File SKIP_SPECIES.TXT lists species and minerals omitted from the calculations due to given T, P, option switches, or suppression in CHIMRUN, or are suppressed in the SOLTHERM database. It also lists minerals for which density is not specified in SOLTHERM. This is an extended P(to 5 kB), T(to 600 C) run (CON_FLAG = 1). methanol,aq is suppressed in SOLTHERM data file. methanol,aq is suppressed in SOLTHERM data file. CuCl4-3 is suppressed in SOLTHERM data file. H2BO3- is suppressed in SOLTHERM data file. UO2CO3,aq is suppressed in SOLTHERM data file. UO2SO4,aq is suppressed in SOLTHERM data file. UO2Cl2,aq is suppressed in SOLTHERM data file. UO2F2,aq is suppressed in SOLTHERM data file. PO4-3 is suppressed in SOLTHERM data file. H2PO4- is suppressed in SOLTHERM data file. H3PO4 is suppressed in SOLTHERM data file. O2,gas is suppressed in THIS RUN. O2,gas is suppressed in THIS RUN. amesite is suppressed in SOLTHERM data file. antigorite is suppressed in SOLTHERM data file. goethite is suppressed in THIS RUN. goethite is suppressed in THIS RUN. riebeckite is suppressed in THIS RUN. riebeckite is suppressed in THIS RUN. sapphirine-Fe(221) is suppressed in SOLTHERM data file. sapphirine(221) is suppressed in SOLTHERM data file. talc-prl is suppressed in SOLTHERM data file. PrO1.833(s) is suppressed in SOLTHERM data file. niter-NH4 is suppressed in SOLTHERM data file. FMQ_HS-1 is suppressed in THIS RUN. kf-ab-equil is suppressed in THIS RUN. ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Species No. Charge Tot.moles Trial molality Gamma Mixing solution H+ 1 1. -0.19166E-01 0.10219E-09 0.8391 0.00000000E+00 H2O 2 0. 0.49853E+02 0.10000E+01 1.0000 0.00000000E+00 Cl- 3 -1. 0.18503E-03 0.20506E-03 0.8339 0.00000000E+00 SO4-- 4 -2. 0.23167E-04 0.25822E-04 0.5162 0.00000000E+00 HCO3- 5 -1. 0.59075E-03 0.24798E-03 0.8352 0.00000000E+00 HS- 6 -1. 0.19649E-03 0.21866E-03 0.8341 0.00000000E+00 Al+++ 7 3. 0.47754E-05 0.11692E-28 0.2279 0.00000000E+00 H4SiO4 8 0. 0.12153E-01 0.79656E-03 1.0000 0.00000000E+00 Ca++ 9 2. 0.20808E-06 0.68942E-07 0.5124 0.00000000E+00 Mg++ 10 2. 0.83683E-10 0.21673E-10 0.5100 0.00000000E+00 Fe++ 11 2. 0.32592E-07 0.46739E-13 0.5105 0.00000000E+00 K+ 12 1. 0.14123E-03 0.15655E-03 0.8354 0.00000000E+00 Na+ 13 1. 0.20032E-01 0.19890E-01 0.8338 0.00000000E+00 Mn++ 14 2. 0.22519E-08 0.24462E-10 0.5110 0.00000000E+00 F- 15 -1. 0.32960E-05 0.36578E-05 0.8322 0.00000000E+00 HPO4-- 16 -2. 0.41688E-07 0.45437E-07 0.5163 0.00000000E+00 Chg. balance for total moles = -.5508E-08 Max. difference allowed = 0.1850E-07 The following parameters were given: ERPC = 0.1000E-11 pH = 0.0000 PFLUID = 50.0000 SLIM = 0.200000E-01 TEMP = 100.0000 SINC = 0.4000E-03 TEMPC = 0.0000 TOTMIX = 0.799000E-02 ENTH = 0.0000 SENTH = 0.0000 DENTH = 0.0000 TOTWAT = 90.0000 SOLMIN = 0.0000E+00 RM = 0.0000 AQGRM = 1000.0103 SUPRNT = 0.1000E-19 VBOX-1 = 400.9996 RHOFRS = 0.0000 RHOROC = 2.5000 The following options were selected: CONFLG = 1 C = 3 IFRAC = 0 IPUNCH = 2 NLOOP = 400 ISTEP = 2 LIMSOL = 1 LOOC = 0 IENTH = 0 ITREF = 0 IDEAL = 0 IPSAT = 1 INCREM = 0 INCP = 0 MINSOL = 3 NEUT = 0 AWAT = 0 CHGF = 0 Of the derived species, only those with molality > 0.10E-19 will appear in the output Species No. Charge Log K(diss) Species No. Charge Log K(diss) SiF6-2 17 -2. -24.5019 Mn+3 70 3. 19.1453 HSiO3- 18 -1. 9.0298 MnF+ 71 1. -1.2264 Ca(HSiO3)+ 19 1. 7.6723 MnO,aq 72 0. 17.9848 Mg(HSiO3)+ 20 1. 7.5773 MnOH+ 73 1. 8.5194 NaHSiO3,aq 21 0. 7.8210 MnO2-2 74 -2. 40.4638 AlO+ 22 1. 6.8663 HMnO2- 75 -1. 29.1232 AlOH+2 23 2. 3.1691 MnO4- 76 -1. 83.3111 HAlO2,aq 24 0. 10.5671 MnO4-2 77 -2. 81.3005 AlO2- 25 -1. 16.2221 MnCl+ 78 1. -0.7894 CH4,aq 26 0. 6.0126 MnSO4,aq 79 0. -2.4604 C2H6,aq 27 0. 12.3733 NaCl,aq 80 0. 0.4796 C3H8,aq 28 0. 17.3707 NaF,aq 81 0. 0.6306 C4H10,aq 29 0. 22.3757 NaOH,aq 82 0. 12.3669 ethanol,aq 30 0. 15.3258 O2,aq 83 0. 53.5502 CO,aq 31 0. 4.6892 OH- 84 -1. 12.2382 CO2,aq 32 0. -6.3298 HO2- 85 -1. 50.8010 CO3-2 33 -2. 10.0588 H2O2,aq 86 0. 40.0166 CaCO3,aq 34 0. 5.9605 H3PO2,aq 87 0. 24.3066 Ca(HCO3)+ 35 1. -1.4070 H2PO2- 88 -1. 26.5366 CaCl+ 36 1. -0.2091 HPO3-2 89 -2. 11.9254 CaCl2,aq 37 0. 0.4151 H3PO3,aq 90 0. 3.5792 CaF+ 38 1. -1.1644 H2PO3- 91 -1. 5.6232 CaOH+ 39 1. 10.1471 H3PO4,aq 92 0. -9.8447 CaSO4,aq 40 0. -2.5018 H2PO4- 93 -1. -7.2659 HCl,aq 41 0. 0.7370 PO4-3 94 -3. 12.0884 HClO,aq 42 0. 32.4260 H4P2O7,aq 95 0. -17.8095 ClO- 43 -1. 39.6530 H3P2O7- 96 -1. -15.9156 HClO2,aq 44 0. 70.1812 H2P2O7-2 97 -2. -13.4262 HF,aq 45 0. -3.8354 HP2O7-3 98 -3. -6.7266 HF2- 46 -1. -3.3639 P2O7-4 99 -4. 2.8952 Fe+3 47 3. 8.3809 H2S,aq 100 0. -6.4900 FeCl+ 48 1. -0.1994 S2-2 101 -2. 1.2355 FeCl2,aq 49 0. 4.3001 S3-2 102 -2. -8.8031 FeCl+2 50 2. 6.5269 S3- 103 -1. -16.3389 FeF+ 51 1. -1.7084 S4-2 104 -2. -18.6615 FeF+2 52 2. 1.4309 S5-2 105 -2. -28.3439 FeO,aq 53 0. 16.4104 SO2,aq 106 0. -0.2309 FeOH+ 54 1. 7.4874 SO3-2 107 -2. 10.3052 HFeO2- 55 -1. 24.3908 HSO3- 108 -1. 2.5086 FeO+ 56 1. 11.4004 HSO4- 109 -1. -2.9839 FeOH+2 57 2. 9.1194 HSO5- 110 -1. 38.8366 FeO2- 58 -1. 24.0895 S2O3-2 111 -2. -4.5600 HFeO2,aq 59 0. 15.9850 HS2O3- 112 -1. -6.8123 H2,aq 60 0. 9.4190 H2S2O3,aq 113 0. -8.0173 KCl,aq 61 0. 1.7417 S2O4-2 114 -2. 10.5541 KHSO4,aq 62 0. -0.4514 HS2O4- 115 -1. 7.6551 KOH,aq 63 0. 12.3695 H2S2O4,aq 116 0. 6.6259 KSO4- 64 -1. -1.1908 S2O5-2 117 -2. 10.0741 MgCO3,aq 65 0. 6.5614 S2O6-2 118 -2. 11.5521 Mg(HCO3)+ 66 1. -1.4164 S2O8-2 119 -2. 42.0620 MgCl+ 67 1. -0.1664 S3O6-2 120 -2. 3.7866 MgF+ 68 1. -1.7331 S4O6-2 121 -2. -17.8657 MgOH+ 69 1. 9.4041 S5O6-2 122 -2. -14.1333 For mixed gases (JSOLS=6), log K(hydrol) = log (K*P) Log K Trial Log K Trial Mineral No. hydrol Moles Mineral No. hydrol Moles H2O,gas 1 1.696 0.0000E+00 osumilite(1) 126 21.717 0.0000E+00 CO2,gas 2 -6.660 0.0000E+00 osumilite(2) 127 20.667 0.0000E+00 CH4,gas 3 4.544 0.0000E+00 osumilite-Fe 128 14.390 0.0000E+00 H2,gas 4 8.000 0.0000E+00 pargasite 129 65.092 0.0000E+00 H2S,gas 5 -6.230 0.0000E+00 periclase 130 16.138 0.0000E+00 S2,gas 6 -7.335 0.0000E+00 periclase-Fe 131 11.627 0.0000E+00 CO,gas 7 3.215 0.0000E+00 perovskite-Al 132 12.344 0.0000E+00 SO3,gas 8 17.121 0.0000E+00 perovskite-Ca 133 23.807 0.0000E+00 SO2,gas 9 0.832 0.0000E+00 perovskite-Fe 134 21.143 0.0000E+00 HF,gas 10 0.473 0.0000E+00 perovskite-Mg 135 23.119 0.0000E+00 HCl,gas 11 5.189 0.0000E+00 phase_A 136 80.189 0.0000E+00 acmite 12 7.710 0.0000E+00 phlogopite-Na 137 29.647 0.0000E+00 akermanite 13 36.442 0.0000E+00 piemontite(ordered) 138 33.776 0.0000E+00 akimotoite 14 16.591 0.0000E+00 prehnite 139 19.372 0.0000E+00 akimotoite-Fe 15 13.067 0.0000E+00 prehnite-Fe 140 22.498 0.0000E+00 albite-high 16 0.693 0.0000E+00 pumpellyite-Fe 141 46.269 0.0000E+00 albite 17 -0.384 0.1585E-05 pumpellyite-Mg 142 48.995 0.0000E+00 almandine 18 24.442 0.0000E+00 px-Mg-tschermaks 143 19.616 0.0000E+00 pyrope 19 37.248 0.0000E+00 px-Ca-tschermaks 144 18.610 0.0000E+00 spessartine 20 24.457 0.0000E+00 pyrite 145 -21.247 0.0000E+00 analcite 21 3.322 0.0000E+00 pyrrhotite 146 -4.260 0.0000E+00 andalusite 22 5.002 0.0000E+00 pyrrhotiteFe0.875 147 -6.017 0.0000E+00 andradite 23 39.009 0.7279E-08 pyroxmangite 148 7.399 0.0000E+00 grossular 24 32.731 0.3279E-09 pyrophyllite 149 -6.176 0.0000E+00 anhydrite 25 -5.317 0.0000E+00 quartz 150 -2.989 0.0000E+00 ankerite 26 -2.135 0.0000E+00 rankinite 151 40.713 0.0000E+00 annite 27 20.123 0.0000E+00 ringwoodite-Fe 152 15.456 0.0000E+00 phlogopite 28 27.065 0.0000E+00 ringwoodite-Mg 153 27.575 0.0000E+00 biotite-Mn 29 32.960 0.0000E+00 rhodochrosite 154 -0.976 0.0000E+00 anorthite 30 12.710 0.0000E+00 rhodonite 155 7.446 0.0000E+00 anthophyllite 31 51.852 0.0000E+00 sanidine 156 -1.275 0.0000E+00 anthophyllite-Fe 32 29.306 0.0000E+00 sapphirine(351) 157 78.899 0.0000E+00 apatite-OH 33 -18.153 0.0000E+00 siderite 158 -2.608 0.0000E+00 apatite-F 34 -34.301 0.0000E+00 sillimanite 159 5.262 0.0000E+00 apatite-OH-zs 35 -12.736 0.0000E+00 sodalite 160 49.976 0.0000E+00 apatite-F-zs 36 -27.774 0.0000E+00 spinel 161 20.870 0.0000E+00 apatite-Cl-zs 37 -16.674 0.0000E+00 spurrite 162 59.482 0.0000E+00 aragonite 38 0.967 0.0000E+00 staurolite-Fe 163 73.598 0.0000E+00 brucite 39 12.569 0.0000E+00 staurolite-Mg 164 89.802 0.0000E+00 calcite 40 0.812 0.0000E+00 staurolite-Mn 165 83.909 0.0000E+00 carnegieite-low 41 9.023 0.0000E+00 stilbite 166 -7.522 0.0000E+00 carnegieite-high 42 10.093 0.0000E+00 stilpnomelane-Fe 167 13.017 0.0000E+00 carpholite-Mg 43 8.582 0.0000E+00 stilpnomelane-Mg 168 27.441 0.0000E+00 carpholite-Fe 44 6.713 0.0000E+00 stishovite 169 2.720 0.0000E+00 celadonite 45 5.342 0.0000E+00 sudoite-Fe 170 18.296 0.0000E+00 celadonite-Fe 46 3.877 0.0000E+00 sudoite 171 21.077 0.0000E+00 chrysotile 47 23.892 0.0000E+00 sulfur 172 -9.152 0.0000E+00 chondrodite 48 56.475 0.0000E+00 sylvite 173 1.338 0.0000E+00 clinochlore 49 39.070 0.0000E+00 talc 174 16.491 0.0000E+00 daphnite 50 28.965 0.0000E+00 talc-Fe 175 13.448 0.0000E+00 chlorite-Mn 51 46.869 0.0000E+00 talc-tschermaks 176 19.091 0.0000E+00 chlorite-Al-free 52 47.173 0.0000E+00 tephroite 177 18.086 0.0000E+00 chloritoid-Mg 53 13.198 0.0000E+00 tilleyite 178 41.377 0.0000E+00 chloritoid-Fe 54 9.174 0.0000E+00 titanite-CaSi 179 15.479 0.0000E+00 chloritoid-Mn 55 11.401 0.0000E+00 topaz-H 180 4.618 0.0000E+00 clinohumite 56 97.128 0.0000E+00 tridymite 181 -2.626 0.0000E+00 coesite 57 -2.376 0.0000E+00 tremolite 182 47.869 0.0000E+00 cordierite-H 58 23.715 0.0000E+00 ferroactinolite 183 38.452 0.0000E+00 cordierite 59 24.049 0.0000E+00 troilite-low 184 -4.411 0.0000E+00 cordierite-Fe 60 20.450 0.0000E+00 tschermakite 185 48.210 0.0000E+00 cordierite-Mn 61 25.066 0.0000E+00 vesuvianite 186 223.471 0.0000E+00 corundum 62 8.383 0.0000E+00 wadeite-Si 187 20.216 0.0000E+00 corundum-MgSi 63 18.891 0.0000E+00 wadsleyite-Fe 188 15.680 0.0000E+00 cristobalite 64 -2.560 0.0000E+00 wadsleyite-Mg 189 25.850 0.0000E+00 cummingtonite 65 52.099 0.0000E+00 wairakite 190 3.950 0.0000E+00 cymrite-K 66 1.685 0.0000E+00 walstromite 191 11.509 0.0000E+00 deerite 67 95.671 0.0000E+00 wollastonite 192 10.461 0.0000E+00 diaspore 68 2.874 0.0000E+00 pseudo-wollastonite 193 11.000 0.0000E+00 diamond 69 -3.102 0.0000E+00 zoisite 194 22.849 0.0000E+00 diopside 70 16.181 0.0000E+00 akaganeite 195 7.755 0.0000E+00 hedenbergite 71 14.208 0.0000E+00 beidellite-Ca 196 -1.646 0.0000E+00 dolomite,ordered 72 0.546 0.0000E+00 beidellite-H 197 -2.326 0.0000E+00 eastonite 73 28.489 0.0000E+00 beidellite-K 198 -1.520 0.0000E+00 enstatite 74 17.265 0.0000E+00 beidellite-Mg 199 -1.790 0.0000E+00 clinoenstatite-HiP 75 18.354 0.0000E+00 beidellite-Na 200 -1.342 0.0000E+00 clinoenstatite 76 17.166 0.0000E+00 calcium 201 84.026 0.0000E+00 protoenstatite 77 17.824 0.0000E+00 chalcedony 202 -2.802 0.0000E+00 epidote 78 24.670 0.0000E+00 dawsonite 203 1.682 0.0000E+00 clinozoisite 79 22.806 0.0000E+00 montmorillonite-Ca 204 -2.291 0.0000E+00 epidote-Fe 80 29.841 0.0000E+00 montmorillonite-K 205 -2.237 0.0000E+00 fayalite 81 14.046 0.0000E+00 montmorillonite-Mg 206 -2.480 0.0000E+00 ferrosilite 82 11.149 0.0000E+00 montmorillonite-Na 207 -2.038 0.0000E+00 forsterite 83 21.016 0.0000E+00 nontronite-Ca 208 3.215 0.0000E+00 gedrite 84 50.522 0.0000E+00 nontronite-H 209 2.533 0.0000E+00 gehlenite 85 36.628 0.0000E+00 nontronite-K 210 3.341 0.0000E+00 gibbsite 86 4.079 0.0000E+00 nontronite-Mg 211 3.075 0.0000E+00 glaucophane 87 22.975 0.0000E+00 nontronite-Na 212 3.520 0.0000E+00 glaucophane-Fe 88 17.276 0.0000E+00 sepiolite 213 24.118 0.0000E+00 graphite 89 -3.546 0.0000E+00 topaz 214 -16.546 0.0000E+00 greenalite 90 16.140 0.0000E+00 alite 215 57.999 0.0000E+00 grunerite 91 31.215 0.0000E+00 belite 216 30.433 0.0000E+00 halite 92 1.575 0.0000E+00 ettringite 217 43.232 0.0000E+00 hematite 93 12.566 0.0000E+00 gypsum 218 -4.955 0.0000E+00 heulandite 94 -5.827 0.0000E+00 hemicarboaluminate 219 70.954 0.0000E+00 hercynite 95 17.279 0.0000E+00 hydrogarnet 220 60.662 0.0000E+00 hollandite 96 25.673 0.0000E+00 hydrogarnet-Si 221 50.586 0.0000E+00 iron 97 19.086 0.0000E+00 jennite 222 24.367 0.0000E+00 jadeite 98 4.215 0.0000E+00 monosulfoaluminate 223 53.400 0.0000E+00 julgoldite 99 70.427 0.0000E+00 monocarboaluminate 224 61.898 0.0000E+00 kalsilite 100 7.584 0.0000E+00 portlandite 225 18.272 0.0000E+00 kaolinite 101 -1.333 0.0000E+00 stratlingite 226 36.502 0.0000E+00 kyanite 102 4.876 0.0000E+00 tricarboaluminate 227 70.370 0.0000E+00 larnite-bredigite 103 30.686 0.0000E+00 tobermorite 228 9.823 0.0000E+00 laumontite 104 2.883 0.0000E+00 C4AH13 229 81.816 0.0000E+00 lawsonite 105 9.616 0.0000E+00 C2AH8 230 45.203 0.0000E+00 leucite 106 4.119 0.0000E+00 C3A 231 86.953 0.0000E+00 lime 107 25.998 0.0000E+00 C4AF 232 117.416 0.0000E+00 lizardite 108 23.244 0.0000E+00 CAH10 233 28.335 0.0000E+00 magnesite 109 0.691 0.0000E+00 alabandite 234 -0.978 0.0000E+00 magnetite 110 20.087 0.0000E+00 alunite 235 -10.435 0.0000E+00 minnesotaite 111 10.388 0.0000E+00 artinite 236 15.121 0.0000E+00 minnesotaite-Mg 112 20.602 0.0000E+00 boehmite 237 4.406 0.0000E+00 magnesioferrite 113 26.212 0.0000E+00 dolomite,disordered 238 1.247 0.0000E+00 majorite 114 53.251 0.0000E+00 ferrous-oxide 239 9.812 0.0000E+00 manganosite 115 14.058 0.0000E+00 fluorite 240 -9.931 0.0000E+00 margarite 116 17.324 0.0000E+00 huntite 241 3.770 0.0000E+00 meionite 117 44.874 0.0000E+00 hydromagnesite 242 19.995 0.0000E+00 merwinite 118 55.930 0.0000E+00 nesquehonite 243 4.723 0.0000E+00 microcline 119 -2.486 0.0000E+00 potassium-oxide 244 69.038 0.0000E+00 monticellite 120 24.339 0.0000E+00 silica-amorphous 245 -2.091 0.0000E+00 mullite-Al 121 363.148 0.0000E+00 sodium-oxide 246 55.169 0.0000E+00 mullite-Si 122 7.264 0.0000E+00 an20ab80 247 2.018 0.0000E+00 muscovite 123 2.582 0.0000E+00 an25ab75 248 2.646 0.0000E+00 paragonite 124 4.239 0.0000E+00 an30ab70 249 3.279 0.0000E+00 nepheline 125 8.339 0.0000E+00 tr.625ac.25prg.125 250 45.165 0.0000E+00 Initial composition of reactant (mole%): H2O 88.87 HCl 0.5900 CO2 7.070 CO 0.1600 H2 1.540 S2 0.8000E-01 SO2 1.150 HF 0.4000E-01 H2S 1.120 0.000 Sum of wt% of reactants: 100.6200 Reactant consumed: 0.0079900 moles log = -2.0975 Original solution: 1000.0103000 g Original solution / Rock added: 125157.73 (Water/Rock Ratio), log = 5.0975 The following minerals and/or gases with identical index are in solid solution: H2O,gas 6 CO2,gas 6 CH4,gas 6 H2,gas 6 H2S,gas 6 S2,gas 6 CO,gas 6 SO3,gas 6 SO2,gas 6 HF,gas 6 HCl,gas 6 almandine 16 pyrope 16 spessartine 16 andradite 8 grossular 8 annite 15 phlogopite 15 biotite-Mn 15 clinochlore 1 daphnite 1 chlorite-Mn 1 diopside 5 hedenbergite 5 epidote 3 clinozoisite 3 iron 9 magnetite 14 talc 7 talc-Fe 7 tremolite 2 ferroactinolite 2 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 10 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 0.0079900 Water: Moles liquid = 0.4986E+02 kg liquid = 0.8982E+00 Moles total = 0.4985E+02 kg total = 0.8981E+00 Activity = 1.0000 Stoichiometric ionic strength = .1184127E-01 Osmotic coef. = 0.9498 True ionic strength = .2048251E-01 Chg. balance for total moles = -.5508E-08 Max. difference allowed = 0.1850E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.10219E-09 -9.9906 0.85744E-10 -10.0668 0.83907E+00 -0.0762 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.20506E-03 -3.6881 0.17100E-03 -3.7670 0.83393E+00 -0.0789 4 SO4-- 0.25822E-04 -4.5880 0.13329E-04 -4.8752 0.51621E+00 -0.2872 5 HCO3- 0.24798E-03 -3.6056 0.20711E-03 -3.6838 0.83517E+00 -0.0782 6 HS- 0.21866E-03 -3.6602 0.18237E-03 -3.7390 0.83405E+00 -0.0788 7 Al+++ 0.11692E-28 -28.9321 0.26643E-29 -29.5744 0.22788E+00 -0.6423 8 H4SiO4 0.79656E-03 -3.0988 0.79656E-03 -3.0988 0.10000E+01 0.0000 9 Ca++ 0.68942E-07 -7.1615 0.35323E-07 -7.4519 0.51235E+00 -0.2904 10 Mg++ 0.21673E-10 -10.6641 0.11052E-10 -10.9565 0.50996E+00 -0.2925 11 Fe++ 0.46739E-13 -13.3303 0.23862E-13 -13.6223 0.51053E+00 -0.2920 12 K+ 0.15655E-03 -3.8053 0.13078E-03 -3.8835 0.83537E+00 -0.0781 13 Na+ 0.19890E-01 -1.7014 0.16584E-01 -1.7803 0.83377E+00 -0.0790 14 Mn++ 0.24462E-10 -10.6115 0.12499E-10 -10.9031 0.51096E+00 -0.2916 15 F- 0.36578E-05 -5.4368 0.30439E-05 -5.5166 0.83218E+00 -0.0798 16 HPO4-- 0.45437E-07 -7.3426 0.23459E-07 -7.6297 0.51628E+00 -0.2871 18 HSiO3- 0.10402E-01 -1.9829 0.86745E-02 -2.0618 0.83393E+00 -0.0789 19 Ca(HSiO3)+ 0.83514E-08 -8.0782 0.69780E-08 -8.1563 0.83556E+00 -0.0780 20 Mg(HSiO3)+ 0.32520E-11 -11.4878 0.27173E-11 -11.5659 0.83556E+00 -0.0780 21 NaHSiO3,aq 0.23267E-02 -2.6333 0.23267E-02 -2.6333 0.10000E+01 0.0000 22 AlO+ 0.59005E-16 -16.2291 0.49302E-16 -16.3071 0.83556E+00 -0.0780 24 HAlO2,aq 0.11451E-09 -9.9412 0.11451E-09 -9.9412 0.10000E+01 0.0000 25 AlO2- 0.35514E-05 -5.4496 0.29562E-05 -5.5293 0.83240E+00 -0.0797 26 CH4,aq 0.27625E-08 -8.5587 0.27525E-08 -8.5603 0.99639E+00 -0.0016 31 CO,aq 0.22957E-15 -15.6391 0.22957E-15 -15.6391 0.10000E+01 0.0000 32 CO2,aq 0.38082E-07 -7.4193 0.37945E-07 -7.4208 0.99639E+00 -0.0016 33 CO3-2 0.40959E-03 -3.3876 0.21098E-03 -3.6758 0.51509E+00 -0.2881 34 CaCO3,aq 0.93443E-07 -7.0295 0.93443E-07 -7.0295 0.10000E+01 0.0000 35 Ca(HCO3)+ 0.22349E-09 -9.6507 0.18674E-09 -9.7288 0.83556E+00 -0.0780 36 CaCl+ 0.11699E-10 -10.9319 0.97751E-11 -11.0099 0.83556E+00 -0.0780 37 CaCl2,aq 0.39713E-15 -15.4011 0.39713E-15 -15.4011 0.10000E+01 0.0000 38 CaF+ 0.18787E-11 -11.7261 0.15698E-11 -11.8042 0.83556E+00 -0.0780 39 CaOH+ 0.35138E-07 -7.4542 0.29360E-07 -7.5322 0.83556E+00 -0.0780 40 CaSO4,aq 0.14951E-09 -9.8253 0.14951E-09 -9.8253 0.10000E+01 0.0000 41 HCl,aq 0.26868E-14 -14.5708 0.26868E-14 -14.5708 0.10000E+01 0.0000 45 HF,aq 0.17867E-11 -11.7479 0.17867E-11 -11.7479 0.10000E+01 0.0000 46 HF2- 0.22019E-17 -17.6572 0.18362E-17 -17.7361 0.83393E+00 -0.0789 48 FeCl+ 0.77298E-17 -17.1118 0.64587E-17 -17.1899 0.83556E+00 -0.0780 51 FeF+ 0.44422E-17 -17.3524 0.37117E-17 -17.4304 0.83556E+00 -0.0780 53 FeO,aq 0.12614E-09 -9.8991 0.12614E-09 -9.8991 0.10000E+01 0.0000 54 FeOH+ 0.10842E-10 -10.9649 0.90588E-11 -11.0429 0.83556E+00 -0.0780 55 HFeO2- 0.18458E-07 -7.7338 0.15393E-07 -7.8127 0.83393E+00 -0.0789 56 FeO+ 0.52694E-16 -16.2782 0.44028E-16 -16.3563 0.83556E+00 -0.0780 58 FeO2- 0.14694E-08 -8.8329 0.12254E-08 -8.9117 0.83393E+00 -0.0789 59 HFeO2,aq 0.13363E-10 -10.8741 0.13363E-10 -10.8741 0.10000E+01 0.0000 60 H2,aq 0.24171E-06 -6.6167 0.24084E-06 -6.6183 0.99639E+00 -0.0016 61 KCl,aq 0.40533E-09 -9.3922 0.40533E-09 -9.3922 0.10000E+01 0.0000 62 KHSO4,aq 0.42261E-18 -18.3741 0.42261E-18 -18.3741 0.10000E+01 0.0000 63 KOH,aq 0.65137E-06 -6.1862 0.65137E-06 -6.1862 0.10000E+01 0.0000 64 KSO4- 0.32437E-07 -7.4890 0.27050E-07 -7.5678 0.83393E+00 -0.0789 65 MgCO3,aq 0.73287E-11 -11.1350 0.73287E-11 -11.1350 0.10000E+01 0.0000 66 Mg(HCO3)+ 0.71454E-13 -13.1460 0.59704E-13 -13.2240 0.83556E+00 -0.0780 67 MgCl+ 0.33177E-14 -14.4792 0.27721E-14 -14.5572 0.83556E+00 -0.0780 68 MgF+ 0.21776E-14 -14.6620 0.18195E-14 -14.7401 0.83556E+00 -0.0780 69 MgOH+ 0.60838E-10 -10.2158 0.50834E-10 -10.2938 0.83556E+00 -0.0780 71 MnF+ 0.76697E-15 -15.1152 0.64085E-15 -15.1932 0.83556E+00 -0.0780 72 MnO,aq 0.17606E-08 -8.7543 0.17606E-08 -8.7543 0.10000E+01 0.0000 73 MnOH+ 0.52756E-09 -9.2777 0.44081E-09 -9.3558 0.83556E+00 -0.0780 74 MnO2-2 0.15430E-10 -10.8116 0.79477E-11 -11.0998 0.51509E+00 -0.2881 75 HMnO2- 0.17903E-09 -9.7471 0.14930E-09 -9.8259 0.83393E+00 -0.0789 78 MnCl+ 0.15752E-13 -13.8027 0.13162E-13 -13.8807 0.83556E+00 -0.0780 79 MnSO4,aq 0.48098E-13 -13.3179 0.48098E-13 -13.3179 0.10000E+01 0.0000 80 NaCl,aq 0.93983E-06 -6.0270 0.93983E-06 -6.0270 0.10000E+01 0.0000 81 NaF,aq 0.11818E-07 -7.9274 0.11818E-07 -7.9274 0.10000E+01 0.0000 82 NaOH,aq 0.83100E-04 -4.0804 0.83100E-04 -4.0804 0.10000E+01 0.0000 84 OH- 0.80952E-02 -2.0918 0.67384E-02 -2.1714 0.83240E+00 -0.0797 89 HPO3-2 0.34181E-16 -16.4662 0.17606E-16 -16.7543 0.51509E+00 -0.2881 92 H3PO4,aq 0.12062E-17 -17.9186 0.12062E-17 -17.9186 0.10000E+01 0.0000 93 H2PO4- 0.44452E-10 -10.3521 0.37105E-10 -10.4306 0.83473E+00 -0.0785 94 PO4-3 0.93181E-09 -9.0307 0.22322E-09 -9.6513 0.23956E+00 -0.6206 98 HP2O7-3 0.11021E-17 -17.9578 0.25140E-18 -18.5996 0.22812E+00 -0.6418 99 P2O7-4 0.93036E-17 -17.0313 0.70045E-18 -18.1546 0.75288E-01 -1.1233 100 H2S,aq 0.48504E-07 -7.3142 0.48329E-07 -7.3158 0.99639E+00 -0.0016 101 S2-2 0.59407E-11 -11.2262 0.30600E-11 -11.5143 0.51509E+00 -0.2881 102 S3-2 0.16061E-17 -17.7942 0.82730E-18 -18.0823 0.51509E+00 -0.2881 107 SO3-2 0.79812E-12 -12.0979 0.41716E-12 -12.3797 0.52268E+00 -0.2818 108 HSO3- 0.26856E-14 -14.5710 0.22396E-14 -14.6498 0.83393E+00 -0.0789 109 HSO4- 0.13169E-11 -11.8804 0.11014E-11 -11.9580 0.83638E+00 -0.0776 111 S2O3-2 0.14691E-13 -13.8330 0.75672E-14 -14.1211 0.51509E+00 -0.2881 Charge balance for all species = -.6132E-08 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.1021894E-09 -.2133154E-01 -.2146291E+02 0.0000 2 H2O 0.1000000E+01 0.5550371E+02 0.9981486E+06 0.0000 3 Cl- 0.2050573E-03 0.2059975E-03 0.7290321E+01 6.2998 4 SO4-- 0.2582154E-04 0.2579113E-04 0.2473158E+01 15.2584 5 HCO3- 0.2479819E-03 0.6577072E-03 0.4006052E+02 6.3830 6 HS- 0.2186571E-03 0.2187686E-03 0.7222328E+01 6.3278 7 Al+++ 0.1169183E-28 0.3551530E-05 0.9565623E-01 0.6260 8 H4SiO4 0.7965626E-03 0.1352523E-01 0.1297685E+04 -3.0988 9 Ca++ 0.6894223E-07 0.2062618E-06 0.8251948E-02 12.6816 10 Mg++ 0.2167261E-10 0.9316864E-10 0.2261113E-05 9.1770 11 Fe++ 0.4673920E-13 0.2007832E-07 0.1119332E-02 6.5113 12 K+ 0.1565533E-03 0.1572375E-03 0.6137435E+01 6.1833 13 Na+ 0.1989024E-01 0.2230100E-01 0.5117893E+03 8.2865 14 Mn++ 0.2446208E-10 0.2507193E-08 0.1374967E-03 9.2305 15 F- 0.3657774E-05 0.3669596E-05 0.6959177E-01 4.5502 16 HPO4-- 0.4543722E-07 0.4641348E-07 0.4446846E-02 12.5039 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.1916622E-01 -.1915980E-01 -.6413875E-05 0.0000000E+00 2 H2O 0.4985295E+02 0.4985296E+02 -.6346249E-05 0.0000000E+00 3 Cl- 0.1850252E-03 0.1850252E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.2316719E-04 0.2316537E-04 0.1819762E-08 0.0000000E+00 5 HCO3- 0.5907470E-03 0.5907470E-03 0.0000000E+00 0.0000000E+00 6 HS- 0.1964943E-03 0.1964961E-03 -.1819762E-08 0.0000000E+00 7 Al+++ 0.4775352E-05 0.3189954E-05 0.1585398E-05 0.0000000E+00 8 H4SiO4 0.1215302E-01 0.1214824E-01 0.4777048E-05 0.0000000E+00 9 Ca++ 0.2080835E-06 0.1852626E-06 0.2282095E-07 0.0000000E+00 10 Mg++ 0.8368328E-10 0.8368328E-10 0.0000000E+00 0.0000000E+00 11 Fe++ 0.3259227E-07 0.1803417E-07 0.1455810E-07 0.0000000E+00 12 K+ 0.1412294E-03 0.1412294E-03 0.0000000E+00 0.0000000E+00 13 Na+ 0.2003215E-01 0.2003057E-01 0.1584742E-05 0.0000000E+00 14 Mn++ 0.2251939E-08 0.2251939E-08 0.0000000E+00 0.0000000E+00 15 F- 0.3296000E-05 0.3296000E-05 0.0000000E+00 0.0000000E+00 16 HPO4-- 0.4168819E-07 0.4168819E-07 0.0000000E+00 0.0000000E+00 Chg. balance for solid moles: -.6353E-21 Mass of aqueous solution: 0.899782E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 0.0079900 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 0.1585E-05 -5.800 0.4156E-03 -3.381 99.08 0.1595E-03 andradite 0.7279E-08 -8.138 0.3699E-05 -5.432 0.8820 0.9610E-06 grossular 0.3279E-09 -9.484 0.1477E-06 -6.831 0.3522E-01 0.4110E-07 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.9569E+00 0.9569E+00 1.0000 -0.019 grossular 0.4311E-01 0.4311E-01 1.0000 -1.365 Solid products produced: Mass = 0.000419 g Volume = 0.000161 cm3 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.0079900 moles log = -2.0975 Original solution: 1000.0103000 g Original solution / Rock added: 125157.73 (Water/Rock Ratio), log = 5.0975 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0206 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9997E+00 0.9859 0.1006E+01 0.1020E+01 CO2,gas 0.3950E-05 1.0071 0.4060E-05 0.4031E-05 CH4,gas 0.3921E-05 1.0125 0.4052E-05 0.4001E-05 H2,gas 0.3096E-03 1.0005 0.3162E-03 0.3160E-03 H2S,gas 0.1307E-05 0.9960 0.1329E-05 0.1334E-05 S2,gas 0.6493E-24 1.0000 0.6627E-24 0.6627E-24 CO,gas 0.3352E-12 1.0000 0.3421E-12 0.3421E-12 SO3,gas 0.3630E-40 1.0000 0.3705E-40 0.3705E-40 SO2,gas 0.4466E-21 1.0000 0.4558E-21 0.4558E-21 HF,gas 0.4298E-14 1.0000 0.4387E-14 0.4387E-14 HCl,gas 0.4645E-17 1.0000 0.4741E-17 0.4741E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 17 albite -0.38 -0.38 0.00 0.000 -0.94784E-12 23 andradite 39.01 39.01 0.00 0.000 -0.12132E-10 24 grossular 32.73 32.73 0.00 0.000 0.12132E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -13.75 -7.09 -2.363 0.12107E+05 -5.392 3 CH4,gas 4.54 -2.55 -7.09 -1.773 0.12108E+05 -5.392 4 H2,gas 8.00 2.80 -5.20 -2.971 0.88772E+04 -3.500 5 H2S,gas -6.23 -13.81 -7.58 -3.788 0.12935E+05 -5.877 6 S2,gas -7.34 -33.21 -25.88 -3.981 0.44185E+05 -24.179 7 CO,gas 3.21 -10.95 -14.16 -4.358 0.24186E+05 -12.466 8 SO3,gas 17.12 -25.01 -42.13 -10.533 0.71936E+05 -40.431 9 SO2,gas 0.83 -22.21 -23.04 -6.144 0.39341E+05 -21.341 10 HF,gas 0.47 -15.58 -16.06 -8.028 0.27417E+05 -14.358 11 HCl,gas 5.19 -13.83 -19.02 -9.512 0.32481E+05 -17.324 12 acmite 7.71 7.20 -0.51 -0.053 0.87056E+03 16 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 20 spessartine 24.46 19.65 -4.81 -0.241 0.82134E+04 21 analcite 3.32 2.71 -0.61 -0.067 0.10363E+04 27 annite 20.12 17.05 -3.08 -0.171 0.52530E+04 28 phlogopite 27.06 25.04 -2.02 -0.112 0.34499E+04 30 anorthite 12.71 7.74 -4.97 -0.383 0.84934E+04 33 apatite-OH -18.15 -19.88 -1.73 -0.133 0.29508E+04 34 apatite-F -34.30 -35.47 -1.16 -0.097 0.19875E+04 38 aragonite 0.97 -1.07 -2.04 -0.678 0.34755E+04 39 brucite 12.57 9.18 -3.39 -0.678 0.57909E+04 40 calcite 0.81 -1.07 -1.88 -0.627 0.32113E+04 41 carnegieite-low 9.02 5.81 -3.21 -0.459 0.54803E+04 42 carnegieite-high 10.09 5.81 -4.28 -0.611 0.73073E+04 43 carpholite-Mg 8.58 4.23 -4.35 -0.290 0.74286E+04 45 celadonite 5.34 3.59 -1.75 -0.103 0.29887E+04 46 celadonite-Fe 3.88 0.93 -2.95 -0.174 0.50388E+04 47 chrysotile 23.89 21.33 -2.56 -0.213 0.43691E+04 49 clinochlore 39.07 37.84 -1.23 -0.038 0.20979E+04 50 daphnite 28.97 24.51 -4.45 -0.139 0.76035E+04 52 chlorite-Al-free 47.17 42.67 -4.51 -0.188 0.76934E+04 54 chloritoid-Fe 9.17 4.66 -4.51 -0.301 0.76992E+04 55 chloritoid-Mn 11.40 7.38 -4.02 -0.268 0.68596E+04 57 coesite -2.38 -3.10 -0.72 -0.241 0.12340E+04 64 cristobalite -2.56 -3.10 -0.54 -0.179 0.91937E+03 66 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71243E+04 68 diaspore 2.87 0.63 -2.25 -0.375 0.38379E+04 70 diopside 16.18 15.66 -0.52 -0.052 0.88826E+03 71 hedenbergite 14.21 13.00 -1.21 -0.121 0.20710E+04 78 epidote 24.67 22.43 -2.24 -0.109 0.38248E+04 79 clinozoisite 22.81 17.94 -4.86 -0.221 0.83002E+04 80 epidote-Fe 29.84 26.91 -2.93 -0.152 0.49960E+04 81 fayalite 14.05 9.92 -4.12 -0.589 0.70380E+04 82 ferrosilite 11.15 6.83 -4.32 -0.432 0.73838E+04 86 gibbsite 4.08 0.63 -3.45 -0.493 0.58965E+04 87 glaucophane 22.97 20.57 -2.41 -0.065 0.41132E+04 88 glaucophane-Fe 17.28 12.57 -4.71 -0.127 0.80374E+04 89 graphite -3.55 -8.15 -4.60 -1.315 0.78594E+04 90 greenalite 16.14 13.34 -2.80 -0.234 0.47863E+04 93 hematite 12.57 10.22 -2.34 -0.284 0.40029E+04 94 heulandite -5.83 -7.76 -1.93 -0.088 0.32964E+04 98 jadeite 4.22 2.71 -1.50 -0.150 0.25618E+04 99 julgoldite 70.43 65.60 -4.83 -0.125 0.82414E+04 100 kalsilite 7.58 3.71 -3.87 -0.553 0.66137E+04 101 kaolinite -1.33 -4.95 -3.61 -0.328 0.61688E+04 104 laumontite 2.88 1.54 -1.34 -0.090 0.22964E+04 105 lawsonite 9.62 7.74 -1.88 -0.125 0.32101E+04 106 leucite 4.12 0.61 -3.51 -0.351 0.59883E+04 108 lizardite 23.24 21.33 -1.91 -0.159 0.32617E+04 110 magnetite 20.09 16.73 -3.35 -0.274 0.57272E+04 111 minnesotaite 10.39 7.14 -3.25 -0.191 0.55481E+04 115 manganosite 14.06 9.23 -4.83 -1.207 0.82431E+04 119 microcline -2.49 -2.49 0.00 0.000 0.88540E+00 123 muscovite 2.58 -1.24 -3.82 -0.225 0.65182E+04 124 paragonite 4.24 0.87 -3.37 -0.198 0.57564E+04 125 nepheline 8.34 5.81 -2.53 -0.361 0.43127E+04 137 phlogopite-Na 29.65 27.15 -2.50 -0.139 0.42678E+04 139 prehnite 19.37 17.32 -2.05 -0.121 0.35054E+04 140 prehnite-Fe 22.50 21.80 -0.69 -0.042 0.11850E+04 141 pumpellyite-Fe 46.27 41.78 -4.49 -0.100 0.76739E+04 142 pumpellyite-Mg 48.99 44.44 -4.55 -0.101 0.77758E+04 145 pyrite -21.25 -23.90 -2.65 -0.625 0.45319E+04 146 pyrrhotite -4.26 -7.29 -3.03 -1.011 0.51808E+04 147 pyrrhotiteFe0.875 -6.02 -8.46 -2.44 -0.897 0.41642E+04 148 pyroxmangite 7.40 6.13 -1.27 -0.253 0.21633E+04 149 pyrophyllite -6.18 -11.14 -4.97 -0.310 0.84816E+04 150 quartz -2.99 -3.10 -0.11 -0.036 0.18670E+03 154 rhodochrosite -0.98 -4.52 -3.54 -1.181 0.60509E+04 155 rhodonite 7.45 6.13 -1.31 -0.263 0.22436E+04 156 sanidine -1.28 -2.49 -1.21 -0.093 0.20686E+04 158 siderite -2.61 -7.24 -4.63 -1.544 0.79076E+04 166 stilbite -7.52 -7.76 -0.24 -0.011 0.40260E+03 167 stilpnomelane-Fe 13.02 12.11 -0.91 -0.027 0.15488E+04 168 stilpnomelane-Mg 27.44 25.44 -2.00 -0.060 0.34197E+04 174 talc 16.49 15.14 -1.36 -0.080 0.23137E+04 177 tephroite 18.09 15.36 -2.72 -0.389 0.46505E+04 181 tridymite -2.63 -3.10 -0.47 -0.157 0.80668E+03 182 tremolite 47.87 46.46 -1.41 -0.038 0.24092E+04 184 troilite-low -4.41 -7.29 -2.88 -0.961 0.49237E+04 190 wairakite 3.95 1.54 -2.41 -0.142 0.41184E+04 191 walstromite 11.51 9.58 -1.93 -0.385 0.32892E+04 192 wollastonite 10.46 9.58 -0.88 -0.176 0.14996E+04 193 pseudo-wollastonite 11.00 9.58 -1.42 -0.283 0.24195E+04 194 zoisite 22.85 17.94 -4.90 -0.223 0.83743E+04 195 akaganeite 7.75 5.11 -2.64 -0.572 0.45140E+04 202 chalcedony -2.80 -3.10 -0.30 -0.099 0.50600E+03 204 montmorillonite-Ca -2.29 -6.23 -3.94 -0.244 0.67242E+04 205 montmorillonite-K -2.24 -6.28 -4.04 -0.248 0.69052E+04 206 montmorillonite-Mg -2.48 -6.81 -4.33 -0.268 0.73886E+04 207 montmorillonite-Na -2.04 -5.59 -3.55 -0.217 0.60598E+04 208 nontronite-Ca 3.21 1.15 -2.07 -0.134 0.35279E+04 209 nontronite-H 2.53 -0.94 -3.48 -0.233 0.59365E+04 210 nontronite-K 3.34 1.10 -2.24 -0.144 0.38320E+04 211 nontronite-Mg 3.07 0.57 -2.50 -0.162 0.42763E+04 212 nontronite-Na 3.52 1.79 -1.73 -0.111 0.29526E+04 228 tobermorite 9.82 7.47 -2.36 -0.643 0.40263E+04 234 alabandite -0.98 -4.58 -3.60 -1.199 0.61426E+04 237 boehmite 4.41 0.63 -3.78 -0.630 0.64548E+04 239 ferrous-oxide 9.81 6.51 -3.30 -0.825 0.56351E+04 245 silica-amorphous -2.09 -3.10 -1.01 -0.336 0.17202E+04 247 an20ab80 2.02 1.24 -0.78 -0.060 0.13278E+04 248 an25ab75 2.65 1.65 -1.00 -0.077 0.17068E+04 249 an30ab70 3.28 2.05 -1.23 -0.094 0.20953E+04 250 tr.625ac.25prg.125 45.16 44.02 -1.14 -0.031 0.19474E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 0.0004000 MOLES Current total amount of reactant added: 0.0079900 MOLES New total amount of reactant added: 0.0083900 MOLES Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.5508E-08 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 7 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 0.0083900 Water: Moles liquid = 0.4986E+02 kg liquid = 0.8982E+00 Moles total = 0.4985E+02 kg total = 0.8981E+00 Activity = 1.0000 Stoichiometric ionic strength = .1186693E-01 Osmotic coef. = 0.9492 True ionic strength = .2050508E-01 Chg. balance for total moles = -.5508E-08 Max. difference allowed = 0.1874E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.10297E-09 -9.9873 0.86395E-10 -10.0635 0.83901E+00 -0.0762 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.20767E-03 -3.6826 0.17317E-03 -3.7615 0.83387E+00 -0.0789 4 SO4-- 0.27945E-04 -4.5537 0.14421E-04 -4.8410 0.51606E+00 -0.2873 5 HCO3- 0.26131E-03 -3.5828 0.21822E-03 -3.6611 0.83511E+00 -0.0783 6 HS- 0.22735E-03 -3.6433 0.18961E-03 -3.7221 0.83399E+00 -0.0788 7 Al+++ 0.11807E-28 -28.9279 0.26888E-29 -29.5704 0.22773E+00 -0.6426 8 H4SiO4 0.80219E-03 -3.0957 0.80219E-03 -3.0957 0.10000E+01 0.0000 9 Ca++ 0.67907E-07 -7.1681 0.34782E-07 -7.4586 0.51220E+00 -0.2906 10 Mg++ 0.21705E-10 -10.6634 0.11065E-10 -10.9560 0.50981E+00 -0.2926 11 Fe++ 0.48985E-13 -13.3099 0.25001E-13 -13.6020 0.51038E+00 -0.2921 12 K+ 0.15655E-03 -3.8053 0.13077E-03 -3.8835 0.83531E+00 -0.0782 13 Na+ 0.19892E-01 -1.7013 0.16584E-01 -1.7803 0.83371E+00 -0.0790 14 Mn++ 0.24814E-10 -10.6053 0.12675E-10 -10.8970 0.51081E+00 -0.2917 15 F- 0.38353E-05 -5.4162 0.31914E-05 -5.4960 0.83212E+00 -0.0798 16 HPO4-- 0.45443E-07 -7.3425 0.23455E-07 -7.6298 0.51614E+00 -0.2872 18 HSiO3- 0.10397E-01 -1.9831 0.86699E-02 -2.0620 0.83387E+00 -0.0789 19 Ca(HSiO3)+ 0.82197E-08 -8.0851 0.68675E-08 -8.1632 0.83550E+00 -0.0781 20 Mg(HSiO3)+ 0.32544E-11 -11.4875 0.27190E-11 -11.5656 0.83550E+00 -0.0781 21 NaHSiO3,aq 0.23255E-02 -2.6335 0.23255E-02 -2.6335 0.10000E+01 0.0000 22 AlO+ 0.58657E-16 -16.2317 0.49008E-16 -16.3097 0.83550E+00 -0.0781 24 HAlO2,aq 0.11297E-09 -9.9470 0.11297E-09 -9.9470 0.10000E+01 0.0000 25 AlO2- 0.34775E-05 -5.4587 0.28944E-05 -5.5384 0.83233E+00 -0.0797 26 CH4,aq 0.27972E-08 -8.5533 0.27871E-08 -8.5549 0.99638E+00 -0.0016 31 CO,aq 0.24085E-15 -15.6182 0.24085E-15 -15.6182 0.10000E+01 0.0000 32 CO2,aq 0.40431E-07 -7.3933 0.40285E-07 -7.3949 0.99638E+00 -0.0016 33 CO3-2 0.42845E-03 -3.3681 0.22063E-03 -3.6563 0.51494E+00 -0.2882 34 CaCO3,aq 0.96221E-07 -7.0167 0.96221E-07 -7.0167 0.10000E+01 0.0000 35 Ca(HCO3)+ 0.23190E-09 -9.6347 0.19375E-09 -9.7128 0.83550E+00 -0.0781 36 CaCl+ 0.11667E-10 -10.9331 0.97474E-11 -11.0111 0.83550E+00 -0.0781 37 CaCl2,aq 0.40102E-15 -15.3968 0.40102E-15 -15.3968 0.10000E+01 0.0000 38 CaF+ 0.19398E-11 -11.7123 0.16207E-11 -11.7903 0.83550E+00 -0.0781 39 CaOH+ 0.34342E-07 -7.4642 0.28693E-07 -7.5422 0.83550E+00 -0.0781 40 CaSO4,aq 0.15928E-09 -9.7978 0.15928E-09 -9.7978 0.10000E+01 0.0000 41 HCl,aq 0.27415E-14 -14.5620 0.27415E-14 -14.5620 0.10000E+01 0.0000 45 HF,aq 0.18875E-11 -11.7241 0.18875E-11 -11.7241 0.10000E+01 0.0000 46 HF2- 0.24390E-17 -17.6128 0.20338E-17 -17.6917 0.83387E+00 -0.0789 48 FeCl+ 0.82020E-17 -17.0861 0.68528E-17 -17.1641 0.83550E+00 -0.0781 51 FeF+ 0.48801E-17 -17.3116 0.40773E-17 -17.3896 0.83550E+00 -0.0781 53 FeO,aq 0.13018E-09 -9.8855 0.13018E-09 -9.8855 0.10000E+01 0.0000 54 FeOH+ 0.11274E-10 -10.9479 0.94196E-11 -11.0260 0.83550E+00 -0.0781 55 HFeO2- 0.18907E-07 -7.7234 0.15766E-07 -7.8023 0.83387E+00 -0.0789 56 FeO+ 0.55122E-16 -16.2587 0.46054E-16 -16.3367 0.83550E+00 -0.0781 58 FeO2- 0.15141E-08 -8.8198 0.12625E-08 -8.8988 0.83387E+00 -0.0789 59 HFeO2,aq 0.13873E-10 -10.8578 0.13873E-10 -10.8578 0.10000E+01 0.0000 60 H2,aq 0.23886E-06 -6.6219 0.23800E-06 -6.6234 0.99638E+00 -0.0016 61 KCl,aq 0.41044E-09 -9.3868 0.41044E-09 -9.3868 0.10000E+01 0.0000 62 KHSO4,aq 0.46066E-18 -18.3366 0.46066E-18 -18.3366 0.10000E+01 0.0000 63 KOH,aq 0.64642E-06 -6.1895 0.64642E-06 -6.1895 0.10000E+01 0.0000 64 KSO4- 0.35094E-07 -7.4548 0.29264E-07 -7.5337 0.83387E+00 -0.0789 65 MgCO3,aq 0.76729E-11 -11.1150 0.76729E-11 -11.1150 0.10000E+01 0.0000 66 Mg(HCO3)+ 0.75383E-13 -13.1227 0.62982E-13 -13.2008 0.83550E+00 -0.0781 67 MgCl+ 0.33639E-14 -14.4732 0.28105E-14 -14.5512 0.83550E+00 -0.0781 68 MgF+ 0.22859E-14 -14.6409 0.19099E-14 -14.7190 0.83550E+00 -0.0781 69 MgOH+ 0.60455E-10 -10.2186 0.50510E-10 -10.2966 0.83550E+00 -0.0781 71 MnF+ 0.81551E-15 -15.0886 0.68136E-15 -15.1666 0.83550E+00 -0.0781 72 MnO,aq 0.17586E-08 -8.7548 0.17586E-08 -8.7548 0.10000E+01 0.0000 73 MnOH+ 0.53099E-09 -9.2749 0.44364E-09 -9.3530 0.83550E+00 -0.0781 74 MnO2-2 0.15185E-10 -10.8186 0.78194E-11 -11.1068 0.51494E+00 -0.2882 75 HMnO2- 0.17749E-09 -9.7508 0.14800E-09 -9.8297 0.83387E+00 -0.0789 78 MnCl+ 0.16178E-13 -13.7911 0.13516E-13 -13.8691 0.83550E+00 -0.0781 79 MnSO4,aq 0.52770E-13 -13.2776 0.52770E-13 -13.2776 0.10000E+01 0.0000 80 NaCl,aq 0.95175E-06 -6.0215 0.95175E-06 -6.0215 0.10000E+01 0.0000 81 NaF,aq 0.12391E-07 -7.9069 0.12391E-07 -7.9069 0.10000E+01 0.0000 82 NaOH,aq 0.82474E-04 -4.0837 0.82474E-04 -4.0837 0.10000E+01 0.0000 84 OH- 0.80348E-02 -2.0950 0.66876E-02 -2.1747 0.83233E+00 -0.0797 89 HPO3-2 0.33782E-16 -16.4713 0.17396E-16 -16.7595 0.51494E+00 -0.2882 92 H3PO4,aq 0.12244E-17 -17.9121 0.12244E-17 -17.9121 0.10000E+01 0.0000 93 H2PO4- 0.44785E-10 -10.3489 0.37381E-10 -10.4273 0.83467E+00 -0.0785 94 PO4-3 0.92521E-09 -9.0338 0.22150E-09 -9.6546 0.23941E+00 -0.6209 98 HP2O7-3 0.11108E-17 -17.9544 0.25323E-18 -18.5965 0.22796E+00 -0.6421 99 P2O7-4 0.93114E-17 -17.0310 0.70023E-18 -18.1548 0.75201E-01 -1.1238 100 H2S,aq 0.50811E-07 -7.2940 0.50628E-07 -7.2956 0.99638E+00 -0.0016 101 S2-2 0.64999E-11 -11.1871 0.33471E-11 -11.4753 0.51494E+00 -0.2882 102 S3-2 0.18628E-17 -17.7298 0.95925E-18 -18.0181 0.51494E+00 -0.2882 107 SO3-2 0.85356E-12 -12.0688 0.44601E-12 -12.3507 0.52253E+00 -0.2819 108 HSO3- 0.28933E-14 -14.5386 0.24127E-14 -14.6175 0.83387E+00 -0.0789 109 HSO4- 0.14357E-11 -11.8429 0.12007E-11 -11.9206 0.83633E+00 -0.0776 111 S2O3-2 0.16655E-13 -13.7785 0.85764E-14 -14.0667 0.51494E+00 -0.2882 Charge balance for all species = -.6132E-08 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.1029722E-09 -.2128313E-01 -.2141417E+02 0.0000 2 H2O 0.1000000E+01 0.5550365E+02 0.9981461E+06 0.0000 3 Cl- 0.2076713E-03 0.2086234E-03 0.7383242E+01 6.3020 4 SO4-- 0.2794454E-04 0.2791747E-04 0.2677053E+01 15.2860 5 HCO3- 0.2613115E-03 0.6899000E-03 0.4202130E+02 6.4024 6 HS- 0.2273489E-03 0.2274621E-03 0.7509318E+01 6.3414 7 Al+++ 0.1180701E-28 0.3477606E-05 0.9366503E-01 0.6201 8 H4SiO4 0.8021858E-03 0.1352490E-01 0.1297652E+04 -3.0957 9 Ca++ 0.6790668E-07 0.2070943E-06 0.8285241E-02 12.6684 10 Mg++ 0.2170452E-10 0.9316794E-10 0.2261092E-05 9.1710 11 Fe++ 0.4898482E-13 0.2057658E-07 0.1147108E-02 6.5250 12 K+ 0.1565544E-03 0.1572363E-03 0.6137379E+01 6.1800 13 Na+ 0.1989183E-01 0.2230075E-01 0.5117829E+03 8.2832 14 Mn++ 0.2481374E-10 0.2507174E-08 0.1374954E-03 9.2300 15 F- 0.3835308E-05 0.3847703E-05 0.7296934E-01 4.5675 16 HPO4-- 0.4544313E-07 0.4641313E-07 0.4446805E-02 12.4973 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.1912315E-01 -.1911647E-01 -.6677087E-05 0.0000000E+00 2 H2O 0.4985328E+02 0.4985328E+02 -.6611729E-05 0.0000000E+00 3 Cl- 0.1873852E-03 0.1873852E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.2507719E-04 0.2507543E-04 0.1763802E-08 0.0000000E+00 5 HCO3- 0.6196670E-03 0.6196670E-03 0.0000000E+00 0.0000000E+00 6 HS- 0.2043043E-03 0.2043060E-03 -.1763802E-08 0.0000000E+00 7 Al+++ 0.4775352E-05 0.3123579E-05 0.1651773E-05 0.0000000E+00 8 H4SiO4 0.1215302E-01 0.1214804E-01 0.4975577E-05 0.0000000E+00 9 Ca++ 0.2080835E-06 0.1860117E-06 0.2207179E-07 0.0000000E+00 10 Mg++ 0.8368328E-10 0.8368328E-10 0.0000000E+00 0.0000000E+00 11 Fe++ 0.3259227E-07 0.1848185E-07 0.1411042E-07 0.0000000E+00 12 K+ 0.1412294E-03 0.1412294E-03 0.0000000E+00 0.0000000E+00 13 Na+ 0.2003215E-01 0.2003050E-01 0.1651169E-05 0.0000000E+00 14 Mn++ 0.2251939E-08 0.2251939E-08 0.0000000E+00 0.0000000E+00 15 F- 0.3456000E-05 0.3456000E-05 0.0000000E+00 0.0000000E+00 16 HPO4-- 0.4168819E-07 0.4168819E-07 0.0000000E+00 0.0000000E+00 Chg. balance for solid moles: 0.2118E-21 Mass of aqueous solution: 0.899790E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 0.0083900 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 0.1651E-05 -5.782 0.4330E-03 -3.364 99.15 0.1662E-03 andradite 0.7055E-08 -8.151 0.3585E-05 -5.445 0.8210 0.9315E-06 grossular 0.3021E-09 -9.520 0.1361E-06 -6.866 0.3116E-01 0.3786E-07 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.9589E+00 0.9589E+00 1.0000 -0.018 grossular 0.4106E-01 0.4106E-01 1.0000 -1.387 Solid products produced: Mass = 0.000437 g Volume = 0.000167 cm3 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.0083900 moles log = -2.0762 Original solution: 1000.0103000 g Original solution / Rock added: 119190.74 (Water/Rock Ratio), log = 5.0762 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0206 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9997E+00 0.9859 0.1006E+01 0.1020E+01 CO2,gas 0.4193E-05 1.0071 0.4310E-05 0.4280E-05 CH4,gas 0.3970E-05 1.0125 0.4102E-05 0.4052E-05 H2,gas 0.3060E-03 1.0005 0.3125E-03 0.3123E-03 H2S,gas 0.1369E-05 0.9960 0.1392E-05 0.1397E-05 S2,gas 0.7296E-24 1.0000 0.7446E-24 0.7446E-24 CO,gas 0.3517E-12 1.0000 0.3589E-12 0.3589E-12 SO3,gas 0.3988E-40 1.0000 0.4070E-40 0.4070E-40 SO2,gas 0.4848E-21 1.0000 0.4948E-21 0.4948E-21 HF,gas 0.4541E-14 1.0000 0.4635E-14 0.4635E-14 HCl,gas 0.4740E-17 1.0000 0.4838E-17 0.4838E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 17 albite -0.38 -0.38 0.00 0.000 -0.94784E-12 23 andradite 39.01 39.01 0.00 0.000 -0.12132E-10 24 grossular 32.73 32.73 0.00 0.000 0.00000E+00 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -13.72 -7.06 -2.355 0.12062E+05 -5.366 3 CH4,gas 4.54 -2.54 -7.09 -1.771 0.12099E+05 -5.387 4 H2,gas 8.00 2.80 -5.20 -2.974 0.88860E+04 -3.505 5 H2S,gas -6.23 -13.79 -7.56 -3.778 0.12901E+05 -5.856 6 S2,gas -7.34 -33.16 -25.83 -3.973 0.44099E+05 -24.128 7 CO,gas 3.21 -10.93 -14.14 -4.352 0.24150E+05 -12.445 8 SO3,gas 17.12 -24.97 -42.09 -10.522 0.71866E+05 -40.390 9 SO2,gas 0.83 -22.17 -23.00 -6.135 0.39280E+05 -21.306 10 HF,gas 0.47 -15.56 -16.03 -8.016 0.27376E+05 -14.334 11 HCl,gas 5.19 -13.83 -19.01 -9.507 0.32466E+05 -17.315 12 acmite 7.71 7.22 -0.49 -0.051 0.83798E+03 16 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 20 spessartine 24.46 19.64 -4.81 -0.241 0.82204E+04 21 analcite 3.32 2.71 -0.61 -0.068 0.10416E+04 27 annite 20.12 17.09 -3.04 -0.169 0.51830E+04 28 phlogopite 27.06 25.03 -2.04 -0.113 0.34810E+04 30 anorthite 12.71 7.72 -4.99 -0.384 0.85257E+04 33 apatite-OH -18.15 -19.93 -1.78 -0.137 0.30308E+04 34 apatite-F -34.30 -35.49 -1.19 -0.099 0.20268E+04 38 aragonite 0.97 -1.06 -2.02 -0.674 0.34538E+04 39 brucite 12.57 9.17 -3.40 -0.680 0.58013E+04 40 calcite 0.81 -1.06 -1.87 -0.623 0.31896E+04 41 carnegieite-low 9.02 5.81 -3.22 -0.459 0.54907E+04 42 carnegieite-high 10.09 5.81 -4.29 -0.612 0.73177E+04 43 carpholite-Mg 8.58 4.22 -4.36 -0.291 0.74486E+04 45 celadonite 5.34 3.59 -1.75 -0.103 0.29939E+04 46 celadonite-Fe 3.88 0.94 -2.93 -0.173 0.50103E+04 47 chrysotile 23.89 21.32 -2.57 -0.214 0.43897E+04 49 clinochlore 39.07 37.81 -1.26 -0.039 0.21541E+04 50 daphnite 28.97 24.58 -4.39 -0.137 0.74912E+04 52 chlorite-Al-free 47.17 42.64 -4.53 -0.189 0.77346E+04 54 chloritoid-Fe 9.17 4.67 -4.50 -0.300 0.76907E+04 55 chloritoid-Mn 11.40 7.37 -4.03 -0.268 0.68753E+04 57 coesite -2.38 -3.10 -0.72 -0.240 0.12288E+04 64 cristobalite -2.56 -3.10 -0.54 -0.178 0.91416E+03 66 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71243E+04 68 diaspore 2.87 0.62 -2.25 -0.376 0.38480E+04 70 diopside 16.18 15.65 -0.53 -0.053 0.91084E+03 71 hedenbergite 14.21 13.00 -1.21 -0.121 0.20598E+04 78 epidote 24.67 22.42 -2.25 -0.109 0.38468E+04 79 clinozoisite 22.81 17.91 -4.90 -0.223 0.83600E+04 80 epidote-Fe 29.84 26.92 -2.92 -0.152 0.49803E+04 81 fayalite 14.05 9.95 -4.09 -0.584 0.69861E+04 82 ferrosilite 11.15 6.86 -4.29 -0.429 0.73267E+04 86 gibbsite 4.08 0.62 -3.46 -0.494 0.59065E+04 87 glaucophane 22.97 20.55 -2.42 -0.065 0.41338E+04 88 glaucophane-Fe 17.28 12.62 -4.66 -0.126 0.79569E+04 89 graphite -3.55 -8.13 -4.59 -1.311 0.78326E+04 90 greenalite 16.14 13.38 -2.76 -0.230 0.47058E+04 93 hematite 12.57 10.25 -2.31 -0.280 0.39473E+04 94 heulandite -5.83 -7.76 -1.93 -0.088 0.33027E+04 98 jadeite 4.22 2.71 -1.50 -0.150 0.25671E+04 99 julgoldite 70.43 65.66 -4.77 -0.124 0.81430E+04 100 kalsilite 7.58 3.70 -3.88 -0.554 0.66241E+04 101 kaolinite -1.33 -4.95 -3.62 -0.329 0.61784E+04 104 laumontite 2.88 1.53 -1.36 -0.091 0.23183E+04 105 lawsonite 9.62 7.72 -1.90 -0.127 0.32424E+04 106 leucite 4.12 0.61 -3.51 -0.351 0.59935E+04 108 lizardite 23.24 21.32 -1.92 -0.160 0.32823E+04 110 magnetite 20.09 16.78 -3.31 -0.270 0.56484E+04 111 minnesotaite 10.39 7.19 -3.20 -0.188 0.54572E+04 115 manganosite 14.06 9.23 -4.83 -1.207 0.82439E+04 119 microcline -2.49 -2.49 0.00 0.000 0.93805E+00 123 muscovite 2.58 -1.25 -3.83 -0.225 0.65384E+04 124 paragonite 4.24 0.86 -3.38 -0.199 0.57765E+04 125 nepheline 8.34 5.81 -2.53 -0.362 0.43231E+04 137 phlogopite-Na 29.65 27.13 -2.52 -0.140 0.42989E+04 139 prehnite 19.37 17.29 -2.08 -0.122 0.35551E+04 140 prehnite-Fe 22.50 21.80 -0.70 -0.042 0.11969E+04 141 pumpellyite-Fe 46.27 41.72 -4.54 -0.101 0.77601E+04 142 pumpellyite-Mg 48.99 44.37 -4.62 -0.103 0.78957E+04 145 pyrite -21.25 -23.84 -2.59 -0.611 0.44309E+04 146 pyrrhotite -4.26 -7.26 -3.00 -1.000 0.51230E+04 147 pyrrhotiteFe0.875 -6.02 -8.42 -2.41 -0.885 0.41082E+04 148 pyroxmangite 7.40 6.13 -1.26 -0.253 0.21590E+04 149 pyrophyllite -6.18 -11.14 -4.97 -0.310 0.84808E+04 150 quartz -2.99 -3.10 -0.11 -0.035 0.18149E+03 154 rhodochrosite -0.98 -4.49 -3.52 -1.173 0.60074E+04 155 rhodonite 7.45 6.13 -1.31 -0.262 0.22392E+04 156 sanidine -1.28 -2.49 -1.21 -0.093 0.20687E+04 158 siderite -2.61 -7.20 -4.59 -1.530 0.78398E+04 166 stilbite -7.52 -7.76 -0.24 -0.011 0.40883E+03 167 stilpnomelane-Fe 13.02 12.19 -0.83 -0.025 0.14132E+04 168 stilpnomelane-Mg 27.44 25.42 -2.02 -0.060 0.34526E+04 174 talc 16.49 15.13 -1.36 -0.080 0.23239E+04 177 tephroite 18.09 15.36 -2.72 -0.389 0.46470E+04 181 tridymite -2.63 -3.10 -0.47 -0.156 0.80146E+03 182 tremolite 47.87 46.43 -1.44 -0.039 0.24645E+04 184 troilite-low -4.41 -7.26 -2.85 -0.950 0.48658E+04 190 wairakite 3.95 1.53 -2.42 -0.143 0.41402E+04 191 walstromite 11.51 9.57 -1.94 -0.387 0.33066E+04 192 wollastonite 10.46 9.57 -0.89 -0.178 0.15171E+04 193 pseudo-wollastonite 11.00 9.57 -1.43 -0.285 0.24369E+04 194 zoisite 22.85 17.91 -4.94 -0.225 0.84341E+04 195 akaganeite 7.75 5.13 -2.63 -0.568 0.44862E+04 202 chalcedony -2.80 -3.10 -0.29 -0.098 0.50078E+03 204 montmorillonite-Ca -2.29 -6.23 -3.94 -0.244 0.67273E+04 205 montmorillonite-K -2.24 -6.28 -4.04 -0.248 0.69063E+04 206 montmorillonite-Mg -2.48 -6.81 -4.33 -0.268 0.73896E+04 207 montmorillonite-Na -2.04 -5.59 -3.55 -0.217 0.60609E+04 208 nontronite-Ca 3.21 1.19 -2.03 -0.131 0.34603E+04 209 nontronite-H 2.53 -0.90 -3.44 -0.230 0.58652E+04 210 nontronite-K 3.34 1.14 -2.20 -0.141 0.37626E+04 211 nontronite-Mg 3.07 0.61 -2.46 -0.160 0.42067E+04 212 nontronite-Na 3.52 1.83 -1.69 -0.108 0.28831E+04 228 tobermorite 9.82 7.46 -2.37 -0.646 0.40399E+04 234 alabandite -0.98 -4.56 -3.58 -1.193 0.61090E+04 237 boehmite 4.41 0.62 -3.79 -0.631 0.64649E+04 239 ferrous-oxide 9.81 6.52 -3.29 -0.822 0.56118E+04 245 silica-amorphous -2.09 -3.10 -1.00 -0.335 0.17150E+04 247 an20ab80 2.02 1.24 -0.78 -0.060 0.13343E+04 248 an25ab75 2.65 1.64 -1.00 -0.077 0.17148E+04 249 an30ab70 3.28 2.05 -1.23 -0.095 0.21050E+04 250 tr.625ac.25prg.125 45.16 44.01 -1.15 -0.031 0.19650E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 0.0004000 MOLES Current total amount of reactant added: 0.0083900 MOLES New total amount of reactant added: 0.0087900 MOLES Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.5508E-08 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 7 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 0.0087900 Water: Moles liquid = 0.4986E+02 kg liquid = 0.8982E+00 Moles total = 0.4985E+02 kg total = 0.8981E+00 Activity = 1.0000 Stoichiometric ionic strength = .1189260E-01 Osmotic coef. = 0.9487 True ionic strength = .2052753E-01 Chg. balance for total moles = -.5508E-08 Max. difference allowed = 0.1897E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.10376E-09 -9.9840 0.87053E-10 -10.0602 0.83895E+00 -0.0763 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.21029E-03 -3.6772 0.17534E-03 -3.7561 0.83381E+00 -0.0789 4 SO4-- 0.30068E-04 -4.5219 0.15512E-04 -4.8093 0.51591E+00 -0.2874 5 HCO3- 0.27476E-03 -3.5610 0.22944E-03 -3.6393 0.83505E+00 -0.0783 6 HS- 0.23604E-03 -3.6270 0.19684E-03 -3.7059 0.83393E+00 -0.0789 7 Al+++ 0.11924E-28 -28.9236 0.27136E-29 -29.5664 0.22758E+00 -0.6429 8 H4SiO4 0.80787E-03 -3.0927 0.80787E-03 -3.0927 0.10000E+01 0.0000 9 Ca++ 0.66920E-07 -7.1744 0.34266E-07 -7.4651 0.51205E+00 -0.2907 10 Mg++ 0.21737E-10 -10.6628 0.11078E-10 -10.9555 0.50966E+00 -0.2927 11 Fe++ 0.51327E-13 -13.2897 0.26189E-13 -13.5819 0.51023E+00 -0.2922 12 K+ 0.15656E-03 -3.8053 0.13076E-03 -3.8835 0.83525E+00 -0.0782 13 Na+ 0.19893E-01 -1.7013 0.16584E-01 -1.7803 0.83365E+00 -0.0790 14 Mn++ 0.25172E-10 -10.5991 0.12854E-10 -10.8910 0.51066E+00 -0.2919 15 F- 0.40128E-05 -5.3965 0.33389E-05 -5.4764 0.83206E+00 -0.0798 16 HPO4-- 0.45449E-07 -7.3425 0.23451E-07 -7.6298 0.51599E+00 -0.2874 18 HSiO3- 0.10392E-01 -1.9833 0.86653E-02 -2.0622 0.83381E+00 -0.0789 19 Ca(HSiO3)+ 0.80941E-08 -8.0918 0.67621E-08 -8.1699 0.83544E+00 -0.0781 20 Mg(HSiO3)+ 0.32567E-11 -11.4872 0.27208E-11 -11.5653 0.83544E+00 -0.0781 21 NaHSiO3,aq 0.23243E-02 -2.6337 0.23243E-02 -2.6337 0.10000E+01 0.0000 22 AlO+ 0.58310E-16 -16.2343 0.48714E-16 -16.3123 0.83544E+00 -0.0781 24 HAlO2,aq 0.11144E-09 -9.9530 0.11144E-09 -9.9530 0.10000E+01 0.0000 25 AlO2- 0.34048E-05 -5.4679 0.28337E-05 -5.5476 0.83227E+00 -0.0797 26 CH4,aq 0.28384E-08 -8.5469 0.28281E-08 -8.5485 0.99638E+00 -0.0016 31 CO,aq 0.25243E-15 -15.5979 0.25243E-15 -15.5979 0.10000E+01 0.0000 32 CO2,aq 0.42834E-07 -7.3682 0.42679E-07 -7.3698 0.99638E+00 -0.0016 33 CO3-2 0.44719E-03 -3.3495 0.23021E-03 -3.6379 0.51480E+00 -0.2884 34 CaCO3,aq 0.98912E-07 -7.0048 0.98912E-07 -7.0048 0.10000E+01 0.0000 35 Ca(HCO3)+ 0.24022E-09 -9.6194 0.20069E-09 -9.6975 0.83544E+00 -0.0781 36 CaCl+ 0.11638E-10 -10.9341 0.97231E-11 -11.0122 0.83544E+00 -0.0781 37 CaCl2,aq 0.40503E-15 -15.3925 0.40503E-15 -15.3925 0.10000E+01 0.0000 38 CaF+ 0.19995E-11 -11.6991 0.16704E-11 -11.7772 0.83544E+00 -0.0781 39 CaOH+ 0.33579E-07 -7.4739 0.28053E-07 -7.5520 0.83544E+00 -0.0781 40 CaSO4,aq 0.16879E-09 -9.7727 0.16879E-09 -9.7727 0.10000E+01 0.0000 41 HCl,aq 0.27970E-14 -14.5533 0.27970E-14 -14.5533 0.10000E+01 0.0000 45 HF,aq 0.19898E-11 -11.7012 0.19898E-11 -11.7012 0.10000E+01 0.0000 46 HF2- 0.26902E-17 -17.5702 0.22431E-17 -17.6492 0.83381E+00 -0.0789 48 FeCl+ 0.86998E-17 -17.0605 0.72681E-17 -17.1386 0.83544E+00 -0.0781 51 FeF+ 0.53486E-17 -17.2718 0.44684E-17 -17.3498 0.83544E+00 -0.0781 53 FeO,aq 0.13431E-09 -9.8719 0.13431E-09 -9.8719 0.10000E+01 0.0000 54 FeOH+ 0.11721E-10 -10.9310 0.97925E-11 -11.0091 0.83544E+00 -0.0781 55 HFeO2- 0.19361E-07 -7.7131 0.16143E-07 -7.7920 0.83381E+00 -0.0789 56 FeO+ 0.57618E-16 -16.2394 0.48136E-16 -16.3175 0.83544E+00 -0.0781 58 FeO2- 0.15588E-08 -8.8072 0.12997E-08 -8.8862 0.83381E+00 -0.0789 59 HFeO2,aq 0.14390E-10 -10.8419 0.14390E-10 -10.8419 0.10000E+01 0.0000 60 H2,aq 0.23631E-06 -6.6265 0.23545E-06 -6.6281 0.99638E+00 -0.0016 61 KCl,aq 0.41555E-09 -9.3814 0.41555E-09 -9.3814 0.10000E+01 0.0000 62 KHSO4,aq 0.49927E-18 -18.3017 0.49927E-18 -18.3017 0.10000E+01 0.0000 63 KOH,aq 0.64148E-06 -6.1928 0.64148E-06 -6.1928 0.10000E+01 0.0000 64 KSO4- 0.37750E-07 -7.4231 0.31476E-07 -7.5020 0.83381E+00 -0.0789 65 MgCO3,aq 0.80156E-11 -11.0961 0.80156E-11 -11.0961 0.10000E+01 0.0000 66 Mg(HCO3)+ 0.79357E-13 -13.1004 0.66298E-13 -13.1785 0.83544E+00 -0.0781 67 MgCl+ 0.34103E-14 -14.4672 0.28491E-14 -14.5453 0.83544E+00 -0.0781 68 MgF+ 0.23946E-14 -14.6208 0.20005E-14 -14.6989 0.83544E+00 -0.0781 69 MgOH+ 0.60073E-10 -10.2213 0.50187E-10 -10.2994 0.83544E+00 -0.0781 71 MnF+ 0.86530E-15 -15.0628 0.72291E-15 -15.1409 0.83544E+00 -0.0781 72 MnO,aq 0.17566E-08 -8.7553 0.17566E-08 -8.7553 0.10000E+01 0.0000 73 MnOH+ 0.53445E-09 -9.2721 0.44650E-09 -9.3502 0.83544E+00 -0.0781 74 MnO2-2 0.14943E-10 -10.8256 0.76924E-11 -11.1139 0.51480E+00 -0.2884 75 HMnO2- 0.17595E-09 -9.7546 0.14671E-09 -9.8335 0.83381E+00 -0.0789 78 MnCl+ 0.16613E-13 -13.7796 0.13879E-13 -13.8576 0.83544E+00 -0.0781 79 MnSO4,aq 0.57564E-13 -13.2398 0.57564E-13 -13.2398 0.10000E+01 0.0000 80 NaCl,aq 0.96366E-06 -6.0161 0.96366E-06 -6.0161 0.10000E+01 0.0000 81 NaF,aq 0.12964E-07 -7.8873 0.12964E-07 -7.8873 0.10000E+01 0.0000 82 NaOH,aq 0.81851E-04 -4.0870 0.81851E-04 -4.0870 0.10000E+01 0.0000 84 OH- 0.79746E-02 -2.0983 0.66370E-02 -2.1780 0.83227E+00 -0.0797 89 HPO3-2 0.33425E-16 -16.4759 0.17207E-16 -16.7643 0.51480E+00 -0.2884 92 H3PO4,aq 0.12430E-17 -17.9055 0.12430E-17 -17.9055 0.10000E+01 0.0000 93 H2PO4- 0.45123E-10 -10.3456 0.37660E-10 -10.4241 0.83461E+00 -0.0785 94 PO4-3 0.91863E-09 -9.0369 0.21979E-09 -9.6580 0.23926E+00 -0.6211 98 HP2O7-3 0.11197E-17 -17.9509 0.25508E-18 -18.5933 0.22781E+00 -0.6424 99 P2O7-4 0.93191E-17 -17.0306 0.70001E-18 -18.1549 0.75115E-01 -1.1243 100 H2S,aq 0.53153E-07 -7.2745 0.52960E-07 -7.2761 0.99638E+00 -0.0016 101 S2-2 0.70833E-11 -11.1498 0.36464E-11 -11.4381 0.51480E+00 -0.2884 102 S3-2 0.21465E-17 -17.6683 0.11050E-17 -17.9566 0.51480E+00 -0.2884 107 SO3-2 0.90856E-12 -12.0416 0.47462E-12 -12.3237 0.52239E+00 -0.2820 108 HSO3- 0.31026E-14 -14.5083 0.25870E-14 -14.5872 0.83381E+00 -0.0789 109 HSO4- 0.15562E-11 -11.8079 0.13014E-11 -11.8856 0.83627E+00 -0.0777 111 S2O3-2 0.18746E-13 -13.7271 0.96504E-14 -14.0155 0.51480E+00 -0.2884 Charge balance for all species = -.6132E-08 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.1037644E-09 -.2123473E-01 -.2136544E+02 0.0000 2 H2O 0.1000000E+01 0.5550360E+02 0.9981435E+06 0.0000 3 Cl- 0.2102852E-03 0.2112493E-03 0.7476161E+01 6.3041 4 SO4-- 0.3006758E-04 0.3004379E-04 0.2880944E+01 15.3111 5 HCO3- 0.2747603E-03 0.7220924E-03 0.4398204E+02 6.4209 6 HS- 0.2360405E-03 0.2361554E-03 0.7796303E+01 6.3543 7 Al+++ 0.1192385E-28 0.3404919E-05 0.9170716E-01 0.6142 8 H4SiO4 0.8078721E-03 0.1352458E-01 0.1297619E+04 -3.0927 9 Ca++ 0.6691970E-07 0.2079279E-06 0.8318578E-02 12.6553 10 Mg++ 0.2173671E-10 0.9316723E-10 0.2261071E-05 9.1649 11 Fe++ 0.5132727E-13 0.2107978E-07 0.1175158E-02 6.5385 12 K+ 0.1565555E-03 0.1572351E-03 0.6137323E+01 6.1767 13 Na+ 0.1989342E-01 0.2230051E-01 0.5117766E+03 8.2799 14 Mn++ 0.2517151E-10 0.2507155E-08 0.1374942E-03 9.2295 15 F- 0.4012839E-05 0.4025807E-05 0.7634686E-01 4.5838 16 HPO4-- 0.4544902E-07 0.4641278E-07 0.4446764E-02 12.4906 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.1908008E-01 -.1907314E-01 -.6935842E-05 0.0000000E+00 2 H2O 0.4985361E+02 0.4985361E+02 -.6872750E-05 0.0000000E+00 3 Cl- 0.1897452E-03 0.1897452E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.2698719E-04 0.2698548E-04 0.1707288E-08 0.0000000E+00 5 HCO3- 0.6485870E-03 0.6485870E-03 0.0000000E+00 0.0000000E+00 6 HS- 0.2121143E-03 0.2121160E-03 -.1707288E-08 0.0000000E+00 7 Al+++ 0.4775352E-05 0.3058316E-05 0.1717036E-05 0.0000000E+00 8 H4SiO4 0.1215302E-01 0.1214785E-01 0.5170762E-05 0.0000000E+00 9 Ca++ 0.2080835E-06 0.1867619E-06 0.2132163E-07 0.0000000E+00 10 Mg++ 0.8368328E-10 0.8368328E-10 0.0000000E+00 0.0000000E+00 11 Fe++ 0.3259227E-07 0.1893397E-07 0.1365830E-07 0.0000000E+00 12 K+ 0.1412294E-03 0.1412294E-03 0.0000000E+00 0.0000000E+00 13 Na+ 0.2003215E-01 0.2003043E-01 0.1716480E-05 0.0000000E+00 14 Mn++ 0.2251939E-08 0.2251939E-08 0.0000000E+00 0.0000000E+00 15 F- 0.3616000E-05 0.3616000E-05 0.0000000E+00 0.0000000E+00 16 HPO4-- 0.4168819E-07 0.4168819E-07 0.0000000E+00 0.0000000E+00 Chg. balance for solid moles: 0.2118E-21 Mass of aqueous solution: 0.899798E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 0.0087900 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 0.1716E-05 -5.765 0.4501E-03 -3.347 99.21 0.1728E-03 andradite 0.6829E-08 -8.166 0.3470E-05 -5.460 0.7649 0.9016E-06 grossular 0.2781E-09 -9.556 0.1253E-06 -6.902 0.2761E-01 0.3485E-07 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.9609E+00 0.9609E+00 1.0000 -0.017 grossular 0.3912E-01 0.3912E-01 1.0000 -1.408 Solid products produced: Mass = 0.000454 g Volume = 0.000174 cm3 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.0087900 moles log = -2.0560 Original solution: 1000.0103000 g Original solution / Rock added: 113766.81 (Water/Rock Ratio), log = 5.0560 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0206 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9997E+00 0.9859 0.1006E+01 0.1020E+01 CO2,gas 0.4442E-05 1.0071 0.4566E-05 0.4534E-05 CH4,gas 0.4028E-05 1.0125 0.4163E-05 0.4111E-05 H2,gas 0.3027E-03 1.0005 0.3091E-03 0.3089E-03 H2S,gas 0.1432E-05 0.9960 0.1456E-05 0.1462E-05 S2,gas 0.8158E-24 1.0000 0.8326E-24 0.8326E-24 CO,gas 0.3686E-12 1.0000 0.3762E-12 0.3762E-12 SO3,gas 0.4355E-40 1.0000 0.4445E-40 0.4445E-40 SO2,gas 0.5237E-21 1.0000 0.5345E-21 0.5345E-21 HF,gas 0.4787E-14 1.0000 0.4886E-14 0.4886E-14 HCl,gas 0.4836E-17 1.0000 0.4935E-17 0.4935E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 17 albite -0.38 -0.38 0.00 0.000 -0.94784E-12 23 andradite 39.01 39.01 0.00 0.000 0.00000E+00 24 grossular 32.73 32.73 0.00 0.000 0.12132E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -13.70 -7.04 -2.346 0.12020E+05 -5.340 3 CH4,gas 4.54 -2.54 -7.08 -1.770 0.12088E+05 -5.381 4 H2,gas 8.00 2.79 -5.21 -2.976 0.88940E+04 -3.510 5 H2S,gas -6.23 -13.77 -7.54 -3.768 0.12867E+05 -5.837 6 S2,gas -7.34 -33.11 -25.78 -3.966 0.44016E+05 -24.080 7 CO,gas 3.21 -10.91 -14.12 -4.346 0.24116E+05 -12.425 8 SO3,gas 17.12 -24.93 -42.05 -10.513 0.71801E+05 -40.352 9 SO2,gas 0.83 -22.14 -22.97 -6.126 0.39222E+05 -21.272 10 HF,gas 0.47 -15.54 -16.01 -8.005 0.27337E+05 -14.311 11 HCl,gas 5.19 -13.82 -19.01 -9.503 0.32452E+05 -17.307 12 acmite 7.71 7.24 -0.47 -0.049 0.80598E+03 16 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 20 spessartine 24.46 19.64 -4.82 -0.241 0.82275E+04 21 analcite 3.32 2.71 -0.61 -0.068 0.10468E+04 27 annite 20.12 17.13 -2.99 -0.166 0.51136E+04 28 phlogopite 27.06 25.01 -2.06 -0.114 0.35122E+04 33 apatite-OH -18.15 -19.97 -1.82 -0.140 0.31090E+04 34 apatite-F -34.30 -35.51 -1.21 -0.101 0.20659E+04 38 aragonite 0.97 -1.04 -2.01 -0.670 0.34333E+04 39 brucite 12.57 9.16 -3.40 -0.681 0.58117E+04 40 calcite 0.81 -1.04 -1.86 -0.619 0.31691E+04 41 carnegieite-low 9.02 5.80 -3.22 -0.460 0.55012E+04 42 carnegieite-high 10.09 5.80 -4.29 -0.613 0.73282E+04 43 carpholite-Mg 8.58 4.21 -4.37 -0.292 0.74687E+04 45 celadonite 5.34 3.59 -1.76 -0.103 0.29991E+04 46 celadonite-Fe 3.88 0.96 -2.92 -0.172 0.49819E+04 47 chrysotile 23.89 21.31 -2.58 -0.215 0.44104E+04 49 clinochlore 39.07 37.77 -1.29 -0.040 0.22105E+04 50 daphnite 28.97 24.64 -4.32 -0.135 0.73799E+04 52 chlorite-Al-free 47.17 42.62 -4.55 -0.190 0.77760E+04 54 chloritoid-Fe 9.17 4.67 -4.50 -0.300 0.76825E+04 55 chloritoid-Mn 11.40 7.37 -4.04 -0.269 0.68911E+04 57 coesite -2.38 -3.09 -0.72 -0.239 0.12236E+04 64 cristobalite -2.56 -3.09 -0.53 -0.177 0.90892E+03 66 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71244E+04 68 diaspore 2.87 0.61 -2.26 -0.377 0.38580E+04 70 diopside 16.18 15.63 -0.55 -0.055 0.93309E+03 71 hedenbergite 14.21 13.01 -1.20 -0.120 0.20485E+04 78 epidote 24.67 22.40 -2.27 -0.110 0.38688E+04 79 clinozoisite 22.81 17.88 -4.93 -0.224 0.84192E+04 80 epidote-Fe 29.84 26.93 -2.91 -0.151 0.49650E+04 81 fayalite 14.05 9.98 -4.06 -0.580 0.69346E+04 82 ferrosilite 11.15 6.89 -4.26 -0.426 0.72699E+04 86 gibbsite 4.08 0.61 -3.47 -0.495 0.59166E+04 87 glaucophane 22.97 20.54 -2.43 -0.066 0.41545E+04 88 glaucophane-Fe 17.28 12.66 -4.61 -0.125 0.78770E+04 89 graphite -3.55 -8.12 -4.57 -1.306 0.78058E+04 90 greenalite 16.14 13.43 -2.71 -0.226 0.46259E+04 93 hematite 12.57 10.29 -2.28 -0.276 0.38931E+04 94 heulandite -5.83 -7.76 -1.94 -0.088 0.33085E+04 98 jadeite 4.22 2.71 -1.51 -0.151 0.25723E+04 99 julgoldite 70.43 65.71 -4.71 -0.122 0.80460E+04 100 kalsilite 7.58 3.70 -3.89 -0.555 0.66347E+04 101 kaolinite -1.33 -4.96 -3.62 -0.329 0.61881E+04 104 laumontite 2.88 1.51 -1.37 -0.091 0.23398E+04 105 lawsonite 9.62 7.70 -1.92 -0.128 0.32744E+04 106 leucite 4.12 0.61 -3.51 -0.351 0.59988E+04 108 lizardite 23.24 21.31 -1.93 -0.161 0.33030E+04 110 magnetite 20.09 16.82 -3.26 -0.266 0.55709E+04 111 minnesotaite 10.39 7.24 -3.14 -0.185 0.53668E+04 115 manganosite 14.06 9.23 -4.83 -1.207 0.82448E+04 119 microcline -2.49 -2.49 0.00 0.000 0.99105E+00 123 muscovite 2.58 -1.26 -3.84 -0.226 0.65586E+04 124 paragonite 4.24 0.84 -3.39 -0.200 0.57967E+04 125 nepheline 8.34 5.80 -2.54 -0.363 0.43336E+04 137 phlogopite-Na 29.65 27.11 -2.54 -0.141 0.43300E+04 139 prehnite 19.37 17.26 -2.11 -0.124 0.36043E+04 140 prehnite-Fe 22.50 21.79 -0.71 -0.043 0.12088E+04 141 pumpellyite-Fe 46.27 41.67 -4.59 -0.102 0.78453E+04 142 pumpellyite-Mg 48.99 44.30 -4.69 -0.104 0.80145E+04 145 pyrite -21.25 -23.78 -2.54 -0.597 0.43329E+04 146 pyrrhotite -4.26 -7.23 -2.97 -0.989 0.50665E+04 147 pyrrhotiteFe0.875 -6.02 -8.39 -2.37 -0.873 0.40535E+04 148 pyroxmangite 7.40 6.14 -1.26 -0.252 0.21546E+04 149 pyrophyllite -6.18 -11.14 -4.97 -0.310 0.84801E+04 150 quartz -2.99 -3.09 -0.10 -0.034 0.17625E+03 154 rhodochrosite -0.98 -4.47 -3.49 -1.165 0.59655E+04 155 rhodonite 7.45 6.14 -1.31 -0.262 0.22349E+04 156 sanidine -1.28 -2.49 -1.21 -0.093 0.20687E+04 158 siderite -2.61 -7.16 -4.55 -1.518 0.77739E+04 166 stilbite -7.52 -7.76 -0.24 -0.012 0.41468E+03 167 stilpnomelane-Fe 13.02 12.27 -0.75 -0.022 0.12785E+04 168 stilpnomelane-Mg 27.44 25.40 -2.04 -0.061 0.34856E+04 174 talc 16.49 15.12 -1.37 -0.080 0.23341E+04 177 tephroite 18.09 15.37 -2.72 -0.389 0.46435E+04 181 tridymite -2.63 -3.09 -0.47 -0.155 0.79623E+03 182 tremolite 47.87 46.39 -1.48 -0.040 0.25192E+04 184 troilite-low -4.41 -7.23 -2.82 -0.939 0.48093E+04 190 wairakite 3.95 1.51 -2.44 -0.143 0.41618E+04 191 walstromite 11.51 9.56 -1.95 -0.389 0.33237E+04 192 wollastonite 10.46 9.56 -0.90 -0.180 0.15342E+04 193 pseudo-wollastonite 11.00 9.56 -1.44 -0.287 0.24540E+04 194 zoisite 22.85 17.88 -4.97 -0.226 0.84933E+04 195 akaganeite 7.75 5.14 -2.61 -0.565 0.44591E+04 202 chalcedony -2.80 -3.09 -0.29 -0.097 0.49555E+03 204 montmorillonite-Ca -2.29 -6.23 -3.94 -0.244 0.67303E+04 205 montmorillonite-K -2.24 -6.28 -4.05 -0.248 0.69075E+04 206 montmorillonite-Mg -2.48 -6.81 -4.33 -0.268 0.73907E+04 207 montmorillonite-Na -2.04 -5.59 -3.55 -0.217 0.60621E+04 208 nontronite-Ca 3.21 1.23 -1.99 -0.129 0.33938E+04 209 nontronite-H 2.53 -0.86 -3.39 -0.227 0.57950E+04 210 nontronite-K 3.34 1.18 -2.16 -0.139 0.36943E+04 211 nontronite-Mg 3.07 0.65 -2.42 -0.157 0.41382E+04 212 nontronite-Na 3.52 1.87 -1.65 -0.106 0.28148E+04 228 tobermorite 9.82 7.45 -2.37 -0.648 0.40533E+04 234 alabandite -0.98 -4.54 -3.56 -1.186 0.60765E+04 237 boehmite 4.41 0.61 -3.79 -0.632 0.64750E+04 239 ferrous-oxide 9.81 6.54 -3.27 -0.818 0.55886E+04 245 silica-amorphous -2.09 -3.09 -1.00 -0.334 0.17097E+04 247 an20ab80 2.02 1.23 -0.79 -0.060 0.13407E+04 248 an25ab75 2.65 1.64 -1.01 -0.078 0.17228E+04 249 an30ab70 3.28 2.04 -1.24 -0.095 0.21146E+04 250 tr.625ac.25prg.125 45.16 44.00 -1.16 -0.031 0.19823E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 0.0004000 MOLES Current total amount of reactant added: 0.0087900 MOLES New total amount of reactant added: 0.0091900 MOLES Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.5508E-08 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 7 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 0.0091900 Water: Moles liquid = 0.4986E+02 kg liquid = 0.8982E+00 Moles total = 0.4985E+02 kg total = 0.8981E+00 Activity = 1.0000 Stoichiometric ionic strength = .1191827E-01 Osmotic coef. = 0.9481 True ionic strength = .2054987E-01 Chg. balance for total moles = -.5508E-08 Max. difference allowed = 0.1921E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.10457E-09 -9.9806 0.87720E-10 -10.0569 0.83890E+00 -0.0763 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.21290E-03 -3.6718 0.17750E-03 -3.7508 0.83375E+00 -0.0790 4 SO4-- 0.32191E-04 -4.4923 0.16603E-04 -4.7798 0.51577E+00 -0.2875 5 HCO3- 0.28833E-03 -3.5401 0.24075E-03 -3.6184 0.83499E+00 -0.0783 6 HS- 0.24473E-03 -3.6113 0.20408E-03 -3.6902 0.83387E+00 -0.0789 7 Al+++ 0.12042E-28 -28.9193 0.27388E-29 -29.5624 0.22743E+00 -0.6431 8 H4SiO4 0.81362E-03 -3.0896 0.81362E-03 -3.0896 0.10000E+01 0.0000 9 Ca++ 0.65978E-07 -7.1806 0.33774E-07 -7.4714 0.51190E+00 -0.2908 10 Mg++ 0.21769E-10 -10.6622 0.11092E-10 -10.9550 0.50951E+00 -0.2928 11 Fe++ 0.53768E-13 -13.2695 0.27426E-13 -13.5618 0.51008E+00 -0.2924 12 K+ 0.15656E-03 -3.8053 0.13076E-03 -3.8835 0.83519E+00 -0.0782 13 Na+ 0.19895E-01 -1.7013 0.16584E-01 -1.7803 0.83359E+00 -0.0790 14 Mn++ 0.25536E-10 -10.5929 0.13036E-10 -10.8849 0.51051E+00 -0.2920 15 F- 0.41904E-05 -5.3777 0.34864E-05 -5.4576 0.83199E+00 -0.0799 16 HPO4-- 0.45455E-07 -7.3424 0.23447E-07 -7.6299 0.51584E+00 -0.2875 18 HSiO3- 0.10388E-01 -1.9835 0.86606E-02 -2.0625 0.83375E+00 -0.0790 19 Ca(HSiO3)+ 0.79742E-08 -8.0983 0.66615E-08 -8.1764 0.83538E+00 -0.0781 20 Mg(HSiO3)+ 0.32591E-11 -11.4869 0.27226E-11 -11.5650 0.83538E+00 -0.0781 21 NaHSiO3,aq 0.23230E-02 -2.6339 0.23230E-02 -2.6339 0.10000E+01 0.0000 22 AlO+ 0.57964E-16 -16.2368 0.48422E-16 -16.3150 0.83538E+00 -0.0781 24 HAlO2,aq 0.10993E-09 -9.9589 0.10993E-09 -9.9589 0.10000E+01 0.0000 25 AlO2- 0.33333E-05 -5.4771 0.27740E-05 -5.5569 0.83221E+00 -0.0798 26 CH4,aq 0.28850E-08 -8.5399 0.28745E-08 -8.5414 0.99637E+00 -0.0016 31 CO,aq 0.26428E-15 -15.5779 0.26428E-15 -15.5779 0.10000E+01 0.0000 32 CO2,aq 0.45290E-07 -7.3440 0.45126E-07 -7.3456 0.99637E+00 -0.0016 33 CO3-2 0.46580E-03 -3.3318 0.23973E-03 -3.6203 0.51465E+00 -0.2885 34 CaCO3,aq 0.10152E-06 -6.9934 0.10152E-06 -6.9934 0.10000E+01 0.0000 35 Ca(HCO3)+ 0.24846E-09 -9.6047 0.20756E-09 -9.6829 0.83538E+00 -0.0781 36 CaCl+ 0.11614E-10 -10.9350 0.97019E-11 -11.0131 0.83538E+00 -0.0781 37 CaCl2,aq 0.40914E-15 -15.3881 0.40914E-15 -15.3881 0.10000E+01 0.0000 38 CaF+ 0.20579E-11 -11.6866 0.17191E-11 -11.7647 0.83538E+00 -0.0781 39 CaOH+ 0.32848E-07 -7.4835 0.27440E-07 -7.5616 0.83538E+00 -0.0781 40 CaSO4,aq 0.17806E-09 -9.7494 0.17806E-09 -9.7494 0.10000E+01 0.0000 41 HCl,aq 0.28533E-14 -14.5447 0.28533E-14 -14.5447 0.10000E+01 0.0000 45 HF,aq 0.20936E-11 -11.6791 0.20936E-11 -11.6791 0.10000E+01 0.0000 46 HF2- 0.29557E-17 -17.5293 0.24643E-17 -17.6083 0.83375E+00 -0.0790 48 FeCl+ 0.92241E-17 -17.0351 0.77056E-17 -17.1132 0.83538E+00 -0.0781 51 FeF+ 0.58491E-17 -17.2329 0.48862E-17 -17.3110 0.83538E+00 -0.0781 53 FeO,aq 0.13853E-09 -9.8585 0.13853E-09 -9.8585 0.10000E+01 0.0000 54 FeOH+ 0.12183E-10 -10.9143 0.10177E-10 -10.9924 0.83538E+00 -0.0781 55 HFeO2- 0.19818E-07 -7.7029 0.16523E-07 -7.7819 0.83375E+00 -0.0790 56 FeO+ 0.60182E-16 -16.2205 0.50275E-16 -16.2987 0.83538E+00 -0.0781 58 FeO2- 0.16035E-08 -8.7949 0.13369E-08 -8.8739 0.83375E+00 -0.0790 59 HFeO2,aq 0.14915E-10 -10.8264 0.14915E-10 -10.8264 0.10000E+01 0.0000 60 H2,aq 0.23399E-06 -6.6308 0.23314E-06 -6.6324 0.99637E+00 -0.0016 61 KCl,aq 0.42065E-09 -9.3761 0.42065E-09 -9.3761 0.10000E+01 0.0000 62 KHSO4,aq 0.53842E-18 -18.2689 0.53842E-18 -18.2689 0.10000E+01 0.0000 63 KOH,aq 0.63657E-06 -6.1962 0.63657E-06 -6.1962 0.10000E+01 0.0000 64 KSO4- 0.40405E-07 -7.3936 0.33687E-07 -7.4725 0.83375E+00 -0.0790 65 MgCO3,aq 0.83569E-11 -11.0780 0.83569E-11 -11.0780 0.10000E+01 0.0000 66 Mg(HCO3)+ 0.83375E-13 -13.0790 0.69650E-13 -13.1571 0.83538E+00 -0.0781 67 MgCl+ 0.34568E-14 -14.4613 0.28877E-14 -14.5394 0.83538E+00 -0.0781 68 MgF+ 0.25035E-14 -14.6015 0.20914E-14 -14.6796 0.83538E+00 -0.0781 69 MgOH+ 0.59692E-10 -10.2241 0.49865E-10 -10.3022 0.83538E+00 -0.0781 71 MnF+ 0.91638E-15 -15.0379 0.76552E-15 -15.1160 0.83538E+00 -0.0781 72 MnO,aq 0.17545E-08 -8.7559 0.17545E-08 -8.7559 0.10000E+01 0.0000 73 MnOH+ 0.53794E-09 -9.2693 0.44938E-09 -9.3474 0.83538E+00 -0.0781 74 MnO2-2 0.14703E-10 -10.8326 0.75669E-11 -11.1211 0.51465E+00 -0.2885 75 HMnO2- 0.17442E-09 -9.7584 0.14542E-09 -9.8374 0.83375E+00 -0.0790 78 MnCl+ 0.17057E-13 -13.7681 0.14249E-13 -13.8462 0.83538E+00 -0.0781 79 MnSO4,aq 0.62484E-13 -13.2042 0.62484E-13 -13.2042 0.10000E+01 0.0000 80 NaCl,aq 0.97558E-06 -6.0107 0.97558E-06 -6.0107 0.10000E+01 0.0000 81 NaF,aq 0.13536E-07 -7.8685 0.13536E-07 -7.8685 0.10000E+01 0.0000 82 NaOH,aq 0.81229E-04 -4.0903 0.81229E-04 -4.0903 0.10000E+01 0.0000 84 OH- 0.79145E-02 -2.1016 0.65866E-02 -2.1813 0.83221E+00 -0.0798 89 HPO3-2 0.33101E-16 -16.4802 0.17035E-16 -16.7686 0.51465E+00 -0.2885 92 H3PO4,aq 0.12619E-17 -17.8990 0.12619E-17 -17.8990 0.10000E+01 0.0000 93 H2PO4- 0.45465E-10 -10.3423 0.37943E-10 -10.4209 0.83455E+00 -0.0785 94 PO4-3 0.91206E-09 -9.0400 0.21809E-09 -9.6614 0.23911E+00 -0.6214 98 HP2O7-3 0.11286E-17 -17.9474 0.25695E-18 -18.5901 0.22767E+00 -0.6427 99 P2O7-4 0.93268E-17 -17.0303 0.69979E-18 -18.1550 0.75029E-01 -1.1248 100 H2S,aq 0.55528E-07 -7.2555 0.55327E-07 -7.2571 0.99637E+00 -0.0016 101 S2-2 0.76911E-11 -11.1140 0.39582E-11 -11.4025 0.51465E+00 -0.2885 102 S3-2 0.24590E-17 -17.6092 0.12655E-17 -17.8977 0.51465E+00 -0.2885 107 SO3-2 0.96314E-12 -12.0163 0.50300E-12 -12.2984 0.52225E+00 -0.2821 108 HSO3- 0.33135E-14 -14.4797 0.27627E-14 -14.5587 0.83375E+00 -0.0790 109 HSO4- 0.16785E-11 -11.7751 0.14036E-11 -11.8528 0.83621E+00 -0.0777 111 S2O3-2 0.20967E-13 -13.6785 0.10790E-13 -13.9670 0.51465E+00 -0.2885 Charge balance for all species = -.6132E-08 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.1045663E-09 -.2118633E-01 -.2131671E+02 0.0000 2 H2O 0.1000000E+01 0.5550354E+02 0.9981410E+06 0.0000 3 Cl- 0.2128991E-03 0.2138752E-03 0.7569078E+01 6.3061 4 SO4-- 0.3219066E-04 0.3217007E-04 0.3084832E+01 15.3340 5 HCO3- 0.2883293E-03 0.7542842E-03 0.4594275E+02 6.4385 6 HS- 0.2447319E-03 0.2448486E-03 0.8083283E+01 6.3667 7 Al+++ 0.1204237E-28 0.3333457E-05 0.8978227E-01 0.6083 8 H4SiO4 0.8136224E-03 0.1352427E-01 0.1297587E+04 -3.0896 9 Ca++ 0.6597800E-07 0.2087617E-06 0.8351924E-02 12.6424 10 Mg++ 0.2176917E-10 0.9316653E-10 0.2261051E-05 9.1588 11 Fe++ 0.5376814E-13 0.2158700E-07 0.1203432E-02 6.5520 12 K+ 0.1565566E-03 0.1572340E-03 0.6137266E+01 6.1734 13 Na+ 0.1989502E-01 0.2230027E-01 0.5117703E+03 8.2766 14 Mn++ 0.2553552E-10 0.2507136E-08 0.1374929E-03 9.2290 15 F- 0.4190367E-05 0.4203908E-05 0.7972431E-01 4.5993 16 HPO4-- 0.4545490E-07 0.4641243E-07 0.4446724E-02 12.4839 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.1903701E-01 -.1902982E-01 -.7190192E-05 0.0000000E+00 2 H2O 0.4985393E+02 0.4985394E+02 -.7129361E-05 0.0000000E+00 3 Cl- 0.1921052E-03 0.1921052E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.2889719E-04 0.2889554E-04 0.1650322E-08 0.0000000E+00 5 HCO3- 0.6775070E-03 0.6775070E-03 0.0000000E+00 0.0000000E+00 6 HS- 0.2199243E-03 0.2199259E-03 -.1650322E-08 0.0000000E+00 7 Al+++ 0.4775352E-05 0.2994150E-05 0.1781202E-05 0.0000000E+00 8 H4SiO4 0.1215302E-01 0.1214766E-01 0.5362641E-05 0.0000000E+00 9 Ca++ 0.2080835E-06 0.1875122E-06 0.2057127E-07 0.0000000E+00 10 Mg++ 0.8368328E-10 0.8368328E-10 0.0000000E+00 0.0000000E+00 11 Fe++ 0.3259227E-07 0.1938969E-07 0.1320258E-07 0.0000000E+00 12 K+ 0.1412294E-03 0.1412294E-03 0.0000000E+00 0.0000000E+00 13 Na+ 0.2003215E-01 0.2003037E-01 0.1780690E-05 0.0000000E+00 14 Mn++ 0.2251939E-08 0.2251939E-08 0.0000000E+00 0.0000000E+00 15 F- 0.3776000E-05 0.3776000E-05 0.0000000E+00 0.0000000E+00 16 HPO4-- 0.4168819E-07 0.4168819E-07 0.0000000E+00 0.0000000E+00 Chg. balance for solid moles: 0.0000E+00 Mass of aqueous solution: 0.899806E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 0.0091900 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 0.1781E-05 -5.749 0.4669E-03 -3.331 99.26 0.1792E-03 andradite 0.6601E-08 -8.180 0.3355E-05 -5.474 0.7131 0.8716E-06 grossular 0.2558E-09 -9.592 0.1152E-06 -6.938 0.2450E-01 0.3206E-07 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.9627E+00 0.9627E+00 1.0000 -0.017 grossular 0.3730E-01 0.3730E-01 1.0000 -1.428 Solid products produced: Mass = 0.000470 g Volume = 0.000180 cm3 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.0091900 moles log = -2.0367 Original solution: 1000.0103000 g Original solution / Rock added: 108815.05 (Water/Rock Ratio), log = 5.0367 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0206 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9997E+00 0.9859 0.1006E+01 0.1020E+01 CO2,gas 0.4697E-05 1.0071 0.4828E-05 0.4794E-05 CH4,gas 0.4094E-05 1.0125 0.4231E-05 0.4179E-05 H2,gas 0.2997E-03 1.0005 0.3061E-03 0.3059E-03 H2S,gas 0.1496E-05 0.9960 0.1521E-05 0.1527E-05 S2,gas 0.9081E-24 1.0000 0.9268E-24 0.9268E-24 CO,gas 0.3859E-12 1.0000 0.3938E-12 0.3938E-12 SO3,gas 0.4733E-40 1.0000 0.4831E-40 0.4831E-40 SO2,gas 0.5636E-21 1.0000 0.5752E-21 0.5752E-21 HF,gas 0.5037E-14 1.0000 0.5140E-14 0.5140E-14 HCl,gas 0.4933E-17 1.0000 0.5035E-17 0.5035E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 17 albite -0.38 -0.38 0.00 0.000 0.11184E-10 23 andradite 39.01 39.01 0.00 0.000 0.12132E-10 24 grossular 32.73 32.73 0.00 0.000 0.36397E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -13.68 -7.02 -2.338 0.11978E+05 -5.316 3 CH4,gas 4.54 -2.53 -7.07 -1.768 0.12076E+05 -5.374 4 H2,gas 8.00 2.79 -5.21 -2.979 0.89013E+04 -3.514 5 H2S,gas -6.23 -13.75 -7.52 -3.758 0.12835E+05 -5.818 6 S2,gas -7.34 -33.07 -25.73 -3.959 0.43937E+05 -24.033 7 CO,gas 3.21 -10.89 -14.10 -4.340 0.24082E+05 -12.405 8 SO3,gas 17.12 -24.89 -42.01 -10.504 0.71739E+05 -40.316 9 SO2,gas 0.83 -22.11 -22.94 -6.117 0.39168E+05 -21.240 10 HF,gas 0.47 -15.51 -15.99 -7.994 0.27299E+05 -14.289 11 HCl,gas 5.19 -13.81 -19.00 -9.499 0.32437E+05 -17.298 12 acmite 7.71 7.26 -0.45 -0.047 0.77454E+03 16 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 20 spessartine 24.46 19.63 -4.82 -0.241 0.82346E+04 21 analcite 3.32 2.71 -0.62 -0.068 0.10521E+04 27 annite 20.12 17.17 -2.95 -0.164 0.50449E+04 28 phlogopite 27.06 24.99 -2.08 -0.115 0.35435E+04 33 apatite-OH -18.15 -20.02 -1.87 -0.144 0.31856E+04 34 apatite-F -34.30 -35.53 -1.23 -0.103 0.21049E+04 38 aragonite 0.97 -1.03 -2.00 -0.666 0.34140E+04 39 brucite 12.57 9.16 -3.41 -0.682 0.58221E+04 40 calcite 0.81 -1.03 -1.84 -0.615 0.31498E+04 41 carnegieite-low 9.02 5.80 -3.23 -0.461 0.55117E+04 42 carnegieite-high 10.09 5.80 -4.30 -0.614 0.73387E+04 43 carpholite-Mg 8.58 4.20 -4.39 -0.292 0.74888E+04 45 celadonite 5.34 3.58 -1.76 -0.103 0.30043E+04 46 celadonite-Fe 3.88 0.98 -2.90 -0.171 0.49538E+04 47 chrysotile 23.89 21.30 -2.60 -0.216 0.44312E+04 49 clinochlore 39.07 37.74 -1.33 -0.041 0.22671E+04 50 daphnite 28.97 24.71 -4.26 -0.133 0.72698E+04 52 chlorite-Al-free 47.17 42.59 -4.58 -0.191 0.78175E+04 54 chloritoid-Fe 9.17 4.68 -4.49 -0.300 0.76746E+04 55 chloritoid-Mn 11.40 7.36 -4.05 -0.270 0.69070E+04 57 coesite -2.38 -3.09 -0.71 -0.238 0.12183E+04 64 cristobalite -2.56 -3.09 -0.53 -0.176 0.90366E+03 66 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71244E+04 68 diaspore 2.87 0.61 -2.27 -0.378 0.38682E+04 69 diamond -3.10 -8.10 -5.00 -1.428 0.85368E+04 70 diopside 16.18 15.62 -0.56 -0.056 0.95504E+03 71 hedenbergite 14.21 13.02 -1.19 -0.119 0.20372E+04 78 epidote 24.67 22.39 -2.28 -0.110 0.38908E+04 79 clinozoisite 22.81 17.84 -4.97 -0.226 0.84779E+04 80 epidote-Fe 29.84 26.94 -2.90 -0.151 0.49503E+04 81 fayalite 14.05 10.01 -4.03 -0.576 0.68835E+04 82 ferrosilite 11.15 6.92 -4.22 -0.422 0.72135E+04 86 gibbsite 4.08 0.61 -3.47 -0.496 0.59267E+04 87 glaucophane 22.97 20.53 -2.45 -0.066 0.41753E+04 88 glaucophane-Fe 17.28 12.71 -4.57 -0.123 0.77977E+04 89 graphite -3.55 -8.10 -4.56 -1.302 0.77791E+04 90 greenalite 16.14 13.48 -2.66 -0.222 0.45466E+04 93 hematite 12.57 10.32 -2.25 -0.273 0.38399E+04 94 heulandite -5.83 -7.77 -1.94 -0.088 0.33140E+04 98 jadeite 4.22 2.71 -1.51 -0.151 0.25775E+04 99 julgoldite 70.43 65.77 -4.66 -0.121 0.79505E+04 100 kalsilite 7.58 3.69 -3.89 -0.556 0.66452E+04 101 kaolinite -1.33 -4.96 -3.63 -0.330 0.61979E+04 104 laumontite 2.88 1.50 -1.38 -0.092 0.23611E+04 105 lawsonite 9.62 7.68 -1.94 -0.129 0.33062E+04 106 leucite 4.12 0.60 -3.52 -0.352 0.60041E+04 108 lizardite 23.24 21.30 -1.95 -0.162 0.33238E+04 110 magnetite 20.09 16.87 -3.22 -0.263 0.54949E+04 111 minnesotaite 10.39 7.30 -3.09 -0.182 0.52770E+04 115 manganosite 14.06 9.23 -4.83 -1.207 0.82457E+04 119 microcline -2.49 -2.49 0.00 0.000 0.10444E+01 123 muscovite 2.58 -1.27 -3.85 -0.227 0.65789E+04 124 paragonite 4.24 0.83 -3.41 -0.200 0.58170E+04 125 nepheline 8.34 5.80 -2.54 -0.363 0.43441E+04 137 phlogopite-Na 29.65 27.09 -2.55 -0.142 0.43613E+04 139 prehnite 19.37 17.23 -2.14 -0.126 0.36528E+04 140 prehnite-Fe 22.50 21.78 -0.71 -0.043 0.12207E+04 141 pumpellyite-Fe 46.27 41.63 -4.64 -0.103 0.79296E+04 142 pumpellyite-Mg 48.99 44.23 -4.76 -0.106 0.81321E+04 145 pyrite -21.25 -23.73 -2.48 -0.584 0.42379E+04 146 pyrrhotite -4.26 -7.20 -2.93 -0.978 0.50111E+04 147 pyrrhotiteFe0.875 -6.02 -8.36 -2.34 -0.862 0.40002E+04 148 pyroxmangite 7.40 6.14 -1.26 -0.252 0.21502E+04 149 pyrophyllite -6.18 -11.14 -4.97 -0.310 0.84793E+04 150 quartz -2.99 -3.09 -0.10 -0.033 0.17099E+03 154 rhodochrosite -0.98 -4.45 -3.47 -1.157 0.59250E+04 155 rhodonite 7.45 6.14 -1.31 -0.261 0.22305E+04 156 sanidine -1.28 -2.49 -1.21 -0.093 0.20688E+04 158 siderite -2.61 -7.12 -4.52 -1.505 0.77096E+04 166 stilbite -7.52 -7.77 -0.25 -0.012 0.42016E+03 167 stilpnomelane-Fe 13.02 12.35 -0.67 -0.020 0.11450E+04 168 stilpnomelane-Mg 27.44 25.38 -2.06 -0.062 0.35188E+04 174 talc 16.49 15.12 -1.37 -0.081 0.23443E+04 177 tephroite 18.09 15.37 -2.72 -0.388 0.46400E+04 181 tridymite -2.63 -3.09 -0.46 -0.154 0.79097E+03 182 tremolite 47.87 46.36 -1.51 -0.041 0.25734E+04 184 troilite-low -4.41 -7.20 -2.78 -0.928 0.47539E+04 190 wairakite 3.95 1.50 -2.45 -0.144 0.41831E+04 191 walstromite 11.51 9.55 -1.96 -0.391 0.33405E+04 192 wollastonite 10.46 9.55 -0.91 -0.182 0.15510E+04 193 pseudo-wollastonite 11.00 9.55 -1.45 -0.289 0.24708E+04 195 akaganeite 7.75 5.16 -2.60 -0.561 0.44325E+04 202 chalcedony -2.80 -3.09 -0.29 -0.096 0.49029E+03 204 montmorillonite-Ca -2.29 -6.23 -3.94 -0.244 0.67332E+04 205 montmorillonite-K -2.24 -6.28 -4.05 -0.248 0.69087E+04 206 montmorillonite-Mg -2.48 -6.81 -4.33 -0.268 0.73917E+04 207 montmorillonite-Na -2.04 -5.59 -3.55 -0.217 0.60633E+04 208 nontronite-Ca 3.21 1.27 -1.95 -0.126 0.33283E+04 209 nontronite-H 2.53 -0.82 -3.35 -0.225 0.57259E+04 210 nontronite-K 3.34 1.22 -2.12 -0.136 0.36270E+04 211 nontronite-Mg 3.07 0.69 -2.38 -0.155 0.40708E+04 212 nontronite-Na 3.52 1.91 -1.61 -0.103 0.27476E+04 228 tobermorite 9.82 7.44 -2.38 -0.650 0.40664E+04 234 alabandite -0.98 -4.52 -3.54 -1.180 0.60449E+04 237 boehmite 4.41 0.61 -3.80 -0.633 0.64851E+04 239 ferrous-oxide 9.81 6.55 -3.26 -0.815 0.55657E+04 245 silica-amorphous -2.09 -3.09 -1.00 -0.333 0.17045E+04 247 an20ab80 2.02 1.23 -0.79 -0.061 0.13471E+04 248 an25ab75 2.65 1.63 -1.01 -0.078 0.17308E+04 249 an30ab70 3.28 2.04 -1.24 -0.096 0.21241E+04 250 tr.625ac.25prg.125 45.16 43.99 -1.17 -0.032 0.19993E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 0.0004000 MOLES Current total amount of reactant added: 0.0091900 MOLES New total amount of reactant added: 0.0095900 MOLES Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.5508E-08 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 7 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 0.0095900 Water: Moles liquid = 0.4986E+02 kg liquid = 0.8982E+00 Moles total = 0.4985E+02 kg total = 0.8981E+00 Activity = 1.0000 Stoichiometric ionic strength = .1194395E-01 Osmotic coef. = 0.9476 True ionic strength = .2057209E-01 Chg. balance for total moles = -.5508E-08 Max. difference allowed = 0.1945E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.10538E-09 -9.9773 0.88395E-10 -10.0536 0.83884E+00 -0.0763 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.21551E-03 -3.6665 0.17967E-03 -3.7455 0.83369E+00 -0.0790 4 SO4-- 0.34314E-04 -4.4645 0.17693E-04 -4.7522 0.51562E+00 -0.2877 5 HCO3- 0.30202E-03 -3.5200 0.25217E-03 -3.5983 0.83493E+00 -0.0783 6 HS- 0.25342E-03 -3.5962 0.21131E-03 -3.6751 0.83381E+00 -0.0789 7 Al+++ 0.12163E-28 -28.9150 0.27644E-29 -29.5584 0.22728E+00 -0.6434 8 H4SiO4 0.81944E-03 -3.0865 0.81944E-03 -3.0865 0.10000E+01 0.0000 9 Ca++ 0.65079E-07 -7.1866 0.33304E-07 -7.4775 0.51175E+00 -0.2909 10 Mg++ 0.21802E-10 -10.6615 0.11105E-10 -10.9545 0.50936E+00 -0.2930 11 Fe++ 0.56309E-13 -13.2494 0.28714E-13 -13.5419 0.50993E+00 -0.2925 12 K+ 0.15656E-03 -3.8053 0.13075E-03 -3.8836 0.83513E+00 -0.0782 13 Na+ 0.19897E-01 -1.7012 0.16584E-01 -1.7803 0.83353E+00 -0.0791 14 Mn++ 0.25906E-10 -10.5866 0.13221E-10 -10.8787 0.51036E+00 -0.2921 15 F- 0.43679E-05 -5.3597 0.36338E-05 -5.4396 0.83193E+00 -0.0799 16 HPO4-- 0.45461E-07 -7.3424 0.23444E-07 -7.6300 0.51569E+00 -0.2876 18 HSiO3- 0.10383E-01 -1.9837 0.86559E-02 -2.0627 0.83369E+00 -0.0790 19 Ca(HSiO3)+ 0.78595E-08 -8.1046 0.65652E-08 -8.1828 0.83532E+00 -0.0781 20 Mg(HSiO3)+ 0.32615E-11 -11.4866 0.27244E-11 -11.5647 0.83532E+00 -0.0781 21 NaHSiO3,aq 0.23218E-02 -2.6342 0.23218E-02 -2.6342 0.10000E+01 0.0000 22 AlO+ 0.57619E-16 -16.2394 0.48130E-16 -16.3176 0.83532E+00 -0.0781 24 HAlO2,aq 0.10843E-09 -9.9648 0.10843E-09 -9.9648 0.10000E+01 0.0000 25 AlO2- 0.32631E-05 -5.4864 0.27154E-05 -5.5662 0.83215E+00 -0.0798 26 CH4,aq 0.29361E-08 -8.5322 0.29254E-08 -8.5338 0.99636E+00 -0.0016 31 CO,aq 0.27641E-15 -15.5584 0.27641E-15 -15.5584 0.10000E+01 0.0000 32 CO2,aq 0.47803E-07 -7.3205 0.47629E-07 -7.3221 0.99636E+00 -0.0016 33 CO3-2 0.48430E-03 -3.3149 0.24917E-03 -3.6035 0.51450E+00 -0.2886 34 CaCO3,aq 0.10405E-06 -6.9827 0.10405E-06 -6.9827 0.10000E+01 0.0000 35 Ca(HCO3)+ 0.25663E-09 -9.5907 0.21437E-09 -9.6688 0.83532E+00 -0.0781 36 CaCl+ 0.11593E-10 -10.9358 0.96836E-11 -11.0140 0.83532E+00 -0.0781 37 CaCl2,aq 0.41335E-15 -15.3837 0.41335E-15 -15.3837 0.10000E+01 0.0000 38 CaF+ 0.21152E-11 -11.6746 0.17669E-11 -11.7528 0.83532E+00 -0.0781 39 CaOH+ 0.32146E-07 -7.4929 0.26852E-07 -7.5710 0.83532E+00 -0.0781 40 CaSO4,aq 0.18711E-09 -9.7279 0.18711E-09 -9.7279 0.10000E+01 0.0000 41 HCl,aq 0.29103E-14 -14.5361 0.29103E-14 -14.5361 0.10000E+01 0.0000 45 HF,aq 0.21989E-11 -11.6578 0.21989E-11 -11.6578 0.10000E+01 0.0000 46 HF2- 0.32359E-17 -17.4900 0.26978E-17 -17.5690 0.83369E+00 -0.0790 48 FeCl+ 0.97758E-17 -17.0098 0.81659E-17 -17.0880 0.83532E+00 -0.0781 51 FeF+ 0.63832E-17 -17.1950 0.53320E-17 -17.2731 0.83532E+00 -0.0781 53 FeO,aq 0.14282E-09 -9.8452 0.14282E-09 -9.8452 0.10000E+01 0.0000 54 FeOH+ 0.12658E-10 -10.8976 0.10574E-10 -10.9758 0.83532E+00 -0.0781 55 HFeO2- 0.20278E-07 -7.6930 0.16906E-07 -7.7720 0.83369E+00 -0.0790 56 FeO+ 0.62817E-16 -16.2019 0.52472E-16 -16.2801 0.83532E+00 -0.0781 58 FeO2- 0.16482E-08 -8.7830 0.13741E-08 -8.8620 0.83369E+00 -0.0790 59 HFeO2,aq 0.15448E-10 -10.8111 0.15448E-10 -10.8111 0.10000E+01 0.0000 60 H2,aq 0.23187E-06 -6.6348 0.23102E-06 -6.6363 0.99636E+00 -0.0016 61 KCl,aq 0.42576E-09 -9.3708 0.42576E-09 -9.3708 0.10000E+01 0.0000 62 KHSO4,aq 0.57815E-18 -18.2380 0.57815E-18 -18.2380 0.10000E+01 0.0000 63 KOH,aq 0.63167E-06 -6.1995 0.63167E-06 -6.1995 0.10000E+01 0.0000 64 KSO4- 0.43058E-07 -7.3660 0.35897E-07 -7.4449 0.83369E+00 -0.0790 65 MgCO3,aq 0.86968E-11 -11.0606 0.86968E-11 -11.0606 0.10000E+01 0.0000 66 Mg(HCO3)+ 0.87440E-13 -13.0583 0.73040E-13 -13.1364 0.83532E+00 -0.0781 67 MgCl+ 0.35035E-14 -14.4555 0.29265E-14 -14.5336 0.83532E+00 -0.0781 68 MgF+ 0.26127E-14 -14.5829 0.21824E-14 -14.6611 0.83532E+00 -0.0781 69 MgOH+ 0.59312E-10 -10.2269 0.49544E-10 -10.3050 0.83532E+00 -0.0781 71 MnF+ 0.96877E-15 -15.0138 0.80923E-15 -15.0919 0.83532E+00 -0.0781 72 MnO,aq 0.17523E-08 -8.7564 0.17523E-08 -8.7564 0.10000E+01 0.0000 73 MnOH+ 0.54145E-09 -9.2664 0.45229E-09 -9.3446 0.83532E+00 -0.0781 74 MnO2-2 0.14466E-10 -10.8397 0.74427E-11 -11.1283 0.51450E+00 -0.2886 75 HMnO2- 0.17289E-09 -9.7622 0.14413E-09 -9.8412 0.83369E+00 -0.0790 78 MnCl+ 0.17512E-13 -13.7567 0.14628E-13 -13.8348 0.83532E+00 -0.0781 79 MnSO4,aq 0.67532E-13 -13.1705 0.67532E-13 -13.1705 0.10000E+01 0.0000 80 NaCl,aq 0.98749E-06 -6.0055 0.98749E-06 -6.0055 0.10000E+01 0.0000 81 NaF,aq 0.14109E-07 -7.8505 0.14109E-07 -7.8505 0.10000E+01 0.0000 82 NaOH,aq 0.80610E-04 -4.0936 0.80610E-04 -4.0936 0.10000E+01 0.0000 84 OH- 0.78547E-02 -2.1049 0.65363E-02 -2.1847 0.83215E+00 -0.0798 89 HPO3-2 0.32805E-16 -16.4841 0.16878E-16 -16.7727 0.51450E+00 -0.2886 92 H3PO4,aq 0.12812E-17 -17.8924 0.12812E-17 -17.8924 0.10000E+01 0.0000 93 H2PO4- 0.45811E-10 -10.3390 0.38229E-10 -10.4176 0.83449E+00 -0.0786 94 PO4-3 0.90551E-09 -9.0431 0.21639E-09 -9.6648 0.23897E+00 -0.6217 98 HP2O7-3 0.11377E-17 -17.9440 0.25885E-18 -18.5869 0.22752E+00 -0.6430 99 P2O7-4 0.93345E-17 -17.0299 0.69957E-18 -18.1552 0.74944E-01 -1.1253 100 H2S,aq 0.57939E-07 -7.2370 0.57728E-07 -7.2386 0.99636E+00 -0.0016 101 S2-2 0.83237E-11 -11.0797 0.42826E-11 -11.3683 0.51450E+00 -0.2886 102 S3-2 0.28022E-17 -17.5525 0.14417E-17 -17.8411 0.51450E+00 -0.2886 107 SO3-2 0.10174E-11 -11.9925 0.53116E-12 -12.2748 0.52210E+00 -0.2822 108 HSO3- 0.35262E-14 -14.4527 0.29398E-14 -14.5317 0.83369E+00 -0.0790 109 HSO4- 0.18026E-11 -11.7441 0.15072E-11 -11.8218 0.83615E+00 -0.0777 111 S2O3-2 0.23320E-13 -13.6323 0.11998E-13 -13.9209 0.51450E+00 -0.2886 Charge balance for all species = -.6132E-08 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.1053778E-09 -.2113795E-01 -.2126799E+02 0.0000 2 H2O 0.1000000E+01 0.5550349E+02 0.9981384E+06 0.0000 3 Cl- 0.2155130E-03 0.2165010E-03 0.7661994E+01 6.3080 4 SO4-- 0.3431377E-04 0.3429632E-04 0.3288716E+01 15.3549 5 HCO3- 0.3020197E-03 0.7864756E-03 0.4790342E+02 6.4553 6 HS- 0.2534230E-03 0.2535417E-03 0.8370258E+01 6.3785 7 Al+++ 0.1216260E-28 0.3263205E-05 0.8789000E-01 0.6023 8 H4SiO4 0.8194375E-03 0.1352396E-01 0.1297555E+04 -3.0865 9 Ca++ 0.6507861E-07 0.2095951E-06 0.8385251E-02 12.6296 10 Mg++ 0.2180191E-10 0.9316583E-10 0.2261030E-05 9.1527 11 Fe++ 0.5630947E-13 0.2209748E-07 0.1231889E-02 6.5652 12 K+ 0.1565576E-03 0.1572328E-03 0.6137210E+01 6.1700 13 Na+ 0.1989663E-01 0.2230003E-01 0.5117640E+03 8.2733 14 Mn++ 0.2590587E-10 0.2507117E-08 0.1374917E-03 9.2284 15 F- 0.4367893E-05 0.4382007E-05 0.8310170E-01 4.6139 16 HPO4-- 0.4546075E-07 0.4641207E-07 0.4446683E-02 12.4772 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.1899394E-01 -.1898650E-01 -.7440188E-05 0.0000000E+00 2 H2O 0.4985426E+02 0.4985427E+02 -.7381612E-05 0.0000000E+00 3 Cl- 0.1944652E-03 0.1944652E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.3080719E-04 0.3080560E-04 0.1592988E-08 0.0000000E+00 5 HCO3- 0.7064270E-03 0.7064270E-03 0.0000000E+00 0.0000000E+00 6 HS- 0.2277343E-03 0.2277359E-03 -.1592988E-08 0.0000000E+00 7 Al+++ 0.4775352E-05 0.2931072E-05 0.1844280E-05 0.0000000E+00 8 H4SiO4 0.1215302E-01 0.1214747E-01 0.5551251E-05 0.0000000E+00 9 Ca++ 0.2080835E-06 0.1882622E-06 0.1982131E-07 0.0000000E+00 10 Mg++ 0.8368328E-10 0.8368328E-10 0.0000000E+00 0.0000000E+00 11 Fe++ 0.3259227E-07 0.1984836E-07 0.1274391E-07 0.0000000E+00 12 K+ 0.1412294E-03 0.1412294E-03 0.0000000E+00 0.0000000E+00 13 Na+ 0.2003215E-01 0.2003031E-01 0.1843810E-05 0.0000000E+00 14 Mn++ 0.2251939E-08 0.2251939E-08 0.0000000E+00 0.0000000E+00 15 F- 0.3936000E-05 0.3936000E-05 0.0000000E+00 0.0000000E+00 16 HPO4-- 0.4168819E-07 0.4168819E-07 0.0000000E+00 0.0000000E+00 Chg. balance for solid moles: -.2118E-21 Mass of aqueous solution: 0.899815E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 0.0095900 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 0.1844E-05 -5.734 0.4835E-03 -3.316 99.31 0.1856E-03 andradite 0.6372E-08 -8.196 0.3238E-05 -5.490 0.6651 0.8413E-06 grossular 0.2351E-09 -9.629 0.1059E-06 -6.975 0.2176E-01 0.2947E-07 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.9644E+00 0.9644E+00 1.0000 -0.016 grossular 0.3559E-01 0.3559E-01 1.0000 -1.449 Solid products produced: Mass = 0.000487 g Volume = 0.000186 cm3 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.0095900 moles log = -2.0182 Original solution: 1000.0103000 g Original solution / Rock added: 104276.36 (Water/Rock Ratio), log = 5.0182 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0206 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9997E+00 0.9859 0.1006E+01 0.1020E+01 CO2,gas 0.4958E-05 1.0071 0.5096E-05 0.5060E-05 CH4,gas 0.4167E-05 1.0125 0.4306E-05 0.4253E-05 H2,gas 0.2970E-03 1.0005 0.3033E-03 0.3031E-03 H2S,gas 0.1561E-05 0.9960 0.1587E-05 0.1593E-05 S2,gas 0.1007E-23 1.0000 0.1028E-23 0.1028E-23 CO,gas 0.4036E-12 1.0000 0.4119E-12 0.4119E-12 SO3,gas 0.5122E-40 1.0000 0.5227E-40 0.5227E-40 SO2,gas 0.6044E-21 1.0000 0.6168E-21 0.6168E-21 HF,gas 0.5290E-14 1.0000 0.5399E-14 0.5399E-14 HCl,gas 0.5032E-17 1.0000 0.5135E-17 0.5135E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 17 albite -0.38 -0.38 0.00 0.000 -0.94784E-12 23 andradite 39.01 39.01 0.00 0.000 -0.12132E-10 24 grossular 32.73 32.73 0.00 0.000 0.00000E+00 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -13.65 -6.99 -2.331 0.11938E+05 -5.293 3 CH4,gas 4.54 -2.52 -7.06 -1.766 0.12063E+05 -5.366 4 H2,gas 8.00 2.78 -5.22 -2.981 0.89080E+04 -3.518 5 H2S,gas -6.23 -13.73 -7.50 -3.749 0.12803E+05 -5.799 6 S2,gas -7.34 -33.02 -25.69 -3.952 0.43860E+05 -23.988 7 CO,gas 3.21 -10.87 -14.08 -4.334 0.24048E+05 -12.385 8 SO3,gas 17.12 -24.86 -41.98 -10.495 0.71681E+05 -40.282 9 SO2,gas 0.83 -22.08 -22.91 -6.109 0.39116E+05 -21.210 10 HF,gas 0.47 -15.49 -15.97 -7.983 0.27263E+05 -14.268 11 HCl,gas 5.19 -13.80 -18.99 -9.494 0.32422E+05 -17.289 12 acmite 7.71 7.27 -0.44 -0.045 0.74362E+03 16 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 20 spessartine 24.46 19.63 -4.83 -0.241 0.82418E+04 21 analcite 3.32 2.70 -0.62 -0.069 0.10573E+04 27 annite 20.12 17.21 -2.91 -0.162 0.49770E+04 28 phlogopite 27.06 24.97 -2.09 -0.116 0.35750E+04 33 apatite-OH -18.15 -20.06 -1.91 -0.147 0.32607E+04 34 apatite-F -34.30 -35.56 -1.26 -0.105 0.21435E+04 38 aragonite 0.97 -1.02 -1.99 -0.663 0.33958E+04 39 brucite 12.57 9.15 -3.42 -0.683 0.58326E+04 40 calcite 0.81 -1.02 -1.83 -0.611 0.31315E+04 41 carnegieite-low 9.02 5.79 -3.23 -0.462 0.55223E+04 42 carnegieite-high 10.09 5.79 -4.30 -0.615 0.73493E+04 43 carpholite-Mg 8.58 4.18 -4.40 -0.293 0.75091E+04 45 celadonite 5.34 3.58 -1.76 -0.104 0.30095E+04 46 celadonite-Fe 3.88 0.99 -2.88 -0.170 0.49259E+04 47 chrysotile 23.89 21.29 -2.61 -0.217 0.44520E+04 49 clinochlore 39.07 37.71 -1.36 -0.043 0.23239E+04 50 daphnite 28.97 24.77 -4.19 -0.131 0.71609E+04 52 chlorite-Al-free 47.17 42.57 -4.60 -0.192 0.78592E+04 54 chloritoid-Fe 9.17 4.68 -4.49 -0.299 0.76670E+04 55 chloritoid-Mn 11.40 7.35 -4.05 -0.270 0.69230E+04 57 coesite -2.38 -3.09 -0.71 -0.237 0.12130E+04 64 cristobalite -2.56 -3.09 -0.53 -0.175 0.89838E+03 66 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71245E+04 68 diaspore 2.87 0.60 -2.27 -0.379 0.38783E+04 69 diamond -3.10 -8.09 -4.98 -1.424 0.85103E+04 70 diopside 16.18 15.61 -0.57 -0.057 0.97671E+03 71 hedenbergite 14.21 13.02 -1.19 -0.119 0.20257E+04 78 epidote 24.67 22.38 -2.29 -0.111 0.39128E+04 79 clinozoisite 22.81 17.81 -5.00 -0.227 0.85361E+04 80 epidote-Fe 29.84 26.95 -2.89 -0.150 0.49361E+04 81 fayalite 14.05 10.04 -4.00 -0.572 0.68329E+04 82 ferrosilite 11.15 6.96 -4.19 -0.419 0.71576E+04 86 gibbsite 4.08 0.60 -3.48 -0.497 0.59369E+04 87 glaucophane 22.97 20.52 -2.46 -0.066 0.41961E+04 88 glaucophane-Fe 17.28 12.76 -4.52 -0.122 0.77192E+04 89 graphite -3.55 -8.09 -4.54 -1.297 0.77526E+04 90 greenalite 16.14 13.52 -2.62 -0.218 0.44681E+04 93 hematite 12.57 10.35 -2.22 -0.269 0.37878E+04 94 heulandite -5.83 -7.77 -1.94 -0.088 0.33191E+04 98 jadeite 4.22 2.70 -1.51 -0.151 0.25828E+04 99 julgoldite 70.43 65.83 -4.60 -0.120 0.78564E+04 100 kalsilite 7.58 3.69 -3.90 -0.557 0.66559E+04 101 kaolinite -1.33 -4.97 -3.64 -0.331 0.62076E+04 104 laumontite 2.88 1.49 -1.40 -0.093 0.23821E+04 105 lawsonite 9.62 7.66 -1.95 -0.130 0.33377E+04 106 leucite 4.12 0.60 -3.52 -0.352 0.60095E+04 108 lizardite 23.24 21.29 -1.96 -0.163 0.33446E+04 110 magnetite 20.09 16.91 -3.17 -0.259 0.54201E+04 111 minnesotaite 10.39 7.35 -3.04 -0.179 0.51879E+04 115 manganosite 14.06 9.23 -4.83 -1.207 0.82466E+04 119 microcline -2.49 -2.49 0.00 0.000 0.10982E+01 123 muscovite 2.58 -1.28 -3.86 -0.227 0.65993E+04 124 paragonite 4.24 0.82 -3.42 -0.201 0.58373E+04 125 nepheline 8.34 5.79 -2.55 -0.364 0.43547E+04 137 phlogopite-Na 29.65 27.07 -2.57 -0.143 0.43927E+04 139 prehnite 19.37 17.20 -2.17 -0.127 0.37008E+04 140 prehnite-Fe 22.50 21.78 -0.72 -0.043 0.12325E+04 141 pumpellyite-Fe 46.27 41.58 -4.69 -0.104 0.80131E+04 142 pumpellyite-Mg 48.99 44.16 -4.83 -0.107 0.82488E+04 145 pyrite -21.25 -23.67 -2.43 -0.571 0.41454E+04 146 pyrrhotite -4.26 -7.16 -2.90 -0.968 0.49570E+04 147 pyrrhotiteFe0.875 -6.02 -8.33 -2.31 -0.850 0.39480E+04 148 pyroxmangite 7.40 6.14 -1.26 -0.251 0.21459E+04 149 pyrophyllite -6.18 -11.14 -4.97 -0.310 0.84785E+04 150 quartz -2.99 -3.09 -0.10 -0.032 0.16571E+03 154 rhodochrosite -0.98 -4.42 -3.45 -1.149 0.58859E+04 155 rhodonite 7.45 6.14 -1.30 -0.261 0.22261E+04 156 sanidine -1.28 -2.49 -1.21 -0.093 0.20688E+04 158 siderite -2.61 -7.09 -4.48 -1.493 0.76469E+04 166 stilbite -7.52 -7.77 -0.25 -0.012 0.42528E+03 167 stilpnomelane-Fe 13.02 12.42 -0.59 -0.018 0.10126E+04 168 stilpnomelane-Mg 27.44 25.36 -2.08 -0.062 0.35521E+04 174 talc 16.49 15.11 -1.38 -0.081 0.23546E+04 177 tephroite 18.09 15.37 -2.72 -0.388 0.46365E+04 181 tridymite -2.63 -3.09 -0.46 -0.153 0.78569E+03 182 tremolite 47.87 46.33 -1.54 -0.042 0.26270E+04 184 troilite-low -4.41 -7.16 -2.75 -0.917 0.46998E+04 190 wairakite 3.95 1.49 -2.46 -0.145 0.42040E+04 191 walstromite 11.51 9.54 -1.97 -0.393 0.33570E+04 192 wollastonite 10.46 9.54 -0.92 -0.184 0.15674E+04 193 pseudo-wollastonite 11.00 9.54 -1.46 -0.291 0.24873E+04 195 akaganeite 7.75 5.17 -2.58 -0.558 0.44064E+04 202 chalcedony -2.80 -3.09 -0.28 -0.095 0.48501E+03 204 montmorillonite-Ca -2.29 -6.24 -3.95 -0.244 0.67361E+04 205 montmorillonite-K -2.24 -6.28 -4.05 -0.248 0.69099E+04 206 montmorillonite-Mg -2.48 -6.81 -4.33 -0.268 0.73927E+04 207 montmorillonite-Na -2.04 -5.59 -3.55 -0.217 0.60645E+04 208 nontronite-Ca 3.21 1.30 -1.91 -0.124 0.32638E+04 209 nontronite-H 2.53 -0.78 -3.31 -0.222 0.56578E+04 210 nontronite-K 3.34 1.26 -2.09 -0.134 0.35608E+04 211 nontronite-Mg 3.07 0.73 -2.35 -0.152 0.40045E+04 212 nontronite-Na 3.52 1.95 -1.57 -0.101 0.26813E+04 228 tobermorite 9.82 7.43 -2.39 -0.652 0.40792E+04 234 alabandite -0.98 -4.50 -3.52 -1.174 0.60143E+04 237 boehmite 4.41 0.60 -3.80 -0.634 0.64952E+04 239 ferrous-oxide 9.81 6.57 -3.25 -0.812 0.55430E+04 245 silica-amorphous -2.09 -3.09 -1.00 -0.332 0.16992E+04 247 an20ab80 2.02 1.23 -0.79 -0.061 0.13534E+04 248 an25ab75 2.65 1.63 -1.02 -0.078 0.17387E+04 249 an30ab70 3.28 2.03 -1.25 -0.096 0.21336E+04 250 tr.625ac.25prg.125 45.16 43.98 -1.18 -0.032 0.20161E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 0.0004000 MOLES Current total amount of reactant added: 0.0095900 MOLES New total amount of reactant added: 0.0099900 MOLES Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.5508E-08 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 7 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 0.0099900 Water: Moles liquid = 0.4986E+02 kg liquid = 0.8982E+00 Moles total = 0.4985E+02 kg total = 0.8981E+00 Activity = 1.0000 Stoichiometric ionic strength = .1196963E-01 Osmotic coef. = 0.9472 True ionic strength = .2059420E-01 Chg. balance for total moles = -.5508E-08 Max. difference allowed = 0.1968E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.10620E-09 -9.9739 0.89078E-10 -10.0502 0.83878E+00 -0.0763 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.21813E-03 -3.6613 0.18184E-03 -3.7403 0.83363E+00 -0.0790 4 SO4-- 0.36437E-04 -4.4385 0.18782E-04 -4.7263 0.51547E+00 -0.2878 5 HCO3- 0.31583E-03 -3.5005 0.26368E-03 -3.5789 0.83487E+00 -0.0784 6 HS- 0.26211E-03 -3.5815 0.21854E-03 -3.6605 0.83375E+00 -0.0790 7 Al+++ 0.12285E-28 -28.9106 0.27903E-29 -29.5544 0.22714E+00 -0.6437 8 H4SiO4 0.82532E-03 -3.0834 0.82532E-03 -3.0834 0.10000E+01 0.0000 9 Ca++ 0.64219E-07 -7.1923 0.32855E-07 -7.4834 0.51160E+00 -0.2911 10 Mg++ 0.21835E-10 -10.6608 0.11119E-10 -10.9540 0.50921E+00 -0.2931 11 Fe++ 0.58954E-13 -13.2295 0.30053E-13 -13.5221 0.50978E+00 -0.2926 12 K+ 0.15656E-03 -3.8053 0.13074E-03 -3.8836 0.83508E+00 -0.0783 13 Na+ 0.19898E-01 -1.7012 0.16585E-01 -1.7803 0.83347E+00 -0.0791 14 Mn++ 0.26283E-10 -10.5803 0.13410E-10 -10.8726 0.51021E+00 -0.2922 15 F- 0.45454E-05 -5.3424 0.37812E-05 -5.4224 0.83187E+00 -0.0799 16 HPO4-- 0.45467E-07 -7.3423 0.23440E-07 -7.6300 0.51555E+00 -0.2877 18 HSiO3- 0.10378E-01 -1.9839 0.86512E-02 -2.0629 0.83363E+00 -0.0790 19 Ca(HSiO3)+ 0.77497E-08 -8.1107 0.64730E-08 -8.1889 0.83526E+00 -0.0782 20 Mg(HSiO3)+ 0.32639E-11 -11.4863 0.27262E-11 -11.5644 0.83526E+00 -0.0782 21 NaHSiO3,aq 0.23205E-02 -2.6344 0.23205E-02 -2.6344 0.10000E+01 0.0000 22 AlO+ 0.57274E-16 -16.2420 0.47839E-16 -16.3202 0.83526E+00 -0.0782 24 HAlO2,aq 0.10695E-09 -9.9708 0.10695E-09 -9.9708 0.10000E+01 0.0000 25 AlO2- 0.31940E-05 -5.4957 0.26577E-05 -5.5755 0.83209E+00 -0.0798 26 CH4,aq 0.29911E-08 -8.5242 0.29802E-08 -8.5258 0.99635E+00 -0.0016 31 CO,aq 0.28882E-15 -15.5394 0.28882E-15 -15.5394 0.10000E+01 0.0000 32 CO2,aq 0.50372E-07 -7.2978 0.50189E-07 -7.2994 0.99635E+00 -0.0016 33 CO3-2 0.50267E-03 -3.2987 0.25855E-03 -3.5875 0.51436E+00 -0.2887 34 CaCO3,aq 0.10651E-06 -6.9726 0.10651E-06 -6.9726 0.10000E+01 0.0000 35 Ca(HCO3)+ 0.26475E-09 -9.5772 0.22114E-09 -9.6553 0.83526E+00 -0.0782 36 CaCl+ 0.11575E-10 -10.9365 0.96681E-11 -11.0147 0.83526E+00 -0.0782 37 CaCl2,aq 0.41767E-15 -15.3792 0.41767E-15 -15.3792 0.10000E+01 0.0000 38 CaF+ 0.21715E-11 -11.6632 0.18138E-11 -11.7414 0.83526E+00 -0.0782 39 CaOH+ 0.31471E-07 -7.5021 0.26286E-07 -7.5803 0.83526E+00 -0.0782 40 CaSO4,aq 0.19595E-09 -9.7078 0.19595E-09 -9.7078 0.10000E+01 0.0000 41 HCl,aq 0.29682E-14 -14.5275 0.29682E-14 -14.5275 0.10000E+01 0.0000 45 HF,aq 0.23058E-11 -11.6372 0.23058E-11 -11.6372 0.10000E+01 0.0000 46 HF2- 0.35311E-17 -17.4521 0.29436E-17 -17.5311 0.83363E+00 -0.0790 48 FeCl+ 0.10356E-16 -16.9848 0.86499E-17 -17.0630 0.83526E+00 -0.0782 51 FeF+ 0.69525E-17 -17.1579 0.58071E-17 -17.2360 0.83526E+00 -0.0782 53 FeO,aq 0.14720E-09 -9.8321 0.14720E-09 -9.8321 0.10000E+01 0.0000 54 FeOH+ 0.13148E-10 -10.8811 0.10982E-10 -10.9593 0.83526E+00 -0.0782 55 HFeO2- 0.20741E-07 -7.6832 0.17290E-07 -7.7622 0.83363E+00 -0.0790 56 FeO+ 0.65524E-16 -16.1836 0.54729E-16 -16.2618 0.83526E+00 -0.0782 58 FeO2- 0.16930E-08 -8.7713 0.14113E-08 -8.8504 0.83363E+00 -0.0790 59 HFeO2,aq 0.15989E-10 -10.7962 0.15989E-10 -10.7962 0.10000E+01 0.0000 60 H2,aq 0.22992E-06 -6.6384 0.22908E-06 -6.6400 0.99635E+00 -0.0016 61 KCl,aq 0.43087E-09 -9.3657 0.43087E-09 -9.3657 0.10000E+01 0.0000 62 KHSO4,aq 0.61845E-18 -18.2087 0.61845E-18 -18.2087 0.10000E+01 0.0000 63 KOH,aq 0.62678E-06 -6.2029 0.62678E-06 -6.2029 0.10000E+01 0.0000 64 KSO4- 0.45709E-07 -7.3400 0.38104E-07 -7.4190 0.83363E+00 -0.0790 65 MgCO3,aq 0.90352E-11 -11.0441 0.90352E-11 -11.0441 0.10000E+01 0.0000 66 Mg(HCO3)+ 0.91551E-13 -13.0383 0.76469E-13 -13.1165 0.83526E+00 -0.0782 67 MgCl+ 0.35503E-14 -14.4497 0.29654E-14 -14.5279 0.83526E+00 -0.0782 68 MgF+ 0.27222E-14 -14.5651 0.22737E-14 -14.6433 0.83526E+00 -0.0782 69 MgOH+ 0.58933E-10 -10.2296 0.49225E-10 -10.3078 0.83526E+00 -0.0782 71 MnF+ 0.10225E-14 -14.9903 0.85406E-15 -15.0685 0.83526E+00 -0.0782 72 MnO,aq 0.17501E-08 -8.7569 0.17501E-08 -8.7569 0.10000E+01 0.0000 73 MnOH+ 0.54500E-09 -9.2636 0.45521E-09 -9.3418 0.83526E+00 -0.0782 74 MnO2-2 0.14231E-10 -10.8468 0.73198E-11 -11.1355 0.51436E+00 -0.2887 75 HMnO2- 0.17136E-09 -9.7661 0.14285E-09 -9.8451 0.83363E+00 -0.0790 78 MnCl+ 0.17977E-13 -13.7453 0.15015E-13 -13.8235 0.83526E+00 -0.0782 79 MnSO4,aq 0.72712E-13 -13.1384 0.72712E-13 -13.1384 0.10000E+01 0.0000 80 NaCl,aq 0.99941E-06 -6.0003 0.99941E-06 -6.0003 0.10000E+01 0.0000 81 NaF,aq 0.14682E-07 -7.8332 0.14682E-07 -7.8332 0.10000E+01 0.0000 82 NaOH,aq 0.79992E-04 -4.0970 0.79992E-04 -4.0970 0.10000E+01 0.0000 84 OH- 0.77950E-02 -2.1082 0.64861E-02 -2.1880 0.83209E+00 -0.0798 89 HPO3-2 0.32533E-16 -16.4877 0.16734E-16 -16.7764 0.51436E+00 -0.2887 92 H3PO4,aq 0.13009E-17 -17.8858 0.13009E-17 -17.8858 0.10000E+01 0.0000 93 H2PO4- 0.46161E-10 -10.3357 0.38518E-10 -10.4143 0.83443E+00 -0.0786 94 PO4-3 0.89897E-09 -9.0463 0.21470E-09 -9.6682 0.23882E+00 -0.6219 98 HP2O7-3 0.11469E-17 -17.9405 0.26077E-18 -18.5837 0.22737E+00 -0.6433 99 P2O7-4 0.93422E-17 -17.0296 0.69936E-18 -18.1553 0.74860E-01 -1.1257 100 H2S,aq 0.60385E-07 -7.2191 0.60165E-07 -7.2207 0.99635E+00 -0.0016 101 S2-2 0.89813E-11 -11.0467 0.46196E-11 -11.3354 0.51436E+00 -0.2887 102 S3-2 0.31780E-17 -17.4979 0.16346E-17 -17.7866 0.51436E+00 -0.2887 107 SO3-2 0.10712E-11 -11.9701 0.55912E-12 -12.2525 0.52196E+00 -0.2824 108 HSO3- 0.37408E-14 -14.4270 0.31185E-14 -14.5061 0.83363E+00 -0.0790 109 HSO4- 0.19285E-11 -11.7148 0.16124E-11 -11.7925 0.83609E+00 -0.0777 111 S2O3-2 0.25808E-13 -13.5883 0.13274E-13 -13.8770 0.51436E+00 -0.2887 Charge balance for all species = -.6132E-08 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.1061993E-09 -.2108956E-01 -.2121928E+02 0.0000 2 H2O 0.1000000E+01 0.5550343E+02 0.9981358E+06 0.0000 3 Cl- 0.2181269E-03 0.2191267E-03 0.7754908E+01 6.3099 4 SO4-- 0.3643689E-04 0.3642254E-04 0.3492596E+01 15.3742 5 HCO3- 0.3158326E-03 0.8186664E-03 0.4986405E+02 6.4713 6 HS- 0.2621140E-03 0.2622346E-03 0.8657227E+01 6.3898 7 Al+++ 0.1228458E-28 0.3194151E-05 0.8602998E-01 0.5963 8 H4SiO4 0.8253182E-03 0.1352365E-01 0.1297523E+04 -3.0834 9 Ca++ 0.6421886E-07 0.2104275E-06 0.8418540E-02 12.6171 10 Mg++ 0.2183493E-10 0.9316512E-10 0.2261009E-05 9.1465 11 Fe++ 0.5895363E-13 0.2261062E-07 0.1260493E-02 6.5784 12 K+ 0.1565587E-03 0.1572316E-03 0.6137154E+01 6.1666 13 Na+ 0.1989825E-01 0.2229980E-01 0.5117577E+03 8.2699 14 Mn++ 0.2628270E-10 0.2507098E-08 0.1374904E-03 9.2279 15 F- 0.4545417E-05 0.4560103E-05 0.8647903E-01 4.6279 16 HPO4-- 0.4546659E-07 0.4641172E-07 0.4446643E-02 12.4704 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.1895087E-01 -.1894318E-01 -.7685881E-05 0.0000000E+00 2 H2O 0.4985459E+02 0.4985460E+02 -.7629551E-05 0.0000000E+00 3 Cl- 0.1968252E-03 0.1968252E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.3271719E-04 0.3271565E-04 0.1535355E-08 0.0000000E+00 5 HCO3- 0.7353470E-03 0.7353470E-03 0.0000000E+00 0.0000000E+00 6 HS- 0.2355443E-03 0.2355458E-03 -.1535355E-08 0.0000000E+00 7 Al+++ 0.4775352E-05 0.2869068E-05 0.1906284E-05 0.0000000E+00 8 H4SiO4 0.1215302E-01 0.1214728E-01 0.5736630E-05 0.0000000E+00 9 Ca++ 0.2080835E-06 0.1890113E-06 0.1907220E-07 0.0000000E+00 10 Mg++ 0.8368328E-10 0.8368328E-10 0.0000000E+00 0.0000000E+00 11 Fe++ 0.3259227E-07 0.2030943E-07 0.1228284E-07 0.0000000E+00 12 K+ 0.1412294E-03 0.1412294E-03 0.0000000E+00 0.0000000E+00 13 Na+ 0.2003215E-01 0.2003024E-01 0.1905853E-05 0.0000000E+00 14 Mn++ 0.2251939E-08 0.2251939E-08 0.0000000E+00 0.0000000E+00 15 F- 0.4096000E-05 0.4096000E-05 0.0000000E+00 0.0000000E+00 16 HPO4-- 0.4168819E-07 0.4168819E-07 0.0000000E+00 0.0000000E+00 Chg. balance for solid moles: 0.1482E-20 Mass of aqueous solution: 0.899823E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 0.0099900 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 0.1906E-05 -5.720 0.4998E-03 -3.301 99.36 0.1918E-03 andradite 0.6141E-08 -8.212 0.3121E-05 -5.506 0.6205 0.8108E-06 grossular 0.2160E-09 -9.666 0.9729E-07 -7.012 0.1934E-01 0.2707E-07 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.9660E+00 0.9660E+00 1.0000 -0.015 grossular 0.3397E-01 0.3397E-01 1.0000 -1.469 Solid products produced: Mass = 0.000503 g Volume = 0.000193 cm3 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.0099900 moles log = -2.0004 Original solution: 1000.0103000 g Original solution / Rock added: 100101.13 (Water/Rock Ratio), log = 5.0004 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0206 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9997E+00 0.9859 0.1006E+01 0.1020E+01 CO2,gas 0.5224E-05 1.0071 0.5370E-05 0.5332E-05 CH4,gas 0.4245E-05 1.0125 0.4387E-05 0.4332E-05 H2,gas 0.2945E-03 1.0005 0.3008E-03 0.3006E-03 H2S,gas 0.1627E-05 0.9960 0.1654E-05 0.1660E-05 S2,gas 0.1112E-23 1.0000 0.1135E-23 0.1135E-23 CO,gas 0.4217E-12 1.0000 0.4304E-12 0.4304E-12 SO3,gas 0.5521E-40 1.0000 0.5635E-40 0.5635E-40 SO2,gas 0.6460E-21 1.0000 0.6594E-21 0.6594E-21 HF,gas 0.5547E-14 1.0000 0.5662E-14 0.5662E-14 HCl,gas 0.5132E-17 1.0000 0.5237E-17 0.5237E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 17 albite -0.38 -0.38 0.00 0.000 -0.94784E-12 23 andradite 39.01 39.01 0.00 0.000 0.12132E-10 24 grossular 32.73 32.73 0.00 0.000 0.00000E+00 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -13.63 -6.97 -2.323 0.11899E+05 -5.270 3 CH4,gas 4.54 -2.51 -7.06 -1.764 0.12049E+05 -5.358 4 H2,gas 8.00 2.78 -5.22 -2.983 0.89143E+04 -3.522 5 H2S,gas -6.23 -13.71 -7.48 -3.740 0.12773E+05 -5.781 6 S2,gas -7.34 -32.98 -25.64 -3.945 0.43786E+05 -23.945 7 CO,gas 3.21 -10.85 -14.07 -4.328 0.24016E+05 -12.366 8 SO3,gas 17.12 -24.83 -41.95 -10.487 0.71625E+05 -40.249 9 SO2,gas 0.83 -22.05 -22.88 -6.101 0.39067E+05 -21.181 10 HF,gas 0.47 -15.47 -15.95 -7.973 0.27227E+05 -14.247 11 HCl,gas 5.19 -13.79 -18.98 -9.490 0.32408E+05 -17.281 12 acmite 7.71 7.29 -0.42 -0.043 0.71318E+03 16 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 20 spessartine 24.46 19.63 -4.83 -0.242 0.82491E+04 21 analcite 3.32 2.70 -0.62 -0.069 0.10626E+04 27 annite 20.12 17.25 -2.88 -0.160 0.49099E+04 28 phlogopite 27.06 24.95 -2.11 -0.117 0.36066E+04 33 apatite-OH -18.15 -20.11 -1.95 -0.150 0.33342E+04 34 apatite-F -34.30 -35.58 -1.28 -0.106 0.21819E+04 38 aragonite 0.97 -1.01 -1.98 -0.660 0.33784E+04 39 brucite 12.57 9.15 -3.42 -0.684 0.58431E+04 40 calcite 0.81 -1.01 -1.82 -0.608 0.31142E+04 41 carnegieite-low 9.02 5.78 -3.24 -0.463 0.55329E+04 42 carnegieite-high 10.09 5.78 -4.31 -0.616 0.73599E+04 43 carpholite-Mg 8.58 4.17 -4.41 -0.294 0.75294E+04 45 celadonite 5.34 3.58 -1.77 -0.104 0.30148E+04 46 celadonite-Fe 3.88 1.01 -2.87 -0.169 0.48983E+04 47 chrysotile 23.89 21.27 -2.62 -0.218 0.44729E+04 49 clinochlore 39.07 37.68 -1.39 -0.044 0.23810E+04 50 daphnite 28.97 24.83 -4.13 -0.129 0.70535E+04 52 chlorite-Al-free 47.17 42.55 -4.63 -0.193 0.79010E+04 54 chloritoid-Fe 9.17 4.69 -4.49 -0.299 0.76597E+04 55 chloritoid-Mn 11.40 7.34 -4.06 -0.271 0.69390E+04 57 coesite -2.38 -3.08 -0.71 -0.236 0.12077E+04 64 cristobalite -2.56 -3.08 -0.52 -0.174 0.89308E+03 66 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71245E+04 68 diaspore 2.87 0.60 -2.28 -0.380 0.38885E+04 69 diamond -3.10 -8.07 -4.97 -1.420 0.84840E+04 70 diopside 16.18 15.60 -0.58 -0.058 0.99811E+03 71 hedenbergite 14.21 13.03 -1.18 -0.118 0.20142E+04 78 epidote 24.67 22.37 -2.30 -0.112 0.39347E+04 80 epidote-Fe 29.84 26.96 -2.88 -0.150 0.49223E+04 81 fayalite 14.05 10.07 -3.97 -0.567 0.67828E+04 82 ferrosilite 11.15 6.99 -4.16 -0.416 0.71022E+04 86 gibbsite 4.08 0.60 -3.48 -0.498 0.59471E+04 87 glaucophane 22.97 20.51 -2.47 -0.067 0.42171E+04 88 glaucophane-Fe 17.28 12.80 -4.48 -0.121 0.76414E+04 89 graphite -3.55 -8.07 -4.52 -1.293 0.77263E+04 90 greenalite 16.14 13.57 -2.57 -0.214 0.43903E+04 93 hematite 12.57 10.38 -2.19 -0.265 0.37368E+04 94 heulandite -5.83 -7.77 -1.95 -0.088 0.33239E+04 98 jadeite 4.22 2.70 -1.52 -0.152 0.25881E+04 99 julgoldite 70.43 65.88 -4.55 -0.118 0.77636E+04 100 kalsilite 7.58 3.68 -3.90 -0.558 0.66665E+04 101 kaolinite -1.33 -4.97 -3.64 -0.331 0.62175E+04 104 laumontite 2.88 1.48 -1.41 -0.094 0.24028E+04 105 lawsonite 9.62 7.64 -1.97 -0.132 0.33690E+04 106 leucite 4.12 0.60 -3.52 -0.352 0.60148E+04 108 lizardite 23.24 21.27 -1.97 -0.164 0.33656E+04 110 magnetite 20.09 16.96 -3.13 -0.256 0.53467E+04 111 minnesotaite 10.39 7.40 -2.99 -0.176 0.50995E+04 115 manganosite 14.06 9.23 -4.83 -1.208 0.82475E+04 119 microcline -2.49 -2.49 0.00 0.000 0.11523E+01 123 muscovite 2.58 -1.29 -3.88 -0.228 0.66198E+04 124 paragonite 4.24 0.81 -3.43 -0.202 0.58577E+04 125 nepheline 8.34 5.78 -2.56 -0.365 0.43653E+04 137 phlogopite-Na 29.65 27.06 -2.59 -0.144 0.44243E+04 139 prehnite 19.37 17.18 -2.20 -0.129 0.37483E+04 140 prehnite-Fe 22.50 21.77 -0.73 -0.044 0.12442E+04 141 pumpellyite-Fe 46.27 41.53 -4.74 -0.105 0.80959E+04 142 pumpellyite-Mg 48.99 44.10 -4.90 -0.109 0.83645E+04 145 pyrite -21.25 -23.62 -2.38 -0.559 0.40555E+04 146 pyrrhotite -4.26 -7.13 -2.87 -0.957 0.49039E+04 147 pyrrhotiteFe0.875 -6.02 -8.30 -2.28 -0.839 0.38969E+04 148 pyroxmangite 7.40 6.14 -1.25 -0.251 0.21415E+04 149 pyrophyllite -6.18 -11.14 -4.97 -0.310 0.84777E+04 150 quartz -2.99 -3.08 -0.09 -0.031 0.16041E+03 154 rhodochrosite -0.98 -4.40 -3.42 -1.142 0.58480E+04 155 rhodonite 7.45 6.14 -1.30 -0.260 0.22217E+04 156 sanidine -1.28 -2.49 -1.21 -0.093 0.20689E+04 158 siderite -2.61 -7.05 -4.44 -1.481 0.75857E+04 166 stilbite -7.52 -7.77 -0.25 -0.012 0.43007E+03 167 stilpnomelane-Fe 13.02 12.50 -0.52 -0.015 0.88149E+03 168 stilpnomelane-Mg 27.44 25.34 -2.10 -0.063 0.35855E+04 174 talc 16.49 15.11 -1.39 -0.081 0.23650E+04 177 tephroite 18.09 15.37 -2.71 -0.388 0.46331E+04 181 tridymite -2.63 -3.08 -0.46 -0.152 0.78038E+03 182 tremolite 47.87 46.30 -1.57 -0.042 0.26801E+04 183 ferroactinolite 38.45 33.46 -4.99 -0.135 0.85263E+04 184 troilite-low -4.41 -7.13 -2.72 -0.907 0.46467E+04 190 wairakite 3.95 1.48 -2.47 -0.146 0.42247E+04 191 walstromite 11.51 9.53 -1.98 -0.395 0.33732E+04 192 wollastonite 10.46 9.53 -0.93 -0.185 0.15836E+04 193 pseudo-wollastonite 11.00 9.53 -1.47 -0.293 0.25035E+04 195 akaganeite 7.75 5.19 -2.57 -0.555 0.43809E+04 202 chalcedony -2.80 -3.08 -0.28 -0.094 0.47970E+03 204 montmorillonite-Ca -2.29 -6.24 -3.95 -0.244 0.67390E+04 205 montmorillonite-K -2.24 -6.28 -4.05 -0.248 0.69111E+04 206 montmorillonite-Mg -2.48 -6.81 -4.33 -0.268 0.73938E+04 207 montmorillonite-Na -2.04 -5.59 -3.55 -0.218 0.60656E+04 208 nontronite-Ca 3.21 1.34 -1.87 -0.122 0.32002E+04 209 nontronite-H 2.53 -0.74 -3.27 -0.219 0.55906E+04 210 nontronite-K 3.34 1.29 -2.05 -0.131 0.34956E+04 211 nontronite-Mg 3.07 0.77 -2.31 -0.150 0.39391E+04 212 nontronite-Na 3.52 1.99 -1.53 -0.098 0.26161E+04 228 tobermorite 9.82 7.43 -2.40 -0.654 0.40918E+04 234 alabandite -0.98 -4.48 -3.50 -1.168 0.59846E+04 237 boehmite 4.41 0.60 -3.81 -0.635 0.65055E+04 239 ferrous-oxide 9.81 6.58 -3.23 -0.808 0.55207E+04 245 silica-amorphous -2.09 -3.08 -0.99 -0.331 0.16939E+04 247 an20ab80 2.02 1.22 -0.80 -0.061 0.13596E+04 248 an25ab75 2.65 1.62 -1.02 -0.079 0.17465E+04 249 an30ab70 3.28 2.02 -1.26 -0.097 0.21430E+04 250 tr.625ac.25prg.125 45.16 43.97 -1.19 -0.032 0.20326E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 0.0004000 MOLES Current total amount of reactant added: 0.0099900 MOLES New total amount of reactant added: 0.0103900 MOLES Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.5508E-08 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 7 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 0.0103900 Water: Moles liquid = 0.4986E+02 kg liquid = 0.8982E+00 Moles total = 0.4985E+02 kg total = 0.8982E+00 Activity = 1.0000 Stoichiometric ionic strength = .1199532E-01 Osmotic coef. = 0.9467 True ionic strength = .2061620E-01 Chg. balance for total moles = -.5508E-08 Max. difference allowed = 0.1992E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.10703E-09 -9.9705 0.89770E-10 -10.0469 0.83873E+00 -0.0764 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.22074E-03 -3.6561 0.18400E-03 -3.7352 0.83357E+00 -0.0791 4 SO4-- 0.38560E-04 -4.4139 0.19871E-04 -4.7018 0.51533E+00 -0.2879 5 HCO3- 0.32977E-03 -3.4818 0.27530E-03 -3.5602 0.83482E+00 -0.0784 6 HS- 0.27080E-03 -3.5673 0.22577E-03 -3.6463 0.83369E+00 -0.0790 7 Al+++ 0.12408E-28 -28.9063 0.28166E-29 -29.5503 0.22699E+00 -0.6440 8 H4SiO4 0.83127E-03 -3.0803 0.83127E-03 -3.0803 0.10000E+01 0.0000 9 Ca++ 0.63396E-07 -7.1979 0.32425E-07 -7.4891 0.51146E+00 -0.2912 10 Mg++ 0.21868E-10 -10.6602 0.11132E-10 -10.9534 0.50906E+00 -0.2932 11 Fe++ 0.61703E-13 -13.2097 0.31446E-13 -13.5024 0.50963E+00 -0.2927 12 K+ 0.15656E-03 -3.8053 0.13073E-03 -3.8836 0.83502E+00 -0.0783 13 Na+ 0.19900E-01 -1.7011 0.16585E-01 -1.7803 0.83341E+00 -0.0791 14 Mn++ 0.26666E-10 -10.5740 0.13601E-10 -10.8664 0.51007E+00 -0.2924 15 F- 0.47229E-05 -5.3258 0.39286E-05 -5.4058 0.83181E+00 -0.0800 16 HPO4-- 0.45472E-07 -7.3423 0.23437E-07 -7.6301 0.51540E+00 -0.2879 18 HSiO3- 0.10373E-01 -1.9841 0.86464E-02 -2.0632 0.83357E+00 -0.0791 19 Ca(HSiO3)+ 0.76446E-08 -8.1166 0.63848E-08 -8.1949 0.83520E+00 -0.0782 20 Mg(HSiO3)+ 0.32664E-11 -11.4859 0.27281E-11 -11.5641 0.83520E+00 -0.0782 21 NaHSiO3,aq 0.23193E-02 -2.6346 0.23193E-02 -2.6346 0.10000E+01 0.0000 22 AlO+ 0.56931E-16 -16.2447 0.47549E-16 -16.3229 0.83520E+00 -0.0782 24 HAlO2,aq 0.10548E-09 -9.9768 0.10548E-09 -9.9768 0.10000E+01 0.0000 25 AlO2- 0.31262E-05 -5.5050 0.26011E-05 -5.5848 0.83203E+00 -0.0799 26 CH4,aq 0.30494E-08 -8.5158 0.30383E-08 -8.5174 0.99635E+00 -0.0016 31 CO,aq 0.30150E-15 -15.5207 0.30150E-15 -15.5207 0.10000E+01 0.0000 32 CO2,aq 0.53000E-07 -7.2757 0.52806E-07 -7.2773 0.99635E+00 -0.0016 33 CO3-2 0.52092E-03 -3.2832 0.26786E-03 -3.5721 0.51421E+00 -0.2889 34 CaCO3,aq 0.10890E-06 -6.9630 0.10890E-06 -6.9630 0.10000E+01 0.0000 35 Ca(HCO3)+ 0.27281E-09 -9.5641 0.22785E-09 -9.6423 0.83520E+00 -0.0782 36 CaCl+ 0.11560E-10 -10.9370 0.96552E-11 -11.0152 0.83520E+00 -0.0782 37 CaCl2,aq 0.42208E-15 -15.3746 0.42208E-15 -15.3746 0.10000E+01 0.0000 38 CaF+ 0.22268E-11 -11.6523 0.18598E-11 -11.7305 0.83520E+00 -0.0782 39 CaOH+ 0.30822E-07 -7.5111 0.25742E-07 -7.5894 0.83520E+00 -0.0782 40 CaSO4,aq 0.20460E-09 -9.6891 0.20460E-09 -9.6891 0.10000E+01 0.0000 41 HCl,aq 0.30268E-14 -14.5190 0.30268E-14 -14.5190 0.10000E+01 0.0000 45 HF,aq 0.24143E-11 -11.6172 0.24143E-11 -11.6172 0.10000E+01 0.0000 46 HF2- 0.38416E-17 -17.4155 0.32023E-17 -17.4945 0.83357E+00 -0.0791 48 FeCl+ 0.10966E-16 -16.9600 0.91585E-17 -17.0382 0.83520E+00 -0.0782 51 FeF+ 0.75587E-17 -17.1216 0.63130E-17 -17.1998 0.83520E+00 -0.0782 53 FeO,aq 0.15166E-09 -9.8191 0.15166E-09 -9.8191 0.10000E+01 0.0000 54 FeOH+ 0.13652E-10 -10.8648 0.11403E-10 -10.9430 0.83520E+00 -0.0782 55 HFeO2- 0.21206E-07 -7.6735 0.17677E-07 -7.7526 0.83357E+00 -0.0791 56 FeO+ 0.68306E-16 -16.1655 0.57049E-16 -16.2438 0.83520E+00 -0.0782 58 FeO2- 0.17378E-08 -8.7600 0.14486E-08 -8.8391 0.83357E+00 -0.0791 59 HFeO2,aq 0.16539E-10 -10.7815 0.16539E-10 -10.7815 0.10000E+01 0.0000 60 H2,aq 0.22811E-06 -6.6418 0.22728E-06 -6.6434 0.99635E+00 -0.0016 61 KCl,aq 0.43597E-09 -9.3605 0.43597E-09 -9.3605 0.10000E+01 0.0000 62 KHSO4,aq 0.65934E-18 -18.1809 0.65934E-18 -18.1809 0.10000E+01 0.0000 63 KOH,aq 0.62192E-06 -6.2063 0.62192E-06 -6.2063 0.10000E+01 0.0000 64 KSO4- 0.48359E-07 -7.3155 0.40311E-07 -7.3946 0.83357E+00 -0.0791 65 MgCO3,aq 0.93721E-11 -11.0282 0.93721E-11 -11.0282 0.10000E+01 0.0000 66 Mg(HCO3)+ 0.95708E-13 -13.0190 0.79936E-13 -13.0973 0.83520E+00 -0.0782 67 MgCl+ 0.35973E-14 -14.4440 0.30044E-14 -14.5222 0.83520E+00 -0.0782 68 MgF+ 0.28320E-14 -14.5479 0.23653E-14 -14.6261 0.83520E+00 -0.0782 69 MgOH+ 0.58556E-10 -10.2324 0.48906E-10 -10.3106 0.83520E+00 -0.0782 71 MnF+ 0.10776E-14 -14.9675 0.90003E-15 -15.0457 0.83520E+00 -0.0782 72 MnO,aq 0.17479E-08 -8.7575 0.17479E-08 -8.7575 0.10000E+01 0.0000 73 MnOH+ 0.54857E-09 -9.2608 0.45816E-09 -9.3390 0.83520E+00 -0.0782 74 MnO2-2 0.13999E-10 -10.8539 0.71983E-11 -11.1428 0.51421E+00 -0.2889 75 HMnO2- 0.16984E-09 -9.7700 0.14157E-09 -9.8490 0.83357E+00 -0.0791 78 MnCl+ 0.18452E-13 -13.7339 0.15411E-13 -13.8122 0.83520E+00 -0.0782 79 MnSO4,aq 0.78027E-13 -13.1078 0.78027E-13 -13.1078 0.10000E+01 0.0000 80 NaCl,aq 0.10113E-05 -5.9951 0.10113E-05 -5.9951 0.10000E+01 0.0000 81 NaF,aq 0.15254E-07 -7.8166 0.15254E-07 -7.8166 0.10000E+01 0.0000 82 NaOH,aq 0.79377E-04 -4.1003 0.79377E-04 -4.1003 0.10000E+01 0.0000 84 OH- 0.77355E-02 -2.1115 0.64362E-02 -2.1914 0.83203E+00 -0.0799 89 HPO3-2 0.32282E-16 -16.4910 0.16600E-16 -16.7799 0.51421E+00 -0.2889 92 H3PO4,aq 0.13209E-17 -17.8791 0.13209E-17 -17.8791 0.10000E+01 0.0000 93 H2PO4- 0.46515E-10 -10.3324 0.38811E-10 -10.4110 0.83438E+00 -0.0786 94 PO4-3 0.89245E-09 -9.0494 0.21301E-09 -9.6716 0.23868E+00 -0.6222 98 HP2O7-3 0.11562E-17 -17.9370 0.26272E-18 -18.5805 0.22723E+00 -0.6435 99 P2O7-4 0.93498E-17 -17.0292 0.69914E-18 -18.1554 0.74776E-01 -1.1262 100 H2S,aq 0.62868E-07 -7.2016 0.62638E-07 -7.2032 0.99635E+00 -0.0016 101 S2-2 0.96639E-11 -11.0148 0.49693E-11 -11.3037 0.51421E+00 -0.2889 102 S3-2 0.35883E-17 -17.4451 0.18451E-17 -17.7340 0.51421E+00 -0.2889 107 SO3-2 0.11247E-11 -11.9490 0.58689E-12 -12.2314 0.52182E+00 -0.2825 108 HSO3- 0.39574E-14 -14.4026 0.32987E-14 -14.4817 0.83357E+00 -0.0791 109 HSO4- 0.20563E-11 -11.6869 0.17191E-11 -11.7647 0.83603E+00 -0.0778 111 S2O3-2 0.28434E-13 -13.5462 0.14621E-13 -13.8350 0.51421E+00 -0.2889 Charge balance for all species = -.6132E-08 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.1070307E-09 -.2104118E-01 -.2117057E+02 0.0000 2 H2O 0.1000000E+01 0.5550338E+02 0.9981333E+06 0.0000 3 Cl- 0.2207407E-03 0.2217525E-03 0.7847820E+01 6.3117 4 SO4-- 0.3856002E-04 0.3854873E-04 0.3696473E+01 15.3920 5 HCO3- 0.3297692E-03 0.8508568E-03 0.5182465E+02 6.4867 6 HS- 0.2708047E-03 0.2709275E-03 0.8944191E+01 6.4005 7 Al+++ 0.1240833E-28 0.3126281E-05 0.8420185E-01 0.5903 8 H4SiO4 0.8312654E-03 0.1352334E-01 0.1297492E+04 -3.0803 9 Ca++ 0.6339632E-07 0.2112585E-06 0.8451774E-02 12.6046 10 Mg++ 0.2186823E-10 0.9316442E-10 0.2260989E-05 9.1403 11 Fe++ 0.6170334E-13 0.2312590E-07 0.1289217E-02 6.5913 12 K+ 0.1565597E-03 0.1572304E-03 0.6137098E+01 6.1632 13 Na+ 0.1989987E-01 0.2229956E-01 0.5117515E+03 8.2666 14 Mn++ 0.2666612E-10 0.2507079E-08 0.1374892E-03 9.2273 15 F- 0.4722937E-05 0.4738196E-05 0.8985629E-01 4.6411 16 HPO4-- 0.4547241E-07 0.4641137E-07 0.4446602E-02 12.4636 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.1890780E-01 -.1889987E-01 -.7927319E-05 0.0000000E+00 2 H2O 0.4985491E+02 0.4985492E+02 -.7873229E-05 0.0000000E+00 3 Cl- 0.1991852E-03 0.1991852E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.3462719E-04 0.3462571E-04 0.1477480E-08 0.0000000E+00 5 HCO3- 0.7642670E-03 0.7642670E-03 0.0000000E+00 0.0000000E+00 6 HS- 0.2433543E-03 0.2433558E-03 -.1477480E-08 0.0000000E+00 7 Al+++ 0.4775352E-05 0.2808126E-05 0.1967226E-05 0.0000000E+00 8 H4SiO4 0.1215302E-01 0.1214710E-01 0.5918814E-05 0.0000000E+00 9 Ca++ 0.2080835E-06 0.1897592E-06 0.1832429E-07 0.0000000E+00 10 Mg++ 0.8368328E-10 0.8368328E-10 0.0000000E+00 0.0000000E+00 11 Fe++ 0.3259227E-07 0.2077243E-07 0.1181984E-07 0.0000000E+00 12 K+ 0.1412294E-03 0.1412294E-03 0.0000000E+00 0.0000000E+00 13 Na+ 0.2003215E-01 0.2003018E-01 0.1966830E-05 0.0000000E+00 14 Mn++ 0.2251939E-08 0.2251939E-08 0.0000000E+00 0.0000000E+00 15 F- 0.4256000E-05 0.4256000E-05 0.0000000E+00 0.0000000E+00 16 HPO4-- 0.4168819E-07 0.4168819E-07 0.0000000E+00 0.0000000E+00 Chg. balance for solid moles: -.8470E-21 Mass of aqueous solution: 0.899831E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 0.0103900 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 0.1967E-05 -5.706 0.5157E-03 -3.288 99.40 0.1980E-03 andradite 0.5910E-08 -8.228 0.3003E-05 -5.522 0.5789 0.7803E-06 grossular 0.1982E-09 -9.703 0.8927E-07 -7.049 0.1721E-01 0.2484E-07 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.9676E+00 0.9676E+00 1.0000 -0.014 grossular 0.3245E-01 0.3245E-01 1.0000 -1.489 Solid products produced: Mass = 0.000519 g Volume = 0.000199 cm3 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.0103900 moles log = -1.9834 Original solution: 1000.0103000 g Original solution / Rock added: 96247.38 (Water/Rock Ratio), log = 4.9834 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0206 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9997E+00 0.9859 0.1006E+01 0.1020E+01 CO2,gas 0.5497E-05 1.0071 0.5650E-05 0.5610E-05 CH4,gas 0.4328E-05 1.0125 0.4472E-05 0.4417E-05 H2,gas 0.2922E-03 1.0005 0.2984E-03 0.2982E-03 H2S,gas 0.1694E-05 0.9960 0.1722E-05 0.1729E-05 S2,gas 0.1225E-23 1.0000 0.1250E-23 0.1250E-23 CO,gas 0.4402E-12 1.0000 0.4493E-12 0.4493E-12 SO3,gas 0.5932E-40 1.0000 0.6055E-40 0.6055E-40 SO2,gas 0.6887E-21 1.0000 0.7029E-21 0.7029E-21 HF,gas 0.5808E-14 1.0000 0.5928E-14 0.5928E-14 HCl,gas 0.5233E-17 1.0000 0.5341E-17 0.5341E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 17 albite -0.38 -0.38 0.00 0.000 -0.94784E-12 23 andradite 39.01 39.01 0.00 0.000 -0.12132E-10 24 grossular 32.73 32.73 0.00 0.000 0.12132E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -13.61 -6.95 -2.316 0.11862E+05 -5.248 3 CH4,gas 4.54 -2.50 -7.05 -1.762 0.12035E+05 -5.349 4 H2,gas 8.00 2.78 -5.22 -2.985 0.89202E+04 -3.525 5 H2S,gas -6.23 -13.69 -7.46 -3.731 0.12743E+05 -5.764 6 S2,gas -7.34 -32.94 -25.60 -3.939 0.43715E+05 -23.903 7 CO,gas 3.21 -10.83 -14.05 -4.322 0.23984E+05 -12.347 8 SO3,gas 17.12 -24.80 -41.92 -10.479 0.71572E+05 -40.218 9 SO2,gas 0.83 -22.02 -22.85 -6.094 0.39019E+05 -21.153 10 HF,gas 0.47 -15.45 -15.93 -7.963 0.27193E+05 -14.227 11 HCl,gas 5.19 -13.78 -18.97 -9.486 0.32393E+05 -17.272 12 acmite 7.71 7.31 -0.40 -0.042 0.68322E+03 16 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 20 spessartine 24.46 19.62 -4.84 -0.242 0.82564E+04 21 analcite 3.32 2.70 -0.63 -0.069 0.10680E+04 27 annite 20.12 17.29 -2.84 -0.158 0.48435E+04 28 phlogopite 27.06 24.93 -2.13 -0.118 0.36383E+04 33 apatite-OH -18.15 -20.15 -1.99 -0.153 0.34064E+04 34 apatite-F -34.30 -35.60 -1.30 -0.108 0.22199E+04 38 aragonite 0.97 -1.00 -1.97 -0.656 0.33620E+04 39 brucite 12.57 9.14 -3.43 -0.686 0.58536E+04 40 calcite 0.81 -1.00 -1.81 -0.605 0.30977E+04 41 carnegieite-low 9.02 5.78 -3.25 -0.464 0.55436E+04 42 carnegieite-high 10.09 5.78 -4.32 -0.617 0.73705E+04 43 carpholite-Mg 8.58 4.16 -4.42 -0.295 0.75498E+04 45 celadonite 5.34 3.57 -1.77 -0.104 0.30201E+04 46 celadonite-Fe 3.88 1.02 -2.85 -0.168 0.48709E+04 47 chrysotile 23.89 21.26 -2.63 -0.219 0.44940E+04 49 clinochlore 39.07 37.64 -1.43 -0.045 0.24383E+04 50 daphnite 28.97 24.90 -4.07 -0.127 0.69474E+04 52 chlorite-Al-free 47.17 42.52 -4.65 -0.194 0.79431E+04 54 chloritoid-Fe 9.17 4.69 -4.48 -0.299 0.76527E+04 55 chloritoid-Mn 11.40 7.33 -4.07 -0.272 0.69551E+04 57 coesite -2.38 -3.08 -0.70 -0.235 0.12024E+04 64 cristobalite -2.56 -3.08 -0.52 -0.173 0.88775E+03 66 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71246E+04 68 diaspore 2.87 0.59 -2.28 -0.381 0.38988E+04 69 diamond -3.10 -8.06 -4.95 -1.415 0.84580E+04 70 diopside 16.18 15.58 -0.60 -0.060 0.10193E+04 71 hedenbergite 14.21 13.04 -1.17 -0.117 0.20027E+04 78 epidote 24.67 22.35 -2.32 -0.112 0.39567E+04 80 epidote-Fe 29.84 26.97 -2.87 -0.149 0.49090E+04 81 fayalite 14.05 10.10 -3.94 -0.563 0.67332E+04 82 ferrosilite 11.15 7.02 -4.13 -0.413 0.70474E+04 86 gibbsite 4.08 0.59 -3.49 -0.498 0.59573E+04 87 glaucophane 22.97 20.49 -2.48 -0.067 0.42381E+04 88 glaucophane-Fe 17.28 12.85 -4.43 -0.120 0.75644E+04 89 graphite -3.55 -8.06 -4.51 -1.288 0.77003E+04 90 greenalite 16.14 13.61 -2.53 -0.211 0.43133E+04 93 hematite 12.57 10.41 -2.16 -0.262 0.36867E+04 94 heulandite -5.83 -7.78 -1.95 -0.089 0.33284E+04 98 jadeite 4.22 2.70 -1.52 -0.152 0.25935E+04 99 julgoldite 70.43 65.93 -4.49 -0.117 0.76722E+04 100 kalsilite 7.58 3.67 -3.91 -0.559 0.66772E+04 101 kaolinite -1.33 -4.98 -3.65 -0.332 0.62273E+04 104 laumontite 2.88 1.46 -1.42 -0.095 0.24232E+04 105 lawsonite 9.62 7.62 -1.99 -0.133 0.34001E+04 106 leucite 4.12 0.59 -3.53 -0.353 0.60202E+04 108 lizardite 23.24 21.26 -1.98 -0.165 0.33866E+04 110 magnetite 20.09 17.00 -3.09 -0.252 0.52745E+04 111 minnesotaite 10.39 7.45 -2.94 -0.173 0.50118E+04 115 manganosite 14.06 9.23 -4.83 -1.208 0.82484E+04 119 microcline -2.49 -2.49 0.00 0.000 0.12068E+01 123 muscovite 2.58 -1.31 -3.89 -0.229 0.66403E+04 124 paragonite 4.24 0.80 -3.44 -0.203 0.58782E+04 125 nepheline 8.34 5.78 -2.56 -0.366 0.43759E+04 137 phlogopite-Na 29.65 27.04 -2.61 -0.145 0.44559E+04 139 prehnite 19.37 17.15 -2.22 -0.131 0.37953E+04 140 prehnite-Fe 22.50 21.76 -0.74 -0.044 0.12560E+04 141 pumpellyite-Fe 46.27 41.48 -4.79 -0.106 0.81780E+04 142 pumpellyite-Mg 48.99 44.03 -4.97 -0.110 0.84793E+04 145 pyrite -21.25 -23.57 -2.32 -0.547 0.39677E+04 146 pyrrhotite -4.26 -7.10 -2.84 -0.947 0.48519E+04 147 pyrrhotiteFe0.875 -6.02 -8.27 -2.25 -0.829 0.38470E+04 148 pyroxmangite 7.40 6.15 -1.25 -0.250 0.21371E+04 149 pyrophyllite -6.18 -11.14 -4.96 -0.310 0.84769E+04 150 quartz -2.99 -3.08 -0.09 -0.030 0.15508E+03 154 rhodochrosite -0.98 -4.38 -3.40 -1.134 0.58112E+04 155 rhodonite 7.45 6.15 -1.30 -0.260 0.22173E+04 156 sanidine -1.28 -2.49 -1.21 -0.093 0.20690E+04 158 siderite -2.61 -7.02 -4.41 -1.469 0.75259E+04 166 stilbite -7.52 -7.78 -0.25 -0.012 0.43453E+03 167 stilpnomelane-Fe 13.02 12.58 -0.44 -0.013 0.75167E+03 168 stilpnomelane-Mg 27.44 25.32 -2.12 -0.063 0.36191E+04 174 talc 16.49 15.10 -1.39 -0.082 0.23753E+04 177 tephroite 18.09 15.37 -2.71 -0.387 0.46296E+04 181 tridymite -2.63 -3.08 -0.45 -0.151 0.77506E+03 182 tremolite 47.87 46.27 -1.60 -0.043 0.27328E+04 183 ferroactinolite 38.45 33.52 -4.93 -0.133 0.84156E+04 184 troilite-low -4.41 -7.10 -2.69 -0.897 0.45947E+04 190 wairakite 3.95 1.46 -2.49 -0.146 0.42452E+04 191 walstromite 11.51 9.52 -1.98 -0.397 0.33891E+04 192 wollastonite 10.46 9.52 -0.94 -0.187 0.15995E+04 193 pseudo-wollastonite 11.00 9.52 -1.48 -0.295 0.25194E+04 195 akaganeite 7.75 5.20 -2.55 -0.552 0.43559E+04 202 chalcedony -2.80 -3.08 -0.28 -0.093 0.47438E+03 204 montmorillonite-Ca -2.29 -6.24 -3.95 -0.244 0.67418E+04 205 montmorillonite-K -2.24 -6.29 -4.05 -0.248 0.69123E+04 206 montmorillonite-Mg -2.48 -6.81 -4.33 -0.268 0.73948E+04 207 montmorillonite-Na -2.04 -5.59 -3.55 -0.218 0.60668E+04 208 nontronite-Ca 3.21 1.38 -1.84 -0.119 0.31375E+04 209 nontronite-H 2.53 -0.70 -3.24 -0.217 0.55244E+04 210 nontronite-K 3.34 1.33 -2.01 -0.129 0.34312E+04 211 nontronite-Mg 3.07 0.81 -2.27 -0.147 0.38745E+04 212 nontronite-Na 3.52 2.03 -1.49 -0.096 0.25517E+04 228 tobermorite 9.82 7.42 -2.40 -0.656 0.41042E+04 234 alabandite -0.98 -4.47 -3.49 -1.163 0.59557E+04 237 boehmite 4.41 0.59 -3.82 -0.636 0.65157E+04 239 ferrous-oxide 9.81 6.59 -3.22 -0.805 0.54985E+04 245 silica-amorphous -2.09 -3.08 -0.99 -0.330 0.16886E+04 247 an20ab80 2.02 1.22 -0.80 -0.062 0.13658E+04 248 an25ab75 2.65 1.62 -1.03 -0.079 0.17543E+04 249 an30ab70 3.28 2.02 -1.26 -0.097 0.21523E+04 250 tr.625ac.25prg.125 45.16 43.96 -1.20 -0.032 0.20490E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 0.0004000 MOLES Current total amount of reactant added: 0.0103900 MOLES New total amount of reactant added: 0.0107900 MOLES Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.5508E-08 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 7 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 0.0107900 Water: Moles liquid = 0.4986E+02 kg liquid = 0.8982E+00 Moles total = 0.4986E+02 kg total = 0.8982E+00 Activity = 1.0000 Stoichiometric ionic strength = .1202101E-01 Osmotic coef. = 0.9463 True ionic strength = .2063807E-01 Chg. balance for total moles = -.5508E-08 Max. difference allowed = 0.2015E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.10787E-09 -9.9671 0.90470E-10 -10.0435 0.83867E+00 -0.0764 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.22335E-03 -3.6510 0.18617E-03 -3.7301 0.83351E+00 -0.0791 4 SO4-- 0.40683E-04 -4.3906 0.20959E-04 -4.6786 0.51519E+00 -0.2880 5 HCO3- 0.34383E-03 -3.4637 0.28702E-03 -3.5421 0.83476E+00 -0.0784 6 HS- 0.27950E-03 -3.5536 0.23300E-03 -3.6327 0.83363E+00 -0.0790 7 Al+++ 0.12534E-28 -28.9019 0.28433E-29 -29.5462 0.22685E+00 -0.6443 8 H4SiO4 0.83728E-03 -3.0771 0.83728E-03 -3.0771 0.10000E+01 0.0000 9 Ca++ 0.62609E-07 -7.2034 0.32013E-07 -7.4947 0.51131E+00 -0.2913 10 Mg++ 0.21902E-10 -10.6595 0.11146E-10 -10.9529 0.50892E+00 -0.2934 11 Fe++ 0.64562E-13 -13.1900 0.32893E-13 -13.4829 0.50949E+00 -0.2929 12 K+ 0.15656E-03 -3.8053 0.13072E-03 -3.8837 0.83496E+00 -0.0783 13 Na+ 0.19902E-01 -1.7011 0.16585E-01 -1.7803 0.83335E+00 -0.0792 14 Mn++ 0.27056E-10 -10.5677 0.13797E-10 -10.8602 0.50992E+00 -0.2925 15 F- 0.49005E-05 -5.3098 0.40760E-05 -5.3898 0.83175E+00 -0.0800 16 HPO4-- 0.45478E-07 -7.3422 0.23433E-07 -7.6302 0.51526E+00 -0.2880 18 HSiO3- 0.10368E-01 -1.9843 0.86416E-02 -2.0634 0.83351E+00 -0.0791 19 Ca(HSiO3)+ 0.75438E-08 -8.1224 0.63001E-08 -8.2006 0.83514E+00 -0.0782 20 Mg(HSiO3)+ 0.32688E-11 -11.4856 0.27300E-11 -11.5638 0.83514E+00 -0.0782 21 NaHSiO3,aq 0.23180E-02 -2.6349 0.23180E-02 -2.6349 0.10000E+01 0.0000 22 AlO+ 0.56588E-16 -16.2473 0.47259E-16 -16.3255 0.83514E+00 -0.0782 24 HAlO2,aq 0.10403E-09 -9.9828 0.10403E-09 -9.9828 0.10000E+01 0.0000 25 AlO2- 0.30595E-05 -5.5144 0.25454E-05 -5.5942 0.83197E+00 -0.0799 26 CH4,aq 0.31107E-08 -8.5071 0.30993E-08 -8.5087 0.99634E+00 -0.0016 31 CO,aq 0.31445E-15 -15.5025 0.31445E-15 -15.5025 0.10000E+01 0.0000 32 CO2,aq 0.55687E-07 -7.2542 0.55484E-07 -7.2558 0.99634E+00 -0.0016 33 CO3-2 0.53905E-03 -3.2684 0.27711E-03 -3.5574 0.51407E+00 -0.2890 34 CaCO3,aq 0.11123E-06 -6.9538 0.11123E-06 -6.9538 0.10000E+01 0.0000 35 Ca(HCO3)+ 0.28083E-09 -9.5516 0.23454E-09 -9.6298 0.83514E+00 -0.0782 36 CaCl+ 0.11549E-10 -10.9375 0.96447E-11 -11.0157 0.83514E+00 -0.0782 37 CaCl2,aq 0.42658E-15 -15.3700 0.42658E-15 -15.3700 0.10000E+01 0.0000 38 CaF+ 0.22811E-11 -11.6419 0.19050E-11 -11.7201 0.83514E+00 -0.0782 39 CaOH+ 0.30197E-07 -7.5200 0.25219E-07 -7.5983 0.83514E+00 -0.0782 40 CaSO4,aq 0.21306E-09 -9.6715 0.21306E-09 -9.6715 0.10000E+01 0.0000 41 HCl,aq 0.30863E-14 -14.5106 0.30863E-14 -14.5106 0.10000E+01 0.0000 45 HF,aq 0.25244E-11 -11.5978 0.25244E-11 -11.5978 0.10000E+01 0.0000 46 HF2- 0.41678E-17 -17.3801 0.34739E-17 -17.4592 0.83351E+00 -0.0791 48 FeCl+ 0.11606E-16 -16.9353 0.96928E-17 -17.0136 0.83514E+00 -0.0782 51 FeF+ 0.82037E-17 -17.0860 0.68513E-17 -17.1642 0.83514E+00 -0.0782 53 FeO,aq 0.15619E-09 -9.8063 0.15619E-09 -9.8063 0.10000E+01 0.0000 54 FeOH+ 0.14171E-10 -10.8486 0.11835E-10 -10.9268 0.83514E+00 -0.0782 55 HFeO2- 0.21673E-07 -7.6641 0.18064E-07 -7.7432 0.83351E+00 -0.0791 56 FeO+ 0.71164E-16 -16.1477 0.59432E-16 -16.2260 0.83514E+00 -0.0782 58 FeO2- 0.17826E-08 -8.7489 0.14858E-08 -8.8280 0.83351E+00 -0.0791 59 HFeO2,aq 0.17096E-10 -10.7671 0.17096E-10 -10.7671 0.10000E+01 0.0000 60 H2,aq 0.22643E-06 -6.6451 0.22561E-06 -6.6466 0.99634E+00 -0.0016 61 KCl,aq 0.44107E-09 -9.3555 0.44107E-09 -9.3555 0.10000E+01 0.0000 62 KHSO4,aq 0.70083E-18 -18.1544 0.70083E-18 -18.1544 0.10000E+01 0.0000 63 KOH,aq 0.61707E-06 -6.2097 0.61707E-06 -6.2097 0.10000E+01 0.0000 64 KSO4- 0.51008E-07 -7.2924 0.42516E-07 -7.3714 0.83351E+00 -0.0791 65 MgCO3,aq 0.97076E-11 -11.0129 0.97076E-11 -11.0129 0.10000E+01 0.0000 66 Mg(HCO3)+ 0.99914E-13 -13.0004 0.83442E-13 -13.0786 0.83514E+00 -0.0782 67 MgCl+ 0.36444E-14 -14.4384 0.30436E-14 -14.5166 0.83514E+00 -0.0782 68 MgF+ 0.29421E-14 -14.5313 0.24571E-14 -14.6096 0.83514E+00 -0.0782 69 MgOH+ 0.58179E-10 -10.2352 0.48588E-10 -10.3135 0.83514E+00 -0.0782 71 MnF+ 0.11342E-14 -14.9453 0.94718E-15 -15.0236 0.83514E+00 -0.0782 72 MnO,aq 0.17456E-08 -8.7580 0.17456E-08 -8.7580 0.10000E+01 0.0000 73 MnOH+ 0.55217E-09 -9.2579 0.46114E-09 -9.3362 0.83514E+00 -0.0782 74 MnO2-2 0.13769E-10 -10.8611 0.70782E-11 -11.1501 0.51407E+00 -0.2890 75 HMnO2- 0.16832E-09 -9.7739 0.14029E-09 -9.8530 0.83351E+00 -0.0791 78 MnCl+ 0.18939E-13 -13.7227 0.15816E-13 -13.8009 0.83514E+00 -0.0782 79 MnSO4,aq 0.83480E-13 -13.0784 0.83480E-13 -13.0784 0.10000E+01 0.0000 80 NaCl,aq 0.10232E-05 -5.9900 0.10232E-05 -5.9900 0.10000E+01 0.0000 81 NaF,aq 0.15826E-07 -7.8006 0.15826E-07 -7.8006 0.10000E+01 0.0000 82 NaOH,aq 0.78764E-04 -4.1037 0.78764E-04 -4.1037 0.10000E+01 0.0000 84 OH- 0.76762E-02 -2.1149 0.63864E-02 -2.1947 0.83197E+00 -0.0799 89 HPO3-2 0.32048E-16 -16.4942 0.16475E-16 -16.7832 0.51407E+00 -0.2890 92 H3PO4,aq 0.13414E-17 -17.8724 0.13414E-17 -17.8724 0.10000E+01 0.0000 93 H2PO4- 0.46874E-10 -10.3291 0.39108E-10 -10.4077 0.83432E+00 -0.0787 94 PO4-3 0.88594E-09 -9.0526 0.21133E-09 -9.6750 0.23854E+00 -0.6224 98 HP2O7-3 0.11656E-17 -17.9335 0.26468E-18 -18.5773 0.22708E+00 -0.6438 99 P2O7-4 0.93574E-17 -17.0288 0.69893E-18 -18.1556 0.74693E-01 -1.1267 100 H2S,aq 0.65387E-07 -7.1845 0.65148E-07 -7.1861 0.99634E+00 -0.0016 101 S2-2 0.10372E-10 -10.9841 0.53319E-11 -11.2731 0.51407E+00 -0.2890 102 S3-2 0.40352E-17 -17.3941 0.20743E-17 -17.6831 0.51407E+00 -0.2890 107 SO3-2 0.11779E-11 -11.9289 0.61447E-12 -12.2115 0.52168E+00 -0.2826 108 HSO3- 0.41760E-14 -14.3792 0.34807E-14 -14.4583 0.83351E+00 -0.0791 109 HSO4- 0.21859E-11 -11.6604 0.18274E-11 -11.7382 0.83598E+00 -0.0778 111 S2O3-2 0.31202E-13 -13.5058 0.16040E-13 -13.7948 0.51407E+00 -0.2890 Charge balance for all species = -.6132E-08 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.1078723E-09 -.2099281E-01 -.2112186E+02 0.0000 2 H2O 0.1000000E+01 0.5550333E+02 0.9981307E+06 0.0000 3 Cl- 0.2233545E-03 0.2243782E-03 0.7940731E+01 6.3134 4 SO4-- 0.4068316E-04 0.4067489E-04 0.3900346E+01 15.4084 5 HCO3- 0.3438305E-03 0.8830467E-03 0.5378521E+02 6.5014 6 HS- 0.2794952E-03 0.2796201E-03 0.9231150E+01 6.4108 7 Al+++ 0.1253388E-28 0.3059581E-05 0.8240526E-01 0.5843 8 H4SiO4 0.8372798E-03 0.1352304E-01 0.1297461E+04 -3.0771 9 Ca++ 0.6260878E-07 0.2120879E-06 0.8484943E-02 12.5923 10 Mg++ 0.2190182E-10 0.9316372E-10 0.2260968E-05 9.1341 11 Fe++ 0.6456157E-13 0.2364292E-07 0.1318038E-02 6.6041 12 K+ 0.1565607E-03 0.1572292E-03 0.6137042E+01 6.1598 13 Na+ 0.1990151E-01 0.2229933E-01 0.5117453E+03 8.2632 14 Mn++ 0.2705626E-10 0.2507060E-08 0.1374879E-03 9.2268 15 F- 0.4900455E-05 0.4916286E-05 0.9323350E-01 4.6537 16 HPO4-- 0.4547821E-07 0.4641102E-07 0.4446561E-02 12.4568 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.1886473E-01 -.1885656E-01 -.8164553E-05 0.0000000E+00 2 H2O 0.4985524E+02 0.4985525E+02 -.8112694E-05 0.0000000E+00 3 Cl- 0.2015452E-03 0.2015452E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.3653719E-04 0.3653577E-04 0.1419410E-08 0.0000000E+00 5 HCO3- 0.7931870E-03 0.7931870E-03 0.0000000E+00 0.0000000E+00 6 HS- 0.2511643E-03 0.2511657E-03 -.1419410E-08 0.0000000E+00 7 Al+++ 0.4775352E-05 0.2748235E-05 0.2027117E-05 0.0000000E+00 8 H4SiO4 0.1215302E-01 0.1214692E-01 0.6097840E-05 0.0000000E+00 9 Ca++ 0.2080835E-06 0.1905056E-06 0.1757785E-07 0.0000000E+00 10 Mg++ 0.8368328E-10 0.8368328E-10 0.0000000E+00 0.0000000E+00 11 Fe++ 0.3259227E-07 0.2123699E-07 0.1135528E-07 0.0000000E+00 12 K+ 0.1412294E-03 0.1412294E-03 0.0000000E+00 0.0000000E+00 13 Na+ 0.2003215E-01 0.2003012E-01 0.2026754E-05 0.0000000E+00 14 Mn++ 0.2251939E-08 0.2251939E-08 0.0000000E+00 0.0000000E+00 15 F- 0.4416000E-05 0.4416000E-05 0.0000000E+00 0.0000000E+00 16 HPO4-- 0.4168819E-07 0.4168819E-07 0.0000000E+00 0.0000000E+00 Chg. balance for solid moles: -.8470E-21 Mass of aqueous solution: 0.899839E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 0.0107900 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 0.2027E-05 -5.693 0.5315E-03 -3.275 99.44 0.2040E-03 andradite 0.5678E-08 -8.246 0.2885E-05 -5.540 0.5399 0.7496E-06 grossular 0.1816E-09 -9.741 0.8182E-07 -7.087 0.1531E-01 0.2277E-07 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.9690E+00 0.9690E+00 1.0000 -0.014 grossular 0.3100E-01 0.3100E-01 1.0000 -1.509 Solid products produced: Mass = 0.000534 g Volume = 0.000205 cm3 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.0107900 moles log = -1.9670 Original solution: 1000.0103000 g Original solution / Rock added: 92679.36 (Water/Rock Ratio), log = 4.9670 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0206 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9997E+00 0.9859 0.1006E+01 0.1020E+01 CO2,gas 0.5775E-05 1.0071 0.5936E-05 0.5894E-05 CH4,gas 0.4415E-05 1.0125 0.4562E-05 0.4506E-05 H2,gas 0.2901E-03 1.0005 0.2962E-03 0.2960E-03 H2S,gas 0.1762E-05 0.9960 0.1791E-05 0.1798E-05 S2,gas 0.1345E-23 1.0000 0.1372E-23 0.1372E-23 CO,gas 0.4591E-12 1.0000 0.4686E-12 0.4686E-12 SO3,gas 0.6355E-40 1.0000 0.6486E-40 0.6486E-40 SO2,gas 0.7323E-21 1.0000 0.7474E-21 0.7474E-21 HF,gas 0.6073E-14 1.0000 0.6198E-14 0.6198E-14 HCl,gas 0.5336E-17 1.0000 0.5446E-17 0.5446E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 17 albite -0.38 -0.38 0.00 0.000 0.11184E-10 23 andradite 39.01 39.01 0.00 0.000 0.36397E-10 24 grossular 32.73 32.73 0.00 0.000 0.00000E+00 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -13.59 -6.93 -2.308 0.11825E+05 -5.226 3 CH4,gas 4.54 -2.50 -7.04 -1.760 0.12020E+05 -5.341 4 H2,gas 8.00 2.77 -5.23 -2.987 0.89256E+04 -3.528 5 H2S,gas -6.23 -13.68 -7.45 -3.723 0.12714E+05 -5.747 6 S2,gas -7.34 -32.90 -25.56 -3.933 0.43646E+05 -23.863 7 CO,gas 3.21 -10.81 -14.03 -4.316 0.23953E+05 -12.329 8 SO3,gas 17.12 -24.77 -41.89 -10.472 0.71521E+05 -40.188 9 SO2,gas 0.83 -21.99 -22.83 -6.087 0.38974E+05 -21.126 10 HF,gas 0.47 -15.43 -15.91 -7.953 0.27160E+05 -14.208 11 HCl,gas 5.19 -13.77 -18.96 -9.481 0.32379E+05 -17.264 12 acmite 7.71 7.33 -0.38 -0.040 0.65369E+03 16 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 20 spessartine 24.46 19.62 -4.84 -0.242 0.82638E+04 21 analcite 3.32 2.69 -0.63 -0.070 0.10733E+04 27 annite 20.12 17.33 -2.80 -0.155 0.47781E+04 28 phlogopite 27.06 24.92 -2.15 -0.119 0.36701E+04 33 apatite-OH -18.15 -20.19 -2.04 -0.157 0.34771E+04 34 apatite-F -34.30 -35.62 -1.32 -0.110 0.22576E+04 38 aragonite 0.97 -0.99 -1.96 -0.653 0.33463E+04 39 brucite 12.57 9.13 -3.43 -0.687 0.58642E+04 40 calcite 0.81 -0.99 -1.81 -0.602 0.30821E+04 41 carnegieite-low 9.02 5.77 -3.25 -0.465 0.55542E+04 42 carnegieite-high 10.09 5.77 -4.32 -0.618 0.73812E+04 43 carpholite-Mg 8.58 4.15 -4.43 -0.296 0.75703E+04 45 celadonite 5.34 3.57 -1.77 -0.104 0.30254E+04 46 celadonite-Fe 3.88 1.04 -2.84 -0.167 0.48437E+04 47 chrysotile 23.89 21.25 -2.64 -0.220 0.45150E+04 49 clinochlore 39.07 37.61 -1.46 -0.046 0.24958E+04 50 daphnite 28.97 24.96 -4.01 -0.125 0.68427E+04 52 chlorite-Al-free 47.17 42.50 -4.68 -0.195 0.79853E+04 54 chloritoid-Fe 9.17 4.70 -4.48 -0.299 0.76461E+04 55 chloritoid-Mn 11.40 7.32 -4.08 -0.272 0.69713E+04 57 coesite -2.38 -3.08 -0.70 -0.234 0.11971E+04 64 cristobalite -2.56 -3.08 -0.52 -0.172 0.88241E+03 66 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71246E+04 68 diaspore 2.87 0.58 -2.29 -0.382 0.39091E+04 69 diamond -3.10 -8.04 -4.94 -1.411 0.84323E+04 70 diopside 16.18 15.57 -0.61 -0.061 0.10402E+04 71 hedenbergite 14.21 13.04 -1.17 -0.117 0.19911E+04 78 epidote 24.67 22.34 -2.33 -0.113 0.39786E+04 80 epidote-Fe 29.84 26.97 -2.87 -0.149 0.48960E+04 81 fayalite 14.05 10.13 -3.91 -0.559 0.66842E+04 82 ferrosilite 11.15 7.05 -4.10 -0.410 0.69930E+04 86 gibbsite 4.08 0.58 -3.49 -0.499 0.59676E+04 87 glaucophane 22.97 20.48 -2.49 -0.067 0.42592E+04 88 glaucophane-Fe 17.28 12.89 -4.39 -0.119 0.74881E+04 89 graphite -3.55 -8.04 -4.49 -1.284 0.76745E+04 90 greenalite 16.14 13.66 -2.48 -0.207 0.42370E+04 93 hematite 12.57 10.44 -2.13 -0.258 0.36375E+04 94 heulandite -5.83 -7.78 -1.95 -0.089 0.33325E+04 98 jadeite 4.22 2.69 -1.52 -0.152 0.25988E+04 99 julgoldite 70.43 65.99 -4.44 -0.115 0.75821E+04 100 kalsilite 7.58 3.67 -3.92 -0.560 0.66880E+04 101 kaolinite -1.33 -4.99 -3.65 -0.332 0.62372E+04 104 laumontite 2.88 1.45 -1.43 -0.095 0.24434E+04 105 lawsonite 9.62 7.61 -2.01 -0.134 0.34310E+04 106 leucite 4.12 0.59 -3.53 -0.353 0.60256E+04 108 lizardite 23.24 21.25 -2.00 -0.166 0.34077E+04 110 magnetite 20.09 17.04 -3.05 -0.249 0.52034E+04 111 minnesotaite 10.39 7.50 -2.88 -0.170 0.49249E+04 115 manganosite 14.06 9.23 -4.83 -1.208 0.82494E+04 119 microcline -2.49 -2.49 0.00 0.000 0.12616E+01 123 muscovite 2.58 -1.32 -3.90 -0.229 0.66609E+04 124 paragonite 4.24 0.78 -3.45 -0.203 0.58988E+04 125 nepheline 8.34 5.77 -2.57 -0.367 0.43866E+04 137 phlogopite-Na 29.65 27.02 -2.63 -0.146 0.44877E+04 139 prehnite 19.37 17.12 -2.25 -0.132 0.38418E+04 140 prehnite-Fe 22.50 21.76 -0.74 -0.045 0.12676E+04 141 pumpellyite-Fe 46.27 41.43 -4.84 -0.107 0.82595E+04 145 pyrite -21.25 -23.52 -2.27 -0.535 0.38822E+04 146 pyrrhotite -4.26 -7.07 -2.81 -0.937 0.48009E+04 147 pyrrhotiteFe0.875 -6.02 -8.24 -2.22 -0.818 0.37981E+04 148 pyroxmangite 7.40 6.15 -1.25 -0.250 0.21327E+04 149 pyrophyllite -6.18 -11.14 -4.96 -0.310 0.84761E+04 150 quartz -2.99 -3.08 -0.09 -0.029 0.14974E+03 154 rhodochrosite -0.98 -4.36 -3.38 -1.128 0.57755E+04 155 rhodonite 7.45 6.15 -1.30 -0.259 0.22130E+04 156 sanidine -1.28 -2.49 -1.21 -0.093 0.20690E+04 158 siderite -2.61 -6.98 -4.37 -1.458 0.74674E+04 166 stilbite -7.52 -7.78 -0.26 -0.012 0.43868E+03 167 stilpnomelane-Fe 13.02 12.65 -0.36 -0.011 0.62315E+03 168 stilpnomelane-Mg 27.44 25.30 -2.14 -0.064 0.36528E+04 174 talc 16.49 15.09 -1.40 -0.082 0.23857E+04 177 tephroite 18.09 15.38 -2.71 -0.387 0.46262E+04 181 tridymite -2.63 -3.08 -0.45 -0.150 0.76971E+03 182 tremolite 47.87 46.24 -1.63 -0.044 0.27850E+04 183 ferroactinolite 38.45 33.59 -4.86 -0.131 0.83056E+04 184 troilite-low -4.41 -7.07 -2.66 -0.887 0.45437E+04 190 wairakite 3.95 1.45 -2.50 -0.147 0.42653E+04 191 walstromite 11.51 9.52 -1.99 -0.399 0.34048E+04 192 wollastonite 10.46 9.52 -0.95 -0.189 0.16152E+04 193 pseudo-wollastonite 11.00 9.52 -1.48 -0.297 0.25350E+04 195 akaganeite 7.75 5.22 -2.54 -0.548 0.43313E+04 202 chalcedony -2.80 -3.08 -0.27 -0.092 0.46903E+03 204 montmorillonite-Ca -2.29 -6.24 -3.95 -0.244 0.67445E+04 205 montmorillonite-K -2.24 -6.29 -4.05 -0.248 0.69135E+04 206 montmorillonite-Mg -2.48 -6.81 -4.33 -0.268 0.73958E+04 207 montmorillonite-Na -2.04 -5.59 -3.55 -0.218 0.60680E+04 208 nontronite-Ca 3.21 1.41 -1.80 -0.117 0.30755E+04 209 nontronite-H 2.53 -0.66 -3.20 -0.214 0.54590E+04 210 nontronite-K 3.34 1.37 -1.97 -0.127 0.33677E+04 211 nontronite-Mg 3.07 0.84 -2.23 -0.145 0.38109E+04 212 nontronite-Na 3.52 2.06 -1.46 -0.094 0.24882E+04 228 tobermorite 9.82 7.41 -2.41 -0.658 0.41163E+04 234 alabandite -0.98 -4.45 -3.47 -1.157 0.59275E+04 237 boehmite 4.41 0.58 -3.82 -0.637 0.65260E+04 239 ferrous-oxide 9.81 6.60 -3.21 -0.802 0.54767E+04 245 silica-amorphous -2.09 -3.08 -0.99 -0.329 0.16832E+04 247 an20ab80 2.02 1.21 -0.80 -0.062 0.13720E+04 248 an25ab75 2.65 1.61 -1.03 -0.079 0.17620E+04 249 an30ab70 3.28 2.01 -1.27 -0.097 0.21616E+04 250 tr.625ac.25prg.125 45.16 43.96 -1.21 -0.033 0.20652E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 0.0004000 MOLES Current total amount of reactant added: 0.0107900 MOLES New total amount of reactant added: 0.0111900 MOLES Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.5508E-08 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 7 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 0.0111900 Water: Moles liquid = 0.4986E+02 kg liquid = 0.8982E+00 Moles total = 0.4986E+02 kg total = 0.8982E+00 Activity = 1.0000 Stoichiometric ionic strength = .1204671E-01 Osmotic coef. = 0.9459 True ionic strength = .2065983E-01 Chg. balance for total moles = -.5508E-08 Max. difference allowed = 0.2039E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.10872E-09 -9.9637 0.91178E-10 -10.0401 0.83862E+00 -0.0764 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.22597E-03 -3.6460 0.18833E-03 -3.7251 0.83345E+00 -0.0791 4 SO4-- 0.42806E-04 -4.3685 0.22047E-04 -4.6566 0.51504E+00 -0.2882 5 HCO3- 0.35802E-03 -3.4461 0.29884E-03 -3.5246 0.83470E+00 -0.0785 6 HS- 0.28819E-03 -3.5403 0.24022E-03 -3.6194 0.83358E+00 -0.0791 7 Al+++ 0.12661E-28 -28.8975 0.28703E-29 -29.5421 0.22670E+00 -0.6445 8 H4SiO4 0.84336E-03 -3.0740 0.84336E-03 -3.0740 0.10000E+01 0.0000 9 Ca++ 0.61854E-07 -7.2086 0.31618E-07 -7.5001 0.51117E+00 -0.2914 10 Mg++ 0.21936E-10 -10.6588 0.11160E-10 -10.9523 0.50877E+00 -0.2935 11 Fe++ 0.67532E-13 -13.1705 0.34397E-13 -13.4635 0.50934E+00 -0.2930 12 K+ 0.15656E-03 -3.8053 0.13071E-03 -3.8837 0.83490E+00 -0.0784 13 Na+ 0.19903E-01 -1.7011 0.16585E-01 -1.7803 0.83329E+00 -0.0792 14 Mn++ 0.27453E-10 -10.5614 0.13995E-10 -10.8540 0.50977E+00 -0.2926 15 F- 0.50780E-05 -5.2943 0.42233E-05 -5.3743 0.83169E+00 -0.0800 16 HPO4-- 0.45484E-07 -7.3421 0.23430E-07 -7.6302 0.51512E+00 -0.2881 18 HSiO3- 0.10363E-01 -1.9845 0.86367E-02 -2.0637 0.83345E+00 -0.0791 19 Ca(HSiO3)+ 0.74471E-08 -8.1280 0.62189E-08 -8.2063 0.83509E+00 -0.0783 20 Mg(HSiO3)+ 0.32713E-11 -11.4853 0.27319E-11 -11.5635 0.83509E+00 -0.0783 21 NaHSiO3,aq 0.23167E-02 -2.6351 0.23167E-02 -2.6351 0.10000E+01 0.0000 22 AlO+ 0.56247E-16 -16.2499 0.46971E-16 -16.3282 0.83509E+00 -0.0783 24 HAlO2,aq 0.10259E-09 -9.9889 0.10259E-09 -9.9889 0.10000E+01 0.0000 25 AlO2- 0.29939E-05 -5.5238 0.24907E-05 -5.6037 0.83191E+00 -0.0799 26 CH4,aq 0.31746E-08 -8.4983 0.31629E-08 -8.4999 0.99633E+00 -0.0016 31 CO,aq 0.32767E-15 -15.4846 0.32767E-15 -15.4846 0.10000E+01 0.0000 32 CO2,aq 0.58436E-07 -7.2333 0.58221E-07 -7.2349 0.99633E+00 -0.0016 33 CO3-2 0.55704E-03 -3.2541 0.28628E-03 -3.5432 0.51392E+00 -0.2891 34 CaCO3,aq 0.11350E-06 -6.9450 0.11350E-06 -6.9450 0.10000E+01 0.0000 35 Ca(HCO3)+ 0.28881E-09 -9.5394 0.24118E-09 -9.6176 0.83509E+00 -0.0783 36 CaCl+ 0.11540E-10 -10.9378 0.96366E-11 -11.0161 0.83509E+00 -0.0783 37 CaCl2,aq 0.43118E-15 -15.3653 0.43118E-15 -15.3653 0.10000E+01 0.0000 38 CaF+ 0.23346E-11 -11.6318 0.19496E-11 -11.7101 0.83509E+00 -0.0783 39 CaOH+ 0.29595E-07 -7.5288 0.24714E-07 -7.6071 0.83509E+00 -0.0783 40 CaSO4,aq 0.22136E-09 -9.6549 0.22136E-09 -9.6549 0.10000E+01 0.0000 41 HCl,aq 0.31467E-14 -14.5021 0.31467E-14 -14.5021 0.10000E+01 0.0000 45 HF,aq 0.26361E-11 -11.5790 0.26361E-11 -11.5790 0.10000E+01 0.0000 46 HF2- 0.45099E-17 -17.3458 0.37588E-17 -17.4250 0.83345E+00 -0.0791 48 FeCl+ 0.12279E-16 -16.9109 0.10254E-16 -16.9891 0.83509E+00 -0.0783 51 FeF+ 0.88894E-17 -17.0511 0.74234E-17 -17.1294 0.83509E+00 -0.0783 53 FeO,aq 0.16080E-09 -9.7937 0.16080E-09 -9.7937 0.10000E+01 0.0000 54 FeOH+ 0.14705E-10 -10.8325 0.12280E-10 -10.9108 0.83509E+00 -0.0783 55 HFeO2- 0.22141E-07 -7.6548 0.18453E-07 -7.7339 0.83345E+00 -0.0791 56 FeO+ 0.74100E-16 -16.1302 0.61880E-16 -16.2084 0.83509E+00 -0.0783 58 FeO2- 0.18274E-08 -8.7382 0.15231E-08 -8.8173 0.83345E+00 -0.0791 59 HFeO2,aq 0.17662E-10 -10.7530 0.17662E-10 -10.7530 0.10000E+01 0.0000 60 H2,aq 0.22487E-06 -6.6481 0.22404E-06 -6.6497 0.99633E+00 -0.0016 61 KCl,aq 0.44618E-09 -9.3505 0.44618E-09 -9.3505 0.10000E+01 0.0000 62 KHSO4,aq 0.74293E-18 -18.1291 0.74293E-18 -18.1291 0.10000E+01 0.0000 63 KOH,aq 0.61223E-06 -6.2131 0.61223E-06 -6.2131 0.10000E+01 0.0000 64 KSO4- 0.53656E-07 -7.2704 0.44720E-07 -7.3495 0.83345E+00 -0.0791 65 MgCO3,aq 0.10042E-10 -10.9982 0.10042E-10 -10.9982 0.10000E+01 0.0000 66 Mg(HCO3)+ 0.10417E-12 -12.9823 0.86989E-13 -13.0605 0.83509E+00 -0.0783 67 MgCl+ 0.36917E-14 -14.4328 0.30829E-14 -14.5110 0.83509E+00 -0.0783 68 MgF+ 0.30525E-14 -14.5153 0.25491E-14 -14.5936 0.83509E+00 -0.0783 69 MgOH+ 0.57804E-10 -10.2380 0.48271E-10 -10.3163 0.83509E+00 -0.0783 71 MnF+ 0.11921E-14 -14.9237 0.99554E-15 -15.0019 0.83509E+00 -0.0783 72 MnO,aq 0.17433E-08 -8.7586 0.17433E-08 -8.7586 0.10000E+01 0.0000 73 MnOH+ 0.55579E-09 -9.2551 0.46414E-09 -9.3334 0.83509E+00 -0.0783 74 MnO2-2 0.13542E-10 -10.8683 0.69594E-11 -11.1574 0.51392E+00 -0.2891 75 HMnO2- 0.16680E-09 -9.7778 0.13902E-09 -9.8569 0.83345E+00 -0.0791 78 MnCl+ 0.19436E-13 -13.7114 0.16231E-13 -13.7897 0.83509E+00 -0.0783 79 MnSO4,aq 0.89076E-13 -13.0502 0.89076E-13 -13.0502 0.10000E+01 0.0000 80 NaCl,aq 0.10351E-05 -5.9850 0.10351E-05 -5.9850 0.10000E+01 0.0000 81 NaF,aq 0.16399E-07 -7.7852 0.16399E-07 -7.7852 0.10000E+01 0.0000 82 NaOH,aq 0.78152E-04 -4.1071 0.78152E-04 -4.1071 0.10000E+01 0.0000 84 OH- 0.76171E-02 -2.1182 0.63368E-02 -2.1981 0.83191E+00 -0.0799 89 HPO3-2 0.31830E-16 -16.4972 0.16358E-16 -16.7863 0.51392E+00 -0.2891 92 H3PO4,aq 0.13623E-17 -17.8657 0.13623E-17 -17.8657 0.10000E+01 0.0000 93 H2PO4- 0.47238E-10 -10.3257 0.39408E-10 -10.4044 0.83426E+00 -0.0787 94 PO4-3 0.87944E-09 -9.0558 0.20966E-09 -9.6785 0.23840E+00 -0.6227 98 HP2O7-3 0.11751E-17 -17.9299 0.26668E-18 -18.5740 0.22694E+00 -0.6441 99 P2O7-4 0.93649E-17 -17.0285 0.69872E-18 -18.1557 0.74611E-01 -1.1272 100 H2S,aq 0.67944E-07 -7.1678 0.67695E-07 -7.1694 0.99633E+00 -0.0016 101 S2-2 0.11106E-10 -10.9545 0.57074E-11 -11.2436 0.51392E+00 -0.2891 102 S3-2 0.45208E-17 -17.3448 0.23234E-17 -17.6339 0.51392E+00 -0.2891 107 SO3-2 0.12307E-11 -11.9098 0.64188E-12 -12.1925 0.52154E+00 -0.2827 108 HSO3- 0.43967E-14 -14.3569 0.36644E-14 -14.4360 0.83345E+00 -0.0791 109 HSO4- 0.23175E-11 -11.6350 0.19373E-11 -11.7128 0.83592E+00 -0.0778 111 S2O3-2 0.34114E-13 -13.4671 0.17532E-13 -13.7562 0.51392E+00 -0.2891 Charge balance for all species = -.6132E-08 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.1087243E-09 -.2094445E-01 -.2107317E+02 0.0000 2 H2O 0.1000000E+01 0.5550327E+02 0.9981282E+06 0.0000 3 Cl- 0.2259682E-03 0.2270038E-03 0.8033640E+01 6.3150 4 SO4-- 0.4280629E-04 0.4280101E-04 0.4104215E+01 15.4236 5 HCO3- 0.3580177E-03 0.9152362E-03 0.5574574E+02 6.5155 6 HS- 0.2881856E-03 0.2883127E-03 0.9518104E+01 6.4207 7 Al+++ 0.1266128E-28 0.2994038E-05 0.8063983E-01 0.5783 8 H4SiO4 0.8433624E-03 0.1352274E-01 0.1297430E+04 -3.0740 9 Ca++ 0.6185422E-07 0.2129155E-06 0.8518036E-02 12.5802 10 Mg++ 0.2193570E-10 0.9316301E-10 0.2260947E-05 9.1279 11 Fe++ 0.6753155E-13 0.2416128E-07 0.1346933E-02 6.6167 12 K+ 0.1565617E-03 0.1572280E-03 0.6136986E+01 6.1564 13 Na+ 0.1990315E-01 0.2229909E-01 0.5117391E+03 8.2598 14 Mn++ 0.2745325E-10 0.2507041E-08 0.1374866E-03 9.2262 15 F- 0.5077971E-05 0.5094374E-05 0.9661064E-01 4.6658 16 HPO4-- 0.4548399E-07 0.4641067E-07 0.4446521E-02 12.4500 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.1882166E-01 -.1881326E-01 -.8397632E-05 0.0000000E+00 2 H2O 0.4985557E+02 0.4985558E+02 -.8347995E-05 0.0000000E+00 3 Cl- 0.2039052E-03 0.2039052E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.3844719E-04 0.3844583E-04 0.1361187E-08 0.0000000E+00 5 HCO3- 0.8221070E-03 0.8221070E-03 0.0000000E+00 0.0000000E+00 6 HS- 0.2589743E-03 0.2589756E-03 -.1361187E-08 0.0000000E+00 7 Al+++ 0.4775352E-05 0.2689382E-05 0.2085970E-05 0.0000000E+00 8 H4SiO4 0.1215302E-01 0.1214675E-01 0.6273746E-05 0.0000000E+00 9 Ca++ 0.2080835E-06 0.1912504E-06 0.1683308E-07 0.0000000E+00 10 Mg++ 0.8368328E-10 0.8368328E-10 0.0000000E+00 0.0000000E+00 11 Fe++ 0.3259227E-07 0.2170277E-07 0.1088950E-07 0.0000000E+00 12 K+ 0.1412294E-03 0.1412294E-03 0.0000000E+00 0.0000000E+00 13 Na+ 0.2003215E-01 0.2003006E-01 0.2085638E-05 0.0000000E+00 14 Mn++ 0.2251939E-08 0.2251939E-08 0.0000000E+00 0.0000000E+00 15 F- 0.4576000E-05 0.4576000E-05 0.0000000E+00 0.0000000E+00 16 HPO4-- 0.4168819E-07 0.4168819E-07 0.0000000E+00 0.0000000E+00 Chg. balance for solid moles: -.8470E-21 Mass of aqueous solution: 0.899848E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 0.0111900 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 0.2086E-05 -5.681 0.5469E-03 -3.262 99.48 0.2099E-03 andradite 0.5445E-08 -8.264 0.2767E-05 -5.558 0.5033 0.7189E-06 grossular 0.1663E-09 -9.779 0.7490E-07 -7.126 0.1362E-01 0.2084E-07 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.9704E+00 0.9704E+00 1.0000 -0.013 grossular 0.2963E-01 0.2963E-01 1.0000 -1.528 Solid products produced: Mass = 0.000550 g Volume = 0.000211 cm3 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.0111900 moles log = -1.9512 Original solution: 1000.0103000 g Original solution / Rock added: 89366.43 (Water/Rock Ratio), log = 4.9512 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0206 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9997E+00 0.9859 0.1006E+01 0.1020E+01 CO2,gas 0.6060E-05 1.0071 0.6229E-05 0.6185E-05 CH4,gas 0.4505E-05 1.0125 0.4656E-05 0.4598E-05 H2,gas 0.2880E-03 1.0005 0.2941E-03 0.2940E-03 H2S,gas 0.1831E-05 0.9960 0.1861E-05 0.1868E-05 S2,gas 0.1472E-23 1.0000 0.1502E-23 0.1502E-23 CO,gas 0.4784E-12 1.0000 0.4883E-12 0.4883E-12 SO3,gas 0.6790E-40 1.0000 0.6930E-40 0.6930E-40 SO2,gas 0.7770E-21 1.0000 0.7931E-21 0.7931E-21 HF,gas 0.6342E-14 1.0000 0.6473E-14 0.6473E-14 HCl,gas 0.5440E-17 1.0000 0.5552E-17 0.5552E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 17 albite -0.38 -0.38 0.00 0.000 -0.13080E-10 23 andradite 39.01 39.01 0.00 0.000 -0.12132E-10 24 grossular 32.73 32.73 0.00 0.000 0.12132E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -13.56 -6.90 -2.302 0.11789E+05 -5.206 3 CH4,gas 4.54 -2.49 -7.03 -1.758 0.12005E+05 -5.332 4 H2,gas 8.00 2.77 -5.23 -2.989 0.89308E+04 -3.531 5 H2S,gas -6.23 -13.66 -7.43 -3.715 0.12685E+05 -5.730 6 S2,gas -7.34 -32.86 -25.52 -3.926 0.43578E+05 -23.823 7 CO,gas 3.21 -10.80 -14.01 -4.311 0.23922E+05 -12.311 8 SO3,gas 17.12 -24.74 -41.86 -10.465 0.71472E+05 -40.159 9 SO2,gas 0.83 -21.97 -22.80 -6.080 0.38930E+05 -21.101 10 HF,gas 0.47 -15.41 -15.89 -7.944 0.27128E+05 -14.189 11 HCl,gas 5.19 -13.77 -18.95 -9.477 0.32364E+05 -17.256 12 acmite 7.71 7.34 -0.37 -0.038 0.62458E+03 16 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 20 spessartine 24.46 19.61 -4.84 -0.242 0.82713E+04 21 analcite 3.32 2.69 -0.63 -0.070 0.10787E+04 27 annite 20.12 17.36 -2.76 -0.153 0.47134E+04 28 phlogopite 27.06 24.90 -2.17 -0.120 0.37021E+04 33 apatite-OH -18.15 -20.23 -2.08 -0.160 0.35466E+04 34 apatite-F -34.30 -35.65 -1.34 -0.112 0.22950E+04 38 aragonite 0.97 -0.98 -1.95 -0.650 0.33314E+04 39 brucite 12.57 9.13 -3.44 -0.688 0.58749E+04 40 calcite 0.81 -0.98 -1.80 -0.599 0.30671E+04 41 carnegieite-low 9.02 5.76 -3.26 -0.466 0.55650E+04 42 carnegieite-high 10.09 5.76 -4.33 -0.618 0.73920E+04 43 carpholite-Mg 8.58 4.14 -4.45 -0.296 0.75908E+04 45 celadonite 5.34 3.57 -1.77 -0.104 0.30307E+04 46 celadonite-Fe 3.88 1.06 -2.82 -0.166 0.48168E+04 47 chrysotile 23.89 21.24 -2.66 -0.221 0.45362E+04 49 clinochlore 39.07 37.57 -1.50 -0.047 0.25535E+04 50 daphnite 28.97 25.02 -3.95 -0.123 0.67394E+04 52 chlorite-Al-free 47.17 42.47 -4.70 -0.196 0.80276E+04 54 chloritoid-Fe 9.17 4.70 -4.47 -0.298 0.76398E+04 55 chloritoid-Mn 11.40 7.31 -4.09 -0.273 0.69876E+04 57 coesite -2.38 -3.07 -0.70 -0.233 0.11917E+04 64 cristobalite -2.56 -3.07 -0.51 -0.171 0.87704E+03 66 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71247E+04 68 diaspore 2.87 0.58 -2.30 -0.383 0.39194E+04 69 diamond -3.10 -8.03 -4.92 -1.407 0.84069E+04 70 diopside 16.18 15.56 -0.62 -0.062 0.10608E+04 71 hedenbergite 14.21 13.05 -1.16 -0.116 0.19796E+04 78 epidote 24.67 22.33 -2.34 -0.114 0.40006E+04 80 epidote-Fe 29.84 26.98 -2.86 -0.149 0.48835E+04 81 fayalite 14.05 10.16 -3.89 -0.555 0.66357E+04 82 ferrosilite 11.15 7.09 -4.06 -0.406 0.69391E+04 86 gibbsite 4.08 0.58 -3.50 -0.500 0.59779E+04 87 glaucophane 22.97 20.47 -2.51 -0.068 0.42804E+04 88 glaucophane-Fe 17.28 12.93 -4.34 -0.117 0.74127E+04 89 graphite -3.55 -8.03 -4.48 -1.280 0.76492E+04 90 greenalite 16.14 13.70 -2.44 -0.203 0.41616E+04 93 hematite 12.57 10.46 -2.10 -0.255 0.35892E+04 94 heulandite -5.83 -7.78 -1.95 -0.089 0.33364E+04 98 jadeite 4.22 2.69 -1.53 -0.153 0.26042E+04 99 julgoldite 70.43 66.04 -4.39 -0.114 0.74933E+04 100 kalsilite 7.58 3.66 -3.92 -0.560 0.66988E+04 101 kaolinite -1.33 -4.99 -3.66 -0.333 0.62471E+04 104 laumontite 2.88 1.44 -1.44 -0.096 0.24633E+04 105 lawsonite 9.62 7.59 -2.03 -0.135 0.34617E+04 106 leucite 4.12 0.59 -3.53 -0.353 0.60310E+04 108 lizardite 23.24 21.24 -2.01 -0.167 0.34288E+04 110 magnetite 20.09 17.08 -3.01 -0.245 0.51336E+04 111 minnesotaite 10.39 7.55 -2.83 -0.167 0.48387E+04 115 manganosite 14.06 9.23 -4.83 -1.208 0.82504E+04 119 microcline -2.49 -2.49 0.00 0.000 0.13169E+01 123 muscovite 2.58 -1.33 -3.91 -0.230 0.66816E+04 124 paragonite 4.24 0.77 -3.47 -0.204 0.59194E+04 125 nepheline 8.34 5.76 -2.58 -0.368 0.43973E+04 137 phlogopite-Na 29.65 27.00 -2.65 -0.147 0.45196E+04 139 prehnite 19.37 17.09 -2.28 -0.134 0.38879E+04 140 prehnite-Fe 22.50 21.75 -0.75 -0.045 0.12792E+04 141 pumpellyite-Fe 46.27 41.38 -4.88 -0.109 0.83405E+04 145 pyrite -21.25 -23.47 -2.22 -0.523 0.37985E+04 146 pyrrhotite -4.26 -7.04 -2.78 -0.927 0.47509E+04 147 pyrrhotiteFe0.875 -6.02 -8.21 -2.20 -0.808 0.37501E+04 148 pyroxmangite 7.40 6.15 -1.25 -0.249 0.21283E+04 149 pyrophyllite -6.18 -11.14 -4.96 -0.310 0.84753E+04 150 quartz -2.99 -3.07 -0.08 -0.028 0.14437E+03 154 rhodochrosite -0.98 -4.34 -3.36 -1.121 0.57408E+04 155 rhodonite 7.45 6.15 -1.29 -0.259 0.22086E+04 156 sanidine -1.28 -2.49 -1.21 -0.093 0.20691E+04 158 siderite -2.61 -6.95 -4.34 -1.447 0.74101E+04 166 stilbite -7.52 -7.78 -0.26 -0.012 0.44254E+03 167 stilpnomelane-Fe 13.02 12.73 -0.29 -0.009 0.49593E+03 168 stilpnomelane-Mg 27.44 25.28 -2.16 -0.064 0.36866E+04 174 talc 16.49 15.09 -1.40 -0.083 0.23962E+04 177 tephroite 18.09 15.38 -2.71 -0.387 0.46228E+04 181 tridymite -2.63 -3.07 -0.45 -0.149 0.76435E+03 182 tremolite 47.87 46.21 -1.66 -0.045 0.28368E+04 183 ferroactinolite 38.45 33.65 -4.80 -0.130 0.81963E+04 184 troilite-low -4.41 -7.04 -2.63 -0.877 0.44937E+04 190 wairakite 3.95 1.44 -2.51 -0.148 0.42853E+04 191 walstromite 11.51 9.51 -2.00 -0.401 0.34202E+04 192 wollastonite 10.46 9.51 -0.95 -0.191 0.16306E+04 193 pseudo-wollastonite 11.00 9.51 -1.49 -0.299 0.25504E+04 195 akaganeite 7.75 5.23 -2.52 -0.545 0.43071E+04 202 chalcedony -2.80 -3.07 -0.27 -0.091 0.46367E+03 204 montmorillonite-Ca -2.29 -6.24 -3.95 -0.244 0.67472E+04 205 montmorillonite-K -2.24 -6.29 -4.05 -0.248 0.69148E+04 206 montmorillonite-Mg -2.48 -6.81 -4.33 -0.268 0.73969E+04 207 montmorillonite-Na -2.04 -5.59 -3.55 -0.218 0.60692E+04 208 nontronite-Ca 3.21 1.45 -1.77 -0.115 0.30144E+04 209 nontronite-H 2.53 -0.63 -3.16 -0.212 0.53944E+04 210 nontronite-K 3.34 1.41 -1.94 -0.124 0.33051E+04 211 nontronite-Mg 3.07 0.88 -2.20 -0.142 0.37481E+04 212 nontronite-Na 3.52 2.10 -1.42 -0.091 0.24255E+04 228 tobermorite 9.82 7.41 -2.42 -0.660 0.41283E+04 234 alabandite -0.98 -4.43 -3.46 -1.152 0.59001E+04 237 boehmite 4.41 0.58 -3.83 -0.638 0.65363E+04 239 ferrous-oxide 9.81 6.62 -3.19 -0.799 0.54551E+04 245 silica-amorphous -2.09 -3.07 -0.98 -0.328 0.16778E+04 247 an20ab80 2.02 1.21 -0.81 -0.062 0.13782E+04 248 an25ab75 2.65 1.61 -1.04 -0.080 0.17697E+04 249 an30ab70 3.28 2.01 -1.27 -0.098 0.21708E+04 250 tr.625ac.25prg.125 45.16 43.95 -1.22 -0.033 0.20814E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 0.0004000 MOLES Current total amount of reactant added: 0.0111900 MOLES New total amount of reactant added: 0.0115900 MOLES Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.5508E-08 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 7 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 0.0115900 Water: Moles liquid = 0.4986E+02 kg liquid = 0.8983E+00 Moles total = 0.4986E+02 kg total = 0.8982E+00 Activity = 1.0000 Stoichiometric ionic strength = .1207242E-01 Osmotic coef. = 0.9455 True ionic strength = .2068148E-01 Chg. balance for total moles = -.5508E-08 Max. difference allowed = 0.2063E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.10959E-09 -9.9602 0.91895E-10 -10.0367 0.83856E+00 -0.0765 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.22858E-03 -3.6410 0.19050E-03 -3.7201 0.83339E+00 -0.0792 4 SO4-- 0.44929E-04 -4.3475 0.23134E-04 -4.6357 0.51490E+00 -0.2883 5 HCO3- 0.37233E-03 -3.4291 0.31076E-03 -3.5076 0.83464E+00 -0.0785 6 HS- 0.29688E-03 -3.5274 0.24745E-03 -3.6065 0.83352E+00 -0.0791 7 Al+++ 0.12791E-28 -28.8931 0.28978E-29 -29.5379 0.22656E+00 -0.6448 8 H4SiO4 0.84951E-03 -3.0708 0.84951E-03 -3.0708 0.10000E+01 0.0000 9 Ca++ 0.61131E-07 -7.2137 0.31239E-07 -7.5053 0.51102E+00 -0.2916 10 Mg++ 0.21970E-10 -10.6582 0.11174E-10 -10.9518 0.50863E+00 -0.2936 11 Fe++ 0.70617E-13 -13.1511 0.35958E-13 -13.4442 0.50920E+00 -0.2931 12 K+ 0.15656E-03 -3.8053 0.13071E-03 -3.8837 0.83485E+00 -0.0784 13 Na+ 0.19905E-01 -1.7010 0.16585E-01 -1.7803 0.83324E+00 -0.0792 14 Mn++ 0.27857E-10 -10.5551 0.14197E-10 -10.8478 0.50963E+00 -0.2927 15 F- 0.52555E-05 -5.2794 0.43706E-05 -5.3595 0.83163E+00 -0.0801 16 HPO4-- 0.45490E-07 -7.3421 0.23426E-07 -7.6303 0.51498E+00 -0.2882 18 HSiO3- 0.10357E-01 -1.9847 0.86318E-02 -2.0639 0.83339E+00 -0.0792 19 Ca(HSiO3)+ 0.73542E-08 -8.1335 0.61410E-08 -8.2118 0.83503E+00 -0.0783 20 Mg(HSiO3)+ 0.32739E-11 -11.4849 0.27338E-11 -11.5632 0.83503E+00 -0.0783 21 NaHSiO3,aq 0.23155E-02 -2.6354 0.23155E-02 -2.6354 0.10000E+01 0.0000 22 AlO+ 0.55906E-16 -16.2525 0.46683E-16 -16.3308 0.83503E+00 -0.0783 24 HAlO2,aq 0.10117E-09 -9.9950 0.10117E-09 -9.9950 0.10000E+01 0.0000 25 AlO2- 0.29295E-05 -5.5332 0.24369E-05 -5.6132 0.83185E+00 -0.0800 26 CH4,aq 0.32408E-08 -8.4893 0.32289E-08 -8.4909 0.99632E+00 -0.0016 31 CO,aq 0.34118E-15 -15.4670 0.34118E-15 -15.4670 0.10000E+01 0.0000 32 CO2,aq 0.61246E-07 -7.2129 0.61021E-07 -7.2145 0.99632E+00 -0.0016 33 CO3-2 0.57491E-03 -3.2404 0.29538E-03 -3.5296 0.51378E+00 -0.2892 34 CaCO3,aq 0.11570E-06 -6.9367 0.11570E-06 -6.9367 0.10000E+01 0.0000 35 Ca(HCO3)+ 0.29676E-09 -9.5276 0.24781E-09 -9.6059 0.83503E+00 -0.0783 36 CaCl+ 0.11533E-10 -10.9380 0.96306E-11 -11.0163 0.83503E+00 -0.0783 37 CaCl2,aq 0.43587E-15 -15.3606 0.43587E-15 -15.3606 0.10000E+01 0.0000 38 CaF+ 0.23872E-11 -11.6221 0.19934E-11 -11.7004 0.83503E+00 -0.0783 39 CaOH+ 0.29014E-07 -7.5374 0.24228E-07 -7.6157 0.83503E+00 -0.0783 40 CaSO4,aq 0.22949E-09 -9.6392 0.22949E-09 -9.6392 0.10000E+01 0.0000 41 HCl,aq 0.32079E-14 -14.4938 0.32079E-14 -14.4938 0.10000E+01 0.0000 45 HF,aq 0.27495E-11 -11.5607 0.27495E-11 -11.5607 0.10000E+01 0.0000 46 HF2- 0.48684E-17 -17.3126 0.40573E-17 -17.3918 0.83339E+00 -0.0792 48 FeCl+ 0.12984E-16 -16.8866 0.10842E-16 -16.9649 0.83503E+00 -0.0783 51 FeF+ 0.96177E-17 -17.0169 0.80310E-17 -17.0952 0.83503E+00 -0.0783 53 FeO,aq 0.16549E-09 -9.7812 0.16549E-09 -9.7812 0.10000E+01 0.0000 54 FeOH+ 0.15253E-10 -10.8166 0.12737E-10 -10.8949 0.83503E+00 -0.0783 55 HFeO2- 0.22609E-07 -7.6457 0.18842E-07 -7.7249 0.83339E+00 -0.0792 56 FeO+ 0.77118E-16 -16.1128 0.64395E-16 -16.1911 0.83503E+00 -0.0783 58 FeO2- 0.18723E-08 -8.7276 0.15603E-08 -8.8068 0.83339E+00 -0.0792 59 HFeO2,aq 0.18237E-10 -10.7391 0.18237E-10 -10.7391 0.10000E+01 0.0000 60 H2,aq 0.22339E-06 -6.6509 0.22257E-06 -6.6525 0.99632E+00 -0.0016 61 KCl,aq 0.45128E-09 -9.3456 0.45128E-09 -9.3456 0.10000E+01 0.0000 62 KHSO4,aq 0.78565E-18 -18.1048 0.78565E-18 -18.1048 0.10000E+01 0.0000 63 KOH,aq 0.60742E-06 -6.2165 0.60742E-06 -6.2165 0.10000E+01 0.0000 64 KSO4- 0.56302E-07 -7.2495 0.46922E-07 -7.3286 0.83339E+00 -0.0792 65 MgCO3,aq 0.10374E-10 -10.9841 0.10374E-10 -10.9841 0.10000E+01 0.0000 66 Mg(HCO3)+ 0.10847E-12 -12.9647 0.90576E-13 -13.0430 0.83503E+00 -0.0783 67 MgCl+ 0.37391E-14 -14.4272 0.31223E-14 -14.5055 0.83503E+00 -0.0783 68 MgF+ 0.31632E-14 -14.4999 0.26414E-14 -14.5782 0.83503E+00 -0.0783 69 MgOH+ 0.57429E-10 -10.2409 0.47955E-10 -10.3192 0.83503E+00 -0.0783 71 MnF+ 0.12516E-14 -14.9025 0.10451E-14 -14.9808 0.83503E+00 -0.0783 72 MnO,aq 0.17410E-08 -8.7592 0.17410E-08 -8.7592 0.10000E+01 0.0000 73 MnOH+ 0.55945E-09 -9.2522 0.46716E-09 -9.3305 0.83503E+00 -0.0783 74 MnO2-2 0.13317E-10 -10.8756 0.68420E-11 -11.1648 0.51378E+00 -0.2892 75 HMnO2- 0.16529E-09 -9.7818 0.13775E-09 -9.8609 0.83339E+00 -0.0792 78 MnCl+ 0.19944E-13 -13.7002 0.16654E-13 -13.7785 0.83503E+00 -0.0783 79 MnSO4,aq 0.94816E-13 -13.0231 0.94816E-13 -13.0231 0.10000E+01 0.0000 80 NaCl,aq 0.10471E-05 -5.9800 0.10471E-05 -5.9800 0.10000E+01 0.0000 81 NaF,aq 0.16971E-07 -7.7703 0.16971E-07 -7.7703 0.10000E+01 0.0000 82 NaOH,aq 0.77543E-04 -4.1105 0.77543E-04 -4.1105 0.10000E+01 0.0000 84 OH- 0.75582E-02 -2.1216 0.62873E-02 -2.2015 0.83185E+00 -0.0800 89 HPO3-2 0.31625E-16 -16.5000 0.16249E-16 -16.7892 0.51378E+00 -0.2892 92 H3PO4,aq 0.13836E-17 -17.8590 0.13836E-17 -17.8590 0.10000E+01 0.0000 93 H2PO4- 0.47605E-10 -10.3223 0.39713E-10 -10.4011 0.83420E+00 -0.0787 94 PO4-3 0.87297E-09 -9.0590 0.20799E-09 -9.6820 0.23826E+00 -0.6230 98 HP2O7-3 0.11848E-17 -17.9264 0.26870E-18 -18.5707 0.22679E+00 -0.6444 99 P2O7-4 0.93724E-17 -17.0281 0.69852E-18 -18.1558 0.74529E-01 -1.1277 100 H2S,aq 0.70539E-07 -7.1516 0.70280E-07 -7.1532 0.99632E+00 -0.0016 101 S2-2 0.11865E-10 -10.9257 0.60960E-11 -11.2150 0.51378E+00 -0.2892 102 S3-2 0.50475E-17 -17.2969 0.25933E-17 -17.5861 0.51378E+00 -0.2892 107 SO3-2 0.12833E-11 -11.8917 0.66911E-12 -12.1745 0.52140E+00 -0.2828 108 HSO3- 0.46196E-14 -14.3354 0.38499E-14 -14.4145 0.83339E+00 -0.0792 109 HSO4- 0.24511E-11 -11.6106 0.20488E-11 -11.6885 0.83586E+00 -0.0779 111 S2O3-2 0.37173E-13 -13.4298 0.19099E-13 -13.7190 0.51378E+00 -0.2892 Charge balance for all species = -.6131E-08 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.1095866E-09 -.2089608E-01 -.2102447E+02 0.0000 2 H2O 0.1000000E+01 0.5550322E+02 0.9981256E+06 0.0000 3 Cl- 0.2285819E-03 0.2296294E-03 0.8126547E+01 6.3166 4 SO4-- 0.4492942E-04 0.4492711E-04 0.4308080E+01 15.4377 5 HCO3- 0.3723319E-03 0.9474251E-03 0.5770623E+02 6.5291 6 HS- 0.2968757E-03 0.2970051E-03 0.9805052E+01 6.4302 7 Al+++ 0.1279055E-28 0.2929639E-05 0.7890522E-01 0.5722 8 H4SiO4 0.8495139E-03 0.1352245E-01 0.1297400E+04 -3.0708 9 Ca++ 0.6113077E-07 0.2137410E-06 0.8551047E-02 12.5681 10 Mg++ 0.2196986E-10 0.9316231E-10 0.2260927E-05 9.1216 11 Fe++ 0.7061671E-13 0.2468070E-07 0.1375887E-02 6.6292 12 K+ 0.1565627E-03 0.1572268E-03 0.6136930E+01 6.1530 13 Na+ 0.1990480E-01 0.2229886E-01 0.5117329E+03 8.2564 14 Mn++ 0.2785721E-10 0.2507022E-08 0.1374854E-03 9.2256 15 F- 0.5255484E-05 0.5272460E-05 0.9998772E-01 4.6772 16 HPO4-- 0.4548975E-07 0.4641032E-07 0.4446480E-02 12.4431 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.1877859E-01 -.1876996E-01 -.8626605E-05 0.0000000E+00 2 H2O 0.4985590E+02 0.4985591E+02 -.8579181E-05 0.0000000E+00 3 Cl- 0.2062652E-03 0.2062652E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.4035719E-04 0.4035589E-04 0.1302847E-08 0.0000000E+00 5 HCO3- 0.8510270E-03 0.8510270E-03 0.0000000E+00 0.0000000E+00 6 HS- 0.2667843E-03 0.2667856E-03 -.1302847E-08 0.0000000E+00 7 Al+++ 0.4775352E-05 0.2631556E-05 0.2143796E-05 0.0000000E+00 8 H4SiO4 0.1215302E-01 0.1214657E-01 0.6446567E-05 0.0000000E+00 9 Ca++ 0.2080835E-06 0.1919933E-06 0.1609015E-07 0.0000000E+00 10 Mg++ 0.8368328E-10 0.8368328E-10 0.0000000E+00 0.0000000E+00 11 Fe++ 0.3259227E-07 0.2216950E-07 0.1042277E-07 0.0000000E+00 12 K+ 0.1412294E-03 0.1412294E-03 0.0000000E+00 0.0000000E+00 13 Na+ 0.2003215E-01 0.2003001E-01 0.2143492E-05 0.0000000E+00 14 Mn++ 0.2251939E-08 0.2251939E-08 0.0000000E+00 0.0000000E+00 15 F- 0.4736000E-05 0.4736000E-05 0.0000000E+00 0.0000000E+00 16 HPO4-- 0.4168819E-07 0.4168819E-07 0.0000000E+00 0.0000000E+00 Chg. balance for solid moles: 0.0000E+00 Mass of aqueous solution: 0.899856E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 0.0115900 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 0.2143E-05 -5.669 0.5621E-03 -3.250 99.52 0.2158E-03 andradite 0.5211E-08 -8.283 0.2648E-05 -5.577 0.4689 0.6881E-06 grossular 0.1520E-09 -9.818 0.6847E-07 -7.165 0.1212E-01 0.1905E-07 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.9717E+00 0.9717E+00 1.0000 -0.012 grossular 0.2834E-01 0.2834E-01 1.0000 -1.548 Solid products produced: Mass = 0.000565 g Volume = 0.000216 cm3 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.0115900 moles log = -1.9359 Original solution: 1000.0103000 g Original solution / Rock added: 86282.17 (Water/Rock Ratio), log = 4.9359 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0206 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9997E+00 0.9859 0.1006E+01 0.1020E+01 CO2,gas 0.6352E-05 1.0071 0.6529E-05 0.6483E-05 CH4,gas 0.4599E-05 1.0125 0.4753E-05 0.4694E-05 H2,gas 0.2862E-03 1.0005 0.2922E-03 0.2921E-03 H2S,gas 0.1900E-05 0.9960 0.1932E-05 0.1940E-05 S2,gas 0.1608E-23 1.0000 0.1641E-23 0.1641E-23 CO,gas 0.4982E-12 1.0000 0.5084E-12 0.5084E-12 SO3,gas 0.7238E-40 1.0000 0.7387E-40 0.7387E-40 SO2,gas 0.8228E-21 1.0000 0.8398E-21 0.8398E-21 HF,gas 0.6615E-14 1.0000 0.6751E-14 0.6751E-14 HCl,gas 0.5546E-17 1.0000 0.5660E-17 0.5660E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 17 albite -0.38 -0.38 0.00 0.000 -0.94784E-12 23 andradite 39.01 39.01 0.00 0.000 0.36397E-10 24 grossular 32.73 32.73 0.00 0.000 0.00000E+00 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -13.54 -6.88 -2.295 0.11754E+05 -5.185 3 CH4,gas 4.54 -2.48 -7.02 -1.756 0.11990E+05 -5.323 4 H2,gas 8.00 2.77 -5.23 -2.990 0.89357E+04 -3.534 5 H2S,gas -6.23 -13.64 -7.41 -3.706 0.12657E+05 -5.714 6 S2,gas -7.34 -32.82 -25.48 -3.921 0.43513E+05 -23.785 7 CO,gas 3.21 -10.78 -13.99 -4.305 0.23892E+05 -12.294 8 SO3,gas 17.12 -24.71 -41.83 -10.458 0.71424E+05 -40.132 9 SO2,gas 0.83 -21.94 -22.77 -6.073 0.38887E+05 -21.076 10 HF,gas 0.47 -15.40 -15.87 -7.935 0.27097E+05 -14.171 11 HCl,gas 5.19 -13.76 -18.95 -9.473 0.32350E+05 -17.247 12 acmite 7.71 7.36 -0.35 -0.036 0.59587E+03 16 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 20 spessartine 24.46 19.61 -4.85 -0.242 0.82789E+04 21 analcite 3.32 2.69 -0.63 -0.071 0.10841E+04 27 annite 20.12 17.40 -2.72 -0.151 0.46496E+04 28 phlogopite 27.06 24.88 -2.19 -0.121 0.37342E+04 33 apatite-OH -18.15 -20.27 -2.12 -0.163 0.36149E+04 34 apatite-F -34.30 -35.67 -1.37 -0.114 0.23320E+04 38 aragonite 0.97 -0.98 -1.94 -0.648 0.33171E+04 39 brucite 12.57 9.12 -3.45 -0.689 0.58855E+04 40 calcite 0.81 -0.98 -1.79 -0.596 0.30529E+04 41 carnegieite-low 9.02 5.76 -3.27 -0.467 0.55758E+04 42 carnegieite-high 10.09 5.76 -4.34 -0.619 0.74028E+04 43 carpholite-Mg 8.58 4.12 -4.46 -0.297 0.76115E+04 45 celadonite 5.34 3.56 -1.78 -0.105 0.30360E+04 46 celadonite-Fe 3.88 1.07 -2.81 -0.165 0.47902E+04 47 chrysotile 23.89 21.22 -2.67 -0.222 0.45575E+04 49 clinochlore 39.07 37.54 -1.53 -0.048 0.26115E+04 50 daphnite 28.97 25.08 -3.89 -0.121 0.66375E+04 52 chlorite-Al-free 47.17 42.45 -4.73 -0.197 0.80701E+04 54 chloritoid-Fe 9.17 4.70 -4.47 -0.298 0.76339E+04 55 chloritoid-Mn 11.40 7.30 -4.10 -0.273 0.70039E+04 57 coesite -2.38 -3.07 -0.69 -0.232 0.11863E+04 64 cristobalite -2.56 -3.07 -0.51 -0.170 0.87165E+03 66 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71248E+04 68 diaspore 2.87 0.57 -2.30 -0.384 0.39298E+04 69 diamond -3.10 -8.01 -4.91 -1.403 0.83818E+04 70 diopside 16.18 15.55 -0.63 -0.063 0.10813E+04 71 hedenbergite 14.21 13.06 -1.15 -0.115 0.19681E+04 78 epidote 24.67 22.31 -2.36 -0.114 0.40225E+04 80 epidote-Fe 29.84 26.99 -2.85 -0.148 0.48713E+04 81 fayalite 14.05 10.19 -3.86 -0.551 0.65877E+04 82 ferrosilite 11.15 7.12 -4.03 -0.403 0.68857E+04 86 gibbsite 4.08 0.57 -3.51 -0.501 0.59883E+04 87 glaucophane 22.97 20.46 -2.52 -0.068 0.43016E+04 88 glaucophane-Fe 17.28 12.98 -4.30 -0.116 0.73380E+04 89 graphite -3.55 -8.01 -4.47 -1.276 0.76241E+04 90 greenalite 16.14 13.75 -2.39 -0.199 0.40869E+04 93 hematite 12.57 10.49 -2.07 -0.251 0.35417E+04 94 heulandite -5.83 -7.78 -1.96 -0.089 0.33399E+04 98 jadeite 4.22 2.69 -1.53 -0.153 0.26096E+04 99 julgoldite 70.43 66.09 -4.34 -0.113 0.74056E+04 100 kalsilite 7.58 3.65 -3.93 -0.561 0.67096E+04 101 kaolinite -1.33 -5.00 -3.66 -0.333 0.62571E+04 104 laumontite 2.88 1.43 -1.45 -0.097 0.24831E+04 105 lawsonite 9.62 7.57 -2.05 -0.136 0.34922E+04 106 leucite 4.12 0.58 -3.54 -0.354 0.60365E+04 108 lizardite 23.24 21.22 -2.02 -0.168 0.34501E+04 110 magnetite 20.09 17.12 -2.97 -0.242 0.50648E+04 111 minnesotaite 10.39 7.60 -2.78 -0.164 0.47533E+04 115 manganosite 14.06 9.23 -4.83 -1.208 0.82514E+04 119 microcline -2.49 -2.49 0.00 0.000 0.13725E+01 123 muscovite 2.58 -1.34 -3.93 -0.231 0.67024E+04 124 paragonite 4.24 0.76 -3.48 -0.205 0.59402E+04 125 nepheline 8.34 5.76 -2.58 -0.369 0.44081E+04 131 periclase-Fe 11.63 6.63 -5.00 -1.249 0.85329E+04 137 phlogopite-Na 29.65 26.98 -2.67 -0.148 0.45516E+04 139 prehnite 19.37 17.07 -2.30 -0.136 0.39336E+04 140 prehnite-Fe 22.50 21.74 -0.76 -0.045 0.12908E+04 141 pumpellyite-Fe 46.27 41.34 -4.93 -0.110 0.84209E+04 145 pyrite -21.25 -23.42 -2.18 -0.512 0.37168E+04 146 pyrrhotite -4.26 -7.01 -2.75 -0.918 0.47019E+04 147 pyrrhotiteFe0.875 -6.02 -8.19 -2.17 -0.798 0.37031E+04 148 pyroxmangite 7.40 6.15 -1.24 -0.249 0.21239E+04 149 pyrophyllite -6.18 -11.14 -4.96 -0.310 0.84744E+04 150 quartz -2.99 -3.07 -0.08 -0.027 0.13898E+03 154 rhodochrosite -0.98 -4.32 -3.34 -1.114 0.57070E+04 155 rhodonite 7.45 6.15 -1.29 -0.258 0.22042E+04 156 sanidine -1.28 -2.49 -1.21 -0.093 0.20691E+04 158 siderite -2.61 -6.92 -4.31 -1.436 0.73540E+04 166 stilbite -7.52 -7.78 -0.26 -0.012 0.44610E+03 167 stilpnomelane-Fe 13.02 12.80 -0.22 -0.006 0.37000E+03 168 stilpnomelane-Mg 27.44 25.26 -2.18 -0.065 0.37205E+04 174 talc 16.49 15.08 -1.41 -0.083 0.24066E+04 177 tephroite 18.09 15.38 -2.71 -0.386 0.46194E+04 181 tridymite -2.63 -3.07 -0.44 -0.148 0.75896E+03 182 tremolite 47.87 46.18 -1.69 -0.046 0.28881E+04 183 ferroactinolite 38.45 33.72 -4.74 -0.128 0.80879E+04 184 troilite-low -4.41 -7.01 -2.60 -0.868 0.44447E+04 190 wairakite 3.95 1.43 -2.52 -0.148 0.43050E+04 191 walstromite 11.51 9.50 -2.01 -0.402 0.34353E+04 192 wollastonite 10.46 9.50 -0.96 -0.193 0.16458E+04 193 pseudo-wollastonite 11.00 9.50 -1.50 -0.301 0.25656E+04 195 akaganeite 7.75 5.25 -2.51 -0.542 0.42834E+04 202 chalcedony -2.80 -3.07 -0.27 -0.089 0.45828E+03 204 montmorillonite-Ca -2.29 -6.24 -3.95 -0.245 0.67499E+04 205 montmorillonite-K -2.24 -6.29 -4.05 -0.248 0.69160E+04 206 montmorillonite-Mg -2.48 -6.81 -4.33 -0.268 0.73979E+04 207 montmorillonite-Na -2.04 -5.59 -3.56 -0.218 0.60704E+04 208 nontronite-Ca 3.21 1.48 -1.73 -0.112 0.29539E+04 209 nontronite-H 2.53 -0.59 -3.12 -0.209 0.53305E+04 210 nontronite-K 3.34 1.44 -1.90 -0.122 0.32432E+04 211 nontronite-Mg 3.07 0.92 -2.16 -0.140 0.36860E+04 212 nontronite-Na 3.52 2.14 -1.38 -0.089 0.23636E+04 228 tobermorite 9.82 7.40 -2.42 -0.662 0.41400E+04 234 alabandite -0.98 -4.42 -3.44 -1.147 0.58733E+04 237 boehmite 4.41 0.57 -3.83 -0.639 0.65467E+04 239 ferrous-oxide 9.81 6.63 -3.18 -0.796 0.54338E+04 245 silica-amorphous -2.09 -3.07 -0.98 -0.326 0.16725E+04 247 an20ab80 2.02 1.21 -0.81 -0.062 0.13843E+04 248 an25ab75 2.65 1.60 -1.04 -0.080 0.17773E+04 249 an30ab70 3.28 2.00 -1.28 -0.098 0.21799E+04 250 tr.625ac.25prg.125 45.16 43.94 -1.23 -0.033 0.20974E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 0.0004000 MOLES Current total amount of reactant added: 0.0115900 MOLES New total amount of reactant added: 0.0119900 MOLES Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.5508E-08 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 7 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 0.0119900 Water: Moles liquid = 0.4986E+02 kg liquid = 0.8983E+00 Moles total = 0.4986E+02 kg total = 0.8982E+00 Activity = 1.0000 Stoichiometric ionic strength = .1209813E-01 Osmotic coef. = 0.9451 True ionic strength = .2070300E-01 Chg. balance for total moles = -.5508E-08 Max. difference allowed = 0.2086E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.11046E-09 -9.9568 0.92621E-10 -10.0333 0.83851E+00 -0.0765 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.23120E-03 -3.6360 0.19266E-03 -3.7152 0.83333E+00 -0.0792 4 SO4-- 0.47053E-04 -4.3274 0.24221E-04 -4.6158 0.51476E+00 -0.2884 5 HCO3- 0.38677E-03 -3.4125 0.32280E-03 -3.4911 0.83459E+00 -0.0785 6 HS- 0.30557E-03 -3.5149 0.25468E-03 -3.5940 0.83346E+00 -0.0791 7 Al+++ 0.12922E-28 -28.8887 0.29257E-29 -29.5338 0.22642E+00 -0.6451 8 H4SiO4 0.85574E-03 -3.0677 0.85574E-03 -3.0677 0.10000E+01 0.0000 9 Ca++ 0.60437E-07 -7.2187 0.30876E-07 -7.5104 0.51088E+00 -0.2917 10 Mg++ 0.22004E-10 -10.6575 0.11189E-10 -10.9512 0.50848E+00 -0.2937 11 Fe++ 0.73821E-13 -13.1318 0.37579E-13 -13.4251 0.50905E+00 -0.2932 12 K+ 0.15656E-03 -3.8053 0.13070E-03 -3.8837 0.83479E+00 -0.0784 13 Na+ 0.19906E-01 -1.7010 0.16586E-01 -1.7803 0.83318E+00 -0.0793 14 Mn++ 0.28268E-10 -10.5487 0.14402E-10 -10.8416 0.50949E+00 -0.2929 15 F- 0.54330E-05 -5.2650 0.45179E-05 -5.3451 0.83157E+00 -0.0801 16 HPO4-- 0.45495E-07 -7.3420 0.23423E-07 -7.6304 0.51484E+00 -0.2883 18 HSiO3- 0.10352E-01 -1.9850 0.86269E-02 -2.0641 0.83333E+00 -0.0792 19 Ca(HSiO3)+ 0.72650E-08 -8.1388 0.60661E-08 -8.2171 0.83497E+00 -0.0783 20 Mg(HSiO3)+ 0.32764E-11 -11.4846 0.27357E-11 -11.5629 0.83497E+00 -0.0783 21 NaHSiO3,aq 0.23142E-02 -2.6356 0.23142E-02 -2.6356 0.10000E+01 0.0000 22 AlO+ 0.55566E-16 -16.2552 0.46396E-16 -16.3335 0.83497E+00 -0.0783 24 HAlO2,aq 0.99758E-10 -10.0011 0.99758E-10 -10.0011 0.10000E+01 0.0000 25 AlO2- 0.28663E-05 -5.5427 0.23841E-05 -5.6227 0.83179E+00 -0.0800 26 CH4,aq 0.33092E-08 -8.4803 0.32970E-08 -8.4819 0.99631E+00 -0.0016 31 CO,aq 0.35496E-15 -15.4498 0.35496E-15 -15.4498 0.10000E+01 0.0000 32 CO2,aq 0.64121E-07 -7.1930 0.63885E-07 -7.1946 0.99631E+00 -0.0016 33 CO3-2 0.59265E-03 -3.2272 0.30441E-03 -3.5165 0.51364E+00 -0.2893 34 CaCO3,aq 0.11785E-06 -6.9287 0.11785E-06 -6.9287 0.10000E+01 0.0000 35 Ca(HCO3)+ 0.30469E-09 -9.5161 0.25441E-09 -9.5945 0.83497E+00 -0.0783 36 CaCl+ 0.11529E-10 -10.9382 0.96268E-11 -11.0165 0.83497E+00 -0.0783 37 CaCl2,aq 0.44064E-15 -15.3559 0.44064E-15 -15.3559 0.10000E+01 0.0000 38 CaF+ 0.24392E-11 -11.6128 0.20366E-11 -11.6911 0.83497E+00 -0.0783 39 CaOH+ 0.28454E-07 -7.5459 0.23758E-07 -7.6242 0.83497E+00 -0.0783 40 CaSO4,aq 0.23747E-09 -9.6244 0.23747E-09 -9.6244 0.10000E+01 0.0000 41 HCl,aq 0.32700E-14 -14.4855 0.32700E-14 -14.4855 0.10000E+01 0.0000 45 HF,aq 0.28646E-11 -11.5429 0.28646E-11 -11.5429 0.10000E+01 0.0000 46 HF2- 0.52435E-17 -17.2804 0.43696E-17 -17.3596 0.83333E+00 -0.0792 48 FeCl+ 0.13725E-16 -16.8625 0.11460E-16 -16.9408 0.83497E+00 -0.0783 51 FeF+ 0.10391E-16 -16.9834 0.86759E-17 -17.0617 0.83497E+00 -0.0783 53 FeO,aq 0.17025E-09 -9.7689 0.17025E-09 -9.7689 0.10000E+01 0.0000 54 FeOH+ 0.15817E-10 -10.8009 0.13207E-10 -10.8792 0.83497E+00 -0.0783 55 HFeO2- 0.23079E-07 -7.6368 0.19232E-07 -7.7160 0.83333E+00 -0.0792 56 FeO+ 0.80218E-16 -16.0957 0.66980E-16 -16.1741 0.83497E+00 -0.0783 58 FeO2- 0.19171E-08 -8.7174 0.15976E-08 -8.7965 0.83333E+00 -0.0792 59 HFeO2,aq 0.18820E-10 -10.7254 0.18820E-10 -10.7254 0.10000E+01 0.0000 60 H2,aq 0.22200E-06 -6.6536 0.22118E-06 -6.6552 0.99631E+00 -0.0016 61 KCl,aq 0.45638E-09 -9.3407 0.45638E-09 -9.3407 0.10000E+01 0.0000 62 KHSO4,aq 0.82900E-18 -18.0814 0.82900E-18 -18.0814 0.10000E+01 0.0000 63 KOH,aq 0.60262E-06 -6.2200 0.60262E-06 -6.2200 0.10000E+01 0.0000 64 KSO4- 0.58947E-07 -7.2295 0.49123E-07 -7.3087 0.83333E+00 -0.0792 65 MgCO3,aq 0.10705E-10 -10.9704 0.10705E-10 -10.9704 0.10000E+01 0.0000 66 Mg(HCO3)+ 0.11282E-12 -12.9476 0.94203E-13 -13.0259 0.83497E+00 -0.0783 67 MgCl+ 0.37867E-14 -14.4217 0.31618E-14 -14.5001 0.83497E+00 -0.0783 68 MgF+ 0.32743E-14 -14.4849 0.27339E-14 -14.5632 0.83497E+00 -0.0783 69 MgOH+ 0.57056E-10 -10.2437 0.47640E-10 -10.3220 0.83497E+00 -0.0783 71 MnF+ 0.13126E-14 -14.8819 0.10960E-14 -14.9602 0.83497E+00 -0.0783 72 MnO,aq 0.17386E-08 -8.7598 0.17386E-08 -8.7598 0.10000E+01 0.0000 73 MnOH+ 0.56314E-09 -9.2494 0.47020E-09 -9.3277 0.83497E+00 -0.0783 74 MnO2-2 0.13095E-10 -10.8829 0.67259E-11 -11.1723 0.51364E+00 -0.2893 75 HMnO2- 0.16378E-09 -9.7857 0.13648E-09 -9.8649 0.83333E+00 -0.0792 78 MnCl+ 0.20464E-13 -13.6890 0.17087E-13 -13.7673 0.83497E+00 -0.0783 79 MnSO4,aq 0.10071E-12 -12.9969 0.10071E-12 -12.9969 0.10000E+01 0.0000 80 NaCl,aq 0.10590E-05 -5.9751 0.10590E-05 -5.9751 0.10000E+01 0.0000 81 NaF,aq 0.17543E-07 -7.7559 0.17543E-07 -7.7559 0.10000E+01 0.0000 82 NaOH,aq 0.76937E-04 -4.1139 0.76937E-04 -4.1139 0.10000E+01 0.0000 84 OH- 0.74995E-02 -2.1250 0.62380E-02 -2.2050 0.83179E+00 -0.0800 89 HPO3-2 0.31432E-16 -16.5026 0.16145E-16 -16.7920 0.51364E+00 -0.2893 92 H3PO4,aq 0.14053E-17 -17.8522 0.14053E-17 -17.8522 0.10000E+01 0.0000 93 H2PO4- 0.47978E-10 -10.3190 0.40020E-10 -10.3977 0.83414E+00 -0.0788 94 PO4-3 0.86650E-09 -9.0622 0.20633E-09 -9.6854 0.23812E+00 -0.6232 98 HP2O7-3 0.11945E-17 -17.9228 0.27074E-18 -18.5674 0.22665E+00 -0.6446 99 P2O7-4 0.93799E-17 -17.0278 0.69831E-18 -18.1560 0.74448E-01 -1.1281 100 H2S,aq 0.73173E-07 -7.1357 0.72903E-07 -7.1373 0.99631E+00 -0.0016 101 S2-2 0.12650E-10 -10.8979 0.64976E-11 -11.1872 0.51364E+00 -0.2893 102 S3-2 0.56174E-17 -17.2505 0.28853E-17 -17.5398 0.51364E+00 -0.2893 107 SO3-2 0.13355E-11 -11.8743 0.69618E-12 -12.1573 0.52127E+00 -0.2829 108 HSO3- 0.48448E-14 -14.3147 0.40373E-14 -14.3939 0.83333E+00 -0.0792 109 HSO4- 0.25867E-11 -11.5873 0.21620E-11 -11.6651 0.83581E+00 -0.0779 111 S2O3-2 0.40383E-13 -13.3938 0.20742E-13 -13.6831 0.51364E+00 -0.2893 Charge balance for all species = -.6131E-08 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.1104596E-09 -.2084773E-01 -.2097579E+02 0.0000 2 H2O 0.1000000E+01 0.5550317E+02 0.9981231E+06 0.0000 3 Cl- 0.2311956E-03 0.2322550E-03 0.8219452E+01 6.3181 4 SO4-- 0.4705255E-04 0.4705317E-04 0.4511942E+01 15.4508 5 HCO3- 0.3867742E-03 0.9796136E-03 0.5966669E+02 6.5422 6 HS- 0.3055656E-03 0.3056974E-03 0.1009200E+02 6.4393 7 Al+++ 0.1292173E-28 0.2866371E-05 0.7720106E-01 0.5661 8 H4SiO4 0.8557352E-03 0.1352216E-01 0.1297370E+04 -3.0677 9 Ca++ 0.6043672E-07 0.2145642E-06 0.8583970E-02 12.5562 10 Mg++ 0.2200432E-10 0.9316161E-10 0.2260906E-05 9.1154 11 Fe++ 0.7382073E-13 0.2520088E-07 0.1404884E-02 6.6415 12 K+ 0.1565636E-03 0.1572257E-03 0.6136874E+01 6.1496 13 Na+ 0.1990646E-01 0.2229863E-01 0.5117268E+03 8.2530 14 Mn++ 0.2826829E-10 0.2507003E-08 0.1374841E-03 9.2250 15 F- 0.5432994E-05 0.5450542E-05 0.1033647E+00 4.6882 16 HPO4-- 0.4549549E-07 0.4640998E-07 0.4446439E-02 12.4362 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.1873552E-01 -.1872667E-01 -.8851519E-05 0.0000000E+00 2 H2O 0.4985622E+02 0.4985623E+02 -.8806300E-05 0.0000000E+00 3 Cl- 0.2086252E-03 0.2086252E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.4226719E-04 0.4226595E-04 0.1244418E-08 0.0000000E+00 5 HCO3- 0.8799470E-03 0.8799470E-03 0.0000000E+00 0.0000000E+00 6 HS- 0.2745943E-03 0.2745955E-03 -.1244418E-08 0.0000000E+00 7 Al+++ 0.4775352E-05 0.2574744E-05 0.2200608E-05 0.0000000E+00 8 H4SiO4 0.1215302E-01 0.1214640E-01 0.6616341E-05 0.0000000E+00 9 Ca++ 0.2080835E-06 0.1927343E-06 0.1534919E-07 0.0000000E+00 10 Mg++ 0.8368328E-10 0.8368328E-10 0.0000000E+00 0.0000000E+00 11 Fe++ 0.3259227E-07 0.2263692E-07 0.9955348E-08 0.0000000E+00 12 K+ 0.1412294E-03 0.1412294E-03 0.0000000E+00 0.0000000E+00 13 Na+ 0.2003215E-01 0.2002995E-01 0.2200331E-05 0.0000000E+00 14 Mn++ 0.2251939E-08 0.2251939E-08 0.0000000E+00 0.0000000E+00 15 F- 0.4896000E-05 0.4896000E-05 0.0000000E+00 0.0000000E+00 16 HPO4-- 0.4168819E-07 0.4168819E-07 0.0000000E+00 0.0000000E+00 Chg. balance for solid moles: -.1271E-20 Mass of aqueous solution: 0.899864E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 0.0119900 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 0.2200E-05 -5.658 0.5770E-03 -3.239 99.55 0.2215E-03 andradite 0.4978E-08 -8.303 0.2530E-05 -5.597 0.4365 0.6572E-06 grossular 0.1387E-09 -9.858 0.6249E-07 -7.204 0.1078E-01 0.1739E-07 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.9729E+00 0.9729E+00 1.0000 -0.012 grossular 0.2711E-01 0.2711E-01 1.0000 -1.567 Solid products produced: Mass = 0.000580 g Volume = 0.000222 cm3 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.0119900 moles log = -1.9212 Original solution: 1000.0103000 g Original solution / Rock added: 83403.69 (Water/Rock Ratio), log = 4.9212 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0206 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9997E+00 0.9859 0.1006E+01 0.1020E+01 CO2,gas 0.6650E-05 1.0071 0.6835E-05 0.6787E-05 CH4,gas 0.4696E-05 1.0125 0.4853E-05 0.4793E-05 H2,gas 0.2844E-03 1.0005 0.2904E-03 0.2902E-03 H2S,gas 0.1971E-05 0.9960 0.2004E-05 0.2012E-05 S2,gas 0.1752E-23 1.0000 0.1788E-23 0.1788E-23 CO,gas 0.5183E-12 1.0000 0.5290E-12 0.5290E-12 SO3,gas 0.7698E-40 1.0000 0.7856E-40 0.7856E-40 SO2,gas 0.8697E-21 1.0000 0.8876E-21 0.8876E-21 HF,gas 0.6892E-14 1.0000 0.7034E-14 0.7034E-14 HCl,gas 0.5653E-17 1.0000 0.5770E-17 0.5770E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 17 albite -0.38 -0.38 0.00 0.000 -0.94784E-12 23 andradite 39.01 39.01 0.00 0.000 0.00000E+00 24 grossular 32.73 32.73 0.00 0.000 0.12132E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -13.52 -6.86 -2.288 0.11720E+05 -5.165 3 CH4,gas 4.54 -2.47 -7.01 -1.753 0.11974E+05 -5.314 4 H2,gas 8.00 2.76 -5.24 -2.992 0.89403E+04 -3.537 5 H2S,gas -6.23 -13.63 -7.40 -3.699 0.12630E+05 -5.698 6 S2,gas -7.34 -32.78 -25.45 -3.915 0.43449E+05 -23.748 7 CO,gas 3.21 -10.76 -13.98 -4.300 0.23863E+05 -12.277 8 SO3,gas 17.12 -24.68 -41.80 -10.451 0.71379E+05 -40.105 9 SO2,gas 0.83 -21.92 -22.75 -6.067 0.38846E+05 -21.052 10 HF,gas 0.47 -15.38 -15.85 -7.926 0.27066E+05 -14.153 11 HCl,gas 5.19 -13.75 -18.94 -9.469 0.32336E+05 -17.239 12 acmite 7.71 7.38 -0.33 -0.035 0.56753E+03 16 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 20 spessartine 24.46 19.60 -4.85 -0.243 0.82865E+04 21 analcite 3.32 2.68 -0.64 -0.071 0.10895E+04 27 annite 20.12 17.44 -2.69 -0.149 0.45866E+04 28 phlogopite 27.06 24.86 -2.21 -0.123 0.37664E+04 33 apatite-OH -18.15 -20.31 -2.16 -0.166 0.36819E+04 34 apatite-F -34.30 -35.69 -1.39 -0.116 0.23686E+04 38 aragonite 0.97 -0.97 -1.93 -0.645 0.33034E+04 39 brucite 12.57 9.12 -3.45 -0.691 0.58963E+04 40 calcite 0.81 -0.97 -1.78 -0.593 0.30392E+04 41 carnegieite-low 9.02 5.75 -3.27 -0.467 0.55866E+04 42 carnegieite-high 10.09 5.75 -4.34 -0.620 0.74136E+04 43 carpholite-Mg 8.58 4.11 -4.47 -0.298 0.76322E+04 45 celadonite 5.34 3.56 -1.78 -0.105 0.30414E+04 46 celadonite-Fe 3.88 1.09 -2.79 -0.164 0.47638E+04 47 chrysotile 23.89 21.21 -2.68 -0.223 0.45788E+04 49 clinochlore 39.07 37.51 -1.56 -0.049 0.26697E+04 50 daphnite 28.97 25.14 -3.83 -0.120 0.65370E+04 52 chlorite-Al-free 47.17 42.42 -4.75 -0.198 0.81128E+04 54 chloritoid-Fe 9.17 4.71 -4.47 -0.298 0.76283E+04 55 chloritoid-Mn 11.40 7.29 -4.11 -0.274 0.70203E+04 57 coesite -2.38 -3.07 -0.69 -0.231 0.11809E+04 64 cristobalite -2.56 -3.07 -0.51 -0.169 0.86624E+03 66 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71248E+04 68 diaspore 2.87 0.57 -2.31 -0.385 0.39402E+04 69 diamond -3.10 -8.00 -4.89 -1.398 0.83571E+04 70 diopside 16.18 15.54 -0.65 -0.065 0.11015E+04 71 hedenbergite 14.21 13.06 -1.15 -0.115 0.19566E+04 78 epidote 24.67 22.30 -2.37 -0.115 0.40445E+04 80 epidote-Fe 29.84 26.99 -2.85 -0.148 0.48595E+04 81 fayalite 14.05 10.22 -3.83 -0.547 0.65402E+04 82 ferrosilite 11.15 7.15 -4.00 -0.400 0.68329E+04 86 gibbsite 4.08 0.57 -3.51 -0.502 0.59987E+04 87 glaucophane 22.97 20.44 -2.53 -0.068 0.43229E+04 88 glaucophane-Fe 17.28 13.02 -4.25 -0.115 0.72641E+04 89 graphite -3.55 -8.00 -4.45 -1.272 0.75993E+04 90 greenalite 16.14 13.79 -2.35 -0.196 0.40130E+04 93 hematite 12.57 10.52 -2.05 -0.248 0.34951E+04 94 heulandite -5.83 -7.79 -1.96 -0.089 0.33432E+04 98 jadeite 4.22 2.68 -1.53 -0.153 0.26150E+04 99 julgoldite 70.43 66.14 -4.29 -0.111 0.73191E+04 100 kalsilite 7.58 3.65 -3.94 -0.562 0.67205E+04 101 kaolinite -1.33 -5.00 -3.67 -0.334 0.62670E+04 104 laumontite 2.88 1.42 -1.47 -0.098 0.25026E+04 105 lawsonite 9.62 7.55 -2.06 -0.138 0.35225E+04 106 leucite 4.12 0.58 -3.54 -0.354 0.60419E+04 108 lizardite 23.24 21.21 -2.03 -0.169 0.34714E+04 110 magnetite 20.09 17.16 -2.93 -0.239 0.49971E+04 111 minnesotaite 10.39 7.65 -2.73 -0.161 0.46686E+04 115 manganosite 14.06 9.23 -4.83 -1.208 0.82524E+04 119 microcline -2.49 -2.49 0.00 0.000 0.14286E+01 123 muscovite 2.58 -1.36 -3.94 -0.232 0.67233E+04 124 paragonite 4.24 0.75 -3.49 -0.205 0.59610E+04 125 nepheline 8.34 5.75 -2.59 -0.370 0.44189E+04 131 periclase-Fe 11.63 6.64 -4.99 -1.246 0.85119E+04 137 phlogopite-Na 29.65 26.96 -2.68 -0.149 0.45838E+04 139 prehnite 19.37 17.04 -2.33 -0.137 0.39789E+04 140 prehnite-Fe 22.50 21.74 -0.76 -0.046 0.13023E+04 141 pumpellyite-Fe 46.27 41.29 -4.98 -0.111 0.85008E+04 145 pyrite -21.25 -23.38 -2.13 -0.501 0.36368E+04 146 pyrrhotite -4.26 -6.99 -2.73 -0.908 0.46536E+04 147 pyrrhotiteFe0.875 -6.02 -8.16 -2.14 -0.788 0.36569E+04 148 pyroxmangite 7.40 6.16 -1.24 -0.248 0.21195E+04 149 pyrophyllite -6.18 -11.14 -4.96 -0.310 0.84736E+04 150 quartz -2.99 -3.07 -0.08 -0.026 0.13357E+03 154 rhodochrosite -0.98 -4.30 -3.32 -1.108 0.56740E+04 155 rhodonite 7.45 6.16 -1.29 -0.258 0.21998E+04 156 sanidine -1.28 -2.49 -1.21 -0.093 0.20692E+04 158 siderite -2.61 -6.88 -4.27 -1.425 0.72989E+04 166 stilbite -7.52 -7.79 -0.26 -0.013 0.44938E+03 167 stilpnomelane-Fe 13.02 12.87 -0.14 -0.004 0.24536E+03 168 stilpnomelane-Mg 27.44 25.24 -2.20 -0.066 0.37546E+04 174 talc 16.49 15.08 -1.42 -0.083 0.24172E+04 177 tephroite 18.09 15.38 -2.70 -0.386 0.46160E+04 181 tridymite -2.63 -3.07 -0.44 -0.147 0.75355E+03 182 tremolite 47.87 46.15 -1.72 -0.047 0.29392E+04 183 ferroactinolite 38.45 33.78 -4.67 -0.126 0.79802E+04 184 troilite-low -4.41 -6.99 -2.57 -0.858 0.43965E+04 190 wairakite 3.95 1.42 -2.53 -0.149 0.43245E+04 191 walstromite 11.51 9.49 -2.02 -0.404 0.34503E+04 192 wollastonite 10.46 9.49 -0.97 -0.195 0.16607E+04 193 pseudo-wollastonite 11.00 9.49 -1.51 -0.302 0.25805E+04 195 akaganeite 7.75 5.26 -2.49 -0.539 0.42601E+04 202 chalcedony -2.80 -3.07 -0.27 -0.088 0.45287E+03 204 montmorillonite-Ca -2.29 -6.25 -3.95 -0.245 0.67525E+04 205 montmorillonite-K -2.24 -6.29 -4.05 -0.248 0.69172E+04 206 montmorillonite-Mg -2.48 -6.81 -4.33 -0.268 0.73990E+04 207 montmorillonite-Na -2.04 -5.59 -3.56 -0.218 0.60716E+04 208 nontronite-Ca 3.21 1.52 -1.70 -0.110 0.28942E+04 209 nontronite-H 2.53 -0.55 -3.08 -0.207 0.52674E+04 210 nontronite-K 3.34 1.48 -1.86 -0.120 0.31820E+04 211 nontronite-Mg 3.07 0.95 -2.12 -0.138 0.36247E+04 212 nontronite-Na 3.52 2.17 -1.35 -0.087 0.23024E+04 228 tobermorite 9.82 7.39 -2.43 -0.663 0.41515E+04 234 alabandite -0.98 -4.40 -3.42 -1.141 0.58471E+04 237 boehmite 4.41 0.57 -3.84 -0.640 0.65571E+04 239 ferrous-oxide 9.81 6.64 -3.17 -0.793 0.54128E+04 245 silica-amorphous -2.09 -3.07 -0.98 -0.325 0.16670E+04 247 an20ab80 2.02 1.20 -0.81 -0.063 0.13903E+04 248 an25ab75 2.65 1.60 -1.05 -0.080 0.17849E+04 249 an30ab70 3.28 2.00 -1.28 -0.099 0.21890E+04 250 tr.625ac.25prg.125 45.16 43.93 -1.24 -0.033 0.21134E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 0.0004000 MOLES Current total amount of reactant added: 0.0119900 MOLES New total amount of reactant added: 0.0123900 MOLES Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.5508E-08 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 7 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 0.0123900 Water: Moles liquid = 0.4986E+02 kg liquid = 0.8983E+00 Moles total = 0.4986E+02 kg total = 0.8982E+00 Activity = 1.0000 Stoichiometric ionic strength = .1212384E-01 Osmotic coef. = 0.9447 True ionic strength = .2072440E-01 Chg. balance for total moles = -.5508E-08 Max. difference allowed = 0.2110E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.11134E-09 -9.9533 0.93357E-10 -10.0299 0.83846E+00 -0.0765 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.23381E-03 -3.6311 0.19483E-03 -3.7103 0.83328E+00 -0.0792 4 SO4-- 0.49176E-04 -4.3082 0.25307E-04 -4.5968 0.51462E+00 -0.2885 5 HCO3- 0.40135E-03 -3.3965 0.33493E-03 -3.4750 0.83453E+00 -0.0786 6 HS- 0.31426E-03 -3.5027 0.26190E-03 -3.5819 0.83340E+00 -0.0791 7 Al+++ 0.13055E-28 -28.8842 0.29540E-29 -29.5296 0.22628E+00 -0.6454 8 H4SiO4 0.86203E-03 -3.0645 0.86203E-03 -3.0645 0.10000E+01 0.0000 9 Ca++ 0.59771E-07 -7.2235 0.30527E-07 -7.5153 0.51074E+00 -0.2918 10 Mg++ 0.22039E-10 -10.6568 0.11203E-10 -10.9507 0.50834E+00 -0.2938 11 Fe++ 0.77147E-13 -13.1127 0.39261E-13 -13.4060 0.50891E+00 -0.2934 12 K+ 0.15656E-03 -3.8053 0.13069E-03 -3.8838 0.83473E+00 -0.0785 13 Na+ 0.19908E-01 -1.7010 0.16586E-01 -1.7803 0.83312E+00 -0.0793 14 Mn++ 0.28687E-10 -10.5423 0.14611E-10 -10.8353 0.50934E+00 -0.2930 15 F- 0.56105E-05 -5.2510 0.46652E-05 -5.3311 0.83151E+00 -0.0801 16 HPO4-- 0.45501E-07 -7.3420 0.23419E-07 -7.6304 0.51470E+00 -0.2884 18 HSiO3- 0.10347E-01 -1.9852 0.86219E-02 -2.0644 0.83328E+00 -0.0792 19 Ca(HSiO3)+ 0.71793E-08 -8.1439 0.59941E-08 -8.2223 0.83492E+00 -0.0784 20 Mg(HSiO3)+ 0.32790E-11 -11.4843 0.27377E-11 -11.5626 0.83492E+00 -0.0784 21 NaHSiO3,aq 0.23129E-02 -2.6359 0.23129E-02 -2.6359 0.10000E+01 0.0000 22 AlO+ 0.55227E-16 -16.2578 0.46110E-16 -16.3362 0.83492E+00 -0.0784 24 HAlO2,aq 0.98362E-10 -10.0072 0.98362E-10 -10.0072 0.10000E+01 0.0000 25 AlO2- 0.28041E-05 -5.5522 0.23323E-05 -5.6322 0.83173E+00 -0.0800 26 CH4,aq 0.33795E-08 -8.4711 0.33670E-08 -8.4728 0.99631E+00 -0.0016 31 CO,aq 0.36903E-15 -15.4329 0.36903E-15 -15.4329 0.10000E+01 0.0000 32 CO2,aq 0.67061E-07 -7.1735 0.66813E-07 -7.1751 0.99631E+00 -0.0016 33 CO3-2 0.61027E-03 -3.2145 0.31337E-03 -3.5039 0.51350E+00 -0.2895 34 CaCO3,aq 0.11995E-06 -6.9210 0.11995E-06 -6.9210 0.10000E+01 0.0000 35 Ca(HCO3)+ 0.31260E-09 -9.5050 0.26099E-09 -9.5834 0.83492E+00 -0.0784 36 CaCl+ 0.11528E-10 -10.9382 0.96250E-11 -11.0166 0.83492E+00 -0.0784 37 CaCl2,aq 0.44551E-15 -15.3511 0.44551E-15 -15.3511 0.10000E+01 0.0000 38 CaF+ 0.24904E-11 -11.6037 0.20793E-11 -11.6821 0.83492E+00 -0.0784 39 CaOH+ 0.27913E-07 -7.5542 0.23305E-07 -7.6326 0.83492E+00 -0.0784 40 CaSO4,aq 0.24532E-09 -9.6103 0.24532E-09 -9.6103 0.10000E+01 0.0000 41 HCl,aq 0.33330E-14 -14.4772 0.33330E-14 -14.4772 0.10000E+01 0.0000 45 HF,aq 0.29815E-11 -11.5256 0.29815E-11 -11.5256 0.10000E+01 0.0000 46 HF2- 0.56357E-17 -17.2490 0.46961E-17 -17.3283 0.83328E+00 -0.0792 48 FeCl+ 0.14501E-16 -16.8386 0.12107E-16 -16.9170 0.83492E+00 -0.0784 51 FeF+ 0.11211E-16 -16.9504 0.93598E-17 -17.0287 0.83492E+00 -0.0784 53 FeO,aq 0.17508E-09 -9.7568 0.17508E-09 -9.7568 0.10000E+01 0.0000 54 FeOH+ 0.16396E-10 -10.7853 0.13689E-10 -10.8636 0.83492E+00 -0.0784 55 HFeO2- 0.23549E-07 -7.6280 0.19623E-07 -7.7072 0.83328E+00 -0.0792 56 FeO+ 0.83403E-16 -16.0788 0.69634E-16 -16.1572 0.83492E+00 -0.0784 58 FeO2- 0.19620E-08 -8.7073 0.16349E-08 -8.7865 0.83328E+00 -0.0792 59 HFeO2,aq 0.19412E-10 -10.7119 0.19412E-10 -10.7119 0.10000E+01 0.0000 60 H2,aq 0.22069E-06 -6.6562 0.21987E-06 -6.6578 0.99631E+00 -0.0016 61 KCl,aq 0.46148E-09 -9.3358 0.46148E-09 -9.3358 0.10000E+01 0.0000 62 KHSO4,aq 0.87299E-18 -18.0590 0.87299E-18 -18.0590 0.10000E+01 0.0000 63 KOH,aq 0.59784E-06 -6.2234 0.59784E-06 -6.2234 0.10000E+01 0.0000 64 KSO4- 0.61590E-07 -7.2105 0.51322E-07 -7.2897 0.83328E+00 -0.0792 65 MgCO3,aq 0.11034E-10 -10.9573 0.11034E-10 -10.9573 0.10000E+01 0.0000 66 Mg(HCO3)+ 0.11722E-12 -12.9310 0.97873E-13 -13.0093 0.83492E+00 -0.0784 67 MgCl+ 0.38345E-14 -14.4163 0.32015E-14 -14.4946 0.83492E+00 -0.0784 68 MgF+ 0.33856E-14 -14.4704 0.28267E-14 -14.5487 0.83492E+00 -0.0784 69 MgOH+ 0.56684E-10 -10.2465 0.47327E-10 -10.3249 0.83492E+00 -0.0784 71 MnF+ 0.13752E-14 -14.8616 0.11481E-14 -14.9400 0.83492E+00 -0.0784 72 MnO,aq 0.17362E-08 -8.7604 0.17362E-08 -8.7604 0.10000E+01 0.0000 73 MnOH+ 0.56685E-09 -9.2465 0.47327E-09 -9.3249 0.83492E+00 -0.0784 74 MnO2-2 0.12875E-10 -10.8903 0.66111E-11 -11.1797 0.51350E+00 -0.2895 75 HMnO2- 0.16227E-09 -9.7898 0.13522E-09 -9.8690 0.83328E+00 -0.0792 78 MnCl+ 0.20996E-13 -13.6779 0.17530E-13 -13.7562 0.83492E+00 -0.0784 79 MnSO4,aq 0.10675E-12 -12.9716 0.10675E-12 -12.9716 0.10000E+01 0.0000 80 NaCl,aq 0.10709E-05 -5.9703 0.10709E-05 -5.9703 0.10000E+01 0.0000 81 NaF,aq 0.18115E-07 -7.7420 0.18115E-07 -7.7420 0.10000E+01 0.0000 82 NaOH,aq 0.76332E-04 -4.1173 0.76332E-04 -4.1173 0.10000E+01 0.0000 84 OH- 0.74410E-02 -2.1284 0.61889E-02 -2.2084 0.83173E+00 -0.0800 89 HPO3-2 0.31250E-16 -16.5051 0.16047E-16 -16.7946 0.51350E+00 -0.2895 92 H3PO4,aq 0.14275E-17 -17.8454 0.14275E-17 -17.8454 0.10000E+01 0.0000 93 H2PO4- 0.48355E-10 -10.3156 0.40332E-10 -10.3943 0.83409E+00 -0.0788 94 PO4-3 0.86006E-09 -9.0655 0.20467E-09 -9.6889 0.23798E+00 -0.6235 98 HP2O7-3 0.12044E-17 -17.9192 0.27281E-18 -18.5641 0.22651E+00 -0.6449 99 P2O7-4 0.93873E-17 -17.0275 0.69811E-18 -18.1561 0.74367E-01 -1.1286 100 H2S,aq 0.75846E-07 -7.1201 0.75566E-07 -7.1217 0.99631E+00 -0.0016 101 S2-2 0.13462E-10 -10.8709 0.69125E-11 -11.1604 0.51350E+00 -0.2895 102 S3-2 0.62331E-17 -17.2053 0.32007E-17 -17.4948 0.51350E+00 -0.2895 107 SO3-2 0.13875E-11 -11.8578 0.72308E-12 -12.1408 0.52113E+00 -0.2831 108 HSO3- 0.50722E-14 -14.2948 0.42266E-14 -14.3740 0.83328E+00 -0.0792 109 HSO4- 0.27243E-11 -11.5647 0.22768E-11 -11.6427 0.83575E+00 -0.0779 111 S2O3-2 0.43747E-13 -13.3591 0.22464E-13 -13.6485 0.51350E+00 -0.2895 Charge balance for all species = -.6131E-08 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.1113433E-09 -.2079938E-01 -.2092710E+02 0.0000 2 H2O 0.1000000E+01 0.5550311E+02 0.9981205E+06 0.0000 3 Cl- 0.2338092E-03 0.2348805E-03 0.8312356E+01 6.3195 4 SO4-- 0.4917566E-04 0.4917920E-04 0.4715800E+01 15.4629 5 HCO3- 0.4013457E-03 0.1011802E-02 0.6162710E+02 6.5548 6 HS- 0.3142554E-03 0.3143896E-03 0.1037893E+02 6.4480 7 Al+++ 0.1305485E-28 0.2804220E-05 0.7552700E-01 0.5600 8 H4SiO4 0.8620273E-03 0.1352187E-01 0.1297340E+04 -3.0645 9 Ca++ 0.5977050E-07 0.2153852E-06 0.8616800E-02 12.5444 10 Mg++ 0.2203907E-10 0.9316091E-10 0.2260885E-05 9.1091 11 Fe++ 0.7714749E-13 0.2572159E-07 0.1433910E-02 6.6537 12 K+ 0.1565646E-03 0.1572245E-03 0.6136818E+01 6.1461 13 Na+ 0.1990812E-01 0.2229840E-01 0.5117207E+03 8.2496 14 Mn++ 0.2868660E-10 0.2506985E-08 0.1374829E-03 9.2244 15 F- 0.5610501E-05 0.5628622E-05 0.1067417E+00 4.6987 16 HPO4-- 0.4550121E-07 0.4640963E-07 0.4446399E-02 12.4293 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.1869245E-01 -.1868337E-01 -.9072424E-05 0.0000000E+00 2 H2O 0.4985655E+02 0.4985656E+02 -.9029400E-05 0.0000000E+00 3 Cl- 0.2109852E-03 0.2109852E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.4417719E-04 0.4417600E-04 0.1185930E-08 0.0000000E+00 5 HCO3- 0.9088670E-03 0.9088670E-03 0.0000000E+00 0.0000000E+00 6 HS- 0.2824043E-03 0.2824055E-03 -.1185930E-08 0.0000000E+00 7 Al+++ 0.4775352E-05 0.2518935E-05 0.2256417E-05 0.0000000E+00 8 H4SiO4 0.1215302E-01 0.1214624E-01 0.6783102E-05 0.0000000E+00 9 Ca++ 0.2080835E-06 0.1934732E-06 0.1461030E-07 0.0000000E+00 10 Mg++ 0.8368328E-10 0.8368328E-10 0.0000000E+00 0.0000000E+00 11 Fe++ 0.3259227E-07 0.2310483E-07 0.9487440E-08 0.0000000E+00 12 K+ 0.1412294E-03 0.1412294E-03 0.0000000E+00 0.0000000E+00 13 Na+ 0.2003215E-01 0.2002989E-01 0.2256164E-05 0.0000000E+00 14 Mn++ 0.2251939E-08 0.2251939E-08 0.0000000E+00 0.0000000E+00 15 F- 0.5056000E-05 0.5056000E-05 0.0000000E+00 0.0000000E+00 16 HPO4-- 0.4168819E-07 0.4168819E-07 0.0000000E+00 0.0000000E+00 Chg. balance for solid moles: 0.0000E+00 Mass of aqueous solution: 0.899872E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 0.0123900 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 0.2256E-05 -5.647 0.5916E-03 -3.228 99.58 0.2271E-03 andradite 0.4744E-08 -8.324 0.2411E-05 -5.618 0.4058 0.6263E-06 grossular 0.1264E-09 -9.898 0.5693E-07 -7.245 0.9582E-02 0.1584E-07 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.9740E+00 0.9740E+00 1.0000 -0.011 grossular 0.2595E-01 0.2595E-01 1.0000 -1.586 Solid products produced: Mass = 0.000594 g Volume = 0.000228 cm3 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.0123900 moles log = -1.9069 Original solution: 1000.0103000 g Original solution / Rock added: 80711.08 (Water/Rock Ratio), log = 4.9069 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0206 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9997E+00 0.9859 0.1006E+01 0.1020E+01 CO2,gas 0.6955E-05 1.0071 0.7148E-05 0.7098E-05 CH4,gas 0.4796E-05 1.0125 0.4956E-05 0.4895E-05 H2,gas 0.2827E-03 1.0005 0.2887E-03 0.2885E-03 H2S,gas 0.2043E-05 0.9960 0.2077E-05 0.2086E-05 S2,gas 0.1905E-23 1.0000 0.1944E-23 0.1944E-23 CO,gas 0.5388E-12 1.0000 0.5499E-12 0.5499E-12 SO3,gas 0.8171E-40 1.0000 0.8339E-40 0.8339E-40 SO2,gas 0.9177E-21 1.0000 0.9366E-21 0.9366E-21 HF,gas 0.7173E-14 1.0000 0.7321E-14 0.7321E-14 HCl,gas 0.5762E-17 1.0000 0.5881E-17 0.5881E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 17 albite -0.38 -0.38 0.00 0.000 0.11184E-10 23 andradite 39.01 39.01 0.00 0.000 0.00000E+00 24 grossular 32.73 32.73 0.00 0.000 0.24265E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -13.50 -6.84 -2.282 0.11687E+05 -5.146 3 CH4,gas 4.54 -2.46 -7.00 -1.751 0.11959E+05 -5.305 4 H2,gas 8.00 2.76 -5.24 -2.993 0.89447E+04 -3.540 5 H2S,gas -6.23 -13.61 -7.38 -3.691 0.12604E+05 -5.683 6 S2,gas -7.34 -32.75 -25.41 -3.909 0.43387E+05 -23.711 7 CO,gas 3.21 -10.74 -13.96 -4.295 0.23834E+05 -12.260 8 SO3,gas 17.12 -24.66 -41.78 -10.444 0.71335E+05 -40.079 9 SO2,gas 0.83 -21.90 -22.73 -6.061 0.38806E+05 -21.028 10 HF,gas 0.47 -15.36 -15.83 -7.917 0.27037E+05 -14.135 11 HCl,gas 5.19 -13.74 -18.93 -9.465 0.32322E+05 -17.231 12 acmite 7.71 7.39 -0.32 -0.033 0.53956E+03 16 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 20 spessartine 24.46 19.60 -4.86 -0.243 0.82942E+04 21 analcite 3.32 2.68 -0.64 -0.071 0.10949E+04 27 annite 20.12 17.47 -2.65 -0.147 0.45244E+04 28 phlogopite 27.06 24.84 -2.22 -0.124 0.37988E+04 33 apatite-OH -18.15 -20.35 -2.19 -0.169 0.37478E+04 34 apatite-F -34.30 -35.71 -1.41 -0.117 0.24048E+04 38 aragonite 0.97 -0.96 -1.93 -0.642 0.32903E+04 39 brucite 12.57 9.11 -3.46 -0.692 0.59070E+04 40 calcite 0.81 -0.96 -1.77 -0.591 0.30261E+04 41 carnegieite-low 9.02 5.75 -3.28 -0.468 0.55974E+04 42 carnegieite-high 10.09 5.75 -4.35 -0.621 0.74244E+04 43 carpholite-Mg 8.58 4.10 -4.48 -0.299 0.76530E+04 45 celadonite 5.34 3.56 -1.78 -0.105 0.30468E+04 46 celadonite-Fe 3.88 1.10 -2.77 -0.163 0.47377E+04 47 chrysotile 23.89 21.20 -2.69 -0.225 0.46002E+04 49 clinochlore 39.07 37.47 -1.60 -0.050 0.27281E+04 50 daphnite 28.97 25.19 -3.77 -0.118 0.64378E+04 52 chlorite-Al-free 47.17 42.40 -4.78 -0.199 0.81556E+04 54 chloritoid-Fe 9.17 4.71 -4.46 -0.298 0.76230E+04 55 chloritoid-Mn 11.40 7.28 -4.12 -0.275 0.70368E+04 57 coesite -2.38 -3.06 -0.69 -0.229 0.11755E+04 64 cristobalite -2.56 -3.06 -0.50 -0.168 0.86081E+03 66 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71249E+04 68 diaspore 2.87 0.56 -2.31 -0.386 0.39506E+04 69 diamond -3.10 -7.98 -4.88 -1.394 0.83327E+04 70 diopside 16.18 15.52 -0.66 -0.066 0.11216E+04 71 hedenbergite 14.21 13.07 -1.14 -0.114 0.19451E+04 78 epidote 24.67 22.29 -2.38 -0.115 0.40664E+04 80 epidote-Fe 29.84 27.00 -2.84 -0.147 0.48480E+04 81 fayalite 14.05 10.24 -3.80 -0.543 0.64933E+04 82 ferrosilite 11.15 7.18 -3.97 -0.397 0.67805E+04 86 gibbsite 4.08 0.56 -3.52 -0.503 0.60092E+04 87 glaucophane 22.97 20.43 -2.54 -0.069 0.43444E+04 88 glaucophane-Fe 17.28 13.06 -4.21 -0.114 0.71910E+04 89 graphite -3.55 -7.98 -4.44 -1.268 0.75749E+04 90 greenalite 16.14 13.83 -2.31 -0.192 0.39399E+04 93 hematite 12.57 10.55 -2.02 -0.245 0.34491E+04 94 heulandite -5.83 -7.79 -1.96 -0.089 0.33462E+04 98 jadeite 4.22 2.68 -1.53 -0.153 0.26204E+04 99 julgoldite 70.43 66.19 -4.24 -0.110 0.72338E+04 100 kalsilite 7.58 3.64 -3.94 -0.563 0.67314E+04 101 kaolinite -1.33 -5.01 -3.68 -0.334 0.62771E+04 104 laumontite 2.88 1.41 -1.48 -0.098 0.25219E+04 105 lawsonite 9.62 7.54 -2.08 -0.139 0.35527E+04 106 leucite 4.12 0.58 -3.54 -0.354 0.60474E+04 108 lizardite 23.24 21.20 -2.05 -0.170 0.34929E+04 110 magnetite 20.09 17.20 -2.89 -0.236 0.49304E+04 111 minnesotaite 10.39 7.70 -2.68 -0.158 0.45846E+04 115 manganosite 14.06 9.22 -4.83 -1.208 0.82534E+04 119 microcline -2.49 -2.49 0.00 0.000 0.14850E+01 123 muscovite 2.58 -1.37 -3.95 -0.232 0.67442E+04 124 paragonite 4.24 0.74 -3.50 -0.206 0.59819E+04 125 nepheline 8.34 5.75 -2.59 -0.371 0.44298E+04 131 periclase-Fe 11.63 6.65 -4.97 -1.243 0.84911E+04 137 phlogopite-Na 29.65 26.94 -2.70 -0.150 0.46161E+04 139 prehnite 19.37 17.02 -2.36 -0.139 0.40238E+04 140 prehnite-Fe 22.50 21.73 -0.77 -0.046 0.13138E+04 145 pyrite -21.25 -23.33 -2.08 -0.490 0.35584E+04 146 pyrrhotite -4.26 -6.96 -2.70 -0.899 0.46063E+04 147 pyrrhotiteFe0.875 -6.02 -8.13 -2.12 -0.778 0.36116E+04 148 pyroxmangite 7.40 6.16 -1.24 -0.248 0.21151E+04 149 pyrophyllite -6.18 -11.14 -4.96 -0.310 0.84728E+04 150 quartz -2.99 -3.06 -0.08 -0.025 0.12814E+03 154 rhodochrosite -0.98 -4.28 -3.30 -1.101 0.56418E+04 155 rhodonite 7.45 6.16 -1.29 -0.257 0.21954E+04 156 sanidine -1.28 -2.49 -1.21 -0.093 0.20692E+04 158 siderite -2.61 -6.85 -4.24 -1.414 0.72449E+04 166 stilbite -7.52 -7.79 -0.26 -0.013 0.45240E+03 167 stilpnomelane-Fe 13.02 12.95 -0.07 -0.002 0.12197E+03 168 stilpnomelane-Mg 27.44 25.22 -2.22 -0.066 0.37888E+04 174 talc 16.49 15.07 -1.42 -0.084 0.24277E+04 177 tephroite 18.09 15.38 -2.70 -0.386 0.46127E+04 181 tridymite -2.63 -3.06 -0.44 -0.146 0.74811E+03 182 tremolite 47.87 46.12 -1.75 -0.047 0.29898E+04 183 ferroactinolite 38.45 33.84 -4.61 -0.125 0.78732E+04 184 troilite-low -4.41 -6.96 -2.55 -0.849 0.43491E+04 190 wairakite 3.95 1.41 -2.54 -0.150 0.43439E+04 191 walstromite 11.51 9.48 -2.03 -0.406 0.34650E+04 192 wollastonite 10.46 9.48 -0.98 -0.196 0.16754E+04 193 pseudo-wollastonite 11.00 9.48 -1.52 -0.304 0.25953E+04 195 akaganeite 7.75 5.27 -2.48 -0.537 0.42371E+04 202 chalcedony -2.80 -3.06 -0.26 -0.087 0.44743E+03 204 montmorillonite-Ca -2.29 -6.25 -3.96 -0.245 0.67551E+04 205 montmorillonite-K -2.24 -6.29 -4.05 -0.248 0.69184E+04 206 montmorillonite-Mg -2.48 -6.81 -4.33 -0.268 0.74000E+04 207 montmorillonite-Na -2.04 -5.59 -3.56 -0.218 0.60728E+04 208 nontronite-Ca 3.21 1.55 -1.66 -0.108 0.28351E+04 209 nontronite-H 2.53 -0.52 -3.05 -0.204 0.52050E+04 210 nontronite-K 3.34 1.51 -1.83 -0.117 0.31216E+04 211 nontronite-Mg 3.07 0.99 -2.09 -0.135 0.35640E+04 212 nontronite-Na 3.52 2.21 -1.31 -0.084 0.22419E+04 228 tobermorite 9.82 7.39 -2.44 -0.665 0.41629E+04 234 alabandite -0.98 -4.39 -3.41 -1.136 0.58215E+04 237 boehmite 4.41 0.56 -3.85 -0.641 0.65675E+04 239 ferrous-oxide 9.81 6.65 -3.16 -0.789 0.53920E+04 245 silica-amorphous -2.09 -3.06 -0.97 -0.324 0.16616E+04 247 an20ab80 2.02 1.20 -0.82 -0.063 0.13964E+04 248 an25ab75 2.65 1.60 -1.05 -0.081 0.17924E+04 249 an30ab70 3.28 1.99 -1.29 -0.099 0.21981E+04 250 tr.625ac.25prg.125 45.16 43.92 -1.25 -0.034 0.21293E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 0.0004000 MOLES Current total amount of reactant added: 0.0123900 MOLES New total amount of reactant added: 0.0127900 MOLES Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.5508E-08 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 7 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 0.0127900 Water: Moles liquid = 0.4986E+02 kg liquid = 0.8983E+00 Moles total = 0.4986E+02 kg total = 0.8982E+00 Activity = 1.0000 Stoichiometric ionic strength = .1214956E-01 Osmotic coef. = 0.9444 True ionic strength = .2074568E-01 Chg. balance for total moles = -.5508E-08 Max. difference allowed = 0.2133E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.11224E-09 -9.9499 0.94101E-10 -10.0264 0.83840E+00 -0.0765 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.23642E-03 -3.6263 0.19699E-03 -3.7056 0.83322E+00 -0.0792 4 SO4-- 0.51299E-04 -4.2899 0.26392E-04 -4.5785 0.51448E+00 -0.2886 5 HCO3- 0.41605E-03 -3.3809 0.34718E-03 -3.4594 0.83447E+00 -0.0786 6 HS- 0.32294E-03 -3.4909 0.26912E-03 -3.5700 0.83334E+00 -0.0792 7 Al+++ 0.13190E-28 -28.8798 0.29827E-29 -29.5254 0.22614E+00 -0.6456 8 H4SiO4 0.86839E-03 -3.0613 0.86839E-03 -3.0613 0.10000E+01 0.0000 9 Ca++ 0.59131E-07 -7.2282 0.30192E-07 -7.5201 0.51060E+00 -0.2919 10 Mg++ 0.22074E-10 -10.6561 0.11218E-10 -10.9501 0.50820E+00 -0.2940 11 Fe++ 0.80601E-13 -13.0937 0.41007E-13 -13.3871 0.50877E+00 -0.2935 12 K+ 0.15657E-03 -3.8053 0.13068E-03 -3.8838 0.83468E+00 -0.0785 13 Na+ 0.19910E-01 -1.7009 0.16586E-01 -1.7803 0.83306E+00 -0.0793 14 Mn++ 0.29112E-10 -10.5359 0.14824E-10 -10.8290 0.50920E+00 -0.2931 15 F- 0.57880E-05 -5.2375 0.48125E-05 -5.3176 0.83145E+00 -0.0802 16 HPO4-- 0.45507E-07 -7.3419 0.23416E-07 -7.6305 0.51456E+00 -0.2886 18 HSiO3- 0.10342E-01 -1.9854 0.86169E-02 -2.0647 0.83322E+00 -0.0792 19 Ca(HSiO3)+ 0.70968E-08 -8.1489 0.59248E-08 -8.2273 0.83486E+00 -0.0784 20 Mg(HSiO3)+ 0.32816E-11 -11.4839 0.27397E-11 -11.5623 0.83486E+00 -0.0784 21 NaHSiO3,aq 0.23115E-02 -2.6361 0.23115E-02 -2.6361 0.10000E+01 0.0000 22 AlO+ 0.54890E-16 -16.2605 0.45825E-16 -16.3389 0.83486E+00 -0.0784 24 HAlO2,aq 0.96981E-10 -10.0133 0.96981E-10 -10.0133 0.10000E+01 0.0000 25 AlO2- 0.27431E-05 -5.5618 0.22813E-05 -5.6418 0.83167E+00 -0.0800 26 CH4,aq 0.34517E-08 -8.4620 0.34389E-08 -8.4636 0.99630E+00 -0.0016 31 CO,aq 0.38339E-15 -15.4164 0.38339E-15 -15.4164 0.10000E+01 0.0000 32 CO2,aq 0.70067E-07 -7.1545 0.69808E-07 -7.1561 0.99630E+00 -0.0016 33 CO3-2 0.62775E-03 -3.2022 0.32226E-03 -3.4918 0.51336E+00 -0.2896 34 CaCO3,aq 0.12200E-06 -6.9136 0.12200E-06 -6.9136 0.10000E+01 0.0000 35 Ca(HCO3)+ 0.32049E-09 -9.4942 0.26757E-09 -9.5726 0.83486E+00 -0.0784 36 CaCl+ 0.11529E-10 -10.9382 0.96250E-11 -11.0166 0.83486E+00 -0.0784 37 CaCl2,aq 0.45046E-15 -15.3463 0.45046E-15 -15.3463 0.10000E+01 0.0000 38 CaF+ 0.25410E-11 -11.5950 0.21214E-11 -11.6734 0.83486E+00 -0.0784 39 CaOH+ 0.27390E-07 -7.5624 0.22867E-07 -7.6408 0.83486E+00 -0.0784 40 CaSO4,aq 0.25303E-09 -9.5968 0.25303E-09 -9.5968 0.10000E+01 0.0000 41 HCl,aq 0.33968E-14 -14.4689 0.33968E-14 -14.4689 0.10000E+01 0.0000 45 HF,aq 0.31001E-11 -11.5086 0.31001E-11 -11.5086 0.10000E+01 0.0000 46 HF2- 0.60454E-17 -17.2186 0.50371E-17 -17.2978 0.83322E+00 -0.0792 48 FeCl+ 0.15315E-16 -16.8149 0.12786E-16 -16.8933 0.83486E+00 -0.0784 51 FeF+ 0.12080E-16 -16.9180 0.10085E-16 -16.9963 0.83486E+00 -0.0784 53 FeO,aq 0.17999E-09 -9.7448 0.17999E-09 -9.7448 0.10000E+01 0.0000 54 FeOH+ 0.16991E-10 -10.7698 0.14185E-10 -10.8482 0.83486E+00 -0.0784 55 HFeO2- 0.24019E-07 -7.6195 0.20013E-07 -7.6987 0.83322E+00 -0.0792 56 FeO+ 0.86675E-16 -16.0621 0.72361E-16 -16.1405 0.83486E+00 -0.0784 58 FeO2- 0.20068E-08 -8.6975 0.16721E-08 -8.7767 0.83322E+00 -0.0792 59 HFeO2,aq 0.20012E-10 -10.6987 0.20012E-10 -10.6987 0.10000E+01 0.0000 60 H2,aq 0.21944E-06 -6.6587 0.21863E-06 -6.6603 0.99630E+00 -0.0016 61 KCl,aq 0.46658E-09 -9.3311 0.46658E-09 -9.3311 0.10000E+01 0.0000 62 KHSO4,aq 0.91763E-18 -18.0373 0.91763E-18 -18.0373 0.10000E+01 0.0000 63 KOH,aq 0.59307E-06 -6.2269 0.59307E-06 -6.2269 0.10000E+01 0.0000 64 KSO4- 0.64233E-07 -7.1922 0.53520E-07 -7.2715 0.83322E+00 -0.0792 65 MgCO3,aq 0.11362E-10 -10.9445 0.11362E-10 -10.9445 0.10000E+01 0.0000 66 Mg(HCO3)+ 0.12168E-12 -12.9148 0.10158E-12 -12.9932 0.83486E+00 -0.0784 67 MgCl+ 0.38824E-14 -14.4109 0.32413E-14 -14.4893 0.83486E+00 -0.0784 68 MgF+ 0.34973E-14 -14.4563 0.29197E-14 -14.5347 0.83486E+00 -0.0784 69 MgOH+ 0.56313E-10 -10.2494 0.47014E-10 -10.3278 0.83486E+00 -0.0784 71 MnF+ 0.14393E-14 -14.8418 0.12016E-14 -14.9202 0.83486E+00 -0.0784 72 MnO,aq 0.17337E-08 -8.7610 0.17337E-08 -8.7610 0.10000E+01 0.0000 73 MnOH+ 0.57059E-09 -9.2437 0.47636E-09 -9.3221 0.83486E+00 -0.0784 74 MnO2-2 0.12657E-10 -10.8977 0.64977E-11 -11.1872 0.51336E+00 -0.2896 75 HMnO2- 0.16077E-09 -9.7938 0.13396E-09 -9.8730 0.83322E+00 -0.0792 78 MnCl+ 0.21540E-13 -13.6668 0.17982E-13 -13.7452 0.83486E+00 -0.0784 79 MnSO4,aq 0.11295E-12 -12.9471 0.11295E-12 -12.9471 0.10000E+01 0.0000 80 NaCl,aq 0.10828E-05 -5.9655 0.10828E-05 -5.9655 0.10000E+01 0.0000 81 NaF,aq 0.18687E-07 -7.7285 0.18687E-07 -7.7285 0.10000E+01 0.0000 82 NaOH,aq 0.75730E-04 -4.1207 0.75730E-04 -4.1207 0.10000E+01 0.0000 84 OH- 0.73827E-02 -2.1318 0.61400E-02 -2.2118 0.83167E+00 -0.0800 89 HPO3-2 0.31077E-16 -16.5076 0.15954E-16 -16.7971 0.51336E+00 -0.2896 92 H3PO4,aq 0.14502E-17 -17.8386 0.14502E-17 -17.8386 0.10000E+01 0.0000 93 H2PO4- 0.48737E-10 -10.3121 0.40648E-10 -10.3910 0.83403E+00 -0.0788 94 PO4-3 0.85363E-09 -9.0687 0.20303E-09 -9.6924 0.23784E+00 -0.6237 98 HP2O7-3 0.12144E-17 -17.9156 0.27490E-18 -18.5608 0.22637E+00 -0.6452 99 P2O7-4 0.93947E-17 -17.0271 0.69791E-18 -18.1562 0.74287E-01 -1.1291 100 H2S,aq 0.78560E-07 -7.1048 0.78269E-07 -7.1064 0.99630E+00 -0.0016 101 S2-2 0.14299E-10 -10.8447 0.73406E-11 -11.1343 0.51336E+00 -0.2896 102 S3-2 0.68969E-17 -17.1613 0.35406E-17 -17.4509 0.51336E+00 -0.2896 107 SO3-2 0.14392E-11 -11.8419 0.74982E-12 -12.1250 0.52100E+00 -0.2832 108 HSO3- 0.53021E-14 -14.2756 0.44178E-14 -14.3548 0.83322E+00 -0.0792 109 HSO4- 0.28640E-11 -11.5430 0.23934E-11 -11.6210 0.83570E+00 -0.0780 111 S2O3-2 0.47268E-13 -13.3254 0.24266E-13 -13.6150 0.51336E+00 -0.2896 Charge balance for all species = -.6131E-08 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.1122380E-09 -.2075103E-01 -.2087843E+02 0.0000 2 H2O 0.1000000E+01 0.5550306E+02 0.9981179E+06 0.0000 3 Cl- 0.2364228E-03 0.2375060E-03 0.8405258E+01 6.3209 4 SO4-- 0.5129876E-04 0.5130520E-04 0.4919655E+01 15.4743 5 HCO3- 0.4160476E-03 0.1043989E-02 0.6358749E+02 6.5670 6 HS- 0.3229450E-03 0.3230816E-03 0.1066587E+02 6.4564 7 Al+++ 0.1318996E-28 0.2743173E-05 0.7388268E-01 0.5538 8 H4SiO4 0.8683909E-03 0.1352159E-01 0.1297311E+04 -3.0613 9 Ca++ 0.5913064E-07 0.2162038E-06 0.8649534E-02 12.5327 10 Mg++ 0.2207411E-10 0.9316021E-10 0.2260865E-05 9.1027 11 Fe++ 0.8060107E-13 0.2624262E-07 0.1462953E-02 6.6657 12 K+ 0.1565655E-03 0.1572233E-03 0.6136762E+01 6.1426 13 Na+ 0.1990980E-01 0.2229817E-01 0.5117146E+03 8.2462 14 Mn++ 0.2911230E-10 0.2506966E-08 0.1374816E-03 9.2238 15 F- 0.5788006E-05 0.5806699E-05 0.1101186E+00 4.7088 16 HPO4-- 0.4550691E-07 0.4640928E-07 0.4446358E-02 12.4223 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.1864938E-01 -.1864009E-01 -.9289367E-05 0.0000000E+00 2 H2O 0.4985688E+02 0.4985689E+02 -.9248529E-05 0.0000000E+00 3 Cl- 0.2133452E-03 0.2133452E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.4608719E-04 0.4608606E-04 0.1127405E-08 0.0000000E+00 5 HCO3- 0.9377870E-03 0.9377870E-03 0.0000000E+00 0.0000000E+00 6 HS- 0.2902143E-03 0.2902154E-03 -.1127405E-08 0.0000000E+00 7 Al+++ 0.4775352E-05 0.2464117E-05 0.2311235E-05 0.0000000E+00 8 H4SiO4 0.1215302E-01 0.1214607E-01 0.6946888E-05 0.0000000E+00 9 Ca++ 0.2080835E-06 0.1942099E-06 0.1387356E-07 0.0000000E+00 10 Mg++ 0.8368328E-10 0.8368328E-10 0.0000000E+00 0.0000000E+00 11 Fe++ 0.3259227E-07 0.2357303E-07 0.9019239E-08 0.0000000E+00 12 K+ 0.1412294E-03 0.1412294E-03 0.0000000E+00 0.0000000E+00 13 Na+ 0.2003215E-01 0.2002984E-01 0.2311005E-05 0.0000000E+00 14 Mn++ 0.2251939E-08 0.2251939E-08 0.0000000E+00 0.0000000E+00 15 F- 0.5216000E-05 0.5216000E-05 0.0000000E+00 0.0000000E+00 16 HPO4-- 0.4168819E-07 0.4168819E-07 0.0000000E+00 0.0000000E+00 Chg. balance for solid moles: 0.1271E-20 Mass of aqueous solution: 0.899880E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 0.0127900 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 0.2311E-05 -5.636 0.6060E-03 -3.218 99.61 0.2326E-03 andradite 0.4510E-08 -8.346 0.2292E-05 -5.640 0.3767 0.5954E-06 grossular 0.1149E-09 -9.940 0.5176E-07 -7.286 0.8508E-02 0.1440E-07 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.9752E+00 0.9752E+00 1.0000 -0.011 grossular 0.2485E-01 0.2485E-01 1.0000 -1.605 Solid products produced: Mass = 0.000608 g Volume = 0.000233 cm3 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.0127900 moles log = -1.8931 Original solution: 1000.0103000 g Original solution / Rock added: 78186.89 (Water/Rock Ratio), log = 4.8931 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0206 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9997E+00 0.9859 0.1006E+01 0.1020E+01 CO2,gas 0.7266E-05 1.0071 0.7469E-05 0.7416E-05 CH4,gas 0.4898E-05 1.0125 0.5062E-05 0.4999E-05 H2,gas 0.2811E-03 1.0005 0.2870E-03 0.2869E-03 H2S,gas 0.2117E-05 0.9960 0.2152E-05 0.2160E-05 S2,gas 0.2067E-23 1.0000 0.2109E-23 0.2109E-23 CO,gas 0.5598E-12 1.0000 0.5713E-12 0.5713E-12 SO3,gas 0.8658E-40 1.0000 0.8836E-40 0.8836E-40 SO2,gas 0.9668E-21 1.0000 0.9868E-21 0.9868E-21 HF,gas 0.7458E-14 1.0000 0.7612E-14 0.7612E-14 HCl,gas 0.5873E-17 1.0000 0.5994E-17 0.5994E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 17 albite -0.38 -0.38 0.00 0.000 -0.94784E-12 23 andradite 39.01 39.01 0.00 0.000 0.12132E-10 24 grossular 32.73 32.73 0.00 0.000 -0.24265E-10 167 stilpnomelane-Fe 13.02 13.02 0.00 0.000 -0.19321E+00 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -13.49 -6.83 -2.275 0.11655E+05 -5.127 3 CH4,gas 4.54 -2.45 -6.99 -1.749 0.11943E+05 -5.296 4 H2,gas 8.00 2.76 -5.24 -2.995 0.89489E+04 -3.542 5 H2S,gas -6.23 -13.60 -7.37 -3.683 0.12578E+05 -5.667 6 S2,gas -7.34 -32.71 -25.37 -3.904 0.43327E+05 -23.676 7 CO,gas 3.21 -10.73 -13.94 -4.290 0.23806E+05 -12.243 8 SO3,gas 17.12 -24.63 -41.75 -10.438 0.71292E+05 -40.054 9 SO2,gas 0.83 -21.87 -22.70 -6.055 0.38768E+05 -21.006 10 HF,gas 0.47 -15.34 -15.82 -7.909 0.27008E+05 -14.119 11 HCl,gas 5.19 -13.73 -18.92 -9.461 0.32308E+05 -17.222 12 acmite 7.71 7.41 -0.30 -0.031 0.51193E+03 16 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 20 spessartine 24.46 19.60 -4.86 -0.243 0.83020E+04 21 analcite 3.32 2.68 -0.64 -0.072 0.11004E+04 27 annite 20.12 17.51 -2.61 -0.145 0.44629E+04 28 phlogopite 27.06 24.82 -2.24 -0.125 0.38312E+04 33 apatite-OH -18.15 -20.39 -2.23 -0.172 0.38126E+04 34 apatite-F -34.30 -35.73 -1.43 -0.119 0.24407E+04 38 aragonite 0.97 -0.95 -1.92 -0.640 0.32778E+04 39 brucite 12.57 9.10 -3.47 -0.693 0.59178E+04 40 calcite 0.81 -0.95 -1.76 -0.588 0.30136E+04 41 carnegieite-low 9.02 5.74 -3.28 -0.469 0.56084E+04 42 carnegieite-high 10.09 5.74 -4.35 -0.622 0.74353E+04 43 carpholite-Mg 8.58 4.09 -4.49 -0.300 0.76738E+04 45 celadonite 5.34 3.55 -1.79 -0.105 0.30522E+04 46 celadonite-Fe 3.88 1.12 -2.76 -0.162 0.47118E+04 47 chrysotile 23.89 21.19 -2.71 -0.226 0.46217E+04 49 clinochlore 39.07 37.44 -1.63 -0.051 0.27867E+04 50 daphnite 28.97 25.25 -3.71 -0.116 0.63399E+04 52 chlorite-Al-free 47.17 42.37 -4.80 -0.200 0.81986E+04 54 chloritoid-Fe 9.17 4.71 -4.46 -0.297 0.76180E+04 55 chloritoid-Mn 11.40 7.27 -4.13 -0.275 0.70534E+04 57 coesite -2.38 -3.06 -0.69 -0.228 0.11700E+04 64 cristobalite -2.56 -3.06 -0.50 -0.167 0.85535E+03 66 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71249E+04 68 diaspore 2.87 0.55 -2.32 -0.387 0.39611E+04 69 diamond -3.10 -7.97 -4.87 -1.390 0.83086E+04 70 diopside 16.18 15.51 -0.67 -0.067 0.11414E+04 71 hedenbergite 14.21 13.08 -1.13 -0.113 0.19337E+04 78 epidote 24.67 22.28 -2.39 -0.116 0.40883E+04 80 epidote-Fe 29.84 27.01 -2.83 -0.147 0.48369E+04 81 fayalite 14.05 10.27 -3.78 -0.539 0.64468E+04 82 ferrosilite 11.15 7.21 -3.94 -0.394 0.67286E+04 86 gibbsite 4.08 0.55 -3.53 -0.504 0.60196E+04 87 glaucophane 22.97 20.42 -2.56 -0.069 0.43659E+04 88 glaucophane-Fe 17.28 13.11 -4.17 -0.113 0.71186E+04 89 graphite -3.55 -7.97 -4.42 -1.263 0.75508E+04 90 greenalite 16.14 13.87 -2.27 -0.189 0.38675E+04 93 hematite 12.57 10.57 -1.99 -0.242 0.34039E+04 94 heulandite -5.83 -7.79 -1.96 -0.089 0.33490E+04 98 jadeite 4.22 2.68 -1.54 -0.154 0.26259E+04 99 julgoldite 70.43 66.24 -4.19 -0.109 0.71495E+04 100 kalsilite 7.58 3.64 -3.95 -0.564 0.67424E+04 101 kaolinite -1.33 -5.01 -3.68 -0.335 0.62871E+04 104 laumontite 2.88 1.40 -1.49 -0.099 0.25410E+04 105 lawsonite 9.62 7.52 -2.10 -0.140 0.35827E+04 106 leucite 4.12 0.57 -3.54 -0.354 0.60529E+04 108 lizardite 23.24 21.19 -2.06 -0.172 0.35144E+04 110 magnetite 20.09 17.24 -2.85 -0.233 0.48647E+04 111 minnesotaite 10.39 7.75 -2.64 -0.155 0.45013E+04 115 manganosite 14.06 9.22 -4.83 -1.209 0.82545E+04 119 microcline -2.49 -2.49 0.00 0.000 0.15418E+01 123 muscovite 2.58 -1.38 -3.96 -0.233 0.67653E+04 124 paragonite 4.24 0.72 -3.52 -0.207 0.60028E+04 125 nepheline 8.34 5.74 -2.60 -0.372 0.44407E+04 131 periclase-Fe 11.63 6.67 -4.96 -1.240 0.84706E+04 137 phlogopite-Na 29.65 26.92 -2.72 -0.151 0.46485E+04 139 prehnite 19.37 16.99 -2.38 -0.140 0.40683E+04 140 prehnite-Fe 22.50 21.72 -0.78 -0.047 0.13253E+04 145 pyrite -21.25 -23.29 -2.04 -0.480 0.34816E+04 146 pyrrhotite -4.26 -6.93 -2.67 -0.890 0.45597E+04 147 pyrrhotiteFe0.875 -6.02 -8.11 -2.09 -0.768 0.35671E+04 148 pyroxmangite 7.40 6.16 -1.24 -0.247 0.21107E+04 149 pyrophyllite -6.18 -11.14 -4.96 -0.310 0.84719E+04 150 quartz -2.99 -3.06 -0.07 -0.024 0.12268E+03 154 rhodochrosite -0.98 -4.26 -3.29 -1.095 0.56103E+04 155 rhodonite 7.45 6.16 -1.28 -0.257 0.21910E+04 156 sanidine -1.28 -2.49 -1.21 -0.093 0.20693E+04 158 siderite -2.61 -6.82 -4.21 -1.404 0.71919E+04 166 stilbite -7.52 -7.79 -0.27 -0.013 0.45515E+03 168 stilpnomelane-Mg 27.44 25.20 -2.24 -0.067 0.38231E+04 174 talc 16.49 15.06 -1.43 -0.084 0.24383E+04 177 tephroite 18.09 15.39 -2.70 -0.386 0.46093E+04 181 tridymite -2.63 -3.06 -0.43 -0.145 0.74266E+03 182 tremolite 47.87 46.09 -1.78 -0.048 0.30401E+04 183 ferroactinolite 38.45 33.90 -4.55 -0.123 0.77670E+04 184 troilite-low -4.41 -6.93 -2.52 -0.840 0.43025E+04 190 wairakite 3.95 1.40 -2.56 -0.150 0.43630E+04 191 walstromite 11.51 9.47 -2.04 -0.408 0.34795E+04 192 wollastonite 10.46 9.47 -0.99 -0.198 0.16899E+04 193 pseudo-wollastonite 11.00 9.47 -1.53 -0.306 0.26098E+04 195 akaganeite 7.75 5.29 -2.47 -0.534 0.42145E+04 202 chalcedony -2.80 -3.06 -0.26 -0.086 0.44198E+03 204 montmorillonite-Ca -2.29 -6.25 -3.96 -0.245 0.67577E+04 205 montmorillonite-K -2.24 -6.29 -4.05 -0.248 0.69196E+04 206 montmorillonite-Mg -2.48 -6.81 -4.33 -0.268 0.74011E+04 207 montmorillonite-Na -2.04 -5.60 -3.56 -0.218 0.60740E+04 208 nontronite-Ca 3.21 1.59 -1.63 -0.105 0.27766E+04 209 nontronite-H 2.53 -0.48 -3.01 -0.202 0.51433E+04 210 nontronite-K 3.34 1.55 -1.79 -0.115 0.30618E+04 211 nontronite-Mg 3.07 1.02 -2.05 -0.133 0.35041E+04 212 nontronite-Na 3.52 2.24 -1.28 -0.082 0.21821E+04 228 tobermorite 9.82 7.38 -2.44 -0.667 0.41741E+04 234 alabandite -0.98 -4.37 -3.39 -1.132 0.57965E+04 237 boehmite 4.41 0.55 -3.85 -0.642 0.65780E+04 239 ferrous-oxide 9.81 6.67 -3.15 -0.786 0.53716E+04 245 silica-amorphous -2.09 -3.06 -0.97 -0.323 0.16562E+04 247 an20ab80 2.02 1.20 -0.82 -0.063 0.14024E+04 248 an25ab75 2.65 1.59 -1.05 -0.081 0.17999E+04 249 an30ab70 3.28 1.99 -1.29 -0.099 0.22071E+04 250 tr.625ac.25prg.125 45.16 43.91 -1.26 -0.034 0.21452E+04 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 6 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 0.0127900 Water: Moles liquid = 0.4986E+02 kg liquid = 0.8983E+00 Moles total = 0.4986E+02 kg total = 0.8982E+00 Activity = 1.0000 Stoichiometric ionic strength = .1214956E-01 Osmotic coef. = 0.9444 True ionic strength = .2074568E-01 Chg. balance for total moles = -.5508E-08 Max. difference allowed = 0.2133E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.11224E-09 -9.9499 0.94101E-10 -10.0264 0.83840E+00 -0.0765 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.23642E-03 -3.6263 0.19699E-03 -3.7056 0.83322E+00 -0.0792 4 SO4-- 0.51299E-04 -4.2899 0.26392E-04 -4.5785 0.51448E+00 -0.2886 5 HCO3- 0.41605E-03 -3.3809 0.34718E-03 -3.4594 0.83447E+00 -0.0786 6 HS- 0.32294E-03 -3.4909 0.26912E-03 -3.5700 0.83334E+00 -0.0792 7 Al+++ 0.13190E-28 -28.8798 0.29827E-29 -29.5254 0.22614E+00 -0.6456 8 H4SiO4 0.86839E-03 -3.0613 0.86839E-03 -3.0613 0.10000E+01 0.0000 9 Ca++ 0.59133E-07 -7.2282 0.30193E-07 -7.5201 0.51060E+00 -0.2919 10 Mg++ 0.22074E-10 -10.6561 0.11218E-10 -10.9501 0.50820E+00 -0.2940 11 Fe++ 0.80597E-13 -13.0937 0.41005E-13 -13.3872 0.50877E+00 -0.2935 12 K+ 0.15657E-03 -3.8053 0.13068E-03 -3.8838 0.83468E+00 -0.0785 13 Na+ 0.19910E-01 -1.7009 0.16586E-01 -1.7803 0.83306E+00 -0.0793 14 Mn++ 0.29112E-10 -10.5359 0.14824E-10 -10.8290 0.50920E+00 -0.2931 15 F- 0.57880E-05 -5.2375 0.48125E-05 -5.3176 0.83145E+00 -0.0802 16 HPO4-- 0.45507E-07 -7.3419 0.23416E-07 -7.6305 0.51456E+00 -0.2886 18 HSiO3- 0.10342E-01 -1.9854 0.86169E-02 -2.0647 0.83322E+00 -0.0792 19 Ca(HSiO3)+ 0.70970E-08 -8.1489 0.59250E-08 -8.2273 0.83486E+00 -0.0784 20 Mg(HSiO3)+ 0.32816E-11 -11.4839 0.27397E-11 -11.5623 0.83486E+00 -0.0784 21 NaHSiO3,aq 0.23115E-02 -2.6361 0.23115E-02 -2.6361 0.10000E+01 0.0000 22 AlO+ 0.54890E-16 -16.2605 0.45825E-16 -16.3389 0.83486E+00 -0.0784 24 HAlO2,aq 0.96981E-10 -10.0133 0.96981E-10 -10.0133 0.10000E+01 0.0000 25 AlO2- 0.27431E-05 -5.5618 0.22813E-05 -5.6418 0.83167E+00 -0.0800 26 CH4,aq 0.34517E-08 -8.4620 0.34389E-08 -8.4636 0.99630E+00 -0.0016 31 CO,aq 0.38339E-15 -15.4164 0.38339E-15 -15.4164 0.10000E+01 0.0000 32 CO2,aq 0.70067E-07 -7.1545 0.69808E-07 -7.1561 0.99630E+00 -0.0016 33 CO3-2 0.62775E-03 -3.2022 0.32226E-03 -3.4918 0.51336E+00 -0.2896 34 CaCO3,aq 0.12200E-06 -6.9136 0.12200E-06 -6.9136 0.10000E+01 0.0000 35 Ca(HCO3)+ 0.32050E-09 -9.4942 0.26757E-09 -9.5726 0.83486E+00 -0.0784 36 CaCl+ 0.11529E-10 -10.9382 0.96254E-11 -11.0166 0.83486E+00 -0.0784 37 CaCl2,aq 0.45048E-15 -15.3463 0.45048E-15 -15.3463 0.10000E+01 0.0000 38 CaF+ 0.25411E-11 -11.5950 0.21214E-11 -11.6734 0.83486E+00 -0.0784 39 CaOH+ 0.27391E-07 -7.5624 0.22867E-07 -7.6408 0.83486E+00 -0.0784 40 CaSO4,aq 0.25304E-09 -9.5968 0.25304E-09 -9.5968 0.10000E+01 0.0000 41 HCl,aq 0.33968E-14 -14.4689 0.33968E-14 -14.4689 0.10000E+01 0.0000 45 HF,aq 0.31001E-11 -11.5086 0.31001E-11 -11.5086 0.10000E+01 0.0000 46 HF2- 0.60454E-17 -17.2186 0.50371E-17 -17.2978 0.83322E+00 -0.0792 48 FeCl+ 0.15315E-16 -16.8149 0.12786E-16 -16.8933 0.83486E+00 -0.0784 51 FeF+ 0.12079E-16 -16.9180 0.10084E-16 -16.9964 0.83486E+00 -0.0784 53 FeO,aq 0.17998E-09 -9.7448 0.17998E-09 -9.7448 0.10000E+01 0.0000 54 FeOH+ 0.16990E-10 -10.7698 0.14184E-10 -10.8482 0.83486E+00 -0.0784 55 HFeO2- 0.24017E-07 -7.6195 0.20012E-07 -7.6987 0.83322E+00 -0.0792 56 FeO+ 0.86670E-16 -16.0621 0.72358E-16 -16.1405 0.83486E+00 -0.0784 58 FeO2- 0.20067E-08 -8.6975 0.16720E-08 -8.7768 0.83322E+00 -0.0792 59 HFeO2,aq 0.20011E-10 -10.6987 0.20011E-10 -10.6987 0.10000E+01 0.0000 60 H2,aq 0.21944E-06 -6.6587 0.21863E-06 -6.6603 0.99630E+00 -0.0016 61 KCl,aq 0.46658E-09 -9.3311 0.46658E-09 -9.3311 0.10000E+01 0.0000 62 KHSO4,aq 0.91763E-18 -18.0373 0.91763E-18 -18.0373 0.10000E+01 0.0000 63 KOH,aq 0.59307E-06 -6.2269 0.59307E-06 -6.2269 0.10000E+01 0.0000 64 KSO4- 0.64233E-07 -7.1922 0.53520E-07 -7.2715 0.83322E+00 -0.0792 65 MgCO3,aq 0.11362E-10 -10.9445 0.11362E-10 -10.9445 0.10000E+01 0.0000 66 Mg(HCO3)+ 0.12168E-12 -12.9148 0.10158E-12 -12.9932 0.83486E+00 -0.0784 67 MgCl+ 0.38824E-14 -14.4109 0.32413E-14 -14.4893 0.83486E+00 -0.0784 68 MgF+ 0.34973E-14 -14.4563 0.29197E-14 -14.5347 0.83486E+00 -0.0784 69 MgOH+ 0.56313E-10 -10.2494 0.47014E-10 -10.3278 0.83486E+00 -0.0784 71 MnF+ 0.14393E-14 -14.8418 0.12016E-14 -14.9202 0.83486E+00 -0.0784 72 MnO,aq 0.17337E-08 -8.7610 0.17337E-08 -8.7610 0.10000E+01 0.0000 73 MnOH+ 0.57059E-09 -9.2437 0.47636E-09 -9.3221 0.83486E+00 -0.0784 74 MnO2-2 0.12657E-10 -10.8977 0.64977E-11 -11.1872 0.51336E+00 -0.2896 75 HMnO2- 0.16077E-09 -9.7938 0.13396E-09 -9.8730 0.83322E+00 -0.0792 78 MnCl+ 0.21540E-13 -13.6668 0.17982E-13 -13.7452 0.83486E+00 -0.0784 79 MnSO4,aq 0.11295E-12 -12.9471 0.11295E-12 -12.9471 0.10000E+01 0.0000 80 NaCl,aq 0.10828E-05 -5.9655 0.10828E-05 -5.9655 0.10000E+01 0.0000 81 NaF,aq 0.18687E-07 -7.7285 0.18687E-07 -7.7285 0.10000E+01 0.0000 82 NaOH,aq 0.75730E-04 -4.1207 0.75730E-04 -4.1207 0.10000E+01 0.0000 84 OH- 0.73827E-02 -2.1318 0.61400E-02 -2.2118 0.83167E+00 -0.0800 89 HPO3-2 0.31077E-16 -16.5076 0.15954E-16 -16.7971 0.51336E+00 -0.2896 92 H3PO4,aq 0.14502E-17 -17.8386 0.14502E-17 -17.8386 0.10000E+01 0.0000 93 H2PO4- 0.48737E-10 -10.3121 0.40648E-10 -10.3910 0.83403E+00 -0.0788 94 PO4-3 0.85363E-09 -9.0687 0.20303E-09 -9.6924 0.23784E+00 -0.6237 98 HP2O7-3 0.12144E-17 -17.9156 0.27490E-18 -18.5608 0.22637E+00 -0.6452 99 P2O7-4 0.93947E-17 -17.0271 0.69791E-18 -18.1562 0.74287E-01 -1.1291 100 H2S,aq 0.78560E-07 -7.1048 0.78269E-07 -7.1064 0.99630E+00 -0.0016 101 S2-2 0.14299E-10 -10.8447 0.73406E-11 -11.1343 0.51336E+00 -0.2896 102 S3-2 0.68969E-17 -17.1613 0.35406E-17 -17.4509 0.51336E+00 -0.2896 107 SO3-2 0.14392E-11 -11.8419 0.74982E-12 -12.1250 0.52100E+00 -0.2832 108 HSO3- 0.53021E-14 -14.2756 0.44178E-14 -14.3548 0.83322E+00 -0.0792 109 HSO4- 0.28640E-11 -11.5430 0.23934E-11 -11.6210 0.83570E+00 -0.0780 111 S2O3-2 0.47268E-13 -13.3254 0.24266E-13 -13.6150 0.51336E+00 -0.2896 Charge balance for all species = -.6131E-08 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.1122380E-09 -.2075103E-01 -.2087843E+02 0.0000 2 H2O 0.1000000E+01 0.5550306E+02 0.9981179E+06 0.0000 3 Cl- 0.2364228E-03 0.2375060E-03 0.8405258E+01 6.3209 4 SO4-- 0.5129876E-04 0.5130520E-04 0.4919655E+01 15.4743 5 HCO3- 0.4160476E-03 0.1043989E-02 0.6358749E+02 6.5670 6 HS- 0.3229450E-03 0.3230816E-03 0.1066587E+02 6.4564 7 Al+++ 0.1318996E-28 0.2743173E-05 0.7388268E-01 0.5538 8 H4SiO4 0.8683909E-03 0.1352159E-01 0.1297311E+04 -3.0613 9 Ca++ 0.5913265E-07 0.2162111E-06 0.8649827E-02 12.5327 10 Mg++ 0.2207411E-10 0.9316021E-10 0.2260865E-05 9.1027 11 Fe++ 0.8059687E-13 0.2624125E-07 0.1462877E-02 6.6657 12 K+ 0.1565655E-03 0.1572233E-03 0.6136762E+01 6.1426 13 Na+ 0.1990980E-01 0.2229817E-01 0.5117146E+03 8.2462 14 Mn++ 0.2911229E-10 0.2506966E-08 0.1374816E-03 9.2238 15 F- 0.5788006E-05 0.5806699E-05 0.1101186E+00 4.7088 16 HPO4-- 0.4550691E-07 0.4640928E-07 0.4446358E-02 12.4223 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.1864938E-01 -.1864009E-01 -.9289356E-05 0.0000000E+00 2 H2O 0.4985688E+02 0.4985689E+02 -.9248520E-05 0.0000000E+00 3 Cl- 0.2133452E-03 0.2133452E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.4608719E-04 0.4608606E-04 0.1126869E-08 0.0000000E+00 5 HCO3- 0.9377870E-03 0.9377870E-03 0.0000000E+00 0.0000000E+00 6 HS- 0.2902143E-03 0.2902154E-03 -.1126869E-08 0.0000000E+00 7 Al+++ 0.4775352E-05 0.2464117E-05 0.2311235E-05 0.0000000E+00 8 H4SiO4 0.1215302E-01 0.1214607E-01 0.6946884E-05 0.0000000E+00 9 Ca++ 0.2080835E-06 0.1942165E-06 0.1386698E-07 0.0000000E+00 10 Mg++ 0.8368328E-10 0.8368328E-10 0.0000000E+00 0.0000000E+00 11 Fe++ 0.3259227E-07 0.2357180E-07 0.9020467E-08 0.0000000E+00 12 K+ 0.1412294E-03 0.1412294E-03 0.5516598E-12 0.0000000E+00 13 Na+ 0.2003215E-01 0.2002984E-01 0.2311003E-05 0.0000000E+00 14 Mn++ 0.2251939E-08 0.2251939E-08 0.0000000E+00 0.0000000E+00 15 F- 0.5216000E-05 0.5216000E-05 0.0000000E+00 0.0000000E+00 16 HPO4-- 0.4168819E-07 0.4168819E-07 0.0000000E+00 0.0000000E+00 Chg. balance for solid moles: -.2118E-20 Mass of aqueous solution: 0.899880E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 0.0127900 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 0.2311E-05 -5.636 0.6060E-03 -3.218 99.61 0.2326E-03 andradite 0.4507E-08 -8.346 0.2291E-05 -5.640 0.3765 0.5951E-06 grossular 0.1149E-09 -9.940 0.5173E-07 -7.286 0.8504E-02 0.1439E-07 stilpnomelane-Fe 0.1103E-11 -11.957 0.1189E-08 -8.925 0.1955E-03 0.4108E-09 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.9752E+00 0.9752E+00 1.0000 -0.011 grossular 0.2485E-01 0.2485E-01 1.0000 -1.605 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 0.000608 g Volume = 0.000233 cm3 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.0127900 moles log = -1.8931 Original solution: 1000.0103000 g Original solution / Rock added: 78186.89 (Water/Rock Ratio), log = 4.8931 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0206 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9997E+00 0.9859 0.1006E+01 0.1020E+01 CO2,gas 0.7266E-05 1.0071 0.7469E-05 0.7416E-05 CH4,gas 0.4898E-05 1.0125 0.5062E-05 0.4999E-05 H2,gas 0.2811E-03 1.0005 0.2870E-03 0.2869E-03 H2S,gas 0.2117E-05 0.9960 0.2152E-05 0.2160E-05 S2,gas 0.2067E-23 1.0000 0.2109E-23 0.2109E-23 CO,gas 0.5598E-12 1.0000 0.5713E-12 0.5713E-12 SO3,gas 0.8658E-40 1.0000 0.8836E-40 0.8836E-40 SO2,gas 0.9668E-21 1.0000 0.9868E-21 0.9868E-21 HF,gas 0.7458E-14 1.0000 0.7612E-14 0.7612E-14 HCl,gas 0.5873E-17 1.0000 0.5994E-17 0.5994E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 17 albite -0.38 -0.38 0.00 0.000 -0.94784E-12 23 andradite 39.01 39.01 0.00 0.000 0.12132E-10 24 grossular 32.73 32.73 0.00 0.000 -0.12132E-10 167 stilpnomelane-Fe 13.02 13.02 0.00 0.000 0.21232E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -13.49 -6.83 -2.275 0.11655E+05 -5.127 3 CH4,gas 4.54 -2.45 -6.99 -1.749 0.11943E+05 -5.296 4 H2,gas 8.00 2.76 -5.24 -2.995 0.89489E+04 -3.542 5 H2S,gas -6.23 -13.60 -7.37 -3.683 0.12578E+05 -5.667 6 S2,gas -7.34 -32.71 -25.37 -3.904 0.43327E+05 -23.676 7 CO,gas 3.21 -10.73 -13.94 -4.290 0.23806E+05 -12.243 8 SO3,gas 17.12 -24.63 -41.75 -10.438 0.71292E+05 -40.054 9 SO2,gas 0.83 -21.87 -22.70 -6.055 0.38768E+05 -21.006 10 HF,gas 0.47 -15.34 -15.82 -7.909 0.27008E+05 -14.119 11 HCl,gas 5.19 -13.73 -18.92 -9.461 0.32308E+05 -17.222 12 acmite 7.71 7.41 -0.30 -0.031 0.51196E+03 16 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 20 spessartine 24.46 19.60 -4.86 -0.243 0.83020E+04 21 analcite 3.32 2.68 -0.64 -0.072 0.11004E+04 27 annite 20.12 17.51 -2.61 -0.145 0.44630E+04 28 phlogopite 27.06 24.82 -2.24 -0.125 0.38312E+04 33 apatite-OH -18.15 -20.39 -2.23 -0.172 0.38125E+04 34 apatite-F -34.30 -35.73 -1.43 -0.119 0.24406E+04 38 aragonite 0.97 -0.95 -1.92 -0.640 0.32778E+04 39 brucite 12.57 9.10 -3.47 -0.693 0.59178E+04 40 calcite 0.81 -0.95 -1.76 -0.588 0.30135E+04 41 carnegieite-low 9.02 5.74 -3.28 -0.469 0.56084E+04 42 carnegieite-high 10.09 5.74 -4.35 -0.622 0.74353E+04 43 carpholite-Mg 8.58 4.09 -4.49 -0.300 0.76738E+04 45 celadonite 5.34 3.55 -1.79 -0.105 0.30522E+04 46 celadonite-Fe 3.88 1.12 -2.76 -0.162 0.47119E+04 47 chrysotile 23.89 21.19 -2.71 -0.226 0.46217E+04 49 clinochlore 39.07 37.44 -1.63 -0.051 0.27867E+04 50 daphnite 28.97 25.25 -3.71 -0.116 0.63401E+04 52 chlorite-Al-free 47.17 42.37 -4.80 -0.200 0.81986E+04 54 chloritoid-Fe 9.17 4.71 -4.46 -0.297 0.76180E+04 55 chloritoid-Mn 11.40 7.27 -4.13 -0.275 0.70534E+04 57 coesite -2.38 -3.06 -0.69 -0.228 0.11700E+04 64 cristobalite -2.56 -3.06 -0.50 -0.167 0.85535E+03 66 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71249E+04 68 diaspore 2.87 0.55 -2.32 -0.387 0.39611E+04 69 diamond -3.10 -7.97 -4.87 -1.390 0.83086E+04 70 diopside 16.18 15.51 -0.67 -0.067 0.11414E+04 71 hedenbergite 14.21 13.08 -1.13 -0.113 0.19337E+04 78 epidote 24.67 22.28 -2.39 -0.116 0.40883E+04 80 epidote-Fe 29.84 27.01 -2.83 -0.147 0.48369E+04 81 fayalite 14.05 10.27 -3.78 -0.539 0.64469E+04 82 ferrosilite 11.15 7.21 -3.94 -0.394 0.67287E+04 86 gibbsite 4.08 0.55 -3.53 -0.504 0.60196E+04 87 glaucophane 22.97 20.42 -2.56 -0.069 0.43659E+04 88 glaucophane-Fe 17.28 13.11 -4.17 -0.113 0.71187E+04 89 graphite -3.55 -7.97 -4.42 -1.263 0.75508E+04 90 greenalite 16.14 13.87 -2.27 -0.189 0.38676E+04 93 hematite 12.57 10.57 -1.99 -0.242 0.34040E+04 94 heulandite -5.83 -7.79 -1.96 -0.089 0.33490E+04 98 jadeite 4.22 2.68 -1.54 -0.154 0.26259E+04 99 julgoldite 70.43 66.24 -4.19 -0.109 0.71496E+04 100 kalsilite 7.58 3.64 -3.95 -0.564 0.67424E+04 101 kaolinite -1.33 -5.01 -3.68 -0.335 0.62871E+04 104 laumontite 2.88 1.40 -1.49 -0.099 0.25410E+04 105 lawsonite 9.62 7.52 -2.10 -0.140 0.35827E+04 106 leucite 4.12 0.57 -3.54 -0.354 0.60529E+04 108 lizardite 23.24 21.19 -2.06 -0.172 0.35144E+04 110 magnetite 20.09 17.24 -2.85 -0.233 0.48649E+04 111 minnesotaite 10.39 7.75 -2.64 -0.155 0.45014E+04 115 manganosite 14.06 9.22 -4.83 -1.209 0.82545E+04 119 microcline -2.49 -2.49 0.00 0.000 0.15418E+01 123 muscovite 2.58 -1.38 -3.96 -0.233 0.67653E+04 124 paragonite 4.24 0.72 -3.52 -0.207 0.60028E+04 125 nepheline 8.34 5.74 -2.60 -0.372 0.44407E+04 131 periclase-Fe 11.63 6.67 -4.96 -1.240 0.84707E+04 137 phlogopite-Na 29.65 26.92 -2.72 -0.151 0.46485E+04 139 prehnite 19.37 16.99 -2.38 -0.140 0.40683E+04 140 prehnite-Fe 22.50 21.72 -0.78 -0.047 0.13253E+04 145 pyrite -21.25 -23.29 -2.04 -0.480 0.34816E+04 146 pyrrhotite -4.26 -6.93 -2.67 -0.890 0.45598E+04 147 pyrrhotiteFe0.875 -6.02 -8.11 -2.09 -0.768 0.35672E+04 148 pyroxmangite 7.40 6.16 -1.24 -0.247 0.21107E+04 149 pyrophyllite -6.18 -11.14 -4.96 -0.310 0.84719E+04 150 quartz -2.99 -3.06 -0.07 -0.024 0.12268E+03 154 rhodochrosite -0.98 -4.26 -3.29 -1.095 0.56103E+04 155 rhodonite 7.45 6.16 -1.28 -0.257 0.21910E+04 156 sanidine -1.28 -2.49 -1.21 -0.093 0.20693E+04 158 siderite -2.61 -6.82 -4.21 -1.404 0.71920E+04 166 stilbite -7.52 -7.79 -0.27 -0.013 0.45513E+03 168 stilpnomelane-Mg 27.44 25.20 -2.24 -0.067 0.38231E+04 174 talc 16.49 15.06 -1.43 -0.084 0.24383E+04 177 tephroite 18.09 15.39 -2.70 -0.386 0.46093E+04 181 tridymite -2.63 -3.06 -0.43 -0.145 0.74266E+03 182 tremolite 47.87 46.09 -1.78 -0.048 0.30401E+04 183 ferroactinolite 38.45 33.90 -4.55 -0.123 0.77672E+04 184 troilite-low -4.41 -6.93 -2.52 -0.840 0.43026E+04 190 wairakite 3.95 1.40 -2.56 -0.150 0.43630E+04 191 walstromite 11.51 9.47 -2.04 -0.408 0.34795E+04 192 wollastonite 10.46 9.47 -0.99 -0.198 0.16899E+04 193 pseudo-wollastonite 11.00 9.47 -1.53 -0.306 0.26097E+04 195 akaganeite 7.75 5.29 -2.47 -0.534 0.42145E+04 202 chalcedony -2.80 -3.06 -0.26 -0.086 0.44198E+03 204 montmorillonite-Ca -2.29 -6.25 -3.96 -0.245 0.67577E+04 205 montmorillonite-K -2.24 -6.29 -4.05 -0.248 0.69196E+04 206 montmorillonite-Mg -2.48 -6.81 -4.33 -0.268 0.74011E+04 207 montmorillonite-Na -2.04 -5.60 -3.56 -0.218 0.60740E+04 208 nontronite-Ca 3.21 1.59 -1.63 -0.105 0.27767E+04 209 nontronite-H 2.53 -0.48 -3.01 -0.202 0.51434E+04 210 nontronite-K 3.34 1.55 -1.79 -0.115 0.30618E+04 211 nontronite-Mg 3.07 1.02 -2.05 -0.133 0.35041E+04 212 nontronite-Na 3.52 2.24 -1.28 -0.082 0.21822E+04 228 tobermorite 9.82 7.38 -2.44 -0.667 0.41741E+04 234 alabandite -0.98 -4.37 -3.39 -1.132 0.57965E+04 237 boehmite 4.41 0.55 -3.85 -0.642 0.65780E+04 239 ferrous-oxide 9.81 6.67 -3.15 -0.786 0.53716E+04 245 silica-amorphous -2.09 -3.06 -0.97 -0.323 0.16562E+04 247 an20ab80 2.02 1.20 -0.82 -0.063 0.14024E+04 248 an25ab75 2.65 1.59 -1.05 -0.081 0.17999E+04 249 an30ab70 3.28 1.99 -1.29 -0.099 0.22071E+04 250 tr.625ac.25prg.125 45.16 43.91 -1.26 -0.034 0.21452E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 0.0004000 MOLES Current total amount of reactant added: 0.0127900 MOLES New total amount of reactant added: 0.0131900 MOLES Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.5508E-08 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 7 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 0.0131900 Water: Moles liquid = 0.4986E+02 kg liquid = 0.8983E+00 Moles total = 0.4986E+02 kg total = 0.8982E+00 Activity = 1.0000 Stoichiometric ionic strength = .1217530E-01 Osmotic coef. = 0.9440 True ionic strength = .2076683E-01 Chg. balance for total moles = -.5508E-08 Max. difference allowed = 0.2157E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.11314E-09 -9.9464 0.94854E-10 -10.0229 0.83835E+00 -0.0766 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.23904E-03 -3.6215 0.19916E-03 -3.7008 0.83316E+00 -0.0793 4 SO4-- 0.53422E-04 -4.2723 0.27477E-04 -4.5610 0.51434E+00 -0.2887 5 HCO3- 0.43088E-03 -3.3656 0.35953E-03 -3.4443 0.83442E+00 -0.0786 6 HS- 0.33163E-03 -3.4793 0.27635E-03 -3.5585 0.83329E+00 -0.0792 7 Al+++ 0.13327E-28 -28.8753 0.30119E-29 -29.5212 0.22600E+00 -0.6459 8 H4SiO4 0.87483E-03 -3.0581 0.87483E-03 -3.0581 0.10000E+01 0.0000 9 Ca++ 0.59773E-07 -7.2235 0.30511E-07 -7.5155 0.51046E+00 -0.2920 10 Mg++ 0.22109E-10 -10.6554 0.11233E-10 -10.9495 0.50805E+00 -0.2941 11 Fe++ 0.81479E-13 -13.0890 0.41443E-13 -13.3826 0.50863E+00 -0.2936 12 K+ 0.15657E-03 -3.8053 0.13067E-03 -3.8838 0.83462E+00 -0.0785 13 Na+ 0.19911E-01 -1.7009 0.16586E-01 -1.7802 0.83301E+00 -0.0794 14 Mn++ 0.29545E-10 -10.5295 0.15040E-10 -10.8227 0.50906E+00 -0.2932 15 F- 0.59655E-05 -5.2244 0.49597E-05 -5.3045 0.83140E+00 -0.0802 16 HPO4-- 0.45513E-07 -7.3419 0.23413E-07 -7.6306 0.51442E+00 -0.2887 18 HSiO3- 0.10336E-01 -1.9856 0.86118E-02 -2.0649 0.83316E+00 -0.0793 19 Ca(HSiO3)+ 0.71681E-08 -8.1446 0.59840E-08 -8.2230 0.83480E+00 -0.0784 20 Mg(HSiO3)+ 0.32842E-11 -11.4836 0.27417E-11 -11.5620 0.83480E+00 -0.0784 21 NaHSiO3,aq 0.23102E-02 -2.6363 0.23102E-02 -2.6363 0.10000E+01 0.0000 22 AlO+ 0.54553E-16 -16.2632 0.45541E-16 -16.3416 0.83480E+00 -0.0784 24 HAlO2,aq 0.95614E-10 -10.0195 0.95614E-10 -10.0195 0.10000E+01 0.0000 25 AlO2- 0.26831E-05 -5.5714 0.22313E-05 -5.6514 0.83162E+00 -0.0801 26 CH4,aq 0.35255E-08 -8.4528 0.35124E-08 -8.4544 0.99629E+00 -0.0016 31 CO,aq 0.39804E-15 -15.4001 0.39804E-15 -15.4001 0.10000E+01 0.0000 32 CO2,aq 0.73142E-07 -7.1358 0.72870E-07 -7.1374 0.99629E+00 -0.0016 33 CO3-2 0.64509E-03 -3.1904 0.33108E-03 -3.4801 0.51322E+00 -0.2897 34 CaCO3,aq 0.12666E-06 -6.8974 0.12666E-06 -6.8974 0.10000E+01 0.0000 35 Ca(HCO3)+ 0.33543E-09 -9.4744 0.28002E-09 -9.5528 0.83480E+00 -0.0784 36 CaCl+ 0.11780E-10 -10.9289 0.98338E-11 -11.0073 0.83480E+00 -0.0784 37 CaCl2,aq 0.46529E-15 -15.3323 0.46529E-15 -15.3323 0.10000E+01 0.0000 38 CaF+ 0.26466E-11 -11.5773 0.22094E-11 -11.6557 0.83480E+00 -0.0784 39 CaOH+ 0.27462E-07 -7.5613 0.22925E-07 -7.6397 0.83480E+00 -0.0784 40 CaSO4,aq 0.26622E-09 -9.5748 0.26622E-09 -9.5748 0.10000E+01 0.0000 41 HCl,aq 0.34616E-14 -14.4607 0.34616E-14 -14.4607 0.10000E+01 0.0000 45 HF,aq 0.32205E-11 -11.4921 0.32205E-11 -11.4921 0.10000E+01 0.0000 46 HF2- 0.64728E-17 -17.1889 0.53929E-17 -17.2682 0.83316E+00 -0.0793 48 FeCl+ 0.15649E-16 -16.8055 0.13064E-16 -16.8839 0.83480E+00 -0.0784 51 FeF+ 0.12582E-16 -16.9002 0.10504E-16 -16.9787 0.83480E+00 -0.0784 53 FeO,aq 0.17902E-09 -9.7471 0.17902E-09 -9.7471 0.10000E+01 0.0000 54 FeOH+ 0.17036E-10 -10.7686 0.14222E-10 -10.8470 0.83480E+00 -0.0784 55 HFeO2- 0.23702E-07 -7.6252 0.19747E-07 -7.7045 0.83316E+00 -0.0793 56 FeO+ 0.87142E-16 -16.0598 0.72747E-16 -16.1382 0.83480E+00 -0.0784 58 FeO2- 0.19857E-08 -8.7021 0.16544E-08 -8.7813 0.83316E+00 -0.0793 59 HFeO2,aq 0.19959E-10 -10.6999 0.19959E-10 -10.6999 0.10000E+01 0.0000 60 H2,aq 0.21825E-06 -6.6610 0.21744E-06 -6.6627 0.99629E+00 -0.0016 61 KCl,aq 0.47167E-09 -9.3264 0.47167E-09 -9.3264 0.10000E+01 0.0000 62 KHSO4,aq 0.96295E-18 -18.0164 0.96295E-18 -18.0164 0.10000E+01 0.0000 63 KOH,aq 0.58832E-06 -6.2304 0.58832E-06 -6.2304 0.10000E+01 0.0000 64 KSO4- 0.66874E-07 -7.1747 0.55717E-07 -7.2540 0.83316E+00 -0.0793 65 MgCO3,aq 0.11688E-10 -10.9322 0.11688E-10 -10.9322 0.10000E+01 0.0000 66 Mg(HCO3)+ 0.12618E-12 -12.8990 0.10534E-12 -12.9774 0.83480E+00 -0.0784 67 MgCl+ 0.39305E-14 -14.4055 0.32812E-14 -14.4840 0.83480E+00 -0.0784 68 MgF+ 0.36093E-14 -14.4426 0.30131E-14 -14.5210 0.83480E+00 -0.0784 69 MgOH+ 0.55944E-10 -10.2522 0.46702E-10 -10.3307 0.83480E+00 -0.0784 71 MnF+ 0.15051E-14 -14.8224 0.12565E-14 -14.9008 0.83480E+00 -0.0784 72 MnO,aq 0.17312E-08 -8.7617 0.17312E-08 -8.7617 0.10000E+01 0.0000 73 MnOH+ 0.57436E-09 -9.2408 0.47948E-09 -9.3192 0.83480E+00 -0.0784 74 MnO2-2 0.12442E-10 -10.9051 0.63856E-11 -11.1948 0.51322E+00 -0.2897 75 HMnO2- 0.15927E-09 -9.7979 0.13270E-09 -9.8771 0.83316E+00 -0.0793 78 MnCl+ 0.22096E-13 -13.6557 0.18445E-13 -13.7341 0.83480E+00 -0.0784 79 MnSO4,aq 0.11931E-12 -12.9233 0.11931E-12 -12.9233 0.10000E+01 0.0000 80 NaCl,aq 0.10947E-05 -5.9607 0.10947E-05 -5.9607 0.10000E+01 0.0000 81 NaF,aq 0.19259E-07 -7.7154 0.19259E-07 -7.7154 0.10000E+01 0.0000 82 NaOH,aq 0.75129E-04 -4.1242 0.75129E-04 -4.1242 0.10000E+01 0.0000 84 OH- 0.73245E-02 -2.1352 0.60912E-02 -2.2153 0.83162E+00 -0.0801 89 HPO3-2 0.30912E-16 -16.5099 0.15865E-16 -16.7996 0.51322E+00 -0.2897 92 H3PO4,aq 0.14733E-17 -17.8317 0.14733E-17 -17.8317 0.10000E+01 0.0000 93 H2PO4- 0.49123E-10 -10.3087 0.40967E-10 -10.3876 0.83397E+00 -0.0788 94 PO4-3 0.84721E-09 -9.0720 0.20138E-09 -9.6960 0.23770E+00 -0.6240 98 HP2O7-3 0.12245E-17 -17.9120 0.27702E-18 -18.5575 0.22623E+00 -0.6454 99 P2O7-4 0.94021E-17 -17.0268 0.69771E-18 -18.1563 0.74207E-01 -1.1296 100 H2S,aq 0.81315E-07 -7.0898 0.81013E-07 -7.0914 0.99629E+00 -0.0016 101 S2-2 0.15163E-10 -10.8192 0.77822E-11 -11.1089 0.51322E+00 -0.2897 102 S3-2 0.76114E-17 -17.1185 0.39063E-17 -17.4082 0.51322E+00 -0.2897 107 SO3-2 0.14906E-11 -11.8266 0.77641E-12 -12.1099 0.52086E+00 -0.2833 108 HSO3- 0.55345E-14 -14.2569 0.46111E-14 -14.3362 0.83316E+00 -0.0793 109 HSO4- 0.30058E-11 -11.5220 0.25118E-11 -11.6000 0.83564E+00 -0.0780 111 S2O3-2 0.50950E-13 -13.2929 0.26149E-13 -13.5825 0.51322E+00 -0.2897 Charge balance for all species = -.6131E-08 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.1131436E-09 -.2070270E-01 -.2082977E+02 0.0000 2 H2O 0.1000000E+01 0.5550301E+02 0.9981154E+06 0.0000 3 Cl- 0.2390363E-03 0.2401315E-03 0.8498158E+01 6.3221 4 SO4-- 0.5342223E-04 0.5343154E-04 0.5123542E+01 15.4849 5 HCO3- 0.4308797E-03 0.1076176E-02 0.6554784E+02 6.5787 6 HS- 0.3316340E-03 0.3317731E-03 0.1095278E+02 6.4644 7 Al+++ 0.1332706E-28 0.2683221E-05 0.7226786E-01 0.5477 8 H4SiO4 0.8748266E-03 0.1352131E-01 0.1297282E+04 -3.0581 9 Ca++ 0.5977280E-07 0.2216815E-06 0.8868663E-02 12.5304 10 Mg++ 0.2210946E-10 0.9315951E-10 0.2260844E-05 9.0964 11 Fe++ 0.8147944E-13 0.2590347E-07 0.1444044E-02 6.6633 12 K+ 0.1565660E-03 0.1572217E-03 0.6136691E+01 6.1391 13 Na+ 0.1991149E-01 0.2229794E-01 0.5117086E+03 8.2427 14 Mn++ 0.2954547E-10 0.2506947E-08 0.1374804E-03 9.2232 15 F- 0.5965509E-05 0.5984774E-05 0.1134954E+00 4.7184 16 HPO4-- 0.4551259E-07 0.4640893E-07 0.4446318E-02 12.4153 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.1860631E-01 -.1859681E-01 -.9494905E-05 0.0000000E+00 2 H2O 0.4985721E+02 0.4985722E+02 -.9458051E-05 0.0000000E+00 3 Cl- 0.2157052E-03 0.2157052E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.4799719E-04 0.4799646E-04 0.7276373E-09 0.0000000E+00 5 HCO3- 0.9667070E-03 0.9667070E-03 0.0000000E+00 0.0000000E+00 6 HS- 0.2980243E-03 0.2980250E-03 -.7276373E-09 0.0000000E+00 7 Al+++ 0.4775352E-05 0.2410282E-05 0.2365070E-05 0.0000000E+00 8 H4SiO4 0.1215302E-01 0.1214591E-01 0.7105123E-05 0.0000000E+00 9 Ca++ 0.2080835E-06 0.1991319E-06 0.8951569E-08 0.0000000E+00 10 Mg++ 0.8368328E-10 0.8368328E-10 0.0000000E+00 0.0000000E+00 11 Fe++ 0.3259227E-07 0.2326855E-07 0.9323717E-08 0.0000000E+00 12 K+ 0.1412294E-03 0.1412290E-03 0.3502619E-09 0.0000000E+00 13 Na+ 0.2003215E-01 0.2002979E-01 0.2363522E-05 0.0000000E+00 14 Mn++ 0.2251939E-08 0.2251939E-08 0.0000000E+00 0.0000000E+00 15 F- 0.5376000E-05 0.5376000E-05 0.0000000E+00 0.0000000E+00 16 HPO4-- 0.4168819E-07 0.4168819E-07 0.0000000E+00 0.0000000E+00 Chg. balance for solid moles: 0.4235E-21 Mass of aqueous solution: 0.899889E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 0.0131900 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 0.2364E-05 -5.626 0.6198E-03 -3.208 99.64 0.2379E-03 andradite 0.2911E-08 -8.536 0.1479E-05 -5.830 0.2378 0.3843E-06 grossular 0.7331E-10 -10.135 0.3302E-07 -7.481 0.5309E-02 0.9188E-08 stilpnomelane-Fe 0.7005E-09 -9.155 0.7552E-06 -6.122 0.1214 0.2608E-06 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.9754E+00 0.9754E+00 1.0000 -0.011 grossular 0.2457E-01 0.2457E-01 1.0000 -1.610 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 0.000622 g Volume = 0.000239 cm3 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.0131900 moles log = -1.8798 Original solution: 1000.0103000 g Original solution / Rock added: 75815.79 (Water/Rock Ratio), log = 4.8798 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0206 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9997E+00 0.9859 0.1006E+01 0.1020E+01 CO2,gas 0.7585E-05 1.0071 0.7796E-05 0.7741E-05 CH4,gas 0.5003E-05 1.0125 0.5170E-05 0.5106E-05 H2,gas 0.2796E-03 1.0005 0.2855E-03 0.2853E-03 H2S,gas 0.2191E-05 0.9960 0.2227E-05 0.2236E-05 S2,gas 0.2238E-23 1.0000 0.2284E-23 0.2284E-23 CO,gas 0.5812E-12 1.0000 0.5932E-12 0.5932E-12 SO3,gas 0.9159E-40 1.0000 0.9348E-40 0.9348E-40 SO2,gas 0.1017E-20 1.0000 0.1038E-20 0.1038E-20 HF,gas 0.7748E-14 1.0000 0.7908E-14 0.7908E-14 HCl,gas 0.5985E-17 1.0000 0.6108E-17 0.6108E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 17 albite -0.38 -0.38 0.00 0.000 0.11184E-10 23 andradite 39.01 39.01 0.00 0.000 0.12132E-10 24 grossular 32.73 32.73 0.00 0.000 0.00000E+00 167 stilpnomelane-Fe 13.02 13.02 0.00 0.000 -0.27298E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -13.47 -6.81 -2.269 0.11623E+05 -5.108 3 CH4,gas 4.54 -2.44 -6.99 -1.746 0.11928E+05 -5.287 4 H2,gas 8.00 2.76 -5.24 -2.996 0.89530E+04 -3.544 5 H2S,gas -6.23 -13.58 -7.35 -3.676 0.12552E+05 -5.652 6 S2,gas -7.34 -32.68 -25.34 -3.898 0.43268E+05 -23.641 7 CO,gas 3.21 -10.71 -13.93 -4.285 0.23778E+05 -12.227 8 SO3,gas 17.12 -24.61 -41.73 -10.432 0.71250E+05 -40.029 9 SO2,gas 0.83 -21.85 -22.68 -6.049 0.38730E+05 -20.984 10 HF,gas 0.47 -15.33 -15.80 -7.900 0.26980E+05 -14.102 11 HCl,gas 5.19 -13.72 -18.91 -9.457 0.32294E+05 -17.214 12 acmite 7.71 7.41 -0.30 -0.031 0.50885E+03 16 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 20 spessartine 24.46 19.59 -4.87 -0.243 0.83099E+04 21 analcite 3.32 2.67 -0.65 -0.072 0.11058E+04 27 annite 20.12 17.50 -2.62 -0.146 0.44750E+04 28 phlogopite 27.06 24.80 -2.26 -0.126 0.38638E+04 33 apatite-OH -18.15 -20.38 -2.22 -0.171 0.37975E+04 34 apatite-F -34.30 -35.71 -1.40 -0.117 0.23974E+04 38 aragonite 0.97 -0.94 -1.90 -0.634 0.32500E+04 39 brucite 12.57 9.10 -3.47 -0.694 0.59287E+04 40 calcite 0.81 -0.94 -1.75 -0.583 0.29857E+04 41 carnegieite-low 9.02 5.73 -3.29 -0.470 0.56193E+04 42 carnegieite-high 10.09 5.73 -4.36 -0.623 0.74463E+04 43 carpholite-Mg 8.58 4.08 -4.51 -0.300 0.76948E+04 45 celadonite 5.34 3.55 -1.79 -0.105 0.30576E+04 46 celadonite-Fe 3.88 1.12 -2.76 -0.162 0.47104E+04 47 chrysotile 23.89 21.17 -2.72 -0.227 0.46433E+04 49 clinochlore 39.07 37.40 -1.67 -0.052 0.28455E+04 50 daphnite 28.97 25.24 -3.73 -0.116 0.63645E+04 52 chlorite-Al-free 47.17 42.35 -4.83 -0.201 0.82418E+04 54 chloritoid-Fe 9.17 4.70 -4.47 -0.298 0.76376E+04 55 chloritoid-Mn 11.40 7.26 -4.14 -0.276 0.70701E+04 57 coesite -2.38 -3.06 -0.68 -0.227 0.11645E+04 64 cristobalite -2.56 -3.06 -0.50 -0.166 0.84988E+03 66 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71250E+04 68 diaspore 2.87 0.55 -2.33 -0.388 0.39716E+04 69 diamond -3.10 -7.95 -4.85 -1.386 0.82848E+04 70 diopside 16.18 15.51 -0.67 -0.067 0.11453E+04 71 hedenbergite 14.21 13.08 -1.13 -0.113 0.19307E+04 78 epidote 24.67 22.27 -2.40 -0.117 0.41030E+04 80 epidote-Fe 29.84 27.00 -2.84 -0.147 0.48430E+04 81 fayalite 14.05 10.27 -3.78 -0.540 0.64494E+04 82 ferrosilite 11.15 7.21 -3.94 -0.394 0.67256E+04 86 gibbsite 4.08 0.55 -3.53 -0.505 0.60302E+04 87 glaucophane 22.97 20.41 -2.57 -0.069 0.43875E+04 88 glaucophane-Fe 17.28 13.11 -4.17 -0.113 0.71196E+04 89 graphite -3.55 -7.95 -4.41 -1.260 0.75271E+04 90 greenalite 16.14 13.87 -2.27 -0.189 0.38685E+04 93 hematite 12.57 10.57 -2.00 -0.242 0.34079E+04 94 heulandite -5.83 -7.78 -1.95 -0.089 0.33357E+04 98 jadeite 4.22 2.67 -1.54 -0.154 0.26313E+04 99 julgoldite 70.43 66.24 -4.19 -0.109 0.71486E+04 100 kalsilite 7.58 3.63 -3.96 -0.565 0.67534E+04 101 kaolinite -1.33 -5.02 -3.69 -0.335 0.62972E+04 104 laumontite 2.88 1.39 -1.49 -0.099 0.25442E+04 105 lawsonite 9.62 7.51 -2.11 -0.140 0.35968E+04 106 leucite 4.12 0.57 -3.55 -0.355 0.60585E+04 108 lizardite 23.24 21.17 -2.07 -0.173 0.35359E+04 110 magnetite 20.09 17.23 -2.85 -0.233 0.48727E+04 111 minnesotaite 10.39 7.76 -2.63 -0.155 0.44913E+04 115 manganosite 14.06 9.22 -4.83 -1.209 0.82556E+04 119 microcline -2.49 -2.49 0.00 0.000 0.16010E+01 123 muscovite 2.58 -1.39 -3.97 -0.234 0.67864E+04 124 paragonite 4.24 0.71 -3.53 -0.208 0.60239E+04 125 nepheline 8.34 5.73 -2.61 -0.372 0.44517E+04 131 periclase-Fe 11.63 6.66 -4.96 -1.241 0.84746E+04 137 phlogopite-Na 29.65 26.91 -2.74 -0.152 0.46810E+04 139 prehnite 19.37 16.98 -2.39 -0.141 0.40810E+04 140 prehnite-Fe 22.50 21.72 -0.78 -0.047 0.13294E+04 145 pyrite -21.25 -23.26 -2.01 -0.473 0.34304E+04 146 pyrrhotite -4.26 -6.92 -2.66 -0.886 0.45382E+04 147 pyrrhotiteFe0.875 -6.02 -8.09 -2.08 -0.763 0.35446E+04 148 pyroxmangite 7.40 6.17 -1.23 -0.247 0.21063E+04 149 pyrophyllite -6.18 -11.14 -4.96 -0.310 0.84711E+04 150 quartz -2.99 -3.06 -0.07 -0.023 0.11721E+03 154 rhodochrosite -0.98 -4.24 -3.27 -1.089 0.55796E+04 155 rhodonite 7.45 6.17 -1.28 -0.256 0.21866E+04 156 sanidine -1.28 -2.49 -1.21 -0.093 0.20694E+04 158 siderite -2.61 -6.80 -4.20 -1.399 0.71641E+04 166 stilbite -7.52 -7.78 -0.26 -0.012 0.44189E+03 168 stilpnomelane-Mg 27.44 25.18 -2.26 -0.067 0.38576E+04 174 talc 16.49 15.06 -1.43 -0.084 0.24489E+04 177 tephroite 18.09 15.39 -2.70 -0.385 0.46060E+04 181 tridymite -2.63 -3.06 -0.43 -0.144 0.73718E+03 182 tremolite 47.87 46.08 -1.79 -0.048 0.30586E+04 183 ferroactinolite 38.45 33.91 -4.54 -0.123 0.77512E+04 184 troilite-low -4.41 -6.92 -2.51 -0.836 0.42810E+04 190 wairakite 3.95 1.39 -2.56 -0.150 0.43661E+04 191 walstromite 11.51 9.47 -2.04 -0.407 0.34780E+04 192 wollastonite 10.46 9.47 -0.99 -0.198 0.16885E+04 193 pseudo-wollastonite 11.00 9.47 -1.53 -0.306 0.26083E+04 195 akaganeite 7.75 5.29 -2.47 -0.534 0.42165E+04 202 chalcedony -2.80 -3.06 -0.26 -0.085 0.43650E+03 204 montmorillonite-Ca -2.29 -6.25 -3.96 -0.245 0.67576E+04 205 montmorillonite-K -2.24 -6.29 -4.05 -0.248 0.69208E+04 206 montmorillonite-Mg -2.48 -6.81 -4.34 -0.268 0.74021E+04 207 montmorillonite-Na -2.04 -5.60 -3.56 -0.218 0.60752E+04 208 nontronite-Ca 3.21 1.60 -1.62 -0.105 0.27646E+04 209 nontronite-H 2.53 -0.47 -3.00 -0.201 0.51306E+04 210 nontronite-K 3.34 1.55 -1.79 -0.115 0.30511E+04 211 nontronite-Mg 3.07 1.03 -2.05 -0.133 0.34932E+04 212 nontronite-Na 3.52 2.25 -1.27 -0.082 0.21714E+04 228 tobermorite 9.82 7.38 -2.44 -0.667 0.41719E+04 234 alabandite -0.98 -4.36 -3.38 -1.127 0.57721E+04 237 boehmite 4.41 0.55 -3.86 -0.643 0.65885E+04 239 ferrous-oxide 9.81 6.66 -3.15 -0.787 0.53755E+04 245 silica-amorphous -2.09 -3.06 -0.97 -0.322 0.16507E+04 247 an20ab80 2.02 1.19 -0.82 -0.063 0.14052E+04 248 an25ab75 2.65 1.59 -1.06 -0.081 0.18035E+04 249 an30ab70 3.28 1.98 -1.30 -0.100 0.22113E+04 250 tr.625ac.25prg.125 45.16 43.90 -1.26 -0.034 0.21598E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 0.0004000 MOLES Current total amount of reactant added: 0.0131900 MOLES New total amount of reactant added: 0.0135900 MOLES Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.5508E-08 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 7 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 0.0135900 Water: Moles liquid = 0.4986E+02 kg liquid = 0.8983E+00 Moles total = 0.4986E+02 kg total = 0.8982E+00 Activity = 1.0000 Stoichiometric ionic strength = .1220104E-01 Osmotic coef. = 0.9437 True ionic strength = .2078787E-01 Chg. balance for total moles = -.5508E-08 Max. difference allowed = 0.2181E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.11406E-09 -9.9429 0.95617E-10 -10.0195 0.83830E+00 -0.0766 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.24165E-03 -3.6168 0.20132E-03 -3.6961 0.83311E+00 -0.0793 4 SO4-- 0.55546E-04 -4.2553 0.28562E-04 -4.5442 0.51421E+00 -0.2889 5 HCO3- 0.44584E-03 -3.3508 0.37200E-03 -3.4295 0.83436E+00 -0.0786 6 HS- 0.34032E-03 -3.4681 0.28357E-03 -3.5473 0.83323E+00 -0.0792 7 Al+++ 0.13466E-28 -28.8708 0.30414E-29 -29.5169 0.22586E+00 -0.6462 8 H4SiO4 0.88134E-03 -3.0549 0.88134E-03 -3.0549 0.10000E+01 0.0000 9 Ca++ 0.60427E-07 -7.2188 0.30837E-07 -7.5109 0.51032E+00 -0.2922 10 Mg++ 0.22145E-10 -10.6547 0.11248E-10 -10.9489 0.50791E+00 -0.2942 11 Fe++ 0.82375E-13 -13.0842 0.41887E-13 -13.3779 0.50849E+00 -0.2937 12 K+ 0.15657E-03 -3.8053 0.13066E-03 -3.8838 0.83456E+00 -0.0785 13 Na+ 0.19913E-01 -1.7009 0.16587E-01 -1.7802 0.83295E+00 -0.0794 14 Mn++ 0.29986E-10 -10.5231 0.15261E-10 -10.8164 0.50892E+00 -0.2933 15 F- 0.61430E-05 -5.2116 0.51069E-05 -5.2918 0.83134E+00 -0.0802 16 HPO4-- 0.45518E-07 -7.3418 0.23409E-07 -7.6306 0.51428E+00 -0.2888 18 HSiO3- 0.10331E-01 -1.9859 0.86067E-02 -2.0652 0.83311E+00 -0.0793 19 Ca(HSiO3)+ 0.72408E-08 -8.1402 0.60443E-08 -8.2187 0.83475E+00 -0.0784 20 Mg(HSiO3)+ 0.32869E-11 -11.4832 0.27437E-11 -11.5617 0.83475E+00 -0.0784 21 NaHSiO3,aq 0.23089E-02 -2.6366 0.23089E-02 -2.6366 0.10000E+01 0.0000 22 AlO+ 0.54217E-16 -16.2659 0.45258E-16 -16.3443 0.83475E+00 -0.0784 24 HAlO2,aq 0.94262E-10 -10.0257 0.94262E-10 -10.0257 0.10000E+01 0.0000 25 AlO2- 0.26243E-05 -5.5810 0.21822E-05 -5.6611 0.83156E+00 -0.0801 26 CH4,aq 0.36009E-08 -8.4436 0.35875E-08 -8.4452 0.99628E+00 -0.0016 27 C2H6,aq 0.10210E-19 -19.9910 0.10172E-19 -19.9926 0.99628E+00 -0.0016 31 CO,aq 0.41298E-15 -15.3841 0.41298E-15 -15.3841 0.10000E+01 0.0000 32 CO2,aq 0.76286E-07 -7.1176 0.76002E-07 -7.1192 0.99628E+00 -0.0016 33 CO3-2 0.66231E-03 -3.1789 0.33982E-03 -3.4688 0.51308E+00 -0.2898 34 CaCO3,aq 0.13140E-06 -6.8814 0.13140E-06 -6.8814 0.10000E+01 0.0000 35 Ca(HCO3)+ 0.35078E-09 -9.4550 0.29282E-09 -9.5334 0.83475E+00 -0.0784 36 CaCl+ 0.12036E-10 -10.9195 0.10047E-10 -10.9980 0.83475E+00 -0.0784 37 CaCl2,aq 0.48053E-15 -15.3183 0.48053E-15 -15.3183 0.10000E+01 0.0000 38 CaF+ 0.27544E-11 -11.5600 0.22993E-11 -11.6384 0.83475E+00 -0.0784 39 CaOH+ 0.27535E-07 -7.5601 0.22985E-07 -7.6386 0.83475E+00 -0.0784 40 CaSO4,aq 0.27969E-09 -9.5533 0.27969E-09 -9.5533 0.10000E+01 0.0000 41 HCl,aq 0.35274E-14 -14.4525 0.35274E-14 -14.4525 0.10000E+01 0.0000 45 HF,aq 0.33428E-11 -11.4759 0.33428E-11 -11.4759 0.10000E+01 0.0000 46 HF2- 0.69184E-17 -17.1600 0.57637E-17 -17.2393 0.83311E+00 -0.0793 48 FeCl+ 0.15990E-16 -16.7962 0.13347E-16 -16.8746 0.83475E+00 -0.0784 51 FeF+ 0.13095E-16 -16.8829 0.10931E-16 -16.9613 0.83475E+00 -0.0784 53 FeO,aq 0.17806E-09 -9.7494 0.17806E-09 -9.7494 0.10000E+01 0.0000 54 FeOH+ 0.17083E-10 -10.7674 0.14260E-10 -10.8459 0.83475E+00 -0.0784 55 HFeO2- 0.23389E-07 -7.6310 0.19485E-07 -7.7103 0.83311E+00 -0.0793 56 FeO+ 0.87608E-16 -16.0575 0.73131E-16 -16.1359 0.83475E+00 -0.0784 58 FeO2- 0.19646E-08 -8.7067 0.16368E-08 -8.7860 0.83311E+00 -0.0793 59 HFeO2,aq 0.19905E-10 -10.7010 0.19905E-10 -10.7010 0.10000E+01 0.0000 60 H2,aq 0.21711E-06 -6.6633 0.21631E-06 -6.6649 0.99628E+00 -0.0016 61 KCl,aq 0.47677E-09 -9.3217 0.47677E-09 -9.3217 0.10000E+01 0.0000 62 KHSO4,aq 0.10089E-17 -17.9961 0.10089E-17 -17.9961 0.10000E+01 0.0000 63 KOH,aq 0.58359E-06 -6.2339 0.58359E-06 -6.2339 0.10000E+01 0.0000 64 KSO4- 0.69514E-07 -7.1579 0.57912E-07 -7.2372 0.83311E+00 -0.0793 65 MgCO3,aq 0.12013E-10 -10.9203 0.12013E-10 -10.9203 0.10000E+01 0.0000 66 Mg(HCO3)+ 0.13074E-12 -12.8836 0.10913E-12 -12.9620 0.83475E+00 -0.0784 67 MgCl+ 0.39788E-14 -14.4002 0.33213E-14 -14.4787 0.83475E+00 -0.0784 68 MgF+ 0.37216E-14 -14.4293 0.31066E-14 -14.5077 0.83475E+00 -0.0784 69 MgOH+ 0.55575E-10 -10.2551 0.46391E-10 -10.3336 0.83475E+00 -0.0784 71 MnF+ 0.15726E-14 -14.8034 0.13127E-14 -14.8818 0.83475E+00 -0.0784 72 MnO,aq 0.17286E-08 -8.7623 0.17286E-08 -8.7623 0.10000E+01 0.0000 73 MnOH+ 0.57816E-09 -9.2380 0.48262E-09 -9.3164 0.83475E+00 -0.0784 74 MnO2-2 0.12230E-10 -10.9126 0.62749E-11 -11.2024 0.51308E+00 -0.2898 75 HMnO2- 0.15778E-09 -9.8020 0.13145E-09 -9.8813 0.83311E+00 -0.0793 78 MnCl+ 0.22664E-13 -13.6447 0.18919E-13 -13.7231 0.83475E+00 -0.0784 79 MnSO4,aq 0.12583E-12 -12.9002 0.12583E-12 -12.9002 0.10000E+01 0.0000 80 NaCl,aq 0.11066E-05 -5.9560 0.11066E-05 -5.9560 0.10000E+01 0.0000 81 NaF,aq 0.19831E-07 -7.7026 0.19831E-07 -7.7026 0.10000E+01 0.0000 82 NaOH,aq 0.74531E-04 -4.1277 0.74531E-04 -4.1277 0.10000E+01 0.0000 84 OH- 0.72666E-02 -2.1387 0.60426E-02 -2.2188 0.83156E+00 -0.0801 89 HPO3-2 0.30755E-16 -16.5121 0.15780E-16 -16.8019 0.51308E+00 -0.2898 92 H3PO4,aq 0.14968E-17 -17.8248 0.14968E-17 -17.8248 0.10000E+01 0.0000 93 H2PO4- 0.49514E-10 -10.3053 0.41291E-10 -10.3841 0.83392E+00 -0.0789 94 PO4-3 0.84082E-09 -9.0753 0.19975E-09 -9.6995 0.23757E+00 -0.6242 98 HP2O7-3 0.12348E-17 -17.9084 0.27917E-18 -18.5541 0.22609E+00 -0.6457 99 P2O7-4 0.94094E-17 -17.0264 0.69751E-18 -18.1565 0.74128E-01 -1.1300 100 H2S,aq 0.84111E-07 -7.0751 0.83798E-07 -7.0768 0.99628E+00 -0.0016 101 S2-2 0.16054E-10 -10.7944 0.82372E-11 -11.0842 0.51308E+00 -0.2898 102 S3-2 0.83793E-17 -17.0768 0.42993E-17 -17.3666 0.51308E+00 -0.2898 107 SO3-2 0.15418E-11 -11.8120 0.80284E-12 -12.0954 0.52073E+00 -0.2834 108 HSO3- 0.57693E-14 -14.2389 0.48064E-14 -14.3182 0.83311E+00 -0.0793 109 HSO4- 0.31498E-11 -11.5017 0.26319E-11 -11.5797 0.83559E+00 -0.0780 111 S2O3-2 0.54797E-13 -13.2612 0.28115E-13 -13.5511 0.51308E+00 -0.2898 Charge balance for all species = -.6131E-08 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.1140604E-09 -.2065437E-01 -.2078111E+02 0.0000 2 H2O 0.1000000E+01 0.5550296E+02 0.9981128E+06 0.0000 3 Cl- 0.2416498E-03 0.2427569E-03 0.8591057E+01 6.3234 4 SO4-- 0.5554570E-04 0.5555787E-04 0.5327426E+01 15.4947 5 HCO3- 0.4458443E-03 0.1108363E-02 0.6750815E+02 6.5900 6 HS- 0.3403227E-03 0.3404645E-03 0.1123969E+02 6.4721 7 Al+++ 0.1346621E-28 0.2624346E-05 0.7068206E-01 0.5415 8 H4SiO4 0.8813355E-03 0.1352103E-01 0.1297254E+04 -3.0549 9 Ca++ 0.6042720E-07 0.2272439E-06 0.9091179E-02 12.5280 10 Mg++ 0.2214510E-10 0.9315881E-10 0.2260823E-05 9.0900 11 Fe++ 0.8237546E-13 0.2556840E-07 0.1425363E-02 6.6610 12 K+ 0.1565666E-03 0.1572201E-03 0.6136619E+01 6.1356 13 Na+ 0.1991318E-01 0.2229772E-01 0.5117026E+03 8.2392 14 Mn++ 0.2998630E-10 0.2506928E-08 0.1374791E-03 9.2225 15 F- 0.6143009E-05 0.6162846E-05 0.1168722E+00 4.7276 16 HPO4-- 0.4551825E-07 0.4640858E-07 0.4446277E-02 12.4083 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.1856324E-01 -.1855354E-01 -.9696407E-05 0.0000000E+00 2 H2O 0.4985753E+02 0.4985754E+02 -.9663613E-05 0.0000000E+00 3 Cl- 0.2180652E-03 0.2180652E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.4990719E-04 0.4990687E-04 0.3214512E-09 0.0000000E+00 5 HCO3- 0.9956270E-03 0.9956270E-03 0.0000000E+00 0.0000000E+00 6 HS- 0.3058343E-03 0.3058346E-03 -.3214512E-09 0.0000000E+00 7 Al+++ 0.4775352E-05 0.2357414E-05 0.2417938E-05 0.0000000E+00 8 H4SiO4 0.1215302E-01 0.1214576E-01 0.7260397E-05 0.0000000E+00 9 Ca++ 0.2080835E-06 0.2041300E-06 0.3953458E-08 0.0000000E+00 10 Mg++ 0.8368328E-10 0.8368328E-10 0.0000000E+00 0.0000000E+00 11 Fe++ 0.3259227E-07 0.2296774E-07 0.9624529E-08 0.0000000E+00 12 K+ 0.1412294E-03 0.1412287E-03 0.7052920E-09 0.0000000E+00 13 Na+ 0.2003215E-01 0.2002973E-01 0.2415053E-05 0.0000000E+00 14 Mn++ 0.2251939E-08 0.2251939E-08 0.0000000E+00 0.0000000E+00 15 F- 0.5536000E-05 0.5536000E-05 0.0000000E+00 0.0000000E+00 16 HPO4-- 0.4168819E-07 0.4168819E-07 0.0000000E+00 0.0000000E+00 Chg. balance for solid moles: -.2541E-20 Mass of aqueous solution: 0.899897E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 0.0135900 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 0.2415E-05 -5.617 0.6333E-03 -3.198 99.66 0.2431E-03 andradite 0.1286E-08 -8.891 0.6534E-06 -6.185 0.1028 0.1698E-06 grossular 0.3201E-10 -10.495 0.1442E-07 -7.841 0.2269E-02 0.4013E-08 stilpnomelane-Fe 0.1411E-08 -8.851 0.1521E-05 -5.818 0.2393 0.5252E-06 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.9757E+00 0.9757E+00 1.0000 -0.011 grossular 0.2429E-01 0.2429E-01 1.0000 -1.615 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 0.000635 g Volume = 0.000244 cm3 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.0135900 moles log = -1.8668 Original solution: 1000.0103000 g Original solution / Rock added: 73584.28 (Water/Rock Ratio), log = 4.8668 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0206 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9997E+00 0.9859 0.1006E+01 0.1020E+01 CO2,gas 0.7911E-05 1.0071 0.8131E-05 0.8074E-05 CH4,gas 0.5110E-05 1.0125 0.5281E-05 0.5215E-05 H2,gas 0.2781E-03 1.0005 0.2840E-03 0.2838E-03 H2S,gas 0.2266E-05 0.9960 0.2304E-05 0.2313E-05 S2,gas 0.2420E-23 1.0000 0.2470E-23 0.2470E-23 CO,gas 0.6030E-12 1.0000 0.6154E-12 0.6154E-12 SO3,gas 0.9674E-40 1.0000 0.9873E-40 0.9873E-40 SO2,gas 0.1069E-20 1.0000 0.1091E-20 0.1091E-20 HF,gas 0.8042E-14 1.0000 0.8208E-14 0.8208E-14 HCl,gas 0.6099E-17 1.0000 0.6224E-17 0.6224E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 17 albite -0.38 -0.38 0.00 0.000 0.11184E-10 23 andradite 39.01 39.01 0.00 0.000 0.00000E+00 24 grossular 32.73 32.73 0.00 0.000 -0.12132E-10 167 stilpnomelane-Fe 13.02 13.02 0.00 0.000 -0.27298E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -13.45 -6.79 -2.263 0.11592E+05 -5.090 3 CH4,gas 4.54 -2.43 -6.98 -1.744 0.11912E+05 -5.277 4 H2,gas 8.00 2.75 -5.25 -2.998 0.89569E+04 -3.547 5 H2S,gas -6.23 -13.57 -7.34 -3.668 0.12527E+05 -5.638 6 S2,gas -7.34 -32.64 -25.31 -3.893 0.43210E+05 -23.607 7 CO,gas 3.21 -10.69 -13.91 -4.280 0.23751E+05 -12.211 8 SO3,gas 17.12 -24.58 -41.70 -10.426 0.71209E+05 -40.006 9 SO2,gas 0.83 -21.83 -22.66 -6.043 0.38693E+05 -20.962 10 HF,gas 0.47 -15.31 -15.78 -7.892 0.26952E+05 -14.086 11 HCl,gas 5.19 -13.72 -18.90 -9.452 0.32280E+05 -17.206 12 acmite 7.71 7.41 -0.30 -0.031 0.50581E+03 16 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 20 spessartine 24.46 19.59 -4.87 -0.244 0.83178E+04 21 analcite 3.32 2.67 -0.65 -0.072 0.11113E+04 27 annite 20.12 17.50 -2.63 -0.146 0.44869E+04 28 phlogopite 27.06 24.78 -2.28 -0.127 0.38965E+04 33 apatite-OH -18.15 -20.37 -2.22 -0.170 0.37822E+04 34 apatite-F -34.30 -35.68 -1.38 -0.115 0.23545E+04 38 aragonite 0.97 -0.92 -1.89 -0.629 0.32228E+04 39 brucite 12.57 9.09 -3.48 -0.696 0.59396E+04 40 calcite 0.81 -0.92 -1.73 -0.578 0.29585E+04 41 carnegieite-low 9.02 5.73 -3.30 -0.471 0.56303E+04 42 carnegieite-high 10.09 5.73 -4.37 -0.624 0.74573E+04 43 carpholite-Mg 8.58 4.06 -4.52 -0.301 0.77158E+04 45 celadonite 5.34 3.55 -1.79 -0.106 0.30631E+04 46 celadonite-Fe 3.88 1.12 -2.76 -0.162 0.47089E+04 47 chrysotile 23.89 21.16 -2.73 -0.228 0.46650E+04 49 clinochlore 39.07 37.37 -1.70 -0.053 0.29046E+04 50 daphnite 28.97 25.22 -3.74 -0.117 0.63890E+04 52 chlorite-Al-free 47.17 42.32 -4.85 -0.202 0.82851E+04 54 chloritoid-Fe 9.17 4.69 -4.48 -0.299 0.76572E+04 55 chloritoid-Mn 11.40 7.25 -4.15 -0.277 0.70868E+04 57 coesite -2.38 -3.05 -0.68 -0.226 0.11590E+04 64 cristobalite -2.56 -3.05 -0.49 -0.165 0.84438E+03 66 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71250E+04 68 diaspore 2.87 0.54 -2.33 -0.389 0.39822E+04 69 diamond -3.10 -7.94 -4.84 -1.382 0.82614E+04 70 diopside 16.18 15.51 -0.67 -0.067 0.11492E+04 71 hedenbergite 14.21 13.08 -1.13 -0.113 0.19277E+04 78 epidote 24.67 22.26 -2.41 -0.117 0.41176E+04 80 epidote-Fe 29.84 27.00 -2.84 -0.148 0.48491E+04 81 fayalite 14.05 10.27 -3.78 -0.540 0.64518E+04 82 ferrosilite 11.15 7.21 -3.94 -0.394 0.67226E+04 86 gibbsite 4.08 0.54 -3.54 -0.505 0.60407E+04 87 glaucophane 22.97 20.39 -2.58 -0.070 0.44091E+04 88 glaucophane-Fe 17.28 13.11 -4.17 -0.113 0.71206E+04 89 graphite -3.55 -7.94 -4.39 -1.256 0.75036E+04 90 greenalite 16.14 13.87 -2.27 -0.189 0.38695E+04 93 hematite 12.57 10.57 -2.00 -0.242 0.34119E+04 94 heulandite -5.83 -7.77 -1.95 -0.088 0.33224E+04 98 jadeite 4.22 2.67 -1.54 -0.154 0.26368E+04 99 julgoldite 70.43 66.24 -4.19 -0.109 0.71477E+04 100 kalsilite 7.58 3.62 -3.96 -0.566 0.67644E+04 101 kaolinite -1.33 -5.03 -3.69 -0.336 0.63074E+04 104 laumontite 2.88 1.39 -1.49 -0.099 0.25473E+04 105 lawsonite 9.62 7.50 -2.11 -0.141 0.36110E+04 106 leucite 4.12 0.57 -3.55 -0.355 0.60640E+04 108 lizardite 23.24 21.16 -2.08 -0.174 0.35576E+04 110 magnetite 20.09 17.23 -2.86 -0.233 0.48807E+04 111 minnesotaite 10.39 7.76 -2.62 -0.154 0.44813E+04 115 manganosite 14.06 9.22 -4.84 -1.209 0.82567E+04 119 microcline -2.49 -2.49 0.00 0.000 0.16605E+01 123 muscovite 2.58 -1.40 -3.99 -0.235 0.68076E+04 124 paragonite 4.24 0.70 -3.54 -0.208 0.60450E+04 125 nepheline 8.34 5.73 -2.61 -0.373 0.44627E+04 131 periclase-Fe 11.63 6.66 -4.97 -1.241 0.84786E+04 137 phlogopite-Na 29.65 26.89 -2.76 -0.153 0.47137E+04 139 prehnite 19.37 16.97 -2.40 -0.141 0.40936E+04 140 prehnite-Fe 22.50 21.72 -0.78 -0.047 0.13335E+04 145 pyrite -21.25 -23.23 -1.98 -0.466 0.33804E+04 146 pyrrhotite -4.26 -6.91 -2.65 -0.882 0.45171E+04 147 pyrrhotiteFe0.875 -6.02 -8.08 -2.06 -0.759 0.35225E+04 148 pyroxmangite 7.40 6.17 -1.23 -0.246 0.21020E+04 149 pyrophyllite -6.18 -11.14 -4.96 -0.310 0.84702E+04 150 quartz -2.99 -3.05 -0.07 -0.022 0.11171E+03 154 rhodochrosite -0.98 -4.23 -3.25 -1.083 0.55495E+04 155 rhodonite 7.45 6.17 -1.28 -0.256 0.21822E+04 156 sanidine -1.28 -2.49 -1.21 -0.093 0.20694E+04 158 siderite -2.61 -6.79 -4.18 -1.393 0.71368E+04 166 stilbite -7.52 -7.77 -0.25 -0.012 0.42855E+03 168 stilpnomelane-Mg 27.44 25.16 -2.28 -0.068 0.38922E+04 174 talc 16.49 15.05 -1.44 -0.085 0.24596E+04 177 tephroite 18.09 15.39 -2.70 -0.385 0.46027E+04 181 tridymite -2.63 -3.05 -0.43 -0.143 0.73169E+03 182 tremolite 47.87 46.07 -1.80 -0.049 0.30770E+04 183 ferroactinolite 38.45 33.92 -4.53 -0.122 0.77351E+04 184 troilite-low -4.41 -6.91 -2.49 -0.832 0.42599E+04 190 wairakite 3.95 1.39 -2.56 -0.151 0.43693E+04 191 walstromite 11.51 9.47 -2.04 -0.407 0.34765E+04 192 wollastonite 10.46 9.47 -0.99 -0.198 0.16870E+04 193 pseudo-wollastonite 11.00 9.47 -1.53 -0.305 0.26068E+04 195 akaganeite 7.75 5.28 -2.47 -0.534 0.42185E+04 202 chalcedony -2.80 -3.05 -0.25 -0.084 0.43101E+03 204 montmorillonite-Ca -2.29 -6.25 -3.96 -0.245 0.67575E+04 205 montmorillonite-K -2.24 -6.29 -4.05 -0.248 0.69221E+04 206 montmorillonite-Mg -2.48 -6.82 -4.34 -0.268 0.74031E+04 207 montmorillonite-Na -2.04 -5.60 -3.56 -0.218 0.60764E+04 208 nontronite-Ca 3.21 1.60 -1.61 -0.105 0.27527E+04 209 nontronite-H 2.53 -0.46 -3.00 -0.201 0.51180E+04 210 nontronite-K 3.34 1.56 -1.78 -0.114 0.30404E+04 211 nontronite-Mg 3.07 1.04 -2.04 -0.132 0.34823E+04 212 nontronite-Na 3.52 2.25 -1.27 -0.081 0.21607E+04 228 tobermorite 9.82 7.38 -2.44 -0.666 0.41698E+04 234 alabandite -0.98 -4.34 -3.37 -1.122 0.57481E+04 237 boehmite 4.41 0.54 -3.86 -0.644 0.65991E+04 239 ferrous-oxide 9.81 6.66 -3.15 -0.788 0.53795E+04 245 silica-amorphous -2.09 -3.05 -0.96 -0.321 0.16452E+04 247 an20ab80 2.02 1.19 -0.82 -0.063 0.14080E+04 248 an25ab75 2.65 1.59 -1.06 -0.081 0.18070E+04 249 an30ab70 3.28 1.98 -1.30 -0.100 0.22156E+04 250 tr.625ac.25prg.125 45.16 43.89 -1.27 -0.034 0.21743E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 0.0004000 MOLES Current total amount of reactant added: 0.0135900 MOLES New total amount of reactant added: 0.0139900 MOLES Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.5508E-08 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 400 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 0.0139900 Water: Moles liquid = 0.4986E+02 kg liquid = 0.8983E+00 Moles total = 0.4986E+02 kg total = 0.8982E+00 Activity = 1.0000 Stoichiometric ionic strength = .1222614E-01 Osmotic coef. = 0.9434 True ionic strength = .2081106E-01 Chg. balance for total moles = -.5508E-08 Max. difference allowed = 0.2204E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.11503E-09 -9.9392 0.96369E-10 -10.0161 0.83824E+00 -0.0766 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.24426E-03 -3.6121 0.20348E-03 -3.6915 0.83304E+00 -0.0793 4 SO4-- 0.58040E-04 -4.2363 0.29970E-04 -4.5233 0.51406E+00 -0.2890 5 HCO3- 0.46096E-03 -3.3363 0.38446E-03 -3.4152 0.83430E+00 -0.0787 6 HS- 0.34900E-03 -3.4572 0.29078E-03 -3.5364 0.83317E+00 -0.0793 7 Al+++ 0.13624E-28 -28.8657 0.30717E-29 -29.5126 0.22571E+00 -0.6465 8 H4SiO4 0.88823E-03 -3.0515 0.88775E-03 -3.0517 0.10000E+01 0.0000 9 Ca++ 0.13453E-06 -6.8712 0.68558E-07 -7.1639 0.51016E+00 -0.2923 10 Mg++ 0.22186E-10 -10.6539 0.11261E-10 -10.9484 0.50776E+00 -0.2943 11 Fe++ 0.83294E-13 -13.0794 0.42321E-13 -13.3734 0.50833E+00 -0.2939 12 K+ 0.15656E-03 -3.8053 0.13065E-03 -3.8839 0.83450E+00 -0.0786 13 Na+ 0.19915E-01 -1.7008 0.16587E-01 -1.7802 0.83289E+00 -0.0794 14 Mn++ 0.30451E-10 -10.5164 0.15477E-10 -10.8103 0.50877E+00 -0.2935 15 F- 0.63205E-05 -5.1992 0.52541E-05 -5.2795 0.83128E+00 -0.0803 16 HPO4-- 0.45524E-07 -7.3418 0.23405E-07 -7.6307 0.51413E+00 -0.2889 18 HSiO3- 0.10326E-01 -1.9861 0.86016E-02 -2.0654 0.83304E+00 -0.0793 19 Ca(HSiO3)+ 0.16107E-07 -7.7930 0.13430E-07 -7.8719 0.83469E+00 -0.0785 20 Mg(HSiO3)+ 0.32903E-11 -11.4828 0.27453E-11 -11.5614 0.83469E+00 -0.0785 21 NaHSiO3,aq 0.23075E-02 -2.6369 0.23076E-02 -2.6368 0.10000E+01 0.0000 22 AlO+ 0.53909E-16 -16.2683 0.44997E-16 -16.3468 0.83469E+00 -0.0785 24 HAlO2,aq 0.92938E-10 -10.0318 0.92987E-10 -10.0316 0.10000E+01 0.0000 25 AlO2- 0.25660E-05 -5.5907 0.21359E-05 -5.6704 0.83149E+00 -0.0801 26 CH4,aq 0.36544E-08 -8.4372 0.36234E-08 -8.4409 0.99628E+00 -0.0016 27 C2H6,aq 0.10586E-19 -19.9753 0.10457E-19 -19.9806 0.99628E+00 -0.0016 31 CO,aq 0.42765E-15 -15.3689 0.42687E-15 -15.3697 0.10000E+01 0.0000 32 CO2,aq 0.79530E-07 -7.0995 0.79167E-07 -7.1015 0.99628E+00 -0.0016 33 CO3-2 0.67921E-03 -3.1680 0.34846E-03 -3.4578 0.51293E+00 -0.2899 34 CaCO3,aq 0.29980E-06 -6.5232 0.29955E-06 -6.5235 0.10000E+01 0.0000 35 Ca(HCO3)+ 0.80716E-09 -9.0930 0.67281E-09 -9.1721 0.83469E+00 -0.0785 36 CaCl+ 0.27076E-10 -10.5674 0.22576E-10 -10.6464 0.83469E+00 -0.0785 37 CaCl2,aq 0.10925E-14 -14.9616 0.10914E-14 -14.9620 0.10000E+01 0.0000 38 CaF+ 0.63073E-11 -11.2002 0.52591E-11 -11.2791 0.83469E+00 -0.0785 39 CaOH+ 0.60776E-07 -7.2163 0.50702E-07 -7.2950 0.83469E+00 -0.0785 40 CaSO4,aq 0.65023E-09 -9.1869 0.65246E-09 -9.1854 0.10000E+01 0.0000 41 HCl,aq 0.35952E-14 -14.4443 0.35933E-14 -14.4445 0.10000E+01 0.0000 45 HF,aq 0.34680E-11 -11.4599 0.34662E-11 -11.4601 0.10000E+01 0.0000 46 HF2- 0.73849E-17 -17.1317 0.61487E-17 -17.2112 0.83304E+00 -0.0793 48 FeCl+ 0.16338E-16 -16.7868 0.13631E-16 -16.8655 0.83469E+00 -0.0785 51 FeF+ 0.13620E-16 -16.8658 0.11363E-16 -16.9445 0.83469E+00 -0.0785 53 FeO,aq 0.17701E-09 -9.7520 0.17711E-09 -9.7517 0.10000E+01 0.0000 54 FeOH+ 0.17125E-10 -10.7664 0.14295E-10 -10.8448 0.83469E+00 -0.0785 55 HFeO2- 0.23058E-07 -7.6372 0.19230E-07 -7.7160 0.83304E+00 -0.0793 56 FeO+ 0.88122E-16 -16.0549 0.73596E-16 -16.1331 0.83469E+00 -0.0785 58 FeO2- 0.19434E-08 -8.7114 0.16216E-08 -8.7901 0.83304E+00 -0.0793 59 HFeO2,aq 0.19853E-10 -10.7022 0.19875E-10 -10.7017 0.10000E+01 0.0000 60 H2,aq 0.21566E-06 -6.6662 0.21464E-06 -6.6683 0.99628E+00 -0.0016 61 KCl,aq 0.48182E-09 -9.3171 0.48182E-09 -9.3171 0.10000E+01 0.0000 62 KHSO4,aq 0.10627E-17 -17.9736 0.10669E-17 -17.9719 0.10000E+01 0.0000 63 KOH,aq 0.57866E-06 -6.2376 0.57896E-06 -6.2373 0.10000E+01 0.0000 64 KSO4- 0.72610E-07 -7.1390 0.60759E-07 -7.2164 0.83304E+00 -0.0793 65 MgCO3,aq 0.12335E-10 -10.9089 0.12333E-10 -10.9089 0.10000E+01 0.0000 66 Mg(HCO3)+ 0.13538E-12 -12.8684 0.11292E-12 -12.9472 0.83469E+00 -0.0785 67 MgCl+ 0.40281E-14 -14.3949 0.33610E-14 -14.4735 0.83469E+00 -0.0785 68 MgF+ 0.38351E-14 -14.4162 0.32000E-14 -14.4949 0.83469E+00 -0.0785 69 MgOH+ 0.55202E-10 -10.2580 0.46084E-10 -10.3364 0.83469E+00 -0.0785 71 MnF+ 0.16426E-14 -14.7845 0.13697E-14 -14.8634 0.83469E+00 -0.0785 72 MnO,aq 0.17258E-08 -8.7630 0.17259E-08 -8.7630 0.10000E+01 0.0000 73 MnOH+ 0.58210E-09 -9.2350 0.48564E-09 -9.3137 0.83469E+00 -0.0785 74 MnO2-2 0.12011E-10 -10.9204 0.61675E-11 -11.2099 0.51293E+00 -0.2899 75 HMnO2- 0.15622E-09 -9.8063 0.13021E-09 -9.8853 0.83304E+00 -0.0793 78 MnCl+ 0.23257E-13 -13.6334 0.19393E-13 -13.7123 0.83469E+00 -0.0785 79 MnSO4,aq 0.13344E-12 -12.8747 0.13391E-12 -12.8732 0.10000E+01 0.0000 80 NaCl,aq 0.11185E-05 -5.9514 0.11185E-05 -5.9513 0.10000E+01 0.0000 81 NaF,aq 0.20403E-07 -7.6903 0.20403E-07 -7.6903 0.10000E+01 0.0000 82 NaOH,aq 0.73910E-04 -4.1313 0.73952E-04 -4.1311 0.10000E+01 0.0000 84 OH- 0.72066E-02 -2.1423 0.59954E-02 -2.2222 0.83149E+00 -0.0801 89 HPO3-2 0.30553E-16 -16.5150 0.15656E-16 -16.8053 0.51293E+00 -0.2899 92 H3PO4,aq 0.15219E-17 -17.8176 0.15202E-17 -17.8181 0.10000E+01 0.0000 93 H2PO4- 0.49926E-10 -10.3017 0.41609E-10 -10.3808 0.83386E+00 -0.0789 94 PO4-3 0.83420E-09 -9.0787 0.19816E-09 -9.7030 0.23742E+00 -0.6245 98 HP2O7-3 0.12456E-17 -17.9046 0.28127E-18 -18.5509 0.22594E+00 -0.6460 99 P2O7-4 0.94174E-17 -17.0261 0.69727E-18 -18.1566 0.74042E-01 -1.1305 100 H2S,aq 0.86974E-07 -7.0606 0.86605E-07 -7.0625 0.99628E+00 -0.0016 101 S2-2 0.17000E-10 -10.7696 0.87284E-11 -11.0591 0.51293E+00 -0.2899 102 S3-2 0.92367E-17 -17.0345 0.47447E-17 -17.3238 0.51293E+00 -0.2899 107 SO3-2 0.16002E-11 -11.7958 0.83595E-12 -12.0778 0.52058E+00 -0.2835 108 HSO3- 0.60370E-14 -14.2192 0.50440E-14 -14.2972 0.83304E+00 -0.0793 109 HSO4- 0.33181E-11 -11.4791 0.27834E-11 -11.5554 0.83553E+00 -0.0780 111 S2O3-2 0.59207E-13 -13.2276 0.30489E-13 -13.5159 0.51293E+00 -0.2899 Charge balance for all species = 0.1469E-05 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.1150268E-09 -.2060552E-01 -.2073192E+02 0.0000 2 H2O 0.1000000E+01 0.5550290E+02 0.9981103E+06 0.0000 3 Cl- 0.2442633E-03 0.2453823E-03 0.8683954E+01 6.3246 4 SO4-- 0.5804001E-04 0.5768406E-04 0.5531297E+01 15.5088 5 HCO3- 0.4609594E-03 0.1140549E-02 0.6946843E+02 6.6009 6 HS- 0.3489998E-03 0.3491559E-03 0.1152660E+02 6.4796 7 Al+++ 0.1362379E-28 0.2473946E-05 0.6663120E-01 0.5356 8 H4SiO4 0.8882262E-03 0.1352045E-01 0.1297195E+04 -3.0517 9 Ca++ 0.1345265E-06 0.2316432E-06 0.9267167E-02 12.8682 10 Mg++ 0.2218630E-10 0.9315811E-10 0.2260803E-05 9.0837 11 Fe++ 0.8329357E-13 -.6834261E-07 -.3809893E-02 6.6587 12 K+ 0.1565579E-03 0.1572093E-03 0.6136185E+01 6.1322 13 Na+ 0.1991458E-01 0.2229744E-01 0.5116954E+03 8.2358 14 Mn++ 0.3045139E-10 0.2506909E-08 0.1374779E-03 9.2218 15 F- 0.6320503E-05 0.6340915E-05 0.1202489E+00 4.7366 16 HPO4-- 0.4552411E-07 0.4640823E-07 0.4446236E-02 12.4014 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.1852017E-01 -.1850979E-01 -.1036123E-04 0.0000000E+00 2 H2O 0.4985786E+02 0.4985787E+02 -.1007939E-04 0.0000000E+00 3 Cl- 0.2204252E-03 0.2204252E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.5181719E-04 0.5181719E-04 0.2500000E-20 0.0000000E+00 5 HCO3- 0.1024547E-02 0.1024547E-02 0.0000000E+00 0.0000000E+00 6 HS- 0.3136443E-03 0.3136443E-03 -.2500000E-20 0.0000000E+00 7 Al+++ 0.4775352E-05 0.2222328E-05 0.2550380E-05 0.0000000E+00 8 H4SiO4 0.1215302E-01 0.1214532E-01 0.7688719E-05 0.0000000E+00 9 Ca++ 0.2080835E-06 0.2080835E-06 0.6000000E-19 0.0000000E+00 10 Mg++ 0.8368328E-10 0.8368328E-10 0.0000000E+00 0.0000000E+00 11 Fe++ 0.3259227E-07 -.6139169E-07 0.9394466E-07 0.0000000E+00 12 K+ 0.1412294E-03 0.1412200E-03 0.9394466E-08 0.0000000E+00 13 Na+ 0.2003215E-01 0.2002963E-01 0.2512803E-05 0.0000000E+00 14 Mn++ 0.2251939E-08 0.2251939E-08 0.0000000E+00 0.0000000E+00 15 F- 0.5696000E-05 0.5696000E-05 0.0000000E+00 0.0000000E+00 16 HPO4-- 0.4168819E-07 0.4168819E-07 0.0000000E+00 0.0000000E+00 Chg. balance for solid moles: -.2118E-20 Mass of aqueous solution: 0.899905E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 0.0139900 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 0.2518E-05 -5.599 0.6602E-03 -3.180 97.02 0.2534E-03 andradite 0.1000E-19 -20.000 0.5082E-17 -17.294 0.7468E-12 0.1320E-17 grossular 0.1000E-19 -20.000 0.4504E-17 -17.346 0.6619E-12 0.1253E-17 stilpnomelane-Fe 0.1882E-07 -7.725 0.2029E-04 -4.693 2.982 0.7009E-05 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.5000E+00 0.5000E+00 1.0000 -0.301 grossular 0.5000E+00 0.5000E+00 1.0000 -0.301 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 0.000680 g Volume = 0.000260 cm3 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.0139900 moles log = -1.8542 Original solution: 1000.0103000 g Original solution / Rock added: 71480.36 (Water/Rock Ratio), log = 4.8542 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0206 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9997E+00 0.9859 0.1006E+01 0.1020E+01 CO2,gas 0.8241E-05 1.0071 0.8470E-05 0.8410E-05 CH4,gas 0.5161E-05 1.0125 0.5333E-05 0.5267E-05 H2,gas 0.2760E-03 1.0005 0.2818E-03 0.2816E-03 H2S,gas 0.2342E-05 0.9960 0.2381E-05 0.2390E-05 S2,gas 0.2625E-23 1.0000 0.2679E-23 0.2679E-23 CO,gas 0.6233E-12 1.0000 0.6361E-12 0.6361E-12 SO3,gas 0.1031E-39 1.0000 0.1052E-39 0.1052E-39 SO2,gas 0.1130E-20 1.0000 0.1154E-20 0.1154E-20 HF,gas 0.8339E-14 1.0000 0.8511E-14 0.8511E-14 HCl,gas 0.6213E-17 1.0000 0.6341E-17 0.6341E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases albite does not satisfy anymore the mass action equation We remove it from matrix. affinity =-.2370E+00 andradite does not satisfy anymore the mass action equation We remove it from matrix. affinity =-.2748E+04 grossular does not satisfy anymore the mass action equation We remove it from matrix. affinity =0.2747E+04 stilpnomelane-Fe does not satisfy anymore the mass action equation We remove it from matrix. affinity =0.1118E-03 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -13.43 -6.77 -2.257 0.11561E+05 -5.072 3 CH4,gas 4.54 -2.43 -6.97 -1.743 0.11904E+05 -5.273 4 H2,gas 8.00 2.75 -5.25 -2.999 0.89626E+04 -3.550 5 H2S,gas -6.23 -13.55 -7.32 -3.661 0.12503E+05 -5.623 6 S2,gas -7.34 -32.61 -25.27 -3.888 0.43150E+05 -23.572 7 CO,gas 3.21 -10.68 -13.90 -4.276 0.23726E+05 -12.196 8 SO3,gas 17.12 -24.56 -41.68 -10.419 0.71162E+05 -39.978 9 SO2,gas 0.83 -21.80 -22.64 -6.036 0.38652E+05 -20.938 10 HF,gas 0.47 -15.30 -15.77 -7.885 0.26925E+05 -14.070 11 HCl,gas 5.19 -13.71 -18.90 -9.448 0.32266E+05 -17.198 12 acmite 7.71 7.42 -0.29 -0.031 0.50197E+03 16 albite-high 0.69 -0.38 -1.08 -0.083 0.18386E+04 17 albite -0.38 -0.38 0.00 0.000 -0.23702E+00 20 spessartine 24.46 19.58 -4.88 -0.244 0.83254E+04 21 analcite 3.32 2.67 -0.65 -0.073 0.11165E+04 23 andradite 39.01 40.62 1.61 0.084 -0.27480E+04 24 grossular 32.73 31.12 -1.61 -0.080 0.27470E+04 27 annite 20.12 17.49 -2.63 -0.146 0.44987E+04 28 phlogopite 27.06 24.76 -2.30 -0.128 0.39286E+04 30 anorthite 12.71 7.84 -4.87 -0.375 0.83229E+04 33 apatite-OH -18.15 -18.65 -0.49 -0.038 0.84354E+03 34 apatite-F -34.30 -33.94 0.36 0.030 -0.61111E+03 38 aragonite 0.97 -0.56 -1.53 -0.510 0.26117E+04 39 brucite 12.57 9.08 -3.48 -0.697 0.59503E+04 40 calcite 0.81 -0.56 -1.37 -0.458 0.23474E+04 41 carnegieite-low 9.02 5.72 -3.30 -0.472 0.56408E+04 42 carnegieite-high 10.09 5.72 -4.37 -0.625 0.74678E+04 43 carpholite-Mg 8.58 4.05 -4.53 -0.302 0.77360E+04 45 celadonite 5.34 3.54 -1.80 -0.106 0.30683E+04 46 celadonite-Fe 3.88 1.12 -2.76 -0.162 0.47074E+04 47 chrysotile 23.89 21.15 -2.74 -0.229 0.46865E+04 49 clinochlore 39.07 37.33 -1.73 -0.054 0.29624E+04 50 daphnite 28.97 25.21 -3.76 -0.117 0.64129E+04 52 chlorite-Al-free 47.17 42.30 -4.88 -0.203 0.83281E+04 54 chloritoid-Fe 9.17 4.68 -4.50 -0.300 0.76759E+04 55 chloritoid-Mn 11.40 7.24 -4.16 -0.277 0.71028E+04 57 coesite -2.38 -3.05 -0.68 -0.225 0.11537E+04 64 cristobalite -2.56 -3.05 -0.49 -0.164 0.83901E+03 66 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71249E+04 68 diaspore 2.87 0.54 -2.34 -0.390 0.39923E+04 69 diamond -3.10 -7.93 -4.83 -1.379 0.82426E+04 70 diopside 16.18 15.85 -0.33 -0.033 0.56839E+03 71 hedenbergite 14.21 13.42 -0.78 -0.078 0.13401E+04 78 epidote 24.67 22.94 -1.73 -0.084 0.29611E+04 79 clinozoisite 22.81 18.19 -4.62 -0.210 0.78852E+04 80 epidote-Fe 29.84 27.68 -2.16 -0.112 0.36836E+04 81 fayalite 14.05 10.27 -3.78 -0.540 0.64544E+04 82 ferrosilite 11.15 7.21 -3.94 -0.394 0.67198E+04 86 gibbsite 4.08 0.54 -3.54 -0.506 0.60508E+04 87 glaucophane 22.97 20.38 -2.59 -0.070 0.44301E+04 88 glaucophane-Fe 17.28 13.11 -4.17 -0.113 0.71213E+04 89 graphite -3.55 -7.93 -4.38 -1.252 0.74848E+04 90 greenalite 16.14 13.87 -2.27 -0.189 0.38706E+04 93 hematite 12.57 10.57 -2.00 -0.242 0.34142E+04 94 heulandite -5.83 -7.42 -1.60 -0.073 0.27241E+04 98 jadeite 4.22 2.67 -1.55 -0.155 0.26420E+04 99 julgoldite 70.43 67.61 -2.81 -0.073 0.48045E+04 100 kalsilite 7.58 3.62 -3.97 -0.567 0.67750E+04 101 kaolinite -1.33 -5.03 -3.70 -0.336 0.63168E+04 104 laumontite 2.88 1.73 -1.15 -0.077 0.19652E+04 105 lawsonite 9.62 7.84 -1.78 -0.119 0.30396E+04 106 leucite 4.12 0.56 -3.55 -0.355 0.60693E+04 108 lizardite 23.24 21.15 -2.10 -0.175 0.35791E+04 110 magnetite 20.09 17.23 -2.86 -0.234 0.48869E+04 111 minnesotaite 10.39 7.77 -2.62 -0.154 0.44717E+04 115 manganosite 14.06 9.22 -4.84 -1.209 0.82578E+04 119 microcline -2.49 -2.49 0.00 0.000 0.15402E+01 123 muscovite 2.58 -1.42 -4.00 -0.235 0.68276E+04 124 paragonite 4.24 0.69 -3.55 -0.209 0.60650E+04 125 nepheline 8.34 5.72 -2.62 -0.374 0.44732E+04 131 periclase-Fe 11.63 6.66 -4.97 -1.242 0.84825E+04 137 phlogopite-Na 29.65 26.87 -2.78 -0.154 0.47457E+04 139 prehnite 19.37 17.65 -1.72 -0.101 0.29360E+04 140 prehnite-Fe 22.50 22.40 -0.10 -0.006 0.16688E+03 141 pumpellyite-Fe 46.27 42.50 -3.77 -0.084 0.64379E+04 142 pumpellyite-Mg 48.99 44.92 -4.07 -0.090 0.69508E+04 145 pyrite -21.25 -23.20 -1.95 -0.459 0.33298E+04 146 pyrrhotite -4.26 -6.89 -2.63 -0.878 0.44966E+04 147 pyrrhotiteFe0.875 -6.02 -8.07 -2.05 -0.754 0.35008E+04 148 pyroxmangite 7.40 6.17 -1.23 -0.246 0.20978E+04 149 pyrophyllite -6.18 -11.14 -4.96 -0.310 0.84689E+04 150 quartz -2.99 -3.05 -0.06 -0.021 0.10634E+03 154 rhodochrosite -0.98 -4.21 -3.23 -1.078 0.55204E+04 155 rhodonite 7.45 6.17 -1.28 -0.255 0.21780E+04 156 sanidine -1.28 -2.49 -1.21 -0.093 0.20693E+04 158 siderite -2.61 -6.77 -4.16 -1.388 0.71106E+04 166 stilbite -7.52 -7.42 0.10 0.005 -0.16972E+03 167 stilpnomelane-Fe 13.02 13.02 0.00 0.000 0.11184E-03 168 stilpnomelane-Mg 27.44 25.14 -2.30 -0.069 0.39260E+04 174 talc 16.49 15.04 -1.45 -0.085 0.24703E+04 177 tephroite 18.09 15.39 -2.69 -0.385 0.45997E+04 181 tridymite -2.63 -3.05 -0.43 -0.142 0.72631E+03 182 tremolite 47.87 46.74 -1.13 -0.030 0.19261E+04 183 ferroactinolite 38.45 34.62 -3.84 -0.104 0.65503E+04 184 troilite-low -4.41 -6.89 -2.48 -0.828 0.42394E+04 190 wairakite 3.95 1.73 -2.22 -0.130 0.37871E+04 191 walstromite 11.51 9.82 -1.69 -0.339 0.28903E+04 192 wollastonite 10.46 9.82 -0.64 -0.129 0.11008E+04 193 pseudo-wollastonite 11.00 9.82 -1.18 -0.237 0.20206E+04 194 zoisite 22.85 18.19 -4.66 -0.212 0.79593E+04 195 akaganeite 7.75 5.28 -2.47 -0.534 0.42196E+04 202 chalcedony -2.80 -3.05 -0.25 -0.083 0.42563E+03 204 montmorillonite-Ca -2.29 -6.19 -3.90 -0.241 0.66606E+04 205 montmorillonite-K -2.24 -6.29 -4.05 -0.248 0.69229E+04 206 montmorillonite-Mg -2.48 -6.82 -4.34 -0.268 0.74038E+04 207 montmorillonite-Na -2.04 -5.60 -3.56 -0.218 0.60772E+04 208 nontronite-Ca 3.21 1.67 -1.55 -0.100 0.26426E+04 209 nontronite-H 2.53 -0.46 -2.99 -0.200 0.51038E+04 210 nontronite-K 3.34 1.57 -1.77 -0.114 0.30282E+04 211 nontronite-Mg 3.07 1.04 -2.03 -0.132 0.34699E+04 212 nontronite-Na 3.52 2.26 -1.26 -0.081 0.21485E+04 228 tobermorite 9.82 7.67 -2.16 -0.588 0.36806E+04 234 alabandite -0.98 -4.33 -3.35 -1.118 0.57248E+04 237 boehmite 4.41 0.54 -3.87 -0.645 0.66092E+04 239 ferrous-oxide 9.81 6.66 -3.15 -0.788 0.53835E+04 245 silica-amorphous -2.09 -3.05 -0.96 -0.320 0.16398E+04 247 an20ab80 2.02 1.26 -0.76 -0.058 0.12935E+04 248 an25ab75 2.65 1.67 -0.97 -0.075 0.16640E+04 249 an30ab70 3.28 2.08 -1.20 -0.092 0.20440E+04 250 tr.625ac.25prg.125 45.16 44.57 -0.60 -0.016 0.10194E+04 Number of iterations reached the given limit ( 400) Non-Convergence assumed. Execution aborted. Check "convergence problems" in manual. Cut step size to one tenth of previous value and try again.