File SKIP_SPECIES.TXT lists species and minerals omitted from the calculations due to given T, P, option switches, or suppression in CHIMRUN, or are suppressed in the SOLTHERM database. It also lists minerals for which density is not specified in SOLTHERM. This is an extended P(to 5 kB), T(to 600 C) run (CON_FLAG = 1). methanol,aq is suppressed in SOLTHERM data file. methanol,aq is suppressed in SOLTHERM data file. CuCl4-3 is suppressed in SOLTHERM data file. H2BO3- is suppressed in SOLTHERM data file. UO2CO3,aq is suppressed in SOLTHERM data file. UO2SO4,aq is suppressed in SOLTHERM data file. UO2Cl2,aq is suppressed in SOLTHERM data file. UO2F2,aq is suppressed in SOLTHERM data file. PO4-3 is suppressed in SOLTHERM data file. H2PO4- is suppressed in SOLTHERM data file. H3PO4 is suppressed in SOLTHERM data file. O2,gas is suppressed in THIS RUN. O2,gas is suppressed in THIS RUN. amesite is suppressed in SOLTHERM data file. andradite is suppressed in THIS RUN. andradite is suppressed in THIS RUN. grossular is suppressed in THIS RUN. antigorite is suppressed in SOLTHERM data file. goethite is suppressed in THIS RUN. goethite is suppressed in THIS RUN. riebeckite is suppressed in THIS RUN. riebeckite is suppressed in THIS RUN. sapphirine-Fe(221) is suppressed in SOLTHERM data file. sapphirine(221) is suppressed in SOLTHERM data file. talc-prl is suppressed in SOLTHERM data file. PrO1.833(s) is suppressed in SOLTHERM data file. niter-NH4 is suppressed in SOLTHERM data file. FMQ_HS-1 is suppressed in THIS RUN. kf-ab-equil is suppressed in THIS RUN. ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Species No. Charge Tot.moles Trial molality Gamma Mixing solution H+ 1 1. -0.18563E-01 0.11406E-09 0.8383 0.00000000E+00 H2O 2 0. 0.49858E+02 0.10000E+01 1.0000 0.00000000E+00 Cl- 3 -1. 0.21807E-03 0.24165E-03 0.8331 0.00000000E+00 SO4-- 4 -2. 0.49907E-04 0.55546E-04 0.5142 0.00000000E+00 HCO3- 5 -1. 0.99563E-03 0.44584E-03 0.8344 0.00000000E+00 HS- 6 -1. 0.30583E-03 0.34032E-03 0.8332 0.00000000E+00 Al+++ 7 3. 0.47754E-05 0.13466E-28 0.2259 0.00000000E+00 H4SiO4 8 0. 0.12153E-01 0.88134E-03 1.0000 0.00000000E+00 Ca++ 9 2. 0.20808E-06 0.60427E-07 0.5103 0.00000000E+00 Mg++ 10 2. 0.83683E-10 0.22145E-10 0.5079 0.00000000E+00 Fe++ 11 2. 0.32592E-07 0.82375E-13 0.5085 0.00000000E+00 K+ 12 1. 0.14123E-03 0.15657E-03 0.8346 0.00000000E+00 Na+ 13 1. 0.20032E-01 0.19913E-01 0.8329 0.00000000E+00 Mn++ 14 2. 0.22519E-08 0.29986E-10 0.5089 0.00000000E+00 F- 15 -1. 0.55360E-05 0.61430E-05 0.8313 0.00000000E+00 HPO4-- 16 -2. 0.41688E-07 0.45518E-07 0.5143 0.00000000E+00 Chg. balance for total moles = -.5508E-08 Max. difference allowed = 0.2181E-07 The following parameters were given: ERPC = 0.1000E-11 pH = 0.0000 PFLUID = 50.0000 SLIM = 0.200000E-01 TEMP = 100.0000 SINC = 0.4000E-03 TEMPC = 0.0000 TOTMIX = 0.135900E-01 ENTH = 0.0000 SENTH = 0.0000 DENTH = 0.0000 TOTWAT = 90.0000 SOLMIN = 0.0000E+00 RM = 0.0000 AQGRM = 1000.0103 SUPRNT = 0.1000E-19 VBOX-1 = 400.9996 RHOFRS = 0.0000 RHOROC = 2.5000 The following options were selected: CONFLG = 1 C = 3 IFRAC = 0 IPUNCH = 2 NLOOP = 400 ISTEP = 2 LIMSOL = 1 LOOC = 0 IENTH = 0 ITREF = 0 IDEAL = 0 IPSAT = 1 INCREM = 0 INCP = 0 MINSOL = 3 NEUT = 0 AWAT = 0 CHGF = 0 Of the derived species, only those with molality > 0.10E-19 will appear in the output Species No. Charge Log K(diss) Species No. Charge Log K(diss) SiF6-2 17 -2. -24.5019 Mn+3 70 3. 19.1453 HSiO3- 18 -1. 9.0298 MnF+ 71 1. -1.2264 Ca(HSiO3)+ 19 1. 7.6723 MnO,aq 72 0. 17.9848 Mg(HSiO3)+ 20 1. 7.5773 MnOH+ 73 1. 8.5194 NaHSiO3,aq 21 0. 7.8210 MnO2-2 74 -2. 40.4638 AlO+ 22 1. 6.8663 HMnO2- 75 -1. 29.1232 AlOH+2 23 2. 3.1691 MnO4- 76 -1. 83.3111 HAlO2,aq 24 0. 10.5671 MnO4-2 77 -2. 81.3005 AlO2- 25 -1. 16.2221 MnCl+ 78 1. -0.7894 CH4,aq 26 0. 6.0126 MnSO4,aq 79 0. -2.4604 C2H6,aq 27 0. 12.3733 NaCl,aq 80 0. 0.4796 C3H8,aq 28 0. 17.3707 NaF,aq 81 0. 0.6306 C4H10,aq 29 0. 22.3757 NaOH,aq 82 0. 12.3669 ethanol,aq 30 0. 15.3258 O2,aq 83 0. 53.5502 CO,aq 31 0. 4.6892 OH- 84 -1. 12.2382 CO2,aq 32 0. -6.3298 HO2- 85 -1. 50.8010 CO3-2 33 -2. 10.0588 H2O2,aq 86 0. 40.0166 CaCO3,aq 34 0. 5.9605 H3PO2,aq 87 0. 24.3066 Ca(HCO3)+ 35 1. -1.4070 H2PO2- 88 -1. 26.5366 CaCl+ 36 1. -0.2091 HPO3-2 89 -2. 11.9254 CaCl2,aq 37 0. 0.4151 H3PO3,aq 90 0. 3.5792 CaF+ 38 1. -1.1644 H2PO3- 91 -1. 5.6232 CaOH+ 39 1. 10.1471 H3PO4,aq 92 0. -9.8447 CaSO4,aq 40 0. -2.5018 H2PO4- 93 -1. -7.2659 HCl,aq 41 0. 0.7370 PO4-3 94 -3. 12.0884 HClO,aq 42 0. 32.4260 H4P2O7,aq 95 0. -17.8095 ClO- 43 -1. 39.6530 H3P2O7- 96 -1. -15.9156 HClO2,aq 44 0. 70.1812 H2P2O7-2 97 -2. -13.4262 HF,aq 45 0. -3.8354 HP2O7-3 98 -3. -6.7266 HF2- 46 -1. -3.3639 P2O7-4 99 -4. 2.8952 Fe+3 47 3. 8.3809 H2S,aq 100 0. -6.4900 FeCl+ 48 1. -0.1994 S2-2 101 -2. 1.2355 FeCl2,aq 49 0. 4.3001 S3-2 102 -2. -8.8031 FeCl+2 50 2. 6.5269 S3- 103 -1. -16.3389 FeF+ 51 1. -1.7084 S4-2 104 -2. -18.6615 FeF+2 52 2. 1.4309 S5-2 105 -2. -28.3439 FeO,aq 53 0. 16.4104 SO2,aq 106 0. -0.2309 FeOH+ 54 1. 7.4874 SO3-2 107 -2. 10.3052 HFeO2- 55 -1. 24.3908 HSO3- 108 -1. 2.5086 FeO+ 56 1. 11.4004 HSO4- 109 -1. -2.9839 FeOH+2 57 2. 9.1194 HSO5- 110 -1. 38.8366 FeO2- 58 -1. 24.0895 S2O3-2 111 -2. -4.5600 HFeO2,aq 59 0. 15.9850 HS2O3- 112 -1. -6.8123 H2,aq 60 0. 9.4190 H2S2O3,aq 113 0. -8.0173 KCl,aq 61 0. 1.7417 S2O4-2 114 -2. 10.5541 KHSO4,aq 62 0. -0.4514 HS2O4- 115 -1. 7.6551 KOH,aq 63 0. 12.3695 H2S2O4,aq 116 0. 6.6259 KSO4- 64 -1. -1.1908 S2O5-2 117 -2. 10.0741 MgCO3,aq 65 0. 6.5614 S2O6-2 118 -2. 11.5521 Mg(HCO3)+ 66 1. -1.4164 S2O8-2 119 -2. 42.0620 MgCl+ 67 1. -0.1664 S3O6-2 120 -2. 3.7866 MgF+ 68 1. -1.7331 S4O6-2 121 -2. -17.8657 MgOH+ 69 1. 9.4041 S5O6-2 122 -2. -14.1333 For mixed gases (JSOLS=6), log K(hydrol) = log (K*P) Log K Trial Log K Trial Mineral No. hydrol Moles Mineral No. hydrol Moles H2O,gas 1 1.696 0.0000E+00 osumilite(2) 125 20.667 0.0000E+00 CO2,gas 2 -6.660 0.0000E+00 osumilite-Fe 126 14.390 0.0000E+00 CH4,gas 3 4.544 0.0000E+00 pargasite 127 65.092 0.0000E+00 H2,gas 4 8.000 0.0000E+00 periclase 128 16.138 0.0000E+00 H2S,gas 5 -6.230 0.0000E+00 periclase-Fe 129 11.627 0.0000E+00 S2,gas 6 -7.335 0.0000E+00 perovskite-Al 130 12.344 0.0000E+00 CO,gas 7 3.215 0.0000E+00 perovskite-Ca 131 23.807 0.0000E+00 SO3,gas 8 17.121 0.0000E+00 perovskite-Fe 132 21.143 0.0000E+00 SO2,gas 9 0.832 0.0000E+00 perovskite-Mg 133 23.119 0.0000E+00 HF,gas 10 0.473 0.0000E+00 phase_A 134 80.189 0.0000E+00 HCl,gas 11 5.189 0.0000E+00 phlogopite-Na 135 29.647 0.0000E+00 acmite 12 7.710 0.0000E+00 piemontite(ordered) 136 33.776 0.0000E+00 akermanite 13 36.442 0.0000E+00 prehnite 137 19.372 0.0000E+00 akimotoite 14 16.591 0.0000E+00 prehnite-Fe 138 22.498 0.0000E+00 akimotoite-Fe 15 13.067 0.0000E+00 pumpellyite-Fe 139 46.269 0.0000E+00 albite-high 16 0.693 0.0000E+00 pumpellyite-Mg 140 48.995 0.0000E+00 albite 17 -0.384 0.2415E-05 px-Mg-tschermaks 141 19.616 0.0000E+00 almandine 18 24.442 0.0000E+00 px-Ca-tschermaks 142 18.610 0.0000E+00 pyrope 19 37.248 0.0000E+00 pyrite 143 -21.247 0.0000E+00 spessartine 20 24.457 0.0000E+00 pyrrhotite 144 -4.260 0.0000E+00 analcite 21 3.322 0.0000E+00 pyrrhotiteFe0.875 145 -6.017 0.0000E+00 andalusite 22 5.002 0.0000E+00 pyroxmangite 146 7.399 0.0000E+00 anhydrite 23 -5.317 0.0000E+00 pyrophyllite 147 -6.176 0.0000E+00 ankerite 24 -2.135 0.0000E+00 quartz 148 -2.989 0.0000E+00 annite 25 20.123 0.0000E+00 rankinite 149 40.713 0.0000E+00 phlogopite 26 27.065 0.0000E+00 ringwoodite-Fe 150 15.456 0.0000E+00 biotite-Mn 27 32.960 0.0000E+00 ringwoodite-Mg 151 27.575 0.0000E+00 anorthite 28 12.710 0.0000E+00 rhodochrosite 152 -0.976 0.0000E+00 anthophyllite 29 51.852 0.0000E+00 rhodonite 153 7.446 0.0000E+00 anthophyllite-Fe 30 29.306 0.0000E+00 sanidine 154 -1.275 0.0000E+00 apatite-OH 31 -18.153 0.0000E+00 sapphirine(351) 155 78.899 0.0000E+00 apatite-F 32 -34.301 0.0000E+00 siderite 156 -2.608 0.0000E+00 apatite-OH-zs 33 -12.736 0.0000E+00 sillimanite 157 5.262 0.0000E+00 apatite-F-zs 34 -27.774 0.0000E+00 sodalite 158 49.976 0.0000E+00 apatite-Cl-zs 35 -16.674 0.0000E+00 spinel 159 20.870 0.0000E+00 aragonite 36 0.967 0.0000E+00 spurrite 160 59.482 0.0000E+00 brucite 37 12.569 0.0000E+00 staurolite-Fe 161 73.598 0.0000E+00 calcite 38 0.812 0.0000E+00 staurolite-Mg 162 89.802 0.0000E+00 carnegieite-low 39 9.023 0.0000E+00 staurolite-Mn 163 83.909 0.0000E+00 carnegieite-high 40 10.093 0.0000E+00 stilbite 164 -7.522 0.0000E+00 carpholite-Mg 41 8.582 0.0000E+00 stilpnomelane-Fe 165 13.017 0.1411E-08 carpholite-Fe 42 6.713 0.0000E+00 stilpnomelane-Mg 166 27.441 0.0000E+00 celadonite 43 5.342 0.0000E+00 stishovite 167 2.720 0.0000E+00 celadonite-Fe 44 3.877 0.0000E+00 sudoite-Fe 168 18.296 0.0000E+00 chrysotile 45 23.892 0.0000E+00 sudoite 169 21.077 0.0000E+00 chondrodite 46 56.475 0.0000E+00 sulfur 170 -9.152 0.0000E+00 clinochlore 47 39.070 0.0000E+00 sylvite 171 1.338 0.0000E+00 daphnite 48 28.965 0.0000E+00 talc 172 16.491 0.0000E+00 chlorite-Mn 49 46.869 0.0000E+00 talc-Fe 173 13.448 0.0000E+00 chlorite-Al-free 50 47.173 0.0000E+00 talc-tschermaks 174 19.091 0.0000E+00 chloritoid-Mg 51 13.198 0.0000E+00 tephroite 175 18.086 0.0000E+00 chloritoid-Fe 52 9.174 0.0000E+00 tilleyite 176 41.377 0.0000E+00 chloritoid-Mn 53 11.401 0.0000E+00 titanite-CaSi 177 15.479 0.0000E+00 clinohumite 54 97.128 0.0000E+00 topaz-H 178 4.618 0.0000E+00 coesite 55 -2.376 0.0000E+00 tridymite 179 -2.626 0.0000E+00 cordierite-H 56 23.715 0.0000E+00 tremolite 180 47.869 0.0000E+00 cordierite 57 24.049 0.0000E+00 ferroactinolite 181 38.452 0.0000E+00 cordierite-Fe 58 20.450 0.0000E+00 troilite-low 182 -4.411 0.0000E+00 cordierite-Mn 59 25.066 0.0000E+00 tschermakite 183 48.210 0.0000E+00 corundum 60 8.383 0.0000E+00 vesuvianite 184 223.471 0.0000E+00 corundum-MgSi 61 18.891 0.0000E+00 wadeite-Si 185 20.216 0.0000E+00 cristobalite 62 -2.560 0.0000E+00 wadsleyite-Fe 186 15.680 0.0000E+00 cummingtonite 63 52.099 0.0000E+00 wadsleyite-Mg 187 25.850 0.0000E+00 cymrite-K 64 1.685 0.0000E+00 wairakite 188 3.950 0.0000E+00 deerite 65 95.671 0.0000E+00 walstromite 189 11.509 0.0000E+00 diaspore 66 2.874 0.0000E+00 wollastonite 190 10.461 0.0000E+00 diamond 67 -3.102 0.0000E+00 pseudo-wollastonite 191 11.000 0.0000E+00 diopside 68 16.181 0.0000E+00 zoisite 192 22.849 0.0000E+00 hedenbergite 69 14.208 0.0000E+00 akaganeite 193 7.755 0.0000E+00 dolomite,ordered 70 0.546 0.0000E+00 beidellite-Ca 194 -1.646 0.0000E+00 eastonite 71 28.489 0.0000E+00 beidellite-H 195 -2.326 0.0000E+00 enstatite 72 17.265 0.0000E+00 beidellite-K 196 -1.520 0.0000E+00 clinoenstatite-HiP 73 18.354 0.0000E+00 beidellite-Mg 197 -1.790 0.0000E+00 clinoenstatite 74 17.166 0.0000E+00 beidellite-Na 198 -1.342 0.0000E+00 protoenstatite 75 17.824 0.0000E+00 calcium 199 84.026 0.0000E+00 epidote 76 24.670 0.0000E+00 chalcedony 200 -2.802 0.0000E+00 clinozoisite 77 22.806 0.0000E+00 dawsonite 201 1.682 0.0000E+00 epidote-Fe 78 29.841 0.0000E+00 montmorillonite-Ca 202 -2.291 0.0000E+00 fayalite 79 14.046 0.0000E+00 montmorillonite-K 203 -2.237 0.0000E+00 ferrosilite 80 11.149 0.0000E+00 montmorillonite-Mg 204 -2.480 0.0000E+00 forsterite 81 21.016 0.0000E+00 montmorillonite-Na 205 -2.038 0.0000E+00 gedrite 82 50.522 0.0000E+00 nontronite-Ca 206 3.215 0.0000E+00 gehlenite 83 36.628 0.0000E+00 nontronite-H 207 2.533 0.0000E+00 gibbsite 84 4.079 0.0000E+00 nontronite-K 208 3.341 0.0000E+00 glaucophane 85 22.975 0.0000E+00 nontronite-Mg 209 3.075 0.0000E+00 glaucophane-Fe 86 17.276 0.0000E+00 nontronite-Na 210 3.520 0.0000E+00 graphite 87 -3.546 0.0000E+00 sepiolite 211 24.118 0.0000E+00 greenalite 88 16.140 0.0000E+00 topaz 212 -16.546 0.0000E+00 grunerite 89 31.215 0.0000E+00 alite 213 57.999 0.0000E+00 halite 90 1.575 0.0000E+00 belite 214 30.433 0.0000E+00 hematite 91 12.566 0.0000E+00 ettringite 215 43.232 0.0000E+00 heulandite 92 -5.827 0.0000E+00 gypsum 216 -4.955 0.0000E+00 hercynite 93 17.279 0.0000E+00 hemicarboaluminate 217 70.954 0.0000E+00 hollandite 94 25.673 0.0000E+00 hydrogarnet 218 60.662 0.0000E+00 iron 95 19.086 0.0000E+00 hydrogarnet-Si 219 50.586 0.0000E+00 jadeite 96 4.215 0.0000E+00 jennite 220 24.367 0.0000E+00 julgoldite 97 70.427 0.0000E+00 monosulfoaluminate 221 53.400 0.0000E+00 kalsilite 98 7.584 0.0000E+00 monocarboaluminate 222 61.898 0.0000E+00 kaolinite 99 -1.333 0.0000E+00 portlandite 223 18.272 0.0000E+00 kyanite 100 4.876 0.0000E+00 stratlingite 224 36.502 0.0000E+00 larnite-bredigite 101 30.686 0.0000E+00 tricarboaluminate 225 70.370 0.0000E+00 laumontite 102 2.883 0.0000E+00 tobermorite 226 9.823 0.0000E+00 lawsonite 103 9.616 0.0000E+00 C4AH13 227 81.816 0.0000E+00 leucite 104 4.119 0.0000E+00 C2AH8 228 45.203 0.0000E+00 lime 105 25.998 0.0000E+00 C3A 229 86.953 0.0000E+00 lizardite 106 23.244 0.0000E+00 C4AF 230 117.416 0.0000E+00 magnesite 107 0.691 0.0000E+00 CAH10 231 28.335 0.0000E+00 magnetite 108 20.087 0.0000E+00 alabandite 232 -0.978 0.0000E+00 minnesotaite 109 10.388 0.0000E+00 alunite 233 -10.435 0.0000E+00 minnesotaite-Mg 110 20.602 0.0000E+00 artinite 234 15.121 0.0000E+00 magnesioferrite 111 26.212 0.0000E+00 boehmite 235 4.406 0.0000E+00 majorite 112 53.251 0.0000E+00 dolomite,disordered 236 1.247 0.0000E+00 manganosite 113 14.058 0.0000E+00 ferrous-oxide 237 9.812 0.0000E+00 margarite 114 17.324 0.0000E+00 fluorite 238 -9.931 0.0000E+00 meionite 115 44.874 0.0000E+00 huntite 239 3.770 0.0000E+00 merwinite 116 55.930 0.0000E+00 hydromagnesite 240 19.995 0.0000E+00 microcline 117 -2.486 0.0000E+00 nesquehonite 241 4.723 0.0000E+00 monticellite 118 24.339 0.0000E+00 potassium-oxide 242 69.038 0.0000E+00 mullite-Al 119 363.148 0.0000E+00 silica-amorphous 243 -2.091 0.0000E+00 mullite-Si 120 7.264 0.0000E+00 sodium-oxide 244 55.169 0.0000E+00 muscovite 121 2.582 0.0000E+00 an20ab80 245 2.018 0.0000E+00 paragonite 122 4.239 0.0000E+00 an25ab75 246 2.646 0.0000E+00 nepheline 123 8.339 0.0000E+00 an30ab70 247 3.279 0.0000E+00 osumilite(1) 124 21.717 0.0000E+00 tr.625ac.25prg.125 248 45.165 0.0000E+00 Initial composition of reactant (mole%): H2O 88.87 HCl 0.5900 CO2 7.070 CO 0.1600 H2 1.540 S2 0.8000E-01 SO2 1.150 HF 0.4000E-01 H2S 1.120 0.000 Sum of wt% of reactants: 100.6200 Reactant consumed: 0.0135900 moles log = -1.8668 Original solution: 1000.0103000 g Original solution / Rock added: 73584.28 (Water/Rock Ratio), log = 4.8668 The following minerals and/or gases with identical index are in solid solution: H2O,gas 6 CO2,gas 6 CH4,gas 6 H2,gas 6 H2S,gas 6 S2,gas 6 CO,gas 6 SO3,gas 6 SO2,gas 6 HF,gas 6 HCl,gas 6 almandine 16 pyrope 16 spessartine 16 annite 15 phlogopite 15 biotite-Mn 15 clinochlore 1 daphnite 1 chlorite-Mn 1 diopside 5 hedenbergite 5 epidote 3 clinozoisite 3 iron 9 magnetite 14 talc 7 talc-Fe 7 tremolite 2 ferroactinolite 2 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 10 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 0.0135900 Water: Moles liquid = 0.4986E+02 kg liquid = 0.8983E+00 Moles total = 0.4986E+02 kg total = 0.8982E+00 Activity = 1.0000 Stoichiometric ionic strength = .1220105E-01 Osmotic coef. = 0.9437 True ionic strength = .2078787E-01 Chg. balance for total moles = -.5508E-08 Max. difference allowed = 0.2181E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.11406E-09 -9.9429 0.95616E-10 -10.0195 0.83830E+00 -0.0766 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.24165E-03 -3.6168 0.20132E-03 -3.6961 0.83311E+00 -0.0793 4 SO4-- 0.55546E-04 -4.2553 0.28562E-04 -4.5442 0.51421E+00 -0.2889 5 HCO3- 0.44584E-03 -3.3508 0.37199E-03 -3.4295 0.83436E+00 -0.0786 6 HS- 0.34032E-03 -3.4681 0.28357E-03 -3.5473 0.83323E+00 -0.0792 7 Al+++ 0.13466E-28 -28.8708 0.30414E-29 -29.5169 0.22586E+00 -0.6462 8 H4SiO4 0.88134E-03 -3.0549 0.88134E-03 -3.0549 0.10000E+01 0.0000 9 Ca++ 0.61598E-07 -7.2104 0.31434E-07 -7.5026 0.51032E+00 -0.2922 10 Mg++ 0.22145E-10 -10.6547 0.11248E-10 -10.9489 0.50791E+00 -0.2942 11 Fe++ 0.82375E-13 -13.0842 0.41887E-13 -13.3779 0.50849E+00 -0.2937 12 K+ 0.15657E-03 -3.8053 0.13066E-03 -3.8838 0.83456E+00 -0.0785 13 Na+ 0.19913E-01 -1.7009 0.16587E-01 -1.7802 0.83295E+00 -0.0794 14 Mn++ 0.29986E-10 -10.5231 0.15261E-10 -10.8164 0.50892E+00 -0.2933 15 F- 0.61430E-05 -5.2116 0.51069E-05 -5.2918 0.83134E+00 -0.0802 16 HPO4-- 0.45518E-07 -7.3418 0.23409E-07 -7.6306 0.51428E+00 -0.2888 18 HSiO3- 0.10331E-01 -1.9859 0.86067E-02 -2.0652 0.83311E+00 -0.0793 19 Ca(HSiO3)+ 0.73811E-08 -8.1319 0.61613E-08 -8.2103 0.83475E+00 -0.0784 20 Mg(HSiO3)+ 0.32869E-11 -11.4832 0.27437E-11 -11.5617 0.83475E+00 -0.0784 21 NaHSiO3,aq 0.23089E-02 -2.6366 0.23089E-02 -2.6366 0.10000E+01 0.0000 22 AlO+ 0.54217E-16 -16.2659 0.45258E-16 -16.3443 0.83475E+00 -0.0784 24 HAlO2,aq 0.94262E-10 -10.0257 0.94262E-10 -10.0257 0.10000E+01 0.0000 25 AlO2- 0.26243E-05 -5.5810 0.21822E-05 -5.6611 0.83156E+00 -0.0801 26 CH4,aq 0.36009E-08 -8.4436 0.35875E-08 -8.4452 0.99628E+00 -0.0016 27 C2H6,aq 0.10210E-19 -19.9910 0.10172E-19 -19.9926 0.99628E+00 -0.0016 31 CO,aq 0.41298E-15 -15.3841 0.41298E-15 -15.3841 0.10000E+01 0.0000 32 CO2,aq 0.76286E-07 -7.1176 0.76002E-07 -7.1192 0.99628E+00 -0.0016 33 CO3-2 0.66231E-03 -3.1789 0.33982E-03 -3.4688 0.51308E+00 -0.2898 34 CaCO3,aq 0.13394E-06 -6.8731 0.13394E-06 -6.8731 0.10000E+01 0.0000 35 Ca(HCO3)+ 0.35758E-09 -9.4466 0.29849E-09 -9.5251 0.83475E+00 -0.0784 36 CaCl+ 0.12269E-10 -10.9112 0.10241E-10 -10.9896 0.83475E+00 -0.0784 37 CaCl2,aq 0.48983E-15 -15.3100 0.48983E-15 -15.3100 0.10000E+01 0.0000 38 CaF+ 0.28078E-11 -11.5516 0.23438E-11 -11.6301 0.83475E+00 -0.0784 39 CaOH+ 0.28069E-07 -7.5518 0.23430E-07 -7.6302 0.83475E+00 -0.0784 40 CaSO4,aq 0.28510E-09 -9.5450 0.28510E-09 -9.5450 0.10000E+01 0.0000 41 HCl,aq 0.35274E-14 -14.4525 0.35274E-14 -14.4525 0.10000E+01 0.0000 45 HF,aq 0.33428E-11 -11.4759 0.33428E-11 -11.4759 0.10000E+01 0.0000 46 HF2- 0.69184E-17 -17.1600 0.57637E-17 -17.2393 0.83311E+00 -0.0793 48 FeCl+ 0.15990E-16 -16.7962 0.13347E-16 -16.8746 0.83475E+00 -0.0784 51 FeF+ 0.13095E-16 -16.8829 0.10931E-16 -16.9613 0.83475E+00 -0.0784 53 FeO,aq 0.17806E-09 -9.7494 0.17806E-09 -9.7494 0.10000E+01 0.0000 54 FeOH+ 0.17083E-10 -10.7674 0.14260E-10 -10.8459 0.83475E+00 -0.0784 55 HFeO2- 0.23389E-07 -7.6310 0.19485E-07 -7.7103 0.83311E+00 -0.0793 56 FeO+ 0.87608E-16 -16.0575 0.73131E-16 -16.1359 0.83475E+00 -0.0784 58 FeO2- 0.19647E-08 -8.7067 0.16368E-08 -8.7860 0.83311E+00 -0.0793 59 HFeO2,aq 0.19905E-10 -10.7010 0.19905E-10 -10.7010 0.10000E+01 0.0000 60 H2,aq 0.21711E-06 -6.6633 0.21630E-06 -6.6649 0.99628E+00 -0.0016 61 KCl,aq 0.47676E-09 -9.3217 0.47676E-09 -9.3217 0.10000E+01 0.0000 62 KHSO4,aq 0.10089E-17 -17.9961 0.10089E-17 -17.9961 0.10000E+01 0.0000 63 KOH,aq 0.58359E-06 -6.2339 0.58359E-06 -6.2339 0.10000E+01 0.0000 64 KSO4- 0.69514E-07 -7.1579 0.57913E-07 -7.2372 0.83311E+00 -0.0793 65 MgCO3,aq 0.12013E-10 -10.9203 0.12013E-10 -10.9203 0.10000E+01 0.0000 66 Mg(HCO3)+ 0.13074E-12 -12.8836 0.10913E-12 -12.9620 0.83475E+00 -0.0784 67 MgCl+ 0.39788E-14 -14.4002 0.33213E-14 -14.4787 0.83475E+00 -0.0784 68 MgF+ 0.37216E-14 -14.4293 0.31066E-14 -14.5077 0.83475E+00 -0.0784 69 MgOH+ 0.55575E-10 -10.2551 0.46391E-10 -10.3336 0.83475E+00 -0.0784 71 MnF+ 0.15726E-14 -14.8034 0.13127E-14 -14.8818 0.83475E+00 -0.0784 72 MnO,aq 0.17286E-08 -8.7623 0.17286E-08 -8.7623 0.10000E+01 0.0000 73 MnOH+ 0.57816E-09 -9.2380 0.48262E-09 -9.3164 0.83475E+00 -0.0784 74 MnO2-2 0.12230E-10 -10.9126 0.62749E-11 -11.2024 0.51308E+00 -0.2898 75 HMnO2- 0.15778E-09 -9.8020 0.13145E-09 -9.8813 0.83311E+00 -0.0793 78 MnCl+ 0.22664E-13 -13.6447 0.18919E-13 -13.7231 0.83475E+00 -0.0784 79 MnSO4,aq 0.12583E-12 -12.9002 0.12583E-12 -12.9002 0.10000E+01 0.0000 80 NaCl,aq 0.11066E-05 -5.9560 0.11066E-05 -5.9560 0.10000E+01 0.0000 81 NaF,aq 0.19831E-07 -7.7026 0.19831E-07 -7.7026 0.10000E+01 0.0000 82 NaOH,aq 0.74531E-04 -4.1277 0.74531E-04 -4.1277 0.10000E+01 0.0000 84 OH- 0.72666E-02 -2.1387 0.60426E-02 -2.2188 0.83156E+00 -0.0801 89 HPO3-2 0.30755E-16 -16.5121 0.15780E-16 -16.8019 0.51308E+00 -0.2898 92 H3PO4,aq 0.14968E-17 -17.8248 0.14968E-17 -17.8248 0.10000E+01 0.0000 93 H2PO4- 0.49514E-10 -10.3053 0.41291E-10 -10.3841 0.83392E+00 -0.0789 94 PO4-3 0.84082E-09 -9.0753 0.19975E-09 -9.6995 0.23757E+00 -0.6242 98 HP2O7-3 0.12348E-17 -17.9084 0.27917E-18 -18.5541 0.22609E+00 -0.6457 99 P2O7-4 0.94094E-17 -17.0264 0.69751E-18 -18.1565 0.74128E-01 -1.1300 100 H2S,aq 0.84111E-07 -7.0751 0.83798E-07 -7.0768 0.99628E+00 -0.0016 101 S2-2 0.16054E-10 -10.7944 0.82372E-11 -11.0842 0.51308E+00 -0.2898 102 S3-2 0.83793E-17 -17.0768 0.42993E-17 -17.3666 0.51308E+00 -0.2898 107 SO3-2 0.15418E-11 -11.8120 0.80285E-12 -12.0954 0.52073E+00 -0.2834 108 HSO3- 0.57693E-14 -14.2389 0.48065E-14 -14.3182 0.83311E+00 -0.0793 109 HSO4- 0.31498E-11 -11.5017 0.26319E-11 -11.5797 0.83559E+00 -0.0780 111 S2O3-2 0.54797E-13 -13.2612 0.28116E-13 -13.5511 0.51308E+00 -0.2898 Charge balance for all species = -.6131E-08 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.1140604E-09 -.2065438E-01 -.2078112E+02 0.0000 2 H2O 0.1000000E+01 0.5550296E+02 0.9981128E+06 0.0000 3 Cl- 0.2416498E-03 0.2427569E-03 0.8591057E+01 6.3234 4 SO4-- 0.5554605E-04 0.5555822E-04 0.5327460E+01 15.4947 5 HCO3- 0.4458431E-03 0.1108363E-02 0.6750815E+02 6.5900 6 HS- 0.3403224E-03 0.3404642E-03 0.1123968E+02 6.4721 7 Al+++ 0.1346620E-28 0.2624349E-05 0.7068213E-01 0.5415 8 H4SiO4 0.8813353E-03 0.1352104E-01 0.1297254E+04 -3.0549 9 Ca++ 0.6159758E-07 0.2316450E-06 0.9267251E-02 12.5363 10 Mg++ 0.2214510E-10 0.9315881E-10 0.2260823E-05 9.0900 11 Fe++ 0.8237541E-13 0.2556843E-07 0.1425364E-02 6.6610 12 K+ 0.1565663E-03 0.1572199E-03 0.6136608E+01 6.1356 13 Na+ 0.1991318E-01 0.2229772E-01 0.5117026E+03 8.2392 14 Mn++ 0.2998627E-10 0.2506928E-08 0.1374791E-03 9.2225 15 F- 0.6143009E-05 0.6162846E-05 0.1168722E+00 4.7276 16 HPO4-- 0.4551825E-07 0.4640858E-07 0.4446277E-02 12.4083 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.1856324E-01 -.1855355E-01 -.9688105E-05 0.0000000E+00 2 H2O 0.4985753E+02 0.4985754E+02 -.9659231E-05 0.0000000E+00 3 Cl- 0.2180652E-03 0.2180652E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.4990719E-04 0.4990719E-04 0.0000000E+00 0.0000000E+00 5 HCO3- 0.9956270E-03 0.9956270E-03 0.0000000E+00 0.0000000E+00 6 HS- 0.3058343E-03 0.3058343E-03 0.0000000E+00 0.0000000E+00 7 Al+++ 0.4775352E-05 0.2357416E-05 0.2417936E-05 0.0000000E+00 8 H4SiO4 0.1215302E-01 0.1214576E-01 0.7257657E-05 0.0000000E+00 9 Ca++ 0.2080835E-06 0.2080835E-06 0.0000000E+00 0.0000000E+00 10 Mg++ 0.8368328E-10 0.8368328E-10 0.0000000E+00 0.0000000E+00 11 Fe++ 0.3259227E-07 0.2296777E-07 0.9624504E-08 0.0000000E+00 12 K+ 0.1412294E-03 0.1412284E-03 0.9624504E-09 0.0000000E+00 13 Na+ 0.2003215E-01 0.2002974E-01 0.2414086E-05 0.0000000E+00 14 Mn++ 0.2251939E-08 0.2251939E-08 0.0000000E+00 0.0000000E+00 15 F- 0.5536000E-05 0.5536000E-05 0.0000000E+00 0.0000000E+00 16 HPO4-- 0.4168819E-07 0.4168819E-07 0.0000000E+00 0.0000000E+00 Chg. balance for solid moles: 0.4235E-21 Mass of aqueous solution: 0.899897E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 0.0135900 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 0.2414E-05 -5.617 0.6330E-03 -3.199 99.67 0.2430E-03 stilpnomelane-Fe 0.1925E-08 -8.716 0.2075E-05 -5.683 0.3267 0.7168E-06 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 0.000635 g Volume = 0.000244 cm3 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.0135900 moles log = -1.8668 Original solution: 1000.0103000 g Original solution / Rock added: 73584.28 (Water/Rock Ratio), log = 4.8668 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0206 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9997E+00 0.9859 0.1006E+01 0.1020E+01 CO2,gas 0.7911E-05 1.0071 0.8131E-05 0.8074E-05 CH4,gas 0.5110E-05 1.0125 0.5281E-05 0.5215E-05 H2,gas 0.2781E-03 1.0005 0.2840E-03 0.2838E-03 H2S,gas 0.2266E-05 0.9960 0.2304E-05 0.2313E-05 S2,gas 0.2420E-23 1.0000 0.2470E-23 0.2470E-23 CO,gas 0.6030E-12 1.0000 0.6154E-12 0.6154E-12 SO3,gas 0.9674E-40 1.0000 0.9873E-40 0.9873E-40 SO2,gas 0.1069E-20 1.0000 0.1091E-20 0.1091E-20 HF,gas 0.8042E-14 1.0000 0.8208E-14 0.8208E-14 HCl,gas 0.6099E-17 1.0000 0.6224E-17 0.6224E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 17 albite -0.38 -0.38 0.00 0.000 0.11184E-10 165 stilpnomelane-Fe 13.02 13.02 0.00 0.000 0.21232E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -13.45 -6.79 -2.263 0.11592E+05 -5.090 3 CH4,gas 4.54 -2.43 -6.98 -1.744 0.11912E+05 -5.277 4 H2,gas 8.00 2.75 -5.25 -2.998 0.89569E+04 -3.547 5 H2S,gas -6.23 -13.57 -7.34 -3.668 0.12527E+05 -5.638 6 S2,gas -7.34 -32.64 -25.31 -3.893 0.43210E+05 -23.607 7 CO,gas 3.21 -10.69 -13.91 -4.280 0.23751E+05 -12.211 8 SO3,gas 17.12 -24.58 -41.70 -10.426 0.71209E+05 -40.006 9 SO2,gas 0.83 -21.83 -22.66 -6.043 0.38693E+05 -20.962 10 HF,gas 0.47 -15.31 -15.78 -7.892 0.26952E+05 -14.086 11 HCl,gas 5.19 -13.72 -18.90 -9.452 0.32280E+05 -17.206 12 acmite 7.71 7.41 -0.30 -0.031 0.50581E+03 16 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 20 spessartine 24.46 19.59 -4.87 -0.244 0.83178E+04 21 analcite 3.32 2.67 -0.65 -0.072 0.11113E+04 25 annite 20.12 17.50 -2.63 -0.146 0.44869E+04 26 phlogopite 27.06 24.78 -2.28 -0.127 0.38965E+04 31 apatite-OH -18.15 -20.33 -2.17 -0.167 0.37111E+04 32 apatite-F -34.30 -35.64 -1.34 -0.111 0.22833E+04 36 aragonite 0.97 -0.91 -1.88 -0.626 0.32085E+04 37 brucite 12.57 9.09 -3.48 -0.696 0.59396E+04 38 calcite 0.81 -0.91 -1.72 -0.575 0.29443E+04 39 carnegieite-low 9.02 5.73 -3.30 -0.471 0.56303E+04 40 carnegieite-high 10.09 5.73 -4.37 -0.624 0.74573E+04 41 carpholite-Mg 8.58 4.06 -4.52 -0.301 0.77158E+04 43 celadonite 5.34 3.55 -1.79 -0.106 0.30631E+04 44 celadonite-Fe 3.88 1.12 -2.76 -0.162 0.47089E+04 45 chrysotile 23.89 21.16 -2.73 -0.228 0.46650E+04 47 clinochlore 39.07 37.37 -1.70 -0.053 0.29046E+04 48 daphnite 28.97 25.22 -3.74 -0.117 0.63890E+04 50 chlorite-Al-free 47.17 42.32 -4.85 -0.202 0.82851E+04 52 chloritoid-Fe 9.17 4.69 -4.48 -0.299 0.76572E+04 53 chloritoid-Mn 11.40 7.25 -4.15 -0.277 0.70868E+04 55 coesite -2.38 -3.05 -0.68 -0.226 0.11590E+04 62 cristobalite -2.56 -3.05 -0.49 -0.165 0.84438E+03 64 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71250E+04 66 diaspore 2.87 0.54 -2.33 -0.389 0.39822E+04 67 diamond -3.10 -7.94 -4.84 -1.382 0.82614E+04 68 diopside 16.18 15.52 -0.66 -0.066 0.11350E+04 69 hedenbergite 14.21 13.09 -1.12 -0.112 0.19135E+04 76 epidote 24.67 22.28 -2.39 -0.116 0.40892E+04 78 epidote-Fe 29.84 27.02 -2.82 -0.147 0.48207E+04 79 fayalite 14.05 10.27 -3.78 -0.540 0.64518E+04 80 ferrosilite 11.15 7.21 -3.94 -0.394 0.67226E+04 84 gibbsite 4.08 0.54 -3.54 -0.505 0.60407E+04 85 glaucophane 22.97 20.39 -2.58 -0.070 0.44091E+04 86 glaucophane-Fe 17.28 13.11 -4.17 -0.113 0.71206E+04 87 graphite -3.55 -7.94 -4.39 -1.256 0.75036E+04 88 greenalite 16.14 13.87 -2.27 -0.189 0.38695E+04 91 hematite 12.57 10.57 -2.00 -0.242 0.34119E+04 92 heulandite -5.83 -7.76 -1.94 -0.088 0.33082E+04 96 jadeite 4.22 2.67 -1.54 -0.154 0.26368E+04 97 julgoldite 70.43 66.27 -4.15 -0.108 0.70908E+04 98 kalsilite 7.58 3.62 -3.96 -0.566 0.67644E+04 99 kaolinite -1.33 -5.03 -3.69 -0.336 0.63074E+04 102 laumontite 2.88 1.40 -1.48 -0.099 0.25331E+04 103 lawsonite 9.62 7.51 -2.11 -0.140 0.35968E+04 104 leucite 4.12 0.57 -3.55 -0.355 0.60640E+04 106 lizardite 23.24 21.16 -2.08 -0.174 0.35576E+04 108 magnetite 20.09 17.23 -2.86 -0.233 0.48807E+04 109 minnesotaite 10.39 7.76 -2.62 -0.154 0.44813E+04 113 manganosite 14.06 9.22 -4.84 -1.209 0.82567E+04 117 microcline -2.49 -2.49 0.00 0.000 0.16619E+01 121 muscovite 2.58 -1.40 -3.99 -0.235 0.68076E+04 122 paragonite 4.24 0.70 -3.54 -0.208 0.60450E+04 123 nepheline 8.34 5.73 -2.61 -0.373 0.44627E+04 129 periclase-Fe 11.63 6.66 -4.97 -1.241 0.84786E+04 135 phlogopite-Na 29.65 26.89 -2.76 -0.153 0.47137E+04 137 prehnite 19.37 16.99 -2.38 -0.140 0.40652E+04 138 prehnite-Fe 22.50 21.73 -0.76 -0.046 0.13050E+04 143 pyrite -21.25 -23.23 -1.98 -0.466 0.33804E+04 144 pyrrhotite -4.26 -6.91 -2.65 -0.882 0.45171E+04 145 pyrrhotiteFe0.875 -6.02 -8.08 -2.06 -0.759 0.35225E+04 146 pyroxmangite 7.40 6.17 -1.23 -0.246 0.21020E+04 147 pyrophyllite -6.18 -11.14 -4.96 -0.310 0.84702E+04 148 quartz -2.99 -3.05 -0.07 -0.022 0.11171E+03 152 rhodochrosite -0.98 -4.23 -3.25 -1.083 0.55495E+04 153 rhodonite 7.45 6.17 -1.28 -0.256 0.21822E+04 154 sanidine -1.28 -2.49 -1.21 -0.093 0.20694E+04 156 siderite -2.61 -6.79 -4.18 -1.393 0.71369E+04 164 stilbite -7.52 -7.76 -0.24 -0.012 0.41433E+03 166 stilpnomelane-Mg 27.44 25.16 -2.28 -0.068 0.38922E+04 172 talc 16.49 15.05 -1.44 -0.085 0.24596E+04 175 tephroite 18.09 15.39 -2.70 -0.385 0.46027E+04 179 tridymite -2.63 -3.05 -0.43 -0.143 0.73169E+03 180 tremolite 47.87 46.08 -1.79 -0.048 0.30486E+04 181 ferroactinolite 38.45 33.94 -4.51 -0.122 0.77067E+04 182 troilite-low -4.41 -6.91 -2.49 -0.832 0.42599E+04 188 wairakite 3.95 1.40 -2.55 -0.150 0.43551E+04 189 walstromite 11.51 9.48 -2.03 -0.406 0.34623E+04 190 wollastonite 10.46 9.48 -0.98 -0.196 0.16728E+04 191 pseudo-wollastonite 11.00 9.48 -1.52 -0.304 0.25926E+04 193 akaganeite 7.75 5.28 -2.47 -0.534 0.42185E+04 200 chalcedony -2.80 -3.05 -0.25 -0.084 0.43101E+03 202 montmorillonite-Ca -2.29 -6.25 -3.96 -0.245 0.67552E+04 203 montmorillonite-K -2.24 -6.29 -4.05 -0.248 0.69221E+04 204 montmorillonite-Mg -2.48 -6.82 -4.34 -0.268 0.74031E+04 205 montmorillonite-Na -2.04 -5.60 -3.56 -0.218 0.60764E+04 206 nontronite-Ca 3.21 1.60 -1.61 -0.104 0.27503E+04 207 nontronite-H 2.53 -0.46 -3.00 -0.201 0.51180E+04 208 nontronite-K 3.34 1.56 -1.78 -0.114 0.30404E+04 209 nontronite-Mg 3.07 1.04 -2.04 -0.132 0.34823E+04 210 nontronite-Na 3.52 2.25 -1.27 -0.081 0.21607E+04 226 tobermorite 9.82 7.39 -2.44 -0.664 0.41579E+04 232 alabandite -0.98 -4.34 -3.37 -1.122 0.57481E+04 235 boehmite 4.41 0.54 -3.86 -0.644 0.65991E+04 237 ferrous-oxide 9.81 6.66 -3.15 -0.788 0.53795E+04 243 silica-amorphous -2.09 -3.05 -0.96 -0.321 0.16452E+04 245 an20ab80 2.02 1.19 -0.82 -0.063 0.14052E+04 246 an25ab75 2.65 1.59 -1.06 -0.081 0.18034E+04 247 an30ab70 3.28 1.98 -1.30 -0.100 0.22113E+04 248 tr.625ac.25prg.125 45.16 43.91 -1.26 -0.034 0.21458E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 0.0004000 MOLES Current total amount of reactant added: 0.0135900 MOLES New total amount of reactant added: 0.0139900 MOLES Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.5508E-08 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 7 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 0.0139900 Water: Moles liquid = 0.4986E+02 kg liquid = 0.8983E+00 Moles total = 0.4986E+02 kg total = 0.8982E+00 Activity = 1.0000 Stoichiometric ionic strength = .1222678E-01 Osmotic coef. = 0.9434 True ionic strength = .2080878E-01 Chg. balance for total moles = -.5508E-08 Max. difference allowed = 0.2204E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.11499E-09 -9.9393 0.96389E-10 -10.0160 0.83824E+00 -0.0766 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.24426E-03 -3.6121 0.20348E-03 -3.6915 0.83305E+00 -0.0793 4 SO4-- 0.57669E-04 -4.2391 0.29646E-04 -4.5280 0.51407E+00 -0.2890 5 HCO3- 0.46094E-03 -3.3364 0.38457E-03 -3.4150 0.83431E+00 -0.0787 6 HS- 0.34901E-03 -3.4572 0.29079E-03 -3.5364 0.83318E+00 -0.0793 7 Al+++ 0.13607E-28 -28.8662 0.30715E-29 -29.5127 0.22572E+00 -0.6464 8 H4SiO4 0.88792E-03 -3.0516 0.88792E-03 -3.0516 0.10000E+01 0.0000 9 Ca++ 0.60766E-07 -7.2163 0.31002E-07 -7.5086 0.51018E+00 -0.2923 10 Mg++ 0.22181E-10 -10.6540 0.11263E-10 -10.9483 0.50777E+00 -0.2943 11 Fe++ 0.83285E-13 -13.0794 0.42338E-13 -13.3733 0.50835E+00 -0.2938 12 K+ 0.15657E-03 -3.8053 0.13066E-03 -3.8839 0.83451E+00 -0.0786 13 Na+ 0.19915E-01 -1.7008 0.16587E-01 -1.7802 0.83289E+00 -0.0794 14 Mn++ 0.30435E-10 -10.5166 0.15485E-10 -10.8101 0.50878E+00 -0.2935 15 F- 0.63205E-05 -5.1992 0.52541E-05 -5.2795 0.83128E+00 -0.0803 16 HPO4-- 0.45524E-07 -7.3418 0.23406E-07 -7.6307 0.51415E+00 -0.2889 18 HSiO3- 0.10325E-01 -1.9861 0.86015E-02 -2.0654 0.83305E+00 -0.0793 19 Ca(HSiO3)+ 0.72756E-08 -8.1381 0.60729E-08 -8.2166 0.83469E+00 -0.0785 20 Mg(HSiO3)+ 0.32895E-11 -11.4829 0.27458E-11 -11.5613 0.83469E+00 -0.0785 21 NaHSiO3,aq 0.23075E-02 -2.6369 0.23075E-02 -2.6369 0.10000E+01 0.0000 22 AlO+ 0.53882E-16 -16.2686 0.44975E-16 -16.3470 0.83469E+00 -0.0785 24 HAlO2,aq 0.92923E-10 -10.0319 0.92923E-10 -10.0319 0.10000E+01 0.0000 25 AlO2- 0.25664E-05 -5.5907 0.21340E-05 -5.6708 0.83150E+00 -0.0801 26 CH4,aq 0.36778E-08 -8.4344 0.36641E-08 -8.4360 0.99628E+00 -0.0016 27 C2H6,aq 0.10705E-19 -19.9704 0.10665E-19 -19.9721 0.99628E+00 -0.0016 31 CO,aq 0.42822E-15 -15.3683 0.42822E-15 -15.3683 0.10000E+01 0.0000 32 CO2,aq 0.79501E-07 -7.0996 0.79205E-07 -7.1012 0.99628E+00 -0.0016 33 CO3-2 0.67939E-03 -3.1679 0.34849E-03 -3.4578 0.51295E+00 -0.2899 34 CaCO3,aq 0.13547E-06 -6.8682 0.13547E-06 -6.8682 0.10000E+01 0.0000 35 Ca(HCO3)+ 0.36460E-09 -9.4382 0.30433E-09 -9.5167 0.83469E+00 -0.0785 36 CaCl+ 0.12231E-10 -10.9125 0.10209E-10 -10.9910 0.83469E+00 -0.0785 37 CaCl2,aq 0.49353E-15 -15.3067 0.49353E-15 -15.3067 0.10000E+01 0.0000 38 CaF+ 0.28491E-11 -11.5453 0.23782E-11 -11.6238 0.83469E+00 -0.0785 39 CaOH+ 0.27462E-07 -7.5613 0.22923E-07 -7.6397 0.83469E+00 -0.0785 40 CaSO4,aq 0.29185E-09 -9.5348 0.29185E-09 -9.5348 0.10000E+01 0.0000 41 HCl,aq 0.35941E-14 -14.4444 0.35941E-14 -14.4444 0.10000E+01 0.0000 45 HF,aq 0.34669E-11 -11.4601 0.34669E-11 -11.4601 0.10000E+01 0.0000 46 HF2- 0.73826E-17 -17.1318 0.61501E-17 -17.2111 0.83305E+00 -0.0793 48 FeCl+ 0.16337E-16 -16.7868 0.13636E-16 -16.8653 0.83469E+00 -0.0785 51 FeF+ 0.13619E-16 -16.8659 0.11367E-16 -16.9443 0.83469E+00 -0.0785 53 FeO,aq 0.17711E-09 -9.7518 0.17711E-09 -9.7518 0.10000E+01 0.0000 54 FeOH+ 0.17129E-10 -10.7663 0.14298E-10 -10.8447 0.83469E+00 -0.0785 55 HFeO2- 0.23078E-07 -7.6368 0.19225E-07 -7.7161 0.83305E+00 -0.0793 56 FeO+ 0.88070E-16 -16.0552 0.73511E-16 -16.1336 0.83469E+00 -0.0785 58 FeO2- 0.19435E-08 -8.7114 0.16190E-08 -8.7907 0.83305E+00 -0.0793 59 HFeO2,aq 0.19848E-10 -10.7023 0.19848E-10 -10.7023 0.10000E+01 0.0000 60 H2,aq 0.21602E-06 -6.6655 0.21522E-06 -6.6671 0.99628E+00 -0.0016 61 KCl,aq 0.48186E-09 -9.3171 0.48186E-09 -9.3171 0.10000E+01 0.0000 62 KHSO4,aq 0.10556E-17 -17.9765 0.10556E-17 -17.9765 0.10000E+01 0.0000 63 KOH,aq 0.57888E-06 -6.2374 0.57888E-06 -6.2374 0.10000E+01 0.0000 64 KSO4- 0.72152E-07 -7.1417 0.60107E-07 -7.2211 0.83305E+00 -0.0793 65 MgCO3,aq 0.12336E-10 -10.9088 0.12336E-10 -10.9088 0.10000E+01 0.0000 66 Mg(HCO3)+ 0.13535E-12 -12.8685 0.11297E-12 -12.9470 0.83469E+00 -0.0785 67 MgCl+ 0.40273E-14 -14.3950 0.33615E-14 -14.4735 0.83469E+00 -0.0785 68 MgF+ 0.38343E-14 -14.4163 0.32005E-14 -14.4948 0.83469E+00 -0.0785 69 MgOH+ 0.55208E-10 -10.2580 0.46082E-10 -10.3365 0.83469E+00 -0.0785 71 MnF+ 0.16418E-14 -14.7847 0.13704E-14 -14.8632 0.83469E+00 -0.0785 72 MnO,aq 0.17260E-08 -8.7630 0.17260E-08 -8.7630 0.10000E+01 0.0000 73 MnOH+ 0.58199E-09 -9.2351 0.48578E-09 -9.3136 0.83469E+00 -0.0785 74 MnO2-2 0.12020E-10 -10.9201 0.61654E-11 -11.2100 0.51295E+00 -0.2899 75 HMnO2- 0.15629E-09 -9.8061 0.13020E-09 -9.8854 0.83305E+00 -0.0793 78 MnCl+ 0.23246E-13 -13.6337 0.19403E-13 -13.7121 0.83469E+00 -0.0785 79 MnSO4,aq 0.13253E-12 -12.8777 0.13253E-12 -12.8777 0.10000E+01 0.0000 80 NaCl,aq 0.11185E-05 -5.9513 0.11185E-05 -5.9513 0.10000E+01 0.0000 81 NaF,aq 0.20403E-07 -7.6903 0.20403E-07 -7.6903 0.10000E+01 0.0000 82 NaOH,aq 0.73936E-04 -4.1311 0.73936E-04 -4.1311 0.10000E+01 0.0000 84 OH- 0.72089E-02 -2.1421 0.59942E-02 -2.2223 0.83150E+00 -0.0801 89 HPO3-2 0.30604E-16 -16.5142 0.15698E-16 -16.8041 0.51295E+00 -0.2899 92 H3PO4,aq 0.15209E-17 -17.8179 0.15209E-17 -17.8179 0.10000E+01 0.0000 93 H2PO4- 0.49910E-10 -10.3018 0.41618E-10 -10.3807 0.83386E+00 -0.0789 94 PO4-3 0.83444E-09 -9.0786 0.19812E-09 -9.7031 0.23743E+00 -0.6245 98 HP2O7-3 0.12451E-17 -17.9048 0.28135E-18 -18.5508 0.22596E+00 -0.6460 99 P2O7-4 0.94167E-17 -17.0261 0.69731E-18 -18.1566 0.74050E-01 -1.1305 100 H2S,aq 0.86950E-07 -7.0607 0.86626E-07 -7.0624 0.99628E+00 -0.0016 101 S2-2 0.16972E-10 -10.7703 0.87057E-11 -11.0602 0.51295E+00 -0.2899 102 S3-2 0.92035E-17 -17.0360 0.47209E-17 -17.3260 0.51295E+00 -0.2899 107 SO3-2 0.15927E-11 -11.7979 0.82913E-12 -12.0814 0.52059E+00 -0.2835 108 HSO3- 0.60067E-14 -14.2214 0.50039E-14 -14.3007 0.83305E+00 -0.0793 109 HSO4- 0.32959E-11 -11.4820 0.27539E-11 -11.5601 0.83553E+00 -0.0780 111 S2O3-2 0.58811E-13 -13.2305 0.30167E-13 -13.5205 0.51295E+00 -0.2899 Charge balance for all species = -.6131E-08 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.1149887E-09 -.2060605E-01 -.2073245E+02 0.0000 2 H2O 0.1000000E+01 0.5550291E+02 0.9981103E+06 0.0000 3 Cl- 0.2442633E-03 0.2453823E-03 0.8683954E+01 6.3245 4 SO4-- 0.5766905E-04 0.5768406E-04 0.5531297E+01 15.5039 5 HCO3- 0.4609429E-03 0.1140549E-02 0.6946842E+02 6.6009 6 HS- 0.3490115E-03 0.3491559E-03 0.1152660E+02 6.4796 7 Al+++ 0.1360747E-28 0.2566535E-05 0.6912492E-01 0.5353 8 H4SiO4 0.8879189E-03 0.1352076E-01 0.1297225E+04 -3.0516 9 Ca++ 0.6076631E-07 0.2316432E-06 0.9267167E-02 12.5233 10 Mg++ 0.2218105E-10 0.9315811E-10 0.2260803E-05 9.0836 11 Fe++ 0.8328517E-13 0.2523607E-07 0.1406834E-02 6.6587 12 K+ 0.1565671E-03 0.1572186E-03 0.6136551E+01 6.1321 13 Na+ 0.1991489E-01 0.2229750E-01 0.5116967E+03 8.2357 14 Mn++ 0.3043494E-10 0.2506909E-08 0.1374779E-03 9.2219 15 F- 0.6320506E-05 0.6340915E-05 0.1202489E+00 4.7365 16 HPO4-- 0.4552388E-07 0.4640823E-07 0.4446236E-02 12.4013 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.1852017E-01 -.1851027E-01 -.9896274E-05 0.0000000E+00 2 H2O 0.4985786E+02 0.4985787E+02 -.9866506E-05 0.0000000E+00 3 Cl- 0.2204252E-03 0.2204252E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.5181719E-04 0.5181719E-04 0.0000000E+00 0.0000000E+00 5 HCO3- 0.1024547E-02 0.1024547E-02 0.0000000E+00 0.0000000E+00 6 HS- 0.3136443E-03 0.3136443E-03 0.0000000E+00 0.0000000E+00 7 Al+++ 0.4775352E-05 0.2305501E-05 0.2469851E-05 0.0000000E+00 8 H4SiO4 0.1215302E-01 0.1214561E-01 0.7413523E-05 0.0000000E+00 9 Ca++ 0.2080835E-06 0.2080835E-06 0.0000000E+00 0.0000000E+00 10 Mg++ 0.8368328E-10 0.8368328E-10 0.0000000E+00 0.0000000E+00 11 Fe++ 0.3259227E-07 0.2266938E-07 0.9922889E-08 0.0000000E+00 12 K+ 0.1412294E-03 0.1412284E-03 0.9922889E-09 0.0000000E+00 13 Na+ 0.2003215E-01 0.2002968E-01 0.2465882E-05 0.0000000E+00 14 Mn++ 0.2251939E-08 0.2251939E-08 0.0000000E+00 0.0000000E+00 15 F- 0.5696000E-05 0.5696000E-05 0.0000000E+00 0.0000000E+00 16 HPO4-- 0.4168819E-07 0.4168819E-07 0.0000000E+00 0.0000000E+00 Chg. balance for solid moles: -.4235E-21 Mass of aqueous solution: 0.899905E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 0.0139900 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 0.2466E-05 -5.608 0.6466E-03 -3.189 99.67 0.2482E-03 stilpnomelane-Fe 0.1985E-08 -8.702 0.2139E-05 -5.670 0.3298 0.7390E-06 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 0.000649 g Volume = 0.000249 cm3 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.0139900 moles log = -1.8542 Original solution: 1000.0103000 g Original solution / Rock added: 71480.36 (Water/Rock Ratio), log = 4.8542 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0206 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9997E+00 0.9859 0.1006E+01 0.1020E+01 CO2,gas 0.8245E-05 1.0071 0.8474E-05 0.8414E-05 CH4,gas 0.5219E-05 1.0125 0.5393E-05 0.5327E-05 H2,gas 0.2767E-03 1.0005 0.2826E-03 0.2824E-03 H2S,gas 0.2343E-05 0.9960 0.2381E-05 0.2391E-05 S2,gas 0.2612E-23 1.0000 0.2666E-23 0.2666E-23 CO,gas 0.6253E-12 1.0000 0.6381E-12 0.6381E-12 SO3,gas 0.1020E-39 1.0000 0.1041E-39 0.1041E-39 SO2,gas 0.1122E-20 1.0000 0.1145E-20 0.1145E-20 HF,gas 0.8341E-14 1.0000 0.8513E-14 0.8513E-14 HCl,gas 0.6214E-17 1.0000 0.6342E-17 0.6342E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 17 albite -0.38 -0.38 0.00 0.000 -0.94784E-12 165 stilpnomelane-Fe 13.02 13.02 0.00 0.000 -0.27298E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -13.43 -6.77 -2.257 0.11561E+05 -5.072 3 CH4,gas 4.54 -2.42 -6.97 -1.742 0.11896E+05 -5.268 4 H2,gas 8.00 2.75 -5.25 -2.999 0.89606E+04 -3.549 5 H2S,gas -6.23 -13.55 -7.32 -3.661 0.12502E+05 -5.623 6 S2,gas -7.34 -32.61 -25.27 -3.888 0.43153E+05 -23.574 7 CO,gas 3.21 -10.68 -13.89 -4.275 0.23724E+05 -12.195 8 SO3,gas 17.12 -24.56 -41.68 -10.420 0.71170E+05 -39.982 9 SO2,gas 0.83 -21.81 -22.64 -6.037 0.38658E+05 -20.941 10 HF,gas 0.47 -15.30 -15.77 -7.884 0.26925E+05 -14.070 11 HCl,gas 5.19 -13.71 -18.90 -9.448 0.32266E+05 -17.198 12 acmite 7.71 7.42 -0.29 -0.031 0.50284E+03 16 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 20 spessartine 24.46 19.58 -4.88 -0.244 0.83258E+04 21 analcite 3.32 2.67 -0.65 -0.073 0.11169E+04 25 annite 20.12 17.49 -2.63 -0.146 0.44990E+04 26 phlogopite 27.06 24.76 -2.30 -0.128 0.39294E+04 31 apatite-OH -18.15 -20.37 -2.22 -0.171 0.37867E+04 32 apatite-F -34.30 -35.67 -1.37 -0.114 0.23319E+04 36 aragonite 0.97 -0.91 -1.87 -0.625 0.32001E+04 37 brucite 12.57 9.08 -3.48 -0.697 0.59505E+04 38 calcite 0.81 -0.91 -1.72 -0.573 0.29359E+04 39 carnegieite-low 9.02 5.72 -3.30 -0.472 0.56413E+04 40 carnegieite-high 10.09 5.72 -4.37 -0.625 0.74683E+04 41 carpholite-Mg 8.58 4.05 -4.53 -0.302 0.77369E+04 43 celadonite 5.34 3.54 -1.80 -0.106 0.30686E+04 44 celadonite-Fe 3.88 1.12 -2.76 -0.162 0.47075E+04 45 chrysotile 23.89 21.15 -2.74 -0.229 0.46867E+04 47 clinochlore 39.07 37.33 -1.74 -0.054 0.29639E+04 48 daphnite 28.97 25.21 -3.76 -0.117 0.64136E+04 50 chlorite-Al-free 47.17 42.30 -4.88 -0.203 0.83286E+04 52 chloritoid-Fe 9.17 4.68 -4.50 -0.300 0.76768E+04 53 chloritoid-Mn 11.40 7.24 -4.16 -0.277 0.71036E+04 55 coesite -2.38 -3.05 -0.68 -0.225 0.11535E+04 62 cristobalite -2.56 -3.05 -0.49 -0.164 0.83886E+03 64 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71251E+04 66 diaspore 2.87 0.54 -2.34 -0.390 0.39928E+04 67 diamond -3.10 -7.93 -4.82 -1.379 0.82383E+04 68 diopside 16.18 15.50 -0.68 -0.068 0.11571E+04 69 hedenbergite 14.21 13.08 -1.13 -0.113 0.19286E+04 76 epidote 24.67 22.25 -2.42 -0.118 0.41404E+04 78 epidote-Fe 29.84 26.99 -2.85 -0.148 0.48634E+04 79 fayalite 14.05 10.27 -3.78 -0.540 0.64543E+04 80 ferrosilite 11.15 7.21 -3.94 -0.394 0.67195E+04 84 gibbsite 4.08 0.54 -3.54 -0.506 0.60513E+04 85 glaucophane 22.97 20.38 -2.59 -0.070 0.44309E+04 86 glaucophane-Fe 17.28 13.11 -4.17 -0.113 0.71215E+04 87 graphite -3.55 -7.93 -4.38 -1.252 0.74805E+04 88 greenalite 16.14 13.87 -2.27 -0.189 0.38704E+04 91 hematite 12.57 10.57 -2.00 -0.243 0.34162E+04 92 heulandite -5.83 -7.77 -1.94 -0.088 0.33129E+04 96 jadeite 4.22 2.67 -1.55 -0.155 0.26423E+04 97 julgoldite 70.43 66.23 -4.20 -0.109 0.71630E+04 98 kalsilite 7.58 3.62 -3.97 -0.567 0.67755E+04 99 kaolinite -1.33 -5.03 -3.70 -0.336 0.63175E+04 102 laumontite 2.88 1.39 -1.50 -0.100 0.25544E+04 103 lawsonite 9.62 7.49 -2.13 -0.142 0.36291E+04 104 leucite 4.12 0.56 -3.55 -0.355 0.60696E+04 106 lizardite 23.24 21.15 -2.10 -0.175 0.35794E+04 108 magnetite 20.09 17.22 -2.86 -0.234 0.48889E+04 109 minnesotaite 10.39 7.77 -2.62 -0.154 0.44712E+04 113 manganosite 14.06 9.22 -4.84 -1.209 0.82578E+04 117 microcline -2.49 -2.49 0.00 0.000 0.17202E+01 121 muscovite 2.58 -1.42 -4.00 -0.235 0.68288E+04 122 paragonite 4.24 0.69 -3.55 -0.209 0.60662E+04 123 nepheline 8.34 5.72 -2.62 -0.374 0.44737E+04 129 periclase-Fe 11.63 6.66 -4.97 -1.242 0.84826E+04 135 phlogopite-Na 29.65 26.87 -2.78 -0.154 0.47465E+04 137 prehnite 19.37 16.96 -2.41 -0.142 0.41142E+04 138 prehnite-Fe 22.50 21.71 -0.79 -0.047 0.13456E+04 143 pyrite -21.25 -23.20 -1.95 -0.459 0.33314E+04 144 pyrrhotite -4.26 -6.89 -2.63 -0.878 0.44965E+04 145 pyrrhotiteFe0.875 -6.02 -8.07 -2.05 -0.754 0.35009E+04 146 pyroxmangite 7.40 6.17 -1.23 -0.246 0.20975E+04 147 pyrophyllite -6.18 -11.14 -4.96 -0.310 0.84693E+04 148 quartz -2.99 -3.05 -0.06 -0.021 0.10619E+03 152 rhodochrosite -0.98 -4.21 -3.23 -1.078 0.55200E+04 153 rhodonite 7.45 6.17 -1.28 -0.255 0.21778E+04 154 sanidine -1.28 -2.49 -1.21 -0.093 0.20695E+04 156 siderite -2.61 -6.77 -4.16 -1.388 0.71102E+04 164 stilbite -7.52 -7.77 -0.25 -0.012 0.41911E+03 166 stilpnomelane-Mg 27.44 25.14 -2.30 -0.069 0.39269E+04 172 talc 16.49 15.04 -1.45 -0.085 0.24703E+04 175 tephroite 18.09 15.39 -2.69 -0.385 0.45994E+04 179 tridymite -2.63 -3.05 -0.43 -0.142 0.72617E+03 180 tremolite 47.87 46.05 -1.82 -0.049 0.31035E+04 181 ferroactinolite 38.45 33.93 -4.53 -0.122 0.77269E+04 182 troilite-low -4.41 -6.89 -2.48 -0.828 0.42393E+04 188 wairakite 3.95 1.39 -2.56 -0.151 0.43764E+04 189 walstromite 11.51 9.47 -2.04 -0.408 0.34790E+04 190 wollastonite 10.46 9.47 -0.99 -0.198 0.16894E+04 191 pseudo-wollastonite 11.00 9.47 -1.53 -0.306 0.26093E+04 193 akaganeite 7.75 5.28 -2.47 -0.534 0.42206E+04 200 chalcedony -2.80 -3.05 -0.25 -0.083 0.42549E+03 202 montmorillonite-Ca -2.29 -6.25 -3.96 -0.245 0.67581E+04 203 montmorillonite-K -2.24 -6.29 -4.05 -0.248 0.69233E+04 204 montmorillonite-Mg -2.48 -6.82 -4.34 -0.268 0.74042E+04 205 montmorillonite-Na -2.04 -5.60 -3.56 -0.218 0.60776E+04 206 nontronite-Ca 3.21 1.61 -1.61 -0.104 0.27415E+04 207 nontronite-H 2.53 -0.46 -2.99 -0.200 0.51055E+04 208 nontronite-K 3.34 1.57 -1.77 -0.114 0.30299E+04 209 nontronite-Mg 3.07 1.04 -2.03 -0.132 0.34716E+04 210 nontronite-Na 3.52 2.26 -1.26 -0.081 0.21502E+04 226 tobermorite 9.82 7.38 -2.44 -0.667 0.41709E+04 232 alabandite -0.98 -4.33 -3.35 -1.118 0.57246E+04 235 boehmite 4.41 0.54 -3.87 -0.645 0.66097E+04 237 ferrous-oxide 9.81 6.66 -3.15 -0.788 0.53835E+04 243 silica-amorphous -2.09 -3.05 -0.96 -0.320 0.16397E+04 245 an20ab80 2.02 1.19 -0.83 -0.064 0.14116E+04 246 an25ab75 2.65 1.58 -1.06 -0.082 0.18115E+04 247 an30ab70 3.28 1.98 -1.30 -0.100 0.22210E+04 248 tr.625ac.25prg.125 45.16 43.88 -1.29 -0.035 0.21968E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 0.0004000 MOLES Current total amount of reactant added: 0.0139900 MOLES New total amount of reactant added: 0.0143900 MOLES Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.5508E-08 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 7 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 0.0143900 Water: Moles liquid = 0.4986E+02 kg liquid = 0.8983E+00 Moles total = 0.4986E+02 kg total = 0.8982E+00 Activity = 1.0000 Stoichiometric ionic strength = .1225251E-01 Osmotic coef. = 0.9431 True ionic strength = .2082956E-01 Chg. balance for total moles = -.5508E-08 Max. difference allowed = 0.2228E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.11593E-09 -9.9358 0.97170E-10 -10.0125 0.83819E+00 -0.0767 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.24688E-03 -3.6075 0.20565E-03 -3.6869 0.83299E+00 -0.0794 4 SO4-- 0.59792E-04 -4.2234 0.30729E-04 -4.5124 0.51394E+00 -0.2891 5 HCO3- 0.47618E-03 -3.3222 0.39725E-03 -3.4009 0.83425E+00 -0.0787 6 HS- 0.35770E-03 -3.4465 0.29801E-03 -3.5258 0.83312E+00 -0.0793 7 Al+++ 0.13751E-28 -28.8617 0.31020E-29 -29.5084 0.22558E+00 -0.6467 8 H4SiO4 0.89458E-03 -3.0484 0.89458E-03 -3.0484 0.10000E+01 0.0000 9 Ca++ 0.59965E-07 -7.2221 0.30585E-07 -7.5145 0.51004E+00 -0.2924 10 Mg++ 0.22217E-10 -10.6533 0.11278E-10 -10.9478 0.50764E+00 -0.2944 11 Fe++ 0.84209E-13 -13.0746 0.42796E-13 -13.3686 0.50821E+00 -0.2940 12 K+ 0.15657E-03 -3.8053 0.13065E-03 -3.8839 0.83445E+00 -0.0786 13 Na+ 0.19917E-01 -1.7008 0.16587E-01 -1.7802 0.83284E+00 -0.0794 14 Mn++ 0.30892E-10 -10.5102 0.15713E-10 -10.8037 0.50864E+00 -0.2936 15 F- 0.64980E-05 -5.1872 0.54013E-05 -5.2675 0.83122E+00 -0.0803 16 HPO4-- 0.45529E-07 -7.3417 0.23403E-07 -7.6307 0.51401E+00 -0.2890 18 HSiO3- 0.10320E-01 -1.9863 0.85963E-02 -2.0657 0.83299E+00 -0.0794 19 Ca(HSiO3)+ 0.71738E-08 -8.1443 0.59875E-08 -8.2228 0.83464E+00 -0.0785 20 Mg(HSiO3)+ 0.32922E-11 -11.4825 0.27478E-11 -11.5610 0.83464E+00 -0.0785 21 NaHSiO3,aq 0.23062E-02 -2.6371 0.23062E-02 -2.6371 0.10000E+01 0.0000 22 AlO+ 0.53549E-16 -16.2713 0.44694E-16 -16.3498 0.83464E+00 -0.0785 24 HAlO2,aq 0.91599E-10 -10.0381 0.91599E-10 -10.0381 0.10000E+01 0.0000 25 AlO2- 0.25097E-05 -5.6004 0.20867E-05 -5.6805 0.83144E+00 -0.0802 26 CH4,aq 0.37562E-08 -8.4252 0.37422E-08 -8.4269 0.99627E+00 -0.0016 27 C2H6,aq 0.11220E-19 -19.9500 0.11178E-19 -19.9516 0.99627E+00 -0.0016 31 CO,aq 0.44377E-15 -15.3528 0.44377E-15 -15.3528 0.10000E+01 0.0000 32 CO2,aq 0.82790E-07 -7.0820 0.82481E-07 -7.0836 0.99627E+00 -0.0016 33 CO3-2 0.69633E-03 -3.1572 0.35709E-03 -3.4472 0.51281E+00 -0.2900 34 CaCO3,aq 0.13694E-06 -6.8635 0.13694E-06 -6.8635 0.10000E+01 0.0000 35 Ca(HCO3)+ 0.37158E-09 -9.4299 0.31013E-09 -9.5084 0.83464E+00 -0.0785 36 CaCl+ 0.12195E-10 -10.9138 0.10179E-10 -10.9923 0.83464E+00 -0.0785 37 CaCl2,aq 0.49730E-15 -15.3034 0.49730E-15 -15.3034 0.10000E+01 0.0000 38 CaF+ 0.28897E-11 -11.5391 0.24119E-11 -11.6176 0.83464E+00 -0.0785 39 CaOH+ 0.26876E-07 -7.5706 0.22432E-07 -7.6491 0.83464E+00 -0.0785 40 CaSO4,aq 0.29844E-09 -9.5251 0.29844E-09 -9.5251 0.10000E+01 0.0000 41 HCl,aq 0.36618E-14 -14.4363 0.36618E-14 -14.4363 0.10000E+01 0.0000 45 HF,aq 0.35929E-11 -11.4445 0.35929E-11 -11.4445 0.10000E+01 0.0000 46 HF2- 0.78658E-17 -17.1043 0.65521E-17 -17.1836 0.83299E+00 -0.0794 48 FeCl+ 0.16690E-16 -16.7775 0.13930E-16 -16.8560 0.83464E+00 -0.0785 51 FeF+ 0.14153E-16 -16.8492 0.11812E-16 -16.9277 0.83464E+00 -0.0785 53 FeO,aq 0.17616E-09 -9.7541 0.17616E-09 -9.7541 0.10000E+01 0.0000 54 FeOH+ 0.17176E-10 -10.7651 0.14336E-10 -10.8436 0.83464E+00 -0.0785 55 HFeO2- 0.22771E-07 -7.6426 0.18968E-07 -7.7220 0.83299E+00 -0.0794 56 FeO+ 0.88527E-16 -16.0529 0.73888E-16 -16.1314 0.83464E+00 -0.0785 58 FeO2- 0.19223E-08 -8.7162 0.16012E-08 -8.7955 0.83299E+00 -0.0794 59 HFeO2,aq 0.19789E-10 -10.7036 0.19789E-10 -10.7036 0.10000E+01 0.0000 60 H2,aq 0.21498E-06 -6.6676 0.21417E-06 -6.6692 0.99627E+00 -0.0016 61 KCl,aq 0.48695E-09 -9.3125 0.48695E-09 -9.3125 0.10000E+01 0.0000 62 KHSO4,aq 0.11030E-17 -17.9574 0.11030E-17 -17.9574 0.10000E+01 0.0000 63 KOH,aq 0.57419E-06 -6.2409 0.57419E-06 -6.2409 0.10000E+01 0.0000 64 KSO4- 0.74789E-07 -7.1262 0.62299E-07 -7.2055 0.83299E+00 -0.0794 65 MgCO3,aq 0.12658E-10 -10.8976 0.12658E-10 -10.8976 0.10000E+01 0.0000 66 Mg(HCO3)+ 0.14001E-12 -12.8538 0.11686E-12 -12.9323 0.83464E+00 -0.0785 67 MgCl+ 0.40759E-14 -14.3898 0.34019E-14 -14.4683 0.83464E+00 -0.0785 68 MgF+ 0.39473E-14 -14.4037 0.32946E-14 -14.4822 0.83464E+00 -0.0785 69 MgOH+ 0.54842E-10 -10.2609 0.45773E-10 -10.3394 0.83464E+00 -0.0785 71 MnF+ 0.17127E-14 -14.7663 0.14295E-14 -14.8448 0.83464E+00 -0.0785 72 MnO,aq 0.17234E-08 -8.7636 0.17234E-08 -8.7636 0.10000E+01 0.0000 73 MnOH+ 0.58585E-09 -9.2322 0.48897E-09 -9.3107 0.83464E+00 -0.0785 74 MnO2-2 0.11812E-10 -10.9277 0.60573E-11 -11.2177 0.51281E+00 -0.2900 75 HMnO2- 0.15480E-09 -9.8102 0.12895E-09 -9.8896 0.83299E+00 -0.0794 78 MnCl+ 0.23840E-13 -13.6227 0.19898E-13 -13.7012 0.83464E+00 -0.0785 79 MnSO4,aq 0.13939E-12 -12.8558 0.13939E-12 -12.8558 0.10000E+01 0.0000 80 NaCl,aq 0.11305E-05 -5.9467 0.11305E-05 -5.9467 0.10000E+01 0.0000 81 NaF,aq 0.20975E-07 -7.6783 0.20975E-07 -7.6783 0.10000E+01 0.0000 82 NaOH,aq 0.73342E-04 -4.1346 0.73342E-04 -4.1346 0.10000E+01 0.0000 84 OH- 0.71514E-02 -2.1456 0.59460E-02 -2.2258 0.83144E+00 -0.0802 89 HPO3-2 0.30459E-16 -16.5163 0.15620E-16 -16.8063 0.51281E+00 -0.2900 92 H3PO4,aq 0.15455E-17 -17.8109 0.15455E-17 -17.8109 0.10000E+01 0.0000 93 H2PO4- 0.50311E-10 -10.2983 0.41950E-10 -10.3773 0.83381E+00 -0.0789 94 PO4-3 0.82808E-09 -9.0819 0.19650E-09 -9.7066 0.23730E+00 -0.6247 98 HP2O7-3 0.12556E-17 -17.9011 0.28355E-18 -18.5474 0.22582E+00 -0.6462 99 P2O7-4 0.94240E-17 -17.0258 0.69712E-18 -18.1567 0.73973E-01 -1.1309 100 H2S,aq 0.89832E-07 -7.0466 0.89497E-07 -7.0482 0.99627E+00 -0.0016 101 S2-2 0.17917E-10 -10.7467 0.91879E-11 -11.0368 0.51281E+00 -0.2900 102 S3-2 0.10087E-16 -16.9963 0.51726E-17 -17.2863 0.51281E+00 -0.2900 107 SO3-2 0.16433E-11 -11.7843 0.85526E-12 -12.0679 0.52046E+00 -0.2836 108 HSO3- 0.62467E-14 -14.2044 0.52034E-14 -14.2837 0.83299E+00 -0.0794 109 HSO4- 0.34443E-11 -11.4629 0.28776E-11 -11.5410 0.83548E+00 -0.0781 111 S2O3-2 0.62997E-13 -13.2007 0.32306E-13 -13.4907 0.51281E+00 -0.2900 Charge balance for all species = -.6131E-08 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.1159285E-09 -.2055772E-01 -.2068380E+02 0.0000 2 H2O 0.1000000E+01 0.5550285E+02 0.9981077E+06 0.0000 3 Cl- 0.2468767E-03 0.2480076E-03 0.8776849E+01 6.3256 4 SO4-- 0.5979203E-04 0.5980987E-04 0.5735130E+01 15.5125 5 HCO3- 0.4761775E-03 0.1172734E-02 0.7142866E+02 6.6115 6 HS- 0.3577003E-03 0.3578475E-03 0.1181351E+02 6.4867 7 Al+++ 0.1375087E-28 0.2509773E-05 0.6759603E-01 0.5290 8 H4SiO4 0.8945776E-03 0.1352049E-01 0.1297197E+04 -3.0484 9 Ca++ 0.5996459E-07 0.2316415E-06 0.9267082E-02 12.5104 10 Mg++ 0.2221730E-10 0.9315741E-10 0.2260782E-05 9.0772 11 Fe++ 0.8420887E-13 0.2490647E-07 0.1388458E-02 6.6563 12 K+ 0.1565680E-03 0.1572174E-03 0.6136493E+01 6.1286 13 Na+ 0.1991660E-01 0.2229727E-01 0.5116907E+03 8.2322 14 Mn++ 0.3089156E-10 0.2506890E-08 0.1374766E-03 9.2212 15 F- 0.6498000E-05 0.6518982E-05 0.1236256E+00 4.7450 16 HPO4-- 0.4552950E-07 0.4640788E-07 0.4446196E-02 12.3942 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.1847710E-01 -.1846700E-01 -.1010067E-04 0.0000000E+00 2 H2O 0.4985819E+02 0.4985820E+02 -.1007001E-04 0.0000000E+00 3 Cl- 0.2227852E-03 0.2227852E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.5372719E-04 0.5372719E-04 0.0000000E+00 0.0000000E+00 5 HCO3- 0.1053467E-02 0.1053467E-02 0.0000000E+00 0.0000000E+00 6 HS- 0.3214543E-03 0.3214543E-03 0.0000000E+00 0.0000000E+00 7 Al+++ 0.4775352E-05 0.2254529E-05 0.2520823E-05 0.0000000E+00 8 H4SiO4 0.1215302E-01 0.1214545E-01 0.7566557E-05 0.0000000E+00 9 Ca++ 0.2080835E-06 0.2080835E-06 0.0000000E+00 0.0000000E+00 10 Mg++ 0.8368328E-10 0.8368328E-10 0.0000000E+00 0.0000000E+00 11 Fe++ 0.3259227E-07 0.2237348E-07 0.1021879E-07 0.0000000E+00 12 K+ 0.1412294E-03 0.1412284E-03 0.1021879E-08 0.0000000E+00 13 Na+ 0.2003215E-01 0.2002963E-01 0.2516736E-05 0.0000000E+00 14 Mn++ 0.2251939E-08 0.2251939E-08 0.0000000E+00 0.0000000E+00 15 F- 0.5856000E-05 0.5856000E-05 0.0000000E+00 0.0000000E+00 16 HPO4-- 0.4168819E-07 0.4168819E-07 0.0000000E+00 0.0000000E+00 Chg. balance for solid moles: 0.4235E-21 Mass of aqueous solution: 0.899913E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 0.0143900 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 0.2517E-05 -5.599 0.6599E-03 -3.180 99.67 0.2533E-03 stilpnomelane-Fe 0.2044E-08 -8.690 0.2203E-05 -5.657 0.3327 0.7610E-06 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 0.000662 g Volume = 0.000254 cm3 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.0143900 moles log = -1.8419 Original solution: 1000.0103000 g Original solution / Rock added: 69493.42 (Water/Rock Ratio), log = 4.8419 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0206 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9997E+00 0.9859 0.1006E+01 0.1020E+01 CO2,gas 0.8586E-05 1.0071 0.8825E-05 0.8762E-05 CH4,gas 0.5330E-05 1.0125 0.5508E-05 0.5440E-05 H2,gas 0.2754E-03 1.0005 0.2812E-03 0.2810E-03 H2S,gas 0.2420E-05 0.9960 0.2460E-05 0.2470E-05 S2,gas 0.2815E-23 1.0000 0.2873E-23 0.2873E-23 CO,gas 0.6480E-12 1.0000 0.6613E-12 0.6613E-12 SO3,gas 0.1075E-39 1.0000 0.1097E-39 0.1097E-39 SO2,gas 0.1176E-20 1.0000 0.1200E-20 0.1200E-20 HF,gas 0.8644E-14 1.0000 0.8822E-14 0.8822E-14 HCl,gas 0.6331E-17 1.0000 0.6461E-17 0.6461E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 17 albite -0.38 -0.38 0.00 0.000 -0.13080E-10 165 stilpnomelane-Fe 13.02 13.02 0.00 0.000 0.21232E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -13.41 -6.75 -2.251 0.11531E+05 -5.054 3 CH4,gas 4.54 -2.41 -6.96 -1.739 0.11881E+05 -5.259 4 H2,gas 8.00 2.75 -5.25 -3.000 0.89642E+04 -3.551 5 H2S,gas -6.23 -13.54 -7.31 -3.654 0.12478E+05 -5.609 6 S2,gas -7.34 -32.58 -25.24 -3.883 0.43098E+05 -23.542 7 CO,gas 3.21 -10.66 -13.88 -4.270 0.23697E+05 -12.180 8 SO3,gas 17.12 -24.54 -41.66 -10.415 0.71131E+05 -39.960 9 SO2,gas 0.83 -21.79 -22.62 -6.032 0.38623E+05 -20.921 10 HF,gas 0.47 -15.28 -15.75 -7.877 0.26899E+05 -14.054 11 HCl,gas 5.19 -13.70 -18.89 -9.444 0.32252E+05 -17.190 12 acmite 7.71 7.42 -0.29 -0.030 0.49994E+03 16 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 20 spessartine 24.46 19.58 -4.88 -0.244 0.83339E+04 21 analcite 3.32 2.66 -0.66 -0.073 0.11224E+04 25 annite 20.12 17.48 -2.64 -0.147 0.45110E+04 26 phlogopite 27.06 24.74 -2.32 -0.129 0.39624E+04 31 apatite-OH -18.15 -20.41 -2.26 -0.174 0.38612E+04 32 apatite-F -34.30 -35.69 -1.39 -0.116 0.23799E+04 36 aragonite 0.97 -0.90 -1.87 -0.623 0.31921E+04 37 brucite 12.57 9.08 -3.49 -0.698 0.59615E+04 38 calcite 0.81 -0.90 -1.71 -0.572 0.29279E+04 39 carnegieite-low 9.02 5.71 -3.31 -0.473 0.56524E+04 40 carnegieite-high 10.09 5.71 -4.38 -0.626 0.74794E+04 41 carpholite-Mg 8.58 4.04 -4.54 -0.303 0.77581E+04 43 celadonite 5.34 3.54 -1.80 -0.106 0.30740E+04 44 celadonite-Fe 3.88 1.12 -2.76 -0.162 0.47060E+04 45 chrysotile 23.89 21.13 -2.76 -0.230 0.47086E+04 47 clinochlore 39.07 37.30 -1.77 -0.055 0.30234E+04 48 daphnite 28.97 25.19 -3.77 -0.118 0.64383E+04 50 chlorite-Al-free 47.17 42.27 -4.90 -0.204 0.83723E+04 52 chloritoid-Fe 9.17 4.67 -4.51 -0.301 0.76966E+04 53 chloritoid-Mn 11.40 7.23 -4.17 -0.278 0.71205E+04 55 coesite -2.38 -3.05 -0.67 -0.224 0.11480E+04 62 cristobalite -2.56 -3.05 -0.49 -0.163 0.83332E+03 64 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71252E+04 66 diaspore 2.87 0.53 -2.34 -0.391 0.40034E+04 67 diamond -3.10 -7.91 -4.81 -1.375 0.82154E+04 68 diopside 16.18 15.49 -0.69 -0.069 0.11790E+04 69 hedenbergite 14.21 13.07 -1.14 -0.114 0.19436E+04 76 epidote 24.67 22.22 -2.45 -0.119 0.41913E+04 78 epidote-Fe 29.84 26.97 -2.87 -0.149 0.49058E+04 79 fayalite 14.05 10.26 -3.78 -0.540 0.64567E+04 80 ferrosilite 11.15 7.22 -3.93 -0.393 0.67164E+04 84 gibbsite 4.08 0.53 -3.55 -0.507 0.60620E+04 85 glaucophane 22.97 20.37 -2.61 -0.070 0.44527E+04 86 glaucophane-Fe 17.28 13.10 -4.17 -0.113 0.71224E+04 87 graphite -3.55 -7.91 -4.37 -1.248 0.74577E+04 88 greenalite 16.14 13.87 -2.27 -0.189 0.38713E+04 91 hematite 12.57 10.56 -2.00 -0.243 0.34206E+04 92 heulandite -5.83 -7.77 -1.94 -0.088 0.33175E+04 96 jadeite 4.22 2.66 -1.55 -0.155 0.26479E+04 97 julgoldite 70.43 66.19 -4.24 -0.110 0.72346E+04 98 kalsilite 7.58 3.61 -3.97 -0.568 0.67867E+04 99 kaolinite -1.33 -5.04 -3.71 -0.337 0.63278E+04 102 laumontite 2.88 1.37 -1.51 -0.101 0.25756E+04 103 lawsonite 9.62 7.47 -2.14 -0.143 0.36614E+04 104 leucite 4.12 0.56 -3.56 -0.356 0.60752E+04 106 lizardite 23.24 21.13 -2.11 -0.176 0.36012E+04 108 magnetite 20.09 17.22 -2.87 -0.234 0.48973E+04 109 minnesotaite 10.39 7.78 -2.61 -0.154 0.44610E+04 113 manganosite 14.06 9.22 -4.84 -1.209 0.82589E+04 117 microcline -2.49 -2.49 0.00 0.000 0.17789E+01 121 muscovite 2.58 -1.43 -4.01 -0.236 0.68502E+04 122 paragonite 4.24 0.67 -3.57 -0.210 0.60875E+04 123 nepheline 8.34 5.71 -2.63 -0.375 0.44848E+04 129 periclase-Fe 11.63 6.66 -4.97 -1.243 0.84866E+04 135 phlogopite-Na 29.65 26.85 -2.80 -0.156 0.47794E+04 137 prehnite 19.37 16.93 -2.44 -0.143 0.41630E+04 138 prehnite-Fe 22.50 21.69 -0.81 -0.049 0.13859E+04 143 pyrite -21.25 -23.17 -1.92 -0.452 0.32835E+04 144 pyrrhotite -4.26 -6.88 -2.62 -0.874 0.44763E+04 145 pyrrhotiteFe0.875 -6.02 -8.05 -2.04 -0.750 0.34798E+04 146 pyroxmangite 7.40 6.17 -1.23 -0.245 0.20931E+04 147 pyrophyllite -6.18 -11.14 -4.96 -0.310 0.84685E+04 148 quartz -2.99 -3.05 -0.06 -0.020 0.10065E+03 152 rhodochrosite -0.98 -4.19 -3.22 -1.072 0.54911E+04 153 rhodonite 7.45 6.17 -1.27 -0.255 0.21734E+04 154 sanidine -1.28 -2.49 -1.21 -0.093 0.20695E+04 156 siderite -2.61 -6.76 -4.15 -1.383 0.70842E+04 164 stilbite -7.52 -7.77 -0.25 -0.012 0.42365E+03 166 stilpnomelane-Mg 27.44 25.12 -2.32 -0.069 0.39617E+04 172 talc 16.49 15.04 -1.45 -0.085 0.24811E+04 175 tephroite 18.09 15.39 -2.69 -0.385 0.45962E+04 179 tridymite -2.63 -3.05 -0.42 -0.141 0.72063E+03 180 tremolite 47.87 46.02 -1.85 -0.050 0.31581E+04 181 ferroactinolite 38.45 33.92 -4.54 -0.123 0.77466E+04 182 troilite-low -4.41 -6.88 -2.47 -0.824 0.42191E+04 188 wairakite 3.95 1.37 -2.58 -0.151 0.43976E+04 189 walstromite 11.51 9.46 -2.05 -0.409 0.34955E+04 190 wollastonite 10.46 9.46 -1.00 -0.200 0.17059E+04 191 pseudo-wollastonite 11.00 9.46 -1.54 -0.308 0.26258E+04 193 akaganeite 7.75 5.28 -2.47 -0.535 0.42228E+04 200 chalcedony -2.80 -3.05 -0.25 -0.082 0.41995E+03 202 montmorillonite-Ca -2.29 -6.25 -3.96 -0.245 0.67610E+04 203 montmorillonite-K -2.24 -6.29 -4.06 -0.248 0.69245E+04 204 montmorillonite-Mg -2.48 -6.82 -4.34 -0.268 0.74052E+04 205 montmorillonite-Na -2.04 -5.60 -3.56 -0.218 0.60788E+04 206 nontronite-Ca 3.21 1.61 -1.60 -0.104 0.27327E+04 207 nontronite-H 2.53 -0.45 -2.98 -0.200 0.50930E+04 208 nontronite-K 3.34 1.57 -1.77 -0.114 0.30194E+04 209 nontronite-Mg 3.07 1.05 -2.03 -0.131 0.34610E+04 210 nontronite-Na 3.52 2.27 -1.25 -0.080 0.21397E+04 226 tobermorite 9.82 7.37 -2.45 -0.669 0.41837E+04 232 alabandite -0.98 -4.32 -3.34 -1.113 0.57016E+04 235 boehmite 4.41 0.53 -3.88 -0.646 0.66204E+04 237 ferrous-oxide 9.81 6.66 -3.16 -0.789 0.53875E+04 243 silica-amorphous -2.09 -3.05 -0.96 -0.319 0.16341E+04 245 an20ab80 2.02 1.19 -0.83 -0.064 0.14181E+04 246 an25ab75 2.65 1.58 -1.07 -0.082 0.18196E+04 247 an30ab70 3.28 1.97 -1.31 -0.100 0.22307E+04 248 tr.625ac.25prg.125 45.16 43.85 -1.32 -0.035 0.22474E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 0.0004000 MOLES Current total amount of reactant added: 0.0143900 MOLES New total amount of reactant added: 0.0147900 MOLES Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.5508E-08 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 7 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 0.0147900 Water: Moles liquid = 0.4986E+02 kg liquid = 0.8983E+00 Moles total = 0.4986E+02 kg total = 0.8982E+00 Activity = 1.0000 Stoichiometric ionic strength = .1227826E-01 Osmotic coef. = 0.9428 True ionic strength = .2085021E-01 Chg. balance for total moles = -.5508E-08 Max. difference allowed = 0.2251E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.11688E-09 -9.9323 0.97962E-10 -10.0089 0.83814E+00 -0.0767 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.24949E-03 -3.6029 0.20781E-03 -3.6823 0.83294E+00 -0.0794 4 SO4-- 0.61915E-04 -4.2082 0.31812E-04 -4.4974 0.51380E+00 -0.2892 5 HCO3- 0.49155E-03 -3.3084 0.41005E-03 -3.3872 0.83420E+00 -0.0787 6 HS- 0.36639E-03 -3.4361 0.30523E-03 -3.5154 0.83306E+00 -0.0793 7 Al+++ 0.13896E-28 -28.8571 0.31329E-29 -29.5040 0.22545E+00 -0.6470 8 H4SiO4 0.90131E-03 -3.0451 0.90131E-03 -3.0451 0.10000E+01 0.0000 9 Ca++ 0.59191E-07 -7.2277 0.30182E-07 -7.5203 0.50991E+00 -0.2925 10 Mg++ 0.22254E-10 -10.6526 0.11294E-10 -10.9472 0.50750E+00 -0.2946 11 Fe++ 0.85147E-13 -13.0698 0.43261E-13 -13.3639 0.50807E+00 -0.2941 12 K+ 0.15657E-03 -3.8053 0.13064E-03 -3.8839 0.83440E+00 -0.0786 13 Na+ 0.19918E-01 -1.7007 0.16588E-01 -1.7802 0.83278E+00 -0.0795 14 Mn++ 0.31356E-10 -10.5037 0.15945E-10 -10.7974 0.50851E+00 -0.2937 15 F- 0.66755E-05 -5.1755 0.55485E-05 -5.2558 0.83117E+00 -0.0803 16 HPO4-- 0.45535E-07 -7.3417 0.23399E-07 -7.6308 0.51388E+00 -0.2891 18 HSiO3- 0.10314E-01 -1.9866 0.85910E-02 -2.0660 0.83294E+00 -0.0794 19 Ca(HSiO3)+ 0.70755E-08 -8.1502 0.59051E-08 -8.2288 0.83459E+00 -0.0785 20 Mg(HSiO3)+ 0.32949E-11 -11.4822 0.27499E-11 -11.5607 0.83459E+00 -0.0785 21 NaHSiO3,aq 0.23048E-02 -2.6374 0.23048E-02 -2.6374 0.10000E+01 0.0000 22 AlO+ 0.53216E-16 -16.2740 0.44413E-16 -16.3525 0.83459E+00 -0.0785 24 HAlO2,aq 0.90288E-10 -10.0444 0.90288E-10 -10.0444 0.10000E+01 0.0000 25 AlO2- 0.24540E-05 -5.6101 0.20402E-05 -5.6903 0.83139E+00 -0.0802 26 CH4,aq 0.38360E-08 -8.4161 0.38217E-08 -8.4177 0.99626E+00 -0.0016 27 C2H6,aq 0.11757E-19 -19.9297 0.11713E-19 -19.9313 0.99626E+00 -0.0016 31 CO,aq 0.45963E-15 -15.3376 0.45963E-15 -15.3376 0.10000E+01 0.0000 32 CO2,aq 0.86154E-07 -7.0647 0.85832E-07 -7.0664 0.99626E+00 -0.0016 33 CO3-2 0.71314E-03 -3.1468 0.36561E-03 -3.4370 0.51268E+00 -0.2902 34 CaCO3,aq 0.13836E-06 -6.8590 0.13836E-06 -6.8590 0.10000E+01 0.0000 35 Ca(HCO3)+ 0.37852E-09 -9.4219 0.31591E-09 -9.5004 0.83459E+00 -0.0785 36 CaCl+ 0.12162E-10 -10.9150 0.10150E-10 -10.9935 0.83459E+00 -0.0785 37 CaCl2,aq 0.50113E-15 -15.3001 0.50113E-15 -15.3001 0.10000E+01 0.0000 38 CaF+ 0.29296E-11 -11.5332 0.24450E-11 -11.6117 0.83459E+00 -0.0785 39 CaOH+ 0.26310E-07 -7.5799 0.21958E-07 -7.6584 0.83459E+00 -0.0785 40 CaSO4,aq 0.30489E-09 -9.5159 0.30489E-09 -9.5159 0.10000E+01 0.0000 41 HCl,aq 0.37304E-14 -14.4282 0.37304E-14 -14.4282 0.10000E+01 0.0000 45 HF,aq 0.37209E-11 -11.4294 0.37209E-11 -11.4294 0.10000E+01 0.0000 46 HF2- 0.83684E-17 -17.0774 0.69704E-17 -17.1567 0.83294E+00 -0.0794 48 FeCl+ 0.17050E-16 -16.7683 0.14230E-16 -16.8468 0.83459E+00 -0.0785 51 FeF+ 0.14697E-16 -16.8328 0.12266E-16 -16.9113 0.83459E+00 -0.0785 53 FeO,aq 0.17520E-09 -9.7565 0.17520E-09 -9.7565 0.10000E+01 0.0000 54 FeOH+ 0.17224E-10 -10.7639 0.14375E-10 -10.8424 0.83459E+00 -0.0785 55 HFeO2- 0.22466E-07 -7.6485 0.18713E-07 -7.7279 0.83294E+00 -0.0794 56 FeO+ 0.88980E-16 -16.0507 0.74261E-16 -16.1292 0.83459E+00 -0.0785 58 FeO2- 0.19010E-08 -8.7210 0.15834E-08 -8.8004 0.83294E+00 -0.0794 59 HFeO2,aq 0.19728E-10 -10.7049 0.19728E-10 -10.7049 0.10000E+01 0.0000 60 H2,aq 0.21397E-06 -6.6696 0.21317E-06 -6.6713 0.99626E+00 -0.0016 61 KCl,aq 0.49205E-09 -9.3080 0.49205E-09 -9.3080 0.10000E+01 0.0000 62 KHSO4,aq 0.11511E-17 -17.9389 0.11511E-17 -17.9389 0.10000E+01 0.0000 63 KOH,aq 0.56952E-06 -6.2445 0.56952E-06 -6.2445 0.10000E+01 0.0000 64 KSO4- 0.77425E-07 -7.1111 0.64491E-07 -7.1905 0.83294E+00 -0.0794 65 MgCO3,aq 0.12978E-10 -10.8868 0.12978E-10 -10.8868 0.10000E+01 0.0000 66 Mg(HCO3)+ 0.14473E-12 -12.8394 0.12079E-12 -12.9180 0.83459E+00 -0.0785 67 MgCl+ 0.41247E-14 -14.3846 0.34424E-14 -14.4631 0.83459E+00 -0.0785 68 MgF+ 0.40607E-14 -14.3914 0.33890E-14 -14.4699 0.83459E+00 -0.0785 69 MgOH+ 0.54477E-10 -10.2638 0.45466E-10 -10.3423 0.83459E+00 -0.0785 71 MnF+ 0.17855E-14 -14.7482 0.14901E-14 -14.8268 0.83459E+00 -0.0785 72 MnO,aq 0.17207E-08 -8.7643 0.17207E-08 -8.7643 0.10000E+01 0.0000 73 MnOH+ 0.58974E-09 -9.2293 0.49219E-09 -9.3079 0.83459E+00 -0.0785 74 MnO2-2 0.11607E-10 -10.9353 0.59505E-11 -11.2254 0.51268E+00 -0.2902 75 HMnO2- 0.15332E-09 -9.8144 0.12771E-09 -9.8938 0.83294E+00 -0.0794 78 MnCl+ 0.24448E-13 -13.6117 0.20404E-13 -13.6903 0.83459E+00 -0.0785 79 MnSO4,aq 0.14644E-12 -12.8344 0.14644E-12 -12.8344 0.10000E+01 0.0000 80 NaCl,aq 0.11424E-05 -5.9422 0.11424E-05 -5.9422 0.10000E+01 0.0000 81 NaF,aq 0.21547E-07 -7.6666 0.21547E-07 -7.6666 0.10000E+01 0.0000 82 NaOH,aq 0.72751E-04 -4.1382 0.72751E-04 -4.1382 0.10000E+01 0.0000 84 OH- 0.70941E-02 -2.1491 0.58979E-02 -2.2293 0.83139E+00 -0.0802 89 HPO3-2 0.30320E-16 -16.5183 0.15544E-16 -16.8084 0.51268E+00 -0.2902 92 H3PO4,aq 0.15705E-17 -17.8040 0.15705E-17 -17.8040 0.10000E+01 0.0000 93 H2PO4- 0.50718E-10 -10.2948 0.42286E-10 -10.3738 0.83375E+00 -0.0790 94 PO4-3 0.82173E-09 -9.0853 0.19489E-09 -9.7102 0.23717E+00 -0.6249 98 HP2O7-3 0.12663E-17 -17.8975 0.28578E-18 -18.5440 0.22569E+00 -0.6465 99 P2O7-4 0.94312E-17 -17.0254 0.69692E-18 -18.1568 0.73895E-01 -1.1314 100 H2S,aq 0.92758E-07 -7.0326 0.92411E-07 -7.0343 0.99626E+00 -0.0016 101 S2-2 0.18889E-10 -10.7238 0.96838E-11 -11.0140 0.51268E+00 -0.2902 102 S3-2 0.11032E-16 -16.9573 0.56559E-17 -17.2475 0.51268E+00 -0.2902 107 SO3-2 0.16936E-11 -11.7712 0.88124E-12 -12.0549 0.52033E+00 -0.2837 108 HSO3- 0.64893E-14 -14.1878 0.54052E-14 -14.2672 0.83294E+00 -0.0794 109 HSO4- 0.35949E-11 -11.4443 0.30033E-11 -11.5224 0.83543E+00 -0.0781 111 S2O3-2 0.67359E-13 -13.1716 0.34533E-13 -13.4618 0.51268E+00 -0.2902 Charge balance for all species = -.6131E-08 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.1168801E-09 -.2050940E-01 -.2063514E+02 0.0000 2 H2O 0.1000000E+01 0.5550280E+02 0.9981051E+06 0.0000 3 Cl- 0.2494901E-03 0.2506330E-03 0.8869743E+01 6.3266 4 SO4-- 0.6191499E-04 0.6193564E-04 0.5938959E+01 15.5205 5 HCO3- 0.4915481E-03 0.1204920E-02 0.7338887E+02 6.6218 6 HS- 0.3663890E-03 0.3665389E-03 0.1210042E+02 6.4936 7 Al+++ 0.1389644E-28 0.2454050E-05 0.6609511E-01 0.5228 8 H4SiO4 0.9013125E-03 0.1352022E-01 0.1297169E+04 -3.0451 9 Ca++ 0.5919100E-07 0.2316398E-06 0.9266997E-02 12.4976 10 Mg++ 0.2225386E-10 0.9315672E-10 0.2260761E-05 9.0707 11 Fe++ 0.8514675E-13 0.2457966E-07 0.1370237E-02 6.6540 12 K+ 0.1565688E-03 0.1572162E-03 0.6136436E+01 6.1250 13 Na+ 0.1991832E-01 0.2229705E-01 0.5116847E+03 8.2287 14 Mn++ 0.3135628E-10 0.2506872E-08 0.1374753E-03 9.2205 15 F- 0.6675492E-05 0.6697046E-05 0.1270021E+00 4.7531 16 HPO4-- 0.4553509E-07 0.4640754E-07 0.4446155E-02 12.3871 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.1843403E-01 -.1842373E-01 -.1030132E-04 0.0000000E+00 2 H2O 0.4985852E+02 0.4985853E+02 -.1026979E-04 0.0000000E+00 3 Cl- 0.2251452E-03 0.2251452E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.5563719E-04 0.5563719E-04 0.0000000E+00 0.0000000E+00 5 HCO3- 0.1082387E-02 0.1082387E-02 0.0000000E+00 0.0000000E+00 6 HS- 0.3292643E-03 0.3292643E-03 0.0000000E+00 0.0000000E+00 7 Al+++ 0.4775352E-05 0.2204489E-05 0.2570863E-05 0.0000000E+00 8 H4SiO4 0.1215302E-01 0.1214530E-01 0.7716795E-05 0.0000000E+00 9 Ca++ 0.2080835E-06 0.2080835E-06 0.0000000E+00 0.0000000E+00 10 Mg++ 0.8368328E-10 0.8368328E-10 0.0000000E+00 0.0000000E+00 11 Fe++ 0.3259227E-07 0.2208007E-07 0.1051220E-07 0.0000000E+00 12 K+ 0.1412294E-03 0.1412283E-03 0.1051220E-08 0.0000000E+00 13 Na+ 0.2003215E-01 0.2002958E-01 0.2566658E-05 0.0000000E+00 14 Mn++ 0.2251939E-08 0.2251939E-08 0.0000000E+00 0.0000000E+00 15 F- 0.6016000E-05 0.6016000E-05 0.0000000E+00 0.0000000E+00 16 HPO4-- 0.4168819E-07 0.4168819E-07 0.0000000E+00 0.0000000E+00 Chg. balance for solid moles: 0.1271E-20 Mass of aqueous solution: 0.899922E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 0.0147900 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 0.2567E-05 -5.591 0.6730E-03 -3.172 99.66 0.2584E-03 stilpnomelane-Fe 0.2102E-08 -8.677 0.2266E-05 -5.645 0.3356 0.7829E-06 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 0.000675 g Volume = 0.000259 cm3 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.0147900 moles log = -1.8300 Original solution: 1000.0103000 g Original solution / Rock added: 67613.95 (Water/Rock Ratio), log = 4.8300 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0206 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9997E+00 0.9859 0.1006E+01 0.1020E+01 CO2,gas 0.8934E-05 1.0071 0.9183E-05 0.9118E-05 CH4,gas 0.5444E-05 1.0125 0.5625E-05 0.5556E-05 H2,gas 0.2741E-03 1.0005 0.2799E-03 0.2797E-03 H2S,gas 0.2499E-05 0.9960 0.2540E-05 0.2550E-05 S2,gas 0.3030E-23 1.0000 0.3093E-23 0.3093E-23 CO,gas 0.6711E-12 1.0000 0.6849E-12 0.6849E-12 SO3,gas 0.1131E-39 1.0000 0.1154E-39 0.1154E-39 SO2,gas 0.1231E-20 1.0000 0.1257E-20 0.1257E-20 HF,gas 0.8952E-14 1.0000 0.9136E-14 0.9136E-14 HCl,gas 0.6450E-17 1.0000 0.6582E-17 0.6582E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 17 albite -0.38 -0.38 0.00 0.000 -0.94784E-12 165 stilpnomelane-Fe 13.02 13.02 0.00 0.000 -0.27298E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -13.40 -6.74 -2.245 0.11502E+05 -5.037 3 CH4,gas 4.54 -2.41 -6.95 -1.737 0.11865E+05 -5.250 4 H2,gas 8.00 2.75 -5.25 -3.001 0.89677E+04 -3.553 5 H2S,gas -6.23 -13.52 -7.29 -3.647 0.12454E+05 -5.595 6 S2,gas -7.34 -32.54 -25.21 -3.878 0.43043E+05 -23.510 7 CO,gas 3.21 -10.65 -13.86 -4.266 0.23671E+05 -12.164 8 SO3,gas 17.12 -24.52 -41.64 -10.409 0.71093E+05 -39.938 9 SO2,gas 0.83 -21.77 -22.60 -6.027 0.38588E+05 -20.901 10 HF,gas 0.47 -15.26 -15.74 -7.869 0.26873E+05 -14.039 11 HCl,gas 5.19 -13.69 -18.88 -9.440 0.32238E+05 -17.182 12 acmite 7.71 7.42 -0.29 -0.030 0.49709E+03 16 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 20 spessartine 24.46 19.57 -4.89 -0.244 0.83421E+04 21 analcite 3.32 2.66 -0.66 -0.073 0.11280E+04 25 annite 20.12 17.47 -2.65 -0.147 0.45231E+04 26 phlogopite 27.06 24.72 -2.34 -0.130 0.39955E+04 31 apatite-OH -18.15 -20.46 -2.30 -0.177 0.39347E+04 32 apatite-F -34.30 -35.72 -1.42 -0.118 0.24275E+04 36 aragonite 0.97 -0.90 -1.86 -0.622 0.31844E+04 37 brucite 12.57 9.07 -3.50 -0.700 0.59725E+04 38 calcite 0.81 -0.90 -1.71 -0.570 0.29202E+04 39 carnegieite-low 9.02 5.71 -3.32 -0.474 0.56635E+04 40 carnegieite-high 10.09 5.71 -4.39 -0.627 0.74905E+04 41 carpholite-Mg 8.58 4.03 -4.56 -0.304 0.77793E+04 43 celadonite 5.34 3.54 -1.80 -0.106 0.30796E+04 44 celadonite-Fe 3.88 1.12 -2.76 -0.162 0.47045E+04 45 chrysotile 23.89 21.12 -2.77 -0.231 0.47305E+04 47 clinochlore 39.07 37.26 -1.81 -0.056 0.30832E+04 48 daphnite 28.97 25.18 -3.79 -0.118 0.64631E+04 50 chlorite-Al-free 47.17 42.24 -4.93 -0.205 0.84162E+04 52 chloritoid-Fe 9.17 4.65 -4.52 -0.301 0.77164E+04 53 chloritoid-Mn 11.40 7.22 -4.18 -0.279 0.71375E+04 55 coesite -2.38 -3.05 -0.67 -0.223 0.11424E+04 62 cristobalite -2.56 -3.05 -0.48 -0.162 0.82776E+03 64 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71252E+04 66 diaspore 2.87 0.52 -2.35 -0.392 0.40141E+04 67 diamond -3.10 -7.90 -4.80 -1.371 0.81929E+04 68 diopside 16.18 15.48 -0.70 -0.070 0.12008E+04 69 hedenbergite 14.21 13.06 -1.15 -0.115 0.19583E+04 76 epidote 24.67 22.19 -2.48 -0.120 0.42420E+04 78 epidote-Fe 29.84 26.94 -2.90 -0.151 0.49481E+04 79 fayalite 14.05 10.26 -3.78 -0.540 0.64592E+04 80 ferrosilite 11.15 7.22 -3.93 -0.393 0.67133E+04 84 gibbsite 4.08 0.52 -3.56 -0.508 0.60727E+04 85 glaucophane 22.97 20.35 -2.62 -0.071 0.44746E+04 86 glaucophane-Fe 17.28 13.10 -4.17 -0.113 0.71234E+04 87 graphite -3.55 -7.90 -4.35 -1.244 0.74351E+04 88 greenalite 16.14 13.87 -2.27 -0.189 0.38722E+04 91 hematite 12.57 10.56 -2.01 -0.243 0.34251E+04 92 heulandite -5.83 -7.77 -1.95 -0.088 0.33218E+04 96 jadeite 4.22 2.66 -1.55 -0.155 0.26534E+04 97 julgoldite 70.43 66.15 -4.28 -0.111 0.73059E+04 98 kalsilite 7.58 3.60 -3.98 -0.569 0.67978E+04 99 kaolinite -1.33 -5.04 -3.71 -0.337 0.63380E+04 102 laumontite 2.88 1.36 -1.52 -0.101 0.25966E+04 103 lawsonite 9.62 7.45 -2.16 -0.144 0.36935E+04 104 leucite 4.12 0.56 -3.56 -0.356 0.60808E+04 106 lizardite 23.24 21.12 -2.12 -0.177 0.36231E+04 108 magnetite 20.09 17.21 -2.87 -0.235 0.49059E+04 109 minnesotaite 10.39 7.78 -2.61 -0.153 0.44508E+04 113 manganosite 14.06 9.22 -4.84 -1.209 0.82601E+04 117 microcline -2.49 -2.49 0.00 0.000 0.18380E+01 121 muscovite 2.58 -1.44 -4.02 -0.237 0.68716E+04 122 paragonite 4.24 0.66 -3.58 -0.210 0.61089E+04 123 nepheline 8.34 5.71 -2.63 -0.376 0.44959E+04 129 periclase-Fe 11.63 6.65 -4.97 -1.243 0.84906E+04 135 phlogopite-Na 29.65 26.83 -2.82 -0.157 0.48124E+04 137 prehnite 19.37 16.91 -2.47 -0.145 0.42114E+04 138 prehnite-Fe 22.50 21.66 -0.84 -0.050 0.14259E+04 143 pyrite -21.25 -23.14 -1.90 -0.446 0.32365E+04 144 pyrrhotite -4.26 -6.87 -2.61 -0.870 0.44565E+04 145 pyrrhotiteFe0.875 -6.02 -8.04 -2.03 -0.745 0.34591E+04 146 pyroxmangite 7.40 6.18 -1.22 -0.245 0.20887E+04 147 pyrophyllite -6.18 -11.13 -4.96 -0.310 0.84676E+04 148 quartz -2.99 -3.05 -0.06 -0.019 0.95089E+02 152 rhodochrosite -0.98 -4.18 -3.20 -1.066 0.54627E+04 153 rhodonite 7.45 6.18 -1.27 -0.254 0.21690E+04 154 sanidine -1.28 -2.49 -1.21 -0.093 0.20696E+04 156 siderite -2.61 -6.74 -4.13 -1.378 0.70587E+04 164 stilbite -7.52 -7.77 -0.25 -0.012 0.42794E+03 166 stilpnomelane-Mg 27.44 25.10 -2.34 -0.070 0.39967E+04 172 talc 16.49 15.03 -1.46 -0.086 0.24919E+04 175 tephroite 18.09 15.40 -2.69 -0.384 0.45929E+04 179 tridymite -2.63 -3.05 -0.42 -0.140 0.71507E+03 180 tremolite 47.87 45.99 -1.88 -0.051 0.32124E+04 181 ferroactinolite 38.45 33.90 -4.55 -0.123 0.77659E+04 182 troilite-low -4.41 -6.87 -2.46 -0.820 0.41993E+04 188 wairakite 3.95 1.36 -2.59 -0.152 0.44185E+04 189 walstromite 11.51 9.45 -2.06 -0.411 0.35118E+04 190 wollastonite 10.46 9.45 -1.01 -0.202 0.17222E+04 191 pseudo-wollastonite 11.00 9.45 -1.55 -0.309 0.26421E+04 193 akaganeite 7.75 5.28 -2.47 -0.535 0.42251E+04 200 chalcedony -2.80 -3.05 -0.24 -0.081 0.41439E+03 202 montmorillonite-Ca -2.29 -6.25 -3.96 -0.245 0.67638E+04 203 montmorillonite-K -2.24 -6.29 -4.06 -0.248 0.69257E+04 204 montmorillonite-Mg -2.48 -6.82 -4.34 -0.268 0.74063E+04 205 montmorillonite-Na -2.04 -5.60 -3.56 -0.218 0.60800E+04 206 nontronite-Ca 3.21 1.62 -1.60 -0.103 0.27239E+04 207 nontronite-H 2.53 -0.44 -2.98 -0.199 0.50807E+04 208 nontronite-K 3.34 1.58 -1.76 -0.113 0.30091E+04 209 nontronite-Mg 3.07 1.05 -2.02 -0.131 0.34505E+04 210 nontronite-Na 3.52 2.27 -1.25 -0.080 0.21294E+04 226 tobermorite 9.82 7.37 -2.46 -0.671 0.41964E+04 232 alabandite -0.98 -4.30 -3.33 -1.109 0.56790E+04 235 boehmite 4.41 0.52 -3.88 -0.647 0.66310E+04 237 ferrous-oxide 9.81 6.65 -3.16 -0.789 0.53915E+04 243 silica-amorphous -2.09 -3.05 -0.95 -0.318 0.16286E+04 245 an20ab80 2.02 1.18 -0.83 -0.064 0.14245E+04 246 an25ab75 2.65 1.58 -1.07 -0.082 0.18276E+04 247 an30ab70 3.28 1.97 -1.31 -0.101 0.22403E+04 248 tr.625ac.25prg.125 45.16 43.82 -1.35 -0.036 0.22978E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 0.0004000 MOLES Current total amount of reactant added: 0.0147900 MOLES New total amount of reactant added: 0.0151900 MOLES Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.5508E-08 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 7 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 0.0151900 Water: Moles liquid = 0.4986E+02 kg liquid = 0.8983E+00 Moles total = 0.4986E+02 kg total = 0.8982E+00 Activity = 1.0000 Stoichiometric ionic strength = .1230400E-01 Osmotic coef. = 0.9425 True ionic strength = .2087074E-01 Chg. balance for total moles = -.5508E-08 Max. difference allowed = 0.2275E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.11784E-09 -9.9287 0.98763E-10 -10.0054 0.83809E+00 -0.0767 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.25210E-03 -3.5984 0.20997E-03 -3.6778 0.83288E+00 -0.0794 4 SO4-- 0.64038E-04 -4.1936 0.32894E-04 -4.4829 0.51367E+00 -0.2893 5 HCO3- 0.50706E-03 -3.2949 0.42296E-03 -3.3737 0.83414E+00 -0.0788 6 HS- 0.37508E-03 -3.4259 0.31244E-03 -3.5052 0.83301E+00 -0.0793 7 Al+++ 0.14044E-28 -28.8525 0.31644E-29 -29.4997 0.22532E+00 -0.6472 8 H4SiO4 0.90812E-03 -3.0419 0.90812E-03 -3.0419 0.10000E+01 0.0000 9 Ca++ 0.58444E-07 -7.2333 0.29793E-07 -7.5259 0.50977E+00 -0.2926 10 Mg++ 0.22291E-10 -10.6519 0.11309E-10 -10.9466 0.50736E+00 -0.2947 11 Fe++ 0.86099E-13 -13.0650 0.43733E-13 -13.3592 0.50794E+00 -0.2942 12 K+ 0.15657E-03 -3.8053 0.13063E-03 -3.8839 0.83435E+00 -0.0787 13 Na+ 0.19920E-01 -1.7007 0.16588E-01 -1.7802 0.83273E+00 -0.0795 14 Mn++ 0.31829E-10 -10.4972 0.16181E-10 -10.7910 0.50837E+00 -0.2938 15 F- 0.68530E-05 -5.1641 0.56956E-05 -5.2445 0.83111E+00 -0.0803 16 HPO4-- 0.45541E-07 -7.3416 0.23396E-07 -7.6309 0.51374E+00 -0.2893 18 HSiO3- 0.10308E-01 -1.9868 0.85857E-02 -2.0662 0.83288E+00 -0.0794 19 Ca(HSiO3)+ 0.69805E-08 -8.1561 0.58254E-08 -8.2347 0.83453E+00 -0.0786 20 Mg(HSiO3)+ 0.32977E-11 -11.4818 0.27520E-11 -11.5603 0.83453E+00 -0.0786 21 NaHSiO3,aq 0.23034E-02 -2.6376 0.23034E-02 -2.6376 0.10000E+01 0.0000 22 AlO+ 0.52885E-16 -16.2767 0.44134E-16 -16.3552 0.83453E+00 -0.0786 24 HAlO2,aq 0.88992E-10 -10.0506 0.88992E-10 -10.0506 0.10000E+01 0.0000 25 AlO2- 0.23993E-05 -5.6199 0.19946E-05 -5.7001 0.83133E+00 -0.0802 26 CH4,aq 0.39171E-08 -8.4070 0.39024E-08 -8.4087 0.99625E+00 -0.0016 27 C2H6,aq 0.12315E-19 -19.9096 0.12269E-19 -19.9112 0.99625E+00 -0.0016 31 CO,aq 0.47581E-15 -15.3226 0.47581E-15 -15.3226 0.10000E+01 0.0000 32 CO2,aq 0.89594E-07 -7.0477 0.89258E-07 -7.0494 0.99625E+00 -0.0016 33 CO3-2 0.72981E-03 -3.1368 0.37406E-03 -3.4271 0.51254E+00 -0.2903 34 CaCO3,aq 0.13974E-06 -6.8547 0.13974E-06 -6.8547 0.10000E+01 0.0000 35 Ca(HCO3)+ 0.38544E-09 -9.4140 0.32166E-09 -9.4926 0.83453E+00 -0.0786 36 CaCl+ 0.12131E-10 -10.9161 0.10124E-10 -10.9947 0.83453E+00 -0.0786 37 CaCl2,aq 0.50503E-15 -15.2967 0.50503E-15 -15.2967 0.10000E+01 0.0000 38 CaF+ 0.29687E-11 -11.5274 0.24775E-11 -11.6060 0.83453E+00 -0.0786 39 CaOH+ 0.25762E-07 -7.5890 0.21499E-07 -7.6676 0.83453E+00 -0.0786 40 CaSO4,aq 0.31120E-09 -9.5070 0.31120E-09 -9.5070 0.10000E+01 0.0000 41 HCl,aq 0.38001E-14 -14.4202 0.38001E-14 -14.4202 0.10000E+01 0.0000 45 HF,aq 0.38508E-11 -11.4144 0.38508E-11 -11.4144 0.10000E+01 0.0000 46 HF2- 0.88908E-17 -17.0511 0.74050E-17 -17.1305 0.83288E+00 -0.0794 48 FeCl+ 0.17417E-16 -16.7590 0.14535E-16 -16.8376 0.83453E+00 -0.0786 51 FeF+ 0.15252E-16 -16.8167 0.12729E-16 -16.8952 0.83453E+00 -0.0786 53 FeO,aq 0.17425E-09 -9.7588 0.17425E-09 -9.7588 0.10000E+01 0.0000 54 FeOH+ 0.17272E-10 -10.7627 0.14414E-10 -10.8412 0.83453E+00 -0.0786 55 HFeO2- 0.22165E-07 -7.6543 0.18461E-07 -7.7338 0.83288E+00 -0.0794 56 FeO+ 0.89430E-16 -16.0485 0.74633E-16 -16.1271 0.83453E+00 -0.0786 58 FeO2- 0.18798E-08 -8.7259 0.15656E-08 -8.8053 0.83288E+00 -0.0794 59 HFeO2,aq 0.19666E-10 -10.7063 0.19666E-10 -10.7063 0.10000E+01 0.0000 60 H2,aq 0.21300E-06 -6.6716 0.21220E-06 -6.6733 0.99625E+00 -0.0016 61 KCl,aq 0.49714E-09 -9.3035 0.49714E-09 -9.3035 0.10000E+01 0.0000 62 KHSO4,aq 0.11999E-17 -17.9208 0.11999E-17 -17.9208 0.10000E+01 0.0000 63 KOH,aq 0.56486E-06 -6.2481 0.56486E-06 -6.2481 0.10000E+01 0.0000 64 KSO4- 0.80060E-07 -7.0966 0.66681E-07 -7.1760 0.83288E+00 -0.0794 65 MgCO3,aq 0.13296E-10 -10.8763 0.13296E-10 -10.8763 0.10000E+01 0.0000 66 Mg(HCO3)+ 0.14950E-12 -12.8253 0.12477E-12 -12.9039 0.83453E+00 -0.0786 67 MgCl+ 0.41737E-14 -14.3795 0.34831E-14 -14.4580 0.83453E+00 -0.0786 68 MgF+ 0.41745E-14 -14.3794 0.34837E-14 -14.4580 0.83453E+00 -0.0786 69 MgOH+ 0.54114E-10 -10.2667 0.45160E-10 -10.3453 0.83453E+00 -0.0786 71 MnF+ 0.18601E-14 -14.7305 0.15523E-14 -14.8090 0.83453E+00 -0.0786 72 MnO,aq 0.17179E-08 -8.7650 0.17179E-08 -8.7650 0.10000E+01 0.0000 73 MnOH+ 0.59365E-09 -9.2265 0.49542E-09 -9.3050 0.83453E+00 -0.0786 74 MnO2-2 0.11404E-10 -10.9429 0.58450E-11 -11.2332 0.51254E+00 -0.2903 75 HMnO2- 0.15185E-09 -9.8186 0.12647E-09 -9.8980 0.83288E+00 -0.0794 78 MnCl+ 0.25070E-13 -13.6008 0.20922E-13 -13.6794 0.83453E+00 -0.0786 79 MnSO4,aq 0.15366E-12 -12.8134 0.15366E-12 -12.8134 0.10000E+01 0.0000 80 NaCl,aq 0.11543E-05 -5.9377 0.11543E-05 -5.9377 0.10000E+01 0.0000 81 NaF,aq 0.22119E-07 -7.6552 0.22119E-07 -7.6552 0.10000E+01 0.0000 82 NaOH,aq 0.72162E-04 -4.1417 0.72162E-04 -4.1417 0.10000E+01 0.0000 84 OH- 0.70370E-02 -2.1526 0.58501E-02 -2.2328 0.83133E+00 -0.0802 89 HPO3-2 0.30186E-16 -16.5202 0.15472E-16 -16.8105 0.51254E+00 -0.2903 92 H3PO4,aq 0.15961E-17 -17.7969 0.15961E-17 -17.7969 0.10000E+01 0.0000 93 H2PO4- 0.51129E-10 -10.2913 0.42626E-10 -10.3703 0.83370E+00 -0.0790 94 PO4-3 0.81540E-09 -9.0886 0.19328E-09 -9.7138 0.23703E+00 -0.6252 98 HP2O7-3 0.12770E-17 -17.8938 0.28804E-18 -18.5405 0.22555E+00 -0.6468 99 P2O7-4 0.94384E-17 -17.0251 0.69673E-18 -18.1569 0.73819E-01 -1.1318 100 H2S,aq 0.95729E-07 -7.0190 0.95370E-07 -7.0206 0.99625E+00 -0.0016 101 S2-2 0.19888E-10 -10.7014 0.10194E-10 -10.9917 0.51254E+00 -0.2903 102 S3-2 0.12042E-16 -16.9193 0.61723E-17 -17.2096 0.51254E+00 -0.2903 107 SO3-2 0.17437E-11 -11.7585 0.90707E-12 -12.0424 0.52020E+00 -0.2838 108 HSO3- 0.67346E-14 -14.1717 0.56092E-14 -14.2511 0.83288E+00 -0.0794 109 HSO4- 0.37479E-11 -11.4262 0.31309E-11 -11.5043 0.83537E+00 -0.0781 111 S2O3-2 0.71899E-13 -13.1433 0.36851E-13 -13.4335 0.51254E+00 -0.2903 Charge balance for all species = -.6131E-08 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.1178435E-09 -.2046108E-01 -.2058649E+02 0.0000 2 H2O 0.1000000E+01 0.5550275E+02 0.9981026E+06 0.0000 3 Cl- 0.2521034E-03 0.2532582E-03 0.8962635E+01 6.3276 4 SO4-- 0.6403794E-04 0.6406139E-04 0.6142785E+01 15.5279 5 HCO3- 0.5070557E-03 0.1237104E-02 0.7534904E+02 6.6317 6 HS- 0.3750776E-03 0.3752302E-03 0.1238732E+02 6.5002 7 Al+++ 0.1404422E-28 0.2399352E-05 0.6462181E-01 0.5165 8 H4SiO4 0.9081244E-03 0.1351996E-01 0.1297142E+04 -3.0419 9 Ca++ 0.5844422E-07 0.2316380E-06 0.9266912E-02 12.4849 10 Mg++ 0.2229074E-10 0.9315602E-10 0.2260741E-05 9.0642 11 Fe++ 0.8609906E-13 0.2425565E-07 0.1352172E-02 6.6516 12 K+ 0.1565696E-03 0.1572150E-03 0.6136378E+01 6.1215 13 Na+ 0.1992006E-01 0.2229683E-01 0.5116788E+03 8.2252 14 Mn++ 0.3182924E-10 0.2506853E-08 0.1374741E-03 9.2198 15 F- 0.6852982E-05 0.6875108E-05 0.1303787E+00 4.7609 16 HPO4-- 0.4554066E-07 0.4640719E-07 0.4446114E-02 12.3800 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.1839096E-01 -.1838046E-01 -.1049830E-04 0.0000000E+00 2 H2O 0.4985884E+02 0.4985886E+02 -.1046589E-04 0.0000000E+00 3 Cl- 0.2275052E-03 0.2275052E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.5754719E-04 0.5754719E-04 0.0000000E+00 0.0000000E+00 5 HCO3- 0.1111307E-02 0.1111307E-02 0.0000000E+00 0.0000000E+00 6 HS- 0.3370743E-03 0.3370743E-03 0.0000000E+00 0.0000000E+00 7 Al+++ 0.4775352E-05 0.2155369E-05 0.2619983E-05 0.0000000E+00 8 H4SiO4 0.1215302E-01 0.1214516E-01 0.7864270E-05 0.0000000E+00 9 Ca++ 0.2080835E-06 0.2080835E-06 0.0000000E+00 0.0000000E+00 10 Mg++ 0.8368328E-10 0.8368328E-10 0.0000000E+00 0.0000000E+00 11 Fe++ 0.3259227E-07 0.2178917E-07 0.1080310E-07 0.0000000E+00 12 K+ 0.1412294E-03 0.1412283E-03 0.1080310E-08 0.0000000E+00 13 Na+ 0.2003215E-01 0.2002953E-01 0.2615662E-05 0.0000000E+00 14 Mn++ 0.2251939E-08 0.2251939E-08 0.0000000E+00 0.0000000E+00 15 F- 0.6176000E-05 0.6176000E-05 0.0000000E+00 0.0000000E+00 16 HPO4-- 0.4168819E-07 0.4168819E-07 0.0000000E+00 0.0000000E+00 Chg. balance for solid moles: 0.0000E+00 Mass of aqueous solution: 0.899930E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 0.0151900 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 0.2616E-05 -5.582 0.6859E-03 -3.164 99.66 0.2633E-03 stilpnomelane-Fe 0.2161E-08 -8.665 0.2329E-05 -5.633 0.3384 0.8045E-06 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 0.000688 g Volume = 0.000264 cm3 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.0151900 moles log = -1.8184 Original solution: 1000.0103000 g Original solution / Rock added: 65833.46 (Water/Rock Ratio), log = 4.8184 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0206 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9997E+00 0.9859 0.1006E+01 0.1020E+01 CO2,gas 0.9291E-05 1.0071 0.9550E-05 0.9482E-05 CH4,gas 0.5559E-05 1.0125 0.5744E-05 0.5673E-05 H2,gas 0.2728E-03 1.0005 0.2786E-03 0.2784E-03 H2S,gas 0.2579E-05 0.9960 0.2622E-05 0.2632E-05 S2,gas 0.3257E-23 1.0000 0.3324E-23 0.3324E-23 CO,gas 0.6947E-12 1.0000 0.7090E-12 0.7090E-12 SO3,gas 0.1189E-39 1.0000 0.1213E-39 0.1213E-39 SO2,gas 0.1288E-20 1.0000 0.1315E-20 0.1315E-20 HF,gas 0.9264E-14 1.0000 0.9455E-14 0.9455E-14 HCl,gas 0.6570E-17 1.0000 0.6705E-17 0.6705E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 17 albite -0.38 -0.38 0.00 0.000 0.11184E-10 165 stilpnomelane-Fe 13.02 13.02 0.00 0.000 -0.75827E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -13.38 -6.72 -2.240 0.11472E+05 -5.020 3 CH4,gas 4.54 -2.40 -6.94 -1.735 0.11849E+05 -5.241 4 H2,gas 8.00 2.75 -5.25 -3.002 0.89711E+04 -3.555 5 H2S,gas -6.23 -13.51 -7.28 -3.640 0.12431E+05 -5.581 6 S2,gas -7.34 -32.51 -25.18 -3.873 0.42990E+05 -23.478 7 CO,gas 3.21 -10.63 -13.85 -4.261 0.23646E+05 -12.149 8 SO3,gas 17.12 -24.49 -41.62 -10.404 0.71057E+05 -39.916 9 SO2,gas 0.83 -21.75 -22.58 -6.021 0.38555E+05 -20.881 10 HF,gas 0.47 -15.25 -15.72 -7.862 0.26847E+05 -14.024 11 HCl,gas 5.19 -13.68 -18.87 -9.436 0.32224E+05 -17.174 12 acmite 7.71 7.42 -0.29 -0.030 0.49430E+03 16 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 20 spessartine 24.46 19.57 -4.89 -0.245 0.83503E+04 21 analcite 3.32 2.66 -0.66 -0.074 0.11335E+04 25 annite 20.12 17.47 -2.66 -0.148 0.45353E+04 26 phlogopite 27.06 24.71 -2.36 -0.131 0.40287E+04 31 apatite-OH -18.15 -20.50 -2.35 -0.181 0.40072E+04 32 apatite-F -34.30 -35.75 -1.45 -0.121 0.24745E+04 36 aragonite 0.97 -0.89 -1.86 -0.620 0.31771E+04 37 brucite 12.57 9.06 -3.50 -0.701 0.59835E+04 38 calcite 0.81 -0.89 -1.71 -0.569 0.29129E+04 39 carnegieite-low 9.02 5.70 -3.32 -0.475 0.56747E+04 40 carnegieite-high 10.09 5.70 -4.39 -0.628 0.75017E+04 41 carpholite-Mg 8.58 4.01 -4.57 -0.305 0.78007E+04 43 celadonite 5.34 3.53 -1.81 -0.106 0.30851E+04 44 celadonite-Fe 3.88 1.12 -2.75 -0.162 0.47030E+04 45 chrysotile 23.89 21.11 -2.78 -0.232 0.47525E+04 47 clinochlore 39.07 37.23 -1.84 -0.058 0.31432E+04 48 daphnite 28.97 25.17 -3.80 -0.119 0.64879E+04 50 chlorite-Al-free 47.17 42.22 -4.95 -0.206 0.84602E+04 52 chloritoid-Fe 9.17 4.64 -4.53 -0.302 0.77363E+04 53 chloritoid-Mn 11.40 7.21 -4.19 -0.279 0.71545E+04 55 coesite -2.38 -3.04 -0.67 -0.222 0.11368E+04 62 cristobalite -2.56 -3.04 -0.48 -0.161 0.82218E+03 64 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71253E+04 66 diaspore 2.87 0.52 -2.36 -0.393 0.40248E+04 67 diamond -3.10 -7.89 -4.79 -1.367 0.81706E+04 68 diopside 16.18 15.47 -0.72 -0.072 0.12224E+04 69 hedenbergite 14.21 13.05 -1.16 -0.116 0.19729E+04 76 epidote 24.67 22.16 -2.51 -0.122 0.42924E+04 78 epidote-Fe 29.84 26.92 -2.92 -0.152 0.49902E+04 79 fayalite 14.05 10.26 -3.78 -0.541 0.64617E+04 80 ferrosilite 11.15 7.22 -3.93 -0.393 0.67103E+04 84 gibbsite 4.08 0.52 -3.56 -0.509 0.60834E+04 85 glaucophane 22.97 20.34 -2.63 -0.071 0.44966E+04 86 glaucophane-Fe 17.28 13.10 -4.17 -0.113 0.71243E+04 87 graphite -3.55 -7.89 -4.34 -1.240 0.74128E+04 88 greenalite 16.14 13.87 -2.27 -0.189 0.38732E+04 91 hematite 12.57 10.56 -2.01 -0.243 0.34298E+04 92 heulandite -5.83 -7.78 -1.95 -0.089 0.33258E+04 96 jadeite 4.22 2.66 -1.56 -0.156 0.26590E+04 97 julgoldite 70.43 66.11 -4.32 -0.112 0.73766E+04 98 kalsilite 7.58 3.60 -3.99 -0.570 0.68091E+04 99 kaolinite -1.33 -5.05 -3.72 -0.338 0.63483E+04 102 laumontite 2.88 1.35 -1.53 -0.102 0.26174E+04 103 lawsonite 9.62 7.43 -2.18 -0.145 0.37255E+04 104 leucite 4.12 0.55 -3.56 -0.356 0.60865E+04 106 lizardite 23.24 21.11 -2.13 -0.178 0.36451E+04 108 magnetite 20.09 17.21 -2.88 -0.235 0.49146E+04 109 minnesotaite 10.39 7.79 -2.60 -0.153 0.44406E+04 113 manganosite 14.06 9.22 -4.84 -1.210 0.82613E+04 117 microcline -2.49 -2.49 0.00 0.000 0.18975E+01 121 muscovite 2.58 -1.45 -4.04 -0.237 0.68931E+04 122 paragonite 4.24 0.65 -3.59 -0.211 0.61303E+04 123 nepheline 8.34 5.70 -2.64 -0.377 0.45071E+04 129 periclase-Fe 11.63 6.65 -4.97 -1.244 0.84946E+04 135 phlogopite-Na 29.65 26.81 -2.84 -0.158 0.48456E+04 137 prehnite 19.37 16.88 -2.49 -0.147 0.42595E+04 138 prehnite-Fe 22.50 21.64 -0.86 -0.052 0.14656E+04 143 pyrite -21.25 -23.12 -1.87 -0.440 0.31904E+04 144 pyrrhotite -4.26 -6.86 -2.60 -0.866 0.44372E+04 145 pyrrhotiteFe0.875 -6.02 -8.03 -2.01 -0.741 0.34388E+04 146 pyroxmangite 7.40 6.18 -1.22 -0.244 0.20843E+04 147 pyrophyllite -6.18 -11.13 -4.96 -0.310 0.84667E+04 148 quartz -2.99 -3.04 -0.05 -0.017 0.89505E+02 152 rhodochrosite -0.98 -4.16 -3.18 -1.061 0.54348E+04 153 rhodonite 7.45 6.18 -1.27 -0.254 0.21646E+04 154 sanidine -1.28 -2.49 -1.21 -0.093 0.20696E+04 156 siderite -2.61 -6.73 -4.12 -1.373 0.70337E+04 164 stilbite -7.52 -7.78 -0.25 -0.012 0.43200E+03 166 stilpnomelane-Mg 27.44 25.08 -2.36 -0.070 0.40318E+04 172 talc 16.49 15.03 -1.47 -0.086 0.25027E+04 175 tephroite 18.09 15.40 -2.69 -0.384 0.45897E+04 179 tridymite -2.63 -3.04 -0.42 -0.139 0.70948E+03 180 tremolite 47.87 45.96 -1.91 -0.052 0.32664E+04 181 ferroactinolite 38.45 33.89 -4.56 -0.123 0.77848E+04 182 troilite-low -4.41 -6.86 -2.45 -0.816 0.41800E+04 188 wairakite 3.95 1.35 -2.60 -0.153 0.44394E+04 189 walstromite 11.51 9.44 -2.07 -0.413 0.35279E+04 190 wollastonite 10.46 9.44 -1.02 -0.204 0.17383E+04 191 pseudo-wollastonite 11.00 9.44 -1.56 -0.311 0.26582E+04 193 akaganeite 7.75 5.28 -2.48 -0.535 0.42274E+04 200 chalcedony -2.80 -3.04 -0.24 -0.080 0.40880E+03 202 montmorillonite-Ca -2.29 -6.25 -3.96 -0.245 0.67666E+04 203 montmorillonite-K -2.24 -6.29 -4.06 -0.248 0.69270E+04 204 montmorillonite-Mg -2.48 -6.82 -4.34 -0.268 0.74073E+04 205 montmorillonite-Na -2.04 -5.60 -3.56 -0.218 0.60812E+04 206 nontronite-Ca 3.21 1.62 -1.59 -0.103 0.27153E+04 207 nontronite-H 2.53 -0.44 -2.97 -0.199 0.50684E+04 208 nontronite-K 3.34 1.58 -1.76 -0.113 0.29989E+04 209 nontronite-Mg 3.07 1.06 -2.01 -0.131 0.34401E+04 210 nontronite-Na 3.52 2.28 -1.24 -0.080 0.21191E+04 226 tobermorite 9.82 7.36 -2.46 -0.673 0.42089E+04 232 alabandite -0.98 -4.29 -3.31 -1.104 0.56568E+04 235 boehmite 4.41 0.52 -3.89 -0.648 0.66418E+04 237 ferrous-oxide 9.81 6.65 -3.16 -0.790 0.53956E+04 243 silica-amorphous -2.09 -3.04 -0.95 -0.317 0.16230E+04 245 an20ab80 2.02 1.18 -0.84 -0.064 0.14309E+04 246 an25ab75 2.65 1.57 -1.08 -0.083 0.18356E+04 247 an30ab70 3.28 1.96 -1.32 -0.101 0.22499E+04 248 tr.625ac.25prg.125 45.16 43.79 -1.38 -0.037 0.23478E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 0.0004000 MOLES Current total amount of reactant added: 0.0151900 MOLES New total amount of reactant added: 0.0155900 MOLES Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.5508E-08 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 7 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 0.0155900 Water: Moles liquid = 0.4986E+02 kg liquid = 0.8983E+00 Moles total = 0.4986E+02 kg total = 0.8982E+00 Activity = 1.0000 Stoichiometric ionic strength = .1232975E-01 Osmotic coef. = 0.9423 True ionic strength = .2089114E-01 Chg. balance for total moles = -.5508E-08 Max. difference allowed = 0.2299E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.11882E-09 -9.9251 0.99575E-10 -10.0018 0.83804E+00 -0.0767 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.25472E-03 -3.5939 0.21214E-03 -3.6734 0.83283E+00 -0.0794 4 SO4-- 0.66161E-04 -4.1794 0.33976E-04 -4.4688 0.51354E+00 -0.2894 5 HCO3- 0.52270E-03 -3.2817 0.43598E-03 -3.3605 0.83409E+00 -0.0788 6 HS- 0.38377E-03 -3.4159 0.31966E-03 -3.4953 0.83296E+00 -0.0794 7 Al+++ 0.14194E-28 -28.8479 0.31963E-29 -29.4954 0.22518E+00 -0.6475 8 H4SiO4 0.91501E-03 -3.0386 0.91501E-03 -3.0386 0.10000E+01 0.0000 9 Ca++ 0.57723E-07 -7.2387 0.29418E-07 -7.5314 0.50964E+00 -0.2927 10 Mg++ 0.22328E-10 -10.6512 0.11325E-10 -10.9459 0.50723E+00 -0.2948 11 Fe++ 0.87066E-13 -13.0602 0.44212E-13 -13.3545 0.50780E+00 -0.2943 12 K+ 0.15657E-03 -3.8053 0.13063E-03 -3.8840 0.83429E+00 -0.0787 13 Na+ 0.19922E-01 -1.7007 0.16588E-01 -1.7802 0.83267E+00 -0.0795 14 Mn++ 0.32311E-10 -10.4907 0.16421E-10 -10.7846 0.50824E+00 -0.2939 15 F- 0.70305E-05 -5.1530 0.58427E-05 -5.2334 0.83106E+00 -0.0804 16 HPO4-- 0.45546E-07 -7.3415 0.23393E-07 -7.6309 0.51361E+00 -0.2894 18 HSiO3- 0.10303E-01 -1.9871 0.85803E-02 -2.0665 0.83283E+00 -0.0794 19 Ca(HSiO3)+ 0.68887E-08 -8.1619 0.57484E-08 -8.2405 0.83448E+00 -0.0786 20 Mg(HSiO3)+ 0.33005E-11 -11.4814 0.27542E-11 -11.5600 0.83448E+00 -0.0786 21 NaHSiO3,aq 0.23020E-02 -2.6379 0.23020E-02 -2.6379 0.10000E+01 0.0000 22 AlO+ 0.52554E-16 -16.2794 0.43855E-16 -16.3580 0.83448E+00 -0.0786 24 HAlO2,aq 0.87710E-10 -10.0570 0.87710E-10 -10.0570 0.10000E+01 0.0000 25 AlO2- 0.23456E-05 -5.6298 0.19498E-05 -5.7100 0.83128E+00 -0.0803 26 CH4,aq 0.39995E-08 -8.3980 0.39845E-08 -8.3996 0.99625E+00 -0.0016 27 C2H6,aq 0.12895E-19 -19.8896 0.12847E-19 -19.8912 0.99625E+00 -0.0016 31 CO,aq 0.49230E-15 -15.3078 0.49230E-15 -15.3078 0.10000E+01 0.0000 32 CO2,aq 0.93112E-07 -7.0310 0.92763E-07 -7.0326 0.99625E+00 -0.0016 33 CO3-2 0.74635E-03 -3.1271 0.38244E-03 -3.4174 0.51241E+00 -0.2904 34 CaCO3,aq 0.14107E-06 -6.8506 0.14107E-06 -6.8506 0.10000E+01 0.0000 35 Ca(HCO3)+ 0.39232E-09 -9.4064 0.32739E-09 -9.4849 0.83448E+00 -0.0786 36 CaCl+ 0.12102E-10 -10.9171 0.10099E-10 -10.9957 0.83448E+00 -0.0786 37 CaCl2,aq 0.50899E-15 -15.2933 0.50899E-15 -15.2933 0.10000E+01 0.0000 38 CaF+ 0.30072E-11 -11.5218 0.25095E-11 -11.6004 0.83448E+00 -0.0786 39 CaOH+ 0.25232E-07 -7.5981 0.21055E-07 -7.6766 0.83448E+00 -0.0786 40 CaSO4,aq 0.31739E-09 -9.4984 0.31739E-09 -9.4984 0.10000E+01 0.0000 41 HCl,aq 0.38708E-14 -14.4122 0.38708E-14 -14.4122 0.10000E+01 0.0000 45 HF,aq 0.39827E-11 -11.3998 0.39827E-11 -11.3998 0.10000E+01 0.0000 46 HF2- 0.94336E-17 -17.0253 0.78566E-17 -17.1048 0.83283E+00 -0.0794 48 FeCl+ 0.17790E-16 -16.7498 0.14845E-16 -16.8284 0.83448E+00 -0.0786 51 FeF+ 0.15819E-16 -16.8008 0.13201E-16 -16.8794 0.83448E+00 -0.0786 53 FeO,aq 0.17330E-09 -9.7612 0.17330E-09 -9.7612 0.10000E+01 0.0000 54 FeOH+ 0.17320E-10 -10.7615 0.14453E-10 -10.8400 0.83448E+00 -0.0786 55 HFeO2- 0.21866E-07 -7.6602 0.18210E-07 -7.7397 0.83283E+00 -0.0794 56 FeO+ 0.89878E-16 -16.0463 0.75002E-16 -16.1249 0.83448E+00 -0.0786 58 FeO2- 0.18585E-08 -8.7308 0.15478E-08 -8.8103 0.83283E+00 -0.0794 59 HFeO2,aq 0.19602E-10 -10.7077 0.19602E-10 -10.7077 0.10000E+01 0.0000 60 H2,aq 0.21206E-06 -6.6735 0.21126E-06 -6.6752 0.99625E+00 -0.0016 61 KCl,aq 0.50223E-09 -9.2991 0.50223E-09 -9.2991 0.10000E+01 0.0000 62 KHSO4,aq 0.12495E-17 -17.9033 0.12495E-17 -17.9033 0.10000E+01 0.0000 63 KOH,aq 0.56023E-06 -6.2516 0.56023E-06 -6.2516 0.10000E+01 0.0000 64 KSO4- 0.82693E-07 -7.0825 0.68869E-07 -7.1620 0.83283E+00 -0.0794 65 MgCO3,aq 0.13613E-10 -10.8661 0.13613E-10 -10.8661 0.10000E+01 0.0000 66 Mg(HCO3)+ 0.15433E-12 -12.8115 0.12879E-12 -12.8901 0.83448E+00 -0.0786 67 MgCl+ 0.42228E-14 -14.3744 0.35239E-14 -14.4530 0.83448E+00 -0.0786 68 MgF+ 0.42886E-14 -14.3677 0.35787E-14 -14.4463 0.83448E+00 -0.0786 69 MgOH+ 0.53751E-10 -10.2696 0.44854E-10 -10.3482 0.83448E+00 -0.0786 71 MnF+ 0.19366E-14 -14.7130 0.16161E-14 -14.7915 0.83448E+00 -0.0786 72 MnO,aq 0.17152E-08 -8.7657 0.17152E-08 -8.7657 0.10000E+01 0.0000 73 MnOH+ 0.59760E-09 -9.2236 0.49868E-09 -9.3022 0.83448E+00 -0.0786 74 MnO2-2 0.11204E-10 -10.9506 0.57408E-11 -11.2410 0.51241E+00 -0.2904 75 HMnO2- 0.15038E-09 -9.8228 0.12524E-09 -9.9023 0.83283E+00 -0.0794 78 MnCl+ 0.25707E-13 -13.5900 0.21452E-13 -13.6685 0.83448E+00 -0.0786 79 MnSO4,aq 0.16107E-12 -12.7930 0.16107E-12 -12.7930 0.10000E+01 0.0000 80 NaCl,aq 0.11662E-05 -5.9332 0.11662E-05 -5.9332 0.10000E+01 0.0000 81 NaF,aq 0.22691E-07 -7.6441 0.22691E-07 -7.6441 0.10000E+01 0.0000 82 NaOH,aq 0.71576E-04 -4.1452 0.71576E-04 -4.1452 0.10000E+01 0.0000 84 OH- 0.69801E-02 -2.1561 0.58024E-02 -2.2364 0.83128E+00 -0.0803 89 HPO3-2 0.30057E-16 -16.5221 0.15401E-16 -16.8124 0.51241E+00 -0.2904 92 H3PO4,aq 0.16222E-17 -17.7899 0.16222E-17 -17.7899 0.10000E+01 0.0000 93 H2PO4- 0.51545E-10 -10.2878 0.42971E-10 -10.3668 0.83365E+00 -0.0790 94 PO4-3 0.80910E-09 -9.0920 0.19168E-09 -9.7174 0.23690E+00 -0.6254 98 HP2O7-3 0.12880E-17 -17.8901 0.29033E-18 -18.5371 0.22542E+00 -0.6470 99 P2O7-4 0.94455E-17 -17.0248 0.69654E-18 -18.1571 0.73743E-01 -1.1323 100 H2S,aq 0.98746E-07 -7.0055 0.98375E-07 -7.0071 0.99625E+00 -0.0016 101 S2-2 0.20915E-10 -10.6795 0.10717E-10 -10.9699 0.51241E+00 -0.2904 102 S3-2 0.13121E-16 -16.8820 0.67235E-17 -17.1724 0.51241E+00 -0.2904 107 SO3-2 0.17935E-11 -11.7463 0.93276E-12 -12.0302 0.52007E+00 -0.2839 108 HSO3- 0.69827E-14 -14.1560 0.58154E-14 -14.2354 0.83283E+00 -0.0794 109 HSO4- 0.39032E-11 -11.4086 0.32604E-11 -11.4867 0.83532E+00 -0.0781 111 S2O3-2 0.76623E-13 -13.1156 0.39262E-13 -13.4060 0.51241E+00 -0.2904 Charge balance for all species = -.6131E-08 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.1188190E-09 -.2041277E-01 -.2053785E+02 0.0000 2 H2O 0.1000000E+01 0.5550270E+02 0.9981000E+06 0.0000 3 Cl- 0.2547167E-03 0.2558835E-03 0.9055525E+01 6.3285 4 SO4-- 0.6616086E-04 0.6618710E-04 0.6346607E+01 15.5349 5 HCO3- 0.5227015E-03 0.1269288E-02 0.7730917E+02 6.6413 6 HS- 0.3837659E-03 0.3839214E-03 0.1267422E+02 6.5065 7 Al+++ 0.1419426E-28 0.2345666E-05 0.6317578E-01 0.5102 8 H4SiO4 0.9150142E-03 0.1351969E-01 0.1297114E+04 -3.0386 9 Ca++ 0.5772302E-07 0.2316363E-06 0.9266828E-02 12.4723 10 Mg++ 0.2232793E-10 0.9315532E-10 0.2260720E-05 9.0577 11 Fe++ 0.8706606E-13 0.2393445E-07 0.1334264E-02 6.6492 12 K+ 0.1565704E-03 0.1572138E-03 0.6136321E+01 6.1179 13 Na+ 0.1992180E-01 0.2229661E-01 0.5116729E+03 8.2217 14 Mn++ 0.3231062E-10 0.2506834E-08 0.1374728E-03 9.2191 15 F- 0.7030469E-05 0.7053167E-05 0.1337551E+00 4.7685 16 HPO4-- 0.4554620E-07 0.4640684E-07 0.4446074E-02 12.3728 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.1834789E-01 -.1833720E-01 -.1069163E-04 0.0000000E+00 2 H2O 0.4985917E+02 0.4985918E+02 -.1065836E-04 0.0000000E+00 3 Cl- 0.2298652E-03 0.2298652E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.5945719E-04 0.5945719E-04 0.0000000E+00 0.0000000E+00 5 HCO3- 0.1140227E-02 0.1140227E-02 0.0000000E+00 0.0000000E+00 6 HS- 0.3448843E-03 0.3448843E-03 0.0000000E+00 0.0000000E+00 7 Al+++ 0.4775352E-05 0.2107158E-05 0.2668194E-05 0.0000000E+00 8 H4SiO4 0.1215302E-01 0.1214501E-01 0.8009018E-05 0.0000000E+00 9 Ca++ 0.2080835E-06 0.2080835E-06 0.0000000E+00 0.0000000E+00 10 Mg++ 0.8368328E-10 0.8368328E-10 0.0000000E+00 0.0000000E+00 11 Fe++ 0.3259227E-07 0.2150080E-07 0.1109147E-07 0.0000000E+00 12 K+ 0.1412294E-03 0.1412283E-03 0.1109147E-08 0.0000000E+00 13 Na+ 0.2003215E-01 0.2002949E-01 0.2663757E-05 0.0000000E+00 14 Mn++ 0.2251939E-08 0.2251939E-08 0.0000000E+00 0.0000000E+00 15 F- 0.6336000E-05 0.6336000E-05 0.0000000E+00 0.0000000E+00 16 HPO4-- 0.4168819E-07 0.4168819E-07 0.0000000E+00 0.0000000E+00 Chg. balance for solid moles: 0.8470E-21 Mass of aqueous solution: 0.899938E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 0.0155900 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 0.2664E-05 -5.575 0.6985E-03 -3.156 99.66 0.2681E-03 stilpnomelane-Fe 0.2218E-08 -8.654 0.2391E-05 -5.621 0.3412 0.8260E-06 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 0.000701 g Volume = 0.000269 cm3 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.0155900 moles log = -1.8072 Original solution: 1000.0103000 g Original solution / Rock added: 64144.34 (Water/Rock Ratio), log = 4.8072 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0206 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9997E+00 0.9859 0.1006E+01 0.1020E+01 CO2,gas 0.9656E-05 1.0071 0.9925E-05 0.9855E-05 CH4,gas 0.5675E-05 1.0125 0.5865E-05 0.5792E-05 H2,gas 0.2716E-03 1.0005 0.2774E-03 0.2772E-03 H2S,gas 0.2660E-05 0.9960 0.2704E-05 0.2715E-05 S2,gas 0.3496E-23 1.0000 0.3568E-23 0.3568E-23 CO,gas 0.7188E-12 1.0000 0.7336E-12 0.7336E-12 SO3,gas 0.1248E-39 1.0000 0.1274E-39 0.1274E-39 SO2,gas 0.1347E-20 1.0000 0.1374E-20 0.1374E-20 HF,gas 0.9582E-14 1.0000 0.9779E-14 0.9779E-14 HCl,gas 0.6692E-17 1.0000 0.6830E-17 0.6830E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 17 albite -0.38 -0.38 0.00 0.000 -0.94784E-12 165 stilpnomelane-Fe 13.02 13.02 0.00 0.000 -0.27298E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -13.36 -6.70 -2.234 0.11444E+05 -5.003 3 CH4,gas 4.54 -2.39 -6.93 -1.733 0.11834E+05 -5.232 4 H2,gas 8.00 2.74 -5.26 -3.003 0.89743E+04 -3.557 5 H2S,gas -6.23 -13.50 -7.27 -3.633 0.12408E+05 -5.568 6 S2,gas -7.34 -32.48 -25.15 -3.869 0.42937E+05 -23.448 7 CO,gas 3.21 -10.62 -13.83 -4.256 0.23620E+05 -12.135 8 SO3,gas 17.12 -24.47 -41.59 -10.398 0.71020E+05 -39.895 9 SO2,gas 0.83 -21.73 -22.56 -6.016 0.38522E+05 -20.862 10 HF,gas 0.47 -15.24 -15.71 -7.854 0.26822E+05 -14.010 11 HCl,gas 5.19 -13.68 -18.86 -9.432 0.32211E+05 -17.166 12 acmite 7.71 7.42 -0.29 -0.030 0.49155E+03 16 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 20 spessartine 24.46 19.56 -4.90 -0.245 0.83586E+04 21 analcite 3.32 2.65 -0.67 -0.074 0.11391E+04 25 annite 20.12 17.46 -2.66 -0.148 0.45475E+04 26 phlogopite 27.06 24.69 -2.38 -0.132 0.40620E+04 31 apatite-OH -18.15 -20.54 -2.39 -0.184 0.40788E+04 32 apatite-F -34.30 -35.78 -1.48 -0.123 0.25211E+04 36 aragonite 0.97 -0.89 -1.86 -0.619 0.31701E+04 37 brucite 12.57 9.06 -3.51 -0.702 0.59946E+04 38 calcite 0.81 -0.89 -1.70 -0.567 0.29059E+04 39 carnegieite-low 9.02 5.69 -3.33 -0.476 0.56859E+04 40 carnegieite-high 10.09 5.69 -4.40 -0.629 0.75129E+04 41 carpholite-Mg 8.58 4.00 -4.58 -0.305 0.78221E+04 43 celadonite 5.34 3.53 -1.81 -0.106 0.30906E+04 44 celadonite-Fe 3.88 1.12 -2.75 -0.162 0.47015E+04 45 chrysotile 23.89 21.10 -2.80 -0.233 0.47746E+04 47 clinochlore 39.07 37.19 -1.88 -0.059 0.32034E+04 48 daphnite 28.97 25.15 -3.81 -0.119 0.65129E+04 50 chlorite-Al-free 47.17 42.19 -4.98 -0.208 0.85043E+04 52 chloritoid-Fe 9.17 4.63 -4.54 -0.303 0.77563E+04 53 chloritoid-Mn 11.40 7.20 -4.20 -0.280 0.71716E+04 55 coesite -2.38 -3.04 -0.66 -0.221 0.11312E+04 62 cristobalite -2.56 -3.04 -0.48 -0.159 0.81657E+03 64 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71253E+04 66 diaspore 2.87 0.51 -2.36 -0.394 0.40356E+04 67 diamond -3.10 -7.87 -4.77 -1.364 0.81486E+04 68 diopside 16.18 15.45 -0.73 -0.073 0.12438E+04 69 hedenbergite 14.21 13.04 -1.16 -0.116 0.19873E+04 76 epidote 24.67 22.13 -2.54 -0.123 0.43426E+04 78 epidote-Fe 29.84 26.89 -2.95 -0.153 0.50320E+04 79 fayalite 14.05 10.26 -3.79 -0.541 0.64642E+04 80 ferrosilite 11.15 7.22 -3.93 -0.393 0.67071E+04 84 gibbsite 4.08 0.51 -3.57 -0.510 0.60942E+04 85 glaucophane 22.97 20.33 -2.65 -0.072 0.45187E+04 86 glaucophane-Fe 17.28 13.10 -4.17 -0.113 0.71252E+04 87 graphite -3.55 -7.87 -4.33 -1.237 0.73908E+04 88 greenalite 16.14 13.87 -2.27 -0.189 0.38741E+04 91 hematite 12.57 10.55 -2.01 -0.244 0.34346E+04 92 heulandite -5.83 -7.78 -1.95 -0.089 0.33297E+04 96 jadeite 4.22 2.65 -1.56 -0.156 0.26646E+04 97 julgoldite 70.43 66.07 -4.36 -0.113 0.74469E+04 98 kalsilite 7.58 3.59 -3.99 -0.571 0.68203E+04 99 kaolinite -1.33 -5.06 -3.72 -0.339 0.63586E+04 102 laumontite 2.88 1.34 -1.54 -0.103 0.26380E+04 103 lawsonite 9.62 7.42 -2.20 -0.147 0.37573E+04 104 leucite 4.12 0.55 -3.57 -0.357 0.60921E+04 106 lizardite 23.24 21.10 -2.15 -0.179 0.36672E+04 107 magnesite 0.69 -4.30 -5.00 -1.665 0.85292E+04 108 magnetite 20.09 17.20 -2.88 -0.235 0.49235E+04 109 minnesotaite 10.39 7.79 -2.59 -0.153 0.44303E+04 113 manganosite 14.06 9.22 -4.84 -1.210 0.82625E+04 117 microcline -2.49 -2.49 0.00 0.000 0.19575E+01 121 muscovite 2.58 -1.47 -4.05 -0.238 0.69147E+04 122 paragonite 4.24 0.64 -3.60 -0.212 0.61519E+04 123 nepheline 8.34 5.69 -2.65 -0.378 0.45183E+04 129 periclase-Fe 11.63 6.65 -4.98 -1.244 0.84987E+04 135 phlogopite-Na 29.65 26.79 -2.86 -0.159 0.48789E+04 137 prehnite 19.37 16.85 -2.52 -0.148 0.43072E+04 138 prehnite-Fe 22.50 21.62 -0.88 -0.053 0.15050E+04 143 pyrite -21.25 -23.09 -1.84 -0.433 0.31451E+04 144 pyrrhotite -4.26 -6.85 -2.59 -0.863 0.44183E+04 145 pyrrhotiteFe0.875 -6.02 -8.02 -2.00 -0.736 0.34190E+04 146 pyroxmangite 7.40 6.18 -1.22 -0.244 0.20799E+04 147 pyrophyllite -6.18 -11.13 -4.96 -0.310 0.84658E+04 148 quartz -2.99 -3.04 -0.05 -0.016 0.83900E+02 152 rhodochrosite -0.98 -4.14 -3.17 -1.056 0.54075E+04 153 rhodonite 7.45 6.18 -1.27 -0.253 0.21602E+04 154 sanidine -1.28 -2.49 -1.21 -0.093 0.20697E+04 156 siderite -2.61 -6.71 -4.10 -1.368 0.70092E+04 164 stilbite -7.52 -7.78 -0.26 -0.012 0.43583E+03 166 stilpnomelane-Mg 27.44 25.06 -2.38 -0.071 0.40670E+04 172 talc 16.49 15.02 -1.47 -0.087 0.25136E+04 175 tephroite 18.09 15.40 -2.69 -0.384 0.45865E+04 179 tridymite -2.63 -3.04 -0.41 -0.137 0.70388E+03 180 tremolite 47.87 45.92 -1.94 -0.053 0.33201E+04 181 ferroactinolite 38.45 33.88 -4.57 -0.124 0.78033E+04 182 troilite-low -4.41 -6.85 -2.44 -0.812 0.41611E+04 188 wairakite 3.95 1.34 -2.61 -0.154 0.44600E+04 189 walstromite 11.51 9.43 -2.08 -0.415 0.35438E+04 190 wollastonite 10.46 9.43 -1.03 -0.205 0.17543E+04 191 pseudo-wollastonite 11.00 9.43 -1.57 -0.313 0.26741E+04 193 akaganeite 7.75 5.28 -2.48 -0.536 0.42299E+04 200 chalcedony -2.80 -3.04 -0.24 -0.079 0.40320E+03 202 montmorillonite-Ca -2.29 -6.26 -3.96 -0.245 0.67694E+04 203 montmorillonite-K -2.24 -6.29 -4.06 -0.248 0.69282E+04 204 montmorillonite-Mg -2.48 -6.82 -4.34 -0.268 0.74084E+04 205 montmorillonite-Na -2.04 -5.60 -3.56 -0.218 0.60825E+04 206 nontronite-Ca 3.21 1.63 -1.59 -0.103 0.27066E+04 207 nontronite-H 2.53 -0.43 -2.96 -0.198 0.50563E+04 208 nontronite-K 3.34 1.59 -1.75 -0.112 0.29887E+04 209 nontronite-Mg 3.07 1.07 -2.01 -0.130 0.34297E+04 210 nontronite-Na 3.52 2.28 -1.24 -0.079 0.21089E+04 226 tobermorite 9.82 7.35 -2.47 -0.675 0.42212E+04 232 alabandite -0.98 -4.28 -3.30 -1.100 0.56350E+04 235 boehmite 4.41 0.51 -3.90 -0.649 0.66525E+04 237 ferrous-oxide 9.81 6.65 -3.16 -0.791 0.53996E+04 243 silica-amorphous -2.09 -3.04 -0.95 -0.316 0.16174E+04 245 an20ab80 2.02 1.18 -0.84 -0.065 0.14373E+04 246 an25ab75 2.65 1.57 -1.08 -0.083 0.18436E+04 247 an30ab70 3.28 1.96 -1.32 -0.102 0.22595E+04 248 tr.625ac.25prg.125 45.16 43.76 -1.40 -0.038 0.23975E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 0.0004000 MOLES Current total amount of reactant added: 0.0155900 MOLES New total amount of reactant added: 0.0159900 MOLES Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.5508E-08 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 7 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 0.0159900 Water: Moles liquid = 0.4986E+02 kg liquid = 0.8983E+00 Moles total = 0.4986E+02 kg total = 0.8982E+00 Activity = 1.0000 Stoichiometric ionic strength = .1235551E-01 Osmotic coef. = 0.9420 True ionic strength = .2091140E-01 Chg. balance for total moles = -.5508E-08 Max. difference allowed = 0.2322E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.11981E-09 -9.9215 0.10040E-09 -9.9983 0.83799E+00 -0.0768 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.25733E-03 -3.5895 0.21430E-03 -3.6690 0.83278E+00 -0.0795 4 SO4-- 0.68284E-04 -4.1657 0.35057E-04 -4.4552 0.51341E+00 -0.2895 5 HCO3- 0.53849E-03 -3.2688 0.44912E-03 -3.3476 0.83404E+00 -0.0788 6 HS- 0.39245E-03 -3.4062 0.32688E-03 -3.4856 0.83290E+00 -0.0794 7 Al+++ 0.14347E-28 -28.8433 0.32287E-29 -29.4910 0.22505E+00 -0.6477 8 H4SiO4 0.92198E-03 -3.0353 0.92198E-03 -3.0353 0.10000E+01 0.0000 9 Ca++ 0.57026E-07 -7.2439 0.29055E-07 -7.5368 0.50950E+00 -0.2929 10 Mg++ 0.22365E-10 -10.6504 0.11341E-10 -10.9453 0.50709E+00 -0.2949 11 Fe++ 0.88048E-13 -13.0553 0.44699E-13 -13.3497 0.50767E+00 -0.2944 12 K+ 0.15657E-03 -3.8053 0.13062E-03 -3.8840 0.83424E+00 -0.0787 13 Na+ 0.19924E-01 -1.7006 0.16589E-01 -1.7802 0.83262E+00 -0.0796 14 Mn++ 0.32801E-10 -10.4841 0.16666E-10 -10.7782 0.50810E+00 -0.2940 15 F- 0.72080E-05 -5.1422 0.59898E-05 -5.2226 0.83100E+00 -0.0804 16 HPO4-- 0.45552E-07 -7.3415 0.23390E-07 -7.6310 0.51348E+00 -0.2895 18 HSiO3- 0.10297E-01 -1.9873 0.85749E-02 -2.0668 0.83278E+00 -0.0795 19 Ca(HSiO3)+ 0.67999E-08 -8.1675 0.56740E-08 -8.2461 0.83443E+00 -0.0786 20 Mg(HSiO3)+ 0.33033E-11 -11.4811 0.27563E-11 -11.5597 0.83443E+00 -0.0786 21 NaHSiO3,aq 0.23006E-02 -2.6382 0.23006E-02 -2.6382 0.10000E+01 0.0000 22 AlO+ 0.52225E-16 -16.2821 0.43578E-16 -16.3607 0.83443E+00 -0.0786 24 HAlO2,aq 0.86442E-10 -10.0633 0.86442E-10 -10.0633 0.10000E+01 0.0000 25 AlO2- 0.22929E-05 -5.6396 0.19059E-05 -5.7199 0.83122E+00 -0.0803 26 CH4,aq 0.40831E-08 -8.3890 0.40677E-08 -8.3906 0.99624E+00 -0.0016 27 C2H6,aq 0.13498E-19 -19.8697 0.13447E-19 -19.8714 0.99624E+00 -0.0016 31 CO,aq 0.50912E-15 -15.2932 0.50912E-15 -15.2932 0.10000E+01 0.0000 32 CO2,aq 0.96710E-07 -7.0145 0.96346E-07 -7.0162 0.99624E+00 -0.0016 33 CO3-2 0.76274E-03 -3.1176 0.39074E-03 -3.4081 0.51228E+00 -0.2905 34 CaCO3,aq 0.14235E-06 -6.8466 0.14235E-06 -6.8466 0.10000E+01 0.0000 35 Ca(HCO3)+ 0.39919E-09 -9.3988 0.33309E-09 -9.4774 0.83443E+00 -0.0786 36 CaCl+ 0.12076E-10 -10.9181 0.10076E-10 -10.9967 0.83443E+00 -0.0786 37 CaCl2,aq 0.51301E-15 -15.2899 0.51301E-15 -15.2899 0.10000E+01 0.0000 38 CaF+ 0.30451E-11 -11.5164 0.25409E-11 -11.5950 0.83443E+00 -0.0786 39 CaOH+ 0.24718E-07 -7.6070 0.20626E-07 -7.6856 0.83443E+00 -0.0786 40 CaSO4,aq 0.32345E-09 -9.4902 0.32345E-09 -9.4902 0.10000E+01 0.0000 41 HCl,aq 0.39425E-14 -14.4042 0.39425E-14 -14.4042 0.10000E+01 0.0000 45 HF,aq 0.41167E-11 -11.3854 0.41167E-11 -11.3854 0.10000E+01 0.0000 46 HF2- 0.99970E-17 -17.0001 0.83253E-17 -17.0796 0.83278E+00 -0.0795 48 FeCl+ 0.18170E-16 -16.7406 0.15162E-16 -16.8192 0.83443E+00 -0.0786 51 FeF+ 0.16397E-16 -16.7852 0.13682E-16 -16.8639 0.83443E+00 -0.0786 53 FeO,aq 0.17236E-09 -9.7636 0.17236E-09 -9.7636 0.10000E+01 0.0000 54 FeOH+ 0.17368E-10 -10.7602 0.14493E-10 -10.8389 0.83443E+00 -0.0786 55 HFeO2- 0.21569E-07 -7.6662 0.17963E-07 -7.7456 0.83278E+00 -0.0795 56 FeO+ 0.90324E-16 -16.0442 0.75369E-16 -16.1228 0.83443E+00 -0.0786 58 FeO2- 0.18373E-08 -8.7358 0.15300E-08 -8.8153 0.83278E+00 -0.0795 59 HFeO2,aq 0.19537E-10 -10.7091 0.19537E-10 -10.7091 0.10000E+01 0.0000 60 H2,aq 0.21115E-06 -6.6754 0.21036E-06 -6.6770 0.99624E+00 -0.0016 61 KCl,aq 0.50732E-09 -9.2947 0.50732E-09 -9.2947 0.10000E+01 0.0000 62 KHSO4,aq 0.12998E-17 -17.8861 0.12998E-17 -17.8861 0.10000E+01 0.0000 63 KOH,aq 0.55561E-06 -6.2552 0.55561E-06 -6.2552 0.10000E+01 0.0000 64 KSO4- 0.85325E-07 -7.0689 0.71057E-07 -7.1484 0.83278E+00 -0.0795 65 MgCO3,aq 0.13928E-10 -10.8561 0.13928E-10 -10.8561 0.10000E+01 0.0000 66 Mg(HCO3)+ 0.15922E-12 -12.7980 0.13286E-12 -12.8766 0.83443E+00 -0.0786 67 MgCl+ 0.42722E-14 -14.3693 0.35648E-14 -14.4480 0.83443E+00 -0.0786 68 MgF+ 0.44030E-14 -14.3562 0.36740E-14 -14.4349 0.83443E+00 -0.0786 69 MgOH+ 0.53390E-10 -10.2725 0.44550E-10 -10.3512 0.83443E+00 -0.0786 71 MnF+ 0.20151E-14 -14.6957 0.16814E-14 -14.7743 0.83443E+00 -0.0786 72 MnO,aq 0.17123E-08 -8.7664 0.17123E-08 -8.7664 0.10000E+01 0.0000 73 MnOH+ 0.60158E-09 -9.2207 0.50197E-09 -9.2993 0.83443E+00 -0.0786 74 MnO2-2 0.11006E-10 -10.9584 0.56379E-11 -11.2489 0.51228E+00 -0.2905 75 HMnO2- 0.14891E-09 -9.8271 0.12401E-09 -9.9066 0.83278E+00 -0.0795 78 MnCl+ 0.26357E-13 -13.5791 0.21993E-13 -13.6577 0.83443E+00 -0.0786 79 MnSO4,aq 0.16867E-12 -12.7730 0.16867E-12 -12.7730 0.10000E+01 0.0000 80 NaCl,aq 0.11781E-05 -5.9288 0.11781E-05 -5.9288 0.10000E+01 0.0000 81 NaF,aq 0.23263E-07 -7.6333 0.23263E-07 -7.6333 0.10000E+01 0.0000 82 NaOH,aq 0.70991E-04 -4.1488 0.70991E-04 -4.1488 0.10000E+01 0.0000 84 OH- 0.69234E-02 -2.1597 0.57549E-02 -2.2400 0.83122E+00 -0.0803 89 HPO3-2 0.29931E-16 -16.5239 0.15333E-16 -16.8144 0.51228E+00 -0.2905 92 H3PO4,aq 0.16489E-17 -17.7828 0.16489E-17 -17.7828 0.10000E+01 0.0000 93 H2PO4- 0.51967E-10 -10.2843 0.43319E-10 -10.3633 0.83359E+00 -0.0790 94 PO4-3 0.80281E-09 -9.0954 0.19008E-09 -9.7211 0.23677E+00 -0.6257 98 HP2O7-3 0.12990E-17 -17.8864 0.29265E-18 -18.5337 0.22529E+00 -0.6473 99 P2O7-4 0.94527E-17 -17.0244 0.69636E-18 -18.1572 0.73668E-01 -1.1327 100 H2S,aq 0.10181E-06 -6.9922 0.10143E-06 -6.9939 0.99624E+00 -0.0016 101 S2-2 0.21970E-10 -10.6582 0.11255E-10 -10.9487 0.51228E+00 -0.2905 102 S3-2 0.14272E-16 -16.8455 0.73112E-17 -17.1360 0.51228E+00 -0.2905 107 SO3-2 0.18431E-11 -11.7345 0.95831E-12 -12.0185 0.51995E+00 -0.2840 108 HSO3- 0.72337E-14 -14.1406 0.60240E-14 -14.2201 0.83278E+00 -0.0795 109 HSO4- 0.40609E-11 -11.3914 0.33919E-11 -11.4696 0.83527E+00 -0.0782 111 S2O3-2 0.81534E-13 -13.0887 0.41768E-13 -13.3792 0.51228E+00 -0.2905 Charge balance for all species = -.6131E-08 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.1198067E-09 -.2036446E-01 -.2048921E+02 0.0000 2 H2O 0.1000000E+01 0.5550265E+02 0.9980975E+06 0.0000 3 Cl- 0.2573300E-03 0.2585086E-03 0.9148413E+01 6.3293 4 SO4-- 0.6828376E-04 0.6831278E-04 0.6550425E+01 15.5413 5 HCO3- 0.5384866E-03 0.1301472E-02 0.7926927E+02 6.6506 6 HS- 0.3924540E-03 0.3926125E-03 0.1296111E+02 6.5127 7 Al+++ 0.1434659E-28 0.2292979E-05 0.6175667E-01 0.5039 8 H4SiO4 0.9219829E-03 0.1351944E-01 0.1297087E+04 -3.0353 9 Ca++ 0.5702622E-07 0.2316346E-06 0.9266743E-02 12.4598 10 Mg++ 0.2236543E-10 0.9315463E-10 0.2260699E-05 9.0512 11 Fe++ 0.8804800E-13 0.2361608E-07 0.1316514E-02 6.6469 12 K+ 0.1565712E-03 0.1572126E-03 0.6136264E+01 6.1143 13 Na+ 0.1992355E-01 0.2229639E-01 0.5116670E+03 8.2181 14 Mn++ 0.3280055E-10 0.2506815E-08 0.1374716E-03 9.2184 15 F- 0.7207953E-05 0.7231223E-05 0.1371315E+00 4.7757 16 HPO4-- 0.4555172E-07 0.4640649E-07 0.4446033E-02 12.3656 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.1830482E-01 -.1829394E-01 -.1088137E-04 0.0000000E+00 2 H2O 0.4985950E+02 0.4985951E+02 -.1084724E-04 0.0000000E+00 3 Cl- 0.2322252E-03 0.2322252E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.6136719E-04 0.6136719E-04 0.0000000E+00 0.0000000E+00 5 HCO3- 0.1169147E-02 0.1169147E-02 0.0000000E+00 0.0000000E+00 6 HS- 0.3526943E-03 0.3526943E-03 0.0000000E+00 0.0000000E+00 7 Al+++ 0.4775352E-05 0.2059844E-05 0.2715508E-05 0.0000000E+00 8 H4SiO4 0.1215302E-01 0.1214487E-01 0.8151074E-05 0.0000000E+00 9 Ca++ 0.2080835E-06 0.2080835E-06 0.0000000E+00 0.0000000E+00 10 Mg++ 0.8368328E-10 0.8368328E-10 0.0000000E+00 0.0000000E+00 11 Fe++ 0.3259227E-07 0.2121496E-07 0.1137731E-07 0.0000000E+00 12 K+ 0.1412294E-03 0.1412283E-03 0.1137731E-08 0.0000000E+00 13 Na+ 0.2003215E-01 0.2002944E-01 0.2710957E-05 0.0000000E+00 14 Mn++ 0.2251939E-08 0.2251939E-08 0.0000000E+00 0.0000000E+00 15 F- 0.6496000E-05 0.6496000E-05 0.0000000E+00 0.0000000E+00 16 HPO4-- 0.4168819E-07 0.4168819E-07 0.0000000E+00 0.0000000E+00 Chg. balance for solid moles: 0.1271E-20 Mass of aqueous solution: 0.899946E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 0.0159900 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 0.2711E-05 -5.567 0.7109E-03 -3.148 99.66 0.2729E-03 stilpnomelane-Fe 0.2275E-08 -8.643 0.2453E-05 -5.610 0.3439 0.8473E-06 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 0.000713 g Volume = 0.000274 cm3 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.0159900 moles log = -1.7962 Original solution: 1000.0103000 g Original solution / Rock added: 62539.73 (Water/Rock Ratio), log = 4.7962 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0206 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9997E+00 0.9859 0.1006E+01 0.1020E+01 CO2,gas 0.1003E-04 1.0071 0.1031E-04 0.1024E-04 CH4,gas 0.5794E-05 1.0125 0.5987E-05 0.5913E-05 H2,gas 0.2705E-03 1.0005 0.2762E-03 0.2760E-03 H2S,gas 0.2743E-05 0.9960 0.2788E-05 0.2799E-05 S2,gas 0.3749E-23 1.0000 0.3826E-23 0.3826E-23 CO,gas 0.7434E-12 1.0000 0.7587E-12 0.7587E-12 SO3,gas 0.1309E-39 1.0000 0.1336E-39 0.1336E-39 SO2,gas 0.1407E-20 1.0000 0.1436E-20 0.1436E-20 HF,gas 0.9904E-14 1.0000 0.1011E-13 0.1011E-13 HCl,gas 0.6816E-17 1.0000 0.6957E-17 0.6957E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 17 albite -0.38 -0.38 0.00 0.000 -0.94784E-12 165 stilpnomelane-Fe 13.02 13.02 0.00 0.000 0.21232E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -13.35 -6.69 -2.229 0.11416E+05 -4.987 3 CH4,gas 4.54 -2.38 -6.92 -1.730 0.11819E+05 -5.223 4 H2,gas 8.00 2.74 -5.26 -3.004 0.89775E+04 -3.559 5 H2S,gas -6.23 -13.48 -7.25 -3.627 0.12385E+05 -5.555 6 S2,gas -7.34 -32.45 -25.12 -3.864 0.42885E+05 -23.417 7 CO,gas 3.21 -10.60 -13.82 -4.252 0.23595E+05 -12.120 8 SO3,gas 17.12 -24.45 -41.57 -10.393 0.70985E+05 -39.874 9 SO2,gas 0.83 -21.71 -22.54 -6.011 0.38490E+05 -20.843 10 HF,gas 0.47 -15.22 -15.69 -7.847 0.26798E+05 -13.995 11 HCl,gas 5.19 -13.67 -18.86 -9.428 0.32197E+05 -17.158 12 acmite 7.71 7.42 -0.29 -0.030 0.48885E+03 16 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 20 spessartine 24.46 19.56 -4.90 -0.245 0.83670E+04 21 analcite 3.32 2.65 -0.67 -0.074 0.11448E+04 25 annite 20.12 17.45 -2.67 -0.148 0.45598E+04 26 phlogopite 27.06 24.67 -2.40 -0.133 0.40955E+04 31 apatite-OH -18.15 -20.58 -2.43 -0.187 0.41495E+04 32 apatite-F -34.30 -35.80 -1.50 -0.125 0.25673E+04 36 aragonite 0.97 -0.89 -1.85 -0.618 0.31634E+04 37 brucite 12.57 9.05 -3.52 -0.703 0.60058E+04 38 calcite 0.81 -0.89 -1.70 -0.566 0.28991E+04 39 carnegieite-low 9.02 5.69 -3.34 -0.477 0.56972E+04 40 carnegieite-high 10.09 5.69 -4.41 -0.630 0.75242E+04 41 carpholite-Mg 8.58 3.99 -4.59 -0.306 0.78436E+04 43 celadonite 5.34 3.53 -1.81 -0.107 0.30962E+04 44 celadonite-Fe 3.88 1.12 -2.75 -0.162 0.47000E+04 45 chrysotile 23.89 21.08 -2.81 -0.234 0.47967E+04 47 clinochlore 39.07 37.16 -1.91 -0.060 0.32638E+04 48 daphnite 28.97 25.14 -3.83 -0.120 0.65380E+04 52 chloritoid-Fe 9.17 4.62 -4.55 -0.304 0.77763E+04 53 chloritoid-Mn 11.40 7.19 -4.21 -0.281 0.71888E+04 55 coesite -2.38 -3.04 -0.66 -0.220 0.11256E+04 62 cristobalite -2.56 -3.04 -0.47 -0.158 0.81094E+03 64 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71254E+04 66 diaspore 2.87 0.50 -2.37 -0.395 0.40464E+04 67 diamond -3.10 -7.86 -4.76 -1.360 0.81269E+04 68 diopside 16.18 15.44 -0.74 -0.074 0.12651E+04 69 hedenbergite 14.21 13.04 -1.17 -0.117 0.20015E+04 76 epidote 24.67 22.10 -2.57 -0.125 0.43926E+04 78 epidote-Fe 29.84 26.87 -2.97 -0.154 0.50737E+04 79 fayalite 14.05 10.26 -3.79 -0.541 0.64667E+04 80 ferrosilite 11.15 7.22 -3.93 -0.393 0.67040E+04 84 gibbsite 4.08 0.50 -3.58 -0.511 0.61050E+04 85 glaucophane 22.97 20.32 -2.66 -0.072 0.45409E+04 86 glaucophane-Fe 17.28 13.10 -4.17 -0.113 0.71262E+04 87 graphite -3.55 -7.86 -4.32 -1.233 0.73691E+04 88 greenalite 16.14 13.87 -2.27 -0.189 0.38751E+04 91 hematite 12.57 10.55 -2.01 -0.244 0.34396E+04 92 heulandite -5.83 -7.78 -1.95 -0.089 0.33333E+04 96 jadeite 4.22 2.65 -1.56 -0.156 0.26703E+04 97 julgoldite 70.43 66.02 -4.40 -0.114 0.75167E+04 98 kalsilite 7.58 3.58 -4.00 -0.572 0.68316E+04 99 kaolinite -1.33 -5.06 -3.73 -0.339 0.63689E+04 102 laumontite 2.88 1.33 -1.56 -0.104 0.26585E+04 103 lawsonite 9.62 7.40 -2.22 -0.148 0.37891E+04 104 leucite 4.12 0.55 -3.57 -0.357 0.60978E+04 106 lizardite 23.24 21.08 -2.16 -0.180 0.36894E+04 107 magnesite 0.69 -4.29 -4.99 -1.662 0.85123E+04 108 magnetite 20.09 17.20 -2.89 -0.236 0.49325E+04 109 minnesotaite 10.39 7.80 -2.59 -0.152 0.44200E+04 113 manganosite 14.06 9.22 -4.84 -1.210 0.82637E+04 117 microcline -2.49 -2.49 0.00 0.000 0.20180E+01 121 muscovite 2.58 -1.48 -4.06 -0.239 0.69364E+04 122 paragonite 4.24 0.62 -3.62 -0.213 0.61735E+04 123 nepheline 8.34 5.69 -2.65 -0.379 0.45295E+04 129 periclase-Fe 11.63 6.65 -4.98 -1.245 0.85027E+04 135 phlogopite-Na 29.65 26.77 -2.88 -0.160 0.49123E+04 137 prehnite 19.37 16.82 -2.55 -0.150 0.43547E+04 138 prehnite-Fe 22.50 21.59 -0.90 -0.054 0.15442E+04 143 pyrite -21.25 -23.06 -1.82 -0.427 0.31007E+04 144 pyrrhotite -4.26 -6.84 -2.58 -0.859 0.43997E+04 145 pyrrhotiteFe0.875 -6.02 -8.01 -1.99 -0.732 0.33995E+04 146 pyroxmangite 7.40 6.18 -1.22 -0.243 0.20755E+04 147 pyrophyllite -6.18 -11.13 -4.96 -0.310 0.84649E+04 148 quartz -2.99 -3.04 -0.05 -0.015 0.78274E+02 152 rhodochrosite -0.98 -4.13 -3.15 -1.050 0.53806E+04 153 rhodonite 7.45 6.18 -1.26 -0.253 0.21558E+04 154 sanidine -1.28 -2.49 -1.21 -0.093 0.20698E+04 156 siderite -2.61 -6.70 -4.09 -1.364 0.69851E+04 164 stilbite -7.52 -7.78 -0.26 -0.012 0.43944E+03 166 stilpnomelane-Mg 27.44 25.04 -2.40 -0.072 0.41024E+04 172 talc 16.49 15.01 -1.48 -0.087 0.25245E+04 175 tephroite 18.09 15.40 -2.68 -0.383 0.45833E+04 179 tridymite -2.63 -3.04 -0.41 -0.136 0.69825E+03 180 tremolite 47.87 45.89 -1.98 -0.053 0.33736E+04 181 ferroactinolite 38.45 33.87 -4.58 -0.124 0.78214E+04 182 troilite-low -4.41 -6.84 -2.43 -0.809 0.41425E+04 188 wairakite 3.95 1.33 -2.62 -0.154 0.44805E+04 189 walstromite 11.51 9.42 -2.08 -0.417 0.35596E+04 190 wollastonite 10.46 9.42 -1.04 -0.207 0.17700E+04 191 pseudo-wollastonite 11.00 9.42 -1.58 -0.315 0.26899E+04 193 akaganeite 7.75 5.28 -2.48 -0.536 0.42323E+04 200 chalcedony -2.80 -3.04 -0.23 -0.078 0.39757E+03 202 montmorillonite-Ca -2.29 -6.26 -3.97 -0.245 0.67721E+04 203 montmorillonite-K -2.24 -6.30 -4.06 -0.249 0.69294E+04 204 montmorillonite-Mg -2.48 -6.82 -4.34 -0.268 0.74094E+04 205 montmorillonite-Na -2.04 -5.60 -3.56 -0.218 0.60837E+04 206 nontronite-Ca 3.21 1.63 -1.58 -0.103 0.26980E+04 207 nontronite-H 2.53 -0.42 -2.95 -0.198 0.50441E+04 208 nontronite-K 3.34 1.60 -1.74 -0.112 0.29786E+04 209 nontronite-Mg 3.07 1.07 -2.00 -0.130 0.34194E+04 210 nontronite-Na 3.52 2.29 -1.23 -0.079 0.20988E+04 226 tobermorite 9.82 7.34 -2.48 -0.676 0.42334E+04 232 alabandite -0.98 -4.27 -3.29 -1.096 0.56135E+04 235 boehmite 4.41 0.50 -3.90 -0.650 0.66633E+04 237 ferrous-oxide 9.81 6.65 -3.16 -0.791 0.54037E+04 243 silica-amorphous -2.09 -3.04 -0.94 -0.315 0.16117E+04 245 an20ab80 2.02 1.17 -0.85 -0.065 0.14436E+04 246 an25ab75 2.65 1.56 -1.08 -0.083 0.18515E+04 247 an30ab70 3.28 1.95 -1.33 -0.102 0.22690E+04 248 tr.625ac.25prg.125 45.16 43.73 -1.43 -0.039 0.24470E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 0.0004000 MOLES Current total amount of reactant added: 0.0159900 MOLES New total amount of reactant added: 0.0163900 MOLES Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.5508E-08 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 7 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 0.0163900 Water: Moles liquid = 0.4986E+02 kg liquid = 0.8983E+00 Moles total = 0.4986E+02 kg total = 0.8982E+00 Activity = 1.0000 Stoichiometric ionic strength = .1238127E-01 Osmotic coef. = 0.9417 True ionic strength = .2093154E-01 Chg. balance for total moles = -.5508E-08 Max. difference allowed = 0.2346E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.12081E-09 -9.9179 0.10123E-09 -9.9947 0.83794E+00 -0.0768 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.25994E-03 -3.5851 0.21646E-03 -3.6646 0.83272E+00 -0.0795 4 SO4-- 0.70407E-04 -4.1524 0.36138E-04 -4.4420 0.51328E+00 -0.2896 5 HCO3- 0.55441E-03 -3.2562 0.46237E-03 -3.3350 0.83398E+00 -0.0788 6 HS- 0.40114E-03 -3.3967 0.33409E-03 -3.4761 0.83285E+00 -0.0794 7 Al+++ 0.14501E-28 -28.8386 0.32616E-29 -29.4866 0.22492E+00 -0.6480 8 H4SiO4 0.92903E-03 -3.0320 0.92903E-03 -3.0320 0.10000E+01 0.0000 9 Ca++ 0.56353E-07 -7.2491 0.28704E-07 -7.5421 0.50937E+00 -0.2930 10 Mg++ 0.22403E-10 -10.6497 0.11358E-10 -10.9447 0.50696E+00 -0.2950 11 Fe++ 0.89045E-13 -13.0504 0.45193E-13 -13.3449 0.50753E+00 -0.2945 12 K+ 0.15657E-03 -3.8053 0.13061E-03 -3.8840 0.83419E+00 -0.0787 13 Na+ 0.19925E-01 -1.7006 0.16589E-01 -1.7802 0.83256E+00 -0.0796 14 Mn++ 0.33299E-10 -10.4776 0.16915E-10 -10.7717 0.50797E+00 -0.2942 15 F- 0.73854E-05 -5.1316 0.61369E-05 -5.2121 0.83095E+00 -0.0804 16 HPO4-- 0.45557E-07 -7.3414 0.23387E-07 -7.6310 0.51335E+00 -0.2896 18 HSiO3- 0.10291E-01 -1.9875 0.85695E-02 -2.0670 0.83272E+00 -0.0795 19 Ca(HSiO3)+ 0.67140E-08 -8.1730 0.56019E-08 -8.2517 0.83437E+00 -0.0786 20 Mg(HSiO3)+ 0.33061E-11 -11.4807 0.27585E-11 -11.5593 0.83437E+00 -0.0786 21 NaHSiO3,aq 0.22992E-02 -2.6384 0.22992E-02 -2.6384 0.10000E+01 0.0000 22 AlO+ 0.51897E-16 -16.2849 0.43301E-16 -16.3635 0.83437E+00 -0.0786 24 HAlO2,aq 0.85187E-10 -10.0696 0.85187E-10 -10.0696 0.10000E+01 0.0000 25 AlO2- 0.22412E-05 -5.6495 0.18628E-05 -5.7298 0.83117E+00 -0.0803 26 CH4,aq 0.41679E-08 -8.3801 0.41522E-08 -8.3817 0.99623E+00 -0.0016 27 C2H6,aq 0.14124E-19 -19.8501 0.14070E-19 -19.8517 0.99623E+00 -0.0016 31 CO,aq 0.52628E-15 -15.2788 0.52628E-15 -15.2788 0.10000E+01 0.0000 32 CO2,aq 0.10039E-06 -6.9983 0.10001E-06 -7.0000 0.99623E+00 -0.0016 33 CO3-2 0.77899E-03 -3.1085 0.39896E-03 -3.3991 0.51215E+00 -0.2906 34 CaCO3,aq 0.14359E-06 -6.8429 0.14359E-06 -6.8429 0.10000E+01 0.0000 35 Ca(HCO3)+ 0.40603E-09 -9.3914 0.33878E-09 -9.4701 0.83437E+00 -0.0786 36 CaCl+ 0.12051E-10 -10.9190 0.10055E-10 -10.9976 0.83437E+00 -0.0786 37 CaCl2,aq 0.51710E-15 -15.2864 0.51710E-15 -15.2864 0.10000E+01 0.0000 38 CaF+ 0.30824E-11 -11.5111 0.25719E-11 -11.5897 0.83437E+00 -0.0786 39 CaOH+ 0.24221E-07 -7.6158 0.20209E-07 -7.6945 0.83437E+00 -0.0786 40 CaSO4,aq 0.32940E-09 -9.4823 0.32940E-09 -9.4823 0.10000E+01 0.0000 41 HCl,aq 0.40153E-14 -14.3963 0.40153E-14 -14.3963 0.10000E+01 0.0000 45 HF,aq 0.42528E-11 -11.3713 0.42528E-11 -11.3713 0.10000E+01 0.0000 46 HF2- 0.10582E-16 -16.9754 0.88116E-17 -17.0549 0.83272E+00 -0.0795 48 FeCl+ 0.18558E-16 -16.7315 0.15484E-16 -16.8101 0.83437E+00 -0.0786 51 FeF+ 0.16986E-16 -16.7699 0.14173E-16 -16.8485 0.83437E+00 -0.0786 53 FeO,aq 0.17141E-09 -9.7660 0.17141E-09 -9.7660 0.10000E+01 0.0000 54 FeOH+ 0.17417E-10 -10.7590 0.14532E-10 -10.8377 0.83437E+00 -0.0786 55 HFeO2- 0.21276E-07 -7.6721 0.17717E-07 -7.7516 0.83272E+00 -0.0795 56 FeO+ 0.90769E-16 -16.0421 0.75735E-16 -16.1207 0.83437E+00 -0.0786 58 FeO2- 0.18161E-08 -8.7409 0.15123E-08 -8.8204 0.83272E+00 -0.0795 59 HFeO2,aq 0.19470E-10 -10.7106 0.19470E-10 -10.7106 0.10000E+01 0.0000 60 H2,aq 0.21027E-06 -6.6772 0.20947E-06 -6.6789 0.99623E+00 -0.0016 61 KCl,aq 0.51241E-09 -9.2904 0.51241E-09 -9.2904 0.10000E+01 0.0000 62 KHSO4,aq 0.13509E-17 -17.8694 0.13509E-17 -17.8694 0.10000E+01 0.0000 63 KOH,aq 0.55101E-06 -6.2588 0.55101E-06 -6.2588 0.10000E+01 0.0000 64 KSO4- 0.87956E-07 -7.0557 0.73243E-07 -7.1352 0.83272E+00 -0.0795 65 MgCO3,aq 0.14241E-10 -10.8464 0.14241E-10 -10.8464 0.10000E+01 0.0000 66 Mg(HCO3)+ 0.16416E-12 -12.7847 0.13697E-12 -12.8634 0.83437E+00 -0.0786 67 MgCl+ 0.43217E-14 -14.3643 0.36059E-14 -14.4430 0.83437E+00 -0.0786 68 MgF+ 0.45179E-14 -14.3451 0.37696E-14 -14.4237 0.83437E+00 -0.0786 69 MgOH+ 0.53030E-10 -10.2755 0.44247E-10 -10.3541 0.83437E+00 -0.0786 71 MnF+ 0.20955E-14 -14.6787 0.17485E-14 -14.7573 0.83437E+00 -0.0786 72 MnO,aq 0.17095E-08 -8.7671 0.17095E-08 -8.7671 0.10000E+01 0.0000 73 MnOH+ 0.60558E-09 -9.2178 0.50528E-09 -9.2965 0.83437E+00 -0.0786 74 MnO2-2 0.10810E-10 -10.9662 0.55363E-11 -11.2568 0.51215E+00 -0.2906 75 HMnO2- 0.14745E-09 -9.8314 0.12278E-09 -9.9109 0.83272E+00 -0.0795 78 MnCl+ 0.27022E-13 -13.5683 0.22547E-13 -13.6469 0.83437E+00 -0.0786 79 MnSO4,aq 0.17647E-12 -12.7533 0.17647E-12 -12.7533 0.10000E+01 0.0000 80 NaCl,aq 0.11900E-05 -5.9244 0.11900E-05 -5.9244 0.10000E+01 0.0000 81 NaF,aq 0.23835E-07 -7.6228 0.23835E-07 -7.6228 0.10000E+01 0.0000 82 NaOH,aq 0.70410E-04 -4.1524 0.70410E-04 -4.1524 0.10000E+01 0.0000 84 OH- 0.68670E-02 -2.1632 0.57076E-02 -2.2435 0.83117E+00 -0.0803 89 HPO3-2 0.29809E-16 -16.5256 0.15267E-16 -16.8163 0.51215E+00 -0.2906 92 H3PO4,aq 0.16761E-17 -17.7757 0.16761E-17 -17.7757 0.10000E+01 0.0000 93 H2PO4- 0.52394E-10 -10.2807 0.43672E-10 -10.3598 0.83354E+00 -0.0791 94 PO4-3 0.79654E-09 -9.0988 0.18850E-09 -9.7247 0.23664E+00 -0.6259 98 HP2O7-3 0.13102E-17 -17.8827 0.29499E-18 -18.5302 0.22516E+00 -0.6475 99 P2O7-4 0.94597E-17 -17.0241 0.69617E-18 -18.1573 0.73593E-01 -1.1332 100 H2S,aq 0.10492E-06 -6.9791 0.10452E-06 -6.9808 0.99623E+00 -0.0016 101 S2-2 0.23053E-10 -10.6373 0.11807E-10 -10.9279 0.51215E+00 -0.2906 102 S3-2 0.15498E-16 -16.8097 0.79371E-17 -17.1003 0.51215E+00 -0.2906 107 SO3-2 0.18924E-11 -11.7230 0.98372E-12 -12.0071 0.51982E+00 -0.2841 108 HSO3- 0.74875E-14 -14.1257 0.62350E-14 -14.2052 0.83272E+00 -0.0795 109 HSO4- 0.42210E-11 -11.3746 0.35255E-11 -11.4528 0.83521E+00 -0.0782 111 S2O3-2 0.86637E-13 -13.0623 0.44371E-13 -13.3529 0.51215E+00 -0.2906 Charge balance for all species = -.6131E-08 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.1208068E-09 -.2031615E-01 -.2044058E+02 0.0000 2 H2O 0.1000000E+01 0.5550260E+02 0.9980949E+06 0.0000 3 Cl- 0.2599433E-03 0.2611338E-03 0.9241300E+01 6.3301 4 SO4-- 0.7040664E-04 0.7043843E-04 0.6754240E+01 15.5474 5 HCO3- 0.5544120E-03 0.1333655E-02 0.8122933E+02 6.6597 6 HS- 0.4011420E-03 0.4013035E-03 0.1324800E+02 6.5186 7 Al+++ 0.1450126E-28 0.2241279E-05 0.6036414E-01 0.4975 8 H4SiO4 0.9290315E-03 0.1351918E-01 0.1297061E+04 -3.0320 9 Ca++ 0.5635275E-07 0.2316328E-06 0.9266658E-02 12.4473 10 Mg++ 0.2240325E-10 0.9315393E-10 0.2260679E-05 9.0447 11 Fe++ 0.8904517E-13 0.2330055E-07 0.1298922E-02 6.6445 12 K+ 0.1565719E-03 0.1572114E-03 0.6136207E+01 6.1107 13 Na+ 0.1992531E-01 0.2229617E-01 0.5116612E+03 8.2145 14 Mn++ 0.3329921E-10 0.2506797E-08 0.1374703E-03 9.2177 15 F- 0.7385435E-05 0.7409276E-05 0.1405079E+00 4.7826 16 HPO4-- 0.4555722E-07 0.4640615E-07 0.4445993E-02 12.3584 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.1826175E-01 -.1825068E-01 -.1106757E-04 0.0000000E+00 2 H2O 0.4985983E+02 0.4985984E+02 -.1103259E-04 0.0000000E+00 3 Cl- 0.2345852E-03 0.2345852E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.6327719E-04 0.6327719E-04 0.0000000E+00 0.0000000E+00 5 HCO3- 0.1198067E-02 0.1198067E-02 0.0000000E+00 0.0000000E+00 6 HS- 0.3605043E-03 0.3605043E-03 0.0000000E+00 0.0000000E+00 7 Al+++ 0.4775352E-05 0.2013416E-05 0.2761936E-05 0.0000000E+00 8 H4SiO4 0.1215302E-01 0.1214473E-01 0.8290473E-05 0.0000000E+00 9 Ca++ 0.2080835E-06 0.2080835E-06 0.0000000E+00 0.0000000E+00 10 Mg++ 0.8368328E-10 0.8368328E-10 0.0000000E+00 0.0000000E+00 11 Fe++ 0.3259227E-07 0.2093166E-07 0.1166061E-07 0.0000000E+00 12 K+ 0.1412294E-03 0.1412282E-03 0.1166061E-08 0.0000000E+00 13 Na+ 0.2003215E-01 0.2002939E-01 0.2757272E-05 0.0000000E+00 14 Mn++ 0.2251939E-08 0.2251939E-08 0.0000000E+00 0.0000000E+00 15 F- 0.6656000E-05 0.6656000E-05 0.0000000E+00 0.0000000E+00 16 HPO4-- 0.4168819E-07 0.4168819E-07 0.0000000E+00 0.0000000E+00 Chg. balance for solid moles: 0.8470E-21 Mass of aqueous solution: 0.899954E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 0.0163900 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 0.2757E-05 -5.560 0.7230E-03 -3.141 99.65 0.2775E-03 stilpnomelane-Fe 0.2332E-08 -8.632 0.2514E-05 -5.600 0.3465 0.8684E-06 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 0.000726 g Volume = 0.000278 cm3 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.0163900 moles log = -1.7854 Original solution: 1000.0103000 g Original solution / Rock added: 61013.44 (Water/Rock Ratio), log = 4.7854 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0206 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9997E+00 0.9859 0.1006E+01 0.1020E+01 CO2,gas 0.1041E-04 1.0071 0.1070E-04 0.1062E-04 CH4,gas 0.5914E-05 1.0125 0.6112E-05 0.6036E-05 H2,gas 0.2693E-03 1.0005 0.2750E-03 0.2749E-03 H2S,gas 0.2827E-05 0.9960 0.2873E-05 0.2885E-05 S2,gas 0.4015E-23 1.0000 0.4097E-23 0.4097E-23 CO,gas 0.7684E-12 1.0000 0.7843E-12 0.7843E-12 SO3,gas 0.1372E-39 1.0000 0.1400E-39 0.1400E-39 SO2,gas 0.1468E-20 1.0000 0.1498E-20 0.1498E-20 HF,gas 0.1023E-13 1.0000 0.1044E-13 0.1044E-13 HCl,gas 0.6942E-17 1.0000 0.7085E-17 0.7085E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 17 albite -0.38 -0.38 0.00 0.000 -0.94784E-12 165 stilpnomelane-Fe 13.02 13.02 0.00 0.000 0.21232E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -13.33 -6.67 -2.223 0.11388E+05 -4.971 3 CH4,gas 4.54 -2.37 -6.91 -1.728 0.11803E+05 -5.214 4 H2,gas 8.00 2.74 -5.26 -3.005 0.89806E+04 -3.561 5 H2S,gas -6.23 -13.47 -7.24 -3.620 0.12363E+05 -5.542 6 S2,gas -7.34 -32.42 -25.09 -3.859 0.42834E+05 -23.388 7 CO,gas 3.21 -10.59 -13.80 -4.248 0.23571E+05 -12.106 8 SO3,gas 17.12 -24.43 -41.55 -10.388 0.70950E+05 -39.854 9 SO2,gas 0.83 -21.69 -22.52 -6.006 0.38458E+05 -20.824 10 HF,gas 0.47 -15.21 -15.68 -7.840 0.26773E+05 -13.981 11 HCl,gas 5.19 -13.66 -18.85 -9.424 0.32184E+05 -17.150 12 acmite 7.71 7.42 -0.28 -0.030 0.48618E+03 16 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 20 spessartine 24.46 19.55 -4.91 -0.245 0.83755E+04 21 analcite 3.32 2.65 -0.67 -0.075 0.11504E+04 25 annite 20.12 17.45 -2.68 -0.149 0.45721E+04 26 phlogopite 27.06 24.65 -2.42 -0.134 0.41291E+04 31 apatite-OH -18.15 -20.62 -2.47 -0.190 0.42193E+04 32 apatite-F -34.30 -35.83 -1.53 -0.128 0.26130E+04 36 aragonite 0.97 -0.88 -1.85 -0.616 0.31569E+04 37 brucite 12.57 9.04 -3.52 -0.705 0.60169E+04 38 calcite 0.81 -0.88 -1.69 -0.565 0.28927E+04 39 carnegieite-low 9.02 5.68 -3.34 -0.478 0.57085E+04 40 carnegieite-high 10.09 5.68 -4.41 -0.630 0.75355E+04 41 carpholite-Mg 8.58 3.98 -4.61 -0.307 0.78651E+04 43 celadonite 5.34 3.52 -1.82 -0.107 0.31018E+04 44 celadonite-Fe 3.88 1.12 -2.75 -0.162 0.46985E+04 45 chrysotile 23.89 21.07 -2.82 -0.235 0.48190E+04 47 clinochlore 39.07 37.12 -1.95 -0.061 0.33244E+04 48 daphnite 28.97 25.12 -3.84 -0.120 0.65631E+04 52 chloritoid-Fe 9.17 4.61 -4.57 -0.304 0.77965E+04 53 chloritoid-Mn 11.40 7.18 -4.22 -0.281 0.72061E+04 55 coesite -2.38 -3.03 -0.66 -0.219 0.11199E+04 62 cristobalite -2.56 -3.03 -0.47 -0.157 0.80530E+03 64 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71255E+04 66 diaspore 2.87 0.50 -2.38 -0.396 0.40573E+04 67 diamond -3.10 -7.85 -4.75 -1.356 0.81054E+04 68 diopside 16.18 15.43 -0.75 -0.075 0.12862E+04 69 hedenbergite 14.21 13.03 -1.18 -0.118 0.20155E+04 76 epidote 24.67 22.07 -2.60 -0.126 0.44423E+04 78 epidote-Fe 29.84 26.85 -3.00 -0.156 0.51151E+04 79 fayalite 14.05 10.26 -3.79 -0.541 0.64692E+04 80 ferrosilite 11.15 7.22 -3.92 -0.392 0.67009E+04 84 gibbsite 4.08 0.50 -3.58 -0.512 0.61158E+04 85 glaucophane 22.97 20.30 -2.67 -0.072 0.45631E+04 86 glaucophane-Fe 17.28 13.10 -4.17 -0.113 0.71271E+04 87 graphite -3.55 -7.85 -4.30 -1.229 0.73477E+04 88 greenalite 16.14 13.87 -2.27 -0.189 0.38760E+04 91 hematite 12.57 10.55 -2.02 -0.245 0.34446E+04 92 heulandite -5.83 -7.78 -1.95 -0.089 0.33367E+04 96 jadeite 4.22 2.65 -1.57 -0.157 0.26759E+04 97 julgoldite 70.43 65.98 -4.44 -0.115 0.75860E+04 98 kalsilite 7.58 3.58 -4.01 -0.573 0.68430E+04 99 kaolinite -1.33 -5.07 -3.74 -0.340 0.63793E+04 102 laumontite 2.88 1.31 -1.57 -0.105 0.26789E+04 103 lawsonite 9.62 7.38 -2.24 -0.149 0.38207E+04 104 leucite 4.12 0.54 -3.57 -0.357 0.61035E+04 106 lizardite 23.24 21.07 -2.17 -0.181 0.37116E+04 107 magnesite 0.69 -4.29 -4.98 -1.659 0.84958E+04 108 magnetite 20.09 17.19 -2.89 -0.236 0.49417E+04 109 minnesotaite 10.39 7.81 -2.58 -0.152 0.44097E+04 113 manganosite 14.06 9.22 -4.84 -1.210 0.82649E+04 117 microcline -2.49 -2.49 0.00 0.000 0.20789E+01 121 muscovite 2.58 -1.49 -4.08 -0.240 0.69581E+04 122 paragonite 4.24 0.61 -3.63 -0.213 0.61951E+04 123 nepheline 8.34 5.68 -2.66 -0.380 0.45408E+04 129 periclase-Fe 11.63 6.64 -4.98 -1.246 0.85068E+04 135 phlogopite-Na 29.65 26.75 -2.90 -0.161 0.49459E+04 137 prehnite 19.37 16.79 -2.58 -0.152 0.44020E+04 138 prehnite-Fe 22.50 21.57 -0.93 -0.056 0.15831E+04 143 pyrite -21.25 -23.04 -1.79 -0.421 0.30571E+04 144 pyrrhotite -4.26 -6.83 -2.57 -0.855 0.43814E+04 145 pyrrhotiteFe0.875 -6.02 -8.00 -1.98 -0.728 0.33804E+04 146 pyroxmangite 7.40 6.19 -1.21 -0.243 0.20711E+04 147 pyrophyllite -6.18 -11.13 -4.96 -0.310 0.84640E+04 148 quartz -2.99 -3.03 -0.04 -0.014 0.72627E+02 152 rhodochrosite -0.98 -4.11 -3.14 -1.045 0.53542E+04 153 rhodonite 7.45 6.19 -1.26 -0.252 0.21514E+04 154 sanidine -1.28 -2.49 -1.21 -0.093 0.20698E+04 156 siderite -2.61 -6.69 -4.08 -1.359 0.69615E+04 164 stilbite -7.52 -7.78 -0.26 -0.012 0.44283E+03 166 stilpnomelane-Mg 27.44 25.02 -2.42 -0.072 0.41379E+04 172 talc 16.49 15.01 -1.48 -0.087 0.25355E+04 175 tephroite 18.09 15.40 -2.68 -0.383 0.45802E+04 179 tridymite -2.63 -3.03 -0.41 -0.135 0.69260E+03 180 tremolite 47.87 45.86 -2.01 -0.054 0.34268E+04 181 ferroactinolite 38.45 33.86 -4.59 -0.124 0.78392E+04 182 troilite-low -4.41 -6.83 -2.42 -0.805 0.41243E+04 188 wairakite 3.95 1.31 -2.64 -0.155 0.45008E+04 189 walstromite 11.51 9.42 -2.09 -0.419 0.35752E+04 190 wollastonite 10.46 9.42 -1.05 -0.209 0.17856E+04 191 pseudo-wollastonite 11.00 9.42 -1.58 -0.317 0.27055E+04 193 akaganeite 7.75 5.27 -2.48 -0.536 0.42349E+04 200 chalcedony -2.80 -3.03 -0.23 -0.077 0.39192E+03 202 montmorillonite-Ca -2.29 -6.26 -3.97 -0.245 0.67748E+04 203 montmorillonite-K -2.24 -6.30 -4.06 -0.249 0.69307E+04 204 montmorillonite-Mg -2.48 -6.82 -4.34 -0.268 0.74105E+04 205 montmorillonite-Na -2.04 -5.60 -3.56 -0.218 0.60849E+04 206 nontronite-Ca 3.21 1.64 -1.58 -0.102 0.26894E+04 207 nontronite-H 2.53 -0.41 -2.95 -0.198 0.50320E+04 208 nontronite-K 3.34 1.60 -1.74 -0.112 0.29685E+04 209 nontronite-Mg 3.07 1.08 -2.00 -0.130 0.34091E+04 210 nontronite-Na 3.52 2.30 -1.22 -0.079 0.20887E+04 226 tobermorite 9.82 7.34 -2.49 -0.678 0.42454E+04 232 alabandite -0.98 -4.25 -3.28 -1.092 0.55925E+04 235 boehmite 4.41 0.50 -3.91 -0.651 0.66742E+04 237 ferrous-oxide 9.81 6.64 -3.17 -0.792 0.54078E+04 243 silica-amorphous -2.09 -3.03 -0.94 -0.314 0.16061E+04 245 an20ab80 2.02 1.17 -0.85 -0.065 0.14500E+04 246 an25ab75 2.65 1.56 -1.09 -0.084 0.18594E+04 247 an30ab70 3.28 1.94 -1.33 -0.103 0.22785E+04 248 tr.625ac.25prg.125 45.16 43.70 -1.46 -0.039 0.24961E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 0.0004000 MOLES Current total amount of reactant added: 0.0163900 MOLES New total amount of reactant added: 0.0167900 MOLES Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.5508E-08 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 7 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 0.0167900 Water: Moles liquid = 0.4987E+02 kg liquid = 0.8983E+00 Moles total = 0.4986E+02 kg total = 0.8982E+00 Activity = 1.0000 Stoichiometric ionic strength = .1240704E-01 Osmotic coef. = 0.9415 True ionic strength = .2095154E-01 Chg. balance for total moles = -.5508E-08 Max. difference allowed = 0.2369E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.12182E-09 -9.9143 0.10207E-09 -9.9911 0.83789E+00 -0.0768 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.26256E-03 -3.5808 0.21862E-03 -3.6603 0.83267E+00 -0.0795 4 SO4-- 0.72529E-04 -4.1395 0.37218E-04 -4.4292 0.51315E+00 -0.2898 5 HCO3- 0.57048E-03 -3.2438 0.47574E-03 -3.3226 0.83393E+00 -0.0789 6 HS- 0.40983E-03 -3.3874 0.34130E-03 -3.4669 0.83279E+00 -0.0795 7 Al+++ 0.14658E-28 -28.8339 0.32950E-29 -29.4821 0.22479E+00 -0.6482 8 H4SiO4 0.93616E-03 -3.0286 0.93616E-03 -3.0286 0.10000E+01 0.0000 9 Ca++ 0.55702E-07 -7.2541 0.28365E-07 -7.5472 0.50924E+00 -0.2931 10 Mg++ 0.22441E-10 -10.6490 0.11374E-10 -10.9441 0.50683E+00 -0.2951 11 Fe++ 0.90058E-13 -13.0455 0.45695E-13 -13.3401 0.50740E+00 -0.2946 12 K+ 0.15657E-03 -3.8053 0.13060E-03 -3.8840 0.83413E+00 -0.0788 13 Na+ 0.19927E-01 -1.7006 0.16589E-01 -1.7802 0.83251E+00 -0.0796 14 Mn++ 0.33807E-10 -10.4710 0.17168E-10 -10.7653 0.50784E+00 -0.2943 15 F- 0.75629E-05 -5.1213 0.62840E-05 -5.2018 0.83089E+00 -0.0805 16 HPO4-- 0.45563E-07 -7.3414 0.23384E-07 -7.6311 0.51322E+00 -0.2897 18 HSiO3- 0.10285E-01 -1.9878 0.85639E-02 -2.0673 0.83267E+00 -0.0795 19 Ca(HSiO3)+ 0.66308E-08 -8.1784 0.55322E-08 -8.2571 0.83432E+00 -0.0787 20 Mg(HSiO3)+ 0.33089E-11 -11.4803 0.27607E-11 -11.5590 0.83432E+00 -0.0787 21 NaHSiO3,aq 0.22978E-02 -2.6387 0.22978E-02 -2.6387 0.10000E+01 0.0000 22 AlO+ 0.51570E-16 -16.2876 0.43026E-16 -16.3663 0.83432E+00 -0.0787 24 HAlO2,aq 0.83947E-10 -10.0760 0.83947E-10 -10.0760 0.10000E+01 0.0000 25 AlO2- 0.21905E-05 -5.6595 0.18205E-05 -5.7398 0.83111E+00 -0.0803 26 CH4,aq 0.42539E-08 -8.3712 0.42378E-08 -8.3729 0.99622E+00 -0.0016 27 C2H6,aq 0.14773E-19 -19.8305 0.14717E-19 -19.8322 0.99622E+00 -0.0016 31 CO,aq 0.54377E-15 -15.2646 0.54377E-15 -15.2646 0.10000E+01 0.0000 32 CO2,aq 0.10415E-06 -6.9823 0.10376E-06 -6.9840 0.99622E+00 -0.0016 33 CO3-2 0.79511E-03 -3.0996 0.40711E-03 -3.3903 0.51202E+00 -0.2907 34 CaCO3,aq 0.14480E-06 -6.8392 0.14480E-06 -6.8392 0.10000E+01 0.0000 35 Ca(HCO3)+ 0.41287E-09 -9.3842 0.34446E-09 -9.4629 0.83432E+00 -0.0787 36 CaCl+ 0.12029E-10 -10.9198 0.10036E-10 -10.9985 0.83432E+00 -0.0787 37 CaCl2,aq 0.52125E-15 -15.2830 0.52125E-15 -15.2830 0.10000E+01 0.0000 38 CaF+ 0.31192E-11 -11.5060 0.26024E-11 -11.5846 0.83432E+00 -0.0787 39 CaOH+ 0.23739E-07 -7.6245 0.19806E-07 -7.7032 0.83432E+00 -0.0787 40 CaSO4,aq 0.33524E-09 -9.4746 0.33524E-09 -9.4746 0.10000E+01 0.0000 41 HCl,aq 0.40891E-14 -14.3884 0.40891E-14 -14.3884 0.10000E+01 0.0000 45 HF,aq 0.43909E-11 -11.3574 0.43909E-11 -11.3574 0.10000E+01 0.0000 46 HF2- 0.11188E-16 -16.9512 0.93159E-17 -17.0308 0.83267E+00 -0.0795 48 FeCl+ 0.18953E-16 -16.7223 0.15813E-16 -16.8010 0.83432E+00 -0.0787 51 FeF+ 0.17588E-16 -16.7548 0.14674E-16 -16.8335 0.83432E+00 -0.0787 53 FeO,aq 0.17046E-09 -9.7684 0.17046E-09 -9.7684 0.10000E+01 0.0000 54 FeOH+ 0.17466E-10 -10.7578 0.14573E-10 -10.8365 0.83432E+00 -0.0787 55 HFeO2- 0.20985E-07 -7.6781 0.17474E-07 -7.7576 0.83267E+00 -0.0795 56 FeO+ 0.91212E-16 -16.0399 0.76100E-16 -16.1186 0.83432E+00 -0.0787 58 FeO2- 0.17950E-08 -8.7459 0.14946E-08 -8.8255 0.83267E+00 -0.0795 59 HFeO2,aq 0.19403E-10 -10.7121 0.19403E-10 -10.7121 0.10000E+01 0.0000 60 H2,aq 0.20941E-06 -6.6790 0.20862E-06 -6.6806 0.99622E+00 -0.0016 61 KCl,aq 0.51749E-09 -9.2861 0.51749E-09 -9.2861 0.10000E+01 0.0000 62 KHSO4,aq 0.14028E-17 -17.8530 0.14028E-17 -17.8530 0.10000E+01 0.0000 63 KOH,aq 0.54643E-06 -6.2625 0.54643E-06 -6.2625 0.10000E+01 0.0000 64 KSO4- 0.90586E-07 -7.0429 0.75428E-07 -7.1225 0.83267E+00 -0.0795 65 MgCO3,aq 0.14553E-10 -10.8370 0.14553E-10 -10.8370 0.10000E+01 0.0000 66 Mg(HCO3)+ 0.16916E-12 -12.7717 0.14113E-12 -12.8504 0.83432E+00 -0.0787 67 MgCl+ 0.43715E-14 -14.3594 0.36472E-14 -14.4380 0.83432E+00 -0.0787 68 MgF+ 0.46331E-14 -14.3341 0.38655E-14 -14.4128 0.83432E+00 -0.0787 69 MgOH+ 0.52672E-10 -10.2784 0.43945E-10 -10.3571 0.83432E+00 -0.0787 71 MnF+ 0.21780E-14 -14.6619 0.18172E-14 -14.7406 0.83432E+00 -0.0787 72 MnO,aq 0.17065E-08 -8.7679 0.17065E-08 -8.7679 0.10000E+01 0.0000 73 MnOH+ 0.60962E-09 -9.2149 0.50862E-09 -9.2936 0.83432E+00 -0.0787 74 MnO2-2 0.10617E-10 -10.9740 0.54360E-11 -11.2647 0.51202E+00 -0.2907 75 HMnO2- 0.14599E-09 -9.8357 0.12156E-09 -9.9152 0.83267E+00 -0.0795 78 MnCl+ 0.27703E-13 -13.5575 0.23113E-13 -13.6361 0.83432E+00 -0.0787 79 MnSO4,aq 0.18447E-12 -12.7341 0.18447E-12 -12.7341 0.10000E+01 0.0000 80 NaCl,aq 0.12019E-05 -5.9201 0.12019E-05 -5.9201 0.10000E+01 0.0000 81 NaF,aq 0.24406E-07 -7.6125 0.24406E-07 -7.6125 0.10000E+01 0.0000 82 NaOH,aq 0.69830E-04 -4.1560 0.69830E-04 -4.1560 0.10000E+01 0.0000 84 OH- 0.68108E-02 -2.1668 0.56605E-02 -2.2471 0.83111E+00 -0.0803 89 HPO3-2 0.29691E-16 -16.5274 0.15202E-16 -16.8181 0.51202E+00 -0.2907 92 H3PO4,aq 0.17039E-17 -17.7686 0.17039E-17 -17.7686 0.10000E+01 0.0000 93 H2PO4- 0.52826E-10 -10.2771 0.44030E-10 -10.3563 0.83349E+00 -0.0791 94 PO4-3 0.79028E-09 -9.1022 0.18691E-09 -9.7284 0.23652E+00 -0.6261 98 HP2O7-3 0.13215E-17 -17.8789 0.29737E-18 -18.5267 0.22503E+00 -0.6478 99 P2O7-4 0.94667E-17 -17.0238 0.69599E-18 -18.1574 0.73519E-01 -1.1336 100 H2S,aq 0.10808E-06 -6.9663 0.10767E-06 -6.9679 0.99622E+00 -0.0016 101 S2-2 0.24164E-10 -10.6168 0.12373E-10 -10.9075 0.51202E+00 -0.2907 102 S3-2 0.16802E-16 -16.7746 0.86030E-17 -17.0654 0.51202E+00 -0.2907 107 SO3-2 0.19415E-11 -11.7119 0.10090E-11 -11.9961 0.51969E+00 -0.2843 108 HSO3- 0.77442E-14 -14.1110 0.64483E-14 -14.1906 0.83267E+00 -0.0795 109 HSO4- 0.43837E-11 -11.3582 0.36611E-11 -11.4364 0.83516E+00 -0.0782 111 S2O3-2 0.91935E-13 -13.0365 0.47072E-13 -13.3272 0.51202E+00 -0.2907 Charge balance for all species = -.6131E-08 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.1218195E-09 -.2026786E-01 -.2039195E+02 0.0000 2 H2O 0.1000000E+01 0.5550255E+02 0.9980923E+06 0.0000 3 Cl- 0.2625565E-03 0.2637589E-03 0.9334185E+01 6.3308 4 SO4-- 0.7252949E-04 0.7256405E-04 0.6958051E+01 15.5529 5 HCO3- 0.5704788E-03 0.1365838E-02 0.8318935E+02 6.6685 6 HS- 0.4098298E-03 0.4099943E-03 0.1353488E+02 6.5242 7 Al+++ 0.1465832E-28 0.2190553E-05 0.5899784E-01 0.4911 8 H4SiO4 0.9361608E-03 0.1351893E-01 0.1297034E+04 -3.0286 9 Ca++ 0.5570156E-07 0.2316311E-06 0.9266574E-02 12.4350 10 Mg++ 0.2244140E-10 0.9315323E-10 0.2260658E-05 9.0381 11 Fe++ 0.9005782E-13 0.2298785E-07 0.1281488E-02 6.6421 12 K+ 0.1565727E-03 0.1572102E-03 0.6136149E+01 6.1070 13 Na+ 0.1992708E-01 0.2229595E-01 0.5116553E+03 8.2109 14 Mn++ 0.3380674E-10 0.2506778E-08 0.1374691E-03 9.2169 15 F- 0.7562914E-05 0.7587327E-05 0.1438842E+00 4.7893 16 HPO4-- 0.4556269E-07 0.4640580E-07 0.4445952E-02 12.3511 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.1821868E-01 -.1820743E-01 -.1125026E-04 0.0000000E+00 2 H2O 0.4986015E+02 0.4986017E+02 -.1121444E-04 0.0000000E+00 3 Cl- 0.2369452E-03 0.2369452E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.6518719E-04 0.6518719E-04 0.0000000E+00 0.0000000E+00 5 HCO3- 0.1226987E-02 0.1226987E-02 0.0000000E+00 0.0000000E+00 6 HS- 0.3683143E-03 0.3683143E-03 0.0000000E+00 0.0000000E+00 7 Al+++ 0.4775352E-05 0.1967861E-05 0.2807491E-05 0.0000000E+00 8 H4SiO4 0.1215302E-01 0.1214459E-01 0.8427248E-05 0.0000000E+00 9 Ca++ 0.2080835E-06 0.2080835E-06 0.0000000E+00 0.0000000E+00 10 Mg++ 0.8368328E-10 0.8368328E-10 0.0000000E+00 0.0000000E+00 11 Fe++ 0.3259227E-07 0.2065091E-07 0.1194136E-07 0.0000000E+00 12 K+ 0.1412294E-03 0.1412282E-03 0.1194136E-08 0.0000000E+00 13 Na+ 0.2003215E-01 0.2002935E-01 0.2802714E-05 0.0000000E+00 14 Mn++ 0.2251939E-08 0.2251939E-08 0.0000000E+00 0.0000000E+00 15 F- 0.6816000E-05 0.6816000E-05 0.0000000E+00 0.0000000E+00 16 HPO4-- 0.4168819E-07 0.4168819E-07 0.0000000E+00 0.0000000E+00 Chg. balance for solid moles: 0.8470E-21 Mass of aqueous solution: 0.899963E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 0.0167900 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 0.2803E-05 -5.552 0.7349E-03 -3.134 99.65 0.2821E-03 stilpnomelane-Fe 0.2388E-08 -8.622 0.2575E-05 -5.589 0.3491 0.8893E-06 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 0.000738 g Volume = 0.000283 cm3 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.0167900 moles log = -1.7749 Original solution: 1000.0103000 g Original solution / Rock added: 59559.87 (Water/Rock Ratio), log = 4.7750 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0206 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9997E+00 0.9859 0.1006E+01 0.1020E+01 CO2,gas 0.1080E-04 1.0071 0.1110E-04 0.1102E-04 CH4,gas 0.6036E-05 1.0125 0.6238E-05 0.6161E-05 H2,gas 0.2682E-03 1.0005 0.2739E-03 0.2737E-03 H2S,gas 0.2912E-05 0.9960 0.2960E-05 0.2972E-05 S2,gas 0.4295E-23 1.0000 0.4383E-23 0.4383E-23 CO,gas 0.7940E-12 1.0000 0.8103E-12 0.8103E-12 SO3,gas 0.1437E-39 1.0000 0.1466E-39 0.1466E-39 SO2,gas 0.1531E-20 1.0000 0.1562E-20 0.1562E-20 HF,gas 0.1056E-13 1.0000 0.1078E-13 0.1078E-13 HCl,gas 0.7070E-17 1.0000 0.7215E-17 0.7215E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 17 albite -0.38 -0.38 0.00 0.000 -0.94784E-12 165 stilpnomelane-Fe 13.02 13.02 0.00 0.000 0.21232E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -13.31 -6.65 -2.218 0.11361E+05 -4.955 3 CH4,gas 4.54 -2.36 -6.90 -1.726 0.11788E+05 -5.205 4 H2,gas 8.00 2.74 -5.26 -3.007 0.89837E+04 -3.562 5 H2S,gas -6.23 -13.46 -7.23 -3.614 0.12341E+05 -5.529 6 S2,gas -7.34 -32.39 -25.06 -3.855 0.42784E+05 -23.358 7 CO,gas 3.21 -10.58 -13.79 -4.243 0.23547E+05 -12.091 8 SO3,gas 17.12 -24.41 -41.53 -10.383 0.70916E+05 -39.834 9 SO2,gas 0.83 -21.67 -22.51 -6.001 0.38427E+05 -20.806 10 HF,gas 0.47 -15.19 -15.67 -7.833 0.26750E+05 -13.967 11 HCl,gas 5.19 -13.65 -18.84 -9.420 0.32170E+05 -17.142 12 acmite 7.71 7.43 -0.28 -0.029 0.48355E+03 16 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 20 spessartine 24.46 19.55 -4.91 -0.246 0.83841E+04 21 analcite 3.32 2.64 -0.68 -0.075 0.11561E+04 25 annite 20.12 17.44 -2.68 -0.149 0.45845E+04 26 phlogopite 27.06 24.63 -2.44 -0.135 0.41629E+04 31 apatite-OH -18.15 -20.66 -2.51 -0.193 0.42882E+04 32 apatite-F -34.30 -35.86 -1.56 -0.130 0.26582E+04 36 aragonite 0.97 -0.88 -1.85 -0.615 0.31507E+04 37 brucite 12.57 9.04 -3.53 -0.706 0.60282E+04 38 calcite 0.81 -0.88 -1.69 -0.564 0.28865E+04 39 carnegieite-low 9.02 5.67 -3.35 -0.479 0.57198E+04 40 carnegieite-high 10.09 5.67 -4.42 -0.631 0.75468E+04 41 carpholite-Mg 8.58 3.96 -4.62 -0.308 0.78868E+04 43 celadonite 5.34 3.52 -1.82 -0.107 0.31074E+04 44 celadonite-Fe 3.88 1.13 -2.75 -0.162 0.46970E+04 45 chrysotile 23.89 21.06 -2.84 -0.236 0.48413E+04 47 clinochlore 39.07 37.09 -1.98 -0.062 0.33853E+04 48 daphnite 28.97 25.11 -3.86 -0.121 0.65884E+04 52 chloritoid-Fe 9.17 4.60 -4.58 -0.305 0.78166E+04 53 chloritoid-Mn 11.40 7.17 -4.23 -0.282 0.72235E+04 55 coesite -2.38 -3.03 -0.65 -0.218 0.11143E+04 62 cristobalite -2.56 -3.03 -0.47 -0.156 0.79963E+03 64 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71255E+04 66 diaspore 2.87 0.49 -2.38 -0.397 0.40681E+04 67 diamond -3.10 -7.84 -4.73 -1.353 0.80842E+04 68 diopside 16.18 15.42 -0.77 -0.077 0.13072E+04 69 hedenbergite 14.21 13.02 -1.19 -0.119 0.20294E+04 76 epidote 24.67 22.04 -2.63 -0.128 0.44919E+04 78 epidote-Fe 29.84 26.82 -3.02 -0.157 0.51563E+04 79 fayalite 14.05 10.26 -3.79 -0.541 0.64717E+04 80 ferrosilite 11.15 7.23 -3.92 -0.392 0.66978E+04 84 gibbsite 4.08 0.49 -3.59 -0.513 0.61267E+04 85 glaucophane 22.97 20.29 -2.69 -0.073 0.45855E+04 86 glaucophane-Fe 17.28 13.10 -4.17 -0.113 0.71281E+04 87 graphite -3.55 -7.84 -4.29 -1.226 0.73264E+04 88 greenalite 16.14 13.87 -2.27 -0.189 0.38770E+04 91 hematite 12.57 10.55 -2.02 -0.245 0.34498E+04 92 heulandite -5.83 -7.78 -1.96 -0.089 0.33398E+04 96 jadeite 4.22 2.64 -1.57 -0.157 0.26816E+04 97 julgoldite 70.43 65.94 -4.48 -0.116 0.76550E+04 98 kalsilite 7.58 3.57 -4.01 -0.573 0.68544E+04 99 kaolinite -1.33 -5.07 -3.74 -0.340 0.63898E+04 102 laumontite 2.88 1.30 -1.58 -0.105 0.26990E+04 103 lawsonite 9.62 7.36 -2.26 -0.150 0.38522E+04 104 leucite 4.12 0.54 -3.58 -0.358 0.61093E+04 106 lizardite 23.24 21.06 -2.19 -0.182 0.37340E+04 107 magnesite 0.69 -4.28 -4.97 -1.655 0.84797E+04 108 magnetite 20.09 17.19 -2.90 -0.237 0.49509E+04 109 minnesotaite 10.39 7.81 -2.58 -0.152 0.43993E+04 113 manganosite 14.06 9.22 -4.84 -1.210 0.82662E+04 117 microcline -2.49 -2.49 0.00 0.000 0.21402E+01 121 muscovite 2.58 -1.51 -4.09 -0.240 0.69799E+04 122 paragonite 4.24 0.60 -3.64 -0.214 0.62169E+04 123 nepheline 8.34 5.67 -2.67 -0.381 0.45522E+04 129 periclase-Fe 11.63 6.64 -4.98 -1.246 0.85109E+04 135 phlogopite-Na 29.65 26.73 -2.92 -0.162 0.49795E+04 137 prehnite 19.37 16.77 -2.61 -0.153 0.44489E+04 138 prehnite-Fe 22.50 21.55 -0.95 -0.057 0.16218E+04 143 pyrite -21.25 -23.01 -1.77 -0.415 0.30142E+04 144 pyrrhotite -4.26 -6.82 -2.56 -0.852 0.43636E+04 145 pyrrhotiteFe0.875 -6.02 -7.99 -1.97 -0.724 0.33616E+04 146 pyroxmangite 7.40 6.19 -1.21 -0.242 0.20667E+04 147 pyrophyllite -6.18 -11.13 -4.96 -0.310 0.84631E+04 148 quartz -2.99 -3.03 -0.04 -0.013 0.66958E+02 152 rhodochrosite -0.98 -4.10 -3.12 -1.040 0.53281E+04 153 rhodonite 7.45 6.19 -1.26 -0.251 0.21470E+04 154 sanidine -1.28 -2.49 -1.21 -0.093 0.20699E+04 156 siderite -2.61 -6.67 -4.06 -1.355 0.69383E+04 164 stilbite -7.52 -7.78 -0.26 -0.012 0.44601E+03 166 stilpnomelane-Mg 27.44 25.00 -2.44 -0.073 0.41735E+04 172 talc 16.49 15.00 -1.49 -0.088 0.25465E+04 175 tephroite 18.09 15.41 -2.68 -0.383 0.45770E+04 179 tridymite -2.63 -3.03 -0.40 -0.134 0.68694E+03 180 tremolite 47.87 45.83 -2.04 -0.055 0.34798E+04 181 ferroactinolite 38.45 33.85 -4.60 -0.124 0.78565E+04 182 troilite-low -4.41 -6.82 -2.40 -0.802 0.41064E+04 188 wairakite 3.95 1.30 -2.65 -0.156 0.45210E+04 189 walstromite 11.51 9.41 -2.10 -0.421 0.35906E+04 190 wollastonite 10.46 9.41 -1.05 -0.211 0.18011E+04 191 pseudo-wollastonite 11.00 9.41 -1.59 -0.319 0.27209E+04 193 akaganeite 7.75 5.27 -2.48 -0.537 0.42374E+04 200 chalcedony -2.80 -3.03 -0.23 -0.075 0.38626E+03 202 montmorillonite-Ca -2.29 -6.26 -3.97 -0.246 0.67775E+04 203 montmorillonite-K -2.24 -6.30 -4.06 -0.249 0.69319E+04 204 montmorillonite-Mg -2.48 -6.82 -4.34 -0.269 0.74115E+04 205 montmorillonite-Na -2.04 -5.60 -3.56 -0.218 0.60861E+04 206 nontronite-Ca 3.21 1.64 -1.57 -0.102 0.26808E+04 207 nontronite-H 2.53 -0.41 -2.94 -0.197 0.50200E+04 208 nontronite-K 3.34 1.61 -1.73 -0.111 0.29585E+04 209 nontronite-Mg 3.07 1.08 -1.99 -0.129 0.33989E+04 210 nontronite-Na 3.52 2.30 -1.22 -0.078 0.20787E+04 226 tobermorite 9.82 7.33 -2.49 -0.680 0.42573E+04 232 alabandite -0.98 -4.24 -3.26 -1.088 0.55718E+04 235 boehmite 4.41 0.49 -3.92 -0.653 0.66851E+04 237 ferrous-oxide 9.81 6.64 -3.17 -0.792 0.54119E+04 243 silica-amorphous -2.09 -3.03 -0.94 -0.312 0.16004E+04 245 an20ab80 2.02 1.16 -0.85 -0.066 0.14563E+04 246 an25ab75 2.65 1.55 -1.09 -0.084 0.18673E+04 247 an30ab70 3.28 1.94 -1.34 -0.103 0.22879E+04 248 tr.625ac.25prg.125 45.16 43.67 -1.49 -0.040 0.25451E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 0.0004000 MOLES Current total amount of reactant added: 0.0167900 MOLES New total amount of reactant added: 0.0171900 MOLES Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.5508E-08 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 7 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 0.0171900 Water: Moles liquid = 0.4987E+02 kg liquid = 0.8983E+00 Moles total = 0.4986E+02 kg total = 0.8983E+00 Activity = 1.0000 Stoichiometric ionic strength = .1243281E-01 Osmotic coef. = 0.9413 True ionic strength = .2097141E-01 Chg. balance for total moles = -.5508E-08 Max. difference allowed = 0.2393E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.12284E-09 -9.9106 0.10292E-09 -9.9875 0.83784E+00 -0.0768 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.26517E-03 -3.5765 0.22078E-03 -3.6560 0.83262E+00 -0.0796 4 SO4-- 0.74652E-04 -4.1270 0.38298E-04 -4.4168 0.51302E+00 -0.2899 5 HCO3- 0.58669E-03 -3.2316 0.48923E-03 -3.3105 0.83388E+00 -0.0789 6 HS- 0.41852E-03 -3.3783 0.34852E-03 -3.4578 0.83274E+00 -0.0795 7 Al+++ 0.14818E-28 -28.8292 0.33290E-29 -29.4777 0.22466E+00 -0.6485 8 H4SiO4 0.94337E-03 -3.0253 0.94337E-03 -3.0253 0.10000E+01 0.0000 9 Ca++ 0.55072E-07 -7.2591 0.28038E-07 -7.5523 0.50911E+00 -0.2932 10 Mg++ 0.22480E-10 -10.6482 0.11390E-10 -10.9435 0.50669E+00 -0.2953 11 Fe++ 0.91086E-13 -13.0405 0.46205E-13 -13.3353 0.50727E+00 -0.2948 12 K+ 0.15657E-03 -3.8053 0.13060E-03 -3.8841 0.83408E+00 -0.0788 13 Na+ 0.19929E-01 -1.7005 0.16590E-01 -1.7802 0.83246E+00 -0.0796 14 Mn++ 0.34323E-10 -10.4644 0.17426E-10 -10.7588 0.50771E+00 -0.2944 15 F- 0.77404E-05 -5.1112 0.64310E-05 -5.1917 0.83084E+00 -0.0805 16 HPO4-- 0.45568E-07 -7.3413 0.23381E-07 -7.6311 0.51309E+00 -0.2898 18 HSiO3- 0.10279E-01 -1.9881 0.85584E-02 -2.0676 0.83262E+00 -0.0796 19 Ca(HSiO3)+ 0.65503E-08 -8.1837 0.54647E-08 -8.2624 0.83427E+00 -0.0787 20 Mg(HSiO3)+ 0.33118E-11 -11.4799 0.27629E-11 -11.5586 0.83427E+00 -0.0787 21 NaHSiO3,aq 0.22964E-02 -2.6390 0.22964E-02 -2.6390 0.10000E+01 0.0000 22 AlO+ 0.51244E-16 -16.2904 0.42751E-16 -16.3690 0.83427E+00 -0.0787 24 HAlO2,aq 0.82720E-10 -10.0824 0.82720E-10 -10.0824 0.10000E+01 0.0000 25 AlO2- 0.21407E-05 -5.6694 0.17790E-05 -5.7498 0.83106E+00 -0.0804 26 CH4,aq 0.43410E-08 -8.3624 0.43246E-08 -8.3641 0.99621E+00 -0.0016 27 C2H6,aq 0.15446E-19 -19.8112 0.15387E-19 -19.8128 0.99621E+00 -0.0016 31 CO,aq 0.56161E-15 -15.2506 0.56161E-15 -15.2506 0.10000E+01 0.0000 32 CO2,aq 0.10800E-06 -6.9666 0.10759E-06 -6.9682 0.99621E+00 -0.0016 33 CO3-2 0.81107E-03 -3.0909 0.41518E-03 -3.3818 0.51189E+00 -0.2908 34 CaCO3,aq 0.14596E-06 -6.8358 0.14596E-06 -6.8358 0.10000E+01 0.0000 35 Ca(HCO3)+ 0.41969E-09 -9.3771 0.35013E-09 -9.4558 0.83427E+00 -0.0787 36 CaCl+ 0.12008E-10 -10.9205 0.10018E-10 -10.9992 0.83427E+00 -0.0787 37 CaCl2,aq 0.52547E-15 -15.2795 0.52547E-15 -15.2795 0.10000E+01 0.0000 38 CaF+ 0.31555E-11 -11.5009 0.26325E-11 -11.5796 0.83427E+00 -0.0787 39 CaOH+ 0.23271E-07 -7.6332 0.19414E-07 -7.7119 0.83427E+00 -0.0787 40 CaSO4,aq 0.34098E-09 -9.4673 0.34098E-09 -9.4673 0.10000E+01 0.0000 41 HCl,aq 0.41641E-14 -14.3805 0.41641E-14 -14.3805 0.10000E+01 0.0000 45 HF,aq 0.45312E-11 -11.3438 0.45312E-11 -11.3438 0.10000E+01 0.0000 46 HF2- 0.11816E-16 -16.9275 0.98385E-17 -17.0071 0.83262E+00 -0.0796 48 FeCl+ 0.19355E-16 -16.7132 0.16147E-16 -16.7919 0.83427E+00 -0.0787 51 FeF+ 0.18201E-16 -16.7399 0.15185E-16 -16.8186 0.83427E+00 -0.0787 53 FeO,aq 0.16952E-09 -9.7708 0.16952E-09 -9.7708 0.10000E+01 0.0000 54 FeOH+ 0.17516E-10 -10.7566 0.14613E-10 -10.8353 0.83427E+00 -0.0787 55 HFeO2- 0.20698E-07 -7.6841 0.17233E-07 -7.7636 0.83262E+00 -0.0796 56 FeO+ 0.91654E-16 -16.0378 0.76464E-16 -16.1165 0.83427E+00 -0.0787 58 FeO2- 0.17739E-08 -8.7511 0.14770E-08 -8.8306 0.83262E+00 -0.0796 59 HFeO2,aq 0.19334E-10 -10.7137 0.19334E-10 -10.7137 0.10000E+01 0.0000 60 H2,aq 0.20858E-06 -6.6807 0.20779E-06 -6.6824 0.99621E+00 -0.0016 61 KCl,aq 0.52258E-09 -9.2818 0.52258E-09 -9.2818 0.10000E+01 0.0000 62 KHSO4,aq 0.14555E-17 -17.8370 0.14555E-17 -17.8370 0.10000E+01 0.0000 63 KOH,aq 0.54187E-06 -6.2661 0.54187E-06 -6.2661 0.10000E+01 0.0000 64 KSO4- 0.93214E-07 -7.0305 0.77612E-07 -7.1101 0.83262E+00 -0.0796 65 MgCO3,aq 0.14863E-10 -10.8279 0.14863E-10 -10.8279 0.10000E+01 0.0000 66 Mg(HCO3)+ 0.17422E-12 -12.7589 0.14535E-12 -12.8376 0.83427E+00 -0.0787 67 MgCl+ 0.44214E-14 -14.3544 0.36886E-14 -14.4331 0.83427E+00 -0.0787 68 MgF+ 0.47487E-14 -14.3234 0.39617E-14 -14.4021 0.83427E+00 -0.0787 69 MgOH+ 0.52314E-10 -10.2814 0.43644E-10 -10.3601 0.83427E+00 -0.0787 71 MnF+ 0.22626E-14 -14.6454 0.18876E-14 -14.7241 0.83427E+00 -0.0787 72 MnO,aq 0.17036E-08 -8.7686 0.17036E-08 -8.7686 0.10000E+01 0.0000 73 MnOH+ 0.61368E-09 -9.2121 0.51198E-09 -9.2908 0.83427E+00 -0.0787 74 MnO2-2 0.10426E-10 -10.9819 0.53370E-11 -11.2727 0.51189E+00 -0.2908 75 HMnO2- 0.14454E-09 -9.8400 0.12034E-09 -9.9196 0.83262E+00 -0.0796 78 MnCl+ 0.28399E-13 -13.5467 0.23692E-13 -13.6254 0.83427E+00 -0.0787 79 MnSO4,aq 0.19267E-12 -12.7152 0.19267E-12 -12.7152 0.10000E+01 0.0000 80 NaCl,aq 0.12139E-05 -5.9158 0.12139E-05 -5.9158 0.10000E+01 0.0000 81 NaF,aq 0.24978E-07 -7.6024 0.24978E-07 -7.6024 0.10000E+01 0.0000 82 NaOH,aq 0.69253E-04 -4.1596 0.69253E-04 -4.1596 0.10000E+01 0.0000 84 OH- 0.67548E-02 -2.1704 0.56136E-02 -2.2508 0.83106E+00 -0.0804 89 HPO3-2 0.29576E-16 -16.5291 0.15140E-16 -16.8199 0.51189E+00 -0.2908 92 H3PO4,aq 0.17323E-17 -17.7614 0.17323E-17 -17.7614 0.10000E+01 0.0000 93 H2PO4- 0.53264E-10 -10.2736 0.44392E-10 -10.3527 0.83343E+00 -0.0791 94 PO4-3 0.78405E-09 -9.1057 0.18534E-09 -9.7320 0.23639E+00 -0.6264 98 HP2O7-3 0.13330E-17 -17.8752 0.29978E-18 -18.5232 0.22490E+00 -0.6480 99 P2O7-4 0.94737E-17 -17.0235 0.69581E-18 -18.1575 0.73446E-01 -1.1340 100 H2S,aq 0.11128E-06 -6.9536 0.11086E-06 -6.9552 0.99621E+00 -0.0016 101 S2-2 0.25304E-10 -10.5968 0.12953E-10 -10.8876 0.51189E+00 -0.2908 102 S3-2 0.18189E-16 -16.7402 0.93108E-17 -17.0310 0.51189E+00 -0.2908 107 SO3-2 0.19903E-11 -11.7011 0.10341E-11 -11.9854 0.51957E+00 -0.2844 108 HSO3- 0.80039E-14 -14.0967 0.66641E-14 -14.1763 0.83262E+00 -0.0796 109 HSO4- 0.45488E-11 -11.3421 0.37988E-11 -11.4204 0.83511E+00 -0.0783 111 S2O3-2 0.97433E-13 -13.0113 0.49875E-13 -13.3021 0.51189E+00 -0.2908 Charge balance for all species = -.6131E-08 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.1228449E-09 -.2021956E-01 -.2034333E+02 0.0000 2 H2O 0.1000000E+01 0.5550250E+02 0.9980898E+06 0.0000 3 Cl- 0.2651696E-03 0.2663840E-03 0.9427068E+01 6.3315 4 SO4-- 0.7465233E-04 0.7468963E-04 0.7161858E+01 15.5581 5 HCO3- 0.5866882E-03 0.1398020E-02 0.8514934E+02 6.6770 6 HS- 0.4185174E-03 0.4186850E-03 0.1382176E+02 6.5297 7 Al+++ 0.1481780E-28 0.2140788E-05 0.5765742E-01 0.4848 8 H4SiO4 0.9433719E-03 0.1351868E-01 0.1297008E+04 -3.0253 9 Ca++ 0.5507170E-07 0.2316294E-06 0.9266489E-02 12.4227 10 Mg++ 0.2247986E-10 0.9315254E-10 0.2260637E-05 9.0315 11 Fe++ 0.9108623E-13 0.2267801E-07 0.1264213E-02 6.6397 12 K+ 0.1565734E-03 0.1572090E-03 0.6136092E+01 6.1034 13 Na+ 0.1992887E-01 0.2229574E-01 0.5116495E+03 8.2073 14 Mn++ 0.3432332E-10 0.2506759E-08 0.1374678E-03 9.2162 15 F- 0.7740390E-05 0.7765376E-05 0.1472604E+00 4.7958 16 HPO4-- 0.4556814E-07 0.4640546E-07 0.4445911E-02 12.3438 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.1817561E-01 -.1816418E-01 -.1142950E-04 0.0000000E+00 2 H2O 0.4986048E+02 0.4986049E+02 -.1139284E-04 0.0000000E+00 3 Cl- 0.2393052E-03 0.2393052E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.6709719E-04 0.6709719E-04 0.0000000E+00 0.0000000E+00 5 HCO3- 0.1255907E-02 0.1255907E-02 0.0000000E+00 0.0000000E+00 6 HS- 0.3761243E-03 0.3761243E-03 0.0000000E+00 0.0000000E+00 7 Al+++ 0.4775352E-05 0.1923170E-05 0.2852182E-05 0.0000000E+00 8 H4SiO4 0.1215302E-01 0.1214446E-01 0.8561435E-05 0.0000000E+00 9 Ca++ 0.2080835E-06 0.2080835E-06 0.0000000E+00 0.0000000E+00 10 Mg++ 0.8368328E-10 0.8368328E-10 0.0000000E+00 0.0000000E+00 11 Fe++ 0.3259227E-07 0.2037271E-07 0.1221956E-07 0.0000000E+00 12 K+ 0.1412294E-03 0.1412282E-03 0.1221956E-08 0.0000000E+00 13 Na+ 0.2003215E-01 0.2002930E-01 0.2847295E-05 0.0000000E+00 14 Mn++ 0.2251939E-08 0.2251939E-08 0.0000000E+00 0.0000000E+00 15 F- 0.6976000E-05 0.6976000E-05 0.0000000E+00 0.0000000E+00 16 HPO4-- 0.4168819E-07 0.4168819E-07 0.0000000E+00 0.0000000E+00 Chg. balance for solid moles: 0.0000E+00 Mass of aqueous solution: 0.899971E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 0.0171900 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 0.2847E-05 -5.546 0.7466E-03 -3.127 99.65 0.2866E-03 stilpnomelane-Fe 0.2444E-08 -8.612 0.2635E-05 -5.579 0.3516 0.9100E-06 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 0.000749 g Volume = 0.000288 cm3 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.0171900 moles log = -1.7647 Original solution: 1000.0103000 g Original solution / Rock added: 58173.96 (Water/Rock Ratio), log = 4.7647 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0206 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9997E+00 0.9859 0.1006E+01 0.1020E+01 CO2,gas 0.1120E-04 1.0071 0.1151E-04 0.1143E-04 CH4,gas 0.6160E-05 1.0125 0.6366E-05 0.6287E-05 H2,gas 0.2671E-03 1.0005 0.2728E-03 0.2727E-03 H2S,gas 0.2998E-05 0.9960 0.3048E-05 0.3060E-05 S2,gas 0.4590E-23 1.0000 0.4685E-23 0.4685E-23 CO,gas 0.8200E-12 1.0000 0.8369E-12 0.8369E-12 SO3,gas 0.1503E-39 1.0000 0.1534E-39 0.1534E-39 SO2,gas 0.1595E-20 1.0000 0.1628E-20 0.1628E-20 HF,gas 0.1090E-13 1.0000 0.1113E-13 0.1113E-13 HCl,gas 0.7199E-17 1.0000 0.7348E-17 0.7348E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 17 albite -0.38 -0.38 0.00 0.000 -0.94784E-12 165 stilpnomelane-Fe 13.02 13.02 0.00 0.000 -0.27298E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -13.30 -6.64 -2.213 0.11334E+05 -4.939 3 CH4,gas 4.54 -2.35 -6.90 -1.724 0.11773E+05 -5.196 4 H2,gas 8.00 2.74 -5.26 -3.008 0.89866E+04 -3.564 5 H2S,gas -6.23 -13.45 -7.22 -3.608 0.12319E+05 -5.516 6 S2,gas -7.34 -32.36 -25.03 -3.851 0.42735E+05 -23.329 7 CO,gas 3.21 -10.56 -13.78 -4.239 0.23523E+05 -12.077 8 SO3,gas 17.12 -24.39 -41.51 -10.378 0.70883E+05 -39.814 9 SO2,gas 0.83 -21.66 -22.49 -5.997 0.38396E+05 -20.788 10 HF,gas 0.47 -15.18 -15.65 -7.826 0.26726E+05 -13.954 11 HCl,gas 5.19 -13.64 -18.83 -9.416 0.32157E+05 -17.134 12 acmite 7.71 7.43 -0.28 -0.029 0.48096E+03 16 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 20 spessartine 24.46 19.54 -4.92 -0.246 0.83927E+04 21 analcite 3.32 2.64 -0.68 -0.076 0.11618E+04 25 annite 20.12 17.43 -2.69 -0.150 0.45969E+04 26 phlogopite 27.06 24.61 -2.46 -0.137 0.41967E+04 31 apatite-OH -18.15 -20.70 -2.55 -0.196 0.43563E+04 32 apatite-F -34.30 -35.88 -1.58 -0.132 0.27030E+04 36 aragonite 0.97 -0.88 -1.84 -0.614 0.31448E+04 37 brucite 12.57 9.03 -3.54 -0.707 0.60394E+04 38 calcite 0.81 -0.88 -1.69 -0.562 0.28806E+04 39 carnegieite-low 9.02 5.67 -3.36 -0.480 0.57312E+04 40 carnegieite-high 10.09 5.67 -4.43 -0.632 0.75582E+04 41 carpholite-Mg 8.58 3.95 -4.63 -0.309 0.79085E+04 43 celadonite 5.34 3.52 -1.82 -0.107 0.31131E+04 44 celadonite-Fe 3.88 1.13 -2.75 -0.162 0.46955E+04 45 chrysotile 23.89 21.04 -2.85 -0.237 0.48638E+04 47 clinochlore 39.07 37.05 -2.02 -0.063 0.34464E+04 48 daphnite 28.97 25.09 -3.87 -0.121 0.66137E+04 52 chloritoid-Fe 9.17 4.58 -4.59 -0.306 0.78369E+04 53 chloritoid-Mn 11.40 7.16 -4.24 -0.283 0.72409E+04 55 coesite -2.38 -3.03 -0.65 -0.216 0.11086E+04 62 cristobalite -2.56 -3.03 -0.46 -0.155 0.79394E+03 64 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71256E+04 66 diaspore 2.87 0.48 -2.39 -0.398 0.40790E+04 67 diamond -3.10 -7.82 -4.72 -1.349 0.80632E+04 68 diopside 16.18 15.40 -0.78 -0.078 0.13280E+04 69 hedenbergite 14.21 13.01 -1.20 -0.120 0.20431E+04 76 epidote 24.67 22.01 -2.66 -0.129 0.45412E+04 78 epidote-Fe 29.84 26.80 -3.04 -0.158 0.51974E+04 79 fayalite 14.05 10.25 -3.79 -0.542 0.64743E+04 80 ferrosilite 11.15 7.23 -3.92 -0.392 0.66946E+04 84 gibbsite 4.08 0.48 -3.59 -0.514 0.61376E+04 85 glaucophane 22.97 20.28 -2.70 -0.073 0.46079E+04 86 glaucophane-Fe 17.28 13.10 -4.18 -0.113 0.71291E+04 87 graphite -3.55 -7.82 -4.28 -1.222 0.73055E+04 88 greenalite 16.14 13.87 -2.27 -0.189 0.38780E+04 91 hematite 12.57 10.54 -2.02 -0.245 0.34551E+04 92 heulandite -5.83 -7.79 -1.96 -0.089 0.33428E+04 96 jadeite 4.22 2.64 -1.57 -0.157 0.26873E+04 97 julgoldite 70.43 65.90 -4.52 -0.117 0.77234E+04 98 kalsilite 7.58 3.56 -4.02 -0.574 0.68658E+04 99 kaolinite -1.33 -5.08 -3.75 -0.341 0.64002E+04 102 laumontite 2.88 1.29 -1.59 -0.106 0.27191E+04 103 lawsonite 9.62 7.34 -2.27 -0.152 0.38836E+04 104 leucite 4.12 0.54 -3.58 -0.358 0.61150E+04 106 lizardite 23.24 21.04 -2.20 -0.183 0.37564E+04 107 magnesite 0.69 -4.27 -4.96 -1.652 0.84641E+04 108 magnetite 20.09 17.18 -2.91 -0.237 0.49603E+04 109 minnesotaite 10.39 7.82 -2.57 -0.151 0.43889E+04 113 manganosite 14.06 9.22 -4.84 -1.210 0.82675E+04 117 microcline -2.49 -2.49 0.00 0.000 0.22020E+01 121 muscovite 2.58 -1.52 -4.10 -0.241 0.70018E+04 122 paragonite 4.24 0.59 -3.65 -0.215 0.62387E+04 123 nepheline 8.34 5.67 -2.67 -0.382 0.45635E+04 129 periclase-Fe 11.63 6.64 -4.99 -1.247 0.85150E+04 135 phlogopite-Na 29.65 26.71 -2.94 -0.163 0.50133E+04 137 prehnite 19.37 16.74 -2.63 -0.155 0.44956E+04 138 prehnite-Fe 22.50 21.53 -0.97 -0.058 0.16602E+04 143 pyrite -21.25 -22.99 -1.74 -0.410 0.29720E+04 144 pyrrhotite -4.26 -6.81 -2.55 -0.848 0.43460E+04 145 pyrrhotiteFe0.875 -6.02 -7.97 -1.96 -0.720 0.33432E+04 146 pyroxmangite 7.40 6.19 -1.21 -0.242 0.20623E+04 147 pyrophyllite -6.18 -11.13 -4.96 -0.310 0.84622E+04 148 quartz -2.99 -3.03 -0.04 -0.012 0.61268E+02 152 rhodochrosite -0.98 -4.08 -3.11 -1.035 0.53025E+04 153 rhodonite 7.45 6.19 -1.25 -0.251 0.21426E+04 154 sanidine -1.28 -2.49 -1.21 -0.093 0.20700E+04 156 siderite -2.61 -6.66 -4.05 -1.350 0.69156E+04 164 stilbite -7.52 -7.79 -0.26 -0.013 0.44898E+03 166 stilpnomelane-Mg 27.44 24.98 -2.47 -0.074 0.42093E+04 172 talc 16.49 14.99 -1.50 -0.088 0.25575E+04 175 tephroite 18.09 15.41 -2.68 -0.383 0.45739E+04 179 tridymite -2.63 -3.03 -0.40 -0.133 0.68125E+03 180 tremolite 47.87 45.80 -2.07 -0.056 0.35325E+04 181 ferroactinolite 38.45 33.84 -4.61 -0.125 0.78735E+04 182 troilite-low -4.41 -6.81 -2.39 -0.798 0.40888E+04 188 wairakite 3.95 1.29 -2.66 -0.156 0.45410E+04 189 walstromite 11.51 9.40 -2.11 -0.422 0.36059E+04 190 wollastonite 10.46 9.40 -1.06 -0.213 0.18163E+04 191 pseudo-wollastonite 11.00 9.40 -1.60 -0.320 0.27362E+04 193 akaganeite 7.75 5.27 -2.48 -0.537 0.42401E+04 200 chalcedony -2.80 -3.03 -0.22 -0.074 0.38057E+03 202 montmorillonite-Ca -2.29 -6.26 -3.97 -0.246 0.67801E+04 203 montmorillonite-K -2.24 -6.30 -4.06 -0.249 0.69332E+04 204 montmorillonite-Mg -2.48 -6.82 -4.34 -0.269 0.74126E+04 205 montmorillonite-Na -2.04 -5.60 -3.57 -0.218 0.60873E+04 206 nontronite-Ca 3.21 1.65 -1.57 -0.102 0.26723E+04 207 nontronite-H 2.53 -0.40 -2.93 -0.197 0.50079E+04 208 nontronite-K 3.34 1.61 -1.73 -0.111 0.29485E+04 209 nontronite-Mg 3.07 1.09 -1.98 -0.129 0.33888E+04 210 nontronite-Na 3.52 2.31 -1.21 -0.078 0.20687E+04 226 tobermorite 9.82 7.32 -2.50 -0.682 0.42691E+04 232 alabandite -0.98 -4.23 -3.25 -1.084 0.55514E+04 235 boehmite 4.41 0.48 -3.92 -0.654 0.66960E+04 237 ferrous-oxide 9.81 6.64 -3.17 -0.793 0.54160E+04 243 silica-amorphous -2.09 -3.03 -0.93 -0.311 0.15947E+04 245 an20ab80 2.02 1.16 -0.86 -0.066 0.14625E+04 246 an25ab75 2.65 1.55 -1.10 -0.084 0.18752E+04 247 an30ab70 3.28 1.93 -1.35 -0.103 0.22974E+04 248 tr.625ac.25prg.125 45.16 43.65 -1.52 -0.041 0.25938E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 0.0004000 MOLES Current total amount of reactant added: 0.0171900 MOLES New total amount of reactant added: 0.0175900 MOLES Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.5508E-08 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 7 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 0.0175900 Water: Moles liquid = 0.4987E+02 kg liquid = 0.8984E+00 Moles total = 0.4986E+02 kg total = 0.8983E+00 Activity = 1.0000 Stoichiometric ionic strength = .1245858E-01 Osmotic coef. = 0.9410 True ionic strength = .2099115E-01 Chg. balance for total moles = -.5508E-08 Max. difference allowed = 0.2417E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.12388E-09 -9.9070 0.10379E-09 -9.9839 0.83779E+00 -0.0769 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.26778E-03 -3.5722 0.22295E-03 -3.6518 0.83256E+00 -0.0796 4 SO4-- 0.76775E-04 -4.1148 0.39377E-04 -4.4048 0.51289E+00 -0.2900 5 HCO3- 0.60304E-03 -3.2197 0.50283E-03 -3.2986 0.83383E+00 -0.0789 6 HS- 0.42720E-03 -3.3694 0.35573E-03 -3.4489 0.83269E+00 -0.0795 7 Al+++ 0.14980E-28 -28.8245 0.33634E-29 -29.4732 0.22453E+00 -0.6487 8 H4SiO4 0.95067E-03 -3.0220 0.95067E-03 -3.0220 0.10000E+01 0.0000 9 Ca++ 0.54462E-07 -7.2639 0.27720E-07 -7.5572 0.50898E+00 -0.2933 10 Mg++ 0.22519E-10 -10.6475 0.11407E-10 -10.9428 0.50656E+00 -0.2954 11 Fe++ 0.92131E-13 -13.0356 0.46723E-13 -13.3305 0.50714E+00 -0.2949 12 K+ 0.15657E-03 -3.8053 0.13059E-03 -3.8841 0.83403E+00 -0.0788 13 Na+ 0.19931E-01 -1.7005 0.16590E-01 -1.7801 0.83240E+00 -0.0797 14 Mn++ 0.34849E-10 -10.4578 0.17689E-10 -10.7523 0.50758E+00 -0.2945 15 F- 0.79179E-05 -5.1014 0.65780E-05 -5.1819 0.83078E+00 -0.0805 16 HPO4-- 0.45574E-07 -7.3413 0.23378E-07 -7.6312 0.51297E+00 -0.2899 18 HSiO3- 0.10273E-01 -1.9883 0.85528E-02 -2.0679 0.83256E+00 -0.0796 19 Ca(HSiO3)+ 0.64723E-08 -8.1889 0.53993E-08 -8.2677 0.83422E+00 -0.0787 20 Mg(HSiO3)+ 0.33147E-11 -11.4796 0.27651E-11 -11.5583 0.83422E+00 -0.0787 21 NaHSiO3,aq 0.22949E-02 -2.6392 0.22949E-02 -2.6392 0.10000E+01 0.0000 22 AlO+ 0.50920E-16 -16.2931 0.42478E-16 -16.3718 0.83422E+00 -0.0787 24 HAlO2,aq 0.81507E-10 -10.0888 0.81507E-10 -10.0888 0.10000E+01 0.0000 25 AlO2- 0.20919E-05 -5.6795 0.17384E-05 -5.7599 0.83100E+00 -0.0804 26 CH4,aq 0.44293E-08 -8.3537 0.44125E-08 -8.3553 0.99621E+00 -0.0017 27 C2H6,aq 0.16143E-19 -19.7920 0.16082E-19 -19.7937 0.99621E+00 -0.0017 31 CO,aq 0.57980E-15 -15.2367 0.57980E-15 -15.2367 0.10000E+01 0.0000 32 CO2,aq 0.11194E-06 -6.9510 0.11151E-06 -6.9527 0.99621E+00 -0.0017 33 CO3-2 0.82690E-03 -3.0825 0.42317E-03 -3.3735 0.51176E+00 -0.2909 34 CaCO3,aq 0.14709E-06 -6.8324 0.14709E-06 -6.8324 0.10000E+01 0.0000 35 Ca(HCO3)+ 0.42650E-09 -9.3701 0.35580E-09 -9.4488 0.83422E+00 -0.0787 36 CaCl+ 0.11989E-10 -10.9212 0.10001E-10 -10.9999 0.83422E+00 -0.0787 37 CaCl2,aq 0.52974E-15 -15.2759 0.52974E-15 -15.2759 0.10000E+01 0.0000 38 CaF+ 0.31913E-11 -11.4960 0.26622E-11 -11.5748 0.83422E+00 -0.0787 39 CaOH+ 0.22818E-07 -7.6417 0.19035E-07 -7.7204 0.83422E+00 -0.0787 40 CaSO4,aq 0.34662E-09 -9.4602 0.34662E-09 -9.4602 0.10000E+01 0.0000 41 HCl,aq 0.42401E-14 -14.3726 0.42401E-14 -14.3726 0.10000E+01 0.0000 45 HF,aq 0.46737E-11 -11.3303 0.46737E-11 -11.3303 0.10000E+01 0.0000 46 HF2- 0.12467E-16 -16.9042 0.10380E-16 -16.9838 0.83256E+00 -0.0796 48 FeCl+ 0.19765E-16 -16.7041 0.16488E-16 -16.7828 0.83422E+00 -0.0787 51 FeF+ 0.18827E-16 -16.7252 0.15706E-16 -16.8039 0.83422E+00 -0.0787 53 FeO,aq 0.16858E-09 -9.7732 0.16858E-09 -9.7732 0.10000E+01 0.0000 54 FeOH+ 0.17566E-10 -10.7553 0.14654E-10 -10.8341 0.83422E+00 -0.0787 55 HFeO2- 0.20413E-07 -7.6901 0.16995E-07 -7.7697 0.83256E+00 -0.0796 56 FeO+ 0.92095E-16 -16.0358 0.76828E-16 -16.1145 0.83422E+00 -0.0787 58 FeO2- 0.17529E-08 -8.7562 0.14594E-08 -8.8358 0.83256E+00 -0.0796 59 HFeO2,aq 0.19264E-10 -10.7152 0.19264E-10 -10.7152 0.10000E+01 0.0000 60 H2,aq 0.20776E-06 -6.6824 0.20697E-06 -6.6841 0.99621E+00 -0.0017 61 KCl,aq 0.52767E-09 -9.2776 0.52767E-09 -9.2776 0.10000E+01 0.0000 62 KHSO4,aq 0.15090E-17 -17.8213 0.15090E-17 -17.8213 0.10000E+01 0.0000 63 KOH,aq 0.53733E-06 -6.2698 0.53733E-06 -6.2698 0.10000E+01 0.0000 64 KSO4- 0.95842E-07 -7.0184 0.79794E-07 -7.0980 0.83256E+00 -0.0796 65 MgCO3,aq 0.15172E-10 -10.8190 0.15172E-10 -10.8190 0.10000E+01 0.0000 66 Mg(HCO3)+ 0.17934E-12 -12.7463 0.14961E-12 -12.8250 0.83422E+00 -0.0787 67 MgCl+ 0.44715E-14 -14.3495 0.37302E-14 -14.4283 0.83422E+00 -0.0787 68 MgF+ 0.48647E-14 -14.3129 0.40582E-14 -14.3917 0.83422E+00 -0.0787 69 MgOH+ 0.51958E-10 -10.2843 0.43344E-10 -10.3631 0.83422E+00 -0.0787 71 MnF+ 0.23493E-14 -14.6291 0.19599E-14 -14.7078 0.83422E+00 -0.0787 72 MnO,aq 0.17006E-08 -8.7694 0.17006E-08 -8.7694 0.10000E+01 0.0000 73 MnOH+ 0.61778E-09 -9.2092 0.51536E-09 -9.2879 0.83422E+00 -0.0787 74 MnO2-2 0.10238E-10 -10.9898 0.52392E-11 -11.2807 0.51176E+00 -0.2909 75 HMnO2- 0.14309E-09 -9.8444 0.11913E-09 -9.9240 0.83256E+00 -0.0796 78 MnCl+ 0.29110E-13 -13.5360 0.24284E-13 -13.6147 0.83422E+00 -0.0787 79 MnSO4,aq 0.20108E-12 -12.6966 0.20108E-12 -12.6966 0.10000E+01 0.0000 80 NaCl,aq 0.12258E-05 -5.9116 0.12258E-05 -5.9116 0.10000E+01 0.0000 81 NaF,aq 0.25550E-07 -7.5926 0.25550E-07 -7.5926 0.10000E+01 0.0000 82 NaOH,aq 0.68679E-04 -4.1632 0.68679E-04 -4.1632 0.10000E+01 0.0000 84 OH- 0.66990E-02 -2.1740 0.55669E-02 -2.2544 0.83100E+00 -0.0804 89 HPO3-2 0.29464E-16 -16.5307 0.15079E-16 -16.8216 0.51176E+00 -0.2909 92 H3PO4,aq 0.17612E-17 -17.7542 0.17612E-17 -17.7542 0.10000E+01 0.0000 93 H2PO4- 0.53708E-10 -10.2700 0.44759E-10 -10.3491 0.83338E+00 -0.0792 94 PO4-3 0.77784E-09 -9.1091 0.18378E-09 -9.7357 0.23626E+00 -0.6266 98 HP2O7-3 0.13446E-17 -17.8714 0.30221E-18 -18.5197 0.22477E+00 -0.6483 99 P2O7-4 0.94807E-17 -17.0232 0.69563E-18 -18.1576 0.73373E-01 -1.1345 100 H2S,aq 0.11454E-06 -6.9410 0.11411E-06 -6.9427 0.99621E+00 -0.0017 101 S2-2 0.26472E-10 -10.5772 0.13547E-10 -10.8681 0.51176E+00 -0.2909 102 S3-2 0.19662E-16 -16.7064 0.10062E-16 -16.9973 0.51176E+00 -0.2909 107 SO3-2 0.20389E-11 -11.6906 0.10591E-11 -11.9751 0.51944E+00 -0.2845 108 HSO3- 0.82666E-14 -14.0827 0.68824E-14 -14.1623 0.83256E+00 -0.0796 109 HSO4- 0.47165E-11 -11.3264 0.39386E-11 -11.4047 0.83506E+00 -0.0783 111 S2O3-2 0.10314E-12 -12.9866 0.52781E-13 -13.2775 0.51176E+00 -0.2909 Charge balance for all species = -.6131E-08 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.1238832E-09 -.2017127E-01 -.2029471E+02 0.0000 2 H2O 0.1000000E+01 0.5550245E+02 0.9980872E+06 0.0000 3 Cl- 0.2677827E-03 0.2690090E-03 0.9519950E+01 6.3321 4 SO4-- 0.7677514E-04 0.7681519E-04 0.7365661E+01 15.5629 5 HCO3- 0.6030412E-03 0.1430202E-02 0.8710929E+02 6.6853 6 HS- 0.4272048E-03 0.4273755E-03 0.1410863E+02 6.5350 7 Al+++ 0.1497976E-28 0.2091970E-05 0.5634254E-01 0.4783 8 H4SiO4 0.9506657E-03 0.1351843E-01 0.1296982E+04 -3.0220 9 Ca++ 0.5446226E-07 0.2316277E-06 0.9266404E-02 12.4105 10 Mg++ 0.2251866E-10 0.9315184E-10 0.2260617E-05 9.0249 11 Fe++ 0.9213068E-13 0.2237101E-07 0.1247097E-02 6.6372 12 K+ 0.1565741E-03 0.1572078E-03 0.6136035E+01 6.0998 13 Na+ 0.1993066E-01 0.2229552E-01 0.5116437E+03 8.2037 14 Mn++ 0.3484912E-10 0.2506741E-08 0.1374665E-03 9.2154 15 F- 0.7917864E-05 0.7943421E-05 0.1506365E+00 4.8019 16 HPO4-- 0.4557356E-07 0.4640511E-07 0.4445871E-02 12.3365 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.1813254E-01 -.1812093E-01 -.1160533E-04 0.0000000E+00 2 H2O 0.4986081E+02 0.4986082E+02 -.1156785E-04 0.0000000E+00 3 Cl- 0.2416652E-03 0.2416652E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.6900719E-04 0.6900719E-04 0.0000000E+00 0.0000000E+00 5 HCO3- 0.1284827E-02 0.1284827E-02 0.0000000E+00 0.0000000E+00 6 HS- 0.3839343E-03 0.3839343E-03 0.0000000E+00 0.0000000E+00 7 Al+++ 0.4775352E-05 0.1879329E-05 0.2896023E-05 0.0000000E+00 8 H4SiO4 0.1215302E-01 0.1214433E-01 0.8693068E-05 0.0000000E+00 9 Ca++ 0.2080835E-06 0.2080835E-06 0.0000000E+00 0.0000000E+00 10 Mg++ 0.8368328E-10 0.8368328E-10 0.0000000E+00 0.0000000E+00 11 Fe++ 0.3259227E-07 0.2009708E-07 0.1249519E-07 0.0000000E+00 12 K+ 0.1412294E-03 0.1412282E-03 0.1249519E-08 0.0000000E+00 13 Na+ 0.2003215E-01 0.2002926E-01 0.2891025E-05 0.0000000E+00 14 Mn++ 0.2251939E-08 0.2251939E-08 0.0000000E+00 0.0000000E+00 15 F- 0.7136000E-05 0.7136000E-05 0.0000000E+00 0.0000000E+00 16 HPO4-- 0.4168819E-07 0.4168819E-07 0.0000000E+00 0.0000000E+00 Chg. balance for solid moles: -.4235E-21 Mass of aqueous solution: 0.899979E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 0.0175900 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 0.2891E-05 -5.539 0.7581E-03 -3.120 99.65 0.2910E-03 stilpnomelane-Fe 0.2499E-08 -8.602 0.2694E-05 -5.570 0.3541 0.9305E-06 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 0.000761 g Volume = 0.000292 cm3 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.0175900 moles log = -1.7547 Original solution: 1000.0103000 g Original solution / Rock added: 56851.07 (Water/Rock Ratio), log = 4.7547 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0206 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9997E+00 0.9859 0.1006E+01 0.1020E+01 CO2,gas 0.1161E-04 1.0071 0.1193E-04 0.1185E-04 CH4,gas 0.6285E-05 1.0125 0.6495E-05 0.6415E-05 H2,gas 0.2661E-03 1.0005 0.2717E-03 0.2716E-03 H2S,gas 0.3086E-05 0.9960 0.3137E-05 0.3149E-05 S2,gas 0.4901E-23 1.0000 0.5002E-23 0.5002E-23 CO,gas 0.8466E-12 1.0000 0.8640E-12 0.8640E-12 SO3,gas 0.1571E-39 1.0000 0.1604E-39 0.1604E-39 SO2,gas 0.1661E-20 1.0000 0.1695E-20 0.1695E-20 HF,gas 0.1124E-13 1.0000 0.1148E-13 0.1148E-13 HCl,gas 0.7331E-17 1.0000 0.7482E-17 0.7482E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 17 albite -0.38 -0.38 0.00 0.000 -0.94784E-12 165 stilpnomelane-Fe 13.02 13.02 0.00 0.000 -0.75827E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -13.28 -6.62 -2.207 0.11307E+05 -4.923 3 CH4,gas 4.54 -2.34 -6.89 -1.722 0.11758E+05 -5.187 4 H2,gas 8.00 2.73 -5.26 -3.008 0.89896E+04 -3.566 5 H2S,gas -6.23 -13.43 -7.20 -3.601 0.12298E+05 -5.504 6 S2,gas -7.34 -32.34 -25.00 -3.846 0.42687E+05 -23.301 7 CO,gas 3.21 -10.55 -13.76 -4.235 0.23499E+05 -12.063 8 SO3,gas 17.12 -24.37 -41.49 -10.373 0.70850E+05 -39.795 9 SO2,gas 0.83 -21.64 -22.47 -5.992 0.38366E+05 -20.771 10 HF,gas 0.47 -15.17 -15.64 -7.820 0.26704E+05 -13.940 11 HCl,gas 5.19 -13.64 -18.82 -9.412 0.32143E+05 -17.126 12 acmite 7.71 7.43 -0.28 -0.029 0.47839E+03 16 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 20 spessartine 24.46 19.54 -4.92 -0.246 0.84014E+04 21 analcite 3.32 2.64 -0.68 -0.076 0.11675E+04 25 annite 20.12 17.42 -2.70 -0.150 0.46093E+04 26 phlogopite 27.06 24.59 -2.48 -0.138 0.42307E+04 31 apatite-OH -18.15 -20.74 -2.59 -0.199 0.44236E+04 32 apatite-F -34.30 -35.91 -1.61 -0.134 0.27473E+04 36 aragonite 0.97 -0.87 -1.84 -0.613 0.31391E+04 37 brucite 12.57 9.02 -3.54 -0.709 0.60507E+04 38 calcite 0.81 -0.87 -1.68 -0.561 0.28749E+04 39 carnegieite-low 9.02 5.66 -3.36 -0.480 0.57426E+04 40 carnegieite-high 10.09 5.66 -4.43 -0.633 0.75696E+04 41 carpholite-Mg 8.58 3.94 -4.64 -0.310 0.79303E+04 43 celadonite 5.34 3.52 -1.83 -0.107 0.31187E+04 44 celadonite-Fe 3.88 1.13 -2.75 -0.162 0.46940E+04 45 chrysotile 23.89 21.03 -2.86 -0.238 0.48863E+04 47 clinochlore 39.07 37.02 -2.05 -0.064 0.35077E+04 48 daphnite 28.97 25.08 -3.89 -0.122 0.66391E+04 52 chloritoid-Fe 9.17 4.57 -4.60 -0.307 0.78572E+04 53 chloritoid-Mn 11.40 7.15 -4.25 -0.283 0.72584E+04 55 coesite -2.38 -3.02 -0.65 -0.215 0.11029E+04 62 cristobalite -2.56 -3.02 -0.46 -0.154 0.78823E+03 64 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71256E+04 66 diaspore 2.87 0.48 -2.40 -0.399 0.40900E+04 67 diamond -3.10 -7.81 -4.71 -1.346 0.80425E+04 68 diopside 16.18 15.39 -0.79 -0.079 0.13488E+04 69 hedenbergite 14.21 13.00 -1.20 -0.120 0.20566E+04 76 epidote 24.67 21.98 -2.69 -0.130 0.45903E+04 78 epidote-Fe 29.84 26.77 -3.07 -0.159 0.52382E+04 79 fayalite 14.05 10.25 -3.79 -0.542 0.64768E+04 80 ferrosilite 11.15 7.23 -3.92 -0.392 0.66915E+04 84 gibbsite 4.08 0.48 -3.60 -0.514 0.61486E+04 85 glaucophane 22.97 20.26 -2.71 -0.073 0.46304E+04 86 glaucophane-Fe 17.28 13.10 -4.18 -0.113 0.71300E+04 87 graphite -3.55 -7.81 -4.27 -1.219 0.72847E+04 88 greenalite 16.14 13.87 -2.27 -0.189 0.38789E+04 91 hematite 12.57 10.54 -2.03 -0.246 0.34604E+04 92 heulandite -5.83 -7.79 -1.96 -0.089 0.33456E+04 96 jadeite 4.22 2.64 -1.58 -0.158 0.26930E+04 97 julgoldite 70.43 65.86 -4.56 -0.119 0.77915E+04 98 kalsilite 7.58 3.56 -4.03 -0.575 0.68773E+04 99 kaolinite -1.33 -5.09 -3.75 -0.341 0.64107E+04 102 laumontite 2.88 1.28 -1.60 -0.107 0.27390E+04 103 lawsonite 9.62 7.32 -2.29 -0.153 0.39149E+04 104 leucite 4.12 0.53 -3.58 -0.358 0.61208E+04 106 lizardite 23.24 21.03 -2.21 -0.184 0.37789E+04 107 magnesite 0.69 -4.26 -4.95 -1.649 0.84488E+04 108 magnetite 20.09 17.18 -2.91 -0.238 0.49698E+04 109 minnesotaite 10.39 7.82 -2.56 -0.151 0.43784E+04 113 manganosite 14.06 9.22 -4.84 -1.211 0.82688E+04 117 microcline -2.49 -2.49 0.00 0.000 0.22643E+01 121 muscovite 2.58 -1.53 -4.11 -0.242 0.70238E+04 122 paragonite 4.24 0.57 -3.67 -0.216 0.62606E+04 123 nepheline 8.34 5.66 -2.68 -0.383 0.45750E+04 129 periclase-Fe 11.63 6.64 -4.99 -1.247 0.85192E+04 135 phlogopite-Na 29.65 26.69 -2.96 -0.164 0.50473E+04 137 prehnite 19.37 16.71 -2.66 -0.156 0.45421E+04 138 prehnite-Fe 22.50 21.50 -0.99 -0.060 0.16984E+04 143 pyrite -21.25 -22.96 -1.72 -0.404 0.29304E+04 144 pyrrhotite -4.26 -6.80 -2.54 -0.845 0.43287E+04 145 pyrrhotiteFe0.875 -6.02 -7.96 -1.95 -0.716 0.33250E+04 146 pyroxmangite 7.40 6.19 -1.21 -0.241 0.20579E+04 147 pyrophyllite -6.18 -11.13 -4.96 -0.310 0.84612E+04 148 quartz -2.99 -3.02 -0.03 -0.011 0.55556E+02 152 rhodochrosite -0.98 -4.07 -3.09 -1.030 0.52773E+04 153 rhodonite 7.45 6.19 -1.25 -0.250 0.21382E+04 154 sanidine -1.28 -2.49 -1.21 -0.093 0.20700E+04 156 siderite -2.61 -6.65 -4.04 -1.346 0.68931E+04 164 stilbite -7.52 -7.79 -0.26 -0.013 0.45174E+03 166 stilpnomelane-Mg 27.44 24.96 -2.49 -0.074 0.42451E+04 172 talc 16.49 14.99 -1.50 -0.088 0.25686E+04 175 tephroite 18.09 15.41 -2.68 -0.382 0.45709E+04 179 tridymite -2.63 -3.02 -0.40 -0.132 0.67553E+03 180 tremolite 47.87 45.77 -2.10 -0.057 0.35850E+04 181 ferroactinolite 38.45 33.83 -4.62 -0.125 0.78902E+04 182 troilite-low -4.41 -6.80 -2.38 -0.795 0.40715E+04 188 wairakite 3.95 1.28 -2.67 -0.157 0.45609E+04 189 walstromite 11.51 9.39 -2.12 -0.424 0.36210E+04 190 wollastonite 10.46 9.39 -1.07 -0.215 0.18315E+04 191 pseudo-wollastonite 11.00 9.39 -1.61 -0.322 0.27513E+04 193 akaganeite 7.75 5.27 -2.48 -0.537 0.42427E+04 200 chalcedony -2.80 -3.02 -0.22 -0.073 0.37485E+03 202 montmorillonite-Ca -2.29 -6.26 -3.97 -0.246 0.67828E+04 203 montmorillonite-K -2.24 -6.30 -4.06 -0.249 0.69344E+04 204 montmorillonite-Mg -2.48 -6.82 -4.34 -0.269 0.74136E+04 205 montmorillonite-Na -2.04 -5.60 -3.57 -0.218 0.60886E+04 206 nontronite-Ca 3.21 1.65 -1.56 -0.101 0.26637E+04 207 nontronite-H 2.53 -0.39 -2.93 -0.196 0.49960E+04 208 nontronite-K 3.34 1.62 -1.72 -0.110 0.29386E+04 209 nontronite-Mg 3.07 1.10 -1.98 -0.128 0.33787E+04 210 nontronite-Na 3.52 2.31 -1.21 -0.077 0.20587E+04 226 tobermorite 9.82 7.32 -2.51 -0.684 0.42808E+04 232 alabandite -0.98 -4.22 -3.24 -1.080 0.55313E+04 235 boehmite 4.41 0.48 -3.93 -0.655 0.67069E+04 237 ferrous-oxide 9.81 6.64 -3.17 -0.794 0.54201E+04 243 silica-amorphous -2.09 -3.02 -0.93 -0.310 0.15890E+04 245 an20ab80 2.02 1.16 -0.86 -0.066 0.14688E+04 246 an25ab75 2.65 1.54 -1.10 -0.085 0.18830E+04 247 an30ab70 3.28 1.93 -1.35 -0.104 0.23068E+04 248 tr.625ac.25prg.125 45.16 43.62 -1.55 -0.042 0.26422E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 0.0004000 MOLES Current total amount of reactant added: 0.0175900 MOLES New total amount of reactant added: 0.0179900 MOLES Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.5508E-08 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 7 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 0.0179900 Water: Moles liquid = 0.4987E+02 kg liquid = 0.8984E+00 Moles total = 0.4986E+02 kg total = 0.8983E+00 Activity = 1.0000 Stoichiometric ionic strength = .1248436E-01 Osmotic coef. = 0.9408 True ionic strength = .2101075E-01 Chg. balance for total moles = -.5508E-08 Max. difference allowed = 0.2440E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.12493E-09 -9.9033 0.10466E-09 -9.9802 0.83774E+00 -0.0769 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.27040E-03 -3.5680 0.22511E-03 -3.6476 0.83251E+00 -0.0796 4 SO4-- 0.78898E-04 -4.1029 0.40456E-04 -4.3930 0.51276E+00 -0.2901 5 HCO3- 0.61954E-03 -3.2079 0.51656E-03 -3.2869 0.83378E+00 -0.0790 6 HS- 0.43589E-03 -3.3606 0.36294E-03 -3.4402 0.83264E+00 -0.0795 7 Al+++ 0.15144E-28 -28.8198 0.33984E-29 -29.4687 0.22440E+00 -0.6490 8 H4SiO4 0.95804E-03 -3.0186 0.95804E-03 -3.0186 0.10000E+01 0.0000 9 Ca++ 0.53872E-07 -7.2686 0.27413E-07 -7.5620 0.50885E+00 -0.2934 10 Mg++ 0.22558E-10 -10.6467 0.11424E-10 -10.9422 0.50643E+00 -0.2955 11 Fe++ 0.93191E-13 -13.0306 0.47249E-13 -13.3256 0.50701E+00 -0.2950 12 K+ 0.15657E-03 -3.8053 0.13058E-03 -3.8841 0.83398E+00 -0.0788 13 Na+ 0.19932E-01 -1.7004 0.16591E-01 -1.7801 0.83235E+00 -0.0797 14 Mn++ 0.35384E-10 -10.4512 0.17956E-10 -10.7458 0.50745E+00 -0.2946 15 F- 0.80953E-05 -5.0918 0.67250E-05 -5.1723 0.83073E+00 -0.0805 16 HPO4-- 0.45579E-07 -7.3412 0.23375E-07 -7.6313 0.51284E+00 -0.2900 18 HSiO3- 0.10267E-01 -1.9886 0.85471E-02 -2.0682 0.83251E+00 -0.0796 19 Ca(HSiO3)+ 0.63967E-08 -8.1940 0.53359E-08 -8.2728 0.83417E+00 -0.0787 20 Mg(HSiO3)+ 0.33176E-11 -11.4792 0.27674E-11 -11.5579 0.83417E+00 -0.0787 21 NaHSiO3,aq 0.22935E-02 -2.6395 0.22935E-02 -2.6395 0.10000E+01 0.0000 22 AlO+ 0.50596E-16 -16.2959 0.42206E-16 -16.3746 0.83417E+00 -0.0787 24 HAlO2,aq 0.80307E-10 -10.0952 0.80307E-10 -10.0952 0.10000E+01 0.0000 25 AlO2- 0.20440E-05 -5.6895 0.16985E-05 -5.7699 0.83095E+00 -0.0804 26 CH4,aq 0.45187E-08 -8.3450 0.45015E-08 -8.3466 0.99620E+00 -0.0017 27 C2H6,aq 0.16866E-19 -19.7730 0.16802E-19 -19.7746 0.99620E+00 -0.0017 31 CO,aq 0.59834E-15 -15.2231 0.59834E-15 -15.2231 0.10000E+01 0.0000 32 CO2,aq 0.11596E-06 -6.9357 0.11552E-06 -6.9373 0.99620E+00 -0.0017 33 CO3-2 0.84258E-03 -3.0744 0.43109E-03 -3.3654 0.51163E+00 -0.2910 34 CaCO3,aq 0.14818E-06 -6.8292 0.14818E-06 -6.8292 0.10000E+01 0.0000 35 Ca(HCO3)+ 0.43332E-09 -9.3632 0.36146E-09 -9.4419 0.83417E+00 -0.0787 36 CaCl+ 0.11972E-10 -10.9218 0.99864E-11 -11.0006 0.83417E+00 -0.0787 37 CaCl2,aq 0.53408E-15 -15.2724 0.53408E-15 -15.2724 0.10000E+01 0.0000 38 CaF+ 0.32267E-11 -11.4912 0.26916E-11 -11.5700 0.83417E+00 -0.0787 39 CaOH+ 0.22378E-07 -7.6502 0.18667E-07 -7.7289 0.83417E+00 -0.0787 40 CaSO4,aq 0.35217E-09 -9.4533 0.35217E-09 -9.4533 0.10000E+01 0.0000 41 HCl,aq 0.43173E-14 -14.3648 0.43173E-14 -14.3648 0.10000E+01 0.0000 45 HF,aq 0.48184E-11 -11.3171 0.48184E-11 -11.3171 0.10000E+01 0.0000 46 HF2- 0.13142E-16 -16.8814 0.10940E-16 -16.9610 0.83251E+00 -0.0796 48 FeCl+ 0.20182E-16 -16.6950 0.16835E-16 -16.7738 0.83417E+00 -0.0787 51 FeF+ 0.19466E-16 -16.7107 0.16238E-16 -16.7895 0.83417E+00 -0.0787 53 FeO,aq 0.16764E-09 -9.7756 0.16764E-09 -9.7756 0.10000E+01 0.0000 54 FeOH+ 0.17616E-10 -10.7541 0.14695E-10 -10.8328 0.83417E+00 -0.0787 55 HFeO2- 0.20130E-07 -7.6961 0.16759E-07 -7.7758 0.83251E+00 -0.0796 56 FeO+ 0.92537E-16 -16.0337 0.77191E-16 -16.1124 0.83417E+00 -0.0787 58 FeO2- 0.17320E-08 -8.7615 0.14419E-08 -8.8411 0.83251E+00 -0.0796 59 HFeO2,aq 0.19194E-10 -10.7168 0.19194E-10 -10.7168 0.10000E+01 0.0000 60 H2,aq 0.20697E-06 -6.6841 0.20618E-06 -6.6858 0.99620E+00 -0.0017 61 KCl,aq 0.53275E-09 -9.2735 0.53275E-09 -9.2735 0.10000E+01 0.0000 62 KHSO4,aq 0.15633E-17 -17.8060 0.15633E-17 -17.8060 0.10000E+01 0.0000 63 KOH,aq 0.53281E-06 -6.2734 0.53281E-06 -6.2734 0.10000E+01 0.0000 64 KSO4- 0.98468E-07 -7.0067 0.81976E-07 -7.0863 0.83251E+00 -0.0796 65 MgCO3,aq 0.15478E-10 -10.8103 0.15478E-10 -10.8103 0.10000E+01 0.0000 66 Mg(HCO3)+ 0.18452E-12 -12.7340 0.15392E-12 -12.8127 0.83417E+00 -0.0787 67 MgCl+ 0.45218E-14 -14.3447 0.37719E-14 -14.4234 0.83417E+00 -0.0787 68 MgF+ 0.49811E-14 -14.3027 0.41551E-14 -14.3814 0.83417E+00 -0.0787 69 MgOH+ 0.51603E-10 -10.2873 0.43046E-10 -10.3661 0.83417E+00 -0.0787 71 MnF+ 0.24383E-14 -14.6129 0.20339E-14 -14.6917 0.83417E+00 -0.0787 72 MnO,aq 0.16975E-08 -8.7702 0.16975E-08 -8.7702 0.10000E+01 0.0000 73 MnOH+ 0.62190E-09 -9.2063 0.51877E-09 -9.2850 0.83417E+00 -0.0787 74 MnO2-2 0.10052E-10 -10.9978 0.51427E-11 -11.2888 0.51163E+00 -0.2910 75 HMnO2- 0.14165E-09 -9.8488 0.11792E-09 -9.9284 0.83251E+00 -0.0796 78 MnCl+ 0.29838E-13 -13.5252 0.24890E-13 -13.6040 0.83417E+00 -0.0787 79 MnSO4,aq 0.20971E-12 -12.6784 0.20971E-12 -12.6784 0.10000E+01 0.0000 80 NaCl,aq 0.12377E-05 -5.9074 0.12377E-05 -5.9074 0.10000E+01 0.0000 81 NaF,aq 0.26121E-07 -7.5830 0.26121E-07 -7.5830 0.10000E+01 0.0000 82 NaOH,aq 0.68106E-04 -4.1668 0.68106E-04 -4.1668 0.10000E+01 0.0000 84 OH- 0.66434E-02 -2.1776 0.55203E-02 -2.2580 0.83095E+00 -0.0804 89 HPO3-2 0.29355E-16 -16.5323 0.15019E-16 -16.8234 0.51163E+00 -0.2910 92 H3PO4,aq 0.17908E-17 -17.7469 0.17908E-17 -17.7469 0.10000E+01 0.0000 93 H2PO4- 0.54157E-10 -10.2663 0.45131E-10 -10.3455 0.83333E+00 -0.0792 94 PO4-3 0.77165E-09 -9.1126 0.18222E-09 -9.7394 0.23614E+00 -0.6268 98 HP2O7-3 0.13563E-17 -17.8676 0.30468E-18 -18.5162 0.22464E+00 -0.6485 99 P2O7-4 0.94876E-17 -17.0228 0.69545E-18 -18.1577 0.73301E-01 -1.1349 100 H2S,aq 0.11785E-06 -6.9287 0.11740E-06 -6.9303 0.99620E+00 -0.0017 101 S2-2 0.27669E-10 -10.5580 0.14156E-10 -10.8490 0.51163E+00 -0.2910 102 S3-2 0.21226E-16 -16.6731 0.10860E-16 -16.9642 0.51163E+00 -0.2910 107 SO3-2 0.20872E-11 -11.6804 0.10839E-11 -11.9650 0.51932E+00 -0.2846 108 HSO3- 0.85324E-14 -14.0689 0.71033E-14 -14.1485 0.83251E+00 -0.0796 109 HSO4- 0.48869E-11 -11.3110 0.40806E-11 -11.3893 0.83501E+00 -0.0783 111 S2O3-2 0.10905E-12 -12.9624 0.55793E-13 -13.2534 0.51163E+00 -0.2910 Charge balance for all species = -.6131E-08 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.1249346E-09 -.2012299E-01 -.2024609E+02 0.0000 2 H2O 0.1000000E+01 0.5550241E+02 0.9980846E+06 0.0000 3 Cl- 0.2703958E-03 0.2716341E-03 0.9612830E+01 6.3326 4 SO4-- 0.7889792E-04 0.7894071E-04 0.7569461E+01 15.5674 5 HCO3- 0.6195389E-03 0.1462383E-02 0.8906921E+02 6.6933 6 HS- 0.4358920E-03 0.4360660E-03 0.1439550E+02 6.5400 7 Al+++ 0.1514425E-28 0.2044089E-05 0.5505286E-01 0.4719 8 H4SiO4 0.9580432E-03 0.1351818E-01 0.1296956E+04 -3.0186 9 Ca++ 0.5387238E-07 0.2316259E-06 0.9266320E-02 12.3984 10 Mg++ 0.2255778E-10 0.9315115E-10 0.2260596E-05 9.0182 11 Fe++ 0.9319146E-13 0.2206688E-07 0.1230141E-02 6.6348 12 K+ 0.1565748E-03 0.1572066E-03 0.6135977E+01 6.0961 13 Na+ 0.1993246E-01 0.2229531E-01 0.5116379E+03 8.2001 14 Mn++ 0.3538430E-10 0.2506722E-08 0.1374653E-03 9.2146 15 F- 0.8095335E-05 0.8121465E-05 0.1540126E+00 4.8079 16 HPO4-- 0.4557896E-07 0.4640476E-07 0.4445830E-02 12.3292 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.1808947E-01 -.1807769E-01 -.1177780E-04 0.0000000E+00 2 H2O 0.4986114E+02 0.4986115E+02 -.1173950E-04 0.0000000E+00 3 Cl- 0.2440252E-03 0.2440252E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.7091719E-04 0.7091719E-04 0.0000000E+00 0.0000000E+00 5 HCO3- 0.1313747E-02 0.1313747E-02 0.0000000E+00 0.0000000E+00 6 HS- 0.3917443E-03 0.3917443E-03 0.0000000E+00 0.0000000E+00 7 Al+++ 0.4775352E-05 0.1836328E-05 0.2939024E-05 0.0000000E+00 8 H4SiO4 0.1215302E-01 0.1214420E-01 0.8822180E-05 0.0000000E+00 9 Ca++ 0.2080835E-06 0.2080835E-06 0.0000000E+00 0.0000000E+00 10 Mg++ 0.8368328E-10 0.8368328E-10 0.0000000E+00 0.0000000E+00 11 Fe++ 0.3259227E-07 0.1982401E-07 0.1276826E-07 0.0000000E+00 12 K+ 0.1412294E-03 0.1412281E-03 0.1276826E-08 0.0000000E+00 13 Na+ 0.2003215E-01 0.2002922E-01 0.2933917E-05 0.0000000E+00 14 Mn++ 0.2251939E-08 0.2251939E-08 0.0000000E+00 0.0000000E+00 15 F- 0.7296000E-05 0.7296000E-05 0.0000000E+00 0.0000000E+00 16 HPO4-- 0.4168819E-07 0.4168819E-07 0.0000000E+00 0.0000000E+00 Chg. balance for solid moles: 0.1271E-20 Mass of aqueous solution: 0.899987E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 0.0179900 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 0.2934E-05 -5.533 0.7693E-03 -3.114 99.64 0.2953E-03 stilpnomelane-Fe 0.2554E-08 -8.593 0.2753E-05 -5.560 0.3565 0.9509E-06 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 0.000772 g Volume = 0.000296 cm3 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.0179900 moles log = -1.7450 Original solution: 1000.0103000 g Original solution / Rock added: 55587.01 (Water/Rock Ratio), log = 4.7450 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0206 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9997E+00 0.9859 0.1006E+01 0.1020E+01 CO2,gas 0.1202E-04 1.0071 0.1236E-04 0.1227E-04 CH4,gas 0.6412E-05 1.0125 0.6626E-05 0.6544E-05 H2,gas 0.2651E-03 1.0005 0.2707E-03 0.2705E-03 H2S,gas 0.3175E-05 0.9960 0.3227E-05 0.3240E-05 S2,gas 0.5228E-23 1.0000 0.5336E-23 0.5336E-23 CO,gas 0.8737E-12 1.0000 0.8916E-12 0.8916E-12 SO3,gas 0.1642E-39 1.0000 0.1676E-39 0.1676E-39 SO2,gas 0.1729E-20 1.0000 0.1765E-20 0.1765E-20 HF,gas 0.1159E-13 1.0000 0.1183E-13 0.1183E-13 HCl,gas 0.7464E-17 1.0000 0.7618E-17 0.7618E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 17 albite -0.38 -0.38 0.00 0.000 0.11184E-10 165 stilpnomelane-Fe 13.02 13.02 0.00 0.000 0.21232E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -13.27 -6.61 -2.202 0.11281E+05 -4.908 3 CH4,gas 4.54 -2.33 -6.88 -1.719 0.11744E+05 -5.179 4 H2,gas 8.00 2.73 -5.27 -3.009 0.89924E+04 -3.568 5 H2S,gas -6.23 -13.42 -7.19 -3.595 0.12277E+05 -5.491 6 S2,gas -7.34 -32.31 -24.97 -3.842 0.42639E+05 -23.273 7 CO,gas 3.21 -10.53 -13.75 -4.230 0.23476E+05 -12.050 8 SO3,gas 17.12 -24.35 -41.47 -10.369 0.70817E+05 -39.776 9 SO2,gas 0.83 -21.62 -22.45 -5.987 0.38337E+05 -20.753 10 HF,gas 0.47 -15.15 -15.63 -7.813 0.26681E+05 -13.927 11 HCl,gas 5.19 -13.63 -18.82 -9.409 0.32130E+05 -17.118 12 acmite 7.71 7.43 -0.28 -0.029 0.47586E+03 16 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 20 spessartine 24.46 19.53 -4.93 -0.246 0.84102E+04 21 analcite 3.32 2.63 -0.69 -0.076 0.11732E+04 25 annite 20.12 17.42 -2.71 -0.150 0.46218E+04 26 phlogopite 27.06 24.57 -2.50 -0.139 0.42648E+04 31 apatite-OH -18.15 -20.78 -2.63 -0.202 0.44901E+04 32 apatite-F -34.30 -35.94 -1.63 -0.136 0.27912E+04 36 aragonite 0.97 -0.87 -1.84 -0.612 0.31336E+04 37 brucite 12.57 9.02 -3.55 -0.710 0.60621E+04 38 calcite 0.81 -0.87 -1.68 -0.560 0.28694E+04 39 carnegieite-low 9.02 5.65 -3.37 -0.481 0.57541E+04 40 carnegieite-high 10.09 5.65 -4.44 -0.634 0.75811E+04 41 carpholite-Mg 8.58 3.92 -4.66 -0.310 0.79522E+04 43 celadonite 5.34 3.51 -1.83 -0.108 0.31244E+04 44 celadonite-Fe 3.88 1.13 -2.75 -0.162 0.46925E+04 45 chrysotile 23.89 21.02 -2.87 -0.240 0.49088E+04 47 clinochlore 39.07 36.98 -2.09 -0.065 0.35693E+04 48 daphnite 28.97 25.06 -3.90 -0.122 0.66647E+04 52 chloritoid-Fe 9.17 4.56 -4.61 -0.308 0.78776E+04 53 chloritoid-Mn 11.40 7.14 -4.26 -0.284 0.72760E+04 55 coesite -2.38 -3.02 -0.64 -0.214 0.10971E+04 62 cristobalite -2.56 -3.02 -0.46 -0.153 0.78249E+03 64 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71257E+04 66 diaspore 2.87 0.47 -2.40 -0.400 0.41010E+04 67 diamond -3.10 -7.80 -4.70 -1.342 0.80220E+04 68 diopside 16.18 15.38 -0.80 -0.080 0.13694E+04 69 hedenbergite 14.21 13.00 -1.21 -0.121 0.20700E+04 76 epidote 24.67 21.95 -2.72 -0.132 0.46393E+04 78 epidote-Fe 29.84 26.75 -3.09 -0.161 0.52789E+04 79 fayalite 14.05 10.25 -3.79 -0.542 0.64794E+04 80 ferrosilite 11.15 7.23 -3.92 -0.392 0.66883E+04 84 gibbsite 4.08 0.47 -3.61 -0.515 0.61595E+04 85 glaucophane 22.97 20.25 -2.73 -0.074 0.46530E+04 86 glaucophane-Fe 17.28 13.10 -4.18 -0.113 0.71310E+04 87 graphite -3.55 -7.80 -4.25 -1.216 0.72642E+04 88 greenalite 16.14 13.87 -2.27 -0.189 0.38799E+04 91 hematite 12.57 10.54 -2.03 -0.246 0.34659E+04 92 heulandite -5.83 -7.79 -1.96 -0.089 0.33481E+04 96 jadeite 4.22 2.63 -1.58 -0.158 0.26987E+04 97 julgoldite 70.43 65.82 -4.60 -0.120 0.78592E+04 98 kalsilite 7.58 3.55 -4.03 -0.576 0.68889E+04 99 kaolinite -1.33 -5.09 -3.76 -0.342 0.64212E+04 102 laumontite 2.88 1.27 -1.62 -0.108 0.27588E+04 103 lawsonite 9.62 7.30 -2.31 -0.154 0.39462E+04 104 leucite 4.12 0.53 -3.59 -0.359 0.61266E+04 106 lizardite 23.24 21.02 -2.23 -0.186 0.38015E+04 107 magnesite 0.69 -4.25 -4.94 -1.646 0.84340E+04 108 magnetite 20.09 17.17 -2.92 -0.238 0.49794E+04 109 minnesotaite 10.39 7.83 -2.56 -0.150 0.43680E+04 113 manganosite 14.06 9.21 -4.84 -1.211 0.82701E+04 117 microcline -2.49 -2.49 0.00 0.000 0.23271E+01 121 muscovite 2.58 -1.54 -4.13 -0.243 0.70459E+04 122 paragonite 4.24 0.56 -3.68 -0.216 0.62826E+04 123 nepheline 8.34 5.65 -2.69 -0.384 0.45864E+04 129 periclase-Fe 11.63 6.63 -4.99 -1.248 0.85233E+04 135 phlogopite-Na 29.65 26.67 -2.98 -0.165 0.50813E+04 137 prehnite 19.37 16.68 -2.69 -0.158 0.45883E+04 138 prehnite-Fe 22.50 21.48 -1.02 -0.061 0.17363E+04 143 pyrite -21.25 -22.94 -1.69 -0.398 0.28895E+04 144 pyrrhotite -4.26 -6.79 -2.53 -0.842 0.43118E+04 145 pyrrhotiteFe0.875 -6.02 -7.95 -1.94 -0.712 0.33072E+04 146 pyroxmangite 7.40 6.20 -1.20 -0.241 0.20535E+04 147 pyrophyllite -6.18 -11.13 -4.95 -0.310 0.84603E+04 148 quartz -2.99 -3.02 -0.03 -0.010 0.49824E+02 152 rhodochrosite -0.98 -4.05 -3.08 -1.025 0.52524E+04 153 rhodonite 7.45 6.20 -1.25 -0.250 0.21338E+04 154 sanidine -1.28 -2.49 -1.21 -0.093 0.20701E+04 156 siderite -2.61 -6.63 -4.02 -1.341 0.68711E+04 164 stilbite -7.52 -7.79 -0.27 -0.013 0.45432E+03 166 stilpnomelane-Mg 27.44 24.93 -2.51 -0.075 0.42812E+04 172 talc 16.49 14.98 -1.51 -0.089 0.25797E+04 175 tephroite 18.09 15.41 -2.68 -0.382 0.45678E+04 179 tridymite -2.63 -3.02 -0.39 -0.131 0.66980E+03 180 tremolite 47.87 45.74 -2.13 -0.058 0.36374E+04 181 ferroactinolite 38.45 33.82 -4.63 -0.125 0.79065E+04 182 troilite-low -4.41 -6.79 -2.37 -0.792 0.40546E+04 188 wairakite 3.95 1.27 -2.68 -0.158 0.45807E+04 189 walstromite 11.51 9.38 -2.13 -0.426 0.36360E+04 190 wollastonite 10.46 9.38 -1.08 -0.216 0.18464E+04 191 pseudo-wollastonite 11.00 9.38 -1.62 -0.324 0.27663E+04 193 akaganeite 7.75 5.27 -2.49 -0.538 0.42455E+04 200 chalcedony -2.80 -3.02 -0.22 -0.072 0.36912E+03 202 montmorillonite-Ca -2.29 -6.26 -3.97 -0.246 0.67854E+04 203 montmorillonite-K -2.24 -6.30 -4.06 -0.249 0.69356E+04 204 montmorillonite-Mg -2.48 -6.82 -4.34 -0.269 0.74147E+04 205 montmorillonite-Na -2.04 -5.60 -3.57 -0.218 0.60898E+04 206 nontronite-Ca 3.21 1.66 -1.56 -0.101 0.26552E+04 207 nontronite-H 2.53 -0.39 -2.92 -0.196 0.49840E+04 208 nontronite-K 3.34 1.63 -1.72 -0.110 0.29287E+04 209 nontronite-Mg 3.07 1.10 -1.97 -0.128 0.33686E+04 210 nontronite-Na 3.52 2.32 -1.20 -0.077 0.20488E+04 226 tobermorite 9.82 7.31 -2.51 -0.686 0.42923E+04 232 alabandite -0.98 -4.21 -3.23 -1.076 0.55115E+04 235 boehmite 4.41 0.47 -3.93 -0.656 0.67179E+04 237 ferrous-oxide 9.81 6.63 -3.18 -0.794 0.54243E+04 243 silica-amorphous -2.09 -3.02 -0.93 -0.309 0.15833E+04 245 an20ab80 2.02 1.15 -0.86 -0.066 0.14751E+04 246 an25ab75 2.65 1.54 -1.11 -0.085 0.18908E+04 247 an30ab70 3.28 1.92 -1.36 -0.104 0.23161E+04 248 tr.625ac.25prg.125 45.16 43.59 -1.58 -0.042 0.26904E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 0.0004000 MOLES Current total amount of reactant added: 0.0179900 MOLES New total amount of reactant added: 0.0183900 MOLES Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.5508E-08 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 7 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 0.0183900 Water: Moles liquid = 0.4987E+02 kg liquid = 0.8984E+00 Moles total = 0.4986E+02 kg total = 0.8983E+00 Activity = 1.0000 Stoichiometric ionic strength = .1251014E-01 Osmotic coef. = 0.9406 True ionic strength = .2103022E-01 Chg. balance for total moles = -.5508E-08 Max. difference allowed = 0.2464E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.12600E-09 -9.8996 0.10555E-09 -9.9765 0.83769E+00 -0.0769 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.27301E-03 -3.5638 0.22727E-03 -3.6435 0.83246E+00 -0.0796 4 SO4-- 0.81021E-04 -4.0914 0.41534E-04 -4.3816 0.51264E+00 -0.2902 5 HCO3- 0.63618E-03 -3.1964 0.53040E-03 -3.2754 0.83372E+00 -0.0790 6 HS- 0.44458E-03 -3.3521 0.37015E-03 -3.4316 0.83259E+00 -0.0796 7 Al+++ 0.15311E-28 -28.8150 0.34340E-29 -29.4642 0.22428E+00 -0.6492 8 H4SiO4 0.96551E-03 -3.0152 0.96551E-03 -3.0152 0.10000E+01 0.0000 9 Ca++ 0.53301E-07 -7.2733 0.27116E-07 -7.5668 0.50872E+00 -0.2935 10 Mg++ 0.22597E-10 -10.6459 0.11441E-10 -10.9415 0.50631E+00 -0.2956 11 Fe++ 0.94269E-13 -13.0256 0.47783E-13 -13.3207 0.50688E+00 -0.2951 12 K+ 0.15658E-03 -3.8053 0.13057E-03 -3.8841 0.83393E+00 -0.0789 13 Na+ 0.19934E-01 -1.7004 0.16591E-01 -1.7801 0.83230E+00 -0.0797 14 Mn++ 0.35929E-10 -10.4446 0.18227E-10 -10.7393 0.50732E+00 -0.2947 15 F- 0.82728E-05 -5.0823 0.68720E-05 -5.1629 0.83068E+00 -0.0806 16 HPO4-- 0.45584E-07 -7.3412 0.23372E-07 -7.6313 0.51271E+00 -0.2901 18 HSiO3- 0.10260E-01 -1.9888 0.85414E-02 -2.0685 0.83246E+00 -0.0796 19 Ca(HSiO3)+ 0.63235E-08 -8.1990 0.52745E-08 -8.2778 0.83412E+00 -0.0788 20 Mg(HSiO3)+ 0.33205E-11 -11.4788 0.27697E-11 -11.5576 0.83412E+00 -0.0788 21 NaHSiO3,aq 0.22920E-02 -2.6398 0.22920E-02 -2.6398 0.10000E+01 0.0000 22 AlO+ 0.50274E-16 -16.2987 0.41934E-16 -16.3774 0.83412E+00 -0.0788 24 HAlO2,aq 0.79121E-10 -10.1017 0.79121E-10 -10.1017 0.10000E+01 0.0000 25 AlO2- 0.19971E-05 -5.6996 0.16593E-05 -5.7801 0.83090E+00 -0.0805 26 CH4,aq 0.46091E-08 -8.3364 0.45916E-08 -8.3380 0.99619E+00 -0.0017 27 C2H6,aq 0.17614E-19 -19.7541 0.17547E-19 -19.7558 0.99619E+00 -0.0017 31 CO,aq 0.61725E-15 -15.2095 0.61725E-15 -15.2095 0.10000E+01 0.0000 32 CO2,aq 0.12008E-06 -6.9205 0.11962E-06 -6.9222 0.99619E+00 -0.0017 33 CO3-2 0.85811E-03 -3.0665 0.43893E-03 -3.3576 0.51151E+00 -0.2911 34 CaCO3,aq 0.14924E-06 -6.8261 0.14924E-06 -6.8261 0.10000E+01 0.0000 35 Ca(HCO3)+ 0.44013E-09 -9.3564 0.36712E-09 -9.4352 0.83412E+00 -0.0788 36 CaCl+ 0.11956E-10 -10.9224 0.99729E-11 -11.0012 0.83412E+00 -0.0788 37 CaCl2,aq 0.53848E-15 -15.2688 0.53848E-15 -15.2688 0.10000E+01 0.0000 38 CaF+ 0.32616E-11 -11.4866 0.27206E-11 -11.5653 0.83412E+00 -0.0788 39 CaOH+ 0.21951E-07 -7.6586 0.18309E-07 -7.7373 0.83412E+00 -0.0788 40 CaSO4,aq 0.35763E-09 -9.4466 0.35763E-09 -9.4466 0.10000E+01 0.0000 41 HCl,aq 0.43957E-14 -14.3570 0.43957E-14 -14.3570 0.10000E+01 0.0000 45 HF,aq 0.49654E-11 -11.3040 0.49654E-11 -11.3040 0.10000E+01 0.0000 46 HF2- 0.13839E-16 -16.8589 0.11521E-16 -16.9385 0.83246E+00 -0.0796 48 FeCl+ 0.20607E-16 -16.6860 0.17189E-16 -16.7648 0.83412E+00 -0.0788 51 FeF+ 0.20117E-16 -16.6964 0.16780E-16 -16.7752 0.83412E+00 -0.0788 53 FeO,aq 0.16670E-09 -9.7781 0.16670E-09 -9.7781 0.10000E+01 0.0000 54 FeOH+ 0.17667E-10 -10.7528 0.14736E-10 -10.8316 0.83412E+00 -0.0788 55 HFeO2- 0.19851E-07 -7.7022 0.16525E-07 -7.7819 0.83246E+00 -0.0796 56 FeO+ 0.92978E-16 -16.0316 0.77554E-16 -16.1104 0.83412E+00 -0.0788 58 FeO2- 0.17111E-08 -8.7667 0.14245E-08 -8.8464 0.83246E+00 -0.0796 59 HFeO2,aq 0.19122E-10 -10.7185 0.19122E-10 -10.7185 0.10000E+01 0.0000 60 H2,aq 0.20619E-06 -6.6857 0.20541E-06 -6.6874 0.99619E+00 -0.0017 61 KCl,aq 0.53784E-09 -9.2693 0.53784E-09 -9.2693 0.10000E+01 0.0000 62 KHSO4,aq 0.16184E-17 -17.7909 0.16184E-17 -17.7909 0.10000E+01 0.0000 63 KOH,aq 0.52831E-06 -6.2771 0.52831E-06 -6.2771 0.10000E+01 0.0000 64 KSO4- 0.10109E-06 -6.9953 0.84156E-07 -7.0749 0.83246E+00 -0.0796 65 MgCO3,aq 0.15783E-10 -10.8018 0.15783E-10 -10.8018 0.10000E+01 0.0000 66 Mg(HCO3)+ 0.18976E-12 -12.7218 0.15828E-12 -12.8006 0.83412E+00 -0.0788 67 MgCl+ 0.45723E-14 -14.3399 0.38138E-14 -14.4186 0.83412E+00 -0.0788 68 MgF+ 0.50979E-14 -14.2926 0.42522E-14 -14.3714 0.83412E+00 -0.0788 69 MgOH+ 0.51250E-10 -10.2903 0.42748E-10 -10.3691 0.83412E+00 -0.0788 71 MnF+ 0.25294E-14 -14.5970 0.21098E-14 -14.6758 0.83412E+00 -0.0788 72 MnO,aq 0.16944E-08 -8.7710 0.16944E-08 -8.7710 0.10000E+01 0.0000 73 MnOH+ 0.62606E-09 -9.2034 0.52220E-09 -9.2822 0.83412E+00 -0.0788 74 MnO2-2 0.98679E-11 -11.0058 0.50475E-11 -11.2969 0.51151E+00 -0.2911 75 HMnO2- 0.14021E-09 -9.8532 0.11672E-09 -9.9329 0.83246E+00 -0.0796 78 MnCl+ 0.30583E-13 -13.5145 0.25509E-13 -13.5933 0.83412E+00 -0.0788 79 MnSO4,aq 0.21856E-12 -12.6604 0.21856E-12 -12.6604 0.10000E+01 0.0000 80 NaCl,aq 0.12496E-05 -5.9032 0.12496E-05 -5.9032 0.10000E+01 0.0000 81 NaF,aq 0.26693E-07 -7.5736 0.26693E-07 -7.5736 0.10000E+01 0.0000 82 NaOH,aq 0.67537E-04 -4.1705 0.67537E-04 -4.1705 0.10000E+01 0.0000 84 OH- 0.65881E-02 -2.1812 0.54740E-02 -2.2617 0.83090E+00 -0.0805 89 HPO3-2 0.29248E-16 -16.5339 0.14961E-16 -16.8251 0.51151E+00 -0.2911 92 H3PO4,aq 0.18210E-17 -17.7397 0.18210E-17 -17.7397 0.10000E+01 0.0000 93 H2PO4- 0.54612E-10 -10.2627 0.45507E-10 -10.3419 0.83328E+00 -0.0792 94 PO4-3 0.76548E-09 -9.1161 0.18066E-09 -9.7431 0.23601E+00 -0.6271 98 HP2O7-3 0.13682E-17 -17.8638 0.30718E-18 -18.5126 0.22452E+00 -0.6488 99 P2O7-4 0.94945E-17 -17.0225 0.69527E-18 -18.1578 0.73229E-01 -1.1353 100 H2S,aq 0.12121E-06 -6.9165 0.12075E-06 -6.9181 0.99619E+00 -0.0017 101 S2-2 0.28895E-10 -10.5392 0.14780E-10 -10.8303 0.51151E+00 -0.2911 102 S3-2 0.22884E-16 -16.6405 0.11706E-16 -16.9316 0.51151E+00 -0.2911 107 SO3-2 0.21353E-11 -11.6705 0.11086E-11 -11.9552 0.51920E+00 -0.2847 108 HSO3- 0.88013E-14 -14.0555 0.73267E-14 -14.1351 0.83246E+00 -0.0796 109 HSO4- 0.50599E-11 -11.2959 0.42248E-11 -11.3742 0.83496E+00 -0.0783 111 S2O3-2 0.11517E-12 -12.9386 0.58912E-13 -13.2298 0.51151E+00 -0.2911 Charge balance for all species = -.6131E-08 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.1259994E-09 -.2007471E-01 -.2019748E+02 0.0000 2 H2O 0.1000000E+01 0.5550236E+02 0.9980821E+06 0.0000 3 Cl- 0.2730089E-03 0.2742590E-03 0.9705708E+01 6.3331 4 SO4-- 0.8102068E-04 0.8106621E-04 0.7773256E+01 15.5715 5 HCO3- 0.6361823E-03 0.1494564E-02 0.9102909E+02 6.7012 6 HS- 0.4445791E-03 0.4447563E-03 0.1468236E+02 6.5449 7 Al+++ 0.1531130E-28 0.1997130E-05 0.5378804E-01 0.4654 8 H4SiO4 0.9655053E-03 0.1351794E-01 0.1296931E+04 -3.0152 9 Ca++ 0.5330126E-07 0.2316242E-06 0.9266235E-02 12.3863 10 Mg++ 0.2259723E-10 0.9315046E-10 0.2260575E-05 9.0116 11 Fe++ 0.9426887E-13 0.2176561E-07 0.1213344E-02 6.6324 12 K+ 0.1565754E-03 0.1572054E-03 0.6135920E+01 6.0924 13 Na+ 0.1993428E-01 0.2229510E-01 0.5116322E+03 8.1964 14 Mn++ 0.3592903E-10 0.2506703E-08 0.1374640E-03 9.2138 15 F- 0.8272804E-05 0.8299505E-05 0.1573886E+00 4.8136 16 HPO4-- 0.4558433E-07 0.4640442E-07 0.4445789E-02 12.3218 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.1804640E-01 -.1803445E-01 -.1194695E-04 0.0000000E+00 2 H2O 0.4986146E+02 0.4986148E+02 -.1190784E-04 0.0000000E+00 3 Cl- 0.2463852E-03 0.2463852E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.7282719E-04 0.7282719E-04 0.0000000E+00 0.0000000E+00 5 HCO3- 0.1342667E-02 0.1342667E-02 0.0000000E+00 0.0000000E+00 6 HS- 0.3995543E-03 0.3995543E-03 0.0000000E+00 0.0000000E+00 7 Al+++ 0.4775352E-05 0.1794155E-05 0.2981197E-05 0.0000000E+00 8 H4SiO4 0.1215302E-01 0.1214407E-01 0.8948806E-05 0.0000000E+00 9 Ca++ 0.2080835E-06 0.2080835E-06 0.0000000E+00 0.0000000E+00 10 Mg++ 0.8368328E-10 0.8368328E-10 0.0000000E+00 0.0000000E+00 11 Fe++ 0.3259227E-07 0.1955350E-07 0.1303877E-07 0.0000000E+00 12 K+ 0.1412294E-03 0.1412281E-03 0.1303877E-08 0.0000000E+00 13 Na+ 0.2003215E-01 0.2002917E-01 0.2975981E-05 0.0000000E+00 14 Mn++ 0.2251939E-08 0.2251939E-08 0.0000000E+00 0.0000000E+00 15 F- 0.7456000E-05 0.7456000E-05 0.0000000E+00 0.0000000E+00 16 HPO4-- 0.4168819E-07 0.4168819E-07 0.0000000E+00 0.0000000E+00 Chg. balance for solid moles: 0.0000E+00 Mass of aqueous solution: 0.899996E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 0.0183900 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 0.2976E-05 -5.526 0.7804E-03 -3.108 99.64 0.2996E-03 stilpnomelane-Fe 0.2608E-08 -8.584 0.2811E-05 -5.551 0.3589 0.9710E-06 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 0.000783 g Volume = 0.000301 cm3 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.0183900 moles log = -1.7354 Original solution: 1000.0103000 g Original solution / Rock added: 54377.94 (Water/Rock Ratio), log = 4.7354 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0206 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9997E+00 0.9859 0.1006E+01 0.1020E+01 CO2,gas 0.1245E-04 1.0071 0.1280E-04 0.1271E-04 CH4,gas 0.6540E-05 1.0125 0.6759E-05 0.6675E-05 H2,gas 0.2641E-03 1.0005 0.2697E-03 0.2695E-03 H2S,gas 0.3265E-05 0.9960 0.3319E-05 0.3332E-05 S2,gas 0.5572E-23 1.0000 0.5687E-23 0.5687E-23 CO,gas 0.9013E-12 1.0000 0.9198E-12 0.9198E-12 SO3,gas 0.1714E-39 1.0000 0.1750E-39 0.1750E-39 SO2,gas 0.1799E-20 1.0000 0.1836E-20 0.1836E-20 HF,gas 0.1195E-13 1.0000 0.1219E-13 0.1219E-13 HCl,gas 0.7600E-17 1.0000 0.7756E-17 0.7756E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 17 albite -0.38 -0.38 0.00 0.000 -0.94784E-12 165 stilpnomelane-Fe 13.02 13.02 0.00 0.000 -0.27298E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -13.25 -6.59 -2.197 0.11255E+05 -4.893 3 CH4,gas 4.54 -2.33 -6.87 -1.717 0.11729E+05 -5.170 4 H2,gas 8.00 2.73 -5.27 -3.010 0.89952E+04 -3.569 5 H2S,gas -6.23 -13.41 -7.18 -3.589 0.12256E+05 -5.479 6 S2,gas -7.34 -32.28 -24.94 -3.838 0.42591E+05 -23.245 7 CO,gas 3.21 -10.52 -13.74 -4.226 0.23453E+05 -12.036 8 SO3,gas 17.12 -24.33 -41.46 -10.364 0.70785E+05 -39.757 9 SO2,gas 0.83 -21.60 -22.44 -5.983 0.38308E+05 -20.736 10 HF,gas 0.47 -15.14 -15.61 -7.806 0.26659E+05 -13.914 11 HCl,gas 5.19 -13.62 -18.81 -9.405 0.32116E+05 -17.110 12 acmite 7.71 7.43 -0.28 -0.029 0.47335E+03 16 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 20 spessartine 24.46 19.53 -4.93 -0.247 0.84191E+04 21 analcite 3.32 2.63 -0.69 -0.077 0.11790E+04 25 annite 20.12 17.41 -2.71 -0.151 0.46344E+04 26 phlogopite 27.06 24.55 -2.52 -0.140 0.42991E+04 31 apatite-OH -18.15 -20.82 -2.67 -0.205 0.45558E+04 32 apatite-F -34.30 -35.96 -1.66 -0.138 0.28346E+04 36 aragonite 0.97 -0.87 -1.83 -0.611 0.31283E+04 37 brucite 12.57 9.01 -3.56 -0.711 0.60735E+04 38 calcite 0.81 -0.87 -1.68 -0.559 0.28641E+04 39 carnegieite-low 9.02 5.65 -3.38 -0.482 0.57656E+04 40 carnegieite-high 10.09 5.65 -4.45 -0.635 0.75926E+04 41 carpholite-Mg 8.58 3.91 -4.67 -0.311 0.79741E+04 43 celadonite 5.34 3.51 -1.83 -0.108 0.31301E+04 44 celadonite-Fe 3.88 1.13 -2.75 -0.162 0.46909E+04 45 chrysotile 23.89 21.00 -2.89 -0.241 0.49315E+04 47 clinochlore 39.07 36.94 -2.13 -0.066 0.36310E+04 48 daphnite 28.97 25.05 -3.92 -0.122 0.66903E+04 52 chloritoid-Fe 9.17 4.55 -4.63 -0.308 0.78981E+04 53 chloritoid-Mn 11.40 7.13 -4.27 -0.285 0.72937E+04 55 coesite -2.38 -3.02 -0.64 -0.213 0.10914E+04 62 cristobalite -2.56 -3.02 -0.45 -0.152 0.77674E+03 64 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71258E+04 66 diaspore 2.87 0.47 -2.41 -0.401 0.41120E+04 67 diamond -3.10 -7.79 -4.69 -1.339 0.80017E+04 68 diopside 16.18 15.37 -0.81 -0.081 0.13898E+04 69 hedenbergite 14.21 12.99 -1.22 -0.122 0.20833E+04 76 epidote 24.67 21.92 -2.75 -0.133 0.46880E+04 78 epidote-Fe 29.84 26.73 -3.12 -0.162 0.53194E+04 79 fayalite 14.05 10.25 -3.80 -0.542 0.64820E+04 80 ferrosilite 11.15 7.23 -3.92 -0.392 0.66851E+04 84 gibbsite 4.08 0.47 -3.61 -0.516 0.61706E+04 85 glaucophane 22.97 20.24 -2.74 -0.074 0.46756E+04 86 glaucophane-Fe 17.28 13.10 -4.18 -0.113 0.71320E+04 87 graphite -3.55 -7.79 -4.24 -1.212 0.72440E+04 88 greenalite 16.14 13.87 -2.27 -0.189 0.38809E+04 91 hematite 12.57 10.53 -2.03 -0.246 0.34714E+04 92 heulandite -5.83 -7.79 -1.96 -0.089 0.33505E+04 96 jadeite 4.22 2.63 -1.58 -0.158 0.27045E+04 97 julgoldite 70.43 65.78 -4.64 -0.121 0.79264E+04 98 kalsilite 7.58 3.54 -4.04 -0.577 0.69004E+04 99 kaolinite -1.33 -5.10 -3.77 -0.342 0.64318E+04 102 laumontite 2.88 1.26 -1.63 -0.108 0.27784E+04 103 lawsonite 9.62 7.29 -2.33 -0.155 0.39773E+04 104 leucite 4.12 0.53 -3.59 -0.359 0.61324E+04 106 lizardite 23.24 21.00 -2.24 -0.187 0.38241E+04 107 magnesite 0.69 -4.24 -4.93 -1.644 0.84195E+04 108 magnetite 20.09 17.17 -2.92 -0.239 0.49891E+04 109 minnesotaite 10.39 7.84 -2.55 -0.150 0.43574E+04 113 manganosite 14.06 9.21 -4.84 -1.211 0.82715E+04 117 microcline -2.49 -2.49 0.00 0.000 0.23903E+01 121 muscovite 2.58 -1.56 -4.14 -0.243 0.70680E+04 122 paragonite 4.24 0.55 -3.69 -0.217 0.63047E+04 123 nepheline 8.34 5.65 -2.69 -0.385 0.45979E+04 129 periclase-Fe 11.63 6.63 -4.99 -1.249 0.85275E+04 135 phlogopite-Na 29.65 26.65 -3.00 -0.166 0.51155E+04 137 prehnite 19.37 16.66 -2.71 -0.160 0.46343E+04 138 prehnite-Fe 22.50 21.46 -1.04 -0.062 0.17740E+04 143 pyrite -21.25 -22.92 -1.67 -0.393 0.28492E+04 144 pyrrhotite -4.26 -6.78 -2.52 -0.838 0.42951E+04 145 pyrrhotiteFe0.875 -6.02 -7.94 -1.93 -0.709 0.32896E+04 146 pyroxmangite 7.40 6.20 -1.20 -0.240 0.20491E+04 147 pyrophyllite -6.18 -11.13 -4.95 -0.310 0.84593E+04 148 quartz -2.99 -3.02 -0.03 -0.009 0.44071E+02 152 rhodochrosite -0.98 -4.04 -3.06 -1.021 0.52279E+04 153 rhodonite 7.45 6.20 -1.25 -0.249 0.21294E+04 154 sanidine -1.28 -2.49 -1.21 -0.093 0.20701E+04 156 siderite -2.61 -6.62 -4.01 -1.337 0.68494E+04 164 stilbite -7.52 -7.79 -0.27 -0.013 0.45669E+03 166 stilpnomelane-Mg 27.44 24.91 -2.53 -0.075 0.43173E+04 172 talc 16.49 14.97 -1.52 -0.089 0.25909E+04 175 tephroite 18.09 15.41 -2.67 -0.382 0.45648E+04 179 tridymite -2.63 -3.02 -0.39 -0.130 0.66405E+03 180 tremolite 47.87 45.71 -2.16 -0.058 0.36895E+04 181 ferroactinolite 38.45 33.81 -4.64 -0.125 0.79224E+04 182 troilite-low -4.41 -6.78 -2.36 -0.788 0.40379E+04 188 wairakite 3.95 1.26 -2.69 -0.158 0.46004E+04 189 walstromite 11.51 9.37 -2.14 -0.428 0.36508E+04 190 wollastonite 10.46 9.37 -1.09 -0.218 0.18613E+04 191 pseudo-wollastonite 11.00 9.37 -1.63 -0.326 0.27811E+04 193 akaganeite 7.75 5.27 -2.49 -0.538 0.42482E+04 200 chalcedony -2.80 -3.02 -0.21 -0.071 0.36337E+03 202 montmorillonite-Ca -2.29 -6.27 -3.98 -0.246 0.67879E+04 203 montmorillonite-K -2.24 -6.30 -4.06 -0.249 0.69369E+04 204 montmorillonite-Mg -2.48 -6.82 -4.34 -0.269 0.74157E+04 205 montmorillonite-Na -2.04 -5.61 -3.57 -0.218 0.60910E+04 206 nontronite-Ca 3.21 1.66 -1.55 -0.101 0.26467E+04 207 nontronite-H 2.53 -0.38 -2.91 -0.195 0.49721E+04 208 nontronite-K 3.34 1.63 -1.71 -0.110 0.29188E+04 209 nontronite-Mg 3.07 1.11 -1.97 -0.128 0.33585E+04 210 nontronite-Na 3.52 2.33 -1.19 -0.077 0.20389E+04 226 tobermorite 9.82 7.30 -2.52 -0.688 0.43037E+04 232 alabandite -0.98 -4.19 -3.22 -1.072 0.54921E+04 235 boehmite 4.41 0.47 -3.94 -0.657 0.67290E+04 237 ferrous-oxide 9.81 6.63 -3.18 -0.795 0.54284E+04 243 silica-amorphous -2.09 -3.02 -0.92 -0.308 0.15775E+04 245 an20ab80 2.02 1.15 -0.87 -0.067 0.14813E+04 246 an25ab75 2.65 1.53 -1.11 -0.086 0.18986E+04 247 an30ab70 3.28 1.92 -1.36 -0.105 0.23255E+04 248 tr.625ac.25prg.125 45.16 43.56 -1.60 -0.043 0.27384E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 0.0004000 MOLES Current total amount of reactant added: 0.0183900 MOLES New total amount of reactant added: 0.0187900 MOLES Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.5508E-08 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 7 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 0.0187900 Water: Moles liquid = 0.4987E+02 kg liquid = 0.8984E+00 Moles total = 0.4986E+02 kg total = 0.8983E+00 Activity = 1.0000 Stoichiometric ionic strength = .1253593E-01 Osmotic coef. = 0.9404 True ionic strength = .2104955E-01 Chg. balance for total moles = -.5508E-08 Max. difference allowed = 0.2487E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.12708E-09 -9.8959 0.10645E-09 -9.9729 0.83764E+00 -0.0769 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.27562E-03 -3.5597 0.22943E-03 -3.6394 0.83241E+00 -0.0797 4 SO4-- 0.83143E-04 -4.0802 0.42612E-04 -4.3705 0.51251E+00 -0.2903 5 HCO3- 0.65297E-03 -3.1851 0.54437E-03 -3.2641 0.83367E+00 -0.0790 6 HS- 0.45327E-03 -3.3436 0.37736E-03 -3.4232 0.83253E+00 -0.0796 7 Al+++ 0.15481E-28 -28.8102 0.34701E-29 -29.4597 0.22415E+00 -0.6495 8 H4SiO4 0.97305E-03 -3.0119 0.97305E-03 -3.0119 0.10000E+01 0.0000 9 Ca++ 0.52748E-07 -7.2778 0.26828E-07 -7.5714 0.50860E+00 -0.2936 10 Mg++ 0.22637E-10 -10.6452 0.11458E-10 -10.9409 0.50618E+00 -0.2957 11 Fe++ 0.95363E-13 -13.0206 0.48326E-13 -13.3158 0.50676E+00 -0.2952 12 K+ 0.15658E-03 -3.8053 0.13057E-03 -3.8842 0.83388E+00 -0.0789 13 Na+ 0.19936E-01 -1.7004 0.16592E-01 -1.7801 0.83225E+00 -0.0797 14 Mn++ 0.36483E-10 -10.4379 0.18504E-10 -10.7327 0.50719E+00 -0.2948 15 F- 0.84503E-05 -5.0731 0.70190E-05 -5.1537 0.83062E+00 -0.0806 16 HPO4-- 0.45590E-07 -7.3411 0.23369E-07 -7.6314 0.51259E+00 -0.2902 18 HSiO3- 0.10254E-01 -1.9891 0.85356E-02 -2.0688 0.83241E+00 -0.0797 19 Ca(HSiO3)+ 0.62525E-08 -8.2039 0.52150E-08 -8.2827 0.83406E+00 -0.0788 20 Mg(HSiO3)+ 0.33235E-11 -11.4784 0.27720E-11 -11.5572 0.83406E+00 -0.0788 21 NaHSiO3,aq 0.22905E-02 -2.6401 0.22905E-02 -2.6401 0.10000E+01 0.0000 22 AlO+ 0.49953E-16 -16.3014 0.41664E-16 -16.3802 0.83406E+00 -0.0788 24 HAlO2,aq 0.77949E-10 -10.1082 0.77949E-10 -10.1082 0.10000E+01 0.0000 25 AlO2- 0.19510E-05 -5.7097 0.16210E-05 -5.7902 0.83084E+00 -0.0805 26 CH4,aq 0.47007E-08 -8.3278 0.46828E-08 -8.3295 0.99618E+00 -0.0017 27 C2H6,aq 0.18388E-19 -19.7355 0.18318E-19 -19.7371 0.99618E+00 -0.0017 31 CO,aq 0.63653E-15 -15.1962 0.63653E-15 -15.1962 0.10000E+01 0.0000 32 CO2,aq 0.12429E-06 -6.9056 0.12382E-06 -6.9072 0.99618E+00 -0.0017 33 CO3-2 0.87349E-03 -3.0587 0.44669E-03 -3.3500 0.51138E+00 -0.2913 34 CaCO3,aq 0.15026E-06 -6.8232 0.15026E-06 -6.8232 0.10000E+01 0.0000 35 Ca(HCO3)+ 0.44695E-09 -9.3497 0.37278E-09 -9.4285 0.83406E+00 -0.0788 36 CaCl+ 0.11942E-10 -10.9229 0.99608E-11 -11.0017 0.83406E+00 -0.0788 37 CaCl2,aq 0.54294E-15 -15.2652 0.54294E-15 -15.2652 0.10000E+01 0.0000 38 CaF+ 0.32962E-11 -11.4820 0.27492E-11 -11.5608 0.83406E+00 -0.0788 39 CaOH+ 0.21536E-07 -7.6668 0.17962E-07 -7.7456 0.83406E+00 -0.0788 40 CaSO4,aq 0.36301E-09 -9.4401 0.36301E-09 -9.4401 0.10000E+01 0.0000 41 HCl,aq 0.44752E-14 -14.3492 0.44752E-14 -14.3492 0.10000E+01 0.0000 45 HF,aq 0.51147E-11 -11.2912 0.51147E-11 -11.2912 0.10000E+01 0.0000 46 HF2- 0.14561E-16 -16.8368 0.12121E-16 -16.9165 0.83241E+00 -0.0797 48 FeCl+ 0.21041E-16 -16.6769 0.17549E-16 -16.7557 0.83406E+00 -0.0788 51 FeF+ 0.20782E-16 -16.6823 0.17334E-16 -16.7611 0.83406E+00 -0.0788 53 FeO,aq 0.16576E-09 -9.7805 0.16576E-09 -9.7805 0.10000E+01 0.0000 54 FeOH+ 0.17718E-10 -10.7516 0.14778E-10 -10.8304 0.83406E+00 -0.0788 55 HFeO2- 0.19574E-07 -7.7083 0.16294E-07 -7.7880 0.83241E+00 -0.0797 56 FeO+ 0.93419E-16 -16.0296 0.77918E-16 -16.1084 0.83406E+00 -0.0788 58 FeO2- 0.16904E-08 -8.7720 0.14071E-08 -8.8517 0.83241E+00 -0.0797 59 HFeO2,aq 0.19050E-10 -10.7201 0.19050E-10 -10.7201 0.10000E+01 0.0000 60 H2,aq 0.20543E-06 -6.6873 0.20465E-06 -6.6890 0.99618E+00 -0.0017 61 KCl,aq 0.54292E-09 -9.2653 0.54292E-09 -9.2653 0.10000E+01 0.0000 62 KHSO4,aq 0.16745E-17 -17.7761 0.16745E-17 -17.7761 0.10000E+01 0.0000 63 KOH,aq 0.52382E-06 -6.2808 0.52382E-06 -6.2808 0.10000E+01 0.0000 64 KSO4- 0.10372E-06 -6.9841 0.86335E-07 -7.0638 0.83241E+00 -0.0797 65 MgCO3,aq 0.16087E-10 -10.7935 0.16087E-10 -10.7935 0.10000E+01 0.0000 66 Mg(HCO3)+ 0.19506E-12 -12.7098 0.16269E-12 -12.7886 0.83406E+00 -0.0788 67 MgCl+ 0.46230E-14 -14.3351 0.38559E-14 -14.4139 0.83406E+00 -0.0788 68 MgF+ 0.52151E-14 -14.2827 0.43497E-14 -14.3615 0.83406E+00 -0.0788 69 MgOH+ 0.50898E-10 -10.2933 0.42452E-10 -10.3721 0.83406E+00 -0.0788 71 MnF+ 0.26229E-14 -14.5812 0.21877E-14 -14.6600 0.83406E+00 -0.0788 72 MnO,aq 0.16912E-08 -8.7718 0.16912E-08 -8.7718 0.10000E+01 0.0000 73 MnOH+ 0.63024E-09 -9.2005 0.52566E-09 -9.2793 0.83406E+00 -0.0788 74 MnO2-2 0.96866E-11 -11.0138 0.49536E-11 -11.3051 0.51138E+00 -0.2913 75 HMnO2- 0.13878E-09 -9.8577 0.11552E-09 -9.9373 0.83241E+00 -0.0797 78 MnCl+ 0.31344E-13 -13.5038 0.26143E-13 -13.5826 0.83406E+00 -0.0788 79 MnSO4,aq 0.22763E-12 -12.6428 0.22763E-12 -12.6428 0.10000E+01 0.0000 80 NaCl,aq 0.12615E-05 -5.8991 0.12615E-05 -5.8991 0.10000E+01 0.0000 81 NaF,aq 0.27265E-07 -7.5644 0.27265E-07 -7.5644 0.10000E+01 0.0000 82 NaOH,aq 0.66970E-04 -4.1741 0.66970E-04 -4.1741 0.10000E+01 0.0000 84 OH- 0.65329E-02 -2.1849 0.54279E-02 -2.2654 0.83084E+00 -0.0805 89 HPO3-2 0.29143E-16 -16.5355 0.14903E-16 -16.8267 0.51138E+00 -0.2913 92 H3PO4,aq 0.18519E-17 -17.7324 0.18519E-17 -17.7324 0.10000E+01 0.0000 93 H2PO4- 0.55072E-10 -10.2591 0.45888E-10 -10.3383 0.83323E+00 -0.0792 94 PO4-3 0.75932E-09 -9.1196 0.17912E-09 -9.7469 0.23589E+00 -0.6273 98 HP2O7-3 0.13803E-17 -17.8600 0.30972E-18 -18.5090 0.22439E+00 -0.6490 99 P2O7-4 0.95013E-17 -17.0222 0.69510E-18 -18.1580 0.73158E-01 -1.1357 100 H2S,aq 0.12462E-06 -6.9044 0.12415E-06 -6.9061 0.99618E+00 -0.0017 101 S2-2 0.30150E-10 -10.5207 0.15418E-10 -10.8120 0.51138E+00 -0.2913 102 S3-2 0.24641E-16 -16.6083 0.12601E-16 -16.8996 0.51138E+00 -0.2913 107 SO3-2 0.21831E-11 -11.6609 0.11332E-11 -11.9457 0.51908E+00 -0.2848 108 HSO3- 0.90734E-14 -14.0422 0.75527E-14 -14.1219 0.83241E+00 -0.0797 109 HSO4- 0.52357E-11 -11.2810 0.43713E-11 -11.3594 0.83491E+00 -0.0784 111 S2O3-2 0.12152E-12 -12.9154 0.62142E-13 -13.2066 0.51138E+00 -0.2913 Charge balance for all species = -.6131E-08 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.1270776E-09 -.2002643E-01 -.2014888E+02 0.0000 2 H2O 0.1000000E+01 0.5550231E+02 0.9980795E+06 0.0000 3 Cl- 0.2756219E-03 0.2768839E-03 0.9798585E+01 6.3335 4 SO4-- 0.8314342E-04 0.8319167E-04 0.7977049E+01 15.5753 5 HCO3- 0.6529724E-03 0.1526745E-02 0.9298894E+02 6.7088 6 HS- 0.4532659E-03 0.4534465E-03 0.1496922E+02 6.5496 7 Al+++ 0.1548097E-28 0.1951081E-05 0.5254773E-01 0.4590 8 H4SiO4 0.9730531E-03 0.1351770E-01 0.1296906E+04 -3.0119 9 Ca++ 0.5274813E-07 0.2316225E-06 0.9266150E-02 12.3743 10 Mg++ 0.2263702E-10 0.9314977E-10 0.2260555E-05 9.0049 11 Fe++ 0.9536318E-13 0.2146720E-07 0.1196707E-02 6.6299 12 K+ 0.1565761E-03 0.1572042E-03 0.6135863E+01 6.0887 13 Na+ 0.1993610E-01 0.2229488E-01 0.5116265E+03 8.1928 14 Mn++ 0.3648349E-10 0.2506685E-08 0.1374628E-03 9.2130 15 F- 0.8450270E-05 0.8477543E-05 0.1607646E+00 4.8191 16 HPO4-- 0.4558968E-07 0.4640407E-07 0.4445749E-02 12.3144 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.1800333E-01 -.1799121E-01 -.1211283E-04 0.0000000E+00 2 H2O 0.4986179E+02 0.4986180E+02 -.1207291E-04 0.0000000E+00 3 Cl- 0.2487452E-03 0.2487452E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.7473719E-04 0.7473719E-04 0.0000000E+00 0.0000000E+00 5 HCO3- 0.1371587E-02 0.1371587E-02 0.0000000E+00 0.0000000E+00 6 HS- 0.4073643E-03 0.4073643E-03 0.0000000E+00 0.0000000E+00 7 Al+++ 0.4775352E-05 0.1752799E-05 0.3022553E-05 0.0000000E+00 8 H4SiO4 0.1215302E-01 0.1214395E-01 0.9072980E-05 0.0000000E+00 9 Ca++ 0.2080835E-06 0.2080835E-06 0.0000000E+00 0.0000000E+00 10 Mg++ 0.8368328E-10 0.8368328E-10 0.0000000E+00 0.0000000E+00 11 Fe++ 0.3259227E-07 0.1928556E-07 0.1330671E-07 0.0000000E+00 12 K+ 0.1412294E-03 0.1412281E-03 0.1330671E-08 0.0000000E+00 13 Na+ 0.2003215E-01 0.2002913E-01 0.3017230E-05 0.0000000E+00 14 Mn++ 0.2251939E-08 0.2251939E-08 0.0000000E+00 0.0000000E+00 15 F- 0.7616000E-05 0.7616000E-05 0.0000000E+00 0.0000000E+00 16 HPO4-- 0.4168819E-07 0.4168819E-07 0.0000000E+00 0.0000000E+00 Chg. balance for solid moles: 0.1271E-20 Mass of aqueous solution: 0.900004E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 0.0187900 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 0.3017E-05 -5.520 0.7912E-03 -3.102 99.64 0.3037E-03 stilpnomelane-Fe 0.2661E-08 -8.575 0.2869E-05 -5.542 0.3613 0.9910E-06 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 0.000794 g Volume = 0.000305 cm3 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.0187900 moles log = -1.7261 Original solution: 1000.0103000 g Original solution / Rock added: 53220.35 (Water/Rock Ratio), log = 4.7261 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0206 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9997E+00 0.9859 0.1006E+01 0.1020E+01 CO2,gas 0.1289E-04 1.0071 0.1325E-04 0.1315E-04 CH4,gas 0.6670E-05 1.0125 0.6893E-05 0.6807E-05 H2,gas 0.2631E-03 1.0005 0.2687E-03 0.2685E-03 H2S,gas 0.3357E-05 0.9960 0.3413E-05 0.3426E-05 S2,gas 0.5934E-23 1.0000 0.6056E-23 0.6056E-23 CO,gas 0.9294E-12 1.0000 0.9485E-12 0.9485E-12 SO3,gas 0.1789E-39 1.0000 0.1826E-39 0.1826E-39 SO2,gas 0.1870E-20 1.0000 0.1908E-20 0.1908E-20 HF,gas 0.1231E-13 1.0000 0.1256E-13 0.1256E-13 HCl,gas 0.7737E-17 1.0000 0.7897E-17 0.7897E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 17 albite -0.38 -0.38 0.00 0.000 -0.13080E-10 165 stilpnomelane-Fe 13.02 13.02 0.00 0.000 -0.75827E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -13.24 -6.58 -2.192 0.11230E+05 -4.878 3 CH4,gas 4.54 -2.32 -6.86 -1.715 0.11714E+05 -5.162 4 H2,gas 8.00 2.73 -5.27 -3.011 0.89979E+04 -3.571 5 H2S,gas -6.23 -13.40 -7.17 -3.583 0.12236E+05 -5.467 6 S2,gas -7.34 -32.25 -24.92 -3.833 0.42545E+05 -23.218 7 CO,gas 3.21 -10.51 -13.72 -4.222 0.23430E+05 -12.023 8 SO3,gas 17.12 -24.32 -41.44 -10.359 0.70754E+05 -39.739 9 SO2,gas 0.83 -21.59 -22.42 -5.978 0.38279E+05 -20.719 10 HF,gas 0.47 -15.13 -15.60 -7.800 0.26637E+05 -13.901 11 HCl,gas 5.19 -13.61 -18.80 -9.401 0.32103E+05 -17.103 12 acmite 7.71 7.43 -0.28 -0.029 0.47086E+03 16 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 20 spessartine 24.46 19.52 -4.94 -0.247 0.84280E+04 21 analcite 3.32 2.63 -0.69 -0.077 0.11848E+04 25 annite 20.12 17.40 -2.72 -0.151 0.46470E+04 26 phlogopite 27.06 24.53 -2.54 -0.141 0.43334E+04 31 apatite-OH -18.15 -20.86 -2.71 -0.208 0.46208E+04 32 apatite-F -34.30 -35.99 -1.69 -0.140 0.28776E+04 36 aragonite 0.97 -0.86 -1.83 -0.610 0.31233E+04 37 brucite 12.57 9.00 -3.56 -0.713 0.60849E+04 38 calcite 0.81 -0.86 -1.67 -0.558 0.28590E+04 39 carnegieite-low 9.02 5.64 -3.38 -0.483 0.57771E+04 40 carnegieite-high 10.09 5.64 -4.45 -0.636 0.76041E+04 41 carpholite-Mg 8.58 3.90 -4.68 -0.312 0.79962E+04 43 celadonite 5.34 3.51 -1.84 -0.108 0.31358E+04 44 celadonite-Fe 3.88 1.13 -2.75 -0.162 0.46894E+04 45 chrysotile 23.89 20.99 -2.90 -0.242 0.49543E+04 47 clinochlore 39.07 36.91 -2.16 -0.068 0.36930E+04 48 daphnite 28.97 25.03 -3.93 -0.123 0.67160E+04 52 chloritoid-Fe 9.17 4.54 -4.64 -0.309 0.79187E+04 53 chloritoid-Mn 11.40 7.12 -4.28 -0.285 0.73114E+04 55 coesite -2.38 -3.01 -0.64 -0.212 0.10856E+04 62 cristobalite -2.56 -3.01 -0.45 -0.151 0.77097E+03 64 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71258E+04 66 diaspore 2.87 0.46 -2.41 -0.402 0.41231E+04 67 diamond -3.10 -7.78 -4.67 -1.336 0.79817E+04 68 diopside 16.18 15.36 -0.83 -0.083 0.14102E+04 69 hedenbergite 14.21 12.98 -1.23 -0.123 0.20964E+04 76 epidote 24.67 21.90 -2.77 -0.134 0.47366E+04 78 epidote-Fe 29.84 26.70 -3.14 -0.163 0.53597E+04 79 fayalite 14.05 10.25 -3.80 -0.543 0.64846E+04 80 ferrosilite 11.15 7.24 -3.91 -0.391 0.66819E+04 84 gibbsite 4.08 0.46 -3.62 -0.517 0.61816E+04 85 glaucophane 22.97 20.22 -2.75 -0.074 0.46984E+04 86 glaucophane-Fe 17.28 13.10 -4.18 -0.113 0.71330E+04 87 graphite -3.55 -7.78 -4.23 -1.209 0.72239E+04 88 greenalite 16.14 13.87 -2.27 -0.189 0.38819E+04 91 hematite 12.57 10.53 -2.04 -0.247 0.34770E+04 92 heulandite -5.83 -7.79 -1.96 -0.089 0.33527E+04 96 jadeite 4.22 2.63 -1.59 -0.159 0.27102E+04 97 julgoldite 70.43 65.75 -4.68 -0.122 0.79932E+04 98 kalsilite 7.58 3.54 -4.05 -0.578 0.69120E+04 99 kaolinite -1.33 -5.11 -3.77 -0.343 0.64424E+04 102 laumontite 2.88 1.24 -1.64 -0.109 0.27979E+04 103 lawsonite 9.62 7.27 -2.35 -0.157 0.40084E+04 104 leucite 4.12 0.52 -3.59 -0.359 0.61382E+04 106 lizardite 23.24 20.99 -2.25 -0.188 0.38469E+04 107 magnesite 0.69 -4.23 -4.92 -1.641 0.84054E+04 108 magnetite 20.09 17.16 -2.93 -0.239 0.49989E+04 109 minnesotaite 10.39 7.84 -2.55 -0.150 0.43469E+04 113 manganosite 14.06 9.21 -4.85 -1.211 0.82729E+04 117 microcline -2.49 -2.49 0.00 0.000 0.24541E+01 121 muscovite 2.58 -1.57 -4.15 -0.244 0.70902E+04 122 paragonite 4.24 0.53 -3.71 -0.218 0.63268E+04 123 nepheline 8.34 5.64 -2.70 -0.386 0.46095E+04 129 periclase-Fe 11.63 6.63 -5.00 -1.249 0.85317E+04 135 phlogopite-Na 29.65 26.63 -3.02 -0.168 0.51498E+04 137 prehnite 19.37 16.63 -2.74 -0.161 0.46800E+04 138 prehnite-Fe 22.50 21.44 -1.06 -0.064 0.18115E+04 143 pyrite -21.25 -22.89 -1.65 -0.387 0.28095E+04 144 pyrrhotite -4.26 -6.77 -2.51 -0.835 0.42787E+04 145 pyrrhotiteFe0.875 -6.02 -7.93 -1.92 -0.705 0.32724E+04 146 pyroxmangite 7.40 6.20 -1.20 -0.240 0.20448E+04 147 pyrophyllite -6.18 -11.13 -4.95 -0.310 0.84584E+04 148 quartz -2.99 -3.01 -0.02 -0.007 0.38296E+02 152 rhodochrosite -0.98 -4.02 -3.05 -1.016 0.52038E+04 153 rhodonite 7.45 6.20 -1.24 -0.249 0.21250E+04 154 sanidine -1.28 -2.49 -1.21 -0.093 0.20702E+04 156 siderite -2.61 -6.61 -4.00 -1.333 0.68280E+04 164 stilbite -7.52 -7.79 -0.27 -0.013 0.45888E+03 166 stilpnomelane-Mg 27.44 24.89 -2.55 -0.076 0.43536E+04 172 talc 16.49 14.97 -1.52 -0.090 0.26021E+04 175 tephroite 18.09 15.41 -2.67 -0.382 0.45617E+04 179 tridymite -2.63 -3.01 -0.39 -0.129 0.65827E+03 180 tremolite 47.87 45.68 -2.19 -0.059 0.37414E+04 181 ferroactinolite 38.45 33.80 -4.65 -0.126 0.79381E+04 182 troilite-low -4.41 -6.77 -2.36 -0.785 0.40215E+04 188 wairakite 3.95 1.24 -2.71 -0.159 0.46199E+04 189 walstromite 11.51 9.36 -2.15 -0.429 0.36655E+04 190 wollastonite 10.46 9.36 -1.10 -0.220 0.18760E+04 191 pseudo-wollastonite 11.00 9.36 -1.64 -0.327 0.27958E+04 193 akaganeite 7.75 5.26 -2.49 -0.538 0.42510E+04 200 chalcedony -2.80 -3.01 -0.21 -0.070 0.35759E+03 202 montmorillonite-Ca -2.29 -6.27 -3.98 -0.246 0.67905E+04 203 montmorillonite-K -2.24 -6.30 -4.06 -0.249 0.69381E+04 204 montmorillonite-Mg -2.48 -6.82 -4.34 -0.269 0.74168E+04 205 montmorillonite-Na -2.04 -5.61 -3.57 -0.218 0.60922E+04 206 nontronite-Ca 3.21 1.67 -1.55 -0.100 0.26381E+04 207 nontronite-H 2.53 -0.37 -2.90 -0.195 0.49601E+04 208 nontronite-K 3.34 1.64 -1.70 -0.109 0.29090E+04 209 nontronite-Mg 3.07 1.11 -1.96 -0.127 0.33485E+04 210 nontronite-Na 3.52 2.33 -1.19 -0.076 0.20291E+04 226 tobermorite 9.82 7.30 -2.53 -0.690 0.43150E+04 232 alabandite -0.98 -4.18 -3.21 -1.068 0.54729E+04 235 boehmite 4.41 0.46 -3.95 -0.658 0.67400E+04 237 ferrous-oxide 9.81 6.63 -3.18 -0.795 0.54326E+04 243 silica-amorphous -2.09 -3.01 -0.92 -0.307 0.15718E+04 245 an20ab80 2.02 1.15 -0.87 -0.067 0.14875E+04 246 an25ab75 2.65 1.53 -1.12 -0.086 0.19063E+04 247 an30ab70 3.28 1.91 -1.37 -0.105 0.23348E+04 248 tr.625ac.25prg.125 45.16 43.53 -1.63 -0.044 0.27862E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 0.0004000 MOLES Current total amount of reactant added: 0.0187900 MOLES New total amount of reactant added: 0.0191900 MOLES Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.5508E-08 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 7 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 0.0191900 Water: Moles liquid = 0.4987E+02 kg liquid = 0.8984E+00 Moles total = 0.4986E+02 kg total = 0.8983E+00 Activity = 1.0000 Stoichiometric ionic strength = .1256172E-01 Osmotic coef. = 0.9401 True ionic strength = .2106875E-01 Chg. balance for total moles = -.5508E-08 Max. difference allowed = 0.2511E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.12817E-09 -9.8922 0.10735E-09 -9.9692 0.83760E+00 -0.0770 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.27823E-03 -3.5556 0.23159E-03 -3.6353 0.83236E+00 -0.0797 4 SO4-- 0.85266E-04 -4.0692 0.43690E-04 -4.3596 0.51239E+00 -0.2904 5 HCO3- 0.66991E-03 -3.1740 0.55845E-03 -3.2530 0.83362E+00 -0.0790 6 HS- 0.46195E-03 -3.3354 0.38457E-03 -3.4150 0.83248E+00 -0.0796 7 Al+++ 0.15653E-28 -28.8054 0.35068E-29 -29.4551 0.22403E+00 -0.6497 8 H4SiO4 0.98069E-03 -3.0085 0.98069E-03 -3.0085 0.10000E+01 0.0000 9 Ca++ 0.52212E-07 -7.2822 0.26549E-07 -7.5760 0.50847E+00 -0.2937 10 Mg++ 0.22677E-10 -10.6444 0.11476E-10 -10.9402 0.50605E+00 -0.2958 11 Fe++ 0.96475E-13 -13.0156 0.48877E-13 -13.3109 0.50663E+00 -0.2953 12 K+ 0.15658E-03 -3.8053 0.13056E-03 -3.8842 0.83383E+00 -0.0789 13 Na+ 0.19938E-01 -1.7003 0.16592E-01 -1.7801 0.83220E+00 -0.0798 14 Mn++ 0.37048E-10 -10.4312 0.18786E-10 -10.7262 0.50707E+00 -0.2949 15 F- 0.86277E-05 -5.0641 0.71660E-05 -5.1447 0.83057E+00 -0.0806 16 HPO4-- 0.45595E-07 -7.3411 0.23366E-07 -7.6314 0.51247E+00 -0.2903 18 HSiO3- 0.10248E-01 -1.9894 0.85298E-02 -2.0691 0.83236E+00 -0.0797 19 Ca(HSiO3)+ 0.61836E-08 -8.2088 0.51572E-08 -8.2876 0.83401E+00 -0.0788 20 Mg(HSiO3)+ 0.33265E-11 -11.4780 0.27743E-11 -11.5568 0.83401E+00 -0.0788 21 NaHSiO3,aq 0.22890E-02 -2.6403 0.22890E-02 -2.6403 0.10000E+01 0.0000 22 AlO+ 0.49634E-16 -16.3042 0.41395E-16 -16.3831 0.83401E+00 -0.0788 24 HAlO2,aq 0.76790E-10 -10.1147 0.76790E-10 -10.1147 0.10000E+01 0.0000 25 AlO2- 0.19059E-05 -5.7199 0.15834E-05 -5.8004 0.83079E+00 -0.0805 26 CH4,aq 0.47933E-08 -8.3194 0.47750E-08 -8.3210 0.99618E+00 -0.0017 27 C2H6,aq 0.19189E-19 -19.7169 0.19116E-19 -19.7186 0.99618E+00 -0.0017 31 CO,aq 0.65618E-15 -15.1830 0.65618E-15 -15.1830 0.10000E+01 0.0000 32 CO2,aq 0.12860E-06 -6.8908 0.12810E-06 -6.8924 0.99618E+00 -0.0017 33 CO3-2 0.88873E-03 -3.0512 0.45437E-03 -3.3426 0.51126E+00 -0.2914 34 CaCO3,aq 0.15126E-06 -6.8203 0.15126E-06 -6.8203 0.10000E+01 0.0000 35 Ca(HCO3)+ 0.45377E-09 -9.3432 0.37845E-09 -9.4220 0.83401E+00 -0.0788 36 CaCl+ 0.11930E-10 -10.9233 0.99500E-11 -11.0022 0.83401E+00 -0.0788 37 CaCl2,aq 0.54746E-15 -15.2616 0.54746E-15 -15.2616 0.10000E+01 0.0000 38 CaF+ 0.33304E-11 -11.4775 0.27776E-11 -11.5563 0.83401E+00 -0.0788 39 CaOH+ 0.21132E-07 -7.6750 0.17625E-07 -7.7539 0.83401E+00 -0.0788 40 CaSO4,aq 0.36832E-09 -9.4338 0.36832E-09 -9.4338 0.10000E+01 0.0000 41 HCl,aq 0.45559E-14 -14.3414 0.45559E-14 -14.3414 0.10000E+01 0.0000 45 HF,aq 0.52664E-11 -11.2785 0.52664E-11 -11.2785 0.10000E+01 0.0000 46 HF2- 0.15308E-16 -16.8151 0.12742E-16 -16.8948 0.83236E+00 -0.0797 48 FeCl+ 0.21483E-16 -16.6679 0.17917E-16 -16.7467 0.83401E+00 -0.0788 51 FeF+ 0.21460E-16 -16.6684 0.17898E-16 -16.7472 0.83401E+00 -0.0788 53 FeO,aq 0.16483E-09 -9.7830 0.16483E-09 -9.7830 0.10000E+01 0.0000 54 FeOH+ 0.17769E-10 -10.7503 0.14820E-10 -10.8292 0.83401E+00 -0.0788 55 HFeO2- 0.19300E-07 -7.7144 0.16065E-07 -7.7941 0.83236E+00 -0.0797 56 FeO+ 0.93861E-16 -16.0275 0.78282E-16 -16.1063 0.83401E+00 -0.0788 58 FeO2- 0.16698E-08 -8.7773 0.13899E-08 -8.8570 0.83236E+00 -0.0797 59 HFeO2,aq 0.18977E-10 -10.7218 0.18977E-10 -10.7218 0.10000E+01 0.0000 60 H2,aq 0.20469E-06 -6.6889 0.20390E-06 -6.6906 0.99618E+00 -0.0017 61 KCl,aq 0.54800E-09 -9.2612 0.54800E-09 -9.2612 0.10000E+01 0.0000 62 KHSO4,aq 0.17314E-17 -17.7616 0.17314E-17 -17.7616 0.10000E+01 0.0000 63 KOH,aq 0.51936E-06 -6.2845 0.51936E-06 -6.2845 0.10000E+01 0.0000 64 KSO4- 0.10634E-06 -6.9733 0.88513E-07 -7.0530 0.83236E+00 -0.0797 65 MgCO3,aq 0.16388E-10 -10.7855 0.16388E-10 -10.7855 0.10000E+01 0.0000 66 Mg(HCO3)+ 0.20042E-12 -12.6980 0.16716E-12 -12.7769 0.83401E+00 -0.0788 67 MgCl+ 0.46740E-14 -14.3303 0.38982E-14 -14.4091 0.83401E+00 -0.0788 68 MgF+ 0.53327E-14 -14.2731 0.44475E-14 -14.3519 0.83401E+00 -0.0788 69 MgOH+ 0.50547E-10 -10.2963 0.42157E-10 -10.3751 0.83401E+00 -0.0788 71 MnF+ 0.27187E-14 -14.5656 0.22674E-14 -14.6445 0.83401E+00 -0.0788 72 MnO,aq 0.16880E-08 -8.7726 0.16880E-08 -8.7726 0.10000E+01 0.0000 73 MnOH+ 0.63445E-09 -9.1976 0.52914E-09 -9.2764 0.83401E+00 -0.0788 74 MnO2-2 0.95076E-11 -11.0219 0.48609E-11 -11.3133 0.51126E+00 -0.2914 75 HMnO2- 0.13735E-09 -9.8622 0.11433E-09 -9.9419 0.83236E+00 -0.0797 78 MnCl+ 0.32123E-13 -13.4932 0.26791E-13 -13.5720 0.83401E+00 -0.0788 79 MnSO4,aq 0.23694E-12 -12.6254 0.23694E-12 -12.6254 0.10000E+01 0.0000 80 NaCl,aq 0.12735E-05 -5.8950 0.12735E-05 -5.8950 0.10000E+01 0.0000 81 NaF,aq 0.27837E-07 -7.5554 0.27837E-07 -7.5554 0.10000E+01 0.0000 82 NaOH,aq 0.66405E-04 -4.1778 0.66405E-04 -4.1778 0.10000E+01 0.0000 84 OH- 0.64781E-02 -2.1886 0.53819E-02 -2.2691 0.83079E+00 -0.0805 89 HPO3-2 0.29041E-16 -16.5370 0.14848E-16 -16.8283 0.51126E+00 -0.2914 92 H3PO4,aq 0.18834E-17 -17.7251 0.18834E-17 -17.7251 0.10000E+01 0.0000 93 H2PO4- 0.55539E-10 -10.2554 0.46274E-10 -10.3347 0.83318E+00 -0.0793 94 PO4-3 0.75319E-09 -9.1231 0.17758E-09 -9.7506 0.23577E+00 -0.6275 98 HP2O7-3 0.13925E-17 -17.8562 0.31228E-18 -18.5055 0.22427E+00 -0.6492 99 P2O7-4 0.95081E-17 -17.0219 0.69493E-18 -18.1581 0.73088E-01 -1.1362 100 H2S,aq 0.12809E-06 -6.8925 0.12760E-06 -6.8942 0.99618E+00 -0.0017 101 S2-2 0.31435E-10 -10.5026 0.16071E-10 -10.7940 0.51126E+00 -0.2914 102 S3-2 0.26502E-16 -16.5767 0.13549E-16 -16.8681 0.51126E+00 -0.2914 107 SO3-2 0.22307E-11 -11.6516 0.11577E-11 -11.9364 0.51896E+00 -0.2849 108 HSO3- 0.93487E-14 -14.0292 0.77814E-14 -14.1089 0.83236E+00 -0.0797 109 HSO4- 0.54142E-11 -11.2665 0.45201E-11 -11.3449 0.83486E+00 -0.0784 111 S2O3-2 0.12808E-12 -12.8925 0.65484E-13 -13.1839 0.51126E+00 -0.2914 Charge balance for all species = -.6131E-08 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.1281694E-09 -.1997816E-01 -.2010027E+02 0.0000 2 H2O 0.1000000E+01 0.5550226E+02 0.9980770E+06 0.0000 3 Cl- 0.2782348E-03 0.2795088E-03 0.9891460E+01 6.3339 4 SO4-- 0.8526613E-04 0.8531710E-04 0.8180837E+01 15.5787 5 HCO3- 0.6699104E-03 0.1558925E-02 0.9494875E+02 6.7162 6 HS- 0.4619526E-03 0.4621365E-03 0.1525607E+02 6.5542 7 Al+++ 0.1565331E-28 0.1905930E-05 0.5133161E-01 0.4525 8 H4SiO4 0.9806876E-03 0.1351747E-01 0.1296881E+04 -3.0085 9 Ca++ 0.5221228E-07 0.2316208E-06 0.9266066E-02 12.3624 10 Mg++ 0.2267714E-10 0.9314907E-10 0.2260534E-05 8.9981 11 Fe++ 0.9647471E-13 0.2117165E-07 0.1180229E-02 6.6275 12 K+ 0.1565767E-03 0.1572030E-03 0.6135806E+01 6.0850 13 Na+ 0.1993794E-01 0.2229467E-01 0.5116207E+03 8.1891 14 Mn++ 0.3704787E-10 0.2506666E-08 0.1374615E-03 9.2122 15 F- 0.8627733E-05 0.8655578E-05 0.1641405E+00 4.8245 16 HPO4-- 0.4559500E-07 0.4640373E-07 0.4445708E-02 12.3069 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.1796026E-01 -.1794798E-01 -.1227548E-04 0.0000000E+00 2 H2O 0.4986212E+02 0.4986213E+02 -.1223477E-04 0.0000000E+00 3 Cl- 0.2511052E-03 0.2511052E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.7664719E-04 0.7664719E-04 0.0000000E+00 0.0000000E+00 5 HCO3- 0.1400507E-02 0.1400507E-02 0.0000000E+00 0.0000000E+00 6 HS- 0.4151743E-03 0.4151743E-03 0.0000000E+00 0.0000000E+00 7 Al+++ 0.4775352E-05 0.1712250E-05 0.3063102E-05 0.0000000E+00 8 H4SiO4 0.1215302E-01 0.1214383E-01 0.9194736E-05 0.0000000E+00 9 Ca++ 0.2080835E-06 0.2080835E-06 0.0000000E+00 0.0000000E+00 10 Mg++ 0.8368328E-10 0.8368328E-10 0.0000000E+00 0.0000000E+00 11 Fe++ 0.3259227E-07 0.1902019E-07 0.1357208E-07 0.0000000E+00 12 K+ 0.1412294E-03 0.1412280E-03 0.1357208E-08 0.0000000E+00 13 Na+ 0.2003215E-01 0.2002909E-01 0.3057673E-05 0.0000000E+00 14 Mn++ 0.2251939E-08 0.2251939E-08 0.0000000E+00 0.0000000E+00 15 F- 0.7776000E-05 0.7776000E-05 0.0000000E+00 0.0000000E+00 16 HPO4-- 0.4168819E-07 0.4168819E-07 0.0000000E+00 0.0000000E+00 Chg. balance for solid moles: -.8470E-21 Mass of aqueous solution: 0.900012E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 0.0191900 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 0.3058E-05 -5.515 0.8018E-03 -3.096 99.64 0.3078E-03 stilpnomelane-Fe 0.2714E-08 -8.566 0.2926E-05 -5.534 0.3636 0.1011E-05 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 0.000805 g Volume = 0.000309 cm3 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.0191900 moles log = -1.7169 Original solution: 1000.0103000 g Original solution / Rock added: 52111.01 (Water/Rock Ratio), log = 4.7169 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0206 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9997E+00 0.9859 0.1006E+01 0.1020E+01 CO2,gas 0.1333E-04 1.0071 0.1371E-04 0.1361E-04 CH4,gas 0.6801E-05 1.0125 0.7028E-05 0.6941E-05 H2,gas 0.2622E-03 1.0005 0.2677E-03 0.2676E-03 H2S,gas 0.3450E-05 0.9960 0.3508E-05 0.3521E-05 S2,gas 0.6314E-23 1.0000 0.6444E-23 0.6444E-23 CO,gas 0.9581E-12 1.0000 0.9778E-12 0.9778E-12 SO3,gas 0.1865E-39 1.0000 0.1904E-39 0.1904E-39 SO2,gas 0.1943E-20 1.0000 0.1983E-20 0.1983E-20 HF,gas 0.1267E-13 1.0000 0.1293E-13 0.1293E-13 HCl,gas 0.7877E-17 1.0000 0.8039E-17 0.8039E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 17 albite -0.38 -0.38 0.00 0.000 -0.94784E-12 165 stilpnomelane-Fe 13.02 13.02 0.00 0.000 0.21232E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -13.22 -6.56 -2.187 0.11205E+05 -4.863 3 CH4,gas 4.54 -2.31 -6.85 -1.713 0.11700E+05 -5.153 4 H2,gas 8.00 2.73 -5.27 -3.012 0.90006E+04 -3.572 5 H2S,gas -6.23 -13.38 -7.15 -3.577 0.12215E+05 -5.455 6 S2,gas -7.34 -32.23 -24.89 -3.829 0.42499E+05 -23.191 7 CO,gas 3.21 -10.49 -13.71 -4.218 0.23407E+05 -12.010 8 SO3,gas 17.12 -24.30 -41.42 -10.355 0.70722E+05 -39.720 9 SO2,gas 0.83 -21.57 -22.40 -5.974 0.38250E+05 -20.703 10 HF,gas 0.47 -15.11 -15.59 -7.794 0.26615E+05 -13.888 11 HCl,gas 5.19 -13.60 -18.79 -9.397 0.32090E+05 -17.095 12 acmite 7.71 7.44 -0.27 -0.029 0.46840E+03 16 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 20 spessartine 24.46 19.52 -4.94 -0.247 0.84371E+04 21 analcite 3.32 2.62 -0.70 -0.077 0.11905E+04 25 annite 20.12 17.39 -2.73 -0.152 0.46596E+04 26 phlogopite 27.06 24.51 -2.56 -0.142 0.43679E+04 31 apatite-OH -18.15 -20.90 -2.74 -0.211 0.46850E+04 32 apatite-F -34.30 -36.01 -1.71 -0.143 0.29202E+04 36 aragonite 0.97 -0.86 -1.83 -0.609 0.31184E+04 37 brucite 12.57 9.00 -3.57 -0.714 0.60964E+04 38 calcite 0.81 -0.86 -1.67 -0.557 0.28542E+04 39 carnegieite-low 9.02 5.63 -3.39 -0.484 0.57887E+04 40 carnegieite-high 10.09 5.63 -4.46 -0.637 0.76157E+04 41 carpholite-Mg 8.58 3.89 -4.70 -0.313 0.80182E+04 43 celadonite 5.34 3.50 -1.84 -0.108 0.31416E+04 44 celadonite-Fe 3.88 1.13 -2.75 -0.161 0.46879E+04 45 chrysotile 23.89 20.98 -2.91 -0.243 0.49771E+04 47 clinochlore 39.07 36.87 -2.20 -0.069 0.37552E+04 48 daphnite 28.97 25.02 -3.95 -0.123 0.67418E+04 52 chloritoid-Fe 9.17 4.52 -4.65 -0.310 0.79393E+04 53 chloritoid-Mn 11.40 7.11 -4.29 -0.286 0.73292E+04 55 coesite -2.38 -3.01 -0.63 -0.211 0.10798E+04 62 cristobalite -2.56 -3.01 -0.45 -0.149 0.76517E+03 64 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71259E+04 66 diaspore 2.87 0.45 -2.42 -0.404 0.41342E+04 67 diamond -3.10 -7.77 -4.66 -1.332 0.79618E+04 68 diopside 16.18 15.34 -0.84 -0.084 0.14304E+04 69 hedenbergite 14.21 12.97 -1.24 -0.124 0.21093E+04 76 epidote 24.67 21.87 -2.80 -0.136 0.47850E+04 78 epidote-Fe 29.84 26.68 -3.16 -0.164 0.53998E+04 79 fayalite 14.05 10.25 -3.80 -0.543 0.64872E+04 80 ferrosilite 11.15 7.24 -3.91 -0.391 0.66787E+04 84 gibbsite 4.08 0.45 -3.63 -0.518 0.61928E+04 85 glaucophane 22.97 20.21 -2.77 -0.075 0.47212E+04 86 glaucophane-Fe 17.28 13.10 -4.18 -0.113 0.71340E+04 87 graphite -3.55 -7.77 -4.22 -1.205 0.72041E+04 88 greenalite 16.14 13.87 -2.27 -0.190 0.38829E+04 91 hematite 12.57 10.53 -2.04 -0.247 0.34827E+04 92 heulandite -5.83 -7.79 -1.96 -0.089 0.33547E+04 96 jadeite 4.22 2.62 -1.59 -0.159 0.27160E+04 97 julgoldite 70.43 65.71 -4.72 -0.123 0.80597E+04 98 kalsilite 7.58 3.53 -4.05 -0.579 0.69237E+04 99 kaolinite -1.33 -5.11 -3.78 -0.344 0.64530E+04 102 laumontite 2.88 1.23 -1.65 -0.110 0.28173E+04 103 lawsonite 9.62 7.25 -2.37 -0.158 0.40394E+04 104 leucite 4.12 0.52 -3.60 -0.360 0.61441E+04 106 lizardite 23.24 20.98 -2.27 -0.189 0.38697E+04 107 magnesite 0.69 -4.22 -4.91 -1.638 0.83916E+04 108 magnetite 20.09 17.15 -2.93 -0.239 0.50088E+04 109 minnesotaite 10.39 7.85 -2.54 -0.149 0.43363E+04 113 manganosite 14.06 9.21 -4.85 -1.211 0.82743E+04 117 microcline -2.49 -2.49 0.00 0.000 0.25183E+01 121 muscovite 2.58 -1.58 -4.17 -0.245 0.71125E+04 122 paragonite 4.24 0.52 -3.72 -0.219 0.63490E+04 123 nepheline 8.34 5.63 -2.71 -0.387 0.46211E+04 129 periclase-Fe 11.63 6.63 -5.00 -1.250 0.85359E+04 135 phlogopite-Na 29.65 26.61 -3.04 -0.169 0.51842E+04 137 prehnite 19.37 16.60 -2.77 -0.163 0.47256E+04 138 prehnite-Fe 22.50 21.42 -1.08 -0.065 0.18488E+04 143 pyrite -21.25 -22.87 -1.62 -0.382 0.27703E+04 144 pyrrhotite -4.26 -6.76 -2.50 -0.832 0.42626E+04 145 pyrrhotiteFe0.875 -6.02 -7.92 -1.91 -0.701 0.32554E+04 146 pyroxmangite 7.40 6.20 -1.19 -0.239 0.20404E+04 147 pyrophyllite -6.18 -11.13 -4.95 -0.310 0.84574E+04 148 quartz -2.99 -3.01 -0.02 -0.006 0.32501E+02 152 rhodochrosite -0.98 -4.01 -3.03 -1.011 0.51799E+04 153 rhodonite 7.45 6.20 -1.24 -0.248 0.21206E+04 154 sanidine -1.28 -2.49 -1.21 -0.093 0.20703E+04 156 siderite -2.61 -6.59 -3.99 -1.329 0.68070E+04 164 stilbite -7.52 -7.79 -0.27 -0.013 0.46089E+03 166 stilpnomelane-Mg 27.44 24.87 -2.57 -0.077 0.43900E+04 172 talc 16.49 14.96 -1.53 -0.090 0.26133E+04 175 tephroite 18.09 15.42 -2.67 -0.381 0.45588E+04 179 tridymite -2.63 -3.01 -0.38 -0.127 0.65248E+03 180 tremolite 47.87 45.65 -2.22 -0.060 0.37931E+04 181 ferroactinolite 38.45 33.79 -4.66 -0.126 0.79534E+04 182 troilite-low -4.41 -6.76 -2.35 -0.782 0.40054E+04 188 wairakite 3.95 1.23 -2.72 -0.160 0.46393E+04 189 walstromite 11.51 9.35 -2.16 -0.431 0.36801E+04 190 wollastonite 10.46 9.35 -1.11 -0.221 0.18905E+04 191 pseudo-wollastonite 11.00 9.35 -1.65 -0.329 0.28104E+04 193 akaganeite 7.75 5.26 -2.49 -0.539 0.42539E+04 200 chalcedony -2.80 -3.01 -0.21 -0.069 0.35180E+03 202 montmorillonite-Ca -2.29 -6.27 -3.98 -0.246 0.67930E+04 203 montmorillonite-K -2.24 -6.30 -4.06 -0.249 0.69394E+04 204 montmorillonite-Mg -2.48 -6.82 -4.34 -0.269 0.74178E+04 205 montmorillonite-Na -2.04 -5.61 -3.57 -0.219 0.60934E+04 206 nontronite-Ca 3.21 1.67 -1.54 -0.100 0.26296E+04 207 nontronite-H 2.53 -0.37 -2.90 -0.194 0.49482E+04 208 nontronite-K 3.34 1.64 -1.70 -0.109 0.28992E+04 209 nontronite-Mg 3.07 1.12 -1.96 -0.127 0.33385E+04 210 nontronite-Na 3.52 2.34 -1.18 -0.076 0.20192E+04 226 tobermorite 9.82 7.29 -2.53 -0.691 0.43261E+04 232 alabandite -0.98 -4.17 -3.19 -1.065 0.54539E+04 235 boehmite 4.41 0.45 -3.95 -0.659 0.67511E+04 237 ferrous-oxide 9.81 6.63 -3.18 -0.796 0.54368E+04 243 silica-amorphous -2.09 -3.01 -0.92 -0.306 0.15660E+04 245 an20ab80 2.02 1.14 -0.87 -0.067 0.14937E+04 246 an25ab75 2.65 1.52 -1.12 -0.086 0.19141E+04 247 an30ab70 3.28 1.91 -1.37 -0.106 0.23441E+04 248 tr.625ac.25prg.125 45.16 43.51 -1.66 -0.045 0.28338E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 0.0004000 MOLES Current total amount of reactant added: 0.0191900 MOLES New total amount of reactant added: 0.0195900 MOLES Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.5508E-08 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 7 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 0.0195900 Water: Moles liquid = 0.4987E+02 kg liquid = 0.8984E+00 Moles total = 0.4986E+02 kg total = 0.8983E+00 Activity = 1.0000 Stoichiometric ionic strength = .1258752E-01 Osmotic coef. = 0.9399 True ionic strength = .2108780E-01 Chg. balance for total moles = -.5508E-08 Max. difference allowed = 0.2535E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.12928E-09 -9.8885 0.10827E-09 -9.9655 0.83755E+00 -0.0770 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.28085E-03 -3.5515 0.23375E-03 -3.6312 0.83231E+00 -0.0797 4 SO4-- 0.87389E-04 -4.0585 0.44767E-04 -4.3490 0.51227E+00 -0.2905 5 HCO3- 0.68700E-03 -3.1630 0.57266E-03 -3.2421 0.83357E+00 -0.0791 6 HS- 0.47064E-03 -3.3273 0.39178E-03 -3.4070 0.83243E+00 -0.0797 7 Al+++ 0.15828E-28 -28.8006 0.35441E-29 -29.4505 0.22391E+00 -0.6499 8 H4SiO4 0.98841E-03 -3.0051 0.98841E-03 -3.0051 0.10000E+01 0.0000 9 Ca++ 0.51693E-07 -7.2866 0.26278E-07 -7.5804 0.50835E+00 -0.2938 10 Mg++ 0.22718E-10 -10.6436 0.11493E-10 -10.9395 0.50593E+00 -0.2959 11 Fe++ 0.97604E-13 -13.0105 0.49437E-13 -13.3060 0.50650E+00 -0.2954 12 K+ 0.15658E-03 -3.8053 0.13055E-03 -3.8842 0.83378E+00 -0.0789 13 Na+ 0.19940E-01 -1.7003 0.16593E-01 -1.7801 0.83215E+00 -0.0798 14 Mn++ 0.37622E-10 -10.4246 0.19072E-10 -10.7196 0.50694E+00 -0.2950 15 F- 0.88052E-05 -5.0553 0.73129E-05 -5.1359 0.83052E+00 -0.0806 16 HPO4-- 0.45600E-07 -7.3410 0.23363E-07 -7.6315 0.51234E+00 -0.2904 18 HSiO3- 0.10241E-01 -1.9896 0.85239E-02 -2.0694 0.83231E+00 -0.0797 19 Ca(HSiO3)+ 0.61167E-08 -8.2135 0.51011E-08 -8.2923 0.83397E+00 -0.0789 20 Mg(HSiO3)+ 0.33295E-11 -11.4776 0.27767E-11 -11.5565 0.83397E+00 -0.0789 21 NaHSiO3,aq 0.22875E-02 -2.6406 0.22875E-02 -2.6406 0.10000E+01 0.0000 22 AlO+ 0.49315E-16 -16.3070 0.41127E-16 -16.3859 0.83397E+00 -0.0789 24 HAlO2,aq 0.75645E-10 -10.1212 0.75645E-10 -10.1212 0.10000E+01 0.0000 25 AlO2- 0.18616E-05 -5.7301 0.15465E-05 -5.8107 0.83074E+00 -0.0805 26 CH4,aq 0.48870E-08 -8.3110 0.48682E-08 -8.3126 0.99617E+00 -0.0017 27 C2H6,aq 0.20018E-19 -19.6986 0.19941E-19 -19.7002 0.99617E+00 -0.0017 31 CO,aq 0.67622E-15 -15.1699 0.67622E-15 -15.1699 0.10000E+01 0.0000 32 CO2,aq 0.13300E-06 -6.8762 0.13249E-06 -6.8778 0.99617E+00 -0.0017 33 CO3-2 0.90382E-03 -3.0439 0.46197E-03 -3.3354 0.51114E+00 -0.2915 34 CaCO3,aq 0.15222E-06 -6.8175 0.15222E-06 -6.8175 0.10000E+01 0.0000 35 Ca(HCO3)+ 0.46060E-09 -9.3367 0.38413E-09 -9.4155 0.83397E+00 -0.0789 36 CaCl+ 0.11920E-10 -10.9237 0.99405E-11 -11.0026 0.83397E+00 -0.0789 37 CaCl2,aq 0.55204E-15 -15.2580 0.55204E-15 -15.2580 0.10000E+01 0.0000 38 CaF+ 0.33643E-11 -11.4731 0.28057E-11 -11.5520 0.83397E+00 -0.0789 39 CaOH+ 0.20741E-07 -7.6832 0.17297E-07 -7.7620 0.83397E+00 -0.0789 40 CaSO4,aq 0.37355E-09 -9.4276 0.37355E-09 -9.4276 0.10000E+01 0.0000 41 HCl,aq 0.46378E-14 -14.3337 0.46378E-14 -14.3337 0.10000E+01 0.0000 45 HF,aq 0.54204E-11 -11.2660 0.54204E-11 -11.2660 0.10000E+01 0.0000 46 HF2- 0.16080E-16 -16.7937 0.13383E-16 -16.8734 0.83231E+00 -0.0797 48 FeCl+ 0.21933E-16 -16.6589 0.18291E-16 -16.7378 0.83397E+00 -0.0789 51 FeF+ 0.22153E-16 -16.6546 0.18475E-16 -16.7334 0.83397E+00 -0.0789 53 FeO,aq 0.16389E-09 -9.7854 0.16389E-09 -9.7854 0.10000E+01 0.0000 54 FeOH+ 0.17821E-10 -10.7491 0.14862E-10 -10.8279 0.83397E+00 -0.0789 55 HFeO2- 0.19029E-07 -7.7206 0.15838E-07 -7.8003 0.83231E+00 -0.0797 56 FeO+ 0.94304E-16 -16.0255 0.78646E-16 -16.1043 0.83397E+00 -0.0789 58 FeO2- 0.16493E-08 -8.7827 0.13727E-08 -8.8624 0.83231E+00 -0.0797 59 HFeO2,aq 0.18903E-10 -10.7235 0.18903E-10 -10.7235 0.10000E+01 0.0000 60 H2,aq 0.20396E-06 -6.6905 0.20318E-06 -6.6921 0.99617E+00 -0.0017 61 KCl,aq 0.55309E-09 -9.2572 0.55309E-09 -9.2572 0.10000E+01 0.0000 62 KHSO4,aq 0.17891E-17 -17.7474 0.17891E-17 -17.7474 0.10000E+01 0.0000 63 KOH,aq 0.51492E-06 -6.2883 0.51492E-06 -6.2883 0.10000E+01 0.0000 64 KSO4- 0.10896E-06 -6.9627 0.90689E-07 -7.0424 0.83231E+00 -0.0797 65 MgCO3,aq 0.16688E-10 -10.7776 0.16688E-10 -10.7776 0.10000E+01 0.0000 66 Mg(HCO3)+ 0.20585E-12 -12.6864 0.17167E-12 -12.7653 0.83397E+00 -0.0789 67 MgCl+ 0.47251E-14 -14.3256 0.39406E-14 -14.4044 0.83397E+00 -0.0789 68 MgF+ 0.54507E-14 -14.2635 0.45457E-14 -14.3424 0.83397E+00 -0.0789 69 MgOH+ 0.50197E-10 -10.2993 0.41863E-10 -10.3782 0.83397E+00 -0.0789 71 MnF+ 0.28170E-14 -14.5502 0.23492E-14 -14.6291 0.83397E+00 -0.0789 72 MnO,aq 0.16848E-08 -8.7735 0.16848E-08 -8.7735 0.10000E+01 0.0000 73 MnOH+ 0.63870E-09 -9.1947 0.53265E-09 -9.2736 0.83397E+00 -0.0789 74 MnO2-2 0.93310E-11 -11.0301 0.47694E-11 -11.3215 0.51114E+00 -0.2915 75 HMnO2- 0.13593E-09 -9.8667 0.11314E-09 -9.9464 0.83231E+00 -0.0797 78 MnCl+ 0.32919E-13 -13.4826 0.27453E-13 -13.5614 0.83397E+00 -0.0789 79 MnSO4,aq 0.24649E-12 -12.6082 0.24649E-12 -12.6082 0.10000E+01 0.0000 80 NaCl,aq 0.12854E-05 -5.8910 0.12854E-05 -5.8910 0.10000E+01 0.0000 81 NaF,aq 0.28408E-07 -7.5466 0.28408E-07 -7.5466 0.10000E+01 0.0000 82 NaOH,aq 0.65843E-04 -4.1815 0.65843E-04 -4.1815 0.10000E+01 0.0000 84 OH- 0.64234E-02 -2.1922 0.53362E-02 -2.2728 0.83074E+00 -0.0805 89 HPO3-2 0.28941E-16 -16.5385 0.14793E-16 -16.8300 0.51114E+00 -0.2915 92 H3PO4,aq 0.19156E-17 -17.7177 0.19156E-17 -17.7177 0.10000E+01 0.0000 93 H2PO4- 0.56011E-10 -10.2517 0.46665E-10 -10.3310 0.83313E+00 -0.0793 94 PO4-3 0.74709E-09 -9.1266 0.17605E-09 -9.7544 0.23565E+00 -0.6277 98 HP2O7-3 0.14048E-17 -17.8524 0.31488E-18 -18.5019 0.22414E+00 -0.6495 99 P2O7-4 0.95148E-17 -17.0216 0.69476E-18 -18.1582 0.73018E-01 -1.1366 100 H2S,aq 0.13161E-06 -6.8807 0.13110E-06 -6.8824 0.99617E+00 -0.0017 101 S2-2 0.32749E-10 -10.4848 0.16739E-10 -10.7763 0.51114E+00 -0.2915 102 S3-2 0.28470E-16 -16.5456 0.14552E-16 -16.8371 0.51114E+00 -0.2915 107 SO3-2 0.22781E-11 -11.6424 0.11820E-11 -11.9274 0.51884E+00 -0.2850 108 HSO3- 0.96273E-14 -14.0165 0.80128E-14 -14.0962 0.83231E+00 -0.0797 109 HSO4- 0.55955E-11 -11.2522 0.46712E-11 -11.3306 0.83481E+00 -0.0784 111 S2O3-2 0.13488E-12 -12.8701 0.68942E-13 -13.1615 0.51114E+00 -0.2915 Charge balance for all species = -.6131E-08 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.1292751E-09 -.1992989E-01 -.2005168E+02 0.0000 2 H2O 0.1000000E+01 0.5550222E+02 0.9980744E+06 0.0000 3 Cl- 0.2808478E-03 0.2821337E-03 0.9984333E+01 6.3342 4 SO4-- 0.8738882E-04 0.8744250E-04 0.8384622E+01 15.5819 5 HCO3- 0.6869973E-03 0.1591104E-02 0.9690852E+02 6.7234 6 HS- 0.4706391E-03 0.4708264E-03 0.1554291E+02 6.5585 7 Al+++ 0.1582837E-28 0.1861664E-05 0.5013933E-01 0.4459 8 H4SiO4 0.9884097E-03 0.1351723E-01 0.1296857E+04 -3.0051 9 Ca++ 0.5169303E-07 0.2316190E-06 0.9265981E-02 12.3505 10 Mg++ 0.2271761E-10 0.9314838E-10 0.2260513E-05 8.9914 11 Fe++ 0.9760377E-13 0.2087897E-07 0.1163912E-02 6.6250 12 K+ 0.1565774E-03 0.1572018E-03 0.6135748E+01 6.0813 13 Na+ 0.1993979E-01 0.2229446E-01 0.5116151E+03 8.1854 14 Mn++ 0.3762233E-10 0.2506647E-08 0.1374603E-03 9.2114 15 F- 0.8805194E-05 0.8833611E-05 0.1675164E+00 4.8296 16 HPO4-- 0.4560029E-07 0.4640338E-07 0.4445668E-02 12.2995 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.1791719E-01 -.1790475E-01 -.1243495E-04 0.0000000E+00 2 H2O 0.4986245E+02 0.4986246E+02 -.1239344E-04 0.0000000E+00 3 Cl- 0.2534652E-03 0.2534652E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.7855719E-04 0.7855719E-04 0.0000000E+00 0.0000000E+00 5 HCO3- 0.1429427E-02 0.1429427E-02 0.0000000E+00 0.0000000E+00 6 HS- 0.4229843E-03 0.4229843E-03 0.0000000E+00 0.0000000E+00 7 Al+++ 0.4775352E-05 0.1672495E-05 0.3102857E-05 0.0000000E+00 8 H4SiO4 0.1215302E-01 0.1214371E-01 0.9314106E-05 0.0000000E+00 9 Ca++ 0.2080835E-06 0.2080835E-06 0.0000000E+00 0.0000000E+00 10 Mg++ 0.8368328E-10 0.8368328E-10 0.0000000E+00 0.0000000E+00 11 Fe++ 0.3259227E-07 0.1875739E-07 0.1383488E-07 0.0000000E+00 12 K+ 0.1412294E-03 0.1412280E-03 0.1383488E-08 0.0000000E+00 13 Na+ 0.2003215E-01 0.2002905E-01 0.3097323E-05 0.0000000E+00 14 Mn++ 0.2251939E-08 0.2251939E-08 0.0000000E+00 0.0000000E+00 15 F- 0.7936000E-05 0.7936000E-05 0.0000000E+00 0.0000000E+00 16 HPO4-- 0.4168819E-07 0.4168819E-07 0.0000000E+00 0.0000000E+00 Chg. balance for solid moles: -.1271E-20 Mass of aqueous solution: 0.900020E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 0.0195900 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 0.3097E-05 -5.509 0.8122E-03 -3.090 99.63 0.3118E-03 stilpnomelane-Fe 0.2767E-08 -8.558 0.2983E-05 -5.525 0.3659 0.1030E-05 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 0.000815 g Volume = 0.000313 cm3 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.0195900 moles log = -1.7080 Original solution: 1000.0103000 g Original solution / Rock added: 51046.98 (Water/Rock Ratio), log = 4.7080 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0206 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9997E+00 0.9859 0.1006E+01 0.1020E+01 CO2,gas 0.1379E-04 1.0071 0.1417E-04 0.1408E-04 CH4,gas 0.6934E-05 1.0125 0.7166E-05 0.7077E-05 H2,gas 0.2612E-03 1.0005 0.2667E-03 0.2666E-03 H2S,gas 0.3545E-05 0.9960 0.3604E-05 0.3618E-05 S2,gas 0.6713E-23 1.0000 0.6852E-23 0.6852E-23 CO,gas 0.9874E-12 1.0000 0.1008E-11 0.1008E-11 SO3,gas 0.1944E-39 1.0000 0.1984E-39 0.1984E-39 SO2,gas 0.2018E-20 1.0000 0.2059E-20 0.2059E-20 HF,gas 0.1304E-13 1.0000 0.1331E-13 0.1331E-13 HCl,gas 0.8018E-17 1.0000 0.8184E-17 0.8184E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 17 albite -0.38 -0.38 0.00 0.000 -0.94784E-12 165 stilpnomelane-Fe 13.02 13.02 0.00 0.000 0.21232E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -13.21 -6.55 -2.182 0.11180E+05 -4.848 3 CH4,gas 4.54 -2.30 -6.84 -1.711 0.11685E+05 -5.145 4 H2,gas 8.00 2.73 -5.27 -3.013 0.90033E+04 -3.574 5 H2S,gas -6.23 -13.37 -7.14 -3.571 0.12195E+05 -5.443 6 S2,gas -7.34 -32.20 -24.86 -3.825 0.42453E+05 -23.164 7 CO,gas 3.21 -10.48 -13.70 -4.214 0.23385E+05 -11.997 8 SO3,gas 17.12 -24.28 -41.40 -10.350 0.70692E+05 -39.702 9 SO2,gas 0.83 -21.55 -22.39 -5.969 0.38222E+05 -20.686 10 HF,gas 0.47 -15.10 -15.57 -7.787 0.26594E+05 -13.876 11 HCl,gas 5.19 -13.60 -18.79 -9.393 0.32077E+05 -17.087 12 acmite 7.71 7.44 -0.27 -0.028 0.46595E+03 16 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 20 spessartine 24.46 19.51 -4.95 -0.247 0.84462E+04 21 analcite 3.32 2.62 -0.70 -0.078 0.11964E+04 25 annite 20.12 17.39 -2.74 -0.152 0.46723E+04 26 phlogopite 27.06 24.49 -2.58 -0.143 0.44026E+04 31 apatite-OH -18.15 -20.93 -2.78 -0.214 0.47486E+04 32 apatite-F -34.30 -36.04 -1.73 -0.145 0.29624E+04 36 aragonite 0.97 -0.86 -1.82 -0.608 0.31137E+04 37 brucite 12.57 8.99 -3.58 -0.715 0.61079E+04 38 calcite 0.81 -0.86 -1.67 -0.556 0.28494E+04 39 carnegieite-low 9.02 5.63 -3.40 -0.485 0.58003E+04 40 carnegieite-high 10.09 5.63 -4.47 -0.638 0.76273E+04 41 carpholite-Mg 8.58 3.87 -4.71 -0.314 0.80404E+04 43 celadonite 5.34 3.50 -1.84 -0.108 0.31473E+04 44 celadonite-Fe 3.88 1.13 -2.74 -0.161 0.46863E+04 45 chrysotile 23.89 20.96 -2.93 -0.244 0.50000E+04 47 clinochlore 39.07 36.83 -2.24 -0.070 0.38177E+04 48 daphnite 28.97 25.00 -3.96 -0.124 0.67677E+04 52 chloritoid-Fe 9.17 4.51 -4.66 -0.311 0.79599E+04 53 chloritoid-Mn 11.40 7.10 -4.30 -0.287 0.73471E+04 55 coesite -2.38 -3.01 -0.63 -0.210 0.10740E+04 62 cristobalite -2.56 -3.01 -0.44 -0.148 0.75935E+03 64 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71260E+04 66 diaspore 2.87 0.45 -2.43 -0.405 0.41454E+04 67 diamond -3.10 -7.75 -4.65 -1.329 0.79422E+04 68 diopside 16.18 15.33 -0.85 -0.085 0.14506E+04 69 hedenbergite 14.21 12.97 -1.24 -0.124 0.21222E+04 76 epidote 24.67 21.84 -2.83 -0.137 0.48332E+04 78 epidote-Fe 29.84 26.65 -3.19 -0.165 0.54398E+04 79 fayalite 14.05 10.24 -3.80 -0.543 0.64898E+04 80 ferrosilite 11.15 7.24 -3.91 -0.391 0.66755E+04 84 gibbsite 4.08 0.45 -3.63 -0.519 0.62039E+04 85 glaucophane 22.97 20.20 -2.78 -0.075 0.47442E+04 86 glaucophane-Fe 17.28 13.10 -4.18 -0.113 0.71350E+04 87 graphite -3.55 -7.75 -4.21 -1.202 0.71844E+04 88 greenalite 16.14 13.86 -2.27 -0.190 0.38839E+04 91 hematite 12.57 10.52 -2.04 -0.248 0.34885E+04 92 heulandite -5.83 -7.79 -1.97 -0.089 0.33565E+04 96 jadeite 4.22 2.62 -1.59 -0.159 0.27219E+04 97 julgoldite 70.43 65.67 -4.76 -0.124 0.81257E+04 98 kalsilite 7.58 3.52 -4.06 -0.580 0.69354E+04 99 kaolinite -1.33 -5.12 -3.79 -0.344 0.64636E+04 102 laumontite 2.88 1.22 -1.66 -0.111 0.28366E+04 103 lawsonite 9.62 7.23 -2.38 -0.159 0.40703E+04 104 leucite 4.12 0.52 -3.60 -0.360 0.61500E+04 106 lizardite 23.24 20.96 -2.28 -0.190 0.38927E+04 107 magnesite 0.69 -4.22 -4.91 -1.636 0.83782E+04 108 magnetite 20.09 17.15 -2.94 -0.240 0.50188E+04 109 minnesotaite 10.39 7.85 -2.53 -0.149 0.43256E+04 113 manganosite 14.06 9.21 -4.85 -1.212 0.82757E+04 117 microcline -2.49 -2.49 0.00 0.000 0.25830E+01 121 muscovite 2.58 -1.60 -4.18 -0.246 0.71348E+04 122 paragonite 4.24 0.51 -3.73 -0.219 0.63713E+04 123 nepheline 8.34 5.63 -2.71 -0.388 0.46327E+04 135 phlogopite-Na 29.65 26.59 -3.06 -0.170 0.52188E+04 137 prehnite 19.37 16.58 -2.79 -0.164 0.47709E+04 138 prehnite-Fe 22.50 21.39 -1.10 -0.066 0.18859E+04 143 pyrite -21.25 -22.85 -1.60 -0.376 0.27317E+04 144 pyrrhotite -4.26 -6.75 -2.49 -0.829 0.42467E+04 145 pyrrhotiteFe0.875 -6.02 -7.91 -1.90 -0.698 0.32386E+04 146 pyroxmangite 7.40 6.21 -1.19 -0.238 0.20360E+04 147 pyrophyllite -6.18 -11.13 -4.95 -0.310 0.84564E+04 148 quartz -2.99 -3.01 -0.02 -0.005 0.26684E+02 152 rhodochrosite -0.98 -4.00 -3.02 -1.007 0.51564E+04 153 rhodonite 7.45 6.21 -1.24 -0.248 0.21162E+04 154 sanidine -1.28 -2.49 -1.21 -0.093 0.20703E+04 156 siderite -2.61 -6.58 -3.97 -1.325 0.67862E+04 164 stilbite -7.52 -7.79 -0.27 -0.013 0.46271E+03 166 stilpnomelane-Mg 27.44 24.85 -2.59 -0.077 0.44265E+04 172 talc 16.49 14.95 -1.54 -0.090 0.26246E+04 175 tephroite 18.09 15.42 -2.67 -0.381 0.45558E+04 179 tridymite -2.63 -3.01 -0.38 -0.126 0.64666E+03 180 tremolite 47.87 45.62 -2.25 -0.061 0.38447E+04 181 ferroactinolite 38.45 33.79 -4.67 -0.126 0.79684E+04 182 troilite-low -4.41 -6.75 -2.34 -0.779 0.39895E+04 188 wairakite 3.95 1.22 -2.73 -0.160 0.46585E+04 189 walstromite 11.51 9.35 -2.16 -0.433 0.36945E+04 190 wollastonite 10.46 9.35 -1.12 -0.223 0.19050E+04 191 pseudo-wollastonite 11.00 9.35 -1.65 -0.331 0.28248E+04 193 akaganeite 7.75 5.26 -2.49 -0.539 0.42568E+04 200 chalcedony -2.80 -3.01 -0.20 -0.068 0.34598E+03 202 montmorillonite-Ca -2.29 -6.27 -3.98 -0.246 0.67955E+04 203 montmorillonite-K -2.24 -6.30 -4.06 -0.249 0.69406E+04 204 montmorillonite-Mg -2.48 -6.82 -4.34 -0.269 0.74189E+04 205 montmorillonite-Na -2.04 -5.61 -3.57 -0.219 0.60947E+04 206 nontronite-Ca 3.21 1.68 -1.54 -0.100 0.26210E+04 207 nontronite-H 2.53 -0.36 -2.89 -0.194 0.49363E+04 208 nontronite-K 3.34 1.65 -1.69 -0.109 0.28894E+04 209 nontronite-Mg 3.07 1.13 -1.95 -0.126 0.33285E+04 210 nontronite-Na 3.52 2.34 -1.18 -0.076 0.20094E+04 226 tobermorite 9.82 7.28 -2.54 -0.693 0.43372E+04 232 alabandite -0.98 -4.16 -3.18 -1.061 0.54353E+04 235 boehmite 4.41 0.45 -3.96 -0.660 0.67623E+04 237 ferrous-oxide 9.81 6.62 -3.19 -0.797 0.54410E+04 243 silica-amorphous -2.09 -3.01 -0.91 -0.305 0.15602E+04 245 an20ab80 2.02 1.14 -0.88 -0.068 0.14999E+04 246 an25ab75 2.65 1.52 -1.13 -0.087 0.19218E+04 247 an30ab70 3.28 1.90 -1.38 -0.106 0.23534E+04 248 tr.625ac.25prg.125 45.16 43.48 -1.69 -0.045 0.28812E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 0.0004000 MOLES Current total amount of reactant added: 0.0195900 MOLES New total amount of reactant added: 0.0199900 MOLES Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.5508E-08 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 7 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 0.0199900 Water: Moles liquid = 0.4987E+02 kg liquid = 0.8984E+00 Moles total = 0.4986E+02 kg total = 0.8983E+00 Activity = 1.0000 Stoichiometric ionic strength = .1261332E-01 Osmotic coef. = 0.9397 True ionic strength = .2110672E-01 Chg. balance for total moles = -.5508E-08 Max. difference allowed = 0.2558E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.13039E-09 -9.8847 0.10921E-09 -9.9618 0.83750E+00 -0.0770 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.28346E-03 -3.5475 0.23591E-03 -3.6273 0.83226E+00 -0.0797 4 SO4-- 0.89511E-04 -4.0481 0.45843E-04 -4.3387 0.51215E+00 -0.2906 5 HCO3- 0.70423E-03 -3.1523 0.58700E-03 -3.2314 0.83352E+00 -0.0791 6 HS- 0.47933E-03 -3.3194 0.39898E-03 -3.3990 0.83238E+00 -0.0797 7 Al+++ 0.16006E-28 -28.7957 0.35819E-29 -29.4459 0.22378E+00 -0.6502 8 H4SiO4 0.99622E-03 -3.0016 0.99622E-03 -3.0016 0.10000E+01 0.0000 9 Ca++ 0.51190E-07 -7.2908 0.26016E-07 -7.5848 0.50823E+00 -0.2939 10 Mg++ 0.22758E-10 -10.6429 0.11511E-10 -10.9389 0.50580E+00 -0.2960 11 Fe++ 0.98751E-13 -13.0055 0.50005E-13 -13.3010 0.50638E+00 -0.2955 12 K+ 0.15658E-03 -3.8053 0.13054E-03 -3.8842 0.83373E+00 -0.0790 13 Na+ 0.19942E-01 -1.7002 0.16593E-01 -1.7801 0.83210E+00 -0.0798 14 Mn++ 0.38207E-10 -10.4179 0.19364E-10 -10.7130 0.50682E+00 -0.2951 15 F- 0.89827E-05 -5.0466 0.74598E-05 -5.1273 0.83047E+00 -0.0807 16 HPO4-- 0.45606E-07 -7.3410 0.23360E-07 -7.6315 0.51222E+00 -0.2905 18 HSiO3- 0.10235E-01 -1.9899 0.85179E-02 -2.0697 0.83226E+00 -0.0797 19 Ca(HSiO3)+ 0.60518E-08 -8.2181 0.50467E-08 -8.2970 0.83392E+00 -0.0789 20 Mg(HSiO3)+ 0.33325E-11 -11.4772 0.27790E-11 -11.5561 0.83392E+00 -0.0789 21 NaHSiO3,aq 0.22860E-02 -2.6409 0.22860E-02 -2.6409 0.10000E+01 0.0000 22 AlO+ 0.48998E-16 -16.3098 0.40860E-16 -16.3887 0.83392E+00 -0.0789 24 HAlO2,aq 0.74513E-10 -10.1278 0.74513E-10 -10.1278 0.10000E+01 0.0000 25 AlO2- 0.18182E-05 -5.7404 0.15104E-05 -5.8209 0.83069E+00 -0.0806 26 CH4,aq 0.49817E-08 -8.3026 0.49625E-08 -8.3043 0.99616E+00 -0.0017 27 C2H6,aq 0.20875E-19 -19.6804 0.20795E-19 -19.6820 0.99616E+00 -0.0017 31 CO,aq 0.69665E-15 -15.1570 0.69665E-15 -15.1570 0.10000E+01 0.0000 32 CO2,aq 0.13750E-06 -6.8617 0.13697E-06 -6.8634 0.99616E+00 -0.0017 33 CO3-2 0.91875E-03 -3.0368 0.46950E-03 -3.3284 0.51101E+00 -0.2916 34 CaCO3,aq 0.15315E-06 -6.8149 0.15315E-06 -6.8149 0.10000E+01 0.0000 35 Ca(HCO3)+ 0.46745E-09 -9.3303 0.38981E-09 -9.4091 0.83392E+00 -0.0789 36 CaCl+ 0.11910E-10 -10.9241 0.99323E-11 -11.0029 0.83392E+00 -0.0789 37 CaCl2,aq 0.55668E-15 -15.2544 0.55668E-15 -15.2544 0.10000E+01 0.0000 38 CaF+ 0.33978E-11 -11.4688 0.28335E-11 -11.5477 0.83392E+00 -0.0789 39 CaOH+ 0.20360E-07 -7.6912 0.16978E-07 -7.7701 0.83392E+00 -0.0789 40 CaSO4,aq 0.37872E-09 -9.4217 0.37872E-09 -9.4217 0.10000E+01 0.0000 41 HCl,aq 0.47210E-14 -14.3260 0.47210E-14 -14.3260 0.10000E+01 0.0000 45 HF,aq 0.55769E-11 -11.2536 0.55769E-11 -11.2536 0.10000E+01 0.0000 46 HF2- 0.16877E-16 -16.7727 0.14046E-16 -16.8524 0.83226E+00 -0.0797 48 FeCl+ 0.22391E-16 -16.6499 0.18672E-16 -16.7288 0.83392E+00 -0.0789 51 FeF+ 0.22859E-16 -16.6409 0.19062E-16 -16.7198 0.83392E+00 -0.0789 53 FeO,aq 0.16296E-09 -9.7879 0.16296E-09 -9.7879 0.10000E+01 0.0000 54 FeOH+ 0.17874E-10 -10.7478 0.14905E-10 -10.8267 0.83392E+00 -0.0789 55 HFeO2- 0.18761E-07 -7.7268 0.15614E-07 -7.8065 0.83226E+00 -0.0797 56 FeO+ 0.94747E-16 -16.0234 0.79011E-16 -16.1023 0.83392E+00 -0.0789 58 FeO2- 0.16289E-08 -8.7881 0.13556E-08 -8.8679 0.83226E+00 -0.0797 59 HFeO2,aq 0.18829E-10 -10.7252 0.18829E-10 -10.7252 0.10000E+01 0.0000 60 H2,aq 0.20324E-06 -6.6920 0.20246E-06 -6.6937 0.99616E+00 -0.0017 61 KCl,aq 0.55817E-09 -9.2532 0.55817E-09 -9.2532 0.10000E+01 0.0000 62 KHSO4,aq 0.18478E-17 -17.7333 0.18478E-17 -17.7333 0.10000E+01 0.0000 63 KOH,aq 0.51050E-06 -6.2920 0.51050E-06 -6.2920 0.10000E+01 0.0000 64 KSO4- 0.11158E-06 -6.9524 0.92865E-07 -7.0321 0.83226E+00 -0.0797 65 MgCO3,aq 0.16986E-10 -10.7699 0.16986E-10 -10.7699 0.10000E+01 0.0000 66 Mg(HCO3)+ 0.21134E-12 -12.6750 0.17624E-12 -12.7539 0.83392E+00 -0.0789 67 MgCl+ 0.47764E-14 -14.3209 0.39832E-14 -14.3998 0.83392E+00 -0.0789 68 MgF+ 0.55692E-14 -14.2542 0.46442E-14 -14.3331 0.83392E+00 -0.0789 69 MgOH+ 0.49849E-10 -10.3023 0.41570E-10 -10.3812 0.83392E+00 -0.0789 71 MnF+ 0.29177E-14 -14.5350 0.24331E-14 -14.6138 0.83392E+00 -0.0789 72 MnO,aq 0.16815E-08 -8.7743 0.16815E-08 -8.7743 0.10000E+01 0.0000 73 MnOH+ 0.64297E-09 -9.1918 0.53618E-09 -9.2707 0.83392E+00 -0.0789 74 MnO2-2 0.91567E-11 -11.0383 0.46792E-11 -11.3298 0.51101E+00 -0.2916 75 HMnO2- 0.13452E-09 -9.8712 0.11195E-09 -9.9510 0.83226E+00 -0.0797 78 MnCl+ 0.33733E-13 -13.4719 0.28131E-13 -13.5508 0.83392E+00 -0.0789 79 MnSO4,aq 0.25627E-12 -12.5913 0.25627E-12 -12.5913 0.10000E+01 0.0000 80 NaCl,aq 0.12973E-05 -5.8870 0.12973E-05 -5.8870 0.10000E+01 0.0000 81 NaF,aq 0.28980E-07 -7.5379 0.28980E-07 -7.5379 0.10000E+01 0.0000 82 NaOH,aq 0.65283E-04 -4.1852 0.65283E-04 -4.1852 0.10000E+01 0.0000 84 OH- 0.63690E-02 -2.1959 0.52907E-02 -2.2765 0.83069E+00 -0.0806 89 HPO3-2 0.28842E-16 -16.5400 0.14739E-16 -16.8315 0.51101E+00 -0.2916 92 H3PO4,aq 0.19485E-17 -17.7103 0.19485E-17 -17.7103 0.10000E+01 0.0000 93 H2PO4- 0.56490E-10 -10.2480 0.47060E-10 -10.3273 0.83308E+00 -0.0793 94 PO4-3 0.74100E-09 -9.1302 0.17453E-09 -9.7581 0.23553E+00 -0.6280 98 HP2O7-3 0.14173E-17 -17.8485 0.31751E-18 -18.4982 0.22402E+00 -0.6497 99 P2O7-4 0.95215E-17 -17.0213 0.69459E-18 -18.1583 0.72949E-01 -1.1370 100 H2S,aq 0.13518E-06 -6.8691 0.13466E-06 -6.8708 0.99616E+00 -0.0017 101 S2-2 0.34093E-10 -10.4673 0.17422E-10 -10.7589 0.51101E+00 -0.2916 102 S3-2 0.30551E-16 -16.5150 0.15612E-16 -16.8065 0.51101E+00 -0.2916 107 SO3-2 0.23252E-11 -11.6335 0.12061E-11 -11.9186 0.51872E+00 -0.2851 108 HSO3- 0.99092E-14 -14.0040 0.82470E-14 -14.0837 0.83226E+00 -0.0797 109 HSO4- 0.57797E-11 -11.2381 0.48247E-11 -11.3165 0.83476E+00 -0.0784 111 S2O3-2 0.14191E-12 -12.8480 0.72517E-13 -13.1396 0.51101E+00 -0.2916 Charge balance for all species = -.6130E-08 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.1303949E-09 -.1988163E-01 -.2000308E+02 0.0000 2 H2O 0.1000000E+01 0.5550217E+02 0.9980718E+06 0.0000 3 Cl- 0.2834606E-03 0.2847585E-03 0.1007720E+02 6.3345 4 SO4-- 0.8951148E-04 0.8956787E-04 0.8588403E+01 15.5848 5 HCO3- 0.7042340E-03 0.1623283E-02 0.9886826E+02 6.7304 6 HS- 0.4793254E-03 0.4795162E-03 0.1582975E+02 6.5627 7 Al+++ 0.1600620E-28 0.1818271E-05 0.4897057E-01 0.4394 8 H4SiO4 0.9962205E-03 0.1351700E-01 0.1296832E+04 -3.0016 9 Ca++ 0.5118973E-07 0.2316173E-06 0.9265896E-02 12.3387 10 Mg++ 0.2275841E-10 0.9314769E-10 0.2260493E-05 8.9846 11 Fe++ 0.9875066E-13 0.2058915E-07 0.1147754E-02 6.6225 12 K+ 0.1565780E-03 0.1572006E-03 0.6135691E+01 6.0775 13 Na+ 0.1994164E-01 0.2229425E-01 0.5116094E+03 8.1817 14 Mn++ 0.3820706E-10 0.2506629E-08 0.1374590E-03 9.2105 15 F- 0.8982652E-05 0.9011641E-05 0.1708922E+00 4.8345 16 HPO4-- 0.4560555E-07 0.4640304E-07 0.4445627E-02 12.2920 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.1787412E-01 -.1786153E-01 -.1259128E-04 0.0000000E+00 2 H2O 0.4986277E+02 0.4986279E+02 -.1254899E-04 0.0000000E+00 3 Cl- 0.2558252E-03 0.2558252E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.8046719E-04 0.8046719E-04 0.0000000E+00 0.0000000E+00 5 HCO3- 0.1458347E-02 0.1458347E-02 0.0000000E+00 0.0000000E+00 6 HS- 0.4307943E-03 0.4307943E-03 0.0000000E+00 0.0000000E+00 7 Al+++ 0.4775352E-05 0.1633523E-05 0.3141829E-05 0.0000000E+00 8 H4SiO4 0.1215302E-01 0.1214359E-01 0.9431125E-05 0.0000000E+00 9 Ca++ 0.2080835E-06 0.2080835E-06 0.0000000E+00 0.0000000E+00 10 Mg++ 0.8368328E-10 0.8368328E-10 0.0000000E+00 0.0000000E+00 11 Fe++ 0.3259227E-07 0.1849716E-07 0.1409511E-07 0.0000000E+00 12 K+ 0.1412294E-03 0.1412280E-03 0.1409511E-08 0.0000000E+00 13 Na+ 0.2003215E-01 0.2002901E-01 0.3136191E-05 0.0000000E+00 14 Mn++ 0.2251939E-08 0.2251939E-08 0.0000000E+00 0.0000000E+00 15 F- 0.8096000E-05 0.8096000E-05 0.0000000E+00 0.0000000E+00 16 HPO4-- 0.4168819E-07 0.4168819E-07 0.0000000E+00 0.0000000E+00 Chg. balance for solid moles: -.4235E-21 Mass of aqueous solution: 0.900028E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 0.0199900 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 0.3136E-05 -5.504 0.8224E-03 -3.085 99.63 0.3157E-03 stilpnomelane-Fe 0.2819E-08 -8.550 0.3039E-05 -5.517 0.3682 0.1050E-05 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 0.000825 g Volume = 0.000317 cm3 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.0199900 moles log = -1.6992 Original solution: 1000.0103000 g Original solution / Rock added: 50025.53 (Water/Rock Ratio), log = 4.6992 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0206 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9997E+00 0.9859 0.1006E+01 0.1020E+01 CO2,gas 0.1426E-04 1.0071 0.1465E-04 0.1455E-04 CH4,gas 0.7069E-05 1.0125 0.7305E-05 0.7214E-05 H2,gas 0.2603E-03 1.0005 0.2658E-03 0.2657E-03 H2S,gas 0.3642E-05 0.9960 0.3702E-05 0.3717E-05 S2,gas 0.7133E-23 1.0000 0.7280E-23 0.7280E-23 CO,gas 0.1017E-11 1.0000 0.1038E-11 0.1038E-11 SO3,gas 0.2025E-39 1.0000 0.2067E-39 0.2067E-39 SO2,gas 0.2095E-20 1.0000 0.2138E-20 0.2138E-20 HF,gas 0.1342E-13 1.0000 0.1369E-13 0.1369E-13 HCl,gas 0.8162E-17 1.0000 0.8330E-17 0.8330E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 17 albite -0.38 -0.38 0.00 0.000 0.11184E-10 165 stilpnomelane-Fe 13.02 13.02 0.00 0.000 0.21232E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -13.19 -6.53 -2.178 0.11155E+05 -4.834 3 CH4,gas 4.54 -2.29 -6.84 -1.709 0.11671E+05 -5.136 4 H2,gas 8.00 2.73 -5.27 -3.014 0.90059E+04 -3.575 5 H2S,gas -6.23 -13.36 -7.13 -3.565 0.12175E+05 -5.432 6 S2,gas -7.34 -32.17 -24.84 -3.821 0.42408E+05 -23.138 7 CO,gas 3.21 -10.47 -13.68 -4.210 0.23363E+05 -11.984 8 SO3,gas 17.12 -24.26 -41.38 -10.346 0.70661E+05 -39.685 9 SO2,gas 0.83 -21.54 -22.37 -5.965 0.38194E+05 -20.670 10 HF,gas 0.47 -15.09 -15.56 -7.781 0.26572E+05 -13.863 11 HCl,gas 5.19 -13.59 -18.78 -9.389 0.32063E+05 -17.079 12 acmite 7.71 7.44 -0.27 -0.028 0.46353E+03 16 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 20 spessartine 24.46 19.51 -4.95 -0.248 0.84554E+04 21 analcite 3.32 2.62 -0.70 -0.078 0.12022E+04 25 annite 20.12 17.38 -2.74 -0.152 0.46851E+04 26 phlogopite 27.06 24.47 -2.60 -0.144 0.44373E+04 31 apatite-OH -18.15 -20.97 -2.82 -0.217 0.48114E+04 32 apatite-F -34.30 -36.06 -1.76 -0.147 0.30041E+04 36 aragonite 0.97 -0.85 -1.82 -0.607 0.31091E+04 37 brucite 12.57 8.98 -3.58 -0.717 0.61195E+04 38 calcite 0.81 -0.85 -1.67 -0.555 0.28449E+04 39 carnegieite-low 9.02 5.62 -3.40 -0.486 0.58120E+04 40 carnegieite-high 10.09 5.62 -4.47 -0.639 0.76390E+04 41 carpholite-Mg 8.58 3.86 -4.72 -0.315 0.80627E+04 43 celadonite 5.34 3.49 -1.85 -0.109 0.31531E+04 44 celadonite-Fe 3.88 1.13 -2.74 -0.161 0.46848E+04 45 chrysotile 23.89 20.95 -2.94 -0.245 0.50230E+04 47 clinochlore 39.07 36.80 -2.27 -0.071 0.38803E+04 48 daphnite 28.97 24.99 -3.98 -0.124 0.67937E+04 52 chloritoid-Fe 9.17 4.50 -4.67 -0.312 0.79807E+04 53 chloritoid-Mn 11.40 7.09 -4.31 -0.288 0.73651E+04 55 coesite -2.38 -3.00 -0.63 -0.209 0.10682E+04 62 cristobalite -2.56 -3.00 -0.44 -0.147 0.75352E+03 64 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71260E+04 66 diaspore 2.87 0.44 -2.43 -0.406 0.41565E+04 67 diamond -3.10 -7.74 -4.64 -1.326 0.79227E+04 68 diopside 16.18 15.32 -0.86 -0.086 0.14706E+04 69 hedenbergite 14.21 12.96 -1.25 -0.125 0.21349E+04 76 epidote 24.67 21.81 -2.86 -0.139 0.48812E+04 78 epidote-Fe 29.84 26.63 -3.21 -0.167 0.54796E+04 79 fayalite 14.05 10.24 -3.80 -0.543 0.64924E+04 80 ferrosilite 11.15 7.24 -3.91 -0.391 0.66723E+04 84 gibbsite 4.08 0.44 -3.64 -0.520 0.62151E+04 85 glaucophane 22.97 20.18 -2.79 -0.075 0.47672E+04 86 glaucophane-Fe 17.28 13.10 -4.18 -0.113 0.71360E+04 87 graphite -3.55 -7.74 -4.20 -1.199 0.71649E+04 88 greenalite 16.14 13.86 -2.28 -0.190 0.38849E+04 91 hematite 12.57 10.52 -2.05 -0.248 0.34943E+04 92 heulandite -5.83 -7.79 -1.97 -0.089 0.33582E+04 96 jadeite 4.22 2.62 -1.60 -0.160 0.27277E+04 97 julgoldite 70.43 65.63 -4.80 -0.125 0.81914E+04 98 kalsilite 7.58 3.52 -4.07 -0.581 0.69471E+04 99 kaolinite -1.33 -5.12 -3.79 -0.345 0.64743E+04 102 laumontite 2.88 1.21 -1.67 -0.111 0.28557E+04 103 lawsonite 9.62 7.21 -2.40 -0.160 0.41011E+04 104 leucite 4.12 0.51 -3.61 -0.361 0.61559E+04 106 lizardite 23.24 20.95 -2.29 -0.191 0.39157E+04 107 magnesite 0.69 -4.21 -4.90 -1.633 0.83651E+04 108 magnetite 20.09 17.14 -2.95 -0.240 0.50288E+04 109 minnesotaite 10.39 7.86 -2.53 -0.149 0.43150E+04 113 manganosite 14.06 9.21 -4.85 -1.212 0.82772E+04 117 microcline -2.49 -2.49 0.00 0.000 0.26482E+01 121 muscovite 2.58 -1.61 -4.19 -0.247 0.71572E+04 122 paragonite 4.24 0.49 -3.74 -0.220 0.63937E+04 123 nepheline 8.34 5.62 -2.72 -0.389 0.46444E+04 135 phlogopite-Na 29.65 26.57 -3.08 -0.171 0.52535E+04 137 prehnite 19.37 16.55 -2.82 -0.166 0.48160E+04 138 prehnite-Fe 22.50 21.37 -1.13 -0.068 0.19228E+04 143 pyrite -21.25 -22.82 -1.58 -0.371 0.26935E+04 144 pyrrhotite -4.26 -6.74 -2.48 -0.826 0.42310E+04 145 pyrrhotiteFe0.875 -6.02 -7.90 -1.89 -0.694 0.32222E+04 146 pyroxmangite 7.40 6.21 -1.19 -0.238 0.20316E+04 147 pyrophyllite -6.18 -11.13 -4.95 -0.310 0.84554E+04 148 quartz -2.99 -3.00 -0.01 -0.004 0.20848E+02 152 rhodochrosite -0.98 -3.98 -3.01 -1.002 0.51332E+04 153 rhodonite 7.45 6.21 -1.24 -0.247 0.21118E+04 154 sanidine -1.28 -2.49 -1.21 -0.093 0.20704E+04 156 siderite -2.61 -6.57 -3.96 -1.321 0.67658E+04 164 stilbite -7.52 -7.79 -0.27 -0.013 0.46436E+03 166 stilpnomelane-Mg 27.44 24.83 -2.61 -0.078 0.44632E+04 172 talc 16.49 14.95 -1.54 -0.091 0.26359E+04 175 tephroite 18.09 15.42 -2.67 -0.381 0.45529E+04 179 tridymite -2.63 -3.00 -0.38 -0.125 0.64082E+03 180 tremolite 47.87 45.59 -2.28 -0.062 0.38961E+04 181 ferroactinolite 38.45 33.78 -4.68 -0.126 0.79832E+04 182 troilite-low -4.41 -6.74 -2.33 -0.776 0.39739E+04 188 wairakite 3.95 1.21 -2.74 -0.161 0.46777E+04 189 walstromite 11.51 9.34 -2.17 -0.434 0.37088E+04 190 wollastonite 10.46 9.34 -1.12 -0.225 0.19193E+04 191 pseudo-wollastonite 11.00 9.34 -1.66 -0.333 0.28391E+04 193 akaganeite 7.75 5.26 -2.49 -0.539 0.42597E+04 200 chalcedony -2.80 -3.00 -0.20 -0.066 0.34014E+03 202 montmorillonite-Ca -2.29 -6.27 -3.98 -0.246 0.67979E+04 203 montmorillonite-K -2.24 -6.30 -4.07 -0.249 0.69419E+04 204 montmorillonite-Mg -2.48 -6.83 -4.35 -0.269 0.74199E+04 205 montmorillonite-Na -2.04 -5.61 -3.57 -0.219 0.60959E+04 206 nontronite-Ca 3.21 1.68 -1.53 -0.099 0.26124E+04 207 nontronite-H 2.53 -0.35 -2.88 -0.193 0.49244E+04 208 nontronite-K 3.34 1.65 -1.69 -0.108 0.28796E+04 209 nontronite-Mg 3.07 1.13 -1.94 -0.126 0.33185E+04 210 nontronite-Na 3.52 2.35 -1.17 -0.075 0.19996E+04 226 tobermorite 9.82 7.28 -2.55 -0.695 0.43481E+04 232 alabandite -0.98 -4.15 -3.17 -1.057 0.54168E+04 235 boehmite 4.41 0.44 -3.97 -0.661 0.67735E+04 237 ferrous-oxide 9.81 6.62 -3.19 -0.797 0.54452E+04 243 silica-amorphous -2.09 -3.00 -0.91 -0.303 0.15543E+04 245 an20ab80 2.02 1.14 -0.88 -0.068 0.15060E+04 246 an25ab75 2.65 1.52 -1.13 -0.087 0.19295E+04 247 an30ab70 3.28 1.90 -1.38 -0.106 0.23626E+04 248 tr.625ac.25prg.125 45.16 43.45 -1.72 -0.046 0.29285E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 0.0004000 MOLES Current total amount of reactant added: 0.0199900 MOLES New total amount of reactant added: 0.0203900 MOLES Mixing fraction reached given limit of 0.2000E-01 TOTMIX = 0.2039E-01 Execution stopped.