File SKIP_SPECIES.TXT lists species and minerals omitted from the calculations due to given T, P, option switches, or suppression in CHIMRUN, or are suppressed in the SOLTHERM database. It also lists minerals for which density is not specified in SOLTHERM. This is an extended P(to 5 kB), T(to 600 C) run (CON_FLAG = 1). methanol,aq is suppressed in SOLTHERM data file. methanol,aq is suppressed in SOLTHERM data file. CuCl4-3 is suppressed in SOLTHERM data file. H2BO3- is suppressed in SOLTHERM data file. UO2CO3,aq is suppressed in SOLTHERM data file. UO2SO4,aq is suppressed in SOLTHERM data file. UO2Cl2,aq is suppressed in SOLTHERM data file. UO2F2,aq is suppressed in SOLTHERM data file. PO4-3 is suppressed in SOLTHERM data file. H2PO4- is suppressed in SOLTHERM data file. H3PO4 is suppressed in SOLTHERM data file. O2,gas is suppressed in THIS RUN. O2,gas is suppressed in THIS RUN. amesite is suppressed in SOLTHERM data file. antigorite is suppressed in SOLTHERM data file. goethite is suppressed in THIS RUN. goethite is suppressed in THIS RUN. riebeckite is suppressed in THIS RUN. riebeckite is suppressed in THIS RUN. sapphirine-Fe(221) is suppressed in SOLTHERM data file. sapphirine(221) is suppressed in SOLTHERM data file. talc-prl is suppressed in SOLTHERM data file. PrO1.833(s) is suppressed in SOLTHERM data file. niter-NH4 is suppressed in SOLTHERM data file. FMQ_HS-1 is suppressed in THIS RUN. kf-ab-equil is suppressed in THIS RUN. ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Species No. Charge Tot.moles Trial molality Gamma Mixing solution H+ 1 1. -0.19812E-01 0.91469E-10 0.8400 0.00000000E+00 H2O 2 0. 0.49848E+02 0.10000E+01 1.0000 0.00000000E+00 Cl- 3 -1. 0.14963E-03 0.16584E-03 0.8349 0.00000000E+00 SO4-- 4 -2. -0.54828E-05 0.11670E-08 0.5185 0.00000000E+00 HCO3- 5 -1. 0.15695E-03 0.59637E-04 0.8361 0.00000000E+00 HS- 6 -1. 0.79344E-04 0.82225E-04 0.8350 0.00000000E+00 Al+++ 7 3. 0.47754E-05 0.10141E-28 0.2302 0.00000000E+00 H4SiO4 8 0. 0.12153E-01 0.71907E-03 1.0000 0.00000000E+00 Ca++ 9 2. 0.20808E-06 0.10495E-06 0.5147 0.00000000E+00 Mg++ 10 2. 0.83683E-10 0.21236E-10 0.5123 0.00000000E+00 Fe++ 11 2. 0.32592E-07 0.47803E-13 0.5129 0.00000000E+00 K+ 12 1. 0.14123E-03 0.15653E-03 0.8363 0.00000000E+00 Na+ 13 1. 0.20032E-01 0.19867E-01 0.8347 0.00000000E+00 Mn++ 14 2. 0.22519E-08 0.19837E-10 0.5133 0.00000000E+00 F- 15 -1. 0.89600E-06 0.99446E-06 0.8332 0.00000000E+00 HPO4-- 16 -2. 0.41688E-07 0.45346E-07 0.5186 0.00000000E+00 Chg. balance for total moles = -.5508E-08 Max. difference allowed = 0.1496E-07 The following parameters were given: ERPC = 0.1000E-11 pH = 0.0000 PFLUID = 50.0000 SLIM = 0.400000E-02 TEMP = 100.0000 SINC = 0.1000E-03 TEMPC = 0.0000 TOTMIX = 0.199000E-02 ENTH = 0.0000 SENTH = 0.0000 DENTH = 0.0000 TOTWAT = 90.0000 SOLMIN = 0.0000E+00 RM = 0.0000 AQGRM = 1000.0103 SUPRNT = 0.1000E-19 VBOX-1 = 400.9996 RHOFRS = 0.0000 RHOROC = 2.5000 The following options were selected: CONFLG = 1 C = 3 IFRAC = 0 IPUNCH = 2 NLOOP = 400 ISTEP = 2 LIMSOL = 1 LOOC = 0 IENTH = 0 ITREF = 0 IDEAL = 0 IPSAT = 1 INCREM = 0 INCP = 0 MINSOL = 3 NEUT = 0 AWAT = 0 CHGF = 0 Of the derived species, only those with molality > 0.10E-19 will appear in the output Species No. Charge Log K(diss) Species No. Charge Log K(diss) SiF6-2 17 -2. -24.5019 Mn+3 70 3. 19.1453 HSiO3- 18 -1. 9.0298 MnF+ 71 1. -1.2264 Ca(HSiO3)+ 19 1. 7.6723 MnO,aq 72 0. 17.9848 Mg(HSiO3)+ 20 1. 7.5773 MnOH+ 73 1. 8.5194 NaHSiO3,aq 21 0. 7.8210 MnO2-2 74 -2. 40.4638 AlO+ 22 1. 6.8663 HMnO2- 75 -1. 29.1232 AlOH+2 23 2. 3.1691 MnO4- 76 -1. 83.3111 HAlO2,aq 24 0. 10.5671 MnO4-2 77 -2. 81.3005 AlO2- 25 -1. 16.2221 MnCl+ 78 1. -0.7894 CH4,aq 26 0. 6.0126 MnSO4,aq 79 0. -2.4604 C2H6,aq 27 0. 12.3733 NaCl,aq 80 0. 0.4796 C3H8,aq 28 0. 17.3707 NaF,aq 81 0. 0.6306 C4H10,aq 29 0. 22.3757 NaOH,aq 82 0. 12.3669 ethanol,aq 30 0. 15.3258 O2,aq 83 0. 53.5502 CO,aq 31 0. 4.6892 OH- 84 -1. 12.2382 CO2,aq 32 0. -6.3298 HO2- 85 -1. 50.8010 CO3-2 33 -2. 10.0588 H2O2,aq 86 0. 40.0166 CaCO3,aq 34 0. 5.9605 H3PO2,aq 87 0. 24.3066 Ca(HCO3)+ 35 1. -1.4070 H2PO2- 88 -1. 26.5366 CaCl+ 36 1. -0.2091 HPO3-2 89 -2. 11.9254 CaCl2,aq 37 0. 0.4151 H3PO3,aq 90 0. 3.5792 CaF+ 38 1. -1.1644 H2PO3- 91 -1. 5.6232 CaOH+ 39 1. 10.1471 H3PO4,aq 92 0. -9.8447 CaSO4,aq 40 0. -2.5018 H2PO4- 93 -1. -7.2659 HCl,aq 41 0. 0.7370 PO4-3 94 -3. 12.0884 HClO,aq 42 0. 32.4260 H4P2O7,aq 95 0. -17.8095 ClO- 43 -1. 39.6530 H3P2O7- 96 -1. -15.9156 HClO2,aq 44 0. 70.1812 H2P2O7-2 97 -2. -13.4262 HF,aq 45 0. -3.8354 HP2O7-3 98 -3. -6.7266 HF2- 46 -1. -3.3639 P2O7-4 99 -4. 2.8952 Fe+3 47 3. 8.3809 H2S,aq 100 0. -6.4900 FeCl+ 48 1. -0.1994 S2-2 101 -2. 1.2355 FeCl2,aq 49 0. 4.3001 S3-2 102 -2. -8.8031 FeCl+2 50 2. 6.5269 S3- 103 -1. -16.3389 FeF+ 51 1. -1.7084 S4-2 104 -2. -18.6615 FeF+2 52 2. 1.4309 S5-2 105 -2. -28.3439 FeO,aq 53 0. 16.4104 SO2,aq 106 0. -0.2309 FeOH+ 54 1. 7.4874 SO3-2 107 -2. 10.3052 HFeO2- 55 -1. 24.3908 HSO3- 108 -1. 2.5086 FeO+ 56 1. 11.4004 HSO4- 109 -1. -2.9839 FeOH+2 57 2. 9.1194 HSO5- 110 -1. 38.8366 FeO2- 58 -1. 24.0895 S2O3-2 111 -2. -4.5600 HFeO2,aq 59 0. 15.9850 HS2O3- 112 -1. -6.8123 H2,aq 60 0. 9.4190 H2S2O3,aq 113 0. -8.0173 KCl,aq 61 0. 1.7417 S2O4-2 114 -2. 10.5541 KHSO4,aq 62 0. -0.4514 HS2O4- 115 -1. 7.6551 KOH,aq 63 0. 12.3695 H2S2O4,aq 116 0. 6.6259 KSO4- 64 -1. -1.1908 S2O5-2 117 -2. 10.0741 MgCO3,aq 65 0. 6.5614 S2O6-2 118 -2. 11.5521 Mg(HCO3)+ 66 1. -1.4164 S2O8-2 119 -2. 42.0620 MgCl+ 67 1. -0.1664 S3O6-2 120 -2. 3.7866 MgF+ 68 1. -1.7331 S4O6-2 121 -2. -17.8657 MgOH+ 69 1. 9.4041 S5O6-2 122 -2. -14.1333 For mixed gases (JSOLS=6), log K(hydrol) = log (K*P) Log K Trial Log K Trial Mineral No. hydrol Moles Mineral No. hydrol Moles H2O,gas 1 1.696 0.0000E+00 osumilite(1) 126 21.717 0.0000E+00 CO2,gas 2 -6.660 0.0000E+00 osumilite(2) 127 20.667 0.0000E+00 CH4,gas 3 4.544 0.0000E+00 osumilite-Fe 128 14.390 0.0000E+00 H2,gas 4 8.000 0.0000E+00 pargasite 129 65.092 0.0000E+00 H2S,gas 5 -6.230 0.0000E+00 periclase 130 16.138 0.0000E+00 S2,gas 6 -7.335 0.0000E+00 periclase-Fe 131 11.627 0.0000E+00 CO,gas 7 3.215 0.0000E+00 perovskite-Al 132 12.344 0.0000E+00 SO3,gas 8 17.121 0.0000E+00 perovskite-Ca 133 23.807 0.0000E+00 SO2,gas 9 0.832 0.0000E+00 perovskite-Fe 134 21.143 0.0000E+00 HF,gas 10 0.473 0.0000E+00 perovskite-Mg 135 23.119 0.0000E+00 HCl,gas 11 5.189 0.0000E+00 phase_A 136 80.189 0.0000E+00 acmite 12 7.710 0.0000E+00 phlogopite-Na 137 29.647 0.0000E+00 akermanite 13 36.442 0.0000E+00 piemontite(ordered) 138 33.776 0.0000E+00 akimotoite 14 16.591 0.0000E+00 prehnite 139 19.372 0.0000E+00 akimotoite-Fe 15 13.067 0.0000E+00 prehnite-Fe 140 22.498 0.0000E+00 albite-high 16 0.693 0.0000E+00 pumpellyite-Fe 141 46.269 0.0000E+00 albite 17 -0.384 0.4433E-06 pumpellyite-Mg 142 48.995 0.0000E+00 almandine 18 24.442 0.0000E+00 px-Mg-tschermaks 143 19.616 0.0000E+00 pyrope 19 37.248 0.0000E+00 px-Ca-tschermaks 144 18.610 0.0000E+00 spessartine 20 24.457 0.0000E+00 pyrite 145 -21.247 0.0000E+00 analcite 21 3.322 0.0000E+00 pyrrhotite 146 -4.260 0.0000E+00 andalusite 22 5.002 0.0000E+00 pyrrhotiteFe0.875 147 -6.017 0.0000E+00 andradite 23 39.009 0.4090E-08 pyroxmangite 148 7.399 0.0000E+00 grossular 24 32.731 0.5493E-09 pyrophyllite 149 -6.176 0.0000E+00 anhydrite 25 -5.317 0.0000E+00 quartz 150 -2.989 0.0000E+00 ankerite 26 -2.135 0.0000E+00 rankinite 151 40.713 0.0000E+00 annite 27 20.123 0.0000E+00 ringwoodite-Fe 152 15.456 0.0000E+00 phlogopite 28 27.065 0.0000E+00 ringwoodite-Mg 153 27.575 0.0000E+00 biotite-Mn 29 32.960 0.0000E+00 rhodochrosite 154 -0.976 0.0000E+00 anorthite 30 12.710 0.0000E+00 rhodonite 155 7.446 0.0000E+00 anthophyllite 31 51.852 0.0000E+00 sanidine 156 -1.275 0.0000E+00 anthophyllite-Fe 32 29.306 0.0000E+00 sapphirine(351) 157 78.899 0.0000E+00 apatite-OH 33 -18.153 0.0000E+00 siderite 158 -2.608 0.0000E+00 apatite-F 34 -34.301 0.0000E+00 sillimanite 159 5.262 0.0000E+00 apatite-OH-zs 35 -12.736 0.0000E+00 sodalite 160 49.976 0.0000E+00 apatite-F-zs 36 -27.774 0.0000E+00 spinel 161 20.870 0.0000E+00 apatite-Cl-zs 37 -16.674 0.0000E+00 spurrite 162 59.482 0.0000E+00 aragonite 38 0.967 0.0000E+00 staurolite-Fe 163 73.598 0.0000E+00 brucite 39 12.569 0.0000E+00 staurolite-Mg 164 89.802 0.0000E+00 calcite 40 0.812 0.0000E+00 staurolite-Mn 165 83.909 0.0000E+00 carnegieite-low 41 9.023 0.0000E+00 stilbite 166 -7.522 0.0000E+00 carnegieite-high 42 10.093 0.0000E+00 stilpnomelane-Fe 167 13.017 0.0000E+00 carpholite-Mg 43 8.582 0.0000E+00 stilpnomelane-Mg 168 27.441 0.0000E+00 carpholite-Fe 44 6.713 0.0000E+00 stishovite 169 2.720 0.0000E+00 celadonite 45 5.342 0.0000E+00 sudoite-Fe 170 18.296 0.0000E+00 celadonite-Fe 46 3.877 0.0000E+00 sudoite 171 21.077 0.0000E+00 chrysotile 47 23.892 0.0000E+00 sulfur 172 -9.152 0.0000E+00 chondrodite 48 56.475 0.0000E+00 sylvite 173 1.338 0.0000E+00 clinochlore 49 39.070 0.0000E+00 talc 174 16.491 0.0000E+00 daphnite 50 28.965 0.0000E+00 talc-Fe 175 13.448 0.0000E+00 chlorite-Mn 51 46.869 0.0000E+00 talc-tschermaks 176 19.091 0.0000E+00 chlorite-Al-free 52 47.173 0.0000E+00 tephroite 177 18.086 0.0000E+00 chloritoid-Mg 53 13.198 0.0000E+00 tilleyite 178 41.377 0.0000E+00 chloritoid-Fe 54 9.174 0.0000E+00 titanite-CaSi 179 15.479 0.0000E+00 chloritoid-Mn 55 11.401 0.0000E+00 topaz-H 180 4.618 0.0000E+00 clinohumite 56 97.128 0.0000E+00 tridymite 181 -2.626 0.0000E+00 coesite 57 -2.376 0.0000E+00 tremolite 182 47.869 0.0000E+00 cordierite-H 58 23.715 0.0000E+00 ferroactinolite 183 38.452 0.0000E+00 cordierite 59 24.049 0.0000E+00 troilite-low 184 -4.411 0.0000E+00 cordierite-Fe 60 20.450 0.0000E+00 tschermakite 185 48.210 0.0000E+00 cordierite-Mn 61 25.066 0.0000E+00 vesuvianite 186 223.471 0.0000E+00 corundum 62 8.383 0.0000E+00 wadeite-Si 187 20.216 0.0000E+00 corundum-MgSi 63 18.891 0.0000E+00 wadsleyite-Fe 188 15.680 0.0000E+00 cristobalite 64 -2.560 0.0000E+00 wadsleyite-Mg 189 25.850 0.0000E+00 cummingtonite 65 52.099 0.0000E+00 wairakite 190 3.950 0.0000E+00 cymrite-K 66 1.685 0.0000E+00 walstromite 191 11.509 0.0000E+00 deerite 67 95.671 0.0000E+00 wollastonite 192 10.461 0.0000E+00 diaspore 68 2.874 0.0000E+00 pseudo-wollastonite 193 11.000 0.0000E+00 diamond 69 -3.102 0.0000E+00 zoisite 194 22.849 0.0000E+00 diopside 70 16.181 0.0000E+00 akaganeite 195 7.755 0.0000E+00 hedenbergite 71 14.208 0.0000E+00 beidellite-Ca 196 -1.646 0.0000E+00 dolomite,ordered 72 0.546 0.0000E+00 beidellite-H 197 -2.326 0.0000E+00 eastonite 73 28.489 0.0000E+00 beidellite-K 198 -1.520 0.0000E+00 enstatite 74 17.265 0.0000E+00 beidellite-Mg 199 -1.790 0.0000E+00 clinoenstatite-HiP 75 18.354 0.0000E+00 beidellite-Na 200 -1.342 0.0000E+00 clinoenstatite 76 17.166 0.0000E+00 calcium 201 84.026 0.0000E+00 protoenstatite 77 17.824 0.0000E+00 chalcedony 202 -2.802 0.0000E+00 epidote 78 24.670 0.0000E+00 dawsonite 203 1.682 0.0000E+00 clinozoisite 79 22.806 0.0000E+00 montmorillonite-Ca 204 -2.291 0.0000E+00 epidote-Fe 80 29.841 0.0000E+00 montmorillonite-K 205 -2.237 0.0000E+00 fayalite 81 14.046 0.0000E+00 montmorillonite-Mg 206 -2.480 0.0000E+00 ferrosilite 82 11.149 0.0000E+00 montmorillonite-Na 207 -2.038 0.0000E+00 forsterite 83 21.016 0.0000E+00 nontronite-Ca 208 3.215 0.0000E+00 gedrite 84 50.522 0.0000E+00 nontronite-H 209 2.533 0.0000E+00 gehlenite 85 36.628 0.0000E+00 nontronite-K 210 3.341 0.0000E+00 gibbsite 86 4.079 0.0000E+00 nontronite-Mg 211 3.075 0.0000E+00 glaucophane 87 22.975 0.0000E+00 nontronite-Na 212 3.520 0.0000E+00 glaucophane-Fe 88 17.276 0.0000E+00 sepiolite 213 24.118 0.0000E+00 graphite 89 -3.546 0.0000E+00 topaz 214 -16.546 0.0000E+00 greenalite 90 16.140 0.0000E+00 alite 215 57.999 0.0000E+00 grunerite 91 31.215 0.0000E+00 belite 216 30.433 0.0000E+00 halite 92 1.575 0.0000E+00 ettringite 217 43.232 0.0000E+00 hematite 93 12.566 0.0000E+00 gypsum 218 -4.955 0.0000E+00 heulandite 94 -5.827 0.0000E+00 hemicarboaluminate 219 70.954 0.0000E+00 hercynite 95 17.279 0.0000E+00 hydrogarnet 220 60.662 0.0000E+00 hollandite 96 25.673 0.0000E+00 hydrogarnet-Si 221 50.586 0.0000E+00 iron 97 19.086 0.0000E+00 jennite 222 24.367 0.0000E+00 jadeite 98 4.215 0.0000E+00 monosulfoaluminate 223 53.400 0.0000E+00 julgoldite 99 70.427 0.0000E+00 monocarboaluminate 224 61.898 0.0000E+00 kalsilite 100 7.584 0.0000E+00 portlandite 225 18.272 0.0000E+00 kaolinite 101 -1.333 0.0000E+00 stratlingite 226 36.502 0.0000E+00 kyanite 102 4.876 0.0000E+00 tricarboaluminate 227 70.370 0.0000E+00 larnite-bredigite 103 30.686 0.0000E+00 tobermorite 228 9.823 0.0000E+00 laumontite 104 2.883 0.0000E+00 C4AH13 229 81.816 0.0000E+00 lawsonite 105 9.616 0.0000E+00 C2AH8 230 45.203 0.0000E+00 leucite 106 4.119 0.0000E+00 C3A 231 86.953 0.0000E+00 lime 107 25.998 0.0000E+00 C4AF 232 117.416 0.0000E+00 lizardite 108 23.244 0.0000E+00 CAH10 233 28.335 0.0000E+00 magnesite 109 0.691 0.0000E+00 alabandite 234 -0.978 0.0000E+00 magnetite 110 20.087 0.0000E+00 alunite 235 -10.435 0.0000E+00 minnesotaite 111 10.388 0.0000E+00 artinite 236 15.121 0.0000E+00 minnesotaite-Mg 112 20.602 0.0000E+00 boehmite 237 4.406 0.0000E+00 magnesioferrite 113 26.212 0.0000E+00 dolomite,disordered 238 1.247 0.0000E+00 majorite 114 53.251 0.0000E+00 ferrous-oxide 239 9.812 0.0000E+00 manganosite 115 14.058 0.0000E+00 fluorite 240 -9.931 0.0000E+00 margarite 116 17.324 0.0000E+00 huntite 241 3.770 0.0000E+00 meionite 117 44.874 0.0000E+00 hydromagnesite 242 19.995 0.0000E+00 merwinite 118 55.930 0.0000E+00 nesquehonite 243 4.723 0.0000E+00 microcline 119 -2.486 0.0000E+00 potassium-oxide 244 69.038 0.0000E+00 monticellite 120 24.339 0.0000E+00 silica-amorphous 245 -2.091 0.0000E+00 mullite-Al 121 363.148 0.0000E+00 sodium-oxide 246 55.169 0.0000E+00 mullite-Si 122 7.264 0.0000E+00 an20ab80 247 2.018 0.0000E+00 muscovite 123 2.582 0.0000E+00 an25ab75 248 2.646 0.0000E+00 paragonite 124 4.239 0.0000E+00 an30ab70 249 3.279 0.0000E+00 nepheline 125 8.339 0.0000E+00 tr.625ac.25prg.125 250 45.165 0.0000E+00 Initial composition of reactant (mole%): H2O 88.87 HCl 0.5900 CO2 7.070 CO 0.1600 H2 1.540 S2 0.8000E-01 SO2 1.150 HF 0.4000E-01 H2S 1.120 0.000 Sum of wt% of reactants: 100.6200 Reactant consumed: 0.0019900 moles log = -2.7011 Original solution: 1000.0103000 g Original solution / Rock added: 502517.74 (Water/Rock Ratio), log = 5.7012 The following minerals and/or gases with identical index are in solid solution: H2O,gas 6 CO2,gas 6 CH4,gas 6 H2,gas 6 H2S,gas 6 S2,gas 6 CO,gas 6 SO3,gas 6 SO2,gas 6 HF,gas 6 HCl,gas 6 almandine 16 pyrope 16 spessartine 16 andradite 8 grossular 8 annite 15 phlogopite 15 biotite-Mn 15 clinochlore 1 daphnite 1 chlorite-Mn 1 diopside 5 hedenbergite 5 epidote 3 clinozoisite 3 iron 9 magnetite 14 talc 7 talc-Fe 7 tremolite 2 ferroactinolite 2 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 10 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 0.0019900 Water: Moles liquid = 0.4985E+02 kg liquid = 0.8981E+00 Moles total = 0.4985E+02 kg total = 0.8980E+00 Activity = 1.0000 Stoichiometric ionic strength = .1145722E-01 Osmotic coef. = 0.9637 True ionic strength = .2013383E-01 Chg. balance for total moles = -.5508E-08 Max. difference allowed = 0.1496E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.91469E-10 -10.0387 0.76830E-10 -10.1145 0.83995E+00 -0.0757 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.16584E-03 -3.7803 0.13846E-03 -3.8587 0.83488E+00 -0.0784 4 SO4-- 0.11670E-08 -8.9329 0.60514E-09 -9.2181 0.51853E+00 -0.2852 5 HCO3- 0.59637E-04 -4.2245 0.49863E-04 -4.3022 0.83611E+00 -0.0777 6 HS- 0.82225E-04 -4.0850 0.68659E-04 -4.1633 0.83500E+00 -0.0783 7 Al+++ 0.10141E-28 -28.9939 0.23348E-29 -29.6317 0.23024E+00 -0.6378 8 H4SiO4 0.71907E-03 -3.1432 0.71907E-03 -3.1432 0.10000E+01 0.0000 9 Ca++ 0.10495E-06 -6.9790 0.54018E-07 -7.2675 0.51471E+00 -0.2884 10 Mg++ 0.21236E-10 -10.6729 0.10880E-10 -10.9634 0.51234E+00 -0.2904 11 Fe++ 0.47803E-13 -13.3205 0.24519E-13 -13.6105 0.51291E+00 -0.2900 12 K+ 0.15653E-03 -3.8054 0.13091E-03 -3.8830 0.83631E+00 -0.0776 13 Na+ 0.19867E-01 -1.7019 0.16584E-01 -1.7803 0.83473E+00 -0.0785 14 Mn++ 0.19837E-10 -10.7025 0.10183E-10 -10.9921 0.51333E+00 -0.2896 15 F- 0.99446E-06 -6.0024 0.82853E-06 -6.0817 0.83315E+00 -0.0793 16 HPO4-- 0.45346E-07 -7.3435 0.23517E-07 -7.6286 0.51860E+00 -0.2852 18 HSiO3- 0.10468E-01 -1.9802 0.87391E-02 -2.0585 0.83488E+00 -0.0784 19 Ca(HSiO3)+ 0.12852E-07 -7.8910 0.10751E-07 -7.9686 0.83649E+00 -0.0775 20 Mg(HSiO3)+ 0.32216E-11 -11.4919 0.26948E-11 -11.5695 0.83649E+00 -0.0775 21 NaHSiO3,aq 0.23440E-02 -2.6300 0.23440E-02 -2.6300 0.10000E+01 0.0000 22 AlO+ 0.64330E-16 -16.1916 0.53811E-16 -16.2691 0.83649E+00 -0.0775 24 HAlO2,aq 0.13948E-09 -9.8555 0.13948E-09 -9.8555 0.10000E+01 0.0000 25 AlO2- 0.48222E-05 -5.3168 0.40187E-05 -5.3959 0.83337E+00 -0.0792 26 CH4,aq 0.55148E-05 -5.2585 0.54955E-05 -5.2600 0.99651E+00 -0.0015 27 C2H6,aq 0.21933E-14 -14.6589 0.21857E-14 -14.6604 0.99651E+00 -0.0015 31 CO,aq 0.48575E-15 -15.3136 0.48575E-15 -15.3136 0.10000E+01 0.0000 32 CO2,aq 0.82146E-08 -8.0854 0.81859E-08 -8.0869 0.99651E+00 -0.0015 33 CO3-2 0.10956E-03 -3.9604 0.56688E-04 -4.2465 0.51742E+00 -0.2862 34 CaCO3,aq 0.38396E-07 -7.4157 0.38396E-07 -7.4157 0.10000E+01 0.0000 35 Ca(HCO3)+ 0.82194E-10 -10.0852 0.68754E-10 -10.1627 0.83649E+00 -0.0775 36 CaCl+ 0.14470E-10 -10.8395 0.12104E-10 -10.9171 0.83649E+00 -0.0775 37 CaCl2,aq 0.39815E-15 -15.4000 0.39815E-15 -15.4000 0.10000E+01 0.0000 38 CaF+ 0.78117E-12 -12.1073 0.65344E-12 -12.1848 0.83649E+00 -0.0775 39 CaOH+ 0.59904E-07 -7.2225 0.50109E-07 -7.3001 0.83649E+00 -0.0775 40 CaSO4,aq 0.10380E-13 -13.9838 0.10380E-13 -13.9838 0.10000E+01 0.0000 41 HCl,aq 0.19493E-14 -14.7101 0.19493E-14 -14.7101 0.10000E+01 0.0000 45 HF,aq 0.43577E-12 -12.3607 0.43577E-12 -12.3607 0.10000E+01 0.0000 46 HF2- 0.14601E-18 -18.8356 0.12190E-18 -18.9140 0.83488E+00 -0.0784 48 FeCl+ 0.64238E-17 -17.1922 0.53734E-17 -17.2697 0.83649E+00 -0.0775 51 FeF+ 0.12410E-17 -17.9062 0.10381E-17 -17.9838 0.83649E+00 -0.0775 53 FeO,aq 0.16144E-09 -9.7920 0.16144E-09 -9.7920 0.10000E+01 0.0000 54 FeOH+ 0.12419E-10 -10.9059 0.10388E-10 -10.9835 0.83649E+00 -0.0775 55 HFeO2- 0.26334E-07 -7.5795 0.21985E-07 -7.6579 0.83488E+00 -0.0784 56 FeO+ 0.19273E-16 -16.7151 0.16121E-16 -16.7926 0.83649E+00 -0.0775 58 FeO2- 0.66937E-09 -9.1743 0.55885E-09 -9.2527 0.83488E+00 -0.0784 59 HFeO2,aq 0.54608E-11 -11.2627 0.54608E-11 -11.2627 0.10000E+01 0.0000 60 H2,aq 0.23704E-05 -5.6252 0.23622E-05 -5.6267 0.99651E+00 -0.0015 61 KCl,aq 0.32850E-09 -9.4835 0.32850E-09 -9.4835 0.10000E+01 0.0000 63 KOH,aq 0.72763E-06 -6.1381 0.72763E-06 -6.1381 0.10000E+01 0.0000 64 KSO4- 0.14724E-11 -11.8320 0.12292E-11 -11.9104 0.83488E+00 -0.0784 65 MgCO3,aq 0.19385E-11 -11.7125 0.19385E-11 -11.7125 0.10000E+01 0.0000 66 Mg(HCO3)+ 0.16916E-13 -13.7717 0.14150E-13 -13.8492 0.83649E+00 -0.0775 67 MgCl+ 0.26414E-14 -14.5782 0.22095E-14 -14.6557 0.83649E+00 -0.0775 68 MgF+ 0.58282E-15 -15.2345 0.48753E-15 -15.3120 0.83649E+00 -0.0775 69 MgOH+ 0.66764E-10 -10.1755 0.55847E-10 -10.2530 0.83649E+00 -0.0775 71 MnF+ 0.16989E-15 -15.7698 0.14211E-15 -15.8474 0.83649E+00 -0.0775 72 MnO,aq 0.17866E-08 -8.7480 0.17866E-08 -8.7480 0.10000E+01 0.0000 73 MnOH+ 0.47914E-09 -9.3195 0.40079E-09 -9.3971 0.83649E+00 -0.0775 74 MnO2-2 0.19413E-10 -10.7119 0.10045E-10 -10.9981 0.51742E+00 -0.2862 75 HMnO2- 0.20251E-09 -9.6936 0.16907E-09 -9.7719 0.83488E+00 -0.0784 78 MnCl+ 0.10380E-13 -13.9838 0.86824E-14 -14.0614 0.83649E+00 -0.0775 79 MnSO4,aq 0.17790E-17 -17.7498 0.17790E-17 -17.7498 0.10000E+01 0.0000 80 NaCl,aq 0.76096E-06 -6.1186 0.76096E-06 -6.1186 0.10000E+01 0.0000 81 NaF,aq 0.32168E-08 -8.4926 0.32168E-08 -8.4926 0.10000E+01 0.0000 82 NaOH,aq 0.92740E-04 -4.0327 0.92740E-04 -4.0327 0.10000E+01 0.0000 84 OH- 0.90239E-02 -2.0446 0.75202E-02 -2.1238 0.83337E+00 -0.0792 89 HPO3-2 0.33457E-15 -15.4755 0.17311E-15 -15.7617 0.51742E+00 -0.2862 91 H2PO3- 0.31946E-19 -19.4956 0.26671E-19 -19.5740 0.83488E+00 -0.0784 92 H3PO4,aq 0.97087E-18 -18.0128 0.97087E-18 -18.0128 0.10000E+01 0.0000 93 H2PO4- 0.39884E-10 -10.3992 0.33330E-10 -10.4772 0.83568E+00 -0.0780 94 PO4-3 0.10325E-08 -8.9861 0.24974E-09 -9.6025 0.24187E+00 -0.6164 98 HP2O7-3 0.98228E-18 -18.0078 0.22639E-18 -18.6451 0.23047E+00 -0.6374 99 P2O7-4 0.91839E-17 -17.0370 0.70393E-18 -18.1525 0.76648E-01 -1.1155 100 H2S,aq 0.16360E-07 -7.7862 0.16303E-07 -7.7877 0.99651E+00 -0.0015 101 S2-2 0.85460E-13 -13.0682 0.44219E-13 -13.3544 0.51742E+00 -0.2862 107 SO3-2 0.35386E-15 -15.4512 0.18576E-15 -15.7311 0.52494E+00 -0.2799 108 HSO3- 0.10703E-17 -17.9705 0.89357E-18 -18.0489 0.83488E+00 -0.0784 109 HSO4- 0.53512E-16 -16.2715 0.44806E-16 -16.3487 0.83731E+00 -0.0771 111 S2O3-2 0.22397E-18 -18.6498 0.11589E-18 -18.9360 0.51742E+00 -0.2862 Charge balance for all species = -.6133E-08 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.9146893E-10 -.2205845E-01 -.2219480E+02 0.0000 2 H2O 0.1000000E+01 0.5550457E+02 0.9981869E+06 0.0000 3 Cl- 0.1658427E-03 0.1666040E-03 0.5896306E+01 6.2558 4 SO4-- 0.1167028E-08 -.6106113E-05 -.5855396E+00 11.0108 5 HCO3- 0.5963702E-04 0.1747566E-03 0.1064456E+02 5.8122 6 HS- 0.8222541E-04 0.8834905E-04 0.2916782E+01 5.9512 7 Al+++ 0.1014082E-28 0.4822371E-05 0.1298878E+00 0.7117 8 H4SiO4 0.7190690E-03 0.1353059E-01 0.1298229E+04 -3.1432 9 Ca++ 0.1049489E-06 0.2161985E-06 0.8649687E-02 12.9615 10 Mg++ 0.2123561E-10 0.9317929E-10 0.2261422E-05 9.2656 11 Fe++ 0.4780344E-13 0.2718232E-07 0.1515402E-02 6.6184 12 K+ 0.1565275E-03 0.1572555E-03 0.6138275E+01 6.2314 13 Na+ 0.1986730E-01 0.2230482E-01 0.5118886E+03 8.3342 14 Mn++ 0.1983750E-10 0.2507479E-08 0.1375155E-03 9.2368 15 F- 0.9944560E-06 0.9976741E-06 0.1892074E-01 4.0328 16 HPO4-- 0.4534638E-07 0.4641878E-07 0.4447455E-02 12.6003 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.1981227E-01 -.1981045E-01 -.1819812E-05 0.0000000E+00 2 H2O 0.4984804E+02 0.4984804E+02 -.1777433E-05 0.0000000E+00 3 Cl- 0.1496252E-03 0.1496252E-03 0.0000000E+00 0.0000000E+00 4 SO4-- -.5482810E-05 -.5483833E-05 0.1022517E-08 0.0000000E+00 5 HCO3- 0.1569470E-03 0.1569470E-03 0.0000000E+00 0.0000000E+00 6 HS- 0.7934428E-04 0.7934530E-04 -.1022517E-08 0.0000000E+00 7 Al+++ 0.4775352E-05 0.4330918E-05 0.4444343E-06 0.0000000E+00 8 H4SiO4 0.1215302E-01 0.1215168E-01 0.1343925E-05 0.0000000E+00 9 Ca++ 0.2080835E-06 0.1941655E-06 0.1391799E-07 0.0000000E+00 10 Mg++ 0.8368328E-10 0.8368328E-10 0.0000000E+00 0.0000000E+00 11 Fe++ 0.3259227E-07 0.2441214E-07 0.8180133E-08 0.0000000E+00 12 K+ 0.1412294E-03 0.1412294E-03 0.0000000E+00 0.0000000E+00 13 Na+ 0.2003215E-01 0.2003171E-01 0.4433358E-06 0.0000000E+00 14 Mn++ 0.2251939E-08 0.2251939E-08 0.0000000E+00 0.0000000E+00 15 F- 0.8960000E-06 0.8960000E-06 0.0000000E+00 0.0000000E+00 16 HPO4-- 0.4168819E-07 0.4168819E-07 0.0000000E+00 0.0000000E+00 Chg. balance for solid moles: 0.1588E-21 Mass of aqueous solution: 0.899659E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 0.0019900 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 0.4433E-06 -6.353 0.1163E-03 -3.935 98.04 0.4463E-04 andradite 0.4090E-08 -8.388 0.2078E-05 -5.682 1.753 0.5400E-06 grossular 0.5493E-09 -9.260 0.2474E-06 -6.607 0.2087 0.6884E-07 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8816E+00 0.8816E+00 1.0000 -0.055 grossular 0.1184E+00 0.1184E+00 1.0000 -0.927 Solid products produced: Mass = 0.000119 g Volume = 0.000045 cm3 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.0019900 moles log = -2.7011 Original solution: 1000.0103000 g Original solution / Rock added: 502517.74 (Water/Rock Ratio), log = 5.7012 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0315 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9892E+00 0.9858 0.1006E+01 0.1020E+01 CO2,gas 0.8431E-06 1.0070 0.8758E-06 0.8697E-06 CH4,gas 0.7745E-02 1.0125 0.8089E-02 0.7989E-02 H2,gas 0.3005E-02 1.0006 0.3101E-02 0.3100E-02 H2S,gas 0.4362E-06 0.9960 0.4482E-06 0.4500E-06 S2,gas 0.7599E-27 1.0000 0.7839E-27 0.7839E-27 CO,gas 0.7017E-12 1.0000 0.7239E-12 0.7239E-12 SO3,gas 0.1309E-44 1.0000 0.1351E-44 0.1351E-44 SO2,gas 0.1580E-24 1.0000 0.1630E-24 0.1630E-24 HF,gas 0.1037E-14 1.0000 0.1070E-14 0.1070E-14 HCl,gas 0.3334E-17 1.0000 0.3440E-17 0.3440E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 17 albite -0.38 -0.38 0.00 0.000 -0.94784E-12 23 andradite 39.01 39.01 0.00 0.000 -0.12132E-10 24 grossular 32.73 32.73 0.00 0.000 0.24265E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -14.42 -7.76 -2.586 0.13244E+05 -6.058 3 CH4,gas 4.54 0.75 -3.79 -0.948 0.64732E+04 -2.092 4 H2,gas 8.00 3.79 -4.21 -2.404 0.71841E+04 -2.508 5 H2S,gas -6.23 -14.28 -8.05 -4.024 0.13741E+05 -6.349 6 S2,gas -7.34 -36.14 -28.80 -4.431 0.49183E+05 -27.106 7 CO,gas 3.21 -10.62 -13.84 -4.258 0.23630E+05 -12.140 8 SO3,gas 17.12 -29.45 -46.57 -11.642 0.79514E+05 -44.869 9 SO2,gas 0.83 -25.65 -26.49 -7.063 0.45226E+05 -24.788 10 HF,gas 0.47 -16.20 -16.67 -8.335 0.28463E+05 -14.971 11 HCl,gas 5.19 -13.97 -19.16 -9.581 0.32719E+05 -17.463 12 acmite 7.71 6.77 -0.94 -0.098 0.16046E+04 16 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 20 spessartine 24.46 19.70 -4.75 -0.238 0.81160E+04 21 analcite 3.32 2.76 -0.56 -0.062 0.96045E+03 27 annite 20.12 17.37 -2.75 -0.153 0.47035E+04 28 phlogopite 27.06 25.31 -1.75 -0.097 0.29957E+04 30 anorthite 12.71 8.10 -4.61 -0.355 0.78748E+04 33 apatite-OH -18.15 -18.77 -0.61 -0.047 0.10446E+04 34 apatite-F -34.30 -34.96 -0.66 -0.055 0.11277E+04 38 aragonite 0.97 -1.46 -2.42 -0.807 0.41350E+04 39 brucite 12.57 9.27 -3.30 -0.661 0.56398E+04 40 calcite 0.81 -1.46 -2.27 -0.756 0.38708E+04 41 carnegieite-low 9.02 5.90 -3.12 -0.446 0.53285E+04 42 carnegieite-high 10.09 5.90 -4.19 -0.599 0.71555E+04 43 carpholite-Mg 8.58 4.40 -4.18 -0.279 0.71366E+04 44 carpholite-Fe 6.71 1.76 -4.96 -0.330 0.84645E+04 45 celadonite 5.34 3.64 -1.71 -0.100 0.29127E+04 46 celadonite-Fe 3.88 0.99 -2.89 -0.170 0.49310E+04 47 chrysotile 23.89 21.51 -2.38 -0.199 0.40675E+04 49 clinochlore 39.07 38.32 -0.75 -0.023 0.12773E+04 50 daphnite 28.97 25.09 -3.88 -0.121 0.66240E+04 52 chlorite-Al-free 47.17 43.02 -4.15 -0.173 0.70901E+04 54 chloritoid-Fe 9.17 4.90 -4.28 -0.285 0.72996E+04 55 chloritoid-Mn 11.40 7.52 -3.88 -0.259 0.66321E+04 57 coesite -2.38 -3.14 -0.77 -0.256 0.13099E+04 64 cristobalite -2.56 -3.14 -0.58 -0.194 0.99527E+03 66 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71236E+04 68 diaspore 2.87 0.71 -2.16 -0.360 0.36916E+04 69 diamond -3.10 -6.83 -3.73 -1.066 0.63683E+04 70 diopside 16.18 15.94 -0.24 -0.024 0.41111E+03 71 hedenbergite 14.21 13.29 -0.91 -0.091 0.15620E+04 76 clinoenstatite 17.17 12.24 -4.92 -0.492 0.84035E+04 78 epidote 24.67 22.64 -2.03 -0.098 0.34679E+04 79 clinozoisite 22.81 18.63 -4.18 -0.190 0.71334E+04 80 epidote-Fe 29.84 26.65 -3.19 -0.166 0.54491E+04 81 fayalite 14.05 10.09 -3.95 -0.565 0.67481E+04 82 ferrosilite 11.15 6.95 -4.20 -0.420 0.71697E+04 86 gibbsite 4.08 0.71 -3.37 -0.481 0.57502E+04 87 glaucophane 22.97 20.74 -2.23 -0.060 0.38116E+04 88 glaucophane-Fe 17.28 12.80 -4.47 -0.121 0.76404E+04 89 graphite -3.55 -6.83 -3.29 -0.939 0.56105E+04 90 greenalite 16.14 13.57 -2.57 -0.214 0.43893E+04 93 hematite 12.57 9.44 -3.12 -0.378 0.53301E+04 94 heulandite -5.83 -7.62 -1.79 -0.081 0.30573E+04 98 jadeite 4.22 2.76 -1.46 -0.146 0.24859E+04 100 kalsilite 7.58 3.80 -3.78 -0.541 0.64612E+04 101 kaolinite -1.33 -4.86 -3.53 -0.321 0.60280E+04 104 laumontite 2.88 1.81 -1.07 -0.071 0.18296E+04 105 lawsonite 9.62 8.10 -1.52 -0.101 0.25915E+04 106 leucite 4.12 0.66 -3.46 -0.346 0.59117E+04 108 lizardite 23.24 21.51 -1.73 -0.144 0.29601E+04 110 magnetite 20.09 16.06 -4.02 -0.329 0.68716E+04 111 minnesotaite 10.39 7.28 -3.11 -0.183 0.53029E+04 115 manganosite 14.06 9.24 -4.82 -1.205 0.82322E+04 119 microcline -2.49 -2.49 0.00 0.000 0.17100E+00 123 muscovite 2.58 -1.06 -3.65 -0.214 0.62249E+04 124 paragonite 4.24 1.04 -3.20 -0.188 0.54639E+04 125 nepheline 8.34 5.90 -2.44 -0.348 0.41609E+04 137 phlogopite-Na 29.65 27.41 -2.23 -0.124 0.38144E+04 139 prehnite 19.37 17.92 -1.46 -0.086 0.24848E+04 140 prehnite-Fe 22.50 21.93 -0.57 -0.034 0.97437E+03 141 pumpellyite-Fe 46.27 43.16 -3.11 -0.069 0.53036E+04 142 pumpellyite-Mg 48.99 45.81 -3.18 -0.071 0.54373E+04 145 pyrite -21.25 -25.73 -4.48 -1.055 0.76538E+04 146 pyrrhotite -4.26 -7.66 -3.40 -1.133 0.58037E+04 147 pyrrhotiteFe0.875 -6.02 -8.96 -2.94 -1.081 0.50199E+04 148 pyroxmangite 7.40 6.09 -1.31 -0.261 0.22284E+04 149 pyrophyllite -6.18 -11.15 -4.97 -0.311 0.84926E+04 150 quartz -2.99 -3.14 -0.15 -0.051 0.26260E+03 154 rhodochrosite -0.98 -5.18 -4.20 -1.401 0.71774E+04 155 rhodonite 7.45 6.09 -1.35 -0.270 0.23086E+04 156 sanidine -1.28 -2.49 -1.21 -0.093 0.20679E+04 166 stilbite -7.52 -7.62 -0.10 -0.005 0.16348E+03 167 stilpnomelane-Fe 13.02 12.49 -0.53 -0.016 0.90764E+03 168 stilpnomelane-Mg 27.44 25.72 -1.72 -0.051 0.29375E+04 174 talc 16.49 15.22 -1.27 -0.075 0.21639E+04 177 tephroite 18.09 15.33 -2.76 -0.394 0.47047E+04 181 tridymite -2.63 -3.14 -0.52 -0.172 0.88258E+03 182 tremolite 47.87 47.10 -0.76 -0.021 0.13050E+04 183 ferroactinolite 38.45 33.87 -4.58 -0.124 0.78254E+04 184 troilite-low -4.41 -7.66 -3.25 -1.083 0.55465E+04 190 wairakite 3.95 1.81 -2.14 -0.126 0.36515E+04 191 walstromite 11.51 9.82 -1.69 -0.338 0.28873E+04 192 wollastonite 10.46 9.82 -0.64 -0.129 0.10977E+04 193 pseudo-wollastonite 11.00 9.82 -1.18 -0.236 0.20176E+04 194 zoisite 22.85 18.63 -4.22 -0.192 0.72075E+04 195 akaganeite 7.75 4.72 -3.03 -0.656 0.51776E+04 202 chalcedony -2.80 -3.14 -0.34 -0.114 0.58190E+03 204 montmorillonite-Ca -2.29 -6.19 -3.90 -0.241 0.66548E+04 205 montmorillonite-K -2.24 -6.27 -4.03 -0.247 0.68874E+04 206 montmorillonite-Mg -2.48 -6.80 -4.32 -0.267 0.73730E+04 207 montmorillonite-Na -2.04 -5.58 -3.54 -0.217 0.60423E+04 208 nontronite-Ca 3.21 0.28 -2.93 -0.190 0.50066E+04 209 nontronite-H 2.53 -1.86 -4.39 -0.294 0.74940E+04 210 nontronite-K 3.34 0.20 -3.14 -0.202 0.53625E+04 211 nontronite-Mg 3.07 -0.33 -3.40 -0.221 0.58089E+04 212 nontronite-Na 3.52 0.89 -2.63 -0.169 0.44833E+04 228 tobermorite 9.82 7.65 -2.17 -0.592 0.37041E+04 234 alabandite -0.98 -5.04 -4.06 -1.354 0.69376E+04 237 boehmite 4.41 0.71 -3.69 -0.616 0.63085E+04 239 ferrous-oxide 9.81 6.62 -3.19 -0.798 0.54522E+04 245 silica-amorphous -2.09 -3.14 -1.05 -0.351 0.17961E+04 247 an20ab80 2.02 1.31 -0.71 -0.054 0.12041E+04 248 an25ab75 2.65 1.74 -0.91 -0.070 0.15521E+04 249 an30ab70 3.28 2.16 -1.12 -0.086 0.19097E+04 250 tr.625ac.25prg.125 45.16 44.73 -0.43 -0.012 0.73838E+03 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 0.0001000 MOLES Current total amount of reactant added: 0.0019900 MOLES New total amount of reactant added: 0.0020900 MOLES Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.5508E-08 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 7 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 0.0020900 Water: Moles liquid = 0.4985E+02 kg liquid = 0.8981E+00 Moles total = 0.4985E+02 kg total = 0.8980E+00 Activity = 1.0000 Stoichiometric ionic strength = .1146361E-01 Osmotic coef. = 0.9635 True ionic strength = .2013967E-01 Chg. balance for total moles = -.5508E-08 Max. difference allowed = 0.1502E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.91635E-10 -10.0379 0.76968E-10 -10.1137 0.83994E+00 -0.0758 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.16650E-03 -3.7786 0.13900E-03 -3.8570 0.83487E+00 -0.0784 4 SO4-- 0.13970E-08 -8.8548 0.72433E-09 -9.1401 0.51849E+00 -0.2853 5 HCO3- 0.62724E-04 -4.2026 0.52443E-04 -4.2803 0.83609E+00 -0.0777 6 HS- 0.84930E-04 -4.0709 0.70916E-04 -4.1493 0.83499E+00 -0.0783 7 Al+++ 0.10164E-28 -28.9929 0.23398E-29 -29.6308 0.23020E+00 -0.6379 8 H4SiO4 0.72028E-03 -3.1425 0.72028E-03 -3.1425 0.10000E+01 0.0000 9 Ca++ 0.10406E-06 -6.9827 0.53557E-07 -7.2712 0.51467E+00 -0.2885 10 Mg++ 0.21242E-10 -10.6728 0.10882E-10 -10.9633 0.51230E+00 -0.2905 11 Fe++ 0.47959E-13 -13.3191 0.24597E-13 -13.6091 0.51287E+00 -0.2900 12 K+ 0.15653E-03 -3.8054 0.13090E-03 -3.8830 0.83629E+00 -0.0776 13 Na+ 0.19868E-01 -1.7019 0.16584E-01 -1.7803 0.83471E+00 -0.0785 14 Mn++ 0.19906E-10 -10.7010 0.10218E-10 -10.9906 0.51329E+00 -0.2896 15 F- 0.10388E-05 -5.9834 0.86550E-06 -6.0627 0.83314E+00 -0.0793 16 HPO4-- 0.45348E-07 -7.3434 0.23516E-07 -7.6286 0.51857E+00 -0.2852 18 HSiO3- 0.10466E-01 -1.9802 0.87381E-02 -2.0586 0.83487E+00 -0.0784 19 Ca(HSiO3)+ 0.12741E-07 -7.8948 0.10658E-07 -7.9723 0.83647E+00 -0.0775 20 Mg(HSiO3)+ 0.32219E-11 -11.4919 0.26950E-11 -11.5694 0.83647E+00 -0.0775 21 NaHSiO3,aq 0.23437E-02 -2.6301 0.23437E-02 -2.6301 0.10000E+01 0.0000 22 AlO+ 0.64238E-16 -16.1922 0.53733E-16 -16.2698 0.83647E+00 -0.0775 24 HAlO2,aq 0.13903E-09 -9.8569 0.13903E-09 -9.8569 0.10000E+01 0.0000 25 AlO2- 0.47981E-05 -5.3189 0.39985E-05 -5.3981 0.83335E+00 -0.0792 26 CH4,aq 0.50050E-05 -5.3006 0.49875E-05 -5.3021 0.99650E+00 -0.0015 27 C2H6,aq 0.18753E-14 -14.7269 0.18687E-14 -14.7285 0.99650E+00 -0.0015 31 CO,aq 0.49305E-15 -15.3071 0.49305E-15 -15.3071 0.10000E+01 0.0000 32 CO2,aq 0.86551E-08 -8.0627 0.86249E-08 -8.0642 0.99650E+00 -0.0015 33 CO3-2 0.11503E-03 -3.9392 0.59514E-04 -4.2254 0.51739E+00 -0.2862 34 CaCO3,aq 0.39967E-07 -7.3983 0.39967E-07 -7.3983 0.10000E+01 0.0000 35 Ca(HCO3)+ 0.85711E-10 -10.0670 0.71695E-10 -10.1445 0.83647E+00 -0.0775 36 CaCl+ 0.14403E-10 -10.8415 0.12048E-10 -10.9191 0.83647E+00 -0.0775 37 CaCl2,aq 0.39786E-15 -15.4003 0.39786E-15 -15.4003 0.10000E+01 0.0000 38 CaF+ 0.80908E-12 -12.0920 0.67677E-12 -12.1696 0.83647E+00 -0.0775 39 CaOH+ 0.59287E-07 -7.2270 0.49592E-07 -7.3046 0.83647E+00 -0.0775 40 CaSO4,aq 0.12319E-13 -13.9094 0.12319E-13 -13.9094 0.10000E+01 0.0000 41 HCl,aq 0.19605E-14 -14.7076 0.19605E-14 -14.7076 0.10000E+01 0.0000 45 HF,aq 0.45603E-12 -12.3410 0.45603E-12 -12.3410 0.10000E+01 0.0000 46 HF2- 0.15962E-18 -18.7969 0.13326E-18 -18.8753 0.83487E+00 -0.0784 48 FeCl+ 0.64696E-17 -17.1891 0.54117E-17 -17.2667 0.83647E+00 -0.0775 51 FeF+ 0.13005E-17 -17.8859 0.10879E-17 -17.9634 0.83647E+00 -0.0775 53 FeO,aq 0.16137E-09 -9.7922 0.16137E-09 -9.7922 0.10000E+01 0.0000 54 FeOH+ 0.12436E-10 -10.9053 0.10402E-10 -10.9829 0.83647E+00 -0.0775 55 HFeO2- 0.26276E-07 -7.5804 0.21937E-07 -7.6588 0.83487E+00 -0.0784 56 FeO+ 0.19663E-16 -16.7063 0.16448E-16 -16.7839 0.83647E+00 -0.0775 58 FeO2- 0.68048E-09 -9.1672 0.56811E-09 -9.2456 0.83487E+00 -0.0784 59 HFeO2,aq 0.55613E-11 -11.2548 0.55613E-11 -11.2548 0.10000E+01 0.0000 60 H2,aq 0.22836E-05 -5.6414 0.22757E-05 -5.6429 0.99650E+00 -0.0015 61 KCl,aq 0.32979E-09 -9.4818 0.32979E-09 -9.4818 0.10000E+01 0.0000 63 KOH,aq 0.72632E-06 -6.1389 0.72632E-06 -6.1389 0.10000E+01 0.0000 64 KSO4- 0.17624E-11 -11.7539 0.14713E-11 -11.8323 0.83487E+00 -0.0784 65 MgCO3,aq 0.20355E-11 -11.6913 0.20355E-11 -11.6913 0.10000E+01 0.0000 66 Mg(HCO3)+ 0.17795E-13 -13.7497 0.14885E-13 -13.8272 0.83647E+00 -0.0775 67 MgCl+ 0.26524E-14 -14.5764 0.22187E-14 -14.6539 0.83647E+00 -0.0775 68 MgF+ 0.60897E-15 -15.2154 0.50939E-15 -15.2930 0.83647E+00 -0.0775 69 MgOH+ 0.66659E-10 -10.1761 0.55758E-10 -10.2537 0.83647E+00 -0.0775 71 MnF+ 0.17808E-15 -15.7494 0.14896E-15 -15.8269 0.83647E+00 -0.0775 72 MnO,aq 0.17862E-08 -8.7481 0.17862E-08 -8.7481 0.10000E+01 0.0000 73 MnOH+ 0.47991E-09 -9.3188 0.40143E-09 -9.3964 0.83647E+00 -0.0775 74 MnO2-2 0.19341E-10 -10.7135 0.10007E-10 -10.9997 0.51739E+00 -0.2862 75 HMnO2- 0.20211E-09 -9.6944 0.16873E-09 -9.7728 0.83487E+00 -0.0784 78 MnCl+ 0.10456E-13 -13.9806 0.87460E-14 -14.0582 0.83647E+00 -0.0775 79 MnSO4,aq 0.21366E-17 -17.6703 0.21366E-17 -17.6703 0.10000E+01 0.0000 80 NaCl,aq 0.76394E-06 -6.1169 0.76394E-06 -6.1169 0.10000E+01 0.0000 81 NaF,aq 0.33604E-08 -8.4736 0.33604E-08 -8.4736 0.10000E+01 0.0000 82 NaOH,aq 0.92574E-04 -4.0335 0.92574E-04 -4.0335 0.10000E+01 0.0000 84 OH- 0.90078E-02 -2.0454 0.75067E-02 -2.1246 0.83335E+00 -0.0792 89 HPO3-2 0.32233E-15 -15.4917 0.16677E-15 -15.7779 0.51739E+00 -0.2862 91 H2PO3- 0.30831E-19 -19.5110 0.25740E-19 -19.5894 0.83487E+00 -0.0784 92 H3PO4,aq 0.97432E-18 -18.0113 0.97432E-18 -18.0113 0.10000E+01 0.0000 93 H2PO4- 0.39955E-10 -10.3984 0.33389E-10 -10.4764 0.83566E+00 -0.0780 94 PO4-3 0.10308E-08 -8.9868 0.24928E-09 -9.6033 0.24183E+00 -0.6165 98 HP2O7-3 0.98413E-18 -18.0069 0.22677E-18 -18.6444 0.23043E+00 -0.6375 99 P2O7-4 0.91860E-17 -17.0369 0.70388E-18 -18.1525 0.76625E-01 -1.1156 100 H2S,aq 0.16928E-07 -7.7714 0.16869E-07 -7.7729 0.99650E+00 -0.0015 101 S2-2 0.94644E-13 -13.0239 0.48968E-13 -13.3101 0.51739E+00 -0.2862 107 SO3-2 0.40807E-15 -15.3893 0.21420E-15 -15.6692 0.52490E+00 -0.2799 108 HSO3- 0.12364E-17 -17.9078 0.10323E-17 -17.9862 0.83487E+00 -0.0784 109 HSO4- 0.64168E-16 -16.1927 0.53727E-16 -16.2698 0.83729E+00 -0.0771 111 S2O3-2 0.27742E-18 -18.5569 0.14353E-18 -18.8430 0.51739E+00 -0.2862 Charge balance for all species = -.6133E-08 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.9163491E-10 -.2204632E-01 -.2218259E+02 0.0000 2 H2O 0.1000000E+01 0.5550456E+02 0.9981863E+06 0.0000 3 Cl- 0.1664963E-03 0.1672606E-03 0.5919543E+01 6.2567 4 SO4-- 0.1396993E-08 -.5574424E-05 -.5345536E+00 11.0873 5 HCO3- 0.6272396E-04 0.1828067E-03 0.1113489E+02 5.8334 6 HS- 0.8493020E-04 0.9052295E-04 0.2988550E+01 5.9644 7 Al+++ 0.1016439E-28 0.4798259E-05 0.1292383E+00 0.7103 8 H4SiO4 0.7202763E-03 0.1353050E-01 0.1298220E+04 -3.1425 9 Ca++ 0.1040618E-06 0.2161582E-06 0.8648069E-02 12.9562 10 Mg++ 0.2124170E-10 0.9317911E-10 0.2261417E-05 9.2641 11 Fe++ 0.4795905E-13 0.2713576E-07 0.1512806E-02 6.6183 12 K+ 0.1565285E-03 0.1572552E-03 0.6138261E+01 6.2306 13 Na+ 0.1986767E-01 0.2230475E-01 0.5118868E+03 8.3334 14 Mn++ 0.1990627E-10 0.2507474E-08 0.1375152E-03 9.2367 15 F- 0.1038849E-05 0.1042211E-05 0.1976537E-01 4.0510 16 HPO4-- 0.4534795E-07 0.4641869E-07 0.4447445E-02 12.5987 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.1980150E-01 -.1979959E-01 -.1906566E-05 0.0000000E+00 2 H2O 0.4984812E+02 0.4984812E+02 -.1864111E-05 0.0000000E+00 3 Cl- 0.1502152E-03 0.1502152E-03 0.0000000E+00 0.0000000E+00 4 SO4-- -.5005310E-05 -.5006338E-05 0.1027738E-08 0.0000000E+00 5 HCO3- 0.1641770E-03 0.1641770E-03 0.0000000E+00 0.0000000E+00 6 HS- 0.8129678E-04 0.8129781E-04 -.1027738E-08 0.0000000E+00 7 Al+++ 0.4775352E-05 0.4309271E-05 0.4660807E-06 0.0000000E+00 8 H4SiO4 0.1215302E-01 0.1215161E-01 0.1408954E-05 0.0000000E+00 9 Ca++ 0.2080835E-06 0.1941296E-06 0.1395387E-07 0.0000000E+00 10 Mg++ 0.8368328E-10 0.8368328E-10 0.0000000E+00 0.0000000E+00 11 Fe++ 0.3259227E-07 0.2437037E-07 0.8221901E-08 0.0000000E+00 12 K+ 0.1412294E-03 0.1412294E-03 0.0000000E+00 0.0000000E+00 13 Na+ 0.2003215E-01 0.2003169E-01 0.4650000E-06 0.0000000E+00 14 Mn++ 0.2251939E-08 0.2251939E-08 0.0000000E+00 0.0000000E+00 15 F- 0.9360000E-06 0.9360000E-06 0.0000000E+00 0.0000000E+00 16 HPO4-- 0.4168819E-07 0.4168819E-07 0.0000000E+00 0.0000000E+00 Chg. balance for solid moles: 0.1588E-21 Mass of aqueous solution: 0.899661E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 0.0020900 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 0.4650E-06 -6.333 0.1219E-03 -3.914 98.12 0.4681E-04 andradite 0.4111E-08 -8.386 0.2089E-05 -5.680 1.681 0.5428E-06 grossular 0.5403E-09 -9.267 0.2434E-06 -6.614 0.1959 0.6772E-07 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8838E+00 0.8838E+00 1.0000 -0.054 grossular 0.1162E+00 0.1162E+00 1.0000 -0.935 Solid products produced: Mass = 0.000124 g Volume = 0.000047 cm3 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.0020900 moles log = -2.6799 Original solution: 1000.0103000 g Original solution / Rock added: 478473.83 (Water/Rock Ratio), log = 5.6799 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0307 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9901E+00 0.9858 0.1006E+01 0.1020E+01 CO2,gas 0.8891E-06 1.0070 0.9228E-06 0.9163E-06 CH4,gas 0.7035E-02 1.0125 0.7341E-02 0.7251E-02 H2,gas 0.2897E-02 1.0005 0.2988E-02 0.2986E-02 H2S,gas 0.4517E-06 0.9960 0.4637E-06 0.4656E-06 S2,gas 0.8774E-27 1.0000 0.9043E-27 0.9043E-27 CO,gas 0.7129E-12 1.0000 0.7347E-12 0.7347E-12 SO3,gas 0.1574E-44 1.0000 0.1622E-44 0.1622E-44 SO2,gas 0.1830E-24 1.0000 0.1886E-24 0.1886E-24 HF,gas 0.1086E-14 1.0000 0.1120E-14 0.1120E-14 HCl,gas 0.3356E-17 1.0000 0.3459E-17 0.3459E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 17 albite -0.38 -0.38 0.00 0.000 -0.94784E-12 23 andradite 39.01 39.01 0.00 0.000 0.12132E-10 24 grossular 32.73 32.73 0.00 0.000 0.24265E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -14.39 -7.73 -2.578 0.13205E+05 -6.035 3 CH4,gas 4.54 0.71 -3.83 -0.958 0.65451E+04 -2.134 4 H2,gas 8.00 3.78 -4.22 -2.414 0.72117E+04 -2.525 5 H2S,gas -6.23 -14.26 -8.03 -4.016 0.13716E+05 -6.334 6 S2,gas -7.34 -36.08 -28.74 -4.422 0.49077E+05 -27.044 7 CO,gas 3.21 -10.62 -13.83 -4.256 0.23619E+05 -12.134 8 SO3,gas 17.12 -29.37 -46.49 -11.622 0.79378E+05 -44.790 9 SO2,gas 0.83 -25.59 -26.42 -7.046 0.45117E+05 -24.724 10 HF,gas 0.47 -16.18 -16.65 -8.325 0.28429E+05 -14.951 11 HCl,gas 5.19 -13.97 -19.16 -9.580 0.32715E+05 -17.461 12 acmite 7.71 6.78 -0.93 -0.097 0.15899E+04 16 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 20 spessartine 24.46 19.70 -4.75 -0.238 0.81175E+04 21 analcite 3.32 2.76 -0.56 -0.063 0.96169E+03 27 annite 20.12 17.37 -2.76 -0.153 0.47045E+04 28 phlogopite 27.06 25.31 -1.76 -0.098 0.30033E+04 30 anorthite 12.71 8.09 -4.62 -0.355 0.78861E+04 33 apatite-OH -18.15 -18.79 -0.63 -0.049 0.10818E+04 34 apatite-F -34.30 -34.96 -0.66 -0.055 0.11312E+04 38 aragonite 0.97 -1.44 -2.40 -0.801 0.41053E+04 39 brucite 12.57 9.26 -3.30 -0.661 0.56423E+04 40 calcite 0.81 -1.44 -2.25 -0.750 0.38411E+04 41 carnegieite-low 9.02 5.90 -3.12 -0.446 0.53310E+04 42 carnegieite-high 10.09 5.90 -4.19 -0.599 0.71580E+04 43 carpholite-Mg 8.58 4.40 -4.18 -0.279 0.71415E+04 44 carpholite-Fe 6.71 1.75 -4.96 -0.331 0.84671E+04 45 celadonite 5.34 3.63 -1.71 -0.100 0.29140E+04 46 celadonite-Fe 3.88 0.99 -2.89 -0.170 0.49301E+04 47 chrysotile 23.89 21.51 -2.39 -0.199 0.40725E+04 49 clinochlore 39.07 38.31 -0.76 -0.024 0.12909E+04 50 daphnite 28.97 25.08 -3.88 -0.121 0.66266E+04 52 chlorite-Al-free 47.17 43.01 -4.16 -0.173 0.71002E+04 54 chloritoid-Fe 9.17 4.90 -4.28 -0.285 0.73035E+04 55 chloritoid-Mn 11.40 7.51 -3.89 -0.259 0.66358E+04 57 coesite -2.38 -3.14 -0.77 -0.255 0.13087E+04 64 cristobalite -2.56 -3.14 -0.58 -0.194 0.99403E+03 66 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71236E+04 68 diaspore 2.87 0.71 -2.16 -0.361 0.36940E+04 69 diamond -3.10 -6.84 -3.74 -1.068 0.63849E+04 70 diopside 16.18 15.94 -0.25 -0.025 0.42014E+03 71 hedenbergite 14.21 13.29 -0.92 -0.092 0.15689E+04 76 clinoenstatite 17.17 12.24 -4.92 -0.492 0.84060E+04 78 epidote 24.67 22.64 -2.03 -0.099 0.34735E+04 79 clinozoisite 22.81 18.62 -4.19 -0.190 0.71549E+04 80 epidote-Fe 29.84 26.66 -3.19 -0.165 0.54387E+04 81 fayalite 14.05 10.09 -3.95 -0.565 0.67475E+04 82 ferrosilite 11.15 6.95 -4.20 -0.420 0.71679E+04 86 gibbsite 4.08 0.71 -3.37 -0.481 0.57526E+04 87 glaucophane 22.97 20.74 -2.24 -0.060 0.38166E+04 88 glaucophane-Fe 17.28 12.80 -4.47 -0.121 0.76389E+04 89 graphite -3.55 -6.84 -3.30 -0.942 0.56271E+04 90 greenalite 16.14 13.57 -2.57 -0.214 0.43878E+04 93 hematite 12.57 9.46 -3.11 -0.376 0.53031E+04 94 heulandite -5.83 -7.62 -1.79 -0.082 0.30624E+04 98 jadeite 4.22 2.76 -1.46 -0.146 0.24872E+04 100 kalsilite 7.58 3.80 -3.79 -0.541 0.64636E+04 101 kaolinite -1.33 -4.86 -3.53 -0.321 0.60303E+04 104 laumontite 2.88 1.81 -1.08 -0.072 0.18384E+04 105 lawsonite 9.62 8.09 -1.52 -0.102 0.26028E+04 106 leucite 4.12 0.66 -3.46 -0.346 0.59129E+04 108 lizardite 23.24 21.51 -1.74 -0.145 0.29651E+04 110 magnetite 20.09 16.08 -4.01 -0.327 0.68448E+04 111 minnesotaite 10.39 7.28 -3.10 -0.183 0.52989E+04 115 manganosite 14.06 9.24 -4.82 -1.205 0.82324E+04 119 microcline -2.49 -2.49 0.00 0.000 0.17981E+00 123 muscovite 2.58 -1.07 -3.65 -0.215 0.62297E+04 124 paragonite 4.24 1.04 -3.20 -0.188 0.54687E+04 125 nepheline 8.34 5.90 -2.44 -0.348 0.41634E+04 137 phlogopite-Na 29.65 27.41 -2.24 -0.124 0.38219E+04 139 prehnite 19.37 17.91 -1.47 -0.086 0.25039E+04 140 prehnite-Fe 22.50 21.93 -0.57 -0.034 0.97755E+03 141 pumpellyite-Fe 46.27 43.14 -3.13 -0.070 0.53445E+04 142 pumpellyite-Mg 48.99 45.79 -3.21 -0.071 0.54804E+04 145 pyrite -21.25 -25.68 -4.44 -1.044 0.75758E+04 146 pyrrhotite -4.26 -7.64 -3.38 -1.128 0.57787E+04 147 pyrrhotiteFe0.875 -6.02 -8.94 -2.92 -1.075 0.49914E+04 148 pyroxmangite 7.40 6.09 -1.30 -0.261 0.22273E+04 149 pyrophyllite -6.18 -11.15 -4.97 -0.311 0.84924E+04 150 quartz -2.99 -3.14 -0.15 -0.051 0.26136E+03 154 rhodochrosite -0.98 -5.16 -4.18 -1.394 0.71389E+04 155 rhodonite 7.45 6.09 -1.35 -0.270 0.23076E+04 156 sanidine -1.28 -2.49 -1.21 -0.093 0.20679E+04 166 stilbite -7.52 -7.62 -0.10 -0.005 0.16858E+03 167 stilpnomelane-Fe 13.02 12.49 -0.53 -0.016 0.90471E+03 168 stilpnomelane-Mg 27.44 25.72 -1.73 -0.051 0.29455E+04 174 talc 16.49 15.22 -1.27 -0.075 0.21664E+04 177 tephroite 18.09 15.33 -2.75 -0.394 0.47038E+04 181 tridymite -2.63 -3.14 -0.52 -0.172 0.88133E+03 182 tremolite 47.87 47.09 -0.78 -0.021 0.13256E+04 183 ferroactinolite 38.45 33.86 -4.59 -0.124 0.78351E+04 184 troilite-low -4.41 -7.64 -3.23 -1.078 0.55215E+04 190 wairakite 3.95 1.81 -2.14 -0.126 0.36604E+04 191 walstromite 11.51 9.81 -1.70 -0.339 0.28951E+04 192 wollastonite 10.46 9.81 -0.65 -0.129 0.11055E+04 193 pseudo-wollastonite 11.00 9.81 -1.19 -0.237 0.20253E+04 194 zoisite 22.85 18.62 -4.23 -0.192 0.72290E+04 195 akaganeite 7.75 4.73 -3.02 -0.654 0.51641E+04 202 chalcedony -2.80 -3.14 -0.34 -0.113 0.58065E+03 204 montmorillonite-Ca -2.29 -6.19 -3.90 -0.241 0.66561E+04 205 montmorillonite-K -2.24 -6.27 -4.03 -0.247 0.68878E+04 206 montmorillonite-Mg -2.48 -6.80 -4.32 -0.267 0.73733E+04 207 montmorillonite-Na -2.04 -5.58 -3.54 -0.217 0.60426E+04 208 nontronite-Ca 3.21 0.30 -2.91 -0.189 0.49772E+04 209 nontronite-H 2.53 -1.84 -4.37 -0.293 0.74632E+04 210 nontronite-K 3.34 0.22 -3.12 -0.200 0.53321E+04 211 nontronite-Mg 3.07 -0.31 -3.38 -0.220 0.57785E+04 212 nontronite-Na 3.52 0.91 -2.61 -0.167 0.44529E+04 228 tobermorite 9.82 7.65 -2.17 -0.593 0.37104E+04 234 alabandite -0.98 -5.03 -4.05 -1.349 0.69124E+04 237 boehmite 4.41 0.71 -3.70 -0.616 0.63109E+04 239 ferrous-oxide 9.81 6.62 -3.19 -0.798 0.54525E+04 245 silica-amorphous -2.09 -3.14 -1.05 -0.350 0.17948E+04 247 an20ab80 2.02 1.31 -0.71 -0.054 0.12064E+04 248 an25ab75 2.65 1.74 -0.91 -0.070 0.15549E+04 249 an30ab70 3.28 2.16 -1.12 -0.086 0.19131E+04 250 tr.625ac.25prg.125 45.16 44.72 -0.44 -0.012 0.75731E+03 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 0.0001000 MOLES Current total amount of reactant added: 0.0020900 MOLES New total amount of reactant added: 0.0021900 MOLES Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.5508E-08 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 7 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 0.0021900 Water: Moles liquid = 0.4985E+02 kg liquid = 0.8981E+00 Moles total = 0.4985E+02 kg total = 0.8980E+00 Activity = 1.0000 Stoichiometric ionic strength = .1147000E-01 Osmotic coef. = 0.9632 True ionic strength = .2014551E-01 Chg. balance for total moles = -.5508E-08 Max. difference allowed = 0.1508E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.91801E-10 -10.0372 0.77106E-10 -10.1129 0.83992E+00 -0.0758 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.16715E-03 -3.7769 0.13955E-03 -3.8553 0.83485E+00 -0.0784 4 SO4-- 0.16840E-08 -8.7736 0.87309E-09 -9.0589 0.51845E+00 -0.2853 5 HCO3- 0.65818E-04 -4.1817 0.55029E-04 -4.2594 0.83608E+00 -0.0778 6 HS- 0.87635E-04 -4.0573 0.73173E-04 -4.1357 0.83497E+00 -0.0783 7 Al+++ 0.10188E-28 -28.9919 0.23449E-29 -29.6299 0.23016E+00 -0.6380 8 H4SiO4 0.72149E-03 -3.1418 0.72149E-03 -3.1418 0.10000E+01 0.0000 9 Ca++ 0.10317E-06 -6.9864 0.53095E-07 -7.2749 0.51463E+00 -0.2885 10 Mg++ 0.21248E-10 -10.6727 0.10884E-10 -10.9632 0.51226E+00 -0.2905 11 Fe++ 0.48073E-13 -13.3181 0.24653E-13 -13.6081 0.51283E+00 -0.2900 12 K+ 0.15653E-03 -3.8054 0.13090E-03 -3.8831 0.83628E+00 -0.0777 13 Na+ 0.19868E-01 -1.7018 0.16584E-01 -1.7803 0.83470E+00 -0.0785 14 Mn++ 0.19975E-10 -10.6995 0.10252E-10 -10.9892 0.51325E+00 -0.2897 15 F- 0.10832E-05 -5.9653 0.90247E-06 -6.0446 0.83312E+00 -0.0793 16 HPO4-- 0.45350E-07 -7.3434 0.23515E-07 -7.6287 0.51853E+00 -0.2852 18 HSiO3- 0.10465E-01 -1.9802 0.87371E-02 -2.0586 0.83485E+00 -0.0784 19 Ca(HSiO3)+ 0.12630E-07 -7.8986 0.10565E-07 -7.9761 0.83646E+00 -0.0776 20 Mg(HSiO3)+ 0.32223E-11 -11.4918 0.26953E-11 -11.5694 0.83646E+00 -0.0776 21 NaHSiO3,aq 0.23435E-02 -2.6301 0.23435E-02 -2.6301 0.10000E+01 0.0000 22 AlO+ 0.64147E-16 -16.1928 0.53656E-16 -16.2704 0.83646E+00 -0.0776 24 HAlO2,aq 0.13858E-09 -9.8583 0.13858E-09 -9.8583 0.10000E+01 0.0000 25 AlO2- 0.47741E-05 -5.3211 0.39784E-05 -5.4003 0.83333E+00 -0.0792 26 CH4,aq 0.44956E-05 -5.3472 0.44799E-05 -5.3487 0.99650E+00 -0.0015 27 C2H6,aq 0.15736E-14 -14.8031 0.15681E-14 -14.8046 0.99650E+00 -0.0015 31 CO,aq 0.49831E-15 -15.3025 0.49831E-15 -15.3025 0.10000E+01 0.0000 32 CO2,aq 0.90982E-08 -8.0410 0.90664E-08 -8.0426 0.99650E+00 -0.0015 33 CO3-2 0.12049E-03 -3.9190 0.62336E-04 -4.2053 0.51735E+00 -0.2862 34 CaCO3,aq 0.41501E-07 -7.3819 0.41501E-07 -7.3819 0.10000E+01 0.0000 35 Ca(HCO3)+ 0.89163E-10 -10.0498 0.74581E-10 -10.1274 0.83646E+00 -0.0776 36 CaCl+ 0.14335E-10 -10.8436 0.11990E-10 -10.9212 0.83646E+00 -0.0776 37 CaCl2,aq 0.39751E-15 -15.4006 0.39751E-15 -15.4006 0.10000E+01 0.0000 38 CaF+ 0.83637E-12 -12.0776 0.69959E-12 -12.1552 0.83646E+00 -0.0776 39 CaOH+ 0.58671E-07 -7.2316 0.49076E-07 -7.3091 0.83646E+00 -0.0776 40 CaSO4,aq 0.14720E-13 -13.8321 0.14720E-13 -13.8321 0.10000E+01 0.0000 41 HCl,aq 0.19717E-14 -14.7052 0.19717E-14 -14.7052 0.10000E+01 0.0000 45 HF,aq 0.47637E-12 -12.3221 0.47637E-12 -12.3221 0.10000E+01 0.0000 46 HF2- 0.17386E-18 -18.7598 0.14515E-18 -18.8382 0.83485E+00 -0.0784 48 FeCl+ 0.65099E-17 -17.1864 0.54453E-17 -17.2640 0.83646E+00 -0.0776 51 FeF+ 0.13592E-17 -17.8667 0.11369E-17 -17.9443 0.83646E+00 -0.0776 53 FeO,aq 0.16116E-09 -9.7927 0.16116E-09 -9.7927 0.10000E+01 0.0000 54 FeOH+ 0.12442E-10 -10.9051 0.10407E-10 -10.9827 0.83646E+00 -0.0776 55 HFeO2- 0.26195E-07 -7.5818 0.21869E-07 -7.6602 0.83485E+00 -0.0784 56 FeO+ 0.20064E-16 -16.6976 0.16782E-16 -16.7751 0.83646E+00 -0.0776 58 FeO2- 0.69186E-09 -9.1600 0.57760E-09 -9.2384 0.83485E+00 -0.0784 59 HFeO2,aq 0.56643E-11 -11.2469 0.56643E-11 -11.2469 0.10000E+01 0.0000 60 H2,aq 0.21956E-05 -5.6584 0.21879E-05 -5.6600 0.99650E+00 -0.0015 61 KCl,aq 0.33107E-09 -9.4801 0.33107E-09 -9.4801 0.10000E+01 0.0000 63 KOH,aq 0.72501E-06 -6.1397 0.72501E-06 -6.1397 0.10000E+01 0.0000 64 KSO4- 0.21243E-11 -11.6728 0.17735E-11 -11.7512 0.83485E+00 -0.0784 65 MgCO3,aq 0.21325E-11 -11.6711 0.21325E-11 -11.6711 0.10000E+01 0.0000 66 Mg(HCO3)+ 0.18677E-13 -13.7287 0.15622E-13 -13.8063 0.83646E+00 -0.0776 67 MgCl+ 0.26634E-14 -14.5746 0.22278E-14 -14.6521 0.83646E+00 -0.0776 68 MgF+ 0.63512E-15 -15.1971 0.53125E-15 -15.2747 0.83646E+00 -0.0776 69 MgOH+ 0.66554E-10 -10.1768 0.55670E-10 -10.2544 0.83646E+00 -0.0776 71 MnF+ 0.18632E-15 -15.7297 0.15585E-15 -15.8073 0.83646E+00 -0.0776 72 MnO,aq 0.17858E-08 -8.7482 0.17858E-08 -8.7482 0.10000E+01 0.0000 73 MnOH+ 0.48068E-09 -9.3181 0.40207E-09 -9.3957 0.83646E+00 -0.0776 74 MnO2-2 0.19269E-10 -10.7152 0.99685E-11 -11.0014 0.51735E+00 -0.2862 75 HMnO2- 0.20171E-09 -9.6953 0.16840E-09 -9.7737 0.83485E+00 -0.0784 78 MnCl+ 0.10532E-13 -13.9775 0.88100E-14 -14.0550 0.83646E+00 -0.0776 79 MnSO4,aq 0.25842E-17 -17.5877 0.25842E-17 -17.5877 0.10000E+01 0.0000 80 NaCl,aq 0.76693E-06 -6.1152 0.76693E-06 -6.1152 0.10000E+01 0.0000 81 NaF,aq 0.35039E-08 -8.4554 0.35039E-08 -8.4554 0.10000E+01 0.0000 82 NaOH,aq 0.92408E-04 -4.0343 0.92408E-04 -4.0343 0.10000E+01 0.0000 84 OH- 0.89918E-02 -2.0462 0.74932E-02 -2.1253 0.83333E+00 -0.0792 89 HPO3-2 0.30991E-15 -15.5088 0.16033E-15 -15.7950 0.51735E+00 -0.2862 91 H2PO3- 0.29695E-19 -19.5273 0.24791E-19 -19.6057 0.83485E+00 -0.0784 92 H3PO4,aq 0.97779E-18 -18.0098 0.97779E-18 -18.0098 0.10000E+01 0.0000 93 H2PO4- 0.40026E-10 -10.3977 0.33448E-10 -10.4756 0.83564E+00 -0.0780 94 PO4-3 0.10291E-08 -8.9876 0.24882E-09 -9.6041 0.24179E+00 -0.6166 98 HP2O7-3 0.98599E-18 -18.0061 0.22716E-18 -18.6437 0.23039E+00 -0.6375 99 P2O7-4 0.91880E-17 -17.0368 0.70382E-18 -18.1525 0.76602E-01 -1.1158 100 H2S,aq 0.17499E-07 -7.7570 0.17437E-07 -7.7585 0.99650E+00 -0.0015 101 S2-2 0.10481E-12 -12.9796 0.54225E-13 -13.2658 0.51735E+00 -0.2862 107 SO3-2 0.47295E-15 -15.3252 0.24824E-15 -15.6051 0.52487E+00 -0.2800 108 HSO3- 0.14355E-17 -17.8430 0.11984E-17 -17.9214 0.83485E+00 -0.0784 109 HSO4- 0.77487E-16 -16.1108 0.64878E-16 -16.1879 0.83727E+00 -0.0771 111 S2O3-2 0.34569E-18 -18.4613 0.17884E-18 -18.7475 0.51735E+00 -0.2862 Charge balance for all species = -.6133E-08 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.9180137E-10 -.2203419E-01 -.2217038E+02 0.0000 2 H2O 0.1000000E+01 0.5550454E+02 0.9981856E+06 0.0000 3 Cl- 0.1671500E-03 0.1679173E-03 0.5942779E+01 6.2576 4 SO4-- 0.1684033E-08 -.5042739E-05 -.4835681E+00 11.1669 5 HCO3- 0.6581769E-04 0.1908568E-03 0.1162522E+02 5.8535 6 HS- 0.8763491E-04 0.9269683E-04 0.3060319E+01 5.9773 7 Al+++ 0.1018804E-28 0.4774242E-05 0.1285914E+00 0.7089 8 H4SiO4 0.7214869E-03 0.1353040E-01 0.1298210E+04 -3.1418 9 Ca++ 0.1031720E-06 0.2160787E-06 0.8644885E-02 12.9509 10 Mg++ 0.2124780E-10 0.9317893E-10 0.2261412E-05 9.2626 11 Fe++ 0.4807281E-13 0.2706621E-07 0.1508928E-02 6.6177 12 K+ 0.1565295E-03 0.1572549E-03 0.6138247E+01 6.2299 13 Na+ 0.1986805E-01 0.2230468E-01 0.5118851E+03 8.3326 14 Mn++ 0.1997533E-10 0.2507469E-08 0.1375149E-03 9.2366 15 F- 0.1083243E-05 0.1086748E-05 0.2061000E-01 4.0683 16 HPO4-- 0.4534951E-07 0.4641860E-07 0.4447435E-02 12.5972 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.1979073E-01 -.1978874E-01 -.1993084E-05 0.0000000E+00 2 H2O 0.4984820E+02 0.4984820E+02 -.1950446E-05 0.0000000E+00 3 Cl- 0.1508052E-03 0.1508052E-03 0.0000000E+00 0.0000000E+00 4 SO4-- -.4527810E-05 -.4528846E-05 0.1035540E-08 0.0000000E+00 5 HCO3- 0.1714070E-03 0.1714070E-03 0.0000000E+00 0.0000000E+00 6 HS- 0.8324928E-04 0.8325032E-04 -.1035540E-08 0.0000000E+00 7 Al+++ 0.4775352E-05 0.4287710E-05 0.4876416E-06 0.0000000E+00 8 H4SiO4 0.1215302E-01 0.1215155E-01 0.1473753E-05 0.0000000E+00 9 Ca++ 0.2080835E-06 0.1940586E-06 0.1402491E-07 0.0000000E+00 10 Mg++ 0.8368328E-10 0.8368328E-10 0.0000000E+00 0.0000000E+00 11 Fe++ 0.3259227E-07 0.2430795E-07 0.8284319E-08 0.0000000E+00 12 K+ 0.1412294E-03 0.1412294E-03 0.0000000E+00 0.0000000E+00 13 Na+ 0.2003215E-01 0.2003166E-01 0.4865759E-06 0.0000000E+00 14 Mn++ 0.2251939E-08 0.2251939E-08 0.0000000E+00 0.0000000E+00 15 F- 0.9760000E-06 0.9760000E-06 0.0000000E+00 0.0000000E+00 16 HPO4-- 0.4168819E-07 0.4168819E-07 0.0000000E+00 0.0000000E+00 Chg. balance for solid moles: -.2118E-21 Mass of aqueous solution: 0.899663E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 0.0021900 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 0.4866E-06 -6.313 0.1276E-03 -3.894 98.20 0.4898E-04 andradite 0.4142E-08 -8.383 0.2105E-05 -5.677 1.620 0.5469E-06 grossular 0.5328E-09 -9.273 0.2400E-06 -6.620 0.1847 0.6678E-07 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8860E+00 0.8860E+00 1.0000 -0.053 grossular 0.1140E+00 0.1140E+00 1.0000 -0.943 Solid products produced: Mass = 0.000130 g Volume = 0.000050 cm3 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.0021900 moles log = -2.6596 Original solution: 1000.0103000 g Original solution / Rock added: 456625.71 (Water/Rock Ratio), log = 5.6596 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0298 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9909E+00 0.9858 0.1006E+01 0.1020E+01 CO2,gas 0.9354E-06 1.0070 0.9700E-06 0.9632E-06 CH4,gas 0.6324E-02 1.0125 0.6594E-02 0.6513E-02 H2,gas 0.2788E-02 1.0005 0.2872E-02 0.2871E-02 H2S,gas 0.4673E-06 0.9960 0.4793E-06 0.4813E-06 S2,gas 0.1015E-26 1.0000 0.1045E-26 0.1045E-26 CO,gas 0.7211E-12 1.0000 0.7426E-12 0.7426E-12 SO3,gas 0.1906E-44 1.0000 0.1963E-44 0.1963E-44 SO2,gas 0.2130E-24 1.0000 0.2193E-24 0.2193E-24 HF,gas 0.1136E-14 1.0000 0.1170E-14 0.1170E-14 HCl,gas 0.3378E-17 1.0000 0.3479E-17 0.3479E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 17 albite -0.38 -0.38 0.00 0.000 0.11184E-10 23 andradite 39.01 39.01 0.00 0.000 -0.12132E-10 24 grossular 32.73 32.73 0.00 0.000 -0.24265E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -14.37 -7.71 -2.571 0.13168E+05 -6.013 3 CH4,gas 4.54 0.66 -3.88 -0.970 0.66247E+04 -2.181 4 H2,gas 8.00 3.76 -4.24 -2.423 0.72409E+04 -2.542 5 H2S,gas -6.23 -14.25 -8.02 -4.009 0.13691E+05 -6.319 6 S2,gas -7.34 -36.02 -28.68 -4.412 0.48970E+05 -26.981 7 CO,gas 3.21 -10.61 -13.83 -4.255 0.23611E+05 -12.129 8 SO3,gas 17.12 -29.28 -46.41 -11.602 0.79237E+05 -44.707 9 SO2,gas 0.83 -25.53 -26.36 -7.029 0.45005E+05 -24.659 10 HF,gas 0.47 -16.16 -16.63 -8.315 0.28397E+05 -14.932 11 HCl,gas 5.19 -13.97 -19.16 -9.579 0.32711E+05 -17.459 12 acmite 7.71 6.79 -0.92 -0.096 0.15751E+04 16 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 20 spessartine 24.46 19.70 -4.76 -0.238 0.81190E+04 21 analcite 3.32 2.76 -0.56 -0.063 0.96294E+03 27 annite 20.12 17.37 -2.76 -0.153 0.47074E+04 28 phlogopite 27.06 25.30 -1.76 -0.098 0.30108E+04 30 anorthite 12.71 8.09 -4.63 -0.356 0.78975E+04 33 apatite-OH -18.15 -18.81 -0.66 -0.050 0.11194E+04 34 apatite-F -34.30 -34.97 -0.67 -0.055 0.11364E+04 38 aragonite 0.97 -1.42 -2.39 -0.796 0.40774E+04 39 brucite 12.57 9.26 -3.31 -0.661 0.56448E+04 40 calcite 0.81 -1.42 -2.23 -0.744 0.38132E+04 41 carnegieite-low 9.02 5.90 -3.12 -0.446 0.53335E+04 42 carnegieite-high 10.09 5.90 -4.19 -0.599 0.71605E+04 43 carpholite-Mg 8.58 4.40 -4.19 -0.279 0.71463E+04 44 carpholite-Fe 6.71 1.75 -4.96 -0.331 0.84704E+04 45 celadonite 5.34 3.63 -1.71 -0.100 0.29153E+04 46 celadonite-Fe 3.88 0.99 -2.89 -0.170 0.49298E+04 47 chrysotile 23.89 21.50 -2.39 -0.199 0.40775E+04 49 clinochlore 39.07 38.31 -0.76 -0.024 0.13045E+04 50 daphnite 28.97 25.08 -3.88 -0.121 0.66325E+04 52 chlorite-Al-free 47.17 43.01 -4.16 -0.174 0.71102E+04 54 chloritoid-Fe 9.17 4.89 -4.28 -0.285 0.73080E+04 55 chloritoid-Mn 11.40 7.51 -3.89 -0.259 0.66395E+04 57 coesite -2.38 -3.14 -0.77 -0.255 0.13074E+04 64 cristobalite -2.56 -3.14 -0.58 -0.194 0.99278E+03 66 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71236E+04 68 diaspore 2.87 0.71 -2.16 -0.361 0.36964E+04 69 diamond -3.10 -6.85 -3.75 -1.072 0.64062E+04 70 diopside 16.18 15.93 -0.25 -0.025 0.42925E+03 71 hedenbergite 14.21 13.29 -0.92 -0.092 0.15764E+04 76 clinoenstatite 17.17 12.24 -4.92 -0.492 0.84086E+04 78 epidote 24.67 22.63 -2.04 -0.099 0.34792E+04 79 clinozoisite 22.81 18.60 -4.20 -0.191 0.71766E+04 80 epidote-Fe 29.84 26.66 -3.18 -0.165 0.54284E+04 81 fayalite 14.05 10.09 -3.95 -0.565 0.67481E+04 82 ferrosilite 11.15 6.95 -4.20 -0.420 0.71673E+04 86 gibbsite 4.08 0.71 -3.37 -0.481 0.57550E+04 87 glaucophane 22.97 20.74 -2.24 -0.060 0.38217E+04 88 glaucophane-Fe 17.28 12.80 -4.47 -0.121 0.76393E+04 89 graphite -3.55 -6.85 -3.31 -0.945 0.56484E+04 90 greenalite 16.14 13.57 -2.57 -0.214 0.43882E+04 93 hematite 12.57 9.48 -3.09 -0.375 0.52758E+04 94 heulandite -5.83 -7.62 -1.80 -0.082 0.30676E+04 98 jadeite 4.22 2.76 -1.46 -0.146 0.24884E+04 100 kalsilite 7.58 3.80 -3.79 -0.541 0.64661E+04 101 kaolinite -1.33 -4.87 -3.53 -0.321 0.60326E+04 104 laumontite 2.88 1.80 -1.08 -0.072 0.18473E+04 105 lawsonite 9.62 8.09 -1.53 -0.102 0.26142E+04 106 leucite 4.12 0.66 -3.46 -0.346 0.59142E+04 108 lizardite 23.24 21.50 -1.74 -0.145 0.29702E+04 110 magnetite 20.09 16.09 -3.99 -0.326 0.68186E+04 111 minnesotaite 10.39 7.29 -3.10 -0.182 0.52968E+04 115 manganosite 14.06 9.24 -4.82 -1.205 0.82325E+04 119 microcline -2.49 -2.49 0.00 0.000 0.18863E+00 123 muscovite 2.58 -1.07 -3.65 -0.215 0.62345E+04 124 paragonite 4.24 1.03 -3.21 -0.189 0.54735E+04 125 nepheline 8.34 5.90 -2.44 -0.349 0.41659E+04 137 phlogopite-Na 29.65 27.40 -2.24 -0.125 0.38294E+04 139 prehnite 19.37 17.89 -1.48 -0.087 0.25232E+04 140 prehnite-Fe 22.50 21.92 -0.57 -0.035 0.98078E+03 141 pumpellyite-Fe 46.27 43.11 -3.15 -0.070 0.53864E+04 142 pumpellyite-Mg 48.99 45.76 -3.24 -0.072 0.55239E+04 145 pyrite -21.25 -25.64 -4.39 -1.033 0.74985E+04 146 pyrrhotite -4.26 -7.63 -3.37 -1.124 0.57551E+04 147 pyrrhotiteFe0.875 -6.02 -8.92 -2.91 -1.069 0.49641E+04 148 pyroxmangite 7.40 6.09 -1.30 -0.261 0.22262E+04 149 pyrophyllite -6.18 -11.15 -4.97 -0.311 0.84923E+04 150 quartz -2.99 -3.14 -0.15 -0.051 0.26011E+03 154 rhodochrosite -0.98 -5.14 -4.16 -1.386 0.71020E+04 155 rhodonite 7.45 6.09 -1.35 -0.270 0.23065E+04 156 sanidine -1.28 -2.49 -1.21 -0.093 0.20679E+04 166 stilbite -7.52 -7.62 -0.10 -0.005 0.17376E+03 167 stilpnomelane-Fe 13.02 12.49 -0.53 -0.016 0.90505E+03 168 stilpnomelane-Mg 27.44 25.71 -1.73 -0.052 0.29536E+04 174 talc 16.49 15.22 -1.27 -0.075 0.21690E+04 177 tephroite 18.09 15.33 -2.75 -0.393 0.47028E+04 181 tridymite -2.63 -3.14 -0.52 -0.172 0.88009E+03 182 tremolite 47.87 47.08 -0.79 -0.021 0.13464E+04 183 ferroactinolite 38.45 33.86 -4.60 -0.124 0.78481E+04 184 troilite-low -4.41 -7.63 -3.22 -1.073 0.54979E+04 190 wairakite 3.95 1.80 -2.15 -0.126 0.36693E+04 191 walstromite 11.51 9.81 -1.70 -0.340 0.29029E+04 192 wollastonite 10.46 9.81 -0.65 -0.130 0.11133E+04 193 pseudo-wollastonite 11.00 9.81 -1.19 -0.238 0.20332E+04 194 zoisite 22.85 18.60 -4.25 -0.193 0.72506E+04 195 akaganeite 7.75 4.74 -3.02 -0.652 0.51505E+04 202 chalcedony -2.80 -3.14 -0.34 -0.113 0.57941E+03 204 montmorillonite-Ca -2.29 -6.19 -3.90 -0.241 0.66575E+04 205 montmorillonite-K -2.24 -6.27 -4.03 -0.247 0.68881E+04 206 montmorillonite-Mg -2.48 -6.80 -4.32 -0.267 0.73736E+04 207 montmorillonite-Na -2.04 -5.58 -3.54 -0.217 0.60429E+04 208 nontronite-Ca 3.21 0.32 -2.90 -0.188 0.49477E+04 209 nontronite-H 2.53 -1.82 -4.35 -0.292 0.74322E+04 210 nontronite-K 3.34 0.24 -3.10 -0.199 0.53015E+04 211 nontronite-Mg 3.07 -0.29 -3.37 -0.218 0.57479E+04 212 nontronite-Na 3.52 0.93 -2.59 -0.166 0.44223E+04 228 tobermorite 9.82 7.65 -2.18 -0.594 0.37167E+04 234 alabandite -0.98 -5.01 -4.03 -1.345 0.68880E+04 237 boehmite 4.41 0.71 -3.70 -0.616 0.63133E+04 239 ferrous-oxide 9.81 6.62 -3.19 -0.798 0.54535E+04 245 silica-amorphous -2.09 -3.14 -1.05 -0.350 0.17936E+04 247 an20ab80 2.02 1.31 -0.71 -0.054 0.12087E+04 248 an25ab75 2.65 1.73 -0.91 -0.070 0.15578E+04 249 an30ab70 3.28 2.16 -1.12 -0.086 0.19165E+04 250 tr.625ac.25prg.125 45.16 44.71 -0.46 -0.012 0.77722E+03 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 0.0001000 MOLES Current total amount of reactant added: 0.0021900 MOLES New total amount of reactant added: 0.0022900 MOLES Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.5508E-08 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 7 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 0.0022900 Water: Moles liquid = 0.4985E+02 kg liquid = 0.8981E+00 Moles total = 0.4985E+02 kg total = 0.8980E+00 Activity = 1.0000 Stoichiometric ionic strength = .1147638E-01 Osmotic coef. = 0.9630 True ionic strength = .2015133E-01 Chg. balance for total moles = -.5508E-08 Max. difference allowed = 0.1514E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.91968E-10 -10.0364 0.77245E-10 -10.1121 0.83991E+00 -0.0758 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.16780E-03 -3.7752 0.14009E-03 -3.8536 0.83483E+00 -0.0784 4 SO4-- 0.20498E-08 -8.6883 0.10627E-08 -8.9736 0.51841E+00 -0.2853 5 HCO3- 0.68918E-04 -4.1617 0.57620E-04 -4.2394 0.83606E+00 -0.0778 6 HS- 0.90340E-04 -4.0441 0.75430E-04 -4.1225 0.83496E+00 -0.0783 7 Al+++ 0.10212E-28 -28.9909 0.23499E-29 -29.6289 0.23012E+00 -0.6380 8 H4SiO4 0.72270E-03 -3.1410 0.72270E-03 -3.1410 0.10000E+01 0.0000 9 Ca++ 0.10227E-06 -6.9902 0.52629E-07 -7.2788 0.51459E+00 -0.2885 10 Mg++ 0.21254E-10 -10.6726 0.10887E-10 -10.9631 0.51222E+00 -0.2905 11 Fe++ 0.48133E-13 -13.3176 0.24682E-13 -13.6076 0.51279E+00 -0.2901 12 K+ 0.15653E-03 -3.8054 0.13090E-03 -3.8831 0.83626E+00 -0.0777 13 Na+ 0.19868E-01 -1.7018 0.16584E-01 -1.7803 0.83468E+00 -0.0785 14 Mn++ 0.20045E-10 -10.6980 0.10287E-10 -10.9877 0.51321E+00 -0.2897 15 F- 0.11276E-05 -5.9478 0.93944E-06 -6.0271 0.83310E+00 -0.0793 16 HPO4-- 0.45351E-07 -7.3434 0.23514E-07 -7.6287 0.51849E+00 -0.2853 18 HSiO3- 0.10464E-01 -1.9803 0.87360E-02 -2.0587 0.83483E+00 -0.0784 19 Ca(HSiO3)+ 0.12518E-07 -7.9025 0.10471E-07 -7.9800 0.83644E+00 -0.0776 20 Mg(HSiO3)+ 0.32226E-11 -11.4918 0.26955E-11 -11.5694 0.83644E+00 -0.0776 21 NaHSiO3,aq 0.23432E-02 -2.6302 0.23432E-02 -2.6302 0.10000E+01 0.0000 22 AlO+ 0.64055E-16 -16.1934 0.53578E-16 -16.2710 0.83644E+00 -0.0776 24 HAlO2,aq 0.13813E-09 -9.8597 0.13813E-09 -9.8597 0.10000E+01 0.0000 25 AlO2- 0.47502E-05 -5.3233 0.39584E-05 -5.4025 0.83332E+00 -0.0792 26 CH4,aq 0.39869E-05 -5.3994 0.39729E-05 -5.4009 0.99650E+00 -0.0015 27 C2H6,aq 0.12907E-14 -14.8892 0.12862E-14 -14.8907 0.99650E+00 -0.0015 31 CO,aq 0.50123E-15 -15.3000 0.50123E-15 -15.3000 0.10000E+01 0.0000 32 CO2,aq 0.95438E-08 -8.0203 0.95104E-08 -8.0218 0.99650E+00 -0.0015 33 CO3-2 0.12595E-03 -3.8998 0.65154E-04 -4.1861 0.51731E+00 -0.2863 34 CaCO3,aq 0.42996E-07 -7.3666 0.42996E-07 -7.3666 0.10000E+01 0.0000 35 Ca(HCO3)+ 0.92544E-10 -10.0337 0.77407E-10 -10.1112 0.83644E+00 -0.0776 36 CaCl+ 0.14264E-10 -10.8457 0.11931E-10 -10.9233 0.83644E+00 -0.0776 37 CaCl2,aq 0.39710E-15 -15.4011 0.39710E-15 -15.4011 0.10000E+01 0.0000 38 CaF+ 0.86301E-12 -12.0640 0.72186E-12 -12.1415 0.83644E+00 -0.0776 39 CaOH+ 0.58053E-07 -7.2362 0.48558E-07 -7.3137 0.83644E+00 -0.0776 40 CaSO4,aq 0.17759E-13 -13.7506 0.17759E-13 -13.7506 0.10000E+01 0.0000 41 HCl,aq 0.19829E-14 -14.7027 0.19829E-14 -14.7027 0.10000E+01 0.0000 45 HF,aq 0.49677E-12 -12.3038 0.49677E-12 -12.3038 0.10000E+01 0.0000 46 HF2- 0.18874E-18 -18.7241 0.15757E-18 -18.8025 0.83483E+00 -0.0784 48 FeCl+ 0.65430E-17 -17.1842 0.54728E-17 -17.2618 0.83644E+00 -0.0776 51 FeF+ 0.14166E-17 -17.8488 0.11849E-17 -17.9263 0.83644E+00 -0.0776 53 FeO,aq 0.16077E-09 -9.7938 0.16077E-09 -9.7938 0.10000E+01 0.0000 54 FeOH+ 0.12435E-10 -10.9054 0.10401E-10 -10.9829 0.83644E+00 -0.0776 55 HFeO2- 0.26085E-07 -7.5836 0.21777E-07 -7.6620 0.83483E+00 -0.0784 56 FeO+ 0.20477E-16 -16.6887 0.17127E-16 -16.7663 0.83644E+00 -0.0776 58 FeO2- 0.70356E-09 -9.1527 0.58735E-09 -9.2311 0.83483E+00 -0.0784 59 HFeO2,aq 0.57704E-11 -11.2388 0.57704E-11 -11.2388 0.10000E+01 0.0000 60 H2,aq 0.21054E-05 -5.6767 0.20980E-05 -5.6782 0.99650E+00 -0.0015 61 KCl,aq 0.33235E-09 -9.4784 0.33235E-09 -9.4784 0.10000E+01 0.0000 63 KOH,aq 0.72369E-06 -6.1404 0.72369E-06 -6.1404 0.10000E+01 0.0000 64 KSO4- 0.25856E-11 -11.5874 0.21585E-11 -11.6658 0.83483E+00 -0.0784 65 MgCO3,aq 0.22294E-11 -11.6518 0.22294E-11 -11.6518 0.10000E+01 0.0000 66 Mg(HCO3)+ 0.19561E-13 -13.7086 0.16362E-13 -13.7862 0.83644E+00 -0.0776 67 MgCl+ 0.26744E-14 -14.5728 0.22369E-14 -14.6503 0.83644E+00 -0.0776 68 MgF+ 0.66129E-15 -15.1796 0.55313E-15 -15.2572 0.83644E+00 -0.0776 69 MgOH+ 0.66450E-10 -10.1775 0.55581E-10 -10.2551 0.83644E+00 -0.0776 71 MnF+ 0.19461E-15 -15.7108 0.16278E-15 -15.7884 0.83644E+00 -0.0776 72 MnO,aq 0.17855E-08 -8.7483 0.17855E-08 -8.7483 0.10000E+01 0.0000 73 MnOH+ 0.48146E-09 -9.3174 0.40271E-09 -9.3950 0.83644E+00 -0.0776 74 MnO2-2 0.19197E-10 -10.7168 0.99306E-11 -11.0030 0.51731E+00 -0.2863 75 HMnO2- 0.20131E-09 -9.6961 0.16806E-09 -9.7745 0.83483E+00 -0.0784 78 MnCl+ 0.10610E-13 -13.9743 0.88743E-14 -14.0519 0.83644E+00 -0.0776 79 MnSO4,aq 0.31559E-17 -17.5009 0.31559E-17 -17.5009 0.10000E+01 0.0000 80 NaCl,aq 0.76991E-06 -6.1136 0.76991E-06 -6.1136 0.10000E+01 0.0000 81 NaF,aq 0.36474E-08 -8.4380 0.36474E-08 -8.4380 0.10000E+01 0.0000 82 NaOH,aq 0.92241E-04 -4.0351 0.92241E-04 -4.0351 0.10000E+01 0.0000 84 OH- 0.89759E-02 -2.0469 0.74797E-02 -2.1261 0.83332E+00 -0.0792 89 HPO3-2 0.29718E-15 -15.5270 0.15374E-15 -15.8132 0.51731E+00 -0.2863 91 H2PO3- 0.28525E-19 -19.5448 0.23813E-19 -19.6232 0.83483E+00 -0.0784 92 H3PO4,aq 0.98127E-18 -18.0082 0.98127E-18 -18.0082 0.10000E+01 0.0000 93 H2PO4- 0.40097E-10 -10.3969 0.33506E-10 -10.4749 0.83563E+00 -0.0780 94 PO4-3 0.10273E-08 -8.9883 0.24836E-09 -9.6049 0.24175E+00 -0.6166 98 HP2O7-3 0.98786E-18 -18.0053 0.22755E-18 -18.6429 0.23035E+00 -0.6376 99 P2O7-4 0.91900E-17 -17.0367 0.70376E-18 -18.1526 0.76579E-01 -1.1159 100 H2S,aq 0.18071E-07 -7.7430 0.18008E-07 -7.7445 0.99650E+00 -0.0015 101 S2-2 0.11616E-12 -12.9349 0.60091E-13 -13.2212 0.51731E+00 -0.2863 107 SO3-2 0.55202E-15 -15.2580 0.28971E-15 -15.5380 0.52483E+00 -0.2800 108 HSO3- 0.16784E-17 -17.7751 0.14012E-17 -17.8535 0.83483E+00 -0.0784 109 HSO4- 0.94483E-16 -16.0246 0.79107E-16 -16.1018 0.83726E+00 -0.0771 111 S2O3-2 0.43453E-18 -18.3620 0.22479E-18 -18.6482 0.51731E+00 -0.2863 Charge balance for all species = -.6133E-08 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.9196830E-10 -.2202206E-01 -.2215817E+02 0.0000 2 H2O 0.1000000E+01 0.5550453E+02 0.9981850E+06 0.0000 3 Cl- 0.1678036E-03 0.1685739E-03 0.5966016E+01 6.2585 4 SO4-- 0.2049824E-08 -.4511061E-05 -.4325832E+00 11.2507 5 HCO3- 0.6891812E-04 0.1989068E-03 0.1211555E+02 5.8727 6 HS- 0.9033953E-04 0.9487072E-04 0.3132087E+01 5.9897 7 Al+++ 0.1021177E-28 0.4750321E-05 0.1279470E+00 0.7074 8 H4SiO4 0.7227008E-03 0.1353030E-01 0.1298200E+04 -3.1410 9 Ca++ 0.1022747E-06 0.2159499E-06 0.8639732E-02 12.9455 10 Mg++ 0.2125392E-10 0.9317875E-10 0.2261407E-05 9.2612 11 Fe++ 0.4813252E-13 0.2696745E-07 0.1503422E-02 6.6166 12 K+ 0.1565305E-03 0.1572546E-03 0.6138233E+01 6.2291 13 Na+ 0.1986842E-01 0.2230461E-01 0.5118834E+03 8.3318 14 Mn++ 0.2004468E-10 0.2507465E-08 0.1375146E-03 9.2366 15 F- 0.1127636E-05 0.1131285E-05 0.2145462E-01 4.0850 16 HPO4-- 0.4535108E-07 0.4641851E-07 0.4447424E-02 12.5956 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.1977996E-01 -.1977788E-01 -.2079392E-05 0.0000000E+00 2 H2O 0.4984828E+02 0.4984829E+02 -.2036438E-05 0.0000000E+00 3 Cl- 0.1513952E-03 0.1513952E-03 0.0000000E+00 0.0000000E+00 4 SO4-- -.4050310E-05 -.4051357E-05 0.1046620E-08 0.0000000E+00 5 HCO3- 0.1786370E-03 0.1786370E-03 0.0000000E+00 0.0000000E+00 6 HS- 0.8520178E-04 0.8520283E-04 -.1046620E-08 0.0000000E+00 7 Al+++ 0.4775352E-05 0.4266235E-05 0.5091166E-06 0.0000000E+00 8 H4SiO4 0.1215302E-01 0.1215148E-01 0.1538329E-05 0.0000000E+00 9 Ca++ 0.2080835E-06 0.1939434E-06 0.1414015E-07 0.0000000E+00 10 Mg++ 0.8368328E-10 0.8368328E-10 0.0000000E+00 0.0000000E+00 11 Fe++ 0.3259227E-07 0.2421931E-07 0.8372962E-08 0.0000000E+00 12 K+ 0.1412294E-03 0.1412294E-03 0.0000000E+00 0.0000000E+00 13 Na+ 0.2003215E-01 0.2003164E-01 0.5080628E-06 0.0000000E+00 14 Mn++ 0.2251939E-08 0.2251939E-08 0.0000000E+00 0.0000000E+00 15 F- 0.1016000E-05 0.1016000E-05 0.0000000E+00 0.0000000E+00 16 HPO4-- 0.4168819E-07 0.4168819E-07 0.0000000E+00 0.0000000E+00 Chg. balance for solid moles: -.4235E-21 Mass of aqueous solution: 0.899665E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 0.0022900 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 0.5081E-06 -6.294 0.1332E-03 -3.875 98.26 0.5114E-04 andradite 0.4186E-08 -8.378 0.2127E-05 -5.672 1.569 0.5527E-06 grossular 0.5269E-09 -9.278 0.2373E-06 -6.625 0.1750 0.6604E-07 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8882E+00 0.8882E+00 1.0000 -0.051 grossular 0.1118E+00 0.1118E+00 1.0000 -0.952 Solid products produced: Mass = 0.000136 g Volume = 0.000052 cm3 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.0022900 moles log = -2.6402 Original solution: 1000.0103000 g Original solution / Rock added: 436685.72 (Water/Rock Ratio), log = 5.6402 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0289 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9917E+00 0.9858 0.1006E+01 0.1020E+01 CO2,gas 0.9820E-06 1.0070 0.1018E-05 0.1010E-05 CH4,gas 0.5613E-02 1.0125 0.5848E-02 0.5776E-02 H2,gas 0.2675E-02 1.0005 0.2754E-02 0.2753E-02 H2S,gas 0.4830E-06 0.9960 0.4950E-06 0.4970E-06 S2,gas 0.1178E-26 1.0000 0.1212E-26 0.1212E-26 CO,gas 0.7259E-12 1.0000 0.7469E-12 0.7469E-12 SO3,gas 0.2330E-44 1.0000 0.2397E-44 0.2397E-44 SO2,gas 0.2497E-24 1.0000 0.2569E-24 0.2569E-24 HF,gas 0.1185E-14 1.0000 0.1220E-14 0.1220E-14 HCl,gas 0.3400E-17 1.0000 0.3499E-17 0.3499E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 17 albite -0.38 -0.38 0.00 0.000 -0.13080E-10 23 andradite 39.01 39.01 0.00 0.000 0.00000E+00 24 grossular 32.73 32.73 0.00 0.000 -0.12132E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -14.35 -7.69 -2.564 0.13133E+05 -5.992 3 CH4,gas 4.54 0.61 -3.93 -0.983 0.67137E+04 -2.233 4 H2,gas 8.00 3.74 -4.26 -2.434 0.72720E+04 -2.560 5 H2S,gas -6.23 -14.23 -8.00 -4.002 0.13667E+05 -6.305 6 S2,gas -7.34 -35.95 -28.62 -4.402 0.48860E+05 -26.916 7 CO,gas 3.21 -10.61 -13.83 -4.254 0.23607E+05 -12.127 8 SO3,gas 17.12 -29.20 -46.32 -11.580 0.79089E+05 -44.620 9 SO2,gas 0.83 -25.46 -26.29 -7.010 0.44888E+05 -24.590 10 HF,gas 0.47 -16.14 -16.61 -8.306 0.28366E+05 -14.914 11 HCl,gas 5.19 -13.97 -19.16 -9.578 0.32707E+05 -17.456 12 acmite 7.71 6.80 -0.91 -0.095 0.15602E+04 16 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 20 spessartine 24.46 19.70 -4.76 -0.238 0.81206E+04 21 analcite 3.32 2.76 -0.56 -0.063 0.96419E+03 27 annite 20.12 17.36 -2.76 -0.153 0.47128E+04 28 phlogopite 27.06 25.30 -1.77 -0.098 0.30184E+04 30 anorthite 12.71 8.08 -4.63 -0.356 0.79091E+04 33 apatite-OH -18.15 -18.83 -0.68 -0.052 0.11575E+04 34 apatite-F -34.30 -34.97 -0.67 -0.056 0.11434E+04 38 aragonite 0.97 -1.41 -2.37 -0.791 0.40511E+04 39 brucite 12.57 9.26 -3.31 -0.661 0.56473E+04 40 calcite 0.81 -1.41 -2.22 -0.739 0.37869E+04 41 carnegieite-low 9.02 5.90 -3.13 -0.446 0.53360E+04 42 carnegieite-high 10.09 5.90 -4.20 -0.599 0.71630E+04 43 carpholite-Mg 8.58 4.39 -4.19 -0.279 0.71511E+04 44 carpholite-Fe 6.71 1.75 -4.96 -0.331 0.84745E+04 45 celadonite 5.34 3.63 -1.71 -0.100 0.29165E+04 46 celadonite-Fe 3.88 0.99 -2.89 -0.170 0.49304E+04 47 chrysotile 23.89 21.50 -2.39 -0.199 0.40826E+04 49 clinochlore 39.07 38.30 -0.77 -0.024 0.13181E+04 50 daphnite 28.97 25.07 -3.89 -0.122 0.66426E+04 52 chlorite-Al-free 47.17 43.00 -4.17 -0.174 0.71203E+04 54 chloritoid-Fe 9.17 4.89 -4.28 -0.286 0.73133E+04 55 chloritoid-Mn 11.40 7.51 -3.89 -0.259 0.66432E+04 57 coesite -2.38 -3.14 -0.76 -0.255 0.13062E+04 64 cristobalite -2.56 -3.14 -0.58 -0.194 0.99153E+03 66 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71236E+04 68 diaspore 2.87 0.71 -2.17 -0.361 0.36988E+04 69 diamond -3.10 -6.87 -3.77 -1.076 0.64330E+04 70 diopside 16.18 15.92 -0.26 -0.026 0.43848E+03 71 hedenbergite 14.21 13.28 -0.93 -0.093 0.15849E+04 76 clinoenstatite 17.17 12.24 -4.93 -0.493 0.84111E+04 78 epidote 24.67 22.63 -2.04 -0.099 0.34849E+04 79 clinozoisite 22.81 18.59 -4.22 -0.192 0.71984E+04 80 epidote-Fe 29.84 26.67 -3.17 -0.165 0.54179E+04 81 fayalite 14.05 10.09 -3.95 -0.565 0.67505E+04 82 ferrosilite 11.15 6.95 -4.20 -0.420 0.71684E+04 86 gibbsite 4.08 0.71 -3.37 -0.482 0.57574E+04 87 glaucophane 22.97 20.73 -2.24 -0.061 0.38267E+04 88 glaucophane-Fe 17.28 12.80 -4.48 -0.121 0.76422E+04 89 graphite -3.55 -6.87 -3.32 -0.950 0.56752E+04 90 greenalite 16.14 13.57 -2.57 -0.214 0.43911E+04 93 hematite 12.57 9.49 -3.07 -0.373 0.52483E+04 94 heulandite -5.83 -7.63 -1.80 -0.082 0.30729E+04 98 jadeite 4.22 2.76 -1.46 -0.146 0.24897E+04 100 kalsilite 7.58 3.80 -3.79 -0.541 0.64686E+04 101 kaolinite -1.33 -4.87 -3.53 -0.321 0.60349E+04 104 laumontite 2.88 1.80 -1.09 -0.072 0.18564E+04 105 lawsonite 9.62 8.08 -1.54 -0.103 0.26257E+04 106 leucite 4.12 0.65 -3.46 -0.346 0.59154E+04 108 lizardite 23.24 21.50 -1.74 -0.145 0.29752E+04 110 magnetite 20.09 16.11 -3.98 -0.325 0.67929E+04 111 minnesotaite 10.39 7.29 -3.10 -0.182 0.52972E+04 115 manganosite 14.06 9.24 -4.82 -1.205 0.82327E+04 119 microcline -2.49 -2.49 0.00 0.000 0.19748E+00 123 muscovite 2.58 -1.07 -3.65 -0.215 0.62394E+04 124 paragonite 4.24 1.03 -3.21 -0.189 0.54783E+04 125 nepheline 8.34 5.90 -2.44 -0.349 0.41683E+04 137 phlogopite-Na 29.65 27.40 -2.25 -0.125 0.38370E+04 139 prehnite 19.37 17.88 -1.49 -0.088 0.25427E+04 140 prehnite-Fe 22.50 21.92 -0.58 -0.035 0.98410E+03 141 pumpellyite-Fe 46.27 43.09 -3.18 -0.071 0.54295E+04 142 pumpellyite-Mg 48.99 45.73 -3.26 -0.072 0.55677E+04 145 pyrite -21.25 -25.59 -4.35 -1.023 0.74214E+04 146 pyrrhotite -4.26 -7.62 -3.36 -1.119 0.57331E+04 147 pyrrhotiteFe0.875 -6.02 -8.91 -2.89 -1.064 0.49379E+04 148 pyroxmangite 7.40 6.10 -1.30 -0.261 0.22251E+04 149 pyrophyllite -6.18 -11.15 -4.97 -0.311 0.84921E+04 150 quartz -2.99 -3.14 -0.15 -0.051 0.25886E+03 154 rhodochrosite -0.98 -5.12 -4.14 -1.380 0.70667E+04 155 rhodonite 7.45 6.10 -1.35 -0.270 0.23054E+04 156 sanidine -1.28 -2.49 -1.21 -0.093 0.20679E+04 166 stilbite -7.52 -7.63 -0.10 -0.005 0.17905E+03 167 stilpnomelane-Fe 13.02 12.48 -0.53 -0.016 0.90959E+03 168 stilpnomelane-Mg 27.44 25.71 -1.73 -0.052 0.29617E+04 174 talc 16.49 15.22 -1.27 -0.075 0.21715E+04 177 tephroite 18.09 15.33 -2.75 -0.393 0.47019E+04 181 tridymite -2.63 -3.14 -0.51 -0.172 0.87884E+03 182 tremolite 47.87 47.07 -0.80 -0.022 0.13674E+04 183 ferroactinolite 38.45 33.85 -4.61 -0.125 0.78656E+04 184 troilite-low -4.41 -7.62 -3.21 -1.069 0.54759E+04 190 wairakite 3.95 1.80 -2.15 -0.127 0.36783E+04 191 walstromite 11.51 9.80 -1.70 -0.341 0.29109E+04 192 wollastonite 10.46 9.80 -0.66 -0.131 0.11213E+04 193 pseudo-wollastonite 11.00 9.80 -1.20 -0.239 0.20411E+04 194 zoisite 22.85 18.59 -4.26 -0.194 0.72725E+04 195 akaganeite 7.75 4.75 -3.01 -0.650 0.51367E+04 202 chalcedony -2.80 -3.14 -0.34 -0.113 0.57816E+03 204 montmorillonite-Ca -2.29 -6.19 -3.90 -0.241 0.66589E+04 205 montmorillonite-K -2.24 -6.27 -4.03 -0.247 0.68884E+04 206 montmorillonite-Mg -2.48 -6.80 -4.32 -0.267 0.73739E+04 207 montmorillonite-Na -2.04 -5.58 -3.54 -0.217 0.60432E+04 208 nontronite-Ca 3.21 0.33 -2.88 -0.187 0.49180E+04 209 nontronite-H 2.53 -1.80 -4.33 -0.291 0.74009E+04 210 nontronite-K 3.34 0.25 -3.09 -0.198 0.52707E+04 211 nontronite-Mg 3.07 -0.27 -3.35 -0.217 0.57170E+04 212 nontronite-Na 3.52 0.95 -2.57 -0.165 0.43915E+04 228 tobermorite 9.82 7.64 -2.18 -0.595 0.37231E+04 234 alabandite -0.98 -5.00 -4.02 -1.340 0.68643E+04 237 boehmite 4.41 0.71 -3.70 -0.616 0.63157E+04 239 ferrous-oxide 9.81 6.62 -3.19 -0.799 0.54553E+04 245 silica-amorphous -2.09 -3.14 -1.05 -0.350 0.17923E+04 247 an20ab80 2.02 1.31 -0.71 -0.055 0.12110E+04 248 an25ab75 2.65 1.73 -0.91 -0.070 0.15607E+04 249 an30ab70 3.28 2.15 -1.12 -0.086 0.19200E+04 250 tr.625ac.25prg.125 45.16 44.70 -0.47 -0.013 0.79840E+03 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 0.0001000 MOLES Current total amount of reactant added: 0.0022900 MOLES New total amount of reactant added: 0.0023900 MOLES Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.5508E-08 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 7 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 0.0023900 Water: Moles liquid = 0.4985E+02 kg liquid = 0.8981E+00 Moles total = 0.4985E+02 kg total = 0.8980E+00 Activity = 1.0000 Stoichiometric ionic strength = .1148277E-01 Osmotic coef. = 0.9628 True ionic strength = .2015715E-01 Chg. balance for total moles = -.5508E-08 Max. difference allowed = 0.1520E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.92136E-10 -10.0356 0.77384E-10 -10.1113 0.83989E+00 -0.0758 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.16846E-03 -3.7735 0.14063E-03 -3.8519 0.83482E+00 -0.0784 4 SO4-- 0.25285E-08 -8.5971 0.13107E-08 -8.8825 0.51837E+00 -0.2854 5 HCO3- 0.72025E-04 -4.1425 0.60216E-04 -4.2203 0.83604E+00 -0.0778 6 HS- 0.93044E-04 -4.0313 0.77686E-04 -4.1097 0.83494E+00 -0.0783 7 Al+++ 0.10236E-28 -28.9899 0.23550E-29 -29.6280 0.23008E+00 -0.6381 8 H4SiO4 0.72392E-03 -3.1403 0.72392E-03 -3.1403 0.10000E+01 0.0000 9 Ca++ 0.10136E-06 -6.9941 0.52157E-07 -7.2827 0.51455E+00 -0.2886 10 Mg++ 0.21260E-10 -10.6724 0.10889E-10 -10.9630 0.51218E+00 -0.2906 11 Fe++ 0.48122E-13 -13.3177 0.24674E-13 -13.6078 0.51275E+00 -0.2901 12 K+ 0.15653E-03 -3.8054 0.13090E-03 -3.8831 0.83624E+00 -0.0777 13 Na+ 0.19869E-01 -1.7018 0.16584E-01 -1.7803 0.83466E+00 -0.0785 14 Mn++ 0.20114E-10 -10.6965 0.10322E-10 -10.9862 0.51317E+00 -0.2897 15 F- 0.11720E-05 -5.9311 0.97640E-06 -6.0104 0.83309E+00 -0.0793 16 HPO4-- 0.45353E-07 -7.3434 0.23513E-07 -7.6287 0.51845E+00 -0.2853 18 HSiO3- 0.10463E-01 -1.9803 0.87350E-02 -2.0587 0.83482E+00 -0.0784 19 Ca(HSiO3)+ 0.12405E-07 -7.9064 0.10375E-07 -7.9840 0.83642E+00 -0.0776 20 Mg(HSiO3)+ 0.32230E-11 -11.4917 0.26958E-11 -11.5693 0.83642E+00 -0.0776 21 NaHSiO3,aq 0.23429E-02 -2.6302 0.23429E-02 -2.6302 0.10000E+01 0.0000 22 AlO+ 0.63964E-16 -16.1941 0.53501E-16 -16.2716 0.83642E+00 -0.0776 24 HAlO2,aq 0.13768E-09 -9.8611 0.13768E-09 -9.8611 0.10000E+01 0.0000 25 AlO2- 0.47264E-05 -5.3255 0.39385E-05 -5.4047 0.83330E+00 -0.0792 26 CH4,aq 0.34791E-05 -5.4585 0.34669E-05 -5.4601 0.99650E+00 -0.0015 27 C2H6,aq 0.10286E-14 -14.9877 0.10250E-14 -14.9893 0.99650E+00 -0.0015 31 CO,aq 0.50140E-15 -15.2998 0.50140E-15 -15.2998 0.10000E+01 0.0000 32 CO2,aq 0.99919E-08 -8.0004 0.99569E-08 -8.0019 0.99650E+00 -0.0015 33 CO3-2 0.13140E-03 -3.8814 0.67968E-04 -4.1677 0.51727E+00 -0.2863 34 CaCO3,aq 0.44450E-07 -7.3521 0.44450E-07 -7.3521 0.10000E+01 0.0000 35 Ca(HCO3)+ 0.95847E-10 -10.0184 0.80169E-10 -10.0960 0.83642E+00 -0.0776 36 CaCl+ 0.14191E-10 -10.8480 0.11870E-10 -10.9255 0.83642E+00 -0.0776 37 CaCl2,aq 0.39659E-15 -15.4017 0.39659E-15 -15.4017 0.10000E+01 0.0000 38 CaF+ 0.88893E-12 -12.0511 0.74352E-12 -12.1287 0.83642E+00 -0.0776 39 CaOH+ 0.57429E-07 -7.2409 0.48035E-07 -7.3184 0.83642E+00 -0.0776 40 CaSO4,aq 0.21708E-13 -13.6634 0.21708E-13 -13.6634 0.10000E+01 0.0000 41 HCl,aq 0.19942E-14 -14.7002 0.19942E-14 -14.7002 0.10000E+01 0.0000 45 HF,aq 0.51725E-12 -12.2863 0.51725E-12 -12.2863 0.10000E+01 0.0000 46 HF2- 0.20425E-18 -18.6898 0.17052E-18 -18.7682 0.83482E+00 -0.0784 48 FeCl+ 0.65665E-17 -17.1827 0.54924E-17 -17.2602 0.83642E+00 -0.0776 51 FeF+ 0.14719E-17 -17.8321 0.12311E-17 -17.9097 0.83642E+00 -0.0776 53 FeO,aq 0.16014E-09 -9.7955 0.16014E-09 -9.7955 0.10000E+01 0.0000 54 FeOH+ 0.12409E-10 -10.9063 0.10379E-10 -10.9838 0.83642E+00 -0.0776 55 HFeO2- 0.25937E-07 -7.5861 0.21653E-07 -7.6645 0.83482E+00 -0.0784 56 FeO+ 0.20904E-16 -16.6798 0.17485E-16 -16.7573 0.83642E+00 -0.0776 58 FeO2- 0.71568E-09 -9.1453 0.59746E-09 -9.2237 0.83482E+00 -0.0784 59 HFeO2,aq 0.58803E-11 -11.2306 0.58803E-11 -11.2306 0.10000E+01 0.0000 60 H2,aq 0.20117E-05 -5.6964 0.20046E-05 -5.6980 0.99650E+00 -0.0015 61 KCl,aq 0.33364E-09 -9.4767 0.33364E-09 -9.4767 0.10000E+01 0.0000 63 KOH,aq 0.72238E-06 -6.1412 0.72238E-06 -6.1412 0.10000E+01 0.0000 64 KSO4- 0.31891E-11 -11.4963 0.26623E-11 -11.5747 0.83482E+00 -0.0784 65 MgCO3,aq 0.23261E-11 -11.6334 0.23261E-11 -11.6334 0.10000E+01 0.0000 66 Mg(HCO3)+ 0.20447E-13 -13.6894 0.17102E-13 -13.7669 0.83642E+00 -0.0776 67 MgCl+ 0.26853E-14 -14.5710 0.22461E-14 -14.6486 0.83642E+00 -0.0776 68 MgF+ 0.68747E-15 -15.1627 0.57502E-15 -15.2403 0.83642E+00 -0.0776 69 MgOH+ 0.66346E-10 -10.1782 0.55493E-10 -10.2558 0.83642E+00 -0.0776 71 MnF+ 0.20296E-15 -15.6926 0.16976E-15 -15.7702 0.83642E+00 -0.0776 72 MnO,aq 0.17851E-08 -8.7483 0.17851E-08 -8.7483 0.10000E+01 0.0000 73 MnOH+ 0.48223E-09 -9.3167 0.40335E-09 -9.3943 0.83642E+00 -0.0776 74 MnO2-2 0.19125E-10 -10.7184 0.98928E-11 -11.0047 0.51727E+00 -0.2863 75 HMnO2- 0.20091E-09 -9.6970 0.16772E-09 -9.7754 0.83482E+00 -0.0784 78 MnCl+ 0.10687E-13 -13.9711 0.89389E-14 -14.0487 0.83642E+00 -0.0776 79 MnSO4,aq 0.39058E-17 -17.4083 0.39058E-17 -17.4083 0.10000E+01 0.0000 80 NaCl,aq 0.77289E-06 -6.1119 0.77289E-06 -6.1119 0.10000E+01 0.0000 81 NaF,aq 0.37909E-08 -8.4213 0.37909E-08 -8.4213 0.10000E+01 0.0000 82 NaOH,aq 0.92075E-04 -4.0359 0.92075E-04 -4.0359 0.10000E+01 0.0000 84 OH- 0.89599E-02 -2.0477 0.74663E-02 -2.1269 0.83330E+00 -0.0792 89 HPO3-2 0.28397E-15 -15.5467 0.14689E-15 -15.8330 0.51727E+00 -0.2863 91 H2PO3- 0.27304E-19 -19.5638 0.22794E-19 -19.6422 0.83482E+00 -0.0784 92 H3PO4,aq 0.98477E-18 -18.0067 0.98477E-18 -18.0067 0.10000E+01 0.0000 93 H2PO4- 0.40169E-10 -10.3961 0.33566E-10 -10.4741 0.83561E+00 -0.0780 94 PO4-3 0.10256E-08 -8.9890 0.24791E-09 -9.6057 0.24172E+00 -0.6167 98 HP2O7-3 0.98973E-18 -18.0045 0.22795E-18 -18.6422 0.23031E+00 -0.6377 99 P2O7-4 0.91920E-17 -17.0366 0.70370E-18 -18.1526 0.76556E-01 -1.1160 100 H2S,aq 0.18645E-07 -7.7294 0.18580E-07 -7.7310 0.99650E+00 -0.0015 101 S2-2 0.12897E-12 -12.8895 0.66710E-13 -13.1758 0.51727E+00 -0.2863 107 SO3-2 0.65061E-15 -15.1867 0.34143E-15 -15.4667 0.52479E+00 -0.2800 108 HSO3- 0.19817E-17 -17.7030 0.16543E-17 -17.7814 0.83482E+00 -0.0784 109 HSO4- 0.11675E-15 -15.9327 0.97747E-16 -16.0099 0.83724E+00 -0.0771 111 S2O3-2 0.55303E-18 -18.2572 0.28607E-18 -18.5435 0.51727E+00 -0.2863 Charge balance for all species = -.6133E-08 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.9213571E-10 -.2200994E-01 -.2214596E+02 0.0000 2 H2O 0.1000000E+01 0.5550451E+02 0.9981844E+06 0.0000 3 Cl- 0.1684573E-03 0.1692305E-03 0.5989252E+01 6.2594 4 SO4-- 0.2528483E-08 -.3979388E-05 -.3815989E+00 11.3402 5 HCO3- 0.7202515E-04 0.2069568E-03 0.1260587E+02 5.8911 6 HS- 0.9304403E-04 0.9704460E-04 0.3203855E+01 6.0017 7 Al+++ 0.1023558E-28 0.4726496E-05 0.1273053E+00 0.7060 8 H4SiO4 0.7239179E-03 0.1353020E-01 0.1298190E+04 -3.1403 9 Ca++ 0.1013638E-06 0.2157585E-06 0.8632069E-02 12.9400 10 Mg++ 0.2126005E-10 0.9317857E-10 0.2261402E-05 9.2597 11 Fe++ 0.4812176E-13 0.2683116E-07 0.1495823E-02 6.6149 12 K+ 0.1565316E-03 0.1572543E-03 0.6138219E+01 6.2283 13 Na+ 0.1986880E-01 0.2230455E-01 0.5118817E+03 8.3310 14 Mn++ 0.2011431E-10 0.2507460E-08 0.1375143E-03 9.2365 15 F- 0.1172029E-05 0.1175821E-05 0.2229924E-01 4.1010 16 HPO4-- 0.4535264E-07 0.4641842E-07 0.4447414E-02 12.5940 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.1976920E-01 -.1976703E-01 -.2165528E-05 0.0000000E+00 2 H2O 0.4984837E+02 0.4984837E+02 -.2122086E-05 0.0000000E+00 3 Cl- 0.1519852E-03 0.1519852E-03 0.0000000E+00 0.0000000E+00 4 SO4-- -.3572810E-05 -.3573872E-05 0.1061915E-08 0.0000000E+00 5 HCO3- 0.1858670E-03 0.1858670E-03 0.0000000E+00 0.0000000E+00 6 HS- 0.8715428E-04 0.8715534E-04 -.1061915E-08 0.0000000E+00 7 Al+++ 0.4775352E-05 0.4244847E-05 0.5305055E-06 0.0000000E+00 8 H4SiO4 0.1215302E-01 0.1215142E-01 0.1602691E-05 0.0000000E+00 9 Ca++ 0.2080835E-06 0.1937718E-06 0.1431171E-07 0.0000000E+00 10 Mg++ 0.8368328E-10 0.8368328E-10 0.0000000E+00 0.0000000E+00 11 Fe++ 0.3259227E-07 0.2409695E-07 0.8495318E-08 0.0000000E+00 12 K+ 0.1412294E-03 0.1412294E-03 0.0000000E+00 0.0000000E+00 13 Na+ 0.2003215E-01 0.2003162E-01 0.5294597E-06 0.0000000E+00 14 Mn++ 0.2251939E-08 0.2251939E-08 0.0000000E+00 0.0000000E+00 15 F- 0.1056000E-05 0.1056000E-05 0.0000000E+00 0.0000000E+00 16 HPO4-- 0.4168819E-07 0.4168819E-07 0.0000000E+00 0.0000000E+00 Chg. balance for solid moles: -.1059E-21 Mass of aqueous solution: 0.899667E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 0.0023900 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 0.5295E-06 -6.276 0.1388E-03 -3.858 98.30 0.5330E-04 andradite 0.4248E-08 -8.372 0.2159E-05 -5.666 1.528 0.5608E-06 grossular 0.5229E-09 -9.282 0.2355E-06 -6.628 0.1668 0.6554E-07 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8904E+00 0.8904E+00 1.0000 -0.050 grossular 0.1096E+00 0.1096E+00 1.0000 -0.960 Solid products produced: Mass = 0.000141 g Volume = 0.000054 cm3 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.0023900 moles log = -2.6216 Original solution: 1000.0103000 g Original solution / Rock added: 418414.35 (Water/Rock Ratio), log = 5.6216 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0281 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9925E+00 0.9858 0.1006E+01 0.1020E+01 CO2,gas 0.1029E-05 1.0070 0.1065E-05 0.1058E-05 CH4,gas 0.4902E-02 1.0125 0.5103E-02 0.5040E-02 H2,gas 0.2559E-02 1.0005 0.2632E-02 0.2630E-02 H2S,gas 0.4988E-06 0.9960 0.5107E-06 0.5128E-06 S2,gas 0.1375E-26 1.0000 0.1414E-26 0.1414E-26 CO,gas 0.7268E-12 1.0000 0.7472E-12 0.7472E-12 SO3,gas 0.2887E-44 1.0000 0.2968E-44 0.2968E-44 SO2,gas 0.2956E-24 1.0000 0.3039E-24 0.3039E-24 HF,gas 0.1235E-14 1.0000 0.1270E-14 0.1270E-14 HCl,gas 0.3423E-17 1.0000 0.3519E-17 0.3519E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 17 albite -0.38 -0.38 0.00 0.000 -0.94784E-12 23 andradite 39.01 39.01 0.00 0.000 -0.12132E-10 24 grossular 32.73 32.73 0.00 0.000 0.24265E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -14.33 -7.67 -2.557 0.13099E+05 -5.973 3 CH4,gas 4.54 0.55 -3.99 -0.998 0.68148E+04 -2.292 4 H2,gas 8.00 3.72 -4.28 -2.445 0.73058E+04 -2.580 5 H2S,gas -6.23 -14.22 -7.99 -3.995 0.13644E+05 -6.292 6 S2,gas -7.34 -35.88 -28.55 -4.392 0.48746E+05 -26.850 7 CO,gas 3.21 -10.61 -13.83 -4.254 0.23607E+05 -12.127 8 SO3,gas 17.12 -29.11 -46.23 -11.557 0.78931E+05 -44.528 9 SO2,gas 0.83 -25.38 -26.22 -6.991 0.44764E+05 -24.517 10 HF,gas 0.47 -16.12 -16.60 -8.298 0.28336E+05 -14.896 11 HCl,gas 5.19 -13.96 -19.15 -9.576 0.32703E+05 -17.454 12 acmite 7.71 6.80 -0.90 -0.094 0.15451E+04 16 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 20 spessartine 24.46 19.70 -4.76 -0.238 0.81221E+04 21 analcite 3.32 2.76 -0.57 -0.063 0.96543E+03 27 annite 20.12 17.36 -2.77 -0.154 0.47215E+04 28 phlogopite 27.06 25.29 -1.77 -0.098 0.30259E+04 30 anorthite 12.71 8.07 -4.64 -0.357 0.79207E+04 33 apatite-OH -18.15 -18.85 -0.70 -0.054 0.11963E+04 34 apatite-F -34.30 -34.98 -0.67 -0.056 0.11523E+04 38 aragonite 0.97 -1.39 -2.36 -0.786 0.40265E+04 39 brucite 12.57 9.26 -3.31 -0.662 0.56498E+04 40 calcite 0.81 -1.39 -2.20 -0.734 0.37623E+04 41 carnegieite-low 9.02 5.90 -3.13 -0.447 0.53385E+04 42 carnegieite-high 10.09 5.90 -4.20 -0.600 0.71655E+04 43 carpholite-Mg 8.58 4.39 -4.19 -0.279 0.71559E+04 44 carpholite-Fe 6.71 1.75 -4.97 -0.331 0.84797E+04 45 celadonite 5.34 3.63 -1.71 -0.101 0.29178E+04 46 celadonite-Fe 3.88 0.99 -2.89 -0.170 0.49321E+04 47 chrysotile 23.89 21.50 -2.39 -0.199 0.40876E+04 49 clinochlore 39.07 38.29 -0.78 -0.024 0.13318E+04 50 daphnite 28.97 25.07 -3.90 -0.122 0.66581E+04 52 chlorite-Al-free 47.17 43.00 -4.18 -0.174 0.71304E+04 54 chloritoid-Fe 9.17 4.89 -4.29 -0.286 0.73198E+04 55 chloritoid-Mn 11.40 7.51 -3.89 -0.260 0.66469E+04 57 coesite -2.38 -3.14 -0.76 -0.255 0.13049E+04 64 cristobalite -2.56 -3.14 -0.58 -0.193 0.99029E+03 66 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71236E+04 68 diaspore 2.87 0.71 -2.17 -0.361 0.37012E+04 69 diamond -3.10 -6.89 -3.79 -1.082 0.64665E+04 70 diopside 16.18 15.92 -0.26 -0.026 0.44786E+03 71 hedenbergite 14.21 13.27 -0.93 -0.093 0.15947E+04 76 clinoenstatite 17.17 12.24 -4.93 -0.493 0.84136E+04 78 epidote 24.67 22.63 -2.04 -0.099 0.34907E+04 79 clinozoisite 22.81 18.58 -4.23 -0.192 0.72207E+04 80 epidote-Fe 29.84 26.67 -3.17 -0.165 0.54073E+04 81 fayalite 14.05 10.09 -3.96 -0.565 0.67550E+04 82 ferrosilite 11.15 6.95 -4.20 -0.420 0.71717E+04 86 gibbsite 4.08 0.71 -3.37 -0.482 0.57598E+04 87 glaucophane 22.97 20.73 -2.24 -0.061 0.38318E+04 88 glaucophane-Fe 17.28 12.80 -4.48 -0.121 0.76484E+04 89 graphite -3.55 -6.89 -3.34 -0.955 0.57087E+04 90 greenalite 16.14 13.56 -2.58 -0.215 0.43973E+04 93 hematite 12.57 9.51 -3.06 -0.371 0.52203E+04 94 heulandite -5.83 -7.63 -1.80 -0.082 0.30783E+04 98 jadeite 4.22 2.76 -1.46 -0.146 0.24909E+04 100 kalsilite 7.58 3.79 -3.79 -0.541 0.64712E+04 101 kaolinite -1.33 -4.87 -3.54 -0.321 0.60373E+04 104 laumontite 2.88 1.79 -1.09 -0.073 0.18656E+04 105 lawsonite 9.62 8.07 -1.54 -0.103 0.26374E+04 106 leucite 4.12 0.65 -3.47 -0.347 0.59167E+04 108 lizardite 23.24 21.50 -1.75 -0.145 0.29803E+04 110 magnetite 20.09 16.12 -3.96 -0.324 0.67678E+04 111 minnesotaite 10.39 7.28 -3.10 -0.183 0.53009E+04 115 manganosite 14.06 9.24 -4.82 -1.205 0.82328E+04 119 microcline -2.49 -2.49 0.00 0.000 0.20634E+00 123 muscovite 2.58 -1.07 -3.66 -0.215 0.62442E+04 124 paragonite 4.24 1.03 -3.21 -0.189 0.54831E+04 125 nepheline 8.34 5.90 -2.44 -0.349 0.41708E+04 137 phlogopite-Na 29.65 27.40 -2.25 -0.125 0.38445E+04 139 prehnite 19.37 17.87 -1.50 -0.088 0.25625E+04 140 prehnite-Fe 22.50 21.92 -0.58 -0.035 0.98750E+03 141 pumpellyite-Fe 46.27 43.06 -3.21 -0.071 0.54744E+04 142 pumpellyite-Mg 48.99 45.71 -3.29 -0.073 0.56122E+04 145 pyrite -21.25 -25.55 -4.30 -1.012 0.73442E+04 146 pyrrhotite -4.26 -7.61 -3.35 -1.115 0.57128E+04 147 pyrrhotiteFe0.875 -6.02 -8.89 -2.88 -1.058 0.49131E+04 148 pyroxmangite 7.40 6.10 -1.30 -0.261 0.22240E+04 149 pyrophyllite -6.18 -11.15 -4.97 -0.311 0.84919E+04 150 quartz -2.99 -3.14 -0.15 -0.050 0.25762E+03 154 rhodochrosite -0.98 -5.10 -4.12 -1.373 0.70328E+04 155 rhodonite 7.45 6.10 -1.35 -0.270 0.23043E+04 156 sanidine -1.28 -2.49 -1.21 -0.093 0.20680E+04 166 stilbite -7.52 -7.63 -0.11 -0.005 0.18449E+03 167 stilpnomelane-Fe 13.02 12.48 -0.54 -0.016 0.91957E+03 168 stilpnomelane-Mg 27.44 25.70 -1.74 -0.052 0.29697E+04 174 talc 16.49 15.22 -1.27 -0.075 0.21741E+04 177 tephroite 18.09 15.33 -2.75 -0.393 0.47010E+04 181 tridymite -2.63 -3.14 -0.51 -0.171 0.87759E+03 182 tremolite 47.87 47.06 -0.81 -0.022 0.13887E+04 183 ferroactinolite 38.45 33.83 -4.62 -0.125 0.78888E+04 184 troilite-low -4.41 -7.61 -3.20 -1.065 0.54556E+04 190 wairakite 3.95 1.79 -2.16 -0.127 0.36875E+04 191 walstromite 11.51 9.80 -1.71 -0.342 0.29190E+04 192 wollastonite 10.46 9.80 -0.66 -0.132 0.11294E+04 193 pseudo-wollastonite 11.00 9.80 -1.20 -0.240 0.20492E+04 194 zoisite 22.85 18.58 -4.27 -0.194 0.72947E+04 195 akaganeite 7.75 4.75 -3.00 -0.649 0.51227E+04 202 chalcedony -2.80 -3.14 -0.34 -0.113 0.57691E+03 204 montmorillonite-Ca -2.29 -6.19 -3.90 -0.241 0.66603E+04 205 montmorillonite-K -2.24 -6.27 -4.03 -0.247 0.68887E+04 206 montmorillonite-Mg -2.48 -6.80 -4.32 -0.267 0.73741E+04 207 montmorillonite-Na -2.04 -5.58 -3.54 -0.217 0.60435E+04 208 nontronite-Ca 3.21 0.35 -2.86 -0.186 0.48877E+04 209 nontronite-H 2.53 -1.78 -4.32 -0.289 0.73691E+04 210 nontronite-K 3.34 0.27 -3.07 -0.197 0.52394E+04 211 nontronite-Mg 3.07 -0.26 -3.33 -0.216 0.56857E+04 212 nontronite-Na 3.52 0.97 -2.55 -0.164 0.43602E+04 228 tobermorite 9.82 7.64 -2.18 -0.596 0.37297E+04 234 alabandite -0.98 -4.98 -4.01 -1.336 0.68413E+04 237 boehmite 4.41 0.71 -3.70 -0.617 0.63181E+04 239 ferrous-oxide 9.81 6.61 -3.20 -0.799 0.54582E+04 245 silica-amorphous -2.09 -3.14 -1.05 -0.350 0.17911E+04 247 an20ab80 2.02 1.31 -0.71 -0.055 0.12133E+04 248 an25ab75 2.65 1.73 -0.92 -0.070 0.15636E+04 249 an30ab70 3.28 2.15 -1.13 -0.087 0.19235E+04 250 tr.625ac.25prg.125 45.16 44.68 -0.48 -0.013 0.82125E+03 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 0.0001000 MOLES Current total amount of reactant added: 0.0023900 MOLES New total amount of reactant added: 0.0024900 MOLES Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.5508E-08 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 7 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 0.0024900 Water: Moles liquid = 0.4985E+02 kg liquid = 0.8981E+00 Moles total = 0.4985E+02 kg total = 0.8980E+00 Activity = 1.0000 Stoichiometric ionic strength = .1148916E-01 Osmotic coef. = 0.9626 True ionic strength = .2016297E-01 Chg. balance for total moles = -.5508E-08 Max. difference allowed = 0.1526E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.92304E-10 -10.0348 0.77524E-10 -10.1106 0.83988E+00 -0.0758 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.16911E-03 -3.7718 0.14117E-03 -3.8502 0.83480E+00 -0.0784 4 SO4-- 0.31769E-08 -8.4980 0.16467E-08 -8.7834 0.51833E+00 -0.2854 5 HCO3- 0.75139E-04 -4.1241 0.62818E-04 -4.2019 0.83603E+00 -0.0778 6 HS- 0.95748E-04 -4.0189 0.79943E-04 -4.0972 0.83492E+00 -0.0784 7 Al+++ 0.10259E-28 -28.9889 0.23601E-29 -29.6271 0.23004E+00 -0.6382 8 H4SiO4 0.72514E-03 -3.1396 0.72514E-03 -3.1396 0.10000E+01 0.0000 9 Ca++ 0.10043E-06 -6.9981 0.51672E-07 -7.2867 0.51451E+00 -0.2886 10 Mg++ 0.21266E-10 -10.6723 0.10891E-10 -10.9629 0.51214E+00 -0.2906 11 Fe++ 0.48017E-13 -13.3186 0.24619E-13 -13.6087 0.51271E+00 -0.2901 12 K+ 0.15653E-03 -3.8054 0.13090E-03 -3.8831 0.83623E+00 -0.0777 13 Na+ 0.19869E-01 -1.7018 0.16584E-01 -1.7803 0.83465E+00 -0.0785 14 Mn++ 0.20184E-10 -10.6950 0.10357E-10 -10.9848 0.51313E+00 -0.2898 15 F- 0.12164E-05 -5.9149 0.10134E-05 -5.9942 0.83307E+00 -0.0793 16 HPO4-- 0.45354E-07 -7.3434 0.23512E-07 -7.6287 0.51841E+00 -0.2853 18 HSiO3- 0.10462E-01 -1.9804 0.87340E-02 -2.0588 0.83480E+00 -0.0784 19 Ca(HSiO3)+ 0.12288E-07 -7.9105 0.10278E-07 -7.9881 0.83641E+00 -0.0776 20 Mg(HSiO3)+ 0.32234E-11 -11.4917 0.26960E-11 -11.5693 0.83641E+00 -0.0776 21 NaHSiO3,aq 0.23426E-02 -2.6303 0.23426E-02 -2.6303 0.10000E+01 0.0000 22 AlO+ 0.63873E-16 -16.1947 0.53424E-16 -16.2723 0.83641E+00 -0.0776 24 HAlO2,aq 0.13724E-09 -9.8625 0.13724E-09 -9.8625 0.10000E+01 0.0000 25 AlO2- 0.47026E-05 -5.3277 0.39186E-05 -5.4069 0.83329E+00 -0.0792 26 CH4,aq 0.29728E-05 -5.5268 0.29624E-05 -5.5284 0.99650E+00 -0.0015 27 C2H6,aq 0.78980E-15 -15.1025 0.78704E-15 -15.1040 0.99650E+00 -0.0015 31 CO,aq 0.49828E-15 -15.3025 0.49828E-15 -15.3025 0.10000E+01 0.0000 32 CO2,aq 0.10442E-07 -7.9812 0.10406E-07 -7.9827 0.99650E+00 -0.0015 33 CO3-2 0.13684E-03 -3.8638 0.70777E-04 -4.1501 0.51723E+00 -0.2863 34 CaCO3,aq 0.45858E-07 -7.3386 0.45858E-07 -7.3386 0.10000E+01 0.0000 35 Ca(HCO3)+ 0.99062E-10 -10.0041 0.82857E-10 -10.0817 0.83641E+00 -0.0776 36 CaCl+ 0.14114E-10 -10.8503 0.11805E-10 -10.9279 0.83641E+00 -0.0776 37 CaCl2,aq 0.39595E-15 -15.4024 0.39595E-15 -15.4024 0.10000E+01 0.0000 38 CaF+ 0.91403E-12 -12.0390 0.76451E-12 -12.1166 0.83641E+00 -0.0776 39 CaOH+ 0.56795E-07 -7.2457 0.47504E-07 -7.3233 0.83641E+00 -0.0776 40 CaSO4,aq 0.27020E-13 -13.5683 0.27020E-13 -13.5683 0.10000E+01 0.0000 41 HCl,aq 0.20055E-14 -14.6978 0.20055E-14 -14.6978 0.10000E+01 0.0000 45 HF,aq 0.53780E-12 -12.2694 0.53780E-12 -12.2694 0.10000E+01 0.0000 46 HF2- 0.22041E-18 -18.6568 0.18400E-18 -18.7352 0.83480E+00 -0.0784 48 FeCl+ 0.65771E-17 -17.1820 0.55012E-17 -17.2595 0.83641E+00 -0.0776 51 FeF+ 0.15242E-17 -17.8170 0.12749E-17 -17.8945 0.83641E+00 -0.0776 53 FeO,aq 0.15921E-09 -9.7980 0.15921E-09 -9.7980 0.10000E+01 0.0000 54 FeOH+ 0.12359E-10 -10.9080 0.10337E-10 -10.9856 0.83641E+00 -0.0776 55 HFeO2- 0.25740E-07 -7.5894 0.21487E-07 -7.6678 0.83480E+00 -0.0784 56 FeO+ 0.21351E-16 -16.6706 0.17858E-16 -16.7482 0.83641E+00 -0.0776 58 FeO2- 0.72834E-09 -9.1377 0.60802E-09 -9.2161 0.83480E+00 -0.0784 59 HFeO2,aq 0.59950E-11 -11.2222 0.59950E-11 -11.2222 0.10000E+01 0.0000 60 H2,aq 0.19129E-05 -5.7183 0.19062E-05 -5.7198 0.99650E+00 -0.0015 61 KCl,aq 0.33492E-09 -9.4751 0.33492E-09 -9.4751 0.10000E+01 0.0000 63 KOH,aq 0.72107E-06 -6.1420 0.72107E-06 -6.1420 0.10000E+01 0.0000 64 KSO4- 0.40067E-11 -11.3972 0.33448E-11 -11.4756 0.83480E+00 -0.0784 65 MgCO3,aq 0.24228E-11 -11.6157 0.24228E-11 -11.6157 0.10000E+01 0.0000 66 Mg(HCO3)+ 0.21335E-13 -13.6709 0.17845E-13 -13.7485 0.83641E+00 -0.0776 67 MgCl+ 0.26963E-14 -14.5692 0.22552E-14 -14.6468 0.83641E+00 -0.0776 68 MgF+ 0.71366E-15 -15.1465 0.59691E-15 -15.2241 0.83641E+00 -0.0776 69 MgOH+ 0.66241E-10 -10.1789 0.55405E-10 -10.2565 0.83641E+00 -0.0776 71 MnF+ 0.21136E-15 -15.6750 0.17678E-15 -15.7526 0.83641E+00 -0.0776 72 MnO,aq 0.17847E-08 -8.7484 0.17847E-08 -8.7484 0.10000E+01 0.0000 73 MnOH+ 0.48301E-09 -9.3160 0.40399E-09 -9.3936 0.83641E+00 -0.0776 74 MnO2-2 0.19054E-10 -10.7200 0.98552E-11 -11.0063 0.51723E+00 -0.2863 75 HMnO2- 0.20051E-09 -9.6979 0.16738E-09 -9.7763 0.83480E+00 -0.0784 78 MnCl+ 0.10765E-13 -13.9680 0.90039E-14 -14.0456 0.83641E+00 -0.0776 79 MnSO4,aq 0.49237E-17 -17.3077 0.49237E-17 -17.3077 0.10000E+01 0.0000 80 NaCl,aq 0.77588E-06 -6.1102 0.77588E-06 -6.1102 0.10000E+01 0.0000 81 NaF,aq 0.39345E-08 -8.4051 0.39345E-08 -8.4051 0.10000E+01 0.0000 82 NaOH,aq 0.91910E-04 -4.0366 0.91910E-04 -4.0366 0.10000E+01 0.0000 84 OH- 0.89439E-02 -2.0485 0.74528E-02 -2.1277 0.83329E+00 -0.0792 89 HPO3-2 0.27003E-15 -15.5686 0.13967E-15 -15.8549 0.51723E+00 -0.2863 91 H2PO3- 0.26010E-19 -19.5849 0.21713E-19 -19.6633 0.83480E+00 -0.0784 92 H3PO4,aq 0.98829E-18 -18.0051 0.98829E-18 -18.0051 0.10000E+01 0.0000 93 H2PO4- 0.40240E-10 -10.3953 0.33625E-10 -10.4733 0.83560E+00 -0.0780 94 PO4-3 0.10239E-08 -8.9897 0.24745E-09 -9.6065 0.24168E+00 -0.6168 98 HP2O7-3 0.99160E-18 -18.0037 0.22834E-18 -18.6414 0.23027E+00 -0.6378 99 P2O7-4 0.91940E-17 -17.0365 0.70365E-18 -18.1526 0.76533E-01 -1.1162 100 H2S,aq 0.19221E-07 -7.7162 0.19154E-07 -7.7177 0.99650E+00 -0.0015 101 S2-2 0.14363E-12 -12.8428 0.74289E-13 -13.1291 0.51723E+00 -0.2863 107 SO3-2 0.77732E-15 -15.1094 0.40790E-15 -15.3894 0.52475E+00 -0.2800 108 HSO3- 0.23717E-17 -17.6249 0.19799E-17 -17.7034 0.83480E+00 -0.0784 109 HSO4- 0.14695E-15 -15.8328 0.12303E-15 -15.9100 0.83723E+00 -0.0772 111 S2O3-2 0.71633E-18 -18.1449 0.37051E-18 -18.4312 0.51723E+00 -0.2863 Charge balance for all species = -.6133E-08 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.9230359E-10 -.2199781E-01 -.2213375E+02 0.0000 2 H2O 0.1000000E+01 0.5550450E+02 0.9981837E+06 0.0000 3 Cl- 0.1691109E-03 0.1698871E-03 0.6012489E+01 6.2603 4 SO4-- 0.3176899E-08 -.3447724E-05 -.3306155E+00 11.4377 5 HCO3- 0.7513864E-04 0.2150067E-03 0.1309619E+02 5.9086 6 HS- 0.9574835E-04 0.9921847E-04 0.3275622E+01 6.0133 7 Al+++ 0.1025946E-28 0.4702768E-05 0.1266661E+00 0.7046 8 H4SiO4 0.7251382E-03 0.1353010E-01 0.1298180E+04 -3.1396 9 Ca++ 0.1004307E-06 0.2154853E-06 0.8621135E-02 12.9344 10 Mg++ 0.2126620E-10 0.9317839E-10 0.2261396E-05 9.2582 11 Fe++ 0.4801736E-13 0.2664558E-07 0.1485477E-02 6.6124 12 K+ 0.1565326E-03 0.1572540E-03 0.6138205E+01 6.2275 13 Na+ 0.1986917E-01 0.2230448E-01 0.5118800E+03 8.3302 14 Mn++ 0.2018424E-10 0.2507455E-08 0.1375140E-03 9.2364 15 F- 0.1216422E-05 0.1220357E-05 0.2314386E-01 4.1163 16 HPO4-- 0.4535421E-07 0.4641833E-07 0.4447404E-02 12.5924 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.1975843E-01 -.1975618E-01 -.2251542E-05 0.0000000E+00 2 H2O 0.4984845E+02 0.4984845E+02 -.2207391E-05 0.0000000E+00 3 Cl- 0.1525752E-03 0.1525752E-03 0.0000000E+00 0.0000000E+00 4 SO4-- -.3095310E-05 -.3096393E-05 0.1082742E-08 0.0000000E+00 5 HCO3- 0.1930970E-03 0.1930970E-03 0.0000000E+00 0.0000000E+00 6 HS- 0.8910678E-04 0.8910786E-04 -.1082742E-08 0.0000000E+00 7 Al+++ 0.4775352E-05 0.4223545E-05 0.5518075E-06 0.0000000E+00 8 H4SiO4 0.1215302E-01 0.1215135E-01 0.1666852E-05 0.0000000E+00 9 Ca++ 0.2080835E-06 0.1935268E-06 0.1455672E-07 0.0000000E+00 10 Mg++ 0.8368328E-10 0.8368328E-10 0.0000000E+00 0.0000000E+00 11 Fe++ 0.3259227E-07 0.2393033E-07 0.8661939E-08 0.0000000E+00 12 K+ 0.1412294E-03 0.1412294E-03 0.0000000E+00 0.0000000E+00 13 Na+ 0.2003215E-01 0.2003160E-01 0.5507649E-06 0.0000000E+00 14 Mn++ 0.2251939E-08 0.2251939E-08 0.0000000E+00 0.0000000E+00 15 F- 0.1096000E-05 0.1096000E-05 0.0000000E+00 0.0000000E+00 16 HPO4-- 0.4168819E-07 0.4168819E-07 0.0000000E+00 0.0000000E+00 Chg. balance for solid moles: -.5294E-21 Mass of aqueous solution: 0.899669E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 0.0024900 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 0.5508E-06 -6.259 0.1444E-03 -3.840 98.34 0.5544E-04 andradite 0.4331E-08 -8.363 0.2201E-05 -5.657 1.499 0.5718E-06 grossular 0.5213E-09 -9.283 0.2348E-06 -6.629 0.1599 0.6533E-07 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8926E+00 0.8926E+00 1.0000 -0.049 grossular 0.1074E+00 0.1074E+00 1.0000 -0.969 Solid products produced: Mass = 0.000147 g Volume = 0.000056 cm3 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.0024900 moles log = -2.6038 Original solution: 1000.0103000 g Original solution / Rock added: 401610.56 (Water/Rock Ratio), log = 5.6038 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0272 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9934E+00 0.9859 0.1006E+01 0.1020E+01 CO2,gas 0.1076E-05 1.0071 0.1113E-05 0.1106E-05 CH4,gas 0.4193E-02 1.0125 0.4360E-02 0.4307E-02 H2,gas 0.2435E-02 1.0005 0.2503E-02 0.2501E-02 H2S,gas 0.5146E-06 0.9960 0.5265E-06 0.5286E-06 S2,gas 0.1618E-26 1.0000 0.1662E-26 0.1662E-26 CO,gas 0.7229E-12 1.0000 0.7425E-12 0.7425E-12 SO3,gas 0.3643E-44 1.0000 0.3742E-44 0.3742E-44 SO2,gas 0.3547E-24 1.0000 0.3643E-24 0.3643E-24 HF,gas 0.1286E-14 1.0000 0.1320E-14 0.1320E-14 HCl,gas 0.3445E-17 1.0000 0.3539E-17 0.3539E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 17 albite -0.38 -0.38 0.00 0.000 -0.94784E-12 23 andradite 39.01 39.01 0.00 0.000 -0.12132E-10 24 grossular 32.73 32.73 0.00 0.000 0.12132E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -14.31 -7.65 -2.551 0.13066E+05 -5.953 3 CH4,gas 4.54 0.48 -4.06 -1.015 0.69314E+04 -2.360 4 H2,gas 8.00 3.70 -4.30 -2.457 0.73431E+04 -2.602 5 H2S,gas -6.23 -14.21 -7.98 -3.989 0.13621E+05 -6.279 6 S2,gas -7.34 -35.81 -28.48 -4.381 0.48626E+05 -26.779 7 CO,gas 3.21 -10.61 -13.83 -4.255 0.23611E+05 -12.129 8 SO3,gas 17.12 -29.00 -46.13 -11.531 0.78759E+05 -44.427 9 SO2,gas 0.83 -25.31 -26.14 -6.970 0.44629E+05 -24.439 10 HF,gas 0.47 -16.10 -16.58 -8.289 0.28307E+05 -14.879 11 HCl,gas 5.19 -13.96 -19.15 -9.575 0.32698E+05 -17.451 12 acmite 7.71 6.81 -0.90 -0.093 0.15296E+04 16 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 20 spessartine 24.46 19.70 -4.76 -0.238 0.81237E+04 21 analcite 3.32 2.76 -0.57 -0.063 0.96668E+03 27 annite 20.12 17.35 -2.77 -0.154 0.47345E+04 28 phlogopite 27.06 25.29 -1.78 -0.099 0.30335E+04 30 anorthite 12.71 8.06 -4.65 -0.357 0.79326E+04 33 apatite-OH -18.15 -18.88 -0.72 -0.056 0.12364E+04 34 apatite-F -34.30 -34.98 -0.68 -0.057 0.11635E+04 38 aragonite 0.97 -1.38 -2.34 -0.782 0.40034E+04 39 brucite 12.57 9.26 -3.31 -0.662 0.56523E+04 40 calcite 0.81 -1.38 -2.19 -0.730 0.37391E+04 41 carnegieite-low 9.02 5.90 -3.13 -0.447 0.53410E+04 42 carnegieite-high 10.09 5.90 -4.20 -0.600 0.71680E+04 43 carpholite-Mg 8.58 4.39 -4.19 -0.280 0.71608E+04 44 carpholite-Fe 6.71 1.74 -4.97 -0.331 0.84864E+04 45 celadonite 5.34 3.63 -1.71 -0.101 0.29191E+04 46 celadonite-Fe 3.88 0.99 -2.89 -0.170 0.49352E+04 47 chrysotile 23.89 21.50 -2.40 -0.200 0.40927E+04 49 clinochlore 39.07 38.28 -0.79 -0.025 0.13454E+04 50 daphnite 28.97 25.05 -3.91 -0.122 0.66809E+04 52 chlorite-Al-free 47.17 42.99 -4.18 -0.174 0.71405E+04 54 chloritoid-Fe 9.17 4.88 -4.29 -0.286 0.73277E+04 55 chloritoid-Mn 11.40 7.51 -3.90 -0.260 0.66507E+04 57 coesite -2.38 -3.14 -0.76 -0.255 0.13037E+04 64 cristobalite -2.56 -3.14 -0.58 -0.193 0.98904E+03 66 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71236E+04 68 diaspore 2.87 0.70 -2.17 -0.362 0.37036E+04 69 diamond -3.10 -6.91 -3.81 -1.089 0.65084E+04 70 diopside 16.18 15.91 -0.27 -0.027 0.45746E+03 71 hedenbergite 14.21 13.27 -0.94 -0.094 0.16061E+04 76 clinoenstatite 17.17 12.24 -4.93 -0.493 0.84162E+04 78 epidote 24.67 22.62 -2.05 -0.099 0.34966E+04 79 clinozoisite 22.81 18.56 -4.24 -0.193 0.72433E+04 80 epidote-Fe 29.84 26.68 -3.16 -0.164 0.53965E+04 81 fayalite 14.05 10.09 -3.96 -0.566 0.67625E+04 82 ferrosilite 11.15 6.95 -4.20 -0.420 0.71779E+04 86 gibbsite 4.08 0.70 -3.37 -0.482 0.57622E+04 87 glaucophane 22.97 20.73 -2.25 -0.061 0.38368E+04 88 glaucophane-Fe 17.28 12.79 -4.49 -0.121 0.76589E+04 89 graphite -3.55 -6.91 -3.37 -0.962 0.57507E+04 90 greenalite 16.14 13.56 -2.58 -0.215 0.44078E+04 93 hematite 12.57 9.53 -3.04 -0.369 0.51917E+04 94 heulandite -5.83 -7.63 -1.81 -0.082 0.30840E+04 98 jadeite 4.22 2.76 -1.46 -0.146 0.24922E+04 100 kalsilite 7.58 3.79 -3.79 -0.542 0.64737E+04 101 kaolinite -1.33 -4.87 -3.54 -0.322 0.60396E+04 104 laumontite 2.88 1.79 -1.10 -0.073 0.18750E+04 105 lawsonite 9.62 8.06 -1.55 -0.103 0.26493E+04 106 leucite 4.12 0.65 -3.47 -0.347 0.59179E+04 108 lizardite 23.24 21.50 -1.75 -0.146 0.29853E+04 110 magnetite 20.09 16.14 -3.95 -0.322 0.67435E+04 111 minnesotaite 10.39 7.28 -3.11 -0.183 0.53089E+04 115 manganosite 14.06 9.24 -4.82 -1.205 0.82330E+04 119 microcline -2.49 -2.49 0.00 0.000 0.21523E+00 123 muscovite 2.58 -1.08 -3.66 -0.215 0.62490E+04 124 paragonite 4.24 1.03 -3.21 -0.189 0.54879E+04 125 nepheline 8.34 5.90 -2.44 -0.349 0.41733E+04 137 phlogopite-Na 29.65 27.39 -2.26 -0.125 0.38521E+04 139 prehnite 19.37 17.86 -1.51 -0.089 0.25827E+04 140 prehnite-Fe 22.50 21.92 -0.58 -0.035 0.99101E+03 141 pumpellyite-Fe 46.27 43.04 -3.23 -0.072 0.55217E+04 142 pumpellyite-Mg 48.99 45.68 -3.31 -0.074 0.56577E+04 145 pyrite -21.25 -25.50 -4.26 -1.001 0.72660E+04 146 pyrrhotite -4.26 -7.60 -3.34 -1.112 0.56945E+04 147 pyrrhotiteFe0.875 -6.02 -8.88 -2.86 -1.053 0.48897E+04 148 pyroxmangite 7.40 6.10 -1.30 -0.260 0.22229E+04 149 pyrophyllite -6.18 -11.15 -4.97 -0.311 0.84917E+04 150 quartz -2.99 -3.14 -0.15 -0.050 0.25637E+03 154 rhodochrosite -0.98 -5.08 -4.10 -1.367 0.70003E+04 155 rhodonite 7.45 6.10 -1.35 -0.270 0.23032E+04 156 sanidine -1.28 -2.49 -1.21 -0.093 0.20680E+04 166 stilbite -7.52 -7.63 -0.11 -0.005 0.19016E+03 167 stilpnomelane-Fe 13.02 12.47 -0.55 -0.016 0.93678E+03 168 stilpnomelane-Mg 27.44 25.70 -1.74 -0.052 0.29778E+04 174 talc 16.49 15.22 -1.27 -0.075 0.21766E+04 177 tephroite 18.09 15.33 -2.75 -0.393 0.47000E+04 181 tridymite -2.63 -3.14 -0.51 -0.171 0.87634E+03 182 tremolite 47.87 47.04 -0.83 -0.022 0.14105E+04 183 ferroactinolite 38.45 33.81 -4.64 -0.125 0.79197E+04 184 troilite-low -4.41 -7.60 -3.18 -1.061 0.54373E+04 190 wairakite 3.95 1.79 -2.17 -0.127 0.36969E+04 191 walstromite 11.51 9.79 -1.71 -0.343 0.29273E+04 192 wollastonite 10.46 9.79 -0.67 -0.133 0.11378E+04 193 pseudo-wollastonite 11.00 9.79 -1.21 -0.241 0.20576E+04 194 zoisite 22.85 18.56 -4.29 -0.195 0.73174E+04 195 akaganeite 7.75 4.76 -2.99 -0.647 0.51084E+04 202 chalcedony -2.80 -3.14 -0.34 -0.112 0.57566E+03 204 montmorillonite-Ca -2.29 -6.19 -3.90 -0.241 0.66617E+04 205 montmorillonite-K -2.24 -6.27 -4.03 -0.247 0.68890E+04 206 montmorillonite-Mg -2.48 -6.80 -4.32 -0.267 0.73744E+04 207 montmorillonite-Na -2.04 -5.58 -3.54 -0.217 0.60438E+04 208 nontronite-Ca 3.21 0.37 -2.84 -0.185 0.48569E+04 209 nontronite-H 2.53 -1.76 -4.30 -0.288 0.73367E+04 210 nontronite-K 3.34 0.29 -3.05 -0.196 0.52074E+04 211 nontronite-Mg 3.07 -0.24 -3.31 -0.215 0.56537E+04 212 nontronite-Na 3.52 0.98 -2.53 -0.163 0.43282E+04 228 tobermorite 9.82 7.63 -2.19 -0.597 0.37364E+04 234 alabandite -0.98 -4.97 -3.99 -1.331 0.68189E+04 237 boehmite 4.41 0.70 -3.70 -0.617 0.63206E+04 239 ferrous-oxide 9.81 6.61 -3.20 -0.800 0.54625E+04 245 silica-amorphous -2.09 -3.14 -1.05 -0.349 0.17898E+04 247 an20ab80 2.02 1.31 -0.71 -0.055 0.12157E+04 248 an25ab75 2.65 1.73 -0.92 -0.071 0.15666E+04 249 an30ab70 3.28 2.15 -1.13 -0.087 0.19271E+04 250 tr.625ac.25prg.125 45.16 44.67 -0.50 -0.013 0.84637E+03 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 0.0001000 MOLES Current total amount of reactant added: 0.0024900 MOLES New total amount of reactant added: 0.0025900 MOLES Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.5508E-08 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 7 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 0.0025900 Water: Moles liquid = 0.4985E+02 kg liquid = 0.8981E+00 Moles total = 0.4985E+02 kg total = 0.8980E+00 Activity = 1.0000 Stoichiometric ionic strength = .1149555E-01 Osmotic coef. = 0.9623 True ionic strength = .2016877E-01 Chg. balance for total moles = -.5508E-08 Max. difference allowed = 0.1532E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.92472E-10 -10.0340 0.77664E-10 -10.1098 0.83986E+00 -0.0758 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.16976E-03 -3.7702 0.14172E-03 -3.8486 0.83479E+00 -0.0784 4 SO4-- 0.40973E-08 -8.3875 0.21236E-08 -8.6729 0.51830E+00 -0.2854 5 HCO3- 0.78258E-04 -4.1065 0.65425E-04 -4.1843 0.83601E+00 -0.0778 6 HS- 0.98452E-04 -4.0068 0.82199E-04 -4.0851 0.83491E+00 -0.0784 7 Al+++ 0.10283E-28 -28.9879 0.23652E-29 -29.6261 0.23000E+00 -0.6383 8 H4SiO4 0.72636E-03 -3.1388 0.72636E-03 -3.1388 0.10000E+01 0.0000 9 Ca++ 0.99463E-07 -7.0023 0.51171E-07 -7.2910 0.51447E+00 -0.2886 10 Mg++ 0.21272E-10 -10.6722 0.10894E-10 -10.9628 0.51210E+00 -0.2906 11 Fe++ 0.47785E-13 -13.3207 0.24498E-13 -13.6109 0.51267E+00 -0.2902 12 K+ 0.15653E-03 -3.8054 0.13090E-03 -3.8831 0.83621E+00 -0.0777 13 Na+ 0.19870E-01 -1.7018 0.16584E-01 -1.7803 0.83463E+00 -0.0785 14 Mn++ 0.20254E-10 -10.6935 0.10392E-10 -10.9833 0.51309E+00 -0.2898 15 F- 0.12608E-05 -5.8993 0.10503E-05 -5.9787 0.83306E+00 -0.0793 16 HPO4-- 0.45356E-07 -7.3434 0.23511E-07 -7.6287 0.51837E+00 -0.2854 18 HSiO3- 0.10461E-01 -1.9804 0.87329E-02 -2.0588 0.83479E+00 -0.0784 19 Ca(HSiO3)+ 0.12168E-07 -7.9148 0.10177E-07 -7.9924 0.83639E+00 -0.0776 20 Mg(HSiO3)+ 0.32237E-11 -11.4916 0.26963E-11 -11.5692 0.83639E+00 -0.0776 21 NaHSiO3,aq 0.23423E-02 -2.6303 0.23423E-02 -2.6303 0.10000E+01 0.0000 22 AlO+ 0.63781E-16 -16.1953 0.53346E-16 -16.2729 0.83639E+00 -0.0776 24 HAlO2,aq 0.13679E-09 -9.8639 0.13679E-09 -9.8639 0.10000E+01 0.0000 25 AlO2- 0.46790E-05 -5.3298 0.38989E-05 -5.4091 0.83327E+00 -0.0792 26 CH4,aq 0.24686E-05 -5.6076 0.24599E-05 -5.6091 0.99650E+00 -0.0015 27 C2H6,aq 0.57660E-15 -15.2391 0.57458E-15 -15.2406 0.99650E+00 -0.0015 31 CO,aq 0.49105E-15 -15.3089 0.49105E-15 -15.3089 0.10000E+01 0.0000 32 CO2,aq 0.10895E-07 -7.9628 0.10857E-07 -7.9643 0.99650E+00 -0.0015 33 CO3-2 0.14227E-03 -3.8469 0.73581E-04 -4.1332 0.51719E+00 -0.2864 34 CaCO3,aq 0.47211E-07 -7.3260 0.47211E-07 -7.3260 0.10000E+01 0.0000 35 Ca(HCO3)+ 0.10217E-09 -9.9907 0.85457E-10 -10.0683 0.83639E+00 -0.0776 36 CaCl+ 0.14031E-10 -10.8529 0.11736E-10 -10.9305 0.83639E+00 -0.0776 37 CaCl2,aq 0.39512E-15 -15.4033 0.39512E-15 -15.4033 0.10000E+01 0.0000 38 CaF+ 0.93819E-12 -12.0277 0.78469E-12 -12.1053 0.83639E+00 -0.0776 39 CaOH+ 0.56143E-07 -7.2507 0.46957E-07 -7.3283 0.83639E+00 -0.0776 40 CaSO4,aq 0.34507E-13 -13.4621 0.34507E-13 -13.4621 0.10000E+01 0.0000 41 HCl,aq 0.20169E-14 -14.6953 0.20169E-14 -14.6953 0.10000E+01 0.0000 45 HF,aq 0.55842E-12 -12.2530 0.55842E-12 -12.2530 0.10000E+01 0.0000 46 HF2- 0.23722E-18 -18.6249 0.19803E-18 -18.7033 0.83479E+00 -0.0784 48 FeCl+ 0.65701E-17 -17.1824 0.54952E-17 -17.2600 0.83639E+00 -0.0776 51 FeF+ 0.15721E-17 -17.8035 0.13149E-17 -17.8811 0.83639E+00 -0.0776 53 FeO,aq 0.15785E-09 -9.8018 0.15785E-09 -9.8018 0.10000E+01 0.0000 54 FeOH+ 0.12276E-10 -10.9109 0.10268E-10 -10.9885 0.83639E+00 -0.0776 55 HFeO2- 0.25475E-07 -7.5939 0.21266E-07 -7.6723 0.83479E+00 -0.0784 56 FeO+ 0.21822E-16 -16.6611 0.18252E-16 -16.7387 0.83639E+00 -0.0776 58 FeO2- 0.74172E-09 -9.1298 0.61918E-09 -9.2082 0.83479E+00 -0.0784 59 HFeO2,aq 0.61161E-11 -11.2135 0.61161E-11 -11.2135 0.10000E+01 0.0000 60 H2,aq 0.18068E-05 -5.7431 0.18004E-05 -5.7446 0.99650E+00 -0.0015 61 KCl,aq 0.33621E-09 -9.4734 0.33621E-09 -9.4734 0.10000E+01 0.0000 63 KOH,aq 0.71976E-06 -6.1428 0.71976E-06 -6.1428 0.10000E+01 0.0000 64 KSO4- 0.51671E-11 -11.2868 0.43134E-11 -11.3652 0.83479E+00 -0.0784 65 MgCO3,aq 0.25193E-11 -11.5987 0.25193E-11 -11.5987 0.10000E+01 0.0000 66 Mg(HCO3)+ 0.22226E-13 -13.6531 0.18590E-13 -13.7307 0.83639E+00 -0.0776 67 MgCl+ 0.27073E-14 -14.5675 0.22644E-14 -14.6451 0.83639E+00 -0.0776 68 MgF+ 0.73986E-15 -15.1309 0.61881E-15 -15.2084 0.83639E+00 -0.0776 69 MgOH+ 0.66137E-10 -10.1796 0.55317E-10 -10.2571 0.83639E+00 -0.0776 71 MnF+ 0.21982E-15 -15.6579 0.18386E-15 -15.7355 0.83639E+00 -0.0776 72 MnO,aq 0.17843E-08 -8.7485 0.17843E-08 -8.7485 0.10000E+01 0.0000 73 MnOH+ 0.48378E-09 -9.3153 0.40463E-09 -9.3929 0.83639E+00 -0.0776 74 MnO2-2 0.18982E-10 -10.7216 0.98176E-11 -11.0080 0.51719E+00 -0.2864 75 HMnO2- 0.20011E-09 -9.6987 0.16704E-09 -9.7772 0.83479E+00 -0.0784 78 MnCl+ 0.10843E-13 -13.9648 0.90693E-14 -14.0424 0.83639E+00 -0.0776 79 MnSO4,aq 0.63713E-17 -17.1958 0.63713E-17 -17.1958 0.10000E+01 0.0000 80 NaCl,aq 0.77886E-06 -6.1085 0.77886E-06 -6.1085 0.10000E+01 0.0000 81 NaF,aq 0.40780E-08 -8.3896 0.40780E-08 -8.3896 0.10000E+01 0.0000 82 NaOH,aq 0.91744E-04 -4.0374 0.91744E-04 -4.0374 0.10000E+01 0.0000 84 OH- 0.89280E-02 -2.0492 0.74394E-02 -2.1285 0.83327E+00 -0.0792 89 HPO3-2 0.25506E-15 -15.5934 0.13191E-15 -15.8797 0.51719E+00 -0.2864 91 H2PO3- 0.24610E-19 -19.6089 0.20544E-19 -19.6873 0.83479E+00 -0.0784 92 H3PO4,aq 0.99182E-18 -18.0036 0.99182E-18 -18.0036 0.10000E+01 0.0000 93 H2PO4- 0.40312E-10 -10.3946 0.33684E-10 -10.4726 0.83558E+00 -0.0780 94 PO4-3 0.10222E-08 -8.9905 0.24699E-09 -9.6073 0.24164E+00 -0.6168 98 HP2O7-3 0.99349E-18 -18.0028 0.22873E-18 -18.6407 0.23023E+00 -0.6378 99 P2O7-4 0.91960E-17 -17.0364 0.70359E-18 -18.1527 0.76510E-01 -1.1163 100 H2S,aq 0.19800E-07 -7.7033 0.19730E-07 -7.7049 0.99650E+00 -0.0015 101 S2-2 0.16078E-12 -12.7938 0.83154E-13 -13.0801 0.51719E+00 -0.2864 107 SO3-2 0.94690E-15 -15.0237 0.49685E-15 -15.3038 0.52471E+00 -0.2801 108 HSO3- 0.28942E-17 -17.5385 0.24160E-17 -17.6169 0.83479E+00 -0.0784 109 HSO4- 0.18985E-15 -15.7216 0.15894E-15 -15.7988 0.83721E+00 -0.0772 111 S2O3-2 0.95165E-18 -18.0215 0.49218E-18 -18.3079 0.51719E+00 -0.2864 Charge balance for all species = -.6133E-08 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.9247193E-10 -.2198568E-01 -.2212154E+02 0.0000 2 H2O 0.1000000E+01 0.5550448E+02 0.9981831E+06 0.0000 3 Cl- 0.1697645E-03 0.1705437E-03 0.6035725E+01 6.2612 4 SO4-- 0.4097303E-08 -.2916071E-05 -.2796331E+00 11.5466 5 HCO3- 0.7825834E-04 0.2230566E-03 0.1358652E+02 5.9255 6 HS- 0.9845238E-04 0.1013923E-03 0.3347390E+01 6.0246 7 Al+++ 0.1028342E-28 0.4679138E-05 0.1260296E+00 0.7032 8 H4SiO4 0.7263616E-03 0.1353001E-01 0.1298170E+04 -3.1388 9 Ca++ 0.9946287E-07 0.2151018E-06 0.8605791E-02 12.9286 10 Mg++ 0.2127237E-10 0.9317821E-10 0.2261391E-05 9.2567 11 Fe++ 0.4778472E-13 0.2639317E-07 0.1471405E-02 6.6087 12 K+ 0.1565336E-03 0.1572537E-03 0.6138191E+01 6.2267 13 Na+ 0.1986954E-01 0.2230442E-01 0.5118783E+03 8.3295 14 Mn++ 0.2025445E-10 0.2507450E-08 0.1375136E-03 9.2363 15 F- 0.1260814E-05 0.1264894E-05 0.2398847E-01 4.1311 16 HPO4-- 0.4535577E-07 0.4641824E-07 0.4447394E-02 12.5908 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.1974766E-01 -.1974532E-01 -.2337509E-05 0.0000000E+00 2 H2O 0.4984853E+02 0.4984853E+02 -.2292350E-05 0.0000000E+00 3 Cl- 0.1531652E-03 0.1531652E-03 0.0000000E+00 0.0000000E+00 4 SO4-- -.2617810E-05 -.2618921E-05 0.1111073E-08 0.0000000E+00 5 HCO3- 0.2003270E-03 0.2003270E-03 0.0000000E+00 0.0000000E+00 6 HS- 0.9105928E-04 0.9106039E-04 -.1111073E-08 0.0000000E+00 7 Al+++ 0.4775352E-05 0.4202330E-05 0.5730216E-06 0.0000000E+00 8 H4SiO4 0.1215302E-01 0.1215129E-01 0.1730830E-05 0.0000000E+00 9 Ca++ 0.2080835E-06 0.1931828E-06 0.1490072E-07 0.0000000E+00 10 Mg++ 0.8368328E-10 0.8368328E-10 0.0000000E+00 0.0000000E+00 11 Fe++ 0.3259227E-07 0.2370369E-07 0.8888582E-08 0.0000000E+00 12 K+ 0.1412294E-03 0.1412294E-03 0.0000000E+00 0.0000000E+00 13 Na+ 0.2003215E-01 0.2003158E-01 0.5719763E-06 0.0000000E+00 14 Mn++ 0.2251939E-08 0.2251939E-08 0.0000000E+00 0.0000000E+00 15 F- 0.1136000E-05 0.1136000E-05 0.0000000E+00 0.0000000E+00 16 HPO4-- 0.4168819E-07 0.4168819E-07 0.0000000E+00 0.0000000E+00 Chg. balance for solid moles: -.4235E-21 Mass of aqueous solution: 0.899671E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 0.0025900 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 0.5720E-06 -6.243 0.1500E-03 -3.824 98.36 0.5758E-04 andradite 0.4444E-08 -8.352 0.2258E-05 -5.646 1.481 0.5868E-06 grossular 0.5226E-09 -9.282 0.2354E-06 -6.628 0.1544 0.6550E-07 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8948E+00 0.8948E+00 1.0000 -0.048 grossular 0.1052E+00 0.1052E+00 1.0000 -0.978 Solid products produced: Mass = 0.000152 g Volume = 0.000058 cm3 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.0025900 moles log = -2.5867 Original solution: 1000.0103000 g Original solution / Rock added: 386104.36 (Water/Rock Ratio), log = 5.5867 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0263 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9942E+00 0.9859 0.1006E+01 0.1020E+01 CO2,gas 0.1124E-05 1.0071 0.1162E-05 0.1153E-05 CH4,gas 0.3484E-02 1.0125 0.3621E-02 0.3576E-02 H2,gas 0.2302E-02 1.0005 0.2364E-02 0.2362E-02 H2S,gas 0.5306E-06 0.9960 0.5424E-06 0.5445E-06 S2,gas 0.1926E-26 1.0000 0.1976E-26 0.1976E-26 CO,gas 0.7130E-12 1.0000 0.7318E-12 0.7318E-12 SO3,gas 0.4719E-44 1.0000 0.4843E-44 0.4843E-44 SO2,gas 0.4340E-24 1.0000 0.4454E-24 0.4454E-24 HF,gas 0.1336E-14 1.0000 0.1371E-14 0.1371E-14 HCl,gas 0.3468E-17 1.0000 0.3559E-17 0.3559E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 17 albite -0.38 -0.38 0.00 0.000 -0.94784E-12 23 andradite 39.01 39.01 0.00 0.000 0.00000E+00 24 grossular 32.73 32.73 0.00 0.000 0.12132E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -14.29 -7.63 -2.545 0.13035E+05 -5.935 3 CH4,gas 4.54 0.40 -4.14 -1.035 0.70692E+04 -2.441 4 H2,gas 8.00 3.67 -4.33 -2.472 0.73854E+04 -2.626 5 H2S,gas -6.23 -14.19 -7.96 -3.982 0.13599E+05 -6.266 6 S2,gas -7.34 -35.74 -28.40 -4.370 0.48498E+05 -26.704 7 CO,gas 3.21 -10.62 -13.83 -4.257 0.23622E+05 -12.136 8 SO3,gas 17.12 -28.89 -46.01 -11.503 0.78567E+05 -44.315 9 SO2,gas 0.83 -25.22 -26.05 -6.947 0.44480E+05 -24.351 10 HF,gas 0.47 -16.09 -16.56 -8.281 0.28279E+05 -14.863 11 HCl,gas 5.19 -13.96 -19.15 -9.574 0.32694E+05 -17.449 12 acmite 7.71 6.82 -0.89 -0.092 0.15136E+04 16 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 20 spessartine 24.46 19.70 -4.76 -0.238 0.81252E+04 21 analcite 3.32 2.75 -0.57 -0.063 0.96793E+03 27 annite 20.12 17.34 -2.78 -0.155 0.47535E+04 28 phlogopite 27.06 25.28 -1.78 -0.099 0.30410E+04 30 anorthite 12.71 8.06 -4.65 -0.358 0.79449E+04 33 apatite-OH -18.15 -18.90 -0.75 -0.058 0.12780E+04 34 apatite-F -34.30 -34.99 -0.69 -0.057 0.11772E+04 38 aragonite 0.97 -1.37 -2.33 -0.777 0.39818E+04 39 brucite 12.57 9.26 -3.31 -0.662 0.56549E+04 40 calcite 0.81 -1.37 -2.18 -0.726 0.37176E+04 41 carnegieite-low 9.02 5.89 -3.13 -0.447 0.53435E+04 42 carnegieite-high 10.09 5.89 -4.20 -0.600 0.71705E+04 43 carpholite-Mg 8.58 4.39 -4.20 -0.280 0.71656E+04 44 carpholite-Fe 6.71 1.74 -4.98 -0.332 0.84951E+04 45 celadonite 5.34 3.63 -1.71 -0.101 0.29204E+04 46 celadonite-Fe 3.88 0.98 -2.89 -0.170 0.49402E+04 47 chrysotile 23.89 21.49 -2.40 -0.200 0.40977E+04 49 clinochlore 39.07 38.27 -0.80 -0.025 0.13591E+04 50 daphnite 28.97 25.03 -3.93 -0.123 0.67137E+04 52 chlorite-Al-free 47.17 42.99 -4.19 -0.174 0.71506E+04 54 chloritoid-Fe 9.17 4.88 -4.30 -0.286 0.73376E+04 55 chloritoid-Mn 11.40 7.50 -3.90 -0.260 0.66544E+04 57 coesite -2.38 -3.14 -0.76 -0.254 0.13024E+04 64 cristobalite -2.56 -3.14 -0.58 -0.193 0.98779E+03 66 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71236E+04 68 diaspore 2.87 0.70 -2.17 -0.362 0.37060E+04 69 diamond -3.10 -6.95 -3.84 -1.098 0.65616E+04 70 diopside 16.18 15.91 -0.27 -0.027 0.46740E+03 71 hedenbergite 14.21 13.26 -0.95 -0.095 0.16199E+04 76 clinoenstatite 17.17 12.24 -4.93 -0.493 0.84187E+04 78 epidote 24.67 22.62 -2.05 -0.099 0.35027E+04 79 clinozoisite 22.81 18.55 -4.26 -0.193 0.72666E+04 80 epidote-Fe 29.84 26.69 -3.15 -0.164 0.53854E+04 81 fayalite 14.05 10.08 -3.97 -0.567 0.67739E+04 82 ferrosilite 11.15 6.94 -4.21 -0.421 0.71881E+04 86 gibbsite 4.08 0.70 -3.38 -0.482 0.57646E+04 87 glaucophane 22.97 20.72 -2.25 -0.061 0.38419E+04 88 glaucophane-Fe 17.28 12.78 -4.50 -0.121 0.76754E+04 89 graphite -3.55 -6.95 -3.40 -0.971 0.58038E+04 90 greenalite 16.14 13.55 -2.59 -0.216 0.44243E+04 93 hematite 12.57 9.54 -3.02 -0.366 0.51620E+04 94 heulandite -5.83 -7.64 -1.81 -0.082 0.30900E+04 98 jadeite 4.22 2.75 -1.46 -0.146 0.24934E+04 100 kalsilite 7.58 3.79 -3.79 -0.542 0.64762E+04 101 kaolinite -1.33 -4.87 -3.54 -0.322 0.60419E+04 104 laumontite 2.88 1.78 -1.10 -0.074 0.18847E+04 105 lawsonite 9.62 8.06 -1.56 -0.104 0.26615E+04 106 leucite 4.12 0.65 -3.47 -0.347 0.59192E+04 108 lizardite 23.24 21.49 -1.75 -0.146 0.29904E+04 110 magnetite 20.09 16.15 -3.94 -0.321 0.67202E+04 111 minnesotaite 10.39 7.27 -3.12 -0.183 0.53229E+04 115 manganosite 14.06 9.24 -4.82 -1.205 0.82332E+04 119 microcline -2.49 -2.49 0.00 0.000 0.22414E+00 123 muscovite 2.58 -1.08 -3.66 -0.215 0.62539E+04 124 paragonite 4.24 1.02 -3.22 -0.189 0.54927E+04 125 nepheline 8.34 5.89 -2.45 -0.349 0.41758E+04 137 phlogopite-Na 29.65 27.39 -2.26 -0.126 0.38596E+04 139 prehnite 19.37 17.85 -1.52 -0.090 0.26036E+04 140 prehnite-Fe 22.50 21.92 -0.58 -0.035 0.99467E+03 141 pumpellyite-Fe 46.27 43.01 -3.26 -0.073 0.55722E+04 142 pumpellyite-Mg 48.99 45.65 -3.34 -0.074 0.57044E+04 145 pyrite -21.25 -25.46 -4.21 -0.990 0.71861E+04 146 pyrrhotite -4.26 -7.59 -3.33 -1.109 0.56789E+04 147 pyrrhotiteFe0.875 -6.02 -8.87 -2.85 -1.049 0.48680E+04 148 pyroxmangite 7.40 6.10 -1.30 -0.260 0.22218E+04 149 pyrophyllite -6.18 -11.15 -4.97 -0.311 0.84916E+04 150 quartz -2.99 -3.14 -0.15 -0.050 0.25512E+03 154 rhodochrosite -0.98 -5.06 -4.08 -1.360 0.69689E+04 155 rhodonite 7.45 6.10 -1.35 -0.270 0.23021E+04 156 sanidine -1.28 -2.49 -1.21 -0.093 0.20680E+04 166 stilbite -7.52 -7.64 -0.11 -0.005 0.19615E+03 167 stilpnomelane-Fe 13.02 12.45 -0.56 -0.017 0.96395E+03 168 stilpnomelane-Mg 27.44 25.69 -1.75 -0.052 0.29859E+04 174 talc 16.49 15.21 -1.28 -0.075 0.21792E+04 177 tephroite 18.09 15.33 -2.75 -0.393 0.46991E+04 181 tridymite -2.63 -3.14 -0.51 -0.171 0.87509E+03 182 tremolite 47.87 47.03 -0.84 -0.023 0.14329E+04 183 ferroactinolite 38.45 33.79 -4.66 -0.126 0.79612E+04 184 troilite-low -4.41 -7.59 -3.18 -1.058 0.54217E+04 190 wairakite 3.95 1.78 -2.17 -0.128 0.37067E+04 191 walstromite 11.51 9.79 -1.72 -0.344 0.29360E+04 192 wollastonite 10.46 9.79 -0.67 -0.134 0.11464E+04 193 pseudo-wollastonite 11.00 9.79 -1.21 -0.242 0.20662E+04 194 zoisite 22.85 18.55 -4.30 -0.195 0.73407E+04 195 akaganeite 7.75 4.77 -2.98 -0.645 0.50936E+04 202 chalcedony -2.80 -3.14 -0.34 -0.112 0.57441E+03 204 montmorillonite-Ca -2.29 -6.19 -3.90 -0.241 0.66632E+04 205 montmorillonite-K -2.24 -6.27 -4.03 -0.247 0.68893E+04 206 montmorillonite-Mg -2.48 -6.80 -4.32 -0.267 0.73747E+04 207 montmorillonite-Na -2.04 -5.58 -3.54 -0.217 0.60441E+04 208 nontronite-Ca 3.21 0.39 -2.83 -0.183 0.48251E+04 209 nontronite-H 2.53 -1.74 -4.28 -0.287 0.73033E+04 210 nontronite-K 3.34 0.31 -3.03 -0.195 0.51744E+04 211 nontronite-Mg 3.07 -0.22 -3.29 -0.214 0.56206E+04 212 nontronite-Na 3.52 1.00 -2.52 -0.161 0.42952E+04 228 tobermorite 9.82 7.63 -2.19 -0.598 0.37434E+04 234 alabandite -0.98 -4.96 -3.98 -1.327 0.67971E+04 237 boehmite 4.41 0.70 -3.70 -0.617 0.63230E+04 239 ferrous-oxide 9.81 6.61 -3.20 -0.801 0.54689E+04 245 silica-amorphous -2.09 -3.14 -1.05 -0.349 0.17886E+04 247 an20ab80 2.02 1.30 -0.71 -0.055 0.12181E+04 248 an25ab75 2.65 1.73 -0.92 -0.071 0.15696E+04 249 an30ab70 3.28 2.15 -1.13 -0.087 0.19307E+04 250 tr.625ac.25prg.125 45.16 44.65 -0.51 -0.014 0.87463E+03 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 0.0001000 MOLES Current total amount of reactant added: 0.0025900 MOLES New total amount of reactant added: 0.0026900 MOLES Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.5508E-08 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 7 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 0.0026900 Water: Moles liquid = 0.4985E+02 kg liquid = 0.8981E+00 Moles total = 0.4985E+02 kg total = 0.8980E+00 Activity = 1.0000 Stoichiometric ionic strength = .1150194E-01 Osmotic coef. = 0.9621 True ionic strength = .2017457E-01 Chg. balance for total moles = -.5508E-08 Max. difference allowed = 0.1538E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.92641E-10 -10.0332 0.77804E-10 -10.1090 0.83985E+00 -0.0758 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.17042E-03 -3.7685 0.14226E-03 -3.8469 0.83477E+00 -0.0784 4 SO4-- 0.54929E-08 -8.2602 0.28467E-08 -8.5457 0.51826E+00 -0.2855 5 HCO3- 0.81384E-04 -4.0895 0.68037E-04 -4.1673 0.83600E+00 -0.0778 6 HS- 0.10116E-03 -3.9950 0.84454E-04 -4.0734 0.83489E+00 -0.0784 7 Al+++ 0.10307E-28 -28.9868 0.23703E-29 -29.6252 0.22996E+00 -0.6383 8 H4SiO4 0.72759E-03 -3.1381 0.72759E-03 -3.1381 0.10000E+01 0.0000 9 Ca++ 0.98440E-07 -7.0068 0.50641E-07 -7.2955 0.51443E+00 -0.2887 10 Mg++ 0.21279E-10 -10.6721 0.10896E-10 -10.9627 0.51206E+00 -0.2907 11 Fe++ 0.47368E-13 -13.3245 0.24282E-13 -13.6147 0.51263E+00 -0.2902 12 K+ 0.15653E-03 -3.8054 0.13089E-03 -3.8831 0.83620E+00 -0.0777 13 Na+ 0.19870E-01 -1.7018 0.16584E-01 -1.7803 0.83462E+00 -0.0785 14 Mn++ 0.20325E-10 -10.6920 0.10428E-10 -10.9818 0.51305E+00 -0.2898 15 F- 0.13052E-05 -5.8843 0.10873E-05 -5.9637 0.83304E+00 -0.0793 16 HPO4-- 0.45357E-07 -7.3434 0.23510E-07 -7.6287 0.51833E+00 -0.2854 18 HSiO3- 0.10460E-01 -1.9805 0.87319E-02 -2.0589 0.83477E+00 -0.0784 19 Ca(HSiO3)+ 0.12040E-07 -7.9194 0.10070E-07 -7.9970 0.83638E+00 -0.0776 20 Mg(HSiO3)+ 0.32241E-11 -11.4916 0.26965E-11 -11.5692 0.83638E+00 -0.0776 21 NaHSiO3,aq 0.23421E-02 -2.6304 0.23421E-02 -2.6304 0.10000E+01 0.0000 22 AlO+ 0.63690E-16 -16.1959 0.53269E-16 -16.2735 0.83638E+00 -0.0776 24 HAlO2,aq 0.13635E-09 -9.8654 0.13635E-09 -9.8654 0.10000E+01 0.0000 25 AlO2- 0.46555E-05 -5.3320 0.38792E-05 -5.4113 0.83325E+00 -0.0792 26 CH4,aq 0.19676E-05 -5.7061 0.19607E-05 -5.7076 0.99649E+00 -0.0015 27 C2H6,aq 0.39167E-15 -15.4071 0.39030E-15 -15.4086 0.99649E+00 -0.0015 31 CO,aq 0.47845E-15 -15.3202 0.47845E-15 -15.3202 0.10000E+01 0.0000 32 CO2,aq 0.11351E-07 -7.9450 0.11311E-07 -7.9465 0.99649E+00 -0.0015 33 CO3-2 0.14770E-03 -3.8306 0.76381E-04 -4.1170 0.51715E+00 -0.2864 34 CaCO3,aq 0.48500E-07 -7.3143 0.48500E-07 -7.3143 0.10000E+01 0.0000 35 Ca(HCO3)+ 0.10515E-09 -9.9782 0.87948E-10 -10.0558 0.83638E+00 -0.0776 36 CaCl+ 0.13939E-10 -10.8558 0.11659E-10 -10.9334 0.83638E+00 -0.0776 37 CaCl2,aq 0.39403E-15 -15.4045 0.39403E-15 -15.4045 0.10000E+01 0.0000 38 CaF+ 0.96116E-12 -12.0172 0.80389E-12 -12.0948 0.83638E+00 -0.0776 39 CaOH+ 0.55462E-07 -7.2560 0.46387E-07 -7.3336 0.83638E+00 -0.0776 40 CaSO4,aq 0.45777E-13 -13.3393 0.45777E-13 -13.3393 0.10000E+01 0.0000 41 HCl,aq 0.20282E-14 -14.6929 0.20282E-14 -14.6929 0.10000E+01 0.0000 45 HF,aq 0.57912E-12 -12.2372 0.57912E-12 -12.2372 0.10000E+01 0.0000 46 HF2- 0.25467E-18 -18.5940 0.21259E-18 -18.6725 0.83477E+00 -0.0784 48 FeCl+ 0.65374E-17 -17.1846 0.54677E-17 -17.2622 0.83638E+00 -0.0776 51 FeF+ 0.16131E-17 -17.7923 0.13492E-17 -17.8699 0.83638E+00 -0.0776 53 FeO,aq 0.15590E-09 -9.8072 0.15590E-09 -9.8072 0.10000E+01 0.0000 54 FeOH+ 0.12146E-10 -10.9156 0.10159E-10 -10.9931 0.83638E+00 -0.0776 55 HFeO2- 0.25115E-07 -7.6001 0.20965E-07 -7.6785 0.83477E+00 -0.0784 56 FeO+ 0.22327E-16 -16.6512 0.18673E-16 -16.7288 0.83638E+00 -0.0776 58 FeO2- 0.75614E-09 -9.1214 0.63120E-09 -9.1998 0.83477E+00 -0.0784 59 HFeO2,aq 0.62461E-11 -11.2044 0.62461E-11 -11.2044 0.10000E+01 0.0000 60 H2,aq 0.16898E-05 -5.7722 0.16838E-05 -5.7737 0.99649E+00 -0.0015 61 KCl,aq 0.33749E-09 -9.4717 0.33749E-09 -9.4717 0.10000E+01 0.0000 63 KOH,aq 0.71846E-06 -6.1436 0.71846E-06 -6.1436 0.10000E+01 0.0000 64 KSO4- 0.69266E-11 -11.1595 0.57822E-11 -11.2379 0.83477E+00 -0.0784 65 MgCO3,aq 0.26157E-11 -11.5824 0.26157E-11 -11.5824 0.10000E+01 0.0000 66 Mg(HCO3)+ 0.23119E-13 -13.6360 0.19336E-13 -13.7136 0.83638E+00 -0.0776 67 MgCl+ 0.27183E-14 -14.5657 0.22735E-14 -14.6433 0.83638E+00 -0.0776 68 MgF+ 0.76607E-15 -15.1157 0.64073E-15 -15.1933 0.83638E+00 -0.0776 69 MgOH+ 0.66033E-10 -10.1802 0.55229E-10 -10.2578 0.83638E+00 -0.0776 71 MnF+ 0.22833E-15 -15.6414 0.19097E-15 -15.7190 0.83638E+00 -0.0776 72 MnO,aq 0.17839E-08 -8.7486 0.17839E-08 -8.7486 0.10000E+01 0.0000 73 MnOH+ 0.48456E-09 -9.3146 0.40528E-09 -9.3922 0.83638E+00 -0.0776 74 MnO2-2 0.18911E-10 -10.7233 0.97801E-11 -11.0097 0.51715E+00 -0.2864 75 HMnO2- 0.19971E-09 -9.6996 0.16671E-09 -9.7780 0.83477E+00 -0.0784 78 MnCl+ 0.10922E-13 -13.9617 0.91350E-14 -14.0393 0.83638E+00 -0.0776 79 MnSO4,aq 0.85699E-17 -17.0670 0.85699E-17 -17.0670 0.10000E+01 0.0000 80 NaCl,aq 0.78185E-06 -6.1069 0.78185E-06 -6.1069 0.10000E+01 0.0000 81 NaF,aq 0.42215E-08 -8.3745 0.42215E-08 -8.3745 0.10000E+01 0.0000 82 NaOH,aq 0.91578E-04 -4.0382 0.91578E-04 -4.0382 0.10000E+01 0.0000 84 OH- 0.89120E-02 -2.0500 0.74260E-02 -2.1292 0.83325E+00 -0.0792 89 HPO3-2 0.23855E-15 -15.6224 0.12337E-15 -15.9088 0.51715E+00 -0.2864 91 H2PO3- 0.23058E-19 -19.6372 0.19248E-19 -19.7156 0.83477E+00 -0.0784 92 H3PO4,aq 0.99537E-18 -18.0020 0.99537E-18 -18.0020 0.10000E+01 0.0000 93 H2PO4- 0.40384E-10 -10.3938 0.33744E-10 -10.4718 0.83557E+00 -0.0780 94 PO4-3 0.10204E-08 -8.9912 0.24654E-09 -9.6081 0.24160E+00 -0.6169 98 HP2O7-3 0.99537E-18 -18.0020 0.22913E-18 -18.6399 0.23019E+00 -0.6379 99 P2O7-4 0.91980E-17 -17.0363 0.70353E-18 -18.1527 0.76487E-01 -1.1164 100 H2S,aq 0.20380E-07 -7.6908 0.20308E-07 -7.6923 0.99649E+00 -0.0015 101 S2-2 0.18149E-12 -12.7411 0.93859E-13 -13.0275 0.51715E+00 -0.2864 107 SO3-2 0.11872E-14 -14.9255 0.62291E-15 -15.2056 0.52468E+00 -0.2801 108 HSO3- 0.36351E-17 -17.4395 0.30345E-17 -17.5179 0.83477E+00 -0.0784 109 HSO4- 0.25496E-15 -15.5935 0.21345E-15 -15.6707 0.83720E+00 -0.0772 111 S2O3-2 0.13132E-17 -17.8817 0.67911E-18 -18.1681 0.51715E+00 -0.2864 Charge balance for all species = -.6132E-08 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.9264072E-10 -.2197355E-01 -.2210933E+02 0.0000 2 H2O 0.1000000E+01 0.5550447E+02 0.9981824E+06 0.0000 3 Cl- 0.1704182E-03 0.1712004E-03 0.6058961E+01 6.2621 4 SO4-- 0.5492893E-08 -.2384431E-05 -.2286521E+00 11.6723 5 HCO3- 0.8138389E-04 0.2311065E-03 0.1407683E+02 5.9417 6 HS- 0.1011559E-03 0.1035662E-03 0.3419158E+01 6.0356 7 Al+++ 0.1030746E-28 0.4655608E-05 0.1253958E+00 0.7018 8 H4SiO4 0.7275881E-03 0.1352991E-01 0.1298161E+04 -3.1381 9 Ca++ 0.9844016E-07 0.2145625E-06 0.8584210E-02 12.9225 10 Mg++ 0.2127855E-10 0.9317803E-10 0.2261386E-05 9.2553 11 Fe++ 0.4736841E-13 0.2604578E-07 0.1452037E-02 6.6033 12 K+ 0.1565346E-03 0.1572534E-03 0.6138177E+01 6.2259 13 Na+ 0.1986992E-01 0.2230435E-01 0.5118766E+03 8.3287 14 Mn++ 0.2032494E-10 0.2507445E-08 0.1375133E-03 9.2362 15 F- 0.1305207E-05 0.1309430E-05 0.2483308E-01 4.1453 16 HPO4-- 0.4535733E-07 0.4641816E-07 0.4447384E-02 12.5892 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.1973689E-01 -.1973447E-01 -.2423549E-05 0.0000000E+00 2 H2O 0.4984861E+02 0.4984861E+02 -.2376961E-05 0.0000000E+00 3 Cl- 0.1537552E-03 0.1537552E-03 0.0000000E+00 0.0000000E+00 4 SO4-- -.2140310E-05 -.2141460E-05 0.1150067E-08 0.0000000E+00 5 HCO3- 0.2075570E-03 0.2075570E-03 0.0000000E+00 0.0000000E+00 6 HS- 0.9301178E-04 0.9301293E-04 -.1150067E-08 0.0000000E+00 7 Al+++ 0.4775352E-05 0.4181206E-05 0.5941461E-06 0.0000000E+00 8 H4SiO4 0.1215302E-01 0.1215123E-01 0.1794655E-05 0.0000000E+00 9 Ca++ 0.2080835E-06 0.1926988E-06 0.1538473E-07 0.0000000E+00 10 Mg++ 0.8368328E-10 0.8368328E-10 0.0000000E+00 0.0000000E+00 11 Fe++ 0.3259227E-07 0.2339174E-07 0.9200534E-08 0.0000000E+00 12 K+ 0.1412294E-03 0.1412294E-03 0.0000000E+00 0.0000000E+00 13 Na+ 0.2003215E-01 0.2003156E-01 0.5930902E-06 0.0000000E+00 14 Mn++ 0.2251939E-08 0.2251939E-08 0.0000000E+00 0.0000000E+00 15 F- 0.1176000E-05 0.1176000E-05 0.0000000E+00 0.0000000E+00 16 HPO4-- 0.4168819E-07 0.4168819E-07 0.0000000E+00 0.0000000E+00 Chg. balance for solid moles: 0.4235E-21 Mass of aqueous solution: 0.899673E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 0.0026900 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 0.5931E-06 -6.227 0.1555E-03 -3.808 98.37 0.5970E-04 andradite 0.4600E-08 -8.337 0.2338E-05 -5.631 1.479 0.6074E-06 grossular 0.5280E-09 -9.277 0.2378E-06 -6.624 0.1504 0.6617E-07 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8970E+00 0.8970E+00 1.0000 -0.047 grossular 0.1030E+00 0.1030E+00 1.0000 -0.987 Solid products produced: Mass = 0.000158 g Volume = 0.000060 cm3 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.0026900 moles log = -2.5702 Original solution: 1000.0103000 g Original solution / Rock added: 371751.04 (Water/Rock Ratio), log = 5.5703 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0254 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9951E+00 0.9859 0.1006E+01 0.1020E+01 CO2,gas 0.1172E-05 1.0071 0.1210E-05 0.1202E-05 CH4,gas 0.2780E-02 1.0125 0.2886E-02 0.2850E-02 H2,gas 0.2155E-02 1.0005 0.2211E-02 0.2209E-02 H2S,gas 0.5466E-06 0.9960 0.5583E-06 0.5605E-06 S2,gas 0.2334E-26 1.0000 0.2394E-26 0.2394E-26 CO,gas 0.6953E-12 1.0000 0.7130E-12 0.7130E-12 SO3,gas 0.6354E-44 1.0000 0.6516E-44 0.6516E-44 SO2,gas 0.5465E-24 1.0000 0.5604E-24 0.5604E-24 HF,gas 0.1387E-14 1.0000 0.1422E-14 0.1422E-14 HCl,gas 0.3490E-17 1.0000 0.3579E-17 0.3579E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 17 albite -0.38 -0.38 0.00 0.000 -0.94784E-12 23 andradite 39.01 39.01 0.00 0.000 0.00000E+00 24 grossular 32.73 32.73 0.00 0.000 0.00000E+00 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -14.28 -7.62 -2.539 0.13004E+05 -5.917 3 CH4,gas 4.54 0.31 -4.24 -1.060 0.72374E+04 -2.540 4 H2,gas 8.00 3.65 -4.35 -2.488 0.74351E+04 -2.655 5 H2S,gas -6.23 -14.18 -7.95 -3.976 0.13578E+05 -6.253 6 S2,gas -7.34 -35.66 -28.32 -4.357 0.48355E+05 -26.621 7 CO,gas 3.21 -10.63 -13.85 -4.260 0.23641E+05 -12.147 8 SO3,gas 17.12 -28.76 -45.89 -11.471 0.78347E+05 -44.186 9 SO2,gas 0.83 -25.12 -25.95 -6.920 0.44310E+05 -24.252 10 HF,gas 0.47 -16.07 -16.55 -8.273 0.28252E+05 -14.847 11 HCl,gas 5.19 -13.96 -19.15 -9.573 0.32690E+05 -17.446 12 acmite 7.71 6.83 -0.88 -0.091 0.14968E+04 16 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 20 spessartine 24.46 19.70 -4.76 -0.238 0.81268E+04 21 analcite 3.32 2.75 -0.57 -0.063 0.96918E+03 27 annite 20.12 17.32 -2.80 -0.156 0.47812E+04 28 phlogopite 27.06 25.28 -1.79 -0.099 0.30486E+04 30 anorthite 12.71 8.05 -4.66 -0.358 0.79576E+04 33 apatite-OH -18.15 -18.93 -0.77 -0.060 0.13220E+04 34 apatite-F -34.30 -35.00 -0.70 -0.058 0.11942E+04 38 aragonite 0.97 -1.35 -2.32 -0.773 0.39618E+04 39 brucite 12.57 9.26 -3.31 -0.663 0.56574E+04 40 calcite 0.81 -1.35 -2.17 -0.722 0.36976E+04 41 carnegieite-low 9.02 5.89 -3.13 -0.447 0.53460E+04 42 carnegieite-high 10.09 5.89 -4.20 -0.600 0.71730E+04 43 carpholite-Mg 8.58 4.38 -4.20 -0.280 0.71705E+04 44 carpholite-Fe 6.71 1.73 -4.98 -0.332 0.85066E+04 45 celadonite 5.34 3.63 -1.71 -0.101 0.29216E+04 46 celadonite-Fe 3.88 0.98 -2.90 -0.170 0.49482E+04 47 chrysotile 23.89 21.49 -2.40 -0.200 0.41028E+04 49 clinochlore 39.07 38.27 -0.80 -0.025 0.13728E+04 50 daphnite 28.97 25.01 -3.96 -0.124 0.67609E+04 52 chlorite-Al-free 47.17 42.98 -4.19 -0.175 0.71608E+04 54 chloritoid-Fe 9.17 4.87 -4.30 -0.287 0.73504E+04 55 chloritoid-Mn 11.40 7.50 -3.90 -0.260 0.66581E+04 57 coesite -2.38 -3.14 -0.76 -0.254 0.13012E+04 64 cristobalite -2.56 -3.14 -0.58 -0.193 0.98654E+03 66 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71236E+04 68 diaspore 2.87 0.70 -2.17 -0.362 0.37085E+04 69 diamond -3.10 -6.99 -3.88 -1.109 0.66305E+04 70 diopside 16.18 15.90 -0.28 -0.028 0.47782E+03 71 hedenbergite 14.21 13.25 -0.96 -0.096 0.16370E+04 76 clinoenstatite 17.17 12.23 -4.93 -0.493 0.84212E+04 78 epidote 24.67 22.61 -2.06 -0.100 0.35090E+04 79 clinozoisite 22.81 18.54 -4.27 -0.194 0.72909E+04 80 epidote-Fe 29.84 26.69 -3.15 -0.163 0.53736E+04 81 fayalite 14.05 10.07 -3.98 -0.568 0.67911E+04 82 ferrosilite 11.15 6.93 -4.22 -0.422 0.72040E+04 86 gibbsite 4.08 0.70 -3.38 -0.483 0.57670E+04 87 glaucophane 22.97 20.72 -2.25 -0.061 0.38469E+04 88 glaucophane-Fe 17.28 12.77 -4.51 -0.122 0.77006E+04 89 graphite -3.55 -6.99 -3.44 -0.983 0.58728E+04 90 greenalite 16.14 13.53 -2.61 -0.217 0.44495E+04 93 hematite 12.57 9.56 -3.00 -0.364 0.51308E+04 94 heulandite -5.83 -7.64 -1.81 -0.082 0.30964E+04 98 jadeite 4.22 2.75 -1.46 -0.146 0.24947E+04 100 kalsilite 7.58 3.79 -3.79 -0.542 0.64787E+04 101 kaolinite -1.33 -4.87 -3.54 -0.322 0.60442E+04 104 laumontite 2.88 1.77 -1.11 -0.074 0.18949E+04 105 lawsonite 9.62 8.05 -1.57 -0.104 0.26743E+04 106 leucite 4.12 0.65 -3.47 -0.347 0.59205E+04 108 lizardite 23.24 21.49 -1.75 -0.146 0.29954E+04 110 magnetite 20.09 16.16 -3.92 -0.320 0.66982E+04 111 minnesotaite 10.39 7.26 -3.13 -0.184 0.53456E+04 115 manganosite 14.06 9.24 -4.82 -1.205 0.82333E+04 119 microcline -2.49 -2.49 0.00 0.000 0.23306E+00 123 muscovite 2.58 -1.08 -3.67 -0.216 0.62587E+04 124 paragonite 4.24 1.02 -3.22 -0.189 0.54976E+04 125 nepheline 8.34 5.89 -2.45 -0.350 0.41783E+04 137 phlogopite-Na 29.65 27.38 -2.26 -0.126 0.38672E+04 139 prehnite 19.37 17.83 -1.54 -0.090 0.26255E+04 140 prehnite-Fe 22.50 21.91 -0.58 -0.035 0.99854E+03 141 pumpellyite-Fe 46.27 42.97 -3.30 -0.073 0.56276E+04 142 pumpellyite-Mg 48.99 45.63 -3.37 -0.075 0.57531E+04 145 pyrite -21.25 -25.41 -4.16 -0.979 0.71028E+04 146 pyrrhotite -4.26 -7.58 -3.32 -1.106 0.56667E+04 147 pyrrhotiteFe0.875 -6.02 -8.86 -2.84 -1.044 0.48485E+04 148 pyroxmangite 7.40 6.10 -1.30 -0.260 0.22208E+04 149 pyrophyllite -6.18 -11.15 -4.97 -0.311 0.84914E+04 150 quartz -2.99 -3.14 -0.15 -0.050 0.25387E+03 154 rhodochrosite -0.98 -5.04 -4.06 -1.355 0.69387E+04 155 rhodonite 7.45 6.10 -1.35 -0.270 0.23010E+04 156 sanidine -1.28 -2.49 -1.21 -0.093 0.20680E+04 166 stilbite -7.52 -7.64 -0.12 -0.006 0.20262E+03 167 stilpnomelane-Fe 13.02 12.43 -0.59 -0.018 0.10056E+04 168 stilpnomelane-Mg 27.44 25.69 -1.75 -0.052 0.29940E+04 174 talc 16.49 15.21 -1.28 -0.075 0.21817E+04 177 tephroite 18.09 15.33 -2.75 -0.393 0.46982E+04 181 tridymite -2.63 -3.14 -0.51 -0.171 0.87384E+03 182 tremolite 47.87 47.02 -0.85 -0.023 0.14563E+04 183 ferroactinolite 38.45 33.76 -4.70 -0.127 0.80181E+04 184 troilite-low -4.41 -7.58 -3.17 -1.056 0.54095E+04 190 wairakite 3.95 1.77 -2.18 -0.128 0.37169E+04 191 walstromite 11.51 9.78 -1.72 -0.345 0.29451E+04 192 wollastonite 10.46 9.78 -0.68 -0.135 0.11556E+04 193 pseudo-wollastonite 11.00 9.78 -1.22 -0.243 0.20754E+04 194 zoisite 22.85 18.54 -4.31 -0.196 0.73650E+04 195 akaganeite 7.75 4.78 -2.97 -0.643 0.50780E+04 202 chalcedony -2.80 -3.14 -0.34 -0.112 0.57316E+03 204 montmorillonite-Ca -2.29 -6.19 -3.90 -0.241 0.66648E+04 205 montmorillonite-K -2.24 -6.27 -4.03 -0.247 0.68896E+04 206 montmorillonite-Mg -2.48 -6.80 -4.32 -0.267 0.73750E+04 207 montmorillonite-Na -2.04 -5.58 -3.54 -0.217 0.60444E+04 208 nontronite-Ca 3.21 0.41 -2.81 -0.182 0.47918E+04 209 nontronite-H 2.53 -1.72 -4.26 -0.285 0.72683E+04 210 nontronite-K 3.34 0.33 -3.01 -0.193 0.51398E+04 211 nontronite-Mg 3.07 -0.20 -3.27 -0.212 0.55861E+04 212 nontronite-Na 3.52 1.02 -2.50 -0.160 0.42606E+04 228 tobermorite 9.82 7.63 -2.20 -0.599 0.37509E+04 234 alabandite -0.98 -4.95 -3.97 -1.323 0.67758E+04 237 boehmite 4.41 0.70 -3.70 -0.617 0.63254E+04 239 ferrous-oxide 9.81 6.60 -3.21 -0.802 0.54781E+04 245 silica-amorphous -2.09 -3.14 -1.05 -0.349 0.17873E+04 247 an20ab80 2.02 1.30 -0.71 -0.055 0.12207E+04 248 an25ab75 2.65 1.72 -0.92 -0.071 0.15728E+04 249 an30ab70 3.28 2.15 -1.13 -0.087 0.19346E+04 250 tr.625ac.25prg.125 45.16 44.63 -0.53 -0.014 0.90748E+03 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 0.0001000 MOLES Current total amount of reactant added: 0.0026900 MOLES New total amount of reactant added: 0.0027900 MOLES Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.5508E-08 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 7 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 0.0027900 Water: Moles liquid = 0.4985E+02 kg liquid = 0.8981E+00 Moles total = 0.4985E+02 kg total = 0.8980E+00 Activity = 1.0000 Stoichiometric ionic strength = .1150833E-01 Osmotic coef. = 0.9619 True ionic strength = .2018036E-01 Chg. balance for total moles = -.5508E-08 Max. difference allowed = 0.1543E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.92810E-10 -10.0324 0.77945E-10 -10.1082 0.83984E+00 -0.0758 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.17107E-03 -3.7668 0.14280E-03 -3.8453 0.83475E+00 -0.0784 4 SO4-- 0.78300E-08 -8.1062 0.40577E-08 -8.3917 0.51822E+00 -0.2855 5 HCO3- 0.84515E-04 -4.0731 0.70653E-04 -4.1509 0.83598E+00 -0.0778 6 HS- 0.10386E-03 -3.9836 0.86709E-04 -4.0619 0.83488E+00 -0.0784 7 Al+++ 0.10332E-28 -28.9858 0.23755E-29 -29.6243 0.22992E+00 -0.6384 8 H4SiO4 0.72882E-03 -3.1374 0.72882E-03 -3.1374 0.10000E+01 0.0000 9 Ca++ 0.97327E-07 -7.0118 0.50064E-07 -7.3005 0.51439E+00 -0.2887 10 Mg++ 0.21285E-10 -10.6719 0.10898E-10 -10.9626 0.51202E+00 -0.2907 11 Fe++ 0.46670E-13 -13.3310 0.23923E-13 -13.6212 0.51259E+00 -0.2902 12 K+ 0.15654E-03 -3.8054 0.13089E-03 -3.8831 0.83618E+00 -0.0777 13 Na+ 0.19870E-01 -1.7018 0.16584E-01 -1.7803 0.83460E+00 -0.0785 14 Mn++ 0.20396E-10 -10.6905 0.10463E-10 -10.9803 0.51301E+00 -0.2899 15 F- 0.13496E-05 -5.8698 0.11242E-05 -5.9491 0.83302E+00 -0.0793 16 HPO4-- 0.45359E-07 -7.3433 0.23509E-07 -7.6288 0.51829E+00 -0.2854 18 HSiO3- 0.10459E-01 -1.9805 0.87309E-02 -2.0589 0.83475E+00 -0.0784 19 Ca(HSiO3)+ 0.11902E-07 -7.9244 0.99545E-08 -8.0020 0.83636E+00 -0.0776 20 Mg(HSiO3)+ 0.32244E-11 -11.4915 0.26968E-11 -11.5692 0.83636E+00 -0.0776 21 NaHSiO3,aq 0.23418E-02 -2.6305 0.23418E-02 -2.6305 0.10000E+01 0.0000 22 AlO+ 0.63599E-16 -16.1965 0.53192E-16 -16.2742 0.83636E+00 -0.0776 24 HAlO2,aq 0.13590E-09 -9.8668 0.13590E-09 -9.8668 0.10000E+01 0.0000 25 AlO2- 0.46320E-05 -5.3342 0.38596E-05 -5.4135 0.83324E+00 -0.0792 26 CH4,aq 0.14717E-05 -5.8322 0.14666E-05 -5.8337 0.99649E+00 -0.0015 27 C2H6,aq 0.23798E-15 -15.6235 0.23715E-15 -15.6250 0.99649E+00 -0.0015 31 CO,aq 0.45834E-15 -15.3388 0.45834E-15 -15.3388 0.10000E+01 0.0000 32 CO2,aq 0.11809E-07 -7.9278 0.11767E-07 -7.9293 0.99649E+00 -0.0015 33 CO3-2 0.15311E-03 -3.8150 0.79174E-04 -4.1014 0.51711E+00 -0.2864 34 CaCO3,aq 0.49702E-07 -7.3036 0.49702E-07 -7.3036 0.10000E+01 0.0000 35 Ca(HCO3)+ 0.10796E-09 -9.9668 0.90290E-10 -10.0444 0.83636E+00 -0.0776 36 CaCl+ 0.13833E-10 -10.8591 0.11570E-10 -10.9367 0.83636E+00 -0.0776 37 CaCl2,aq 0.39253E-15 -15.4061 0.39253E-15 -15.4061 0.10000E+01 0.0000 38 CaF+ 0.98254E-12 -12.0077 0.82176E-12 -12.0853 0.83636E+00 -0.0776 39 CaOH+ 0.54733E-07 -7.2618 0.45776E-07 -7.3394 0.83636E+00 -0.0776 40 CaSO4,aq 0.64507E-13 -13.1904 0.64507E-13 -13.1904 0.10000E+01 0.0000 41 HCl,aq 0.20397E-14 -14.6904 0.20397E-14 -14.6904 0.10000E+01 0.0000 45 HF,aq 0.59989E-12 -12.2219 0.59989E-12 -12.2219 0.10000E+01 0.0000 46 HF2- 0.27278E-18 -18.5642 0.22770E-18 -18.6426 0.83475E+00 -0.0784 48 FeCl+ 0.64653E-17 -17.1894 0.54073E-17 -17.2670 0.83636E+00 -0.0776 51 FeF+ 0.16433E-17 -17.7843 0.13744E-17 -17.8619 0.83636E+00 -0.0776 53 FeO,aq 0.15304E-09 -9.8152 0.15304E-09 -9.8152 0.10000E+01 0.0000 54 FeOH+ 0.11945E-10 -10.9228 0.99905E-11 -11.0004 0.83636E+00 -0.0776 55 HFeO2- 0.24610E-07 -7.6089 0.20543E-07 -7.6873 0.83475E+00 -0.0784 56 FeO+ 0.22881E-16 -16.6405 0.19137E-16 -16.7181 0.83636E+00 -0.0776 58 FeO2- 0.77212E-09 -9.1123 0.64453E-09 -9.1908 0.83475E+00 -0.0784 59 HFeO2,aq 0.63895E-11 -11.1945 0.63895E-11 -11.1945 0.10000E+01 0.0000 60 H2,aq 0.15560E-05 -5.8080 0.15505E-05 -5.8095 0.99649E+00 -0.0015 61 KCl,aq 0.33877E-09 -9.4701 0.33877E-09 -9.4701 0.10000E+01 0.0000 63 KOH,aq 0.71715E-06 -6.1444 0.71715E-06 -6.1444 0.10000E+01 0.0000 64 KSO4- 0.98731E-11 -11.0055 0.82416E-11 -11.0840 0.83475E+00 -0.0784 65 MgCO3,aq 0.27119E-11 -11.5667 0.27119E-11 -11.5667 0.10000E+01 0.0000 66 Mg(HCO3)+ 0.24013E-13 -13.6196 0.20084E-13 -13.6972 0.83636E+00 -0.0776 67 MgCl+ 0.27293E-14 -14.5639 0.22827E-14 -14.6416 0.83636E+00 -0.0776 68 MgF+ 0.79230E-15 -15.1011 0.66265E-15 -15.1787 0.83636E+00 -0.0776 69 MgOH+ 0.65929E-10 -10.1809 0.55141E-10 -10.2585 0.83636E+00 -0.0776 71 MnF+ 0.23690E-15 -15.6254 0.19814E-15 -15.7030 0.83636E+00 -0.0776 72 MnO,aq 0.17835E-08 -8.7487 0.17835E-08 -8.7487 0.10000E+01 0.0000 73 MnOH+ 0.48534E-09 -9.3139 0.40592E-09 -9.3916 0.83636E+00 -0.0776 74 MnO2-2 0.18841E-10 -10.7249 0.97427E-11 -11.0113 0.51711E+00 -0.2864 75 HMnO2- 0.19931E-09 -9.7005 0.16637E-09 -9.7789 0.83475E+00 -0.0784 78 MnCl+ 0.11001E-13 -13.9586 0.92011E-14 -14.0362 0.83636E+00 -0.0776 79 MnSO4,aq 0.12257E-16 -16.9116 0.12257E-16 -16.9116 0.10000E+01 0.0000 80 NaCl,aq 0.78483E-06 -6.1052 0.78483E-06 -6.1052 0.10000E+01 0.0000 81 NaF,aq 0.43650E-08 -8.3600 0.43650E-08 -8.3600 0.10000E+01 0.0000 82 NaOH,aq 0.91413E-04 -4.0390 0.91413E-04 -4.0390 0.10000E+01 0.0000 84 OH- 0.88961E-02 -2.0508 0.74126E-02 -2.1300 0.83324E+00 -0.0792 89 HPO3-2 0.21968E-15 -15.6582 0.11360E-15 -15.9446 0.51711E+00 -0.2864 91 H2PO3- 0.21270E-19 -19.6722 0.17756E-19 -19.7507 0.83475E+00 -0.0784 92 H3PO4,aq 0.99894E-18 -18.0005 0.99894E-18 -18.0005 0.10000E+01 0.0000 93 H2PO4- 0.40456E-10 -10.3930 0.33803E-10 -10.4710 0.83555E+00 -0.0780 94 PO4-3 0.10187E-08 -8.9919 0.24608E-09 -9.6089 0.24156E+00 -0.6170 98 HP2O7-3 0.99726E-18 -18.0012 0.22952E-18 -18.6392 0.23015E+00 -0.6380 99 P2O7-4 0.92000E-17 -17.0362 0.70347E-18 -18.1528 0.76464E-01 -1.1165 100 H2S,aq 0.20962E-07 -7.6786 0.20888E-07 -7.6801 0.99649E+00 -0.0015 101 S2-2 0.20777E-12 -12.6824 0.10744E-12 -12.9688 0.51711E+00 -0.2864 107 SO3-2 0.15584E-14 -14.8073 0.81759E-15 -15.0875 0.52464E+00 -0.2801 108 HSO3- 0.47800E-17 -17.3206 0.39901E-17 -17.3990 0.83475E+00 -0.0784 109 HSO4- 0.36408E-15 -15.4388 0.30480E-15 -15.5160 0.83718E+00 -0.0772 111 S2O3-2 0.19253E-17 -17.7155 0.99562E-18 -18.0019 0.51711E+00 -0.2864 Charge balance for all species = -.6132E-08 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.9280993E-10 -.2196143E-01 -.2209712E+02 0.0000 2 H2O 0.1000000E+01 0.5550445E+02 0.9981818E+06 0.0000 3 Cl- 0.1710718E-03 0.1718570E-03 0.6082197E+01 6.2629 4 SO4-- 0.7830003E-08 -.1852812E-05 -.1776730E+00 11.8247 5 HCO3- 0.8451460E-04 0.2391564E-03 0.1456715E+02 5.9573 6 HS- 0.1038585E-03 0.1057401E-03 0.3490926E+01 6.0463 7 Al+++ 0.1033157E-28 0.4632181E-05 0.1247648E+00 0.7004 8 H4SiO4 0.7288174E-03 0.1352981E-01 0.1298151E+04 -3.1374 9 Ca++ 0.9732721E-07 0.2137864E-06 0.8553159E-02 12.9159 10 Mg++ 0.2128474E-10 0.9317785E-10 0.2261381E-05 9.2538 11 Fe++ 0.4667048E-13 0.2555355E-07 0.1424595E-02 6.5952 12 K+ 0.1565356E-03 0.1572531E-03 0.6138163E+01 6.2251 13 Na+ 0.1987029E-01 0.2230428E-01 0.5118749E+03 8.3279 14 Mn++ 0.2039570E-10 0.2507440E-08 0.1375130E-03 9.2361 15 F- 0.1349599E-05 0.1353965E-05 0.2567768E-01 4.1591 16 HPO4-- 0.4535889E-07 0.4641807E-07 0.4447374E-02 12.5877 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.1972613E-01 -.1972362E-01 -.2509876E-05 0.0000000E+00 2 H2O 0.4984869E+02 0.4984870E+02 -.2461220E-05 0.0000000E+00 3 Cl- 0.1543452E-03 0.1543452E-03 0.0000000E+00 0.0000000E+00 4 SO4-- -.1662810E-05 -.1664015E-05 0.1205319E-08 0.0000000E+00 5 HCO3- 0.2147870E-03 0.2147870E-03 0.0000000E+00 0.0000000E+00 6 HS- 0.9496428E-04 0.9496549E-04 -.1205319E-08 0.0000000E+00 7 Al+++ 0.4775352E-05 0.4160174E-05 0.6151781E-06 0.0000000E+00 8 H4SiO4 0.1215302E-01 0.1215116E-01 0.1858381E-05 0.0000000E+00 9 Ca++ 0.2080835E-06 0.1920022E-06 0.1608133E-07 0.0000000E+00 10 Mg++ 0.8368328E-10 0.8368328E-10 0.0000000E+00 0.0000000E+00 11 Fe++ 0.3259227E-07 0.2294972E-07 0.9642554E-08 0.0000000E+00 12 K+ 0.1412294E-03 0.1412294E-03 0.0000000E+00 0.0000000E+00 13 Na+ 0.2003215E-01 0.2003154E-01 0.6140997E-06 0.0000000E+00 14 Mn++ 0.2251939E-08 0.2251939E-08 0.0000000E+00 0.0000000E+00 15 F- 0.1216000E-05 0.1216000E-05 0.0000000E+00 0.0000000E+00 16 HPO4-- 0.4168819E-07 0.4168819E-07 0.0000000E+00 0.0000000E+00 Chg. balance for solid moles: -.3176E-21 Mass of aqueous solution: 0.899675E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 0.0027900 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 0.6141E-06 -6.212 0.1610E-03 -3.793 98.36 0.6182E-04 andradite 0.4821E-08 -8.317 0.2450E-05 -5.611 1.496 0.6365E-06 grossular 0.5392E-09 -9.268 0.2429E-06 -6.615 0.1483 0.6758E-07 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8994E+00 0.8994E+00 1.0000 -0.046 grossular 0.1006E+00 0.1006E+00 1.0000 -0.997 Solid products produced: Mass = 0.000164 g Volume = 0.000063 cm3 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.0027900 moles log = -2.5544 Original solution: 1000.0103000 g Original solution / Rock added: 358426.63 (Water/Rock Ratio), log = 5.5544 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0245 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9959E+00 0.9859 0.1006E+01 0.1020E+01 CO2,gas 0.1220E-05 1.0071 0.1259E-05 0.1250E-05 CH4,gas 0.2081E-02 1.0125 0.2159E-02 0.2132E-02 H2,gas 0.1986E-02 1.0005 0.2036E-02 0.2035E-02 H2S,gas 0.5627E-06 0.9960 0.5742E-06 0.5765E-06 S2,gas 0.2915E-26 1.0000 0.2986E-26 0.2986E-26 CO,gas 0.6667E-12 1.0000 0.6830E-12 0.6830E-12 SO3,gas 0.9098E-44 1.0000 0.9321E-44 0.9321E-44 SO2,gas 0.7205E-24 1.0000 0.7382E-24 0.7382E-24 HF,gas 0.1438E-14 1.0000 0.1473E-14 0.1473E-14 HCl,gas 0.3513E-17 1.0000 0.3599E-17 0.3599E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 17 albite -0.38 -0.38 0.00 0.000 -0.13080E-10 23 andradite 39.01 39.01 0.00 0.000 0.00000E+00 24 grossular 32.73 32.73 0.00 0.000 0.12132E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -14.26 -7.60 -2.533 0.12975E+05 -5.900 3 CH4,gas 4.54 0.18 -4.36 -1.091 0.74527E+04 -2.666 4 H2,gas 8.00 3.61 -4.39 -2.509 0.74963E+04 -2.691 5 H2S,gas -6.23 -14.17 -7.94 -3.970 0.13557E+05 -6.241 6 S2,gas -7.34 -35.56 -28.22 -4.342 0.48191E+05 -26.525 7 CO,gas 3.21 -10.65 -13.86 -4.266 0.23673E+05 -12.166 8 SO3,gas 17.12 -28.61 -45.73 -11.432 0.78082E+05 -44.031 9 SO2,gas 0.83 -25.00 -25.83 -6.888 0.44105E+05 -24.132 10 HF,gas 0.47 -16.06 -16.53 -8.265 0.28226E+05 -14.832 11 HCl,gas 5.19 -13.95 -19.14 -9.571 0.32686E+05 -17.444 12 acmite 7.71 6.84 -0.87 -0.090 0.14788E+04 16 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 20 spessartine 24.46 19.70 -4.76 -0.238 0.81283E+04 21 analcite 3.32 2.75 -0.57 -0.063 0.97044E+03 27 annite 20.12 17.30 -2.82 -0.157 0.48225E+04 28 phlogopite 27.06 25.27 -1.79 -0.099 0.30562E+04 30 anorthite 12.71 8.04 -4.67 -0.359 0.79711E+04 33 apatite-OH -18.15 -18.96 -0.80 -0.062 0.13699E+04 34 apatite-F -34.30 -35.01 -0.71 -0.059 0.12160E+04 38 aragonite 0.97 -1.34 -2.31 -0.770 0.39437E+04 39 brucite 12.57 9.25 -3.31 -0.663 0.56599E+04 40 calcite 0.81 -1.34 -2.15 -0.718 0.36794E+04 41 carnegieite-low 9.02 5.89 -3.13 -0.447 0.53485E+04 42 carnegieite-high 10.09 5.89 -4.20 -0.600 0.71755E+04 43 carpholite-Mg 8.58 4.38 -4.20 -0.280 0.71753E+04 44 carpholite-Fe 6.71 1.72 -4.99 -0.333 0.85227E+04 45 celadonite 5.34 3.63 -1.71 -0.101 0.29229E+04 46 celadonite-Fe 3.88 0.97 -2.91 -0.171 0.49607E+04 47 chrysotile 23.89 21.49 -2.41 -0.200 0.41079E+04 49 clinochlore 39.07 38.26 -0.81 -0.025 0.13865E+04 50 daphnite 28.97 24.96 -4.00 -0.125 0.68307E+04 52 chlorite-Al-free 47.17 42.97 -4.20 -0.175 0.71709E+04 54 chloritoid-Fe 9.17 4.86 -4.32 -0.288 0.73678E+04 55 chloritoid-Mn 11.40 7.50 -3.90 -0.260 0.66619E+04 57 coesite -2.38 -3.14 -0.76 -0.254 0.12999E+04 64 cristobalite -2.56 -3.14 -0.58 -0.192 0.98528E+03 66 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71236E+04 68 diaspore 2.87 0.70 -2.17 -0.362 0.37109E+04 69 diamond -3.10 -7.04 -3.94 -1.125 0.67235E+04 70 diopside 16.18 15.89 -0.29 -0.029 0.48900E+03 71 hedenbergite 14.21 13.24 -0.97 -0.097 0.16594E+04 76 clinoenstatite 17.17 12.23 -4.93 -0.493 0.84238E+04 78 epidote 24.67 22.61 -2.06 -0.100 0.35155E+04 79 clinozoisite 22.81 18.52 -4.29 -0.195 0.73167E+04 80 epidote-Fe 29.84 26.70 -3.14 -0.163 0.53609E+04 81 fayalite 14.05 10.05 -3.99 -0.570 0.68173E+04 82 ferrosilite 11.15 6.92 -4.23 -0.423 0.72290E+04 86 gibbsite 4.08 0.70 -3.38 -0.483 0.57694E+04 87 glaucophane 22.97 20.72 -2.26 -0.061 0.38520E+04 88 glaucophane-Fe 17.28 12.74 -4.53 -0.123 0.77393E+04 89 graphite -3.55 -7.04 -3.49 -0.998 0.59658E+04 90 greenalite 16.14 13.51 -2.63 -0.219 0.44882E+04 93 hematite 12.57 9.58 -2.99 -0.362 0.50972E+04 94 heulandite -5.83 -7.64 -1.82 -0.083 0.31037E+04 98 jadeite 4.22 2.75 -1.46 -0.146 0.24959E+04 100 kalsilite 7.58 3.79 -3.80 -0.542 0.64812E+04 101 kaolinite -1.33 -4.87 -3.54 -0.322 0.60466E+04 104 laumontite 2.88 1.77 -1.12 -0.074 0.19059E+04 105 lawsonite 9.62 8.04 -1.57 -0.105 0.26878E+04 106 leucite 4.12 0.65 -3.47 -0.347 0.59217E+04 108 lizardite 23.24 21.49 -1.76 -0.146 0.30005E+04 110 magnetite 20.09 16.18 -3.91 -0.319 0.66783E+04 111 minnesotaite 10.39 7.24 -3.15 -0.185 0.53818E+04 115 manganosite 14.06 9.24 -4.82 -1.206 0.82335E+04 119 microcline -2.49 -2.49 0.00 0.000 0.24201E+00 123 muscovite 2.58 -1.09 -3.67 -0.216 0.62635E+04 124 paragonite 4.24 1.02 -3.22 -0.190 0.55024E+04 125 nepheline 8.34 5.89 -2.45 -0.350 0.41808E+04 137 phlogopite-Na 29.65 27.38 -2.27 -0.126 0.38748E+04 139 prehnite 19.37 17.82 -1.55 -0.091 0.26489E+04 140 prehnite-Fe 22.50 21.91 -0.59 -0.035 0.10027E+04 141 pumpellyite-Fe 46.27 42.94 -3.33 -0.074 0.56906E+04 142 pumpellyite-Mg 48.99 45.60 -3.40 -0.076 0.58048E+04 145 pyrite -21.25 -25.35 -4.11 -0.967 0.70137E+04 146 pyrrhotite -4.26 -7.57 -3.31 -1.105 0.56596E+04 147 pyrrhotiteFe0.875 -6.02 -8.85 -2.83 -1.041 0.48321E+04 148 pyroxmangite 7.40 6.10 -1.30 -0.260 0.22197E+04 149 pyrophyllite -6.18 -11.15 -4.97 -0.311 0.84912E+04 150 quartz -2.99 -3.14 -0.15 -0.049 0.25261E+03 154 rhodochrosite -0.98 -5.02 -4.05 -1.349 0.69096E+04 155 rhodonite 7.45 6.10 -1.35 -0.269 0.22999E+04 156 sanidine -1.28 -2.49 -1.21 -0.093 0.20680E+04 166 stilbite -7.52 -7.64 -0.12 -0.006 0.20985E+03 167 stilpnomelane-Fe 13.02 12.39 -0.63 -0.019 0.10698E+04 168 stilpnomelane-Mg 27.44 25.68 -1.76 -0.052 0.30021E+04 174 talc 16.49 15.21 -1.28 -0.075 0.21843E+04 177 tephroite 18.09 15.33 -2.75 -0.393 0.46972E+04 181 tridymite -2.63 -3.14 -0.51 -0.170 0.87259E+03 182 tremolite 47.87 47.00 -0.87 -0.023 0.14812E+04 183 ferroactinolite 38.45 33.71 -4.74 -0.128 0.80991E+04 184 troilite-low -4.41 -7.57 -3.16 -1.055 0.54024E+04 190 wairakite 3.95 1.77 -2.18 -0.128 0.37279E+04 191 walstromite 11.51 9.78 -1.73 -0.346 0.29551E+04 192 wollastonite 10.46 9.78 -0.68 -0.137 0.11655E+04 193 pseudo-wollastonite 11.00 9.78 -1.22 -0.244 0.20853E+04 194 zoisite 22.85 18.52 -4.33 -0.197 0.73908E+04 195 akaganeite 7.75 4.79 -2.96 -0.641 0.50611E+04 202 chalcedony -2.80 -3.14 -0.33 -0.112 0.57191E+03 204 montmorillonite-Ca -2.29 -6.20 -3.90 -0.242 0.66665E+04 205 montmorillonite-K -2.24 -6.27 -4.04 -0.247 0.68899E+04 206 montmorillonite-Mg -2.48 -6.80 -4.32 -0.267 0.73752E+04 207 montmorillonite-Na -2.04 -5.58 -3.54 -0.217 0.60447E+04 208 nontronite-Ca 3.21 0.43 -2.79 -0.181 0.47562E+04 209 nontronite-H 2.53 -1.70 -4.23 -0.284 0.72308E+04 210 nontronite-K 3.34 0.35 -2.99 -0.192 0.51028E+04 211 nontronite-Mg 3.07 -0.18 -3.25 -0.211 0.55490E+04 212 nontronite-Na 3.52 1.05 -2.47 -0.159 0.42236E+04 228 tobermorite 9.82 7.62 -2.20 -0.601 0.37589E+04 234 alabandite -0.98 -4.93 -3.96 -1.319 0.67551E+04 237 boehmite 4.41 0.70 -3.71 -0.618 0.63278E+04 239 ferrous-oxide 9.81 6.60 -3.22 -0.804 0.54918E+04 245 silica-amorphous -2.09 -3.14 -1.05 -0.349 0.17861E+04 247 an20ab80 2.02 1.30 -0.72 -0.055 0.12234E+04 248 an25ab75 2.65 1.72 -0.92 -0.071 0.15762E+04 249 an30ab70 3.28 2.14 -1.14 -0.087 0.19386E+04 250 tr.625ac.25prg.125 45.16 44.61 -0.55 -0.015 0.94751E+03 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 0.0001000 MOLES Current total amount of reactant added: 0.0027900 MOLES New total amount of reactant added: 0.0028900 MOLES Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.5508E-08 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 7 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 0.0028900 Water: Moles liquid = 0.4985E+02 kg liquid = 0.8981E+00 Moles total = 0.4985E+02 kg total = 0.8980E+00 Activity = 1.0000 Stoichiometric ionic strength = .1151471E-01 Osmotic coef. = 0.9617 True ionic strength = .2018613E-01 Chg. balance for total moles = -.5508E-08 Max. difference allowed = 0.1549E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.92980E-10 -10.0316 0.78086E-10 -10.1074 0.83982E+00 -0.0758 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.17173E-03 -3.7652 0.14335E-03 -3.8436 0.83474E+00 -0.0784 4 SO4-- 0.12446E-07 -7.9050 0.64492E-08 -8.1905 0.51818E+00 -0.2855 5 HCO3- 0.87649E-04 -4.0573 0.73272E-04 -4.1351 0.83597E+00 -0.0778 6 HS- 0.10656E-03 -3.9724 0.88962E-04 -4.0508 0.83486E+00 -0.0784 7 Al+++ 0.10356E-28 -28.9848 0.23806E-29 -29.6233 0.22988E+00 -0.6385 8 H4SiO4 0.73005E-03 -3.1366 0.73005E-03 -3.1366 0.10000E+01 0.0000 9 Ca++ 0.96052E-07 -7.0175 0.49404E-07 -7.3062 0.51435E+00 -0.2887 10 Mg++ 0.21291E-10 -10.6718 0.10901E-10 -10.9625 0.51198E+00 -0.2907 11 Fe++ 0.45492E-13 -13.3421 0.23317E-13 -13.6323 0.51255E+00 -0.2903 12 K+ 0.15654E-03 -3.8054 0.13089E-03 -3.8831 0.83617E+00 -0.0777 13 Na+ 0.19871E-01 -1.7018 0.16584E-01 -1.7803 0.83458E+00 -0.0785 14 Mn++ 0.20467E-10 -10.6890 0.10499E-10 -10.9789 0.51297E+00 -0.2899 15 F- 0.13940E-05 -5.8557 0.11612E-05 -5.9351 0.83301E+00 -0.0794 16 HPO4-- 0.45360E-07 -7.3433 0.23508E-07 -7.6288 0.51825E+00 -0.2855 18 HSiO3- 0.10458E-01 -1.9805 0.87298E-02 -2.0590 0.83474E+00 -0.0784 19 Ca(HSiO3)+ 0.11744E-07 -7.9302 0.98221E-08 -8.0078 0.83635E+00 -0.0776 20 Mg(HSiO3)+ 0.32248E-11 -11.4915 0.26971E-11 -11.5691 0.83635E+00 -0.0776 21 NaHSiO3,aq 0.23415E-02 -2.6305 0.23415E-02 -2.6305 0.10000E+01 0.0000 22 AlO+ 0.63508E-16 -16.1972 0.53115E-16 -16.2748 0.83635E+00 -0.0776 24 HAlO2,aq 0.13546E-09 -9.8682 0.13546E-09 -9.8682 0.10000E+01 0.0000 25 AlO2- 0.46087E-05 -5.3364 0.38401E-05 -5.4157 0.83322E+00 -0.0792 26 CH4,aq 0.98526E-06 -6.0064 0.98180E-06 -6.0080 0.99649E+00 -0.0015 27 C2H6,aq 0.11904E-15 -15.9243 0.11862E-15 -15.9258 0.99649E+00 -0.0015 31 CO,aq 0.42664E-15 -15.3699 0.42664E-15 -15.3699 0.10000E+01 0.0000 32 CO2,aq 0.12269E-07 -7.9112 0.12225E-07 -7.9127 0.99649E+00 -0.0015 33 CO3-2 0.15851E-03 -3.7999 0.81961E-04 -4.0864 0.51707E+00 -0.2864 34 CaCO3,aq 0.50773E-07 -7.2944 0.50773E-07 -7.2944 0.10000E+01 0.0000 35 Ca(HCO3)+ 0.11048E-09 -9.9567 0.92403E-10 -10.0343 0.83635E+00 -0.0776 36 CaCl+ 0.13703E-10 -10.8632 0.11461E-10 -10.9408 0.83635E+00 -0.0776 37 CaCl2,aq 0.39031E-15 -15.4086 0.39031E-15 -15.4086 0.10000E+01 0.0000 38 CaF+ 0.10015E-11 -11.9994 0.83759E-12 -12.0770 0.83635E+00 -0.0776 39 CaOH+ 0.53915E-07 -7.2683 0.45092E-07 -7.3459 0.83635E+00 -0.0776 40 CaSO4,aq 0.10118E-12 -12.9949 0.10118E-12 -12.9949 0.10000E+01 0.0000 41 HCl,aq 0.20511E-14 -14.6880 0.20511E-14 -14.6880 0.10000E+01 0.0000 45 HF,aq 0.62073E-12 -12.2071 0.62073E-12 -12.2071 0.10000E+01 0.0000 46 HF2- 0.29154E-18 -18.5353 0.24336E-18 -18.6138 0.83474E+00 -0.0784 48 FeCl+ 0.63255E-17 -17.1989 0.52903E-17 -17.2765 0.83635E+00 -0.0776 51 FeF+ 0.16543E-17 -17.7814 0.13836E-17 -17.8590 0.83635E+00 -0.0776 53 FeO,aq 0.14862E-09 -9.8279 0.14862E-09 -9.8279 0.10000E+01 0.0000 54 FeOH+ 0.11622E-10 -10.9347 0.97198E-11 -11.0123 0.83635E+00 -0.0776 55 HFeO2- 0.23857E-07 -7.6224 0.19915E-07 -7.7008 0.83474E+00 -0.0784 56 FeO+ 0.23519E-16 -16.6286 0.19670E-16 -16.7062 0.83635E+00 -0.0776 58 FeO2- 0.79077E-09 -9.1019 0.66009E-09 -9.1804 0.83474E+00 -0.0784 59 HFeO2,aq 0.65556E-11 -11.1834 0.65556E-11 -11.1834 0.10000E+01 0.0000 60 H2,aq 0.13941E-05 -5.8557 0.13892E-05 -5.8572 0.99649E+00 -0.0015 61 KCl,aq 0.34006E-09 -9.4684 0.34006E-09 -9.4684 0.10000E+01 0.0000 63 KOH,aq 0.71585E-06 -6.1452 0.71585E-06 -6.1452 0.10000E+01 0.0000 64 KSO4- 0.15692E-10 -10.8043 0.13099E-10 -10.8828 0.83474E+00 -0.0784 65 MgCO3,aq 0.28080E-11 -11.5516 0.28080E-11 -11.5516 0.10000E+01 0.0000 66 Mg(HCO3)+ 0.24909E-13 -13.6036 0.20833E-13 -13.6813 0.83635E+00 -0.0776 67 MgCl+ 0.27403E-14 -14.5622 0.22919E-14 -14.6398 0.83635E+00 -0.0776 68 MgF+ 0.81853E-15 -15.0870 0.68458E-15 -15.1646 0.83635E+00 -0.0776 69 MgOH+ 0.65825E-10 -10.1816 0.55053E-10 -10.2592 0.83635E+00 -0.0776 71 MnF+ 0.24553E-15 -15.6099 0.20535E-15 -15.6875 0.83635E+00 -0.0776 72 MnO,aq 0.17832E-08 -8.7488 0.17832E-08 -8.7488 0.10000E+01 0.0000 73 MnOH+ 0.48613E-09 -9.3133 0.40657E-09 -9.3909 0.83635E+00 -0.0776 74 MnO2-2 0.18770E-10 -10.7265 0.97054E-11 -11.0130 0.51707E+00 -0.2864 75 HMnO2- 0.19891E-09 -9.7014 0.16603E-09 -9.7798 0.83474E+00 -0.0784 78 MnCl+ 0.11081E-13 -13.9554 0.92675E-14 -14.0330 0.83635E+00 -0.0776 79 MnSO4,aq 0.19547E-16 -16.7089 0.19547E-16 -16.7089 0.10000E+01 0.0000 80 NaCl,aq 0.78781E-06 -6.1036 0.78781E-06 -6.1036 0.10000E+01 0.0000 81 NaF,aq 0.45084E-08 -8.3460 0.45084E-08 -8.3460 0.10000E+01 0.0000 82 NaOH,aq 0.91248E-04 -4.0398 0.91248E-04 -4.0398 0.10000E+01 0.0000 84 OH- 0.88802E-02 -2.0516 0.73992E-02 -2.1308 0.83322E+00 -0.0792 89 HPO3-2 0.19682E-15 -15.7059 0.10177E-15 -15.9924 0.51707E+00 -0.2864 91 H2PO3- 0.19091E-19 -19.7192 0.15936E-19 -19.7976 0.83474E+00 -0.0784 92 H3PO4,aq 0.10025E-17 -17.9989 0.10025E-17 -17.9989 0.10000E+01 0.0000 93 H2PO4- 0.40529E-10 -10.3922 0.33863E-10 -10.4703 0.83553E+00 -0.0780 94 PO4-3 0.10170E-08 -8.9927 0.24563E-09 -9.6097 0.24152E+00 -0.6170 98 HP2O7-3 0.99916E-18 -18.0004 0.22992E-18 -18.6384 0.23011E+00 -0.6381 99 P2O7-4 0.92020E-17 -17.0361 0.70342E-18 -18.1528 0.76441E-01 -1.1167 100 H2S,aq 0.21545E-07 -7.6666 0.21470E-07 -7.6682 0.99649E+00 -0.0015 101 S2-2 0.24413E-12 -12.6124 0.12623E-12 -12.8988 0.51707E+00 -0.2864 107 SO3-2 0.22193E-14 -14.6538 0.11642E-14 -14.9340 0.52460E+00 -0.2802 108 HSO3- 0.68191E-17 -17.1663 0.56922E-17 -17.2447 0.83474E+00 -0.0784 109 HSO4- 0.57971E-15 -15.2368 0.48532E-15 -15.3140 0.83717E+00 -0.0772 111 S2O3-2 0.31455E-17 -17.5023 0.16265E-17 -17.7888 0.51707E+00 -0.2864 Charge balance for all species = -.6132E-08 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.9297951E-10 -.2194930E-01 -.2208490E+02 0.0000 2 H2O 0.1000000E+01 0.5550443E+02 0.9981812E+06 0.0000 3 Cl- 0.1717254E-03 0.1725136E-03 0.6105433E+01 6.2638 4 SO4-- 0.1244580E-07 -.1321225E-05 -.1266972E+00 12.0244 5 HCO3- 0.8764897E-04 0.2472062E-03 0.1505747E+02 5.9724 6 HS- 0.1065588E-03 0.1079140E-03 0.3562694E+01 6.0566 7 Al+++ 0.1035574E-28 0.4608864E-05 0.1241367E+00 0.6990 8 H4SiO4 0.7300492E-03 0.1352972E-01 0.1298141E+04 -3.1366 9 Ca++ 0.9605196E-07 0.2126090E-06 0.8506048E-02 12.9086 10 Mg++ 0.2129096E-10 0.9317767E-10 0.2261376E-05 9.2523 11 Fe++ 0.4549156E-13 0.2481483E-07 0.1383412E-02 6.5825 12 K+ 0.1565366E-03 0.1572528E-03 0.6138149E+01 6.2243 13 Na+ 0.1987067E-01 0.2230422E-01 0.5118732E+03 8.3271 14 Mn++ 0.2046671E-10 0.2507436E-08 0.1375127E-03 9.2360 15 F- 0.1393991E-05 0.1398501E-05 0.2652228E-01 4.1723 16 HPO4-- 0.4536044E-07 0.4641798E-07 0.4447363E-02 12.5861 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.1971536E-01 -.1971276E-01 -.2596925E-05 0.0000000E+00 2 H2O 0.4984877E+02 0.4984878E+02 -.2545118E-05 0.0000000E+00 3 Cl- 0.1549352E-03 0.1549352E-03 0.0000000E+00 0.0000000E+00 4 SO4-- -.1185310E-05 -.1186598E-05 0.1288245E-08 0.0000000E+00 5 HCO3- 0.2220170E-03 0.2220170E-03 0.0000000E+00 0.0000000E+00 6 HS- 0.9691678E-04 0.9691807E-04 -.1288245E-08 0.0000000E+00 7 Al+++ 0.4775352E-05 0.4139241E-05 0.6361110E-06 0.0000000E+00 8 H4SiO4 0.1215302E-01 0.1215110E-01 0.1922112E-05 0.0000000E+00 9 Ca++ 0.2080835E-06 0.1909451E-06 0.1713844E-07 0.0000000E+00 10 Mg++ 0.8368328E-10 0.8368328E-10 0.0000000E+00 0.0000000E+00 11 Fe++ 0.3259227E-07 0.2228631E-07 0.1030596E-07 0.0000000E+00 12 K+ 0.1412294E-03 0.1412294E-03 0.0000000E+00 0.0000000E+00 13 Na+ 0.2003215E-01 0.2003152E-01 0.6349913E-06 0.0000000E+00 14 Mn++ 0.2251939E-08 0.2251939E-08 0.0000000E+00 0.0000000E+00 15 F- 0.1256000E-05 0.1256000E-05 0.0000000E+00 0.0000000E+00 16 HPO4-- 0.4168819E-07 0.4168819E-07 0.0000000E+00 0.0000000E+00 Chg. balance for solid moles: -.3176E-21 Mass of aqueous solution: 0.899677E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 0.0028900 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 0.6350E-06 -6.197 0.1665E-03 -3.779 98.31 0.6392E-04 andradite 0.5153E-08 -8.288 0.2619E-05 -5.582 1.546 0.6803E-06 grossular 0.5598E-09 -9.252 0.2522E-06 -6.598 0.1489 0.7017E-07 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.9020E+00 0.9020E+00 1.0000 -0.045 grossular 0.9800E-01 0.9800E-01 1.0000 -1.009 Solid products produced: Mass = 0.000169 g Volume = 0.000065 cm3 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.0028900 moles log = -2.5391 Original solution: 1000.0103000 g Original solution / Rock added: 346024.33 (Water/Rock Ratio), log = 5.5391 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0236 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9968E+00 0.9859 0.1006E+01 0.1020E+01 CO2,gas 0.1269E-05 1.0071 0.1308E-05 0.1299E-05 CH4,gas 0.1394E-02 1.0125 0.1445E-02 0.1427E-02 H2,gas 0.1781E-02 1.0005 0.1824E-02 0.1823E-02 H2S,gas 0.5789E-06 0.9960 0.5902E-06 0.5925E-06 S2,gas 0.3840E-26 1.0000 0.3930E-26 0.3930E-26 CO,gas 0.6211E-12 1.0000 0.6358E-12 0.6358E-12 SO3,gas 0.1453E-43 1.0000 0.1487E-43 0.1487E-43 SO2,gas 0.1031E-23 1.0000 0.1055E-23 0.1055E-23 HF,gas 0.1489E-14 1.0000 0.1524E-14 0.1524E-14 HCl,gas 0.3536E-17 1.0000 0.3619E-17 0.3619E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 17 albite -0.38 -0.38 0.00 0.000 -0.94784E-12 23 andradite 39.01 39.01 0.00 0.000 0.00000E+00 24 grossular 32.73 32.73 0.00 0.000 -0.36397E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -14.24 -7.58 -2.527 0.12947E+05 -5.883 3 CH4,gas 4.54 0.00 -4.54 -1.135 0.77503E+04 -2.840 4 H2,gas 8.00 3.56 -4.44 -2.536 0.75777E+04 -2.739 5 H2S,gas -6.23 -14.16 -7.93 -3.964 0.13537E+05 -6.229 6 S2,gas -7.34 -35.44 -28.10 -4.324 0.47988E+05 -26.406 7 CO,gas 3.21 -10.68 -13.90 -4.276 0.23726E+05 -12.197 8 SO3,gas 17.12 -28.41 -45.53 -11.382 0.77736E+05 -43.828 9 SO2,gas 0.83 -24.84 -25.68 -6.847 0.43841E+05 -23.977 10 HF,gas 0.47 -16.04 -16.52 -8.258 0.28201E+05 -14.817 11 HCl,gas 5.19 -13.95 -19.14 -9.570 0.32682E+05 -17.441 12 acmite 7.71 6.86 -0.85 -0.089 0.14586E+04 16 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 20 spessartine 24.46 19.70 -4.76 -0.238 0.81299E+04 21 analcite 3.32 2.75 -0.57 -0.063 0.97169E+03 27 annite 20.12 17.26 -2.86 -0.159 0.48876E+04 28 phlogopite 27.06 25.27 -1.79 -0.100 0.30638E+04 30 anorthite 12.71 8.03 -4.68 -0.360 0.79860E+04 33 apatite-OH -18.15 -18.99 -0.83 -0.064 0.14246E+04 34 apatite-F -34.30 -35.03 -0.73 -0.061 0.12453E+04 38 aragonite 0.97 -1.33 -2.30 -0.767 0.39279E+04 39 brucite 12.57 9.25 -3.32 -0.663 0.56624E+04 40 calcite 0.81 -1.33 -2.15 -0.715 0.36636E+04 41 carnegieite-low 9.02 5.89 -3.13 -0.448 0.53510E+04 42 carnegieite-high 10.09 5.89 -4.20 -0.601 0.71780E+04 43 carpholite-Mg 8.58 4.38 -4.21 -0.280 0.71802E+04 45 celadonite 5.34 3.63 -1.71 -0.101 0.29242E+04 46 celadonite-Fe 3.88 0.96 -2.92 -0.172 0.49812E+04 47 chrysotile 23.89 21.48 -2.41 -0.201 0.41129E+04 49 clinochlore 39.07 38.25 -0.82 -0.026 0.14001E+04 50 daphnite 28.97 24.90 -4.06 -0.127 0.69403E+04 52 chlorite-Al-free 47.17 42.97 -4.21 -0.175 0.71810E+04 54 chloritoid-Fe 9.17 4.84 -4.33 -0.289 0.73930E+04 55 chloritoid-Mn 11.40 7.50 -3.90 -0.260 0.66656E+04 57 coesite -2.38 -3.14 -0.76 -0.254 0.12987E+04 64 cristobalite -2.56 -3.14 -0.58 -0.192 0.98403E+03 66 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71236E+04 68 diaspore 2.87 0.70 -2.17 -0.362 0.37133E+04 69 diamond -3.10 -7.12 -4.02 -1.148 0.68581E+04 70 diopside 16.18 15.89 -0.29 -0.029 0.50154E+03 71 hedenbergite 14.21 13.22 -0.99 -0.099 0.16911E+04 76 clinoenstatite 17.17 12.23 -4.93 -0.493 0.84263E+04 78 epidote 24.67 22.61 -2.06 -0.100 0.35226E+04 79 clinozoisite 22.81 18.50 -4.30 -0.196 0.73453E+04 80 epidote-Fe 29.84 26.71 -3.13 -0.163 0.53466E+04 81 fayalite 14.05 10.03 -4.02 -0.574 0.68595E+04 82 ferrosilite 11.15 6.89 -4.26 -0.426 0.72699E+04 86 gibbsite 4.08 0.70 -3.38 -0.483 0.57718E+04 87 glaucophane 22.97 20.72 -2.26 -0.061 0.38570E+04 88 glaucophane-Fe 17.28 12.71 -4.57 -0.123 0.78020E+04 89 graphite -3.55 -7.12 -3.57 -1.021 0.61004E+04 90 greenalite 16.14 13.47 -2.67 -0.222 0.45508E+04 93 hematite 12.57 9.60 -2.96 -0.359 0.50591E+04 94 heulandite -5.83 -7.65 -1.82 -0.083 0.31123E+04 98 jadeite 4.22 2.75 -1.46 -0.146 0.24972E+04 100 kalsilite 7.58 3.79 -3.80 -0.542 0.64837E+04 101 kaolinite -1.33 -4.88 -3.54 -0.322 0.60489E+04 104 laumontite 2.88 1.76 -1.12 -0.075 0.19183E+04 105 lawsonite 9.62 8.03 -1.58 -0.106 0.27026E+04 106 leucite 4.12 0.65 -3.47 -0.347 0.59230E+04 108 lizardite 23.24 21.48 -1.76 -0.147 0.30055E+04 110 magnetite 20.09 16.19 -3.90 -0.318 0.66619E+04 111 minnesotaite 10.39 7.20 -3.19 -0.187 0.54420E+04 115 manganosite 14.06 9.24 -4.82 -1.206 0.82336E+04 119 microcline -2.49 -2.49 0.00 0.000 0.25099E+00 123 muscovite 2.58 -1.09 -3.67 -0.216 0.62684E+04 124 paragonite 4.24 1.01 -3.23 -0.190 0.55072E+04 125 nepheline 8.34 5.89 -2.45 -0.350 0.41834E+04 137 phlogopite-Na 29.65 27.37 -2.27 -0.126 0.38823E+04 139 prehnite 19.37 17.81 -1.57 -0.092 0.26750E+04 140 prehnite-Fe 22.50 21.91 -0.59 -0.035 0.10074E+04 141 pumpellyite-Fe 46.27 42.89 -3.38 -0.075 0.57670E+04 142 pumpellyite-Mg 48.99 45.56 -3.43 -0.076 0.58620E+04 145 pyrite -21.25 -25.30 -4.05 -0.953 0.69132E+04 146 pyrrhotite -4.26 -7.58 -3.32 -1.105 0.56609E+04 147 pyrrhotiteFe0.875 -6.02 -8.84 -2.82 -1.038 0.48206E+04 148 pyroxmangite 7.40 6.10 -1.30 -0.260 0.22186E+04 149 pyrophyllite -6.18 -11.15 -4.97 -0.311 0.84910E+04 150 quartz -2.99 -3.14 -0.15 -0.049 0.25136E+03 154 rhodochrosite -0.98 -5.01 -4.03 -1.343 0.68814E+04 155 rhodonite 7.45 6.10 -1.35 -0.269 0.22988E+04 156 sanidine -1.28 -2.49 -1.21 -0.093 0.20680E+04 166 stilbite -7.52 -7.65 -0.13 -0.006 0.21844E+03 167 stilpnomelane-Fe 13.02 12.33 -0.69 -0.021 0.11738E+04 168 stilpnomelane-Mg 27.44 25.68 -1.76 -0.053 0.30102E+04 174 talc 16.49 15.21 -1.28 -0.075 0.21868E+04 177 tephroite 18.09 15.34 -2.75 -0.393 0.46963E+04 181 tridymite -2.63 -3.14 -0.51 -0.170 0.87134E+03 182 tremolite 47.87 46.99 -0.88 -0.024 0.15089E+04 183 ferroactinolite 38.45 33.64 -4.82 -0.130 0.82227E+04 184 troilite-low -4.41 -7.58 -3.16 -1.055 0.54037E+04 190 wairakite 3.95 1.76 -2.19 -0.129 0.37402E+04 191 walstromite 11.51 9.77 -1.74 -0.347 0.29663E+04 192 wollastonite 10.46 9.77 -0.69 -0.138 0.11768E+04 193 pseudo-wollastonite 11.00 9.77 -1.23 -0.246 0.20966E+04 194 zoisite 22.85 18.50 -4.35 -0.198 0.74193E+04 195 akaganeite 7.75 4.80 -2.95 -0.638 0.50421E+04 202 chalcedony -2.80 -3.14 -0.33 -0.111 0.57066E+03 204 montmorillonite-Ca -2.29 -6.20 -3.91 -0.242 0.66684E+04 205 montmorillonite-K -2.24 -6.27 -4.04 -0.247 0.68902E+04 206 montmorillonite-Mg -2.48 -6.80 -4.32 -0.267 0.73755E+04 207 montmorillonite-Na -2.04 -5.58 -3.54 -0.217 0.60450E+04 208 nontronite-Ca 3.21 0.45 -2.76 -0.179 0.47164E+04 209 nontronite-H 2.53 -1.68 -4.21 -0.282 0.71889E+04 210 nontronite-K 3.34 0.38 -2.96 -0.190 0.50614E+04 211 nontronite-Mg 3.07 -0.15 -3.23 -0.209 0.55076E+04 212 nontronite-Na 3.52 1.07 -2.45 -0.157 0.41822E+04 228 tobermorite 9.82 7.62 -2.21 -0.602 0.37681E+04 234 alabandite -0.98 -4.92 -3.94 -1.315 0.67349E+04 237 boehmite 4.41 0.70 -3.71 -0.618 0.63302E+04 239 ferrous-oxide 9.81 6.58 -3.23 -0.807 0.55135E+04 245 silica-amorphous -2.09 -3.14 -1.05 -0.348 0.17848E+04 247 an20ab80 2.02 1.30 -0.72 -0.055 0.12263E+04 248 an25ab75 2.65 1.72 -0.93 -0.071 0.15799E+04 249 an30ab70 3.28 2.14 -1.14 -0.088 0.19431E+04 250 tr.625ac.25prg.125 45.16 44.58 -0.59 -0.016 0.10002E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 0.0001000 MOLES Current total amount of reactant added: 0.0028900 MOLES New total amount of reactant added: 0.0029900 MOLES Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.5508E-08 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 8 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 0.0029900 Water: Moles liquid = 0.4985E+02 kg liquid = 0.8981E+00 Moles total = 0.4985E+02 kg total = 0.8980E+00 Activity = 1.0000 Stoichiometric ionic strength = .1152110E-01 Osmotic coef. = 0.9615 True ionic strength = .2019190E-01 Chg. balance for total moles = -.5508E-08 Max. difference allowed = 0.1555E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.93149E-10 -10.0308 0.78227E-10 -10.1066 0.83981E+00 -0.0758 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.17238E-03 -3.7635 0.14389E-03 -3.8420 0.83472E+00 -0.0785 4 SO4-- 0.25020E-07 -7.6017 0.12964E-07 -7.8873 0.51814E+00 -0.2856 5 HCO3- 0.90783E-04 -4.0420 0.75890E-04 -4.1198 0.83595E+00 -0.0778 6 HS- 0.10925E-03 -3.9616 0.91208E-04 -4.0400 0.83484E+00 -0.0784 7 Al+++ 0.10380E-28 -28.9838 0.23858E-29 -29.6224 0.22984E+00 -0.6386 8 H4SiO4 0.73128E-03 -3.1359 0.73128E-03 -3.1359 0.10000E+01 0.0000 9 Ca++ 0.94432E-07 -7.0249 0.48567E-07 -7.3137 0.51431E+00 -0.2888 10 Mg++ 0.21297E-10 -10.6717 0.10903E-10 -10.9625 0.51194E+00 -0.2908 11 Fe++ 0.43326E-13 -13.3633 0.22205E-13 -13.6536 0.51251E+00 -0.2903 12 K+ 0.15654E-03 -3.8054 0.13089E-03 -3.8831 0.83615E+00 -0.0777 13 Na+ 0.19871E-01 -1.7018 0.16584E-01 -1.7803 0.83457E+00 -0.0785 14 Mn++ 0.20538E-10 -10.6874 0.10535E-10 -10.9774 0.51294E+00 -0.2899 15 F- 0.14384E-05 -5.8421 0.11982E-05 -5.9215 0.83299E+00 -0.0794 16 HPO4-- 0.45362E-07 -7.3433 0.23507E-07 -7.6288 0.51822E+00 -0.2855 18 HSiO3- 0.10457E-01 -1.9806 0.87288E-02 -2.0590 0.83472E+00 -0.0785 19 Ca(HSiO3)+ 0.11544E-07 -7.9376 0.96545E-08 -8.0153 0.83633E+00 -0.0776 20 Mg(HSiO3)+ 0.32252E-11 -11.4914 0.26973E-11 -11.5691 0.83633E+00 -0.0776 21 NaHSiO3,aq 0.23412E-02 -2.6306 0.23412E-02 -2.6306 0.10000E+01 0.0000 22 AlO+ 0.63417E-16 -16.1978 0.53038E-16 -16.2754 0.83633E+00 -0.0776 24 HAlO2,aq 0.13502E-09 -9.8696 0.13502E-09 -9.8696 0.10000E+01 0.0000 25 AlO2- 0.45855E-05 -5.3386 0.38207E-05 -5.4179 0.83320E+00 -0.0792 26 CH4,aq 0.52046E-06 -6.2836 0.51863E-06 -6.2851 0.99649E+00 -0.0015 27 C2H6,aq 0.39325E-16 -16.4053 0.39187E-16 -16.4069 0.99649E+00 -0.0015 31 CO,aq 0.37394E-15 -15.4272 0.37394E-15 -15.4272 0.10000E+01 0.0000 32 CO2,aq 0.12730E-07 -7.8952 0.12685E-07 -7.8967 0.99649E+00 -0.0015 33 CO3-2 0.16389E-03 -3.7855 0.84736E-04 -4.0719 0.51703E+00 -0.2865 34 CaCO3,aq 0.51603E-07 -7.2873 0.51603E-07 -7.2873 0.10000E+01 0.0000 35 Ca(HCO3)+ 0.11249E-09 -9.9489 0.94083E-10 -10.0265 0.83633E+00 -0.0776 36 CaCl+ 0.13522E-10 -10.8689 0.11309E-10 -10.9466 0.83633E+00 -0.0776 37 CaCl2,aq 0.38660E-15 -15.4127 0.38660E-15 -15.4127 0.10000E+01 0.0000 38 CaF+ 0.10159E-11 -11.9932 0.84960E-12 -12.0708 0.83633E+00 -0.0776 39 CaOH+ 0.52907E-07 -7.2765 0.44248E-07 -7.3541 0.83633E+00 -0.0776 40 CaSO4,aq 0.19994E-12 -12.6991 0.19994E-12 -12.6991 0.10000E+01 0.0000 41 HCl,aq 0.20626E-14 -14.6856 0.20626E-14 -14.6856 0.10000E+01 0.0000 45 HF,aq 0.64164E-12 -12.1927 0.64164E-12 -12.1927 0.10000E+01 0.0000 46 HF2- 0.31096E-18 -18.5073 0.25956E-18 -18.5858 0.83472E+00 -0.0785 48 FeCl+ 0.60468E-17 -17.2185 0.50572E-17 -17.2961 0.83633E+00 -0.0776 51 FeF+ 0.16256E-17 -17.7890 0.13596E-17 -17.8666 0.83633E+00 -0.0776 53 FeO,aq 0.14102E-09 -9.8507 0.14102E-09 -9.8507 0.10000E+01 0.0000 54 FeOH+ 0.11048E-10 -10.9567 0.92396E-11 -11.0343 0.83633E+00 -0.0776 55 HFeO2- 0.22597E-07 -7.6459 0.18862E-07 -7.7244 0.83472E+00 -0.0785 56 FeO+ 0.24326E-16 -16.6139 0.20344E-16 -16.6916 0.83633E+00 -0.0776 58 FeO2- 0.81496E-09 -9.0889 0.68026E-09 -9.1673 0.83472E+00 -0.0785 59 HFeO2,aq 0.67682E-11 -11.1695 0.67682E-11 -11.1695 0.10000E+01 0.0000 60 H2,aq 0.11776E-05 -5.9290 0.11735E-05 -5.9305 0.99649E+00 -0.0015 61 KCl,aq 0.34134E-09 -9.4668 0.34134E-09 -9.4668 0.10000E+01 0.0000 63 KOH,aq 0.71455E-06 -6.1460 0.71455E-06 -6.1460 0.10000E+01 0.0000 64 KSO4- 0.31545E-10 -10.5011 0.26331E-10 -10.5795 0.83472E+00 -0.0785 65 MgCO3,aq 0.29037E-11 -11.5370 0.29037E-11 -11.5370 0.10000E+01 0.0000 66 Mg(HCO3)+ 0.25805E-13 -13.5883 0.21582E-13 -13.6659 0.83633E+00 -0.0776 67 MgCl+ 0.27514E-14 -14.5605 0.23010E-14 -14.6381 0.83633E+00 -0.0776 68 MgF+ 0.84478E-15 -15.0733 0.70652E-15 -15.1509 0.83633E+00 -0.0776 69 MgOH+ 0.65722E-10 -10.1823 0.54965E-10 -10.2599 0.83633E+00 -0.0776 71 MnF+ 0.25421E-15 -15.5948 0.21260E-15 -15.6724 0.83633E+00 -0.0776 72 MnO,aq 0.17828E-08 -8.7489 0.17828E-08 -8.7489 0.10000E+01 0.0000 73 MnOH+ 0.48691E-09 -9.3126 0.40722E-09 -9.3902 0.83633E+00 -0.0776 74 MnO2-2 0.18699E-10 -10.7282 0.96683E-11 -11.0147 0.51703E+00 -0.2865 75 HMnO2- 0.19851E-09 -9.7022 0.16570E-09 -9.7807 0.83472E+00 -0.0785 78 MnCl+ 0.11161E-13 -13.9523 0.93343E-14 -14.0299 0.83633E+00 -0.0776 79 MnSO4,aq 0.39427E-16 -16.4042 0.39427E-16 -16.4042 0.10000E+01 0.0000 80 NaCl,aq 0.79080E-06 -6.1019 0.79080E-06 -6.1019 0.10000E+01 0.0000 81 NaF,aq 0.46519E-08 -8.3324 0.46519E-08 -8.3324 0.10000E+01 0.0000 82 NaOH,aq 0.91083E-04 -4.0406 0.91083E-04 -4.0406 0.10000E+01 0.0000 84 OH- 0.88644E-02 -2.0524 0.73858E-02 -2.1316 0.83320E+00 -0.0792 89 HPO3-2 0.16626E-15 -15.7792 0.85963E-16 -16.0657 0.51703E+00 -0.2865 91 H2PO3- 0.16155E-19 -19.7917 0.13485E-19 -19.8701 0.83472E+00 -0.0785 92 H3PO4,aq 0.10061E-17 -17.9974 0.10061E-17 -17.9974 0.10000E+01 0.0000 93 H2PO4- 0.40601E-10 -10.3915 0.33923E-10 -10.4695 0.83552E+00 -0.0780 94 PO4-3 0.10153E-08 -8.9934 0.24518E-09 -9.6105 0.24148E+00 -0.6171 98 HP2O7-3 0.10011E-17 -17.9995 0.23032E-18 -18.6377 0.23008E+00 -0.6381 99 P2O7-4 0.92040E-17 -17.0360 0.70336E-18 -18.1528 0.76419E-01 -1.1168 100 H2S,aq 0.22129E-07 -7.6550 0.22051E-07 -7.6566 0.99649E+00 -0.0015 101 S2-2 0.30382E-12 -12.5174 0.15708E-12 -12.8039 0.51703E+00 -0.2865 107 SO3-2 0.37687E-14 -14.4238 0.19769E-14 -14.7040 0.52456E+00 -0.2802 108 HSO3- 0.11600E-16 -16.9355 0.96828E-17 -17.0140 0.83472E+00 -0.0785 109 HSO4- 0.11675E-14 -14.9328 0.97735E-15 -15.0099 0.83715E+00 -0.0772 111 S2O3-2 0.64950E-17 -17.1874 0.33581E-17 -17.4739 0.51703E+00 -0.2865 Charge balance for all species = -.6132E-08 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.9314932E-10 -.2193717E-01 -.2207269E+02 0.0000 2 H2O 0.1000000E+01 0.5550442E+02 0.9981805E+06 0.0000 3 Cl- 0.1723790E-03 0.1731702E-03 0.6128669E+01 6.2647 4 SO4-- 0.2502045E-07 -.7897038E-06 -.7572758E-01 12.3260 5 HCO3- 0.9078254E-04 0.2552560E-03 0.1554778E+02 5.9868 6 HS- 0.1092511E-03 0.1100880E-03 0.3634465E+01 6.0667 7 Al+++ 0.1037996E-28 0.4585677E-05 0.1235121E+00 0.6976 8 H4SiO4 0.7312823E-03 0.1352962E-01 0.1298131E+04 -3.1359 9 Ca++ 0.9443159E-07 0.2106119E-06 0.8426147E-02 12.8996 10 Mg++ 0.2129720E-10 0.9317750E-10 0.2261371E-05 9.2508 11 Fe++ 0.4332570E-13 0.2357106E-07 0.1314071E-02 6.5597 12 K+ 0.1565375E-03 0.1572525E-03 0.6138135E+01 6.2235 13 Na+ 0.1987105E-01 0.2230415E-01 0.5118715E+03 8.3263 14 Mn++ 0.2053791E-10 0.2507431E-08 0.1375124E-03 9.2359 15 F- 0.1438383E-05 0.1443037E-05 0.2736688E-01 4.1852 16 HPO4-- 0.4536200E-07 0.4641789E-07 0.4447353E-02 12.5845 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.1970459E-01 -.1970191E-01 -.2685794E-05 0.0000000E+00 2 H2O 0.4984886E+02 0.4984886E+02 -.2628629E-05 0.0000000E+00 3 Cl- 0.1555252E-03 0.1555252E-03 0.0000000E+00 0.0000000E+00 4 SO4-- -.7078100E-06 -.7092379E-06 0.1427870E-08 0.0000000E+00 5 HCO3- 0.2292470E-03 0.2292470E-03 0.0000000E+00 0.0000000E+00 6 HS- 0.9886928E-04 0.9887071E-04 -.1427870E-08 0.0000000E+00 7 Al+++ 0.4775352E-05 0.4118424E-05 0.6569276E-06 0.0000000E+00 8 H4SiO4 0.1215302E-01 0.1215103E-01 0.1986120E-05 0.0000000E+00 9 Ca++ 0.2080835E-06 0.1891519E-06 0.1893163E-07 0.0000000E+00 10 Mg++ 0.8368328E-10 0.8368328E-10 0.0000000E+00 0.0000000E+00 11 Fe++ 0.3259227E-07 0.2116931E-07 0.1142296E-07 0.0000000E+00 12 K+ 0.1412294E-03 0.1412294E-03 0.0000000E+00 0.0000000E+00 13 Na+ 0.2003215E-01 0.2003149E-01 0.6557295E-06 0.0000000E+00 14 Mn++ 0.2251939E-08 0.2251939E-08 0.0000000E+00 0.0000000E+00 15 F- 0.1296000E-05 0.1296000E-05 0.0000000E+00 0.0000000E+00 16 HPO4-- 0.4168819E-07 0.4168819E-07 0.0000000E+00 0.0000000E+00 Chg. balance for solid moles: 0.2118E-21 Mass of aqueous solution: 0.899679E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 0.0029900 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 0.6557E-06 -6.183 0.1719E-03 -3.765 98.19 0.6601E-04 andradite 0.5711E-08 -8.243 0.2902E-05 -5.537 1.657 0.7541E-06 grossular 0.5991E-09 -9.223 0.2698E-06 -6.569 0.1541 0.7508E-07 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.9051E+00 0.9051E+00 1.0000 -0.043 grossular 0.9493E-01 0.9493E-01 1.0000 -1.023 Solid products produced: Mass = 0.000175 g Volume = 0.000067 cm3 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.0029900 moles log = -2.5243 Original solution: 1000.0103000 g Original solution / Rock added: 334451.61 (Water/Rock Ratio), log = 5.5243 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0226 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9978E+00 0.9859 0.1006E+01 0.1020E+01 CO2,gas 0.1318E-05 1.0071 0.1357E-05 0.1348E-05 CH4,gas 0.7373E-03 1.0125 0.7634E-03 0.7539E-03 H2,gas 0.1506E-02 1.0005 0.1541E-02 0.1540E-02 H2S,gas 0.5951E-06 0.9960 0.6062E-06 0.6086E-06 S2,gas 0.5683E-26 1.0000 0.5811E-26 0.5811E-26 CO,gas 0.5449E-12 1.0000 0.5572E-12 0.5572E-12 SO3,gas 0.2933E-43 1.0000 0.3000E-43 0.3000E-43 SO2,gas 0.1758E-23 1.0000 0.1798E-23 0.1798E-23 HF,gas 0.1541E-14 1.0000 0.1575E-14 0.1575E-14 HCl,gas 0.3559E-17 1.0000 0.3640E-17 0.3640E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 17 albite -0.38 -0.38 0.00 0.000 0.11184E-10 23 andradite 39.01 39.01 0.00 0.000 0.00000E+00 24 grossular 32.73 32.73 0.00 0.000 0.12132E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -14.23 -7.57 -2.522 0.12919E+05 -5.867 3 CH4,gas 4.54 -0.27 -4.82 -1.204 0.82236E+04 -3.117 4 H2,gas 8.00 3.49 -4.51 -2.578 0.77029E+04 -2.812 5 H2S,gas -6.23 -14.15 -7.92 -3.958 0.13517E+05 -6.217 6 S2,gas -7.34 -35.27 -27.93 -4.298 0.47698E+05 -26.236 7 CO,gas 3.21 -10.74 -13.95 -4.293 0.23824E+05 -12.254 8 SO3,gas 17.12 -28.10 -45.22 -11.305 0.77215E+05 -43.523 9 SO2,gas 0.83 -24.61 -25.44 -6.785 0.43445E+05 -23.745 10 HF,gas 0.47 -16.03 -16.50 -8.251 0.28176E+05 -14.803 11 HCl,gas 5.19 -13.95 -19.14 -9.569 0.32677E+05 -17.439 12 acmite 7.71 6.87 -0.84 -0.087 0.14338E+04 16 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 20 spessartine 24.46 19.70 -4.76 -0.238 0.81314E+04 21 analcite 3.32 2.75 -0.57 -0.063 0.97294E+03 27 annite 20.12 17.19 -2.93 -0.163 0.50044E+04 28 phlogopite 27.06 25.27 -1.80 -0.100 0.30713E+04 30 anorthite 12.71 8.02 -4.69 -0.361 0.80036E+04 33 apatite-OH -18.15 -19.03 -0.87 -0.067 0.14934E+04 34 apatite-F -34.30 -35.06 -0.76 -0.063 0.12896E+04 38 aragonite 0.97 -1.33 -2.29 -0.764 0.39158E+04 39 brucite 12.57 9.25 -3.32 -0.664 0.56649E+04 40 calcite 0.81 -1.33 -2.14 -0.713 0.36516E+04 41 carnegieite-low 9.02 5.89 -3.14 -0.448 0.53535E+04 42 carnegieite-high 10.09 5.89 -4.21 -0.601 0.71805E+04 43 carpholite-Mg 8.58 4.37 -4.21 -0.281 0.71850E+04 45 celadonite 5.34 3.63 -1.71 -0.101 0.29255E+04 46 celadonite-Fe 3.88 0.94 -2.94 -0.173 0.50189E+04 47 chrysotile 23.89 21.48 -2.41 -0.201 0.41180E+04 49 clinochlore 39.07 38.24 -0.83 -0.026 0.14138E+04 50 daphnite 28.97 24.79 -4.18 -0.131 0.71359E+04 52 chlorite-Al-free 47.17 42.96 -4.21 -0.175 0.71911E+04 54 chloritoid-Fe 9.17 4.82 -4.35 -0.290 0.74355E+04 55 chloritoid-Mn 11.40 7.50 -3.91 -0.260 0.66694E+04 57 coesite -2.38 -3.14 -0.76 -0.253 0.12974E+04 64 cristobalite -2.56 -3.14 -0.58 -0.192 0.98278E+03 66 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71236E+04 68 diaspore 2.87 0.70 -2.18 -0.363 0.37157E+04 69 diamond -3.10 -7.25 -4.15 -1.185 0.70811E+04 70 diopside 16.18 15.88 -0.30 -0.030 0.51691E+03 71 hedenbergite 14.21 13.19 -1.02 -0.102 0.17429E+04 76 clinoenstatite 17.17 12.23 -4.94 -0.494 0.84289E+04 78 epidote 24.67 22.60 -2.07 -0.100 0.35307E+04 79 clinozoisite 22.81 18.48 -4.32 -0.196 0.73795E+04 80 epidote-Fe 29.84 26.72 -3.12 -0.162 0.53286E+04 81 fayalite 14.05 9.98 -4.06 -0.580 0.69361E+04 82 ferrosilite 11.15 6.85 -4.30 -0.430 0.73452E+04 86 gibbsite 4.08 0.70 -3.38 -0.483 0.57743E+04 87 glaucophane 22.97 20.71 -2.26 -0.061 0.38621E+04 88 glaucophane-Fe 17.28 12.64 -4.64 -0.125 0.79162E+04 89 graphite -3.55 -7.25 -3.70 -1.058 0.63233E+04 90 greenalite 16.14 13.41 -2.73 -0.228 0.46651E+04 93 hematite 12.57 9.63 -2.94 -0.356 0.50118E+04 94 heulandite -5.83 -7.66 -1.83 -0.083 0.31237E+04 98 jadeite 4.22 2.75 -1.46 -0.146 0.24984E+04 100 kalsilite 7.58 3.79 -3.80 -0.543 0.64862E+04 101 kaolinite -1.33 -4.88 -3.54 -0.322 0.60512E+04 104 laumontite 2.88 1.75 -1.13 -0.075 0.19334E+04 105 lawsonite 9.62 8.02 -1.59 -0.106 0.27203E+04 106 leucite 4.12 0.65 -3.47 -0.347 0.59242E+04 108 lizardite 23.24 21.48 -1.76 -0.147 0.30106E+04 110 magnetite 20.09 16.19 -3.90 -0.318 0.66535E+04 111 minnesotaite 10.39 7.14 -3.25 -0.191 0.55537E+04 115 manganosite 14.06 9.24 -4.82 -1.206 0.82338E+04 119 microcline -2.49 -2.49 0.00 0.000 0.26003E+00 123 muscovite 2.58 -1.09 -3.67 -0.216 0.62732E+04 124 paragonite 4.24 1.01 -3.23 -0.190 0.55120E+04 125 nepheline 8.34 5.89 -2.45 -0.350 0.41859E+04 137 phlogopite-Na 29.65 27.37 -2.28 -0.127 0.38899E+04 139 prehnite 19.37 17.79 -1.59 -0.093 0.27068E+04 140 prehnite-Fe 22.50 21.90 -0.59 -0.036 0.10131E+04 141 pumpellyite-Fe 46.27 42.83 -3.44 -0.076 0.58718E+04 142 pumpellyite-Mg 48.99 45.52 -3.47 -0.077 0.59305E+04 145 pyrite -21.25 -25.22 -3.98 -0.935 0.67873E+04 146 pyrrhotite -4.26 -7.59 -3.33 -1.109 0.56800E+04 147 pyrrhotiteFe0.875 -6.02 -8.84 -2.82 -1.038 0.48193E+04 148 pyroxmangite 7.40 6.10 -1.30 -0.260 0.22175E+04 149 pyrophyllite -6.18 -11.15 -4.97 -0.311 0.84908E+04 150 quartz -2.99 -3.14 -0.15 -0.049 0.25011E+03 154 rhodochrosite -0.98 -4.99 -4.01 -1.338 0.68542E+04 155 rhodonite 7.45 6.10 -1.35 -0.269 0.22977E+04 156 sanidine -1.28 -2.49 -1.21 -0.093 0.20680E+04 166 stilbite -7.52 -7.66 -0.13 -0.006 0.22986E+03 167 stilpnomelane-Fe 13.02 12.22 -0.80 -0.024 0.13639E+04 168 stilpnomelane-Mg 27.44 25.67 -1.77 -0.053 0.30183E+04 174 talc 16.49 15.21 -1.28 -0.075 0.21894E+04 177 tephroite 18.09 15.34 -2.75 -0.393 0.46954E+04 181 tridymite -2.63 -3.14 -0.51 -0.170 0.87009E+03 182 tremolite 47.87 46.97 -0.90 -0.024 0.15422E+04 183 ferroactinolite 38.45 33.51 -4.94 -0.134 0.84380E+04 184 troilite-low -4.41 -7.59 -3.18 -1.059 0.54228E+04 190 wairakite 3.95 1.75 -2.20 -0.129 0.37554E+04 191 walstromite 11.51 9.76 -1.75 -0.349 0.29804E+04 192 wollastonite 10.46 9.76 -0.70 -0.139 0.11909E+04 193 pseudo-wollastonite 11.00 9.76 -1.24 -0.247 0.21107E+04 194 zoisite 22.85 18.48 -4.37 -0.198 0.74535E+04 195 akaganeite 7.75 4.82 -2.94 -0.635 0.50184E+04 202 chalcedony -2.80 -3.14 -0.33 -0.111 0.56941E+03 204 montmorillonite-Ca -2.29 -6.20 -3.91 -0.242 0.66708E+04 205 montmorillonite-K -2.24 -6.27 -4.04 -0.247 0.68905E+04 206 montmorillonite-Mg -2.48 -6.80 -4.32 -0.267 0.73758E+04 207 montmorillonite-Na -2.04 -5.58 -3.54 -0.217 0.60453E+04 208 nontronite-Ca 3.21 0.48 -2.73 -0.177 0.46678E+04 209 nontronite-H 2.53 -1.65 -4.18 -0.280 0.71378E+04 210 nontronite-K 3.34 0.41 -2.93 -0.188 0.50107E+04 211 nontronite-Mg 3.07 -0.12 -3.20 -0.207 0.54569E+04 212 nontronite-Na 3.52 1.10 -2.42 -0.155 0.41315E+04 228 tobermorite 9.82 7.61 -2.21 -0.604 0.37796E+04 234 alabandite -0.98 -4.91 -3.93 -1.311 0.67152E+04 237 boehmite 4.41 0.70 -3.71 -0.618 0.63326E+04 239 ferrous-oxide 9.81 6.56 -3.25 -0.813 0.55525E+04 245 silica-amorphous -2.09 -3.14 -1.04 -0.348 0.17836E+04 247 an20ab80 2.02 1.30 -0.72 -0.055 0.12299E+04 248 an25ab75 2.65 1.72 -0.93 -0.071 0.15843E+04 249 an30ab70 3.28 2.14 -1.14 -0.088 0.19484E+04 250 tr.625ac.25prg.125 45.16 44.53 -0.63 -0.017 0.10800E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 0.0001000 MOLES Current total amount of reactant added: 0.0029900 MOLES New total amount of reactant added: 0.0030900 MOLES Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.5508E-08 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 8 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 0.0030900 Water: Moles liquid = 0.4985E+02 kg liquid = 0.8981E+00 Moles total = 0.4985E+02 kg total = 0.8980E+00 Activity = 1.0000 Stoichiometric ionic strength = .1152748E-01 Osmotic coef. = 0.9613 True ionic strength = .2019765E-01 Chg. balance for total moles = -.5508E-08 Max. difference allowed = 0.1561E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.93319E-10 -10.0300 0.78368E-10 -10.1059 0.83979E+00 -0.0758 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.17303E-03 -3.7619 0.14443E-03 -3.8403 0.83471E+00 -0.0785 4 SO4-- 0.96204E-07 -7.0168 0.49843E-07 -7.3024 0.51810E+00 -0.2856 5 HCO3- 0.93892E-04 -4.0274 0.78487E-04 -4.1052 0.83594E+00 -0.0778 6 HS- 0.11188E-03 -3.9512 0.93405E-04 -4.0296 0.83483E+00 -0.0784 7 Al+++ 0.10404E-28 -28.9828 0.23909E-29 -29.6214 0.22980E+00 -0.6386 8 H4SiO4 0.73251E-03 -3.1352 0.73251E-03 -3.1352 0.10000E+01 0.0000 9 Ca++ 0.91928E-07 -7.0366 0.47276E-07 -7.3254 0.51427E+00 -0.2888 10 Mg++ 0.21304E-10 -10.6715 0.10905E-10 -10.9624 0.51190E+00 -0.2908 11 Fe++ 0.38664E-13 -13.4127 0.19814E-13 -13.7030 0.51247E+00 -0.2903 12 K+ 0.15654E-03 -3.8054 0.13089E-03 -3.8831 0.83614E+00 -0.0777 13 Na+ 0.19871E-01 -1.7018 0.16584E-01 -1.7803 0.83455E+00 -0.0785 14 Mn++ 0.20609E-10 -10.6859 0.10570E-10 -10.9759 0.51290E+00 -0.2900 15 F- 0.14828E-05 -5.8289 0.12351E-05 -5.9083 0.83297E+00 -0.0794 16 HPO4-- 0.45364E-07 -7.3433 0.23506E-07 -7.6288 0.51818E+00 -0.2855 18 HSiO3- 0.10456E-01 -1.9806 0.87277E-02 -2.0591 0.83471E+00 -0.0785 19 Ca(HSiO3)+ 0.11236E-07 -7.9494 0.93967E-08 -8.0270 0.83632E+00 -0.0776 20 Mg(HSiO3)+ 0.32256E-11 -11.4914 0.26976E-11 -11.5690 0.83632E+00 -0.0776 21 NaHSiO3,aq 0.23409E-02 -2.6306 0.23409E-02 -2.6306 0.10000E+01 0.0000 22 AlO+ 0.63327E-16 -16.1984 0.52962E-16 -16.2760 0.83632E+00 -0.0776 24 HAlO2,aq 0.13458E-09 -9.8710 0.13458E-09 -9.8710 0.10000E+01 0.0000 25 AlO2- 0.45626E-05 -5.3408 0.38015E-05 -5.4200 0.83319E+00 -0.0793 26 CH4,aq 0.14338E-06 -6.8435 0.14287E-06 -6.8451 0.99649E+00 -0.0015 27 C2H6,aq 0.41560E-17 -17.3813 0.41414E-17 -17.3829 0.99649E+00 -0.0015 31 CO,aq 0.27821E-15 -15.5556 0.27821E-15 -15.5556 0.10000E+01 0.0000 32 CO2,aq 0.13189E-07 -7.8798 0.13143E-07 -7.8813 0.99649E+00 -0.0015 33 CO3-2 0.16921E-03 -3.7716 0.87479E-04 -4.0581 0.51700E+00 -0.2865 34 CaCO3,aq 0.51856E-07 -7.2852 0.51856E-07 -7.2852 0.10000E+01 0.0000 35 Ca(HCO3)+ 0.11325E-09 -9.9459 0.94716E-10 -10.0236 0.83632E+00 -0.0776 36 CaCl+ 0.13213E-10 -10.8790 0.11050E-10 -10.9566 0.83632E+00 -0.0776 37 CaCl2,aq 0.37917E-15 -15.4212 0.37917E-15 -15.4212 0.10000E+01 0.0000 38 CaF+ 0.10194E-11 -11.9917 0.85252E-12 -12.0693 0.83632E+00 -0.0776 39 CaOH+ 0.51408E-07 -7.2890 0.42994E-07 -7.3666 0.83632E+00 -0.0776 40 CaSO4,aq 0.74826E-12 -12.1259 0.74826E-12 -12.1259 0.10000E+01 0.0000 41 HCl,aq 0.20741E-14 -14.6832 0.20741E-14 -14.6832 0.10000E+01 0.0000 45 HF,aq 0.66262E-12 -12.1787 0.66262E-12 -12.1787 0.10000E+01 0.0000 46 HF2- 0.33103E-18 -18.4801 0.27632E-18 -18.5586 0.83471E+00 -0.0785 48 FeCl+ 0.54162E-17 -17.2663 0.45297E-17 -17.3439 0.83632E+00 -0.0776 51 FeF+ 0.14953E-17 -17.8253 0.12506E-17 -17.9029 0.83632E+00 -0.0776 53 FeO,aq 0.12539E-09 -9.9017 0.12539E-09 -9.9017 0.10000E+01 0.0000 54 FeOH+ 0.98406E-11 -11.0070 0.82299E-11 -11.0846 0.83632E+00 -0.0776 55 HFeO2- 0.20056E-07 -7.6978 0.16741E-07 -7.7762 0.83471E+00 -0.0785 56 FeO+ 0.25570E-16 -16.5923 0.21385E-16 -16.6699 0.83632E+00 -0.0776 58 FeO2- 0.85356E-09 -9.0688 0.71247E-09 -9.1472 0.83471E+00 -0.0785 59 HFeO2,aq 0.71014E-11 -11.1487 0.71014E-11 -11.1487 0.10000E+01 0.0000 60 H2,aq 0.84560E-06 -6.0728 0.84263E-06 -6.0744 0.99649E+00 -0.0015 61 KCl,aq 0.34262E-09 -9.4652 0.34262E-09 -9.4652 0.10000E+01 0.0000 63 KOH,aq 0.71325E-06 -6.1468 0.71325E-06 -6.1468 0.10000E+01 0.0000 64 KSO4- 0.12128E-09 -9.9162 0.10123E-09 -9.9947 0.83471E+00 -0.0785 65 MgCO3,aq 0.29983E-11 -11.5231 0.29983E-11 -11.5231 0.10000E+01 0.0000 66 Mg(HCO3)+ 0.26695E-13 -13.5736 0.22325E-13 -13.6512 0.83632E+00 -0.0776 67 MgCl+ 0.27624E-14 -14.5587 0.23102E-14 -14.6363 0.83632E+00 -0.0776 68 MgF+ 0.87104E-15 -15.0600 0.72847E-15 -15.1376 0.83632E+00 -0.0776 69 MgOH+ 0.65620E-10 -10.1830 0.54879E-10 -10.2606 0.83632E+00 -0.0776 71 MnF+ 0.26294E-15 -15.5801 0.21990E-15 -15.6578 0.83632E+00 -0.0776 72 MnO,aq 0.17824E-08 -8.7490 0.17824E-08 -8.7490 0.10000E+01 0.0000 73 MnOH+ 0.48769E-09 -9.3119 0.40786E-09 -9.3895 0.83632E+00 -0.0776 74 MnO2-2 0.18630E-10 -10.7298 0.96314E-11 -11.0163 0.51700E+00 -0.2865 75 HMnO2- 0.19811E-09 -9.7031 0.16536E-09 -9.7816 0.83471E+00 -0.0785 78 MnCl+ 0.11241E-13 -13.9492 0.94012E-14 -14.0268 0.83632E+00 -0.0776 79 MnSO4,aq 0.15210E-15 -15.8179 0.15210E-15 -15.8179 0.10000E+01 0.0000 80 NaCl,aq 0.79378E-06 -6.1003 0.79378E-06 -6.1003 0.10000E+01 0.0000 81 NaF,aq 0.47954E-08 -8.3192 0.47954E-08 -8.3192 0.10000E+01 0.0000 82 NaOH,aq 0.90919E-04 -4.0413 0.90919E-04 -4.0413 0.10000E+01 0.0000 84 OH- 0.88486E-02 -2.0531 0.73725E-02 -2.1324 0.83319E+00 -0.0793 89 HPO3-2 0.11939E-15 -15.9230 0.61726E-16 -16.2095 0.51700E+00 -0.2865 91 H2PO3- 0.11621E-19 -19.9347 0.97004E-20 -20.0132 0.83471E+00 -0.0785 92 H3PO4,aq 0.10097E-17 -17.9958 0.10097E-17 -17.9958 0.10000E+01 0.0000 93 H2PO4- 0.40673E-10 -10.3907 0.33983E-10 -10.4687 0.83550E+00 -0.0781 94 PO4-3 0.10136E-08 -8.9941 0.24472E-09 -9.6113 0.24144E+00 -0.6172 98 HP2O7-3 0.10029E-17 -17.9987 0.23071E-18 -18.6369 0.23004E+00 -0.6382 99 P2O7-4 0.92060E-17 -17.0359 0.70330E-18 -18.1529 0.76396E-01 -1.1169 100 H2S,aq 0.22703E-07 -7.6439 0.22623E-07 -7.6454 0.99649E+00 -0.0015 101 S2-2 0.44376E-12 -12.3529 0.22942E-12 -12.6394 0.51700E+00 -0.2865 102 S3-2 0.16051E-19 -19.7945 0.82985E-20 -20.0810 0.51700E+00 -0.2865 107 SO3-2 0.10405E-13 -13.9827 0.54578E-14 -14.2630 0.52453E+00 -0.2802 108 HSO3- 0.32084E-16 -16.4937 0.26781E-16 -16.5722 0.83471E+00 -0.0785 109 HSO4- 0.44968E-14 -14.3471 0.37644E-14 -14.4243 0.83714E+00 -0.0772 111 S2O3-2 0.25621E-16 -16.5914 0.13246E-16 -16.8779 0.51700E+00 -0.2865 Charge balance for all species = -.6132E-08 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.9331881E-10 -.2192503E-01 -.2206047E+02 0.0000 2 H2O 0.1000000E+01 0.5550440E+02 0.9981799E+06 0.0000 3 Cl- 0.1730326E-03 0.1738268E-03 0.6151904E+01 6.2655 4 SO4-- 0.9620377E-07 -.2583439E-06 -.2477353E-01 12.9093 5 HCO3- 0.9389150E-04 0.2633058E-03 0.1603809E+02 6.0007 6 HS- 0.1118847E-03 0.1122621E-03 0.3706240E+01 6.0762 7 Al+++ 0.1040416E-28 0.4562696E-05 0.1228931E+00 0.6961 8 H4SiO4 0.7325128E-03 0.1352952E-01 0.1298121E+04 -3.1352 9 Ca++ 0.9192769E-07 0.2065562E-06 0.8263883E-02 12.8864 10 Mg++ 0.2130355E-10 0.9317732E-10 0.2261366E-05 9.2494 11 Fe++ 0.3866360E-13 0.2105177E-07 0.1173622E-02 6.5087 12 K+ 0.1565384E-03 0.1572522E-03 0.6138121E+01 6.2228 13 Na+ 0.1987142E-01 0.2230408E-01 0.5118698E+03 8.3255 14 Mn++ 0.2060907E-10 0.2507426E-08 0.1375121E-03 9.2358 15 F- 0.1482775E-05 0.1487572E-05 0.2821147E-01 4.1976 16 HPO4-- 0.4536354E-07 0.4641780E-07 0.4447343E-02 12.5829 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.1969382E-01 -.1969104E-01 -.2779680E-05 0.0000000E+00 2 H2O 0.4984894E+02 0.4984894E+02 -.2711624E-05 0.0000000E+00 3 Cl- 0.1561152E-03 0.1561152E-03 0.0000000E+00 0.0000000E+00 4 SO4-- -.2303100E-06 -.2320207E-06 0.1710689E-08 0.0000000E+00 5 HCO3- 0.2364770E-03 0.2364770E-03 0.0000000E+00 0.0000000E+00 6 HS- 0.1008218E-03 0.1008235E-03 -.1710689E-08 0.0000000E+00 7 Al+++ 0.4775352E-05 0.4097793E-05 0.6775590E-06 0.0000000E+00 8 H4SiO4 0.1215302E-01 0.1215097E-01 0.2051160E-05 0.0000000E+00 9 Ca++ 0.2080835E-06 0.1855098E-06 0.2257375E-07 0.0000000E+00 10 Mg++ 0.8368328E-10 0.8368328E-10 0.0000000E+00 0.0000000E+00 11 Fe++ 0.3259227E-07 0.1890676E-07 0.1368551E-07 0.0000000E+00 12 K+ 0.1412294E-03 0.1412294E-03 0.0000000E+00 0.0000000E+00 13 Na+ 0.2003215E-01 0.2003147E-01 0.6761953E-06 0.0000000E+00 14 Mn++ 0.2251939E-08 0.2251939E-08 0.0000000E+00 0.0000000E+00 15 F- 0.1336000E-05 0.1336000E-05 0.0000000E+00 0.0000000E+00 16 HPO4-- 0.4168819E-07 0.4168819E-07 0.0000000E+00 0.0000000E+00 Chg. balance for solid moles: -.1059E-21 Mass of aqueous solution: 0.899681E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 0.0030900 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 0.6762E-06 -6.170 0.1773E-03 -3.751 97.91 0.6807E-04 andradite 0.6843E-08 -8.165 0.3477E-05 -5.459 1.920 0.9034E-06 grossular 0.6818E-09 -9.166 0.3071E-06 -6.513 0.1696 0.8546E-07 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.9094E+00 0.9094E+00 1.0000 -0.041 grossular 0.9061E-01 0.9061E-01 1.0000 -1.043 Solid products produced: Mass = 0.000181 g Volume = 0.000069 cm3 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.0030900 moles log = -2.5100 Original solution: 1000.0103000 g Original solution / Rock added: 323627.93 (Water/Rock Ratio), log = 5.5100 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0216 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9987E+00 0.9859 0.1006E+01 0.1020E+01 CO2,gas 0.1367E-05 1.0071 0.1406E-05 0.1396E-05 CH4,gas 0.2033E-03 1.0125 0.2103E-03 0.2077E-03 H2,gas 0.1082E-02 1.0005 0.1106E-02 0.1106E-02 H2S,gas 0.6112E-06 0.9960 0.6219E-06 0.6244E-06 S2,gas 0.1161E-25 1.0000 0.1186E-25 0.1186E-25 CO,gas 0.4058E-12 1.0000 0.4146E-12 0.4146E-12 SO3,gas 0.1133E-42 1.0000 0.1157E-42 0.1157E-42 SO2,gas 0.4876E-23 1.0000 0.4982E-23 0.4982E-23 HF,gas 0.1593E-14 1.0000 0.1627E-14 0.1627E-14 HCl,gas 0.3582E-17 1.0000 0.3660E-17 0.3660E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 17 albite -0.38 -0.38 0.00 0.000 -0.94784E-12 23 andradite 39.01 39.01 0.00 0.000 0.12132E-10 24 grossular 32.73 32.73 0.00 0.000 0.00000E+00 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -14.21 -7.55 -2.517 0.12893E+05 -5.852 3 CH4,gas 4.54 -0.83 -5.38 -1.344 0.91796E+04 -3.677 4 H2,gas 8.00 3.34 -4.66 -2.660 0.79485E+04 -2.956 5 H2S,gas -6.23 -14.14 -7.91 -3.953 0.13498E+05 -6.206 6 S2,gas -7.34 -34.96 -27.62 -4.250 0.47169E+05 -25.926 7 CO,gas 3.21 -10.87 -14.08 -4.333 0.24044E+05 -12.382 8 SO3,gas 17.12 -27.51 -44.64 -11.159 0.76214E+05 -42.937 9 SO2,gas 0.83 -24.17 -25.00 -6.667 0.42690E+05 -23.303 10 HF,gas 0.47 -16.01 -16.49 -8.244 0.28152E+05 -14.789 11 HCl,gas 5.19 -13.95 -19.14 -9.568 0.32673E+05 -17.437 12 acmite 7.71 6.89 -0.82 -0.085 0.13970E+04 16 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 20 spessartine 24.46 19.69 -4.76 -0.238 0.81330E+04 21 analcite 3.32 2.75 -0.57 -0.063 0.97419E+03 27 annite 20.12 17.04 -3.08 -0.171 0.52658E+04 28 phlogopite 27.06 25.26 -1.80 -0.100 0.30789E+04 30 anorthite 12.71 8.01 -4.70 -0.362 0.80286E+04 33 apatite-OH -18.15 -19.09 -0.94 -0.072 0.15987E+04 34 apatite-F -34.30 -35.10 -0.80 -0.067 0.13711E+04 38 aragonite 0.97 -1.32 -2.29 -0.764 0.39122E+04 39 brucite 12.57 9.25 -3.32 -0.664 0.56675E+04 40 calcite 0.81 -1.32 -2.14 -0.712 0.36480E+04 41 carnegieite-low 9.02 5.89 -3.14 -0.448 0.53560E+04 42 carnegieite-high 10.09 5.89 -4.21 -0.601 0.71830E+04 43 carpholite-Mg 8.58 4.37 -4.21 -0.281 0.71898E+04 45 celadonite 5.34 3.63 -1.71 -0.101 0.29267E+04 46 celadonite-Fe 3.88 0.89 -2.99 -0.176 0.51048E+04 47 chrysotile 23.89 21.48 -2.41 -0.201 0.41230E+04 49 clinochlore 39.07 38.23 -0.84 -0.026 0.14274E+04 50 daphnite 28.97 24.53 -4.44 -0.139 0.75727E+04 52 chlorite-Al-free 47.17 42.96 -4.22 -0.176 0.72012E+04 54 chloritoid-Fe 9.17 4.77 -4.41 -0.294 0.75262E+04 55 chloritoid-Mn 11.40 7.49 -3.91 -0.261 0.66731E+04 57 coesite -2.38 -3.14 -0.76 -0.253 0.12962E+04 64 cristobalite -2.56 -3.14 -0.57 -0.192 0.98153E+03 66 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71237E+04 68 diaspore 2.87 0.70 -2.18 -0.363 0.37181E+04 69 diamond -3.10 -7.52 -4.42 -1.263 0.75459E+04 70 diopside 16.18 15.87 -0.32 -0.032 0.53957E+03 71 hedenbergite 14.21 13.12 -1.08 -0.108 0.18502E+04 76 clinoenstatite 17.17 12.23 -4.94 -0.494 0.84314E+04 78 epidote 24.67 22.60 -2.07 -0.101 0.35415E+04 79 clinozoisite 22.81 18.46 -4.35 -0.198 0.74282E+04 80 epidote-Fe 29.84 26.74 -3.10 -0.161 0.53013E+04 81 fayalite 14.05 9.88 -4.16 -0.595 0.71091E+04 82 ferrosilite 11.15 6.75 -4.40 -0.440 0.75171E+04 86 gibbsite 4.08 0.70 -3.38 -0.483 0.57767E+04 87 glaucophane 22.97 20.71 -2.26 -0.061 0.38671E+04 88 glaucophane-Fe 17.28 12.49 -4.79 -0.129 0.81751E+04 89 graphite -3.55 -7.52 -3.98 -1.136 0.67882E+04 90 greenalite 16.14 13.26 -2.88 -0.240 0.49240E+04 93 hematite 12.57 9.67 -2.89 -0.351 0.49405E+04 94 heulandite -5.83 -7.67 -1.84 -0.084 0.31424E+04 98 jadeite 4.22 2.75 -1.46 -0.146 0.24997E+04 100 kalsilite 7.58 3.78 -3.80 -0.543 0.64887E+04 101 kaolinite -1.33 -4.88 -3.55 -0.322 0.60535E+04 104 laumontite 2.88 1.74 -1.15 -0.076 0.19559E+04 105 lawsonite 9.62 8.01 -1.61 -0.107 0.27453E+04 106 leucite 4.12 0.65 -3.47 -0.347 0.59255E+04 108 lizardite 23.24 21.48 -1.77 -0.147 0.30156E+04 110 magnetite 20.09 16.18 -3.91 -0.319 0.66694E+04 111 minnesotaite 10.39 6.99 -3.40 -0.200 0.58101E+04 115 manganosite 14.06 9.24 -4.82 -1.206 0.82340E+04 119 microcline -2.49 -2.49 0.00 0.000 0.26941E+00 123 muscovite 2.58 -1.09 -3.68 -0.216 0.62780E+04 124 paragonite 4.24 1.01 -3.23 -0.190 0.55169E+04 125 nepheline 8.34 5.89 -2.45 -0.350 0.41883E+04 137 phlogopite-Na 29.65 27.36 -2.28 -0.127 0.38974E+04 139 prehnite 19.37 17.76 -1.61 -0.095 0.27532E+04 140 prehnite-Fe 22.50 21.90 -0.60 -0.036 0.10214E+04 141 pumpellyite-Fe 46.27 42.72 -3.55 -0.079 0.60542E+04 142 pumpellyite-Mg 48.99 45.46 -3.53 -0.078 0.60282E+04 145 pyrite -21.25 -25.11 -3.86 -0.908 0.65909E+04 146 pyrrhotite -4.26 -7.63 -3.37 -1.122 0.57482E+04 147 pyrrhotiteFe0.875 -6.02 -8.86 -2.84 -1.044 0.48461E+04 148 pyroxmangite 7.40 6.10 -1.30 -0.260 0.22164E+04 149 pyrophyllite -6.18 -11.15 -4.97 -0.311 0.84907E+04 150 quartz -2.99 -3.14 -0.15 -0.049 0.24886E+03 154 rhodochrosite -0.98 -4.98 -4.00 -1.333 0.68281E+04 155 rhodonite 7.45 6.10 -1.35 -0.269 0.22966E+04 156 sanidine -1.28 -2.49 -1.21 -0.093 0.20680E+04 166 stilbite -7.52 -7.67 -0.15 -0.007 0.24860E+03 167 stilpnomelane-Fe 13.02 11.97 -1.05 -0.031 0.17951E+04 168 stilpnomelane-Mg 27.44 25.67 -1.77 -0.053 0.30263E+04 174 talc 16.49 15.21 -1.28 -0.076 0.21919E+04 177 tephroite 18.09 15.34 -2.75 -0.393 0.46945E+04 181 tridymite -2.63 -3.14 -0.51 -0.170 0.86884E+03 182 tremolite 47.87 46.94 -0.93 -0.025 0.15900E+04 184 troilite-low -4.41 -7.63 -3.22 -1.072 0.54910E+04 190 wairakite 3.95 1.74 -2.21 -0.130 0.37779E+04 191 walstromite 11.51 9.75 -1.76 -0.352 0.30018E+04 192 wollastonite 10.46 9.75 -0.71 -0.142 0.12123E+04 193 pseudo-wollastonite 11.00 9.75 -1.25 -0.250 0.21321E+04 194 zoisite 22.85 18.46 -4.39 -0.200 0.75023E+04 195 akaganeite 7.75 4.84 -2.92 -0.631 0.49828E+04 202 chalcedony -2.80 -3.14 -0.33 -0.111 0.56816E+03 204 montmorillonite-Ca -2.29 -6.20 -3.91 -0.242 0.66744E+04 205 montmorillonite-K -2.24 -6.27 -4.04 -0.247 0.68908E+04 206 montmorillonite-Mg -2.48 -6.80 -4.32 -0.267 0.73761E+04 207 montmorillonite-Na -2.04 -5.58 -3.54 -0.217 0.60456E+04 208 nontronite-Ca 3.21 0.52 -2.69 -0.175 0.45965E+04 209 nontronite-H 2.53 -1.60 -4.14 -0.277 0.70627E+04 210 nontronite-K 3.34 0.45 -2.89 -0.186 0.49361E+04 211 nontronite-Mg 3.07 -0.08 -3.15 -0.204 0.53822E+04 212 nontronite-Na 3.52 1.14 -2.38 -0.152 0.40569E+04 228 tobermorite 9.82 7.60 -2.22 -0.607 0.37972E+04 234 alabandite -0.98 -4.90 -3.92 -1.307 0.66964E+04 237 boehmite 4.41 0.70 -3.71 -0.618 0.63350E+04 239 ferrous-oxide 9.81 6.51 -3.30 -0.826 0.56396E+04 245 silica-amorphous -2.09 -3.14 -1.04 -0.348 0.17823E+04 247 an20ab80 2.02 1.29 -0.72 -0.056 0.12349E+04 248 an25ab75 2.65 1.71 -0.93 -0.072 0.15906E+04 249 an30ab70 3.28 2.13 -1.15 -0.088 0.19559E+04 250 tr.625ac.25prg.125 45.16 44.44 -0.72 -0.019 0.12348E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 0.0001000 MOLES Current total amount of reactant added: 0.0030900 MOLES New total amount of reactant added: 0.0031900 MOLES Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.5508E-08 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 8 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 0.0031900 Water: Moles liquid = 0.4985E+02 kg liquid = 0.8981E+00 Moles total = 0.4985E+02 kg total = 0.8980E+00 Activity = 1.0000 Stoichiometric ionic strength = .1153386E-01 Osmotic coef. = 0.9610 True ionic strength = .2020351E-01 Chg. balance for total moles = -.5508E-08 Max. difference allowed = 0.1567E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.93487E-10 -10.0292 0.78508E-10 -10.1051 0.83978E+00 -0.0758 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.17369E-03 -3.7602 0.14497E-03 -3.8387 0.83469E+00 -0.0785 4 SO4-- 0.44918E-06 -6.3476 0.23270E-06 -6.6332 0.51806E+00 -0.2856 5 HCO3- 0.96911E-04 -4.0136 0.81010E-04 -4.0915 0.83592E+00 -0.0778 6 HS- 0.11424E-03 -3.9422 0.95366E-04 -4.0206 0.83481E+00 -0.0784 7 Al+++ 0.10428E-28 -28.9818 0.23960E-29 -29.6205 0.22976E+00 -0.6387 8 H4SiO4 0.73374E-03 -3.1345 0.73374E-03 -3.1345 0.10000E+01 0.0000 9 Ca++ 0.89409E-07 -7.0486 0.45977E-07 -7.3375 0.51423E+00 -0.2888 10 Mg++ 0.21310E-10 -10.6714 0.10908E-10 -10.9623 0.51186E+00 -0.2908 11 Fe++ 0.33704E-13 -13.4723 0.17271E-13 -13.7627 0.51243E+00 -0.2904 12 K+ 0.15654E-03 -3.8054 0.13089E-03 -3.8831 0.83612E+00 -0.0777 13 Na+ 0.19872E-01 -1.7018 0.16584E-01 -1.7803 0.83454E+00 -0.0786 14 Mn++ 0.20680E-10 -10.6845 0.10606E-10 -10.9745 0.51286E+00 -0.2900 15 F- 0.15272E-05 -5.8161 0.12721E-05 -5.8955 0.83296E+00 -0.0794 16 HPO4-- 0.45365E-07 -7.3433 0.23505E-07 -7.6288 0.51814E+00 -0.2856 18 HSiO3- 0.10455E-01 -1.9807 0.87267E-02 -2.0592 0.83469E+00 -0.0785 19 Ca(HSiO3)+ 0.10926E-07 -7.9615 0.91374E-08 -8.0392 0.83630E+00 -0.0776 20 Mg(HSiO3)+ 0.32260E-11 -11.4913 0.26979E-11 -11.5690 0.83630E+00 -0.0776 21 NaHSiO3,aq 0.23407E-02 -2.6307 0.23407E-02 -2.6307 0.10000E+01 0.0000 22 AlO+ 0.63238E-16 -16.1990 0.52886E-16 -16.2767 0.83630E+00 -0.0776 24 HAlO2,aq 0.13415E-09 -9.8724 0.13415E-09 -9.8724 0.10000E+01 0.0000 25 AlO2- 0.45399E-05 -5.3430 0.37825E-05 -5.4222 0.83317E+00 -0.0793 26 CH4,aq 0.32363E-07 -7.4900 0.32249E-07 -7.4915 0.99648E+00 -0.0015 27 C2H6,aq 0.30978E-18 -18.5090 0.30869E-18 -18.5105 0.99648E+00 -0.0015 31 CO,aq 0.19663E-15 -15.7064 0.19663E-15 -15.7064 0.10000E+01 0.0000 32 CO2,aq 0.13638E-07 -7.8653 0.13590E-07 -7.8668 0.99648E+00 -0.0015 33 CO3-2 0.17435E-03 -3.7586 0.90129E-04 -4.0451 0.51696E+00 -0.2865 34 CaCO3,aq 0.51960E-07 -7.2843 0.51960E-07 -7.2843 0.10000E+01 0.0000 35 Ca(HCO3)+ 0.11368E-09 -9.9443 0.95074E-10 -10.0219 0.83630E+00 -0.0776 36 CaCl+ 0.12898E-10 -10.8895 0.10787E-10 -10.9671 0.83630E+00 -0.0776 37 CaCl2,aq 0.37153E-15 -15.4300 0.37153E-15 -15.4300 0.10000E+01 0.0000 38 CaF+ 0.10210E-11 -11.9910 0.85390E-12 -12.0686 0.83630E+00 -0.0776 39 CaOH+ 0.49907E-07 -7.3018 0.41738E-07 -7.3795 0.83630E+00 -0.0776 40 CaSO4,aq 0.33974E-11 -11.4688 0.33974E-11 -11.4688 0.10000E+01 0.0000 41 HCl,aq 0.20856E-14 -14.6808 0.20856E-14 -14.6808 0.10000E+01 0.0000 45 HF,aq 0.68367E-12 -12.1652 0.68367E-12 -12.1652 0.10000E+01 0.0000 46 HF2- 0.35177E-18 -18.4537 0.29362E-18 -18.5322 0.83469E+00 -0.0785 48 FeCl+ 0.47389E-17 -17.3243 0.39631E-17 -17.4020 0.83630E+00 -0.0776 51 FeF+ 0.13424E-17 -17.8721 0.11227E-17 -17.9497 0.83630E+00 -0.0776 53 FeO,aq 0.10890E-09 -9.9630 0.10890E-09 -9.9630 0.10000E+01 0.0000 54 FeOH+ 0.85624E-11 -11.0674 0.71608E-11 -11.1450 0.83630E+00 -0.0776 55 HFeO2- 0.17389E-07 -7.7597 0.14514E-07 -7.8382 0.83469E+00 -0.0785 56 FeO+ 0.26911E-16 -16.5701 0.22505E-16 -16.6477 0.83630E+00 -0.0776 58 FeO2- 0.89511E-09 -9.0481 0.74714E-09 -9.1266 0.83469E+00 -0.0785 59 HFeO2,aq 0.74602E-11 -11.1272 0.74602E-11 -11.1272 0.10000E+01 0.0000 60 H2,aq 0.57800E-06 -6.2381 0.57597E-06 -6.2396 0.99648E+00 -0.0015 61 KCl,aq 0.34391E-09 -9.4636 0.34391E-09 -9.4636 0.10000E+01 0.0000 63 KOH,aq 0.71197E-06 -6.1475 0.71197E-06 -6.1475 0.10000E+01 0.0000 64 KSO4- 0.56623E-09 -9.2470 0.47263E-09 -9.3255 0.83469E+00 -0.0785 65 MgCO3,aq 0.30899E-11 -11.5100 0.30899E-11 -11.5100 0.10000E+01 0.0000 66 Mg(HCO3)+ 0.27560E-13 -13.5597 0.23048E-13 -13.6374 0.83630E+00 -0.0776 67 MgCl+ 0.27735E-14 -14.5570 0.23195E-14 -14.6346 0.83630E+00 -0.0776 68 MgF+ 0.89734E-15 -15.0470 0.75044E-15 -15.1247 0.83630E+00 -0.0776 69 MgOH+ 0.65520E-10 -10.1836 0.54794E-10 -10.2613 0.83630E+00 -0.0776 71 MnF+ 0.27172E-15 -15.5659 0.22724E-15 -15.6435 0.83630E+00 -0.0776 72 MnO,aq 0.17820E-08 -8.7491 0.17820E-08 -8.7491 0.10000E+01 0.0000 73 MnOH+ 0.48846E-09 -9.3112 0.40850E-09 -9.3888 0.83630E+00 -0.0776 74 MnO2-2 0.18560E-10 -10.7314 0.95950E-11 -11.0180 0.51696E+00 -0.2865 75 HMnO2- 0.19772E-09 -9.7040 0.16503E-09 -9.7824 0.83469E+00 -0.0785 78 MnCl+ 0.11322E-13 -13.9461 0.94683E-14 -14.0237 0.83630E+00 -0.0776 79 MnSO4,aq 0.71250E-15 -15.1472 0.71250E-15 -15.1472 0.10000E+01 0.0000 80 NaCl,aq 0.79676E-06 -6.0987 0.79676E-06 -6.0987 0.10000E+01 0.0000 81 NaF,aq 0.49389E-08 -8.3064 0.49389E-08 -8.3064 0.10000E+01 0.0000 82 NaOH,aq 0.90757E-04 -4.0421 0.90757E-04 -4.0421 0.10000E+01 0.0000 84 OH- 0.88330E-02 -2.0539 0.73594E-02 -2.1332 0.83317E+00 -0.0793 89 HPO3-2 0.81613E-16 -16.0882 0.42190E-16 -16.3748 0.51696E+00 -0.2865 92 H3PO4,aq 0.10133E-17 -17.9943 0.10133E-17 -17.9943 0.10000E+01 0.0000 93 H2PO4- 0.40745E-10 -10.3899 0.34042E-10 -10.4680 0.83549E+00 -0.0781 94 PO4-3 0.10119E-08 -8.9949 0.24428E-09 -9.6121 0.24141E+00 -0.6173 98 HP2O7-3 0.10048E-17 -17.9979 0.23111E-18 -18.6362 0.23000E+00 -0.6383 99 P2O7-4 0.92080E-17 -17.0358 0.70325E-18 -18.1529 0.76373E-01 -1.1171 100 H2S,aq 0.23221E-07 -7.6341 0.23140E-07 -7.6356 0.99648E+00 -0.0015 101 S2-2 0.67680E-12 -12.1695 0.34988E-12 -12.4561 0.51696E+00 -0.2865 102 S3-2 0.36633E-19 -19.4361 0.18937E-19 -19.7227 0.51696E+00 -0.2865 107 SO3-2 0.33208E-13 -13.4788 0.17417E-13 -13.7590 0.52449E+00 -0.2803 108 HSO3- 0.10257E-15 -15.9890 0.85616E-16 -16.0674 0.83469E+00 -0.0785 109 HSO4- 0.21032E-13 -13.6771 0.17606E-13 -13.7543 0.83712E+00 -0.0772 111 S2O3-2 0.12236E-15 -15.9124 0.63253E-16 -16.1989 0.51696E+00 -0.2865 Charge balance for all species = -.6132E-08 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.9348737E-10 -.2191290E-01 -.2204825E+02 0.0000 2 H2O 0.1000000E+01 0.5550439E+02 0.9981793E+06 0.0000 3 Cl- 0.1736863E-03 0.1744834E-03 0.6175140E+01 6.2664 4 SO4-- 0.4491799E-06 0.2729985E-06 0.2617881E-01 13.5770 5 HCO3- 0.9691134E-04 0.2713555E-03 0.1652839E+02 6.0136 6 HS- 0.1142363E-03 0.1144362E-03 0.3778016E+01 6.0845 7 Al+++ 0.1042830E-28 0.4540012E-05 0.1222821E+00 0.6947 8 H4SiO4 0.7337357E-03 0.1352942E-01 0.1298111E+04 -3.1345 9 Ca++ 0.8940882E-07 0.2023328E-06 0.8094912E-02 12.8727 10 Mg++ 0.2131040E-10 0.9317714E-10 0.2261360E-05 9.2479 11 Fe++ 0.3370378E-13 0.1840862E-07 0.1026268E-02 6.4475 12 K+ 0.1565390E-03 0.1572519E-03 0.6138107E+01 6.2220 13 Na+ 0.1987179E-01 0.2230402E-01 0.5118681E+03 8.3248 14 Mn++ 0.2067995E-10 0.2507421E-08 0.1375118E-03 9.2357 15 F- 0.1527166E-05 0.1532107E-05 0.2905606E-01 4.2096 16 HPO4-- 0.4536507E-07 0.4641771E-07 0.4447333E-02 12.5813 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.1968306E-01 -.1968018E-01 -.2873019E-05 0.0000000E+00 2 H2O 0.4984902E+02 0.4984902E+02 -.2793650E-05 0.0000000E+00 3 Cl- 0.1567052E-03 0.1567052E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.2471900E-06 0.2451826E-06 0.2007414E-08 0.0000000E+00 5 HCO3- 0.2437070E-03 0.2437070E-03 0.0000000E+00 0.0000000E+00 6 HS- 0.1027743E-03 0.1027763E-03 -.2007414E-08 0.0000000E+00 7 Al+++ 0.4775352E-05 0.4077429E-05 0.6979234E-06 0.0000000E+00 8 H4SiO4 0.1215302E-01 0.1215090E-01 0.2115582E-05 0.0000000E+00 9 Ca++ 0.2080835E-06 0.1817171E-06 0.2636645E-07 0.0000000E+00 10 Mg++ 0.8368328E-10 0.8368328E-10 0.0000000E+00 0.0000000E+00 11 Fe++ 0.3259227E-07 0.1653296E-07 0.1605931E-07 0.0000000E+00 12 K+ 0.1412294E-03 0.1412294E-03 0.0000000E+00 0.0000000E+00 13 Na+ 0.2003215E-01 0.2003145E-01 0.6964050E-06 0.0000000E+00 14 Mn++ 0.2251939E-08 0.2251939E-08 0.0000000E+00 0.0000000E+00 15 F- 0.1376000E-05 0.1376000E-05 0.0000000E+00 0.0000000E+00 16 HPO4-- 0.4168819E-07 0.4168819E-07 0.0000000E+00 0.0000000E+00 Chg. balance for solid moles: 0.3176E-21 Mass of aqueous solution: 0.899683E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 0.0031900 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 0.6964E-06 -6.157 0.1826E-03 -3.738 97.64 0.7010E-04 andradite 0.8030E-08 -8.095 0.4081E-05 -5.389 2.182 0.1060E-05 grossular 0.7592E-09 -9.120 0.3420E-06 -6.466 0.1828 0.9515E-07 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.9136E+00 0.9136E+00 1.0000 -0.039 grossular 0.8638E-01 0.8638E-01 1.0000 -1.064 Solid products produced: Mass = 0.000187 g Volume = 0.000071 cm3 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.0031900 moles log = -2.4962 Original solution: 1000.0103000 g Original solution / Rock added: 313482.85 (Water/Rock Ratio), log = 5.4962 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0211 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9992E+00 0.9859 0.1006E+01 0.1020E+01 CO2,gas 0.1414E-05 1.0071 0.1454E-05 0.1444E-05 CH4,gas 0.4591E-04 1.0125 0.4747E-04 0.4688E-04 H2,gas 0.7401E-03 1.0005 0.7562E-03 0.7558E-03 H2S,gas 0.6254E-06 0.9960 0.6361E-06 0.6386E-06 S2,gas 0.2601E-25 1.0000 0.2656E-25 0.2656E-25 CO,gas 0.2870E-12 1.0000 0.2930E-12 0.2930E-12 SO3,gas 0.5311E-42 1.0000 0.5423E-42 0.5423E-42 SO2,gas 0.1562E-22 1.0000 0.1595E-22 0.1595E-22 HF,gas 0.1644E-14 1.0000 0.1679E-14 0.1679E-14 HCl,gas 0.3604E-17 1.0000 0.3680E-17 0.3680E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 17 albite -0.38 -0.38 0.00 0.000 -0.94784E-12 23 andradite 39.01 39.01 0.00 0.000 0.00000E+00 24 grossular 32.73 32.73 0.00 0.000 0.00000E+00 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -14.20 -7.54 -2.512 0.12868E+05 -5.837 3 CH4,gas 4.54 -1.48 -6.02 -1.506 0.10283E+05 -4.324 4 H2,gas 8.00 3.18 -4.82 -2.754 0.82306E+04 -3.121 5 H2S,gas -6.23 -14.13 -7.90 -3.948 0.13481E+05 -6.196 6 S2,gas -7.34 -34.61 -27.27 -4.196 0.46571E+05 -25.576 7 CO,gas 3.21 -11.02 -14.23 -4.379 0.24301E+05 -12.533 8 SO3,gas 17.12 -26.84 -43.96 -10.991 0.75069E+05 -42.266 9 SO2,gas 0.83 -23.66 -24.50 -6.532 0.41826E+05 -22.797 10 HF,gas 0.47 -16.00 -16.47 -8.237 0.28129E+05 -14.775 11 HCl,gas 5.19 -13.94 -19.13 -9.567 0.32669E+05 -17.434 12 acmite 7.71 6.91 -0.80 -0.083 0.13593E+04 16 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 20 spessartine 24.46 19.69 -4.76 -0.238 0.81345E+04 21 analcite 3.32 2.75 -0.57 -0.063 0.97542E+03 27 annite 20.12 16.86 -3.27 -0.182 0.55794E+04 28 phlogopite 27.06 25.26 -1.81 -0.100 0.30863E+04 30 anorthite 12.71 7.99 -4.72 -0.363 0.80542E+04 33 apatite-OH -18.15 -19.15 -1.00 -0.077 0.17074E+04 34 apatite-F -34.30 -35.15 -0.85 -0.071 0.14566E+04 38 aragonite 0.97 -1.32 -2.29 -0.763 0.39107E+04 39 brucite 12.57 9.25 -3.32 -0.664 0.56699E+04 40 calcite 0.81 -1.32 -2.14 -0.712 0.36465E+04 41 carnegieite-low 9.02 5.89 -3.14 -0.448 0.53585E+04 42 carnegieite-high 10.09 5.89 -4.21 -0.601 0.71855E+04 43 carpholite-Mg 8.58 4.37 -4.21 -0.281 0.71946E+04 45 celadonite 5.34 3.63 -1.71 -0.101 0.29280E+04 46 celadonite-Fe 3.88 0.83 -3.05 -0.179 0.52081E+04 47 chrysotile 23.89 21.47 -2.42 -0.201 0.41279E+04 49 clinochlore 39.07 38.23 -0.84 -0.026 0.14408E+04 50 daphnite 28.97 24.22 -4.74 -0.148 0.80964E+04 52 chlorite-Al-free 47.17 42.95 -4.22 -0.176 0.72110E+04 54 chloritoid-Fe 9.17 4.70 -4.47 -0.298 0.76343E+04 55 chloritoid-Mn 11.40 7.49 -3.91 -0.261 0.66768E+04 57 coesite -2.38 -3.13 -0.76 -0.253 0.12949E+04 64 cristobalite -2.56 -3.13 -0.57 -0.191 0.98030E+03 66 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71237E+04 68 diaspore 2.87 0.69 -2.18 -0.363 0.37205E+04 69 diamond -3.10 -7.84 -4.74 -1.353 0.80854E+04 70 diopside 16.18 15.85 -0.33 -0.033 0.56288E+03 71 hedenbergite 14.21 13.05 -1.16 -0.116 0.19756E+04 76 clinoenstatite 17.17 12.23 -4.94 -0.494 0.84338E+04 78 epidote 24.67 22.59 -2.08 -0.101 0.35526E+04 79 clinozoisite 22.81 18.43 -4.38 -0.199 0.74783E+04 80 epidote-Fe 29.84 26.75 -3.09 -0.160 0.52735E+04 81 fayalite 14.05 9.76 -4.29 -0.612 0.73169E+04 82 ferrosilite 11.15 6.63 -4.52 -0.452 0.77236E+04 86 gibbsite 4.08 0.69 -3.38 -0.484 0.57790E+04 87 glaucophane 22.97 20.71 -2.27 -0.061 0.38721E+04 88 glaucophane-Fe 17.28 12.31 -4.97 -0.134 0.84862E+04 89 graphite -3.55 -7.84 -4.29 -1.226 0.73277E+04 90 greenalite 16.14 13.07 -3.07 -0.255 0.52351E+04 93 hematite 12.57 9.72 -2.85 -0.346 0.48674E+04 94 heulandite -5.83 -7.68 -1.85 -0.084 0.31618E+04 98 jadeite 4.22 2.75 -1.46 -0.146 0.25009E+04 100 kalsilite 7.58 3.78 -3.80 -0.543 0.64912E+04 101 kaolinite -1.33 -4.88 -3.55 -0.322 0.60558E+04 104 laumontite 2.88 1.72 -1.16 -0.077 0.19790E+04 105 lawsonite 9.62 7.99 -1.62 -0.108 0.27709E+04 106 leucite 4.12 0.65 -3.47 -0.347 0.59267E+04 108 lizardite 23.24 21.47 -1.77 -0.147 0.30206E+04 110 magnetite 20.09 16.16 -3.92 -0.320 0.67008E+04 111 minnesotaite 10.39 6.80 -3.58 -0.211 0.61187E+04 115 manganosite 14.06 9.24 -4.82 -1.206 0.82341E+04 119 microcline -2.49 -2.49 0.00 0.000 0.28047E+00 123 muscovite 2.58 -1.10 -3.68 -0.216 0.62828E+04 124 paragonite 4.24 1.01 -3.23 -0.190 0.55216E+04 125 nepheline 8.34 5.89 -2.45 -0.351 0.41908E+04 137 phlogopite-Na 29.65 27.36 -2.29 -0.127 0.39048E+04 139 prehnite 19.37 17.73 -1.64 -0.096 0.28009E+04 140 prehnite-Fe 22.50 21.89 -0.60 -0.036 0.10301E+04 141 pumpellyite-Fe 46.27 42.61 -3.66 -0.081 0.62564E+04 142 pumpellyite-Mg 48.99 45.41 -3.59 -0.080 0.61284E+04 145 pyrite -21.25 -24.98 -3.74 -0.879 0.63798E+04 146 pyrrhotite -4.26 -7.68 -3.42 -1.139 0.58360E+04 147 pyrrhotiteFe0.875 -6.02 -8.88 -2.86 -1.052 0.48858E+04 148 pyroxmangite 7.40 6.10 -1.30 -0.259 0.22153E+04 149 pyrophyllite -6.18 -11.15 -4.97 -0.311 0.84905E+04 150 quartz -2.99 -3.13 -0.15 -0.048 0.24763E+03 154 rhodochrosite -0.98 -4.96 -3.98 -1.328 0.68034E+04 155 rhodonite 7.45 6.10 -1.34 -0.269 0.22956E+04 156 sanidine -1.28 -2.49 -1.21 -0.093 0.20680E+04 166 stilbite -7.52 -7.68 -0.16 -0.007 0.26802E+03 167 stilpnomelane-Fe 13.02 11.66 -1.35 -0.040 0.23132E+04 168 stilpnomelane-Mg 27.44 25.66 -1.78 -0.053 0.30342E+04 174 talc 16.49 15.21 -1.29 -0.076 0.21944E+04 177 tephroite 18.09 15.34 -2.75 -0.393 0.46935E+04 181 tridymite -2.63 -3.13 -0.51 -0.169 0.86760E+03 182 tremolite 47.87 46.91 -0.96 -0.026 0.16391E+04 184 troilite-low -4.41 -7.68 -3.27 -1.089 0.55788E+04 190 wairakite 3.95 1.72 -2.23 -0.131 0.38010E+04 191 walstromite 11.51 9.74 -1.77 -0.354 0.30239E+04 192 wollastonite 10.46 9.74 -0.72 -0.145 0.12343E+04 193 pseudo-wollastonite 11.00 9.74 -1.26 -0.252 0.21542E+04 194 zoisite 22.85 18.43 -4.42 -0.201 0.75524E+04 195 akaganeite 7.75 4.86 -2.90 -0.626 0.49462E+04 202 chalcedony -2.80 -3.13 -0.33 -0.111 0.56692E+03 204 montmorillonite-Ca -2.29 -6.20 -3.91 -0.242 0.66781E+04 205 montmorillonite-K -2.24 -6.27 -4.04 -0.247 0.68911E+04 206 montmorillonite-Mg -2.48 -6.80 -4.32 -0.267 0.73763E+04 207 montmorillonite-Na -2.04 -5.58 -3.54 -0.217 0.60459E+04 208 nontronite-Ca 3.21 0.57 -2.65 -0.172 0.45234E+04 209 nontronite-H 2.53 -1.56 -4.09 -0.274 0.69859E+04 210 nontronite-K 3.34 0.49 -2.85 -0.183 0.48597E+04 211 nontronite-Mg 3.07 -0.03 -3.11 -0.202 0.53058E+04 212 nontronite-Na 3.52 1.19 -2.33 -0.150 0.39804E+04 228 tobermorite 9.82 7.59 -2.23 -0.610 0.38154E+04 234 alabandite -0.98 -4.89 -3.91 -1.304 0.66798E+04 237 boehmite 4.41 0.69 -3.71 -0.619 0.63374E+04 239 ferrous-oxide 9.81 6.45 -3.36 -0.841 0.57441E+04 245 silica-amorphous -2.09 -3.13 -1.04 -0.348 0.17811E+04 247 an20ab80 2.02 1.29 -0.73 -0.056 0.12400E+04 248 an25ab75 2.65 1.71 -0.94 -0.072 0.15970E+04 249 an30ab70 3.28 2.13 -1.15 -0.088 0.19635E+04 250 tr.625ac.25prg.125 45.16 44.34 -0.83 -0.022 0.14125E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 0.0001000 MOLES Current total amount of reactant added: 0.0031900 MOLES New total amount of reactant added: 0.0032900 MOLES Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.5508E-08 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 7 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 0.0032900 Water: Moles liquid = 0.4985E+02 kg liquid = 0.8981E+00 Moles total = 0.4985E+02 kg total = 0.8980E+00 Activity = 1.0000 Stoichiometric ionic strength = .1154025E-01 Osmotic coef. = 0.9607 True ionic strength = .2020944E-01 Chg. balance for total moles = -.5508E-08 Max. difference allowed = 0.1573E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.93656E-10 -10.0285 0.78649E-10 -10.1043 0.83976E+00 -0.0758 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.17434E-03 -3.7586 0.14552E-03 -3.8371 0.83467E+00 -0.0785 4 SO4-- 0.94014E-06 -6.0268 0.48702E-06 -6.3125 0.51802E+00 -0.2857 5 HCO3- 0.99904E-04 -4.0004 0.83510E-04 -4.0783 0.83590E+00 -0.0778 6 HS- 0.11645E-03 -3.9339 0.97212E-04 -4.0123 0.83480E+00 -0.0784 7 Al+++ 0.10453E-28 -28.9808 0.24012E-29 -29.6196 0.22972E+00 -0.6388 8 H4SiO4 0.73496E-03 -3.1337 0.73496E-03 -3.1337 0.10000E+01 0.0000 9 Ca++ 0.88065E-07 -7.0552 0.45282E-07 -7.3441 0.51419E+00 -0.2889 10 Mg++ 0.21318E-10 -10.6713 0.10911E-10 -10.9621 0.51182E+00 -0.2909 11 Fe++ 0.31801E-13 -13.4976 0.16295E-13 -13.7880 0.51239E+00 -0.2904 12 K+ 0.15654E-03 -3.8054 0.13088E-03 -3.8831 0.83610E+00 -0.0777 13 Na+ 0.19872E-01 -1.7018 0.16584E-01 -1.7803 0.83452E+00 -0.0786 14 Mn++ 0.20751E-10 -10.6830 0.10641E-10 -10.9730 0.51282E+00 -0.2900 15 F- 0.15716E-05 -5.8037 0.13090E-05 -5.8831 0.83294E+00 -0.0794 16 HPO4-- 0.45367E-07 -7.3433 0.23504E-07 -7.6289 0.51810E+00 -0.2856 18 HSiO3- 0.10454E-01 -1.9807 0.87257E-02 -2.0592 0.83467E+00 -0.0785 19 Ca(HSiO3)+ 0.10760E-07 -7.9682 0.89983E-08 -8.0458 0.83628E+00 -0.0776 20 Mg(HSiO3)+ 0.32265E-11 -11.4913 0.26983E-11 -11.5689 0.83628E+00 -0.0776 21 NaHSiO3,aq 0.23404E-02 -2.6307 0.23404E-02 -2.6307 0.10000E+01 0.0000 22 AlO+ 0.63149E-16 -16.1996 0.52810E-16 -16.2773 0.83628E+00 -0.0776 24 HAlO2,aq 0.13372E-09 -9.8738 0.13372E-09 -9.8738 0.10000E+01 0.0000 25 AlO2- 0.45173E-05 -5.3451 0.37636E-05 -5.4244 0.83316E+00 -0.0793 26 CH4,aq 0.16249E-07 -7.7892 0.16192E-07 -7.7907 0.99648E+00 -0.0015 27 C2H6,aq 0.93522E-19 -19.0291 0.93193E-19 -19.0306 0.99648E+00 -0.0015 31 CO,aq 0.16956E-15 -15.7707 0.16956E-15 -15.7707 0.10000E+01 0.0000 32 CO2,aq 0.14084E-07 -7.8513 0.14034E-07 -7.8528 0.99648E+00 -0.0015 33 CO3-2 0.17942E-03 -3.7461 0.92744E-04 -4.0327 0.51692E+00 -0.2866 34 CaCO3,aq 0.52659E-07 -7.2785 0.52659E-07 -7.2785 0.10000E+01 0.0000 35 Ca(HCO3)+ 0.11542E-09 -9.9377 0.96527E-10 -10.0154 0.83628E+00 -0.0776 36 CaCl+ 0.12751E-10 -10.8944 0.10664E-10 -10.9721 0.83628E+00 -0.0776 37 CaCl2,aq 0.36866E-15 -15.4334 0.36866E-15 -15.4334 0.10000E+01 0.0000 38 CaF+ 0.10348E-11 -11.9851 0.86543E-12 -12.0628 0.83628E+00 -0.0776 39 CaOH+ 0.49067E-07 -7.3092 0.41034E-07 -7.3869 0.83628E+00 -0.0776 40 CaSO4,aq 0.70029E-11 -11.1547 0.70029E-11 -11.1547 0.10000E+01 0.0000 41 HCl,aq 0.20972E-14 -14.6784 0.20972E-14 -14.6784 0.10000E+01 0.0000 45 HF,aq 0.70478E-12 -12.1519 0.70478E-12 -12.1519 0.10000E+01 0.0000 46 HF2- 0.37318E-18 -18.4281 0.31148E-18 -18.5066 0.83467E+00 -0.0785 48 FeCl+ 0.44878E-17 -17.3480 0.37531E-17 -17.4256 0.83628E+00 -0.0776 51 FeF+ 0.13034E-17 -17.8849 0.10900E-17 -17.9626 0.83628E+00 -0.0776 53 FeO,aq 0.10238E-09 -9.9898 0.10238E-09 -9.9898 0.10000E+01 0.0000 54 FeOH+ 0.80642E-11 -11.0934 0.67439E-11 -11.1711 0.83628E+00 -0.0776 55 HFeO2- 0.16318E-07 -7.7873 0.13620E-07 -7.8658 0.83467E+00 -0.0785 56 FeO+ 0.27735E-16 -16.5570 0.23195E-16 -16.6346 0.83628E+00 -0.0776 58 FeO2- 0.91925E-09 -9.0366 0.76728E-09 -9.1150 0.83467E+00 -0.0785 59 HFeO2,aq 0.76750E-11 -11.1149 0.76750E-11 -11.1149 0.10000E+01 0.0000 60 H2,aq 0.48265E-06 -6.3164 0.48095E-06 -6.3179 0.99648E+00 -0.0015 61 KCl,aq 0.34519E-09 -9.4619 0.34519E-09 -9.4619 0.10000E+01 0.0000 62 KHSO4,aq 0.14174E-19 -19.8485 0.14174E-19 -19.8485 0.10000E+01 0.0000 63 KOH,aq 0.71068E-06 -6.1483 0.71068E-06 -6.1483 0.10000E+01 0.0000 64 KSO4- 0.11850E-08 -8.9263 0.98912E-09 -9.0047 0.83467E+00 -0.0785 65 MgCO3,aq 0.31804E-11 -11.4975 0.31804E-11 -11.4975 0.10000E+01 0.0000 66 Mg(HCO3)+ 0.28418E-13 -13.5464 0.23766E-13 -13.6241 0.83628E+00 -0.0776 67 MgCl+ 0.27847E-14 -14.5552 0.23288E-14 -14.6329 0.83628E+00 -0.0776 68 MgF+ 0.92365E-15 -15.0345 0.77244E-15 -15.1121 0.83628E+00 -0.0776 69 MgOH+ 0.65420E-10 -10.1843 0.54710E-10 -10.2619 0.83628E+00 -0.0776 71 MnF+ 0.28056E-15 -15.5520 0.23463E-15 -15.6296 0.83628E+00 -0.0776 72 MnO,aq 0.17816E-08 -8.7492 0.17816E-08 -8.7492 0.10000E+01 0.0000 73 MnOH+ 0.48924E-09 -9.3105 0.40914E-09 -9.3881 0.83628E+00 -0.0776 74 MnO2-2 0.18492E-10 -10.7330 0.95586E-11 -11.0196 0.51692E+00 -0.2866 75 HMnO2- 0.19732E-09 -9.7048 0.16470E-09 -9.7833 0.83467E+00 -0.0785 78 MnCl+ 0.11402E-13 -13.9430 0.95357E-14 -14.0206 0.83628E+00 -0.0776 79 MnSO4,aq 0.14962E-14 -14.8250 0.14962E-14 -14.8250 0.10000E+01 0.0000 80 NaCl,aq 0.79974E-06 -6.0970 0.79974E-06 -6.0970 0.10000E+01 0.0000 81 NaF,aq 0.50823E-08 -8.2939 0.50823E-08 -8.2939 0.10000E+01 0.0000 82 NaOH,aq 0.90595E-04 -4.0429 0.90595E-04 -4.0429 0.10000E+01 0.0000 84 OH- 0.88174E-02 -2.0547 0.73462E-02 -2.1339 0.83316E+00 -0.0793 89 HPO3-2 0.68152E-16 -16.1665 0.35229E-16 -16.4531 0.51692E+00 -0.2866 92 H3PO4,aq 0.10168E-17 -17.9927 0.10168E-17 -17.9927 0.10000E+01 0.0000 93 H2PO4- 0.40817E-10 -10.3892 0.34101E-10 -10.4672 0.83547E+00 -0.0781 94 PO4-3 0.10102E-08 -8.9956 0.24383E-09 -9.6129 0.24137E+00 -0.6173 98 HP2O7-3 0.10067E-17 -17.9971 0.23150E-18 -18.6354 0.22996E+00 -0.6384 99 P2O7-4 0.92101E-17 -17.0357 0.70319E-18 -18.1529 0.76350E-01 -1.1172 100 H2S,aq 0.23713E-07 -7.6250 0.23630E-07 -7.6265 0.99648E+00 -0.0015 101 S2-2 0.84226E-12 -12.0746 0.43538E-12 -12.3611 0.51692E+00 -0.2866 102 S3-2 0.55751E-19 -19.2537 0.28818E-19 -19.5403 0.51692E+00 -0.2866 107 SO3-2 0.58039E-13 -13.2363 0.30438E-13 -13.5166 0.52445E+00 -0.2803 108 HSO3- 0.17958E-15 -15.7457 0.14989E-15 -15.8242 0.83467E+00 -0.0785 109 HSO4- 0.44097E-13 -13.3556 0.36913E-13 -13.4328 0.83710E+00 -0.0772 111 S2O3-2 0.26152E-15 -15.5825 0.13518E-15 -15.8691 0.51692E+00 -0.2866 Charge balance for all species = -.6132E-08 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.9365629E-10 -.2190077E-01 -.2203605E+02 0.0000 2 H2O 0.1000000E+01 0.5550437E+02 0.9981786E+06 0.0000 3 Cl- 0.1743399E-03 0.1751400E-03 0.6198375E+01 6.2672 4 SO4-- 0.9401418E-06 0.8045377E-06 0.7714997E-01 13.8962 5 HCO3- 0.9990352E-04 0.2794052E-03 0.1701870E+02 6.0260 6 HS- 0.1164497E-03 0.1166102E-03 0.3849785E+01 6.0920 7 Al+++ 0.1045253E-28 0.4517441E-05 0.1216741E+00 0.6933 8 H4SiO4 0.7349608E-03 0.1352933E-01 0.1298102E+04 -3.1337 9 Ca++ 0.8806503E-07 0.2006872E-06 0.8029072E-02 12.8645 10 Mg++ 0.2131751E-10 0.9317696E-10 0.2261355E-05 9.2465 11 Fe++ 0.3180116E-13 0.1735565E-07 0.9675653E-03 6.4207 12 K+ 0.1565393E-03 0.1572516E-03 0.6138093E+01 6.2212 13 Na+ 0.1987217E-01 0.2230395E-01 0.5118664E+03 8.3240 14 Mn++ 0.2075108E-10 0.2507416E-08 0.1375115E-03 9.2356 15 F- 0.1571558E-05 0.1576642E-05 0.2990064E-01 4.2213 16 HPO4-- 0.4536659E-07 0.4641762E-07 0.4447323E-02 12.5798 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.1967229E-01 -.1966933E-01 -.2958765E-05 0.0000000E+00 2 H2O 0.4984910E+02 0.4984911E+02 -.2875022E-05 0.0000000E+00 3 Cl- 0.1572952E-03 0.1572952E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.7246900E-06 0.7225644E-06 0.2125621E-08 0.0000000E+00 5 HCO3- 0.2509370E-03 0.2509370E-03 0.0000000E+00 0.0000000E+00 6 HS- 0.1047268E-03 0.1047289E-03 -.2125621E-08 0.0000000E+00 7 Al+++ 0.4775352E-05 0.4057164E-05 0.7181877E-06 0.0000000E+00 8 H4SiO4 0.1215302E-01 0.1215084E-01 0.2177734E-05 0.0000000E+00 9 Ca++ 0.2080835E-06 0.1802395E-06 0.2784403E-07 0.0000000E+00 10 Mg++ 0.8368328E-10 0.8368328E-10 0.0000000E+00 0.0000000E+00 11 Fe++ 0.3259227E-07 0.1558731E-07 0.1700496E-07 0.0000000E+00 12 K+ 0.1412294E-03 0.1412294E-03 0.0000000E+00 0.0000000E+00 13 Na+ 0.2003215E-01 0.2003143E-01 0.7166299E-06 0.0000000E+00 14 Mn++ 0.2251939E-08 0.2251939E-08 0.0000000E+00 0.0000000E+00 15 F- 0.1416000E-05 0.1416000E-05 0.0000000E+00 0.0000000E+00 16 HPO4-- 0.4168819E-07 0.4168819E-07 0.0000000E+00 0.0000000E+00 Chg. balance for solid moles: -.1059E-21 Mass of aqueous solution: 0.899685E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 0.0032900 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 0.7166E-06 -6.145 0.1879E-03 -3.726 97.57 0.7214E-04 andradite 0.8502E-08 -8.070 0.4321E-05 -5.364 2.244 0.1123E-05 grossular 0.7789E-09 -9.109 0.3508E-06 -6.455 0.1822 0.9762E-07 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.9161E+00 0.9161E+00 1.0000 -0.038 grossular 0.8392E-01 0.8392E-01 1.0000 -1.076 Solid products produced: Mass = 0.000193 g Volume = 0.000073 cm3 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.0032900 moles log = -2.4828 Original solution: 1000.0103000 g Original solution / Rock added: 303954.50 (Water/Rock Ratio), log = 5.4828 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0210 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9994E+00 0.9859 0.1006E+01 0.1020E+01 CO2,gas 0.1460E-05 1.0071 0.1502E-05 0.1491E-05 CH4,gas 0.2306E-04 1.0125 0.2383E-04 0.2354E-04 H2,gas 0.6181E-03 1.0005 0.6314E-03 0.6311E-03 H2S,gas 0.6388E-06 0.9960 0.6496E-06 0.6521E-06 S2,gas 0.3891E-25 1.0000 0.3972E-25 0.3972E-25 CO,gas 0.2475E-12 1.0000 0.2527E-12 0.2527E-12 SO3,gas 0.1116E-41 1.0000 0.1139E-41 0.1139E-41 SO2,gas 0.2741E-22 1.0000 0.2798E-22 0.2798E-22 HF,gas 0.1695E-14 1.0000 0.1730E-14 0.1730E-14 HCl,gas 0.3625E-17 1.0000 0.3701E-17 0.3701E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 17 albite -0.38 -0.38 0.00 0.000 -0.94784E-12 23 andradite 39.01 39.01 0.00 0.000 0.24265E-10 24 grossular 32.73 32.73 0.00 0.000 0.24265E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -14.18 -7.52 -2.507 0.12844E+05 -5.823 3 CH4,gas 4.54 -1.78 -6.32 -1.580 0.10794E+05 -4.623 4 H2,gas 8.00 3.10 -4.90 -2.799 0.83643E+04 -3.200 5 H2S,gas -6.23 -14.12 -7.89 -3.943 0.13466E+05 -6.187 6 S2,gas -7.34 -34.44 -27.10 -4.169 0.46272E+05 -25.401 7 CO,gas 3.21 -11.08 -14.30 -4.399 0.24411E+05 -12.597 8 SO3,gas 17.12 -26.52 -43.64 -10.911 0.74518E+05 -41.943 9 SO2,gas 0.83 -23.42 -24.25 -6.467 0.41410E+05 -22.553 10 HF,gas 0.47 -15.99 -16.46 -8.230 0.28106E+05 -14.762 11 HCl,gas 5.19 -13.94 -19.13 -9.565 0.32665E+05 -17.432 12 acmite 7.71 6.93 -0.78 -0.081 0.13371E+04 16 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 20 spessartine 24.46 19.69 -4.76 -0.238 0.81361E+04 21 analcite 3.32 2.75 -0.57 -0.064 0.97666E+03 27 annite 20.12 16.78 -3.35 -0.186 0.57168E+04 28 phlogopite 27.06 25.25 -1.81 -0.101 0.30937E+04 30 anorthite 12.71 7.98 -4.73 -0.364 0.80704E+04 33 apatite-OH -18.15 -19.19 -1.04 -0.080 0.17693E+04 34 apatite-F -34.30 -35.18 -0.88 -0.073 0.14958E+04 38 aragonite 0.97 -1.32 -2.28 -0.762 0.39008E+04 39 brucite 12.57 9.25 -3.32 -0.664 0.56724E+04 40 calcite 0.81 -1.32 -2.13 -0.710 0.36366E+04 41 carnegieite-low 9.02 5.88 -3.14 -0.449 0.53609E+04 42 carnegieite-high 10.09 5.88 -4.21 -0.601 0.71879E+04 43 carpholite-Mg 8.58 4.37 -4.22 -0.281 0.71994E+04 45 celadonite 5.34 3.63 -1.72 -0.101 0.29292E+04 46 celadonite-Fe 3.88 0.80 -3.08 -0.181 0.52526E+04 47 chrysotile 23.89 21.47 -2.42 -0.202 0.41329E+04 49 clinochlore 39.07 38.22 -0.85 -0.027 0.14542E+04 50 daphnite 28.97 24.09 -4.88 -0.152 0.83264E+04 52 chlorite-Al-free 47.17 42.94 -4.23 -0.176 0.72209E+04 54 chloritoid-Fe 9.17 4.67 -4.50 -0.300 0.76836E+04 55 chloritoid-Mn 11.40 7.49 -3.91 -0.261 0.66805E+04 57 coesite -2.38 -3.13 -0.76 -0.253 0.12937E+04 64 cristobalite -2.56 -3.13 -0.57 -0.191 0.97906E+03 66 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71237E+04 68 diaspore 2.87 0.69 -2.18 -0.363 0.37229E+04 69 diamond -3.10 -7.98 -4.88 -1.394 0.83289E+04 70 diopside 16.18 15.84 -0.34 -0.034 0.57681E+03 71 hedenbergite 14.21 13.02 -1.19 -0.119 0.20328E+04 76 clinoenstatite 17.17 12.23 -4.94 -0.494 0.84363E+04 78 epidote 24.67 22.58 -2.09 -0.101 0.35605E+04 79 clinozoisite 22.81 18.41 -4.40 -0.200 0.75096E+04 80 epidote-Fe 29.84 26.76 -3.08 -0.160 0.52580E+04 81 fayalite 14.05 9.71 -4.34 -0.620 0.74073E+04 82 ferrosilite 11.15 6.57 -4.58 -0.458 0.78127E+04 86 gibbsite 4.08 0.69 -3.39 -0.484 0.57814E+04 87 glaucophane 22.97 20.70 -2.27 -0.061 0.38770E+04 89 graphite -3.55 -7.98 -4.43 -1.267 0.75712E+04 90 greenalite 16.14 12.99 -3.15 -0.262 0.53700E+04 93 hematite 12.57 9.74 -2.83 -0.343 0.48253E+04 94 heulandite -5.83 -7.68 -1.86 -0.084 0.31719E+04 98 jadeite 4.22 2.75 -1.47 -0.147 0.25021E+04 100 kalsilite 7.58 3.78 -3.80 -0.543 0.64937E+04 101 kaolinite -1.33 -4.88 -3.55 -0.323 0.60581E+04 104 laumontite 2.88 1.72 -1.17 -0.078 0.19928E+04 105 lawsonite 9.62 7.98 -1.63 -0.109 0.27871E+04 106 leucite 4.12 0.65 -3.47 -0.347 0.59280E+04 108 lizardite 23.24 21.47 -1.77 -0.148 0.30255E+04 110 magnetite 20.09 16.16 -3.93 -0.321 0.67045E+04 111 minnesotaite 10.39 6.73 -3.66 -0.215 0.62512E+04 115 manganosite 14.06 9.24 -4.82 -1.206 0.82343E+04 119 microcline -2.49 -2.49 0.00 0.000 0.29237E+00 123 muscovite 2.58 -1.10 -3.68 -0.217 0.62876E+04 124 paragonite 4.24 1.00 -3.24 -0.190 0.55264E+04 125 nepheline 8.34 5.88 -2.46 -0.351 0.41933E+04 137 phlogopite-Na 29.65 27.36 -2.29 -0.127 0.39122E+04 139 prehnite 19.37 17.71 -1.66 -0.097 0.28298E+04 140 prehnite-Fe 22.50 21.89 -0.61 -0.036 0.10356E+04 141 pumpellyite-Fe 46.27 42.54 -3.73 -0.083 0.63625E+04 142 pumpellyite-Mg 48.99 45.37 -3.63 -0.081 0.61911E+04 145 pyrite -21.25 -24.91 -3.67 -0.863 0.62608E+04 146 pyrrhotite -4.26 -7.70 -3.44 -1.145 0.58662E+04 147 pyrrhotiteFe0.875 -6.02 -8.88 -2.87 -1.054 0.48938E+04 148 pyroxmangite 7.40 6.10 -1.30 -0.259 0.22142E+04 149 pyrophyllite -6.18 -11.15 -4.97 -0.311 0.84903E+04 150 quartz -2.99 -3.13 -0.14 -0.048 0.24639E+03 154 rhodochrosite -0.98 -4.95 -3.97 -1.324 0.67797E+04 155 rhodonite 7.45 6.10 -1.34 -0.269 0.22945E+04 156 sanidine -1.28 -2.49 -1.21 -0.093 0.20680E+04 166 stilbite -7.52 -7.68 -0.16 -0.008 0.27807E+03 167 stilpnomelane-Fe 13.02 11.53 -1.49 -0.044 0.25378E+04 168 stilpnomelane-Mg 27.44 25.66 -1.78 -0.053 0.30421E+04 174 talc 16.49 15.20 -1.29 -0.076 0.21968E+04 177 tephroite 18.09 15.34 -2.75 -0.393 0.46926E+04 181 tridymite -2.63 -3.13 -0.51 -0.169 0.86637E+03 182 tremolite 47.87 46.89 -0.98 -0.026 0.16694E+04 184 troilite-low -4.41 -7.70 -3.28 -1.095 0.56090E+04 190 wairakite 3.95 1.72 -2.23 -0.131 0.38148E+04 191 walstromite 11.51 9.73 -1.78 -0.356 0.30366E+04 192 wollastonite 10.46 9.73 -0.73 -0.146 0.12470E+04 193 pseudo-wollastonite 11.00 9.73 -1.27 -0.254 0.21669E+04 194 zoisite 22.85 18.41 -4.44 -0.202 0.75837E+04 195 akaganeite 7.75 4.87 -2.88 -0.624 0.49252E+04 202 chalcedony -2.80 -3.13 -0.33 -0.110 0.56569E+03 204 montmorillonite-Ca -2.29 -6.20 -3.91 -0.242 0.66802E+04 205 montmorillonite-K -2.24 -6.27 -4.04 -0.247 0.68914E+04 206 montmorillonite-Mg -2.48 -6.80 -4.32 -0.267 0.73766E+04 207 montmorillonite-Na -2.04 -5.58 -3.54 -0.217 0.60462E+04 208 nontronite-Ca 3.21 0.59 -2.62 -0.170 0.44799E+04 209 nontronite-H 2.53 -1.53 -4.06 -0.272 0.69400E+04 210 nontronite-K 3.34 0.52 -2.82 -0.181 0.48142E+04 211 nontronite-Mg 3.07 -0.01 -3.08 -0.200 0.52603E+04 212 nontronite-Na 3.52 1.22 -2.30 -0.148 0.39350E+04 228 tobermorite 9.82 7.58 -2.24 -0.611 0.38258E+04 234 alabandite -0.98 -4.88 -3.90 -1.301 0.66644E+04 237 boehmite 4.41 0.69 -3.71 -0.619 0.63398E+04 239 ferrous-oxide 9.81 6.42 -3.39 -0.848 0.57899E+04 245 silica-amorphous -2.09 -3.13 -1.04 -0.347 0.17799E+04 247 an20ab80 2.02 1.29 -0.73 -0.056 0.12432E+04 248 an25ab75 2.65 1.71 -0.94 -0.072 0.16010E+04 249 an30ab70 3.28 2.13 -1.15 -0.089 0.19684E+04 250 tr.625ac.25prg.125 45.16 44.29 -0.88 -0.024 0.14980E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 0.0001000 MOLES Current total amount of reactant added: 0.0032900 MOLES New total amount of reactant added: 0.0033900 MOLES Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.5508E-08 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 7 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 0.0033900 Water: Moles liquid = 0.4985E+02 kg liquid = 0.8981E+00 Moles total = 0.4985E+02 kg total = 0.8980E+00 Activity = 1.0000 Stoichiometric ionic strength = .1154664E-01 Osmotic coef. = 0.9603 True ionic strength = .2021539E-01 Chg. balance for total moles = -.5508E-08 Max. difference allowed = 0.1579E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.93826E-10 -10.0277 0.78790E-10 -10.1035 0.83975E+00 -0.0759 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.17499E-03 -3.7570 0.14606E-03 -3.8355 0.83466E+00 -0.0785 4 SO4-- 0.14539E-05 -5.8375 0.75308E-06 -6.1232 0.51798E+00 -0.2857 5 HCO3- 0.10290E-03 -3.9876 0.86011E-04 -4.0654 0.83589E+00 -0.0779 6 HS- 0.11864E-03 -3.9258 0.99039E-04 -4.0042 0.83478E+00 -0.0784 7 Al+++ 0.10477E-28 -28.9798 0.24064E-29 -29.6186 0.22968E+00 -0.6389 8 H4SiO4 0.73619E-03 -3.1330 0.73619E-03 -3.1330 0.10000E+01 0.0000 9 Ca++ 0.87120E-07 -7.0599 0.44793E-07 -7.3488 0.51415E+00 -0.2889 10 Mg++ 0.21325E-10 -10.6711 0.10914E-10 -10.9620 0.51178E+00 -0.2909 11 Fe++ 0.30938E-13 -13.5095 0.15851E-13 -13.7999 0.51235E+00 -0.2904 12 K+ 0.15654E-03 -3.8054 0.13088E-03 -3.8831 0.83609E+00 -0.0777 13 Na+ 0.19873E-01 -1.7017 0.16584E-01 -1.7803 0.83450E+00 -0.0786 14 Mn++ 0.20823E-10 -10.6815 0.10677E-10 -10.9715 0.51278E+00 -0.2901 15 F- 0.16159E-05 -5.7916 0.13460E-05 -5.8710 0.83292E+00 -0.0794 16 HPO4-- 0.45368E-07 -7.3432 0.23503E-07 -7.6289 0.51806E+00 -0.2856 18 HSiO3- 0.10453E-01 -1.9808 0.87246E-02 -2.0593 0.83466E+00 -0.0785 19 Ca(HSiO3)+ 0.10643E-07 -7.9730 0.89000E-08 -8.0506 0.83627E+00 -0.0777 20 Mg(HSiO3)+ 0.32270E-11 -11.4912 0.26987E-11 -11.5689 0.83627E+00 -0.0777 21 NaHSiO3,aq 0.23401E-02 -2.6308 0.23401E-02 -2.6308 0.10000E+01 0.0000 22 AlO+ 0.63060E-16 -16.2002 0.52735E-16 -16.2779 0.83627E+00 -0.0777 24 HAlO2,aq 0.13329E-09 -9.8752 0.13329E-09 -9.8752 0.10000E+01 0.0000 25 AlO2- 0.44948E-05 -5.3473 0.37448E-05 -5.4266 0.83314E+00 -0.0793 26 CH4,aq 0.11027E-07 -7.9576 0.10988E-07 -7.9591 0.99648E+00 -0.0015 27 C2H6,aq 0.47822E-19 -19.3204 0.47653E-19 -19.3219 0.99648E+00 -0.0015 31 CO,aq 0.15755E-15 -15.8026 0.15755E-15 -15.8026 0.10000E+01 0.0000 32 CO2,aq 0.14532E-07 -7.8377 0.14480E-07 -7.8392 0.99648E+00 -0.0015 33 CO3-2 0.18448E-03 -3.7341 0.95352E-04 -4.0207 0.51688E+00 -0.2866 34 CaCO3,aq 0.53555E-07 -7.2712 0.53555E-07 -7.2712 0.10000E+01 0.0000 35 Ca(HCO3)+ 0.11760E-09 -9.9296 0.98344E-10 -10.0073 0.83627E+00 -0.0777 36 CaCl+ 0.12661E-10 -10.8975 0.10588E-10 -10.9752 0.83627E+00 -0.0777 37 CaCl2,aq 0.36740E-15 -15.4349 0.36740E-15 -15.4349 0.10000E+01 0.0000 38 CaF+ 0.10526E-11 -11.9777 0.88023E-12 -12.0554 0.83627E+00 -0.0777 39 CaOH+ 0.48450E-07 -7.3147 0.40517E-07 -7.3924 0.83627E+00 -0.0777 40 CaSO4,aq 0.10712E-10 -10.9701 0.10712E-10 -10.9701 0.10000E+01 0.0000 41 HCl,aq 0.21088E-14 -14.6760 0.21088E-14 -14.6760 0.10000E+01 0.0000 45 HF,aq 0.72597E-12 -12.1391 0.72597E-12 -12.1391 0.10000E+01 0.0000 46 HF2- 0.39526E-18 -18.4031 0.32991E-18 -18.4816 0.83466E+00 -0.0785 48 FeCl+ 0.43820E-17 -17.3583 0.36645E-17 -17.4360 0.83627E+00 -0.0777 51 FeF+ 0.13037E-17 -17.8848 0.10902E-17 -17.9625 0.83627E+00 -0.0777 53 FeO,aq 0.99238E-10 -10.0033 0.99238E-10 -10.0033 0.10000E+01 0.0000 54 FeOH+ 0.78307E-11 -11.1062 0.65486E-11 -11.1839 0.83627E+00 -0.0777 55 HFeO2- 0.15789E-07 -7.8016 0.13179E-07 -7.8801 0.83466E+00 -0.0785 56 FeO+ 0.28381E-16 -16.5470 0.23734E-16 -16.6246 0.83627E+00 -0.0777 58 FeO2- 0.93728E-09 -9.0281 0.78231E-09 -9.1066 0.83466E+00 -0.0785 59 HFeO2,aq 0.78394E-11 -11.1057 0.78394E-11 -11.1057 0.10000E+01 0.0000 60 H2,aq 0.43465E-06 -6.3619 0.43312E-06 -6.3634 0.99648E+00 -0.0015 61 KCl,aq 0.34647E-09 -9.4603 0.34647E-09 -9.4603 0.10000E+01 0.0000 62 KHSO4,aq 0.21957E-19 -19.6584 0.21957E-19 -19.6584 0.10000E+01 0.0000 63 KOH,aq 0.70940E-06 -6.1491 0.70940E-06 -6.1491 0.10000E+01 0.0000 64 KSO4- 0.18325E-08 -8.7370 0.15295E-08 -8.8155 0.83466E+00 -0.0785 65 MgCO3,aq 0.32707E-11 -11.4854 0.32707E-11 -11.4854 0.10000E+01 0.0000 66 Mg(HCO3)+ 0.29277E-13 -13.5335 0.24484E-13 -13.6111 0.83627E+00 -0.0777 67 MgCl+ 0.27958E-14 -14.5535 0.23380E-14 -14.6311 0.83627E+00 -0.0777 68 MgF+ 0.94999E-15 -15.0223 0.79444E-15 -15.0999 0.83627E+00 -0.0777 69 MgOH+ 0.65321E-10 -10.1849 0.54626E-10 -10.2626 0.83627E+00 -0.0777 71 MnF+ 0.28946E-15 -15.5384 0.24206E-15 -15.6161 0.83627E+00 -0.0777 72 MnO,aq 0.17812E-08 -8.7493 0.17812E-08 -8.7493 0.10000E+01 0.0000 73 MnOH+ 0.49002E-09 -9.3098 0.40978E-09 -9.3874 0.83627E+00 -0.0777 74 MnO2-2 0.18423E-10 -10.7346 0.95224E-11 -11.0213 0.51688E+00 -0.2866 75 HMnO2- 0.19693E-09 -9.7057 0.16437E-09 -9.7842 0.83466E+00 -0.0785 78 MnCl+ 0.11484E-13 -13.9399 0.96034E-14 -14.0176 0.83627E+00 -0.0777 79 MnSO4,aq 0.23213E-14 -14.6343 0.23213E-14 -14.6343 0.10000E+01 0.0000 80 NaCl,aq 0.80273E-06 -6.0954 0.80273E-06 -6.0954 0.10000E+01 0.0000 81 NaF,aq 0.52258E-08 -8.2818 0.52258E-08 -8.2818 0.10000E+01 0.0000 82 NaOH,aq 0.90433E-04 -4.0437 0.90433E-04 -4.0437 0.10000E+01 0.0000 84 OH- 0.88018E-02 -2.0554 0.73331E-02 -2.1347 0.83314E+00 -0.0793 89 HPO3-2 0.61375E-16 -16.2120 0.31723E-16 -16.4986 0.51688E+00 -0.2866 92 H3PO4,aq 0.10205E-17 -17.9912 0.10205E-17 -17.9912 0.10000E+01 0.0000 93 H2PO4- 0.40889E-10 -10.3884 0.34161E-10 -10.4665 0.83545E+00 -0.0781 94 PO4-3 0.10085E-08 -8.9963 0.24338E-09 -9.6137 0.24133E+00 -0.6174 98 HP2O7-3 0.10086E-17 -17.9963 0.23190E-18 -18.6347 0.22992E+00 -0.6384 99 P2O7-4 0.92121E-17 -17.0356 0.70312E-18 -18.1530 0.76326E-01 -1.1173 100 H2S,aq 0.24202E-07 -7.6161 0.24117E-07 -7.6177 0.99648E+00 -0.0015 101 S2-2 0.97084E-12 -12.0129 0.50180E-12 -12.2995 0.51688E+00 -0.2866 102 S3-2 0.72830E-19 -19.1377 0.37644E-19 -19.4243 0.51688E+00 -0.2866 107 SO3-2 0.80826E-13 -13.0924 0.42386E-13 -13.3728 0.52441E+00 -0.2803 108 HSO3- 0.25052E-15 -15.6012 0.20910E-15 -15.6796 0.83466E+00 -0.0785 109 HSO4- 0.68311E-13 -13.1655 0.57182E-13 -13.2427 0.83709E+00 -0.0772 111 S2O3-2 0.41276E-15 -15.3843 0.21334E-15 -15.6709 0.51688E+00 -0.2866 Charge balance for all species = -.6132E-08 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.9382576E-10 -.2188865E-01 -.2202384E+02 0.0000 2 H2O 0.1000000E+01 0.5550436E+02 0.9981780E+06 0.0000 3 Cl- 0.1749935E-03 0.1757966E-03 0.6221611E+01 6.2681 4 SO4-- 0.1453869E-05 0.1336142E-05 0.1281274E+00 14.0839 5 HCO3- 0.1028984E-03 0.2874549E-03 0.1750900E+02 6.0381 6 HS- 0.1186402E-03 0.1187840E-03 0.3921551E+01 6.0993 7 Al+++ 0.1047685E-28 0.4494950E-05 0.1210683E+00 0.6920 8 H4SiO4 0.7361896E-03 0.1352923E-01 0.1298092E+04 -3.1330 9 Ca++ 0.8711981E-07 0.1999094E-06 0.7997948E-02 12.8583 10 Mg++ 0.2132467E-10 0.9317678E-10 0.2261350E-05 9.2450 11 Fe++ 0.3093767E-13 0.1684143E-07 0.9388974E-03 6.4071 12 K+ 0.1565397E-03 0.1572513E-03 0.6138079E+01 6.2204 13 Na+ 0.1987254E-01 0.2230389E-01 0.5118647E+03 8.3232 14 Mn++ 0.2082254E-10 0.2507412E-08 0.1375111E-03 9.2355 15 F- 0.1615949E-05 0.1621177E-05 0.3074522E-01 4.2326 16 HPO4-- 0.4536811E-07 0.4641753E-07 0.4447313E-02 12.5782 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.1966152E-01 -.1965848E-01 -.3041789E-05 0.0000000E+00 2 H2O 0.4984918E+02 0.4984919E+02 -.2956004E-05 0.0000000E+00 3 Cl- 0.1578852E-03 0.1578852E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.1202190E-05 0.1200007E-05 0.2183346E-08 0.0000000E+00 5 HCO3- 0.2581670E-03 0.2581670E-03 0.0000000E+00 0.0000000E+00 6 HS- 0.1066793E-03 0.1066815E-03 -.2183346E-08 0.0000000E+00 7 Al+++ 0.4775352E-05 0.4036973E-05 0.7383790E-06 0.0000000E+00 8 H4SiO4 0.1215302E-01 0.1215078E-01 0.2238995E-05 0.0000000E+00 9 Ca++ 0.2080835E-06 0.1795412E-06 0.2854229E-07 0.0000000E+00 10 Mg++ 0.8368328E-10 0.8368328E-10 0.0000000E+00 0.0000000E+00 11 Fe++ 0.3259227E-07 0.1512551E-07 0.1746676E-07 0.0000000E+00 12 K+ 0.1412294E-03 0.1412294E-03 0.0000000E+00 0.0000000E+00 13 Na+ 0.2003215E-01 0.2003141E-01 0.7368175E-06 0.0000000E+00 14 Mn++ 0.2251939E-08 0.2251939E-08 0.0000000E+00 0.0000000E+00 15 F- 0.1456000E-05 0.1456000E-05 0.0000000E+00 0.0000000E+00 16 HPO4-- 0.4168819E-07 0.4168819E-07 0.0000000E+00 0.0000000E+00 Chg. balance for solid moles: 0.1059E-21 Mass of aqueous solution: 0.899687E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 0.0033900 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 0.7368E-06 -6.133 0.1932E-03 -3.714 97.58 0.7417E-04 andradite 0.8733E-08 -8.059 0.4438E-05 -5.353 2.242 0.1153E-05 grossular 0.7807E-09 -9.108 0.3517E-06 -6.454 0.1776 0.9785E-07 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.9179E+00 0.9179E+00 1.0000 -0.037 grossular 0.8206E-01 0.8206E-01 1.0000 -1.086 Solid products produced: Mass = 0.000198 g Volume = 0.000075 cm3 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.0033900 moles log = -2.4698 Original solution: 1000.0103000 g Original solution / Rock added: 294988.29 (Water/Rock Ratio), log = 5.4698 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0209 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9994E+00 0.9859 0.1006E+01 0.1020E+01 CO2,gas 0.1507E-05 1.0071 0.1549E-05 0.1538E-05 CH4,gas 0.1565E-04 1.0125 0.1617E-04 0.1597E-04 H2,gas 0.5567E-03 1.0005 0.5686E-03 0.5683E-03 H2S,gas 0.6520E-06 0.9960 0.6630E-06 0.6656E-06 S2,gas 0.4998E-25 1.0000 0.5102E-25 0.5102E-25 CO,gas 0.2300E-12 1.0000 0.2348E-12 0.2348E-12 SO3,gas 0.1731E-41 1.0000 0.1768E-41 0.1768E-41 SO2,gas 0.3830E-22 1.0000 0.3910E-22 0.3910E-22 HF,gas 0.1746E-14 1.0000 0.1783E-14 0.1783E-14 HCl,gas 0.3645E-17 1.0000 0.3721E-17 0.3721E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 17 albite -0.38 -0.38 0.00 0.000 -0.94784E-12 23 andradite 39.01 39.01 0.00 0.000 0.12132E-10 24 grossular 32.73 32.73 0.00 0.000 0.36397E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -14.17 -7.51 -2.503 0.12821E+05 -5.810 3 CH4,gas 4.54 -1.95 -6.49 -1.623 0.11082E+05 -4.791 4 H2,gas 8.00 3.06 -4.94 -2.825 0.84420E+04 -3.245 5 H2S,gas -6.23 -14.11 -7.88 -3.939 0.13451E+05 -6.179 6 S2,gas -7.34 -34.33 -26.99 -4.152 0.46087E+05 -25.292 7 CO,gas 3.21 -11.11 -14.33 -4.409 0.24465E+05 -12.629 8 SO3,gas 17.12 -26.33 -43.45 -10.863 0.74192E+05 -41.753 9 SO2,gas 0.83 -23.27 -24.11 -6.428 0.41162E+05 -22.408 10 HF,gas 0.47 -15.97 -16.45 -8.224 0.28084E+05 -14.749 11 HCl,gas 5.19 -13.94 -19.13 -9.564 0.32661E+05 -17.429 12 acmite 7.71 6.94 -0.77 -0.080 0.13203E+04 16 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 20 spessartine 24.46 19.69 -4.77 -0.238 0.81376E+04 21 analcite 3.32 2.75 -0.57 -0.064 0.97790E+03 27 annite 20.12 16.73 -3.39 -0.188 0.57862E+04 28 phlogopite 27.06 25.25 -1.82 -0.101 0.31011E+04 30 anorthite 12.71 7.98 -4.73 -0.364 0.80835E+04 33 apatite-OH -18.15 -19.22 -1.06 -0.082 0.18150E+04 34 apatite-F -34.30 -35.19 -0.89 -0.074 0.15196E+04 38 aragonite 0.97 -1.31 -2.28 -0.759 0.38883E+04 39 brucite 12.57 9.25 -3.32 -0.665 0.56748E+04 40 calcite 0.81 -1.31 -2.12 -0.707 0.36241E+04 41 carnegieite-low 9.02 5.88 -3.14 -0.449 0.53634E+04 42 carnegieite-high 10.09 5.88 -4.21 -0.602 0.71904E+04 43 carpholite-Mg 8.58 4.36 -4.22 -0.281 0.72041E+04 45 celadonite 5.34 3.63 -1.72 -0.101 0.29305E+04 46 celadonite-Fe 3.88 0.79 -3.09 -0.182 0.52745E+04 47 chrysotile 23.89 21.47 -2.42 -0.202 0.41378E+04 49 clinochlore 39.07 38.21 -0.86 -0.027 0.14676E+04 50 daphnite 28.97 24.02 -4.94 -0.155 0.84431E+04 52 chlorite-Al-free 47.17 42.94 -4.23 -0.176 0.72307E+04 54 chloritoid-Fe 9.17 4.66 -4.52 -0.301 0.77103E+04 55 chloritoid-Mn 11.40 7.49 -3.91 -0.261 0.66842E+04 57 coesite -2.38 -3.13 -0.76 -0.252 0.12925E+04 64 cristobalite -2.56 -3.13 -0.57 -0.191 0.97782E+03 66 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71237E+04 68 diaspore 2.87 0.69 -2.18 -0.364 0.37253E+04 69 diamond -3.10 -8.06 -4.96 -1.416 0.84611E+04 70 diopside 16.18 15.84 -0.34 -0.034 0.58751E+03 71 hedenbergite 14.21 13.00 -1.21 -0.121 0.20642E+04 76 clinoenstatite 17.17 12.22 -4.94 -0.494 0.84387E+04 78 epidote 24.67 22.58 -2.09 -0.101 0.35673E+04 79 clinozoisite 22.81 18.39 -4.41 -0.201 0.75345E+04 80 epidote-Fe 29.84 26.77 -3.07 -0.160 0.52466E+04 81 fayalite 14.05 9.68 -4.36 -0.624 0.74523E+04 82 ferrosilite 11.15 6.55 -4.60 -0.460 0.78565E+04 86 gibbsite 4.08 0.69 -3.39 -0.484 0.57838E+04 87 glaucophane 22.97 20.70 -2.27 -0.061 0.38819E+04 89 graphite -3.55 -8.06 -4.51 -1.289 0.77034E+04 90 greenalite 16.14 12.96 -3.18 -0.265 0.54369E+04 93 hematite 12.57 9.76 -2.81 -0.340 0.47939E+04 94 heulandite -5.83 -7.69 -1.86 -0.085 0.31787E+04 98 jadeite 4.22 2.75 -1.47 -0.147 0.25034E+04 100 kalsilite 7.58 3.78 -3.80 -0.544 0.64962E+04 101 kaolinite -1.33 -4.88 -3.55 -0.323 0.60604E+04 104 laumontite 2.88 1.71 -1.17 -0.078 0.20033E+04 105 lawsonite 9.62 7.98 -1.64 -0.109 0.28001E+04 106 leucite 4.12 0.65 -3.47 -0.347 0.59292E+04 108 lizardite 23.24 21.47 -1.77 -0.148 0.30304E+04 110 magnetite 20.09 16.17 -3.92 -0.320 0.66962E+04 111 minnesotaite 10.39 6.69 -3.70 -0.218 0.63156E+04 115 manganosite 14.06 9.24 -4.82 -1.206 0.82344E+04 119 microcline -2.49 -2.49 0.00 0.000 0.30444E+00 123 muscovite 2.58 -1.10 -3.69 -0.217 0.62924E+04 124 paragonite 4.24 1.00 -3.24 -0.191 0.55312E+04 125 nepheline 8.34 5.88 -2.46 -0.351 0.41958E+04 137 phlogopite-Na 29.65 27.35 -2.30 -0.128 0.39196E+04 139 prehnite 19.37 17.70 -1.67 -0.098 0.28523E+04 140 prehnite-Fe 22.50 21.89 -0.61 -0.037 0.10400E+04 141 pumpellyite-Fe 46.27 42.50 -3.77 -0.084 0.64330E+04 142 pumpellyite-Mg 48.99 45.34 -3.66 -0.081 0.62409E+04 145 pyrite -21.25 -24.86 -3.62 -0.851 0.61760E+04 146 pyrrhotite -4.26 -7.70 -3.44 -1.147 0.58742E+04 147 pyrrhotiteFe0.875 -6.02 -8.88 -2.86 -1.053 0.48893E+04 148 pyroxmangite 7.40 6.10 -1.30 -0.259 0.22132E+04 149 pyrophyllite -6.18 -11.15 -4.97 -0.311 0.84901E+04 150 quartz -2.99 -3.13 -0.14 -0.048 0.24515E+03 154 rhodochrosite -0.98 -4.93 -3.96 -1.319 0.67567E+04 155 rhodonite 7.45 6.10 -1.34 -0.269 0.22934E+04 156 sanidine -1.28 -2.49 -1.21 -0.093 0.20681E+04 166 stilbite -7.52 -7.69 -0.17 -0.008 0.28489E+03 167 stilpnomelane-Fe 13.02 11.47 -1.55 -0.046 0.26489E+04 168 stilpnomelane-Mg 27.44 25.66 -1.79 -0.053 0.30500E+04 174 talc 16.49 15.20 -1.29 -0.076 0.21993E+04 177 tephroite 18.09 15.34 -2.75 -0.393 0.46917E+04 181 tridymite -2.63 -3.13 -0.51 -0.169 0.86513E+03 182 tremolite 47.87 46.88 -0.99 -0.027 0.16932E+04 184 troilite-low -4.41 -7.70 -3.29 -1.097 0.56170E+04 190 wairakite 3.95 1.71 -2.24 -0.132 0.38253E+04 191 walstromite 11.51 9.73 -1.78 -0.357 0.30461E+04 192 wollastonite 10.46 9.73 -0.74 -0.147 0.12565E+04 193 pseudo-wollastonite 11.00 9.73 -1.27 -0.255 0.21763E+04 194 zoisite 22.85 18.39 -4.46 -0.203 0.76086E+04 195 akaganeite 7.75 4.88 -2.88 -0.622 0.49095E+04 202 chalcedony -2.80 -3.13 -0.33 -0.110 0.56445E+03 204 montmorillonite-Ca -2.29 -6.20 -3.91 -0.242 0.66818E+04 205 montmorillonite-K -2.24 -6.27 -4.04 -0.247 0.68917E+04 206 montmorillonite-Mg -2.48 -6.80 -4.32 -0.267 0.73768E+04 207 montmorillonite-Na -2.04 -5.58 -3.54 -0.217 0.60464E+04 208 nontronite-Ca 3.21 0.61 -2.60 -0.169 0.44465E+04 209 nontronite-H 2.53 -1.51 -4.04 -0.271 0.69048E+04 210 nontronite-K 3.34 0.54 -2.80 -0.180 0.47795E+04 211 nontronite-Mg 3.07 0.01 -3.06 -0.199 0.52255E+04 212 nontronite-Na 3.52 1.24 -2.28 -0.147 0.39003E+04 228 tobermorite 9.82 7.58 -2.25 -0.613 0.38335E+04 234 alabandite -0.98 -4.87 -3.89 -1.298 0.66495E+04 237 boehmite 4.41 0.69 -3.71 -0.619 0.63422E+04 239 ferrous-oxide 9.81 6.41 -3.40 -0.851 0.58130E+04 245 silica-amorphous -2.09 -3.13 -1.04 -0.347 0.17786E+04 247 an20ab80 2.02 1.29 -0.73 -0.056 0.12458E+04 248 an25ab75 2.65 1.71 -0.94 -0.072 0.16043E+04 249 an30ab70 3.28 2.12 -1.16 -0.089 0.19723E+04 250 tr.625ac.25prg.125 45.16 44.26 -0.91 -0.024 0.15487E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 0.0001000 MOLES Current total amount of reactant added: 0.0033900 MOLES New total amount of reactant added: 0.0034900 MOLES Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.5508E-08 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 7 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 0.0034900 Water: Moles liquid = 0.4985E+02 kg liquid = 0.8981E+00 Moles total = 0.4985E+02 kg total = 0.8981E+00 Activity = 1.0000 Stoichiometric ionic strength = .1155303E-01 Osmotic coef. = 0.9600 True ionic strength = .2022133E-01 Chg. balance for total moles = -.5508E-08 Max. difference allowed = 0.1585E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.93996E-10 -10.0269 0.78931E-10 -10.1028 0.83973E+00 -0.0759 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.17565E-03 -3.7554 0.14660E-03 -3.8339 0.83464E+00 -0.0785 4 SO4-- 0.19747E-05 -5.7045 0.10228E-05 -5.9902 0.51794E+00 -0.2857 5 HCO3- 0.10590E-03 -3.9751 0.88518E-04 -4.0530 0.83587E+00 -0.0779 6 HS- 0.12082E-03 -3.9178 0.10086E-03 -3.9963 0.83476E+00 -0.0784 7 Al+++ 0.10501E-28 -28.9788 0.24115E-29 -29.6177 0.22964E+00 -0.6389 8 H4SiO4 0.73742E-03 -3.1323 0.73742E-03 -3.1323 0.10000E+01 0.0000 9 Ca++ 0.86341E-07 -7.0638 0.44389E-07 -7.3527 0.51411E+00 -0.2889 10 Mg++ 0.21332E-10 -10.6710 0.10916E-10 -10.9619 0.51174E+00 -0.2909 11 Fe++ 0.30497E-13 -13.5157 0.15624E-13 -13.8062 0.51231E+00 -0.2905 12 K+ 0.15654E-03 -3.8054 0.13088E-03 -3.8831 0.83607E+00 -0.0778 13 Na+ 0.19873E-01 -1.7017 0.16584E-01 -1.7803 0.83449E+00 -0.0786 14 Mn++ 0.20894E-10 -10.6800 0.10713E-10 -10.9701 0.51273E+00 -0.2901 15 F- 0.16603E-05 -5.7798 0.13829E-05 -5.8592 0.83291E+00 -0.0794 16 HPO4-- 0.45370E-07 -7.3432 0.23502E-07 -7.6289 0.51802E+00 -0.2857 18 HSiO3- 0.10452E-01 -1.9808 0.87236E-02 -2.0593 0.83464E+00 -0.0785 19 Ca(HSiO3)+ 0.10545E-07 -7.9769 0.88186E-08 -8.0546 0.83625E+00 -0.0777 20 Mg(HSiO3)+ 0.32275E-11 -11.4911 0.26990E-11 -11.5688 0.83625E+00 -0.0777 21 NaHSiO3,aq 0.23398E-02 -2.6308 0.23398E-02 -2.6308 0.10000E+01 0.0000 22 AlO+ 0.62971E-16 -16.2009 0.52659E-16 -16.2785 0.83625E+00 -0.0777 24 HAlO2,aq 0.13286E-09 -9.8766 0.13286E-09 -9.8766 0.10000E+01 0.0000 25 AlO2- 0.44724E-05 -5.3495 0.37261E-05 -5.4287 0.83312E+00 -0.0793 26 CH4,aq 0.85090E-08 -8.0701 0.84790E-08 -8.0717 0.99648E+00 -0.0015 27 C2H6,aq 0.30616E-19 -19.5140 0.30509E-19 -19.5156 0.99648E+00 -0.0015 31 CO,aq 0.15109E-15 -15.8208 0.15109E-15 -15.8208 0.10000E+01 0.0000 32 CO2,aq 0.14982E-07 -7.8244 0.14929E-07 -7.8260 0.99648E+00 -0.0015 33 CO3-2 0.18953E-03 -3.7223 0.97955E-04 -4.0090 0.51684E+00 -0.2866 34 CaCO3,aq 0.54520E-07 -7.2634 0.54520E-07 -7.2634 0.10000E+01 0.0000 35 Ca(HCO3)+ 0.11994E-09 -9.9211 0.10030E-09 -9.9987 0.83625E+00 -0.0777 36 CaCl+ 0.12593E-10 -10.8999 0.10531E-10 -10.9775 0.83625E+00 -0.0777 37 CaCl2,aq 0.36680E-15 -15.4356 0.36680E-15 -15.4356 0.10000E+01 0.0000 38 CaF+ 0.10717E-11 -11.9699 0.89624E-12 -12.0476 0.83625E+00 -0.0777 39 CaOH+ 0.47928E-07 -7.3194 0.40080E-07 -7.3971 0.83625E+00 -0.0777 40 CaSO4,aq 0.14417E-10 -10.8411 0.14417E-10 -10.8411 0.10000E+01 0.0000 41 HCl,aq 0.21204E-14 -14.6736 0.21204E-14 -14.6736 0.10000E+01 0.0000 45 HF,aq 0.74724E-12 -12.1265 0.74724E-12 -12.1265 0.10000E+01 0.0000 46 HF2- 0.41801E-18 -18.3788 0.34889E-18 -18.4573 0.83464E+00 -0.0785 48 FeCl+ 0.43354E-17 -17.3630 0.36255E-17 -17.4406 0.83625E+00 -0.0777 51 FeF+ 0.13203E-17 -17.8793 0.11041E-17 -17.9570 0.83625E+00 -0.0777 53 FeO,aq 0.97467E-10 -10.0111 0.97467E-10 -10.0111 0.10000E+01 0.0000 54 FeOH+ 0.77049E-11 -11.1132 0.64432E-11 -11.1909 0.83625E+00 -0.0777 55 HFeO2- 0.15480E-07 -7.8102 0.12920E-07 -7.8887 0.83464E+00 -0.0785 56 FeO+ 0.28954E-16 -16.5383 0.24213E-16 -16.6159 0.83625E+00 -0.0777 58 FeO2- 0.95281E-09 -9.0210 0.79525E-09 -9.0995 0.83464E+00 -0.0785 59 HFeO2,aq 0.79834E-11 -11.0978 0.79834E-11 -11.0978 0.10000E+01 0.0000 60 H2,aq 0.40428E-06 -6.3933 0.40286E-06 -6.3948 0.99648E+00 -0.0015 61 KCl,aq 0.34775E-09 -9.4587 0.34775E-09 -9.4587 0.10000E+01 0.0000 62 KHSO4,aq 0.29874E-19 -19.5247 0.29874E-19 -19.5247 0.10000E+01 0.0000 63 KOH,aq 0.70812E-06 -6.1499 0.70812E-06 -6.1499 0.10000E+01 0.0000 64 KSO4- 0.24888E-08 -8.6040 0.20772E-08 -8.6825 0.83464E+00 -0.0785 65 MgCO3,aq 0.33608E-11 -11.4736 0.33608E-11 -11.4736 0.10000E+01 0.0000 66 Mg(HCO3)+ 0.30139E-13 -13.5209 0.25204E-13 -13.5985 0.83625E+00 -0.0777 67 MgCl+ 0.28070E-14 -14.5518 0.23473E-14 -14.6294 0.83625E+00 -0.0777 68 MgF+ 0.97633E-15 -15.0104 0.81646E-15 -15.0881 0.83625E+00 -0.0777 69 MgOH+ 0.65222E-10 -10.1856 0.54542E-10 -10.2633 0.83625E+00 -0.0777 71 MnF+ 0.29841E-15 -15.5252 0.24955E-15 -15.6029 0.83625E+00 -0.0777 72 MnO,aq 0.17808E-08 -8.7494 0.17808E-08 -8.7494 0.10000E+01 0.0000 73 MnOH+ 0.49080E-09 -9.3091 0.41043E-09 -9.3868 0.83625E+00 -0.0777 74 MnO2-2 0.18354E-10 -10.7363 0.94862E-11 -11.0229 0.51684E+00 -0.2866 75 HMnO2- 0.19654E-09 -9.7065 0.16404E-09 -9.7850 0.83464E+00 -0.0785 78 MnCl+ 0.11565E-13 -13.9368 0.96716E-14 -14.0145 0.83625E+00 -0.0777 79 MnSO4,aq 0.31633E-14 -14.4999 0.31633E-14 -14.4999 0.10000E+01 0.0000 80 NaCl,aq 0.80571E-06 -6.0938 0.80571E-06 -6.0938 0.10000E+01 0.0000 81 NaF,aq 0.53692E-08 -8.2701 0.53692E-08 -8.2701 0.10000E+01 0.0000 82 NaOH,aq 0.90271E-04 -4.0445 0.90271E-04 -4.0445 0.10000E+01 0.0000 84 OH- 0.87862E-02 -2.0562 0.73200E-02 -2.1355 0.83312E+00 -0.0793 89 HPO3-2 0.57089E-16 -16.2434 0.29506E-16 -16.5301 0.51684E+00 -0.2866 92 H3PO4,aq 0.10241E-17 -17.9897 0.10241E-17 -17.9897 0.10000E+01 0.0000 93 H2PO4- 0.40962E-10 -10.3876 0.34221E-10 -10.4657 0.83544E+00 -0.0781 94 PO4-3 0.10068E-08 -8.9970 0.24294E-09 -9.6145 0.24129E+00 -0.6175 98 HP2O7-3 0.10105E-17 -17.9955 0.23229E-18 -18.6340 0.22988E+00 -0.6385 99 P2O7-4 0.92141E-17 -17.0355 0.70306E-18 -18.1530 0.76303E-01 -1.1175 100 H2S,aq 0.24691E-07 -7.6075 0.24604E-07 -7.6090 0.99648E+00 -0.0015 101 S2-2 0.10826E-11 -11.9655 0.55951E-12 -12.2522 0.51684E+00 -0.2866 102 S3-2 0.89077E-19 -19.0502 0.46038E-19 -19.3369 0.51684E+00 -0.2866 107 SO3-2 0.10211E-12 -12.9909 0.53545E-13 -13.2713 0.52437E+00 -0.2804 108 HSO3- 0.31705E-15 -15.4989 0.26462E-15 -15.5774 0.83464E+00 -0.0785 109 HSO4- 0.92945E-13 -13.0318 0.77802E-13 -13.1090 0.83707E+00 -0.0772 111 S2O3-2 0.57196E-15 -15.2426 0.29561E-15 -15.5293 0.51684E+00 -0.2866 Charge balance for all species = -.6132E-08 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.9399576E-10 -.2187653E-01 -.2201163E+02 0.0000 2 H2O 0.1000000E+01 0.5550435E+02 0.9981773E+06 0.0000 3 Cl- 0.1756471E-03 0.1764532E-03 0.6244846E+01 6.2689 4 SO4-- 0.1974728E-05 0.1867772E-05 0.1791071E+00 14.2153 5 HCO3- 0.1058988E-03 0.2955046E-03 0.1799930E+02 6.0498 6 HS- 0.1208237E-03 0.1209578E-03 0.3993316E+01 6.1065 7 Al+++ 0.1050126E-28 0.4472544E-05 0.1204647E+00 0.6905 8 H4SiO4 0.7374220E-03 0.1352914E-01 0.1298083E+04 -3.1323 9 Ca++ 0.8634054E-07 0.1994823E-06 0.7980860E-02 12.8528 10 Mg++ 0.2133186E-10 0.9317661E-10 0.2261345E-05 9.2436 11 Fe++ 0.3049703E-13 0.1654594E-07 0.9224237E-03 6.3993 12 K+ 0.1565400E-03 0.1572510E-03 0.6138065E+01 6.2196 13 Na+ 0.1987292E-01 0.2230382E-01 0.5118630E+03 8.3224 14 Mn++ 0.2089431E-10 0.2507407E-08 0.1375108E-03 9.2354 15 F- 0.1660340E-05 0.1665711E-05 0.3158980E-01 4.2435 16 HPO4-- 0.4536964E-07 0.4641744E-07 0.4447303E-02 12.5766 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.1965075E-01 -.1964763E-01 -.3123526E-05 0.0000000E+00 2 H2O 0.4984927E+02 0.4984927E+02 -.3036639E-05 0.0000000E+00 3 Cl- 0.1584752E-03 0.1584752E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.1679690E-05 0.1677473E-05 0.2216515E-08 0.0000000E+00 5 HCO3- 0.2653970E-03 0.2653970E-03 0.0000000E+00 0.0000000E+00 6 HS- 0.1086318E-03 0.1086340E-03 -.2216515E-08 0.0000000E+00 7 Al+++ 0.4775352E-05 0.4016857E-05 0.7584947E-06 0.0000000E+00 8 H4SiO4 0.1215302E-01 0.1215072E-01 0.2299755E-05 0.0000000E+00 9 Ca++ 0.2080835E-06 0.1791580E-06 0.2892550E-07 0.0000000E+00 10 Mg++ 0.8368328E-10 0.8368328E-10 0.0000000E+00 0.0000000E+00 11 Fe++ 0.3259227E-07 0.1486015E-07 0.1773212E-07 0.0000000E+00 12 K+ 0.1412294E-03 0.1412294E-03 0.0000000E+00 0.0000000E+00 13 Na+ 0.2003215E-01 0.2003139E-01 0.7569432E-06 0.0000000E+00 14 Mn++ 0.2251939E-08 0.2251939E-08 0.0000000E+00 0.0000000E+00 15 F- 0.1496000E-05 0.1496000E-05 0.0000000E+00 0.0000000E+00 16 HPO4-- 0.4168819E-07 0.4168819E-07 0.0000000E+00 0.0000000E+00 Chg. balance for solid moles: 0.3176E-21 Mass of aqueous solution: 0.899689E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 0.0034900 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 0.7569E-06 -6.121 0.1985E-03 -3.702 97.61 0.7619E-04 andradite 0.8866E-08 -8.052 0.4506E-05 -5.346 2.216 0.1171E-05 grossular 0.7758E-09 -9.110 0.3494E-06 -6.457 0.1719 0.9723E-07 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.9195E+00 0.9195E+00 1.0000 -0.036 grossular 0.8046E-01 0.8046E-01 1.0000 -1.094 Solid products produced: Mass = 0.000203 g Volume = 0.000077 cm3 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.0034900 moles log = -2.4572 Original solution: 1000.0103000 g Original solution / Rock added: 286535.90 (Water/Rock Ratio), log = 5.4572 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0208 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9995E+00 0.9859 0.1006E+01 0.1020E+01 CO2,gas 0.1554E-05 1.0071 0.1597E-05 0.1586E-05 CH4,gas 0.1207E-04 1.0125 0.1248E-04 0.1233E-04 H2,gas 0.5178E-03 1.0005 0.5289E-03 0.5286E-03 H2S,gas 0.6652E-06 0.9960 0.6764E-06 0.6790E-06 S2,gas 0.6013E-25 1.0000 0.6138E-25 0.6138E-25 CO,gas 0.2205E-12 1.0000 0.2251E-12 0.2251E-12 SO3,gas 0.2360E-41 1.0000 0.2409E-41 0.2409E-41 SO2,gas 0.4856E-22 1.0000 0.4958E-22 0.4958E-22 HF,gas 0.1797E-14 1.0000 0.1835E-14 0.1835E-14 HCl,gas 0.3665E-17 1.0000 0.3742E-17 0.3742E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 17 albite -0.38 -0.38 0.00 0.000 -0.13080E-10 23 andradite 39.01 39.01 0.00 0.000 0.00000E+00 24 grossular 32.73 32.73 0.00 0.000 -0.12132E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -14.16 -7.50 -2.499 0.12799E+05 -5.797 3 CH4,gas 4.54 -2.06 -6.60 -1.651 0.11274E+05 -4.904 4 H2,gas 8.00 3.02 -4.98 -2.843 0.84957E+04 -3.277 5 H2S,gas -6.23 -14.10 -7.87 -3.934 0.13436E+05 -6.170 6 S2,gas -7.34 -34.25 -26.91 -4.140 0.45950E+05 -25.212 7 CO,gas 3.21 -11.13 -14.35 -4.414 0.24496E+05 -12.648 8 SO3,gas 17.12 -26.20 -43.32 -10.829 0.73963E+05 -41.618 9 SO2,gas 0.83 -23.17 -24.00 -6.401 0.40986E+05 -22.305 10 HF,gas 0.47 -15.96 -16.44 -8.218 0.28063E+05 -14.736 11 HCl,gas 5.19 -13.94 -19.13 -9.563 0.32657E+05 -17.427 12 acmite 7.71 6.95 -0.76 -0.079 0.13056E+04 16 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 20 spessartine 24.46 19.69 -4.77 -0.238 0.81392E+04 21 analcite 3.32 2.75 -0.57 -0.064 0.97914E+03 27 annite 20.12 16.71 -3.41 -0.190 0.58262E+04 28 phlogopite 27.06 25.24 -1.82 -0.101 0.31085E+04 30 anorthite 12.71 7.97 -4.74 -0.365 0.80951E+04 33 apatite-OH -18.15 -19.24 -1.09 -0.084 0.18540E+04 34 apatite-F -34.30 -35.20 -0.90 -0.075 0.15372E+04 38 aragonite 0.97 -1.30 -2.27 -0.756 0.38750E+04 39 brucite 12.57 9.24 -3.32 -0.665 0.56773E+04 40 calcite 0.81 -1.30 -2.11 -0.705 0.36108E+04 41 carnegieite-low 9.02 5.88 -3.14 -0.449 0.53659E+04 42 carnegieite-high 10.09 5.88 -4.21 -0.602 0.71929E+04 43 carpholite-Mg 8.58 4.36 -4.22 -0.281 0.72089E+04 45 celadonite 5.34 3.62 -1.72 -0.101 0.29317E+04 46 celadonite-Fe 3.88 0.78 -3.10 -0.182 0.52867E+04 47 chrysotile 23.89 21.47 -2.43 -0.202 0.41427E+04 49 clinochlore 39.07 38.20 -0.87 -0.027 0.14810E+04 50 daphnite 28.97 23.98 -4.98 -0.156 0.85110E+04 52 chlorite-Al-free 47.17 42.93 -4.24 -0.177 0.72405E+04 54 chloritoid-Fe 9.17 4.65 -4.53 -0.302 0.77272E+04 55 chloritoid-Mn 11.40 7.48 -3.92 -0.261 0.66879E+04 57 coesite -2.38 -3.13 -0.76 -0.252 0.12912E+04 64 cristobalite -2.56 -3.13 -0.57 -0.191 0.97658E+03 66 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71237E+04 68 diaspore 2.87 0.69 -2.18 -0.364 0.37277E+04 70 diopside 16.18 15.83 -0.35 -0.035 0.59687E+03 71 hedenbergite 14.21 12.99 -1.22 -0.122 0.20844E+04 76 clinoenstatite 17.17 12.22 -4.94 -0.494 0.84412E+04 78 epidote 24.67 22.58 -2.09 -0.101 0.35736E+04 79 clinozoisite 22.81 18.38 -4.43 -0.201 0.75567E+04 80 epidote-Fe 29.84 26.77 -3.07 -0.159 0.52371E+04 81 fayalite 14.05 9.67 -4.38 -0.626 0.74778E+04 82 ferrosilite 11.15 6.53 -4.62 -0.462 0.78807E+04 86 gibbsite 4.08 0.69 -3.39 -0.484 0.57862E+04 87 glaucophane 22.97 20.70 -2.28 -0.062 0.38868E+04 89 graphite -3.55 -8.11 -4.56 -1.303 0.77881E+04 90 greenalite 16.14 12.93 -3.21 -0.267 0.54745E+04 93 hematite 12.57 9.77 -2.79 -0.338 0.47669E+04 94 heulandite -5.83 -7.69 -1.86 -0.085 0.31842E+04 98 jadeite 4.22 2.75 -1.47 -0.147 0.25046E+04 100 kalsilite 7.58 3.78 -3.81 -0.544 0.64987E+04 101 kaolinite -1.33 -4.88 -3.55 -0.323 0.60627E+04 104 laumontite 2.88 1.70 -1.18 -0.079 0.20125E+04 105 lawsonite 9.62 7.97 -1.65 -0.110 0.28118E+04 106 leucite 4.12 0.65 -3.47 -0.347 0.59305E+04 108 lizardite 23.24 21.47 -1.78 -0.148 0.30353E+04 110 magnetite 20.09 16.17 -3.91 -0.319 0.66825E+04 111 minnesotaite 10.39 6.67 -3.72 -0.219 0.63507E+04 115 manganosite 14.06 9.24 -4.82 -1.206 0.82346E+04 119 microcline -2.49 -2.49 0.00 0.000 0.31656E+00 123 muscovite 2.58 -1.11 -3.69 -0.217 0.62972E+04 124 paragonite 4.24 1.00 -3.24 -0.191 0.55360E+04 125 nepheline 8.34 5.88 -2.46 -0.351 0.41983E+04 137 phlogopite-Na 29.65 27.35 -2.30 -0.128 0.39270E+04 139 prehnite 19.37 17.69 -1.68 -0.099 0.28721E+04 140 prehnite-Fe 22.50 21.89 -0.61 -0.037 0.10440E+04 141 pumpellyite-Fe 46.27 42.47 -3.80 -0.084 0.64884E+04 142 pumpellyite-Mg 48.99 45.31 -3.68 -0.082 0.62854E+04 145 pyrite -21.25 -24.82 -3.58 -0.841 0.61060E+04 146 pyrrhotite -4.26 -7.70 -3.44 -1.146 0.58727E+04 147 pyrrhotiteFe0.875 -6.02 -8.87 -2.86 -1.051 0.48795E+04 148 pyroxmangite 7.40 6.10 -1.30 -0.259 0.22121E+04 149 pyrophyllite -6.18 -11.15 -4.97 -0.311 0.84900E+04 150 quartz -2.99 -3.13 -0.14 -0.048 0.24391E+03 154 rhodochrosite -0.98 -4.92 -3.94 -1.315 0.67342E+04 155 rhodonite 7.45 6.10 -1.34 -0.269 0.22923E+04 156 sanidine -1.28 -2.49 -1.21 -0.093 0.20681E+04 166 stilbite -7.52 -7.69 -0.17 -0.008 0.29037E+03 167 stilpnomelane-Fe 13.02 11.43 -1.59 -0.047 0.27112E+04 168 stilpnomelane-Mg 27.44 25.65 -1.79 -0.053 0.30578E+04 174 talc 16.49 15.20 -1.29 -0.076 0.22017E+04 177 tephroite 18.09 15.34 -2.75 -0.392 0.46908E+04 181 tridymite -2.63 -3.13 -0.51 -0.169 0.86389E+03 182 tremolite 47.87 46.87 -1.00 -0.027 0.17144E+04 184 troilite-low -4.41 -7.70 -3.29 -1.096 0.56155E+04 190 wairakite 3.95 1.70 -2.25 -0.132 0.38345E+04 191 walstromite 11.51 9.72 -1.79 -0.358 0.30542E+04 192 wollastonite 10.46 9.72 -0.74 -0.148 0.12646E+04 193 pseudo-wollastonite 11.00 9.72 -1.28 -0.256 0.21845E+04 194 zoisite 22.85 18.38 -4.47 -0.203 0.76308E+04 195 akaganeite 7.75 4.89 -2.87 -0.620 0.48960E+04 202 chalcedony -2.80 -3.13 -0.33 -0.110 0.56321E+03 204 montmorillonite-Ca -2.29 -6.20 -3.91 -0.242 0.66832E+04 205 montmorillonite-K -2.24 -6.27 -4.04 -0.247 0.68919E+04 206 montmorillonite-Mg -2.48 -6.80 -4.32 -0.267 0.73771E+04 207 montmorillonite-Na -2.04 -5.58 -3.54 -0.217 0.60467E+04 208 nontronite-Ca 3.21 0.63 -2.59 -0.168 0.44173E+04 209 nontronite-H 2.53 -1.49 -4.03 -0.270 0.68741E+04 210 nontronite-K 3.34 0.56 -2.78 -0.179 0.47492E+04 211 nontronite-Mg 3.07 0.03 -3.04 -0.197 0.51952E+04 212 nontronite-Na 3.52 1.25 -2.27 -0.145 0.38700E+04 228 tobermorite 9.82 7.57 -2.25 -0.614 0.38401E+04 234 alabandite -0.98 -4.86 -3.89 -1.295 0.66348E+04 237 boehmite 4.41 0.69 -3.72 -0.619 0.63446E+04 239 ferrous-oxide 9.81 6.40 -3.41 -0.853 0.58264E+04 245 silica-amorphous -2.09 -3.13 -1.04 -0.347 0.17774E+04 247 an20ab80 2.02 1.29 -0.73 -0.056 0.12482E+04 248 an25ab75 2.65 1.70 -0.94 -0.072 0.16072E+04 249 an30ab70 3.28 2.12 -1.16 -0.089 0.19758E+04 250 tr.625ac.25prg.125 45.16 44.24 -0.93 -0.025 0.15846E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 0.0001000 MOLES Current total amount of reactant added: 0.0034900 MOLES New total amount of reactant added: 0.0035900 MOLES Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.5508E-08 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 7 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 0.0035900 Water: Moles liquid = 0.4985E+02 kg liquid = 0.8981E+00 Moles total = 0.4985E+02 kg total = 0.8981E+00 Activity = 1.0000 Stoichiometric ionic strength = .1155943E-01 Osmotic coef. = 0.9596 True ionic strength = .2022727E-01 Chg. balance for total moles = -.5508E-08 Max. difference allowed = 0.1591E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.94166E-10 -10.0261 0.79073E-10 -10.1020 0.83972E+00 -0.0759 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.17630E-03 -3.7537 0.14715E-03 -3.8323 0.83463E+00 -0.0785 4 SO4-- 0.24988E-05 -5.6023 0.12942E-05 -5.8880 0.51790E+00 -0.2858 5 HCO3- 0.10891E-03 -3.9630 0.91029E-04 -4.0408 0.83586E+00 -0.0779 6 HS- 0.12300E-03 -3.9101 0.10268E-03 -3.9885 0.83475E+00 -0.0784 7 Al+++ 0.10526E-28 -28.9777 0.24167E-29 -29.6168 0.22960E+00 -0.6390 8 H4SiO4 0.73866E-03 -3.1316 0.73866E-03 -3.1316 0.10000E+01 0.0000 9 Ca++ 0.85652E-07 -7.0673 0.44031E-07 -7.3562 0.51407E+00 -0.2890 10 Mg++ 0.21339E-10 -10.6708 0.10919E-10 -10.9618 0.51170E+00 -0.2910 11 Fe++ 0.30280E-13 -13.5189 0.15511E-13 -13.8094 0.51227E+00 -0.2905 12 K+ 0.15654E-03 -3.8054 0.13088E-03 -3.8831 0.83606E+00 -0.0778 13 Na+ 0.19873E-01 -1.7017 0.16584E-01 -1.7803 0.83447E+00 -0.0786 14 Mn++ 0.20966E-10 -10.6785 0.10749E-10 -10.9686 0.51269E+00 -0.2901 15 F- 0.17047E-05 -5.7683 0.14199E-05 -5.8478 0.83289E+00 -0.0794 16 HPO4-- 0.45371E-07 -7.3432 0.23501E-07 -7.6289 0.51798E+00 -0.2857 18 HSiO3- 0.10451E-01 -1.9808 0.87225E-02 -2.0594 0.83463E+00 -0.0785 19 Ca(HSiO3)+ 0.10459E-07 -7.9805 0.87466E-08 -8.0582 0.83624E+00 -0.0777 20 Mg(HSiO3)+ 0.32280E-11 -11.4911 0.26994E-11 -11.5687 0.83624E+00 -0.0777 21 NaHSiO3,aq 0.23395E-02 -2.6309 0.23395E-02 -2.6309 0.10000E+01 0.0000 22 AlO+ 0.62881E-16 -16.2015 0.52584E-16 -16.2791 0.83624E+00 -0.0777 24 HAlO2,aq 0.13243E-09 -9.8780 0.13243E-09 -9.8780 0.10000E+01 0.0000 25 AlO2- 0.44501E-05 -5.3516 0.37074E-05 -5.4309 0.83311E+00 -0.0793 26 CH4,aq 0.70403E-08 -8.1524 0.70154E-08 -8.1539 0.99648E+00 -0.0015 27 C2H6,aq 0.22140E-19 -19.6548 0.22062E-19 -19.6564 0.99648E+00 -0.0015 31 CO,aq 0.14735E-15 -15.8317 0.14735E-15 -15.8317 0.10000E+01 0.0000 32 CO2,aq 0.15435E-07 -7.8115 0.15380E-07 -7.8130 0.99648E+00 -0.0015 33 CO3-2 0.19457E-03 -3.7109 0.10055E-03 -3.9976 0.51680E+00 -0.2867 34 CaCO3,aq 0.55516E-07 -7.2556 0.55516E-07 -7.2556 0.10000E+01 0.0000 35 Ca(HCO3)+ 0.12235E-09 -9.9124 0.10231E-09 -9.9901 0.83624E+00 -0.0777 36 CaCl+ 0.12538E-10 -10.9018 0.10485E-10 -10.9794 0.83624E+00 -0.0777 37 CaCl2,aq 0.36654E-15 -15.4359 0.36654E-15 -15.4359 0.10000E+01 0.0000 38 CaF+ 0.10915E-11 -11.9620 0.91277E-12 -12.0396 0.83624E+00 -0.0777 39 CaOH+ 0.47458E-07 -7.3237 0.39686E-07 -7.4014 0.83624E+00 -0.0777 40 CaSO4,aq 0.18095E-10 -10.7424 0.18095E-10 -10.7424 0.10000E+01 0.0000 41 HCl,aq 0.21321E-14 -14.6712 0.21321E-14 -14.6712 0.10000E+01 0.0000 45 HF,aq 0.76858E-12 -12.1143 0.76858E-12 -12.1143 0.10000E+01 0.0000 46 HF2- 0.44145E-18 -18.3551 0.36844E-18 -18.4336 0.83463E+00 -0.0785 48 FeCl+ 0.43201E-17 -17.3645 0.36126E-17 -17.4422 0.83624E+00 -0.0777 51 FeF+ 0.13458E-17 -17.8710 0.11254E-17 -17.9487 0.83624E+00 -0.0777 53 FeO,aq 0.96417E-10 -10.0158 0.96417E-10 -10.0158 0.10000E+01 0.0000 54 FeOH+ 0.76358E-11 -11.1171 0.63853E-11 -11.1948 0.83624E+00 -0.0777 55 HFeO2- 0.15286E-07 -7.8157 0.12758E-07 -7.8942 0.83463E+00 -0.0785 56 FeO+ 0.29492E-16 -16.5303 0.24662E-16 -16.6080 0.83624E+00 -0.0777 58 FeO2- 0.96702E-09 -9.0146 0.80710E-09 -9.0931 0.83463E+00 -0.0785 59 HFeO2,aq 0.81169E-11 -11.0906 0.81169E-11 -11.0906 0.10000E+01 0.0000 60 H2,aq 0.38272E-06 -6.4171 0.38137E-06 -6.4187 0.99648E+00 -0.0015 61 KCl,aq 0.34903E-09 -9.4571 0.34903E-09 -9.4571 0.10000E+01 0.0000 62 KHSO4,aq 0.37867E-19 -19.4217 0.37867E-19 -19.4217 0.10000E+01 0.0000 63 KOH,aq 0.70684E-06 -6.1507 0.70684E-06 -6.1507 0.10000E+01 0.0000 64 KSO4- 0.31491E-08 -8.5018 0.26283E-08 -8.5803 0.83463E+00 -0.0785 65 MgCO3,aq 0.34509E-11 -11.4621 0.34509E-11 -11.4621 0.10000E+01 0.0000 66 Mg(HCO3)+ 0.31003E-13 -13.5086 0.25926E-13 -13.5863 0.83624E+00 -0.0777 67 MgCl+ 0.28181E-14 -14.5500 0.23566E-14 -14.6277 0.83624E+00 -0.0777 68 MgF+ 0.10027E-14 -14.9988 0.83849E-15 -15.0765 0.83624E+00 -0.0777 69 MgOH+ 0.65124E-10 -10.1863 0.54459E-10 -10.2639 0.83624E+00 -0.0777 71 MnF+ 0.30742E-15 -15.5123 0.25708E-15 -15.5899 0.83624E+00 -0.0777 72 MnO,aq 0.17804E-08 -8.7495 0.17804E-08 -8.7495 0.10000E+01 0.0000 73 MnOH+ 0.49158E-09 -9.3084 0.41107E-09 -9.3861 0.83624E+00 -0.0777 74 MnO2-2 0.18286E-10 -10.7379 0.94501E-11 -11.0246 0.51680E+00 -0.2867 75 HMnO2- 0.19615E-09 -9.7074 0.16371E-09 -9.7859 0.83463E+00 -0.0785 78 MnCl+ 0.11648E-13 -13.9338 0.97401E-14 -14.0114 0.83624E+00 -0.0777 79 MnSO4,aq 0.40161E-14 -14.3962 0.40161E-14 -14.3962 0.10000E+01 0.0000 80 NaCl,aq 0.80869E-06 -6.0922 0.80869E-06 -6.0922 0.10000E+01 0.0000 81 NaF,aq 0.55127E-08 -8.2586 0.55127E-08 -8.2586 0.10000E+01 0.0000 82 NaOH,aq 0.90109E-04 -4.0452 0.90109E-04 -4.0452 0.10000E+01 0.0000 84 OH- 0.87706E-02 -2.0570 0.73069E-02 -2.1363 0.83311E+00 -0.0793 89 HPO3-2 0.54046E-16 -16.2672 0.27931E-16 -16.5539 0.51680E+00 -0.2867 92 H3PO4,aq 0.10277E-17 -17.9881 0.10277E-17 -17.9881 0.10000E+01 0.0000 93 H2PO4- 0.41034E-10 -10.3869 0.34281E-10 -10.4649 0.83542E+00 -0.0781 94 PO4-3 0.10052E-08 -8.9978 0.24249E-09 -9.6153 0.24125E+00 -0.6175 98 HP2O7-3 0.10124E-17 -17.9946 0.23269E-18 -18.6332 0.22983E+00 -0.6386 99 P2O7-4 0.92161E-17 -17.0355 0.70300E-18 -18.1530 0.76280E-01 -1.1176 100 H2S,aq 0.25181E-07 -7.5989 0.25093E-07 -7.6005 0.99648E+00 -0.0015 101 S2-2 0.11853E-11 -11.9262 0.61254E-12 -12.2129 0.51680E+00 -0.2867 102 S3-2 0.10507E-18 -18.9785 0.54298E-19 -19.2652 0.51680E+00 -0.2867 107 SO3-2 0.12232E-12 -12.9125 0.64137E-13 -13.1929 0.52433E+00 -0.2804 108 HSO3- 0.38046E-15 -15.4197 0.31754E-15 -15.4982 0.83463E+00 -0.0785 109 HSO4- 0.11782E-12 -12.9288 0.98620E-13 -13.0060 0.83706E+00 -0.0772 111 S2O3-2 0.73814E-15 -15.1319 0.38147E-15 -15.4185 0.51680E+00 -0.2867 Charge balance for all species = -.6132E-08 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.9416626E-10 -.2186441E-01 -.2199943E+02 0.0000 2 H2O 0.1000000E+01 0.5550433E+02 0.9981767E+06 0.0000 3 Cl- 0.1763007E-03 0.1771098E-03 0.6268081E+01 6.2697 4 SO4-- 0.2498845E-05 0.2399414E-05 0.2300881E+00 14.3159 5 HCO3- 0.1089055E-03 0.3035542E-03 0.1848960E+02 6.0612 6 HS- 0.1230038E-03 0.1231316E-03 0.4065080E+01 6.1134 7 Al+++ 0.1052575E-28 0.4450223E-05 0.1198635E+00 0.6891 8 H4SiO4 0.7386579E-03 0.1352905E-01 0.1298073E+04 -3.1316 9 Ca++ 0.8565175E-07 0.1992387E-06 0.7971111E-02 12.8477 10 Mg++ 0.2133907E-10 0.9317643E-10 0.2261340E-05 9.2421 11 Fe++ 0.3027955E-13 0.1636536E-07 0.9123563E-03 6.3946 12 K+ 0.1565403E-03 0.1572507E-03 0.6138051E+01 6.2188 13 Na+ 0.1987329E-01 0.2230376E-01 0.5118613E+03 8.3217 14 Mn++ 0.2096640E-10 0.2507402E-08 0.1375105E-03 9.2353 15 F- 0.1704731E-05 0.1710246E-05 0.3243437E-01 4.2542 16 HPO4-- 0.4537116E-07 0.4641736E-07 0.4447292E-02 12.5750 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.1963999E-01 -.1963678E-01 -.3204439E-05 0.0000000E+00 2 H2O 0.4984935E+02 0.4984935E+02 -.3116942E-05 0.0000000E+00 3 Cl- 0.1590652E-03 0.1590652E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.2157190E-05 0.2154953E-05 0.2236784E-08 0.0000000E+00 5 HCO3- 0.2726270E-03 0.2726270E-03 0.0000000E+00 0.0000000E+00 6 HS- 0.1105843E-03 0.1105865E-03 -.2236784E-08 0.0000000E+00 7 Al+++ 0.4775352E-05 0.3996818E-05 0.7785336E-06 0.0000000E+00 8 H4SiO4 0.1215302E-01 0.1215066E-01 0.2360140E-05 0.0000000E+00 9 Ca++ 0.2080835E-06 0.1789396E-06 0.2914394E-07 0.0000000E+00 10 Mg++ 0.8368328E-10 0.8368328E-10 0.0000000E+00 0.0000000E+00 11 Fe++ 0.3259227E-07 0.1469800E-07 0.1789427E-07 0.0000000E+00 12 K+ 0.1412294E-03 0.1412294E-03 0.0000000E+00 0.0000000E+00 13 Na+ 0.2003215E-01 0.2003137E-01 0.7769986E-06 0.0000000E+00 14 Mn++ 0.2251939E-08 0.2251939E-08 0.0000000E+00 0.0000000E+00 15 F- 0.1536000E-05 0.1536000E-05 0.0000000E+00 0.0000000E+00 16 HPO4-- 0.4168819E-07 0.4168819E-07 0.0000000E+00 0.0000000E+00 Chg. balance for solid moles: 0.6353E-21 Mass of aqueous solution: 0.899691E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 0.0035900 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 0.7770E-06 -6.110 0.2037E-03 -3.691 97.66 0.7821E-04 andradite 0.8947E-08 -8.048 0.4547E-05 -5.342 2.179 0.1181E-05 grossular 0.7675E-09 -9.115 0.3457E-06 -6.461 0.1657 0.9620E-07 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.9210E+00 0.9210E+00 1.0000 -0.036 grossular 0.7901E-01 0.7901E-01 1.0000 -1.102 Solid products produced: Mass = 0.000209 g Volume = 0.000079 cm3 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.0035900 moles log = -2.4449 Original solution: 1000.0103000 g Original solution / Rock added: 278554.40 (Water/Rock Ratio), log = 5.4449 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0208 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9995E+00 0.9859 0.1006E+01 0.1020E+01 CO2,gas 0.1601E-05 1.0071 0.1646E-05 0.1634E-05 CH4,gas 0.9991E-05 1.0125 0.1033E-04 0.1020E-04 H2,gas 0.4902E-03 1.0005 0.5007E-03 0.5004E-03 H2S,gas 0.6784E-06 0.9960 0.6898E-06 0.6925E-06 S2,gas 0.6979E-25 1.0000 0.7124E-25 0.7124E-25 CO,gas 0.2151E-12 1.0000 0.2196E-12 0.2196E-12 SO3,gas 0.2997E-41 1.0000 0.3060E-41 0.3060E-41 SO2,gas 0.5838E-22 1.0000 0.5960E-22 0.5960E-22 HF,gas 0.1849E-14 1.0000 0.1887E-14 0.1887E-14 HCl,gas 0.3685E-17 1.0000 0.3762E-17 0.3762E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 17 albite -0.38 -0.38 0.00 0.000 -0.94784E-12 23 andradite 39.01 39.01 0.00 0.000 0.12132E-10 24 grossular 32.73 32.73 0.00 0.000 0.00000E+00 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -14.14 -7.48 -2.494 0.12776E+05 -5.784 3 CH4,gas 4.54 -2.14 -6.69 -1.671 0.11415E+05 -4.986 4 H2,gas 8.00 3.00 -5.00 -2.857 0.85363E+04 -3.300 5 H2S,gas -6.23 -14.09 -7.86 -3.930 0.13421E+05 -6.161 6 S2,gas -7.34 -34.18 -26.85 -4.130 0.45839E+05 -25.147 7 CO,gas 3.21 -11.14 -14.36 -4.418 0.24515E+05 -12.658 8 SO3,gas 17.12 -26.09 -43.21 -10.803 0.73786E+05 -41.514 9 SO2,gas 0.83 -23.09 -23.92 -6.380 0.40849E+05 -22.225 10 HF,gas 0.47 -15.95 -16.42 -8.212 0.28042E+05 -14.724 11 HCl,gas 5.19 -13.93 -19.12 -9.562 0.32653E+05 -17.425 12 acmite 7.71 6.95 -0.76 -0.079 0.12922E+04 16 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 20 spessartine 24.46 19.69 -4.77 -0.238 0.81408E+04 21 analcite 3.32 2.75 -0.57 -0.064 0.98038E+03 27 annite 20.12 16.70 -3.43 -0.190 0.58503E+04 28 phlogopite 27.06 25.24 -1.82 -0.101 0.31159E+04 30 anorthite 12.71 7.96 -4.75 -0.365 0.81061E+04 33 apatite-OH -18.15 -19.26 -1.11 -0.085 0.18894E+04 34 apatite-F -34.30 -35.21 -0.91 -0.076 0.15517E+04 38 aragonite 0.97 -1.30 -2.26 -0.754 0.38616E+04 39 brucite 12.57 9.24 -3.33 -0.665 0.56798E+04 40 calcite 0.81 -1.30 -2.11 -0.702 0.35974E+04 41 carnegieite-low 9.02 5.88 -3.14 -0.449 0.53684E+04 42 carnegieite-high 10.09 5.88 -4.21 -0.602 0.71954E+04 43 carpholite-Mg 8.58 4.36 -4.22 -0.282 0.72137E+04 45 celadonite 5.34 3.62 -1.72 -0.101 0.29329E+04 46 celadonite-Fe 3.88 0.78 -3.10 -0.182 0.52935E+04 47 chrysotile 23.89 21.46 -2.43 -0.202 0.41476E+04 49 clinochlore 39.07 38.19 -0.88 -0.027 0.14944E+04 52 chlorite-Al-free 47.17 42.93 -4.25 -0.177 0.72504E+04 54 chloritoid-Fe 9.17 4.64 -4.53 -0.302 0.77388E+04 55 chloritoid-Mn 11.40 7.48 -3.92 -0.261 0.66916E+04 57 coesite -2.38 -3.13 -0.76 -0.252 0.12900E+04 64 cristobalite -2.56 -3.13 -0.57 -0.190 0.97534E+03 66 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71237E+04 68 diaspore 2.87 0.69 -2.18 -0.364 0.37301E+04 70 diopside 16.18 15.83 -0.35 -0.035 0.60552E+03 71 hedenbergite 14.21 12.98 -1.23 -0.123 0.20986E+04 76 clinoenstatite 17.17 12.22 -4.95 -0.495 0.84437E+04 78 epidote 24.67 22.57 -2.10 -0.102 0.35797E+04 79 clinozoisite 22.81 18.37 -4.44 -0.202 0.75775E+04 80 epidote-Fe 29.84 26.78 -3.06 -0.159 0.52284E+04 81 fayalite 14.05 9.66 -4.39 -0.627 0.74926E+04 82 ferrosilite 11.15 6.53 -4.62 -0.462 0.78943E+04 86 gibbsite 4.08 0.69 -3.39 -0.484 0.57886E+04 87 glaucophane 22.97 20.70 -2.28 -0.062 0.38917E+04 89 graphite -3.55 -8.14 -4.60 -1.313 0.78474E+04 90 greenalite 16.14 12.92 -3.22 -0.268 0.54961E+04 93 hematite 12.57 9.79 -2.78 -0.337 0.47423E+04 94 heulandite -5.83 -7.69 -1.87 -0.085 0.31890E+04 98 jadeite 4.22 2.75 -1.47 -0.147 0.25059E+04 100 kalsilite 7.58 3.78 -3.81 -0.544 0.65012E+04 101 kaolinite -1.33 -4.88 -3.55 -0.323 0.60650E+04 104 laumontite 2.88 1.70 -1.18 -0.079 0.20210E+04 105 lawsonite 9.62 7.96 -1.65 -0.110 0.28228E+04 106 leucite 4.12 0.64 -3.47 -0.347 0.59317E+04 108 lizardite 23.24 21.46 -1.78 -0.148 0.30402E+04 110 magnetite 20.09 16.18 -3.90 -0.319 0.66659E+04 111 minnesotaite 10.39 6.66 -3.73 -0.219 0.63698E+04 115 manganosite 14.06 9.24 -4.82 -1.206 0.82348E+04 119 microcline -2.49 -2.49 0.00 0.000 0.32873E+00 123 muscovite 2.58 -1.11 -3.69 -0.217 0.63020E+04 124 paragonite 4.24 0.99 -3.24 -0.191 0.55407E+04 125 nepheline 8.34 5.88 -2.46 -0.351 0.42007E+04 137 phlogopite-Na 29.65 27.34 -2.30 -0.128 0.39344E+04 139 prehnite 19.37 17.68 -1.69 -0.100 0.28905E+04 140 prehnite-Fe 22.50 21.88 -0.61 -0.037 0.10476E+04 141 pumpellyite-Fe 46.27 42.44 -3.83 -0.085 0.65355E+04 142 pumpellyite-Mg 48.99 45.29 -3.71 -0.082 0.63271E+04 145 pyrite -21.25 -24.79 -3.54 -0.833 0.60442E+04 146 pyrrhotite -4.26 -7.70 -3.44 -1.145 0.58662E+04 147 pyrrhotiteFe0.875 -6.02 -8.87 -2.85 -1.048 0.48669E+04 148 pyroxmangite 7.40 6.10 -1.29 -0.259 0.22110E+04 149 pyrophyllite -6.18 -11.15 -4.97 -0.311 0.84898E+04 150 quartz -2.99 -3.13 -0.14 -0.047 0.24267E+03 154 rhodochrosite -0.98 -4.91 -3.93 -1.310 0.67123E+04 155 rhodonite 7.45 6.10 -1.34 -0.268 0.22913E+04 156 sanidine -1.28 -2.49 -1.21 -0.093 0.20681E+04 166 stilbite -7.52 -7.69 -0.17 -0.008 0.29512E+03 167 stilpnomelane-Fe 13.02 11.41 -1.61 -0.048 0.27469E+04 168 stilpnomelane-Mg 27.44 25.65 -1.80 -0.054 0.30657E+04 174 talc 16.49 15.20 -1.29 -0.076 0.22042E+04 177 tephroite 18.09 15.34 -2.75 -0.392 0.46899E+04 181 tridymite -2.63 -3.13 -0.51 -0.168 0.86265E+03 182 tremolite 47.87 46.85 -1.02 -0.027 0.17341E+04 184 troilite-low -4.41 -7.70 -3.28 -1.095 0.56090E+04 190 wairakite 3.95 1.70 -2.25 -0.132 0.38430E+04 191 walstromite 11.51 9.72 -1.79 -0.359 0.30616E+04 192 wollastonite 10.46 9.72 -0.74 -0.149 0.12721E+04 193 pseudo-wollastonite 11.00 9.72 -1.28 -0.257 0.21919E+04 194 zoisite 22.85 18.37 -4.48 -0.204 0.76516E+04 195 akaganeite 7.75 4.89 -2.86 -0.618 0.48837E+04 202 chalcedony -2.80 -3.13 -0.33 -0.110 0.56197E+03 204 montmorillonite-Ca -2.29 -6.21 -3.91 -0.242 0.66845E+04 205 montmorillonite-K -2.24 -6.27 -4.04 -0.247 0.68922E+04 206 montmorillonite-Mg -2.48 -6.80 -4.32 -0.267 0.73773E+04 207 montmorillonite-Na -2.04 -5.58 -3.54 -0.217 0.60470E+04 208 nontronite-Ca 3.21 0.64 -2.57 -0.167 0.43903E+04 209 nontronite-H 2.53 -1.48 -4.01 -0.269 0.68457E+04 210 nontronite-K 3.34 0.58 -2.77 -0.177 0.47213E+04 211 nontronite-Mg 3.07 0.05 -3.03 -0.196 0.51672E+04 212 nontronite-Na 3.52 1.27 -2.25 -0.144 0.38420E+04 228 tobermorite 9.82 7.57 -2.25 -0.615 0.38460E+04 234 alabandite -0.98 -4.86 -3.88 -1.292 0.66204E+04 237 boehmite 4.41 0.69 -3.72 -0.620 0.63470E+04 239 ferrous-oxide 9.81 6.39 -3.42 -0.854 0.58344E+04 245 silica-amorphous -2.09 -3.13 -1.04 -0.347 0.17761E+04 247 an20ab80 2.02 1.29 -0.73 -0.056 0.12504E+04 248 an25ab75 2.65 1.70 -0.94 -0.073 0.16099E+04 249 an30ab70 3.28 2.12 -1.16 -0.089 0.19791E+04 250 tr.625ac.25prg.125 45.16 44.22 -0.94 -0.025 0.16123E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 0.0001000 MOLES Current total amount of reactant added: 0.0035900 MOLES New total amount of reactant added: 0.0036900 MOLES Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.5508E-08 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 7 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 0.0036900 Water: Moles liquid = 0.4985E+02 kg liquid = 0.8981E+00 Moles total = 0.4985E+02 kg total = 0.8981E+00 Activity = 1.0000 Stoichiometric ionic strength = .1156582E-01 Osmotic coef. = 0.9593 True ionic strength = .2023321E-01 Chg. balance for total moles = -.5508E-08 Max. difference allowed = 0.1597E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.94337E-10 -10.0253 0.79215E-10 -10.1012 0.83970E+00 -0.0759 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.17695E-03 -3.7521 0.14769E-03 -3.8307 0.83461E+00 -0.0785 4 SO4-- 0.30248E-05 -5.5193 0.15664E-05 -5.8051 0.51787E+00 -0.2858 5 HCO3- 0.11192E-03 -3.9511 0.93546E-04 -4.0290 0.83584E+00 -0.0779 6 HS- 0.12518E-03 -3.9025 0.10449E-03 -3.9809 0.83473E+00 -0.0785 7 Al+++ 0.10550E-28 -28.9767 0.24220E-29 -29.6158 0.22956E+00 -0.6391 8 H4SiO4 0.73990E-03 -3.1308 0.73990E-03 -3.1308 0.10000E+01 0.0000 9 Ca++ 0.85021E-07 -7.0705 0.43703E-07 -7.3595 0.51403E+00 -0.2890 10 Mg++ 0.21346E-10 -10.6707 0.10922E-10 -10.9617 0.51166E+00 -0.2910 11 Fe++ 0.30199E-13 -13.5200 0.15469E-13 -13.8105 0.51223E+00 -0.2905 12 K+ 0.15654E-03 -3.8054 0.13087E-03 -3.8831 0.83604E+00 -0.0778 13 Na+ 0.19874E-01 -1.7017 0.16584E-01 -1.7803 0.83446E+00 -0.0786 14 Mn++ 0.21039E-10 -10.6770 0.10786E-10 -10.9672 0.51265E+00 -0.2902 15 F- 0.17491E-05 -5.7572 0.14568E-05 -5.8366 0.83287E+00 -0.0794 16 HPO4-- 0.45373E-07 -7.3432 0.23500E-07 -7.6289 0.51794E+00 -0.2857 18 HSiO3- 0.10450E-01 -1.9809 0.87215E-02 -2.0594 0.83461E+00 -0.0785 19 Ca(HSiO3)+ 0.10381E-07 -7.9838 0.86804E-08 -8.0615 0.83622E+00 -0.0777 20 Mg(HSiO3)+ 0.32286E-11 -11.4910 0.26998E-11 -11.5687 0.83622E+00 -0.0777 21 NaHSiO3,aq 0.23393E-02 -2.6309 0.23393E-02 -2.6309 0.10000E+01 0.0000 22 AlO+ 0.62792E-16 -16.2021 0.52508E-16 -16.2798 0.83622E+00 -0.0777 24 HAlO2,aq 0.13201E-09 -9.8794 0.13201E-09 -9.8794 0.10000E+01 0.0000 25 AlO2- 0.44279E-05 -5.3538 0.36888E-05 -5.4331 0.83309E+00 -0.0793 26 CH4,aq 0.60832E-08 -8.2159 0.60617E-08 -8.2174 0.99647E+00 -0.0015 27 C2H6,aq 0.17270E-19 -19.7627 0.17209E-19 -19.7643 0.99647E+00 -0.0015 31 CO,aq 0.14519E-15 -15.8381 0.14519E-15 -15.8381 0.10000E+01 0.0000 32 CO2,aq 0.15890E-07 -7.7989 0.15834E-07 -7.8004 0.99647E+00 -0.0015 33 CO3-2 0.19961E-03 -3.6998 0.10315E-03 -3.9865 0.51676E+00 -0.2867 34 CaCO3,aq 0.56524E-07 -7.2478 0.56524E-07 -7.2478 0.10000E+01 0.0000 35 Ca(HCO3)+ 0.12480E-09 -9.9038 0.10436E-09 -9.9815 0.83622E+00 -0.0777 36 CaCl+ 0.12491E-10 -10.9034 0.10445E-10 -10.9811 0.83622E+00 -0.0777 37 CaCl2,aq 0.36650E-15 -15.4359 0.36650E-15 -15.4359 0.10000E+01 0.0000 38 CaF+ 0.11116E-11 -11.9541 0.92954E-12 -12.0317 0.83622E+00 -0.0777 39 CaOH+ 0.47021E-07 -7.3277 0.39320E-07 -7.4054 0.83622E+00 -0.0777 40 CaSO4,aq 0.21739E-10 -10.6628 0.21739E-10 -10.6628 0.10000E+01 0.0000 41 HCl,aq 0.21438E-14 -14.6688 0.21438E-14 -14.6688 0.10000E+01 0.0000 45 HF,aq 0.79000E-12 -12.1024 0.79000E-12 -12.1024 0.10000E+01 0.0000 46 HF2- 0.46556E-18 -18.3320 0.38856E-18 -18.4105 0.83461E+00 -0.0785 48 FeCl+ 0.43242E-17 -17.3641 0.36160E-17 -17.4418 0.83622E+00 -0.0777 51 FeF+ 0.13771E-17 -17.8610 0.11516E-17 -17.9387 0.83622E+00 -0.0777 53 FeO,aq 0.95808E-10 -10.0186 0.95808E-10 -10.0186 0.10000E+01 0.0000 54 FeOH+ 0.76013E-11 -11.1191 0.63564E-11 -11.1968 0.83622E+00 -0.0777 55 HFeO2- 0.15163E-07 -7.8192 0.12655E-07 -7.8977 0.83461E+00 -0.0785 56 FeO+ 0.30009E-16 -16.5228 0.25094E-16 -16.6004 0.83622E+00 -0.0777 58 FeO2- 0.98044E-09 -9.0086 0.81829E-09 -9.0871 0.83461E+00 -0.0785 59 HFeO2,aq 0.82442E-11 -11.0839 0.82442E-11 -11.0839 0.10000E+01 0.0000 60 H2,aq 0.36632E-06 -6.4361 0.36503E-06 -6.4377 0.99647E+00 -0.0015 61 KCl,aq 0.35031E-09 -9.4555 0.35031E-09 -9.4555 0.10000E+01 0.0000 62 KHSO4,aq 0.45915E-19 -19.3380 0.45915E-19 -19.3380 0.10000E+01 0.0000 63 KOH,aq 0.70556E-06 -6.1515 0.70556E-06 -6.1515 0.10000E+01 0.0000 64 KSO4- 0.38116E-08 -8.4189 0.31812E-08 -8.4974 0.83461E+00 -0.0785 65 MgCO3,aq 0.35408E-11 -11.4509 0.35408E-11 -11.4509 0.10000E+01 0.0000 66 Mg(HCO3)+ 0.31869E-13 -13.4966 0.26649E-13 -13.5743 0.83622E+00 -0.0777 67 MgCl+ 0.28293E-14 -14.5483 0.23659E-14 -14.6260 0.83622E+00 -0.0777 68 MgF+ 0.10291E-14 -14.9876 0.86053E-15 -15.0652 0.83622E+00 -0.0777 69 MgOH+ 0.65025E-10 -10.1869 0.54375E-10 -10.2646 0.83622E+00 -0.0777 71 MnF+ 0.31649E-15 -15.4996 0.26465E-15 -15.5773 0.83622E+00 -0.0777 72 MnO,aq 0.17800E-08 -8.7496 0.17800E-08 -8.7496 0.10000E+01 0.0000 73 MnOH+ 0.49236E-09 -9.3077 0.41172E-09 -9.3854 0.83622E+00 -0.0777 74 MnO2-2 0.18218E-10 -10.7395 0.94141E-11 -11.0262 0.51676E+00 -0.2867 75 HMnO2- 0.19576E-09 -9.7083 0.16338E-09 -9.7868 0.83461E+00 -0.0785 78 MnCl+ 0.11730E-13 -13.9307 0.98090E-14 -14.0084 0.83622E+00 -0.0777 79 MnSO4,aq 0.48774E-14 -14.3118 0.48774E-14 -14.3118 0.10000E+01 0.0000 80 NaCl,aq 0.81167E-06 -6.0906 0.81167E-06 -6.0906 0.10000E+01 0.0000 81 NaF,aq 0.56561E-08 -8.2475 0.56561E-08 -8.2475 0.10000E+01 0.0000 82 NaOH,aq 0.89947E-04 -4.0460 0.89947E-04 -4.0460 0.10000E+01 0.0000 84 OH- 0.87550E-02 -2.0577 0.72937E-02 -2.1370 0.83309E+00 -0.0793 89 HPO3-2 0.51732E-16 -16.2862 0.26733E-16 -16.5730 0.51676E+00 -0.2867 92 H3PO4,aq 0.10314E-17 -17.9866 0.10314E-17 -17.9866 0.10000E+01 0.0000 93 H2PO4- 0.41107E-10 -10.3861 0.34341E-10 -10.4642 0.83541E+00 -0.0781 94 PO4-3 0.10035E-08 -8.9985 0.24205E-09 -9.6161 0.24121E+00 -0.6176 98 HP2O7-3 0.10143E-17 -17.9938 0.23309E-18 -18.6325 0.22979E+00 -0.6387 99 P2O7-4 0.92182E-17 -17.0354 0.70294E-18 -18.1531 0.76256E-01 -1.1177 100 H2S,aq 0.25673E-07 -7.5905 0.25582E-07 -7.5921 0.99647E+00 -0.0015 101 S2-2 0.12826E-11 -11.8919 0.66280E-12 -12.1786 0.51676E+00 -0.2867 102 S3-2 0.12111E-18 -18.9168 0.62582E-19 -19.2035 0.51676E+00 -0.2867 107 SO3-2 0.14172E-12 -12.8486 0.74304E-13 -13.1290 0.52429E+00 -0.2804 108 HSO3- 0.44157E-15 -15.3550 0.36853E-15 -15.4335 0.83461E+00 -0.0785 109 HSO4- 0.14286E-12 -12.8451 0.11958E-12 -12.9223 0.83704E+00 -0.0773 111 S2O3-2 0.91093E-15 -15.0405 0.47073E-15 -15.3272 0.51676E+00 -0.2867 Charge balance for all species = -.6132E-08 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.9433728E-10 -.2185229E-01 -.2198723E+02 0.0000 2 H2O 0.1000000E+01 0.5550432E+02 0.9981761E+06 0.0000 3 Cl- 0.1769543E-03 0.1777664E-03 0.6291316E+01 6.2705 4 SO4-- 0.3024769E-05 0.2931063E-05 0.2810696E+00 14.3973 5 HCO3- 0.1119186E-03 0.3116038E-03 0.1897990E+02 6.0722 6 HS- 0.1251822E-03 0.1253054E-03 0.4136843E+01 6.1203 7 Al+++ 0.1055033E-28 0.4427988E-05 0.1192646E+00 0.6877 8 H4SiO4 0.7398972E-03 0.1352895E-01 0.1298064E+04 -3.1308 9 Ca++ 0.8502061E-07 0.1991061E-06 0.7965802E-02 12.8429 10 Mg++ 0.2134629E-10 0.9317625E-10 0.2261335E-05 9.2407 11 Fe++ 0.3019884E-13 0.1625467E-07 0.9061850E-03 6.3918 12 K+ 0.1565406E-03 0.1572504E-03 0.6138037E+01 6.2180 13 Na+ 0.1987367E-01 0.2230370E-01 0.5118597E+03 8.3209 14 Mn++ 0.2103879E-10 0.2507397E-08 0.1375102E-03 9.2352 15 F- 0.1749122E-05 0.1754780E-05 0.3327894E-01 4.2646 16 HPO4-- 0.4537268E-07 0.4641727E-07 0.4447282E-02 12.5735 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.1962922E-01 -.1962593E-01 -.3284730E-05 0.0000000E+00 2 H2O 0.4984943E+02 0.4984943E+02 -.3196918E-05 0.0000000E+00 3 Cl- 0.1596552E-03 0.1596552E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.2634690E-05 0.2632441E-05 0.2249207E-08 0.0000000E+00 5 HCO3- 0.2798570E-03 0.2798570E-03 0.0000000E+00 0.0000000E+00 6 HS- 0.1125368E-03 0.1125390E-03 -.2249207E-08 0.0000000E+00 7 Al+++ 0.4775352E-05 0.3976857E-05 0.7984952E-06 0.0000000E+00 8 H4SiO4 0.1215302E-01 0.1215060E-01 0.2420204E-05 0.0000000E+00 9 Ca++ 0.2080835E-06 0.1788208E-06 0.2926271E-07 0.0000000E+00 10 Mg++ 0.8368328E-10 0.8368328E-10 0.0000000E+00 0.0000000E+00 11 Fe++ 0.3259227E-07 0.1459861E-07 0.1799366E-07 0.0000000E+00 12 K+ 0.1412294E-03 0.1412294E-03 0.0000000E+00 0.0000000E+00 13 Na+ 0.2003215E-01 0.2003135E-01 0.7969804E-06 0.0000000E+00 14 Mn++ 0.2251939E-08 0.2251939E-08 0.0000000E+00 0.0000000E+00 15 F- 0.1576000E-05 0.1576000E-05 0.0000000E+00 0.0000000E+00 16 HPO4-- 0.4168819E-07 0.4168819E-07 0.0000000E+00 0.0000000E+00 Chg. balance for solid moles: -.4235E-21 Mass of aqueous solution: 0.899693E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 0.0036900 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 0.7970E-06 -6.099 0.2090E-03 -3.680 97.70 0.8022E-04 andradite 0.8997E-08 -8.046 0.4572E-05 -5.340 2.137 0.1188E-05 grossular 0.7574E-09 -9.121 0.3412E-06 -6.467 0.1595 0.9493E-07 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.9224E+00 0.9224E+00 1.0000 -0.035 grossular 0.7765E-01 0.7765E-01 1.0000 -1.110 Solid products produced: Mass = 0.000214 g Volume = 0.000082 cm3 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.0036900 moles log = -2.4330 Original solution: 1000.0103000 g Original solution / Rock added: 271005.50 (Water/Rock Ratio), log = 5.4330 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0208 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9995E+00 0.9859 0.1006E+01 0.1020E+01 CO2,gas 0.1648E-05 1.0071 0.1694E-05 0.1682E-05 CH4,gas 0.8633E-05 1.0125 0.8922E-05 0.8812E-05 H2,gas 0.4692E-03 1.0005 0.4792E-03 0.4790E-03 H2S,gas 0.6917E-06 0.9960 0.7032E-06 0.7060E-06 S2,gas 0.7918E-25 1.0000 0.8083E-25 0.8083E-25 CO,gas 0.2120E-12 1.0000 0.2164E-12 0.2164E-12 SO3,gas 0.3641E-41 1.0000 0.3717E-41 0.3717E-41 SO2,gas 0.6788E-22 1.0000 0.6929E-22 0.6929E-22 HF,gas 0.1900E-14 1.0000 0.1940E-14 0.1940E-14 HCl,gas 0.3706E-17 1.0000 0.3783E-17 0.3783E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 17 albite -0.38 -0.38 0.00 0.000 0.11184E-10 23 andradite 39.01 39.01 0.00 0.000 0.00000E+00 24 grossular 32.73 32.73 0.00 0.000 0.12132E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -14.13 -7.47 -2.490 0.12755E+05 -5.771 3 CH4,gas 4.54 -2.20 -6.75 -1.687 0.11523E+05 -5.050 4 H2,gas 8.00 2.98 -5.02 -2.868 0.85688E+04 -3.319 5 H2S,gas -6.23 -14.08 -7.85 -3.926 0.13407E+05 -6.153 6 S2,gas -7.34 -34.13 -26.79 -4.122 0.45746E+05 -25.092 7 CO,gas 3.21 -11.15 -14.36 -4.420 0.24526E+05 -12.665 8 SO3,gas 17.12 -26.01 -43.13 -10.782 0.73641E+05 -41.430 9 SO2,gas 0.83 -23.03 -23.86 -6.362 0.40737E+05 -22.159 10 HF,gas 0.47 -15.94 -16.41 -8.206 0.28022E+05 -14.712 11 HCl,gas 5.19 -13.93 -19.12 -9.561 0.32649E+05 -17.422 12 acmite 7.71 6.96 -0.75 -0.078 0.12795E+04 16 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 20 spessartine 24.46 19.69 -4.77 -0.238 0.81423E+04 21 analcite 3.32 2.75 -0.57 -0.064 0.98162E+03 27 annite 20.12 16.69 -3.43 -0.191 0.58645E+04 28 phlogopite 27.06 25.24 -1.83 -0.102 0.31233E+04 30 anorthite 12.71 7.96 -4.75 -0.366 0.81166E+04 33 apatite-OH -18.15 -19.28 -1.13 -0.087 0.19225E+04 34 apatite-F -34.30 -35.22 -0.92 -0.076 0.15645E+04 38 aragonite 0.97 -1.29 -2.25 -0.751 0.38483E+04 39 brucite 12.57 9.24 -3.33 -0.666 0.56823E+04 40 calcite 0.81 -1.29 -2.10 -0.700 0.35841E+04 41 carnegieite-low 9.02 5.88 -3.15 -0.449 0.53709E+04 42 carnegieite-high 10.09 5.88 -4.22 -0.602 0.71979E+04 43 carpholite-Mg 8.58 4.35 -4.23 -0.282 0.72185E+04 45 celadonite 5.34 3.62 -1.72 -0.101 0.29342E+04 46 celadonite-Fe 3.88 0.77 -3.10 -0.182 0.52969E+04 47 chrysotile 23.89 21.46 -2.43 -0.203 0.41525E+04 49 clinochlore 39.07 38.19 -0.88 -0.028 0.15078E+04 52 chlorite-Al-free 47.17 42.92 -4.25 -0.177 0.72602E+04 54 chloritoid-Fe 9.17 4.64 -4.54 -0.302 0.77470E+04 55 chloritoid-Mn 11.40 7.48 -3.92 -0.261 0.66953E+04 57 coesite -2.38 -3.13 -0.75 -0.252 0.12887E+04 64 cristobalite -2.56 -3.13 -0.57 -0.190 0.97410E+03 66 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71237E+04 68 diaspore 2.87 0.69 -2.19 -0.364 0.37325E+04 70 diopside 16.18 15.82 -0.36 -0.036 0.61371E+03 71 hedenbergite 14.21 12.97 -1.24 -0.124 0.21091E+04 76 clinoenstatite 17.17 12.22 -4.95 -0.495 0.84461E+04 78 epidote 24.67 22.57 -2.10 -0.102 0.35856E+04 79 clinozoisite 22.81 18.36 -4.45 -0.202 0.75974E+04 80 epidote-Fe 29.84 26.78 -3.06 -0.159 0.52205E+04 81 fayalite 14.05 9.65 -4.39 -0.628 0.75007E+04 82 ferrosilite 11.15 6.52 -4.63 -0.463 0.79012E+04 86 gibbsite 4.08 0.69 -3.39 -0.485 0.57910E+04 87 glaucophane 22.97 20.69 -2.28 -0.062 0.38967E+04 89 graphite -3.55 -8.17 -4.62 -1.320 0.78908E+04 90 greenalite 16.14 12.91 -3.23 -0.269 0.55077E+04 93 hematite 12.57 9.80 -2.76 -0.335 0.47192E+04 94 heulandite -5.83 -7.70 -1.87 -0.085 0.31933E+04 98 jadeite 4.22 2.75 -1.47 -0.147 0.25071E+04 100 kalsilite 7.58 3.77 -3.81 -0.544 0.65037E+04 101 kaolinite -1.33 -4.89 -3.55 -0.323 0.60673E+04 104 laumontite 2.88 1.70 -1.19 -0.079 0.20291E+04 105 lawsonite 9.62 7.96 -1.66 -0.111 0.28333E+04 106 leucite 4.12 0.64 -3.47 -0.347 0.59330E+04 108 lizardite 23.24 21.46 -1.78 -0.149 0.30452E+04 110 magnetite 20.09 16.19 -3.89 -0.318 0.66476E+04 111 minnesotaite 10.39 6.65 -3.74 -0.220 0.63790E+04 115 manganosite 14.06 9.24 -4.82 -1.206 0.82349E+04 119 microcline -2.49 -2.49 0.00 0.000 0.34092E+00 123 muscovite 2.58 -1.11 -3.69 -0.217 0.63068E+04 124 paragonite 4.24 0.99 -3.25 -0.191 0.55455E+04 125 nepheline 8.34 5.88 -2.46 -0.352 0.42032E+04 137 phlogopite-Na 29.65 27.34 -2.31 -0.128 0.39418E+04 139 prehnite 19.37 17.67 -1.70 -0.100 0.29080E+04 140 prehnite-Fe 22.50 21.88 -0.62 -0.037 0.10512E+04 141 pumpellyite-Fe 46.27 42.42 -3.85 -0.086 0.65776E+04 142 pumpellyite-Mg 48.99 45.27 -3.73 -0.083 0.63669E+04 145 pyrite -21.25 -24.75 -3.51 -0.825 0.59877E+04 146 pyrrhotite -4.26 -7.69 -3.43 -1.143 0.58565E+04 147 pyrrhotiteFe0.875 -6.02 -8.86 -2.84 -1.045 0.48526E+04 148 pyroxmangite 7.40 6.10 -1.29 -0.259 0.22099E+04 149 pyrophyllite -6.18 -11.15 -4.97 -0.311 0.84896E+04 150 quartz -2.99 -3.13 -0.14 -0.047 0.24143E+03 154 rhodochrosite -0.98 -4.89 -3.92 -1.306 0.66909E+04 155 rhodonite 7.45 6.10 -1.34 -0.268 0.22902E+04 156 sanidine -1.28 -2.49 -1.21 -0.093 0.20681E+04 166 stilbite -7.52 -7.70 -0.18 -0.008 0.29942E+03 167 stilpnomelane-Fe 13.02 11.40 -1.62 -0.048 0.27659E+04 168 stilpnomelane-Mg 27.44 25.64 -1.80 -0.054 0.30736E+04 174 talc 16.49 15.20 -1.29 -0.076 0.22066E+04 177 tephroite 18.09 15.34 -2.75 -0.392 0.46890E+04 181 tridymite -2.63 -3.13 -0.50 -0.168 0.86140E+03 182 tremolite 47.87 46.84 -1.03 -0.028 0.17530E+04 184 troilite-low -4.41 -7.69 -3.28 -1.093 0.55993E+04 190 wairakite 3.95 1.70 -2.26 -0.133 0.38510E+04 191 walstromite 11.51 9.71 -1.80 -0.359 0.30686E+04 192 wollastonite 10.46 9.71 -0.75 -0.150 0.12790E+04 193 pseudo-wollastonite 11.00 9.71 -1.29 -0.258 0.21989E+04 194 zoisite 22.85 18.36 -4.49 -0.204 0.76714E+04 195 akaganeite 7.75 4.90 -2.85 -0.617 0.48721E+04 202 chalcedony -2.80 -3.13 -0.33 -0.109 0.56072E+03 204 montmorillonite-Ca -2.29 -6.21 -3.92 -0.242 0.66857E+04 205 montmorillonite-K -2.24 -6.27 -4.04 -0.247 0.68925E+04 206 montmorillonite-Mg -2.48 -6.80 -4.32 -0.267 0.73776E+04 207 montmorillonite-Na -2.04 -5.58 -3.54 -0.217 0.60473E+04 208 nontronite-Ca 3.21 0.66 -2.56 -0.166 0.43648E+04 209 nontronite-H 2.53 -1.46 -3.99 -0.268 0.68189E+04 210 nontronite-K 3.34 0.59 -2.75 -0.176 0.46949E+04 211 nontronite-Mg 3.07 0.06 -3.01 -0.195 0.51408E+04 212 nontronite-Na 3.52 1.29 -2.23 -0.143 0.38156E+04 228 tobermorite 9.82 7.57 -2.26 -0.615 0.38516E+04 234 alabandite -0.98 -4.85 -3.87 -1.290 0.66062E+04 237 boehmite 4.41 0.69 -3.72 -0.620 0.63494E+04 239 ferrous-oxide 9.81 6.39 -3.42 -0.855 0.58391E+04 245 silica-amorphous -2.09 -3.13 -1.04 -0.346 0.17749E+04 247 an20ab80 2.02 1.28 -0.73 -0.056 0.12525E+04 248 an25ab75 2.65 1.70 -0.94 -0.073 0.16126E+04 249 an30ab70 3.28 2.12 -1.16 -0.089 0.19823E+04 250 tr.625ac.25prg.125 45.16 44.21 -0.96 -0.026 0.16350E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 0.0001000 MOLES Current total amount of reactant added: 0.0036900 MOLES New total amount of reactant added: 0.0037900 MOLES Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.5508E-08 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 7 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 0.0037900 Water: Moles liquid = 0.4985E+02 kg liquid = 0.8981E+00 Moles total = 0.4985E+02 kg total = 0.8981E+00 Activity = 1.0000 Stoichiometric ionic strength = .1157222E-01 Osmotic coef. = 0.9590 True ionic strength = .2023914E-01 Chg. balance for total moles = -.5508E-08 Max. difference allowed = 0.1602E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.94509E-10 -10.0245 0.79358E-10 -10.1004 0.83969E+00 -0.0759 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.17761E-03 -3.7505 0.14823E-03 -3.8291 0.83459E+00 -0.0785 4 SO4-- 0.35518E-05 -5.4495 0.18392E-05 -5.7354 0.51783E+00 -0.2858 5 HCO3- 0.11494E-03 -3.9395 0.96068E-04 -4.0174 0.83582E+00 -0.0779 6 HS- 0.12736E-03 -3.8950 0.10631E-03 -3.9734 0.83472E+00 -0.0785 7 Al+++ 0.10575E-28 -28.9757 0.24272E-29 -29.6149 0.22952E+00 -0.6392 8 H4SiO4 0.74114E-03 -3.1301 0.74114E-03 -3.1301 0.10000E+01 0.0000 9 Ca++ 0.84430E-07 -7.0735 0.43396E-07 -7.3625 0.51399E+00 -0.2890 10 Mg++ 0.21354E-10 -10.6705 0.10925E-10 -10.9616 0.51162E+00 -0.2911 11 Fe++ 0.30210E-13 -13.5198 0.15473E-13 -13.8104 0.51218E+00 -0.2906 12 K+ 0.15654E-03 -3.8054 0.13087E-03 -3.8832 0.83602E+00 -0.0778 13 Na+ 0.19874E-01 -1.7017 0.16584E-01 -1.7803 0.83444E+00 -0.0786 14 Mn++ 0.21111E-10 -10.6755 0.10822E-10 -10.9657 0.51261E+00 -0.2902 15 F- 0.17935E-05 -5.7463 0.14937E-05 -5.8257 0.83286E+00 -0.0794 16 HPO4-- 0.45374E-07 -7.3432 0.23499E-07 -7.6289 0.51790E+00 -0.2858 18 HSiO3- 0.10449E-01 -1.9809 0.87204E-02 -2.0595 0.83459E+00 -0.0785 19 Ca(HSiO3)+ 0.10307E-07 -7.9869 0.86184E-08 -8.0646 0.83620E+00 -0.0777 20 Mg(HSiO3)+ 0.32291E-11 -11.4909 0.27002E-11 -11.5686 0.83620E+00 -0.0777 21 NaHSiO3,aq 0.23390E-02 -2.6310 0.23390E-02 -2.6310 0.10000E+01 0.0000 22 AlO+ 0.62703E-16 -16.2027 0.52433E-16 -16.2804 0.83620E+00 -0.0777 24 HAlO2,aq 0.13158E-09 -9.8808 0.13158E-09 -9.8808 0.10000E+01 0.0000 25 AlO2- 0.44057E-05 -5.3560 0.36703E-05 -5.4353 0.83307E+00 -0.0793 26 CH4,aq 0.54130E-08 -8.2666 0.53939E-08 -8.2681 0.99647E+00 -0.0015 27 C2H6,aq 0.14179E-19 -19.8483 0.14129E-19 -19.8499 0.99647E+00 -0.0015 31 CO,aq 0.14405E-15 -15.8415 0.14405E-15 -15.8415 0.10000E+01 0.0000 32 CO2,aq 0.16348E-07 -7.7865 0.16290E-07 -7.7881 0.99647E+00 -0.0015 33 CO3-2 0.20464E-03 -3.6890 0.10574E-03 -3.9758 0.51672E+00 -0.2867 34 CaCO3,aq 0.57537E-07 -7.2401 0.57537E-07 -7.2401 0.10000E+01 0.0000 35 Ca(HCO3)+ 0.12726E-09 -9.8953 0.10642E-09 -9.9730 0.83620E+00 -0.0777 36 CaCl+ 0.12449E-10 -10.9049 0.10410E-10 -10.9825 0.83620E+00 -0.0777 37 CaCl2,aq 0.36660E-15 -15.4358 0.36660E-15 -15.4358 0.10000E+01 0.0000 38 CaF+ 0.11318E-11 -11.9462 0.94642E-12 -12.0239 0.83620E+00 -0.0777 39 CaOH+ 0.46607E-07 -7.3315 0.38973E-07 -7.4092 0.83620E+00 -0.0777 40 CaSO4,aq 0.25345E-10 -10.5961 0.25345E-10 -10.5961 0.10000E+01 0.0000 41 HCl,aq 0.21556E-14 -14.6664 0.21556E-14 -14.6664 0.10000E+01 0.0000 45 HF,aq 0.81149E-12 -12.0907 0.81149E-12 -12.0907 0.10000E+01 0.0000 46 HF2- 0.49036E-18 -18.3095 0.40925E-18 -18.3880 0.83459E+00 -0.0785 48 FeCl+ 0.43415E-17 -17.3624 0.36304E-17 -17.4400 0.83620E+00 -0.0777 51 FeF+ 0.14125E-17 -17.8500 0.11811E-17 -17.9277 0.83620E+00 -0.0777 53 FeO,aq 0.95492E-10 -10.0200 0.95492E-10 -10.0200 0.10000E+01 0.0000 54 FeOH+ 0.75901E-11 -11.1198 0.63468E-11 -11.1974 0.83620E+00 -0.0777 55 HFeO2- 0.15086E-07 -7.8214 0.12590E-07 -7.9000 0.83459E+00 -0.0785 56 FeO+ 0.30513E-16 -16.5155 0.25515E-16 -16.5932 0.83620E+00 -0.0777 58 FeO2- 0.99334E-09 -9.0029 0.82903E-09 -9.0814 0.83459E+00 -0.0785 59 HFeO2,aq 0.83675E-11 -11.0774 0.83675E-11 -11.0774 0.10000E+01 0.0000 60 H2,aq 0.35327E-06 -6.4519 0.35202E-06 -6.4534 0.99647E+00 -0.0015 61 KCl,aq 0.35159E-09 -9.4540 0.35159E-09 -9.4540 0.10000E+01 0.0000 62 KHSO4,aq 0.54007E-19 -19.2675 0.54007E-19 -19.2675 0.10000E+01 0.0000 63 KOH,aq 0.70428E-06 -6.1523 0.70428E-06 -6.1523 0.10000E+01 0.0000 64 KSO4- 0.44754E-08 -8.3492 0.37351E-08 -8.4277 0.83459E+00 -0.0785 65 MgCO3,aq 0.36307E-11 -11.4400 0.36307E-11 -11.4400 0.10000E+01 0.0000 66 Mg(HCO3)+ 0.32737E-13 -13.4850 0.27375E-13 -13.5626 0.83620E+00 -0.0777 67 MgCl+ 0.28405E-14 -14.5466 0.23753E-14 -14.6243 0.83620E+00 -0.0777 68 MgF+ 0.10555E-14 -14.9766 0.88258E-15 -15.0542 0.83620E+00 -0.0777 69 MgOH+ 0.64926E-10 -10.1876 0.54292E-10 -10.2653 0.83620E+00 -0.0777 71 MnF+ 0.32562E-15 -15.4873 0.27228E-15 -15.5650 0.83620E+00 -0.0777 72 MnO,aq 0.17796E-08 -8.7497 0.17796E-08 -8.7497 0.10000E+01 0.0000 73 MnOH+ 0.49314E-09 -9.3070 0.41237E-09 -9.3847 0.83620E+00 -0.0777 74 MnO2-2 0.18150E-10 -10.7411 0.93782E-11 -11.0279 0.51672E+00 -0.2867 75 HMnO2- 0.19536E-09 -9.7092 0.16305E-09 -9.7877 0.83459E+00 -0.0785 78 MnCl+ 0.11813E-13 -13.9276 0.98783E-14 -14.0053 0.83620E+00 -0.0777 79 MnSO4,aq 0.57462E-14 -14.2406 0.57462E-14 -14.2406 0.10000E+01 0.0000 80 NaCl,aq 0.81465E-06 -6.0890 0.81465E-06 -6.0890 0.10000E+01 0.0000 81 NaF,aq 0.57995E-08 -8.2366 0.57995E-08 -8.2366 0.10000E+01 0.0000 82 NaOH,aq 0.89785E-04 -4.0468 0.89785E-04 -4.0468 0.10000E+01 0.0000 84 OH- 0.87395E-02 -2.0585 0.72806E-02 -2.1378 0.83307E+00 -0.0793 89 HPO3-2 0.49890E-16 -16.3020 0.25779E-16 -16.5887 0.51672E+00 -0.2867 92 H3PO4,aq 0.10350E-17 -17.9850 0.10350E-17 -17.9850 0.10000E+01 0.0000 93 H2PO4- 0.41180E-10 -10.3853 0.34401E-10 -10.4634 0.83539E+00 -0.0781 94 PO4-3 0.10018E-08 -8.9992 0.24160E-09 -9.6169 0.24117E+00 -0.6177 98 HP2O7-3 0.10162E-17 -17.9930 0.23349E-18 -18.6317 0.22975E+00 -0.6387 99 P2O7-4 0.92202E-17 -17.0353 0.70288E-18 -18.1531 0.76233E-01 -1.1179 100 H2S,aq 0.26166E-07 -7.5823 0.26074E-07 -7.5838 0.99647E+00 -0.0015 101 S2-2 0.13767E-11 -11.8612 0.71138E-12 -12.1479 0.51672E+00 -0.2867 102 S3-2 0.13738E-18 -18.8621 0.70988E-19 -19.1488 0.51672E+00 -0.2867 107 SO3-2 0.16049E-12 -12.7946 0.84135E-13 -13.0750 0.52426E+00 -0.2805 108 HSO3- 0.50090E-15 -15.3002 0.41805E-15 -15.3788 0.83459E+00 -0.0785 109 HSO4- 0.16805E-12 -12.7746 0.14066E-12 -12.8518 0.83703E+00 -0.0773 111 S2O3-2 0.10902E-14 -14.9625 0.56332E-15 -15.2492 0.51672E+00 -0.2867 Charge balance for all species = -.6132E-08 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.9450880E-10 -.2184017E-01 -.2197502E+02 0.0000 2 H2O 0.1000000E+01 0.5550430E+02 0.9981754E+06 0.0000 3 Cl- 0.1776079E-03 0.1784230E-03 0.6314551E+01 6.2713 4 SO4-- 0.3551819E-05 0.3462716E-05 0.3320514E+00 14.4655 5 HCO3- 0.1149383E-03 0.3196533E-03 0.1947019E+02 6.0830 6 HS- 0.1273594E-03 0.1274791E-03 0.4208606E+01 6.1270 7 Al+++ 0.1057500E-28 0.4405840E-05 0.1186680E+00 0.6863 8 H4SiO4 0.7411400E-03 0.1352886E-01 0.1298055E+04 -3.1301 9 Ca++ 0.8443004E-07 0.1990470E-06 0.7963435E-02 12.8383 10 Mg++ 0.2135354E-10 0.9317607E-10 0.2261329E-05 9.2392 11 Fe++ 0.3021027E-13 0.1619058E-07 0.9026119E-03 6.3904 12 K+ 0.1565410E-03 0.1572501E-03 0.6138023E+01 6.2173 13 Na+ 0.1987404E-01 0.2230363E-01 0.5118580E+03 8.3201 14 Mn++ 0.2111149E-10 0.2507393E-08 0.1375099E-03 9.2351 15 F- 0.1793513E-05 0.1799314E-05 0.3412351E-01 4.2747 16 HPO4-- 0.4537420E-07 0.4641718E-07 0.4447272E-02 12.5719 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.1961845E-01 -.1961509E-01 -.3364502E-05 0.0000000E+00 2 H2O 0.4984951E+02 0.4984951E+02 -.3276573E-05 0.0000000E+00 3 Cl- 0.1602452E-03 0.1602452E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.3112190E-05 0.3109934E-05 0.2256398E-08 0.0000000E+00 5 HCO3- 0.2870870E-03 0.2870870E-03 0.0000000E+00 0.0000000E+00 6 HS- 0.1144893E-03 0.1144915E-03 -.2256398E-08 0.0000000E+00 7 Al+++ 0.4775352E-05 0.3956973E-05 0.8183793E-06 0.0000000E+00 8 H4SiO4 0.1215302E-01 0.1215054E-01 0.2479976E-05 0.0000000E+00 9 Ca++ 0.2080835E-06 0.1787681E-06 0.2931542E-07 0.0000000E+00 10 Mg++ 0.8368328E-10 0.8368328E-10 0.0000000E+00 0.0000000E+00 11 Fe++ 0.3259227E-07 0.1454108E-07 0.1805119E-07 0.0000000E+00 12 K+ 0.1412294E-03 0.1412294E-03 0.0000000E+00 0.0000000E+00 13 Na+ 0.2003215E-01 0.2003133E-01 0.8168869E-06 0.0000000E+00 14 Mn++ 0.2251939E-08 0.2251939E-08 0.0000000E+00 0.0000000E+00 15 F- 0.1616000E-05 0.1616000E-05 0.0000000E+00 0.0000000E+00 16 HPO4-- 0.4168819E-07 0.4168819E-07 0.0000000E+00 0.0000000E+00 Chg. balance for solid moles: -.5294E-21 Mass of aqueous solution: 0.899696E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 0.0037900 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 0.8169E-06 -6.088 0.2142E-03 -3.669 97.75 0.8223E-04 andradite 0.9026E-08 -8.045 0.4587E-05 -5.339 2.093 0.1192E-05 grossular 0.7462E-09 -9.127 0.3361E-06 -6.473 0.1534 0.9353E-07 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.9236E+00 0.9236E+00 1.0000 -0.034 grossular 0.7636E-01 0.7636E-01 1.0000 -1.117 Solid products produced: Mass = 0.000219 g Volume = 0.000084 cm3 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.0037900 moles log = -2.4214 Original solution: 1000.0103000 g Original solution / Rock added: 263854.96 (Water/Rock Ratio), log = 5.4214 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0208 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9995E+00 0.9859 0.1006E+01 0.1020E+01 CO2,gas 0.1695E-05 1.0071 0.1743E-05 0.1731E-05 CH4,gas 0.7682E-05 1.0125 0.7939E-05 0.7841E-05 H2,gas 0.4525E-03 1.0005 0.4622E-03 0.4619E-03 H2S,gas 0.7050E-06 0.9960 0.7168E-06 0.7196E-06 S2,gas 0.8844E-25 1.0000 0.9028E-25 0.9028E-25 CO,gas 0.2103E-12 1.0000 0.2147E-12 0.2147E-12 SO3,gas 0.4290E-41 1.0000 0.4379E-41 0.4379E-41 SO2,gas 0.7714E-22 1.0000 0.7874E-22 0.7874E-22 HF,gas 0.1952E-14 1.0000 0.1992E-14 0.1992E-14 HCl,gas 0.3726E-17 1.0000 0.3804E-17 0.3804E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 17 albite -0.38 -0.38 0.00 0.000 -0.94784E-12 23 andradite 39.01 39.01 0.00 0.000 -0.24265E-10 24 grossular 32.73 32.73 0.00 0.000 0.12132E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -14.12 -7.46 -2.486 0.12734E+05 -5.759 3 CH4,gas 4.54 -2.26 -6.80 -1.700 0.11609E+05 -5.100 4 H2,gas 8.00 2.97 -5.03 -2.877 0.85957E+04 -3.335 5 H2S,gas -6.23 -14.07 -7.84 -3.922 0.13393E+05 -6.145 6 S2,gas -7.34 -34.08 -26.74 -4.114 0.45664E+05 -25.044 7 CO,gas 3.21 -11.15 -14.37 -4.421 0.24532E+05 -12.668 8 SO3,gas 17.12 -25.94 -43.06 -10.764 0.73520E+05 -41.359 9 SO2,gas 0.83 -22.97 -23.80 -6.347 0.40643E+05 -22.104 10 HF,gas 0.47 -15.93 -16.40 -8.200 0.28002E+05 -14.701 11 HCl,gas 5.19 -13.93 -19.12 -9.559 0.32645E+05 -17.420 12 acmite 7.71 6.97 -0.74 -0.077 0.12673E+04 16 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 20 spessartine 24.46 19.69 -4.77 -0.238 0.81439E+04 21 analcite 3.32 2.75 -0.58 -0.064 0.98287E+03 27 annite 20.12 16.68 -3.44 -0.191 0.58718E+04 28 phlogopite 27.06 25.23 -1.83 -0.102 0.31308E+04 30 anorthite 12.71 7.95 -4.76 -0.366 0.81268E+04 33 apatite-OH -18.15 -19.30 -1.14 -0.088 0.19541E+04 34 apatite-F -34.30 -35.22 -0.92 -0.077 0.15761E+04 38 aragonite 0.97 -1.28 -2.25 -0.749 0.38351E+04 39 brucite 12.57 9.24 -3.33 -0.666 0.56847E+04 40 calcite 0.81 -1.28 -2.09 -0.697 0.35709E+04 41 carnegieite-low 9.02 5.88 -3.15 -0.450 0.53734E+04 42 carnegieite-high 10.09 5.88 -4.22 -0.602 0.72004E+04 43 carpholite-Mg 8.58 4.35 -4.23 -0.282 0.72232E+04 45 celadonite 5.34 3.62 -1.72 -0.101 0.29354E+04 46 celadonite-Fe 3.88 0.77 -3.10 -0.183 0.52982E+04 47 chrysotile 23.89 21.46 -2.43 -0.203 0.41575E+04 49 clinochlore 39.07 38.18 -0.89 -0.028 0.15212E+04 52 chlorite-Al-free 47.17 42.92 -4.26 -0.177 0.72701E+04 54 chloritoid-Fe 9.17 4.63 -4.54 -0.303 0.77530E+04 55 chloritoid-Mn 11.40 7.48 -3.92 -0.262 0.66990E+04 57 coesite -2.38 -3.13 -0.75 -0.251 0.12875E+04 64 cristobalite -2.56 -3.13 -0.57 -0.190 0.97285E+03 66 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71237E+04 68 diaspore 2.87 0.69 -2.19 -0.365 0.37349E+04 70 diopside 16.18 15.82 -0.36 -0.036 0.62159E+03 71 hedenbergite 14.21 12.97 -1.24 -0.124 0.21169E+04 76 clinoenstatite 17.17 12.22 -4.95 -0.495 0.84486E+04 78 epidote 24.67 22.57 -2.10 -0.102 0.35915E+04 79 clinozoisite 22.81 18.35 -4.46 -0.203 0.76166E+04 80 epidote-Fe 29.84 26.79 -3.05 -0.159 0.52129E+04 81 fayalite 14.05 9.65 -4.40 -0.628 0.75044E+04 82 ferrosilite 11.15 6.52 -4.63 -0.463 0.79036E+04 86 gibbsite 4.08 0.69 -3.39 -0.485 0.57934E+04 87 glaucophane 22.97 20.69 -2.29 -0.062 0.39016E+04 89 graphite -3.55 -8.19 -4.64 -1.326 0.79235E+04 90 greenalite 16.14 12.91 -3.23 -0.269 0.55126E+04 93 hematite 12.57 9.82 -2.75 -0.333 0.46972E+04 94 heulandite -5.83 -7.70 -1.87 -0.085 0.31972E+04 98 jadeite 4.22 2.75 -1.47 -0.147 0.25084E+04 100 kalsilite 7.58 3.77 -3.81 -0.544 0.65062E+04 101 kaolinite -1.33 -4.89 -3.55 -0.323 0.60696E+04 104 laumontite 2.88 1.69 -1.19 -0.080 0.20368E+04 105 lawsonite 9.62 7.95 -1.67 -0.111 0.28435E+04 106 leucite 4.12 0.64 -3.48 -0.348 0.59343E+04 108 lizardite 23.24 21.46 -1.79 -0.149 0.30501E+04 110 magnetite 20.09 16.21 -3.88 -0.317 0.66280E+04 111 minnesotaite 10.39 6.65 -3.74 -0.220 0.63813E+04 115 manganosite 14.06 9.24 -4.82 -1.206 0.82351E+04 119 microcline -2.49 -2.49 0.00 0.000 0.35314E+00 123 muscovite 2.58 -1.11 -3.70 -0.217 0.63116E+04 124 paragonite 4.24 0.99 -3.25 -0.191 0.55503E+04 125 nepheline 8.34 5.88 -2.46 -0.352 0.42057E+04 137 phlogopite-Na 29.65 27.33 -2.31 -0.128 0.39492E+04 139 prehnite 19.37 17.66 -1.71 -0.101 0.29248E+04 140 prehnite-Fe 22.50 21.88 -0.62 -0.037 0.10546E+04 141 pumpellyite-Fe 46.27 42.39 -3.87 -0.086 0.66161E+04 142 pumpellyite-Mg 48.99 45.24 -3.75 -0.083 0.64055E+04 145 pyrite -21.25 -24.72 -3.48 -0.818 0.59351E+04 146 pyrrhotite -4.26 -7.68 -3.42 -1.141 0.58449E+04 147 pyrrhotiteFe0.875 -6.02 -8.85 -2.83 -1.042 0.48373E+04 148 pyroxmangite 7.40 6.11 -1.29 -0.259 0.22089E+04 149 pyrophyllite -6.18 -11.15 -4.97 -0.311 0.84894E+04 150 quartz -2.99 -3.13 -0.14 -0.047 0.24018E+03 154 rhodochrosite -0.98 -4.88 -3.91 -1.302 0.66700E+04 155 rhodonite 7.45 6.11 -1.34 -0.268 0.22891E+04 156 sanidine -1.28 -2.49 -1.21 -0.093 0.20681E+04 166 stilbite -7.52 -7.70 -0.18 -0.008 0.30340E+03 167 stilpnomelane-Fe 13.02 11.39 -1.62 -0.048 0.27737E+04 168 stilpnomelane-Mg 27.44 25.64 -1.80 -0.054 0.30815E+04 174 talc 16.49 15.20 -1.29 -0.076 0.22090E+04 177 tephroite 18.09 15.34 -2.75 -0.392 0.46881E+04 181 tridymite -2.63 -3.13 -0.50 -0.168 0.86016E+03 182 tremolite 47.87 46.83 -1.04 -0.028 0.17712E+04 184 troilite-low -4.41 -7.68 -3.27 -1.091 0.55877E+04 190 wairakite 3.95 1.69 -2.26 -0.133 0.38587E+04 191 walstromite 11.51 9.71 -1.80 -0.360 0.30752E+04 192 wollastonite 10.46 9.71 -0.75 -0.151 0.12857E+04 193 pseudo-wollastonite 11.00 9.71 -1.29 -0.258 0.22055E+04 194 zoisite 22.85 18.35 -4.50 -0.205 0.76907E+04 195 akaganeite 7.75 4.91 -2.85 -0.616 0.48611E+04 202 chalcedony -2.80 -3.13 -0.33 -0.109 0.55948E+03 204 montmorillonite-Ca -2.29 -6.21 -3.92 -0.242 0.66869E+04 205 montmorillonite-K -2.24 -6.27 -4.04 -0.247 0.68928E+04 206 montmorillonite-Mg -2.48 -6.80 -4.32 -0.267 0.73778E+04 207 montmorillonite-Na -2.04 -5.58 -3.54 -0.217 0.60476E+04 208 nontronite-Ca 3.21 0.67 -2.54 -0.165 0.43404E+04 209 nontronite-H 2.53 -1.45 -3.98 -0.267 0.67931E+04 210 nontronite-K 3.34 0.61 -2.73 -0.176 0.46695E+04 211 nontronite-Mg 3.07 0.08 -3.00 -0.194 0.51154E+04 212 nontronite-Na 3.52 1.30 -2.22 -0.142 0.37903E+04 228 tobermorite 9.82 7.56 -2.26 -0.616 0.38570E+04 234 alabandite -0.98 -4.84 -3.86 -1.287 0.65923E+04 237 boehmite 4.41 0.69 -3.72 -0.620 0.63518E+04 239 ferrous-oxide 9.81 6.39 -3.42 -0.855 0.58416E+04 245 silica-amorphous -2.09 -3.13 -1.04 -0.346 0.17737E+04 247 an20ab80 2.02 1.28 -0.73 -0.057 0.12545E+04 248 an25ab75 2.65 1.70 -0.95 -0.073 0.16151E+04 249 an30ab70 3.28 2.12 -1.16 -0.089 0.19853E+04 250 tr.625ac.25prg.125 45.16 44.20 -0.97 -0.026 0.16542E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 0.0001000 MOLES Current total amount of reactant added: 0.0037900 MOLES New total amount of reactant added: 0.0038900 MOLES Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.5508E-08 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 7 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 0.0038900 Water: Moles liquid = 0.4985E+02 kg liquid = 0.8981E+00 Moles total = 0.4985E+02 kg total = 0.8981E+00 Activity = 1.0000 Stoichiometric ionic strength = .1157862E-01 Osmotic coef. = 0.9587 True ionic strength = .2024506E-01 Chg. balance for total moles = -.5508E-08 Max. difference allowed = 0.1608E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.94681E-10 -10.0237 0.79501E-10 -10.0996 0.83967E+00 -0.0759 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.17826E-03 -3.7489 0.14877E-03 -3.8275 0.83458E+00 -0.0785 4 SO4-- 0.40796E-05 -5.3894 0.21124E-05 -5.6752 0.51779E+00 -0.2858 5 HCO3- 0.11796E-03 -3.9282 0.98596E-04 -4.0061 0.83581E+00 -0.0779 6 HS- 0.12954E-03 -3.8876 0.10812E-03 -3.9661 0.83470E+00 -0.0785 7 Al+++ 0.10600E-28 -28.9747 0.24324E-29 -29.6140 0.22948E+00 -0.6393 8 H4SiO4 0.74239E-03 -3.1294 0.74239E-03 -3.1294 0.10000E+01 0.0000 9 Ca++ 0.83870E-07 -7.0764 0.43105E-07 -7.3655 0.51395E+00 -0.2891 10 Mg++ 0.21361E-10 -10.6704 0.10928E-10 -10.9615 0.51158E+00 -0.2911 11 Fe++ 0.30288E-13 -13.5187 0.15512E-13 -13.8093 0.51214E+00 -0.2906 12 K+ 0.15654E-03 -3.8054 0.13087E-03 -3.8832 0.83601E+00 -0.0778 13 Na+ 0.19874E-01 -1.7017 0.16584E-01 -1.7803 0.83442E+00 -0.0786 14 Mn++ 0.21185E-10 -10.6740 0.10859E-10 -10.9642 0.51257E+00 -0.2902 15 F- 0.18379E-05 -5.7357 0.15307E-05 -5.8151 0.83284E+00 -0.0794 16 HPO4-- 0.45376E-07 -7.3432 0.23498E-07 -7.6290 0.51786E+00 -0.2858 18 HSiO3- 0.10448E-01 -1.9810 0.87194E-02 -2.0595 0.83458E+00 -0.0785 19 Ca(HSiO3)+ 0.10236E-07 -7.9899 0.85595E-08 -8.0676 0.83619E+00 -0.0777 20 Mg(HSiO3)+ 0.32296E-11 -11.4909 0.27005E-11 -11.5685 0.83619E+00 -0.0777 21 NaHSiO3,aq 0.23387E-02 -2.6310 0.23387E-02 -2.6310 0.10000E+01 0.0000 22 AlO+ 0.62614E-16 -16.2033 0.52358E-16 -16.2810 0.83619E+00 -0.0777 24 HAlO2,aq 0.13115E-09 -9.8822 0.13115E-09 -9.8822 0.10000E+01 0.0000 25 AlO2- 0.43836E-05 -5.3582 0.36518E-05 -5.4375 0.83306E+00 -0.0793 26 CH4,aq 0.49196E-08 -8.3081 0.49023E-08 -8.3096 0.99647E+00 -0.0015 27 C2H6,aq 0.12079E-19 -19.9180 0.12036E-19 -19.9195 0.99647E+00 -0.0015 31 CO,aq 0.14361E-15 -15.8428 0.14361E-15 -15.8428 0.10000E+01 0.0000 32 CO2,aq 0.16808E-07 -7.7745 0.16749E-07 -7.7760 0.99647E+00 -0.0015 33 CO3-2 0.20966E-03 -3.6785 0.10833E-03 -3.9653 0.51668E+00 -0.2868 34 CaCO3,aq 0.58549E-07 -7.2325 0.58549E-07 -7.2325 0.10000E+01 0.0000 35 Ca(HCO3)+ 0.12974E-09 -9.8869 0.10849E-09 -9.9646 0.83619E+00 -0.0777 36 CaCl+ 0.12411E-10 -10.9062 0.10378E-10 -10.9839 0.83619E+00 -0.0777 37 CaCl2,aq 0.36681E-15 -15.4356 0.36681E-15 -15.4356 0.10000E+01 0.0000 38 CaF+ 0.11520E-11 -11.9385 0.96332E-12 -12.0162 0.83619E+00 -0.0777 39 CaOH+ 0.46212E-07 -7.3352 0.38642E-07 -7.4129 0.83619E+00 -0.0777 40 CaSO4,aq 0.28914E-10 -10.5389 0.28914E-10 -10.5389 0.10000E+01 0.0000 41 HCl,aq 0.21673E-14 -14.6641 0.21673E-14 -14.6641 0.10000E+01 0.0000 45 HF,aq 0.83306E-12 -12.0793 0.83306E-12 -12.0793 0.10000E+01 0.0000 46 HF2- 0.51586E-18 -18.2875 0.43052E-18 -18.3660 0.83458E+00 -0.0785 48 FeCl+ 0.43684E-17 -17.3597 0.36528E-17 -17.4374 0.83619E+00 -0.0777 51 FeF+ 0.14510E-17 -17.8383 0.12133E-17 -17.9160 0.83619E+00 -0.0777 53 FeO,aq 0.95387E-10 -10.0205 0.95387E-10 -10.0205 0.10000E+01 0.0000 54 FeOH+ 0.75955E-11 -11.1194 0.63512E-11 -11.1971 0.83619E+00 -0.0777 55 HFeO2- 0.15042E-07 -7.8227 0.12554E-07 -7.9012 0.83458E+00 -0.0785 56 FeO+ 0.31009E-16 -16.5085 0.25930E-16 -16.5862 0.83619E+00 -0.0777 58 FeO2- 0.10059E-08 -8.9975 0.83947E-09 -9.0760 0.83458E+00 -0.0785 59 HFeO2,aq 0.84881E-11 -11.0712 0.84881E-11 -11.0712 0.10000E+01 0.0000 60 H2,aq 0.34254E-06 -6.4653 0.34133E-06 -6.4668 0.99647E+00 -0.0015 61 KCl,aq 0.35288E-09 -9.4524 0.35288E-09 -9.4524 0.10000E+01 0.0000 62 KHSO4,aq 0.62139E-19 -19.2066 0.62139E-19 -19.2066 0.10000E+01 0.0000 63 KOH,aq 0.70300E-06 -6.1530 0.70300E-06 -6.1530 0.10000E+01 0.0000 64 KSO4- 0.51401E-08 -8.2890 0.42898E-08 -8.3676 0.83458E+00 -0.0785 65 MgCO3,aq 0.37205E-11 -11.4294 0.37205E-11 -11.4294 0.10000E+01 0.0000 66 Mg(HCO3)+ 0.33608E-13 -13.4736 0.28102E-13 -13.5513 0.83619E+00 -0.0777 67 MgCl+ 0.28517E-14 -14.5449 0.23846E-14 -14.6226 0.83619E+00 -0.0777 68 MgF+ 0.10819E-14 -14.9658 0.90465E-15 -15.0435 0.83619E+00 -0.0777 69 MgOH+ 0.64827E-10 -10.1882 0.54208E-10 -10.2659 0.83619E+00 -0.0777 71 MnF+ 0.33480E-15 -15.4752 0.27996E-15 -15.5529 0.83619E+00 -0.0777 72 MnO,aq 0.17792E-08 -8.7498 0.17792E-08 -8.7498 0.10000E+01 0.0000 73 MnOH+ 0.49393E-09 -9.3063 0.41302E-09 -9.3840 0.83619E+00 -0.0777 74 MnO2-2 0.18082E-10 -10.7428 0.93423E-11 -11.0295 0.51668E+00 -0.2868 75 HMnO2- 0.19497E-09 -9.7100 0.16272E-09 -9.7886 0.83458E+00 -0.0785 78 MnCl+ 0.11897E-13 -13.9246 0.99479E-14 -14.0023 0.83619E+00 -0.0777 79 MnSO4,aq 0.66219E-14 -14.1790 0.66219E-14 -14.1790 0.10000E+01 0.0000 80 NaCl,aq 0.81764E-06 -6.0874 0.81764E-06 -6.0874 0.10000E+01 0.0000 81 NaF,aq 0.59429E-08 -8.2260 0.59429E-08 -8.2260 0.10000E+01 0.0000 82 NaOH,aq 0.89624E-04 -4.0476 0.89624E-04 -4.0476 0.10000E+01 0.0000 84 OH- 0.87239E-02 -2.0593 0.72675E-02 -2.1386 0.83306E+00 -0.0793 89 HPO3-2 0.48377E-16 -16.3154 0.24995E-16 -16.6021 0.51668E+00 -0.2868 92 H3PO4,aq 0.10387E-17 -17.9835 0.10387E-17 -17.9835 0.10000E+01 0.0000 93 H2PO4- 0.41253E-10 -10.3845 0.34462E-10 -10.4627 0.83537E+00 -0.0781 94 PO4-3 0.10001E-08 -8.9999 0.24116E-09 -9.6177 0.24113E+00 -0.6178 98 HP2O7-3 0.10182E-17 -17.9922 0.23389E-18 -18.6310 0.22971E+00 -0.6388 99 P2O7-4 0.92222E-17 -17.0352 0.70282E-18 -18.1532 0.76210E-01 -1.1180 100 H2S,aq 0.26661E-07 -7.5741 0.26567E-07 -7.5757 0.99647E+00 -0.0015 101 S2-2 0.14688E-11 -11.8330 0.75892E-12 -12.1198 0.51668E+00 -0.2868 102 S3-2 0.15402E-18 -18.8124 0.79580E-19 -19.0992 0.51668E+00 -0.2868 107 SO3-2 0.17874E-12 -12.7478 0.93697E-13 -13.0283 0.52422E+00 -0.2805 108 HSO3- 0.55884E-15 -15.2527 0.46640E-15 -15.3312 0.83458E+00 -0.0785 109 HSO4- 0.19336E-12 -12.7136 0.16184E-12 -12.7909 0.83701E+00 -0.0773 111 S2O3-2 0.12759E-14 -14.8942 0.65922E-15 -15.1810 0.51668E+00 -0.2868 Charge balance for all species = -.6132E-08 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.9468082E-10 -.2182805E-01 -.2196282E+02 0.0000 2 H2O 0.1000000E+01 0.5550429E+02 0.9981748E+06 0.0000 3 Cl- 0.1782615E-03 0.1790795E-03 0.6337786E+01 6.2722 4 SO4-- 0.4079629E-05 0.3994370E-05 0.3830335E+00 14.5240 5 HCO3- 0.1179646E-03 0.3277029E-03 0.1996048E+02 6.0935 6 HS- 0.1295358E-03 0.1296529E-03 0.4280369E+01 6.1335 7 Al+++ 0.1059975E-28 0.4383779E-05 0.1180737E+00 0.6849 8 H4SiO4 0.7423863E-03 0.1352877E-01 0.1298045E+04 -3.1294 9 Ca++ 0.8387007E-07 0.1990398E-06 0.7963143E-02 12.8338 10 Mg++ 0.2136080E-10 0.9317590E-10 0.2261324E-05 9.2378 11 Fe++ 0.3028806E-13 0.1615960E-07 0.9008841E-03 6.3899 12 K+ 0.1565413E-03 0.1572498E-03 0.6138009E+01 6.2165 13 Na+ 0.1987442E-01 0.2230357E-01 0.5118563E+03 8.3193 14 Mn++ 0.2118451E-10 0.2507388E-08 0.1375096E-03 9.2350 15 F- 0.1837903E-05 0.1843848E-05 0.3496807E-01 4.2845 16 HPO4-- 0.4537572E-07 0.4641709E-07 0.4447262E-02 12.5703 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.1960768E-01 -.1960424E-01 -.3443816E-05 0.0000000E+00 2 H2O 0.4984959E+02 0.4984960E+02 -.3355908E-05 0.0000000E+00 3 Cl- 0.1608352E-03 0.1608352E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.3589690E-05 0.3587430E-05 0.2259874E-08 0.0000000E+00 5 HCO3- 0.2943170E-03 0.2943170E-03 0.0000000E+00 0.0000000E+00 6 HS- 0.1164418E-03 0.1164440E-03 -.2259874E-08 0.0000000E+00 7 Al+++ 0.4775352E-05 0.3937166E-05 0.8381858E-06 0.0000000E+00 8 H4SiO4 0.1215302E-01 0.1215048E-01 0.2539473E-05 0.0000000E+00 9 Ca++ 0.2080835E-06 0.1787619E-06 0.2932157E-07 0.0000000E+00 10 Mg++ 0.8368328E-10 0.8368328E-10 0.0000000E+00 0.0000000E+00 11 Fe++ 0.3259227E-07 0.1451328E-07 0.1807899E-07 0.0000000E+00 12 K+ 0.1412294E-03 0.1412294E-03 0.0000000E+00 0.0000000E+00 13 Na+ 0.2003215E-01 0.2003131E-01 0.8367170E-06 0.0000000E+00 14 Mn++ 0.2251939E-08 0.2251939E-08 0.0000000E+00 0.0000000E+00 15 F- 0.1656000E-05 0.1656000E-05 0.0000000E+00 0.0000000E+00 16 HPO4-- 0.4168819E-07 0.4168819E-07 0.0000000E+00 0.0000000E+00 Chg. balance for solid moles: 0.1059E-21 Mass of aqueous solution: 0.899698E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 0.0038900 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 0.8367E-06 -6.077 0.2194E-03 -3.659 97.80 0.8422E-04 andradite 0.9039E-08 -8.044 0.4594E-05 -5.338 2.048 0.1193E-05 grossular 0.7344E-09 -9.134 0.3308E-06 -6.480 0.1475 0.9204E-07 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.9249E+00 0.9249E+00 1.0000 -0.034 grossular 0.7514E-01 0.7514E-01 1.0000 -1.124 Solid products produced: Mass = 0.000224 g Volume = 0.000086 cm3 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.0038900 moles log = -2.4101 Original solution: 1000.0103000 g Original solution / Rock added: 257072.06 (Water/Rock Ratio), log = 5.4101 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0208 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9996E+00 0.9859 0.1006E+01 0.1020E+01 CO2,gas 0.1743E-05 1.0071 0.1792E-05 0.1779E-05 CH4,gas 0.6982E-05 1.0125 0.7216E-05 0.7126E-05 H2,gas 0.4388E-03 1.0005 0.4481E-03 0.4479E-03 H2S,gas 0.7183E-06 0.9960 0.7303E-06 0.7332E-06 S2,gas 0.9766E-25 1.0000 0.9969E-25 0.9969E-25 CO,gas 0.2097E-12 1.0000 0.2140E-12 0.2140E-12 SO3,gas 0.4945E-41 1.0000 0.5048E-41 0.5048E-41 SO2,gas 0.8622E-22 1.0000 0.8801E-22 0.8801E-22 HF,gas 0.2004E-14 1.0000 0.2045E-14 0.2045E-14 HCl,gas 0.3747E-17 1.0000 0.3824E-17 0.3824E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 17 albite -0.38 -0.38 0.00 0.000 -0.94784E-12 23 andradite 39.01 39.01 0.00 0.000 -0.12132E-10 24 grossular 32.73 32.73 0.00 0.000 0.00000E+00 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -14.11 -7.45 -2.482 0.12713E+05 -5.747 3 CH4,gas 4.54 -2.30 -6.84 -1.710 0.11680E+05 -5.142 4 H2,gas 8.00 2.95 -5.05 -2.884 0.86186E+04 -3.349 5 H2S,gas -6.23 -14.07 -7.84 -3.918 0.13379E+05 -6.136 6 S2,gas -7.34 -34.04 -26.70 -4.108 0.45590E+05 -25.001 7 CO,gas 3.21 -11.15 -14.37 -4.421 0.24534E+05 -12.670 8 SO3,gas 17.12 -25.87 -43.00 -10.749 0.73414E+05 -41.297 9 SO2,gas 0.83 -22.92 -23.75 -6.335 0.40560E+05 -22.055 10 HF,gas 0.47 -15.91 -16.39 -8.194 0.27982E+05 -14.689 11 HCl,gas 5.19 -13.93 -19.12 -9.558 0.32641E+05 -17.417 12 acmite 7.71 6.97 -0.74 -0.076 0.12555E+04 16 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 20 spessartine 24.46 19.69 -4.77 -0.239 0.81455E+04 21 analcite 3.32 2.75 -0.58 -0.064 0.98412E+03 27 annite 20.12 16.68 -3.44 -0.191 0.58743E+04 28 phlogopite 27.06 25.23 -1.84 -0.102 0.31382E+04 30 anorthite 12.71 7.94 -4.77 -0.367 0.81368E+04 33 apatite-OH -18.15 -19.32 -1.16 -0.089 0.19845E+04 34 apatite-F -34.30 -35.23 -0.93 -0.077 0.15871E+04 38 aragonite 0.97 -1.27 -2.24 -0.746 0.38222E+04 39 brucite 12.57 9.24 -3.33 -0.666 0.56872E+04 40 calcite 0.81 -1.27 -2.08 -0.695 0.35580E+04 41 carnegieite-low 9.02 5.87 -3.15 -0.450 0.53758E+04 42 carnegieite-high 10.09 5.87 -4.22 -0.603 0.72028E+04 43 carpholite-Mg 8.58 4.35 -4.23 -0.282 0.72280E+04 45 celadonite 5.34 3.62 -1.72 -0.101 0.29367E+04 46 celadonite-Fe 3.88 0.77 -3.10 -0.183 0.52977E+04 47 chrysotile 23.89 21.45 -2.44 -0.203 0.41624E+04 49 clinochlore 39.07 38.17 -0.90 -0.028 0.15347E+04 52 chlorite-Al-free 47.17 42.91 -4.26 -0.178 0.72800E+04 54 chloritoid-Fe 9.17 4.63 -4.54 -0.303 0.77574E+04 55 chloritoid-Mn 11.40 7.48 -3.93 -0.262 0.67028E+04 57 coesite -2.38 -3.13 -0.75 -0.251 0.12863E+04 64 cristobalite -2.56 -3.13 -0.57 -0.190 0.97161E+03 66 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71237E+04 68 diaspore 2.87 0.68 -2.19 -0.365 0.37373E+04 70 diopside 16.18 15.81 -0.37 -0.037 0.62924E+03 71 hedenbergite 14.21 12.96 -1.24 -0.124 0.21229E+04 76 clinoenstatite 17.17 12.22 -4.95 -0.495 0.84510E+04 78 epidote 24.67 22.56 -2.11 -0.102 0.35972E+04 79 clinozoisite 22.81 18.33 -4.47 -0.203 0.76354E+04 80 epidote-Fe 29.84 26.79 -3.05 -0.158 0.52057E+04 81 fayalite 14.05 9.65 -4.40 -0.628 0.75048E+04 82 ferrosilite 11.15 6.52 -4.63 -0.463 0.79028E+04 86 gibbsite 4.08 0.68 -3.39 -0.485 0.57958E+04 87 glaucophane 22.97 20.69 -2.29 -0.062 0.39065E+04 89 graphite -3.55 -8.20 -4.66 -1.330 0.79486E+04 90 greenalite 16.14 12.91 -3.23 -0.269 0.55125E+04 93 hematite 12.57 9.83 -2.74 -0.332 0.46760E+04 94 heulandite -5.83 -7.70 -1.87 -0.085 0.32010E+04 98 jadeite 4.22 2.75 -1.47 -0.147 0.25096E+04 100 kalsilite 7.58 3.77 -3.81 -0.545 0.65087E+04 101 kaolinite -1.33 -4.89 -3.56 -0.323 0.60720E+04 104 laumontite 2.88 1.69 -1.20 -0.080 0.20443E+04 105 lawsonite 9.62 7.94 -1.67 -0.111 0.28535E+04 106 leucite 4.12 0.64 -3.48 -0.348 0.59355E+04 108 lizardite 23.24 21.45 -1.79 -0.149 0.30550E+04 110 magnetite 20.09 16.22 -3.87 -0.316 0.66076E+04 111 minnesotaite 10.39 6.65 -3.74 -0.220 0.63788E+04 115 manganosite 14.06 9.24 -4.82 -1.206 0.82353E+04 119 microcline -2.49 -2.49 0.00 0.000 0.36539E+00 123 muscovite 2.58 -1.12 -3.70 -0.218 0.63164E+04 124 paragonite 4.24 0.99 -3.25 -0.191 0.55551E+04 125 nepheline 8.34 5.87 -2.46 -0.352 0.42082E+04 137 phlogopite-Na 29.65 27.33 -2.32 -0.129 0.39567E+04 139 prehnite 19.37 17.65 -1.72 -0.101 0.29412E+04 140 prehnite-Fe 22.50 21.88 -0.62 -0.037 0.10580E+04 141 pumpellyite-Fe 46.27 42.37 -3.90 -0.087 0.66522E+04 142 pumpellyite-Mg 48.99 45.22 -3.77 -0.084 0.64431E+04 145 pyrite -21.25 -24.69 -3.45 -0.811 0.58852E+04 146 pyrrhotite -4.26 -7.68 -3.42 -1.138 0.58318E+04 147 pyrrhotiteFe0.875 -6.02 -8.84 -2.82 -1.038 0.48213E+04 148 pyroxmangite 7.40 6.11 -1.29 -0.259 0.22078E+04 149 pyrophyllite -6.18 -11.15 -4.97 -0.311 0.84892E+04 150 quartz -2.99 -3.13 -0.14 -0.047 0.23894E+03 154 rhodochrosite -0.98 -4.87 -3.89 -1.298 0.66496E+04 155 rhodonite 7.45 6.11 -1.34 -0.268 0.22880E+04 156 sanidine -1.28 -2.49 -1.21 -0.093 0.20681E+04 166 stilbite -7.52 -7.70 -0.18 -0.009 0.30715E+03 167 stilpnomelane-Fe 13.02 11.39 -1.62 -0.048 0.27733E+04 168 stilpnomelane-Mg 27.44 25.63 -1.81 -0.054 0.30894E+04 174 talc 16.49 15.20 -1.30 -0.076 0.22115E+04 177 tephroite 18.09 15.34 -2.75 -0.392 0.46872E+04 181 tridymite -2.63 -3.13 -0.50 -0.168 0.85891E+03 182 tremolite 47.87 46.82 -1.05 -0.028 0.17889E+04 184 troilite-low -4.41 -7.68 -3.26 -1.088 0.55746E+04 190 wairakite 3.95 1.69 -2.26 -0.133 0.38662E+04 191 walstromite 11.51 9.70 -1.80 -0.361 0.30817E+04 192 wollastonite 10.46 9.70 -0.76 -0.151 0.12921E+04 193 pseudo-wollastonite 11.00 9.70 -1.30 -0.259 0.22119E+04 194 zoisite 22.85 18.33 -4.52 -0.205 0.77095E+04 195 akaganeite 7.75 4.91 -2.84 -0.614 0.48505E+04 202 chalcedony -2.80 -3.13 -0.33 -0.109 0.55823E+03 204 montmorillonite-Ca -2.29 -6.21 -3.92 -0.242 0.66880E+04 205 montmorillonite-K -2.24 -6.27 -4.04 -0.247 0.68931E+04 206 montmorillonite-Mg -2.48 -6.80 -4.32 -0.267 0.73781E+04 207 montmorillonite-Na -2.04 -5.58 -3.54 -0.217 0.60479E+04 208 nontronite-Ca 3.21 0.69 -2.53 -0.164 0.43166E+04 209 nontronite-H 2.53 -1.43 -3.96 -0.266 0.67681E+04 210 nontronite-K 3.34 0.62 -2.72 -0.175 0.46450E+04 211 nontronite-Mg 3.07 0.09 -2.98 -0.193 0.50908E+04 212 nontronite-Na 3.52 1.31 -2.21 -0.142 0.37657E+04 228 tobermorite 9.82 7.56 -2.26 -0.617 0.38621E+04 234 alabandite -0.98 -4.83 -3.85 -1.284 0.65786E+04 237 boehmite 4.41 0.68 -3.72 -0.620 0.63542E+04 239 ferrous-oxide 9.81 6.39 -3.42 -0.855 0.58424E+04 245 silica-amorphous -2.09 -3.13 -1.04 -0.346 0.17724E+04 247 an20ab80 2.02 1.28 -0.74 -0.057 0.12565E+04 248 an25ab75 2.65 1.70 -0.95 -0.073 0.16176E+04 249 an30ab70 3.28 2.11 -1.16 -0.090 0.19883E+04 250 tr.625ac.25prg.125 45.16 44.19 -0.98 -0.026 0.16710E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 0.0001000 MOLES Current total amount of reactant added: 0.0038900 MOLES New total amount of reactant added: 0.0039900 MOLES Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.5508E-08 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 7 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 0.0039900 Water: Moles liquid = 0.4985E+02 kg liquid = 0.8981E+00 Moles total = 0.4985E+02 kg total = 0.8981E+00 Activity = 1.0000 Stoichiometric ionic strength = .1158502E-01 Osmotic coef. = 0.9583 True ionic strength = .2025098E-01 Chg. balance for total moles = -.5508E-08 Max. difference allowed = 0.1614E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.94853E-10 -10.0229 0.79644E-10 -10.0988 0.83965E+00 -0.0759 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.17892E-03 -3.7474 0.14932E-03 -3.8259 0.83456E+00 -0.0785 4 SO4-- 0.46080E-05 -5.3365 0.23858E-05 -5.6224 0.51775E+00 -0.2859 5 HCO3- 0.12100E-03 -3.9172 0.10113E-03 -3.9951 0.83579E+00 -0.0779 6 HS- 0.13171E-03 -3.8804 0.10994E-03 -3.9589 0.83468E+00 -0.0785 7 Al+++ 0.10625E-28 -28.9737 0.24377E-29 -29.6130 0.22944E+00 -0.6393 8 H4SiO4 0.74364E-03 -3.1286 0.74364E-03 -3.1286 0.10000E+01 0.0000 9 Ca++ 0.83334E-07 -7.0792 0.42826E-07 -7.3683 0.51391E+00 -0.2891 10 Mg++ 0.21368E-10 -10.6702 0.10931E-10 -10.9614 0.51154E+00 -0.2911 11 Fe++ 0.30416E-13 -13.5169 0.15576E-13 -13.8075 0.51210E+00 -0.2906 12 K+ 0.15654E-03 -3.8054 0.13087E-03 -3.8832 0.83599E+00 -0.0778 13 Na+ 0.19875E-01 -1.7017 0.16584E-01 -1.7803 0.83441E+00 -0.0786 14 Mn++ 0.21258E-10 -10.6725 0.10895E-10 -10.9628 0.51253E+00 -0.2903 15 F- 0.18823E-05 -5.7253 0.15676E-05 -5.8048 0.83283E+00 -0.0794 16 HPO4-- 0.45377E-07 -7.3432 0.23497E-07 -7.6290 0.51782E+00 -0.2858 18 HSiO3- 0.10447E-01 -1.9810 0.87183E-02 -2.0596 0.83456E+00 -0.0785 19 Ca(HSiO3)+ 0.10169E-07 -7.9927 0.85032E-08 -8.0704 0.83617E+00 -0.0777 20 Mg(HSiO3)+ 0.32301E-11 -11.4908 0.27009E-11 -11.5685 0.83617E+00 -0.0777 21 NaHSiO3,aq 0.23384E-02 -2.6311 0.23384E-02 -2.6311 0.10000E+01 0.0000 22 AlO+ 0.62526E-16 -16.2039 0.52282E-16 -16.2816 0.83617E+00 -0.0777 24 HAlO2,aq 0.13073E-09 -9.8836 0.13073E-09 -9.8836 0.10000E+01 0.0000 25 AlO2- 0.43617E-05 -5.3603 0.36334E-05 -5.4397 0.83304E+00 -0.0793 26 CH4,aq 0.45427E-08 -8.3427 0.45267E-08 -8.3442 0.99647E+00 -0.0015 27 C2H6,aq 0.10578E-19 -19.9756 0.10541E-19 -19.9771 0.99647E+00 -0.0015 31 CO,aq 0.14368E-15 -15.8426 0.14368E-15 -15.8426 0.10000E+01 0.0000 32 CO2,aq 0.17271E-07 -7.7627 0.17210E-07 -7.7642 0.99647E+00 -0.0015 33 CO3-2 0.21467E-03 -3.6682 0.11091E-03 -3.9550 0.51664E+00 -0.2868 34 CaCO3,aq 0.59557E-07 -7.2251 0.59557E-07 -7.2251 0.10000E+01 0.0000 35 Ca(HCO3)+ 0.13221E-09 -9.8787 0.11055E-09 -9.9564 0.83617E+00 -0.0777 36 CaCl+ 0.12376E-10 -10.9074 0.10349E-10 -10.9851 0.83617E+00 -0.0777 37 CaCl2,aq 0.36711E-15 -15.4352 0.36711E-15 -15.4352 0.10000E+01 0.0000 38 CaF+ 0.11722E-11 -11.9310 0.98019E-12 -12.0087 0.83617E+00 -0.0777 39 CaOH+ 0.45832E-07 -7.3388 0.38323E-07 -7.4165 0.83617E+00 -0.0777 40 CaSO4,aq 0.32445E-10 -10.4889 0.32445E-10 -10.4889 0.10000E+01 0.0000 41 HCl,aq 0.21792E-14 -14.6617 0.21792E-14 -14.6617 0.10000E+01 0.0000 45 HF,aq 0.85470E-12 -12.0682 0.85470E-12 -12.0682 0.10000E+01 0.0000 46 HF2- 0.54204E-18 -18.2660 0.45236E-18 -18.3445 0.83456E+00 -0.0785 48 FeCl+ 0.44025E-17 -17.3563 0.36813E-17 -17.4340 0.83617E+00 -0.0777 51 FeF+ 0.14922E-17 -17.8262 0.12478E-17 -17.9039 0.83617E+00 -0.0777 53 FeO,aq 0.95437E-10 -10.0203 0.95437E-10 -10.0203 0.10000E+01 0.0000 54 FeOH+ 0.76134E-11 -11.1184 0.63661E-11 -11.1961 0.83617E+00 -0.0777 55 HFeO2- 0.15023E-07 -7.8232 0.12538E-07 -7.9018 0.83456E+00 -0.0785 56 FeO+ 0.31500E-16 -16.5017 0.26340E-16 -16.5794 0.83617E+00 -0.0777 58 FeO2- 0.10181E-08 -8.9922 0.84967E-09 -9.0707 0.83456E+00 -0.0785 59 HFeO2,aq 0.86068E-11 -11.0652 0.86068E-11 -11.0652 0.10000E+01 0.0000 60 H2,aq 0.33351E-06 -6.4769 0.33233E-06 -6.4784 0.99647E+00 -0.0015 61 KCl,aq 0.35416E-09 -9.4508 0.35416E-09 -9.4508 0.10000E+01 0.0000 62 KHSO4,aq 0.70307E-19 -19.1530 0.70307E-19 -19.1530 0.10000E+01 0.0000 63 KOH,aq 0.70172E-06 -6.1538 0.70172E-06 -6.1538 0.10000E+01 0.0000 64 KSO4- 0.58053E-08 -8.2362 0.48449E-08 -8.3147 0.83456E+00 -0.0785 65 MgCO3,aq 0.38102E-11 -11.4191 0.38102E-11 -11.4191 0.10000E+01 0.0000 66 Mg(HCO3)+ 0.34481E-13 -13.4624 0.28832E-13 -13.5401 0.83617E+00 -0.0777 67 MgCl+ 0.28629E-14 -14.5432 0.23939E-14 -14.6209 0.83617E+00 -0.0777 68 MgF+ 0.11083E-14 -14.9553 0.92672E-15 -15.0331 0.83617E+00 -0.0777 69 MgOH+ 0.64729E-10 -10.1889 0.54125E-10 -10.2666 0.83617E+00 -0.0777 71 MnF+ 0.34405E-15 -15.4634 0.28768E-15 -15.5411 0.83617E+00 -0.0777 72 MnO,aq 0.17788E-08 -8.7499 0.17788E-08 -8.7499 0.10000E+01 0.0000 73 MnOH+ 0.49472E-09 -9.3056 0.41367E-09 -9.3833 0.83617E+00 -0.0777 74 MnO2-2 0.18014E-10 -10.7444 0.93066E-11 -11.0312 0.51664E+00 -0.2868 75 HMnO2- 0.19458E-09 -9.7109 0.16239E-09 -9.7894 0.83456E+00 -0.0785 78 MnCl+ 0.11981E-13 -13.9215 0.10018E-13 -13.9992 0.83617E+00 -0.0777 79 MnSO4,aq 0.75042E-14 -14.1247 0.75042E-14 -14.1247 0.10000E+01 0.0000 80 NaCl,aq 0.82062E-06 -6.0859 0.82062E-06 -6.0859 0.10000E+01 0.0000 81 NaF,aq 0.60863E-08 -8.2156 0.60863E-08 -8.2156 0.10000E+01 0.0000 82 NaOH,aq 0.89462E-04 -4.0484 0.89462E-04 -4.0484 0.10000E+01 0.0000 84 OH- 0.87084E-02 -2.0601 0.72544E-02 -2.1394 0.83304E+00 -0.0793 89 HPO3-2 0.47103E-16 -16.3269 0.24335E-16 -16.6138 0.51664E+00 -0.2868 92 H3PO4,aq 0.10424E-17 -17.9820 0.10424E-17 -17.9820 0.10000E+01 0.0000 93 H2PO4- 0.41327E-10 -10.3838 0.34523E-10 -10.4619 0.83536E+00 -0.0781 94 PO4-3 0.99844E-09 -9.0007 0.24071E-09 -9.6185 0.24109E+00 -0.6178 98 HP2O7-3 0.10201E-17 -17.9914 0.23429E-18 -18.6302 0.22967E+00 -0.6389 99 P2O7-4 0.92242E-17 -17.0351 0.70276E-18 -18.1532 0.76187E-01 -1.1181 100 H2S,aq 0.27157E-07 -7.5661 0.27061E-07 -7.5677 0.99647E+00 -0.0015 101 S2-2 0.15598E-11 -11.8069 0.80584E-12 -12.0938 0.51664E+00 -0.2868 102 S3-2 0.17111E-18 -18.7667 0.88404E-19 -19.0535 0.51664E+00 -0.2868 107 SO3-2 0.19656E-12 -12.7065 0.10303E-12 -12.9870 0.52418E+00 -0.2805 108 HSO3- 0.61565E-15 -15.2107 0.51380E-15 -15.2892 0.83456E+00 -0.0785 109 HSO4- 0.21878E-12 -12.6600 0.18312E-12 -12.7373 0.83699E+00 -0.0773 111 S2O3-2 0.14679E-14 -14.8333 0.75839E-15 -15.1201 0.51664E+00 -0.2868 Charge balance for all species = -.6132E-08 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.9485336E-10 -.2181593E-01 -.2195062E+02 0.0000 2 H2O 0.1000000E+01 0.5550427E+02 0.9981742E+06 0.0000 3 Cl- 0.1789151E-03 0.1797361E-03 0.6361020E+01 6.2730 4 SO4-- 0.4607980E-05 0.4526026E-05 0.4340155E+00 14.5753 5 HCO3- 0.1209975E-03 0.3357524E-03 0.2045077E+02 6.1037 6 HS- 0.1317117E-03 0.1318266E-03 0.4352131E+01 6.1400 7 Al+++ 0.1062458E-28 0.4361804E-05 0.1174818E+00 0.6835 8 H4SiO4 0.7436360E-03 0.1352868E-01 0.1298036E+04 -3.1286 9 Ca++ 0.8333438E-07 0.1990708E-06 0.7964381E-02 12.8294 10 Mg++ 0.2136808E-10 0.9317572E-10 0.2261319E-05 9.2363 11 Fe++ 0.3041601E-13 0.1615322E-07 0.9005284E-03 6.3902 12 K+ 0.1565416E-03 0.1572495E-03 0.6137995E+01 6.2157 13 Na+ 0.1987480E-01 0.2230350E-01 0.5118546E+03 8.3185 14 Mn++ 0.2125783E-10 0.2507383E-08 0.1375093E-03 9.2349 15 F- 0.1882294E-05 0.1888382E-05 0.3581263E-01 4.2941 16 HPO4-- 0.4537724E-07 0.4641700E-07 0.4447252E-02 12.5687 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.1959692E-01 -.1959339E-01 -.3522710E-05 0.0000000E+00 2 H2O 0.4984968E+02 0.4984968E+02 -.3434924E-05 0.0000000E+00 3 Cl- 0.1614252E-03 0.1614252E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.4067190E-05 0.4064929E-05 0.2260586E-08 0.0000000E+00 5 HCO3- 0.3015470E-03 0.3015470E-03 0.0000000E+00 0.0000000E+00 6 HS- 0.1183943E-03 0.1183965E-03 -.2260586E-08 0.0000000E+00 7 Al+++ 0.4775352E-05 0.3917437E-05 0.8579147E-06 0.0000000E+00 8 H4SiO4 0.1215302E-01 0.1215042E-01 0.2598705E-05 0.0000000E+00 9 Ca++ 0.2080835E-06 0.1787901E-06 0.2929338E-07 0.0000000E+00 10 Mg++ 0.8368328E-10 0.8368328E-10 0.0000000E+00 0.0000000E+00 11 Fe++ 0.3259227E-07 0.1450758E-07 0.1808469E-07 0.0000000E+00 12 K+ 0.1412294E-03 0.1412294E-03 0.0000000E+00 0.0000000E+00 13 Na+ 0.2003215E-01 0.2003129E-01 0.8564705E-06 0.0000000E+00 14 Mn++ 0.2251939E-08 0.2251939E-08 0.0000000E+00 0.0000000E+00 15 F- 0.1696000E-05 0.1696000E-05 0.0000000E+00 0.0000000E+00 16 HPO4-- 0.4168819E-07 0.4168819E-07 0.0000000E+00 0.0000000E+00 Chg. balance for solid moles: -.6353E-21 Mass of aqueous solution: 0.899700E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 0.0039900 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 0.8565E-06 -6.067 0.2246E-03 -3.649 97.86 0.8621E-04 andradite 0.9042E-08 -8.044 0.4595E-05 -5.338 2.002 0.1194E-05 grossular 0.7221E-09 -9.141 0.3253E-06 -6.488 0.1417 0.9051E-07 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.9260E+00 0.9260E+00 1.0000 -0.033 grossular 0.7395E-01 0.7395E-01 1.0000 -1.131 Solid products produced: Mass = 0.000230 g Volume = 0.000087 cm3 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.0039900 moles log = -2.3990 Original solution: 1000.0103000 g Original solution / Rock added: 250629.15 (Water/Rock Ratio), log = 5.3990 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0207 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9996E+00 0.9859 0.1006E+01 0.1020E+01 CO2,gas 0.1791E-05 1.0071 0.1841E-05 0.1828E-05 CH4,gas 0.6447E-05 1.0125 0.6663E-05 0.6581E-05 H2,gas 0.4272E-03 1.0005 0.4363E-03 0.4361E-03 H2S,gas 0.7317E-06 0.9960 0.7439E-06 0.7469E-06 S2,gas 0.1069E-24 1.0000 0.1091E-24 0.1091E-24 CO,gas 0.2098E-12 1.0000 0.2141E-12 0.2141E-12 SO3,gas 0.5606E-41 1.0000 0.5722E-41 0.5722E-41 SO2,gas 0.9516E-22 1.0000 0.9713E-22 0.9713E-22 HF,gas 0.2056E-14 1.0000 0.2099E-14 0.2099E-14 HCl,gas 0.3767E-17 1.0000 0.3845E-17 0.3845E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 17 albite -0.38 -0.38 0.00 0.000 -0.13080E-10 23 andradite 39.01 39.01 0.00 0.000 -0.12132E-10 24 grossular 32.73 32.73 0.00 0.000 -0.12132E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -14.09 -7.43 -2.478 0.12693E+05 -5.735 3 CH4,gas 4.54 -2.33 -6.88 -1.719 0.11739E+05 -5.176 4 H2,gas 8.00 2.94 -5.06 -2.891 0.86384E+04 -3.360 5 H2S,gas -6.23 -14.06 -7.83 -3.914 0.13365E+05 -6.128 6 S2,gas -7.34 -34.00 -26.66 -4.102 0.45523E+05 -24.962 7 CO,gas 3.21 -11.15 -14.37 -4.421 0.24534E+05 -12.669 8 SO3,gas 17.12 -25.82 -42.94 -10.735 0.73321E+05 -41.242 9 SO2,gas 0.83 -22.88 -23.71 -6.323 0.40487E+05 -22.013 10 HF,gas 0.47 -15.90 -16.38 -8.189 0.27963E+05 -14.678 11 HCl,gas 5.19 -13.92 -19.11 -9.557 0.32637E+05 -17.415 12 acmite 7.71 6.98 -0.73 -0.076 0.12441E+04 16 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 20 spessartine 24.46 19.69 -4.77 -0.239 0.81470E+04 21 analcite 3.32 2.74 -0.58 -0.064 0.98536E+03 27 annite 20.12 16.68 -3.44 -0.191 0.58731E+04 28 phlogopite 27.06 25.22 -1.84 -0.102 0.31457E+04 30 anorthite 12.71 7.94 -4.77 -0.367 0.81466E+04 33 apatite-OH -18.15 -19.33 -1.18 -0.091 0.20140E+04 34 apatite-F -34.30 -35.24 -0.94 -0.078 0.15975E+04 38 aragonite 0.97 -1.26 -2.23 -0.744 0.38095E+04 39 brucite 12.57 9.24 -3.33 -0.666 0.56897E+04 40 calcite 0.81 -1.26 -2.08 -0.692 0.35453E+04 41 carnegieite-low 9.02 5.87 -3.15 -0.450 0.53783E+04 42 carnegieite-high 10.09 5.87 -4.22 -0.603 0.72053E+04 43 carpholite-Mg 8.58 4.35 -4.24 -0.282 0.72328E+04 45 celadonite 5.34 3.62 -1.72 -0.101 0.29379E+04 46 celadonite-Fe 3.88 0.77 -3.10 -0.182 0.52961E+04 47 chrysotile 23.89 21.45 -2.44 -0.203 0.41674E+04 49 clinochlore 39.07 38.16 -0.91 -0.028 0.15482E+04 52 chlorite-Al-free 47.17 42.90 -4.27 -0.178 0.72899E+04 54 chloritoid-Fe 9.17 4.63 -4.55 -0.303 0.77606E+04 55 chloritoid-Mn 11.40 7.47 -3.93 -0.262 0.67065E+04 57 coesite -2.38 -3.13 -0.75 -0.251 0.12850E+04 64 cristobalite -2.56 -3.13 -0.57 -0.189 0.97036E+03 66 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71238E+04 68 diaspore 2.87 0.68 -2.19 -0.365 0.37397E+04 70 diopside 16.18 15.81 -0.37 -0.037 0.63671E+03 71 hedenbergite 14.21 12.96 -1.25 -0.125 0.21275E+04 76 clinoenstatite 17.17 12.22 -4.95 -0.495 0.84535E+04 78 epidote 24.67 22.56 -2.11 -0.102 0.36030E+04 79 clinozoisite 22.81 18.32 -4.48 -0.204 0.76539E+04 80 epidote-Fe 29.84 26.80 -3.04 -0.158 0.51987E+04 81 fayalite 14.05 9.65 -4.39 -0.628 0.75027E+04 82 ferrosilite 11.15 6.52 -4.63 -0.463 0.78995E+04 86 gibbsite 4.08 0.68 -3.40 -0.485 0.57982E+04 87 glaucophane 22.97 20.68 -2.29 -0.062 0.39115E+04 89 graphite -3.55 -8.21 -4.67 -1.333 0.79681E+04 90 greenalite 16.14 12.91 -3.23 -0.269 0.55089E+04 93 hematite 12.57 9.84 -2.73 -0.330 0.46554E+04 94 heulandite -5.83 -7.70 -1.88 -0.085 0.32045E+04 98 jadeite 4.22 2.74 -1.47 -0.147 0.25108E+04 100 kalsilite 7.58 3.77 -3.81 -0.545 0.65112E+04 101 kaolinite -1.33 -4.89 -3.56 -0.323 0.60743E+04 104 laumontite 2.88 1.68 -1.20 -0.080 0.20516E+04 105 lawsonite 9.62 7.94 -1.68 -0.112 0.28633E+04 106 leucite 4.12 0.64 -3.48 -0.348 0.59368E+04 108 lizardite 23.24 21.45 -1.79 -0.149 0.30600E+04 110 magnetite 20.09 16.23 -3.86 -0.315 0.65866E+04 111 minnesotaite 10.39 6.66 -3.73 -0.220 0.63726E+04 115 manganosite 14.06 9.23 -4.82 -1.206 0.82354E+04 119 microcline -2.49 -2.49 0.00 0.000 0.37765E+00 123 muscovite 2.58 -1.12 -3.70 -0.218 0.63212E+04 124 paragonite 4.24 0.98 -3.26 -0.192 0.55600E+04 125 nepheline 8.34 5.87 -2.47 -0.352 0.42107E+04 137 phlogopite-Na 29.65 27.33 -2.32 -0.129 0.39641E+04 139 prehnite 19.37 17.64 -1.73 -0.102 0.29572E+04 140 prehnite-Fe 22.50 21.88 -0.62 -0.037 0.10613E+04 141 pumpellyite-Fe 46.27 42.35 -3.92 -0.087 0.66862E+04 142 pumpellyite-Mg 48.99 45.20 -3.80 -0.084 0.64801E+04 145 pyrite -21.25 -24.67 -3.42 -0.804 0.58377E+04 146 pyrrhotite -4.26 -7.67 -3.41 -1.136 0.58177E+04 147 pyrrhotiteFe0.875 -6.02 -8.83 -2.81 -1.035 0.48048E+04 148 pyroxmangite 7.40 6.11 -1.29 -0.258 0.22067E+04 149 pyrophyllite -6.18 -11.15 -4.97 -0.311 0.84891E+04 150 quartz -2.99 -3.13 -0.14 -0.046 0.23769E+03 154 rhodochrosite -0.98 -4.86 -3.88 -1.294 0.66296E+04 155 rhodonite 7.45 6.11 -1.34 -0.268 0.22870E+04 156 sanidine -1.28 -2.49 -1.21 -0.093 0.20681E+04 166 stilbite -7.52 -7.70 -0.18 -0.009 0.31071E+03 167 stilpnomelane-Fe 13.02 11.40 -1.62 -0.048 0.27668E+04 168 stilpnomelane-Mg 27.44 25.63 -1.81 -0.054 0.30973E+04 174 talc 16.49 15.19 -1.30 -0.076 0.22139E+04 177 tephroite 18.09 15.34 -2.74 -0.392 0.46863E+04 181 tridymite -2.63 -3.13 -0.50 -0.167 0.85767E+03 182 tremolite 47.87 46.81 -1.06 -0.029 0.18063E+04 184 troilite-low -4.41 -7.67 -3.26 -1.086 0.55606E+04 190 wairakite 3.95 1.68 -2.27 -0.133 0.38735E+04 191 walstromite 11.51 9.70 -1.81 -0.362 0.30879E+04 192 wollastonite 10.46 9.70 -0.76 -0.152 0.12983E+04 193 pseudo-wollastonite 11.00 9.70 -1.30 -0.260 0.22182E+04 194 zoisite 22.85 18.32 -4.53 -0.206 0.77279E+04 195 akaganeite 7.75 4.92 -2.83 -0.613 0.48402E+04 202 chalcedony -2.80 -3.13 -0.33 -0.109 0.55699E+03 204 montmorillonite-Ca -2.29 -6.21 -3.92 -0.242 0.66890E+04 205 montmorillonite-K -2.24 -6.27 -4.04 -0.247 0.68934E+04 206 montmorillonite-Mg -2.48 -6.80 -4.32 -0.267 0.73783E+04 207 montmorillonite-Na -2.04 -5.58 -3.54 -0.217 0.60482E+04 208 nontronite-Ca 3.21 0.70 -2.51 -0.163 0.42935E+04 209 nontronite-H 2.53 -1.42 -3.95 -0.265 0.67437E+04 210 nontronite-K 3.34 0.63 -2.71 -0.174 0.46210E+04 211 nontronite-Mg 3.07 0.11 -2.97 -0.193 0.50668E+04 212 nontronite-Na 3.52 1.33 -2.19 -0.141 0.37418E+04 228 tobermorite 9.82 7.56 -2.26 -0.618 0.38671E+04 234 alabandite -0.98 -4.82 -3.84 -1.282 0.65651E+04 237 boehmite 4.41 0.68 -3.72 -0.620 0.63566E+04 239 ferrous-oxide 9.81 6.39 -3.42 -0.855 0.58420E+04 245 silica-amorphous -2.09 -3.13 -1.04 -0.346 0.17712E+04 247 an20ab80 2.02 1.28 -0.74 -0.057 0.12585E+04 248 an25ab75 2.65 1.70 -0.95 -0.073 0.16201E+04 249 an30ab70 3.28 2.11 -1.17 -0.090 0.19913E+04 250 tr.625ac.25prg.125 45.16 44.18 -0.99 -0.027 0.16858E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 0.0001000 MOLES Current total amount of reactant added: 0.0039900 MOLES New total amount of reactant added: 0.0040900 MOLES Mixing fraction reached given limit of 0.4000E-02 TOTMIX = 0.4090E-02 Execution stopped.