File SKIP_SPECIES.TXT lists species and minerals omitted from the calculations due to given T, P, option switches, or suppression in CHIMRUN, or are suppressed in the SOLTHERM database. It also lists minerals for which density is not specified in SOLTHERM. This is an extended P(to 5 kB), T(to 600 C) run (CON_FLAG = 1). methanol,aq is suppressed in SOLTHERM data file. methanol,aq is suppressed in SOLTHERM data file. CuCl4-3 is suppressed in SOLTHERM data file. H2BO3- is suppressed in SOLTHERM data file. UO2CO3,aq is suppressed in SOLTHERM data file. UO2SO4,aq is suppressed in SOLTHERM data file. UO2Cl2,aq is suppressed in SOLTHERM data file. UO2F2,aq is suppressed in SOLTHERM data file. PO4-3 is suppressed in SOLTHERM data file. H2PO4- is suppressed in SOLTHERM data file. H3PO4 is suppressed in SOLTHERM data file. O2,gas is suppressed in THIS RUN. O2,gas is suppressed in THIS RUN. amesite is suppressed in SOLTHERM data file. antigorite is suppressed in SOLTHERM data file. goethite is suppressed in THIS RUN. goethite is suppressed in THIS RUN. riebeckite is suppressed in THIS RUN. riebeckite is suppressed in THIS RUN. sapphirine-Fe(221) is suppressed in SOLTHERM data file. sapphirine(221) is suppressed in SOLTHERM data file. talc-prl is suppressed in SOLTHERM data file. PrO1.833(s) is suppressed in SOLTHERM data file. niter-NH4 is suppressed in SOLTHERM data file. FMQ_HS-1 is suppressed in THIS RUN. kf-ab-equil is suppressed in THIS RUN. ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Species No. Charge Tot.moles Trial molality Gamma Mixing solution H+ 1 1. -0.19597E-01 0.94853E-10 0.8397 0.00000000E+00 H2O 2 0. 0.49850E+02 0.10000E+01 1.0000 0.00000000E+00 Cl- 3 -1. 0.16143E-03 0.17892E-03 0.8346 0.00000000E+00 SO4-- 4 -2. 0.40672E-05 0.46080E-05 0.5177 0.00000000E+00 HCO3- 5 -1. 0.30155E-03 0.12100E-03 0.8358 0.00000000E+00 HS- 6 -1. 0.11839E-03 0.13171E-03 0.8347 0.00000000E+00 Al+++ 7 3. 0.47754E-05 0.10625E-28 0.2294 0.00000000E+00 H4SiO4 8 0. 0.12153E-01 0.74364E-03 1.0000 0.00000000E+00 Ca++ 9 2. 0.20808E-06 0.83334E-07 0.5139 0.00000000E+00 Mg++ 10 2. 0.83683E-10 0.21368E-10 0.5115 0.00000000E+00 Fe++ 11 2. 0.32592E-07 0.30416E-13 0.5121 0.00000000E+00 K+ 12 1. 0.14123E-03 0.15654E-03 0.8360 0.00000000E+00 Na+ 13 1. 0.20032E-01 0.19875E-01 0.8344 0.00000000E+00 Mn++ 14 2. 0.22519E-08 0.21258E-10 0.5125 0.00000000E+00 F- 15 -1. 0.16960E-05 0.18823E-05 0.8328 0.00000000E+00 HPO4-- 16 -2. 0.41688E-07 0.45377E-07 0.5178 0.00000000E+00 Chg. balance for total moles = -.5508E-08 Max. difference allowed = 0.1614E-07 The following parameters were given: ERPC = 0.1000E-11 pH = 0.0000 PFLUID = 50.0000 SLIM = 0.800000E-02 TEMP = 100.0000 SINC = 0.2000E-03 TEMPC = 0.0000 TOTMIX = 0.399000E-02 ENTH = 0.0000 SENTH = 0.0000 DENTH = 0.0000 TOTWAT = 90.0000 SOLMIN = 0.0000E+00 RM = 0.0000 AQGRM = 1000.0103 SUPRNT = 0.1000E-19 VBOX-1 = 400.9996 RHOFRS = 0.0000 RHOROC = 2.5000 The following options were selected: CONFLG = 1 C = 3 IFRAC = 0 IPUNCH = 2 NLOOP = 400 ISTEP = 2 LIMSOL = 1 LOOC = 0 IENTH = 0 ITREF = 0 IDEAL = 0 IPSAT = 1 INCREM = 0 INCP = 0 MINSOL = 3 NEUT = 0 AWAT = 0 CHGF = 0 Of the derived species, only those with molality > 0.10E-19 will appear in the output Species No. Charge Log K(diss) Species No. Charge Log K(diss) SiF6-2 17 -2. -24.5019 Mn+3 70 3. 19.1453 HSiO3- 18 -1. 9.0298 MnF+ 71 1. -1.2264 Ca(HSiO3)+ 19 1. 7.6723 MnO,aq 72 0. 17.9848 Mg(HSiO3)+ 20 1. 7.5773 MnOH+ 73 1. 8.5194 NaHSiO3,aq 21 0. 7.8210 MnO2-2 74 -2. 40.4638 AlO+ 22 1. 6.8663 HMnO2- 75 -1. 29.1232 AlOH+2 23 2. 3.1691 MnO4- 76 -1. 83.3111 HAlO2,aq 24 0. 10.5671 MnO4-2 77 -2. 81.3005 AlO2- 25 -1. 16.2221 MnCl+ 78 1. -0.7894 CH4,aq 26 0. 6.0126 MnSO4,aq 79 0. -2.4604 C2H6,aq 27 0. 12.3733 NaCl,aq 80 0. 0.4796 C3H8,aq 28 0. 17.3707 NaF,aq 81 0. 0.6306 C4H10,aq 29 0. 22.3757 NaOH,aq 82 0. 12.3669 ethanol,aq 30 0. 15.3258 O2,aq 83 0. 53.5502 CO,aq 31 0. 4.6892 OH- 84 -1. 12.2382 CO2,aq 32 0. -6.3298 HO2- 85 -1. 50.8010 CO3-2 33 -2. 10.0588 H2O2,aq 86 0. 40.0166 CaCO3,aq 34 0. 5.9605 H3PO2,aq 87 0. 24.3066 Ca(HCO3)+ 35 1. -1.4070 H2PO2- 88 -1. 26.5366 CaCl+ 36 1. -0.2091 HPO3-2 89 -2. 11.9254 CaCl2,aq 37 0. 0.4151 H3PO3,aq 90 0. 3.5792 CaF+ 38 1. -1.1644 H2PO3- 91 -1. 5.6232 CaOH+ 39 1. 10.1471 H3PO4,aq 92 0. -9.8447 CaSO4,aq 40 0. -2.5018 H2PO4- 93 -1. -7.2659 HCl,aq 41 0. 0.7370 PO4-3 94 -3. 12.0884 HClO,aq 42 0. 32.4260 H4P2O7,aq 95 0. -17.8095 ClO- 43 -1. 39.6530 H3P2O7- 96 -1. -15.9156 HClO2,aq 44 0. 70.1812 H2P2O7-2 97 -2. -13.4262 HF,aq 45 0. -3.8354 HP2O7-3 98 -3. -6.7266 HF2- 46 -1. -3.3639 P2O7-4 99 -4. 2.8952 Fe+3 47 3. 8.3809 H2S,aq 100 0. -6.4900 FeCl+ 48 1. -0.1994 S2-2 101 -2. 1.2355 FeCl2,aq 49 0. 4.3001 S3-2 102 -2. -8.8031 FeCl+2 50 2. 6.5269 S3- 103 -1. -16.3389 FeF+ 51 1. -1.7084 S4-2 104 -2. -18.6615 FeF+2 52 2. 1.4309 S5-2 105 -2. -28.3439 FeO,aq 53 0. 16.4104 SO2,aq 106 0. -0.2309 FeOH+ 54 1. 7.4874 SO3-2 107 -2. 10.3052 HFeO2- 55 -1. 24.3908 HSO3- 108 -1. 2.5086 FeO+ 56 1. 11.4004 HSO4- 109 -1. -2.9839 FeOH+2 57 2. 9.1194 HSO5- 110 -1. 38.8366 FeO2- 58 -1. 24.0895 S2O3-2 111 -2. -4.5600 HFeO2,aq 59 0. 15.9850 HS2O3- 112 -1. -6.8123 H2,aq 60 0. 9.4190 H2S2O3,aq 113 0. -8.0173 KCl,aq 61 0. 1.7417 S2O4-2 114 -2. 10.5541 KHSO4,aq 62 0. -0.4514 HS2O4- 115 -1. 7.6551 KOH,aq 63 0. 12.3695 H2S2O4,aq 116 0. 6.6259 KSO4- 64 -1. -1.1908 S2O5-2 117 -2. 10.0741 MgCO3,aq 65 0. 6.5614 S2O6-2 118 -2. 11.5521 Mg(HCO3)+ 66 1. -1.4164 S2O8-2 119 -2. 42.0620 MgCl+ 67 1. -0.1664 S3O6-2 120 -2. 3.7866 MgF+ 68 1. -1.7331 S4O6-2 121 -2. -17.8657 MgOH+ 69 1. 9.4041 S5O6-2 122 -2. -14.1333 For mixed gases (JSOLS=6), log K(hydrol) = log (K*P) Log K Trial Log K Trial Mineral No. hydrol Moles Mineral No. hydrol Moles H2O,gas 1 1.696 0.0000E+00 osumilite(1) 126 21.717 0.0000E+00 CO2,gas 2 -6.660 0.0000E+00 osumilite(2) 127 20.667 0.0000E+00 CH4,gas 3 4.544 0.0000E+00 osumilite-Fe 128 14.390 0.0000E+00 H2,gas 4 8.000 0.0000E+00 pargasite 129 65.092 0.0000E+00 H2S,gas 5 -6.230 0.0000E+00 periclase 130 16.138 0.0000E+00 S2,gas 6 -7.335 0.0000E+00 periclase-Fe 131 11.627 0.0000E+00 CO,gas 7 3.215 0.0000E+00 perovskite-Al 132 12.344 0.0000E+00 SO3,gas 8 17.121 0.0000E+00 perovskite-Ca 133 23.807 0.0000E+00 SO2,gas 9 0.832 0.0000E+00 perovskite-Fe 134 21.143 0.0000E+00 HF,gas 10 0.473 0.0000E+00 perovskite-Mg 135 23.119 0.0000E+00 HCl,gas 11 5.189 0.0000E+00 phase_A 136 80.189 0.0000E+00 acmite 12 7.710 0.0000E+00 phlogopite-Na 137 29.647 0.0000E+00 akermanite 13 36.442 0.0000E+00 piemontite(ordered) 138 33.776 0.0000E+00 akimotoite 14 16.591 0.0000E+00 prehnite 139 19.372 0.0000E+00 akimotoite-Fe 15 13.067 0.0000E+00 prehnite-Fe 140 22.498 0.0000E+00 albite-high 16 0.693 0.0000E+00 pumpellyite-Fe 141 46.269 0.0000E+00 albite 17 -0.384 0.8565E-06 pumpellyite-Mg 142 48.995 0.0000E+00 almandine 18 24.442 0.0000E+00 px-Mg-tschermaks 143 19.616 0.0000E+00 pyrope 19 37.248 0.0000E+00 px-Ca-tschermaks 144 18.610 0.0000E+00 spessartine 20 24.457 0.0000E+00 pyrite 145 -21.247 0.0000E+00 analcite 21 3.322 0.0000E+00 pyrrhotite 146 -4.260 0.0000E+00 andalusite 22 5.002 0.0000E+00 pyrrhotiteFe0.875 147 -6.017 0.0000E+00 andradite 23 39.009 0.9042E-08 pyroxmangite 148 7.399 0.0000E+00 grossular 24 32.731 0.7221E-09 pyrophyllite 149 -6.176 0.0000E+00 anhydrite 25 -5.317 0.0000E+00 quartz 150 -2.989 0.0000E+00 ankerite 26 -2.135 0.0000E+00 rankinite 151 40.713 0.0000E+00 annite 27 20.123 0.0000E+00 ringwoodite-Fe 152 15.456 0.0000E+00 phlogopite 28 27.065 0.0000E+00 ringwoodite-Mg 153 27.575 0.0000E+00 biotite-Mn 29 32.960 0.0000E+00 rhodochrosite 154 -0.976 0.0000E+00 anorthite 30 12.710 0.0000E+00 rhodonite 155 7.446 0.0000E+00 anthophyllite 31 51.852 0.0000E+00 sanidine 156 -1.275 0.0000E+00 anthophyllite-Fe 32 29.306 0.0000E+00 sapphirine(351) 157 78.899 0.0000E+00 apatite-OH 33 -18.153 0.0000E+00 siderite 158 -2.608 0.0000E+00 apatite-F 34 -34.301 0.0000E+00 sillimanite 159 5.262 0.0000E+00 apatite-OH-zs 35 -12.736 0.0000E+00 sodalite 160 49.976 0.0000E+00 apatite-F-zs 36 -27.774 0.0000E+00 spinel 161 20.870 0.0000E+00 apatite-Cl-zs 37 -16.674 0.0000E+00 spurrite 162 59.482 0.0000E+00 aragonite 38 0.967 0.0000E+00 staurolite-Fe 163 73.598 0.0000E+00 brucite 39 12.569 0.0000E+00 staurolite-Mg 164 89.802 0.0000E+00 calcite 40 0.812 0.0000E+00 staurolite-Mn 165 83.909 0.0000E+00 carnegieite-low 41 9.023 0.0000E+00 stilbite 166 -7.522 0.0000E+00 carnegieite-high 42 10.093 0.0000E+00 stilpnomelane-Fe 167 13.017 0.0000E+00 carpholite-Mg 43 8.582 0.0000E+00 stilpnomelane-Mg 168 27.441 0.0000E+00 carpholite-Fe 44 6.713 0.0000E+00 stishovite 169 2.720 0.0000E+00 celadonite 45 5.342 0.0000E+00 sudoite-Fe 170 18.296 0.0000E+00 celadonite-Fe 46 3.877 0.0000E+00 sudoite 171 21.077 0.0000E+00 chrysotile 47 23.892 0.0000E+00 sulfur 172 -9.152 0.0000E+00 chondrodite 48 56.475 0.0000E+00 sylvite 173 1.338 0.0000E+00 clinochlore 49 39.070 0.0000E+00 talc 174 16.491 0.0000E+00 daphnite 50 28.965 0.0000E+00 talc-Fe 175 13.448 0.0000E+00 chlorite-Mn 51 46.869 0.0000E+00 talc-tschermaks 176 19.091 0.0000E+00 chlorite-Al-free 52 47.173 0.0000E+00 tephroite 177 18.086 0.0000E+00 chloritoid-Mg 53 13.198 0.0000E+00 tilleyite 178 41.377 0.0000E+00 chloritoid-Fe 54 9.174 0.0000E+00 titanite-CaSi 179 15.479 0.0000E+00 chloritoid-Mn 55 11.401 0.0000E+00 topaz-H 180 4.618 0.0000E+00 clinohumite 56 97.128 0.0000E+00 tridymite 181 -2.626 0.0000E+00 coesite 57 -2.376 0.0000E+00 tremolite 182 47.869 0.0000E+00 cordierite-H 58 23.715 0.0000E+00 ferroactinolite 183 38.452 0.0000E+00 cordierite 59 24.049 0.0000E+00 troilite-low 184 -4.411 0.0000E+00 cordierite-Fe 60 20.450 0.0000E+00 tschermakite 185 48.210 0.0000E+00 cordierite-Mn 61 25.066 0.0000E+00 vesuvianite 186 223.471 0.0000E+00 corundum 62 8.383 0.0000E+00 wadeite-Si 187 20.216 0.0000E+00 corundum-MgSi 63 18.891 0.0000E+00 wadsleyite-Fe 188 15.680 0.0000E+00 cristobalite 64 -2.560 0.0000E+00 wadsleyite-Mg 189 25.850 0.0000E+00 cummingtonite 65 52.099 0.0000E+00 wairakite 190 3.950 0.0000E+00 cymrite-K 66 1.685 0.0000E+00 walstromite 191 11.509 0.0000E+00 deerite 67 95.671 0.0000E+00 wollastonite 192 10.461 0.0000E+00 diaspore 68 2.874 0.0000E+00 pseudo-wollastonite 193 11.000 0.0000E+00 diamond 69 -3.102 0.0000E+00 zoisite 194 22.849 0.0000E+00 diopside 70 16.181 0.0000E+00 akaganeite 195 7.755 0.0000E+00 hedenbergite 71 14.208 0.0000E+00 beidellite-Ca 196 -1.646 0.0000E+00 dolomite,ordered 72 0.546 0.0000E+00 beidellite-H 197 -2.326 0.0000E+00 eastonite 73 28.489 0.0000E+00 beidellite-K 198 -1.520 0.0000E+00 enstatite 74 17.265 0.0000E+00 beidellite-Mg 199 -1.790 0.0000E+00 clinoenstatite-HiP 75 18.354 0.0000E+00 beidellite-Na 200 -1.342 0.0000E+00 clinoenstatite 76 17.166 0.0000E+00 calcium 201 84.026 0.0000E+00 protoenstatite 77 17.824 0.0000E+00 chalcedony 202 -2.802 0.0000E+00 epidote 78 24.670 0.0000E+00 dawsonite 203 1.682 0.0000E+00 clinozoisite 79 22.806 0.0000E+00 montmorillonite-Ca 204 -2.291 0.0000E+00 epidote-Fe 80 29.841 0.0000E+00 montmorillonite-K 205 -2.237 0.0000E+00 fayalite 81 14.046 0.0000E+00 montmorillonite-Mg 206 -2.480 0.0000E+00 ferrosilite 82 11.149 0.0000E+00 montmorillonite-Na 207 -2.038 0.0000E+00 forsterite 83 21.016 0.0000E+00 nontronite-Ca 208 3.215 0.0000E+00 gedrite 84 50.522 0.0000E+00 nontronite-H 209 2.533 0.0000E+00 gehlenite 85 36.628 0.0000E+00 nontronite-K 210 3.341 0.0000E+00 gibbsite 86 4.079 0.0000E+00 nontronite-Mg 211 3.075 0.0000E+00 glaucophane 87 22.975 0.0000E+00 nontronite-Na 212 3.520 0.0000E+00 glaucophane-Fe 88 17.276 0.0000E+00 sepiolite 213 24.118 0.0000E+00 graphite 89 -3.546 0.0000E+00 topaz 214 -16.546 0.0000E+00 greenalite 90 16.140 0.0000E+00 alite 215 57.999 0.0000E+00 grunerite 91 31.215 0.0000E+00 belite 216 30.433 0.0000E+00 halite 92 1.575 0.0000E+00 ettringite 217 43.232 0.0000E+00 hematite 93 12.566 0.0000E+00 gypsum 218 -4.955 0.0000E+00 heulandite 94 -5.827 0.0000E+00 hemicarboaluminate 219 70.954 0.0000E+00 hercynite 95 17.279 0.0000E+00 hydrogarnet 220 60.662 0.0000E+00 hollandite 96 25.673 0.0000E+00 hydrogarnet-Si 221 50.586 0.0000E+00 iron 97 19.086 0.0000E+00 jennite 222 24.367 0.0000E+00 jadeite 98 4.215 0.0000E+00 monosulfoaluminate 223 53.400 0.0000E+00 julgoldite 99 70.427 0.0000E+00 monocarboaluminate 224 61.898 0.0000E+00 kalsilite 100 7.584 0.0000E+00 portlandite 225 18.272 0.0000E+00 kaolinite 101 -1.333 0.0000E+00 stratlingite 226 36.502 0.0000E+00 kyanite 102 4.876 0.0000E+00 tricarboaluminate 227 70.370 0.0000E+00 larnite-bredigite 103 30.686 0.0000E+00 tobermorite 228 9.823 0.0000E+00 laumontite 104 2.883 0.0000E+00 C4AH13 229 81.816 0.0000E+00 lawsonite 105 9.616 0.0000E+00 C2AH8 230 45.203 0.0000E+00 leucite 106 4.119 0.0000E+00 C3A 231 86.953 0.0000E+00 lime 107 25.998 0.0000E+00 C4AF 232 117.416 0.0000E+00 lizardite 108 23.244 0.0000E+00 CAH10 233 28.335 0.0000E+00 magnesite 109 0.691 0.0000E+00 alabandite 234 -0.978 0.0000E+00 magnetite 110 20.087 0.0000E+00 alunite 235 -10.435 0.0000E+00 minnesotaite 111 10.388 0.0000E+00 artinite 236 15.121 0.0000E+00 minnesotaite-Mg 112 20.602 0.0000E+00 boehmite 237 4.406 0.0000E+00 magnesioferrite 113 26.212 0.0000E+00 dolomite,disordered 238 1.247 0.0000E+00 majorite 114 53.251 0.0000E+00 ferrous-oxide 239 9.812 0.0000E+00 manganosite 115 14.058 0.0000E+00 fluorite 240 -9.931 0.0000E+00 margarite 116 17.324 0.0000E+00 huntite 241 3.770 0.0000E+00 meionite 117 44.874 0.0000E+00 hydromagnesite 242 19.995 0.0000E+00 merwinite 118 55.930 0.0000E+00 nesquehonite 243 4.723 0.0000E+00 microcline 119 -2.486 0.0000E+00 potassium-oxide 244 69.038 0.0000E+00 monticellite 120 24.339 0.0000E+00 silica-amorphous 245 -2.091 0.0000E+00 mullite-Al 121 363.148 0.0000E+00 sodium-oxide 246 55.169 0.0000E+00 mullite-Si 122 7.264 0.0000E+00 an20ab80 247 2.018 0.0000E+00 muscovite 123 2.582 0.0000E+00 an25ab75 248 2.646 0.0000E+00 paragonite 124 4.239 0.0000E+00 an30ab70 249 3.279 0.0000E+00 nepheline 125 8.339 0.0000E+00 tr.625ac.25prg.125 250 45.165 0.0000E+00 Initial composition of reactant (mole%): H2O 88.87 HCl 0.5900 CO2 7.070 CO 0.1600 H2 1.540 S2 0.8000E-01 SO2 1.150 HF 0.4000E-01 H2S 1.120 0.000 Sum of wt% of reactants: 100.6200 Reactant consumed: 0.0039900 moles log = -2.3990 Original solution: 1000.0103000 g Original solution / Rock added: 250629.15 (Water/Rock Ratio), log = 5.3990 The following minerals and/or gases with identical index are in solid solution: H2O,gas 6 CO2,gas 6 CH4,gas 6 H2,gas 6 H2S,gas 6 S2,gas 6 CO,gas 6 SO3,gas 6 SO2,gas 6 HF,gas 6 HCl,gas 6 almandine 16 pyrope 16 spessartine 16 andradite 8 grossular 8 annite 15 phlogopite 15 biotite-Mn 15 clinochlore 1 daphnite 1 chlorite-Mn 1 diopside 5 hedenbergite 5 epidote 3 clinozoisite 3 iron 9 magnetite 14 talc 7 talc-Fe 7 tremolite 2 ferroactinolite 2 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 10 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 0.0039900 Water: Moles liquid = 0.4985E+02 kg liquid = 0.8981E+00 Moles total = 0.4985E+02 kg total = 0.8981E+00 Activity = 1.0000 Stoichiometric ionic strength = .1158502E-01 Osmotic coef. = 0.9583 True ionic strength = .2025098E-01 Chg. balance for total moles = -.5508E-08 Max. difference allowed = 0.1614E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.94853E-10 -10.0229 0.79644E-10 -10.0988 0.83965E+00 -0.0759 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.17892E-03 -3.7474 0.14932E-03 -3.8259 0.83456E+00 -0.0785 4 SO4-- 0.46080E-05 -5.3365 0.23858E-05 -5.6224 0.51775E+00 -0.2859 5 HCO3- 0.12100E-03 -3.9172 0.10113E-03 -3.9951 0.83579E+00 -0.0779 6 HS- 0.13171E-03 -3.8804 0.10994E-03 -3.9589 0.83468E+00 -0.0785 7 Al+++ 0.10625E-28 -28.9737 0.24377E-29 -29.6130 0.22944E+00 -0.6393 8 H4SiO4 0.74364E-03 -3.1286 0.74364E-03 -3.1286 0.10000E+01 0.0000 9 Ca++ 0.83334E-07 -7.0792 0.42826E-07 -7.3683 0.51391E+00 -0.2891 10 Mg++ 0.21368E-10 -10.6702 0.10931E-10 -10.9614 0.51154E+00 -0.2911 11 Fe++ 0.30416E-13 -13.5169 0.15576E-13 -13.8075 0.51210E+00 -0.2906 12 K+ 0.15654E-03 -3.8054 0.13087E-03 -3.8832 0.83599E+00 -0.0778 13 Na+ 0.19875E-01 -1.7017 0.16584E-01 -1.7803 0.83441E+00 -0.0786 14 Mn++ 0.21258E-10 -10.6725 0.10895E-10 -10.9628 0.51253E+00 -0.2903 15 F- 0.18823E-05 -5.7253 0.15676E-05 -5.8048 0.83283E+00 -0.0794 16 HPO4-- 0.45377E-07 -7.3432 0.23497E-07 -7.6290 0.51782E+00 -0.2858 18 HSiO3- 0.10447E-01 -1.9810 0.87183E-02 -2.0596 0.83456E+00 -0.0785 19 Ca(HSiO3)+ 0.10169E-07 -7.9927 0.85032E-08 -8.0704 0.83617E+00 -0.0777 20 Mg(HSiO3)+ 0.32301E-11 -11.4908 0.27009E-11 -11.5685 0.83617E+00 -0.0777 21 NaHSiO3,aq 0.23384E-02 -2.6311 0.23384E-02 -2.6311 0.10000E+01 0.0000 22 AlO+ 0.62526E-16 -16.2039 0.52282E-16 -16.2816 0.83617E+00 -0.0777 24 HAlO2,aq 0.13073E-09 -9.8836 0.13073E-09 -9.8836 0.10000E+01 0.0000 25 AlO2- 0.43617E-05 -5.3603 0.36334E-05 -5.4397 0.83304E+00 -0.0793 26 CH4,aq 0.45427E-08 -8.3427 0.45267E-08 -8.3442 0.99647E+00 -0.0015 27 C2H6,aq 0.10578E-19 -19.9756 0.10541E-19 -19.9771 0.99647E+00 -0.0015 31 CO,aq 0.14368E-15 -15.8426 0.14368E-15 -15.8426 0.10000E+01 0.0000 32 CO2,aq 0.17271E-07 -7.7627 0.17210E-07 -7.7642 0.99647E+00 -0.0015 33 CO3-2 0.21467E-03 -3.6682 0.11091E-03 -3.9550 0.51664E+00 -0.2868 34 CaCO3,aq 0.59557E-07 -7.2251 0.59557E-07 -7.2251 0.10000E+01 0.0000 35 Ca(HCO3)+ 0.13221E-09 -9.8787 0.11055E-09 -9.9564 0.83617E+00 -0.0777 36 CaCl+ 0.12376E-10 -10.9074 0.10349E-10 -10.9851 0.83617E+00 -0.0777 37 CaCl2,aq 0.36711E-15 -15.4352 0.36711E-15 -15.4352 0.10000E+01 0.0000 38 CaF+ 0.11722E-11 -11.9310 0.98019E-12 -12.0087 0.83617E+00 -0.0777 39 CaOH+ 0.45832E-07 -7.3388 0.38323E-07 -7.4165 0.83617E+00 -0.0777 40 CaSO4,aq 0.32445E-10 -10.4889 0.32445E-10 -10.4889 0.10000E+01 0.0000 41 HCl,aq 0.21792E-14 -14.6617 0.21792E-14 -14.6617 0.10000E+01 0.0000 45 HF,aq 0.85470E-12 -12.0682 0.85470E-12 -12.0682 0.10000E+01 0.0000 46 HF2- 0.54204E-18 -18.2660 0.45236E-18 -18.3445 0.83456E+00 -0.0785 48 FeCl+ 0.44025E-17 -17.3563 0.36813E-17 -17.4340 0.83617E+00 -0.0777 51 FeF+ 0.14922E-17 -17.8262 0.12478E-17 -17.9039 0.83617E+00 -0.0777 53 FeO,aq 0.95437E-10 -10.0203 0.95437E-10 -10.0203 0.10000E+01 0.0000 54 FeOH+ 0.76134E-11 -11.1184 0.63661E-11 -11.1961 0.83617E+00 -0.0777 55 HFeO2- 0.15023E-07 -7.8232 0.12538E-07 -7.9018 0.83456E+00 -0.0785 56 FeO+ 0.31500E-16 -16.5017 0.26340E-16 -16.5794 0.83617E+00 -0.0777 58 FeO2- 0.10181E-08 -8.9922 0.84967E-09 -9.0707 0.83456E+00 -0.0785 59 HFeO2,aq 0.86068E-11 -11.0652 0.86068E-11 -11.0652 0.10000E+01 0.0000 60 H2,aq 0.33351E-06 -6.4769 0.33233E-06 -6.4784 0.99647E+00 -0.0015 61 KCl,aq 0.35416E-09 -9.4508 0.35416E-09 -9.4508 0.10000E+01 0.0000 62 KHSO4,aq 0.70307E-19 -19.1530 0.70307E-19 -19.1530 0.10000E+01 0.0000 63 KOH,aq 0.70172E-06 -6.1538 0.70172E-06 -6.1538 0.10000E+01 0.0000 64 KSO4- 0.58053E-08 -8.2362 0.48449E-08 -8.3147 0.83456E+00 -0.0785 65 MgCO3,aq 0.38102E-11 -11.4191 0.38102E-11 -11.4191 0.10000E+01 0.0000 66 Mg(HCO3)+ 0.34481E-13 -13.4624 0.28832E-13 -13.5401 0.83617E+00 -0.0777 67 MgCl+ 0.28629E-14 -14.5432 0.23939E-14 -14.6209 0.83617E+00 -0.0777 68 MgF+ 0.11083E-14 -14.9553 0.92672E-15 -15.0331 0.83617E+00 -0.0777 69 MgOH+ 0.64729E-10 -10.1889 0.54125E-10 -10.2666 0.83617E+00 -0.0777 71 MnF+ 0.34405E-15 -15.4634 0.28768E-15 -15.5411 0.83617E+00 -0.0777 72 MnO,aq 0.17788E-08 -8.7499 0.17788E-08 -8.7499 0.10000E+01 0.0000 73 MnOH+ 0.49472E-09 -9.3056 0.41367E-09 -9.3833 0.83617E+00 -0.0777 74 MnO2-2 0.18014E-10 -10.7444 0.93066E-11 -11.0312 0.51664E+00 -0.2868 75 HMnO2- 0.19458E-09 -9.7109 0.16239E-09 -9.7894 0.83456E+00 -0.0785 78 MnCl+ 0.11981E-13 -13.9215 0.10018E-13 -13.9992 0.83617E+00 -0.0777 79 MnSO4,aq 0.75042E-14 -14.1247 0.75042E-14 -14.1247 0.10000E+01 0.0000 80 NaCl,aq 0.82062E-06 -6.0859 0.82062E-06 -6.0859 0.10000E+01 0.0000 81 NaF,aq 0.60863E-08 -8.2156 0.60863E-08 -8.2156 0.10000E+01 0.0000 82 NaOH,aq 0.89462E-04 -4.0484 0.89462E-04 -4.0484 0.10000E+01 0.0000 84 OH- 0.87084E-02 -2.0601 0.72544E-02 -2.1394 0.83304E+00 -0.0793 89 HPO3-2 0.47103E-16 -16.3269 0.24335E-16 -16.6138 0.51664E+00 -0.2868 92 H3PO4,aq 0.10424E-17 -17.9820 0.10424E-17 -17.9820 0.10000E+01 0.0000 93 H2PO4- 0.41327E-10 -10.3838 0.34523E-10 -10.4619 0.83536E+00 -0.0781 94 PO4-3 0.99844E-09 -9.0007 0.24071E-09 -9.6185 0.24109E+00 -0.6178 98 HP2O7-3 0.10201E-17 -17.9914 0.23429E-18 -18.6302 0.22967E+00 -0.6389 99 P2O7-4 0.92242E-17 -17.0351 0.70276E-18 -18.1532 0.76187E-01 -1.1181 100 H2S,aq 0.27157E-07 -7.5661 0.27061E-07 -7.5677 0.99647E+00 -0.0015 101 S2-2 0.15598E-11 -11.8069 0.80584E-12 -12.0938 0.51664E+00 -0.2868 102 S3-2 0.17111E-18 -18.7667 0.88404E-19 -19.0535 0.51664E+00 -0.2868 107 SO3-2 0.19656E-12 -12.7065 0.10303E-12 -12.9870 0.52418E+00 -0.2805 108 HSO3- 0.61565E-15 -15.2107 0.51380E-15 -15.2892 0.83456E+00 -0.0785 109 HSO4- 0.21878E-12 -12.6600 0.18312E-12 -12.7373 0.83699E+00 -0.0773 111 S2O3-2 0.14679E-14 -14.8333 0.75839E-15 -15.1201 0.51664E+00 -0.2868 Charge balance for all species = -.6132E-08 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.9485336E-10 -.2181593E-01 -.2195062E+02 0.0000 2 H2O 0.1000000E+01 0.5550427E+02 0.9981742E+06 0.0000 3 Cl- 0.1789151E-03 0.1797361E-03 0.6361020E+01 6.2730 4 SO4-- 0.4607980E-05 0.4526026E-05 0.4340155E+00 14.5753 5 HCO3- 0.1209975E-03 0.3357524E-03 0.2045077E+02 6.1037 6 HS- 0.1317117E-03 0.1318266E-03 0.4352131E+01 6.1400 7 Al+++ 0.1062458E-28 0.4361804E-05 0.1174818E+00 0.6835 8 H4SiO4 0.7436360E-03 0.1352868E-01 0.1298036E+04 -3.1286 9 Ca++ 0.8333438E-07 0.1990708E-06 0.7964381E-02 12.8294 10 Mg++ 0.2136808E-10 0.9317572E-10 0.2261319E-05 9.2363 11 Fe++ 0.3041601E-13 0.1615322E-07 0.9005284E-03 6.3902 12 K+ 0.1565416E-03 0.1572495E-03 0.6137995E+01 6.2157 13 Na+ 0.1987480E-01 0.2230350E-01 0.5118546E+03 8.3185 14 Mn++ 0.2125783E-10 0.2507383E-08 0.1375093E-03 9.2349 15 F- 0.1882294E-05 0.1888382E-05 0.3581263E-01 4.2941 16 HPO4-- 0.4537724E-07 0.4641700E-07 0.4447252E-02 12.5687 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.1959692E-01 -.1959339E-01 -.3522710E-05 0.0000000E+00 2 H2O 0.4984968E+02 0.4984968E+02 -.3434924E-05 0.0000000E+00 3 Cl- 0.1614252E-03 0.1614252E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.4067190E-05 0.4064929E-05 0.2260586E-08 0.0000000E+00 5 HCO3- 0.3015470E-03 0.3015470E-03 0.0000000E+00 0.0000000E+00 6 HS- 0.1183943E-03 0.1183965E-03 -.2260586E-08 0.0000000E+00 7 Al+++ 0.4775352E-05 0.3917437E-05 0.8579147E-06 0.0000000E+00 8 H4SiO4 0.1215302E-01 0.1215042E-01 0.2598705E-05 0.0000000E+00 9 Ca++ 0.2080835E-06 0.1787901E-06 0.2929338E-07 0.0000000E+00 10 Mg++ 0.8368328E-10 0.8368328E-10 0.0000000E+00 0.0000000E+00 11 Fe++ 0.3259227E-07 0.1450758E-07 0.1808469E-07 0.0000000E+00 12 K+ 0.1412294E-03 0.1412294E-03 0.0000000E+00 0.0000000E+00 13 Na+ 0.2003215E-01 0.2003129E-01 0.8564705E-06 0.0000000E+00 14 Mn++ 0.2251939E-08 0.2251939E-08 0.0000000E+00 0.0000000E+00 15 F- 0.1696000E-05 0.1696000E-05 0.0000000E+00 0.0000000E+00 16 HPO4-- 0.4168819E-07 0.4168819E-07 0.0000000E+00 0.0000000E+00 Chg. balance for solid moles: 0.7412E-21 Mass of aqueous solution: 0.899700E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 0.0039900 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 0.8565E-06 -6.067 0.2246E-03 -3.649 97.86 0.8621E-04 andradite 0.9042E-08 -8.044 0.4595E-05 -5.338 2.002 0.1194E-05 grossular 0.7221E-09 -9.141 0.3253E-06 -6.488 0.1417 0.9051E-07 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.9260E+00 0.9260E+00 1.0000 -0.033 grossular 0.7395E-01 0.7395E-01 1.0000 -1.131 Solid products produced: Mass = 0.000230 g Volume = 0.000087 cm3 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.0039900 moles log = -2.3990 Original solution: 1000.0103000 g Original solution / Rock added: 250629.15 (Water/Rock Ratio), log = 5.3990 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0207 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9996E+00 0.9859 0.1006E+01 0.1020E+01 CO2,gas 0.1791E-05 1.0071 0.1841E-05 0.1828E-05 CH4,gas 0.6447E-05 1.0125 0.6663E-05 0.6581E-05 H2,gas 0.4272E-03 1.0005 0.4363E-03 0.4361E-03 H2S,gas 0.7317E-06 0.9960 0.7439E-06 0.7469E-06 S2,gas 0.1069E-24 1.0000 0.1091E-24 0.1091E-24 CO,gas 0.2098E-12 1.0000 0.2141E-12 0.2141E-12 SO3,gas 0.5606E-41 1.0000 0.5722E-41 0.5722E-41 SO2,gas 0.9516E-22 1.0000 0.9713E-22 0.9713E-22 HF,gas 0.2056E-14 1.0000 0.2099E-14 0.2099E-14 HCl,gas 0.3767E-17 1.0000 0.3845E-17 0.3845E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 17 albite -0.38 -0.38 0.00 0.000 -0.94784E-12 23 andradite 39.01 39.01 0.00 0.000 -0.12132E-10 24 grossular 32.73 32.73 0.00 0.000 -0.24265E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -14.09 -7.43 -2.478 0.12693E+05 -5.735 3 CH4,gas 4.54 -2.33 -6.88 -1.719 0.11739E+05 -5.176 4 H2,gas 8.00 2.94 -5.06 -2.891 0.86384E+04 -3.360 5 H2S,gas -6.23 -14.06 -7.83 -3.914 0.13365E+05 -6.128 6 S2,gas -7.34 -34.00 -26.66 -4.102 0.45523E+05 -24.962 7 CO,gas 3.21 -11.15 -14.37 -4.421 0.24534E+05 -12.669 8 SO3,gas 17.12 -25.82 -42.94 -10.735 0.73321E+05 -41.242 9 SO2,gas 0.83 -22.88 -23.71 -6.323 0.40487E+05 -22.013 10 HF,gas 0.47 -15.90 -16.38 -8.189 0.27963E+05 -14.678 11 HCl,gas 5.19 -13.92 -19.11 -9.557 0.32637E+05 -17.415 12 acmite 7.71 6.98 -0.73 -0.076 0.12441E+04 16 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 20 spessartine 24.46 19.69 -4.77 -0.239 0.81470E+04 21 analcite 3.32 2.74 -0.58 -0.064 0.98536E+03 27 annite 20.12 16.68 -3.44 -0.191 0.58731E+04 28 phlogopite 27.06 25.22 -1.84 -0.102 0.31457E+04 30 anorthite 12.71 7.94 -4.77 -0.367 0.81466E+04 33 apatite-OH -18.15 -19.33 -1.18 -0.091 0.20140E+04 34 apatite-F -34.30 -35.24 -0.94 -0.078 0.15975E+04 38 aragonite 0.97 -1.26 -2.23 -0.744 0.38095E+04 39 brucite 12.57 9.24 -3.33 -0.666 0.56897E+04 40 calcite 0.81 -1.26 -2.08 -0.692 0.35453E+04 41 carnegieite-low 9.02 5.87 -3.15 -0.450 0.53783E+04 42 carnegieite-high 10.09 5.87 -4.22 -0.603 0.72053E+04 43 carpholite-Mg 8.58 4.35 -4.24 -0.282 0.72328E+04 45 celadonite 5.34 3.62 -1.72 -0.101 0.29379E+04 46 celadonite-Fe 3.88 0.77 -3.10 -0.182 0.52961E+04 47 chrysotile 23.89 21.45 -2.44 -0.203 0.41674E+04 49 clinochlore 39.07 38.16 -0.91 -0.028 0.15482E+04 52 chlorite-Al-free 47.17 42.90 -4.27 -0.178 0.72899E+04 54 chloritoid-Fe 9.17 4.63 -4.55 -0.303 0.77606E+04 55 chloritoid-Mn 11.40 7.47 -3.93 -0.262 0.67065E+04 57 coesite -2.38 -3.13 -0.75 -0.251 0.12850E+04 64 cristobalite -2.56 -3.13 -0.57 -0.189 0.97036E+03 66 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71238E+04 68 diaspore 2.87 0.68 -2.19 -0.365 0.37397E+04 70 diopside 16.18 15.81 -0.37 -0.037 0.63671E+03 71 hedenbergite 14.21 12.96 -1.25 -0.125 0.21275E+04 76 clinoenstatite 17.17 12.22 -4.95 -0.495 0.84535E+04 78 epidote 24.67 22.56 -2.11 -0.102 0.36030E+04 79 clinozoisite 22.81 18.32 -4.48 -0.204 0.76539E+04 80 epidote-Fe 29.84 26.80 -3.04 -0.158 0.51987E+04 81 fayalite 14.05 9.65 -4.39 -0.628 0.75027E+04 82 ferrosilite 11.15 6.52 -4.63 -0.463 0.78995E+04 86 gibbsite 4.08 0.68 -3.40 -0.485 0.57982E+04 87 glaucophane 22.97 20.68 -2.29 -0.062 0.39115E+04 89 graphite -3.55 -8.21 -4.67 -1.333 0.79681E+04 90 greenalite 16.14 12.91 -3.23 -0.269 0.55089E+04 93 hematite 12.57 9.84 -2.73 -0.330 0.46554E+04 94 heulandite -5.83 -7.70 -1.88 -0.085 0.32045E+04 98 jadeite 4.22 2.74 -1.47 -0.147 0.25108E+04 100 kalsilite 7.58 3.77 -3.81 -0.545 0.65112E+04 101 kaolinite -1.33 -4.89 -3.56 -0.323 0.60743E+04 104 laumontite 2.88 1.68 -1.20 -0.080 0.20516E+04 105 lawsonite 9.62 7.94 -1.68 -0.112 0.28633E+04 106 leucite 4.12 0.64 -3.48 -0.348 0.59368E+04 108 lizardite 23.24 21.45 -1.79 -0.149 0.30600E+04 110 magnetite 20.09 16.23 -3.86 -0.315 0.65866E+04 111 minnesotaite 10.39 6.66 -3.73 -0.220 0.63726E+04 115 manganosite 14.06 9.23 -4.82 -1.206 0.82354E+04 119 microcline -2.49 -2.49 0.00 0.000 0.37765E+00 123 muscovite 2.58 -1.12 -3.70 -0.218 0.63212E+04 124 paragonite 4.24 0.98 -3.26 -0.192 0.55600E+04 125 nepheline 8.34 5.87 -2.47 -0.352 0.42107E+04 137 phlogopite-Na 29.65 27.33 -2.32 -0.129 0.39641E+04 139 prehnite 19.37 17.64 -1.73 -0.102 0.29572E+04 140 prehnite-Fe 22.50 21.88 -0.62 -0.037 0.10613E+04 141 pumpellyite-Fe 46.27 42.35 -3.92 -0.087 0.66862E+04 142 pumpellyite-Mg 48.99 45.20 -3.80 -0.084 0.64801E+04 145 pyrite -21.25 -24.67 -3.42 -0.804 0.58377E+04 146 pyrrhotite -4.26 -7.67 -3.41 -1.136 0.58177E+04 147 pyrrhotiteFe0.875 -6.02 -8.83 -2.81 -1.035 0.48048E+04 148 pyroxmangite 7.40 6.11 -1.29 -0.258 0.22067E+04 149 pyrophyllite -6.18 -11.15 -4.97 -0.311 0.84891E+04 150 quartz -2.99 -3.13 -0.14 -0.046 0.23769E+03 154 rhodochrosite -0.98 -4.86 -3.88 -1.294 0.66296E+04 155 rhodonite 7.45 6.11 -1.34 -0.268 0.22870E+04 156 sanidine -1.28 -2.49 -1.21 -0.093 0.20681E+04 166 stilbite -7.52 -7.70 -0.18 -0.009 0.31071E+03 167 stilpnomelane-Fe 13.02 11.40 -1.62 -0.048 0.27668E+04 168 stilpnomelane-Mg 27.44 25.63 -1.81 -0.054 0.30973E+04 174 talc 16.49 15.19 -1.30 -0.076 0.22139E+04 177 tephroite 18.09 15.34 -2.74 -0.392 0.46863E+04 181 tridymite -2.63 -3.13 -0.50 -0.167 0.85767E+03 182 tremolite 47.87 46.81 -1.06 -0.029 0.18063E+04 184 troilite-low -4.41 -7.67 -3.26 -1.086 0.55606E+04 190 wairakite 3.95 1.68 -2.27 -0.133 0.38735E+04 191 walstromite 11.51 9.70 -1.81 -0.362 0.30879E+04 192 wollastonite 10.46 9.70 -0.76 -0.152 0.12983E+04 193 pseudo-wollastonite 11.00 9.70 -1.30 -0.260 0.22182E+04 194 zoisite 22.85 18.32 -4.53 -0.206 0.77279E+04 195 akaganeite 7.75 4.92 -2.83 -0.613 0.48402E+04 202 chalcedony -2.80 -3.13 -0.33 -0.109 0.55699E+03 204 montmorillonite-Ca -2.29 -6.21 -3.92 -0.242 0.66890E+04 205 montmorillonite-K -2.24 -6.27 -4.04 -0.247 0.68934E+04 206 montmorillonite-Mg -2.48 -6.80 -4.32 -0.267 0.73783E+04 207 montmorillonite-Na -2.04 -5.58 -3.54 -0.217 0.60482E+04 208 nontronite-Ca 3.21 0.70 -2.51 -0.163 0.42935E+04 209 nontronite-H 2.53 -1.42 -3.95 -0.265 0.67437E+04 210 nontronite-K 3.34 0.63 -2.71 -0.174 0.46210E+04 211 nontronite-Mg 3.07 0.11 -2.97 -0.193 0.50668E+04 212 nontronite-Na 3.52 1.33 -2.19 -0.141 0.37418E+04 228 tobermorite 9.82 7.56 -2.26 -0.618 0.38671E+04 234 alabandite -0.98 -4.82 -3.84 -1.282 0.65651E+04 237 boehmite 4.41 0.68 -3.72 -0.620 0.63566E+04 239 ferrous-oxide 9.81 6.39 -3.42 -0.855 0.58420E+04 245 silica-amorphous -2.09 -3.13 -1.04 -0.346 0.17712E+04 247 an20ab80 2.02 1.28 -0.74 -0.057 0.12585E+04 248 an25ab75 2.65 1.70 -0.95 -0.073 0.16201E+04 249 an30ab70 3.28 2.11 -1.17 -0.090 0.19913E+04 250 tr.625ac.25prg.125 45.16 44.18 -0.99 -0.027 0.16858E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 0.0002000 MOLES Current total amount of reactant added: 0.0039900 MOLES New total amount of reactant added: 0.0041900 MOLES Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.5508E-08 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 7 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 0.0041900 Water: Moles liquid = 0.4985E+02 kg liquid = 0.8981E+00 Moles total = 0.4985E+02 kg total = 0.8981E+00 Activity = 1.0000 Stoichiometric ionic strength = .1159781E-01 Osmotic coef. = 0.9577 True ionic strength = .2026280E-01 Chg. balance for total moles = -.5508E-08 Max. difference allowed = 0.1626E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.95200E-10 -10.0214 0.79932E-10 -10.0973 0.83962E+00 -0.0759 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.18022E-03 -3.7442 0.15040E-03 -3.8228 0.83453E+00 -0.0786 4 SO4-- 0.56658E-05 -5.2467 0.29330E-05 -5.5327 0.51767E+00 -0.2859 5 HCO3- 0.12708E-03 -3.8959 0.10621E-03 -3.9738 0.83576E+00 -0.0779 6 HS- 0.13606E-03 -3.8663 0.11356E-03 -3.9448 0.83465E+00 -0.0785 7 Al+++ 0.10675E-28 -28.9717 0.24483E-29 -29.6111 0.22936E+00 -0.6395 8 H4SiO4 0.74615E-03 -3.1272 0.74615E-03 -3.1272 0.10000E+01 0.0000 9 Ca++ 0.82320E-07 -7.0845 0.42299E-07 -7.3737 0.51383E+00 -0.2892 10 Mg++ 0.21383E-10 -10.6699 0.10936E-10 -10.9611 0.51146E+00 -0.2912 11 Fe++ 0.30783E-13 -13.5117 0.15761E-13 -13.8024 0.51202E+00 -0.2907 12 K+ 0.15654E-03 -3.8054 0.13086E-03 -3.8832 0.83596E+00 -0.0778 13 Na+ 0.19876E-01 -1.7017 0.16584E-01 -1.7803 0.83437E+00 -0.0786 14 Mn++ 0.21405E-10 -10.6695 0.10969E-10 -10.9598 0.51245E+00 -0.2903 15 F- 0.19711E-05 -5.7053 0.16415E-05 -5.7848 0.83279E+00 -0.0795 16 HPO4-- 0.45380E-07 -7.3431 0.23495E-07 -7.6290 0.51774E+00 -0.2859 18 HSiO3- 0.10444E-01 -1.9811 0.87162E-02 -2.0597 0.83453E+00 -0.0786 19 Ca(HSiO3)+ 0.10042E-07 -7.9982 0.83963E-08 -8.0759 0.83614E+00 -0.0777 20 Mg(HSiO3)+ 0.32311E-11 -11.4906 0.27017E-11 -11.5684 0.83614E+00 -0.0777 21 NaHSiO3,aq 0.23378E-02 -2.6312 0.23378E-02 -2.6312 0.10000E+01 0.0000 22 AlO+ 0.62348E-16 -16.2052 0.52132E-16 -16.2829 0.83614E+00 -0.0777 24 HAlO2,aq 0.12988E-09 -9.8864 0.12988E-09 -9.8864 0.10000E+01 0.0000 25 AlO2- 0.43180E-05 -5.3647 0.35969E-05 -5.4441 0.83301E+00 -0.0794 26 CH4,aq 0.40089E-08 -8.3970 0.39948E-08 -8.3985 0.99646E+00 -0.0015 31 CO,aq 0.14487E-15 -15.8390 0.14487E-15 -15.8390 0.10000E+01 0.0000 32 CO2,aq 0.18205E-07 -7.7398 0.18140E-07 -7.7414 0.99646E+00 -0.0015 33 CO3-2 0.22468E-03 -3.6484 0.11606E-03 -3.9353 0.51656E+00 -0.2869 34 CaCO3,aq 0.61557E-07 -7.2107 0.61557E-07 -7.2107 0.10000E+01 0.0000 35 Ca(HCO3)+ 0.13715E-09 -9.8628 0.11468E-09 -9.9405 0.83614E+00 -0.0777 36 CaCl+ 0.12313E-10 -10.9096 0.10295E-10 -10.9874 0.83614E+00 -0.0777 37 CaCl2,aq 0.36787E-15 -15.4343 0.36787E-15 -15.4343 0.10000E+01 0.0000 38 CaF+ 0.12124E-11 -11.9164 0.10137E-11 -11.9941 0.83614E+00 -0.0777 39 CaOH+ 0.45105E-07 -7.3458 0.37714E-07 -7.4235 0.83614E+00 -0.0777 40 CaSO4,aq 0.39395E-10 -10.4046 0.39395E-10 -10.4046 0.10000E+01 0.0000 41 HCl,aq 0.22030E-14 -14.6570 0.22030E-14 -14.6570 0.10000E+01 0.0000 45 HF,aq 0.89821E-12 -12.0466 0.89821E-12 -12.0466 0.10000E+01 0.0000 46 HF2- 0.59650E-18 -18.2244 0.49780E-18 -18.3029 0.83453E+00 -0.0786 48 FeCl+ 0.44875E-17 -17.3480 0.37522E-17 -17.4257 0.83614E+00 -0.0777 51 FeF+ 0.15812E-17 -17.8010 0.13221E-17 -17.8787 0.83614E+00 -0.0777 53 FeO,aq 0.95878E-10 -10.0183 0.95878E-10 -10.0183 0.10000E+01 0.0000 54 FeOH+ 0.76764E-11 -11.1148 0.64186E-11 -11.1926 0.83614E+00 -0.0777 55 HFeO2- 0.15039E-07 -7.8228 0.12550E-07 -7.9013 0.83453E+00 -0.0786 56 FeO+ 0.32474E-16 -16.4885 0.27153E-16 -16.5662 0.83614E+00 -0.0777 58 FeO2- 0.10420E-08 -8.9821 0.86962E-09 -9.0607 0.83453E+00 -0.0786 59 HFeO2,aq 0.88407E-11 -11.0535 0.88407E-11 -11.0535 0.10000E+01 0.0000 60 H2,aq 0.31902E-06 -6.4962 0.31790E-06 -6.4977 0.99646E+00 -0.0015 61 KCl,aq 0.35672E-09 -9.4477 0.35672E-09 -9.4477 0.10000E+01 0.0000 62 KHSO4,aq 0.86743E-19 -19.0618 0.86743E-19 -19.0618 0.10000E+01 0.0000 63 KOH,aq 0.69917E-06 -6.1554 0.69917E-06 -6.1554 0.10000E+01 0.0000 64 KSO4- 0.71369E-08 -8.1465 0.59560E-08 -8.2250 0.83453E+00 -0.0786 65 MgCO3,aq 0.39894E-11 -11.3991 0.39894E-11 -11.3991 0.10000E+01 0.0000 66 Mg(HCO3)+ 0.36234E-13 -13.4409 0.30297E-13 -13.5186 0.83614E+00 -0.0777 67 MgCl+ 0.28853E-14 -14.5398 0.24126E-14 -14.6175 0.83614E+00 -0.0777 68 MgF+ 0.11612E-14 -14.9351 0.97090E-15 -15.0128 0.83614E+00 -0.0777 69 MgOH+ 0.64532E-10 -10.1902 0.53958E-10 -10.2679 0.83614E+00 -0.0777 71 MnF+ 0.36272E-15 -15.4404 0.30329E-15 -15.5181 0.83614E+00 -0.0777 72 MnO,aq 0.17780E-08 -8.7501 0.17780E-08 -8.7501 0.10000E+01 0.0000 73 MnOH+ 0.49630E-09 -9.3043 0.41497E-09 -9.3820 0.83614E+00 -0.0777 74 MnO2-2 0.17879E-10 -10.7477 0.92353E-11 -11.0345 0.51656E+00 -0.2869 75 HMnO2- 0.19380E-09 -9.7127 0.16173E-09 -9.7912 0.83453E+00 -0.0786 78 MnCl+ 0.12150E-13 -13.9154 0.10159E-13 -13.9931 0.83614E+00 -0.0777 79 MnSO4,aq 0.92880E-14 -14.0321 0.92880E-14 -14.0321 0.10000E+01 0.0000 80 NaCl,aq 0.82658E-06 -6.0827 0.82658E-06 -6.0827 0.10000E+01 0.0000 81 NaF,aq 0.63732E-08 -8.1956 0.63732E-08 -8.1956 0.10000E+01 0.0000 82 NaOH,aq 0.89140E-04 -4.0499 0.89140E-04 -4.0499 0.10000E+01 0.0000 84 OH- 0.86774E-02 -2.0616 0.72283E-02 -2.1410 0.83301E+00 -0.0794 89 HPO3-2 0.45060E-16 -16.3462 0.23276E-16 -16.6331 0.51656E+00 -0.2869 92 H3PO4,aq 0.10499E-17 -17.9789 0.10499E-17 -17.9789 0.10000E+01 0.0000 93 H2PO4- 0.41474E-10 -10.3822 0.34645E-10 -10.4604 0.83533E+00 -0.0781 94 PO4-3 0.99508E-09 -9.0021 0.23982E-09 -9.6201 0.24101E+00 -0.6180 98 HP2O7-3 0.10240E-17 -17.9897 0.23510E-18 -18.6288 0.22959E+00 -0.6390 99 P2O7-4 0.92283E-17 -17.0349 0.70264E-18 -18.1533 0.76140E-01 -1.1184 100 H2S,aq 0.28155E-07 -7.5505 0.28055E-07 -7.5520 0.99646E+00 -0.0015 101 S2-2 0.17403E-11 -11.7594 0.89894E-12 -12.0463 0.51656E+00 -0.2869 102 S3-2 0.20691E-18 -18.6842 0.10688E-18 -18.9711 0.51656E+00 -0.2869 107 SO3-2 0.23118E-12 -12.6360 0.12116E-12 -12.9166 0.52410E+00 -0.2806 108 HSO3- 0.72663E-15 -15.1387 0.60639E-15 -15.2172 0.83453E+00 -0.0786 109 HSO4- 0.26995E-12 -12.5687 0.22593E-12 -12.6460 0.83696E+00 -0.0773 111 S2O3-2 0.18712E-14 -14.7279 0.96659E-15 -15.0148 0.51656E+00 -0.2869 Charge balance for all species = -.6132E-08 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.9519995E-10 -.2179169E-01 -.2192622E+02 0.0000 2 H2O 0.1000000E+01 0.5550424E+02 0.9981729E+06 0.0000 3 Cl- 0.1802223E-03 0.1810493E-03 0.6407489E+01 6.2745 4 SO4-- 0.5665795E-05 0.5589338E-05 0.5359796E+00 14.6619 5 HCO3- 0.1270833E-03 0.3518513E-03 0.2143135E+02 6.1234 6 HS- 0.1360622E-03 0.1361740E-03 0.4495654E+01 6.1525 7 Al+++ 0.1067451E-28 0.4318112E-05 0.1163049E+00 0.6807 8 H4SiO4 0.7461457E-03 0.1352850E-01 0.1298018E+04 -3.1272 9 Ca++ 0.8232002E-07 0.1992140E-06 0.7970105E-02 12.8209 10 Mg++ 0.2138269E-10 0.9317536E-10 0.2261309E-05 9.2334 11 Fe++ 0.3078266E-13 0.1619337E-07 0.9027659E-03 6.3922 12 K+ 0.1565422E-03 0.1572489E-03 0.6137967E+01 6.2141 13 Na+ 0.1987555E-01 0.2230337E-01 0.5118513E+03 8.3170 14 Mn++ 0.2140541E-10 0.2507373E-08 0.1375086E-03 9.2347 15 F- 0.1971074E-05 0.1977449E-05 0.3750173E-01 4.3125 16 HPO4-- 0.4538027E-07 0.4641683E-07 0.4447231E-02 12.5655 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.1957538E-01 -.1957170E-01 -.3679337E-05 0.0000000E+00 2 H2O 0.4984984E+02 0.4984984E+02 -.3592009E-05 0.0000000E+00 3 Cl- 0.1626052E-03 0.1626052E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.5022190E-05 0.5019934E-05 0.2256072E-08 0.0000000E+00 5 HCO3- 0.3160070E-03 0.3160070E-03 0.0000000E+00 0.0000000E+00 6 HS- 0.1222993E-03 0.1223015E-03 -.2256072E-08 0.0000000E+00 7 Al+++ 0.4775352E-05 0.3878212E-05 0.8971404E-06 0.0000000E+00 8 H4SiO4 0.1215302E-01 0.1215030E-01 0.2716403E-05 0.0000000E+00 9 Ca++ 0.2080835E-06 0.1789194E-06 0.2916406E-07 0.0000000E+00 10 Mg++ 0.8368328E-10 0.8368328E-10 0.0000000E+00 0.0000000E+00 11 Fe++ 0.3259227E-07 0.1454370E-07 0.1804857E-07 0.0000000E+00 12 K+ 0.1412294E-03 0.1412294E-03 0.0000000E+00 0.0000000E+00 13 Na+ 0.2003215E-01 0.2003125E-01 0.8957463E-06 0.0000000E+00 14 Mn++ 0.2251939E-08 0.2251939E-08 0.0000000E+00 0.0000000E+00 15 F- 0.1776000E-05 0.1776000E-05 0.0000000E+00 0.0000000E+00 16 HPO4-- 0.4168819E-07 0.4168819E-07 0.0000000E+00 0.0000000E+00 Chg. balance for solid moles: -.1059E-21 Mass of aqueous solution: 0.899704E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 0.0041900 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 0.8957E-06 -6.048 0.2349E-03 -3.629 97.96 0.9017E-04 andradite 0.9024E-08 -8.045 0.4586E-05 -5.339 1.913 0.1191E-05 grossular 0.6971E-09 -9.157 0.3140E-06 -6.503 0.1309 0.8737E-07 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.9283E+00 0.9283E+00 1.0000 -0.032 grossular 0.7170E-01 0.7170E-01 1.0000 -1.144 Solid products produced: Mass = 0.000240 g Volume = 0.000091 cm3 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.0041900 moles log = -2.3778 Original solution: 1000.0103000 g Original solution / Rock added: 238665.94 (Water/Rock Ratio), log = 5.3778 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0207 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9996E+00 0.9859 0.1006E+01 0.1020E+01 CO2,gas 0.1888E-05 1.0071 0.1941E-05 0.1927E-05 CH4,gas 0.5689E-05 1.0125 0.5880E-05 0.5807E-05 H2,gas 0.4087E-03 1.0005 0.4174E-03 0.4171E-03 H2S,gas 0.7586E-06 0.9960 0.7712E-06 0.7743E-06 S2,gas 0.1256E-24 1.0000 0.1282E-24 0.1282E-24 CO,gas 0.2115E-12 1.0000 0.2159E-12 0.2159E-12 SO3,gas 0.6942E-41 1.0000 0.7085E-41 0.7085E-41 SO2,gas 0.1127E-21 1.0000 0.1150E-21 0.1150E-21 HF,gas 0.2161E-14 1.0000 0.2205E-14 0.2205E-14 HCl,gas 0.3808E-17 1.0000 0.3887E-17 0.3887E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 17 albite -0.38 -0.38 0.00 0.000 -0.94784E-12 23 andradite 39.01 39.01 0.00 0.000 0.12132E-10 24 grossular 32.73 32.73 0.00 0.000 0.12132E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -14.07 -7.41 -2.470 0.12654E+05 -5.712 3 CH4,gas 4.54 -2.39 -6.93 -1.732 0.11832E+05 -5.231 4 H2,gas 8.00 2.92 -5.08 -2.902 0.86713E+04 -3.379 5 H2S,gas -6.23 -14.04 -7.81 -3.906 0.13338E+05 -6.113 6 S2,gas -7.34 -33.93 -26.59 -4.091 0.45404E+05 -24.892 7 CO,gas 3.21 -11.15 -14.36 -4.420 0.24527E+05 -12.666 8 SO3,gas 17.12 -25.73 -42.85 -10.712 0.73163E+05 -41.150 9 SO2,gas 0.83 -22.81 -23.64 -6.303 0.40361E+05 -21.939 10 HF,gas 0.47 -15.88 -16.36 -8.178 0.27927E+05 -14.657 11 HCl,gas 5.19 -13.92 -19.11 -9.555 0.32629E+05 -17.410 12 acmite 7.71 6.99 -0.72 -0.074 0.12219E+04 16 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 20 spessartine 24.46 19.68 -4.77 -0.239 0.81502E+04 21 analcite 3.32 2.74 -0.58 -0.064 0.98786E+03 27 annite 20.12 16.69 -3.43 -0.191 0.58629E+04 28 phlogopite 27.06 25.21 -1.85 -0.103 0.31606E+04 30 anorthite 12.71 7.93 -4.78 -0.368 0.81658E+04 33 apatite-OH -18.15 -19.37 -1.21 -0.093 0.20709E+04 34 apatite-F -34.30 -35.25 -0.95 -0.079 0.16176E+04 38 aragonite 0.97 -1.25 -2.22 -0.739 0.37850E+04 39 brucite 12.57 9.23 -3.34 -0.667 0.56947E+04 40 calcite 0.81 -1.25 -2.06 -0.687 0.35208E+04 41 carnegieite-low 9.02 5.87 -3.15 -0.450 0.53833E+04 42 carnegieite-high 10.09 5.87 -4.22 -0.603 0.72103E+04 43 carpholite-Mg 8.58 4.34 -4.24 -0.283 0.72424E+04 45 celadonite 5.34 3.62 -1.72 -0.101 0.29404E+04 46 celadonite-Fe 3.88 0.78 -3.10 -0.182 0.52902E+04 47 chrysotile 23.89 21.45 -2.45 -0.204 0.41773E+04 49 clinochlore 39.07 38.15 -0.92 -0.029 0.15751E+04 52 chlorite-Al-free 47.17 42.89 -4.28 -0.178 0.73097E+04 54 chloritoid-Fe 9.17 4.63 -4.55 -0.303 0.77643E+04 55 chloritoid-Mn 11.40 7.47 -3.93 -0.262 0.67140E+04 57 coesite -2.38 -3.13 -0.75 -0.250 0.12825E+04 64 cristobalite -2.56 -3.13 -0.57 -0.189 0.96786E+03 66 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71238E+04 68 diaspore 2.87 0.68 -2.19 -0.365 0.37445E+04 70 diopside 16.18 15.80 -0.38 -0.038 0.65123E+03 71 hedenbergite 14.21 12.96 -1.25 -0.125 0.21337E+04 76 clinoenstatite 17.17 12.21 -4.95 -0.495 0.84584E+04 78 epidote 24.67 22.55 -2.12 -0.103 0.36143E+04 79 clinozoisite 22.81 18.30 -4.50 -0.205 0.76899E+04 80 epidote-Fe 29.84 26.80 -3.04 -0.158 0.51854E+04 81 fayalite 14.05 9.66 -4.39 -0.627 0.74934E+04 82 ferrosilite 11.15 6.53 -4.62 -0.462 0.78877E+04 86 gibbsite 4.08 0.68 -3.40 -0.486 0.58030E+04 87 glaucophane 22.97 20.68 -2.30 -0.062 0.39214E+04 89 graphite -3.55 -8.23 -4.68 -1.338 0.79949E+04 90 greenalite 16.14 12.92 -3.22 -0.268 0.54936E+04 93 hematite 12.57 9.86 -2.70 -0.328 0.46156E+04 94 heulandite -5.83 -7.71 -1.88 -0.085 0.32112E+04 98 jadeite 4.22 2.74 -1.47 -0.147 0.25133E+04 100 kalsilite 7.58 3.77 -3.82 -0.545 0.65162E+04 101 kaolinite -1.33 -4.89 -3.56 -0.324 0.60789E+04 104 laumontite 2.88 1.67 -1.21 -0.081 0.20657E+04 105 lawsonite 9.62 7.93 -1.69 -0.113 0.28824E+04 106 leucite 4.12 0.64 -3.48 -0.348 0.59393E+04 108 lizardite 23.24 21.45 -1.80 -0.150 0.30699E+04 110 magnetite 20.09 16.26 -3.83 -0.313 0.65434E+04 111 minnesotaite 10.39 6.67 -3.72 -0.219 0.63524E+04 115 manganosite 14.06 9.23 -4.82 -1.206 0.82358E+04 119 microcline -2.49 -2.49 0.00 0.000 0.40225E+00 123 muscovite 2.58 -1.13 -3.71 -0.218 0.63309E+04 124 paragonite 4.24 0.98 -3.26 -0.192 0.55696E+04 125 nepheline 8.34 5.87 -2.47 -0.353 0.42157E+04 137 phlogopite-Na 29.65 27.32 -2.33 -0.129 0.39790E+04 139 prehnite 19.37 17.62 -1.75 -0.103 0.29885E+04 140 prehnite-Fe 22.50 21.87 -0.63 -0.038 0.10679E+04 141 pumpellyite-Fe 46.27 42.32 -3.95 -0.088 0.67501E+04 142 pumpellyite-Mg 48.99 45.16 -3.84 -0.085 0.65524E+04 145 pyrite -21.25 -24.61 -3.37 -0.792 0.57478E+04 146 pyrrhotite -4.26 -7.65 -3.39 -1.130 0.57876E+04 147 pyrrhotiteFe0.875 -6.02 -8.81 -2.79 -1.028 0.47710E+04 148 pyroxmangite 7.40 6.11 -1.29 -0.258 0.22046E+04 149 pyrophyllite -6.18 -11.15 -4.97 -0.311 0.84887E+04 150 quartz -2.99 -3.13 -0.14 -0.046 0.23519E+03 154 rhodochrosite -0.98 -4.84 -3.86 -1.287 0.65909E+04 155 rhodonite 7.45 6.11 -1.34 -0.268 0.22848E+04 156 sanidine -1.28 -2.49 -1.21 -0.093 0.20682E+04 166 stilbite -7.52 -7.71 -0.19 -0.009 0.31741E+03 167 stilpnomelane-Fe 13.02 11.41 -1.61 -0.048 0.27408E+04 168 stilpnomelane-Mg 27.44 25.62 -1.82 -0.054 0.31131E+04 174 talc 16.49 15.19 -1.30 -0.076 0.22188E+04 177 tephroite 18.09 15.34 -2.74 -0.392 0.46845E+04 181 tridymite -2.63 -3.13 -0.50 -0.167 0.85517E+03 182 tremolite 47.87 46.79 -1.08 -0.029 0.18402E+04 184 troilite-low -4.41 -7.65 -3.24 -1.080 0.55304E+04 190 wairakite 3.95 1.67 -2.28 -0.134 0.38877E+04 191 walstromite 11.51 9.69 -1.82 -0.363 0.31000E+04 192 wollastonite 10.46 9.69 -0.77 -0.153 0.13104E+04 193 pseudo-wollastonite 11.00 9.69 -1.31 -0.261 0.22302E+04 194 zoisite 22.85 18.30 -4.55 -0.207 0.77640E+04 195 akaganeite 7.75 4.93 -2.82 -0.610 0.48203E+04 202 chalcedony -2.80 -3.13 -0.32 -0.108 0.55449E+03 204 montmorillonite-Ca -2.29 -6.21 -3.92 -0.242 0.66911E+04 205 montmorillonite-K -2.24 -6.27 -4.04 -0.247 0.68940E+04 206 montmorillonite-Mg -2.48 -6.80 -4.32 -0.267 0.73789E+04 207 montmorillonite-Na -2.04 -5.58 -3.54 -0.217 0.60487E+04 208 nontronite-Ca 3.21 0.73 -2.49 -0.161 0.42485E+04 209 nontronite-H 2.53 -1.39 -3.92 -0.263 0.66964E+04 210 nontronite-K 3.34 0.66 -2.68 -0.172 0.45746E+04 211 nontronite-Mg 3.07 0.13 -2.94 -0.191 0.50203E+04 212 nontronite-Na 3.52 1.36 -2.16 -0.139 0.36953E+04 228 tobermorite 9.82 7.55 -2.27 -0.619 0.38767E+04 234 alabandite -0.98 -4.81 -3.83 -1.276 0.65387E+04 237 boehmite 4.41 0.68 -3.73 -0.621 0.63614E+04 239 ferrous-oxide 9.81 6.39 -3.42 -0.855 0.58386E+04 245 silica-amorphous -2.09 -3.13 -1.04 -0.345 0.17687E+04 247 an20ab80 2.02 1.28 -0.74 -0.057 0.12623E+04 248 an25ab75 2.65 1.69 -0.95 -0.073 0.16249E+04 249 an30ab70 3.28 2.11 -1.17 -0.090 0.19970E+04 250 tr.625ac.25prg.125 45.16 44.16 -1.00 -0.027 0.17115E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 0.0002000 MOLES Current total amount of reactant added: 0.0041900 MOLES New total amount of reactant added: 0.0043900 MOLES Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.5508E-08 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 7 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 0.0043900 Water: Moles liquid = 0.4985E+02 kg liquid = 0.8981E+00 Moles total = 0.4985E+02 kg total = 0.8981E+00 Activity = 1.0000 Stoichiometric ionic strength = .1161061E-01 Osmotic coef. = 0.9572 True ionic strength = .2027460E-01 Chg. balance for total moles = -.5508E-08 Max. difference allowed = 0.1638E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.95549E-10 -10.0198 0.80222E-10 -10.0957 0.83959E+00 -0.0759 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.18153E-03 -3.7411 0.15149E-03 -3.8196 0.83450E+00 -0.0786 4 SO4-- 0.67246E-05 -5.1723 0.34806E-05 -5.4583 0.51759E+00 -0.2860 5 HCO3- 0.13320E-03 -3.8755 0.11132E-03 -3.9534 0.83573E+00 -0.0779 6 HS- 0.14041E-03 -3.8526 0.11719E-03 -3.9311 0.83462E+00 -0.0785 7 Al+++ 0.10725E-28 -28.9696 0.24590E-29 -29.6092 0.22928E+00 -0.6396 8 H4SiO4 0.74867E-03 -3.1257 0.74867E-03 -3.1257 0.10000E+01 0.0000 9 Ca++ 0.81365E-07 -7.0896 0.41802E-07 -7.3788 0.51375E+00 -0.2892 10 Mg++ 0.21397E-10 -10.6696 0.10942E-10 -10.9609 0.51138E+00 -0.2913 11 Fe++ 0.31257E-13 -13.5051 0.16002E-13 -13.7958 0.51194E+00 -0.2908 12 K+ 0.15654E-03 -3.8054 0.13086E-03 -3.8832 0.83593E+00 -0.0778 13 Na+ 0.19876E-01 -1.7017 0.16584E-01 -1.7803 0.83434E+00 -0.0787 14 Mn++ 0.21554E-10 -10.6665 0.11044E-10 -10.9569 0.51237E+00 -0.2904 15 F- 0.20599E-05 -5.6862 0.17154E-05 -5.7656 0.83276E+00 -0.0795 16 HPO4-- 0.45383E-07 -7.3431 0.23493E-07 -7.6291 0.51766E+00 -0.2860 18 HSiO3- 0.10442E-01 -1.9812 0.87141E-02 -2.0598 0.83450E+00 -0.0786 19 Ca(HSiO3)+ 0.99217E-08 -8.0034 0.82956E-08 -8.0812 0.83611E+00 -0.0777 20 Mg(HSiO3)+ 0.32322E-11 -11.4905 0.27025E-11 -11.5682 0.83611E+00 -0.0777 21 NaHSiO3,aq 0.23373E-02 -2.6313 0.23373E-02 -2.6313 0.10000E+01 0.0000 22 AlO+ 0.62170E-16 -16.2064 0.51981E-16 -16.2842 0.83611E+00 -0.0777 24 HAlO2,aq 0.12904E-09 -9.8893 0.12904E-09 -9.8893 0.10000E+01 0.0000 25 AlO2- 0.42746E-05 -5.3691 0.35607E-05 -5.4485 0.83297E+00 -0.0794 26 CH4,aq 0.36536E-08 -8.4373 0.36407E-08 -8.4388 0.99646E+00 -0.0015 31 CO,aq 0.14701E-15 -15.8326 0.14701E-15 -15.8326 0.10000E+01 0.0000 32 CO2,aq 0.19149E-07 -7.7179 0.19081E-07 -7.7194 0.99646E+00 -0.0015 33 CO3-2 0.23467E-03 -3.6295 0.12120E-03 -3.9165 0.51648E+00 -0.2869 34 CaCO3,aq 0.63527E-07 -7.1970 0.63527E-07 -7.1970 0.10000E+01 0.0000 35 Ca(HCO3)+ 0.14206E-09 -9.8475 0.11878E-09 -9.9253 0.83611E+00 -0.0777 36 CaCl+ 0.12256E-10 -10.9116 0.10248E-10 -10.9894 0.83611E+00 -0.0777 37 CaCl2,aq 0.36881E-15 -15.4332 0.36881E-15 -15.4332 0.10000E+01 0.0000 38 CaF+ 0.12521E-11 -11.9024 0.10469E-11 -11.9801 0.83611E+00 -0.0777 39 CaOH+ 0.44416E-07 -7.3525 0.37137E-07 -7.4302 0.83611E+00 -0.0777 40 CaSO4,aq 0.46201E-10 -10.3353 0.46201E-10 -10.3353 0.10000E+01 0.0000 41 HCl,aq 0.22269E-14 -14.6523 0.22269E-14 -14.6523 0.10000E+01 0.0000 45 HF,aq 0.94204E-12 -12.0259 0.94204E-12 -12.0259 0.10000E+01 0.0000 46 HF2- 0.65378E-18 -18.1846 0.54558E-18 -18.2631 0.83450E+00 -0.0786 48 FeCl+ 0.45889E-17 -17.3383 0.38368E-17 -17.4160 0.83611E+00 -0.0777 51 FeF+ 0.16776E-17 -17.7753 0.14027E-17 -17.8530 0.83611E+00 -0.0777 53 FeO,aq 0.96637E-10 -10.0149 0.96637E-10 -10.0149 0.10000E+01 0.0000 54 FeOH+ 0.77656E-11 -11.1098 0.64929E-11 -11.1876 0.83611E+00 -0.0777 55 HFeO2- 0.15104E-07 -7.8209 0.12604E-07 -7.8995 0.83450E+00 -0.0786 56 FeO+ 0.33446E-16 -16.4757 0.27964E-16 -16.5534 0.83611E+00 -0.0777 58 FeO2- 0.10655E-08 -8.9725 0.88913E-09 -9.0510 0.83450E+00 -0.0786 59 HFeO2,aq 0.90718E-11 -11.0423 0.90718E-11 -11.0423 0.10000E+01 0.0000 60 H2,aq 0.30779E-06 -6.5117 0.30670E-06 -6.5133 0.99646E+00 -0.0015 61 KCl,aq 0.35928E-09 -9.4446 0.35928E-09 -9.4446 0.10000E+01 0.0000 62 KHSO4,aq 0.10331E-18 -18.9859 0.10331E-18 -18.9859 0.10000E+01 0.0000 63 KOH,aq 0.69662E-06 -6.1570 0.69662E-06 -6.1570 0.10000E+01 0.0000 64 KSO4- 0.84694E-08 -8.0721 0.70677E-08 -8.1507 0.83450E+00 -0.0786 65 MgCO3,aq 0.41682E-11 -11.3801 0.41682E-11 -11.3801 0.10000E+01 0.0000 66 Mg(HCO3)+ 0.37997E-13 -13.4202 0.31770E-13 -13.4980 0.83611E+00 -0.0777 67 MgCl+ 0.29078E-14 -14.5364 0.24312E-14 -14.6142 0.83611E+00 -0.0777 68 MgF+ 0.12141E-14 -14.9157 0.10151E-14 -14.9935 0.83611E+00 -0.0777 69 MgOH+ 0.64335E-10 -10.1916 0.53791E-10 -10.2693 0.83611E+00 -0.0777 71 MnF+ 0.38163E-15 -15.4184 0.31909E-15 -15.4961 0.83611E+00 -0.0777 72 MnO,aq 0.17771E-08 -8.7503 0.17771E-08 -8.7503 0.10000E+01 0.0000 73 MnOH+ 0.49788E-09 -9.3029 0.41628E-09 -9.3806 0.83611E+00 -0.0777 74 MnO2-2 0.17744E-10 -10.7509 0.91645E-11 -11.0379 0.51648E+00 -0.2869 75 HMnO2- 0.19301E-09 -9.7144 0.16107E-09 -9.7930 0.83450E+00 -0.0786 78 MnCl+ 0.12321E-13 -13.9093 0.10302E-13 -13.9871 0.83611E+00 -0.0777 79 MnSO4,aq 0.11097E-13 -13.9548 0.11097E-13 -13.9548 0.10000E+01 0.0000 80 NaCl,aq 0.83254E-06 -6.0796 0.83254E-06 -6.0796 0.10000E+01 0.0000 81 NaF,aq 0.66599E-08 -8.1765 0.66599E-08 -8.1765 0.10000E+01 0.0000 82 NaOH,aq 0.88818E-04 -4.0515 0.88818E-04 -4.0515 0.10000E+01 0.0000 84 OH- 0.86463E-02 -2.0632 0.72022E-02 -2.1425 0.83297E+00 -0.0794 89 HPO3-2 0.43477E-16 -16.3617 0.22455E-16 -16.6487 0.51648E+00 -0.2869 92 H3PO4,aq 0.10574E-17 -17.9757 0.10574E-17 -17.9757 0.10000E+01 0.0000 93 H2PO4- 0.41623E-10 -10.3807 0.34767E-10 -10.4588 0.83529E+00 -0.0782 94 PO4-3 0.99172E-09 -9.0036 0.23894E-09 -9.6217 0.24093E+00 -0.6181 98 HP2O7-3 0.10279E-17 -17.9881 0.23591E-18 -18.6273 0.22951E+00 -0.6392 99 P2O7-4 0.92323E-17 -17.0347 0.70252E-18 -18.1533 0.76094E-01 -1.1186 100 H2S,aq 0.29159E-07 -7.5352 0.29056E-07 -7.5368 0.99646E+00 -0.0015 101 S2-2 0.19211E-11 -11.7165 0.99219E-12 -12.0034 0.51648E+00 -0.2869 102 S3-2 0.24519E-18 -18.6105 0.12664E-18 -18.8974 0.51648E+00 -0.2869 107 SO3-2 0.26472E-12 -12.5772 0.13872E-12 -12.8579 0.52402E+00 -0.2806 108 HSO3- 0.83498E-15 -15.0783 0.69679E-15 -15.1569 0.83450E+00 -0.0786 109 HSO4- 0.32152E-12 -12.4928 0.26909E-12 -12.5701 0.83693E+00 -0.0773 111 S2O3-2 0.23001E-14 -14.6382 0.11880E-14 -14.9252 0.51648E+00 -0.2869 Charge balance for all species = -.6132E-08 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.9554858E-10 -.2176746E-01 -.2190182E+02 0.0000 2 H2O 0.1000000E+01 0.5550422E+02 0.9981716E+06 0.0000 3 Cl- 0.1815295E-03 0.1823624E-03 0.6453958E+01 6.2761 4 SO4-- 0.6724600E-05 0.6652649E-05 0.6379434E+00 14.7331 5 HCO3- 0.1331961E-03 0.3679500E-03 0.2241191E+02 6.1423 6 HS- 0.1404118E-03 0.1405214E-03 0.4639175E+01 6.1646 7 Al+++ 0.1072477E-28 0.4274764E-05 0.1151373E+00 0.6779 8 H4SiO4 0.7486693E-03 0.1352831E-01 0.1297999E+04 -3.1257 9 Ca++ 0.8136532E-07 0.1994316E-06 0.7978801E-02 12.8126 10 Mg++ 0.2139737E-10 0.9317501E-10 0.2261298E-05 9.2305 11 Fe++ 0.3125674E-13 0.1628277E-07 0.9077493E-03 6.3956 12 K+ 0.1565428E-03 0.1572483E-03 0.6137939E+01 6.2125 13 Na+ 0.1987631E-01 0.2230324E-01 0.5118480E+03 8.3154 14 Mn++ 0.2155425E-10 0.2507364E-08 0.1375080E-03 9.2345 15 F- 0.2059854E-05 0.2066516E-05 0.3919082E-01 4.3301 16 HPO4-- 0.4538330E-07 0.4641665E-07 0.4447211E-02 12.5624 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.1955385E-01 -.1955001E-01 -.3834512E-05 0.0000000E+00 2 H2O 0.4985000E+02 0.4985001E+02 -.3747839E-05 0.0000000E+00 3 Cl- 0.1637852E-03 0.1637852E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.5977190E-05 0.5974944E-05 0.2246028E-08 0.0000000E+00 5 HCO3- 0.3304670E-03 0.3304670E-03 0.0000000E+00 0.0000000E+00 6 HS- 0.1262043E-03 0.1262065E-03 -.2246028E-08 0.0000000E+00 7 Al+++ 0.4775352E-05 0.3839295E-05 0.9360574E-06 0.0000000E+00 8 H4SiO4 0.1215302E-01 0.1215019E-01 0.2833109E-05 0.0000000E+00 9 Ca++ 0.2080835E-06 0.1791155E-06 0.2896802E-07 0.0000000E+00 10 Mg++ 0.8368328E-10 0.8368328E-10 0.0000000E+00 0.0000000E+00 11 Fe++ 0.3259227E-07 0.1462405E-07 0.1796822E-07 0.0000000E+00 12 K+ 0.1412294E-03 0.1412294E-03 0.0000000E+00 0.0000000E+00 13 Na+ 0.2003215E-01 0.2003122E-01 0.9347136E-06 0.0000000E+00 14 Mn++ 0.2251939E-08 0.2251939E-08 0.0000000E+00 0.0000000E+00 15 F- 0.1856000E-05 0.1856000E-05 0.0000000E+00 0.0000000E+00 16 HPO4-- 0.4168819E-07 0.4168819E-07 0.0000000E+00 0.0000000E+00 Chg. balance for solid moles: 0.5294E-21 Mass of aqueous solution: 0.899708E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 0.0043900 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 0.9347E-06 -6.029 0.2451E-03 -3.611 98.05 0.9409E-04 andradite 0.8984E-08 -8.047 0.4566E-05 -5.341 1.826 0.1186E-05 grossular 0.6719E-09 -9.173 0.3027E-06 -6.519 0.1211 0.8421E-07 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.9304E+00 0.9304E+00 1.0000 -0.031 grossular 0.6958E-01 0.6958E-01 1.0000 -1.157 Solid products produced: Mass = 0.000250 g Volume = 0.000095 cm3 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.0043900 moles log = -2.3575 Original solution: 1000.0103000 g Original solution / Rock added: 227792.78 (Water/Rock Ratio), log = 5.3575 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0207 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9996E+00 0.9859 0.1006E+01 0.1020E+01 CO2,gas 0.1986E-05 1.0071 0.2041E-05 0.2027E-05 CH4,gas 0.5185E-05 1.0125 0.5359E-05 0.5293E-05 H2,gas 0.3943E-03 1.0005 0.4027E-03 0.4024E-03 H2S,gas 0.7856E-06 0.9960 0.7987E-06 0.8019E-06 S2,gas 0.1447E-24 1.0000 0.1477E-24 0.1477E-24 CO,gas 0.2146E-12 1.0000 0.2191E-12 0.2191E-12 SO3,gas 0.8297E-41 1.0000 0.8469E-41 0.8469E-41 SO2,gas 0.1300E-21 1.0000 0.1327E-21 0.1327E-21 HF,gas 0.2266E-14 1.0000 0.2313E-14 0.2313E-14 HCl,gas 0.3850E-17 1.0000 0.3929E-17 0.3929E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 17 albite -0.38 -0.38 0.00 0.000 -0.94784E-12 23 andradite 39.01 39.01 0.00 0.000 -0.12132E-10 24 grossular 32.73 32.73 0.00 0.000 -0.12132E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -14.05 -7.39 -2.463 0.12617E+05 -5.690 3 CH4,gas 4.54 -2.43 -6.97 -1.742 0.11901E+05 -5.271 4 H2,gas 8.00 2.91 -5.09 -2.911 0.86979E+04 -3.395 5 H2S,gas -6.23 -14.03 -7.80 -3.898 0.13312E+05 -6.098 6 S2,gas -7.34 -33.87 -26.53 -4.081 0.45299E+05 -24.831 7 CO,gas 3.21 -11.14 -14.36 -4.418 0.24517E+05 -12.659 8 SO3,gas 17.12 -25.65 -42.77 -10.693 0.73031E+05 -41.072 9 SO2,gas 0.83 -22.74 -23.58 -6.287 0.40256E+05 -21.877 10 HF,gas 0.47 -15.86 -16.33 -8.167 0.27891E+05 -14.636 11 HCl,gas 5.19 -13.92 -19.10 -9.552 0.32621E+05 -17.406 12 acmite 7.71 7.01 -0.70 -0.073 0.12004E+04 16 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 20 spessartine 24.46 19.68 -4.78 -0.239 0.81534E+04 21 analcite 3.32 2.74 -0.58 -0.064 0.99036E+03 27 annite 20.12 16.70 -3.42 -0.190 0.58454E+04 28 phlogopite 27.06 25.20 -1.86 -0.103 0.31755E+04 30 anorthite 12.71 7.92 -4.79 -0.369 0.81846E+04 33 apatite-OH -18.15 -19.40 -1.24 -0.096 0.21256E+04 34 apatite-F -34.30 -35.26 -0.96 -0.080 0.16370E+04 38 aragonite 0.97 -1.24 -2.20 -0.734 0.37617E+04 39 brucite 12.57 9.23 -3.34 -0.668 0.56996E+04 40 calcite 0.81 -1.24 -2.05 -0.683 0.34975E+04 41 carnegieite-low 9.02 5.87 -3.16 -0.451 0.53883E+04 42 carnegieite-high 10.09 5.87 -4.23 -0.604 0.72153E+04 43 carpholite-Mg 8.58 4.33 -4.25 -0.283 0.72520E+04 45 celadonite 5.34 3.62 -1.72 -0.101 0.29429E+04 46 celadonite-Fe 3.88 0.78 -3.09 -0.182 0.52819E+04 47 chrysotile 23.89 21.44 -2.45 -0.204 0.41872E+04 49 clinochlore 39.07 38.13 -0.94 -0.029 0.16022E+04 52 chlorite-Al-free 47.17 42.88 -4.29 -0.179 0.73295E+04 54 chloritoid-Fe 9.17 4.63 -4.55 -0.303 0.77656E+04 55 chloritoid-Mn 11.40 7.46 -3.94 -0.262 0.67215E+04 57 coesite -2.38 -3.13 -0.75 -0.250 0.12800E+04 64 cristobalite -2.56 -3.13 -0.57 -0.188 0.96536E+03 66 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71238E+04 68 diaspore 2.87 0.68 -2.20 -0.366 0.37493E+04 70 diopside 16.18 15.79 -0.39 -0.039 0.66533E+03 71 hedenbergite 14.21 12.96 -1.25 -0.125 0.21369E+04 76 clinoenstatite 17.17 12.21 -4.96 -0.496 0.84634E+04 78 epidote 24.67 22.55 -2.12 -0.103 0.36256E+04 79 clinozoisite 22.81 18.28 -4.52 -0.206 0.77252E+04 80 epidote-Fe 29.84 26.81 -3.03 -0.157 0.51727E+04 81 fayalite 14.05 9.67 -4.38 -0.626 0.74792E+04 82 ferrosilite 11.15 6.54 -4.61 -0.461 0.78710E+04 86 gibbsite 4.08 0.68 -3.40 -0.486 0.58079E+04 87 glaucophane 22.97 20.67 -2.30 -0.062 0.39313E+04 89 graphite -3.55 -8.24 -4.69 -1.340 0.80106E+04 90 greenalite 16.14 12.94 -3.20 -0.267 0.54711E+04 93 hematite 12.57 9.89 -2.68 -0.325 0.45773E+04 94 heulandite -5.83 -7.71 -1.88 -0.086 0.32175E+04 98 jadeite 4.22 2.74 -1.47 -0.147 0.25159E+04 100 kalsilite 7.58 3.76 -3.82 -0.546 0.65212E+04 101 kaolinite -1.33 -4.90 -3.56 -0.324 0.60836E+04 104 laumontite 2.88 1.67 -1.22 -0.081 0.20795E+04 105 lawsonite 9.62 7.92 -1.70 -0.113 0.29012E+04 106 leucite 4.12 0.64 -3.48 -0.348 0.59418E+04 108 lizardite 23.24 21.44 -1.80 -0.150 0.30798E+04 110 magnetite 20.09 16.28 -3.81 -0.311 0.64993E+04 111 minnesotaite 10.39 6.68 -3.70 -0.218 0.63248E+04 115 manganosite 14.06 9.23 -4.82 -1.206 0.82361E+04 119 microcline -2.49 -2.49 0.00 0.000 0.42694E+00 123 muscovite 2.58 -1.13 -3.71 -0.218 0.63406E+04 124 paragonite 4.24 0.97 -3.27 -0.192 0.55792E+04 125 nepheline 8.34 5.87 -2.47 -0.353 0.42207E+04 137 phlogopite-Na 29.65 27.31 -2.34 -0.130 0.39939E+04 139 prehnite 19.37 17.60 -1.77 -0.104 0.30189E+04 140 prehnite-Fe 22.50 21.87 -0.63 -0.038 0.10743E+04 141 pumpellyite-Fe 46.27 42.28 -3.99 -0.089 0.68099E+04 142 pumpellyite-Mg 48.99 45.12 -3.88 -0.086 0.66230E+04 145 pyrite -21.25 -24.56 -3.32 -0.780 0.56634E+04 146 pyrrhotite -4.26 -7.63 -3.37 -1.124 0.57557E+04 147 pyrrhotiteFe0.875 -6.02 -8.79 -2.77 -1.020 0.47366E+04 148 pyroxmangite 7.40 6.11 -1.29 -0.258 0.22024E+04 149 pyrophyllite -6.18 -11.15 -4.97 -0.311 0.84883E+04 150 quartz -2.99 -3.13 -0.14 -0.045 0.23269E+03 154 rhodochrosite -0.98 -4.81 -3.84 -1.279 0.65538E+04 155 rhodonite 7.45 6.11 -1.34 -0.267 0.22826E+04 156 sanidine -1.28 -2.49 -1.21 -0.093 0.20682E+04 166 stilbite -7.52 -7.71 -0.19 -0.009 0.32367E+03 167 stilpnomelane-Fe 13.02 11.43 -1.58 -0.047 0.27025E+04 168 stilpnomelane-Mg 27.44 25.61 -1.83 -0.055 0.31289E+04 174 talc 16.49 15.19 -1.30 -0.077 0.22238E+04 177 tephroite 18.09 15.34 -2.74 -0.392 0.46826E+04 181 tridymite -2.63 -3.13 -0.50 -0.166 0.85266E+03 182 tremolite 47.87 46.77 -1.10 -0.030 0.18734E+04 184 troilite-low -4.41 -7.63 -3.22 -1.073 0.54986E+04 190 wairakite 3.95 1.67 -2.28 -0.134 0.39015E+04 191 walstromite 11.51 9.69 -1.82 -0.364 0.31116E+04 192 wollastonite 10.46 9.69 -0.77 -0.155 0.13220E+04 193 pseudo-wollastonite 11.00 9.69 -1.31 -0.263 0.22418E+04 194 zoisite 22.85 18.28 -4.57 -0.208 0.77992E+04 195 akaganeite 7.75 4.94 -2.81 -0.608 0.48012E+04 202 chalcedony -2.80 -3.13 -0.32 -0.108 0.55198E+03 204 montmorillonite-Ca -2.29 -6.21 -3.92 -0.242 0.66932E+04 205 montmorillonite-K -2.24 -6.27 -4.04 -0.247 0.68946E+04 206 montmorillonite-Mg -2.48 -6.80 -4.32 -0.267 0.73794E+04 207 montmorillonite-Na -2.04 -5.58 -3.54 -0.217 0.60493E+04 208 nontronite-Ca 3.21 0.75 -2.46 -0.160 0.42050E+04 209 nontronite-H 2.53 -1.36 -3.89 -0.261 0.66505E+04 210 nontronite-K 3.34 0.69 -2.65 -0.170 0.45296E+04 211 nontronite-Mg 3.07 0.16 -2.91 -0.189 0.49753E+04 212 nontronite-Na 3.52 1.38 -2.14 -0.137 0.36503E+04 228 tobermorite 9.82 7.55 -2.28 -0.621 0.38860E+04 234 alabandite -0.98 -4.79 -3.81 -1.271 0.65130E+04 237 boehmite 4.41 0.68 -3.73 -0.621 0.63662E+04 239 ferrous-oxide 9.81 6.40 -3.42 -0.854 0.58327E+04 245 silica-amorphous -2.09 -3.13 -1.03 -0.345 0.17662E+04 247 an20ab80 2.02 1.28 -0.74 -0.057 0.12661E+04 248 an25ab75 2.65 1.69 -0.95 -0.073 0.16296E+04 249 an30ab70 3.28 2.11 -1.17 -0.090 0.20026E+04 250 tr.625ac.25prg.125 45.16 44.15 -1.02 -0.027 0.17332E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 0.0002000 MOLES Current total amount of reactant added: 0.0043900 MOLES New total amount of reactant added: 0.0045900 MOLES Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.5508E-08 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 7 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 0.0045900 Water: Moles liquid = 0.4985E+02 kg liquid = 0.8981E+00 Moles total = 0.4985E+02 kg total = 0.8981E+00 Activity = 1.0000 Stoichiometric ionic strength = .1162341E-01 Osmotic coef. = 0.9566 True ionic strength = .2028637E-01 Chg. balance for total moles = -.5508E-08 Max. difference allowed = 0.1650E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.95899E-10 -10.0182 0.80514E-10 -10.0941 0.83956E+00 -0.0759 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.18284E-03 -3.7379 0.15257E-03 -3.8165 0.83446E+00 -0.0786 4 SO4-- 0.77841E-05 -5.1088 0.40283E-05 -5.3949 0.51751E+00 -0.2861 5 HCO3- 0.13934E-03 -3.8559 0.11644E-03 -3.9339 0.83570E+00 -0.0780 6 HS- 0.14476E-03 -3.8393 0.12082E-03 -3.9179 0.83459E+00 -0.0785 7 Al+++ 0.10775E-28 -28.9676 0.24697E-29 -29.6073 0.22920E+00 -0.6398 8 H4SiO4 0.75121E-03 -3.1242 0.75121E-03 -3.1242 0.10000E+01 0.0000 9 Ca++ 0.80458E-07 -7.0944 0.41329E-07 -7.3837 0.51367E+00 -0.2893 10 Mg++ 0.21412E-10 -10.6693 0.10948E-10 -10.9607 0.51130E+00 -0.2913 11 Fe++ 0.31809E-13 -13.4974 0.16282E-13 -13.7883 0.51186E+00 -0.2908 12 K+ 0.15654E-03 -3.8054 0.13085E-03 -3.8832 0.83590E+00 -0.0778 13 Na+ 0.19877E-01 -1.7016 0.16584E-01 -1.7803 0.83431E+00 -0.0787 14 Mn++ 0.21704E-10 -10.6635 0.11119E-10 -10.9539 0.51229E+00 -0.2905 15 F- 0.21486E-05 -5.6678 0.17892E-05 -5.7473 0.83273E+00 -0.0795 16 HPO4-- 0.45386E-07 -7.3431 0.23491E-07 -7.6291 0.51758E+00 -0.2860 18 HSiO3- 0.10440E-01 -1.9813 0.87120E-02 -2.0599 0.83446E+00 -0.0786 19 Ca(HSiO3)+ 0.98075E-08 -8.0084 0.81999E-08 -8.0862 0.83608E+00 -0.0778 20 Mg(HSiO3)+ 0.32332E-11 -11.4904 0.27032E-11 -11.5681 0.83608E+00 -0.0778 21 NaHSiO3,aq 0.23367E-02 -2.6314 0.23367E-02 -2.6314 0.10000E+01 0.0000 22 AlO+ 0.61993E-16 -16.2077 0.51831E-16 -16.2854 0.83608E+00 -0.0778 24 HAlO2,aq 0.12820E-09 -9.8921 0.12820E-09 -9.8921 0.10000E+01 0.0000 25 AlO2- 0.42316E-05 -5.3735 0.35247E-05 -5.4529 0.83294E+00 -0.0794 26 CH4,aq 0.34044E-08 -8.4680 0.33923E-08 -8.4695 0.99646E+00 -0.0015 31 CO,aq 0.14981E-15 -15.8245 0.14981E-15 -15.8245 0.10000E+01 0.0000 32 CO2,aq 0.20104E-07 -7.6967 0.20033E-07 -7.6983 0.99646E+00 -0.0015 33 CO3-2 0.24462E-03 -3.6115 0.12632E-03 -3.8985 0.51640E+00 -0.2870 34 CaCO3,aq 0.65464E-07 -7.1840 0.65464E-07 -7.1840 0.10000E+01 0.0000 35 Ca(HCO3)+ 0.14693E-09 -9.8329 0.12284E-09 -9.9107 0.83608E+00 -0.0778 36 CaCl+ 0.12205E-10 -10.9135 0.10204E-10 -10.9912 0.83608E+00 -0.0778 37 CaCl2,aq 0.36988E-15 -15.4319 0.36988E-15 -15.4319 0.10000E+01 0.0000 38 CaF+ 0.12913E-11 -11.8890 0.10796E-11 -11.9667 0.83608E+00 -0.0778 39 CaOH+ 0.43756E-07 -7.3590 0.36584E-07 -7.4367 0.83608E+00 -0.0778 40 CaSO4,aq 0.52867E-10 -10.2768 0.52867E-10 -10.2768 0.10000E+01 0.0000 41 HCl,aq 0.22510E-14 -14.6476 0.22510E-14 -14.6476 0.10000E+01 0.0000 45 HF,aq 0.98617E-12 -12.0060 0.98617E-12 -12.0060 0.10000E+01 0.0000 46 HF2- 0.71391E-18 -18.1464 0.59573E-18 -18.2249 0.83446E+00 -0.0786 48 FeCl+ 0.47029E-17 -17.3276 0.39320E-17 -17.4054 0.83608E+00 -0.0778 51 FeF+ 0.17806E-17 -17.7494 0.14887E-17 -17.8272 0.83608E+00 -0.0778 53 FeO,aq 0.97619E-10 -10.0105 0.97619E-10 -10.0105 0.10000E+01 0.0000 54 FeOH+ 0.78733E-11 -11.1038 0.65827E-11 -11.1816 0.83608E+00 -0.0778 55 HFeO2- 0.15203E-07 -7.8181 0.12686E-07 -7.8967 0.83446E+00 -0.0786 56 FeO+ 0.34419E-16 -16.4632 0.28777E-16 -16.5410 0.83608E+00 -0.0778 58 FeO2- 0.10886E-08 -8.9632 0.90836E-09 -9.0417 0.83446E+00 -0.0786 59 HFeO2,aq 0.93017E-11 -11.0314 0.93017E-11 -11.0314 0.10000E+01 0.0000 60 H2,aq 0.29875E-06 -6.5247 0.29769E-06 -6.5262 0.99646E+00 -0.0015 61 KCl,aq 0.36184E-09 -9.4415 0.36184E-09 -9.4415 0.10000E+01 0.0000 62 KHSO4,aq 0.12000E-18 -18.9208 0.12000E-18 -18.9208 0.10000E+01 0.0000 63 KOH,aq 0.69407E-06 -6.1586 0.69407E-06 -6.1586 0.10000E+01 0.0000 64 KSO4- 0.98023E-08 -8.0087 0.81797E-08 -8.0873 0.83446E+00 -0.0786 65 MgCO3,aq 0.43467E-11 -11.3618 0.43467E-11 -11.3618 0.10000E+01 0.0000 66 Mg(HCO3)+ 0.39770E-13 -13.4004 0.33251E-13 -13.4782 0.83608E+00 -0.0778 67 MgCl+ 0.29303E-14 -14.5331 0.24500E-14 -14.6108 0.83608E+00 -0.0778 68 MgF+ 0.12671E-14 -14.8972 0.10594E-14 -14.9749 0.83608E+00 -0.0778 69 MgOH+ 0.64139E-10 -10.1929 0.53625E-10 -10.2706 0.83608E+00 -0.0778 71 MnF+ 0.40079E-15 -15.3971 0.33509E-15 -15.4748 0.83608E+00 -0.0778 72 MnO,aq 0.17763E-08 -8.7505 0.17763E-08 -8.7505 0.10000E+01 0.0000 73 MnOH+ 0.49947E-09 -9.3015 0.41760E-09 -9.3792 0.83608E+00 -0.0778 74 MnO2-2 0.17610E-10 -10.7542 0.90939E-11 -11.0412 0.51640E+00 -0.2870 75 HMnO2- 0.19223E-09 -9.7162 0.16041E-09 -9.7948 0.83446E+00 -0.0786 78 MnCl+ 0.12495E-13 -13.9033 0.10446E-13 -13.9810 0.83608E+00 -0.0778 79 MnSO4,aq 0.12931E-13 -13.8884 0.12931E-13 -13.8884 0.10000E+01 0.0000 80 NaCl,aq 0.83851E-06 -6.0765 0.83851E-06 -6.0765 0.10000E+01 0.0000 81 NaF,aq 0.69467E-08 -8.1582 0.69467E-08 -8.1582 0.10000E+01 0.0000 82 NaOH,aq 0.88496E-04 -4.0531 0.88496E-04 -4.0531 0.10000E+01 0.0000 84 OH- 0.86154E-02 -2.0647 0.71761E-02 -2.1441 0.83294E+00 -0.0794 89 HPO3-2 0.42202E-16 -16.3747 0.21793E-16 -16.6617 0.51640E+00 -0.2870 92 H3PO4,aq 0.10650E-17 -17.9726 0.10650E-17 -17.9726 0.10000E+01 0.0000 93 H2PO4- 0.41772E-10 -10.3791 0.34891E-10 -10.4573 0.83526E+00 -0.0782 94 PO4-3 0.98837E-09 -9.0051 0.23805E-09 -9.6233 0.24085E+00 -0.6182 98 HP2O7-3 0.10318E-17 -17.9864 0.23673E-18 -18.6258 0.22943E+00 -0.6393 99 P2O7-4 0.92363E-17 -17.0345 0.70240E-18 -18.1534 0.76048E-01 -1.1189 100 H2S,aq 0.30170E-07 -7.5204 0.30063E-07 -7.5220 0.99646E+00 -0.0015 101 S2-2 0.21039E-11 -11.6770 0.10865E-11 -11.9640 0.51640E+00 -0.2870 102 S3-2 0.28625E-18 -18.5433 0.14782E-18 -18.8303 0.51640E+00 -0.2870 107 SO3-2 0.29742E-12 -12.5266 0.15583E-12 -12.8073 0.52395E+00 -0.2807 108 HSO3- 0.94143E-15 -15.0262 0.78559E-15 -15.1048 0.83446E+00 -0.0786 109 HSO4- 0.37348E-12 -12.4277 0.31257E-12 -12.5051 0.83690E+00 -0.0773 111 S2O3-2 0.27548E-14 -14.5599 0.14226E-14 -14.8469 0.51640E+00 -0.2870 Charge balance for all species = -.6132E-08 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.9589927E-10 -.2174323E-01 -.2187742E+02 0.0000 2 H2O 0.1000000E+01 0.5550419E+02 0.9981703E+06 0.0000 3 Cl- 0.1828367E-03 0.1836756E-03 0.6500426E+01 6.2776 4 SO4-- 0.7784053E-05 0.7715955E-05 0.7399066E+00 14.7934 5 HCO3- 0.1393358E-03 0.3840487E-03 0.2339246E+02 6.1602 6 HS- 0.1447607E-03 0.1448688E-03 0.4782695E+01 6.1763 7 Al+++ 0.1077539E-28 0.4231759E-05 0.1139789E+00 0.6750 8 H4SiO4 0.7512069E-03 0.1352813E-01 0.1297981E+04 -3.1242 9 Ca++ 0.8045801E-07 0.1996988E-06 0.7989487E-02 12.8045 10 Mg++ 0.2141211E-10 0.9317465E-10 0.2261288E-05 9.2276 11 Fe++ 0.3180923E-13 0.1640598E-07 0.9146172E-03 6.4000 12 K+ 0.1565434E-03 0.1572477E-03 0.6137911E+01 6.2109 13 Na+ 0.1987707E-01 0.2230312E-01 0.5118446E+03 8.3138 14 Mn++ 0.2170436E-10 0.2507354E-08 0.1375074E-03 9.2343 15 F- 0.2148633E-05 0.2155582E-05 0.4087989E-01 4.3468 16 HPO4-- 0.4538633E-07 0.4641647E-07 0.4447191E-02 12.5592 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.1953231E-01 -.1952832E-01 -.3988311E-05 0.0000000E+00 2 H2O 0.4985017E+02 0.4985017E+02 -.3902420E-05 0.0000000E+00 3 Cl- 0.1649652E-03 0.1649652E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.6932190E-05 0.6929958E-05 0.2232189E-08 0.0000000E+00 5 HCO3- 0.3449270E-03 0.3449270E-03 0.0000000E+00 0.0000000E+00 6 HS- 0.1301093E-03 0.1301115E-03 -.2232189E-08 0.0000000E+00 7 Al+++ 0.4775352E-05 0.3800685E-05 0.9746670E-06 0.0000000E+00 8 H4SiO4 0.1215302E-01 0.1215007E-01 0.2948846E-05 0.0000000E+00 9 Ca++ 0.2080835E-06 0.1793562E-06 0.2872732E-07 0.0000000E+00 10 Mg++ 0.8368328E-10 0.8368328E-10 0.0000000E+00 0.0000000E+00 11 Fe++ 0.3259227E-07 0.1473476E-07 0.1785751E-07 0.0000000E+00 12 K+ 0.1412294E-03 0.1412294E-03 0.0000000E+00 0.0000000E+00 13 Na+ 0.2003215E-01 0.2003118E-01 0.9733729E-06 0.0000000E+00 14 Mn++ 0.2251939E-08 0.2251939E-08 0.0000000E+00 0.0000000E+00 15 F- 0.1936000E-05 0.1936000E-05 0.0000000E+00 0.0000000E+00 16 HPO4-- 0.4168819E-07 0.4168819E-07 0.0000000E+00 0.0000000E+00 Chg. balance for solid moles: 0.2118E-21 Mass of aqueous solution: 0.899712E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 0.0045900 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 0.9734E-06 -6.012 0.2552E-03 -3.593 98.14 0.9798E-04 andradite 0.8929E-08 -8.049 0.4537E-05 -5.343 1.745 0.1179E-05 grossular 0.6470E-09 -9.189 0.2914E-06 -6.535 0.1121 0.8109E-07 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.9324E+00 0.9324E+00 1.0000 -0.030 grossular 0.6757E-01 0.6757E-01 1.0000 -1.170 Solid products produced: Mass = 0.000260 g Volume = 0.000099 cm3 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.0045900 moles log = -2.3382 Original solution: 1000.0103000 g Original solution / Rock added: 217867.17 (Water/Rock Ratio), log = 5.3382 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0207 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9996E+00 0.9859 0.1006E+01 0.1020E+01 CO2,gas 0.2085E-05 1.0071 0.2143E-05 0.2128E-05 CH4,gas 0.4831E-05 1.0125 0.4993E-05 0.4931E-05 H2,gas 0.3827E-03 1.0005 0.3908E-03 0.3906E-03 H2S,gas 0.8129E-06 0.9960 0.8264E-06 0.8297E-06 S2,gas 0.1644E-24 1.0000 0.1678E-24 0.1678E-24 CO,gas 0.2187E-12 1.0000 0.2232E-12 0.2232E-12 SO3,gas 0.9673E-41 1.0000 0.9874E-41 0.9874E-41 SO2,gas 0.1471E-21 1.0000 0.1501E-21 0.1501E-21 HF,gas 0.2372E-14 1.0000 0.2421E-14 0.2421E-14 HCl,gas 0.3891E-17 1.0000 0.3972E-17 0.3972E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 17 albite -0.38 -0.38 0.00 0.000 0.11184E-10 23 andradite 39.01 39.01 0.00 0.000 0.12132E-10 24 grossular 32.73 32.73 0.00 0.000 -0.12132E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -14.03 -7.37 -2.456 0.12580E+05 -5.669 3 CH4,gas 4.54 -2.46 -7.00 -1.750 0.11953E+05 -5.302 4 H2,gas 8.00 2.89 -5.11 -2.918 0.87200E+04 -3.408 5 H2S,gas -6.23 -14.01 -7.78 -3.891 0.13287E+05 -6.083 6 S2,gas -7.34 -33.81 -26.47 -4.073 0.45204E+05 -24.775 7 CO,gas 3.21 -11.14 -14.35 -4.415 0.24503E+05 -12.651 8 SO3,gas 17.12 -25.58 -42.70 -10.676 0.72917E+05 -41.006 9 SO2,gas 0.83 -22.69 -23.52 -6.273 0.40164E+05 -21.824 10 HF,gas 0.47 -15.84 -16.31 -8.157 0.27857E+05 -14.616 11 HCl,gas 5.19 -13.91 -19.10 -9.550 0.32613E+05 -17.401 12 acmite 7.71 7.02 -0.69 -0.072 0.11795E+04 16 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 20 spessartine 24.46 19.68 -4.78 -0.239 0.81566E+04 21 analcite 3.32 2.74 -0.58 -0.065 0.99287E+03 27 annite 20.12 16.71 -3.41 -0.189 0.58229E+04 28 phlogopite 27.06 25.20 -1.87 -0.104 0.31905E+04 30 anorthite 12.71 7.91 -4.80 -0.370 0.82030E+04 33 apatite-OH -18.15 -19.43 -1.28 -0.098 0.21787E+04 34 apatite-F -34.30 -35.27 -0.97 -0.081 0.16562E+04 38 aragonite 0.97 -1.22 -2.19 -0.730 0.37394E+04 39 brucite 12.57 9.23 -3.34 -0.668 0.57046E+04 40 calcite 0.81 -1.22 -2.04 -0.678 0.34752E+04 41 carnegieite-low 9.02 5.86 -3.16 -0.451 0.53934E+04 42 carnegieite-high 10.09 5.86 -4.23 -0.604 0.72204E+04 43 carpholite-Mg 8.58 4.33 -4.25 -0.284 0.72617E+04 45 celadonite 5.34 3.62 -1.73 -0.101 0.29454E+04 46 celadonite-Fe 3.88 0.79 -3.09 -0.182 0.52719E+04 47 chrysotile 23.89 21.43 -2.46 -0.205 0.41971E+04 49 clinochlore 39.07 38.12 -0.95 -0.030 0.16292E+04 50 daphnite 28.97 23.98 -4.99 -0.156 0.85169E+04 52 chlorite-Al-free 47.17 42.87 -4.30 -0.179 0.73494E+04 54 chloritoid-Fe 9.17 4.63 -4.55 -0.303 0.77653E+04 55 chloritoid-Mn 11.40 7.46 -3.94 -0.263 0.67290E+04 57 coesite -2.38 -3.12 -0.75 -0.249 0.12775E+04 64 cristobalite -2.56 -3.12 -0.56 -0.188 0.96285E+03 66 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71238E+04 68 diaspore 2.87 0.68 -2.20 -0.366 0.37541E+04 70 diopside 16.18 15.78 -0.40 -0.040 0.67911E+03 71 hedenbergite 14.21 12.96 -1.25 -0.125 0.21382E+04 76 clinoenstatite 17.17 12.21 -4.96 -0.496 0.84683E+04 78 epidote 24.67 22.54 -2.13 -0.103 0.36368E+04 79 clinozoisite 22.81 18.26 -4.54 -0.207 0.77598E+04 80 epidote-Fe 29.84 26.82 -3.02 -0.157 0.51605E+04 81 fayalite 14.05 9.68 -4.37 -0.624 0.74617E+04 82 ferrosilite 11.15 6.55 -4.60 -0.460 0.78510E+04 86 gibbsite 4.08 0.68 -3.40 -0.486 0.58127E+04 87 glaucophane 22.97 20.67 -2.31 -0.062 0.39412E+04 89 graphite -3.55 -8.24 -4.70 -1.342 0.80188E+04 90 greenalite 16.14 12.95 -3.19 -0.266 0.54436E+04 93 hematite 12.57 9.91 -2.66 -0.322 0.45402E+04 94 heulandite -5.83 -7.72 -1.89 -0.086 0.32234E+04 98 jadeite 4.22 2.74 -1.47 -0.147 0.25184E+04 100 kalsilite 7.58 3.76 -3.82 -0.546 0.65263E+04 101 kaolinite -1.33 -4.90 -3.57 -0.324 0.60882E+04 104 laumontite 2.88 1.66 -1.23 -0.082 0.20930E+04 105 lawsonite 9.62 7.91 -1.71 -0.114 0.29197E+04 106 leucite 4.12 0.64 -3.48 -0.348 0.59444E+04 108 lizardite 23.24 21.43 -1.81 -0.151 0.30897E+04 110 magnetite 20.09 16.31 -3.78 -0.309 0.64547E+04 111 minnesotaite 10.39 6.70 -3.69 -0.217 0.62923E+04 115 manganosite 14.06 9.23 -4.82 -1.206 0.82365E+04 119 microcline -2.49 -2.49 0.00 0.000 0.45170E+00 123 muscovite 2.58 -1.14 -3.72 -0.219 0.63503E+04 124 paragonite 4.24 0.97 -3.27 -0.193 0.55889E+04 125 nepheline 8.34 5.86 -2.47 -0.354 0.42257E+04 137 phlogopite-Na 29.65 27.30 -2.35 -0.130 0.40089E+04 139 prehnite 19.37 17.59 -1.79 -0.105 0.30487E+04 140 prehnite-Fe 22.50 21.86 -0.63 -0.038 0.10807E+04 141 pumpellyite-Fe 46.27 42.25 -4.02 -0.089 0.68668E+04 142 pumpellyite-Mg 48.99 45.08 -3.92 -0.087 0.66923E+04 145 pyrite -21.25 -24.52 -3.27 -0.769 0.55833E+04 146 pyrrhotite -4.26 -7.61 -3.35 -1.117 0.57230E+04 147 pyrrhotiteFe0.875 -6.02 -8.77 -2.75 -1.013 0.47020E+04 148 pyroxmangite 7.40 6.11 -1.29 -0.258 0.22002E+04 149 pyrophyllite -6.18 -11.15 -4.97 -0.311 0.84880E+04 150 quartz -2.99 -3.12 -0.13 -0.045 0.23018E+03 154 rhodochrosite -0.98 -4.79 -3.82 -1.272 0.65181E+04 155 rhodonite 7.45 6.11 -1.34 -0.267 0.22805E+04 156 sanidine -1.28 -2.49 -1.21 -0.093 0.20682E+04 166 stilbite -7.52 -7.72 -0.19 -0.009 0.32959E+03 167 stilpnomelane-Fe 13.02 11.46 -1.56 -0.046 0.26560E+04 168 stilpnomelane-Mg 27.44 25.60 -1.84 -0.055 0.31448E+04 174 talc 16.49 15.19 -1.31 -0.077 0.22287E+04 177 tephroite 18.09 15.34 -2.74 -0.392 0.46808E+04 181 tridymite -2.63 -3.12 -0.50 -0.166 0.85015E+03 182 tremolite 47.87 46.75 -1.12 -0.030 0.19058E+04 184 troilite-low -4.41 -7.61 -3.20 -1.067 0.54658E+04 190 wairakite 3.95 1.66 -2.29 -0.135 0.39149E+04 191 walstromite 11.51 9.68 -1.83 -0.366 0.31229E+04 192 wollastonite 10.46 9.68 -0.78 -0.156 0.13333E+04 193 pseudo-wollastonite 11.00 9.68 -1.32 -0.264 0.22531E+04 194 zoisite 22.85 18.26 -4.59 -0.209 0.78338E+04 195 akaganeite 7.75 4.95 -2.80 -0.606 0.47826E+04 202 chalcedony -2.80 -3.12 -0.32 -0.107 0.54947E+03 204 montmorillonite-Ca -2.29 -6.21 -3.92 -0.243 0.66951E+04 205 montmorillonite-K -2.24 -6.27 -4.04 -0.247 0.68951E+04 206 montmorillonite-Mg -2.48 -6.80 -4.32 -0.267 0.73799E+04 207 montmorillonite-Na -2.04 -5.58 -3.54 -0.217 0.60499E+04 208 nontronite-Ca 3.21 0.78 -2.44 -0.158 0.41625E+04 209 nontronite-H 2.53 -1.34 -3.87 -0.259 0.66058E+04 210 nontronite-K 3.34 0.71 -2.63 -0.169 0.44858E+04 211 nontronite-Mg 3.07 0.19 -2.89 -0.187 0.49314E+04 212 nontronite-Na 3.52 1.41 -2.11 -0.136 0.36065E+04 228 tobermorite 9.82 7.54 -2.28 -0.622 0.38950E+04 234 alabandite -0.98 -4.78 -3.80 -1.267 0.64881E+04 237 boehmite 4.41 0.68 -3.73 -0.622 0.63711E+04 239 ferrous-oxide 9.81 6.40 -3.41 -0.853 0.58252E+04 245 silica-amorphous -2.09 -3.12 -1.03 -0.344 0.17637E+04 247 an20ab80 2.02 1.27 -0.74 -0.057 0.12698E+04 248 an25ab75 2.65 1.69 -0.96 -0.074 0.16342E+04 249 an30ab70 3.28 2.10 -1.18 -0.090 0.20082E+04 250 tr.625ac.25prg.125 45.16 44.14 -1.03 -0.028 0.17522E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 0.0002000 MOLES Current total amount of reactant added: 0.0045900 MOLES New total amount of reactant added: 0.0047900 MOLES Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.5508E-08 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 7 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 0.0047900 Water: Moles liquid = 0.4985E+02 kg liquid = 0.8981E+00 Moles total = 0.4985E+02 kg total = 0.8981E+00 Activity = 1.0000 Stoichiometric ionic strength = .1163621E-01 Osmotic coef. = 0.9561 True ionic strength = .2029812E-01 Chg. balance for total moles = -.5508E-08 Max. difference allowed = 0.1661E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.96252E-10 -10.0166 0.80807E-10 -10.0926 0.83953E+00 -0.0760 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.18414E-03 -3.7348 0.15366E-03 -3.8135 0.83443E+00 -0.0786 4 SO4-- 0.88440E-05 -5.0534 0.45761E-05 -5.3395 0.51743E+00 -0.2861 5 HCO3- 0.14550E-03 -3.8371 0.12159E-03 -3.9151 0.83566E+00 -0.0780 6 HS- 0.14911E-03 -3.8265 0.12444E-03 -3.9050 0.83455E+00 -0.0785 7 Al+++ 0.10826E-28 -28.9655 0.24806E-29 -29.6055 0.22912E+00 -0.6399 8 H4SiO4 0.75376E-03 -3.1228 0.75376E-03 -3.1228 0.10000E+01 0.0000 9 Ca++ 0.79590E-07 -7.0991 0.40877E-07 -7.3885 0.51359E+00 -0.2894 10 Mg++ 0.21427E-10 -10.6690 0.10954E-10 -10.9604 0.51122E+00 -0.2914 11 Fe++ 0.32423E-13 -13.4891 0.16593E-13 -13.7801 0.51178E+00 -0.2909 12 K+ 0.15654E-03 -3.8054 0.13085E-03 -3.8832 0.83587E+00 -0.0779 13 Na+ 0.19878E-01 -1.7016 0.16584E-01 -1.7803 0.83428E+00 -0.0787 14 Mn++ 0.21856E-10 -10.6604 0.11195E-10 -10.9510 0.51221E+00 -0.2906 15 F- 0.22374E-05 -5.6503 0.18631E-05 -5.7298 0.83269E+00 -0.0795 16 HPO4-- 0.45389E-07 -7.3430 0.23489E-07 -7.6291 0.51751E+00 -0.2861 18 HSiO3- 0.10438E-01 -1.9814 0.87098E-02 -2.0600 0.83443E+00 -0.0786 19 Ca(HSiO3)+ 0.96983E-08 -8.0133 0.81082E-08 -8.0911 0.83605E+00 -0.0778 20 Mg(HSiO3)+ 0.32343E-11 -11.4902 0.27040E-11 -11.5680 0.83605E+00 -0.0778 21 NaHSiO3,aq 0.23361E-02 -2.6315 0.23361E-02 -2.6315 0.10000E+01 0.0000 22 AlO+ 0.61816E-16 -16.2089 0.51681E-16 -16.2867 0.83605E+00 -0.0778 24 HAlO2,aq 0.12737E-09 -9.8949 0.12737E-09 -9.8949 0.10000E+01 0.0000 25 AlO2- 0.41890E-05 -5.3779 0.34890E-05 -5.4573 0.83291E+00 -0.0794 26 CH4,aq 0.32233E-08 -8.4917 0.32118E-08 -8.4932 0.99645E+00 -0.0015 31 CO,aq 0.15307E-15 -15.8151 0.15307E-15 -15.8151 0.10000E+01 0.0000 32 CO2,aq 0.21069E-07 -7.6763 0.20995E-07 -7.6779 0.99645E+00 -0.0015 33 CO3-2 0.25455E-03 -3.5942 0.13143E-03 -3.8813 0.51632E+00 -0.2871 34 CaCO3,aq 0.67365E-07 -7.1716 0.67365E-07 -7.1716 0.10000E+01 0.0000 35 Ca(HCO3)+ 0.15175E-09 -9.8189 0.12687E-09 -9.8966 0.83605E+00 -0.0778 36 CaCl+ 0.12158E-10 -10.9151 0.10165E-10 -10.9929 0.83605E+00 -0.0778 37 CaCl2,aq 0.37106E-15 -15.4306 0.37106E-15 -15.4306 0.10000E+01 0.0000 38 CaF+ 0.13299E-11 -11.8762 0.11119E-11 -11.9539 0.83605E+00 -0.0778 39 CaOH+ 0.43122E-07 -7.3653 0.36052E-07 -7.4431 0.83605E+00 -0.0778 40 CaSO4,aq 0.59400E-10 -10.2262 0.59400E-10 -10.2262 0.10000E+01 0.0000 41 HCl,aq 0.22753E-14 -14.6430 0.22753E-14 -14.6430 0.10000E+01 0.0000 45 HF,aq 0.10306E-11 -11.9869 0.10306E-11 -11.9869 0.10000E+01 0.0000 46 HF2- 0.77691E-18 -18.1096 0.64828E-18 -18.1882 0.83443E+00 -0.0786 48 FeCl+ 0.48271E-17 -17.3163 0.40357E-17 -17.3941 0.83605E+00 -0.0778 51 FeF+ 0.18896E-17 -17.7236 0.15798E-17 -17.8014 0.83605E+00 -0.0778 53 FeO,aq 0.98765E-10 -10.0054 0.98765E-10 -10.0054 0.10000E+01 0.0000 54 FeOH+ 0.79951E-11 -11.0972 0.66843E-11 -11.1749 0.83605E+00 -0.0778 55 HFeO2- 0.15326E-07 -7.8146 0.12788E-07 -7.8932 0.83443E+00 -0.0786 56 FeO+ 0.35398E-16 -16.4510 0.29594E-16 -16.5288 0.83605E+00 -0.0778 58 FeO2- 0.11114E-08 -8.9541 0.92739E-09 -9.0327 0.83443E+00 -0.0786 59 HFeO2,aq 0.95312E-11 -11.0209 0.95312E-11 -11.0209 0.10000E+01 0.0000 60 H2,aq 0.29126E-06 -6.5357 0.29023E-06 -6.5373 0.99645E+00 -0.0015 61 KCl,aq 0.36440E-09 -9.4384 0.36440E-09 -9.4384 0.10000E+01 0.0000 62 KHSO4,aq 0.13681E-18 -18.8639 0.13681E-18 -18.8639 0.10000E+01 0.0000 63 KOH,aq 0.69153E-06 -6.1602 0.69153E-06 -6.1602 0.10000E+01 0.0000 64 KSO4- 0.11135E-07 -7.9533 0.92917E-08 -8.0319 0.83443E+00 -0.0786 65 MgCO3,aq 0.45248E-11 -11.3444 0.45248E-11 -11.3444 0.10000E+01 0.0000 66 Mg(HCO3)+ 0.41552E-13 -13.3814 0.34740E-13 -13.4592 0.83605E+00 -0.0778 67 MgCl+ 0.29528E-14 -14.5298 0.24687E-14 -14.6075 0.83605E+00 -0.0778 68 MgF+ 0.13202E-14 -14.8794 0.11037E-14 -14.9571 0.83605E+00 -0.0778 69 MgOH+ 0.63942E-10 -10.1942 0.53459E-10 -10.2720 0.83605E+00 -0.0778 71 MnF+ 0.42019E-15 -15.3765 0.35130E-15 -15.4543 0.83605E+00 -0.0778 72 MnO,aq 0.17755E-08 -8.7507 0.17755E-08 -8.7507 0.10000E+01 0.0000 73 MnOH+ 0.50107E-09 -9.3001 0.41892E-09 -9.3779 0.83605E+00 -0.0778 74 MnO2-2 0.17477E-10 -10.7575 0.90237E-11 -11.0446 0.51632E+00 -0.2871 75 HMnO2- 0.19145E-09 -9.7179 0.15975E-09 -9.7966 0.83443E+00 -0.0786 78 MnCl+ 0.12670E-13 -13.8972 0.10592E-13 -13.9750 0.83605E+00 -0.0778 79 MnSO4,aq 0.14789E-13 -13.8300 0.14789E-13 -13.8300 0.10000E+01 0.0000 80 NaCl,aq 0.84447E-06 -6.0734 0.84447E-06 -6.0734 0.10000E+01 0.0000 81 NaF,aq 0.72335E-08 -8.1407 0.72335E-08 -8.1407 0.10000E+01 0.0000 82 NaOH,aq 0.88175E-04 -4.0547 0.88175E-04 -4.0547 0.10000E+01 0.0000 84 OH- 0.85844E-02 -2.0663 0.71501E-02 -2.1457 0.83291E+00 -0.0794 89 HPO3-2 0.41146E-16 -16.3857 0.21245E-16 -16.6727 0.51632E+00 -0.2871 92 H3PO4,aq 0.10727E-17 -17.9695 0.10727E-17 -17.9695 0.10000E+01 0.0000 93 H2PO4- 0.41922E-10 -10.3776 0.35015E-10 -10.4557 0.83523E+00 -0.0782 94 PO4-3 0.98502E-09 -9.0066 0.23717E-09 -9.6249 0.24077E+00 -0.6184 98 HP2O7-3 0.10357E-17 -17.9848 0.23755E-18 -18.6242 0.22935E+00 -0.6395 99 P2O7-4 0.92403E-17 -17.0343 0.70229E-18 -18.1535 0.76002E-01 -1.1192 100 H2S,aq 0.31189E-07 -7.5060 0.31078E-07 -7.5075 0.99645E+00 -0.0015 101 S2-2 0.22898E-11 -11.6402 0.11823E-11 -11.9273 0.51632E+00 -0.2871 102 S3-2 0.33034E-18 -18.4810 0.17056E-18 -18.7681 0.51632E+00 -0.2871 107 SO3-2 0.32945E-12 -12.4822 0.17259E-12 -12.7630 0.52387E+00 -0.2808 108 HSO3- 0.10465E-14 -14.9803 0.87321E-15 -15.0589 0.83443E+00 -0.0786 109 HSO4- 0.42583E-12 -12.3708 0.35637E-12 -12.4481 0.83687E+00 -0.0773 111 S2O3-2 0.32356E-14 -14.4900 0.16706E-14 -14.7771 0.51632E+00 -0.2871 Charge balance for all species = -.6132E-08 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.9625203E-10 -.2171900E-01 -.2185303E+02 0.0000 2 H2O 0.1000000E+01 0.5550416E+02 0.9981691E+06 0.0000 3 Cl- 0.1841439E-03 0.1849887E-03 0.6546894E+01 6.2791 4 SO4-- 0.8843958E-05 0.8779256E-05 0.8418692E+00 14.8456 5 HCO3- 0.1455028E-03 0.4001472E-03 0.2437301E+02 6.1775 6 HS- 0.1491090E-03 0.1492161E-03 0.4926214E+01 6.1875 7 Al+++ 0.1082635E-28 0.4189096E-05 0.1128297E+00 0.6722 8 H4SiO4 0.7537584E-03 0.1352796E-01 0.1297963E+04 -3.1228 9 Ca++ 0.7959037E-07 0.2000010E-06 0.8001572E-02 12.7966 10 Mg++ 0.2142691E-10 0.9317430E-10 0.2261278E-05 9.2247 11 Fe++ 0.3242282E-13 0.1655367E-07 0.9228503E-03 6.4050 12 K+ 0.1565440E-03 0.1572471E-03 0.6137883E+01 6.2093 13 Na+ 0.1987783E-01 0.2230299E-01 0.5118413E+03 8.3122 14 Mn++ 0.2185575E-10 0.2507345E-08 0.1375067E-03 9.2341 15 F- 0.2237411E-05 0.2244647E-05 0.4256895E-01 4.3628 16 HPO4-- 0.4538936E-07 0.4641630E-07 0.4447171E-02 12.5560 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.1951078E-01 -.1950664E-01 -.4140781E-05 0.0000000E+00 2 H2O 0.4985033E+02 0.4985033E+02 -.4055763E-05 0.0000000E+00 3 Cl- 0.1661452E-03 0.1661452E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.7887190E-05 0.7884974E-05 0.2215601E-08 0.0000000E+00 5 HCO3- 0.3593870E-03 0.3593870E-03 0.0000000E+00 0.0000000E+00 6 HS- 0.1340143E-03 0.1340165E-03 -.2215601E-08 0.0000000E+00 7 Al+++ 0.4775352E-05 0.3762382E-05 0.1012970E-05 0.0000000E+00 8 H4SiO4 0.1215302E-01 0.1214996E-01 0.3063630E-05 0.0000000E+00 9 Ca++ 0.2080835E-06 0.1796283E-06 0.2845520E-07 0.0000000E+00 10 Mg++ 0.8368328E-10 0.8368328E-10 0.0000000E+00 0.0000000E+00 11 Fe++ 0.3259227E-07 0.1486746E-07 0.1772481E-07 0.0000000E+00 12 K+ 0.1412294E-03 0.1412294E-03 0.0000000E+00 0.0000000E+00 13 Na+ 0.2003215E-01 0.2003114E-01 0.1011725E-05 0.0000000E+00 14 Mn++ 0.2251939E-08 0.2251939E-08 0.0000000E+00 0.0000000E+00 15 F- 0.2016000E-05 0.2016000E-05 0.0000000E+00 0.0000000E+00 16 HPO4-- 0.4168819E-07 0.4168819E-07 0.0000000E+00 0.0000000E+00 Chg. balance for solid moles: 0.2118E-21 Mass of aqueous solution: 0.899716E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 0.0047900 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 0.1012E-05 -5.995 0.2653E-03 -3.576 98.23 0.1018E-03 andradite 0.8862E-08 -8.052 0.4504E-05 -5.346 1.668 0.1170E-05 grossular 0.6227E-09 -9.206 0.2805E-06 -6.552 0.1039 0.7804E-07 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.9344E+00 0.9344E+00 1.0000 -0.029 grossular 0.6565E-01 0.6565E-01 1.0000 -1.183 Solid products produced: Mass = 0.000270 g Volume = 0.000103 cm3 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.0047900 moles log = -2.3197 Original solution: 1000.0103000 g Original solution / Rock added: 208770.42 (Water/Rock Ratio), log = 5.3197 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0207 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9996E+00 0.9859 0.1006E+01 0.1020E+01 CO2,gas 0.2185E-05 1.0071 0.2246E-05 0.2230E-05 CH4,gas 0.4574E-05 1.0125 0.4728E-05 0.4669E-05 H2,gas 0.3731E-03 1.0005 0.3810E-03 0.3808E-03 H2S,gas 0.8403E-06 0.9960 0.8543E-06 0.8577E-06 S2,gas 0.1849E-24 1.0000 0.1887E-24 0.1887E-24 CO,gas 0.2235E-12 1.0000 0.2281E-12 0.2281E-12 SO3,gas 0.1107E-40 1.0000 0.1130E-40 0.1130E-40 SO2,gas 0.1641E-21 1.0000 0.1675E-21 0.1675E-21 HF,gas 0.2479E-14 1.0000 0.2531E-14 0.2531E-14 HCl,gas 0.3933E-17 1.0000 0.4015E-17 0.4015E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 17 albite -0.38 -0.38 0.00 0.000 0.11184E-10 23 andradite 39.01 39.01 0.00 0.000 0.12132E-10 24 grossular 32.73 32.73 0.00 0.000 0.00000E+00 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -14.01 -7.35 -2.449 0.12546E+05 -5.649 3 CH4,gas 4.54 -2.48 -7.02 -1.756 0.11994E+05 -5.325 4 H2,gas 8.00 2.88 -5.12 -2.925 0.87389E+04 -3.419 5 H2S,gas -6.23 -14.00 -7.77 -3.884 0.13263E+05 -6.068 6 S2,gas -7.34 -33.76 -26.42 -4.065 0.45117E+05 -24.724 7 CO,gas 3.21 -11.13 -14.34 -4.413 0.24487E+05 -12.642 8 SO3,gas 17.12 -25.52 -42.65 -10.661 0.72817E+05 -40.947 9 SO2,gas 0.83 -22.64 -23.47 -6.260 0.40083E+05 -21.776 10 HF,gas 0.47 -15.82 -16.30 -8.148 0.27825E+05 -14.597 11 HCl,gas 5.19 -13.91 -19.10 -9.548 0.32605E+05 -17.396 12 acmite 7.71 7.03 -0.68 -0.071 0.11591E+04 16 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 20 spessartine 24.46 19.68 -4.78 -0.239 0.81598E+04 21 analcite 3.32 2.74 -0.58 -0.065 0.99539E+03 27 annite 20.12 16.73 -3.40 -0.189 0.57970E+04 28 phlogopite 27.06 25.19 -1.88 -0.104 0.32055E+04 30 anorthite 12.71 7.90 -4.81 -0.370 0.82212E+04 33 apatite-OH -18.15 -19.46 -1.31 -0.100 0.22305E+04 34 apatite-F -34.30 -35.28 -0.98 -0.082 0.16752E+04 38 aragonite 0.97 -1.21 -2.18 -0.726 0.37182E+04 39 brucite 12.57 9.22 -3.34 -0.669 0.57096E+04 40 calcite 0.81 -1.21 -2.02 -0.674 0.34539E+04 41 carnegieite-low 9.02 5.86 -3.16 -0.452 0.53984E+04 42 carnegieite-high 10.09 5.86 -4.23 -0.605 0.72254E+04 43 carpholite-Mg 8.58 4.32 -4.26 -0.284 0.72714E+04 45 celadonite 5.34 3.62 -1.73 -0.102 0.29479E+04 46 celadonite-Fe 3.88 0.80 -3.08 -0.181 0.52608E+04 47 chrysotile 23.89 21.43 -2.46 -0.205 0.42071E+04 49 clinochlore 39.07 38.10 -0.97 -0.030 0.16564E+04 50 daphnite 28.97 24.00 -4.96 -0.155 0.84758E+04 52 chlorite-Al-free 47.17 42.86 -4.32 -0.180 0.73693E+04 54 chloritoid-Fe 9.17 4.63 -4.55 -0.303 0.77638E+04 55 chloritoid-Mn 11.40 7.46 -3.95 -0.263 0.67365E+04 57 coesite -2.38 -3.12 -0.75 -0.249 0.12750E+04 64 cristobalite -2.56 -3.12 -0.56 -0.187 0.96033E+03 66 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71239E+04 68 diaspore 2.87 0.67 -2.20 -0.367 0.37590E+04 70 diopside 16.18 15.78 -0.41 -0.041 0.69262E+03 71 hedenbergite 14.21 12.96 -1.25 -0.125 0.21381E+04 76 clinoenstatite 17.17 12.20 -4.96 -0.496 0.84733E+04 78 epidote 24.67 22.53 -2.14 -0.104 0.36480E+04 79 clinozoisite 22.81 18.24 -4.56 -0.207 0.77939E+04 80 epidote-Fe 29.84 26.83 -3.02 -0.157 0.51487E+04 81 fayalite 14.05 9.69 -4.36 -0.623 0.74419E+04 82 ferrosilite 11.15 6.56 -4.58 -0.458 0.78286E+04 86 gibbsite 4.08 0.67 -3.41 -0.487 0.58175E+04 87 glaucophane 22.97 20.66 -2.31 -0.063 0.39512E+04 89 graphite -3.55 -8.24 -4.70 -1.342 0.80217E+04 90 greenalite 16.14 12.97 -3.17 -0.264 0.54126E+04 93 hematite 12.57 9.93 -2.64 -0.320 0.45041E+04 94 heulandite -5.83 -7.72 -1.89 -0.086 0.32291E+04 98 jadeite 4.22 2.74 -1.48 -0.148 0.25209E+04 100 kalsilite 7.58 3.76 -3.83 -0.546 0.65313E+04 101 kaolinite -1.33 -4.90 -3.57 -0.324 0.60929E+04 104 laumontite 2.88 1.65 -1.23 -0.082 0.21062E+04 105 lawsonite 9.62 7.90 -1.72 -0.115 0.29379E+04 106 leucite 4.12 0.64 -3.48 -0.348 0.59469E+04 108 lizardite 23.24 21.43 -1.82 -0.151 0.30997E+04 110 magnetite 20.09 16.33 -3.75 -0.306 0.64099E+04 111 minnesotaite 10.39 6.72 -3.66 -0.216 0.62563E+04 115 manganosite 14.06 9.23 -4.82 -1.206 0.82368E+04 119 microcline -2.49 -2.49 0.00 0.000 0.47655E+00 123 muscovite 2.58 -1.14 -3.72 -0.219 0.63600E+04 124 paragonite 4.24 0.96 -3.28 -0.193 0.55986E+04 125 nepheline 8.34 5.86 -2.48 -0.354 0.42308E+04 137 phlogopite-Na 29.65 27.29 -2.36 -0.131 0.40239E+04 139 prehnite 19.37 17.57 -1.80 -0.106 0.30779E+04 140 prehnite-Fe 22.50 21.86 -0.64 -0.038 0.10870E+04 141 pumpellyite-Fe 46.27 42.22 -4.05 -0.090 0.69215E+04 142 pumpellyite-Mg 48.99 45.04 -3.96 -0.088 0.67607E+04 145 pyrite -21.25 -24.47 -3.22 -0.759 0.55065E+04 146 pyrrhotite -4.26 -7.59 -3.33 -1.111 0.56897E+04 147 pyrrhotiteFe0.875 -6.02 -8.75 -2.73 -1.005 0.46675E+04 148 pyroxmangite 7.40 6.11 -1.29 -0.257 0.21981E+04 149 pyrophyllite -6.18 -11.15 -4.97 -0.311 0.84876E+04 150 quartz -2.99 -3.12 -0.13 -0.044 0.22766E+03 154 rhodochrosite -0.98 -4.77 -3.80 -1.266 0.64836E+04 155 rhodonite 7.45 6.11 -1.33 -0.267 0.22783E+04 156 sanidine -1.28 -2.49 -1.21 -0.093 0.20682E+04 158 siderite -2.61 -7.60 -4.99 -1.665 0.85279E+04 166 stilbite -7.52 -7.72 -0.20 -0.009 0.33523E+03 167 stilpnomelane-Fe 13.02 11.49 -1.52 -0.046 0.26036E+04 168 stilpnomelane-Mg 27.44 25.59 -1.85 -0.055 0.31608E+04 174 talc 16.49 15.18 -1.31 -0.077 0.22336E+04 177 tephroite 18.09 15.35 -2.74 -0.391 0.46790E+04 181 tridymite -2.63 -3.12 -0.50 -0.165 0.84764E+03 182 tremolite 47.87 46.73 -1.13 -0.031 0.19378E+04 184 troilite-low -4.41 -7.59 -3.18 -1.061 0.54325E+04 190 wairakite 3.95 1.65 -2.30 -0.135 0.39281E+04 191 walstromite 11.51 9.67 -1.84 -0.367 0.31339E+04 192 wollastonite 10.46 9.67 -0.79 -0.157 0.13443E+04 193 pseudo-wollastonite 11.00 9.67 -1.33 -0.265 0.22642E+04 194 zoisite 22.85 18.24 -4.61 -0.209 0.78679E+04 195 akaganeite 7.75 4.96 -2.79 -0.603 0.47646E+04 202 chalcedony -2.80 -3.12 -0.32 -0.107 0.54696E+03 204 montmorillonite-Ca -2.29 -6.21 -3.92 -0.243 0.66970E+04 205 montmorillonite-K -2.24 -6.28 -4.04 -0.247 0.68957E+04 206 montmorillonite-Mg -2.48 -6.80 -4.32 -0.267 0.73804E+04 207 montmorillonite-Na -2.04 -5.58 -3.54 -0.217 0.60505E+04 208 nontronite-Ca 3.21 0.80 -2.41 -0.157 0.41210E+04 209 nontronite-H 2.53 -1.31 -3.84 -0.258 0.65620E+04 210 nontronite-K 3.34 0.74 -2.60 -0.167 0.44429E+04 211 nontronite-Mg 3.07 0.21 -2.86 -0.186 0.48884E+04 212 nontronite-Na 3.52 1.43 -2.09 -0.134 0.35636E+04 228 tobermorite 9.82 7.54 -2.29 -0.624 0.39037E+04 234 alabandite -0.98 -4.76 -3.79 -1.262 0.64638E+04 237 boehmite 4.41 0.67 -3.73 -0.622 0.63759E+04 239 ferrous-oxide 9.81 6.41 -3.41 -0.852 0.58166E+04 245 silica-amorphous -2.09 -3.12 -1.03 -0.344 0.17611E+04 247 an20ab80 2.02 1.27 -0.75 -0.057 0.12734E+04 248 an25ab75 2.65 1.69 -0.96 -0.074 0.16387E+04 249 an30ab70 3.28 2.10 -1.18 -0.091 0.20137E+04 250 tr.625ac.25prg.125 45.16 44.13 -1.04 -0.028 0.17693E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 0.0002000 MOLES Current total amount of reactant added: 0.0047900 MOLES New total amount of reactant added: 0.0049900 MOLES Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.5508E-08 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 7 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 0.0049900 Water: Moles liquid = 0.4985E+02 kg liquid = 0.8981E+00 Moles total = 0.4985E+02 kg total = 0.8981E+00 Activity = 1.0000 Stoichiometric ionic strength = .1164902E-01 Osmotic coef. = 0.9556 True ionic strength = .2030984E-01 Chg. balance for total moles = -.5508E-08 Max. difference allowed = 0.1673E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.96607E-10 -10.0150 0.81102E-10 -10.0910 0.83950E+00 -0.0760 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.18545E-03 -3.7318 0.15474E-03 -3.8104 0.83440E+00 -0.0786 4 SO4-- 0.99042E-05 -5.0042 0.51240E-05 -5.2904 0.51735E+00 -0.2862 5 HCO3- 0.15170E-03 -3.8190 0.12676E-03 -3.8970 0.83563E+00 -0.0780 6 HS- 0.15346E-03 -3.8140 0.12806E-03 -3.8926 0.83452E+00 -0.0786 7 Al+++ 0.10878E-28 -28.9635 0.24914E-29 -29.6035 0.22904E+00 -0.6401 8 H4SiO4 0.75632E-03 -3.1213 0.75632E-03 -3.1213 0.10000E+01 0.0000 9 Ca++ 0.78757E-07 -7.1037 0.40443E-07 -7.3932 0.51351E+00 -0.2894 10 Mg++ 0.21442E-10 -10.6687 0.10960E-10 -10.9602 0.51114E+00 -0.2915 11 Fe++ 0.33086E-13 -13.4803 0.16930E-13 -13.7713 0.51170E+00 -0.2910 12 K+ 0.15654E-03 -3.8054 0.13085E-03 -3.8832 0.83583E+00 -0.0779 13 Na+ 0.19879E-01 -1.7016 0.16584E-01 -1.7803 0.83425E+00 -0.0787 14 Mn++ 0.22008E-10 -10.6574 0.11271E-10 -10.9480 0.51213E+00 -0.2906 15 F- 0.23262E-05 -5.6334 0.19369E-05 -5.7129 0.83266E+00 -0.0795 16 HPO4-- 0.45392E-07 -7.3430 0.23487E-07 -7.6292 0.51743E+00 -0.2861 18 HSiO3- 0.10436E-01 -1.9815 0.87077E-02 -2.0601 0.83440E+00 -0.0786 19 Ca(HSiO3)+ 0.95932E-08 -8.0180 0.80201E-08 -8.0958 0.83602E+00 -0.0778 20 Mg(HSiO3)+ 0.32354E-11 -11.4901 0.27048E-11 -11.5679 0.83602E+00 -0.0778 21 NaHSiO3,aq 0.23356E-02 -2.6316 0.23356E-02 -2.6316 0.10000E+01 0.0000 22 AlO+ 0.61639E-16 -16.2101 0.51531E-16 -16.2879 0.83602E+00 -0.0778 24 HAlO2,aq 0.12654E-09 -9.8978 0.12654E-09 -9.8978 0.10000E+01 0.0000 25 AlO2- 0.41466E-05 -5.3823 0.34536E-05 -5.4617 0.83288E+00 -0.0794 26 CH4,aq 0.30885E-08 -8.5103 0.30775E-08 -8.5118 0.99645E+00 -0.0015 31 CO,aq 0.15667E-15 -15.8050 0.15667E-15 -15.8050 0.10000E+01 0.0000 32 CO2,aq 0.22046E-07 -7.6567 0.21967E-07 -7.6582 0.99645E+00 -0.0015 33 CO3-2 0.26445E-03 -3.5776 0.13652E-03 -3.8648 0.51624E+00 -0.2871 34 CaCO3,aq 0.69232E-07 -7.1597 0.69232E-07 -7.1597 0.10000E+01 0.0000 35 Ca(HCO3)+ 0.15653E-09 -9.8054 0.13086E-09 -9.8832 0.83602E+00 -0.0778 36 CaCl+ 0.12114E-10 -10.9167 0.10128E-10 -10.9945 0.83602E+00 -0.0778 37 CaCl2,aq 0.37232E-15 -15.4291 0.37232E-15 -15.4291 0.10000E+01 0.0000 38 CaF+ 0.13680E-11 -11.8639 0.11437E-11 -11.9417 0.83602E+00 -0.0778 39 CaOH+ 0.42511E-07 -7.3715 0.35540E-07 -7.4493 0.83602E+00 -0.0778 40 CaSO4,aq 0.65804E-10 -10.1817 0.65804E-10 -10.1817 0.10000E+01 0.0000 41 HCl,aq 0.22997E-14 -14.6383 0.22997E-14 -14.6383 0.10000E+01 0.0000 45 HF,aq 0.10754E-11 -11.9684 0.10754E-11 -11.9684 0.10000E+01 0.0000 46 HF2- 0.84282E-18 -18.0743 0.70325E-18 -18.1529 0.83440E+00 -0.0786 48 FeCl+ 0.49601E-17 -17.3045 0.41467E-17 -17.3823 0.83602E+00 -0.0778 51 FeF+ 0.20045E-17 -17.6980 0.16758E-17 -17.7758 0.83602E+00 -0.0778 53 FeO,aq 0.10004E-09 -9.9998 0.10004E-09 -9.9998 0.10000E+01 0.0000 54 FeOH+ 0.81281E-11 -11.0900 0.67952E-11 -11.1678 0.83602E+00 -0.0778 55 HFeO2- 0.15468E-07 -7.8106 0.12906E-07 -7.8892 0.83440E+00 -0.0786 56 FeO+ 0.36385E-16 -16.4391 0.30418E-16 -16.5169 0.83602E+00 -0.0778 58 FeO2- 0.11341E-08 -8.9453 0.94629E-09 -9.0240 0.83440E+00 -0.0786 59 HFeO2,aq 0.97609E-11 -11.0105 0.97609E-11 -11.0105 0.10000E+01 0.0000 60 H2,aq 0.28492E-06 -6.5453 0.28391E-06 -6.5468 0.99645E+00 -0.0015 61 KCl,aq 0.36696E-09 -9.4354 0.36696E-09 -9.4354 0.10000E+01 0.0000 62 KHSO4,aq 0.15374E-18 -18.8132 0.15374E-18 -18.8132 0.10000E+01 0.0000 63 KOH,aq 0.68899E-06 -6.1618 0.68899E-06 -6.1618 0.10000E+01 0.0000 64 KSO4- 0.12469E-07 -7.9042 0.10404E-07 -7.9828 0.83440E+00 -0.0786 65 MgCO3,aq 0.47026E-11 -11.3277 0.47026E-11 -11.3277 0.10000E+01 0.0000 66 Mg(HCO3)+ 0.43344E-13 -13.3631 0.36237E-13 -13.4409 0.83602E+00 -0.0778 67 MgCl+ 0.29754E-14 -14.5265 0.24875E-14 -14.6042 0.83602E+00 -0.0778 68 MgF+ 0.13733E-14 -14.8622 0.11481E-14 -14.9400 0.83602E+00 -0.0778 69 MgOH+ 0.63746E-10 -10.1955 0.53293E-10 -10.2733 0.83602E+00 -0.0778 71 MnF+ 0.43985E-15 -15.3567 0.36772E-15 -15.4345 0.83602E+00 -0.0778 72 MnO,aq 0.17746E-08 -8.7509 0.17746E-08 -8.7509 0.10000E+01 0.0000 73 MnOH+ 0.50268E-09 -9.2987 0.42025E-09 -9.3765 0.83602E+00 -0.0778 74 MnO2-2 0.17344E-10 -10.7608 0.89539E-11 -11.0480 0.51624E+00 -0.2871 75 HMnO2- 0.19067E-09 -9.7197 0.15909E-09 -9.7983 0.83440E+00 -0.0786 78 MnCl+ 0.12847E-13 -13.8912 0.10740E-13 -13.9690 0.83602E+00 -0.0778 79 MnSO4,aq 0.16673E-13 -13.7780 0.16673E-13 -13.7780 0.10000E+01 0.0000 80 NaCl,aq 0.85043E-06 -6.0704 0.85043E-06 -6.0704 0.10000E+01 0.0000 81 NaF,aq 0.75202E-08 -8.1238 0.75202E-08 -8.1238 0.10000E+01 0.0000 82 NaOH,aq 0.87854E-04 -4.0562 0.87854E-04 -4.0562 0.10000E+01 0.0000 84 OH- 0.85536E-02 -2.0679 0.71240E-02 -2.1473 0.83288E+00 -0.0794 89 HPO3-2 0.40253E-16 -16.3952 0.20781E-16 -16.6823 0.51624E+00 -0.2871 92 H3PO4,aq 0.10805E-17 -17.9664 0.10805E-17 -17.9664 0.10000E+01 0.0000 93 H2PO4- 0.42073E-10 -10.3760 0.35140E-10 -10.4542 0.83520E+00 -0.0782 94 PO4-3 0.98167E-09 -9.0080 0.23628E-09 -9.6266 0.24070E+00 -0.6185 98 HP2O7-3 0.10397E-17 -17.9831 0.23838E-18 -18.6227 0.22928E+00 -0.6396 99 P2O7-4 0.92444E-17 -17.0341 0.70217E-18 -18.1536 0.75956E-01 -1.1194 100 H2S,aq 0.32214E-07 -7.4920 0.32100E-07 -7.4935 0.99645E+00 -0.0015 101 S2-2 0.24794E-11 -11.6057 0.12800E-11 -11.8928 0.51624E+00 -0.2871 102 S3-2 0.37768E-18 -18.4229 0.19497E-18 -18.7100 0.51624E+00 -0.2871 107 SO3-2 0.36091E-12 -12.4426 0.18904E-12 -12.7234 0.52380E+00 -0.2808 108 HSO3- 0.11505E-14 -14.9391 0.95996E-15 -15.0177 0.83440E+00 -0.0786 109 HSO4- 0.47857E-12 -12.3201 0.40049E-12 -12.3974 0.83684E+00 -0.0774 111 S2O3-2 0.37426E-14 -14.4268 0.19321E-14 -14.7140 0.51624E+00 -0.2871 Charge balance for all species = -.6132E-08 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.9660686E-10 -.2169477E-01 -.2182863E+02 0.0000 2 H2O 0.1000000E+01 0.5550413E+02 0.9981678E+06 0.0000 3 Cl- 0.1854510E-03 0.1863018E-03 0.6593362E+01 6.2806 4 SO4-- 0.9904192E-05 0.9842552E-05 0.9438311E+00 14.8915 5 HCO3- 0.1516970E-03 0.4162456E-03 0.2535355E+02 6.1940 6 HS- 0.1534570E-03 0.1535634E-03 0.5069731E+01 6.1984 7 Al+++ 0.1087767E-28 0.4146772E-05 0.1116897E+00 0.6694 8 H4SiO4 0.7563241E-03 0.1352778E-01 0.1297945E+04 -3.1213 9 Ca++ 0.7875714E-07 0.2003288E-06 0.8014680E-02 12.7888 10 Mg++ 0.2144178E-10 0.9317395E-10 0.2261267E-05 9.2217 11 Fe++ 0.3308645E-13 0.1671983E-07 0.9321125E-03 6.4106 12 K+ 0.1565446E-03 0.1572465E-03 0.6137855E+01 6.2077 13 Na+ 0.1987859E-01 0.2230286E-01 0.5118380E+03 8.3106 14 Mn++ 0.2200843E-10 0.2507335E-08 0.1375061E-03 9.2339 15 F- 0.2326188E-05 0.2333711E-05 0.4425799E-01 4.3781 16 HPO4-- 0.4539238E-07 0.4641612E-07 0.4447150E-02 12.5528 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.1948924E-01 -.1948495E-01 -.4291953E-05 0.0000000E+00 2 H2O 0.4985049E+02 0.4985050E+02 -.4207873E-05 0.0000000E+00 3 Cl- 0.1673252E-03 0.1673252E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.8842190E-05 0.8839993E-05 0.2196940E-08 0.0000000E+00 5 HCO3- 0.3738470E-03 0.3738470E-03 0.0000000E+00 0.0000000E+00 6 HS- 0.1379193E-03 0.1379215E-03 -.2196940E-08 0.0000000E+00 7 Al+++ 0.4775352E-05 0.3724383E-05 0.1050969E-05 0.0000000E+00 8 H4SiO4 0.1215302E-01 0.1214984E-01 0.3177474E-05 0.0000000E+00 9 Ca++ 0.2080835E-06 0.1799234E-06 0.2816013E-07 0.0000000E+00 10 Mg++ 0.8368328E-10 0.8368328E-10 0.0000000E+00 0.0000000E+00 11 Fe++ 0.3259227E-07 0.1501675E-07 0.1757552E-07 0.0000000E+00 12 K+ 0.1412294E-03 0.1412294E-03 0.0000000E+00 0.0000000E+00 13 Na+ 0.2003215E-01 0.2003110E-01 0.1049771E-05 0.0000000E+00 14 Mn++ 0.2251939E-08 0.2251939E-08 0.0000000E+00 0.0000000E+00 15 F- 0.2096000E-05 0.2096000E-05 0.0000000E+00 0.0000000E+00 16 HPO4-- 0.4168819E-07 0.4168819E-07 0.0000000E+00 0.0000000E+00 Chg. balance for solid moles: 0.2118E-21 Mass of aqueous solution: 0.899720E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 0.0049900 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 0.1050E-05 -5.979 0.2753E-03 -3.560 98.31 0.1057E-03 andradite 0.8788E-08 -8.056 0.4466E-05 -5.350 1.595 0.1160E-05 grossular 0.5989E-09 -9.223 0.2698E-06 -6.569 0.9635E-01 0.7507E-07 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.9362E+00 0.9362E+00 1.0000 -0.029 grossular 0.6381E-01 0.6381E-01 1.0000 -1.195 Solid products produced: Mass = 0.000280 g Volume = 0.000107 cm3 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.0049900 moles log = -2.3019 Original solution: 1000.0103000 g Original solution / Rock added: 200402.87 (Water/Rock Ratio), log = 5.3019 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0207 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9996E+00 0.9859 0.1006E+01 0.1020E+01 CO2,gas 0.2286E-05 1.0071 0.2350E-05 0.2334E-05 CH4,gas 0.4383E-05 1.0125 0.4530E-05 0.4474E-05 H2,gas 0.3650E-03 1.0005 0.3727E-03 0.3725E-03 H2S,gas 0.8680E-06 0.9960 0.8824E-06 0.8859E-06 S2,gas 0.2061E-24 1.0000 0.2104E-24 0.2104E-24 CO,gas 0.2287E-12 1.0000 0.2335E-12 0.2335E-12 SO3,gas 0.1249E-40 1.0000 0.1274E-40 0.1274E-40 SO2,gas 0.1811E-21 1.0000 0.1848E-21 0.1848E-21 HF,gas 0.2587E-14 1.0000 0.2640E-14 0.2640E-14 HCl,gas 0.3976E-17 1.0000 0.4058E-17 0.4058E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 17 albite -0.38 -0.38 0.00 0.000 0.11184E-10 23 andradite 39.01 39.01 0.00 0.000 -0.24265E-10 24 grossular 32.73 32.73 0.00 0.000 -0.48529E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -13.99 -7.33 -2.443 0.12512E+05 -5.629 3 CH4,gas 4.54 -2.50 -7.04 -1.761 0.12026E+05 -5.344 4 H2,gas 8.00 2.87 -5.13 -2.930 0.87552E+04 -3.429 5 H2S,gas -6.23 -13.98 -7.75 -3.877 0.13239E+05 -6.054 6 S2,gas -7.34 -33.71 -26.38 -4.058 0.45036E+05 -24.677 7 CO,gas 3.21 -11.12 -14.33 -4.409 0.24469E+05 -12.632 8 SO3,gas 17.12 -25.47 -42.59 -10.648 0.72728E+05 -40.895 9 SO2,gas 0.83 -22.60 -23.43 -6.249 0.40010E+05 -21.733 10 HF,gas 0.47 -15.80 -16.28 -8.139 0.27793E+05 -14.578 11 HCl,gas 5.19 -13.90 -19.09 -9.545 0.32597E+05 -17.392 12 acmite 7.71 7.04 -0.67 -0.069 0.11391E+04 16 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 20 spessartine 24.46 19.68 -4.78 -0.239 0.81630E+04 21 analcite 3.32 2.74 -0.58 -0.065 0.99791E+03 27 annite 20.12 16.75 -3.38 -0.188 0.57685E+04 28 phlogopite 27.06 25.18 -1.89 -0.105 0.32206E+04 30 anorthite 12.71 7.88 -4.83 -0.371 0.82392E+04 33 apatite-OH -18.15 -19.49 -1.34 -0.103 0.22811E+04 34 apatite-F -34.30 -35.29 -0.99 -0.083 0.16943E+04 38 aragonite 0.97 -1.20 -2.17 -0.722 0.36979E+04 39 brucite 12.57 9.22 -3.35 -0.669 0.57146E+04 40 calcite 0.81 -1.20 -2.01 -0.670 0.34337E+04 41 carnegieite-low 9.02 5.86 -3.16 -0.452 0.54034E+04 42 carnegieite-high 10.09 5.86 -4.23 -0.605 0.72304E+04 43 carpholite-Mg 8.58 4.32 -4.26 -0.284 0.72810E+04 45 celadonite 5.34 3.61 -1.73 -0.102 0.29504E+04 46 celadonite-Fe 3.88 0.80 -3.07 -0.181 0.52488E+04 47 chrysotile 23.89 21.42 -2.47 -0.206 0.42171E+04 49 clinochlore 39.07 38.08 -0.99 -0.031 0.16835E+04 50 daphnite 28.97 24.03 -4.94 -0.154 0.84304E+04 52 chlorite-Al-free 47.17 42.85 -4.33 -0.180 0.73893E+04 54 chloritoid-Fe 9.17 4.63 -4.55 -0.303 0.77615E+04 55 chloritoid-Mn 11.40 7.45 -3.95 -0.263 0.67441E+04 57 coesite -2.38 -3.12 -0.75 -0.248 0.12725E+04 64 cristobalite -2.56 -3.12 -0.56 -0.187 0.95781E+03 66 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71239E+04 68 diaspore 2.87 0.67 -2.20 -0.367 0.37638E+04 70 diopside 16.18 15.77 -0.41 -0.041 0.70591E+03 71 hedenbergite 14.21 12.96 -1.25 -0.125 0.21369E+04 76 clinoenstatite 17.17 12.20 -4.97 -0.497 0.84783E+04 78 epidote 24.67 22.53 -2.14 -0.104 0.36591E+04 79 clinozoisite 22.81 18.22 -4.58 -0.208 0.78275E+04 80 epidote-Fe 29.84 26.83 -3.01 -0.156 0.51373E+04 81 fayalite 14.05 9.70 -4.35 -0.621 0.74204E+04 82 ferrosilite 11.15 6.58 -4.57 -0.457 0.78046E+04 86 gibbsite 4.08 0.67 -3.41 -0.487 0.58224E+04 87 glaucophane 22.97 20.65 -2.32 -0.063 0.39612E+04 89 graphite -3.55 -8.24 -4.70 -1.342 0.80207E+04 90 greenalite 16.14 12.99 -3.15 -0.263 0.53790E+04 93 hematite 12.57 9.95 -2.62 -0.317 0.44687E+04 94 heulandite -5.83 -7.72 -1.89 -0.086 0.32345E+04 98 jadeite 4.22 2.74 -1.48 -0.148 0.25234E+04 100 kalsilite 7.58 3.76 -3.83 -0.547 0.65364E+04 101 kaolinite -1.33 -4.90 -3.57 -0.325 0.60975E+04 104 laumontite 2.88 1.64 -1.24 -0.083 0.21191E+04 105 lawsonite 9.62 7.88 -1.73 -0.115 0.29559E+04 106 leucite 4.12 0.63 -3.48 -0.348 0.59494E+04 108 lizardite 23.24 21.42 -1.82 -0.152 0.31097E+04 110 magnetite 20.09 16.36 -3.73 -0.304 0.63651E+04 111 minnesotaite 10.39 6.75 -3.64 -0.214 0.62177E+04 115 manganosite 14.06 9.23 -4.82 -1.206 0.82372E+04 119 microcline -2.49 -2.49 0.00 0.000 0.50148E+00 123 muscovite 2.58 -1.15 -3.73 -0.219 0.63697E+04 124 paragonite 4.24 0.95 -3.28 -0.193 0.56083E+04 125 nepheline 8.34 5.86 -2.48 -0.354 0.42358E+04 137 phlogopite-Na 29.65 27.28 -2.37 -0.131 0.40389E+04 139 prehnite 19.37 17.55 -1.82 -0.107 0.31067E+04 140 prehnite-Fe 22.50 21.86 -0.64 -0.039 0.10933E+04 141 pumpellyite-Fe 46.27 42.18 -4.08 -0.091 0.69744E+04 142 pumpellyite-Mg 48.99 45.00 -4.00 -0.089 0.68281E+04 145 pyrite -21.25 -24.43 -3.18 -0.749 0.54327E+04 146 pyrrhotite -4.26 -7.57 -3.31 -1.104 0.56562E+04 147 pyrrhotiteFe0.875 -6.02 -8.73 -2.71 -0.998 0.46332E+04 148 pyroxmangite 7.40 6.11 -1.29 -0.257 0.21959E+04 149 pyrophyllite -6.18 -11.15 -4.97 -0.311 0.84872E+04 150 quartz -2.99 -3.12 -0.13 -0.044 0.22514E+03 154 rhodochrosite -0.98 -4.75 -3.78 -1.259 0.64504E+04 155 rhodonite 7.45 6.11 -1.33 -0.267 0.22762E+04 156 sanidine -1.28 -2.49 -1.21 -0.093 0.20683E+04 158 siderite -2.61 -7.58 -4.97 -1.656 0.84848E+04 166 stilbite -7.52 -7.72 -0.20 -0.009 0.34063E+03 167 stilpnomelane-Fe 13.02 11.53 -1.49 -0.045 0.25470E+04 168 stilpnomelane-Mg 27.44 25.58 -1.86 -0.056 0.31767E+04 174 talc 16.49 15.18 -1.31 -0.077 0.22385E+04 177 tephroite 18.09 15.35 -2.74 -0.391 0.46772E+04 181 tridymite -2.63 -3.12 -0.49 -0.165 0.84512E+03 182 tremolite 47.87 46.72 -1.15 -0.031 0.19693E+04 184 troilite-low -4.41 -7.57 -3.16 -1.054 0.53990E+04 190 wairakite 3.95 1.64 -2.31 -0.136 0.39411E+04 191 walstromite 11.51 9.67 -1.84 -0.368 0.31447E+04 192 wollastonite 10.46 9.67 -0.79 -0.159 0.13552E+04 193 pseudo-wollastonite 11.00 9.67 -1.33 -0.266 0.22750E+04 194 zoisite 22.85 18.22 -4.63 -0.210 0.79016E+04 195 akaganeite 7.75 4.97 -2.78 -0.601 0.47469E+04 202 chalcedony -2.80 -3.12 -0.32 -0.106 0.54444E+03 204 montmorillonite-Ca -2.29 -6.21 -3.92 -0.243 0.66989E+04 205 montmorillonite-K -2.24 -6.28 -4.04 -0.247 0.68963E+04 206 montmorillonite-Mg -2.48 -6.80 -4.32 -0.267 0.73809E+04 207 montmorillonite-Na -2.04 -5.58 -3.54 -0.217 0.60510E+04 208 nontronite-Ca 3.21 0.82 -2.39 -0.155 0.40802E+04 209 nontronite-H 2.53 -1.29 -3.82 -0.256 0.65190E+04 210 nontronite-K 3.34 0.76 -2.58 -0.165 0.44008E+04 211 nontronite-Mg 3.07 0.24 -2.84 -0.184 0.48463E+04 212 nontronite-Na 3.52 1.46 -2.06 -0.132 0.35215E+04 228 tobermorite 9.82 7.53 -2.29 -0.625 0.39123E+04 234 alabandite -0.98 -4.75 -3.77 -1.257 0.64402E+04 237 boehmite 4.41 0.67 -3.74 -0.623 0.63808E+04 239 ferrous-oxide 9.81 6.41 -3.40 -0.850 0.58071E+04 245 silica-amorphous -2.09 -3.12 -1.03 -0.343 0.17586E+04 247 an20ab80 2.02 1.27 -0.75 -0.058 0.12770E+04 248 an25ab75 2.65 1.68 -0.96 -0.074 0.16432E+04 249 an30ab70 3.28 2.10 -1.18 -0.091 0.20191E+04 250 tr.625ac.25prg.125 45.16 44.12 -1.05 -0.028 0.17848E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 0.0002000 MOLES Current total amount of reactant added: 0.0049900 MOLES New total amount of reactant added: 0.0051900 MOLES Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.5508E-08 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 7 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 0.0051900 Water: Moles liquid = 0.4985E+02 kg liquid = 0.8981E+00 Moles total = 0.4985E+02 kg total = 0.8981E+00 Activity = 1.0000 Stoichiometric ionic strength = .1166182E-01 Osmotic coef. = 0.9551 True ionic strength = .2032153E-01 Chg. balance for total moles = -.5508E-08 Max. difference allowed = 0.1685E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.96964E-10 -10.0134 0.81399E-10 -10.0894 0.83947E+00 -0.0760 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.18676E-03 -3.7287 0.15582E-03 -3.8074 0.83437E+00 -0.0786 4 SO4-- 0.10965E-04 -4.9600 0.56718E-05 -5.2463 0.51728E+00 -0.2863 5 HCO3- 0.15792E-03 -3.8016 0.13196E-03 -3.8796 0.83560E+00 -0.0780 6 HS- 0.15780E-03 -3.8019 0.13169E-03 -3.8805 0.83449E+00 -0.0786 7 Al+++ 0.10929E-28 -28.9614 0.25024E-29 -29.6016 0.22896E+00 -0.6402 8 H4SiO4 0.75890E-03 -3.1198 0.75890E-03 -3.1198 0.10000E+01 0.0000 9 Ca++ 0.77955E-07 -7.1082 0.40024E-07 -7.3977 0.51343E+00 -0.2895 10 Mg++ 0.21457E-10 -10.6684 0.10966E-10 -10.9600 0.51106E+00 -0.2915 11 Fe++ 0.33793E-13 -13.4712 0.17289E-13 -13.7622 0.51162E+00 -0.2910 12 K+ 0.15655E-03 -3.8054 0.13084E-03 -3.8833 0.83580E+00 -0.0779 13 Na+ 0.19879E-01 -1.7016 0.16584E-01 -1.7803 0.83421E+00 -0.0787 14 Mn++ 0.22162E-10 -10.6544 0.11348E-10 -10.9451 0.51205E+00 -0.2907 15 F- 0.24150E-05 -5.6171 0.20108E-05 -5.6966 0.83263E+00 -0.0795 16 HPO4-- 0.45395E-07 -7.3430 0.23485E-07 -7.6292 0.51735E+00 -0.2862 18 HSiO3- 0.10434E-01 -1.9816 0.87055E-02 -2.0602 0.83437E+00 -0.0786 19 Ca(HSiO3)+ 0.94920E-08 -8.0226 0.79352E-08 -8.1004 0.83598E+00 -0.0778 20 Mg(HSiO3)+ 0.32364E-11 -11.4899 0.27056E-11 -11.5677 0.83598E+00 -0.0778 21 NaHSiO3,aq 0.23350E-02 -2.6317 0.23350E-02 -2.6317 0.10000E+01 0.0000 22 AlO+ 0.61462E-16 -16.2114 0.51381E-16 -16.2892 0.83598E+00 -0.0778 24 HAlO2,aq 0.12571E-09 -9.9006 0.12571E-09 -9.9006 0.10000E+01 0.0000 25 AlO2- 0.41047E-05 -5.3867 0.34185E-05 -5.4662 0.83284E+00 -0.0794 26 CH4,aq 0.29867E-08 -8.5248 0.29761E-08 -8.5264 0.99645E+00 -0.0015 31 CO,aq 0.16056E-15 -15.7944 0.16056E-15 -15.7944 0.10000E+01 0.0000 32 CO2,aq 0.23033E-07 -7.6376 0.22951E-07 -7.6392 0.99645E+00 -0.0015 33 CO3-2 0.27433E-03 -3.5617 0.14160E-03 -3.8489 0.51617E+00 -0.2872 34 CaCO3,aq 0.71063E-07 -7.1484 0.71063E-07 -7.1484 0.10000E+01 0.0000 35 Ca(HCO3)+ 0.16127E-09 -9.7925 0.13482E-09 -9.8703 0.83598E+00 -0.0778 36 CaCl+ 0.12073E-10 -10.9182 0.10093E-10 -10.9960 0.83598E+00 -0.0778 37 CaCl2,aq 0.37365E-15 -15.4275 0.37365E-15 -15.4275 0.10000E+01 0.0000 38 CaF+ 0.14055E-11 -11.8522 0.11750E-11 -11.9300 0.83598E+00 -0.0778 39 CaOH+ 0.41919E-07 -7.3776 0.35044E-07 -7.4554 0.83598E+00 -0.0778 40 CaSO4,aq 0.72086E-10 -10.1421 0.72086E-10 -10.1421 0.10000E+01 0.0000 41 HCl,aq 0.23243E-14 -14.6337 0.23243E-14 -14.6337 0.10000E+01 0.0000 45 HF,aq 0.11205E-11 -11.9506 0.11205E-11 -11.9506 0.10000E+01 0.0000 46 HF2- 0.91167E-18 -18.0402 0.76067E-18 -18.1188 0.83437E+00 -0.0786 48 FeCl+ 0.51009E-17 -17.2924 0.42643E-17 -17.3702 0.83598E+00 -0.0778 51 FeF+ 0.21251E-17 -17.6726 0.17765E-17 -17.7504 0.83598E+00 -0.0778 53 FeO,aq 0.10142E-09 -9.9939 0.10142E-09 -9.9939 0.10000E+01 0.0000 54 FeOH+ 0.82703E-11 -11.0825 0.69139E-11 -11.1603 0.83598E+00 -0.0778 55 HFeO2- 0.15624E-07 -7.8062 0.13036E-07 -7.8849 0.83437E+00 -0.0786 56 FeO+ 0.37381E-16 -16.4273 0.31250E-16 -16.5051 0.83598E+00 -0.0778 58 FeO2- 0.11567E-08 -8.9368 0.96509E-09 -9.0154 0.83437E+00 -0.0786 59 HFeO2,aq 0.99913E-11 -11.0004 0.99913E-11 -11.0004 0.10000E+01 0.0000 60 H2,aq 0.27947E-06 -6.5537 0.27847E-06 -6.5552 0.99645E+00 -0.0015 61 KCl,aq 0.36952E-09 -9.4324 0.36952E-09 -9.4324 0.10000E+01 0.0000 62 KHSO4,aq 0.17079E-18 -18.7675 0.17079E-18 -18.7675 0.10000E+01 0.0000 63 KOH,aq 0.68645E-06 -6.1634 0.68645E-06 -6.1634 0.10000E+01 0.0000 64 KSO4- 0.13802E-07 -7.8601 0.11516E-07 -7.9387 0.83437E+00 -0.0786 65 MgCO3,aq 0.48801E-11 -11.3116 0.48801E-11 -11.3116 0.10000E+01 0.0000 66 Mg(HCO3)+ 0.45146E-13 -13.3454 0.37742E-13 -13.4232 0.83598E+00 -0.0778 67 MgCl+ 0.29980E-14 -14.5232 0.25063E-14 -14.6010 0.83598E+00 -0.0778 68 MgF+ 0.14265E-14 -14.8457 0.11925E-14 -14.9235 0.83598E+00 -0.0778 69 MgOH+ 0.63551E-10 -10.1969 0.53127E-10 -10.2747 0.83598E+00 -0.0778 71 MnF+ 0.45976E-15 -15.3375 0.38435E-15 -15.4153 0.83598E+00 -0.0778 72 MnO,aq 0.17737E-08 -8.7511 0.17737E-08 -8.7511 0.10000E+01 0.0000 73 MnOH+ 0.50429E-09 -9.2973 0.42158E-09 -9.3751 0.83598E+00 -0.0778 74 MnO2-2 0.17212E-10 -10.7642 0.88844E-11 -11.0514 0.51617E+00 -0.2872 75 HMnO2- 0.18989E-09 -9.7215 0.15844E-09 -9.8001 0.83437E+00 -0.0786 78 MnCl+ 0.13026E-13 -13.8852 0.10889E-13 -13.9630 0.83598E+00 -0.0778 79 MnSO4,aq 0.18582E-13 -13.7309 0.18582E-13 -13.7309 0.10000E+01 0.0000 80 NaCl,aq 0.85639E-06 -6.0673 0.85639E-06 -6.0673 0.10000E+01 0.0000 81 NaF,aq 0.78069E-08 -8.1075 0.78069E-08 -8.1075 0.10000E+01 0.0000 82 NaOH,aq 0.87534E-04 -4.0578 0.87534E-04 -4.0578 0.10000E+01 0.0000 84 OH- 0.85227E-02 -2.0694 0.70981E-02 -2.1489 0.83284E+00 -0.0794 89 HPO3-2 0.39485E-16 -16.4036 0.20381E-16 -16.6908 0.51617E+00 -0.2872 92 H3PO4,aq 0.10883E-17 -17.9632 0.10883E-17 -17.9632 0.10000E+01 0.0000 93 H2PO4- 0.42225E-10 -10.3744 0.35265E-10 -10.4527 0.83517E+00 -0.0782 94 PO4-3 0.97832E-09 -9.0095 0.23540E-09 -9.6282 0.24062E+00 -0.6187 98 HP2O7-3 0.10437E-17 -17.9814 0.23921E-18 -18.6212 0.22920E+00 -0.6398 99 P2O7-4 0.92484E-17 -17.0339 0.70205E-18 -18.1536 0.75911E-01 -1.1197 100 H2S,aq 0.33247E-07 -7.4782 0.33129E-07 -7.4798 0.99645E+00 -0.0015 101 S2-2 0.26733E-11 -11.5730 0.13798E-11 -11.8602 0.51617E+00 -0.2872 102 S3-2 0.42846E-18 -18.3681 0.22116E-18 -18.6553 0.51617E+00 -0.2872 107 SO3-2 0.39190E-12 -12.4068 0.20525E-12 -12.6877 0.52372E+00 -0.2809 108 HSO3- 0.12537E-14 -14.9018 0.10461E-14 -14.9804 0.83437E+00 -0.0786 109 HSO4- 0.53169E-12 -12.2743 0.44492E-12 -12.3517 0.83681E+00 -0.0774 111 S2O3-2 0.42762E-14 -14.3689 0.22072E-14 -14.6562 0.51617E+00 -0.2872 Charge balance for all species = -.6132E-08 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.9696380E-10 -.2167055E-01 -.2180424E+02 0.0000 2 H2O 0.1000000E+01 0.5550410E+02 0.9981665E+06 0.0000 3 Cl- 0.1867582E-03 0.1876150E-03 0.6639828E+01 6.2820 4 SO4-- 0.1096467E-04 0.1090584E-04 0.1045792E+01 14.9325 5 HCO3- 0.1579187E-03 0.4323439E-03 0.2633407E+02 6.2098 6 HS- 0.1578047E-03 0.1579106E-03 0.5213247E+01 6.2089 7 Al+++ 0.1092934E-28 0.4104785E-05 0.1105587E+00 0.6665 8 H4SiO4 0.7589040E-03 0.1352760E-01 0.1297927E+04 -3.1198 9 Ca++ 0.7795451E-07 0.2006757E-06 0.8028553E-02 12.7811 10 Mg++ 0.2145671E-10 0.9317359E-10 0.2261257E-05 9.2188 11 Fe++ 0.3379271E-13 0.1690033E-07 0.9421750E-03 6.4165 12 K+ 0.1565452E-03 0.1572459E-03 0.6137827E+01 6.2061 13 Na+ 0.1987936E-01 0.2230274E-01 0.5118347E+03 8.3091 14 Mn++ 0.2216241E-10 0.2507326E-08 0.1375055E-03 9.2337 15 F- 0.2414965E-05 0.2422775E-05 0.4594702E-01 4.3927 16 HPO4-- 0.4539539E-07 0.4641594E-07 0.4447130E-02 12.5496 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.1946771E-01 -.1946326E-01 -.4441852E-05 0.0000000E+00 2 H2O 0.4985066E+02 0.4985066E+02 -.4358758E-05 0.0000000E+00 3 Cl- 0.1685052E-03 0.1685052E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.9797190E-05 0.9795013E-05 0.2176668E-08 0.0000000E+00 5 HCO3- 0.3883070E-03 0.3883070E-03 0.0000000E+00 0.0000000E+00 6 HS- 0.1418243E-03 0.1418265E-03 -.2176668E-08 0.0000000E+00 7 Al+++ 0.4775352E-05 0.3686687E-05 0.1088665E-05 0.0000000E+00 8 H4SiO4 0.1215302E-01 0.1214973E-01 0.3290386E-05 0.0000000E+00 9 Ca++ 0.2080835E-06 0.1802356E-06 0.2784785E-07 0.0000000E+00 10 Mg++ 0.8368328E-10 0.8368328E-10 0.0000000E+00 0.0000000E+00 11 Fe++ 0.3259227E-07 0.1517893E-07 0.1741334E-07 0.0000000E+00 12 K+ 0.1412294E-03 0.1412294E-03 0.0000000E+00 0.0000000E+00 13 Na+ 0.2003215E-01 0.2003106E-01 0.1087513E-05 0.0000000E+00 14 Mn++ 0.2251939E-08 0.2251939E-08 0.0000000E+00 0.0000000E+00 15 F- 0.2176000E-05 0.2176000E-05 0.0000000E+00 0.0000000E+00 16 HPO4-- 0.4168819E-07 0.4168819E-07 0.0000000E+00 0.0000000E+00 Chg. balance for solid moles: 0.0000E+00 Mass of aqueous solution: 0.899724E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 0.0051900 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 0.1088E-05 -5.964 0.2852E-03 -3.545 98.38 0.1095E-03 andradite 0.8707E-08 -8.060 0.4425E-05 -5.354 1.526 0.1150E-05 grossular 0.5759E-09 -9.240 0.2594E-06 -6.586 0.8951E-01 0.7219E-07 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.9380E+00 0.9380E+00 1.0000 -0.028 grossular 0.6205E-01 0.6205E-01 1.0000 -1.207 Solid products produced: Mass = 0.000290 g Volume = 0.000111 cm3 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.0051900 moles log = -2.2848 Original solution: 1000.0103000 g Original solution / Rock added: 192680.21 (Water/Rock Ratio), log = 5.2848 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0207 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9996E+00 0.9859 0.1006E+01 0.1020E+01 CO2,gas 0.2389E-05 1.0071 0.2456E-05 0.2438E-05 CH4,gas 0.4239E-05 1.0125 0.4381E-05 0.4326E-05 H2,gas 0.3580E-03 1.0005 0.3656E-03 0.3654E-03 H2S,gas 0.8958E-06 0.9960 0.9107E-06 0.9143E-06 S2,gas 0.2282E-24 1.0000 0.2329E-24 0.2329E-24 CO,gas 0.2344E-12 1.0000 0.2393E-12 0.2393E-12 SO3,gas 0.1392E-40 1.0000 0.1421E-40 0.1421E-40 SO2,gas 0.1980E-21 1.0000 0.2021E-21 0.2021E-21 HF,gas 0.2695E-14 1.0000 0.2751E-14 0.2751E-14 HCl,gas 0.4018E-17 1.0000 0.4101E-17 0.4101E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 17 albite -0.38 -0.38 0.00 0.000 -0.94784E-12 23 andradite 39.01 39.01 0.00 0.000 -0.24265E-10 24 grossular 32.73 32.73 0.00 0.000 -0.12132E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -13.97 -7.31 -2.436 0.12480E+05 -5.610 3 CH4,gas 4.54 -2.51 -7.06 -1.764 0.12050E+05 -5.358 4 H2,gas 8.00 2.86 -5.14 -2.935 0.87695E+04 -3.437 5 H2S,gas -6.23 -13.97 -7.74 -3.870 0.13215E+05 -6.041 6 S2,gas -7.34 -33.67 -26.33 -4.051 0.44961E+05 -24.633 7 CO,gas 3.21 -11.11 -14.32 -4.406 0.24451E+05 -12.621 8 SO3,gas 17.12 -25.43 -42.55 -10.637 0.72647E+05 -40.847 9 SO2,gas 0.83 -22.56 -23.39 -6.238 0.39944E+05 -21.694 10 HF,gas 0.47 -15.79 -16.26 -8.130 0.27763E+05 -14.560 11 HCl,gas 5.19 -13.90 -19.09 -9.543 0.32589E+05 -17.387 12 acmite 7.71 7.05 -0.66 -0.068 0.11195E+04 16 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 20 spessartine 24.46 19.67 -4.78 -0.239 0.81663E+04 21 analcite 3.32 2.74 -0.59 -0.065 0.10004E+04 27 annite 20.12 16.76 -3.36 -0.187 0.57381E+04 28 phlogopite 27.06 25.17 -1.89 -0.105 0.32357E+04 30 anorthite 12.71 7.87 -4.84 -0.372 0.82570E+04 33 apatite-OH -18.15 -19.52 -1.36 -0.105 0.23306E+04 34 apatite-F -34.30 -35.30 -1.00 -0.084 0.17134E+04 38 aragonite 0.97 -1.19 -2.15 -0.718 0.36785E+04 39 brucite 12.57 9.22 -3.35 -0.670 0.57196E+04 40 calcite 0.81 -1.19 -2.00 -0.667 0.34143E+04 41 carnegieite-low 9.02 5.86 -3.17 -0.453 0.54085E+04 42 carnegieite-high 10.09 5.86 -4.24 -0.605 0.72355E+04 43 carpholite-Mg 8.58 4.31 -4.27 -0.285 0.72907E+04 45 celadonite 5.34 3.61 -1.73 -0.102 0.29529E+04 46 celadonite-Fe 3.88 0.81 -3.07 -0.180 0.52361E+04 47 chrysotile 23.89 21.42 -2.48 -0.206 0.42271E+04 49 clinochlore 39.07 38.07 -1.00 -0.031 0.17108E+04 50 daphnite 28.97 24.06 -4.91 -0.153 0.83819E+04 52 chlorite-Al-free 47.17 42.83 -4.34 -0.181 0.74093E+04 54 chloritoid-Fe 9.17 4.63 -4.54 -0.303 0.77585E+04 55 chloritoid-Mn 11.40 7.45 -3.95 -0.264 0.67516E+04 57 coesite -2.38 -3.12 -0.74 -0.248 0.12699E+04 64 cristobalite -2.56 -3.12 -0.56 -0.186 0.95529E+03 66 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71239E+04 68 diaspore 2.87 0.67 -2.21 -0.368 0.37687E+04 70 diopside 16.18 15.76 -0.42 -0.042 0.71901E+03 71 hedenbergite 14.21 12.96 -1.25 -0.125 0.21348E+04 76 clinoenstatite 17.17 12.20 -4.97 -0.497 0.84833E+04 78 epidote 24.67 22.52 -2.15 -0.104 0.36702E+04 79 clinozoisite 22.81 18.20 -4.60 -0.209 0.78608E+04 80 epidote-Fe 29.84 26.84 -3.00 -0.156 0.51263E+04 81 fayalite 14.05 9.71 -4.33 -0.619 0.73976E+04 82 ferrosilite 11.15 6.59 -4.56 -0.456 0.77792E+04 86 gibbsite 4.08 0.67 -3.41 -0.488 0.58273E+04 87 glaucophane 22.97 20.65 -2.33 -0.063 0.39712E+04 89 graphite -3.55 -8.24 -4.70 -1.341 0.80169E+04 90 greenalite 16.14 13.01 -3.13 -0.261 0.53436E+04 93 hematite 12.57 9.97 -2.60 -0.315 0.44341E+04 94 heulandite -5.83 -7.72 -1.90 -0.086 0.32396E+04 98 jadeite 4.22 2.74 -1.48 -0.148 0.25259E+04 100 kalsilite 7.58 3.75 -3.83 -0.547 0.65415E+04 101 kaolinite -1.33 -4.91 -3.57 -0.325 0.61022E+04 104 laumontite 2.88 1.63 -1.25 -0.083 0.21319E+04 105 lawsonite 9.62 7.87 -1.74 -0.116 0.29737E+04 106 leucite 4.12 0.63 -3.49 -0.349 0.59520E+04 108 lizardite 23.24 21.42 -1.83 -0.152 0.31197E+04 110 magnetite 20.09 16.39 -3.70 -0.302 0.63203E+04 111 minnesotaite 10.39 6.77 -3.62 -0.213 0.61772E+04 115 manganosite 14.06 9.23 -4.82 -1.206 0.82376E+04 119 microcline -2.49 -2.49 0.00 0.000 0.52649E+00 123 muscovite 2.58 -1.15 -3.74 -0.220 0.63795E+04 124 paragonite 4.24 0.95 -3.29 -0.194 0.56181E+04 125 nepheline 8.34 5.86 -2.48 -0.355 0.42408E+04 137 phlogopite-Na 29.65 27.27 -2.37 -0.132 0.40539E+04 139 prehnite 19.37 17.54 -1.84 -0.108 0.31351E+04 140 prehnite-Fe 22.50 21.85 -0.64 -0.039 0.10996E+04 141 pumpellyite-Fe 46.27 42.15 -4.11 -0.091 0.70260E+04 142 pumpellyite-Mg 48.99 44.96 -4.04 -0.090 0.68948E+04 145 pyrite -21.25 -24.39 -3.14 -0.739 0.53615E+04 146 pyrrhotite -4.26 -7.55 -3.29 -1.098 0.56227E+04 147 pyrrhotiteFe0.875 -6.02 -8.71 -2.69 -0.991 0.45991E+04 148 pyroxmangite 7.40 6.11 -1.28 -0.257 0.21938E+04 149 pyrophyllite -6.18 -11.15 -4.97 -0.311 0.84869E+04 150 quartz -2.99 -3.12 -0.13 -0.043 0.22262E+03 154 rhodochrosite -0.98 -4.74 -3.76 -1.253 0.64183E+04 155 rhodonite 7.45 6.11 -1.33 -0.266 0.22740E+04 156 sanidine -1.28 -2.49 -1.21 -0.093 0.20683E+04 158 siderite -2.61 -7.55 -4.94 -1.648 0.84422E+04 166 stilbite -7.52 -7.72 -0.20 -0.010 0.34581E+03 167 stilpnomelane-Fe 13.02 11.56 -1.46 -0.043 0.24873E+04 168 stilpnomelane-Mg 27.44 25.57 -1.87 -0.056 0.31927E+04 174 talc 16.49 15.18 -1.31 -0.077 0.22435E+04 177 tephroite 18.09 15.35 -2.74 -0.391 0.46754E+04 181 tridymite -2.63 -3.12 -0.49 -0.164 0.84259E+03 182 tremolite 47.87 46.70 -1.17 -0.032 0.20004E+04 184 troilite-low -4.41 -7.55 -3.14 -1.047 0.53655E+04 190 wairakite 3.95 1.63 -2.32 -0.136 0.39538E+04 191 walstromite 11.51 9.66 -1.85 -0.370 0.31553E+04 192 wollastonite 10.46 9.66 -0.80 -0.160 0.13658E+04 193 pseudo-wollastonite 11.00 9.66 -1.34 -0.268 0.22856E+04 194 zoisite 22.85 18.20 -4.65 -0.211 0.79348E+04 195 akaganeite 7.75 4.98 -2.77 -0.599 0.47296E+04 202 chalcedony -2.80 -3.12 -0.32 -0.106 0.54191E+03 204 montmorillonite-Ca -2.29 -6.22 -3.92 -0.243 0.67008E+04 205 montmorillonite-K -2.24 -6.28 -4.04 -0.247 0.68969E+04 206 montmorillonite-Mg -2.48 -6.80 -4.32 -0.267 0.73814E+04 207 montmorillonite-Na -2.04 -5.58 -3.54 -0.217 0.60516E+04 208 nontronite-Ca 3.21 0.85 -2.37 -0.153 0.40401E+04 209 nontronite-H 2.53 -1.26 -3.79 -0.254 0.64768E+04 210 nontronite-K 3.34 0.79 -2.55 -0.164 0.43595E+04 211 nontronite-Mg 3.07 0.26 -2.81 -0.183 0.48048E+04 212 nontronite-Na 3.52 1.48 -2.04 -0.131 0.34802E+04 228 tobermorite 9.82 7.53 -2.30 -0.627 0.39207E+04 234 alabandite -0.98 -4.74 -3.76 -1.253 0.64172E+04 237 boehmite 4.41 0.67 -3.74 -0.623 0.63856E+04 239 ferrous-oxide 9.81 6.42 -3.40 -0.849 0.57969E+04 245 silica-amorphous -2.09 -3.12 -1.03 -0.343 0.17561E+04 247 an20ab80 2.02 1.27 -0.75 -0.058 0.12806E+04 248 an25ab75 2.65 1.68 -0.96 -0.074 0.16477E+04 249 an30ab70 3.28 2.09 -1.19 -0.091 0.20244E+04 250 tr.625ac.25prg.125 45.16 44.11 -1.05 -0.028 0.17992E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 0.0002000 MOLES Current total amount of reactant added: 0.0051900 MOLES New total amount of reactant added: 0.0053900 MOLES Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.5508E-08 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 7 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 0.0053900 Water: Moles liquid = 0.4985E+02 kg liquid = 0.8981E+00 Moles total = 0.4985E+02 kg total = 0.8981E+00 Activity = 1.0000 Stoichiometric ionic strength = .1167463E-01 Osmotic coef. = 0.9546 True ionic strength = .2033320E-01 Chg. balance for total moles = -.5508E-08 Max. difference allowed = 0.1697E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.97323E-10 -10.0118 0.81697E-10 -10.0878 0.83945E+00 -0.0760 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.18807E-03 -3.7257 0.15691E-03 -3.8044 0.83434E+00 -0.0787 4 SO4-- 0.12025E-04 -4.9199 0.62195E-05 -5.2062 0.51720E+00 -0.2863 5 HCO3- 0.16417E-03 -3.7847 0.13717E-03 -3.8627 0.83557E+00 -0.0780 6 HS- 0.16215E-03 -3.7901 0.13531E-03 -3.8687 0.83446E+00 -0.0786 7 Al+++ 0.10981E-28 -28.9593 0.25135E-29 -29.5997 0.22888E+00 -0.6404 8 H4SiO4 0.76150E-03 -3.1183 0.76150E-03 -3.1183 0.10000E+01 0.0000 9 Ca++ 0.77180E-07 -7.1125 0.39621E-07 -7.4021 0.51336E+00 -0.2896 10 Mg++ 0.21472E-10 -10.6681 0.10972E-10 -10.9597 0.51098E+00 -0.2916 11 Fe++ 0.34536E-13 -13.4617 0.17667E-13 -13.7528 0.51154E+00 -0.2911 12 K+ 0.15655E-03 -3.8054 0.13084E-03 -3.8833 0.83577E+00 -0.0779 13 Na+ 0.19880E-01 -1.7016 0.16584E-01 -1.7803 0.83418E+00 -0.0787 14 Mn++ 0.22318E-10 -10.6514 0.11426E-10 -10.9421 0.51197E+00 -0.2908 15 F- 0.25037E-05 -5.6014 0.20846E-05 -5.6810 0.83260E+00 -0.0796 16 HPO4-- 0.45398E-07 -7.3430 0.23483E-07 -7.6292 0.51727E+00 -0.2863 18 HSiO3- 0.10432E-01 -1.9817 0.87034E-02 -2.0603 0.83434E+00 -0.0787 19 Ca(HSiO3)+ 0.93942E-08 -8.0271 0.78531E-08 -8.1050 0.83595E+00 -0.0778 20 Mg(HSiO3)+ 0.32375E-11 -11.4898 0.27064E-11 -11.5676 0.83595E+00 -0.0778 21 NaHSiO3,aq 0.23344E-02 -2.6318 0.23344E-02 -2.6318 0.10000E+01 0.0000 22 AlO+ 0.61285E-16 -16.2126 0.51231E-16 -16.2905 0.83595E+00 -0.0778 24 HAlO2,aq 0.12488E-09 -9.9035 0.12488E-09 -9.9035 0.10000E+01 0.0000 25 AlO2- 0.40630E-05 -5.3912 0.33837E-05 -5.4706 0.83281E+00 -0.0795 26 CH4,aq 0.29093E-08 -8.5362 0.28989E-08 -8.5378 0.99644E+00 -0.0015 31 CO,aq 0.16466E-15 -15.7834 0.16466E-15 -15.7834 0.10000E+01 0.0000 32 CO2,aq 0.24032E-07 -7.6192 0.23946E-07 -7.6208 0.99644E+00 -0.0015 33 CO3-2 0.28417E-03 -3.5464 0.14666E-03 -3.8337 0.51609E+00 -0.2873 34 CaCO3,aq 0.72860E-07 -7.1375 0.72860E-07 -7.1375 0.10000E+01 0.0000 35 Ca(HCO3)+ 0.16596E-09 -9.7800 0.13873E-09 -9.8578 0.83595E+00 -0.0778 36 CaCl+ 0.12035E-10 -10.9195 0.10061E-10 -10.9974 0.83595E+00 -0.0778 37 CaCl2,aq 0.37505E-15 -15.4259 0.37505E-15 -15.4259 0.10000E+01 0.0000 38 CaF+ 0.14425E-11 -11.8409 0.12059E-11 -11.9187 0.83595E+00 -0.0778 39 CaOH+ 0.41346E-07 -7.3836 0.34563E-07 -7.4614 0.83595E+00 -0.0778 40 CaSO4,aq 0.78250E-10 -10.1065 0.78250E-10 -10.1065 0.10000E+01 0.0000 41 HCl,aq 0.23490E-14 -14.6291 0.23490E-14 -14.6291 0.10000E+01 0.0000 45 HF,aq 0.11659E-11 -11.9334 0.11659E-11 -11.9334 0.10000E+01 0.0000 46 HF2- 0.98348E-18 -18.0072 0.82055E-18 -18.0859 0.83434E+00 -0.0787 48 FeCl+ 0.52488E-17 -17.2799 0.43878E-17 -17.3578 0.83595E+00 -0.0778 51 FeF+ 0.22513E-17 -17.6476 0.18820E-17 -17.7254 0.83595E+00 -0.0778 53 FeO,aq 0.10288E-09 -9.9877 0.10288E-09 -9.9877 0.10000E+01 0.0000 54 FeOH+ 0.84205E-11 -11.0747 0.70391E-11 -11.1525 0.83595E+00 -0.0778 55 HFeO2- 0.15792E-07 -7.8016 0.13175E-07 -7.8802 0.83434E+00 -0.0787 56 FeO+ 0.38388E-16 -16.4158 0.32091E-16 -16.4936 0.83595E+00 -0.0778 58 FeO2- 0.11792E-08 -8.9284 0.98382E-09 -9.0071 0.83434E+00 -0.0787 59 HFeO2,aq 0.10223E-10 -10.9904 0.10223E-10 -10.9904 0.10000E+01 0.0000 60 H2,aq 0.27471E-06 -6.5611 0.27373E-06 -6.5627 0.99644E+00 -0.0015 61 KCl,aq 0.37208E-09 -9.4294 0.37208E-09 -9.4294 0.10000E+01 0.0000 62 KHSO4,aq 0.18796E-18 -18.7259 0.18796E-18 -18.7259 0.10000E+01 0.0000 63 KOH,aq 0.68392E-06 -6.1650 0.68392E-06 -6.1650 0.10000E+01 0.0000 64 KSO4- 0.15134E-07 -7.8200 0.12627E-07 -7.8987 0.83434E+00 -0.0787 65 MgCO3,aq 0.50573E-11 -11.2961 0.50573E-11 -11.2961 0.10000E+01 0.0000 66 Mg(HCO3)+ 0.46958E-13 -13.3283 0.39255E-13 -13.4061 0.83595E+00 -0.0778 67 MgCl+ 0.30206E-14 -14.5199 0.25251E-14 -14.5977 0.83595E+00 -0.0778 68 MgF+ 0.14797E-14 -14.8298 0.12370E-14 -14.9076 0.83595E+00 -0.0778 69 MgOH+ 0.63355E-10 -10.1982 0.52962E-10 -10.2760 0.83595E+00 -0.0778 71 MnF+ 0.47993E-15 -15.3188 0.40120E-15 -15.3966 0.83595E+00 -0.0778 72 MnO,aq 0.17729E-08 -8.7513 0.17729E-08 -8.7513 0.10000E+01 0.0000 73 MnOH+ 0.50591E-09 -9.2959 0.42292E-09 -9.3737 0.83595E+00 -0.0778 74 MnO2-2 0.17081E-10 -10.7675 0.88152E-11 -11.0548 0.51609E+00 -0.2873 75 HMnO2- 0.18911E-09 -9.7233 0.15778E-09 -9.8019 0.83434E+00 -0.0787 78 MnCl+ 0.13207E-13 -13.8792 0.11040E-13 -13.9570 0.83595E+00 -0.0778 79 MnSO4,aq 0.20516E-13 -13.6879 0.20516E-13 -13.6879 0.10000E+01 0.0000 80 NaCl,aq 0.86235E-06 -6.0643 0.86235E-06 -6.0643 0.10000E+01 0.0000 81 NaF,aq 0.80935E-08 -8.0919 0.80935E-08 -8.0919 0.10000E+01 0.0000 82 NaOH,aq 0.87214E-04 -4.0594 0.87214E-04 -4.0594 0.10000E+01 0.0000 84 OH- 0.84919E-02 -2.0710 0.70721E-02 -2.1504 0.83281E+00 -0.0795 89 HPO3-2 0.38816E-16 -16.4110 0.20032E-16 -16.6983 0.51609E+00 -0.2873 92 H3PO4,aq 0.10962E-17 -17.9601 0.10962E-17 -17.9601 0.10000E+01 0.0000 93 H2PO4- 0.42378E-10 -10.3729 0.35392E-10 -10.4511 0.83514E+00 -0.0782 94 PO4-3 0.97498E-09 -9.0110 0.23452E-09 -9.6298 0.24054E+00 -0.6188 98 HP2O7-3 0.10477E-17 -17.9798 0.24004E-18 -18.6197 0.22912E+00 -0.6399 99 P2O7-4 0.92523E-17 -17.0337 0.70193E-18 -18.1537 0.75865E-01 -1.1200 100 H2S,aq 0.34287E-07 -7.4649 0.34165E-07 -7.4664 0.99644E+00 -0.0015 101 S2-2 0.28717E-11 -11.5419 0.14820E-11 -11.8291 0.51609E+00 -0.2873 102 S3-2 0.48289E-18 -18.3162 0.24921E-18 -18.6034 0.51609E+00 -0.2873 107 SO3-2 0.42249E-12 -12.3742 0.22124E-12 -12.6551 0.52364E+00 -0.2810 108 HSO3- 0.13564E-14 -14.8676 0.11317E-14 -14.9463 0.83434E+00 -0.0787 109 HSO4- 0.58520E-12 -12.2327 0.48968E-12 -12.3101 0.83678E+00 -0.0774 111 S2O3-2 0.48365E-14 -14.3155 0.24961E-14 -14.6027 0.51609E+00 -0.2873 Charge balance for all species = -.6132E-08 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.9732284E-10 -.2164632E-01 -.2177985E+02 0.0000 2 H2O 0.1000000E+01 0.5550407E+02 0.9981652E+06 0.0000 3 Cl- 0.1880653E-03 0.1889281E-03 0.6686295E+01 6.2834 4 SO4-- 0.1202535E-04 0.1196912E-04 0.1147753E+01 14.9693 5 HCO3- 0.1641680E-03 0.4484421E-03 0.2731459E+02 6.2251 6 HS- 0.1621521E-03 0.1622579E-03 0.5356761E+01 6.2191 7 Al+++ 0.1098137E-28 0.4063135E-05 0.1094368E+00 0.6637 8 H4SiO4 0.7614981E-03 0.1352742E-01 0.1297909E+04 -3.1183 9 Ca++ 0.7717958E-07 0.2010373E-06 0.8043014E-02 12.7735 10 Mg++ 0.2147170E-10 0.9317324E-10 0.2261247E-05 9.2159 11 Fe++ 0.3453642E-13 0.1709228E-07 0.9528751E-03 6.4227 12 K+ 0.1565458E-03 0.1572453E-03 0.6137799E+01 6.2045 13 Na+ 0.1988012E-01 0.2230261E-01 0.5118314E+03 8.3075 14 Mn++ 0.2231771E-10 0.2507316E-08 0.1375049E-03 9.2335 15 F- 0.2503742E-05 0.2511838E-05 0.4763603E-01 4.4068 16 HPO4-- 0.4539841E-07 0.4641577E-07 0.4447110E-02 12.5463 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.1944617E-01 -.1944158E-01 -.4590497E-05 0.0000000E+00 2 H2O 0.4985082E+02 0.4985083E+02 -.4508424E-05 0.0000000E+00 3 Cl- 0.1696852E-03 0.1696852E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.1075219E-04 0.1075003E-04 0.2155111E-08 0.0000000E+00 5 HCO3- 0.4027670E-03 0.4027670E-03 0.0000000E+00 0.0000000E+00 6 HS- 0.1457293E-03 0.1457314E-03 -.2155111E-08 0.0000000E+00 7 Al+++ 0.4775352E-05 0.3649294E-05 0.1126058E-05 0.0000000E+00 8 H4SiO4 0.1215302E-01 0.1214962E-01 0.3402375E-05 0.0000000E+00 9 Ca++ 0.2080835E-06 0.1805611E-06 0.2752240E-07 0.0000000E+00 10 Mg++ 0.8368328E-10 0.8368328E-10 0.0000000E+00 0.0000000E+00 11 Fe++ 0.3259227E-07 0.1535138E-07 0.1724089E-07 0.0000000E+00 12 K+ 0.1412294E-03 0.1412294E-03 0.0000000E+00 0.0000000E+00 13 Na+ 0.2003215E-01 0.2003103E-01 0.1124951E-05 0.0000000E+00 14 Mn++ 0.2251939E-08 0.2251939E-08 0.0000000E+00 0.0000000E+00 15 F- 0.2256000E-05 0.2256000E-05 0.0000000E+00 0.0000000E+00 16 HPO4-- 0.4168819E-07 0.4168819E-07 0.0000000E+00 0.0000000E+00 Chg. balance for solid moles: 0.4235E-21 Mass of aqueous solution: 0.899728E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 0.0053900 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 0.1125E-05 -5.949 0.2950E-03 -3.530 98.45 0.1132E-03 andradite 0.8620E-08 -8.064 0.4381E-05 -5.358 1.462 0.1138E-05 grossular 0.5537E-09 -9.257 0.2494E-06 -6.603 0.8324E-01 0.6940E-07 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.9396E+00 0.9396E+00 1.0000 -0.027 grossular 0.6035E-01 0.6035E-01 1.0000 -1.219 Solid products produced: Mass = 0.000300 g Volume = 0.000114 cm3 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.0053900 moles log = -2.2684 Original solution: 1000.0103000 g Original solution / Rock added: 185530.67 (Water/Rock Ratio), log = 5.2684 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0207 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9996E+00 0.9859 0.1006E+01 0.1020E+01 CO2,gas 0.2492E-05 1.0071 0.2562E-05 0.2544E-05 CH4,gas 0.4129E-05 1.0125 0.4267E-05 0.4214E-05 H2,gas 0.3519E-03 1.0005 0.3594E-03 0.3592E-03 H2S,gas 0.9238E-06 0.9960 0.9392E-06 0.9429E-06 S2,gas 0.2512E-24 1.0000 0.2564E-24 0.2564E-24 CO,gas 0.2404E-12 1.0000 0.2454E-12 0.2454E-12 SO3,gas 0.1538E-40 1.0000 0.1570E-40 0.1570E-40 SO2,gas 0.2150E-21 1.0000 0.2194E-21 0.2194E-21 HF,gas 0.2805E-14 1.0000 0.2863E-14 0.2863E-14 HCl,gas 0.4061E-17 1.0000 0.4145E-17 0.4145E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 17 albite -0.38 -0.38 0.00 0.000 -0.94784E-12 23 andradite 39.01 39.01 0.00 0.000 -0.12132E-10 24 grossular 32.73 32.73 0.00 0.000 0.00000E+00 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -13.95 -7.29 -2.430 0.12448E+05 -5.591 3 CH4,gas 4.54 -2.53 -7.07 -1.767 0.12070E+05 -5.370 4 H2,gas 8.00 2.86 -5.14 -2.939 0.87822E+04 -3.444 5 H2S,gas -6.23 -13.96 -7.73 -3.863 0.13192E+05 -6.027 6 S2,gas -7.34 -33.63 -26.29 -4.045 0.44890E+05 -24.591 7 CO,gas 3.21 -11.09 -14.31 -4.403 0.24432E+05 -12.610 8 SO3,gas 17.12 -25.38 -42.50 -10.626 0.72573E+05 -40.804 9 SO2,gas 0.83 -22.53 -23.36 -6.229 0.39883E+05 -21.659 10 HF,gas 0.47 -15.77 -16.24 -8.121 0.27733E+05 -14.543 11 HCl,gas 5.19 -13.89 -19.08 -9.541 0.32581E+05 -17.382 12 acmite 7.71 7.07 -0.64 -0.067 0.11002E+04 16 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 20 spessartine 24.46 19.67 -4.78 -0.239 0.81695E+04 21 analcite 3.32 2.73 -0.59 -0.065 0.10030E+04 27 annite 20.12 16.78 -3.34 -0.186 0.57063E+04 28 phlogopite 27.06 25.16 -1.90 -0.106 0.32508E+04 30 anorthite 12.71 7.86 -4.85 -0.373 0.82747E+04 33 apatite-OH -18.15 -19.55 -1.39 -0.107 0.23793E+04 34 apatite-F -34.30 -35.32 -1.01 -0.085 0.17326E+04 38 aragonite 0.97 -1.18 -2.14 -0.715 0.36600E+04 39 brucite 12.57 9.22 -3.35 -0.671 0.57247E+04 40 calcite 0.81 -1.18 -1.99 -0.663 0.33958E+04 41 carnegieite-low 9.02 5.85 -3.17 -0.453 0.54135E+04 42 carnegieite-high 10.09 5.85 -4.24 -0.606 0.72405E+04 43 carpholite-Mg 8.58 4.31 -4.28 -0.285 0.73005E+04 45 celadonite 5.34 3.61 -1.73 -0.102 0.29555E+04 46 celadonite-Fe 3.88 0.82 -3.06 -0.180 0.52230E+04 47 chrysotile 23.89 21.41 -2.48 -0.207 0.42371E+04 49 clinochlore 39.07 38.05 -1.02 -0.032 0.17381E+04 50 daphnite 28.97 24.09 -4.88 -0.152 0.83311E+04 52 chlorite-Al-free 47.17 42.82 -4.35 -0.181 0.74293E+04 54 chloritoid-Fe 9.17 4.63 -4.54 -0.303 0.77552E+04 55 chloritoid-Mn 11.40 7.44 -3.96 -0.264 0.67592E+04 57 coesite -2.38 -3.12 -0.74 -0.247 0.12674E+04 64 cristobalite -2.56 -3.12 -0.56 -0.186 0.95276E+03 66 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71239E+04 68 diaspore 2.87 0.66 -2.21 -0.368 0.37736E+04 70 diopside 16.18 15.75 -0.43 -0.043 0.73192E+03 71 hedenbergite 14.21 12.96 -1.25 -0.125 0.21321E+04 76 clinoenstatite 17.17 12.20 -4.97 -0.497 0.84882E+04 78 epidote 24.67 22.51 -2.16 -0.105 0.36813E+04 79 clinozoisite 22.81 18.18 -4.62 -0.210 0.78937E+04 80 epidote-Fe 29.84 26.84 -3.00 -0.156 0.51155E+04 81 fayalite 14.05 9.73 -4.32 -0.617 0.73738E+04 82 ferrosilite 11.15 6.61 -4.54 -0.454 0.77530E+04 86 gibbsite 4.08 0.66 -3.42 -0.488 0.58321E+04 87 glaucophane 22.97 20.64 -2.33 -0.063 0.39812E+04 89 graphite -3.55 -8.24 -4.69 -1.340 0.80109E+04 90 greenalite 16.14 13.03 -3.11 -0.259 0.53067E+04 93 hematite 12.57 9.99 -2.58 -0.312 0.44002E+04 94 heulandite -5.83 -7.73 -1.90 -0.086 0.32446E+04 98 jadeite 4.22 2.73 -1.48 -0.148 0.25285E+04 100 kalsilite 7.58 3.75 -3.83 -0.548 0.65466E+04 101 kaolinite -1.33 -4.91 -3.58 -0.325 0.61069E+04 104 laumontite 2.88 1.63 -1.26 -0.084 0.21445E+04 105 lawsonite 9.62 7.86 -1.75 -0.117 0.29914E+04 106 leucite 4.12 0.63 -3.49 -0.349 0.59546E+04 108 lizardite 23.24 21.41 -1.83 -0.153 0.31297E+04 110 magnetite 20.09 16.41 -3.68 -0.300 0.62758E+04 111 minnesotaite 10.39 6.79 -3.59 -0.211 0.61353E+04 115 manganosite 14.06 9.23 -4.82 -1.206 0.82379E+04 119 microcline -2.49 -2.49 0.00 0.000 0.55158E+00 123 muscovite 2.58 -1.16 -3.74 -0.220 0.63893E+04 124 paragonite 4.24 0.94 -3.30 -0.194 0.56278E+04 125 nepheline 8.34 5.85 -2.49 -0.355 0.42459E+04 137 phlogopite-Na 29.65 27.26 -2.38 -0.132 0.40690E+04 139 prehnite 19.37 17.52 -1.85 -0.109 0.31632E+04 140 prehnite-Fe 22.50 21.85 -0.65 -0.039 0.11058E+04 141 pumpellyite-Fe 46.27 42.13 -4.14 -0.092 0.70764E+04 142 pumpellyite-Mg 48.99 44.92 -4.08 -0.091 0.69609E+04 145 pyrite -21.25 -24.35 -3.10 -0.729 0.52925E+04 146 pyrrhotite -4.26 -7.53 -3.27 -1.091 0.55892E+04 147 pyrrhotiteFe0.875 -6.02 -8.69 -2.67 -0.983 0.45654E+04 148 pyroxmangite 7.40 6.12 -1.28 -0.257 0.21916E+04 149 pyrophyllite -6.18 -11.15 -4.97 -0.311 0.84865E+04 150 quartz -2.99 -3.12 -0.13 -0.043 0.22009E+03 154 rhodochrosite -0.98 -4.72 -3.74 -1.247 0.63872E+04 155 rhodonite 7.45 6.12 -1.33 -0.266 0.22718E+04 156 sanidine -1.28 -2.49 -1.21 -0.093 0.20683E+04 158 siderite -2.61 -7.53 -4.92 -1.640 0.84001E+04 166 stilbite -7.52 -7.73 -0.21 -0.010 0.35080E+03 167 stilpnomelane-Fe 13.02 11.60 -1.42 -0.042 0.24251E+04 168 stilpnomelane-Mg 27.44 25.56 -1.88 -0.056 0.32087E+04 174 talc 16.49 15.17 -1.32 -0.077 0.22485E+04 177 tephroite 18.09 15.35 -2.74 -0.391 0.46736E+04 181 tridymite -2.63 -3.12 -0.49 -0.164 0.84006E+03 182 tremolite 47.87 46.68 -1.19 -0.032 0.20312E+04 184 troilite-low -4.41 -7.53 -3.12 -1.041 0.53320E+04 190 wairakite 3.95 1.63 -2.32 -0.137 0.39664E+04 191 walstromite 11.51 9.66 -1.85 -0.371 0.31657E+04 192 wollastonite 10.46 9.66 -0.81 -0.161 0.13762E+04 193 pseudo-wollastonite 11.00 9.66 -1.34 -0.269 0.22960E+04 194 zoisite 22.85 18.18 -4.67 -0.212 0.79678E+04 195 akaganeite 7.75 4.99 -2.76 -0.597 0.47126E+04 202 chalcedony -2.80 -3.12 -0.32 -0.105 0.53938E+03 204 montmorillonite-Ca -2.29 -6.22 -3.93 -0.243 0.67026E+04 205 montmorillonite-K -2.24 -6.28 -4.04 -0.247 0.68975E+04 206 montmorillonite-Mg -2.48 -6.80 -4.32 -0.267 0.73819E+04 207 montmorillonite-Na -2.04 -5.58 -3.54 -0.217 0.60522E+04 208 nontronite-Ca 3.21 0.87 -2.34 -0.152 0.40007E+04 209 nontronite-H 2.53 -1.24 -3.77 -0.253 0.64351E+04 210 nontronite-K 3.34 0.81 -2.53 -0.162 0.43188E+04 211 nontronite-Mg 3.07 0.28 -2.79 -0.181 0.47641E+04 212 nontronite-Na 3.52 1.51 -2.01 -0.129 0.34394E+04 228 tobermorite 9.82 7.52 -2.30 -0.628 0.39290E+04 234 alabandite -0.98 -4.72 -3.75 -1.248 0.63947E+04 237 boehmite 4.41 0.66 -3.74 -0.624 0.63905E+04 239 ferrous-oxide 9.81 6.42 -3.39 -0.847 0.57863E+04 245 silica-amorphous -2.09 -3.12 -1.03 -0.342 0.17536E+04 247 an20ab80 2.02 1.27 -0.75 -0.058 0.12841E+04 248 an25ab75 2.65 1.68 -0.97 -0.074 0.16521E+04 249 an30ab70 3.28 2.09 -1.19 -0.091 0.20297E+04 250 tr.625ac.25prg.125 45.16 44.10 -1.06 -0.029 0.18126E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 0.0002000 MOLES Current total amount of reactant added: 0.0053900 MOLES New total amount of reactant added: 0.0055900 MOLES Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.5508E-08 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 7 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 0.0055900 Water: Moles liquid = 0.4985E+02 kg liquid = 0.8982E+00 Moles total = 0.4985E+02 kg total = 0.8981E+00 Activity = 1.0000 Stoichiometric ionic strength = .1168744E-01 Osmotic coef. = 0.9542 True ionic strength = .2034485E-01 Chg. balance for total moles = -.5508E-08 Max. difference allowed = 0.1709E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.97684E-10 -10.0102 0.81997E-10 -10.0862 0.83942E+00 -0.0760 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.18937E-03 -3.7227 0.15799E-03 -3.8014 0.83430E+00 -0.0787 4 SO4-- 0.13086E-04 -4.8832 0.67671E-05 -5.1696 0.51712E+00 -0.2864 5 HCO3- 0.17045E-03 -3.7684 0.14241E-03 -3.8464 0.83554E+00 -0.0780 6 HS- 0.16650E-03 -3.7786 0.13893E-03 -3.8572 0.83443E+00 -0.0786 7 Al+++ 0.11034E-28 -28.9573 0.25246E-29 -29.5978 0.22881E+00 -0.6405 8 H4SiO4 0.76411E-03 -3.1168 0.76411E-03 -3.1168 0.10000E+01 0.0000 9 Ca++ 0.76430E-07 -7.1167 0.39230E-07 -7.4064 0.51328E+00 -0.2896 10 Mg++ 0.21487E-10 -10.6678 0.10978E-10 -10.9595 0.51090E+00 -0.2917 11 Fe++ 0.35314E-13 -13.4521 0.18062E-13 -13.7432 0.51147E+00 -0.2912 12 K+ 0.15655E-03 -3.8054 0.13083E-03 -3.8833 0.83574E+00 -0.0779 13 Na+ 0.19881E-01 -1.7016 0.16584E-01 -1.7803 0.83415E+00 -0.0788 14 Mn++ 0.22474E-10 -10.6483 0.11504E-10 -10.9391 0.51189E+00 -0.2908 15 F- 0.25925E-05 -5.5863 0.21584E-05 -5.6659 0.83256E+00 -0.0796 16 HPO4-- 0.45401E-07 -7.3429 0.23481E-07 -7.6293 0.51720E+00 -0.2863 18 HSiO3- 0.10429E-01 -1.9817 0.87012E-02 -2.0604 0.83430E+00 -0.0787 19 Ca(HSiO3)+ 0.92996E-08 -8.0315 0.77737E-08 -8.1094 0.83592E+00 -0.0778 20 Mg(HSiO3)+ 0.32386E-11 -11.4896 0.27072E-11 -11.5675 0.83592E+00 -0.0778 21 NaHSiO3,aq 0.23338E-02 -2.6319 0.23338E-02 -2.6319 0.10000E+01 0.0000 22 AlO+ 0.61109E-16 -16.2139 0.51082E-16 -16.2917 0.83592E+00 -0.0778 24 HAlO2,aq 0.12406E-09 -9.9064 0.12406E-09 -9.9064 0.10000E+01 0.0000 25 AlO2- 0.40217E-05 -5.3956 0.33492E-05 -5.4751 0.83278E+00 -0.0795 26 CH4,aq 0.28503E-08 -8.5451 0.28401E-08 -8.5467 0.99644E+00 -0.0015 31 CO,aq 0.16896E-15 -15.7722 0.16896E-15 -15.7722 0.10000E+01 0.0000 32 CO2,aq 0.25041E-07 -7.6013 0.24952E-07 -7.6029 0.99644E+00 -0.0015 33 CO3-2 0.29399E-03 -3.5317 0.15170E-03 -3.8190 0.51601E+00 -0.2873 34 CaCO3,aq 0.74622E-07 -7.1271 0.74622E-07 -7.1271 0.10000E+01 0.0000 35 Ca(HCO3)+ 0.17060E-09 -9.7680 0.14261E-09 -9.8458 0.83592E+00 -0.0778 36 CaCl+ 0.11999E-10 -10.9208 0.10030E-10 -10.9987 0.83592E+00 -0.0778 37 CaCl2,aq 0.37650E-15 -15.4242 0.37650E-15 -15.4242 0.10000E+01 0.0000 38 CaF+ 0.14789E-11 -11.8301 0.12363E-11 -11.9079 0.83592E+00 -0.0778 39 CaOH+ 0.40790E-07 -7.3894 0.34097E-07 -7.4673 0.83592E+00 -0.0778 40 CaSO4,aq 0.84300E-10 -10.0742 0.84300E-10 -10.0742 0.10000E+01 0.0000 41 HCl,aq 0.23740E-14 -14.6245 0.23740E-14 -14.6245 0.10000E+01 0.0000 45 HF,aq 0.12116E-11 -11.9166 0.12116E-11 -11.9166 0.10000E+01 0.0000 46 HF2- 0.10583E-17 -17.9754 0.88294E-18 -18.0541 0.83430E+00 -0.0787 48 FeCl+ 0.54035E-17 -17.2673 0.45169E-17 -17.3452 0.83592E+00 -0.0778 51 FeF+ 0.23833E-17 -17.6228 0.19922E-17 -17.7007 0.83592E+00 -0.0778 53 FeO,aq 0.10441E-09 -9.9813 0.10441E-09 -9.9813 0.10000E+01 0.0000 54 FeOH+ 0.85775E-11 -11.0666 0.71701E-11 -11.1445 0.83592E+00 -0.0778 55 HFeO2- 0.15968E-07 -7.7967 0.13323E-07 -7.8754 0.83430E+00 -0.0787 56 FeO+ 0.39407E-16 -16.4044 0.32941E-16 -16.4823 0.83592E+00 -0.0778 58 FeO2- 0.12016E-08 -8.9202 0.10025E-08 -8.9989 0.83430E+00 -0.0787 59 HFeO2,aq 0.10455E-10 -10.9807 0.10455E-10 -10.9807 0.10000E+01 0.0000 60 H2,aq 0.27051E-06 -6.5678 0.26955E-06 -6.5694 0.99644E+00 -0.0015 61 KCl,aq 0.37464E-09 -9.4264 0.37464E-09 -9.4264 0.10000E+01 0.0000 62 KHSO4,aq 0.20526E-18 -18.6877 0.20526E-18 -18.6877 0.10000E+01 0.0000 63 KOH,aq 0.68140E-06 -6.1666 0.68140E-06 -6.1666 0.10000E+01 0.0000 64 KSO4- 0.16467E-07 -7.7834 0.13739E-07 -7.8621 0.83430E+00 -0.0787 65 MgCO3,aq 0.52341E-11 -11.2812 0.52341E-11 -11.2812 0.10000E+01 0.0000 66 Mg(HCO3)+ 0.48781E-13 -13.3118 0.40777E-13 -13.3896 0.83592E+00 -0.0778 67 MgCl+ 0.30432E-14 -14.5167 0.25439E-14 -14.5945 0.83592E+00 -0.0778 68 MgF+ 0.15330E-14 -14.8145 0.12815E-14 -14.8923 0.83592E+00 -0.0778 69 MgOH+ 0.63160E-10 -10.1996 0.52797E-10 -10.2774 0.83592E+00 -0.0778 71 MnF+ 0.50035E-15 -15.3007 0.41826E-15 -15.3786 0.83592E+00 -0.0778 72 MnO,aq 0.17720E-08 -8.7515 0.17720E-08 -8.7515 0.10000E+01 0.0000 73 MnOH+ 0.50754E-09 -9.2945 0.42426E-09 -9.3724 0.83592E+00 -0.0778 74 MnO2-2 0.16950E-10 -10.7708 0.87464E-11 -11.0582 0.51601E+00 -0.2873 75 HMnO2- 0.18833E-09 -9.7251 0.15712E-09 -9.8038 0.83430E+00 -0.0787 78 MnCl+ 0.13390E-13 -13.8732 0.11193E-13 -13.9511 0.83592E+00 -0.0778 79 MnSO4,aq 0.22475E-13 -13.6483 0.22475E-13 -13.6483 0.10000E+01 0.0000 80 NaCl,aq 0.86831E-06 -6.0613 0.86831E-06 -6.0613 0.10000E+01 0.0000 81 NaF,aq 0.83802E-08 -8.0767 0.83802E-08 -8.0767 0.10000E+01 0.0000 82 NaOH,aq 0.86895E-04 -4.0610 0.86895E-04 -4.0610 0.10000E+01 0.0000 84 OH- 0.84611E-02 -2.0726 0.70462E-02 -2.1520 0.83278E+00 -0.0795 89 HPO3-2 0.38225E-16 -16.4177 0.19724E-16 -16.7050 0.51601E+00 -0.2873 92 H3PO4,aq 0.11042E-17 -17.9570 0.11042E-17 -17.9570 0.10000E+01 0.0000 93 H2PO4- 0.42532E-10 -10.3713 0.35519E-10 -10.4495 0.83510E+00 -0.0783 94 PO4-3 0.97164E-09 -9.0125 0.23365E-09 -9.6314 0.24046E+00 -0.6189 98 HP2O7-3 0.10517E-17 -17.9781 0.24089E-18 -18.6182 0.22904E+00 -0.6401 99 P2O7-4 0.92563E-17 -17.0336 0.70181E-18 -18.1538 0.75820E-01 -1.1202 100 H2S,aq 0.35334E-07 -7.4518 0.35208E-07 -7.4534 0.99644E+00 -0.0015 101 S2-2 0.30750E-11 -11.5122 0.15867E-11 -11.7995 0.51601E+00 -0.2873 102 S3-2 0.54114E-18 -18.2667 0.27923E-18 -18.5540 0.51601E+00 -0.2873 107 SO3-2 0.45273E-12 -12.3442 0.23703E-12 -12.6252 0.52357E+00 -0.2810 108 HSO3- 0.14586E-14 -14.8361 0.12169E-14 -14.9147 0.83430E+00 -0.0787 109 HSO4- 0.63909E-12 -12.1944 0.53476E-12 -12.2718 0.83675E+00 -0.0774 111 S2O3-2 0.54239E-14 -14.2657 0.27988E-14 -14.5530 0.51601E+00 -0.2873 Charge balance for all species = -.6132E-08 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.9768401E-10 -.2162210E-01 -.2175546E+02 0.0000 2 H2O 0.1000000E+01 0.5550404E+02 0.9981639E+06 0.0000 3 Cl- 0.1893724E-03 0.1902411E-03 0.6732761E+01 6.2848 4 SO4-- 0.1308617E-04 0.1303240E-04 0.1249712E+01 15.0028 5 HCO3- 0.1704450E-03 0.4645401E-03 0.2829510E+02 6.2398 6 HS- 0.1664994E-03 0.1666050E-03 0.5500274E+01 6.2290 7 Al+++ 0.1103376E-28 0.4021820E-05 0.1083240E+00 0.6608 8 H4SiO4 0.7641066E-03 0.1352725E-01 0.1297891E+04 -3.1168 9 Ca++ 0.7643007E-07 0.2014103E-06 0.8057931E-02 12.7660 10 Mg++ 0.2148676E-10 0.9317288E-10 0.2261236E-05 9.2129 11 Fe++ 0.3531392E-13 0.1729353E-07 0.9640936E-03 6.4292 12 K+ 0.1565464E-03 0.1572447E-03 0.6137771E+01 6.2029 13 Na+ 0.1988089E-01 0.2230248E-01 0.5118281E+03 8.3059 14 Mn++ 0.2247433E-10 0.2507307E-08 0.1375042E-03 9.2333 15 F- 0.2592517E-05 0.2600900E-05 0.4932503E-01 4.4203 16 HPO4-- 0.4540142E-07 0.4641559E-07 0.4447089E-02 12.5431 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.1942464E-01 -.1941990E-01 -.4737904E-05 0.0000000E+00 2 H2O 0.4985099E+02 0.4985099E+02 -.4656880E-05 0.0000000E+00 3 Cl- 0.1708652E-03 0.1708652E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.1170719E-04 0.1170506E-04 0.2132510E-08 0.0000000E+00 5 HCO3- 0.4172270E-03 0.4172270E-03 0.0000000E+00 0.0000000E+00 6 HS- 0.1496343E-03 0.1496364E-03 -.2132510E-08 0.0000000E+00 7 Al+++ 0.4775352E-05 0.3612200E-05 0.1163152E-05 0.0000000E+00 8 H4SiO4 0.1215302E-01 0.1214951E-01 0.3513449E-05 0.0000000E+00 9 Ca++ 0.2080835E-06 0.1808968E-06 0.2718668E-07 0.0000000E+00 10 Mg++ 0.8368328E-10 0.8368328E-10 0.0000000E+00 0.0000000E+00 11 Fe++ 0.3259227E-07 0.1553219E-07 0.1706008E-07 0.0000000E+00 12 K+ 0.1412294E-03 0.1412294E-03 0.0000000E+00 0.0000000E+00 13 Na+ 0.2003215E-01 0.2003099E-01 0.1162087E-05 0.0000000E+00 14 Mn++ 0.2251939E-08 0.2251939E-08 0.0000000E+00 0.0000000E+00 15 F- 0.2336000E-05 0.2336000E-05 0.0000000E+00 0.0000000E+00 16 HPO4-- 0.4168819E-07 0.4168819E-07 0.0000000E+00 0.0000000E+00 Chg. balance for solid moles: -.6353E-21 Mass of aqueous solution: 0.899732E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 0.0055900 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 0.1162E-05 -5.935 0.3047E-03 -3.516 98.52 0.1170E-03 andradite 0.8530E-08 -8.069 0.4335E-05 -5.363 1.401 0.1126E-05 grossular 0.5322E-09 -9.274 0.2397E-06 -6.620 0.7751E-01 0.6670E-07 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.9413E+00 0.9413E+00 1.0000 -0.026 grossular 0.5873E-01 0.5873E-01 1.0000 -1.231 Solid products produced: Mass = 0.000309 g Volume = 0.000118 cm3 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.0055900 moles log = -2.2526 Original solution: 1000.0103000 g Original solution / Rock added: 178892.72 (Water/Rock Ratio), log = 5.2526 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0207 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9996E+00 0.9859 0.1006E+01 0.1020E+01 CO2,gas 0.2597E-05 1.0071 0.2670E-05 0.2651E-05 CH4,gas 0.4045E-05 1.0125 0.4180E-05 0.4129E-05 H2,gas 0.3465E-03 1.0005 0.3539E-03 0.3537E-03 H2S,gas 0.9520E-06 0.9960 0.9679E-06 0.9717E-06 S2,gas 0.2751E-24 1.0000 0.2808E-24 0.2808E-24 CO,gas 0.2467E-12 1.0000 0.2518E-12 0.2518E-12 SO3,gas 0.1686E-40 1.0000 0.1720E-40 0.1720E-40 SO2,gas 0.2321E-21 1.0000 0.2369E-21 0.2369E-21 HF,gas 0.2915E-14 1.0000 0.2975E-14 0.2975E-14 HCl,gas 0.4104E-17 1.0000 0.4189E-17 0.4189E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 17 albite -0.38 -0.38 0.00 0.000 -0.13080E-10 23 andradite 39.01 39.01 0.00 0.000 -0.12132E-10 24 grossular 32.73 32.73 0.00 0.000 -0.12132E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -13.93 -7.27 -2.424 0.12418E+05 -5.574 3 CH4,gas 4.54 -2.53 -7.08 -1.769 0.12085E+05 -5.379 4 H2,gas 8.00 2.85 -5.15 -2.943 0.87937E+04 -3.451 5 H2S,gas -6.23 -13.94 -7.71 -3.857 0.13170E+05 -6.014 6 S2,gas -7.34 -33.59 -26.25 -4.039 0.44822E+05 -24.552 7 CO,gas 3.21 -11.08 -14.30 -4.399 0.24413E+05 -12.599 8 SO3,gas 17.12 -25.34 -42.46 -10.616 0.72505E+05 -40.764 9 SO2,gas 0.83 -22.49 -23.32 -6.220 0.39826E+05 -21.626 10 HF,gas 0.47 -15.75 -16.23 -8.113 0.27705E+05 -14.527 11 HCl,gas 5.19 -13.89 -19.08 -9.538 0.32573E+05 -17.378 12 acmite 7.71 7.08 -0.63 -0.066 0.10812E+04 16 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 20 spessartine 24.46 19.67 -4.79 -0.239 0.81728E+04 21 analcite 3.32 2.73 -0.59 -0.065 0.10055E+04 27 annite 20.12 16.80 -3.32 -0.185 0.56735E+04 28 phlogopite 27.06 25.15 -1.91 -0.106 0.32659E+04 30 anorthite 12.71 7.85 -4.86 -0.374 0.82922E+04 33 apatite-OH -18.15 -19.57 -1.42 -0.109 0.24271E+04 34 apatite-F -34.30 -35.33 -1.03 -0.086 0.17519E+04 38 aragonite 0.97 -1.17 -2.13 -0.711 0.36423E+04 39 brucite 12.57 9.21 -3.36 -0.671 0.57297E+04 40 calcite 0.81 -1.17 -1.98 -0.659 0.33781E+04 41 carnegieite-low 9.02 5.85 -3.17 -0.453 0.54186E+04 42 carnegieite-high 10.09 5.85 -4.24 -0.606 0.72456E+04 43 carpholite-Mg 8.58 4.30 -4.28 -0.285 0.73102E+04 45 celadonite 5.34 3.61 -1.73 -0.102 0.29580E+04 46 celadonite-Fe 3.88 0.83 -3.05 -0.179 0.52096E+04 47 chrysotile 23.89 21.41 -2.49 -0.207 0.42471E+04 49 clinochlore 39.07 38.04 -1.03 -0.032 0.17654E+04 50 daphnite 28.97 24.12 -4.85 -0.152 0.82785E+04 52 chlorite-Al-free 47.17 42.81 -4.36 -0.182 0.74494E+04 54 chloritoid-Fe 9.17 4.63 -4.54 -0.303 0.77515E+04 55 chloritoid-Mn 11.40 7.44 -3.96 -0.264 0.67668E+04 57 coesite -2.38 -3.12 -0.74 -0.247 0.12649E+04 64 cristobalite -2.56 -3.12 -0.56 -0.186 0.95022E+03 66 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71240E+04 68 diaspore 2.87 0.66 -2.21 -0.369 0.37785E+04 70 diopside 16.18 15.75 -0.44 -0.044 0.74468E+03 71 hedenbergite 14.21 12.96 -1.25 -0.125 0.21289E+04 76 clinoenstatite 17.17 12.19 -4.97 -0.497 0.84932E+04 78 epidote 24.67 22.51 -2.16 -0.105 0.36924E+04 79 clinozoisite 22.81 18.16 -4.64 -0.211 0.79264E+04 80 epidote-Fe 29.84 26.85 -2.99 -0.155 0.51051E+04 81 fayalite 14.05 9.74 -4.30 -0.615 0.73494E+04 82 ferrosilite 11.15 6.62 -4.52 -0.452 0.77260E+04 86 gibbsite 4.08 0.66 -3.42 -0.488 0.58370E+04 87 glaucophane 22.97 20.64 -2.34 -0.063 0.39912E+04 88 glaucophane-Fe 17.28 12.29 -4.99 -0.135 0.85199E+04 89 graphite -3.55 -8.23 -4.69 -1.339 0.80032E+04 90 greenalite 16.14 13.05 -3.09 -0.257 0.52688E+04 93 hematite 12.57 10.01 -2.56 -0.310 0.43669E+04 94 heulandite -5.83 -7.73 -1.90 -0.087 0.32495E+04 98 jadeite 4.22 2.73 -1.48 -0.148 0.25310E+04 100 kalsilite 7.58 3.75 -3.84 -0.548 0.65517E+04 101 kaolinite -1.33 -4.91 -3.58 -0.325 0.61116E+04 104 laumontite 2.88 1.62 -1.26 -0.084 0.21569E+04 105 lawsonite 9.62 7.85 -1.76 -0.117 0.30089E+04 106 leucite 4.12 0.63 -3.49 -0.349 0.59571E+04 108 lizardite 23.24 21.41 -1.84 -0.153 0.31397E+04 110 magnetite 20.09 16.44 -3.65 -0.298 0.62315E+04 111 minnesotaite 10.39 6.82 -3.57 -0.210 0.60923E+04 115 manganosite 14.06 9.23 -4.82 -1.206 0.82383E+04 119 microcline -2.49 -2.49 0.00 0.000 0.57675E+00 123 muscovite 2.58 -1.17 -3.75 -0.220 0.63991E+04 124 paragonite 4.24 0.94 -3.30 -0.194 0.56376E+04 125 nepheline 8.34 5.85 -2.49 -0.356 0.42510E+04 137 phlogopite-Na 29.65 27.25 -2.39 -0.133 0.40841E+04 139 prehnite 19.37 17.50 -1.87 -0.110 0.31909E+04 140 prehnite-Fe 22.50 21.85 -0.65 -0.039 0.11120E+04 141 pumpellyite-Fe 46.27 42.10 -4.17 -0.093 0.71258E+04 142 pumpellyite-Mg 48.99 44.88 -4.12 -0.091 0.70263E+04 145 pyrite -21.25 -24.31 -3.06 -0.720 0.52255E+04 146 pyrrhotite -4.26 -7.51 -3.25 -1.085 0.55560E+04 147 pyrrhotiteFe0.875 -6.02 -8.67 -2.65 -0.976 0.45321E+04 148 pyroxmangite 7.40 6.12 -1.28 -0.256 0.21894E+04 149 pyrophyllite -6.18 -11.15 -4.97 -0.311 0.84861E+04 150 quartz -2.99 -3.12 -0.13 -0.042 0.21755E+03 154 rhodochrosite -0.98 -4.70 -3.72 -1.241 0.63570E+04 155 rhodonite 7.45 6.12 -1.33 -0.266 0.22697E+04 156 sanidine -1.28 -2.49 -1.21 -0.093 0.20683E+04 158 siderite -2.61 -7.50 -4.90 -1.632 0.83587E+04 166 stilbite -7.52 -7.73 -0.21 -0.010 0.35562E+03 167 stilpnomelane-Fe 13.02 11.63 -1.38 -0.041 0.23612E+04 168 stilpnomelane-Mg 27.44 25.55 -1.89 -0.056 0.32247E+04 174 talc 16.49 15.17 -1.32 -0.078 0.22534E+04 177 tephroite 18.09 15.35 -2.74 -0.391 0.46718E+04 181 tridymite -2.63 -3.12 -0.49 -0.164 0.83753E+03 182 tremolite 47.87 46.66 -1.21 -0.033 0.20617E+04 184 troilite-low -4.41 -7.51 -3.10 -1.034 0.52988E+04 190 wairakite 3.95 1.62 -2.33 -0.137 0.39788E+04 191 walstromite 11.51 9.65 -1.86 -0.372 0.31760E+04 192 wollastonite 10.46 9.65 -0.81 -0.162 0.13864E+04 193 pseudo-wollastonite 11.00 9.65 -1.35 -0.270 0.23063E+04 194 zoisite 22.85 18.16 -4.69 -0.213 0.80004E+04 195 akaganeite 7.75 5.00 -2.75 -0.595 0.46960E+04 202 chalcedony -2.80 -3.12 -0.31 -0.105 0.53685E+03 204 montmorillonite-Ca -2.29 -6.22 -3.93 -0.243 0.67044E+04 205 montmorillonite-K -2.24 -6.28 -4.04 -0.247 0.68981E+04 206 montmorillonite-Mg -2.48 -6.80 -4.32 -0.267 0.73824E+04 207 montmorillonite-Na -2.04 -5.58 -3.54 -0.217 0.60528E+04 208 nontronite-Ca 3.21 0.89 -2.32 -0.151 0.39617E+04 209 nontronite-H 2.53 -1.21 -3.74 -0.251 0.63941E+04 210 nontronite-K 3.34 0.83 -2.51 -0.161 0.42786E+04 211 nontronite-Mg 3.07 0.31 -2.77 -0.179 0.47239E+04 212 nontronite-Na 3.52 1.53 -1.99 -0.128 0.33993E+04 228 tobermorite 9.82 7.52 -2.31 -0.629 0.39371E+04 234 alabandite -0.98 -4.71 -3.73 -1.244 0.63727E+04 237 boehmite 4.41 0.66 -3.75 -0.624 0.63954E+04 239 ferrous-oxide 9.81 6.43 -3.38 -0.846 0.57754E+04 245 silica-amorphous -2.09 -3.12 -1.03 -0.342 0.17510E+04 247 an20ab80 2.02 1.26 -0.75 -0.058 0.12876E+04 248 an25ab75 2.65 1.68 -0.97 -0.075 0.16565E+04 249 an30ab70 3.28 2.09 -1.19 -0.092 0.20349E+04 250 tr.625ac.25prg.125 45.16 44.10 -1.07 -0.029 0.18253E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 0.0002000 MOLES Current total amount of reactant added: 0.0055900 MOLES New total amount of reactant added: 0.0057900 MOLES Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.5508E-08 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 7 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 0.0057900 Water: Moles liquid = 0.4985E+02 kg liquid = 0.8982E+00 Moles total = 0.4985E+02 kg total = 0.8981E+00 Activity = 1.0000 Stoichiometric ionic strength = .1170025E-01 Osmotic coef. = 0.9537 True ionic strength = .2035647E-01 Chg. balance for total moles = -.5508E-08 Max. difference allowed = 0.1720E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.98047E-10 -10.0086 0.82300E-10 -10.0846 0.83939E+00 -0.0760 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.19068E-03 -3.7197 0.15908E-03 -3.7984 0.83427E+00 -0.0787 4 SO4-- 0.14147E-04 -4.8493 0.73147E-05 -5.1358 0.51704E+00 -0.2865 5 HCO3- 0.17675E-03 -3.7526 0.14768E-03 -3.8307 0.83551E+00 -0.0780 6 HS- 0.17085E-03 -3.7674 0.14255E-03 -3.8460 0.83440E+00 -0.0786 7 Al+++ 0.11087E-28 -28.9552 0.25358E-29 -29.5959 0.22873E+00 -0.6407 8 H4SiO4 0.76673E-03 -3.1154 0.76673E-03 -3.1154 0.10000E+01 0.0000 9 Ca++ 0.75704E-07 -7.1209 0.38851E-07 -7.4106 0.51320E+00 -0.2897 10 Mg++ 0.21502E-10 -10.6675 0.10984E-10 -10.9593 0.51082E+00 -0.2917 11 Fe++ 0.36122E-13 -13.4422 0.18473E-13 -13.7335 0.51139E+00 -0.2913 12 K+ 0.15655E-03 -3.8054 0.13083E-03 -3.8833 0.83571E+00 -0.0779 13 Na+ 0.19882E-01 -1.7015 0.16584E-01 -1.7803 0.83412E+00 -0.0788 14 Mn++ 0.22632E-10 -10.6453 0.11584E-10 -10.9362 0.51182E+00 -0.2909 15 F- 0.26813E-05 -5.5717 0.22323E-05 -5.6513 0.83253E+00 -0.0796 16 HPO4-- 0.45404E-07 -7.3429 0.23479E-07 -7.6293 0.51712E+00 -0.2864 18 HSiO3- 0.10427E-01 -1.9818 0.86990E-02 -2.0605 0.83427E+00 -0.0787 19 Ca(HSiO3)+ 0.92079E-08 -8.0358 0.76968E-08 -8.1137 0.83589E+00 -0.0779 20 Mg(HSiO3)+ 0.32397E-11 -11.4895 0.27080E-11 -11.5673 0.83589E+00 -0.0779 21 NaHSiO3,aq 0.23332E-02 -2.6320 0.23332E-02 -2.6320 0.10000E+01 0.0000 22 AlO+ 0.60932E-16 -16.2152 0.50933E-16 -16.2930 0.83589E+00 -0.0779 24 HAlO2,aq 0.12325E-09 -9.9092 0.12325E-09 -9.9092 0.10000E+01 0.0000 25 AlO2- 0.39807E-05 -5.4000 0.33149E-05 -5.4795 0.83275E+00 -0.0795 26 CH4,aq 0.28056E-08 -8.5520 0.27956E-08 -8.5535 0.99643E+00 -0.0016 31 CO,aq 0.17341E-15 -15.7609 0.17341E-15 -15.7609 0.10000E+01 0.0000 32 CO2,aq 0.26062E-07 -7.5840 0.25970E-07 -7.5855 0.99643E+00 -0.0016 33 CO3-2 0.30378E-03 -3.5174 0.15673E-03 -3.8048 0.51593E+00 -0.2874 34 CaCO3,aq 0.76352E-07 -7.1172 0.76352E-07 -7.1172 0.10000E+01 0.0000 35 Ca(HCO3)+ 0.17521E-09 -9.7565 0.14645E-09 -9.8343 0.83589E+00 -0.0779 36 CaCl+ 0.11965E-10 -10.9221 0.10002E-10 -10.9999 0.83589E+00 -0.0779 37 CaCl2,aq 0.37801E-15 -15.4225 0.37801E-15 -15.4225 0.10000E+01 0.0000 38 CaF+ 0.15148E-11 -11.8196 0.12662E-11 -11.8975 0.83589E+00 -0.0779 39 CaOH+ 0.40250E-07 -7.3952 0.33644E-07 -7.4731 0.83589E+00 -0.0779 40 CaSO4,aq 0.90242E-10 -10.0446 0.90242E-10 -10.0446 0.10000E+01 0.0000 41 HCl,aq 0.23991E-14 -14.6200 0.23991E-14 -14.6200 0.10000E+01 0.0000 45 HF,aq 0.12577E-11 -11.9004 0.12577E-11 -11.9004 0.10000E+01 0.0000 46 HF2- 0.11361E-17 -17.9446 0.94785E-18 -18.0233 0.83427E+00 -0.0787 48 FeCl+ 0.55645E-17 -17.2546 0.46513E-17 -17.3324 0.83589E+00 -0.0779 51 FeF+ 0.25209E-17 -17.5984 0.21072E-17 -17.6763 0.83589E+00 -0.0779 53 FeO,aq 0.10600E-09 -9.9747 0.10600E-09 -9.9747 0.10000E+01 0.0000 54 FeOH+ 0.87407E-11 -11.0585 0.73062E-11 -11.1363 0.83589E+00 -0.0779 55 HFeO2- 0.16153E-07 -7.7917 0.13476E-07 -7.8704 0.83427E+00 -0.0787 56 FeO+ 0.40437E-16 -16.3932 0.33801E-16 -16.4711 0.83589E+00 -0.0779 58 FeO2- 0.12240E-08 -8.9122 0.10211E-08 -8.9909 0.83427E+00 -0.0787 59 HFeO2,aq 0.10689E-10 -10.9711 0.10689E-10 -10.9711 0.10000E+01 0.0000 60 H2,aq 0.26677E-06 -6.5739 0.26581E-06 -6.5754 0.99643E+00 -0.0016 61 KCl,aq 0.37720E-09 -9.4234 0.37720E-09 -9.4234 0.10000E+01 0.0000 62 KHSO4,aq 0.22268E-18 -18.6523 0.22268E-18 -18.6523 0.10000E+01 0.0000 63 KOH,aq 0.67887E-06 -6.1682 0.67887E-06 -6.1682 0.10000E+01 0.0000 64 KSO4- 0.17800E-07 -7.7496 0.14850E-07 -7.8283 0.83427E+00 -0.0787 65 MgCO3,aq 0.54105E-11 -11.2668 0.54105E-11 -11.2668 0.10000E+01 0.0000 66 Mg(HCO3)+ 0.50613E-13 -13.2957 0.42307E-13 -13.3736 0.83589E+00 -0.0779 67 MgCl+ 0.30659E-14 -14.5134 0.25628E-14 -14.5913 0.83589E+00 -0.0779 68 MgF+ 0.15864E-14 -14.7996 0.13260E-14 -14.8774 0.83589E+00 -0.0779 69 MgOH+ 0.62965E-10 -10.2009 0.52632E-10 -10.2787 0.83589E+00 -0.0779 71 MnF+ 0.52104E-15 -15.2831 0.43553E-15 -15.3610 0.83589E+00 -0.0779 72 MnO,aq 0.17711E-08 -8.7518 0.17711E-08 -8.7518 0.10000E+01 0.0000 73 MnOH+ 0.50917E-09 -9.2931 0.42561E-09 -9.3710 0.83589E+00 -0.0779 74 MnO2-2 0.16820E-10 -10.7742 0.86779E-11 -11.0616 0.51593E+00 -0.2874 75 HMnO2- 0.18755E-09 -9.7269 0.15647E-09 -9.8056 0.83427E+00 -0.0787 78 MnCl+ 0.13575E-13 -13.8673 0.11347E-13 -13.9451 0.83589E+00 -0.0779 79 MnSO4,aq 0.24461E-13 -13.6115 0.24461E-13 -13.6115 0.10000E+01 0.0000 80 NaCl,aq 0.87427E-06 -6.0584 0.87427E-06 -6.0584 0.10000E+01 0.0000 81 NaF,aq 0.86668E-08 -8.0621 0.86668E-08 -8.0621 0.10000E+01 0.0000 82 NaOH,aq 0.86576E-04 -4.0626 0.86576E-04 -4.0626 0.10000E+01 0.0000 84 OH- 0.84304E-02 -2.0742 0.70204E-02 -2.1536 0.83275E+00 -0.0795 89 HPO3-2 0.37698E-16 -16.4237 0.19450E-16 -16.7111 0.51593E+00 -0.2874 92 H3PO4,aq 0.11123E-17 -17.9538 0.11123E-17 -17.9538 0.10000E+01 0.0000 93 H2PO4- 0.42687E-10 -10.3697 0.35647E-10 -10.4480 0.83507E+00 -0.0783 94 PO4-3 0.96831E-09 -9.0140 0.23277E-09 -9.6331 0.24039E+00 -0.6191 98 HP2O7-3 0.10558E-17 -17.9764 0.24173E-18 -18.6167 0.22896E+00 -0.6402 99 P2O7-4 0.92603E-17 -17.0334 0.70170E-18 -18.1538 0.75775E-01 -1.1205 100 H2S,aq 0.36389E-07 -7.4390 0.36259E-07 -7.4406 0.99643E+00 -0.0016 101 S2-2 0.32833E-11 -11.4837 0.16940E-11 -11.7711 0.51593E+00 -0.2874 102 S3-2 0.60341E-18 -18.2194 0.31132E-18 -18.5068 0.51593E+00 -0.2874 107 SO3-2 0.48266E-12 -12.3164 0.25267E-12 -12.5975 0.52349E+00 -0.2811 108 HSO3- 0.15606E-14 -14.8067 0.13020E-14 -14.8854 0.83427E+00 -0.0787 109 HSO4- 0.69337E-12 -12.1590 0.58015E-12 -12.2365 0.83672E+00 -0.0774 111 S2O3-2 0.60387E-14 -14.2191 0.31156E-14 -14.5065 0.51593E+00 -0.2874 Charge balance for all species = -.6132E-08 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.9804732E-10 -.2159787E-01 -.2173107E+02 0.0000 2 H2O 0.1000000E+01 0.5550402E+02 0.9981627E+06 0.0000 3 Cl- 0.1906796E-03 0.1915542E-03 0.6779227E+01 6.2862 4 SO4-- 0.1414712E-04 0.1409567E-04 0.1351671E+01 15.0334 5 HCO3- 0.1767499E-03 0.4806381E-03 0.2927560E+02 6.2539 6 HS- 0.1708464E-03 0.1709522E-03 0.5643786E+01 6.2386 7 Al+++ 0.1108652E-28 0.3980838E-05 0.1072201E+00 0.6579 8 H4SiO4 0.7667295E-03 0.1352707E-01 0.1297873E+04 -3.1154 9 Ca++ 0.7570411E-07 0.2017924E-06 0.8073209E-02 12.7586 10 Mg++ 0.2150189E-10 0.9317253E-10 0.2261226E-05 9.2099 11 Fe++ 0.3612249E-13 0.1750246E-07 0.9757403E-03 6.4357 12 K+ 0.1565470E-03 0.1572441E-03 0.6137743E+01 6.2013 13 Na+ 0.1988166E-01 0.2230236E-01 0.5118249E+03 8.3043 14 Mn++ 0.2263230E-10 0.2507297E-08 0.1375036E-03 9.2330 15 F- 0.2681292E-05 0.2689962E-05 0.5101401E-01 4.4333 16 HPO4-- 0.4540442E-07 0.4641541E-07 0.4447069E-02 12.5399 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.1940310E-01 -.1939822E-01 -.4884084E-05 0.0000000E+00 2 H2O 0.4985115E+02 0.4985115E+02 -.4804130E-05 0.0000000E+00 3 Cl- 0.1720452E-03 0.1720452E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.1266219E-04 0.1266008E-04 0.2109046E-08 0.0000000E+00 5 HCO3- 0.4316870E-03 0.4316870E-03 0.0000000E+00 0.0000000E+00 6 HS- 0.1535393E-03 0.1535414E-03 -.2109046E-08 0.0000000E+00 7 Al+++ 0.4775352E-05 0.3575406E-05 0.1199946E-05 0.0000000E+00 8 H4SiO4 0.1215302E-01 0.1214940E-01 0.3623614E-05 0.0000000E+00 9 Ca++ 0.2080835E-06 0.1812406E-06 0.2684288E-07 0.0000000E+00 10 Mg++ 0.8368328E-10 0.8368328E-10 0.0000000E+00 0.0000000E+00 11 Fe++ 0.3259227E-07 0.1571990E-07 0.1687237E-07 0.0000000E+00 12 K+ 0.1412294E-03 0.1412294E-03 0.0000000E+00 0.0000000E+00 13 Na+ 0.2003215E-01 0.2003095E-01 0.1198924E-05 0.0000000E+00 14 Mn++ 0.2251939E-08 0.2251939E-08 0.0000000E+00 0.0000000E+00 15 F- 0.2416000E-05 0.2416000E-05 0.0000000E+00 0.0000000E+00 16 HPO4-- 0.4168819E-07 0.4168819E-07 0.0000000E+00 0.0000000E+00 Chg. balance for solid moles: 0.4235E-21 Mass of aqueous solution: 0.899737E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 0.0057900 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 0.1199E-05 -5.921 0.3144E-03 -3.503 98.58 0.1207E-03 andradite 0.8436E-08 -8.074 0.4287E-05 -5.368 1.344 0.1114E-05 grossular 0.5114E-09 -9.291 0.2304E-06 -6.638 0.7224E-01 0.6410E-07 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.9428E+00 0.9428E+00 1.0000 -0.026 grossular 0.5716E-01 0.5716E-01 1.0000 -1.243 Solid products produced: Mass = 0.000319 g Volume = 0.000122 cm3 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.0057900 moles log = -2.2373 Original solution: 1000.0103000 g Original solution / Rock added: 172713.35 (Water/Rock Ratio), log = 5.2373 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0207 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9997E+00 0.9859 0.1006E+01 0.1020E+01 CO2,gas 0.2703E-05 1.0071 0.2778E-05 0.2759E-05 CH4,gas 0.3982E-05 1.0125 0.4115E-05 0.4064E-05 H2,gas 0.3417E-03 1.0005 0.3490E-03 0.3488E-03 H2S,gas 0.9805E-06 0.9960 0.9967E-06 0.1001E-05 S2,gas 0.3000E-24 1.0000 0.3062E-24 0.3062E-24 CO,gas 0.2532E-12 1.0000 0.2584E-12 0.2584E-12 SO3,gas 0.1835E-40 1.0000 0.1873E-40 0.1873E-40 SO2,gas 0.2492E-21 1.0000 0.2543E-21 0.2543E-21 HF,gas 0.3025E-14 1.0000 0.3088E-14 0.3088E-14 HCl,gas 0.4148E-17 1.0000 0.4233E-17 0.4233E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 17 albite -0.38 -0.38 0.00 0.000 -0.94784E-12 23 andradite 39.01 39.01 0.00 0.000 0.12132E-10 24 grossular 32.73 32.73 0.00 0.000 0.00000E+00 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -13.92 -7.26 -2.418 0.12388E+05 -5.556 3 CH4,gas 4.54 -2.54 -7.08 -1.771 0.12097E+05 -5.386 4 H2,gas 8.00 2.84 -5.16 -2.946 0.88040E+04 -3.457 5 H2S,gas -6.23 -13.93 -7.70 -3.850 0.13148E+05 -6.001 6 S2,gas -7.34 -33.55 -26.21 -4.033 0.44758E+05 -24.514 7 CO,gas 3.21 -11.07 -14.29 -4.396 0.24394E+05 -12.588 8 SO3,gas 17.12 -25.31 -42.43 -10.607 0.72442E+05 -40.727 9 SO2,gas 0.83 -22.46 -23.29 -6.212 0.39773E+05 -21.595 10 HF,gas 0.47 -15.74 -16.21 -8.105 0.27677E+05 -14.510 11 HCl,gas 5.19 -13.88 -19.07 -9.536 0.32565E+05 -17.373 12 acmite 7.71 7.09 -0.62 -0.065 0.10624E+04 16 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 20 spessartine 24.46 19.67 -4.79 -0.239 0.81761E+04 21 analcite 3.32 2.73 -0.59 -0.066 0.10080E+04 27 annite 20.12 16.82 -3.30 -0.184 0.56399E+04 28 phlogopite 27.06 25.14 -1.92 -0.107 0.32811E+04 30 anorthite 12.71 7.84 -4.87 -0.374 0.83095E+04 33 apatite-OH -18.15 -19.60 -1.45 -0.111 0.24741E+04 34 apatite-F -34.30 -35.34 -1.04 -0.086 0.17713E+04 38 aragonite 0.97 -1.16 -2.12 -0.708 0.36253E+04 39 brucite 12.57 9.21 -3.36 -0.672 0.57347E+04 40 calcite 0.81 -1.16 -1.97 -0.656 0.33611E+04 41 carnegieite-low 9.02 5.85 -3.18 -0.454 0.54237E+04 42 carnegieite-high 10.09 5.85 -4.25 -0.607 0.72507E+04 43 carpholite-Mg 8.58 4.30 -4.29 -0.286 0.73200E+04 45 celadonite 5.34 3.61 -1.73 -0.102 0.29605E+04 46 celadonite-Fe 3.88 0.83 -3.04 -0.179 0.51958E+04 47 chrysotile 23.89 21.40 -2.49 -0.208 0.42572E+04 49 clinochlore 39.07 38.02 -1.05 -0.033 0.17928E+04 50 daphnite 28.97 24.15 -4.82 -0.151 0.82246E+04 52 chlorite-Al-free 47.17 42.80 -4.37 -0.182 0.74695E+04 54 chloritoid-Fe 9.17 4.64 -4.54 -0.302 0.77475E+04 55 chloritoid-Mn 11.40 7.43 -3.97 -0.265 0.67745E+04 57 coesite -2.38 -3.12 -0.74 -0.246 0.12623E+04 64 cristobalite -2.56 -3.12 -0.56 -0.185 0.94768E+03 66 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71240E+04 68 diaspore 2.87 0.66 -2.22 -0.369 0.37834E+04 70 diopside 16.18 15.74 -0.44 -0.044 0.75729E+03 71 hedenbergite 14.21 12.96 -1.24 -0.124 0.21252E+04 76 clinoenstatite 17.17 12.19 -4.98 -0.498 0.84983E+04 78 epidote 24.67 22.50 -2.17 -0.105 0.37035E+04 79 clinozoisite 22.81 18.14 -4.66 -0.212 0.79587E+04 80 epidote-Fe 29.84 26.86 -2.98 -0.155 0.50949E+04 81 fayalite 14.05 9.76 -4.29 -0.613 0.73244E+04 82 ferrosilite 11.15 6.64 -4.51 -0.451 0.76985E+04 86 gibbsite 4.08 0.66 -3.42 -0.489 0.58419E+04 87 glaucophane 22.97 20.63 -2.34 -0.063 0.40013E+04 88 glaucophane-Fe 17.28 12.31 -4.97 -0.134 0.84811E+04 89 graphite -3.55 -8.23 -4.68 -1.338 0.79943E+04 90 greenalite 16.14 13.08 -3.06 -0.255 0.52300E+04 93 hematite 12.57 10.03 -2.54 -0.308 0.43341E+04 94 heulandite -5.83 -7.73 -1.91 -0.087 0.32541E+04 98 jadeite 4.22 2.73 -1.48 -0.148 0.25335E+04 100 kalsilite 7.58 3.74 -3.84 -0.549 0.65568E+04 101 kaolinite -1.33 -4.91 -3.58 -0.326 0.61163E+04 104 laumontite 2.88 1.61 -1.27 -0.085 0.21692E+04 105 lawsonite 9.62 7.84 -1.77 -0.118 0.30262E+04 106 leucite 4.12 0.63 -3.49 -0.349 0.59597E+04 108 lizardite 23.24 21.40 -1.84 -0.154 0.31498E+04 110 magnetite 20.09 16.46 -3.62 -0.296 0.61875E+04 111 minnesotaite 10.39 6.85 -3.54 -0.208 0.60484E+04 115 manganosite 14.06 9.23 -4.83 -1.206 0.82387E+04 119 microcline -2.49 -2.49 0.00 0.000 0.60201E+00 123 muscovite 2.58 -1.17 -3.75 -0.221 0.64089E+04 124 paragonite 4.24 0.93 -3.31 -0.195 0.56474E+04 125 nepheline 8.34 5.85 -2.49 -0.356 0.42561E+04 137 phlogopite-Na 29.65 27.25 -2.40 -0.133 0.40993E+04 139 prehnite 19.37 17.49 -1.88 -0.111 0.32184E+04 140 prehnite-Fe 22.50 21.84 -0.65 -0.039 0.11182E+04 141 pumpellyite-Fe 46.27 42.07 -4.20 -0.093 0.71744E+04 142 pumpellyite-Mg 48.99 44.84 -4.15 -0.092 0.70912E+04 145 pyrite -21.25 -24.27 -3.02 -0.711 0.51603E+04 146 pyrrhotite -4.26 -7.49 -3.23 -1.078 0.55229E+04 147 pyrrhotiteFe0.875 -6.02 -8.65 -2.64 -0.969 0.44992E+04 148 pyroxmangite 7.40 6.12 -1.28 -0.256 0.21873E+04 149 pyrophyllite -6.18 -11.15 -4.97 -0.311 0.84858E+04 150 quartz -2.99 -3.12 -0.13 -0.042 0.21501E+03 154 rhodochrosite -0.98 -4.68 -3.71 -1.235 0.63278E+04 155 rhodonite 7.45 6.12 -1.33 -0.266 0.22675E+04 156 sanidine -1.28 -2.49 -1.21 -0.093 0.20684E+04 158 siderite -2.61 -7.48 -4.87 -1.624 0.83178E+04 166 stilbite -7.52 -7.73 -0.21 -0.010 0.36027E+03 167 stilpnomelane-Fe 13.02 11.67 -1.34 -0.040 0.22960E+04 168 stilpnomelane-Mg 27.44 25.54 -1.90 -0.057 0.32408E+04 174 talc 16.49 15.17 -1.32 -0.078 0.22584E+04 177 tephroite 18.09 15.35 -2.74 -0.391 0.46700E+04 181 tridymite -2.63 -3.12 -0.49 -0.163 0.83499E+03 182 tremolite 47.87 46.64 -1.23 -0.033 0.20919E+04 184 troilite-low -4.41 -7.49 -3.08 -1.028 0.52657E+04 190 wairakite 3.95 1.61 -2.34 -0.137 0.39911E+04 191 walstromite 11.51 9.64 -1.87 -0.373 0.31861E+04 192 wollastonite 10.46 9.64 -0.82 -0.164 0.13965E+04 193 pseudo-wollastonite 11.00 9.64 -1.36 -0.271 0.23164E+04 194 zoisite 22.85 18.14 -4.70 -0.214 0.80328E+04 195 akaganeite 7.75 5.01 -2.74 -0.593 0.46796E+04 202 chalcedony -2.80 -3.12 -0.31 -0.104 0.53431E+03 204 montmorillonite-Ca -2.29 -6.22 -3.93 -0.243 0.67061E+04 205 montmorillonite-K -2.24 -6.28 -4.04 -0.247 0.68986E+04 206 montmorillonite-Mg -2.48 -6.80 -4.32 -0.267 0.73829E+04 207 montmorillonite-Na -2.04 -5.58 -3.55 -0.217 0.60533E+04 208 nontronite-Ca 3.21 0.92 -2.30 -0.149 0.39233E+04 209 nontronite-H 2.53 -1.19 -3.72 -0.249 0.63536E+04 210 nontronite-K 3.34 0.86 -2.48 -0.159 0.42391E+04 211 nontronite-Mg 3.07 0.33 -2.74 -0.178 0.46842E+04 212 nontronite-Na 3.52 1.55 -1.97 -0.126 0.33597E+04 228 tobermorite 9.82 7.51 -2.31 -0.630 0.39451E+04 234 alabandite -0.98 -4.70 -3.72 -1.240 0.63513E+04 237 boehmite 4.41 0.66 -3.75 -0.625 0.64003E+04 239 ferrous-oxide 9.81 6.44 -3.38 -0.844 0.57642E+04 245 silica-amorphous -2.09 -3.12 -1.02 -0.341 0.17485E+04 247 an20ab80 2.02 1.26 -0.76 -0.058 0.12911E+04 248 an25ab75 2.65 1.67 -0.97 -0.075 0.16608E+04 249 an30ab70 3.28 2.08 -1.19 -0.092 0.20401E+04 250 tr.625ac.25prg.125 45.16 44.09 -1.08 -0.029 0.18373E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 0.0002000 MOLES Current total amount of reactant added: 0.0057900 MOLES New total amount of reactant added: 0.0059900 MOLES Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.5508E-08 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 7 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 0.0059900 Water: Moles liquid = 0.4986E+02 kg liquid = 0.8982E+00 Moles total = 0.4985E+02 kg total = 0.8981E+00 Activity = 1.0000 Stoichiometric ionic strength = .1171306E-01 Osmotic coef. = 0.9533 True ionic strength = .2036806E-01 Chg. balance for total moles = -.5508E-08 Max. difference allowed = 0.1732E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.98413E-10 -10.0069 0.82603E-10 -10.0830 0.83936E+00 -0.0761 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.19199E-03 -3.7167 0.16016E-03 -3.7954 0.83424E+00 -0.0787 4 SO4-- 0.15208E-04 -4.8179 0.78621E-05 -5.1045 0.51697E+00 -0.2865 5 HCO3- 0.18308E-03 -3.7374 0.15296E-03 -3.8154 0.83548E+00 -0.0781 6 HS- 0.17519E-03 -3.7565 0.14618E-03 -3.8351 0.83436E+00 -0.0786 7 Al+++ 0.11140E-28 -28.9531 0.25471E-29 -29.5940 0.22865E+00 -0.6408 8 H4SiO4 0.76937E-03 -3.1139 0.76937E-03 -3.1139 0.10000E+01 0.0000 9 Ca++ 0.75000E-07 -7.1249 0.38484E-07 -7.4147 0.51312E+00 -0.2898 10 Mg++ 0.21517E-10 -10.6672 0.10990E-10 -10.9590 0.51074E+00 -0.2918 11 Fe++ 0.36960E-13 -13.4323 0.18898E-13 -13.7236 0.51131E+00 -0.2913 12 K+ 0.15655E-03 -3.8054 0.13082E-03 -3.8833 0.83568E+00 -0.0780 13 Na+ 0.19882E-01 -1.7015 0.16584E-01 -1.7803 0.83409E+00 -0.0788 14 Mn++ 0.22792E-10 -10.6422 0.11663E-10 -10.9332 0.51174E+00 -0.2910 15 F- 0.27701E-05 -5.5575 0.23061E-05 -5.6371 0.83250E+00 -0.0796 16 HPO4-- 0.45407E-07 -7.3429 0.23478E-07 -7.6293 0.51704E+00 -0.2865 18 HSiO3- 0.10425E-01 -1.9819 0.86969E-02 -2.0606 0.83424E+00 -0.0787 19 Ca(HSiO3)+ 0.91189E-08 -8.0401 0.76222E-08 -8.1179 0.83586E+00 -0.0779 20 Mg(HSiO3)+ 0.32408E-11 -11.4894 0.27088E-11 -11.5672 0.83586E+00 -0.0779 21 NaHSiO3,aq 0.23327E-02 -2.6321 0.23327E-02 -2.6321 0.10000E+01 0.0000 22 AlO+ 0.60756E-16 -16.2164 0.50784E-16 -16.2943 0.83586E+00 -0.0779 24 HAlO2,aq 0.12243E-09 -9.9121 0.12243E-09 -9.9121 0.10000E+01 0.0000 25 AlO2- 0.39401E-05 -5.4045 0.32809E-05 -5.4840 0.83271E+00 -0.0795 26 CH4,aq 0.27724E-08 -8.5571 0.27625E-08 -8.5587 0.99643E+00 -0.0016 31 CO,aq 0.17801E-15 -15.7496 0.17801E-15 -15.7496 0.10000E+01 0.0000 32 CO2,aq 0.27095E-07 -7.5671 0.26998E-07 -7.5687 0.99643E+00 -0.0016 33 CO3-2 0.31354E-03 -3.5037 0.16174E-03 -3.7912 0.51586E+00 -0.2875 34 CaCO3,aq 0.78049E-07 -7.1076 0.78049E-07 -7.1076 0.10000E+01 0.0000 35 Ca(HCO3)+ 0.17977E-09 -9.7453 0.15026E-09 -9.8232 0.83586E+00 -0.0779 36 CaCl+ 0.11934E-10 -10.9232 0.99748E-11 -11.0011 0.83586E+00 -0.0779 37 CaCl2,aq 0.37956E-15 -15.4207 0.37956E-15 -15.4207 0.10000E+01 0.0000 38 CaF+ 0.15502E-11 -11.8096 0.12957E-11 -11.8875 0.83586E+00 -0.0779 39 CaOH+ 0.39724E-07 -7.4009 0.33204E-07 -7.4788 0.83586E+00 -0.0779 40 CaSO4,aq 0.96079E-10 -10.0174 0.96079E-10 -10.0174 0.10000E+01 0.0000 41 HCl,aq 0.24243E-14 -14.6154 0.24243E-14 -14.6154 0.10000E+01 0.0000 45 HF,aq 0.13040E-11 -11.8847 0.13040E-11 -11.8847 0.10000E+01 0.0000 46 HF2- 0.12170E-17 -17.9147 0.10153E-17 -17.9934 0.83424E+00 -0.0787 48 FeCl+ 0.57317E-17 -17.2417 0.47909E-17 -17.3196 0.83586E+00 -0.0779 51 FeF+ 0.26643E-17 -17.5744 0.22270E-17 -17.6523 0.83586E+00 -0.0779 53 FeO,aq 0.10764E-09 -9.9680 0.10764E-09 -9.9680 0.10000E+01 0.0000 54 FeOH+ 0.89094E-11 -11.0502 0.74470E-11 -11.1280 0.83586E+00 -0.0779 55 HFeO2- 0.16344E-07 -7.7866 0.13635E-07 -7.8654 0.83424E+00 -0.0787 56 FeO+ 0.41480E-16 -16.3822 0.34672E-16 -16.4600 0.83586E+00 -0.0779 58 FeO2- 0.12463E-08 -8.9044 0.10397E-08 -8.9831 0.83424E+00 -0.0787 59 HFeO2,aq 0.10923E-10 -10.9616 0.10923E-10 -10.9616 0.10000E+01 0.0000 60 H2,aq 0.26340E-06 -6.5794 0.26246E-06 -6.5809 0.99643E+00 -0.0016 61 KCl,aq 0.37976E-09 -9.4205 0.37976E-09 -9.4205 0.10000E+01 0.0000 62 KHSO4,aq 0.24022E-18 -18.6194 0.24022E-18 -18.6194 0.10000E+01 0.0000 63 KOH,aq 0.67635E-06 -6.1698 0.67635E-06 -6.1698 0.10000E+01 0.0000 64 KSO4- 0.19132E-07 -7.7182 0.15961E-07 -7.7970 0.83424E+00 -0.0787 65 MgCO3,aq 0.55866E-11 -11.2529 0.55866E-11 -11.2529 0.10000E+01 0.0000 66 Mg(HCO3)+ 0.52455E-13 -13.2802 0.43845E-13 -13.3581 0.83586E+00 -0.0779 67 MgCl+ 0.30886E-14 -14.5102 0.25817E-14 -14.5881 0.83586E+00 -0.0779 68 MgF+ 0.16398E-14 -14.7852 0.13706E-14 -14.8631 0.83586E+00 -0.0779 69 MgOH+ 0.62771E-10 -10.2022 0.52467E-10 -10.2801 0.83586E+00 -0.0779 71 MnF+ 0.54200E-15 -15.2660 0.45303E-15 -15.3439 0.83586E+00 -0.0779 72 MnO,aq 0.17702E-08 -8.7520 0.17702E-08 -8.7520 0.10000E+01 0.0000 73 MnOH+ 0.51081E-09 -9.2917 0.42696E-09 -9.3696 0.83586E+00 -0.0779 74 MnO2-2 0.16690E-10 -10.7775 0.86098E-11 -11.0650 0.51586E+00 -0.2875 75 HMnO2- 0.18677E-09 -9.7287 0.15581E-09 -9.8074 0.83424E+00 -0.0787 78 MnCl+ 0.13762E-13 -13.8613 0.11503E-13 -13.9392 0.83586E+00 -0.0779 79 MnSO4,aq 0.26473E-13 -13.5772 0.26473E-13 -13.5772 0.10000E+01 0.0000 80 NaCl,aq 0.88023E-06 -6.0554 0.88023E-06 -6.0554 0.10000E+01 0.0000 81 NaF,aq 0.89534E-08 -8.0480 0.89534E-08 -8.0480 0.10000E+01 0.0000 82 NaOH,aq 0.86257E-04 -4.0642 0.86257E-04 -4.0642 0.10000E+01 0.0000 84 OH- 0.83997E-02 -2.0757 0.69946E-02 -2.1552 0.83271E+00 -0.0795 89 HPO3-2 0.37225E-16 -16.4292 0.19203E-16 -16.7166 0.51586E+00 -0.2875 92 H3PO4,aq 0.11204E-17 -17.9506 0.11204E-17 -17.9506 0.10000E+01 0.0000 93 H2PO4- 0.42842E-10 -10.3681 0.35775E-10 -10.4464 0.83504E+00 -0.0783 94 PO4-3 0.96497E-09 -9.0155 0.23189E-09 -9.6347 0.24031E+00 -0.6192 98 HP2O7-3 0.10599E-17 -17.9747 0.24259E-18 -18.6151 0.22888E+00 -0.6404 99 P2O7-4 0.92643E-17 -17.0332 0.70158E-18 -18.1539 0.75730E-01 -1.1207 100 H2S,aq 0.37452E-07 -7.4265 0.37318E-07 -7.4281 0.99643E+00 -0.0016 101 S2-2 0.34969E-11 -11.4563 0.18039E-11 -11.7438 0.51586E+00 -0.2875 102 S3-2 0.66986E-18 -18.1740 0.34555E-18 -18.4615 0.51586E+00 -0.2875 107 SO3-2 0.51231E-12 -12.2905 0.26815E-12 -12.5716 0.52342E+00 -0.2812 108 HSO3- 0.16624E-14 -14.7793 0.13869E-14 -14.8580 0.83424E+00 -0.0787 109 HSO4- 0.74804E-12 -12.1261 0.62587E-12 -12.2035 0.83669E+00 -0.0774 111 S2O3-2 0.66811E-14 -14.1752 0.34465E-14 -14.4626 0.51586E+00 -0.2875 Charge balance for all species = -.6132E-08 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.9841278E-10 -.2157365E-01 -.2170668E+02 0.0000 2 H2O 0.1000000E+01 0.5550399E+02 0.9981614E+06 0.0000 3 Cl- 0.1919867E-03 0.1928673E-03 0.6825692E+01 6.2876 4 SO4-- 0.1520817E-04 0.1515893E-04 0.1453629E+01 15.0615 5 HCO3- 0.1830828E-03 0.4967359E-03 0.3025610E+02 6.2676 6 HS- 0.1751934E-03 0.1752993E-03 0.5787296E+01 6.2479 7 Al+++ 0.1113964E-28 0.3940187E-05 0.1061251E+00 0.6550 8 H4SiO4 0.7693670E-03 0.1352690E-01 0.1297856E+04 -3.1139 9 Ca++ 0.7500017E-07 0.2021816E-06 0.8088774E-02 12.7513 10 Mg++ 0.2151708E-10 0.9317218E-10 0.2261216E-05 9.2070 11 Fe++ 0.3696016E-13 0.1771782E-07 0.9877459E-03 6.4424 12 K+ 0.1565476E-03 0.1572435E-03 0.6137715E+01 6.1997 13 Na+ 0.1988243E-01 0.2230223E-01 0.5118216E+03 8.3027 14 Mn++ 0.2279162E-10 0.2507288E-08 0.1375030E-03 9.2328 15 F- 0.2770067E-05 0.2779023E-05 0.5270297E-01 4.4459 16 HPO4-- 0.4540742E-07 0.4641524E-07 0.4447049E-02 12.5367 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.1938157E-01 -.1937654E-01 -.5029050E-05 0.0000000E+00 2 H2O 0.4985131E+02 0.4985132E+02 -.4950183E-05 0.0000000E+00 3 Cl- 0.1732252E-03 0.1732252E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.1361719E-04 0.1361511E-04 0.2084860E-08 0.0000000E+00 5 HCO3- 0.4461470E-03 0.4461470E-03 0.0000000E+00 0.0000000E+00 6 HS- 0.1574443E-03 0.1574464E-03 -.2084860E-08 0.0000000E+00 7 Al+++ 0.4775352E-05 0.3538908E-05 0.1236444E-05 0.0000000E+00 8 H4SiO4 0.1215302E-01 0.1214929E-01 0.3732875E-05 0.0000000E+00 9 Ca++ 0.2080835E-06 0.1815909E-06 0.2649263E-07 0.0000000E+00 10 Mg++ 0.8368328E-10 0.8368328E-10 0.0000000E+00 0.0000000E+00 11 Fe++ 0.3259227E-07 0.1591339E-07 0.1667888E-07 0.0000000E+00 12 K+ 0.1412294E-03 0.1412294E-03 0.0000000E+00 0.0000000E+00 13 Na+ 0.2003215E-01 0.2003091E-01 0.1235461E-05 0.0000000E+00 14 Mn++ 0.2251939E-08 0.2251939E-08 0.0000000E+00 0.0000000E+00 15 F- 0.2496000E-05 0.2496000E-05 0.0000000E+00 0.0000000E+00 16 HPO4-- 0.4168819E-07 0.4168819E-07 0.0000000E+00 0.0000000E+00 Chg. balance for solid moles: 0.4235E-21 Mass of aqueous solution: 0.899741E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 0.0059900 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 0.1235E-05 -5.908 0.3240E-03 -3.490 98.64 0.1244E-03 andradite 0.8339E-08 -8.079 0.4238E-05 -5.373 1.290 0.1101E-05 grossular 0.4914E-09 -9.309 0.2214E-06 -6.655 0.6740E-01 0.6159E-07 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.9444E+00 0.9444E+00 1.0000 -0.025 grossular 0.5565E-01 0.5565E-01 1.0000 -1.255 Solid products produced: Mass = 0.000328 g Volume = 0.000126 cm3 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.0059900 moles log = -2.2226 Original solution: 1000.0103000 g Original solution / Rock added: 166946.63 (Water/Rock Ratio), log = 5.2226 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0207 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9997E+00 0.9859 0.1006E+01 0.1020E+01 CO2,gas 0.2810E-05 1.0071 0.2889E-05 0.2868E-05 CH4,gas 0.3935E-05 1.0125 0.4066E-05 0.4016E-05 H2,gas 0.3374E-03 1.0005 0.3446E-03 0.3444E-03 H2S,gas 0.1009E-05 0.9960 0.1026E-05 0.1030E-05 S2,gas 0.3259E-24 1.0000 0.3327E-24 0.3327E-24 CO,gas 0.2599E-12 1.0000 0.2653E-12 0.2653E-12 SO3,gas 0.1987E-40 1.0000 0.2028E-40 0.2028E-40 SO2,gas 0.2664E-21 1.0000 0.2719E-21 0.2719E-21 HF,gas 0.3137E-14 1.0000 0.3202E-14 0.3202E-14 HCl,gas 0.4191E-17 1.0000 0.4278E-17 0.4278E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 17 albite -0.38 -0.38 0.00 0.000 -0.94784E-12 23 andradite 39.01 39.01 0.00 0.000 0.24265E-10 24 grossular 32.73 32.73 0.00 0.000 -0.60662E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -13.90 -7.24 -2.413 0.12359E+05 -5.539 3 CH4,gas 4.54 -2.55 -7.09 -1.772 0.12106E+05 -5.391 4 H2,gas 8.00 2.84 -5.16 -2.950 0.88134E+04 -3.463 5 H2S,gas -6.23 -13.92 -7.69 -3.844 0.13127E+05 -5.989 6 S2,gas -7.34 -33.51 -26.18 -4.027 0.44696E+05 -24.478 7 CO,gas 3.21 -11.06 -14.28 -4.392 0.24375E+05 -12.576 8 SO3,gas 17.12 -25.27 -42.39 -10.598 0.72383E+05 -40.693 9 SO2,gas 0.83 -22.43 -23.26 -6.204 0.39724E+05 -21.566 10 HF,gas 0.47 -15.72 -16.19 -8.097 0.27650E+05 -14.495 11 HCl,gas 5.19 -13.88 -19.07 -9.534 0.32558E+05 -17.369 12 acmite 7.71 7.10 -0.61 -0.064 0.10439E+04 16 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 20 spessartine 24.46 19.67 -4.79 -0.240 0.81794E+04 21 analcite 3.32 2.73 -0.59 -0.066 0.10106E+04 27 annite 20.12 16.84 -3.28 -0.182 0.56056E+04 28 phlogopite 27.06 25.13 -1.93 -0.107 0.32963E+04 30 anorthite 12.71 7.83 -4.88 -0.375 0.83268E+04 33 apatite-OH -18.15 -19.63 -1.48 -0.114 0.25205E+04 34 apatite-F -34.30 -35.35 -1.05 -0.087 0.17907E+04 38 aragonite 0.97 -1.15 -2.11 -0.705 0.36090E+04 39 brucite 12.57 9.21 -3.36 -0.672 0.57398E+04 40 calcite 0.81 -1.15 -1.96 -0.653 0.33448E+04 41 carnegieite-low 9.02 5.84 -3.18 -0.454 0.54288E+04 42 carnegieite-high 10.09 5.84 -4.25 -0.607 0.72558E+04 43 carpholite-Mg 8.58 4.29 -4.29 -0.286 0.73297E+04 45 celadonite 5.34 3.61 -1.74 -0.102 0.29631E+04 46 celadonite-Fe 3.88 0.84 -3.03 -0.179 0.51819E+04 47 chrysotile 23.89 21.39 -2.50 -0.208 0.42672E+04 49 clinochlore 39.07 38.00 -1.07 -0.033 0.18203E+04 50 daphnite 28.97 24.18 -4.78 -0.150 0.81696E+04 52 chlorite-Al-free 47.17 42.79 -4.39 -0.183 0.74897E+04 54 chloritoid-Fe 9.17 4.64 -4.53 -0.302 0.77433E+04 55 chloritoid-Mn 11.40 7.43 -3.97 -0.265 0.67821E+04 57 coesite -2.38 -3.11 -0.74 -0.246 0.12598E+04 64 cristobalite -2.56 -3.11 -0.55 -0.185 0.94513E+03 66 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71240E+04 68 diaspore 2.87 0.66 -2.22 -0.370 0.37883E+04 70 diopside 16.18 15.73 -0.45 -0.045 0.76976E+03 71 hedenbergite 14.21 12.97 -1.24 -0.124 0.21212E+04 76 clinoenstatite 17.17 12.19 -4.98 -0.498 0.85033E+04 78 epidote 24.67 22.49 -2.18 -0.105 0.37145E+04 79 clinozoisite 22.81 18.13 -4.68 -0.213 0.79908E+04 80 epidote-Fe 29.84 26.86 -2.98 -0.155 0.50849E+04 81 fayalite 14.05 9.77 -4.27 -0.611 0.72990E+04 82 ferrosilite 11.15 6.66 -4.49 -0.449 0.76706E+04 86 gibbsite 4.08 0.66 -3.42 -0.489 0.58468E+04 87 glaucophane 22.97 20.63 -2.35 -0.063 0.40114E+04 88 glaucophane-Fe 17.28 12.33 -4.94 -0.134 0.84418E+04 89 graphite -3.55 -8.22 -4.68 -1.336 0.79843E+04 90 greenalite 16.14 13.10 -3.04 -0.253 0.51907E+04 93 hematite 12.57 10.05 -2.52 -0.305 0.43018E+04 94 heulandite -5.83 -7.74 -1.91 -0.087 0.32586E+04 98 jadeite 4.22 2.73 -1.49 -0.149 0.25361E+04 100 kalsilite 7.58 3.74 -3.84 -0.549 0.65619E+04 101 kaolinite -1.33 -4.92 -3.58 -0.326 0.61211E+04 104 laumontite 2.88 1.61 -1.28 -0.085 0.21813E+04 105 lawsonite 9.62 7.83 -1.78 -0.119 0.30434E+04 106 leucite 4.12 0.63 -3.49 -0.349 0.59623E+04 108 lizardite 23.24 21.39 -1.85 -0.154 0.31599E+04 110 magnetite 20.09 16.49 -3.60 -0.294 0.61439E+04 111 minnesotaite 10.39 6.87 -3.52 -0.207 0.60040E+04 115 manganosite 14.06 9.23 -4.83 -1.206 0.82390E+04 119 microcline -2.49 -2.49 0.00 0.000 0.62735E+00 123 muscovite 2.58 -1.18 -3.76 -0.221 0.64187E+04 124 paragonite 4.24 0.93 -3.31 -0.195 0.56572E+04 125 nepheline 8.34 5.84 -2.50 -0.357 0.42612E+04 137 phlogopite-Na 29.65 27.24 -2.41 -0.134 0.41144E+04 139 prehnite 19.37 17.47 -1.90 -0.112 0.32456E+04 140 prehnite-Fe 22.50 21.84 -0.66 -0.040 0.11243E+04 141 pumpellyite-Fe 46.27 42.04 -4.23 -0.094 0.72223E+04 142 pumpellyite-Mg 48.99 44.80 -4.19 -0.093 0.71555E+04 145 pyrite -21.25 -24.23 -2.98 -0.702 0.50968E+04 146 pyrrhotite -4.26 -7.48 -3.22 -1.072 0.54902E+04 147 pyrrhotiteFe0.875 -6.02 -8.63 -2.62 -0.962 0.44667E+04 148 pyroxmangite 7.40 6.12 -1.28 -0.256 0.21851E+04 149 pyrophyllite -6.18 -11.15 -4.97 -0.311 0.84854E+04 150 quartz -2.99 -3.11 -0.12 -0.041 0.21246E+03 154 rhodochrosite -0.98 -4.67 -3.69 -1.230 0.62993E+04 155 rhodonite 7.45 6.12 -1.33 -0.265 0.22653E+04 156 sanidine -1.28 -2.49 -1.21 -0.093 0.20684E+04 158 siderite -2.61 -7.46 -4.85 -1.616 0.82776E+04 166 stilbite -7.52 -7.74 -0.21 -0.010 0.36477E+03 167 stilpnomelane-Fe 13.02 11.71 -1.31 -0.039 0.22297E+04 168 stilpnomelane-Mg 27.44 25.53 -1.91 -0.057 0.32569E+04 174 talc 16.49 15.17 -1.33 -0.078 0.22634E+04 177 tephroite 18.09 15.35 -2.73 -0.391 0.46682E+04 181 tridymite -2.63 -3.11 -0.49 -0.163 0.83244E+03 182 tremolite 47.87 46.63 -1.24 -0.034 0.21218E+04 184 troilite-low -4.41 -7.48 -3.06 -1.022 0.52330E+04 190 wairakite 3.95 1.61 -2.34 -0.138 0.40032E+04 191 walstromite 11.51 9.64 -1.87 -0.374 0.31961E+04 192 wollastonite 10.46 9.64 -0.82 -0.165 0.14065E+04 193 pseudo-wollastonite 11.00 9.64 -1.36 -0.272 0.23263E+04 194 zoisite 22.85 18.13 -4.72 -0.215 0.80649E+04 195 akaganeite 7.75 5.02 -2.73 -0.591 0.46635E+04 202 chalcedony -2.80 -3.11 -0.31 -0.104 0.53176E+03 204 montmorillonite-Ca -2.29 -6.22 -3.93 -0.243 0.67079E+04 205 montmorillonite-K -2.24 -6.28 -4.04 -0.247 0.68992E+04 206 montmorillonite-Mg -2.48 -6.80 -4.32 -0.268 0.73834E+04 207 montmorillonite-Na -2.04 -5.58 -3.55 -0.217 0.60539E+04 208 nontronite-Ca 3.21 0.94 -2.28 -0.148 0.38854E+04 209 nontronite-H 2.53 -1.16 -3.70 -0.248 0.63137E+04 210 nontronite-K 3.34 0.88 -2.46 -0.158 0.42000E+04 211 nontronite-Mg 3.07 0.35 -2.72 -0.176 0.46451E+04 212 nontronite-Na 3.52 1.57 -1.94 -0.125 0.33207E+04 228 tobermorite 9.82 7.51 -2.32 -0.632 0.39530E+04 234 alabandite -0.98 -4.69 -3.71 -1.236 0.63303E+04 237 boehmite 4.41 0.66 -3.75 -0.625 0.64052E+04 239 ferrous-oxide 9.81 6.44 -3.37 -0.842 0.57528E+04 245 silica-amorphous -2.09 -3.11 -1.02 -0.341 0.17459E+04 247 an20ab80 2.02 1.26 -0.76 -0.058 0.12945E+04 248 an25ab75 2.65 1.67 -0.98 -0.075 0.16651E+04 249 an30ab70 3.28 2.08 -1.20 -0.092 0.20453E+04 250 tr.625ac.25prg.125 45.16 44.08 -1.08 -0.029 0.18488E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 0.0002000 MOLES Current total amount of reactant added: 0.0059900 MOLES New total amount of reactant added: 0.0061900 MOLES Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.5508E-08 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 7 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 0.0061900 Water: Moles liquid = 0.4986E+02 kg liquid = 0.8982E+00 Moles total = 0.4985E+02 kg total = 0.8981E+00 Activity = 1.0000 Stoichiometric ionic strength = .1172588E-01 Osmotic coef. = 0.9529 True ionic strength = .2037963E-01 Chg. balance for total moles = -.5508E-08 Max. difference allowed = 0.1744E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.98780E-10 -10.0053 0.82909E-10 -10.0814 0.83933E+00 -0.0761 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.19329E-03 -3.7138 0.16125E-03 -3.7925 0.83421E+00 -0.0787 4 SO4-- 0.16269E-04 -4.7886 0.84094E-05 -5.0752 0.51689E+00 -0.2866 5 HCO3- 0.18944E-03 -3.7225 0.15827E-03 -3.8006 0.83545E+00 -0.0781 6 HS- 0.17954E-03 -3.7458 0.14980E-03 -3.8245 0.83433E+00 -0.0787 7 Al+++ 0.11193E-28 -28.9510 0.25584E-29 -29.5920 0.22857E+00 -0.6410 8 H4SiO4 0.77202E-03 -3.1124 0.77202E-03 -3.1124 0.10000E+01 0.0000 9 Ca++ 0.74317E-07 -7.1289 0.38128E-07 -7.4188 0.51304E+00 -0.2898 10 Mg++ 0.21532E-10 -10.6669 0.10996E-10 -10.9588 0.51066E+00 -0.2919 11 Fe++ 0.37825E-13 -13.4222 0.19337E-13 -13.7136 0.51123E+00 -0.2914 12 K+ 0.15655E-03 -3.8054 0.13082E-03 -3.8833 0.83565E+00 -0.0780 13 Na+ 0.19883E-01 -1.7015 0.16584E-01 -1.7803 0.83406E+00 -0.0788 14 Mn++ 0.22952E-10 -10.6392 0.11744E-10 -10.9302 0.51166E+00 -0.2910 15 F- 0.28588E-05 -5.5438 0.23799E-05 -5.6234 0.83247E+00 -0.0796 16 HPO4-- 0.45410E-07 -7.3428 0.23476E-07 -7.6294 0.51697E+00 -0.2865 18 HSiO3- 0.10423E-01 -1.9820 0.86947E-02 -2.0607 0.83421E+00 -0.0787 19 Ca(HSiO3)+ 0.90326E-08 -8.0442 0.75497E-08 -8.1221 0.83583E+00 -0.0779 20 Mg(HSiO3)+ 0.32419E-11 -11.4892 0.27096E-11 -11.5671 0.83583E+00 -0.0779 21 NaHSiO3,aq 0.23321E-02 -2.6323 0.23321E-02 -2.6323 0.10000E+01 0.0000 22 AlO+ 0.60580E-16 -16.2177 0.50635E-16 -16.2956 0.83583E+00 -0.0779 24 HAlO2,aq 0.12162E-09 -9.9150 0.12162E-09 -9.9150 0.10000E+01 0.0000 25 AlO2- 0.38997E-05 -5.4090 0.32472E-05 -5.4885 0.83268E+00 -0.0795 26 CH4,aq 0.27484E-08 -8.5609 0.27386E-08 -8.5625 0.99643E+00 -0.0016 31 CO,aq 0.18273E-15 -15.7382 0.18273E-15 -15.7382 0.10000E+01 0.0000 32 CO2,aq 0.28139E-07 -7.5507 0.28039E-07 -7.5522 0.99643E+00 -0.0016 33 CO3-2 0.32328E-03 -3.4904 0.16674E-03 -3.7780 0.51578E+00 -0.2875 34 CaCO3,aq 0.79715E-07 -7.0985 0.79715E-07 -7.0985 0.10000E+01 0.0000 35 Ca(HCO3)+ 0.18429E-09 -9.7345 0.15404E-09 -9.8124 0.83583E+00 -0.0779 36 CaCl+ 0.11904E-10 -10.9243 0.99494E-11 -11.0022 0.83583E+00 -0.0779 37 CaCl2,aq 0.38115E-15 -15.4189 0.38115E-15 -15.4189 0.10000E+01 0.0000 38 CaF+ 0.15850E-11 -11.8000 0.13248E-11 -11.8778 0.83583E+00 -0.0779 39 CaOH+ 0.39212E-07 -7.4066 0.32775E-07 -7.4845 0.83583E+00 -0.0779 40 CaSO4,aq 0.10182E-09 -9.9922 0.10182E-09 -9.9922 0.10000E+01 0.0000 41 HCl,aq 0.24498E-14 -14.6109 0.24498E-14 -14.6109 0.10000E+01 0.0000 45 HF,aq 0.13508E-11 -11.8694 0.13508E-11 -11.8694 0.10000E+01 0.0000 46 HF2- 0.13010E-17 -17.8857 0.10853E-17 -17.9644 0.83421E+00 -0.0787 48 FeCl+ 0.59049E-17 -17.2288 0.49355E-17 -17.3067 0.83583E+00 -0.0779 51 FeF+ 0.28137E-17 -17.5507 0.23517E-17 -17.6286 0.83583E+00 -0.0779 53 FeO,aq 0.10934E-09 -9.9612 0.10934E-09 -9.9612 0.10000E+01 0.0000 54 FeOH+ 0.90833E-11 -11.0418 0.75921E-11 -11.1196 0.83583E+00 -0.0779 55 HFeO2- 0.16540E-07 -7.7815 0.13798E-07 -7.8602 0.83421E+00 -0.0787 56 FeO+ 0.42537E-16 -16.3712 0.35553E-16 -16.4491 0.83583E+00 -0.0779 58 FeO2- 0.12687E-08 -8.8967 0.10583E-08 -8.9754 0.83421E+00 -0.0787 59 HFeO2,aq 0.11160E-10 -10.9523 0.11160E-10 -10.9523 0.10000E+01 0.0000 60 H2,aq 0.26036E-06 -6.5844 0.25943E-06 -6.5860 0.99643E+00 -0.0016 61 KCl,aq 0.38232E-09 -9.4176 0.38232E-09 -9.4176 0.10000E+01 0.0000 62 KHSO4,aq 0.25788E-18 -18.5886 0.25788E-18 -18.5886 0.10000E+01 0.0000 63 KOH,aq 0.67384E-06 -6.1714 0.67384E-06 -6.1714 0.10000E+01 0.0000 64 KSO4- 0.20464E-07 -7.6890 0.17071E-07 -7.7677 0.83421E+00 -0.0787 65 MgCO3,aq 0.57624E-11 -11.2394 0.57624E-11 -11.2394 0.10000E+01 0.0000 66 Mg(HCO3)+ 0.54308E-13 -13.2651 0.45392E-13 -13.3430 0.83583E+00 -0.0779 67 MgCl+ 0.31114E-14 -14.5070 0.26006E-14 -14.5849 0.83583E+00 -0.0779 68 MgF+ 0.16933E-14 -14.7713 0.14153E-14 -14.8492 0.83583E+00 -0.0779 69 MgOH+ 0.62576E-10 -10.2036 0.52303E-10 -10.2815 0.83583E+00 -0.0779 71 MnF+ 0.56322E-15 -15.2493 0.47076E-15 -15.3272 0.83583E+00 -0.0779 72 MnO,aq 0.17693E-08 -8.7522 0.17693E-08 -8.7522 0.10000E+01 0.0000 73 MnOH+ 0.51245E-09 -9.2903 0.42832E-09 -9.3682 0.83583E+00 -0.0779 74 MnO2-2 0.16561E-10 -10.7809 0.85421E-11 -11.0684 0.51578E+00 -0.2875 75 HMnO2- 0.18599E-09 -9.7305 0.15516E-09 -9.8092 0.83421E+00 -0.0787 78 MnCl+ 0.13951E-13 -13.8554 0.11661E-13 -13.9333 0.83583E+00 -0.0779 79 MnSO4,aq 0.28511E-13 -13.5450 0.28511E-13 -13.5450 0.10000E+01 0.0000 80 NaCl,aq 0.88620E-06 -6.0525 0.88620E-06 -6.0525 0.10000E+01 0.0000 81 NaF,aq 0.92400E-08 -8.0343 0.92400E-08 -8.0343 0.10000E+01 0.0000 82 NaOH,aq 0.85939E-04 -4.0658 0.85939E-04 -4.0658 0.10000E+01 0.0000 84 OH- 0.83691E-02 -2.0773 0.69688E-02 -2.1568 0.83268E+00 -0.0795 89 HPO3-2 0.36797E-16 -16.4342 0.18979E-16 -16.7217 0.51578E+00 -0.2875 92 H3PO4,aq 0.11286E-17 -17.9475 0.11286E-17 -17.9475 0.10000E+01 0.0000 93 H2PO4- 0.42999E-10 -10.3665 0.35905E-10 -10.4448 0.83501E+00 -0.0783 94 PO4-3 0.96164E-09 -9.0170 0.23102E-09 -9.6364 0.24023E+00 -0.6194 98 HP2O7-3 0.10640E-17 -17.9731 0.24344E-18 -18.6136 0.22880E+00 -0.6405 99 P2O7-4 0.92683E-17 -17.0330 0.70147E-18 -18.1540 0.75685E-01 -1.1210 100 H2S,aq 0.38522E-07 -7.4143 0.38384E-07 -7.4159 0.99643E+00 -0.0016 101 S2-2 0.37158E-11 -11.4299 0.19165E-11 -11.7175 0.51578E+00 -0.2875 102 S3-2 0.74069E-18 -18.1304 0.38203E-18 -18.4179 0.51578E+00 -0.2875 107 SO3-2 0.54172E-12 -12.2662 0.28350E-12 -12.5474 0.52334E+00 -0.2812 108 HSO3- 0.17642E-14 -14.7535 0.14717E-14 -14.8322 0.83421E+00 -0.0787 109 HSO4- 0.80311E-12 -12.0952 0.67192E-12 -12.1727 0.83665E+00 -0.0775 111 S2O3-2 0.73515E-14 -14.1336 0.37917E-14 -14.4212 0.51578E+00 -0.2875 Charge balance for all species = -.6132E-08 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.9878042E-10 -.2154944E-01 -.2168230E+02 0.0000 2 H2O 0.1000000E+01 0.5550396E+02 0.9981601E+06 0.0000 3 Cl- 0.1932938E-03 0.1941804E-03 0.6872157E+01 6.2889 4 SO4-- 0.1626929E-04 0.1622218E-04 0.1555586E+01 15.0876 5 HCO3- 0.1894438E-03 0.5128335E-03 0.3123658E+02 6.2808 6 HS- 0.1795402E-03 0.1796464E-03 0.5930806E+01 6.2569 7 Al+++ 0.1119314E-28 0.3899866E-05 0.1050390E+00 0.6522 8 H4SiO4 0.7720192E-03 0.1352673E-01 0.1297838E+04 -3.1124 9 Ca++ 0.7431689E-07 0.2025765E-06 0.8104568E-02 12.7440 10 Mg++ 0.2153233E-10 0.9317182E-10 0.2261205E-05 9.2040 11 Fe++ 0.3782542E-13 0.1793864E-07 0.1000056E-02 6.4492 12 K+ 0.1565482E-03 0.1572429E-03 0.6137687E+01 6.1981 13 Na+ 0.1988321E-01 0.2230211E-01 0.5118183E+03 8.3011 14 Mn++ 0.2295230E-10 0.2507278E-08 0.1375023E-03 9.2326 15 F- 0.2858840E-05 0.2868083E-05 0.5439192E-01 4.4580 16 HPO4-- 0.4541042E-07 0.4641506E-07 0.4447028E-02 12.5334 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.1936003E-01 -.1935486E-01 -.5172813E-05 0.0000000E+00 2 H2O 0.4985148E+02 0.4985148E+02 -.5095044E-05 0.0000000E+00 3 Cl- 0.1744052E-03 0.1744052E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.1457219E-04 0.1457013E-04 0.2060061E-08 0.0000000E+00 5 HCO3- 0.4606070E-03 0.4606070E-03 0.0000000E+00 0.0000000E+00 6 HS- 0.1613493E-03 0.1613513E-03 -.2060061E-08 0.0000000E+00 7 Al+++ 0.4775352E-05 0.3502707E-05 0.1272645E-05 0.0000000E+00 8 H4SiO4 0.1215302E-01 0.1214918E-01 0.3841240E-05 0.0000000E+00 9 Ca++ 0.2080835E-06 0.1819463E-06 0.2613721E-07 0.0000000E+00 10 Mg++ 0.8368328E-10 0.8368328E-10 0.0000000E+00 0.0000000E+00 11 Fe++ 0.3259227E-07 0.1611178E-07 0.1648049E-07 0.0000000E+00 12 K+ 0.1412294E-03 0.1412294E-03 0.0000000E+00 0.0000000E+00 13 Na+ 0.2003215E-01 0.2003088E-01 0.1271701E-05 0.0000000E+00 14 Mn++ 0.2251939E-08 0.2251939E-08 0.0000000E+00 0.0000000E+00 15 F- 0.2576000E-05 0.2576000E-05 0.0000000E+00 0.0000000E+00 16 HPO4-- 0.4168819E-07 0.4168819E-07 0.0000000E+00 0.0000000E+00 Chg. balance for solid moles: 0.0000E+00 Mass of aqueous solution: 0.899745E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 0.0061900 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 0.1272E-05 -5.896 0.3335E-03 -3.477 98.70 0.1280E-03 andradite 0.8240E-08 -8.084 0.4188E-05 -5.378 1.239 0.1088E-05 grossular 0.4722E-09 -9.326 0.2127E-06 -6.672 0.6295E-01 0.5918E-07 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.9458E+00 0.9458E+00 1.0000 -0.024 grossular 0.5419E-01 0.5419E-01 1.0000 -1.266 Solid products produced: Mass = 0.000338 g Volume = 0.000129 cm3 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.0061900 moles log = -2.2083 Original solution: 1000.0103000 g Original solution / Rock added: 161552.55 (Water/Rock Ratio), log = 5.2083 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0206 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9997E+00 0.9859 0.1006E+01 0.1020E+01 CO2,gas 0.2918E-05 1.0071 0.3000E-05 0.2979E-05 CH4,gas 0.3901E-05 1.0125 0.4031E-05 0.3981E-05 H2,gas 0.3335E-03 1.0005 0.3406E-03 0.3404E-03 H2S,gas 0.1038E-05 0.9960 0.1055E-05 0.1059E-05 S2,gas 0.3530E-24 1.0000 0.3602E-24 0.3602E-24 CO,gas 0.2668E-12 1.0000 0.2723E-12 0.2723E-12 SO3,gas 0.2141E-40 1.0000 0.2186E-40 0.2186E-40 SO2,gas 0.2838E-21 1.0000 0.2896E-21 0.2896E-21 HF,gas 0.3249E-14 1.0000 0.3317E-14 0.3317E-14 HCl,gas 0.4235E-17 1.0000 0.4323E-17 0.4323E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 17 albite -0.38 -0.38 0.00 0.000 0.11184E-10 23 andradite 39.01 39.01 0.00 0.000 0.12132E-10 24 grossular 32.73 32.73 0.00 0.000 0.12132E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -13.88 -7.22 -2.407 0.12331E+05 -5.523 3 CH4,gas 4.54 -2.55 -7.09 -1.773 0.12112E+05 -5.395 4 H2,gas 8.00 2.83 -5.17 -2.952 0.88220E+04 -3.468 5 H2S,gas -6.23 -13.91 -7.68 -3.838 0.13106E+05 -5.977 6 S2,gas -7.34 -33.48 -26.14 -4.022 0.44637E+05 -24.443 7 CO,gas 3.21 -11.05 -14.26 -4.389 0.24355E+05 -12.565 8 SO3,gas 17.12 -25.24 -42.36 -10.590 0.72328E+05 -40.660 9 SO2,gas 0.83 -22.40 -23.24 -6.197 0.39677E+05 -21.538 10 HF,gas 0.47 -15.70 -16.18 -8.089 0.27624E+05 -14.479 11 HCl,gas 5.19 -13.87 -19.06 -9.532 0.32550E+05 -17.364 12 acmite 7.71 7.11 -0.60 -0.062 0.10257E+04 16 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 20 spessartine 24.46 19.67 -4.79 -0.240 0.81827E+04 21 analcite 3.32 2.73 -0.59 -0.066 0.10131E+04 27 annite 20.12 16.86 -3.26 -0.181 0.55709E+04 28 phlogopite 27.06 25.13 -1.94 -0.108 0.33115E+04 30 anorthite 12.71 7.82 -4.89 -0.376 0.83439E+04 33 apatite-OH -18.15 -19.66 -1.50 -0.116 0.25661E+04 34 apatite-F -34.30 -35.36 -1.06 -0.088 0.18103E+04 38 aragonite 0.97 -1.14 -2.10 -0.701 0.35933E+04 39 brucite 12.57 9.20 -3.36 -0.673 0.57449E+04 40 calcite 0.81 -1.14 -1.95 -0.650 0.33291E+04 41 carnegieite-low 9.02 5.84 -3.18 -0.455 0.54339E+04 42 carnegieite-high 10.09 5.84 -4.25 -0.607 0.72609E+04 43 carpholite-Mg 8.58 4.28 -4.30 -0.287 0.73395E+04 45 celadonite 5.34 3.60 -1.74 -0.102 0.29656E+04 46 celadonite-Fe 3.88 0.85 -3.03 -0.178 0.51678E+04 47 chrysotile 23.89 21.39 -2.51 -0.209 0.42773E+04 49 clinochlore 39.07 37.99 -1.08 -0.034 0.18478E+04 50 daphnite 28.97 24.21 -4.75 -0.149 0.81140E+04 52 chlorite-Al-free 47.17 42.77 -4.40 -0.183 0.75098E+04 54 chloritoid-Fe 9.17 4.64 -4.53 -0.302 0.77390E+04 55 chloritoid-Mn 11.40 7.42 -3.98 -0.265 0.67898E+04 57 coesite -2.38 -3.11 -0.74 -0.245 0.12572E+04 64 cristobalite -2.56 -3.11 -0.55 -0.184 0.94258E+03 66 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71240E+04 68 diaspore 2.87 0.65 -2.22 -0.370 0.37932E+04 70 diopside 16.18 15.72 -0.46 -0.046 0.78210E+03 71 hedenbergite 14.21 12.97 -1.24 -0.124 0.21169E+04 76 clinoenstatite 17.17 12.18 -4.98 -0.498 0.85083E+04 78 epidote 24.67 22.49 -2.18 -0.106 0.37256E+04 79 clinozoisite 22.81 18.11 -4.70 -0.214 0.80227E+04 80 epidote-Fe 29.84 26.87 -2.97 -0.154 0.50751E+04 81 fayalite 14.05 9.79 -4.26 -0.609 0.72733E+04 82 ferrosilite 11.15 6.67 -4.48 -0.448 0.76423E+04 86 gibbsite 4.08 0.65 -3.43 -0.490 0.58517E+04 87 glaucophane 22.97 20.62 -2.36 -0.064 0.40215E+04 88 glaucophane-Fe 17.28 12.36 -4.92 -0.133 0.84020E+04 89 graphite -3.55 -8.22 -4.67 -1.334 0.79735E+04 90 greenalite 16.14 13.12 -3.02 -0.251 0.51509E+04 93 hematite 12.57 10.07 -2.50 -0.303 0.42701E+04 94 heulandite -5.83 -7.74 -1.91 -0.087 0.32629E+04 98 jadeite 4.22 2.73 -1.49 -0.149 0.25386E+04 100 kalsilite 7.58 3.74 -3.85 -0.549 0.65670E+04 101 kaolinite -1.33 -4.92 -3.59 -0.326 0.61258E+04 104 laumontite 2.88 1.60 -1.28 -0.086 0.21933E+04 105 lawsonite 9.62 7.82 -1.79 -0.119 0.30605E+04 106 leucite 4.12 0.63 -3.49 -0.349 0.59648E+04 108 lizardite 23.24 21.39 -1.86 -0.155 0.31700E+04 110 magnetite 20.09 16.51 -3.57 -0.292 0.61005E+04 111 minnesotaite 10.39 6.90 -3.49 -0.205 0.59591E+04 115 manganosite 14.06 9.23 -4.83 -1.206 0.82394E+04 119 microcline -2.49 -2.49 0.00 0.000 0.65277E+00 123 muscovite 2.58 -1.18 -3.76 -0.221 0.64286E+04 124 paragonite 4.24 0.92 -3.32 -0.195 0.56670E+04 125 nepheline 8.34 5.84 -2.50 -0.357 0.42663E+04 137 phlogopite-Na 29.65 27.23 -2.42 -0.134 0.41296E+04 139 prehnite 19.37 17.46 -1.92 -0.113 0.32725E+04 140 prehnite-Fe 22.50 21.84 -0.66 -0.040 0.11304E+04 141 pumpellyite-Fe 46.27 42.01 -4.26 -0.095 0.72695E+04 142 pumpellyite-Mg 48.99 44.77 -4.23 -0.094 0.72194E+04 145 pyrite -21.25 -24.20 -2.95 -0.694 0.50348E+04 146 pyrrhotite -4.26 -7.46 -3.20 -1.065 0.54577E+04 147 pyrrhotiteFe0.875 -6.02 -8.61 -2.60 -0.955 0.44346E+04 148 pyroxmangite 7.40 6.12 -1.28 -0.256 0.21829E+04 149 pyrophyllite -6.18 -11.15 -4.97 -0.311 0.84850E+04 150 quartz -2.99 -3.11 -0.12 -0.041 0.20991E+03 154 rhodochrosite -0.98 -4.65 -3.67 -1.224 0.62717E+04 155 rhodonite 7.45 6.12 -1.33 -0.265 0.22632E+04 156 sanidine -1.28 -2.49 -1.21 -0.093 0.20684E+04 158 siderite -2.61 -7.43 -4.82 -1.608 0.82380E+04 166 stilbite -7.52 -7.74 -0.22 -0.010 0.36911E+03 167 stilpnomelane-Fe 13.02 11.75 -1.27 -0.038 0.21627E+04 168 stilpnomelane-Mg 27.44 25.52 -1.92 -0.057 0.32731E+04 174 talc 16.49 15.16 -1.33 -0.078 0.22684E+04 177 tephroite 18.09 15.35 -2.73 -0.390 0.46665E+04 181 tridymite -2.63 -3.11 -0.49 -0.162 0.82989E+03 182 tremolite 47.87 46.61 -1.26 -0.034 0.21515E+04 184 troilite-low -4.41 -7.46 -3.05 -1.015 0.52005E+04 190 wairakite 3.95 1.60 -2.35 -0.138 0.40152E+04 191 walstromite 11.51 9.63 -1.88 -0.376 0.32059E+04 192 wollastonite 10.46 9.63 -0.83 -0.166 0.14163E+04 193 pseudo-wollastonite 11.00 9.63 -1.37 -0.274 0.23361E+04 194 zoisite 22.85 18.11 -4.74 -0.216 0.80967E+04 195 akaganeite 7.75 5.03 -2.72 -0.589 0.46476E+04 202 chalcedony -2.80 -3.11 -0.31 -0.103 0.52921E+03 204 montmorillonite-Ca -2.29 -6.22 -3.93 -0.243 0.67096E+04 205 montmorillonite-K -2.24 -6.28 -4.04 -0.247 0.68998E+04 206 montmorillonite-Mg -2.48 -6.80 -4.32 -0.268 0.73840E+04 207 montmorillonite-Na -2.04 -5.58 -3.55 -0.217 0.60545E+04 208 nontronite-Ca 3.21 0.96 -2.25 -0.146 0.38480E+04 209 nontronite-H 2.53 -1.14 -3.67 -0.246 0.62742E+04 210 nontronite-K 3.34 0.90 -2.44 -0.156 0.41614E+04 211 nontronite-Mg 3.07 0.38 -2.70 -0.175 0.46064E+04 212 nontronite-Na 3.52 1.60 -1.92 -0.123 0.32821E+04 228 tobermorite 9.82 7.50 -2.32 -0.633 0.39607E+04 234 alabandite -0.98 -4.67 -3.70 -1.232 0.63098E+04 237 boehmite 4.41 0.65 -3.75 -0.626 0.64101E+04 239 ferrous-oxide 9.81 6.45 -3.36 -0.841 0.57412E+04 245 silica-amorphous -2.09 -3.11 -1.02 -0.340 0.17434E+04 247 an20ab80 2.02 1.26 -0.76 -0.058 0.12979E+04 248 an25ab75 2.65 1.67 -0.98 -0.075 0.16694E+04 249 an30ab70 3.28 2.08 -1.20 -0.092 0.20504E+04 250 tr.625ac.25prg.125 45.16 44.08 -1.09 -0.029 0.18599E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 0.0002000 MOLES Current total amount of reactant added: 0.0061900 MOLES New total amount of reactant added: 0.0063900 MOLES Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.5508E-08 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 7 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 0.0063900 Water: Moles liquid = 0.4986E+02 kg liquid = 0.8982E+00 Moles total = 0.4985E+02 kg total = 0.8981E+00 Activity = 1.0000 Stoichiometric ionic strength = .1173869E-01 Osmotic coef. = 0.9525 True ionic strength = .2039116E-01 Chg. balance for total moles = -.5508E-08 Max. difference allowed = 0.1756E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.99150E-10 -10.0037 0.83217E-10 -10.0798 0.83930E+00 -0.0761 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.19460E-03 -3.7109 0.16233E-03 -3.7896 0.83418E+00 -0.0787 4 SO4-- 0.17330E-04 -4.7612 0.89566E-05 -5.0479 0.51681E+00 -0.2867 5 HCO3- 0.19583E-03 -3.7081 0.16360E-03 -3.7862 0.83542E+00 -0.0781 6 HS- 0.18389E-03 -3.7354 0.15342E-03 -3.8141 0.83430E+00 -0.0787 7 Al+++ 0.11247E-28 -28.9490 0.25699E-29 -29.5901 0.22849E+00 -0.6411 8 H4SiO4 0.77469E-03 -3.1109 0.77469E-03 -3.1109 0.10000E+01 0.0000 9 Ca++ 0.73653E-07 -7.1328 0.37781E-07 -7.4227 0.51296E+00 -0.2899 10 Mg++ 0.21548E-10 -10.6666 0.11002E-10 -10.9585 0.51058E+00 -0.2919 11 Fe++ 0.38717E-13 -13.4121 0.19790E-13 -13.7035 0.51115E+00 -0.2915 12 K+ 0.15655E-03 -3.8054 0.13081E-03 -3.8833 0.83562E+00 -0.0780 13 Na+ 0.19884E-01 -1.7015 0.16584E-01 -1.7803 0.83402E+00 -0.0788 14 Mn++ 0.23114E-10 -10.6361 0.11825E-10 -10.9272 0.51158E+00 -0.2911 15 F- 0.29476E-05 -5.5305 0.24537E-05 -5.6102 0.83243E+00 -0.0796 16 HPO4-- 0.45413E-07 -7.3428 0.23474E-07 -7.6294 0.51689E+00 -0.2866 18 HSiO3- 0.10420E-01 -1.9821 0.86925E-02 -2.0609 0.83418E+00 -0.0787 19 Ca(HSiO3)+ 0.89486E-08 -8.0482 0.74792E-08 -8.1261 0.83580E+00 -0.0779 20 Mg(HSiO3)+ 0.32430E-11 -11.4891 0.27105E-11 -11.5670 0.83580E+00 -0.0779 21 NaHSiO3,aq 0.23315E-02 -2.6324 0.23315E-02 -2.6324 0.10000E+01 0.0000 22 AlO+ 0.60404E-16 -16.2189 0.50486E-16 -16.2968 0.83580E+00 -0.0779 24 HAlO2,aq 0.12082E-09 -9.9179 0.12082E-09 -9.9179 0.10000E+01 0.0000 25 AlO2- 0.38598E-05 -5.4134 0.32138E-05 -5.4930 0.83265E+00 -0.0795 26 CH4,aq 0.27319E-08 -8.5635 0.27221E-08 -8.5651 0.99642E+00 -0.0016 31 CO,aq 0.18756E-15 -15.7268 0.18756E-15 -15.7268 0.10000E+01 0.0000 32 CO2,aq 0.29195E-07 -7.5347 0.29091E-07 -7.5362 0.99642E+00 -0.0016 33 CO3-2 0.33298E-03 -3.4776 0.17172E-03 -3.7652 0.51570E+00 -0.2876 34 CaCO3,aq 0.81350E-07 -7.0896 0.81350E-07 -7.0896 0.10000E+01 0.0000 35 Ca(HCO3)+ 0.18878E-09 -9.7241 0.15778E-09 -9.8019 0.83580E+00 -0.0779 36 CaCl+ 0.11875E-10 -10.9254 0.99253E-11 -11.0033 0.83580E+00 -0.0779 37 CaCl2,aq 0.38279E-15 -15.4170 0.38279E-15 -15.4170 0.10000E+01 0.0000 38 CaF+ 0.16194E-11 -11.7906 0.13535E-11 -11.8685 0.83580E+00 -0.0779 39 CaOH+ 0.38714E-07 -7.4121 0.32357E-07 -7.4900 0.83580E+00 -0.0779 40 CaSO4,aq 0.10746E-09 -9.9688 0.10746E-09 -9.9688 0.10000E+01 0.0000 41 HCl,aq 0.24754E-14 -14.6064 0.24754E-14 -14.6064 0.10000E+01 0.0000 45 HF,aq 0.13978E-11 -11.8546 0.13978E-11 -11.8546 0.10000E+01 0.0000 46 HF2- 0.13882E-17 -17.8576 0.11580E-17 -17.9363 0.83418E+00 -0.0787 48 FeCl+ 0.60840E-17 -17.2158 0.50850E-17 -17.2937 0.83580E+00 -0.0779 51 FeF+ 0.29690E-17 -17.5274 0.24815E-17 -17.6053 0.83580E+00 -0.0779 53 FeO,aq 0.11107E-09 -9.9544 0.11107E-09 -9.9544 0.10000E+01 0.0000 54 FeOH+ 0.92620E-11 -11.0333 0.77412E-11 -11.1112 0.83580E+00 -0.0779 55 HFeO2- 0.16741E-07 -7.7762 0.13965E-07 -7.8550 0.83418E+00 -0.0787 56 FeO+ 0.43606E-16 -16.3604 0.36446E-16 -16.4383 0.83580E+00 -0.0779 58 FeO2- 0.12910E-08 -8.8891 0.10769E-08 -8.9678 0.83418E+00 -0.0787 59 HFeO2,aq 0.11398E-10 -10.9432 0.11398E-10 -10.9432 0.10000E+01 0.0000 60 H2,aq 0.25758E-06 -6.5891 0.25666E-06 -6.5906 0.99642E+00 -0.0016 61 KCl,aq 0.38487E-09 -9.4147 0.38487E-09 -9.4147 0.10000E+01 0.0000 62 KHSO4,aq 0.27567E-18 -18.5596 0.27567E-18 -18.5596 0.10000E+01 0.0000 63 KOH,aq 0.67132E-06 -6.1731 0.67132E-06 -6.1731 0.10000E+01 0.0000 64 KSO4- 0.21796E-07 -7.6616 0.18181E-07 -7.7404 0.83418E+00 -0.0787 65 MgCO3,aq 0.59378E-11 -11.2264 0.59378E-11 -11.2264 0.10000E+01 0.0000 66 Mg(HCO3)+ 0.56171E-13 -13.2505 0.46947E-13 -13.3284 0.83580E+00 -0.0779 67 MgCl+ 0.31342E-14 -14.5039 0.26195E-14 -14.5818 0.83580E+00 -0.0779 68 MgF+ 0.17468E-14 -14.7578 0.14600E-14 -14.8356 0.83580E+00 -0.0779 69 MgOH+ 0.62382E-10 -10.2049 0.52139E-10 -10.2828 0.83580E+00 -0.0779 71 MnF+ 0.58472E-15 -15.2330 0.48871E-15 -15.3109 0.83580E+00 -0.0779 72 MnO,aq 0.17684E-08 -8.7524 0.17684E-08 -8.7524 0.10000E+01 0.0000 73 MnOH+ 0.51410E-09 -9.2890 0.42969E-09 -9.3668 0.83580E+00 -0.0779 74 MnO2-2 0.16433E-10 -10.7843 0.84746E-11 -11.0719 0.51570E+00 -0.2876 75 HMnO2- 0.18522E-09 -9.7323 0.15450E-09 -9.8111 0.83418E+00 -0.0787 78 MnCl+ 0.14143E-13 -13.8495 0.11820E-13 -13.9274 0.83580E+00 -0.0779 79 MnSO4,aq 0.30576E-13 -13.5146 0.30576E-13 -13.5146 0.10000E+01 0.0000 80 NaCl,aq 0.89216E-06 -6.0496 0.89216E-06 -6.0496 0.10000E+01 0.0000 81 NaF,aq 0.95266E-08 -8.0211 0.95266E-08 -8.0211 0.10000E+01 0.0000 82 NaOH,aq 0.85622E-04 -4.0674 0.85622E-04 -4.0674 0.10000E+01 0.0000 84 OH- 0.83385E-02 -2.0789 0.69430E-02 -2.1585 0.83265E+00 -0.0795 89 HPO3-2 0.36407E-16 -16.4388 0.18775E-16 -16.7264 0.51570E+00 -0.2876 92 H3PO4,aq 0.11369E-17 -17.9443 0.11369E-17 -17.9443 0.10000E+01 0.0000 93 H2PO4- 0.43157E-10 -10.3650 0.36035E-10 -10.4433 0.83498E+00 -0.0783 94 PO4-3 0.95831E-09 -9.0185 0.23015E-09 -9.6380 0.24016E+00 -0.6195 98 HP2O7-3 0.10681E-17 -17.9714 0.24431E-18 -18.6121 0.22873E+00 -0.6407 99 P2O7-4 0.92722E-17 -17.0328 0.70135E-18 -18.1541 0.75640E-01 -1.1212 100 H2S,aq 0.39599E-07 -7.4023 0.39457E-07 -7.4039 0.99642E+00 -0.0016 101 S2-2 0.39402E-11 -11.4045 0.20320E-11 -11.6921 0.51570E+00 -0.2876 102 S3-2 0.81609E-18 -18.0883 0.42086E-18 -18.3759 0.51570E+00 -0.2876 107 SO3-2 0.57090E-12 -12.2434 0.29873E-12 -12.5247 0.52327E+00 -0.2813 108 HSO3- 0.18659E-14 -14.7291 0.15565E-14 -14.8078 0.83418E+00 -0.0787 109 HSO4- 0.85857E-12 -12.0662 0.71830E-12 -12.1437 0.83662E+00 -0.0775 111 S2O3-2 0.80500E-14 -14.0942 0.41514E-14 -14.3818 0.51570E+00 -0.2876 Charge balance for all species = -.6132E-08 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.9915024E-10 -.2152522E-01 -.2165792E+02 0.0000 2 H2O 0.1000000E+01 0.5550393E+02 0.9981588E+06 0.0000 3 Cl- 0.1946009E-03 0.1954934E-03 0.6918621E+01 6.2902 4 SO4-- 0.1733049E-04 0.1728543E-04 0.1657542E+01 15.1117 5 HCO3- 0.1958331E-03 0.5289311E-03 0.3221705E+02 6.2936 6 HS- 0.1838869E-03 0.1839934E-03 0.6074313E+01 6.2657 7 Al+++ 0.1124700E-28 0.3859872E-05 0.1039617E+00 0.6493 8 H4SiO4 0.7746860E-03 0.1352656E-01 0.1297821E+04 -3.1109 9 Ca++ 0.7365314E-07 0.2029761E-06 0.8120548E-02 12.7369 10 Mg++ 0.2154765E-10 0.9317147E-10 0.2261195E-05 9.2010 11 Fe++ 0.3871716E-13 0.1816413E-07 0.1012626E-02 6.4560 12 K+ 0.1565488E-03 0.1572423E-03 0.6137659E+01 6.1964 13 Na+ 0.1988398E-01 0.2230198E-01 0.5118151E+03 8.2995 14 Mn++ 0.2311436E-10 0.2507269E-08 0.1375017E-03 9.2324 15 F- 0.2947613E-05 0.2957143E-05 0.5608085E-01 4.4696 16 HPO4-- 0.4541342E-07 0.4641489E-07 0.4447008E-02 12.5302 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.1933850E-01 -.1933318E-01 -.5315380E-05 0.0000000E+00 2 H2O 0.4985164E+02 0.4985165E+02 -.5238721E-05 0.0000000E+00 3 Cl- 0.1755852E-03 0.1755852E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.1552719E-04 0.1552516E-04 0.2034737E-08 0.0000000E+00 5 HCO3- 0.4750670E-03 0.4750670E-03 0.0000000E+00 0.0000000E+00 6 HS- 0.1652543E-03 0.1652563E-03 -.2034737E-08 0.0000000E+00 7 Al+++ 0.4775352E-05 0.3466799E-05 0.1308553E-05 0.0000000E+00 8 H4SiO4 0.1215302E-01 0.1214907E-01 0.3948714E-05 0.0000000E+00 9 Ca++ 0.2080835E-06 0.1823059E-06 0.2577763E-07 0.0000000E+00 10 Mg++ 0.8368328E-10 0.8368328E-10 0.0000000E+00 0.0000000E+00 11 Fe++ 0.3259227E-07 0.1631438E-07 0.1627789E-07 0.0000000E+00 12 K+ 0.1412294E-03 0.1412294E-03 0.0000000E+00 0.0000000E+00 13 Na+ 0.2003215E-01 0.2003084E-01 0.1307645E-05 0.0000000E+00 14 Mn++ 0.2251939E-08 0.2251939E-08 0.0000000E+00 0.0000000E+00 15 F- 0.2656000E-05 0.2656000E-05 0.0000000E+00 0.0000000E+00 16 HPO4-- 0.4168819E-07 0.4168819E-07 0.0000000E+00 0.0000000E+00 Chg. balance for solid moles: -.4235E-21 Mass of aqueous solution: 0.899749E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 0.0063900 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 0.1308E-05 -5.884 0.3429E-03 -3.465 98.75 0.1316E-03 andradite 0.8139E-08 -8.089 0.4136E-05 -5.383 1.191 0.1075E-05 grossular 0.4536E-09 -9.343 0.2043E-06 -6.690 0.5884E-01 0.5685E-07 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.9472E+00 0.9472E+00 1.0000 -0.024 grossular 0.5279E-01 0.5279E-01 1.0000 -1.277 Solid products produced: Mass = 0.000347 g Volume = 0.000133 cm3 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.0063900 moles log = -2.1945 Original solution: 1000.0103000 g Original solution / Rock added: 156496.13 (Water/Rock Ratio), log = 5.1945 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0206 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9997E+00 0.9859 0.1006E+01 0.1020E+01 CO2,gas 0.3028E-05 1.0071 0.3112E-05 0.3090E-05 CH4,gas 0.3877E-05 1.0125 0.4007E-05 0.3957E-05 H2,gas 0.3300E-03 1.0005 0.3370E-03 0.3368E-03 H2S,gas 0.1067E-05 0.9960 0.1085E-05 0.1089E-05 S2,gas 0.3811E-24 1.0000 0.3889E-24 0.3889E-24 CO,gas 0.2739E-12 1.0000 0.2795E-12 0.2795E-12 SO3,gas 0.2298E-40 1.0000 0.2345E-40 0.2345E-40 SO2,gas 0.3012E-21 1.0000 0.3074E-21 0.3074E-21 HF,gas 0.3363E-14 1.0000 0.3432E-14 0.3432E-14 HCl,gas 0.4280E-17 1.0000 0.4368E-17 0.4368E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 17 albite -0.38 -0.38 0.00 0.000 -0.94784E-12 23 andradite 39.01 39.01 0.00 0.000 0.36397E-10 24 grossular 32.73 32.73 0.00 0.000 0.00000E+00 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -13.87 -7.21 -2.402 0.12304E+05 -5.507 3 CH4,gas 4.54 -2.55 -7.10 -1.774 0.12117E+05 -5.397 4 H2,gas 8.00 2.83 -5.17 -2.955 0.88300E+04 -3.472 5 H2S,gas -6.23 -13.89 -7.66 -3.832 0.13086E+05 -5.965 6 S2,gas -7.34 -33.44 -26.11 -4.017 0.44581E+05 -24.410 7 CO,gas 3.21 -11.04 -14.25 -4.385 0.24336E+05 -12.554 8 SO3,gas 17.12 -25.21 -42.33 -10.582 0.72275E+05 -40.630 9 SO2,gas 0.83 -22.38 -23.21 -6.190 0.39632E+05 -21.512 10 HF,gas 0.47 -15.69 -16.16 -8.082 0.27599E+05 -14.464 11 HCl,gas 5.19 -13.87 -19.06 -9.529 0.32542E+05 -17.360 12 acmite 7.71 7.12 -0.59 -0.061 0.10077E+04 16 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 20 spessartine 24.46 19.66 -4.79 -0.240 0.81861E+04 21 analcite 3.32 2.73 -0.59 -0.066 0.10157E+04 27 annite 20.12 16.88 -3.24 -0.180 0.55359E+04 28 phlogopite 27.06 25.12 -1.95 -0.108 0.33267E+04 30 anorthite 12.71 7.81 -4.90 -0.377 0.83609E+04 33 apatite-OH -18.15 -19.68 -1.53 -0.118 0.26111E+04 34 apatite-F -34.30 -35.37 -1.07 -0.089 0.18299E+04 38 aragonite 0.97 -1.13 -2.10 -0.699 0.35783E+04 39 brucite 12.57 9.20 -3.37 -0.674 0.57499E+04 40 calcite 0.81 -1.13 -1.94 -0.647 0.33141E+04 41 carnegieite-low 9.02 5.84 -3.19 -0.455 0.54390E+04 42 carnegieite-high 10.09 5.84 -4.26 -0.608 0.72660E+04 43 carpholite-Mg 8.58 4.28 -4.30 -0.287 0.73493E+04 45 celadonite 5.34 3.60 -1.74 -0.102 0.29681E+04 46 celadonite-Fe 3.88 0.86 -3.02 -0.178 0.51536E+04 47 chrysotile 23.89 21.38 -2.51 -0.209 0.42875E+04 49 clinochlore 39.07 37.97 -1.10 -0.034 0.18754E+04 50 daphnite 28.97 24.25 -4.72 -0.147 0.80578E+04 52 chlorite-Al-free 47.17 42.76 -4.41 -0.184 0.75301E+04 54 chloritoid-Fe 9.17 4.64 -4.53 -0.302 0.77347E+04 55 chloritoid-Mn 11.40 7.42 -3.98 -0.265 0.67975E+04 57 coesite -2.38 -3.11 -0.73 -0.245 0.12547E+04 64 cristobalite -2.56 -3.11 -0.55 -0.184 0.94002E+03 66 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71241E+04 68 diaspore 2.87 0.65 -2.22 -0.371 0.37981E+04 70 diopside 16.18 15.72 -0.47 -0.047 0.79431E+03 71 hedenbergite 14.21 12.97 -1.24 -0.124 0.21124E+04 76 clinoenstatite 17.17 12.18 -4.99 -0.499 0.85133E+04 78 epidote 24.67 22.48 -2.19 -0.106 0.37366E+04 79 clinozoisite 22.81 18.09 -4.72 -0.214 0.80543E+04 80 epidote-Fe 29.84 26.87 -2.97 -0.154 0.50656E+04 81 fayalite 14.05 9.80 -4.24 -0.606 0.72474E+04 82 ferrosilite 11.15 6.69 -4.46 -0.446 0.76139E+04 86 gibbsite 4.08 0.65 -3.43 -0.490 0.58567E+04 87 glaucophane 22.97 20.61 -2.36 -0.064 0.40316E+04 88 glaucophane-Fe 17.28 12.38 -4.90 -0.132 0.83618E+04 89 graphite -3.55 -8.21 -4.66 -1.332 0.79621E+04 90 greenalite 16.14 13.15 -2.99 -0.249 0.51107E+04 93 hematite 12.57 10.08 -2.48 -0.301 0.42388E+04 94 heulandite -5.83 -7.74 -1.91 -0.087 0.32672E+04 98 jadeite 4.22 2.73 -1.49 -0.149 0.25412E+04 100 kalsilite 7.58 3.73 -3.85 -0.550 0.65721E+04 101 kaolinite -1.33 -4.92 -3.59 -0.326 0.61305E+04 104 laumontite 2.88 1.59 -1.29 -0.086 0.22052E+04 105 lawsonite 9.62 7.81 -1.80 -0.120 0.30775E+04 106 leucite 4.12 0.62 -3.49 -0.349 0.59674E+04 108 lizardite 23.24 21.38 -1.86 -0.155 0.31801E+04 110 magnetite 20.09 16.54 -3.55 -0.290 0.60576E+04 111 minnesotaite 10.39 6.92 -3.46 -0.204 0.59138E+04 115 manganosite 14.06 9.23 -4.83 -1.206 0.82398E+04 119 microcline -2.49 -2.49 0.00 0.000 0.67828E+00 123 muscovite 2.58 -1.19 -3.77 -0.222 0.64385E+04 124 paragonite 4.24 0.91 -3.32 -0.196 0.56769E+04 125 nepheline 8.34 5.84 -2.50 -0.357 0.42714E+04 137 phlogopite-Na 29.65 27.22 -2.43 -0.135 0.41449E+04 139 prehnite 19.37 17.44 -1.93 -0.114 0.32992E+04 140 prehnite-Fe 22.50 21.83 -0.67 -0.040 0.11366E+04 141 pumpellyite-Fe 46.27 41.98 -4.28 -0.095 0.73161E+04 142 pumpellyite-Mg 48.99 44.73 -4.27 -0.095 0.72827E+04 145 pyrite -21.25 -24.16 -2.91 -0.685 0.49743E+04 146 pyrrhotite -4.26 -7.44 -3.18 -1.059 0.54256E+04 147 pyrrhotiteFe0.875 -6.02 -8.60 -2.58 -0.948 0.44030E+04 148 pyroxmangite 7.40 6.12 -1.28 -0.255 0.21807E+04 149 pyrophyllite -6.18 -11.14 -4.97 -0.311 0.84847E+04 150 quartz -2.99 -3.11 -0.12 -0.040 0.20735E+03 154 rhodochrosite -0.98 -4.63 -3.66 -1.219 0.62447E+04 155 rhodonite 7.45 6.12 -1.32 -0.265 0.22610E+04 156 sanidine -1.28 -2.49 -1.21 -0.093 0.20684E+04 158 siderite -2.61 -7.41 -4.80 -1.601 0.81990E+04 166 stilbite -7.52 -7.74 -0.22 -0.010 0.37332E+03 167 stilpnomelane-Fe 13.02 11.79 -1.23 -0.037 0.20951E+04 168 stilpnomelane-Mg 27.44 25.52 -1.93 -0.058 0.32892E+04 174 talc 16.49 15.16 -1.33 -0.078 0.22734E+04 177 tephroite 18.09 15.35 -2.73 -0.390 0.46647E+04 181 tridymite -2.63 -3.11 -0.48 -0.162 0.82733E+03 182 tremolite 47.87 46.59 -1.28 -0.035 0.21809E+04 184 troilite-low -4.41 -7.44 -3.03 -1.009 0.51684E+04 190 wairakite 3.95 1.59 -2.36 -0.139 0.40271E+04 191 walstromite 11.51 9.63 -1.88 -0.377 0.32156E+04 192 wollastonite 10.46 9.63 -0.84 -0.167 0.14260E+04 193 pseudo-wollastonite 11.00 9.63 -1.37 -0.275 0.23458E+04 194 zoisite 22.85 18.09 -4.76 -0.216 0.81283E+04 195 akaganeite 7.75 5.04 -2.71 -0.587 0.46319E+04 202 chalcedony -2.80 -3.11 -0.31 -0.103 0.52665E+03 204 montmorillonite-Ca -2.29 -6.22 -3.93 -0.243 0.67113E+04 205 montmorillonite-K -2.24 -6.28 -4.04 -0.247 0.69004E+04 206 montmorillonite-Mg -2.48 -6.80 -4.32 -0.268 0.73845E+04 207 montmorillonite-Na -2.04 -5.58 -3.55 -0.217 0.60551E+04 208 nontronite-Ca 3.21 0.98 -2.23 -0.145 0.38109E+04 209 nontronite-H 2.53 -1.12 -3.65 -0.245 0.62351E+04 210 nontronite-K 3.34 0.93 -2.41 -0.155 0.41233E+04 211 nontronite-Mg 3.07 0.40 -2.68 -0.174 0.45682E+04 212 nontronite-Na 3.52 1.62 -1.90 -0.122 0.32439E+04 228 tobermorite 9.82 7.50 -2.32 -0.634 0.39684E+04 234 alabandite -0.98 -4.66 -3.68 -1.228 0.62898E+04 237 boehmite 4.41 0.65 -3.76 -0.626 0.64150E+04 239 ferrous-oxide 9.81 6.46 -3.36 -0.839 0.57295E+04 245 silica-amorphous -2.09 -3.11 -1.02 -0.340 0.17408E+04 247 an20ab80 2.02 1.26 -0.76 -0.059 0.13013E+04 248 an25ab75 2.65 1.67 -0.98 -0.075 0.16736E+04 249 an30ab70 3.28 2.08 -1.20 -0.093 0.20555E+04 250 tr.625ac.25prg.125 45.16 44.07 -1.10 -0.030 0.18706E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 0.0002000 MOLES Current total amount of reactant added: 0.0063900 MOLES New total amount of reactant added: 0.0065900 MOLES Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.5508E-08 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 7 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 0.0065900 Water: Moles liquid = 0.4986E+02 kg liquid = 0.8982E+00 Moles total = 0.4985E+02 kg total = 0.8981E+00 Activity = 1.0000 Stoichiometric ionic strength = .1175151E-01 Osmotic coef. = 0.9521 True ionic strength = .2040268E-01 Chg. balance for total moles = -.5508E-08 Max. difference allowed = 0.1768E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.99522E-10 -10.0021 0.83526E-10 -10.0782 0.83927E+00 -0.0761 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.19591E-03 -3.7079 0.16342E-03 -3.7867 0.83415E+00 -0.0788 4 SO4-- 0.18392E-04 -4.7354 0.95037E-05 -5.0221 0.51674E+00 -0.2867 5 HCO3- 0.20225E-03 -3.6941 0.16896E-03 -3.7722 0.83538E+00 -0.0781 6 HS- 0.18823E-03 -3.7253 0.15704E-03 -3.8040 0.83427E+00 -0.0787 7 Al+++ 0.11301E-28 -28.9469 0.25814E-29 -29.5881 0.22842E+00 -0.6413 8 H4SiO4 0.77737E-03 -3.1094 0.77737E-03 -3.1094 0.10000E+01 0.0000 9 Ca++ 0.73008E-07 -7.1366 0.37445E-07 -7.4266 0.51289E+00 -0.2900 10 Mg++ 0.21563E-10 -10.6663 0.11008E-10 -10.9583 0.51051E+00 -0.2920 11 Fe++ 0.39635E-13 -13.4019 0.20256E-13 -13.6934 0.51107E+00 -0.2915 12 K+ 0.15655E-03 -3.8053 0.13081E-03 -3.8834 0.83559E+00 -0.0780 13 Na+ 0.19885E-01 -1.7015 0.16584E-01 -1.7803 0.83399E+00 -0.0788 14 Mn++ 0.23278E-10 -10.6331 0.11907E-10 -10.9242 0.51150E+00 -0.2912 15 F- 0.30364E-05 -5.5176 0.25275E-05 -5.5973 0.83240E+00 -0.0797 16 HPO4-- 0.45416E-07 -7.3428 0.23472E-07 -7.6295 0.51681E+00 -0.2867 18 HSiO3- 0.10418E-01 -1.9822 0.86902E-02 -2.0610 0.83415E+00 -0.0788 19 Ca(HSiO3)+ 0.88669E-08 -8.0522 0.74107E-08 -8.1301 0.83577E+00 -0.0779 20 Mg(HSiO3)+ 0.32441E-11 -11.4889 0.27113E-11 -11.5668 0.83577E+00 -0.0779 21 NaHSiO3,aq 0.23309E-02 -2.6325 0.23309E-02 -2.6325 0.10000E+01 0.0000 22 AlO+ 0.60229E-16 -16.2202 0.50337E-16 -16.2981 0.83577E+00 -0.0779 24 HAlO2,aq 0.12002E-09 -9.9208 0.12002E-09 -9.9208 0.10000E+01 0.0000 25 AlO2- 0.38201E-05 -5.4179 0.31807E-05 -5.4975 0.83262E+00 -0.0796 26 CH4,aq 0.27217E-08 -8.5652 0.27119E-08 -8.5667 0.99642E+00 -0.0016 31 CO,aq 0.19251E-15 -15.7156 0.19251E-15 -15.7156 0.10000E+01 0.0000 32 CO2,aq 0.30263E-07 -7.5191 0.30155E-07 -7.5206 0.99642E+00 -0.0016 33 CO3-2 0.34266E-03 -3.4651 0.17668E-03 -3.7528 0.51562E+00 -0.2877 34 CaCO3,aq 0.82956E-07 -7.0812 0.82956E-07 -7.0812 0.10000E+01 0.0000 35 Ca(HCO3)+ 0.19323E-09 -9.7139 0.16149E-09 -9.7918 0.83577E+00 -0.0779 36 CaCl+ 0.11848E-10 -10.9263 0.99026E-11 -11.0043 0.83577E+00 -0.0779 37 CaCl2,aq 0.38446E-15 -15.4151 0.38446E-15 -15.4151 0.10000E+01 0.0000 38 CaF+ 0.16533E-11 -11.7816 0.13818E-11 -11.8596 0.83577E+00 -0.0779 39 CaOH+ 0.38229E-07 -7.4176 0.31950E-07 -7.4955 0.83577E+00 -0.0779 40 CaSO4,aq 0.11300E-09 -9.9469 0.11300E-09 -9.9469 0.10000E+01 0.0000 41 HCl,aq 0.25012E-14 -14.6019 0.25012E-14 -14.6019 0.10000E+01 0.0000 45 HF,aq 0.14452E-11 -11.8401 0.14452E-11 -11.8401 0.10000E+01 0.0000 46 HF2- 0.14785E-17 -17.8302 0.12333E-17 -17.9089 0.83415E+00 -0.0788 48 FeCl+ 0.62690E-17 -17.2028 0.52395E-17 -17.2807 0.83577E+00 -0.0779 51 FeF+ 0.31304E-17 -17.5044 0.26163E-17 -17.5823 0.83577E+00 -0.0779 53 FeO,aq 0.11284E-09 -9.9475 0.11284E-09 -9.9475 0.10000E+01 0.0000 54 FeOH+ 0.94453E-11 -11.0248 0.78941E-11 -11.1027 0.83577E+00 -0.0779 55 HFeO2- 0.16946E-07 -7.7709 0.14136E-07 -7.8497 0.83415E+00 -0.0788 56 FeO+ 0.44690E-16 -16.3498 0.37351E-16 -16.4277 0.83577E+00 -0.0779 58 FeO2- 0.13133E-08 -8.8816 0.10955E-08 -8.9604 0.83415E+00 -0.0788 59 HFeO2,aq 0.11638E-10 -10.9341 0.11638E-10 -10.9341 0.10000E+01 0.0000 60 H2,aq 0.25504E-06 -6.5934 0.25413E-06 -6.5949 0.99642E+00 -0.0016 61 KCl,aq 0.38743E-09 -9.4118 0.38743E-09 -9.4118 0.10000E+01 0.0000 62 KHSO4,aq 0.29359E-18 -18.5323 0.29359E-18 -18.5323 0.10000E+01 0.0000 63 KOH,aq 0.66882E-06 -6.1747 0.66882E-06 -6.1747 0.10000E+01 0.0000 64 KSO4- 0.23127E-07 -7.6359 0.19291E-07 -7.7146 0.83415E+00 -0.0788 65 MgCO3,aq 0.61129E-11 -11.2138 0.61129E-11 -11.2138 0.10000E+01 0.0000 66 Mg(HCO3)+ 0.58044E-13 -13.2362 0.48511E-13 -13.3142 0.83577E+00 -0.0779 67 MgCl+ 0.31570E-14 -14.5007 0.26385E-14 -14.5786 0.83577E+00 -0.0779 68 MgF+ 0.18004E-14 -14.7446 0.15047E-14 -14.8225 0.83577E+00 -0.0779 69 MgOH+ 0.62188E-10 -10.2063 0.51975E-10 -10.2842 0.83577E+00 -0.0779 71 MnF+ 0.60650E-15 -15.2172 0.50689E-15 -15.2951 0.83577E+00 -0.0779 72 MnO,aq 0.17674E-08 -8.7527 0.17674E-08 -8.7527 0.10000E+01 0.0000 73 MnOH+ 0.51576E-09 -9.2876 0.43106E-09 -9.3655 0.83577E+00 -0.0779 74 MnO2-2 0.16306E-10 -10.7877 0.84076E-11 -11.0753 0.51562E+00 -0.2877 75 HMnO2- 0.18444E-09 -9.7341 0.15385E-09 -9.8129 0.83415E+00 -0.0788 78 MnCl+ 0.14336E-13 -13.8436 0.11982E-13 -13.9215 0.83577E+00 -0.0779 79 MnSO4,aq 0.32668E-13 -13.4859 0.32668E-13 -13.4859 0.10000E+01 0.0000 80 NaCl,aq 0.89812E-06 -6.0467 0.89812E-06 -6.0467 0.10000E+01 0.0000 81 NaF,aq 0.98131E-08 -8.0082 0.98131E-08 -8.0082 0.10000E+01 0.0000 82 NaOH,aq 0.85305E-04 -4.0690 0.85305E-04 -4.0690 0.10000E+01 0.0000 84 OH- 0.83079E-02 -2.0805 0.69173E-02 -2.1601 0.83262E+00 -0.0796 89 HPO3-2 0.36051E-16 -16.4431 0.18589E-16 -16.7308 0.51562E+00 -0.2877 92 H3PO4,aq 0.11453E-17 -17.9411 0.11453E-17 -17.9411 0.10000E+01 0.0000 93 H2PO4- 0.43315E-10 -10.3634 0.36166E-10 -10.4417 0.83495E+00 -0.0783 94 PO4-3 0.95499E-09 -9.0200 0.22928E-09 -9.6396 0.24008E+00 -0.6196 98 HP2O7-3 0.10723E-17 -17.9697 0.24518E-18 -18.6105 0.22865E+00 -0.6408 99 P2O7-4 0.92762E-17 -17.0326 0.70124E-18 -18.1541 0.75596E-01 -1.1215 100 H2S,aq 0.40684E-07 -7.3906 0.40539E-07 -7.3921 0.99642E+00 -0.0016 101 S2-2 0.41701E-11 -11.3799 0.21502E-11 -11.6675 0.51562E+00 -0.2877 102 S3-2 0.89622E-18 -18.0476 0.46211E-18 -18.3353 0.51562E+00 -0.2877 107 SO3-2 0.59987E-12 -12.2219 0.31385E-12 -12.5033 0.52319E+00 -0.2813 108 HSO3- 0.19677E-14 -14.7060 0.16414E-14 -14.7848 0.83415E+00 -0.0788 109 HSO4- 0.91443E-12 -12.0389 0.76500E-12 -12.1163 0.83659E+00 -0.0775 111 S2O3-2 0.87771E-14 -14.0566 0.45257E-14 -14.3443 0.51562E+00 -0.2877 Charge balance for all species = -.6132E-08 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.9952226E-10 -.2150100E-01 -.2163353E+02 0.0000 2 H2O 0.1000000E+01 0.5550390E+02 0.9981576E+06 0.0000 3 Cl- 0.1959080E-03 0.1968065E-03 0.6965085E+01 6.2915 4 SO4-- 0.1839174E-04 0.1834867E-04 0.1759497E+01 15.1343 5 HCO3- 0.2022509E-03 0.5450285E-03 0.3319752E+02 6.3060 6 HS- 0.1882334E-03 0.1883404E-03 0.6217820E+01 6.2742 7 Al+++ 0.1130125E-28 0.3820205E-05 0.1028932E+00 0.6464 8 H4SiO4 0.7773677E-03 0.1352639E-01 0.1297803E+04 -3.1094 9 Ca++ 0.7300788E-07 0.2033794E-06 0.8136679E-02 12.7297 10 Mg++ 0.2156304E-10 0.9317111E-10 0.2261185E-05 9.1981 11 Fe++ 0.3963453E-13 0.1839366E-07 0.1025421E-02 6.4629 12 K+ 0.1565494E-03 0.1572417E-03 0.6137631E+01 6.1948 13 Na+ 0.1988476E-01 0.2230186E-01 0.5118118E+03 8.2979 14 Mn++ 0.2327782E-10 0.2507259E-08 0.1375011E-03 9.2321 15 F- 0.3036386E-05 0.3046202E-05 0.5776977E-01 4.4809 16 HPO4-- 0.4541641E-07 0.4641471E-07 0.4446988E-02 12.5269 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.1931696E-01 -.1931150E-01 -.5456761E-05 0.0000000E+00 2 H2O 0.4985180E+02 0.4985181E+02 -.5381219E-05 0.0000000E+00 3 Cl- 0.1767652E-03 0.1767652E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.1648219E-04 0.1648018E-04 0.2008960E-08 0.0000000E+00 5 HCO3- 0.4895270E-03 0.4895270E-03 0.0000000E+00 0.0000000E+00 6 HS- 0.1691593E-03 0.1691613E-03 -.2008960E-08 0.0000000E+00 7 Al+++ 0.4775352E-05 0.3431185E-05 0.1344167E-05 0.0000000E+00 8 H4SiO4 0.1215302E-01 0.1214896E-01 0.4055302E-05 0.0000000E+00 9 Ca++ 0.2080835E-06 0.1826688E-06 0.2541467E-07 0.0000000E+00 10 Mg++ 0.8368328E-10 0.8368328E-10 0.0000000E+00 0.0000000E+00 11 Fe++ 0.3259227E-07 0.1652059E-07 0.1607168E-07 0.0000000E+00 12 K+ 0.1412294E-03 0.1412294E-03 0.0000000E+00 0.0000000E+00 13 Na+ 0.2003215E-01 0.2003081E-01 0.1343296E-05 0.0000000E+00 14 Mn++ 0.2251939E-08 0.2251939E-08 0.0000000E+00 0.0000000E+00 15 F- 0.2736000E-05 0.2736000E-05 0.0000000E+00 0.0000000E+00 16 HPO4-- 0.4168819E-07 0.4168819E-07 0.0000000E+00 0.0000000E+00 Chg. balance for solid moles: 0.2118E-21 Mass of aqueous solution: 0.899753E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 0.0065900 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 0.1343E-05 -5.872 0.3522E-03 -3.453 98.80 0.1352E-03 andradite 0.8036E-08 -8.095 0.4084E-05 -5.389 1.145 0.1061E-05 grossular 0.4357E-09 -9.361 0.1963E-06 -6.707 0.5505E-01 0.5461E-07 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.9486E+00 0.9486E+00 1.0000 -0.023 grossular 0.5143E-01 0.5143E-01 1.0000 -1.289 Solid products produced: Mass = 0.000357 g Volume = 0.000136 cm3 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.0065900 moles log = -2.1811 Original solution: 1000.0103000 g Original solution / Rock added: 151746.63 (Water/Rock Ratio), log = 5.1811 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0206 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9997E+00 0.9859 0.1006E+01 0.1020E+01 CO2,gas 0.3139E-05 1.0071 0.3226E-05 0.3203E-05 CH4,gas 0.3863E-05 1.0125 0.3992E-05 0.3942E-05 H2,gas 0.3267E-03 1.0005 0.3336E-03 0.3335E-03 H2S,gas 0.1096E-05 0.9960 0.1114E-05 0.1119E-05 S2,gas 0.4103E-24 1.0000 0.4188E-24 0.4188E-24 CO,gas 0.2811E-12 1.0000 0.2869E-12 0.2869E-12 SO3,gas 0.2456E-40 1.0000 0.2507E-40 0.2507E-40 SO2,gas 0.3188E-21 1.0000 0.3254E-21 0.3254E-21 HF,gas 0.3477E-14 1.0000 0.3548E-14 0.3548E-14 HCl,gas 0.4324E-17 1.0000 0.4413E-17 0.4413E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 17 albite -0.38 -0.38 0.00 0.000 -0.94784E-12 23 andradite 39.01 39.01 0.00 0.000 0.00000E+00 24 grossular 32.73 32.73 0.00 0.000 -0.36397E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -13.85 -7.19 -2.397 0.12277E+05 -5.491 3 CH4,gas 4.54 -2.55 -7.10 -1.774 0.12119E+05 -5.399 4 H2,gas 8.00 2.82 -5.18 -2.958 0.88373E+04 -3.477 5 H2S,gas -6.23 -13.88 -7.65 -3.826 0.13065E+05 -5.953 6 S2,gas -7.34 -33.41 -26.08 -4.012 0.44526E+05 -24.378 7 CO,gas 3.21 -11.03 -14.24 -4.382 0.24317E+05 -12.542 8 SO3,gas 17.12 -25.18 -42.30 -10.575 0.72226E+05 -40.601 9 SO2,gas 0.83 -22.35 -23.19 -6.183 0.39590E+05 -21.488 10 HF,gas 0.47 -15.68 -16.15 -8.074 0.27574E+05 -14.450 11 HCl,gas 5.19 -13.86 -19.05 -9.527 0.32535E+05 -17.355 12 acmite 7.71 7.13 -0.58 -0.060 0.98986E+03 16 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 20 spessartine 24.46 19.66 -4.80 -0.240 0.81894E+04 21 analcite 3.32 2.73 -0.60 -0.066 0.10183E+04 27 annite 20.12 16.90 -3.22 -0.179 0.55007E+04 28 phlogopite 27.06 25.11 -1.96 -0.109 0.33420E+04 30 anorthite 12.71 7.80 -4.91 -0.377 0.83778E+04 33 apatite-OH -18.15 -19.71 -1.56 -0.120 0.26555E+04 34 apatite-F -34.30 -35.38 -1.08 -0.090 0.18495E+04 38 aragonite 0.97 -1.12 -2.09 -0.696 0.35638E+04 39 brucite 12.57 9.20 -3.37 -0.674 0.57550E+04 40 calcite 0.81 -1.12 -1.93 -0.644 0.32996E+04 41 carnegieite-low 9.02 5.83 -3.19 -0.455 0.54441E+04 42 carnegieite-high 10.09 5.83 -4.26 -0.608 0.72711E+04 43 carpholite-Mg 8.58 4.27 -4.31 -0.287 0.73592E+04 45 celadonite 5.34 3.60 -1.74 -0.102 0.29707E+04 46 celadonite-Fe 3.88 0.87 -3.01 -0.177 0.51393E+04 47 chrysotile 23.89 21.38 -2.52 -0.210 0.42976E+04 49 clinochlore 39.07 37.96 -1.11 -0.035 0.19030E+04 50 daphnite 28.97 24.28 -4.69 -0.146 0.80012E+04 52 chlorite-Al-free 47.17 42.75 -4.42 -0.184 0.75504E+04 54 chloritoid-Fe 9.17 4.65 -4.53 -0.302 0.77302E+04 55 chloritoid-Mn 11.40 7.42 -3.99 -0.266 0.68052E+04 57 coesite -2.38 -3.11 -0.73 -0.244 0.12521E+04 64 cristobalite -2.56 -3.11 -0.55 -0.183 0.93746E+03 66 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71241E+04 68 diaspore 2.87 0.65 -2.23 -0.371 0.38031E+04 70 diopside 16.18 15.71 -0.47 -0.047 0.80642E+03 71 hedenbergite 14.21 12.97 -1.23 -0.123 0.21076E+04 76 clinoenstatite 17.17 12.18 -4.99 -0.499 0.85184E+04 78 epidote 24.67 22.48 -2.19 -0.106 0.37477E+04 79 clinozoisite 22.81 18.07 -4.74 -0.215 0.80857E+04 80 epidote-Fe 29.84 26.88 -2.96 -0.154 0.50563E+04 81 fayalite 14.05 9.82 -4.23 -0.604 0.72214E+04 82 ferrosilite 11.15 6.71 -4.44 -0.444 0.75852E+04 86 gibbsite 4.08 0.65 -3.43 -0.490 0.58616E+04 87 glaucophane 22.97 20.61 -2.37 -0.064 0.40417E+04 88 glaucophane-Fe 17.28 12.40 -4.87 -0.132 0.83215E+04 89 graphite -3.55 -8.20 -4.66 -1.330 0.79501E+04 90 greenalite 16.14 13.17 -2.97 -0.247 0.50704E+04 93 hematite 12.57 10.10 -2.46 -0.299 0.42079E+04 94 heulandite -5.83 -7.74 -1.92 -0.087 0.32712E+04 98 jadeite 4.22 2.73 -1.49 -0.149 0.25437E+04 100 kalsilite 7.58 3.73 -3.85 -0.550 0.65773E+04 101 kaolinite -1.33 -4.93 -3.59 -0.327 0.61353E+04 104 laumontite 2.88 1.59 -1.30 -0.087 0.22169E+04 105 lawsonite 9.62 7.80 -1.81 -0.121 0.30944E+04 106 leucite 4.12 0.62 -3.50 -0.350 0.59700E+04 108 lizardite 23.24 21.38 -1.87 -0.156 0.31902E+04 110 magnetite 20.09 16.56 -3.52 -0.288 0.60149E+04 111 minnesotaite 10.39 6.95 -3.44 -0.202 0.58683E+04 115 manganosite 14.06 9.23 -4.83 -1.206 0.82402E+04 119 microcline -2.49 -2.49 0.00 0.000 0.70387E+00 123 muscovite 2.58 -1.19 -3.78 -0.222 0.64484E+04 124 paragonite 4.24 0.91 -3.33 -0.196 0.56868E+04 125 nepheline 8.34 5.83 -2.50 -0.358 0.42765E+04 137 phlogopite-Na 29.65 27.21 -2.44 -0.135 0.41601E+04 139 prehnite 19.37 17.42 -1.95 -0.115 0.33257E+04 140 prehnite-Fe 22.50 21.83 -0.67 -0.040 0.11427E+04 141 pumpellyite-Fe 46.27 41.96 -4.31 -0.096 0.73623E+04 142 pumpellyite-Mg 48.99 44.69 -4.30 -0.096 0.73457E+04 145 pyrite -21.25 -24.13 -2.88 -0.677 0.49151E+04 146 pyrrhotite -4.26 -7.42 -3.16 -1.053 0.53938E+04 147 pyrrhotiteFe0.875 -6.02 -8.58 -2.56 -0.942 0.43717E+04 148 pyroxmangite 7.40 6.12 -1.28 -0.255 0.21786E+04 149 pyrophyllite -6.18 -11.14 -4.97 -0.311 0.84843E+04 150 quartz -2.99 -3.11 -0.12 -0.040 0.20479E+03 154 rhodochrosite -0.98 -4.62 -3.64 -1.214 0.62185E+04 155 rhodonite 7.45 6.12 -1.32 -0.265 0.22588E+04 156 sanidine -1.28 -2.49 -1.21 -0.093 0.20685E+04 158 siderite -2.61 -7.39 -4.78 -1.593 0.81606E+04 166 stilbite -7.52 -7.74 -0.22 -0.011 0.37740E+03 167 stilpnomelane-Fe 13.02 11.83 -1.19 -0.035 0.20271E+04 168 stilpnomelane-Mg 27.44 25.51 -1.94 -0.058 0.33054E+04 174 talc 16.49 15.16 -1.33 -0.078 0.22784E+04 177 tephroite 18.09 15.35 -2.73 -0.390 0.46629E+04 181 tridymite -2.63 -3.11 -0.48 -0.161 0.82477E+03 182 tremolite 47.87 46.57 -1.29 -0.035 0.22102E+04 184 troilite-low -4.41 -7.42 -3.01 -1.003 0.51366E+04 190 wairakite 3.95 1.59 -2.37 -0.139 0.40389E+04 191 walstromite 11.51 9.62 -1.89 -0.378 0.32252E+04 192 wollastonite 10.46 9.62 -0.84 -0.168 0.14356E+04 193 pseudo-wollastonite 11.00 9.62 -1.38 -0.276 0.23554E+04 194 zoisite 22.85 18.07 -4.78 -0.217 0.81598E+04 195 akaganeite 7.75 5.05 -2.70 -0.585 0.46165E+04 202 chalcedony -2.80 -3.11 -0.31 -0.102 0.52409E+03 204 montmorillonite-Ca -2.29 -6.22 -3.93 -0.243 0.67130E+04 205 montmorillonite-K -2.24 -6.28 -4.04 -0.247 0.69010E+04 206 montmorillonite-Mg -2.48 -6.80 -4.33 -0.268 0.73850E+04 207 montmorillonite-Na -2.04 -5.58 -3.55 -0.217 0.60557E+04 208 nontronite-Ca 3.21 1.00 -2.21 -0.143 0.37743E+04 209 nontronite-H 2.53 -1.10 -3.63 -0.243 0.61965E+04 210 nontronite-K 3.34 0.95 -2.39 -0.154 0.40855E+04 211 nontronite-Mg 3.07 0.42 -2.65 -0.172 0.45304E+04 212 nontronite-Na 3.52 1.64 -1.88 -0.121 0.32062E+04 228 tobermorite 9.82 7.49 -2.33 -0.635 0.39759E+04 234 alabandite -0.98 -4.65 -3.67 -1.224 0.62701E+04 237 boehmite 4.41 0.65 -3.76 -0.627 0.64200E+04 239 ferrous-oxide 9.81 6.46 -3.35 -0.837 0.57178E+04 245 silica-amorphous -2.09 -3.11 -1.02 -0.339 0.17383E+04 247 an20ab80 2.02 1.25 -0.76 -0.059 0.13047E+04 248 an25ab75 2.65 1.66 -0.98 -0.076 0.16779E+04 249 an30ab70 3.28 2.07 -1.21 -0.093 0.20606E+04 250 tr.625ac.25prg.125 45.16 44.06 -1.10 -0.030 0.18810E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 0.0002000 MOLES Current total amount of reactant added: 0.0065900 MOLES New total amount of reactant added: 0.0067900 MOLES Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.5508E-08 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 7 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 0.0067900 Water: Moles liquid = 0.4986E+02 kg liquid = 0.8982E+00 Moles total = 0.4985E+02 kg total = 0.8981E+00 Activity = 1.0000 Stoichiometric ionic strength = .1176433E-01 Osmotic coef. = 0.9518 True ionic strength = .2041416E-01 Chg. balance for total moles = -.5508E-08 Max. difference allowed = 0.1779E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.99897E-10 -10.0004 0.83837E-10 -10.0766 0.83924E+00 -0.0761 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.19722E-03 -3.7051 0.16450E-03 -3.7838 0.83412E+00 -0.0788 4 SO4-- 0.19453E-04 -4.7110 0.10051E-04 -4.9978 0.51666E+00 -0.2868 5 HCO3- 0.20870E-03 -3.6805 0.17434E-03 -3.7586 0.83535E+00 -0.0781 6 HS- 0.19258E-03 -3.7154 0.16066E-03 -3.7941 0.83424E+00 -0.0787 7 Al+++ 0.11356E-28 -28.9448 0.25930E-29 -29.5862 0.22834E+00 -0.6414 8 H4SiO4 0.78006E-03 -3.1079 0.78006E-03 -3.1079 0.10000E+01 0.0000 9 Ca++ 0.72380E-07 -7.1404 0.37117E-07 -7.4304 0.51281E+00 -0.2900 10 Mg++ 0.21578E-10 -10.6660 0.11014E-10 -10.9580 0.51043E+00 -0.2921 11 Fe++ 0.40577E-13 -13.3917 0.20735E-13 -13.6833 0.51100E+00 -0.2916 12 K+ 0.15655E-03 -3.8053 0.13081E-03 -3.8834 0.83556E+00 -0.0780 13 Na+ 0.19886E-01 -1.7015 0.16584E-01 -1.7803 0.83396E+00 -0.0789 14 Mn++ 0.23443E-10 -10.6300 0.11989E-10 -10.9212 0.51143E+00 -0.2912 15 F- 0.31252E-05 -5.5051 0.26013E-05 -5.5848 0.83237E+00 -0.0797 16 HPO4-- 0.45419E-07 -7.3428 0.23470E-07 -7.6295 0.51674E+00 -0.2867 18 HSiO3- 0.10416E-01 -1.9823 0.86880E-02 -2.0611 0.83412E+00 -0.0788 19 Ca(HSiO3)+ 0.87874E-08 -8.0561 0.73440E-08 -8.1341 0.83574E+00 -0.0779 20 Mg(HSiO3)+ 0.32452E-11 -11.4888 0.27121E-11 -11.5667 0.83574E+00 -0.0779 21 NaHSiO3,aq 0.23303E-02 -2.6326 0.23303E-02 -2.6326 0.10000E+01 0.0000 22 AlO+ 0.60053E-16 -16.2215 0.50189E-16 -16.2994 0.83574E+00 -0.0779 24 HAlO2,aq 0.11922E-09 -9.9237 0.11922E-09 -9.9237 0.10000E+01 0.0000 25 AlO2- 0.37807E-05 -5.4224 0.31478E-05 -5.5020 0.83259E+00 -0.0796 26 CH4,aq 0.27167E-08 -8.5660 0.27070E-08 -8.5675 0.99641E+00 -0.0016 31 CO,aq 0.19754E-15 -15.7043 0.19754E-15 -15.7043 0.10000E+01 0.0000 32 CO2,aq 0.31343E-07 -7.5039 0.31231E-07 -7.5054 0.99641E+00 -0.0016 33 CO3-2 0.35231E-03 -3.4531 0.18163E-03 -3.7408 0.51555E+00 -0.2877 34 CaCO3,aq 0.84534E-07 -7.0730 0.84534E-07 -7.0730 0.10000E+01 0.0000 35 Ca(HCO3)+ 0.19764E-09 -9.7041 0.16518E-09 -9.7821 0.83574E+00 -0.0779 36 CaCl+ 0.11823E-10 -10.9273 0.98811E-11 -11.0052 0.83574E+00 -0.0779 37 CaCl2,aq 0.38617E-15 -15.4132 0.38617E-15 -15.4132 0.10000E+01 0.0000 38 CaF+ 0.16867E-11 -11.7729 0.14097E-11 -11.8509 0.83574E+00 -0.0779 39 CaOH+ 0.37755E-07 -7.4230 0.31553E-07 -7.5010 0.83574E+00 -0.0779 40 CaSO4,aq 0.11846E-09 -9.9264 0.11846E-09 -9.9264 0.10000E+01 0.0000 41 HCl,aq 0.25272E-14 -14.5974 0.25272E-14 -14.5974 0.10000E+01 0.0000 45 HF,aq 0.14929E-11 -11.8260 0.14929E-11 -11.8260 0.10000E+01 0.0000 46 HF2- 0.15720E-17 -17.8036 0.13112E-17 -17.8823 0.83412E+00 -0.0788 48 FeCl+ 0.64599E-17 -17.1898 0.53988E-17 -17.2677 0.83574E+00 -0.0779 51 FeF+ 0.32980E-17 -17.4818 0.27563E-17 -17.5597 0.83574E+00 -0.0779 53 FeO,aq 0.11465E-09 -9.9406 0.11465E-09 -9.9406 0.10000E+01 0.0000 54 FeOH+ 0.96329E-11 -11.0162 0.80505E-11 -11.0942 0.83574E+00 -0.0779 55 HFeO2- 0.17155E-07 -7.7656 0.14309E-07 -7.8444 0.83412E+00 -0.0788 56 FeO+ 0.45788E-16 -16.3392 0.38267E-16 -16.4172 0.83574E+00 -0.0779 58 FeO2- 0.13356E-08 -8.8743 0.11140E-08 -8.9531 0.83412E+00 -0.0788 59 HFeO2,aq 0.11879E-10 -10.9252 0.11879E-10 -10.9252 0.10000E+01 0.0000 60 H2,aq 0.25270E-06 -6.5974 0.25180E-06 -6.5989 0.99641E+00 -0.0016 61 KCl,aq 0.38999E-09 -9.4089 0.38999E-09 -9.4089 0.10000E+01 0.0000 62 KHSO4,aq 0.31163E-18 -18.5064 0.31163E-18 -18.5064 0.10000E+01 0.0000 63 KOH,aq 0.66631E-06 -6.1763 0.66631E-06 -6.1763 0.10000E+01 0.0000 64 KSO4- 0.24458E-07 -7.6116 0.20401E-07 -7.6904 0.83412E+00 -0.0788 65 MgCO3,aq 0.62876E-11 -11.2015 0.62876E-11 -11.2015 0.10000E+01 0.0000 66 Mg(HCO3)+ 0.59928E-13 -13.2224 0.50084E-13 -13.3003 0.83574E+00 -0.0779 67 MgCl+ 0.31799E-14 -14.4976 0.26575E-14 -14.5755 0.83574E+00 -0.0779 68 MgF+ 0.18541E-14 -14.7319 0.15496E-14 -14.8098 0.83574E+00 -0.0779 69 MgOH+ 0.61994E-10 -10.2076 0.51811E-10 -10.2856 0.83574E+00 -0.0779 71 MnF+ 0.62855E-15 -15.2017 0.52531E-15 -15.2796 0.83574E+00 -0.0779 72 MnO,aq 0.17665E-08 -8.7529 0.17665E-08 -8.7529 0.10000E+01 0.0000 73 MnOH+ 0.51743E-09 -9.2862 0.43243E-09 -9.3641 0.83574E+00 -0.0779 74 MnO2-2 0.16179E-10 -10.7911 0.83408E-11 -11.0788 0.51555E+00 -0.2877 75 HMnO2- 0.18367E-09 -9.7360 0.15320E-09 -9.8147 0.83412E+00 -0.0788 78 MnCl+ 0.14532E-13 -13.8377 0.12145E-13 -13.9156 0.83574E+00 -0.0779 79 MnSO4,aq 0.34787E-13 -13.4586 0.34787E-13 -13.4586 0.10000E+01 0.0000 80 NaCl,aq 0.90408E-06 -6.0438 0.90408E-06 -6.0438 0.10000E+01 0.0000 81 NaF,aq 0.10100E-07 -7.9957 0.10100E-07 -7.9957 0.10000E+01 0.0000 82 NaOH,aq 0.84988E-04 -4.0706 0.84988E-04 -4.0706 0.10000E+01 0.0000 84 OH- 0.82774E-02 -2.0821 0.68916E-02 -2.1617 0.83259E+00 -0.0796 89 HPO3-2 0.35722E-16 -16.4471 0.18416E-16 -16.7348 0.51555E+00 -0.2877 92 H3PO4,aq 0.11537E-17 -17.9379 0.11537E-17 -17.9379 0.10000E+01 0.0000 93 H2PO4- 0.43475E-10 -10.3618 0.36298E-10 -10.4401 0.83492E+00 -0.0784 94 PO4-3 0.95167E-09 -9.0215 0.22841E-09 -9.6413 0.24001E+00 -0.6198 98 HP2O7-3 0.10765E-17 -17.9680 0.24605E-18 -18.6090 0.22857E+00 -0.6410 99 P2O7-4 0.92801E-17 -17.0324 0.70112E-18 -18.1542 0.75551E-01 -1.1218 100 H2S,aq 0.41778E-07 -7.3791 0.41628E-07 -7.3806 0.99641E+00 -0.0016 101 S2-2 0.44057E-11 -11.3560 0.22713E-11 -11.6437 0.51555E+00 -0.2877 102 S3-2 0.98129E-18 -18.0082 0.50590E-18 -18.2959 0.51555E+00 -0.2877 107 SO3-2 0.62866E-12 -12.2016 0.32887E-12 -12.4830 0.52312E+00 -0.2814 108 HSO3- 0.20696E-14 -14.6841 0.17263E-14 -14.7629 0.83412E+00 -0.0788 109 HSO4- 0.97069E-12 -12.0129 0.81204E-12 -12.0904 0.83656E+00 -0.0775 111 S2O3-2 0.95330E-14 -14.0208 0.49147E-14 -14.3085 0.51555E+00 -0.2877 Charge balance for all species = -.6132E-08 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.9989650E-10 -.2147679E-01 -.2160915E+02 0.0000 2 H2O 0.1000000E+01 0.5550387E+02 0.9981563E+06 0.0000 3 Cl- 0.1972150E-03 0.1981195E-03 0.7011549E+01 6.2927 4 SO4-- 0.1945305E-04 0.1941190E-04 0.1861451E+01 15.1553 5 HCO3- 0.2086971E-03 0.5611259E-03 0.3417797E+02 6.3180 6 HS- 0.1925799E-03 0.1926874E-03 0.6361325E+01 6.2825 7 Al+++ 0.1135588E-28 0.3780863E-05 0.1018335E+00 0.6435 8 H4SiO4 0.7800643E-03 0.1352622E-01 0.1297786E+04 -3.1079 9 Ca++ 0.7238022E-07 0.2037858E-06 0.8152930E-02 12.7227 10 Mg++ 0.2157849E-10 0.9317076E-10 0.2261174E-05 9.1951 11 Fe++ 0.4057692E-13 0.1862670E-07 0.1038411E-02 6.4698 12 K+ 0.1565499E-03 0.1572411E-03 0.6137603E+01 6.1932 13 Na+ 0.1988554E-01 0.2230173E-01 0.5118086E+03 8.2962 14 Mn++ 0.2344268E-10 0.2507250E-08 0.1375005E-03 9.2319 15 F- 0.3125157E-05 0.3135260E-05 0.5945868E-01 4.4918 16 HPO4-- 0.4541939E-07 0.4641453E-07 0.4446968E-02 12.5236 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.1929543E-01 -.1928983E-01 -.5596965E-05 0.0000000E+00 2 H2O 0.4985197E+02 0.4985197E+02 -.5522545E-05 0.0000000E+00 3 Cl- 0.1779452E-03 0.1779452E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.1743719E-04 0.1743521E-04 0.1982789E-08 0.0000000E+00 5 HCO3- 0.5039870E-03 0.5039870E-03 0.0000000E+00 0.0000000E+00 6 HS- 0.1730643E-03 0.1730663E-03 -.1982789E-08 0.0000000E+00 7 Al+++ 0.4775352E-05 0.3395862E-05 0.1379490E-05 0.0000000E+00 8 H4SiO4 0.1215302E-01 0.1214886E-01 0.4161009E-05 0.0000000E+00 9 Ca++ 0.2080835E-06 0.1830345E-06 0.2504898E-07 0.0000000E+00 10 Mg++ 0.8368328E-10 0.8368328E-10 0.0000000E+00 0.0000000E+00 11 Fe++ 0.3259227E-07 0.1672996E-07 0.1586231E-07 0.0000000E+00 12 K+ 0.1412294E-03 0.1412294E-03 0.0000000E+00 0.0000000E+00 13 Na+ 0.2003215E-01 0.2003077E-01 0.1378653E-05 0.0000000E+00 14 Mn++ 0.2251939E-08 0.2251939E-08 0.0000000E+00 0.0000000E+00 15 F- 0.2816000E-05 0.2816000E-05 0.0000000E+00 0.0000000E+00 16 HPO4-- 0.4168819E-07 0.4168819E-07 0.0000000E+00 0.0000000E+00 Chg. balance for solid moles: 0.2118E-21 Mass of aqueous solution: 0.899757E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 0.0067900 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 0.1379E-05 -5.861 0.3615E-03 -3.442 98.85 0.1388E-03 andradite 0.7931E-08 -8.101 0.4030E-05 -5.395 1.102 0.1047E-05 grossular 0.4185E-09 -9.378 0.1885E-06 -6.725 0.5155E-01 0.5245E-07 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.9499E+00 0.9499E+00 1.0000 -0.022 grossular 0.5012E-01 0.5012E-01 1.0000 -1.300 Solid products produced: Mass = 0.000366 g Volume = 0.000140 cm3 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.0067900 moles log = -2.1681 Original solution: 1000.0103000 g Original solution / Rock added: 147276.92 (Water/Rock Ratio), log = 5.1681 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0206 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9997E+00 0.9859 0.1006E+01 0.1020E+01 CO2,gas 0.3251E-05 1.0071 0.3341E-05 0.3318E-05 CH4,gas 0.3856E-05 1.0125 0.3984E-05 0.3935E-05 H2,gas 0.3237E-03 1.0005 0.3306E-03 0.3304E-03 H2S,gas 0.1126E-05 0.9960 0.1144E-05 0.1149E-05 S2,gas 0.4407E-24 1.0000 0.4498E-24 0.4498E-24 CO,gas 0.2884E-12 1.0000 0.2944E-12 0.2944E-12 SO3,gas 0.2617E-40 1.0000 0.2671E-40 0.2671E-40 SO2,gas 0.3366E-21 1.0000 0.3435E-21 0.3435E-21 HF,gas 0.3592E-14 1.0000 0.3666E-14 0.3666E-14 HCl,gas 0.4369E-17 1.0000 0.4459E-17 0.4459E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 17 albite -0.38 -0.38 0.00 0.000 -0.94784E-12 23 andradite 39.01 39.01 0.00 0.000 -0.12132E-10 24 grossular 32.73 32.73 0.00 0.000 -0.24265E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -13.84 -7.18 -2.392 0.12251E+05 -5.476 3 CH4,gas 4.54 -2.55 -7.10 -1.775 0.12121E+05 -5.400 4 H2,gas 8.00 2.82 -5.18 -2.960 0.88442E+04 -3.481 5 H2S,gas -6.23 -13.87 -7.64 -3.820 0.13046E+05 -5.941 6 S2,gas -7.34 -33.38 -26.05 -4.007 0.44473E+05 -24.347 7 CO,gas 3.21 -11.02 -14.23 -4.378 0.24297E+05 -12.531 8 SO3,gas 17.12 -25.15 -42.27 -10.568 0.72179E+05 -40.573 9 SO2,gas 0.83 -22.33 -23.16 -6.177 0.39550E+05 -21.464 10 HF,gas 0.47 -15.66 -16.13 -8.067 0.27550E+05 -14.436 11 HCl,gas 5.19 -13.86 -19.05 -9.525 0.32527E+05 -17.351 12 acmite 7.71 7.14 -0.57 -0.059 0.97226E+03 16 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 20 spessartine 24.46 19.66 -4.80 -0.240 0.81928E+04 21 analcite 3.32 2.72 -0.60 -0.066 0.10208E+04 27 annite 20.12 16.92 -3.20 -0.178 0.54654E+04 28 phlogopite 27.06 25.10 -1.97 -0.109 0.33573E+04 30 anorthite 12.71 7.79 -4.92 -0.378 0.83946E+04 33 apatite-OH -18.15 -19.73 -1.58 -0.122 0.26992E+04 34 apatite-F -34.30 -35.40 -1.09 -0.091 0.18692E+04 38 aragonite 0.97 -1.11 -2.08 -0.693 0.35498E+04 39 brucite 12.57 9.20 -3.37 -0.675 0.57601E+04 40 calcite 0.81 -1.11 -1.92 -0.641 0.32856E+04 41 carnegieite-low 9.02 5.83 -3.19 -0.456 0.54493E+04 42 carnegieite-high 10.09 5.83 -4.26 -0.609 0.72763E+04 43 carpholite-Mg 8.58 4.27 -4.32 -0.288 0.73690E+04 45 celadonite 5.34 3.60 -1.74 -0.102 0.29732E+04 46 celadonite-Fe 3.88 0.88 -3.00 -0.177 0.51250E+04 47 chrysotile 23.89 21.37 -2.52 -0.210 0.43078E+04 49 clinochlore 39.07 37.94 -1.13 -0.035 0.19307E+04 50 daphnite 28.97 24.31 -4.65 -0.145 0.79444E+04 52 chlorite-Al-free 47.17 42.74 -4.43 -0.185 0.75707E+04 54 chloritoid-Fe 9.17 4.65 -4.52 -0.302 0.77258E+04 55 chloritoid-Mn 11.40 7.41 -3.99 -0.266 0.68129E+04 57 coesite -2.38 -3.11 -0.73 -0.244 0.12495E+04 64 cristobalite -2.56 -3.11 -0.55 -0.183 0.93489E+03 66 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71241E+04 68 diaspore 2.87 0.64 -2.23 -0.372 0.38080E+04 70 diopside 16.18 15.70 -0.48 -0.048 0.81841E+03 71 hedenbergite 14.21 12.98 -1.23 -0.123 0.21027E+04 76 clinoenstatite 17.17 12.17 -4.99 -0.499 0.85234E+04 78 epidote 24.67 22.47 -2.20 -0.107 0.37587E+04 79 clinozoisite 22.81 18.05 -4.75 -0.216 0.81169E+04 80 epidote-Fe 29.84 26.88 -2.96 -0.154 0.50472E+04 81 fayalite 14.05 9.83 -4.21 -0.602 0.71952E+04 82 ferrosilite 11.15 6.72 -4.43 -0.443 0.75565E+04 86 gibbsite 4.08 0.64 -3.44 -0.491 0.58666E+04 87 glaucophane 22.97 20.60 -2.37 -0.064 0.40519E+04 88 glaucophane-Fe 17.28 12.43 -4.85 -0.131 0.82809E+04 89 graphite -3.55 -8.20 -4.65 -1.328 0.79378E+04 90 greenalite 16.14 13.19 -2.95 -0.245 0.50298E+04 93 hematite 12.57 10.12 -2.45 -0.297 0.41775E+04 94 heulandite -5.83 -7.75 -1.92 -0.087 0.32752E+04 98 jadeite 4.22 2.72 -1.49 -0.149 0.25463E+04 100 kalsilite 7.58 3.73 -3.86 -0.551 0.65825E+04 101 kaolinite -1.33 -4.93 -3.60 -0.327 0.61400E+04 104 laumontite 2.88 1.58 -1.31 -0.087 0.22286E+04 105 lawsonite 9.62 7.79 -1.82 -0.121 0.31112E+04 106 leucite 4.12 0.62 -3.50 -0.350 0.59726E+04 108 lizardite 23.24 21.37 -1.87 -0.156 0.32004E+04 110 magnetite 20.09 16.59 -3.50 -0.286 0.59727E+04 111 minnesotaite 10.39 6.98 -3.41 -0.201 0.58227E+04 115 manganosite 14.06 9.23 -4.83 -1.207 0.82406E+04 119 microcline -2.49 -2.49 0.00 0.000 0.72954E+00 123 muscovite 2.58 -1.20 -3.78 -0.222 0.64583E+04 124 paragonite 4.24 0.90 -3.34 -0.196 0.56967E+04 125 nepheline 8.34 5.83 -2.51 -0.358 0.42816E+04 137 phlogopite-Na 29.65 27.20 -2.45 -0.136 0.41754E+04 139 prehnite 19.37 17.41 -1.96 -0.115 0.33519E+04 140 prehnite-Fe 22.50 21.83 -0.67 -0.040 0.11488E+04 141 pumpellyite-Fe 46.27 41.93 -4.34 -0.096 0.74079E+04 142 pumpellyite-Mg 48.99 44.66 -4.34 -0.096 0.74082E+04 145 pyrite -21.25 -24.09 -2.84 -0.669 0.48571E+04 146 pyrrhotite -4.26 -7.40 -3.14 -1.047 0.53623E+04 147 pyrrhotiteFe0.875 -6.02 -8.56 -2.54 -0.935 0.43409E+04 148 pyroxmangite 7.40 6.12 -1.27 -0.255 0.21764E+04 149 pyrophyllite -6.18 -11.14 -4.97 -0.311 0.84839E+04 150 quartz -2.99 -3.11 -0.12 -0.039 0.20222E+03 154 rhodochrosite -0.98 -4.60 -3.63 -1.209 0.61929E+04 155 rhodonite 7.45 6.12 -1.32 -0.264 0.22566E+04 156 sanidine -1.28 -2.49 -1.21 -0.093 0.20685E+04 158 siderite -2.61 -7.37 -4.76 -1.586 0.81228E+04 166 stilbite -7.52 -7.75 -0.22 -0.011 0.38135E+03 167 stilpnomelane-Fe 13.02 11.87 -1.15 -0.034 0.19588E+04 168 stilpnomelane-Mg 27.44 25.50 -1.95 -0.058 0.33216E+04 174 talc 16.49 15.15 -1.34 -0.079 0.22834E+04 177 tephroite 18.09 15.36 -2.73 -0.390 0.46611E+04 181 tridymite -2.63 -3.11 -0.48 -0.161 0.82220E+03 182 tremolite 47.87 46.56 -1.31 -0.035 0.22392E+04 184 troilite-low -4.41 -7.40 -2.99 -0.997 0.51052E+04 190 wairakite 3.95 1.58 -2.37 -0.140 0.40505E+04 191 walstromite 11.51 9.61 -1.89 -0.379 0.32346E+04 192 wollastonite 10.46 9.61 -0.85 -0.169 0.14451E+04 193 pseudo-wollastonite 11.00 9.61 -1.39 -0.277 0.23649E+04 194 zoisite 22.85 18.05 -4.80 -0.218 0.81909E+04 195 akaganeite 7.75 5.06 -2.69 -0.583 0.46013E+04 202 chalcedony -2.80 -3.11 -0.31 -0.102 0.52152E+03 204 montmorillonite-Ca -2.29 -6.22 -3.93 -0.243 0.67146E+04 205 montmorillonite-K -2.24 -6.28 -4.04 -0.248 0.69016E+04 206 montmorillonite-Mg -2.48 -6.81 -4.33 -0.268 0.73855E+04 207 montmorillonite-Na -2.04 -5.58 -3.55 -0.217 0.60562E+04 208 nontronite-Ca 3.21 1.03 -2.19 -0.142 0.37381E+04 209 nontronite-H 2.53 -1.07 -3.61 -0.242 0.61582E+04 210 nontronite-K 3.34 0.97 -2.37 -0.152 0.40482E+04 211 nontronite-Mg 3.07 0.44 -2.63 -0.171 0.44930E+04 212 nontronite-Na 3.52 1.66 -1.86 -0.119 0.31689E+04 228 tobermorite 9.82 7.49 -2.33 -0.637 0.39834E+04 234 alabandite -0.98 -4.64 -3.66 -1.220 0.62508E+04 237 boehmite 4.41 0.64 -3.76 -0.627 0.64249E+04 239 ferrous-oxide 9.81 6.47 -3.34 -0.835 0.57060E+04 245 silica-amorphous -2.09 -3.11 -1.02 -0.339 0.17357E+04 247 an20ab80 2.02 1.25 -0.77 -0.059 0.13081E+04 248 an25ab75 2.65 1.66 -0.99 -0.076 0.16820E+04 249 an30ab70 3.28 2.07 -1.21 -0.093 0.20656E+04 250 tr.625ac.25prg.125 45.16 44.06 -1.11 -0.030 0.18911E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 0.0002000 MOLES Current total amount of reactant added: 0.0067900 MOLES New total amount of reactant added: 0.0069900 MOLES Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.5508E-08 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 7 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 0.0069900 Water: Moles liquid = 0.4986E+02 kg liquid = 0.8982E+00 Moles total = 0.4985E+02 kg total = 0.8981E+00 Activity = 1.0000 Stoichiometric ionic strength = .1177715E-01 Osmotic coef. = 0.9514 True ionic strength = .2042562E-01 Chg. balance for total moles = -.5508E-08 Max. difference allowed = 0.1791E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.10027E-09 -9.9988 0.84150E-10 -10.0749 0.83921E+00 -0.0761 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.19852E-03 -3.7022 0.16558E-03 -3.7810 0.83408E+00 -0.0788 4 SO4-- 0.20514E-04 -4.6879 0.10597E-04 -4.9748 0.51659E+00 -0.2869 5 HCO3- 0.21517E-03 -3.6672 0.17974E-03 -3.7454 0.83532E+00 -0.0781 6 HS- 0.19693E-03 -3.7057 0.16428E-03 -3.7844 0.83421E+00 -0.0787 7 Al+++ 0.11411E-28 -28.9427 0.26047E-29 -29.5842 0.22826E+00 -0.6416 8 H4SiO4 0.78278E-03 -3.1064 0.78278E-03 -3.1064 0.10000E+01 0.0000 9 Ca++ 0.71769E-07 -7.1441 0.36798E-07 -7.4342 0.51273E+00 -0.2901 10 Mg++ 0.21594E-10 -10.6657 0.11020E-10 -10.9578 0.51035E+00 -0.2921 11 Fe++ 0.41544E-13 -13.3815 0.21225E-13 -13.6731 0.51092E+00 -0.2916 12 K+ 0.15655E-03 -3.8053 0.13080E-03 -3.8834 0.83552E+00 -0.0780 13 Na+ 0.19886E-01 -1.7014 0.16584E-01 -1.7803 0.83393E+00 -0.0789 14 Mn++ 0.23609E-10 -10.6269 0.12072E-10 -10.9182 0.51135E+00 -0.2913 15 F- 0.32139E-05 -5.4930 0.26751E-05 -5.5727 0.83234E+00 -0.0797 16 HPO4-- 0.45422E-07 -7.3427 0.23468E-07 -7.6295 0.51666E+00 -0.2868 18 HSiO3- 0.10414E-01 -1.9824 0.86858E-02 -2.0612 0.83408E+00 -0.0788 19 Ca(HSiO3)+ 0.87100E-08 -8.0600 0.72790E-08 -8.1379 0.83571E+00 -0.0779 20 Mg(HSiO3)+ 0.32463E-11 -11.4886 0.27130E-11 -11.5666 0.83571E+00 -0.0779 21 NaHSiO3,aq 0.23297E-02 -2.6327 0.23297E-02 -2.6327 0.10000E+01 0.0000 22 AlO+ 0.59878E-16 -16.2227 0.50040E-16 -16.3007 0.83571E+00 -0.0779 24 HAlO2,aq 0.11842E-09 -9.9266 0.11842E-09 -9.9266 0.10000E+01 0.0000 25 AlO2- 0.37417E-05 -5.4269 0.31152E-05 -5.5065 0.83255E+00 -0.0796 26 CH4,aq 0.27162E-08 -8.5660 0.27065E-08 -8.5676 0.99641E+00 -0.0016 31 CO,aq 0.20267E-15 -15.6932 0.20267E-15 -15.6932 0.10000E+01 0.0000 32 CO2,aq 0.32435E-07 -7.4890 0.32319E-07 -7.4905 0.99641E+00 -0.0016 33 CO3-2 0.36193E-03 -3.4414 0.18656E-03 -3.7292 0.51547E+00 -0.2878 34 CaCO3,aq 0.86083E-07 -7.0651 0.86083E-07 -7.0651 0.10000E+01 0.0000 35 Ca(HCO3)+ 0.20202E-09 -9.6946 0.16883E-09 -9.7725 0.83571E+00 -0.0779 36 CaCl+ 0.11799E-10 -10.9281 0.98608E-11 -11.0061 0.83571E+00 -0.0779 37 CaCl2,aq 0.38792E-15 -15.4113 0.38792E-15 -15.4113 0.10000E+01 0.0000 38 CaF+ 0.17198E-11 -11.7645 0.14372E-11 -11.8425 0.83571E+00 -0.0779 39 CaOH+ 0.37293E-07 -7.4284 0.31166E-07 -7.5063 0.83571E+00 -0.0779 40 CaSO4,aq 0.12383E-09 -9.9072 0.12383E-09 -9.9072 0.10000E+01 0.0000 41 HCl,aq 0.25533E-14 -14.5929 0.25533E-14 -14.5929 0.10000E+01 0.0000 45 HF,aq 0.15410E-11 -11.8122 0.15410E-11 -11.8122 0.10000E+01 0.0000 46 HF2- 0.16687E-17 -17.7776 0.13918E-17 -17.8564 0.83408E+00 -0.0788 48 FeCl+ 0.66567E-17 -17.1767 0.55630E-17 -17.2547 0.83571E+00 -0.0779 51 FeF+ 0.34720E-17 -17.4594 0.29015E-17 -17.5374 0.83571E+00 -0.0779 53 FeO,aq 0.11650E-09 -9.9337 0.11650E-09 -9.9337 0.10000E+01 0.0000 54 FeOH+ 0.98246E-11 -11.0077 0.82105E-11 -11.0856 0.83571E+00 -0.0779 55 HFeO2- 0.17366E-07 -7.7603 0.14485E-07 -7.8391 0.83408E+00 -0.0788 56 FeO+ 0.46901E-16 -16.3288 0.39196E-16 -16.4068 0.83571E+00 -0.0779 58 FeO2- 0.13579E-08 -8.8671 0.11326E-08 -8.9459 0.83408E+00 -0.0788 59 HFeO2,aq 0.12122E-10 -10.9164 0.12122E-10 -10.9164 0.10000E+01 0.0000 60 H2,aq 0.25054E-06 -6.6011 0.24964E-06 -6.6027 0.99641E+00 -0.0016 61 KCl,aq 0.39255E-09 -9.4061 0.39255E-09 -9.4061 0.10000E+01 0.0000 62 KHSO4,aq 0.32980E-18 -18.4817 0.32980E-18 -18.4817 0.10000E+01 0.0000 63 KOH,aq 0.66381E-06 -6.1780 0.66381E-06 -6.1780 0.10000E+01 0.0000 64 KSO4- 0.25789E-07 -7.5886 0.21510E-07 -7.6674 0.83408E+00 -0.0788 65 MgCO3,aq 0.64620E-11 -11.1896 0.64620E-11 -11.1896 0.10000E+01 0.0000 66 Mg(HCO3)+ 0.61822E-13 -13.2089 0.51665E-13 -13.2868 0.83571E+00 -0.0779 67 MgCl+ 0.32027E-14 -14.4945 0.26766E-14 -14.5724 0.83571E+00 -0.0779 68 MgF+ 0.19079E-14 -14.7195 0.15944E-14 -14.7974 0.83571E+00 -0.0779 69 MgOH+ 0.61801E-10 -10.2090 0.51648E-10 -10.2869 0.83571E+00 -0.0779 71 MnF+ 0.65089E-15 -15.1865 0.54396E-15 -15.2644 0.83571E+00 -0.0779 72 MnO,aq 0.17655E-08 -8.7531 0.17655E-08 -8.7531 0.10000E+01 0.0000 73 MnOH+ 0.51910E-09 -9.2848 0.43381E-09 -9.3627 0.83571E+00 -0.0779 74 MnO2-2 0.16052E-10 -10.7945 0.82744E-11 -11.0823 0.51547E+00 -0.2878 75 HMnO2- 0.18289E-09 -9.7378 0.15255E-09 -9.8166 0.83408E+00 -0.0788 78 MnCl+ 0.14730E-13 -13.8318 0.12310E-13 -13.9098 0.83571E+00 -0.0779 79 MnSO4,aq 0.36934E-13 -13.4326 0.36934E-13 -13.4326 0.10000E+01 0.0000 80 NaCl,aq 0.91003E-06 -6.0409 0.91003E-06 -6.0409 0.10000E+01 0.0000 81 NaF,aq 0.10386E-07 -7.9835 0.10386E-07 -7.9835 0.10000E+01 0.0000 82 NaOH,aq 0.84672E-04 -4.0723 0.84672E-04 -4.0723 0.10000E+01 0.0000 84 OH- 0.82469E-02 -2.0837 0.68660E-02 -2.1633 0.83255E+00 -0.0796 89 HPO3-2 0.35418E-16 -16.4508 0.18257E-16 -16.7386 0.51547E+00 -0.2878 92 H3PO4,aq 0.11623E-17 -17.9347 0.11623E-17 -17.9347 0.10000E+01 0.0000 93 H2PO4- 0.43635E-10 -10.3602 0.36430E-10 -10.4385 0.83489E+00 -0.0784 94 PO4-3 0.94835E-09 -9.0230 0.22754E-09 -9.6429 0.23993E+00 -0.6199 98 HP2O7-3 0.10807E-17 -17.9663 0.24693E-18 -18.6074 0.22850E+00 -0.6411 99 P2O7-4 0.92841E-17 -17.0323 0.70101E-18 -18.1543 0.75507E-01 -1.1220 100 H2S,aq 0.42879E-07 -7.3678 0.42725E-07 -7.3693 0.99641E+00 -0.0016 101 S2-2 0.46470E-11 -11.3328 0.23954E-11 -11.6206 0.51547E+00 -0.2878 102 S3-2 0.10715E-17 -17.9700 0.55232E-18 -18.2578 0.51547E+00 -0.2878 107 SO3-2 0.65728E-12 -12.1823 0.34379E-12 -12.4637 0.52305E+00 -0.2815 108 HSO3- 0.21717E-14 -14.6632 0.18114E-14 -14.7420 0.83408E+00 -0.0788 109 HSO4- 0.10274E-11 -11.9883 0.85942E-12 -12.0658 0.83653E+00 -0.0775 111 S2O3-2 0.10318E-13 -13.9864 0.53186E-14 -14.2742 0.51547E+00 -0.2878 Charge balance for all species = -.6132E-08 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.1002730E-09 -.2145258E-01 -.2158478E+02 0.0000 2 H2O 0.1000000E+01 0.5550385E+02 0.9981550E+06 0.0000 3 Cl- 0.1985221E-03 0.1994325E-03 0.7058012E+01 6.2940 4 SO4-- 0.2051439E-04 0.2047512E-04 0.1963404E+01 15.1751 5 HCO3- 0.2151721E-03 0.5772231E-03 0.3515842E+02 6.3296 6 HS- 0.1969263E-03 0.1970344E-03 0.6504829E+01 6.2905 7 Al+++ 0.1141089E-28 0.3741843E-05 0.1007825E+00 0.6406 8 H4SiO4 0.7827759E-03 0.1352605E-01 0.1297769E+04 -3.1064 9 Ca++ 0.7176932E-07 0.2041947E-06 0.8169281E-02 12.7157 10 Mg++ 0.2159401E-10 0.9317041E-10 0.2261164E-05 9.1921 11 Fe++ 0.4154386E-13 0.1886280E-07 0.1051573E-02 6.4767 12 K+ 0.1565505E-03 0.1572405E-03 0.6137575E+01 6.1916 13 Na+ 0.1988632E-01 0.2230161E-01 0.5118053E+03 8.2946 14 Mn++ 0.2360895E-10 0.2507240E-08 0.1374998E-03 9.2317 15 F- 0.3213929E-05 0.3224318E-05 0.6114756E-01 4.5023 16 HPO4-- 0.4542237E-07 0.4641436E-07 0.4446947E-02 12.5204 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.1927389E-01 -.1926816E-01 -.5735998E-05 0.0000000E+00 2 H2O 0.4985213E+02 0.4985214E+02 -.5662705E-05 0.0000000E+00 3 Cl- 0.1791252E-03 0.1791252E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.1839219E-04 0.1839023E-04 0.1956273E-08 0.0000000E+00 5 HCO3- 0.5184470E-03 0.5184470E-03 0.0000000E+00 0.0000000E+00 6 HS- 0.1769693E-03 0.1769712E-03 -.1956273E-08 0.0000000E+00 7 Al+++ 0.4775352E-05 0.3360828E-05 0.1414524E-05 0.0000000E+00 8 H4SiO4 0.1215302E-01 0.1214875E-01 0.4265841E-05 0.0000000E+00 9 Ca++ 0.2080835E-06 0.1834024E-06 0.2468108E-07 0.0000000E+00 10 Mg++ 0.8368328E-10 0.8368328E-10 0.0000000E+00 0.0000000E+00 11 Fe++ 0.3259227E-07 0.1694209E-07 0.1565018E-07 0.0000000E+00 12 K+ 0.1412294E-03 0.1412294E-03 0.0000000E+00 0.0000000E+00 13 Na+ 0.2003215E-01 0.2003074E-01 0.1413720E-05 0.0000000E+00 14 Mn++ 0.2251939E-08 0.2251939E-08 0.0000000E+00 0.0000000E+00 15 F- 0.2896000E-05 0.2896000E-05 0.0000000E+00 0.0000000E+00 16 HPO4-- 0.4168819E-07 0.4168819E-07 0.0000000E+00 0.0000000E+00 Chg. balance for solid moles: 0.0000E+00 Mass of aqueous solution: 0.899761E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 0.0069900 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 0.1414E-05 -5.850 0.3707E-03 -3.431 98.89 0.1423E-03 andradite 0.7825E-08 -8.107 0.3977E-05 -5.400 1.061 0.1033E-05 grossular 0.4019E-09 -9.396 0.1811E-06 -6.742 0.4830E-01 0.5038E-07 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.9511E+00 0.9511E+00 1.0000 -0.022 grossular 0.4886E-01 0.4886E-01 1.0000 -1.311 Solid products produced: Mass = 0.000375 g Volume = 0.000143 cm3 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.0069900 moles log = -2.1555 Original solution: 1000.0103000 g Original solution / Rock added: 143062.99 (Water/Rock Ratio), log = 5.1555 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0206 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9997E+00 0.9859 0.1006E+01 0.1020E+01 CO2,gas 0.3364E-05 1.0071 0.3458E-05 0.3433E-05 CH4,gas 0.3855E-05 1.0125 0.3984E-05 0.3934E-05 H2,gas 0.3209E-03 1.0005 0.3277E-03 0.3276E-03 H2S,gas 0.1155E-05 0.9960 0.1174E-05 0.1179E-05 S2,gas 0.4723E-24 1.0000 0.4820E-24 0.4820E-24 CO,gas 0.2959E-12 1.0000 0.3020E-12 0.3020E-12 SO3,gas 0.2780E-40 1.0000 0.2837E-40 0.2837E-40 SO2,gas 0.3545E-21 1.0000 0.3618E-21 0.3618E-21 HF,gas 0.3707E-14 1.0000 0.3784E-14 0.3784E-14 HCl,gas 0.4414E-17 1.0000 0.4505E-17 0.4505E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 17 albite -0.38 -0.38 0.00 0.000 -0.94784E-12 23 andradite 39.01 39.01 0.00 0.000 0.00000E+00 24 grossular 32.73 32.73 0.00 0.000 -0.12132E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -13.82 -7.16 -2.387 0.12226E+05 -5.461 3 CH4,gas 4.54 -2.55 -7.10 -1.775 0.12121E+05 -5.400 4 H2,gas 8.00 2.82 -5.18 -2.962 0.88506E+04 -3.484 5 H2S,gas -6.23 -13.86 -7.63 -3.815 0.13027E+05 -5.930 6 S2,gas -7.34 -33.35 -26.02 -4.002 0.44421E+05 -24.317 7 CO,gas 3.21 -11.00 -14.22 -4.375 0.24278E+05 -12.520 8 SO3,gas 17.12 -25.12 -42.25 -10.562 0.72134E+05 -40.547 9 SO2,gas 0.83 -22.31 -23.14 -6.171 0.39512E+05 -21.442 10 HF,gas 0.47 -15.65 -16.12 -8.061 0.27526E+05 -14.422 11 HCl,gas 5.19 -13.86 -19.05 -9.523 0.32519E+05 -17.346 12 acmite 7.71 7.15 -0.56 -0.058 0.95486E+03 16 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 20 spessartine 24.46 19.66 -4.80 -0.240 0.81962E+04 21 analcite 3.32 2.72 -0.60 -0.067 0.10234E+04 27 annite 20.12 16.94 -3.18 -0.177 0.54299E+04 28 phlogopite 27.06 25.09 -1.98 -0.110 0.33727E+04 30 anorthite 12.71 7.78 -4.93 -0.379 0.84112E+04 33 apatite-OH -18.15 -19.76 -1.61 -0.124 0.27425E+04 34 apatite-F -34.30 -35.41 -1.11 -0.092 0.18889E+04 38 aragonite 0.97 -1.10 -2.07 -0.690 0.35364E+04 39 brucite 12.57 9.19 -3.38 -0.675 0.57652E+04 40 calcite 0.81 -1.10 -1.92 -0.639 0.32721E+04 41 carnegieite-low 9.02 5.83 -3.19 -0.456 0.54544E+04 42 carnegieite-high 10.09 5.83 -4.26 -0.609 0.72814E+04 43 carpholite-Mg 8.58 4.26 -4.32 -0.288 0.73789E+04 45 celadonite 5.34 3.60 -1.74 -0.103 0.29758E+04 46 celadonite-Fe 3.88 0.88 -2.99 -0.176 0.51106E+04 47 chrysotile 23.89 21.36 -2.53 -0.211 0.43179E+04 49 clinochlore 39.07 37.92 -1.15 -0.036 0.19584E+04 50 daphnite 28.97 24.35 -4.62 -0.144 0.78875E+04 52 chlorite-Al-free 47.17 42.73 -4.45 -0.185 0.75910E+04 54 chloritoid-Fe 9.17 4.65 -4.52 -0.301 0.77213E+04 55 chloritoid-Mn 11.40 7.41 -3.99 -0.266 0.68206E+04 57 coesite -2.38 -3.11 -0.73 -0.243 0.12470E+04 64 cristobalite -2.56 -3.11 -0.55 -0.182 0.93232E+03 66 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71241E+04 68 diaspore 2.87 0.64 -2.23 -0.372 0.38130E+04 70 diopside 16.18 15.70 -0.49 -0.049 0.83029E+03 71 hedenbergite 14.21 12.98 -1.23 -0.123 0.20977E+04 76 clinoenstatite 17.17 12.17 -4.99 -0.499 0.85285E+04 78 epidote 24.67 22.46 -2.21 -0.107 0.37697E+04 79 clinozoisite 22.81 18.03 -4.77 -0.217 0.81479E+04 80 epidote-Fe 29.84 26.89 -2.95 -0.153 0.50382E+04 81 fayalite 14.05 9.85 -4.20 -0.600 0.71690E+04 82 ferrosilite 11.15 6.74 -4.41 -0.441 0.75277E+04 86 gibbsite 4.08 0.64 -3.44 -0.491 0.58715E+04 87 glaucophane 22.97 20.60 -2.38 -0.064 0.40621E+04 88 glaucophane-Fe 17.28 12.45 -4.83 -0.130 0.82403E+04 89 graphite -3.55 -8.19 -4.64 -1.326 0.79252E+04 90 greenalite 16.14 13.22 -2.92 -0.243 0.49892E+04 93 hematite 12.57 10.14 -2.43 -0.294 0.41475E+04 94 heulandite -5.83 -7.75 -1.92 -0.087 0.32790E+04 98 jadeite 4.22 2.72 -1.49 -0.149 0.25489E+04 99 julgoldite 70.43 65.45 -4.97 -0.129 0.84936E+04 100 kalsilite 7.58 3.73 -3.86 -0.551 0.65876E+04 101 kaolinite -1.33 -4.93 -3.60 -0.327 0.61448E+04 104 laumontite 2.88 1.57 -1.31 -0.087 0.22401E+04 105 lawsonite 9.62 7.78 -1.83 -0.122 0.31279E+04 106 leucite 4.12 0.62 -3.50 -0.350 0.59752E+04 108 lizardite 23.24 21.36 -1.88 -0.157 0.32105E+04 110 magnetite 20.09 16.61 -3.47 -0.284 0.59309E+04 111 minnesotaite 10.39 7.00 -3.38 -0.199 0.57769E+04 115 manganosite 14.06 9.23 -4.83 -1.207 0.82410E+04 119 microcline -2.49 -2.49 0.00 0.000 0.75530E+00 123 muscovite 2.58 -1.21 -3.79 -0.223 0.64682E+04 124 paragonite 4.24 0.90 -3.34 -0.197 0.57066E+04 125 nepheline 8.34 5.83 -2.51 -0.359 0.42868E+04 137 phlogopite-Na 29.65 27.19 -2.45 -0.136 0.41907E+04 139 prehnite 19.37 17.39 -1.98 -0.116 0.33780E+04 140 prehnite-Fe 22.50 21.82 -0.68 -0.041 0.11548E+04 141 pumpellyite-Fe 46.27 41.90 -4.37 -0.097 0.74531E+04 142 pumpellyite-Mg 48.99 44.62 -4.38 -0.097 0.74704E+04 145 pyrite -21.25 -24.06 -2.81 -0.662 0.48004E+04 146 pyrrhotite -4.26 -7.38 -3.12 -1.041 0.53312E+04 147 pyrrhotiteFe0.875 -6.02 -8.54 -2.52 -0.928 0.43105E+04 148 pyroxmangite 7.40 6.13 -1.27 -0.255 0.21742E+04 149 pyrophyllite -6.18 -11.14 -4.97 -0.311 0.84835E+04 150 quartz -2.99 -3.11 -0.12 -0.039 0.19965E+03 154 rhodochrosite -0.98 -4.59 -3.61 -1.204 0.61679E+04 155 rhodonite 7.45 6.13 -1.32 -0.264 0.22545E+04 156 sanidine -1.28 -2.49 -1.21 -0.093 0.20685E+04 158 siderite -2.61 -7.34 -4.74 -1.578 0.80856E+04 166 stilbite -7.52 -7.75 -0.23 -0.011 0.38518E+03 167 stilpnomelane-Fe 13.02 11.91 -1.11 -0.033 0.18904E+04 168 stilpnomelane-Mg 27.44 25.49 -1.95 -0.058 0.33379E+04 174 talc 16.49 15.15 -1.34 -0.079 0.22884E+04 177 tephroite 18.09 15.36 -2.73 -0.390 0.46593E+04 181 tridymite -2.63 -3.11 -0.48 -0.160 0.81963E+03 182 tremolite 47.87 46.54 -1.33 -0.036 0.22680E+04 184 troilite-low -4.41 -7.38 -2.97 -0.991 0.50740E+04 190 wairakite 3.95 1.57 -2.38 -0.140 0.40621E+04 191 walstromite 11.51 9.61 -1.90 -0.380 0.32440E+04 192 wollastonite 10.46 9.61 -0.85 -0.170 0.14544E+04 193 pseudo-wollastonite 11.00 9.61 -1.39 -0.278 0.23742E+04 194 zoisite 22.85 18.03 -4.82 -0.219 0.82219E+04 195 akaganeite 7.75 5.07 -2.69 -0.581 0.45863E+04 202 chalcedony -2.80 -3.11 -0.30 -0.101 0.51895E+03 204 montmorillonite-Ca -2.29 -6.22 -3.93 -0.243 0.67163E+04 205 montmorillonite-K -2.24 -6.28 -4.04 -0.248 0.69022E+04 206 montmorillonite-Mg -2.48 -6.81 -4.33 -0.268 0.73860E+04 207 montmorillonite-Na -2.04 -5.59 -3.55 -0.217 0.60568E+04 208 nontronite-Ca 3.21 1.05 -2.17 -0.141 0.37022E+04 209 nontronite-H 2.53 -1.05 -3.58 -0.240 0.61204E+04 210 nontronite-K 3.34 0.99 -2.35 -0.151 0.40113E+04 211 nontronite-Mg 3.07 0.46 -2.61 -0.169 0.44560E+04 212 nontronite-Na 3.52 1.69 -1.83 -0.118 0.31319E+04 228 tobermorite 9.82 7.49 -2.34 -0.638 0.39907E+04 234 alabandite -0.98 -4.63 -3.65 -1.217 0.62320E+04 237 boehmite 4.41 0.64 -3.77 -0.628 0.64299E+04 239 ferrous-oxide 9.81 6.48 -3.33 -0.834 0.56941E+04 245 silica-amorphous -2.09 -3.11 -1.02 -0.338 0.17331E+04 247 an20ab80 2.02 1.25 -0.77 -0.059 0.13114E+04 248 an25ab75 2.65 1.66 -0.99 -0.076 0.16862E+04 249 an30ab70 3.28 2.07 -1.21 -0.093 0.20707E+04 250 tr.625ac.25prg.125 45.16 44.05 -1.11 -0.030 0.19009E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 0.0002000 MOLES Current total amount of reactant added: 0.0069900 MOLES New total amount of reactant added: 0.0071900 MOLES Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.5508E-08 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 7 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 0.0071900 Water: Moles liquid = 0.4986E+02 kg liquid = 0.8982E+00 Moles total = 0.4985E+02 kg total = 0.8981E+00 Activity = 1.0000 Stoichiometric ionic strength = .1178997E-01 Osmotic coef. = 0.9511 True ionic strength = .2043706E-01 Chg. balance for total moles = -.5508E-08 Max. difference allowed = 0.1803E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.10065E-09 -9.9972 0.84465E-10 -10.0733 0.83918E+00 -0.0761 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.19983E-03 -3.6993 0.16667E-03 -3.7781 0.83405E+00 -0.0788 4 SO4-- 0.21576E-04 -4.6660 0.11144E-04 -4.9530 0.51651E+00 -0.2869 5 HCO3- 0.22168E-03 -3.6543 0.18516E-03 -3.7324 0.83529E+00 -0.0782 6 HS- 0.20127E-03 -3.6962 0.16790E-03 -3.7750 0.83418E+00 -0.0787 7 Al+++ 0.11466E-28 -28.9406 0.26164E-29 -29.5823 0.22819E+00 -0.6417 8 H4SiO4 0.78550E-03 -3.1049 0.78550E-03 -3.1049 0.10000E+01 0.0000 9 Ca++ 0.71174E-07 -7.1477 0.36488E-07 -7.4378 0.51266E+00 -0.2902 10 Mg++ 0.21610E-10 -10.6654 0.11027E-10 -10.9576 0.51027E+00 -0.2922 11 Fe++ 0.42535E-13 -13.3713 0.21729E-13 -13.6630 0.51084E+00 -0.2917 12 K+ 0.15655E-03 -3.8053 0.13080E-03 -3.8834 0.83549E+00 -0.0781 13 Na+ 0.19887E-01 -1.7014 0.16584E-01 -1.7803 0.83390E+00 -0.0789 14 Mn++ 0.23777E-10 -10.6238 0.12156E-10 -10.9152 0.51127E+00 -0.2913 15 F- 0.33027E-05 -5.4811 0.27489E-05 -5.5608 0.83231E+00 -0.0797 16 HPO4-- 0.45425E-07 -7.3427 0.23466E-07 -7.6296 0.51658E+00 -0.2869 18 HSiO3- 0.10411E-01 -1.9825 0.86836E-02 -2.0613 0.83405E+00 -0.0788 19 Ca(HSiO3)+ 0.86346E-08 -8.0638 0.72158E-08 -8.1417 0.83568E+00 -0.0780 20 Mg(HSiO3)+ 0.32475E-11 -11.4885 0.27138E-11 -11.5664 0.83568E+00 -0.0780 21 NaHSiO3,aq 0.23291E-02 -2.6328 0.23291E-02 -2.6328 0.10000E+01 0.0000 22 AlO+ 0.59703E-16 -16.2240 0.49892E-16 -16.3020 0.83568E+00 -0.0780 24 HAlO2,aq 0.11763E-09 -9.9295 0.11763E-09 -9.9295 0.10000E+01 0.0000 25 AlO2- 0.37030E-05 -5.4314 0.30829E-05 -5.5110 0.83252E+00 -0.0796 26 CH4,aq 0.27196E-08 -8.5655 0.27098E-08 -8.5671 0.99641E+00 -0.0016 31 CO,aq 0.20789E-15 -15.6822 0.20789E-15 -15.6822 0.10000E+01 0.0000 32 CO2,aq 0.33539E-07 -7.4744 0.33419E-07 -7.4760 0.99641E+00 -0.0016 33 CO3-2 0.37152E-03 -3.4300 0.19148E-03 -3.7179 0.51540E+00 -0.2879 34 CaCO3,aq 0.87606E-07 -7.0575 0.87606E-07 -7.0575 0.10000E+01 0.0000 35 Ca(HCO3)+ 0.20637E-09 -9.6853 0.17246E-09 -9.7633 0.83568E+00 -0.0780 36 CaCl+ 0.11777E-10 -10.9290 0.98416E-11 -11.0069 0.83568E+00 -0.0780 37 CaCl2,aq 0.38970E-15 -15.4093 0.38970E-15 -15.4093 0.10000E+01 0.0000 38 CaF+ 0.17523E-11 -11.7564 0.14644E-11 -11.8343 0.83568E+00 -0.0780 39 CaOH+ 0.36842E-07 -7.4337 0.30788E-07 -7.5116 0.83568E+00 -0.0780 40 CaSO4,aq 0.12912E-09 -9.8890 0.12912E-09 -9.8890 0.10000E+01 0.0000 41 HCl,aq 0.25797E-14 -14.5884 0.25797E-14 -14.5884 0.10000E+01 0.0000 45 HF,aq 0.15895E-11 -11.7988 0.15895E-11 -11.7988 0.10000E+01 0.0000 46 HF2- 0.17686E-17 -17.7524 0.14751E-17 -17.8312 0.83405E+00 -0.0788 48 FeCl+ 0.68593E-17 -17.1637 0.57322E-17 -17.2417 0.83568E+00 -0.0780 51 FeF+ 0.36524E-17 -17.4374 0.30522E-17 -17.5154 0.83568E+00 -0.0780 53 FeO,aq 0.11837E-09 -9.9268 0.11837E-09 -9.9268 0.10000E+01 0.0000 54 FeOH+ 0.10020E-10 -10.9991 0.83738E-11 -11.0771 0.83568E+00 -0.0780 55 HFeO2- 0.17581E-07 -7.7550 0.14663E-07 -7.8338 0.83405E+00 -0.0788 56 FeO+ 0.48029E-16 -16.3185 0.40136E-16 -16.3965 0.83568E+00 -0.0780 58 FeO2- 0.13802E-08 -8.8601 0.11512E-08 -8.9389 0.83405E+00 -0.0788 59 HFeO2,aq 0.12366E-10 -10.9078 0.12366E-10 -10.9078 0.10000E+01 0.0000 60 H2,aq 0.24853E-06 -6.6046 0.24764E-06 -6.6062 0.99641E+00 -0.0016 61 KCl,aq 0.39510E-09 -9.4033 0.39510E-09 -9.4033 0.10000E+01 0.0000 62 KHSO4,aq 0.34810E-18 -18.4583 0.34810E-18 -18.4583 0.10000E+01 0.0000 63 KOH,aq 0.66131E-06 -6.1796 0.66131E-06 -6.1796 0.10000E+01 0.0000 64 KSO4- 0.27119E-07 -7.5667 0.22619E-07 -7.6455 0.83405E+00 -0.0788 65 MgCO3,aq 0.66361E-11 -11.1781 0.66361E-11 -11.1781 0.10000E+01 0.0000 66 Mg(HCO3)+ 0.63727E-13 -13.1957 0.53255E-13 -13.2736 0.83568E+00 -0.0780 67 MgCl+ 0.32257E-14 -14.4914 0.26956E-14 -14.5693 0.83568E+00 -0.0780 68 MgF+ 0.19617E-14 -14.7074 0.16393E-14 -14.7853 0.83568E+00 -0.0780 69 MgOH+ 0.61608E-10 -10.2104 0.51484E-10 -10.2883 0.83568E+00 -0.0780 71 MnF+ 0.67352E-15 -15.1716 0.56285E-15 -15.2496 0.83568E+00 -0.0780 72 MnO,aq 0.17646E-08 -8.7534 0.17646E-08 -8.7534 0.10000E+01 0.0000 73 MnOH+ 0.52078E-09 -9.2833 0.43520E-09 -9.3613 0.83568E+00 -0.0780 74 MnO2-2 0.15926E-10 -10.7979 0.82084E-11 -11.0857 0.51540E+00 -0.2879 75 HMnO2- 0.18212E-09 -9.7396 0.15190E-09 -9.8185 0.83405E+00 -0.0788 78 MnCl+ 0.14930E-13 -13.8259 0.12476E-13 -13.9039 0.83568E+00 -0.0780 79 MnSO4,aq 0.39109E-13 -13.4077 0.39109E-13 -13.4077 0.10000E+01 0.0000 80 NaCl,aq 0.91599E-06 -6.0381 0.91599E-06 -6.0381 0.10000E+01 0.0000 81 NaF,aq 0.10673E-07 -7.9717 0.10673E-07 -7.9717 0.10000E+01 0.0000 82 NaOH,aq 0.84357E-04 -4.0739 0.84357E-04 -4.0739 0.10000E+01 0.0000 84 OH- 0.82165E-02 -2.0853 0.68404E-02 -2.1649 0.83252E+00 -0.0796 89 HPO3-2 0.35136E-16 -16.4542 0.18109E-16 -16.7421 0.51540E+00 -0.2879 92 H3PO4,aq 0.11709E-17 -17.9315 0.11709E-17 -17.9315 0.10000E+01 0.0000 93 H2PO4- 0.43796E-10 -10.3586 0.36564E-10 -10.4370 0.83486E+00 -0.0784 94 PO4-3 0.94503E-09 -9.0246 0.22667E-09 -9.6446 0.23985E+00 -0.6201 98 HP2O7-3 0.10849E-17 -17.9646 0.24781E-18 -18.6059 0.22842E+00 -0.6413 99 P2O7-4 0.92880E-17 -17.0321 0.70090E-18 -18.1543 0.75463E-01 -1.1223 100 H2S,aq 0.43987E-07 -7.3567 0.43829E-07 -7.3582 0.99641E+00 -0.0016 101 S2-2 0.48940E-11 -11.3103 0.25223E-11 -11.5982 0.51540E+00 -0.2879 102 S3-2 0.11670E-17 -17.9329 0.60146E-18 -18.2208 0.51540E+00 -0.2879 107 SO3-2 0.68573E-12 -12.1638 0.35862E-12 -12.4454 0.52297E+00 -0.2815 108 HSO3- 0.22739E-14 -14.6432 0.18966E-14 -14.7220 0.83405E+00 -0.0788 109 HSO4- 0.10844E-11 -11.9648 0.90713E-12 -12.0423 0.83650E+00 -0.0775 111 S2O3-2 0.11132E-13 -13.9534 0.57376E-14 -14.2413 0.51540E+00 -0.2879 Charge balance for all species = -.6132E-08 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.1006517E-09 -.2142837E-01 -.2156040E+02 0.0000 2 H2O 0.1000000E+01 0.5550382E+02 0.9981537E+06 0.0000 3 Cl- 0.1998291E-03 0.2007455E-03 0.7104475E+01 6.2952 4 SO4-- 0.2157577E-04 0.2153834E-04 0.2065357E+01 15.1937 5 HCO3- 0.2216758E-03 0.5933201E-03 0.3613886E+02 6.3409 6 HS- 0.2012726E-03 0.2013813E-03 0.6648331E+01 6.2984 7 Al+++ 0.1146629E-28 0.3703145E-05 0.9974012E-01 0.6377 8 H4SiO4 0.7855027E-03 0.1352588E-01 0.1297752E+04 -3.1049 9 Ca++ 0.7117445E-07 0.2046055E-06 0.8185710E-02 12.7088 10 Mg++ 0.2160960E-10 0.9317006E-10 0.2261154E-05 9.1891 11 Fe++ 0.4253505E-13 0.1910162E-07 0.1064886E-02 6.4837 12 K+ 0.1565511E-03 0.1572399E-03 0.6137547E+01 6.1899 13 Na+ 0.1988710E-01 0.2230149E-01 0.5118021E+03 8.2930 14 Mn++ 0.2377666E-10 0.2507231E-08 0.1374992E-03 9.2314 15 F- 0.3302699E-05 0.3313375E-05 0.6283644E-01 4.5125 16 HPO4-- 0.4542535E-07 0.4641418E-07 0.4446927E-02 12.5171 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.1925236E-01 -.1924648E-01 -.5873870E-05 0.0000000E+00 2 H2O 0.4985230E+02 0.4985230E+02 -.5801707E-05 0.0000000E+00 3 Cl- 0.1803052E-03 0.1803052E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.1934719E-04 0.1934526E-04 0.1929452E-08 0.0000000E+00 5 HCO3- 0.5329070E-03 0.5329070E-03 0.0000000E+00 0.0000000E+00 6 HS- 0.1808743E-03 0.1808762E-03 -.1929452E-08 0.0000000E+00 7 Al+++ 0.4775352E-05 0.3326083E-05 0.1449269E-05 0.0000000E+00 8 H4SiO4 0.1215302E-01 0.1214865E-01 0.4369803E-05 0.0000000E+00 9 Ca++ 0.2080835E-06 0.1837721E-06 0.2431139E-07 0.0000000E+00 10 Mg++ 0.8368328E-10 0.8368328E-10 0.0000000E+00 0.0000000E+00 11 Fe++ 0.3259227E-07 0.1715665E-07 0.1543562E-07 0.0000000E+00 12 K+ 0.1412294E-03 0.1412294E-03 0.0000000E+00 0.0000000E+00 13 Na+ 0.2003215E-01 0.2003070E-01 0.1448497E-05 0.0000000E+00 14 Mn++ 0.2251939E-08 0.2251939E-08 0.0000000E+00 0.0000000E+00 15 F- 0.2976000E-05 0.2976000E-05 0.0000000E+00 0.0000000E+00 16 HPO4-- 0.4168819E-07 0.4168819E-07 0.0000000E+00 0.0000000E+00 Chg. balance for solid moles: -.1059E-20 Mass of aqueous solution: 0.899765E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 0.0071900 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 0.1448E-05 -5.839 0.3798E-03 -3.420 98.93 0.1458E-03 andradite 0.7718E-08 -8.113 0.3922E-05 -5.406 1.022 0.1019E-05 grossular 0.3860E-09 -9.413 0.1739E-06 -6.760 0.4529E-01 0.4838E-07 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.9524E+00 0.9524E+00 1.0000 -0.021 grossular 0.4763E-01 0.4763E-01 1.0000 -1.322 Solid products produced: Mass = 0.000384 g Volume = 0.000147 cm3 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.0071900 moles log = -2.1433 Original solution: 1000.0103000 g Original solution / Rock added: 139083.49 (Water/Rock Ratio), log = 5.1433 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0206 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9997E+00 0.9859 0.1006E+01 0.1020E+01 CO2,gas 0.3478E-05 1.0071 0.3575E-05 0.3550E-05 CH4,gas 0.3860E-05 1.0125 0.3989E-05 0.3939E-05 H2,gas 0.3184E-03 1.0005 0.3251E-03 0.3249E-03 H2S,gas 0.1185E-05 0.9960 0.1205E-05 0.1210E-05 S2,gas 0.5051E-24 1.0000 0.5155E-24 0.5155E-24 CO,gas 0.3035E-12 1.0000 0.3098E-12 0.3098E-12 SO3,gas 0.2945E-40 1.0000 0.3006E-40 0.3006E-40 SO2,gas 0.3725E-21 1.0000 0.3802E-21 0.3802E-21 HF,gas 0.3824E-14 1.0000 0.3903E-14 0.3903E-14 HCl,gas 0.4460E-17 1.0000 0.4552E-17 0.4552E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 17 albite -0.38 -0.38 0.00 0.000 -0.94784E-12 23 andradite 39.01 39.01 0.00 0.000 -0.24265E-10 24 grossular 32.73 32.73 0.00 0.000 -0.12132E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -13.81 -7.15 -2.382 0.12201E+05 -5.447 3 CH4,gas 4.54 -2.55 -7.10 -1.775 0.12120E+05 -5.399 4 H2,gas 8.00 2.81 -5.19 -2.964 0.88565E+04 -3.488 5 H2S,gas -6.23 -13.85 -7.62 -3.809 0.13008E+05 -5.919 6 S2,gas -7.34 -33.32 -25.99 -3.998 0.44372E+05 -24.288 7 CO,gas 3.21 -10.99 -14.21 -4.372 0.24260E+05 -12.509 8 SO3,gas 17.12 -25.10 -42.22 -10.555 0.72091E+05 -40.522 9 SO2,gas 0.83 -22.29 -23.12 -6.165 0.39475E+05 -21.420 10 HF,gas 0.47 -15.63 -16.11 -8.054 0.27503E+05 -14.409 11 HCl,gas 5.19 -13.85 -19.04 -9.520 0.32512E+05 -17.342 12 acmite 7.71 7.16 -0.55 -0.057 0.93765E+03 16 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 20 spessartine 24.46 19.66 -4.80 -0.240 0.81996E+04 21 analcite 3.32 2.72 -0.60 -0.067 0.10260E+04 27 annite 20.12 16.96 -3.16 -0.176 0.53944E+04 28 phlogopite 27.06 25.08 -1.98 -0.110 0.33881E+04 30 anorthite 12.71 7.77 -4.94 -0.380 0.84278E+04 33 apatite-OH -18.15 -19.78 -1.63 -0.125 0.27851E+04 34 apatite-F -34.30 -35.42 -1.12 -0.093 0.19087E+04 38 aragonite 0.97 -1.10 -2.06 -0.688 0.35234E+04 39 brucite 12.57 9.19 -3.38 -0.676 0.57704E+04 40 calcite 0.81 -1.10 -1.91 -0.636 0.32591E+04 41 carnegieite-low 9.02 5.83 -3.20 -0.457 0.54596E+04 42 carnegieite-high 10.09 5.83 -4.27 -0.610 0.72866E+04 43 carpholite-Mg 8.58 4.25 -4.33 -0.288 0.73888E+04 45 celadonite 5.34 3.60 -1.74 -0.103 0.29784E+04 46 celadonite-Fe 3.88 0.89 -2.98 -0.176 0.50962E+04 47 chrysotile 23.89 21.36 -2.53 -0.211 0.43281E+04 49 clinochlore 39.07 37.91 -1.16 -0.036 0.19862E+04 50 daphnite 28.97 24.38 -4.59 -0.143 0.78305E+04 52 chlorite-Al-free 47.17 42.72 -4.46 -0.186 0.76114E+04 54 chloritoid-Fe 9.17 4.65 -4.52 -0.301 0.77168E+04 55 chloritoid-Mn 11.40 7.40 -4.00 -0.267 0.68284E+04 57 coesite -2.38 -3.10 -0.73 -0.243 0.12444E+04 64 cristobalite -2.56 -3.10 -0.54 -0.182 0.92974E+03 66 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71242E+04 68 diaspore 2.87 0.64 -2.24 -0.373 0.38179E+04 70 diopside 16.18 15.69 -0.49 -0.049 0.84207E+03 71 hedenbergite 14.21 12.98 -1.23 -0.123 0.20925E+04 76 clinoenstatite 17.17 12.17 -5.00 -0.500 0.85336E+04 78 epidote 24.67 22.46 -2.21 -0.107 0.37808E+04 79 clinozoisite 22.81 18.02 -4.79 -0.218 0.81787E+04 80 epidote-Fe 29.84 26.90 -2.95 -0.153 0.50295E+04 81 fayalite 14.05 9.86 -4.18 -0.598 0.71427E+04 82 ferrosilite 11.15 6.76 -4.39 -0.439 0.74989E+04 86 gibbsite 4.08 0.64 -3.44 -0.492 0.58765E+04 87 glaucophane 22.97 20.59 -2.38 -0.064 0.40722E+04 88 glaucophane-Fe 17.28 12.47 -4.80 -0.130 0.81997E+04 89 graphite -3.55 -8.18 -4.63 -1.324 0.79123E+04 90 greenalite 16.14 13.24 -2.90 -0.242 0.49486E+04 93 hematite 12.57 10.15 -2.41 -0.292 0.41178E+04 94 heulandite -5.83 -7.75 -1.92 -0.087 0.32827E+04 98 jadeite 4.22 2.72 -1.49 -0.149 0.25515E+04 99 julgoldite 70.43 65.48 -4.94 -0.128 0.84425E+04 100 kalsilite 7.58 3.72 -3.86 -0.552 0.65928E+04 101 kaolinite -1.33 -4.93 -3.60 -0.327 0.61496E+04 104 laumontite 2.88 1.56 -1.32 -0.088 0.22516E+04 105 lawsonite 9.62 7.77 -1.84 -0.123 0.31445E+04 106 leucite 4.12 0.62 -3.50 -0.350 0.59778E+04 108 lizardite 23.24 21.36 -1.89 -0.157 0.32207E+04 110 magnetite 20.09 16.64 -3.45 -0.282 0.58894E+04 111 minnesotaite 10.39 7.03 -3.36 -0.197 0.57311E+04 115 manganosite 14.06 9.23 -4.83 -1.207 0.82414E+04 119 microcline -2.49 -2.49 0.00 0.000 0.78115E+00 123 muscovite 2.58 -1.21 -3.79 -0.223 0.64782E+04 124 paragonite 4.24 0.89 -3.35 -0.197 0.57165E+04 125 nepheline 8.34 5.83 -2.51 -0.359 0.42919E+04 137 phlogopite-Na 29.65 27.18 -2.46 -0.137 0.42061E+04 139 prehnite 19.37 17.38 -1.99 -0.117 0.34038E+04 140 prehnite-Fe 22.50 21.82 -0.68 -0.041 0.11609E+04 141 pumpellyite-Fe 46.27 41.88 -4.39 -0.098 0.74980E+04 142 pumpellyite-Mg 48.99 44.58 -4.41 -0.098 0.75322E+04 145 pyrite -21.25 -24.03 -2.78 -0.654 0.47447E+04 146 pyrrhotite -4.26 -7.36 -3.10 -1.035 0.53005E+04 147 pyrrhotiteFe0.875 -6.02 -8.52 -2.51 -0.922 0.42805E+04 148 pyroxmangite 7.40 6.13 -1.27 -0.254 0.21720E+04 149 pyrophyllite -6.18 -11.14 -4.97 -0.311 0.84831E+04 150 quartz -2.99 -3.10 -0.12 -0.038 0.19707E+03 154 rhodochrosite -0.98 -4.57 -3.60 -1.199 0.61435E+04 155 rhodonite 7.45 6.13 -1.32 -0.264 0.22523E+04 156 sanidine -1.28 -2.49 -1.21 -0.093 0.20685E+04 158 siderite -2.61 -7.32 -4.71 -1.571 0.80489E+04 166 stilbite -7.52 -7.75 -0.23 -0.011 0.38888E+03 167 stilpnomelane-Fe 13.02 11.95 -1.07 -0.032 0.18220E+04 168 stilpnomelane-Mg 27.44 25.48 -1.96 -0.059 0.33542E+04 174 talc 16.49 15.15 -1.34 -0.079 0.22935E+04 177 tephroite 18.09 15.36 -2.73 -0.390 0.46576E+04 181 tridymite -2.63 -3.10 -0.48 -0.160 0.81705E+03 182 tremolite 47.87 46.52 -1.35 -0.036 0.22966E+04 184 troilite-low -4.41 -7.36 -2.95 -0.985 0.50433E+04 190 wairakite 3.95 1.56 -2.39 -0.140 0.40735E+04 191 walstromite 11.51 9.60 -1.91 -0.381 0.32532E+04 192 wollastonite 10.46 9.60 -0.86 -0.171 0.14637E+04 193 pseudo-wollastonite 11.00 9.60 -1.40 -0.279 0.23835E+04 194 zoisite 22.85 18.02 -4.83 -0.220 0.82528E+04 195 akaganeite 7.75 5.08 -2.68 -0.579 0.45714E+04 202 chalcedony -2.80 -3.10 -0.30 -0.101 0.51637E+03 204 montmorillonite-Ca -2.29 -6.23 -3.93 -0.243 0.67179E+04 205 montmorillonite-K -2.24 -6.28 -4.04 -0.248 0.69028E+04 206 montmorillonite-Mg -2.48 -6.81 -4.33 -0.268 0.73865E+04 207 montmorillonite-Na -2.04 -5.59 -3.55 -0.217 0.60574E+04 208 nontronite-Ca 3.21 1.07 -2.15 -0.139 0.36667E+04 209 nontronite-H 2.53 -1.03 -3.56 -0.239 0.60829E+04 210 nontronite-K 3.34 1.01 -2.33 -0.149 0.39748E+04 211 nontronite-Mg 3.07 0.49 -2.59 -0.168 0.44194E+04 212 nontronite-Na 3.52 1.71 -1.81 -0.116 0.30954E+04 228 tobermorite 9.82 7.48 -2.34 -0.639 0.39980E+04 234 alabandite -0.98 -4.62 -3.64 -1.213 0.62134E+04 237 boehmite 4.41 0.64 -3.77 -0.628 0.64349E+04 239 ferrous-oxide 9.81 6.48 -3.33 -0.832 0.56823E+04 245 silica-amorphous -2.09 -3.10 -1.01 -0.338 0.17305E+04 247 an20ab80 2.02 1.25 -0.77 -0.059 0.13147E+04 248 an25ab75 2.65 1.66 -0.99 -0.076 0.16904E+04 249 an30ab70 3.28 2.06 -1.22 -0.094 0.20756E+04 250 tr.625ac.25prg.125 45.16 44.05 -1.12 -0.030 0.19105E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 0.0002000 MOLES Current total amount of reactant added: 0.0071900 MOLES New total amount of reactant added: 0.0073900 MOLES Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.5508E-08 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 7 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 0.0073900 Water: Moles liquid = 0.4986E+02 kg liquid = 0.8982E+00 Moles total = 0.4985E+02 kg total = 0.8981E+00 Activity = 1.0000 Stoichiometric ionic strength = .1180279E-01 Osmotic coef. = 0.9507 True ionic strength = .2044846E-01 Chg. balance for total moles = -.5508E-08 Max. difference allowed = 0.1815E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.10103E-09 -9.9955 0.84782E-10 -10.0717 0.83915E+00 -0.0762 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.20114E-03 -3.6965 0.16775E-03 -3.7753 0.83402E+00 -0.0788 4 SO4-- 0.22637E-04 -4.6452 0.11691E-04 -4.9322 0.51643E+00 -0.2870 5 HCO3- 0.22821E-03 -3.6417 0.19061E-03 -3.7198 0.83526E+00 -0.0782 6 HS- 0.20562E-03 -3.6869 0.17152E-03 -3.7657 0.83415E+00 -0.0788 7 Al+++ 0.11522E-28 -28.9385 0.26283E-29 -29.5803 0.22811E+00 -0.6419 8 H4SiO4 0.78824E-03 -3.1033 0.78824E-03 -3.1033 0.10000E+01 0.0000 9 Ca++ 0.70595E-07 -7.1512 0.36185E-07 -7.4415 0.51258E+00 -0.2902 10 Mg++ 0.21625E-10 -10.6650 0.11033E-10 -10.9573 0.51020E+00 -0.2923 11 Fe++ 0.43550E-13 -13.3610 0.22244E-13 -13.6528 0.51076E+00 -0.2918 12 K+ 0.15655E-03 -3.8053 0.13079E-03 -3.8834 0.83546E+00 -0.0781 13 Na+ 0.19888E-01 -1.7014 0.16584E-01 -1.7803 0.83387E+00 -0.0789 14 Mn++ 0.23946E-10 -10.6208 0.12241E-10 -10.9122 0.51119E+00 -0.2914 15 F- 0.33915E-05 -5.4696 0.28226E-05 -5.5493 0.83228E+00 -0.0797 16 HPO4-- 0.45428E-07 -7.3427 0.23464E-07 -7.6296 0.51651E+00 -0.2869 18 HSiO3- 0.10409E-01 -1.9826 0.86813E-02 -2.0614 0.83402E+00 -0.0788 19 Ca(HSiO3)+ 0.85611E-08 -8.0675 0.71541E-08 -8.1454 0.83565E+00 -0.0780 20 Mg(HSiO3)+ 0.32486E-11 -11.4883 0.27147E-11 -11.5663 0.83565E+00 -0.0780 21 NaHSiO3,aq 0.23285E-02 -2.6329 0.23285E-02 -2.6329 0.10000E+01 0.0000 22 AlO+ 0.59528E-16 -16.2253 0.49745E-16 -16.3033 0.83565E+00 -0.0780 24 HAlO2,aq 0.11685E-09 -9.9324 0.11685E-09 -9.9324 0.10000E+01 0.0000 25 AlO2- 0.36646E-05 -5.4360 0.30508E-05 -5.5156 0.83249E+00 -0.0796 26 CH4,aq 0.27263E-08 -8.5644 0.27165E-08 -8.5660 0.99640E+00 -0.0016 31 CO,aq 0.21319E-15 -15.6712 0.21319E-15 -15.6712 0.10000E+01 0.0000 32 CO2,aq 0.34656E-07 -7.4602 0.34531E-07 -7.4618 0.99640E+00 -0.0016 33 CO3-2 0.38108E-03 -3.4190 0.19638E-03 -3.7069 0.51532E+00 -0.2879 34 CaCO3,aq 0.89102E-07 -7.0501 0.89102E-07 -7.0501 0.10000E+01 0.0000 35 Ca(HCO3)+ 0.21069E-09 -9.6763 0.17606E-09 -9.7543 0.83565E+00 -0.0780 36 CaCl+ 0.11756E-10 -10.9298 0.98235E-11 -11.0077 0.83565E+00 -0.0780 37 CaCl2,aq 0.39151E-15 -15.4073 0.39151E-15 -15.4073 0.10000E+01 0.0000 38 CaF+ 0.17845E-11 -11.7485 0.14912E-11 -11.8265 0.83565E+00 -0.0780 39 CaOH+ 0.36401E-07 -7.4389 0.30418E-07 -7.5169 0.83565E+00 -0.0780 40 CaSO4,aq 0.13433E-09 -9.8718 0.13433E-09 -9.8718 0.10000E+01 0.0000 41 HCl,aq 0.26062E-14 -14.5840 0.26062E-14 -14.5840 0.10000E+01 0.0000 45 HF,aq 0.16382E-11 -11.7856 0.16382E-11 -11.7856 0.10000E+01 0.0000 46 HF2- 0.18719E-17 -17.7277 0.15612E-17 -17.8065 0.83402E+00 -0.0788 48 FeCl+ 0.70679E-17 -17.1507 0.59063E-17 -17.2287 0.83565E+00 -0.0780 51 FeF+ 0.38395E-17 -17.4157 0.32085E-17 -17.4937 0.83565E+00 -0.0780 53 FeO,aq 0.12027E-09 -9.9198 0.12027E-09 -9.9198 0.10000E+01 0.0000 54 FeOH+ 0.10220E-10 -10.9905 0.85403E-11 -11.0685 0.83565E+00 -0.0780 55 HFeO2- 0.17797E-07 -7.7496 0.14843E-07 -7.8285 0.83402E+00 -0.0788 56 FeO+ 0.49172E-16 -16.3083 0.41090E-16 -16.3863 0.83565E+00 -0.0780 58 FeO2- 0.14025E-08 -8.8531 0.11697E-08 -8.9319 0.83402E+00 -0.0788 59 HFeO2,aq 0.12613E-10 -10.8992 0.12613E-10 -10.8992 0.10000E+01 0.0000 60 H2,aq 0.24665E-06 -6.6079 0.24577E-06 -6.6095 0.99640E+00 -0.0016 61 KCl,aq 0.39766E-09 -9.4005 0.39766E-09 -9.4005 0.10000E+01 0.0000 62 KHSO4,aq 0.36653E-18 -18.4359 0.36653E-18 -18.4359 0.10000E+01 0.0000 63 KOH,aq 0.65882E-06 -6.1812 0.65882E-06 -6.1812 0.10000E+01 0.0000 64 KSO4- 0.28449E-07 -7.5459 0.23727E-07 -7.6248 0.83402E+00 -0.0788 65 MgCO3,aq 0.68098E-11 -11.1669 0.68098E-11 -11.1669 0.10000E+01 0.0000 66 Mg(HCO3)+ 0.65643E-13 -13.1828 0.54854E-13 -13.2608 0.83565E+00 -0.0780 67 MgCl+ 0.32486E-14 -14.4883 0.27147E-14 -14.5663 0.83565E+00 -0.0780 68 MgF+ 0.20155E-14 -14.6956 0.16843E-14 -14.7736 0.83565E+00 -0.0780 69 MgOH+ 0.61415E-10 -10.2117 0.51321E-10 -10.2897 0.83565E+00 -0.0780 71 MnF+ 0.69644E-15 -15.1571 0.58198E-15 -15.2351 0.83565E+00 -0.0780 72 MnO,aq 0.17636E-08 -8.7536 0.17636E-08 -8.7536 0.10000E+01 0.0000 73 MnOH+ 0.52246E-09 -9.2819 0.43659E-09 -9.3599 0.83565E+00 -0.0780 74 MnO2-2 0.15801E-10 -10.8013 0.81427E-11 -11.0892 0.51532E+00 -0.2879 75 HMnO2- 0.18134E-09 -9.7415 0.15125E-09 -9.8203 0.83402E+00 -0.0788 78 MnCl+ 0.15132E-13 -13.8201 0.12645E-13 -13.8981 0.83565E+00 -0.0780 79 MnSO4,aq 0.41313E-13 -13.3839 0.41313E-13 -13.3839 0.10000E+01 0.0000 80 NaCl,aq 0.92195E-06 -6.0353 0.92195E-06 -6.0353 0.10000E+01 0.0000 81 NaF,aq 0.10959E-07 -7.9602 0.10959E-07 -7.9602 0.10000E+01 0.0000 82 NaOH,aq 0.84042E-04 -4.0755 0.84042E-04 -4.0755 0.10000E+01 0.0000 84 OH- 0.81861E-02 -2.0869 0.68148E-02 -2.1665 0.83249E+00 -0.0796 89 HPO3-2 0.34874E-16 -16.4575 0.17971E-16 -16.7454 0.51532E+00 -0.2879 92 H3PO4,aq 0.11796E-17 -17.9283 0.11796E-17 -17.9283 0.10000E+01 0.0000 93 H2PO4- 0.43959E-10 -10.3570 0.36698E-10 -10.4354 0.83483E+00 -0.0784 94 PO4-3 0.94172E-09 -9.0261 0.22581E-09 -9.6463 0.23978E+00 -0.6202 98 HP2O7-3 0.10892E-17 -17.9629 0.24870E-18 -18.6043 0.22834E+00 -0.6414 99 P2O7-4 0.92919E-17 -17.0319 0.70078E-18 -18.1544 0.75419E-01 -1.1225 100 H2S,aq 0.45104E-07 -7.3458 0.44942E-07 -7.3473 0.99640E+00 -0.0016 101 S2-2 0.51468E-11 -11.2885 0.26523E-11 -11.5764 0.51532E+00 -0.2879 102 S3-2 0.12680E-17 -17.8969 0.65343E-18 -18.1848 0.51532E+00 -0.2879 107 SO3-2 0.71403E-12 -12.1463 0.37337E-12 -12.4279 0.52290E+00 -0.2816 108 HSO3- 0.23764E-14 -14.6241 0.19820E-14 -14.7029 0.83402E+00 -0.0788 109 HSO4- 0.11419E-11 -11.9424 0.95519E-12 -12.0199 0.83647E+00 -0.0775 111 S2O3-2 0.11977E-13 -13.9217 0.61718E-14 -14.2096 0.51532E+00 -0.2879 Charge balance for all species = -.6132E-08 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.1010327E-09 -.2140416E-01 -.2153602E+02 0.0000 2 H2O 0.1000000E+01 0.5550379E+02 0.9981525E+06 0.0000 3 Cl- 0.2011362E-03 0.2020585E-03 0.7150937E+01 6.2964 4 SO4-- 0.2263718E-04 0.2260155E-04 0.2167309E+01 15.2112 5 HCO3- 0.2282086E-03 0.6094171E-03 0.3711929E+02 6.3519 6 HS- 0.2056188E-03 0.2057282E-03 0.6791832E+01 6.3060 7 Al+++ 0.1152208E-28 0.3664766E-05 0.9870635E-01 0.6348 8 H4SiO4 0.7882446E-03 0.1352572E-01 0.1297735E+04 -3.1033 9 Ca++ 0.7059491E-07 0.2050179E-06 0.8202204E-02 12.7019 10 Mg++ 0.2162525E-10 0.9316970E-10 0.2261144E-05 9.1861 11 Fe++ 0.4355026E-13 0.1934283E-07 0.1078332E-02 6.4906 12 K+ 0.1565516E-03 0.1572393E-03 0.6137519E+01 6.1883 13 Na+ 0.1988788E-01 0.2230136E-01 0.5117989E+03 8.2914 14 Mn++ 0.2394581E-10 0.2507221E-08 0.1374986E-03 9.2312 15 F- 0.3391469E-05 0.3402431E-05 0.6452529E-01 4.5224 16 HPO4-- 0.4542832E-07 0.4641401E-07 0.4446907E-02 12.5138 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.1923082E-01 -.1922481E-01 -.6010586E-05 0.0000000E+00 2 H2O 0.4985246E+02 0.4985246E+02 -.5939556E-05 0.0000000E+00 3 Cl- 0.1814852E-03 0.1814852E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.2030219E-04 0.2030029E-04 0.1902363E-08 0.0000000E+00 5 HCO3- 0.5473670E-03 0.5473670E-03 0.0000000E+00 0.0000000E+00 6 HS- 0.1847793E-03 0.1847812E-03 -.1902363E-08 0.0000000E+00 7 Al+++ 0.4775352E-05 0.3291624E-05 0.1483728E-05 0.0000000E+00 8 H4SiO4 0.1215302E-01 0.1214855E-01 0.4472900E-05 0.0000000E+00 9 Ca++ 0.2080835E-06 0.1841432E-06 0.2394026E-07 0.0000000E+00 10 Mg++ 0.8368328E-10 0.8368328E-10 0.0000000E+00 0.0000000E+00 11 Fe++ 0.3259227E-07 0.1737336E-07 0.1521891E-07 0.0000000E+00 12 K+ 0.1412294E-03 0.1412294E-03 0.0000000E+00 0.0000000E+00 13 Na+ 0.2003215E-01 0.2003067E-01 0.1482987E-05 0.0000000E+00 14 Mn++ 0.2251939E-08 0.2251939E-08 0.0000000E+00 0.0000000E+00 15 F- 0.3056000E-05 0.3056000E-05 0.0000000E+00 0.0000000E+00 16 HPO4-- 0.4168819E-07 0.4168819E-07 0.0000000E+00 0.0000000E+00 Chg. balance for solid moles: -.2118E-21 Mass of aqueous solution: 0.899769E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 0.0073900 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 0.1483E-05 -5.829 0.3889E-03 -3.410 98.97 0.1493E-03 andradite 0.7609E-08 -8.119 0.3867E-05 -5.413 0.9842 0.1005E-05 grossular 0.3706E-09 -9.431 0.1670E-06 -6.777 0.4249E-01 0.4645E-07 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.9536E+00 0.9536E+00 1.0000 -0.021 grossular 0.4644E-01 0.4644E-01 1.0000 -1.333 Solid products produced: Mass = 0.000393 g Volume = 0.000150 cm3 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.0073900 moles log = -2.1314 Original solution: 1000.0103000 g Original solution / Rock added: 135319.39 (Water/Rock Ratio), log = 5.1314 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0206 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9997E+00 0.9859 0.1006E+01 0.1020E+01 CO2,gas 0.3594E-05 1.0071 0.3694E-05 0.3668E-05 CH4,gas 0.3869E-05 1.0125 0.3999E-05 0.3949E-05 H2,gas 0.3160E-03 1.0005 0.3227E-03 0.3225E-03 H2S,gas 0.1215E-05 0.9960 0.1235E-05 0.1240E-05 S2,gas 0.5392E-24 1.0000 0.5503E-24 0.5503E-24 CO,gas 0.3113E-12 1.0000 0.3177E-12 0.3177E-12 SO3,gas 0.3113E-40 1.0000 0.3177E-40 0.3177E-40 SO2,gas 0.3908E-21 1.0000 0.3988E-21 0.3988E-21 HF,gas 0.3941E-14 1.0000 0.4022E-14 0.4022E-14 HCl,gas 0.4506E-17 1.0000 0.4599E-17 0.4599E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 17 albite -0.38 -0.38 0.00 0.000 -0.94784E-12 23 andradite 39.01 39.01 0.00 0.000 0.00000E+00 24 grossular 32.73 32.73 0.00 0.000 0.12132E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -13.79 -7.13 -2.377 0.12177E+05 -5.432 3 CH4,gas 4.54 -2.55 -7.10 -1.774 0.12118E+05 -5.398 4 H2,gas 8.00 2.81 -5.19 -2.966 0.88622E+04 -3.491 5 H2S,gas -6.23 -13.84 -7.61 -3.804 0.12989E+05 -5.908 6 S2,gas -7.34 -33.29 -25.96 -3.994 0.44323E+05 -24.259 7 CO,gas 3.21 -10.98 -14.20 -4.368 0.24241E+05 -12.498 8 SO3,gas 17.12 -25.08 -42.20 -10.549 0.72050E+05 -40.498 9 SO2,gas 0.83 -22.27 -23.10 -6.160 0.39439E+05 -21.399 10 HF,gas 0.47 -15.62 -16.09 -8.047 0.27481E+05 -14.396 11 HCl,gas 5.19 -13.85 -19.04 -9.518 0.32504E+05 -17.337 12 acmite 7.71 7.17 -0.54 -0.056 0.92062E+03 16 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 20 spessartine 24.46 19.65 -4.80 -0.240 0.82030E+04 21 analcite 3.32 2.72 -0.60 -0.067 0.10286E+04 27 annite 20.12 16.98 -3.14 -0.174 0.53590E+04 28 phlogopite 27.06 25.07 -1.99 -0.111 0.34035E+04 30 anorthite 12.71 7.76 -4.95 -0.380 0.84444E+04 33 apatite-OH -18.15 -19.81 -1.66 -0.127 0.28273E+04 34 apatite-F -34.30 -35.43 -1.13 -0.094 0.19284E+04 38 aragonite 0.97 -1.09 -2.06 -0.685 0.35108E+04 39 brucite 12.57 9.19 -3.38 -0.676 0.57755E+04 40 calcite 0.81 -1.09 -1.90 -0.634 0.32466E+04 41 carnegieite-low 9.02 5.82 -3.20 -0.457 0.54647E+04 42 carnegieite-high 10.09 5.82 -4.27 -0.610 0.72917E+04 43 carpholite-Mg 8.58 4.25 -4.33 -0.289 0.73987E+04 45 celadonite 5.34 3.60 -1.75 -0.103 0.29809E+04 46 celadonite-Fe 3.88 0.90 -2.98 -0.175 0.50818E+04 47 chrysotile 23.89 21.35 -2.54 -0.212 0.43383E+04 49 clinochlore 39.07 37.89 -1.18 -0.037 0.20140E+04 50 daphnite 28.97 24.41 -4.55 -0.142 0.77736E+04 52 chlorite-Al-free 47.17 42.70 -4.47 -0.186 0.76318E+04 54 chloritoid-Fe 9.17 4.66 -4.52 -0.301 0.77123E+04 55 chloritoid-Mn 11.40 7.40 -4.00 -0.267 0.68362E+04 57 coesite -2.38 -3.10 -0.73 -0.242 0.12418E+04 64 cristobalite -2.56 -3.10 -0.54 -0.181 0.92716E+03 66 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71242E+04 68 diaspore 2.87 0.63 -2.24 -0.373 0.38229E+04 70 diopside 16.18 15.68 -0.50 -0.050 0.85376E+03 71 hedenbergite 14.21 12.99 -1.22 -0.122 0.20873E+04 78 epidote 24.67 22.45 -2.22 -0.108 0.37918E+04 79 clinozoisite 22.81 18.00 -4.81 -0.219 0.82093E+04 80 epidote-Fe 29.84 26.90 -2.94 -0.153 0.50209E+04 81 fayalite 14.05 9.88 -4.17 -0.595 0.71165E+04 82 ferrosilite 11.15 6.77 -4.37 -0.437 0.74701E+04 86 gibbsite 4.08 0.63 -3.44 -0.492 0.58815E+04 87 glaucophane 22.97 20.58 -2.39 -0.065 0.40825E+04 88 glaucophane-Fe 17.28 12.50 -4.78 -0.129 0.81590E+04 89 graphite -3.55 -8.17 -4.63 -1.322 0.78993E+04 90 greenalite 16.14 13.27 -2.87 -0.240 0.49079E+04 93 hematite 12.57 10.17 -2.39 -0.290 0.40886E+04 94 heulandite -5.83 -7.75 -1.92 -0.087 0.32863E+04 98 jadeite 4.22 2.72 -1.50 -0.150 0.25540E+04 99 julgoldite 70.43 65.51 -4.91 -0.128 0.83917E+04 100 kalsilite 7.58 3.72 -3.86 -0.552 0.65980E+04 101 kaolinite -1.33 -4.94 -3.60 -0.328 0.61544E+04 104 laumontite 2.88 1.56 -1.33 -0.088 0.22629E+04 105 lawsonite 9.62 7.76 -1.85 -0.123 0.31610E+04 106 leucite 4.12 0.62 -3.50 -0.350 0.59804E+04 108 lizardite 23.24 21.35 -1.89 -0.158 0.32310E+04 110 magnetite 20.09 16.66 -3.43 -0.280 0.58483E+04 111 minnesotaite 10.39 7.06 -3.33 -0.196 0.56853E+04 115 manganosite 14.06 9.23 -4.83 -1.207 0.82418E+04 119 microcline -2.49 -2.49 0.00 0.000 0.80708E+00 123 muscovite 2.58 -1.22 -3.80 -0.224 0.64882E+04 124 paragonite 4.24 0.89 -3.35 -0.197 0.57265E+04 125 nepheline 8.34 5.82 -2.52 -0.360 0.42971E+04 137 phlogopite-Na 29.65 27.17 -2.47 -0.137 0.42215E+04 139 prehnite 19.37 17.36 -2.01 -0.118 0.34295E+04 140 prehnite-Fe 22.50 21.81 -0.68 -0.041 0.11669E+04 141 pumpellyite-Fe 46.27 41.85 -4.42 -0.098 0.75424E+04 142 pumpellyite-Mg 48.99 44.55 -4.45 -0.099 0.75936E+04 145 pyrite -21.25 -23.99 -2.75 -0.646 0.46901E+04 146 pyrrhotite -4.26 -7.35 -3.09 -1.029 0.52701E+04 147 pyrrhotiteFe0.875 -6.02 -8.51 -2.49 -0.916 0.42508E+04 148 pyroxmangite 7.40 6.13 -1.27 -0.254 0.21699E+04 149 pyrophyllite -6.18 -11.14 -4.97 -0.311 0.84828E+04 150 quartz -2.99 -3.10 -0.11 -0.038 0.19449E+03 154 rhodochrosite -0.98 -4.56 -3.58 -1.195 0.61196E+04 155 rhodonite 7.45 6.13 -1.32 -0.264 0.22501E+04 156 sanidine -1.28 -2.49 -1.21 -0.093 0.20686E+04 158 siderite -2.61 -7.30 -4.69 -1.564 0.80128E+04 166 stilbite -7.52 -7.75 -0.23 -0.011 0.39248E+03 167 stilpnomelane-Fe 13.02 11.99 -1.03 -0.031 0.17535E+04 168 stilpnomelane-Mg 27.44 25.47 -1.97 -0.059 0.33705E+04 174 talc 16.49 15.14 -1.35 -0.079 0.22985E+04 177 tephroite 18.09 15.36 -2.73 -0.390 0.46558E+04 181 tridymite -2.63 -3.10 -0.48 -0.159 0.81447E+03 182 tremolite 47.87 46.51 -1.36 -0.037 0.23250E+04 184 troilite-low -4.41 -7.35 -2.94 -0.979 0.50129E+04 190 wairakite 3.95 1.56 -2.39 -0.141 0.40849E+04 191 walstromite 11.51 9.60 -1.91 -0.382 0.32624E+04 192 wollastonite 10.46 9.60 -0.86 -0.173 0.14728E+04 193 pseudo-wollastonite 11.00 9.60 -1.40 -0.280 0.23926E+04 194 zoisite 22.85 18.00 -4.85 -0.221 0.82834E+04 195 akaganeite 7.75 5.09 -2.67 -0.577 0.45568E+04 202 chalcedony -2.80 -3.10 -0.30 -0.100 0.51379E+03 204 montmorillonite-Ca -2.29 -6.23 -3.94 -0.243 0.67195E+04 205 montmorillonite-K -2.24 -6.28 -4.04 -0.248 0.69034E+04 206 montmorillonite-Mg -2.48 -6.81 -4.33 -0.268 0.73870E+04 207 montmorillonite-Na -2.04 -5.59 -3.55 -0.217 0.60580E+04 208 nontronite-Ca 3.21 1.09 -2.13 -0.138 0.36315E+04 209 nontronite-H 2.53 -1.01 -3.54 -0.237 0.60458E+04 210 nontronite-K 3.34 1.03 -2.31 -0.148 0.39386E+04 211 nontronite-Mg 3.07 0.51 -2.57 -0.167 0.43831E+04 212 nontronite-Na 3.52 1.73 -1.79 -0.115 0.30592E+04 228 tobermorite 9.82 7.48 -2.35 -0.640 0.40052E+04 234 alabandite -0.98 -4.61 -3.63 -1.209 0.61952E+04 237 boehmite 4.41 0.63 -3.77 -0.629 0.64398E+04 239 ferrous-oxide 9.81 6.49 -3.32 -0.830 0.56705E+04 245 silica-amorphous -2.09 -3.10 -1.01 -0.337 0.17280E+04 247 an20ab80 2.02 1.25 -0.77 -0.059 0.13180E+04 248 an25ab75 2.65 1.65 -0.99 -0.076 0.16945E+04 249 an30ab70 3.28 2.06 -1.22 -0.094 0.20806E+04 250 tr.625ac.25prg.125 45.16 44.04 -1.12 -0.030 0.19200E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 0.0002000 MOLES Current total amount of reactant added: 0.0073900 MOLES New total amount of reactant added: 0.0075900 MOLES Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.5508E-08 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 7 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 0.0075900 Water: Moles liquid = 0.4986E+02 kg liquid = 0.8982E+00 Moles total = 0.4985E+02 kg total = 0.8981E+00 Activity = 1.0000 Stoichiometric ionic strength = .1181562E-01 Osmotic coef. = 0.9504 True ionic strength = .2045984E-01 Chg. balance for total moles = -.5508E-08 Max. difference allowed = 0.1827E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.10142E-09 -9.9939 0.85101E-10 -10.0701 0.83912E+00 -0.0762 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.20244E-03 -3.6937 0.16884E-03 -3.7725 0.83399E+00 -0.0788 4 SO4-- 0.23699E-04 -4.6253 0.12237E-04 -4.9123 0.51636E+00 -0.2870 5 HCO3- 0.23477E-03 -3.6294 0.19609E-03 -3.7075 0.83523E+00 -0.0782 6 HS- 0.20996E-03 -3.6779 0.17514E-03 -3.7566 0.83412E+00 -0.0788 7 Al+++ 0.11578E-28 -28.9364 0.26402E-29 -29.5784 0.22803E+00 -0.6420 8 H4SiO4 0.79100E-03 -3.1018 0.79100E-03 -3.1018 0.10000E+01 0.0000 9 Ca++ 0.70030E-07 -7.1547 0.35891E-07 -7.4450 0.51250E+00 -0.2903 10 Mg++ 0.21641E-10 -10.6647 0.11039E-10 -10.9571 0.51012E+00 -0.2923 11 Fe++ 0.44589E-13 -13.3508 0.22771E-13 -13.6426 0.51069E+00 -0.2918 12 K+ 0.15655E-03 -3.8053 0.13079E-03 -3.8834 0.83543E+00 -0.0781 13 Na+ 0.19889E-01 -1.7014 0.16584E-01 -1.7803 0.83384E+00 -0.0789 14 Mn++ 0.24116E-10 -10.6177 0.12326E-10 -10.9092 0.51112E+00 -0.2915 15 F- 0.34802E-05 -5.4584 0.28964E-05 -5.5381 0.83224E+00 -0.0797 16 HPO4-- 0.45431E-07 -7.3426 0.23462E-07 -7.6296 0.51643E+00 -0.2870 18 HSiO3- 0.10407E-01 -1.9827 0.86790E-02 -2.0615 0.83399E+00 -0.0788 19 Ca(HSiO3)+ 0.84895E-08 -8.0711 0.70939E-08 -8.1491 0.83562E+00 -0.0780 20 Mg(HSiO3)+ 0.32497E-11 -11.4882 0.27155E-11 -11.5661 0.83562E+00 -0.0780 21 NaHSiO3,aq 0.23279E-02 -2.6330 0.23279E-02 -2.6330 0.10000E+01 0.0000 22 AlO+ 0.59354E-16 -16.2266 0.49597E-16 -16.3045 0.83562E+00 -0.0780 24 HAlO2,aq 0.11606E-09 -9.9353 0.11606E-09 -9.9353 0.10000E+01 0.0000 25 AlO2- 0.36266E-05 -5.4405 0.30190E-05 -5.5201 0.83246E+00 -0.0796 26 CH4,aq 0.27359E-08 -8.5629 0.27261E-08 -8.5645 0.99640E+00 -0.0016 31 CO,aq 0.21857E-15 -15.6604 0.21857E-15 -15.6604 0.10000E+01 0.0000 32 CO2,aq 0.35785E-07 -7.4463 0.35657E-07 -7.4479 0.99640E+00 -0.0016 33 CO3-2 0.39061E-03 -3.4083 0.20126E-03 -3.6962 0.51524E+00 -0.2880 34 CaCO3,aq 0.90574E-07 -7.0430 0.90574E-07 -7.0430 0.10000E+01 0.0000 35 Ca(HCO3)+ 0.21498E-09 -9.6676 0.17964E-09 -9.7456 0.83562E+00 -0.0780 36 CaCl+ 0.11736E-10 -10.9305 0.98064E-11 -11.0085 0.83562E+00 -0.0780 37 CaCl2,aq 0.39335E-15 -15.4052 0.39335E-15 -15.4052 0.10000E+01 0.0000 38 CaF+ 0.18163E-11 -11.7408 0.15177E-11 -11.8188 0.83562E+00 -0.0780 39 CaOH+ 0.35970E-07 -7.4441 0.30057E-07 -7.5220 0.83562E+00 -0.0780 40 CaSO4,aq 0.13946E-09 -9.8555 0.13946E-09 -9.8555 0.10000E+01 0.0000 41 HCl,aq 0.26329E-14 -14.5796 0.26329E-14 -14.5796 0.10000E+01 0.0000 45 HF,aq 0.16874E-11 -11.7728 0.16874E-11 -11.7728 0.10000E+01 0.0000 46 HF2- 0.19785E-17 -17.7037 0.16501E-17 -17.7825 0.83399E+00 -0.0788 48 FeCl+ 0.72825E-17 -17.1377 0.60853E-17 -17.2157 0.83562E+00 -0.0780 51 FeF+ 0.40334E-17 -17.3943 0.33704E-17 -17.4723 0.83562E+00 -0.0780 53 FeO,aq 0.12220E-09 -9.9129 0.12220E-09 -9.9129 0.10000E+01 0.0000 54 FeOH+ 0.10423E-10 -10.9820 0.87100E-11 -11.0600 0.83562E+00 -0.0780 55 HFeO2- 0.18016E-07 -7.7443 0.15025E-07 -7.8232 0.83399E+00 -0.0788 56 FeO+ 0.50330E-16 -16.2982 0.42056E-16 -16.3762 0.83562E+00 -0.0780 58 FeO2- 0.14248E-08 -8.8462 0.11883E-08 -8.9251 0.83399E+00 -0.0788 59 HFeO2,aq 0.12861E-10 -10.8907 0.12861E-10 -10.8907 0.10000E+01 0.0000 60 H2,aq 0.24490E-06 -6.6110 0.24402E-06 -6.6126 0.99640E+00 -0.0016 61 KCl,aq 0.40022E-09 -9.3977 0.40022E-09 -9.3977 0.10000E+01 0.0000 62 KHSO4,aq 0.38509E-18 -18.4144 0.38509E-18 -18.4144 0.10000E+01 0.0000 63 KOH,aq 0.65633E-06 -6.1829 0.65633E-06 -6.1829 0.10000E+01 0.0000 64 KSO4- 0.29779E-07 -7.5261 0.24835E-07 -7.6049 0.83399E+00 -0.0788 65 MgCO3,aq 0.69831E-11 -11.1560 0.69831E-11 -11.1560 0.10000E+01 0.0000 66 Mg(HCO3)+ 0.67569E-13 -13.1703 0.56462E-13 -13.2482 0.83562E+00 -0.0780 67 MgCl+ 0.32716E-14 -14.4852 0.27338E-14 -14.5632 0.83562E+00 -0.0780 68 MgF+ 0.20695E-14 -14.6841 0.17293E-14 -14.7621 0.83562E+00 -0.0780 69 MgOH+ 0.61223E-10 -10.2131 0.51159E-10 -10.2911 0.83562E+00 -0.0780 71 MnF+ 0.71965E-15 -15.1429 0.60135E-15 -15.2209 0.83562E+00 -0.0780 72 MnO,aq 0.17626E-08 -8.7538 0.17626E-08 -8.7538 0.10000E+01 0.0000 73 MnOH+ 0.52415E-09 -9.2805 0.43799E-09 -9.3585 0.83562E+00 -0.0780 74 MnO2-2 0.15677E-10 -10.8047 0.80773E-11 -11.0927 0.51524E+00 -0.2880 75 HMnO2- 0.18057E-09 -9.7434 0.15060E-09 -9.8222 0.83399E+00 -0.0788 78 MnCl+ 0.15337E-13 -13.8143 0.12815E-13 -13.8923 0.83562E+00 -0.0780 79 MnSO4,aq 0.43545E-13 -13.3611 0.43545E-13 -13.3611 0.10000E+01 0.0000 80 NaCl,aq 0.92791E-06 -6.0325 0.92791E-06 -6.0325 0.10000E+01 0.0000 81 NaF,aq 0.11246E-07 -7.9490 0.11246E-07 -7.9490 0.10000E+01 0.0000 82 NaOH,aq 0.83727E-04 -4.0771 0.83727E-04 -4.0771 0.10000E+01 0.0000 84 OH- 0.81557E-02 -2.0885 0.67893E-02 -2.1682 0.83246E+00 -0.0796 89 HPO3-2 0.34628E-16 -16.4606 0.17842E-16 -16.7486 0.51524E+00 -0.2880 92 H3PO4,aq 0.11884E-17 -17.9250 0.11884E-17 -17.9250 0.10000E+01 0.0000 93 H2PO4- 0.44122E-10 -10.3553 0.36833E-10 -10.4338 0.83479E+00 -0.0784 94 PO4-3 0.93841E-09 -9.0276 0.22494E-09 -9.6479 0.23970E+00 -0.6203 98 HP2O7-3 0.10934E-17 -17.9612 0.24960E-18 -18.6028 0.22827E+00 -0.6416 99 P2O7-4 0.92958E-17 -17.0317 0.70067E-18 -18.1545 0.75375E-01 -1.1228 100 H2S,aq 0.46229E-07 -7.3351 0.46063E-07 -7.3366 0.99640E+00 -0.0016 101 S2-2 0.54055E-11 -11.2672 0.27852E-11 -11.5551 0.51524E+00 -0.2880 102 S3-2 0.13747E-17 -17.8618 0.70832E-18 -18.1498 0.51524E+00 -0.2880 107 SO3-2 0.74219E-12 -12.1295 0.38804E-12 -12.4111 0.52283E+00 -0.2816 108 HSO3- 0.24792E-14 -14.6057 0.20676E-14 -14.6845 0.83399E+00 -0.0788 109 HSO4- 0.11998E-11 -11.9209 0.10036E-11 -11.9984 0.83644E+00 -0.0776 111 S2O3-2 0.12851E-13 -13.8911 0.66213E-14 -14.1791 0.51524E+00 -0.2880 Charge balance for all species = -.6132E-08 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.1014160E-09 -.2137995E-01 -.2151165E+02 0.0000 2 H2O 0.1000000E+01 0.5550376E+02 0.9981512E+06 0.0000 3 Cl- 0.2024432E-03 0.2033715E-03 0.7197399E+01 6.2975 4 SO4-- 0.2369861E-04 0.2366475E-04 0.2269259E+01 15.2278 5 HCO3- 0.2347704E-03 0.6255139E-03 0.3809971E+02 6.3625 6 HS- 0.2099650E-03 0.2100750E-03 0.6935332E+01 6.3134 7 Al+++ 0.1157826E-28 0.3626705E-05 0.9768114E-01 0.6318 8 H4SiO4 0.7910019E-03 0.1352555E-01 0.1297718E+04 -3.1018 9 Ca++ 0.7003008E-07 0.2054316E-06 0.8218748E-02 12.6951 10 Mg++ 0.2164097E-10 0.9316935E-10 0.2261133E-05 9.1831 11 Fe++ 0.4458938E-13 0.1958616E-07 0.1091897E-02 6.4975 12 K+ 0.1565522E-03 0.1572387E-03 0.6137491E+01 6.1866 13 Na+ 0.1988867E-01 0.2230124E-01 0.5117957E+03 8.2898 14 Mn++ 0.2411643E-10 0.2507212E-08 0.1374980E-03 9.2310 15 F- 0.3480238E-05 0.3491487E-05 0.6621413E-01 4.5319 16 HPO4-- 0.4543129E-07 0.4641383E-07 0.4446886E-02 12.5105 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.1920929E-01 -.1920314E-01 -.6146154E-05 0.0000000E+00 2 H2O 0.4985262E+02 0.4985263E+02 -.6076258E-05 0.0000000E+00 3 Cl- 0.1826652E-03 0.1826652E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.2125719E-04 0.2125531E-04 0.1875035E-08 0.0000000E+00 5 HCO3- 0.5618270E-03 0.5618270E-03 0.0000000E+00 0.0000000E+00 6 HS- 0.1886843E-03 0.1886862E-03 -.1875035E-08 0.0000000E+00 7 Al+++ 0.4775352E-05 0.3257451E-05 0.1517901E-05 0.0000000E+00 8 H4SiO4 0.1215302E-01 0.1214844E-01 0.4575136E-05 0.0000000E+00 9 Ca++ 0.2080835E-06 0.1845155E-06 0.2356799E-07 0.0000000E+00 10 Mg++ 0.8368328E-10 0.8368328E-10 0.0000000E+00 0.0000000E+00 11 Fe++ 0.3259227E-07 0.1759199E-07 0.1500028E-07 0.0000000E+00 12 K+ 0.1412294E-03 0.1412294E-03 0.0000000E+00 0.0000000E+00 13 Na+ 0.2003215E-01 0.2003063E-01 0.1517189E-05 0.0000000E+00 14 Mn++ 0.2251939E-08 0.2251939E-08 0.0000000E+00 0.0000000E+00 15 F- 0.3136000E-05 0.3136000E-05 0.0000000E+00 0.0000000E+00 16 HPO4-- 0.4168819E-07 0.4168819E-07 0.0000000E+00 0.0000000E+00 Chg. balance for solid moles: 0.0000E+00 Mass of aqueous solution: 0.899774E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 0.0075900 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 0.1517E-05 -5.819 0.3978E-03 -3.400 99.01 0.1527E-03 andradite 0.7500E-08 -8.125 0.3811E-05 -5.419 0.9486 0.9902E-06 grossular 0.3559E-09 -9.449 0.1603E-06 -6.795 0.3989E-01 0.4460E-07 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.9547E+00 0.9547E+00 1.0000 -0.020 grossular 0.4530E-01 0.4530E-01 1.0000 -1.344 Solid products produced: Mass = 0.000402 g Volume = 0.000154 cm3 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.0075900 moles log = -2.1198 Original solution: 1000.0103000 g Original solution / Rock added: 131753.66 (Water/Rock Ratio), log = 5.1198 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0206 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9997E+00 0.9859 0.1006E+01 0.1020E+01 CO2,gas 0.3711E-05 1.0071 0.3815E-05 0.3788E-05 CH4,gas 0.3883E-05 1.0125 0.4013E-05 0.3963E-05 H2,gas 0.3137E-03 1.0005 0.3204E-03 0.3202E-03 H2S,gas 0.1246E-05 0.9960 0.1266E-05 0.1271E-05 S2,gas 0.5745E-24 1.0000 0.5864E-24 0.5864E-24 CO,gas 0.3191E-12 1.0000 0.3257E-12 0.3257E-12 SO3,gas 0.3283E-40 1.0000 0.3351E-40 0.3351E-40 SO2,gas 0.4092E-21 1.0000 0.4176E-21 0.4176E-21 HF,gas 0.4059E-14 1.0000 0.4143E-14 0.4143E-14 HCl,gas 0.4552E-17 1.0000 0.4646E-17 0.4646E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 17 albite -0.38 -0.38 0.00 0.000 0.11184E-10 23 andradite 39.01 39.01 0.00 0.000 0.24265E-10 24 grossular 32.73 32.73 0.00 0.000 -0.12132E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -13.78 -7.12 -2.372 0.12153E+05 -5.419 3 CH4,gas 4.54 -2.55 -7.10 -1.774 0.12115E+05 -5.397 4 H2,gas 8.00 2.81 -5.19 -2.968 0.88675E+04 -3.494 5 H2S,gas -6.23 -13.83 -7.60 -3.798 0.12971E+05 -5.897 6 S2,gas -7.34 -33.27 -25.93 -3.989 0.44276E+05 -24.232 7 CO,gas 3.21 -10.97 -14.19 -4.365 0.24222E+05 -12.487 8 SO3,gas 17.12 -25.05 -42.17 -10.543 0.72011E+05 -40.475 9 SO2,gas 0.83 -22.25 -23.08 -6.154 0.39405E+05 -21.379 10 HF,gas 0.47 -15.61 -16.08 -8.041 0.27459E+05 -14.383 11 HCl,gas 5.19 -13.84 -19.03 -9.516 0.32496E+05 -17.333 12 acmite 7.71 7.18 -0.53 -0.055 0.90377E+03 16 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 20 spessartine 24.46 19.65 -4.81 -0.240 0.82065E+04 21 analcite 3.32 2.72 -0.60 -0.067 0.10312E+04 27 annite 20.12 17.01 -3.12 -0.173 0.53236E+04 28 phlogopite 27.06 25.06 -2.00 -0.111 0.34189E+04 30 anorthite 12.71 7.76 -4.96 -0.381 0.84608E+04 33 apatite-OH -18.15 -19.83 -1.68 -0.129 0.28689E+04 34 apatite-F -34.30 -35.44 -1.14 -0.095 0.19481E+04 38 aragonite 0.97 -1.08 -2.05 -0.683 0.34986E+04 39 brucite 12.57 9.18 -3.39 -0.677 0.57806E+04 40 calcite 0.81 -1.08 -1.89 -0.631 0.32344E+04 41 carnegieite-low 9.02 5.82 -3.20 -0.458 0.54699E+04 42 carnegieite-high 10.09 5.82 -4.27 -0.611 0.72969E+04 43 carpholite-Mg 8.58 4.24 -4.34 -0.289 0.74087E+04 45 celadonite 5.34 3.59 -1.75 -0.103 0.29835E+04 46 celadonite-Fe 3.88 0.91 -2.97 -0.175 0.50674E+04 47 chrysotile 23.89 21.35 -2.55 -0.212 0.43486E+04 49 clinochlore 39.07 37.87 -1.20 -0.037 0.20419E+04 50 daphnite 28.97 24.45 -4.52 -0.141 0.77168E+04 52 chlorite-Al-free 47.17 42.69 -4.48 -0.187 0.76523E+04 54 chloritoid-Fe 9.17 4.66 -4.51 -0.301 0.77079E+04 55 chloritoid-Mn 11.40 7.39 -4.01 -0.267 0.68439E+04 57 coesite -2.38 -3.10 -0.73 -0.242 0.12392E+04 64 cristobalite -2.56 -3.10 -0.54 -0.180 0.92457E+03 66 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71242E+04 68 diaspore 2.87 0.63 -2.24 -0.374 0.38279E+04 70 diopside 16.18 15.67 -0.51 -0.051 0.86535E+03 71 hedenbergite 14.21 12.99 -1.22 -0.122 0.20819E+04 78 epidote 24.67 22.44 -2.23 -0.108 0.38028E+04 79 clinozoisite 22.81 17.98 -4.83 -0.219 0.82398E+04 80 epidote-Fe 29.84 26.91 -2.94 -0.152 0.50124E+04 81 fayalite 14.05 9.89 -4.15 -0.593 0.70903E+04 82 ferrosilite 11.15 6.79 -4.36 -0.436 0.74413E+04 86 gibbsite 4.08 0.63 -3.45 -0.492 0.58864E+04 87 glaucophane 22.97 20.58 -2.40 -0.065 0.40927E+04 88 glaucophane-Fe 17.28 12.52 -4.75 -0.129 0.81184E+04 89 graphite -3.55 -8.16 -4.62 -1.320 0.78861E+04 90 greenalite 16.14 13.29 -2.85 -0.238 0.48673E+04 93 hematite 12.57 10.19 -2.38 -0.288 0.40597E+04 94 heulandite -5.83 -7.75 -1.93 -0.088 0.32898E+04 98 jadeite 4.22 2.72 -1.50 -0.150 0.25566E+04 99 julgoldite 70.43 65.54 -4.89 -0.127 0.83412E+04 100 kalsilite 7.58 3.72 -3.87 -0.552 0.66032E+04 101 kaolinite -1.33 -4.94 -3.61 -0.328 0.61592E+04 104 laumontite 2.88 1.55 -1.33 -0.089 0.22742E+04 105 lawsonite 9.62 7.76 -1.86 -0.124 0.31775E+04 106 leucite 4.12 0.61 -3.50 -0.350 0.59830E+04 108 lizardite 23.24 21.35 -1.90 -0.158 0.32412E+04 110 magnetite 20.09 16.69 -3.40 -0.278 0.58076E+04 111 minnesotaite 10.39 7.09 -3.30 -0.194 0.56395E+04 115 manganosite 14.06 9.23 -4.83 -1.207 0.82422E+04 119 microcline -2.49 -2.49 0.00 0.000 0.83310E+00 123 muscovite 2.58 -1.22 -3.81 -0.224 0.64982E+04 124 paragonite 4.24 0.88 -3.36 -0.198 0.57364E+04 125 nepheline 8.34 5.82 -2.52 -0.360 0.43023E+04 137 phlogopite-Na 29.65 27.17 -2.48 -0.138 0.42369E+04 139 prehnite 19.37 17.35 -2.02 -0.119 0.34549E+04 140 prehnite-Fe 22.50 21.81 -0.69 -0.041 0.11729E+04 141 pumpellyite-Fe 46.27 41.83 -4.44 -0.099 0.75865E+04 142 pumpellyite-Mg 48.99 44.51 -4.48 -0.100 0.76547E+04 145 pyrite -21.25 -23.96 -2.72 -0.639 0.46364E+04 146 pyrrhotite -4.26 -7.33 -3.07 -1.023 0.52400E+04 147 pyrrhotiteFe0.875 -6.02 -8.49 -2.47 -0.909 0.42216E+04 148 pyroxmangite 7.40 6.13 -1.27 -0.254 0.21677E+04 149 pyrophyllite -6.18 -11.14 -4.97 -0.310 0.84824E+04 150 quartz -2.99 -3.10 -0.11 -0.037 0.19190E+03 154 rhodochrosite -0.98 -4.55 -3.57 -1.190 0.60962E+04 155 rhodonite 7.45 6.13 -1.32 -0.263 0.22479E+04 156 sanidine -1.28 -2.49 -1.21 -0.093 0.20686E+04 158 siderite -2.61 -7.28 -4.67 -1.557 0.79772E+04 166 stilbite -7.52 -7.75 -0.23 -0.011 0.39596E+03 167 stilpnomelane-Fe 13.02 12.03 -0.99 -0.029 0.16852E+04 168 stilpnomelane-Mg 27.44 25.46 -1.98 -0.059 0.33869E+04 174 talc 16.49 15.14 -1.35 -0.079 0.23036E+04 177 tephroite 18.09 15.36 -2.73 -0.389 0.46540E+04 181 tridymite -2.63 -3.10 -0.48 -0.158 0.81188E+03 182 tremolite 47.87 46.49 -1.38 -0.037 0.23532E+04 184 troilite-low -4.41 -7.33 -2.92 -0.973 0.49828E+04 190 wairakite 3.95 1.55 -2.40 -0.141 0.40961E+04 191 walstromite 11.51 9.59 -1.92 -0.383 0.32714E+04 192 wollastonite 10.46 9.59 -0.87 -0.174 0.14818E+04 193 pseudo-wollastonite 11.00 9.59 -1.41 -0.281 0.24017E+04 194 zoisite 22.85 17.98 -4.87 -0.221 0.83139E+04 195 akaganeite 7.75 5.09 -2.66 -0.575 0.45424E+04 202 chalcedony -2.80 -3.10 -0.30 -0.100 0.51120E+03 204 montmorillonite-Ca -2.29 -6.23 -3.94 -0.244 0.67211E+04 205 montmorillonite-K -2.24 -6.28 -4.04 -0.248 0.69040E+04 206 montmorillonite-Mg -2.48 -6.81 -4.33 -0.268 0.73876E+04 207 montmorillonite-Na -2.04 -5.59 -3.55 -0.217 0.60586E+04 208 nontronite-Ca 3.21 1.11 -2.11 -0.137 0.35967E+04 209 nontronite-H 2.53 -0.99 -3.52 -0.236 0.60091E+04 210 nontronite-K 3.34 1.06 -2.29 -0.147 0.39027E+04 211 nontronite-Mg 3.07 0.53 -2.55 -0.165 0.43472E+04 212 nontronite-Na 3.52 1.75 -1.77 -0.114 0.30233E+04 228 tobermorite 9.82 7.47 -2.35 -0.641 0.40123E+04 234 alabandite -0.98 -4.60 -3.62 -1.206 0.61774E+04 237 boehmite 4.41 0.63 -3.77 -0.629 0.64448E+04 239 ferrous-oxide 9.81 6.50 -3.31 -0.829 0.56587E+04 245 silica-amorphous -2.09 -3.10 -1.01 -0.337 0.17254E+04 247 an20ab80 2.02 1.24 -0.77 -0.060 0.13213E+04 248 an25ab75 2.65 1.65 -0.99 -0.077 0.16986E+04 249 an30ab70 3.28 2.06 -1.22 -0.094 0.20855E+04 250 tr.625ac.25prg.125 45.16 44.03 -1.13 -0.030 0.19293E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 0.0002000 MOLES Current total amount of reactant added: 0.0075900 MOLES New total amount of reactant added: 0.0077900 MOLES Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.5508E-08 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 7 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 0.0077900 Water: Moles liquid = 0.4986E+02 kg liquid = 0.8982E+00 Moles total = 0.4985E+02 kg total = 0.8981E+00 Activity = 1.0000 Stoichiometric ionic strength = .1182844E-01 Osmotic coef. = 0.9501 True ionic strength = .2047119E-01 Chg. balance for total moles = -.5508E-08 Max. difference allowed = 0.1838E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.10180E-09 -9.9922 0.85421E-10 -10.0684 0.83909E+00 -0.0762 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.20375E-03 -3.6909 0.16992E-03 -3.7698 0.83396E+00 -0.0789 4 SO4-- 0.24760E-04 -4.6062 0.12783E-04 -4.8934 0.51628E+00 -0.2871 5 HCO3- 0.24136E-03 -3.6173 0.20159E-03 -3.6955 0.83520E+00 -0.0782 6 HS- 0.21431E-03 -3.6690 0.17875E-03 -3.7477 0.83408E+00 -0.0788 7 Al+++ 0.11635E-28 -28.9342 0.26522E-29 -29.5764 0.22796E+00 -0.6421 8 H4SiO4 0.79377E-03 -3.1003 0.79377E-03 -3.1003 0.10000E+01 0.0000 9 Ca++ 0.69479E-07 -7.1581 0.35603E-07 -7.4485 0.51243E+00 -0.2904 10 Mg++ 0.21657E-10 -10.6644 0.11046E-10 -10.9568 0.51004E+00 -0.2924 11 Fe++ 0.45652E-13 -13.3405 0.23311E-13 -13.6324 0.51061E+00 -0.2919 12 K+ 0.15655E-03 -3.8053 0.13078E-03 -3.8834 0.83540E+00 -0.0781 13 Na+ 0.19889E-01 -1.7014 0.16584E-01 -1.7803 0.83381E+00 -0.0789 14 Mn++ 0.24289E-10 -10.6146 0.12412E-10 -10.9061 0.51104E+00 -0.2915 15 F- 0.35690E-05 -5.4475 0.29702E-05 -5.5272 0.83221E+00 -0.0798 16 HPO4-- 0.45434E-07 -7.3426 0.23460E-07 -7.6297 0.51636E+00 -0.2870 18 HSiO3- 0.10404E-01 -1.9828 0.86768E-02 -2.0616 0.83396E+00 -0.0789 19 Ca(HSiO3)+ 0.84196E-08 -8.0747 0.70353E-08 -8.1527 0.83559E+00 -0.0780 20 Mg(HSiO3)+ 0.32509E-11 -11.4880 0.27164E-11 -11.5660 0.83559E+00 -0.0780 21 NaHSiO3,aq 0.23273E-02 -2.6331 0.23273E-02 -2.6331 0.10000E+01 0.0000 22 AlO+ 0.59179E-16 -16.2278 0.49449E-16 -16.3058 0.83559E+00 -0.0780 24 HAlO2,aq 0.11528E-09 -9.9382 0.11528E-09 -9.9382 0.10000E+01 0.0000 25 AlO2- 0.35888E-05 -5.4450 0.29875E-05 -5.5247 0.83243E+00 -0.0797 26 CH4,aq 0.27481E-08 -8.5610 0.27382E-08 -8.5625 0.99640E+00 -0.0016 31 CO,aq 0.22403E-15 -15.6497 0.22403E-15 -15.6497 0.10000E+01 0.0000 32 CO2,aq 0.36927E-07 -7.4327 0.36794E-07 -7.4342 0.99640E+00 -0.0016 33 CO3-2 0.40012E-03 -3.3978 0.20613E-03 -3.6859 0.51517E+00 -0.2880 34 CaCO3,aq 0.92020E-07 -7.0361 0.92020E-07 -7.0361 0.10000E+01 0.0000 35 Ca(HCO3)+ 0.21925E-09 -9.6591 0.18320E-09 -9.7371 0.83559E+00 -0.0780 36 CaCl+ 0.11717E-10 -10.9312 0.97903E-11 -11.0092 0.83559E+00 -0.0780 37 CaCl2,aq 0.39523E-15 -15.4032 0.39523E-15 -15.4032 0.10000E+01 0.0000 38 CaF+ 0.18477E-11 -11.7334 0.15439E-11 -11.8114 0.83559E+00 -0.0780 39 CaOH+ 0.35550E-07 -7.4492 0.29705E-07 -7.5272 0.83559E+00 -0.0780 40 CaSO4,aq 0.14452E-09 -9.8401 0.14452E-09 -9.8401 0.10000E+01 0.0000 41 HCl,aq 0.26598E-14 -14.5752 0.26598E-14 -14.5752 0.10000E+01 0.0000 45 HF,aq 0.17369E-11 -11.7602 0.17369E-11 -11.7602 0.10000E+01 0.0000 46 HF2- 0.20885E-17 -17.6802 0.17417E-17 -17.7590 0.83396E+00 -0.0789 48 FeCl+ 0.75031E-17 -17.1248 0.62695E-17 -17.2028 0.83559E+00 -0.0780 51 FeF+ 0.42343E-17 -17.3732 0.35381E-17 -17.4512 0.83559E+00 -0.0780 53 FeO,aq 0.12416E-09 -9.9060 0.12416E-09 -9.9060 0.10000E+01 0.0000 54 FeOH+ 0.10631E-10 -10.9734 0.88828E-11 -11.0514 0.83559E+00 -0.0780 55 HFeO2- 0.18236E-07 -7.7391 0.15208E-07 -7.8179 0.83396E+00 -0.0789 56 FeO+ 0.51504E-16 -16.2882 0.43036E-16 -16.3662 0.83559E+00 -0.0780 58 FeO2- 0.14471E-08 -8.8395 0.12068E-08 -8.9184 0.83396E+00 -0.0789 59 HFeO2,aq 0.13111E-10 -10.8824 0.13111E-10 -10.8824 0.10000E+01 0.0000 60 H2,aq 0.24326E-06 -6.6139 0.24238E-06 -6.6155 0.99640E+00 -0.0016 61 KCl,aq 0.40277E-09 -9.3949 0.40277E-09 -9.3949 0.10000E+01 0.0000 62 KHSO4,aq 0.40378E-18 -18.3939 0.40378E-18 -18.3939 0.10000E+01 0.0000 63 KOH,aq 0.65385E-06 -6.1845 0.65385E-06 -6.1845 0.10000E+01 0.0000 64 KSO4- 0.31108E-07 -7.5071 0.25943E-07 -7.5860 0.83396E+00 -0.0789 65 MgCO3,aq 0.71561E-11 -11.1453 0.71561E-11 -11.1453 0.10000E+01 0.0000 66 Mg(HCO3)+ 0.69506E-13 -13.1580 0.58078E-13 -13.2360 0.83559E+00 -0.0780 67 MgCl+ 0.32946E-14 -14.4822 0.27529E-14 -14.5602 0.83559E+00 -0.0780 68 MgF+ 0.21235E-14 -14.6729 0.17744E-14 -14.7510 0.83559E+00 -0.0780 69 MgOH+ 0.61030E-10 -10.2145 0.50996E-10 -10.2925 0.83559E+00 -0.0780 71 MnF+ 0.74316E-15 -15.1289 0.62097E-15 -15.2069 0.83559E+00 -0.0780 72 MnO,aq 0.17616E-08 -8.7541 0.17616E-08 -8.7541 0.10000E+01 0.0000 73 MnOH+ 0.52585E-09 -9.2791 0.43940E-09 -9.3571 0.83559E+00 -0.0780 74 MnO2-2 0.15553E-10 -10.8082 0.80123E-11 -11.0962 0.51517E+00 -0.2880 75 HMnO2- 0.17980E-09 -9.7452 0.14995E-09 -9.8241 0.83396E+00 -0.0789 78 MnCl+ 0.15543E-13 -13.8085 0.12988E-13 -13.8865 0.83559E+00 -0.0780 79 MnSO4,aq 0.45807E-13 -13.3391 0.45807E-13 -13.3391 0.10000E+01 0.0000 80 NaCl,aq 0.93387E-06 -6.0297 0.93387E-06 -6.0297 0.10000E+01 0.0000 81 NaF,aq 0.11532E-07 -7.9381 0.11532E-07 -7.9381 0.10000E+01 0.0000 82 NaOH,aq 0.83413E-04 -4.0788 0.83413E-04 -4.0788 0.10000E+01 0.0000 84 OH- 0.81254E-02 -2.0902 0.67638E-02 -2.1698 0.83243E+00 -0.0797 89 HPO3-2 0.34397E-16 -16.4635 0.17720E-16 -16.7515 0.51517E+00 -0.2880 92 H3PO4,aq 0.11973E-17 -17.9218 0.11973E-17 -17.9218 0.10000E+01 0.0000 93 H2PO4- 0.44286E-10 -10.3537 0.36969E-10 -10.4322 0.83476E+00 -0.0784 94 PO4-3 0.93511E-09 -9.0291 0.22408E-09 -9.6496 0.23963E+00 -0.6205 98 HP2O7-3 0.10977E-17 -17.9595 0.25050E-18 -18.6012 0.22819E+00 -0.6417 99 P2O7-4 0.92997E-17 -17.0315 0.70056E-18 -18.1546 0.75331E-01 -1.1230 100 H2S,aq 0.47362E-07 -7.3246 0.47192E-07 -7.3261 0.99640E+00 -0.0016 101 S2-2 0.56702E-11 -11.2464 0.29211E-11 -11.5345 0.51517E+00 -0.2880 102 S3-2 0.14874E-17 -17.8276 0.76625E-18 -18.1156 0.51517E+00 -0.2880 107 SO3-2 0.77022E-12 -12.1134 0.40263E-12 -12.3951 0.52275E+00 -0.2817 108 HSO3- 0.25822E-14 -14.5880 0.21535E-14 -14.6669 0.83396E+00 -0.0789 109 HSO4- 0.12582E-11 -11.9003 0.10523E-11 -11.9778 0.83641E+00 -0.0776 111 S2O3-2 0.13756E-13 -13.8615 0.70864E-14 -14.1496 0.51517E+00 -0.2880 Charge balance for all species = -.6132E-08 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.1018015E-09 -.2135574E-01 -.2148728E+02 0.0000 2 H2O 0.1000000E+01 0.5550374E+02 0.9981499E+06 0.0000 3 Cl- 0.2037502E-03 0.2046845E-03 0.7243860E+01 6.2987 4 SO4-- 0.2476007E-04 0.2472794E-04 0.2371209E+01 15.2435 5 HCO3- 0.2413615E-03 0.6416106E-03 0.3908012E+02 6.3729 6 HS- 0.2143111E-03 0.2144218E-03 0.7078831E+01 6.3207 7 Al+++ 0.1163484E-28 0.3588960E-05 0.9666445E-01 0.6289 8 H4SiO4 0.7937745E-03 0.1352539E-01 0.1297702E+04 -3.1003 9 Ca++ 0.6947937E-07 0.2058463E-06 0.8235333E-02 12.6884 10 Mg++ 0.2165676E-10 0.9316900E-10 0.2261123E-05 9.1801 11 Fe++ 0.4565235E-13 0.1983139E-07 0.1105567E-02 6.5044 12 K+ 0.1565528E-03 0.1572381E-03 0.6137463E+01 6.1850 13 Na+ 0.1988946E-01 0.2230112E-01 0.5117925E+03 8.2881 14 Mn++ 0.2428851E-10 0.2507202E-08 0.1374973E-03 9.2307 15 F- 0.3569006E-05 0.3580542E-05 0.6790296E-01 4.5412 16 HPO4-- 0.4543426E-07 0.4641365E-07 0.4446866E-02 12.5072 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.1918775E-01 -.1918147E-01 -.6280582E-05 0.0000000E+00 2 H2O 0.4985279E+02 0.4985279E+02 -.6211820E-05 0.0000000E+00 3 Cl- 0.1838452E-03 0.1838452E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.2221219E-04 0.2221034E-04 0.1847494E-08 0.0000000E+00 5 HCO3- 0.5762870E-03 0.5762870E-03 0.0000000E+00 0.0000000E+00 6 HS- 0.1925893E-03 0.1925911E-03 -.1847494E-08 0.0000000E+00 7 Al+++ 0.4775352E-05 0.3223561E-05 0.1551791E-05 0.0000000E+00 8 H4SiO4 0.1215302E-01 0.1214834E-01 0.4676517E-05 0.0000000E+00 9 Ca++ 0.2080835E-06 0.1848887E-06 0.2319482E-07 0.0000000E+00 10 Mg++ 0.8368328E-10 0.8368328E-10 0.0000000E+00 0.0000000E+00 11 Fe++ 0.3259227E-07 0.1781232E-07 0.1477995E-07 0.0000000E+00 12 K+ 0.1412294E-03 0.1412294E-03 0.0000000E+00 0.0000000E+00 13 Na+ 0.2003215E-01 0.2003060E-01 0.1551108E-05 0.0000000E+00 14 Mn++ 0.2251939E-08 0.2251939E-08 0.0000000E+00 0.0000000E+00 15 F- 0.3216000E-05 0.3216000E-05 0.0000000E+00 0.0000000E+00 16 HPO4-- 0.4168819E-07 0.4168819E-07 0.0000000E+00 0.0000000E+00 Chg. balance for solid moles: 0.2118E-21 Mass of aqueous solution: 0.899778E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 0.0077900 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 0.1551E-05 -5.809 0.4067E-03 -3.391 99.05 0.1561E-03 andradite 0.7390E-08 -8.131 0.3755E-05 -5.425 0.9145 0.9757E-06 grossular 0.3416E-09 -9.466 0.1539E-06 -6.813 0.3747E-01 0.4282E-07 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.9558E+00 0.9558E+00 1.0000 -0.020 grossular 0.4419E-01 0.4419E-01 1.0000 -1.355 Solid products produced: Mass = 0.000411 g Volume = 0.000157 cm3 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.0077900 moles log = -2.1085 Original solution: 1000.0103000 g Original solution / Rock added: 128371.03 (Water/Rock Ratio), log = 5.1085 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0206 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9997E+00 0.9859 0.1006E+01 0.1020E+01 CO2,gas 0.3830E-05 1.0071 0.3937E-05 0.3909E-05 CH4,gas 0.3900E-05 1.0125 0.4030E-05 0.3981E-05 H2,gas 0.3116E-03 1.0005 0.3182E-03 0.3180E-03 H2S,gas 0.1276E-05 0.9960 0.1297E-05 0.1302E-05 S2,gas 0.6112E-24 1.0000 0.6238E-24 0.6238E-24 CO,gas 0.3271E-12 1.0000 0.3339E-12 0.3339E-12 SO3,gas 0.3456E-40 1.0000 0.3527E-40 0.3527E-40 SO2,gas 0.4278E-21 1.0000 0.4366E-21 0.4366E-21 HF,gas 0.4178E-14 1.0000 0.4265E-14 0.4265E-14 HCl,gas 0.4598E-17 1.0000 0.4693E-17 0.4693E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 17 albite -0.38 -0.38 0.00 0.000 -0.94784E-12 23 andradite 39.01 39.01 0.00 0.000 -0.12132E-10 24 grossular 32.73 32.73 0.00 0.000 0.24265E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -13.76 -7.10 -2.368 0.12130E+05 -5.405 3 CH4,gas 4.54 -2.55 -7.09 -1.773 0.12112E+05 -5.395 4 H2,gas 8.00 2.80 -5.20 -2.969 0.88725E+04 -3.497 5 H2S,gas -6.23 -13.82 -7.59 -3.793 0.12953E+05 -5.887 6 S2,gas -7.34 -33.24 -25.90 -3.985 0.44230E+05 -24.205 7 CO,gas 3.21 -10.96 -14.18 -4.362 0.24204E+05 -12.476 8 SO3,gas 17.12 -25.03 -42.15 -10.538 0.71973E+05 -40.453 9 SO2,gas 0.83 -22.23 -23.06 -6.149 0.39372E+05 -21.360 10 HF,gas 0.47 -15.60 -16.07 -8.035 0.27438E+05 -14.370 11 HCl,gas 5.19 -13.84 -19.03 -9.514 0.32489E+05 -17.329 12 acmite 7.71 7.19 -0.52 -0.054 0.88708E+03 16 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 20 spessartine 24.46 19.65 -4.81 -0.240 0.82099E+04 21 analcite 3.32 2.72 -0.61 -0.067 0.10337E+04 27 annite 20.12 17.03 -3.10 -0.172 0.52883E+04 28 phlogopite 27.06 25.05 -2.01 -0.112 0.34344E+04 30 anorthite 12.71 7.75 -4.96 -0.382 0.84771E+04 33 apatite-OH -18.15 -19.86 -1.70 -0.131 0.29101E+04 34 apatite-F -34.30 -35.45 -1.15 -0.096 0.19678E+04 38 aragonite 0.97 -1.08 -2.04 -0.681 0.34869E+04 39 brucite 12.57 9.18 -3.39 -0.678 0.57858E+04 40 calcite 0.81 -1.08 -1.89 -0.629 0.32227E+04 41 carnegieite-low 9.02 5.82 -3.21 -0.458 0.54751E+04 42 carnegieite-high 10.09 5.82 -4.28 -0.611 0.73021E+04 43 carpholite-Mg 8.58 4.24 -4.34 -0.290 0.74186E+04 45 celadonite 5.34 3.59 -1.75 -0.103 0.29861E+04 46 celadonite-Fe 3.88 0.92 -2.96 -0.174 0.50531E+04 47 chrysotile 23.89 21.34 -2.55 -0.213 0.43588E+04 49 clinochlore 39.07 37.86 -1.21 -0.038 0.20699E+04 50 daphnite 28.97 24.48 -4.49 -0.140 0.76601E+04 52 chlorite-Al-free 47.17 42.68 -4.49 -0.187 0.76728E+04 54 chloritoid-Fe 9.17 4.66 -4.51 -0.301 0.77035E+04 55 chloritoid-Mn 11.40 7.39 -4.01 -0.268 0.68518E+04 57 coesite -2.38 -3.10 -0.72 -0.241 0.12366E+04 64 cristobalite -2.56 -3.10 -0.54 -0.180 0.92197E+03 66 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71242E+04 68 diaspore 2.87 0.63 -2.24 -0.374 0.38329E+04 70 diopside 16.18 15.67 -0.51 -0.051 0.87685E+03 71 hedenbergite 14.21 12.99 -1.22 -0.122 0.20765E+04 78 epidote 24.67 22.44 -2.23 -0.108 0.38138E+04 79 clinozoisite 22.81 17.96 -4.84 -0.220 0.82701E+04 80 epidote-Fe 29.84 26.91 -2.93 -0.152 0.50042E+04 81 fayalite 14.05 9.91 -4.14 -0.591 0.70641E+04 82 ferrosilite 11.15 6.81 -4.34 -0.434 0.74125E+04 86 gibbsite 4.08 0.63 -3.45 -0.493 0.58914E+04 87 glaucophane 22.97 20.57 -2.40 -0.065 0.41030E+04 88 glaucophane-Fe 17.28 12.54 -4.73 -0.128 0.80779E+04 89 graphite -3.55 -8.16 -4.61 -1.317 0.78728E+04 90 greenalite 16.14 13.31 -2.83 -0.236 0.48268E+04 93 hematite 12.57 10.21 -2.36 -0.286 0.40311E+04 94 heulandite -5.83 -7.76 -1.93 -0.088 0.32932E+04 98 jadeite 4.22 2.72 -1.50 -0.150 0.25592E+04 99 julgoldite 70.43 65.57 -4.86 -0.126 0.82911E+04 100 kalsilite 7.58 3.71 -3.87 -0.553 0.66084E+04 101 kaolinite -1.33 -4.94 -3.61 -0.328 0.61640E+04 104 laumontite 2.88 1.54 -1.34 -0.089 0.22853E+04 105 lawsonite 9.62 7.75 -1.87 -0.125 0.31938E+04 106 leucite 4.12 0.61 -3.51 -0.351 0.59856E+04 108 lizardite 23.24 21.34 -1.90 -0.159 0.32514E+04 110 magnetite 20.09 16.71 -3.38 -0.276 0.57672E+04 111 minnesotaite 10.39 7.11 -3.28 -0.193 0.55938E+04 115 manganosite 14.06 9.23 -4.83 -1.207 0.82426E+04 119 microcline -2.49 -2.49 0.00 0.000 0.85920E+00 123 muscovite 2.58 -1.23 -3.81 -0.224 0.65082E+04 124 paragonite 4.24 0.87 -3.37 -0.198 0.57464E+04 125 nepheline 8.34 5.82 -2.52 -0.360 0.43075E+04 137 phlogopite-Na 29.65 27.16 -2.49 -0.138 0.42523E+04 139 prehnite 19.37 17.33 -2.04 -0.120 0.34802E+04 140 prehnite-Fe 22.50 21.81 -0.69 -0.042 0.11790E+04 141 pumpellyite-Fe 46.27 41.80 -4.47 -0.099 0.76303E+04 142 pumpellyite-Mg 48.99 44.48 -4.52 -0.100 0.77154E+04 145 pyrite -21.25 -23.93 -2.68 -0.632 0.45837E+04 146 pyrrhotite -4.26 -7.31 -3.05 -1.017 0.52102E+04 147 pyrrhotiteFe0.875 -6.02 -8.47 -2.46 -0.903 0.41927E+04 148 pyroxmangite 7.40 6.13 -1.27 -0.254 0.21655E+04 149 pyrophyllite -6.18 -11.14 -4.97 -0.310 0.84820E+04 150 quartz -2.99 -3.10 -0.11 -0.037 0.18930E+03 154 rhodochrosite -0.98 -4.53 -3.56 -1.186 0.60734E+04 155 rhodonite 7.45 6.13 -1.32 -0.263 0.22458E+04 156 sanidine -1.28 -2.49 -1.21 -0.093 0.20686E+04 158 siderite -2.61 -7.26 -4.65 -1.550 0.79422E+04 166 stilbite -7.52 -7.76 -0.23 -0.011 0.39933E+03 167 stilpnomelane-Fe 13.02 12.07 -0.95 -0.028 0.16169E+04 168 stilpnomelane-Mg 27.44 25.45 -1.99 -0.059 0.34032E+04 174 talc 16.49 15.14 -1.35 -0.080 0.23086E+04 177 tephroite 18.09 15.36 -2.72 -0.389 0.46523E+04 181 tridymite -2.63 -3.10 -0.47 -0.158 0.80928E+03 182 tremolite 47.87 46.47 -1.39 -0.038 0.23813E+04 184 troilite-low -4.41 -7.31 -2.90 -0.967 0.49531E+04 190 wairakite 3.95 1.54 -2.41 -0.141 0.41073E+04 191 walstromite 11.51 9.59 -1.92 -0.384 0.32803E+04 192 wollastonite 10.46 9.59 -0.87 -0.175 0.14908E+04 193 pseudo-wollastonite 11.00 9.59 -1.41 -0.282 0.24106E+04 194 zoisite 22.85 17.96 -4.89 -0.222 0.83441E+04 195 akaganeite 7.75 5.10 -2.65 -0.573 0.45281E+04 202 chalcedony -2.80 -3.10 -0.30 -0.099 0.50860E+03 204 montmorillonite-Ca -2.29 -6.23 -3.94 -0.244 0.67227E+04 205 montmorillonite-K -2.24 -6.28 -4.04 -0.248 0.69046E+04 206 montmorillonite-Mg -2.48 -6.81 -4.33 -0.268 0.73881E+04 207 montmorillonite-Na -2.04 -5.59 -3.55 -0.217 0.60592E+04 208 nontronite-Ca 3.21 1.13 -2.09 -0.135 0.35621E+04 209 nontronite-H 2.53 -0.97 -3.50 -0.234 0.59726E+04 210 nontronite-K 3.34 1.08 -2.26 -0.145 0.38672E+04 211 nontronite-Mg 3.07 0.55 -2.53 -0.164 0.43116E+04 212 nontronite-Na 3.52 1.77 -1.75 -0.112 0.29878E+04 228 tobermorite 9.82 7.47 -2.35 -0.642 0.40193E+04 234 alabandite -0.98 -4.59 -3.61 -1.203 0.61599E+04 237 boehmite 4.41 0.63 -3.78 -0.630 0.64498E+04 239 ferrous-oxide 9.81 6.50 -3.31 -0.827 0.56469E+04 245 silica-amorphous -2.09 -3.10 -1.01 -0.336 0.17228E+04 247 an20ab80 2.02 1.24 -0.78 -0.060 0.13246E+04 248 an25ab75 2.65 1.65 -1.00 -0.077 0.17027E+04 249 an30ab70 3.28 2.05 -1.22 -0.094 0.20904E+04 250 tr.625ac.25prg.125 45.16 44.03 -1.14 -0.031 0.19384E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 0.0002000 MOLES Current total amount of reactant added: 0.0077900 MOLES New total amount of reactant added: 0.0079900 MOLES Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.5508E-08 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 7 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 0.0079900 Water: Moles liquid = 0.4986E+02 kg liquid = 0.8982E+00 Moles total = 0.4985E+02 kg total = 0.8981E+00 Activity = 1.0000 Stoichiometric ionic strength = .1184127E-01 Osmotic coef. = 0.9498 True ionic strength = .2048251E-01 Chg. balance for total moles = -.5508E-08 Max. difference allowed = 0.1850E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.10219E-09 -9.9906 0.85744E-10 -10.0668 0.83907E+00 -0.0762 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.20506E-03 -3.6881 0.17100E-03 -3.7670 0.83393E+00 -0.0789 4 SO4-- 0.25822E-04 -4.5880 0.13329E-04 -4.8752 0.51621E+00 -0.2872 5 HCO3- 0.24798E-03 -3.6056 0.20711E-03 -3.6838 0.83517E+00 -0.0782 6 HS- 0.21866E-03 -3.6602 0.18237E-03 -3.7390 0.83405E+00 -0.0788 7 Al+++ 0.11692E-28 -28.9321 0.26643E-29 -29.5744 0.22788E+00 -0.6423 8 H4SiO4 0.79656E-03 -3.0988 0.79656E-03 -3.0988 0.10000E+01 0.0000 9 Ca++ 0.68942E-07 -7.1615 0.35323E-07 -7.4519 0.51235E+00 -0.2904 10 Mg++ 0.21673E-10 -10.6641 0.11052E-10 -10.9565 0.50996E+00 -0.2925 11 Fe++ 0.46739E-13 -13.3303 0.23862E-13 -13.6223 0.51053E+00 -0.2920 12 K+ 0.15655E-03 -3.8053 0.13078E-03 -3.8835 0.83537E+00 -0.0781 13 Na+ 0.19890E-01 -1.7014 0.16584E-01 -1.7803 0.83377E+00 -0.0790 14 Mn++ 0.24462E-10 -10.6115 0.12499E-10 -10.9031 0.51096E+00 -0.2916 15 F- 0.36578E-05 -5.4368 0.30439E-05 -5.5166 0.83218E+00 -0.0798 16 HPO4-- 0.45437E-07 -7.3426 0.23459E-07 -7.6297 0.51628E+00 -0.2871 18 HSiO3- 0.10402E-01 -1.9829 0.86745E-02 -2.0618 0.83393E+00 -0.0789 19 Ca(HSiO3)+ 0.83514E-08 -8.0782 0.69780E-08 -8.1563 0.83556E+00 -0.0780 20 Mg(HSiO3)+ 0.32520E-11 -11.4878 0.27173E-11 -11.5659 0.83556E+00 -0.0780 21 NaHSiO3,aq 0.23267E-02 -2.6333 0.23267E-02 -2.6333 0.10000E+01 0.0000 22 AlO+ 0.59005E-16 -16.2291 0.49302E-16 -16.3071 0.83556E+00 -0.0780 24 HAlO2,aq 0.11451E-09 -9.9412 0.11451E-09 -9.9412 0.10000E+01 0.0000 25 AlO2- 0.35514E-05 -5.4496 0.29562E-05 -5.5293 0.83240E+00 -0.0797 26 CH4,aq 0.27625E-08 -8.5587 0.27525E-08 -8.5603 0.99639E+00 -0.0016 31 CO,aq 0.22957E-15 -15.6391 0.22957E-15 -15.6391 0.10000E+01 0.0000 32 CO2,aq 0.38082E-07 -7.4193 0.37945E-07 -7.4208 0.99639E+00 -0.0016 33 CO3-2 0.40959E-03 -3.3876 0.21098E-03 -3.6758 0.51509E+00 -0.2881 34 CaCO3,aq 0.93443E-07 -7.0295 0.93443E-07 -7.0295 0.10000E+01 0.0000 35 Ca(HCO3)+ 0.22349E-09 -9.6507 0.18674E-09 -9.7288 0.83556E+00 -0.0780 36 CaCl+ 0.11699E-10 -10.9319 0.97751E-11 -11.0099 0.83556E+00 -0.0780 37 CaCl2,aq 0.39713E-15 -15.4011 0.39713E-15 -15.4011 0.10000E+01 0.0000 38 CaF+ 0.18787E-11 -11.7261 0.15698E-11 -11.8042 0.83556E+00 -0.0780 39 CaOH+ 0.35138E-07 -7.4542 0.29360E-07 -7.5322 0.83556E+00 -0.0780 40 CaSO4,aq 0.14951E-09 -9.8253 0.14951E-09 -9.8253 0.10000E+01 0.0000 41 HCl,aq 0.26868E-14 -14.5708 0.26868E-14 -14.5708 0.10000E+01 0.0000 45 HF,aq 0.17867E-11 -11.7479 0.17867E-11 -11.7479 0.10000E+01 0.0000 46 HF2- 0.22019E-17 -17.6572 0.18362E-17 -17.7361 0.83393E+00 -0.0789 48 FeCl+ 0.77298E-17 -17.1118 0.64587E-17 -17.1899 0.83556E+00 -0.0780 51 FeF+ 0.44422E-17 -17.3524 0.37117E-17 -17.4304 0.83556E+00 -0.0780 53 FeO,aq 0.12614E-09 -9.8991 0.12614E-09 -9.8991 0.10000E+01 0.0000 54 FeOH+ 0.10842E-10 -10.9649 0.90588E-11 -11.0429 0.83556E+00 -0.0780 55 HFeO2- 0.18458E-07 -7.7338 0.15393E-07 -7.8127 0.83393E+00 -0.0789 56 FeO+ 0.52694E-16 -16.2782 0.44028E-16 -16.3563 0.83556E+00 -0.0780 58 FeO2- 0.14694E-08 -8.8329 0.12254E-08 -8.9117 0.83393E+00 -0.0789 59 HFeO2,aq 0.13363E-10 -10.8741 0.13363E-10 -10.8741 0.10000E+01 0.0000 60 H2,aq 0.24171E-06 -6.6167 0.24084E-06 -6.6183 0.99639E+00 -0.0016 61 KCl,aq 0.40533E-09 -9.3922 0.40533E-09 -9.3922 0.10000E+01 0.0000 62 KHSO4,aq 0.42261E-18 -18.3741 0.42261E-18 -18.3741 0.10000E+01 0.0000 63 KOH,aq 0.65137E-06 -6.1862 0.65137E-06 -6.1862 0.10000E+01 0.0000 64 KSO4- 0.32437E-07 -7.4890 0.27050E-07 -7.5678 0.83393E+00 -0.0789 65 MgCO3,aq 0.73287E-11 -11.1350 0.73287E-11 -11.1350 0.10000E+01 0.0000 66 Mg(HCO3)+ 0.71454E-13 -13.1460 0.59704E-13 -13.2240 0.83556E+00 -0.0780 67 MgCl+ 0.33177E-14 -14.4792 0.27721E-14 -14.5572 0.83556E+00 -0.0780 68 MgF+ 0.21776E-14 -14.6620 0.18195E-14 -14.7401 0.83556E+00 -0.0780 69 MgOH+ 0.60838E-10 -10.2158 0.50834E-10 -10.2938 0.83556E+00 -0.0780 71 MnF+ 0.76697E-15 -15.1152 0.64085E-15 -15.1932 0.83556E+00 -0.0780 72 MnO,aq 0.17606E-08 -8.7543 0.17606E-08 -8.7543 0.10000E+01 0.0000 73 MnOH+ 0.52756E-09 -9.2777 0.44081E-09 -9.3558 0.83556E+00 -0.0780 74 MnO2-2 0.15430E-10 -10.8116 0.79477E-11 -11.0998 0.51509E+00 -0.2881 75 HMnO2- 0.17903E-09 -9.7471 0.14930E-09 -9.8259 0.83393E+00 -0.0789 78 MnCl+ 0.15752E-13 -13.8027 0.13162E-13 -13.8807 0.83556E+00 -0.0780 79 MnSO4,aq 0.48098E-13 -13.3179 0.48098E-13 -13.3179 0.10000E+01 0.0000 80 NaCl,aq 0.93983E-06 -6.0270 0.93983E-06 -6.0270 0.10000E+01 0.0000 81 NaF,aq 0.11818E-07 -7.9274 0.11818E-07 -7.9274 0.10000E+01 0.0000 82 NaOH,aq 0.83100E-04 -4.0804 0.83100E-04 -4.0804 0.10000E+01 0.0000 84 OH- 0.80952E-02 -2.0918 0.67384E-02 -2.1714 0.83240E+00 -0.0797 89 HPO3-2 0.34181E-16 -16.4662 0.17606E-16 -16.7543 0.51509E+00 -0.2881 92 H3PO4,aq 0.12062E-17 -17.9186 0.12062E-17 -17.9186 0.10000E+01 0.0000 93 H2PO4- 0.44452E-10 -10.3521 0.37105E-10 -10.4306 0.83473E+00 -0.0785 94 PO4-3 0.93181E-09 -9.0307 0.22322E-09 -9.6513 0.23956E+00 -0.6206 98 HP2O7-3 0.11021E-17 -17.9578 0.25140E-18 -18.5996 0.22812E+00 -0.6418 99 P2O7-4 0.93036E-17 -17.0313 0.70045E-18 -18.1546 0.75288E-01 -1.1233 100 H2S,aq 0.48504E-07 -7.3142 0.48329E-07 -7.3158 0.99639E+00 -0.0016 101 S2-2 0.59407E-11 -11.2262 0.30600E-11 -11.5143 0.51509E+00 -0.2881 102 S3-2 0.16061E-17 -17.7942 0.82730E-18 -18.0823 0.51509E+00 -0.2881 107 SO3-2 0.79812E-12 -12.0979 0.41716E-12 -12.3797 0.52268E+00 -0.2818 108 HSO3- 0.26856E-14 -14.5710 0.22396E-14 -14.6498 0.83393E+00 -0.0789 109 HSO4- 0.13169E-11 -11.8804 0.11014E-11 -11.9580 0.83638E+00 -0.0776 111 S2O3-2 0.14691E-13 -13.8330 0.75672E-14 -14.1211 0.51509E+00 -0.2881 Charge balance for all species = -.6132E-08 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.1021894E-09 -.2133154E-01 -.2146291E+02 0.0000 2 H2O 0.1000000E+01 0.5550371E+02 0.9981486E+06 0.0000 3 Cl- 0.2050573E-03 0.2059975E-03 0.7290321E+01 6.2998 4 SO4-- 0.2582154E-04 0.2579113E-04 0.2473158E+01 15.2584 5 HCO3- 0.2479819E-03 0.6577072E-03 0.4006052E+02 6.3830 6 HS- 0.2186571E-03 0.2187686E-03 0.7222328E+01 6.3278 7 Al+++ 0.1169183E-28 0.3551530E-05 0.9565623E-01 0.6260 8 H4SiO4 0.7965626E-03 0.1352523E-01 0.1297685E+04 -3.0988 9 Ca++ 0.6894223E-07 0.2062618E-06 0.8251948E-02 12.6816 10 Mg++ 0.2167261E-10 0.9316864E-10 0.2261113E-05 9.1770 11 Fe++ 0.4673920E-13 0.2007832E-07 0.1119332E-02 6.5113 12 K+ 0.1565533E-03 0.1572375E-03 0.6137435E+01 6.1833 13 Na+ 0.1989024E-01 0.2230100E-01 0.5117893E+03 8.2865 14 Mn++ 0.2446208E-10 0.2507193E-08 0.1374967E-03 9.2305 15 F- 0.3657774E-05 0.3669596E-05 0.6959177E-01 4.5502 16 HPO4-- 0.4543722E-07 0.4641348E-07 0.4446846E-02 12.5039 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.1916622E-01 -.1915980E-01 -.6413875E-05 0.0000000E+00 2 H2O 0.4985295E+02 0.4985296E+02 -.6346249E-05 0.0000000E+00 3 Cl- 0.1850252E-03 0.1850252E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.2316719E-04 0.2316537E-04 0.1819762E-08 0.0000000E+00 5 HCO3- 0.5907470E-03 0.5907470E-03 0.0000000E+00 0.0000000E+00 6 HS- 0.1964943E-03 0.1964961E-03 -.1819762E-08 0.0000000E+00 7 Al+++ 0.4775352E-05 0.3189954E-05 0.1585398E-05 0.0000000E+00 8 H4SiO4 0.1215302E-01 0.1214824E-01 0.4777048E-05 0.0000000E+00 9 Ca++ 0.2080835E-06 0.1852626E-06 0.2282095E-07 0.0000000E+00 10 Mg++ 0.8368328E-10 0.8368328E-10 0.0000000E+00 0.0000000E+00 11 Fe++ 0.3259227E-07 0.1803417E-07 0.1455810E-07 0.0000000E+00 12 K+ 0.1412294E-03 0.1412294E-03 0.0000000E+00 0.0000000E+00 13 Na+ 0.2003215E-01 0.2003057E-01 0.1584742E-05 0.0000000E+00 14 Mn++ 0.2251939E-08 0.2251939E-08 0.0000000E+00 0.0000000E+00 15 F- 0.3296000E-05 0.3296000E-05 0.0000000E+00 0.0000000E+00 16 HPO4-- 0.4168819E-07 0.4168819E-07 0.0000000E+00 0.0000000E+00 Chg. balance for solid moles: -.2118E-21 Mass of aqueous solution: 0.899782E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 0.0079900 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 0.1585E-05 -5.800 0.4156E-03 -3.381 99.08 0.1595E-03 andradite 0.7279E-08 -8.138 0.3699E-05 -5.432 0.8820 0.9610E-06 grossular 0.3279E-09 -9.484 0.1477E-06 -6.831 0.3522E-01 0.4110E-07 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.9569E+00 0.9569E+00 1.0000 -0.019 grossular 0.4311E-01 0.4311E-01 1.0000 -1.365 Solid products produced: Mass = 0.000419 g Volume = 0.000161 cm3 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.0079900 moles log = -2.0975 Original solution: 1000.0103000 g Original solution / Rock added: 125157.73 (Water/Rock Ratio), log = 5.0975 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0206 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9997E+00 0.9859 0.1006E+01 0.1020E+01 CO2,gas 0.3950E-05 1.0071 0.4060E-05 0.4031E-05 CH4,gas 0.3921E-05 1.0125 0.4052E-05 0.4001E-05 H2,gas 0.3096E-03 1.0005 0.3162E-03 0.3160E-03 H2S,gas 0.1307E-05 0.9960 0.1329E-05 0.1334E-05 S2,gas 0.6493E-24 1.0000 0.6627E-24 0.6627E-24 CO,gas 0.3352E-12 1.0000 0.3421E-12 0.3421E-12 SO3,gas 0.3630E-40 1.0000 0.3705E-40 0.3705E-40 SO2,gas 0.4466E-21 1.0000 0.4558E-21 0.4558E-21 HF,gas 0.4298E-14 1.0000 0.4387E-14 0.4387E-14 HCl,gas 0.4645E-17 1.0000 0.4741E-17 0.4741E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 17 albite -0.38 -0.38 0.00 0.000 0.11184E-10 23 andradite 39.01 39.01 0.00 0.000 0.00000E+00 24 grossular 32.73 32.73 0.00 0.000 0.24265E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -13.75 -7.09 -2.363 0.12107E+05 -5.392 3 CH4,gas 4.54 -2.55 -7.09 -1.773 0.12108E+05 -5.392 4 H2,gas 8.00 2.80 -5.20 -2.971 0.88772E+04 -3.500 5 H2S,gas -6.23 -13.81 -7.58 -3.788 0.12935E+05 -5.877 6 S2,gas -7.34 -33.21 -25.88 -3.981 0.44185E+05 -24.179 7 CO,gas 3.21 -10.95 -14.16 -4.358 0.24186E+05 -12.466 8 SO3,gas 17.12 -25.01 -42.13 -10.533 0.71936E+05 -40.431 9 SO2,gas 0.83 -22.21 -23.04 -6.144 0.39341E+05 -21.341 10 HF,gas 0.47 -15.58 -16.06 -8.028 0.27417E+05 -14.358 11 HCl,gas 5.19 -13.83 -19.02 -9.512 0.32481E+05 -17.324 12 acmite 7.71 7.20 -0.51 -0.053 0.87056E+03 16 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 20 spessartine 24.46 19.65 -4.81 -0.241 0.82134E+04 21 analcite 3.32 2.71 -0.61 -0.067 0.10363E+04 27 annite 20.12 17.05 -3.08 -0.171 0.52530E+04 28 phlogopite 27.06 25.04 -2.02 -0.112 0.34499E+04 30 anorthite 12.71 7.74 -4.97 -0.383 0.84934E+04 33 apatite-OH -18.15 -19.88 -1.73 -0.133 0.29508E+04 34 apatite-F -34.30 -35.47 -1.16 -0.097 0.19875E+04 38 aragonite 0.97 -1.07 -2.04 -0.678 0.34755E+04 39 brucite 12.57 9.18 -3.39 -0.678 0.57909E+04 40 calcite 0.81 -1.07 -1.88 -0.627 0.32113E+04 41 carnegieite-low 9.02 5.81 -3.21 -0.459 0.54803E+04 42 carnegieite-high 10.09 5.81 -4.28 -0.611 0.73073E+04 43 carpholite-Mg 8.58 4.23 -4.35 -0.290 0.74286E+04 45 celadonite 5.34 3.59 -1.75 -0.103 0.29887E+04 46 celadonite-Fe 3.88 0.93 -2.95 -0.174 0.50388E+04 47 chrysotile 23.89 21.33 -2.56 -0.213 0.43691E+04 49 clinochlore 39.07 37.84 -1.23 -0.038 0.20979E+04 50 daphnite 28.97 24.51 -4.45 -0.139 0.76035E+04 52 chlorite-Al-free 47.17 42.67 -4.51 -0.188 0.76934E+04 54 chloritoid-Fe 9.17 4.66 -4.51 -0.301 0.76992E+04 55 chloritoid-Mn 11.40 7.38 -4.02 -0.268 0.68596E+04 57 coesite -2.38 -3.10 -0.72 -0.241 0.12340E+04 64 cristobalite -2.56 -3.10 -0.54 -0.179 0.91937E+03 66 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71243E+04 68 diaspore 2.87 0.63 -2.25 -0.375 0.38379E+04 70 diopside 16.18 15.66 -0.52 -0.052 0.88826E+03 71 hedenbergite 14.21 13.00 -1.21 -0.121 0.20710E+04 78 epidote 24.67 22.43 -2.24 -0.109 0.38248E+04 79 clinozoisite 22.81 17.94 -4.86 -0.221 0.83002E+04 80 epidote-Fe 29.84 26.91 -2.93 -0.152 0.49960E+04 81 fayalite 14.05 9.92 -4.12 -0.589 0.70380E+04 82 ferrosilite 11.15 6.83 -4.32 -0.432 0.73838E+04 86 gibbsite 4.08 0.63 -3.45 -0.493 0.58965E+04 87 glaucophane 22.97 20.57 -2.41 -0.065 0.41132E+04 88 glaucophane-Fe 17.28 12.57 -4.71 -0.127 0.80374E+04 89 graphite -3.55 -8.15 -4.60 -1.315 0.78594E+04 90 greenalite 16.14 13.34 -2.80 -0.234 0.47863E+04 93 hematite 12.57 10.22 -2.34 -0.284 0.40029E+04 94 heulandite -5.83 -7.76 -1.93 -0.088 0.32964E+04 98 jadeite 4.22 2.71 -1.50 -0.150 0.25618E+04 99 julgoldite 70.43 65.60 -4.83 -0.125 0.82414E+04 100 kalsilite 7.58 3.71 -3.87 -0.553 0.66137E+04 101 kaolinite -1.33 -4.95 -3.61 -0.328 0.61688E+04 104 laumontite 2.88 1.54 -1.34 -0.090 0.22964E+04 105 lawsonite 9.62 7.74 -1.88 -0.125 0.32101E+04 106 leucite 4.12 0.61 -3.51 -0.351 0.59883E+04 108 lizardite 23.24 21.33 -1.91 -0.159 0.32617E+04 110 magnetite 20.09 16.73 -3.35 -0.274 0.57272E+04 111 minnesotaite 10.39 7.14 -3.25 -0.191 0.55481E+04 115 manganosite 14.06 9.23 -4.83 -1.207 0.82431E+04 119 microcline -2.49 -2.49 0.00 0.000 0.88540E+00 123 muscovite 2.58 -1.24 -3.82 -0.225 0.65182E+04 124 paragonite 4.24 0.87 -3.37 -0.198 0.57564E+04 125 nepheline 8.34 5.81 -2.53 -0.361 0.43127E+04 137 phlogopite-Na 29.65 27.15 -2.50 -0.139 0.42678E+04 139 prehnite 19.37 17.32 -2.05 -0.121 0.35054E+04 140 prehnite-Fe 22.50 21.80 -0.69 -0.042 0.11850E+04 141 pumpellyite-Fe 46.27 41.78 -4.49 -0.100 0.76739E+04 142 pumpellyite-Mg 48.99 44.44 -4.55 -0.101 0.77758E+04 145 pyrite -21.25 -23.90 -2.65 -0.625 0.45319E+04 146 pyrrhotite -4.26 -7.29 -3.03 -1.011 0.51808E+04 147 pyrrhotiteFe0.875 -6.02 -8.46 -2.44 -0.897 0.41642E+04 148 pyroxmangite 7.40 6.13 -1.27 -0.253 0.21633E+04 149 pyrophyllite -6.18 -11.14 -4.97 -0.310 0.84816E+04 150 quartz -2.99 -3.10 -0.11 -0.036 0.18670E+03 154 rhodochrosite -0.98 -4.52 -3.54 -1.181 0.60509E+04 155 rhodonite 7.45 6.13 -1.31 -0.263 0.22436E+04 156 sanidine -1.28 -2.49 -1.21 -0.093 0.20686E+04 158 siderite -2.61 -7.24 -4.63 -1.544 0.79076E+04 166 stilbite -7.52 -7.76 -0.24 -0.011 0.40260E+03 167 stilpnomelane-Fe 13.02 12.11 -0.91 -0.027 0.15488E+04 168 stilpnomelane-Mg 27.44 25.44 -2.00 -0.060 0.34197E+04 174 talc 16.49 15.14 -1.36 -0.080 0.23137E+04 177 tephroite 18.09 15.36 -2.72 -0.389 0.46505E+04 181 tridymite -2.63 -3.10 -0.47 -0.157 0.80668E+03 182 tremolite 47.87 46.46 -1.41 -0.038 0.24092E+04 184 troilite-low -4.41 -7.29 -2.88 -0.961 0.49237E+04 190 wairakite 3.95 1.54 -2.41 -0.142 0.41184E+04 191 walstromite 11.51 9.58 -1.93 -0.385 0.32892E+04 192 wollastonite 10.46 9.58 -0.88 -0.176 0.14996E+04 193 pseudo-wollastonite 11.00 9.58 -1.42 -0.283 0.24195E+04 194 zoisite 22.85 17.94 -4.90 -0.223 0.83743E+04 195 akaganeite 7.75 5.11 -2.64 -0.572 0.45140E+04 202 chalcedony -2.80 -3.10 -0.30 -0.099 0.50600E+03 204 montmorillonite-Ca -2.29 -6.23 -3.94 -0.244 0.67242E+04 205 montmorillonite-K -2.24 -6.28 -4.04 -0.248 0.69052E+04 206 montmorillonite-Mg -2.48 -6.81 -4.33 -0.268 0.73886E+04 207 montmorillonite-Na -2.04 -5.59 -3.55 -0.217 0.60598E+04 208 nontronite-Ca 3.21 1.15 -2.07 -0.134 0.35279E+04 209 nontronite-H 2.53 -0.94 -3.48 -0.233 0.59365E+04 210 nontronite-K 3.34 1.10 -2.24 -0.144 0.38320E+04 211 nontronite-Mg 3.07 0.57 -2.50 -0.162 0.42763E+04 212 nontronite-Na 3.52 1.79 -1.73 -0.111 0.29526E+04 228 tobermorite 9.82 7.47 -2.36 -0.643 0.40263E+04 234 alabandite -0.98 -4.58 -3.60 -1.199 0.61426E+04 237 boehmite 4.41 0.63 -3.78 -0.630 0.64548E+04 239 ferrous-oxide 9.81 6.51 -3.30 -0.825 0.56351E+04 245 silica-amorphous -2.09 -3.10 -1.01 -0.336 0.17202E+04 247 an20ab80 2.02 1.24 -0.78 -0.060 0.13278E+04 248 an25ab75 2.65 1.65 -1.00 -0.077 0.17068E+04 249 an30ab70 3.28 2.05 -1.23 -0.094 0.20953E+04 250 tr.625ac.25prg.125 45.16 44.02 -1.14 -0.031 0.19474E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 0.0002000 MOLES Current total amount of reactant added: 0.0079900 MOLES New total amount of reactant added: 0.0081900 MOLES Mixing fraction reached given limit of 0.8000E-02 TOTMIX = 0.8190E-02 Execution stopped.