File SKIP_SPECIES.TXT lists species and minerals omitted from the calculations due to given T, P, option switches, or suppression in CHIMRUN, or are suppressed in the SOLTHERM database. It also lists minerals for which density is not specified in SOLTHERM. This is an extended P(to 5 kB), T(to 600 C) run (CON_FLAG = 1). methanol,aq is suppressed in SOLTHERM data file. methanol,aq is suppressed in SOLTHERM data file. CuCl4-3 is suppressed in SOLTHERM data file. H2BO3- is suppressed in SOLTHERM data file. UO2CO3,aq is suppressed in SOLTHERM data file. UO2SO4,aq is suppressed in SOLTHERM data file. UO2Cl2,aq is suppressed in SOLTHERM data file. UO2F2,aq is suppressed in SOLTHERM data file. PO4-3 is suppressed in SOLTHERM data file. H2PO4- is suppressed in SOLTHERM data file. H3PO4 is suppressed in SOLTHERM data file. O2,gas is suppressed in THIS RUN. O2,gas is suppressed in THIS RUN. amesite is suppressed in SOLTHERM data file. antigorite is suppressed in SOLTHERM data file. goethite is suppressed in THIS RUN. goethite is suppressed in THIS RUN. riebeckite is suppressed in THIS RUN. riebeckite is suppressed in THIS RUN. sapphirine-Fe(221) is suppressed in SOLTHERM data file. sapphirine(221) is suppressed in SOLTHERM data file. talc-prl is suppressed in SOLTHERM data file. PrO1.833(s) is suppressed in SOLTHERM data file. niter-NH4 is suppressed in SOLTHERM data file. FMQ_HS-1 is suppressed in THIS RUN. kf-ab-equil is suppressed in THIS RUN. ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Species No. Charge Tot.moles Trial molality Gamma Mixing solution H+ 1 1. -0.19941E-01 0.89515E-10 0.8401 0.00000000E+00 H2O 2 0. 0.49847E+02 0.10000E+01 1.0000 0.00000000E+00 Cl- 3 -1. 0.14255E-03 0.15800E-03 0.8351 0.00000000E+00 SO4-- 4 -2. -0.11213E-04 0.13051E-09 0.5190 0.00000000E+00 HCO3- 5 -1. 0.70187E-04 0.23146E-04 0.8363 0.00000000E+00 HS- 6 -1. 0.55914E-04 0.49765E-04 0.8352 0.00000000E+00 Al+++ 7 3. 0.47754E-05 0.98642E-29 0.2307 0.00000000E+00 H4SiO4 8 0. 0.12153E-01 0.70484E-03 1.0000 0.00000000E+00 Ca++ 9 2. 0.20808E-06 0.11650E-06 0.5152 0.00000000E+00 Mg++ 10 2. 0.83683E-10 0.21164E-10 0.5128 0.00000000E+00 Fe++ 11 2. 0.32592E-07 0.45124E-13 0.5134 0.00000000E+00 K+ 12 1. 0.14123E-03 0.15652E-03 0.8365 0.00000000E+00 Na+ 13 1. 0.20032E-01 0.19863E-01 0.8349 0.00000000E+00 Mn++ 14 2. 0.22519E-08 0.19035E-10 0.5138 0.00000000E+00 F- 15 -1. 0.41600E-06 0.46172E-06 0.8334 0.00000000E+00 HPO4-- 16 -2. 0.41688E-07 0.45328E-07 0.5191 0.00000000E+00 Chg. balance for total moles = -.5508E-08 Max. difference allowed = 0.1425E-07 The following parameters were given: ERPC = 0.1000E-11 pH = 0.0000 PFLUID = 50.0000 SLIM = 0.200000E-02 TEMP = 100.0000 SINC = 0.4000E-04 TEMPC = 0.0000 TOTMIX = 0.790000E-03 ENTH = 0.0000 SENTH = 0.0000 DENTH = 0.0000 TOTWAT = 90.0000 SOLMIN = 0.0000E+00 RM = 0.0000 AQGRM = 1000.0103 SUPRNT = 0.1000E-19 VBOX-1 = 400.9996 RHOFRS = 0.0000 RHOROC = 2.5000 The following options were selected: CONFLG = 1 C = 3 IFRAC = 0 IPUNCH = 2 NLOOP = 400 ISTEP = 2 LIMSOL = 1 LOOC = 0 IENTH = 0 ITREF = 0 IDEAL = 0 IPSAT = 1 INCREM = 0 INCP = 0 MINSOL = 3 NEUT = 0 AWAT = 0 CHGF = 0 Of the derived species, only those with molality > 0.10E-19 will appear in the output Species No. Charge Log K(diss) Species No. Charge Log K(diss) SiF6-2 17 -2. -24.5019 Mn+3 70 3. 19.1453 HSiO3- 18 -1. 9.0298 MnF+ 71 1. -1.2264 Ca(HSiO3)+ 19 1. 7.6723 MnO,aq 72 0. 17.9848 Mg(HSiO3)+ 20 1. 7.5773 MnOH+ 73 1. 8.5194 NaHSiO3,aq 21 0. 7.8210 MnO2-2 74 -2. 40.4638 AlO+ 22 1. 6.8663 HMnO2- 75 -1. 29.1232 AlOH+2 23 2. 3.1691 MnO4- 76 -1. 83.3111 HAlO2,aq 24 0. 10.5671 MnO4-2 77 -2. 81.3005 AlO2- 25 -1. 16.2221 MnCl+ 78 1. -0.7894 CH4,aq 26 0. 6.0126 MnSO4,aq 79 0. -2.4604 C2H6,aq 27 0. 12.3733 NaCl,aq 80 0. 0.4796 C3H8,aq 28 0. 17.3707 NaF,aq 81 0. 0.6306 C4H10,aq 29 0. 22.3757 NaOH,aq 82 0. 12.3669 ethanol,aq 30 0. 15.3258 O2,aq 83 0. 53.5502 CO,aq 31 0. 4.6892 OH- 84 -1. 12.2382 CO2,aq 32 0. -6.3298 HO2- 85 -1. 50.8010 CO3-2 33 -2. 10.0588 H2O2,aq 86 0. 40.0166 CaCO3,aq 34 0. 5.9605 H3PO2,aq 87 0. 24.3066 Ca(HCO3)+ 35 1. -1.4070 H2PO2- 88 -1. 26.5366 CaCl+ 36 1. -0.2091 HPO3-2 89 -2. 11.9254 CaCl2,aq 37 0. 0.4151 H3PO3,aq 90 0. 3.5792 CaF+ 38 1. -1.1644 H2PO3- 91 -1. 5.6232 CaOH+ 39 1. 10.1471 H3PO4,aq 92 0. -9.8447 CaSO4,aq 40 0. -2.5018 H2PO4- 93 -1. -7.2659 HCl,aq 41 0. 0.7370 PO4-3 94 -3. 12.0884 HClO,aq 42 0. 32.4260 H4P2O7,aq 95 0. -17.8095 ClO- 43 -1. 39.6530 H3P2O7- 96 -1. -15.9156 HClO2,aq 44 0. 70.1812 H2P2O7-2 97 -2. -13.4262 HF,aq 45 0. -3.8354 HP2O7-3 98 -3. -6.7266 HF2- 46 -1. -3.3639 P2O7-4 99 -4. 2.8952 Fe+3 47 3. 8.3809 H2S,aq 100 0. -6.4900 FeCl+ 48 1. -0.1994 S2-2 101 -2. 1.2355 FeCl2,aq 49 0. 4.3001 S3-2 102 -2. -8.8031 FeCl+2 50 2. 6.5269 S3- 103 -1. -16.3389 FeF+ 51 1. -1.7084 S4-2 104 -2. -18.6615 FeF+2 52 2. 1.4309 S5-2 105 -2. -28.3439 FeO,aq 53 0. 16.4104 SO2,aq 106 0. -0.2309 FeOH+ 54 1. 7.4874 SO3-2 107 -2. 10.3052 HFeO2- 55 -1. 24.3908 HSO3- 108 -1. 2.5086 FeO+ 56 1. 11.4004 HSO4- 109 -1. -2.9839 FeOH+2 57 2. 9.1194 HSO5- 110 -1. 38.8366 FeO2- 58 -1. 24.0895 S2O3-2 111 -2. -4.5600 HFeO2,aq 59 0. 15.9850 HS2O3- 112 -1. -6.8123 H2,aq 60 0. 9.4190 H2S2O3,aq 113 0. -8.0173 KCl,aq 61 0. 1.7417 S2O4-2 114 -2. 10.5541 KHSO4,aq 62 0. -0.4514 HS2O4- 115 -1. 7.6551 KOH,aq 63 0. 12.3695 H2S2O4,aq 116 0. 6.6259 KSO4- 64 -1. -1.1908 S2O5-2 117 -2. 10.0741 MgCO3,aq 65 0. 6.5614 S2O6-2 118 -2. 11.5521 Mg(HCO3)+ 66 1. -1.4164 S2O8-2 119 -2. 42.0620 MgCl+ 67 1. -0.1664 S3O6-2 120 -2. 3.7866 MgF+ 68 1. -1.7331 S4O6-2 121 -2. -17.8657 MgOH+ 69 1. 9.4041 S5O6-2 122 -2. -14.1333 For mixed gases (JSOLS=6), log K(hydrol) = log (K*P) Log K Trial Log K Trial Mineral No. hydrol Moles Mineral No. hydrol Moles H2O,gas 1 1.696 0.0000E+00 osumilite(1) 126 21.717 0.0000E+00 CO2,gas 2 -6.660 0.0000E+00 osumilite(2) 127 20.667 0.0000E+00 CH4,gas 3 4.544 0.0000E+00 osumilite-Fe 128 14.390 0.0000E+00 H2,gas 4 8.000 0.0000E+00 pargasite 129 65.092 0.0000E+00 H2S,gas 5 -6.230 0.0000E+00 periclase 130 16.138 0.0000E+00 S2,gas 6 -7.335 0.0000E+00 periclase-Fe 131 11.627 0.0000E+00 CO,gas 7 3.215 0.0000E+00 perovskite-Al 132 12.344 0.0000E+00 SO3,gas 8 17.121 0.0000E+00 perovskite-Ca 133 23.807 0.0000E+00 SO2,gas 9 0.832 0.0000E+00 perovskite-Fe 134 21.143 0.0000E+00 HF,gas 10 0.473 0.0000E+00 perovskite-Mg 135 23.119 0.0000E+00 HCl,gas 11 5.189 0.0000E+00 phase_A 136 80.189 0.0000E+00 acmite 12 7.710 0.0000E+00 phlogopite-Na 137 29.647 0.0000E+00 akermanite 13 36.442 0.0000E+00 piemontite(ordered) 138 33.776 0.0000E+00 akimotoite 14 16.591 0.0000E+00 prehnite 139 19.372 0.0000E+00 akimotoite-Fe 15 13.067 0.0000E+00 prehnite-Fe 140 22.498 0.0000E+00 albite-high 16 0.693 0.0000E+00 pumpellyite-Fe 141 46.269 0.0000E+00 albite 17 -0.384 0.1767E-06 pumpellyite-Mg 142 48.995 0.0000E+00 almandine 18 24.442 0.0000E+00 px-Mg-tschermaks 143 19.616 0.0000E+00 pyrope 19 37.248 0.0000E+00 px-Ca-tschermaks 144 18.610 0.0000E+00 spessartine 20 24.457 0.0000E+00 pyrite 145 -21.247 0.0000E+00 analcite 21 3.322 0.0000E+00 pyrrhotite 146 -4.260 0.0000E+00 andalusite 22 5.002 0.0000E+00 pyrrhotiteFe0.875 147 -6.017 0.0000E+00 andradite 23 39.009 0.4063E-08 pyroxmangite 148 7.399 0.0000E+00 grossular 24 32.731 0.7121E-09 pyrophyllite 149 -6.176 0.0000E+00 anhydrite 25 -5.317 0.0000E+00 quartz 150 -2.989 0.0000E+00 ankerite 26 -2.135 0.0000E+00 rankinite 151 40.713 0.0000E+00 annite 27 20.123 0.0000E+00 ringwoodite-Fe 152 15.456 0.0000E+00 phlogopite 28 27.065 0.0000E+00 ringwoodite-Mg 153 27.575 0.0000E+00 biotite-Mn 29 32.960 0.0000E+00 rhodochrosite 154 -0.976 0.0000E+00 anorthite 30 12.710 0.0000E+00 rhodonite 155 7.446 0.0000E+00 anthophyllite 31 51.852 0.0000E+00 sanidine 156 -1.275 0.0000E+00 anthophyllite-Fe 32 29.306 0.0000E+00 sapphirine(351) 157 78.899 0.0000E+00 apatite-OH 33 -18.153 0.0000E+00 siderite 158 -2.608 0.0000E+00 apatite-F 34 -34.301 0.0000E+00 sillimanite 159 5.262 0.0000E+00 apatite-OH-zs 35 -12.736 0.0000E+00 sodalite 160 49.976 0.0000E+00 apatite-F-zs 36 -27.774 0.0000E+00 spinel 161 20.870 0.0000E+00 apatite-Cl-zs 37 -16.674 0.0000E+00 spurrite 162 59.482 0.0000E+00 aragonite 38 0.967 0.0000E+00 staurolite-Fe 163 73.598 0.0000E+00 brucite 39 12.569 0.0000E+00 staurolite-Mg 164 89.802 0.0000E+00 calcite 40 0.812 0.0000E+00 staurolite-Mn 165 83.909 0.0000E+00 carnegieite-low 41 9.023 0.0000E+00 stilbite 166 -7.522 0.0000E+00 carnegieite-high 42 10.093 0.0000E+00 stilpnomelane-Fe 167 13.017 0.0000E+00 carpholite-Mg 43 8.582 0.0000E+00 stilpnomelane-Mg 168 27.441 0.0000E+00 carpholite-Fe 44 6.713 0.0000E+00 stishovite 169 2.720 0.0000E+00 celadonite 45 5.342 0.0000E+00 sudoite-Fe 170 18.296 0.0000E+00 celadonite-Fe 46 3.877 0.0000E+00 sudoite 171 21.077 0.0000E+00 chrysotile 47 23.892 0.0000E+00 sulfur 172 -9.152 0.0000E+00 chondrodite 48 56.475 0.0000E+00 sylvite 173 1.338 0.0000E+00 clinochlore 49 39.070 0.0000E+00 talc 174 16.491 0.0000E+00 daphnite 50 28.965 0.0000E+00 talc-Fe 175 13.448 0.0000E+00 chlorite-Mn 51 46.869 0.0000E+00 talc-tschermaks 176 19.091 0.0000E+00 chlorite-Al-free 52 47.173 0.0000E+00 tephroite 177 18.086 0.0000E+00 chloritoid-Mg 53 13.198 0.0000E+00 tilleyite 178 41.377 0.0000E+00 chloritoid-Fe 54 9.174 0.0000E+00 titanite-CaSi 179 15.479 0.0000E+00 chloritoid-Mn 55 11.401 0.0000E+00 topaz-H 180 4.618 0.0000E+00 clinohumite 56 97.128 0.0000E+00 tridymite 181 -2.626 0.0000E+00 coesite 57 -2.376 0.0000E+00 tremolite 182 47.869 0.0000E+00 cordierite-H 58 23.715 0.0000E+00 ferroactinolite 183 38.452 0.0000E+00 cordierite 59 24.049 0.0000E+00 troilite-low 184 -4.411 0.0000E+00 cordierite-Fe 60 20.450 0.0000E+00 tschermakite 185 48.210 0.0000E+00 cordierite-Mn 61 25.066 0.0000E+00 vesuvianite 186 223.471 0.0000E+00 corundum 62 8.383 0.0000E+00 wadeite-Si 187 20.216 0.0000E+00 corundum-MgSi 63 18.891 0.0000E+00 wadsleyite-Fe 188 15.680 0.0000E+00 cristobalite 64 -2.560 0.0000E+00 wadsleyite-Mg 189 25.850 0.0000E+00 cummingtonite 65 52.099 0.0000E+00 wairakite 190 3.950 0.0000E+00 cymrite-K 66 1.685 0.0000E+00 walstromite 191 11.509 0.0000E+00 deerite 67 95.671 0.0000E+00 wollastonite 192 10.461 0.0000E+00 diaspore 68 2.874 0.0000E+00 pseudo-wollastonite 193 11.000 0.0000E+00 diamond 69 -3.102 0.0000E+00 zoisite 194 22.849 0.0000E+00 diopside 70 16.181 0.0000E+00 akaganeite 195 7.755 0.0000E+00 hedenbergite 71 14.208 0.0000E+00 beidellite-Ca 196 -1.646 0.0000E+00 dolomite,ordered 72 0.546 0.0000E+00 beidellite-H 197 -2.326 0.0000E+00 eastonite 73 28.489 0.0000E+00 beidellite-K 198 -1.520 0.0000E+00 enstatite 74 17.265 0.0000E+00 beidellite-Mg 199 -1.790 0.0000E+00 clinoenstatite-HiP 75 18.354 0.0000E+00 beidellite-Na 200 -1.342 0.0000E+00 clinoenstatite 76 17.166 0.0000E+00 calcium 201 84.026 0.0000E+00 protoenstatite 77 17.824 0.0000E+00 chalcedony 202 -2.802 0.0000E+00 epidote 78 24.670 0.0000E+00 dawsonite 203 1.682 0.0000E+00 clinozoisite 79 22.806 0.0000E+00 montmorillonite-Ca 204 -2.291 0.0000E+00 epidote-Fe 80 29.841 0.0000E+00 montmorillonite-K 205 -2.237 0.0000E+00 fayalite 81 14.046 0.0000E+00 montmorillonite-Mg 206 -2.480 0.0000E+00 ferrosilite 82 11.149 0.0000E+00 montmorillonite-Na 207 -2.038 0.0000E+00 forsterite 83 21.016 0.0000E+00 nontronite-Ca 208 3.215 0.0000E+00 gedrite 84 50.522 0.0000E+00 nontronite-H 209 2.533 0.0000E+00 gehlenite 85 36.628 0.0000E+00 nontronite-K 210 3.341 0.0000E+00 gibbsite 86 4.079 0.0000E+00 nontronite-Mg 211 3.075 0.0000E+00 glaucophane 87 22.975 0.0000E+00 nontronite-Na 212 3.520 0.0000E+00 glaucophane-Fe 88 17.276 0.0000E+00 sepiolite 213 24.118 0.0000E+00 graphite 89 -3.546 0.0000E+00 topaz 214 -16.546 0.0000E+00 greenalite 90 16.140 0.0000E+00 alite 215 57.999 0.0000E+00 grunerite 91 31.215 0.0000E+00 belite 216 30.433 0.0000E+00 halite 92 1.575 0.0000E+00 ettringite 217 43.232 0.0000E+00 hematite 93 12.566 0.0000E+00 gypsum 218 -4.955 0.0000E+00 heulandite 94 -5.827 0.0000E+00 hemicarboaluminate 219 70.954 0.0000E+00 hercynite 95 17.279 0.0000E+00 hydrogarnet 220 60.662 0.0000E+00 hollandite 96 25.673 0.0000E+00 hydrogarnet-Si 221 50.586 0.0000E+00 iron 97 19.086 0.0000E+00 jennite 222 24.367 0.0000E+00 jadeite 98 4.215 0.0000E+00 monosulfoaluminate 223 53.400 0.0000E+00 julgoldite 99 70.427 0.0000E+00 monocarboaluminate 224 61.898 0.0000E+00 kalsilite 100 7.584 0.0000E+00 portlandite 225 18.272 0.0000E+00 kaolinite 101 -1.333 0.0000E+00 stratlingite 226 36.502 0.0000E+00 kyanite 102 4.876 0.0000E+00 tricarboaluminate 227 70.370 0.0000E+00 larnite-bredigite 103 30.686 0.0000E+00 tobermorite 228 9.823 0.0000E+00 laumontite 104 2.883 0.0000E+00 C4AH13 229 81.816 0.0000E+00 lawsonite 105 9.616 0.0000E+00 C2AH8 230 45.203 0.0000E+00 leucite 106 4.119 0.0000E+00 C3A 231 86.953 0.0000E+00 lime 107 25.998 0.0000E+00 C4AF 232 117.416 0.0000E+00 lizardite 108 23.244 0.0000E+00 CAH10 233 28.335 0.0000E+00 magnesite 109 0.691 0.0000E+00 alabandite 234 -0.978 0.0000E+00 magnetite 110 20.087 0.0000E+00 alunite 235 -10.435 0.0000E+00 minnesotaite 111 10.388 0.0000E+00 artinite 236 15.121 0.0000E+00 minnesotaite-Mg 112 20.602 0.0000E+00 boehmite 237 4.406 0.0000E+00 magnesioferrite 113 26.212 0.0000E+00 dolomite,disordered 238 1.247 0.0000E+00 majorite 114 53.251 0.0000E+00 ferrous-oxide 239 9.812 0.0000E+00 manganosite 115 14.058 0.0000E+00 fluorite 240 -9.931 0.0000E+00 margarite 116 17.324 0.0000E+00 huntite 241 3.770 0.0000E+00 meionite 117 44.874 0.0000E+00 hydromagnesite 242 19.995 0.0000E+00 merwinite 118 55.930 0.0000E+00 nesquehonite 243 4.723 0.0000E+00 microcline 119 -2.486 0.0000E+00 potassium-oxide 244 69.038 0.0000E+00 monticellite 120 24.339 0.0000E+00 silica-amorphous 245 -2.091 0.0000E+00 mullite-Al 121 363.148 0.0000E+00 sodium-oxide 246 55.169 0.0000E+00 mullite-Si 122 7.264 0.0000E+00 an20ab80 247 2.018 0.0000E+00 muscovite 123 2.582 0.0000E+00 an25ab75 248 2.646 0.0000E+00 paragonite 124 4.239 0.0000E+00 an30ab70 249 3.279 0.0000E+00 nepheline 125 8.339 0.0000E+00 tr.625ac.25prg.125 250 45.165 0.0000E+00 Initial composition of reactant (mole%): H2O 88.87 HCl 0.5900 CO2 7.070 CO 0.1600 H2 1.540 S2 0.8000E-01 SO2 1.150 HF 0.4000E-01 H2S 1.120 0.000 Sum of wt% of reactants: 100.6200 Reactant consumed: 0.0007900 moles log = -3.1024 Original solution: 1000.0103000 g Original solution / Rock added: 1265835.82 (Water/Rock Ratio), log = 6.1024 The following minerals and/or gases with identical index are in solid solution: H2O,gas 6 CO2,gas 6 CH4,gas 6 H2,gas 6 H2S,gas 6 S2,gas 6 CO,gas 6 SO3,gas 6 SO2,gas 6 HF,gas 6 HCl,gas 6 almandine 16 pyrope 16 spessartine 16 andradite 8 grossular 8 annite 15 phlogopite 15 biotite-Mn 15 clinochlore 1 daphnite 1 chlorite-Mn 1 diopside 5 hedenbergite 5 epidote 3 clinozoisite 3 iron 9 magnetite 14 talc 7 talc-Fe 7 tremolite 2 ferroactinolite 2 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 10 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 0.0007900 Water: Moles liquid = 0.4985E+02 kg liquid = 0.8981E+00 Moles total = 0.4985E+02 kg total = 0.8980E+00 Activity = 1.0000 Stoichiometric ionic strength = .1138061E-01 Osmotic coef. = 0.9668 True ionic strength = .2006327E-01 Chg. balance for total moles = -.5508E-08 Max. difference allowed = 0.1425E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.89515E-10 -10.0481 0.75205E-10 -10.1238 0.84014E+00 -0.0757 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.15800E-03 -3.8013 0.13194E-03 -3.8796 0.83508E+00 -0.0783 4 SO4-- 0.13051E-09 -9.8844 0.67734E-10 -10.1692 0.51900E+00 -0.2848 5 HCO3- 0.23146E-04 -4.6355 0.19357E-04 -4.7132 0.83630E+00 -0.0776 6 HS- 0.49765E-04 -4.3031 0.41564E-04 -4.3813 0.83520E+00 -0.0782 7 Al+++ 0.98642E-29 -29.0059 0.22759E-29 -29.6428 0.23072E+00 -0.6369 8 H4SiO4 0.70484E-03 -3.1519 0.70484E-03 -3.1519 0.10000E+01 0.0000 9 Ca++ 0.11650E-06 -6.9337 0.60020E-07 -7.2217 0.51519E+00 -0.2880 10 Mg++ 0.21164E-10 -10.6744 0.10853E-10 -10.9644 0.51283E+00 -0.2900 11 Fe++ 0.45124E-13 -13.3456 0.23166E-13 -13.6351 0.51339E+00 -0.2896 12 K+ 0.15652E-03 -3.8054 0.13092E-03 -3.8830 0.83650E+00 -0.0775 13 Na+ 0.19863E-01 -1.7020 0.16584E-01 -1.7803 0.83492E+00 -0.0784 14 Mn++ 0.19035E-10 -10.7204 0.97804E-11 -11.0096 0.51382E+00 -0.2892 15 F- 0.46172E-06 -6.3356 0.38478E-06 -6.4148 0.83335E+00 -0.0792 16 HPO4-- 0.45328E-07 -7.3436 0.23529E-07 -7.6284 0.51908E+00 -0.2848 18 HSiO3- 0.10480E-01 -1.9797 0.87513E-02 -2.0579 0.83508E+00 -0.0783 19 Ca(HSiO3)+ 0.14297E-07 -7.8448 0.11962E-07 -7.9222 0.83668E+00 -0.0774 20 Mg(HSiO3)+ 0.32175E-11 -11.4925 0.26920E-11 -11.5699 0.83668E+00 -0.0774 21 NaHSiO3,aq 0.23473E-02 -2.6294 0.23473E-02 -2.6294 0.10000E+01 0.0000 22 AlO+ 0.65430E-16 -16.1842 0.54744E-16 -16.2617 0.83668E+00 -0.0774 24 HAlO2,aq 0.14497E-09 -9.8387 0.14497E-09 -9.8387 0.10000E+01 0.0000 25 AlO2- 0.51189E-05 -5.2908 0.42669E-05 -5.3699 0.83356E+00 -0.0791 26 CH4,aq 0.11578E-04 -4.9364 0.11538E-04 -4.9379 0.99653E+00 -0.0015 27 C2H6,aq 0.63061E-14 -14.2002 0.62842E-14 -14.2017 0.99653E+00 -0.0015 31 CO,aq 0.28299E-15 -15.5482 0.28299E-15 -15.5482 0.10000E+01 0.0000 32 CO2,aq 0.31214E-08 -8.5057 0.31105E-08 -8.5072 0.99653E+00 -0.0015 33 CO3-2 0.43409E-04 -4.3624 0.22482E-04 -4.6482 0.51790E+00 -0.2858 34 CaCO3,aq 0.16919E-07 -7.7716 0.16919E-07 -7.7716 0.10000E+01 0.0000 35 Ca(HCO3)+ 0.35445E-10 -10.4505 0.29656E-10 -10.5279 0.83668E+00 -0.0774 36 CaCl+ 0.15317E-10 -10.8148 0.12815E-10 -10.8923 0.83668E+00 -0.0774 37 CaCl2,aq 0.40172E-15 -15.3961 0.40172E-15 -15.3961 0.10000E+01 0.0000 38 CaF+ 0.40299E-12 -12.3947 0.33718E-12 -12.4721 0.83668E+00 -0.0774 39 CaOH+ 0.67982E-07 -7.1676 0.56879E-07 -7.2451 0.83668E+00 -0.0774 40 CaSO4,aq 0.12909E-14 -14.8891 0.12909E-14 -14.8891 0.10000E+01 0.0000 41 HCl,aq 0.18183E-14 -14.7403 0.18183E-14 -14.7403 0.10000E+01 0.0000 45 HF,aq 0.19809E-12 -12.7031 0.19809E-12 -12.7031 0.10000E+01 0.0000 46 HF2- 0.30817E-19 -19.5112 0.25735E-19 -19.5895 0.83508E+00 -0.0783 48 FeCl+ 0.57824E-17 -17.2379 0.48380E-17 -17.3153 0.83668E+00 -0.0774 51 FeF+ 0.54443E-18 -18.2641 0.45551E-18 -18.3415 0.83668E+00 -0.0774 53 FeO,aq 0.15919E-09 -9.7981 0.15919E-09 -9.7981 0.10000E+01 0.0000 54 FeOH+ 0.11984E-10 -10.9214 0.10027E-10 -10.9988 0.83668E+00 -0.0774 55 HFeO2- 0.26523E-07 -7.5764 0.22148E-07 -7.6547 0.83508E+00 -0.0783 56 FeO+ 0.15021E-16 -16.8233 0.12568E-16 -16.9008 0.83668E+00 -0.0774 58 FeO2- 0.54448E-09 -9.2640 0.45468E-09 -9.3423 0.83508E+00 -0.0783 59 HFeO2,aq 0.43490E-11 -11.3616 0.43490E-11 -11.3616 0.10000E+01 0.0000 60 H2,aq 0.36342E-05 -5.4396 0.36216E-05 -5.4411 0.99653E+00 -0.0015 61 KCl,aq 0.31308E-09 -9.5043 0.31308E-09 -9.5043 0.10000E+01 0.0000 63 KOH,aq 0.74346E-06 -6.1287 0.74346E-06 -6.1287 0.10000E+01 0.0000 64 KSO4- 0.16479E-12 -12.7831 0.13761E-12 -12.8614 0.83508E+00 -0.0783 65 MgCO3,aq 0.76689E-12 -12.1153 0.76689E-12 -12.1153 0.10000E+01 0.0000 66 Mg(HCO3)+ 0.65493E-14 -14.1838 0.54796E-14 -14.2612 0.83668E+00 -0.0774 67 MgCl+ 0.25104E-14 -14.6003 0.21004E-14 -14.6777 0.83668E+00 -0.0774 68 MgF+ 0.26995E-15 -15.5687 0.22586E-15 -15.6462 0.83668E+00 -0.0774 69 MgOH+ 0.68024E-10 -10.1673 0.56914E-10 -10.2448 0.83668E+00 -0.0774 71 MnF+ 0.75761E-16 -16.1206 0.63387E-16 -16.1980 0.83668E+00 -0.0774 72 MnO,aq 0.17908E-08 -8.7469 0.17908E-08 -8.7469 0.10000E+01 0.0000 73 MnOH+ 0.47002E-09 -9.3279 0.39326E-09 -9.4053 0.83668E+00 -0.0774 74 MnO2-2 0.20290E-10 -10.6927 0.10508E-10 -10.9785 0.51790E+00 -0.2858 75 HMnO2- 0.20733E-09 -9.6833 0.17314E-09 -9.7616 0.83508E+00 -0.0783 78 MnCl+ 0.94976E-14 -14.0224 0.79464E-14 -14.0998 0.83668E+00 -0.0774 79 MnSO4,aq 0.19125E-18 -18.7184 0.19125E-18 -18.7184 0.10000E+01 0.0000 80 NaCl,aq 0.72514E-06 -6.1396 0.72514E-06 -6.1396 0.10000E+01 0.0000 81 NaF,aq 0.14939E-08 -8.8257 0.14939E-08 -8.8257 0.10000E+01 0.0000 82 NaOH,aq 0.94745E-04 -4.0234 0.94745E-04 -4.0234 0.10000E+01 0.0000 84 OH- 0.92166E-02 -2.0354 0.76827E-02 -2.1145 0.83356E+00 -0.0791 89 HPO3-2 0.51273E-15 -15.2901 0.26555E-15 -15.5759 0.51790E+00 -0.2858 91 H2PO3- 0.47956E-19 -19.3192 0.40047E-19 -19.3974 0.83508E+00 -0.0783 92 H3PO4,aq 0.93070E-18 -18.0312 0.93070E-18 -18.0312 0.10000E+01 0.0000 93 H2PO4- 0.39051E-10 -10.4084 0.32642E-10 -10.4862 0.83587E+00 -0.0779 94 PO4-3 0.10533E-08 -8.9775 0.25526E-09 -9.5930 0.24235E+00 -0.6156 98 HP2O7-3 0.96045E-18 -18.0175 0.22182E-18 -18.6540 0.23095E+00 -0.6365 99 P2O7-4 0.91596E-17 -17.0381 0.70463E-18 -18.1520 0.76928E-01 -1.1139 100 H2S,aq 0.96943E-08 -8.0135 0.96607E-08 -8.0150 0.99653E+00 -0.0015 101 S2-2 0.20409E-13 -13.6902 0.10570E-13 -13.9759 0.51790E+00 -0.2858 107 SO3-2 0.60671E-16 -16.2170 0.31877E-16 -16.4965 0.52540E+00 -0.2795 108 HSO3- 0.17975E-18 -18.7453 0.15010E-18 -18.8236 0.83508E+00 -0.0783 109 HSO4- 0.58616E-17 -17.2320 0.49091E-17 -17.3090 0.83749E+00 -0.0770 111 S2O3-2 0.14842E-19 -19.8285 0.76866E-20 -20.1143 0.51790E+00 -0.2858 Charge balance for all species = -.6133E-08 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.8951527E-10 -.2220402E-01 -.2234137E+02 0.0000 2 H2O 0.1000000E+01 0.5550476E+02 0.9981945E+06 0.0000 3 Cl- 0.1579988E-03 0.1587243E-03 0.5617457E+01 6.2441 4 SO4-- 0.1305067E-09 -.1248661E-04 -.1197396E+01 10.0783 5 HCO3- 0.2314573E-04 0.7815331E-04 0.4760397E+01 5.4106 6 HS- 0.4976532E-04 0.6226175E-04 0.2055537E+01 5.7425 7 Al+++ 0.9864204E-29 0.5119040E-05 0.1378790E+00 0.7284 8 H4SiO4 0.7048424E-03 0.1353180E-01 0.1298350E+04 -3.1519 9 Ca++ 0.1165002E-06 0.2157492E-06 0.8631746E-02 13.0258 10 Mg++ 0.2116373E-10 0.9318144E-10 0.2261484E-05 9.2831 11 Fe++ 0.4512405E-13 0.2724267E-07 0.1518774E-02 6.6124 12 K+ 0.1565153E-03 0.1572591E-03 0.6138444E+01 6.2408 13 Na+ 0.1986286E-01 0.2230563E-01 0.5119094E+03 8.3434 14 Mn++ 0.1903491E-10 0.2507537E-08 0.1375193E-03 9.2379 15 F- 0.4617220E-06 0.4632165E-06 0.8784871E-02 3.7090 16 HPO4-- 0.4532752E-07 0.4641985E-07 0.4447577E-02 12.6191 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.1994148E-01 -.1994072E-01 -.7548865E-06 0.0000000E+00 2 H2O 0.4984706E+02 0.4984706E+02 -.7107879E-06 0.0000000E+00 3 Cl- 0.1425452E-03 0.1425452E-03 0.0000000E+00 0.0000000E+00 4 SO4-- -.1121281E-04 -.1121383E-04 0.1015812E-08 0.0000000E+00 5 HCO3- 0.7018700E-04 0.7018700E-04 0.0000000E+00 0.0000000E+00 6 HS- 0.5591428E-04 0.5591530E-04 -.1015812E-08 0.0000000E+00 7 Al+++ 0.4775352E-05 0.4597247E-05 0.1781054E-06 0.0000000E+00 8 H4SiO4 0.1215302E-01 0.1215248E-01 0.5443695E-06 0.0000000E+00 9 Ca++ 0.2080835E-06 0.1937574E-06 0.1432605E-07 0.0000000E+00 10 Mg++ 0.8368328E-10 0.8368328E-10 0.0000000E+00 0.0000000E+00 11 Fe++ 0.3259227E-07 0.2446578E-07 0.8126494E-08 0.0000000E+00 12 K+ 0.1412294E-03 0.1412294E-03 0.0000000E+00 0.0000000E+00 13 Na+ 0.2003215E-01 0.2003197E-01 0.1766812E-06 0.0000000E+00 14 Mn++ 0.2251939E-08 0.2251939E-08 0.0000000E+00 0.0000000E+00 15 F- 0.4160000E-06 0.4160000E-06 0.0000000E+00 0.0000000E+00 16 HPO4-- 0.4168819E-07 0.4168819E-07 0.0000000E+00 0.0000000E+00 Chg. balance for solid moles: -.2647E-22 Mass of aqueous solution: 0.899634E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 0.0007900 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 0.1767E-06 -6.753 0.4633E-04 -4.334 95.10 0.1778E-04 andradite 0.4063E-08 -8.391 0.2065E-05 -5.685 4.239 0.5365E-06 grossular 0.7121E-09 -9.147 0.3208E-06 -6.494 0.6585 0.8925E-07 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8509E+00 0.8509E+00 1.0000 -0.070 grossular 0.1491E+00 0.1491E+00 1.0000 -0.826 Solid products produced: Mass = 0.000049 g Volume = 0.000018 cm3 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.0007900 moles log = -3.1024 Original solution: 1000.0103000 g Original solution / Rock added: 1265835.82 (Water/Rock Ratio), log = 6.1024 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0421 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9793E+00 0.9857 0.1006E+01 0.1021E+01 CO2,gas 0.3172E-06 1.0069 0.3328E-06 0.3305E-06 CH4,gas 0.1610E-01 1.0124 0.1698E-01 0.1678E-01 H2,gas 0.4560E-02 1.0006 0.4755E-02 0.4752E-02 H2S,gas 0.2559E-06 0.9960 0.2656E-06 0.2666E-06 S2,gas 0.1124E-27 1.0000 0.1171E-27 0.1171E-27 CO,gas 0.4047E-12 1.0000 0.4217E-12 0.4217E-12 SO3,gas 0.1390E-45 1.0000 0.1448E-45 0.1448E-45 SO2,gas 0.2571E-25 1.0000 0.2679E-25 0.2679E-25 HF,gas 0.4667E-15 1.0000 0.4864E-15 0.4864E-15 HCl,gas 0.3079E-17 1.0000 0.3208E-17 0.3208E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 17 albite -0.38 -0.38 0.00 0.000 0.11184E-10 23 andradite 39.01 39.01 0.00 0.000 0.00000E+00 24 grossular 32.73 32.73 0.00 0.000 0.12132E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -14.84 -8.18 -2.726 0.13962E+05 -6.478 3 CH4,gas 4.54 1.07 -3.47 -0.867 0.59231E+04 -1.770 4 H2,gas 8.00 3.98 -4.02 -2.298 0.68672E+04 -2.323 5 H2S,gas -6.23 -14.51 -8.27 -4.137 0.14129E+05 -6.576 6 S2,gas -7.34 -36.97 -29.63 -4.559 0.50593E+05 -27.931 7 CO,gas 3.21 -10.86 -14.07 -4.330 0.24031E+05 -12.375 8 SO3,gas 17.12 -30.42 -47.54 -11.885 0.81170E+05 -45.839 9 SO2,gas 0.83 -26.44 -27.27 -7.272 0.46564E+05 -25.572 10 HF,gas 0.47 -16.54 -17.01 -8.506 0.29047E+05 -15.313 11 HCl,gas 5.19 -14.00 -19.19 -9.596 0.32771E+05 -17.494 12 acmite 7.71 6.66 -1.05 -0.109 0.17872E+04 16 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 20 spessartine 24.46 19.71 -4.74 -0.237 0.80979E+04 21 analcite 3.32 2.77 -0.55 -0.062 0.94563E+03 27 annite 20.12 17.35 -2.77 -0.154 0.47346E+04 28 phlogopite 27.06 25.36 -1.70 -0.095 0.29060E+04 30 anorthite 12.71 8.18 -4.53 -0.349 0.77374E+04 33 apatite-OH -18.15 -18.50 -0.35 -0.027 0.58950E+03 34 apatite-F -34.30 -35.04 -0.74 -0.061 0.12572E+04 38 aragonite 0.97 -1.81 -2.78 -0.926 0.47427E+04 39 brucite 12.57 9.28 -3.29 -0.657 0.56099E+04 40 calcite 0.81 -1.81 -2.62 -0.874 0.44785E+04 41 carnegieite-low 9.02 5.92 -3.10 -0.443 0.52989E+04 42 carnegieite-high 10.09 5.92 -4.17 -0.596 0.71259E+04 43 carpholite-Mg 8.58 4.44 -4.15 -0.276 0.70792E+04 44 carpholite-Fe 6.71 1.77 -4.95 -0.330 0.84473E+04 45 celadonite 5.34 3.64 -1.70 -0.100 0.28975E+04 46 celadonite-Fe 3.88 0.97 -2.90 -0.171 0.49561E+04 47 chrysotile 23.89 21.55 -2.35 -0.196 0.40074E+04 49 clinochlore 39.07 38.42 -0.65 -0.020 0.11151E+04 50 daphnite 28.97 25.06 -3.90 -0.122 0.66631E+04 52 chlorite-Al-free 47.17 43.09 -4.08 -0.170 0.69700E+04 54 chloritoid-Fe 9.17 4.92 -4.26 -0.284 0.72676E+04 55 chloritoid-Mn 11.40 7.54 -3.86 -0.257 0.65879E+04 57 coesite -2.38 -3.15 -0.78 -0.259 0.13247E+04 64 cristobalite -2.56 -3.15 -0.59 -0.197 0.10101E+04 66 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71235E+04 68 diaspore 2.87 0.73 -2.15 -0.358 0.36630E+04 69 diamond -3.10 -6.88 -3.78 -1.080 0.64520E+04 70 diopside 16.18 16.01 -0.18 -0.018 0.30103E+03 71 hedenbergite 14.21 13.33 -0.87 -0.087 0.14922E+04 76 clinoenstatite 17.17 12.26 -4.90 -0.490 0.83734E+04 78 epidote 24.67 22.68 -1.99 -0.097 0.34044E+04 79 clinozoisite 22.81 18.78 -4.02 -0.183 0.68724E+04 80 epidote-Fe 29.84 26.57 -3.27 -0.170 0.55829E+04 81 fayalite 14.05 10.07 -3.97 -0.568 0.67836E+04 82 ferrosilite 11.15 6.92 -4.23 -0.423 0.72201E+04 86 gibbsite 4.08 0.73 -3.35 -0.479 0.57216E+04 87 glaucophane 22.97 20.78 -2.20 -0.059 0.37516E+04 88 glaucophane-Fe 17.28 12.77 -4.51 -0.122 0.77012E+04 89 graphite -3.55 -6.88 -3.33 -0.953 0.56943E+04 90 greenalite 16.14 13.53 -2.61 -0.217 0.44501E+04 93 hematite 12.57 9.25 -3.32 -0.402 0.56677E+04 94 heulandite -5.83 -7.58 -1.75 -0.080 0.29940E+04 98 jadeite 4.22 2.77 -1.45 -0.145 0.24711E+04 100 kalsilite 7.58 3.82 -3.77 -0.538 0.64314E+04 101 kaolinite -1.33 -4.85 -3.51 -0.319 0.60004E+04 104 laumontite 2.88 1.87 -1.01 -0.067 0.17218E+04 105 lawsonite 9.62 8.18 -1.44 -0.096 0.24541E+04 106 leucite 4.12 0.67 -3.45 -0.345 0.58967E+04 108 lizardite 23.24 21.55 -1.70 -0.142 0.29001E+04 110 magnetite 20.09 15.86 -4.23 -0.345 0.72196E+04 111 minnesotaite 10.39 7.23 -3.16 -0.186 0.53933E+04 115 manganosite 14.06 9.24 -4.82 -1.205 0.82304E+04 119 microcline -2.49 -2.49 0.00 0.000 0.66852E-01 123 muscovite 2.58 -1.03 -3.61 -0.212 0.61676E+04 124 paragonite 4.24 1.07 -3.17 -0.186 0.54067E+04 125 nepheline 8.34 5.92 -2.42 -0.346 0.41312E+04 137 phlogopite-Na 29.65 27.47 -2.18 -0.121 0.37247E+04 139 prehnite 19.37 18.05 -1.32 -0.078 0.22525E+04 140 prehnite-Fe 22.50 21.95 -0.55 -0.033 0.93940E+03 141 pumpellyite-Fe 46.27 43.45 -2.82 -0.063 0.48206E+04 142 pumpellyite-Mg 48.99 46.12 -2.88 -0.064 0.49141E+04 146 pyrrhotite -4.26 -7.89 -3.63 -1.211 0.62021E+04 147 pyrrhotiteFe0.875 -6.02 -9.21 -3.20 -1.175 0.54563E+04 148 pyroxmangite 7.40 6.09 -1.31 -0.263 0.22414E+04 149 pyrophyllite -6.18 -11.15 -4.98 -0.311 0.84947E+04 150 quartz -2.99 -3.15 -0.16 -0.054 0.27742E+03 154 rhodochrosite -0.98 -5.60 -4.62 -1.541 0.78932E+04 155 rhodonite 7.45 6.09 -1.36 -0.272 0.23217E+04 156 sanidine -1.28 -2.49 -1.21 -0.093 0.20678E+04 166 stilbite -7.52 -7.58 -0.06 -0.003 0.10019E+03 167 stilpnomelane-Fe 13.02 12.42 -0.59 -0.018 0.10129E+04 168 stilpnomelane-Mg 27.44 25.78 -1.66 -0.050 0.28414E+04 174 talc 16.49 15.24 -1.25 -0.073 0.21335E+04 177 tephroite 18.09 15.32 -2.76 -0.395 0.47160E+04 181 tridymite -2.63 -3.15 -0.53 -0.175 0.89740E+03 182 tremolite 47.87 47.25 -0.62 -0.017 0.10545E+04 183 ferroactinolite 38.45 33.90 -4.55 -0.123 0.77762E+04 184 troilite-low -4.41 -7.89 -3.48 -1.161 0.59450E+04 190 wairakite 3.95 1.87 -2.08 -0.122 0.35438E+04 191 walstromite 11.51 9.87 -1.64 -0.327 0.27923E+04 192 wollastonite 10.46 9.87 -0.59 -0.117 0.10027E+04 193 pseudo-wollastonite 11.00 9.87 -1.13 -0.225 0.19226E+04 194 zoisite 22.85 18.78 -4.07 -0.185 0.69465E+04 195 akaganeite 7.75 4.62 -3.13 -0.677 0.53464E+04 202 chalcedony -2.80 -3.15 -0.35 -0.116 0.59672E+03 204 montmorillonite-Ca -2.29 -6.18 -3.89 -0.241 0.66383E+04 205 montmorillonite-K -2.24 -6.27 -4.03 -0.247 0.68838E+04 206 montmorillonite-Mg -2.48 -6.80 -4.32 -0.267 0.73698E+04 207 montmorillonite-Na -2.04 -5.57 -3.54 -0.217 0.60387E+04 208 nontronite-Ca 3.21 0.07 -3.15 -0.204 0.53710E+04 209 nontronite-H 2.53 -2.08 -4.61 -0.309 0.78766E+04 210 nontronite-K 3.34 -0.02 -3.36 -0.216 0.57398E+04 211 nontronite-Mg 3.07 -0.55 -3.62 -0.235 0.61866E+04 212 nontronite-Na 3.52 0.67 -2.85 -0.183 0.48606E+04 228 tobermorite 9.82 7.70 -2.12 -0.580 0.36275E+04 234 alabandite -0.98 -5.27 -4.29 -1.430 0.73239E+04 237 boehmite 4.41 0.73 -3.68 -0.613 0.62799E+04 239 ferrous-oxide 9.81 6.61 -3.20 -0.800 0.54626E+04 245 silica-amorphous -2.09 -3.15 -1.06 -0.354 0.18109E+04 247 an20ab80 2.02 1.33 -0.69 -0.053 0.11766E+04 248 an25ab75 2.65 1.76 -0.89 -0.068 0.15178E+04 249 an30ab70 3.28 2.18 -1.09 -0.084 0.18685E+04 250 tr.625ac.25prg.125 45.16 44.86 -0.31 -0.008 0.52548E+03 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 0.0000400 MOLES Current total amount of reactant added: 0.0007900 MOLES New total amount of reactant added: 0.0008300 MOLES Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.5508E-08 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 7 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 0.0008300 Water: Moles liquid = 0.4985E+02 kg liquid = 0.8981E+00 Moles total = 0.4985E+02 kg total = 0.8980E+00 Activity = 1.0000 Stoichiometric ionic strength = .1138316E-01 Osmotic coef. = 0.9667 True ionic strength = .2006563E-01 Chg. balance for total moles = -.5508E-08 Max. difference allowed = 0.1428E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.89579E-10 -10.0478 0.75258E-10 -10.1234 0.84013E+00 -0.0757 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.15826E-03 -3.8006 0.13216E-03 -3.8789 0.83507E+00 -0.0783 4 SO4-- 0.14269E-09 -9.8456 0.74052E-10 -10.1305 0.51899E+00 -0.2848 5 HCO3- 0.24345E-04 -4.6136 0.20359E-04 -4.6912 0.83629E+00 -0.0776 6 HS- 0.50847E-04 -4.2937 0.42467E-04 -4.3719 0.83519E+00 -0.0782 7 Al+++ 0.98732E-29 -29.0055 0.22778E-29 -29.6425 0.23071E+00 -0.6369 8 H4SiO4 0.70531E-03 -3.1516 0.70531E-03 -3.1516 0.10000E+01 0.0000 9 Ca++ 0.11606E-06 -6.9353 0.59789E-07 -7.2234 0.51517E+00 -0.2880 10 Mg++ 0.21166E-10 -10.6744 0.10854E-10 -10.9644 0.51281E+00 -0.2900 11 Fe++ 0.45180E-13 -13.3451 0.23194E-13 -13.6346 0.51337E+00 -0.2896 12 K+ 0.15652E-03 -3.8054 0.13092E-03 -3.8830 0.83649E+00 -0.0775 13 Na+ 0.19863E-01 -1.7020 0.16584E-01 -1.7803 0.83492E+00 -0.0784 14 Mn++ 0.19061E-10 -10.7199 0.97935E-11 -11.0091 0.51380E+00 -0.2892 15 F- 0.47948E-06 -6.3192 0.39957E-06 -6.3984 0.83334E+00 -0.0792 16 HPO4-- 0.45328E-07 -7.3436 0.23528E-07 -7.6284 0.51906E+00 -0.2848 18 HSiO3- 0.10479E-01 -1.9797 0.87509E-02 -2.0579 0.83507E+00 -0.0783 19 Ca(HSiO3)+ 0.14241E-07 -7.8464 0.11915E-07 -7.9239 0.83667E+00 -0.0774 20 Mg(HSiO3)+ 0.32176E-11 -11.4925 0.26921E-11 -11.5699 0.83667E+00 -0.0774 21 NaHSiO3,aq 0.23472E-02 -2.6295 0.23472E-02 -2.6295 0.10000E+01 0.0000 22 AlO+ 0.65394E-16 -16.1845 0.54713E-16 -16.2619 0.83667E+00 -0.0774 24 HAlO2,aq 0.14478E-09 -9.8393 0.14478E-09 -9.8393 0.10000E+01 0.0000 25 AlO2- 0.51088E-05 -5.2917 0.42585E-05 -5.3707 0.83356E+00 -0.0791 26 CH4,aq 0.11381E-04 -4.9438 0.11341E-04 -4.9453 0.99653E+00 -0.0015 27 C2H6,aq 0.61981E-14 -14.2077 0.61766E-14 -14.2093 0.99653E+00 -0.0015 31 CO,aq 0.29281E-15 -15.5334 0.29281E-15 -15.5334 0.10000E+01 0.0000 32 CO2,aq 0.32854E-08 -8.4834 0.32740E-08 -8.4849 0.99653E+00 -0.0015 33 CO3-2 0.45627E-04 -4.3408 0.23629E-04 -4.6265 0.51789E+00 -0.2858 34 CaCO3,aq 0.17715E-07 -7.7517 0.17715E-07 -7.7517 0.10000E+01 0.0000 35 Ca(HCO3)+ 0.37137E-10 -10.4302 0.31072E-10 -10.5076 0.83667E+00 -0.0774 36 CaCl+ 0.15283E-10 -10.8158 0.12787E-10 -10.8932 0.83667E+00 -0.0774 37 CaCl2,aq 0.40149E-15 -15.3963 0.40149E-15 -15.3963 0.10000E+01 0.0000 38 CaF+ 0.41688E-12 -12.3800 0.34879E-12 -12.4574 0.83667E+00 -0.0774 39 CaOH+ 0.67673E-07 -7.1696 0.56620E-07 -7.2470 0.83667E+00 -0.0774 40 CaSO4,aq 0.14059E-14 -14.8520 0.14059E-14 -14.8520 0.10000E+01 0.0000 41 HCl,aq 0.18226E-14 -14.7393 0.18226E-14 -14.7393 0.10000E+01 0.0000 45 HF,aq 0.20586E-12 -12.6864 0.20586E-12 -12.6864 0.10000E+01 0.0000 46 HF2- 0.33256E-19 -19.4781 0.27771E-19 -19.5564 0.83507E+00 -0.0783 48 FeCl+ 0.57990E-17 -17.2366 0.48519E-17 -17.3141 0.83667E+00 -0.0774 51 FeF+ 0.56605E-18 -18.2471 0.47360E-18 -18.3246 0.83667E+00 -0.0774 53 FeO,aq 0.15916E-09 -9.7982 0.15916E-09 -9.7982 0.10000E+01 0.0000 54 FeOH+ 0.11990E-10 -10.9212 0.10032E-10 -10.9986 0.83667E+00 -0.0774 55 HFeO2- 0.26499E-07 -7.5768 0.22128E-07 -7.6551 0.83507E+00 -0.0783 56 FeO+ 0.15157E-16 -16.8194 0.12682E-16 -16.8968 0.83667E+00 -0.0774 58 FeO2- 0.54865E-09 -9.2607 0.45816E-09 -9.3390 0.83507E+00 -0.0783 59 HFeO2,aq 0.43854E-11 -11.3580 0.43854E-11 -11.3580 0.10000E+01 0.0000 60 H2,aq 0.35726E-05 -5.4470 0.35602E-05 -5.4485 0.99653E+00 -0.0015 61 KCl,aq 0.31360E-09 -9.5036 0.31360E-09 -9.5036 0.10000E+01 0.0000 63 KOH,aq 0.74294E-06 -6.1290 0.74294E-06 -6.1290 0.10000E+01 0.0000 64 KSO4- 0.18016E-12 -12.7443 0.15045E-12 -12.8226 0.83507E+00 -0.0783 65 MgCO3,aq 0.80610E-12 -12.0936 0.80610E-12 -12.0936 0.10000E+01 0.0000 66 Mg(HCO3)+ 0.68891E-14 -14.1618 0.57639E-14 -14.2393 0.83667E+00 -0.0774 67 MgCl+ 0.25147E-14 -14.5995 0.21040E-14 -14.6770 0.83667E+00 -0.0774 68 MgF+ 0.28035E-15 -15.5523 0.23456E-15 -15.6297 0.83667E+00 -0.0774 69 MgOH+ 0.67982E-10 -10.1676 0.56878E-10 -10.2451 0.83667E+00 -0.0774 71 MnF+ 0.78780E-16 -16.1036 0.65913E-16 -16.1810 0.83667E+00 -0.0774 72 MnO,aq 0.17907E-08 -8.7470 0.17907E-08 -8.7470 0.10000E+01 0.0000 73 MnOH+ 0.47032E-09 -9.3276 0.39351E-09 -9.4050 0.83667E+00 -0.0774 74 MnO2-2 0.20261E-10 -10.6933 0.10493E-10 -10.9791 0.51789E+00 -0.2858 75 HMnO2- 0.20717E-09 -9.6837 0.17300E-09 -9.7619 0.83507E+00 -0.0783 78 MnCl+ 0.95261E-14 -14.0211 0.79702E-14 -14.0985 0.83667E+00 -0.0774 79 MnSO4,aq 0.20937E-18 -18.6791 0.20937E-18 -18.6791 0.10000E+01 0.0000 80 NaCl,aq 0.72634E-06 -6.1389 0.72634E-06 -6.1389 0.10000E+01 0.0000 81 NaF,aq 0.15514E-08 -8.8093 0.15514E-08 -8.8093 0.10000E+01 0.0000 82 NaOH,aq 0.94678E-04 -4.0238 0.94678E-04 -4.0238 0.10000E+01 0.0000 84 OH- 0.92102E-02 -2.0357 0.76772E-02 -2.1148 0.83356E+00 -0.0791 89 HPO3-2 0.50405E-15 -15.2975 0.26104E-15 -15.5833 0.51789E+00 -0.2858 91 H2PO3- 0.47176E-19 -19.3263 0.39395E-19 -19.4046 0.83507E+00 -0.0783 92 H3PO4,aq 0.93200E-18 -18.0306 0.93200E-18 -18.0306 0.10000E+01 0.0000 93 H2PO4- 0.39079E-10 -10.4081 0.32664E-10 -10.4859 0.83586E+00 -0.0779 94 PO4-3 0.10526E-08 -8.9777 0.25507E-09 -9.5933 0.24233E+00 -0.6156 98 HP2O7-3 0.96116E-18 -18.0172 0.22197E-18 -18.6537 0.23094E+00 -0.6365 99 P2O7-4 0.91604E-17 -17.0381 0.70461E-18 -18.1521 0.76919E-01 -1.1140 100 H2S,aq 0.99121E-08 -8.0038 0.98777E-08 -8.0053 0.99653E+00 -0.0015 101 S2-2 0.21674E-13 -13.6641 0.11224E-13 -13.9498 0.51789E+00 -0.2858 107 SO3-2 0.65209E-16 -16.1857 0.34260E-16 -16.4652 0.52539E+00 -0.2795 108 HSO3- 0.19332E-18 -18.7137 0.16144E-18 -18.7920 0.83507E+00 -0.0783 109 HSO4- 0.64130E-17 -17.1929 0.53708E-17 -17.2700 0.83749E+00 -0.0770 111 S2O3-2 0.16591E-19 -19.7801 0.85923E-20 -20.0659 0.51789E+00 -0.2858 Charge balance for all species = -.6133E-08 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.8957923E-10 -.2219917E-01 -.2233648E+02 0.0000 2 H2O 0.1000000E+01 0.5550475E+02 0.9981943E+06 0.0000 3 Cl- 0.1582603E-03 0.1589869E-03 0.5626752E+01 6.2445 4 SO4-- 0.1426852E-09 -.1227392E-04 -.1177000E+01 10.1164 5 HCO3- 0.2434474E-04 0.8137350E-04 0.4956540E+01 5.4322 6 HS- 0.5084737E-04 0.6313135E-04 0.2084246E+01 5.7515 7 Al+++ 0.9873236E-29 0.5108939E-05 0.1376069E+00 0.7279 8 H4SiO4 0.7053086E-03 0.1353176E-01 0.1298346E+04 -3.1516 9 Ca++ 0.1160555E-06 0.2157369E-06 0.8631253E-02 13.0235 10 Mg++ 0.2116609E-10 0.9318137E-10 0.2261482E-05 9.2825 11 Fe++ 0.4517997E-13 0.2722283E-07 0.1517667E-02 6.6123 12 K+ 0.1565157E-03 0.1572590E-03 0.6138438E+01 6.2405 13 Na+ 0.1986301E-01 0.2230560E-01 0.5119087E+03 8.3431 14 Mn++ 0.1906098E-10 0.2507535E-08 0.1375192E-03 9.2378 15 F- 0.4794802E-06 0.4810322E-06 0.9122742E-02 3.7250 16 HPO4-- 0.4532815E-07 0.4641982E-07 0.4447573E-02 12.6185 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.1993717E-01 -.1993638E-01 -.7912243E-06 0.0000000E+00 2 H2O 0.4984709E+02 0.4984709E+02 -.7471110E-06 0.0000000E+00 3 Cl- 0.1427812E-03 0.1427812E-03 0.0000000E+00 0.0000000E+00 4 SO4-- -.1102181E-04 -.1102283E-04 0.1018037E-08 0.0000000E+00 5 HCO3- 0.7307900E-04 0.7307900E-04 0.0000000E+00 0.0000000E+00 6 HS- 0.5669528E-04 0.5669630E-04 -.1018037E-08 0.0000000E+00 7 Al+++ 0.4775352E-05 0.4588179E-05 0.1871734E-06 0.0000000E+00 8 H4SiO4 0.1215302E-01 0.1215245E-01 0.5716161E-06 0.0000000E+00 9 Ca++ 0.2080835E-06 0.1937466E-06 0.1433694E-07 0.0000000E+00 10 Mg++ 0.8368328E-10 0.8368328E-10 0.0000000E+00 0.0000000E+00 11 Fe++ 0.3259227E-07 0.2444797E-07 0.8144296E-08 0.0000000E+00 12 K+ 0.1412294E-03 0.1412294E-03 0.0000000E+00 0.0000000E+00 13 Na+ 0.2003215E-01 0.2003196E-01 0.1857597E-06 0.0000000E+00 14 Mn++ 0.2251939E-08 0.2251939E-08 0.0000000E+00 0.0000000E+00 15 F- 0.4320000E-06 0.4320000E-06 0.0000000E+00 0.0000000E+00 16 HPO4-- 0.4168819E-07 0.4168819E-07 0.0000000E+00 0.0000000E+00 Chg. balance for solid moles: 0.0000E+00 Mass of aqueous solution: 0.899635E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 0.0008300 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 0.1858E-06 -6.731 0.4871E-04 -4.312 95.33 0.1870E-04 andradite 0.4072E-08 -8.390 0.2069E-05 -5.684 4.050 0.5376E-06 grossular 0.7068E-09 -9.151 0.3184E-06 -6.497 0.6231 0.8859E-07 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8521E+00 0.8521E+00 1.0000 -0.070 grossular 0.1479E+00 0.1479E+00 1.0000 -0.830 Solid products produced: Mass = 0.000051 g Volume = 0.000019 cm3 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.0008300 moles log = -3.0809 Original solution: 1000.0103000 g Original solution / Rock added: 1204831.69 (Water/Rock Ratio), log = 6.0809 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0418 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9797E+00 0.9857 0.1006E+01 0.1021E+01 CO2,gas 0.3339E-06 1.0069 0.3503E-06 0.3479E-06 CH4,gas 0.1583E-01 1.0124 0.1669E-01 0.1649E-01 H2,gas 0.4484E-02 1.0006 0.4674E-02 0.4672E-02 H2S,gas 0.2617E-06 0.9960 0.2715E-06 0.2726E-06 S2,gas 0.1216E-27 1.0000 0.1267E-27 0.1267E-27 CO,gas 0.4188E-12 1.0000 0.4363E-12 0.4363E-12 SO3,gas 0.1522E-45 1.0000 0.1586E-45 0.1586E-45 SO2,gas 0.2768E-25 1.0000 0.2884E-25 0.2884E-25 HF,gas 0.4852E-15 1.0000 0.5055E-15 0.5055E-15 HCl,gas 0.3087E-17 1.0000 0.3216E-17 0.3216E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 17 albite -0.38 -0.38 0.00 0.000 -0.94784E-12 23 andradite 39.01 39.01 0.00 0.000 0.12132E-10 24 grossular 32.73 32.73 0.00 0.000 0.12132E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -14.81 -8.15 -2.718 0.13924E+05 -6.456 3 CH4,gas 4.54 1.07 -3.48 -0.869 0.59359E+04 -1.777 4 H2,gas 8.00 3.97 -4.03 -2.302 0.68799E+04 -2.330 5 H2S,gas -6.23 -14.50 -8.27 -4.133 0.14113E+05 -6.566 6 S2,gas -7.34 -36.93 -29.60 -4.553 0.50535E+05 -27.897 7 CO,gas 3.21 -10.84 -14.06 -4.326 0.24006E+05 -12.360 8 SO3,gas 17.12 -30.38 -47.50 -11.875 0.81103E+05 -45.800 9 SO2,gas 0.83 -26.41 -27.24 -7.264 0.46510E+05 -25.540 10 HF,gas 0.47 -16.52 -17.00 -8.498 0.29019E+05 -15.296 11 HCl,gas 5.19 -14.00 -19.19 -9.596 0.32769E+05 -17.493 12 acmite 7.71 6.67 -1.04 -0.108 0.17805E+04 16 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 20 spessartine 24.46 19.71 -4.74 -0.237 0.80985E+04 21 analcite 3.32 2.77 -0.55 -0.062 0.94612E+03 27 annite 20.12 17.35 -2.77 -0.154 0.47350E+04 28 phlogopite 27.06 25.36 -1.70 -0.095 0.29089E+04 30 anorthite 12.71 8.18 -4.53 -0.349 0.77422E+04 33 apatite-OH -18.15 -18.51 -0.35 -0.027 0.60594E+03 34 apatite-F -34.30 -35.03 -0.73 -0.061 0.12451E+04 38 aragonite 0.97 -1.79 -2.76 -0.919 0.47087E+04 39 brucite 12.57 9.28 -3.29 -0.657 0.56109E+04 40 calcite 0.81 -1.79 -2.60 -0.868 0.44445E+04 41 carnegieite-low 9.02 5.92 -3.10 -0.443 0.52999E+04 42 carnegieite-high 10.09 5.92 -4.17 -0.596 0.71269E+04 43 carpholite-Mg 8.58 4.43 -4.15 -0.276 0.70811E+04 44 carpholite-Fe 6.71 1.76 -4.95 -0.330 0.84484E+04 45 celadonite 5.34 3.64 -1.70 -0.100 0.28980E+04 46 celadonite-Fe 3.88 0.97 -2.90 -0.171 0.49558E+04 47 chrysotile 23.89 21.54 -2.35 -0.196 0.40094E+04 49 clinochlore 39.07 38.41 -0.66 -0.021 0.11204E+04 50 daphnite 28.97 25.06 -3.90 -0.122 0.66643E+04 52 chlorite-Al-free 47.17 43.09 -4.08 -0.170 0.69740E+04 54 chloritoid-Fe 9.17 4.92 -4.26 -0.284 0.72691E+04 55 chloritoid-Mn 11.40 7.54 -3.86 -0.257 0.65894E+04 57 coesite -2.38 -3.15 -0.78 -0.259 0.13242E+04 64 cristobalite -2.56 -3.15 -0.59 -0.197 0.10096E+04 66 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71235E+04 68 diaspore 2.87 0.73 -2.15 -0.358 0.36640E+04 69 diamond -3.10 -6.87 -3.77 -1.078 0.64394E+04 70 diopside 16.18 16.00 -0.18 -0.018 0.30495E+03 71 hedenbergite 14.21 13.33 -0.88 -0.088 0.14953E+04 76 clinoenstatite 17.17 12.26 -4.90 -0.490 0.83744E+04 78 epidote 24.67 22.67 -2.00 -0.097 0.34064E+04 79 clinozoisite 22.81 18.78 -4.03 -0.183 0.68816E+04 80 epidote-Fe 29.84 26.57 -3.27 -0.170 0.55778E+04 81 fayalite 14.05 10.07 -3.97 -0.568 0.67835E+04 82 ferrosilite 11.15 6.92 -4.23 -0.423 0.72195E+04 86 gibbsite 4.08 0.73 -3.35 -0.479 0.57225E+04 87 glaucophane 22.97 20.78 -2.20 -0.059 0.37535E+04 88 glaucophane-Fe 17.28 12.77 -4.51 -0.122 0.77007E+04 89 graphite -3.55 -6.87 -3.33 -0.951 0.56817E+04 90 greenalite 16.14 13.53 -2.61 -0.217 0.44496E+04 93 hematite 12.57 9.25 -3.31 -0.401 0.56554E+04 94 heulandite -5.83 -7.58 -1.75 -0.080 0.29964E+04 98 jadeite 4.22 2.77 -1.45 -0.145 0.24716E+04 100 kalsilite 7.58 3.82 -3.77 -0.538 0.64324E+04 101 kaolinite -1.33 -4.85 -3.51 -0.320 0.60013E+04 104 laumontite 2.88 1.87 -1.01 -0.067 0.17257E+04 105 lawsonite 9.62 8.18 -1.44 -0.096 0.24589E+04 106 leucite 4.12 0.67 -3.45 -0.345 0.58972E+04 108 lizardite 23.24 21.54 -1.70 -0.142 0.29020E+04 110 magnetite 20.09 15.87 -4.22 -0.345 0.72074E+04 111 minnesotaite 10.39 7.23 -3.16 -0.186 0.53918E+04 115 manganosite 14.06 9.24 -4.82 -1.205 0.82305E+04 119 microcline -2.49 -2.49 0.00 0.000 0.70276E-01 123 muscovite 2.58 -1.03 -3.61 -0.213 0.61695E+04 124 paragonite 4.24 1.07 -3.17 -0.186 0.54086E+04 125 nepheline 8.34 5.92 -2.42 -0.346 0.41322E+04 137 phlogopite-Na 29.65 27.46 -2.18 -0.121 0.37277E+04 139 prehnite 19.37 18.05 -1.32 -0.078 0.22607E+04 140 prehnite-Fe 22.50 21.95 -0.55 -0.033 0.94050E+03 141 pumpellyite-Fe 46.27 43.44 -2.83 -0.063 0.48382E+04 142 pumpellyite-Mg 48.99 46.11 -2.89 -0.064 0.49325E+04 146 pyrrhotite -4.26 -7.88 -3.62 -1.208 0.61858E+04 147 pyrrhotiteFe0.875 -6.02 -9.20 -3.19 -1.171 0.54384E+04 148 pyroxmangite 7.40 6.09 -1.31 -0.262 0.22410E+04 149 pyrophyllite -6.18 -11.15 -4.97 -0.311 0.84946E+04 150 quartz -2.99 -3.15 -0.16 -0.054 0.27693E+03 154 rhodochrosite -0.98 -5.58 -4.60 -1.534 0.78553E+04 155 rhodonite 7.45 6.09 -1.36 -0.272 0.23213E+04 156 sanidine -1.28 -2.49 -1.21 -0.093 0.20678E+04 166 stilbite -7.52 -7.58 -0.06 -0.003 0.10255E+03 167 stilpnomelane-Fe 13.02 12.42 -0.59 -0.018 0.10119E+04 168 stilpnomelane-Mg 27.44 25.78 -1.67 -0.050 0.28446E+04 174 talc 16.49 15.24 -1.25 -0.074 0.21345E+04 177 tephroite 18.09 15.32 -2.76 -0.395 0.47156E+04 181 tridymite -2.63 -3.15 -0.53 -0.175 0.89690E+03 182 tremolite 47.87 47.25 -0.62 -0.017 0.10633E+04 183 ferroactinolite 38.45 33.90 -4.56 -0.123 0.77809E+04 184 troilite-low -4.41 -7.88 -3.47 -1.157 0.59286E+04 190 wairakite 3.95 1.87 -2.08 -0.122 0.35476E+04 191 walstromite 11.51 9.87 -1.64 -0.327 0.27957E+04 192 wollastonite 10.46 9.87 -0.59 -0.118 0.10061E+04 193 pseudo-wollastonite 11.00 9.87 -1.13 -0.226 0.19260E+04 194 zoisite 22.85 18.78 -4.07 -0.185 0.69557E+04 195 akaganeite 7.75 4.63 -3.13 -0.676 0.53402E+04 202 chalcedony -2.80 -3.15 -0.35 -0.116 0.59622E+03 204 montmorillonite-Ca -2.29 -6.18 -3.89 -0.241 0.66389E+04 205 montmorillonite-K -2.24 -6.27 -4.03 -0.247 0.68840E+04 206 montmorillonite-Mg -2.48 -6.80 -4.32 -0.267 0.73699E+04 207 montmorillonite-Na -2.04 -5.57 -3.54 -0.217 0.60388E+04 208 nontronite-Ca 3.21 0.08 -3.14 -0.204 0.53578E+04 209 nontronite-H 2.53 -2.07 -4.60 -0.309 0.78627E+04 210 nontronite-K 3.34 -0.01 -3.35 -0.215 0.57261E+04 211 nontronite-Mg 3.07 -0.54 -3.62 -0.235 0.61729E+04 212 nontronite-Na 3.52 0.68 -2.84 -0.182 0.48469E+04 228 tobermorite 9.82 7.70 -2.13 -0.580 0.36302E+04 234 alabandite -0.98 -5.26 -4.28 -1.427 0.73075E+04 237 boehmite 4.41 0.73 -3.68 -0.613 0.62809E+04 239 ferrous-oxide 9.81 6.61 -3.20 -0.800 0.54627E+04 245 silica-amorphous -2.09 -3.15 -1.06 -0.353 0.18104E+04 247 an20ab80 2.02 1.33 -0.69 -0.053 0.11776E+04 248 an25ab75 2.65 1.76 -0.89 -0.068 0.15190E+04 249 an30ab70 3.28 2.18 -1.10 -0.084 0.18700E+04 250 tr.625ac.25prg.125 45.16 44.85 -0.31 -0.008 0.53370E+03 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 0.0000400 MOLES Current total amount of reactant added: 0.0008300 MOLES New total amount of reactant added: 0.0008700 MOLES Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.5508E-08 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 7 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 0.0008700 Water: Moles liquid = 0.4985E+02 kg liquid = 0.8981E+00 Moles total = 0.4985E+02 kg total = 0.8980E+00 Activity = 1.0000 Stoichiometric ionic strength = .1138571E-01 Osmotic coef. = 0.9666 True ionic strength = .2006800E-01 Chg. balance for total moles = -.5508E-08 Max. difference allowed = 0.1430E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.89643E-10 -10.0475 0.75311E-10 -10.1231 0.84012E+00 -0.0757 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.15852E-03 -3.7999 0.13238E-03 -3.8782 0.83506E+00 -0.0783 4 SO4-- 0.15562E-09 -9.8079 0.80760E-10 -10.0928 0.51897E+00 -0.2849 5 HCO3- 0.25545E-04 -4.5927 0.21363E-04 -4.6703 0.83629E+00 -0.0776 6 HS- 0.51929E-04 -4.2846 0.43371E-04 -4.3628 0.83518E+00 -0.0782 7 Al+++ 0.98823E-29 -29.0051 0.22797E-29 -29.6421 0.23069E+00 -0.6370 8 H4SiO4 0.70578E-03 -3.1513 0.70578E-03 -3.1513 0.10000E+01 0.0000 9 Ca++ 0.11562E-06 -6.9370 0.59561E-07 -7.2250 0.51516E+00 -0.2881 10 Mg++ 0.21168E-10 -10.6743 0.10855E-10 -10.9644 0.51279E+00 -0.2901 11 Fe++ 0.45243E-13 -13.3444 0.23226E-13 -13.6340 0.51336E+00 -0.2896 12 K+ 0.15652E-03 -3.8054 0.13092E-03 -3.8830 0.83648E+00 -0.0775 13 Na+ 0.19863E-01 -1.7020 0.16584E-01 -1.7803 0.83491E+00 -0.0784 14 Mn++ 0.19087E-10 -10.7193 0.98066E-11 -11.0085 0.51378E+00 -0.2892 15 F- 0.49724E-06 -6.3034 0.41437E-06 -6.3826 0.83334E+00 -0.0792 16 HPO4-- 0.45329E-07 -7.3436 0.23528E-07 -7.6284 0.51905E+00 -0.2848 18 HSiO3- 0.10479E-01 -1.9797 0.87505E-02 -2.0580 0.83506E+00 -0.0783 19 Ca(HSiO3)+ 0.14187E-07 -7.8481 0.11869E-07 -7.9256 0.83666E+00 -0.0774 20 Mg(HSiO3)+ 0.32177E-11 -11.4925 0.26922E-11 -11.5699 0.83666E+00 -0.0774 21 NaHSiO3,aq 0.23471E-02 -2.6295 0.23471E-02 -2.6295 0.10000E+01 0.0000 22 AlO+ 0.65357E-16 -16.1847 0.54682E-16 -16.2622 0.83666E+00 -0.0774 24 HAlO2,aq 0.14460E-09 -9.8398 0.14460E-09 -9.8398 0.10000E+01 0.0000 25 AlO2- 0.50987E-05 -5.2925 0.42500E-05 -5.3716 0.83355E+00 -0.0791 26 CH4,aq 0.11183E-04 -4.9514 0.11144E-04 -4.9530 0.99653E+00 -0.0015 27 C2H6,aq 0.60845E-14 -14.2158 0.60633E-14 -14.2173 0.99653E+00 -0.0015 31 CO,aq 0.30240E-15 -15.5194 0.30240E-15 -15.5194 0.10000E+01 0.0000 32 CO2,aq 0.34498E-08 -8.4622 0.34378E-08 -8.4637 0.99653E+00 -0.0015 33 CO3-2 0.47844E-04 -4.3202 0.24777E-04 -4.6060 0.51787E+00 -0.2858 34 CaCO3,aq 0.18504E-07 -7.7327 0.18504E-07 -7.7327 0.10000E+01 0.0000 35 Ca(HCO3)+ 0.38820E-10 -10.4109 0.32479E-10 -10.4884 0.83666E+00 -0.0774 36 CaCl+ 0.15250E-10 -10.8167 0.12760E-10 -10.8942 0.83666E+00 -0.0774 37 CaCl2,aq 0.40128E-15 -15.3966 0.40128E-15 -15.3966 0.10000E+01 0.0000 38 CaF+ 0.43068E-12 -12.3658 0.36033E-12 -12.4433 0.83666E+00 -0.0774 39 CaOH+ 0.67368E-07 -7.1715 0.56365E-07 -7.2490 0.83666E+00 -0.0774 40 CaSO4,aq 0.15275E-14 -14.8160 0.15275E-14 -14.8160 0.10000E+01 0.0000 41 HCl,aq 0.18268E-14 -14.7383 0.18268E-14 -14.7383 0.10000E+01 0.0000 45 HF,aq 0.21363E-12 -12.6703 0.21363E-12 -12.6703 0.10000E+01 0.0000 46 HF2- 0.35790E-19 -19.4462 0.29887E-19 -19.5245 0.83506E+00 -0.0783 48 FeCl+ 0.58165E-17 -17.2353 0.48665E-17 -17.3128 0.83666E+00 -0.0774 51 FeF+ 0.58782E-18 -18.2308 0.49180E-18 -18.3082 0.83666E+00 -0.0774 53 FeO,aq 0.15915E-09 -9.7982 0.15915E-09 -9.7982 0.10000E+01 0.0000 54 FeOH+ 0.11998E-10 -10.9209 0.10039E-10 -10.9983 0.83666E+00 -0.0774 55 HFeO2- 0.26479E-07 -7.5771 0.22111E-07 -7.6554 0.83506E+00 -0.0783 56 FeO+ 0.15294E-16 -16.8155 0.12796E-16 -16.8929 0.83666E+00 -0.0774 58 FeO2- 0.55281E-09 -9.2574 0.46163E-09 -9.3357 0.83506E+00 -0.0783 59 HFeO2,aq 0.44217E-11 -11.3544 0.44217E-11 -11.3544 0.10000E+01 0.0000 60 H2,aq 0.35138E-05 -5.4542 0.35016E-05 -5.4557 0.99653E+00 -0.0015 61 KCl,aq 0.31411E-09 -9.5029 0.31411E-09 -9.5029 0.10000E+01 0.0000 63 KOH,aq 0.74241E-06 -6.1294 0.74241E-06 -6.1294 0.10000E+01 0.0000 64 KSO4- 0.19648E-12 -12.7067 0.16407E-12 -12.7850 0.83506E+00 -0.0783 65 MgCO3,aq 0.84531E-12 -12.0730 0.84531E-12 -12.0730 0.10000E+01 0.0000 66 Mg(HCO3)+ 0.72293E-14 -14.1409 0.60485E-14 -14.2184 0.83666E+00 -0.0774 67 MgCl+ 0.25191E-14 -14.5988 0.21076E-14 -14.6762 0.83666E+00 -0.0774 68 MgF+ 0.29076E-15 -15.5365 0.24327E-15 -15.6139 0.83666E+00 -0.0774 69 MgOH+ 0.67940E-10 -10.1679 0.56843E-10 -10.2453 0.83666E+00 -0.0774 71 MnF+ 0.81807E-16 -16.0872 0.68445E-16 -16.1647 0.83666E+00 -0.0774 72 MnO,aq 0.17906E-08 -8.7470 0.17906E-08 -8.7470 0.10000E+01 0.0000 73 MnOH+ 0.47062E-09 -9.3273 0.39375E-09 -9.4048 0.83666E+00 -0.0774 74 MnO2-2 0.20231E-10 -10.6940 0.10477E-10 -10.9798 0.51787E+00 -0.2858 75 HMnO2- 0.20701E-09 -9.6840 0.17287E-09 -9.7623 0.83506E+00 -0.0783 78 MnCl+ 0.95546E-14 -14.0198 0.79940E-14 -14.0972 0.83666E+00 -0.0774 79 MnSO4,aq 0.22864E-18 -18.6408 0.22864E-18 -18.6408 0.10000E+01 0.0000 80 NaCl,aq 0.72753E-06 -6.1381 0.72753E-06 -6.1381 0.10000E+01 0.0000 81 NaF,aq 0.16088E-08 -8.7935 0.16088E-08 -8.7935 0.10000E+01 0.0000 82 NaOH,aq 0.94611E-04 -4.0241 0.94611E-04 -4.0241 0.10000E+01 0.0000 84 OH- 0.92037E-02 -2.0360 0.76718E-02 -2.1151 0.83355E+00 -0.0791 89 HPO3-2 0.49576E-15 -15.3047 0.25674E-15 -15.5905 0.51787E+00 -0.2858 91 H2PO3- 0.46432E-19 -19.3332 0.38773E-19 -19.4115 0.83506E+00 -0.0783 92 H3PO4,aq 0.93331E-18 -18.0300 0.93331E-18 -18.0300 0.10000E+01 0.0000 93 H2PO4- 0.39106E-10 -10.4078 0.32687E-10 -10.4856 0.83585E+00 -0.0779 94 PO4-3 0.10519E-08 -8.9780 0.25489E-09 -9.5936 0.24232E+00 -0.6156 98 HP2O7-3 0.96188E-18 -18.0169 0.22212E-18 -18.6534 0.23092E+00 -0.6365 99 P2O7-4 0.91612E-17 -17.0380 0.70459E-18 -18.1521 0.76910E-01 -1.1140 100 H2S,aq 0.10130E-07 -7.9944 0.10095E-07 -7.9959 0.99653E+00 -0.0015 101 S2-2 0.22985E-13 -13.6386 0.11903E-13 -13.9243 0.51787E+00 -0.2858 107 SO3-2 0.69947E-16 -16.1552 0.36749E-16 -16.4348 0.52537E+00 -0.2795 108 HSO3- 0.20751E-18 -18.6830 0.17329E-18 -18.7612 0.83506E+00 -0.0783 109 HSO4- 0.69990E-17 -17.1550 0.58615E-17 -17.2320 0.83748E+00 -0.0770 111 S2O3-2 0.18493E-19 -19.7330 0.95768E-20 -20.0188 0.51787E+00 -0.2858 Charge balance for all species = -.6133E-08 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.8964327E-10 -.2219431E-01 -.2233159E+02 0.0000 2 H2O 0.1000000E+01 0.5550475E+02 0.9981940E+06 0.0000 3 Cl- 0.1585217E-03 0.1592496E-03 0.5636048E+01 6.2449 4 SO4-- 0.1556158E-09 -.1206124E-04 -.1156605E+01 10.1535 5 HCO3- 0.2554505E-04 0.8459368E-04 0.5152684E+01 5.4528 6 HS- 0.5192942E-04 0.6400095E-04 0.2112955E+01 5.7603 7 Al+++ 0.9882281E-29 0.5098852E-05 0.1373352E+00 0.7273 8 H4SiO4 0.7057754E-03 0.1353172E-01 0.1298342E+04 -3.1513 9 Ca++ 0.1156180E-06 0.2157315E-06 0.8631036E-02 13.0212 10 Mg++ 0.2116846E-10 0.9318130E-10 0.2261480E-05 9.2819 11 Fe++ 0.4524301E-13 0.2720711E-07 0.1516790E-02 6.6122 12 K+ 0.1565162E-03 0.1572589E-03 0.6138432E+01 6.2402 13 Na+ 0.1986316E-01 0.2230557E-01 0.5119080E+03 8.3428 14 Mn++ 0.1908711E-10 0.2507533E-08 0.1375190E-03 9.2378 15 F- 0.4972383E-06 0.4988478E-06 0.9460613E-02 3.7405 16 HPO4-- 0.4532878E-07 0.4641978E-07 0.4447569E-02 12.6179 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.1993286E-01 -.1993204E-01 -.8274934E-06 0.0000000E+00 2 H2O 0.4984712E+02 0.4984712E+02 -.7833843E-06 0.0000000E+00 3 Cl- 0.1430172E-03 0.1430172E-03 0.0000000E+00 0.0000000E+00 4 SO4-- -.1083081E-04 -.1083183E-04 0.1019799E-08 0.0000000E+00 5 HCO3- 0.7597100E-04 0.7597100E-04 0.0000000E+00 0.0000000E+00 6 HS- 0.5747628E-04 0.5747730E-04 -.1019799E-08 0.0000000E+00 7 Al+++ 0.4775352E-05 0.4579123E-05 0.1962290E-06 0.0000000E+00 8 H4SiO4 0.1215302E-01 0.1215242E-01 0.5988205E-06 0.0000000E+00 9 Ca++ 0.2080835E-06 0.1937419E-06 0.1434163E-07 0.0000000E+00 10 Mg++ 0.8368328E-10 0.8368328E-10 0.0000000E+00 0.0000000E+00 11 Fe++ 0.3259227E-07 0.2443387E-07 0.8158395E-08 0.0000000E+00 12 K+ 0.1412294E-03 0.1412294E-03 0.0000000E+00 0.0000000E+00 13 Na+ 0.2003215E-01 0.2003196E-01 0.1948263E-06 0.0000000E+00 14 Mn++ 0.2251939E-08 0.2251939E-08 0.0000000E+00 0.0000000E+00 15 F- 0.4480000E-06 0.4480000E-06 0.0000000E+00 0.0000000E+00 16 HPO4-- 0.4168819E-07 0.4168819E-07 0.0000000E+00 0.0000000E+00 Chg. balance for solid moles: 0.0000E+00 Mass of aqueous solution: 0.899636E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 0.0008700 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 0.1948E-06 -6.710 0.5109E-04 -4.292 95.53 0.1961E-04 andradite 0.4079E-08 -8.389 0.2073E-05 -5.683 3.876 0.5386E-06 grossular 0.7013E-09 -9.154 0.3159E-06 -6.500 0.5908 0.8790E-07 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8533E+00 0.8533E+00 1.0000 -0.069 grossular 0.1467E+00 0.1467E+00 1.0000 -0.834 Solid products produced: Mass = 0.000053 g Volume = 0.000020 cm3 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.0008700 moles log = -3.0605 Original solution: 1000.0103000 g Original solution / Rock added: 1149437.13 (Water/Rock Ratio), log = 6.0605 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0414 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9800E+00 0.9857 0.1006E+01 0.1021E+01 CO2,gas 0.3508E-06 1.0069 0.3678E-06 0.3653E-06 CH4,gas 0.1556E-01 1.0124 0.1640E-01 0.1620E-01 H2,gas 0.4412E-02 1.0006 0.4597E-02 0.4595E-02 H2S,gas 0.2676E-06 0.9960 0.2775E-06 0.2786E-06 S2,gas 0.1313E-27 1.0000 0.1368E-27 0.1368E-27 CO,gas 0.4327E-12 1.0000 0.4506E-12 0.4506E-12 SO3,gas 0.1663E-45 1.0000 0.1732E-45 0.1732E-45 SO2,gas 0.2975E-25 1.0000 0.3098E-25 0.3098E-25 HF,gas 0.5037E-15 1.0000 0.5245E-15 0.5245E-15 HCl,gas 0.3095E-17 1.0000 0.3224E-17 0.3224E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 17 albite -0.38 -0.38 0.00 0.000 -0.94784E-12 23 andradite 39.01 39.01 0.00 0.000 0.00000E+00 24 grossular 32.73 32.73 0.00 0.000 0.12132E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -14.79 -8.13 -2.711 0.13887E+05 -6.434 3 CH4,gas 4.54 1.06 -3.48 -0.871 0.59489E+04 -1.785 4 H2,gas 8.00 3.96 -4.04 -2.307 0.68922E+04 -2.338 5 H2S,gas -6.23 -14.49 -8.26 -4.128 0.14096E+05 -6.557 6 S2,gas -7.34 -36.90 -29.56 -4.548 0.50478E+05 -27.864 7 CO,gas 3.21 -10.83 -14.05 -4.322 0.23982E+05 -12.346 8 SO3,gas 17.12 -30.34 -47.46 -11.865 0.81037E+05 -45.761 9 SO2,gas 0.83 -26.38 -27.21 -7.255 0.46457E+05 -25.509 10 HF,gas 0.47 -16.51 -16.98 -8.490 0.28992E+05 -15.280 11 HCl,gas 5.19 -14.00 -19.19 -9.595 0.32767E+05 -17.492 12 acmite 7.71 6.67 -1.04 -0.108 0.17740E+04 16 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 20 spessartine 24.46 19.71 -4.74 -0.237 0.80991E+04 21 analcite 3.32 2.77 -0.55 -0.062 0.94661E+03 27 annite 20.12 17.35 -2.77 -0.154 0.47351E+04 28 phlogopite 27.06 25.36 -1.71 -0.095 0.29119E+04 30 anorthite 12.71 8.17 -4.54 -0.349 0.77470E+04 33 apatite-OH -18.15 -18.52 -0.36 -0.028 0.62219E+03 34 apatite-F -34.30 -35.02 -0.72 -0.060 0.12339E+04 38 aragonite 0.97 -1.77 -2.74 -0.913 0.46763E+04 39 brucite 12.57 9.28 -3.29 -0.657 0.56119E+04 40 calcite 0.81 -1.77 -2.58 -0.861 0.44121E+04 41 carnegieite-low 9.02 5.92 -3.10 -0.443 0.53008E+04 42 carnegieite-high 10.09 5.92 -4.17 -0.596 0.71278E+04 43 carpholite-Mg 8.58 4.43 -4.15 -0.277 0.70830E+04 44 carpholite-Fe 6.71 1.76 -4.95 -0.330 0.84493E+04 45 celadonite 5.34 3.64 -1.70 -0.100 0.28985E+04 46 celadonite-Fe 3.88 0.97 -2.90 -0.171 0.49553E+04 47 chrysotile 23.89 21.54 -2.35 -0.196 0.40114E+04 49 clinochlore 39.07 38.41 -0.66 -0.021 0.11258E+04 50 daphnite 28.97 25.06 -3.90 -0.122 0.66649E+04 52 chlorite-Al-free 47.17 43.09 -4.09 -0.170 0.69780E+04 54 chloritoid-Fe 9.17 4.92 -4.26 -0.284 0.72706E+04 55 chloritoid-Mn 11.40 7.54 -3.86 -0.257 0.65908E+04 57 coesite -2.38 -3.15 -0.78 -0.258 0.13238E+04 64 cristobalite -2.56 -3.15 -0.59 -0.197 0.10091E+04 66 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71235E+04 68 diaspore 2.87 0.73 -2.15 -0.358 0.36649E+04 69 diamond -3.10 -6.87 -3.76 -1.076 0.64278E+04 70 diopside 16.18 16.00 -0.18 -0.018 0.30883E+03 71 hedenbergite 14.21 13.33 -0.88 -0.088 0.14982E+04 76 clinoenstatite 17.17 12.26 -4.91 -0.491 0.83754E+04 78 epidote 24.67 22.67 -2.00 -0.097 0.34085E+04 79 clinozoisite 22.81 18.77 -4.04 -0.183 0.68907E+04 80 epidote-Fe 29.84 26.58 -3.26 -0.170 0.55728E+04 81 fayalite 14.05 10.07 -3.97 -0.568 0.67830E+04 82 ferrosilite 11.15 6.92 -4.23 -0.423 0.72185E+04 86 gibbsite 4.08 0.73 -3.35 -0.479 0.57235E+04 87 glaucophane 22.97 20.78 -2.20 -0.059 0.37555E+04 88 glaucophane-Fe 17.28 12.77 -4.51 -0.122 0.76998E+04 89 graphite -3.55 -6.87 -3.32 -0.949 0.56701E+04 90 greenalite 16.14 13.53 -2.61 -0.217 0.44487E+04 93 hematite 12.57 9.26 -3.30 -0.401 0.56431E+04 94 heulandite -5.83 -7.58 -1.76 -0.080 0.29987E+04 98 jadeite 4.22 2.77 -1.45 -0.145 0.24721E+04 100 kalsilite 7.58 3.82 -3.77 -0.538 0.64334E+04 101 kaolinite -1.33 -4.85 -3.52 -0.320 0.60023E+04 104 laumontite 2.88 1.87 -1.01 -0.068 0.17295E+04 105 lawsonite 9.62 8.17 -1.44 -0.096 0.24637E+04 106 leucite 4.12 0.66 -3.45 -0.345 0.58977E+04 108 lizardite 23.24 21.54 -1.70 -0.142 0.29040E+04 110 magnetite 20.09 15.87 -4.21 -0.344 0.71952E+04 111 minnesotaite 10.39 7.23 -3.16 -0.186 0.53900E+04 115 manganosite 14.06 9.24 -4.82 -1.205 0.82306E+04 119 microcline -2.49 -2.49 0.00 0.000 0.73703E-01 123 muscovite 2.58 -1.03 -3.61 -0.213 0.61714E+04 124 paragonite 4.24 1.07 -3.17 -0.186 0.54104E+04 125 nepheline 8.34 5.92 -2.42 -0.346 0.41332E+04 137 phlogopite-Na 29.65 27.46 -2.18 -0.121 0.37307E+04 139 prehnite 19.37 18.04 -1.33 -0.078 0.22689E+04 140 prehnite-Fe 22.50 21.95 -0.55 -0.033 0.94161E+03 141 pumpellyite-Fe 46.27 43.43 -2.84 -0.063 0.48555E+04 142 pumpellyite-Mg 48.99 46.10 -2.90 -0.064 0.49508E+04 146 pyrrhotite -4.26 -7.87 -3.61 -1.204 0.61697E+04 147 pyrrhotiteFe0.875 -6.02 -9.19 -3.17 -1.168 0.54208E+04 148 pyroxmangite 7.40 6.09 -1.31 -0.262 0.22406E+04 149 pyrophyllite -6.18 -11.15 -4.97 -0.311 0.84945E+04 150 quartz -2.99 -3.15 -0.16 -0.054 0.27644E+03 154 rhodochrosite -0.98 -5.56 -4.58 -1.526 0.78191E+04 155 rhodonite 7.45 6.09 -1.36 -0.272 0.23208E+04 156 sanidine -1.28 -2.49 -1.21 -0.093 0.20678E+04 166 stilbite -7.52 -7.58 -0.06 -0.003 0.10489E+03 167 stilpnomelane-Fe 13.02 12.43 -0.59 -0.018 0.10103E+04 168 stilpnomelane-Mg 27.44 25.77 -1.67 -0.050 0.28478E+04 174 talc 16.49 15.24 -1.25 -0.074 0.21355E+04 177 tephroite 18.09 15.32 -2.76 -0.395 0.47152E+04 181 tridymite -2.63 -3.15 -0.52 -0.175 0.89641E+03 182 tremolite 47.87 47.24 -0.63 -0.017 0.10721E+04 183 ferroactinolite 38.45 33.89 -4.56 -0.123 0.77849E+04 184 troilite-low -4.41 -7.87 -3.46 -1.154 0.59125E+04 190 wairakite 3.95 1.87 -2.08 -0.122 0.35514E+04 191 walstromite 11.51 9.87 -1.64 -0.328 0.27991E+04 192 wollastonite 10.46 9.87 -0.59 -0.118 0.10095E+04 193 pseudo-wollastonite 11.00 9.87 -1.13 -0.226 0.19294E+04 194 zoisite 22.85 18.77 -4.08 -0.185 0.69648E+04 195 akaganeite 7.75 4.63 -3.12 -0.675 0.53341E+04 202 chalcedony -2.80 -3.15 -0.35 -0.116 0.59573E+03 204 montmorillonite-Ca -2.29 -6.18 -3.89 -0.241 0.66395E+04 205 montmorillonite-K -2.24 -6.27 -4.03 -0.247 0.68841E+04 206 montmorillonite-Mg -2.48 -6.80 -4.32 -0.267 0.73700E+04 207 montmorillonite-Na -2.04 -5.57 -3.54 -0.217 0.60389E+04 208 nontronite-Ca 3.21 0.08 -3.13 -0.203 0.53447E+04 209 nontronite-H 2.53 -2.06 -4.60 -0.308 0.78490E+04 210 nontronite-K 3.34 0.00 -3.35 -0.215 0.57125E+04 211 nontronite-Mg 3.07 -0.53 -3.61 -0.234 0.61593E+04 212 nontronite-Na 3.52 0.69 -2.83 -0.182 0.48334E+04 228 tobermorite 9.82 7.70 -2.13 -0.581 0.36330E+04 234 alabandite -0.98 -5.25 -4.27 -1.423 0.72914E+04 237 boehmite 4.41 0.73 -3.68 -0.613 0.62818E+04 239 ferrous-oxide 9.81 6.61 -3.20 -0.800 0.54628E+04 245 silica-amorphous -2.09 -3.15 -1.06 -0.353 0.18099E+04 247 an20ab80 2.02 1.33 -0.69 -0.053 0.11786E+04 248 an25ab75 2.65 1.76 -0.89 -0.068 0.15202E+04 249 an30ab70 3.28 2.18 -1.10 -0.084 0.18714E+04 250 tr.625ac.25prg.125 45.16 44.85 -0.32 -0.009 0.54170E+03 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 0.0000400 MOLES Current total amount of reactant added: 0.0008700 MOLES New total amount of reactant added: 0.0009100 MOLES Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.5508E-08 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 7 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 0.0009100 Water: Moles liquid = 0.4985E+02 kg liquid = 0.8981E+00 Moles total = 0.4985E+02 kg total = 0.8980E+00 Activity = 1.0000 Stoichiometric ionic strength = .1138827E-01 Osmotic coef. = 0.9665 True ionic strength = .2007036E-01 Chg. balance for total moles = -.5508E-08 Max. difference allowed = 0.1433E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.89707E-10 -10.0472 0.75365E-10 -10.1228 0.84012E+00 -0.0757 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.15878E-03 -3.7992 0.13259E-03 -3.8775 0.83506E+00 -0.0783 4 SO4-- 0.16934E-09 -9.7712 0.87881E-10 -10.0561 0.51896E+00 -0.2849 5 HCO3- 0.26747E-04 -4.5727 0.22368E-04 -4.6504 0.83628E+00 -0.0776 6 HS- 0.53011E-04 -4.2756 0.44274E-04 -4.3539 0.83518E+00 -0.0782 7 Al+++ 0.98913E-29 -29.0047 0.22817E-29 -29.6417 0.23067E+00 -0.6370 8 H4SiO4 0.70624E-03 -3.1510 0.70624E-03 -3.1510 0.10000E+01 0.0000 9 Ca++ 0.11519E-06 -6.9386 0.59337E-07 -7.2267 0.51514E+00 -0.2881 10 Mg++ 0.21171E-10 -10.6743 0.10856E-10 -10.9643 0.51278E+00 -0.2901 11 Fe++ 0.45312E-13 -13.3438 0.23261E-13 -13.6334 0.51334E+00 -0.2896 12 K+ 0.15652E-03 -3.8054 0.13092E-03 -3.8830 0.83648E+00 -0.0775 13 Na+ 0.19863E-01 -1.7019 0.16584E-01 -1.7803 0.83490E+00 -0.0784 14 Mn++ 0.19113E-10 -10.7187 0.98198E-11 -11.0079 0.51377E+00 -0.2892 15 F- 0.51500E-06 -6.2882 0.42916E-06 -6.3674 0.83333E+00 -0.0792 16 HPO4-- 0.45329E-07 -7.3436 0.23527E-07 -7.6284 0.51903E+00 -0.2848 18 HSiO3- 0.10478E-01 -1.9797 0.87501E-02 -2.0580 0.83506E+00 -0.0783 19 Ca(HSiO3)+ 0.14133E-07 -7.8498 0.11824E-07 -7.9272 0.83666E+00 -0.0775 20 Mg(HSiO3)+ 0.32179E-11 -11.4924 0.26922E-11 -11.5699 0.83666E+00 -0.0775 21 NaHSiO3,aq 0.23470E-02 -2.6295 0.23470E-02 -2.6295 0.10000E+01 0.0000 22 AlO+ 0.65320E-16 -16.1850 0.54651E-16 -16.2624 0.83666E+00 -0.0775 24 HAlO2,aq 0.14441E-09 -9.8404 0.14441E-09 -9.8404 0.10000E+01 0.0000 25 AlO2- 0.50886E-05 -5.2934 0.42416E-05 -5.3725 0.83354E+00 -0.0791 26 CH4,aq 0.10984E-04 -4.9592 0.10946E-04 -4.9607 0.99653E+00 -0.0015 27 C2H6,aq 0.59658E-14 -14.2243 0.59451E-14 -14.2258 0.99653E+00 -0.0015 31 CO,aq 0.31177E-15 -15.5062 0.31177E-15 -15.5062 0.10000E+01 0.0000 32 CO2,aq 0.36146E-08 -8.4419 0.36020E-08 -8.4435 0.99653E+00 -0.0015 33 CO3-2 0.50060E-04 -4.3005 0.25924E-04 -4.5863 0.51785E+00 -0.2858 34 CaCO3,aq 0.19288E-07 -7.7147 0.19288E-07 -7.7147 0.10000E+01 0.0000 35 Ca(HCO3)+ 0.40493E-10 -10.3926 0.33879E-10 -10.4701 0.83666E+00 -0.0775 36 CaCl+ 0.15218E-10 -10.8176 0.12732E-10 -10.8951 0.83666E+00 -0.0775 37 CaCl2,aq 0.40109E-15 -15.3968 0.40109E-15 -15.3968 0.10000E+01 0.0000 38 CaF+ 0.44438E-12 -12.3522 0.37180E-12 -12.4297 0.83666E+00 -0.0775 39 CaOH+ 0.67068E-07 -7.1735 0.56113E-07 -7.2509 0.83666E+00 -0.0775 40 CaSO4,aq 0.16559E-14 -14.7810 0.16559E-14 -14.7810 0.10000E+01 0.0000 41 HCl,aq 0.18311E-14 -14.7373 0.18311E-14 -14.7373 0.10000E+01 0.0000 45 HF,aq 0.22142E-12 -12.6548 0.22142E-12 -12.6548 0.10000E+01 0.0000 46 HF2- 0.38419E-19 -19.4155 0.32082E-19 -19.4937 0.83506E+00 -0.0783 48 FeCl+ 0.58348E-17 -17.2340 0.48818E-17 -17.3114 0.83666E+00 -0.0775 51 FeF+ 0.60972E-18 -18.2149 0.51013E-18 -18.2923 0.83666E+00 -0.0775 53 FeO,aq 0.15917E-09 -9.7981 0.15917E-09 -9.7981 0.10000E+01 0.0000 54 FeOH+ 0.12008E-10 -10.9205 0.10047E-10 -10.9980 0.83666E+00 -0.0775 55 HFeO2- 0.26462E-07 -7.5774 0.22098E-07 -7.6557 0.83506E+00 -0.0783 56 FeO+ 0.15430E-16 -16.8116 0.12910E-16 -16.8891 0.83666E+00 -0.0775 58 FeO2- 0.55695E-09 -9.2542 0.46508E-09 -9.3325 0.83506E+00 -0.0783 59 HFeO2,aq 0.44579E-11 -11.3509 0.44579E-11 -11.3509 0.10000E+01 0.0000 60 H2,aq 0.34575E-05 -5.4612 0.34455E-05 -5.4627 0.99653E+00 -0.0015 61 KCl,aq 0.31463E-09 -9.5022 0.31463E-09 -9.5022 0.10000E+01 0.0000 63 KOH,aq 0.74188E-06 -6.1297 0.74188E-06 -6.1297 0.10000E+01 0.0000 64 KSO4- 0.21380E-12 -12.6700 0.17854E-12 -12.7483 0.83506E+00 -0.0783 65 MgCO3,aq 0.88451E-12 -12.0533 0.88451E-12 -12.0533 0.10000E+01 0.0000 66 Mg(HCO3)+ 0.75700E-14 -14.1209 0.63335E-14 -14.1984 0.83666E+00 -0.0775 67 MgCl+ 0.25235E-14 -14.5980 0.21113E-14 -14.6755 0.83666E+00 -0.0775 68 MgF+ 0.30116E-15 -15.5212 0.25197E-15 -15.5986 0.83666E+00 -0.0775 69 MgOH+ 0.67898E-10 -10.1681 0.56807E-10 -10.2456 0.83666E+00 -0.0775 71 MnF+ 0.84842E-16 -16.0714 0.70984E-16 -16.1488 0.83666E+00 -0.0775 72 MnO,aq 0.17904E-08 -8.7470 0.17904E-08 -8.7470 0.10000E+01 0.0000 73 MnOH+ 0.47092E-09 -9.3270 0.39400E-09 -9.4045 0.83666E+00 -0.0775 74 MnO2-2 0.20202E-10 -10.6946 0.10461E-10 -10.9804 0.51785E+00 -0.2858 75 HMnO2- 0.20685E-09 -9.6843 0.17273E-09 -9.7626 0.83506E+00 -0.0783 78 MnCl+ 0.95832E-14 -14.0185 0.80178E-14 -14.0959 0.83666E+00 -0.0775 79 MnSO4,aq 0.24913E-18 -18.6036 0.24913E-18 -18.6036 0.10000E+01 0.0000 80 NaCl,aq 0.72872E-06 -6.1374 0.72872E-06 -6.1374 0.10000E+01 0.0000 81 NaF,aq 0.16663E-08 -8.7783 0.16663E-08 -8.7783 0.10000E+01 0.0000 82 NaOH,aq 0.94544E-04 -4.0244 0.94544E-04 -4.0244 0.10000E+01 0.0000 84 OH- 0.91973E-02 -2.0363 0.76664E-02 -2.1154 0.83354E+00 -0.0791 89 HPO3-2 0.48783E-15 -15.3117 0.25262E-15 -15.5975 0.51785E+00 -0.2858 91 H2PO3- 0.45720E-19 -19.3399 0.38179E-19 -19.4182 0.83506E+00 -0.0783 92 H3PO4,aq 0.93461E-18 -18.0294 0.93461E-18 -18.0294 0.10000E+01 0.0000 93 H2PO4- 0.39133E-10 -10.4075 0.32709E-10 -10.4853 0.83585E+00 -0.0779 94 PO4-3 0.10512E-08 -8.9783 0.25470E-09 -9.5940 0.24230E+00 -0.6156 98 HP2O7-3 0.96260E-18 -18.0166 0.22227E-18 -18.6531 0.23091E+00 -0.6366 99 P2O7-4 0.91620E-17 -17.0380 0.70456E-18 -18.1521 0.76900E-01 -1.1141 100 H2S,aq 0.10348E-07 -7.9851 0.10312E-07 -7.9866 0.99653E+00 -0.0015 101 S2-2 0.24343E-13 -13.6136 0.12606E-13 -13.8994 0.51785E+00 -0.2858 107 SO3-2 0.74898E-16 -16.1255 0.39348E-16 -16.4051 0.52536E+00 -0.2795 108 HSO3- 0.22235E-18 -18.6530 0.18567E-18 -18.7312 0.83506E+00 -0.0783 109 HSO4- 0.76215E-17 -17.1180 0.63828E-17 -17.1950 0.83747E+00 -0.0770 111 S2O3-2 0.20557E-19 -19.6870 0.10646E-19 -19.9728 0.51785E+00 -0.2858 Charge balance for all species = -.6133E-08 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.8970740E-10 -.2218946E-01 -.2232671E+02 0.0000 2 H2O 0.1000000E+01 0.5550474E+02 0.9981938E+06 0.0000 3 Cl- 0.1587832E-03 0.1595123E-03 0.5645343E+01 6.2454 4 SO4-- 0.1693409E-09 -.1184855E-04 -.1136209E+01 10.1896 5 HCO3- 0.2674666E-04 0.8781385E-04 0.5348827E+01 5.4725 6 HS- 0.5301147E-04 0.6487054E-04 0.2141664E+01 5.7690 7 Al+++ 0.9891340E-29 0.5088778E-05 0.1370638E+00 0.7267 8 H4SiO4 0.7062428E-03 0.1353168E-01 0.1298338E+04 -3.1510 9 Ca++ 0.1151871E-06 0.2157321E-06 0.8631058E-02 13.0190 10 Mg++ 0.2117082E-10 0.9318122E-10 0.2261478E-05 9.2813 11 Fe++ 0.4531232E-13 0.2719498E-07 0.1516114E-02 6.6123 12 K+ 0.1565166E-03 0.1572588E-03 0.6138427E+01 6.2398 13 Na+ 0.1986330E-01 0.2230555E-01 0.5119073E+03 8.3425 14 Mn++ 0.1911327E-10 0.2507531E-08 0.1375189E-03 9.2378 15 F- 0.5149965E-06 0.5166634E-06 0.9798483E-02 3.7555 16 HPO4-- 0.4532941E-07 0.4641975E-07 0.4447564E-02 12.6172 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.1992856E-01 -.1992769E-01 -.8636958E-06 0.0000000E+00 2 H2O 0.4984715E+02 0.4984715E+02 -.8196070E-06 0.0000000E+00 3 Cl- 0.1432532E-03 0.1432532E-03 0.0000000E+00 0.0000000E+00 4 SO4-- -.1063981E-04 -.1064083E-04 0.1021158E-08 0.0000000E+00 5 HCO3- 0.7886300E-04 0.7886300E-04 0.0000000E+00 0.0000000E+00 6 HS- 0.5825728E-04 0.5825830E-04 -.1021158E-08 0.0000000E+00 7 Al+++ 0.4775352E-05 0.4570080E-05 0.2052720E-06 0.0000000E+00 8 H4SiO4 0.1215302E-01 0.1215239E-01 0.6259827E-06 0.0000000E+00 9 Ca++ 0.2080835E-06 0.1937425E-06 0.1434096E-07 0.0000000E+00 10 Mg++ 0.8368328E-10 0.8368328E-10 0.0000000E+00 0.0000000E+00 11 Fe++ 0.3259227E-07 0.2442300E-07 0.8169267E-08 0.0000000E+00 12 K+ 0.1412294E-03 0.1412294E-03 0.0000000E+00 0.0000000E+00 13 Na+ 0.2003215E-01 0.2003195E-01 0.2038806E-06 0.0000000E+00 14 Mn++ 0.2251939E-08 0.2251939E-08 0.0000000E+00 0.0000000E+00 15 F- 0.4640000E-06 0.4640000E-06 0.0000000E+00 0.0000000E+00 16 HPO4-- 0.4168819E-07 0.4168819E-07 0.0000000E+00 0.0000000E+00 Chg. balance for solid moles: 0.2647E-22 Mass of aqueous solution: 0.899636E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 0.0009100 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 0.2039E-06 -6.691 0.5346E-04 -4.272 95.72 0.2052E-04 andradite 0.4085E-08 -8.389 0.2076E-05 -5.683 3.717 0.5393E-06 grossular 0.6957E-09 -9.158 0.3134E-06 -6.504 0.5611 0.8719E-07 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8545E+00 0.8545E+00 1.0000 -0.068 grossular 0.1455E+00 0.1455E+00 1.0000 -0.837 Solid products produced: Mass = 0.000056 g Volume = 0.000021 cm3 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.0009100 moles log = -3.0410 Original solution: 1000.0103000 g Original solution / Rock added: 1098912.42 (Water/Rock Ratio), log = 6.0410 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0410 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9804E+00 0.9857 0.1006E+01 0.1021E+01 CO2,gas 0.3677E-06 1.0069 0.3854E-06 0.3827E-06 CH4,gas 0.1529E-01 1.0124 0.1611E-01 0.1592E-01 H2,gas 0.4343E-02 1.0006 0.4524E-02 0.4521E-02 H2S,gas 0.2734E-06 0.9960 0.2835E-06 0.2846E-06 S2,gas 0.1416E-27 1.0000 0.1474E-27 0.1474E-27 CO,gas 0.4463E-12 1.0000 0.4646E-12 0.4646E-12 SO3,gas 0.1813E-45 1.0000 0.1887E-45 0.1887E-45 SO2,gas 0.3191E-25 1.0000 0.3321E-25 0.3321E-25 HF,gas 0.5222E-15 1.0000 0.5437E-15 0.5437E-15 HCl,gas 0.3104E-17 1.0000 0.3231E-17 0.3231E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 17 albite -0.38 -0.38 0.00 0.000 -0.94784E-12 23 andradite 39.01 39.01 0.00 0.000 -0.24265E-10 24 grossular 32.73 32.73 0.00 0.000 -0.48529E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -14.77 -8.11 -2.704 0.13853E+05 -6.414 3 CH4,gas 4.54 1.05 -3.49 -0.873 0.59622E+04 -1.793 4 H2,gas 8.00 3.96 -4.04 -2.311 0.69041E+04 -2.345 5 H2S,gas -6.23 -14.48 -8.25 -4.123 0.14081E+05 -6.547 6 S2,gas -7.34 -36.87 -29.53 -4.543 0.50422E+05 -27.831 7 CO,gas 3.21 -10.82 -14.03 -4.318 0.23959E+05 -12.333 8 SO3,gas 17.12 -30.30 -47.42 -11.856 0.80974E+05 -45.724 9 SO2,gas 0.83 -26.35 -27.18 -7.247 0.46405E+05 -25.479 10 HF,gas 0.47 -16.49 -16.96 -8.482 0.28965E+05 -15.265 11 HCl,gas 5.19 -14.00 -19.19 -9.595 0.32766E+05 -17.491 12 acmite 7.71 6.67 -1.04 -0.108 0.17675E+04 16 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 20 spessartine 24.46 19.71 -4.74 -0.237 0.80997E+04 21 analcite 3.32 2.77 -0.55 -0.062 0.94710E+03 27 annite 20.12 17.35 -2.77 -0.154 0.47350E+04 28 phlogopite 27.06 25.36 -1.71 -0.095 0.29149E+04 30 anorthite 12.71 8.17 -4.54 -0.349 0.77518E+04 33 apatite-OH -18.15 -18.53 -0.37 -0.029 0.63829E+03 34 apatite-F -34.30 -35.02 -0.72 -0.060 0.12235E+04 38 aragonite 0.97 -1.75 -2.72 -0.907 0.46456E+04 39 brucite 12.57 9.28 -3.29 -0.657 0.56129E+04 40 calcite 0.81 -1.75 -2.57 -0.855 0.43814E+04 41 carnegieite-low 9.02 5.92 -3.11 -0.444 0.53018E+04 42 carnegieite-high 10.09 5.92 -4.18 -0.596 0.71288E+04 43 carpholite-Mg 8.58 4.43 -4.15 -0.277 0.70849E+04 44 carpholite-Fe 6.71 1.76 -4.95 -0.330 0.84502E+04 45 celadonite 5.34 3.64 -1.70 -0.100 0.28990E+04 46 celadonite-Fe 3.88 0.97 -2.90 -0.171 0.49548E+04 47 chrysotile 23.89 21.54 -2.35 -0.196 0.40134E+04 49 clinochlore 39.07 38.41 -0.66 -0.021 0.11312E+04 50 daphnite 28.97 25.06 -3.90 -0.122 0.66650E+04 52 chlorite-Al-free 47.17 43.08 -4.09 -0.170 0.69820E+04 54 chloritoid-Fe 9.17 4.91 -4.26 -0.284 0.72719E+04 55 chloritoid-Mn 11.40 7.54 -3.86 -0.257 0.65923E+04 57 coesite -2.38 -3.15 -0.77 -0.258 0.13233E+04 64 cristobalite -2.56 -3.15 -0.59 -0.197 0.10086E+04 66 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71235E+04 68 diaspore 2.87 0.73 -2.15 -0.358 0.36659E+04 69 diamond -3.10 -6.86 -3.76 -1.074 0.64172E+04 70 diopside 16.18 16.00 -0.18 -0.018 0.31268E+03 71 hedenbergite 14.21 13.33 -0.88 -0.088 0.15010E+04 76 clinoenstatite 17.17 12.26 -4.91 -0.491 0.83764E+04 78 epidote 24.67 22.67 -2.00 -0.097 0.34105E+04 79 clinozoisite 22.81 18.77 -4.04 -0.184 0.68998E+04 80 epidote-Fe 29.84 26.58 -3.26 -0.169 0.55679E+04 81 fayalite 14.05 10.07 -3.97 -0.567 0.67824E+04 82 ferrosilite 11.15 6.92 -4.23 -0.423 0.72174E+04 86 gibbsite 4.08 0.73 -3.35 -0.479 0.57244E+04 87 glaucophane 22.97 20.77 -2.20 -0.059 0.37575E+04 88 glaucophane-Fe 17.28 12.77 -4.51 -0.122 0.76986E+04 89 graphite -3.55 -6.86 -3.31 -0.947 0.56594E+04 90 greenalite 16.14 13.53 -2.60 -0.217 0.44475E+04 93 hematite 12.57 9.27 -3.30 -0.400 0.56310E+04 94 heulandite -5.83 -7.58 -1.76 -0.080 0.30010E+04 98 jadeite 4.22 2.77 -1.45 -0.145 0.24726E+04 100 kalsilite 7.58 3.82 -3.77 -0.538 0.64344E+04 101 kaolinite -1.33 -4.85 -3.52 -0.320 0.60032E+04 104 laumontite 2.88 1.87 -1.02 -0.068 0.17333E+04 105 lawsonite 9.62 8.17 -1.45 -0.096 0.24684E+04 106 leucite 4.12 0.66 -3.45 -0.345 0.58982E+04 108 lizardite 23.24 21.54 -1.70 -0.142 0.29060E+04 110 magnetite 20.09 15.88 -4.21 -0.343 0.71830E+04 111 minnesotaite 10.39 7.23 -3.16 -0.186 0.53878E+04 115 manganosite 14.06 9.24 -4.82 -1.205 0.82306E+04 119 microcline -2.49 -2.49 0.00 0.000 0.77134E-01 123 muscovite 2.58 -1.03 -3.62 -0.213 0.61733E+04 124 paragonite 4.24 1.07 -3.17 -0.186 0.54123E+04 125 nepheline 8.34 5.92 -2.42 -0.346 0.41342E+04 137 phlogopite-Na 29.65 27.46 -2.19 -0.121 0.37336E+04 139 prehnite 19.37 18.04 -1.33 -0.078 0.22770E+04 140 prehnite-Fe 22.50 21.95 -0.55 -0.033 0.94272E+03 141 pumpellyite-Fe 46.27 43.42 -2.85 -0.063 0.48726E+04 142 pumpellyite-Mg 48.99 46.08 -2.91 -0.065 0.49689E+04 146 pyrrhotite -4.26 -7.86 -3.60 -1.201 0.61539E+04 147 pyrrhotiteFe0.875 -6.02 -9.18 -3.16 -1.164 0.54034E+04 148 pyroxmangite 7.40 6.09 -1.31 -0.262 0.22401E+04 149 pyrophyllite -6.18 -11.15 -4.97 -0.311 0.84945E+04 150 quartz -2.99 -3.15 -0.16 -0.054 0.27595E+03 154 rhodochrosite -0.98 -5.54 -4.56 -1.520 0.77846E+04 155 rhodonite 7.45 6.09 -1.36 -0.272 0.23204E+04 156 sanidine -1.28 -2.49 -1.21 -0.093 0.20678E+04 166 stilbite -7.52 -7.58 -0.06 -0.003 0.10719E+03 167 stilpnomelane-Fe 13.02 12.43 -0.59 -0.018 0.10082E+04 168 stilpnomelane-Mg 27.44 25.77 -1.67 -0.050 0.28509E+04 174 talc 16.49 15.24 -1.25 -0.074 0.21365E+04 177 tephroite 18.09 15.32 -2.76 -0.394 0.47149E+04 181 tridymite -2.63 -3.15 -0.52 -0.175 0.89592E+03 182 tremolite 47.87 47.24 -0.63 -0.017 0.10808E+04 183 ferroactinolite 38.45 33.89 -4.56 -0.123 0.77883E+04 184 troilite-low -4.41 -7.86 -3.45 -1.151 0.58967E+04 190 wairakite 3.95 1.87 -2.08 -0.122 0.35552E+04 191 walstromite 11.51 9.87 -1.64 -0.328 0.28024E+04 192 wollastonite 10.46 9.87 -0.59 -0.119 0.10129E+04 193 pseudo-wollastonite 11.00 9.87 -1.13 -0.226 0.19327E+04 194 zoisite 22.85 18.77 -4.08 -0.186 0.69738E+04 195 akaganeite 7.75 4.63 -3.12 -0.675 0.53281E+04 202 chalcedony -2.80 -3.15 -0.35 -0.116 0.59524E+03 204 montmorillonite-Ca -2.29 -6.18 -3.89 -0.241 0.66401E+04 205 montmorillonite-K -2.24 -6.27 -4.03 -0.247 0.68842E+04 206 montmorillonite-Mg -2.48 -6.80 -4.32 -0.267 0.73701E+04 207 montmorillonite-Na -2.04 -5.57 -3.54 -0.217 0.60391E+04 208 nontronite-Ca 3.21 0.09 -3.12 -0.203 0.53318E+04 209 nontronite-H 2.53 -2.06 -4.59 -0.308 0.78354E+04 210 nontronite-K 3.34 0.00 -3.34 -0.214 0.56991E+04 211 nontronite-Mg 3.07 -0.52 -3.60 -0.234 0.61459E+04 212 nontronite-Na 3.52 0.70 -2.82 -0.181 0.48200E+04 228 tobermorite 9.82 7.69 -2.13 -0.581 0.36357E+04 234 alabandite -0.98 -5.24 -4.26 -1.420 0.72756E+04 237 boehmite 4.41 0.73 -3.68 -0.613 0.62828E+04 239 ferrous-oxide 9.81 6.61 -3.20 -0.800 0.54627E+04 245 silica-amorphous -2.09 -3.15 -1.06 -0.353 0.18094E+04 247 an20ab80 2.02 1.33 -0.69 -0.053 0.11795E+04 248 an25ab75 2.65 1.75 -0.89 -0.069 0.15214E+04 249 an30ab70 3.28 2.18 -1.10 -0.084 0.18728E+04 250 tr.625ac.25prg.125 45.16 44.84 -0.32 -0.009 0.54951E+03 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 0.0000400 MOLES Current total amount of reactant added: 0.0009100 MOLES New total amount of reactant added: 0.0009500 MOLES Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.5508E-08 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 7 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 0.0009500 Water: Moles liquid = 0.4985E+02 kg liquid = 0.8981E+00 Moles total = 0.4985E+02 kg total = 0.8980E+00 Activity = 1.0000 Stoichiometric ionic strength = .1139082E-01 Osmotic coef. = 0.9664 True ionic strength = .2007272E-01 Chg. balance for total moles = -.5508E-08 Max. difference allowed = 0.1435E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.89772E-10 -10.0469 0.75418E-10 -10.1225 0.84011E+00 -0.0757 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.15904E-03 -3.7985 0.13281E-03 -3.8768 0.83505E+00 -0.0783 4 SO4-- 0.18391E-09 -9.7354 0.95436E-10 -10.0203 0.51894E+00 -0.2849 5 HCO3- 0.27950E-04 -4.5536 0.23373E-04 -4.6313 0.83627E+00 -0.0777 6 HS- 0.54094E-04 -4.2669 0.45177E-04 -4.3451 0.83517E+00 -0.0782 7 Al+++ 0.99004E-29 -29.0043 0.22836E-29 -29.6414 0.23066E+00 -0.6370 8 H4SiO4 0.70671E-03 -3.1508 0.70671E-03 -3.1508 0.10000E+01 0.0000 9 Ca++ 0.11476E-06 -6.9402 0.59117E-07 -7.2283 0.51512E+00 -0.2881 10 Mg++ 0.21173E-10 -10.6742 0.10857E-10 -10.9643 0.51276E+00 -0.2901 11 Fe++ 0.45387E-13 -13.3431 0.23298E-13 -13.6327 0.51332E+00 -0.2896 12 K+ 0.15652E-03 -3.8054 0.13092E-03 -3.8830 0.83647E+00 -0.0775 13 Na+ 0.19863E-01 -1.7019 0.16584E-01 -1.7803 0.83490E+00 -0.0784 14 Mn++ 0.19139E-10 -10.7181 0.98329E-11 -11.0073 0.51375E+00 -0.2892 15 F- 0.53275E-06 -6.2735 0.44396E-06 -6.3527 0.83332E+00 -0.0792 16 HPO4-- 0.45330E-07 -7.3436 0.23527E-07 -7.6284 0.51901E+00 -0.2848 18 HSiO3- 0.10478E-01 -1.9797 0.87497E-02 -2.0580 0.83505E+00 -0.0783 19 Ca(HSiO3)+ 0.14080E-07 -7.8514 0.11780E-07 -7.9289 0.83665E+00 -0.0775 20 Mg(HSiO3)+ 0.32180E-11 -11.4924 0.26923E-11 -11.5699 0.83665E+00 -0.0775 21 NaHSiO3,aq 0.23469E-02 -2.6295 0.23469E-02 -2.6295 0.10000E+01 0.0000 22 AlO+ 0.65283E-16 -16.1852 0.54619E-16 -16.2627 0.83665E+00 -0.0775 24 HAlO2,aq 0.14423E-09 -9.8410 0.14423E-09 -9.8410 0.10000E+01 0.0000 25 AlO2- 0.50786E-05 -5.2943 0.42332E-05 -5.3733 0.83354E+00 -0.0791 26 CH4,aq 0.10785E-04 -4.9672 0.10748E-04 -4.9687 0.99653E+00 -0.0015 27 C2H6,aq 0.58427E-14 -14.2334 0.58224E-14 -14.2349 0.99653E+00 -0.0015 31 CO,aq 0.32093E-15 -15.4936 0.32093E-15 -15.4936 0.10000E+01 0.0000 32 CO2,aq 0.37798E-08 -8.4225 0.37666E-08 -8.4240 0.99653E+00 -0.0015 33 CO3-2 0.52275E-04 -4.2817 0.27070E-04 -4.5675 0.51784E+00 -0.2858 34 CaCO3,aq 0.20066E-07 -7.6975 0.20066E-07 -7.6975 0.10000E+01 0.0000 35 Ca(HCO3)+ 0.42157E-10 -10.3751 0.35271E-10 -10.4526 0.83665E+00 -0.0775 36 CaCl+ 0.15187E-10 -10.8185 0.12706E-10 -10.8960 0.83665E+00 -0.0775 37 CaCl2,aq 0.40091E-15 -15.3970 0.40091E-15 -15.3970 0.10000E+01 0.0000 38 CaF+ 0.45800E-12 -12.3391 0.38318E-12 -12.4166 0.83665E+00 -0.0775 39 CaOH+ 0.66772E-07 -7.1754 0.55865E-07 -7.2529 0.83665E+00 -0.0775 40 CaSO4,aq 0.17916E-14 -14.7468 0.17916E-14 -14.7468 0.10000E+01 0.0000 41 HCl,aq 0.18354E-14 -14.7363 0.18354E-14 -14.7363 0.10000E+01 0.0000 45 HF,aq 0.22921E-12 -12.6398 0.22921E-12 -12.6398 0.10000E+01 0.0000 46 HF2- 0.41143E-19 -19.3857 0.34357E-19 -19.4640 0.83505E+00 -0.0783 48 FeCl+ 0.58539E-17 -17.2326 0.48977E-17 -17.3100 0.83665E+00 -0.0775 51 FeF+ 0.63177E-18 -18.1994 0.52857E-18 -18.2769 0.83665E+00 -0.0775 53 FeO,aq 0.15920E-09 -9.7981 0.15920E-09 -9.7981 0.10000E+01 0.0000 54 FeOH+ 0.12019E-10 -10.9201 0.10056E-10 -10.9976 0.83665E+00 -0.0775 55 HFeO2- 0.26449E-07 -7.5776 0.22086E-07 -7.6559 0.83505E+00 -0.0783 56 FeO+ 0.15566E-16 -16.8078 0.13024E-16 -16.8853 0.83665E+00 -0.0775 58 FeO2- 0.56107E-09 -9.2510 0.46852E-09 -9.3293 0.83505E+00 -0.0783 59 HFeO2,aq 0.44941E-11 -11.3474 0.44941E-11 -11.3474 0.10000E+01 0.0000 60 H2,aq 0.34035E-05 -5.4681 0.33917E-05 -5.4696 0.99653E+00 -0.0015 61 KCl,aq 0.31514E-09 -9.5015 0.31514E-09 -9.5015 0.10000E+01 0.0000 63 KOH,aq 0.74135E-06 -6.1300 0.74135E-06 -6.1300 0.10000E+01 0.0000 64 KSO4- 0.23219E-12 -12.6342 0.19389E-12 -12.7124 0.83505E+00 -0.0783 65 MgCO3,aq 0.92370E-12 -12.0345 0.92370E-12 -12.0345 0.10000E+01 0.0000 66 Mg(HCO3)+ 0.79111E-14 -14.1018 0.66188E-14 -14.1792 0.83665E+00 -0.0775 67 MgCl+ 0.25278E-14 -14.5973 0.21149E-14 -14.6747 0.83665E+00 -0.0775 68 MgF+ 0.31157E-15 -15.5064 0.26068E-15 -15.5839 0.83665E+00 -0.0775 69 MgOH+ 0.67856E-10 -10.1684 0.56771E-10 -10.2459 0.83665E+00 -0.0775 71 MnF+ 0.87885E-16 -16.0561 0.73529E-16 -16.1335 0.83665E+00 -0.0775 72 MnO,aq 0.17903E-08 -8.7471 0.17903E-08 -8.7471 0.10000E+01 0.0000 73 MnOH+ 0.47122E-09 -9.3268 0.39425E-09 -9.4042 0.83665E+00 -0.0775 74 MnO2-2 0.20172E-10 -10.6952 0.10446E-10 -10.9811 0.51784E+00 -0.2858 75 HMnO2- 0.20669E-09 -9.6847 0.17260E-09 -9.7630 0.83505E+00 -0.0783 78 MnCl+ 0.96118E-14 -14.0172 0.80417E-14 -14.0947 0.83665E+00 -0.0775 79 MnSO4,aq 0.27091E-18 -18.5672 0.27091E-18 -18.5672 0.10000E+01 0.0000 80 NaCl,aq 0.72992E-06 -6.1367 0.72992E-06 -6.1367 0.10000E+01 0.0000 81 NaF,aq 0.17237E-08 -8.7635 0.17237E-08 -8.7635 0.10000E+01 0.0000 82 NaOH,aq 0.94477E-04 -4.0247 0.94477E-04 -4.0247 0.10000E+01 0.0000 84 OH- 0.91909E-02 -2.0366 0.76609E-02 -2.1157 0.83354E+00 -0.0791 89 HPO3-2 0.48021E-15 -15.3186 0.24867E-15 -15.6044 0.51784E+00 -0.2858 91 H2PO3- 0.45037E-19 -19.3464 0.37608E-19 -19.4247 0.83505E+00 -0.0783 92 H3PO4,aq 0.93592E-18 -18.0288 0.93592E-18 -18.0288 0.10000E+01 0.0000 93 H2PO4- 0.39161E-10 -10.4071 0.32732E-10 -10.4850 0.83584E+00 -0.0779 94 PO4-3 0.10505E-08 -8.9786 0.25452E-09 -9.5943 0.24228E+00 -0.6157 98 HP2O7-3 0.96331E-18 -18.0162 0.22242E-18 -18.6528 0.23089E+00 -0.6366 99 P2O7-4 0.91629E-17 -17.0380 0.70454E-18 -18.1521 0.76891E-01 -1.1141 100 H2S,aq 0.10567E-07 -7.9760 0.10530E-07 -7.9776 0.99653E+00 -0.0015 101 S2-2 0.25749E-13 -13.5892 0.13334E-13 -13.8750 0.51784E+00 -0.2858 107 SO3-2 0.80069E-16 -16.0965 0.42063E-16 -16.3761 0.52534E+00 -0.2796 108 HSO3- 0.23786E-18 -18.6237 0.19863E-18 -18.7020 0.83505E+00 -0.0783 109 HSO4- 0.82827E-17 -17.0818 0.69365E-17 -17.1589 0.83747E+00 -0.0770 111 S2O3-2 0.22797E-19 -19.6421 0.11805E-19 -19.9279 0.51784E+00 -0.2858 Charge balance for all species = -.6133E-08 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.8977161E-10 -.2218461E-01 -.2232182E+02 0.0000 2 H2O 0.1000000E+01 0.5550474E+02 0.9981935E+06 0.0000 3 Cl- 0.1590447E-03 0.1597749E-03 0.5654638E+01 6.2458 4 SO4-- 0.1839060E-09 -.1163587E-04 -.1115814E+01 10.2248 5 HCO3- 0.2794954E-04 0.9103402E-04 0.5544970E+01 5.4912 6 HS- 0.5409352E-04 0.6574014E-04 0.2170372E+01 5.7774 7 Al+++ 0.9900412E-29 0.5078719E-05 0.1367929E+00 0.7262 8 H4SiO4 0.7067107E-03 0.1353163E-01 0.1298334E+04 -3.1508 9 Ca++ 0.1147624E-06 0.2157378E-06 0.8631286E-02 13.0168 10 Mg++ 0.2117319E-10 0.9318115E-10 0.2261476E-05 9.2808 11 Fe++ 0.4538714E-13 0.2718598E-07 0.1515612E-02 6.6124 12 K+ 0.1565170E-03 0.1572586E-03 0.6138421E+01 6.2395 13 Na+ 0.1986345E-01 0.2230552E-01 0.5119066E+03 8.3422 14 Mn++ 0.1913949E-10 0.2507529E-08 0.1375188E-03 9.2377 15 F- 0.5327546E-06 0.5344790E-06 0.1013635E-01 3.7699 16 HPO4-- 0.4533004E-07 0.4641971E-07 0.4447560E-02 12.6166 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.1992425E-01 -.1992335E-01 -.8998330E-06 0.0000000E+00 2 H2O 0.4984719E+02 0.4984719E+02 -.8557785E-06 0.0000000E+00 3 Cl- 0.1434892E-03 0.1434892E-03 0.0000000E+00 0.0000000E+00 4 SO4-- -.1044881E-04 -.1044983E-04 0.1022166E-08 0.0000000E+00 5 HCO3- 0.8175500E-04 0.8175500E-04 0.0000000E+00 0.0000000E+00 6 HS- 0.5903828E-04 0.5903930E-04 -.1022166E-08 0.0000000E+00 7 Al+++ 0.4775352E-05 0.4561050E-05 0.2143022E-06 0.0000000E+00 8 H4SiO4 0.1215302E-01 0.1215237E-01 0.6531030E-06 0.0000000E+00 9 Ca++ 0.2080835E-06 0.1937478E-06 0.1433566E-07 0.0000000E+00 10 Mg++ 0.8368328E-10 0.8368328E-10 0.0000000E+00 0.0000000E+00 11 Fe++ 0.3259227E-07 0.2441494E-07 0.8177329E-08 0.0000000E+00 12 K+ 0.1412294E-03 0.1412294E-03 0.0000000E+00 0.0000000E+00 13 Na+ 0.2003215E-01 0.2003194E-01 0.2129225E-06 0.0000000E+00 14 Mn++ 0.2251939E-08 0.2251939E-08 0.0000000E+00 0.0000000E+00 15 F- 0.4800000E-06 0.4800000E-06 0.0000000E+00 0.0000000E+00 16 HPO4-- 0.4168819E-07 0.4168819E-07 0.0000000E+00 0.0000000E+00 Chg. balance for solid moles: 0.2647E-22 Mass of aqueous solution: 0.899637E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 0.0009500 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 0.2129E-06 -6.672 0.5583E-04 -4.253 95.90 0.2143E-04 andradite 0.4089E-08 -8.388 0.2078E-05 -5.682 3.569 0.5398E-06 grossular 0.6899E-09 -9.161 0.3108E-06 -6.508 0.5338 0.8647E-07 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8556E+00 0.8556E+00 1.0000 -0.068 grossular 0.1444E+00 0.1444E+00 1.0000 -0.841 Solid products produced: Mass = 0.000058 g Volume = 0.000022 cm3 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.0009500 moles log = -3.0223 Original solution: 1000.0103000 g Original solution / Rock added: 1052642.42 (Water/Rock Ratio), log = 6.0223 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0407 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9807E+00 0.9857 0.1006E+01 0.1021E+01 CO2,gas 0.3846E-06 1.0069 0.4030E-06 0.4002E-06 CH4,gas 0.1502E-01 1.0124 0.1582E-01 0.1563E-01 H2,gas 0.4277E-02 1.0006 0.4453E-02 0.4450E-02 H2S,gas 0.2793E-06 0.9960 0.2895E-06 0.2906E-06 S2,gas 0.1524E-27 1.0000 0.1586E-27 0.1586E-27 CO,gas 0.4596E-12 1.0000 0.4782E-12 0.4782E-12 SO3,gas 0.1972E-45 1.0000 0.2052E-45 0.2052E-45 SO2,gas 0.3417E-25 1.0000 0.3556E-25 0.3556E-25 HF,gas 0.5408E-15 1.0000 0.5628E-15 0.5628E-15 HCl,gas 0.3112E-17 1.0000 0.3239E-17 0.3239E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 17 albite -0.38 -0.38 0.00 0.000 0.23317E-10 23 andradite 39.01 39.01 0.00 0.000 -0.12132E-10 24 grossular 32.73 32.73 0.00 0.000 -0.12132E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -14.75 -8.09 -2.698 0.13820E+05 -6.395 3 CH4,gas 4.54 1.04 -3.50 -0.875 0.59758E+04 -1.801 4 H2,gas 8.00 3.95 -4.05 -2.314 0.69158E+04 -2.351 5 H2S,gas -6.23 -14.47 -8.24 -4.119 0.14065E+05 -6.538 6 S2,gas -7.34 -36.83 -29.50 -4.538 0.50368E+05 -27.800 7 CO,gas 3.21 -10.80 -14.02 -4.314 0.23938E+05 -12.320 8 SO3,gas 17.12 -30.27 -47.39 -11.847 0.80911E+05 -45.688 9 SO2,gas 0.83 -26.32 -27.15 -7.239 0.46355E+05 -25.449 10 HF,gas 0.47 -16.48 -16.95 -8.474 0.28939E+05 -15.250 11 HCl,gas 5.19 -14.00 -19.19 -9.594 0.32764E+05 -17.490 12 acmite 7.71 6.68 -1.03 -0.107 0.17610E+04 16 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 20 spessartine 24.46 19.71 -4.74 -0.237 0.81003E+04 21 analcite 3.32 2.77 -0.55 -0.062 0.94760E+03 27 annite 20.12 17.35 -2.77 -0.154 0.47345E+04 28 phlogopite 27.06 25.36 -1.71 -0.095 0.29179E+04 30 anorthite 12.71 8.17 -4.54 -0.349 0.77565E+04 33 apatite-OH -18.15 -18.54 -0.38 -0.029 0.65424E+03 34 apatite-F -34.30 -35.01 -0.71 -0.059 0.12138E+04 38 aragonite 0.97 -1.74 -2.70 -0.901 0.46163E+04 39 brucite 12.57 9.28 -3.29 -0.658 0.56139E+04 40 calcite 0.81 -1.74 -2.55 -0.850 0.43520E+04 41 carnegieite-low 9.02 5.92 -3.11 -0.444 0.53028E+04 42 carnegieite-high 10.09 5.92 -4.18 -0.597 0.71298E+04 43 carpholite-Mg 8.58 4.43 -4.15 -0.277 0.70868E+04 44 carpholite-Fe 6.71 1.76 -4.95 -0.330 0.84509E+04 45 celadonite 5.34 3.64 -1.70 -0.100 0.28995E+04 46 celadonite-Fe 3.88 0.98 -2.90 -0.171 0.49541E+04 47 chrysotile 23.89 21.54 -2.35 -0.196 0.40154E+04 49 clinochlore 39.07 38.40 -0.67 -0.021 0.11366E+04 50 daphnite 28.97 25.06 -3.90 -0.122 0.66647E+04 52 chlorite-Al-free 47.17 43.08 -4.09 -0.170 0.69859E+04 54 chloritoid-Fe 9.17 4.91 -4.26 -0.284 0.72732E+04 55 chloritoid-Mn 11.40 7.54 -3.86 -0.257 0.65938E+04 57 coesite -2.38 -3.15 -0.77 -0.258 0.13228E+04 64 cristobalite -2.56 -3.15 -0.59 -0.197 0.10081E+04 66 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71235E+04 68 diaspore 2.87 0.73 -2.15 -0.358 0.36668E+04 69 diamond -3.10 -6.85 -3.75 -1.072 0.64074E+04 70 diopside 16.18 16.00 -0.19 -0.019 0.31650E+03 71 hedenbergite 14.21 13.33 -0.88 -0.088 0.15037E+04 76 clinoenstatite 17.17 12.26 -4.91 -0.491 0.83774E+04 78 epidote 24.67 22.67 -2.00 -0.097 0.34126E+04 79 clinozoisite 22.81 18.76 -4.05 -0.184 0.69088E+04 80 epidote-Fe 29.84 26.58 -3.26 -0.169 0.55630E+04 81 fayalite 14.05 10.07 -3.97 -0.567 0.67816E+04 82 ferrosilite 11.15 6.92 -4.23 -0.423 0.72162E+04 86 gibbsite 4.08 0.73 -3.35 -0.479 0.57253E+04 87 glaucophane 22.97 20.77 -2.20 -0.060 0.37595E+04 88 glaucophane-Fe 17.28 12.77 -4.51 -0.122 0.76972E+04 89 graphite -3.55 -6.85 -3.31 -0.945 0.56496E+04 90 greenalite 16.14 13.54 -2.60 -0.217 0.44461E+04 93 hematite 12.57 9.28 -3.29 -0.399 0.56191E+04 94 heulandite -5.83 -7.59 -1.76 -0.080 0.30033E+04 98 jadeite 4.22 2.77 -1.45 -0.145 0.24731E+04 100 kalsilite 7.58 3.81 -3.77 -0.538 0.64353E+04 101 kaolinite -1.33 -4.85 -3.52 -0.320 0.60041E+04 104 laumontite 2.88 1.87 -1.02 -0.068 0.17370E+04 105 lawsonite 9.62 8.17 -1.45 -0.097 0.24732E+04 106 leucite 4.12 0.66 -3.45 -0.345 0.58987E+04 108 lizardite 23.24 21.54 -1.70 -0.142 0.29080E+04 110 magnetite 20.09 15.89 -4.20 -0.343 0.71709E+04 111 minnesotaite 10.39 7.23 -3.15 -0.186 0.53854E+04 115 manganosite 14.06 9.24 -4.82 -1.205 0.82307E+04 119 microcline -2.49 -2.49 0.00 0.000 0.80569E-01 123 muscovite 2.58 -1.03 -3.62 -0.213 0.61752E+04 124 paragonite 4.24 1.07 -3.17 -0.187 0.54142E+04 125 nepheline 8.34 5.92 -2.42 -0.346 0.41352E+04 137 phlogopite-Na 29.65 27.46 -2.19 -0.122 0.37366E+04 139 prehnite 19.37 18.03 -1.34 -0.079 0.22850E+04 140 prehnite-Fe 22.50 21.95 -0.55 -0.033 0.94383E+03 141 pumpellyite-Fe 46.27 43.41 -2.86 -0.064 0.48895E+04 142 pumpellyite-Mg 48.99 46.07 -2.92 -0.065 0.49869E+04 146 pyrrhotite -4.26 -7.86 -3.59 -1.198 0.61382E+04 147 pyrrhotiteFe0.875 -6.02 -9.17 -3.15 -1.160 0.53863E+04 148 pyroxmangite 7.40 6.09 -1.31 -0.262 0.22397E+04 149 pyrophyllite -6.18 -11.15 -4.97 -0.311 0.84944E+04 150 quartz -2.99 -3.15 -0.16 -0.054 0.27545E+03 154 rhodochrosite -0.98 -5.52 -4.54 -1.513 0.77515E+04 155 rhodonite 7.45 6.09 -1.36 -0.272 0.23200E+04 156 sanidine -1.28 -2.49 -1.21 -0.093 0.20678E+04 166 stilbite -7.52 -7.59 -0.06 -0.003 0.10946E+03 167 stilpnomelane-Fe 13.02 12.43 -0.59 -0.018 0.10057E+04 168 stilpnomelane-Mg 27.44 25.77 -1.67 -0.050 0.28541E+04 174 talc 16.49 15.24 -1.25 -0.074 0.21375E+04 177 tephroite 18.09 15.32 -2.76 -0.394 0.47145E+04 181 tridymite -2.63 -3.15 -0.52 -0.175 0.89543E+03 182 tremolite 47.87 47.23 -0.64 -0.017 0.10894E+04 183 ferroactinolite 38.45 33.89 -4.56 -0.123 0.77913E+04 184 troilite-low -4.41 -7.86 -3.44 -1.148 0.58810E+04 190 wairakite 3.95 1.87 -2.08 -0.123 0.35590E+04 191 walstromite 11.51 9.87 -1.64 -0.329 0.28058E+04 192 wollastonite 10.46 9.87 -0.60 -0.119 0.10162E+04 193 pseudo-wollastonite 11.00 9.87 -1.13 -0.227 0.19360E+04 194 zoisite 22.85 18.76 -4.09 -0.186 0.69828E+04 195 akaganeite 7.75 4.64 -3.12 -0.674 0.53221E+04 202 chalcedony -2.80 -3.15 -0.35 -0.116 0.59475E+03 204 montmorillonite-Ca -2.29 -6.18 -3.89 -0.241 0.66406E+04 205 montmorillonite-K -2.24 -6.27 -4.03 -0.247 0.68843E+04 206 montmorillonite-Mg -2.48 -6.80 -4.32 -0.267 0.73702E+04 207 montmorillonite-Na -2.04 -5.57 -3.54 -0.217 0.60392E+04 208 nontronite-Ca 3.21 0.10 -3.12 -0.202 0.53189E+04 209 nontronite-H 2.53 -2.05 -4.58 -0.307 0.78220E+04 210 nontronite-K 3.34 0.01 -3.33 -0.214 0.56858E+04 211 nontronite-Mg 3.07 -0.52 -3.59 -0.233 0.61326E+04 212 nontronite-Na 3.52 0.70 -2.82 -0.181 0.48067E+04 228 tobermorite 9.82 7.69 -2.13 -0.581 0.36384E+04 234 alabandite -0.98 -5.23 -4.25 -1.417 0.72602E+04 237 boehmite 4.41 0.73 -3.68 -0.613 0.62837E+04 239 ferrous-oxide 9.81 6.61 -3.20 -0.800 0.54626E+04 245 silica-amorphous -2.09 -3.15 -1.06 -0.353 0.18089E+04 247 an20ab80 2.02 1.33 -0.69 -0.053 0.11805E+04 248 an25ab75 2.65 1.75 -0.89 -0.069 0.15225E+04 249 an30ab70 3.28 2.18 -1.10 -0.084 0.18742E+04 250 tr.625ac.25prg.125 45.16 44.84 -0.33 -0.009 0.55716E+03 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 0.0000400 MOLES Current total amount of reactant added: 0.0009500 MOLES New total amount of reactant added: 0.0009900 MOLES Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.5508E-08 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 7 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 0.0009900 Water: Moles liquid = 0.4985E+02 kg liquid = 0.8981E+00 Moles total = 0.4985E+02 kg total = 0.8980E+00 Activity = 1.0000 Stoichiometric ionic strength = .1139337E-01 Osmotic coef. = 0.9663 True ionic strength = .2007508E-01 Chg. balance for total moles = -.5508E-08 Max. difference allowed = 0.1437E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.89836E-10 -10.0466 0.75472E-10 -10.1222 0.84011E+00 -0.0757 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.15931E-03 -3.7978 0.13303E-03 -3.8761 0.83504E+00 -0.0783 4 SO4-- 0.19936E-09 -9.7004 0.10345E-09 -9.9853 0.51892E+00 -0.2849 5 HCO3- 0.29154E-04 -4.5353 0.24380E-04 -4.6130 0.83627E+00 -0.0777 6 HS- 0.55176E-04 -4.2583 0.46081E-04 -4.3365 0.83517E+00 -0.0782 7 Al+++ 0.99095E-29 -29.0039 0.22855E-29 -29.6410 0.23064E+00 -0.6371 8 H4SiO4 0.70718E-03 -3.1505 0.70718E-03 -3.1505 0.10000E+01 0.0000 9 Ca++ 0.11434E-06 -6.9418 0.58899E-07 -7.2299 0.51511E+00 -0.2881 10 Mg++ 0.21176E-10 -10.6742 0.10858E-10 -10.9643 0.51275E+00 -0.2901 11 Fe++ 0.45467E-13 -13.3423 0.23338E-13 -13.6319 0.51331E+00 -0.2896 12 K+ 0.15652E-03 -3.8054 0.13092E-03 -3.8830 0.83647E+00 -0.0776 13 Na+ 0.19864E-01 -1.7019 0.16584E-01 -1.7803 0.83489E+00 -0.0784 14 Mn++ 0.19166E-10 -10.7175 0.98461E-11 -11.0067 0.51374E+00 -0.2893 15 F- 0.55051E-06 -6.2592 0.45875E-06 -6.3384 0.83332E+00 -0.0792 16 HPO4-- 0.45331E-07 -7.3436 0.23527E-07 -7.6284 0.51900E+00 -0.2848 18 HSiO3- 0.10478E-01 -1.9797 0.87493E-02 -2.0580 0.83504E+00 -0.0783 19 Ca(HSiO3)+ 0.14027E-07 -7.8530 0.11736E-07 -7.9305 0.83665E+00 -0.0775 20 Mg(HSiO3)+ 0.32181E-11 -11.4924 0.26924E-11 -11.5699 0.83665E+00 -0.0775 21 NaHSiO3,aq 0.23468E-02 -2.6295 0.23468E-02 -2.6295 0.10000E+01 0.0000 22 AlO+ 0.65247E-16 -16.1854 0.54588E-16 -16.2629 0.83665E+00 -0.0775 24 HAlO2,aq 0.14404E-09 -9.8415 0.14404E-09 -9.8415 0.10000E+01 0.0000 25 AlO2- 0.50685E-05 -5.2951 0.42248E-05 -5.3742 0.83353E+00 -0.0791 26 CH4,aq 0.10586E-04 -4.9753 0.10549E-04 -4.9768 0.99653E+00 -0.0015 27 C2H6,aq 0.57157E-14 -14.2429 0.56958E-14 -14.2444 0.99653E+00 -0.0015 31 CO,aq 0.32987E-15 -15.4817 0.32987E-15 -15.4817 0.10000E+01 0.0000 32 CO2,aq 0.39454E-08 -8.4039 0.39317E-08 -8.4054 0.99653E+00 -0.0015 33 CO3-2 0.54490E-04 -4.2637 0.28216E-04 -4.5495 0.51782E+00 -0.2858 34 CaCO3,aq 0.20838E-07 -7.6811 0.20838E-07 -7.6811 0.10000E+01 0.0000 35 Ca(HCO3)+ 0.43812E-10 -10.3584 0.36655E-10 -10.4359 0.83665E+00 -0.0775 36 CaCl+ 0.15156E-10 -10.8194 0.12680E-10 -10.8969 0.83665E+00 -0.0775 37 CaCl2,aq 0.40074E-15 -15.3971 0.40074E-15 -15.3971 0.10000E+01 0.0000 38 CaF+ 0.47152E-12 -12.3265 0.39450E-12 -12.4040 0.83665E+00 -0.0775 39 CaOH+ 0.66479E-07 -7.1773 0.55620E-07 -7.2548 0.83665E+00 -0.0775 40 CaSO4,aq 0.19349E-14 -14.7133 0.19349E-14 -14.7133 0.10000E+01 0.0000 41 HCl,aq 0.18397E-14 -14.7352 0.18397E-14 -14.7352 0.10000E+01 0.0000 45 HF,aq 0.23702E-12 -12.6252 0.23702E-12 -12.6252 0.10000E+01 0.0000 46 HF2- 0.43963E-19 -19.3569 0.36711E-19 -19.4352 0.83504E+00 -0.0783 48 FeCl+ 0.58736E-17 -17.2311 0.49142E-17 -17.3086 0.83665E+00 -0.0775 51 FeF+ 0.65395E-18 -18.1845 0.54712E-18 -18.2619 0.83665E+00 -0.0775 53 FeO,aq 0.15925E-09 -9.7979 0.15925E-09 -9.7979 0.10000E+01 0.0000 54 FeOH+ 0.12031E-10 -10.9197 0.10066E-10 -10.9971 0.83665E+00 -0.0775 55 HFeO2- 0.26439E-07 -7.5778 0.22077E-07 -7.6561 0.83504E+00 -0.0783 56 FeO+ 0.15703E-16 -16.8040 0.13138E-16 -16.8815 0.83665E+00 -0.0775 58 FeO2- 0.56518E-09 -9.2478 0.47195E-09 -9.3261 0.83504E+00 -0.0783 59 HFeO2,aq 0.45302E-11 -11.3439 0.45302E-11 -11.3439 0.10000E+01 0.0000 60 H2,aq 0.33515E-05 -5.4748 0.33399E-05 -5.4763 0.99653E+00 -0.0015 61 KCl,aq 0.31565E-09 -9.5008 0.31565E-09 -9.5008 0.10000E+01 0.0000 63 KOH,aq 0.74082E-06 -6.1303 0.74082E-06 -6.1303 0.10000E+01 0.0000 64 KSO4- 0.25169E-12 -12.5991 0.21017E-12 -12.6774 0.83504E+00 -0.0783 65 MgCO3,aq 0.96288E-12 -12.0164 0.96288E-12 -12.0164 0.10000E+01 0.0000 66 Mg(HCO3)+ 0.82526E-14 -14.0834 0.69045E-14 -14.1609 0.83665E+00 -0.0775 67 MgCl+ 0.25322E-14 -14.5965 0.21185E-14 -14.6740 0.83665E+00 -0.0775 68 MgF+ 0.32199E-15 -15.4922 0.26939E-15 -15.5696 0.83665E+00 -0.0775 69 MgOH+ 0.67813E-10 -10.1687 0.56736E-10 -10.2461 0.83665E+00 -0.0775 71 MnF+ 0.90936E-16 -16.0413 0.76081E-16 -16.1187 0.83665E+00 -0.0775 72 MnO,aq 0.17902E-08 -8.7471 0.17902E-08 -8.7471 0.10000E+01 0.0000 73 MnOH+ 0.47153E-09 -9.3265 0.39450E-09 -9.4040 0.83665E+00 -0.0775 74 MnO2-2 0.20143E-10 -10.6959 0.10430E-10 -10.9817 0.51782E+00 -0.2858 75 HMnO2- 0.20653E-09 -9.6850 0.17246E-09 -9.7633 0.83504E+00 -0.0783 78 MnCl+ 0.96405E-14 -14.0159 0.80657E-14 -14.0934 0.83665E+00 -0.0775 79 MnSO4,aq 0.29407E-18 -18.5316 0.29407E-18 -18.5316 0.10000E+01 0.0000 80 NaCl,aq 0.73111E-06 -6.1360 0.73111E-06 -6.1360 0.10000E+01 0.0000 81 NaF,aq 0.17812E-08 -8.7493 0.17812E-08 -8.7493 0.10000E+01 0.0000 82 NaOH,aq 0.94410E-04 -4.0250 0.94410E-04 -4.0250 0.10000E+01 0.0000 84 OH- 0.91844E-02 -2.0369 0.76555E-02 -2.1160 0.83353E+00 -0.0791 89 HPO3-2 0.47288E-15 -15.3252 0.24487E-15 -15.6111 0.51782E+00 -0.2858 91 H2PO3- 0.44380E-19 -19.3528 0.37059E-19 -19.4311 0.83504E+00 -0.0783 92 H3PO4,aq 0.93724E-18 -18.0282 0.93724E-18 -18.0282 0.10000E+01 0.0000 93 H2PO4- 0.39188E-10 -10.4068 0.32755E-10 -10.4847 0.83584E+00 -0.0779 94 PO4-3 0.10498E-08 -8.9789 0.25434E-09 -9.5946 0.24227E+00 -0.6157 98 HP2O7-3 0.96403E-18 -18.0159 0.22257E-18 -18.6525 0.23087E+00 -0.6366 99 P2O7-4 0.91637E-17 -17.0379 0.70452E-18 -18.1521 0.76881E-01 -1.1142 100 H2S,aq 0.10786E-07 -7.9671 0.10749E-07 -7.9687 0.99653E+00 -0.0015 101 S2-2 0.27206E-13 -13.5653 0.14088E-13 -13.8512 0.51782E+00 -0.2858 107 SO3-2 0.85471E-16 -16.0682 0.44900E-16 -16.3478 0.52533E+00 -0.2796 108 HSO3- 0.25409E-18 -18.5950 0.21217E-18 -18.6733 0.83504E+00 -0.0783 109 HSO4- 0.89849E-17 -17.0465 0.75245E-17 -17.1235 0.83746E+00 -0.0770 111 S2O3-2 0.25225E-19 -19.5982 0.13062E-19 -19.8840 0.51782E+00 -0.2858 Charge balance for all species = -.6133E-08 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.8983590E-10 -.2217975E-01 -.2231693E+02 0.0000 2 H2O 0.1000000E+01 0.5550473E+02 0.9981933E+06 0.0000 3 Cl- 0.1593061E-03 0.1600376E-03 0.5663933E+01 6.2462 4 SO4-- 0.1993603E-09 -.1142318E-04 -.1095418E+01 10.2592 5 HCO3- 0.2915367E-04 0.9425418E-04 0.5741112E+01 5.5093 6 HS- 0.5517556E-04 0.6660973E-04 0.2199081E+01 5.7857 7 Al+++ 0.9909497E-29 0.5068674E-05 0.1365223E+00 0.7256 8 H4SiO4 0.7071792E-03 0.1353159E-01 0.1298330E+04 -3.1505 9 Ca++ 0.1143433E-06 0.2157480E-06 0.8631691E-02 13.0145 10 Mg++ 0.2117556E-10 0.9318108E-10 0.2261474E-05 9.2802 11 Fe++ 0.4546679E-13 0.2717971E-07 0.1515262E-02 6.6125 12 K+ 0.1565174E-03 0.1572585E-03 0.6138416E+01 6.2392 13 Na+ 0.1986360E-01 0.2230549E-01 0.5119059E+03 8.3419 14 Mn++ 0.1916576E-10 0.2507527E-08 0.1375187E-03 9.2377 15 F- 0.5505126E-06 0.5522945E-06 0.1047422E-01 3.7838 16 HPO4-- 0.4533067E-07 0.4641967E-07 0.4447556E-02 12.6160 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.1991994E-01 -.1991901E-01 -.9359066E-06 0.0000000E+00 2 H2O 0.4984722E+02 0.4984722E+02 -.8918983E-06 0.0000000E+00 3 Cl- 0.1437252E-03 0.1437252E-03 0.0000000E+00 0.0000000E+00 4 SO4-- -.1025781E-04 -.1025883E-04 0.1022869E-08 0.0000000E+00 5 HCO3- 0.8464700E-04 0.8464700E-04 0.0000000E+00 0.0000000E+00 6 HS- 0.5981928E-04 0.5982030E-04 -.1022869E-08 0.0000000E+00 7 Al+++ 0.4775352E-05 0.4552032E-05 0.2233197E-06 0.0000000E+00 8 H4SiO4 0.1215302E-01 0.1215234E-01 0.6801815E-06 0.0000000E+00 9 Ca++ 0.2080835E-06 0.1937571E-06 0.1432638E-07 0.0000000E+00 10 Mg++ 0.8368328E-10 0.8368328E-10 0.0000000E+00 0.0000000E+00 11 Fe++ 0.3259227E-07 0.2440932E-07 0.8182949E-08 0.0000000E+00 12 K+ 0.1412294E-03 0.1412294E-03 0.0000000E+00 0.0000000E+00 13 Na+ 0.2003215E-01 0.2003193E-01 0.2219517E-06 0.0000000E+00 14 Mn++ 0.2251939E-08 0.2251939E-08 0.0000000E+00 0.0000000E+00 15 F- 0.4960000E-06 0.4960000E-06 0.0000000E+00 0.0000000E+00 16 HPO4-- 0.4168819E-07 0.4168819E-07 0.0000000E+00 0.0000000E+00 Chg. balance for solid moles: 0.0000E+00 Mass of aqueous solution: 0.899638E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 0.0009900 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 0.2220E-06 -6.654 0.5820E-04 -4.235 96.06 0.2234E-04 andradite 0.4091E-08 -8.388 0.2079E-05 -5.682 3.432 0.5402E-06 grossular 0.6840E-09 -9.165 0.3081E-06 -6.511 0.5085 0.8573E-07 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8568E+00 0.8568E+00 1.0000 -0.067 grossular 0.1432E+00 0.1432E+00 1.0000 -0.844 Solid products produced: Mass = 0.000061 g Volume = 0.000023 cm3 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.0009900 moles log = -3.0044 Original solution: 1000.0103000 g Original solution / Rock added: 1010111.41 (Water/Rock Ratio), log = 6.0044 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0403 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9810E+00 0.9857 0.1006E+01 0.1021E+01 CO2,gas 0.4016E-06 1.0069 0.4206E-06 0.4178E-06 CH4,gas 0.1474E-01 1.0124 0.1553E-01 0.1534E-01 H2,gas 0.4213E-02 1.0006 0.4385E-02 0.4382E-02 H2S,gas 0.2852E-06 0.9960 0.2955E-06 0.2967E-06 S2,gas 0.1638E-27 1.0000 0.1704E-27 0.1704E-27 CO,gas 0.4725E-12 1.0000 0.4916E-12 0.4916E-12 SO3,gas 0.2142E-45 1.0000 0.2228E-45 0.2228E-45 SO2,gas 0.3654E-25 1.0000 0.3801E-25 0.3801E-25 HF,gas 0.5594E-15 1.0000 0.5820E-15 0.5820E-15 HCl,gas 0.3121E-17 1.0000 0.3246E-17 0.3246E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 17 albite -0.38 -0.38 0.00 0.000 -0.13080E-10 23 andradite 39.01 39.01 0.00 0.000 0.12132E-10 24 grossular 32.73 32.73 0.00 0.000 -0.36397E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -14.74 -8.08 -2.692 0.13788E+05 -6.376 3 CH4,gas 4.54 1.04 -3.51 -0.877 0.59896E+04 -1.809 4 H2,gas 8.00 3.94 -4.06 -2.318 0.69272E+04 -2.358 5 H2S,gas -6.23 -14.46 -8.23 -4.114 0.14050E+05 -6.529 6 S2,gas -7.34 -36.80 -29.47 -4.533 0.50315E+05 -27.768 7 CO,gas 3.21 -10.79 -14.01 -4.310 0.23917E+05 -12.308 8 SO3,gas 17.12 -30.23 -47.35 -11.838 0.80851E+05 -45.652 9 SO2,gas 0.83 -26.29 -27.12 -7.232 0.46305E+05 -25.420 10 HF,gas 0.47 -16.46 -16.93 -8.467 0.28914E+05 -15.235 11 HCl,gas 5.19 -14.00 -19.19 -9.594 0.32762E+05 -17.489 12 acmite 7.71 6.68 -1.03 -0.107 0.17546E+04 16 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 20 spessartine 24.46 19.71 -4.74 -0.237 0.81009E+04 21 analcite 3.32 2.77 -0.56 -0.062 0.94809E+03 27 annite 20.12 17.35 -2.77 -0.154 0.47338E+04 28 phlogopite 27.06 25.35 -1.71 -0.095 0.29208E+04 30 anorthite 12.71 8.16 -4.55 -0.350 0.77612E+04 33 apatite-OH -18.15 -18.55 -0.39 -0.030 0.67006E+03 34 apatite-F -34.30 -35.01 -0.71 -0.059 0.12047E+04 38 aragonite 0.97 -1.72 -2.69 -0.896 0.45882E+04 39 brucite 12.57 9.28 -3.29 -0.658 0.56148E+04 40 calcite 0.81 -1.72 -2.53 -0.844 0.43240E+04 41 carnegieite-low 9.02 5.92 -3.11 -0.444 0.53038E+04 42 carnegieite-high 10.09 5.92 -4.18 -0.597 0.71308E+04 43 carpholite-Mg 8.58 4.43 -4.15 -0.277 0.70887E+04 44 carpholite-Fe 6.71 1.76 -4.95 -0.330 0.84516E+04 45 celadonite 5.34 3.64 -1.70 -0.100 0.29001E+04 46 celadonite-Fe 3.88 0.98 -2.90 -0.171 0.49534E+04 47 chrysotile 23.89 21.54 -2.35 -0.196 0.40174E+04 49 clinochlore 39.07 38.40 -0.67 -0.021 0.11420E+04 50 daphnite 28.97 25.06 -3.90 -0.122 0.66640E+04 52 chlorite-Al-free 47.17 43.08 -4.09 -0.171 0.69899E+04 54 chloritoid-Fe 9.17 4.91 -4.26 -0.284 0.72744E+04 55 chloritoid-Mn 11.40 7.54 -3.86 -0.258 0.65952E+04 57 coesite -2.38 -3.15 -0.77 -0.258 0.13223E+04 64 cristobalite -2.56 -3.15 -0.59 -0.197 0.10076E+04 66 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71235E+04 68 diaspore 2.87 0.73 -2.15 -0.358 0.36677E+04 69 diamond -3.10 -6.85 -3.75 -1.071 0.63984E+04 70 diopside 16.18 15.99 -0.19 -0.019 0.32030E+03 71 hedenbergite 14.21 13.33 -0.88 -0.088 0.15063E+04 76 clinoenstatite 17.17 12.26 -4.91 -0.491 0.83784E+04 78 epidote 24.67 22.67 -2.00 -0.097 0.34147E+04 79 clinozoisite 22.81 18.75 -4.05 -0.184 0.69177E+04 80 epidote-Fe 29.84 26.59 -3.26 -0.169 0.55582E+04 81 fayalite 14.05 10.07 -3.97 -0.567 0.67807E+04 82 ferrosilite 11.15 6.92 -4.23 -0.423 0.72147E+04 86 gibbsite 4.08 0.73 -3.35 -0.479 0.57263E+04 87 glaucophane 22.97 20.77 -2.20 -0.060 0.37615E+04 88 glaucophane-Fe 17.28 12.77 -4.51 -0.122 0.76955E+04 89 graphite -3.55 -6.85 -3.30 -0.944 0.56406E+04 90 greenalite 16.14 13.54 -2.60 -0.217 0.44444E+04 93 hematite 12.57 9.28 -3.28 -0.398 0.56072E+04 94 heulandite -5.83 -7.59 -1.76 -0.080 0.30055E+04 98 jadeite 4.22 2.77 -1.45 -0.145 0.24736E+04 100 kalsilite 7.58 3.81 -3.77 -0.539 0.64363E+04 101 kaolinite -1.33 -4.85 -3.52 -0.320 0.60050E+04 104 laumontite 2.88 1.86 -1.02 -0.068 0.17407E+04 105 lawsonite 9.62 8.16 -1.45 -0.097 0.24779E+04 106 leucite 4.12 0.66 -3.45 -0.345 0.58992E+04 108 lizardite 23.24 21.54 -1.70 -0.142 0.29100E+04 110 magnetite 20.09 15.89 -4.19 -0.342 0.71588E+04 111 minnesotaite 10.39 7.24 -3.15 -0.185 0.53828E+04 115 manganosite 14.06 9.24 -4.82 -1.205 0.82307E+04 119 microcline -2.49 -2.49 0.00 0.000 0.84007E-01 123 muscovite 2.58 -1.04 -3.62 -0.213 0.61771E+04 124 paragonite 4.24 1.07 -3.17 -0.187 0.54161E+04 125 nepheline 8.34 5.92 -2.42 -0.346 0.41361E+04 137 phlogopite-Na 29.65 27.46 -2.19 -0.122 0.37396E+04 139 prehnite 19.37 18.03 -1.34 -0.079 0.22930E+04 140 prehnite-Fe 22.50 21.94 -0.55 -0.033 0.94495E+03 141 pumpellyite-Fe 46.27 43.40 -2.87 -0.064 0.49062E+04 142 pumpellyite-Mg 48.99 46.06 -2.93 -0.065 0.50049E+04 146 pyrrhotite -4.26 -7.85 -3.59 -1.195 0.61228E+04 147 pyrrhotiteFe0.875 -6.02 -9.16 -3.14 -1.157 0.53695E+04 148 pyroxmangite 7.40 6.09 -1.31 -0.262 0.22393E+04 149 pyrophyllite -6.18 -11.15 -4.97 -0.311 0.84943E+04 150 quartz -2.99 -3.15 -0.16 -0.054 0.27496E+03 154 rhodochrosite -0.98 -5.50 -4.52 -1.507 0.77198E+04 155 rhodonite 7.45 6.09 -1.36 -0.272 0.23195E+04 156 sanidine -1.28 -2.49 -1.21 -0.093 0.20678E+04 166 stilbite -7.52 -7.59 -0.07 -0.003 0.11170E+03 167 stilpnomelane-Fe 13.02 12.43 -0.59 -0.018 0.10028E+04 168 stilpnomelane-Mg 27.44 25.77 -1.67 -0.050 0.28573E+04 174 talc 16.49 15.24 -1.25 -0.074 0.21385E+04 177 tephroite 18.09 15.32 -2.76 -0.394 0.47141E+04 181 tridymite -2.63 -3.15 -0.52 -0.175 0.89494E+03 182 tremolite 47.87 47.23 -0.64 -0.017 0.10980E+04 183 ferroactinolite 38.45 33.89 -4.56 -0.123 0.77938E+04 184 troilite-low -4.41 -7.85 -3.44 -1.145 0.58656E+04 190 wairakite 3.95 1.86 -2.09 -0.123 0.35627E+04 191 walstromite 11.51 9.86 -1.65 -0.329 0.28091E+04 192 wollastonite 10.46 9.86 -0.60 -0.119 0.10195E+04 193 pseudo-wollastonite 11.00 9.86 -1.14 -0.227 0.19393E+04 194 zoisite 22.85 18.75 -4.09 -0.186 0.69918E+04 195 akaganeite 7.75 4.64 -3.11 -0.673 0.53161E+04 202 chalcedony -2.80 -3.15 -0.35 -0.116 0.59426E+03 204 montmorillonite-Ca -2.29 -6.18 -3.89 -0.241 0.66412E+04 205 montmorillonite-K -2.24 -6.27 -4.03 -0.247 0.68844E+04 206 montmorillonite-Mg -2.48 -6.80 -4.32 -0.267 0.73703E+04 207 montmorillonite-Na -2.04 -5.57 -3.54 -0.217 0.60393E+04 208 nontronite-Ca 3.21 0.11 -3.11 -0.202 0.53062E+04 209 nontronite-H 2.53 -2.04 -4.57 -0.307 0.78086E+04 210 nontronite-K 3.34 0.02 -3.32 -0.213 0.56727E+04 211 nontronite-Mg 3.07 -0.51 -3.58 -0.232 0.61194E+04 212 nontronite-Na 3.52 0.71 -2.81 -0.180 0.47935E+04 228 tobermorite 9.82 7.69 -2.13 -0.582 0.36410E+04 234 alabandite -0.98 -5.22 -4.24 -1.414 0.72450E+04 237 boehmite 4.41 0.73 -3.68 -0.613 0.62847E+04 239 ferrous-oxide 9.81 6.61 -3.20 -0.800 0.54623E+04 245 silica-amorphous -2.09 -3.15 -1.06 -0.353 0.18084E+04 247 an20ab80 2.02 1.33 -0.69 -0.053 0.11814E+04 248 an25ab75 2.65 1.75 -0.89 -0.069 0.15237E+04 249 an30ab70 3.28 2.18 -1.10 -0.084 0.18756E+04 250 tr.625ac.25prg.125 45.16 44.83 -0.33 -0.009 0.56466E+03 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 0.0000400 MOLES Current total amount of reactant added: 0.0009900 MOLES New total amount of reactant added: 0.0010300 MOLES Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.5508E-08 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 7 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 0.0010300 Water: Moles liquid = 0.4985E+02 kg liquid = 0.8981E+00 Moles total = 0.4985E+02 kg total = 0.8980E+00 Activity = 1.0000 Stoichiometric ionic strength = .1139592E-01 Osmotic coef. = 0.9662 True ionic strength = .2007744E-01 Chg. balance for total moles = -.5508E-08 Max. difference allowed = 0.1440E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.89900E-10 -10.0462 0.75525E-10 -10.1219 0.84010E+00 -0.0757 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.15957E-03 -3.7971 0.13324E-03 -3.8753 0.83504E+00 -0.0783 4 SO4-- 0.21576E-09 -9.6660 0.11196E-09 -9.9509 0.51891E+00 -0.2849 5 HCO3- 0.30359E-04 -4.5177 0.25388E-04 -4.5954 0.83626E+00 -0.0777 6 HS- 0.56258E-04 -4.2498 0.46984E-04 -4.3280 0.83516E+00 -0.0782 7 Al+++ 0.99186E-29 -29.0035 0.22875E-29 -29.6406 0.23063E+00 -0.6371 8 H4SiO4 0.70765E-03 -3.1502 0.70765E-03 -3.1502 0.10000E+01 0.0000 9 Ca++ 0.11393E-06 -6.9434 0.58684E-07 -7.2315 0.51509E+00 -0.2881 10 Mg++ 0.21178E-10 -10.6741 0.10859E-10 -10.9642 0.51273E+00 -0.2901 11 Fe++ 0.45551E-13 -13.3415 0.23381E-13 -13.6311 0.51329E+00 -0.2896 12 K+ 0.15652E-03 -3.8054 0.13092E-03 -3.8830 0.83646E+00 -0.0776 13 Na+ 0.19864E-01 -1.7019 0.16584E-01 -1.7803 0.83488E+00 -0.0784 14 Mn++ 0.19192E-10 -10.7169 0.98593E-11 -11.0062 0.51372E+00 -0.2893 15 F- 0.56827E-06 -6.2454 0.47355E-06 -6.3246 0.83331E+00 -0.0792 16 HPO4-- 0.45331E-07 -7.3436 0.23526E-07 -7.6284 0.51898E+00 -0.2848 18 HSiO3- 0.10477E-01 -1.9798 0.87489E-02 -2.0580 0.83504E+00 -0.0783 19 Ca(HSiO3)+ 0.13976E-07 -7.8546 0.11693E-07 -7.9321 0.83664E+00 -0.0775 20 Mg(HSiO3)+ 0.32183E-11 -11.4924 0.26925E-11 -11.5698 0.83664E+00 -0.0775 21 NaHSiO3,aq 0.23466E-02 -2.6296 0.23466E-02 -2.6296 0.10000E+01 0.0000 22 AlO+ 0.65210E-16 -16.1857 0.54557E-16 -16.2631 0.83664E+00 -0.0775 24 HAlO2,aq 0.14386E-09 -9.8421 0.14386E-09 -9.8421 0.10000E+01 0.0000 25 AlO2- 0.50585E-05 -5.2960 0.42164E-05 -5.3751 0.83353E+00 -0.0791 26 CH4,aq 0.10385E-04 -4.9836 0.10349E-04 -4.9851 0.99653E+00 -0.0015 27 C2H6,aq 0.55852E-14 -14.2530 0.55658E-14 -14.2545 0.99653E+00 -0.0015 31 CO,aq 0.33861E-15 -15.4703 0.33861E-15 -15.4703 0.10000E+01 0.0000 32 CO2,aq 0.41114E-08 -8.3860 0.40971E-08 -8.3875 0.99653E+00 -0.0015 33 CO3-2 0.56704E-04 -4.2464 0.29362E-04 -4.5322 0.51781E+00 -0.2858 34 CaCO3,aq 0.21605E-07 -7.6654 0.21605E-07 -7.6654 0.10000E+01 0.0000 35 Ca(HCO3)+ 0.45456E-10 -10.3424 0.38031E-10 -10.4199 0.83664E+00 -0.0775 36 CaCl+ 0.15125E-10 -10.8203 0.12654E-10 -10.8978 0.83664E+00 -0.0775 37 CaCl2,aq 0.40058E-15 -15.3973 0.40058E-15 -15.3973 0.10000E+01 0.0000 38 CaF+ 0.48495E-12 -12.3143 0.40573E-12 -12.3918 0.83664E+00 -0.0775 39 CaOH+ 0.66190E-07 -7.1792 0.55377E-07 -7.2567 0.83664E+00 -0.0775 40 CaSO4,aq 0.20863E-14 -14.6806 0.20863E-14 -14.6806 0.10000E+01 0.0000 41 HCl,aq 0.18441E-14 -14.7342 0.18441E-14 -14.7342 0.10000E+01 0.0000 45 HF,aq 0.24483E-12 -12.6111 0.24483E-12 -12.6111 0.10000E+01 0.0000 46 HF2- 0.46878E-19 -19.3290 0.39144E-19 -19.4073 0.83504E+00 -0.0783 48 FeCl+ 0.58939E-17 -17.2296 0.49311E-17 -17.3071 0.83664E+00 -0.0775 51 FeF+ 0.67627E-18 -18.1699 0.56579E-18 -18.2473 0.83664E+00 -0.0775 53 FeO,aq 0.15931E-09 -9.7978 0.15931E-09 -9.7978 0.10000E+01 0.0000 54 FeOH+ 0.12045E-10 -10.9192 0.10077E-10 -10.9967 0.83664E+00 -0.0775 55 HFeO2- 0.26431E-07 -7.5779 0.22070E-07 -7.6562 0.83504E+00 -0.0783 56 FeO+ 0.15839E-16 -16.8003 0.13252E-16 -16.8777 0.83664E+00 -0.0775 58 FeO2- 0.56928E-09 -9.2447 0.47537E-09 -9.3230 0.83504E+00 -0.0783 59 HFeO2,aq 0.45662E-11 -11.3404 0.45662E-11 -11.3404 0.10000E+01 0.0000 60 H2,aq 0.33014E-05 -5.4813 0.32899E-05 -5.4828 0.99653E+00 -0.0015 61 KCl,aq 0.31617E-09 -9.5001 0.31617E-09 -9.5001 0.10000E+01 0.0000 63 KOH,aq 0.74029E-06 -6.1306 0.74029E-06 -6.1306 0.10000E+01 0.0000 64 KSO4- 0.27238E-12 -12.5648 0.22745E-12 -12.6431 0.83504E+00 -0.0783 65 MgCO3,aq 0.10021E-11 -11.9991 0.10021E-11 -11.9991 0.10000E+01 0.0000 66 Mg(HCO3)+ 0.85945E-14 -14.0658 0.71905E-14 -14.1432 0.83664E+00 -0.0775 67 MgCl+ 0.25365E-14 -14.5958 0.21222E-14 -14.6732 0.83664E+00 -0.0775 68 MgF+ 0.33240E-15 -15.4783 0.27810E-15 -15.5558 0.83664E+00 -0.0775 69 MgOH+ 0.67771E-10 -10.1690 0.56700E-10 -10.2464 0.83664E+00 -0.0775 71 MnF+ 0.93995E-16 -16.0269 0.78640E-16 -16.1044 0.83664E+00 -0.0775 72 MnO,aq 0.17900E-08 -8.7471 0.17900E-08 -8.7471 0.10000E+01 0.0000 73 MnOH+ 0.47183E-09 -9.3262 0.39475E-09 -9.4037 0.83664E+00 -0.0775 74 MnO2-2 0.20113E-10 -10.6965 0.10415E-10 -10.9824 0.51781E+00 -0.2858 75 HMnO2- 0.20637E-09 -9.6854 0.17232E-09 -9.7637 0.83504E+00 -0.0783 78 MnCl+ 0.96693E-14 -14.0146 0.80897E-14 -14.0921 0.83664E+00 -0.0775 79 MnSO4,aq 0.31867E-18 -18.4967 0.31867E-18 -18.4967 0.10000E+01 0.0000 80 NaCl,aq 0.73231E-06 -6.1353 0.73231E-06 -6.1353 0.10000E+01 0.0000 81 NaF,aq 0.18386E-08 -8.7355 0.18386E-08 -8.7355 0.10000E+01 0.0000 82 NaOH,aq 0.94343E-04 -4.0253 0.94343E-04 -4.0253 0.10000E+01 0.0000 84 OH- 0.91780E-02 -2.0373 0.76501E-02 -2.1163 0.83353E+00 -0.0791 89 HPO3-2 0.46581E-15 -15.3318 0.24120E-15 -15.6176 0.51781E+00 -0.2858 91 H2PO3- 0.43747E-19 -19.3591 0.36530E-19 -19.4373 0.83504E+00 -0.0783 92 H3PO4,aq 0.93855E-18 -18.0275 0.93855E-18 -18.0275 0.10000E+01 0.0000 93 H2PO4- 0.39216E-10 -10.4065 0.32777E-10 -10.4844 0.83583E+00 -0.0779 94 PO4-3 0.10491E-08 -8.9792 0.25415E-09 -9.5949 0.24225E+00 -0.6157 98 HP2O7-3 0.96475E-18 -18.0156 0.22272E-18 -18.6522 0.23086E+00 -0.6367 99 P2O7-4 0.91645E-17 -17.0379 0.70449E-18 -18.1521 0.76872E-01 -1.1142 100 H2S,aq 0.11005E-07 -7.9584 0.10967E-07 -7.9599 0.99653E+00 -0.0015 101 S2-2 0.28713E-13 -13.5419 0.14868E-13 -13.8278 0.51781E+00 -0.2858 107 SO3-2 0.91117E-16 -16.0404 0.47865E-16 -16.3200 0.52531E+00 -0.2796 108 HSO3- 0.27106E-18 -18.5669 0.22634E-18 -18.6452 0.83504E+00 -0.0783 109 HSO4- 0.97305E-17 -17.0119 0.81489E-17 -17.0889 0.83746E+00 -0.0770 111 S2O3-2 0.27855E-19 -19.5551 0.14423E-19 -19.8409 0.51781E+00 -0.2858 Charge balance for all species = -.6133E-08 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.8990027E-10 -.2217490E-01 -.2231205E+02 0.0000 2 H2O 0.1000000E+01 0.5550472E+02 0.9981930E+06 0.0000 3 Cl- 0.1595676E-03 0.1603002E-03 0.5673228E+01 6.2466 4 SO4-- 0.2157567E-09 -.1121049E-04 -.1075023E+01 10.2929 5 HCO3- 0.3035903E-04 0.9747434E-04 0.5937254E+01 5.5265 6 HS- 0.5625760E-04 0.6747932E-04 0.2227790E+01 5.7939 7 Al+++ 0.9918596E-29 0.5058644E-05 0.1362521E+00 0.7251 8 H4SiO4 0.7076483E-03 0.1353155E-01 0.1298326E+04 -3.1502 9 Ca++ 0.1139296E-06 0.2157619E-06 0.8632248E-02 13.0123 10 Mg++ 0.2117793E-10 0.9318101E-10 0.2261472E-05 9.2796 11 Fe++ 0.4555067E-13 0.2717578E-07 0.1515043E-02 6.6127 12 K+ 0.1565178E-03 0.1572584E-03 0.6138410E+01 6.2389 13 Na+ 0.1986374E-01 0.2230546E-01 0.5119052E+03 8.3416 14 Mn++ 0.1919207E-10 0.2507525E-08 0.1375185E-03 9.2377 15 F- 0.5682707E-06 0.5701100E-06 0.1081209E-01 3.7973 16 HPO4-- 0.4533130E-07 0.4641964E-07 0.4447552E-02 12.6154 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.1991563E-01 -.1991466E-01 -.9719178E-06 0.0000000E+00 2 H2O 0.4984725E+02 0.4984725E+02 -.9279660E-06 0.0000000E+00 3 Cl- 0.1439612E-03 0.1439612E-03 0.0000000E+00 0.0000000E+00 4 SO4-- -.1006681E-04 -.1006783E-04 0.1023307E-08 0.0000000E+00 5 HCO3- 0.8753900E-04 0.8753900E-04 0.0000000E+00 0.0000000E+00 6 HS- 0.6060028E-04 0.6060130E-04 -.1023307E-08 0.0000000E+00 7 Al+++ 0.4775352E-05 0.4543028E-05 0.2323242E-06 0.0000000E+00 8 H4SiO4 0.1215302E-01 0.1215231E-01 0.7072183E-06 0.0000000E+00 9 Ca++ 0.2080835E-06 0.1937698E-06 0.1431370E-07 0.0000000E+00 10 Mg++ 0.8368328E-10 0.8368328E-10 0.0000000E+00 0.0000000E+00 11 Fe++ 0.3259227E-07 0.2440581E-07 0.8186457E-08 0.0000000E+00 12 K+ 0.1412294E-03 0.1412294E-03 0.0000000E+00 0.0000000E+00 13 Na+ 0.2003215E-01 0.2003192E-01 0.2309682E-06 0.0000000E+00 14 Mn++ 0.2251939E-08 0.2251939E-08 0.0000000E+00 0.0000000E+00 15 F- 0.5120000E-06 0.5120000E-06 0.0000000E+00 0.0000000E+00 16 HPO4-- 0.4168819E-07 0.4168819E-07 0.0000000E+00 0.0000000E+00 Chg. balance for solid moles: 0.1588E-21 Mass of aqueous solution: 0.899639E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 0.0010300 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 0.2310E-06 -6.636 0.6056E-04 -4.218 96.21 0.2325E-04 andradite 0.4093E-08 -8.388 0.2080E-05 -5.682 3.304 0.5404E-06 grossular 0.6780E-09 -9.169 0.3054E-06 -6.515 0.4852 0.8498E-07 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8579E+00 0.8579E+00 1.0000 -0.067 grossular 0.1421E+00 0.1421E+00 1.0000 -0.847 Solid products produced: Mass = 0.000063 g Volume = 0.000024 cm3 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.0010300 moles log = -2.9872 Original solution: 1000.0103000 g Original solution / Rock added: 970883.79 (Water/Rock Ratio), log = 5.9872 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0399 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9814E+00 0.9857 0.1006E+01 0.1021E+01 CO2,gas 0.4186E-06 1.0069 0.4383E-06 0.4353E-06 CH4,gas 0.1447E-01 1.0124 0.1523E-01 0.1505E-01 H2,gas 0.4151E-02 1.0006 0.4319E-02 0.4317E-02 H2S,gas 0.2911E-06 0.9960 0.3015E-06 0.3027E-06 S2,gas 0.1758E-27 1.0000 0.1829E-27 0.1829E-27 CO,gas 0.4852E-12 1.0000 0.5046E-12 0.5046E-12 SO3,gas 0.2322E-45 1.0000 0.2415E-45 0.2415E-45 SO2,gas 0.3902E-25 1.0000 0.4058E-25 0.4058E-25 HF,gas 0.5781E-15 1.0000 0.6012E-15 0.6012E-15 HCl,gas 0.3129E-17 1.0000 0.3254E-17 0.3254E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 17 albite -0.38 -0.38 0.00 0.000 -0.94784E-12 23 andradite 39.01 39.01 0.00 0.000 -0.12132E-10 24 grossular 32.73 32.73 0.00 0.000 0.12132E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -14.72 -8.06 -2.686 0.13757E+05 -6.358 3 CH4,gas 4.54 1.03 -3.52 -0.879 0.60038E+04 -1.817 4 H2,gas 8.00 3.94 -4.06 -2.322 0.69384E+04 -2.365 5 H2S,gas -6.23 -14.45 -8.22 -4.110 0.14035E+05 -6.521 6 S2,gas -7.34 -36.77 -29.44 -4.529 0.50263E+05 -27.738 7 CO,gas 3.21 -10.78 -14.00 -4.306 0.23898E+05 -12.297 8 SO3,gas 17.12 -30.19 -47.32 -11.829 0.80791E+05 -45.617 9 SO2,gas 0.83 -26.26 -27.09 -7.224 0.46257E+05 -25.392 10 HF,gas 0.47 -16.45 -16.92 -8.460 0.28890E+05 -15.221 11 HCl,gas 5.19 -14.00 -19.19 -9.593 0.32761E+05 -17.488 12 acmite 7.71 6.69 -1.02 -0.106 0.17483E+04 16 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 20 spessartine 24.46 19.71 -4.74 -0.237 0.81015E+04 21 analcite 3.32 2.77 -0.56 -0.062 0.94858E+03 27 annite 20.12 17.35 -2.77 -0.154 0.47330E+04 28 phlogopite 27.06 25.35 -1.71 -0.095 0.29238E+04 30 anorthite 12.71 8.16 -4.55 -0.350 0.77659E+04 33 apatite-OH -18.15 -18.56 -0.40 -0.031 0.68575E+03 34 apatite-F -34.30 -35.00 -0.70 -0.058 0.11964E+04 38 aragonite 0.97 -1.70 -2.67 -0.890 0.45614E+04 39 brucite 12.57 9.28 -3.29 -0.658 0.56158E+04 40 calcite 0.81 -1.70 -2.52 -0.839 0.42972E+04 41 carnegieite-low 9.02 5.92 -3.11 -0.444 0.53048E+04 42 carnegieite-high 10.09 5.92 -4.18 -0.597 0.71318E+04 43 carpholite-Mg 8.58 4.43 -4.15 -0.277 0.70906E+04 44 carpholite-Fe 6.71 1.76 -4.95 -0.330 0.84523E+04 45 celadonite 5.34 3.64 -1.70 -0.100 0.29006E+04 46 celadonite-Fe 3.88 0.98 -2.90 -0.171 0.49527E+04 47 chrysotile 23.89 21.54 -2.35 -0.196 0.40194E+04 49 clinochlore 39.07 38.40 -0.67 -0.021 0.11473E+04 50 daphnite 28.97 25.06 -3.90 -0.122 0.66630E+04 52 chlorite-Al-free 47.17 43.08 -4.10 -0.171 0.69939E+04 54 chloritoid-Fe 9.17 4.91 -4.26 -0.284 0.72755E+04 55 chloritoid-Mn 11.40 7.54 -3.86 -0.258 0.65967E+04 57 coesite -2.38 -3.15 -0.77 -0.258 0.13218E+04 64 cristobalite -2.56 -3.15 -0.59 -0.197 0.10071E+04 66 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71235E+04 68 diaspore 2.87 0.73 -2.15 -0.358 0.36687E+04 69 diamond -3.10 -6.84 -3.74 -1.069 0.63902E+04 70 diopside 16.18 15.99 -0.19 -0.019 0.32407E+03 71 hedenbergite 14.21 13.32 -0.88 -0.088 0.15088E+04 76 clinoenstatite 17.17 12.26 -4.91 -0.491 0.83794E+04 78 epidote 24.67 22.67 -2.00 -0.097 0.34167E+04 79 clinozoisite 22.81 18.75 -4.06 -0.184 0.69266E+04 80 epidote-Fe 29.84 26.59 -3.25 -0.169 0.55534E+04 81 fayalite 14.05 10.08 -3.97 -0.567 0.67796E+04 82 ferrosilite 11.15 6.92 -4.22 -0.422 0.72132E+04 86 gibbsite 4.08 0.73 -3.35 -0.479 0.57272E+04 87 glaucophane 22.97 20.77 -2.20 -0.060 0.37635E+04 88 glaucophane-Fe 17.28 12.77 -4.51 -0.122 0.76937E+04 89 graphite -3.55 -6.84 -3.30 -0.942 0.56324E+04 90 greenalite 16.14 13.54 -2.60 -0.217 0.44426E+04 93 hematite 12.57 9.29 -3.28 -0.397 0.55954E+04 94 heulandite -5.83 -7.59 -1.76 -0.080 0.30078E+04 98 jadeite 4.22 2.77 -1.45 -0.145 0.24741E+04 100 kalsilite 7.58 3.81 -3.77 -0.539 0.64373E+04 101 kaolinite -1.33 -4.85 -3.52 -0.320 0.60059E+04 104 laumontite 2.88 1.86 -1.02 -0.068 0.17444E+04 105 lawsonite 9.62 8.16 -1.45 -0.097 0.24825E+04 106 leucite 4.12 0.66 -3.46 -0.346 0.58997E+04 108 lizardite 23.24 21.54 -1.71 -0.142 0.29120E+04 110 magnetite 20.09 15.90 -4.19 -0.342 0.71467E+04 111 minnesotaite 10.39 7.24 -3.15 -0.185 0.53799E+04 115 manganosite 14.06 9.24 -4.82 -1.205 0.82308E+04 119 microcline -2.49 -2.49 0.00 0.000 0.87448E-01 123 muscovite 2.58 -1.04 -3.62 -0.213 0.61790E+04 124 paragonite 4.24 1.07 -3.17 -0.187 0.54180E+04 125 nepheline 8.34 5.92 -2.42 -0.346 0.41371E+04 137 phlogopite-Na 29.65 27.45 -2.19 -0.122 0.37426E+04 139 prehnite 19.37 18.02 -1.35 -0.079 0.23010E+04 140 prehnite-Fe 22.50 21.94 -0.55 -0.033 0.94607E+03 141 pumpellyite-Fe 46.27 43.39 -2.88 -0.064 0.49228E+04 142 pumpellyite-Mg 48.99 46.05 -2.94 -0.065 0.50227E+04 145 pyrite -21.25 -26.22 -4.98 -1.171 0.84973E+04 146 pyrrhotite -4.26 -7.84 -3.58 -1.192 0.61076E+04 147 pyrrhotiteFe0.875 -6.02 -9.15 -3.14 -1.153 0.53529E+04 148 pyroxmangite 7.40 6.09 -1.31 -0.262 0.22388E+04 149 pyrophyllite -6.18 -11.15 -4.97 -0.311 0.84943E+04 150 quartz -2.99 -3.15 -0.16 -0.054 0.27447E+03 154 rhodochrosite -0.98 -5.48 -4.50 -1.501 0.76893E+04 155 rhodonite 7.45 6.09 -1.36 -0.272 0.23191E+04 156 sanidine -1.28 -2.49 -1.21 -0.093 0.20678E+04 166 stilbite -7.52 -7.59 -0.07 -0.003 0.11392E+03 167 stilpnomelane-Fe 13.02 12.43 -0.59 -0.017 0.99958E+03 168 stilpnomelane-Mg 27.44 25.77 -1.68 -0.050 0.28605E+04 174 talc 16.49 15.24 -1.25 -0.074 0.21395E+04 177 tephroite 18.09 15.33 -2.76 -0.394 0.47137E+04 181 tridymite -2.63 -3.15 -0.52 -0.175 0.89445E+03 182 tremolite 47.87 47.22 -0.65 -0.018 0.11066E+04 183 ferroactinolite 38.45 33.89 -4.57 -0.123 0.77959E+04 184 troilite-low -4.41 -7.84 -3.43 -1.142 0.58504E+04 190 wairakite 3.95 1.86 -2.09 -0.123 0.35664E+04 191 walstromite 11.51 9.86 -1.65 -0.329 0.28123E+04 192 wollastonite 10.46 9.86 -0.60 -0.120 0.10228E+04 193 pseudo-wollastonite 11.00 9.86 -1.14 -0.228 0.19426E+04 194 zoisite 22.85 18.75 -4.10 -0.186 0.70007E+04 195 akaganeite 7.75 4.64 -3.11 -0.672 0.53103E+04 202 chalcedony -2.80 -3.15 -0.35 -0.116 0.59377E+03 204 montmorillonite-Ca -2.29 -6.18 -3.89 -0.241 0.66418E+04 205 montmorillonite-K -2.24 -6.27 -4.03 -0.247 0.68846E+04 206 montmorillonite-Mg -2.48 -6.80 -4.32 -0.267 0.73704E+04 207 montmorillonite-Na -2.04 -5.57 -3.54 -0.217 0.60394E+04 208 nontronite-Ca 3.21 0.11 -3.10 -0.201 0.52936E+04 209 nontronite-H 2.53 -2.03 -4.57 -0.306 0.77954E+04 210 nontronite-K 3.34 0.03 -3.31 -0.213 0.56596E+04 211 nontronite-Mg 3.07 -0.50 -3.58 -0.232 0.61063E+04 212 nontronite-Na 3.52 0.72 -2.80 -0.180 0.47804E+04 228 tobermorite 9.82 7.69 -2.13 -0.582 0.36437E+04 234 alabandite -0.98 -5.21 -4.23 -1.411 0.72302E+04 237 boehmite 4.41 0.73 -3.68 -0.614 0.62856E+04 239 ferrous-oxide 9.81 6.61 -3.20 -0.800 0.54620E+04 245 silica-amorphous -2.09 -3.15 -1.06 -0.353 0.18079E+04 247 an20ab80 2.02 1.33 -0.69 -0.053 0.11823E+04 248 an25ab75 2.65 1.75 -0.89 -0.069 0.15249E+04 249 an30ab70 3.28 2.18 -1.10 -0.085 0.18770E+04 250 tr.625ac.25prg.125 45.16 44.83 -0.34 -0.009 0.57203E+03 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 0.0000400 MOLES Current total amount of reactant added: 0.0010300 MOLES New total amount of reactant added: 0.0010700 MOLES Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.5508E-08 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 7 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 0.0010700 Water: Moles liquid = 0.4985E+02 kg liquid = 0.8981E+00 Moles total = 0.4985E+02 kg total = 0.8980E+00 Activity = 1.0000 Stoichiometric ionic strength = .1139848E-01 Osmotic coef. = 0.9660 True ionic strength = .2007980E-01 Chg. balance for total moles = -.5508E-08 Max. difference allowed = 0.1442E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.89965E-10 -10.0459 0.75579E-10 -10.1216 0.84009E+00 -0.0757 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.15983E-03 -3.7963 0.13346E-03 -3.8746 0.83503E+00 -0.0783 4 SO4-- 0.23315E-09 -9.6324 0.12098E-09 -9.9173 0.51889E+00 -0.2849 5 HCO3- 0.31566E-04 -4.5008 0.26397E-04 -4.5784 0.83625E+00 -0.0777 6 HS- 0.57340E-04 -4.2415 0.47887E-04 -4.3198 0.83515E+00 -0.0782 7 Al+++ 0.99277E-29 -29.0032 0.22894E-29 -29.6403 0.23061E+00 -0.6371 8 H4SiO4 0.70812E-03 -3.1499 0.70812E-03 -3.1499 0.10000E+01 0.0000 9 Ca++ 0.11352E-06 -6.9449 0.58472E-07 -7.2331 0.51508E+00 -0.2881 10 Mg++ 0.21180E-10 -10.6741 0.10859E-10 -10.9642 0.51271E+00 -0.2901 11 Fe++ 0.45638E-13 -13.3407 0.23425E-13 -13.6303 0.51328E+00 -0.2896 12 K+ 0.15652E-03 -3.8054 0.13092E-03 -3.8830 0.83645E+00 -0.0776 13 Na+ 0.19864E-01 -1.7019 0.16584E-01 -1.7803 0.83488E+00 -0.0784 14 Mn++ 0.19218E-10 -10.7163 0.98726E-11 -11.0056 0.51370E+00 -0.2893 15 F- 0.58603E-06 -6.2321 0.48834E-06 -6.3113 0.83330E+00 -0.0792 16 HPO4-- 0.45332E-07 -7.3436 0.23526E-07 -7.6285 0.51897E+00 -0.2849 18 HSiO3- 0.10477E-01 -1.9798 0.87485E-02 -2.0581 0.83503E+00 -0.0783 19 Ca(HSiO3)+ 0.13924E-07 -7.8562 0.11650E-07 -7.9337 0.83663E+00 -0.0775 20 Mg(HSiO3)+ 0.32184E-11 -11.4924 0.26926E-11 -11.5698 0.83663E+00 -0.0775 21 NaHSiO3,aq 0.23465E-02 -2.6296 0.23465E-02 -2.6296 0.10000E+01 0.0000 22 AlO+ 0.65173E-16 -16.1859 0.54526E-16 -16.2634 0.83663E+00 -0.0775 24 HAlO2,aq 0.14367E-09 -9.8426 0.14367E-09 -9.8426 0.10000E+01 0.0000 25 AlO2- 0.50485E-05 -5.2968 0.42080E-05 -5.3759 0.83352E+00 -0.0791 26 CH4,aq 0.10185E-04 -4.9920 0.10149E-04 -4.9936 0.99652E+00 -0.0015 27 C2H6,aq 0.54516E-14 -14.2635 0.54327E-14 -14.2650 0.99652E+00 -0.0015 31 CO,aq 0.34714E-15 -15.4595 0.34714E-15 -15.4595 0.10000E+01 0.0000 32 CO2,aq 0.42778E-08 -8.3688 0.42629E-08 -8.3703 0.99652E+00 -0.0015 33 CO3-2 0.58917E-04 -4.2298 0.30507E-04 -4.5156 0.51779E+00 -0.2858 34 CaCO3,aq 0.22367E-07 -7.6504 0.22367E-07 -7.6504 0.10000E+01 0.0000 35 Ca(HCO3)+ 0.47092E-10 -10.3271 0.39399E-10 -10.4045 0.83663E+00 -0.0775 36 CaCl+ 0.15095E-10 -10.8212 0.12629E-10 -10.8986 0.83663E+00 -0.0775 37 CaCl2,aq 0.40043E-15 -15.3975 0.40043E-15 -15.3975 0.10000E+01 0.0000 38 CaF+ 0.49830E-12 -12.3025 0.41689E-12 -12.3800 0.83663E+00 -0.0775 39 CaOH+ 0.65904E-07 -7.1811 0.55138E-07 -7.2586 0.83663E+00 -0.0775 40 CaSO4,aq 0.22463E-14 -14.6485 0.22463E-14 -14.6485 0.10000E+01 0.0000 41 HCl,aq 0.18484E-14 -14.7332 0.18484E-14 -14.7332 0.10000E+01 0.0000 45 HF,aq 0.25266E-12 -12.5975 0.25266E-12 -12.5975 0.10000E+01 0.0000 46 HF2- 0.49888E-19 -19.3020 0.41658E-19 -19.3803 0.83503E+00 -0.0783 48 FeCl+ 0.59148E-17 -17.2281 0.49485E-17 -17.3055 0.83663E+00 -0.0775 51 FeF+ 0.69872E-18 -18.1557 0.58457E-18 -18.2332 0.83663E+00 -0.0775 53 FeO,aq 0.15938E-09 -9.7976 0.15938E-09 -9.7976 0.10000E+01 0.0000 54 FeOH+ 0.12059E-10 -10.9187 0.10089E-10 -10.9962 0.83663E+00 -0.0775 55 HFeO2- 0.26424E-07 -7.5780 0.22065E-07 -7.6563 0.83503E+00 -0.0783 56 FeO+ 0.15976E-16 -16.7965 0.13366E-16 -16.8740 0.83663E+00 -0.0775 58 FeO2- 0.57338E-09 -9.2416 0.47879E-09 -9.3199 0.83503E+00 -0.0783 59 HFeO2,aq 0.46023E-11 -11.3370 0.46023E-11 -11.3370 0.10000E+01 0.0000 60 H2,aq 0.32529E-05 -5.4877 0.32416E-05 -5.4892 0.99652E+00 -0.0015 61 KCl,aq 0.31668E-09 -9.4994 0.31668E-09 -9.4994 0.10000E+01 0.0000 63 KOH,aq 0.73976E-06 -6.1309 0.73976E-06 -6.1309 0.10000E+01 0.0000 64 KSO4- 0.29434E-12 -12.5312 0.24578E-12 -12.6095 0.83503E+00 -0.0783 65 MgCO3,aq 0.10412E-11 -11.9825 0.10412E-11 -11.9825 0.10000E+01 0.0000 66 Mg(HCO3)+ 0.89368E-14 -14.0488 0.74768E-14 -14.1263 0.83663E+00 -0.0775 67 MgCl+ 0.25409E-14 -14.5950 0.21258E-14 -14.6725 0.83663E+00 -0.0775 68 MgF+ 0.34281E-15 -15.4649 0.28681E-15 -15.5424 0.83663E+00 -0.0775 69 MgOH+ 0.67729E-10 -10.1692 0.56664E-10 -10.2467 0.83663E+00 -0.0775 71 MnF+ 0.97063E-16 -16.0129 0.81206E-16 -16.0904 0.83663E+00 -0.0775 72 MnO,aq 0.17899E-08 -8.7472 0.17899E-08 -8.7472 0.10000E+01 0.0000 73 MnOH+ 0.47213E-09 -9.3259 0.39500E-09 -9.4034 0.83663E+00 -0.0775 74 MnO2-2 0.20084E-10 -10.6972 0.10399E-10 -10.9830 0.51779E+00 -0.2858 75 HMnO2- 0.20621E-09 -9.6857 0.17219E-09 -9.7640 0.83503E+00 -0.0783 78 MnCl+ 0.96981E-14 -14.0133 0.81138E-14 -14.0908 0.83663E+00 -0.0775 79 MnSO4,aq 0.34481E-18 -18.4624 0.34481E-18 -18.4624 0.10000E+01 0.0000 80 NaCl,aq 0.73350E-06 -6.1346 0.73350E-06 -6.1346 0.10000E+01 0.0000 81 NaF,aq 0.18960E-08 -8.7222 0.18960E-08 -8.7222 0.10000E+01 0.0000 82 NaOH,aq 0.94276E-04 -4.0256 0.94276E-04 -4.0256 0.10000E+01 0.0000 84 OH- 0.91716E-02 -2.0376 0.76447E-02 -2.1166 0.83352E+00 -0.0791 89 HPO3-2 0.45898E-15 -15.3382 0.23766E-15 -15.6241 0.51779E+00 -0.2858 91 H2PO3- 0.43135E-19 -19.3652 0.36019E-19 -19.4435 0.83503E+00 -0.0783 92 H3PO4,aq 0.93987E-18 -18.0269 0.93987E-18 -18.0269 0.10000E+01 0.0000 93 H2PO4- 0.39243E-10 -10.4062 0.32800E-10 -10.4841 0.83582E+00 -0.0779 94 PO4-3 0.10484E-08 -8.9795 0.25397E-09 -9.5952 0.24224E+00 -0.6158 98 HP2O7-3 0.96547E-18 -18.0153 0.22287E-18 -18.6519 0.23084E+00 -0.6367 99 P2O7-4 0.91653E-17 -17.0379 0.70447E-18 -18.1521 0.76863E-01 -1.1143 100 H2S,aq 0.11225E-07 -7.9498 0.11186E-07 -7.9513 0.99652E+00 -0.0015 101 S2-2 0.30273E-13 -13.5189 0.15675E-13 -13.8048 0.51779E+00 -0.2858 107 SO3-2 0.97017E-16 -16.0132 0.50963E-16 -16.2927 0.52530E+00 -0.2796 108 HSO3- 0.28881E-18 -18.5394 0.24116E-18 -18.6177 0.83503E+00 -0.0783 109 HSO4- 0.10522E-16 -16.9779 0.88118E-17 -17.0549 0.83745E+00 -0.0770 111 S2O3-2 0.30701E-19 -19.5128 0.15897E-19 -19.7987 0.51779E+00 -0.2858 Charge balance for all species = -.6133E-08 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.8996473E-10 -.2217005E-01 -.2230716E+02 0.0000 2 H2O 0.1000000E+01 0.5550472E+02 0.9981928E+06 0.0000 3 Cl- 0.1598291E-03 0.1605629E-03 0.5682523E+01 6.2470 4 SO4-- 0.2331523E-09 -.1099781E-04 -.1054627E+01 10.3259 5 HCO3- 0.3156561E-04 0.1006945E-03 0.6133396E+01 5.5432 6 HS- 0.5733964E-04 0.6834890E-04 0.2256498E+01 5.8018 7 Al+++ 0.9927707E-29 0.5048628E-05 0.1359823E+00 0.7245 8 H4SiO4 0.7081179E-03 0.1353151E-01 0.1298322E+04 -3.1499 9 Ca++ 0.1135208E-06 0.2157791E-06 0.8632934E-02 13.0101 10 Mg++ 0.2118031E-10 0.9318094E-10 0.2261470E-05 9.2790 11 Fe++ 0.4563824E-13 0.2717388E-07 0.1514937E-02 6.6129 12 K+ 0.1565182E-03 0.1572583E-03 0.6138404E+01 6.2386 13 Na+ 0.1986389E-01 0.2230544E-01 0.5119045E+03 8.3413 14 Mn++ 0.1921843E-10 0.2507523E-08 0.1375184E-03 9.2376 15 F- 0.5860287E-06 0.5879255E-06 0.1114996E-01 3.8103 16 HPO4-- 0.4533193E-07 0.4641960E-07 0.4447548E-02 12.6147 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.1991133E-01 -.1991032E-01 -.1007868E-05 0.0000000E+00 2 H2O 0.4984728E+02 0.4984729E+02 -.9639812E-06 0.0000000E+00 3 Cl- 0.1441972E-03 0.1441972E-03 0.0000000E+00 0.0000000E+00 4 SO4-- -.9875810E-05 -.9876834E-05 0.1023518E-08 0.0000000E+00 5 HCO3- 0.9043100E-04 0.9043100E-04 0.0000000E+00 0.0000000E+00 6 HS- 0.6138128E-04 0.6138230E-04 -.1023518E-08 0.0000000E+00 7 Al+++ 0.4775352E-05 0.4534036E-05 0.2413157E-06 0.0000000E+00 8 H4SiO4 0.1215302E-01 0.1215229E-01 0.7342135E-06 0.0000000E+00 9 Ca++ 0.2080835E-06 0.1937854E-06 0.1429813E-07 0.0000000E+00 10 Mg++ 0.8368328E-10 0.8368328E-10 0.0000000E+00 0.0000000E+00 11 Fe++ 0.3259227E-07 0.2440412E-07 0.8188147E-08 0.0000000E+00 12 K+ 0.1412294E-03 0.1412294E-03 0.0000000E+00 0.0000000E+00 13 Na+ 0.2003215E-01 0.2003191E-01 0.2399718E-06 0.0000000E+00 14 Mn++ 0.2251939E-08 0.2251939E-08 0.0000000E+00 0.0000000E+00 15 F- 0.5280000E-06 0.5280000E-06 0.0000000E+00 0.0000000E+00 16 HPO4-- 0.4168819E-07 0.4168819E-07 0.0000000E+00 0.0000000E+00 Chg. balance for solid moles: 0.0000E+00 Mass of aqueous solution: 0.899640E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 0.0010700 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 0.2400E-06 -6.620 0.6293E-04 -4.201 96.35 0.2416E-04 andradite 0.4094E-08 -8.388 0.2081E-05 -5.682 3.186 0.5405E-06 grossular 0.6720E-09 -9.173 0.3027E-06 -6.519 0.4635 0.8422E-07 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8590E+00 0.8590E+00 1.0000 -0.066 grossular 0.1410E+00 0.1410E+00 1.0000 -0.851 Solid products produced: Mass = 0.000065 g Volume = 0.000025 cm3 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.0010700 moles log = -2.9706 Original solution: 1000.0103000 g Original solution / Rock added: 934589.07 (Water/Rock Ratio), log = 5.9706 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0396 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9817E+00 0.9857 0.1006E+01 0.1021E+01 CO2,gas 0.4357E-06 1.0069 0.4561E-06 0.4530E-06 CH4,gas 0.1419E-01 1.0124 0.1494E-01 0.1476E-01 H2,gas 0.4092E-02 1.0006 0.4256E-02 0.4253E-02 H2S,gas 0.2970E-06 0.9960 0.3075E-06 0.3087E-06 S2,gas 0.1885E-27 1.0000 0.1959E-27 0.1959E-27 CO,gas 0.4976E-12 1.0000 0.5173E-12 0.5173E-12 SO3,gas 0.2513E-45 1.0000 0.2613E-45 0.2613E-45 SO2,gas 0.4162E-25 1.0000 0.4326E-25 0.4326E-25 HF,gas 0.5968E-15 1.0000 0.6204E-15 0.6204E-15 HCl,gas 0.3137E-17 1.0000 0.3262E-17 0.3262E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 17 albite -0.38 -0.38 0.00 0.000 -0.94784E-12 23 andradite 39.01 39.01 0.00 0.000 -0.24265E-10 24 grossular 32.73 32.73 0.00 0.000 0.00000E+00 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -14.70 -8.04 -2.680 0.13728E+05 -6.341 3 CH4,gas 4.54 1.02 -3.52 -0.881 0.60182E+04 -1.826 4 H2,gas 8.00 3.93 -4.07 -2.326 0.69494E+04 -2.371 5 H2S,gas -6.23 -14.44 -8.21 -4.106 0.14020E+05 -6.512 6 S2,gas -7.34 -36.74 -29.41 -4.524 0.50211E+05 -27.708 7 CO,gas 3.21 -10.77 -13.99 -4.303 0.23879E+05 -12.286 8 SO3,gas 17.12 -30.16 -47.28 -11.820 0.80732E+05 -45.583 9 SO2,gas 0.83 -26.23 -27.06 -7.217 0.46209E+05 -25.364 10 HF,gas 0.47 -16.43 -16.91 -8.453 0.28867E+05 -15.207 11 HCl,gas 5.19 -14.00 -19.19 -9.593 0.32759E+05 -17.487 12 acmite 7.71 6.69 -1.02 -0.106 0.17420E+04 16 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 20 spessartine 24.46 19.71 -4.75 -0.237 0.81021E+04 21 analcite 3.32 2.77 -0.56 -0.062 0.94907E+03 27 annite 20.12 17.35 -2.77 -0.154 0.47319E+04 28 phlogopite 27.06 25.35 -1.71 -0.095 0.29268E+04 30 anorthite 12.71 8.16 -4.55 -0.350 0.77705E+04 33 apatite-OH -18.15 -18.56 -0.41 -0.032 0.70134E+03 34 apatite-F -34.30 -35.00 -0.70 -0.058 0.11886E+04 38 aragonite 0.97 -1.69 -2.66 -0.885 0.45358E+04 39 brucite 12.57 9.28 -3.29 -0.658 0.56168E+04 40 calcite 0.81 -1.69 -2.50 -0.834 0.42715E+04 41 carnegieite-low 9.02 5.92 -3.11 -0.444 0.53058E+04 42 carnegieite-high 10.09 5.92 -4.18 -0.597 0.71328E+04 43 carpholite-Mg 8.58 4.43 -4.15 -0.277 0.70925E+04 44 carpholite-Fe 6.71 1.76 -4.95 -0.330 0.84528E+04 45 celadonite 5.34 3.64 -1.70 -0.100 0.29011E+04 46 celadonite-Fe 3.88 0.98 -2.90 -0.171 0.49518E+04 47 chrysotile 23.89 21.54 -2.36 -0.196 0.40214E+04 49 clinochlore 39.07 38.39 -0.68 -0.021 0.11527E+04 50 daphnite 28.97 25.06 -3.90 -0.122 0.66616E+04 52 chlorite-Al-free 47.17 43.07 -4.10 -0.171 0.69979E+04 54 chloritoid-Fe 9.17 4.91 -4.26 -0.284 0.72765E+04 55 chloritoid-Mn 11.40 7.54 -3.86 -0.258 0.65982E+04 57 coesite -2.38 -3.15 -0.77 -0.258 0.13213E+04 64 cristobalite -2.56 -3.15 -0.59 -0.197 0.10067E+04 66 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71235E+04 68 diaspore 2.87 0.72 -2.15 -0.358 0.36696E+04 69 diamond -3.10 -6.84 -3.74 -1.068 0.63827E+04 70 diopside 16.18 15.99 -0.19 -0.019 0.32782E+03 71 hedenbergite 14.21 13.32 -0.89 -0.089 0.15112E+04 76 clinoenstatite 17.17 12.26 -4.91 -0.491 0.83804E+04 78 epidote 24.67 22.67 -2.00 -0.097 0.34188E+04 79 clinozoisite 22.81 18.74 -4.06 -0.185 0.69355E+04 80 epidote-Fe 29.84 26.59 -3.25 -0.169 0.55487E+04 81 fayalite 14.05 10.08 -3.97 -0.567 0.67784E+04 82 ferrosilite 11.15 6.93 -4.22 -0.422 0.72115E+04 86 gibbsite 4.08 0.72 -3.35 -0.479 0.57282E+04 87 glaucophane 22.97 20.77 -2.21 -0.060 0.37655E+04 88 glaucophane-Fe 17.28 12.77 -4.50 -0.122 0.76917E+04 89 graphite -3.55 -6.84 -3.29 -0.941 0.56250E+04 90 greenalite 16.14 13.54 -2.60 -0.217 0.44405E+04 93 hematite 12.57 9.30 -3.27 -0.396 0.55838E+04 94 heulandite -5.83 -7.59 -1.76 -0.080 0.30099E+04 98 jadeite 4.22 2.77 -1.45 -0.145 0.24746E+04 100 kalsilite 7.58 3.81 -3.77 -0.539 0.64383E+04 101 kaolinite -1.33 -4.85 -3.52 -0.320 0.60068E+04 104 laumontite 2.88 1.86 -1.02 -0.068 0.17481E+04 105 lawsonite 9.62 8.16 -1.46 -0.097 0.24872E+04 106 leucite 4.12 0.66 -3.46 -0.346 0.59002E+04 108 lizardite 23.24 21.54 -1.71 -0.142 0.29140E+04 110 magnetite 20.09 15.91 -4.18 -0.341 0.71347E+04 111 minnesotaite 10.39 7.24 -3.15 -0.185 0.53769E+04 115 manganosite 14.06 9.24 -4.82 -1.205 0.82308E+04 119 microcline -2.49 -2.49 0.00 0.000 0.90892E-01 123 muscovite 2.58 -1.04 -3.62 -0.213 0.61809E+04 124 paragonite 4.24 1.07 -3.17 -0.187 0.54199E+04 125 nepheline 8.34 5.92 -2.42 -0.346 0.41381E+04 137 phlogopite-Na 29.65 27.45 -2.19 -0.122 0.37455E+04 139 prehnite 19.37 18.02 -1.35 -0.080 0.23089E+04 140 prehnite-Fe 22.50 21.94 -0.55 -0.033 0.94719E+03 141 pumpellyite-Fe 46.27 43.38 -2.89 -0.064 0.49392E+04 142 pumpellyite-Mg 48.99 46.04 -2.95 -0.066 0.50405E+04 145 pyrite -21.25 -26.20 -4.95 -1.165 0.84566E+04 146 pyrrhotite -4.26 -7.83 -3.57 -1.189 0.60926E+04 147 pyrrhotiteFe0.875 -6.02 -9.14 -3.13 -1.149 0.53366E+04 148 pyroxmangite 7.40 6.09 -1.31 -0.262 0.22384E+04 149 pyrophyllite -6.18 -11.15 -4.97 -0.311 0.84942E+04 150 quartz -2.99 -3.15 -0.16 -0.053 0.27398E+03 154 rhodochrosite -0.98 -5.46 -4.49 -1.495 0.76599E+04 155 rhodonite 7.45 6.09 -1.36 -0.272 0.23186E+04 156 sanidine -1.28 -2.49 -1.21 -0.093 0.20678E+04 166 stilbite -7.52 -7.59 -0.07 -0.003 0.11612E+03 167 stilpnomelane-Fe 13.02 12.43 -0.58 -0.017 0.99607E+03 168 stilpnomelane-Mg 27.44 25.76 -1.68 -0.050 0.28637E+04 174 talc 16.49 15.24 -1.25 -0.074 0.21405E+04 177 tephroite 18.09 15.33 -2.76 -0.394 0.47134E+04 181 tridymite -2.63 -3.15 -0.52 -0.175 0.89396E+03 182 tremolite 47.87 47.22 -0.65 -0.018 0.11151E+04 183 ferroactinolite 38.45 33.89 -4.57 -0.123 0.77977E+04 184 troilite-low -4.41 -7.83 -3.42 -1.139 0.58354E+04 190 wairakite 3.95 1.86 -2.09 -0.123 0.35700E+04 191 walstromite 11.51 9.86 -1.65 -0.330 0.28156E+04 192 wollastonite 10.46 9.86 -0.60 -0.120 0.10260E+04 193 pseudo-wollastonite 11.00 9.86 -1.14 -0.228 0.19458E+04 194 zoisite 22.85 18.74 -4.11 -0.187 0.70095E+04 195 akaganeite 7.75 4.65 -3.11 -0.672 0.53044E+04 202 chalcedony -2.80 -3.15 -0.35 -0.116 0.59328E+03 204 montmorillonite-Ca -2.29 -6.18 -3.89 -0.241 0.66423E+04 205 montmorillonite-K -2.24 -6.27 -4.03 -0.247 0.68847E+04 206 montmorillonite-Mg -2.48 -6.80 -4.32 -0.267 0.73705E+04 207 montmorillonite-Na -2.04 -5.57 -3.54 -0.217 0.60395E+04 208 nontronite-Ca 3.21 0.12 -3.09 -0.201 0.52810E+04 209 nontronite-H 2.53 -2.03 -4.56 -0.305 0.77822E+04 210 nontronite-K 3.34 0.03 -3.31 -0.212 0.56466E+04 211 nontronite-Mg 3.07 -0.49 -3.57 -0.232 0.60933E+04 212 nontronite-Na 3.52 0.73 -2.79 -0.179 0.47674E+04 228 tobermorite 9.82 7.69 -2.14 -0.583 0.36463E+04 234 alabandite -0.98 -5.20 -4.23 -1.409 0.72156E+04 237 boehmite 4.41 0.72 -3.68 -0.614 0.62866E+04 239 ferrous-oxide 9.81 6.61 -3.20 -0.800 0.54617E+04 245 silica-amorphous -2.09 -3.15 -1.06 -0.353 0.18075E+04 247 an20ab80 2.02 1.32 -0.69 -0.053 0.11833E+04 248 an25ab75 2.65 1.75 -0.89 -0.069 0.15260E+04 249 an30ab70 3.28 2.18 -1.10 -0.085 0.18784E+04 250 tr.625ac.25prg.125 45.16 44.83 -0.34 -0.009 0.57928E+03 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 0.0000400 MOLES Current total amount of reactant added: 0.0010700 MOLES New total amount of reactant added: 0.0011100 MOLES Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.5508E-08 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 7 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 0.0011100 Water: Moles liquid = 0.4985E+02 kg liquid = 0.8981E+00 Moles total = 0.4985E+02 kg total = 0.8980E+00 Activity = 1.0000 Stoichiometric ionic strength = .1140103E-01 Osmotic coef. = 0.9659 True ionic strength = .2008216E-01 Chg. balance for total moles = -.5508E-08 Max. difference allowed = 0.1444E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.90029E-10 -10.0456 0.75632E-10 -10.1213 0.84009E+00 -0.0757 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.16009E-03 -3.7956 0.13368E-03 -3.8739 0.83502E+00 -0.0783 4 SO4-- 0.25161E-09 -9.5993 0.13055E-09 -9.8842 0.51888E+00 -0.2849 5 HCO3- 0.32773E-04 -4.4845 0.27407E-04 -4.5621 0.83625E+00 -0.0777 6 HS- 0.58422E-04 -4.2334 0.48791E-04 -4.3117 0.83515E+00 -0.0782 7 Al+++ 0.99368E-29 -29.0028 0.22914E-29 -29.6399 0.23059E+00 -0.6372 8 H4SiO4 0.70859E-03 -3.1496 0.70859E-03 -3.1496 0.10000E+01 0.0000 9 Ca++ 0.11312E-06 -6.9465 0.58262E-07 -7.2346 0.51506E+00 -0.2881 10 Mg++ 0.21183E-10 -10.6740 0.10860E-10 -10.9642 0.51270E+00 -0.2901 11 Fe++ 0.45729E-13 -13.3398 0.23471E-13 -13.6295 0.51326E+00 -0.2897 12 K+ 0.15652E-03 -3.8054 0.13092E-03 -3.8830 0.83645E+00 -0.0776 13 Na+ 0.19864E-01 -1.7019 0.16584E-01 -1.7803 0.83487E+00 -0.0784 14 Mn++ 0.19245E-10 -10.7157 0.98858E-11 -11.0050 0.51369E+00 -0.2893 15 F- 0.60379E-06 -6.2191 0.50313E-06 -6.2983 0.83330E+00 -0.0792 16 HPO4-- 0.45333E-07 -7.3436 0.23525E-07 -7.6285 0.51895E+00 -0.2849 18 HSiO3- 0.10476E-01 -1.9798 0.87481E-02 -2.0581 0.83502E+00 -0.0783 19 Ca(HSiO3)+ 0.13874E-07 -7.8578 0.11607E-07 -7.9353 0.83663E+00 -0.0775 20 Mg(HSiO3)+ 0.32185E-11 -11.4923 0.26927E-11 -11.5698 0.83663E+00 -0.0775 21 NaHSiO3,aq 0.23464E-02 -2.6296 0.23464E-02 -2.6296 0.10000E+01 0.0000 22 AlO+ 0.65136E-16 -16.1862 0.54495E-16 -16.2636 0.83663E+00 -0.0775 24 HAlO2,aq 0.14349E-09 -9.8432 0.14349E-09 -9.8432 0.10000E+01 0.0000 25 AlO2- 0.50385E-05 -5.2977 0.41996E-05 -5.3768 0.83351E+00 -0.0791 26 CH4,aq 0.99840E-05 -5.0007 0.99493E-05 -5.0022 0.99652E+00 -0.0015 27 C2H6,aq 0.53154E-14 -14.2745 0.52969E-14 -14.2760 0.99652E+00 -0.0015 31 CO,aq 0.35547E-15 -15.4492 0.35547E-15 -15.4492 0.10000E+01 0.0000 32 CO2,aq 0.44446E-08 -8.3522 0.44292E-08 -8.3537 0.99652E+00 -0.0015 33 CO3-2 0.61130E-04 -4.2137 0.31651E-04 -4.4996 0.51777E+00 -0.2859 34 CaCO3,aq 0.23122E-07 -7.6360 0.23122E-07 -7.6360 0.10000E+01 0.0000 35 Ca(HCO3)+ 0.48718E-10 -10.3123 0.40759E-10 -10.3898 0.83663E+00 -0.0775 36 CaCl+ 0.15065E-10 -10.8220 0.12604E-10 -10.8995 0.83663E+00 -0.0775 37 CaCl2,aq 0.40030E-15 -15.3976 0.40030E-15 -15.3976 0.10000E+01 0.0000 38 CaF+ 0.51155E-12 -12.2911 0.42798E-12 -12.3686 0.83663E+00 -0.0775 39 CaOH+ 0.65622E-07 -7.1830 0.54901E-07 -7.2604 0.83663E+00 -0.0775 40 CaSO4,aq 0.24154E-14 -14.6170 0.24154E-14 -14.6170 0.10000E+01 0.0000 41 HCl,aq 0.18527E-14 -14.7322 0.18527E-14 -14.7322 0.10000E+01 0.0000 45 HF,aq 0.26050E-12 -12.5842 0.26050E-12 -12.5842 0.10000E+01 0.0000 46 HF2- 0.52994E-19 -19.2758 0.44252E-19 -19.3541 0.83502E+00 -0.0783 48 FeCl+ 0.59360E-17 -17.2265 0.49662E-17 -17.3040 0.83663E+00 -0.0775 51 FeF+ 0.72130E-18 -18.1419 0.60346E-18 -18.2194 0.83663E+00 -0.0775 53 FeO,aq 0.15947E-09 -9.7973 0.15947E-09 -9.7973 0.10000E+01 0.0000 54 FeOH+ 0.12074E-10 -10.9181 0.10102E-10 -10.9956 0.83663E+00 -0.0775 55 HFeO2- 0.26420E-07 -7.5781 0.22061E-07 -7.6564 0.83502E+00 -0.0783 56 FeO+ 0.16112E-16 -16.7928 0.13480E-16 -16.8703 0.83663E+00 -0.0775 58 FeO2- 0.57746E-09 -9.2385 0.48220E-09 -9.3168 0.83502E+00 -0.0783 59 HFeO2,aq 0.46384E-11 -11.3336 0.46384E-11 -11.3336 0.10000E+01 0.0000 60 H2,aq 0.32059E-05 -5.4940 0.31948E-05 -5.4956 0.99652E+00 -0.0015 61 KCl,aq 0.31720E-09 -9.4987 0.31720E-09 -9.4987 0.10000E+01 0.0000 63 KOH,aq 0.73923E-06 -6.1312 0.73923E-06 -6.1312 0.10000E+01 0.0000 64 KSO4- 0.31763E-12 -12.4981 0.26523E-12 -12.5764 0.83502E+00 -0.0783 65 MgCO3,aq 0.10804E-11 -11.9664 0.10804E-11 -11.9664 0.10000E+01 0.0000 66 Mg(HCO3)+ 0.92794E-14 -14.0325 0.77634E-14 -14.1099 0.83663E+00 -0.0775 67 MgCl+ 0.25452E-14 -14.5943 0.21294E-14 -14.6717 0.83663E+00 -0.0775 68 MgF+ 0.35323E-15 -15.4519 0.29552E-15 -15.5294 0.83663E+00 -0.0775 69 MgOH+ 0.67687E-10 -10.1695 0.56629E-10 -10.2470 0.83663E+00 -0.0775 71 MnF+ 0.10014E-15 -15.9994 0.83778E-16 -16.0769 0.83663E+00 -0.0775 72 MnO,aq 0.17897E-08 -8.7472 0.17897E-08 -8.7472 0.10000E+01 0.0000 73 MnOH+ 0.47243E-09 -9.3257 0.39525E-09 -9.4031 0.83663E+00 -0.0775 74 MnO2-2 0.20054E-10 -10.6978 0.10384E-10 -10.9837 0.51777E+00 -0.2859 75 HMnO2- 0.20605E-09 -9.6860 0.17205E-09 -9.7643 0.83502E+00 -0.0783 78 MnCl+ 0.97270E-14 -14.0120 0.81379E-14 -14.0895 0.83663E+00 -0.0775 79 MnSO4,aq 0.37260E-18 -18.4288 0.37260E-18 -18.4288 0.10000E+01 0.0000 80 NaCl,aq 0.73469E-06 -6.1339 0.73469E-06 -6.1339 0.10000E+01 0.0000 81 NaF,aq 0.19535E-08 -8.7092 0.19535E-08 -8.7092 0.10000E+01 0.0000 82 NaOH,aq 0.94209E-04 -4.0259 0.94209E-04 -4.0259 0.10000E+01 0.0000 84 OH- 0.91651E-02 -2.0379 0.76392E-02 -2.1170 0.83351E+00 -0.0791 89 HPO3-2 0.45236E-15 -15.3445 0.23422E-15 -15.6304 0.51777E+00 -0.2859 91 H2PO3- 0.42542E-19 -19.3712 0.35523E-19 -19.4495 0.83502E+00 -0.0783 92 H3PO4,aq 0.94119E-18 -18.0263 0.94119E-18 -18.0263 0.10000E+01 0.0000 93 H2PO4- 0.39271E-10 -10.4059 0.32823E-10 -10.4838 0.83582E+00 -0.0779 94 PO4-3 0.10477E-08 -8.9797 0.25378E-09 -9.5955 0.24222E+00 -0.6158 98 HP2O7-3 0.96619E-18 -18.0149 0.22302E-18 -18.6517 0.23082E+00 -0.6367 99 P2O7-4 0.91661E-17 -17.0378 0.70445E-18 -18.1522 0.76853E-01 -1.1143 100 H2S,aq 0.11445E-07 -7.9414 0.11405E-07 -7.9429 0.99652E+00 -0.0015 101 S2-2 0.31888E-13 -13.4964 0.16511E-13 -13.7822 0.51777E+00 -0.2859 107 SO3-2 0.10319E-15 -15.9864 0.54201E-16 -16.2660 0.52528E+00 -0.2796 108 HSO3- 0.30738E-18 -18.5123 0.25667E-18 -18.5906 0.83502E+00 -0.0783 109 HSO4- 0.11363E-16 -16.9445 0.95159E-17 -17.0216 0.83744E+00 -0.0770 111 S2O3-2 0.33780E-19 -19.4713 0.17490E-19 -19.7572 0.51777E+00 -0.2859 Charge balance for all species = -.6133E-08 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.9002926E-10 -.2216519E-01 -.2230228E+02 0.0000 2 H2O 0.1000000E+01 0.5550471E+02 0.9981925E+06 0.0000 3 Cl- 0.1600905E-03 0.1608256E-03 0.5691818E+01 6.2474 4 SO4-- 0.2516091E-09 -.1078512E-04 -.1034232E+01 10.3584 5 HCO3- 0.3277341E-04 0.1039146E-03 0.6329537E+01 5.5591 6 HS- 0.5842167E-04 0.6921849E-04 0.2285207E+01 5.8096 7 Al+++ 0.9936832E-29 0.5038627E-05 0.1357129E+00 0.7240 8 H4SiO4 0.7085881E-03 0.1353147E-01 0.1298318E+04 -3.1496 9 Ca++ 0.1131166E-06 0.2157990E-06 0.8633728E-02 13.0080 10 Mg++ 0.2118269E-10 0.9318087E-10 0.2261468E-05 9.2784 11 Fe++ 0.4572900E-13 0.2717370E-07 0.1514927E-02 6.6131 12 K+ 0.1565186E-03 0.1572581E-03 0.6138399E+01 6.2383 13 Na+ 0.1986404E-01 0.2230541E-01 0.5119038E+03 8.3410 14 Mn++ 0.1924483E-10 0.2507522E-08 0.1375183E-03 9.2376 15 F- 0.6037867E-06 0.6057410E-06 0.1148782E-01 3.8230 16 HPO4-- 0.4533256E-07 0.4641957E-07 0.4447544E-02 12.6141 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.1990702E-01 -.1990598E-01 -.1043758E-05 0.0000000E+00 2 H2O 0.4984732E+02 0.4984732E+02 -.9999435E-06 0.0000000E+00 3 Cl- 0.1444332E-03 0.1444332E-03 0.0000000E+00 0.0000000E+00 4 SO4-- -.9684810E-05 -.9685834E-05 0.1023536E-08 0.0000000E+00 5 HCO3- 0.9332300E-04 0.9332300E-04 0.0000000E+00 0.0000000E+00 6 HS- 0.6216228E-04 0.6216330E-04 -.1023536E-08 0.0000000E+00 7 Al+++ 0.4775352E-05 0.4525058E-05 0.2502942E-06 0.0000000E+00 8 H4SiO4 0.1215302E-01 0.1215226E-01 0.7611672E-06 0.0000000E+00 9 Ca++ 0.2080835E-06 0.1938034E-06 0.1428014E-07 0.0000000E+00 10 Mg++ 0.8368328E-10 0.8368328E-10 0.0000000E+00 0.0000000E+00 11 Fe++ 0.3259227E-07 0.2440398E-07 0.8188287E-08 0.0000000E+00 12 K+ 0.1412294E-03 0.1412294E-03 0.0000000E+00 0.0000000E+00 13 Na+ 0.2003215E-01 0.2003190E-01 0.2489623E-06 0.0000000E+00 14 Mn++ 0.2251939E-08 0.2251939E-08 0.0000000E+00 0.0000000E+00 15 F- 0.5440000E-06 0.5440000E-06 0.0000000E+00 0.0000000E+00 16 HPO4-- 0.4168819E-07 0.4168819E-07 0.0000000E+00 0.0000000E+00 Chg. balance for solid moles: -.5294E-22 Mass of aqueous solution: 0.899640E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 0.0011100 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 0.2490E-06 -6.604 0.6528E-04 -4.185 96.48 0.2506E-04 andradite 0.4094E-08 -8.388 0.2081E-05 -5.682 3.075 0.5405E-06 grossular 0.6659E-09 -9.177 0.3000E-06 -6.523 0.4433 0.8346E-07 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8601E+00 0.8601E+00 1.0000 -0.065 grossular 0.1399E+00 0.1399E+00 1.0000 -0.854 Solid products produced: Mass = 0.000068 g Volume = 0.000026 cm3 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.0011100 moles log = -2.9547 Original solution: 1000.0103000 g Original solution / Rock added: 900910.18 (Water/Rock Ratio), log = 5.9547 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0392 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9820E+00 0.9857 0.1006E+01 0.1021E+01 CO2,gas 0.4529E-06 1.0069 0.4739E-06 0.4706E-06 CH4,gas 0.1392E-01 1.0124 0.1464E-01 0.1447E-01 H2,gas 0.4034E-02 1.0006 0.4194E-02 0.4192E-02 H2S,gas 0.3029E-06 0.9960 0.3135E-06 0.3148E-06 S2,gas 0.2018E-27 1.0000 0.2097E-27 0.2097E-27 CO,gas 0.5097E-12 1.0000 0.5297E-12 0.5297E-12 SO3,gas 0.2717E-45 1.0000 0.2824E-45 0.2824E-45 SO2,gas 0.4434E-25 1.0000 0.4608E-25 0.4608E-25 HF,gas 0.6155E-15 1.0000 0.6396E-15 0.6396E-15 HCl,gas 0.3146E-17 1.0000 0.3269E-17 0.3269E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 17 albite -0.38 -0.38 0.00 0.000 0.11184E-10 23 andradite 39.01 39.01 0.00 0.000 0.24265E-10 24 grossular 32.73 32.73 0.00 0.000 -0.12132E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -14.68 -8.02 -2.674 0.13700E+05 -6.324 3 CH4,gas 4.54 1.01 -3.53 -0.883 0.60330E+04 -1.834 4 H2,gas 8.00 3.92 -4.08 -2.329 0.69602E+04 -2.377 5 H2S,gas -6.23 -14.43 -8.20 -4.101 0.14006E+05 -6.504 6 S2,gas -7.34 -36.71 -29.38 -4.520 0.50161E+05 -27.678 7 CO,gas 3.21 -10.76 -13.97 -4.300 0.23862E+05 -12.276 8 SO3,gas 17.12 -30.13 -47.25 -11.812 0.80675E+05 -45.549 9 SO2,gas 0.83 -26.20 -27.04 -7.209 0.46162E+05 -25.337 10 HF,gas 0.47 -16.42 -16.89 -8.447 0.28844E+05 -15.194 11 HCl,gas 5.19 -14.00 -19.18 -9.592 0.32757E+05 -17.486 12 acmite 7.71 6.69 -1.02 -0.106 0.17358E+04 16 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 20 spessartine 24.46 19.71 -4.75 -0.237 0.81027E+04 21 analcite 3.32 2.77 -0.56 -0.062 0.94956E+03 27 annite 20.12 17.35 -2.77 -0.154 0.47307E+04 28 phlogopite 27.06 25.35 -1.72 -0.095 0.29298E+04 30 anorthite 12.71 8.16 -4.55 -0.350 0.77752E+04 33 apatite-OH -18.15 -18.57 -0.42 -0.032 0.71682E+03 34 apatite-F -34.30 -34.99 -0.69 -0.058 0.11814E+04 38 aragonite 0.97 -1.68 -2.64 -0.881 0.45111E+04 39 brucite 12.57 9.28 -3.29 -0.658 0.56178E+04 40 calcite 0.81 -1.68 -2.49 -0.829 0.42469E+04 41 carnegieite-low 9.02 5.92 -3.11 -0.444 0.53067E+04 42 carnegieite-high 10.09 5.92 -4.18 -0.597 0.71337E+04 43 carpholite-Mg 8.58 4.43 -4.15 -0.277 0.70944E+04 44 carpholite-Fe 6.71 1.76 -4.95 -0.330 0.84533E+04 45 celadonite 5.34 3.64 -1.70 -0.100 0.29016E+04 46 celadonite-Fe 3.88 0.98 -2.90 -0.171 0.49509E+04 47 chrysotile 23.89 21.54 -2.36 -0.196 0.40234E+04 49 clinochlore 39.07 38.39 -0.68 -0.021 0.11581E+04 50 daphnite 28.97 25.06 -3.90 -0.122 0.66601E+04 52 chlorite-Al-free 47.17 43.07 -4.10 -0.171 0.70019E+04 54 chloritoid-Fe 9.17 4.91 -4.26 -0.284 0.72775E+04 55 chloritoid-Mn 11.40 7.54 -3.87 -0.258 0.65996E+04 57 coesite -2.38 -3.15 -0.77 -0.258 0.13208E+04 64 cristobalite -2.56 -3.15 -0.59 -0.196 0.10062E+04 66 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71235E+04 68 diaspore 2.87 0.72 -2.15 -0.358 0.36706E+04 69 diamond -3.10 -6.84 -3.73 -1.067 0.63759E+04 70 diopside 16.18 15.99 -0.19 -0.019 0.33155E+03 71 hedenbergite 14.21 13.32 -0.89 -0.089 0.15135E+04 76 clinoenstatite 17.17 12.26 -4.91 -0.491 0.83814E+04 78 epidote 24.67 22.67 -2.00 -0.097 0.34209E+04 79 clinozoisite 22.81 18.74 -4.07 -0.185 0.69443E+04 80 epidote-Fe 29.84 26.59 -3.25 -0.169 0.55441E+04 81 fayalite 14.05 10.08 -3.97 -0.567 0.67771E+04 82 ferrosilite 11.15 6.93 -4.22 -0.422 0.72097E+04 86 gibbsite 4.08 0.72 -3.36 -0.479 0.57291E+04 87 glaucophane 22.97 20.77 -2.21 -0.060 0.37675E+04 88 glaucophane-Fe 17.28 12.77 -4.50 -0.122 0.76895E+04 89 graphite -3.55 -6.84 -3.29 -0.940 0.56182E+04 90 greenalite 16.14 13.54 -2.60 -0.217 0.44384E+04 93 hematite 12.57 9.30 -3.26 -0.396 0.55722E+04 94 heulandite -5.83 -7.59 -1.76 -0.080 0.30121E+04 98 jadeite 4.22 2.77 -1.45 -0.145 0.24750E+04 100 kalsilite 7.58 3.81 -3.77 -0.539 0.64393E+04 101 kaolinite -1.33 -4.85 -3.52 -0.320 0.60077E+04 104 laumontite 2.88 1.86 -1.03 -0.068 0.17517E+04 105 lawsonite 9.62 8.16 -1.46 -0.097 0.24918E+04 106 leucite 4.12 0.66 -3.46 -0.346 0.59007E+04 108 lizardite 23.24 21.54 -1.71 -0.142 0.29160E+04 110 magnetite 20.09 15.92 -4.17 -0.341 0.71227E+04 111 minnesotaite 10.39 7.24 -3.15 -0.185 0.53737E+04 115 manganosite 14.06 9.24 -4.82 -1.205 0.82309E+04 119 microcline -2.49 -2.49 0.00 0.000 0.94340E-01 123 muscovite 2.58 -1.04 -3.62 -0.213 0.61828E+04 124 paragonite 4.24 1.06 -3.18 -0.187 0.54218E+04 125 nepheline 8.34 5.92 -2.42 -0.346 0.41391E+04 137 phlogopite-Na 29.65 27.45 -2.20 -0.122 0.37485E+04 139 prehnite 19.37 18.02 -1.36 -0.080 0.23167E+04 140 prehnite-Fe 22.50 21.94 -0.56 -0.033 0.94831E+03 141 pumpellyite-Fe 46.27 43.37 -2.90 -0.064 0.49555E+04 142 pumpellyite-Mg 48.99 46.03 -2.96 -0.066 0.50581E+04 145 pyrite -21.25 -26.18 -4.93 -1.160 0.84167E+04 146 pyrrhotite -4.26 -7.82 -3.56 -1.187 0.60778E+04 147 pyrrhotiteFe0.875 -6.02 -9.13 -3.12 -1.146 0.53206E+04 148 pyroxmangite 7.40 6.09 -1.31 -0.262 0.22380E+04 149 pyrophyllite -6.18 -11.15 -4.97 -0.311 0.84941E+04 150 quartz -2.99 -3.15 -0.16 -0.053 0.27349E+03 154 rhodochrosite -0.98 -5.45 -4.47 -1.490 0.76316E+04 155 rhodonite 7.45 6.09 -1.36 -0.272 0.23182E+04 156 sanidine -1.28 -2.49 -1.21 -0.093 0.20678E+04 166 stilbite -7.52 -7.59 -0.07 -0.003 0.11829E+03 167 stilpnomelane-Fe 13.02 12.44 -0.58 -0.017 0.99231E+03 168 stilpnomelane-Mg 27.44 25.76 -1.68 -0.050 0.28669E+04 174 talc 16.49 15.24 -1.25 -0.074 0.21415E+04 177 tephroite 18.09 15.33 -2.76 -0.394 0.47130E+04 181 tridymite -2.63 -3.15 -0.52 -0.174 0.89346E+03 182 tremolite 47.87 47.21 -0.66 -0.018 0.11236E+04 183 ferroactinolite 38.45 33.88 -4.57 -0.123 0.77992E+04 184 troilite-low -4.41 -7.82 -3.41 -1.136 0.58206E+04 190 wairakite 3.95 1.86 -2.09 -0.123 0.35737E+04 191 walstromite 11.51 9.86 -1.65 -0.330 0.28188E+04 192 wollastonite 10.46 9.86 -0.60 -0.121 0.10292E+04 193 pseudo-wollastonite 11.00 9.86 -1.14 -0.228 0.19491E+04 194 zoisite 22.85 18.74 -4.11 -0.187 0.70183E+04 195 akaganeite 7.75 4.65 -3.10 -0.671 0.52986E+04 202 chalcedony -2.80 -3.15 -0.35 -0.116 0.59279E+03 204 montmorillonite-Ca -2.29 -6.18 -3.89 -0.241 0.66429E+04 205 montmorillonite-K -2.24 -6.27 -4.03 -0.247 0.68848E+04 206 montmorillonite-Mg -2.48 -6.80 -4.32 -0.267 0.73706E+04 207 montmorillonite-Na -2.04 -5.57 -3.54 -0.217 0.60397E+04 208 nontronite-Ca 3.21 0.13 -3.09 -0.200 0.52686E+04 209 nontronite-H 2.53 -2.02 -4.55 -0.305 0.77691E+04 210 nontronite-K 3.34 0.04 -3.30 -0.212 0.56337E+04 211 nontronite-Mg 3.07 -0.49 -3.56 -0.231 0.60804E+04 212 nontronite-Na 3.52 0.74 -2.78 -0.179 0.47545E+04 228 tobermorite 9.82 7.69 -2.14 -0.583 0.36489E+04 234 alabandite -0.98 -5.20 -4.22 -1.406 0.72012E+04 237 boehmite 4.41 0.72 -3.68 -0.614 0.62875E+04 239 ferrous-oxide 9.81 6.61 -3.20 -0.800 0.54613E+04 245 silica-amorphous -2.09 -3.15 -1.06 -0.353 0.18070E+04 247 an20ab80 2.02 1.32 -0.69 -0.053 0.11842E+04 248 an25ab75 2.65 1.75 -0.89 -0.069 0.15272E+04 249 an30ab70 3.28 2.18 -1.10 -0.085 0.18798E+04 250 tr.625ac.25prg.125 45.16 44.82 -0.34 -0.009 0.58643E+03 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 0.0000400 MOLES Current total amount of reactant added: 0.0011100 MOLES New total amount of reactant added: 0.0011500 MOLES Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.5508E-08 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 7 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 0.0011500 Water: Moles liquid = 0.4985E+02 kg liquid = 0.8981E+00 Moles total = 0.4985E+02 kg total = 0.8980E+00 Activity = 1.0000 Stoichiometric ionic strength = .1140358E-01 Osmotic coef. = 0.9658 True ionic strength = .2008452E-01 Chg. balance for total moles = -.5508E-08 Max. difference allowed = 0.1447E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.90094E-10 -10.0453 0.75686E-10 -10.1210 0.84008E+00 -0.0757 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.16035E-03 -3.7949 0.13390E-03 -3.8732 0.83502E+00 -0.0783 4 SO4-- 0.27119E-09 -9.5667 0.14071E-09 -9.8517 0.51886E+00 -0.2849 5 HCO3- 0.33982E-04 -4.4687 0.28417E-04 -4.5464 0.83624E+00 -0.0777 6 HS- 0.59504E-04 -4.2255 0.49694E-04 -4.3037 0.83514E+00 -0.0782 7 Al+++ 0.99460E-29 -29.0024 0.22933E-29 -29.6395 0.23058E+00 -0.6372 8 H4SiO4 0.70906E-03 -3.1493 0.70906E-03 -3.1493 0.10000E+01 0.0000 9 Ca++ 0.11272E-06 -6.9480 0.58054E-07 -7.2362 0.51504E+00 -0.2882 10 Mg++ 0.21185E-10 -10.6740 0.10861E-10 -10.9641 0.51268E+00 -0.2902 11 Fe++ 0.45823E-13 -13.3389 0.23518E-13 -13.6286 0.51324E+00 -0.2897 12 K+ 0.15652E-03 -3.8054 0.13092E-03 -3.8830 0.83644E+00 -0.0776 13 Na+ 0.19864E-01 -1.7019 0.16584E-01 -1.7803 0.83486E+00 -0.0784 14 Mn++ 0.19271E-10 -10.7151 0.98991E-11 -11.0044 0.51367E+00 -0.2893 15 F- 0.62154E-06 -6.2065 0.51793E-06 -6.2857 0.83329E+00 -0.0792 16 HPO4-- 0.45333E-07 -7.3436 0.23525E-07 -7.6285 0.51894E+00 -0.2849 18 HSiO3- 0.10476E-01 -1.9798 0.87477E-02 -2.0581 0.83502E+00 -0.0783 19 Ca(HSiO3)+ 0.13824E-07 -7.8594 0.11565E-07 -7.9368 0.83662E+00 -0.0775 20 Mg(HSiO3)+ 0.32187E-11 -11.4923 0.26928E-11 -11.5698 0.83662E+00 -0.0775 21 NaHSiO3,aq 0.23463E-02 -2.6296 0.23463E-02 -2.6296 0.10000E+01 0.0000 22 AlO+ 0.65100E-16 -16.1864 0.54464E-16 -16.2639 0.83662E+00 -0.0775 24 HAlO2,aq 0.14331E-09 -9.8437 0.14331E-09 -9.8437 0.10000E+01 0.0000 25 AlO2- 0.50285E-05 -5.2986 0.41913E-05 -5.3777 0.83351E+00 -0.0791 26 CH4,aq 0.97827E-05 -5.0095 0.97487E-05 -5.0111 0.99652E+00 -0.0015 27 C2H6,aq 0.51769E-14 -14.2859 0.51588E-14 -14.2874 0.99652E+00 -0.0015 31 CO,aq 0.36359E-15 -15.4394 0.36359E-15 -15.4394 0.10000E+01 0.0000 32 CO2,aq 0.46118E-08 -8.3361 0.45958E-08 -8.3376 0.99652E+00 -0.0015 33 CO3-2 0.63341E-04 -4.1983 0.32795E-04 -4.4842 0.51776E+00 -0.2859 34 CaCO3,aq 0.23873E-07 -7.6221 0.23873E-07 -7.6221 0.10000E+01 0.0000 35 Ca(HCO3)+ 0.50335E-10 -10.2981 0.42111E-10 -10.3756 0.83662E+00 -0.0775 36 CaCl+ 0.15036E-10 -10.8229 0.12580E-10 -10.9003 0.83662E+00 -0.0775 37 CaCl2,aq 0.40017E-15 -15.3978 0.40017E-15 -15.3978 0.10000E+01 0.0000 38 CaF+ 0.52472E-12 -12.2801 0.43899E-12 -12.3575 0.83662E+00 -0.0775 39 CaOH+ 0.65342E-07 -7.1848 0.54666E-07 -7.2623 0.83662E+00 -0.0775 40 CaSO4,aq 0.25940E-14 -14.5860 0.25940E-14 -14.5860 0.10000E+01 0.0000 41 HCl,aq 0.18570E-14 -14.7312 0.18570E-14 -14.7312 0.10000E+01 0.0000 45 HF,aq 0.26835E-12 -12.5713 0.26835E-12 -12.5713 0.10000E+01 0.0000 46 HF2- 0.56197E-19 -19.2503 0.46925E-19 -19.3286 0.83502E+00 -0.0783 48 FeCl+ 0.59577E-17 -17.2249 0.49843E-17 -17.3024 0.83662E+00 -0.0775 51 FeF+ 0.74401E-18 -18.1284 0.62245E-18 -18.2059 0.83662E+00 -0.0775 53 FeO,aq 0.15956E-09 -9.7971 0.15956E-09 -9.7971 0.10000E+01 0.0000 54 FeOH+ 0.12090E-10 -10.9176 0.10115E-10 -10.9950 0.83662E+00 -0.0775 55 HFeO2- 0.26417E-07 -7.5781 0.22059E-07 -7.6564 0.83502E+00 -0.0783 56 FeO+ 0.16249E-16 -16.7892 0.13595E-16 -16.8666 0.83662E+00 -0.0775 58 FeO2- 0.58155E-09 -9.2354 0.48560E-09 -9.3137 0.83502E+00 -0.0783 59 HFeO2,aq 0.46745E-11 -11.3303 0.46745E-11 -11.3303 0.10000E+01 0.0000 60 H2,aq 0.31603E-05 -5.5003 0.31494E-05 -5.5018 0.99652E+00 -0.0015 61 KCl,aq 0.31771E-09 -9.4980 0.31771E-09 -9.4980 0.10000E+01 0.0000 63 KOH,aq 0.73870E-06 -6.1315 0.73870E-06 -6.1315 0.10000E+01 0.0000 64 KSO4- 0.34234E-12 -12.4655 0.28586E-12 -12.5438 0.83502E+00 -0.0783 65 MgCO3,aq 0.11195E-11 -11.9510 0.11195E-11 -11.9510 0.10000E+01 0.0000 66 Mg(HCO3)+ 0.96225E-14 -14.0167 0.80504E-14 -14.0942 0.83662E+00 -0.0775 67 MgCl+ 0.25496E-14 -14.5935 0.21331E-14 -14.6710 0.83662E+00 -0.0775 68 MgF+ 0.36365E-15 -15.4393 0.30423E-15 -15.5168 0.83662E+00 -0.0775 69 MgOH+ 0.67645E-10 -10.1698 0.56593E-10 -10.2472 0.83662E+00 -0.0775 71 MnF+ 0.10322E-15 -15.9862 0.86357E-16 -16.0637 0.83662E+00 -0.0775 72 MnO,aq 0.17896E-08 -8.7472 0.17896E-08 -8.7472 0.10000E+01 0.0000 73 MnOH+ 0.47273E-09 -9.3254 0.39550E-09 -9.4029 0.83662E+00 -0.0775 74 MnO2-2 0.20025E-10 -10.6984 0.10368E-10 -10.9843 0.51776E+00 -0.2859 75 HMnO2- 0.20589E-09 -9.6864 0.17192E-09 -9.7647 0.83502E+00 -0.0783 78 MnCl+ 0.97560E-14 -14.0107 0.81621E-14 -14.0882 0.83662E+00 -0.0775 79 MnSO4,aq 0.40213E-18 -18.3956 0.40213E-18 -18.3956 0.10000E+01 0.0000 80 NaCl,aq 0.73589E-06 -6.1332 0.73589E-06 -6.1332 0.10000E+01 0.0000 81 NaF,aq 0.20109E-08 -8.6966 0.20109E-08 -8.6966 0.10000E+01 0.0000 82 NaOH,aq 0.94142E-04 -4.0262 0.94142E-04 -4.0262 0.10000E+01 0.0000 84 OH- 0.91587E-02 -2.0382 0.76338E-02 -2.1173 0.83351E+00 -0.0791 89 HPO3-2 0.44593E-15 -15.3507 0.23089E-15 -15.6366 0.51776E+00 -0.2859 91 H2PO3- 0.41966E-19 -19.3771 0.35042E-19 -19.4554 0.83502E+00 -0.0783 92 H3PO4,aq 0.94251E-18 -18.0257 0.94251E-18 -18.0257 0.10000E+01 0.0000 93 H2PO4- 0.39298E-10 -10.4056 0.32846E-10 -10.4835 0.83581E+00 -0.0779 94 PO4-3 0.10470E-08 -8.9800 0.25360E-09 -9.5959 0.24220E+00 -0.6158 98 HP2O7-3 0.96691E-18 -18.0146 0.22317E-18 -18.6514 0.23081E+00 -0.6367 99 P2O7-4 0.91669E-17 -17.0378 0.70442E-18 -18.1522 0.76844E-01 -1.1144 100 H2S,aq 0.11665E-07 -7.9331 0.11624E-07 -7.9346 0.99652E+00 -0.0015 101 S2-2 0.33557E-13 -13.4742 0.17375E-13 -13.7601 0.51776E+00 -0.2859 107 SO3-2 0.10964E-15 -15.9601 0.57587E-16 -16.2397 0.52527E+00 -0.2796 108 HSO3- 0.32682E-18 -18.4857 0.27290E-18 -18.5640 0.83502E+00 -0.0783 109 HSO4- 0.12256E-16 -16.9117 0.10264E-16 -16.9887 0.83744E+00 -0.0770 111 S2O3-2 0.37110E-19 -19.4305 0.19214E-19 -19.7164 0.51776E+00 -0.2859 Charge balance for all species = -.6133E-08 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.9009388E-10 -.2216034E-01 -.2229739E+02 0.0000 2 H2O 0.1000000E+01 0.5550470E+02 0.9981923E+06 0.0000 3 Cl- 0.1603520E-03 0.1610882E-03 0.5701113E+01 6.2478 4 SO4-- 0.2711941E-09 -.1057244E-04 -.1013836E+01 10.3903 5 HCO3- 0.3398240E-04 0.1071348E-03 0.6525678E+01 5.5746 6 HS- 0.5950370E-04 0.7008808E-04 0.2313916E+01 5.8173 7 Al+++ 0.9945970E-29 0.5028640E-05 0.1354439E+00 0.7234 8 H4SiO4 0.7090588E-03 0.1353143E-01 0.1298314E+04 -3.1493 9 Ca++ 0.1127167E-06 0.2158211E-06 0.8634611E-02 13.0058 10 Mg++ 0.2118507E-10 0.9318079E-10 0.2261466E-05 9.2778 11 Fe++ 0.4582251E-13 0.2717498E-07 0.1514997E-02 6.6134 12 K+ 0.1565190E-03 0.1572580E-03 0.6138393E+01 6.2380 13 Na+ 0.1986419E-01 0.2230538E-01 0.5119031E+03 8.3407 14 Mn++ 0.1927128E-10 0.2507520E-08 0.1375182E-03 9.2376 15 F- 0.6215447E-06 0.6235564E-06 0.1182569E-01 3.8353 16 HPO4-- 0.4533319E-07 0.4641953E-07 0.4447540E-02 12.6135 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.1990271E-01 -.1990163E-01 -.1079589E-05 0.0000000E+00 2 H2O 0.4984735E+02 0.4984735E+02 -.1035853E-05 0.0000000E+00 3 Cl- 0.1446692E-03 0.1446692E-03 0.0000000E+00 0.0000000E+00 4 SO4-- -.9493810E-05 -.9494833E-05 0.1023390E-08 0.0000000E+00 5 HCO3- 0.9621500E-04 0.9621500E-04 0.0000000E+00 0.0000000E+00 6 HS- 0.6294328E-04 0.6294430E-04 -.1023390E-08 0.0000000E+00 7 Al+++ 0.4775352E-05 0.4516093E-05 0.2592594E-06 0.0000000E+00 8 H4SiO4 0.1215302E-01 0.1215223E-01 0.7880795E-06 0.0000000E+00 9 Ca++ 0.2080835E-06 0.1938234E-06 0.1426014E-07 0.0000000E+00 10 Mg++ 0.8368328E-10 0.8368328E-10 0.0000000E+00 0.0000000E+00 11 Fe++ 0.3259227E-07 0.2440515E-07 0.8187122E-08 0.0000000E+00 12 K+ 0.1412294E-03 0.1412294E-03 0.0000000E+00 0.0000000E+00 13 Na+ 0.2003215E-01 0.2003189E-01 0.2579398E-06 0.0000000E+00 14 Mn++ 0.2251939E-08 0.2251939E-08 0.0000000E+00 0.0000000E+00 15 F- 0.5600000E-06 0.5600000E-06 0.0000000E+00 0.0000000E+00 16 HPO4-- 0.4168819E-07 0.4168819E-07 0.0000000E+00 0.0000000E+00 Chg. balance for solid moles: 0.1059E-21 Mass of aqueous solution: 0.899641E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 0.0011500 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 0.2579E-06 -6.588 0.6764E-04 -4.170 96.60 0.2596E-04 andradite 0.4094E-08 -8.388 0.2080E-05 -5.682 2.971 0.5405E-06 grossular 0.6598E-09 -9.181 0.2972E-06 -6.527 0.4245 0.8270E-07 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8612E+00 0.8612E+00 1.0000 -0.065 grossular 0.1388E+00 0.1388E+00 1.0000 -0.858 Solid products produced: Mass = 0.000070 g Volume = 0.000027 cm3 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.0011500 moles log = -2.9393 Original solution: 1000.0103000 g Original solution / Rock added: 869574.17 (Water/Rock Ratio), log = 5.9393 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0389 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9824E+00 0.9857 0.1006E+01 0.1021E+01 CO2,gas 0.4701E-06 1.0069 0.4917E-06 0.4883E-06 CH4,gas 0.1364E-01 1.0124 0.1435E-01 0.1417E-01 H2,gas 0.3978E-02 1.0006 0.4135E-02 0.4132E-02 H2S,gas 0.3088E-06 0.9960 0.3195E-06 0.3208E-06 S2,gas 0.2158E-27 1.0000 0.2242E-27 0.2242E-27 CO,gas 0.5216E-12 1.0000 0.5418E-12 0.5418E-12 SO3,gas 0.2934E-45 1.0000 0.3048E-45 0.3048E-45 SO2,gas 0.4719E-25 1.0000 0.4903E-25 0.4903E-25 HF,gas 0.6342E-15 1.0000 0.6589E-15 0.6589E-15 HCl,gas 0.3154E-17 1.0000 0.3277E-17 0.3277E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 17 albite -0.38 -0.38 0.00 0.000 0.11184E-10 23 andradite 39.01 39.01 0.00 0.000 -0.12132E-10 24 grossular 32.73 32.73 0.00 0.000 0.12132E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -14.67 -8.01 -2.669 0.13672E+05 -6.308 3 CH4,gas 4.54 1.00 -3.54 -0.886 0.60481E+04 -1.843 4 H2,gas 8.00 3.92 -4.08 -2.333 0.69708E+04 -2.384 5 H2S,gas -6.23 -14.42 -8.19 -4.097 0.13992E+05 -6.495 6 S2,gas -7.34 -36.68 -29.35 -4.515 0.50112E+05 -27.649 7 CO,gas 3.21 -10.75 -13.97 -4.297 0.23845E+05 -12.266 8 SO3,gas 17.12 -30.09 -47.21 -11.804 0.80618E+05 -45.516 9 SO2,gas 0.83 -26.18 -27.01 -7.202 0.46116E+05 -25.310 10 HF,gas 0.47 -16.41 -16.88 -8.440 0.28822E+05 -15.181 11 HCl,gas 5.19 -13.99 -19.18 -9.592 0.32755E+05 -17.485 12 acmite 7.71 6.70 -1.01 -0.105 0.17295E+04 16 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 20 spessartine 24.46 19.71 -4.75 -0.237 0.81033E+04 21 analcite 3.32 2.77 -0.56 -0.062 0.95006E+03 27 annite 20.12 17.35 -2.77 -0.154 0.47294E+04 28 phlogopite 27.06 25.35 -1.72 -0.095 0.29328E+04 30 anorthite 12.71 8.15 -4.56 -0.350 0.77798E+04 33 apatite-OH -18.15 -18.58 -0.43 -0.033 0.73221E+03 34 apatite-F -34.30 -34.99 -0.69 -0.057 0.11748E+04 38 aragonite 0.97 -1.66 -2.63 -0.876 0.44874E+04 39 brucite 12.57 9.28 -3.29 -0.658 0.56188E+04 40 calcite 0.81 -1.66 -2.47 -0.824 0.42232E+04 41 carnegieite-low 9.02 5.91 -3.11 -0.444 0.53077E+04 42 carnegieite-high 10.09 5.91 -4.18 -0.597 0.71347E+04 43 carpholite-Mg 8.58 4.43 -4.16 -0.277 0.70963E+04 44 carpholite-Fe 6.71 1.76 -4.95 -0.330 0.84538E+04 45 celadonite 5.34 3.64 -1.70 -0.100 0.29021E+04 46 celadonite-Fe 3.88 0.98 -2.90 -0.171 0.49500E+04 47 chrysotile 23.89 21.53 -2.36 -0.196 0.40254E+04 49 clinochlore 39.07 38.39 -0.68 -0.021 0.11635E+04 50 daphnite 28.97 25.07 -3.90 -0.122 0.66583E+04 52 chlorite-Al-free 47.17 43.07 -4.10 -0.171 0.70059E+04 54 chloritoid-Fe 9.17 4.91 -4.26 -0.284 0.72785E+04 55 chloritoid-Mn 11.40 7.54 -3.87 -0.258 0.66011E+04 57 coesite -2.38 -3.15 -0.77 -0.258 0.13203E+04 64 cristobalite -2.56 -3.15 -0.59 -0.196 0.10057E+04 66 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71235E+04 68 diaspore 2.87 0.72 -2.15 -0.358 0.36715E+04 69 diamond -3.10 -6.83 -3.73 -1.066 0.63698E+04 70 diopside 16.18 15.99 -0.20 -0.020 0.33526E+03 71 hedenbergite 14.21 13.32 -0.89 -0.089 0.15158E+04 76 clinoenstatite 17.17 12.26 -4.91 -0.491 0.83824E+04 78 epidote 24.67 22.67 -2.00 -0.097 0.34230E+04 79 clinozoisite 22.81 18.73 -4.07 -0.185 0.69531E+04 80 epidote-Fe 29.84 26.60 -3.24 -0.169 0.55394E+04 81 fayalite 14.05 10.08 -3.97 -0.567 0.67758E+04 82 ferrosilite 11.15 6.93 -4.22 -0.422 0.72078E+04 86 gibbsite 4.08 0.72 -3.36 -0.479 0.57301E+04 87 glaucophane 22.97 20.77 -2.21 -0.060 0.37695E+04 88 glaucophane-Fe 17.28 12.77 -4.50 -0.122 0.76872E+04 89 graphite -3.55 -6.83 -3.29 -0.939 0.56120E+04 90 greenalite 16.14 13.54 -2.60 -0.217 0.44361E+04 93 hematite 12.57 9.31 -3.26 -0.395 0.55607E+04 94 heulandite -5.83 -7.59 -1.77 -0.080 0.30143E+04 98 jadeite 4.22 2.77 -1.45 -0.145 0.24755E+04 100 kalsilite 7.58 3.81 -3.77 -0.539 0.64403E+04 101 kaolinite -1.33 -4.85 -3.52 -0.320 0.60087E+04 104 laumontite 2.88 1.86 -1.03 -0.069 0.17554E+04 105 lawsonite 9.62 8.15 -1.46 -0.097 0.24965E+04 106 leucite 4.12 0.66 -3.46 -0.346 0.59012E+04 108 lizardite 23.24 21.53 -1.71 -0.142 0.29180E+04 110 magnetite 20.09 15.92 -4.16 -0.340 0.71108E+04 111 minnesotaite 10.39 7.24 -3.15 -0.185 0.53705E+04 115 manganosite 14.06 9.24 -4.82 -1.205 0.82310E+04 119 microcline -2.49 -2.49 0.00 0.000 0.97791E-01 123 muscovite 2.58 -1.04 -3.62 -0.213 0.61847E+04 124 paragonite 4.24 1.06 -3.18 -0.187 0.54237E+04 125 nepheline 8.34 5.91 -2.42 -0.346 0.41401E+04 137 phlogopite-Na 29.65 27.45 -2.20 -0.122 0.37515E+04 139 prehnite 19.37 18.01 -1.36 -0.080 0.23246E+04 140 prehnite-Fe 22.50 21.94 -0.56 -0.033 0.94944E+03 141 pumpellyite-Fe 46.27 43.36 -2.91 -0.065 0.49716E+04 142 pumpellyite-Mg 48.99 46.02 -2.97 -0.066 0.50757E+04 145 pyrite -21.25 -26.15 -4.91 -1.154 0.83774E+04 146 pyrrhotite -4.26 -7.81 -3.55 -1.184 0.60632E+04 147 pyrrhotiteFe0.875 -6.02 -9.12 -3.11 -1.143 0.53047E+04 148 pyroxmangite 7.40 6.09 -1.31 -0.262 0.22375E+04 149 pyrophyllite -6.18 -11.15 -4.97 -0.311 0.84941E+04 150 quartz -2.99 -3.15 -0.16 -0.053 0.27300E+03 154 rhodochrosite -0.98 -5.43 -4.45 -1.485 0.76043E+04 155 rhodonite 7.45 6.09 -1.36 -0.271 0.23178E+04 156 sanidine -1.28 -2.49 -1.21 -0.093 0.20678E+04 166 stilbite -7.52 -7.59 -0.07 -0.003 0.12045E+03 167 stilpnomelane-Fe 13.02 12.44 -0.58 -0.017 0.98835E+03 168 stilpnomelane-Mg 27.44 25.76 -1.68 -0.050 0.28701E+04 174 talc 16.49 15.24 -1.25 -0.074 0.21425E+04 177 tephroite 18.09 15.33 -2.76 -0.394 0.47126E+04 181 tridymite -2.63 -3.15 -0.52 -0.174 0.89297E+03 182 tremolite 47.87 47.21 -0.66 -0.018 0.11320E+04 183 ferroactinolite 38.45 33.88 -4.57 -0.123 0.78005E+04 184 troilite-low -4.41 -7.81 -3.40 -1.133 0.58060E+04 190 wairakite 3.95 1.86 -2.10 -0.123 0.35773E+04 191 walstromite 11.51 9.86 -1.65 -0.331 0.28220E+04 192 wollastonite 10.46 9.86 -0.60 -0.121 0.10325E+04 193 pseudo-wollastonite 11.00 9.86 -1.14 -0.229 0.19523E+04 194 zoisite 22.85 18.73 -4.12 -0.187 0.70271E+04 195 akaganeite 7.75 4.65 -3.10 -0.670 0.52929E+04 202 chalcedony -2.80 -3.15 -0.35 -0.116 0.59229E+03 204 montmorillonite-Ca -2.29 -6.18 -3.89 -0.241 0.66434E+04 205 montmorillonite-K -2.24 -6.27 -4.03 -0.247 0.68849E+04 206 montmorillonite-Mg -2.48 -6.80 -4.32 -0.267 0.73707E+04 207 montmorillonite-Na -2.04 -5.58 -3.54 -0.217 0.60398E+04 208 nontronite-Ca 3.21 0.14 -3.08 -0.200 0.52562E+04 209 nontronite-H 2.53 -2.01 -4.54 -0.304 0.77561E+04 210 nontronite-K 3.34 0.05 -3.29 -0.211 0.56209E+04 211 nontronite-Mg 3.07 -0.48 -3.55 -0.231 0.60676E+04 212 nontronite-Na 3.52 0.74 -2.78 -0.178 0.47417E+04 228 tobermorite 9.82 7.68 -2.14 -0.584 0.36515E+04 234 alabandite -0.98 -5.19 -4.21 -1.403 0.71872E+04 237 boehmite 4.41 0.72 -3.68 -0.614 0.62885E+04 239 ferrous-oxide 9.81 6.61 -3.20 -0.800 0.54609E+04 245 silica-amorphous -2.09 -3.15 -1.06 -0.353 0.18065E+04 247 an20ab80 2.02 1.32 -0.69 -0.053 0.11851E+04 248 an25ab75 2.65 1.75 -0.90 -0.069 0.15284E+04 249 an30ab70 3.28 2.18 -1.10 -0.085 0.18812E+04 250 tr.625ac.25prg.125 45.16 44.82 -0.35 -0.009 0.59350E+03 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 0.0000400 MOLES Current total amount of reactant added: 0.0011500 MOLES New total amount of reactant added: 0.0011900 MOLES Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.5508E-08 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 7 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 0.0011900 Water: Moles liquid = 0.4985E+02 kg liquid = 0.8981E+00 Moles total = 0.4985E+02 kg total = 0.8980E+00 Activity = 1.0000 Stoichiometric ionic strength = .1140614E-01 Osmotic coef. = 0.9657 True ionic strength = .2008687E-01 Chg. balance for total moles = -.5508E-08 Max. difference allowed = 0.1449E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.90159E-10 -10.0450 0.75740E-10 -10.1207 0.84007E+00 -0.0757 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.16061E-03 -3.7942 0.13411E-03 -3.8725 0.83501E+00 -0.0783 4 SO4-- 0.29198E-09 -9.5346 0.15149E-09 -9.8196 0.51885E+00 -0.2850 5 HCO3- 0.35193E-04 -4.4535 0.29429E-04 -4.5312 0.83623E+00 -0.0777 6 HS- 0.60586E-04 -4.2176 0.50597E-04 -4.2959 0.83513E+00 -0.0782 7 Al+++ 0.99551E-29 -29.0020 0.22953E-29 -29.6392 0.23056E+00 -0.6372 8 H4SiO4 0.70953E-03 -3.1490 0.70953E-03 -3.1490 0.10000E+01 0.0000 9 Ca++ 0.11232E-06 -6.9495 0.57848E-07 -7.2377 0.51503E+00 -0.2882 10 Mg++ 0.21187E-10 -10.6739 0.10862E-10 -10.9641 0.51266E+00 -0.2902 11 Fe++ 0.45918E-13 -13.3380 0.23567E-13 -13.6277 0.51323E+00 -0.2897 12 K+ 0.15652E-03 -3.8054 0.13092E-03 -3.8830 0.83643E+00 -0.0776 13 Na+ 0.19864E-01 -1.7019 0.16584E-01 -1.7803 0.83486E+00 -0.0784 14 Mn++ 0.19298E-10 -10.7145 0.99124E-11 -11.0038 0.51365E+00 -0.2893 15 F- 0.63930E-06 -6.1943 0.53272E-06 -6.2735 0.83329E+00 -0.0792 16 HPO4-- 0.45334E-07 -7.3436 0.23525E-07 -7.6285 0.51892E+00 -0.2849 18 HSiO3- 0.10476E-01 -1.9798 0.87473E-02 -2.0581 0.83501E+00 -0.0783 19 Ca(HSiO3)+ 0.13774E-07 -7.8609 0.11524E-07 -7.9384 0.83661E+00 -0.0775 20 Mg(HSiO3)+ 0.32188E-11 -11.4923 0.26929E-11 -11.5698 0.83661E+00 -0.0775 21 NaHSiO3,aq 0.23462E-02 -2.6296 0.23462E-02 -2.6296 0.10000E+01 0.0000 22 AlO+ 0.65063E-16 -16.1867 0.54433E-16 -16.2641 0.83661E+00 -0.0775 24 HAlO2,aq 0.14312E-09 -9.8443 0.14312E-09 -9.8443 0.10000E+01 0.0000 25 AlO2- 0.50185E-05 -5.2994 0.41829E-05 -5.3785 0.83350E+00 -0.0791 26 CH4,aq 0.95811E-05 -5.0186 0.95478E-05 -5.0201 0.99652E+00 -0.0015 27 C2H6,aq 0.50364E-14 -14.2979 0.50188E-14 -14.2994 0.99652E+00 -0.0015 31 CO,aq 0.37152E-15 -15.4300 0.37152E-15 -15.4300 0.10000E+01 0.0000 32 CO2,aq 0.47794E-08 -8.3206 0.47628E-08 -8.3221 0.99652E+00 -0.0015 33 CO3-2 0.65552E-04 -4.1834 0.33939E-04 -4.4693 0.51774E+00 -0.2859 34 CaCO3,aq 0.24618E-07 -7.6088 0.24618E-07 -7.6088 0.10000E+01 0.0000 35 Ca(HCO3)+ 0.51943E-10 -10.2845 0.43456E-10 -10.3619 0.83661E+00 -0.0775 36 CaCl+ 0.15007E-10 -10.8237 0.12555E-10 -10.9012 0.83661E+00 -0.0775 37 CaCl2,aq 0.40004E-15 -15.3979 0.40004E-15 -15.3979 0.10000E+01 0.0000 38 CaF+ 0.53780E-12 -12.2694 0.44993E-12 -12.3469 0.83661E+00 -0.0775 39 CaOH+ 0.65064E-07 -7.1867 0.54434E-07 -7.2641 0.83661E+00 -0.0775 40 CaSO4,aq 0.27828E-14 -14.5555 0.27828E-14 -14.5555 0.10000E+01 0.0000 41 HCl,aq 0.18614E-14 -14.7302 0.18614E-14 -14.7302 0.10000E+01 0.0000 45 HF,aq 0.27621E-12 -12.5588 0.27621E-12 -12.5588 0.10000E+01 0.0000 46 HF2- 0.59496E-19 -19.2255 0.49680E-19 -19.3038 0.83501E+00 -0.0783 48 FeCl+ 0.59797E-17 -17.2233 0.50027E-17 -17.3008 0.83661E+00 -0.0775 51 FeF+ 0.76684E-18 -18.1153 0.64155E-18 -18.1928 0.83661E+00 -0.0775 53 FeO,aq 0.15967E-09 -9.7968 0.15967E-09 -9.7968 0.10000E+01 0.0000 54 FeOH+ 0.12106E-10 -10.9170 0.10128E-10 -10.9945 0.83661E+00 -0.0775 55 HFeO2- 0.26415E-07 -7.5781 0.22057E-07 -7.6565 0.83501E+00 -0.0783 56 FeO+ 0.16387E-16 -16.7855 0.13709E-16 -16.8630 0.83661E+00 -0.0775 58 FeO2- 0.58563E-09 -9.2324 0.48901E-09 -9.3107 0.83501E+00 -0.0783 59 HFeO2,aq 0.47106E-11 -11.3269 0.47106E-11 -11.3269 0.10000E+01 0.0000 60 H2,aq 0.31160E-05 -5.5064 0.31052E-05 -5.5079 0.99652E+00 -0.0015 61 KCl,aq 0.31822E-09 -9.4973 0.31822E-09 -9.4973 0.10000E+01 0.0000 63 KOH,aq 0.73818E-06 -6.1318 0.73818E-06 -6.1318 0.10000E+01 0.0000 64 KSO4- 0.36857E-12 -12.4335 0.30776E-12 -12.5118 0.83501E+00 -0.0783 65 MgCO3,aq 0.11586E-11 -11.9361 0.11586E-11 -11.9361 0.10000E+01 0.0000 66 Mg(HCO3)+ 0.99660E-14 -14.0015 0.83377E-14 -14.0790 0.83661E+00 -0.0775 67 MgCl+ 0.25540E-14 -14.5928 0.21367E-14 -14.6703 0.83661E+00 -0.0775 68 MgF+ 0.37407E-15 -15.4271 0.31295E-15 -15.5045 0.83661E+00 -0.0775 69 MgOH+ 0.67603E-10 -10.1700 0.56558E-10 -10.2475 0.83661E+00 -0.0775 71 MnF+ 0.10631E-15 -15.9734 0.88943E-16 -16.0509 0.83661E+00 -0.0775 72 MnO,aq 0.17895E-08 -8.7473 0.17895E-08 -8.7473 0.10000E+01 0.0000 73 MnOH+ 0.47303E-09 -9.3251 0.39575E-09 -9.4026 0.83661E+00 -0.0775 74 MnO2-2 0.19995E-10 -10.6991 0.10352E-10 -10.9850 0.51774E+00 -0.2859 75 HMnO2- 0.20572E-09 -9.6867 0.17178E-09 -9.7650 0.83501E+00 -0.0783 78 MnCl+ 0.97850E-14 -14.0094 0.81863E-14 -14.0869 0.83661E+00 -0.0775 79 MnSO4,aq 0.43352E-18 -18.3630 0.43352E-18 -18.3630 0.10000E+01 0.0000 80 NaCl,aq 0.73708E-06 -6.1325 0.73708E-06 -6.1325 0.10000E+01 0.0000 81 NaF,aq 0.20683E-08 -8.6844 0.20683E-08 -8.6844 0.10000E+01 0.0000 82 NaOH,aq 0.94075E-04 -4.0265 0.94075E-04 -4.0265 0.10000E+01 0.0000 84 OH- 0.91522E-02 -2.0385 0.76284E-02 -2.1176 0.83350E+00 -0.0791 89 HPO3-2 0.43968E-15 -15.3569 0.22764E-15 -15.6427 0.51774E+00 -0.2859 91 H2PO3- 0.41406E-19 -19.3829 0.34575E-19 -19.4612 0.83501E+00 -0.0783 92 H3PO4,aq 0.94383E-18 -18.0251 0.94383E-18 -18.0251 0.10000E+01 0.0000 93 H2PO4- 0.39326E-10 -10.4053 0.32869E-10 -10.4832 0.83580E+00 -0.0779 94 PO4-3 0.10464E-08 -8.9803 0.25341E-09 -9.5962 0.24219E+00 -0.6158 98 HP2O7-3 0.96764E-18 -18.0143 0.22332E-18 -18.6511 0.23079E+00 -0.6368 99 P2O7-4 0.91677E-17 -17.0377 0.70440E-18 -18.1522 0.76834E-01 -1.1144 100 H2S,aq 0.11885E-07 -7.9250 0.11844E-07 -7.9265 0.99652E+00 -0.0015 101 S2-2 0.35285E-13 -13.4524 0.18268E-13 -13.7383 0.51774E+00 -0.2859 107 SO3-2 0.11638E-15 -15.9341 0.61130E-16 -16.2137 0.52525E+00 -0.2796 108 HSO3- 0.34717E-18 -18.4595 0.28989E-18 -18.5378 0.83501E+00 -0.0783 109 HSO4- 0.13204E-16 -16.8793 0.11058E-16 -16.9563 0.83743E+00 -0.0771 111 S2O3-2 0.40709E-19 -19.3903 0.21077E-19 -19.6762 0.51774E+00 -0.2859 Charge balance for all species = -.6133E-08 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.9015857E-10 -.2215549E-01 -.2229250E+02 0.0000 2 H2O 0.1000000E+01 0.5550470E+02 0.9981920E+06 0.0000 3 Cl- 0.1606135E-03 0.1613509E-03 0.5710408E+01 6.2481 4 SO4-- 0.2919800E-09 -.1035975E-04 -.9934407E+00 10.4217 5 HCO3- 0.3519258E-04 0.1103549E-03 0.6721819E+01 5.5895 6 HS- 0.6058573E-04 0.7095766E-04 0.2342624E+01 5.8248 7 Al+++ 0.9955120E-29 0.5018668E-05 0.1351753E+00 0.7229 8 H4SiO4 0.7095301E-03 0.1353139E-01 0.1298310E+04 -3.1490 9 Ca++ 0.1123209E-06 0.2158450E-06 0.8635566E-02 13.0036 10 Mg++ 0.2118745E-10 0.9318072E-10 0.2261464E-05 9.2773 11 Fe++ 0.4591834E-13 0.2717746E-07 0.1515136E-02 6.6136 12 K+ 0.1565194E-03 0.1572579E-03 0.6138387E+01 6.2377 13 Na+ 0.1986433E-01 0.2230536E-01 0.5119024E+03 8.3404 14 Mn++ 0.1929778E-10 0.2507518E-08 0.1375180E-03 9.2375 15 F- 0.6393026E-06 0.6413718E-06 0.1216356E-01 3.8472 16 HPO4-- 0.4533382E-07 0.4641950E-07 0.4447536E-02 12.6129 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.1989841E-01 -.1989729E-01 -.1115362E-05 0.0000000E+00 2 H2O 0.4984738E+02 0.4984738E+02 -.1071709E-05 0.0000000E+00 3 Cl- 0.1449052E-03 0.1449052E-03 0.0000000E+00 0.0000000E+00 4 SO4-- -.9302810E-05 -.9303833E-05 0.1023109E-08 0.0000000E+00 5 HCO3- 0.9910700E-04 0.9910700E-04 0.0000000E+00 0.0000000E+00 6 HS- 0.6372428E-04 0.6372530E-04 -.1023109E-08 0.0000000E+00 7 Al+++ 0.4775352E-05 0.4507140E-05 0.2682115E-06 0.0000000E+00 8 H4SiO4 0.1215302E-01 0.1215221E-01 0.8149507E-06 0.0000000E+00 9 Ca++ 0.2080835E-06 0.1938450E-06 0.1423853E-07 0.0000000E+00 10 Mg++ 0.8368328E-10 0.8368328E-10 0.0000000E+00 0.0000000E+00 11 Fe++ 0.3259227E-07 0.2440739E-07 0.8184876E-08 0.0000000E+00 12 K+ 0.1412294E-03 0.1412294E-03 0.0000000E+00 0.0000000E+00 13 Na+ 0.2003215E-01 0.2003188E-01 0.2669041E-06 0.0000000E+00 14 Mn++ 0.2251939E-08 0.2251939E-08 0.0000000E+00 0.0000000E+00 15 F- 0.5760000E-06 0.5760000E-06 0.0000000E+00 0.0000000E+00 16 HPO4-- 0.4168819E-07 0.4168819E-07 0.0000000E+00 0.0000000E+00 Chg. balance for solid moles: -.1588E-21 Mass of aqueous solution: 0.899642E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 0.0011900 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 0.2669E-06 -6.574 0.6999E-04 -4.155 96.72 0.2687E-04 andradite 0.4092E-08 -8.388 0.2080E-05 -5.682 2.874 0.5403E-06 grossular 0.6537E-09 -9.185 0.2945E-06 -6.531 0.4070 0.8194E-07 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8623E+00 0.8623E+00 1.0000 -0.064 grossular 0.1377E+00 0.1377E+00 1.0000 -0.861 Solid products produced: Mass = 0.000072 g Volume = 0.000027 cm3 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.0011900 moles log = -2.9245 Original solution: 1000.0103000 g Original solution / Rock added: 840344.79 (Water/Rock Ratio), log = 5.9245 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0385 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9827E+00 0.9857 0.1006E+01 0.1021E+01 CO2,gas 0.4873E-06 1.0069 0.5096E-06 0.5061E-06 CH4,gas 0.1337E-01 1.0124 0.1405E-01 0.1388E-01 H2,gas 0.3923E-02 1.0006 0.4077E-02 0.4074E-02 H2S,gas 0.3148E-06 0.9960 0.3256E-06 0.3269E-06 S2,gas 0.2305E-27 1.0000 0.2394E-27 0.2394E-27 CO,gas 0.5331E-12 1.0000 0.5536E-12 0.5536E-12 SO3,gas 0.3164E-45 1.0000 0.3286E-45 0.3286E-45 SO2,gas 0.5018E-25 1.0000 0.5212E-25 0.5212E-25 HF,gas 0.6531E-15 1.0000 0.6782E-15 0.6782E-15 HCl,gas 0.3163E-17 1.0000 0.3284E-17 0.3284E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 17 albite -0.38 -0.38 0.00 0.000 0.11184E-10 23 andradite 39.01 39.01 0.00 0.000 -0.24265E-10 24 grossular 32.73 32.73 0.00 0.000 0.12132E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -14.65 -7.99 -2.664 0.13646E+05 -6.293 3 CH4,gas 4.54 0.99 -3.55 -0.888 0.60635E+04 -1.852 4 H2,gas 8.00 3.91 -4.09 -2.336 0.69813E+04 -2.390 5 H2S,gas -6.23 -14.42 -8.19 -4.093 0.13978E+05 -6.487 6 S2,gas -7.34 -36.66 -29.32 -4.511 0.50063E+05 -27.621 7 CO,gas 3.21 -10.74 -13.96 -4.294 0.23829E+05 -12.257 8 SO3,gas 17.12 -30.06 -47.18 -11.796 0.80563E+05 -45.483 9 SO2,gas 0.83 -26.15 -26.98 -7.195 0.46071E+05 -25.283 10 HF,gas 0.47 -16.39 -16.87 -8.434 0.28801E+05 -15.169 11 HCl,gas 5.19 -13.99 -19.18 -9.591 0.32754E+05 -17.484 12 acmite 7.71 6.70 -1.01 -0.105 0.17234E+04 16 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 20 spessartine 24.46 19.71 -4.75 -0.237 0.81039E+04 21 analcite 3.32 2.77 -0.56 -0.062 0.95055E+03 27 annite 20.12 17.35 -2.77 -0.154 0.47280E+04 28 phlogopite 27.06 25.35 -1.72 -0.096 0.29358E+04 30 anorthite 12.71 8.15 -4.56 -0.351 0.77844E+04 33 apatite-OH -18.15 -18.59 -0.44 -0.034 0.74752E+03 34 apatite-F -34.30 -34.99 -0.68 -0.057 0.11687E+04 38 aragonite 0.97 -1.65 -2.61 -0.872 0.44647E+04 39 brucite 12.57 9.28 -3.29 -0.658 0.56198E+04 40 calcite 0.81 -1.65 -2.46 -0.820 0.42004E+04 41 carnegieite-low 9.02 5.91 -3.11 -0.444 0.53087E+04 42 carnegieite-high 10.09 5.91 -4.18 -0.597 0.71357E+04 43 carpholite-Mg 8.58 4.42 -4.16 -0.277 0.70983E+04 44 carpholite-Fe 6.71 1.76 -4.95 -0.330 0.84543E+04 45 celadonite 5.34 3.64 -1.70 -0.100 0.29026E+04 46 celadonite-Fe 3.88 0.98 -2.90 -0.170 0.49490E+04 47 chrysotile 23.89 21.53 -2.36 -0.197 0.40274E+04 49 clinochlore 39.07 38.38 -0.68 -0.021 0.11689E+04 50 daphnite 28.97 25.07 -3.90 -0.122 0.66564E+04 52 chlorite-Al-free 47.17 43.07 -4.11 -0.171 0.70099E+04 54 chloritoid-Fe 9.17 4.91 -4.26 -0.284 0.72794E+04 55 chloritoid-Mn 11.40 7.53 -3.87 -0.258 0.66026E+04 57 coesite -2.38 -3.15 -0.77 -0.258 0.13198E+04 64 cristobalite -2.56 -3.15 -0.59 -0.196 0.10052E+04 66 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71235E+04 68 diaspore 2.87 0.72 -2.15 -0.358 0.36725E+04 69 diamond -3.10 -6.83 -3.73 -1.065 0.63643E+04 70 diopside 16.18 15.98 -0.20 -0.020 0.33895E+03 71 hedenbergite 14.21 13.32 -0.89 -0.089 0.15180E+04 76 clinoenstatite 17.17 12.26 -4.91 -0.491 0.83834E+04 78 epidote 24.67 22.66 -2.01 -0.097 0.34250E+04 79 clinozoisite 22.81 18.73 -4.08 -0.185 0.69618E+04 80 epidote-Fe 29.84 26.60 -3.24 -0.168 0.55349E+04 81 fayalite 14.05 10.08 -3.97 -0.567 0.67743E+04 82 ferrosilite 11.15 6.93 -4.22 -0.422 0.72059E+04 86 gibbsite 4.08 0.72 -3.36 -0.479 0.57310E+04 87 glaucophane 22.97 20.77 -2.21 -0.060 0.37715E+04 88 glaucophane-Fe 17.28 12.78 -4.50 -0.122 0.76848E+04 89 graphite -3.55 -6.83 -3.28 -0.938 0.56065E+04 90 greenalite 16.14 13.54 -2.60 -0.216 0.44337E+04 93 hematite 12.57 9.32 -3.25 -0.394 0.55493E+04 94 heulandite -5.83 -7.59 -1.77 -0.080 0.30164E+04 98 jadeite 4.22 2.77 -1.45 -0.145 0.24760E+04 100 kalsilite 7.58 3.81 -3.77 -0.539 0.64413E+04 101 kaolinite -1.33 -4.85 -3.52 -0.320 0.60096E+04 104 laumontite 2.88 1.85 -1.03 -0.069 0.17590E+04 105 lawsonite 9.62 8.15 -1.46 -0.098 0.25011E+04 106 leucite 4.12 0.66 -3.46 -0.346 0.59017E+04 108 lizardite 23.24 21.53 -1.71 -0.143 0.29200E+04 110 magnetite 20.09 15.93 -4.16 -0.339 0.70989E+04 111 minnesotaite 10.39 7.24 -3.14 -0.185 0.53671E+04 115 manganosite 14.06 9.24 -4.82 -1.205 0.82310E+04 119 microcline -2.49 -2.49 0.00 0.000 0.10125E+00 123 muscovite 2.58 -1.04 -3.62 -0.213 0.61866E+04 124 paragonite 4.24 1.06 -3.18 -0.187 0.54256E+04 125 nepheline 8.34 5.91 -2.43 -0.346 0.41411E+04 137 phlogopite-Na 29.65 27.45 -2.20 -0.122 0.37545E+04 139 prehnite 19.37 18.01 -1.37 -0.080 0.23324E+04 140 prehnite-Fe 22.50 21.94 -0.56 -0.033 0.95058E+03 141 pumpellyite-Fe 46.27 43.35 -2.92 -0.065 0.49877E+04 142 pumpellyite-Mg 48.99 46.01 -2.98 -0.066 0.50933E+04 145 pyrite -21.25 -26.13 -4.88 -1.149 0.83387E+04 146 pyrrhotite -4.26 -7.80 -3.54 -1.181 0.60489E+04 147 pyrrhotiteFe0.875 -6.02 -9.11 -3.10 -1.139 0.52891E+04 148 pyroxmangite 7.40 6.09 -1.31 -0.262 0.22371E+04 149 pyrophyllite -6.18 -11.15 -4.97 -0.311 0.84940E+04 150 quartz -2.99 -3.15 -0.16 -0.053 0.27250E+03 154 rhodochrosite -0.98 -5.41 -4.44 -1.479 0.75778E+04 155 rhodonite 7.45 6.09 -1.36 -0.271 0.23173E+04 156 sanidine -1.28 -2.49 -1.21 -0.093 0.20679E+04 166 stilbite -7.52 -7.59 -0.07 -0.003 0.12259E+03 167 stilpnomelane-Fe 13.02 12.44 -0.58 -0.017 0.98421E+03 168 stilpnomelane-Mg 27.44 25.76 -1.68 -0.050 0.28733E+04 174 talc 16.49 15.24 -1.26 -0.074 0.21436E+04 177 tephroite 18.09 15.33 -2.76 -0.394 0.47122E+04 181 tridymite -2.63 -3.15 -0.52 -0.174 0.89248E+03 182 tremolite 47.87 47.20 -0.67 -0.018 0.11404E+04 183 ferroactinolite 38.45 33.88 -4.57 -0.123 0.78016E+04 184 troilite-low -4.41 -7.80 -3.39 -1.131 0.57917E+04 190 wairakite 3.95 1.85 -2.10 -0.123 0.35809E+04 191 walstromite 11.51 9.85 -1.65 -0.331 0.28252E+04 192 wollastonite 10.46 9.85 -0.61 -0.121 0.10356E+04 193 pseudo-wollastonite 11.00 9.85 -1.15 -0.229 0.19555E+04 194 zoisite 22.85 18.73 -4.12 -0.187 0.70359E+04 195 akaganeite 7.75 4.66 -3.10 -0.670 0.52872E+04 202 chalcedony -2.80 -3.15 -0.35 -0.116 0.59180E+03 204 montmorillonite-Ca -2.29 -6.18 -3.89 -0.241 0.66440E+04 205 montmorillonite-K -2.24 -6.27 -4.03 -0.247 0.68850E+04 206 montmorillonite-Mg -2.48 -6.80 -4.32 -0.267 0.73709E+04 207 montmorillonite-Na -2.04 -5.58 -3.54 -0.217 0.60399E+04 208 nontronite-Ca 3.21 0.14 -3.07 -0.199 0.52439E+04 209 nontronite-H 2.53 -2.00 -4.53 -0.304 0.77432E+04 210 nontronite-K 3.34 0.06 -3.28 -0.211 0.56081E+04 211 nontronite-Mg 3.07 -0.47 -3.55 -0.230 0.60548E+04 212 nontronite-Na 3.52 0.75 -2.77 -0.178 0.47290E+04 228 tobermorite 9.82 7.68 -2.14 -0.584 0.36541E+04 234 alabandite -0.98 -5.18 -4.20 -1.400 0.71734E+04 237 boehmite 4.41 0.72 -3.68 -0.614 0.62894E+04 239 ferrous-oxide 9.81 6.61 -3.20 -0.799 0.54604E+04 245 silica-amorphous -2.09 -3.15 -1.06 -0.353 0.18060E+04 247 an20ab80 2.02 1.32 -0.69 -0.053 0.11860E+04 248 an25ab75 2.65 1.75 -0.90 -0.069 0.15295E+04 249 an30ab70 3.28 2.18 -1.10 -0.085 0.18826E+04 250 tr.625ac.25prg.125 45.16 44.81 -0.35 -0.009 0.60049E+03 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 0.0000400 MOLES Current total amount of reactant added: 0.0011900 MOLES New total amount of reactant added: 0.0012300 MOLES Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.5508E-08 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 7 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 0.0012300 Water: Moles liquid = 0.4985E+02 kg liquid = 0.8981E+00 Moles total = 0.4985E+02 kg total = 0.8980E+00 Activity = 1.0000 Stoichiometric ionic strength = .1140869E-01 Osmotic coef. = 0.9656 True ionic strength = .2008923E-01 Chg. balance for total moles = -.5508E-08 Max. difference allowed = 0.1451E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.90223E-10 -10.0447 0.75794E-10 -10.1204 0.84007E+00 -0.0757 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.16087E-03 -3.7935 0.13433E-03 -3.8718 0.83500E+00 -0.0783 4 SO4-- 0.31405E-09 -9.5030 0.16294E-09 -9.7880 0.51883E+00 -0.2850 5 HCO3- 0.36404E-04 -4.4389 0.30442E-04 -4.5165 0.83623E+00 -0.0777 6 HS- 0.61668E-04 -4.2099 0.51500E-04 -4.2882 0.83513E+00 -0.0782 7 Al+++ 0.99643E-29 -29.0016 0.22972E-29 -29.6388 0.23054E+00 -0.6372 8 H4SiO4 0.71000E-03 -3.1487 0.71000E-03 -3.1487 0.10000E+01 0.0000 9 Ca++ 0.11193E-06 -6.9511 0.57645E-07 -7.2392 0.51501E+00 -0.2882 10 Mg++ 0.21190E-10 -10.6739 0.10863E-10 -10.9641 0.51265E+00 -0.2902 11 Fe++ 0.46016E-13 -13.3371 0.23616E-13 -13.6268 0.51321E+00 -0.2897 12 K+ 0.15652E-03 -3.8054 0.13092E-03 -3.8830 0.83643E+00 -0.0776 13 Na+ 0.19864E-01 -1.7019 0.16584E-01 -1.7803 0.83485E+00 -0.0784 14 Mn++ 0.19324E-10 -10.7139 0.99257E-11 -11.0032 0.51364E+00 -0.2893 15 F- 0.65706E-06 -6.1824 0.54751E-06 -6.2616 0.83328E+00 -0.0792 16 HPO4-- 0.45334E-07 -7.3436 0.23524E-07 -7.6285 0.51890E+00 -0.2849 18 HSiO3- 0.10475E-01 -1.9798 0.87469E-02 -2.0581 0.83500E+00 -0.0783 19 Ca(HSiO3)+ 0.13725E-07 -7.8625 0.11483E-07 -7.9400 0.83661E+00 -0.0775 20 Mg(HSiO3)+ 0.32189E-11 -11.4923 0.26930E-11 -11.5698 0.83661E+00 -0.0775 21 NaHSiO3,aq 0.23461E-02 -2.6297 0.23461E-02 -2.6297 0.10000E+01 0.0000 22 AlO+ 0.65026E-16 -16.1869 0.54401E-16 -16.2644 0.83661E+00 -0.0775 24 HAlO2,aq 0.14294E-09 -9.8448 0.14294E-09 -9.8448 0.10000E+01 0.0000 25 AlO2- 0.50086E-05 -5.3003 0.41746E-05 -5.3794 0.83349E+00 -0.0791 26 CH4,aq 0.93793E-05 -5.0278 0.93466E-05 -5.0293 0.99652E+00 -0.0015 27 C2H6,aq 0.48942E-14 -14.3103 0.48772E-14 -14.3118 0.99652E+00 -0.0015 31 CO,aq 0.37925E-15 -15.4211 0.37925E-15 -15.4211 0.10000E+01 0.0000 32 CO2,aq 0.49474E-08 -8.3056 0.49302E-08 -8.3071 0.99652E+00 -0.0015 33 CO3-2 0.67762E-04 -4.1690 0.35082E-04 -4.4549 0.51773E+00 -0.2859 34 CaCO3,aq 0.25357E-07 -7.5959 0.25357E-07 -7.5959 0.10000E+01 0.0000 35 Ca(HCO3)+ 0.53542E-10 -10.2713 0.44793E-10 -10.3488 0.83661E+00 -0.0775 36 CaCl+ 0.14979E-10 -10.8245 0.12531E-10 -10.9020 0.83661E+00 -0.0775 37 CaCl2,aq 0.39993E-15 -15.3980 0.39993E-15 -15.3980 0.10000E+01 0.0000 38 CaF+ 0.55079E-12 -12.2590 0.46080E-12 -12.3365 0.83661E+00 -0.0775 39 CaOH+ 0.64790E-07 -7.1885 0.54204E-07 -7.2660 0.83661E+00 -0.0775 40 CaSO4,aq 0.29825E-14 -14.5254 0.29825E-14 -14.5254 0.10000E+01 0.0000 41 HCl,aq 0.18657E-14 -14.7292 0.18657E-14 -14.7292 0.10000E+01 0.0000 45 HF,aq 0.28408E-12 -12.5466 0.28408E-12 -12.5466 0.10000E+01 0.0000 46 HF2- 0.62891E-19 -19.2014 0.52514E-19 -19.2797 0.83500E+00 -0.0783 48 FeCl+ 0.60020E-17 -17.2217 0.50213E-17 -17.2992 0.83661E+00 -0.0775 51 FeF+ 0.78980E-18 -18.1025 0.66075E-18 -18.1800 0.83661E+00 -0.0775 53 FeO,aq 0.15977E-09 -9.7965 0.15977E-09 -9.7965 0.10000E+01 0.0000 54 FeOH+ 0.12123E-10 -10.9164 0.10142E-10 -10.9939 0.83661E+00 -0.0775 55 HFeO2- 0.26415E-07 -7.5782 0.22056E-07 -7.6565 0.83500E+00 -0.0783 56 FeO+ 0.16525E-16 -16.7819 0.13825E-16 -16.8593 0.83661E+00 -0.0775 58 FeO2- 0.58972E-09 -9.2294 0.49242E-09 -9.3077 0.83500E+00 -0.0783 59 HFeO2,aq 0.47468E-11 -11.3236 0.47468E-11 -11.3236 0.10000E+01 0.0000 60 H2,aq 0.30728E-05 -5.5125 0.30621E-05 -5.5140 0.99652E+00 -0.0015 61 KCl,aq 0.31874E-09 -9.4966 0.31874E-09 -9.4966 0.10000E+01 0.0000 63 KOH,aq 0.73765E-06 -6.1322 0.73765E-06 -6.1322 0.10000E+01 0.0000 64 KSO4- 0.39642E-12 -12.4018 0.33101E-12 -12.4802 0.83500E+00 -0.0783 65 MgCO3,aq 0.11978E-11 -11.9216 0.11978E-11 -11.9216 0.10000E+01 0.0000 66 Mg(HCO3)+ 0.10310E-13 -13.9867 0.86253E-14 -14.0642 0.83661E+00 -0.0775 67 MgCl+ 0.25583E-14 -14.5920 0.21403E-14 -14.6695 0.83661E+00 -0.0775 68 MgF+ 0.38449E-15 -15.4151 0.32167E-15 -15.4926 0.83661E+00 -0.0775 69 MgOH+ 0.67561E-10 -10.1703 0.56522E-10 -10.2478 0.83661E+00 -0.0775 71 MnF+ 0.10941E-15 -15.9609 0.91536E-16 -16.0384 0.83661E+00 -0.0775 72 MnO,aq 0.17893E-08 -8.7473 0.17893E-08 -8.7473 0.10000E+01 0.0000 73 MnOH+ 0.47334E-09 -9.3248 0.39600E-09 -9.4023 0.83661E+00 -0.0775 74 MnO2-2 0.19966E-10 -10.6997 0.10337E-10 -10.9856 0.51773E+00 -0.2859 75 HMnO2- 0.20556E-09 -9.6871 0.17165E-09 -9.7654 0.83500E+00 -0.0783 78 MnCl+ 0.98141E-14 -14.0081 0.82106E-14 -14.0856 0.83661E+00 -0.0775 79 MnSO4,aq 0.46689E-18 -18.3308 0.46689E-18 -18.3308 0.10000E+01 0.0000 80 NaCl,aq 0.73828E-06 -6.1318 0.73828E-06 -6.1318 0.10000E+01 0.0000 81 NaF,aq 0.21258E-08 -8.6725 0.21258E-08 -8.6725 0.10000E+01 0.0000 82 NaOH,aq 0.94008E-04 -4.0268 0.94008E-04 -4.0268 0.10000E+01 0.0000 84 OH- 0.91458E-02 -2.0388 0.76230E-02 -2.1179 0.83349E+00 -0.0791 89 HPO3-2 0.43359E-15 -15.3629 0.22448E-15 -15.6488 0.51773E+00 -0.2859 91 H2PO3- 0.40861E-19 -19.3887 0.34119E-19 -19.4670 0.83500E+00 -0.0783 92 H3PO4,aq 0.94516E-18 -18.0245 0.94516E-18 -18.0245 0.10000E+01 0.0000 93 H2PO4- 0.39353E-10 -10.4050 0.32891E-10 -10.4829 0.83580E+00 -0.0779 94 PO4-3 0.10457E-08 -8.9806 0.25323E-09 -9.5965 0.24217E+00 -0.6159 98 HP2O7-3 0.96836E-18 -18.0140 0.22347E-18 -18.6508 0.23078E+00 -0.6368 99 P2O7-4 0.91685E-17 -17.0377 0.70437E-18 -18.1522 0.76825E-01 -1.1145 100 H2S,aq 0.12106E-07 -7.9170 0.12064E-07 -7.9185 0.99652E+00 -0.0015 101 S2-2 0.37071E-13 -13.4310 0.19192E-13 -13.7169 0.51773E+00 -0.2859 107 SO3-2 0.12344E-15 -15.9085 0.64836E-16 -16.1882 0.52523E+00 -0.2796 108 HSO3- 0.36849E-18 -18.4336 0.30769E-18 -18.5119 0.83500E+00 -0.0783 109 HSO4- 0.14212E-16 -16.8473 0.11901E-16 -16.9244 0.83742E+00 -0.0771 111 S2O3-2 0.44599E-19 -19.3507 0.23090E-19 -19.6366 0.51773E+00 -0.2859 Charge balance for all species = -.6133E-08 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.9022335E-10 -.2215064E-01 -.2228762E+02 0.0000 2 H2O 0.1000000E+01 0.5550469E+02 0.9981917E+06 0.0000 3 Cl- 0.1608749E-03 0.1616135E-03 0.5719704E+01 6.2485 4 SO4-- 0.3140458E-09 -.1014706E-04 -.9730452E+00 10.4528 5 HCO3- 0.3640394E-04 0.1135751E-03 0.6917959E+01 5.6038 6 HS- 0.6166776E-04 0.7182724E-04 0.2371332E+01 5.8322 7 Al+++ 0.9964284E-29 0.5008711E-05 0.1349071E+00 0.7223 8 H4SiO4 0.7100020E-03 0.1353135E-01 0.1298306E+04 -3.1487 9 Ca++ 0.1119289E-06 0.2158703E-06 0.8636576E-02 13.0015 10 Mg++ 0.2118984E-10 0.9318065E-10 0.2261462E-05 9.2767 11 Fe++ 0.4601609E-13 0.2718091E-07 0.1515328E-02 6.6139 12 K+ 0.1565198E-03 0.1572578E-03 0.6138382E+01 6.2374 13 Na+ 0.1986448E-01 0.2230533E-01 0.5119017E+03 8.3401 14 Mn++ 0.1932433E-10 0.2507516E-08 0.1375179E-03 9.2375 15 F- 0.6570606E-06 0.6591872E-06 0.1250142E-01 3.8588 16 HPO4-- 0.4533445E-07 0.4641946E-07 0.4447532E-02 12.6122 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.1989410E-01 -.1989295E-01 -.1151078E-05 0.0000000E+00 2 H2O 0.4984742E+02 0.4984742E+02 -.1107511E-05 0.0000000E+00 3 Cl- 0.1451412E-03 0.1451412E-03 0.0000000E+00 0.0000000E+00 4 SO4-- -.9111810E-05 -.9112833E-05 0.1022720E-08 0.0000000E+00 5 HCO3- 0.1019990E-03 0.1019990E-03 0.0000000E+00 0.0000000E+00 6 HS- 0.6450528E-04 0.6450630E-04 -.1022720E-08 0.0000000E+00 7 Al+++ 0.4775352E-05 0.4498202E-05 0.2771504E-06 0.0000000E+00 8 H4SiO4 0.1215302E-01 0.1215218E-01 0.8417807E-06 0.0000000E+00 9 Ca++ 0.2080835E-06 0.1938678E-06 0.1421567E-07 0.0000000E+00 10 Mg++ 0.8368328E-10 0.8368328E-10 0.0000000E+00 0.0000000E+00 11 Fe++ 0.3259227E-07 0.2441051E-07 0.8181757E-08 0.0000000E+00 12 K+ 0.1412294E-03 0.1412294E-03 0.0000000E+00 0.0000000E+00 13 Na+ 0.2003215E-01 0.2003187E-01 0.2758550E-06 0.0000000E+00 14 Mn++ 0.2251939E-08 0.2251939E-08 0.0000000E+00 0.0000000E+00 15 F- 0.5920000E-06 0.5920000E-06 0.0000000E+00 0.0000000E+00 16 HPO4-- 0.4168819E-07 0.4168819E-07 0.0000000E+00 0.0000000E+00 Chg. balance for solid moles: 0.5294E-22 Mass of aqueous solution: 0.899643E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 0.0012300 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 0.2759E-06 -6.559 0.7233E-04 -4.141 96.83 0.2777E-04 andradite 0.4091E-08 -8.388 0.2079E-05 -5.682 2.783 0.5401E-06 grossular 0.6477E-09 -9.189 0.2917E-06 -6.535 0.3905 0.8118E-07 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8633E+00 0.8633E+00 1.0000 -0.064 grossular 0.1367E+00 0.1367E+00 1.0000 -0.864 Solid products produced: Mass = 0.000075 g Volume = 0.000028 cm3 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.0012300 moles log = -2.9101 Original solution: 1000.0103000 g Original solution / Rock added: 813016.50 (Water/Rock Ratio), log = 5.9101 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0382 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9830E+00 0.9857 0.1006E+01 0.1021E+01 CO2,gas 0.5046E-06 1.0069 0.5275E-06 0.5238E-06 CH4,gas 0.1309E-01 1.0124 0.1376E-01 0.1359E-01 H2,gas 0.3870E-02 1.0006 0.4020E-02 0.4018E-02 H2S,gas 0.3207E-06 0.9960 0.3316E-06 0.3330E-06 S2,gas 0.2460E-27 1.0000 0.2554E-27 0.2554E-27 CO,gas 0.5444E-12 1.0000 0.5651E-12 0.5651E-12 SO3,gas 0.3409E-45 1.0000 0.3539E-45 0.3539E-45 SO2,gas 0.5332E-25 1.0000 0.5535E-25 0.5535E-25 HF,gas 0.6719E-15 1.0000 0.6975E-15 0.6975E-15 HCl,gas 0.3171E-17 1.0000 0.3292E-17 0.3292E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 17 albite -0.38 -0.38 0.00 0.000 -0.94784E-12 23 andradite 39.01 39.01 0.00 0.000 0.12132E-10 24 grossular 32.73 32.73 0.00 0.000 0.00000E+00 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -14.64 -7.98 -2.659 0.13620E+05 -6.278 3 CH4,gas 4.54 0.98 -3.56 -0.890 0.60793E+04 -1.861 4 H2,gas 8.00 3.91 -4.09 -2.340 0.69916E+04 -2.396 5 H2S,gas -6.23 -14.41 -8.18 -4.089 0.13964E+05 -6.479 6 S2,gas -7.34 -36.63 -29.29 -4.506 0.50015E+05 -27.593 7 CO,gas 3.21 -10.73 -13.95 -4.291 0.23814E+05 -12.248 8 SO3,gas 17.12 -30.03 -47.15 -11.788 0.80507E+05 -45.451 9 SO2,gas 0.83 -26.12 -26.96 -7.188 0.46026E+05 -25.257 10 HF,gas 0.47 -16.38 -16.86 -8.428 0.28780E+05 -15.156 11 HCl,gas 5.19 -13.99 -19.18 -9.591 0.32752E+05 -17.483 12 acmite 7.71 6.70 -1.01 -0.104 0.17172E+04 16 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 20 spessartine 24.46 19.71 -4.75 -0.237 0.81045E+04 21 analcite 3.32 2.76 -0.56 -0.062 0.95104E+03 27 annite 20.12 17.36 -2.77 -0.154 0.47265E+04 28 phlogopite 27.06 25.34 -1.72 -0.096 0.29387E+04 30 anorthite 12.71 8.15 -4.56 -0.351 0.77890E+04 33 apatite-OH -18.15 -18.60 -0.45 -0.034 0.76274E+03 34 apatite-F -34.30 -34.98 -0.68 -0.057 0.11631E+04 38 aragonite 0.97 -1.64 -2.60 -0.867 0.44427E+04 39 brucite 12.57 9.28 -3.29 -0.658 0.56208E+04 40 calcite 0.81 -1.64 -2.45 -0.816 0.41785E+04 41 carnegieite-low 9.02 5.91 -3.11 -0.444 0.53097E+04 42 carnegieite-high 10.09 5.91 -4.18 -0.597 0.71367E+04 43 carpholite-Mg 8.58 4.42 -4.16 -0.277 0.71002E+04 44 carpholite-Fe 6.71 1.76 -4.95 -0.330 0.84547E+04 45 celadonite 5.34 3.64 -1.70 -0.100 0.29031E+04 46 celadonite-Fe 3.88 0.98 -2.90 -0.170 0.49481E+04 47 chrysotile 23.89 21.53 -2.36 -0.197 0.40294E+04 49 clinochlore 39.07 38.38 -0.69 -0.021 0.11743E+04 50 daphnite 28.97 25.07 -3.90 -0.122 0.66543E+04 52 chlorite-Al-free 47.17 43.07 -4.11 -0.171 0.70139E+04 54 chloritoid-Fe 9.17 4.91 -4.26 -0.284 0.72804E+04 55 chloritoid-Mn 11.40 7.53 -3.87 -0.258 0.66040E+04 57 coesite -2.38 -3.15 -0.77 -0.258 0.13193E+04 64 cristobalite -2.56 -3.15 -0.59 -0.196 0.10047E+04 66 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71235E+04 68 diaspore 2.87 0.72 -2.15 -0.359 0.36734E+04 69 diamond -3.10 -6.83 -3.72 -1.064 0.63594E+04 70 diopside 16.18 15.98 -0.20 -0.020 0.34263E+03 71 hedenbergite 14.21 13.32 -0.89 -0.089 0.15202E+04 76 clinoenstatite 17.17 12.26 -4.91 -0.491 0.83844E+04 78 epidote 24.67 22.66 -2.01 -0.097 0.34271E+04 79 clinozoisite 22.81 18.72 -4.08 -0.186 0.69705E+04 80 epidote-Fe 29.84 26.60 -3.24 -0.168 0.55303E+04 81 fayalite 14.05 10.08 -3.97 -0.567 0.67728E+04 82 ferrosilite 11.15 6.93 -4.22 -0.422 0.72039E+04 86 gibbsite 4.08 0.72 -3.36 -0.480 0.57320E+04 87 glaucophane 22.97 20.76 -2.21 -0.060 0.37735E+04 88 glaucophane-Fe 17.28 12.78 -4.50 -0.122 0.76823E+04 89 graphite -3.55 -6.83 -3.28 -0.937 0.56016E+04 90 greenalite 16.14 13.54 -2.60 -0.216 0.44312E+04 93 hematite 12.57 9.32 -3.24 -0.393 0.55379E+04 94 heulandite -5.83 -7.60 -1.77 -0.080 0.30185E+04 98 jadeite 4.22 2.76 -1.45 -0.145 0.24765E+04 100 kalsilite 7.58 3.81 -3.77 -0.539 0.64423E+04 101 kaolinite -1.33 -4.85 -3.52 -0.320 0.60105E+04 104 laumontite 2.88 1.85 -1.03 -0.069 0.17626E+04 105 lawsonite 9.62 8.15 -1.47 -0.098 0.25056E+04 106 leucite 4.12 0.66 -3.46 -0.346 0.59022E+04 108 lizardite 23.24 21.53 -1.71 -0.143 0.29220E+04 110 magnetite 20.09 15.94 -4.15 -0.339 0.70871E+04 111 minnesotaite 10.39 7.25 -3.14 -0.185 0.53636E+04 115 manganosite 14.06 9.24 -4.82 -1.205 0.82311E+04 119 microcline -2.49 -2.49 0.00 0.000 0.10470E+00 123 muscovite 2.58 -1.04 -3.62 -0.213 0.61885E+04 124 paragonite 4.24 1.06 -3.18 -0.187 0.54275E+04 125 nepheline 8.34 5.91 -2.43 -0.347 0.41421E+04 137 phlogopite-Na 29.65 27.45 -2.20 -0.122 0.37575E+04 139 prehnite 19.37 18.00 -1.37 -0.081 0.23401E+04 140 prehnite-Fe 22.50 21.94 -0.56 -0.034 0.95171E+03 141 pumpellyite-Fe 46.27 43.34 -2.93 -0.065 0.50037E+04 142 pumpellyite-Mg 48.99 46.00 -2.99 -0.067 0.51108E+04 145 pyrite -21.25 -26.11 -4.86 -1.144 0.83005E+04 146 pyrrhotite -4.26 -7.79 -3.53 -1.178 0.60347E+04 147 pyrrhotiteFe0.875 -6.02 -9.11 -3.09 -1.136 0.52738E+04 148 pyroxmangite 7.40 6.09 -1.31 -0.262 0.22367E+04 149 pyrophyllite -6.18 -11.15 -4.97 -0.311 0.84939E+04 150 quartz -2.99 -3.15 -0.16 -0.053 0.27201E+03 154 rhodochrosite -0.98 -5.40 -4.42 -1.474 0.75523E+04 155 rhodonite 7.45 6.09 -1.36 -0.271 0.23169E+04 156 sanidine -1.28 -2.49 -1.21 -0.093 0.20679E+04 166 stilbite -7.52 -7.60 -0.07 -0.003 0.12471E+03 167 stilpnomelane-Fe 13.02 12.44 -0.57 -0.017 0.97994E+03 168 stilpnomelane-Mg 27.44 25.76 -1.68 -0.050 0.28765E+04 174 talc 16.49 15.24 -1.26 -0.074 0.21446E+04 177 tephroite 18.09 15.33 -2.76 -0.394 0.47118E+04 181 tridymite -2.63 -3.15 -0.52 -0.174 0.89199E+03 182 tremolite 47.87 47.20 -0.67 -0.018 0.11488E+04 183 ferroactinolite 38.45 33.88 -4.57 -0.124 0.78025E+04 184 troilite-low -4.41 -7.79 -3.38 -1.128 0.57775E+04 190 wairakite 3.95 1.85 -2.10 -0.123 0.35846E+04 191 walstromite 11.51 9.85 -1.66 -0.331 0.28284E+04 192 wollastonite 10.46 9.85 -0.61 -0.122 0.10388E+04 193 pseudo-wollastonite 11.00 9.85 -1.15 -0.229 0.19586E+04 194 zoisite 22.85 18.72 -4.13 -0.188 0.70446E+04 195 akaganeite 7.75 4.66 -3.09 -0.669 0.52815E+04 202 chalcedony -2.80 -3.15 -0.35 -0.115 0.59131E+03 204 montmorillonite-Ca -2.29 -6.18 -3.89 -0.241 0.66445E+04 205 montmorillonite-K -2.24 -6.27 -4.03 -0.247 0.68852E+04 206 montmorillonite-Mg -2.48 -6.80 -4.32 -0.267 0.73710E+04 207 montmorillonite-Na -2.04 -5.58 -3.54 -0.217 0.60400E+04 208 nontronite-Ca 3.21 0.15 -3.06 -0.199 0.52317E+04 209 nontronite-H 2.53 -1.99 -4.53 -0.303 0.77304E+04 210 nontronite-K 3.34 0.06 -3.28 -0.210 0.55955E+04 211 nontronite-Mg 3.07 -0.46 -3.54 -0.230 0.60421E+04 212 nontronite-Na 3.52 0.76 -2.76 -0.177 0.47163E+04 228 tobermorite 9.82 7.68 -2.14 -0.584 0.36566E+04 234 alabandite -0.98 -5.17 -4.19 -1.398 0.71598E+04 237 boehmite 4.41 0.72 -3.68 -0.614 0.62904E+04 239 ferrous-oxide 9.81 6.61 -3.20 -0.799 0.54599E+04 245 silica-amorphous -2.09 -3.15 -1.06 -0.352 0.18055E+04 247 an20ab80 2.02 1.32 -0.70 -0.053 0.11869E+04 248 an25ab75 2.65 1.75 -0.90 -0.069 0.15307E+04 249 an30ab70 3.28 2.18 -1.10 -0.085 0.18840E+04 250 tr.625ac.25prg.125 45.16 44.81 -0.36 -0.010 0.60741E+03 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 0.0000400 MOLES Current total amount of reactant added: 0.0012300 MOLES New total amount of reactant added: 0.0012700 MOLES Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.5508E-08 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 7 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 0.0012700 Water: Moles liquid = 0.4985E+02 kg liquid = 0.8981E+00 Moles total = 0.4985E+02 kg total = 0.8980E+00 Activity = 1.0000 Stoichiometric ionic strength = .1141124E-01 Osmotic coef. = 0.9655 True ionic strength = .2009159E-01 Chg. balance for total moles = -.5508E-08 Max. difference allowed = 0.1454E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.90288E-10 -10.0444 0.75848E-10 -10.1201 0.84006E+00 -0.0757 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.16114E-03 -3.7928 0.13455E-03 -3.8711 0.83500E+00 -0.0783 4 SO4-- 0.33748E-09 -9.4718 0.17509E-09 -9.7567 0.51881E+00 -0.2850 5 HCO3- 0.37616E-04 -4.4246 0.31456E-04 -4.5023 0.83622E+00 -0.0777 6 HS- 0.62750E-04 -4.2024 0.52404E-04 -4.2806 0.83512E+00 -0.0783 7 Al+++ 0.99735E-29 -29.0012 0.22992E-29 -29.6384 0.23053E+00 -0.6373 8 H4SiO4 0.71047E-03 -3.1485 0.71047E-03 -3.1485 0.10000E+01 0.0000 9 Ca++ 0.11154E-06 -6.9526 0.57443E-07 -7.2408 0.51499E+00 -0.2882 10 Mg++ 0.21192E-10 -10.6738 0.10864E-10 -10.9640 0.51263E+00 -0.2902 11 Fe++ 0.46115E-13 -13.3362 0.23666E-13 -13.6259 0.51320E+00 -0.2897 12 K+ 0.15652E-03 -3.8054 0.13092E-03 -3.8830 0.83642E+00 -0.0776 13 Na+ 0.19865E-01 -1.7019 0.16584E-01 -1.7803 0.83485E+00 -0.0784 14 Mn++ 0.19351E-10 -10.7133 0.99391E-11 -11.0027 0.51362E+00 -0.2894 15 F- 0.67482E-06 -6.1708 0.56231E-06 -6.2500 0.83327E+00 -0.0792 16 HPO4-- 0.45335E-07 -7.3436 0.23524E-07 -7.6285 0.51889E+00 -0.2849 18 HSiO3- 0.10475E-01 -1.9799 0.87465E-02 -2.0582 0.83500E+00 -0.0783 19 Ca(HSiO3)+ 0.13677E-07 -7.8640 0.11442E-07 -7.9415 0.83660E+00 -0.0775 20 Mg(HSiO3)+ 0.32191E-11 -11.4923 0.26931E-11 -11.5698 0.83660E+00 -0.0775 21 NaHSiO3,aq 0.23460E-02 -2.6297 0.23460E-02 -2.6297 0.10000E+01 0.0000 22 AlO+ 0.64990E-16 -16.1872 0.54370E-16 -16.2646 0.83660E+00 -0.0775 24 HAlO2,aq 0.14276E-09 -9.8454 0.14276E-09 -9.8454 0.10000E+01 0.0000 25 AlO2- 0.49986E-05 -5.3011 0.41663E-05 -5.3803 0.83349E+00 -0.0791 26 CH4,aq 0.91771E-05 -5.0373 0.91452E-05 -5.0388 0.99652E+00 -0.0015 27 C2H6,aq 0.47507E-14 -14.3232 0.47342E-14 -14.3248 0.99652E+00 -0.0015 31 CO,aq 0.38677E-15 -15.4125 0.38677E-15 -15.4125 0.10000E+01 0.0000 32 CO2,aq 0.51158E-08 -8.2911 0.50980E-08 -8.2926 0.99652E+00 -0.0015 33 CO3-2 0.69970E-04 -4.1551 0.36224E-04 -4.4410 0.51771E+00 -0.2859 34 CaCO3,aq 0.26091E-07 -7.5835 0.26091E-07 -7.5835 0.10000E+01 0.0000 35 Ca(HCO3)+ 0.55131E-10 -10.2586 0.46123E-10 -10.3361 0.83660E+00 -0.0775 36 CaCl+ 0.14951E-10 -10.8253 0.12508E-10 -10.9028 0.83660E+00 -0.0775 37 CaCl2,aq 0.39982E-15 -15.3981 0.39982E-15 -15.3981 0.10000E+01 0.0000 38 CaF+ 0.56370E-12 -12.2490 0.47159E-12 -12.3264 0.83660E+00 -0.0775 39 CaOH+ 0.64517E-07 -7.1903 0.53975E-07 -7.2678 0.83660E+00 -0.0775 40 CaSO4,aq 0.31937E-14 -14.4957 0.31937E-14 -14.4957 0.10000E+01 0.0000 41 HCl,aq 0.18701E-14 -14.7281 0.18701E-14 -14.7281 0.10000E+01 0.0000 45 HF,aq 0.29197E-12 -12.5347 0.29197E-12 -12.5347 0.10000E+01 0.0000 46 HF2- 0.66383E-19 -19.1779 0.55430E-19 -19.2563 0.83500E+00 -0.0783 48 FeCl+ 0.60245E-17 -17.2201 0.50401E-17 -17.2976 0.83660E+00 -0.0775 51 FeF+ 0.81287E-18 -18.0900 0.68004E-18 -18.1675 0.83660E+00 -0.0775 53 FeO,aq 0.15989E-09 -9.7962 0.15989E-09 -9.7962 0.10000E+01 0.0000 54 FeOH+ 0.12140E-10 -10.9158 0.10157E-10 -10.9932 0.83660E+00 -0.0775 55 HFeO2- 0.26414E-07 -7.5782 0.22056E-07 -7.6565 0.83500E+00 -0.0783 56 FeO+ 0.16663E-16 -16.7783 0.13940E-16 -16.8557 0.83660E+00 -0.0775 58 FeO2- 0.59380E-09 -9.2264 0.49582E-09 -9.3047 0.83500E+00 -0.0783 59 HFeO2,aq 0.47831E-11 -11.3203 0.47831E-11 -11.3203 0.10000E+01 0.0000 60 H2,aq 0.30307E-05 -5.5185 0.30201E-05 -5.5200 0.99652E+00 -0.0015 61 KCl,aq 0.31925E-09 -9.4959 0.31925E-09 -9.4959 0.10000E+01 0.0000 63 KOH,aq 0.73712E-06 -6.1325 0.73712E-06 -6.1325 0.10000E+01 0.0000 64 KSO4- 0.42598E-12 -12.3706 0.35569E-12 -12.4489 0.83500E+00 -0.0783 65 MgCO3,aq 0.12369E-11 -11.9077 0.12369E-11 -11.9077 0.10000E+01 0.0000 66 Mg(HCO3)+ 0.10654E-13 -13.9725 0.89133E-14 -14.0500 0.83660E+00 -0.0775 67 MgCl+ 0.25627E-14 -14.5913 0.21440E-14 -14.6688 0.83660E+00 -0.0775 68 MgF+ 0.39491E-15 -15.4035 0.33038E-15 -15.4810 0.83660E+00 -0.0775 69 MgOH+ 0.67519E-10 -10.1706 0.56486E-10 -10.2481 0.83660E+00 -0.0775 71 MnF+ 0.11252E-15 -15.9488 0.94136E-16 -16.0262 0.83660E+00 -0.0775 72 MnO,aq 0.17892E-08 -8.7473 0.17892E-08 -8.7473 0.10000E+01 0.0000 73 MnOH+ 0.47364E-09 -9.3246 0.39625E-09 -9.4020 0.83660E+00 -0.0775 74 MnO2-2 0.19937E-10 -10.7003 0.10321E-10 -10.9863 0.51771E+00 -0.2859 75 HMnO2- 0.20540E-09 -9.6874 0.17151E-09 -9.7657 0.83500E+00 -0.0783 78 MnCl+ 0.98433E-14 -14.0069 0.82349E-14 -14.0843 0.83660E+00 -0.0775 79 MnSO4,aq 0.50239E-18 -18.2990 0.50239E-18 -18.2990 0.10000E+01 0.0000 80 NaCl,aq 0.73947E-06 -6.1311 0.73947E-06 -6.1311 0.10000E+01 0.0000 81 NaF,aq 0.21832E-08 -8.6609 0.21832E-08 -8.6609 0.10000E+01 0.0000 82 NaOH,aq 0.93941E-04 -4.0271 0.93941E-04 -4.0271 0.10000E+01 0.0000 84 OH- 0.91394E-02 -2.0391 0.76175E-02 -2.1182 0.83349E+00 -0.0791 89 HPO3-2 0.42765E-15 -15.3689 0.22140E-15 -15.6548 0.51771E+00 -0.2859 91 H2PO3- 0.40329E-19 -19.3944 0.33674E-19 -19.4727 0.83500E+00 -0.0783 92 H3PO4,aq 0.94649E-18 -18.0239 0.94649E-18 -18.0239 0.10000E+01 0.0000 93 H2PO4- 0.39381E-10 -10.4047 0.32914E-10 -10.4826 0.83579E+00 -0.0779 94 PO4-3 0.10450E-08 -8.9809 0.25304E-09 -9.5968 0.24216E+00 -0.6159 98 HP2O7-3 0.96909E-18 -18.0136 0.22363E-18 -18.6505 0.23076E+00 -0.6368 99 P2O7-4 0.91694E-17 -17.0377 0.70435E-18 -18.1522 0.76816E-01 -1.1145 100 H2S,aq 0.12327E-07 -7.9091 0.12284E-07 -7.9107 0.99652E+00 -0.0015 101 S2-2 0.38917E-13 -13.4099 0.20148E-13 -13.6958 0.51771E+00 -0.2859 107 SO3-2 0.13083E-15 -15.8833 0.68716E-16 -16.1629 0.52522E+00 -0.2797 108 HSO3- 0.39082E-18 -18.4080 0.32633E-18 -18.4863 0.83500E+00 -0.0783 109 HSO4- 0.15283E-16 -16.8158 0.12798E-16 -16.8929 0.83742E+00 -0.0771 111 S2O3-2 0.48802E-19 -19.3116 0.25265E-19 -19.5975 0.51771E+00 -0.2859 Charge balance for all species = -.6133E-08 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.9028820E-10 -.2214578E-01 -.2228273E+02 0.0000 2 H2O 0.1000000E+01 0.5550469E+02 0.9981915E+06 0.0000 3 Cl- 0.1611364E-03 0.1618762E-03 0.5728999E+01 6.2489 4 SO4-- 0.3374776E-09 -.9934380E-05 -.9526498E+00 10.4834 5 HCO3- 0.3761648E-04 0.1167952E-03 0.7114099E+01 5.6178 6 HS- 0.6274978E-04 0.7269682E-04 0.2400041E+01 5.8394 7 Al+++ 0.9973460E-29 0.4998768E-05 0.1346393E+00 0.7217 8 H4SiO4 0.7104743E-03 0.1353131E-01 0.1298302E+04 -3.1485 9 Ca++ 0.1115404E-06 0.2158966E-06 0.8637628E-02 12.9993 10 Mg++ 0.2119222E-10 0.9318058E-10 0.2261459E-05 9.2761 11 Fe++ 0.4611542E-13 0.2718511E-07 0.1515562E-02 6.6142 12 K+ 0.1565202E-03 0.1572577E-03 0.6138376E+01 6.2371 13 Na+ 0.1986463E-01 0.2230530E-01 0.5119010E+03 8.3397 14 Mn++ 0.1935092E-10 0.2507514E-08 0.1375178E-03 9.2375 15 F- 0.6748185E-06 0.6770025E-06 0.1283929E-01 3.8700 16 HPO4-- 0.4533508E-07 0.4641942E-07 0.4447528E-02 12.6116 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.1988979E-01 -.1988861E-01 -.1186738E-05 0.0000000E+00 2 H2O 0.4984745E+02 0.4984745E+02 -.1143260E-05 0.0000000E+00 3 Cl- 0.1453772E-03 0.1453772E-03 0.0000000E+00 0.0000000E+00 4 SO4-- -.8920810E-05 -.8921832E-05 0.1022245E-08 0.0000000E+00 5 HCO3- 0.1048910E-03 0.1048910E-03 0.0000000E+00 0.0000000E+00 6 HS- 0.6528628E-04 0.6528730E-04 -.1022245E-08 0.0000000E+00 7 Al+++ 0.4775352E-05 0.4489276E-05 0.2860759E-06 0.0000000E+00 8 H4SiO4 0.1215302E-01 0.1215215E-01 0.8685698E-06 0.0000000E+00 9 Ca++ 0.2080835E-06 0.1938916E-06 0.1419187E-07 0.0000000E+00 10 Mg++ 0.8368328E-10 0.8368328E-10 0.0000000E+00 0.0000000E+00 11 Fe++ 0.3259227E-07 0.2441431E-07 0.8177959E-08 0.0000000E+00 12 K+ 0.1412294E-03 0.1412294E-03 0.0000000E+00 0.0000000E+00 13 Na+ 0.2003215E-01 0.2003187E-01 0.2847926E-06 0.0000000E+00 14 Mn++ 0.2251939E-08 0.2251939E-08 0.0000000E+00 0.0000000E+00 15 F- 0.6080000E-06 0.6080000E-06 0.0000000E+00 0.0000000E+00 16 HPO4-- 0.4168819E-07 0.4168819E-07 0.0000000E+00 0.0000000E+00 Chg. balance for solid moles: -.1059E-21 Mass of aqueous solution: 0.899644E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 0.0012700 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 0.2848E-06 -6.545 0.7468E-04 -4.127 96.93 0.2867E-04 andradite 0.4089E-08 -8.388 0.2078E-05 -5.682 2.697 0.5399E-06 grossular 0.6416E-09 -9.193 0.2890E-06 -6.539 0.3751 0.8042E-07 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8644E+00 0.8644E+00 1.0000 -0.063 grossular 0.1356E+00 0.1356E+00 1.0000 -0.868 Solid products produced: Mass = 0.000077 g Volume = 0.000029 cm3 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.0012700 moles log = -2.8962 Original solution: 1000.0103000 g Original solution / Rock added: 787409.69 (Water/Rock Ratio), log = 5.8962 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0378 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9834E+00 0.9857 0.1006E+01 0.1021E+01 CO2,gas 0.5219E-06 1.0069 0.5454E-06 0.5417E-06 CH4,gas 0.1281E-01 1.0124 0.1346E-01 0.1330E-01 H2,gas 0.3819E-02 1.0006 0.3965E-02 0.3963E-02 H2S,gas 0.3267E-06 0.9960 0.3377E-06 0.3391E-06 S2,gas 0.2623E-27 1.0000 0.2723E-27 0.2723E-27 CO,gas 0.5554E-12 1.0000 0.5764E-12 0.5764E-12 SO3,gas 0.3670E-45 1.0000 0.3808E-45 0.3808E-45 SO2,gas 0.5661E-25 1.0000 0.5875E-25 0.5875E-25 HF,gas 0.6908E-15 1.0000 0.7169E-15 0.7169E-15 HCl,gas 0.3180E-17 1.0000 0.3300E-17 0.3300E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 17 albite -0.38 -0.38 0.00 0.000 -0.94784E-12 23 andradite 39.01 39.01 0.00 0.000 -0.12132E-10 24 grossular 32.73 32.73 0.00 0.000 0.00000E+00 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -14.62 -7.96 -2.654 0.13595E+05 -6.263 3 CH4,gas 4.54 0.97 -3.57 -0.892 0.60955E+04 -1.871 4 H2,gas 8.00 3.90 -4.10 -2.343 0.70019E+04 -2.402 5 H2S,gas -6.23 -14.40 -8.17 -4.085 0.13951E+05 -6.471 6 S2,gas -7.34 -36.60 -29.26 -4.502 0.49967E+05 -27.565 7 CO,gas 3.21 -10.72 -13.94 -4.289 0.23799E+05 -12.239 8 SO3,gas 17.12 -30.00 -47.12 -11.780 0.80453E+05 -45.419 9 SO2,gas 0.83 -26.10 -26.93 -7.181 0.45982E+05 -25.231 10 HF,gas 0.47 -16.37 -16.84 -8.422 0.28760E+05 -15.145 11 HCl,gas 5.19 -13.99 -19.18 -9.590 0.32750E+05 -17.482 12 acmite 7.71 6.71 -1.00 -0.104 0.17111E+04 16 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 20 spessartine 24.46 19.71 -4.75 -0.237 0.81051E+04 21 analcite 3.32 2.76 -0.56 -0.062 0.95153E+03 27 annite 20.12 17.36 -2.77 -0.154 0.47250E+04 28 phlogopite 27.06 25.34 -1.72 -0.096 0.29417E+04 30 anorthite 12.71 8.15 -4.56 -0.351 0.77936E+04 33 apatite-OH -18.15 -18.61 -0.46 -0.035 0.77790E+03 34 apatite-F -34.30 -34.98 -0.68 -0.057 0.11580E+04 38 aragonite 0.97 -1.62 -2.59 -0.863 0.44215E+04 39 brucite 12.57 9.28 -3.29 -0.658 0.56218E+04 40 calcite 0.81 -1.62 -2.43 -0.812 0.41573E+04 41 carnegieite-low 9.02 5.91 -3.11 -0.444 0.53107E+04 42 carnegieite-high 10.09 5.91 -4.18 -0.597 0.71377E+04 43 carpholite-Mg 8.58 4.42 -4.16 -0.277 0.71021E+04 44 carpholite-Fe 6.71 1.76 -4.95 -0.330 0.84551E+04 45 celadonite 5.34 3.64 -1.70 -0.100 0.29036E+04 46 celadonite-Fe 3.88 0.98 -2.90 -0.170 0.49470E+04 47 chrysotile 23.89 21.53 -2.36 -0.197 0.40313E+04 49 clinochlore 39.07 38.38 -0.69 -0.022 0.11797E+04 50 daphnite 28.97 25.07 -3.90 -0.122 0.66521E+04 52 chlorite-Al-free 47.17 43.06 -4.11 -0.171 0.70179E+04 54 chloritoid-Fe 9.17 4.91 -4.26 -0.284 0.72812E+04 55 chloritoid-Mn 11.40 7.53 -3.87 -0.258 0.66055E+04 57 coesite -2.38 -3.15 -0.77 -0.257 0.13188E+04 64 cristobalite -2.56 -3.15 -0.59 -0.196 0.10042E+04 66 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71235E+04 68 diaspore 2.87 0.72 -2.15 -0.359 0.36744E+04 69 diamond -3.10 -6.82 -3.72 -1.063 0.63550E+04 70 diopside 16.18 15.98 -0.20 -0.020 0.34630E+03 71 hedenbergite 14.21 13.32 -0.89 -0.089 0.15224E+04 76 clinoenstatite 17.17 12.26 -4.91 -0.491 0.83854E+04 78 epidote 24.67 22.66 -2.01 -0.097 0.34292E+04 79 clinozoisite 22.81 18.72 -4.09 -0.186 0.69792E+04 80 epidote-Fe 29.84 26.60 -3.24 -0.168 0.55258E+04 81 fayalite 14.05 10.08 -3.97 -0.567 0.67713E+04 82 ferrosilite 11.15 6.93 -4.22 -0.422 0.72019E+04 86 gibbsite 4.08 0.72 -3.36 -0.480 0.57329E+04 87 glaucophane 22.97 20.76 -2.21 -0.060 0.37755E+04 88 glaucophane-Fe 17.28 12.78 -4.50 -0.122 0.76797E+04 89 graphite -3.55 -6.82 -3.28 -0.937 0.55973E+04 90 greenalite 16.14 13.55 -2.59 -0.216 0.44286E+04 93 hematite 12.57 9.33 -3.24 -0.392 0.55266E+04 94 heulandite -5.83 -7.60 -1.77 -0.080 0.30206E+04 98 jadeite 4.22 2.76 -1.45 -0.145 0.24770E+04 100 kalsilite 7.58 3.81 -3.77 -0.539 0.64433E+04 101 kaolinite -1.33 -4.85 -3.52 -0.320 0.60114E+04 104 laumontite 2.88 1.85 -1.03 -0.069 0.17662E+04 105 lawsonite 9.62 8.15 -1.47 -0.098 0.25102E+04 106 leucite 4.12 0.66 -3.46 -0.346 0.59027E+04 108 lizardite 23.24 21.53 -1.71 -0.143 0.29240E+04 110 magnetite 20.09 15.94 -4.14 -0.338 0.70753E+04 111 minnesotaite 10.39 7.25 -3.14 -0.185 0.53601E+04 115 manganosite 14.06 9.24 -4.82 -1.205 0.82311E+04 119 microcline -2.49 -2.49 0.00 0.000 0.10816E+00 123 muscovite 2.58 -1.04 -3.63 -0.213 0.61904E+04 124 paragonite 4.24 1.06 -3.18 -0.187 0.54294E+04 125 nepheline 8.34 5.91 -2.43 -0.347 0.41430E+04 137 phlogopite-Na 29.65 27.44 -2.20 -0.122 0.37604E+04 139 prehnite 19.37 18.00 -1.38 -0.081 0.23479E+04 140 prehnite-Fe 22.50 21.94 -0.56 -0.034 0.95286E+03 141 pumpellyite-Fe 46.27 43.33 -2.94 -0.065 0.50196E+04 142 pumpellyite-Mg 48.99 45.99 -3.00 -0.067 0.51282E+04 145 pyrite -21.25 -26.09 -4.84 -1.139 0.82629E+04 146 pyrrhotite -4.26 -7.79 -3.53 -1.175 0.60208E+04 147 pyrrhotiteFe0.875 -6.02 -9.10 -3.08 -1.133 0.52586E+04 148 pyroxmangite 7.40 6.09 -1.31 -0.262 0.22362E+04 149 pyrophyllite -6.18 -11.15 -4.97 -0.311 0.84939E+04 150 quartz -2.99 -3.15 -0.16 -0.053 0.27152E+03 154 rhodochrosite -0.98 -5.38 -4.41 -1.470 0.75275E+04 155 rhodonite 7.45 6.09 -1.36 -0.271 0.23165E+04 156 sanidine -1.28 -2.49 -1.21 -0.093 0.20679E+04 166 stilbite -7.52 -7.60 -0.07 -0.004 0.12682E+03 167 stilpnomelane-Fe 13.02 12.45 -0.57 -0.017 0.97556E+03 168 stilpnomelane-Mg 27.44 25.75 -1.69 -0.050 0.28797E+04 174 talc 16.49 15.23 -1.26 -0.074 0.21456E+04 177 tephroite 18.09 15.33 -2.76 -0.394 0.47115E+04 181 tridymite -2.63 -3.15 -0.52 -0.174 0.89149E+03 182 tremolite 47.87 47.19 -0.68 -0.018 0.11571E+04 183 ferroactinolite 38.45 33.88 -4.57 -0.124 0.78033E+04 184 troilite-low -4.41 -7.79 -3.38 -1.125 0.57636E+04 190 wairakite 3.95 1.85 -2.10 -0.124 0.35881E+04 191 walstromite 11.51 9.85 -1.66 -0.332 0.28316E+04 192 wollastonite 10.46 9.85 -0.61 -0.122 0.10420E+04 193 pseudo-wollastonite 11.00 9.85 -1.15 -0.230 0.19618E+04 194 zoisite 22.85 18.72 -4.13 -0.188 0.70533E+04 195 akaganeite 7.75 4.66 -3.09 -0.668 0.52759E+04 202 chalcedony -2.80 -3.15 -0.35 -0.115 0.59081E+03 204 montmorillonite-Ca -2.29 -6.18 -3.89 -0.241 0.66451E+04 205 montmorillonite-K -2.24 -6.27 -4.03 -0.247 0.68853E+04 206 montmorillonite-Mg -2.48 -6.80 -4.32 -0.267 0.73711E+04 207 montmorillonite-Na -2.04 -5.58 -3.54 -0.217 0.60401E+04 208 nontronite-Ca 3.21 0.16 -3.06 -0.198 0.52195E+04 209 nontronite-H 2.53 -1.99 -4.52 -0.303 0.77176E+04 210 nontronite-K 3.34 0.07 -3.27 -0.210 0.55829E+04 211 nontronite-Mg 3.07 -0.46 -3.53 -0.229 0.60295E+04 212 nontronite-Na 3.52 0.76 -2.75 -0.177 0.47037E+04 228 tobermorite 9.82 7.68 -2.14 -0.585 0.36592E+04 234 alabandite -0.98 -5.16 -4.19 -1.395 0.71464E+04 237 boehmite 4.41 0.72 -3.68 -0.614 0.62913E+04 239 ferrous-oxide 9.81 6.61 -3.20 -0.799 0.54594E+04 245 silica-amorphous -2.09 -3.15 -1.06 -0.352 0.18050E+04 247 an20ab80 2.02 1.32 -0.70 -0.054 0.11879E+04 248 an25ab75 2.65 1.75 -0.90 -0.069 0.15318E+04 249 an30ab70 3.28 2.18 -1.10 -0.085 0.18853E+04 250 tr.625ac.25prg.125 45.16 44.80 -0.36 -0.010 0.61428E+03 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 0.0000400 MOLES Current total amount of reactant added: 0.0012700 MOLES New total amount of reactant added: 0.0013100 MOLES Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.5508E-08 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 7 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 0.0013100 Water: Moles liquid = 0.4985E+02 kg liquid = 0.8981E+00 Moles total = 0.4985E+02 kg total = 0.8980E+00 Activity = 1.0000 Stoichiometric ionic strength = .1141380E-01 Osmotic coef. = 0.9654 True ionic strength = .2009394E-01 Chg. balance for total moles = -.5508E-08 Max. difference allowed = 0.1456E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.90353E-10 -10.0441 0.75902E-10 -10.1197 0.84006E+00 -0.0757 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.16140E-03 -3.7921 0.13477E-03 -3.8704 0.83499E+00 -0.0783 4 SO4-- 0.36237E-09 -9.4408 0.18800E-09 -9.7259 0.51880E+00 -0.2850 5 HCO3- 0.38830E-04 -4.4108 0.32470E-04 -4.4885 0.83622E+00 -0.0777 6 HS- 0.63832E-04 -4.1950 0.53307E-04 -4.2732 0.83511E+00 -0.0783 7 Al+++ 0.99826E-29 -29.0008 0.23011E-29 -29.6381 0.23051E+00 -0.6373 8 H4SiO4 0.71095E-03 -3.1482 0.71095E-03 -3.1482 0.10000E+01 0.0000 9 Ca++ 0.11116E-06 -6.9541 0.57243E-07 -7.2423 0.51498E+00 -0.2882 10 Mg++ 0.21195E-10 -10.6738 0.10865E-10 -10.9640 0.51262E+00 -0.2902 11 Fe++ 0.46216E-13 -13.3352 0.23717E-13 -13.6249 0.51318E+00 -0.2897 12 K+ 0.15652E-03 -3.8054 0.13092E-03 -3.8830 0.83641E+00 -0.0776 13 Na+ 0.19865E-01 -1.7019 0.16584E-01 -1.7803 0.83484E+00 -0.0784 14 Mn++ 0.19378E-10 -10.7127 0.99524E-11 -11.0021 0.51361E+00 -0.2894 15 F- 0.69258E-06 -6.1595 0.57710E-06 -6.2387 0.83327E+00 -0.0792 16 HPO4-- 0.45336E-07 -7.3436 0.23523E-07 -7.6285 0.51887E+00 -0.2849 18 HSiO3- 0.10474E-01 -1.9799 0.87461E-02 -2.0582 0.83499E+00 -0.0783 19 Ca(HSiO3)+ 0.13629E-07 -7.8655 0.11402E-07 -7.9430 0.83659E+00 -0.0775 20 Mg(HSiO3)+ 0.32192E-11 -11.4923 0.26932E-11 -11.5697 0.83659E+00 -0.0775 21 NaHSiO3,aq 0.23459E-02 -2.6297 0.23459E-02 -2.6297 0.10000E+01 0.0000 22 AlO+ 0.64953E-16 -16.1874 0.54339E-16 -16.2649 0.83659E+00 -0.0775 24 HAlO2,aq 0.14257E-09 -9.8460 0.14257E-09 -9.8460 0.10000E+01 0.0000 25 AlO2- 0.49887E-05 -5.3020 0.41580E-05 -5.3811 0.83348E+00 -0.0791 26 CH4,aq 0.89748E-05 -5.0470 0.89435E-05 -5.0485 0.99652E+00 -0.0015 27 C2H6,aq 0.46061E-14 -14.3367 0.45901E-14 -14.3382 0.99652E+00 -0.0015 31 CO,aq 0.39410E-15 -15.4044 0.39410E-15 -15.4044 0.10000E+01 0.0000 32 CO2,aq 0.52846E-08 -8.2770 0.52662E-08 -8.2785 0.99652E+00 -0.0015 33 CO3-2 0.72178E-04 -4.1416 0.37366E-04 -4.4275 0.51769E+00 -0.2859 34 CaCO3,aq 0.26820E-07 -7.5715 0.26820E-07 -7.5715 0.10000E+01 0.0000 35 Ca(HCO3)+ 0.56712E-10 -10.2463 0.47445E-10 -10.3238 0.83659E+00 -0.0775 36 CaCl+ 0.14923E-10 -10.8262 0.12484E-10 -10.9036 0.83659E+00 -0.0775 37 CaCl2,aq 0.39971E-15 -15.3983 0.39971E-15 -15.3983 0.10000E+01 0.0000 38 CaF+ 0.57652E-12 -12.2392 0.48231E-12 -12.3167 0.83659E+00 -0.0775 39 CaOH+ 0.64247E-07 -7.1921 0.53749E-07 -7.2696 0.83659E+00 -0.0775 40 CaSO4,aq 0.34172E-14 -14.4663 0.34172E-14 -14.4663 0.10000E+01 0.0000 41 HCl,aq 0.18744E-14 -14.7271 0.18744E-14 -14.7271 0.10000E+01 0.0000 45 HF,aq 0.29986E-12 -12.5231 0.29986E-12 -12.5231 0.10000E+01 0.0000 46 HF2- 0.69972E-19 -19.1551 0.58426E-19 -19.2334 0.83499E+00 -0.0783 48 FeCl+ 0.60473E-17 -17.2184 0.50591E-17 -17.2959 0.83659E+00 -0.0775 51 FeF+ 0.83605E-18 -18.0778 0.69943E-18 -18.1553 0.83659E+00 -0.0775 53 FeO,aq 0.16000E-09 -9.7959 0.16000E-09 -9.7959 0.10000E+01 0.0000 54 FeOH+ 0.12158E-10 -10.9151 0.10171E-10 -10.9926 0.83659E+00 -0.0775 55 HFeO2- 0.26415E-07 -7.5782 0.22056E-07 -7.6565 0.83499E+00 -0.0783 56 FeO+ 0.16801E-16 -16.7747 0.14056E-16 -16.8521 0.83659E+00 -0.0775 58 FeO2- 0.59789E-09 -9.2234 0.49924E-09 -9.3017 0.83499E+00 -0.0783 59 HFeO2,aq 0.48194E-11 -11.3170 0.48194E-11 -11.3170 0.10000E+01 0.0000 60 H2,aq 0.29895E-05 -5.5244 0.29791E-05 -5.5259 0.99652E+00 -0.0015 61 KCl,aq 0.31977E-09 -9.4952 0.31977E-09 -9.4952 0.10000E+01 0.0000 63 KOH,aq 0.73659E-06 -6.1328 0.73659E-06 -6.1328 0.10000E+01 0.0000 64 KSO4- 0.45739E-12 -12.3397 0.38192E-12 -12.4180 0.83499E+00 -0.0783 65 MgCO3,aq 0.12760E-11 -11.8942 0.12760E-11 -11.8942 0.10000E+01 0.0000 66 Mg(HCO3)+ 0.10999E-13 -13.9587 0.92015E-14 -14.0361 0.83659E+00 -0.0775 67 MgCl+ 0.25671E-14 -14.5906 0.21476E-14 -14.6680 0.83659E+00 -0.0775 68 MgF+ 0.40534E-15 -15.3922 0.33910E-15 -15.4697 0.83659E+00 -0.0775 69 MgOH+ 0.67477E-10 -10.1708 0.56451E-10 -10.2483 0.83659E+00 -0.0775 71 MnF+ 0.11564E-15 -15.9369 0.96742E-16 -16.0144 0.83659E+00 -0.0775 72 MnO,aq 0.17890E-08 -8.7474 0.17890E-08 -8.7474 0.10000E+01 0.0000 73 MnOH+ 0.47394E-09 -9.3243 0.39650E-09 -9.4018 0.83659E+00 -0.0775 74 MnO2-2 0.19907E-10 -10.7010 0.10306E-10 -10.9869 0.51769E+00 -0.2859 75 HMnO2- 0.20524E-09 -9.6877 0.17138E-09 -9.7661 0.83499E+00 -0.0783 78 MnCl+ 0.98725E-14 -14.0056 0.82593E-14 -14.0831 0.83659E+00 -0.0775 79 MnSO4,aq 0.54015E-18 -18.2675 0.54015E-18 -18.2675 0.10000E+01 0.0000 80 NaCl,aq 0.74066E-06 -6.1304 0.74066E-06 -6.1304 0.10000E+01 0.0000 81 NaF,aq 0.22406E-08 -8.6496 0.22406E-08 -8.6496 0.10000E+01 0.0000 82 NaOH,aq 0.93874E-04 -4.0275 0.93874E-04 -4.0275 0.10000E+01 0.0000 84 OH- 0.91330E-02 -2.0394 0.76121E-02 -2.1185 0.83348E+00 -0.0791 89 HPO3-2 0.42184E-15 -15.3748 0.21839E-15 -15.6608 0.51769E+00 -0.2859 91 H2PO3- 0.39808E-19 -19.4000 0.33240E-19 -19.4783 0.83499E+00 -0.0783 92 H3PO4,aq 0.94782E-18 -18.0233 0.94782E-18 -18.0233 0.10000E+01 0.0000 93 H2PO4- 0.39409E-10 -10.4044 0.32937E-10 -10.4823 0.83578E+00 -0.0779 94 PO4-3 0.10443E-08 -8.9812 0.25286E-09 -9.5971 0.24214E+00 -0.6159 98 HP2O7-3 0.96981E-18 -18.0133 0.22378E-18 -18.6502 0.23074E+00 -0.6369 99 P2O7-4 0.91702E-17 -17.0376 0.70433E-18 -18.1522 0.76806E-01 -1.1146 100 H2S,aq 0.12549E-07 -7.9014 0.12505E-07 -7.9029 0.99652E+00 -0.0015 101 S2-2 0.40827E-13 -13.3891 0.21136E-13 -13.6750 0.51769E+00 -0.2859 107 SO3-2 0.13857E-15 -15.8583 0.72778E-16 -16.1380 0.52520E+00 -0.2797 108 HSO3- 0.41422E-18 -18.3828 0.34587E-18 -18.4611 0.83499E+00 -0.0783 109 HSO4- 0.16421E-16 -16.7846 0.13752E-16 -16.8616 0.83741E+00 -0.0771 111 S2O3-2 0.53343E-19 -19.2729 0.27615E-19 -19.5588 0.51769E+00 -0.2859 Charge balance for all species = -.6133E-08 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.9035313E-10 -.2214093E-01 -.2227785E+02 0.0000 2 H2O 0.1000000E+01 0.5550468E+02 0.9981912E+06 0.0000 3 Cl- 0.1613979E-03 0.1621389E-03 0.5738294E+01 6.2493 4 SO4-- 0.3623694E-09 -.9721695E-05 -.9322544E+00 10.5136 5 HCO3- 0.3883018E-04 0.1200153E-03 0.7310239E+01 5.6312 6 HS- 0.6383180E-04 0.7356640E-04 0.2428749E+01 5.8465 7 Al+++ 0.9982649E-29 0.4988841E-05 0.1343719E+00 0.7212 8 H4SiO4 0.7109473E-03 0.1353127E-01 0.1298297E+04 -3.1482 9 Ca++ 0.1111553E-06 0.2159236E-06 0.8638708E-02 12.9972 10 Mg++ 0.2119461E-10 0.9318051E-10 0.2261457E-05 9.2755 11 Fe++ 0.4621596E-13 0.2718987E-07 0.1515827E-02 6.6146 12 K+ 0.1565206E-03 0.1572575E-03 0.6138371E+01 6.2367 13 Na+ 0.1986478E-01 0.2230527E-01 0.5119003E+03 8.3394 14 Mn++ 0.1937756E-10 0.2507512E-08 0.1375177E-03 9.2374 15 F- 0.6925763E-06 0.6948178E-06 0.1317715E-01 3.8810 16 HPO4-- 0.4533571E-07 0.4641939E-07 0.4447524E-02 12.6110 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.1988549E-01 -.1988426E-01 -.1222342E-05 0.0000000E+00 2 H2O 0.4984748E+02 0.4984748E+02 -.1178954E-05 0.0000000E+00 3 Cl- 0.1456132E-03 0.1456132E-03 0.0000000E+00 0.0000000E+00 4 SO4-- -.8729810E-05 -.8730832E-05 0.1021708E-08 0.0000000E+00 5 HCO3- 0.1077830E-03 0.1077830E-03 0.0000000E+00 0.0000000E+00 6 HS- 0.6606728E-04 0.6606830E-04 -.1021708E-08 0.0000000E+00 7 Al+++ 0.4775352E-05 0.4480364E-05 0.2949881E-06 0.0000000E+00 8 H4SiO4 0.1215302E-01 0.1215212E-01 0.8953180E-06 0.0000000E+00 9 Ca++ 0.2080835E-06 0.1939160E-06 0.1416747E-07 0.0000000E+00 10 Mg++ 0.8368328E-10 0.8368328E-10 0.0000000E+00 0.0000000E+00 11 Fe++ 0.3259227E-07 0.2441860E-07 0.8173667E-08 0.0000000E+00 12 K+ 0.1412294E-03 0.1412294E-03 0.0000000E+00 0.0000000E+00 13 Na+ 0.2003215E-01 0.2003186E-01 0.2937168E-06 0.0000000E+00 14 Mn++ 0.2251939E-08 0.2251939E-08 0.0000000E+00 0.0000000E+00 15 F- 0.6240000E-06 0.6240000E-06 0.0000000E+00 0.0000000E+00 16 HPO4-- 0.4168819E-07 0.4168819E-07 0.0000000E+00 0.0000000E+00 Chg. balance for solid moles: -.2647E-21 Mass of aqueous solution: 0.899645E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 0.0013100 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 0.2937E-06 -6.532 0.7702E-04 -4.113 97.02 0.2957E-04 andradite 0.4087E-08 -8.389 0.2077E-05 -5.683 2.616 0.5396E-06 grossular 0.6357E-09 -9.197 0.2863E-06 -6.543 0.3607 0.7967E-07 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8654E+00 0.8654E+00 1.0000 -0.063 grossular 0.1346E+00 0.1346E+00 1.0000 -0.871 Solid products produced: Mass = 0.000079 g Volume = 0.000030 cm3 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.0013100 moles log = -2.8827 Original solution: 1000.0103000 g Original solution / Rock added: 763366.64 (Water/Rock Ratio), log = 5.8827 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0374 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9837E+00 0.9857 0.1006E+01 0.1021E+01 CO2,gas 0.5393E-06 1.0069 0.5634E-06 0.5595E-06 CH4,gas 0.1253E-01 1.0124 0.1316E-01 0.1300E-01 H2,gas 0.3768E-02 1.0006 0.3911E-02 0.3909E-02 H2S,gas 0.3327E-06 0.9960 0.3438E-06 0.3451E-06 S2,gas 0.2795E-27 1.0000 0.2900E-27 0.2900E-27 CO,gas 0.5661E-12 1.0000 0.5873E-12 0.5873E-12 SO3,gas 0.3947E-45 1.0000 0.4095E-45 0.4095E-45 SO2,gas 0.6006E-25 1.0000 0.6231E-25 0.6231E-25 HF,gas 0.7097E-15 1.0000 0.7363E-15 0.7363E-15 HCl,gas 0.3188E-17 1.0000 0.3307E-17 0.3307E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 17 albite -0.38 -0.38 0.00 0.000 0.11184E-10 23 andradite 39.01 39.01 0.00 0.000 0.00000E+00 24 grossular 32.73 32.73 0.00 0.000 -0.36397E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -14.61 -7.95 -2.649 0.13571E+05 -6.249 3 CH4,gas 4.54 0.96 -3.58 -0.895 0.61120E+04 -1.881 4 H2,gas 8.00 3.89 -4.11 -2.347 0.70120E+04 -2.408 5 H2S,gas -6.23 -14.39 -8.16 -4.081 0.13938E+05 -6.464 6 S2,gas -7.34 -36.57 -29.24 -4.498 0.49921E+05 -27.538 7 CO,gas 3.21 -10.72 -13.93 -4.286 0.23785E+05 -12.231 8 SO3,gas 17.12 -29.97 -47.09 -11.772 0.80399E+05 -45.388 9 SO2,gas 0.83 -26.07 -26.90 -7.175 0.45939E+05 -25.205 10 HF,gas 0.47 -16.36 -16.83 -8.416 0.28740E+05 -15.133 11 HCl,gas 5.19 -13.99 -19.18 -9.590 0.32748E+05 -17.481 12 acmite 7.71 6.71 -1.00 -0.104 0.17051E+04 16 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 20 spessartine 24.46 19.71 -4.75 -0.237 0.81057E+04 21 analcite 3.32 2.76 -0.56 -0.062 0.95203E+03 27 annite 20.12 17.36 -2.77 -0.154 0.47234E+04 28 phlogopite 27.06 25.34 -1.72 -0.096 0.29447E+04 30 anorthite 12.71 8.14 -4.57 -0.351 0.77981E+04 33 apatite-OH -18.15 -18.62 -0.46 -0.036 0.79298E+03 34 apatite-F -34.30 -34.98 -0.68 -0.056 0.11533E+04 38 aragonite 0.97 -1.61 -2.58 -0.859 0.44011E+04 39 brucite 12.57 9.28 -3.29 -0.659 0.56228E+04 40 calcite 0.81 -1.61 -2.42 -0.808 0.41369E+04 41 carnegieite-low 9.02 5.91 -3.11 -0.444 0.53117E+04 42 carnegieite-high 10.09 5.91 -4.18 -0.597 0.71387E+04 43 carpholite-Mg 8.58 4.42 -4.16 -0.277 0.71040E+04 44 carpholite-Fe 6.71 1.76 -4.95 -0.330 0.84555E+04 45 celadonite 5.34 3.64 -1.70 -0.100 0.29041E+04 46 celadonite-Fe 3.88 0.98 -2.90 -0.170 0.49460E+04 47 chrysotile 23.89 21.53 -2.36 -0.197 0.40333E+04 49 clinochlore 39.07 38.38 -0.69 -0.022 0.11851E+04 50 daphnite 28.97 25.07 -3.89 -0.122 0.66499E+04 52 chlorite-Al-free 47.17 43.06 -4.11 -0.171 0.70219E+04 54 chloritoid-Fe 9.17 4.91 -4.26 -0.284 0.72821E+04 55 chloritoid-Mn 11.40 7.53 -3.87 -0.258 0.66070E+04 57 coesite -2.38 -3.15 -0.77 -0.257 0.13183E+04 64 cristobalite -2.56 -3.15 -0.59 -0.196 0.10037E+04 66 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71235E+04 68 diaspore 2.87 0.72 -2.15 -0.359 0.36754E+04 69 diamond -3.10 -6.82 -3.72 -1.063 0.63513E+04 70 diopside 16.18 15.98 -0.20 -0.020 0.34995E+03 71 hedenbergite 14.21 13.32 -0.89 -0.089 0.15245E+04 76 clinoenstatite 17.17 12.25 -4.91 -0.491 0.83864E+04 78 epidote 24.67 22.66 -2.01 -0.097 0.34313E+04 79 clinozoisite 22.81 18.71 -4.09 -0.186 0.69879E+04 80 epidote-Fe 29.84 26.61 -3.23 -0.168 0.55214E+04 81 fayalite 14.05 10.08 -3.96 -0.566 0.67697E+04 82 ferrosilite 11.15 6.93 -4.22 -0.422 0.71998E+04 86 gibbsite 4.08 0.72 -3.36 -0.480 0.57339E+04 87 glaucophane 22.97 20.76 -2.21 -0.060 0.37775E+04 88 glaucophane-Fe 17.28 12.78 -4.50 -0.122 0.76772E+04 89 graphite -3.55 -6.82 -3.28 -0.936 0.55935E+04 90 greenalite 16.14 13.55 -2.59 -0.216 0.44260E+04 93 hematite 12.57 9.34 -3.23 -0.392 0.55154E+04 94 heulandite -5.83 -7.60 -1.77 -0.080 0.30227E+04 98 jadeite 4.22 2.76 -1.45 -0.145 0.24775E+04 100 kalsilite 7.58 3.81 -3.77 -0.539 0.64442E+04 101 kaolinite -1.33 -4.85 -3.52 -0.320 0.60123E+04 104 laumontite 2.88 1.85 -1.04 -0.069 0.17698E+04 105 lawsonite 9.62 8.14 -1.47 -0.098 0.25148E+04 106 leucite 4.12 0.66 -3.46 -0.346 0.59032E+04 108 lizardite 23.24 21.53 -1.71 -0.143 0.29260E+04 110 magnetite 20.09 15.95 -4.14 -0.338 0.70635E+04 111 minnesotaite 10.39 7.25 -3.14 -0.185 0.53565E+04 115 manganosite 14.06 9.24 -4.82 -1.205 0.82312E+04 119 microcline -2.49 -2.49 0.00 0.000 0.11163E+00 123 muscovite 2.58 -1.04 -3.63 -0.213 0.61924E+04 124 paragonite 4.24 1.06 -3.18 -0.187 0.54313E+04 125 nepheline 8.34 5.91 -2.43 -0.347 0.41440E+04 137 phlogopite-Na 29.65 27.44 -2.20 -0.122 0.37634E+04 139 prehnite 19.37 17.99 -1.38 -0.081 0.23556E+04 140 prehnite-Fe 22.50 21.94 -0.56 -0.034 0.95400E+03 141 pumpellyite-Fe 46.27 43.32 -2.95 -0.066 0.50354E+04 142 pumpellyite-Mg 48.99 45.98 -3.01 -0.067 0.51455E+04 145 pyrite -21.25 -26.06 -4.82 -1.134 0.82258E+04 146 pyrrhotite -4.26 -7.78 -3.52 -1.173 0.60070E+04 147 pyrrhotiteFe0.875 -6.02 -9.09 -3.07 -1.129 0.52437E+04 148 pyroxmangite 7.40 6.09 -1.31 -0.262 0.22358E+04 149 pyrophyllite -6.18 -11.15 -4.97 -0.311 0.84938E+04 150 quartz -2.99 -3.15 -0.16 -0.053 0.27102E+03 154 rhodochrosite -0.98 -5.37 -4.39 -1.465 0.75035E+04 155 rhodonite 7.45 6.09 -1.36 -0.271 0.23160E+04 156 sanidine -1.28 -2.49 -1.21 -0.093 0.20679E+04 166 stilbite -7.52 -7.60 -0.08 -0.004 0.12891E+03 167 stilpnomelane-Fe 13.02 12.45 -0.57 -0.017 0.97111E+03 168 stilpnomelane-Mg 27.44 25.75 -1.69 -0.050 0.28829E+04 174 talc 16.49 15.23 -1.26 -0.074 0.21466E+04 177 tephroite 18.09 15.33 -2.76 -0.394 0.47111E+04 181 tridymite -2.63 -3.15 -0.52 -0.174 0.89100E+03 182 tremolite 47.87 47.19 -0.68 -0.018 0.11654E+04 183 ferroactinolite 38.45 33.88 -4.57 -0.124 0.78039E+04 184 troilite-low -4.41 -7.78 -3.37 -1.122 0.57498E+04 190 wairakite 3.95 1.85 -2.10 -0.124 0.35917E+04 191 walstromite 11.51 9.85 -1.66 -0.332 0.28347E+04 192 wollastonite 10.46 9.85 -0.61 -0.122 0.10451E+04 193 pseudo-wollastonite 11.00 9.85 -1.15 -0.230 0.19650E+04 194 zoisite 22.85 18.71 -4.14 -0.188 0.70619E+04 195 akaganeite 7.75 4.67 -3.09 -0.667 0.52702E+04 202 chalcedony -2.80 -3.15 -0.35 -0.115 0.59032E+03 204 montmorillonite-Ca -2.29 -6.18 -3.89 -0.241 0.66456E+04 205 montmorillonite-K -2.24 -6.27 -4.03 -0.247 0.68854E+04 206 montmorillonite-Mg -2.48 -6.80 -4.32 -0.267 0.73712E+04 207 montmorillonite-Na -2.04 -5.58 -3.54 -0.217 0.60403E+04 208 nontronite-Ca 3.21 0.16 -3.05 -0.198 0.52074E+04 209 nontronite-H 2.53 -1.98 -4.51 -0.302 0.77049E+04 210 nontronite-K 3.34 0.08 -3.26 -0.209 0.55703E+04 211 nontronite-Mg 3.07 -0.45 -3.52 -0.229 0.60170E+04 212 nontronite-Na 3.52 0.77 -2.75 -0.176 0.46912E+04 228 tobermorite 9.82 7.68 -2.14 -0.585 0.36617E+04 234 alabandite -0.98 -5.16 -4.18 -1.393 0.71333E+04 237 boehmite 4.41 0.72 -3.69 -0.614 0.62923E+04 239 ferrous-oxide 9.81 6.61 -3.20 -0.799 0.54588E+04 245 silica-amorphous -2.09 -3.15 -1.06 -0.352 0.18045E+04 247 an20ab80 2.02 1.32 -0.70 -0.054 0.11888E+04 248 an25ab75 2.65 1.75 -0.90 -0.069 0.15329E+04 249 an30ab70 3.28 2.17 -1.10 -0.085 0.18867E+04 250 tr.625ac.25prg.125 45.16 44.80 -0.36 -0.010 0.62110E+03 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 0.0000400 MOLES Current total amount of reactant added: 0.0013100 MOLES New total amount of reactant added: 0.0013500 MOLES Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.5508E-08 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 7 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 0.0013500 Water: Moles liquid = 0.4985E+02 kg liquid = 0.8981E+00 Moles total = 0.4985E+02 kg total = 0.8980E+00 Activity = 1.0000 Stoichiometric ionic strength = .1141635E-01 Osmotic coef. = 0.9653 True ionic strength = .2009629E-01 Chg. balance for total moles = -.5508E-08 Max. difference allowed = 0.1458E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.90418E-10 -10.0437 0.75956E-10 -10.1194 0.84005E+00 -0.0757 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.16166E-03 -3.7914 0.13498E-03 -3.8697 0.83498E+00 -0.0783 4 SO4-- 0.38882E-09 -9.4102 0.20171E-09 -9.6953 0.51878E+00 -0.2850 5 HCO3- 0.40045E-04 -4.3975 0.33486E-04 -4.4751 0.83621E+00 -0.0777 6 HS- 0.64914E-04 -4.1877 0.54210E-04 -4.2659 0.83511E+00 -0.0783 7 Al+++ 0.99919E-29 -29.0004 0.23031E-29 -29.6377 0.23050E+00 -0.6373 8 H4SiO4 0.71142E-03 -3.1479 0.71142E-03 -3.1479 0.10000E+01 0.0000 9 Ca++ 0.11077E-06 -6.9556 0.57044E-07 -7.2438 0.51496E+00 -0.2882 10 Mg++ 0.21197E-10 -10.6737 0.10866E-10 -10.9639 0.51260E+00 -0.2902 11 Fe++ 0.46317E-13 -13.3343 0.23768E-13 -13.6240 0.51316E+00 -0.2897 12 K+ 0.15652E-03 -3.8054 0.13092E-03 -3.8830 0.83641E+00 -0.0776 13 Na+ 0.19865E-01 -1.7019 0.16584E-01 -1.7803 0.83483E+00 -0.0784 14 Mn++ 0.19404E-10 -10.7121 0.99658E-11 -11.0015 0.51359E+00 -0.2894 15 F- 0.71033E-06 -6.1485 0.59189E-06 -6.2278 0.83326E+00 -0.0792 16 HPO4-- 0.45336E-07 -7.3436 0.23523E-07 -7.6285 0.51886E+00 -0.2850 18 HSiO3- 0.10474E-01 -1.9799 0.87456E-02 -2.0582 0.83498E+00 -0.0783 19 Ca(HSiO3)+ 0.13581E-07 -7.8671 0.11362E-07 -7.9446 0.83659E+00 -0.0775 20 Mg(HSiO3)+ 0.32193E-11 -11.4922 0.26933E-11 -11.5697 0.83659E+00 -0.0775 21 NaHSiO3,aq 0.23458E-02 -2.6297 0.23458E-02 -2.6297 0.10000E+01 0.0000 22 AlO+ 0.64916E-16 -16.1876 0.54308E-16 -16.2651 0.83659E+00 -0.0775 24 HAlO2,aq 0.14239E-09 -9.8465 0.14239E-09 -9.8465 0.10000E+01 0.0000 25 AlO2- 0.49788E-05 -5.3029 0.41497E-05 -5.3820 0.83347E+00 -0.0791 26 CH4,aq 0.87722E-05 -5.0569 0.87417E-05 -5.0584 0.99652E+00 -0.0015 27 C2H6,aq 0.44607E-14 -14.3506 0.44452E-14 -14.3521 0.99652E+00 -0.0015 31 CO,aq 0.40123E-15 -15.3966 0.40123E-15 -15.3966 0.10000E+01 0.0000 32 CO2,aq 0.54538E-08 -8.2633 0.54348E-08 -8.2648 0.99652E+00 -0.0015 33 CO3-2 0.74385E-04 -4.1285 0.38508E-04 -4.4145 0.51768E+00 -0.2859 34 CaCO3,aq 0.27543E-07 -7.5600 0.27543E-07 -7.5600 0.10000E+01 0.0000 35 Ca(HCO3)+ 0.58284E-10 -10.2345 0.48759E-10 -10.3119 0.83659E+00 -0.0775 36 CaCl+ 0.14895E-10 -10.8270 0.12461E-10 -10.9044 0.83659E+00 -0.0775 37 CaCl2,aq 0.39961E-15 -15.3984 0.39961E-15 -15.3984 0.10000E+01 0.0000 38 CaF+ 0.58925E-12 -12.2297 0.49296E-12 -12.3072 0.83659E+00 -0.0775 39 CaOH+ 0.63980E-07 -7.1940 0.53525E-07 -7.2714 0.83659E+00 -0.0775 40 CaSO4,aq 0.36539E-14 -14.4372 0.36539E-14 -14.4372 0.10000E+01 0.0000 41 HCl,aq 0.18788E-14 -14.7261 0.18788E-14 -14.7261 0.10000E+01 0.0000 45 HF,aq 0.30777E-12 -12.5118 0.30777E-12 -12.5118 0.10000E+01 0.0000 46 HF2- 0.73658E-19 -19.1328 0.61503E-19 -19.2111 0.83498E+00 -0.0783 48 FeCl+ 0.60702E-17 -17.2168 0.50782E-17 -17.2943 0.83659E+00 -0.0775 51 FeF+ 0.85934E-18 -18.0658 0.71891E-18 -18.1433 0.83659E+00 -0.0775 53 FeO,aq 0.16012E-09 -9.7956 0.16012E-09 -9.7956 0.10000E+01 0.0000 54 FeOH+ 0.12176E-10 -10.9145 0.10186E-10 -10.9920 0.83659E+00 -0.0775 55 HFeO2- 0.26416E-07 -7.5781 0.22057E-07 -7.6565 0.83498E+00 -0.0783 56 FeO+ 0.16941E-16 -16.7711 0.14172E-16 -16.8486 0.83659E+00 -0.0775 58 FeO2- 0.60199E-09 -9.2204 0.50265E-09 -9.2987 0.83498E+00 -0.0783 59 HFeO2,aq 0.48558E-11 -11.3137 0.48558E-11 -11.3137 0.10000E+01 0.0000 60 H2,aq 0.29491E-05 -5.5303 0.29389E-05 -5.5318 0.99652E+00 -0.0015 61 KCl,aq 0.32028E-09 -9.4945 0.32028E-09 -9.4945 0.10000E+01 0.0000 63 KOH,aq 0.73606E-06 -6.1331 0.73606E-06 -6.1331 0.10000E+01 0.0000 64 KSO4- 0.49077E-12 -12.3091 0.40978E-12 -12.3874 0.83498E+00 -0.0783 65 MgCO3,aq 0.13150E-11 -11.8811 0.13150E-11 -11.8811 0.10000E+01 0.0000 66 Mg(HCO3)+ 0.11344E-13 -13.9452 0.94901E-14 -14.0227 0.83659E+00 -0.0775 67 MgCl+ 0.25714E-14 -14.5898 0.21512E-14 -14.6673 0.83659E+00 -0.0775 68 MgF+ 0.41576E-15 -15.3812 0.34782E-15 -15.4586 0.83659E+00 -0.0775 69 MgOH+ 0.67435E-10 -10.1711 0.56415E-10 -10.2486 0.83659E+00 -0.0775 71 MnF+ 0.11876E-15 -15.9253 0.99355E-16 -16.0028 0.83659E+00 -0.0775 72 MnO,aq 0.17889E-08 -8.7474 0.17889E-08 -8.7474 0.10000E+01 0.0000 73 MnOH+ 0.47425E-09 -9.3240 0.39675E-09 -9.4015 0.83659E+00 -0.0775 74 MnO2-2 0.19878E-10 -10.7016 0.10290E-10 -10.9876 0.51768E+00 -0.2859 75 HMnO2- 0.20508E-09 -9.6881 0.17124E-09 -9.7664 0.83498E+00 -0.0783 78 MnCl+ 0.99018E-14 -14.0043 0.82837E-14 -14.0818 0.83659E+00 -0.0775 79 MnSO4,aq 0.58034E-18 -18.2363 0.58034E-18 -18.2363 0.10000E+01 0.0000 80 NaCl,aq 0.74186E-06 -6.1297 0.74186E-06 -6.1297 0.10000E+01 0.0000 81 NaF,aq 0.22981E-08 -8.6386 0.22981E-08 -8.6386 0.10000E+01 0.0000 82 NaOH,aq 0.93808E-04 -4.0278 0.93808E-04 -4.0278 0.10000E+01 0.0000 84 OH- 0.91265E-02 -2.0397 0.76067E-02 -2.1188 0.83347E+00 -0.0791 89 HPO3-2 0.41616E-15 -15.3807 0.21543E-15 -15.6667 0.51768E+00 -0.2859 91 H2PO3- 0.39299E-19 -19.4056 0.32814E-19 -19.4839 0.83498E+00 -0.0783 92 H3PO4,aq 0.94916E-18 -18.0227 0.94916E-18 -18.0227 0.10000E+01 0.0000 93 H2PO4- 0.39436E-10 -10.4041 0.32960E-10 -10.4820 0.83578E+00 -0.0779 94 PO4-3 0.10436E-08 -8.9815 0.25268E-09 -9.5974 0.24212E+00 -0.6160 98 HP2O7-3 0.97054E-18 -18.0130 0.22393E-18 -18.6499 0.23073E+00 -0.6369 99 P2O7-4 0.91710E-17 -17.0376 0.70430E-18 -18.1522 0.76797E-01 -1.1147 100 H2S,aq 0.12770E-07 -7.8938 0.12726E-07 -7.8953 0.99652E+00 -0.0015 101 S2-2 0.42801E-13 -13.3685 0.22157E-13 -13.6545 0.51768E+00 -0.2859 107 SO3-2 0.14668E-15 -15.8336 0.77035E-16 -16.1133 0.52519E+00 -0.2797 108 HSO3- 0.43877E-18 -18.3578 0.36636E-18 -18.4361 0.83498E+00 -0.0783 109 HSO4- 0.17632E-16 -16.7537 0.14766E-16 -16.8308 0.83741E+00 -0.0771 111 S2O3-2 0.58249E-19 -19.2347 0.30154E-19 -19.5207 0.51768E+00 -0.2859 Charge balance for all species = -.6133E-08 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.9041814E-10 -.2213608E-01 -.2227296E+02 0.0000 2 H2O 0.1000000E+01 0.5550467E+02 0.9981910E+06 0.0000 3 Cl- 0.1616593E-03 0.1624015E-03 0.5747589E+01 6.2497 4 SO4-- 0.3888238E-09 -.9509010E-05 -.9118591E+00 10.5436 5 HCO3- 0.4004504E-04 0.1232354E-03 0.7506378E+01 5.6443 6 HS- 0.6491381E-04 0.7443598E-04 0.2457457E+01 5.8535 7 Al+++ 0.9991852E-29 0.4978928E-05 0.1341049E+00 0.7206 8 H4SiO4 0.7114207E-03 0.1353123E-01 0.1298293E+04 -3.1479 9 Ca++ 0.1107734E-06 0.2159509E-06 0.8639801E-02 12.9951 10 Mg++ 0.2119700E-10 0.9318043E-10 0.2261455E-05 9.2749 11 Fe++ 0.4631738E-13 0.2719499E-07 0.1516112E-02 6.6149 12 K+ 0.1565210E-03 0.1572574E-03 0.6138365E+01 6.2364 13 Na+ 0.1986493E-01 0.2230525E-01 0.5118996E+03 8.3391 14 Mn++ 0.1940424E-10 0.2507510E-08 0.1375175E-03 9.2374 15 F- 0.7103342E-06 0.7126331E-06 0.1351501E-01 3.8917 16 HPO4-- 0.4533633E-07 0.4641935E-07 0.4447520E-02 12.6104 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.1988118E-01 -.1987992E-01 -.1257891E-05 0.0000000E+00 2 H2O 0.4984751E+02 0.4984752E+02 -.1214595E-05 0.0000000E+00 3 Cl- 0.1458492E-03 0.1458492E-03 0.0000000E+00 0.0000000E+00 4 SO4-- -.8538810E-05 -.8539831E-05 0.1021132E-08 0.0000000E+00 5 HCO3- 0.1106750E-03 0.1106750E-03 0.0000000E+00 0.0000000E+00 6 HS- 0.6684828E-04 0.6684930E-04 -.1021132E-08 0.0000000E+00 7 Al+++ 0.4775352E-05 0.4471465E-05 0.3038870E-06 0.0000000E+00 8 H4SiO4 0.1215302E-01 0.1215210E-01 0.9220254E-06 0.0000000E+00 9 Ca++ 0.2080835E-06 0.1939408E-06 0.1414275E-07 0.0000000E+00 10 Mg++ 0.8368328E-10 0.8368328E-10 0.0000000E+00 0.0000000E+00 11 Fe++ 0.3259227E-07 0.2442322E-07 0.8169052E-08 0.0000000E+00 12 K+ 0.1412294E-03 0.1412294E-03 0.0000000E+00 0.0000000E+00 13 Na+ 0.2003215E-01 0.2003185E-01 0.3026276E-06 0.0000000E+00 14 Mn++ 0.2251939E-08 0.2251939E-08 0.0000000E+00 0.0000000E+00 15 F- 0.6400000E-06 0.6400000E-06 0.0000000E+00 0.0000000E+00 16 HPO4-- 0.4168819E-07 0.4168819E-07 0.0000000E+00 0.0000000E+00 Chg. balance for solid moles: 0.1588E-21 Mass of aqueous solution: 0.899645E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 0.0013500 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 0.3026E-06 -6.519 0.7935E-04 -4.100 97.11 0.3046E-04 andradite 0.4085E-08 -8.389 0.2076E-05 -5.683 2.540 0.5393E-06 grossular 0.6297E-09 -9.201 0.2837E-06 -6.547 0.3471 0.7893E-07 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8664E+00 0.8664E+00 1.0000 -0.062 grossular 0.1336E+00 0.1336E+00 1.0000 -0.874 Solid products produced: Mass = 0.000082 g Volume = 0.000031 cm3 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.0013500 moles log = -2.8697 Original solution: 1000.0103000 g Original solution / Rock added: 740748.37 (Water/Rock Ratio), log = 5.8697 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0371 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9840E+00 0.9857 0.1006E+01 0.1021E+01 CO2,gas 0.5568E-06 1.0069 0.5815E-06 0.5775E-06 CH4,gas 0.1225E-01 1.0124 0.1287E-01 0.1271E-01 H2,gas 0.3718E-02 1.0006 0.3858E-02 0.3856E-02 H2S,gas 0.3387E-06 0.9960 0.3498E-06 0.3512E-06 S2,gas 0.2975E-27 1.0000 0.3086E-27 0.3086E-27 CO,gas 0.5765E-12 1.0000 0.5979E-12 0.5979E-12 SO3,gas 0.4243E-45 1.0000 0.4400E-45 0.4400E-45 SO2,gas 0.6369E-25 1.0000 0.6605E-25 0.6605E-25 HF,gas 0.7286E-15 1.0000 0.7557E-15 0.7557E-15 HCl,gas 0.3197E-17 1.0000 0.3315E-17 0.3315E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 17 albite -0.38 -0.38 0.00 0.000 0.11184E-10 23 andradite 39.01 39.01 0.00 0.000 -0.12132E-10 24 grossular 32.73 32.73 0.00 0.000 -0.24265E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -14.59 -7.93 -2.645 0.13548E+05 -6.235 3 CH4,gas 4.54 0.95 -3.59 -0.897 0.61290E+04 -1.891 4 H2,gas 8.00 3.89 -4.11 -2.350 0.70221E+04 -2.414 5 H2S,gas -6.23 -14.39 -8.16 -4.078 0.13925E+05 -6.456 6 S2,gas -7.34 -36.55 -29.21 -4.494 0.49875E+05 -27.511 7 CO,gas 3.21 -10.71 -13.92 -4.284 0.23772E+05 -12.223 8 SO3,gas 17.12 -29.93 -47.06 -11.764 0.80346E+05 -45.357 9 SO2,gas 0.83 -26.05 -26.88 -7.168 0.45895E+05 -25.180 10 HF,gas 0.47 -16.35 -16.82 -8.410 0.28721E+05 -15.122 11 HCl,gas 5.19 -13.99 -19.18 -9.589 0.32747E+05 -17.479 12 acmite 7.71 6.71 -1.00 -0.103 0.16990E+04 16 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 20 spessartine 24.46 19.71 -4.75 -0.237 0.81063E+04 21 analcite 3.32 2.76 -0.56 -0.062 0.95252E+03 27 annite 20.12 17.36 -2.77 -0.154 0.47217E+04 28 phlogopite 27.06 25.34 -1.73 -0.096 0.29477E+04 30 anorthite 12.71 8.14 -4.57 -0.352 0.78027E+04 33 apatite-OH -18.15 -18.63 -0.47 -0.036 0.80801E+03 34 apatite-F -34.30 -34.97 -0.67 -0.056 0.11490E+04 38 aragonite 0.97 -1.60 -2.57 -0.855 0.43814E+04 39 brucite 12.57 9.27 -3.29 -0.659 0.56238E+04 40 calcite 0.81 -1.60 -2.41 -0.804 0.41172E+04 41 carnegieite-low 9.02 5.91 -3.11 -0.444 0.53127E+04 42 carnegieite-high 10.09 5.91 -4.18 -0.597 0.71397E+04 43 carpholite-Mg 8.58 4.42 -4.16 -0.277 0.71059E+04 44 carpholite-Fe 6.71 1.76 -4.95 -0.330 0.84558E+04 45 celadonite 5.34 3.64 -1.70 -0.100 0.29046E+04 46 celadonite-Fe 3.88 0.98 -2.90 -0.170 0.49450E+04 47 chrysotile 23.89 21.53 -2.36 -0.197 0.40353E+04 49 clinochlore 39.07 38.37 -0.70 -0.022 0.11905E+04 50 daphnite 28.97 25.07 -3.89 -0.122 0.66476E+04 52 chlorite-Al-free 47.17 43.06 -4.11 -0.171 0.70259E+04 54 chloritoid-Fe 9.17 4.91 -4.27 -0.284 0.72830E+04 55 chloritoid-Mn 11.40 7.53 -3.87 -0.258 0.66084E+04 57 coesite -2.38 -3.15 -0.77 -0.257 0.13178E+04 64 cristobalite -2.56 -3.15 -0.59 -0.196 0.10032E+04 66 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71235E+04 68 diaspore 2.87 0.72 -2.15 -0.359 0.36763E+04 69 diamond -3.10 -6.82 -3.72 -1.062 0.63480E+04 70 diopside 16.18 15.97 -0.21 -0.021 0.35359E+03 71 hedenbergite 14.21 13.31 -0.89 -0.089 0.15266E+04 76 clinoenstatite 17.17 12.25 -4.91 -0.491 0.83874E+04 78 epidote 24.67 22.66 -2.01 -0.097 0.34334E+04 79 clinozoisite 22.81 18.71 -4.10 -0.186 0.69965E+04 80 epidote-Fe 29.84 26.61 -3.23 -0.168 0.55169E+04 81 fayalite 14.05 10.08 -3.96 -0.566 0.67682E+04 82 ferrosilite 11.15 6.93 -4.22 -0.422 0.71978E+04 86 gibbsite 4.08 0.72 -3.36 -0.480 0.57349E+04 87 glaucophane 22.97 20.76 -2.21 -0.060 0.37795E+04 88 glaucophane-Fe 17.28 12.78 -4.49 -0.121 0.76745E+04 89 graphite -3.55 -6.82 -3.27 -0.935 0.55903E+04 90 greenalite 16.14 13.55 -2.59 -0.216 0.44234E+04 93 hematite 12.57 9.34 -3.22 -0.391 0.55042E+04 94 heulandite -5.83 -7.60 -1.77 -0.081 0.30248E+04 98 jadeite 4.22 2.76 -1.45 -0.145 0.24780E+04 100 kalsilite 7.58 3.81 -3.77 -0.539 0.64452E+04 101 kaolinite -1.33 -4.85 -3.52 -0.320 0.60132E+04 104 laumontite 2.88 1.84 -1.04 -0.069 0.17733E+04 105 lawsonite 9.62 8.14 -1.48 -0.098 0.25193E+04 106 leucite 4.12 0.66 -3.46 -0.346 0.59037E+04 108 lizardite 23.24 21.53 -1.71 -0.143 0.29280E+04 110 magnetite 20.09 15.96 -4.13 -0.337 0.70518E+04 111 minnesotaite 10.39 7.25 -3.13 -0.184 0.53529E+04 115 manganosite 14.06 9.24 -4.82 -1.205 0.82313E+04 119 microcline -2.49 -2.49 0.00 0.000 0.11509E+00 123 muscovite 2.58 -1.05 -3.63 -0.213 0.61943E+04 124 paragonite 4.24 1.06 -3.18 -0.187 0.54332E+04 125 nepheline 8.34 5.91 -2.43 -0.347 0.41450E+04 137 phlogopite-Na 29.65 27.44 -2.21 -0.123 0.37664E+04 139 prehnite 19.37 17.99 -1.38 -0.081 0.23633E+04 140 prehnite-Fe 22.50 21.94 -0.56 -0.034 0.95516E+03 141 pumpellyite-Fe 46.27 43.31 -2.96 -0.066 0.50512E+04 142 pumpellyite-Mg 48.99 45.97 -3.02 -0.067 0.51629E+04 145 pyrite -21.25 -26.04 -4.80 -1.128 0.81892E+04 146 pyrrhotite -4.26 -7.77 -3.51 -1.170 0.59935E+04 147 pyrrhotiteFe0.875 -6.02 -9.08 -3.06 -1.126 0.52290E+04 148 pyroxmangite 7.40 6.09 -1.31 -0.262 0.22354E+04 149 pyrophyllite -6.18 -11.15 -4.97 -0.311 0.84937E+04 150 quartz -2.99 -3.15 -0.16 -0.053 0.27053E+03 154 rhodochrosite -0.98 -5.36 -4.38 -1.460 0.74802E+04 155 rhodonite 7.45 6.09 -1.36 -0.271 0.23156E+04 156 sanidine -1.28 -2.49 -1.21 -0.093 0.20679E+04 166 stilbite -7.52 -7.60 -0.08 -0.004 0.13099E+03 167 stilpnomelane-Fe 13.02 12.45 -0.57 -0.017 0.96660E+03 168 stilpnomelane-Mg 27.44 25.75 -1.69 -0.050 0.28861E+04 174 talc 16.49 15.23 -1.26 -0.074 0.21476E+04 177 tephroite 18.09 15.33 -2.76 -0.394 0.47107E+04 181 tridymite -2.63 -3.15 -0.52 -0.174 0.89051E+03 182 tremolite 47.87 47.18 -0.69 -0.019 0.11737E+04 183 ferroactinolite 38.45 33.88 -4.57 -0.124 0.78045E+04 184 troilite-low -4.41 -7.77 -3.36 -1.120 0.57363E+04 190 wairakite 3.95 1.84 -2.11 -0.124 0.35953E+04 191 walstromite 11.51 9.85 -1.66 -0.332 0.28378E+04 192 wollastonite 10.46 9.85 -0.61 -0.123 0.10483E+04 193 pseudo-wollastonite 11.00 9.85 -1.15 -0.231 0.19681E+04 194 zoisite 22.85 18.71 -4.14 -0.188 0.70706E+04 195 akaganeite 7.75 4.67 -3.08 -0.667 0.52647E+04 202 chalcedony -2.80 -3.15 -0.35 -0.115 0.58983E+03 204 montmorillonite-Ca -2.29 -6.18 -3.89 -0.241 0.66462E+04 205 montmorillonite-K -2.24 -6.27 -4.03 -0.247 0.68855E+04 206 montmorillonite-Mg -2.48 -6.80 -4.32 -0.267 0.73713E+04 207 montmorillonite-Na -2.04 -5.58 -3.54 -0.217 0.60404E+04 208 nontronite-Ca 3.21 0.17 -3.04 -0.197 0.51953E+04 209 nontronite-H 2.53 -1.97 -4.51 -0.302 0.76922E+04 210 nontronite-K 3.34 0.09 -3.26 -0.209 0.55578E+04 211 nontronite-Mg 3.07 -0.44 -3.52 -0.228 0.60045E+04 212 nontronite-Na 3.52 0.78 -2.74 -0.176 0.46787E+04 228 tobermorite 9.82 7.68 -2.15 -0.586 0.36643E+04 234 alabandite -0.98 -5.15 -4.17 -1.390 0.71203E+04 237 boehmite 4.41 0.72 -3.69 -0.614 0.62932E+04 239 ferrous-oxide 9.81 6.61 -3.20 -0.799 0.54583E+04 245 silica-amorphous -2.09 -3.15 -1.06 -0.352 0.18040E+04 247 an20ab80 2.02 1.32 -0.70 -0.054 0.11897E+04 248 an25ab75 2.65 1.75 -0.90 -0.069 0.15341E+04 249 an30ab70 3.28 2.17 -1.11 -0.085 0.18881E+04 250 tr.625ac.25prg.125 45.16 44.80 -0.37 -0.010 0.62789E+03 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 0.0000400 MOLES Current total amount of reactant added: 0.0013500 MOLES New total amount of reactant added: 0.0013900 MOLES Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.5508E-08 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 7 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 0.0013900 Water: Moles liquid = 0.4985E+02 kg liquid = 0.8981E+00 Moles total = 0.4985E+02 kg total = 0.8980E+00 Activity = 1.0000 Stoichiometric ionic strength = .1141891E-01 Osmotic coef. = 0.9652 True ionic strength = .2009865E-01 Chg. balance for total moles = -.5508E-08 Max. difference allowed = 0.1461E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.90483E-10 -10.0434 0.76010E-10 -10.1191 0.84004E+00 -0.0757 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.16192E-03 -3.7907 0.13520E-03 -3.8690 0.83498E+00 -0.0783 4 SO4-- 0.41695E-09 -9.3799 0.21630E-09 -9.6649 0.51877E+00 -0.2850 5 HCO3- 0.41261E-04 -4.3845 0.34503E-04 -4.4621 0.83620E+00 -0.0777 6 HS- 0.65996E-04 -4.1805 0.55113E-04 -4.2587 0.83510E+00 -0.0783 7 Al+++ 0.10001E-28 -29.0000 0.23050E-29 -29.6373 0.23048E+00 -0.6374 8 H4SiO4 0.71189E-03 -3.1476 0.71189E-03 -3.1476 0.10000E+01 0.0000 9 Ca++ 0.11039E-06 -6.9571 0.56847E-07 -7.2453 0.51495E+00 -0.2882 10 Mg++ 0.21199E-10 -10.6737 0.10866E-10 -10.9639 0.51258E+00 -0.2902 11 Fe++ 0.46419E-13 -13.3333 0.23820E-13 -13.6231 0.51315E+00 -0.2898 12 K+ 0.15652E-03 -3.8054 0.13091E-03 -3.8830 0.83640E+00 -0.0776 13 Na+ 0.19865E-01 -1.7019 0.16584E-01 -1.7803 0.83483E+00 -0.0784 14 Mn++ 0.19431E-10 -10.7115 0.99792E-11 -11.0009 0.51357E+00 -0.2894 15 F- 0.72809E-06 -6.1378 0.60668E-06 -6.2170 0.83325E+00 -0.0792 16 HPO4-- 0.45337E-07 -7.3435 0.23523E-07 -7.6285 0.51884E+00 -0.2850 18 HSiO3- 0.10474E-01 -1.9799 0.87452E-02 -2.0582 0.83498E+00 -0.0783 19 Ca(HSiO3)+ 0.13533E-07 -7.8686 0.11322E-07 -7.9461 0.83658E+00 -0.0775 20 Mg(HSiO3)+ 0.32195E-11 -11.4922 0.26934E-11 -11.5697 0.83658E+00 -0.0775 21 NaHSiO3,aq 0.23457E-02 -2.6297 0.23457E-02 -2.6297 0.10000E+01 0.0000 22 AlO+ 0.64879E-16 -16.1879 0.54277E-16 -16.2654 0.83658E+00 -0.0775 24 HAlO2,aq 0.14221E-09 -9.8471 0.14221E-09 -9.8471 0.10000E+01 0.0000 25 AlO2- 0.49689E-05 -5.3037 0.41414E-05 -5.3829 0.83347E+00 -0.0791 26 CH4,aq 0.85694E-05 -5.0670 0.85396E-05 -5.0686 0.99652E+00 -0.0015 27 C2H6,aq 0.43148E-14 -14.3650 0.42997E-14 -14.3666 0.99652E+00 -0.0015 31 CO,aq 0.40816E-15 -15.3892 0.40816E-15 -15.3892 0.10000E+01 0.0000 32 CO2,aq 0.56233E-08 -8.2500 0.56038E-08 -8.2515 0.99652E+00 -0.0015 33 CO3-2 0.76591E-04 -4.1158 0.39648E-04 -4.4018 0.51766E+00 -0.2860 34 CaCO3,aq 0.28261E-07 -7.5488 0.28261E-07 -7.5488 0.10000E+01 0.0000 35 Ca(HCO3)+ 0.59846E-10 -10.2230 0.50066E-10 -10.3005 0.83658E+00 -0.0775 36 CaCl+ 0.14868E-10 -10.8278 0.12438E-10 -10.9053 0.83658E+00 -0.0775 37 CaCl2,aq 0.39952E-15 -15.3985 0.39952E-15 -15.3985 0.10000E+01 0.0000 38 CaF+ 0.60189E-12 -12.2205 0.50353E-12 -12.2980 0.83658E+00 -0.0775 39 CaOH+ 0.63714E-07 -7.1958 0.53302E-07 -7.2733 0.83658E+00 -0.0775 40 CaSO4,aq 0.39046E-14 -14.4084 0.39046E-14 -14.4084 0.10000E+01 0.0000 41 HCl,aq 0.18831E-14 -14.7251 0.18831E-14 -14.7251 0.10000E+01 0.0000 45 HF,aq 0.31568E-12 -12.5007 0.31568E-12 -12.5007 0.10000E+01 0.0000 46 HF2- 0.77441E-19 -19.1110 0.64662E-19 -19.1894 0.83498E+00 -0.0783 48 FeCl+ 0.60932E-17 -17.2152 0.50975E-17 -17.2926 0.83658E+00 -0.0775 51 FeF+ 0.88273E-18 -18.0542 0.73848E-18 -18.1317 0.83658E+00 -0.0775 53 FeO,aq 0.16024E-09 -9.7952 0.16024E-09 -9.7952 0.10000E+01 0.0000 54 FeOH+ 0.12193E-10 -10.9139 0.10201E-10 -10.9914 0.83658E+00 -0.0775 55 HFeO2- 0.26417E-07 -7.5781 0.22057E-07 -7.6564 0.83498E+00 -0.0783 56 FeO+ 0.17080E-16 -16.7675 0.14289E-16 -16.8450 0.83658E+00 -0.0775 58 FeO2- 0.60609E-09 -9.2175 0.50607E-09 -9.2958 0.83498E+00 -0.0783 59 HFeO2,aq 0.48923E-11 -11.3105 0.48923E-11 -11.3105 0.10000E+01 0.0000 60 H2,aq 0.29096E-05 -5.5362 0.28994E-05 -5.5377 0.99652E+00 -0.0015 61 KCl,aq 0.32079E-09 -9.4938 0.32079E-09 -9.4938 0.10000E+01 0.0000 63 KOH,aq 0.73554E-06 -6.1334 0.73554E-06 -6.1334 0.10000E+01 0.0000 64 KSO4- 0.52626E-12 -12.2788 0.43941E-12 -12.3571 0.83498E+00 -0.0783 65 MgCO3,aq 0.13541E-11 -11.8683 0.13541E-11 -11.8683 0.10000E+01 0.0000 66 Mg(HCO3)+ 0.11689E-13 -13.9322 0.97790E-14 -14.0097 0.83658E+00 -0.0775 67 MgCl+ 0.25758E-14 -14.5891 0.21549E-14 -14.6666 0.83658E+00 -0.0775 68 MgF+ 0.42619E-15 -15.3704 0.35654E-15 -15.4479 0.83658E+00 -0.0775 69 MgOH+ 0.67393E-10 -10.1714 0.56380E-10 -10.2489 0.83658E+00 -0.0775 71 MnF+ 0.12190E-15 -15.9140 0.10198E-15 -15.9915 0.83658E+00 -0.0775 72 MnO,aq 0.17887E-08 -8.7475 0.17887E-08 -8.7475 0.10000E+01 0.0000 73 MnOH+ 0.47455E-09 -9.3237 0.39700E-09 -9.4012 0.83658E+00 -0.0775 74 MnO2-2 0.19849E-10 -10.7023 0.10275E-10 -10.9882 0.51766E+00 -0.2860 75 HMnO2- 0.20492E-09 -9.6884 0.17110E-09 -9.7667 0.83498E+00 -0.0783 78 MnCl+ 0.99312E-14 -14.0030 0.83083E-14 -14.0805 0.83658E+00 -0.0775 79 MnSO4,aq 0.62315E-18 -18.2054 0.62315E-18 -18.2054 0.10000E+01 0.0000 80 NaCl,aq 0.74305E-06 -6.1290 0.74305E-06 -6.1290 0.10000E+01 0.0000 81 NaF,aq 0.23555E-08 -8.6279 0.23555E-08 -8.6279 0.10000E+01 0.0000 82 NaOH,aq 0.93741E-04 -4.0281 0.93741E-04 -4.0281 0.10000E+01 0.0000 84 OH- 0.91201E-02 -2.0400 0.76013E-02 -2.1191 0.83347E+00 -0.0791 89 HPO3-2 0.41058E-15 -15.3866 0.21254E-15 -15.6726 0.51766E+00 -0.2860 91 H2PO3- 0.38799E-19 -19.4112 0.32396E-19 -19.4895 0.83498E+00 -0.0783 92 H3PO4,aq 0.95050E-18 -18.0220 0.95050E-18 -18.0220 0.10000E+01 0.0000 93 H2PO4- 0.39464E-10 -10.4038 0.32983E-10 -10.4817 0.83577E+00 -0.0779 94 PO4-3 0.10429E-08 -8.9818 0.25249E-09 -9.5978 0.24211E+00 -0.6160 98 HP2O7-3 0.97126E-18 -18.0127 0.22408E-18 -18.6496 0.23071E+00 -0.6369 99 P2O7-4 0.91718E-17 -17.0375 0.70428E-18 -18.1523 0.76788E-01 -1.1147 100 H2S,aq 0.12992E-07 -7.8863 0.12947E-07 -7.8878 0.99652E+00 -0.0015 101 S2-2 0.44842E-13 -13.3483 0.23213E-13 -13.6343 0.51766E+00 -0.2860 107 SO3-2 0.15518E-15 -15.8092 0.81498E-16 -16.0889 0.52517E+00 -0.2797 108 HSO3- 0.46452E-18 -18.3330 0.38786E-18 -18.4113 0.83498E+00 -0.0783 109 HSO4- 0.18921E-16 -16.7231 0.15845E-16 -16.8001 0.83740E+00 -0.0771 111 S2O3-2 0.63548E-19 -19.1969 0.32897E-19 -19.4828 0.51766E+00 -0.2860 Charge balance for all species = -.6133E-08 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.9048323E-10 -.2213123E-01 -.2226808E+02 0.0000 2 H2O 0.1000000E+01 0.5550467E+02 0.9981907E+06 0.0000 3 Cl- 0.1619208E-03 0.1626642E-03 0.5756884E+01 6.2501 4 SO4-- 0.4169531E-09 -.9296326E-05 -.8914638E+00 10.5733 5 HCO3- 0.4126106E-04 0.1264555E-03 0.7702517E+01 5.6570 6 HS- 0.6599582E-04 0.7530556E-04 0.2486165E+01 5.8604 7 Al+++ 0.1000107E-28 0.4969031E-05 0.1338383E+00 0.7201 8 H4SiO4 0.7118947E-03 0.1353119E-01 0.1298289E+04 -3.1476 9 Ca++ 0.1103944E-06 0.2159784E-06 0.8640896E-02 12.9930 10 Mg++ 0.2119940E-10 0.9318036E-10 0.2261453E-05 9.2743 11 Fe++ 0.4641937E-13 0.2720028E-07 0.1516407E-02 6.6152 12 K+ 0.1565214E-03 0.1572573E-03 0.6138359E+01 6.2361 13 Na+ 0.1986507E-01 0.2230522E-01 0.5118989E+03 8.3388 14 Mn++ 0.1943097E-10 0.2507508E-08 0.1375174E-03 9.2374 15 F- 0.7280920E-06 0.7304484E-06 0.1385288E-01 3.9021 16 HPO4-- 0.4533696E-07 0.4641932E-07 0.4447516E-02 12.6097 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.1987687E-01 -.1987558E-01 -.1293386E-05 0.0000000E+00 2 H2O 0.4984755E+02 0.4984755E+02 -.1250181E-05 0.0000000E+00 3 Cl- 0.1460852E-03 0.1460852E-03 0.0000000E+00 0.0000000E+00 4 SO4-- -.8347810E-05 -.8348831E-05 0.1020535E-08 0.0000000E+00 5 HCO3- 0.1135670E-03 0.1135670E-03 0.0000000E+00 0.0000000E+00 6 HS- 0.6762928E-04 0.6763030E-04 -.1020535E-08 0.0000000E+00 7 Al+++ 0.4775352E-05 0.4462580E-05 0.3127725E-06 0.0000000E+00 8 H4SiO4 0.1215302E-01 0.1215207E-01 0.9486923E-06 0.0000000E+00 9 Ca++ 0.2080835E-06 0.1939655E-06 0.1411799E-07 0.0000000E+00 10 Mg++ 0.8368328E-10 0.8368328E-10 0.0000000E+00 0.0000000E+00 11 Fe++ 0.3259227E-07 0.2442799E-07 0.8164282E-08 0.0000000E+00 12 K+ 0.1412294E-03 0.1412294E-03 0.0000000E+00 0.0000000E+00 13 Na+ 0.2003215E-01 0.2003184E-01 0.3115248E-06 0.0000000E+00 14 Mn++ 0.2251939E-08 0.2251939E-08 0.0000000E+00 0.0000000E+00 15 F- 0.6560000E-06 0.6560000E-06 0.0000000E+00 0.0000000E+00 16 HPO4-- 0.4168819E-07 0.4168819E-07 0.0000000E+00 0.0000000E+00 Chg. balance for solid moles: 0.1588E-21 Mass of aqueous solution: 0.899646E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 0.0013900 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 0.3115E-06 -6.507 0.8169E-04 -4.088 97.20 0.3136E-04 andradite 0.4082E-08 -8.389 0.2074E-05 -5.683 2.468 0.5390E-06 grossular 0.6239E-09 -9.205 0.2810E-06 -6.551 0.3344 0.7819E-07 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8674E+00 0.8674E+00 1.0000 -0.062 grossular 0.1326E+00 0.1326E+00 1.0000 -0.878 Solid products produced: Mass = 0.000084 g Volume = 0.000032 cm3 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.0013900 moles log = -2.8570 Original solution: 1000.0103000 g Original solution / Rock added: 719431.87 (Water/Rock Ratio), log = 5.8570 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0367 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9844E+00 0.9857 0.1006E+01 0.1021E+01 CO2,gas 0.5743E-06 1.0069 0.5995E-06 0.5954E-06 CH4,gas 0.1198E-01 1.0124 0.1257E-01 0.1242E-01 H2,gas 0.3670E-02 1.0006 0.3807E-02 0.3805E-02 H2S,gas 0.3447E-06 0.9960 0.3559E-06 0.3573E-06 S2,gas 0.3165E-27 1.0000 0.3281E-27 0.3281E-27 CO,gas 0.5867E-12 1.0000 0.6082E-12 0.6082E-12 SO3,gas 0.4558E-45 1.0000 0.4725E-45 0.4725E-45 SO2,gas 0.6750E-25 1.0000 0.6998E-25 0.6998E-25 HF,gas 0.7476E-15 1.0000 0.7751E-15 0.7751E-15 HCl,gas 0.3205E-17 1.0000 0.3323E-17 0.3323E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 17 albite -0.38 -0.38 0.00 0.000 -0.94784E-12 23 andradite 39.01 39.01 0.00 0.000 0.00000E+00 24 grossular 32.73 32.73 0.00 0.000 0.12132E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -14.58 -7.92 -2.640 0.13525E+05 -6.222 3 CH4,gas 4.54 0.94 -3.60 -0.900 0.61463E+04 -1.901 4 H2,gas 8.00 3.88 -4.12 -2.353 0.70321E+04 -2.419 5 H2S,gas -6.23 -14.38 -8.15 -4.074 0.13912E+05 -6.449 6 S2,gas -7.34 -36.52 -29.18 -4.490 0.49829E+05 -27.484 7 CO,gas 3.21 -10.70 -13.91 -4.282 0.23759E+05 -12.216 8 SO3,gas 17.12 -29.90 -47.02 -11.756 0.80293E+05 -45.326 9 SO2,gas 0.83 -26.02 -26.85 -7.161 0.45853E+05 -25.155 10 HF,gas 0.47 -16.34 -16.81 -8.405 0.28702E+05 -15.111 11 HCl,gas 5.19 -13.99 -19.18 -9.589 0.32745E+05 -17.478 12 acmite 7.71 6.72 -0.99 -0.103 0.16930E+04 16 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 20 spessartine 24.46 19.71 -4.75 -0.237 0.81069E+04 21 analcite 3.32 2.76 -0.56 -0.062 0.95302E+03 27 annite 20.12 17.36 -2.76 -0.154 0.47201E+04 28 phlogopite 27.06 25.34 -1.73 -0.096 0.29507E+04 30 anorthite 12.71 8.14 -4.57 -0.352 0.78072E+04 33 apatite-OH -18.15 -18.64 -0.48 -0.037 0.82298E+03 34 apatite-F -34.30 -34.97 -0.67 -0.056 0.11451E+04 38 aragonite 0.97 -1.59 -2.55 -0.852 0.43623E+04 39 brucite 12.57 9.27 -3.29 -0.659 0.56248E+04 40 calcite 0.81 -1.59 -2.40 -0.800 0.40981E+04 41 carnegieite-low 9.02 5.91 -3.11 -0.445 0.53136E+04 42 carnegieite-high 10.09 5.91 -4.18 -0.597 0.71406E+04 43 carpholite-Mg 8.58 4.42 -4.16 -0.278 0.71078E+04 44 carpholite-Fe 6.71 1.76 -4.95 -0.330 0.84562E+04 45 celadonite 5.34 3.64 -1.70 -0.100 0.29051E+04 46 celadonite-Fe 3.88 0.98 -2.90 -0.170 0.49439E+04 47 chrysotile 23.89 21.53 -2.36 -0.197 0.40373E+04 49 clinochlore 39.07 38.37 -0.70 -0.022 0.11959E+04 50 daphnite 28.97 25.07 -3.89 -0.122 0.66452E+04 52 chlorite-Al-free 47.17 43.06 -4.12 -0.172 0.70299E+04 54 chloritoid-Fe 9.17 4.91 -4.27 -0.284 0.72838E+04 55 chloritoid-Mn 11.40 7.53 -3.87 -0.258 0.66099E+04 57 coesite -2.38 -3.15 -0.77 -0.257 0.13174E+04 64 cristobalite -2.56 -3.15 -0.59 -0.196 0.10027E+04 66 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71235E+04 68 diaspore 2.87 0.72 -2.15 -0.359 0.36773E+04 69 diamond -3.10 -6.82 -3.72 -1.062 0.63454E+04 70 diopside 16.18 15.97 -0.21 -0.021 0.35722E+03 71 hedenbergite 14.21 13.31 -0.90 -0.090 0.15287E+04 76 clinoenstatite 17.17 12.25 -4.91 -0.491 0.83884E+04 78 epidote 24.67 22.66 -2.01 -0.098 0.34355E+04 79 clinozoisite 22.81 18.70 -4.10 -0.186 0.70051E+04 80 epidote-Fe 29.84 26.61 -3.23 -0.168 0.55125E+04 81 fayalite 14.05 10.08 -3.96 -0.566 0.67666E+04 82 ferrosilite 11.15 6.94 -4.21 -0.421 0.71957E+04 86 gibbsite 4.08 0.72 -3.36 -0.480 0.57358E+04 87 glaucophane 22.97 20.76 -2.21 -0.060 0.37815E+04 88 glaucophane-Fe 17.28 12.78 -4.49 -0.121 0.76719E+04 89 graphite -3.55 -6.82 -3.27 -0.935 0.55876E+04 90 greenalite 16.14 13.55 -2.59 -0.216 0.44208E+04 93 hematite 12.57 9.35 -3.22 -0.390 0.54931E+04 94 heulandite -5.83 -7.60 -1.77 -0.081 0.30269E+04 98 jadeite 4.22 2.76 -1.45 -0.145 0.24785E+04 100 kalsilite 7.58 3.81 -3.78 -0.539 0.64462E+04 101 kaolinite -1.33 -4.86 -3.52 -0.320 0.60142E+04 104 laumontite 2.88 1.84 -1.04 -0.069 0.17769E+04 105 lawsonite 9.62 8.14 -1.48 -0.099 0.25239E+04 106 leucite 4.12 0.66 -3.46 -0.346 0.59042E+04 108 lizardite 23.24 21.53 -1.72 -0.143 0.29300E+04 110 magnetite 20.09 15.96 -4.12 -0.337 0.70401E+04 111 minnesotaite 10.39 7.26 -3.13 -0.184 0.53492E+04 115 manganosite 14.06 9.24 -4.82 -1.205 0.82313E+04 119 microcline -2.49 -2.49 0.00 0.000 0.11857E+00 123 muscovite 2.58 -1.05 -3.63 -0.213 0.61962E+04 124 paragonite 4.24 1.06 -3.18 -0.187 0.54352E+04 125 nepheline 8.34 5.91 -2.43 -0.347 0.41460E+04 137 phlogopite-Na 29.65 27.44 -2.21 -0.123 0.37694E+04 139 prehnite 19.37 17.98 -1.39 -0.082 0.23709E+04 140 prehnite-Fe 22.50 21.94 -0.56 -0.034 0.95631E+03 141 pumpellyite-Fe 46.27 43.30 -2.97 -0.066 0.50669E+04 142 pumpellyite-Mg 48.99 45.96 -3.03 -0.067 0.51802E+04 145 pyrite -21.25 -26.02 -4.77 -1.124 0.81531E+04 146 pyrrhotite -4.26 -7.76 -3.50 -1.167 0.59802E+04 147 pyrrhotiteFe0.875 -6.02 -9.07 -3.05 -1.123 0.52145E+04 148 pyroxmangite 7.40 6.09 -1.31 -0.262 0.22349E+04 149 pyrophyllite -6.18 -11.15 -4.97 -0.311 0.84937E+04 150 quartz -2.99 -3.15 -0.16 -0.053 0.27004E+03 154 rhodochrosite -0.98 -5.34 -4.37 -1.456 0.74576E+04 155 rhodonite 7.45 6.09 -1.36 -0.271 0.23152E+04 156 sanidine -1.28 -2.49 -1.21 -0.093 0.20679E+04 166 stilbite -7.52 -7.60 -0.08 -0.004 0.13306E+03 167 stilpnomelane-Fe 13.02 12.45 -0.56 -0.017 0.96206E+03 168 stilpnomelane-Mg 27.44 25.75 -1.69 -0.051 0.28893E+04 174 talc 16.49 15.23 -1.26 -0.074 0.21486E+04 177 tephroite 18.09 15.33 -2.76 -0.394 0.47103E+04 181 tridymite -2.63 -3.15 -0.52 -0.174 0.89001E+03 182 tremolite 47.87 47.18 -0.69 -0.019 0.11820E+04 183 ferroactinolite 38.45 33.88 -4.57 -0.124 0.78050E+04 184 troilite-low -4.41 -7.76 -3.35 -1.117 0.57230E+04 190 wairakite 3.95 1.84 -2.11 -0.124 0.35988E+04 191 walstromite 11.51 9.85 -1.66 -0.333 0.28410E+04 192 wollastonite 10.46 9.85 -0.62 -0.123 0.10514E+04 193 pseudo-wollastonite 11.00 9.85 -1.15 -0.231 0.19712E+04 194 zoisite 22.85 18.70 -4.15 -0.188 0.70792E+04 195 akaganeite 7.75 4.67 -3.08 -0.666 0.52591E+04 202 chalcedony -2.80 -3.15 -0.35 -0.115 0.58933E+03 204 montmorillonite-Ca -2.29 -6.18 -3.89 -0.241 0.66467E+04 205 montmorillonite-K -2.24 -6.27 -4.03 -0.247 0.68856E+04 206 montmorillonite-Mg -2.48 -6.80 -4.32 -0.267 0.73714E+04 207 montmorillonite-Na -2.04 -5.58 -3.54 -0.217 0.60405E+04 208 nontronite-Ca 3.21 0.18 -3.04 -0.197 0.51833E+04 209 nontronite-H 2.53 -1.96 -4.50 -0.301 0.76796E+04 210 nontronite-K 3.34 0.09 -3.25 -0.208 0.55454E+04 211 nontronite-Mg 3.07 -0.43 -3.51 -0.228 0.59920E+04 212 nontronite-Na 3.52 0.79 -2.73 -0.175 0.46662E+04 228 tobermorite 9.82 7.68 -2.15 -0.586 0.36668E+04 234 alabandite -0.98 -5.14 -4.16 -1.388 0.71076E+04 237 boehmite 4.41 0.72 -3.69 -0.614 0.62942E+04 239 ferrous-oxide 9.81 6.62 -3.20 -0.799 0.54577E+04 245 silica-amorphous -2.09 -3.15 -1.06 -0.352 0.18035E+04 247 an20ab80 2.02 1.32 -0.70 -0.054 0.11906E+04 248 an25ab75 2.65 1.75 -0.90 -0.069 0.15352E+04 249 an30ab70 3.28 2.17 -1.11 -0.085 0.18894E+04 250 tr.625ac.25prg.125 45.16 44.79 -0.37 -0.010 0.63465E+03 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 0.0000400 MOLES Current total amount of reactant added: 0.0013900 MOLES New total amount of reactant added: 0.0014300 MOLES Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.5508E-08 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 7 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 0.0014300 Water: Moles liquid = 0.4985E+02 kg liquid = 0.8981E+00 Moles total = 0.4985E+02 kg total = 0.8980E+00 Activity = 1.0000 Stoichiometric ionic strength = .1142146E-01 Osmotic coef. = 0.9651 True ionic strength = .2010100E-01 Chg. balance for total moles = -.5508E-08 Max. difference allowed = 0.1463E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.90548E-10 -10.0431 0.76064E-10 -10.1188 0.84004E+00 -0.0757 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.16218E-03 -3.7900 0.13542E-03 -3.8683 0.83497E+00 -0.0783 4 SO4-- 0.44688E-09 -9.3498 0.23182E-09 -9.6348 0.51875E+00 -0.2850 5 HCO3- 0.42478E-04 -4.3718 0.35520E-04 -4.4495 0.83620E+00 -0.0777 6 HS- 0.67078E-04 -4.1734 0.56016E-04 -4.2517 0.83509E+00 -0.0783 7 Al+++ 0.10010E-28 -28.9996 0.23070E-29 -29.6370 0.23046E+00 -0.6374 8 H4SiO4 0.71237E-03 -3.1473 0.71237E-03 -3.1473 0.10000E+01 0.0000 9 Ca++ 0.11002E-06 -6.9585 0.56652E-07 -7.2468 0.51493E+00 -0.2883 10 Mg++ 0.21202E-10 -10.6736 0.10867E-10 -10.9639 0.51257E+00 -0.2902 11 Fe++ 0.46522E-13 -13.3323 0.23872E-13 -13.6221 0.51313E+00 -0.2898 12 K+ 0.15652E-03 -3.8054 0.13091E-03 -3.8830 0.83640E+00 -0.0776 13 Na+ 0.19865E-01 -1.7019 0.16584E-01 -1.7803 0.83482E+00 -0.0784 14 Mn++ 0.19458E-10 -10.7109 0.99927E-11 -11.0003 0.51356E+00 -0.2894 15 F- 0.74585E-06 -6.1273 0.62148E-06 -6.2066 0.83325E+00 -0.0792 16 HPO4-- 0.45338E-07 -7.3435 0.23522E-07 -7.6285 0.51882E+00 -0.2850 18 HSiO3- 0.10473E-01 -1.9799 0.87448E-02 -2.0582 0.83497E+00 -0.0783 19 Ca(HSiO3)+ 0.13486E-07 -7.8701 0.11282E-07 -7.9476 0.83658E+00 -0.0775 20 Mg(HSiO3)+ 0.32196E-11 -11.4922 0.26935E-11 -11.5697 0.83658E+00 -0.0775 21 NaHSiO3,aq 0.23456E-02 -2.6298 0.23456E-02 -2.6298 0.10000E+01 0.0000 22 AlO+ 0.64843E-16 -16.1881 0.54246E-16 -16.2656 0.83658E+00 -0.0775 24 HAlO2,aq 0.14202E-09 -9.8476 0.14202E-09 -9.8476 0.10000E+01 0.0000 25 AlO2- 0.49590E-05 -5.3046 0.41331E-05 -5.3837 0.83346E+00 -0.0791 26 CH4,aq 0.83665E-05 -5.0775 0.83373E-05 -5.0790 0.99652E+00 -0.0015 27 C2H6,aq 0.41685E-14 -14.3800 0.41539E-14 -14.3815 0.99652E+00 -0.0015 31 CO,aq 0.41488E-15 -15.3821 0.41488E-15 -15.3821 0.10000E+01 0.0000 32 CO2,aq 0.57933E-08 -8.2371 0.57731E-08 -8.2386 0.99652E+00 -0.0015 33 CO3-2 0.78796E-04 -4.1035 0.40789E-04 -4.3895 0.51765E+00 -0.2860 34 CaCO3,aq 0.28974E-07 -7.5380 0.28974E-07 -7.5380 0.10000E+01 0.0000 35 Ca(HCO3)+ 0.61400E-10 -10.2118 0.51365E-10 -10.2893 0.83658E+00 -0.0775 36 CaCl+ 0.14840E-10 -10.8286 0.12415E-10 -10.9060 0.83658E+00 -0.0775 37 CaCl2,aq 0.39942E-15 -15.3986 0.39942E-15 -15.3986 0.10000E+01 0.0000 38 CaF+ 0.61445E-12 -12.2115 0.51404E-12 -12.2890 0.83658E+00 -0.0775 39 CaOH+ 0.63450E-07 -7.1976 0.53081E-07 -7.2751 0.83658E+00 -0.0775 40 CaSO4,aq 0.41703E-14 -14.3798 0.41703E-14 -14.3798 0.10000E+01 0.0000 41 HCl,aq 0.18875E-14 -14.7241 0.18875E-14 -14.7241 0.10000E+01 0.0000 45 HF,aq 0.32361E-12 -12.4900 0.32361E-12 -12.4900 0.10000E+01 0.0000 46 HF2- 0.81322E-19 -19.0898 0.67902E-19 -19.1681 0.83497E+00 -0.0783 48 FeCl+ 0.61163E-17 -17.2135 0.51167E-17 -17.2910 0.83658E+00 -0.0775 51 FeF+ 0.90623E-18 -18.0428 0.75813E-18 -18.1203 0.83658E+00 -0.0775 53 FeO,aq 0.16036E-09 -9.7949 0.16036E-09 -9.7949 0.10000E+01 0.0000 54 FeOH+ 0.12211E-10 -10.9132 0.10216E-10 -10.9907 0.83658E+00 -0.0775 55 HFeO2- 0.26418E-07 -7.5781 0.22058E-07 -7.6564 0.83497E+00 -0.0783 56 FeO+ 0.17221E-16 -16.7640 0.14406E-16 -16.8414 0.83658E+00 -0.0775 58 FeO2- 0.61020E-09 -9.2145 0.50950E-09 -9.2929 0.83497E+00 -0.0783 59 HFeO2,aq 0.49290E-11 -11.3072 0.49290E-11 -11.3072 0.10000E+01 0.0000 60 H2,aq 0.28707E-05 -5.5420 0.28607E-05 -5.5435 0.99652E+00 -0.0015 61 KCl,aq 0.32131E-09 -9.4931 0.32131E-09 -9.4931 0.10000E+01 0.0000 63 KOH,aq 0.73501E-06 -6.1337 0.73501E-06 -6.1337 0.10000E+01 0.0000 64 KSO4- 0.56401E-12 -12.2487 0.47094E-12 -12.3270 0.83497E+00 -0.0783 65 MgCO3,aq 0.13932E-11 -11.8560 0.13932E-11 -11.8560 0.10000E+01 0.0000 66 Mg(HCO3)+ 0.12035E-13 -13.9196 0.10068E-13 -13.9970 0.83658E+00 -0.0775 67 MgCl+ 0.25802E-14 -14.5884 0.21585E-14 -14.6658 0.83658E+00 -0.0775 68 MgF+ 0.43662E-15 -15.3599 0.36527E-15 -15.4374 0.83658E+00 -0.0775 69 MgOH+ 0.67351E-10 -10.1717 0.56344E-10 -10.2492 0.83658E+00 -0.0775 71 MnF+ 0.12504E-15 -15.9030 0.10460E-15 -15.9805 0.83658E+00 -0.0775 72 MnO,aq 0.17886E-08 -8.7475 0.17886E-08 -8.7475 0.10000E+01 0.0000 73 MnOH+ 0.47486E-09 -9.3234 0.39725E-09 -9.4009 0.83658E+00 -0.0775 74 MnO2-2 0.19819E-10 -10.7029 0.10259E-10 -10.9889 0.51765E+00 -0.2860 75 HMnO2- 0.20476E-09 -9.6888 0.17097E-09 -9.7671 0.83497E+00 -0.0783 78 MnCl+ 0.99606E-14 -14.0017 0.83328E-14 -14.0792 0.83658E+00 -0.0775 79 MnSO4,aq 0.66875E-18 -18.1747 0.66875E-18 -18.1747 0.10000E+01 0.0000 80 NaCl,aq 0.74425E-06 -6.1283 0.74425E-06 -6.1283 0.10000E+01 0.0000 81 NaF,aq 0.24129E-08 -8.6175 0.24129E-08 -8.6175 0.10000E+01 0.0000 82 NaOH,aq 0.93674E-04 -4.0284 0.93674E-04 -4.0284 0.10000E+01 0.0000 84 OH- 0.91137E-02 -2.0403 0.75959E-02 -2.1194 0.83346E+00 -0.0791 89 HPO3-2 0.40511E-15 -15.3924 0.20970E-15 -15.6784 0.51765E+00 -0.2860 91 H2PO3- 0.38308E-19 -19.4167 0.31986E-19 -19.4950 0.83497E+00 -0.0783 92 H3PO4,aq 0.95184E-18 -18.0214 0.95184E-18 -18.0214 0.10000E+01 0.0000 93 H2PO4- 0.39492E-10 -10.4035 0.33006E-10 -10.4814 0.83576E+00 -0.0779 94 PO4-3 0.10422E-08 -8.9821 0.25231E-09 -9.5981 0.24209E+00 -0.6160 98 HP2O7-3 0.97199E-18 -18.0123 0.22423E-18 -18.6493 0.23070E+00 -0.6370 99 P2O7-4 0.91726E-17 -17.0375 0.70426E-18 -18.1523 0.76778E-01 -1.1148 100 H2S,aq 0.13215E-07 -7.8789 0.13169E-07 -7.8805 0.99652E+00 -0.0015 101 S2-2 0.46951E-13 -13.3284 0.24304E-13 -13.6143 0.51765E+00 -0.2860 107 SO3-2 0.16410E-15 -15.7849 0.86180E-16 -16.0646 0.52516E+00 -0.2797 108 HSO3- 0.49156E-18 -18.3084 0.41043E-18 -18.3868 0.83497E+00 -0.0783 109 HSO4- 0.20293E-16 -16.6926 0.16993E-16 -16.7697 0.83739E+00 -0.0771 111 S2O3-2 0.69275E-19 -19.1594 0.35860E-19 -19.4454 0.51765E+00 -0.2860 Charge balance for all species = -.6133E-08 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.9054840E-10 -.2212637E-01 -.2226319E+02 0.0000 2 H2O 0.1000000E+01 0.5550466E+02 0.9981905E+06 0.0000 3 Cl- 0.1621823E-03 0.1629268E-03 0.5766178E+01 6.2505 4 SO4-- 0.4468807E-09 -.9083642E-05 -.8710685E+00 10.6028 5 HCO3- 0.4247822E-04 0.1296756E-03 0.7898655E+01 5.6693 6 HS- 0.6707783E-04 0.7617513E-04 0.2514873E+01 5.8671 7 Al+++ 0.1001029E-28 0.4959148E-05 0.1335721E+00 0.7195 8 H4SiO4 0.7123693E-03 0.1353115E-01 0.1298285E+04 -3.1473 9 Ca++ 0.1100182E-06 0.2160055E-06 0.8641981E-02 12.9909 10 Mg++ 0.2120180E-10 0.9318029E-10 0.2261451E-05 9.2738 11 Fe++ 0.4652160E-13 0.2720557E-07 0.1516701E-02 6.6155 12 K+ 0.1565218E-03 0.1572572E-03 0.6138354E+01 6.2358 13 Na+ 0.1986522E-01 0.2230519E-01 0.5118983E+03 8.3385 14 Mn++ 0.1945775E-10 0.2507506E-08 0.1375173E-03 9.2373 15 F- 0.7458498E-06 0.7482636E-06 0.1419074E-01 3.9122 16 HPO4-- 0.4533759E-07 0.4641928E-07 0.4447512E-02 12.6091 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.1987256E-01 -.1987124E-01 -.1328828E-05 0.0000000E+00 2 H2O 0.4984758E+02 0.4984758E+02 -.1285713E-05 0.0000000E+00 3 Cl- 0.1463212E-03 0.1463212E-03 0.0000000E+00 0.0000000E+00 4 SO4-- -.8156810E-05 -.8157830E-05 0.1019940E-08 0.0000000E+00 5 HCO3- 0.1164590E-03 0.1164590E-03 0.0000000E+00 0.0000000E+00 6 HS- 0.6841028E-04 0.6841130E-04 -.1019940E-08 0.0000000E+00 7 Al+++ 0.4775352E-05 0.4453707E-05 0.3216445E-06 0.0000000E+00 8 H4SiO4 0.1215302E-01 0.1215204E-01 0.9753187E-06 0.0000000E+00 9 Ca++ 0.2080835E-06 0.1939900E-06 0.1409345E-07 0.0000000E+00 10 Mg++ 0.8368328E-10 0.8368328E-10 0.0000000E+00 0.0000000E+00 11 Fe++ 0.3259227E-07 0.2443275E-07 0.8159517E-08 0.0000000E+00 12 K+ 0.1412294E-03 0.1412294E-03 0.0000000E+00 0.0000000E+00 13 Na+ 0.2003215E-01 0.2003183E-01 0.3204084E-06 0.0000000E+00 14 Mn++ 0.2251939E-08 0.2251939E-08 0.0000000E+00 0.0000000E+00 15 F- 0.6720000E-06 0.6720000E-06 0.0000000E+00 0.0000000E+00 16 HPO4-- 0.4168819E-07 0.4168819E-07 0.0000000E+00 0.0000000E+00 Chg. balance for solid moles: 0.1059E-21 Mass of aqueous solution: 0.899647E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 0.0014300 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 0.3204E-06 -6.494 0.8402E-04 -4.076 97.28 0.3225E-04 andradite 0.4080E-08 -8.389 0.2073E-05 -5.683 2.400 0.5386E-06 grossular 0.6181E-09 -9.209 0.2784E-06 -6.555 0.3223 0.7746E-07 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8684E+00 0.8684E+00 1.0000 -0.061 grossular 0.1316E+00 0.1316E+00 1.0000 -0.881 Solid products produced: Mass = 0.000086 g Volume = 0.000033 cm3 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.0014300 moles log = -2.8447 Original solution: 1000.0103000 g Original solution / Rock added: 699307.90 (Water/Rock Ratio), log = 5.8447 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0364 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9847E+00 0.9857 0.1006E+01 0.1021E+01 CO2,gas 0.5919E-06 1.0069 0.6177E-06 0.6134E-06 CH4,gas 0.1170E-01 1.0124 0.1227E-01 0.1212E-01 H2,gas 0.3622E-02 1.0006 0.3756E-02 0.3754E-02 H2S,gas 0.3507E-06 0.9960 0.3620E-06 0.3635E-06 S2,gas 0.3365E-27 1.0000 0.3487E-27 0.3487E-27 CO,gas 0.5965E-12 1.0000 0.6183E-12 0.6183E-12 SO3,gas 0.4893E-45 1.0000 0.5071E-45 0.5071E-45 SO2,gas 0.7150E-25 1.0000 0.7410E-25 0.7410E-25 HF,gas 0.7667E-15 1.0000 0.7946E-15 0.7946E-15 HCl,gas 0.3214E-17 1.0000 0.3331E-17 0.3331E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 17 albite -0.38 -0.38 0.00 0.000 -0.94784E-12 23 andradite 39.01 39.01 0.00 0.000 0.12132E-10 24 grossular 32.73 32.73 0.00 0.000 -0.24265E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -14.57 -7.91 -2.636 0.13503E+05 -6.209 3 CH4,gas 4.54 0.93 -3.61 -0.903 0.61641E+04 -1.911 4 H2,gas 8.00 3.88 -4.12 -2.357 0.70421E+04 -2.425 5 H2S,gas -6.23 -14.37 -8.14 -4.070 0.13899E+05 -6.441 6 S2,gas -7.34 -36.49 -29.16 -4.486 0.49784E+05 -27.458 7 CO,gas 3.21 -10.69 -13.91 -4.279 0.23747E+05 -12.209 8 SO3,gas 17.12 -29.87 -46.99 -11.748 0.80241E+05 -45.295 9 SO2,gas 0.83 -26.00 -26.83 -7.154 0.45810E+05 -25.130 10 HF,gas 0.47 -16.33 -16.80 -8.399 0.28684E+05 -15.100 11 HCl,gas 5.19 -13.99 -19.18 -9.588 0.32743E+05 -17.477 12 acmite 7.71 6.72 -0.99 -0.103 0.16870E+04 16 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 20 spessartine 24.46 19.71 -4.75 -0.237 0.81075E+04 21 analcite 3.32 2.76 -0.56 -0.062 0.95351E+03 27 annite 20.12 17.36 -2.76 -0.154 0.47184E+04 28 phlogopite 27.06 25.33 -1.73 -0.096 0.29537E+04 30 anorthite 12.71 8.14 -4.58 -0.352 0.78117E+04 33 apatite-OH -18.15 -18.64 -0.49 -0.038 0.83790E+03 34 apatite-F -34.30 -34.97 -0.67 -0.056 0.11417E+04 38 aragonite 0.97 -1.58 -2.54 -0.848 0.43438E+04 39 brucite 12.57 9.27 -3.29 -0.659 0.56258E+04 40 calcite 0.81 -1.58 -2.39 -0.796 0.40796E+04 41 carnegieite-low 9.02 5.91 -3.11 -0.445 0.53146E+04 42 carnegieite-high 10.09 5.91 -4.18 -0.598 0.71416E+04 43 carpholite-Mg 8.58 4.42 -4.16 -0.278 0.71097E+04 44 carpholite-Fe 6.71 1.76 -4.95 -0.330 0.84566E+04 45 celadonite 5.34 3.64 -1.70 -0.100 0.29056E+04 46 celadonite-Fe 3.88 0.98 -2.89 -0.170 0.49429E+04 47 chrysotile 23.89 21.53 -2.37 -0.197 0.40394E+04 49 clinochlore 39.07 38.37 -0.70 -0.022 0.12013E+04 50 daphnite 28.97 25.07 -3.89 -0.122 0.66429E+04 52 chlorite-Al-free 47.17 43.05 -4.12 -0.172 0.70339E+04 54 chloritoid-Fe 9.17 4.91 -4.27 -0.284 0.72847E+04 55 chloritoid-Mn 11.40 7.53 -3.87 -0.258 0.66114E+04 57 coesite -2.38 -3.15 -0.77 -0.257 0.13169E+04 64 cristobalite -2.56 -3.15 -0.59 -0.196 0.10022E+04 66 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71235E+04 68 diaspore 2.87 0.72 -2.15 -0.359 0.36782E+04 69 diamond -3.10 -6.82 -3.71 -1.061 0.63432E+04 70 diopside 16.18 15.97 -0.21 -0.021 0.36084E+03 71 hedenbergite 14.21 13.31 -0.90 -0.090 0.15307E+04 76 clinoenstatite 17.17 12.25 -4.91 -0.491 0.83894E+04 78 epidote 24.67 22.66 -2.01 -0.098 0.34376E+04 79 clinozoisite 22.81 18.70 -4.11 -0.187 0.70137E+04 80 epidote-Fe 29.84 26.61 -3.23 -0.168 0.55082E+04 81 fayalite 14.05 10.08 -3.96 -0.566 0.67650E+04 82 ferrosilite 11.15 6.94 -4.21 -0.421 0.71936E+04 86 gibbsite 4.08 0.72 -3.36 -0.480 0.57368E+04 87 glaucophane 22.97 20.76 -2.22 -0.060 0.37835E+04 88 glaucophane-Fe 17.28 12.78 -4.49 -0.121 0.76692E+04 89 graphite -3.55 -6.82 -3.27 -0.935 0.55854E+04 90 greenalite 16.14 13.55 -2.59 -0.216 0.44181E+04 93 hematite 12.57 9.36 -3.21 -0.389 0.54821E+04 94 heulandite -5.83 -7.60 -1.77 -0.081 0.30290E+04 98 jadeite 4.22 2.76 -1.45 -0.145 0.24790E+04 100 kalsilite 7.58 3.81 -3.78 -0.539 0.64472E+04 101 kaolinite -1.33 -4.86 -3.52 -0.320 0.60151E+04 104 laumontite 2.88 1.84 -1.04 -0.070 0.17804E+04 105 lawsonite 9.62 8.14 -1.48 -0.099 0.25284E+04 106 leucite 4.12 0.66 -3.46 -0.346 0.59047E+04 108 lizardite 23.24 21.53 -1.72 -0.143 0.29320E+04 110 magnetite 20.09 15.97 -4.12 -0.336 0.70285E+04 111 minnesotaite 10.39 7.26 -3.13 -0.184 0.53456E+04 115 manganosite 14.06 9.24 -4.82 -1.205 0.82314E+04 119 microcline -2.49 -2.49 0.00 0.000 0.12204E+00 123 muscovite 2.58 -1.05 -3.63 -0.214 0.61981E+04 124 paragonite 4.24 1.06 -3.18 -0.187 0.54371E+04 125 nepheline 8.34 5.91 -2.43 -0.347 0.41470E+04 137 phlogopite-Na 29.65 27.44 -2.21 -0.123 0.37724E+04 139 prehnite 19.37 17.98 -1.39 -0.082 0.23786E+04 140 prehnite-Fe 22.50 21.94 -0.56 -0.034 0.95747E+03 141 pumpellyite-Fe 46.27 43.29 -2.98 -0.066 0.50826E+04 142 pumpellyite-Mg 48.99 45.95 -3.04 -0.068 0.51974E+04 145 pyrite -21.25 -26.00 -4.75 -1.119 0.81174E+04 146 pyrrhotite -4.26 -7.75 -3.49 -1.165 0.59670E+04 147 pyrrhotiteFe0.875 -6.02 -9.06 -3.05 -1.120 0.52002E+04 148 pyroxmangite 7.40 6.09 -1.31 -0.262 0.22345E+04 149 pyrophyllite -6.18 -11.15 -4.97 -0.311 0.84936E+04 150 quartz -2.99 -3.15 -0.16 -0.053 0.26954E+03 154 rhodochrosite -0.98 -5.33 -4.35 -1.452 0.74355E+04 155 rhodonite 7.45 6.09 -1.36 -0.271 0.23147E+04 156 sanidine -1.28 -2.49 -1.21 -0.093 0.20679E+04 166 stilbite -7.52 -7.60 -0.08 -0.004 0.13512E+03 167 stilpnomelane-Fe 13.02 12.46 -0.56 -0.017 0.95753E+03 168 stilpnomelane-Mg 27.44 25.75 -1.69 -0.051 0.28925E+04 174 talc 16.49 15.23 -1.26 -0.074 0.21496E+04 177 tephroite 18.09 15.33 -2.76 -0.394 0.47100E+04 181 tridymite -2.63 -3.15 -0.52 -0.174 0.88952E+03 182 tremolite 47.87 47.17 -0.70 -0.019 0.11903E+04 183 ferroactinolite 38.45 33.88 -4.57 -0.124 0.78055E+04 184 troilite-low -4.41 -7.75 -3.34 -1.115 0.57098E+04 190 wairakite 3.95 1.84 -2.11 -0.124 0.36024E+04 191 walstromite 11.51 9.84 -1.67 -0.333 0.28441E+04 192 wollastonite 10.46 9.84 -0.62 -0.124 0.10545E+04 193 pseudo-wollastonite 11.00 9.84 -1.16 -0.231 0.19743E+04 194 zoisite 22.85 18.70 -4.15 -0.189 0.70878E+04 195 akaganeite 7.75 4.68 -3.08 -0.665 0.52536E+04 202 chalcedony -2.80 -3.15 -0.34 -0.115 0.58884E+03 204 montmorillonite-Ca -2.29 -6.18 -3.89 -0.241 0.66473E+04 205 montmorillonite-K -2.24 -6.27 -4.03 -0.247 0.68858E+04 206 montmorillonite-Mg -2.48 -6.80 -4.32 -0.267 0.73715E+04 207 montmorillonite-Na -2.04 -5.58 -3.54 -0.217 0.60406E+04 208 nontronite-Ca 3.21 0.19 -3.03 -0.196 0.51713E+04 209 nontronite-H 2.53 -1.96 -4.49 -0.301 0.76670E+04 210 nontronite-K 3.34 0.10 -3.24 -0.208 0.55330E+04 211 nontronite-Mg 3.07 -0.43 -3.50 -0.227 0.59796E+04 212 nontronite-Na 3.52 0.79 -2.73 -0.175 0.46538E+04 228 tobermorite 9.82 7.67 -2.15 -0.586 0.36693E+04 234 alabandite -0.98 -5.13 -4.16 -1.385 0.70951E+04 237 boehmite 4.41 0.72 -3.69 -0.614 0.62951E+04 239 ferrous-oxide 9.81 6.62 -3.20 -0.799 0.54572E+04 245 silica-amorphous -2.09 -3.15 -1.06 -0.352 0.18030E+04 247 an20ab80 2.02 1.32 -0.70 -0.054 0.11915E+04 248 an25ab75 2.65 1.75 -0.90 -0.069 0.15363E+04 249 an30ab70 3.28 2.17 -1.11 -0.085 0.18908E+04 250 tr.625ac.25prg.125 45.16 44.79 -0.38 -0.010 0.64139E+03 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 0.0000400 MOLES Current total amount of reactant added: 0.0014300 MOLES New total amount of reactant added: 0.0014700 MOLES Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.5508E-08 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 7 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 0.0014700 Water: Moles liquid = 0.4985E+02 kg liquid = 0.8981E+00 Moles total = 0.4985E+02 kg total = 0.8980E+00 Activity = 1.0000 Stoichiometric ionic strength = .1142401E-01 Osmotic coef. = 0.9650 True ionic strength = .2010335E-01 Chg. balance for total moles = -.5508E-08 Max. difference allowed = 0.1466E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.90614E-10 -10.0428 0.76118E-10 -10.1185 0.84003E+00 -0.0757 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.16244E-03 -3.7893 0.13563E-03 -3.8676 0.83496E+00 -0.0783 4 SO4-- 0.47874E-09 -9.3199 0.24834E-09 -9.6050 0.51873E+00 -0.2851 5 HCO3- 0.43697E-04 -4.3596 0.36539E-04 -4.4372 0.83619E+00 -0.0777 6 HS- 0.68160E-04 -4.1665 0.56919E-04 -4.2447 0.83509E+00 -0.0783 7 Al+++ 0.10020E-28 -28.9992 0.23090E-29 -29.6366 0.23045E+00 -0.6374 8 H4SiO4 0.71284E-03 -3.1470 0.71284E-03 -3.1470 0.10000E+01 0.0000 9 Ca++ 0.10964E-06 -6.9600 0.56458E-07 -7.2483 0.51491E+00 -0.2883 10 Mg++ 0.21204E-10 -10.6736 0.10868E-10 -10.9638 0.51255E+00 -0.2903 11 Fe++ 0.46624E-13 -13.3314 0.23923E-13 -13.6212 0.51311E+00 -0.2898 12 K+ 0.15652E-03 -3.8054 0.13091E-03 -3.8830 0.83639E+00 -0.0776 13 Na+ 0.19865E-01 -1.7019 0.16584E-01 -1.7803 0.83481E+00 -0.0784 14 Mn++ 0.19485E-10 -10.7103 0.10006E-10 -10.9997 0.51354E+00 -0.2894 15 F- 0.76361E-06 -6.1171 0.63627E-06 -6.1964 0.83324E+00 -0.0792 16 HPO4-- 0.45338E-07 -7.3435 0.23522E-07 -7.6285 0.51881E+00 -0.2850 18 HSiO3- 0.10473E-01 -1.9799 0.87444E-02 -2.0583 0.83496E+00 -0.0783 19 Ca(HSiO3)+ 0.13440E-07 -7.8716 0.11243E-07 -7.9491 0.83657E+00 -0.0775 20 Mg(HSiO3)+ 0.32198E-11 -11.4922 0.26936E-11 -11.5697 0.83657E+00 -0.0775 21 NaHSiO3,aq 0.23454E-02 -2.6298 0.23454E-02 -2.6298 0.10000E+01 0.0000 22 AlO+ 0.64806E-16 -16.1884 0.54215E-16 -16.2659 0.83657E+00 -0.0775 24 HAlO2,aq 0.14184E-09 -9.8482 0.14184E-09 -9.8482 0.10000E+01 0.0000 25 AlO2- 0.49491E-05 -5.3055 0.41249E-05 -5.3846 0.83345E+00 -0.0791 26 CH4,aq 0.81634E-05 -5.0881 0.81349E-05 -5.0896 0.99652E+00 -0.0015 27 C2H6,aq 0.40220E-14 -14.3956 0.40080E-14 -14.3971 0.99652E+00 -0.0015 31 CO,aq 0.42140E-15 -15.3753 0.42140E-15 -15.3753 0.10000E+01 0.0000 32 CO2,aq 0.59637E-08 -8.2245 0.59429E-08 -8.2260 0.99652E+00 -0.0015 33 CO3-2 0.81000E-04 -4.0915 0.41928E-04 -4.3775 0.51763E+00 -0.2860 34 CaCO3,aq 0.29682E-07 -7.5275 0.29682E-07 -7.5275 0.10000E+01 0.0000 35 Ca(HCO3)+ 0.62944E-10 -10.2010 0.52657E-10 -10.2785 0.83657E+00 -0.0775 36 CaCl+ 0.14813E-10 -10.8293 0.12392E-10 -10.9068 0.83657E+00 -0.0775 37 CaCl2,aq 0.39933E-15 -15.3987 0.39933E-15 -15.3987 0.10000E+01 0.0000 38 CaF+ 0.62692E-12 -12.2028 0.52447E-12 -12.2803 0.83657E+00 -0.0775 39 CaOH+ 0.63188E-07 -7.1994 0.52861E-07 -7.2769 0.83657E+00 -0.0775 40 CaSO4,aq 0.44522E-14 -14.3514 0.44522E-14 -14.3514 0.10000E+01 0.0000 41 HCl,aq 0.18919E-14 -14.7231 0.18919E-14 -14.7231 0.10000E+01 0.0000 45 HF,aq 0.33155E-12 -12.4795 0.33155E-12 -12.4795 0.10000E+01 0.0000 46 HF2- 0.85301E-19 -19.0690 0.71223E-19 -19.1474 0.83496E+00 -0.0783 48 FeCl+ 0.61394E-17 -17.2119 0.51360E-17 -17.2894 0.83657E+00 -0.0775 51 FeF+ 0.92981E-18 -18.0316 0.77785E-18 -18.1091 0.83657E+00 -0.0775 53 FeO,aq 0.16047E-09 -9.7946 0.16047E-09 -9.7946 0.10000E+01 0.0000 54 FeOH+ 0.12229E-10 -10.9126 0.10231E-10 -10.9901 0.83657E+00 -0.0775 55 HFeO2- 0.26419E-07 -7.5781 0.22059E-07 -7.6564 0.83496E+00 -0.0783 56 FeO+ 0.17362E-16 -16.7604 0.14524E-16 -16.8379 0.83657E+00 -0.0775 58 FeO2- 0.61432E-09 -9.2116 0.51293E-09 -9.2899 0.83496E+00 -0.0783 59 HFeO2,aq 0.49657E-11 -11.3040 0.49657E-11 -11.3040 0.10000E+01 0.0000 60 H2,aq 0.28326E-05 -5.5478 0.28227E-05 -5.5493 0.99652E+00 -0.0015 61 KCl,aq 0.32182E-09 -9.4924 0.32182E-09 -9.4924 0.10000E+01 0.0000 63 KOH,aq 0.73448E-06 -6.1340 0.73448E-06 -6.1340 0.10000E+01 0.0000 64 KSO4- 0.60421E-12 -12.2188 0.50449E-12 -12.2971 0.83496E+00 -0.0783 65 MgCO3,aq 0.14322E-11 -11.8440 0.14322E-11 -11.8440 0.10000E+01 0.0000 66 Mg(HCO3)+ 0.12381E-13 -13.9072 0.10358E-13 -13.9847 0.83657E+00 -0.0775 67 MgCl+ 0.25845E-14 -14.5876 0.21621E-14 -14.6651 0.83657E+00 -0.0775 68 MgF+ 0.44705E-15 -15.3496 0.37399E-15 -15.4271 0.83657E+00 -0.0775 69 MgOH+ 0.67309E-10 -10.1719 0.56308E-10 -10.2494 0.83657E+00 -0.0775 71 MnF+ 0.12819E-15 -15.8922 0.10724E-15 -15.9697 0.83657E+00 -0.0775 72 MnO,aq 0.17885E-08 -8.7475 0.17885E-08 -8.7475 0.10000E+01 0.0000 73 MnOH+ 0.47516E-09 -9.3232 0.39750E-09 -9.4007 0.83657E+00 -0.0775 74 MnO2-2 0.19790E-10 -10.7035 0.10244E-10 -10.9895 0.51763E+00 -0.2860 75 HMnO2- 0.20460E-09 -9.6891 0.17083E-09 -9.7674 0.83496E+00 -0.0783 78 MnCl+ 0.99901E-14 -14.0004 0.83574E-14 -14.0779 0.83657E+00 -0.0775 79 MnSO4,aq 0.71738E-18 -18.1443 0.71738E-18 -18.1443 0.10000E+01 0.0000 80 NaCl,aq 0.74544E-06 -6.1276 0.74544E-06 -6.1276 0.10000E+01 0.0000 81 NaF,aq 0.24704E-08 -8.6072 0.24704E-08 -8.6072 0.10000E+01 0.0000 82 NaOH,aq 0.93607E-04 -4.0287 0.93607E-04 -4.0287 0.10000E+01 0.0000 84 OH- 0.91072E-02 -2.0406 0.75905E-02 -2.1197 0.83345E+00 -0.0791 89 HPO3-2 0.39972E-15 -15.3982 0.20691E-15 -15.6842 0.51763E+00 -0.2860 91 H2PO3- 0.37825E-19 -19.4222 0.31583E-19 -19.5006 0.83496E+00 -0.0783 92 H3PO4,aq 0.95318E-18 -18.0208 0.95318E-18 -18.0208 0.10000E+01 0.0000 93 H2PO4- 0.39520E-10 -10.4032 0.33029E-10 -10.4811 0.83576E+00 -0.0779 94 PO4-3 0.10415E-08 -8.9823 0.25212E-09 -9.5984 0.24208E+00 -0.6160 98 HP2O7-3 0.97272E-18 -18.0120 0.22439E-18 -18.6490 0.23068E+00 -0.6370 99 P2O7-4 0.91734E-17 -17.0375 0.70423E-18 -18.1523 0.76769E-01 -1.1148 100 H2S,aq 0.13437E-07 -7.8717 0.13390E-07 -7.8732 0.99652E+00 -0.0015 101 S2-2 0.49132E-13 -13.3086 0.25432E-13 -13.5946 0.51763E+00 -0.2860 107 SO3-2 0.17346E-15 -15.7608 0.91093E-16 -16.0405 0.52514E+00 -0.2797 108 HSO3- 0.51996E-18 -18.2840 0.43415E-18 -18.3624 0.83496E+00 -0.0783 109 HSO4- 0.21755E-16 -16.6624 0.18217E-16 -16.7395 0.83739E+00 -0.0771 111 S2O3-2 0.75465E-19 -19.1223 0.39063E-19 -19.4082 0.51763E+00 -0.2860 Charge balance for all species = -.6133E-08 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.9061365E-10 -.2212152E-01 -.2225830E+02 0.0000 2 H2O 0.1000000E+01 0.5550465E+02 0.9981902E+06 0.0000 3 Cl- 0.1624437E-03 0.1631895E-03 0.5775473E+01 6.2509 4 SO4-- 0.4787422E-09 -.8870959E-05 -.8506732E+00 10.6321 5 HCO3- 0.4369653E-04 0.1328958E-03 0.8094794E+01 5.6813 6 HS- 0.6815983E-04 0.7704470E-04 0.2543582E+01 5.8738 7 Al+++ 0.1001953E-28 0.4949280E-05 0.1333063E+00 0.7190 8 H4SiO4 0.7128444E-03 0.1353111E-01 0.1298281E+04 -3.1470 9 Ca++ 0.1096446E-06 0.2160321E-06 0.8643044E-02 12.9887 10 Mg++ 0.2120420E-10 0.9318022E-10 0.2261449E-05 9.2732 11 Fe++ 0.4662379E-13 0.2721067E-07 0.1516986E-02 6.6158 12 K+ 0.1565223E-03 0.1572571E-03 0.6138348E+01 6.2355 13 Na+ 0.1986537E-01 0.2230517E-01 0.5118976E+03 8.3382 14 Mn++ 0.1948457E-10 0.2507504E-08 0.1375172E-03 9.2373 15 F- 0.7636075E-06 0.7660788E-06 0.1452860E-01 3.9221 16 HPO4-- 0.4533822E-07 0.4641925E-07 0.4447508E-02 12.6085 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.1986826E-01 -.1986689E-01 -.1364217E-05 0.0000000E+00 2 H2O 0.4984761E+02 0.4984761E+02 -.1321191E-05 0.0000000E+00 3 Cl- 0.1465572E-03 0.1465572E-03 0.0000000E+00 0.0000000E+00 4 SO4-- -.7965810E-05 -.7966829E-05 0.1019364E-08 0.0000000E+00 5 HCO3- 0.1193510E-03 0.1193510E-03 0.0000000E+00 0.0000000E+00 6 HS- 0.6919128E-04 0.6919230E-04 -.1019364E-08 0.0000000E+00 7 Al+++ 0.4775352E-05 0.4444849E-05 0.3305031E-06 0.0000000E+00 8 H4SiO4 0.1215302E-01 0.1215202E-01 0.1001905E-05 0.0000000E+00 9 Ca++ 0.2080835E-06 0.1940141E-06 0.1406941E-07 0.0000000E+00 10 Mg++ 0.8368328E-10 0.8368328E-10 0.0000000E+00 0.0000000E+00 11 Fe++ 0.3259227E-07 0.2443736E-07 0.8154911E-08 0.0000000E+00 12 K+ 0.1412294E-03 0.1412294E-03 0.0000000E+00 0.0000000E+00 13 Na+ 0.2003215E-01 0.2003182E-01 0.3292784E-06 0.0000000E+00 14 Mn++ 0.2251939E-08 0.2251939E-08 0.0000000E+00 0.0000000E+00 15 F- 0.6880000E-06 0.6880000E-06 0.0000000E+00 0.0000000E+00 16 HPO4-- 0.4168819E-07 0.4168819E-07 0.0000000E+00 0.0000000E+00 Chg. balance for solid moles: -.5294E-22 Mass of aqueous solution: 0.899648E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 0.0014700 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 0.3293E-06 -6.482 0.8634E-04 -4.064 97.35 0.3315E-04 andradite 0.4077E-08 -8.390 0.2072E-05 -5.684 2.336 0.5383E-06 grossular 0.6123E-09 -9.213 0.2758E-06 -6.559 0.3110 0.7675E-07 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8694E+00 0.8694E+00 1.0000 -0.061 grossular 0.1306E+00 0.1306E+00 1.0000 -0.884 Solid products produced: Mass = 0.000089 g Volume = 0.000034 cm3 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.0014700 moles log = -2.8327 Original solution: 1000.0103000 g Original solution / Rock added: 680279.12 (Water/Rock Ratio), log = 5.8327 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0360 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9850E+00 0.9857 0.1006E+01 0.1021E+01 CO2,gas 0.6095E-06 1.0070 0.6358E-06 0.6314E-06 CH4,gas 0.1142E-01 1.0124 0.1197E-01 0.1183E-01 H2,gas 0.3575E-02 1.0006 0.3706E-02 0.3704E-02 H2S,gas 0.3567E-06 0.9960 0.3681E-06 0.3696E-06 S2,gas 0.3574E-27 1.0000 0.3703E-27 0.3703E-27 CO,gas 0.6061E-12 1.0000 0.6280E-12 0.6280E-12 SO3,gas 0.5251E-45 1.0000 0.5440E-45 0.5440E-45 SO2,gas 0.7571E-25 1.0000 0.7844E-25 0.7844E-25 HF,gas 0.7857E-15 1.0000 0.8141E-15 0.8141E-15 HCl,gas 0.3222E-17 1.0000 0.3338E-17 0.3338E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 17 albite -0.38 -0.38 0.00 0.000 -0.94784E-12 23 andradite 39.01 39.01 0.00 0.000 -0.12132E-10 24 grossular 32.73 32.73 0.00 0.000 0.00000E+00 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -14.56 -7.90 -2.632 0.13482E+05 -6.197 3 CH4,gas 4.54 0.92 -3.62 -0.905 0.61823E+04 -1.922 4 H2,gas 8.00 3.87 -4.13 -2.360 0.70520E+04 -2.431 5 H2S,gas -6.23 -14.36 -8.13 -4.067 0.13887E+05 -6.434 6 S2,gas -7.34 -36.47 -29.13 -4.482 0.49739E+05 -27.431 7 CO,gas 3.21 -10.69 -13.90 -4.277 0.23736E+05 -12.202 8 SO3,gas 17.12 -29.84 -46.96 -11.741 0.80189E+05 -45.264 9 SO2,gas 0.83 -25.97 -26.80 -7.148 0.45768E+05 -25.105 10 HF,gas 0.47 -16.31 -16.79 -8.394 0.28666E+05 -15.089 11 HCl,gas 5.19 -13.99 -19.18 -9.588 0.32742E+05 -17.476 12 acmite 7.71 6.73 -0.98 -0.102 0.16810E+04 16 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 20 spessartine 24.46 19.71 -4.75 -0.237 0.81081E+04 21 analcite 3.32 2.76 -0.56 -0.062 0.95400E+03 27 annite 20.12 17.36 -2.76 -0.153 0.47168E+04 28 phlogopite 27.06 25.33 -1.73 -0.096 0.29567E+04 30 anorthite 12.71 8.13 -4.58 -0.352 0.78163E+04 33 apatite-OH -18.15 -18.65 -0.50 -0.038 0.85279E+03 34 apatite-F -34.30 -34.97 -0.67 -0.056 0.11386E+04 38 aragonite 0.97 -1.57 -2.53 -0.845 0.43259E+04 39 brucite 12.57 9.27 -3.30 -0.659 0.56268E+04 40 calcite 0.81 -1.57 -2.38 -0.793 0.40617E+04 41 carnegieite-low 9.02 5.91 -3.11 -0.445 0.53156E+04 42 carnegieite-high 10.09 5.91 -4.18 -0.598 0.71426E+04 43 carpholite-Mg 8.58 4.42 -4.17 -0.278 0.71116E+04 44 carpholite-Fe 6.71 1.76 -4.95 -0.330 0.84569E+04 45 celadonite 5.34 3.64 -1.70 -0.100 0.29061E+04 46 celadonite-Fe 3.88 0.98 -2.89 -0.170 0.49419E+04 47 chrysotile 23.89 21.53 -2.37 -0.197 0.40414E+04 49 clinochlore 39.07 38.36 -0.71 -0.022 0.12067E+04 50 daphnite 28.97 25.08 -3.89 -0.122 0.66406E+04 52 chlorite-Al-free 47.17 43.05 -4.12 -0.172 0.70379E+04 54 chloritoid-Fe 9.17 4.91 -4.27 -0.284 0.72856E+04 55 chloritoid-Mn 11.40 7.53 -3.87 -0.258 0.66128E+04 57 coesite -2.38 -3.15 -0.77 -0.257 0.13164E+04 64 cristobalite -2.56 -3.15 -0.59 -0.196 0.10017E+04 66 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71235E+04 68 diaspore 2.87 0.72 -2.15 -0.359 0.36792E+04 69 diamond -3.10 -6.82 -3.71 -1.061 0.63416E+04 70 diopside 16.18 15.97 -0.21 -0.021 0.36445E+03 71 hedenbergite 14.21 13.31 -0.90 -0.090 0.15328E+04 76 clinoenstatite 17.17 12.25 -4.91 -0.491 0.83904E+04 78 epidote 24.67 22.66 -2.01 -0.098 0.34398E+04 79 clinozoisite 22.81 18.69 -4.11 -0.187 0.70223E+04 80 epidote-Fe 29.84 26.62 -3.22 -0.167 0.55038E+04 81 fayalite 14.05 10.08 -3.96 -0.566 0.67634E+04 82 ferrosilite 11.15 6.94 -4.21 -0.421 0.71915E+04 86 gibbsite 4.08 0.72 -3.36 -0.480 0.57377E+04 87 glaucophane 22.97 20.76 -2.22 -0.060 0.37855E+04 88 glaucophane-Fe 17.28 12.79 -4.49 -0.121 0.76666E+04 89 graphite -3.55 -6.82 -3.27 -0.934 0.55838E+04 90 greenalite 16.14 13.55 -2.59 -0.215 0.44155E+04 93 hematite 12.57 9.36 -3.20 -0.388 0.54710E+04 94 heulandite -5.83 -7.60 -1.78 -0.081 0.30310E+04 98 jadeite 4.22 2.76 -1.45 -0.145 0.24795E+04 100 kalsilite 7.58 3.81 -3.78 -0.539 0.64482E+04 101 kaolinite -1.33 -4.86 -3.52 -0.320 0.60160E+04 104 laumontite 2.88 1.84 -1.04 -0.070 0.17839E+04 105 lawsonite 9.62 8.13 -1.48 -0.099 0.25329E+04 106 leucite 4.12 0.66 -3.46 -0.346 0.59052E+04 108 lizardite 23.24 21.53 -1.72 -0.143 0.29340E+04 110 magnetite 20.09 15.98 -4.11 -0.335 0.70169E+04 111 minnesotaite 10.39 7.26 -3.13 -0.184 0.53420E+04 115 manganosite 14.06 9.24 -4.82 -1.205 0.82314E+04 119 microcline -2.49 -2.49 0.00 0.000 0.12552E+00 123 muscovite 2.58 -1.05 -3.63 -0.214 0.62000E+04 124 paragonite 4.24 1.05 -3.19 -0.187 0.54390E+04 125 nepheline 8.34 5.91 -2.43 -0.347 0.41480E+04 137 phlogopite-Na 29.65 27.44 -2.21 -0.123 0.37754E+04 139 prehnite 19.37 17.97 -1.40 -0.082 0.23862E+04 140 prehnite-Fe 22.50 21.94 -0.56 -0.034 0.95864E+03 141 pumpellyite-Fe 46.27 43.28 -2.99 -0.066 0.50983E+04 142 pumpellyite-Mg 48.99 45.94 -3.05 -0.068 0.52146E+04 145 pyrite -21.25 -25.98 -4.73 -1.114 0.80822E+04 146 pyrrhotite -4.26 -7.75 -3.49 -1.162 0.59541E+04 147 pyrrhotiteFe0.875 -6.02 -9.05 -3.04 -1.117 0.51861E+04 148 pyroxmangite 7.40 6.09 -1.31 -0.262 0.22341E+04 149 pyrophyllite -6.18 -11.15 -4.97 -0.311 0.84935E+04 150 quartz -2.99 -3.15 -0.16 -0.053 0.26905E+03 154 rhodochrosite -0.98 -5.32 -4.34 -1.447 0.74141E+04 155 rhodonite 7.45 6.09 -1.36 -0.271 0.23143E+04 156 sanidine -1.28 -2.49 -1.21 -0.093 0.20679E+04 166 stilbite -7.52 -7.60 -0.08 -0.004 0.13717E+03 167 stilpnomelane-Fe 13.02 12.46 -0.56 -0.017 0.95302E+03 168 stilpnomelane-Mg 27.44 25.75 -1.70 -0.051 0.28957E+04 174 talc 16.49 15.23 -1.26 -0.074 0.21506E+04 177 tephroite 18.09 15.33 -2.76 -0.394 0.47096E+04 181 tridymite -2.63 -3.15 -0.52 -0.174 0.88902E+03 182 tremolite 47.87 47.17 -0.70 -0.019 0.11985E+04 183 ferroactinolite 38.45 33.88 -4.57 -0.124 0.78061E+04 184 troilite-low -4.41 -7.75 -3.34 -1.112 0.56969E+04 190 wairakite 3.95 1.84 -2.11 -0.124 0.36059E+04 191 walstromite 11.51 9.84 -1.67 -0.333 0.28472E+04 192 wollastonite 10.46 9.84 -0.62 -0.124 0.10576E+04 193 pseudo-wollastonite 11.00 9.84 -1.16 -0.232 0.19775E+04 194 zoisite 22.85 18.69 -4.16 -0.189 0.70964E+04 195 akaganeite 7.75 4.68 -3.07 -0.665 0.52481E+04 202 chalcedony -2.80 -3.15 -0.34 -0.115 0.58834E+03 204 montmorillonite-Ca -2.29 -6.18 -3.89 -0.241 0.66478E+04 205 montmorillonite-K -2.24 -6.27 -4.03 -0.247 0.68859E+04 206 montmorillonite-Mg -2.48 -6.80 -4.32 -0.267 0.73716E+04 207 montmorillonite-Na -2.04 -5.58 -3.54 -0.217 0.60407E+04 208 nontronite-Ca 3.21 0.19 -3.02 -0.196 0.51594E+04 209 nontronite-H 2.53 -1.95 -4.48 -0.300 0.76545E+04 210 nontronite-K 3.34 0.11 -3.23 -0.208 0.55207E+04 211 nontronite-Mg 3.07 -0.42 -3.49 -0.227 0.59673E+04 212 nontronite-Na 3.52 0.80 -2.72 -0.174 0.46415E+04 228 tobermorite 9.82 7.67 -2.15 -0.587 0.36718E+04 234 alabandite -0.98 -5.13 -4.15 -1.383 0.70828E+04 237 boehmite 4.41 0.72 -3.69 -0.615 0.62961E+04 239 ferrous-oxide 9.81 6.62 -3.20 -0.799 0.54566E+04 245 silica-amorphous -2.09 -3.15 -1.06 -0.352 0.18025E+04 247 an20ab80 2.02 1.32 -0.70 -0.054 0.11924E+04 248 an25ab75 2.65 1.75 -0.90 -0.069 0.15375E+04 249 an30ab70 3.28 2.17 -1.11 -0.085 0.18922E+04 250 tr.625ac.25prg.125 45.16 44.79 -0.38 -0.010 0.64813E+03 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 0.0000400 MOLES Current total amount of reactant added: 0.0014700 MOLES New total amount of reactant added: 0.0015100 MOLES Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.5508E-08 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 7 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 0.0015100 Water: Moles liquid = 0.4985E+02 kg liquid = 0.8981E+00 Moles total = 0.4985E+02 kg total = 0.8980E+00 Activity = 1.0000 Stoichiometric ionic strength = .1142657E-01 Osmotic coef. = 0.9649 True ionic strength = .2010570E-01 Chg. balance for total moles = -.5508E-08 Max. difference allowed = 0.1468E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.90679E-10 -10.0425 0.76173E-10 -10.1182 0.84003E+00 -0.0757 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.16271E-03 -3.7886 0.13585E-03 -3.8669 0.83496E+00 -0.0783 4 SO4-- 0.51269E-09 -9.2901 0.26594E-09 -9.5752 0.51872E+00 -0.2851 5 HCO3- 0.44916E-04 -4.3476 0.37558E-04 -4.4253 0.83618E+00 -0.0777 6 HS- 0.69242E-04 -4.1596 0.57823E-04 -4.2379 0.83508E+00 -0.0783 7 Al+++ 0.10029E-28 -28.9988 0.23110E-29 -29.6362 0.23043E+00 -0.6375 8 H4SiO4 0.71332E-03 -3.1467 0.71332E-03 -3.1467 0.10000E+01 0.0000 9 Ca++ 0.10927E-06 -6.9615 0.56265E-07 -7.2498 0.51490E+00 -0.2883 10 Mg++ 0.21207E-10 -10.6735 0.10869E-10 -10.9638 0.51254E+00 -0.2903 11 Fe++ 0.46726E-13 -13.3304 0.23975E-13 -13.6202 0.51310E+00 -0.2898 12 K+ 0.15652E-03 -3.8054 0.13091E-03 -3.8830 0.83638E+00 -0.0776 13 Na+ 0.19866E-01 -1.7019 0.16584E-01 -1.7803 0.83481E+00 -0.0784 14 Mn++ 0.19511E-10 -10.7097 0.10020E-10 -10.9991 0.51353E+00 -0.2894 15 F- 0.78137E-06 -6.1071 0.65106E-06 -6.1864 0.83323E+00 -0.0792 16 HPO4-- 0.45339E-07 -7.3435 0.23521E-07 -7.6285 0.51879E+00 -0.2850 18 HSiO3- 0.10472E-01 -1.9800 0.87440E-02 -2.0583 0.83496E+00 -0.0783 19 Ca(HSiO3)+ 0.13393E-07 -7.8731 0.11204E-07 -7.9506 0.83656E+00 -0.0775 20 Mg(HSiO3)+ 0.32199E-11 -11.4922 0.26936E-11 -11.5697 0.83656E+00 -0.0775 21 NaHSiO3,aq 0.23453E-02 -2.6298 0.23453E-02 -2.6298 0.10000E+01 0.0000 22 AlO+ 0.64769E-16 -16.1886 0.54184E-16 -16.2661 0.83656E+00 -0.0775 24 HAlO2,aq 0.14166E-09 -9.8488 0.14166E-09 -9.8488 0.10000E+01 0.0000 25 AlO2- 0.49393E-05 -5.3063 0.41166E-05 -5.3855 0.83345E+00 -0.0791 26 CH4,aq 0.79601E-05 -5.0991 0.79324E-05 -5.1006 0.99652E+00 -0.0015 27 C2H6,aq 0.38757E-14 -14.4117 0.38622E-14 -14.4132 0.99652E+00 -0.0015 31 CO,aq 0.42771E-15 -15.3688 0.42771E-15 -15.3688 0.10000E+01 0.0000 32 CO2,aq 0.61344E-08 -8.2122 0.61131E-08 -8.2137 0.99652E+00 -0.0015 33 CO3-2 0.83203E-04 -4.0799 0.43067E-04 -4.3659 0.51761E+00 -0.2860 34 CaCO3,aq 0.30384E-07 -7.5174 0.30384E-07 -7.5174 0.10000E+01 0.0000 35 Ca(HCO3)+ 0.64480E-10 -10.1906 0.53941E-10 -10.2681 0.83656E+00 -0.0775 36 CaCl+ 0.14787E-10 -10.8301 0.12370E-10 -10.9076 0.83656E+00 -0.0775 37 CaCl2,aq 0.39924E-15 -15.3988 0.39924E-15 -15.3988 0.10000E+01 0.0000 38 CaF+ 0.63931E-12 -12.1943 0.53482E-12 -12.2718 0.83656E+00 -0.0775 39 CaOH+ 0.62928E-07 -7.2012 0.52643E-07 -7.2787 0.83656E+00 -0.0775 40 CaSO4,aq 0.47515E-14 -14.3232 0.47515E-14 -14.3232 0.10000E+01 0.0000 41 HCl,aq 0.18963E-14 -14.7221 0.18963E-14 -14.7221 0.10000E+01 0.0000 45 HF,aq 0.33950E-12 -12.4692 0.33950E-12 -12.4692 0.10000E+01 0.0000 46 HF2- 0.89377E-19 -19.0488 0.74626E-19 -19.1271 0.83496E+00 -0.0783 48 FeCl+ 0.61625E-17 -17.2102 0.51553E-17 -17.2877 0.83656E+00 -0.0775 51 FeF+ 0.95348E-18 -18.0207 0.79765E-18 -18.0982 0.83656E+00 -0.0775 53 FeO,aq 0.16059E-09 -9.7943 0.16059E-09 -9.7943 0.10000E+01 0.0000 54 FeOH+ 0.12247E-10 -10.9120 0.10245E-10 -10.9895 0.83656E+00 -0.0775 55 HFeO2- 0.26419E-07 -7.5781 0.22059E-07 -7.6564 0.83496E+00 -0.0783 56 FeO+ 0.17503E-16 -16.7569 0.14643E-16 -16.8344 0.83656E+00 -0.0775 58 FeO2- 0.61844E-09 -9.2087 0.51638E-09 -9.2870 0.83496E+00 -0.0783 59 HFeO2,aq 0.50027E-11 -11.3008 0.50027E-11 -11.3008 0.10000E+01 0.0000 60 H2,aq 0.27950E-05 -5.5536 0.27852E-05 -5.5551 0.99652E+00 -0.0015 61 KCl,aq 0.32234E-09 -9.4917 0.32234E-09 -9.4917 0.10000E+01 0.0000 63 KOH,aq 0.73395E-06 -6.1343 0.73395E-06 -6.1343 0.10000E+01 0.0000 64 KSO4- 0.64703E-12 -12.1891 0.54025E-12 -12.2674 0.83496E+00 -0.0783 65 MgCO3,aq 0.14712E-11 -11.8323 0.14712E-11 -11.8323 0.10000E+01 0.0000 66 Mg(HCO3)+ 0.12728E-13 -13.8952 0.10648E-13 -13.9727 0.83656E+00 -0.0775 67 MgCl+ 0.25889E-14 -14.5869 0.21658E-14 -14.6644 0.83656E+00 -0.0775 68 MgF+ 0.45749E-15 -15.3396 0.38272E-15 -15.4171 0.83656E+00 -0.0775 69 MgOH+ 0.67267E-10 -10.1722 0.56273E-10 -10.2497 0.83656E+00 -0.0775 71 MnF+ 0.13134E-15 -15.8816 0.10988E-15 -15.9591 0.83656E+00 -0.0775 72 MnO,aq 0.17883E-08 -8.7476 0.17883E-08 -8.7476 0.10000E+01 0.0000 73 MnOH+ 0.47546E-09 -9.3229 0.39776E-09 -9.4004 0.83656E+00 -0.0775 74 MnO2-2 0.19761E-10 -10.7042 0.10229E-10 -10.9902 0.51761E+00 -0.2860 75 HMnO2- 0.20444E-09 -9.6894 0.17070E-09 -9.7678 0.83496E+00 -0.0783 78 MnCl+ 0.10020E-13 -13.9991 0.83821E-14 -14.0766 0.83656E+00 -0.0775 79 MnSO4,aq 0.76926E-18 -18.1139 0.76926E-18 -18.1139 0.10000E+01 0.0000 80 NaCl,aq 0.74663E-06 -6.1269 0.74663E-06 -6.1269 0.10000E+01 0.0000 81 NaF,aq 0.25278E-08 -8.5973 0.25278E-08 -8.5973 0.10000E+01 0.0000 82 NaOH,aq 0.93540E-04 -4.0290 0.93540E-04 -4.0290 0.10000E+01 0.0000 84 OH- 0.91008E-02 -2.0409 0.75850E-02 -2.1200 0.83345E+00 -0.0791 89 HPO3-2 0.39442E-15 -15.4040 0.20416E-15 -15.6900 0.51761E+00 -0.2860 91 H2PO3- 0.37350E-19 -19.4277 0.31185E-19 -19.5061 0.83496E+00 -0.0783 92 H3PO4,aq 0.95452E-18 -18.0202 0.95452E-18 -18.0202 0.10000E+01 0.0000 93 H2PO4- 0.39548E-10 -10.4029 0.33052E-10 -10.4808 0.83575E+00 -0.0779 94 PO4-3 0.10408E-08 -8.9826 0.25194E-09 -9.5987 0.24206E+00 -0.6161 98 HP2O7-3 0.97345E-18 -18.0117 0.22454E-18 -18.6487 0.23066E+00 -0.6370 99 P2O7-4 0.91742E-17 -17.0374 0.70421E-18 -18.1523 0.76760E-01 -1.1149 100 H2S,aq 0.13660E-07 -7.8645 0.13613E-07 -7.8661 0.99652E+00 -0.0015 101 S2-2 0.51388E-13 -13.2891 0.26599E-13 -13.5751 0.51761E+00 -0.2860 107 SO3-2 0.18330E-15 -15.7368 0.96254E-16 -16.0166 0.52513E+00 -0.2797 108 HSO3- 0.54981E-18 -18.2598 0.45907E-18 -18.3381 0.83496E+00 -0.0783 109 HSO4- 0.23314E-16 -16.6324 0.19522E-16 -16.7095 0.83738E+00 -0.0771 111 S2O3-2 0.82156E-19 -19.0854 0.42525E-19 -19.3714 0.51761E+00 -0.2860 Charge balance for all species = -.6133E-08 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.9067897E-10 -.2211667E-01 -.2225342E+02 0.0000 2 H2O 0.1000000E+01 0.5550465E+02 0.9981900E+06 0.0000 3 Cl- 0.1627052E-03 0.1634521E-03 0.5784768E+01 6.2513 4 SO4-- 0.5126872E-09 -.8658275E-05 -.8302780E+00 10.6612 5 HCO3- 0.4491598E-04 0.1361158E-03 0.8290931E+01 5.6929 6 HS- 0.6924183E-04 0.7791428E-04 0.2572290E+01 5.8803 7 Al+++ 0.1002879E-28 0.4939427E-05 0.1330409E+00 0.7184 8 H4SiO4 0.7133200E-03 0.1353107E-01 0.1298277E+04 -3.1467 9 Ca++ 0.1092734E-06 0.2160579E-06 0.8644074E-02 12.9866 10 Mg++ 0.2120660E-10 0.9318015E-10 0.2261447E-05 9.2726 11 Fe++ 0.4672561E-13 0.2721543E-07 0.1517251E-02 6.6162 12 K+ 0.1565227E-03 0.1572569E-03 0.6138343E+01 6.2352 13 Na+ 0.1986552E-01 0.2230514E-01 0.5118969E+03 8.3379 14 Mn++ 0.1951144E-10 0.2507502E-08 0.1375170E-03 9.2373 15 F- 0.7813653E-06 0.7838940E-06 0.1486646E-01 3.9318 16 HPO4-- 0.4533885E-07 0.4641921E-07 0.4447504E-02 12.6079 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.1986395E-01 -.1986255E-01 -.1399554E-05 0.0000000E+00 2 H2O 0.4984764E+02 0.4984765E+02 -.1356615E-05 0.0000000E+00 3 Cl- 0.1467932E-03 0.1467932E-03 0.0000000E+00 0.0000000E+00 4 SO4-- -.7774810E-05 -.7775829E-05 0.1018827E-08 0.0000000E+00 5 HCO3- 0.1222430E-03 0.1222430E-03 0.0000000E+00 0.0000000E+00 6 HS- 0.6997228E-04 0.6997330E-04 -.1018827E-08 0.0000000E+00 7 Al+++ 0.4775352E-05 0.4436004E-05 0.3393483E-06 0.0000000E+00 8 H4SiO4 0.1215302E-01 0.1215199E-01 0.1028451E-05 0.0000000E+00 9 Ca++ 0.2080835E-06 0.1940374E-06 0.1404612E-07 0.0000000E+00 10 Mg++ 0.8368328E-10 0.8368328E-10 0.0000000E+00 0.0000000E+00 11 Fe++ 0.3259227E-07 0.2444165E-07 0.8150617E-08 0.0000000E+00 12 K+ 0.1412294E-03 0.1412294E-03 0.0000000E+00 0.0000000E+00 13 Na+ 0.2003215E-01 0.2003181E-01 0.3381348E-06 0.0000000E+00 14 Mn++ 0.2251939E-08 0.2251939E-08 0.0000000E+00 0.0000000E+00 15 F- 0.7040000E-06 0.7040000E-06 0.0000000E+00 0.0000000E+00 16 HPO4-- 0.4168819E-07 0.4168819E-07 0.0000000E+00 0.0000000E+00 Chg. balance for solid moles: 0.2647E-21 Mass of aqueous solution: 0.899649E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 0.0015100 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 0.3381E-06 -6.471 0.8867E-04 -4.052 97.42 0.3404E-04 andradite 0.4075E-08 -8.390 0.2071E-05 -5.684 2.276 0.5381E-06 grossular 0.6067E-09 -9.217 0.2733E-06 -6.563 0.3003 0.7604E-07 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8704E+00 0.8704E+00 1.0000 -0.060 grossular 0.1296E+00 0.1296E+00 1.0000 -0.887 Solid products produced: Mass = 0.000091 g Volume = 0.000035 cm3 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.0015100 moles log = -2.8210 Original solution: 1000.0103000 g Original solution / Rock added: 662258.48 (Water/Rock Ratio), log = 5.8210 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0357 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9853E+00 0.9857 0.1006E+01 0.1021E+01 CO2,gas 0.6271E-06 1.0070 0.6540E-06 0.6495E-06 CH4,gas 0.1114E-01 1.0124 0.1168E-01 0.1153E-01 H2,gas 0.3529E-02 1.0006 0.3657E-02 0.3655E-02 H2S,gas 0.3628E-06 0.9960 0.3742E-06 0.3757E-06 S2,gas 0.3795E-27 1.0000 0.3931E-27 0.3931E-27 CO,gas 0.6154E-12 1.0000 0.6374E-12 0.6374E-12 SO3,gas 0.5633E-45 1.0000 0.5834E-45 0.5834E-45 SO2,gas 0.8014E-25 1.0000 0.8300E-25 0.8300E-25 HF,gas 0.8049E-15 1.0000 0.8336E-15 0.8336E-15 HCl,gas 0.3231E-17 1.0000 0.3346E-17 0.3346E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 17 albite -0.38 -0.38 0.00 0.000 -0.13080E-10 23 andradite 39.01 39.01 0.00 0.000 -0.24265E-10 24 grossular 32.73 32.73 0.00 0.000 -0.36397E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -14.54 -7.88 -2.628 0.13461E+05 -6.184 3 CH4,gas 4.54 0.91 -3.63 -0.908 0.62010E+04 -1.933 4 H2,gas 8.00 3.86 -4.14 -2.363 0.70619E+04 -2.437 5 H2S,gas -6.23 -14.36 -8.13 -4.063 0.13875E+05 -6.427 6 S2,gas -7.34 -36.44 -29.10 -4.478 0.49695E+05 -27.406 7 CO,gas 3.21 -10.68 -13.89 -4.275 0.23725E+05 -12.196 8 SO3,gas 17.12 -29.81 -46.93 -11.733 0.80137E+05 -45.234 9 SO2,gas 0.83 -25.95 -26.78 -7.141 0.45726E+05 -25.081 10 HF,gas 0.47 -16.30 -16.78 -8.389 0.28648E+05 -15.079 11 HCl,gas 5.19 -13.99 -19.17 -9.587 0.32740E+05 -17.475 12 acmite 7.71 6.73 -0.98 -0.102 0.16751E+04 16 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 20 spessartine 24.46 19.71 -4.75 -0.237 0.81087E+04 21 analcite 3.32 2.76 -0.56 -0.062 0.95450E+03 27 annite 20.12 17.36 -2.76 -0.153 0.47152E+04 28 phlogopite 27.06 25.33 -1.73 -0.096 0.29597E+04 30 anorthite 12.71 8.13 -4.58 -0.352 0.78208E+04 33 apatite-OH -18.15 -18.66 -0.51 -0.039 0.86763E+03 34 apatite-F -34.30 -34.97 -0.67 -0.055 0.11358E+04 38 aragonite 0.97 -1.56 -2.52 -0.841 0.43086E+04 39 brucite 12.57 9.27 -3.30 -0.659 0.56278E+04 40 calcite 0.81 -1.56 -2.37 -0.790 0.40444E+04 41 carnegieite-low 9.02 5.91 -3.11 -0.445 0.53166E+04 42 carnegieite-high 10.09 5.91 -4.18 -0.598 0.71436E+04 43 carpholite-Mg 8.58 4.42 -4.17 -0.278 0.71136E+04 44 carpholite-Fe 6.71 1.76 -4.95 -0.330 0.84573E+04 45 celadonite 5.34 3.64 -1.70 -0.100 0.29066E+04 46 celadonite-Fe 3.88 0.98 -2.89 -0.170 0.49408E+04 47 chrysotile 23.89 21.52 -2.37 -0.197 0.40434E+04 49 clinochlore 39.07 38.36 -0.71 -0.022 0.12121E+04 50 daphnite 28.97 25.08 -3.89 -0.121 0.66383E+04 52 chlorite-Al-free 47.17 43.05 -4.12 -0.172 0.70419E+04 54 chloritoid-Fe 9.17 4.91 -4.27 -0.284 0.72865E+04 55 chloritoid-Mn 11.40 7.53 -3.87 -0.258 0.66143E+04 57 coesite -2.38 -3.15 -0.77 -0.257 0.13159E+04 64 cristobalite -2.56 -3.15 -0.59 -0.195 0.10012E+04 66 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71235E+04 68 diaspore 2.87 0.72 -2.16 -0.359 0.36801E+04 69 diamond -3.10 -6.82 -3.71 -1.061 0.63404E+04 70 diopside 16.18 15.97 -0.22 -0.022 0.36806E+03 71 hedenbergite 14.21 13.31 -0.90 -0.090 0.15349E+04 76 clinoenstatite 17.17 12.25 -4.91 -0.491 0.83914E+04 78 epidote 24.67 22.65 -2.02 -0.098 0.34419E+04 79 clinozoisite 22.81 18.69 -4.12 -0.187 0.70309E+04 80 epidote-Fe 29.84 26.62 -3.22 -0.167 0.54995E+04 81 fayalite 14.05 10.09 -3.96 -0.566 0.67618E+04 82 ferrosilite 11.15 6.94 -4.21 -0.421 0.71894E+04 86 gibbsite 4.08 0.72 -3.36 -0.480 0.57387E+04 87 glaucophane 22.97 20.76 -2.22 -0.060 0.37875E+04 88 glaucophane-Fe 17.28 12.79 -4.49 -0.121 0.76640E+04 89 graphite -3.55 -6.82 -3.27 -0.934 0.55827E+04 90 greenalite 16.14 13.56 -2.58 -0.215 0.44129E+04 93 hematite 12.57 9.37 -3.20 -0.388 0.54601E+04 94 heulandite -5.83 -7.60 -1.78 -0.081 0.30330E+04 98 jadeite 4.22 2.76 -1.45 -0.145 0.24800E+04 100 kalsilite 7.58 3.81 -3.78 -0.540 0.64492E+04 101 kaolinite -1.33 -4.86 -3.52 -0.320 0.60169E+04 104 laumontite 2.88 1.84 -1.05 -0.070 0.17875E+04 105 lawsonite 9.62 8.13 -1.49 -0.099 0.25374E+04 106 leucite 4.12 0.66 -3.46 -0.346 0.59057E+04 108 lizardite 23.24 21.52 -1.72 -0.143 0.29360E+04 110 magnetite 20.09 15.98 -4.10 -0.335 0.70054E+04 111 minnesotaite 10.39 7.26 -3.13 -0.184 0.53384E+04 115 manganosite 14.06 9.24 -4.82 -1.205 0.82315E+04 119 microcline -2.49 -2.49 0.00 0.000 0.12900E+00 123 muscovite 2.58 -1.05 -3.63 -0.214 0.62019E+04 124 paragonite 4.24 1.05 -3.19 -0.187 0.54409E+04 125 nepheline 8.34 5.91 -2.43 -0.347 0.41490E+04 137 phlogopite-Na 29.65 27.43 -2.21 -0.123 0.37784E+04 139 prehnite 19.37 17.97 -1.40 -0.082 0.23938E+04 140 prehnite-Fe 22.50 21.94 -0.56 -0.034 0.95981E+03 141 pumpellyite-Fe 46.27 43.27 -3.00 -0.067 0.51140E+04 142 pumpellyite-Mg 48.99 45.93 -3.06 -0.068 0.52318E+04 145 pyrite -21.25 -25.96 -4.71 -1.109 0.80473E+04 146 pyrrhotite -4.26 -7.74 -3.48 -1.160 0.59414E+04 147 pyrrhotiteFe0.875 -6.02 -9.05 -3.03 -1.114 0.51722E+04 148 pyroxmangite 7.40 6.09 -1.31 -0.262 0.22336E+04 149 pyrophyllite -6.18 -11.15 -4.97 -0.311 0.84934E+04 150 quartz -2.99 -3.15 -0.16 -0.052 0.26855E+03 154 rhodochrosite -0.98 -5.31 -4.33 -1.443 0.73932E+04 155 rhodonite 7.45 6.09 -1.36 -0.271 0.23139E+04 156 sanidine -1.28 -2.49 -1.21 -0.093 0.20679E+04 166 stilbite -7.52 -7.60 -0.08 -0.004 0.13922E+03 167 stilpnomelane-Fe 13.02 12.46 -0.56 -0.017 0.94855E+03 168 stilpnomelane-Mg 27.44 25.74 -1.70 -0.051 0.28989E+04 174 talc 16.49 15.23 -1.26 -0.074 0.21517E+04 177 tephroite 18.09 15.33 -2.76 -0.394 0.47092E+04 181 tridymite -2.63 -3.15 -0.52 -0.173 0.88853E+03 182 tremolite 47.87 47.16 -0.71 -0.019 0.12067E+04 183 ferroactinolite 38.45 33.88 -4.57 -0.124 0.78066E+04 184 troilite-low -4.41 -7.74 -3.33 -1.110 0.56842E+04 190 wairakite 3.95 1.84 -2.11 -0.124 0.36094E+04 191 walstromite 11.51 9.84 -1.67 -0.334 0.28503E+04 192 wollastonite 10.46 9.84 -0.62 -0.124 0.10607E+04 193 pseudo-wollastonite 11.00 9.84 -1.16 -0.232 0.19806E+04 194 zoisite 22.85 18.69 -4.16 -0.189 0.71050E+04 195 akaganeite 7.75 4.68 -3.07 -0.664 0.52426E+04 202 chalcedony -2.80 -3.15 -0.34 -0.115 0.58785E+03 204 montmorillonite-Ca -2.29 -6.18 -3.89 -0.241 0.66483E+04 205 montmorillonite-K -2.24 -6.27 -4.03 -0.247 0.68860E+04 206 montmorillonite-Mg -2.48 -6.80 -4.32 -0.267 0.73717E+04 207 montmorillonite-Na -2.04 -5.58 -3.54 -0.217 0.60408E+04 208 nontronite-Ca 3.21 0.20 -3.01 -0.196 0.51475E+04 209 nontronite-H 2.53 -1.94 -4.48 -0.300 0.76420E+04 210 nontronite-K 3.34 0.11 -3.23 -0.207 0.55084E+04 211 nontronite-Mg 3.07 -0.41 -3.49 -0.226 0.59550E+04 212 nontronite-Na 3.52 0.81 -2.71 -0.174 0.46292E+04 228 tobermorite 9.82 7.67 -2.15 -0.587 0.36743E+04 234 alabandite -0.98 -5.12 -4.14 -1.380 0.70706E+04 237 boehmite 4.41 0.72 -3.69 -0.615 0.62970E+04 239 ferrous-oxide 9.81 6.62 -3.20 -0.799 0.54561E+04 245 silica-amorphous -2.09 -3.15 -1.06 -0.352 0.18020E+04 247 an20ab80 2.02 1.32 -0.70 -0.054 0.11933E+04 248 an25ab75 2.65 1.74 -0.90 -0.069 0.15386E+04 249 an30ab70 3.28 2.17 -1.11 -0.085 0.18935E+04 250 tr.625ac.25prg.125 45.16 44.78 -0.38 -0.010 0.65485E+03 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 0.0000400 MOLES Current total amount of reactant added: 0.0015100 MOLES New total amount of reactant added: 0.0015500 MOLES Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.5508E-08 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 7 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 0.0015500 Water: Moles liquid = 0.4985E+02 kg liquid = 0.8981E+00 Moles total = 0.4985E+02 kg total = 0.8980E+00 Activity = 1.0000 Stoichiometric ionic strength = .1142912E-01 Osmotic coef. = 0.9648 True ionic strength = .2010805E-01 Chg. balance for total moles = -.5508E-08 Max. difference allowed = 0.1470E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.90744E-10 -10.0422 0.76227E-10 -10.1179 0.84002E+00 -0.0757 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.16297E-03 -3.7879 0.13607E-03 -3.8662 0.83495E+00 -0.0783 4 SO4-- 0.54888E-09 -9.2605 0.28471E-09 -9.5456 0.51870E+00 -0.2851 5 HCO3- 0.46137E-04 -4.3360 0.38578E-04 -4.4137 0.83618E+00 -0.0777 6 HS- 0.70324E-04 -4.1529 0.58726E-04 -4.2312 0.83507E+00 -0.0783 7 Al+++ 0.10038E-28 -28.9984 0.23129E-29 -29.6358 0.23042E+00 -0.6375 8 H4SiO4 0.71380E-03 -3.1464 0.71380E-03 -3.1464 0.10000E+01 0.0000 9 Ca++ 0.10890E-06 -6.9630 0.56073E-07 -7.2512 0.51488E+00 -0.2883 10 Mg++ 0.21209E-10 -10.6735 0.10870E-10 -10.9638 0.51252E+00 -0.2903 11 Fe++ 0.46827E-13 -13.3295 0.24026E-13 -13.6193 0.51308E+00 -0.2898 12 K+ 0.15652E-03 -3.8054 0.13091E-03 -3.8830 0.83638E+00 -0.0776 13 Na+ 0.19866E-01 -1.7019 0.16584E-01 -1.7803 0.83480E+00 -0.0784 14 Mn++ 0.19538E-10 -10.7091 0.10033E-10 -10.9986 0.51351E+00 -0.2895 15 F- 0.79912E-06 -6.0974 0.66585E-06 -6.1766 0.83323E+00 -0.0792 16 HPO4-- 0.45339E-07 -7.3435 0.23521E-07 -7.6285 0.51878E+00 -0.2850 18 HSiO3- 0.10472E-01 -1.9800 0.87436E-02 -2.0583 0.83495E+00 -0.0783 19 Ca(HSiO3)+ 0.13347E-07 -7.8746 0.11166E-07 -7.9521 0.83656E+00 -0.0775 20 Mg(HSiO3)+ 0.32200E-11 -11.4921 0.26937E-11 -11.5696 0.83656E+00 -0.0775 21 NaHSiO3,aq 0.23452E-02 -2.6298 0.23452E-02 -2.6298 0.10000E+01 0.0000 22 AlO+ 0.64733E-16 -16.1889 0.54153E-16 -16.2664 0.83656E+00 -0.0775 24 HAlO2,aq 0.14148E-09 -9.8493 0.14148E-09 -9.8493 0.10000E+01 0.0000 25 AlO2- 0.49294E-05 -5.3072 0.41084E-05 -5.3863 0.83344E+00 -0.0791 26 CH4,aq 0.77567E-05 -5.1103 0.77297E-05 -5.1118 0.99652E+00 -0.0015 27 C2H6,aq 0.37296E-14 -14.4283 0.37166E-14 -14.4299 0.99652E+00 -0.0015 31 CO,aq 0.43382E-15 -15.3627 0.43382E-15 -15.3627 0.10000E+01 0.0000 32 CO2,aq 0.63056E-08 -8.2003 0.62836E-08 -8.2018 0.99652E+00 -0.0015 33 CO3-2 0.85405E-04 -4.0685 0.44206E-04 -4.3545 0.51760E+00 -0.2860 34 CaCO3,aq 0.31081E-07 -7.5075 0.31081E-07 -7.5075 0.10000E+01 0.0000 35 Ca(HCO3)+ 0.66006E-10 -10.1804 0.55218E-10 -10.2579 0.83656E+00 -0.0775 36 CaCl+ 0.14760E-10 -10.8309 0.12347E-10 -10.9084 0.83656E+00 -0.0775 37 CaCl2,aq 0.39916E-15 -15.3989 0.39916E-15 -15.3989 0.10000E+01 0.0000 38 CaF+ 0.65161E-12 -12.1860 0.54511E-12 -12.2635 0.83656E+00 -0.0775 39 CaOH+ 0.62669E-07 -7.2029 0.52426E-07 -7.2805 0.83656E+00 -0.0775 40 CaSO4,aq 0.50694E-14 -14.2950 0.50694E-14 -14.2950 0.10000E+01 0.0000 41 HCl,aq 0.19007E-14 -14.7211 0.19007E-14 -14.7211 0.10000E+01 0.0000 45 HF,aq 0.34746E-12 -12.4591 0.34746E-12 -12.4591 0.10000E+01 0.0000 46 HF2- 0.93552E-19 -19.0289 0.78112E-19 -19.1073 0.83495E+00 -0.0783 48 FeCl+ 0.61856E-17 -17.2086 0.51746E-17 -17.2861 0.83656E+00 -0.0775 51 FeF+ 0.97723E-18 -18.0100 0.81751E-18 -18.0875 0.83656E+00 -0.0775 53 FeO,aq 0.16070E-09 -9.7940 0.16070E-09 -9.7940 0.10000E+01 0.0000 54 FeOH+ 0.12264E-10 -10.9114 0.10260E-10 -10.9889 0.83656E+00 -0.0775 55 HFeO2- 0.26419E-07 -7.5781 0.22059E-07 -7.6564 0.83495E+00 -0.0783 56 FeO+ 0.17646E-16 -16.7534 0.14761E-16 -16.8309 0.83656E+00 -0.0775 58 FeO2- 0.62258E-09 -9.2058 0.51983E-09 -9.2841 0.83495E+00 -0.0783 59 HFeO2,aq 0.50397E-11 -11.2976 0.50397E-11 -11.2976 0.10000E+01 0.0000 60 H2,aq 0.27579E-05 -5.5594 0.27483E-05 -5.5609 0.99652E+00 -0.0015 61 KCl,aq 0.32285E-09 -9.4910 0.32285E-09 -9.4910 0.10000E+01 0.0000 63 KOH,aq 0.73343E-06 -6.1346 0.73343E-06 -6.1346 0.10000E+01 0.0000 64 KSO4- 0.69269E-12 -12.1595 0.57836E-12 -12.2378 0.83495E+00 -0.0783 65 MgCO3,aq 0.15102E-11 -11.8210 0.15102E-11 -11.8210 0.10000E+01 0.0000 66 Mg(HCO3)+ 0.13075E-13 -13.8836 0.10938E-13 -13.9611 0.83656E+00 -0.0775 67 MgCl+ 0.25933E-14 -14.5861 0.21694E-14 -14.6637 0.83656E+00 -0.0775 68 MgF+ 0.46792E-15 -15.3298 0.39144E-15 -15.4073 0.83656E+00 -0.0775 69 MgOH+ 0.67225E-10 -10.1725 0.56237E-10 -10.2500 0.83656E+00 -0.0775 71 MnF+ 0.13451E-15 -15.8712 0.11252E-15 -15.9488 0.83656E+00 -0.0775 72 MnO,aq 0.17882E-08 -8.7476 0.17882E-08 -8.7476 0.10000E+01 0.0000 73 MnOH+ 0.47577E-09 -9.3226 0.39801E-09 -9.4001 0.83656E+00 -0.0775 74 MnO2-2 0.19732E-10 -10.7048 0.10213E-10 -10.9908 0.51760E+00 -0.2860 75 HMnO2- 0.20428E-09 -9.6898 0.17056E-09 -9.7681 0.83495E+00 -0.0783 78 MnCl+ 0.10049E-13 -13.9979 0.84068E-14 -14.0754 0.83656E+00 -0.0775 79 MnSO4,aq 0.82465E-18 -18.0837 0.82465E-18 -18.0837 0.10000E+01 0.0000 80 NaCl,aq 0.74783E-06 -6.1262 0.74783E-06 -6.1262 0.10000E+01 0.0000 81 NaF,aq 0.25852E-08 -8.5875 0.25852E-08 -8.5875 0.10000E+01 0.0000 82 NaOH,aq 0.93474E-04 -4.0293 0.93474E-04 -4.0293 0.10000E+01 0.0000 84 OH- 0.90944E-02 -2.0412 0.75796E-02 -2.1204 0.83344E+00 -0.0791 89 HPO3-2 0.38920E-15 -15.4098 0.20145E-15 -15.6958 0.51760E+00 -0.2860 91 H2PO3- 0.36880E-19 -19.4332 0.30793E-19 -19.5115 0.83495E+00 -0.0783 92 H3PO4,aq 0.95587E-18 -18.0196 0.95587E-18 -18.0196 0.10000E+01 0.0000 93 H2PO4- 0.39575E-10 -10.4026 0.33075E-10 -10.4805 0.83575E+00 -0.0779 94 PO4-3 0.10401E-08 -8.9829 0.25176E-09 -9.5990 0.24205E+00 -0.6161 98 HP2O7-3 0.97418E-18 -18.0114 0.22469E-18 -18.6484 0.23065E+00 -0.6371 99 P2O7-4 0.91750E-17 -17.0374 0.70419E-18 -18.1523 0.76750E-01 -1.1149 100 H2S,aq 0.13884E-07 -7.8575 0.13835E-07 -7.8590 0.99652E+00 -0.0015 101 S2-2 0.53719E-13 -13.2699 0.27805E-13 -13.5559 0.51760E+00 -0.2860 107 SO3-2 0.19364E-15 -15.7130 0.10168E-15 -15.9928 0.52511E+00 -0.2797 108 HSO3- 0.58122E-18 -18.2357 0.48529E-18 -18.3140 0.83495E+00 -0.0783 109 HSO4- 0.24977E-16 -16.6025 0.20915E-16 -16.6795 0.83737E+00 -0.0771 111 S2O3-2 0.89394E-19 -19.0487 0.46270E-19 -19.3347 0.51760E+00 -0.2860 Charge balance for all species = -.6133E-08 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.9074437E-10 -.2211182E-01 -.2224853E+02 0.0000 2 H2O 0.1000000E+01 0.5550464E+02 0.9981897E+06 0.0000 3 Cl- 0.1629666E-03 0.1637148E-03 0.5794063E+01 6.2517 4 SO4-- 0.5488809E-09 -.8445592E-05 -.8098829E+00 10.6902 5 HCO3- 0.4613657E-04 0.1393359E-03 0.8487069E+01 5.7042 6 HS- 0.7032382E-04 0.7878385E-04 0.2600997E+01 5.8867 7 Al+++ 0.1003805E-28 0.4929590E-05 0.1327759E+00 0.7178 8 H4SiO4 0.7137961E-03 0.1353103E-01 0.1298273E+04 -3.1464 9 Ca++ 0.1089045E-06 0.2160825E-06 0.8645060E-02 12.9845 10 Mg++ 0.2120900E-10 0.9318008E-10 0.2261445E-05 9.2720 11 Fe++ 0.4682677E-13 0.2721968E-07 0.1517488E-02 6.6165 12 K+ 0.1565231E-03 0.1572568E-03 0.6138337E+01 6.2349 13 Na+ 0.1986567E-01 0.2230511E-01 0.5118962E+03 8.3376 14 Mn++ 0.1953836E-10 0.2507500E-08 0.1375169E-03 9.2372 15 F- 0.7991230E-06 0.8017092E-06 0.1520432E-01 3.9413 16 HPO4-- 0.4533948E-07 0.4641917E-07 0.4447499E-02 12.6072 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.1985964E-01 -.1985821E-01 -.1434840E-05 0.0000000E+00 2 H2O 0.4984768E+02 0.4984768E+02 -.1391984E-05 0.0000000E+00 3 Cl- 0.1470292E-03 0.1470292E-03 0.0000000E+00 0.0000000E+00 4 SO4-- -.7583810E-05 -.7584828E-05 0.1018348E-08 0.0000000E+00 5 HCO3- 0.1251350E-03 0.1251350E-03 0.0000000E+00 0.0000000E+00 6 HS- 0.7075328E-04 0.7075430E-04 -.1018348E-08 0.0000000E+00 7 Al+++ 0.4775352E-05 0.4427172E-05 0.3481800E-06 0.0000000E+00 8 H4SiO4 0.1215302E-01 0.1215197E-01 0.1054956E-05 0.0000000E+00 9 Ca++ 0.2080835E-06 0.1940597E-06 0.1402382E-07 0.0000000E+00 10 Mg++ 0.8368328E-10 0.8368328E-10 0.0000000E+00 0.0000000E+00 11 Fe++ 0.3259227E-07 0.2444548E-07 0.8146786E-08 0.0000000E+00 12 K+ 0.1412294E-03 0.1412294E-03 0.0000000E+00 0.0000000E+00 13 Na+ 0.2003215E-01 0.2003180E-01 0.3469775E-06 0.0000000E+00 14 Mn++ 0.2251939E-08 0.2251939E-08 0.0000000E+00 0.0000000E+00 15 F- 0.7200000E-06 0.7200000E-06 0.0000000E+00 0.0000000E+00 16 HPO4-- 0.4168819E-07 0.4168819E-07 0.0000000E+00 0.0000000E+00 Chg. balance for solid moles: -.5294E-22 Mass of aqueous solution: 0.899650E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 0.0015500 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 0.3470E-06 -6.460 0.9098E-04 -4.041 97.49 0.3493E-04 andradite 0.4073E-08 -8.390 0.2070E-05 -5.684 2.218 0.5378E-06 grossular 0.6012E-09 -9.221 0.2708E-06 -6.567 0.2902 0.7535E-07 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8714E+00 0.8714E+00 1.0000 -0.060 grossular 0.1286E+00 0.1286E+00 1.0000 -0.891 Solid products produced: Mass = 0.000093 g Volume = 0.000036 cm3 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.0015500 moles log = -2.8097 Original solution: 1000.0103000 g Original solution / Rock added: 645167.94 (Water/Rock Ratio), log = 5.8097 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0354 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9857E+00 0.9857 0.1006E+01 0.1021E+01 CO2,gas 0.6448E-06 1.0070 0.6723E-06 0.6676E-06 CH4,gas 0.1085E-01 1.0124 0.1138E-01 0.1124E-01 H2,gas 0.3483E-02 1.0006 0.3608E-02 0.3606E-02 H2S,gas 0.3688E-06 0.9960 0.3803E-06 0.3819E-06 S2,gas 0.4028E-27 1.0000 0.4170E-27 0.4170E-27 CO,gas 0.6244E-12 1.0000 0.6465E-12 0.6465E-12 SO3,gas 0.6041E-45 1.0000 0.6255E-45 0.6255E-45 SO2,gas 0.8481E-25 1.0000 0.8781E-25 0.8781E-25 HF,gas 0.8240E-15 1.0000 0.8531E-15 0.8531E-15 HCl,gas 0.3239E-17 1.0000 0.3354E-17 0.3354E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 17 albite -0.38 -0.38 0.00 0.000 -0.13080E-10 23 andradite 39.01 39.01 0.00 0.000 -0.36397E-10 24 grossular 32.73 32.73 0.00 0.000 0.00000E+00 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -14.53 -7.87 -2.624 0.13440E+05 -6.172 3 CH4,gas 4.54 0.90 -3.64 -0.911 0.62202E+04 -1.944 4 H2,gas 8.00 3.86 -4.14 -2.367 0.70718E+04 -2.443 5 H2S,gas -6.23 -14.35 -8.12 -4.059 0.13863E+05 -6.420 6 S2,gas -7.34 -36.41 -29.08 -4.474 0.49651E+05 -27.380 7 CO,gas 3.21 -10.67 -13.89 -4.273 0.23714E+05 -12.189 8 SO3,gas 17.12 -29.78 -46.90 -11.726 0.80085E+05 -45.204 9 SO2,gas 0.83 -25.92 -26.76 -7.135 0.45684E+05 -25.056 10 HF,gas 0.47 -16.29 -16.77 -8.384 0.28631E+05 -15.069 11 HCl,gas 5.19 -13.98 -19.17 -9.587 0.32738E+05 -17.474 12 acmite 7.71 6.73 -0.98 -0.102 0.16692E+04 16 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 20 spessartine 24.46 19.71 -4.75 -0.237 0.81093E+04 21 analcite 3.32 2.76 -0.56 -0.062 0.95499E+03 27 annite 20.12 17.36 -2.76 -0.153 0.47136E+04 28 phlogopite 27.06 25.33 -1.74 -0.096 0.29627E+04 30 anorthite 12.71 8.13 -4.58 -0.353 0.78253E+04 33 apatite-OH -18.15 -18.67 -0.52 -0.040 0.88244E+03 34 apatite-F -34.30 -34.96 -0.66 -0.055 0.11335E+04 38 aragonite 0.97 -1.55 -2.51 -0.838 0.42918E+04 39 brucite 12.57 9.27 -3.30 -0.659 0.56288E+04 40 calcite 0.81 -1.55 -2.36 -0.786 0.40276E+04 41 carnegieite-low 9.02 5.91 -3.11 -0.445 0.53176E+04 42 carnegieite-high 10.09 5.91 -4.18 -0.598 0.71446E+04 43 carpholite-Mg 8.58 4.41 -4.17 -0.278 0.71155E+04 44 carpholite-Fe 6.71 1.76 -4.95 -0.330 0.84577E+04 45 celadonite 5.34 3.64 -1.70 -0.100 0.29071E+04 46 celadonite-Fe 3.88 0.98 -2.89 -0.170 0.49398E+04 47 chrysotile 23.89 21.52 -2.37 -0.197 0.40454E+04 49 clinochlore 39.07 38.36 -0.71 -0.022 0.12175E+04 50 daphnite 28.97 25.08 -3.89 -0.121 0.66362E+04 52 chlorite-Al-free 47.17 43.05 -4.13 -0.172 0.70459E+04 54 chloritoid-Fe 9.17 4.91 -4.27 -0.285 0.72874E+04 55 chloritoid-Mn 11.40 7.53 -3.87 -0.258 0.66158E+04 57 coesite -2.38 -3.15 -0.77 -0.257 0.13154E+04 64 cristobalite -2.56 -3.15 -0.59 -0.195 0.10007E+04 66 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71235E+04 68 diaspore 2.87 0.72 -2.16 -0.359 0.36811E+04 69 diamond -3.10 -6.82 -3.71 -1.061 0.63398E+04 70 diopside 16.18 15.96 -0.22 -0.022 0.37165E+03 71 hedenbergite 14.21 13.31 -0.90 -0.090 0.15370E+04 76 clinoenstatite 17.17 12.25 -4.92 -0.492 0.83924E+04 78 epidote 24.67 22.65 -2.02 -0.098 0.34440E+04 79 clinozoisite 22.81 18.68 -4.12 -0.187 0.70395E+04 80 epidote-Fe 29.84 26.62 -3.22 -0.167 0.54952E+04 81 fayalite 14.05 10.09 -3.96 -0.566 0.67603E+04 82 ferrosilite 11.15 6.94 -4.21 -0.421 0.71874E+04 86 gibbsite 4.08 0.72 -3.36 -0.480 0.57396E+04 87 glaucophane 22.97 20.76 -2.22 -0.060 0.37895E+04 88 glaucophane-Fe 17.28 12.79 -4.49 -0.121 0.76615E+04 89 graphite -3.55 -6.82 -3.27 -0.934 0.55821E+04 90 greenalite 16.14 13.56 -2.58 -0.215 0.44104E+04 93 hematite 12.57 9.37 -3.19 -0.387 0.54491E+04 94 heulandite -5.83 -7.60 -1.78 -0.081 0.30351E+04 98 jadeite 4.22 2.76 -1.45 -0.145 0.24805E+04 100 kalsilite 7.58 3.81 -3.78 -0.540 0.64502E+04 101 kaolinite -1.33 -4.86 -3.52 -0.320 0.60178E+04 104 laumontite 2.88 1.83 -1.05 -0.070 0.17910E+04 105 lawsonite 9.62 8.13 -1.49 -0.099 0.25420E+04 106 leucite 4.12 0.66 -3.46 -0.346 0.59062E+04 108 lizardite 23.24 21.52 -1.72 -0.143 0.29380E+04 110 magnetite 20.09 15.99 -4.10 -0.334 0.69940E+04 111 minnesotaite 10.39 7.26 -3.12 -0.184 0.53349E+04 115 manganosite 14.06 9.24 -4.82 -1.205 0.82315E+04 119 microcline -2.49 -2.49 0.00 0.000 0.13248E+00 123 muscovite 2.58 -1.05 -3.63 -0.214 0.62038E+04 124 paragonite 4.24 1.05 -3.19 -0.188 0.54428E+04 125 nepheline 8.34 5.91 -2.43 -0.347 0.41500E+04 137 phlogopite-Na 29.65 27.43 -2.21 -0.123 0.37814E+04 139 prehnite 19.37 17.97 -1.41 -0.083 0.24014E+04 140 prehnite-Fe 22.50 21.94 -0.56 -0.034 0.96099E+03 141 pumpellyite-Fe 46.27 43.27 -3.00 -0.067 0.51296E+04 142 pumpellyite-Mg 48.99 45.92 -3.07 -0.068 0.52490E+04 145 pyrite -21.25 -25.94 -4.69 -1.104 0.80128E+04 146 pyrrhotite -4.26 -7.73 -3.47 -1.157 0.59288E+04 147 pyrrhotiteFe0.875 -6.02 -9.04 -3.02 -1.111 0.51585E+04 148 pyroxmangite 7.40 6.09 -1.31 -0.262 0.22332E+04 149 pyrophyllite -6.18 -11.15 -4.97 -0.311 0.84934E+04 150 quartz -2.99 -3.15 -0.16 -0.052 0.26806E+03 154 rhodochrosite -0.98 -5.29 -4.32 -1.439 0.73729E+04 155 rhodonite 7.45 6.09 -1.35 -0.271 0.23134E+04 156 sanidine -1.28 -2.49 -1.21 -0.093 0.20679E+04 166 stilbite -7.52 -7.60 -0.08 -0.004 0.14125E+03 167 stilpnomelane-Fe 13.02 12.46 -0.55 -0.017 0.94416E+03 168 stilpnomelane-Mg 27.44 25.74 -1.70 -0.051 0.29021E+04 174 talc 16.49 15.23 -1.26 -0.074 0.21527E+04 177 tephroite 18.09 15.33 -2.76 -0.394 0.47088E+04 181 tridymite -2.63 -3.15 -0.52 -0.173 0.88803E+03 182 tremolite 47.87 47.16 -0.71 -0.019 0.12149E+04 183 ferroactinolite 38.45 33.88 -4.57 -0.124 0.78072E+04 184 troilite-low -4.41 -7.73 -3.32 -1.107 0.56716E+04 190 wairakite 3.95 1.83 -2.12 -0.124 0.36129E+04 191 walstromite 11.51 9.84 -1.67 -0.334 0.28534E+04 192 wollastonite 10.46 9.84 -0.62 -0.125 0.10638E+04 193 pseudo-wollastonite 11.00 9.84 -1.16 -0.232 0.19836E+04 194 zoisite 22.85 18.68 -4.17 -0.189 0.71135E+04 195 akaganeite 7.75 4.69 -3.07 -0.663 0.52371E+04 202 chalcedony -2.80 -3.15 -0.34 -0.115 0.58735E+03 204 montmorillonite-Ca -2.29 -6.18 -3.89 -0.241 0.66489E+04 205 montmorillonite-K -2.24 -6.27 -4.03 -0.247 0.68861E+04 206 montmorillonite-Mg -2.48 -6.80 -4.32 -0.267 0.73718E+04 207 montmorillonite-Na -2.04 -5.58 -3.54 -0.217 0.60410E+04 208 nontronite-Ca 3.21 0.21 -3.01 -0.195 0.51356E+04 209 nontronite-H 2.53 -1.94 -4.47 -0.299 0.76296E+04 210 nontronite-K 3.34 0.12 -3.22 -0.207 0.54961E+04 211 nontronite-Mg 3.07 -0.41 -3.48 -0.226 0.59427E+04 212 nontronite-Na 3.52 0.82 -2.70 -0.174 0.46169E+04 228 tobermorite 9.82 7.67 -2.15 -0.588 0.36768E+04 234 alabandite -0.98 -5.11 -4.13 -1.378 0.70587E+04 237 boehmite 4.41 0.72 -3.69 -0.615 0.62980E+04 239 ferrous-oxide 9.81 6.62 -3.20 -0.799 0.54556E+04 245 silica-amorphous -2.09 -3.15 -1.06 -0.352 0.18015E+04 247 an20ab80 2.02 1.32 -0.70 -0.054 0.11942E+04 248 an25ab75 2.65 1.74 -0.90 -0.069 0.15397E+04 249 an30ab70 3.28 2.17 -1.11 -0.085 0.18949E+04 250 tr.625ac.25prg.125 45.16 44.78 -0.39 -0.010 0.66159E+03 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 0.0000400 MOLES Current total amount of reactant added: 0.0015500 MOLES New total amount of reactant added: 0.0015900 MOLES Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.5508E-08 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 7 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 0.0015900 Water: Moles liquid = 0.4985E+02 kg liquid = 0.8981E+00 Moles total = 0.4985E+02 kg total = 0.8980E+00 Activity = 1.0000 Stoichiometric ionic strength = .1143168E-01 Osmotic coef. = 0.9647 True ionic strength = .2011040E-01 Chg. balance for total moles = -.5508E-08 Max. difference allowed = 0.1473E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.90810E-10 -10.0419 0.76282E-10 -10.1176 0.84001E+00 -0.0757 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.16323E-03 -3.7872 0.13629E-03 -3.8655 0.83495E+00 -0.0783 4 SO4-- 0.58751E-09 -9.2310 0.30473E-09 -9.5161 0.51869E+00 -0.2851 5 HCO3- 0.47358E-04 -4.3246 0.39600E-04 -4.4023 0.83617E+00 -0.0777 6 HS- 0.71406E-04 -4.1463 0.59629E-04 -4.2245 0.83507E+00 -0.0783 7 Al+++ 0.10047E-28 -28.9979 0.23149E-29 -29.6355 0.23040E+00 -0.6375 8 H4SiO4 0.71427E-03 -3.1461 0.71427E-03 -3.1461 0.10000E+01 0.0000 9 Ca++ 0.10854E-06 -6.9644 0.55882E-07 -7.2527 0.51487E+00 -0.2883 10 Mg++ 0.21211E-10 -10.6734 0.10871E-10 -10.9637 0.51250E+00 -0.2903 11 Fe++ 0.46927E-13 -13.3286 0.24077E-13 -13.6184 0.51307E+00 -0.2898 12 K+ 0.15652E-03 -3.8054 0.13091E-03 -3.8830 0.83637E+00 -0.0776 13 Na+ 0.19866E-01 -1.7019 0.16584E-01 -1.7803 0.83479E+00 -0.0784 14 Mn++ 0.19565E-10 -10.7085 0.10047E-10 -10.9980 0.51349E+00 -0.2895 15 F- 0.81688E-06 -6.0878 0.68064E-06 -6.1671 0.83322E+00 -0.0792 16 HPO4-- 0.45340E-07 -7.3435 0.23521E-07 -7.6285 0.51876E+00 -0.2850 18 HSiO3- 0.10472E-01 -1.9800 0.87432E-02 -2.0583 0.83495E+00 -0.0783 19 Ca(HSiO3)+ 0.13301E-07 -7.8761 0.11127E-07 -7.9536 0.83655E+00 -0.0775 20 Mg(HSiO3)+ 0.32202E-11 -11.4921 0.26938E-11 -11.5696 0.83655E+00 -0.0775 21 NaHSiO3,aq 0.23451E-02 -2.6298 0.23451E-02 -2.6298 0.10000E+01 0.0000 22 AlO+ 0.64696E-16 -16.1891 0.54122E-16 -16.2666 0.83655E+00 -0.0775 24 HAlO2,aq 0.14129E-09 -9.8499 0.14129E-09 -9.8499 0.10000E+01 0.0000 25 AlO2- 0.49196E-05 -5.3081 0.41002E-05 -5.3872 0.83343E+00 -0.0791 26 CH4,aq 0.75532E-05 -5.1219 0.75269E-05 -5.1234 0.99651E+00 -0.0015 27 C2H6,aq 0.35840E-14 -14.4456 0.35715E-14 -14.4471 0.99651E+00 -0.0015 31 CO,aq 0.43971E-15 -15.3568 0.43971E-15 -15.3568 0.10000E+01 0.0000 32 CO2,aq 0.64771E-08 -8.1886 0.64546E-08 -8.1901 0.99651E+00 -0.0015 33 CO3-2 0.87606E-04 -4.0575 0.45343E-04 -4.3435 0.51758E+00 -0.2860 34 CaCO3,aq 0.31772E-07 -7.4980 0.31772E-07 -7.4980 0.10000E+01 0.0000 35 Ca(HCO3)+ 0.67524E-10 -10.1705 0.56487E-10 -10.2481 0.83655E+00 -0.0775 36 CaCl+ 0.14733E-10 -10.8317 0.12325E-10 -10.9092 0.83655E+00 -0.0775 37 CaCl2,aq 0.39907E-15 -15.3989 0.39907E-15 -15.3989 0.10000E+01 0.0000 38 CaF+ 0.66383E-12 -12.1779 0.55533E-12 -12.2555 0.83655E+00 -0.0775 39 CaOH+ 0.62412E-07 -7.2047 0.52211E-07 -7.2822 0.83655E+00 -0.0775 40 CaSO4,aq 0.54076E-14 -14.2670 0.54076E-14 -14.2670 0.10000E+01 0.0000 41 HCl,aq 0.19051E-14 -14.7201 0.19051E-14 -14.7201 0.10000E+01 0.0000 45 HF,aq 0.35543E-12 -12.4492 0.35543E-12 -12.4492 0.10000E+01 0.0000 46 HF2- 0.97825E-19 -19.0095 0.81679E-19 -19.0879 0.83495E+00 -0.0783 48 FeCl+ 0.62086E-17 -17.2070 0.51938E-17 -17.2845 0.83655E+00 -0.0775 51 FeF+ 0.10011E-17 -17.9995 0.83743E-18 -18.0771 0.83655E+00 -0.0775 53 FeO,aq 0.16081E-09 -9.7937 0.16081E-09 -9.7937 0.10000E+01 0.0000 54 FeOH+ 0.12281E-10 -10.9108 0.10274E-10 -10.9883 0.83655E+00 -0.0775 55 HFeO2- 0.26418E-07 -7.5781 0.22058E-07 -7.6564 0.83495E+00 -0.0783 56 FeO+ 0.17789E-16 -16.7499 0.14881E-16 -16.8274 0.83655E+00 -0.0775 58 FeO2- 0.62674E-09 -9.2029 0.52329E-09 -9.2813 0.83495E+00 -0.0783 59 HFeO2,aq 0.50769E-11 -11.2944 0.50769E-11 -11.2944 0.10000E+01 0.0000 60 H2,aq 0.27213E-05 -5.5652 0.27118E-05 -5.5667 0.99651E+00 -0.0015 61 KCl,aq 0.32336E-09 -9.4903 0.32336E-09 -9.4903 0.10000E+01 0.0000 63 KOH,aq 0.73290E-06 -6.1350 0.73290E-06 -6.1350 0.10000E+01 0.0000 64 KSO4- 0.74142E-12 -12.1299 0.61904E-12 -12.2083 0.83495E+00 -0.0783 65 MgCO3,aq 0.15492E-11 -11.8099 0.15492E-11 -11.8099 0.10000E+01 0.0000 66 Mg(HCO3)+ 0.13422E-13 -13.8722 0.11228E-13 -13.9497 0.83655E+00 -0.0775 67 MgCl+ 0.25977E-14 -14.5854 0.21731E-14 -14.6629 0.83655E+00 -0.0775 68 MgF+ 0.47836E-15 -15.3202 0.40017E-15 -15.3978 0.83655E+00 -0.0775 69 MgOH+ 0.67183E-10 -10.1727 0.56202E-10 -10.2503 0.83655E+00 -0.0775 71 MnF+ 0.13768E-15 -15.8611 0.11518E-15 -15.9386 0.83655E+00 -0.0775 72 MnO,aq 0.17880E-08 -8.7476 0.17880E-08 -8.7476 0.10000E+01 0.0000 73 MnOH+ 0.47607E-09 -9.3223 0.39826E-09 -9.3998 0.83655E+00 -0.0775 74 MnO2-2 0.19703E-10 -10.7055 0.10198E-10 -10.9915 0.51758E+00 -0.2860 75 HMnO2- 0.20412E-09 -9.6901 0.17043E-09 -9.7685 0.83495E+00 -0.0783 78 MnCl+ 0.10079E-13 -13.9966 0.84316E-14 -14.0741 0.83655E+00 -0.0775 79 MnSO4,aq 0.88384E-18 -18.0536 0.88384E-18 -18.0536 0.10000E+01 0.0000 80 NaCl,aq 0.74902E-06 -6.1255 0.74902E-06 -6.1255 0.10000E+01 0.0000 81 NaF,aq 0.26426E-08 -8.5780 0.26426E-08 -8.5780 0.10000E+01 0.0000 82 NaOH,aq 0.93407E-04 -4.0296 0.93407E-04 -4.0296 0.10000E+01 0.0000 84 OH- 0.90880E-02 -2.0415 0.75742E-02 -2.1207 0.83343E+00 -0.0791 89 HPO3-2 0.38404E-15 -15.4156 0.19877E-15 -15.7016 0.51758E+00 -0.2860 91 H2PO3- 0.36417E-19 -19.4387 0.30406E-19 -19.5170 0.83495E+00 -0.0783 92 H3PO4,aq 0.95722E-18 -18.0190 0.95722E-18 -18.0190 0.10000E+01 0.0000 93 H2PO4- 0.39603E-10 -10.4023 0.33098E-10 -10.4802 0.83574E+00 -0.0779 94 PO4-3 0.10394E-08 -8.9832 0.25157E-09 -9.5993 0.24203E+00 -0.6161 98 HP2O7-3 0.97491E-18 -18.0110 0.22485E-18 -18.6481 0.23063E+00 -0.6371 99 P2O7-4 0.91759E-17 -17.0374 0.70416E-18 -18.1523 0.76741E-01 -1.1150 100 H2S,aq 0.14107E-07 -7.8506 0.14058E-07 -7.8521 0.99651E+00 -0.0015 101 S2-2 0.56131E-13 -13.2508 0.29052E-13 -13.5368 0.51758E+00 -0.2860 107 SO3-2 0.20451E-15 -15.6893 0.10739E-15 -15.9690 0.52510E+00 -0.2798 108 HSO3- 0.61430E-18 -18.2116 0.51290E-18 -18.2900 0.83495E+00 -0.0783 109 HSO4- 0.26753E-16 -16.5726 0.22402E-16 -16.6497 0.83737E+00 -0.0771 111 S2O3-2 0.97225E-19 -19.0122 0.50322E-19 -19.2982 0.51758E+00 -0.2860 Charge balance for all species = -.6133E-08 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.9080985E-10 -.2210697E-01 -.2224365E+02 0.0000 2 H2O 0.1000000E+01 0.5550464E+02 0.9981895E+06 0.0000 3 Cl- 0.1632281E-03 0.1639775E-03 0.5803358E+01 6.2520 4 SO4-- 0.5875062E-09 -.8232910E-05 -.7894878E+00 10.7191 5 HCO3- 0.4735829E-04 0.1425560E-03 0.8683206E+01 5.7153 6 HS- 0.7140581E-04 0.7965342E-04 0.2629705E+01 5.8930 7 Al+++ 0.1004733E-28 0.4919767E-05 0.1325113E+00 0.7173 8 H4SiO4 0.7142728E-03 0.1353099E-01 0.1298269E+04 -3.1461 9 Ca++ 0.1085377E-06 0.2161058E-06 0.8645990E-02 12.9824 10 Mg++ 0.2121141E-10 0.9318000E-10 0.2261443E-05 9.2714 11 Fe++ 0.4692698E-13 0.2722324E-07 0.1517686E-02 6.6168 12 K+ 0.1565235E-03 0.1572567E-03 0.6138331E+01 6.2346 13 Na+ 0.1986581E-01 0.2230508E-01 0.5118955E+03 8.3373 14 Mn++ 0.1956532E-10 0.2507498E-08 0.1375168E-03 9.2372 15 F- 0.8168807E-06 0.8195243E-06 0.1554218E-01 3.9505 16 HPO4-- 0.4534011E-07 0.4641914E-07 0.4447495E-02 12.6066 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.1985534E-01 -.1985387E-01 -.1470076E-05 0.0000000E+00 2 H2O 0.4984771E+02 0.4984771E+02 -.1427298E-05 0.0000000E+00 3 Cl- 0.1472652E-03 0.1472652E-03 0.0000000E+00 0.0000000E+00 4 SO4-- -.7392810E-05 -.7393828E-05 0.1017946E-08 0.0000000E+00 5 HCO3- 0.1280270E-03 0.1280270E-03 0.0000000E+00 0.0000000E+00 6 HS- 0.7153428E-04 0.7153530E-04 -.1017946E-08 0.0000000E+00 7 Al+++ 0.4775352E-05 0.4418354E-05 0.3569981E-06 0.0000000E+00 8 H4SiO4 0.1215302E-01 0.1215194E-01 0.1081422E-05 0.0000000E+00 9 Ca++ 0.2080835E-06 0.1940807E-06 0.1400276E-07 0.0000000E+00 10 Mg++ 0.8368328E-10 0.8368328E-10 0.0000000E+00 0.0000000E+00 11 Fe++ 0.3259227E-07 0.2444870E-07 0.8143568E-08 0.0000000E+00 12 K+ 0.1412294E-03 0.1412294E-03 0.0000000E+00 0.0000000E+00 13 Na+ 0.2003215E-01 0.2003179E-01 0.3558065E-06 0.0000000E+00 14 Mn++ 0.2251939E-08 0.2251939E-08 0.0000000E+00 0.0000000E+00 15 F- 0.7360000E-06 0.7360000E-06 0.0000000E+00 0.0000000E+00 16 HPO4-- 0.4168819E-07 0.4168819E-07 0.0000000E+00 0.0000000E+00 Chg. balance for solid moles: -.1588E-21 Mass of aqueous solution: 0.899650E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 0.0015900 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 0.3558E-06 -6.449 0.9330E-04 -4.030 97.56 0.3582E-04 andradite 0.4072E-08 -8.390 0.2069E-05 -5.684 2.164 0.5376E-06 grossular 0.5958E-09 -9.225 0.2684E-06 -6.571 0.2806 0.7467E-07 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8724E+00 0.8724E+00 1.0000 -0.059 grossular 0.1276E+00 0.1276E+00 1.0000 -0.894 Solid products produced: Mass = 0.000096 g Volume = 0.000036 cm3 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.0015900 moles log = -2.7986 Original solution: 1000.0103000 g Original solution / Rock added: 628937.30 (Water/Rock Ratio), log = 5.7986 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0350 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9860E+00 0.9858 0.1006E+01 0.1021E+01 CO2,gas 0.6626E-06 1.0070 0.6906E-06 0.6858E-06 CH4,gas 0.1057E-01 1.0124 0.1108E-01 0.1094E-01 H2,gas 0.3438E-02 1.0006 0.3560E-02 0.3558E-02 H2S,gas 0.3749E-06 0.9960 0.3864E-06 0.3880E-06 S2,gas 0.4273E-27 1.0000 0.4422E-27 0.4422E-27 CO,gas 0.6331E-12 1.0000 0.6553E-12 0.6553E-12 SO3,gas 0.6478E-45 1.0000 0.6705E-45 0.6705E-45 SO2,gas 0.8973E-25 1.0000 0.9287E-25 0.9287E-25 HF,gas 0.8432E-15 1.0000 0.8727E-15 0.8727E-15 HCl,gas 0.3248E-17 1.0000 0.3362E-17 0.3362E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 17 albite -0.38 -0.38 0.00 0.000 -0.94784E-12 23 andradite 39.01 39.01 0.00 0.000 0.12132E-10 24 grossular 32.73 32.73 0.00 0.000 0.24265E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -14.52 -7.86 -2.620 0.13420E+05 -6.161 3 CH4,gas 4.54 0.89 -3.65 -0.914 0.62399E+04 -1.955 4 H2,gas 8.00 3.85 -4.15 -2.370 0.70817E+04 -2.449 5 H2S,gas -6.23 -14.34 -8.11 -4.056 0.13851E+05 -6.413 6 S2,gas -7.34 -36.39 -29.05 -4.470 0.49608E+05 -27.354 7 CO,gas 3.21 -10.67 -13.88 -4.272 0.23704E+05 -12.184 8 SO3,gas 17.12 -29.75 -46.87 -11.718 0.80034E+05 -45.174 9 SO2,gas 0.83 -25.90 -26.73 -7.128 0.45643E+05 -25.032 10 HF,gas 0.47 -16.28 -16.76 -8.379 0.28614E+05 -15.059 11 HCl,gas 5.19 -13.98 -19.17 -9.586 0.32736E+05 -17.473 12 acmite 7.71 6.74 -0.97 -0.101 0.16633E+04 16 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 20 spessartine 24.46 19.71 -4.75 -0.237 0.81099E+04 21 analcite 3.32 2.76 -0.56 -0.062 0.95549E+03 27 annite 20.12 17.36 -2.76 -0.153 0.47121E+04 28 phlogopite 27.06 25.33 -1.74 -0.096 0.29657E+04 30 anorthite 12.71 8.12 -4.59 -0.353 0.78298E+04 33 apatite-OH -18.15 -18.68 -0.53 -0.040 0.89722E+03 34 apatite-F -34.30 -34.96 -0.66 -0.055 0.11314E+04 38 aragonite 0.97 -1.54 -2.50 -0.835 0.42755E+04 39 brucite 12.57 9.27 -3.30 -0.659 0.56298E+04 40 calcite 0.81 -1.54 -2.35 -0.783 0.40112E+04 41 carnegieite-low 9.02 5.91 -3.11 -0.445 0.53186E+04 42 carnegieite-high 10.09 5.91 -4.18 -0.598 0.71456E+04 43 carpholite-Mg 8.58 4.41 -4.17 -0.278 0.71174E+04 44 carpholite-Fe 6.71 1.76 -4.95 -0.330 0.84581E+04 45 celadonite 5.34 3.64 -1.70 -0.100 0.29076E+04 46 celadonite-Fe 3.88 0.98 -2.89 -0.170 0.49388E+04 47 chrysotile 23.89 21.52 -2.37 -0.198 0.40474E+04 49 clinochlore 39.07 38.35 -0.72 -0.022 0.12230E+04 50 daphnite 28.97 25.08 -3.89 -0.121 0.66341E+04 52 chlorite-Al-free 47.17 43.04 -4.13 -0.172 0.70499E+04 54 chloritoid-Fe 9.17 4.91 -4.27 -0.285 0.72883E+04 55 chloritoid-Mn 11.40 7.53 -3.88 -0.258 0.66173E+04 57 coesite -2.38 -3.15 -0.77 -0.257 0.13149E+04 64 cristobalite -2.56 -3.15 -0.59 -0.195 0.10002E+04 66 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71235E+04 68 diaspore 2.87 0.72 -2.16 -0.359 0.36820E+04 69 diamond -3.10 -6.82 -3.71 -1.061 0.63397E+04 70 diopside 16.18 15.96 -0.22 -0.022 0.37525E+03 71 hedenbergite 14.21 13.31 -0.90 -0.090 0.15390E+04 76 clinoenstatite 17.17 12.25 -4.92 -0.492 0.83934E+04 78 epidote 24.67 22.65 -2.02 -0.098 0.34462E+04 79 clinozoisite 22.81 18.68 -4.13 -0.188 0.70480E+04 80 epidote-Fe 29.84 26.62 -3.22 -0.167 0.54909E+04 81 fayalite 14.05 10.09 -3.96 -0.565 0.67588E+04 82 ferrosilite 11.15 6.94 -4.21 -0.421 0.71854E+04 86 gibbsite 4.08 0.72 -3.36 -0.480 0.57406E+04 87 glaucophane 22.97 20.75 -2.22 -0.060 0.37915E+04 88 glaucophane-Fe 17.28 12.79 -4.49 -0.121 0.76590E+04 89 graphite -3.55 -6.82 -3.27 -0.934 0.55820E+04 90 greenalite 16.14 13.56 -2.58 -0.215 0.44079E+04 93 hematite 12.57 9.38 -3.18 -0.386 0.54382E+04 94 heulandite -5.83 -7.61 -1.78 -0.081 0.30371E+04 98 jadeite 4.22 2.76 -1.45 -0.145 0.24810E+04 100 kalsilite 7.58 3.81 -3.78 -0.540 0.64512E+04 101 kaolinite -1.33 -4.86 -3.52 -0.320 0.60188E+04 104 laumontite 2.88 1.83 -1.05 -0.070 0.17945E+04 105 lawsonite 9.62 8.12 -1.49 -0.099 0.25465E+04 106 leucite 4.12 0.66 -3.46 -0.346 0.59067E+04 108 lizardite 23.24 21.52 -1.72 -0.143 0.29400E+04 110 magnetite 20.09 16.00 -4.09 -0.334 0.69825E+04 111 minnesotaite 10.39 7.27 -3.12 -0.184 0.53314E+04 115 manganosite 14.06 9.24 -4.82 -1.205 0.82316E+04 119 microcline -2.49 -2.49 0.00 0.000 0.13596E+00 123 muscovite 2.58 -1.05 -3.63 -0.214 0.62057E+04 124 paragonite 4.24 1.05 -3.19 -0.188 0.54447E+04 125 nepheline 8.34 5.91 -2.43 -0.347 0.41510E+04 137 phlogopite-Na 29.65 27.43 -2.22 -0.123 0.37844E+04 139 prehnite 19.37 17.96 -1.41 -0.083 0.24090E+04 140 prehnite-Fe 22.50 21.93 -0.56 -0.034 0.96217E+03 141 pumpellyite-Fe 46.27 43.26 -3.01 -0.067 0.51452E+04 142 pumpellyite-Mg 48.99 45.91 -3.08 -0.069 0.52661E+04 145 pyrite -21.25 -25.92 -4.67 -1.099 0.79787E+04 146 pyrrhotite -4.26 -7.73 -3.47 -1.155 0.59165E+04 147 pyrrhotiteFe0.875 -6.02 -9.03 -3.01 -1.108 0.51450E+04 148 pyroxmangite 7.40 6.09 -1.31 -0.262 0.22327E+04 149 pyrophyllite -6.18 -11.15 -4.97 -0.311 0.84933E+04 150 quartz -2.99 -3.15 -0.16 -0.052 0.26756E+03 154 rhodochrosite -0.98 -5.28 -4.31 -1.435 0.73530E+04 155 rhodonite 7.45 6.09 -1.35 -0.271 0.23130E+04 156 sanidine -1.28 -2.49 -1.21 -0.093 0.20679E+04 166 stilbite -7.52 -7.61 -0.08 -0.004 0.14328E+03 167 stilpnomelane-Fe 13.02 12.47 -0.55 -0.016 0.93987E+03 168 stilpnomelane-Mg 27.44 25.74 -1.70 -0.051 0.29053E+04 174 talc 16.49 15.23 -1.26 -0.074 0.21537E+04 177 tephroite 18.09 15.33 -2.76 -0.394 0.47085E+04 181 tridymite -2.63 -3.15 -0.52 -0.173 0.88754E+03 182 tremolite 47.87 47.15 -0.72 -0.019 0.12231E+04 183 ferroactinolite 38.45 33.88 -4.57 -0.124 0.78079E+04 184 troilite-low -4.41 -7.73 -3.31 -1.105 0.56593E+04 190 wairakite 3.95 1.83 -2.12 -0.125 0.36165E+04 191 walstromite 11.51 9.84 -1.67 -0.335 0.28565E+04 192 wollastonite 10.46 9.84 -0.62 -0.125 0.10669E+04 193 pseudo-wollastonite 11.00 9.84 -1.16 -0.233 0.19867E+04 194 zoisite 22.85 18.68 -4.17 -0.190 0.71221E+04 195 akaganeite 7.75 4.69 -3.06 -0.662 0.52316E+04 202 chalcedony -2.80 -3.15 -0.34 -0.115 0.58686E+03 204 montmorillonite-Ca -2.29 -6.19 -3.89 -0.241 0.66494E+04 205 montmorillonite-K -2.24 -6.27 -4.03 -0.247 0.68862E+04 206 montmorillonite-Mg -2.48 -6.80 -4.32 -0.267 0.73719E+04 207 montmorillonite-Na -2.04 -5.58 -3.54 -0.217 0.60411E+04 208 nontronite-Ca 3.21 0.21 -3.00 -0.195 0.51238E+04 209 nontronite-H 2.53 -1.93 -4.46 -0.299 0.76172E+04 210 nontronite-K 3.34 0.13 -3.21 -0.206 0.54839E+04 211 nontronite-Mg 3.07 -0.40 -3.47 -0.225 0.59304E+04 212 nontronite-Na 3.52 0.82 -2.70 -0.173 0.46047E+04 228 tobermorite 9.82 7.67 -2.15 -0.588 0.36793E+04 234 alabandite -0.98 -5.10 -4.13 -1.376 0.70469E+04 237 boehmite 4.41 0.72 -3.69 -0.615 0.62990E+04 239 ferrous-oxide 9.81 6.62 -3.19 -0.799 0.54551E+04 245 silica-amorphous -2.09 -3.15 -1.05 -0.352 0.18010E+04 247 an20ab80 2.02 1.32 -0.70 -0.054 0.11951E+04 248 an25ab75 2.65 1.74 -0.90 -0.069 0.15409E+04 249 an30ab70 3.28 2.17 -1.11 -0.085 0.18962E+04 250 tr.625ac.25prg.125 45.16 44.77 -0.39 -0.011 0.66833E+03 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 0.0000400 MOLES Current total amount of reactant added: 0.0015900 MOLES New total amount of reactant added: 0.0016300 MOLES Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.5508E-08 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 7 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 0.0016300 Water: Moles liquid = 0.4985E+02 kg liquid = 0.8981E+00 Moles total = 0.4985E+02 kg total = 0.8980E+00 Activity = 1.0000 Stoichiometric ionic strength = .1143423E-01 Osmotic coef. = 0.9646 True ionic strength = .2011275E-01 Chg. balance for total moles = -.5508E-08 Max. difference allowed = 0.1475E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.90875E-10 -10.0416 0.76336E-10 -10.1173 0.84001E+00 -0.0757 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.16349E-03 -3.7865 0.13650E-03 -3.8649 0.83494E+00 -0.0783 4 SO4-- 0.62877E-09 -9.2015 0.32612E-09 -9.4866 0.51867E+00 -0.2851 5 HCO3- 0.48581E-04 -4.3135 0.40622E-04 -4.3912 0.83616E+00 -0.0777 6 HS- 0.72488E-04 -4.1397 0.60532E-04 -4.2180 0.83506E+00 -0.0783 7 Al+++ 0.10057E-28 -28.9975 0.23169E-29 -29.6351 0.23038E+00 -0.6375 8 H4SiO4 0.71475E-03 -3.1458 0.71475E-03 -3.1458 0.10000E+01 0.0000 9 Ca++ 0.10817E-06 -6.9659 0.55693E-07 -7.2542 0.51485E+00 -0.2883 10 Mg++ 0.21214E-10 -10.6734 0.10872E-10 -10.9637 0.51249E+00 -0.2903 11 Fe++ 0.47026E-13 -13.3277 0.24127E-13 -13.6175 0.51305E+00 -0.2898 12 K+ 0.15652E-03 -3.8054 0.13091E-03 -3.8830 0.83636E+00 -0.0776 13 Na+ 0.19866E-01 -1.7019 0.16584E-01 -1.7803 0.83479E+00 -0.0784 14 Mn++ 0.19592E-10 -10.7079 0.10060E-10 -10.9974 0.51348E+00 -0.2895 15 F- 0.83464E-06 -6.0785 0.69543E-06 -6.1577 0.83321E+00 -0.0792 16 HPO4-- 0.45341E-07 -7.3435 0.23520E-07 -7.6286 0.51875E+00 -0.2850 18 HSiO3- 0.10471E-01 -1.9800 0.87428E-02 -2.0583 0.83494E+00 -0.0783 19 Ca(HSiO3)+ 0.13255E-07 -7.8776 0.11089E-07 -7.9551 0.83654E+00 -0.0775 20 Mg(HSiO3)+ 0.32203E-11 -11.4921 0.26939E-11 -11.5696 0.83654E+00 -0.0775 21 NaHSiO3,aq 0.23450E-02 -2.6299 0.23450E-02 -2.6299 0.10000E+01 0.0000 22 AlO+ 0.64659E-16 -16.1894 0.54090E-16 -16.2669 0.83654E+00 -0.0775 24 HAlO2,aq 0.14111E-09 -9.8504 0.14111E-09 -9.8504 0.10000E+01 0.0000 25 AlO2- 0.49098E-05 -5.3089 0.40920E-05 -5.3881 0.83343E+00 -0.0791 26 CH4,aq 0.73497E-05 -5.1337 0.73240E-05 -5.1353 0.99651E+00 -0.0015 27 C2H6,aq 0.34391E-14 -14.4636 0.34271E-14 -14.4651 0.99651E+00 -0.0015 31 CO,aq 0.44538E-15 -15.3513 0.44538E-15 -15.3513 0.10000E+01 0.0000 32 CO2,aq 0.66491E-08 -8.1772 0.66259E-08 -8.1788 0.99651E+00 -0.0015 33 CO3-2 0.89806E-04 -4.0467 0.46481E-04 -4.3327 0.51757E+00 -0.2860 34 CaCO3,aq 0.32459E-07 -7.4887 0.32459E-07 -7.4887 0.10000E+01 0.0000 35 Ca(HCO3)+ 0.69032E-10 -10.1609 0.57749E-10 -10.2385 0.83654E+00 -0.0775 36 CaCl+ 0.14707E-10 -10.8325 0.12303E-10 -10.9100 0.83654E+00 -0.0775 37 CaCl2,aq 0.39899E-15 -15.3990 0.39899E-15 -15.3990 0.10000E+01 0.0000 38 CaF+ 0.67596E-12 -12.1701 0.56547E-12 -12.2476 0.83654E+00 -0.0775 39 CaOH+ 0.62156E-07 -7.2065 0.51996E-07 -7.2840 0.83654E+00 -0.0775 40 CaSO4,aq 0.57675E-14 -14.2390 0.57675E-14 -14.2390 0.10000E+01 0.0000 41 HCl,aq 0.19095E-14 -14.7191 0.19095E-14 -14.7191 0.10000E+01 0.0000 45 HF,aq 0.36341E-12 -12.4396 0.36341E-12 -12.4396 0.10000E+01 0.0000 46 HF2- 0.10220E-18 -18.9906 0.85328E-19 -19.0689 0.83494E+00 -0.0783 48 FeCl+ 0.62314E-17 -17.2054 0.52129E-17 -17.2829 0.83654E+00 -0.0775 51 FeF+ 0.10249E-17 -17.9893 0.85740E-18 -18.0668 0.83654E+00 -0.0775 53 FeO,aq 0.16092E-09 -9.7934 0.16092E-09 -9.7934 0.10000E+01 0.0000 54 FeOH+ 0.12298E-10 -10.9102 0.10288E-10 -10.9877 0.83654E+00 -0.0775 55 HFeO2- 0.26417E-07 -7.5781 0.22056E-07 -7.6565 0.83494E+00 -0.0783 56 FeO+ 0.17933E-16 -16.7464 0.15001E-16 -16.8239 0.83654E+00 -0.0775 58 FeO2- 0.63091E-09 -9.2000 0.52677E-09 -9.2784 0.83494E+00 -0.0783 59 HFeO2,aq 0.51143E-11 -11.2912 0.51143E-11 -11.2912 0.10000E+01 0.0000 60 H2,aq 0.26851E-05 -5.5710 0.26758E-05 -5.5725 0.99651E+00 -0.0015 61 KCl,aq 0.32388E-09 -9.4896 0.32388E-09 -9.4896 0.10000E+01 0.0000 63 KOH,aq 0.73237E-06 -6.1353 0.73237E-06 -6.1353 0.10000E+01 0.0000 64 KSO4- 0.79346E-12 -12.1005 0.66249E-12 -12.1788 0.83494E+00 -0.0783 65 MgCO3,aq 0.15882E-11 -11.7991 0.15882E-11 -11.7991 0.10000E+01 0.0000 66 Mg(HCO3)+ 0.13770E-13 -13.8611 0.11519E-13 -13.9386 0.83654E+00 -0.0775 67 MgCl+ 0.26020E-14 -14.5847 0.21767E-14 -14.6622 0.83654E+00 -0.0775 68 MgF+ 0.48880E-15 -15.3109 0.40890E-15 -15.3884 0.83654E+00 -0.0775 69 MgOH+ 0.67141E-10 -10.1730 0.56166E-10 -10.2505 0.83654E+00 -0.0775 71 MnF+ 0.14087E-15 -15.8512 0.11784E-15 -15.9287 0.83654E+00 -0.0775 72 MnO,aq 0.17879E-08 -8.7477 0.17879E-08 -8.7477 0.10000E+01 0.0000 73 MnOH+ 0.47638E-09 -9.3220 0.39851E-09 -9.3996 0.83654E+00 -0.0775 74 MnO2-2 0.19674E-10 -10.7061 0.10182E-10 -10.9921 0.51757E+00 -0.2860 75 HMnO2- 0.20396E-09 -9.6905 0.17029E-09 -9.7688 0.83494E+00 -0.0783 78 MnCl+ 0.10109E-13 -13.9953 0.84564E-14 -14.0728 0.83654E+00 -0.0775 79 MnSO4,aq 0.94716E-18 -18.0236 0.94716E-18 -18.0236 0.10000E+01 0.0000 80 NaCl,aq 0.75021E-06 -6.1248 0.75021E-06 -6.1248 0.10000E+01 0.0000 81 NaF,aq 0.27001E-08 -8.5686 0.27001E-08 -8.5686 0.10000E+01 0.0000 82 NaOH,aq 0.93340E-04 -4.0299 0.93340E-04 -4.0299 0.10000E+01 0.0000 84 OH- 0.90816E-02 -2.0418 0.75688E-02 -2.1210 0.83343E+00 -0.0791 89 HPO3-2 0.37894E-15 -15.4214 0.19613E-15 -15.7075 0.51757E+00 -0.2860 91 H2PO3- 0.35958E-19 -19.4442 0.30023E-19 -19.5226 0.83494E+00 -0.0783 92 H3PO4,aq 0.95858E-18 -18.0184 0.95858E-18 -18.0184 0.10000E+01 0.0000 93 H2PO4- 0.39631E-10 -10.4020 0.33121E-10 -10.4799 0.83573E+00 -0.0779 94 PO4-3 0.10387E-08 -8.9835 0.25139E-09 -9.5997 0.24201E+00 -0.6162 98 HP2O7-3 0.97565E-18 -18.0107 0.22500E-18 -18.6478 0.23062E+00 -0.6371 99 P2O7-4 0.91767E-17 -17.0373 0.70414E-18 -18.1523 0.76732E-01 -1.1150 100 H2S,aq 0.14331E-07 -7.8437 0.14281E-07 -7.8452 0.99651E+00 -0.0015 101 S2-2 0.58625E-13 -13.2319 0.30342E-13 -13.5180 0.51757E+00 -0.2860 107 SO3-2 0.21596E-15 -15.6656 0.11340E-15 -15.9454 0.52508E+00 -0.2798 108 HSO3- 0.64915E-18 -18.1877 0.54200E-18 -18.2660 0.83494E+00 -0.0783 109 HSO4- 0.28652E-16 -16.5429 0.23992E-16 -16.6199 0.83736E+00 -0.0771 111 S2O3-2 0.10570E-18 -18.9759 0.54709E-19 -19.2619 0.51757E+00 -0.2860 Charge balance for all species = -.6133E-08 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.9087541E-10 -.2210211E-01 -.2223876E+02 0.0000 2 H2O 0.1000000E+01 0.5550463E+02 0.9981892E+06 0.0000 3 Cl- 0.1634896E-03 0.1642401E-03 0.5812653E+01 6.2524 4 SO4-- 0.6287665E-09 -.8020228E-05 -.7690927E+00 10.7479 5 HCO3- 0.4858113E-04 0.1457761E-03 0.8879342E+01 5.7260 6 HS- 0.7248780E-04 0.8052299E-04 0.2658413E+01 5.8993 7 Al+++ 0.1005662E-28 0.4909959E-05 0.1322471E+00 0.7167 8 H4SiO4 0.7147500E-03 0.1353095E-01 0.1298265E+04 -3.1458 9 Ca++ 0.1081728E-06 0.2161274E-06 0.8646854E-02 12.9803 10 Mg++ 0.2121382E-10 0.9317993E-10 0.2261441E-05 9.2708 11 Fe++ 0.4702591E-13 0.2722595E-07 0.1517837E-02 6.6170 12 K+ 0.1565239E-03 0.1572566E-03 0.6138326E+01 6.2342 13 Na+ 0.1986596E-01 0.2230506E-01 0.5118948E+03 8.3370 14 Mn++ 0.1959233E-10 0.2507496E-08 0.1375167E-03 9.2371 15 F- 0.8346383E-06 0.8373394E-06 0.1588004E-01 3.9595 16 HPO4-- 0.4534073E-07 0.4641910E-07 0.4447491E-02 12.6060 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.1985103E-01 -.1984952E-01 -.1505261E-05 0.0000000E+00 2 H2O 0.4984774E+02 0.4984774E+02 -.1462558E-05 0.0000000E+00 3 Cl- 0.1475012E-03 0.1475012E-03 0.0000000E+00 0.0000000E+00 4 SO4-- -.7201810E-05 -.7202828E-05 0.1017639E-08 0.0000000E+00 5 HCO3- 0.1309190E-03 0.1309190E-03 0.0000000E+00 0.0000000E+00 6 HS- 0.7231528E-04 0.7231630E-04 -.1017639E-08 0.0000000E+00 7 Al+++ 0.4775352E-05 0.4409549E-05 0.3658028E-06 0.0000000E+00 8 H4SiO4 0.1215302E-01 0.1215191E-01 0.1107848E-05 0.0000000E+00 9 Ca++ 0.2080835E-06 0.1941003E-06 0.1398319E-07 0.0000000E+00 10 Mg++ 0.8368328E-10 0.8368328E-10 0.0000000E+00 0.0000000E+00 11 Fe++ 0.3259227E-07 0.2445116E-07 0.8141113E-08 0.0000000E+00 12 K+ 0.1412294E-03 0.1412294E-03 0.0000000E+00 0.0000000E+00 13 Na+ 0.2003215E-01 0.2003179E-01 0.3646218E-06 0.0000000E+00 14 Mn++ 0.2251939E-08 0.2251939E-08 0.0000000E+00 0.0000000E+00 15 F- 0.7520000E-06 0.7520000E-06 0.0000000E+00 0.0000000E+00 16 HPO4-- 0.4168819E-07 0.4168819E-07 0.0000000E+00 0.0000000E+00 Chg. balance for solid moles: 0.1059E-21 Mass of aqueous solution: 0.899651E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 0.0016300 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 0.3646E-06 -6.438 0.9561E-04 -4.019 97.62 0.3670E-04 andradite 0.4071E-08 -8.390 0.2069E-05 -5.684 2.112 0.5374E-06 grossular 0.5905E-09 -9.229 0.2660E-06 -6.575 0.2716 0.7401E-07 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8733E+00 0.8733E+00 1.0000 -0.059 grossular 0.1267E+00 0.1267E+00 1.0000 -0.897 Solid products produced: Mass = 0.000098 g Volume = 0.000037 cm3 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.0016300 moles log = -2.7878 Original solution: 1000.0103000 g Original solution / Rock added: 613503.25 (Water/Rock Ratio), log = 5.7878 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0347 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9863E+00 0.9858 0.1006E+01 0.1020E+01 CO2,gas 0.6804E-06 1.0070 0.7089E-06 0.7040E-06 CH4,gas 0.1029E-01 1.0124 0.1078E-01 0.1065E-01 H2,gas 0.3393E-02 1.0006 0.3513E-02 0.3511E-02 H2S,gas 0.3810E-06 0.9960 0.3926E-06 0.3942E-06 S2,gas 0.4531E-27 1.0000 0.4688E-27 0.4688E-27 CO,gas 0.6415E-12 1.0000 0.6637E-12 0.6637E-12 SO3,gas 0.6945E-45 1.0000 0.7185E-45 0.7185E-45 SO2,gas 0.9492E-25 1.0000 0.9821E-25 0.9821E-25 HF,gas 0.8624E-15 1.0000 0.8923E-15 0.8923E-15 HCl,gas 0.3256E-17 1.0000 0.3369E-17 0.3369E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 17 albite -0.38 -0.38 0.00 0.000 0.11184E-10 23 andradite 39.01 39.01 0.00 0.000 0.00000E+00 24 grossular 32.73 32.73 0.00 0.000 -0.12132E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -14.51 -7.85 -2.616 0.13401E+05 -6.149 3 CH4,gas 4.54 0.88 -3.67 -0.917 0.62602E+04 -1.967 4 H2,gas 8.00 3.85 -4.15 -2.373 0.70916E+04 -2.454 5 H2S,gas -6.23 -14.34 -8.11 -4.053 0.13839E+05 -6.406 6 S2,gas -7.34 -36.36 -29.03 -4.466 0.49565E+05 -27.329 7 CO,gas 3.21 -10.66 -13.88 -4.270 0.23695E+05 -12.178 8 SO3,gas 17.12 -29.72 -46.84 -11.711 0.79982E+05 -45.144 9 SO2,gas 0.83 -25.87 -26.71 -7.122 0.45601E+05 -25.008 10 HF,gas 0.47 -16.28 -16.75 -8.374 0.28598E+05 -15.049 11 HCl,gas 5.19 -13.98 -19.17 -9.586 0.32735E+05 -17.472 12 acmite 7.71 6.74 -0.97 -0.101 0.16574E+04 16 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 20 spessartine 24.46 19.71 -4.75 -0.237 0.81105E+04 21 analcite 3.32 2.76 -0.56 -0.062 0.95598E+03 27 annite 20.12 17.36 -2.76 -0.153 0.47107E+04 28 phlogopite 27.06 25.33 -1.74 -0.097 0.29687E+04 30 anorthite 12.71 8.12 -4.59 -0.353 0.78343E+04 33 apatite-OH -18.15 -18.69 -0.53 -0.041 0.91197E+03 34 apatite-F -34.30 -34.96 -0.66 -0.055 0.11297E+04 38 aragonite 0.97 -1.53 -2.49 -0.832 0.42596E+04 39 brucite 12.57 9.27 -3.30 -0.660 0.56308E+04 40 calcite 0.81 -1.53 -2.34 -0.780 0.39954E+04 41 carnegieite-low 9.02 5.91 -3.12 -0.445 0.53196E+04 42 carnegieite-high 10.09 5.91 -4.19 -0.598 0.71466E+04 43 carpholite-Mg 8.58 4.41 -4.17 -0.278 0.71193E+04 44 carpholite-Fe 6.71 1.76 -4.95 -0.330 0.84586E+04 45 celadonite 5.34 3.64 -1.70 -0.100 0.29081E+04 46 celadonite-Fe 3.88 0.98 -2.89 -0.170 0.49379E+04 47 chrysotile 23.89 21.52 -2.37 -0.198 0.40494E+04 49 clinochlore 39.07 38.35 -0.72 -0.022 0.12284E+04 50 daphnite 28.97 25.08 -3.88 -0.121 0.66321E+04 52 chlorite-Al-free 47.17 43.04 -4.13 -0.172 0.70539E+04 54 chloritoid-Fe 9.17 4.90 -4.27 -0.285 0.72892E+04 55 chloritoid-Mn 11.40 7.52 -3.88 -0.258 0.66187E+04 57 coesite -2.38 -3.15 -0.77 -0.257 0.13144E+04 64 cristobalite -2.56 -3.15 -0.59 -0.195 0.99974E+03 66 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71235E+04 68 diaspore 2.87 0.72 -2.16 -0.359 0.36830E+04 69 diamond -3.10 -6.82 -3.71 -1.061 0.63402E+04 70 diopside 16.18 15.96 -0.22 -0.022 0.37883E+03 71 hedenbergite 14.21 13.31 -0.90 -0.090 0.15412E+04 76 clinoenstatite 17.17 12.25 -4.92 -0.492 0.83944E+04 78 epidote 24.67 22.65 -2.02 -0.098 0.34483E+04 79 clinozoisite 22.81 18.67 -4.13 -0.188 0.70565E+04 80 epidote-Fe 29.84 26.63 -3.21 -0.167 0.54867E+04 81 fayalite 14.05 10.09 -3.96 -0.565 0.67573E+04 82 ferrosilite 11.15 6.94 -4.21 -0.421 0.71835E+04 86 gibbsite 4.08 0.72 -3.36 -0.480 0.57415E+04 87 glaucophane 22.97 20.75 -2.22 -0.060 0.37935E+04 88 glaucophane-Fe 17.28 12.79 -4.48 -0.121 0.76565E+04 89 graphite -3.55 -6.82 -3.27 -0.934 0.55824E+04 90 greenalite 16.14 13.56 -2.58 -0.215 0.44054E+04 93 hematite 12.57 9.39 -3.18 -0.385 0.54273E+04 94 heulandite -5.83 -7.61 -1.78 -0.081 0.30391E+04 98 jadeite 4.22 2.76 -1.45 -0.145 0.24815E+04 100 kalsilite 7.58 3.81 -3.78 -0.540 0.64522E+04 101 kaolinite -1.33 -4.86 -3.53 -0.320 0.60197E+04 104 laumontite 2.88 1.83 -1.05 -0.070 0.17980E+04 105 lawsonite 9.62 8.12 -1.49 -0.100 0.25510E+04 106 leucite 4.12 0.66 -3.46 -0.346 0.59072E+04 108 lizardite 23.24 21.52 -1.72 -0.144 0.29420E+04 110 magnetite 20.09 16.00 -4.08 -0.333 0.69712E+04 111 minnesotaite 10.39 7.27 -3.12 -0.184 0.53280E+04 115 manganosite 14.06 9.24 -4.82 -1.205 0.82317E+04 119 microcline -2.49 -2.49 0.00 0.000 0.13945E+00 123 muscovite 2.58 -1.05 -3.64 -0.214 0.62076E+04 124 paragonite 4.24 1.05 -3.19 -0.188 0.54466E+04 125 nepheline 8.34 5.91 -2.43 -0.347 0.41519E+04 137 phlogopite-Na 29.65 27.43 -2.22 -0.123 0.37874E+04 139 prehnite 19.37 17.96 -1.42 -0.083 0.24166E+04 140 prehnite-Fe 22.50 21.93 -0.56 -0.034 0.96336E+03 141 pumpellyite-Fe 46.27 43.25 -3.02 -0.067 0.51609E+04 142 pumpellyite-Mg 48.99 45.90 -3.09 -0.069 0.52832E+04 145 pyrite -21.25 -25.90 -4.65 -1.095 0.79450E+04 146 pyrrhotite -4.26 -7.72 -3.46 -1.153 0.59043E+04 147 pyrrhotiteFe0.875 -6.02 -9.02 -3.01 -1.105 0.51316E+04 148 pyroxmangite 7.40 6.09 -1.31 -0.261 0.22323E+04 149 pyrophyllite -6.18 -11.15 -4.97 -0.311 0.84932E+04 150 quartz -2.99 -3.15 -0.16 -0.052 0.26707E+03 154 rhodochrosite -0.98 -5.27 -4.30 -1.432 0.73337E+04 155 rhodonite 7.45 6.09 -1.35 -0.271 0.23126E+04 156 sanidine -1.28 -2.49 -1.21 -0.093 0.20679E+04 166 stilbite -7.52 -7.61 -0.09 -0.004 0.14531E+03 167 stilpnomelane-Fe 13.02 12.47 -0.55 -0.016 0.93569E+03 168 stilpnomelane-Mg 27.44 25.74 -1.70 -0.051 0.29085E+04 174 talc 16.49 15.23 -1.26 -0.074 0.21547E+04 177 tephroite 18.09 15.33 -2.76 -0.394 0.47081E+04 181 tridymite -2.63 -3.15 -0.52 -0.173 0.88704E+03 182 tremolite 47.87 47.15 -0.72 -0.019 0.12313E+04 183 ferroactinolite 38.45 33.88 -4.57 -0.124 0.78087E+04 184 troilite-low -4.41 -7.72 -3.31 -1.102 0.56471E+04 190 wairakite 3.95 1.83 -2.12 -0.125 0.36200E+04 191 walstromite 11.51 9.83 -1.67 -0.335 0.28596E+04 192 wollastonite 10.46 9.83 -0.63 -0.125 0.10700E+04 193 pseudo-wollastonite 11.00 9.83 -1.17 -0.233 0.19898E+04 194 zoisite 22.85 18.67 -4.18 -0.190 0.71306E+04 195 akaganeite 7.75 4.69 -3.06 -0.662 0.52262E+04 202 chalcedony -2.80 -3.15 -0.34 -0.114 0.58636E+03 204 montmorillonite-Ca -2.29 -6.19 -3.89 -0.241 0.66500E+04 205 montmorillonite-K -2.24 -6.27 -4.03 -0.247 0.68864E+04 206 montmorillonite-Mg -2.48 -6.80 -4.32 -0.267 0.73721E+04 207 montmorillonite-Na -2.04 -5.58 -3.54 -0.217 0.60412E+04 208 nontronite-Ca 3.21 0.22 -2.99 -0.194 0.51120E+04 209 nontronite-H 2.53 -1.92 -4.45 -0.299 0.76048E+04 210 nontronite-K 3.34 0.14 -3.20 -0.206 0.54716E+04 211 nontronite-Mg 3.07 -0.39 -3.47 -0.225 0.59182E+04 212 nontronite-Na 3.52 0.83 -2.69 -0.173 0.45925E+04 228 tobermorite 9.82 7.67 -2.16 -0.588 0.36818E+04 234 alabandite -0.98 -5.10 -4.12 -1.373 0.70352E+04 237 boehmite 4.41 0.72 -3.69 -0.615 0.62999E+04 239 ferrous-oxide 9.81 6.62 -3.19 -0.799 0.54546E+04 245 silica-amorphous -2.09 -3.15 -1.05 -0.352 0.18005E+04 247 an20ab80 2.02 1.32 -0.70 -0.054 0.11960E+04 248 an25ab75 2.65 1.74 -0.90 -0.069 0.15420E+04 249 an30ab70 3.28 2.17 -1.11 -0.085 0.18976E+04 250 tr.625ac.25prg.125 45.16 44.77 -0.40 -0.011 0.67510E+03 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 0.0000400 MOLES Current total amount of reactant added: 0.0016300 MOLES New total amount of reactant added: 0.0016700 MOLES Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.5508E-08 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 7 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 0.0016700 Water: Moles liquid = 0.4985E+02 kg liquid = 0.8981E+00 Moles total = 0.4985E+02 kg total = 0.8980E+00 Activity = 1.0000 Stoichiometric ionic strength = .1143678E-01 Osmotic coef. = 0.9645 True ionic strength = .2011509E-01 Chg. balance for total moles = -.5508E-08 Max. difference allowed = 0.1477E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.90941E-10 -10.0412 0.76391E-10 -10.1170 0.84000E+00 -0.0757 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.16375E-03 -3.7858 0.13672E-03 -3.8642 0.83493E+00 -0.0783 4 SO4-- 0.67289E-09 -9.1721 0.34900E-09 -9.4572 0.51866E+00 -0.2851 5 HCO3- 0.49805E-04 -4.3027 0.41645E-04 -4.3804 0.83616E+00 -0.0777 6 HS- 0.73570E-04 -4.1333 0.61435E-04 -4.2116 0.83506E+00 -0.0783 7 Al+++ 0.10066E-28 -28.9971 0.23189E-29 -29.6347 0.23037E+00 -0.6376 8 H4SiO4 0.71523E-03 -3.1456 0.71523E-03 -3.1456 0.10000E+01 0.0000 9 Ca++ 0.10781E-06 -6.9673 0.55504E-07 -7.2557 0.51483E+00 -0.2883 10 Mg++ 0.21216E-10 -10.6733 0.10873E-10 -10.9637 0.51247E+00 -0.2903 11 Fe++ 0.47123E-13 -13.3268 0.24176E-13 -13.6166 0.51303E+00 -0.2899 12 K+ 0.15652E-03 -3.8054 0.13091E-03 -3.8830 0.83636E+00 -0.0776 13 Na+ 0.19866E-01 -1.7019 0.16584E-01 -1.7803 0.83478E+00 -0.0784 14 Mn++ 0.19619E-10 -10.7073 0.10074E-10 -10.9968 0.51346E+00 -0.2895 15 F- 0.85240E-06 -6.0694 0.71022E-06 -6.1486 0.83321E+00 -0.0792 16 HPO4-- 0.45341E-07 -7.3435 0.23520E-07 -7.6286 0.51873E+00 -0.2851 18 HSiO3- 0.10471E-01 -1.9800 0.87424E-02 -2.0584 0.83493E+00 -0.0783 19 Ca(HSiO3)+ 0.13210E-07 -7.8791 0.11051E-07 -7.9566 0.83654E+00 -0.0775 20 Mg(HSiO3)+ 0.32205E-11 -11.4921 0.26940E-11 -11.5696 0.83654E+00 -0.0775 21 NaHSiO3,aq 0.23449E-02 -2.6299 0.23449E-02 -2.6299 0.10000E+01 0.0000 22 AlO+ 0.64623E-16 -16.1896 0.54059E-16 -16.2671 0.83654E+00 -0.0775 24 HAlO2,aq 0.14093E-09 -9.8510 0.14093E-09 -9.8510 0.10000E+01 0.0000 25 AlO2- 0.49000E-05 -5.3098 0.40838E-05 -5.3889 0.83342E+00 -0.0791 26 CH4,aq 0.71460E-05 -5.1459 0.71210E-05 -5.1475 0.99651E+00 -0.0015 27 C2H6,aq 0.32951E-14 -14.4821 0.32836E-14 -14.4837 0.99651E+00 -0.0015 31 CO,aq 0.45083E-15 -15.3460 0.45083E-15 -15.3460 0.10000E+01 0.0000 32 CO2,aq 0.68214E-08 -8.1661 0.67977E-08 -8.1676 0.99651E+00 -0.0015 33 CO3-2 0.92005E-04 -4.0362 0.47617E-04 -4.3222 0.51755E+00 -0.2860 34 CaCO3,aq 0.33140E-07 -7.4797 0.33140E-07 -7.4797 0.10000E+01 0.0000 35 Ca(HCO3)+ 0.70532E-10 -10.1516 0.59003E-10 -10.2291 0.83654E+00 -0.0775 36 CaCl+ 0.14680E-10 -10.8333 0.12281E-10 -10.9108 0.83654E+00 -0.0775 37 CaCl2,aq 0.39890E-15 -15.3991 0.39890E-15 -15.3991 0.10000E+01 0.0000 38 CaF+ 0.68800E-12 -12.1624 0.57554E-12 -12.2399 0.83654E+00 -0.0775 39 CaOH+ 0.61902E-07 -7.2083 0.51783E-07 -7.2858 0.83654E+00 -0.0775 40 CaSO4,aq 0.61511E-14 -14.2110 0.61511E-14 -14.2110 0.10000E+01 0.0000 41 HCl,aq 0.19139E-14 -14.7181 0.19139E-14 -14.7181 0.10000E+01 0.0000 45 HF,aq 0.37141E-12 -12.4301 0.37141E-12 -12.4301 0.10000E+01 0.0000 46 HF2- 0.10667E-18 -18.9720 0.89060E-19 -19.0503 0.83493E+00 -0.0783 48 FeCl+ 0.62541E-17 -17.2038 0.52318E-17 -17.2813 0.83654E+00 -0.0775 51 FeF+ 0.10489E-17 -17.9793 0.87742E-18 -18.0568 0.83654E+00 -0.0775 53 FeO,aq 0.16101E-09 -9.7931 0.16101E-09 -9.7931 0.10000E+01 0.0000 54 FeOH+ 0.12315E-10 -10.9096 0.10302E-10 -10.9871 0.83654E+00 -0.0775 55 HFeO2- 0.26414E-07 -7.5782 0.22054E-07 -7.6565 0.83493E+00 -0.0783 56 FeO+ 0.18077E-16 -16.7429 0.15122E-16 -16.8204 0.83654E+00 -0.0775 58 FeO2- 0.63509E-09 -9.1972 0.53026E-09 -9.2755 0.83493E+00 -0.0783 59 HFeO2,aq 0.51519E-11 -11.2880 0.51519E-11 -11.2880 0.10000E+01 0.0000 60 H2,aq 0.26493E-05 -5.5769 0.26401E-05 -5.5784 0.99651E+00 -0.0015 61 KCl,aq 0.32439E-09 -9.4889 0.32439E-09 -9.4889 0.10000E+01 0.0000 63 KOH,aq 0.73184E-06 -6.1356 0.73184E-06 -6.1356 0.10000E+01 0.0000 64 KSO4- 0.84912E-12 -12.0710 0.70896E-12 -12.1494 0.83493E+00 -0.0783 65 MgCO3,aq 0.16272E-11 -11.7886 0.16272E-11 -11.7886 0.10000E+01 0.0000 66 Mg(HCO3)+ 0.14118E-13 -13.8502 0.11810E-13 -13.9277 0.83654E+00 -0.0775 67 MgCl+ 0.26064E-14 -14.5840 0.21804E-14 -14.6615 0.83654E+00 -0.0775 68 MgF+ 0.49924E-15 -15.3017 0.41763E-15 -15.3792 0.83654E+00 -0.0775 69 MgOH+ 0.67099E-10 -10.1733 0.56131E-10 -10.2508 0.83654E+00 -0.0775 71 MnF+ 0.14406E-15 -15.8415 0.12051E-15 -15.9190 0.83654E+00 -0.0775 72 MnO,aq 0.17877E-08 -8.7477 0.17877E-08 -8.7477 0.10000E+01 0.0000 73 MnOH+ 0.47669E-09 -9.3218 0.39877E-09 -9.3993 0.83654E+00 -0.0775 74 MnO2-2 0.19644E-10 -10.7068 0.10167E-10 -10.9928 0.51755E+00 -0.2860 75 HMnO2- 0.20380E-09 -9.6908 0.17016E-09 -9.7692 0.83493E+00 -0.0783 78 MnCl+ 0.10139E-13 -13.9940 0.84813E-14 -14.0715 0.83654E+00 -0.0775 79 MnSO4,aq 0.10150E-17 -17.9935 0.10150E-17 -17.9935 0.10000E+01 0.0000 80 NaCl,aq 0.75141E-06 -6.1241 0.75141E-06 -6.1241 0.10000E+01 0.0000 81 NaF,aq 0.27575E-08 -8.5595 0.27575E-08 -8.5595 0.10000E+01 0.0000 82 NaOH,aq 0.93273E-04 -4.0302 0.93273E-04 -4.0302 0.10000E+01 0.0000 84 OH- 0.90751E-02 -2.0421 0.75634E-02 -2.1213 0.83342E+00 -0.0791 89 HPO3-2 0.37389E-15 -15.4273 0.19351E-15 -15.7133 0.51755E+00 -0.2860 91 H2PO3- 0.35503E-19 -19.4497 0.29643E-19 -19.5281 0.83493E+00 -0.0783 92 H3PO4,aq 0.95993E-18 -18.0178 0.95993E-18 -18.0178 0.10000E+01 0.0000 93 H2PO4- 0.39659E-10 -10.4017 0.33144E-10 -10.4796 0.83573E+00 -0.0779 94 PO4-3 0.10380E-08 -8.9838 0.25120E-09 -9.6000 0.24200E+00 -0.6162 98 HP2O7-3 0.97638E-18 -18.0104 0.22515E-18 -18.6475 0.23060E+00 -0.6371 99 P2O7-4 0.91775E-17 -17.0373 0.70412E-18 -18.1524 0.76722E-01 -1.1151 100 H2S,aq 0.14555E-07 -7.8370 0.14504E-07 -7.8385 0.99651E+00 -0.0015 101 S2-2 0.61205E-13 -13.2132 0.31677E-13 -13.4993 0.51755E+00 -0.2860 107 SO3-2 0.22804E-15 -15.6420 0.11973E-15 -15.9218 0.52506E+00 -0.2798 108 HSO3- 0.68591E-18 -18.1637 0.57269E-18 -18.2421 0.83493E+00 -0.0783 109 HSO4- 0.30683E-16 -16.5131 0.25693E-16 -16.5902 0.83736E+00 -0.0771 111 S2O3-2 0.11489E-18 -18.9397 0.59463E-19 -19.2258 0.51755E+00 -0.2860 Charge balance for all species = -.6133E-08 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.9094105E-10 -.2209726E-01 -.2223388E+02 0.0000 2 H2O 0.1000000E+01 0.5550462E+02 0.9981889E+06 0.0000 3 Cl- 0.1637510E-03 0.1645028E-03 0.5821948E+01 6.2528 4 SO4-- 0.6728882E-09 -.7807547E-05 -.7486977E+00 10.7767 5 HCO3- 0.4980511E-04 0.1489962E-03 0.9075479E+01 5.7365 6 HS- 0.7356978E-04 0.8139256E-04 0.2687121E+01 5.9054 7 Al+++ 0.1006593E-28 0.4900167E-05 0.1319833E+00 0.7162 8 H4SiO4 0.7152278E-03 0.1353091E-01 0.1298261E+04 -3.1456 9 Ca++ 0.1078097E-06 0.2161471E-06 0.8647640E-02 12.9782 10 Mg++ 0.2121623E-10 0.9317986E-10 0.2261439E-05 9.2703 11 Fe++ 0.4712327E-13 0.2722765E-07 0.1517931E-02 6.6173 12 K+ 0.1565243E-03 0.1572565E-03 0.6138320E+01 6.2339 13 Na+ 0.1986611E-01 0.2230503E-01 0.5118941E+03 8.3366 14 Mn++ 0.1961939E-10 0.2507494E-08 0.1375165E-03 9.2371 15 F- 0.8523959E-06 0.8551545E-06 0.1621790E-01 3.9684 16 HPO4-- 0.4534136E-07 0.4641907E-07 0.4447487E-02 12.6054 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.1984672E-01 -.1984518E-01 -.1540397E-05 0.0000000E+00 2 H2O 0.4984778E+02 0.4984778E+02 -.1497763E-05 0.0000000E+00 3 Cl- 0.1477372E-03 0.1477372E-03 0.0000000E+00 0.0000000E+00 4 SO4-- -.7010810E-05 -.7011827E-05 0.1017447E-08 0.0000000E+00 5 HCO3- 0.1338110E-03 0.1338110E-03 0.0000000E+00 0.0000000E+00 6 HS- 0.7309628E-04 0.7309730E-04 -.1017447E-08 0.0000000E+00 7 Al+++ 0.4775352E-05 0.4400758E-05 0.3745939E-06 0.0000000E+00 8 H4SiO4 0.1215302E-01 0.1215189E-01 0.1134235E-05 0.0000000E+00 9 Ca++ 0.2080835E-06 0.1941181E-06 0.1396536E-07 0.0000000E+00 10 Mg++ 0.8368328E-10 0.8368328E-10 0.0000000E+00 0.0000000E+00 11 Fe++ 0.3259227E-07 0.2445270E-07 0.8139573E-08 0.0000000E+00 12 K+ 0.1412294E-03 0.1412294E-03 0.0000000E+00 0.0000000E+00 13 Na+ 0.2003215E-01 0.2003178E-01 0.3734232E-06 0.0000000E+00 14 Mn++ 0.2251939E-08 0.2251939E-08 0.0000000E+00 0.0000000E+00 15 F- 0.7680000E-06 0.7680000E-06 0.0000000E+00 0.0000000E+00 16 HPO4-- 0.4168819E-07 0.4168819E-07 0.0000000E+00 0.0000000E+00 Chg. balance for solid moles: -.1588E-21 Mass of aqueous solution: 0.899652E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 0.0016700 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 0.3734E-06 -6.428 0.9792E-04 -4.009 97.67 0.3759E-04 andradite 0.4070E-08 -8.390 0.2068E-05 -5.684 2.063 0.5373E-06 grossular 0.5853E-09 -9.233 0.2637E-06 -6.579 0.2630 0.7336E-07 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8743E+00 0.8743E+00 1.0000 -0.058 grossular 0.1257E+00 0.1257E+00 1.0000 -0.901 Solid products produced: Mass = 0.000100 g Volume = 0.000038 cm3 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.0016700 moles log = -2.7773 Original solution: 1000.0103000 g Original solution / Rock added: 598808.56 (Water/Rock Ratio), log = 5.7773 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0343 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9866E+00 0.9858 0.1006E+01 0.1020E+01 CO2,gas 0.6983E-06 1.0070 0.7273E-06 0.7222E-06 CH4,gas 0.1001E-01 1.0124 0.1048E-01 0.1035E-01 H2,gas 0.3349E-02 1.0006 0.3466E-02 0.3464E-02 H2S,gas 0.3870E-06 0.9960 0.3987E-06 0.4003E-06 S2,gas 0.4802E-27 1.0000 0.4967E-27 0.4967E-27 CO,gas 0.6495E-12 1.0000 0.6718E-12 0.6718E-12 SO3,gas 0.7445E-45 1.0000 0.7700E-45 0.7700E-45 SO2,gas 0.1004E-24 1.0000 0.1038E-24 0.1038E-24 HF,gas 0.8817E-15 1.0000 0.9119E-15 0.9119E-15 HCl,gas 0.3265E-17 1.0000 0.3377E-17 0.3377E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 17 albite -0.38 -0.38 0.00 0.000 0.11184E-10 23 andradite 39.01 39.01 0.00 0.000 -0.12132E-10 24 grossular 32.73 32.73 0.00 0.000 -0.12132E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -14.50 -7.84 -2.612 0.13382E+05 -6.138 3 CH4,gas 4.54 0.87 -3.68 -0.920 0.62810E+04 -1.980 4 H2,gas 8.00 3.84 -4.16 -2.377 0.71016E+04 -2.460 5 H2S,gas -6.23 -14.33 -8.10 -4.049 0.13828E+05 -6.399 6 S2,gas -7.34 -36.34 -29.00 -4.462 0.49522E+05 -27.304 7 CO,gas 3.21 -10.66 -13.87 -4.268 0.23686E+05 -12.173 8 SO3,gas 17.12 -29.69 -46.81 -11.703 0.79931E+05 -45.113 9 SO2,gas 0.83 -25.85 -26.68 -7.115 0.45560E+05 -24.984 10 HF,gas 0.47 -16.27 -16.74 -8.370 0.28581E+05 -15.040 11 HCl,gas 5.19 -13.98 -19.17 -9.585 0.32733E+05 -17.471 12 acmite 7.71 6.74 -0.97 -0.100 0.16515E+04 16 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 20 spessartine 24.46 19.71 -4.75 -0.238 0.81111E+04 21 analcite 3.32 2.76 -0.56 -0.062 0.95648E+03 27 annite 20.12 17.37 -2.76 -0.153 0.47093E+04 28 phlogopite 27.06 25.32 -1.74 -0.097 0.29717E+04 30 anorthite 12.71 8.12 -4.59 -0.353 0.78388E+04 33 apatite-OH -18.15 -18.70 -0.54 -0.042 0.92671E+03 34 apatite-F -34.30 -34.96 -0.66 -0.055 0.11283E+04 38 aragonite 0.97 -1.52 -2.49 -0.829 0.42442E+04 39 brucite 12.57 9.27 -3.30 -0.660 0.56318E+04 40 calcite 0.81 -1.52 -2.33 -0.777 0.39800E+04 41 carnegieite-low 9.02 5.91 -3.12 -0.445 0.53206E+04 42 carnegieite-high 10.09 5.91 -4.19 -0.598 0.71476E+04 43 carpholite-Mg 8.58 4.41 -4.17 -0.278 0.71212E+04 44 carpholite-Fe 6.71 1.76 -4.95 -0.330 0.84591E+04 45 celadonite 5.34 3.64 -1.70 -0.100 0.29086E+04 46 celadonite-Fe 3.88 0.99 -2.89 -0.170 0.49369E+04 47 chrysotile 23.89 21.52 -2.37 -0.198 0.40514E+04 49 clinochlore 39.07 38.35 -0.72 -0.023 0.12338E+04 50 daphnite 28.97 25.08 -3.88 -0.121 0.66303E+04 52 chlorite-Al-free 47.17 43.04 -4.13 -0.172 0.70579E+04 54 chloritoid-Fe 9.17 4.90 -4.27 -0.285 0.72902E+04 55 chloritoid-Mn 11.40 7.52 -3.88 -0.258 0.66202E+04 57 coesite -2.38 -3.15 -0.77 -0.256 0.13139E+04 64 cristobalite -2.56 -3.15 -0.59 -0.195 0.99924E+03 66 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71235E+04 68 diaspore 2.87 0.72 -2.16 -0.360 0.36839E+04 69 diamond -3.10 -6.82 -3.71 -1.061 0.63411E+04 70 diopside 16.18 15.96 -0.22 -0.022 0.38242E+03 71 hedenbergite 14.21 13.30 -0.90 -0.090 0.15433E+04 76 clinoenstatite 17.17 12.25 -4.92 -0.492 0.83954E+04 78 epidote 24.67 22.65 -2.02 -0.098 0.34505E+04 79 clinozoisite 22.81 18.67 -4.14 -0.188 0.70651E+04 80 epidote-Fe 29.84 26.63 -3.21 -0.167 0.54825E+04 81 fayalite 14.05 10.09 -3.96 -0.565 0.67559E+04 82 ferrosilite 11.15 6.94 -4.21 -0.421 0.71816E+04 86 gibbsite 4.08 0.72 -3.36 -0.480 0.57425E+04 87 glaucophane 22.97 20.75 -2.22 -0.060 0.37955E+04 88 glaucophane-Fe 17.28 12.79 -4.48 -0.121 0.76542E+04 89 graphite -3.55 -6.82 -3.27 -0.934 0.55833E+04 90 greenalite 16.14 13.56 -2.58 -0.215 0.44031E+04 93 hematite 12.57 9.39 -3.17 -0.385 0.54165E+04 94 heulandite -5.83 -7.61 -1.78 -0.081 0.30412E+04 98 jadeite 4.22 2.76 -1.45 -0.145 0.24820E+04 100 kalsilite 7.58 3.80 -3.78 -0.540 0.64532E+04 101 kaolinite -1.33 -4.86 -3.53 -0.321 0.60206E+04 104 laumontite 2.88 1.83 -1.06 -0.070 0.18015E+04 105 lawsonite 9.62 8.12 -1.50 -0.100 0.25555E+04 106 leucite 4.12 0.66 -3.46 -0.346 0.59077E+04 108 lizardite 23.24 21.52 -1.72 -0.144 0.29440E+04 110 magnetite 20.09 16.01 -4.08 -0.333 0.69599E+04 111 minnesotaite 10.39 7.27 -3.12 -0.183 0.53246E+04 115 manganosite 14.06 9.24 -4.82 -1.205 0.82317E+04 119 microcline -2.49 -2.49 0.00 0.000 0.14295E+00 123 muscovite 2.58 -1.05 -3.64 -0.214 0.62096E+04 124 paragonite 4.24 1.05 -3.19 -0.188 0.54485E+04 125 nepheline 8.34 5.91 -2.43 -0.347 0.41529E+04 137 phlogopite-Na 29.65 27.43 -2.22 -0.123 0.37904E+04 139 prehnite 19.37 17.95 -1.42 -0.084 0.24242E+04 140 prehnite-Fe 22.50 21.93 -0.56 -0.034 0.96456E+03 141 pumpellyite-Fe 46.27 43.24 -3.03 -0.067 0.51766E+04 142 pumpellyite-Mg 48.99 45.89 -3.10 -0.069 0.53003E+04 145 pyrite -21.25 -25.88 -4.63 -1.090 0.79116E+04 146 pyrrhotite -4.26 -7.71 -3.45 -1.150 0.58924E+04 147 pyrrhotiteFe0.875 -6.02 -9.01 -3.00 -1.102 0.51185E+04 148 pyroxmangite 7.40 6.09 -1.31 -0.261 0.22319E+04 149 pyrophyllite -6.18 -11.15 -4.97 -0.311 0.84932E+04 150 quartz -2.99 -3.15 -0.16 -0.052 0.26657E+03 154 rhodochrosite -0.98 -5.26 -4.28 -1.428 0.73148E+04 155 rhodonite 7.45 6.09 -1.35 -0.271 0.23121E+04 156 sanidine -1.28 -2.49 -1.21 -0.093 0.20679E+04 166 stilbite -7.52 -7.61 -0.09 -0.004 0.14733E+03 167 stilpnomelane-Fe 13.02 12.47 -0.55 -0.016 0.93165E+03 168 stilpnomelane-Mg 27.44 25.74 -1.71 -0.051 0.29117E+04 174 talc 16.49 15.23 -1.26 -0.074 0.21557E+04 177 tephroite 18.09 15.33 -2.76 -0.394 0.47077E+04 181 tridymite -2.63 -3.15 -0.52 -0.173 0.88655E+03 182 tremolite 47.87 47.14 -0.73 -0.020 0.12395E+04 183 ferroactinolite 38.45 33.88 -4.57 -0.124 0.78097E+04 184 troilite-low -4.41 -7.71 -3.30 -1.100 0.56352E+04 190 wairakite 3.95 1.83 -2.12 -0.125 0.36235E+04 191 walstromite 11.51 9.83 -1.68 -0.335 0.28626E+04 192 wollastonite 10.46 9.83 -0.63 -0.126 0.10731E+04 193 pseudo-wollastonite 11.00 9.83 -1.17 -0.233 0.19929E+04 194 zoisite 22.85 18.67 -4.18 -0.190 0.71391E+04 195 akaganeite 7.75 4.70 -3.06 -0.661 0.52208E+04 202 chalcedony -2.80 -3.15 -0.34 -0.114 0.58587E+03 204 montmorillonite-Ca -2.29 -6.19 -3.89 -0.241 0.66505E+04 205 montmorillonite-K -2.24 -6.27 -4.03 -0.247 0.68865E+04 206 montmorillonite-Mg -2.48 -6.80 -4.32 -0.267 0.73722E+04 207 montmorillonite-Na -2.04 -5.58 -3.54 -0.217 0.60413E+04 208 nontronite-Ca 3.21 0.23 -2.99 -0.194 0.51003E+04 209 nontronite-H 2.53 -1.91 -4.45 -0.298 0.75924E+04 210 nontronite-K 3.34 0.14 -3.20 -0.205 0.54595E+04 211 nontronite-Mg 3.07 -0.38 -3.46 -0.224 0.59060E+04 212 nontronite-Na 3.52 0.84 -2.68 -0.172 0.45803E+04 228 tobermorite 9.82 7.67 -2.16 -0.589 0.36843E+04 234 alabandite -0.98 -5.09 -4.11 -1.371 0.70238E+04 237 boehmite 4.41 0.72 -3.69 -0.615 0.63009E+04 239 ferrous-oxide 9.81 6.62 -3.19 -0.799 0.54541E+04 245 silica-amorphous -2.09 -3.15 -1.05 -0.351 0.18000E+04 247 an20ab80 2.02 1.32 -0.70 -0.054 0.11969E+04 248 an25ab75 2.65 1.74 -0.90 -0.070 0.15431E+04 249 an30ab70 3.28 2.17 -1.11 -0.086 0.18989E+04 250 tr.625ac.25prg.125 45.16 44.77 -0.40 -0.011 0.68190E+03 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 0.0000400 MOLES Current total amount of reactant added: 0.0016700 MOLES New total amount of reactant added: 0.0017100 MOLES Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.5508E-08 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 7 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 0.0017100 Water: Moles liquid = 0.4985E+02 kg liquid = 0.8981E+00 Moles total = 0.4985E+02 kg total = 0.8980E+00 Activity = 1.0000 Stoichiometric ionic strength = .1143934E-01 Osmotic coef. = 0.9644 True ionic strength = .2011744E-01 Chg. balance for total moles = -.5508E-08 Max. difference allowed = 0.1480E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.91007E-10 -10.0409 0.76445E-10 -10.1166 0.84000E+00 -0.0757 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.16401E-03 -3.7851 0.13694E-03 -3.8635 0.83493E+00 -0.0784 4 SO4-- 0.72012E-09 -9.1426 0.37349E-09 -9.4277 0.51864E+00 -0.2851 5 HCO3- 0.51030E-04 -4.2922 0.42669E-04 -4.3699 0.83615E+00 -0.0777 6 HS- 0.74652E-04 -4.1270 0.62338E-04 -4.2052 0.83505E+00 -0.0783 7 Al+++ 0.10075E-28 -28.9967 0.23208E-29 -29.6344 0.23035E+00 -0.6376 8 H4SiO4 0.71571E-03 -3.1453 0.71571E-03 -3.1453 0.10000E+01 0.0000 9 Ca++ 0.10745E-06 -6.9688 0.55316E-07 -7.2571 0.51482E+00 -0.2883 10 Mg++ 0.21219E-10 -10.6733 0.10874E-10 -10.9636 0.51245E+00 -0.2903 11 Fe++ 0.47219E-13 -13.3259 0.24224E-13 -13.6158 0.51302E+00 -0.2899 12 K+ 0.15652E-03 -3.8054 0.13091E-03 -3.8830 0.83635E+00 -0.0776 13 Na+ 0.19866E-01 -1.7019 0.16584E-01 -1.7803 0.83477E+00 -0.0784 14 Mn++ 0.19646E-10 -10.7067 0.10087E-10 -10.9962 0.51344E+00 -0.2895 15 F- 0.87015E-06 -6.0604 0.72501E-06 -6.1397 0.83320E+00 -0.0793 16 HPO4-- 0.45342E-07 -7.3435 0.23520E-07 -7.6286 0.51871E+00 -0.2851 18 HSiO3- 0.10470E-01 -1.9800 0.87420E-02 -2.0584 0.83493E+00 -0.0784 19 Ca(HSiO3)+ 0.13165E-07 -7.8806 0.11013E-07 -7.9581 0.83653E+00 -0.0775 20 Mg(HSiO3)+ 0.32206E-11 -11.4921 0.26941E-11 -11.5696 0.83653E+00 -0.0775 21 NaHSiO3,aq 0.23448E-02 -2.6299 0.23448E-02 -2.6299 0.10000E+01 0.0000 22 AlO+ 0.64586E-16 -16.1899 0.54028E-16 -16.2674 0.83653E+00 -0.0775 24 HAlO2,aq 0.14075E-09 -9.8516 0.14075E-09 -9.8516 0.10000E+01 0.0000 25 AlO2- 0.48902E-05 -5.3107 0.40756E-05 -5.3898 0.83341E+00 -0.0791 26 CH4,aq 0.69422E-05 -5.1585 0.69180E-05 -5.1600 0.99651E+00 -0.0015 27 C2H6,aq 0.31521E-14 -14.5014 0.31411E-14 -14.5029 0.99651E+00 -0.0015 31 CO,aq 0.45606E-15 -15.3410 0.45606E-15 -15.3410 0.10000E+01 0.0000 32 CO2,aq 0.69942E-08 -8.1553 0.69698E-08 -8.1568 0.99651E+00 -0.0015 33 CO3-2 0.94203E-04 -4.0259 0.48753E-04 -4.3120 0.51754E+00 -0.2861 34 CaCO3,aq 0.33816E-07 -7.4709 0.33816E-07 -7.4709 0.10000E+01 0.0000 35 Ca(HCO3)+ 0.72022E-10 -10.1425 0.60249E-10 -10.2201 0.83653E+00 -0.0775 36 CaCl+ 0.14654E-10 -10.8340 0.12259E-10 -10.9116 0.83653E+00 -0.0775 37 CaCl2,aq 0.39882E-15 -15.3992 0.39882E-15 -15.3992 0.10000E+01 0.0000 38 CaF+ 0.69996E-12 -12.1549 0.58554E-12 -12.2324 0.83653E+00 -0.0775 39 CaOH+ 0.61649E-07 -7.2101 0.51571E-07 -7.2876 0.83653E+00 -0.0775 40 CaSO4,aq 0.65605E-14 -14.1831 0.65605E-14 -14.1831 0.10000E+01 0.0000 41 HCl,aq 0.19183E-14 -14.7171 0.19183E-14 -14.7171 0.10000E+01 0.0000 45 HF,aq 0.37941E-12 -12.4209 0.37941E-12 -12.4209 0.10000E+01 0.0000 46 HF2- 0.11124E-18 -18.9538 0.92874E-19 -19.0321 0.83493E+00 -0.0784 48 FeCl+ 0.62766E-17 -17.2023 0.52506E-17 -17.2798 0.83653E+00 -0.0775 51 FeF+ 0.10729E-17 -17.9695 0.89748E-18 -18.0470 0.83653E+00 -0.0775 53 FeO,aq 0.16111E-09 -9.7929 0.16111E-09 -9.7929 0.10000E+01 0.0000 54 FeOH+ 0.12330E-10 -10.9090 0.10315E-10 -10.9865 0.83653E+00 -0.0775 55 HFeO2- 0.26410E-07 -7.5782 0.22051E-07 -7.6566 0.83493E+00 -0.0784 56 FeO+ 0.18223E-16 -16.7394 0.15244E-16 -16.8169 0.83653E+00 -0.0775 58 FeO2- 0.63930E-09 -9.1943 0.53377E-09 -9.2726 0.83493E+00 -0.0784 59 HFeO2,aq 0.51896E-11 -11.2849 0.51896E-11 -11.2849 0.10000E+01 0.0000 60 H2,aq 0.26139E-05 -5.5827 0.26047E-05 -5.5842 0.99651E+00 -0.0015 61 KCl,aq 0.32490E-09 -9.4882 0.32490E-09 -9.4882 0.10000E+01 0.0000 63 KOH,aq 0.73132E-06 -6.1359 0.73132E-06 -6.1359 0.10000E+01 0.0000 64 KSO4- 0.90870E-12 -12.0416 0.75870E-12 -12.1199 0.83493E+00 -0.0784 65 MgCO3,aq 0.16662E-11 -11.7783 0.16662E-11 -11.7783 0.10000E+01 0.0000 66 Mg(HCO3)+ 0.14466E-13 -13.8396 0.12102E-13 -13.9172 0.83653E+00 -0.0775 67 MgCl+ 0.26108E-14 -14.5832 0.21840E-14 -14.6607 0.83653E+00 -0.0775 68 MgF+ 0.50968E-15 -15.2927 0.42636E-15 -15.3702 0.83653E+00 -0.0775 69 MgOH+ 0.67057E-10 -10.1736 0.56095E-10 -10.2511 0.83653E+00 -0.0775 71 MnF+ 0.14726E-15 -15.8319 0.12319E-15 -15.9094 0.83653E+00 -0.0775 72 MnO,aq 0.17876E-08 -8.7477 0.17876E-08 -8.7477 0.10000E+01 0.0000 73 MnOH+ 0.47699E-09 -9.3215 0.39902E-09 -9.3990 0.83653E+00 -0.0775 74 MnO2-2 0.19615E-10 -10.7074 0.10152E-10 -10.9935 0.51754E+00 -0.2861 75 HMnO2- 0.20363E-09 -9.6911 0.17002E-09 -9.7695 0.83493E+00 -0.0784 78 MnCl+ 0.10168E-13 -13.9927 0.85063E-14 -14.0703 0.83653E+00 -0.0775 79 MnSO4,aq 0.10876E-17 -17.9635 0.10876E-17 -17.9635 0.10000E+01 0.0000 80 NaCl,aq 0.75260E-06 -6.1234 0.75260E-06 -6.1234 0.10000E+01 0.0000 81 NaF,aq 0.28149E-08 -8.5505 0.28149E-08 -8.5505 0.10000E+01 0.0000 82 NaOH,aq 0.93207E-04 -4.0306 0.93207E-04 -4.0306 0.10000E+01 0.0000 84 OH- 0.90687E-02 -2.0425 0.75580E-02 -2.1216 0.83341E+00 -0.0791 89 HPO3-2 0.36889E-15 -15.4331 0.19091E-15 -15.7192 0.51754E+00 -0.2861 91 H2PO3- 0.35053E-19 -19.4553 0.29266E-19 -19.5336 0.83493E+00 -0.0784 92 H3PO4,aq 0.96129E-18 -18.0171 0.96129E-18 -18.0171 0.10000E+01 0.0000 93 H2PO4- 0.39687E-10 -10.4013 0.33167E-10 -10.4793 0.83572E+00 -0.0779 94 PO4-3 0.10374E-08 -8.9841 0.25102E-09 -9.6003 0.24198E+00 -0.6162 98 HP2O7-3 0.97711E-18 -18.0101 0.22531E-18 -18.6472 0.23058E+00 -0.6372 99 P2O7-4 0.91783E-17 -17.0372 0.70409E-18 -18.1524 0.76713E-01 -1.1151 100 H2S,aq 0.14780E-07 -7.8303 0.14728E-07 -7.8319 0.99651E+00 -0.0015 101 S2-2 0.63875E-13 -13.1947 0.33058E-13 -13.4807 0.51754E+00 -0.2861 107 SO3-2 0.24078E-15 -15.6184 0.12642E-15 -15.8982 0.52505E+00 -0.2798 108 HSO3- 0.72473E-18 -18.1398 0.60510E-18 -18.2182 0.83493E+00 -0.0784 109 HSO4- 0.32860E-16 -16.4833 0.27515E-16 -16.5604 0.83735E+00 -0.0771 111 S2O3-2 0.12485E-18 -18.9036 0.64616E-19 -19.1897 0.51754E+00 -0.2861 Charge balance for all species = -.6133E-08 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.9100676E-10 -.2209241E-01 -.2222899E+02 0.0000 2 H2O 0.1000000E+01 0.5550462E+02 0.9981887E+06 0.0000 3 Cl- 0.1640125E-03 0.1647654E-03 0.5831243E+01 6.2532 4 SO4-- 0.7201242E-09 -.7594865E-05 -.7283027E+00 10.8056 5 HCO3- 0.5103020E-04 0.1522163E-03 0.9271615E+01 5.7468 6 HS- 0.7465176E-04 0.8226212E-04 0.2715829E+01 5.9114 7 Al+++ 0.1007525E-28 0.4890389E-05 0.1317199E+00 0.7156 8 H4SiO4 0.7157061E-03 0.1353087E-01 0.1298257E+04 -3.1453 9 Ca++ 0.1074482E-06 0.2161646E-06 0.8648337E-02 12.9762 10 Mg++ 0.2121864E-10 0.9317979E-10 0.2261437E-05 9.2697 11 Fe++ 0.4721872E-13 0.2722815E-07 0.1517959E-02 6.6175 12 K+ 0.1565247E-03 0.1572563E-03 0.6138315E+01 6.2336 13 Na+ 0.1986626E-01 0.2230500E-01 0.5118934E+03 8.3363 14 Mn++ 0.1964649E-10 0.2507493E-08 0.1375164E-03 9.2371 15 F- 0.8701535E-06 0.8729695E-06 0.1655576E-01 3.9770 16 HPO4-- 0.4534199E-07 0.4641903E-07 0.4447483E-02 12.6047 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.1984242E-01 -.1984084E-01 -.1575485E-05 0.0000000E+00 2 H2O 0.4984781E+02 0.4984781E+02 -.1532913E-05 0.0000000E+00 3 Cl- 0.1479732E-03 0.1479732E-03 0.0000000E+00 0.0000000E+00 4 SO4-- -.6819810E-05 -.6820827E-05 0.1017388E-08 0.0000000E+00 5 HCO3- 0.1367030E-03 0.1367030E-03 0.0000000E+00 0.0000000E+00 6 HS- 0.7387728E-04 0.7387830E-04 -.1017388E-08 0.0000000E+00 7 Al+++ 0.4775352E-05 0.4391981E-05 0.3833715E-06 0.0000000E+00 8 H4SiO4 0.1215302E-01 0.1215186E-01 0.1160582E-05 0.0000000E+00 9 Ca++ 0.2080835E-06 0.1941340E-06 0.1394953E-07 0.0000000E+00 10 Mg++ 0.8368328E-10 0.8368328E-10 0.0000000E+00 0.0000000E+00 11 Fe++ 0.3259227E-07 0.2445317E-07 0.8139104E-08 0.0000000E+00 12 K+ 0.1412294E-03 0.1412294E-03 0.0000000E+00 0.0000000E+00 13 Na+ 0.2003215E-01 0.2003177E-01 0.3822109E-06 0.0000000E+00 14 Mn++ 0.2251939E-08 0.2251939E-08 0.0000000E+00 0.0000000E+00 15 F- 0.7840000E-06 0.7840000E-06 0.0000000E+00 0.0000000E+00 16 HPO4-- 0.4168819E-07 0.4168819E-07 0.0000000E+00 0.0000000E+00 Chg. balance for solid moles: 0.0000E+00 Mass of aqueous solution: 0.899653E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 0.0017100 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 0.3822E-06 -6.418 0.1002E-03 -3.999 97.73 0.3847E-04 andradite 0.4070E-08 -8.390 0.2068E-05 -5.684 2.017 0.5373E-06 grossular 0.5803E-09 -9.236 0.2614E-06 -6.583 0.2549 0.7273E-07 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8752E+00 0.8752E+00 1.0000 -0.058 grossular 0.1248E+00 0.1248E+00 1.0000 -0.904 Solid products produced: Mass = 0.000103 g Volume = 0.000039 cm3 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.0017100 moles log = -2.7670 Original solution: 1000.0103000 g Original solution / Rock added: 584801.35 (Water/Rock Ratio), log = 5.7670 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0340 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9870E+00 0.9858 0.1006E+01 0.1020E+01 CO2,gas 0.7162E-06 1.0070 0.7457E-06 0.7405E-06 CH4,gas 0.9727E-02 1.0124 0.1018E-01 0.1006E-01 H2,gas 0.3306E-02 1.0006 0.3420E-02 0.3418E-02 H2S,gas 0.3931E-06 0.9960 0.4049E-06 0.4065E-06 S2,gas 0.5088E-27 1.0000 0.5261E-27 0.5261E-27 CO,gas 0.6573E-12 1.0000 0.6796E-12 0.6796E-12 SO3,gas 0.7981E-45 1.0000 0.8253E-45 0.8253E-45 SO2,gas 0.1062E-24 1.0000 0.1098E-24 0.1098E-24 HF,gas 0.9010E-15 1.0000 0.9316E-15 0.9316E-15 HCl,gas 0.3274E-17 1.0000 0.3385E-17 0.3385E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 17 albite -0.38 -0.38 0.00 0.000 -0.94784E-12 23 andradite 39.01 39.01 0.00 0.000 0.24265E-10 24 grossular 32.73 32.73 0.00 0.000 0.00000E+00 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -14.49 -7.83 -2.609 0.13363E+05 -6.127 3 CH4,gas 4.54 0.85 -3.69 -0.923 0.63025E+04 -1.992 4 H2,gas 8.00 3.83 -4.16 -2.380 0.71116E+04 -2.466 5 H2S,gas -6.23 -14.32 -8.09 -4.046 0.13816E+05 -6.393 6 S2,gas -7.34 -36.31 -28.98 -4.458 0.49479E+05 -27.279 7 CO,gas 3.21 -10.65 -13.87 -4.267 0.23677E+05 -12.168 8 SO3,gas 17.12 -29.66 -46.78 -11.696 0.79880E+05 -45.083 9 SO2,gas 0.83 -25.83 -26.66 -7.109 0.45518E+05 -24.959 10 HF,gas 0.47 -16.26 -16.73 -8.365 0.28566E+05 -15.031 11 HCl,gas 5.19 -13.98 -19.17 -9.585 0.32731E+05 -17.470 12 acmite 7.71 6.75 -0.96 -0.100 0.16456E+04 16 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 20 spessartine 24.46 19.71 -4.75 -0.238 0.81117E+04 21 analcite 3.32 2.76 -0.56 -0.062 0.95697E+03 27 annite 20.12 17.37 -2.76 -0.153 0.47081E+04 28 phlogopite 27.06 25.32 -1.74 -0.097 0.29747E+04 30 anorthite 12.71 8.12 -4.59 -0.353 0.78433E+04 33 apatite-OH -18.15 -18.70 -0.55 -0.042 0.94144E+03 34 apatite-F -34.30 -34.96 -0.66 -0.055 0.11272E+04 38 aragonite 0.97 -1.51 -2.48 -0.826 0.42292E+04 39 brucite 12.57 9.27 -3.30 -0.660 0.56328E+04 40 calcite 0.81 -1.51 -2.32 -0.774 0.39650E+04 41 carnegieite-low 9.02 5.91 -3.12 -0.445 0.53216E+04 42 carnegieite-high 10.09 5.91 -4.19 -0.598 0.71486E+04 43 carpholite-Mg 8.58 4.41 -4.17 -0.278 0.71232E+04 44 carpholite-Fe 6.71 1.76 -4.95 -0.330 0.84596E+04 45 celadonite 5.34 3.64 -1.70 -0.100 0.29092E+04 46 celadonite-Fe 3.88 0.99 -2.89 -0.170 0.49360E+04 47 chrysotile 23.89 21.52 -2.37 -0.198 0.40534E+04 49 clinochlore 39.07 38.34 -0.73 -0.023 0.12392E+04 50 daphnite 28.97 25.08 -3.88 -0.121 0.66286E+04 52 chlorite-Al-free 47.17 43.04 -4.14 -0.172 0.70619E+04 54 chloritoid-Fe 9.17 4.90 -4.27 -0.285 0.72912E+04 55 chloritoid-Mn 11.40 7.52 -3.88 -0.259 0.66217E+04 57 coesite -2.38 -3.15 -0.77 -0.256 0.13134E+04 64 cristobalite -2.56 -3.15 -0.58 -0.195 0.99875E+03 66 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71235E+04 68 diaspore 2.87 0.72 -2.16 -0.360 0.36849E+04 69 diamond -3.10 -6.82 -3.71 -1.061 0.63426E+04 70 diopside 16.18 15.96 -0.23 -0.023 0.38600E+03 71 hedenbergite 14.21 13.30 -0.91 -0.091 0.15455E+04 76 clinoenstatite 17.17 12.25 -4.92 -0.492 0.83964E+04 78 epidote 24.67 22.65 -2.02 -0.098 0.34526E+04 79 clinozoisite 22.81 18.66 -4.14 -0.188 0.70736E+04 80 epidote-Fe 29.84 26.63 -3.21 -0.167 0.54782E+04 81 fayalite 14.05 10.09 -3.96 -0.565 0.67546E+04 82 ferrosilite 11.15 6.94 -4.20 -0.420 0.71797E+04 86 gibbsite 4.08 0.72 -3.36 -0.481 0.57434E+04 87 glaucophane 22.97 20.75 -2.22 -0.060 0.37975E+04 88 glaucophane-Fe 17.28 12.79 -4.48 -0.121 0.76520E+04 89 graphite -3.55 -6.82 -3.27 -0.935 0.55848E+04 90 greenalite 16.14 13.56 -2.58 -0.215 0.44008E+04 93 hematite 12.57 9.40 -3.17 -0.384 0.54056E+04 94 heulandite -5.83 -7.61 -1.78 -0.081 0.30432E+04 98 jadeite 4.22 2.76 -1.45 -0.145 0.24825E+04 100 kalsilite 7.58 3.80 -3.78 -0.540 0.64542E+04 101 kaolinite -1.33 -4.86 -3.53 -0.321 0.60215E+04 104 laumontite 2.88 1.83 -1.06 -0.070 0.18050E+04 105 lawsonite 9.62 8.12 -1.50 -0.100 0.25599E+04 106 leucite 4.12 0.66 -3.46 -0.346 0.59082E+04 108 lizardite 23.24 21.52 -1.73 -0.144 0.29460E+04 110 magnetite 20.09 16.02 -4.07 -0.332 0.69486E+04 111 minnesotaite 10.39 7.27 -3.12 -0.183 0.53214E+04 115 manganosite 14.06 9.24 -4.82 -1.205 0.82318E+04 119 microcline -2.49 -2.49 0.00 0.000 0.14644E+00 123 muscovite 2.58 -1.06 -3.64 -0.214 0.62115E+04 124 paragonite 4.24 1.05 -3.19 -0.188 0.54504E+04 125 nepheline 8.34 5.91 -2.43 -0.348 0.41539E+04 137 phlogopite-Na 29.65 27.43 -2.22 -0.123 0.37934E+04 139 prehnite 19.37 17.95 -1.42 -0.084 0.24318E+04 140 prehnite-Fe 22.50 21.93 -0.57 -0.034 0.96576E+03 141 pumpellyite-Fe 46.27 43.23 -3.04 -0.068 0.51922E+04 142 pumpellyite-Mg 48.99 45.88 -3.11 -0.069 0.53174E+04 145 pyrite -21.25 -25.86 -4.61 -1.086 0.78784E+04 146 pyrrhotite -4.26 -7.70 -3.44 -1.148 0.58806E+04 147 pyrrhotiteFe0.875 -6.02 -9.01 -2.99 -1.100 0.51055E+04 148 pyroxmangite 7.40 6.09 -1.31 -0.261 0.22314E+04 149 pyrophyllite -6.18 -11.15 -4.97 -0.311 0.84931E+04 150 quartz -2.99 -3.15 -0.16 -0.052 0.26608E+03 154 rhodochrosite -0.98 -5.25 -4.27 -1.424 0.72963E+04 155 rhodonite 7.45 6.09 -1.35 -0.271 0.23117E+04 156 sanidine -1.28 -2.49 -1.21 -0.093 0.20679E+04 166 stilbite -7.52 -7.61 -0.09 -0.004 0.14934E+03 167 stilpnomelane-Fe 13.02 12.47 -0.54 -0.016 0.92779E+03 168 stilpnomelane-Mg 27.44 25.73 -1.71 -0.051 0.29149E+04 174 talc 16.49 15.23 -1.26 -0.074 0.21567E+04 177 tephroite 18.09 15.33 -2.76 -0.394 0.47073E+04 181 tridymite -2.63 -3.15 -0.52 -0.173 0.88605E+03 182 tremolite 47.87 47.14 -0.73 -0.020 0.12477E+04 183 ferroactinolite 38.45 33.88 -4.57 -0.124 0.78108E+04 184 troilite-low -4.41 -7.70 -3.29 -1.098 0.56234E+04 190 wairakite 3.95 1.83 -2.12 -0.125 0.36270E+04 191 walstromite 11.51 9.83 -1.68 -0.336 0.28657E+04 192 wollastonite 10.46 9.83 -0.63 -0.126 0.10762E+04 193 pseudo-wollastonite 11.00 9.83 -1.17 -0.234 0.19960E+04 194 zoisite 22.85 18.66 -4.19 -0.190 0.71477E+04 195 akaganeite 7.75 4.70 -3.05 -0.660 0.52154E+04 202 chalcedony -2.80 -3.15 -0.34 -0.114 0.58537E+03 204 montmorillonite-Ca -2.29 -6.19 -3.90 -0.241 0.66510E+04 205 montmorillonite-K -2.24 -6.27 -4.03 -0.247 0.68866E+04 206 montmorillonite-Mg -2.48 -6.80 -4.32 -0.267 0.73723E+04 207 montmorillonite-Na -2.04 -5.58 -3.54 -0.217 0.60414E+04 208 nontronite-Ca 3.21 0.23 -2.98 -0.193 0.50885E+04 209 nontronite-H 2.53 -1.91 -4.44 -0.298 0.75801E+04 210 nontronite-K 3.34 0.15 -3.19 -0.205 0.54473E+04 211 nontronite-Mg 3.07 -0.38 -3.45 -0.224 0.58938E+04 212 nontronite-Na 3.52 0.84 -2.68 -0.172 0.45681E+04 228 tobermorite 9.82 7.66 -2.16 -0.589 0.36867E+04 234 alabandite -0.98 -5.08 -4.11 -1.369 0.70125E+04 237 boehmite 4.41 0.72 -3.69 -0.615 0.63018E+04 239 ferrous-oxide 9.81 6.62 -3.19 -0.799 0.54537E+04 245 silica-amorphous -2.09 -3.15 -1.05 -0.351 0.17996E+04 247 an20ab80 2.02 1.32 -0.70 -0.054 0.11978E+04 248 an25ab75 2.65 1.74 -0.90 -0.070 0.15442E+04 249 an30ab70 3.28 2.17 -1.11 -0.086 0.19003E+04 250 tr.625ac.25prg.125 45.16 44.76 -0.40 -0.011 0.68874E+03 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 0.0000400 MOLES Current total amount of reactant added: 0.0017100 MOLES New total amount of reactant added: 0.0017500 MOLES Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.5508E-08 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 7 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 0.0017500 Water: Moles liquid = 0.4985E+02 kg liquid = 0.8981E+00 Moles total = 0.4985E+02 kg total = 0.8980E+00 Activity = 1.0000 Stoichiometric ionic strength = .1144189E-01 Osmotic coef. = 0.9643 True ionic strength = .2011978E-01 Chg. balance for total moles = -.5508E-08 Max. difference allowed = 0.1482E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.91073E-10 -10.0406 0.76500E-10 -10.1163 0.83999E+00 -0.0757 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.16427E-03 -3.7844 0.13716E-03 -3.8628 0.83492E+00 -0.0784 4 SO4-- 0.77076E-09 -9.1131 0.39973E-09 -9.3982 0.51862E+00 -0.2851 5 HCO3- 0.52256E-04 -4.2819 0.43694E-04 -4.3596 0.83615E+00 -0.0777 6 HS- 0.75734E-04 -4.1207 0.63241E-04 -4.1990 0.83504E+00 -0.0783 7 Al+++ 0.10085E-28 -28.9963 0.23228E-29 -29.6340 0.23034E+00 -0.6376 8 H4SiO4 0.71618E-03 -3.1450 0.71618E-03 -3.1450 0.10000E+01 0.0000 9 Ca++ 0.10709E-06 -6.9703 0.55129E-07 -7.2586 0.51480E+00 -0.2884 10 Mg++ 0.21221E-10 -10.6732 0.10874E-10 -10.9636 0.51244E+00 -0.2904 11 Fe++ 0.47312E-13 -13.3250 0.24271E-13 -13.6149 0.51300E+00 -0.2899 12 K+ 0.15653E-03 -3.8054 0.13091E-03 -3.8830 0.83634E+00 -0.0776 13 Na+ 0.19866E-01 -1.7019 0.16584E-01 -1.7803 0.83477E+00 -0.0784 14 Mn++ 0.19674E-10 -10.7061 0.10101E-10 -10.9956 0.51343E+00 -0.2895 15 F- 0.88791E-06 -6.0516 0.73980E-06 -6.1309 0.83319E+00 -0.0793 16 HPO4-- 0.45343E-07 -7.3435 0.23519E-07 -7.6286 0.51870E+00 -0.2851 18 HSiO3- 0.10470E-01 -1.9801 0.87416E-02 -2.0584 0.83492E+00 -0.0784 19 Ca(HSiO3)+ 0.13120E-07 -7.8821 0.10975E-07 -7.9596 0.83653E+00 -0.0775 20 Mg(HSiO3)+ 0.32207E-11 -11.4920 0.26942E-11 -11.5696 0.83653E+00 -0.0775 21 NaHSiO3,aq 0.23447E-02 -2.6299 0.23447E-02 -2.6299 0.10000E+01 0.0000 22 AlO+ 0.64549E-16 -16.1901 0.53997E-16 -16.2676 0.83653E+00 -0.0775 24 HAlO2,aq 0.14057E-09 -9.8521 0.14057E-09 -9.8521 0.10000E+01 0.0000 25 AlO2- 0.48805E-05 -5.3115 0.40674E-05 -5.3907 0.83341E+00 -0.0791 26 CH4,aq 0.67384E-05 -5.1714 0.67149E-05 -5.1730 0.99651E+00 -0.0015 27 C2H6,aq 0.30102E-14 -14.5214 0.29997E-14 -14.5229 0.99651E+00 -0.0015 31 CO,aq 0.46105E-15 -15.3363 0.46105E-15 -15.3363 0.10000E+01 0.0000 32 CO2,aq 0.71673E-08 -8.1446 0.71423E-08 -8.1462 0.99651E+00 -0.0015 33 CO3-2 0.96400E-04 -4.0159 0.49889E-04 -4.3020 0.51752E+00 -0.2861 34 CaCO3,aq 0.34486E-07 -7.4624 0.34486E-07 -7.4624 0.10000E+01 0.0000 35 Ca(HCO3)+ 0.73503E-10 -10.1337 0.61487E-10 -10.2112 0.83653E+00 -0.0775 36 CaCl+ 0.14628E-10 -10.8348 0.12237E-10 -10.9123 0.83653E+00 -0.0775 37 CaCl2,aq 0.39873E-15 -15.3993 0.39873E-15 -15.3993 0.10000E+01 0.0000 38 CaF+ 0.71183E-12 -12.1476 0.59546E-12 -12.2251 0.83653E+00 -0.0775 39 CaOH+ 0.61397E-07 -7.2119 0.51360E-07 -7.2894 0.83653E+00 -0.0775 40 CaSO4,aq 0.69978E-14 -14.1550 0.69978E-14 -14.1550 0.10000E+01 0.0000 41 HCl,aq 0.19227E-14 -14.7161 0.19227E-14 -14.7161 0.10000E+01 0.0000 45 HF,aq 0.38743E-12 -12.4118 0.38743E-12 -12.4118 0.10000E+01 0.0000 46 HF2- 0.11590E-18 -18.9359 0.96771E-19 -19.0143 0.83492E+00 -0.0784 48 FeCl+ 0.62988E-17 -17.2007 0.52691E-17 -17.2783 0.83653E+00 -0.0775 51 FeF+ 0.10969E-17 -17.9598 0.91757E-18 -18.0374 0.83653E+00 -0.0775 53 FeO,aq 0.16119E-09 -9.7927 0.16119E-09 -9.7927 0.10000E+01 0.0000 54 FeOH+ 0.12346E-10 -10.9085 0.10327E-10 -10.9860 0.83653E+00 -0.0775 55 HFeO2- 0.26405E-07 -7.5783 0.22046E-07 -7.6567 0.83492E+00 -0.0784 56 FeO+ 0.18370E-16 -16.7359 0.15367E-16 -16.8134 0.83653E+00 -0.0775 58 FeO2- 0.64352E-09 -9.1914 0.53729E-09 -9.2698 0.83492E+00 -0.0784 59 HFeO2,aq 0.52276E-11 -11.2817 0.52276E-11 -11.2817 0.10000E+01 0.0000 60 H2,aq 0.25786E-05 -5.5886 0.25697E-05 -5.5901 0.99651E+00 -0.0015 61 KCl,aq 0.32542E-09 -9.4876 0.32542E-09 -9.4876 0.10000E+01 0.0000 63 KOH,aq 0.73079E-06 -6.1362 0.73079E-06 -6.1362 0.10000E+01 0.0000 64 KSO4- 0.97257E-12 -12.0121 0.81202E-12 -12.0904 0.83492E+00 -0.0784 65 MgCO3,aq 0.17051E-11 -11.7682 0.17051E-11 -11.7682 0.10000E+01 0.0000 66 Mg(HCO3)+ 0.14815E-13 -13.8293 0.12393E-13 -13.9068 0.83653E+00 -0.0775 67 MgCl+ 0.26152E-14 -14.5825 0.21876E-14 -14.6600 0.83653E+00 -0.0775 68 MgF+ 0.52012E-15 -15.2839 0.43510E-15 -15.3614 0.83653E+00 -0.0775 69 MgOH+ 0.67015E-10 -10.1738 0.56060E-10 -10.2513 0.83653E+00 -0.0775 71 MnF+ 0.15047E-15 -15.8226 0.12587E-15 -15.9001 0.83653E+00 -0.0775 72 MnO,aq 0.17874E-08 -8.7478 0.17874E-08 -8.7478 0.10000E+01 0.0000 73 MnOH+ 0.47730E-09 -9.3212 0.39927E-09 -9.3987 0.83653E+00 -0.0775 74 MnO2-2 0.19586E-10 -10.7080 0.10136E-10 -10.9941 0.51752E+00 -0.2861 75 HMnO2- 0.20347E-09 -9.6915 0.16988E-09 -9.7698 0.83492E+00 -0.0784 78 MnCl+ 0.10198E-13 -13.9915 0.85313E-14 -14.0690 0.83653E+00 -0.0775 79 MnSO4,aq 0.11657E-17 -17.9334 0.11657E-17 -17.9334 0.10000E+01 0.0000 80 NaCl,aq 0.75380E-06 -6.1227 0.75380E-06 -6.1227 0.10000E+01 0.0000 81 NaF,aq 0.28723E-08 -8.5418 0.28723E-08 -8.5418 0.10000E+01 0.0000 82 NaOH,aq 0.93140E-04 -4.0309 0.93140E-04 -4.0309 0.10000E+01 0.0000 84 OH- 0.90623E-02 -2.0428 0.75526E-02 -2.1219 0.83341E+00 -0.0791 89 HPO3-2 0.36393E-15 -15.4390 0.18834E-15 -15.7251 0.51752E+00 -0.2861 91 H2PO3- 0.34605E-19 -19.4609 0.28892E-19 -19.5392 0.83492E+00 -0.0784 92 H3PO4,aq 0.96265E-18 -18.0165 0.96265E-18 -18.0165 0.10000E+01 0.0000 93 H2PO4- 0.39715E-10 -10.4010 0.33191E-10 -10.4790 0.83571E+00 -0.0779 94 PO4-3 0.10367E-08 -8.9844 0.25084E-09 -9.6006 0.24197E+00 -0.6162 98 HP2O7-3 0.97785E-18 -18.0097 0.22546E-18 -18.6469 0.23057E+00 -0.6372 99 P2O7-4 0.91791E-17 -17.0372 0.70407E-18 -18.1524 0.76704E-01 -1.1152 100 H2S,aq 0.15005E-07 -7.8238 0.14952E-07 -7.8253 0.99651E+00 -0.0015 101 S2-2 0.66639E-13 -13.1763 0.34487E-13 -13.4623 0.51752E+00 -0.2861 107 SO3-2 0.25423E-15 -15.5948 0.13348E-15 -15.8746 0.52503E+00 -0.2798 108 HSO3- 0.76577E-18 -18.1159 0.63936E-18 -18.1943 0.83492E+00 -0.0784 109 HSO4- 0.35195E-16 -16.4535 0.29470E-16 -16.5306 0.83734E+00 -0.0771 111 S2O3-2 0.13567E-18 -18.8675 0.70210E-19 -19.1536 0.51752E+00 -0.2861 Charge balance for all species = -.6133E-08 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.9107255E-10 -.2208756E-01 -.2222411E+02 0.0000 2 H2O 0.1000000E+01 0.5550461E+02 0.9981884E+06 0.0000 3 Cl- 0.1642739E-03 0.1650281E-03 0.5840538E+01 6.2536 4 SO4-- 0.7707578E-09 -.7382185E-05 -.7079078E+00 10.8344 5 HCO3- 0.5225642E-04 0.1554363E-03 0.9467750E+01 5.7568 6 HS- 0.7573373E-04 0.8313169E-04 0.2744537E+01 5.9173 7 Al+++ 0.1008457E-28 0.4880627E-05 0.1314570E+00 0.7150 8 H4SiO4 0.7161849E-03 0.1353083E-01 0.1298253E+04 -3.1450 9 Ca++ 0.1070881E-06 0.2161795E-06 0.8648934E-02 12.9741 10 Mg++ 0.2122106E-10 0.9317972E-10 0.2261435E-05 9.2691 11 Fe++ 0.4731194E-13 0.2722728E-07 0.1517910E-02 6.6178 12 K+ 0.1565251E-03 0.1572562E-03 0.6138309E+01 6.2333 13 Na+ 0.1986641E-01 0.2230498E-01 0.5118927E+03 8.3360 14 Mn++ 0.1967364E-10 0.2507491E-08 0.1375163E-03 9.2370 15 F- 0.8879111E-06 0.8907846E-06 0.1689361E-01 3.9855 16 HPO4-- 0.4534262E-07 0.4641899E-07 0.4447479E-02 12.6041 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.1983811E-01 -.1983650E-01 -.1610525E-05 0.0000000E+00 2 H2O 0.4984784E+02 0.4984784E+02 -.1568009E-05 0.0000000E+00 3 Cl- 0.1482092E-03 0.1482092E-03 0.0000000E+00 0.0000000E+00 4 SO4-- -.6628810E-05 -.6629827E-05 0.1017483E-08 0.0000000E+00 5 HCO3- 0.1395950E-03 0.1395950E-03 0.0000000E+00 0.0000000E+00 6 HS- 0.7465828E-04 0.7465930E-04 -.1017483E-08 0.0000000E+00 7 Al+++ 0.4775352E-05 0.4383217E-05 0.3921355E-06 0.0000000E+00 8 H4SiO4 0.1215302E-01 0.1215183E-01 0.1186890E-05 0.0000000E+00 9 Ca++ 0.2080835E-06 0.1941475E-06 0.1393596E-07 0.0000000E+00 10 Mg++ 0.8368328E-10 0.8368328E-10 0.0000000E+00 0.0000000E+00 11 Fe++ 0.3259227E-07 0.2445240E-07 0.8139866E-08 0.0000000E+00 12 K+ 0.1412294E-03 0.1412294E-03 0.0000000E+00 0.0000000E+00 13 Na+ 0.2003215E-01 0.2003176E-01 0.3909847E-06 0.0000000E+00 14 Mn++ 0.2251939E-08 0.2251939E-08 0.0000000E+00 0.0000000E+00 15 F- 0.8000000E-06 0.8000000E-06 0.0000000E+00 0.0000000E+00 16 HPO4-- 0.4168819E-07 0.4168819E-07 0.0000000E+00 0.0000000E+00 Chg. balance for solid moles: 0.2118E-21 Mass of aqueous solution: 0.899654E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 0.0017500 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 0.3910E-06 -6.408 0.1025E-03 -3.989 97.78 0.3936E-04 andradite 0.4070E-08 -8.390 0.2068E-05 -5.684 1.973 0.5373E-06 grossular 0.5754E-09 -9.240 0.2592E-06 -6.586 0.2472 0.7212E-07 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8761E+00 0.8761E+00 1.0000 -0.057 grossular 0.1239E+00 0.1239E+00 1.0000 -0.907 Solid products produced: Mass = 0.000105 g Volume = 0.000040 cm3 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.0017500 moles log = -2.7570 Original solution: 1000.0103000 g Original solution / Rock added: 571434.46 (Water/Rock Ratio), log = 5.7570 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0336 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9873E+00 0.9858 0.1006E+01 0.1020E+01 CO2,gas 0.7342E-06 1.0070 0.7642E-06 0.7589E-06 CH4,gas 0.9445E-02 1.0124 0.9884E-02 0.9762E-02 H2,gas 0.3262E-02 1.0006 0.3374E-02 0.3372E-02 H2S,gas 0.3993E-06 0.9960 0.4110E-06 0.4127E-06 S2,gas 0.5390E-27 1.0000 0.5572E-27 0.5572E-27 CO,gas 0.6647E-12 1.0000 0.6871E-12 0.6871E-12 SO3,gas 0.8557E-45 1.0000 0.8845E-45 0.8845E-45 SO2,gas 0.1123E-24 1.0000 0.1161E-24 0.1161E-24 HF,gas 0.9203E-15 1.0000 0.9513E-15 0.9513E-15 HCl,gas 0.3282E-17 1.0000 0.3393E-17 0.3393E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 17 albite -0.38 -0.38 0.00 0.000 -0.94784E-12 23 andradite 39.01 39.01 0.00 0.000 0.00000E+00 24 grossular 32.73 32.73 0.00 0.000 0.00000E+00 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -14.48 -7.82 -2.605 0.13345E+05 -6.117 3 CH4,gas 4.54 0.84 -3.70 -0.926 0.63246E+04 -2.005 4 H2,gas 8.00 3.83 -4.17 -2.383 0.71216E+04 -2.472 5 H2S,gas -6.23 -14.32 -8.09 -4.043 0.13805E+05 -6.386 6 S2,gas -7.34 -36.29 -28.95 -4.454 0.49436E+05 -27.254 7 CO,gas 3.21 -10.65 -13.86 -4.265 0.23669E+05 -12.163 8 SO3,gas 17.12 -29.63 -46.75 -11.688 0.79828E+05 -45.053 9 SO2,gas 0.83 -25.80 -26.63 -7.102 0.45477E+05 -24.935 10 HF,gas 0.47 -16.25 -16.72 -8.360 0.28550E+05 -15.022 11 HCl,gas 5.19 -13.98 -19.17 -9.584 0.32730E+05 -17.469 12 acmite 7.71 6.75 -0.96 -0.100 0.16397E+04 16 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 20 spessartine 24.46 19.71 -4.75 -0.238 0.81123E+04 21 analcite 3.32 2.76 -0.56 -0.062 0.95747E+03 27 annite 20.12 17.37 -2.76 -0.153 0.47070E+04 28 phlogopite 27.06 25.32 -1.74 -0.097 0.29777E+04 30 anorthite 12.71 8.11 -4.60 -0.354 0.78478E+04 33 apatite-OH -18.15 -18.71 -0.56 -0.043 0.95616E+03 34 apatite-F -34.30 -34.96 -0.66 -0.055 0.11264E+04 38 aragonite 0.97 -1.50 -2.47 -0.823 0.42147E+04 39 brucite 12.57 9.27 -3.30 -0.660 0.56338E+04 40 calcite 0.81 -1.50 -2.31 -0.771 0.39505E+04 41 carnegieite-low 9.02 5.91 -3.12 -0.445 0.53226E+04 42 carnegieite-high 10.09 5.91 -4.19 -0.598 0.71496E+04 43 carpholite-Mg 8.58 4.41 -4.17 -0.278 0.71251E+04 44 carpholite-Fe 6.71 1.76 -4.95 -0.330 0.84601E+04 45 celadonite 5.34 3.64 -1.70 -0.100 0.29097E+04 46 celadonite-Fe 3.88 0.99 -2.89 -0.170 0.49351E+04 47 chrysotile 23.89 21.52 -2.38 -0.198 0.40554E+04 49 clinochlore 39.07 38.34 -0.73 -0.023 0.12447E+04 50 daphnite 28.97 25.08 -3.88 -0.121 0.66272E+04 52 chlorite-Al-free 47.17 43.03 -4.14 -0.172 0.70660E+04 54 chloritoid-Fe 9.17 4.90 -4.27 -0.285 0.72922E+04 55 chloritoid-Mn 11.40 7.52 -3.88 -0.259 0.66232E+04 57 coesite -2.38 -3.14 -0.77 -0.256 0.13129E+04 64 cristobalite -2.56 -3.14 -0.58 -0.195 0.99825E+03 66 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71235E+04 68 diaspore 2.87 0.72 -2.16 -0.360 0.36859E+04 69 diamond -3.10 -6.82 -3.72 -1.062 0.63445E+04 70 diopside 16.18 15.95 -0.23 -0.023 0.38958E+03 71 hedenbergite 14.21 13.30 -0.91 -0.091 0.15477E+04 76 clinoenstatite 17.17 12.25 -4.92 -0.492 0.83974E+04 78 epidote 24.67 22.65 -2.02 -0.098 0.34548E+04 79 clinozoisite 22.81 18.66 -4.15 -0.189 0.70821E+04 80 epidote-Fe 29.84 26.63 -3.21 -0.167 0.54740E+04 81 fayalite 14.05 10.09 -3.96 -0.565 0.67533E+04 82 ferrosilite 11.15 6.95 -4.20 -0.420 0.71780E+04 86 gibbsite 4.08 0.72 -3.36 -0.481 0.57444E+04 87 glaucophane 22.97 20.75 -2.23 -0.060 0.37995E+04 88 glaucophane-Fe 17.28 12.80 -4.48 -0.121 0.76498E+04 89 graphite -3.55 -6.82 -3.27 -0.935 0.55868E+04 90 greenalite 16.14 13.56 -2.58 -0.215 0.43987E+04 93 hematite 12.57 9.41 -3.16 -0.383 0.53948E+04 94 heulandite -5.83 -7.61 -1.78 -0.081 0.30452E+04 98 jadeite 4.22 2.76 -1.45 -0.145 0.24830E+04 100 kalsilite 7.58 3.80 -3.78 -0.540 0.64552E+04 101 kaolinite -1.33 -4.86 -3.53 -0.321 0.60224E+04 104 laumontite 2.88 1.82 -1.06 -0.071 0.18085E+04 105 lawsonite 9.62 8.11 -1.50 -0.100 0.25644E+04 106 leucite 4.12 0.66 -3.46 -0.346 0.59087E+04 108 lizardite 23.24 21.52 -1.73 -0.144 0.29480E+04 110 magnetite 20.09 16.02 -4.06 -0.332 0.69374E+04 111 minnesotaite 10.39 7.27 -3.11 -0.183 0.53183E+04 115 manganosite 14.06 9.24 -4.82 -1.205 0.82319E+04 119 microcline -2.49 -2.49 0.00 0.000 0.14994E+00 123 muscovite 2.58 -1.06 -3.64 -0.214 0.62134E+04 124 paragonite 4.24 1.05 -3.19 -0.188 0.54524E+04 125 nepheline 8.34 5.91 -2.43 -0.348 0.41549E+04 137 phlogopite-Na 29.65 27.42 -2.22 -0.124 0.37964E+04 139 prehnite 19.37 17.94 -1.43 -0.084 0.24393E+04 140 prehnite-Fe 22.50 21.93 -0.57 -0.034 0.96697E+03 141 pumpellyite-Fe 46.27 43.22 -3.05 -0.068 0.52080E+04 142 pumpellyite-Mg 48.99 45.87 -3.12 -0.069 0.53345E+04 145 pyrite -21.25 -25.84 -4.59 -1.081 0.78456E+04 146 pyrrhotite -4.26 -7.70 -3.44 -1.146 0.58690E+04 147 pyrrhotiteFe0.875 -6.02 -9.00 -2.98 -1.097 0.50928E+04 148 pyroxmangite 7.40 6.09 -1.31 -0.261 0.22310E+04 149 pyrophyllite -6.18 -11.15 -4.97 -0.311 0.84930E+04 150 quartz -2.99 -3.14 -0.16 -0.052 0.26558E+03 154 rhodochrosite -0.98 -5.24 -4.26 -1.421 0.72782E+04 155 rhodonite 7.45 6.09 -1.35 -0.271 0.23113E+04 156 sanidine -1.28 -2.49 -1.21 -0.093 0.20679E+04 166 stilbite -7.52 -7.61 -0.09 -0.004 0.15136E+03 167 stilpnomelane-Fe 13.02 12.48 -0.54 -0.016 0.92411E+03 168 stilpnomelane-Mg 27.44 25.73 -1.71 -0.051 0.29182E+04 174 talc 16.49 15.23 -1.26 -0.074 0.21578E+04 177 tephroite 18.09 15.33 -2.76 -0.394 0.47070E+04 181 tridymite -2.63 -3.14 -0.52 -0.173 0.88556E+03 182 tremolite 47.87 47.13 -0.74 -0.020 0.12559E+04 183 ferroactinolite 38.45 33.88 -4.58 -0.124 0.78121E+04 184 troilite-low -4.41 -7.70 -3.29 -1.096 0.56118E+04 190 wairakite 3.95 1.82 -2.13 -0.125 0.36305E+04 191 walstromite 11.51 9.83 -1.68 -0.336 0.28688E+04 192 wollastonite 10.46 9.83 -0.63 -0.126 0.10792E+04 193 pseudo-wollastonite 11.00 9.83 -1.17 -0.234 0.19991E+04 194 zoisite 22.85 18.66 -4.19 -0.191 0.71562E+04 195 akaganeite 7.75 4.70 -3.05 -0.660 0.52099E+04 202 chalcedony -2.80 -3.14 -0.34 -0.114 0.58488E+03 204 montmorillonite-Ca -2.29 -6.19 -3.90 -0.241 0.66516E+04 205 montmorillonite-K -2.24 -6.27 -4.03 -0.247 0.68867E+04 206 montmorillonite-Mg -2.48 -6.80 -4.32 -0.267 0.73724E+04 207 montmorillonite-Na -2.04 -5.58 -3.54 -0.217 0.60416E+04 208 nontronite-Ca 3.21 0.24 -2.97 -0.193 0.50768E+04 209 nontronite-H 2.53 -1.90 -4.43 -0.297 0.75678E+04 210 nontronite-K 3.34 0.16 -3.18 -0.204 0.54352E+04 211 nontronite-Mg 3.07 -0.37 -3.44 -0.223 0.58817E+04 212 nontronite-Na 3.52 0.85 -2.67 -0.171 0.45560E+04 228 tobermorite 9.82 7.66 -2.16 -0.590 0.36892E+04 234 alabandite -0.98 -5.08 -4.10 -1.367 0.70014E+04 237 boehmite 4.41 0.72 -3.69 -0.615 0.63028E+04 239 ferrous-oxide 9.81 6.62 -3.19 -0.798 0.54534E+04 245 silica-amorphous -2.09 -3.14 -1.05 -0.351 0.17991E+04 247 an20ab80 2.02 1.32 -0.70 -0.054 0.11987E+04 248 an25ab75 2.65 1.74 -0.91 -0.070 0.15454E+04 249 an30ab70 3.28 2.17 -1.11 -0.086 0.19016E+04 250 tr.625ac.25prg.125 45.16 44.76 -0.41 -0.011 0.69562E+03 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 0.0000400 MOLES Current total amount of reactant added: 0.0017500 MOLES New total amount of reactant added: 0.0017900 MOLES Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.5508E-08 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 6 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 0.0017900 Water: Moles liquid = 0.4985E+02 kg liquid = 0.8981E+00 Moles total = 0.4985E+02 kg total = 0.8980E+00 Activity = 1.0000 Stoichiometric ionic strength = .1144445E-01 Osmotic coef. = 0.9642 True ionic strength = .2012213E-01 Chg. balance for total moles = -.5508E-08 Max. difference allowed = 0.1484E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.91138E-10 -10.0403 0.76555E-10 -10.1160 0.83998E+00 -0.0757 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.16454E-03 -3.7837 0.13737E-03 -3.8621 0.83491E+00 -0.0784 4 SO4-- 0.82511E-09 -9.0835 0.42791E-09 -9.3686 0.51861E+00 -0.2852 5 HCO3- 0.53484E-04 -4.2718 0.44720E-04 -4.3495 0.83614E+00 -0.0777 6 HS- 0.76816E-04 -4.1146 0.64144E-04 -4.1928 0.83504E+00 -0.0783 7 Al+++ 0.10094E-28 -28.9959 0.23248E-29 -29.6336 0.23032E+00 -0.6377 8 H4SiO4 0.71666E-03 -3.1447 0.71666E-03 -3.1447 0.10000E+01 0.0000 9 Ca++ 0.10673E-06 -6.9717 0.54943E-07 -7.2601 0.51479E+00 -0.2884 10 Mg++ 0.21223E-10 -10.6732 0.10875E-10 -10.9636 0.51242E+00 -0.2904 11 Fe++ 0.47403E-13 -13.3242 0.24317E-13 -13.6141 0.51299E+00 -0.2899 12 K+ 0.15653E-03 -3.8054 0.13091E-03 -3.8830 0.83634E+00 -0.0776 13 Na+ 0.19867E-01 -1.7019 0.16584E-01 -1.7803 0.83476E+00 -0.0784 14 Mn++ 0.19701E-10 -10.7055 0.10115E-10 -10.9950 0.51341E+00 -0.2895 15 F- 0.90567E-06 -6.0430 0.75459E-06 -6.1223 0.83319E+00 -0.0793 16 HPO4-- 0.45343E-07 -7.3435 0.23519E-07 -7.6286 0.51868E+00 -0.2851 18 HSiO3- 0.10470E-01 -1.9801 0.87412E-02 -2.0584 0.83491E+00 -0.0784 19 Ca(HSiO3)+ 0.13075E-07 -7.8836 0.10937E-07 -7.9611 0.83652E+00 -0.0775 20 Mg(HSiO3)+ 0.32209E-11 -11.4920 0.26943E-11 -11.5696 0.83652E+00 -0.0775 21 NaHSiO3,aq 0.23446E-02 -2.6299 0.23446E-02 -2.6299 0.10000E+01 0.0000 22 AlO+ 0.64513E-16 -16.1904 0.53966E-16 -16.2679 0.83652E+00 -0.0775 24 HAlO2,aq 0.14039E-09 -9.8527 0.14039E-09 -9.8527 0.10000E+01 0.0000 25 AlO2- 0.48707E-05 -5.3124 0.40593E-05 -5.3916 0.83340E+00 -0.0791 26 CH4,aq 0.65345E-05 -5.1848 0.65117E-05 -5.1863 0.99651E+00 -0.0015 27 C2H6,aq 0.28698E-14 -14.5422 0.28598E-14 -14.5437 0.99651E+00 -0.0015 31 CO,aq 0.46581E-15 -15.3318 0.46581E-15 -15.3318 0.10000E+01 0.0000 32 CO2,aq 0.73409E-08 -8.1343 0.73153E-08 -8.1358 0.99651E+00 -0.0015 33 CO3-2 0.98596E-04 -4.0061 0.51024E-04 -4.2922 0.51750E+00 -0.2861 34 CaCO3,aq 0.35151E-07 -7.4541 0.35151E-07 -7.4541 0.10000E+01 0.0000 35 Ca(HCO3)+ 0.74975E-10 -10.1251 0.62718E-10 -10.2026 0.83652E+00 -0.0775 36 CaCl+ 0.14602E-10 -10.8356 0.12214E-10 -10.9131 0.83652E+00 -0.0775 37 CaCl2,aq 0.39864E-15 -15.3994 0.39864E-15 -15.3994 0.10000E+01 0.0000 38 CaF+ 0.72361E-12 -12.1405 0.60531E-12 -12.2180 0.83652E+00 -0.0775 39 CaOH+ 0.61146E-07 -7.2136 0.51150E-07 -7.2912 0.83652E+00 -0.0775 40 CaSO4,aq 0.74657E-14 -14.1269 0.74657E-14 -14.1269 0.10000E+01 0.0000 41 HCl,aq 0.19271E-14 -14.7151 0.19271E-14 -14.7151 0.10000E+01 0.0000 45 HF,aq 0.39546E-12 -12.4029 0.39546E-12 -12.4029 0.10000E+01 0.0000 46 HF2- 0.12067E-18 -18.9184 0.10075E-18 -18.9968 0.83491E+00 -0.0784 48 FeCl+ 0.63207E-17 -17.1992 0.52874E-17 -17.2768 0.83652E+00 -0.0775 51 FeF+ 0.11209E-17 -17.9504 0.93768E-18 -18.0279 0.83652E+00 -0.0775 53 FeO,aq 0.16126E-09 -9.7925 0.16126E-09 -9.7925 0.10000E+01 0.0000 54 FeOH+ 0.12360E-10 -10.9080 0.10339E-10 -10.9855 0.83652E+00 -0.0775 55 HFeO2- 0.26398E-07 -7.5784 0.22040E-07 -7.6568 0.83491E+00 -0.0784 56 FeO+ 0.18517E-16 -16.7324 0.15490E-16 -16.8099 0.83652E+00 -0.0775 58 FeO2- 0.64776E-09 -9.1886 0.54083E-09 -9.2669 0.83491E+00 -0.0784 59 HFeO2,aq 0.52658E-11 -11.2785 0.52658E-11 -11.2785 0.10000E+01 0.0000 60 H2,aq 0.25437E-05 -5.5945 0.25348E-05 -5.5961 0.99651E+00 -0.0015 61 KCl,aq 0.32593E-09 -9.4869 0.32593E-09 -9.4869 0.10000E+01 0.0000 63 KOH,aq 0.73026E-06 -6.1365 0.73026E-06 -6.1365 0.10000E+01 0.0000 64 KSO4- 0.10411E-11 -11.9825 0.86924E-12 -12.0609 0.83491E+00 -0.0784 65 MgCO3,aq 0.17440E-11 -11.7584 0.17440E-11 -11.7584 0.10000E+01 0.0000 66 Mg(HCO3)+ 0.15164E-13 -13.8192 0.12685E-13 -13.8967 0.83652E+00 -0.0775 67 MgCl+ 0.26195E-14 -14.5818 0.21913E-14 -14.6593 0.83652E+00 -0.0775 68 MgF+ 0.53057E-15 -15.2753 0.44383E-15 -15.3528 0.83652E+00 -0.0775 69 MgOH+ 0.66973E-10 -10.1741 0.56024E-10 -10.2516 0.83652E+00 -0.0775 71 MnF+ 0.15368E-15 -15.8134 0.12856E-15 -15.8909 0.83652E+00 -0.0775 72 MnO,aq 0.17873E-08 -8.7478 0.17873E-08 -8.7478 0.10000E+01 0.0000 73 MnOH+ 0.47760E-09 -9.3209 0.39952E-09 -9.3985 0.83652E+00 -0.0775 74 MnO2-2 0.19557E-10 -10.7087 0.10121E-10 -10.9948 0.51750E+00 -0.2861 75 HMnO2- 0.20331E-09 -9.6918 0.16975E-09 -9.7702 0.83491E+00 -0.0784 78 MnCl+ 0.10228E-13 -13.9902 0.85563E-14 -14.0677 0.83652E+00 -0.0775 79 MnSO4,aq 0.12495E-17 -17.9033 0.12495E-17 -17.9033 0.10000E+01 0.0000 80 NaCl,aq 0.75499E-06 -6.1221 0.75499E-06 -6.1221 0.10000E+01 0.0000 81 NaF,aq 0.29298E-08 -8.5332 0.29298E-08 -8.5332 0.10000E+01 0.0000 82 NaOH,aq 0.93073E-04 -4.0312 0.93073E-04 -4.0312 0.10000E+01 0.0000 84 OH- 0.90559E-02 -2.0431 0.75472E-02 -2.1222 0.83340E+00 -0.0791 89 HPO3-2 0.35899E-15 -15.4449 0.18578E-15 -15.7310 0.51750E+00 -0.2861 91 H2PO3- 0.34159E-19 -19.4665 0.28520E-19 -19.5448 0.83491E+00 -0.0784 92 H3PO4,aq 0.96401E-18 -18.0159 0.96401E-18 -18.0159 0.10000E+01 0.0000 93 H2PO4- 0.39743E-10 -10.4007 0.33214E-10 -10.4787 0.83571E+00 -0.0779 94 PO4-3 0.10360E-08 -8.9847 0.25065E-09 -9.6009 0.24195E+00 -0.6163 98 HP2O7-3 0.97859E-18 -18.0094 0.22561E-18 -18.6466 0.23055E+00 -0.6372 99 P2O7-4 0.91799E-17 -17.0372 0.70405E-18 -18.1524 0.76695E-01 -1.1152 100 H2S,aq 0.15230E-07 -7.8173 0.15177E-07 -7.8188 0.99651E+00 -0.0015 101 S2-2 0.69500E-13 -13.1580 0.35967E-13 -13.4441 0.51750E+00 -0.2861 107 SO3-2 0.26847E-15 -15.5711 0.14095E-15 -15.8509 0.52502E+00 -0.2798 108 HSO3- 0.80920E-18 -18.0919 0.67562E-18 -18.1703 0.83491E+00 -0.0784 109 HSO4- 0.37703E-16 -16.4236 0.31570E-16 -16.5007 0.83734E+00 -0.0771 111 S2O3-2 0.14741E-18 -18.8315 0.76286E-19 -19.1176 0.51750E+00 -0.2861 Charge balance for all species = -.6133E-08 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.9113842E-10 -.2208271E-01 -.2221922E+02 0.0000 2 H2O 0.1000000E+01 0.5550460E+02 0.9981882E+06 0.0000 3 Cl- 0.1645354E-03 0.1652907E-03 0.5849832E+01 6.2539 4 SO4-- 0.8251077E-09 -.7169505E-05 -.6875130E+00 10.8634 5 HCO3- 0.5348375E-04 0.1586564E-03 0.9663886E+01 5.7665 6 HS- 0.7681569E-04 0.8400125E-04 0.2773244E+01 5.9232 7 Al+++ 0.1009392E-28 0.4870880E-05 0.1311944E+00 0.7145 8 H4SiO4 0.7166643E-03 0.1353079E-01 0.1298249E+04 -3.1447 9 Ca++ 0.1067294E-06 0.2161917E-06 0.8649418E-02 12.9720 10 Mg++ 0.2122348E-10 0.9317965E-10 0.2261433E-05 9.2685 11 Fe++ 0.4740257E-13 0.2722486E-07 0.1517775E-02 6.6180 12 K+ 0.1565255E-03 0.1572561E-03 0.6138303E+01 6.2330 13 Na+ 0.1986656E-01 0.2230495E-01 0.5118920E+03 8.3357 14 Mn++ 0.1970083E-10 0.2507489E-08 0.1375162E-03 9.2370 15 F- 0.9056687E-06 0.9085995E-06 0.1723147E-01 3.9937 16 HPO4-- 0.4534325E-07 0.4641896E-07 0.4447475E-02 12.6035 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.1983380E-01 -.1983216E-01 -.1645519E-05 0.0000000E+00 2 H2O 0.4984787E+02 0.4984788E+02 -.1603050E-05 0.0000000E+00 3 Cl- 0.1484452E-03 0.1484452E-03 0.0000000E+00 0.0000000E+00 4 SO4-- -.6437810E-05 -.6438828E-05 0.1017753E-08 0.0000000E+00 5 HCO3- 0.1424870E-03 0.1424870E-03 0.0000000E+00 0.0000000E+00 6 HS- 0.7543928E-04 0.7544030E-04 -.1017753E-08 0.0000000E+00 7 Al+++ 0.4775352E-05 0.4374466E-05 0.4008860E-06 0.0000000E+00 8 H4SiO4 0.1215302E-01 0.1215181E-01 0.1213159E-05 0.0000000E+00 9 Ca++ 0.2080835E-06 0.1941586E-06 0.1392492E-07 0.0000000E+00 10 Mg++ 0.8368328E-10 0.8368328E-10 0.0000000E+00 0.0000000E+00 11 Fe++ 0.3259227E-07 0.2445025E-07 0.8142024E-08 0.0000000E+00 12 K+ 0.1412294E-03 0.1412294E-03 0.0000000E+00 0.0000000E+00 13 Na+ 0.2003215E-01 0.2003175E-01 0.3997447E-06 0.0000000E+00 14 Mn++ 0.2251939E-08 0.2251939E-08 0.0000000E+00 0.0000000E+00 15 F- 0.8160000E-06 0.8160000E-06 0.0000000E+00 0.0000000E+00 16 HPO4-- 0.4168819E-07 0.4168819E-07 0.0000000E+00 0.0000000E+00 Chg. balance for solid moles: 0.1588E-21 Mass of aqueous solution: 0.899654E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 0.0017900 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 0.3997E-06 -6.398 0.1048E-03 -3.980 97.83 0.4024E-04 andradite 0.4071E-08 -8.390 0.2069E-05 -5.684 1.931 0.5375E-06 grossular 0.5706E-09 -9.244 0.2570E-06 -6.590 0.2399 0.7152E-07 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8771E+00 0.8771E+00 1.0000 -0.057 grossular 0.1229E+00 0.1229E+00 1.0000 -0.910 Solid products produced: Mass = 0.000107 g Volume = 0.000041 cm3 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.0017900 moles log = -2.7471 Original solution: 1000.0103000 g Original solution / Rock added: 558664.97 (Water/Rock Ratio), log = 5.7472 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0333 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9876E+00 0.9858 0.1006E+01 0.1020E+01 CO2,gas 0.7522E-06 1.0070 0.7827E-06 0.7772E-06 CH4,gas 0.9162E-02 1.0124 0.9585E-02 0.9467E-02 H2,gas 0.3219E-02 1.0006 0.3328E-02 0.3326E-02 H2S,gas 0.4054E-06 0.9960 0.4172E-06 0.4189E-06 S2,gas 0.5709E-27 1.0000 0.5899E-27 0.5899E-27 CO,gas 0.6718E-12 1.0000 0.6941E-12 0.6941E-12 SO3,gas 0.9177E-45 1.0000 0.9482E-45 0.9482E-45 SO2,gas 0.1188E-24 1.0000 0.1228E-24 0.1228E-24 HF,gas 0.9397E-15 1.0000 0.9710E-15 0.9710E-15 HCl,gas 0.3291E-17 1.0000 0.3400E-17 0.3400E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 17 albite -0.38 -0.38 0.00 0.000 -0.94784E-12 23 andradite 39.01 39.01 0.00 0.000 0.00000E+00 24 grossular 32.73 32.73 0.00 0.000 -0.12132E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -14.47 -7.81 -2.602 0.13328E+05 -6.106 3 CH4,gas 4.54 0.83 -3.72 -0.929 0.63473E+04 -2.018 4 H2,gas 8.00 3.82 -4.18 -2.387 0.71318E+04 -2.478 5 H2S,gas -6.23 -14.31 -8.08 -4.039 0.13794E+05 -6.380 6 S2,gas -7.34 -36.26 -28.93 -4.450 0.49394E+05 -27.229 7 CO,gas 3.21 -10.64 -13.86 -4.264 0.23661E+05 -12.159 8 SO3,gas 17.12 -29.60 -46.72 -11.681 0.79777E+05 -45.023 9 SO2,gas 0.83 -25.78 -26.61 -7.096 0.45436E+05 -24.911 10 HF,gas 0.47 -16.24 -16.71 -8.356 0.28535E+05 -15.013 11 HCl,gas 5.19 -13.98 -19.17 -9.584 0.32728E+05 -17.468 12 acmite 7.71 6.75 -0.96 -0.099 0.16339E+04 16 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 20 spessartine 24.46 19.71 -4.75 -0.238 0.81129E+04 21 analcite 3.32 2.76 -0.56 -0.062 0.95797E+03 27 annite 20.12 17.37 -2.76 -0.153 0.47060E+04 28 phlogopite 27.06 25.32 -1.75 -0.097 0.29807E+04 30 anorthite 12.71 8.11 -4.60 -0.354 0.78523E+04 33 apatite-OH -18.15 -18.72 -0.57 -0.044 0.97087E+03 34 apatite-F -34.30 -34.96 -0.66 -0.055 0.11259E+04 38 aragonite 0.97 -1.49 -2.46 -0.820 0.42005E+04 39 brucite 12.57 9.27 -3.30 -0.660 0.56348E+04 40 calcite 0.81 -1.49 -2.31 -0.768 0.39363E+04 41 carnegieite-low 9.02 5.91 -3.12 -0.445 0.53235E+04 42 carnegieite-high 10.09 5.91 -4.19 -0.598 0.71505E+04 43 carpholite-Mg 8.58 4.41 -4.17 -0.278 0.71270E+04 44 carpholite-Fe 6.71 1.76 -4.96 -0.330 0.84607E+04 45 celadonite 5.34 3.64 -1.70 -0.100 0.29102E+04 46 celadonite-Fe 3.88 0.99 -2.89 -0.170 0.49343E+04 47 chrysotile 23.89 21.52 -2.38 -0.198 0.40574E+04 49 clinochlore 39.07 38.34 -0.73 -0.023 0.12501E+04 50 daphnite 28.97 25.08 -3.88 -0.121 0.66259E+04 52 chlorite-Al-free 47.17 43.03 -4.14 -0.173 0.70700E+04 54 chloritoid-Fe 9.17 4.90 -4.27 -0.285 0.72933E+04 55 chloritoid-Mn 11.40 7.52 -3.88 -0.259 0.66247E+04 57 coesite -2.38 -3.14 -0.77 -0.256 0.13124E+04 64 cristobalite -2.56 -3.14 -0.58 -0.195 0.99775E+03 66 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71235E+04 68 diaspore 2.87 0.71 -2.16 -0.360 0.36868E+04 69 diamond -3.10 -6.82 -3.72 -1.062 0.63471E+04 70 diopside 16.18 15.95 -0.23 -0.023 0.39316E+03 71 hedenbergite 14.21 13.30 -0.91 -0.091 0.15499E+04 76 clinoenstatite 17.17 12.25 -4.92 -0.492 0.83985E+04 78 epidote 24.67 22.65 -2.02 -0.098 0.34570E+04 79 clinozoisite 22.81 18.65 -4.15 -0.189 0.70907E+04 80 epidote-Fe 29.84 26.64 -3.20 -0.166 0.54699E+04 81 fayalite 14.05 10.09 -3.95 -0.565 0.67522E+04 82 ferrosilite 11.15 6.95 -4.20 -0.420 0.71763E+04 86 gibbsite 4.08 0.71 -3.36 -0.481 0.57454E+04 87 glaucophane 22.97 20.75 -2.23 -0.060 0.38015E+04 88 glaucophane-Fe 17.28 12.80 -4.48 -0.121 0.76478E+04 89 graphite -3.55 -6.82 -3.27 -0.935 0.55893E+04 90 greenalite 16.14 13.56 -2.57 -0.215 0.43967E+04 93 hematite 12.57 9.41 -3.15 -0.382 0.53840E+04 94 heulandite -5.83 -7.61 -1.78 -0.081 0.30472E+04 98 jadeite 4.22 2.76 -1.45 -0.145 0.24835E+04 100 kalsilite 7.58 3.80 -3.78 -0.540 0.64562E+04 101 kaolinite -1.33 -4.86 -3.53 -0.321 0.60234E+04 104 laumontite 2.88 1.82 -1.06 -0.071 0.18120E+04 105 lawsonite 9.62 8.11 -1.50 -0.100 0.25689E+04 106 leucite 4.12 0.66 -3.46 -0.346 0.59092E+04 108 lizardite 23.24 21.52 -1.73 -0.144 0.29500E+04 110 magnetite 20.09 16.03 -4.06 -0.331 0.69263E+04 111 minnesotaite 10.39 7.28 -3.11 -0.183 0.53153E+04 115 manganosite 14.06 9.24 -4.82 -1.205 0.82319E+04 119 microcline -2.49 -2.49 0.00 0.000 0.15344E+00 123 muscovite 2.58 -1.06 -3.64 -0.214 0.62153E+04 124 paragonite 4.24 1.05 -3.19 -0.188 0.54543E+04 125 nepheline 8.34 5.91 -2.43 -0.348 0.41559E+04 137 phlogopite-Na 29.65 27.42 -2.23 -0.124 0.37994E+04 139 prehnite 19.37 17.94 -1.43 -0.084 0.24469E+04 140 prehnite-Fe 22.50 21.93 -0.57 -0.034 0.96818E+03 141 pumpellyite-Fe 46.27 43.21 -3.06 -0.068 0.52237E+04 142 pumpellyite-Mg 48.99 45.86 -3.13 -0.070 0.53517E+04 145 pyrite -21.25 -25.82 -4.58 -1.077 0.78131E+04 146 pyrrhotite -4.26 -7.69 -3.43 -1.144 0.58576E+04 147 pyrrhotiteFe0.875 -6.02 -8.99 -2.98 -1.094 0.50802E+04 148 pyroxmangite 7.40 6.09 -1.31 -0.261 0.22306E+04 149 pyrophyllite -6.18 -11.15 -4.97 -0.311 0.84930E+04 150 quartz -2.99 -3.14 -0.16 -0.052 0.26508E+03 154 rhodochrosite -0.98 -5.23 -4.25 -1.417 0.72605E+04 155 rhodonite 7.45 6.09 -1.35 -0.271 0.23108E+04 156 sanidine -1.28 -2.49 -1.21 -0.093 0.20679E+04 166 stilbite -7.52 -7.61 -0.09 -0.004 0.15337E+03 167 stilpnomelane-Fe 13.02 12.48 -0.54 -0.016 0.92065E+03 168 stilpnomelane-Mg 27.44 25.73 -1.71 -0.051 0.29214E+04 174 talc 16.49 15.23 -1.26 -0.074 0.21588E+04 177 tephroite 18.09 15.33 -2.76 -0.394 0.47066E+04 181 tridymite -2.63 -3.14 -0.52 -0.173 0.88506E+03 182 tremolite 47.87 47.13 -0.74 -0.020 0.12640E+04 183 ferroactinolite 38.45 33.88 -4.58 -0.124 0.78136E+04 184 troilite-low -4.41 -7.69 -3.28 -1.093 0.56004E+04 190 wairakite 3.95 1.82 -2.13 -0.125 0.36340E+04 191 walstromite 11.51 9.83 -1.68 -0.336 0.28719E+04 192 wollastonite 10.46 9.83 -0.63 -0.127 0.10823E+04 193 pseudo-wollastonite 11.00 9.83 -1.17 -0.235 0.20021E+04 194 zoisite 22.85 18.65 -4.20 -0.191 0.71647E+04 195 akaganeite 7.75 4.71 -3.05 -0.659 0.52045E+04 202 chalcedony -2.80 -3.14 -0.34 -0.114 0.58438E+03 204 montmorillonite-Ca -2.29 -6.19 -3.90 -0.241 0.66521E+04 205 montmorillonite-K -2.24 -6.27 -4.03 -0.247 0.68868E+04 206 montmorillonite-Mg -2.48 -6.80 -4.32 -0.267 0.73725E+04 207 montmorillonite-Na -2.04 -5.58 -3.54 -0.217 0.60417E+04 208 nontronite-Ca 3.21 0.25 -2.97 -0.192 0.50651E+04 209 nontronite-H 2.53 -1.89 -4.42 -0.297 0.75555E+04 210 nontronite-K 3.34 0.16 -3.18 -0.204 0.54230E+04 211 nontronite-Mg 3.07 -0.36 -3.44 -0.223 0.58695E+04 212 nontronite-Na 3.52 0.86 -2.66 -0.171 0.45439E+04 228 tobermorite 9.82 7.66 -2.16 -0.590 0.36917E+04 234 alabandite -0.98 -5.07 -4.09 -1.365 0.69904E+04 237 boehmite 4.41 0.71 -3.69 -0.615 0.63037E+04 239 ferrous-oxide 9.81 6.62 -3.19 -0.798 0.54530E+04 245 silica-amorphous -2.09 -3.14 -1.05 -0.351 0.17986E+04 247 an20ab80 2.02 1.32 -0.70 -0.054 0.11996E+04 248 an25ab75 2.65 1.74 -0.91 -0.070 0.15465E+04 249 an30ab70 3.28 2.16 -1.11 -0.086 0.19030E+04 250 tr.625ac.25prg.125 45.16 44.75 -0.41 -0.011 0.70255E+03 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 0.0000400 MOLES Current total amount of reactant added: 0.0017900 MOLES New total amount of reactant added: 0.0018300 MOLES Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.5508E-08 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 6 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 0.0018300 Water: Moles liquid = 0.4985E+02 kg liquid = 0.8981E+00 Moles total = 0.4985E+02 kg total = 0.8980E+00 Activity = 1.0000 Stoichiometric ionic strength = .1144700E-01 Osmotic coef. = 0.9641 True ionic strength = .2012447E-01 Chg. balance for total moles = -.5508E-08 Max. difference allowed = 0.1487E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.91204E-10 -10.0400 0.76610E-10 -10.1157 0.83998E+00 -0.0757 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.16480E-03 -3.7831 0.13759E-03 -3.8614 0.83491E+00 -0.0784 4 SO4-- 0.88353E-09 -9.0538 0.45819E-09 -9.3390 0.51859E+00 -0.2852 5 HCO3- 0.54712E-04 -4.2619 0.45747E-04 -4.3396 0.83613E+00 -0.0777 6 HS- 0.77898E-04 -4.1085 0.65047E-04 -4.1868 0.83503E+00 -0.0783 7 Al+++ 0.10103E-28 -28.9955 0.23268E-29 -29.6332 0.23030E+00 -0.6377 8 H4SiO4 0.71714E-03 -3.1444 0.71714E-03 -3.1444 0.10000E+01 0.0000 9 Ca++ 0.10637E-06 -6.9732 0.54757E-07 -7.2616 0.51477E+00 -0.2884 10 Mg++ 0.21226E-10 -10.6731 0.10876E-10 -10.9635 0.51241E+00 -0.2904 11 Fe++ 0.47490E-13 -13.3234 0.24361E-13 -13.6133 0.51297E+00 -0.2899 12 K+ 0.15653E-03 -3.8054 0.13091E-03 -3.8830 0.83633E+00 -0.0776 13 Na+ 0.19867E-01 -1.7019 0.16584E-01 -1.7803 0.83475E+00 -0.0784 14 Mn++ 0.19728E-10 -10.7049 0.10128E-10 -10.9945 0.51340E+00 -0.2895 15 F- 0.92343E-06 -6.0346 0.76938E-06 -6.1139 0.83318E+00 -0.0793 16 HPO4-- 0.45344E-07 -7.3435 0.23518E-07 -7.6286 0.51867E+00 -0.2851 18 HSiO3- 0.10469E-01 -1.9801 0.87408E-02 -2.0585 0.83491E+00 -0.0784 19 Ca(HSiO3)+ 0.13030E-07 -7.8850 0.10900E-07 -7.9626 0.83651E+00 -0.0775 20 Mg(HSiO3)+ 0.32210E-11 -11.4920 0.26944E-11 -11.5695 0.83651E+00 -0.0775 21 NaHSiO3,aq 0.23445E-02 -2.6300 0.23445E-02 -2.6300 0.10000E+01 0.0000 22 AlO+ 0.64476E-16 -16.1906 0.53935E-16 -16.2681 0.83651E+00 -0.0775 24 HAlO2,aq 0.14021E-09 -9.8532 0.14021E-09 -9.8532 0.10000E+01 0.0000 25 AlO2- 0.48610E-05 -5.3133 0.40511E-05 -5.3924 0.83339E+00 -0.0792 26 CH4,aq 0.63306E-05 -5.1986 0.63085E-05 -5.2001 0.99651E+00 -0.0015 27 C2H6,aq 0.27308E-14 -14.5637 0.27213E-14 -14.5652 0.99651E+00 -0.0015 31 CO,aq 0.47032E-15 -15.3276 0.47032E-15 -15.3276 0.10000E+01 0.0000 32 CO2,aq 0.75148E-08 -8.1241 0.74886E-08 -8.1256 0.99651E+00 -0.0015 33 CO3-2 0.10079E-03 -3.9966 0.52158E-04 -4.2827 0.51749E+00 -0.2861 34 CaCO3,aq 0.35811E-07 -7.4460 0.35811E-07 -7.4460 0.10000E+01 0.0000 35 Ca(HCO3)+ 0.76438E-10 -10.1167 0.63941E-10 -10.1942 0.83651E+00 -0.0775 36 CaCl+ 0.14575E-10 -10.8364 0.12192E-10 -10.9139 0.83651E+00 -0.0775 37 CaCl2,aq 0.39855E-15 -15.3995 0.39855E-15 -15.3995 0.10000E+01 0.0000 38 CaF+ 0.73530E-12 -12.1335 0.61509E-12 -12.2111 0.83651E+00 -0.0775 39 CaOH+ 0.60896E-07 -7.2154 0.50940E-07 -7.2929 0.83651E+00 -0.0775 40 CaSO4,aq 0.79670E-14 -14.0987 0.79670E-14 -14.0987 0.10000E+01 0.0000 41 HCl,aq 0.19315E-14 -14.7141 0.19315E-14 -14.7141 0.10000E+01 0.0000 45 HF,aq 0.40350E-12 -12.3942 0.40350E-12 -12.3942 0.10000E+01 0.0000 46 HF2- 0.12554E-18 -18.9012 0.10481E-18 -18.9796 0.83491E+00 -0.0784 48 FeCl+ 0.63423E-17 -17.1978 0.53054E-17 -17.2753 0.83651E+00 -0.0775 51 FeF+ 0.11450E-17 -17.9412 0.95779E-18 -18.0187 0.83651E+00 -0.0775 53 FeO,aq 0.16132E-09 -9.7923 0.16132E-09 -9.7923 0.10000E+01 0.0000 54 FeOH+ 0.12374E-10 -10.9075 0.10351E-10 -10.9850 0.83651E+00 -0.0775 55 HFeO2- 0.26390E-07 -7.5786 0.22033E-07 -7.6569 0.83491E+00 -0.0784 56 FeO+ 0.18666E-16 -16.7289 0.15614E-16 -16.8065 0.83651E+00 -0.0775 58 FeO2- 0.65203E-09 -9.1857 0.54438E-09 -9.2641 0.83491E+00 -0.0784 59 HFeO2,aq 0.53043E-11 -11.2754 0.53043E-11 -11.2754 0.10000E+01 0.0000 60 H2,aq 0.25089E-05 -5.6005 0.25001E-05 -5.6020 0.99651E+00 -0.0015 61 KCl,aq 0.32645E-09 -9.4862 0.32645E-09 -9.4862 0.10000E+01 0.0000 63 KOH,aq 0.72974E-06 -6.1368 0.72974E-06 -6.1368 0.10000E+01 0.0000 64 KSO4- 0.11148E-11 -11.9528 0.93076E-12 -12.0312 0.83491E+00 -0.0784 65 MgCO3,aq 0.17829E-11 -11.7489 0.17829E-11 -11.7489 0.10000E+01 0.0000 66 Mg(HCO3)+ 0.15514E-13 -13.8093 0.12978E-13 -13.8868 0.83651E+00 -0.0775 67 MgCl+ 0.26239E-14 -14.5810 0.21949E-14 -14.6586 0.83651E+00 -0.0775 68 MgF+ 0.54102E-15 -15.2668 0.45257E-15 -15.3443 0.83651E+00 -0.0775 69 MgOH+ 0.66931E-10 -10.1744 0.55989E-10 -10.2519 0.83651E+00 -0.0775 71 MnF+ 0.15691E-15 -15.8044 0.13125E-15 -15.8819 0.83651E+00 -0.0775 72 MnO,aq 0.17872E-08 -8.7478 0.17872E-08 -8.7478 0.10000E+01 0.0000 73 MnOH+ 0.47791E-09 -9.3207 0.39978E-09 -9.3982 0.83651E+00 -0.0775 74 MnO2-2 0.19528E-10 -10.7093 0.10106E-10 -10.9954 0.51749E+00 -0.2861 75 HMnO2- 0.20315E-09 -9.6922 0.16961E-09 -9.7705 0.83491E+00 -0.0784 78 MnCl+ 0.10259E-13 -13.9889 0.85814E-14 -14.0664 0.83651E+00 -0.0775 79 MnSO4,aq 0.13397E-17 -17.8730 0.13397E-17 -17.8730 0.10000E+01 0.0000 80 NaCl,aq 0.75618E-06 -6.1214 0.75618E-06 -6.1214 0.10000E+01 0.0000 81 NaF,aq 0.29872E-08 -8.5247 0.29872E-08 -8.5247 0.10000E+01 0.0000 82 NaOH,aq 0.93007E-04 -4.0315 0.93007E-04 -4.0315 0.10000E+01 0.0000 84 OH- 0.90495E-02 -2.0434 0.75418E-02 -2.1225 0.83339E+00 -0.0792 89 HPO3-2 0.35409E-15 -15.4509 0.18323E-15 -15.7370 0.51749E+00 -0.2861 91 H2PO3- 0.33716E-19 -19.4722 0.28150E-19 -19.5505 0.83491E+00 -0.0784 92 H3PO4,aq 0.96538E-18 -18.0153 0.96538E-18 -18.0153 0.10000E+01 0.0000 93 H2PO4- 0.39772E-10 -10.4004 0.33237E-10 -10.4784 0.83570E+00 -0.0779 94 PO4-3 0.10353E-08 -8.9849 0.25047E-09 -9.6012 0.24194E+00 -0.6163 98 HP2O7-3 0.97932E-18 -18.0091 0.22577E-18 -18.6463 0.23054E+00 -0.6373 99 P2O7-4 0.91807E-17 -17.0371 0.70403E-18 -18.1524 0.76685E-01 -1.1153 100 H2S,aq 0.15455E-07 -7.8109 0.15401E-07 -7.8124 0.99651E+00 -0.0015 101 S2-2 0.72465E-13 -13.1399 0.37500E-13 -13.4260 0.51749E+00 -0.2861 107 SO3-2 0.28354E-15 -15.5474 0.14886E-15 -15.8272 0.52500E+00 -0.2798 108 HSO3- 0.85524E-18 -18.0679 0.71404E-18 -18.1463 0.83491E+00 -0.0784 109 HSO4- 0.40400E-16 -16.3936 0.33829E-16 -16.4707 0.83733E+00 -0.0771 111 S2O3-2 0.16019E-18 -18.7954 0.82895E-19 -19.0815 0.51749E+00 -0.2861 Charge balance for all species = -.6133E-08 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.9120437E-10 -.2207785E-01 -.2221434E+02 0.0000 2 H2O 0.1000000E+01 0.5550460E+02 0.9981879E+06 0.0000 3 Cl- 0.1647969E-03 0.1655534E-03 0.5859127E+01 6.2543 4 SO4-- 0.8835333E-09 -.6956825E-05 -.6671182E+00 10.8925 5 HCO3- 0.5471219E-04 0.1618765E-03 0.9860021E+01 5.7761 6 HS- 0.7789765E-04 0.8487081E-04 0.2801952E+01 5.9289 7 Al+++ 0.1010327E-28 0.4861148E-05 0.1309323E+00 0.7139 8 H4SiO4 0.7171442E-03 0.1353075E-01 0.1298245E+04 -3.1444 9 Ca++ 0.1063718E-06 0.2162007E-06 0.8649777E-02 12.9699 10 Mg++ 0.2122590E-10 0.9317957E-10 0.2261431E-05 9.2679 11 Fe++ 0.4749026E-13 0.2722069E-07 0.1517542E-02 6.6181 12 K+ 0.1565259E-03 0.1572560E-03 0.6138298E+01 6.2327 13 Na+ 0.1986671E-01 0.2230492E-01 0.5118913E+03 8.3354 14 Mn++ 0.1972807E-10 0.2507487E-08 0.1375160E-03 9.2370 15 F- 0.9234262E-06 0.9264145E-06 0.1756933E-01 4.0019 16 HPO4-- 0.4534387E-07 0.4641892E-07 0.4447471E-02 12.6028 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.1982949E-01 -.1982781E-01 -.1680466E-05 0.0000000E+00 2 H2O 0.4984791E+02 0.4984791E+02 -.1638036E-05 0.0000000E+00 3 Cl- 0.1486812E-03 0.1486812E-03 0.0000000E+00 0.0000000E+00 4 SO4-- -.6246810E-05 -.6247828E-05 0.1018219E-08 0.0000000E+00 5 HCO3- 0.1453790E-03 0.1453790E-03 0.0000000E+00 0.0000000E+00 6 HS- 0.7622028E-04 0.7622130E-04 -.1018219E-08 0.0000000E+00 7 Al+++ 0.4775352E-05 0.4365729E-05 0.4096228E-06 0.0000000E+00 8 H4SiO4 0.1215302E-01 0.1215178E-01 0.1239389E-05 0.0000000E+00 9 Ca++ 0.2080835E-06 0.1941668E-06 0.1391668E-07 0.0000000E+00 10 Mg++ 0.8368328E-10 0.8368328E-10 0.0000000E+00 0.0000000E+00 11 Fe++ 0.3259227E-07 0.2444652E-07 0.8145750E-08 0.0000000E+00 12 K+ 0.1412294E-03 0.1412294E-03 0.0000000E+00 0.0000000E+00 13 Na+ 0.2003215E-01 0.2003174E-01 0.4084908E-06 0.0000000E+00 14 Mn++ 0.2251939E-08 0.2251939E-08 0.0000000E+00 0.0000000E+00 15 F- 0.8320000E-06 0.8320000E-06 0.0000000E+00 0.0000000E+00 16 HPO4-- 0.4168819E-07 0.4168819E-07 0.0000000E+00 0.0000000E+00 Chg. balance for solid moles: -.2647E-21 Mass of aqueous solution: 0.899655E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 0.0018300 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 0.4085E-06 -6.389 0.1071E-03 -3.970 97.88 0.4112E-04 andradite 0.4073E-08 -8.390 0.2070E-05 -5.684 1.891 0.5377E-06 grossular 0.5660E-09 -9.247 0.2550E-06 -6.594 0.2330 0.7094E-07 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8780E+00 0.8780E+00 1.0000 -0.057 grossular 0.1220E+00 0.1220E+00 1.0000 -0.914 Solid products produced: Mass = 0.000109 g Volume = 0.000042 cm3 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.0018300 moles log = -2.7375 Original solution: 1000.0103000 g Original solution / Rock added: 546453.72 (Water/Rock Ratio), log = 5.7376 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0329 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9879E+00 0.9858 0.1006E+01 0.1020E+01 CO2,gas 0.7703E-06 1.0070 0.8012E-06 0.7956E-06 CH4,gas 0.8879E-02 1.0124 0.9286E-02 0.9172E-02 H2,gas 0.3176E-02 1.0006 0.3282E-02 0.3281E-02 H2S,gas 0.4115E-06 0.9960 0.4234E-06 0.4251E-06 S2,gas 0.6046E-27 1.0000 0.6245E-27 0.6245E-27 CO,gas 0.6785E-12 1.0000 0.7009E-12 0.7009E-12 SO3,gas 0.9844E-45 1.0000 0.1017E-44 0.1017E-44 SO2,gas 0.1257E-24 1.0000 0.1298E-24 0.1298E-24 HF,gas 0.9591E-15 1.0000 0.9907E-15 0.9907E-15 HCl,gas 0.3300E-17 1.0000 0.3408E-17 0.3408E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 17 albite -0.38 -0.38 0.00 0.000 -0.94784E-12 23 andradite 39.01 39.01 0.00 0.000 -0.12132E-10 24 grossular 32.73 32.73 0.00 0.000 0.00000E+00 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -14.46 -7.80 -2.598 0.13310E+05 -6.096 3 CH4,gas 4.54 0.81 -3.73 -0.933 0.63708E+04 -2.032 4 H2,gas 8.00 3.82 -4.18 -2.390 0.71420E+04 -2.484 5 H2S,gas -6.23 -14.30 -8.07 -4.036 0.13783E+05 -6.373 6 S2,gas -7.34 -36.24 -28.90 -4.447 0.49352E+05 -27.204 7 CO,gas 3.21 -10.64 -13.85 -4.263 0.23654E+05 -12.154 8 SO3,gas 17.12 -29.57 -46.69 -11.673 0.79725E+05 -44.993 9 SO2,gas 0.83 -25.75 -26.59 -7.089 0.45394E+05 -24.887 10 HF,gas 0.47 -16.23 -16.70 -8.352 0.28520E+05 -15.004 11 HCl,gas 5.19 -13.98 -19.17 -9.583 0.32726E+05 -17.467 12 acmite 7.71 6.76 -0.95 -0.099 0.16280E+04 16 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 20 spessartine 24.46 19.71 -4.75 -0.238 0.81135E+04 21 analcite 3.32 2.76 -0.56 -0.062 0.95846E+03 27 annite 20.12 17.37 -2.76 -0.153 0.47051E+04 28 phlogopite 27.06 25.32 -1.75 -0.097 0.29837E+04 30 anorthite 12.71 8.11 -4.60 -0.354 0.78568E+04 33 apatite-OH -18.15 -18.73 -0.58 -0.044 0.98559E+03 34 apatite-F -34.30 -34.96 -0.66 -0.055 0.11257E+04 38 aragonite 0.97 -1.49 -2.45 -0.817 0.41867E+04 39 brucite 12.57 9.27 -3.30 -0.660 0.56358E+04 40 calcite 0.81 -1.49 -2.30 -0.766 0.39225E+04 41 carnegieite-low 9.02 5.90 -3.12 -0.445 0.53245E+04 42 carnegieite-high 10.09 5.90 -4.19 -0.598 0.71515E+04 43 carpholite-Mg 8.58 4.41 -4.18 -0.278 0.71289E+04 44 carpholite-Fe 6.71 1.76 -4.96 -0.330 0.84613E+04 45 celadonite 5.34 3.64 -1.70 -0.100 0.29107E+04 46 celadonite-Fe 3.88 0.99 -2.89 -0.170 0.49335E+04 47 chrysotile 23.89 21.51 -2.38 -0.198 0.40594E+04 49 clinochlore 39.07 38.33 -0.74 -0.023 0.12555E+04 50 daphnite 28.97 25.09 -3.88 -0.121 0.66249E+04 52 chlorite-Al-free 47.17 43.03 -4.14 -0.173 0.70740E+04 54 chloritoid-Fe 9.17 4.90 -4.27 -0.285 0.72944E+04 55 chloritoid-Mn 11.40 7.52 -3.88 -0.259 0.66261E+04 57 coesite -2.38 -3.14 -0.77 -0.256 0.13119E+04 64 cristobalite -2.56 -3.14 -0.58 -0.195 0.99726E+03 66 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71235E+04 68 diaspore 2.87 0.71 -2.16 -0.360 0.36878E+04 69 diamond -3.10 -6.82 -3.72 -1.063 0.63501E+04 70 diopside 16.18 15.95 -0.23 -0.023 0.39675E+03 71 hedenbergite 14.21 13.30 -0.91 -0.091 0.15522E+04 76 clinoenstatite 17.17 12.25 -4.92 -0.492 0.83995E+04 78 epidote 24.67 22.64 -2.03 -0.098 0.34591E+04 79 clinozoisite 22.81 18.65 -4.16 -0.189 0.70992E+04 80 epidote-Fe 29.84 26.64 -3.20 -0.166 0.54657E+04 81 fayalite 14.05 10.09 -3.95 -0.565 0.67511E+04 82 ferrosilite 11.15 6.95 -4.20 -0.420 0.71748E+04 86 gibbsite 4.08 0.71 -3.37 -0.481 0.57463E+04 87 glaucophane 22.97 20.75 -2.23 -0.060 0.38035E+04 88 glaucophane-Fe 17.28 12.80 -4.48 -0.121 0.76460E+04 89 graphite -3.55 -6.82 -3.28 -0.936 0.55924E+04 90 greenalite 16.14 13.57 -2.57 -0.214 0.43949E+04 93 hematite 12.57 9.42 -3.15 -0.381 0.53732E+04 94 heulandite -5.83 -7.61 -1.79 -0.081 0.30492E+04 98 jadeite 4.22 2.76 -1.45 -0.145 0.24840E+04 100 kalsilite 7.58 3.80 -3.78 -0.540 0.64572E+04 101 kaolinite -1.33 -4.86 -3.53 -0.321 0.60243E+04 104 laumontite 2.88 1.82 -1.06 -0.071 0.18155E+04 105 lawsonite 9.62 8.11 -1.51 -0.100 0.25734E+04 106 leucite 4.12 0.66 -3.46 -0.346 0.59097E+04 108 lizardite 23.24 21.51 -1.73 -0.144 0.29520E+04 110 magnetite 20.09 16.04 -4.05 -0.331 0.69152E+04 111 minnesotaite 10.39 7.28 -3.11 -0.183 0.53124E+04 115 manganosite 14.06 9.24 -4.82 -1.205 0.82320E+04 119 microcline -2.49 -2.49 0.00 0.000 0.15695E+00 123 muscovite 2.58 -1.06 -3.64 -0.214 0.62172E+04 124 paragonite 4.24 1.04 -3.20 -0.188 0.54562E+04 125 nepheline 8.34 5.90 -2.43 -0.348 0.41569E+04 137 phlogopite-Na 29.65 27.42 -2.23 -0.124 0.38024E+04 139 prehnite 19.37 17.93 -1.44 -0.085 0.24545E+04 140 prehnite-Fe 22.50 21.93 -0.57 -0.034 0.96941E+03 141 pumpellyite-Fe 46.27 43.20 -3.07 -0.068 0.52396E+04 142 pumpellyite-Mg 48.99 45.85 -3.14 -0.070 0.53688E+04 145 pyrite -21.25 -25.80 -4.56 -1.072 0.77808E+04 146 pyrrhotite -4.26 -7.68 -3.42 -1.141 0.58465E+04 147 pyrrhotiteFe0.875 -6.02 -8.98 -2.97 -1.092 0.50678E+04 148 pyroxmangite 7.40 6.09 -1.31 -0.261 0.22301E+04 149 pyrophyllite -6.18 -11.15 -4.97 -0.311 0.84929E+04 150 quartz -2.99 -3.14 -0.15 -0.052 0.26459E+03 154 rhodochrosite -0.98 -5.22 -4.24 -1.414 0.72432E+04 155 rhodonite 7.45 6.09 -1.35 -0.271 0.23104E+04 156 sanidine -1.28 -2.49 -1.21 -0.093 0.20679E+04 166 stilbite -7.52 -7.61 -0.09 -0.004 0.15539E+03 167 stilpnomelane-Fe 13.02 12.48 -0.54 -0.016 0.91744E+03 168 stilpnomelane-Mg 27.44 25.73 -1.71 -0.051 0.29246E+04 174 talc 16.49 15.23 -1.26 -0.074 0.21598E+04 177 tephroite 18.09 15.33 -2.76 -0.394 0.47062E+04 181 tridymite -2.63 -3.14 -0.52 -0.173 0.88456E+03 182 tremolite 47.87 47.12 -0.75 -0.020 0.12722E+04 183 ferroactinolite 38.45 33.88 -4.58 -0.124 0.78153E+04 184 troilite-low -4.41 -7.68 -3.27 -1.091 0.55893E+04 190 wairakite 3.95 1.82 -2.13 -0.125 0.36375E+04 191 walstromite 11.51 9.83 -1.68 -0.337 0.28750E+04 192 wollastonite 10.46 9.83 -0.64 -0.127 0.10854E+04 193 pseudo-wollastonite 11.00 9.83 -1.17 -0.235 0.20052E+04 194 zoisite 22.85 18.65 -4.20 -0.191 0.71733E+04 195 akaganeite 7.75 4.71 -3.04 -0.658 0.51992E+04 202 chalcedony -2.80 -3.14 -0.34 -0.114 0.58388E+03 204 montmorillonite-Ca -2.29 -6.19 -3.90 -0.241 0.66526E+04 205 montmorillonite-K -2.24 -6.27 -4.03 -0.247 0.68870E+04 206 montmorillonite-Mg -2.48 -6.80 -4.32 -0.267 0.73726E+04 207 montmorillonite-Na -2.04 -5.58 -3.54 -0.217 0.60418E+04 208 nontronite-Ca 3.21 0.25 -2.96 -0.192 0.50534E+04 209 nontronite-H 2.53 -1.89 -4.42 -0.296 0.75432E+04 210 nontronite-K 3.34 0.17 -3.17 -0.203 0.54109E+04 211 nontronite-Mg 3.07 -0.36 -3.43 -0.223 0.58574E+04 212 nontronite-Na 3.52 0.87 -2.65 -0.170 0.45317E+04 228 tobermorite 9.82 7.66 -2.16 -0.590 0.36942E+04 234 alabandite -0.98 -5.07 -4.09 -1.363 0.69796E+04 237 boehmite 4.41 0.71 -3.69 -0.615 0.63047E+04 239 ferrous-oxide 9.81 6.62 -3.19 -0.798 0.54527E+04 245 silica-amorphous -2.09 -3.14 -1.05 -0.351 0.17981E+04 247 an20ab80 2.02 1.31 -0.70 -0.054 0.12005E+04 248 an25ab75 2.65 1.74 -0.91 -0.070 0.15476E+04 249 an30ab70 3.28 2.16 -1.12 -0.086 0.19043E+04 250 tr.625ac.25prg.125 45.16 44.75 -0.42 -0.011 0.70955E+03 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 0.0000400 MOLES Current total amount of reactant added: 0.0018300 MOLES New total amount of reactant added: 0.0018700 MOLES Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.5508E-08 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 6 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 0.0018700 Water: Moles liquid = 0.4985E+02 kg liquid = 0.8981E+00 Moles total = 0.4985E+02 kg total = 0.8980E+00 Activity = 1.0000 Stoichiometric ionic strength = .1144956E-01 Osmotic coef. = 0.9640 True ionic strength = .2012681E-01 Chg. balance for total moles = -.5508E-08 Max. difference allowed = 0.1489E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.91270E-10 -10.0397 0.76665E-10 -10.1154 0.83997E+00 -0.0757 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.16506E-03 -3.7824 0.13781E-03 -3.8607 0.83490E+00 -0.0784 4 SO4-- 0.94644E-09 -9.0239 0.49080E-09 -9.3091 0.51858E+00 -0.2852 5 HCO3- 0.55942E-04 -4.2523 0.46774E-04 -4.3300 0.83613E+00 -0.0777 6 HS- 0.78980E-04 -4.1025 0.65950E-04 -4.1808 0.83502E+00 -0.0783 7 Al+++ 0.10113E-28 -28.9951 0.23288E-29 -29.6329 0.23029E+00 -0.6377 8 H4SiO4 0.71762E-03 -3.1441 0.71762E-03 -3.1441 0.10000E+01 0.0000 9 Ca++ 0.10602E-06 -6.9746 0.54572E-07 -7.2630 0.51475E+00 -0.2884 10 Mg++ 0.21228E-10 -10.6731 0.10877E-10 -10.9635 0.51239E+00 -0.2904 11 Fe++ 0.47575E-13 -13.3226 0.24404E-13 -13.6125 0.51295E+00 -0.2899 12 K+ 0.15653E-03 -3.8054 0.13091E-03 -3.8830 0.83633E+00 -0.0776 13 Na+ 0.19867E-01 -1.7019 0.16584E-01 -1.7803 0.83475E+00 -0.0784 14 Mn++ 0.19755E-10 -10.7043 0.10142E-10 -10.9939 0.51338E+00 -0.2896 15 F- 0.94118E-06 -6.0263 0.78417E-06 -6.1056 0.83317E+00 -0.0793 16 HPO4-- 0.45345E-07 -7.3435 0.23518E-07 -7.6286 0.51865E+00 -0.2851 18 HSiO3- 0.10469E-01 -1.9801 0.87404E-02 -2.0585 0.83490E+00 -0.0784 19 Ca(HSiO3)+ 0.12986E-07 -7.8865 0.10863E-07 -7.9641 0.83651E+00 -0.0775 20 Mg(HSiO3)+ 0.32211E-11 -11.4920 0.26945E-11 -11.5695 0.83651E+00 -0.0775 21 NaHSiO3,aq 0.23443E-02 -2.6300 0.23443E-02 -2.6300 0.10000E+01 0.0000 22 AlO+ 0.64440E-16 -16.1908 0.53904E-16 -16.2684 0.83651E+00 -0.0775 24 HAlO2,aq 0.14002E-09 -9.8538 0.14002E-09 -9.8538 0.10000E+01 0.0000 25 AlO2- 0.48513E-05 -5.3141 0.40430E-05 -5.3933 0.83339E+00 -0.0792 26 CH4,aq 0.61266E-05 -5.2128 0.61052E-05 -5.2143 0.99651E+00 -0.0015 27 C2H6,aq 0.25936E-14 -14.5861 0.25845E-14 -14.5876 0.99651E+00 -0.0015 31 CO,aq 0.47457E-15 -15.3237 0.47457E-15 -15.3237 0.10000E+01 0.0000 32 CO2,aq 0.76892E-08 -8.1141 0.76623E-08 -8.1156 0.99651E+00 -0.0015 33 CO3-2 0.10298E-03 -3.9872 0.53291E-04 -4.2733 0.51747E+00 -0.2861 34 CaCO3,aq 0.36466E-07 -7.4381 0.36466E-07 -7.4381 0.10000E+01 0.0000 35 Ca(HCO3)+ 0.77891E-10 -10.1085 0.65157E-10 -10.1860 0.83651E+00 -0.0775 36 CaCl+ 0.14549E-10 -10.8372 0.12170E-10 -10.9147 0.83651E+00 -0.0775 37 CaCl2,aq 0.39846E-15 -15.3996 0.39846E-15 -15.3996 0.10000E+01 0.0000 38 CaF+ 0.74690E-12 -12.1267 0.62479E-12 -12.2043 0.83651E+00 -0.0775 39 CaOH+ 0.60647E-07 -7.2172 0.50731E-07 -7.2947 0.83651E+00 -0.0775 40 CaSO4,aq 0.85052E-14 -14.0703 0.85052E-14 -14.0703 0.10000E+01 0.0000 41 HCl,aq 0.19360E-14 -14.7131 0.19360E-14 -14.7131 0.10000E+01 0.0000 45 HF,aq 0.41155E-12 -12.3856 0.41155E-12 -12.3856 0.10000E+01 0.0000 46 HF2- 0.13051E-18 -18.8844 0.10896E-18 -18.9627 0.83490E+00 -0.0784 48 FeCl+ 0.63634E-17 -17.1963 0.53230E-17 -17.2738 0.83651E+00 -0.0775 51 FeF+ 0.11690E-17 -17.9322 0.97791E-18 -18.0097 0.83651E+00 -0.0775 53 FeO,aq 0.16137E-09 -9.7922 0.16137E-09 -9.7922 0.10000E+01 0.0000 54 FeOH+ 0.12387E-10 -10.9070 0.10362E-10 -10.9846 0.83651E+00 -0.0775 55 HFeO2- 0.26379E-07 -7.5787 0.22024E-07 -7.6571 0.83490E+00 -0.0784 56 FeO+ 0.18816E-16 -16.7255 0.15740E-16 -16.8030 0.83651E+00 -0.0775 58 FeO2- 0.65632E-09 -9.1829 0.54796E-09 -9.2612 0.83490E+00 -0.0784 59 HFeO2,aq 0.53430E-11 -11.2722 0.53430E-11 -11.2722 0.10000E+01 0.0000 60 H2,aq 0.24742E-05 -5.6066 0.24655E-05 -5.6081 0.99651E+00 -0.0015 61 KCl,aq 0.32696E-09 -9.4855 0.32696E-09 -9.4855 0.10000E+01 0.0000 63 KOH,aq 0.72921E-06 -6.1371 0.72921E-06 -6.1371 0.10000E+01 0.0000 64 KSO4- 0.11942E-11 -11.9229 0.99700E-12 -12.0013 0.83490E+00 -0.0784 65 MgCO3,aq 0.18218E-11 -11.7395 0.18218E-11 -11.7395 0.10000E+01 0.0000 66 Mg(HCO3)+ 0.15864E-13 -13.7996 0.13270E-13 -13.8771 0.83651E+00 -0.0775 67 MgCl+ 0.26283E-14 -14.5803 0.21986E-14 -14.6579 0.83651E+00 -0.0775 68 MgF+ 0.55147E-15 -15.2585 0.46131E-15 -15.3360 0.83651E+00 -0.0775 69 MgOH+ 0.66889E-10 -10.1746 0.55953E-10 -10.2522 0.83651E+00 -0.0775 71 MnF+ 0.16014E-15 -15.7955 0.13396E-15 -15.8730 0.83651E+00 -0.0775 72 MnO,aq 0.17870E-08 -8.7479 0.17870E-08 -8.7479 0.10000E+01 0.0000 73 MnOH+ 0.47822E-09 -9.3204 0.40003E-09 -9.3979 0.83651E+00 -0.0775 74 MnO2-2 0.19499E-10 -10.7100 0.10090E-10 -10.9961 0.51747E+00 -0.2861 75 HMnO2- 0.20299E-09 -9.6925 0.16948E-09 -9.7709 0.83490E+00 -0.0784 78 MnCl+ 0.10289E-13 -13.9876 0.86066E-14 -14.0652 0.83651E+00 -0.0775 79 MnSO4,aq 0.14370E-17 -17.8425 0.14370E-17 -17.8425 0.10000E+01 0.0000 80 NaCl,aq 0.75738E-06 -6.1207 0.75738E-06 -6.1207 0.10000E+01 0.0000 81 NaF,aq 0.30446E-08 -8.5165 0.30446E-08 -8.5165 0.10000E+01 0.0000 82 NaOH,aq 0.92940E-04 -4.0318 0.92940E-04 -4.0318 0.10000E+01 0.0000 84 OH- 0.90431E-02 -2.0437 0.75364E-02 -2.1228 0.83339E+00 -0.0792 89 HPO3-2 0.34920E-15 -15.4569 0.18070E-15 -15.7430 0.51747E+00 -0.2861 91 H2PO3- 0.33273E-19 -19.4779 0.27780E-19 -19.5563 0.83490E+00 -0.0784 92 H3PO4,aq 0.96675E-18 -18.0147 0.96675E-18 -18.0147 0.10000E+01 0.0000 93 H2PO4- 0.39800E-10 -10.4001 0.33260E-10 -10.4781 0.83569E+00 -0.0780 94 PO4-3 0.10346E-08 -8.9852 0.25029E-09 -9.6016 0.24192E+00 -0.6163 98 HP2O7-3 0.98006E-18 -18.0087 0.22592E-18 -18.6460 0.23052E+00 -0.6373 99 P2O7-4 0.91815E-17 -17.0371 0.70400E-18 -18.1524 0.76676E-01 -1.1153 100 H2S,aq 0.15681E-07 -7.8046 0.15626E-07 -7.8061 0.99651E+00 -0.0015 101 S2-2 0.75537E-13 -13.1218 0.39088E-13 -13.4080 0.51747E+00 -0.2861 107 SO3-2 0.29953E-15 -15.5236 0.15725E-15 -15.8034 0.52499E+00 -0.2799 108 HSO3- 0.90409E-18 -18.0438 0.75483E-18 -18.1222 0.83490E+00 -0.0784 109 HSO4- 0.43307E-16 -16.3634 0.36262E-16 -16.4405 0.83732E+00 -0.0771 111 S2O3-2 0.17410E-18 -18.7592 0.90091E-19 -19.0453 0.51747E+00 -0.2861 Charge balance for all species = -.6133E-08 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.9127040E-10 -.2207300E-01 -.2220945E+02 0.0000 2 H2O 0.1000000E+01 0.5550459E+02 0.9981877E+06 0.0000 3 Cl- 0.1650583E-03 0.1658160E-03 0.5868422E+01 6.2547 4 SO4-- 0.9464416E-09 -.6744146E-05 -.6467234E+00 10.9217 5 HCO3- 0.5594174E-04 0.1650965E-03 0.1005616E+02 5.7854 6 HS- 0.7897960E-04 0.8574038E-04 0.2830659E+01 5.9346 7 Al+++ 0.1011264E-28 0.4851431E-05 0.1306705E+00 0.7133 8 H4SiO4 0.7176246E-03 0.1353071E-01 0.1298241E+04 -3.1441 9 Ca++ 0.1060151E-06 0.2162062E-06 0.8649998E-02 12.9678 10 Mg++ 0.2122832E-10 0.9317950E-10 0.2261428E-05 9.2673 11 Fe++ 0.4757462E-13 0.2721457E-07 0.1517201E-02 6.6183 12 K+ 0.1565263E-03 0.1572558E-03 0.6138292E+01 6.2324 13 Na+ 0.1986686E-01 0.2230490E-01 0.5118906E+03 8.3351 14 Mn++ 0.1975536E-10 0.2507485E-08 0.1375159E-03 9.2369 15 F- 0.9411837E-06 0.9442295E-06 0.1790718E-01 4.0098 16 HPO4-- 0.4534450E-07 0.4641889E-07 0.4447467E-02 12.6022 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.1982519E-01 -.1982347E-01 -.1715368E-05 0.0000000E+00 2 H2O 0.4984794E+02 0.4984794E+02 -.1672967E-05 0.0000000E+00 3 Cl- 0.1489172E-03 0.1489172E-03 0.0000000E+00 0.0000000E+00 4 SO4-- -.6055810E-05 -.6056829E-05 0.1018903E-08 0.0000000E+00 5 HCO3- 0.1482710E-03 0.1482710E-03 0.0000000E+00 0.0000000E+00 6 HS- 0.7700128E-04 0.7700230E-04 -.1018903E-08 0.0000000E+00 7 Al+++ 0.4775352E-05 0.4357006E-05 0.4183461E-06 0.0000000E+00 8 H4SiO4 0.1215302E-01 0.1215175E-01 0.1265580E-05 0.0000000E+00 9 Ca++ 0.2080835E-06 0.1941720E-06 0.1391155E-07 0.0000000E+00 10 Mg++ 0.8368328E-10 0.8368328E-10 0.0000000E+00 0.0000000E+00 11 Fe++ 0.3259227E-07 0.2444104E-07 0.8151226E-08 0.0000000E+00 12 K+ 0.1412294E-03 0.1412294E-03 0.0000000E+00 0.0000000E+00 13 Na+ 0.2003215E-01 0.2003173E-01 0.4172230E-06 0.0000000E+00 14 Mn++ 0.2251939E-08 0.2251939E-08 0.0000000E+00 0.0000000E+00 15 F- 0.8480000E-06 0.8480000E-06 0.0000000E+00 0.0000000E+00 16 HPO4-- 0.4168819E-07 0.4168819E-07 0.0000000E+00 0.0000000E+00 Chg. balance for solid moles: 0.1588E-21 Mass of aqueous solution: 0.899656E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 0.0018700 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 0.4172E-06 -6.380 0.1094E-03 -3.961 97.92 0.4200E-04 andradite 0.4076E-08 -8.390 0.2071E-05 -5.684 1.854 0.5381E-06 grossular 0.5616E-09 -9.251 0.2530E-06 -6.597 0.2264 0.7038E-07 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8789E+00 0.8789E+00 1.0000 -0.056 grossular 0.1211E+00 0.1211E+00 1.0000 -0.917 Solid products produced: Mass = 0.000112 g Volume = 0.000043 cm3 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.0018700 moles log = -2.7282 Original solution: 1000.0103000 g Original solution / Rock added: 534764.87 (Water/Rock Ratio), log = 5.7282 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0326 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9883E+00 0.9858 0.1006E+01 0.1020E+01 CO2,gas 0.7884E-06 1.0070 0.8198E-06 0.8141E-06 CH4,gas 0.8596E-02 1.0124 0.8987E-02 0.8876E-02 H2,gas 0.3133E-02 1.0006 0.3237E-02 0.3235E-02 H2S,gas 0.4177E-06 0.9960 0.4296E-06 0.4313E-06 S2,gas 0.6402E-27 1.0000 0.6610E-27 0.6610E-27 CO,gas 0.6849E-12 1.0000 0.7072E-12 0.7072E-12 SO3,gas 0.1056E-44 1.0000 0.1091E-44 0.1091E-44 SO2,gas 0.1330E-24 1.0000 0.1374E-24 0.1374E-24 HF,gas 0.9786E-15 1.0000 0.1010E-14 0.1010E-14 HCl,gas 0.3308E-17 1.0000 0.3416E-17 0.3416E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 17 albite -0.38 -0.38 0.00 0.000 -0.94784E-12 23 andradite 39.01 39.01 0.00 0.000 -0.12132E-10 24 grossular 32.73 32.73 0.00 0.000 0.00000E+00 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -14.45 -7.79 -2.595 0.13293E+05 -6.086 3 CH4,gas 4.54 0.80 -3.75 -0.936 0.63951E+04 -2.046 4 H2,gas 8.00 3.81 -4.19 -2.394 0.71523E+04 -2.490 5 H2S,gas -6.23 -14.30 -8.07 -4.033 0.13772E+05 -6.367 6 S2,gas -7.34 -36.21 -28.88 -4.443 0.49310E+05 -27.180 7 CO,gas 3.21 -10.63 -13.85 -4.261 0.23648E+05 -12.150 8 SO3,gas 17.12 -29.54 -46.66 -11.665 0.79673E+05 -44.962 9 SO2,gas 0.83 -25.73 -26.56 -7.083 0.45352E+05 -24.862 10 HF,gas 0.47 -16.22 -16.69 -8.347 0.28505E+05 -14.995 11 HCl,gas 5.19 -13.98 -19.17 -9.583 0.32724E+05 -17.466 12 acmite 7.71 6.76 -0.95 -0.099 0.16221E+04 16 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 20 spessartine 24.46 19.71 -4.75 -0.238 0.81141E+04 21 analcite 3.32 2.76 -0.56 -0.062 0.95896E+03 27 annite 20.12 17.37 -2.76 -0.153 0.47044E+04 28 phlogopite 27.06 25.32 -1.75 -0.097 0.29867E+04 30 anorthite 12.71 8.11 -4.60 -0.354 0.78613E+04 33 apatite-OH -18.15 -18.74 -0.59 -0.045 0.10003E+04 34 apatite-F -34.30 -34.96 -0.66 -0.055 0.11258E+04 38 aragonite 0.97 -1.48 -2.44 -0.815 0.41733E+04 39 brucite 12.57 9.27 -3.30 -0.660 0.56368E+04 40 calcite 0.81 -1.48 -2.29 -0.763 0.39091E+04 41 carnegieite-low 9.02 5.90 -3.12 -0.446 0.53255E+04 42 carnegieite-high 10.09 5.90 -4.19 -0.598 0.71525E+04 43 carpholite-Mg 8.58 4.41 -4.18 -0.278 0.71309E+04 44 carpholite-Fe 6.71 1.76 -4.96 -0.330 0.84620E+04 45 celadonite 5.34 3.64 -1.70 -0.100 0.29112E+04 46 celadonite-Fe 3.88 0.99 -2.89 -0.170 0.49328E+04 47 chrysotile 23.89 21.51 -2.38 -0.198 0.40614E+04 49 clinochlore 39.07 38.33 -0.74 -0.023 0.12609E+04 50 daphnite 28.97 25.09 -3.88 -0.121 0.66242E+04 52 chlorite-Al-free 47.17 43.03 -4.15 -0.173 0.70780E+04 54 chloritoid-Fe 9.17 4.90 -4.27 -0.285 0.72956E+04 55 chloritoid-Mn 11.40 7.52 -3.88 -0.259 0.66276E+04 57 coesite -2.38 -3.14 -0.77 -0.256 0.13114E+04 64 cristobalite -2.56 -3.14 -0.58 -0.195 0.99676E+03 66 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71235E+04 68 diaspore 2.87 0.71 -2.16 -0.360 0.36887E+04 69 diamond -3.10 -6.82 -3.72 -1.063 0.63538E+04 70 diopside 16.18 15.95 -0.23 -0.023 0.40033E+03 71 hedenbergite 14.21 13.30 -0.91 -0.091 0.15546E+04 76 clinoenstatite 17.17 12.25 -4.92 -0.492 0.84005E+04 78 epidote 24.67 22.64 -2.03 -0.098 0.34613E+04 79 clinozoisite 22.81 18.64 -4.16 -0.189 0.71077E+04 80 epidote-Fe 29.84 26.64 -3.20 -0.166 0.54615E+04 81 fayalite 14.05 10.09 -3.95 -0.565 0.67502E+04 82 ferrosilite 11.15 6.95 -4.20 -0.420 0.71733E+04 86 gibbsite 4.08 0.71 -3.37 -0.481 0.57473E+04 87 glaucophane 22.97 20.75 -2.23 -0.060 0.38056E+04 88 glaucophane-Fe 17.28 12.80 -4.48 -0.121 0.76443E+04 89 graphite -3.55 -6.82 -3.28 -0.936 0.55960E+04 90 greenalite 16.14 13.57 -2.57 -0.214 0.43932E+04 93 hematite 12.57 9.43 -3.14 -0.381 0.53625E+04 94 heulandite -5.83 -7.61 -1.79 -0.081 0.30512E+04 98 jadeite 4.22 2.76 -1.46 -0.146 0.24844E+04 100 kalsilite 7.58 3.80 -3.78 -0.540 0.64582E+04 101 kaolinite -1.33 -4.86 -3.53 -0.321 0.60252E+04 104 laumontite 2.88 1.82 -1.07 -0.071 0.18190E+04 105 lawsonite 9.62 8.11 -1.51 -0.101 0.25779E+04 106 leucite 4.12 0.66 -3.46 -0.346 0.59102E+04 108 lizardite 23.24 21.51 -1.73 -0.144 0.29540E+04 110 magnetite 20.09 16.04 -4.04 -0.330 0.69042E+04 111 minnesotaite 10.39 7.28 -3.11 -0.183 0.53098E+04 115 manganosite 14.06 9.24 -4.82 -1.205 0.82320E+04 119 microcline -2.49 -2.49 0.00 0.000 0.16046E+00 123 muscovite 2.58 -1.06 -3.64 -0.214 0.62192E+04 124 paragonite 4.24 1.04 -3.20 -0.188 0.54581E+04 125 nepheline 8.34 5.90 -2.44 -0.348 0.41579E+04 137 phlogopite-Na 29.65 27.42 -2.23 -0.124 0.38054E+04 139 prehnite 19.37 17.93 -1.44 -0.085 0.24621E+04 140 prehnite-Fe 22.50 21.93 -0.57 -0.034 0.97064E+03 141 pumpellyite-Fe 46.27 43.19 -3.08 -0.068 0.52554E+04 142 pumpellyite-Mg 48.99 45.84 -3.15 -0.070 0.53859E+04 145 pyrite -21.25 -25.79 -4.54 -1.068 0.77487E+04 146 pyrrhotite -4.26 -7.68 -3.42 -1.139 0.58355E+04 147 pyrrhotiteFe0.875 -6.02 -8.98 -2.96 -1.089 0.50555E+04 148 pyroxmangite 7.40 6.09 -1.31 -0.261 0.22297E+04 149 pyrophyllite -6.18 -11.15 -4.97 -0.311 0.84928E+04 150 quartz -2.99 -3.14 -0.15 -0.052 0.26409E+03 154 rhodochrosite -0.98 -5.21 -4.23 -1.411 0.72263E+04 155 rhodonite 7.45 6.09 -1.35 -0.271 0.23099E+04 156 sanidine -1.28 -2.49 -1.21 -0.093 0.20679E+04 166 stilbite -7.52 -7.61 -0.09 -0.004 0.15741E+03 167 stilpnomelane-Fe 13.02 12.48 -0.54 -0.016 0.91450E+03 168 stilpnomelane-Mg 27.44 25.73 -1.71 -0.051 0.29278E+04 174 talc 16.49 15.23 -1.27 -0.074 0.21608E+04 177 tephroite 18.09 15.33 -2.76 -0.394 0.47058E+04 181 tridymite -2.63 -3.14 -0.52 -0.173 0.88407E+03 182 tremolite 47.87 47.12 -0.75 -0.020 0.12804E+04 183 ferroactinolite 38.45 33.87 -4.58 -0.124 0.78173E+04 184 troilite-low -4.41 -7.68 -3.27 -1.089 0.55783E+04 190 wairakite 3.95 1.82 -2.13 -0.125 0.36410E+04 191 walstromite 11.51 9.82 -1.69 -0.337 0.28780E+04 192 wollastonite 10.46 9.82 -0.64 -0.127 0.10885E+04 193 pseudo-wollastonite 11.00 9.82 -1.18 -0.235 0.20083E+04 194 zoisite 22.85 18.64 -4.21 -0.191 0.71818E+04 195 akaganeite 7.75 4.71 -3.04 -0.658 0.51938E+04 202 chalcedony -2.80 -3.14 -0.34 -0.114 0.58339E+03 204 montmorillonite-Ca -2.29 -6.19 -3.90 -0.241 0.66532E+04 205 montmorillonite-K -2.24 -6.27 -4.03 -0.247 0.68871E+04 206 montmorillonite-Mg -2.48 -6.80 -4.32 -0.267 0.73727E+04 207 montmorillonite-Na -2.04 -5.58 -3.54 -0.217 0.60419E+04 208 nontronite-Ca 3.21 0.26 -2.95 -0.192 0.50417E+04 209 nontronite-H 2.53 -1.88 -4.41 -0.296 0.75309E+04 210 nontronite-K 3.34 0.18 -3.16 -0.203 0.53988E+04 211 nontronite-Mg 3.07 -0.35 -3.42 -0.222 0.58453E+04 212 nontronite-Na 3.52 0.87 -2.65 -0.170 0.45196E+04 228 tobermorite 9.82 7.66 -2.16 -0.591 0.36967E+04 234 alabandite -0.98 -5.06 -4.08 -1.360 0.69689E+04 237 boehmite 4.41 0.71 -3.69 -0.615 0.63057E+04 239 ferrous-oxide 9.81 6.62 -3.19 -0.798 0.54525E+04 245 silica-amorphous -2.09 -3.14 -1.05 -0.351 0.17976E+04 247 an20ab80 2.02 1.31 -0.70 -0.054 0.12014E+04 248 an25ab75 2.65 1.74 -0.91 -0.070 0.15487E+04 249 an30ab70 3.28 2.16 -1.12 -0.086 0.19057E+04 250 tr.625ac.25prg.125 45.16 44.75 -0.42 -0.011 0.71662E+03 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 0.0000400 MOLES Current total amount of reactant added: 0.0018700 MOLES New total amount of reactant added: 0.0019100 MOLES Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.5508E-08 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 6 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 0.0019100 Water: Moles liquid = 0.4985E+02 kg liquid = 0.8981E+00 Moles total = 0.4985E+02 kg total = 0.8980E+00 Activity = 1.0000 Stoichiometric ionic strength = .1145211E-01 Osmotic coef. = 0.9639 True ionic strength = .2012915E-01 Chg. balance for total moles = -.5508E-08 Max. difference allowed = 0.1492E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.91336E-10 -10.0394 0.76720E-10 -10.1151 0.83997E+00 -0.0757 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.16532E-03 -3.7817 0.13802E-03 -3.8600 0.83489E+00 -0.0784 4 SO4-- 0.10143E-08 -8.9938 0.52597E-09 -9.2790 0.51856E+00 -0.2852 5 HCO3- 0.57172E-04 -4.2428 0.47803E-04 -4.3205 0.83612E+00 -0.0777 6 HS- 0.80062E-04 -4.0966 0.66853E-04 -4.1749 0.83502E+00 -0.0783 7 Al+++ 0.10122E-28 -28.9947 0.23308E-29 -29.6325 0.23027E+00 -0.6378 8 H4SiO4 0.71811E-03 -3.1438 0.71811E-03 -3.1438 0.10000E+01 0.0000 9 Ca++ 0.10566E-06 -6.9761 0.54387E-07 -7.2645 0.51474E+00 -0.2884 10 Mg++ 0.21231E-10 -10.6730 0.10878E-10 -10.9634 0.51237E+00 -0.2904 11 Fe++ 0.47655E-13 -13.3219 0.24444E-13 -13.6118 0.51294E+00 -0.2899 12 K+ 0.15653E-03 -3.8054 0.13091E-03 -3.8830 0.83632E+00 -0.0776 13 Na+ 0.19867E-01 -1.7019 0.16584E-01 -1.7803 0.83474E+00 -0.0784 14 Mn++ 0.19783E-10 -10.7037 0.10156E-10 -10.9933 0.51336E+00 -0.2896 15 F- 0.95894E-06 -6.0182 0.79896E-06 -6.0975 0.83317E+00 -0.0793 16 HPO4-- 0.45345E-07 -7.3435 0.23518E-07 -7.6286 0.51864E+00 -0.2851 18 HSiO3- 0.10468E-01 -1.9801 0.87399E-02 -2.0585 0.83489E+00 -0.0784 19 Ca(HSiO3)+ 0.12941E-07 -7.8880 0.10825E-07 -7.9656 0.83650E+00 -0.0775 20 Mg(HSiO3)+ 0.32213E-11 -11.4920 0.26946E-11 -11.5695 0.83650E+00 -0.0775 21 NaHSiO3,aq 0.23442E-02 -2.6300 0.23442E-02 -2.6300 0.10000E+01 0.0000 22 AlO+ 0.64403E-16 -16.1911 0.53873E-16 -16.2686 0.83650E+00 -0.0775 24 HAlO2,aq 0.13984E-09 -9.8544 0.13984E-09 -9.8544 0.10000E+01 0.0000 25 AlO2- 0.48416E-05 -5.3150 0.40349E-05 -5.3942 0.83338E+00 -0.0792 26 CH4,aq 0.59227E-05 -5.2275 0.59020E-05 -5.2290 0.99651E+00 -0.0015 27 C2H6,aq 0.24581E-14 -14.6094 0.24495E-14 -14.6109 0.99651E+00 -0.0015 31 CO,aq 0.47857E-15 -15.3201 0.47857E-15 -15.3201 0.10000E+01 0.0000 32 CO2,aq 0.78639E-08 -8.1044 0.78364E-08 -8.1059 0.99651E+00 -0.0015 33 CO3-2 0.10518E-03 -3.9781 0.54424E-04 -4.2642 0.51746E+00 -0.2861 34 CaCO3,aq 0.37115E-07 -7.4305 0.37115E-07 -7.4305 0.10000E+01 0.0000 35 Ca(HCO3)+ 0.79335E-10 -10.1005 0.66364E-10 -10.1781 0.83650E+00 -0.0775 36 CaCl+ 0.14523E-10 -10.8380 0.12148E-10 -10.9155 0.83650E+00 -0.0775 37 CaCl2,aq 0.39836E-15 -15.3997 0.39836E-15 -15.3997 0.10000E+01 0.0000 38 CaF+ 0.75842E-12 -12.1201 0.63441E-12 -12.1976 0.83650E+00 -0.0775 39 CaOH+ 0.60398E-07 -7.2190 0.50523E-07 -7.2965 0.83650E+00 -0.0775 40 CaSO4,aq 0.90838E-14 -14.0417 0.90838E-14 -14.0417 0.10000E+01 0.0000 41 HCl,aq 0.19404E-14 -14.7121 0.19404E-14 -14.7121 0.10000E+01 0.0000 45 HF,aq 0.41961E-12 -12.3772 0.41961E-12 -12.3772 0.10000E+01 0.0000 46 HF2- 0.13557E-18 -18.8678 0.11319E-18 -18.9462 0.83489E+00 -0.0784 48 FeCl+ 0.63841E-17 -17.1949 0.53403E-17 -17.2724 0.83650E+00 -0.0775 51 FeF+ 0.11931E-17 -17.9233 0.99801E-18 -18.0009 0.83650E+00 -0.0775 53 FeO,aq 0.16141E-09 -9.7921 0.16141E-09 -9.7921 0.10000E+01 0.0000 54 FeOH+ 0.12398E-10 -10.9066 0.10371E-10 -10.9842 0.83650E+00 -0.0775 55 HFeO2- 0.26366E-07 -7.5789 0.22013E-07 -7.6573 0.83489E+00 -0.0784 56 FeO+ 0.18967E-16 -16.7220 0.15866E-16 -16.7995 0.83650E+00 -0.0775 58 FeO2- 0.66064E-09 -9.1800 0.55157E-09 -9.2584 0.83489E+00 -0.0784 59 HFeO2,aq 0.53819E-11 -11.2691 0.53819E-11 -11.2691 0.10000E+01 0.0000 60 H2,aq 0.24396E-05 -5.6127 0.24311E-05 -5.6142 0.99651E+00 -0.0015 61 KCl,aq 0.32747E-09 -9.4848 0.32747E-09 -9.4848 0.10000E+01 0.0000 63 KOH,aq 0.72869E-06 -6.1375 0.72869E-06 -6.1375 0.10000E+01 0.0000 64 KSO4- 0.12797E-11 -11.8929 0.10684E-11 -11.9713 0.83489E+00 -0.0784 65 MgCO3,aq 0.18607E-11 -11.7303 0.18607E-11 -11.7303 0.10000E+01 0.0000 66 Mg(HCO3)+ 0.16214E-13 -13.7901 0.13563E-13 -13.8676 0.83650E+00 -0.0775 67 MgCl+ 0.26327E-14 -14.5796 0.22022E-14 -14.6571 0.83650E+00 -0.0775 68 MgF+ 0.56192E-15 -15.2503 0.47004E-15 -15.3279 0.83650E+00 -0.0775 69 MgOH+ 0.66847E-10 -10.1749 0.55918E-10 -10.2525 0.83650E+00 -0.0775 71 MnF+ 0.16338E-15 -15.7868 0.13667E-15 -15.8643 0.83650E+00 -0.0775 72 MnO,aq 0.17869E-08 -8.7479 0.17869E-08 -8.7479 0.10000E+01 0.0000 73 MnOH+ 0.47852E-09 -9.3201 0.40029E-09 -9.3976 0.83650E+00 -0.0775 74 MnO2-2 0.19470E-10 -10.7106 0.10075E-10 -10.9968 0.51746E+00 -0.2861 75 HMnO2- 0.20283E-09 -9.6929 0.16934E-09 -9.7712 0.83489E+00 -0.0784 78 MnCl+ 0.10319E-13 -13.9864 0.86318E-14 -14.0639 0.83650E+00 -0.0775 79 MnSO4,aq 0.15421E-17 -17.8119 0.15421E-17 -17.8119 0.10000E+01 0.0000 80 NaCl,aq 0.75857E-06 -6.1200 0.75857E-06 -6.1200 0.10000E+01 0.0000 81 NaF,aq 0.31020E-08 -8.5084 0.31020E-08 -8.5084 0.10000E+01 0.0000 82 NaOH,aq 0.92873E-04 -4.0321 0.92873E-04 -4.0321 0.10000E+01 0.0000 84 OH- 0.90367E-02 -2.0440 0.75310E-02 -2.1231 0.83338E+00 -0.0792 89 HPO3-2 0.34432E-15 -15.4630 0.17817E-15 -15.7492 0.51746E+00 -0.2861 91 H2PO3- 0.32831E-19 -19.4837 0.27411E-19 -19.5621 0.83489E+00 -0.0784 92 H3PO4,aq 0.96812E-18 -18.0141 0.96812E-18 -18.0141 0.10000E+01 0.0000 93 H2PO4- 0.39828E-10 -10.3998 0.33284E-10 -10.4778 0.83569E+00 -0.0780 94 PO4-3 0.10339E-08 -8.9855 0.25010E-09 -9.6019 0.24190E+00 -0.6164 98 HP2O7-3 0.98080E-18 -18.0084 0.22608E-18 -18.6457 0.23050E+00 -0.6373 99 P2O7-4 0.91823E-17 -17.0370 0.70398E-18 -18.1524 0.76667E-01 -1.1154 100 H2S,aq 0.15907E-07 -7.7984 0.15852E-07 -7.7999 0.99651E+00 -0.0015 101 S2-2 0.78723E-13 -13.1039 0.40736E-13 -13.3900 0.51746E+00 -0.2861 107 SO3-2 0.31652E-15 -15.4996 0.16616E-15 -15.7795 0.52497E+00 -0.2799 108 HSO3- 0.95603E-18 -18.0195 0.79818E-18 -18.0979 0.83489E+00 -0.0784 109 HSO4- 0.46444E-16 -16.3331 0.38888E-16 -16.4102 0.83732E+00 -0.0771 111 S2O3-2 0.18927E-18 -18.7229 0.97939E-19 -19.0090 0.51746E+00 -0.2861 Charge balance for all species = -.6133E-08 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.9133650E-10 -.2206815E-01 -.2220457E+02 0.0000 2 H2O 0.1000000E+01 0.5550459E+02 0.9981874E+06 0.0000 3 Cl- 0.1653198E-03 0.1660787E-03 0.5877717E+01 6.2550 4 SO4-- 0.1014295E-08 -.6531468E-05 -.6263288E+00 10.9512 5 HCO3- 0.5717240E-04 0.1683166E-03 0.1025229E+02 5.7945 6 HS- 0.8006155E-04 0.8660994E-04 0.2859367E+01 5.9402 7 Al+++ 0.1012202E-28 0.4841729E-05 0.1304092E+00 0.7128 8 H4SiO4 0.7181055E-03 0.1353067E-01 0.1298237E+04 -3.1438 9 Ca++ 0.1056592E-06 0.2162080E-06 0.8650067E-02 12.9657 10 Mg++ 0.2123075E-10 0.9317943E-10 0.2261426E-05 9.2667 11 Fe++ 0.4765523E-13 0.2720629E-07 0.1516739E-02 6.6184 12 K+ 0.1565267E-03 0.1572557E-03 0.6138287E+01 6.2321 13 Na+ 0.1986700E-01 0.2230487E-01 0.5118899E+03 8.3348 14 Mn++ 0.1978269E-10 0.2507483E-08 0.1375158E-03 9.2369 15 F- 0.9589412E-06 0.9620444E-06 0.1824504E-01 4.0176 16 HPO4-- 0.4534513E-07 0.4641885E-07 0.4447463E-02 12.6016 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.1982088E-01 -.1981913E-01 -.1750226E-05 0.0000000E+00 2 H2O 0.4984797E+02 0.4984797E+02 -.1707844E-05 0.0000000E+00 3 Cl- 0.1491532E-03 0.1491532E-03 0.0000000E+00 0.0000000E+00 4 SO4-- -.5864810E-05 -.5865830E-05 0.1019830E-08 0.0000000E+00 5 HCO3- 0.1511630E-03 0.1511630E-03 0.0000000E+00 0.0000000E+00 6 HS- 0.7778228E-04 0.7778330E-04 -.1019830E-08 0.0000000E+00 7 Al+++ 0.4775352E-05 0.4348296E-05 0.4270558E-06 0.0000000E+00 8 H4SiO4 0.1215302E-01 0.1215173E-01 0.1291733E-05 0.0000000E+00 9 Ca++ 0.2080835E-06 0.1941737E-06 0.1390983E-07 0.0000000E+00 10 Mg++ 0.8368328E-10 0.8368328E-10 0.0000000E+00 0.0000000E+00 11 Fe++ 0.3259227E-07 0.2443363E-07 0.8158643E-08 0.0000000E+00 12 K+ 0.1412294E-03 0.1412294E-03 0.0000000E+00 0.0000000E+00 13 Na+ 0.2003215E-01 0.2003172E-01 0.4259412E-06 0.0000000E+00 14 Mn++ 0.2251939E-08 0.2251939E-08 0.0000000E+00 0.0000000E+00 15 F- 0.8640000E-06 0.8640000E-06 0.0000000E+00 0.0000000E+00 16 HPO4-- 0.4168819E-07 0.4168819E-07 0.0000000E+00 0.0000000E+00 Chg. balance for solid moles: 0.0000E+00 Mass of aqueous solution: 0.899657E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 0.0019100 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 0.4259E-06 -6.371 0.1117E-03 -3.952 97.96 0.4288E-04 andradite 0.4079E-08 -8.389 0.2073E-05 -5.683 1.818 0.5386E-06 grossular 0.5573E-09 -9.254 0.2510E-06 -6.600 0.2202 0.6985E-07 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8798E+00 0.8798E+00 1.0000 -0.056 grossular 0.1202E+00 0.1202E+00 1.0000 -0.920 Solid products produced: Mass = 0.000114 g Volume = 0.000043 cm3 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.0019100 moles log = -2.7190 Original solution: 1000.0103000 g Original solution / Rock added: 523565.60 (Water/Rock Ratio), log = 5.7190 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0322 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9886E+00 0.9858 0.1006E+01 0.1020E+01 CO2,gas 0.8066E-06 1.0070 0.8384E-06 0.8326E-06 CH4,gas 0.8313E-02 1.0125 0.8687E-02 0.8581E-02 H2,gas 0.3090E-02 1.0006 0.3192E-02 0.3190E-02 H2S,gas 0.4238E-06 0.9960 0.4357E-06 0.4375E-06 S2,gas 0.6778E-27 1.0000 0.6996E-27 0.6996E-27 CO,gas 0.6909E-12 1.0000 0.7132E-12 0.7132E-12 SO3,gas 0.1134E-44 1.0000 0.1171E-44 0.1171E-44 SO2,gas 0.1408E-24 1.0000 0.1453E-24 0.1453E-24 HF,gas 0.9981E-15 1.0000 0.1030E-14 0.1030E-14 HCl,gas 0.3317E-17 1.0000 0.3424E-17 0.3424E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 17 albite -0.38 -0.38 0.00 0.000 -0.94784E-12 23 andradite 39.01 39.01 0.00 0.000 0.12132E-10 24 grossular 32.73 32.73 0.00 0.000 0.00000E+00 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -14.44 -7.78 -2.592 0.13276E+05 -6.077 3 CH4,gas 4.54 0.78 -3.76 -0.940 0.64202E+04 -2.061 4 H2,gas 8.00 3.80 -4.19 -2.397 0.71628E+04 -2.496 5 H2S,gas -6.23 -14.29 -8.06 -4.030 0.13762E+05 -6.361 6 S2,gas -7.34 -36.19 -28.85 -4.439 0.49268E+05 -27.155 7 CO,gas 3.21 -10.63 -13.85 -4.260 0.23641E+05 -12.147 8 SO3,gas 17.12 -29.51 -46.63 -11.658 0.79620E+05 -44.932 9 SO2,gas 0.83 -25.70 -26.54 -7.076 0.45310E+05 -24.838 10 HF,gas 0.47 -16.21 -16.69 -8.343 0.28491E+05 -14.987 11 HCl,gas 5.19 -13.98 -19.16 -9.582 0.32723E+05 -17.465 12 acmite 7.71 6.76 -0.95 -0.098 0.16163E+04 16 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 20 spessartine 24.46 19.70 -4.75 -0.238 0.81148E+04 21 analcite 3.32 2.76 -0.56 -0.062 0.95946E+03 27 annite 20.12 17.37 -2.75 -0.153 0.47039E+04 28 phlogopite 27.06 25.31 -1.75 -0.097 0.29897E+04 30 anorthite 12.71 8.10 -4.61 -0.354 0.78658E+04 33 apatite-OH -18.15 -18.75 -0.59 -0.046 0.10151E+04 34 apatite-F -34.30 -34.96 -0.66 -0.055 0.11262E+04 38 aragonite 0.97 -1.47 -2.44 -0.812 0.41602E+04 39 brucite 12.57 9.27 -3.30 -0.660 0.56378E+04 40 calcite 0.81 -1.47 -2.28 -0.761 0.38960E+04 41 carnegieite-low 9.02 5.90 -3.12 -0.446 0.53265E+04 42 carnegieite-high 10.09 5.90 -4.19 -0.599 0.71535E+04 43 carpholite-Mg 8.58 4.40 -4.18 -0.278 0.71328E+04 44 carpholite-Fe 6.71 1.76 -4.96 -0.330 0.84628E+04 45 celadonite 5.34 3.64 -1.71 -0.100 0.29117E+04 46 celadonite-Fe 3.88 0.99 -2.89 -0.170 0.49321E+04 47 chrysotile 23.89 21.51 -2.38 -0.198 0.40634E+04 49 clinochlore 39.07 38.33 -0.74 -0.023 0.12664E+04 50 daphnite 28.97 25.09 -3.88 -0.121 0.66238E+04 52 chlorite-Al-free 47.17 43.03 -4.15 -0.173 0.70820E+04 54 chloritoid-Fe 9.17 4.90 -4.27 -0.285 0.72969E+04 55 chloritoid-Mn 11.40 7.52 -3.88 -0.259 0.66291E+04 57 coesite -2.38 -3.14 -0.77 -0.256 0.13109E+04 64 cristobalite -2.56 -3.14 -0.58 -0.194 0.99626E+03 66 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71235E+04 68 diaspore 2.87 0.71 -2.16 -0.360 0.36897E+04 69 diamond -3.10 -6.83 -3.72 -1.064 0.63580E+04 70 diopside 16.18 15.94 -0.24 -0.024 0.40392E+03 71 hedenbergite 14.21 13.30 -0.91 -0.091 0.15570E+04 76 clinoenstatite 17.17 12.25 -4.92 -0.492 0.84015E+04 78 epidote 24.67 22.64 -2.03 -0.098 0.34635E+04 79 clinozoisite 22.81 18.64 -4.17 -0.189 0.71163E+04 80 epidote-Fe 29.84 26.64 -3.20 -0.166 0.54574E+04 81 fayalite 14.05 10.09 -3.95 -0.565 0.67493E+04 82 ferrosilite 11.15 6.95 -4.20 -0.420 0.71720E+04 86 gibbsite 4.08 0.71 -3.37 -0.481 0.57482E+04 87 glaucophane 22.97 20.74 -2.23 -0.060 0.38076E+04 88 glaucophane-Fe 17.28 12.80 -4.48 -0.121 0.76428E+04 89 graphite -3.55 -6.83 -3.28 -0.937 0.56002E+04 90 greenalite 16.14 13.57 -2.57 -0.214 0.43917E+04 93 hematite 12.57 9.43 -3.13 -0.380 0.53517E+04 94 heulandite -5.83 -7.62 -1.79 -0.081 0.30533E+04 98 jadeite 4.22 2.76 -1.46 -0.146 0.24849E+04 100 kalsilite 7.58 3.80 -3.78 -0.540 0.64592E+04 101 kaolinite -1.33 -4.86 -3.53 -0.321 0.60261E+04 104 laumontite 2.88 1.82 -1.07 -0.071 0.18226E+04 105 lawsonite 9.62 8.10 -1.51 -0.101 0.25824E+04 106 leucite 4.12 0.66 -3.46 -0.346 0.59107E+04 108 lizardite 23.24 21.51 -1.73 -0.144 0.29561E+04 110 magnetite 20.09 16.05 -4.04 -0.330 0.68933E+04 111 minnesotaite 10.39 7.28 -3.11 -0.183 0.53073E+04 115 manganosite 14.06 9.24 -4.82 -1.205 0.82321E+04 119 microcline -2.49 -2.49 0.00 0.000 0.16397E+00 123 muscovite 2.58 -1.06 -3.64 -0.214 0.62211E+04 124 paragonite 4.24 1.04 -3.20 -0.188 0.54600E+04 125 nepheline 8.34 5.90 -2.44 -0.348 0.41589E+04 137 phlogopite-Na 29.65 27.42 -2.23 -0.124 0.38084E+04 139 prehnite 19.37 17.93 -1.45 -0.085 0.24696E+04 140 prehnite-Fe 22.50 21.93 -0.57 -0.034 0.97187E+03 141 pumpellyite-Fe 46.27 43.18 -3.09 -0.069 0.52714E+04 142 pumpellyite-Mg 48.99 45.83 -3.16 -0.070 0.54030E+04 145 pyrite -21.25 -25.77 -4.52 -1.063 0.77169E+04 146 pyrrhotite -4.26 -7.67 -3.41 -1.137 0.58247E+04 147 pyrrhotiteFe0.875 -6.02 -8.97 -2.95 -1.086 0.50435E+04 148 pyroxmangite 7.40 6.09 -1.31 -0.261 0.22293E+04 149 pyrophyllite -6.18 -11.15 -4.97 -0.311 0.84927E+04 150 quartz -2.99 -3.14 -0.15 -0.051 0.26359E+03 154 rhodochrosite -0.98 -5.20 -4.22 -1.407 0.72097E+04 155 rhodonite 7.45 6.09 -1.35 -0.271 0.23095E+04 156 sanidine -1.28 -2.49 -1.21 -0.093 0.20679E+04 166 stilbite -7.52 -7.62 -0.09 -0.004 0.15942E+03 167 stilpnomelane-Fe 13.02 12.48 -0.53 -0.016 0.91186E+03 168 stilpnomelane-Mg 27.44 25.72 -1.72 -0.051 0.29310E+04 174 talc 16.49 15.22 -1.27 -0.074 0.21618E+04 177 tephroite 18.09 15.33 -2.76 -0.394 0.47055E+04 181 tridymite -2.63 -3.14 -0.52 -0.172 0.88357E+03 182 tremolite 47.87 47.11 -0.75 -0.020 0.12886E+04 183 ferroactinolite 38.45 33.87 -4.58 -0.124 0.78197E+04 184 troilite-low -4.41 -7.67 -3.26 -1.087 0.55675E+04 190 wairakite 3.95 1.82 -2.13 -0.126 0.36445E+04 191 walstromite 11.51 9.82 -1.69 -0.337 0.28811E+04 192 wollastonite 10.46 9.82 -0.64 -0.128 0.10915E+04 193 pseudo-wollastonite 11.00 9.82 -1.18 -0.236 0.20114E+04 194 zoisite 22.85 18.64 -4.21 -0.191 0.71903E+04 195 akaganeite 7.75 4.72 -3.04 -0.657 0.51884E+04 202 chalcedony -2.80 -3.14 -0.34 -0.114 0.58289E+03 204 montmorillonite-Ca -2.29 -6.19 -3.90 -0.241 0.66537E+04 205 montmorillonite-K -2.24 -6.27 -4.03 -0.247 0.68872E+04 206 montmorillonite-Mg -2.48 -6.80 -4.32 -0.267 0.73728E+04 207 montmorillonite-Na -2.04 -5.58 -3.54 -0.217 0.60420E+04 208 nontronite-Ca 3.21 0.27 -2.95 -0.191 0.50300E+04 209 nontronite-H 2.53 -1.87 -4.40 -0.295 0.75186E+04 210 nontronite-K 3.34 0.19 -3.15 -0.202 0.53867E+04 211 nontronite-Mg 3.07 -0.34 -3.42 -0.222 0.58332E+04 212 nontronite-Na 3.52 0.88 -2.64 -0.169 0.45075E+04 228 tobermorite 9.82 7.66 -2.17 -0.591 0.36992E+04 234 alabandite -0.98 -5.05 -4.08 -1.358 0.69583E+04 237 boehmite 4.41 0.71 -3.69 -0.616 0.63066E+04 239 ferrous-oxide 9.81 6.62 -3.19 -0.798 0.54523E+04 245 silica-amorphous -2.09 -3.14 -1.05 -0.351 0.17971E+04 247 an20ab80 2.02 1.31 -0.70 -0.054 0.12023E+04 248 an25ab75 2.65 1.74 -0.91 -0.070 0.15499E+04 249 an30ab70 3.28 2.16 -1.12 -0.086 0.19070E+04 250 tr.625ac.25prg.125 45.16 44.74 -0.42 -0.011 0.72378E+03 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 0.0000400 MOLES Current total amount of reactant added: 0.0019100 MOLES New total amount of reactant added: 0.0019500 MOLES Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.5508E-08 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 6 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 0.0019500 Water: Moles liquid = 0.4985E+02 kg liquid = 0.8981E+00 Moles total = 0.4985E+02 kg total = 0.8980E+00 Activity = 1.0000 Stoichiometric ionic strength = .1145467E-01 Osmotic coef. = 0.9638 True ionic strength = .2013149E-01 Chg. balance for total moles = -.5508E-08 Max. difference allowed = 0.1494E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.91403E-10 -10.0390 0.76775E-10 -10.1148 0.83996E+00 -0.0757 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.16558E-03 -3.7810 0.13824E-03 -3.8594 0.83489E+00 -0.0784 4 SO4-- 0.10876E-08 -8.9635 0.56398E-09 -9.2487 0.51855E+00 -0.2852 5 HCO3- 0.58404E-04 -4.2336 0.48833E-04 -4.3113 0.83611E+00 -0.0777 6 HS- 0.81143E-04 -4.0907 0.67756E-04 -4.1691 0.83501E+00 -0.0783 7 Al+++ 0.10131E-28 -28.9943 0.23328E-29 -29.6321 0.23026E+00 -0.6378 8 H4SiO4 0.71859E-03 -3.1435 0.71859E-03 -3.1435 0.10000E+01 0.0000 9 Ca++ 0.10530E-06 -6.9776 0.54202E-07 -7.2660 0.51472E+00 -0.2884 10 Mg++ 0.21233E-10 -10.6730 0.10879E-10 -10.9634 0.51236E+00 -0.2904 11 Fe++ 0.47732E-13 -13.3212 0.24483E-13 -13.6111 0.51292E+00 -0.2899 12 K+ 0.15653E-03 -3.8054 0.13091E-03 -3.8830 0.83631E+00 -0.0776 13 Na+ 0.19867E-01 -1.7019 0.16584E-01 -1.7803 0.83474E+00 -0.0785 14 Mn++ 0.19810E-10 -10.7031 0.10169E-10 -10.9927 0.51335E+00 -0.2896 15 F- 0.97670E-06 -6.0102 0.81375E-06 -6.0895 0.83316E+00 -0.0793 16 HPO4-- 0.45346E-07 -7.3435 0.23517E-07 -7.6286 0.51862E+00 -0.2852 18 HSiO3- 0.10468E-01 -1.9801 0.87395E-02 -2.0585 0.83489E+00 -0.0784 19 Ca(HSiO3)+ 0.12897E-07 -7.8895 0.10788E-07 -7.9671 0.83649E+00 -0.0775 20 Mg(HSiO3)+ 0.32214E-11 -11.4920 0.26947E-11 -11.5695 0.83649E+00 -0.0775 21 NaHSiO3,aq 0.23441E-02 -2.6300 0.23441E-02 -2.6300 0.10000E+01 0.0000 22 AlO+ 0.64366E-16 -16.1913 0.53842E-16 -16.2689 0.83649E+00 -0.0775 24 HAlO2,aq 0.13966E-09 -9.8549 0.13966E-09 -9.8549 0.10000E+01 0.0000 25 AlO2- 0.48319E-05 -5.3159 0.40268E-05 -5.3950 0.83337E+00 -0.0792 26 CH4,aq 0.57187E-05 -5.2427 0.56987E-05 -5.2442 0.99651E+00 -0.0015 27 C2H6,aq 0.23247E-14 -14.6336 0.23165E-14 -14.6352 0.99651E+00 -0.0015 31 CO,aq 0.48230E-15 -15.3167 0.48230E-15 -15.3167 0.10000E+01 0.0000 32 CO2,aq 0.80390E-08 -8.0948 0.80109E-08 -8.0963 0.99651E+00 -0.0015 33 CO3-2 0.10737E-03 -3.9691 0.55556E-04 -4.2553 0.51744E+00 -0.2861 34 CaCO3,aq 0.37758E-07 -7.4230 0.37758E-07 -7.4230 0.10000E+01 0.0000 35 Ca(HCO3)+ 0.80769E-10 -10.0928 0.67563E-10 -10.1703 0.83649E+00 -0.0775 36 CaCl+ 0.14496E-10 -10.8387 0.12126E-10 -10.9163 0.83649E+00 -0.0775 37 CaCl2,aq 0.39826E-15 -15.3998 0.39826E-15 -15.3998 0.10000E+01 0.0000 38 CaF+ 0.76984E-12 -12.1136 0.64396E-12 -12.1911 0.83649E+00 -0.0775 39 CaOH+ 0.60151E-07 -7.2208 0.50316E-07 -7.2983 0.83649E+00 -0.0775 40 CaSO4,aq 0.97071E-14 -14.0129 0.97071E-14 -14.0129 0.10000E+01 0.0000 41 HCl,aq 0.19449E-14 -14.7111 0.19449E-14 -14.7111 0.10000E+01 0.0000 45 HF,aq 0.42769E-12 -12.3689 0.42769E-12 -12.3689 0.10000E+01 0.0000 46 HF2- 0.14074E-18 -18.8516 0.11750E-18 -18.9300 0.83489E+00 -0.0784 48 FeCl+ 0.64043E-17 -17.1935 0.53571E-17 -17.2711 0.83649E+00 -0.0775 51 FeF+ 0.12171E-17 -17.9147 0.10181E-17 -17.9922 0.83649E+00 -0.0775 53 FeO,aq 0.16143E-09 -9.7920 0.16143E-09 -9.7920 0.10000E+01 0.0000 54 FeOH+ 0.12409E-10 -10.9063 0.10380E-10 -10.9838 0.83649E+00 -0.0775 55 HFeO2- 0.26351E-07 -7.5792 0.22000E-07 -7.6576 0.83489E+00 -0.0784 56 FeO+ 0.19119E-16 -16.7185 0.15993E-16 -16.7961 0.83649E+00 -0.0775 58 FeO2- 0.66499E-09 -9.1772 0.55519E-09 -9.2556 0.83489E+00 -0.0784 59 HFeO2,aq 0.54212E-11 -11.2659 0.54212E-11 -11.2659 0.10000E+01 0.0000 60 H2,aq 0.24050E-05 -5.6189 0.23966E-05 -5.6204 0.99651E+00 -0.0015 61 KCl,aq 0.32799E-09 -9.4841 0.32799E-09 -9.4841 0.10000E+01 0.0000 63 KOH,aq 0.72816E-06 -6.1378 0.72816E-06 -6.1378 0.10000E+01 0.0000 64 KSO4- 0.13722E-11 -11.8626 0.11456E-11 -11.9410 0.83489E+00 -0.0784 65 MgCO3,aq 0.18996E-11 -11.7213 0.18996E-11 -11.7213 0.10000E+01 0.0000 66 Mg(HCO3)+ 0.16565E-13 -13.7808 0.13856E-13 -13.8583 0.83649E+00 -0.0775 67 MgCl+ 0.26371E-14 -14.5789 0.22059E-14 -14.6564 0.83649E+00 -0.0775 68 MgF+ 0.57237E-15 -15.2423 0.47878E-15 -15.3199 0.83649E+00 -0.0775 69 MgOH+ 0.66805E-10 -10.1752 0.55882E-10 -10.2527 0.83649E+00 -0.0775 71 MnF+ 0.16663E-15 -15.7782 0.13939E-15 -15.8558 0.83649E+00 -0.0775 72 MnO,aq 0.17867E-08 -8.7479 0.17867E-08 -8.7479 0.10000E+01 0.0000 73 MnOH+ 0.47883E-09 -9.3198 0.40054E-09 -9.3974 0.83649E+00 -0.0775 74 MnO2-2 0.19442E-10 -10.7113 0.10060E-10 -10.9974 0.51744E+00 -0.2861 75 HMnO2- 0.20267E-09 -9.6932 0.16921E-09 -9.7716 0.83489E+00 -0.0784 78 MnCl+ 0.10349E-13 -13.9851 0.86571E-14 -14.0626 0.83649E+00 -0.0775 79 MnSO4,aq 0.16558E-17 -17.7810 0.16558E-17 -17.7810 0.10000E+01 0.0000 80 NaCl,aq 0.75976E-06 -6.1193 0.75976E-06 -6.1193 0.10000E+01 0.0000 81 NaF,aq 0.31594E-08 -8.5004 0.31594E-08 -8.5004 0.10000E+01 0.0000 82 NaOH,aq 0.92807E-04 -4.0324 0.92807E-04 -4.0324 0.10000E+01 0.0000 84 OH- 0.90303E-02 -2.0443 0.75256E-02 -2.1235 0.83337E+00 -0.0792 89 HPO3-2 0.33944E-15 -15.4692 0.17564E-15 -15.7554 0.51744E+00 -0.2861 91 H2PO3- 0.32389E-19 -19.4896 0.27041E-19 -19.5680 0.83489E+00 -0.0784 92 H3PO4,aq 0.96949E-18 -18.0135 0.96949E-18 -18.0135 0.10000E+01 0.0000 93 H2PO4- 0.39856E-10 -10.3995 0.33307E-10 -10.4775 0.83568E+00 -0.0780 94 PO4-3 0.10332E-08 -8.9858 0.24992E-09 -9.6022 0.24189E+00 -0.6164 98 HP2O7-3 0.98154E-18 -18.0081 0.22623E-18 -18.6454 0.23049E+00 -0.6374 99 P2O7-4 0.91831E-17 -17.0370 0.70396E-18 -18.1525 0.76657E-01 -1.1154 100 H2S,aq 0.16133E-07 -7.7923 0.16077E-07 -7.7938 0.99651E+00 -0.0015 101 S2-2 0.82028E-13 -13.0860 0.42445E-13 -13.3722 0.51744E+00 -0.2861 107 SO3-2 0.33459E-15 -15.4755 0.17565E-15 -15.7554 0.52496E+00 -0.2799 108 HSO3- 0.10113E-17 -17.9951 0.84434E-18 -18.0735 0.83489E+00 -0.0784 109 HSO4- 0.49836E-16 -16.3025 0.41728E-16 -16.3796 0.83731E+00 -0.0771 111 S2O3-2 0.20584E-18 -18.6865 0.10651E-18 -18.9726 0.51744E+00 -0.2861 Charge balance for all species = -.6133E-08 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.9140268E-10 -.2206330E-01 -.2219968E+02 0.0000 2 H2O 0.1000000E+01 0.5550458E+02 0.9981872E+06 0.0000 3 Cl- 0.1655812E-03 0.1663414E-03 0.5887011E+01 6.2554 4 SO4-- 0.1087622E-08 -.6318790E-05 -.6059342E+00 10.9808 5 HCO3- 0.5840416E-04 0.1715366E-03 0.1044842E+02 5.8035 6 HS- 0.8114348E-04 0.8747950E-04 0.2888074E+01 5.9457 7 Al+++ 0.1013141E-28 0.4832042E-05 0.1301483E+00 0.7122 8 H4SiO4 0.7185870E-03 0.1353063E-01 0.1298233E+04 -3.1435 9 Ca++ 0.1053039E-06 0.2162055E-06 0.8649968E-02 12.9636 10 Mg++ 0.2123318E-10 0.9317936E-10 0.2261424E-05 9.2662 11 Fe++ 0.4773166E-13 0.2719562E-07 0.1516144E-02 6.6184 12 K+ 0.1565271E-03 0.1572556E-03 0.6138281E+01 6.2317 13 Na+ 0.1986715E-01 0.2230484E-01 0.5118893E+03 8.3345 14 Mn++ 0.1981007E-10 0.2507481E-08 0.1375157E-03 9.2369 15 F- 0.9766986E-06 0.9798592E-06 0.1858289E-01 4.0253 16 HPO4-- 0.4534575E-07 0.4641882E-07 0.4447459E-02 12.6010 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.1981657E-01 -.1981479E-01 -.1785040E-05 0.0000000E+00 2 H2O 0.4984801E+02 0.4984801E+02 -.1742666E-05 0.0000000E+00 3 Cl- 0.1493892E-03 0.1493892E-03 0.0000000E+00 0.0000000E+00 4 SO4-- -.5673810E-05 -.5674831E-05 0.1021026E-08 0.0000000E+00 5 HCO3- 0.1540550E-03 0.1540550E-03 0.0000000E+00 0.0000000E+00 6 HS- 0.7856328E-04 0.7856430E-04 -.1021026E-08 0.0000000E+00 7 Al+++ 0.4775352E-05 0.4339600E-05 0.4357519E-06 0.0000000E+00 8 H4SiO4 0.1215302E-01 0.1215170E-01 0.1317848E-05 0.0000000E+00 9 Ca++ 0.2080835E-06 0.1941716E-06 0.1391186E-07 0.0000000E+00 10 Mg++ 0.8368328E-10 0.8368328E-10 0.0000000E+00 0.0000000E+00 11 Fe++ 0.3259227E-07 0.2442406E-07 0.8168205E-08 0.0000000E+00 12 K+ 0.1412294E-03 0.1412294E-03 0.0000000E+00 0.0000000E+00 13 Na+ 0.2003215E-01 0.2003172E-01 0.4346455E-06 0.0000000E+00 14 Mn++ 0.2251939E-08 0.2251939E-08 0.0000000E+00 0.0000000E+00 15 F- 0.8800000E-06 0.8800000E-06 0.0000000E+00 0.0000000E+00 16 HPO4-- 0.4168819E-07 0.4168819E-07 0.0000000E+00 0.0000000E+00 Chg. balance for solid moles: -.2118E-21 Mass of aqueous solution: 0.899658E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 0.0019500 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 0.4346E-06 -6.362 0.1140E-03 -3.943 98.00 0.4375E-04 andradite 0.4084E-08 -8.389 0.2075E-05 -5.683 1.785 0.5392E-06 grossular 0.5532E-09 -9.257 0.2492E-06 -6.603 0.2143 0.6933E-07 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8807E+00 0.8807E+00 1.0000 -0.055 grossular 0.1193E+00 0.1193E+00 1.0000 -0.923 Solid products produced: Mass = 0.000116 g Volume = 0.000044 cm3 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.0019500 moles log = -2.7100 Original solution: 1000.0103000 g Original solution / Rock added: 512825.79 (Water/Rock Ratio), log = 5.7100 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0319 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9889E+00 0.9858 0.1006E+01 0.1020E+01 CO2,gas 0.8248E-06 1.0070 0.8571E-06 0.8511E-06 CH4,gas 0.8029E-02 1.0125 0.8388E-02 0.8285E-02 H2,gas 0.3048E-02 1.0006 0.3146E-02 0.3145E-02 H2S,gas 0.4300E-06 0.9960 0.4419E-06 0.4437E-06 S2,gas 0.7177E-27 1.0000 0.7405E-27 0.7405E-27 CO,gas 0.6965E-12 1.0000 0.7187E-12 0.7187E-12 SO3,gas 0.1218E-44 1.0000 0.1257E-44 0.1257E-44 SO2,gas 0.1491E-24 1.0000 0.1539E-24 0.1539E-24 HF,gas 0.1018E-14 1.0000 0.1050E-14 0.1050E-14 HCl,gas 0.3326E-17 1.0000 0.3432E-17 0.3432E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 17 albite -0.38 -0.38 0.00 0.000 -0.94784E-12 23 andradite 39.01 39.01 0.00 0.000 -0.12132E-10 24 grossular 32.73 32.73 0.00 0.000 -0.12132E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -14.43 -7.77 -2.589 0.13260E+05 -6.067 3 CH4,gas 4.54 0.77 -3.78 -0.944 0.64462E+04 -2.076 4 H2,gas 8.00 3.80 -4.20 -2.401 0.71733E+04 -2.502 5 H2S,gas -6.23 -14.28 -8.05 -4.027 0.13751E+05 -6.355 6 S2,gas -7.34 -36.16 -28.83 -4.435 0.49225E+05 -27.130 7 CO,gas 3.21 -10.63 -13.84 -4.259 0.23636E+05 -12.143 8 SO3,gas 17.12 -29.48 -46.60 -11.650 0.79568E+05 -44.901 9 SO2,gas 0.83 -25.68 -26.51 -7.070 0.45268E+05 -24.813 10 HF,gas 0.47 -16.20 -16.68 -8.339 0.28477E+05 -14.979 11 HCl,gas 5.19 -13.97 -19.16 -9.582 0.32721E+05 -17.464 12 acmite 7.71 6.77 -0.94 -0.098 0.16104E+04 16 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 20 spessartine 24.46 19.70 -4.75 -0.238 0.81154E+04 21 analcite 3.32 2.76 -0.56 -0.062 0.95995E+03 27 annite 20.12 17.37 -2.75 -0.153 0.47036E+04 28 phlogopite 27.06 25.31 -1.75 -0.097 0.29927E+04 30 anorthite 12.71 8.10 -4.61 -0.355 0.78703E+04 33 apatite-OH -18.15 -18.76 -0.60 -0.046 0.10298E+04 34 apatite-F -34.30 -34.96 -0.66 -0.055 0.11268E+04 38 aragonite 0.97 -1.46 -2.43 -0.810 0.41475E+04 39 brucite 12.57 9.27 -3.30 -0.660 0.56388E+04 40 calcite 0.81 -1.46 -2.27 -0.758 0.38832E+04 41 carnegieite-low 9.02 5.90 -3.12 -0.446 0.53275E+04 42 carnegieite-high 10.09 5.90 -4.19 -0.599 0.71545E+04 43 carpholite-Mg 8.58 4.40 -4.18 -0.279 0.71347E+04 44 carpholite-Fe 6.71 1.76 -4.96 -0.330 0.84636E+04 45 celadonite 5.34 3.64 -1.71 -0.100 0.29122E+04 46 celadonite-Fe 3.88 0.99 -2.89 -0.170 0.49315E+04 47 chrysotile 23.89 21.51 -2.38 -0.198 0.40654E+04 49 clinochlore 39.07 38.32 -0.74 -0.023 0.12718E+04 50 daphnite 28.97 25.09 -3.88 -0.121 0.66237E+04 52 chlorite-Al-free 47.17 43.02 -4.15 -0.173 0.70861E+04 54 chloritoid-Fe 9.17 4.90 -4.27 -0.285 0.72982E+04 55 chloritoid-Mn 11.40 7.52 -3.88 -0.259 0.66306E+04 57 coesite -2.38 -3.14 -0.77 -0.256 0.13104E+04 64 cristobalite -2.56 -3.14 -0.58 -0.194 0.99577E+03 66 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71236E+04 68 diaspore 2.87 0.71 -2.16 -0.360 0.36906E+04 69 diamond -3.10 -6.83 -3.73 -1.065 0.63628E+04 70 diopside 16.18 15.94 -0.24 -0.024 0.40751E+03 71 hedenbergite 14.21 13.29 -0.91 -0.091 0.15595E+04 76 clinoenstatite 17.17 12.25 -4.92 -0.492 0.84025E+04 78 epidote 24.67 22.64 -2.03 -0.098 0.34657E+04 79 clinozoisite 22.81 18.63 -4.17 -0.190 0.71248E+04 80 epidote-Fe 29.84 26.65 -3.19 -0.166 0.54532E+04 81 fayalite 14.05 10.09 -3.95 -0.565 0.67486E+04 82 ferrosilite 11.15 6.95 -4.20 -0.420 0.71708E+04 86 gibbsite 4.08 0.71 -3.37 -0.481 0.57492E+04 87 glaucophane 22.97 20.74 -2.23 -0.060 0.38096E+04 88 glaucophane-Fe 17.28 12.80 -4.48 -0.121 0.76415E+04 89 graphite -3.55 -6.83 -3.28 -0.938 0.56051E+04 90 greenalite 16.14 13.57 -2.57 -0.214 0.43904E+04 93 hematite 12.57 9.44 -3.13 -0.379 0.53409E+04 94 heulandite -5.83 -7.62 -1.79 -0.081 0.30553E+04 98 jadeite 4.22 2.76 -1.46 -0.146 0.24854E+04 100 kalsilite 7.58 3.80 -3.78 -0.540 0.64602E+04 101 kaolinite -1.33 -4.86 -3.53 -0.321 0.60271E+04 104 laumontite 2.88 1.81 -1.07 -0.071 0.18261E+04 105 lawsonite 9.62 8.10 -1.52 -0.101 0.25869E+04 106 leucite 4.12 0.66 -3.46 -0.346 0.59112E+04 108 lizardite 23.24 21.51 -1.73 -0.144 0.29581E+04 110 magnetite 20.09 16.06 -4.03 -0.329 0.68824E+04 111 minnesotaite 10.39 7.28 -3.11 -0.183 0.53050E+04 115 manganosite 14.06 9.24 -4.82 -1.205 0.82322E+04 119 microcline -2.49 -2.49 0.00 0.000 0.16748E+00 123 muscovite 2.58 -1.06 -3.64 -0.214 0.62230E+04 124 paragonite 4.24 1.04 -3.20 -0.188 0.54619E+04 125 nepheline 8.34 5.90 -2.44 -0.348 0.41599E+04 137 phlogopite-Na 29.65 27.41 -2.23 -0.124 0.38114E+04 139 prehnite 19.37 17.92 -1.45 -0.085 0.24772E+04 140 prehnite-Fe 22.50 21.93 -0.57 -0.034 0.97312E+03 141 pumpellyite-Fe 46.27 43.17 -3.10 -0.069 0.52875E+04 142 pumpellyite-Mg 48.99 45.82 -3.17 -0.071 0.54202E+04 145 pyrite -21.25 -25.75 -4.50 -1.059 0.76852E+04 146 pyrrhotite -4.26 -7.67 -3.41 -1.135 0.58141E+04 147 pyrrhotiteFe0.875 -6.02 -8.96 -2.95 -1.084 0.50316E+04 148 pyroxmangite 7.40 6.09 -1.31 -0.261 0.22288E+04 149 pyrophyllite -6.18 -11.15 -4.97 -0.311 0.84927E+04 150 quartz -2.99 -3.14 -0.15 -0.051 0.26310E+03 154 rhodochrosite -0.98 -5.19 -4.21 -1.404 0.71934E+04 155 rhodonite 7.45 6.09 -1.35 -0.270 0.23091E+04 156 sanidine -1.28 -2.49 -1.21 -0.093 0.20679E+04 166 stilbite -7.52 -7.62 -0.09 -0.005 0.16145E+03 167 stilpnomelane-Fe 13.02 12.48 -0.53 -0.016 0.90956E+03 168 stilpnomelane-Mg 27.44 25.72 -1.72 -0.051 0.29343E+04 174 talc 16.49 15.22 -1.27 -0.075 0.21628E+04 177 tephroite 18.09 15.33 -2.76 -0.394 0.47051E+04 181 tridymite -2.63 -3.14 -0.52 -0.172 0.88307E+03 182 tremolite 47.87 47.11 -0.76 -0.021 0.12968E+04 183 ferroactinolite 38.45 33.87 -4.58 -0.124 0.78224E+04 184 troilite-low -4.41 -7.67 -3.25 -1.085 0.55569E+04 190 wairakite 3.95 1.81 -2.14 -0.126 0.36480E+04 191 walstromite 11.51 9.82 -1.69 -0.338 0.28842E+04 192 wollastonite 10.46 9.82 -0.64 -0.128 0.10946E+04 193 pseudo-wollastonite 11.00 9.82 -1.18 -0.236 0.20145E+04 194 zoisite 22.85 18.63 -4.22 -0.192 0.71989E+04 195 akaganeite 7.75 4.72 -3.04 -0.656 0.51830E+04 202 chalcedony -2.80 -3.14 -0.34 -0.114 0.58239E+03 204 montmorillonite-Ca -2.29 -6.19 -3.90 -0.241 0.66542E+04 205 montmorillonite-K -2.24 -6.27 -4.03 -0.247 0.68873E+04 206 montmorillonite-Mg -2.48 -6.80 -4.32 -0.267 0.73729E+04 207 montmorillonite-Na -2.04 -5.58 -3.54 -0.217 0.60422E+04 208 nontronite-Ca 3.21 0.28 -2.94 -0.191 0.50183E+04 209 nontronite-H 2.53 -1.86 -4.40 -0.295 0.75063E+04 210 nontronite-K 3.34 0.19 -3.15 -0.202 0.53746E+04 211 nontronite-Mg 3.07 -0.33 -3.41 -0.221 0.58210E+04 212 nontronite-Na 3.52 0.89 -2.63 -0.169 0.44954E+04 228 tobermorite 9.82 7.66 -2.17 -0.592 0.37016E+04 234 alabandite -0.98 -5.05 -4.07 -1.356 0.69479E+04 237 boehmite 4.41 0.71 -3.69 -0.616 0.63076E+04 239 ferrous-oxide 9.81 6.62 -3.19 -0.798 0.54522E+04 245 silica-amorphous -2.09 -3.14 -1.05 -0.351 0.17966E+04 247 an20ab80 2.02 1.31 -0.70 -0.054 0.12032E+04 248 an25ab75 2.65 1.74 -0.91 -0.070 0.15510E+04 249 an30ab70 3.28 2.16 -1.12 -0.086 0.19084E+04 250 tr.625ac.25prg.125 45.16 44.74 -0.43 -0.012 0.73102E+03 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 0.0000400 MOLES Current total amount of reactant added: 0.0019500 MOLES New total amount of reactant added: 0.0019900 MOLES Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.5508E-08 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 6 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 0.0019900 Water: Moles liquid = 0.4985E+02 kg liquid = 0.8981E+00 Moles total = 0.4985E+02 kg total = 0.8980E+00 Activity = 1.0000 Stoichiometric ionic strength = .1145722E-01 Osmotic coef. = 0.9637 True ionic strength = .2013383E-01 Chg. balance for total moles = -.5508E-08 Max. difference allowed = 0.1496E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.91469E-10 -10.0387 0.76830E-10 -10.1145 0.83995E+00 -0.0757 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.16584E-03 -3.7803 0.13846E-03 -3.8587 0.83488E+00 -0.0784 4 SO4-- 0.11670E-08 -8.9329 0.60514E-09 -9.2181 0.51853E+00 -0.2852 5 HCO3- 0.59637E-04 -4.2245 0.49863E-04 -4.3022 0.83611E+00 -0.0777 6 HS- 0.82225E-04 -4.0850 0.68659E-04 -4.1633 0.83500E+00 -0.0783 7 Al+++ 0.10141E-28 -28.9939 0.23348E-29 -29.6317 0.23024E+00 -0.6378 8 H4SiO4 0.71907E-03 -3.1432 0.71907E-03 -3.1432 0.10000E+01 0.0000 9 Ca++ 0.10495E-06 -6.9790 0.54018E-07 -7.2675 0.51471E+00 -0.2884 10 Mg++ 0.21236E-10 -10.6729 0.10880E-10 -10.9634 0.51234E+00 -0.2904 11 Fe++ 0.47803E-13 -13.3205 0.24519E-13 -13.6105 0.51291E+00 -0.2900 12 K+ 0.15653E-03 -3.8054 0.13091E-03 -3.8830 0.83631E+00 -0.0776 13 Na+ 0.19867E-01 -1.7019 0.16584E-01 -1.7803 0.83473E+00 -0.0785 14 Mn++ 0.19837E-10 -10.7025 0.10183E-10 -10.9921 0.51333E+00 -0.2896 15 F- 0.99446E-06 -6.0024 0.82853E-06 -6.0817 0.83315E+00 -0.0793 16 HPO4-- 0.45346E-07 -7.3435 0.23517E-07 -7.6286 0.51860E+00 -0.2852 18 HSiO3- 0.10468E-01 -1.9802 0.87391E-02 -2.0585 0.83488E+00 -0.0784 19 Ca(HSiO3)+ 0.12852E-07 -7.8910 0.10751E-07 -7.9686 0.83649E+00 -0.0775 20 Mg(HSiO3)+ 0.32216E-11 -11.4919 0.26948E-11 -11.5695 0.83649E+00 -0.0775 21 NaHSiO3,aq 0.23440E-02 -2.6300 0.23440E-02 -2.6300 0.10000E+01 0.0000 22 AlO+ 0.64330E-16 -16.1916 0.53811E-16 -16.2691 0.83649E+00 -0.0775 24 HAlO2,aq 0.13948E-09 -9.8555 0.13948E-09 -9.8555 0.10000E+01 0.0000 25 AlO2- 0.48222E-05 -5.3168 0.40187E-05 -5.3959 0.83337E+00 -0.0792 26 CH4,aq 0.55148E-05 -5.2585 0.54955E-05 -5.2600 0.99651E+00 -0.0015 27 C2H6,aq 0.21933E-14 -14.6589 0.21857E-14 -14.6604 0.99651E+00 -0.0015 31 CO,aq 0.48575E-15 -15.3136 0.48575E-15 -15.3136 0.10000E+01 0.0000 32 CO2,aq 0.82146E-08 -8.0854 0.81859E-08 -8.0869 0.99651E+00 -0.0015 33 CO3-2 0.10956E-03 -3.9604 0.56688E-04 -4.2465 0.51742E+00 -0.2862 34 CaCO3,aq 0.38396E-07 -7.4157 0.38396E-07 -7.4157 0.10000E+01 0.0000 35 Ca(HCO3)+ 0.82194E-10 -10.0852 0.68754E-10 -10.1627 0.83649E+00 -0.0775 36 CaCl+ 0.14470E-10 -10.8395 0.12104E-10 -10.9171 0.83649E+00 -0.0775 37 CaCl2,aq 0.39815E-15 -15.4000 0.39815E-15 -15.4000 0.10000E+01 0.0000 38 CaF+ 0.78117E-12 -12.1073 0.65344E-12 -12.1848 0.83649E+00 -0.0775 39 CaOH+ 0.59904E-07 -7.2225 0.50109E-07 -7.3001 0.83649E+00 -0.0775 40 CaSO4,aq 0.10380E-13 -13.9838 0.10380E-13 -13.9838 0.10000E+01 0.0000 41 HCl,aq 0.19493E-14 -14.7101 0.19493E-14 -14.7101 0.10000E+01 0.0000 45 HF,aq 0.43577E-12 -12.3607 0.43577E-12 -12.3607 0.10000E+01 0.0000 46 HF2- 0.14601E-18 -18.8356 0.12190E-18 -18.9140 0.83488E+00 -0.0784 48 FeCl+ 0.64238E-17 -17.1922 0.53734E-17 -17.2697 0.83649E+00 -0.0775 51 FeF+ 0.12410E-17 -17.9062 0.10381E-17 -17.9838 0.83649E+00 -0.0775 53 FeO,aq 0.16144E-09 -9.7920 0.16144E-09 -9.7920 0.10000E+01 0.0000 54 FeOH+ 0.12419E-10 -10.9059 0.10388E-10 -10.9835 0.83649E+00 -0.0775 55 HFeO2- 0.26334E-07 -7.5795 0.21985E-07 -7.6579 0.83488E+00 -0.0784 56 FeO+ 0.19273E-16 -16.7151 0.16121E-16 -16.7926 0.83649E+00 -0.0775 58 FeO2- 0.66937E-09 -9.1743 0.55885E-09 -9.2527 0.83488E+00 -0.0784 59 HFeO2,aq 0.54608E-11 -11.2627 0.54608E-11 -11.2627 0.10000E+01 0.0000 60 H2,aq 0.23704E-05 -5.6252 0.23622E-05 -5.6267 0.99651E+00 -0.0015 61 KCl,aq 0.32850E-09 -9.4835 0.32850E-09 -9.4835 0.10000E+01 0.0000 63 KOH,aq 0.72763E-06 -6.1381 0.72763E-06 -6.1381 0.10000E+01 0.0000 64 KSO4- 0.14724E-11 -11.8320 0.12292E-11 -11.9104 0.83488E+00 -0.0784 65 MgCO3,aq 0.19385E-11 -11.7125 0.19385E-11 -11.7125 0.10000E+01 0.0000 66 Mg(HCO3)+ 0.16916E-13 -13.7717 0.14150E-13 -13.8492 0.83649E+00 -0.0775 67 MgCl+ 0.26414E-14 -14.5782 0.22095E-14 -14.6557 0.83649E+00 -0.0775 68 MgF+ 0.58282E-15 -15.2345 0.48753E-15 -15.3120 0.83649E+00 -0.0775 69 MgOH+ 0.66764E-10 -10.1755 0.55847E-10 -10.2530 0.83649E+00 -0.0775 71 MnF+ 0.16989E-15 -15.7698 0.14211E-15 -15.8474 0.83649E+00 -0.0775 72 MnO,aq 0.17866E-08 -8.7480 0.17866E-08 -8.7480 0.10000E+01 0.0000 73 MnOH+ 0.47914E-09 -9.3195 0.40079E-09 -9.3971 0.83649E+00 -0.0775 74 MnO2-2 0.19413E-10 -10.7119 0.10045E-10 -10.9981 0.51742E+00 -0.2862 75 HMnO2- 0.20251E-09 -9.6936 0.16907E-09 -9.7719 0.83488E+00 -0.0784 78 MnCl+ 0.10380E-13 -13.9838 0.86824E-14 -14.0614 0.83649E+00 -0.0775 79 MnSO4,aq 0.17790E-17 -17.7498 0.17790E-17 -17.7498 0.10000E+01 0.0000 80 NaCl,aq 0.76096E-06 -6.1186 0.76096E-06 -6.1186 0.10000E+01 0.0000 81 NaF,aq 0.32168E-08 -8.4926 0.32168E-08 -8.4926 0.10000E+01 0.0000 82 NaOH,aq 0.92740E-04 -4.0327 0.92740E-04 -4.0327 0.10000E+01 0.0000 84 OH- 0.90239E-02 -2.0446 0.75202E-02 -2.1238 0.83337E+00 -0.0792 89 HPO3-2 0.33457E-15 -15.4755 0.17311E-15 -15.7617 0.51742E+00 -0.2862 91 H2PO3- 0.31946E-19 -19.4956 0.26671E-19 -19.5740 0.83488E+00 -0.0784 92 H3PO4,aq 0.97087E-18 -18.0128 0.97087E-18 -18.0128 0.10000E+01 0.0000 93 H2PO4- 0.39884E-10 -10.3992 0.33330E-10 -10.4772 0.83568E+00 -0.0780 94 PO4-3 0.10325E-08 -8.9861 0.24974E-09 -9.6025 0.24187E+00 -0.6164 98 HP2O7-3 0.98228E-18 -18.0078 0.22639E-18 -18.6451 0.23047E+00 -0.6374 99 P2O7-4 0.91839E-17 -17.0370 0.70393E-18 -18.1525 0.76648E-01 -1.1155 100 H2S,aq 0.16360E-07 -7.7862 0.16303E-07 -7.7877 0.99651E+00 -0.0015 101 S2-2 0.85460E-13 -13.0682 0.44219E-13 -13.3544 0.51742E+00 -0.2862 107 SO3-2 0.35386E-15 -15.4512 0.18576E-15 -15.7311 0.52494E+00 -0.2799 108 HSO3- 0.10703E-17 -17.9705 0.89357E-18 -18.0489 0.83488E+00 -0.0784 109 HSO4- 0.53512E-16 -16.2715 0.44806E-16 -16.3487 0.83731E+00 -0.0771 111 S2O3-2 0.22397E-18 -18.6498 0.11589E-18 -18.9360 0.51742E+00 -0.2862 Charge balance for all species = -.6133E-08 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.9146893E-10 -.2205845E-01 -.2219480E+02 0.0000 2 H2O 0.1000000E+01 0.5550457E+02 0.9981869E+06 0.0000 3 Cl- 0.1658427E-03 0.1666040E-03 0.5896306E+01 6.2558 4 SO4-- 0.1167028E-08 -.6106113E-05 -.5855396E+00 11.0108 5 HCO3- 0.5963702E-04 0.1747566E-03 0.1064456E+02 5.8122 6 HS- 0.8222541E-04 0.8834905E-04 0.2916782E+01 5.9512 7 Al+++ 0.1014082E-28 0.4822371E-05 0.1298878E+00 0.7117 8 H4SiO4 0.7190690E-03 0.1353059E-01 0.1298229E+04 -3.1432 9 Ca++ 0.1049489E-06 0.2161985E-06 0.8649687E-02 12.9615 10 Mg++ 0.2123561E-10 0.9317929E-10 0.2261422E-05 9.2656 11 Fe++ 0.4780344E-13 0.2718232E-07 0.1515402E-02 6.6184 12 K+ 0.1565275E-03 0.1572555E-03 0.6138275E+01 6.2314 13 Na+ 0.1986730E-01 0.2230482E-01 0.5118886E+03 8.3342 14 Mn++ 0.1983750E-10 0.2507479E-08 0.1375155E-03 9.2368 15 F- 0.9944560E-06 0.9976741E-06 0.1892074E-01 4.0328 16 HPO4-- 0.4534638E-07 0.4641878E-07 0.4447455E-02 12.6003 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.1981227E-01 -.1981045E-01 -.1819812E-05 0.0000000E+00 2 H2O 0.4984804E+02 0.4984804E+02 -.1777433E-05 0.0000000E+00 3 Cl- 0.1496252E-03 0.1496252E-03 0.0000000E+00 0.0000000E+00 4 SO4-- -.5482810E-05 -.5483833E-05 0.1022517E-08 0.0000000E+00 5 HCO3- 0.1569470E-03 0.1569470E-03 0.0000000E+00 0.0000000E+00 6 HS- 0.7934428E-04 0.7934530E-04 -.1022517E-08 0.0000000E+00 7 Al+++ 0.4775352E-05 0.4330918E-05 0.4444343E-06 0.0000000E+00 8 H4SiO4 0.1215302E-01 0.1215168E-01 0.1343925E-05 0.0000000E+00 9 Ca++ 0.2080835E-06 0.1941655E-06 0.1391799E-07 0.0000000E+00 10 Mg++ 0.8368328E-10 0.8368328E-10 0.0000000E+00 0.0000000E+00 11 Fe++ 0.3259227E-07 0.2441214E-07 0.8180133E-08 0.0000000E+00 12 K+ 0.1412294E-03 0.1412294E-03 0.0000000E+00 0.0000000E+00 13 Na+ 0.2003215E-01 0.2003171E-01 0.4433358E-06 0.0000000E+00 14 Mn++ 0.2251939E-08 0.2251939E-08 0.0000000E+00 0.0000000E+00 15 F- 0.8960000E-06 0.8960000E-06 0.0000000E+00 0.0000000E+00 16 HPO4-- 0.4168819E-07 0.4168819E-07 0.0000000E+00 0.0000000E+00 Chg. balance for solid moles: 0.1588E-21 Mass of aqueous solution: 0.899659E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 0.0019900 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 0.4433E-06 -6.353 0.1163E-03 -3.935 98.04 0.4463E-04 andradite 0.4090E-08 -8.388 0.2078E-05 -5.682 1.753 0.5400E-06 grossular 0.5493E-09 -9.260 0.2474E-06 -6.607 0.2087 0.6884E-07 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8816E+00 0.8816E+00 1.0000 -0.055 grossular 0.1184E+00 0.1184E+00 1.0000 -0.927 Solid products produced: Mass = 0.000119 g Volume = 0.000045 cm3 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.0019900 moles log = -2.7011 Original solution: 1000.0103000 g Original solution / Rock added: 502517.74 (Water/Rock Ratio), log = 5.7012 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0315 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9892E+00 0.9858 0.1006E+01 0.1020E+01 CO2,gas 0.8431E-06 1.0070 0.8758E-06 0.8697E-06 CH4,gas 0.7745E-02 1.0125 0.8089E-02 0.7989E-02 H2,gas 0.3005E-02 1.0006 0.3101E-02 0.3100E-02 H2S,gas 0.4362E-06 0.9960 0.4482E-06 0.4500E-06 S2,gas 0.7599E-27 1.0000 0.7839E-27 0.7839E-27 CO,gas 0.7017E-12 1.0000 0.7239E-12 0.7239E-12 SO3,gas 0.1309E-44 1.0000 0.1351E-44 0.1351E-44 SO2,gas 0.1580E-24 1.0000 0.1630E-24 0.1630E-24 HF,gas 0.1037E-14 1.0000 0.1070E-14 0.1070E-14 HCl,gas 0.3334E-17 1.0000 0.3440E-17 0.3440E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 17 albite -0.38 -0.38 0.00 0.000 -0.94784E-12 23 andradite 39.01 39.01 0.00 0.000 0.12132E-10 24 grossular 32.73 32.73 0.00 0.000 -0.12132E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -14.42 -7.76 -2.586 0.13244E+05 -6.058 3 CH4,gas 4.54 0.75 -3.79 -0.948 0.64732E+04 -2.092 4 H2,gas 8.00 3.79 -4.21 -2.404 0.71841E+04 -2.508 5 H2S,gas -6.23 -14.28 -8.05 -4.024 0.13741E+05 -6.349 6 S2,gas -7.34 -36.14 -28.80 -4.431 0.49183E+05 -27.106 7 CO,gas 3.21 -10.62 -13.84 -4.258 0.23630E+05 -12.140 8 SO3,gas 17.12 -29.45 -46.57 -11.642 0.79514E+05 -44.869 9 SO2,gas 0.83 -25.65 -26.49 -7.063 0.45226E+05 -24.788 10 HF,gas 0.47 -16.20 -16.67 -8.335 0.28463E+05 -14.971 11 HCl,gas 5.19 -13.97 -19.16 -9.581 0.32719E+05 -17.463 12 acmite 7.71 6.77 -0.94 -0.098 0.16046E+04 16 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 20 spessartine 24.46 19.70 -4.75 -0.238 0.81160E+04 21 analcite 3.32 2.76 -0.56 -0.062 0.96045E+03 27 annite 20.12 17.37 -2.75 -0.153 0.47035E+04 28 phlogopite 27.06 25.31 -1.75 -0.097 0.29957E+04 30 anorthite 12.71 8.10 -4.61 -0.355 0.78748E+04 33 apatite-OH -18.15 -18.77 -0.61 -0.047 0.10446E+04 34 apatite-F -34.30 -34.96 -0.66 -0.055 0.11277E+04 38 aragonite 0.97 -1.46 -2.42 -0.807 0.41350E+04 39 brucite 12.57 9.27 -3.30 -0.661 0.56398E+04 40 calcite 0.81 -1.46 -2.27 -0.756 0.38708E+04 41 carnegieite-low 9.02 5.90 -3.12 -0.446 0.53285E+04 42 carnegieite-high 10.09 5.90 -4.19 -0.599 0.71555E+04 43 carpholite-Mg 8.58 4.40 -4.18 -0.279 0.71366E+04 44 carpholite-Fe 6.71 1.76 -4.96 -0.330 0.84645E+04 45 celadonite 5.34 3.64 -1.71 -0.100 0.29127E+04 46 celadonite-Fe 3.88 0.99 -2.89 -0.170 0.49310E+04 47 chrysotile 23.89 21.51 -2.38 -0.199 0.40675E+04 49 clinochlore 39.07 38.32 -0.75 -0.023 0.12773E+04 50 daphnite 28.97 25.09 -3.88 -0.121 0.66240E+04 52 chlorite-Al-free 47.17 43.02 -4.15 -0.173 0.70901E+04 54 chloritoid-Fe 9.17 4.90 -4.28 -0.285 0.72996E+04 55 chloritoid-Mn 11.40 7.52 -3.88 -0.259 0.66321E+04 57 coesite -2.38 -3.14 -0.77 -0.256 0.13099E+04 64 cristobalite -2.56 -3.14 -0.58 -0.194 0.99527E+03 66 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71236E+04 68 diaspore 2.87 0.71 -2.16 -0.360 0.36916E+04 69 diamond -3.10 -6.83 -3.73 -1.066 0.63683E+04 70 diopside 16.18 15.94 -0.24 -0.024 0.41111E+03 71 hedenbergite 14.21 13.29 -0.91 -0.091 0.15620E+04 76 clinoenstatite 17.17 12.24 -4.92 -0.492 0.84035E+04 78 epidote 24.67 22.64 -2.03 -0.098 0.34679E+04 79 clinozoisite 22.81 18.63 -4.18 -0.190 0.71334E+04 80 epidote-Fe 29.84 26.65 -3.19 -0.166 0.54491E+04 81 fayalite 14.05 10.09 -3.95 -0.565 0.67481E+04 82 ferrosilite 11.15 6.95 -4.20 -0.420 0.71697E+04 86 gibbsite 4.08 0.71 -3.37 -0.481 0.57502E+04 87 glaucophane 22.97 20.74 -2.23 -0.060 0.38116E+04 88 glaucophane-Fe 17.28 12.80 -4.47 -0.121 0.76404E+04 89 graphite -3.55 -6.83 -3.29 -0.939 0.56105E+04 90 greenalite 16.14 13.57 -2.57 -0.214 0.43893E+04 93 hematite 12.57 9.44 -3.12 -0.378 0.53301E+04 94 heulandite -5.83 -7.62 -1.79 -0.081 0.30573E+04 98 jadeite 4.22 2.76 -1.46 -0.146 0.24859E+04 100 kalsilite 7.58 3.80 -3.78 -0.541 0.64612E+04 101 kaolinite -1.33 -4.86 -3.53 -0.321 0.60280E+04 104 laumontite 2.88 1.81 -1.07 -0.071 0.18296E+04 105 lawsonite 9.62 8.10 -1.52 -0.101 0.25915E+04 106 leucite 4.12 0.66 -3.46 -0.346 0.59117E+04 108 lizardite 23.24 21.51 -1.73 -0.144 0.29601E+04 110 magnetite 20.09 16.06 -4.02 -0.329 0.68716E+04 111 minnesotaite 10.39 7.28 -3.11 -0.183 0.53029E+04 115 manganosite 14.06 9.24 -4.82 -1.205 0.82322E+04 119 microcline -2.49 -2.49 0.00 0.000 0.17100E+00 123 muscovite 2.58 -1.06 -3.65 -0.214 0.62249E+04 124 paragonite 4.24 1.04 -3.20 -0.188 0.54639E+04 125 nepheline 8.34 5.90 -2.44 -0.348 0.41609E+04 137 phlogopite-Na 29.65 27.41 -2.23 -0.124 0.38144E+04 139 prehnite 19.37 17.92 -1.46 -0.086 0.24848E+04 140 prehnite-Fe 22.50 21.93 -0.57 -0.034 0.97437E+03 141 pumpellyite-Fe 46.27 43.16 -3.11 -0.069 0.53036E+04 142 pumpellyite-Mg 48.99 45.81 -3.18 -0.071 0.54373E+04 145 pyrite -21.25 -25.73 -4.48 -1.055 0.76538E+04 146 pyrrhotite -4.26 -7.66 -3.40 -1.133 0.58037E+04 147 pyrrhotiteFe0.875 -6.02 -8.96 -2.94 -1.081 0.50199E+04 148 pyroxmangite 7.40 6.09 -1.31 -0.261 0.22284E+04 149 pyrophyllite -6.18 -11.15 -4.97 -0.311 0.84926E+04 150 quartz -2.99 -3.14 -0.15 -0.051 0.26260E+03 154 rhodochrosite -0.98 -5.18 -4.20 -1.401 0.71774E+04 155 rhodonite 7.45 6.09 -1.35 -0.270 0.23086E+04 156 sanidine -1.28 -2.49 -1.21 -0.093 0.20679E+04 166 stilbite -7.52 -7.62 -0.10 -0.005 0.16348E+03 167 stilpnomelane-Fe 13.02 12.49 -0.53 -0.016 0.90764E+03 168 stilpnomelane-Mg 27.44 25.72 -1.72 -0.051 0.29375E+04 174 talc 16.49 15.22 -1.27 -0.075 0.21639E+04 177 tephroite 18.09 15.33 -2.76 -0.394 0.47047E+04 181 tridymite -2.63 -3.14 -0.52 -0.172 0.88258E+03 182 tremolite 47.87 47.10 -0.76 -0.021 0.13050E+04 183 ferroactinolite 38.45 33.87 -4.58 -0.124 0.78254E+04 184 troilite-low -4.41 -7.66 -3.25 -1.083 0.55465E+04 190 wairakite 3.95 1.81 -2.14 -0.126 0.36515E+04 191 walstromite 11.51 9.82 -1.69 -0.338 0.28873E+04 192 wollastonite 10.46 9.82 -0.64 -0.129 0.10977E+04 193 pseudo-wollastonite 11.00 9.82 -1.18 -0.236 0.20176E+04 194 zoisite 22.85 18.63 -4.22 -0.192 0.72075E+04 195 akaganeite 7.75 4.72 -3.03 -0.656 0.51776E+04 202 chalcedony -2.80 -3.14 -0.34 -0.114 0.58190E+03 204 montmorillonite-Ca -2.29 -6.19 -3.90 -0.241 0.66548E+04 205 montmorillonite-K -2.24 -6.27 -4.03 -0.247 0.68874E+04 206 montmorillonite-Mg -2.48 -6.80 -4.32 -0.267 0.73730E+04 207 montmorillonite-Na -2.04 -5.58 -3.54 -0.217 0.60423E+04 208 nontronite-Ca 3.21 0.28 -2.93 -0.190 0.50066E+04 209 nontronite-H 2.53 -1.86 -4.39 -0.294 0.74940E+04 210 nontronite-K 3.34 0.20 -3.14 -0.202 0.53625E+04 211 nontronite-Mg 3.07 -0.33 -3.40 -0.221 0.58089E+04 212 nontronite-Na 3.52 0.89 -2.63 -0.169 0.44833E+04 228 tobermorite 9.82 7.65 -2.17 -0.592 0.37041E+04 234 alabandite -0.98 -5.04 -4.06 -1.354 0.69376E+04 237 boehmite 4.41 0.71 -3.69 -0.616 0.63085E+04 239 ferrous-oxide 9.81 6.62 -3.19 -0.798 0.54522E+04 245 silica-amorphous -2.09 -3.14 -1.05 -0.351 0.17961E+04 247 an20ab80 2.02 1.31 -0.71 -0.054 0.12041E+04 248 an25ab75 2.65 1.74 -0.91 -0.070 0.15521E+04 249 an30ab70 3.28 2.16 -1.12 -0.086 0.19097E+04 250 tr.625ac.25prg.125 45.16 44.73 -0.43 -0.012 0.73838E+03 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 0.0000400 MOLES Current total amount of reactant added: 0.0019900 MOLES New total amount of reactant added: 0.0020300 MOLES Mixing fraction reached given limit of 0.2000E-02 TOTMIX = 0.2030E-02 Execution stopped.