 0.58633E+04 -1.735 4 H2,gas 8.00 4.02 -3.98 -2.274 0.67962E+04 -2.281 5 H2S,gas -6.23 -14.56 -8.33 -4.163 0.14217E+05 -6.627 6 S2,gas -7.34 -37.15 -29.82 -4.587 0.50911E+05 -28.118 7 CO,gas 3.21 -10.95 -14.16 -4.358 0.24184E+05 -12.465 8 SO3,gas 17.12 -30.63 -47.76 -11.939 0.81542E+05 -46.057 9 SO2,gas 0.83 -26.61 -27.45 -7.319 0.46865E+05 -25.748 10 HF,gas 0.47 -16.63 -17.11 -8.553 0.29208E+05 -15.407 11 HCl,gas 5.19 -14.01 -19.20 -9.599 0.32780E+05 -17.499 12 acmite 7.71 6.64 -1.07 -0.111 0.18217E+04 16 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 20 spessartine 24.46 19.72 -4.74 -0.237 0.80950E+04 21 analcite 3.32 2.77 -0.55 -0.061 0.94319E+03 27 annite 20.12 17.36 -2.77 -0.154 0.47250E+04 28 phlogopite 27.06 25.37 -1.69 -0.094 0.28911E+04 30 anorthite 12.71 8.19 -4.52 -0.347 0.77127E+04 33 apatite-OH -18.15 -18.45 -0.30 -0.023 0.50395E+03 34 apatite-F -34.30 -35.08 -0.78 -0.065 0.13326E+04 38 aragonite 0.97 -1.93 -2.90 -0.966 0.49465E+04 39 brucite 12.57 9.29 -3.28 -0.657 0.56050E+04 40 calcite 0.81 -1.93 -2.74 -0.914 0.46823E+04 41 carnegieite-low 9.02 5.92 -3.10 -0.443 0.52940E+04 42 carnegieite-high 10.09 5.92 -4.17 -0.596 0.71210E+04 43 carpholite-Mg 8.58 4.44 -4.14 -0.276 0.70697E+04 44 carpholite-Fe 6.71 1.77 -4.94 -0.330 0.84396E+04 45 celadonite 5.34 3.65 -1.70 -0.100 0.28950E+04 46 celadonite-Fe 3.88 0.97 -2.90 -0.171 0.49554E+04 47 chrysotile 23.89 21.55 -2.34 -0.195 0.39975E+04 49 clinochlore 39.07 38.43 -0.64 -0.020 0.10883E+04 50 daphnite 28.97 25.07 -3.89 -0.122 0.66451E+04 52 chlorite-Al-free 47.17 43.10 -4.07 -0.170 0.69502E+04 54 chloritoid-Fe 9.17 4.92 -4.25 -0.283 0.72574E+04 55 chloritoid-Mn 11.40 7.55 -3.85 -0.257 0.65806E+04 57 coesite -2.38 -3.15 -0.78 -0.259 0.13272E+04 64 cristobalite -2.56 -3.15 -0.59 -0.198 0.10125E+04 66 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71234E+04 68 diaspore 2.87 0.73 -2.14 -0.357 0.36583E+04 69 diamond -3.10 -6.93 -3.83 -1.093 0.65341E+04 70 diopside 16.18 16.02 -0.16 -0.016 0.28077E+03 71 hedenbergite 14.21 13.35 -0.86 -0.086 0.14737E+04 74 enstatite 17.26 12.27 -5.00 -0.500 0.85368E+04 76 clinoenstatite 17.17 12.27 -4.90 -0.490 0.83684E+04 78 epidote 24.67 22.68 -1.99 -0.096 0.33941E+04 79 clinozoisite 22.81 18.81 -4.00 -0.182 0.68252E+04 80 epidote-Fe 29.84 26.56 -3.29 -0.171 0.56097E+04 81 fayalite 14.05 10.08 -3.97 -0.567 0.67797E+04 82 ferrosilite 11.15 6.92 -4.23 -0.423 0.72187E+04 86 gibbsite 4.08 0.73 -3.35 -0.478 0.57168E+04 87 glaucophane 22.97 20.78 -2.19 -0.059 0.37416E+04 88 glaucophane-Fe 17.28 12.77 -4.51 -0.122 0.76965E+04 89 graphite -3.55 -6.93 -3.38 -0.967 0.57764E+04 90 greenalite 16.14 13.54 -2.60 -0.217 0.44454E+04 93 hematite 12.57 9.21 -3.36 -0.407 0.57323E+04 94 heulandite -5.83 -7.57 -1.75 -0.079 0.29815E+04 98 jadeite 4.22 2.77 -1.45 -0.145 0.24687E+04 100 kalsilite 7.58 3.82 -3.76 -0.538 0.64265E+04 101 kaolinite -1.33 -4.84 -3.51 -0.319 0.59959E+04 104 laumontite 2.88 1.89 -1.00 -0.066 0.17020E+04 105 lawsonite 9.62 8.19 -1.42 -0.095 0.24293E+04 106 leucite 4.12 0.67 -3.45 -0.345 0.58943E+04 108 lizardite 23.24 21.55 -1.69 -0.141 0.28901E+04 110 magnetite 20.09 15.82 -4.26 -0.348 0.72810E+04 111 minnesotaite 10.39 7.23 -3.16 -0.186 0.53935E+04 115 manganosite 14.06 9.24 -4.82 -1.205 0.82302E+04 119 microcline -2.49 -2.49 0.00 0.000 0.49787E-01 123 muscovite 2.58 -1.02 -3.61 -0.212 0.61582E+04 124 paragonite 4.24 1.08 -3.16 -0.186 0.53972E+04 125 nepheline 8.34 5.92 -2.42 -0.345 0.41263E+04 137 phlogopite-Na 29.65 27.47 -2.17 -0.121 0.37099E+04 139 prehnite 19.37 18.08 -1.29 -0.076 0.22099E+04 140 prehnite-Fe 22.50 21.95 -0.55 -0.033 0.93388E+03 141 pumpellyite-Fe 46.27 43.50 -2.77 -0.062 0.47276E+04 142 pumpellyite-Mg 48.99 46.17 -2.82 -0.063 0.48194E+04 146 pyrrhotite -4.26 -7.94 -3.68 -1.227 0.62869E+04 147 pyrrhotiteFe0.875 -6.02 -9.27 -3.25 -1.195 0.55502E+04 148 pyroxmangite 7.40 6.08 -1.31 -0.263 0.22436E+04 149 pyrophyllite -6.18 -11.15 -4.98 -0.311 0.84950E+04 150 quartz -2.99 -3.15 -0.16 -0.055 0.27986E+03 154 rhodochrosite -0.98 -5.73 -4.75 -1.585 0.81169E+04 155 rhodonite 7.45 6.08 -1.36 -0.272 0.23239E+04 156 sanidine -1.28 -2.49 -1.21 -0.093 0.20678E+04 166 stilbite -7.52 -7.57 -0.05 -0.002 0.87654E+02 167 stilpnomelane-Fe 13.02 12.43 -0.59 -0.018 0.10058E+04 168 stilpnomelane-Mg 27.44 25.79 -1.65 -0.049 0.28255E+04 174 talc 16.49 15.24 -1.25 -0.073 0.21284E+04 177 tephroite 18.09 15.32 -2.76 -0.395 0.47179E+04 181 tridymite -2.63 -3.15 -0.53 -0.176 0.89984E+03 182 tremolite 47.87 47.28 -0.59 -0.016 0.10089E+04 183 ferroactinolite 38.45 33.92 -4.53 -0.123 0.77394E+04 184 troilite-low -4.41 -7.94 -3.53 -1.177 0.60297E+04 190 wairakite 3.95 1.89 -2.06 -0.121 0.35239E+04 191 walstromite 11.51 9.88 -1.62 -0.325 0.27745E+04 192 wollastonite 10.46 9.88 -0.58 -0.115 0.98496E+03 193 pseudo-wollastonite 11.00 9.88 -1.12 -0.223 0.19048E+04 194 zoisite 22.85 18.81 -4.04 -0.184 0.68992E+04 195 akaganeite 7.75 4.60 -3.15 -0.681 0.53787E+04 202 chalcedony -2.80 -3.15 -0.35 -0.117 0.59916E+03 204 montmorillonite-Ca -2.29 -6.18 -3.89 -0.240 0.66352E+04 205 montmorillonite-K -2.24 -6.27 -4.03 -0.247 0.68832E+04 206 montmorillonite-Mg -2.48 -6.80 -4.32 -0.267 0.73692E+04 207 montmorillonite-Na -2.04 -5.57 -3.54 -0.217 0.60381E+04 208 nontronite-Ca 3.21 0.03 -3.19 -0.207 0.54397E+04 209 nontronite-H 2.53 -2.12 -4.66 -0.312 0.79486E+04 210 nontronite-K 3.34 -0.06 -3.40 -0.218 0.58109E+04 211 nontronite-Mg 3.07 -0.59 -3.66 -0.238 0.62577E+04 212 nontronite-Na 3.52 0.63 -2.89 -0.185 0.49318E+04 228 tobermorite 9.82 7.71 -2.12 -0.577 0.36131E+04 234 alabandite -0.98 -5.32 -4.34 -1.447 0.74115E+04 237 boehmite 4.41 0.73 -3.68 -0.613 0.62752E+04 239 ferrous-oxide 9.81 6.61 -3.20 -0.799 0.54594E+04 245 silica-amorphous -2.09 -3.15 -1.06 -0.354 0.18133E+04 247 an20ab80 2.02 1.33 -0.69 -0.053 0.11717E+04 248 an25ab75 2.65 1.76 -0.89 -0.068 0.15116E+04 249 an30ab70 3.28 2.19 -1.09 -0.084 0.18611E+04 250 tr.625ac.25prg.125 45.16 44.88 -0.28 -0.008 0.48004E+03 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 0.0000200 MOLES Current total amount of reactant added: 0.0005900 MOLES New total amount of reactant added: 0.0006100 MOLES Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.5508E-08 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 6 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 0.0006100 Water: Moles liquid = 0.4985E+02 kg liquid = 0.8981E+00 Moles total = 0.4985E+02 kg total = 0.8980E+00 Activity = 1.0000 Stoichiometric ionic strength = .1136912E-01 Osmotic coef. = 0.9674 True ionic strength = .2005263E-01 Chg. balance for total moles = -.5508E-08 Max. difference allowed = 0.1415E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.89229E-10 -10.0495 0.74967E-10 -10.1251 0.84016E+00 -0.0756 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.15682E-03 -3.8046 0.13096E-03 -3.8829 0.83510E+00 -0.0783 4 SO4-- 0.84014E-10 -10.0756 0.43610E-10 -10.3604 0.51908E+00 -0.2848 5 HCO3- 0.17767E-04 -4.7504 0.14859E-04 -4.8280 0.83633E+00 -0.0776 6 HS- 0.44896E-04 -4.3478 0.37498E-04 -4.4260 0.83523E+00 -0.0782 7 Al+++ 0.98237E-29 -29.0077 0.22673E-29 -29.6445 0.23080E+00 -0.6368 8 H4SiO4 0.70275E-03 -3.1532 0.70275E-03 -3.1532 0.10000E+01 0.0000 9 Ca++ 0.11861E-06 -6.9259 0.61116E-07 -7.2138 0.51526E+00 -0.2880 10 Mg++ 0.21153E-10 -10.6746 0.10849E-10 -10.9646 0.51290E+00 -0.2900 11 Fe++ 0.44991E-13 -13.3469 0.23101E-13 -13.6364 0.51346E+00 -0.2895 12 K+ 0.15651E-03 -3.8054 0.13093E-03 -3.8830 0.83653E+00 -0.0775 13 Na+ 0.19862E-01 -1.7020 0.16584E-01 -1.7803 0.83495E+00 -0.0783 14 Mn++ 0.18918E-10 -10.7231 0.97219E-11 -11.0123 0.51389E+00 -0.2891 15 F- 0.38181E-06 -6.4182 0.31819E-06 -6.4973 0.83338E+00 -0.0792 16 HPO4-- 0.45325E-07 -7.3437 0.23530E-07 -7.6284 0.51915E+00 -0.2847 18 HSiO3- 0.10481E-01 -1.9796 0.87531E-02 -2.0578 0.83510E+00 -0.0783 19 Ca(HSiO3)+ 0.14560E-07 -7.8368 0.12183E-07 -7.9143 0.83671E+00 -0.0774 20 Mg(HSiO3)+ 0.32169E-11 -11.4926 0.26916E-11 -11.5700 0.83671E+00 -0.0774 21 NaHSiO3,aq 0.23478E-02 -2.6293 0.23478E-02 -2.6293 0.10000E+01 0.0000 22 AlO+ 0.65596E-16 -16.1831 0.54884E-16 -16.2606 0.83671E+00 -0.0774 24 HAlO2,aq 0.14580E-09 -9.8362 0.14580E-09 -9.8362 0.10000E+01 0.0000 25 AlO2- 0.51645E-05 -5.2870 0.43051E-05 -5.3660 0.83359E+00 -0.0790 26 CH4,aq 0.12455E-04 -4.9047 0.12411E-04 -4.9062 0.99653E+00 -0.0015 27 C2H6,aq 0.67013E-14 -14.1738 0.66780E-14 -14.1754 0.99653E+00 -0.0015 31 CO,aq 0.23579E-15 -15.6275 0.23579E-15 -15.6275 0.10000E+01 0.0000 32 CO2,aq 0.23885E-08 -8.6219 0.23803E-08 -8.6234 0.99653E+00 -0.0015 33 CO3-2 0.33425E-04 -4.4759 0.17313E-04 -4.7616 0.51797E+00 -0.2857 34 CaCO3,aq 0.13267E-07 -7.8772 0.13267E-07 -7.8772 0.10000E+01 0.0000 35 Ca(HCO3)+ 0.27705E-10 -10.5574 0.23181E-10 -10.6349 0.83671E+00 -0.0774 36 CaCl+ 0.15481E-10 -10.8102 0.12953E-10 -10.8876 0.83671E+00 -0.0774 37 CaCl2,aq 0.40301E-15 -15.3947 0.40301E-15 -15.3947 0.10000E+01 0.0000 38 CaF+ 0.33933E-12 -12.4694 0.28392E-12 -12.5468 0.83671E+00 -0.0774 39 CaOH+ 0.69441E-07 -7.1584 0.58102E-07 -7.2358 0.83671E+00 -0.0774 40 CaSO4,aq 0.84633E-15 -15.0725 0.84633E-15 -15.0725 0.10000E+01 0.0000 41 HCl,aq 0.17991E-14 -14.7450 0.17991E-14 -14.7450 0.10000E+01 0.0000 45 HF,aq 0.16330E-12 -12.7870 0.16330E-12 -12.7870 0.10000E+01 0.0000 46 HF2- 0.21007E-19 -19.6776 0.17543E-19 -19.7559 0.83510E+00 -0.0783 48 FeCl+ 0.57233E-17 -17.2424 0.47887E-17 -17.3198 0.83671E+00 -0.0774 51 FeF+ 0.44894E-18 -18.3478 0.37563E-18 -18.4252 0.83671E+00 -0.0774 53 FeO,aq 0.15976E-09 -9.7965 0.15976E-09 -9.7965 0.10000E+01 0.0000 54 FeOH+ 0.11988E-10 -10.9212 0.10031E-10 -10.9987 0.83671E+00 -0.0774 55 HFeO2- 0.26701E-07 -7.5735 0.22298E-07 -7.6517 0.83510E+00 -0.0783 56 FeO+ 0.14400E-16 -16.8416 0.12048E-16 -16.9191 0.83671E+00 -0.0774 58 FeO2- 0.52529E-09 -9.2796 0.43867E-09 -9.3579 0.83510E+00 -0.0783 59 HFeO2,aq 0.41825E-11 -11.3786 0.41825E-11 -11.3786 0.10000E+01 0.0000 60 H2,aq 0.39571E-05 -5.4026 0.39434E-05 -5.4041 0.99653E+00 -0.0015 61 KCl,aq 0.31077E-09 -9.5076 0.31077E-09 -9.5076 0.10000E+01 0.0000 63 KOH,aq 0.74585E-06 -6.1274 0.74585E-06 -6.1274 0.10000E+01 0.0000 64 KSO4- 0.10610E-12 -12.9743 0.88601E-13 -13.0526 0.83510E+00 -0.0783 65 MgCO3,aq 0.59037E-12 -12.2289 0.59037E-12 -12.2289 0.10000E+01 0.0000 66 Mg(HCO3)+ 0.50256E-14 -14.2988 0.42050E-14 -14.3762 0.83671E+00 -0.0774 67 MgCl+ 0.24908E-14 -14.6037 0.20841E-14 -14.6811 0.83671E+00 -0.0774 68 MgF+ 0.22315E-15 -15.6514 0.18671E-15 -15.7288 0.83671E+00 -0.0774 69 MgOH+ 0.68214E-10 -10.1661 0.57075E-10 -10.2436 0.83671E+00 -0.0774 71 MnF+ 0.62273E-16 -16.2057 0.52104E-16 -16.2831 0.83671E+00 -0.0774 72 MnO,aq 0.17915E-08 -8.7468 0.17915E-08 -8.7468 0.10000E+01 0.0000 73 MnOH+ 0.46868E-09 -9.3291 0.39215E-09 -9.4066 0.83671E+00 -0.0774 74 MnO2-2 0.20424E-10 -10.6899 0.10579E-10 -10.9756 0.51797E+00 -0.2857 75 HMnO2- 0.20806E-09 -9.6818 0.17375E-09 -9.7601 0.83510E+00 -0.0783 78 MnCl+ 0.93704E-14 -14.0282 0.78403E-14 -14.1057 0.83671E+00 -0.0774 79 MnSO4,aq 0.12240E-18 -18.9122 0.12240E-18 -18.9122 0.10000E+01 0.0000 80 NaCl,aq 0.71977E-06 -6.1428 0.71977E-06 -6.1428 0.10000E+01 0.0000 81 NaF,aq 0.12354E-08 -8.9082 0.12354E-08 -8.9082 0.10000E+01 0.0000 82 NaOH,aq 0.95046E-04 -4.0221 0.95046E-04 -4.0221 0.10000E+01 0.0000 84 OH- 0.92456E-02 -2.0341 0.77071E-02 -2.1131 0.83359E+00 -0.0790 89 HPO3-2 0.55826E-15 -15.2532 0.28917E-15 -15.5389 0.51797E+00 -0.2857 91 H2PO3- 0.52054E-19 -19.2835 0.43470E-19 -19.3618 0.83510E+00 -0.0783 92 H3PO4,aq 0.92488E-18 -18.0339 0.92488E-18 -18.0339 0.10000E+01 0.0000 93 H2PO4- 0.38929E-10 -10.4097 0.32541E-10 -10.4876 0.83590E+00 -0.0778 94 PO4-3 0.10564E-08 -8.9762 0.25609E-09 -9.5916 0.24242E+00 -0.6154 98 HP2O7-3 0.95725E-18 -18.0190 0.22115E-18 -18.6553 0.23103E+00 -0.6363 99 P2O7-4 0.91559E-17 -17.0383 0.70474E-18 -18.1520 0.76971E-01 -1.1137 100 H2S,aq 0.87183E-08 -8.0596 0.86881E-08 -8.0611 0.99653E+00 -0.0015 101 S2-2 0.15254E-13 -13.8166 0.79010E-14 -14.1023 0.51797E+00 -0.2857 107 SO3-2 0.42528E-16 -16.3713 0.22348E-16 -16.6508 0.52547E+00 -0.2794 108 HSO3- 0.12561E-18 -18.9010 0.10490E-18 -18.9792 0.83510E+00 -0.0783 109 HSO4- 0.37619E-17 -17.4246 0.31506E-17 -17.5016 0.83752E+00 -0.0770 Charge balance for all species = -.6133E-08 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.8922855E-10 -.2222586E-01 -.2236336E+02 0.0000 2 H2O 0.1000000E+01 0.5550479E+02 0.9981957E+06 0.0000 3 Cl- 0.1568222E-03 0.1575423E-03 0.5575628E+01 6.2423 4 SO4-- 0.8401378E-10 -.1344369E-04 -.1289176E+01 9.8898 5 HCO3- 0.1776739E-04 0.6366243E-04 0.3877745E+01 5.2971 6 HS- 0.4489604E-04 0.5834854E-04 0.1926345E+01 5.6991 7 Al+++ 0.9823734E-29 0.5164661E-05 0.1391078E+00 0.7309 8 H4SiO4 0.7027521E-03 0.1353198E-01 0.1298369E+04 -3.1532 9 Ca++ 0.1186111E-06 0.2159235E-06 0.8638724E-02 13.0364 10 Mg++ 0.2115314E-10 0.9318176E-10 0.2261494E-05 9.2857 11 Fe++ 0.4499132E-13 0.2740189E-07 0.1527651E-02 6.6139 12 K+ 0.1565135E-03 0.1572597E-03 0.6138469E+01 6.2422 13 Na+ 0.1986220E-01 0.2230575E-01 0.5119126E+03 8.3448 14 Mn++ 0.1891819E-10 0.2507546E-08 0.1375199E-03 9.2380 15 F- 0.3818098E-06 0.3830458E-06 0.7264442E-02 3.6278 16 HPO4-- 0.4532469E-07 0.4642001E-07 0.4447595E-02 12.6219 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.1996086E-01 -.1996027E-01 -.5904509E-06 0.0000000E+00 2 H2O 0.4984691E+02 0.4984691E+02 -.5467435E-06 0.0000000E+00 3 Cl- 0.1414832E-03 0.1414832E-03 0.0000000E+00 0.0000000E+00 4 SO4-- -.1207231E-04 -.1207331E-04 0.9979495E-09 0.0000000E+00 5 HCO3- 0.5717300E-04 0.5717300E-04 0.0000000E+00 0.0000000E+00 6 HS- 0.5239978E-04 0.5240078E-04 -.9979495E-09 0.0000000E+00 7 Al+++ 0.4775352E-05 0.4638201E-05 0.1371511E-06 0.0000000E+00 8 H4SiO4 0.1215302E-01 0.1215260E-01 0.4212339E-06 0.0000000E+00 9 Ca++ 0.2080835E-06 0.1939133E-06 0.1417020E-07 0.0000000E+00 10 Mg++ 0.8368328E-10 0.8368328E-10 0.0000000E+00 0.0000000E+00 11 Fe++ 0.3259227E-07 0.2460867E-07 0.7983596E-08 0.0000000E+00 12 K+ 0.1412294E-03 0.1412294E-03 0.0000000E+00 0.0000000E+00 13 Na+ 0.2003215E-01 0.2003201E-01 0.1356879E-06 0.0000000E+00 14 Mn++ 0.2251939E-08 0.2251939E-08 0.0000000E+00 0.0000000E+00 15 F- 0.3440000E-06 0.3440000E-06 0.0000000E+00 0.0000000E+00 16 HPO4-- 0.4168819E-07 0.4168819E-07 0.0000000E+00 0.0000000E+00 Chg. balance for solid moles: -.2647E-22 Mass of aqueous solution: 0.899630E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 0.0006100 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 0.1357E-06 -6.867 0.3558E-04 -4.449 93.78 0.1366E-04 andradite 0.3992E-08 -8.399 0.2029E-05 -5.693 5.347 0.5270E-06 grossular 0.7316E-09 -9.136 0.3295E-06 -6.482 0.8686 0.9169E-07 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8451E+00 0.8451E+00 1.0000 -0.073 grossular 0.1549E+00 0.1549E+00 1.0000 -0.810 Solid products produced: Mass = 0.000038 g Volume = 0.000014 cm3 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.0006100 moles log = -3.2147 Original solution: 1000.0103000 g Original solution / Rock added: 1639361.15 (Water/Rock Ratio), log = 6.2147 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0438 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9778E+00 0.9856 0.1006E+01 0.1021E+01 CO2,gas 0.2423E-06 1.0069 0.2547E-06 0.2529E-06 CH4,gas 0.1729E-01 1.0123 0.1827E-01 0.1805E-01 H2,gas 0.4957E-02 1.0006 0.5177E-02 0.5174E-02 H2S,gas 0.2297E-06 0.9959 0.2388E-06 0.2398E-06 S2,gas 0.7652E-28 1.0000 0.7988E-28 0.7988E-28 CO,gas 0.3366E-12 1.0000 0.3514E-12 0.3514E-12 SO3,gas 0.8878E-46 1.0000 0.9267E-46 0.9267E-46 SO2,gas 0.1788E-25 1.0000 0.1867E-25 0.1867E-25 HF,gas 0.3841E-15 1.0000 0.4009E-15 0.4009E-15 HCl,gas 0.3041E-17 1.0000 0.3175E-17 0.3175E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 17 albite -0.38 -0.38 0.00 0.000 -0.13080E-10 23 andradite 39.01 39.01 0.00 0.000 -0.12132E-10 24 grossular 32.73 32.73 0.00 0.000 -0.48529E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -14.95 -8.29 -2.764 0.14160E+05 -6.594 3 CH4,gas 4.54 1.11 -3.44 -0.859 0.58690E+04 -1.738 4 H2,gas 8.00 4.01 -3.98 -2.277 0.68041E+04 -2.286 5 H2S,gas -6.23 -14.55 -8.32 -4.160 0.14208E+05 -6.622 6 S2,gas -7.34 -37.13 -29.80 -4.584 0.50877E+05 -28.098 7 CO,gas 3.21 -10.94 -14.15 -4.355 0.24166E+05 -12.454 8 SO3,gas 17.12 -30.61 -47.73 -11.933 0.81501E+05 -46.033 9 SO2,gas 0.83 -26.60 -27.43 -7.314 0.46832E+05 -25.729 10 HF,gas 0.47 -16.62 -17.10 -8.548 0.29191E+05 -15.397 11 HCl,gas 5.19 -14.01 -19.20 -9.599 0.32779E+05 -17.498 12 acmite 7.71 6.64 -1.06 -0.111 0.18182E+04 16 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 20 spessartine 24.46 19.72 -4.74 -0.237 0.80953E+04 21 analcite 3.32 2.77 -0.55 -0.061 0.94343E+03 27 annite 20.12 17.36 -2.77 -0.154 0.47266E+04 28 phlogopite 27.06 25.37 -1.69 -0.094 0.28926E+04 30 anorthite 12.71 8.19 -4.52 -0.348 0.77152E+04 33 apatite-OH -18.15 -18.45 -0.30 -0.023 0.51282E+03 34 apatite-F -34.30 -35.08 -0.78 -0.065 0.13238E+04 38 aragonite 0.97 -1.92 -2.88 -0.961 0.49230E+04 39 brucite 12.57 9.29 -3.28 -0.657 0.56054E+04 40 calcite 0.81 -1.92 -2.73 -0.909 0.46588E+04 41 carnegieite-low 9.02 5.92 -3.10 -0.443 0.52945E+04 42 carnegieite-high 10.09 5.92 -4.17 -0.596 0.71215E+04 43 carpholite-Mg 8.58 4.44 -4.14 -0.276 0.70707E+04 44 carpholite-Fe 6.71 1.77 -4.94 -0.330 0.84406E+04 45 celadonite 5.34 3.65 -1.70 -0.100 0.28953E+04 46 celadonite-Fe 3.88 0.97 -2.90 -0.171 0.49557E+04 47 chrysotile 23.89 21.55 -2.34 -0.195 0.39985E+04 49 clinochlore 39.07 38.43 -0.64 -0.020 0.10910E+04 50 daphnite 28.97 25.07 -3.89 -0.122 0.66481E+04 52 chlorite-Al-free 47.17 43.10 -4.07 -0.170 0.69522E+04 54 chloritoid-Fe 9.17 4.92 -4.25 -0.283 0.72586E+04 55 chloritoid-Mn 11.40 7.55 -3.85 -0.257 0.65814E+04 57 coesite -2.38 -3.15 -0.78 -0.259 0.13269E+04 64 cristobalite -2.56 -3.15 -0.59 -0.198 0.10123E+04 66 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71234E+04 68 diaspore 2.87 0.73 -2.14 -0.357 0.36588E+04 69 diamond -3.10 -6.92 -3.82 -1.092 0.65242E+04 70 diopside 16.18 16.02 -0.17 -0.017 0.28286E+03 71 hedenbergite 14.21 13.34 -0.86 -0.086 0.14759E+04 74 enstatite 17.26 12.26 -5.00 -0.500 0.85373E+04 76 clinoenstatite 17.17 12.26 -4.90 -0.490 0.83689E+04 78 epidote 24.67 22.68 -1.99 -0.096 0.33951E+04 79 clinozoisite 22.81 18.81 -4.00 -0.182 0.68300E+04 80 epidote-Fe 29.84 26.56 -3.28 -0.171 0.56069E+04 81 fayalite 14.05 10.07 -3.97 -0.567 0.67806E+04 82 ferrosilite 11.15 6.92 -4.23 -0.423 0.72193E+04 86 gibbsite 4.08 0.73 -3.35 -0.478 0.57173E+04 87 glaucophane 22.97 20.78 -2.19 -0.059 0.37426E+04 88 glaucophane-Fe 17.28 12.77 -4.51 -0.122 0.76977E+04 89 graphite -3.55 -6.92 -3.38 -0.965 0.57664E+04 90 greenalite 16.14 13.54 -2.60 -0.217 0.44466E+04 93 hematite 12.57 9.21 -3.35 -0.406 0.57256E+04 94 heulandite -5.83 -7.57 -1.75 -0.079 0.29828E+04 98 jadeite 4.22 2.77 -1.45 -0.145 0.24689E+04 100 kalsilite 7.58 3.82 -3.76 -0.538 0.64270E+04 101 kaolinite -1.33 -4.84 -3.51 -0.319 0.59963E+04 104 laumontite 2.88 1.89 -1.00 -0.067 0.17040E+04 105 lawsonite 9.62 8.19 -1.42 -0.095 0.24319E+04 106 leucite 4.12 0.67 -3.45 -0.345 0.58945E+04 108 lizardite 23.24 21.55 -1.69 -0.141 0.28911E+04 110 magnetite 20.09 15.83 -4.26 -0.348 0.72748E+04 111 minnesotaite 10.39 7.23 -3.16 -0.186 0.53942E+04 115 manganosite 14.06 9.24 -4.82 -1.205 0.82302E+04 119 microcline -2.49 -2.49 0.00 0.000 0.51489E-01 123 muscovite 2.58 -1.02 -3.61 -0.212 0.61591E+04 124 paragonite 4.24 1.08 -3.16 -0.186 0.53982E+04 125 nepheline 8.34 5.92 -2.42 -0.345 0.41268E+04 137 phlogopite-Na 29.65 27.47 -2.17 -0.121 0.37114E+04 139 prehnite 19.37 18.08 -1.30 -0.076 0.22143E+04 140 prehnite-Fe 22.50 21.95 -0.55 -0.033 0.93443E+03 141 pumpellyite-Fe 46.27 43.49 -2.77 -0.062 0.47374E+04 142 pumpellyite-Mg 48.99 46.17 -2.83 -0.063 0.48291E+04 146 pyrrhotite -4.26 -7.94 -3.68 -1.226 0.62782E+04 147 pyrrhotiteFe0.875 -6.02 -9.26 -3.24 -1.193 0.55405E+04 148 pyroxmangite 7.40 6.08 -1.31 -0.263 0.22434E+04 149 pyrophyllite -6.18 -11.15 -4.98 -0.311 0.84950E+04 150 quartz -2.99 -3.15 -0.16 -0.055 0.27962E+03 154 rhodochrosite -0.98 -5.72 -4.74 -1.580 0.80914E+04 155 rhodonite 7.45 6.08 -1.36 -0.272 0.23236E+04 156 sanidine -1.28 -2.49 -1.21 -0.093 0.20678E+04 166 stilbite -7.52 -7.57 -0.05 -0.002 0.88970E+02 167 stilpnomelane-Fe 13.02 12.43 -0.59 -0.018 0.10077E+04 168 stilpnomelane-Mg 27.44 25.79 -1.66 -0.049 0.28271E+04 174 talc 16.49 15.24 -1.25 -0.073 0.21289E+04 177 tephroite 18.09 15.32 -2.76 -0.395 0.47177E+04 181 tridymite -2.63 -3.15 -0.53 -0.176 0.89960E+03 182 tremolite 47.87 47.28 -0.59 -0.016 0.10136E+04 183 ferroactinolite 38.45 33.92 -4.54 -0.123 0.77444E+04 184 troilite-low -4.41 -7.94 -3.53 -1.175 0.60210E+04 190 wairakite 3.95 1.89 -2.07 -0.121 0.35260E+04 191 walstromite 11.51 9.88 -1.63 -0.325 0.27764E+04 192 wollastonite 10.46 9.88 -0.58 -0.116 0.98679E+03 193 pseudo-wollastonite 11.00 9.88 -1.12 -0.223 0.19066E+04 194 zoisite 22.85 18.81 -4.04 -0.184 0.69041E+04 195 akaganeite 7.75 4.61 -3.15 -0.681 0.53753E+04 202 chalcedony -2.80 -3.15 -0.35 -0.117 0.59892E+03 204 montmorillonite-Ca -2.29 -6.18 -3.89 -0.240 0.66355E+04 205 montmorillonite-K -2.24 -6.27 -4.03 -0.247 0.68833E+04 206 montmorillonite-Mg -2.48 -6.80 -4.32 -0.267 0.73693E+04 207 montmorillonite-Na -2.04 -5.57 -3.54 -0.217 0.60382E+04 208 nontronite-Ca 3.21 0.03 -3.18 -0.206 0.54326E+04 209 nontronite-H 2.53 -2.12 -4.65 -0.312 0.79411E+04 210 nontronite-K 3.34 -0.06 -3.40 -0.218 0.58035E+04 211 nontronite-Mg 3.07 -0.59 -3.66 -0.237 0.62504E+04 212 nontronite-Na 3.52 0.64 -2.88 -0.185 0.49244E+04 228 tobermorite 9.82 7.71 -2.12 -0.578 0.36146E+04 234 alabandite -0.98 -5.31 -4.34 -1.445 0.74023E+04 237 boehmite 4.41 0.73 -3.68 -0.613 0.62757E+04 239 ferrous-oxide 9.81 6.61 -3.20 -0.799 0.54599E+04 245 silica-amorphous -2.09 -3.15 -1.06 -0.354 0.18131E+04 247 an20ab80 2.02 1.33 -0.69 -0.053 0.11722E+04 248 an25ab75 2.65 1.76 -0.89 -0.068 0.15122E+04 249 an30ab70 3.28 2.19 -1.09 -0.084 0.18618E+04 250 tr.625ac.25prg.125 45.16 44.88 -0.28 -0.008 0.48500E+03 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 0.0000200 MOLES Current total amount of reactant added: 0.0006100 MOLES New total amount of reactant added: 0.0006300 MOLES Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.5508E-08 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 6 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 0.0006300 Water: Moles liquid = 0.4985E+02 kg liquid = 0.8981E+00 Moles total = 0.4985E+02 kg total = 0.8980E+00 Activity = 1.0000 Stoichiometric ionic strength = .1137040E-01 Osmotic coef. = 0.9673 True ionic strength = .2005381E-01 Chg. balance for total moles = -.5508E-08 Max. difference allowed = 0.1416E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.89260E-10 -10.0493 0.74993E-10 -10.1250 0.84016E+00 -0.0756 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.15695E-03 -3.8042 0.13107E-03 -3.8825 0.83510E+00 -0.0783 4 SO4-- 0.88564E-10 -10.0527 0.45971E-10 -10.3375 0.51907E+00 -0.2848 5 HCO3- 0.18364E-04 -4.7360 0.15358E-04 -4.8137 0.83632E+00 -0.0776 6 HS- 0.45437E-04 -4.3426 0.37950E-04 -4.4208 0.83522E+00 -0.0782 7 Al+++ 0.98282E-29 -29.0075 0.22682E-29 -29.6443 0.23079E+00 -0.6368 8 H4SiO4 0.70298E-03 -3.1531 0.70298E-03 -3.1531 0.10000E+01 0.0000 9 Ca++ 0.11837E-06 -6.9268 0.60988E-07 -7.2148 0.51525E+00 -0.2880 10 Mg++ 0.21154E-10 -10.6746 0.10850E-10 -10.9646 0.51289E+00 -0.2900 11 Fe++ 0.44994E-13 -13.3468 0.23102E-13 -13.6363 0.51345E+00 -0.2895 12 K+ 0.15651E-03 -3.8054 0.13093E-03 -3.8830 0.83652E+00 -0.0775 13 Na+ 0.19862E-01 -1.7020 0.16584E-01 -1.7803 0.83495E+00 -0.0783 14 Mn++ 0.18931E-10 -10.7228 0.97283E-11 -11.0120 0.51388E+00 -0.2891 15 F- 0.39069E-06 -6.4082 0.32559E-06 -6.4873 0.83338E+00 -0.0792 16 HPO4-- 0.45325E-07 -7.3437 0.23530E-07 -7.6284 0.51914E+00 -0.2847 18 HSiO3- 0.10481E-01 -1.9796 0.87529E-02 -2.0578 0.83510E+00 -0.0783 19 Ca(HSiO3)+ 0.14530E-07 -7.8377 0.12157E-07 -7.9152 0.83670E+00 -0.0774 20 Mg(HSiO3)+ 0.32169E-11 -11.4926 0.26916E-11 -11.5700 0.83670E+00 -0.0774 21 NaHSiO3,aq 0.23477E-02 -2.6294 0.23477E-02 -2.6294 0.10000E+01 0.0000 22 AlO+ 0.65577E-16 -16.1832 0.54869E-16 -16.2607 0.83670E+00 -0.0774 24 HAlO2,aq 0.14571E-09 -9.8365 0.14571E-09 -9.8365 0.10000E+01 0.0000 25 AlO2- 0.51594E-05 -5.2874 0.43009E-05 -5.3664 0.83359E+00 -0.0790 26 CH4,aq 0.12358E-04 -4.9080 0.12315E-04 -4.9095 0.99653E+00 -0.0015 27 C2H6,aq 0.66663E-14 -14.1761 0.66432E-14 -14.1776 0.99653E+00 -0.0015 31 CO,aq 0.24130E-15 -15.6174 0.24130E-15 -15.6174 0.10000E+01 0.0000 32 CO2,aq 0.24695E-08 -8.6074 0.24610E-08 -8.6089 0.99653E+00 -0.0015 33 CO3-2 0.34535E-04 -4.4617 0.17888E-04 -4.7474 0.51796E+00 -0.2857 34 CaCO3,aq 0.13679E-07 -7.8639 0.13679E-07 -7.8639 0.10000E+01 0.0000 35 Ca(HCO3)+ 0.28575E-10 -10.5440 0.23909E-10 -10.6214 0.83670E+00 -0.0774 36 CaCl+ 0.15461E-10 -10.8108 0.12937E-10 -10.8882 0.83670E+00 -0.0774 37 CaCl2,aq 0.40284E-15 -15.3949 0.40284E-15 -15.3949 0.10000E+01 0.0000 38 CaF+ 0.34650E-12 -12.4603 0.28992E-12 -12.5377 0.83670E+00 -0.0774 39 CaOH+ 0.69272E-07 -7.1594 0.57960E-07 -7.2369 0.83670E+00 -0.0774 40 CaSO4,aq 0.89030E-15 -15.0505 0.89030E-15 -15.0505 0.10000E+01 0.0000 41 HCl,aq 0.18012E-14 -14.7444 0.18012E-14 -14.7444 0.10000E+01 0.0000 45 HF,aq 0.16715E-12 -12.7769 0.16715E-12 -12.7769 0.10000E+01 0.0000 46 HF2- 0.22003E-19 -19.6575 0.18375E-19 -19.7358 0.83510E+00 -0.0783 48 FeCl+ 0.57283E-17 -17.2420 0.47929E-17 -17.3194 0.83670E+00 -0.0774 51 FeF+ 0.45940E-18 -18.3378 0.38438E-18 -18.4152 0.83670E+00 -0.0774 53 FeO,aq 0.15965E-09 -9.7968 0.15965E-09 -9.7968 0.10000E+01 0.0000 54 FeOH+ 0.11985E-10 -10.9214 0.10028E-10 -10.9988 0.83670E+00 -0.0774 55 HFeO2- 0.26674E-07 -7.5739 0.22275E-07 -7.6522 0.83510E+00 -0.0783 56 FeO+ 0.14469E-16 -16.8395 0.12107E-16 -16.9170 0.83670E+00 -0.0774 58 FeO2- 0.52746E-09 -9.2778 0.44048E-09 -9.3561 0.83510E+00 -0.0783 59 HFeO2,aq 0.42013E-11 -11.3766 0.42013E-11 -11.3766 0.10000E+01 0.0000 60 H2,aq 0.39167E-05 -5.4071 0.39031E-05 -5.4086 0.99653E+00 -0.0015 61 KCl,aq 0.31103E-09 -9.5072 0.31103E-09 -9.5072 0.10000E+01 0.0000 63 KOH,aq 0.74558E-06 -6.1275 0.74558E-06 -6.1275 0.10000E+01 0.0000 64 KSO4- 0.11184E-12 -12.9514 0.93398E-13 -13.0297 0.83510E+00 -0.0783 65 MgCO3,aq 0.60998E-12 -12.2147 0.60998E-12 -12.2147 0.10000E+01 0.0000 66 Mg(HCO3)+ 0.51945E-14 -14.2845 0.43462E-14 -14.3619 0.83670E+00 -0.0774 67 MgCl+ 0.24930E-14 -14.6033 0.20859E-14 -14.6807 0.83670E+00 -0.0774 68 MgF+ 0.22834E-15 -15.6414 0.19106E-15 -15.7188 0.83670E+00 -0.0774 69 MgOH+ 0.68193E-10 -10.1663 0.57057E-10 -10.2437 0.83670E+00 -0.0774 71 MnF+ 0.63764E-16 -16.1954 0.53352E-16 -16.2729 0.83670E+00 -0.0774 72 MnO,aq 0.17914E-08 -8.7468 0.17914E-08 -8.7468 0.10000E+01 0.0000 73 MnOH+ 0.46883E-09 -9.3290 0.39227E-09 -9.4064 0.83670E+00 -0.0774 74 MnO2-2 0.20409E-10 -10.6902 0.10571E-10 -10.9759 0.51796E+00 -0.2857 75 HMnO2- 0.20798E-09 -9.6820 0.17368E-09 -9.7602 0.83510E+00 -0.0783 78 MnCl+ 0.93845E-14 -14.0276 0.78520E-14 -14.1050 0.83670E+00 -0.0774 79 MnSO4,aq 0.12911E-18 -18.8890 0.12911E-18 -18.8890 0.10000E+01 0.0000 80 NaCl,aq 0.72037E-06 -6.1424 0.72037E-06 -6.1424 0.10000E+01 0.0000 81 NaF,aq 0.12641E-08 -8.8982 0.12641E-08 -8.8982 0.10000E+01 0.0000 82 NaOH,aq 0.95013E-04 -4.0222 0.95013E-04 -4.0222 0.10000E+01 0.0000 84 OH- 0.92424E-02 -2.0342 0.77044E-02 -2.1133 0.83359E+00 -0.0790 89 HPO3-2 0.55256E-15 -15.2576 0.28621E-15 -15.5433 0.51796E+00 -0.2857 91 H2PO3- 0.51540E-19 -19.2879 0.43041E-19 -19.3661 0.83510E+00 -0.0783 92 H3PO4,aq 0.92552E-18 -18.0336 0.92552E-18 -18.0336 0.10000E+01 0.0000 93 H2PO4- 0.38943E-10 -10.4096 0.32552E-10 -10.4874 0.83589E+00 -0.0778 94 PO4-3 0.10560E-08 -8.9763 0.25600E-09 -9.5918 0.24241E+00 -0.6154 98 HP2O7-3 0.95760E-18 -18.0188 0.22122E-18 -18.6552 0.23102E+00 -0.6364 99 P2O7-4 0.91563E-17 -17.0383 0.70473E-18 -18.1520 0.76966E-01 -1.1137 100 H2S,aq 0.88265E-08 -8.0542 0.87959E-08 -8.0557 0.99653E+00 -0.0015 101 S2-2 0.15785E-13 -13.8018 0.81761E-14 -14.0875 0.51796E+00 -0.2857 107 SO3-2 0.44373E-16 -16.3529 0.23317E-16 -16.6323 0.52547E+00 -0.2795 108 HSO3- 0.13110E-18 -18.8824 0.10948E-18 -18.9607 0.83510E+00 -0.0783 109 HSO4- 0.39670E-17 -17.4015 0.33224E-17 -17.4785 0.83752E+00 -0.0770 Charge balance for all species = -.6133E-08 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.8926031E-10 -.2222343E-01 -.2236091E+02 0.0000 2 H2O 0.1000000E+01 0.5550479E+02 0.9981956E+06 0.0000 3 Cl- 0.1569529E-03 0.1576736E-03 0.5580276E+01 6.2425 4 SO4-- 0.8856396E-10 -.1333735E-04 -.1278978E+01 9.9124 5 HCO3- 0.1836352E-04 0.6527253E-04 0.3975818E+01 5.3113 6 HS- 0.4543708E-04 0.5878334E-04 0.1940700E+01 5.7042 7 Al+++ 0.9828217E-29 0.5159579E-05 0.1389710E+00 0.7306 8 H4SiO4 0.7029837E-03 0.1353196E-01 0.1298367E+04 -3.1531 9 Ca++ 0.1183661E-06 0.2158918E-06 0.8637458E-02 13.0352 10 Mg++ 0.2115431E-10 0.9318173E-10 0.2261492E-05 9.2854 11 Fe++ 0.4499403E-13 0.2737705E-07 0.1526266E-02 6.6136 12 K+ 0.1565137E-03 0.1572596E-03 0.6138466E+01 6.2420 13 Na+ 0.1986227E-01 0.2230574E-01 0.5119122E+03 8.3447 14 Mn++ 0.1893111E-10 0.2507545E-08 0.1375198E-03 9.2380 15 F- 0.3906890E-06 0.3919537E-06 0.7433380E-02 3.6377 16 HPO4-- 0.4532500E-07 0.4642000E-07 0.4447593E-02 12.6216 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.1995870E-01 -.1995810E-01 -.6088007E-06 0.0000000E+00 2 H2O 0.4984692E+02 0.4984693E+02 -.5650161E-06 0.0000000E+00 3 Cl- 0.1416012E-03 0.1416012E-03 0.0000000E+00 0.0000000E+00 4 SO4-- -.1197681E-04 -.1197781E-04 0.1000736E-08 0.0000000E+00 5 HCO3- 0.5861900E-04 0.5861900E-04 0.0000000E+00 0.0000000E+00 6 HS- 0.5279028E-04 0.5279128E-04 -.1000736E-08 0.0000000E+00 7 Al+++ 0.4775352E-05 0.4633639E-05 0.1417131E-06 0.0000000E+00 8 H4SiO4 0.1215302E-01 0.1215259E-01 0.4349584E-06 0.0000000E+00 9 Ca++ 0.2080835E-06 0.1938850E-06 0.1419854E-07 0.0000000E+00 10 Mg++ 0.8368328E-10 0.8368328E-10 0.0000000E+00 0.0000000E+00 11 Fe++ 0.3259227E-07 0.2458638E-07 0.8005888E-08 0.0000000E+00 12 K+ 0.1412294E-03 0.1412294E-03 0.0000000E+00 0.0000000E+00 13 Na+ 0.2003215E-01 0.2003201E-01 0.1402533E-06 0.0000000E+00 14 Mn++ 0.2251939E-08 0.2251939E-08 0.0000000E+00 0.0000000E+00 15 F- 0.3520000E-06 0.3520000E-06 0.0000000E+00 0.0000000E+00 16 HPO4-- 0.4168819E-07 0.4168819E-07 0.0000000E+00 0.0000000E+00 Chg. balance for solid moles: -.2647E-22 Mass of aqueous solution: 0.899631E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 0.0006300 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 0.1403E-06 -6.853 0.3678E-04 -4.434 93.96 0.1412E-04 andradite 0.4003E-08 -8.398 0.2034E-05 -5.692 5.197 0.5285E-06 grossular 0.7299E-09 -9.137 0.3288E-06 -6.483 0.8400 0.9148E-07 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8458E+00 0.8458E+00 1.0000 -0.073 grossular 0.1542E+00 0.1542E+00 1.0000 -0.812 Solid products produced: Mass = 0.000039 g Volume = 0.000015 cm3 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.0006300 moles log = -3.2007 Original solution: 1000.0103000 g Original solution / Rock added: 1587317.94 (Water/Rock Ratio), log = 6.2007 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0437 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9779E+00 0.9856 0.1006E+01 0.1021E+01 CO2,gas 0.2506E-06 1.0069 0.2633E-06 0.2615E-06 CH4,gas 0.1716E-01 1.0124 0.1813E-01 0.1791E-01 H2,gas 0.4907E-02 1.0006 0.5124E-02 0.5121E-02 H2S,gas 0.2326E-06 0.9959 0.2418E-06 0.2428E-06 S2,gas 0.8008E-28 1.0000 0.8357E-28 0.8357E-28 CO,gas 0.3445E-12 1.0000 0.3596E-12 0.3596E-12 SO3,gas 0.9367E-46 1.0000 0.9775E-46 0.9775E-46 SO2,gas 0.1867E-25 1.0000 0.1949E-25 0.1949E-25 HF,gas 0.3933E-15 1.0000 0.4104E-15 0.4104E-15 HCl,gas 0.3045E-17 1.0000 0.3178E-17 0.3178E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 17 albite -0.38 -0.38 0.00 0.000 0.11184E-10 23 andradite 39.01 39.01 0.00 0.000 -0.12132E-10 24 grossular 32.73 32.73 0.00 0.000 0.24265E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -14.94 -8.28 -2.760 0.14135E+05 -6.580 3 CH4,gas 4.54 1.10 -3.44 -0.860 0.58748E+04 -1.742 4 H2,gas 8.00 4.01 -3.99 -2.280 0.68117E+04 -2.290 5 H2S,gas -6.23 -14.55 -8.32 -4.158 0.14199E+05 -6.617 6 S2,gas -7.34 -37.11 -29.78 -4.581 0.50843E+05 -28.078 7 CO,gas 3.21 -10.93 -14.14 -4.352 0.24149E+05 -12.444 8 SO3,gas 17.12 -30.59 -47.71 -11.927 0.81462E+05 -46.010 9 SO2,gas 0.83 -26.58 -27.41 -7.309 0.46800E+05 -25.710 10 HF,gas 0.47 -16.61 -17.09 -8.543 0.29173E+05 -15.387 11 HCl,gas 5.19 -14.01 -19.20 -9.598 0.32778E+05 -17.498 12 acmite 7.71 6.65 -1.06 -0.110 0.18146E+04 16 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 20 spessartine 24.46 19.72 -4.74 -0.237 0.80955E+04 21 analcite 3.32 2.77 -0.55 -0.061 0.94367E+03 27 annite 20.12 17.35 -2.77 -0.154 0.47281E+04 28 phlogopite 27.06 25.37 -1.69 -0.094 0.28941E+04 30 anorthite 12.71 8.19 -4.52 -0.348 0.77177E+04 33 apatite-OH -18.15 -18.46 -0.31 -0.023 0.52160E+03 34 apatite-F -34.30 -35.07 -0.77 -0.064 0.13153E+04 38 aragonite 0.97 -1.90 -2.87 -0.957 0.49004E+04 39 brucite 12.57 9.29 -3.28 -0.657 0.56059E+04 40 calcite 0.81 -1.90 -2.72 -0.905 0.46362E+04 41 carnegieite-low 9.02 5.92 -3.10 -0.443 0.52950E+04 42 carnegieite-high 10.09 5.92 -4.17 -0.596 0.71220E+04 43 carpholite-Mg 8.58 4.44 -4.14 -0.276 0.70716E+04 44 carpholite-Fe 6.71 1.77 -4.94 -0.330 0.84415E+04 45 celadonite 5.34 3.65 -1.70 -0.100 0.28955E+04 46 celadonite-Fe 3.88 0.97 -2.90 -0.171 0.49559E+04 47 chrysotile 23.89 21.55 -2.34 -0.195 0.39995E+04 49 clinochlore 39.07 38.43 -0.64 -0.020 0.10936E+04 50 daphnite 28.97 25.07 -3.90 -0.122 0.66507E+04 52 chlorite-Al-free 47.17 43.10 -4.07 -0.170 0.69541E+04 54 chloritoid-Fe 9.17 4.92 -4.25 -0.283 0.72598E+04 55 chloritoid-Mn 11.40 7.55 -3.85 -0.257 0.65821E+04 57 coesite -2.38 -3.15 -0.78 -0.259 0.13267E+04 64 cristobalite -2.56 -3.15 -0.59 -0.198 0.10120E+04 66 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71234E+04 68 diaspore 2.87 0.73 -2.14 -0.357 0.36592E+04 69 diamond -3.10 -6.92 -3.82 -1.090 0.65147E+04 70 diopside 16.18 16.01 -0.17 -0.017 0.28493E+03 71 hedenbergite 14.21 13.34 -0.87 -0.087 0.14779E+04 76 clinoenstatite 17.17 12.26 -4.90 -0.490 0.83694E+04 78 epidote 24.67 22.68 -1.99 -0.096 0.33962E+04 79 clinozoisite 22.81 18.80 -4.00 -0.182 0.68348E+04 80 epidote-Fe 29.84 26.56 -3.28 -0.170 0.56041E+04 81 fayalite 14.05 10.07 -3.97 -0.567 0.67813E+04 82 ferrosilite 11.15 6.92 -4.23 -0.423 0.72198E+04 86 gibbsite 4.08 0.73 -3.35 -0.478 0.57178E+04 87 glaucophane 22.97 20.78 -2.19 -0.059 0.37436E+04 88 glaucophane-Fe 17.28 12.77 -4.51 -0.122 0.76987E+04 89 graphite -3.55 -6.92 -3.37 -0.963 0.57569E+04 90 greenalite 16.14 13.53 -2.60 -0.217 0.44476E+04 93 hematite 12.57 9.22 -3.35 -0.406 0.57190E+04 94 heulandite -5.83 -7.57 -1.75 -0.079 0.29841E+04 98 jadeite 4.22 2.77 -1.45 -0.145 0.24692E+04 100 kalsilite 7.58 3.82 -3.76 -0.538 0.64275E+04 101 kaolinite -1.33 -4.84 -3.51 -0.319 0.59968E+04 104 laumontite 2.88 1.88 -1.00 -0.067 0.17061E+04 105 lawsonite 9.62 8.19 -1.43 -0.095 0.24344E+04 106 leucite 4.12 0.67 -3.45 -0.345 0.58948E+04 108 lizardite 23.24 21.55 -1.69 -0.141 0.28921E+04 110 magnetite 20.09 15.83 -4.26 -0.348 0.72687E+04 111 minnesotaite 10.39 7.23 -3.16 -0.186 0.53947E+04 115 manganosite 14.06 9.24 -4.82 -1.205 0.82302E+04 119 microcline -2.49 -2.49 0.00 0.000 0.53192E-01 123 muscovite 2.58 -1.03 -3.61 -0.212 0.61601E+04 124 paragonite 4.24 1.08 -3.16 -0.186 0.53991E+04 125 nepheline 8.34 5.92 -2.42 -0.345 0.41273E+04 137 phlogopite-Na 29.65 27.47 -2.17 -0.121 0.37129E+04 139 prehnite 19.37 18.07 -1.30 -0.076 0.22186E+04 140 prehnite-Fe 22.50 21.95 -0.55 -0.033 0.93498E+03 141 pumpellyite-Fe 46.27 43.49 -2.78 -0.062 0.47471E+04 142 pumpellyite-Mg 48.99 46.16 -2.83 -0.063 0.48387E+04 146 pyrrhotite -4.26 -7.93 -3.67 -1.224 0.62695E+04 147 pyrrhotiteFe0.875 -6.02 -9.26 -3.24 -1.191 0.55308E+04 148 pyroxmangite 7.40 6.08 -1.31 -0.263 0.22432E+04 149 pyrophyllite -6.18 -11.15 -4.98 -0.311 0.84950E+04 150 quartz -2.99 -3.15 -0.16 -0.055 0.27938E+03 154 rhodochrosite -0.98 -5.70 -4.72 -1.575 0.80667E+04 155 rhodonite 7.45 6.08 -1.36 -0.272 0.23234E+04 156 sanidine -1.28 -2.49 -1.21 -0.093 0.20678E+04 166 stilbite -7.52 -7.57 -0.05 -0.003 0.90271E+02 167 stilpnomelane-Fe 13.02 12.43 -0.59 -0.018 0.10092E+04 168 stilpnomelane-Mg 27.44 25.78 -1.66 -0.049 0.28287E+04 174 talc 16.49 15.24 -1.25 -0.073 0.21294E+04 177 tephroite 18.09 15.32 -2.76 -0.395 0.47175E+04 181 tridymite -2.63 -3.15 -0.53 -0.176 0.89935E+03 182 tremolite 47.87 47.27 -0.60 -0.016 0.10183E+04 183 ferroactinolite 38.45 33.91 -4.54 -0.123 0.77490E+04 184 troilite-low -4.41 -7.93 -3.52 -1.174 0.60124E+04 190 wairakite 3.95 1.88 -2.07 -0.122 0.35280E+04 191 walstromite 11.51 9.88 -1.63 -0.325 0.27782E+04 192 wollastonite 10.46 9.88 -0.58 -0.116 0.98862E+03 193 pseudo-wollastonite 11.00 9.88 -1.12 -0.224 0.19084E+04 194 zoisite 22.85 18.80 -4.05 -0.184 0.69089E+04 195 akaganeite 7.75 4.61 -3.15 -0.680 0.53720E+04 202 chalcedony -2.80 -3.15 -0.35 -0.117 0.59867E+03 204 montmorillonite-Ca -2.29 -6.18 -3.89 -0.240 0.66359E+04 205 montmorillonite-K -2.24 -6.27 -4.03 -0.247 0.68834E+04 206 montmorillonite-Mg -2.48 -6.80 -4.32 -0.267 0.73693E+04 207 montmorillonite-Na -2.04 -5.57 -3.54 -0.217 0.60382E+04 208 nontronite-Ca 3.21 0.04 -3.18 -0.206 0.54255E+04 209 nontronite-H 2.53 -2.11 -4.65 -0.311 0.79338E+04 210 nontronite-K 3.34 -0.05 -3.39 -0.218 0.57962E+04 211 nontronite-Mg 3.07 -0.58 -3.66 -0.237 0.62431E+04 212 nontronite-Na 3.52 0.64 -2.88 -0.185 0.49171E+04 228 tobermorite 9.82 7.71 -2.12 -0.578 0.36160E+04 234 alabandite -0.98 -5.31 -4.33 -1.443 0.73932E+04 237 boehmite 4.41 0.73 -3.68 -0.613 0.62762E+04 239 ferrous-oxide 9.81 6.61 -3.20 -0.799 0.54604E+04 245 silica-amorphous -2.09 -3.15 -1.06 -0.354 0.18129E+04 247 an20ab80 2.02 1.33 -0.69 -0.053 0.11727E+04 248 an25ab75 2.65 1.76 -0.89 -0.068 0.15128E+04 249 an30ab70 3.28 2.19 -1.09 -0.084 0.18626E+04 250 tr.625ac.25prg.125 45.16 44.88 -0.29 -0.008 0.48985E+03 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 0.0000200 MOLES Current total amount of reactant added: 0.0006300 MOLES New total amount of reactant added: 0.0006500 MOLES Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.5508E-08 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 6 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 0.0006500 Water: Moles liquid = 0.4985E+02 kg liquid = 0.8981E+00 Moles total = 0.4985E+02 kg total = 0.8980E+00 Activity = 1.0000 Stoichiometric ionic strength = .1137167E-01 Osmotic coef. = 0.9673 True ionic strength = .2005500E-01 Chg. balance for total moles = -.5508E-08 Max. difference allowed = 0.1417E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.89292E-10 -10.0492 0.75019E-10 -10.1248 0.84016E+00 -0.0756 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.15708E-03 -3.8039 0.13118E-03 -3.8821 0.83510E+00 -0.0783 4 SO4-- 0.93259E-10 -10.0303 0.48407E-10 -10.3151 0.51906E+00 -0.2848 5 HCO3- 0.18960E-04 -4.7222 0.15857E-04 -4.7998 0.83632E+00 -0.0776 6 HS- 0.45978E-04 -4.3374 0.38402E-04 -4.4156 0.83522E+00 -0.0782 7 Al+++ 0.98327E-29 -29.0073 0.22692E-29 -29.6441 0.23078E+00 -0.6368 8 H4SiO4 0.70322E-03 -3.1529 0.70322E-03 -3.1529 0.10000E+01 0.0000 9 Ca++ 0.11812E-06 -6.9277 0.60863E-07 -7.2156 0.51524E+00 -0.2880 10 Mg++ 0.21155E-10 -10.6746 0.10850E-10 -10.9646 0.51288E+00 -0.2900 11 Fe++ 0.45000E-13 -13.3468 0.23105E-13 -13.6363 0.51345E+00 -0.2895 12 K+ 0.15651E-03 -3.8054 0.13093E-03 -3.8830 0.83652E+00 -0.0775 13 Na+ 0.19862E-01 -1.7020 0.16584E-01 -1.7803 0.83495E+00 -0.0783 14 Mn++ 0.18944E-10 -10.7225 0.97348E-11 -11.0117 0.51387E+00 -0.2891 15 F- 0.39957E-06 -6.3984 0.33299E-06 -6.4776 0.83337E+00 -0.0792 16 HPO4-- 0.45325E-07 -7.3437 0.23530E-07 -7.6284 0.51913E+00 -0.2847 18 HSiO3- 0.10481E-01 -1.9796 0.87527E-02 -2.0579 0.83510E+00 -0.0783 19 Ca(HSiO3)+ 0.14500E-07 -7.8386 0.12132E-07 -7.9161 0.83670E+00 -0.0774 20 Mg(HSiO3)+ 0.32170E-11 -11.4926 0.26917E-11 -11.5700 0.83670E+00 -0.0774 21 NaHSiO3,aq 0.23477E-02 -2.6294 0.23477E-02 -2.6294 0.10000E+01 0.0000 22 AlO+ 0.65559E-16 -16.1834 0.54853E-16 -16.2608 0.83670E+00 -0.0774 24 HAlO2,aq 0.14561E-09 -9.8368 0.14561E-09 -9.8368 0.10000E+01 0.0000 25 AlO2- 0.51544E-05 -5.2878 0.42966E-05 -5.3669 0.83359E+00 -0.0790 26 CH4,aq 0.12262E-04 -4.9114 0.12219E-04 -4.9130 0.99653E+00 -0.0015 27 C2H6,aq 0.66287E-14 -14.1786 0.66057E-14 -14.1801 0.99653E+00 -0.0015 31 CO,aq 0.24673E-15 -15.6078 0.24673E-15 -15.6078 0.10000E+01 0.0000 32 CO2,aq 0.25506E-08 -8.5933 0.25418E-08 -8.5949 0.99653E+00 -0.0015 33 CO3-2 0.35644E-04 -4.4480 0.18462E-04 -4.7337 0.51796E+00 -0.2857 34 CaCO3,aq 0.14089E-07 -7.8511 0.14089E-07 -7.8511 0.10000E+01 0.0000 35 Ca(HCO3)+ 0.29443E-10 -10.5310 0.24635E-10 -10.6085 0.83670E+00 -0.0774 36 CaCl+ 0.15442E-10 -10.8113 0.12921E-10 -10.8887 0.83670E+00 -0.0774 37 CaCl2,aq 0.40268E-15 -15.3950 0.40268E-15 -15.3950 0.10000E+01 0.0000 38 CaF+ 0.35365E-12 -12.4514 0.29590E-12 -12.5289 0.83670E+00 -0.0774 39 CaOH+ 0.69105E-07 -7.1605 0.57820E-07 -7.2379 0.83670E+00 -0.0774 40 CaSO4,aq 0.93555E-15 -15.0289 0.93555E-15 -15.0289 0.10000E+01 0.0000 41 HCl,aq 0.18033E-14 -14.7439 0.18033E-14 -14.7439 0.10000E+01 0.0000 45 HF,aq 0.17101E-12 -12.7670 0.17101E-12 -12.7670 0.10000E+01 0.0000 46 HF2- 0.23022E-19 -19.6378 0.19226E-19 -19.7161 0.83510E+00 -0.0783 48 FeCl+ 0.57338E-17 -17.2416 0.47975E-17 -17.3190 0.83670E+00 -0.0774 51 FeF+ 0.46990E-18 -18.3280 0.39317E-18 -18.4054 0.83670E+00 -0.0774 53 FeO,aq 0.15956E-09 -9.7971 0.15956E-09 -9.7971 0.10000E+01 0.0000 54 FeOH+ 0.11982E-10 -10.9215 0.10025E-10 -10.9989 0.83670E+00 -0.0774 55 HFeO2- 0.26649E-07 -7.5743 0.22254E-07 -7.6526 0.83510E+00 -0.0783 56 FeO+ 0.14539E-16 -16.8375 0.12165E-16 -16.9149 0.83670E+00 -0.0774 58 FeO2- 0.52962E-09 -9.2760 0.44229E-09 -9.3543 0.83510E+00 -0.0783 59 HFeO2,aq 0.42200E-11 -11.3747 0.42200E-11 -11.3747 0.10000E+01 0.0000 60 H2,aq 0.38776E-05 -5.4114 0.38641E-05 -5.4129 0.99653E+00 -0.0015 61 KCl,aq 0.31128E-09 -9.5068 0.31128E-09 -9.5068 0.10000E+01 0.0000 63 KOH,aq 0.74532E-06 -6.1277 0.74532E-06 -6.1277 0.10000E+01 0.0000 64 KSO4- 0.11777E-12 -12.9290 0.98347E-13 -13.0072 0.83510E+00 -0.0783 65 MgCO3,aq 0.62960E-12 -12.2009 0.62960E-12 -12.2009 0.10000E+01 0.0000 66 Mg(HCO3)+ 0.53634E-14 -14.2706 0.44876E-14 -14.3480 0.83670E+00 -0.0774 67 MgCl+ 0.24952E-14 -14.6029 0.20877E-14 -14.6803 0.83670E+00 -0.0774 68 MgF+ 0.23354E-15 -15.6316 0.19541E-15 -15.7091 0.83670E+00 -0.0774 69 MgOH+ 0.68172E-10 -10.1664 0.57039E-10 -10.2438 0.83670E+00 -0.0774 71 MnF+ 0.65257E-16 -16.1854 0.54600E-16 -16.2628 0.83670E+00 -0.0774 72 MnO,aq 0.17913E-08 -8.7468 0.17913E-08 -8.7468 0.10000E+01 0.0000 73 MnOH+ 0.46898E-09 -9.3288 0.39239E-09 -9.4063 0.83670E+00 -0.0774 74 MnO2-2 0.20394E-10 -10.6905 0.10563E-10 -10.9762 0.51796E+00 -0.2857 75 HMnO2- 0.20790E-09 -9.6822 0.17361E-09 -9.7604 0.83510E+00 -0.0783 78 MnCl+ 0.93986E-14 -14.0269 0.78638E-14 -14.1044 0.83670E+00 -0.0774 79 MnSO4,aq 0.13604E-18 -18.8663 0.13604E-18 -18.8663 0.10000E+01 0.0000 80 NaCl,aq 0.72096E-06 -6.1421 0.72096E-06 -6.1421 0.10000E+01 0.0000 81 NaF,aq 0.12929E-08 -8.8884 0.12929E-08 -8.8884 0.10000E+01 0.0000 82 NaOH,aq 0.94979E-04 -4.0224 0.94979E-04 -4.0224 0.10000E+01 0.0000 84 OH- 0.92392E-02 -2.0344 0.77017E-02 -2.1134 0.83359E+00 -0.0790 89 HPO3-2 0.54704E-15 -15.2620 0.28335E-15 -15.5477 0.51796E+00 -0.2857 91 H2PO3- 0.51042E-19 -19.2921 0.42625E-19 -19.3703 0.83510E+00 -0.0783 92 H3PO4,aq 0.92617E-18 -18.0333 0.92617E-18 -18.0333 0.10000E+01 0.0000 93 H2PO4- 0.38956E-10 -10.4094 0.32563E-10 -10.4873 0.83589E+00 -0.0779 94 PO4-3 0.10557E-08 -8.9765 0.25591E-09 -9.5919 0.24240E+00 -0.6155 98 HP2O7-3 0.95796E-18 -18.0187 0.22130E-18 -18.6550 0.23101E+00 -0.6364 99 P2O7-4 0.91567E-17 -17.0383 0.70472E-18 -18.1520 0.76961E-01 -1.1137 100 H2S,aq 0.89347E-08 -8.0489 0.89037E-08 -8.0504 0.99653E+00 -0.0015 101 S2-2 0.16326E-13 -13.7871 0.84564E-14 -14.0728 0.51796E+00 -0.2857 107 SO3-2 0.46259E-16 -16.3348 0.24307E-16 -16.6143 0.52546E+00 -0.2795 108 HSO3- 0.13672E-18 -18.8642 0.11417E-18 -18.9424 0.83510E+00 -0.0783 109 HSO4- 0.41787E-17 -17.3790 0.34997E-17 -17.4560 0.83752E+00 -0.0770 Charge balance for all species = -.6133E-08 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.8929210E-10 -.2222101E-01 -.2235847E+02 0.0000 2 H2O 0.1000000E+01 0.5550478E+02 0.9981954E+06 0.0000 3 Cl- 0.1570836E-03 0.1578049E-03 0.5584924E+01 6.2427 4 SO4-- 0.9325902E-10 -.1323101E-04 -.1268780E+01 9.9346 5 HCO3- 0.1896004E-04 0.6688263E-04 0.4073890E+01 5.3250 6 HS- 0.4597811E-04 0.5921814E-04 0.1955055E+01 5.7092 7 Al+++ 0.9832702E-29 0.5154500E-05 0.1388342E+00 0.7304 8 H4SiO4 0.7032155E-03 0.1353194E-01 0.1298365E+04 -3.1529 9 Ca++ 0.1181240E-06 0.2158638E-06 0.8636336E-02 13.0340 10 Mg++ 0.2115549E-10 0.9318169E-10 0.2261491E-05 9.2851 11 Fe++ 0.4500027E-13 0.2735432E-07 0.1524999E-02 6.6134 12 K+ 0.1565139E-03 0.1572595E-03 0.6138463E+01 6.2419 13 Na+ 0.1986235E-01 0.2230572E-01 0.5119119E+03 8.3445 14 Mn++ 0.1894404E-10 0.2507544E-08 0.1375197E-03 9.2380 15 F- 0.3995681E-06 0.4008615E-06 0.7602317E-02 3.6473 16 HPO4-- 0.4532532E-07 0.4641998E-07 0.4447591E-02 12.6213 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.1995655E-01 -.1995592E-01 -.6271296E-06 0.0000000E+00 2 H2O 0.4984694E+02 0.4984694E+02 -.5832779E-06 0.0000000E+00 3 Cl- 0.1417192E-03 0.1417192E-03 0.0000000E+00 0.0000000E+00 4 SO4-- -.1188131E-04 -.1188231E-04 0.1003287E-08 0.0000000E+00 5 HCO3- 0.6006500E-04 0.6006500E-04 0.0000000E+00 0.0000000E+00 6 HS- 0.5318078E-04 0.5318178E-04 -.1003287E-08 0.0000000E+00 7 Al+++ 0.4775352E-05 0.4629080E-05 0.1462723E-06 0.0000000E+00 8 H4SiO4 0.1215302E-01 0.1215257E-01 0.4486722E-06 0.0000000E+00 9 Ca++ 0.2080835E-06 0.1938599E-06 0.1422362E-07 0.0000000E+00 10 Mg++ 0.8368328E-10 0.8368328E-10 0.0000000E+00 0.0000000E+00 11 Fe++ 0.3259227E-07 0.2456598E-07 0.8026295E-08 0.0000000E+00 12 K+ 0.1412294E-03 0.1412294E-03 0.0000000E+00 0.0000000E+00 13 Na+ 0.2003215E-01 0.2003201E-01 0.1448162E-06 0.0000000E+00 14 Mn++ 0.2251939E-08 0.2251939E-08 0.0000000E+00 0.0000000E+00 15 F- 0.3600000E-06 0.3600000E-06 0.0000000E+00 0.0000000E+00 16 HPO4-- 0.4168819E-07 0.4168819E-07 0.0000000E+00 0.0000000E+00 Chg. balance for solid moles: 0.5294E-22 Mass of aqueous solution: 0.899631E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 0.0006500 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 0.1448E-06 -6.839 0.3797E-04 -4.421 94.13 0.1458E-04 andradite 0.4013E-08 -8.397 0.2039E-05 -5.690 5.055 0.5299E-06 grossular 0.7281E-09 -9.138 0.3280E-06 -6.484 0.8130 0.9125E-07 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8464E+00 0.8464E+00 1.0000 -0.072 grossular 0.1536E+00 0.1536E+00 1.0000 -0.814 Solid products produced: Mass = 0.000040 g Volume = 0.000015 cm3 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.0006500 moles log = -3.1871 Original solution: 1000.0103000 g Original solution / Rock added: 1538477.38 (Water/Rock Ratio), log = 6.1871 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0435 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9781E+00 0.9856 0.1006E+01 0.1021E+01 CO2,gas 0.2588E-06 1.0069 0.2719E-06 0.2701E-06 CH4,gas 0.1703E-01 1.0124 0.1799E-01 0.1777E-01 H2,gas 0.4859E-02 1.0006 0.5073E-02 0.5070E-02 H2S,gas 0.2355E-06 0.9959 0.2448E-06 0.2458E-06 S2,gas 0.8373E-28 1.0000 0.8737E-28 0.8737E-28 CO,gas 0.3524E-12 1.0000 0.3677E-12 0.3677E-12 SO3,gas 0.9872E-46 1.0000 0.1030E-45 0.1030E-45 SO2,gas 0.1948E-25 1.0000 0.2033E-25 0.2033E-25 HF,gas 0.4024E-15 1.0000 0.4199E-15 0.4199E-15 HCl,gas 0.3050E-17 1.0000 0.3182E-17 0.3182E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 17 albite -0.38 -0.38 0.00 0.000 -0.94784E-12 23 andradite 39.01 39.01 0.00 0.000 -0.12132E-10 24 grossular 32.73 32.73 0.00 0.000 0.36397E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -14.92 -8.26 -2.755 0.14111E+05 -6.566 3 CH4,gas 4.54 1.10 -3.44 -0.861 0.58806E+04 -1.745 4 H2,gas 8.00 4.01 -3.99 -2.282 0.68191E+04 -2.295 5 H2S,gas -6.23 -14.54 -8.31 -4.155 0.14190E+05 -6.611 6 S2,gas -7.34 -37.09 -29.76 -4.578 0.50810E+05 -28.059 7 CO,gas 3.21 -10.92 -14.13 -4.349 0.24133E+05 -12.435 8 SO3,gas 17.12 -30.56 -47.69 -11.922 0.81423E+05 -45.987 9 SO2,gas 0.83 -26.56 -27.39 -7.304 0.46769E+05 -25.692 10 HF,gas 0.47 -16.60 -17.08 -8.538 0.29157E+05 -15.377 11 HCl,gas 5.19 -14.01 -19.20 -9.598 0.32777E+05 -17.497 12 acmite 7.71 6.65 -1.06 -0.110 0.18111E+04 16 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 20 spessartine 24.46 19.72 -4.74 -0.237 0.80958E+04 21 analcite 3.32 2.77 -0.55 -0.061 0.94392E+03 27 annite 20.12 17.35 -2.77 -0.154 0.47294E+04 28 phlogopite 27.06 25.37 -1.70 -0.094 0.28956E+04 30 anorthite 12.71 8.19 -4.52 -0.348 0.77202E+04 33 apatite-OH -18.15 -18.46 -0.31 -0.024 0.53032E+03 34 apatite-F -34.30 -35.07 -0.77 -0.064 0.13070E+04 38 aragonite 0.97 -1.89 -2.86 -0.952 0.48785E+04 39 brucite 12.57 9.29 -3.28 -0.657 0.56064E+04 40 calcite 0.81 -1.89 -2.70 -0.901 0.46142E+04 41 carnegieite-low 9.02 5.92 -3.10 -0.443 0.52955E+04 42 carnegieite-high 10.09 5.92 -4.17 -0.596 0.71224E+04 43 carpholite-Mg 8.58 4.44 -4.14 -0.276 0.70725E+04 44 carpholite-Fe 6.71 1.77 -4.94 -0.330 0.84424E+04 45 celadonite 5.34 3.65 -1.70 -0.100 0.28958E+04 46 celadonite-Fe 3.88 0.97 -2.90 -0.171 0.49561E+04 47 chrysotile 23.89 21.55 -2.34 -0.195 0.40005E+04 49 clinochlore 39.07 38.43 -0.64 -0.020 0.10963E+04 50 daphnite 28.97 25.07 -3.90 -0.122 0.66531E+04 52 chlorite-Al-free 47.17 43.10 -4.07 -0.170 0.69561E+04 54 chloritoid-Fe 9.17 4.92 -4.25 -0.283 0.72610E+04 55 chloritoid-Mn 11.40 7.55 -3.86 -0.257 0.65828E+04 57 coesite -2.38 -3.15 -0.78 -0.259 0.13264E+04 64 cristobalite -2.56 -3.15 -0.59 -0.198 0.10118E+04 66 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71234E+04 68 diaspore 2.87 0.73 -2.14 -0.357 0.36597E+04 69 diamond -3.10 -6.91 -3.81 -1.089 0.65056E+04 70 diopside 16.18 16.01 -0.17 -0.017 0.28699E+03 71 hedenbergite 14.21 13.34 -0.87 -0.087 0.14799E+04 76 clinoenstatite 17.17 12.26 -4.90 -0.490 0.83699E+04 78 epidote 24.67 22.68 -1.99 -0.096 0.33972E+04 79 clinozoisite 22.81 18.80 -4.01 -0.182 0.68396E+04 80 epidote-Fe 29.84 26.56 -3.28 -0.170 0.56014E+04 81 fayalite 14.05 10.07 -3.97 -0.567 0.67819E+04 82 ferrosilite 11.15 6.92 -4.23 -0.423 0.72201E+04 86 gibbsite 4.08 0.73 -3.35 -0.478 0.57183E+04 87 glaucophane 22.97 20.78 -2.19 -0.059 0.37446E+04 88 glaucophane-Fe 17.28 12.77 -4.51 -0.122 0.76995E+04 89 graphite -3.55 -6.91 -3.37 -0.962 0.57479E+04 90 greenalite 16.14 13.53 -2.61 -0.217 0.44484E+04 93 hematite 12.57 9.22 -3.35 -0.406 0.57124E+04 94 heulandite -5.83 -7.58 -1.75 -0.079 0.29854E+04 98 jadeite 4.22 2.77 -1.45 -0.145 0.24694E+04 100 kalsilite 7.58 3.82 -3.76 -0.538 0.64280E+04 101 kaolinite -1.33 -4.85 -3.51 -0.319 0.59972E+04 104 laumontite 2.88 1.88 -1.00 -0.067 0.17081E+04 105 lawsonite 9.62 8.19 -1.43 -0.095 0.24369E+04 106 leucite 4.12 0.67 -3.45 -0.345 0.58950E+04 108 lizardite 23.24 21.55 -1.69 -0.141 0.28931E+04 110 magnetite 20.09 15.83 -4.25 -0.347 0.72625E+04 111 minnesotaite 10.39 7.23 -3.16 -0.186 0.53950E+04 115 manganosite 14.06 9.24 -4.82 -1.205 0.82302E+04 119 microcline -2.49 -2.49 0.00 0.000 0.54896E-01 123 muscovite 2.58 -1.03 -3.61 -0.212 0.61610E+04 124 paragonite 4.24 1.08 -3.16 -0.186 0.54000E+04 125 nepheline 8.34 5.92 -2.42 -0.345 0.41278E+04 137 phlogopite-Na 29.65 27.47 -2.18 -0.121 0.37143E+04 139 prehnite 19.37 18.07 -1.30 -0.077 0.22230E+04 140 prehnite-Fe 22.50 21.95 -0.55 -0.033 0.93553E+03 141 pumpellyite-Fe 46.27 43.48 -2.79 -0.062 0.47566E+04 142 pumpellyite-Mg 48.99 46.16 -2.84 -0.063 0.48483E+04 146 pyrrhotite -4.26 -7.93 -3.67 -1.222 0.62609E+04 147 pyrrhotiteFe0.875 -6.02 -9.25 -3.23 -1.189 0.55213E+04 148 pyroxmangite 7.40 6.09 -1.31 -0.263 0.22430E+04 149 pyrophyllite -6.18 -11.15 -4.98 -0.311 0.84949E+04 150 quartz -2.99 -3.15 -0.16 -0.054 0.27913E+03 154 rhodochrosite -0.98 -5.69 -4.71 -1.570 0.80427E+04 155 rhodonite 7.45 6.09 -1.36 -0.272 0.23232E+04 156 sanidine -1.28 -2.49 -1.21 -0.093 0.20678E+04 166 stilbite -7.52 -7.58 -0.05 -0.003 0.91555E+02 167 stilpnomelane-Fe 13.02 12.43 -0.59 -0.018 0.10105E+04 168 stilpnomelane-Mg 27.44 25.78 -1.66 -0.049 0.28303E+04 174 talc 16.49 15.24 -1.25 -0.073 0.21299E+04 177 tephroite 18.09 15.32 -2.76 -0.395 0.47173E+04 181 tridymite -2.63 -3.15 -0.53 -0.176 0.89911E+03 182 tremolite 47.87 47.27 -0.60 -0.016 0.10229E+04 183 ferroactinolite 38.45 33.91 -4.54 -0.123 0.77533E+04 184 troilite-low -4.41 -7.93 -3.52 -1.172 0.60038E+04 190 wairakite 3.95 1.88 -2.07 -0.122 0.35300E+04 191 walstromite 11.51 9.88 -1.63 -0.326 0.27800E+04 192 wollastonite 10.46 9.88 -0.58 -0.116 0.99043E+03 193 pseudo-wollastonite 11.00 9.88 -1.12 -0.224 0.19103E+04 194 zoisite 22.85 18.80 -4.05 -0.184 0.69137E+04 195 akaganeite 7.75 4.61 -3.14 -0.680 0.53687E+04 202 chalcedony -2.80 -3.15 -0.35 -0.117 0.59843E+03 204 montmorillonite-Ca -2.29 -6.18 -3.89 -0.240 0.66362E+04 205 montmorillonite-K -2.24 -6.27 -4.03 -0.247 0.68834E+04 206 montmorillonite-Mg -2.48 -6.80 -4.32 -0.267 0.73694E+04 207 montmorillonite-Na -2.04 -5.57 -3.54 -0.217 0.60383E+04 208 nontronite-Ca 3.21 0.04 -3.17 -0.206 0.54186E+04 209 nontronite-H 2.53 -2.11 -4.64 -0.311 0.79264E+04 210 nontronite-K 3.34 -0.05 -3.39 -0.218 0.57890E+04 211 nontronite-Mg 3.07 -0.58 -3.65 -0.237 0.62358E+04 212 nontronite-Na 3.52 0.64 -2.88 -0.185 0.49099E+04 228 tobermorite 9.82 7.70 -2.12 -0.578 0.36175E+04 234 alabandite -0.98 -5.30 -4.32 -1.442 0.73842E+04 237 boehmite 4.41 0.73 -3.68 -0.613 0.62766E+04 239 ferrous-oxide 9.81 6.61 -3.20 -0.800 0.54609E+04 245 silica-amorphous -2.09 -3.15 -1.06 -0.354 0.18126E+04 247 an20ab80 2.02 1.33 -0.69 -0.053 0.11732E+04 248 an25ab75 2.65 1.76 -0.89 -0.068 0.15135E+04 249 an30ab70 3.28 2.19 -1.09 -0.084 0.18633E+04 250 tr.625ac.25prg.125 45.16 44.88 -0.29 -0.008 0.49460E+03 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 0.0000200 MOLES Current total amount of reactant added: 0.0006500 MOLES New total amount of reactant added: 0.0006700 MOLES Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.5508E-08 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 6 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 0.0006700 Water: Moles liquid = 0.4985E+02 kg liquid = 0.8981E+00 Moles total = 0.4985E+02 kg total = 0.8980E+00 Activity = 1.0000 Stoichiometric ionic strength = .1137295E-01 Osmotic coef. = 0.9672 True ionic strength = .2005618E-01 Chg. balance for total moles = -.5508E-08 Max. difference allowed = 0.1418E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.89324E-10 -10.0490 0.75046E-10 -10.1247 0.84015E+00 -0.0756 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.15721E-03 -3.8035 0.13129E-03 -3.8818 0.83509E+00 -0.0783 4 SO4-- 0.98103E-10 -10.0083 0.50920E-10 -10.2931 0.51905E+00 -0.2848 5 HCO3- 0.19557E-04 -4.7087 0.16356E-04 -4.7863 0.83632E+00 -0.0776 6 HS- 0.46519E-04 -4.3324 0.38854E-04 -4.4106 0.83522E+00 -0.0782 7 Al+++ 0.98372E-29 -29.0071 0.22701E-29 -29.6439 0.23077E+00 -0.6368 8 H4SiO4 0.70345E-03 -3.1528 0.70345E-03 -3.1528 0.10000E+01 0.0000 9 Ca++ 0.11788E-06 -6.9285 0.60739E-07 -7.2165 0.51524E+00 -0.2880 10 Mg++ 0.21157E-10 -10.6746 0.10851E-10 -10.9645 0.51288E+00 -0.2900 11 Fe++ 0.45010E-13 -13.3467 0.23110E-13 -13.6362 0.51344E+00 -0.2895 12 K+ 0.15651E-03 -3.8054 0.13093E-03 -3.8830 0.83652E+00 -0.0775 13 Na+ 0.19862E-01 -1.7020 0.16584E-01 -1.7803 0.83494E+00 -0.0783 14 Mn++ 0.18957E-10 -10.7222 0.97413E-11 -11.0114 0.51387E+00 -0.2892 15 F- 0.40845E-06 -6.3889 0.34039E-06 -6.4680 0.83337E+00 -0.0792 16 HPO4-- 0.45326E-07 -7.3437 0.23530E-07 -7.6284 0.51913E+00 -0.2847 18 HSiO3- 0.10481E-01 -1.9796 0.87525E-02 -2.0579 0.83509E+00 -0.0783 19 Ca(HSiO3)+ 0.14470E-07 -7.8395 0.12107E-07 -7.9170 0.83670E+00 -0.0774 20 Mg(HSiO3)+ 0.32171E-11 -11.4925 0.26917E-11 -11.5700 0.83670E+00 -0.0774 21 NaHSiO3,aq 0.23476E-02 -2.6294 0.23476E-02 -2.6294 0.10000E+01 0.0000 22 AlO+ 0.65540E-16 -16.1835 0.54837E-16 -16.2609 0.83670E+00 -0.0774 24 HAlO2,aq 0.14552E-09 -9.8371 0.14552E-09 -9.8371 0.10000E+01 0.0000 25 AlO2- 0.51493E-05 -5.2883 0.42924E-05 -5.3673 0.83358E+00 -0.0791 26 CH4,aq 0.12165E-04 -4.9149 0.12123E-04 -4.9164 0.99653E+00 -0.0015 27 C2H6,aq 0.65888E-14 -14.1812 0.65659E-14 -14.1827 0.99653E+00 -0.0015 31 CO,aq 0.25210E-15 -15.5984 0.25210E-15 -15.5984 0.10000E+01 0.0000 32 CO2,aq 0.26319E-08 -8.5797 0.26227E-08 -8.5812 0.99653E+00 -0.0015 33 CO3-2 0.36754E-04 -4.4347 0.19037E-04 -4.7204 0.51795E+00 -0.2857 34 CaCO3,aq 0.14498E-07 -7.8387 0.14498E-07 -7.8387 0.10000E+01 0.0000 35 Ca(HCO3)+ 0.30308E-10 -10.5184 0.25358E-10 -10.5959 0.83670E+00 -0.0774 36 CaCl+ 0.15424E-10 -10.8118 0.12905E-10 -10.8892 0.83670E+00 -0.0774 37 CaCl2,aq 0.40252E-15 -15.3952 0.40252E-15 -15.3952 0.10000E+01 0.0000 38 CaF+ 0.36077E-12 -12.4428 0.30185E-12 -12.5202 0.83670E+00 -0.0774 39 CaOH+ 0.68940E-07 -7.1615 0.57682E-07 -7.2390 0.83670E+00 -0.0774 40 CaSO4,aq 0.98212E-15 -15.0078 0.98212E-15 -15.0078 0.10000E+01 0.0000 41 HCl,aq 0.18055E-14 -14.7434 0.18055E-14 -14.7434 0.10000E+01 0.0000 45 HF,aq 0.17487E-12 -12.7573 0.17487E-12 -12.7573 0.10000E+01 0.0000 46 HF2- 0.24065E-19 -19.6186 0.20097E-19 -19.6969 0.83509E+00 -0.0783 48 FeCl+ 0.57397E-17 -17.2411 0.48024E-17 -17.3185 0.83670E+00 -0.0774 51 FeF+ 0.48044E-18 -18.3184 0.40198E-18 -18.3958 0.83670E+00 -0.0774 53 FeO,aq 0.15948E-09 -9.7973 0.15948E-09 -9.7973 0.10000E+01 0.0000 54 FeOH+ 0.11980E-10 -10.9215 0.10024E-10 -10.9990 0.83670E+00 -0.0774 55 HFeO2- 0.26626E-07 -7.5747 0.22235E-07 -7.6530 0.83509E+00 -0.0783 56 FeO+ 0.14608E-16 -16.8354 0.12223E-16 -16.9128 0.83670E+00 -0.0774 58 FeO2- 0.53177E-09 -9.2743 0.44408E-09 -9.3525 0.83509E+00 -0.0783 59 HFeO2,aq 0.42386E-11 -11.3728 0.42386E-11 -11.3728 0.10000E+01 0.0000 60 H2,aq 0.38397E-05 -5.4157 0.38264E-05 -5.4172 0.99653E+00 -0.0015 61 KCl,aq 0.31154E-09 -9.5065 0.31154E-09 -9.5065 0.10000E+01 0.0000 63 KOH,aq 0.74505E-06 -6.1278 0.74505E-06 -6.1278 0.10000E+01 0.0000 64 KSO4- 0.12388E-12 -12.9070 0.10345E-12 -12.9853 0.83509E+00 -0.0783 65 MgCO3,aq 0.64921E-12 -12.1876 0.64921E-12 -12.1876 0.10000E+01 0.0000 66 Mg(HCO3)+ 0.55325E-14 -14.2571 0.46290E-14 -14.3345 0.83670E+00 -0.0774 67 MgCl+ 0.24973E-14 -14.6025 0.20895E-14 -14.6800 0.83670E+00 -0.0774 68 MgF+ 0.23874E-15 -15.6221 0.19975E-15 -15.6995 0.83670E+00 -0.0774 69 MgOH+ 0.68150E-10 -10.1665 0.57021E-10 -10.2440 0.83670E+00 -0.0774 71 MnF+ 0.66751E-16 -16.1755 0.55851E-16 -16.2530 0.83670E+00 -0.0774 72 MnO,aq 0.17913E-08 -8.7468 0.17913E-08 -8.7468 0.10000E+01 0.0000 73 MnOH+ 0.46913E-09 -9.3287 0.39252E-09 -9.4061 0.83670E+00 -0.0774 74 MnO2-2 0.20379E-10 -10.6908 0.10555E-10 -10.9765 0.51795E+00 -0.2857 75 HMnO2- 0.20782E-09 -9.6823 0.17355E-09 -9.7606 0.83509E+00 -0.0783 78 MnCl+ 0.94127E-14 -14.0263 0.78756E-14 -14.1037 0.83670E+00 -0.0774 79 MnSO4,aq 0.14320E-18 -18.8441 0.14320E-18 -18.8441 0.10000E+01 0.0000 80 NaCl,aq 0.72156E-06 -6.1417 0.72156E-06 -6.1417 0.10000E+01 0.0000 81 NaF,aq 0.13216E-08 -8.8789 0.13216E-08 -8.8789 0.10000E+01 0.0000 82 NaOH,aq 0.94946E-04 -4.0225 0.94946E-04 -4.0225 0.10000E+01 0.0000 84 OH- 0.92359E-02 -2.0345 0.76989E-02 -2.1136 0.83358E+00 -0.0791 89 HPO3-2 0.54170E-15 -15.2662 0.28057E-15 -15.5520 0.51795E+00 -0.2857 91 H2PO3- 0.50561E-19 -19.2962 0.42223E-19 -19.3744 0.83509E+00 -0.0783 92 H3PO4,aq 0.92681E-18 -18.0330 0.92681E-18 -18.0330 0.10000E+01 0.0000 93 H2PO4- 0.38970E-10 -10.4093 0.32574E-10 -10.4871 0.83589E+00 -0.0779 94 PO4-3 0.10554E-08 -8.9766 0.25581E-09 -9.5921 0.24240E+00 -0.6155 98 HP2O7-3 0.95831E-18 -18.0185 0.22137E-18 -18.6549 0.23100E+00 -0.6364 99 P2O7-4 0.91572E-17 -17.0382 0.70470E-18 -18.1520 0.76957E-01 -1.1138 100 H2S,aq 0.90430E-08 -8.0437 0.90116E-08 -8.0452 0.99653E+00 -0.0015 101 S2-2 0.16878E-13 -13.7727 0.87419E-14 -14.0584 0.51795E+00 -0.2857 107 SO3-2 0.48186E-16 -16.3171 0.25319E-16 -16.5965 0.52545E+00 -0.2795 108 HSO3- 0.14246E-18 -18.8463 0.11897E-18 -18.9246 0.83509E+00 -0.0783 109 HSO4- 0.43972E-17 -17.3568 0.36827E-17 -17.4338 0.83751E+00 -0.0770 111 S2O3-2 0.10407E-19 -19.9827 0.53903E-20 -20.2684 0.51795E+00 -0.2857 Charge balance for all species = -.6133E-08 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.8932392E-10 -.2221858E-01 -.2235603E+02 0.0000 2 H2O 0.1000000E+01 0.5550478E+02 0.9981953E+06 0.0000 3 Cl- 0.1572144E-03 0.1579363E-03 0.5589571E+01 6.2429 4 SO4-- 0.9810265E-10 -.1312466E-04 -.1258582E+01 9.9562 5 HCO3- 0.1955692E-04 0.6849274E-04 0.4171963E+01 5.3383 6 HS- 0.4651914E-04 0.5965295E-04 0.1969409E+01 5.7141 7 Al+++ 0.9837192E-29 0.5149425E-05 0.1386974E+00 0.7301 8 H4SiO4 0.7034474E-03 0.1353192E-01 0.1298363E+04 -3.1528 9 Ca++ 0.1178848E-06 0.2158392E-06 0.8635350E-02 13.0328 10 Mg++ 0.2115666E-10 0.9318166E-10 0.2261490E-05 9.2848 11 Fe++ 0.4500977E-13 0.2733353E-07 0.1523840E-02 6.6131 12 K+ 0.1565141E-03 0.1572595E-03 0.6138460E+01 6.2417 13 Na+ 0.1986242E-01 0.2230571E-01 0.5119115E+03 8.3444 14 Mn++ 0.1895699E-10 0.2507543E-08 0.1375197E-03 9.2380 15 F- 0.4084473E-06 0.4097694E-06 0.7771253E-02 3.6566 16 HPO4-- 0.4532563E-07 0.4641996E-07 0.4447589E-02 12.6210 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.1995440E-01 -.1995375E-01 -.6454382E-06 0.0000000E+00 2 H2O 0.4984696E+02 0.4984696E+02 -.6015285E-06 0.0000000E+00 3 Cl- 0.1418372E-03 0.1418372E-03 0.0000000E+00 0.0000000E+00 4 SO4-- -.1178581E-04 -.1178682E-04 0.1005619E-08 0.0000000E+00 5 HCO3- 0.6151100E-04 0.6151100E-04 0.0000000E+00 0.0000000E+00 6 HS- 0.5357128E-04 0.5357229E-04 -.1005619E-08 0.0000000E+00 7 Al+++ 0.4775352E-05 0.4624523E-05 0.1508287E-06 0.0000000E+00 8 H4SiO4 0.1215302E-01 0.1215256E-01 0.4623752E-06 0.0000000E+00 9 Ca++ 0.2080835E-06 0.1938378E-06 0.1424568E-07 0.0000000E+00 10 Mg++ 0.8368328E-10 0.8368328E-10 0.0000000E+00 0.0000000E+00 11 Fe++ 0.3259227E-07 0.2454732E-07 0.8044952E-08 0.0000000E+00 12 K+ 0.1412294E-03 0.1412294E-03 0.0000000E+00 0.0000000E+00 13 Na+ 0.2003215E-01 0.2003200E-01 0.1493765E-06 0.0000000E+00 14 Mn++ 0.2251939E-08 0.2251939E-08 0.0000000E+00 0.0000000E+00 15 F- 0.3680000E-06 0.3680000E-06 0.0000000E+00 0.0000000E+00 16 HPO4-- 0.4168819E-07 0.4168819E-07 0.0000000E+00 0.0000000E+00 Chg. balance for solid moles: -.7941E-22 Mass of aqueous solution: 0.899631E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 0.0006700 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 0.1494E-06 -6.826 0.3917E-04 -4.407 94.29 0.1504E-04 andradite 0.4022E-08 -8.396 0.2044E-05 -5.689 4.921 0.5311E-06 grossular 0.7261E-09 -9.139 0.3271E-06 -6.485 0.7873 0.9100E-07 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8471E+00 0.8471E+00 1.0000 -0.072 grossular 0.1529E+00 0.1529E+00 1.0000 -0.816 Solid products produced: Mass = 0.000042 g Volume = 0.000016 cm3 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.0006700 moles log = -3.1739 Original solution: 1000.0103000 g Original solution / Rock added: 1492552.69 (Water/Rock Ratio), log = 6.1739 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0433 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9783E+00 0.9856 0.1006E+01 0.1021E+01 CO2,gas 0.2671E-06 1.0069 0.2806E-06 0.2787E-06 CH4,gas 0.1690E-01 1.0124 0.1784E-01 0.1763E-01 H2,gas 0.4813E-02 1.0006 0.5024E-02 0.5021E-02 H2S,gas 0.2384E-06 0.9959 0.2477E-06 0.2487E-06 S2,gas 0.8749E-28 1.0000 0.9128E-28 0.9128E-28 CO,gas 0.3601E-12 1.0000 0.3757E-12 0.3757E-12 SO3,gas 0.1039E-45 1.0000 0.1084E-45 0.1084E-45 SO2,gas 0.2031E-25 1.0000 0.2119E-25 0.2119E-25 HF,gas 0.4116E-15 1.0000 0.4294E-15 0.4294E-15 HCl,gas 0.3054E-17 1.0000 0.3186E-17 0.3186E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 17 albite -0.38 -0.38 0.00 0.000 0.11184E-10 23 andradite 39.01 39.01 0.00 0.000 -0.24265E-10 24 grossular 32.73 32.73 0.00 0.000 -0.12132E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -14.91 -8.25 -2.750 0.14088E+05 -6.552 3 CH4,gas 4.54 1.10 -3.45 -0.862 0.58865E+04 -1.749 4 H2,gas 8.00 4.00 -4.00 -2.285 0.68264E+04 -2.299 5 H2S,gas -6.23 -14.54 -8.31 -4.153 0.14181E+05 -6.606 6 S2,gas -7.34 -37.07 -29.74 -4.575 0.50778E+05 -28.040 7 CO,gas 3.21 -10.91 -14.12 -4.346 0.24117E+05 -12.425 8 SO3,gas 17.12 -30.54 -47.66 -11.916 0.81385E+05 -45.965 9 SO2,gas 0.83 -26.54 -27.37 -7.299 0.46738E+05 -25.674 10 HF,gas 0.47 -16.59 -17.07 -8.533 0.29140E+05 -15.367 11 HCl,gas 5.19 -14.01 -19.20 -9.598 0.32776E+05 -17.497 12 acmite 7.71 6.65 -1.06 -0.110 0.18076E+04 16 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 20 spessartine 24.46 19.72 -4.74 -0.237 0.80961E+04 21 analcite 3.32 2.77 -0.55 -0.061 0.94416E+03 27 annite 20.12 17.35 -2.77 -0.154 0.47305E+04 28 phlogopite 27.06 25.37 -1.70 -0.094 0.28971E+04 30 anorthite 12.71 8.19 -4.52 -0.348 0.77227E+04 33 apatite-OH -18.15 -18.47 -0.32 -0.024 0.53896E+03 34 apatite-F -34.30 -35.06 -0.76 -0.063 0.12991E+04 38 aragonite 0.97 -1.88 -2.84 -0.948 0.48573E+04 39 brucite 12.57 9.28 -3.28 -0.657 0.56069E+04 40 calcite 0.81 -1.88 -2.69 -0.897 0.45930E+04 41 carnegieite-low 9.02 5.92 -3.10 -0.443 0.52959E+04 42 carnegieite-high 10.09 5.92 -4.17 -0.596 0.71229E+04 43 carpholite-Mg 8.58 4.44 -4.14 -0.276 0.70735E+04 44 carpholite-Fe 6.71 1.77 -4.94 -0.330 0.84433E+04 45 celadonite 5.34 3.65 -1.70 -0.100 0.28960E+04 46 celadonite-Fe 3.88 0.97 -2.90 -0.171 0.49562E+04 47 chrysotile 23.89 21.55 -2.34 -0.195 0.40015E+04 49 clinochlore 39.07 38.43 -0.64 -0.020 0.10990E+04 50 daphnite 28.97 25.07 -3.90 -0.122 0.66552E+04 52 chlorite-Al-free 47.17 43.10 -4.08 -0.170 0.69581E+04 54 chloritoid-Fe 9.17 4.92 -4.25 -0.284 0.72620E+04 55 chloritoid-Mn 11.40 7.55 -3.86 -0.257 0.65835E+04 57 coesite -2.38 -3.15 -0.78 -0.259 0.13262E+04 64 cristobalite -2.56 -3.15 -0.59 -0.197 0.10116E+04 66 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71234E+04 68 diaspore 2.87 0.73 -2.14 -0.357 0.36602E+04 69 diamond -3.10 -6.91 -3.81 -1.087 0.64969E+04 70 diopside 16.18 16.01 -0.17 -0.017 0.28903E+03 71 hedenbergite 14.21 13.34 -0.87 -0.087 0.14818E+04 76 clinoenstatite 17.17 12.26 -4.90 -0.490 0.83704E+04 78 epidote 24.67 22.68 -1.99 -0.096 0.33982E+04 79 clinozoisite 22.81 18.80 -4.01 -0.182 0.68444E+04 80 epidote-Fe 29.84 26.56 -3.28 -0.170 0.55987E+04 81 fayalite 14.05 10.07 -3.97 -0.567 0.67824E+04 82 ferrosilite 11.15 6.92 -4.23 -0.423 0.72204E+04 86 gibbsite 4.08 0.73 -3.35 -0.478 0.57187E+04 87 glaucophane 22.97 20.78 -2.19 -0.059 0.37456E+04 88 glaucophane-Fe 17.28 12.77 -4.51 -0.122 0.77001E+04 89 graphite -3.55 -6.91 -3.36 -0.960 0.57392E+04 90 greenalite 16.14 13.53 -2.61 -0.217 0.44490E+04 93 hematite 12.57 9.22 -3.34 -0.405 0.57059E+04 94 heulandite -5.83 -7.58 -1.75 -0.080 0.29867E+04 98 jadeite 4.22 2.77 -1.45 -0.145 0.24697E+04 100 kalsilite 7.58 3.82 -3.76 -0.538 0.64285E+04 101 kaolinite -1.33 -4.85 -3.51 -0.319 0.59977E+04 104 laumontite 2.88 1.88 -1.00 -0.067 0.17101E+04 105 lawsonite 9.62 8.19 -1.43 -0.095 0.24394E+04 106 leucite 4.12 0.67 -3.45 -0.345 0.58953E+04 108 lizardite 23.24 21.55 -1.69 -0.141 0.28941E+04 110 magnetite 20.09 15.84 -4.25 -0.347 0.72564E+04 111 minnesotaite 10.39 7.23 -3.16 -0.186 0.53952E+04 115 manganosite 14.06 9.24 -4.82 -1.205 0.82303E+04 119 microcline -2.49 -2.49 0.00 0.000 0.56601E-01 123 muscovite 2.58 -1.03 -3.61 -0.212 0.61619E+04 124 paragonite 4.24 1.08 -3.16 -0.186 0.54010E+04 125 nepheline 8.34 5.92 -2.42 -0.345 0.41283E+04 137 phlogopite-Na 29.65 27.47 -2.18 -0.121 0.37158E+04 139 prehnite 19.37 18.07 -1.30 -0.077 0.22272E+04 140 prehnite-Fe 22.50 21.95 -0.55 -0.033 0.93609E+03 141 pumpellyite-Fe 46.27 43.48 -2.79 -0.062 0.47660E+04 142 pumpellyite-Mg 48.99 46.15 -2.85 -0.063 0.48579E+04 146 pyrrhotite -4.26 -7.92 -3.66 -1.221 0.62524E+04 147 pyrrhotiteFe0.875 -6.02 -9.24 -3.23 -1.187 0.55118E+04 148 pyroxmangite 7.40 6.09 -1.31 -0.263 0.22427E+04 149 pyrophyllite -6.18 -11.15 -4.98 -0.311 0.84949E+04 150 quartz -2.99 -3.15 -0.16 -0.054 0.27889E+03 154 rhodochrosite -0.98 -5.67 -4.70 -1.566 0.80195E+04 155 rhodonite 7.45 6.09 -1.36 -0.272 0.23230E+04 156 sanidine -1.28 -2.49 -1.21 -0.093 0.20678E+04 166 stilbite -7.52 -7.58 -0.05 -0.003 0.92826E+02 167 stilpnomelane-Fe 13.02 12.42 -0.59 -0.018 0.10115E+04 168 stilpnomelane-Mg 27.44 25.78 -1.66 -0.050 0.28319E+04 174 talc 16.49 15.24 -1.25 -0.073 0.21305E+04 177 tephroite 18.09 15.32 -2.76 -0.395 0.47171E+04 181 tridymite -2.63 -3.15 -0.53 -0.175 0.89886E+03 182 tremolite 47.87 47.27 -0.60 -0.016 0.10275E+04 183 ferroactinolite 38.45 33.91 -4.54 -0.123 0.77574E+04 184 troilite-low -4.41 -7.92 -3.51 -1.170 0.59952E+04 190 wairakite 3.95 1.88 -2.07 -0.122 0.35320E+04 191 walstromite 11.51 9.88 -1.63 -0.326 0.27818E+04 192 wollastonite 10.46 9.88 -0.58 -0.116 0.99222E+03 193 pseudo-wollastonite 11.00 9.88 -1.12 -0.224 0.19120E+04 194 zoisite 22.85 18.80 -4.05 -0.184 0.69184E+04 195 akaganeite 7.75 4.61 -3.14 -0.679 0.53655E+04 202 chalcedony -2.80 -3.15 -0.35 -0.117 0.59818E+03 204 montmorillonite-Ca -2.29 -6.18 -3.89 -0.240 0.66365E+04 205 montmorillonite-K -2.24 -6.27 -4.03 -0.247 0.68835E+04 206 montmorillonite-Mg -2.48 -6.80 -4.32 -0.267 0.73694E+04 207 montmorillonite-Na -2.04 -5.57 -3.54 -0.217 0.60383E+04 208 nontronite-Ca 3.21 0.05 -3.17 -0.206 0.54116E+04 209 nontronite-H 2.53 -2.11 -4.64 -0.311 0.79192E+04 210 nontronite-K 3.34 -0.05 -3.39 -0.217 0.57818E+04 211 nontronite-Mg 3.07 -0.57 -3.65 -0.237 0.62287E+04 212 nontronite-Na 3.52 0.65 -2.87 -0.184 0.49027E+04 228 tobermorite 9.82 7.70 -2.12 -0.578 0.36190E+04 234 alabandite -0.98 -5.30 -4.32 -1.440 0.73753E+04 237 boehmite 4.41 0.73 -3.68 -0.613 0.62771E+04 239 ferrous-oxide 9.81 6.61 -3.20 -0.800 0.54612E+04 245 silica-amorphous -2.09 -3.15 -1.06 -0.354 0.18124E+04 247 an20ab80 2.02 1.33 -0.69 -0.053 0.11737E+04 248 an25ab75 2.65 1.76 -0.89 -0.068 0.15141E+04 249 an30ab70 3.28 2.19 -1.09 -0.084 0.18641E+04 250 tr.625ac.25prg.125 45.16 44.87 -0.29 -0.008 0.49925E+03 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 0.0000200 MOLES Current total amount of reactant added: 0.0006700 MOLES New total amount of reactant added: 0.0006900 MOLES Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.5508E-08 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 6 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 0.0006900 Water: Moles liquid = 0.4985E+02 kg liquid = 0.8981E+00 Moles total = 0.4985E+02 kg total = 0.8980E+00 Activity = 1.0000 Stoichiometric ionic strength = .1137423E-01 Osmotic coef. = 0.9671 True ionic strength = .2005736E-01 Chg. balance for total moles = -.5508E-08 Max. difference allowed = 0.1420E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.89356E-10 -10.0489 0.75072E-10 -10.1245 0.84015E+00 -0.0756 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.15735E-03 -3.8031 0.13140E-03 -3.8814 0.83509E+00 -0.0783 4 SO4-- 0.10310E-09 -9.9867 0.53513E-10 -10.2715 0.51904E+00 -0.2848 5 HCO3- 0.20154E-04 -4.6956 0.16855E-04 -4.7733 0.83631E+00 -0.0776 6 HS- 0.47060E-04 -4.3273 0.39305E-04 -4.4055 0.83521E+00 -0.0782 7 Al+++ 0.98417E-29 -29.0069 0.22711E-29 -29.6438 0.23076E+00 -0.6368 8 H4SiO4 0.70368E-03 -3.1526 0.70368E-03 -3.1526 0.10000E+01 0.0000 9 Ca++ 0.11765E-06 -6.9294 0.60616E-07 -7.2174 0.51523E+00 -0.2880 10 Mg++ 0.21158E-10 -10.6745 0.10851E-10 -10.9645 0.51287E+00 -0.2900 11 Fe++ 0.45022E-13 -13.3466 0.23116E-13 -13.6361 0.51343E+00 -0.2895 12 K+ 0.15651E-03 -3.8054 0.13093E-03 -3.8830 0.83651E+00 -0.0775 13 Na+ 0.19862E-01 -1.7020 0.16584E-01 -1.7803 0.83494E+00 -0.0783 14 Mn++ 0.18970E-10 -10.7219 0.97478E-11 -11.0111 0.51386E+00 -0.2892 15 F- 0.41733E-06 -6.3795 0.34779E-06 -6.4587 0.83337E+00 -0.0792 16 HPO4-- 0.45326E-07 -7.3437 0.23530E-07 -7.6284 0.51912E+00 -0.2847 18 HSiO3- 0.10481E-01 -1.9796 0.87523E-02 -2.0579 0.83509E+00 -0.0783 19 Ca(HSiO3)+ 0.14440E-07 -7.8404 0.12082E-07 -7.9179 0.83669E+00 -0.0774 20 Mg(HSiO3)+ 0.32171E-11 -11.4925 0.26917E-11 -11.5700 0.83669E+00 -0.0774 21 NaHSiO3,aq 0.23476E-02 -2.6294 0.23476E-02 -2.6294 0.10000E+01 0.0000 22 AlO+ 0.65522E-16 -16.1836 0.54822E-16 -16.2610 0.83669E+00 -0.0774 24 HAlO2,aq 0.14543E-09 -9.8374 0.14543E-09 -9.8374 0.10000E+01 0.0000 25 AlO2- 0.51442E-05 -5.2887 0.42881E-05 -5.3677 0.83358E+00 -0.0791 26 CH4,aq 0.12068E-04 -4.9184 0.12026E-04 -4.9199 0.99653E+00 -0.0015 27 C2H6,aq 0.65466E-14 -14.1840 0.65239E-14 -14.1855 0.99653E+00 -0.0015 31 CO,aq 0.25740E-15 -15.5894 0.25740E-15 -15.5894 0.10000E+01 0.0000 32 CO2,aq 0.27132E-08 -8.5665 0.27038E-08 -8.5680 0.99653E+00 -0.0015 33 CO3-2 0.37863E-04 -4.4218 0.19611E-04 -4.7075 0.51794E+00 -0.2857 34 CaCO3,aq 0.14905E-07 -7.8267 0.14905E-07 -7.8267 0.10000E+01 0.0000 35 Ca(HCO3)+ 0.31170E-10 -10.5063 0.26080E-10 -10.5837 0.83669E+00 -0.0774 36 CaCl+ 0.15405E-10 -10.8123 0.12889E-10 -10.8898 0.83669E+00 -0.0774 37 CaCl2,aq 0.40237E-15 -15.3954 0.40237E-15 -15.3954 0.10000E+01 0.0000 38 CaF+ 0.36786E-12 -12.4343 0.30779E-12 -12.5117 0.83669E+00 -0.0774 39 CaOH+ 0.68777E-07 -7.1626 0.57545E-07 -7.2400 0.83669E+00 -0.0774 40 CaSO4,aq 0.10300E-14 -14.9872 0.10300E-14 -14.9872 0.10000E+01 0.0000 41 HCl,aq 0.18076E-14 -14.7429 0.18076E-14 -14.7429 0.10000E+01 0.0000 45 HF,aq 0.17874E-12 -12.7478 0.17874E-12 -12.7478 0.10000E+01 0.0000 46 HF2- 0.25132E-19 -19.5998 0.20987E-19 -19.6780 0.83509E+00 -0.0783 48 FeCl+ 0.57460E-17 -17.2406 0.48076E-17 -17.3181 0.83669E+00 -0.0774 51 FeF+ 0.49101E-18 -18.3089 0.41083E-18 -18.3863 0.83669E+00 -0.0774 53 FeO,aq 0.15941E-09 -9.7975 0.15941E-09 -9.7975 0.10000E+01 0.0000 54 FeOH+ 0.11979E-10 -10.9216 0.10023E-10 -10.9990 0.83669E+00 -0.0774 55 HFeO2- 0.26605E-07 -7.5750 0.22218E-07 -7.6533 0.83509E+00 -0.0783 56 FeO+ 0.14677E-16 -16.8334 0.12280E-16 -16.9108 0.83669E+00 -0.0774 58 FeO2- 0.53391E-09 -9.2725 0.44587E-09 -9.3508 0.83509E+00 -0.0783 59 HFeO2,aq 0.42571E-11 -11.3709 0.42571E-11 -11.3709 0.10000E+01 0.0000 60 H2,aq 0.38029E-05 -5.4199 0.37898E-05 -5.4214 0.99653E+00 -0.0015 61 KCl,aq 0.31180E-09 -9.5061 0.31180E-09 -9.5061 0.10000E+01 0.0000 63 KOH,aq 0.74479E-06 -6.1280 0.74479E-06 -6.1280 0.10000E+01 0.0000 64 KSO4- 0.13019E-12 -12.8854 0.10872E-12 -12.9637 0.83509E+00 -0.0783 65 MgCO3,aq 0.66883E-12 -12.1747 0.66883E-12 -12.1747 0.10000E+01 0.0000 66 Mg(HCO3)+ 0.57017E-14 -14.2440 0.47705E-14 -14.3214 0.83669E+00 -0.0774 67 MgCl+ 0.24995E-14 -14.6021 0.20913E-14 -14.6796 0.83669E+00 -0.0774 68 MgF+ 0.24394E-15 -15.6127 0.20410E-15 -15.6901 0.83669E+00 -0.0774 69 MgOH+ 0.68129E-10 -10.1667 0.57003E-10 -10.2441 0.83669E+00 -0.0774 71 MnF+ 0.68248E-16 -16.1659 0.57103E-16 -16.2433 0.83669E+00 -0.0774 72 MnO,aq 0.17912E-08 -8.7469 0.17912E-08 -8.7469 0.10000E+01 0.0000 73 MnOH+ 0.46927E-09 -9.3286 0.39264E-09 -9.4060 0.83669E+00 -0.0774 74 MnO2-2 0.20364E-10 -10.6911 0.10548E-10 -10.9768 0.51794E+00 -0.2857 75 HMnO2- 0.20773E-09 -9.6825 0.17348E-09 -9.7608 0.83509E+00 -0.0783 78 MnCl+ 0.94268E-14 -14.0256 0.78873E-14 -14.1031 0.83669E+00 -0.0774 79 MnSO4,aq 0.15059E-18 -18.8222 0.15059E-18 -18.8222 0.10000E+01 0.0000 80 NaCl,aq 0.72216E-06 -6.1414 0.72216E-06 -6.1414 0.10000E+01 0.0000 81 NaF,aq 0.13503E-08 -8.8696 0.13503E-08 -8.8696 0.10000E+01 0.0000 82 NaOH,aq 0.94912E-04 -4.0227 0.94912E-04 -4.0227 0.10000E+01 0.0000 84 OH- 0.92327E-02 -2.0347 0.76962E-02 -2.1137 0.83358E+00 -0.0791 89 HPO3-2 0.53652E-15 -15.2704 0.27789E-15 -15.5561 0.51794E+00 -0.2857 91 H2PO3- 0.50095E-19 -19.3002 0.41834E-19 -19.3785 0.83509E+00 -0.0783 92 H3PO4,aq 0.92746E-18 -18.0327 0.92746E-18 -18.0327 0.10000E+01 0.0000 93 H2PO4- 0.38983E-10 -10.4091 0.32586E-10 -10.4870 0.83588E+00 -0.0779 94 PO4-3 0.10550E-08 -8.9767 0.25572E-09 -9.5922 0.24239E+00 -0.6155 98 HP2O7-3 0.95867E-18 -18.0183 0.22145E-18 -18.6547 0.23099E+00 -0.6364 99 P2O7-4 0.91576E-17 -17.0382 0.70469E-18 -18.1520 0.76952E-01 -1.1138 100 H2S,aq 0.91514E-08 -8.0385 0.91196E-08 -8.0400 0.99653E+00 -0.0015 101 S2-2 0.17440E-13 -13.7585 0.90328E-14 -14.0442 0.51794E+00 -0.2857 107 SO3-2 0.50155E-16 -16.2997 0.26354E-16 -16.5792 0.52544E+00 -0.2795 108 HSO3- 0.14834E-18 -18.8288 0.12387E-18 -18.9070 0.83509E+00 -0.0783 109 HSO4- 0.46227E-17 -17.3351 0.38716E-17 -17.4121 0.83751E+00 -0.0770 111 S2O3-2 0.11068E-19 -19.9559 0.57326E-20 -20.2416 0.51794E+00 -0.2857 Charge balance for all species = -.6133E-08 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.8935576E-10 -.2221615E-01 -.2235358E+02 0.0000 2 H2O 0.1000000E+01 0.5550478E+02 0.9981952E+06 0.0000 3 Cl- 0.1573451E-03 0.1580676E-03 0.5594219E+01 6.2431 4 SO4-- 0.1030986E-09 -.1301832E-04 -.1248385E+01 9.9775 5 HCO3- 0.2015418E-04 0.7010284E-04 0.4270035E+01 5.3513 6 HS- 0.4706017E-04 0.6008775E-04 0.1983764E+01 5.7190 7 Al+++ 0.9841685E-29 0.5144352E-05 0.1385608E+00 0.7298 8 H4SiO4 0.7036796E-03 0.1353190E-01 0.1298361E+04 -3.1526 9 Ca++ 0.1176482E-06 0.2158176E-06 0.8634487E-02 13.0316 10 Mg++ 0.2115784E-10 0.9318162E-10 0.2261489E-05 9.2845 11 Fe++ 0.4502232E-13 0.2731456E-07 0.1522782E-02 6.6130 12 K+ 0.1565143E-03 0.1572594E-03 0.6138458E+01 6.2415 13 Na+ 0.1986249E-01 0.2230570E-01 0.5119112E+03 8.3442 14 Mn++ 0.1896994E-10 0.2507542E-08 0.1375196E-03 9.2379 15 F- 0.4173264E-06 0.4186773E-06 0.7940190E-02 3.6658 16 HPO4-- 0.4532595E-07 0.4641994E-07 0.4447587E-02 12.6207 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.1995224E-01 -.1995158E-01 -.6637269E-06 0.0000000E+00 2 H2O 0.4984697E+02 0.4984697E+02 -.6197678E-06 0.0000000E+00 3 Cl- 0.1419552E-03 0.1419552E-03 0.0000000E+00 0.0000000E+00 4 SO4-- -.1169031E-04 -.1169132E-04 0.1007748E-08 0.0000000E+00 5 HCO3- 0.6295700E-04 0.6295700E-04 0.0000000E+00 0.0000000E+00 6 HS- 0.5396178E-04 0.5396279E-04 -.1007748E-08 0.0000000E+00 7 Al+++ 0.4775352E-05 0.4619970E-05 0.1553822E-06 0.0000000E+00 8 H4SiO4 0.1215302E-01 0.1215254E-01 0.4760675E-06 0.0000000E+00 9 Ca++ 0.2080835E-06 0.1938185E-06 0.1426496E-07 0.0000000E+00 10 Mg++ 0.8368328E-10 0.8368328E-10 0.0000000E+00 0.0000000E+00 11 Fe++ 0.3259227E-07 0.2453028E-07 0.8061986E-08 0.0000000E+00 12 K+ 0.1412294E-03 0.1412294E-03 0.0000000E+00 0.0000000E+00 13 Na+ 0.2003215E-01 0.2003200E-01 0.1539342E-06 0.0000000E+00 14 Mn++ 0.2251939E-08 0.2251939E-08 0.0000000E+00 0.0000000E+00 15 F- 0.3760000E-06 0.3760000E-06 0.0000000E+00 0.0000000E+00 16 HPO4-- 0.4168819E-07 0.4168819E-07 0.0000000E+00 0.0000000E+00 Chg. balance for solid moles: 0.2647E-22 Mass of aqueous solution: 0.899632E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 0.0006900 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 0.1539E-06 -6.813 0.4036E-04 -4.394 94.44 0.1550E-04 andradite 0.4031E-08 -8.395 0.2048E-05 -5.689 4.793 0.5322E-06 grossular 0.7240E-09 -9.140 0.3261E-06 -6.487 0.7631 0.9074E-07 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8477E+00 0.8477E+00 1.0000 -0.072 grossular 0.1523E+00 0.1523E+00 1.0000 -0.817 Solid products produced: Mass = 0.000043 g Volume = 0.000016 cm3 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.0006900 moles log = -3.1612 Original solution: 1000.0103000 g Original solution / Rock added: 1449290.29 (Water/Rock Ratio), log = 6.1612 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0431 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9785E+00 0.9856 0.1006E+01 0.1021E+01 CO2,gas 0.2754E-06 1.0069 0.2893E-06 0.2873E-06 CH4,gas 0.1676E-01 1.0124 0.1770E-01 0.1749E-01 H2,gas 0.4767E-02 1.0006 0.4976E-02 0.4973E-02 H2S,gas 0.2413E-06 0.9959 0.2507E-06 0.2517E-06 S2,gas 0.9136E-28 1.0000 0.9529E-28 0.9529E-28 CO,gas 0.3677E-12 1.0000 0.3836E-12 0.3836E-12 SO3,gas 0.1093E-45 1.0000 0.1140E-45 0.1140E-45 SO2,gas 0.2116E-25 1.0000 0.2207E-25 0.2207E-25 HF,gas 0.4207E-15 1.0000 0.4389E-15 0.4389E-15 HCl,gas 0.3058E-17 1.0000 0.3190E-17 0.3190E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 17 albite -0.38 -0.38 0.00 0.000 -0.94784E-12 23 andradite 39.01 39.01 0.00 0.000 0.24265E-10 24 grossular 32.73 32.73 0.00 0.000 -0.24265E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -14.90 -8.24 -2.746 0.14066E+05 -6.539 3 CH4,gas 4.54 1.09 -3.45 -0.863 0.58924E+04 -1.752 4 H2,gas 8.00 4.00 -4.00 -2.287 0.68335E+04 -2.303 5 H2S,gas -6.23 -14.53 -8.30 -4.150 0.14172E+05 -6.601 6 S2,gas -7.34 -37.06 -29.72 -4.572 0.50746E+05 -28.021 7 CO,gas 3.21 -10.90 -14.12 -4.343 0.24101E+05 -12.416 8 SO3,gas 17.12 -30.52 -47.64 -11.910 0.81347E+05 -45.943 9 SO2,gas 0.83 -26.52 -27.36 -7.295 0.46708E+05 -25.656 10 HF,gas 0.47 -16.58 -17.06 -8.528 0.29124E+05 -15.358 11 HCl,gas 5.19 -14.01 -19.20 -9.598 0.32775E+05 -17.496 12 acmite 7.71 6.65 -1.06 -0.110 0.18041E+04 16 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 20 spessartine 24.46 19.72 -4.74 -0.237 0.80964E+04 21 analcite 3.32 2.77 -0.55 -0.061 0.94441E+03 27 annite 20.12 17.35 -2.77 -0.154 0.47315E+04 28 phlogopite 27.06 25.37 -1.70 -0.094 0.28985E+04 30 anorthite 12.71 8.19 -4.52 -0.348 0.77252E+04 33 apatite-OH -18.15 -18.47 -0.32 -0.025 0.54753E+03 34 apatite-F -34.30 -35.06 -0.76 -0.063 0.12915E+04 38 aragonite 0.97 -1.87 -2.83 -0.944 0.48367E+04 39 brucite 12.57 9.28 -3.28 -0.657 0.56074E+04 40 calcite 0.81 -1.87 -2.68 -0.893 0.45725E+04 41 carnegieite-low 9.02 5.92 -3.10 -0.443 0.52964E+04 42 carnegieite-high 10.09 5.92 -4.17 -0.596 0.71234E+04 43 carpholite-Mg 8.58 4.44 -4.14 -0.276 0.70744E+04 44 carpholite-Fe 6.71 1.77 -4.95 -0.330 0.84440E+04 45 celadonite 5.34 3.65 -1.70 -0.100 0.28963E+04 46 celadonite-Fe 3.88 0.97 -2.90 -0.171 0.49563E+04 47 chrysotile 23.89 21.55 -2.34 -0.195 0.40025E+04 49 clinochlore 39.07 38.42 -0.65 -0.020 0.11017E+04 50 daphnite 28.97 25.07 -3.90 -0.122 0.66570E+04 52 chlorite-Al-free 47.17 43.10 -4.08 -0.170 0.69601E+04 54 chloritoid-Fe 9.17 4.92 -4.25 -0.284 0.72631E+04 55 chloritoid-Mn 11.40 7.54 -3.86 -0.257 0.65843E+04 57 coesite -2.38 -3.15 -0.78 -0.259 0.13260E+04 64 cristobalite -2.56 -3.15 -0.59 -0.197 0.10113E+04 66 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71234E+04 68 diaspore 2.87 0.73 -2.14 -0.357 0.36606E+04 69 diamond -3.10 -6.90 -3.80 -1.086 0.64886E+04 70 diopside 16.18 16.01 -0.17 -0.017 0.29106E+03 71 hedenbergite 14.21 13.34 -0.87 -0.087 0.14837E+04 76 clinoenstatite 17.17 12.26 -4.90 -0.490 0.83709E+04 78 epidote 24.67 22.68 -1.99 -0.097 0.33992E+04 79 clinozoisite 22.81 18.79 -4.01 -0.182 0.68491E+04 80 epidote-Fe 29.84 26.56 -3.28 -0.170 0.55960E+04 81 fayalite 14.05 10.07 -3.97 -0.567 0.67829E+04 82 ferrosilite 11.15 6.92 -4.23 -0.423 0.72206E+04 86 gibbsite 4.08 0.73 -3.35 -0.479 0.57192E+04 87 glaucophane 22.97 20.78 -2.19 -0.059 0.37466E+04 88 glaucophane-Fe 17.28 12.77 -4.51 -0.122 0.77006E+04 89 graphite -3.55 -6.90 -3.36 -0.959 0.57309E+04 90 greenalite 16.14 13.53 -2.61 -0.217 0.44495E+04 93 hematite 12.57 9.23 -3.34 -0.405 0.56994E+04 94 heulandite -5.83 -7.58 -1.75 -0.080 0.29879E+04 98 jadeite 4.22 2.77 -1.45 -0.145 0.24699E+04 100 kalsilite 7.58 3.82 -3.77 -0.538 0.64290E+04 101 kaolinite -1.33 -4.85 -3.51 -0.319 0.59982E+04 104 laumontite 2.88 1.88 -1.00 -0.067 0.17121E+04 105 lawsonite 9.62 8.19 -1.43 -0.095 0.24419E+04 106 leucite 4.12 0.67 -3.45 -0.345 0.58955E+04 108 lizardite 23.24 21.55 -1.70 -0.141 0.28951E+04 110 magnetite 20.09 15.84 -4.25 -0.347 0.72502E+04 111 minnesotaite 10.39 7.23 -3.16 -0.186 0.53952E+04 115 manganosite 14.06 9.24 -4.82 -1.205 0.82303E+04 119 microcline -2.49 -2.49 0.00 0.000 0.58307E-01 123 muscovite 2.58 -1.03 -3.61 -0.212 0.61629E+04 124 paragonite 4.24 1.08 -3.16 -0.186 0.54019E+04 125 nepheline 8.34 5.92 -2.42 -0.345 0.41288E+04 137 phlogopite-Na 29.65 27.47 -2.18 -0.121 0.37173E+04 139 prehnite 19.37 18.06 -1.31 -0.077 0.22315E+04 140 prehnite-Fe 22.50 21.95 -0.55 -0.033 0.93664E+03 141 pumpellyite-Fe 46.27 43.47 -2.80 -0.062 0.47753E+04 142 pumpellyite-Mg 48.99 46.14 -2.85 -0.063 0.48673E+04 146 pyrrhotite -4.26 -7.92 -3.66 -1.219 0.62439E+04 147 pyrrhotiteFe0.875 -6.02 -9.24 -3.22 -1.185 0.55023E+04 148 pyroxmangite 7.40 6.09 -1.31 -0.263 0.22425E+04 149 pyrophyllite -6.18 -11.15 -4.98 -0.311 0.84949E+04 150 quartz -2.99 -3.15 -0.16 -0.054 0.27864E+03 154 rhodochrosite -0.98 -5.66 -4.68 -1.561 0.79970E+04 155 rhodonite 7.45 6.09 -1.36 -0.272 0.23228E+04 156 sanidine -1.28 -2.49 -1.21 -0.093 0.20678E+04 166 stilbite -7.52 -7.58 -0.06 -0.003 0.94082E+02 167 stilpnomelane-Fe 13.02 12.42 -0.59 -0.018 0.10123E+04 168 stilpnomelane-Mg 27.44 25.78 -1.66 -0.050 0.28335E+04 174 talc 16.49 15.24 -1.25 -0.073 0.21310E+04 177 tephroite 18.09 15.32 -2.76 -0.395 0.47169E+04 181 tridymite -2.63 -3.15 -0.53 -0.175 0.89862E+03 182 tremolite 47.87 47.26 -0.60 -0.016 0.10320E+04 183 ferroactinolite 38.45 33.91 -4.55 -0.123 0.77611E+04 184 troilite-low -4.41 -7.92 -3.51 -1.169 0.59867E+04 190 wairakite 3.95 1.88 -2.07 -0.122 0.35340E+04 191 walstromite 11.51 9.88 -1.63 -0.326 0.27836E+04 192 wollastonite 10.46 9.88 -0.58 -0.116 0.99400E+03 193 pseudo-wollastonite 11.00 9.88 -1.12 -0.224 0.19138E+04 194 zoisite 22.85 18.79 -4.05 -0.184 0.69232E+04 195 akaganeite 7.75 4.61 -3.14 -0.679 0.53622E+04 202 chalcedony -2.80 -3.15 -0.35 -0.117 0.59794E+03 204 montmorillonite-Ca -2.29 -6.18 -3.89 -0.240 0.66368E+04 205 montmorillonite-K -2.24 -6.27 -4.03 -0.247 0.68835E+04 206 montmorillonite-Mg -2.48 -6.80 -4.32 -0.267 0.73695E+04 207 montmorillonite-Na -2.04 -5.57 -3.54 -0.217 0.60384E+04 208 nontronite-Ca 3.21 0.05 -3.17 -0.205 0.54047E+04 209 nontronite-H 2.53 -2.10 -4.63 -0.311 0.79120E+04 210 nontronite-K 3.34 -0.04 -3.38 -0.217 0.57747E+04 211 nontronite-Mg 3.07 -0.57 -3.64 -0.236 0.62215E+04 212 nontronite-Na 3.52 0.65 -2.87 -0.184 0.48956E+04 228 tobermorite 9.82 7.70 -2.12 -0.579 0.36204E+04 234 alabandite -0.98 -5.29 -4.31 -1.438 0.73665E+04 237 boehmite 4.41 0.73 -3.68 -0.613 0.62776E+04 239 ferrous-oxide 9.81 6.61 -3.20 -0.800 0.54616E+04 245 silica-amorphous -2.09 -3.15 -1.06 -0.354 0.18121E+04 247 an20ab80 2.02 1.33 -0.69 -0.053 0.11742E+04 248 an25ab75 2.65 1.76 -0.89 -0.068 0.15147E+04 249 an30ab70 3.28 2.19 -1.09 -0.084 0.18648E+04 250 tr.625ac.25prg.125 45.16 44.87 -0.30 -0.008 0.50382E+03 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 0.0000200 MOLES Current total amount of reactant added: 0.0006900 MOLES New total amount of reactant added: 0.0007100 MOLES Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.5508E-08 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 6 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 0.0007100 Water: Moles liquid = 0.4985E+02 kg liquid = 0.8981E+00 Moles total = 0.4985E+02 kg total = 0.8980E+00 Activity = 1.0000 Stoichiometric ionic strength = .1137550E-01 Osmotic coef. = 0.9671 True ionic strength = .2005854E-01 Chg. balance for total moles = -.5508E-08 Max. difference allowed = 0.1421E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.89388E-10 -10.0487 0.75099E-10 -10.1244 0.84015E+00 -0.0756 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.15748E-03 -3.8028 0.13151E-03 -3.8811 0.83509E+00 -0.0783 4 SO4-- 0.10825E-09 -9.9656 0.56186E-10 -10.2504 0.51904E+00 -0.2848 5 HCO3- 0.20752E-04 -4.6829 0.17355E-04 -4.7606 0.83631E+00 -0.0776 6 HS- 0.47601E-04 -4.3224 0.39757E-04 -4.4006 0.83521E+00 -0.0782 7 Al+++ 0.98462E-29 -29.0067 0.22721E-29 -29.6436 0.23076E+00 -0.6368 8 H4SiO4 0.70391E-03 -3.1525 0.70391E-03 -3.1525 0.10000E+01 0.0000 9 Ca++ 0.11741E-06 -6.9303 0.60494E-07 -7.2183 0.51522E+00 -0.2880 10 Mg++ 0.21159E-10 -10.6745 0.10852E-10 -10.9645 0.51286E+00 -0.2900 11 Fe++ 0.45038E-13 -13.3464 0.23123E-13 -13.6359 0.51342E+00 -0.2895 12 K+ 0.15651E-03 -3.8054 0.13093E-03 -3.8830 0.83651E+00 -0.0775 13 Na+ 0.19863E-01 -1.7020 0.16584E-01 -1.7803 0.83494E+00 -0.0783 14 Mn++ 0.18983E-10 -10.7216 0.97543E-11 -11.0108 0.51385E+00 -0.2892 15 F- 0.42621E-06 -6.3704 0.35518E-06 -6.4495 0.83336E+00 -0.0792 16 HPO4-- 0.45326E-07 -7.3437 0.23529E-07 -7.6284 0.51911E+00 -0.2847 18 HSiO3- 0.10480E-01 -1.9796 0.87521E-02 -2.0579 0.83509E+00 -0.0783 19 Ca(HSiO3)+ 0.14411E-07 -7.8413 0.12058E-07 -7.9187 0.83669E+00 -0.0774 20 Mg(HSiO3)+ 0.32172E-11 -11.4925 0.26918E-11 -11.5700 0.83669E+00 -0.0774 21 NaHSiO3,aq 0.23475E-02 -2.6294 0.23475E-02 -2.6294 0.10000E+01 0.0000 22 AlO+ 0.65504E-16 -16.1837 0.54806E-16 -16.2612 0.83669E+00 -0.0774 24 HAlO2,aq 0.14534E-09 -9.8376 0.14534E-09 -9.8376 0.10000E+01 0.0000 25 AlO2- 0.51391E-05 -5.2891 0.42839E-05 -5.3682 0.83358E+00 -0.0791 26 CH4,aq 0.11970E-04 -4.9219 0.11929E-04 -4.9234 0.99653E+00 -0.0015 27 C2H6,aq 0.65023E-14 -14.1869 0.64797E-14 -14.1884 0.99653E+00 -0.0015 31 CO,aq 0.26264E-15 -15.5806 0.26264E-15 -15.5806 0.10000E+01 0.0000 32 CO2,aq 0.27946E-08 -8.5537 0.27849E-08 -8.5552 0.99653E+00 -0.0015 33 CO3-2 0.38973E-04 -4.4092 0.20185E-04 -4.6950 0.51793E+00 -0.2857 34 CaCO3,aq 0.15311E-07 -7.8150 0.15311E-07 -7.8150 0.10000E+01 0.0000 35 Ca(HCO3)+ 0.32030E-10 -10.4944 0.26799E-10 -10.5719 0.83669E+00 -0.0774 36 CaCl+ 0.15387E-10 -10.8128 0.12874E-10 -10.8903 0.83669E+00 -0.0774 37 CaCl2,aq 0.40223E-15 -15.3955 0.40223E-15 -15.3955 0.10000E+01 0.0000 38 CaF+ 0.37494E-12 -12.4260 0.31371E-12 -12.5035 0.83669E+00 -0.0774 39 CaOH+ 0.68615E-07 -7.1636 0.57409E-07 -7.2410 0.83669E+00 -0.0774 40 CaSO4,aq 0.10793E-14 -14.9669 0.10793E-14 -14.9669 0.10000E+01 0.0000 41 HCl,aq 0.18097E-14 -14.7424 0.18097E-14 -14.7424 0.10000E+01 0.0000 45 HF,aq 0.18260E-12 -12.7385 0.18260E-12 -12.7385 0.10000E+01 0.0000 46 HF2- 0.26222E-19 -19.5813 0.21897E-19 -19.6596 0.83509E+00 -0.0783 48 FeCl+ 0.57526E-17 -17.2401 0.48132E-17 -17.3176 0.83669E+00 -0.0774 51 FeF+ 0.50162E-18 -18.2996 0.41970E-18 -18.3771 0.83669E+00 -0.0774 53 FeO,aq 0.15935E-09 -9.7977 0.15935E-09 -9.7977 0.10000E+01 0.0000 54 FeOH+ 0.11979E-10 -10.9216 0.10023E-10 -10.9990 0.83669E+00 -0.0774 55 HFeO2- 0.26586E-07 -7.5754 0.22201E-07 -7.6536 0.83509E+00 -0.0783 56 FeO+ 0.14746E-16 -16.8313 0.12338E-16 -16.9088 0.83669E+00 -0.0774 58 FeO2- 0.53604E-09 -9.2708 0.44764E-09 -9.3491 0.83509E+00 -0.0783 59 HFeO2,aq 0.42756E-11 -11.3690 0.42756E-11 -11.3690 0.10000E+01 0.0000 60 H2,aq 0.37673E-05 -5.4240 0.37542E-05 -5.4255 0.99653E+00 -0.0015 61 KCl,aq 0.31206E-09 -9.5058 0.31206E-09 -9.5058 0.10000E+01 0.0000 63 KOH,aq 0.74452E-06 -6.1281 0.74452E-06 -6.1281 0.10000E+01 0.0000 64 KSO4- 0.13669E-12 -12.8643 0.11415E-12 -12.9425 0.83509E+00 -0.0783 65 MgCO3,aq 0.68844E-12 -12.1621 0.68844E-12 -12.1621 0.10000E+01 0.0000 66 Mg(HCO3)+ 0.58710E-14 -14.2313 0.49122E-14 -14.3087 0.83669E+00 -0.0774 67 MgCl+ 0.25017E-14 -14.6018 0.20931E-14 -14.6792 0.83669E+00 -0.0774 68 MgF+ 0.24914E-15 -15.6036 0.20845E-15 -15.6810 0.83669E+00 -0.0774 69 MgOH+ 0.68108E-10 -10.1668 0.56986E-10 -10.2442 0.83669E+00 -0.0774 71 MnF+ 0.69747E-16 -16.1565 0.58356E-16 -16.2339 0.83669E+00 -0.0774 72 MnO,aq 0.17911E-08 -8.7469 0.17911E-08 -8.7469 0.10000E+01 0.0000 73 MnOH+ 0.46942E-09 -9.3284 0.39276E-09 -9.4059 0.83669E+00 -0.0774 74 MnO2-2 0.20350E-10 -10.6914 0.10540E-10 -10.9772 0.51793E+00 -0.2857 75 HMnO2- 0.20765E-09 -9.6827 0.17341E-09 -9.7609 0.83509E+00 -0.0783 78 MnCl+ 0.94409E-14 -14.0250 0.78991E-14 -14.1024 0.83669E+00 -0.0774 79 MnSO4,aq 0.15822E-18 -18.8007 0.15822E-18 -18.8007 0.10000E+01 0.0000 80 NaCl,aq 0.72275E-06 -6.1410 0.72275E-06 -6.1410 0.10000E+01 0.0000 81 NaF,aq 0.13790E-08 -8.8604 0.13790E-08 -8.8604 0.10000E+01 0.0000 82 NaOH,aq 0.94879E-04 -4.0228 0.94879E-04 -4.0228 0.10000E+01 0.0000 84 OH- 0.92295E-02 -2.0348 0.76935E-02 -2.1139 0.83358E+00 -0.0791 89 HPO3-2 0.53150E-15 -15.2745 0.27528E-15 -15.5602 0.51793E+00 -0.2857 91 H2PO3- 0.49643E-19 -19.3041 0.41456E-19 -19.3824 0.83509E+00 -0.0783 92 H3PO4,aq 0.92811E-18 -18.0324 0.92811E-18 -18.0324 0.10000E+01 0.0000 93 H2PO4- 0.38997E-10 -10.4090 0.32597E-10 -10.4868 0.83588E+00 -0.0779 94 PO4-3 0.10547E-08 -8.9769 0.25563E-09 -9.5924 0.24238E+00 -0.6155 98 HP2O7-3 0.95902E-18 -18.0182 0.22152E-18 -18.6546 0.23099E+00 -0.6364 99 P2O7-4 0.91580E-17 -17.0382 0.70468E-18 -18.1520 0.76947E-01 -1.1138 100 H2S,aq 0.92598E-08 -8.0334 0.92277E-08 -8.0349 0.99653E+00 -0.0015 101 S2-2 0.18012E-13 -13.7444 0.93291E-14 -14.0302 0.51793E+00 -0.2857 107 SO3-2 0.52168E-16 -16.2826 0.27411E-16 -16.5621 0.52544E+00 -0.2795 108 HSO3- 0.15434E-18 -18.8115 0.12889E-18 -18.8898 0.83509E+00 -0.0783 109 HSO4- 0.48554E-17 -17.3138 0.40664E-17 -17.3908 0.83751E+00 -0.0770 111 S2O3-2 0.11759E-19 -19.9296 0.60904E-20 -20.2154 0.51793E+00 -0.2857 Charge balance for all species = -.6133E-08 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.8938762E-10 -.2221373E-01 -.2235114E+02 0.0000 2 H2O 0.1000000E+01 0.5550477E+02 0.9981951E+06 0.0000 3 Cl- 0.1574759E-03 0.1581989E-03 0.5598867E+01 6.2433 4 SO4-- 0.1082509E-09 -.1291198E-04 -.1238187E+01 9.9984 5 HCO3- 0.2075179E-04 0.7171293E-04 0.4368108E+01 5.3638 6 HS- 0.4760120E-04 0.6052255E-04 0.1998119E+01 5.7238 7 Al+++ 0.9846182E-29 0.5139283E-05 0.1384243E+00 0.7295 8 H4SiO4 0.7039118E-03 0.1353188E-01 0.1298359E+04 -3.1525 9 Ca++ 0.1174140E-06 0.2157989E-06 0.8633740E-02 13.0304 10 Mg++ 0.2115902E-10 0.9318158E-10 0.2261488E-05 9.2842 11 Fe++ 0.4503771E-13 0.2729726E-07 0.1521817E-02 6.6128 12 K+ 0.1565145E-03 0.1572594E-03 0.6138455E+01 6.2414 13 Na+ 0.1986257E-01 0.2230568E-01 0.5119108E+03 8.3441 14 Mn++ 0.1898291E-10 0.2507541E-08 0.1375195E-03 9.2379 15 F- 0.4262056E-06 0.4275852E-06 0.8109127E-02 3.6748 16 HPO4-- 0.4532626E-07 0.4641992E-07 0.4447585E-02 12.6203 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.1995009E-01 -.1994941E-01 -.6819961E-06 0.0000000E+00 2 H2O 0.4984699E+02 0.4984699E+02 -.6379955E-06 0.0000000E+00 3 Cl- 0.1420732E-03 0.1420732E-03 0.0000000E+00 0.0000000E+00 4 SO4-- -.1159481E-04 -.1159582E-04 0.1009689E-08 0.0000000E+00 5 HCO3- 0.6440300E-04 0.6440300E-04 0.0000000E+00 0.0000000E+00 6 HS- 0.5435228E-04 0.5435329E-04 -.1009689E-08 0.0000000E+00 7 Al+++ 0.4775352E-05 0.4615419E-05 0.1599328E-06 0.0000000E+00 8 H4SiO4 0.1215302E-01 0.1215253E-01 0.4897492E-06 0.0000000E+00 9 Ca++ 0.2080835E-06 0.1938019E-06 0.1428164E-07 0.0000000E+00 10 Mg++ 0.8368328E-10 0.8368328E-10 0.0000000E+00 0.0000000E+00 11 Fe++ 0.3259227E-07 0.2451476E-07 0.8077510E-08 0.0000000E+00 12 K+ 0.1412294E-03 0.1412294E-03 0.0000000E+00 0.0000000E+00 13 Na+ 0.2003215E-01 0.2003199E-01 0.1584892E-06 0.0000000E+00 14 Mn++ 0.2251939E-08 0.2251939E-08 0.0000000E+00 0.0000000E+00 15 F- 0.3840000E-06 0.3840000E-06 0.0000000E+00 0.0000000E+00 16 HPO4-- 0.4168819E-07 0.4168819E-07 0.0000000E+00 0.0000000E+00 Chg. balance for solid moles: -.1059E-21 Mass of aqueous solution: 0.899632E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 0.0007100 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 0.1585E-06 -6.800 0.4156E-04 -4.381 94.59 0.1595E-04 andradite 0.4039E-08 -8.394 0.2052E-05 -5.688 4.671 0.5332E-06 grossular 0.7218E-09 -9.142 0.3251E-06 -6.488 0.7400 0.9047E-07 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8484E+00 0.8484E+00 1.0000 -0.071 grossular 0.1516E+00 0.1516E+00 1.0000 -0.819 Solid products produced: Mass = 0.000044 g Volume = 0.000017 cm3 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.0007100 moles log = -3.1487 Original solution: 1000.0103000 g Original solution / Rock added: 1408465.21 (Water/Rock Ratio), log = 6.1487 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0429 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9786E+00 0.9856 0.1006E+01 0.1021E+01 CO2,gas 0.2838E-06 1.0069 0.2980E-06 0.2959E-06 CH4,gas 0.1663E-01 1.0124 0.1756E-01 0.1734E-01 H2,gas 0.4724E-02 1.0006 0.4929E-02 0.4926E-02 H2S,gas 0.2442E-06 0.9959 0.2537E-06 0.2547E-06 S2,gas 0.9533E-28 1.0000 0.9942E-28 0.9942E-28 CO,gas 0.3753E-12 1.0000 0.3914E-12 0.3914E-12 SO3,gas 0.1149E-45 1.0000 0.1198E-45 0.1198E-45 SO2,gas 0.2203E-25 1.0000 0.2298E-25 0.2298E-25 HF,gas 0.4299E-15 1.0000 0.4484E-15 0.4484E-15 HCl,gas 0.3062E-17 1.0000 0.3193E-17 0.3193E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 17 albite -0.38 -0.38 0.00 0.000 -0.94784E-12 23 andradite 39.01 39.01 0.00 0.000 -0.12132E-10 24 grossular 32.73 32.73 0.00 0.000 -0.48529E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -14.88 -8.22 -2.742 0.14044E+05 -6.526 3 CH4,gas 4.54 1.09 -3.45 -0.864 0.58984E+04 -1.756 4 H2,gas 8.00 3.99 -4.01 -2.289 0.68405E+04 -2.307 5 H2S,gas -6.23 -14.52 -8.29 -4.147 0.14163E+05 -6.596 6 S2,gas -7.34 -37.04 -29.70 -4.569 0.50715E+05 -28.003 7 CO,gas 3.21 -10.89 -14.11 -4.340 0.24086E+05 -12.407 8 SO3,gas 17.12 -30.50 -47.62 -11.905 0.81311E+05 -45.921 9 SO2,gas 0.83 -26.51 -27.34 -7.290 0.46678E+05 -25.639 10 HF,gas 0.47 -16.57 -17.05 -8.524 0.29108E+05 -15.348 11 HCl,gas 5.19 -14.01 -19.19 -9.597 0.32774E+05 -17.496 12 acmite 7.71 6.66 -1.05 -0.110 0.18007E+04 16 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 20 spessartine 24.46 19.72 -4.74 -0.237 0.80967E+04 21 analcite 3.32 2.77 -0.55 -0.061 0.94465E+03 27 annite 20.12 17.35 -2.77 -0.154 0.47324E+04 28 phlogopite 27.06 25.37 -1.70 -0.094 0.29000E+04 30 anorthite 12.71 8.18 -4.53 -0.348 0.77277E+04 33 apatite-OH -18.15 -18.48 -0.33 -0.025 0.55604E+03 34 apatite-F -34.30 -35.05 -0.75 -0.063 0.12841E+04 38 aragonite 0.97 -1.85 -2.82 -0.940 0.48168E+04 39 brucite 12.57 9.28 -3.28 -0.657 0.56079E+04 40 calcite 0.81 -1.85 -2.67 -0.889 0.45526E+04 41 carnegieite-low 9.02 5.92 -3.10 -0.443 0.52969E+04 42 carnegieite-high 10.09 5.92 -4.17 -0.596 0.71239E+04 43 carpholite-Mg 8.58 4.44 -4.14 -0.276 0.70754E+04 44 carpholite-Fe 6.71 1.77 -4.95 -0.330 0.84448E+04 45 celadonite 5.34 3.65 -1.70 -0.100 0.28965E+04 46 celadonite-Fe 3.88 0.97 -2.90 -0.171 0.49564E+04 47 chrysotile 23.89 21.55 -2.34 -0.195 0.40035E+04 49 clinochlore 39.07 38.42 -0.65 -0.020 0.11043E+04 50 daphnite 28.97 25.07 -3.90 -0.122 0.66587E+04 52 chlorite-Al-free 47.17 43.10 -4.08 -0.170 0.69621E+04 54 chloritoid-Fe 9.17 4.92 -4.25 -0.284 0.72641E+04 55 chloritoid-Mn 11.40 7.54 -3.86 -0.257 0.65850E+04 57 coesite -2.38 -3.15 -0.78 -0.259 0.13257E+04 64 cristobalite -2.56 -3.15 -0.59 -0.197 0.10111E+04 66 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71234E+04 68 diaspore 2.87 0.73 -2.14 -0.357 0.36611E+04 69 diamond -3.10 -6.90 -3.80 -1.084 0.64807E+04 70 diopside 16.18 16.01 -0.17 -0.017 0.29308E+03 71 hedenbergite 14.21 13.34 -0.87 -0.087 0.14855E+04 76 clinoenstatite 17.17 12.26 -4.90 -0.490 0.83714E+04 78 epidote 24.67 22.68 -1.99 -0.097 0.34003E+04 79 clinozoisite 22.81 18.79 -4.01 -0.182 0.68538E+04 80 epidote-Fe 29.84 26.57 -3.28 -0.170 0.55933E+04 81 fayalite 14.05 10.07 -3.97 -0.568 0.67832E+04 82 ferrosilite 11.15 6.92 -4.23 -0.423 0.72206E+04 86 gibbsite 4.08 0.73 -3.35 -0.479 0.57197E+04 87 glaucophane 22.97 20.78 -2.19 -0.059 0.37476E+04 88 glaucophane-Fe 17.28 12.77 -4.51 -0.122 0.77010E+04 89 graphite -3.55 -6.90 -3.35 -0.958 0.57229E+04 90 greenalite 16.14 13.53 -2.61 -0.217 0.44499E+04 93 hematite 12.57 9.23 -3.33 -0.404 0.56930E+04 94 heulandite -5.83 -7.58 -1.75 -0.080 0.29892E+04 98 jadeite 4.22 2.77 -1.45 -0.145 0.24701E+04 100 kalsilite 7.58 3.82 -3.77 -0.538 0.64294E+04 101 kaolinite -1.33 -4.85 -3.51 -0.319 0.59986E+04 104 laumontite 2.88 1.88 -1.00 -0.067 0.17140E+04 105 lawsonite 9.62 8.18 -1.43 -0.095 0.24443E+04 106 leucite 4.12 0.67 -3.45 -0.345 0.58957E+04 108 lizardite 23.24 21.55 -1.70 -0.141 0.28961E+04 110 magnetite 20.09 15.84 -4.24 -0.346 0.72441E+04 111 minnesotaite 10.39 7.23 -3.16 -0.186 0.53951E+04 115 manganosite 14.06 9.24 -4.82 -1.205 0.82303E+04 119 microcline -2.49 -2.49 0.00 0.000 0.60014E-01 123 muscovite 2.58 -1.03 -3.61 -0.212 0.61638E+04 124 paragonite 4.24 1.08 -3.16 -0.186 0.54029E+04 125 nepheline 8.34 5.92 -2.42 -0.345 0.41293E+04 137 phlogopite-Na 29.65 27.47 -2.18 -0.121 0.37188E+04 139 prehnite 19.37 18.06 -1.31 -0.077 0.22357E+04 140 prehnite-Fe 22.50 21.95 -0.55 -0.033 0.93719E+03 141 pumpellyite-Fe 46.27 43.47 -2.80 -0.062 0.47846E+04 142 pumpellyite-Mg 48.99 46.14 -2.86 -0.063 0.48768E+04 146 pyrrhotite -4.26 -7.91 -3.65 -1.217 0.62354E+04 147 pyrrhotiteFe0.875 -6.02 -9.23 -3.22 -1.183 0.54930E+04 148 pyroxmangite 7.40 6.09 -1.31 -0.263 0.22423E+04 149 pyrophyllite -6.18 -11.15 -4.98 -0.311 0.84948E+04 150 quartz -2.99 -3.15 -0.16 -0.054 0.27840E+03 154 rhodochrosite -0.98 -5.65 -4.67 -1.557 0.79751E+04 155 rhodonite 7.45 6.09 -1.36 -0.272 0.23226E+04 156 sanidine -1.28 -2.49 -1.21 -0.093 0.20678E+04 166 stilbite -7.52 -7.58 -0.06 -0.003 0.95326E+02 167 stilpnomelane-Fe 13.02 12.42 -0.59 -0.018 0.10128E+04 168 stilpnomelane-Mg 27.44 25.78 -1.66 -0.050 0.28350E+04 174 talc 16.49 15.24 -1.25 -0.073 0.21315E+04 177 tephroite 18.09 15.32 -2.76 -0.395 0.47167E+04 181 tridymite -2.63 -3.15 -0.53 -0.175 0.89837E+03 182 tremolite 47.87 47.26 -0.61 -0.016 0.10366E+04 183 ferroactinolite 38.45 33.90 -4.55 -0.123 0.77646E+04 184 troilite-low -4.41 -7.91 -3.50 -1.167 0.59782E+04 190 wairakite 3.95 1.88 -2.07 -0.122 0.35360E+04 191 walstromite 11.51 9.88 -1.63 -0.326 0.27853E+04 192 wollastonite 10.46 9.88 -0.58 -0.117 0.99577E+03 193 pseudo-wollastonite 11.00 9.88 -1.12 -0.224 0.19156E+04 194 zoisite 22.85 18.79 -4.06 -0.184 0.69279E+04 195 akaganeite 7.75 4.62 -3.14 -0.679 0.53590E+04 202 chalcedony -2.80 -3.15 -0.35 -0.117 0.59770E+03 204 montmorillonite-Ca -2.29 -6.18 -3.89 -0.240 0.66371E+04 205 montmorillonite-K -2.24 -6.27 -4.03 -0.247 0.68836E+04 206 montmorillonite-Mg -2.48 -6.80 -4.32 -0.267 0.73695E+04 207 montmorillonite-Na -2.04 -5.57 -3.54 -0.217 0.60385E+04 208 nontronite-Ca 3.21 0.05 -3.16 -0.205 0.53979E+04 209 nontronite-H 2.53 -2.10 -4.63 -0.310 0.79048E+04 210 nontronite-K 3.34 -0.04 -3.38 -0.217 0.57676E+04 211 nontronite-Mg 3.07 -0.56 -3.64 -0.236 0.62144E+04 212 nontronite-Na 3.52 0.66 -2.86 -0.184 0.48885E+04 228 tobermorite 9.82 7.70 -2.12 -0.579 0.36218E+04 234 alabandite -0.98 -5.29 -4.31 -1.436 0.73578E+04 237 boehmite 4.41 0.73 -3.68 -0.613 0.62780E+04 239 ferrous-oxide 9.81 6.61 -3.20 -0.800 0.54619E+04 245 silica-amorphous -2.09 -3.15 -1.06 -0.354 0.18119E+04 247 an20ab80 2.02 1.33 -0.69 -0.053 0.11747E+04 248 an25ab75 2.65 1.76 -0.89 -0.068 0.15153E+04 249 an30ab70 3.28 2.19 -1.09 -0.084 0.18656E+04 250 tr.625ac.25prg.125 45.16 44.87 -0.30 -0.008 0.50830E+03 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 0.0000200 MOLES Current total amount of reactant added: 0.0007100 MOLES New total amount of reactant added: 0.0007300 MOLES Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.5508E-08 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 6 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 0.0007300 Water: Moles liquid = 0.4985E+02 kg liquid = 0.8981E+00 Moles total = 0.4985E+02 kg total = 0.8980E+00 Activity = 1.0000 Stoichiometric ionic strength = .1137678E-01 Osmotic coef. = 0.9670 True ionic strength = .2005972E-01 Chg. balance for total moles = -.5508E-08 Max. difference allowed = 0.1422E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.89419E-10 -10.0486 0.75125E-10 -10.1242 0.84014E+00 -0.0756 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.15761E-03 -3.8024 0.13161E-03 -3.8807 0.83508E+00 -0.0783 4 SO4-- 0.11356E-09 -9.9448 0.58943E-10 -10.2296 0.51903E+00 -0.2848 5 HCO3- 0.21350E-04 -4.6706 0.17855E-04 -4.7482 0.83631E+00 -0.0776 6 HS- 0.48142E-04 -4.3175 0.40209E-04 -4.3957 0.83521E+00 -0.0782 7 Al+++ 0.98507E-29 -29.0065 0.22730E-29 -29.6434 0.23075E+00 -0.6369 8 H4SiO4 0.70414E-03 -3.1523 0.70414E-03 -3.1523 0.10000E+01 0.0000 9 Ca++ 0.11718E-06 -6.9311 0.60374E-07 -7.2192 0.51521E+00 -0.2880 10 Mg++ 0.21160E-10 -10.6745 0.10852E-10 -10.9645 0.51285E+00 -0.2900 11 Fe++ 0.45056E-13 -13.3462 0.23132E-13 -13.6358 0.51341E+00 -0.2895 12 K+ 0.15651E-03 -3.8054 0.13093E-03 -3.8830 0.83651E+00 -0.0775 13 Na+ 0.19863E-01 -1.7020 0.16584E-01 -1.7803 0.83493E+00 -0.0783 14 Mn++ 0.18996E-10 -10.7213 0.97609E-11 -11.0105 0.51384E+00 -0.2892 15 F- 0.43508E-06 -6.3614 0.36258E-06 -6.4406 0.83336E+00 -0.0792 16 HPO4-- 0.45327E-07 -7.3436 0.23529E-07 -7.6284 0.51910E+00 -0.2847 18 HSiO3- 0.10480E-01 -1.9796 0.87519E-02 -2.0579 0.83508E+00 -0.0783 19 Ca(HSiO3)+ 0.14382E-07 -7.8422 0.12033E-07 -7.9196 0.83669E+00 -0.0774 20 Mg(HSiO3)+ 0.32173E-11 -11.4925 0.26918E-11 -11.5700 0.83669E+00 -0.0774 21 NaHSiO3,aq 0.23475E-02 -2.6294 0.23475E-02 -2.6294 0.10000E+01 0.0000 22 AlO+ 0.65485E-16 -16.1839 0.54791E-16 -16.2613 0.83669E+00 -0.0774 24 HAlO2,aq 0.14524E-09 -9.8379 0.14524E-09 -9.8379 0.10000E+01 0.0000 25 AlO2- 0.51341E-05 -5.2895 0.42796E-05 -5.3686 0.83357E+00 -0.0791 26 CH4,aq 0.11873E-04 -4.9255 0.11831E-04 -4.9270 0.99653E+00 -0.0015 27 C2H6,aq 0.64560E-14 -14.1900 0.64336E-14 -14.1915 0.99653E+00 -0.0015 31 CO,aq 0.26782E-15 -15.5722 0.26782E-15 -15.5722 0.10000E+01 0.0000 32 CO2,aq 0.28761E-08 -8.5412 0.28662E-08 -8.5427 0.99653E+00 -0.0015 33 CO3-2 0.40082E-04 -4.3971 0.20759E-04 -4.6828 0.51793E+00 -0.2857 34 CaCO3,aq 0.15715E-07 -7.8037 0.15715E-07 -7.8037 0.10000E+01 0.0000 35 Ca(HCO3)+ 0.32887E-10 -10.4830 0.27516E-10 -10.5604 0.83669E+00 -0.0774 36 CaCl+ 0.15369E-10 -10.8133 0.12859E-10 -10.8908 0.83669E+00 -0.0774 37 CaCl2,aq 0.40209E-15 -15.3957 0.40209E-15 -15.3957 0.10000E+01 0.0000 38 CaF+ 0.38199E-12 -12.4180 0.31960E-12 -12.4954 0.83669E+00 -0.0774 39 CaOH+ 0.68455E-07 -7.1646 0.57275E-07 -7.2420 0.83669E+00 -0.0774 40 CaSO4,aq 0.11300E-14 -14.9469 0.11300E-14 -14.9469 0.10000E+01 0.0000 41 HCl,aq 0.18119E-14 -14.7419 0.18119E-14 -14.7419 0.10000E+01 0.0000 45 HF,aq 0.18647E-12 -12.7294 0.18647E-12 -12.7294 0.10000E+01 0.0000 46 HF2- 0.27335E-19 -19.5633 0.22827E-19 -19.6415 0.83508E+00 -0.0783 48 FeCl+ 0.57596E-17 -17.2396 0.48190E-17 -17.3170 0.83669E+00 -0.0774 51 FeF+ 0.51227E-18 -18.2905 0.42861E-18 -18.3679 0.83669E+00 -0.0774 53 FeO,aq 0.15930E-09 -9.7978 0.15930E-09 -9.7978 0.10000E+01 0.0000 54 FeOH+ 0.11979E-10 -10.9216 0.10023E-10 -10.9990 0.83669E+00 -0.0774 55 HFeO2- 0.26568E-07 -7.5756 0.22186E-07 -7.6539 0.83508E+00 -0.0783 56 FeO+ 0.14815E-16 -16.8293 0.12396E-16 -16.9067 0.83669E+00 -0.0774 58 FeO2- 0.53816E-09 -9.2691 0.44941E-09 -9.3474 0.83508E+00 -0.0783 59 HFeO2,aq 0.42940E-11 -11.3671 0.42940E-11 -11.3671 0.10000E+01 0.0000 60 H2,aq 0.37327E-05 -5.4280 0.37197E-05 -5.4295 0.99653E+00 -0.0015 61 KCl,aq 0.31231E-09 -9.5054 0.31231E-09 -9.5054 0.10000E+01 0.0000 63 KOH,aq 0.74426E-06 -6.1283 0.74426E-06 -6.1283 0.10000E+01 0.0000 64 KSO4- 0.14340E-12 -12.8435 0.11975E-12 -12.9217 0.83508E+00 -0.0783 65 MgCO3,aq 0.70805E-12 -12.1499 0.70805E-12 -12.1499 0.10000E+01 0.0000 66 Mg(HCO3)+ 0.60404E-14 -14.2189 0.50539E-14 -14.2964 0.83669E+00 -0.0774 67 MgCl+ 0.25039E-14 -14.6014 0.20949E-14 -14.6788 0.83669E+00 -0.0774 68 MgF+ 0.25434E-15 -15.5946 0.21280E-15 -15.6720 0.83669E+00 -0.0774 69 MgOH+ 0.68087E-10 -10.1669 0.56968E-10 -10.2444 0.83669E+00 -0.0774 71 MnF+ 0.71247E-16 -16.1472 0.59612E-16 -16.2247 0.83669E+00 -0.0774 72 MnO,aq 0.17911E-08 -8.7469 0.17911E-08 -8.7469 0.10000E+01 0.0000 73 MnOH+ 0.46957E-09 -9.3283 0.39289E-09 -9.4057 0.83669E+00 -0.0774 74 MnO2-2 0.20335E-10 -10.6918 0.10532E-10 -10.9775 0.51793E+00 -0.2857 75 HMnO2- 0.20757E-09 -9.6828 0.17334E-09 -9.7611 0.83508E+00 -0.0783 78 MnCl+ 0.94551E-14 -14.0243 0.79109E-14 -14.1018 0.83669E+00 -0.0774 79 MnSO4,aq 0.16609E-18 -18.7796 0.16609E-18 -18.7796 0.10000E+01 0.0000 80 NaCl,aq 0.72335E-06 -6.1407 0.72335E-06 -6.1407 0.10000E+01 0.0000 81 NaF,aq 0.14078E-08 -8.8515 0.14078E-08 -8.8515 0.10000E+01 0.0000 82 NaOH,aq 0.94845E-04 -4.0230 0.94845E-04 -4.0230 0.10000E+01 0.0000 84 OH- 0.92263E-02 -2.0350 0.76908E-02 -2.1140 0.83357E+00 -0.0791 89 HPO3-2 0.52661E-15 -15.2785 0.27275E-15 -15.5642 0.51793E+00 -0.2857 91 H2PO3- 0.49203E-19 -19.3080 0.41089E-19 -19.3863 0.83508E+00 -0.0783 92 H3PO4,aq 0.92876E-18 -18.0321 0.92876E-18 -18.0321 0.10000E+01 0.0000 93 H2PO4- 0.39011E-10 -10.4088 0.32608E-10 -10.4867 0.83588E+00 -0.0779 94 PO4-3 0.10543E-08 -8.9770 0.25554E-09 -9.5925 0.24237E+00 -0.6155 98 HP2O7-3 0.95938E-18 -18.0180 0.22160E-18 -18.6544 0.23098E+00 -0.6364 99 P2O7-4 0.91584E-17 -17.0382 0.70467E-18 -18.1520 0.76943E-01 -1.1138 100 H2S,aq 0.93683E-08 -8.0283 0.93358E-08 -8.0298 0.99653E+00 -0.0015 101 S2-2 0.18595E-13 -13.7306 0.96308E-14 -14.0163 0.51793E+00 -0.2857 107 SO3-2 0.54225E-16 -16.2658 0.28491E-16 -16.5453 0.52543E+00 -0.2795 108 HSO3- 0.16048E-18 -18.7946 0.13402E-18 -18.8728 0.83508E+00 -0.0783 109 HSO4- 0.50954E-17 -17.2928 0.42674E-17 -17.3698 0.83750E+00 -0.0770 111 S2O3-2 0.12481E-19 -19.9038 0.64640E-20 -20.1895 0.51793E+00 -0.2857 Charge balance for all species = -.6133E-08 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.8941950E-10 -.2221130E-01 -.2234870E+02 0.0000 2 H2O 0.1000000E+01 0.5550477E+02 0.9981949E+06 0.0000 3 Cl- 0.1576066E-03 0.1583303E-03 0.5603514E+01 6.2435 4 SO4-- 0.1135636E-09 -.1280564E-04 -.1227989E+01 10.0189 5 HCO3- 0.2134976E-04 0.7332303E-04 0.4466180E+01 5.3760 6 HS- 0.4814223E-04 0.6095735E-04 0.2012473E+01 5.7285 7 Al+++ 0.9850682E-29 0.5134217E-05 0.1382878E+00 0.7292 8 H4SiO4 0.7041442E-03 0.1353186E-01 0.1298357E+04 -3.1523 9 Ca++ 0.1171823E-06 0.2157830E-06 0.8633099E-02 13.0293 10 Mg++ 0.2116020E-10 0.9318155E-10 0.2261487E-05 9.2839 11 Fe++ 0.4505574E-13 0.2728152E-07 0.1520940E-02 6.6126 12 K+ 0.1565147E-03 0.1572593E-03 0.6138452E+01 6.2412 13 Na+ 0.1986264E-01 0.2230567E-01 0.5119105E+03 8.3439 14 Mn++ 0.1899589E-10 0.2507540E-08 0.1375195E-03 9.2379 15 F- 0.4350847E-06 0.4364930E-06 0.8278063E-02 3.6836 16 HPO4-- 0.4532658E-07 0.4641991E-07 0.4447583E-02 12.6200 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.1994794E-01 -.1994724E-01 -.7002464E-06 0.0000000E+00 2 H2O 0.4984701E+02 0.4984701E+02 -.6562115E-06 0.0000000E+00 3 Cl- 0.1421912E-03 0.1421912E-03 0.0000000E+00 0.0000000E+00 4 SO4-- -.1149931E-04 -.1150032E-04 0.1011454E-08 0.0000000E+00 5 HCO3- 0.6584900E-04 0.6584900E-04 0.0000000E+00 0.0000000E+00 6 HS- 0.5474278E-04 0.5474379E-04 -.1011454E-08 0.0000000E+00 7 Al+++ 0.4775352E-05 0.4610872E-05 0.1644804E-06 0.0000000E+00 8 H4SiO4 0.1215302E-01 0.1215252E-01 0.5034202E-06 0.0000000E+00 9 Ca++ 0.2080835E-06 0.1937876E-06 0.1429593E-07 0.0000000E+00 10 Mg++ 0.8368328E-10 0.8368328E-10 0.0000000E+00 0.0000000E+00 11 Fe++ 0.3259227E-07 0.2450064E-07 0.8091631E-08 0.0000000E+00 12 K+ 0.1412294E-03 0.1412294E-03 0.0000000E+00 0.0000000E+00 13 Na+ 0.2003215E-01 0.2003199E-01 0.1630414E-06 0.0000000E+00 14 Mn++ 0.2251939E-08 0.2251939E-08 0.0000000E+00 0.0000000E+00 15 F- 0.3920000E-06 0.3920000E-06 0.0000000E+00 0.0000000E+00 16 HPO4-- 0.4168819E-07 0.4168819E-07 0.0000000E+00 0.0000000E+00 Chg. balance for solid moles: 0.5294E-22 Mass of aqueous solution: 0.899633E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 0.0007300 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 0.1630E-06 -6.788 0.4275E-04 -4.369 94.73 0.1641E-04 andradite 0.4046E-08 -8.393 0.2056E-05 -5.687 4.555 0.5342E-06 grossular 0.7195E-09 -9.143 0.3241E-06 -6.489 0.7181 0.9018E-07 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8490E+00 0.8490E+00 1.0000 -0.071 grossular 0.1510E+00 0.1510E+00 1.0000 -0.821 Solid products produced: Mass = 0.000045 g Volume = 0.000017 cm3 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.0007300 moles log = -3.1367 Original solution: 1000.0103000 g Original solution / Rock added: 1369877.12 (Water/Rock Ratio), log = 6.1367 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0427 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9788E+00 0.9856 0.1006E+01 0.1021E+01 CO2,gas 0.2921E-06 1.0069 0.3066E-06 0.3046E-06 CH4,gas 0.1650E-01 1.0124 0.1742E-01 0.1720E-01 H2,gas 0.4681E-02 1.0006 0.4884E-02 0.4881E-02 H2S,gas 0.2471E-06 0.9959 0.2566E-06 0.2577E-06 S2,gas 0.9942E-28 1.0000 0.1037E-27 0.1037E-27 CO,gas 0.3828E-12 1.0000 0.3991E-12 0.3991E-12 SO3,gas 0.1206E-45 1.0000 0.1258E-45 0.1258E-45 SO2,gas 0.2292E-25 1.0000 0.2390E-25 0.2390E-25 HF,gas 0.4391E-15 1.0000 0.4579E-15 0.4579E-15 HCl,gas 0.3066E-17 1.0000 0.3197E-17 0.3197E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 17 albite -0.38 -0.38 0.00 0.000 -0.13080E-10 23 andradite 39.01 39.01 0.00 0.000 -0.24265E-10 24 grossular 32.73 32.73 0.00 0.000 0.12132E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -14.87 -8.21 -2.737 0.14022E+05 -6.513 3 CH4,gas 4.54 1.09 -3.46 -0.865 0.59045E+04 -1.759 4 H2,gas 8.00 3.99 -4.01 -2.292 0.68474E+04 -2.311 5 H2S,gas -6.23 -14.52 -8.29 -4.145 0.14154E+05 -6.591 6 S2,gas -7.34 -37.02 -29.68 -4.567 0.50684E+05 -27.984 7 CO,gas 3.21 -10.88 -14.10 -4.338 0.24072E+05 -12.399 8 SO3,gas 17.12 -30.48 -47.60 -11.900 0.81275E+05 -45.900 9 SO2,gas 0.83 -26.49 -27.32 -7.285 0.46649E+05 -25.622 10 HF,gas 0.47 -16.56 -17.04 -8.519 0.29092E+05 -15.339 11 HCl,gas 5.19 -14.00 -19.19 -9.597 0.32774E+05 -17.495 12 acmite 7.71 6.66 -1.05 -0.109 0.17973E+04 16 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 20 spessartine 24.46 19.72 -4.74 -0.237 0.80970E+04 21 analcite 3.32 2.77 -0.55 -0.061 0.94490E+03 27 annite 20.12 17.35 -2.77 -0.154 0.47331E+04 28 phlogopite 27.06 25.37 -1.70 -0.094 0.29015E+04 30 anorthite 12.71 8.18 -4.53 -0.348 0.77301E+04 33 apatite-OH -18.15 -18.48 -0.33 -0.025 0.56449E+03 34 apatite-F -34.30 -35.05 -0.75 -0.062 0.12770E+04 38 aragonite 0.97 -1.84 -2.81 -0.937 0.47975E+04 39 brucite 12.57 9.28 -3.28 -0.657 0.56084E+04 40 calcite 0.81 -1.84 -2.65 -0.885 0.45333E+04 41 carnegieite-low 9.02 5.92 -3.10 -0.443 0.52974E+04 42 carnegieite-high 10.09 5.92 -4.17 -0.596 0.71244E+04 43 carpholite-Mg 8.58 4.44 -4.14 -0.276 0.70763E+04 44 carpholite-Fe 6.71 1.77 -4.95 -0.330 0.84455E+04 45 celadonite 5.34 3.65 -1.70 -0.100 0.28968E+04 46 celadonite-Fe 3.88 0.97 -2.90 -0.171 0.49564E+04 47 chrysotile 23.89 21.55 -2.35 -0.195 0.40045E+04 49 clinochlore 39.07 38.42 -0.65 -0.020 0.11070E+04 50 daphnite 28.97 25.06 -3.90 -0.122 0.66601E+04 52 chlorite-Al-free 47.17 43.09 -4.08 -0.170 0.69641E+04 54 chloritoid-Fe 9.17 4.92 -4.25 -0.284 0.72650E+04 55 chloritoid-Mn 11.40 7.54 -3.86 -0.257 0.65857E+04 57 coesite -2.38 -3.15 -0.78 -0.259 0.13255E+04 64 cristobalite -2.56 -3.15 -0.59 -0.197 0.10108E+04 66 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71234E+04 68 diaspore 2.87 0.73 -2.14 -0.357 0.36616E+04 69 diamond -3.10 -6.89 -3.79 -1.083 0.64731E+04 70 diopside 16.18 16.01 -0.17 -0.017 0.29508E+03 71 hedenbergite 14.21 13.34 -0.87 -0.087 0.14873E+04 76 clinoenstatite 17.17 12.26 -4.90 -0.490 0.83719E+04 78 epidote 24.67 22.68 -1.99 -0.097 0.34013E+04 79 clinozoisite 22.81 18.79 -4.02 -0.183 0.68585E+04 80 epidote-Fe 29.84 26.57 -3.27 -0.170 0.55907E+04 81 fayalite 14.05 10.07 -3.97 -0.568 0.67834E+04 82 ferrosilite 11.15 6.92 -4.23 -0.423 0.72206E+04 86 gibbsite 4.08 0.73 -3.35 -0.479 0.57201E+04 87 glaucophane 22.97 20.78 -2.20 -0.059 0.37486E+04 88 glaucophane-Fe 17.28 12.77 -4.51 -0.122 0.77012E+04 89 graphite -3.55 -6.89 -3.35 -0.956 0.57153E+04 90 greenalite 16.14 13.53 -2.61 -0.217 0.44501E+04 93 hematite 12.57 9.24 -3.33 -0.404 0.56866E+04 94 heulandite -5.83 -7.58 -1.75 -0.080 0.29904E+04 98 jadeite 4.22 2.77 -1.45 -0.145 0.24704E+04 100 kalsilite 7.58 3.82 -3.77 -0.538 0.64299E+04 101 kaolinite -1.33 -4.85 -3.51 -0.319 0.59991E+04 104 laumontite 2.88 1.88 -1.00 -0.067 0.17160E+04 105 lawsonite 9.62 8.18 -1.43 -0.096 0.24468E+04 106 leucite 4.12 0.67 -3.45 -0.345 0.58960E+04 108 lizardite 23.24 21.55 -1.70 -0.141 0.28971E+04 110 magnetite 20.09 15.85 -4.24 -0.346 0.72379E+04 111 minnesotaite 10.39 7.23 -3.16 -0.186 0.53948E+04 115 manganosite 14.06 9.24 -4.82 -1.205 0.82304E+04 119 microcline -2.49 -2.49 0.00 0.000 0.61722E-01 123 muscovite 2.58 -1.03 -3.61 -0.212 0.61648E+04 124 paragonite 4.24 1.07 -3.16 -0.186 0.54038E+04 125 nepheline 8.34 5.92 -2.42 -0.346 0.41298E+04 137 phlogopite-Na 29.65 27.47 -2.18 -0.121 0.37203E+04 139 prehnite 19.37 18.06 -1.31 -0.077 0.22400E+04 140 prehnite-Fe 22.50 21.95 -0.55 -0.033 0.93774E+03 141 pumpellyite-Fe 46.27 43.46 -2.81 -0.062 0.47937E+04 142 pumpellyite-Mg 48.99 46.13 -2.86 -0.064 0.48862E+04 146 pyrrhotite -4.26 -7.91 -3.65 -1.216 0.62270E+04 147 pyrrhotiteFe0.875 -6.02 -9.23 -3.21 -1.181 0.54837E+04 148 pyroxmangite 7.40 6.09 -1.31 -0.263 0.22421E+04 149 pyrophyllite -6.18 -11.15 -4.98 -0.311 0.84948E+04 150 quartz -2.99 -3.15 -0.16 -0.054 0.27815E+03 154 rhodochrosite -0.98 -5.63 -4.66 -1.553 0.79538E+04 155 rhodonite 7.45 6.09 -1.36 -0.272 0.23223E+04 156 sanidine -1.28 -2.49 -1.21 -0.093 0.20678E+04 166 stilbite -7.52 -7.58 -0.06 -0.003 0.96557E+02 167 stilpnomelane-Fe 13.02 12.42 -0.59 -0.018 0.10131E+04 168 stilpnomelane-Mg 27.44 25.78 -1.66 -0.050 0.28366E+04 174 talc 16.49 15.24 -1.25 -0.073 0.21320E+04 177 tephroite 18.09 15.32 -2.76 -0.395 0.47166E+04 181 tridymite -2.63 -3.15 -0.53 -0.175 0.89813E+03 182 tremolite 47.87 47.26 -0.61 -0.016 0.10411E+04 183 ferroactinolite 38.45 33.90 -4.55 -0.123 0.77678E+04 184 troilite-low -4.41 -7.91 -3.50 -1.165 0.59698E+04 190 wairakite 3.95 1.88 -2.07 -0.122 0.35380E+04 191 walstromite 11.51 9.88 -1.63 -0.326 0.27871E+04 192 wollastonite 10.46 9.88 -0.58 -0.117 0.99752E+03 193 pseudo-wollastonite 11.00 9.88 -1.12 -0.225 0.19174E+04 194 zoisite 22.85 18.79 -4.06 -0.185 0.69326E+04 195 akaganeite 7.75 4.62 -3.14 -0.678 0.53558E+04 202 chalcedony -2.80 -3.15 -0.35 -0.117 0.59745E+03 204 montmorillonite-Ca -2.29 -6.18 -3.89 -0.240 0.66374E+04 205 montmorillonite-K -2.24 -6.27 -4.03 -0.247 0.68837E+04 206 montmorillonite-Mg -2.48 -6.80 -4.32 -0.267 0.73696E+04 207 montmorillonite-Na -2.04 -5.57 -3.54 -0.217 0.60385E+04 208 nontronite-Ca 3.21 0.06 -3.16 -0.205 0.53911E+04 209 nontronite-H 2.53 -2.09 -4.63 -0.310 0.78977E+04 210 nontronite-K 3.34 -0.03 -3.37 -0.217 0.57606E+04 211 nontronite-Mg 3.07 -0.56 -3.64 -0.236 0.62074E+04 212 nontronite-Na 3.52 0.66 -2.86 -0.183 0.48815E+04 228 tobermorite 9.82 7.70 -2.12 -0.579 0.36233E+04 234 alabandite -0.98 -5.28 -4.30 -1.435 0.73491E+04 237 boehmite 4.41 0.73 -3.68 -0.613 0.62785E+04 239 ferrous-oxide 9.81 6.61 -3.20 -0.800 0.54621E+04 245 silica-amorphous -2.09 -3.15 -1.06 -0.354 0.18116E+04 247 an20ab80 2.02 1.33 -0.69 -0.053 0.11752E+04 248 an25ab75 2.65 1.76 -0.89 -0.068 0.15159E+04 249 an30ab70 3.28 2.19 -1.09 -0.084 0.18663E+04 250 tr.625ac.25prg.125 45.16 44.86 -0.30 -0.008 0.51270E+03 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 0.0000200 MOLES Current total amount of reactant added: 0.0007300 MOLES New total amount of reactant added: 0.0007500 MOLES Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.5508E-08 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 6 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 0.0007500 Water: Moles liquid = 0.4985E+02 kg liquid = 0.8981E+00 Moles total = 0.4985E+02 kg total = 0.8980E+00 Activity = 1.0000 Stoichiometric ionic strength = .1137805E-01 Osmotic coef. = 0.9670 True ionic strength = .2006091E-01 Chg. balance for total moles = -.5508E-08 Max. difference allowed = 0.1423E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.89451E-10 -10.0484 0.75152E-10 -10.1241 0.84014E+00 -0.0756 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.15774E-03 -3.8021 0.13172E-03 -3.8803 0.83508E+00 -0.0783 4 SO4-- 0.11904E-09 -9.9243 0.61785E-10 -10.2091 0.51902E+00 -0.2848 5 HCO3- 0.21948E-04 -4.6586 0.18355E-04 -4.7362 0.83630E+00 -0.0776 6 HS- 0.48683E-04 -4.3126 0.40660E-04 -4.3908 0.83520E+00 -0.0782 7 Al+++ 0.98552E-29 -29.0063 0.22740E-29 -29.6432 0.23074E+00 -0.6369 8 H4SiO4 0.70438E-03 -3.1522 0.70438E-03 -3.1522 0.10000E+01 0.0000 9 Ca++ 0.11695E-06 -6.9320 0.60255E-07 -7.2200 0.51520E+00 -0.2880 10 Mg++ 0.21161E-10 -10.6745 0.10852E-10 -10.9645 0.51284E+00 -0.2900 11 Fe++ 0.45076E-13 -13.3461 0.23142E-13 -13.6356 0.51341E+00 -0.2895 12 K+ 0.15651E-03 -3.8054 0.13093E-03 -3.8830 0.83650E+00 -0.0775 13 Na+ 0.19863E-01 -1.7020 0.16584E-01 -1.7803 0.83493E+00 -0.0784 14 Mn++ 0.19009E-10 -10.7210 0.97674E-11 -11.0102 0.51383E+00 -0.2892 15 F- 0.44396E-06 -6.3527 0.36998E-06 -6.4318 0.83336E+00 -0.0792 16 HPO4-- 0.45327E-07 -7.3436 0.23529E-07 -7.6284 0.51909E+00 -0.2848 18 HSiO3- 0.10480E-01 -1.9796 0.87517E-02 -2.0579 0.83508E+00 -0.0783 19 Ca(HSiO3)+ 0.14353E-07 -7.8430 0.12009E-07 -7.9205 0.83668E+00 -0.0774 20 Mg(HSiO3)+ 0.32173E-11 -11.4925 0.26919E-11 -11.5699 0.83668E+00 -0.0774 21 NaHSiO3,aq 0.23474E-02 -2.6294 0.23474E-02 -2.6294 0.10000E+01 0.0000 22 AlO+ 0.65467E-16 -16.1840 0.54775E-16 -16.2614 0.83668E+00 -0.0774 24 HAlO2,aq 0.14515E-09 -9.8382 0.14515E-09 -9.8382 0.10000E+01 0.0000 25 AlO2- 0.51290E-05 -5.2900 0.42754E-05 -5.3690 0.83357E+00 -0.0791 26 CH4,aq 0.11775E-04 -4.9290 0.11734E-04 -4.9306 0.99653E+00 -0.0015 27 C2H6,aq 0.64077E-14 -14.1933 0.63855E-14 -14.1948 0.99653E+00 -0.0015 31 CO,aq 0.27294E-15 -15.5639 0.27294E-15 -15.5639 0.10000E+01 0.0000 32 CO2,aq 0.29578E-08 -8.5290 0.29475E-08 -8.5305 0.99653E+00 -0.0015 33 CO3-2 0.41191E-04 -4.3852 0.21334E-04 -4.6709 0.51792E+00 -0.2857 34 CaCO3,aq 0.16118E-07 -7.7927 0.16118E-07 -7.7927 0.10000E+01 0.0000 35 Ca(HCO3)+ 0.33742E-10 -10.4718 0.28232E-10 -10.5493 0.83668E+00 -0.0774 36 CaCl+ 0.15352E-10 -10.8138 0.12844E-10 -10.8913 0.83668E+00 -0.0774 37 CaCl2,aq 0.40196E-15 -15.3958 0.40196E-15 -15.3958 0.10000E+01 0.0000 38 CaF+ 0.38901E-12 -12.4100 0.32548E-12 -12.4875 0.83668E+00 -0.0774 39 CaOH+ 0.68296E-07 -7.1656 0.57142E-07 -7.2430 0.83668E+00 -0.0774 40 CaSO4,aq 0.11822E-14 -14.9273 0.11822E-14 -14.9273 0.10000E+01 0.0000 41 HCl,aq 0.18140E-14 -14.7414 0.18140E-14 -14.7414 0.10000E+01 0.0000 45 HF,aq 0.19034E-12 -12.7205 0.19034E-12 -12.7205 0.10000E+01 0.0000 46 HF2- 0.28472E-19 -19.5456 0.23777E-19 -19.6238 0.83508E+00 -0.0783 48 FeCl+ 0.57669E-17 -17.2391 0.48251E-17 -17.3165 0.83668E+00 -0.0774 51 FeF+ 0.52295E-18 -18.2815 0.43755E-18 -18.3590 0.83668E+00 -0.0774 53 FeO,aq 0.15926E-09 -9.7979 0.15926E-09 -9.7979 0.10000E+01 0.0000 54 FeOH+ 0.11980E-10 -10.9215 0.10024E-10 -10.9990 0.83668E+00 -0.0774 55 HFeO2- 0.26551E-07 -7.5759 0.22173E-07 -7.6542 0.83508E+00 -0.0783 56 FeO+ 0.14884E-16 -16.8273 0.12453E-16 -16.9047 0.83668E+00 -0.0774 58 FeO2- 0.54027E-09 -9.2674 0.45117E-09 -9.3457 0.83508E+00 -0.0783 59 HFeO2,aq 0.43124E-11 -11.3653 0.43124E-11 -11.3653 0.10000E+01 0.0000 60 H2,aq 0.36990E-05 -5.4319 0.36861E-05 -5.4334 0.99653E+00 -0.0015 61 KCl,aq 0.31257E-09 -9.5051 0.31257E-09 -9.5051 0.10000E+01 0.0000 63 KOH,aq 0.74399E-06 -6.1284 0.74399E-06 -6.1284 0.10000E+01 0.0000 64 KSO4- 0.15031E-12 -12.8230 0.12552E-12 -12.9013 0.83508E+00 -0.0783 65 MgCO3,aq 0.72767E-12 -12.1381 0.72767E-12 -12.1381 0.10000E+01 0.0000 66 Mg(HCO3)+ 0.62099E-14 -14.2069 0.51957E-14 -14.2844 0.83668E+00 -0.0774 67 MgCl+ 0.25060E-14 -14.6010 0.20968E-14 -14.6785 0.83668E+00 -0.0774 68 MgF+ 0.25954E-15 -15.5858 0.21716E-15 -15.6632 0.83668E+00 -0.0774 69 MgOH+ 0.68066E-10 -10.1671 0.56950E-10 -10.2445 0.83668E+00 -0.0774 71 MnF+ 0.72750E-16 -16.1382 0.60868E-16 -16.2156 0.83668E+00 -0.0774 72 MnO,aq 0.17910E-08 -8.7469 0.17910E-08 -8.7469 0.10000E+01 0.0000 73 MnOH+ 0.46972E-09 -9.3282 0.39301E-09 -9.4056 0.83668E+00 -0.0774 74 MnO2-2 0.20320E-10 -10.6921 0.10524E-10 -10.9778 0.51792E+00 -0.2857 75 HMnO2- 0.20749E-09 -9.6830 0.17327E-09 -9.7613 0.83508E+00 -0.0783 78 MnCl+ 0.94692E-14 -14.0237 0.79228E-14 -14.1011 0.83668E+00 -0.0774 79 MnSO4,aq 0.17422E-18 -18.7589 0.17422E-18 -18.7589 0.10000E+01 0.0000 80 NaCl,aq 0.72395E-06 -6.1403 0.72395E-06 -6.1403 0.10000E+01 0.0000 81 NaF,aq 0.14365E-08 -8.8427 0.14365E-08 -8.8427 0.10000E+01 0.0000 82 NaOH,aq 0.94812E-04 -4.0231 0.94812E-04 -4.0231 0.10000E+01 0.0000 84 OH- 0.92231E-02 -2.0351 0.76881E-02 -2.1142 0.83357E+00 -0.0791 89 HPO3-2 0.52186E-15 -15.2824 0.27028E-15 -15.5682 0.51792E+00 -0.2857 91 H2PO3- 0.48776E-19 -19.3118 0.40732E-19 -19.3901 0.83508E+00 -0.0783 92 H3PO4,aq 0.92940E-18 -18.0318 0.92940E-18 -18.0318 0.10000E+01 0.0000 93 H2PO4- 0.39024E-10 -10.4087 0.32619E-10 -10.4865 0.83587E+00 -0.0779 94 PO4-3 0.10540E-08 -8.9772 0.25544E-09 -9.5927 0.24236E+00 -0.6155 98 HP2O7-3 0.95974E-18 -18.0178 0.22167E-18 -18.6543 0.23097E+00 -0.6364 99 P2O7-4 0.91588E-17 -17.0382 0.70466E-18 -18.1520 0.76938E-01 -1.1139 100 H2S,aq 0.94769E-08 -8.0233 0.94440E-08 -8.0248 0.99653E+00 -0.0015 101 S2-2 0.19189E-13 -13.7170 0.99381E-14 -14.0027 0.51792E+00 -0.2857 107 SO3-2 0.56327E-16 -16.2493 0.29596E-16 -16.5288 0.52542E+00 -0.2795 108 HSO3- 0.16676E-18 -18.7779 0.13926E-18 -18.8562 0.83508E+00 -0.0783 109 HSO4- 0.53430E-17 -17.2722 0.44748E-17 -17.3492 0.83750E+00 -0.0770 111 S2O3-2 0.13234E-19 -19.8783 0.68542E-20 -20.1640 0.51792E+00 -0.2857 Charge balance for all species = -.6133E-08 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.8945140E-10 -.2220887E-01 -.2234625E+02 0.0000 2 H2O 0.1000000E+01 0.5550477E+02 0.9981948E+06 0.0000 3 Cl- 0.1577373E-03 0.1584616E-03 0.5608162E+01 6.2437 4 SO4-- 0.1190409E-09 -.1269929E-04 -.1217792E+01 10.0390 5 HCO3- 0.2194807E-04 0.7493313E-04 0.4564252E+01 5.3878 6 HS- 0.4868326E-04 0.6139215E-04 0.2026828E+01 5.7332 7 Al+++ 0.9855186E-29 0.5129155E-05 0.1381514E+00 0.7290 8 H4SiO4 0.7043768E-03 0.1353184E-01 0.1298354E+04 -3.1522 9 Ca++ 0.1169528E-06 0.2157694E-06 0.8632558E-02 13.0281 10 Mg++ 0.2116137E-10 0.9318151E-10 0.2261486E-05 9.2836 11 Fe++ 0.4507624E-13 0.2726725E-07 0.1520144E-02 6.6125 12 K+ 0.1565149E-03 0.1572592E-03 0.6138449E+01 6.2411 13 Na+ 0.1986271E-01 0.2230566E-01 0.5119101E+03 8.3437 14 Mn++ 0.1900889E-10 0.2507539E-08 0.1375194E-03 9.2379 15 F- 0.4439638E-06 0.4454009E-06 0.8446999E-02 3.6922 16 HPO4-- 0.4532689E-07 0.4641989E-07 0.4447581E-02 12.6197 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.1994578E-01 -.1994507E-01 -.7184780E-06 0.0000000E+00 2 H2O 0.4984702E+02 0.4984702E+02 -.6744157E-06 0.0000000E+00 3 Cl- 0.1423092E-03 0.1423092E-03 0.0000000E+00 0.0000000E+00 4 SO4-- -.1140381E-04 -.1140482E-04 0.1013055E-08 0.0000000E+00 5 HCO3- 0.6729500E-04 0.6729500E-04 0.0000000E+00 0.0000000E+00 6 HS- 0.5513328E-04 0.5513429E-04 -.1013055E-08 0.0000000E+00 7 Al+++ 0.4775352E-05 0.4606327E-05 0.1690251E-06 0.0000000E+00 8 H4SiO4 0.1215302E-01 0.1215250E-01 0.5170806E-06 0.0000000E+00 9 Ca++ 0.2080835E-06 0.1937755E-06 0.1430799E-07 0.0000000E+00 10 Mg++ 0.8368328E-10 0.8368328E-10 0.0000000E+00 0.0000000E+00 11 Fe++ 0.3259227E-07 0.2448783E-07 0.8104444E-08 0.0000000E+00 12 K+ 0.1412294E-03 0.1412294E-03 0.0000000E+00 0.0000000E+00 13 Na+ 0.2003215E-01 0.2003198E-01 0.1675909E-06 0.0000000E+00 14 Mn++ 0.2251939E-08 0.2251939E-08 0.0000000E+00 0.0000000E+00 15 F- 0.4000000E-06 0.4000000E-06 0.0000000E+00 0.0000000E+00 16 HPO4-- 0.4168819E-07 0.4168819E-07 0.0000000E+00 0.0000000E+00 Chg. balance for solid moles: -.1059E-21 Mass of aqueous solution: 0.899633E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 0.0007500 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 0.1676E-06 -6.776 0.4395E-04 -4.357 94.86 0.1687E-04 andradite 0.4052E-08 -8.392 0.2059E-05 -5.686 4.445 0.5350E-06 grossular 0.7171E-09 -9.144 0.3230E-06 -6.491 0.6973 0.8988E-07 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8496E+00 0.8496E+00 1.0000 -0.071 grossular 0.1504E+00 0.1504E+00 1.0000 -0.823 Solid products produced: Mass = 0.000046 g Volume = 0.000017 cm3 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.0007500 moles log = -3.1249 Original solution: 1000.0103000 g Original solution / Rock added: 1333347.07 (Water/Rock Ratio), log = 6.1249 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0425 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9790E+00 0.9857 0.1006E+01 0.1021E+01 CO2,gas 0.3004E-06 1.0069 0.3154E-06 0.3132E-06 CH4,gas 0.1637E-01 1.0124 0.1727E-01 0.1706E-01 H2,gas 0.4640E-02 1.0006 0.4839E-02 0.4837E-02 H2S,gas 0.2500E-06 0.9960 0.2596E-06 0.2607E-06 S2,gas 0.1036E-27 1.0000 0.1080E-27 0.1080E-27 CO,gas 0.3901E-12 1.0000 0.4067E-12 0.4067E-12 SO3,gas 0.1266E-45 1.0000 0.1319E-45 0.1319E-45 SO2,gas 0.2383E-25 1.0000 0.2484E-25 0.2484E-25 HF,gas 0.4483E-15 1.0000 0.4674E-15 0.4674E-15 HCl,gas 0.3070E-17 1.0000 0.3201E-17 0.3201E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 17 albite -0.38 -0.38 0.00 0.000 0.11184E-10 23 andradite 39.01 39.01 0.00 0.000 -0.24265E-10 24 grossular 32.73 32.73 0.00 0.000 -0.12132E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -14.86 -8.20 -2.733 0.14002E+05 -6.501 3 CH4,gas 4.54 1.08 -3.46 -0.865 0.59107E+04 -1.763 4 H2,gas 8.00 3.99 -4.01 -2.294 0.68541E+04 -2.315 5 H2S,gas -6.23 -14.51 -8.28 -4.142 0.14146E+05 -6.586 6 S2,gas -7.34 -37.00 -29.67 -4.564 0.50653E+05 -27.967 7 CO,gas 3.21 -10.87 -14.09 -4.335 0.24058E+05 -12.391 8 SO3,gas 17.12 -30.46 -47.58 -11.895 0.81239E+05 -45.880 9 SO2,gas 0.83 -26.47 -27.30 -7.281 0.46620E+05 -25.605 10 HF,gas 0.47 -16.56 -17.03 -8.515 0.29077E+05 -15.330 11 HCl,gas 5.19 -14.00 -19.19 -9.597 0.32773E+05 -17.495 12 acmite 7.71 6.66 -1.05 -0.109 0.17939E+04 16 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 20 spessartine 24.46 19.72 -4.74 -0.237 0.80973E+04 21 analcite 3.32 2.77 -0.55 -0.062 0.94514E+03 27 annite 20.12 17.35 -2.77 -0.154 0.47337E+04 28 phlogopite 27.06 25.36 -1.70 -0.094 0.29030E+04 30 anorthite 12.71 8.18 -4.53 -0.348 0.77326E+04 33 apatite-OH -18.15 -18.49 -0.34 -0.026 0.57288E+03 34 apatite-F -34.30 -35.04 -0.74 -0.062 0.12702E+04 38 aragonite 0.97 -1.83 -2.80 -0.933 0.47787E+04 39 brucite 12.57 9.28 -3.28 -0.657 0.56089E+04 40 calcite 0.81 -1.83 -2.64 -0.881 0.45145E+04 41 carnegieite-low 9.02 5.92 -3.10 -0.443 0.52979E+04 42 carnegieite-high 10.09 5.92 -4.17 -0.596 0.71249E+04 43 carpholite-Mg 8.58 4.44 -4.14 -0.276 0.70773E+04 44 carpholite-Fe 6.71 1.77 -4.95 -0.330 0.84461E+04 45 celadonite 5.34 3.64 -1.70 -0.100 0.28970E+04 46 celadonite-Fe 3.88 0.97 -2.90 -0.171 0.49563E+04 47 chrysotile 23.89 21.55 -2.35 -0.195 0.40054E+04 49 clinochlore 39.07 38.42 -0.65 -0.020 0.11097E+04 50 daphnite 28.97 25.06 -3.90 -0.122 0.66613E+04 52 chlorite-Al-free 47.17 43.09 -4.08 -0.170 0.69661E+04 54 chloritoid-Fe 9.17 4.92 -4.26 -0.284 0.72659E+04 55 chloritoid-Mn 11.40 7.54 -3.86 -0.257 0.65865E+04 57 coesite -2.38 -3.15 -0.78 -0.259 0.13252E+04 64 cristobalite -2.56 -3.15 -0.59 -0.197 0.10106E+04 66 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71234E+04 68 diaspore 2.87 0.73 -2.14 -0.357 0.36621E+04 69 diamond -3.10 -6.89 -3.79 -1.082 0.64657E+04 70 diopside 16.18 16.01 -0.17 -0.017 0.29708E+03 71 hedenbergite 14.21 13.34 -0.87 -0.087 0.14890E+04 76 clinoenstatite 17.17 12.26 -4.90 -0.490 0.83724E+04 78 epidote 24.67 22.68 -1.99 -0.097 0.34023E+04 79 clinozoisite 22.81 18.79 -4.02 -0.183 0.68632E+04 80 epidote-Fe 29.84 26.57 -3.27 -0.170 0.55881E+04 81 fayalite 14.05 10.07 -3.97 -0.568 0.67836E+04 82 ferrosilite 11.15 6.92 -4.23 -0.423 0.72205E+04 86 gibbsite 4.08 0.73 -3.35 -0.479 0.57206E+04 87 glaucophane 22.97 20.78 -2.20 -0.059 0.37496E+04 88 glaucophane-Fe 17.28 12.77 -4.51 -0.122 0.77013E+04 89 graphite -3.55 -6.89 -3.34 -0.955 0.57080E+04 90 greenalite 16.14 13.53 -2.61 -0.217 0.44502E+04 93 hematite 12.57 9.24 -3.33 -0.403 0.56803E+04 94 heulandite -5.83 -7.58 -1.75 -0.080 0.29916E+04 98 jadeite 4.22 2.77 -1.45 -0.145 0.24706E+04 100 kalsilite 7.58 3.82 -3.77 -0.538 0.64304E+04 101 kaolinite -1.33 -4.85 -3.51 -0.319 0.59995E+04 104 laumontite 2.88 1.88 -1.01 -0.067 0.17180E+04 105 lawsonite 9.62 8.18 -1.43 -0.096 0.24492E+04 106 leucite 4.12 0.67 -3.45 -0.345 0.58962E+04 108 lizardite 23.24 21.55 -1.70 -0.141 0.28981E+04 110 magnetite 20.09 15.85 -4.24 -0.346 0.72318E+04 111 minnesotaite 10.39 7.23 -3.16 -0.186 0.53944E+04 115 manganosite 14.06 9.24 -4.82 -1.205 0.82304E+04 119 microcline -2.49 -2.49 0.00 0.000 0.63431E-01 123 muscovite 2.58 -1.03 -3.61 -0.212 0.61657E+04 124 paragonite 4.24 1.07 -3.17 -0.186 0.54048E+04 125 nepheline 8.34 5.92 -2.42 -0.346 0.41303E+04 137 phlogopite-Na 29.65 27.47 -2.18 -0.121 0.37218E+04 139 prehnite 19.37 18.06 -1.31 -0.077 0.22441E+04 140 prehnite-Fe 22.50 21.95 -0.55 -0.033 0.93829E+03 141 pumpellyite-Fe 46.27 43.46 -2.81 -0.063 0.48027E+04 142 pumpellyite-Mg 48.99 46.13 -2.87 -0.064 0.48955E+04 146 pyrrhotite -4.26 -7.90 -3.64 -1.214 0.62187E+04 147 pyrrhotiteFe0.875 -6.02 -9.22 -3.21 -1.179 0.54745E+04 148 pyroxmangite 7.40 6.09 -1.31 -0.263 0.22419E+04 149 pyrophyllite -6.18 -11.15 -4.98 -0.311 0.84948E+04 150 quartz -2.99 -3.15 -0.16 -0.054 0.27791E+03 154 rhodochrosite -0.98 -5.62 -4.65 -1.549 0.79331E+04 155 rhodonite 7.45 6.09 -1.36 -0.272 0.23221E+04 156 sanidine -1.28 -2.49 -1.21 -0.093 0.20678E+04 166 stilbite -7.52 -7.58 -0.06 -0.003 0.97777E+02 167 stilpnomelane-Fe 13.02 12.42 -0.59 -0.018 0.10132E+04 168 stilpnomelane-Mg 27.44 25.78 -1.66 -0.050 0.28382E+04 174 talc 16.49 15.24 -1.25 -0.073 0.21325E+04 177 tephroite 18.09 15.32 -2.76 -0.395 0.47164E+04 181 tridymite -2.63 -3.15 -0.53 -0.175 0.89789E+03 182 tremolite 47.87 47.26 -0.61 -0.017 0.10456E+04 183 ferroactinolite 38.45 33.90 -4.55 -0.123 0.77708E+04 184 troilite-low -4.41 -7.90 -3.49 -1.164 0.59615E+04 190 wairakite 3.95 1.88 -2.07 -0.122 0.35399E+04 191 walstromite 11.51 9.88 -1.63 -0.327 0.27888E+04 192 wollastonite 10.46 9.88 -0.59 -0.117 0.99927E+03 193 pseudo-wollastonite 11.00 9.88 -1.12 -0.225 0.19191E+04 194 zoisite 22.85 18.79 -4.06 -0.185 0.69372E+04 195 akaganeite 7.75 4.62 -3.13 -0.678 0.53527E+04 202 chalcedony -2.80 -3.15 -0.35 -0.117 0.59721E+03 204 montmorillonite-Ca -2.29 -6.18 -3.89 -0.240 0.66377E+04 205 montmorillonite-K -2.24 -6.27 -4.03 -0.247 0.68837E+04 206 montmorillonite-Mg -2.48 -6.80 -4.32 -0.267 0.73697E+04 207 montmorillonite-Na -2.04 -5.57 -3.54 -0.217 0.60386E+04 208 nontronite-Ca 3.21 0.06 -3.15 -0.205 0.53844E+04 209 nontronite-H 2.53 -2.09 -4.62 -0.310 0.78906E+04 210 nontronite-K 3.34 -0.03 -3.37 -0.216 0.57536E+04 211 nontronite-Mg 3.07 -0.56 -3.63 -0.236 0.62004E+04 212 nontronite-Na 3.52 0.66 -2.85 -0.183 0.48745E+04 228 tobermorite 9.82 7.70 -2.12 -0.579 0.36247E+04 234 alabandite -0.98 -5.28 -4.30 -1.433 0.73406E+04 237 boehmite 4.41 0.73 -3.68 -0.613 0.62790E+04 239 ferrous-oxide 9.81 6.61 -3.20 -0.800 0.54623E+04 245 silica-amorphous -2.09 -3.15 -1.06 -0.354 0.18114E+04 247 an20ab80 2.02 1.33 -0.69 -0.053 0.11757E+04 248 an25ab75 2.65 1.76 -0.89 -0.068 0.15166E+04 249 an30ab70 3.28 2.19 -1.09 -0.084 0.18670E+04 250 tr.625ac.25prg.125 45.16 44.86 -0.30 -0.008 0.51703E+03 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 0.0000200 MOLES Current total amount of reactant added: 0.0007500 MOLES New total amount of reactant added: 0.0007700 MOLES Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.5508E-08 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 6 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 0.0007700 Water: Moles liquid = 0.4985E+02 kg liquid = 0.8981E+00 Moles total = 0.4985E+02 kg total = 0.8980E+00 Activity = 1.0000 Stoichiometric ionic strength = .1137933E-01 Osmotic coef. = 0.9669 True ionic strength = .2006209E-01 Chg. balance for total moles = -.5508E-08 Max. difference allowed = 0.1424E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.89483E-10 -10.0483 0.75178E-10 -10.1239 0.84014E+00 -0.0756 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.15787E-03 -3.8017 0.13183E-03 -3.8800 0.83508E+00 -0.0783 4 SO4-- 0.12469E-09 -9.9042 0.64714E-10 -10.1890 0.51901E+00 -0.2848 5 HCO3- 0.22547E-04 -4.6469 0.18856E-04 -4.7246 0.83630E+00 -0.0776 6 HS- 0.49224E-04 -4.3078 0.41112E-04 -4.3860 0.83520E+00 -0.0782 7 Al+++ 0.98597E-29 -29.0061 0.22749E-29 -29.6430 0.23073E+00 -0.6369 8 H4SiO4 0.70461E-03 -3.1521 0.70461E-03 -3.1521 0.10000E+01 0.0000 9 Ca++ 0.11673E-06 -6.9328 0.60137E-07 -7.2209 0.51520E+00 -0.2880 10 Mg++ 0.21163E-10 -10.6744 0.10853E-10 -10.9645 0.51284E+00 -0.2900 11 Fe++ 0.45099E-13 -13.3458 0.23154E-13 -13.6354 0.51340E+00 -0.2895 12 K+ 0.15652E-03 -3.8054 0.13093E-03 -3.8830 0.83650E+00 -0.0775 13 Na+ 0.19863E-01 -1.7020 0.16584E-01 -1.7803 0.83493E+00 -0.0784 14 Mn++ 0.19022E-10 -10.7207 0.97739E-11 -11.0099 0.51382E+00 -0.2892 15 F- 0.45284E-06 -6.3441 0.37738E-06 -6.4232 0.83335E+00 -0.0792 16 HPO4-- 0.45327E-07 -7.3436 0.23529E-07 -7.6284 0.51909E+00 -0.2848 18 HSiO3- 0.10480E-01 -1.9796 0.87515E-02 -2.0579 0.83508E+00 -0.0783 19 Ca(HSiO3)+ 0.14325E-07 -7.8439 0.11985E-07 -7.9213 0.83668E+00 -0.0774 20 Mg(HSiO3)+ 0.32174E-11 -11.4925 0.26919E-11 -11.5699 0.83668E+00 -0.0774 21 NaHSiO3,aq 0.23473E-02 -2.6294 0.23473E-02 -2.6294 0.10000E+01 0.0000 22 AlO+ 0.65449E-16 -16.1841 0.54760E-16 -16.2615 0.83668E+00 -0.0774 24 HAlO2,aq 0.14506E-09 -9.8385 0.14506E-09 -9.8385 0.10000E+01 0.0000 25 AlO2- 0.51240E-05 -5.2904 0.42712E-05 -5.3695 0.83357E+00 -0.0791 26 CH4,aq 0.11677E-04 -4.9327 0.11636E-04 -4.9342 0.99653E+00 -0.0015 27 C2H6,aq 0.63578E-14 -14.1967 0.63357E-14 -14.1982 0.99653E+00 -0.0015 31 CO,aq 0.27799E-15 -15.5560 0.27799E-15 -15.5560 0.10000E+01 0.0000 32 CO2,aq 0.30395E-08 -8.5172 0.30290E-08 -8.5187 0.99653E+00 -0.0015 33 CO3-2 0.42300E-04 -4.3737 0.21908E-04 -4.6594 0.51791E+00 -0.2857 34 CaCO3,aq 0.16519E-07 -7.7820 0.16519E-07 -7.7820 0.10000E+01 0.0000 35 Ca(HCO3)+ 0.34595E-10 -10.4610 0.28945E-10 -10.5384 0.83668E+00 -0.0774 36 CaCl+ 0.15334E-10 -10.8143 0.12830E-10 -10.8918 0.83668E+00 -0.0774 37 CaCl2,aq 0.40184E-15 -15.3959 0.40184E-15 -15.3959 0.10000E+01 0.0000 38 CaF+ 0.39601E-12 -12.4023 0.33134E-12 -12.4797 0.83668E+00 -0.0774 39 CaOH+ 0.68138E-07 -7.1666 0.57010E-07 -7.2441 0.83668E+00 -0.0774 40 CaSO4,aq 0.12358E-14 -14.9081 0.12358E-14 -14.9081 0.10000E+01 0.0000 41 HCl,aq 0.18161E-14 -14.7409 0.18161E-14 -14.7409 0.10000E+01 0.0000 45 HF,aq 0.19422E-12 -12.7117 0.19422E-12 -12.7117 0.10000E+01 0.0000 46 HF2- 0.29633E-19 -19.5282 0.24746E-19 -19.6065 0.83508E+00 -0.0783 48 FeCl+ 0.57746E-17 -17.2385 0.48315E-17 -17.3159 0.83668E+00 -0.0774 51 FeF+ 0.53367E-18 -18.2727 0.44651E-18 -18.3502 0.83668E+00 -0.0774 53 FeO,aq 0.15922E-09 -9.7980 0.15922E-09 -9.7980 0.10000E+01 0.0000 54 FeOH+ 0.11982E-10 -10.9215 0.10025E-10 -10.9989 0.83668E+00 -0.0774 55 HFeO2- 0.26536E-07 -7.5762 0.22160E-07 -7.6544 0.83508E+00 -0.0783 56 FeO+ 0.14952E-16 -16.8253 0.12510E-16 -16.9027 0.83668E+00 -0.0774 58 FeO2- 0.54238E-09 -9.2657 0.45293E-09 -9.3440 0.83508E+00 -0.0783 59 HFeO2,aq 0.43307E-11 -11.3634 0.43307E-11 -11.3634 0.10000E+01 0.0000 60 H2,aq 0.36662E-05 -5.4358 0.36534E-05 -5.4373 0.99653E+00 -0.0015 61 KCl,aq 0.31283E-09 -9.5047 0.31283E-09 -9.5047 0.10000E+01 0.0000 63 KOH,aq 0.74373E-06 -6.1286 0.74373E-06 -6.1286 0.10000E+01 0.0000 64 KSO4- 0.15744E-12 -12.8029 0.13148E-12 -12.8812 0.83508E+00 -0.0783 65 MgCO3,aq 0.74728E-12 -12.1265 0.74728E-12 -12.1265 0.10000E+01 0.0000 66 Mg(HCO3)+ 0.63795E-14 -14.1952 0.53376E-14 -14.2727 0.83668E+00 -0.0774 67 MgCl+ 0.25082E-14 -14.6006 0.20986E-14 -14.6781 0.83668E+00 -0.0774 68 MgF+ 0.26474E-15 -15.5772 0.22151E-15 -15.6546 0.83668E+00 -0.0774 69 MgOH+ 0.68045E-10 -10.1672 0.56932E-10 -10.2446 0.83668E+00 -0.0774 71 MnF+ 0.74254E-16 -16.1293 0.62127E-16 -16.2067 0.83668E+00 -0.0774 72 MnO,aq 0.17909E-08 -8.7469 0.17909E-08 -8.7469 0.10000E+01 0.0000 73 MnOH+ 0.46987E-09 -9.3280 0.39313E-09 -9.4055 0.83668E+00 -0.0774 74 MnO2-2 0.20305E-10 -10.6924 0.10516E-10 -10.9781 0.51791E+00 -0.2857 75 HMnO2- 0.20741E-09 -9.6832 0.17321E-09 -9.7614 0.83508E+00 -0.0783 78 MnCl+ 0.94834E-14 -14.0230 0.79346E-14 -14.1005 0.83668E+00 -0.0774 79 MnSO4,aq 0.18260E-18 -18.7385 0.18260E-18 -18.7385 0.10000E+01 0.0000 80 NaCl,aq 0.72455E-06 -6.1399 0.72455E-06 -6.1399 0.10000E+01 0.0000 81 NaF,aq 0.14652E-08 -8.8341 0.14652E-08 -8.8341 0.10000E+01 0.0000 82 NaOH,aq 0.94778E-04 -4.0233 0.94778E-04 -4.0233 0.10000E+01 0.0000 84 OH- 0.92198E-02 -2.0353 0.76854E-02 -2.1143 0.83357E+00 -0.0791 89 HPO3-2 0.51724E-15 -15.2863 0.26788E-15 -15.5721 0.51791E+00 -0.2857 91 H2PO3- 0.48361E-19 -19.3155 0.40385E-19 -19.3938 0.83508E+00 -0.0783 92 H3PO4,aq 0.93005E-18 -18.0315 0.93005E-18 -18.0315 0.10000E+01 0.0000 93 H2PO4- 0.39038E-10 -10.4085 0.32631E-10 -10.4864 0.83587E+00 -0.0779 94 PO4-3 0.10536E-08 -8.9773 0.25535E-09 -9.5929 0.24236E+00 -0.6155 98 HP2O7-3 0.96009E-18 -18.0177 0.22175E-18 -18.6541 0.23096E+00 -0.6365 99 P2O7-4 0.91592E-17 -17.0381 0.70465E-18 -18.1520 0.76933E-01 -1.1139 100 H2S,aq 0.95856E-08 -8.0184 0.95523E-08 -8.0199 0.99653E+00 -0.0015 101 S2-2 0.19793E-13 -13.7035 0.10251E-13 -13.9892 0.51791E+00 -0.2857 107 SO3-2 0.58476E-16 -16.2330 0.30724E-16 -16.5125 0.52541E+00 -0.2795 108 HSO3- 0.17318E-18 -18.7615 0.14462E-18 -18.8398 0.83508E+00 -0.0783 109 HSO4- 0.55983E-17 -17.2519 0.46886E-17 -17.3290 0.83750E+00 -0.0770 111 S2O3-2 0.14021E-19 -19.8532 0.72615E-20 -20.1390 0.51791E+00 -0.2857 Charge balance for all species = -.6133E-08 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.8948333E-10 -.2220645E-01 -.2234381E+02 0.0000 2 H2O 0.1000000E+01 0.5550476E+02 0.9981947E+06 0.0000 3 Cl- 0.1578681E-03 0.1585929E-03 0.5612810E+01 6.2439 4 SO4-- 0.1246870E-09 -.1259295E-04 -.1207594E+01 10.0588 5 HCO3- 0.2254673E-04 0.7654322E-04 0.4662324E+01 5.3994 6 HS- 0.4922429E-04 0.6182695E-04 0.2041182E+01 5.7379 7 Al+++ 0.9859693E-29 0.5124096E-05 0.1380152E+00 0.7287 8 H4SiO4 0.7046096E-03 0.1353182E-01 0.1298352E+04 -3.1521 9 Ca++ 0.1167255E-06 0.2157582E-06 0.8632109E-02 13.0270 10 Mg++ 0.2116255E-10 0.9318148E-10 0.2261485E-05 9.2834 11 Fe++ 0.4509906E-13 0.2725433E-07 0.1519423E-02 6.6124 12 K+ 0.1565151E-03 0.1572592E-03 0.6138446E+01 6.2409 13 Na+ 0.1986279E-01 0.2230564E-01 0.5119098E+03 8.3436 14 Mn++ 0.1902189E-10 0.2507538E-08 0.1375194E-03 9.2379 15 F- 0.4528429E-06 0.4543087E-06 0.8615935E-02 3.7007 16 HPO4-- 0.4532721E-07 0.4641987E-07 0.4447579E-02 12.6194 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.1994363E-01 -.1994289E-01 -.7366912E-06 0.0000000E+00 2 H2O 0.4984704E+02 0.4984704E+02 -.6926079E-06 0.0000000E+00 3 Cl- 0.1424272E-03 0.1424272E-03 0.0000000E+00 0.0000000E+00 4 SO4-- -.1130831E-04 -.1130932E-04 0.1014505E-08 0.0000000E+00 5 HCO3- 0.6874100E-04 0.6874100E-04 0.0000000E+00 0.0000000E+00 6 HS- 0.5552378E-04 0.5552479E-04 -.1014505E-08 0.0000000E+00 7 Al+++ 0.4775352E-05 0.4601785E-05 0.1735667E-06 0.0000000E+00 8 H4SiO4 0.1215302E-01 0.1215249E-01 0.5307304E-06 0.0000000E+00 9 Ca++ 0.2080835E-06 0.1937655E-06 0.1431798E-07 0.0000000E+00 10 Mg++ 0.8368328E-10 0.8368328E-10 0.0000000E+00 0.0000000E+00 11 Fe++ 0.3259227E-07 0.2447623E-07 0.8116037E-08 0.0000000E+00 12 K+ 0.1412294E-03 0.1412294E-03 0.0000000E+00 0.0000000E+00 13 Na+ 0.2003215E-01 0.2003198E-01 0.1721375E-06 0.0000000E+00 14 Mn++ 0.2251939E-08 0.2251939E-08 0.0000000E+00 0.0000000E+00 15 F- 0.4080000E-06 0.4080000E-06 0.0000000E+00 0.0000000E+00 16 HPO4-- 0.4168819E-07 0.4168819E-07 0.0000000E+00 0.0000000E+00 Chg. balance for solid moles: -.5294E-22 Mass of aqueous solution: 0.899634E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 0.0007700 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 0.1721E-06 -6.764 0.4514E-04 -4.345 94.98 0.1733E-04 andradite 0.4058E-08 -8.392 0.2062E-05 -5.686 4.339 0.5358E-06 grossular 0.7146E-09 -9.146 0.3219E-06 -6.492 0.6774 0.8957E-07 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8503E+00 0.8503E+00 1.0000 -0.070 grossular 0.1497E+00 0.1497E+00 1.0000 -0.825 Solid products produced: Mass = 0.000048 g Volume = 0.000018 cm3 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.0007700 moles log = -3.1135 Original solution: 1000.0103000 g Original solution / Rock added: 1298714.68 (Water/Rock Ratio), log = 6.1135 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0423 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9792E+00 0.9857 0.1006E+01 0.1021E+01 CO2,gas 0.3088E-06 1.0069 0.3241E-06 0.3219E-06 CH4,gas 0.1623E-01 1.0124 0.1713E-01 0.1692E-01 H2,gas 0.4599E-02 1.0006 0.4797E-02 0.4794E-02 H2S,gas 0.2530E-06 0.9960 0.2626E-06 0.2637E-06 S2,gas 0.1079E-27 1.0000 0.1125E-27 0.1125E-27 CO,gas 0.3974E-12 1.0000 0.4143E-12 0.4143E-12 SO3,gas 0.1327E-45 1.0000 0.1383E-45 0.1383E-45 SO2,gas 0.2476E-25 1.0000 0.2581E-25 0.2581E-25 HF,gas 0.4575E-15 1.0000 0.4769E-15 0.4769E-15 HCl,gas 0.3075E-17 1.0000 0.3205E-17 0.3205E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 17 albite -0.38 -0.38 0.00 0.000 -0.13080E-10 23 andradite 39.01 39.01 0.00 0.000 0.12132E-10 24 grossular 32.73 32.73 0.00 0.000 0.12132E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -14.85 -8.19 -2.729 0.13981E+05 -6.489 3 CH4,gas 4.54 1.08 -3.47 -0.866 0.59169E+04 -1.766 4 H2,gas 8.00 3.98 -4.02 -2.296 0.68607E+04 -2.319 5 H2S,gas -6.23 -14.51 -8.28 -4.140 0.14137E+05 -6.581 6 S2,gas -7.34 -36.98 -29.65 -4.561 0.50623E+05 -27.949 7 CO,gas 3.21 -10.87 -14.08 -4.333 0.24044E+05 -12.383 8 SO3,gas 17.12 -30.44 -47.56 -11.890 0.81204E+05 -45.859 9 SO2,gas 0.83 -26.46 -27.29 -7.277 0.46592E+05 -25.588 10 HF,gas 0.47 -16.55 -17.02 -8.510 0.29062E+05 -15.322 11 HCl,gas 5.19 -14.00 -19.19 -9.597 0.32772E+05 -17.494 12 acmite 7.71 6.66 -1.05 -0.109 0.17905E+04 16 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 20 spessartine 24.46 19.71 -4.74 -0.237 0.80976E+04 21 analcite 3.32 2.77 -0.55 -0.062 0.94539E+03 27 annite 20.12 17.35 -2.77 -0.154 0.47342E+04 28 phlogopite 27.06 25.36 -1.70 -0.095 0.29045E+04 30 anorthite 12.71 8.18 -4.53 -0.348 0.77350E+04 33 apatite-OH -18.15 -18.49 -0.34 -0.026 0.58122E+03 34 apatite-F -34.30 -35.04 -0.74 -0.062 0.12636E+04 38 aragonite 0.97 -1.82 -2.79 -0.929 0.47605E+04 39 brucite 12.57 9.28 -3.29 -0.657 0.56094E+04 40 calcite 0.81 -1.82 -2.63 -0.878 0.44963E+04 41 carnegieite-low 9.02 5.92 -3.10 -0.443 0.52984E+04 42 carnegieite-high 10.09 5.92 -4.17 -0.596 0.71254E+04 43 carpholite-Mg 8.58 4.44 -4.15 -0.276 0.70782E+04 44 carpholite-Fe 6.71 1.77 -4.95 -0.330 0.84467E+04 45 celadonite 5.34 3.64 -1.70 -0.100 0.28973E+04 46 celadonite-Fe 3.88 0.97 -2.90 -0.171 0.49562E+04 47 chrysotile 23.89 21.55 -2.35 -0.196 0.40064E+04 49 clinochlore 39.07 38.42 -0.65 -0.020 0.11124E+04 50 daphnite 28.97 25.06 -3.90 -0.122 0.66623E+04 52 chlorite-Al-free 47.17 43.09 -4.08 -0.170 0.69680E+04 54 chloritoid-Fe 9.17 4.92 -4.26 -0.284 0.72668E+04 55 chloritoid-Mn 11.40 7.54 -3.86 -0.257 0.65872E+04 57 coesite -2.38 -3.15 -0.78 -0.259 0.13250E+04 64 cristobalite -2.56 -3.15 -0.59 -0.197 0.10103E+04 66 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71234E+04 68 diaspore 2.87 0.73 -2.15 -0.358 0.36625E+04 69 diamond -3.10 -6.89 -3.78 -1.081 0.64587E+04 70 diopside 16.18 16.01 -0.18 -0.018 0.29906E+03 71 hedenbergite 14.21 13.34 -0.87 -0.087 0.14906E+04 76 clinoenstatite 17.17 12.26 -4.90 -0.490 0.83729E+04 78 epidote 24.67 22.68 -1.99 -0.097 0.34033E+04 79 clinozoisite 22.81 18.78 -4.02 -0.183 0.68678E+04 80 epidote-Fe 29.84 26.57 -3.27 -0.170 0.55855E+04 81 fayalite 14.05 10.07 -3.97 -0.568 0.67836E+04 82 ferrosilite 11.15 6.92 -4.23 -0.423 0.72204E+04 86 gibbsite 4.08 0.73 -3.35 -0.479 0.57211E+04 87 glaucophane 22.97 20.78 -2.20 -0.059 0.37506E+04 88 glaucophane-Fe 17.28 12.77 -4.51 -0.122 0.77013E+04 89 graphite -3.55 -6.89 -3.34 -0.954 0.57010E+04 90 greenalite 16.14 13.53 -2.61 -0.217 0.44502E+04 93 hematite 12.57 9.24 -3.32 -0.403 0.56740E+04 94 heulandite -5.83 -7.58 -1.75 -0.080 0.29928E+04 98 jadeite 4.22 2.77 -1.45 -0.145 0.24709E+04 100 kalsilite 7.58 3.82 -3.77 -0.538 0.64309E+04 101 kaolinite -1.33 -4.85 -3.51 -0.319 0.60000E+04 104 laumontite 2.88 1.88 -1.01 -0.067 0.17199E+04 105 lawsonite 9.62 8.18 -1.44 -0.096 0.24517E+04 106 leucite 4.12 0.67 -3.45 -0.345 0.58965E+04 108 lizardite 23.24 21.55 -1.70 -0.141 0.28991E+04 110 magnetite 20.09 15.86 -4.23 -0.345 0.72257E+04 111 minnesotaite 10.39 7.23 -3.16 -0.186 0.53939E+04 115 manganosite 14.06 9.24 -4.82 -1.205 0.82304E+04 119 microcline -2.49 -2.49 0.00 0.000 0.65141E-01 123 muscovite 2.58 -1.03 -3.61 -0.212 0.61667E+04 124 paragonite 4.24 1.07 -3.17 -0.186 0.54057E+04 125 nepheline 8.34 5.92 -2.42 -0.346 0.41308E+04 137 phlogopite-Na 29.65 27.47 -2.18 -0.121 0.37232E+04 139 prehnite 19.37 18.06 -1.32 -0.077 0.22483E+04 140 prehnite-Fe 22.50 21.95 -0.55 -0.033 0.93884E+03 141 pumpellyite-Fe 46.27 43.45 -2.82 -0.063 0.48117E+04 142 pumpellyite-Mg 48.99 46.12 -2.87 -0.064 0.49048E+04 146 pyrrhotite -4.26 -7.90 -3.64 -1.212 0.62104E+04 147 pyrrhotiteFe0.875 -6.02 -9.22 -3.20 -1.177 0.54653E+04 148 pyroxmangite 7.40 6.09 -1.31 -0.263 0.22417E+04 149 pyrophyllite -6.18 -11.15 -4.98 -0.311 0.84947E+04 150 quartz -2.99 -3.15 -0.16 -0.054 0.27766E+03 154 rhodochrosite -0.98 -5.61 -4.63 -1.545 0.79129E+04 155 rhodonite 7.45 6.09 -1.36 -0.272 0.23219E+04 156 sanidine -1.28 -2.49 -1.21 -0.093 0.20678E+04 166 stilbite -7.52 -7.58 -0.06 -0.003 0.98986E+02 167 stilpnomelane-Fe 13.02 12.42 -0.59 -0.018 0.10131E+04 168 stilpnomelane-Mg 27.44 25.78 -1.66 -0.050 0.28398E+04 174 talc 16.49 15.24 -1.25 -0.073 0.21330E+04 177 tephroite 18.09 15.32 -2.76 -0.395 0.47162E+04 181 tridymite -2.63 -3.15 -0.53 -0.175 0.89764E+03 182 tremolite 47.87 47.25 -0.61 -0.017 0.10500E+04 183 ferroactinolite 38.45 33.90 -4.55 -0.123 0.77736E+04 184 troilite-low -4.41 -7.90 -3.49 -1.162 0.59532E+04 190 wairakite 3.95 1.88 -2.07 -0.122 0.35419E+04 191 walstromite 11.51 9.87 -1.63 -0.327 0.27906E+04 192 wollastonite 10.46 9.87 -0.59 -0.117 0.10010E+04 193 pseudo-wollastonite 11.00 9.87 -1.12 -0.225 0.19208E+04 194 zoisite 22.85 18.78 -4.07 -0.185 0.69419E+04 195 akaganeite 7.75 4.62 -3.13 -0.677 0.53495E+04 202 chalcedony -2.80 -3.15 -0.35 -0.117 0.59696E+03 204 montmorillonite-Ca -2.29 -6.18 -3.89 -0.240 0.66380E+04 205 montmorillonite-K -2.24 -6.27 -4.03 -0.247 0.68838E+04 206 montmorillonite-Mg -2.48 -6.80 -4.32 -0.267 0.73697E+04 207 montmorillonite-Na -2.04 -5.57 -3.54 -0.217 0.60386E+04 208 nontronite-Ca 3.21 0.07 -3.15 -0.204 0.53777E+04 209 nontronite-H 2.53 -2.08 -4.62 -0.309 0.78836E+04 210 nontronite-K 3.34 -0.02 -3.37 -0.216 0.57467E+04 211 nontronite-Mg 3.07 -0.55 -3.63 -0.235 0.61935E+04 212 nontronite-Na 3.52 0.67 -2.85 -0.183 0.48675E+04 228 tobermorite 9.82 7.70 -2.12 -0.579 0.36261E+04 234 alabandite -0.98 -5.27 -4.29 -1.431 0.73322E+04 237 boehmite 4.41 0.73 -3.68 -0.613 0.62795E+04 239 ferrous-oxide 9.81 6.61 -3.20 -0.800 0.54625E+04 245 silica-amorphous -2.09 -3.15 -1.06 -0.354 0.18111E+04 247 an20ab80 2.02 1.33 -0.69 -0.053 0.11762E+04 248 an25ab75 2.65 1.76 -0.89 -0.068 0.15172E+04 249 an30ab70 3.28 2.19 -1.09 -0.084 0.18678E+04 250 tr.625ac.25prg.125 45.16 44.86 -0.31 -0.008 0.52129E+03 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 0.0000200 MOLES Current total amount of reactant added: 0.0007700 MOLES New total amount of reactant added: 0.0007900 MOLES Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.5508E-08 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 6 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 0.0007900 Water: Moles liquid = 0.4985E+02 kg liquid = 0.8981E+00 Moles total = 0.4985E+02 kg total = 0.8980E+00 Activity = 1.0000 Stoichiometric ionic strength = .1138061E-01 Osmotic coef. = 0.9668 True ionic strength = .2006327E-01 Chg. balance for total moles = -.5508E-08 Max. difference allowed = 0.1425E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.89515E-10 -10.0481 0.75205E-10 -10.1238 0.84014E+00 -0.0757 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.15800E-03 -3.8013 0.13194E-03 -3.8796 0.83508E+00 -0.0783 4 SO4-- 0.13051E-09 -9.8844 0.67734E-10 -10.1692 0.51900E+00 -0.2848 5 HCO3- 0.23146E-04 -4.6355 0.19357E-04 -4.7132 0.83630E+00 -0.0776 6 HS- 0.49765E-04 -4.3031 0.41564E-04 -4.3813 0.83520E+00 -0.0782 7 Al+++ 0.98642E-29 -29.0059 0.22759E-29 -29.6428 0.23072E+00 -0.6369 8 H4SiO4 0.70484E-03 -3.1519 0.70484E-03 -3.1519 0.10000E+01 0.0000 9 Ca++ 0.11650E-06 -6.9337 0.60020E-07 -7.2217 0.51519E+00 -0.2880 10 Mg++ 0.21164E-10 -10.6744 0.10853E-10 -10.9644 0.51283E+00 -0.2900 11 Fe++ 0.45124E-13 -13.3456 0.23166E-13 -13.6351 0.51339E+00 -0.2896 12 K+ 0.15652E-03 -3.8054 0.13092E-03 -3.8830 0.83650E+00 -0.0775 13 Na+ 0.19863E-01 -1.7020 0.16584E-01 -1.7803 0.83492E+00 -0.0784 14 Mn++ 0.19035E-10 -10.7204 0.97804E-11 -11.0096 0.51382E+00 -0.2892 15 F- 0.46172E-06 -6.3356 0.38478E-06 -6.4148 0.83335E+00 -0.0792 16 HPO4-- 0.45328E-07 -7.3436 0.23529E-07 -7.6284 0.51908E+00 -0.2848 18 HSiO3- 0.10480E-01 -1.9797 0.87513E-02 -2.0579 0.83508E+00 -0.0783 19 Ca(HSiO3)+ 0.14297E-07 -7.8448 0.11962E-07 -7.9222 0.83668E+00 -0.0774 20 Mg(HSiO3)+ 0.32175E-11 -11.4925 0.26920E-11 -11.5699 0.83668E+00 -0.0774 21 NaHSiO3,aq 0.23473E-02 -2.6294 0.23473E-02 -2.6294 0.10000E+01 0.0000 22 AlO+ 0.65430E-16 -16.1842 0.54744E-16 -16.2617 0.83668E+00 -0.0774 24 HAlO2,aq 0.14497E-09 -9.8387 0.14497E-09 -9.8387 0.10000E+01 0.0000 25 AlO2- 0.51189E-05 -5.2908 0.42669E-05 -5.3699 0.83356E+00 -0.0791 26 CH4,aq 0.11578E-04 -4.9364 0.11538E-04 -4.9379 0.99653E+00 -0.0015 27 C2H6,aq 0.63061E-14 -14.2002 0.62842E-14 -14.2017 0.99653E+00 -0.0015 31 CO,aq 0.28299E-15 -15.5482 0.28299E-15 -15.5482 0.10000E+01 0.0000 32 CO2,aq 0.31214E-08 -8.5057 0.31105E-08 -8.5072 0.99653E+00 -0.0015 33 CO3-2 0.43409E-04 -4.3624 0.22482E-04 -4.6482 0.51790E+00 -0.2858 34 CaCO3,aq 0.16919E-07 -7.7716 0.16919E-07 -7.7716 0.10000E+01 0.0000 35 Ca(HCO3)+ 0.35445E-10 -10.4505 0.29656E-10 -10.5279 0.83668E+00 -0.0774 36 CaCl+ 0.15317E-10 -10.8148 0.12815E-10 -10.8923 0.83668E+00 -0.0774 37 CaCl2,aq 0.40172E-15 -15.3961 0.40172E-15 -15.3961 0.10000E+01 0.0000 38 CaF+ 0.40299E-12 -12.3947 0.33718E-12 -12.4721 0.83668E+00 -0.0774 39 CaOH+ 0.67982E-07 -7.1676 0.56879E-07 -7.2451 0.83668E+00 -0.0774 40 CaSO4,aq 0.12909E-14 -14.8891 0.12909E-14 -14.8891 0.10000E+01 0.0000 41 HCl,aq 0.18183E-14 -14.7403 0.18183E-14 -14.7403 0.10000E+01 0.0000 45 HF,aq 0.19809E-12 -12.7031 0.19809E-12 -12.7031 0.10000E+01 0.0000 46 HF2- 0.30817E-19 -19.5112 0.25735E-19 -19.5895 0.83508E+00 -0.0783 48 FeCl+ 0.57824E-17 -17.2379 0.48380E-17 -17.3153 0.83668E+00 -0.0774 51 FeF+ 0.54443E-18 -18.2641 0.45551E-18 -18.3415 0.83668E+00 -0.0774 53 FeO,aq 0.15919E-09 -9.7981 0.15919E-09 -9.7981 0.10000E+01 0.0000 54 FeOH+ 0.11984E-10 -10.9214 0.10027E-10 -10.9988 0.83668E+00 -0.0774 55 HFeO2- 0.26523E-07 -7.5764 0.22148E-07 -7.6547 0.83508E+00 -0.0783 56 FeO+ 0.15021E-16 -16.8233 0.12568E-16 -16.9008 0.83668E+00 -0.0774 58 FeO2- 0.54448E-09 -9.2640 0.45468E-09 -9.3423 0.83508E+00 -0.0783 59 HFeO2,aq 0.43490E-11 -11.3616 0.43490E-11 -11.3616 0.10000E+01 0.0000 60 H2,aq 0.36342E-05 -5.4396 0.36216E-05 -5.4411 0.99653E+00 -0.0015 61 KCl,aq 0.31308E-09 -9.5043 0.31308E-09 -9.5043 0.10000E+01 0.0000 63 KOH,aq 0.74346E-06 -6.1287 0.74346E-06 -6.1287 0.10000E+01 0.0000 64 KSO4- 0.16479E-12 -12.7831 0.13761E-12 -12.8614 0.83508E+00 -0.0783 65 MgCO3,aq 0.76689E-12 -12.1153 0.76689E-12 -12.1153 0.10000E+01 0.0000 66 Mg(HCO3)+ 0.65493E-14 -14.1838 0.54796E-14 -14.2612 0.83668E+00 -0.0774 67 MgCl+ 0.25104E-14 -14.6003 0.21004E-14 -14.6777 0.83668E+00 -0.0774 68 MgF+ 0.26995E-15 -15.5687 0.22586E-15 -15.6462 0.83668E+00 -0.0774 69 MgOH+ 0.68024E-10 -10.1673 0.56914E-10 -10.2448 0.83668E+00 -0.0774 71 MnF+ 0.75761E-16 -16.1206 0.63387E-16 -16.1980 0.83668E+00 -0.0774 72 MnO,aq 0.17908E-08 -8.7469 0.17908E-08 -8.7469 0.10000E+01 0.0000 73 MnOH+ 0.47002E-09 -9.3279 0.39326E-09 -9.4053 0.83668E+00 -0.0774 74 MnO2-2 0.20290E-10 -10.6927 0.10508E-10 -10.9785 0.51790E+00 -0.2858 75 HMnO2- 0.20733E-09 -9.6833 0.17314E-09 -9.7616 0.83508E+00 -0.0783 78 MnCl+ 0.94976E-14 -14.0224 0.79464E-14 -14.0998 0.83668E+00 -0.0774 79 MnSO4,aq 0.19125E-18 -18.7184 0.19125E-18 -18.7184 0.10000E+01 0.0000 80 NaCl,aq 0.72514E-06 -6.1396 0.72514E-06 -6.1396 0.10000E+01 0.0000 81 NaF,aq 0.14939E-08 -8.8257 0.14939E-08 -8.8257 0.10000E+01 0.0000 82 NaOH,aq 0.94745E-04 -4.0234 0.94745E-04 -4.0234 0.10000E+01 0.0000 84 OH- 0.92166E-02 -2.0354 0.76827E-02 -2.1145 0.83356E+00 -0.0791 89 HPO3-2 0.51273E-15 -15.2901 0.26555E-15 -15.5759 0.51790E+00 -0.2858 91 H2PO3- 0.47956E-19 -19.3192 0.40047E-19 -19.3974 0.83508E+00 -0.0783 92 H3PO4,aq 0.93070E-18 -18.0312 0.93070E-18 -18.0312 0.10000E+01 0.0000 93 H2PO4- 0.39051E-10 -10.4084 0.32642E-10 -10.4862 0.83587E+00 -0.0779 94 PO4-3 0.10533E-08 -8.9775 0.25526E-09 -9.5930 0.24235E+00 -0.6156 98 HP2O7-3 0.96045E-18 -18.0175 0.22182E-18 -18.6540 0.23095E+00 -0.6365 99 P2O7-4 0.91596E-17 -17.0381 0.70463E-18 -18.1520 0.76928E-01 -1.1139 100 H2S,aq 0.96943E-08 -8.0135 0.96607E-08 -8.0150 0.99653E+00 -0.0015 101 S2-2 0.20409E-13 -13.6902 0.10570E-13 -13.9759 0.51790E+00 -0.2858 107 SO3-2 0.60671E-16 -16.2170 0.31877E-16 -16.4965 0.52540E+00 -0.2795 108 HSO3- 0.17975E-18 -18.7453 0.15010E-18 -18.8236 0.83508E+00 -0.0783 109 HSO4- 0.58616E-17 -17.2320 0.49091E-17 -17.3090 0.83749E+00 -0.0770 111 S2O3-2 0.14842E-19 -19.8285 0.76866E-20 -20.1143 0.51790E+00 -0.2858 Charge balance for all species = -.6133E-08 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.8951527E-10 -.2220402E-01 -.2234137E+02 0.0000 2 H2O 0.1000000E+01 0.5550476E+02 0.9981945E+06 0.0000 3 Cl- 0.1579988E-03 0.1587243E-03 0.5617457E+01 6.2441 4 SO4-- 0.1305067E-09 -.1248661E-04 -.1197396E+01 10.0783 5 HCO3- 0.2314573E-04 0.7815331E-04 0.4760397E+01 5.4106 6 HS- 0.4976532E-04 0.6226175E-04 0.2055537E+01 5.7425 7 Al+++ 0.9864204E-29 0.5119040E-05 0.1378790E+00 0.7284 8 H4SiO4 0.7048424E-03 0.1353180E-01 0.1298350E+04 -3.1519 9 Ca++ 0.1165002E-06 0.2157492E-06 0.8631746E-02 13.0258 10 Mg++ 0.2116373E-10 0.9318144E-10 0.2261484E-05 9.2831 11 Fe++ 0.4512405E-13 0.2724267E-07 0.1518774E-02 6.6124 12 K+ 0.1565153E-03 0.1572591E-03 0.6138444E+01 6.2408 13 Na+ 0.1986286E-01 0.2230563E-01 0.5119094E+03 8.3434 14 Mn++ 0.1903491E-10 0.2507537E-08 0.1375193E-03 9.2379 15 F- 0.4617220E-06 0.4632165E-06 0.8784871E-02 3.7090 16 HPO4-- 0.4532752E-07 0.4641985E-07 0.4447577E-02 12.6191 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.1994148E-01 -.1994072E-01 -.7548865E-06 0.0000000E+00 2 H2O 0.4984706E+02 0.4984706E+02 -.7107879E-06 0.0000000E+00 3 Cl- 0.1425452E-03 0.1425452E-03 0.0000000E+00 0.0000000E+00 4 SO4-- -.1121281E-04 -.1121383E-04 0.1015812E-08 0.0000000E+00 5 HCO3- 0.7018700E-04 0.7018700E-04 0.0000000E+00 0.0000000E+00 6 HS- 0.5591428E-04 0.5591530E-04 -.1015812E-08 0.0000000E+00 7 Al+++ 0.4775352E-05 0.4597247E-05 0.1781054E-06 0.0000000E+00 8 H4SiO4 0.1215302E-01 0.1215248E-01 0.5443695E-06 0.0000000E+00 9 Ca++ 0.2080835E-06 0.1937574E-06 0.1432605E-07 0.0000000E+00 10 Mg++ 0.8368328E-10 0.8368328E-10 0.0000000E+00 0.0000000E+00 11 Fe++ 0.3259227E-07 0.2446578E-07 0.8126494E-08 0.0000000E+00 12 K+ 0.1412294E-03 0.1412294E-03 0.0000000E+00 0.0000000E+00 13 Na+ 0.2003215E-01 0.2003197E-01 0.1766812E-06 0.0000000E+00 14 Mn++ 0.2251939E-08 0.2251939E-08 0.0000000E+00 0.0000000E+00 15 F- 0.4160000E-06 0.4160000E-06 0.0000000E+00 0.0000000E+00 16 HPO4-- 0.4168819E-07 0.4168819E-07 0.0000000E+00 0.0000000E+00 Chg. balance for solid moles: -.2647E-22 Mass of aqueous solution: 0.899634E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 0.0007900 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 0.1767E-06 -6.753 0.4633E-04 -4.334 95.10 0.1778E-04 andradite 0.4063E-08 -8.391 0.2065E-05 -5.685 4.239 0.5365E-06 grossular 0.7121E-09 -9.147 0.3208E-06 -6.494 0.6585 0.8925E-07 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8509E+00 0.8509E+00 1.0000 -0.070 grossular 0.1491E+00 0.1491E+00 1.0000 -0.826 Solid products produced: Mass = 0.000049 g Volume = 0.000018 cm3 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.0007900 moles log = -3.1024 Original solution: 1000.0103000 g Original solution / Rock added: 1265835.82 (Water/Rock Ratio), log = 6.1024 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0421 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9793E+00 0.9857 0.1006E+01 0.1021E+01 CO2,gas 0.3172E-06 1.0069 0.3328E-06 0.3305E-06 CH4,gas 0.1610E-01 1.0124 0.1698E-01 0.1678E-01 H2,gas 0.4560E-02 1.0006 0.4755E-02 0.4752E-02 H2S,gas 0.2559E-06 0.9960 0.2656E-06 0.2666E-06 S2,gas 0.1124E-27 1.0000 0.1171E-27 0.1171E-27 CO,gas 0.4047E-12 1.0000 0.4217E-12 0.4217E-12 SO3,gas 0.1390E-45 1.0000 0.1448E-45 0.1448E-45 SO2,gas 0.2571E-25 1.0000 0.2679E-25 0.2679E-25 HF,gas 0.4667E-15 1.0000 0.4864E-15 0.4864E-15 HCl,gas 0.3079E-17 1.0000 0.3208E-17 0.3208E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 17 albite -0.38 -0.38 0.00 0.000 -0.94784E-12 23 andradite 39.01 39.01 0.00 0.000 0.00000E+00 24 grossular 32.73 32.73 0.00 0.000 0.00000E+00 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -14.84 -8.18 -2.726 0.13962E+05 -6.478 3 CH4,gas 4.54 1.07 -3.47 -0.867 0.59231E+04 -1.770 4 H2,gas 8.00 3.98 -4.02 -2.298 0.68672E+04 -2.323 5 H2S,gas -6.23 -14.51 -8.27 -4.137 0.14129E+05 -6.576 6 S2,gas -7.34 -36.97 -29.63 -4.559 0.50593E+05 -27.931 7 CO,gas 3.21 -10.86 -14.07 -4.330 0.24031E+05 -12.375 8 SO3,gas 17.12 -30.42 -47.54 -11.885 0.81170E+05 -45.839 9 SO2,gas 0.83 -26.44 -27.27 -7.272 0.46564E+05 -25.572 10 HF,gas 0.47 -16.54 -17.01 -8.506 0.29047E+05 -15.313 11 HCl,gas 5.19 -14.00 -19.19 -9.596 0.32771E+05 -17.494 12 acmite 7.71 6.66 -1.05 -0.109 0.17872E+04 16 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 20 spessartine 24.46 19.71 -4.74 -0.237 0.80979E+04 21 analcite 3.32 2.77 -0.55 -0.062 0.94563E+03 27 annite 20.12 17.35 -2.77 -0.154 0.47346E+04 28 phlogopite 27.06 25.36 -1.70 -0.095 0.29060E+04 30 anorthite 12.71 8.18 -4.53 -0.349 0.77374E+04 33 apatite-OH -18.15 -18.50 -0.35 -0.027 0.58950E+03 34 apatite-F -34.30 -35.04 -0.74 -0.061 0.12572E+04 38 aragonite 0.97 -1.81 -2.78 -0.926 0.47427E+04 39 brucite 12.57 9.28 -3.29 -0.657 0.56099E+04 40 calcite 0.81 -1.81 -2.62 -0.874 0.44785E+04 41 carnegieite-low 9.02 5.92 -3.10 -0.443 0.52989E+04 42 carnegieite-high 10.09 5.92 -4.17 -0.596 0.71259E+04 43 carpholite-Mg 8.58 4.44 -4.15 -0.276 0.70792E+04 44 carpholite-Fe 6.71 1.77 -4.95 -0.330 0.84473E+04 45 celadonite 5.34 3.64 -1.70 -0.100 0.28975E+04 46 celadonite-Fe 3.88 0.97 -2.90 -0.171 0.49561E+04 47 chrysotile 23.89 21.55 -2.35 -0.196 0.40074E+04 49 clinochlore 39.07 38.42 -0.65 -0.020 0.11151E+04 50 daphnite 28.97 25.06 -3.90 -0.122 0.66631E+04 52 chlorite-Al-free 47.17 43.09 -4.08 -0.170 0.69700E+04 54 chloritoid-Fe 9.17 4.92 -4.26 -0.284 0.72676E+04 55 chloritoid-Mn 11.40 7.54 -3.86 -0.257 0.65879E+04 57 coesite -2.38 -3.15 -0.78 -0.259 0.13247E+04 64 cristobalite -2.56 -3.15 -0.59 -0.197 0.10101E+04 66 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71235E+04 68 diaspore 2.87 0.73 -2.15 -0.358 0.36630E+04 69 diamond -3.10 -6.88 -3.78 -1.080 0.64520E+04 70 diopside 16.18 16.01 -0.18 -0.018 0.30103E+03 71 hedenbergite 14.21 13.33 -0.87 -0.087 0.14922E+04 76 clinoenstatite 17.17 12.26 -4.90 -0.490 0.83734E+04 78 epidote 24.67 22.68 -1.99 -0.097 0.34044E+04 79 clinozoisite 22.81 18.78 -4.02 -0.183 0.68724E+04 80 epidote-Fe 29.84 26.57 -3.27 -0.170 0.55829E+04 81 fayalite 14.05 10.07 -3.97 -0.568 0.67836E+04 82 ferrosilite 11.15 6.92 -4.23 -0.423 0.72201E+04 86 gibbsite 4.08 0.73 -3.35 -0.479 0.57216E+04 87 glaucophane 22.97 20.78 -2.20 -0.059 0.37516E+04 88 glaucophane-Fe 17.28 12.77 -4.51 -0.122 0.77012E+04 89 graphite -3.55 -6.88 -3.33 -0.953 0.56943E+04 90 greenalite 16.14 13.53 -2.61 -0.217 0.44501E+04 93 hematite 12.57 9.25 -3.32 -0.402 0.56677E+04 94 heulandite -5.83 -7.58 -1.75 -0.080 0.29940E+04 98 jadeite 4.22 2.77 -1.45 -0.145 0.24711E+04 100 kalsilite 7.58 3.82 -3.77 -0.538 0.64314E+04 101 kaolinite -1.33 -4.85 -3.51 -0.319 0.60004E+04 104 laumontite 2.88 1.87 -1.01 -0.067 0.17218E+04 105 lawsonite 9.62 8.18 -1.44 -0.096 0.24541E+04 106 leucite 4.12 0.67 -3.45 -0.345 0.58967E+04 108 lizardite 23.24 21.55 -1.70 -0.142 0.29001E+04 110 magnetite 20.09 15.86 -4.23 -0.345 0.72196E+04 111 minnesotaite 10.39 7.23 -3.16 -0.186 0.53933E+04 115 manganosite 14.06 9.24 -4.82 -1.205 0.82304E+04 119 microcline -2.49 -2.49 0.00 0.000 0.66852E-01 123 muscovite 2.58 -1.03 -3.61 -0.212 0.61676E+04 124 paragonite 4.24 1.07 -3.17 -0.186 0.54067E+04 125 nepheline 8.34 5.92 -2.42 -0.346 0.41312E+04 137 phlogopite-Na 29.65 27.47 -2.18 -0.121 0.37247E+04 139 prehnite 19.37 18.05 -1.32 -0.078 0.22525E+04 140 prehnite-Fe 22.50 21.95 -0.55 -0.033 0.93940E+03 141 pumpellyite-Fe 46.27 43.45 -2.82 -0.063 0.48206E+04 142 pumpellyite-Mg 48.99 46.12 -2.88 -0.064 0.49141E+04 146 pyrrhotite -4.26 -7.89 -3.63 -1.211 0.62021E+04 147 pyrrhotiteFe0.875 -6.02 -9.21 -3.20 -1.175 0.54563E+04 148 pyroxmangite 7.40 6.09 -1.31 -0.263 0.22414E+04 149 pyrophyllite -6.18 -11.15 -4.98 -0.311 0.84947E+04 150 quartz -2.99 -3.15 -0.16 -0.054 0.27742E+03 154 rhodochrosite -0.98 -5.60 -4.62 -1.541 0.78932E+04 155 rhodonite 7.45 6.09 -1.36 -0.272 0.23217E+04 156 sanidine -1.28 -2.49 -1.21 -0.093 0.20678E+04 166 stilbite -7.52 -7.58 -0.06 -0.003 0.10019E+03 167 stilpnomelane-Fe 13.02 12.42 -0.59 -0.018 0.10129E+04 168 stilpnomelane-Mg 27.44 25.78 -1.66 -0.050 0.28414E+04 174 talc 16.49 15.24 -1.25 -0.073 0.21335E+04 177 tephroite 18.09 15.32 -2.76 -0.395 0.47160E+04 181 tridymite -2.63 -3.15 -0.53 -0.175 0.89740E+03 182 tremolite 47.87 47.25 -0.62 -0.017 0.10545E+04 183 ferroactinolite 38.45 33.90 -4.55 -0.123 0.77762E+04 184 troilite-low -4.41 -7.89 -3.48 -1.161 0.59450E+04 190 wairakite 3.95 1.87 -2.08 -0.122 0.35438E+04 191 walstromite 11.51 9.87 -1.64 -0.327 0.27923E+04 192 wollastonite 10.46 9.87 -0.59 -0.117 0.10027E+04 193 pseudo-wollastonite 11.00 9.87 -1.13 -0.225 0.19226E+04 194 zoisite 22.85 18.78 -4.07 -0.185 0.69465E+04 195 akaganeite 7.75 4.62 -3.13 -0.677 0.53464E+04 202 chalcedony -2.80 -3.15 -0.35 -0.116 0.59672E+03 204 montmorillonite-Ca -2.29 -6.18 -3.89 -0.241 0.66383E+04 205 montmorillonite-K -2.24 -6.27 -4.03 -0.247 0.68838E+04 206 montmorillonite-Mg -2.48 -6.80 -4.32 -0.267 0.73698E+04 207 montmorillonite-Na -2.04 -5.57 -3.54 -0.217 0.60387E+04 208 nontronite-Ca 3.21 0.07 -3.15 -0.204 0.53710E+04 209 nontronite-H 2.53 -2.08 -4.61 -0.309 0.78766E+04 210 nontronite-K 3.34 -0.02 -3.36 -0.216 0.57398E+04 211 nontronite-Mg 3.07 -0.55 -3.62 -0.235 0.61866E+04 212 nontronite-Na 3.52 0.67 -2.85 -0.183 0.48606E+04 228 tobermorite 9.82 7.70 -2.12 -0.580 0.36275E+04 234 alabandite -0.98 -5.27 -4.29 -1.430 0.73239E+04 237 boehmite 4.41 0.73 -3.68 -0.613 0.62799E+04 239 ferrous-oxide 9.81 6.61 -3.20 -0.800 0.54626E+04 245 silica-amorphous -2.09 -3.15 -1.06 -0.354 0.18109E+04 247 an20ab80 2.02 1.33 -0.69 -0.053 0.11766E+04 248 an25ab75 2.65 1.76 -0.89 -0.068 0.15178E+04 249 an30ab70 3.28 2.18 -1.09 -0.084 0.18685E+04 250 tr.625ac.25prg.125 45.16 44.86 -0.31 -0.008 0.52548E+03 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 0.0000200 MOLES Current total amount of reactant added: 0.0007900 MOLES New total amount of reactant added: 0.0008100 MOLES Mixing fraction reached given limit of 0.8000E-03 TOTMIX = 0.8100E-03 Execution stopped.