File SKIP_SPECIES.TXT lists species and minerals omitted from the calculations due to given T, P, option switches, or suppression in CHIMRUN, or are suppressed in the SOLTHERM database. It also lists minerals for which density is not specified in SOLTHERM. This is an extended P(to 5 kB), T(to 600 C) run (CON_FLAG = 1). methanol,aq is suppressed in SOLTHERM data file. methanol,aq is suppressed in SOLTHERM data file. CuCl4-3 is suppressed in SOLTHERM data file. H2BO3- is suppressed in SOLTHERM data file. UO2CO3,aq is suppressed in SOLTHERM data file. UO2SO4,aq is suppressed in SOLTHERM data file. UO2Cl2,aq is suppressed in SOLTHERM data file. UO2F2,aq is suppressed in SOLTHERM data file. PO4-3 is suppressed in SOLTHERM data file. H2PO4- is suppressed in SOLTHERM data file. H3PO4 is suppressed in SOLTHERM data file. O2,gas is suppressed in THIS RUN. O2,gas is suppressed in THIS RUN. amesite is suppressed in SOLTHERM data file. antigorite is suppressed in SOLTHERM data file. goethite is suppressed in THIS RUN. goethite is suppressed in THIS RUN. riebeckite is suppressed in THIS RUN. riebeckite is suppressed in THIS RUN. sapphirine-Fe(221) is suppressed in SOLTHERM data file. sapphirine(221) is suppressed in SOLTHERM data file. talc-prl is suppressed in SOLTHERM data file. PrO1.833(s) is suppressed in SOLTHERM data file. niter-NH4 is suppressed in SOLTHERM data file. FMQ_HS-1 is suppressed in THIS RUN. kf-ab-equil is suppressed in THIS RUN. ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Species No. Charge Tot.moles Trial molality Gamma Mixing solution H+ 1 1. -0.17874E-01 0.13039E-09 0.8375 0.00000000E+00 H2O 2 0. 0.49863E+02 0.10000E+01 1.0000 0.00000000E+00 Cl- 3 -1. 0.25583E-03 0.28346E-03 0.8323 0.00000000E+00 SO4-- 4 -2. 0.80467E-04 0.89511E-04 0.5121 0.00000000E+00 HCO3- 5 -1. 0.14583E-02 0.70423E-03 0.8335 0.00000000E+00 HS- 6 -1. 0.43079E-03 0.47933E-03 0.8324 0.00000000E+00 Al+++ 7 3. 0.47754E-05 0.16006E-28 0.2238 0.00000000E+00 H4SiO4 8 0. 0.12153E-01 0.99622E-03 1.0000 0.00000000E+00 Ca++ 9 2. 0.20808E-06 0.51190E-07 0.5082 0.00000000E+00 Mg++ 10 2. 0.83683E-10 0.22758E-10 0.5058 0.00000000E+00 Fe++ 11 2. 0.32592E-07 0.98751E-13 0.5064 0.00000000E+00 K+ 12 1. 0.14123E-03 0.15658E-03 0.8337 0.00000000E+00 Na+ 13 1. 0.20032E-01 0.19942E-01 0.8321 0.00000000E+00 Mn++ 14 2. 0.22519E-08 0.38207E-10 0.5068 0.00000000E+00 F- 15 -1. 0.80960E-05 0.89827E-05 0.8305 0.00000000E+00 HPO4-- 16 -2. 0.41688E-07 0.45606E-07 0.5122 0.00000000E+00 Chg. balance for total moles = -.5508E-08 Max. difference allowed = 0.2558E-07 The following parameters were given: ERPC = 0.1000E-11 pH = 0.0000 PFLUID = 50.0000 SLIM = 0.400000E-01 TEMP = 100.0000 SINC = 0.1000E-02 TEMPC = 0.0000 TOTMIX = 0.199900E-01 ENTH = 0.0000 SENTH = 0.0000 DENTH = 0.0000 TOTWAT = 90.0000 SOLMIN = 0.0000E+00 RM = 0.0000 AQGRM = 1000.0103 SUPRNT = 0.1000E-19 VBOX-1 = 400.9996 RHOFRS = 0.0000 RHOROC = 2.5000 The following options were selected: CONFLG = 1 C = 3 IFRAC = 0 IPUNCH = 2 NLOOP = 400 ISTEP = 2 LIMSOL = 1 LOOC = 0 IENTH = 0 ITREF = 0 IDEAL = 0 IPSAT = 1 INCREM = 0 INCP = 0 MINSOL = 3 NEUT = 0 AWAT = 0 CHGF = 0 Of the derived species, only those with molality > 0.10E-19 will appear in the output Species No. Charge Log K(diss) Species No. Charge Log K(diss) SiF6-2 17 -2. -24.5019 Mn+3 70 3. 19.1453 HSiO3- 18 -1. 9.0298 MnF+ 71 1. -1.2264 Ca(HSiO3)+ 19 1. 7.6723 MnO,aq 72 0. 17.9848 Mg(HSiO3)+ 20 1. 7.5773 MnOH+ 73 1. 8.5194 NaHSiO3,aq 21 0. 7.8210 MnO2-2 74 -2. 40.4638 AlO+ 22 1. 6.8663 HMnO2- 75 -1. 29.1232 AlOH+2 23 2. 3.1691 MnO4- 76 -1. 83.3111 HAlO2,aq 24 0. 10.5671 MnO4-2 77 -2. 81.3005 AlO2- 25 -1. 16.2221 MnCl+ 78 1. -0.7894 CH4,aq 26 0. 6.0126 MnSO4,aq 79 0. -2.4604 C2H6,aq 27 0. 12.3733 NaCl,aq 80 0. 0.4796 C3H8,aq 28 0. 17.3707 NaF,aq 81 0. 0.6306 C4H10,aq 29 0. 22.3757 NaOH,aq 82 0. 12.3669 ethanol,aq 30 0. 15.3258 O2,aq 83 0. 53.5502 CO,aq 31 0. 4.6892 OH- 84 -1. 12.2382 CO2,aq 32 0. -6.3298 HO2- 85 -1. 50.8010 CO3-2 33 -2. 10.0588 H2O2,aq 86 0. 40.0166 CaCO3,aq 34 0. 5.9605 H3PO2,aq 87 0. 24.3066 Ca(HCO3)+ 35 1. -1.4070 H2PO2- 88 -1. 26.5366 CaCl+ 36 1. -0.2091 HPO3-2 89 -2. 11.9254 CaCl2,aq 37 0. 0.4151 H3PO3,aq 90 0. 3.5792 CaF+ 38 1. -1.1644 H2PO3- 91 -1. 5.6232 CaOH+ 39 1. 10.1471 H3PO4,aq 92 0. -9.8447 CaSO4,aq 40 0. -2.5018 H2PO4- 93 -1. -7.2659 HCl,aq 41 0. 0.7370 PO4-3 94 -3. 12.0884 HClO,aq 42 0. 32.4260 H4P2O7,aq 95 0. -17.8095 ClO- 43 -1. 39.6530 H3P2O7- 96 -1. -15.9156 HClO2,aq 44 0. 70.1812 H2P2O7-2 97 -2. -13.4262 HF,aq 45 0. -3.8354 HP2O7-3 98 -3. -6.7266 HF2- 46 -1. -3.3639 P2O7-4 99 -4. 2.8952 Fe+3 47 3. 8.3809 H2S,aq 100 0. -6.4900 FeCl+ 48 1. -0.1994 S2-2 101 -2. 1.2355 FeCl2,aq 49 0. 4.3001 S3-2 102 -2. -8.8031 FeCl+2 50 2. 6.5269 S3- 103 -1. -16.3389 FeF+ 51 1. -1.7084 S4-2 104 -2. -18.6615 FeF+2 52 2. 1.4309 S5-2 105 -2. -28.3439 FeO,aq 53 0. 16.4104 SO2,aq 106 0. -0.2309 FeOH+ 54 1. 7.4874 SO3-2 107 -2. 10.3052 HFeO2- 55 -1. 24.3908 HSO3- 108 -1. 2.5086 FeO+ 56 1. 11.4004 HSO4- 109 -1. -2.9839 FeOH+2 57 2. 9.1194 HSO5- 110 -1. 38.8366 FeO2- 58 -1. 24.0895 S2O3-2 111 -2. -4.5600 HFeO2,aq 59 0. 15.9850 HS2O3- 112 -1. -6.8123 H2,aq 60 0. 9.4190 H2S2O3,aq 113 0. -8.0173 KCl,aq 61 0. 1.7417 S2O4-2 114 -2. 10.5541 KHSO4,aq 62 0. -0.4514 HS2O4- 115 -1. 7.6551 KOH,aq 63 0. 12.3695 H2S2O4,aq 116 0. 6.6259 KSO4- 64 -1. -1.1908 S2O5-2 117 -2. 10.0741 MgCO3,aq 65 0. 6.5614 S2O6-2 118 -2. 11.5521 Mg(HCO3)+ 66 1. -1.4164 S2O8-2 119 -2. 42.0620 MgCl+ 67 1. -0.1664 S3O6-2 120 -2. 3.7866 MgF+ 68 1. -1.7331 S4O6-2 121 -2. -17.8657 MgOH+ 69 1. 9.4041 S5O6-2 122 -2. -14.1333 For mixed gases (JSOLS=6), log K(hydrol) = log (K*P) Log K Trial Log K Trial Mineral No. hydrol Moles Mineral No. hydrol Moles H2O,gas 1 1.696 0.0000E+00 osumilite(1) 126 21.717 0.0000E+00 CO2,gas 2 -6.660 0.0000E+00 osumilite(2) 127 20.667 0.0000E+00 CH4,gas 3 4.544 0.0000E+00 osumilite-Fe 128 14.390 0.0000E+00 H2,gas 4 8.000 0.0000E+00 pargasite 129 65.092 0.0000E+00 H2S,gas 5 -6.230 0.0000E+00 periclase 130 16.138 0.0000E+00 S2,gas 6 -7.335 0.0000E+00 periclase-Fe 131 11.627 0.0000E+00 CO,gas 7 3.215 0.0000E+00 perovskite-Al 132 12.344 0.0000E+00 SO3,gas 8 17.121 0.0000E+00 perovskite-Ca 133 23.807 0.0000E+00 SO2,gas 9 0.832 0.0000E+00 perovskite-Fe 134 21.143 0.0000E+00 HF,gas 10 0.473 0.0000E+00 perovskite-Mg 135 23.119 0.0000E+00 HCl,gas 11 5.189 0.0000E+00 phase_A 136 80.189 0.0000E+00 acmite 12 7.710 0.0000E+00 phlogopite-Na 137 29.647 0.0000E+00 akermanite 13 36.442 0.0000E+00 piemontite(ordered) 138 33.776 0.0000E+00 akimotoite 14 16.591 0.0000E+00 prehnite 139 19.372 0.0000E+00 akimotoite-Fe 15 13.067 0.0000E+00 prehnite-Fe 140 22.498 0.0000E+00 albite-high 16 0.693 0.0000E+00 pumpellyite-Fe 141 46.269 0.0000E+00 albite 17 -0.384 0.3136E-05 pumpellyite-Mg 142 48.995 0.0000E+00 almandine 18 24.442 0.0000E+00 px-Mg-tschermaks 143 19.616 0.0000E+00 pyrope 19 37.248 0.0000E+00 px-Ca-tschermaks 144 18.610 0.0000E+00 spessartine 20 24.457 0.0000E+00 pyrite 145 -21.247 0.0000E+00 analcite 21 3.322 0.0000E+00 pyrrhotite 146 -4.260 0.0000E+00 andalusite 22 5.002 0.0000E+00 pyrrhotiteFe0.875 147 -6.017 0.0000E+00 andradite 23 39.009 0.0000E+00 pyroxmangite 148 7.399 0.0000E+00 grossular 24 32.731 0.0000E+00 pyrophyllite 149 -6.176 0.0000E+00 anhydrite 25 -5.317 0.0000E+00 quartz 150 -2.989 0.0000E+00 ankerite 26 -2.135 0.0000E+00 rankinite 151 40.713 0.0000E+00 annite 27 20.123 0.0000E+00 ringwoodite-Fe 152 15.456 0.0000E+00 phlogopite 28 27.065 0.0000E+00 ringwoodite-Mg 153 27.575 0.0000E+00 biotite-Mn 29 32.960 0.0000E+00 rhodochrosite 154 -0.976 0.0000E+00 anorthite 30 12.710 0.0000E+00 rhodonite 155 7.446 0.0000E+00 anthophyllite 31 51.852 0.0000E+00 sanidine 156 -1.275 0.0000E+00 anthophyllite-Fe 32 29.306 0.0000E+00 sapphirine(351) 157 78.899 0.0000E+00 apatite-OH 33 -18.153 0.0000E+00 siderite 158 -2.608 0.0000E+00 apatite-F 34 -34.301 0.0000E+00 sillimanite 159 5.262 0.0000E+00 apatite-OH-zs 35 -12.736 0.0000E+00 sodalite 160 49.976 0.0000E+00 apatite-F-zs 36 -27.774 0.0000E+00 spinel 161 20.870 0.0000E+00 apatite-Cl-zs 37 -16.674 0.0000E+00 spurrite 162 59.482 0.0000E+00 aragonite 38 0.967 0.0000E+00 staurolite-Fe 163 73.598 0.0000E+00 brucite 39 12.569 0.0000E+00 staurolite-Mg 164 89.802 0.0000E+00 calcite 40 0.812 0.0000E+00 staurolite-Mn 165 83.909 0.0000E+00 carnegieite-low 41 9.023 0.0000E+00 stilbite 166 -7.522 0.0000E+00 carnegieite-high 42 10.093 0.0000E+00 stilpnomelane-Fe 167 13.017 0.2819E-08 carpholite-Mg 43 8.582 0.0000E+00 stilpnomelane-Mg 168 27.441 0.0000E+00 carpholite-Fe 44 6.713 0.0000E+00 stishovite 169 2.720 0.0000E+00 celadonite 45 5.342 0.0000E+00 sudoite-Fe 170 18.296 0.0000E+00 celadonite-Fe 46 3.877 0.0000E+00 sudoite 171 21.077 0.0000E+00 chrysotile 47 23.892 0.0000E+00 sulfur 172 -9.152 0.0000E+00 chondrodite 48 56.475 0.0000E+00 sylvite 173 1.338 0.0000E+00 clinochlore 49 39.070 0.0000E+00 talc 174 16.491 0.0000E+00 daphnite 50 28.965 0.0000E+00 talc-Fe 175 13.448 0.0000E+00 chlorite-Mn 51 46.869 0.0000E+00 talc-tschermaks 176 19.091 0.0000E+00 chlorite-Al-free 52 47.173 0.0000E+00 tephroite 177 18.086 0.0000E+00 chloritoid-Mg 53 13.198 0.0000E+00 tilleyite 178 41.377 0.0000E+00 chloritoid-Fe 54 9.174 0.0000E+00 titanite-CaSi 179 15.479 0.0000E+00 chloritoid-Mn 55 11.401 0.0000E+00 topaz-H 180 4.618 0.0000E+00 clinohumite 56 97.128 0.0000E+00 tridymite 181 -2.626 0.0000E+00 coesite 57 -2.376 0.0000E+00 tremolite 182 47.869 0.0000E+00 cordierite-H 58 23.715 0.0000E+00 ferroactinolite 183 38.452 0.0000E+00 cordierite 59 24.049 0.0000E+00 troilite-low 184 -4.411 0.0000E+00 cordierite-Fe 60 20.450 0.0000E+00 tschermakite 185 48.210 0.0000E+00 cordierite-Mn 61 25.066 0.0000E+00 vesuvianite 186 223.471 0.0000E+00 corundum 62 8.383 0.0000E+00 wadeite-Si 187 20.216 0.0000E+00 corundum-MgSi 63 18.891 0.0000E+00 wadsleyite-Fe 188 15.680 0.0000E+00 cristobalite 64 -2.560 0.0000E+00 wadsleyite-Mg 189 25.850 0.0000E+00 cummingtonite 65 52.099 0.0000E+00 wairakite 190 3.950 0.0000E+00 cymrite-K 66 1.685 0.0000E+00 walstromite 191 11.509 0.0000E+00 deerite 67 95.671 0.0000E+00 wollastonite 192 10.461 0.0000E+00 diaspore 68 2.874 0.0000E+00 pseudo-wollastonite 193 11.000 0.0000E+00 diamond 69 -3.102 0.0000E+00 zoisite 194 22.849 0.0000E+00 diopside 70 16.181 0.0000E+00 akaganeite 195 7.755 0.0000E+00 hedenbergite 71 14.208 0.0000E+00 beidellite-Ca 196 -1.646 0.0000E+00 dolomite,ordered 72 0.546 0.0000E+00 beidellite-H 197 -2.326 0.0000E+00 eastonite 73 28.489 0.0000E+00 beidellite-K 198 -1.520 0.0000E+00 enstatite 74 17.265 0.0000E+00 beidellite-Mg 199 -1.790 0.0000E+00 clinoenstatite-HiP 75 18.354 0.0000E+00 beidellite-Na 200 -1.342 0.0000E+00 clinoenstatite 76 17.166 0.0000E+00 calcium 201 84.026 0.0000E+00 protoenstatite 77 17.824 0.0000E+00 chalcedony 202 -2.802 0.0000E+00 epidote 78 24.670 0.0000E+00 dawsonite 203 1.682 0.0000E+00 clinozoisite 79 22.806 0.0000E+00 montmorillonite-Ca 204 -2.291 0.0000E+00 epidote-Fe 80 29.841 0.0000E+00 montmorillonite-K 205 -2.237 0.0000E+00 fayalite 81 14.046 0.0000E+00 montmorillonite-Mg 206 -2.480 0.0000E+00 ferrosilite 82 11.149 0.0000E+00 montmorillonite-Na 207 -2.038 0.0000E+00 forsterite 83 21.016 0.0000E+00 nontronite-Ca 208 3.215 0.0000E+00 gedrite 84 50.522 0.0000E+00 nontronite-H 209 2.533 0.0000E+00 gehlenite 85 36.628 0.0000E+00 nontronite-K 210 3.341 0.0000E+00 gibbsite 86 4.079 0.0000E+00 nontronite-Mg 211 3.075 0.0000E+00 glaucophane 87 22.975 0.0000E+00 nontronite-Na 212 3.520 0.0000E+00 glaucophane-Fe 88 17.276 0.0000E+00 sepiolite 213 24.118 0.0000E+00 graphite 89 -3.546 0.0000E+00 topaz 214 -16.546 0.0000E+00 greenalite 90 16.140 0.0000E+00 alite 215 57.999 0.0000E+00 grunerite 91 31.215 0.0000E+00 belite 216 30.433 0.0000E+00 halite 92 1.575 0.0000E+00 ettringite 217 43.232 0.0000E+00 hematite 93 12.566 0.0000E+00 gypsum 218 -4.955 0.0000E+00 heulandite 94 -5.827 0.0000E+00 hemicarboaluminate 219 70.954 0.0000E+00 hercynite 95 17.279 0.0000E+00 hydrogarnet 220 60.662 0.0000E+00 hollandite 96 25.673 0.0000E+00 hydrogarnet-Si 221 50.586 0.0000E+00 iron 97 19.086 0.0000E+00 jennite 222 24.367 0.0000E+00 jadeite 98 4.215 0.0000E+00 monosulfoaluminate 223 53.400 0.0000E+00 julgoldite 99 70.427 0.0000E+00 monocarboaluminate 224 61.898 0.0000E+00 kalsilite 100 7.584 0.0000E+00 portlandite 225 18.272 0.0000E+00 kaolinite 101 -1.333 0.0000E+00 stratlingite 226 36.502 0.0000E+00 kyanite 102 4.876 0.0000E+00 tricarboaluminate 227 70.370 0.0000E+00 larnite-bredigite 103 30.686 0.0000E+00 tobermorite 228 9.823 0.0000E+00 laumontite 104 2.883 0.0000E+00 C4AH13 229 81.816 0.0000E+00 lawsonite 105 9.616 0.0000E+00 C2AH8 230 45.203 0.0000E+00 leucite 106 4.119 0.0000E+00 C3A 231 86.953 0.0000E+00 lime 107 25.998 0.0000E+00 C4AF 232 117.416 0.0000E+00 lizardite 108 23.244 0.0000E+00 CAH10 233 28.335 0.0000E+00 magnesite 109 0.691 0.0000E+00 alabandite 234 -0.978 0.0000E+00 magnetite 110 20.087 0.0000E+00 alunite 235 -10.435 0.0000E+00 minnesotaite 111 10.388 0.0000E+00 artinite 236 15.121 0.0000E+00 minnesotaite-Mg 112 20.602 0.0000E+00 boehmite 237 4.406 0.0000E+00 magnesioferrite 113 26.212 0.0000E+00 dolomite,disordered 238 1.247 0.0000E+00 majorite 114 53.251 0.0000E+00 ferrous-oxide 239 9.812 0.0000E+00 manganosite 115 14.058 0.0000E+00 fluorite 240 -9.931 0.0000E+00 margarite 116 17.324 0.0000E+00 huntite 241 3.770 0.0000E+00 meionite 117 44.874 0.0000E+00 hydromagnesite 242 19.995 0.0000E+00 merwinite 118 55.930 0.0000E+00 nesquehonite 243 4.723 0.0000E+00 microcline 119 -2.486 0.0000E+00 potassium-oxide 244 69.038 0.0000E+00 monticellite 120 24.339 0.0000E+00 silica-amorphous 245 -2.091 0.0000E+00 mullite-Al 121 363.148 0.0000E+00 sodium-oxide 246 55.169 0.0000E+00 mullite-Si 122 7.264 0.0000E+00 an20ab80 247 2.018 0.0000E+00 muscovite 123 2.582 0.0000E+00 an25ab75 248 2.646 0.0000E+00 paragonite 124 4.239 0.0000E+00 an30ab70 249 3.279 0.0000E+00 nepheline 125 8.339 0.0000E+00 tr.625ac.25prg.125 250 45.165 0.0000E+00 Initial composition of reactant (mole%): H2O 88.87 HCl 0.5900 CO2 7.070 CO 0.1600 H2 1.540 S2 0.8000E-01 SO2 1.150 HF 0.4000E-01 H2S 1.120 0.000 Sum of wt% of reactants: 100.6200 Reactant consumed: 0.0199900 moles log = -1.6992 Original solution: 1000.0103000 g Original solution / Rock added: 50025.53 (Water/Rock Ratio), log = 4.6992 The following minerals and/or gases with identical index are in solid solution: H2O,gas 6 CO2,gas 6 CH4,gas 6 H2,gas 6 H2S,gas 6 S2,gas 6 CO,gas 6 SO3,gas 6 SO2,gas 6 HF,gas 6 HCl,gas 6 almandine 16 pyrope 16 spessartine 16 andradite 8 grossular 8 annite 15 phlogopite 15 biotite-Mn 15 clinochlore 1 daphnite 1 chlorite-Mn 1 diopside 5 hedenbergite 5 epidote 3 clinozoisite 3 iron 9 magnetite 14 talc 7 talc-Fe 7 tremolite 2 ferroactinolite 2 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 10 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 0.0199900 Water: Moles liquid = 0.4987E+02 kg liquid = 0.8984E+00 Moles total = 0.4986E+02 kg total = 0.8983E+00 Activity = 1.0000 Stoichiometric ionic strength = .1261332E-01 Osmotic coef. = 0.9397 True ionic strength = .2110672E-01 Chg. balance for total moles = -.5508E-08 Max. difference allowed = 0.2558E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.13039E-09 -9.8847 0.10921E-09 -9.9618 0.83750E+00 -0.0770 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.28346E-03 -3.5475 0.23591E-03 -3.6273 0.83226E+00 -0.0797 4 SO4-- 0.89511E-04 -4.0481 0.45843E-04 -4.3387 0.51215E+00 -0.2906 5 HCO3- 0.70423E-03 -3.1523 0.58700E-03 -3.2314 0.83352E+00 -0.0791 6 HS- 0.47933E-03 -3.3194 0.39898E-03 -3.3990 0.83238E+00 -0.0797 7 Al+++ 0.16006E-28 -28.7957 0.35819E-29 -29.4459 0.22378E+00 -0.6502 8 H4SiO4 0.99622E-03 -3.0016 0.99622E-03 -3.0016 0.10000E+01 0.0000 9 Ca++ 0.51190E-07 -7.2908 0.26016E-07 -7.5848 0.50823E+00 -0.2939 10 Mg++ 0.22758E-10 -10.6429 0.11511E-10 -10.9389 0.50580E+00 -0.2960 11 Fe++ 0.98751E-13 -13.0055 0.50005E-13 -13.3010 0.50638E+00 -0.2955 12 K+ 0.15658E-03 -3.8053 0.13054E-03 -3.8842 0.83373E+00 -0.0790 13 Na+ 0.19942E-01 -1.7002 0.16593E-01 -1.7801 0.83210E+00 -0.0798 14 Mn++ 0.38207E-10 -10.4179 0.19364E-10 -10.7130 0.50682E+00 -0.2951 15 F- 0.89827E-05 -5.0466 0.74598E-05 -5.1273 0.83047E+00 -0.0807 16 HPO4-- 0.45606E-07 -7.3410 0.23360E-07 -7.6315 0.51222E+00 -0.2905 18 HSiO3- 0.10235E-01 -1.9899 0.85179E-02 -2.0697 0.83226E+00 -0.0797 19 Ca(HSiO3)+ 0.60518E-08 -8.2181 0.50467E-08 -8.2970 0.83392E+00 -0.0789 20 Mg(HSiO3)+ 0.33325E-11 -11.4772 0.27790E-11 -11.5561 0.83392E+00 -0.0789 21 NaHSiO3,aq 0.22860E-02 -2.6409 0.22860E-02 -2.6409 0.10000E+01 0.0000 22 AlO+ 0.48998E-16 -16.3098 0.40860E-16 -16.3887 0.83392E+00 -0.0789 24 HAlO2,aq 0.74513E-10 -10.1278 0.74513E-10 -10.1278 0.10000E+01 0.0000 25 AlO2- 0.18182E-05 -5.7404 0.15104E-05 -5.8209 0.83069E+00 -0.0806 26 CH4,aq 0.49817E-08 -8.3026 0.49625E-08 -8.3043 0.99616E+00 -0.0017 27 C2H6,aq 0.20875E-19 -19.6804 0.20795E-19 -19.6820 0.99616E+00 -0.0017 31 CO,aq 0.69665E-15 -15.1570 0.69665E-15 -15.1570 0.10000E+01 0.0000 32 CO2,aq 0.13750E-06 -6.8617 0.13697E-06 -6.8634 0.99616E+00 -0.0017 33 CO3-2 0.91875E-03 -3.0368 0.46950E-03 -3.3284 0.51101E+00 -0.2916 34 CaCO3,aq 0.15315E-06 -6.8149 0.15315E-06 -6.8149 0.10000E+01 0.0000 35 Ca(HCO3)+ 0.46745E-09 -9.3303 0.38981E-09 -9.4091 0.83392E+00 -0.0789 36 CaCl+ 0.11910E-10 -10.9241 0.99323E-11 -11.0029 0.83392E+00 -0.0789 37 CaCl2,aq 0.55668E-15 -15.2544 0.55668E-15 -15.2544 0.10000E+01 0.0000 38 CaF+ 0.33978E-11 -11.4688 0.28335E-11 -11.5477 0.83392E+00 -0.0789 39 CaOH+ 0.20360E-07 -7.6912 0.16978E-07 -7.7701 0.83392E+00 -0.0789 40 CaSO4,aq 0.37872E-09 -9.4217 0.37872E-09 -9.4217 0.10000E+01 0.0000 41 HCl,aq 0.47210E-14 -14.3260 0.47210E-14 -14.3260 0.10000E+01 0.0000 45 HF,aq 0.55769E-11 -11.2536 0.55769E-11 -11.2536 0.10000E+01 0.0000 46 HF2- 0.16877E-16 -16.7727 0.14046E-16 -16.8524 0.83226E+00 -0.0797 48 FeCl+ 0.22391E-16 -16.6499 0.18672E-16 -16.7288 0.83392E+00 -0.0789 51 FeF+ 0.22859E-16 -16.6409 0.19062E-16 -16.7198 0.83392E+00 -0.0789 53 FeO,aq 0.16296E-09 -9.7879 0.16296E-09 -9.7879 0.10000E+01 0.0000 54 FeOH+ 0.17874E-10 -10.7478 0.14905E-10 -10.8267 0.83392E+00 -0.0789 55 HFeO2- 0.18761E-07 -7.7268 0.15614E-07 -7.8065 0.83226E+00 -0.0797 56 FeO+ 0.94747E-16 -16.0234 0.79011E-16 -16.1023 0.83392E+00 -0.0789 58 FeO2- 0.16289E-08 -8.7881 0.13556E-08 -8.8679 0.83226E+00 -0.0797 59 HFeO2,aq 0.18829E-10 -10.7252 0.18829E-10 -10.7252 0.10000E+01 0.0000 60 H2,aq 0.20324E-06 -6.6920 0.20246E-06 -6.6937 0.99616E+00 -0.0017 61 KCl,aq 0.55817E-09 -9.2532 0.55817E-09 -9.2532 0.10000E+01 0.0000 62 KHSO4,aq 0.18478E-17 -17.7333 0.18478E-17 -17.7333 0.10000E+01 0.0000 63 KOH,aq 0.51050E-06 -6.2920 0.51050E-06 -6.2920 0.10000E+01 0.0000 64 KSO4- 0.11158E-06 -6.9524 0.92865E-07 -7.0321 0.83226E+00 -0.0797 65 MgCO3,aq 0.16986E-10 -10.7699 0.16986E-10 -10.7699 0.10000E+01 0.0000 66 Mg(HCO3)+ 0.21134E-12 -12.6750 0.17624E-12 -12.7539 0.83392E+00 -0.0789 67 MgCl+ 0.47764E-14 -14.3209 0.39832E-14 -14.3998 0.83392E+00 -0.0789 68 MgF+ 0.55692E-14 -14.2542 0.46442E-14 -14.3331 0.83392E+00 -0.0789 69 MgOH+ 0.49849E-10 -10.3023 0.41570E-10 -10.3812 0.83392E+00 -0.0789 71 MnF+ 0.29177E-14 -14.5350 0.24331E-14 -14.6138 0.83392E+00 -0.0789 72 MnO,aq 0.16815E-08 -8.7743 0.16815E-08 -8.7743 0.10000E+01 0.0000 73 MnOH+ 0.64297E-09 -9.1918 0.53618E-09 -9.2707 0.83392E+00 -0.0789 74 MnO2-2 0.91567E-11 -11.0383 0.46792E-11 -11.3298 0.51101E+00 -0.2916 75 HMnO2- 0.13452E-09 -9.8712 0.11195E-09 -9.9510 0.83226E+00 -0.0797 78 MnCl+ 0.33733E-13 -13.4719 0.28131E-13 -13.5508 0.83392E+00 -0.0789 79 MnSO4,aq 0.25627E-12 -12.5913 0.25627E-12 -12.5913 0.10000E+01 0.0000 80 NaCl,aq 0.12973E-05 -5.8870 0.12973E-05 -5.8870 0.10000E+01 0.0000 81 NaF,aq 0.28980E-07 -7.5379 0.28980E-07 -7.5379 0.10000E+01 0.0000 82 NaOH,aq 0.65283E-04 -4.1852 0.65283E-04 -4.1852 0.10000E+01 0.0000 84 OH- 0.63690E-02 -2.1959 0.52907E-02 -2.2765 0.83069E+00 -0.0806 89 HPO3-2 0.28842E-16 -16.5400 0.14739E-16 -16.8315 0.51101E+00 -0.2916 92 H3PO4,aq 0.19485E-17 -17.7103 0.19485E-17 -17.7103 0.10000E+01 0.0000 93 H2PO4- 0.56490E-10 -10.2480 0.47060E-10 -10.3273 0.83308E+00 -0.0793 94 PO4-3 0.74100E-09 -9.1302 0.17453E-09 -9.7581 0.23553E+00 -0.6280 98 HP2O7-3 0.14173E-17 -17.8485 0.31751E-18 -18.4982 0.22402E+00 -0.6497 99 P2O7-4 0.95215E-17 -17.0213 0.69459E-18 -18.1583 0.72949E-01 -1.1370 100 H2S,aq 0.13518E-06 -6.8691 0.13466E-06 -6.8708 0.99616E+00 -0.0017 101 S2-2 0.34093E-10 -10.4673 0.17422E-10 -10.7589 0.51101E+00 -0.2916 102 S3-2 0.30551E-16 -16.5150 0.15612E-16 -16.8065 0.51101E+00 -0.2916 107 SO3-2 0.23252E-11 -11.6335 0.12061E-11 -11.9186 0.51872E+00 -0.2851 108 HSO3- 0.99092E-14 -14.0040 0.82470E-14 -14.0837 0.83226E+00 -0.0797 109 HSO4- 0.57797E-11 -11.2381 0.48247E-11 -11.3165 0.83476E+00 -0.0784 111 S2O3-2 0.14191E-12 -12.8480 0.72517E-13 -13.1396 0.51101E+00 -0.2916 Charge balance for all species = -.6130E-08 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.1303949E-09 -.1988163E-01 -.2000308E+02 0.0000 2 H2O 0.1000000E+01 0.5550217E+02 0.9980718E+06 0.0000 3 Cl- 0.2834606E-03 0.2847585E-03 0.1007720E+02 6.3345 4 SO4-- 0.8951148E-04 0.8956787E-04 0.8588403E+01 15.5848 5 HCO3- 0.7042340E-03 0.1623283E-02 0.9886826E+02 6.7304 6 HS- 0.4793254E-03 0.4795162E-03 0.1582975E+02 6.5627 7 Al+++ 0.1600620E-28 0.1818271E-05 0.4897057E-01 0.4394 8 H4SiO4 0.9962205E-03 0.1351700E-01 0.1296832E+04 -3.0016 9 Ca++ 0.5118973E-07 0.2316173E-06 0.9265896E-02 12.3387 10 Mg++ 0.2275841E-10 0.9314769E-10 0.2260493E-05 8.9846 11 Fe++ 0.9875066E-13 0.2058915E-07 0.1147754E-02 6.6225 12 K+ 0.1565780E-03 0.1572006E-03 0.6135691E+01 6.0775 13 Na+ 0.1994164E-01 0.2229425E-01 0.5116094E+03 8.1817 14 Mn++ 0.3820706E-10 0.2506629E-08 0.1374590E-03 9.2105 15 F- 0.8982652E-05 0.9011641E-05 0.1708922E+00 4.8345 16 HPO4-- 0.4560555E-07 0.4640304E-07 0.4445627E-02 12.2920 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.1787412E-01 -.1786153E-01 -.1259128E-04 0.0000000E+00 2 H2O 0.4986277E+02 0.4986279E+02 -.1254899E-04 0.0000000E+00 3 Cl- 0.2558252E-03 0.2558252E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.8046719E-04 0.8046719E-04 0.0000000E+00 0.0000000E+00 5 HCO3- 0.1458347E-02 0.1458347E-02 0.0000000E+00 0.0000000E+00 6 HS- 0.4307943E-03 0.4307943E-03 0.0000000E+00 0.0000000E+00 7 Al+++ 0.4775352E-05 0.1633523E-05 0.3141829E-05 0.0000000E+00 8 H4SiO4 0.1215302E-01 0.1214359E-01 0.9431125E-05 0.0000000E+00 9 Ca++ 0.2080835E-06 0.2080835E-06 0.0000000E+00 0.0000000E+00 10 Mg++ 0.8368328E-10 0.8368328E-10 0.0000000E+00 0.0000000E+00 11 Fe++ 0.3259227E-07 0.1849716E-07 0.1409511E-07 0.0000000E+00 12 K+ 0.1412294E-03 0.1412280E-03 0.1409511E-08 0.0000000E+00 13 Na+ 0.2003215E-01 0.2002901E-01 0.3136191E-05 0.0000000E+00 14 Mn++ 0.2251939E-08 0.2251939E-08 0.0000000E+00 0.0000000E+00 15 F- 0.8096000E-05 0.8096000E-05 0.0000000E+00 0.0000000E+00 16 HPO4-- 0.4168819E-07 0.4168819E-07 0.0000000E+00 0.0000000E+00 Chg. balance for solid moles: -.4235E-21 Mass of aqueous solution: 0.900028E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 0.0199900 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 0.3136E-05 -5.504 0.8224E-03 -3.085 99.63 0.3157E-03 stilpnomelane-Fe 0.2819E-08 -8.550 0.3039E-05 -5.517 0.3682 0.1050E-05 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 0.000825 g Volume = 0.000317 cm3 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.0199900 moles log = -1.6992 Original solution: 1000.0103000 g Original solution / Rock added: 50025.53 (Water/Rock Ratio), log = 4.6992 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0206 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9997E+00 0.9859 0.1006E+01 0.1020E+01 CO2,gas 0.1426E-04 1.0071 0.1465E-04 0.1455E-04 CH4,gas 0.7069E-05 1.0125 0.7305E-05 0.7214E-05 H2,gas 0.2603E-03 1.0005 0.2658E-03 0.2657E-03 H2S,gas 0.3642E-05 0.9960 0.3702E-05 0.3717E-05 S2,gas 0.7133E-23 1.0000 0.7280E-23 0.7280E-23 CO,gas 0.1017E-11 1.0000 0.1038E-11 0.1038E-11 SO3,gas 0.2025E-39 1.0000 0.2067E-39 0.2067E-39 SO2,gas 0.2095E-20 1.0000 0.2138E-20 0.2138E-20 HF,gas 0.1342E-13 1.0000 0.1369E-13 0.1369E-13 HCl,gas 0.8162E-17 1.0000 0.8330E-17 0.8330E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 17 albite -0.38 -0.38 0.00 0.000 0.11184E-10 167 stilpnomelane-Fe 13.02 13.02 0.00 0.000 -0.27298E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -13.19 -6.53 -2.178 0.11155E+05 -4.834 3 CH4,gas 4.54 -2.29 -6.84 -1.709 0.11671E+05 -5.136 4 H2,gas 8.00 2.73 -5.27 -3.014 0.90059E+04 -3.575 5 H2S,gas -6.23 -13.36 -7.13 -3.565 0.12175E+05 -5.432 6 S2,gas -7.34 -32.17 -24.84 -3.821 0.42408E+05 -23.138 7 CO,gas 3.21 -10.47 -13.68 -4.210 0.23363E+05 -11.984 8 SO3,gas 17.12 -24.26 -41.38 -10.346 0.70661E+05 -39.685 9 SO2,gas 0.83 -21.54 -22.37 -5.965 0.38194E+05 -20.670 10 HF,gas 0.47 -15.09 -15.56 -7.781 0.26572E+05 -13.863 11 HCl,gas 5.19 -13.59 -18.78 -9.389 0.32063E+05 -17.079 12 acmite 7.71 7.44 -0.27 -0.028 0.46353E+03 16 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 20 spessartine 24.46 19.51 -4.95 -0.248 0.84554E+04 21 analcite 3.32 2.62 -0.70 -0.078 0.12022E+04 23 andradite 39.01 38.53 -0.48 -0.025 0.81576E+03 24 grossular 32.73 28.89 -3.84 -0.192 0.65590E+04 27 annite 20.12 17.38 -2.74 -0.152 0.46851E+04 28 phlogopite 27.06 24.47 -2.60 -0.144 0.44373E+04 33 apatite-OH -18.15 -20.97 -2.82 -0.217 0.48114E+04 34 apatite-F -34.30 -36.06 -1.76 -0.147 0.30041E+04 38 aragonite 0.97 -0.85 -1.82 -0.607 0.31091E+04 39 brucite 12.57 8.98 -3.58 -0.717 0.61195E+04 40 calcite 0.81 -0.85 -1.67 -0.555 0.28449E+04 41 carnegieite-low 9.02 5.62 -3.40 -0.486 0.58120E+04 42 carnegieite-high 10.09 5.62 -4.47 -0.639 0.76390E+04 43 carpholite-Mg 8.58 3.86 -4.72 -0.315 0.80627E+04 45 celadonite 5.34 3.49 -1.85 -0.109 0.31531E+04 46 celadonite-Fe 3.88 1.13 -2.74 -0.161 0.46848E+04 47 chrysotile 23.89 20.95 -2.94 -0.245 0.50230E+04 49 clinochlore 39.07 36.80 -2.27 -0.071 0.38803E+04 50 daphnite 28.97 24.99 -3.98 -0.124 0.67937E+04 54 chloritoid-Fe 9.17 4.50 -4.67 -0.312 0.79807E+04 55 chloritoid-Mn 11.40 7.09 -4.31 -0.288 0.73651E+04 57 coesite -2.38 -3.00 -0.63 -0.209 0.10682E+04 64 cristobalite -2.56 -3.00 -0.44 -0.147 0.75352E+03 66 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71260E+04 68 diaspore 2.87 0.44 -2.43 -0.406 0.41565E+04 69 diamond -3.10 -7.74 -4.64 -1.326 0.79227E+04 70 diopside 16.18 15.32 -0.86 -0.086 0.14706E+04 71 hedenbergite 14.21 12.96 -1.25 -0.125 0.21349E+04 78 epidote 24.67 21.81 -2.86 -0.139 0.48812E+04 80 epidote-Fe 29.84 26.63 -3.21 -0.167 0.54796E+04 81 fayalite 14.05 10.24 -3.80 -0.543 0.64924E+04 82 ferrosilite 11.15 7.24 -3.91 -0.391 0.66723E+04 86 gibbsite 4.08 0.44 -3.64 -0.520 0.62151E+04 87 glaucophane 22.97 20.18 -2.79 -0.075 0.47672E+04 88 glaucophane-Fe 17.28 13.10 -4.18 -0.113 0.71360E+04 89 graphite -3.55 -7.74 -4.20 -1.199 0.71649E+04 90 greenalite 16.14 13.86 -2.28 -0.190 0.38849E+04 93 hematite 12.57 10.52 -2.05 -0.248 0.34943E+04 94 heulandite -5.83 -7.79 -1.97 -0.089 0.33582E+04 98 jadeite 4.22 2.62 -1.60 -0.160 0.27277E+04 99 julgoldite 70.43 65.63 -4.80 -0.125 0.81914E+04 100 kalsilite 7.58 3.52 -4.07 -0.581 0.69471E+04 101 kaolinite -1.33 -5.12 -3.79 -0.345 0.64743E+04 104 laumontite 2.88 1.21 -1.67 -0.111 0.28557E+04 105 lawsonite 9.62 7.21 -2.40 -0.160 0.41011E+04 106 leucite 4.12 0.51 -3.61 -0.361 0.61559E+04 108 lizardite 23.24 20.95 -2.29 -0.191 0.39157E+04 109 magnesite 0.69 -4.21 -4.90 -1.633 0.83651E+04 110 magnetite 20.09 17.14 -2.95 -0.240 0.50288E+04 111 minnesotaite 10.39 7.86 -2.53 -0.149 0.43150E+04 115 manganosite 14.06 9.21 -4.85 -1.212 0.82772E+04 119 microcline -2.49 -2.49 0.00 0.000 0.26482E+01 123 muscovite 2.58 -1.61 -4.19 -0.247 0.71572E+04 124 paragonite 4.24 0.49 -3.74 -0.220 0.63937E+04 125 nepheline 8.34 5.62 -2.72 -0.389 0.46444E+04 137 phlogopite-Na 29.65 26.57 -3.08 -0.171 0.52535E+04 139 prehnite 19.37 16.55 -2.82 -0.166 0.48160E+04 140 prehnite-Fe 22.50 21.37 -1.13 -0.068 0.19228E+04 145 pyrite -21.25 -22.82 -1.58 -0.371 0.26935E+04 146 pyrrhotite -4.26 -6.74 -2.48 -0.826 0.42310E+04 147 pyrrhotiteFe0.875 -6.02 -7.90 -1.89 -0.694 0.32222E+04 148 pyroxmangite 7.40 6.21 -1.19 -0.238 0.20316E+04 149 pyrophyllite -6.18 -11.13 -4.95 -0.310 0.84554E+04 150 quartz -2.99 -3.00 -0.01 -0.004 0.20848E+02 154 rhodochrosite -0.98 -3.98 -3.01 -1.002 0.51332E+04 155 rhodonite 7.45 6.21 -1.24 -0.247 0.21118E+04 156 sanidine -1.28 -2.49 -1.21 -0.093 0.20704E+04 158 siderite -2.61 -6.57 -3.96 -1.321 0.67658E+04 166 stilbite -7.52 -7.79 -0.27 -0.013 0.46436E+03 168 stilpnomelane-Mg 27.44 24.83 -2.61 -0.078 0.44632E+04 174 talc 16.49 14.95 -1.54 -0.091 0.26359E+04 177 tephroite 18.09 15.42 -2.67 -0.381 0.45529E+04 181 tridymite -2.63 -3.00 -0.38 -0.125 0.64082E+03 182 tremolite 47.87 45.59 -2.28 -0.062 0.38961E+04 183 ferroactinolite 38.45 33.78 -4.68 -0.126 0.79832E+04 184 troilite-low -4.41 -6.74 -2.33 -0.776 0.39739E+04 190 wairakite 3.95 1.21 -2.74 -0.161 0.46777E+04 191 walstromite 11.51 9.34 -2.17 -0.434 0.37088E+04 192 wollastonite 10.46 9.34 -1.12 -0.225 0.19193E+04 193 pseudo-wollastonite 11.00 9.34 -1.66 -0.333 0.28391E+04 195 akaganeite 7.75 5.26 -2.49 -0.539 0.42597E+04 202 chalcedony -2.80 -3.00 -0.20 -0.066 0.34014E+03 204 montmorillonite-Ca -2.29 -6.27 -3.98 -0.246 0.67979E+04 205 montmorillonite-K -2.24 -6.30 -4.07 -0.249 0.69419E+04 206 montmorillonite-Mg -2.48 -6.83 -4.35 -0.269 0.74199E+04 207 montmorillonite-Na -2.04 -5.61 -3.57 -0.219 0.60959E+04 208 nontronite-Ca 3.21 1.68 -1.53 -0.099 0.26124E+04 209 nontronite-H 2.53 -0.35 -2.88 -0.193 0.49244E+04 210 nontronite-K 3.34 1.65 -1.69 -0.108 0.28796E+04 211 nontronite-Mg 3.07 1.13 -1.94 -0.126 0.33185E+04 212 nontronite-Na 3.52 2.35 -1.17 -0.075 0.19996E+04 228 tobermorite 9.82 7.28 -2.55 -0.695 0.43481E+04 234 alabandite -0.98 -4.15 -3.17 -1.057 0.54168E+04 237 boehmite 4.41 0.44 -3.97 -0.661 0.67735E+04 239 ferrous-oxide 9.81 6.62 -3.19 -0.797 0.54452E+04 245 silica-amorphous -2.09 -3.00 -0.91 -0.303 0.15543E+04 247 an20ab80 2.02 1.14 -0.88 -0.068 0.15060E+04 248 an25ab75 2.65 1.52 -1.13 -0.087 0.19295E+04 249 an30ab70 3.28 1.90 -1.38 -0.106 0.23626E+04 250 tr.625ac.25prg.125 45.16 43.45 -1.72 -0.046 0.29285E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 0.0010000 MOLES Current total amount of reactant added: 0.0199900 MOLES New total amount of reactant added: 0.0209900 MOLES Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.5508E-08 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 6 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 0.0209900 Water: Moles liquid = 0.4987E+02 kg liquid = 0.8984E+00 Moles total = 0.4986E+02 kg total = 0.8983E+00 Activity = 1.0000 Stoichiometric ionic strength = .1267783E-01 Osmotic coef. = 0.9393 True ionic strength = .2115340E-01 Chg. balance for total moles = -.5508E-08 Max. difference allowed = 0.2617E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.13326E-09 -9.8753 0.11159E-09 -9.9524 0.83739E+00 -0.0771 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.28999E-03 -3.5376 0.24131E-03 -3.6174 0.83213E+00 -0.0798 4 SO4-- 0.94818E-04 -4.0231 0.48532E-04 -4.3140 0.51185E+00 -0.2909 5 HCO3- 0.74799E-03 -3.1261 0.62338E-03 -3.2053 0.83340E+00 -0.0791 6 HS- 0.50104E-03 -3.3001 0.41700E-03 -3.3799 0.83226E+00 -0.0797 7 Al+++ 0.16463E-28 -28.7835 0.36793E-29 -29.4342 0.22348E+00 -0.6508 8 H4SiO4 0.10161E-02 -2.9930 0.10161E-02 -2.9930 0.10000E+01 0.0000 9 Ca++ 0.49997E-07 -7.3011 0.25395E-07 -7.5953 0.50792E+00 -0.2942 10 Mg++ 0.22862E-10 -10.6409 0.11557E-10 -10.9372 0.50550E+00 -0.2963 11 Fe++ 0.10170E-12 -12.9927 0.51467E-13 -13.2885 0.50607E+00 -0.2958 12 K+ 0.15658E-03 -3.8053 0.13053E-03 -3.8843 0.83361E+00 -0.0790 13 Na+ 0.19946E-01 -1.7001 0.16595E-01 -1.7800 0.83197E+00 -0.0799 14 Mn++ 0.39715E-10 -10.4010 0.20116E-10 -10.6965 0.50651E+00 -0.2954 15 F- 0.94263E-05 -5.0257 0.78271E-05 -5.1064 0.83034E+00 -0.0807 16 HPO4-- 0.45619E-07 -7.3409 0.23353E-07 -7.6317 0.51192E+00 -0.2908 18 HSiO3- 0.10218E-01 -1.9906 0.85028E-02 -2.0704 0.83213E+00 -0.0798 19 Ca(HSiO3)+ 0.58977E-08 -8.2293 0.49175E-08 -8.3083 0.83379E+00 -0.0789 20 Mg(HSiO3)+ 0.33402E-11 -11.4762 0.27850E-11 -11.5552 0.83379E+00 -0.0789 21 NaHSiO3,aq 0.22821E-02 -2.6417 0.22821E-02 -2.6417 0.10000E+01 0.0000 22 AlO+ 0.48211E-16 -16.3169 0.40198E-16 -16.3958 0.83379E+00 -0.0789 24 HAlO2,aq 0.71741E-10 -10.1442 0.71741E-10 -10.1442 0.10000E+01 0.0000 25 AlO2- 0.17135E-05 -5.7661 0.14231E-05 -5.8468 0.83056E+00 -0.0806 26 CH4,aq 0.52230E-08 -8.2821 0.52028E-08 -8.2838 0.99614E+00 -0.0017 27 C2H6,aq 0.23144E-19 -19.6356 0.23055E-19 -19.6372 0.99614E+00 -0.0017 31 CO,aq 0.74948E-15 -15.1252 0.74948E-15 -15.1252 0.10000E+01 0.0000 32 CO2,aq 0.14921E-06 -6.8262 0.14864E-06 -6.8279 0.99614E+00 -0.0017 33 CO3-2 0.95543E-03 -3.0198 0.48795E-03 -3.3116 0.51071E+00 -0.2918 34 CaCO3,aq 0.15537E-06 -6.8086 0.15537E-06 -6.8086 0.10000E+01 0.0000 35 Ca(HCO3)+ 0.48464E-09 -9.3146 0.40409E-09 -9.3935 0.83379E+00 -0.0789 36 CaCl+ 0.11894E-10 -10.9247 0.99171E-11 -11.0036 0.83379E+00 -0.0789 37 CaCl2,aq 0.56855E-15 -15.2452 0.56855E-15 -15.2452 0.10000E+01 0.0000 38 CaF+ 0.34805E-11 -11.4584 0.29020E-11 -11.5373 0.83379E+00 -0.0789 39 CaOH+ 0.19452E-07 -7.7110 0.16219E-07 -7.7900 0.83379E+00 -0.0789 40 CaSO4,aq 0.39137E-09 -9.4074 0.39137E-09 -9.4074 0.10000E+01 0.0000 41 HCl,aq 0.49343E-14 -14.3068 0.49343E-14 -14.3068 0.10000E+01 0.0000 45 HF,aq 0.59791E-11 -11.2234 0.59791E-11 -11.2234 0.10000E+01 0.0000 46 HF2- 0.18988E-16 -16.7215 0.15800E-16 -16.8013 0.83213E+00 -0.0798 48 FeCl+ 0.23577E-16 -16.6275 0.19658E-16 -16.7065 0.83379E+00 -0.0789 51 FeF+ 0.24689E-16 -16.6075 0.20585E-16 -16.6864 0.83379E+00 -0.0789 53 FeO,aq 0.16064E-09 -9.7941 0.16064E-09 -9.7941 0.10000E+01 0.0000 54 FeOH+ 0.18006E-10 -10.7446 0.15013E-10 -10.8235 0.83379E+00 -0.0789 55 HFeO2- 0.18101E-07 -7.7423 0.15063E-07 -7.8221 0.83213E+00 -0.0798 56 FeO+ 0.95860E-16 -16.0184 0.79928E-16 -16.0973 0.83379E+00 -0.0789 58 FeO2- 0.15784E-08 -8.8018 0.13134E-08 -8.8816 0.83213E+00 -0.0798 59 HFeO2,aq 0.18641E-10 -10.7295 0.18641E-10 -10.7295 0.10000E+01 0.0000 60 H2,aq 0.20150E-06 -6.6957 0.20073E-06 -6.6974 0.99614E+00 -0.0017 61 KCl,aq 0.57087E-09 -9.2435 0.57087E-09 -9.2435 0.10000E+01 0.0000 62 KHSO4,aq 0.19986E-17 -17.6993 0.19986E-17 -17.6993 0.10000E+01 0.0000 63 KOH,aq 0.49953E-06 -6.3014 0.49953E-06 -6.3014 0.10000E+01 0.0000 64 KSO4- 0.11813E-06 -6.9276 0.98300E-07 -7.0074 0.83213E+00 -0.0798 65 MgCO3,aq 0.17723E-10 -10.7515 0.17723E-10 -10.7515 0.10000E+01 0.0000 66 Mg(HCO3)+ 0.22536E-12 -12.6471 0.18790E-12 -12.7261 0.83379E+00 -0.0789 67 MgCl+ 0.49058E-14 -14.3093 0.40904E-14 -14.3882 0.83379E+00 -0.0789 68 MgF+ 0.58672E-14 -14.2316 0.48921E-14 -14.3105 0.83379E+00 -0.0789 69 MgOH+ 0.48984E-10 -10.3099 0.40843E-10 -10.3889 0.83379E+00 -0.0789 71 MnF+ 0.31807E-14 -14.4975 0.26520E-14 -14.5764 0.83379E+00 -0.0789 72 MnO,aq 0.16730E-08 -8.7765 0.16730E-08 -8.7765 0.10000E+01 0.0000 73 MnOH+ 0.65378E-09 -9.1846 0.54512E-09 -9.2635 0.83379E+00 -0.0789 74 MnO2-2 0.87310E-11 -11.0589 0.44590E-11 -11.3508 0.51071E+00 -0.2918 75 HMnO2- 0.13100E-09 -9.8827 0.10901E-09 -9.9625 0.83213E+00 -0.0798 78 MnCl+ 0.35851E-13 -13.4455 0.29892E-13 -13.5244 0.83379E+00 -0.0789 79 MnSO4,aq 0.28185E-12 -12.5500 0.28185E-12 -12.5500 0.10000E+01 0.0000 80 NaCl,aq 0.13271E-05 -5.8771 0.13271E-05 -5.8771 0.10000E+01 0.0000 81 NaF,aq 0.30409E-07 -7.5170 0.30409E-07 -7.5170 0.10000E+01 0.0000 82 NaOH,aq 0.63895E-04 -4.1945 0.63895E-04 -4.1945 0.10000E+01 0.0000 84 OH- 0.62340E-02 -2.2052 0.51777E-02 -2.2859 0.83056E+00 -0.0806 89 HPO3-2 0.28603E-16 -16.5436 0.14608E-16 -16.8354 0.51071E+00 -0.2918 92 H3PO4,aq 0.20338E-17 -17.6917 0.20338E-17 -17.6917 0.10000E+01 0.0000 93 H2PO4- 0.57713E-10 -10.2387 0.48072E-10 -10.3181 0.83295E+00 -0.0794 94 PO4-3 0.72588E-09 -9.1391 0.17075E-09 -9.7676 0.23523E+00 -0.6285 98 HP2O7-3 0.14493E-17 -17.8388 0.32425E-18 -18.4891 0.22372E+00 -0.6503 99 P2O7-4 0.95380E-17 -17.0205 0.69417E-18 -18.1585 0.72779E-01 -1.1380 100 H2S,aq 0.14437E-06 -6.8405 0.14381E-06 -6.8422 0.99614E+00 -0.0017 101 S2-2 0.37585E-10 -10.4250 0.19195E-10 -10.7168 0.51071E+00 -0.2918 102 S3-2 0.36279E-16 -16.4403 0.18528E-16 -16.7322 0.51071E+00 -0.2918 107 SO3-2 0.24419E-11 -11.6123 0.12659E-11 -11.8976 0.51843E+00 -0.2853 108 HSO3- 0.10629E-13 -13.9735 0.88448E-14 -14.0533 0.83213E+00 -0.0798 109 HSO4- 0.62531E-11 -11.2039 0.52191E-11 -11.2824 0.83464E+00 -0.0785 111 S2O3-2 0.16053E-12 -12.7944 0.81987E-13 -13.0863 0.51071E+00 -0.2918 Charge balance for all species = -.6130E-08 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.1332571E-09 -.1976099E-01 -.1988162E+02 0.0000 2 H2O 0.1000000E+01 0.5550205E+02 0.9980654E+06 0.0000 3 Cl- 0.2899927E-03 0.2913204E-03 0.1030938E+02 6.3350 4 SO4-- 0.9481801E-04 0.9488115E-04 0.9097839E+01 15.5908 5 HCO3- 0.7479882E-03 0.1703729E-02 0.1037675E+03 6.7471 6 HS- 0.5010404E-03 0.5012402E-03 0.1654683E+02 6.5725 7 Al+++ 0.1646325E-28 0.1713527E-05 0.4614933E-01 0.4229 8 H4SiO4 0.1016142E-02 0.1351644E-01 0.1296772E+04 -2.9930 9 Ca++ 0.4999739E-07 0.2316130E-06 0.9265685E-02 12.3095 10 Mg++ 0.2286194E-10 0.9314597E-10 0.2260441E-05 8.9676 11 Fe++ 0.1016980E-12 0.1987712E-07 0.1108056E-02 6.6163 12 K+ 0.1565794E-03 0.1571976E-03 0.6135548E+01 6.0681 13 Na+ 0.1994634E-01 0.2229374E-01 0.5115953E+03 8.1724 14 Mn++ 0.3971506E-10 0.2506582E-08 0.1374559E-03 9.2083 15 F- 0.9426287E-05 0.9456705E-05 0.1793313E+00 4.8460 16 HPO4-- 0.4561859E-07 0.4640218E-07 0.4445525E-02 12.2731 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.1776644E-01 -.1775347E-01 -.1296866E-04 0.0000000E+00 2 H2O 0.4986359E+02 0.4986361E+02 -.1292445E-04 0.0000000E+00 3 Cl- 0.2617252E-03 0.2617252E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.8524219E-04 0.8524219E-04 0.0000000E+00 0.0000000E+00 5 HCO3- 0.1530647E-02 0.1530647E-02 0.0000000E+00 0.0000000E+00 6 HS- 0.4503193E-03 0.4503193E-03 0.0000000E+00 0.0000000E+00 7 Al+++ 0.4775352E-05 0.1539450E-05 0.3235902E-05 0.0000000E+00 8 H4SiO4 0.1215302E-01 0.1214331E-01 0.9713600E-05 0.0000000E+00 9 Ca++ 0.2080835E-06 0.2080835E-06 0.0000000E+00 0.0000000E+00 10 Mg++ 0.8368328E-10 0.8368328E-10 0.0000000E+00 0.0000000E+00 11 Fe++ 0.3259227E-07 0.1785781E-07 0.1473446E-07 0.0000000E+00 12 K+ 0.1412294E-03 0.1412279E-03 0.1473446E-08 0.0000000E+00 13 Na+ 0.2003215E-01 0.2002892E-01 0.3230008E-05 0.0000000E+00 14 Mn++ 0.2251939E-08 0.2251939E-08 0.0000000E+00 0.0000000E+00 15 F- 0.8496000E-05 0.8496000E-05 0.0000000E+00 0.0000000E+00 16 HPO4-- 0.4168819E-07 0.4168819E-07 0.0000000E+00 0.0000000E+00 Chg. balance for solid moles: -.4235E-21 Mass of aqueous solution: 0.900049E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 0.0209900 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 0.3230E-05 -5.491 0.8470E-03 -3.072 99.63 0.3251E-03 stilpnomelane-Fe 0.2947E-08 -8.531 0.3177E-05 -5.498 0.3737 0.1097E-05 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 0.000850 g Volume = 0.000326 cm3 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.0209900 moles log = -1.6780 Original solution: 1000.0103000 g Original solution / Rock added: 47642.22 (Water/Rock Ratio), log = 4.6780 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0206 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9997E+00 0.9859 0.1006E+01 0.1020E+01 CO2,gas 0.1547E-04 1.0071 0.1590E-04 0.1579E-04 CH4,gas 0.7411E-05 1.0125 0.7658E-05 0.7563E-05 H2,gas 0.2581E-03 1.0005 0.2635E-03 0.2634E-03 H2S,gas 0.3889E-05 0.9960 0.3953E-05 0.3969E-05 S2,gas 0.8277E-23 1.0000 0.8447E-23 0.8447E-23 CO,gas 0.1094E-11 1.0000 0.1117E-11 0.1117E-11 SO3,gas 0.2239E-39 1.0000 0.2285E-39 0.2285E-39 SO2,gas 0.2295E-20 1.0000 0.2343E-20 0.2343E-20 HF,gas 0.1438E-13 1.0000 0.1468E-13 0.1468E-13 HCl,gas 0.8531E-17 1.0000 0.8707E-17 0.8707E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 17 albite -0.38 -0.38 0.00 0.000 -0.94784E-12 167 stilpnomelane-Fe 13.02 13.02 0.00 0.000 0.69761E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -13.16 -6.50 -2.166 0.11094E+05 -4.799 3 CH4,gas 4.54 -2.27 -6.81 -1.704 0.11636E+05 -5.116 4 H2,gas 8.00 2.72 -5.28 -3.016 0.90123E+04 -3.579 5 H2S,gas -6.23 -13.33 -7.10 -3.551 0.12126E+05 -5.403 6 S2,gas -7.34 -32.11 -24.77 -3.811 0.42298E+05 -23.073 7 CO,gas 3.21 -10.44 -13.65 -4.200 0.23309E+05 -11.952 8 SO3,gas 17.12 -24.22 -41.34 -10.335 0.70587E+05 -39.641 9 SO2,gas 0.83 -21.50 -22.33 -5.954 0.38127E+05 -20.630 10 HF,gas 0.47 -15.06 -15.53 -7.766 0.26521E+05 -13.833 11 HCl,gas 5.19 -13.57 -18.76 -9.380 0.32031E+05 -17.060 12 acmite 7.71 7.44 -0.27 -0.028 0.45755E+03 16 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 20 spessartine 24.46 19.49 -4.97 -0.248 0.84788E+04 21 analcite 3.32 2.61 -0.71 -0.079 0.12169E+04 23 andradite 39.01 38.46 -0.55 -0.028 0.93636E+03 24 grossular 32.73 28.80 -3.94 -0.197 0.67210E+04 27 annite 20.12 17.36 -2.76 -0.153 0.47172E+04 28 phlogopite 27.06 24.41 -2.65 -0.147 0.45247E+04 33 apatite-OH -18.15 -21.06 -2.91 -0.224 0.49657E+04 34 apatite-F -34.30 -36.12 -1.82 -0.152 0.31068E+04 38 aragonite 0.97 -0.85 -1.81 -0.605 0.30985E+04 39 brucite 12.57 8.97 -3.60 -0.720 0.61486E+04 40 calcite 0.81 -0.85 -1.66 -0.553 0.28342E+04 41 carnegieite-low 9.02 5.60 -3.42 -0.489 0.58414E+04 42 carnegieite-high 10.09 5.60 -4.49 -0.642 0.76684E+04 43 carpholite-Mg 8.58 3.83 -4.75 -0.317 0.81186E+04 45 celadonite 5.34 3.49 -1.86 -0.109 0.31677E+04 46 celadonite-Fe 3.88 1.14 -2.74 -0.161 0.46809E+04 47 chrysotile 23.89 20.92 -2.98 -0.248 0.50809E+04 49 clinochlore 39.07 36.70 -2.36 -0.074 0.40379E+04 50 daphnite 28.97 24.95 -4.02 -0.126 0.68591E+04 54 chloritoid-Fe 9.17 4.47 -4.70 -0.314 0.80329E+04 55 chloritoid-Mn 11.40 7.06 -4.34 -0.289 0.74104E+04 57 coesite -2.38 -2.99 -0.62 -0.206 0.10535E+04 64 cristobalite -2.56 -2.99 -0.43 -0.144 0.73884E+03 66 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71262E+04 68 diaspore 2.87 0.42 -2.45 -0.408 0.41846E+04 69 diamond -3.10 -7.71 -4.61 -1.318 0.78749E+04 70 diopside 16.18 15.29 -0.89 -0.089 0.15202E+04 71 hedenbergite 14.21 12.94 -1.27 -0.127 0.21660E+04 78 epidote 24.67 21.74 -2.93 -0.142 0.50007E+04 80 epidote-Fe 29.84 26.57 -3.27 -0.170 0.55784E+04 81 fayalite 14.05 10.24 -3.81 -0.544 0.64990E+04 82 ferrosilite 11.15 7.25 -3.90 -0.390 0.66642E+04 86 gibbsite 4.08 0.42 -3.66 -0.522 0.62432E+04 87 glaucophane 22.97 20.15 -2.83 -0.076 0.48250E+04 88 glaucophane-Fe 17.28 13.10 -4.18 -0.113 0.71385E+04 89 graphite -3.55 -7.71 -4.17 -1.191 0.71171E+04 90 greenalite 16.14 13.86 -2.28 -0.190 0.38874E+04 93 hematite 12.57 10.51 -2.06 -0.249 0.35092E+04 94 heulandite -5.83 -7.80 -1.97 -0.089 0.33616E+04 98 jadeite 4.22 2.61 -1.61 -0.161 0.27424E+04 99 julgoldite 70.43 65.53 -4.89 -0.127 0.83540E+04 100 kalsilite 7.58 3.50 -4.09 -0.584 0.69767E+04 101 kaolinite -1.33 -5.14 -3.81 -0.346 0.65012E+04 104 laumontite 2.88 1.18 -1.70 -0.113 0.29031E+04 105 lawsonite 9.62 7.17 -2.45 -0.163 0.41779E+04 106 leucite 4.12 0.50 -3.61 -0.361 0.61707E+04 108 lizardite 23.24 20.92 -2.33 -0.194 0.39735E+04 109 magnesite 0.69 -4.19 -4.88 -1.627 0.83336E+04 110 magnetite 20.09 17.13 -2.96 -0.242 0.50543E+04 111 minnesotaite 10.39 7.88 -2.51 -0.148 0.42882E+04 115 manganosite 14.06 9.21 -4.85 -1.212 0.82809E+04 119 microcline -2.49 -2.49 0.00 0.000 0.28136E+01 123 muscovite 2.58 -1.64 -4.22 -0.249 0.72136E+04 124 paragonite 4.24 0.46 -3.78 -0.222 0.64499E+04 125 nepheline 8.34 5.60 -2.74 -0.391 0.46737E+04 137 phlogopite-Na 29.65 26.52 -3.13 -0.174 0.53407E+04 139 prehnite 19.37 16.49 -2.89 -0.170 0.49281E+04 140 prehnite-Fe 22.50 21.32 -1.18 -0.071 0.20141E+04 145 pyrite -21.25 -22.77 -1.52 -0.358 0.26003E+04 146 pyrrhotite -4.26 -6.72 -2.46 -0.819 0.41929E+04 147 pyrrhotiteFe0.875 -6.02 -7.88 -1.86 -0.685 0.31819E+04 148 pyroxmangite 7.40 6.22 -1.18 -0.237 0.20206E+04 149 pyrophyllite -6.18 -11.13 -4.95 -0.309 0.84529E+04 150 quartz -2.99 -2.99 0.00 -0.001 0.61652E+01 154 rhodochrosite -0.98 -3.95 -2.97 -0.991 0.50763E+04 155 rhodonite 7.45 6.22 -1.23 -0.246 0.21009E+04 156 sanidine -1.28 -2.49 -1.21 -0.093 0.20706E+04 158 siderite -2.61 -6.54 -3.93 -1.311 0.67158E+04 166 stilbite -7.52 -7.80 -0.27 -0.013 0.46772E+03 168 stilpnomelane-Mg 27.44 24.77 -2.67 -0.080 0.45554E+04 174 talc 16.49 14.93 -1.56 -0.092 0.26644E+04 177 tephroite 18.09 15.42 -2.66 -0.380 0.45457E+04 181 tridymite -2.63 -2.99 -0.37 -0.122 0.62614E+03 182 tremolite 47.87 45.51 -2.36 -0.064 0.40239E+04 183 ferroactinolite 38.45 33.76 -4.70 -0.127 0.80187E+04 184 troilite-low -4.41 -6.72 -2.31 -0.768 0.39357E+04 190 wairakite 3.95 1.18 -2.77 -0.163 0.47251E+04 191 walstromite 11.51 9.32 -2.19 -0.439 0.37441E+04 192 wollastonite 10.46 9.32 -1.14 -0.229 0.19545E+04 193 pseudo-wollastonite 11.00 9.32 -1.68 -0.337 0.28743E+04 195 akaganeite 7.75 5.26 -2.50 -0.540 0.42671E+04 202 chalcedony -2.80 -2.99 -0.19 -0.064 0.32546E+03 204 montmorillonite-Ca -2.29 -6.28 -3.98 -0.247 0.68040E+04 205 montmorillonite-K -2.24 -6.30 -4.07 -0.249 0.69450E+04 206 montmorillonite-Mg -2.48 -6.83 -4.35 -0.269 0.74225E+04 207 montmorillonite-Na -2.04 -5.61 -3.57 -0.219 0.60990E+04 208 nontronite-Ca 3.21 1.70 -1.52 -0.098 0.25910E+04 209 nontronite-H 2.53 -0.33 -2.87 -0.192 0.48947E+04 210 nontronite-K 3.34 1.67 -1.67 -0.107 0.28552E+04 211 nontronite-Mg 3.07 1.15 -1.93 -0.125 0.32936E+04 212 nontronite-Na 3.52 2.36 -1.16 -0.074 0.19752E+04 228 tobermorite 9.82 7.26 -2.56 -0.699 0.43750E+04 234 alabandite -0.98 -4.12 -3.15 -1.049 0.53718E+04 237 boehmite 4.41 0.42 -3.98 -0.664 0.68016E+04 239 ferrous-oxide 9.81 6.62 -3.20 -0.799 0.54559E+04 245 silica-amorphous -2.09 -2.99 -0.90 -0.301 0.15396E+04 247 an20ab80 2.02 1.13 -0.89 -0.069 0.15214E+04 248 an25ab75 2.65 1.50 -1.14 -0.088 0.19487E+04 249 an30ab70 3.28 1.88 -1.40 -0.107 0.23856E+04 250 tr.625ac.25prg.125 45.16 43.38 -1.78 -0.048 0.30458E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 0.0010000 MOLES Current total amount of reactant added: 0.0209900 MOLES New total amount of reactant added: 0.0219900 MOLES Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.5508E-08 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 7 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 0.0219900 Water: Moles liquid = 0.4987E+02 kg liquid = 0.8984E+00 Moles total = 0.4986E+02 kg total = 0.8983E+00 Activity = 1.0000 Stoichiometric ionic strength = .1274237E-01 Osmotic coef. = 0.9388 True ionic strength = .2119918E-01 Chg. balance for total moles = -.5508E-08 Max. difference allowed = 0.2676E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.13621E-09 -9.8658 0.11405E-09 -9.9429 0.83727E+00 -0.0771 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.29652E-03 -3.5279 0.24671E-03 -3.6078 0.83201E+00 -0.0799 4 SO4-- 0.10012E-03 -3.9995 0.51219E-04 -4.2906 0.51155E+00 -0.2911 5 HCO3- 0.79270E-03 -3.1009 0.66054E-03 -3.1801 0.83328E+00 -0.0792 6 HS- 0.52275E-03 -3.2817 0.43500E-03 -3.3615 0.83214E+00 -0.0798 7 Al+++ 0.16939E-28 -28.7711 0.37806E-29 -29.4224 0.22319E+00 -0.6513 8 H4SiO4 0.10366E-02 -2.9844 0.10366E-02 -2.9844 0.10000E+01 0.0000 9 Ca++ 0.48892E-07 -7.3108 0.24819E-07 -7.6052 0.50762E+00 -0.2945 10 Mg++ 0.22968E-10 -10.6389 0.11603E-10 -10.9354 0.50520E+00 -0.2965 11 Fe++ 0.10476E-12 -12.9798 0.52987E-13 -13.2758 0.50577E+00 -0.2960 12 K+ 0.15658E-03 -3.8053 0.13051E-03 -3.8844 0.83349E+00 -0.0791 13 Na+ 0.19951E-01 -1.7000 0.16596E-01 -1.7800 0.83185E+00 -0.0800 14 Mn++ 0.41291E-10 -10.3841 0.20902E-10 -10.6798 0.50621E+00 -0.2957 15 F- 0.98699E-05 -5.0057 0.81942E-05 -5.0865 0.83022E+00 -0.0808 16 HPO4-- 0.45631E-07 -7.3407 0.23346E-07 -7.6318 0.51163E+00 -0.2910 18 HSiO3- 0.10201E-01 -1.9914 0.84874E-02 -2.0712 0.83201E+00 -0.0799 19 Ca(HSiO3)+ 0.57543E-08 -8.2400 0.47972E-08 -8.3190 0.83368E+00 -0.0790 20 Mg(HSiO3)+ 0.33480E-11 -11.4752 0.27912E-11 -11.5542 0.83368E+00 -0.0790 21 NaHSiO3,aq 0.22782E-02 -2.6424 0.22782E-02 -2.6424 0.10000E+01 0.0000 22 AlO+ 0.47433E-16 -16.3239 0.39543E-16 -16.4029 0.83368E+00 -0.0790 24 HAlO2,aq 0.69051E-10 -10.1608 0.69051E-10 -10.1608 0.10000E+01 0.0000 25 AlO2- 0.16139E-05 -5.7921 0.13402E-05 -5.8728 0.83044E+00 -0.0807 26 CH4,aq 0.54707E-08 -8.2620 0.54494E-08 -8.2636 0.99612E+00 -0.0017 27 C2H6,aq 0.25603E-19 -19.5917 0.25504E-19 -19.5934 0.99612E+00 -0.0017 31 CO,aq 0.80492E-15 -15.0942 0.80492E-15 -15.0942 0.10000E+01 0.0000 32 CO2,aq 0.16159E-06 -6.7916 0.16097E-06 -6.7933 0.99612E+00 -0.0017 33 CO3-2 0.99115E-03 -3.0039 0.50590E-03 -3.2959 0.51042E+00 -0.2921 34 CaCO3,aq 0.15744E-06 -6.8029 0.15744E-06 -6.8029 0.10000E+01 0.0000 35 Ca(HCO3)+ 0.50196E-09 -9.2993 0.41847E-09 -9.3783 0.83368E+00 -0.0790 36 CaCl+ 0.11886E-10 -10.9250 0.99091E-11 -11.0040 0.83368E+00 -0.0790 37 CaCl2,aq 0.58081E-15 -15.2360 0.58081E-15 -15.2360 0.10000E+01 0.0000 38 CaF+ 0.35616E-11 -11.4484 0.29692E-11 -11.5274 0.83368E+00 -0.0790 39 CaOH+ 0.18604E-07 -7.7304 0.15510E-07 -7.8094 0.83368E+00 -0.0790 40 CaSO4,aq 0.40367E-09 -9.3940 0.40367E-09 -9.3940 0.10000E+01 0.0000 41 HCl,aq 0.51559E-14 -14.2877 0.51559E-14 -14.2877 0.10000E+01 0.0000 45 HF,aq 0.63974E-11 -11.1940 0.63974E-11 -11.1940 0.10000E+01 0.0000 46 HF2- 0.21272E-16 -16.6722 0.17699E-16 -16.7521 0.83201E+00 -0.0799 48 FeCl+ 0.24820E-16 -16.6052 0.20692E-16 -16.6842 0.83368E+00 -0.0790 51 FeF+ 0.26614E-16 -16.5749 0.22188E-16 -16.6539 0.83368E+00 -0.0790 53 FeO,aq 0.15833E-09 -9.8004 0.15833E-09 -9.8004 0.10000E+01 0.0000 54 FeOH+ 0.18141E-10 -10.7413 0.15123E-10 -10.8203 0.83368E+00 -0.0790 55 HFeO2- 0.17459E-07 -7.7580 0.14526E-07 -7.8378 0.83201E+00 -0.0799 56 FeO+ 0.96982E-16 -16.0133 0.80852E-16 -16.0923 0.83368E+00 -0.0790 58 FeO2- 0.15288E-08 -8.8157 0.12720E-08 -8.8955 0.83201E+00 -0.0799 59 HFeO2,aq 0.18450E-10 -10.7340 0.18450E-10 -10.7340 0.10000E+01 0.0000 60 H2,aq 0.19983E-06 -6.6993 0.19906E-06 -6.7010 0.99612E+00 -0.0017 61 KCl,aq 0.58356E-09 -9.2339 0.58356E-09 -9.2339 0.10000E+01 0.0000 62 KHSO4,aq 0.21554E-17 -17.6665 0.21554E-17 -17.6665 0.10000E+01 0.0000 63 KOH,aq 0.48870E-06 -6.3110 0.48870E-06 -6.3110 0.10000E+01 0.0000 64 KSO4- 0.12467E-06 -6.9042 0.10373E-06 -6.9841 0.83201E+00 -0.0799 65 MgCO3,aq 0.18449E-10 -10.7340 0.18449E-10 -10.7340 0.10000E+01 0.0000 66 Mg(HCO3)+ 0.23979E-12 -12.6202 0.19991E-12 -12.6992 0.83368E+00 -0.0790 67 MgCl+ 0.50364E-14 -14.2979 0.41988E-14 -14.3769 0.83368E+00 -0.0790 68 MgF+ 0.61680E-14 -14.2099 0.51421E-14 -14.2889 0.83368E+00 -0.0790 69 MgOH+ 0.48128E-10 -10.3176 0.40123E-10 -10.3966 0.83368E+00 -0.0790 71 MnF+ 0.34605E-14 -14.4609 0.28849E-14 -14.5399 0.83368E+00 -0.0790 72 MnO,aq 0.16643E-08 -8.7788 0.16643E-08 -8.7788 0.10000E+01 0.0000 73 MnOH+ 0.66478E-09 -9.1773 0.55421E-09 -9.2563 0.83368E+00 -0.0790 74 MnO2-2 0.83196E-11 -11.0799 0.42465E-11 -11.3720 0.51042E+00 -0.2921 75 HMnO2- 0.12752E-09 -9.8944 0.10610E-09 -9.9743 0.83201E+00 -0.0799 78 MnCl+ 0.38091E-13 -13.4192 0.31755E-13 -13.4982 0.83368E+00 -0.0790 79 MnSO4,aq 0.30907E-12 -12.5099 0.30907E-12 -12.5099 0.10000E+01 0.0000 80 NaCl,aq 0.13569E-05 -5.8674 0.13569E-05 -5.8674 0.10000E+01 0.0000 81 NaF,aq 0.31839E-07 -7.4970 0.31839E-07 -7.4970 0.10000E+01 0.0000 82 NaOH,aq 0.62524E-04 -4.2040 0.62524E-04 -4.2040 0.10000E+01 0.0000 84 OH- 0.61005E-02 -2.2146 0.50661E-02 -2.2953 0.83044E+00 -0.0807 89 HPO3-2 0.28374E-16 -16.5471 0.14482E-16 -16.8392 0.51042E+00 -0.2921 92 H3PO4,aq 0.21238E-17 -17.6729 0.21238E-17 -17.6729 0.10000E+01 0.0000 93 H2PO4- 0.58976E-10 -10.2293 0.49117E-10 -10.3088 0.83283E+00 -0.0794 94 PO4-3 0.71089E-09 -9.1482 0.16702E-09 -9.7772 0.23495E+00 -0.6290 98 HP2O7-3 0.14823E-17 -17.8291 0.33120E-18 -18.4799 0.22343E+00 -0.6509 99 P2O7-4 0.95543E-17 -17.0198 0.69377E-18 -18.1588 0.72613E-01 -1.1390 100 H2S,aq 0.15392E-06 -6.8127 0.15333E-06 -6.8144 0.99612E+00 -0.0017 101 S2-2 0.41268E-10 -10.3844 0.21064E-10 -10.6765 0.51042E+00 -0.2921 102 S3-2 0.42826E-16 -16.3683 0.21859E-16 -16.6604 0.51042E+00 -0.2921 107 SO3-2 0.25570E-11 -11.5923 0.13249E-11 -11.8778 0.51814E+00 -0.2856 108 HSO3- 0.11371E-13 -13.9442 0.94608E-14 -14.0241 0.83201E+00 -0.0799 109 HSO4- 0.67456E-11 -11.1710 0.56294E-11 -11.2495 0.83453E+00 -0.0786 111 S2O3-2 0.18074E-12 -12.7430 0.92251E-13 -13.0350 0.51042E+00 -0.2921 Charge balance for all species = -.6130E-08 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.1362114E-09 -.1964038E-01 -.1976019E+02 0.0000 2 H2O 0.1000000E+01 0.5550194E+02 0.9980590E+06 0.0000 3 Cl- 0.2965245E-03 0.2978821E-03 0.1054154E+02 6.3351 4 SO4-- 0.1001244E-03 0.1001942E-03 0.9607252E+01 15.5953 5 HCO3- 0.7927010E-03 0.1784171E-02 0.1086664E+03 6.7628 6 HS- 0.5227541E-03 0.5229634E-03 0.1726388E+02 6.5814 7 Al+++ 0.1693882E-28 0.1613969E-05 0.4346781E-01 0.4063 8 H4SiO4 0.1036640E-02 0.1351589E-01 0.1296714E+04 -2.9844 9 Ca++ 0.4889238E-07 0.2316088E-06 0.9265473E-02 12.2806 10 Mg++ 0.2296765E-10 0.9314424E-10 0.2260390E-05 8.9504 11 Fe++ 0.1047639E-12 0.1918293E-07 0.1069354E-02 6.6100 12 K+ 0.1565807E-03 0.1571946E-03 0.6135405E+01 6.0586 13 Na+ 0.1995111E-01 0.2229323E-01 0.5115813E+03 8.1629 14 Mn++ 0.4129142E-10 0.2506536E-08 0.1374527E-03 9.2060 15 F- 0.9869905E-05 0.9901753E-05 0.1877702E+00 4.8564 16 HPO4-- 0.4563145E-07 0.4640132E-07 0.4445424E-02 12.2541 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.1765877E-01 -.1764544E-01 -.1332739E-04 0.0000000E+00 2 H2O 0.4986441E+02 0.4986443E+02 -.1328131E-04 0.0000000E+00 3 Cl- 0.2676252E-03 0.2676252E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.9001719E-04 0.9001719E-04 0.0000000E+00 0.0000000E+00 5 HCO3- 0.1602947E-02 0.1602947E-02 0.0000000E+00 0.0000000E+00 6 HS- 0.4698443E-03 0.4698443E-03 0.0000000E+00 0.0000000E+00 7 Al+++ 0.4775352E-05 0.1450033E-05 0.3325319E-05 0.0000000E+00 8 H4SiO4 0.1215302E-01 0.1214304E-01 0.9982101E-05 0.0000000E+00 9 Ca++ 0.2080835E-06 0.2080835E-06 0.0000000E+00 0.0000000E+00 10 Mg++ 0.8368328E-10 0.8368328E-10 0.0000000E+00 0.0000000E+00 11 Fe++ 0.3259227E-07 0.1723446E-07 0.1535781E-07 0.0000000E+00 12 K+ 0.1412294E-03 0.1412279E-03 0.1535781E-08 0.0000000E+00 13 Na+ 0.2003215E-01 0.2002883E-01 0.3319176E-05 0.0000000E+00 14 Mn++ 0.2251939E-08 0.2251939E-08 0.0000000E+00 0.0000000E+00 15 F- 0.8896000E-05 0.8896000E-05 0.0000000E+00 0.0000000E+00 16 HPO4-- 0.4168819E-07 0.4168819E-07 0.0000000E+00 0.0000000E+00 Chg. balance for solid moles: 0.4235E-21 Mass of aqueous solution: 0.900070E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 0.0219900 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 0.3319E-05 -5.479 0.8704E-03 -3.060 99.62 0.3341E-03 stilpnomelane-Fe 0.3072E-08 -8.513 0.3311E-05 -5.480 0.3790 0.1144E-05 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 0.000874 g Volume = 0.000335 cm3 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.0219900 moles log = -1.6578 Original solution: 1000.0103000 g Original solution / Rock added: 45475.68 (Water/Rock Ratio), log = 4.6578 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0206 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9997E+00 0.9859 0.1006E+01 0.1020E+01 CO2,gas 0.1676E-04 1.0071 0.1722E-04 0.1710E-04 CH4,gas 0.7762E-05 1.0125 0.8021E-05 0.7922E-05 H2,gas 0.2559E-03 1.0005 0.2613E-03 0.2612E-03 H2S,gas 0.4146E-05 0.9960 0.4215E-05 0.4232E-05 S2,gas 0.9567E-23 1.0000 0.9764E-23 0.9764E-23 CO,gas 0.1175E-11 1.0000 0.1199E-11 0.1199E-11 SO3,gas 0.2468E-39 1.0000 0.2519E-39 0.2519E-39 SO2,gas 0.2509E-20 1.0000 0.2561E-20 0.2561E-20 HF,gas 0.1539E-13 1.0000 0.1571E-13 0.1571E-13 HCl,gas 0.8914E-17 1.0000 0.9098E-17 0.9098E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 17 albite -0.38 -0.38 0.00 0.000 -0.94784E-12 167 stilpnomelane-Fe 13.02 13.02 0.00 0.000 -0.27298E-10 150 quartz -2.99 -2.98 0.01 0.002 -0.86446E+01 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -13.12 -6.46 -2.154 0.11035E+05 -4.764 3 CH4,gas 4.54 -2.25 -6.79 -1.699 0.11602E+05 -5.096 4 H2,gas 8.00 2.72 -5.28 -3.018 0.90185E+04 -3.583 5 H2S,gas -6.23 -13.30 -7.07 -3.537 0.12079E+05 -5.375 6 S2,gas -7.34 -32.04 -24.71 -3.801 0.42191E+05 -23.010 7 CO,gas 3.21 -10.41 -13.62 -4.191 0.23256E+05 -11.921 8 SO3,gas 17.12 -24.18 -41.30 -10.324 0.70515E+05 -39.599 9 SO2,gas 0.83 -21.46 -22.29 -5.944 0.38061E+05 -20.592 10 HF,gas 0.47 -15.03 -15.50 -7.751 0.26471E+05 -13.804 11 HCl,gas 5.19 -13.55 -18.74 -9.370 0.31998E+05 -17.041 12 acmite 7.71 7.45 -0.26 -0.027 0.45166E+03 16 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 20 spessartine 24.46 19.48 -4.98 -0.249 0.85027E+04 21 analcite 3.32 2.60 -0.72 -0.080 0.12317E+04 23 andradite 39.01 38.39 -0.62 -0.032 0.10552E+04 24 grossular 32.73 28.70 -4.03 -0.202 0.68812E+04 27 annite 20.12 17.34 -2.78 -0.155 0.47495E+04 28 phlogopite 27.06 24.36 -2.70 -0.150 0.46129E+04 33 apatite-OH -18.15 -21.15 -3.00 -0.230 0.51160E+04 34 apatite-F -34.30 -36.18 -1.88 -0.157 0.32069E+04 38 aragonite 0.97 -0.84 -1.81 -0.603 0.30887E+04 39 brucite 12.57 8.95 -3.62 -0.724 0.61779E+04 40 calcite 0.81 -0.84 -1.65 -0.551 0.28245E+04 41 carnegieite-low 9.02 5.58 -3.44 -0.491 0.58710E+04 42 carnegieite-high 10.09 5.58 -4.51 -0.644 0.76980E+04 43 carpholite-Mg 8.58 3.79 -4.79 -0.319 0.81750E+04 45 celadonite 5.34 3.48 -1.86 -0.110 0.31824E+04 46 celadonite-Fe 3.88 1.14 -2.74 -0.161 0.46770E+04 47 chrysotile 23.89 20.88 -3.01 -0.251 0.51393E+04 49 clinochlore 39.07 36.61 -2.46 -0.077 0.41968E+04 50 daphnite 28.97 24.91 -4.06 -0.127 0.69250E+04 54 chloritoid-Fe 9.17 4.44 -4.74 -0.316 0.80855E+04 55 chloritoid-Mn 11.40 7.03 -4.37 -0.291 0.74562E+04 57 coesite -2.38 -2.98 -0.61 -0.203 0.10387E+04 64 cristobalite -2.56 -2.98 -0.42 -0.141 0.72403E+03 66 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71264E+04 68 diaspore 2.87 0.41 -2.47 -0.411 0.42130E+04 69 diamond -3.10 -7.69 -4.58 -1.310 0.78281E+04 70 diopside 16.18 15.26 -0.92 -0.092 0.15693E+04 71 hedenbergite 14.21 12.92 -1.29 -0.129 0.21965E+04 78 epidote 24.67 21.67 -3.00 -0.145 0.51192E+04 80 epidote-Fe 29.84 26.52 -3.32 -0.173 0.56762E+04 81 fayalite 14.05 10.24 -3.81 -0.544 0.65056E+04 82 ferrosilite 11.15 7.25 -3.90 -0.390 0.66560E+04 86 gibbsite 4.08 0.41 -3.67 -0.525 0.62715E+04 87 glaucophane 22.97 20.11 -2.86 -0.077 0.48834E+04 88 glaucophane-Fe 17.28 13.09 -4.18 -0.113 0.71411E+04 89 graphite -3.55 -7.69 -4.14 -1.183 0.70704E+04 90 greenalite 16.14 13.86 -2.28 -0.190 0.38900E+04 93 hematite 12.57 10.50 -2.06 -0.250 0.35245E+04 94 heulandite -5.83 -7.80 -1.97 -0.090 0.33639E+04 98 jadeite 4.22 2.60 -1.61 -0.161 0.27572E+04 99 julgoldite 70.43 65.44 -4.99 -0.130 0.85145E+04 100 kalsilite 7.58 3.48 -4.10 -0.586 0.70064E+04 101 kaolinite -1.33 -5.16 -3.82 -0.348 0.65282E+04 104 laumontite 2.88 1.16 -1.73 -0.115 0.29499E+04 105 lawsonite 9.62 7.12 -2.49 -0.166 0.42543E+04 106 leucite 4.12 0.50 -3.62 -0.362 0.61857E+04 108 lizardite 23.24 20.88 -2.36 -0.197 0.40319E+04 109 magnesite 0.69 -4.17 -4.86 -1.621 0.83038E+04 110 magnetite 20.09 17.11 -2.98 -0.243 0.50804E+04 111 minnesotaite 10.39 7.89 -2.50 -0.147 0.42611E+04 115 manganosite 14.06 9.21 -4.85 -1.213 0.82848E+04 119 microcline -2.49 -2.49 0.00 0.000 0.29822E+01 123 muscovite 2.58 -1.68 -4.26 -0.250 0.72705E+04 124 paragonite 4.24 0.43 -3.81 -0.224 0.65066E+04 125 nepheline 8.34 5.58 -2.75 -0.394 0.47034E+04 137 phlogopite-Na 29.65 26.47 -3.18 -0.177 0.54287E+04 139 prehnite 19.37 16.42 -2.95 -0.174 0.50390E+04 140 prehnite-Fe 22.50 21.27 -1.23 -0.074 0.21043E+04 145 pyrite -21.25 -22.72 -1.47 -0.346 0.25098E+04 146 pyrrhotite -4.26 -6.69 -2.43 -0.811 0.41562E+04 147 pyrrhotiteFe0.875 -6.02 -7.86 -1.84 -0.677 0.31430E+04 148 pyroxmangite 7.40 6.22 -1.18 -0.235 0.20097E+04 149 pyrophyllite -6.18 -11.12 -4.95 -0.309 0.84504E+04 154 rhodochrosite -0.98 -3.92 -2.94 -0.980 0.50211E+04 155 rhodonite 7.45 6.22 -1.22 -0.245 0.20900E+04 156 sanidine -1.28 -2.49 -1.21 -0.093 0.20707E+04 158 siderite -2.61 -6.51 -3.90 -1.302 0.66675E+04 166 stilbite -7.52 -7.80 -0.28 -0.013 0.47006E+03 168 stilpnomelane-Mg 27.44 24.72 -2.72 -0.081 0.46484E+04 174 talc 16.49 14.91 -1.58 -0.093 0.26932E+04 177 tephroite 18.09 15.43 -2.66 -0.380 0.45386E+04 181 tridymite -2.63 -2.98 -0.36 -0.119 0.61133E+03 182 tremolite 47.87 45.44 -2.43 -0.066 0.41507E+04 183 ferroactinolite 38.45 33.74 -4.72 -0.127 0.80526E+04 184 troilite-low -4.41 -6.69 -2.28 -0.761 0.38990E+04 190 wairakite 3.95 1.16 -2.79 -0.164 0.47719E+04 191 walstromite 11.51 9.30 -2.21 -0.443 0.37786E+04 192 wollastonite 10.46 9.30 -1.16 -0.233 0.19890E+04 193 pseudo-wollastonite 11.00 9.30 -1.70 -0.341 0.29089E+04 195 akaganeite 7.75 5.25 -2.50 -0.541 0.42748E+04 202 chalcedony -2.80 -2.98 -0.18 -0.061 0.31065E+03 204 montmorillonite-Ca -2.29 -6.28 -3.99 -0.247 0.68099E+04 205 montmorillonite-K -2.24 -6.31 -4.07 -0.249 0.69481E+04 206 montmorillonite-Mg -2.48 -6.83 -4.35 -0.269 0.74251E+04 207 montmorillonite-Na -2.04 -5.61 -3.57 -0.219 0.61021E+04 208 nontronite-Ca 3.21 1.71 -1.50 -0.098 0.25694E+04 209 nontronite-H 2.53 -0.32 -2.85 -0.191 0.48650E+04 210 nontronite-K 3.34 1.68 -1.66 -0.106 0.28308E+04 211 nontronite-Mg 3.07 1.16 -1.91 -0.124 0.32687E+04 212 nontronite-Na 3.52 2.38 -1.14 -0.073 0.19507E+04 228 tobermorite 9.82 7.25 -2.58 -0.703 0.44013E+04 234 alabandite -0.98 -4.10 -3.12 -1.040 0.53282E+04 237 boehmite 4.41 0.41 -4.00 -0.667 0.68299E+04 239 ferrous-oxide 9.81 6.61 -3.20 -0.800 0.54666E+04 245 silica-amorphous -2.09 -2.98 -0.89 -0.298 0.15248E+04 247 an20ab80 2.02 1.12 -0.90 -0.069 0.15367E+04 248 an25ab75 2.65 1.49 -1.15 -0.089 0.19678E+04 249 an30ab70 3.28 1.87 -1.41 -0.109 0.24086E+04 250 tr.625ac.25prg.125 45.16 43.31 -1.85 -0.050 0.31620E+04 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 7 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 0.0219900 Water: Moles liquid = 0.4987E+02 kg liquid = 0.8984E+00 Moles total = 0.4986E+02 kg total = 0.8983E+00 Activity = 1.0000 Stoichiometric ionic strength = .1274263E-01 Osmotic coef. = 0.9388 True ionic strength = .2121064E-01 Chg. balance for total moles = -.5508E-08 Max. difference allowed = 0.2676E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.13519E-09 -9.8690 0.11319E-09 -9.9462 0.83725E+00 -0.0771 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.29652E-03 -3.5279 0.24670E-03 -3.6078 0.83198E+00 -0.0799 4 SO4-- 0.10012E-03 -3.9995 0.51212E-04 -4.2906 0.51148E+00 -0.2912 5 HCO3- 0.78934E-03 -3.1027 0.65772E-03 -3.1820 0.83325E+00 -0.0792 6 HS- 0.52275E-03 -3.2817 0.43499E-03 -3.3615 0.83211E+00 -0.0798 7 Al+++ 0.17021E-28 -28.7690 0.37976E-29 -29.4205 0.22312E+00 -0.6515 8 H4SiO4 0.10246E-02 -2.9894 0.10246E-02 -2.9894 0.10000E+01 0.0000 9 Ca++ 0.48766E-07 -7.3119 0.24751E-07 -7.6064 0.50755E+00 -0.2945 10 Mg++ 0.22869E-10 -10.6407 0.11552E-10 -10.9374 0.50512E+00 -0.2966 11 Fe++ 0.10395E-12 -12.9832 0.52566E-13 -13.2793 0.50570E+00 -0.2961 12 K+ 0.15658E-03 -3.8053 0.13050E-03 -3.8844 0.83346E+00 -0.0791 13 Na+ 0.19959E-01 -1.6999 0.16602E-01 -1.7798 0.83182E+00 -0.0800 14 Mn++ 0.40753E-10 -10.3898 0.20627E-10 -10.6856 0.50614E+00 -0.2957 15 F- 0.98699E-05 -5.0057 0.81939E-05 -5.0865 0.83019E+00 -0.0808 16 HPO4-- 0.45626E-07 -7.3408 0.23341E-07 -7.6319 0.51156E+00 -0.2911 18 HSiO3- 0.10159E-01 -1.9931 0.84524E-02 -2.0730 0.83198E+00 -0.0799 19 Ca(HSiO3)+ 0.57152E-08 -8.2430 0.47644E-08 -8.3220 0.83365E+00 -0.0790 20 Mg(HSiO3)+ 0.33196E-11 -11.4789 0.27674E-11 -11.5579 0.83365E+00 -0.0790 21 NaHSiO3,aq 0.22697E-02 -2.6440 0.22697E-02 -2.6440 0.10000E+01 0.0000 22 AlO+ 0.48371E-16 -16.3154 0.40324E-16 -16.3944 0.83365E+00 -0.0790 24 HAlO2,aq 0.70946E-10 -10.1491 0.70946E-10 -10.1491 0.10000E+01 0.0000 25 AlO2- 0.16708E-05 -5.7771 0.13874E-05 -5.8578 0.83041E+00 -0.0807 26 CH4,aq 0.54478E-08 -8.2638 0.54267E-08 -8.2655 0.99612E+00 -0.0017 27 C2H6,aq 0.25342E-19 -19.5962 0.25244E-19 -19.5978 0.99612E+00 -0.0017 31 CO,aq 0.79698E-15 -15.0986 0.79698E-15 -15.0986 0.10000E+01 0.0000 32 CO2,aq 0.15970E-06 -6.7967 0.15908E-06 -6.7984 0.99612E+00 -0.0017 33 CO3-2 0.99451E-03 -3.0024 0.50754E-03 -3.2945 0.51035E+00 -0.2921 34 CaCO3,aq 0.15752E-06 -6.8027 0.15752E-06 -6.8027 0.10000E+01 0.0000 35 Ca(HCO3)+ 0.49847E-09 -9.3024 0.41555E-09 -9.3814 0.83365E+00 -0.0790 36 CaCl+ 0.11854E-10 -10.9262 0.98817E-11 -11.0052 0.83365E+00 -0.0790 37 CaCl2,aq 0.57918E-15 -15.2372 0.57918E-15 -15.2372 0.10000E+01 0.0000 38 CaF+ 0.35519E-11 -11.4495 0.29610E-11 -11.5286 0.83365E+00 -0.0790 39 CaOH+ 0.18694E-07 -7.7283 0.15584E-07 -7.8073 0.83365E+00 -0.0790 40 CaSO4,aq 0.40251E-09 -9.3952 0.40251E-09 -9.3952 0.10000E+01 0.0000 41 HCl,aq 0.51170E-14 -14.2910 0.51170E-14 -14.2910 0.10000E+01 0.0000 45 HF,aq 0.63492E-11 -11.1973 0.63492E-11 -11.1973 0.10000E+01 0.0000 46 HF2- 0.21112E-16 -16.6755 0.17565E-16 -16.7554 0.83198E+00 -0.0799 48 FeCl+ 0.24622E-16 -16.6087 0.20526E-16 -16.6877 0.83365E+00 -0.0790 51 FeF+ 0.26402E-16 -16.5784 0.22010E-16 -16.6574 0.83365E+00 -0.0790 53 FeO,aq 0.15946E-09 -9.7974 0.15946E-09 -9.7974 0.10000E+01 0.0000 54 FeOH+ 0.18133E-10 -10.7415 0.15117E-10 -10.8205 0.83365E+00 -0.0790 55 HFeO2- 0.17717E-07 -7.7516 0.14740E-07 -7.8315 0.83198E+00 -0.0799 56 FeO+ 0.96849E-16 -16.0139 0.80738E-16 -16.0929 0.83365E+00 -0.0790 58 FeO2- 0.15499E-08 -8.8097 0.12894E-08 -8.8896 0.83198E+00 -0.0799 59 HFeO2,aq 0.18563E-10 -10.7314 0.18563E-10 -10.7314 0.10000E+01 0.0000 60 H2,aq 0.20021E-06 -6.6985 0.19944E-06 -6.7002 0.99612E+00 -0.0017 61 KCl,aq 0.58350E-09 -9.2340 0.58350E-09 -9.2340 0.10000E+01 0.0000 62 KHSO4,aq 0.21388E-17 -17.6698 0.21388E-17 -17.6698 0.10000E+01 0.0000 63 KOH,aq 0.49236E-06 -6.3077 0.49236E-06 -6.3077 0.10000E+01 0.0000 64 KSO4- 0.12465E-06 -6.9043 0.10371E-06 -6.9842 0.83198E+00 -0.0799 65 MgCO3,aq 0.18427E-10 -10.7345 0.18427E-10 -10.7345 0.10000E+01 0.0000 66 Mg(HCO3)+ 0.23772E-12 -12.6239 0.19817E-12 -12.7030 0.83365E+00 -0.0790 67 MgCl+ 0.50141E-14 -14.2998 0.41800E-14 -14.3788 0.83365E+00 -0.0790 68 MgF+ 0.61407E-14 -14.2118 0.51192E-14 -14.2908 0.83365E+00 -0.0790 69 MgOH+ 0.48279E-10 -10.3162 0.40248E-10 -10.3953 0.83365E+00 -0.0790 71 MnF+ 0.34149E-14 -14.4666 0.28468E-14 -14.5456 0.83365E+00 -0.0790 72 MnO,aq 0.16672E-08 -8.7780 0.16672E-08 -8.7780 0.10000E+01 0.0000 73 MnOH+ 0.66100E-09 -9.1798 0.55104E-09 -9.2588 0.83365E+00 -0.0790 74 MnO2-2 0.84622E-11 -11.0725 0.43187E-11 -11.3647 0.51035E+00 -0.2921 75 HMnO2- 0.12872E-09 -9.8903 0.10710E-09 -9.9702 0.83198E+00 -0.0799 78 MnCl+ 0.37589E-13 -13.4249 0.31336E-13 -13.5040 0.83365E+00 -0.0790 79 MnSO4,aq 0.30495E-12 -12.5158 0.30495E-12 -12.5158 0.10000E+01 0.0000 80 NaCl,aq 0.13574E-05 -5.8673 0.13574E-05 -5.8673 0.10000E+01 0.0000 81 NaF,aq 0.31849E-07 -7.4969 0.31849E-07 -7.4969 0.10000E+01 0.0000 82 NaOH,aq 0.63019E-04 -4.2005 0.63019E-04 -4.2005 0.10000E+01 0.0000 84 OH- 0.61469E-02 -2.2113 0.51044E-02 -2.2921 0.83041E+00 -0.0807 89 HPO3-2 0.28425E-16 -16.5463 0.14507E-16 -16.8384 0.51035E+00 -0.2921 92 H3PO4,aq 0.20915E-17 -17.6795 0.20915E-17 -17.6795 0.10000E+01 0.0000 93 H2PO4- 0.58521E-10 -10.2327 0.48737E-10 -10.3121 0.83280E+00 -0.0795 94 PO4-3 0.71631E-09 -9.1449 0.16824E-09 -9.7741 0.23487E+00 -0.6292 98 HP2O7-3 0.14710E-17 -17.8324 0.32855E-18 -18.4834 0.22336E+00 -0.6510 99 P2O7-4 0.95550E-17 -17.0198 0.69342E-18 -18.1590 0.72572E-01 -1.1392 100 H2S,aq 0.15276E-06 -6.8160 0.15217E-06 -6.8177 0.99612E+00 -0.0017 101 S2-2 0.41192E-10 -10.3852 0.21022E-10 -10.6773 0.51035E+00 -0.2921 102 S3-2 0.42344E-16 -16.3732 0.21610E-16 -16.6653 0.51035E+00 -0.2921 107 SO3-2 0.25619E-11 -11.5914 0.13272E-11 -11.8770 0.51807E+00 -0.2856 108 HSO3- 0.11306E-13 -13.9467 0.94064E-14 -14.0266 0.83198E+00 -0.0799 109 HSO4- 0.66943E-11 -11.1743 0.55864E-11 -11.2529 0.83450E+00 -0.0786 111 S2O3-2 0.17937E-12 -12.7462 0.91543E-13 -13.0384 0.51035E+00 -0.2921 Charge balance for all species = -.6130E-08 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.1351942E-09 -.1964059E-01 -.1976049E+02 0.0000 2 H2O 0.1000000E+01 0.5550203E+02 0.9980650E+06 0.0000 3 Cl- 0.2965239E-03 0.2978819E-03 0.1054158E+02 6.3384 4 SO4-- 0.1001244E-03 0.1001942E-03 0.9607288E+01 15.6017 5 HCO3- 0.7893391E-03 0.1784170E-02 0.1086668E+03 6.7642 6 HS- 0.5227550E-03 0.5229631E-03 0.1726394E+02 6.5847 7 Al+++ 0.1702059E-28 0.1670856E-05 0.4500011E-01 0.4181 8 H4SiO4 0.1024625E-02 0.1345367E-01 0.1290750E+04 -2.9894 9 Ca++ 0.4876599E-07 0.2316086E-06 0.9265507E-02 12.2860 10 Mg++ 0.2286938E-10 0.9314420E-10 0.2260398E-05 8.9550 11 Fe++ 0.1039463E-12 0.1946272E-07 0.1084955E-02 6.6131 12 K+ 0.1565770E-03 0.1571946E-03 0.6135429E+01 6.0618 13 Na+ 0.1995921E-01 0.2229327E-01 0.5115845E+03 8.1664 14 Mn++ 0.4075319E-10 0.2506535E-08 0.1374532E-03 9.2068 15 F- 0.9869890E-05 0.9901748E-05 0.1877709E+00 4.8597 16 HPO4-- 0.4562647E-07 0.4640130E-07 0.4445440E-02 12.2605 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.1765877E-01 -.1764564E-01 -.1312252E-04 0.0000000E+00 2 H2O 0.4986441E+02 0.4986454E+02 -.1251763E-03 0.0000000E+00 3 Cl- 0.2676252E-03 0.2676252E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.9001719E-04 0.9001719E-04 0.0000000E+00 0.0000000E+00 5 HCO3- 0.1602947E-02 0.1602947E-02 0.0000000E+00 0.0000000E+00 6 HS- 0.4698443E-03 0.4698443E-03 0.0000000E+00 0.0000000E+00 7 Al+++ 0.4775352E-05 0.1501143E-05 0.3274209E-05 0.0000000E+00 8 H4SiO4 0.1215302E-01 0.1208714E-01 0.6587824E-04 0.0000000E+00 9 Ca++ 0.2080835E-06 0.2080835E-06 0.0000000E+00 0.0000000E+00 10 Mg++ 0.8368328E-10 0.8368328E-10 0.0000000E+00 0.0000000E+00 11 Fe++ 0.3259227E-07 0.1748584E-07 0.1510643E-07 0.0000000E+00 12 K+ 0.1412294E-03 0.1412279E-03 0.1510643E-08 0.0000000E+00 13 Na+ 0.2003215E-01 0.2002888E-01 0.3268167E-05 0.0000000E+00 14 Mn++ 0.2251939E-08 0.2251939E-08 0.0000000E+00 0.0000000E+00 15 F- 0.8896000E-05 0.8896000E-05 0.0000000E+00 0.0000000E+00 16 HPO4-- 0.4168819E-07 0.4168819E-07 0.0000000E+00 0.0000000E+00 Chg. balance for solid moles: -.8470E-21 Mass of aqueous solution: 0.900066E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 0.0219900 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 0.3268E-05 -5.486 0.8570E-03 -3.067 20.27 0.3290E-03 stilpnomelane-Fe 0.3021E-08 -8.520 0.3257E-05 -5.487 0.7704E-01 0.1125E-05 quartz 0.5605E-04 -4.251 0.3367E-02 -2.473 79.65 0.1272E-02 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 quartz 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 0.004228 g Volume = 0.001602 cm3 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.0219900 moles log = -1.6578 Original solution: 1000.0103000 g Original solution / Rock added: 45475.68 (Water/Rock Ratio), log = 4.6578 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0206 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9997E+00 0.9859 0.1006E+01 0.1020E+01 CO2,gas 0.1656E-04 1.0071 0.1702E-04 0.1690E-04 CH4,gas 0.7730E-05 1.0125 0.7988E-05 0.7889E-05 H2,gas 0.2564E-03 1.0005 0.2618E-03 0.2617E-03 H2S,gas 0.4115E-05 0.9960 0.4183E-05 0.4200E-05 S2,gas 0.9387E-23 1.0000 0.9580E-23 0.9580E-23 CO,gas 0.1164E-11 1.0000 0.1188E-11 0.1188E-11 SO3,gas 0.2431E-39 1.0000 0.2481E-39 0.2481E-39 SO2,gas 0.2476E-20 1.0000 0.2527E-20 0.2527E-20 HF,gas 0.1527E-13 1.0000 0.1559E-13 0.1559E-13 HCl,gas 0.8847E-17 1.0000 0.9029E-17 0.9029E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 17 albite -0.38 -0.38 0.00 0.000 -0.13080E-10 150 quartz -2.99 -2.99 0.00 0.000 0.00000E+00 167 stilpnomelane-Fe 13.02 13.02 0.00 0.000 0.21232E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -13.13 -6.47 -2.156 0.11044E+05 -4.769 3 CH4,gas 4.54 -2.25 -6.80 -1.699 0.11605E+05 -5.098 4 H2,gas 8.00 2.72 -5.28 -3.018 0.90171E+04 -3.582 5 H2S,gas -6.23 -13.31 -7.08 -3.539 0.12085E+05 -5.379 6 S2,gas -7.34 -32.05 -24.72 -3.803 0.42205E+05 -23.019 7 CO,gas 3.21 -10.41 -13.62 -4.192 0.23263E+05 -11.925 8 SO3,gas 17.12 -24.18 -41.30 -10.326 0.70526E+05 -39.605 9 SO2,gas 0.83 -21.46 -22.30 -5.946 0.38070E+05 -20.597 10 HF,gas 0.47 -15.03 -15.51 -7.753 0.26476E+05 -13.807 11 HCl,gas 5.19 -13.55 -18.74 -9.372 0.32004E+05 -17.044 12 acmite 7.71 7.44 -0.27 -0.028 0.45855E+03 16 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 20 spessartine 24.46 19.49 -4.97 -0.248 0.84845E+04 21 analcite 3.32 2.61 -0.72 -0.080 0.12231E+04 23 andradite 39.01 38.40 -0.61 -0.032 0.10446E+04 24 grossular 32.73 28.73 -4.01 -0.200 0.68396E+04 27 annite 20.12 17.35 -2.77 -0.154 0.47341E+04 28 phlogopite 27.06 24.38 -2.69 -0.149 0.45896E+04 33 apatite-OH -18.15 -21.14 -2.99 -0.230 0.51044E+04 34 apatite-F -34.30 -36.18 -1.87 -0.156 0.32009E+04 38 aragonite 0.97 -0.84 -1.81 -0.603 0.30883E+04 39 brucite 12.57 8.96 -3.61 -0.723 0.61700E+04 40 calcite 0.81 -0.84 -1.65 -0.551 0.28241E+04 41 carnegieite-low 9.02 5.60 -3.43 -0.490 0.58537E+04 42 carnegieite-high 10.09 5.60 -4.50 -0.643 0.76807E+04 43 carpholite-Mg 8.58 3.81 -4.77 -0.318 0.81443E+04 45 celadonite 5.34 3.48 -1.86 -0.110 0.31835E+04 46 celadonite-Fe 3.88 1.14 -2.74 -0.161 0.46807E+04 47 chrysotile 23.89 20.89 -3.01 -0.251 0.51330E+04 49 clinochlore 39.07 36.64 -2.43 -0.076 0.41432E+04 50 daphnite 28.97 24.93 -4.03 -0.126 0.68845E+04 54 chloritoid-Fe 9.17 4.46 -4.71 -0.314 0.80487E+04 55 chloritoid-Mn 11.40 7.05 -4.35 -0.290 0.74233E+04 57 coesite -2.38 -2.99 -0.61 -0.204 0.10473E+04 64 cristobalite -2.56 -2.99 -0.43 -0.143 0.73267E+03 66 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71267E+04 68 diaspore 2.87 0.42 -2.46 -0.409 0.41929E+04 69 diamond -3.10 -7.69 -4.59 -1.311 0.78341E+04 70 diopside 16.18 15.26 -0.92 -0.092 0.15696E+04 71 hedenbergite 14.21 12.92 -1.29 -0.129 0.21994E+04 78 epidote 24.67 21.69 -2.98 -0.144 0.50822E+04 80 epidote-Fe 29.84 26.53 -3.31 -0.172 0.56547E+04 81 fayalite 14.05 10.24 -3.81 -0.544 0.65038E+04 82 ferrosilite 11.15 7.25 -3.90 -0.390 0.66628E+04 86 gibbsite 4.08 0.42 -3.66 -0.523 0.62515E+04 87 glaucophane 22.97 20.12 -2.86 -0.077 0.48771E+04 88 glaucophane-Fe 17.28 13.09 -4.18 -0.113 0.71427E+04 89 graphite -3.55 -7.69 -4.14 -1.184 0.70763E+04 90 greenalite 16.14 13.86 -2.28 -0.190 0.38916E+04 93 hematite 12.57 10.51 -2.06 -0.250 0.35154E+04 94 heulandite -5.83 -7.80 -1.98 -0.090 0.33751E+04 98 jadeite 4.22 2.61 -1.61 -0.161 0.27485E+04 99 julgoldite 70.43 65.45 -4.98 -0.129 0.85012E+04 100 kalsilite 7.58 3.49 -4.09 -0.585 0.69895E+04 101 kaolinite -1.33 -5.14 -3.81 -0.346 0.65054E+04 104 laumontite 2.88 1.16 -1.72 -0.115 0.29352E+04 105 lawsonite 9.62 7.14 -2.47 -0.165 0.42223E+04 106 leucite 4.12 0.50 -3.62 -0.362 0.61774E+04 108 lizardite 23.24 20.89 -2.36 -0.196 0.40256E+04 109 magnesite 0.69 -4.17 -4.86 -1.621 0.83047E+04 110 magnetite 20.09 17.12 -2.97 -0.242 0.50660E+04 111 minnesotaite 10.39 7.88 -2.51 -0.147 0.42800E+04 115 manganosite 14.06 9.21 -4.85 -1.213 0.82835E+04 119 microcline -2.49 -2.49 0.00 0.000 0.33000E+01 123 muscovite 2.58 -1.65 -4.23 -0.249 0.72306E+04 124 paragonite 4.24 0.45 -3.79 -0.223 0.64664E+04 125 nepheline 8.34 5.60 -2.74 -0.392 0.46861E+04 137 phlogopite-Na 29.65 26.48 -3.17 -0.176 0.54051E+04 139 prehnite 19.37 16.44 -2.93 -0.172 0.50065E+04 140 prehnite-Fe 22.50 21.28 -1.22 -0.074 0.20873E+04 145 pyrite -21.25 -22.72 -1.47 -0.347 0.25172E+04 146 pyrrhotite -4.26 -6.69 -2.43 -0.811 0.41565E+04 147 pyrrhotiteFe0.875 -6.02 -7.86 -1.84 -0.677 0.31442E+04 148 pyroxmangite 7.40 6.22 -1.18 -0.236 0.20170E+04 149 pyrophyllite -6.18 -11.12 -4.95 -0.309 0.84448E+04 154 rhodochrosite -0.98 -3.92 -2.95 -0.982 0.50285E+04 155 rhodonite 7.45 6.22 -1.23 -0.246 0.20973E+04 156 sanidine -1.28 -2.49 -1.21 -0.093 0.20710E+04 158 siderite -2.61 -6.52 -3.91 -1.302 0.66710E+04 166 stilbite -7.52 -7.80 -0.28 -0.013 0.48128E+03 168 stilpnomelane-Mg 27.44 24.73 -2.71 -0.081 0.46353E+04 174 talc 16.49 14.91 -1.58 -0.093 0.27042E+04 177 tephroite 18.09 15.42 -2.66 -0.380 0.45446E+04 181 tridymite -2.63 -2.99 -0.36 -0.121 0.61998E+03 182 tremolite 47.87 45.43 -2.44 -0.066 0.41622E+04 183 ferroactinolite 38.45 33.72 -4.73 -0.128 0.80772E+04 184 troilite-low -4.41 -6.69 -2.28 -0.761 0.38993E+04 190 wairakite 3.95 1.16 -2.79 -0.164 0.47571E+04 191 walstromite 11.51 9.30 -2.21 -0.443 0.37781E+04 192 wollastonite 10.46 9.30 -1.16 -0.233 0.19885E+04 193 pseudo-wollastonite 11.00 9.30 -1.70 -0.341 0.29084E+04 195 akaganeite 7.75 5.25 -2.50 -0.541 0.42702E+04 202 chalcedony -2.80 -2.99 -0.19 -0.062 0.31930E+03 204 montmorillonite-Ca -2.29 -6.28 -3.99 -0.247 0.68068E+04 205 montmorillonite-K -2.24 -6.30 -4.07 -0.249 0.69448E+04 206 montmorillonite-Mg -2.48 -6.83 -4.35 -0.269 0.74223E+04 207 montmorillonite-Na -2.04 -5.61 -3.57 -0.219 0.60986E+04 208 nontronite-Ca 3.21 1.70 -1.51 -0.098 0.25839E+04 209 nontronite-H 2.53 -0.33 -2.86 -0.192 0.48810E+04 210 nontronite-K 3.34 1.67 -1.67 -0.107 0.28450E+04 211 nontronite-Mg 3.07 1.15 -1.92 -0.125 0.32834E+04 212 nontronite-Na 3.52 2.37 -1.15 -0.074 0.19648E+04 228 tobermorite 9.82 7.24 -2.58 -0.703 0.44023E+04 234 alabandite -0.98 -4.10 -3.12 -1.041 0.53325E+04 237 boehmite 4.41 0.42 -3.99 -0.665 0.68098E+04 239 ferrous-oxide 9.81 6.61 -3.20 -0.800 0.54614E+04 245 silica-amorphous -2.09 -2.99 -0.90 -0.299 0.15335E+04 247 an20ab80 2.02 1.12 -0.90 -0.069 0.15303E+04 248 an25ab75 2.65 1.50 -1.15 -0.088 0.19598E+04 249 an30ab70 3.28 1.87 -1.40 -0.108 0.23990E+04 250 tr.625ac.25prg.125 45.16 43.31 -1.86 -0.050 0.31674E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 0.0010000 MOLES Current total amount of reactant added: 0.0219900 MOLES New total amount of reactant added: 0.0229900 MOLES Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.5508E-08 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 7 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 0.0229900 Water: Moles liquid = 0.4987E+02 kg liquid = 0.8984E+00 Moles total = 0.4987E+02 kg total = 0.8983E+00 Activity = 1.0000 Stoichiometric ionic strength = .1280761E-01 Osmotic coef. = 0.9384 True ionic strength = .2127559E-01 Chg. balance for total moles = -.5508E-08 Max. difference allowed = 0.2735E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.13644E-09 -9.8651 0.11421E-09 -9.9423 0.83709E+00 -0.0772 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.30305E-03 -3.5185 0.25208E-03 -3.5985 0.83181E+00 -0.0800 4 SO4-- 0.10543E-03 -3.9770 0.53882E-04 -4.2686 0.51107E+00 -0.2915 5 HCO3- 0.82877E-03 -3.0816 0.69043E-03 -3.1609 0.83308E+00 -0.0793 6 HS- 0.54447E-03 -3.2640 0.45296E-03 -3.3439 0.83194E+00 -0.0799 7 Al+++ 0.17662E-28 -28.7530 0.39333E-29 -29.4052 0.22270E+00 -0.6523 8 H4SiO4 0.10246E-02 -2.9894 0.10246E-02 -2.9894 0.10000E+01 0.0000 9 Ca++ 0.47526E-07 -7.3231 0.24102E-07 -7.6179 0.50713E+00 -0.2949 10 Mg++ 0.22808E-10 -10.6419 0.11511E-10 -10.9389 0.50470E+00 -0.2970 11 Fe++ 0.10566E-12 -12.9761 0.53389E-13 -13.2725 0.50528E+00 -0.2965 12 K+ 0.15657E-03 -3.8053 0.13047E-03 -3.8845 0.83329E+00 -0.0792 13 Na+ 0.19978E-01 -1.6995 0.16615E-01 -1.7795 0.83165E+00 -0.0801 14 Mn++ 0.41431E-10 -10.3827 0.20952E-10 -10.6788 0.50571E+00 -0.2961 15 F- 0.10313E-04 -4.9866 0.85603E-05 -5.0675 0.83001E+00 -0.0809 16 HPO4-- 0.45631E-07 -7.3407 0.23324E-07 -7.6322 0.51114E+00 -0.2915 18 HSiO3- 0.10071E-01 -1.9969 0.83770E-02 -2.0769 0.83181E+00 -0.0800 19 Ca(HSiO3)+ 0.55167E-08 -8.2583 0.45981E-08 -8.3374 0.83348E+00 -0.0791 20 Mg(HSiO3)+ 0.32791E-11 -11.4842 0.27331E-11 -11.5634 0.83348E+00 -0.0791 21 NaHSiO3,aq 0.22510E-02 -2.6476 0.22510E-02 -2.6476 0.10000E+01 0.0000 22 AlO+ 0.49219E-16 -16.3079 0.41023E-16 -16.3870 0.83348E+00 -0.0791 24 HAlO2,aq 0.71532E-10 -10.1455 0.71532E-10 -10.1455 0.10000E+01 0.0000 25 AlO2- 0.16699E-05 -5.7773 0.13864E-05 -5.8581 0.83023E+00 -0.0808 26 CH4,aq 0.56601E-08 -8.2472 0.56381E-08 -8.2489 0.99610E+00 -0.0017 27 C2H6,aq 0.27487E-19 -19.5609 0.27380E-19 -19.5626 0.99610E+00 -0.0017 31 CO,aq 0.84009E-15 -15.0757 0.84009E-15 -15.0757 0.10000E+01 0.0000 32 CO2,aq 0.16915E-06 -6.7717 0.16849E-06 -6.7734 0.99610E+00 -0.0017 33 CO3-2 0.10355E-02 -2.9848 0.52803E-03 -3.2773 0.50993E+00 -0.2925 34 CaCO3,aq 0.15958E-06 -6.7970 0.15958E-06 -6.7970 0.10000E+01 0.0000 35 Ca(HCO3)+ 0.50964E-09 -9.2927 0.42477E-09 -9.3718 0.83348E+00 -0.0791 36 CaCl+ 0.11797E-10 -10.9282 0.98324E-11 -11.0073 0.83348E+00 -0.0791 37 CaCl2,aq 0.58886E-15 -15.2300 0.58886E-15 -15.2300 0.10000E+01 0.0000 38 CaF+ 0.36141E-11 -11.4420 0.30123E-11 -11.5211 0.83348E+00 -0.0791 39 CaOH+ 0.18045E-07 -7.7436 0.15040E-07 -7.8227 0.83348E+00 -0.0791 40 CaSO4,aq 0.41239E-09 -9.3847 0.41239E-09 -9.3847 0.10000E+01 0.0000 41 HCl,aq 0.52757E-14 -14.2777 0.52757E-14 -14.2777 0.10000E+01 0.0000 45 HF,aq 0.66928E-11 -11.1744 0.66928E-11 -11.1744 0.10000E+01 0.0000 46 HF2- 0.23255E-16 -16.6335 0.19343E-16 -16.7135 0.83181E+00 -0.0800 48 FeCl+ 0.25559E-16 -16.5925 0.21303E-16 -16.6716 0.83348E+00 -0.0791 51 FeF+ 0.28021E-16 -16.5525 0.23355E-16 -16.6316 0.83348E+00 -0.0791 53 FeO,aq 0.15908E-09 -9.7984 0.15908E-09 -9.7984 0.10000E+01 0.0000 54 FeOH+ 0.18257E-10 -10.7386 0.15217E-10 -10.8177 0.83348E+00 -0.0791 55 HFeO2- 0.17521E-07 -7.7565 0.14574E-07 -7.8364 0.83181E+00 -0.0800 56 FeO+ 0.97744E-16 -16.0099 0.81467E-16 -16.0890 0.83348E+00 -0.0791 58 FeO2- 0.15364E-08 -8.8135 0.12780E-08 -8.8935 0.83181E+00 -0.0800 59 HFeO2,aq 0.18564E-10 -10.7313 0.18564E-10 -10.7313 0.10000E+01 0.0000 60 H2,aq 0.19925E-06 -6.7006 0.19848E-06 -6.7023 0.99610E+00 -0.0017 61 KCl,aq 0.59609E-09 -9.2247 0.59609E-09 -9.2247 0.10000E+01 0.0000 62 KHSO4,aq 0.22701E-17 -17.6440 0.22701E-17 -17.6440 0.10000E+01 0.0000 63 KOH,aq 0.48786E-06 -6.3117 0.48786E-06 -6.3117 0.10000E+01 0.0000 64 KSO4- 0.13115E-06 -6.8822 0.10909E-06 -6.9622 0.83181E+00 -0.0800 65 MgCO3,aq 0.19104E-10 -10.7189 0.19104E-10 -10.7189 0.10000E+01 0.0000 66 Mg(HCO3)+ 0.24872E-12 -12.6043 0.20730E-12 -12.6834 0.83348E+00 -0.0791 67 MgCl+ 0.51066E-14 -14.2919 0.42562E-14 -14.3710 0.83348E+00 -0.0791 68 MgF+ 0.63941E-14 -14.1942 0.53294E-14 -14.2733 0.83348E+00 -0.0791 69 MgOH+ 0.47691E-10 -10.3216 0.39749E-10 -10.4007 0.83348E+00 -0.0791 71 MnF+ 0.36246E-14 -14.4407 0.30210E-14 -14.5198 0.83348E+00 -0.0791 72 MnO,aq 0.16635E-08 -8.7790 0.16635E-08 -8.7790 0.10000E+01 0.0000 73 MnOH+ 0.66558E-09 -9.1768 0.55475E-09 -9.2559 0.83348E+00 -0.0791 74 MnO2-2 0.83000E-11 -11.0809 0.42324E-11 -11.3734 0.50993E+00 -0.2925 75 HMnO2- 0.12731E-09 -9.8951 0.10590E-09 -9.9751 0.83181E+00 -0.0800 78 MnCl+ 0.39023E-13 -13.4087 0.32525E-13 -13.4878 0.83348E+00 -0.0791 79 MnSO4,aq 0.32592E-12 -12.4869 0.32592E-12 -12.4869 0.10000E+01 0.0000 80 NaCl,aq 0.13880E-05 -5.8576 0.13880E-05 -5.8576 0.10000E+01 0.0000 81 NaF,aq 0.33298E-07 -7.4776 0.33298E-07 -7.4776 0.10000E+01 0.0000 82 NaOH,aq 0.62503E-04 -4.2041 0.62503E-04 -4.2041 0.10000E+01 0.0000 84 OH- 0.60933E-02 -2.2151 0.50589E-02 -2.2959 0.83023E+00 -0.0808 89 HPO3-2 0.28291E-16 -16.5484 0.14426E-16 -16.8408 0.50993E+00 -0.2925 92 H3PO4,aq 0.21278E-17 -17.6721 0.21278E-17 -17.6721 0.10000E+01 0.0000 93 H2PO4- 0.59017E-10 -10.2290 0.49140E-10 -10.3086 0.83264E+00 -0.0795 94 PO4-3 0.71064E-09 -9.1483 0.16662E-09 -9.7783 0.23447E+00 -0.6299 98 HP2O7-3 0.14848E-17 -17.8283 0.33103E-18 -18.4801 0.22294E+00 -0.6518 99 P2O7-4 0.95722E-17 -17.0190 0.69243E-18 -18.1596 0.72337E-01 -1.1406 100 H2S,aq 0.16051E-06 -6.7945 0.15989E-06 -6.7962 0.99610E+00 -0.0017 101 S2-2 0.44920E-10 -10.3476 0.22906E-10 -10.6401 0.50993E+00 -0.2925 102 S3-2 0.48751E-16 -16.3120 0.24860E-16 -16.6045 0.50993E+00 -0.2925 107 SO3-2 0.26846E-11 -11.5711 0.13897E-11 -11.8571 0.51767E+00 -0.2860 108 HSO3- 0.11947E-13 -13.9227 0.99379E-14 -14.0027 0.83181E+00 -0.0800 109 HSO4- 0.71082E-11 -11.1482 0.59306E-11 -11.2269 0.83433E+00 -0.0787 111 S2O3-2 0.19846E-12 -12.7023 0.10120E-12 -12.9948 0.50993E+00 -0.2925 Charge balance for all species = -.6130E-08 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.1364370E-09 -.1952037E-01 -.1963958E+02 0.0000 2 H2O 0.1000000E+01 0.5550209E+02 0.9980688E+06 0.0000 3 Cl- 0.3030545E-03 0.3044431E-03 0.1077379E+02 6.3438 4 SO4-- 0.1054307E-03 0.1055070E-03 0.1011674E+02 15.6160 5 HCO3- 0.8287673E-03 0.1864608E-02 0.1135663E+03 6.7814 6 HS- 0.5444691E-03 0.5446850E-03 0.1798107E+02 6.5984 7 Al+++ 0.1766161E-28 0.1669993E-05 0.4497699E-01 0.4216 8 H4SiO4 0.1024625E-02 0.1334653E-01 0.1280474E+04 -2.9894 9 Ca++ 0.4752634E-07 0.2316042E-06 0.9265355E-02 12.2666 10 Mg++ 0.2280845E-10 0.9314240E-10 0.2260361E-05 8.9457 11 Fe++ 0.1056633E-12 0.1925299E-07 0.1073267E-02 6.6120 12 K+ 0.1565719E-03 0.1571915E-03 0.6135328E+01 6.0578 13 Na+ 0.1997787E-01 0.2229284E-01 0.5115761E+03 8.1628 14 Mn++ 0.4143113E-10 0.2506486E-08 0.1374510E-03 9.2058 15 F- 0.1031346E-04 0.1034677E-04 0.1962106E+00 4.8748 16 HPO4-- 0.4563075E-07 0.4640040E-07 0.4445367E-02 12.2524 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.1755109E-01 -.1753797E-01 -.1312582E-04 0.0000000E+00 2 H2O 0.4986523E+02 0.4986555E+02 -.3172330E-03 0.0000000E+00 3 Cl- 0.2735252E-03 0.2735252E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.9479219E-04 0.9479219E-04 0.0000000E+00 0.0000000E+00 5 HCO3- 0.1675247E-02 0.1675247E-02 0.0000000E+00 0.0000000E+00 6 HS- 0.4893693E-03 0.4893693E-03 0.0000000E+00 0.0000000E+00 7 Al+++ 0.4775352E-05 0.1500396E-05 0.3274956E-05 0.0000000E+00 8 H4SiO4 0.1215302E-01 0.1199111E-01 0.1619075E-03 0.0000000E+00 9 Ca++ 0.2080835E-06 0.2080835E-06 0.0000000E+00 0.0000000E+00 10 Mg++ 0.8368328E-10 0.8368328E-10 0.0000000E+00 0.0000000E+00 11 Fe++ 0.3259227E-07 0.1729774E-07 0.1529453E-07 0.0000000E+00 12 K+ 0.1412294E-03 0.1412279E-03 0.1529453E-08 0.0000000E+00 13 Na+ 0.2003215E-01 0.2002888E-01 0.3268838E-05 0.0000000E+00 14 Mn++ 0.2251939E-08 0.2251939E-08 0.0000000E+00 0.0000000E+00 15 F- 0.9296000E-05 0.9296000E-05 0.0000000E+00 0.0000000E+00 16 HPO4-- 0.4168819E-07 0.4168819E-07 0.0000000E+00 0.0000000E+00 Chg. balance for solid moles: -.1694E-20 Mass of aqueous solution: 0.900081E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 0.0229900 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 0.3269E-05 -5.486 0.8572E-03 -3.067 8.574 0.3290E-03 quartz 0.1521E-03 -3.818 0.9137E-02 -2.039 91.39 0.3450E-02 stilpnomelane-Fe 0.3059E-08 -8.514 0.3297E-05 -5.482 0.3298E-01 0.1139E-05 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 quartz 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 0.009997 g Volume = 0.003781 cm3 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.0229900 moles log = -1.6385 Original solution: 1000.0103000 g Original solution / Rock added: 43497.62 (Water/Rock Ratio), log = 4.6385 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0206 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9997E+00 0.9859 0.1006E+01 0.1020E+01 CO2,gas 0.1754E-04 1.0071 0.1803E-04 0.1790E-04 CH4,gas 0.8031E-05 1.0125 0.8299E-05 0.8196E-05 H2,gas 0.2552E-03 1.0005 0.2606E-03 0.2604E-03 H2S,gas 0.4324E-05 0.9960 0.4395E-05 0.4413E-05 S2,gas 0.1046E-22 1.0000 0.1068E-22 0.1068E-22 CO,gas 0.1227E-11 1.0000 0.1252E-11 0.1252E-11 SO3,gas 0.2604E-39 1.0000 0.2657E-39 0.2657E-39 SO2,gas 0.2640E-20 1.0000 0.2694E-20 0.2694E-20 HF,gas 0.1610E-13 1.0000 0.1643E-13 0.1643E-13 HCl,gas 0.9121E-17 1.0000 0.9309E-17 0.9309E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 17 albite -0.38 -0.38 0.00 0.000 -0.94784E-12 150 quartz -2.99 -2.99 0.00 0.000 0.00000E+00 167 stilpnomelane-Fe 13.02 13.02 0.00 0.000 -0.27298E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -13.10 -6.44 -2.148 0.11001E+05 -4.744 3 CH4,gas 4.54 -2.24 -6.78 -1.695 0.11577E+05 -5.081 4 H2,gas 8.00 2.72 -5.28 -3.019 0.90206E+04 -3.584 5 H2S,gas -6.23 -13.29 -7.06 -3.528 0.12048E+05 -5.357 6 S2,gas -7.34 -32.01 -24.67 -3.795 0.42124E+05 -22.971 7 CO,gas 3.21 -10.39 -13.60 -4.185 0.23224E+05 -11.902 8 SO3,gas 17.12 -24.15 -41.27 -10.319 0.70475E+05 -39.576 9 SO2,gas 0.83 -21.44 -22.27 -5.938 0.38023E+05 -20.570 10 HF,gas 0.47 -15.01 -15.48 -7.742 0.26437E+05 -13.784 11 HCl,gas 5.19 -13.54 -18.73 -9.365 0.31981E+05 -17.031 12 acmite 7.71 7.44 -0.27 -0.028 0.46462E+03 16 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 20 spessartine 24.46 19.49 -4.96 -0.248 0.84773E+04 21 analcite 3.32 2.61 -0.72 -0.080 0.12231E+04 23 andradite 39.01 38.34 -0.67 -0.035 0.11436E+04 24 grossular 32.73 28.67 -4.06 -0.203 0.69263E+04 27 annite 20.12 17.35 -2.78 -0.154 0.47401E+04 28 phlogopite 27.06 24.35 -2.72 -0.151 0.46380E+04 33 apatite-OH -18.15 -21.22 -3.06 -0.236 0.52311E+04 34 apatite-F -34.30 -36.23 -1.93 -0.160 0.32885E+04 38 aragonite 0.97 -0.84 -1.80 -0.601 0.30787E+04 39 brucite 12.57 8.95 -3.62 -0.725 0.61859E+04 40 calcite 0.81 -0.84 -1.65 -0.549 0.28144E+04 41 carnegieite-low 9.02 5.60 -3.43 -0.490 0.58537E+04 42 carnegieite-high 10.09 5.60 -4.50 -0.643 0.76807E+04 43 carpholite-Mg 8.58 3.81 -4.77 -0.318 0.81479E+04 45 celadonite 5.34 3.47 -1.87 -0.110 0.32001E+04 46 celadonite-Fe 3.88 1.13 -2.74 -0.161 0.46832E+04 47 chrysotile 23.89 20.86 -3.03 -0.253 0.51806E+04 49 clinochlore 39.07 36.60 -2.47 -0.077 0.42105E+04 50 daphnite 28.97 24.94 -4.03 -0.126 0.68811E+04 54 chloritoid-Fe 9.17 4.47 -4.71 -0.314 0.80383E+04 55 chloritoid-Mn 11.40 7.06 -4.34 -0.289 0.74128E+04 57 coesite -2.38 -2.99 -0.61 -0.204 0.10473E+04 64 cristobalite -2.56 -2.99 -0.43 -0.143 0.73267E+03 66 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71274E+04 68 diaspore 2.87 0.42 -2.45 -0.409 0.41868E+04 69 diamond -3.10 -7.67 -4.57 -1.305 0.77986E+04 70 diopside 16.18 15.23 -0.95 -0.095 0.16184E+04 71 hedenbergite 14.21 12.90 -1.31 -0.131 0.22341E+04 78 epidote 24.67 21.66 -3.01 -0.146 0.51360E+04 80 epidote-Fe 29.84 26.49 -3.35 -0.174 0.57146E+04 81 fayalite 14.05 10.23 -3.81 -0.544 0.65073E+04 82 ferrosilite 11.15 7.25 -3.90 -0.390 0.66664E+04 86 gibbsite 4.08 0.42 -3.66 -0.523 0.62453E+04 87 glaucophane 22.97 20.09 -2.88 -0.078 0.49248E+04 88 glaucophane-Fe 17.28 13.09 -4.19 -0.113 0.71480E+04 89 graphite -3.55 -7.67 -4.12 -1.178 0.70408E+04 90 greenalite 16.14 13.86 -2.28 -0.190 0.38968E+04 93 hematite 12.57 10.51 -2.06 -0.250 0.35154E+04 94 heulandite -5.83 -7.82 -1.99 -0.090 0.33959E+04 98 jadeite 4.22 2.61 -1.61 -0.161 0.27485E+04 100 kalsilite 7.58 3.49 -4.09 -0.585 0.69902E+04 101 kaolinite -1.33 -5.14 -3.80 -0.346 0.64932E+04 104 laumontite 2.88 1.15 -1.73 -0.115 0.29560E+04 105 lawsonite 9.62 7.13 -2.48 -0.166 0.42431E+04 106 leucite 4.12 0.50 -3.62 -0.362 0.61781E+04 108 lizardite 23.24 20.86 -2.39 -0.199 0.40733E+04 109 magnesite 0.69 -4.16 -4.85 -1.616 0.82779E+04 110 magnetite 20.09 17.12 -2.97 -0.242 0.50677E+04 111 minnesotaite 10.39 7.88 -2.51 -0.148 0.42852E+04 115 manganosite 14.06 9.21 -4.85 -1.213 0.82851E+04 119 microcline -2.49 -2.49 0.00 0.000 0.40133E+01 123 muscovite 2.58 -1.65 -4.23 -0.249 0.72191E+04 124 paragonite 4.24 0.46 -3.78 -0.222 0.64542E+04 125 nepheline 8.34 5.60 -2.74 -0.392 0.46861E+04 137 phlogopite-Na 29.65 26.45 -3.19 -0.177 0.54528E+04 139 prehnite 19.37 16.41 -2.96 -0.174 0.50602E+04 140 prehnite-Fe 22.50 21.24 -1.26 -0.076 0.21472E+04 145 pyrite -21.25 -22.68 -1.43 -0.337 0.24421E+04 146 pyrrhotite -4.26 -6.67 -2.41 -0.805 0.41216E+04 147 pyrrhotiteFe0.875 -6.02 -7.84 -1.82 -0.670 0.31087E+04 148 pyroxmangite 7.40 6.22 -1.18 -0.236 0.20187E+04 149 pyrophyllite -6.18 -11.11 -4.94 -0.309 0.84326E+04 154 rhodochrosite -0.98 -3.90 -2.92 -0.974 0.49876E+04 155 rhodonite 7.45 6.22 -1.23 -0.246 0.20990E+04 156 sanidine -1.28 -2.49 -1.21 -0.093 0.20718E+04 158 siderite -2.61 -6.49 -3.88 -1.294 0.66301E+04 166 stilbite -7.52 -7.82 -0.29 -0.014 0.50207E+03 168 stilpnomelane-Mg 27.44 24.69 -2.76 -0.082 0.47059E+04 174 talc 16.49 14.88 -1.61 -0.095 0.27518E+04 177 tephroite 18.09 15.42 -2.66 -0.381 0.45480E+04 181 tridymite -2.63 -2.99 -0.36 -0.121 0.61998E+03 182 tremolite 47.87 45.35 -2.52 -0.068 0.43077E+04 183 ferroactinolite 38.45 33.68 -4.77 -0.129 0.81520E+04 184 troilite-low -4.41 -6.67 -2.26 -0.754 0.38644E+04 190 wairakite 3.95 1.15 -2.80 -0.165 0.47779E+04 191 walstromite 11.51 9.28 -2.23 -0.446 0.38111E+04 192 wollastonite 10.46 9.28 -1.18 -0.237 0.20215E+04 193 pseudo-wollastonite 11.00 9.28 -1.72 -0.345 0.29414E+04 195 akaganeite 7.75 5.25 -2.50 -0.541 0.42702E+04 202 chalcedony -2.80 -2.99 -0.19 -0.062 0.31930E+03 204 montmorillonite-Ca -2.29 -6.28 -3.99 -0.247 0.68073E+04 205 montmorillonite-K -2.24 -6.30 -4.07 -0.249 0.69421E+04 206 montmorillonite-Mg -2.48 -6.83 -4.35 -0.269 0.74199E+04 207 montmorillonite-Na -2.04 -5.61 -3.57 -0.219 0.60956E+04 208 nontronite-Ca 3.21 1.70 -1.52 -0.098 0.25873E+04 209 nontronite-H 2.53 -0.32 -2.86 -0.192 0.48790E+04 210 nontronite-K 3.34 1.67 -1.67 -0.107 0.28452E+04 211 nontronite-Mg 3.07 1.15 -1.92 -0.125 0.32840E+04 212 nontronite-Na 3.52 2.37 -1.15 -0.074 0.19648E+04 228 tobermorite 9.82 7.23 -2.59 -0.708 0.44298E+04 234 alabandite -0.98 -4.08 -3.10 -1.034 0.52975E+04 237 boehmite 4.41 0.42 -3.98 -0.664 0.68037E+04 239 ferrous-oxide 9.81 6.61 -3.20 -0.800 0.54631E+04 245 silica-amorphous -2.09 -2.99 -0.90 -0.299 0.15335E+04 247 an20ab80 2.02 1.12 -0.90 -0.069 0.15344E+04 248 an25ab75 2.65 1.49 -1.15 -0.089 0.19650E+04 249 an30ab70 3.28 1.87 -1.41 -0.108 0.24052E+04 250 tr.625ac.25prg.125 45.16 43.24 -1.93 -0.052 0.32917E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 0.0010000 MOLES Current total amount of reactant added: 0.0229900 MOLES New total amount of reactant added: 0.0239900 MOLES Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.5508E-08 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 7 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 0.0239900 Water: Moles liquid = 0.4987E+02 kg liquid = 0.8985E+00 Moles total = 0.4987E+02 kg total = 0.8984E+00 Activity = 1.0000 Stoichiometric ionic strength = .1287259E-01 Osmotic coef. = 0.9380 True ionic strength = .2134015E-01 Chg. balance for total moles = -.5508E-08 Max. difference allowed = 0.2794E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.13770E-09 -9.8611 0.11524E-09 -9.9384 0.83693E+00 -0.0773 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.30958E-03 -3.5092 0.25746E-03 -3.5893 0.83164E+00 -0.0801 4 SO4-- 0.11074E-03 -3.9557 0.56548E-04 -4.2476 0.51066E+00 -0.2919 5 HCO3- 0.86856E-03 -3.0612 0.72344E-03 -3.1406 0.83292E+00 -0.0794 6 HS- 0.56618E-03 -3.2470 0.47093E-03 -3.3270 0.83177E+00 -0.0800 7 Al+++ 0.18330E-28 -28.7368 0.40747E-29 -29.3899 0.22229E+00 -0.6531 8 H4SiO4 0.10246E-02 -2.9894 0.10246E-02 -2.9894 0.10000E+01 0.0000 9 Ca++ 0.46362E-07 -7.3338 0.23492E-07 -7.6291 0.50671E+00 -0.2952 10 Mg++ 0.22749E-10 -10.6430 0.11472E-10 -10.9404 0.50428E+00 -0.2973 11 Fe++ 0.10742E-12 -12.9689 0.54230E-13 -13.2658 0.50486E+00 -0.2968 12 K+ 0.15657E-03 -3.8053 0.13044E-03 -3.8846 0.83312E+00 -0.0793 13 Na+ 0.19996E-01 -1.6990 0.16627E-01 -1.7792 0.83148E+00 -0.0801 14 Mn++ 0.42123E-10 -10.3755 0.21285E-10 -10.6719 0.50530E+00 -0.2965 15 F- 0.10757E-04 -4.9683 0.89266E-05 -5.0493 0.82984E+00 -0.0810 16 HPO4-- 0.45635E-07 -7.3407 0.23307E-07 -7.6325 0.51073E+00 -0.2918 18 HSiO3- 0.99825E-02 -2.0008 0.83018E-02 -2.0808 0.83164E+00 -0.0801 19 Ca(HSiO3)+ 0.53300E-08 -8.2733 0.44416E-08 -8.3525 0.83331E+00 -0.0792 20 Mg(HSiO3)+ 0.32392E-11 -11.4896 0.26993E-11 -11.5688 0.83331E+00 -0.0792 21 NaHSiO3,aq 0.22325E-02 -2.6512 0.22325E-02 -2.6512 0.10000E+01 0.0000 22 AlO+ 0.50088E-16 -16.3003 0.41739E-16 -16.3795 0.83331E+00 -0.0792 24 HAlO2,aq 0.72128E-10 -10.1419 0.72128E-10 -10.1419 0.10000E+01 0.0000 25 AlO2- 0.16691E-05 -5.7775 0.13854E-05 -5.8584 0.83006E+00 -0.0809 26 CH4,aq 0.58753E-08 -8.2310 0.58523E-08 -8.2327 0.99608E+00 -0.0017 27 C2H6,aq 0.29753E-19 -19.5265 0.29636E-19 -19.5282 0.99608E+00 -0.0017 31 CO,aq 0.88414E-15 -15.0535 0.88414E-15 -15.0535 0.10000E+01 0.0000 32 CO2,aq 0.17885E-06 -6.7475 0.17815E-06 -6.7492 0.99608E+00 -0.0017 33 CO3-2 0.10761E-02 -2.9681 0.54831E-03 -3.2610 0.50952E+00 -0.2928 34 CaCO3,aq 0.16152E-06 -6.7918 0.16152E-06 -6.7918 0.10000E+01 0.0000 35 Ca(HCO3)+ 0.52060E-09 -9.2835 0.43382E-09 -9.3627 0.83331E+00 -0.0792 36 CaCl+ 0.11746E-10 -10.9301 0.97882E-11 -11.0093 0.83331E+00 -0.0792 37 CaCl2,aq 0.59872E-15 -15.2228 0.59872E-15 -15.2228 0.10000E+01 0.0000 38 CaF+ 0.36742E-11 -11.4348 0.30617E-11 -11.5140 0.83331E+00 -0.0792 39 CaOH+ 0.17434E-07 -7.7586 0.14528E-07 -7.8378 0.83331E+00 -0.0792 40 CaSO4,aq 0.42185E-09 -9.3748 0.42185E-09 -9.3748 0.10000E+01 0.0000 41 HCl,aq 0.54371E-14 -14.2646 0.54371E-14 -14.2646 0.10000E+01 0.0000 45 HF,aq 0.70424E-11 -11.1523 0.70424E-11 -11.1523 0.10000E+01 0.0000 46 HF2- 0.25522E-16 -16.5931 0.21225E-16 -16.6732 0.83164E+00 -0.0801 48 FeCl+ 0.26521E-16 -16.5764 0.22100E-16 -16.6556 0.83331E+00 -0.0792 51 FeF+ 0.29686E-16 -16.5274 0.24738E-16 -16.6066 0.83331E+00 -0.0792 53 FeO,aq 0.15870E-09 -9.7994 0.15870E-09 -9.7994 0.10000E+01 0.0000 54 FeOH+ 0.18382E-10 -10.7356 0.15318E-10 -10.8148 0.83331E+00 -0.0792 55 HFeO2- 0.17325E-07 -7.7613 0.14409E-07 -7.8414 0.83164E+00 -0.0801 56 FeO+ 0.98640E-16 -16.0059 0.82198E-16 -16.0851 0.83331E+00 -0.0792 58 FeO2- 0.15228E-08 -8.8174 0.12664E-08 -8.8974 0.83164E+00 -0.0801 59 HFeO2,aq 0.18562E-10 -10.7314 0.18562E-10 -10.7314 0.10000E+01 0.0000 60 H2,aq 0.19834E-06 -6.7026 0.19757E-06 -6.7043 0.99608E+00 -0.0017 61 KCl,aq 0.60867E-09 -9.2156 0.60867E-09 -9.2156 0.10000E+01 0.0000 62 KHSO4,aq 0.24034E-17 -17.6192 0.24034E-17 -17.6192 0.10000E+01 0.0000 63 KOH,aq 0.48337E-06 -6.3157 0.48337E-06 -6.3157 0.10000E+01 0.0000 64 KSO4- 0.13763E-06 -6.8613 0.11446E-06 -6.9413 0.83164E+00 -0.0801 65 MgCO3,aq 0.19770E-10 -10.7040 0.19770E-10 -10.7040 0.10000E+01 0.0000 66 Mg(HCO3)+ 0.25977E-12 -12.5854 0.21647E-12 -12.6646 0.83331E+00 -0.0792 67 MgCl+ 0.51988E-14 -14.2841 0.43322E-14 -14.3633 0.83331E+00 -0.0792 68 MgF+ 0.66463E-14 -14.1774 0.55384E-14 -14.2566 0.83331E+00 -0.0792 69 MgOH+ 0.47110E-10 -10.3269 0.39258E-10 -10.4061 0.83331E+00 -0.0792 71 MnF+ 0.38404E-14 -14.4156 0.32003E-14 -14.4948 0.83331E+00 -0.0792 72 MnO,aq 0.16597E-08 -8.7800 0.16597E-08 -8.7800 0.10000E+01 0.0000 73 MnOH+ 0.67020E-09 -9.1738 0.55849E-09 -9.2530 0.83331E+00 -0.0792 74 MnO2-2 0.81396E-11 -11.0894 0.41473E-11 -11.3822 0.50952E+00 -0.2928 75 HMnO2- 0.12591E-09 -9.8999 0.10471E-09 -9.9800 0.83164E+00 -0.0801 78 MnCl+ 0.40495E-13 -13.3926 0.33745E-13 -13.4718 0.83331E+00 -0.0792 79 MnSO4,aq 0.34747E-12 -12.4591 0.34747E-12 -12.4591 0.10000E+01 0.0000 80 NaCl,aq 0.14186E-05 -5.8481 0.14186E-05 -5.8481 0.10000E+01 0.0000 81 NaF,aq 0.34748E-07 -7.4591 0.34748E-07 -7.4591 0.10000E+01 0.0000 82 NaOH,aq 0.61987E-04 -4.2077 0.61987E-04 -4.2077 0.10000E+01 0.0000 84 OH- 0.60399E-02 -2.2190 0.50135E-02 -2.2999 0.83006E+00 -0.0809 89 HPO3-2 0.28164E-16 -16.5503 0.14350E-16 -16.8432 0.50952E+00 -0.2928 92 H3PO4,aq 0.21650E-17 -17.6646 0.21650E-17 -17.6646 0.10000E+01 0.0000 93 H2PO4- 0.59522E-10 -10.2253 0.49550E-10 -10.3050 0.83247E+00 -0.0796 94 PO4-3 0.70498E-09 -9.1518 0.16501E-09 -9.7825 0.23406E+00 -0.6307 98 HP2O7-3 0.14989E-17 -17.8242 0.33355E-18 -18.4768 0.22253E+00 -0.6526 99 P2O7-4 0.95893E-17 -17.0182 0.69144E-18 -18.1602 0.72106E-01 -1.1420 100 H2S,aq 0.16839E-06 -6.7737 0.16773E-06 -6.7754 0.99608E+00 -0.0017 101 S2-2 0.48817E-10 -10.3114 0.24873E-10 -10.6043 0.50952E+00 -0.2928 102 S3-2 0.55838E-16 -16.2531 0.28451E-16 -16.5459 0.50952E+00 -0.2928 107 SO3-2 0.28067E-11 -11.5518 0.14518E-11 -11.8381 0.51726E+00 -0.2863 108 HSO3- 0.12597E-13 -13.8997 0.10476E-13 -13.9798 0.83164E+00 -0.0801 109 HSO4- 0.75289E-11 -11.1233 0.62804E-11 -11.2020 0.83417E+00 -0.0787 111 S2O3-2 0.21868E-12 -12.6602 0.11142E-12 -12.9530 0.50952E+00 -0.2928 Charge balance for all species = -.6130E-08 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.1376984E-09 -.1940014E-01 -.1951868E+02 0.0000 2 H2O 0.1000000E+01 0.5550214E+02 0.9980725E+06 0.0000 3 Cl- 0.3095847E-03 0.3110040E-03 0.1100601E+02 6.3491 4 SO4-- 0.1107368E-03 0.1108196E-03 0.1062618E+02 15.6292 5 HCO3- 0.8685576E-03 0.1945043E-02 0.1184656E+03 6.7978 6 HS- 0.5661823E-03 0.5664061E-03 0.1869818E+02 6.6113 7 Al+++ 0.1833050E-28 0.1669129E-05 0.4495384E-01 0.4252 8 H4SiO4 0.1024625E-02 0.1323962E-01 0.1270222E+04 -2.9894 9 Ca++ 0.4636239E-07 0.2315997E-06 0.9265202E-02 12.2477 10 Mg++ 0.2274944E-10 0.9314060E-10 0.2260323E-05 8.9364 11 Fe++ 0.1074178E-12 0.1904401E-07 0.1061620E-02 6.6110 12 K+ 0.1565669E-03 0.1571885E-03 0.6135226E+01 6.0538 13 Na+ 0.1999650E-01 0.2229241E-01 0.5115677E+03 8.1592 14 Mn++ 0.4212292E-10 0.2506438E-08 0.1374487E-03 9.2048 15 F- 0.1075702E-04 0.1079178E-04 0.2046500E+00 4.8891 16 HPO4-- 0.4563501E-07 0.4639951E-07 0.4445294E-02 12.2443 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.1744342E-01 -.1743029E-01 -.1312913E-04 0.0000000E+00 2 H2O 0.4986605E+02 0.4986656E+02 -.5088625E-03 0.0000000E+00 3 Cl- 0.2794252E-03 0.2794252E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.9956719E-04 0.9956719E-04 0.0000000E+00 0.0000000E+00 5 HCO3- 0.1747547E-02 0.1747547E-02 0.0000000E+00 0.0000000E+00 6 HS- 0.5088943E-03 0.5088943E-03 0.0000000E+00 0.0000000E+00 7 Al+++ 0.4775352E-05 0.1499649E-05 0.3275703E-05 0.0000000E+00 8 H4SiO4 0.1215302E-01 0.1189530E-01 0.2577232E-03 0.0000000E+00 9 Ca++ 0.2080835E-06 0.2080835E-06 0.0000000E+00 0.0000000E+00 10 Mg++ 0.8368328E-10 0.8368328E-10 0.0000000E+00 0.0000000E+00 11 Fe++ 0.3259227E-07 0.1711031E-07 0.1548196E-07 0.0000000E+00 12 K+ 0.1412294E-03 0.1412279E-03 0.1548196E-08 0.0000000E+00 13 Na+ 0.2003215E-01 0.2002888E-01 0.3269511E-05 0.0000000E+00 14 Mn++ 0.2251939E-08 0.2251939E-08 0.0000000E+00 0.0000000E+00 15 F- 0.9696000E-05 0.9696000E-05 0.0000000E+00 0.0000000E+00 16 HPO4-- 0.4168819E-07 0.4168819E-07 0.0000000E+00 0.0000000E+00 Chg. balance for solid moles: -.1271E-20 Mass of aqueous solution: 0.900096E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 0.0239900 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 0.3270E-05 -5.486 0.8573E-03 -3.067 5.442 0.3291E-03 quartz 0.2479E-03 -3.606 0.1489E-01 -1.827 94.54 0.5624E-02 stilpnomelane-Fe 0.3096E-08 -8.509 0.3338E-05 -5.477 0.2119E-01 0.1153E-05 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 quartz 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 0.015754 g Volume = 0.005955 cm3 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.0239900 moles log = -1.6200 Original solution: 1000.0103000 g Original solution / Rock added: 41684.46 (Water/Rock Ratio), log = 4.6200 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0206 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9997E+00 0.9859 0.1006E+01 0.1020E+01 CO2,gas 0.1854E-04 1.0071 0.1906E-04 0.1893E-04 CH4,gas 0.8336E-05 1.0125 0.8614E-05 0.8508E-05 H2,gas 0.2540E-03 1.0005 0.2594E-03 0.2592E-03 H2S,gas 0.4536E-05 0.9960 0.4611E-05 0.4629E-05 S2,gas 0.1162E-22 1.0000 0.1186E-22 0.1186E-22 CO,gas 0.1291E-11 1.0000 0.1318E-11 0.1318E-11 SO3,gas 0.2782E-39 1.0000 0.2840E-39 0.2840E-39 SO2,gas 0.2808E-20 1.0000 0.2866E-20 0.2866E-20 HF,gas 0.1694E-13 1.0000 0.1729E-13 0.1729E-13 HCl,gas 0.9400E-17 1.0000 0.9594E-17 0.9594E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 17 albite -0.38 -0.38 0.00 0.000 -0.94784E-12 150 quartz -2.99 -2.99 0.00 0.000 0.00000E+00 167 stilpnomelane-Fe 13.02 13.02 0.00 0.000 0.21232E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -13.08 -6.42 -2.140 0.10960E+05 -4.720 3 CH4,gas 4.54 -2.22 -6.76 -1.691 0.11549E+05 -5.065 4 H2,gas 8.00 2.71 -5.29 -3.020 0.90240E+04 -3.586 5 H2S,gas -6.23 -13.27 -7.04 -3.518 0.12012E+05 -5.336 6 S2,gas -7.34 -31.96 -24.62 -3.788 0.42046E+05 -22.926 7 CO,gas 3.21 -10.36 -13.58 -4.178 0.23186E+05 -11.880 8 SO3,gas 17.12 -24.12 -41.25 -10.311 0.70426E+05 -39.547 9 SO2,gas 0.83 -21.41 -22.24 -5.931 0.37977E+05 -20.543 10 HF,gas 0.47 -14.99 -15.46 -7.731 0.26399E+05 -13.762 11 HCl,gas 5.19 -13.53 -18.72 -9.358 0.31959E+05 -17.018 12 acmite 7.71 7.43 -0.28 -0.029 0.47084E+03 16 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 20 spessartine 24.46 19.50 -4.96 -0.248 0.84702E+04 21 analcite 3.32 2.61 -0.72 -0.080 0.12231E+04 23 andradite 39.01 38.28 -0.73 -0.038 0.12408E+04 24 grossular 32.73 28.63 -4.11 -0.205 0.70111E+04 27 annite 20.12 17.34 -2.78 -0.154 0.47461E+04 28 phlogopite 27.06 24.32 -2.74 -0.152 0.46864E+04 33 apatite-OH -18.15 -21.29 -3.14 -0.241 0.53544E+04 34 apatite-F -34.30 -36.28 -1.98 -0.165 0.33741E+04 38 aragonite 0.97 -0.83 -1.80 -0.599 0.30697E+04 39 brucite 12.57 8.94 -3.63 -0.726 0.62018E+04 40 calcite 0.81 -0.83 -1.64 -0.548 0.28055E+04 41 carnegieite-low 9.02 5.60 -3.43 -0.490 0.58537E+04 42 carnegieite-high 10.09 5.60 -4.50 -0.643 0.76807E+04 43 carpholite-Mg 8.58 3.81 -4.77 -0.318 0.81516E+04 45 celadonite 5.34 3.46 -1.88 -0.111 0.32167E+04 46 celadonite-Fe 3.88 1.13 -2.74 -0.161 0.46857E+04 47 chrysotile 23.89 20.83 -3.06 -0.255 0.52284E+04 49 clinochlore 39.07 36.56 -2.51 -0.078 0.42777E+04 50 daphnite 28.97 24.94 -4.03 -0.126 0.68777E+04 54 chloritoid-Fe 9.17 4.47 -4.70 -0.313 0.80278E+04 55 chloritoid-Mn 11.40 7.07 -4.34 -0.289 0.74022E+04 57 coesite -2.38 -2.99 -0.61 -0.204 0.10473E+04 64 cristobalite -2.56 -2.99 -0.43 -0.143 0.73267E+03 66 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71281E+04 68 diaspore 2.87 0.43 -2.45 -0.408 0.41807E+04 69 diamond -3.10 -7.65 -4.55 -1.299 0.77641E+04 70 diopside 16.18 15.21 -0.98 -0.098 0.16667E+04 71 hedenbergite 14.21 12.88 -1.33 -0.133 0.22683E+04 78 epidote 24.67 21.63 -3.04 -0.147 0.51885E+04 80 epidote-Fe 29.84 26.46 -3.38 -0.176 0.57733E+04 81 fayalite 14.05 10.23 -3.81 -0.545 0.65108E+04 82 ferrosilite 11.15 7.24 -3.91 -0.391 0.66699E+04 86 gibbsite 4.08 0.43 -3.65 -0.522 0.62392E+04 87 glaucophane 22.97 20.06 -2.91 -0.079 0.49725E+04 88 glaucophane-Fe 17.28 13.09 -4.19 -0.113 0.71533E+04 89 graphite -3.55 -7.65 -4.10 -1.172 0.70064E+04 90 greenalite 16.14 13.85 -2.29 -0.190 0.39022E+04 93 hematite 12.57 10.51 -2.06 -0.250 0.35155E+04 94 heulandite -5.83 -7.83 -2.00 -0.091 0.34160E+04 98 jadeite 4.22 2.61 -1.61 -0.161 0.27485E+04 100 kalsilite 7.58 3.49 -4.09 -0.585 0.69909E+04 101 kaolinite -1.33 -5.13 -3.80 -0.345 0.64809E+04 104 laumontite 2.88 1.14 -1.74 -0.116 0.29761E+04 105 lawsonite 9.62 7.12 -2.50 -0.166 0.42631E+04 106 leucite 4.12 0.50 -3.62 -0.362 0.61788E+04 108 lizardite 23.24 20.83 -2.41 -0.201 0.41210E+04 109 magnesite 0.69 -4.14 -4.83 -1.611 0.82525E+04 110 magnetite 20.09 17.12 -2.97 -0.242 0.50696E+04 111 minnesotaite 10.39 7.88 -2.51 -0.148 0.42906E+04 115 manganosite 14.06 9.20 -4.85 -1.213 0.82868E+04 119 microcline -2.49 -2.49 0.00 0.000 0.47250E+01 123 muscovite 2.58 -1.64 -4.22 -0.248 0.72076E+04 124 paragonite 4.24 0.47 -3.77 -0.222 0.64419E+04 125 nepheline 8.34 5.60 -2.74 -0.392 0.46861E+04 137 phlogopite-Na 29.65 26.43 -3.22 -0.179 0.55005E+04 139 prehnite 19.37 16.38 -2.99 -0.176 0.51127E+04 140 prehnite-Fe 22.50 21.21 -1.29 -0.078 0.22059E+04 145 pyrite -21.25 -22.63 -1.39 -0.327 0.23694E+04 146 pyrrhotite -4.26 -6.65 -2.39 -0.798 0.40879E+04 147 pyrrhotiteFe0.875 -6.02 -7.82 -1.80 -0.662 0.30743E+04 148 pyroxmangite 7.40 6.22 -1.18 -0.237 0.20204E+04 149 pyrophyllite -6.18 -11.11 -4.93 -0.308 0.84203E+04 154 rhodochrosite -0.98 -3.87 -2.90 -0.966 0.49480E+04 155 rhodonite 7.45 6.22 -1.23 -0.246 0.21007E+04 156 sanidine -1.28 -2.49 -1.21 -0.093 0.20725E+04 158 siderite -2.61 -6.47 -3.86 -1.287 0.65906E+04 166 stilbite -7.52 -7.83 -0.31 -0.015 0.52214E+03 168 stilpnomelane-Mg 27.44 24.64 -2.80 -0.084 0.47766E+04 174 talc 16.49 14.85 -1.64 -0.096 0.27996E+04 177 tephroite 18.09 15.42 -2.67 -0.381 0.45514E+04 181 tridymite -2.63 -2.99 -0.36 -0.121 0.61998E+03 182 tremolite 47.87 45.26 -2.61 -0.070 0.44519E+04 183 ferroactinolite 38.45 33.63 -4.82 -0.130 0.82256E+04 184 troilite-low -4.41 -6.65 -2.24 -0.748 0.38307E+04 190 wairakite 3.95 1.14 -2.81 -0.165 0.47980E+04 191 walstromite 11.51 9.26 -2.25 -0.450 0.38435E+04 192 wollastonite 10.46 9.26 -1.20 -0.241 0.20539E+04 193 pseudo-wollastonite 11.00 9.26 -1.74 -0.348 0.29737E+04 195 akaganeite 7.75 5.25 -2.50 -0.541 0.42703E+04 202 chalcedony -2.80 -2.99 -0.19 -0.062 0.31930E+03 204 montmorillonite-Ca -2.29 -6.28 -3.99 -0.247 0.68076E+04 205 montmorillonite-K -2.24 -6.30 -4.06 -0.249 0.69393E+04 206 montmorillonite-Mg -2.48 -6.82 -4.34 -0.269 0.74176E+04 207 montmorillonite-Na -2.04 -5.61 -3.57 -0.219 0.60927E+04 208 nontronite-Ca 3.21 1.70 -1.52 -0.098 0.25907E+04 209 nontronite-H 2.53 -0.32 -2.86 -0.191 0.48771E+04 210 nontronite-K 3.34 1.67 -1.67 -0.107 0.28456E+04 211 nontronite-Mg 3.07 1.15 -1.92 -0.125 0.32847E+04 212 nontronite-Na 3.52 2.37 -1.15 -0.074 0.19649E+04 228 tobermorite 9.82 7.21 -2.61 -0.712 0.44568E+04 234 alabandite -0.98 -4.06 -3.08 -1.028 0.52637E+04 237 boehmite 4.41 0.43 -3.98 -0.664 0.67976E+04 239 ferrous-oxide 9.81 6.61 -3.20 -0.800 0.54649E+04 245 silica-amorphous -2.09 -2.99 -0.90 -0.299 0.15335E+04 247 an20ab80 2.02 1.12 -0.90 -0.069 0.15384E+04 248 an25ab75 2.65 1.49 -1.15 -0.089 0.19700E+04 249 an30ab70 3.28 1.87 -1.41 -0.109 0.24112E+04 250 tr.625ac.25prg.125 45.16 43.16 -2.00 -0.054 0.34147E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 0.0010000 MOLES Current total amount of reactant added: 0.0239900 MOLES New total amount of reactant added: 0.0249900 MOLES Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.5508E-08 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 7 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 0.0249900 Water: Moles liquid = 0.4987E+02 kg liquid = 0.8985E+00 Moles total = 0.4987E+02 kg total = 0.8984E+00 Activity = 1.0000 Stoichiometric ionic strength = .1293756E-01 Osmotic coef. = 0.9376 True ionic strength = .2140431E-01 Chg. balance for total moles = -.5508E-08 Max. difference allowed = 0.2853E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.13898E-09 -9.8571 0.11629E-09 -9.9344 0.83677E+00 -0.0774 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.31611E-03 -3.5002 0.26284E-03 -3.5803 0.83147E+00 -0.0802 4 SO4-- 0.11604E-03 -3.9354 0.59211E-04 -4.2276 0.51025E+00 -0.2922 5 HCO3- 0.90871E-03 -3.0416 0.75673E-03 -3.1211 0.83275E+00 -0.0795 6 HS- 0.58789E-03 -3.2307 0.48889E-03 -3.3108 0.83160E+00 -0.0801 7 Al+++ 0.19029E-28 -28.7206 0.42222E-29 -29.3745 0.22189E+00 -0.6539 8 H4SiO4 0.10246E-02 -2.9894 0.10246E-02 -2.9894 0.10000E+01 0.0000 9 Ca++ 0.45268E-07 -7.3442 0.22919E-07 -7.6398 0.50630E+00 -0.2956 10 Mg++ 0.22692E-10 -10.6441 0.11434E-10 -10.9418 0.50386E+00 -0.2977 11 Fe++ 0.10921E-12 -12.9617 0.55090E-13 -13.2589 0.50444E+00 -0.2972 12 K+ 0.15656E-03 -3.8053 0.13041E-03 -3.8847 0.83296E+00 -0.0794 13 Na+ 0.20015E-01 -1.6986 0.16639E-01 -1.7789 0.83131E+00 -0.0802 14 Mn++ 0.42829E-10 -10.3683 0.21623E-10 -10.6651 0.50488E+00 -0.2968 15 F- 0.11201E-04 -4.9508 0.92927E-05 -5.0319 0.82967E+00 -0.0811 16 HPO4-- 0.45639E-07 -7.3407 0.23291E-07 -7.6328 0.51033E+00 -0.2922 18 HSiO3- 0.98944E-02 -2.0046 0.82269E-02 -2.0848 0.83147E+00 -0.0802 19 Ca(HSiO3)+ 0.51540E-08 -8.2879 0.42940E-08 -8.3671 0.83315E+00 -0.0793 20 Mg(HSiO3)+ 0.31999E-11 -11.4949 0.26660E-11 -11.5741 0.83315E+00 -0.0793 21 NaHSiO3,aq 0.22139E-02 -2.6548 0.22139E-02 -2.6548 0.10000E+01 0.0000 22 AlO+ 0.50978E-16 -16.2926 0.42472E-16 -16.3719 0.83315E+00 -0.0793 24 HAlO2,aq 0.72732E-10 -10.1383 0.72732E-10 -10.1383 0.10000E+01 0.0000 25 AlO2- 0.16682E-05 -5.7778 0.13844E-05 -5.8587 0.82989E+00 -0.0810 26 CH4,aq 0.60934E-08 -8.2151 0.60694E-08 -8.2169 0.99606E+00 -0.0017 27 C2H6,aq 0.32143E-19 -19.4929 0.32017E-19 -19.4946 0.99606E+00 -0.0017 31 CO,aq 0.92915E-15 -15.0319 0.92915E-15 -15.0319 0.10000E+01 0.0000 32 CO2,aq 0.18878E-06 -6.7240 0.18804E-06 -6.7257 0.99606E+00 -0.0017 33 CO3-2 0.11164E-02 -2.9522 0.56837E-03 -3.2454 0.50911E+00 -0.2932 34 CaCO3,aq 0.16334E-06 -6.7869 0.16334E-06 -6.7869 0.10000E+01 0.0000 35 Ca(HCO3)+ 0.53137E-09 -9.2746 0.44271E-09 -9.3539 0.83315E+00 -0.0793 36 CaCl+ 0.11701E-10 -10.9318 0.97488E-11 -11.0111 0.83315E+00 -0.0793 37 CaCl2,aq 0.60876E-15 -15.2156 0.60876E-15 -15.2156 0.10000E+01 0.0000 38 CaF+ 0.37323E-11 -11.4280 0.31095E-11 -11.5073 0.83315E+00 -0.0793 39 CaOH+ 0.16859E-07 -7.7732 0.14046E-07 -7.8525 0.83315E+00 -0.0793 40 CaSO4,aq 0.43093E-09 -9.3656 0.43093E-09 -9.3656 0.10000E+01 0.0000 41 HCl,aq 0.56012E-14 -14.2517 0.56012E-14 -14.2517 0.10000E+01 0.0000 45 HF,aq 0.73980E-11 -11.1309 0.73980E-11 -11.1309 0.10000E+01 0.0000 46 HF2- 0.27916E-16 -16.5542 0.23211E-16 -16.6343 0.83147E+00 -0.0802 48 FeCl+ 0.27509E-16 -16.5605 0.22919E-16 -16.6398 0.83315E+00 -0.0793 51 FeF+ 0.31400E-16 -16.5031 0.26161E-16 -16.5823 0.83315E+00 -0.0793 53 FeO,aq 0.15832E-09 -9.8005 0.15832E-09 -9.8005 0.10000E+01 0.0000 54 FeOH+ 0.18508E-10 -10.7326 0.15420E-10 -10.8119 0.83315E+00 -0.0793 55 HFeO2- 0.17131E-07 -7.7662 0.14244E-07 -7.8464 0.83147E+00 -0.0802 56 FeO+ 0.99538E-16 -16.0020 0.82930E-16 -16.0813 0.83315E+00 -0.0793 58 FeO2- 0.15091E-08 -8.8213 0.12547E-08 -8.9014 0.83147E+00 -0.0802 59 HFeO2,aq 0.18558E-10 -10.7315 0.18558E-10 -10.7315 0.10000E+01 0.0000 60 H2,aq 0.19747E-06 -6.7045 0.19670E-06 -6.7062 0.99606E+00 -0.0017 61 KCl,aq 0.62124E-09 -9.2067 0.62124E-09 -9.2067 0.10000E+01 0.0000 62 KHSO4,aq 0.25389E-17 -17.5954 0.25389E-17 -17.5954 0.10000E+01 0.0000 63 KOH,aq 0.47889E-06 -6.3198 0.47889E-06 -6.3198 0.10000E+01 0.0000 64 KSO4- 0.14411E-06 -6.8413 0.11982E-06 -6.9215 0.83147E+00 -0.0802 65 MgCO3,aq 0.20425E-10 -10.6898 0.20425E-10 -10.6898 0.10000E+01 0.0000 66 Mg(HCO3)+ 0.27087E-12 -12.5672 0.22568E-12 -12.6465 0.83315E+00 -0.0793 67 MgCl+ 0.52907E-14 -14.2765 0.44079E-14 -14.3558 0.83315E+00 -0.0793 68 MgF+ 0.68972E-14 -14.1613 0.57464E-14 -14.2406 0.83315E+00 -0.0793 69 MgOH+ 0.46539E-10 -10.3322 0.38774E-10 -10.4115 0.83315E+00 -0.0793 71 MnF+ 0.40624E-14 -14.3912 0.33846E-14 -14.4705 0.83315E+00 -0.0793 72 MnO,aq 0.16558E-08 -8.7810 0.16558E-08 -8.7810 0.10000E+01 0.0000 73 MnOH+ 0.67486E-09 -9.1708 0.56226E-09 -9.2501 0.83315E+00 -0.0793 74 MnO2-2 0.79810E-11 -11.0979 0.40632E-11 -11.3911 0.50911E+00 -0.2932 75 HMnO2- 0.12451E-09 -9.9048 0.10352E-09 -9.9850 0.83147E+00 -0.0802 78 MnCl+ 0.42008E-13 -13.3767 0.34999E-13 -13.4559 0.83315E+00 -0.0793 79 MnSO4,aq 0.36962E-12 -12.4322 0.36962E-12 -12.4322 0.10000E+01 0.0000 80 NaCl,aq 0.14493E-05 -5.8388 0.14493E-05 -5.8388 0.10000E+01 0.0000 81 NaF,aq 0.36199E-07 -7.4413 0.36199E-07 -7.4413 0.10000E+01 0.0000 82 NaOH,aq 0.61472E-04 -4.2113 0.61472E-04 -4.2113 0.10000E+01 0.0000 84 OH- 0.59866E-02 -2.2228 0.49682E-02 -2.3038 0.82989E+00 -0.0810 89 HPO3-2 0.28043E-16 -16.5522 0.14277E-16 -16.8454 0.50911E+00 -0.2932 92 H3PO4,aq 0.22030E-17 -17.6570 0.22030E-17 -17.6570 0.10000E+01 0.0000 93 H2PO4- 0.60034E-10 -10.2216 0.49966E-10 -10.3013 0.83230E+00 -0.0797 94 PO4-3 0.69932E-09 -9.1553 0.16340E-09 -9.7867 0.23366E+00 -0.6314 98 HP2O7-3 0.15132E-17 -17.8201 0.33612E-18 -18.4735 0.22213E+00 -0.6534 99 P2O7-4 0.96064E-17 -17.0174 0.69047E-18 -18.1609 0.71876E-01 -1.1434 100 H2S,aq 0.17641E-06 -6.7535 0.17572E-06 -6.7552 0.99606E+00 -0.0017 101 S2-2 0.52887E-10 -10.2767 0.26925E-10 -10.5698 0.50911E+00 -0.2932 102 S3-2 0.63653E-16 -16.1962 0.32406E-16 -16.4894 0.50911E+00 -0.2932 107 SO3-2 0.29281E-11 -11.5334 0.15135E-11 -11.8200 0.51687E+00 -0.2866 108 HSO3- 0.13254E-13 -13.8777 0.11020E-13 -13.9578 0.83147E+00 -0.0802 109 HSO4- 0.79568E-11 -11.0993 0.66360E-11 -11.1781 0.83400E+00 -0.0788 111 S2O3-2 0.24006E-12 -12.6197 0.12222E-12 -12.9129 0.50911E+00 -0.2932 Charge balance for all species = -.6130E-08 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.1389789E-09 -.1927992E-01 -.1939778E+02 0.0000 2 H2O 0.1000000E+01 0.5550219E+02 0.9980763E+06 0.0000 3 Cl- 0.3161146E-03 0.3175646E-03 0.1123821E+02 6.3541 4 SO4-- 0.1160427E-03 0.1161320E-03 0.1113560E+02 15.6413 5 HCO3- 0.9087142E-03 0.2025475E-02 0.1233648E+03 6.8134 6 HS- 0.5878945E-03 0.5881263E-03 0.1941526E+02 6.6237 7 Al+++ 0.1902861E-28 0.1668263E-05 0.4493066E-01 0.4289 8 H4SiO4 0.1024625E-02 0.1313297E-01 0.1259992E+04 -2.9894 9 Ca++ 0.4526769E-07 0.2315952E-06 0.9265049E-02 12.2291 10 Mg++ 0.2269235E-10 0.9313880E-10 0.2260286E-05 8.9271 11 Fe++ 0.1092108E-12 0.1883580E-07 0.1050016E-02 6.6100 12 K+ 0.1565618E-03 0.1571854E-03 0.6135124E+01 6.0498 13 Na+ 0.2001509E-01 0.2229198E-01 0.5115592E+03 8.1556 14 Mn++ 0.4282889E-10 0.2506390E-08 0.1374464E-03 9.2038 15 F- 0.1120055E-04 0.1123677E-04 0.2130891E+00 4.9026 16 HPO4-- 0.4563926E-07 0.4639861E-07 0.4445221E-02 12.2361 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.1733574E-01 -.1732261E-01 -.1313245E-04 0.0000000E+00 2 H2O 0.4986687E+02 0.4986757E+02 -.7000598E-03 0.0000000E+00 3 Cl- 0.2853252E-03 0.2853252E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.1043422E-03 0.1043422E-03 0.0000000E+00 0.0000000E+00 5 HCO3- 0.1819847E-02 0.1819847E-02 0.0000000E+00 0.0000000E+00 6 HS- 0.5284193E-03 0.5284193E-03 0.0000000E+00 0.0000000E+00 7 Al+++ 0.4775352E-05 0.1498900E-05 0.3276452E-05 0.0000000E+00 8 H4SiO4 0.1215302E-01 0.1179970E-01 0.3533228E-03 0.0000000E+00 9 Ca++ 0.2080835E-06 0.2080835E-06 0.0000000E+00 0.0000000E+00 10 Mg++ 0.8368328E-10 0.8368328E-10 0.0000000E+00 0.0000000E+00 11 Fe++ 0.3259227E-07 0.1692357E-07 0.1566870E-07 0.0000000E+00 12 K+ 0.1412294E-03 0.1412278E-03 0.1566870E-08 0.0000000E+00 13 Na+ 0.2003215E-01 0.2002888E-01 0.3270185E-05 0.0000000E+00 14 Mn++ 0.2251939E-08 0.2251939E-08 0.0000000E+00 0.0000000E+00 15 F- 0.1009600E-04 0.1009600E-04 0.0000000E+00 0.0000000E+00 16 HPO4-- 0.4168819E-07 0.4168819E-07 0.0000000E+00 0.0000000E+00 Chg. balance for solid moles: -.8470E-21 Mass of aqueous solution: 0.900111E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 0.0249900 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 0.3270E-05 -5.485 0.8575E-03 -3.067 3.989 0.3292E-03 quartz 0.3435E-03 -3.464 0.2064E-01 -1.685 96.00 0.7793E-02 stilpnomelane-Fe 0.3134E-08 -8.504 0.3378E-05 -5.471 0.1571E-01 0.1167E-05 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 quartz 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 0.021498 g Volume = 0.008124 cm3 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.0249900 moles log = -1.6022 Original solution: 1000.0103000 g Original solution / Rock added: 40016.42 (Water/Rock Ratio), log = 4.6022 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0206 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9997E+00 0.9859 0.1006E+01 0.1020E+01 CO2,gas 0.1957E-04 1.0071 0.2012E-04 0.1998E-04 CH4,gas 0.8645E-05 1.0125 0.8934E-05 0.8823E-05 H2,gas 0.2529E-03 1.0005 0.2582E-03 0.2581E-03 H2S,gas 0.4752E-05 0.9960 0.4830E-05 0.4850E-05 S2,gas 0.1287E-22 1.0000 0.1313E-22 0.1313E-22 CO,gas 0.1357E-11 1.0000 0.1385E-11 0.1385E-11 SO3,gas 0.2967E-39 1.0000 0.3028E-39 0.3028E-39 SO2,gas 0.2981E-20 1.0000 0.3042E-20 0.3042E-20 HF,gas 0.1780E-13 1.0000 0.1816E-13 0.1816E-13 HCl,gas 0.9684E-17 1.0000 0.9883E-17 0.9883E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 17 albite -0.38 -0.38 0.00 0.000 -0.13080E-10 150 quartz -2.99 -2.99 0.00 0.000 0.00000E+00 167 stilpnomelane-Fe 13.02 13.02 0.00 0.000 -0.27298E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -13.06 -6.40 -2.132 0.10920E+05 -4.696 3 CH4,gas 4.54 -2.20 -6.75 -1.687 0.11522E+05 -5.049 4 H2,gas 8.00 2.71 -5.29 -3.021 0.90273E+04 -3.588 5 H2S,gas -6.23 -13.25 -7.01 -3.507 0.11978E+05 -5.316 6 S2,gas -7.34 -31.92 -24.58 -3.782 0.41971E+05 -22.882 7 CO,gas 3.21 -10.34 -13.56 -4.172 0.23149E+05 -11.859 8 SO3,gas 17.12 -24.10 -41.22 -10.304 0.70378E+05 -39.519 9 SO2,gas 0.83 -21.38 -22.22 -5.924 0.37933E+05 -20.517 10 HF,gas 0.47 -14.97 -15.44 -7.720 0.26363E+05 -13.741 11 HCl,gas 5.19 -13.51 -18.70 -9.352 0.31937E+05 -17.005 12 acmite 7.71 7.43 -0.28 -0.029 0.47717E+03 16 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 20 spessartine 24.46 19.50 -4.96 -0.248 0.84630E+04 21 analcite 3.32 2.61 -0.72 -0.080 0.12231E+04 23 andradite 39.01 38.23 -0.78 -0.041 0.13364E+04 24 grossular 32.73 28.58 -4.15 -0.208 0.70941E+04 27 annite 20.12 17.34 -2.78 -0.155 0.47522E+04 28 phlogopite 27.06 24.29 -2.77 -0.154 0.47349E+04 33 apatite-OH -18.15 -21.36 -3.21 -0.247 0.54745E+04 34 apatite-F -34.30 -36.33 -2.03 -0.169 0.34576E+04 38 aragonite 0.97 -0.83 -1.79 -0.598 0.30614E+04 39 brucite 12.57 8.93 -3.64 -0.728 0.62177E+04 40 calcite 0.81 -0.83 -1.64 -0.546 0.27972E+04 41 carnegieite-low 9.02 5.60 -3.43 -0.490 0.58537E+04 42 carnegieite-high 10.09 5.60 -4.50 -0.643 0.76807E+04 43 carpholite-Mg 8.58 3.81 -4.78 -0.318 0.81551E+04 45 celadonite 5.34 3.45 -1.89 -0.111 0.32333E+04 46 celadonite-Fe 3.88 1.13 -2.75 -0.162 0.46882E+04 47 chrysotile 23.89 20.80 -3.09 -0.258 0.52761E+04 49 clinochlore 39.07 36.52 -2.54 -0.080 0.43450E+04 50 daphnite 28.97 24.94 -4.03 -0.126 0.68742E+04 54 chloritoid-Fe 9.17 4.48 -4.70 -0.313 0.80172E+04 55 chloritoid-Mn 11.40 7.07 -4.33 -0.289 0.73916E+04 57 coesite -2.38 -2.99 -0.61 -0.204 0.10473E+04 64 cristobalite -2.56 -2.99 -0.43 -0.143 0.73267E+03 66 cymrite-K 1.69 -2.49 -4.18 -0.348 0.71288E+04 68 diaspore 2.87 0.43 -2.44 -0.407 0.41745E+04 69 diamond -3.10 -7.63 -4.53 -1.294 0.77306E+04 70 diopside 16.18 15.18 -1.00 -0.100 0.17144E+04 71 hedenbergite 14.21 12.86 -1.35 -0.135 0.23018E+04 78 epidote 24.67 21.60 -3.07 -0.149 0.52398E+04 80 epidote-Fe 29.84 26.43 -3.41 -0.177 0.58309E+04 81 fayalite 14.05 10.23 -3.82 -0.545 0.65144E+04 82 ferrosilite 11.15 7.24 -3.91 -0.391 0.66735E+04 86 gibbsite 4.08 0.43 -3.65 -0.521 0.62330E+04 87 glaucophane 22.97 20.03 -2.94 -0.079 0.50203E+04 88 glaucophane-Fe 17.28 13.08 -4.19 -0.113 0.71586E+04 89 graphite -3.55 -7.63 -4.08 -1.167 0.69728E+04 90 greenalite 16.14 13.85 -2.29 -0.191 0.39075E+04 93 hematite 12.57 10.51 -2.06 -0.250 0.35158E+04 94 heulandite -5.83 -7.84 -2.01 -0.091 0.34354E+04 98 jadeite 4.22 2.61 -1.61 -0.161 0.27485E+04 100 kalsilite 7.58 3.49 -4.09 -0.585 0.69916E+04 101 kaolinite -1.33 -5.12 -3.79 -0.344 0.64685E+04 104 laumontite 2.88 1.13 -1.75 -0.117 0.29955E+04 105 lawsonite 9.62 7.11 -2.51 -0.167 0.42825E+04 106 leucite 4.12 0.50 -3.62 -0.362 0.61795E+04 108 lizardite 23.24 20.80 -2.44 -0.203 0.41688E+04 109 magnesite 0.69 -4.13 -4.82 -1.606 0.82284E+04 110 magnetite 20.09 17.12 -2.97 -0.242 0.50717E+04 111 minnesotaite 10.39 7.87 -2.52 -0.148 0.42959E+04 115 manganosite 14.06 9.20 -4.85 -1.214 0.82886E+04 119 microcline -2.49 -2.49 0.00 0.000 0.54348E+01 123 muscovite 2.58 -1.63 -4.21 -0.248 0.71959E+04 124 paragonite 4.24 0.47 -3.77 -0.222 0.64296E+04 125 nepheline 8.34 5.60 -2.74 -0.392 0.46861E+04 137 phlogopite-Na 29.65 26.40 -3.25 -0.181 0.55483E+04 139 prehnite 19.37 16.35 -3.02 -0.178 0.51639E+04 140 prehnite-Fe 22.50 21.17 -1.33 -0.080 0.22634E+04 145 pyrite -21.25 -22.59 -1.35 -0.317 0.22989E+04 146 pyrrhotite -4.26 -6.64 -2.37 -0.792 0.40552E+04 147 pyrrhotiteFe0.875 -6.02 -7.80 -1.78 -0.655 0.30409E+04 148 pyroxmangite 7.40 6.21 -1.18 -0.237 0.20222E+04 149 pyrophyllite -6.18 -11.10 -4.92 -0.308 0.84079E+04 154 rhodochrosite -0.98 -3.85 -2.88 -0.958 0.49096E+04 155 rhodonite 7.45 6.21 -1.23 -0.246 0.21024E+04 156 sanidine -1.28 -2.49 -1.21 -0.093 0.20732E+04 158 siderite -2.61 -6.45 -3.84 -1.279 0.65522E+04 166 stilbite -7.52 -7.84 -0.32 -0.015 0.54154E+03 168 stilpnomelane-Mg 27.44 24.60 -2.84 -0.085 0.48473E+04 174 talc 16.49 14.82 -1.67 -0.098 0.28473E+04 177 tephroite 18.09 15.42 -2.67 -0.381 0.45548E+04 181 tridymite -2.63 -2.99 -0.36 -0.121 0.61998E+03 182 tremolite 47.87 45.18 -2.69 -0.073 0.45951E+04 183 ferroactinolite 38.45 33.59 -4.86 -0.131 0.82981E+04 184 troilite-low -4.41 -6.64 -2.22 -0.741 0.37980E+04 190 wairakite 3.95 1.13 -2.82 -0.166 0.48174E+04 191 walstromite 11.51 9.24 -2.27 -0.454 0.38752E+04 192 wollastonite 10.46 9.24 -1.22 -0.244 0.20857E+04 193 pseudo-wollastonite 11.00 9.24 -1.76 -0.352 0.30055E+04 195 akaganeite 7.75 5.25 -2.50 -0.541 0.42704E+04 202 chalcedony -2.80 -2.99 -0.19 -0.062 0.31930E+03 204 montmorillonite-Ca -2.29 -6.28 -3.99 -0.247 0.68078E+04 205 montmorillonite-K -2.24 -6.30 -4.06 -0.249 0.69365E+04 206 montmorillonite-Mg -2.48 -6.82 -4.34 -0.269 0.74151E+04 207 montmorillonite-Na -2.04 -5.60 -3.57 -0.218 0.60896E+04 208 nontronite-Ca 3.21 1.70 -1.52 -0.099 0.25942E+04 209 nontronite-H 2.53 -0.32 -2.86 -0.191 0.48753E+04 210 nontronite-K 3.34 1.67 -1.67 -0.107 0.28461E+04 211 nontronite-Mg 3.07 1.15 -1.92 -0.125 0.32856E+04 212 nontronite-Na 3.52 2.37 -1.15 -0.074 0.19652E+04 228 tobermorite 9.82 7.20 -2.63 -0.716 0.44832E+04 234 alabandite -0.98 -4.04 -3.06 -1.021 0.52309E+04 237 boehmite 4.41 0.43 -3.98 -0.663 0.67914E+04 239 ferrous-oxide 9.81 6.61 -3.20 -0.800 0.54667E+04 245 silica-amorphous -2.09 -2.99 -0.90 -0.299 0.15335E+04 247 an20ab80 2.02 1.11 -0.90 -0.069 0.15423E+04 248 an25ab75 2.65 1.49 -1.16 -0.089 0.19749E+04 249 an30ab70 3.28 1.86 -1.42 -0.109 0.24170E+04 250 tr.625ac.25prg.125 45.16 43.09 -2.07 -0.056 0.35367E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 0.0010000 MOLES Current total amount of reactant added: 0.0249900 MOLES New total amount of reactant added: 0.0259900 MOLES Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.5508E-08 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 7 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 0.0259900 Water: Moles liquid = 0.4987E+02 kg liquid = 0.8985E+00 Moles total = 0.4987E+02 kg total = 0.8984E+00 Activity = 1.0000 Stoichiometric ionic strength = .1300254E-01 Osmotic coef. = 0.9372 True ionic strength = .2146806E-01 Chg. balance for total moles = -.5508E-08 Max. difference allowed = 0.2912E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.14028E-09 -9.8530 0.11736E-09 -9.9305 0.83661E+00 -0.0775 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.32264E-03 -3.4913 0.26822E-03 -3.5715 0.83130E+00 -0.0802 4 SO4-- 0.12135E-03 -3.9160 0.61869E-04 -4.2085 0.50985E+00 -0.2926 5 HCO3- 0.94924E-03 -3.0226 0.79033E-03 -3.1022 0.83259E+00 -0.0796 6 HS- 0.60961E-03 -3.2150 0.50685E-03 -3.2951 0.83143E+00 -0.0802 7 Al+++ 0.19757E-28 -28.7043 0.43760E-29 -29.3589 0.22148E+00 -0.6547 8 H4SiO4 0.10246E-02 -2.9894 0.10246E-02 -2.9894 0.10000E+01 0.0000 9 Ca++ 0.44236E-07 -7.3542 0.22379E-07 -7.6502 0.50589E+00 -0.2959 10 Mg++ 0.22637E-10 -10.6452 0.11397E-10 -10.9432 0.50345E+00 -0.2980 11 Fe++ 0.11104E-12 -12.9545 0.55969E-13 -13.2521 0.50403E+00 -0.2975 12 K+ 0.15656E-03 -3.8053 0.13038E-03 -3.8848 0.83279E+00 -0.0795 13 Na+ 0.20034E-01 -1.6982 0.16651E-01 -1.7786 0.83114E+00 -0.0803 14 Mn++ 0.43549E-10 -10.3610 0.21969E-10 -10.6582 0.50447E+00 -0.2972 15 F- 0.11644E-04 -4.9339 0.96587E-05 -5.0151 0.82950E+00 -0.0812 16 HPO4-- 0.45644E-07 -7.3406 0.23275E-07 -7.6331 0.50992E+00 -0.2925 18 HSiO3- 0.98065E-02 -2.0085 0.81522E-02 -2.0887 0.83130E+00 -0.0802 19 Ca(HSiO3)+ 0.49878E-08 -8.3021 0.41548E-08 -8.3815 0.83298E+00 -0.0794 20 Mg(HSiO3)+ 0.31612E-11 -11.5002 0.26332E-11 -11.5795 0.83298E+00 -0.0794 21 NaHSiO3,aq 0.21954E-02 -2.6585 0.21954E-02 -2.6585 0.10000E+01 0.0000 22 AlO+ 0.51889E-16 -16.2849 0.43223E-16 -16.3643 0.83298E+00 -0.0794 24 HAlO2,aq 0.73345E-10 -10.1346 0.73345E-10 -10.1346 0.10000E+01 0.0000 25 AlO2- 0.16673E-05 -5.7780 0.13834E-05 -5.8590 0.82972E+00 -0.0811 26 CH4,aq 0.63142E-08 -8.1997 0.62892E-08 -8.2014 0.99605E+00 -0.0017 27 C2H6,aq 0.34661E-19 -19.4602 0.34524E-19 -19.4619 0.99605E+00 -0.0017 31 CO,aq 0.97514E-15 -15.0109 0.97514E-15 -15.0109 0.10000E+01 0.0000 32 CO2,aq 0.19898E-06 -6.7012 0.19819E-06 -6.7029 0.99605E+00 -0.0017 33 CO3-2 0.11563E-02 -2.9369 0.58821E-03 -3.2305 0.50870E+00 -0.2935 34 CaCO3,aq 0.16505E-06 -6.7824 0.16505E-06 -6.7824 0.10000E+01 0.0000 35 Ca(HCO3)+ 0.54199E-09 -9.2660 0.45147E-09 -9.3454 0.83298E+00 -0.0794 36 CaCl+ 0.11661E-10 -10.9333 0.97136E-11 -11.0126 0.83298E+00 -0.0794 37 CaCl2,aq 0.61897E-15 -15.2083 0.61897E-15 -15.2083 0.10000E+01 0.0000 38 CaF+ 0.37886E-11 -11.4215 0.31558E-11 -11.5009 0.83298E+00 -0.0794 39 CaOH+ 0.16315E-07 -7.7874 0.13590E-07 -7.8668 0.83298E+00 -0.0794 40 CaSO4,aq 0.43966E-09 -9.3569 0.43966E-09 -9.3569 0.10000E+01 0.0000 41 HCl,aq 0.57681E-14 -14.2390 0.57681E-14 -14.2390 0.10000E+01 0.0000 45 HF,aq 0.77599E-11 -11.1101 0.77599E-11 -11.1101 0.10000E+01 0.0000 46 HF2- 0.30440E-16 -16.5166 0.25305E-16 -16.5968 0.83130E+00 -0.0802 48 FeCl+ 0.28525E-16 -16.5448 0.23761E-16 -16.6241 0.83298E+00 -0.0794 51 FeF+ 0.33164E-16 -16.4793 0.27625E-16 -16.5587 0.83298E+00 -0.0794 53 FeO,aq 0.15793E-09 -9.8015 0.15793E-09 -9.8015 0.10000E+01 0.0000 54 FeOH+ 0.18636E-10 -10.7296 0.15524E-10 -10.8090 0.83298E+00 -0.0794 55 HFeO2- 0.16938E-07 -7.7711 0.14081E-07 -7.8514 0.83130E+00 -0.0802 56 FeO+ 0.10044E-15 -15.9981 0.83665E-16 -16.0775 0.83298E+00 -0.0794 58 FeO2- 0.14952E-08 -8.8253 0.12430E-08 -8.9055 0.83130E+00 -0.0802 59 HFeO2,aq 0.18553E-10 -10.7316 0.18553E-10 -10.7316 0.10000E+01 0.0000 60 H2,aq 0.19664E-06 -6.7063 0.19586E-06 -6.7080 0.99605E+00 -0.0017 61 KCl,aq 0.63380E-09 -9.1980 0.63380E-09 -9.1980 0.10000E+01 0.0000 62 KHSO4,aq 0.26766E-17 -17.5724 0.26766E-17 -17.5724 0.10000E+01 0.0000 63 KOH,aq 0.47444E-06 -6.3238 0.47444E-06 -6.3238 0.10000E+01 0.0000 64 KSO4- 0.15057E-06 -6.8223 0.12517E-06 -6.9025 0.83130E+00 -0.0802 65 MgCO3,aq 0.21069E-10 -10.6764 0.21069E-10 -10.6764 0.10000E+01 0.0000 66 Mg(HCO3)+ 0.28203E-12 -12.5497 0.23493E-12 -12.6291 0.83298E+00 -0.0794 67 MgCl+ 0.53824E-14 -14.2690 0.44834E-14 -14.3484 0.83298E+00 -0.0794 68 MgF+ 0.71469E-14 -14.1459 0.59533E-14 -14.2252 0.83298E+00 -0.0794 69 MgOH+ 0.45975E-10 -10.3375 0.38297E-10 -10.4168 0.83298E+00 -0.0794 71 MnF+ 0.42908E-14 -14.3675 0.35741E-14 -14.4468 0.83298E+00 -0.0794 72 MnO,aq 0.16519E-08 -8.7820 0.16519E-08 -8.7820 0.10000E+01 0.0000 73 MnOH+ 0.67956E-09 -9.1678 0.56606E-09 -9.2471 0.83298E+00 -0.0794 74 MnO2-2 0.78243E-11 -11.1066 0.39802E-11 -11.4001 0.50870E+00 -0.2935 75 HMnO2- 0.12311E-09 -9.9097 0.10234E-09 -9.9900 0.83130E+00 -0.0802 78 MnCl+ 0.43561E-13 -13.3609 0.36286E-13 -13.4403 0.83298E+00 -0.0794 79 MnSO4,aq 0.39240E-12 -12.4063 0.39240E-12 -12.4063 0.10000E+01 0.0000 80 NaCl,aq 0.14800E-05 -5.8297 0.14800E-05 -5.8297 0.10000E+01 0.0000 81 NaF,aq 0.37652E-07 -7.4242 0.37652E-07 -7.4242 0.10000E+01 0.0000 82 NaOH,aq 0.60958E-04 -4.2150 0.60958E-04 -4.2150 0.10000E+01 0.0000 84 OH- 0.59335E-02 -2.2267 0.49231E-02 -2.3078 0.82972E+00 -0.0811 89 HPO3-2 0.27927E-16 -16.5540 0.14206E-16 -16.8475 0.50870E+00 -0.2935 92 H3PO4,aq 0.22420E-17 -17.6494 0.22420E-17 -17.6494 0.10000E+01 0.0000 93 H2PO4- 0.60554E-10 -10.2179 0.50389E-10 -10.2977 0.83213E+00 -0.0798 94 PO4-3 0.69366E-09 -9.1589 0.16181E-09 -9.7910 0.23327E+00 -0.6321 98 HP2O7-3 0.15277E-17 -17.8160 0.33873E-18 -18.4702 0.22172E+00 -0.6542 99 P2O7-4 0.96233E-17 -17.0167 0.68951E-18 -18.1615 0.71650E-01 -1.1448 100 H2S,aq 0.18457E-06 -6.7338 0.18384E-06 -6.7356 0.99605E+00 -0.0017 101 S2-2 0.57130E-10 -10.2431 0.29062E-10 -10.5367 0.50870E+00 -0.2935 102 S3-2 0.72244E-16 -16.1412 0.36751E-16 -16.4347 0.50870E+00 -0.2935 107 SO3-2 0.30490E-11 -11.5158 0.15747E-11 -11.8028 0.51648E+00 -0.2870 108 HSO3- 0.13919E-13 -13.8564 0.11571E-13 -13.9366 0.83130E+00 -0.0802 109 HSO4- 0.83918E-11 -11.0761 0.69975E-11 -11.1551 0.83384E+00 -0.0789 111 S2O3-2 0.26264E-12 -12.5806 0.13361E-12 -12.8742 0.50870E+00 -0.2935 Charge balance for all species = -.6130E-08 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.1402789E-09 -.1915971E-01 -.1927688E+02 0.0000 2 H2O 0.1000000E+01 0.5550225E+02 0.9980800E+06 0.0000 3 Cl- 0.3226443E-03 0.3241250E-03 0.1147041E+02 6.3590 4 SO4-- 0.1213484E-03 0.1214442E-03 0.1164501E+02 15.6524 5 HCO3- 0.9492414E-03 0.2105903E-02 0.1282638E+03 6.8283 6 HS- 0.6096058E-03 0.6098457E-03 0.2013232E+02 6.6354 7 Al+++ 0.1975742E-28 0.1667396E-05 0.4490744E-01 0.4325 8 H4SiO4 0.1024625E-02 0.1302656E-01 0.1249787E+04 -2.9894 9 Ca++ 0.4423649E-07 0.2315908E-06 0.9264896E-02 12.2108 10 Mg++ 0.2263714E-10 0.9313701E-10 0.2260249E-05 8.9177 11 Fe++ 0.1110435E-12 0.1862840E-07 0.1038457E-02 6.6089 12 K+ 0.1565567E-03 0.1571824E-03 0.6135022E+01 6.0457 13 Na+ 0.2003366E-01 0.2229155E-01 0.5115507E+03 8.1519 14 Mn++ 0.4354939E-10 0.2506341E-08 0.1374442E-03 9.2028 15 F- 0.1164407E-04 0.1168174E-04 0.2215280E+00 4.9154 16 HPO4-- 0.4564351E-07 0.4639772E-07 0.4445147E-02 12.2278 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.1722807E-01 -.1721493E-01 -.1313576E-04 0.0000000E+00 2 H2O 0.4986769E+02 0.4986858E+02 -.8908197E-03 0.0000000E+00 3 Cl- 0.2912252E-03 0.2912252E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.1091172E-03 0.1091172E-03 0.0000000E+00 0.0000000E+00 5 HCO3- 0.1892147E-02 0.1892147E-02 0.0000000E+00 0.0000000E+00 6 HS- 0.5479443E-03 0.5479443E-03 0.0000000E+00 0.0000000E+00 7 Al+++ 0.4775352E-05 0.1498150E-05 0.3277202E-05 0.0000000E+00 8 H4SiO4 0.1215302E-01 0.1170432E-01 0.4487037E-03 0.0000000E+00 9 Ca++ 0.2080835E-06 0.2080835E-06 0.0000000E+00 0.0000000E+00 10 Mg++ 0.8368328E-10 0.8368328E-10 0.0000000E+00 0.0000000E+00 11 Fe++ 0.3259227E-07 0.1673755E-07 0.1585472E-07 0.0000000E+00 12 K+ 0.1412294E-03 0.1412278E-03 0.1585472E-08 0.0000000E+00 13 Na+ 0.2003215E-01 0.2002888E-01 0.3270860E-05 0.0000000E+00 14 Mn++ 0.2251939E-08 0.2251939E-08 0.0000000E+00 0.0000000E+00 15 F- 0.1049600E-04 0.1049600E-04 0.0000000E+00 0.0000000E+00 16 HPO4-- 0.4168819E-07 0.4168819E-07 0.0000000E+00 0.0000000E+00 Chg. balance for solid moles: 0.4235E-21 Mass of aqueous solution: 0.900126E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 0.0259900 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 0.3271E-05 -5.485 0.8577E-03 -3.067 3.150 0.3292E-03 quartz 0.4389E-03 -3.358 0.2637E-01 -1.579 96.84 0.9957E-02 stilpnomelane-Fe 0.3171E-08 -8.499 0.3418E-05 -5.466 0.1255E-01 0.1181E-05 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 quartz 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 0.027228 g Volume = 0.010288 cm3 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.0259900 moles log = -1.5852 Original solution: 1000.0103000 g Original solution / Rock added: 38476.73 (Water/Rock Ratio), log = 4.5852 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0206 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9997E+00 0.9859 0.1006E+01 0.1020E+01 CO2,gas 0.2063E-04 1.0071 0.2120E-04 0.2105E-04 CH4,gas 0.8958E-05 1.0125 0.9257E-05 0.9143E-05 H2,gas 0.2518E-03 1.0005 0.2571E-03 0.2570E-03 H2S,gas 0.4971E-05 0.9960 0.5054E-05 0.5074E-05 S2,gas 0.1421E-22 1.0000 0.1450E-22 0.1450E-22 CO,gas 0.1424E-11 1.0000 0.1453E-11 0.1453E-11 SO3,gas 0.3157E-39 1.0000 0.3222E-39 0.3222E-39 SO2,gas 0.3158E-20 1.0000 0.3223E-20 0.3223E-20 HF,gas 0.1867E-13 1.0000 0.1905E-13 0.1905E-13 HCl,gas 0.9973E-17 1.0000 0.1018E-16 0.1018E-16 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 17 albite -0.38 -0.38 0.00 0.000 0.11184E-10 150 quartz -2.99 -2.99 0.00 0.000 0.00000E+00 167 stilpnomelane-Fe 13.02 13.02 0.00 0.000 -0.27298E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -13.03 -6.37 -2.124 0.10881E+05 -4.674 3 CH4,gas 4.54 -2.19 -6.73 -1.683 0.11496E+05 -5.034 4 H2,gas 8.00 2.71 -5.29 -3.022 0.90305E+04 -3.590 5 H2S,gas -6.23 -13.23 -7.00 -3.498 0.11944E+05 -5.296 6 S2,gas -7.34 -31.87 -24.54 -3.775 0.41897E+05 -22.839 7 CO,gas 3.21 -10.32 -13.54 -4.165 0.23113E+05 -11.838 8 SO3,gas 17.12 -24.07 -41.19 -10.298 0.70332E+05 -39.492 9 SO2,gas 0.83 -21.36 -22.19 -5.918 0.37890E+05 -20.492 10 HF,gas 0.47 -14.95 -15.42 -7.710 0.26328E+05 -13.720 11 HCl,gas 5.19 -13.50 -18.69 -9.346 0.31915E+05 -16.992 12 acmite 7.71 7.43 -0.28 -0.029 0.48362E+03 16 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 20 spessartine 24.46 19.51 -4.95 -0.248 0.84558E+04 21 analcite 3.32 2.61 -0.72 -0.080 0.12231E+04 23 andradite 39.01 38.17 -0.84 -0.044 0.14305E+04 24 grossular 32.73 28.53 -4.20 -0.210 0.71753E+04 27 annite 20.12 17.34 -2.79 -0.155 0.47583E+04 28 phlogopite 27.06 24.26 -2.80 -0.156 0.47834E+04 33 apatite-OH -18.15 -21.43 -3.27 -0.252 0.55915E+04 34 apatite-F -34.30 -36.37 -2.07 -0.173 0.35393E+04 38 aragonite 0.97 -0.82 -1.79 -0.596 0.30536E+04 39 brucite 12.57 8.92 -3.65 -0.730 0.62337E+04 40 calcite 0.81 -0.82 -1.63 -0.545 0.27894E+04 41 carnegieite-low 9.02 5.60 -3.43 -0.490 0.58537E+04 42 carnegieite-high 10.09 5.60 -4.50 -0.643 0.76807E+04 43 carpholite-Mg 8.58 3.80 -4.78 -0.319 0.81586E+04 45 celadonite 5.34 3.44 -1.90 -0.112 0.32500E+04 46 celadonite-Fe 3.88 1.13 -2.75 -0.162 0.46907E+04 47 chrysotile 23.89 20.77 -3.12 -0.260 0.53240E+04 49 clinochlore 39.07 36.49 -2.58 -0.081 0.44123E+04 50 daphnite 28.97 24.94 -4.02 -0.126 0.68708E+04 54 chloritoid-Fe 9.17 4.48 -4.69 -0.313 0.80065E+04 55 chloritoid-Mn 11.40 7.08 -4.32 -0.288 0.73809E+04 57 coesite -2.38 -2.99 -0.61 -0.204 0.10473E+04 64 cristobalite -2.56 -2.99 -0.43 -0.143 0.73267E+03 66 cymrite-K 1.69 -2.49 -4.18 -0.348 0.71295E+04 68 diaspore 2.87 0.43 -2.44 -0.407 0.41682E+04 69 diamond -3.10 -7.61 -4.51 -1.288 0.76979E+04 70 diopside 16.18 15.15 -1.03 -0.103 0.17616E+04 71 hedenbergite 14.21 12.84 -1.37 -0.137 0.23349E+04 78 epidote 24.67 21.57 -3.10 -0.150 0.52900E+04 80 epidote-Fe 29.84 26.39 -3.45 -0.179 0.58876E+04 81 fayalite 14.05 10.23 -3.82 -0.545 0.65180E+04 82 ferrosilite 11.15 7.24 -3.91 -0.391 0.66771E+04 86 gibbsite 4.08 0.43 -3.65 -0.521 0.62268E+04 87 glaucophane 22.97 20.01 -2.97 -0.080 0.50681E+04 88 glaucophane-Fe 17.28 13.08 -4.20 -0.113 0.71640E+04 89 graphite -3.55 -7.61 -4.06 -1.161 0.69401E+04 90 greenalite 16.14 13.85 -2.29 -0.191 0.39129E+04 93 hematite 12.57 10.51 -2.06 -0.250 0.35162E+04 94 heulandite -5.83 -7.85 -2.02 -0.092 0.34541E+04 98 jadeite 4.22 2.61 -1.61 -0.161 0.27485E+04 100 kalsilite 7.58 3.49 -4.10 -0.585 0.69923E+04 101 kaolinite -1.33 -5.11 -3.78 -0.344 0.64561E+04 104 laumontite 2.88 1.12 -1.77 -0.118 0.30142E+04 105 lawsonite 9.62 7.10 -2.52 -0.168 0.43013E+04 106 leucite 4.12 0.50 -3.62 -0.362 0.61802E+04 108 lizardite 23.24 20.77 -2.47 -0.206 0.42166E+04 109 magnesite 0.69 -4.11 -4.81 -1.602 0.82053E+04 110 magnetite 20.09 17.12 -2.97 -0.243 0.50740E+04 111 minnesotaite 10.39 7.87 -2.52 -0.148 0.43013E+04 115 manganosite 14.06 9.20 -4.86 -1.214 0.82903E+04 119 microcline -2.49 -2.49 0.00 0.000 0.61430E+01 123 muscovite 2.58 -1.63 -4.21 -0.247 0.71842E+04 124 paragonite 4.24 0.48 -3.76 -0.221 0.64171E+04 125 nepheline 8.34 5.60 -2.74 -0.392 0.46861E+04 137 phlogopite-Na 29.65 26.37 -3.28 -0.182 0.55961E+04 139 prehnite 19.37 16.32 -3.05 -0.180 0.52138E+04 140 prehnite-Fe 22.50 21.14 -1.36 -0.082 0.23198E+04 145 pyrite -21.25 -22.55 -1.31 -0.307 0.22305E+04 146 pyrrhotite -4.26 -6.62 -2.36 -0.785 0.40234E+04 147 pyrrhotiteFe0.875 -6.02 -7.78 -1.76 -0.648 0.30086E+04 148 pyroxmangite 7.40 6.21 -1.19 -0.237 0.20239E+04 149 pyrophyllite -6.18 -11.09 -4.92 -0.307 0.83955E+04 154 rhodochrosite -0.98 -3.83 -2.85 -0.951 0.48724E+04 155 rhodonite 7.45 6.21 -1.23 -0.246 0.21042E+04 156 sanidine -1.28 -2.49 -1.21 -0.093 0.20739E+04 158 siderite -2.61 -6.42 -3.82 -1.272 0.65151E+04 166 stilbite -7.52 -7.85 -0.33 -0.016 0.56031E+03 168 stilpnomelane-Mg 27.44 24.56 -2.88 -0.086 0.49180E+04 174 talc 16.49 14.80 -1.70 -0.100 0.28952E+04 177 tephroite 18.09 15.42 -2.67 -0.381 0.45584E+04 181 tridymite -2.63 -2.99 -0.36 -0.121 0.61998E+03 182 tremolite 47.87 45.09 -2.77 -0.075 0.47373E+04 183 ferroactinolite 38.45 33.55 -4.90 -0.132 0.83695E+04 184 troilite-low -4.41 -6.62 -2.21 -0.735 0.37663E+04 190 wairakite 3.95 1.12 -2.83 -0.167 0.48362E+04 191 walstromite 11.51 9.22 -2.29 -0.458 0.39065E+04 192 wollastonite 10.46 9.22 -1.24 -0.248 0.21169E+04 193 pseudo-wollastonite 11.00 9.22 -1.78 -0.356 0.30367E+04 195 akaganeite 7.75 5.25 -2.50 -0.541 0.42707E+04 202 chalcedony -2.80 -2.99 -0.19 -0.062 0.31930E+03 204 montmorillonite-Ca -2.29 -6.28 -3.99 -0.247 0.68078E+04 205 montmorillonite-K -2.24 -6.30 -4.06 -0.249 0.69337E+04 206 montmorillonite-Mg -2.48 -6.82 -4.34 -0.269 0.74126E+04 207 montmorillonite-Na -2.04 -5.60 -3.56 -0.218 0.60865E+04 208 nontronite-Ca 3.21 1.69 -1.52 -0.099 0.25977E+04 209 nontronite-H 2.53 -0.32 -2.85 -0.191 0.48737E+04 210 nontronite-K 3.34 1.67 -1.67 -0.107 0.28468E+04 211 nontronite-Mg 3.07 1.15 -1.92 -0.125 0.32866E+04 212 nontronite-Na 3.52 2.37 -1.15 -0.074 0.19657E+04 228 tobermorite 9.82 7.18 -2.64 -0.721 0.45092E+04 234 alabandite -0.98 -4.02 -3.04 -1.015 0.51992E+04 237 boehmite 4.41 0.43 -3.97 -0.662 0.67852E+04 239 ferrous-oxide 9.81 6.61 -3.20 -0.801 0.54685E+04 245 silica-amorphous -2.09 -2.99 -0.90 -0.299 0.15335E+04 247 an20ab80 2.02 1.11 -0.91 -0.070 0.15461E+04 248 an25ab75 2.65 1.49 -1.16 -0.089 0.19796E+04 249 an30ab70 3.28 1.86 -1.42 -0.109 0.24227E+04 250 tr.625ac.25prg.125 45.16 43.02 -2.14 -0.058 0.36576E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 0.0010000 MOLES Current total amount of reactant added: 0.0259900 MOLES New total amount of reactant added: 0.0269900 MOLES Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.5508E-08 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 7 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 0.0269900 Water: Moles liquid = 0.4987E+02 kg liquid = 0.8985E+00 Moles total = 0.4987E+02 kg total = 0.8984E+00 Activity = 1.0000 Stoichiometric ionic strength = .1306751E-01 Osmotic coef. = 0.9368 True ionic strength = .2153141E-01 Chg. balance for total moles = -.5508E-08 Max. difference allowed = 0.2971E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.14160E-09 -9.8489 0.11844E-09 -9.9265 0.83646E+00 -0.0776 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.32917E-03 -3.4826 0.27359E-03 -3.5629 0.83114E+00 -0.0803 4 SO4-- 0.12665E-03 -3.8974 0.64523E-04 -4.1903 0.50945E+00 -0.2929 5 HCO3- 0.99014E-03 -3.0043 0.82422E-03 -3.0840 0.83242E+00 -0.0797 6 HS- 0.63132E-03 -3.1998 0.52479E-03 -3.2800 0.83127E+00 -0.0803 7 Al+++ 0.20518E-28 -28.6879 0.45363E-29 -29.3433 0.22109E+00 -0.6554 8 H4SiO4 0.10246E-02 -2.9894 0.10246E-02 -2.9894 0.10000E+01 0.0000 9 Ca++ 0.43264E-07 -7.3639 0.21869E-07 -7.6602 0.50548E+00 -0.2963 10 Mg++ 0.22584E-10 -10.6462 0.11360E-10 -10.9446 0.50304E+00 -0.2984 11 Fe++ 0.11292E-12 -12.9472 0.56867E-13 -13.2451 0.50362E+00 -0.2979 12 K+ 0.15655E-03 -3.8053 0.13035E-03 -3.8849 0.83263E+00 -0.0795 13 Na+ 0.20052E-01 -1.6978 0.16663E-01 -1.7783 0.83097E+00 -0.0804 14 Mn++ 0.44285E-10 -10.3537 0.22322E-10 -10.6513 0.50406E+00 -0.2975 15 F- 0.12088E-04 -4.9177 0.10025E-04 -4.9989 0.82933E+00 -0.0813 16 HPO4-- 0.45648E-07 -7.3406 0.23259E-07 -7.6334 0.50952E+00 -0.2928 18 HSiO3- 0.97188E-02 -2.0124 0.80777E-02 -2.0927 0.83114E+00 -0.0803 19 Ca(HSiO3)+ 0.48306E-08 -8.3160 0.40230E-08 -8.3954 0.83282E+00 -0.0794 20 Mg(HSiO3)+ 0.31230E-11 -11.5054 0.26009E-11 -11.5849 0.83282E+00 -0.0794 21 NaHSiO3,aq 0.21769E-02 -2.6622 0.21769E-02 -2.6622 0.10000E+01 0.0000 22 AlO+ 0.52823E-16 -16.2772 0.43992E-16 -16.3566 0.83282E+00 -0.0794 24 HAlO2,aq 0.73968E-10 -10.1310 0.73968E-10 -10.1310 0.10000E+01 0.0000 25 AlO2- 0.16665E-05 -5.7782 0.13824E-05 -5.8594 0.82955E+00 -0.0812 26 CH4,aq 0.65378E-08 -8.1846 0.65118E-08 -8.1863 0.99603E+00 -0.0017 27 C2H6,aq 0.37311E-19 -19.4282 0.37163E-19 -19.4299 0.99603E+00 -0.0017 31 CO,aq 0.10221E-14 -14.9905 0.10221E-14 -14.9905 0.10000E+01 0.0000 32 CO2,aq 0.20943E-06 -6.6790 0.20859E-06 -6.6807 0.99603E+00 -0.0017 33 CO3-2 0.11958E-02 -2.9223 0.60783E-03 -3.2162 0.50830E+00 -0.2939 34 CaCO3,aq 0.16668E-06 -6.7781 0.16668E-06 -6.7781 0.10000E+01 0.0000 35 Ca(HCO3)+ 0.55246E-09 -9.2577 0.46010E-09 -9.3371 0.83282E+00 -0.0794 36 CaCl+ 0.11626E-10 -10.9346 0.96826E-11 -11.0140 0.83282E+00 -0.0794 37 CaCl2,aq 0.62936E-15 -15.2011 0.62936E-15 -15.2011 0.10000E+01 0.0000 38 CaF+ 0.38433E-11 -11.4153 0.32007E-11 -11.4947 0.83282E+00 -0.0794 39 CaOH+ 0.15801E-07 -7.8013 0.13159E-07 -7.8808 0.83282E+00 -0.0794 40 CaSO4,aq 0.44808E-09 -9.3486 0.44808E-09 -9.3486 0.10000E+01 0.0000 41 HCl,aq 0.59379E-14 -14.2264 0.59379E-14 -14.2264 0.10000E+01 0.0000 45 HF,aq 0.81281E-11 -11.0900 0.81281E-11 -11.0900 0.10000E+01 0.0000 46 HF2- 0.33099E-16 -16.4802 0.27510E-16 -16.5605 0.83114E+00 -0.0803 48 FeCl+ 0.29569E-16 -16.5292 0.24626E-16 -16.6086 0.83282E+00 -0.0794 51 FeF+ 0.34979E-16 -16.4562 0.29131E-16 -16.5356 0.83282E+00 -0.0794 53 FeO,aq 0.15755E-09 -9.8026 0.15755E-09 -9.8026 0.10000E+01 0.0000 54 FeOH+ 0.18766E-10 -10.7266 0.15629E-10 -10.8061 0.83282E+00 -0.0794 55 HFeO2- 0.16746E-07 -7.7761 0.13918E-07 -7.8564 0.83114E+00 -0.0803 56 FeO+ 0.10135E-15 -15.9942 0.84403E-16 -16.0736 0.83282E+00 -0.0794 58 FeO2- 0.14812E-08 -8.8294 0.12311E-08 -8.9097 0.83114E+00 -0.0803 59 HFeO2,aq 0.18546E-10 -10.7318 0.18546E-10 -10.7318 0.10000E+01 0.0000 60 H2,aq 0.19584E-06 -6.7081 0.19506E-06 -6.7098 0.99603E+00 -0.0017 61 KCl,aq 0.64635E-09 -9.1895 0.64635E-09 -9.1895 0.10000E+01 0.0000 62 KHSO4,aq 0.28165E-17 -17.5503 0.28165E-17 -17.5503 0.10000E+01 0.0000 63 KOH,aq 0.46999E-06 -6.3279 0.46999E-06 -6.3279 0.10000E+01 0.0000 64 KSO4- 0.15703E-06 -6.8040 0.13051E-06 -6.8843 0.83114E+00 -0.0803 65 MgCO3,aq 0.21703E-10 -10.6635 0.21703E-10 -10.6635 0.10000E+01 0.0000 66 Mg(HCO3)+ 0.29325E-12 -12.5328 0.24423E-12 -12.6122 0.83282E+00 -0.0794 67 MgCl+ 0.54739E-14 -14.2617 0.45588E-14 -14.3412 0.83282E+00 -0.0794 68 MgF+ 0.73956E-14 -14.1310 0.61592E-14 -14.2105 0.83282E+00 -0.0794 69 MgOH+ 0.45420E-10 -10.3428 0.37826E-10 -10.4222 0.83282E+00 -0.0794 71 MnF+ 0.45257E-14 -14.3443 0.37691E-14 -14.4238 0.83282E+00 -0.0794 72 MnO,aq 0.16479E-08 -8.7831 0.16479E-08 -8.7831 0.10000E+01 0.0000 73 MnOH+ 0.68430E-09 -9.1648 0.56990E-09 -9.2442 0.83282E+00 -0.0794 74 MnO2-2 0.76694E-11 -11.1152 0.38984E-11 -11.4091 0.50830E+00 -0.2939 75 HMnO2- 0.12171E-09 -9.9147 0.10116E-09 -9.9950 0.83114E+00 -0.0803 78 MnCl+ 0.45156E-13 -13.3453 0.37607E-13 -13.4247 0.83282E+00 -0.0794 79 MnSO4,aq 0.41581E-12 -12.3811 0.41581E-12 -12.3811 0.10000E+01 0.0000 80 NaCl,aq 0.15108E-05 -5.8208 0.15108E-05 -5.8208 0.10000E+01 0.0000 81 NaF,aq 0.39107E-07 -7.4078 0.39107E-07 -7.4078 0.10000E+01 0.0000 82 NaOH,aq 0.60445E-04 -4.2186 0.60445E-04 -4.2186 0.10000E+01 0.0000 84 OH- 0.58805E-02 -2.2306 0.48781E-02 -2.3117 0.82955E+00 -0.0812 89 HPO3-2 0.27815E-16 -16.5557 0.14138E-16 -16.8496 0.50830E+00 -0.2939 92 H3PO4,aq 0.22820E-17 -17.6417 0.22820E-17 -17.6417 0.10000E+01 0.0000 93 H2PO4- 0.61082E-10 -10.2141 0.50818E-10 -10.2940 0.83197E+00 -0.0799 94 PO4-3 0.68800E-09 -9.1624 0.16022E-09 -9.7953 0.23288E+00 -0.6329 98 HP2O7-3 0.15424E-17 -17.8118 0.34138E-18 -18.4668 0.22133E+00 -0.6550 99 P2O7-4 0.96401E-17 -17.0159 0.68856E-18 -18.1621 0.71426E-01 -1.1461 100 H2S,aq 0.19287E-06 -6.7147 0.19210E-06 -6.7165 0.99603E+00 -0.0017 101 S2-2 0.61547E-10 -10.2108 0.31285E-10 -10.5047 0.50830E+00 -0.2939 102 S3-2 0.81663E-16 -16.0880 0.41509E-16 -16.3819 0.50830E+00 -0.2939 107 SO3-2 0.31692E-11 -11.4991 0.16356E-11 -11.7863 0.51609E+00 -0.2873 108 HSO3- 0.14593E-13 -13.8358 0.12129E-13 -13.9162 0.83114E+00 -0.0803 109 HSO4- 0.88343E-11 -11.0538 0.73650E-11 -11.1328 0.83368E+00 -0.0790 111 S2O3-2 0.28645E-12 -12.5429 0.14560E-12 -12.8368 0.50830E+00 -0.2939 Charge balance for all species = -.6130E-08 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.1415988E-09 -.1903950E-01 -.1915599E+02 0.0000 2 H2O 0.1000000E+01 0.5550230E+02 0.9980837E+06 0.0000 3 Cl- 0.3291737E-03 0.3306852E-03 0.1170260E+02 6.3636 4 SO4-- 0.1266540E-03 0.1267562E-03 0.1215440E+02 15.6627 5 HCO3- 0.9901435E-03 0.2186329E-02 0.1331626E+03 6.8425 6 HS- 0.6313160E-03 0.6315643E-03 0.2084935E+02 6.6465 7 Al+++ 0.2051844E-28 0.1666528E-05 0.4488418E-01 0.4362 8 H4SiO4 0.1024625E-02 0.1292040E-01 0.1239605E+04 -2.9894 9 Ca++ 0.4326368E-07 0.2315863E-06 0.9264743E-02 12.1928 10 Mg++ 0.2258379E-10 0.9313521E-10 0.2260212E-05 8.9084 11 Fe++ 0.1129168E-12 0.1842182E-07 0.1026944E-02 6.6079 12 K+ 0.1565516E-03 0.1571793E-03 0.6134919E+01 6.0416 13 Na+ 0.2005220E-01 0.2229112E-01 0.5115423E+03 8.1482 14 Mn++ 0.4428478E-10 0.2506293E-08 0.1374419E-03 9.2017 15 F- 0.1208757E-04 0.1212669E-04 0.2299666E+00 4.9276 16 HPO4-- 0.4564774E-07 0.4639682E-07 0.4445074E-02 12.2196 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.1712039E-01 -.1710725E-01 -.1313908E-04 0.0000000E+00 2 H2O 0.4986851E+02 0.4986959E+02 -.1081137E-02 0.0000000E+00 3 Cl- 0.2971252E-03 0.2971252E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.1138922E-03 0.1138922E-03 0.0000000E+00 0.0000000E+00 5 HCO3- 0.1964447E-02 0.1964447E-02 0.0000000E+00 0.0000000E+00 6 HS- 0.5674693E-03 0.5674693E-03 0.0000000E+00 0.0000000E+00 7 Al+++ 0.4775352E-05 0.1497399E-05 0.3277953E-05 0.0000000E+00 8 H4SiO4 0.1215302E-01 0.1160916E-01 0.5438634E-03 0.0000000E+00 9 Ca++ 0.2080835E-06 0.2080835E-06 0.0000000E+00 0.0000000E+00 10 Mg++ 0.8368328E-10 0.8368328E-10 0.0000000E+00 0.0000000E+00 11 Fe++ 0.3259227E-07 0.1655226E-07 0.1604001E-07 0.0000000E+00 12 K+ 0.1412294E-03 0.1412278E-03 0.1604001E-08 0.0000000E+00 13 Na+ 0.2003215E-01 0.2002888E-01 0.3271537E-05 0.0000000E+00 14 Mn++ 0.2251939E-08 0.2251939E-08 0.0000000E+00 0.0000000E+00 15 F- 0.1089600E-04 0.1089600E-04 0.0000000E+00 0.0000000E+00 16 HPO4-- 0.4168819E-07 0.4168819E-07 0.0000000E+00 0.0000000E+00 Chg. balance for solid moles: -.8470E-21 Mass of aqueous solution: 0.900140E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 0.0269900 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 0.3272E-05 -5.485 0.8579E-03 -3.067 2.604 0.3293E-03 quartz 0.5340E-03 -3.272 0.3208E-01 -1.494 97.39 0.1212E-01 stilpnomelane-Fe 0.3208E-08 -8.494 0.3458E-05 -5.461 0.1050E-01 0.1195E-05 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 quartz 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 0.032945 g Volume = 0.012447 cm3 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.0269900 moles log = -1.5688 Original solution: 1000.0103000 g Original solution / Rock added: 37051.14 (Water/Rock Ratio), log = 4.5688 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0206 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9997E+00 0.9859 0.1006E+01 0.1020E+01 CO2,gas 0.2171E-04 1.0071 0.2232E-04 0.2216E-04 CH4,gas 0.9275E-05 1.0125 0.9585E-05 0.9466E-05 H2,gas 0.2508E-03 1.0005 0.2561E-03 0.2560E-03 H2S,gas 0.5195E-05 0.9960 0.5281E-05 0.5302E-05 S2,gas 0.1564E-22 1.0000 0.1596E-22 0.1596E-22 CO,gas 0.1492E-11 1.0000 0.1523E-11 0.1523E-11 SO3,gas 0.3353E-39 1.0000 0.3422E-39 0.3422E-39 SO2,gas 0.3341E-20 1.0000 0.3410E-20 0.3410E-20 HF,gas 0.1955E-13 1.0000 0.1996E-13 0.1996E-13 HCl,gas 0.1027E-16 1.0000 0.1048E-16 0.1048E-16 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 17 albite -0.38 -0.38 0.00 0.000 -0.94784E-12 150 quartz -2.99 -2.99 0.00 0.000 0.00000E+00 167 stilpnomelane-Fe 13.02 13.02 0.00 0.000 0.21232E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -13.01 -6.35 -2.117 0.10843E+05 -4.651 3 CH4,gas 4.54 -2.17 -6.72 -1.679 0.11470E+05 -5.018 4 H2,gas 8.00 2.71 -5.29 -3.023 0.90335E+04 -3.592 5 H2S,gas -6.23 -13.21 -6.98 -3.488 0.11912E+05 -5.277 6 S2,gas -7.34 -31.83 -24.50 -3.769 0.41826E+05 -22.797 7 CO,gas 3.21 -10.30 -13.52 -4.159 0.23079E+05 -11.817 8 SO3,gas 17.12 -24.04 -41.16 -10.291 0.70287E+05 -39.466 9 SO2,gas 0.83 -21.33 -22.17 -5.911 0.37848E+05 -20.467 10 HF,gas 0.47 -14.93 -15.40 -7.699 0.26293E+05 -13.700 11 HCl,gas 5.19 -13.49 -18.68 -9.339 0.31893E+05 -16.980 12 acmite 7.71 7.42 -0.29 -0.030 0.49018E+03 16 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 20 spessartine 24.46 19.51 -4.95 -0.247 0.84487E+04 21 analcite 3.32 2.61 -0.72 -0.080 0.12231E+04 23 andradite 39.01 38.12 -0.89 -0.046 0.15232E+04 24 grossular 32.73 28.48 -4.25 -0.212 0.72549E+04 27 annite 20.12 17.33 -2.79 -0.155 0.47644E+04 28 phlogopite 27.06 24.23 -2.83 -0.157 0.48320E+04 33 apatite-OH -18.15 -21.50 -3.34 -0.257 0.57057E+04 34 apatite-F -34.30 -36.42 -2.12 -0.177 0.36191E+04 38 aragonite 0.97 -0.82 -1.78 -0.595 0.30464E+04 39 brucite 12.57 8.91 -3.66 -0.732 0.62497E+04 40 calcite 0.81 -0.82 -1.63 -0.543 0.27822E+04 41 carnegieite-low 9.02 5.60 -3.43 -0.490 0.58537E+04 42 carnegieite-high 10.09 5.60 -4.50 -0.643 0.76807E+04 43 carpholite-Mg 8.58 3.80 -4.78 -0.319 0.81620E+04 45 celadonite 5.34 3.43 -1.91 -0.113 0.32667E+04 46 celadonite-Fe 3.88 1.13 -2.75 -0.162 0.46932E+04 47 chrysotile 23.89 20.75 -3.15 -0.262 0.53719E+04 49 clinochlore 39.07 36.45 -2.62 -0.082 0.44796E+04 50 daphnite 28.97 24.94 -4.02 -0.126 0.68673E+04 54 chloritoid-Fe 9.17 4.49 -4.68 -0.312 0.79958E+04 55 chloritoid-Mn 11.40 7.08 -4.32 -0.288 0.73701E+04 57 coesite -2.38 -2.99 -0.61 -0.204 0.10473E+04 64 cristobalite -2.56 -2.99 -0.43 -0.143 0.73267E+03 66 cymrite-K 1.69 -2.49 -4.18 -0.348 0.71302E+04 68 diaspore 2.87 0.44 -2.44 -0.406 0.41620E+04 69 diamond -3.10 -7.59 -4.49 -1.283 0.76660E+04 70 diopside 16.18 15.12 -1.06 -0.106 0.18082E+04 71 hedenbergite 14.21 12.82 -1.39 -0.139 0.23674E+04 78 epidote 24.67 21.54 -3.13 -0.152 0.53392E+04 80 epidote-Fe 29.84 26.36 -3.48 -0.181 0.59433E+04 81 fayalite 14.05 10.23 -3.82 -0.546 0.65216E+04 82 ferrosilite 11.15 7.24 -3.91 -0.391 0.66807E+04 86 gibbsite 4.08 0.44 -3.64 -0.520 0.62205E+04 87 glaucophane 22.97 19.98 -3.00 -0.081 0.51160E+04 88 glaucophane-Fe 17.28 13.08 -4.20 -0.113 0.71695E+04 89 graphite -3.55 -7.59 -4.05 -1.156 0.69083E+04 90 greenalite 16.14 13.84 -2.29 -0.191 0.39183E+04 93 hematite 12.57 10.51 -2.06 -0.250 0.35168E+04 94 heulandite -5.83 -7.86 -2.03 -0.092 0.34723E+04 98 jadeite 4.22 2.61 -1.61 -0.161 0.27485E+04 100 kalsilite 7.58 3.49 -4.10 -0.585 0.69930E+04 101 kaolinite -1.33 -5.11 -3.77 -0.343 0.64435E+04 104 laumontite 2.88 1.11 -1.78 -0.118 0.30324E+04 105 lawsonite 9.62 7.09 -2.53 -0.169 0.43195E+04 106 leucite 4.12 0.50 -3.62 -0.362 0.61809E+04 108 lizardite 23.24 20.75 -2.50 -0.208 0.42645E+04 109 magnesite 0.69 -4.10 -4.79 -1.598 0.81833E+04 110 magnetite 20.09 17.11 -2.97 -0.243 0.50764E+04 111 minnesotaite 10.39 7.87 -2.52 -0.148 0.43067E+04 115 manganosite 14.06 9.20 -4.86 -1.214 0.82921E+04 119 microcline -2.49 -2.49 0.00 0.000 0.68493E+01 123 muscovite 2.58 -1.62 -4.20 -0.247 0.71723E+04 124 paragonite 4.24 0.49 -3.75 -0.221 0.64046E+04 125 nepheline 8.34 5.60 -2.74 -0.392 0.46861E+04 137 phlogopite-Na 29.65 26.34 -3.31 -0.184 0.56440E+04 139 prehnite 19.37 16.29 -3.08 -0.181 0.52627E+04 140 prehnite-Fe 22.50 21.11 -1.39 -0.084 0.23752E+04 145 pyrite -21.25 -22.51 -1.27 -0.298 0.21641E+04 146 pyrrhotite -4.26 -6.60 -2.34 -0.779 0.39926E+04 147 pyrrhotiteFe0.875 -6.02 -7.76 -1.74 -0.641 0.29772E+04 148 pyroxmangite 7.40 6.21 -1.19 -0.237 0.20257E+04 149 pyrophyllite -6.18 -11.09 -4.91 -0.307 0.83829E+04 154 rhodochrosite -0.98 -3.81 -2.83 -0.944 0.48363E+04 155 rhodonite 7.45 6.21 -1.23 -0.247 0.21060E+04 156 sanidine -1.28 -2.49 -1.22 -0.093 0.20746E+04 158 siderite -2.61 -6.40 -3.79 -1.265 0.64789E+04 166 stilbite -7.52 -7.86 -0.34 -0.016 0.57847E+03 168 stilpnomelane-Mg 27.44 24.52 -2.92 -0.087 0.49888E+04 174 talc 16.49 14.77 -1.72 -0.101 0.29431E+04 177 tephroite 18.09 15.41 -2.67 -0.382 0.45620E+04 181 tridymite -2.63 -2.99 -0.36 -0.121 0.61998E+03 182 tremolite 47.87 45.01 -2.86 -0.077 0.48785E+04 183 ferroactinolite 38.45 33.51 -4.94 -0.134 0.84399E+04 184 troilite-low -4.41 -6.60 -2.19 -0.729 0.37355E+04 190 wairakite 3.95 1.11 -2.84 -0.167 0.48543E+04 191 walstromite 11.51 9.20 -2.31 -0.461 0.39372E+04 192 wollastonite 10.46 9.20 -1.26 -0.252 0.21476E+04 193 pseudo-wollastonite 11.00 9.20 -1.80 -0.359 0.30674E+04 195 akaganeite 7.75 5.25 -2.50 -0.541 0.42709E+04 202 chalcedony -2.80 -2.99 -0.19 -0.062 0.31930E+03 204 montmorillonite-Ca -2.29 -6.28 -3.99 -0.247 0.68077E+04 205 montmorillonite-K -2.24 -6.30 -4.06 -0.249 0.69308E+04 206 montmorillonite-Mg -2.48 -6.82 -4.34 -0.268 0.74100E+04 207 montmorillonite-Na -2.04 -5.60 -3.56 -0.218 0.60834E+04 208 nontronite-Ca 3.21 1.69 -1.52 -0.099 0.26013E+04 209 nontronite-H 2.53 -0.32 -2.85 -0.191 0.48722E+04 210 nontronite-K 3.34 1.67 -1.67 -0.107 0.28476E+04 211 nontronite-Mg 3.07 1.15 -1.93 -0.125 0.32877E+04 212 nontronite-Na 3.52 2.37 -1.15 -0.074 0.19662E+04 228 tobermorite 9.82 7.17 -2.66 -0.725 0.45348E+04 234 alabandite -0.98 -4.00 -3.03 -1.009 0.51684E+04 237 boehmite 4.41 0.44 -3.97 -0.662 0.67789E+04 239 ferrous-oxide 9.81 6.61 -3.20 -0.801 0.54703E+04 245 silica-amorphous -2.09 -2.99 -0.90 -0.299 0.15335E+04 247 an20ab80 2.02 1.11 -0.91 -0.070 0.15497E+04 248 an25ab75 2.65 1.48 -1.16 -0.089 0.19841E+04 249 an30ab70 3.28 1.86 -1.42 -0.109 0.24281E+04 250 tr.625ac.25prg.125 45.16 42.95 -2.21 -0.060 0.37776E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 0.0010000 MOLES Current total amount of reactant added: 0.0269900 MOLES New total amount of reactant added: 0.0279900 MOLES Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.5508E-08 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 7 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 0.0279900 Water: Moles liquid = 0.4988E+02 kg liquid = 0.8985E+00 Moles total = 0.4987E+02 kg total = 0.8984E+00 Activity = 1.0000 Stoichiometric ionic strength = .1313248E-01 Osmotic coef. = 0.9365 True ionic strength = .2159433E-01 Chg. balance for total moles = -.5508E-08 Max. difference allowed = 0.3030E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.14294E-09 -9.8448 0.11954E-09 -9.9225 0.83631E+00 -0.0776 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.33570E-03 -3.4740 0.27896E-03 -3.5545 0.83097E+00 -0.0804 4 SO4-- 0.13196E-03 -3.8796 0.67174E-04 -4.1728 0.50905E+00 -0.2932 5 HCO3- 0.10314E-02 -2.9866 0.85842E-03 -3.0663 0.83226E+00 -0.0797 6 HS- 0.65303E-03 -3.1851 0.54273E-03 -3.2654 0.83110E+00 -0.0803 7 Al+++ 0.21313E-28 -28.6713 0.47037E-29 -29.3276 0.22069E+00 -0.6562 8 H4SiO4 0.10246E-02 -2.9894 0.10246E-02 -2.9894 0.10000E+01 0.0000 9 Ca++ 0.42345E-07 -7.3732 0.21388E-07 -7.6698 0.50508E+00 -0.2966 10 Mg++ 0.22532E-10 -10.6472 0.11325E-10 -10.9459 0.50263E+00 -0.2988 11 Fe++ 0.11483E-12 -12.9399 0.57785E-13 -13.2382 0.50321E+00 -0.2982 12 K+ 0.15655E-03 -3.8054 0.13032E-03 -3.8850 0.83247E+00 -0.0796 13 Na+ 0.20071E-01 -1.6974 0.16675E-01 -1.7779 0.83081E+00 -0.0805 14 Mn++ 0.45035E-10 -10.3464 0.22682E-10 -10.6443 0.50366E+00 -0.2979 15 F- 0.12531E-04 -4.9020 0.10390E-04 -4.9834 0.82916E+00 -0.0814 16 HPO4-- 0.45652E-07 -7.3405 0.23243E-07 -7.6337 0.50913E+00 -0.2932 18 HSiO3- 0.96314E-02 -2.0163 0.80034E-02 -2.0967 0.83097E+00 -0.0804 19 Ca(HSiO3)+ 0.46817E-08 -8.3296 0.38983E-08 -8.4091 0.83266E+00 -0.0795 20 Mg(HSiO3)+ 0.30853E-11 -11.5107 0.25690E-11 -11.5902 0.83266E+00 -0.0795 21 NaHSiO3,aq 0.21585E-02 -2.6659 0.21585E-02 -2.6659 0.10000E+01 0.0000 22 AlO+ 0.53779E-16 -16.2694 0.44780E-16 -16.3489 0.83266E+00 -0.0795 24 HAlO2,aq 0.74600E-10 -10.1273 0.74600E-10 -10.1273 0.10000E+01 0.0000 25 AlO2- 0.16656E-05 -5.7784 0.13814E-05 -5.8597 0.82938E+00 -0.0812 26 CH4,aq 0.67641E-08 -8.1698 0.67370E-08 -8.1715 0.99601E+00 -0.0017 27 C2H6,aq 0.40097E-19 -19.3969 0.39937E-19 -19.3986 0.99601E+00 -0.0017 31 CO,aq 0.10702E-14 -14.9705 0.10702E-14 -14.9705 0.10000E+01 0.0000 32 CO2,aq 0.22014E-06 -6.6573 0.21927E-06 -6.6590 0.99601E+00 -0.0017 33 CO3-2 0.12349E-02 -2.9084 0.62723E-03 -3.2026 0.50790E+00 -0.2942 34 CaCO3,aq 0.16821E-06 -6.7742 0.16821E-06 -6.7742 0.10000E+01 0.0000 35 Ca(HCO3)+ 0.56283E-09 -9.2496 0.46864E-09 -9.3292 0.83266E+00 -0.0795 36 CaCl+ 0.11596E-10 -10.9357 0.96553E-11 -11.0152 0.83266E+00 -0.0795 37 CaCl2,aq 0.63990E-15 -15.1939 0.63990E-15 -15.1939 0.10000E+01 0.0000 38 CaF+ 0.38965E-11 -11.4093 0.32444E-11 -11.4889 0.83266E+00 -0.0795 39 CaOH+ 0.15314E-07 -7.8149 0.12751E-07 -7.8945 0.83266E+00 -0.0795 40 CaSO4,aq 0.45621E-09 -9.3408 0.45621E-09 -9.3408 0.10000E+01 0.0000 41 HCl,aq 0.61107E-14 -14.2139 0.61107E-14 -14.2139 0.10000E+01 0.0000 45 HF,aq 0.85027E-11 -11.0704 0.85027E-11 -11.0704 0.10000E+01 0.0000 46 HF2- 0.35895E-16 -16.4450 0.29828E-16 -16.5254 0.83097E+00 -0.0804 48 FeCl+ 0.30643E-16 -16.5137 0.25515E-16 -16.5932 0.83266E+00 -0.0795 51 FeF+ 0.36847E-16 -16.4336 0.30681E-16 -16.5131 0.83266E+00 -0.0795 53 FeO,aq 0.15716E-09 -9.8037 0.15716E-09 -9.8037 0.10000E+01 0.0000 54 FeOH+ 0.18897E-10 -10.7236 0.15735E-10 -10.8031 0.83266E+00 -0.0795 55 HFeO2- 0.16554E-07 -7.7811 0.13756E-07 -7.8615 0.83097E+00 -0.0804 56 FeO+ 0.10226E-15 -15.9903 0.85146E-16 -16.0698 0.83266E+00 -0.0795 58 FeO2- 0.14672E-08 -8.8335 0.12192E-08 -8.9139 0.83097E+00 -0.0804 59 HFeO2,aq 0.18537E-10 -10.7320 0.18537E-10 -10.7320 0.10000E+01 0.0000 60 H2,aq 0.19507E-06 -6.7098 0.19429E-06 -6.7116 0.99601E+00 -0.0017 61 KCl,aq 0.65889E-09 -9.1812 0.65889E-09 -9.1812 0.10000E+01 0.0000 62 KHSO4,aq 0.29588E-17 -17.5289 0.29588E-17 -17.5289 0.10000E+01 0.0000 63 KOH,aq 0.46557E-06 -6.3320 0.46557E-06 -6.3320 0.10000E+01 0.0000 64 KSO4- 0.16347E-06 -6.7865 0.13584E-06 -6.8670 0.83097E+00 -0.0804 65 MgCO3,aq 0.22326E-10 -10.6512 0.22326E-10 -10.6512 0.10000E+01 0.0000 66 Mg(HCO3)+ 0.30454E-12 -12.5164 0.25358E-12 -12.5959 0.83266E+00 -0.0795 67 MgCl+ 0.55652E-14 -14.2545 0.46339E-14 -14.3340 0.83266E+00 -0.0795 68 MgF+ 0.76432E-14 -14.1167 0.63642E-14 -14.1963 0.83266E+00 -0.0795 69 MgOH+ 0.44872E-10 -10.3480 0.37363E-10 -10.4276 0.83266E+00 -0.0795 71 MnF+ 0.47674E-14 -14.3217 0.39696E-14 -14.4013 0.83266E+00 -0.0795 72 MnO,aq 0.16438E-08 -8.7842 0.16438E-08 -8.7842 0.10000E+01 0.0000 73 MnOH+ 0.68908E-09 -9.1617 0.57377E-09 -9.2413 0.83266E+00 -0.0795 74 MnO2-2 0.75163E-11 -11.1240 0.38176E-11 -11.4182 0.50790E+00 -0.2942 75 HMnO2- 0.12032E-09 -9.9197 0.99981E-10 -10.0001 0.83097E+00 -0.0804 78 MnCl+ 0.46795E-13 -13.3298 0.38964E-13 -13.4093 0.83266E+00 -0.0795 79 MnSO4,aq 0.43987E-12 -12.3567 0.43987E-12 -12.3567 0.10000E+01 0.0000 80 NaCl,aq 0.15416E-05 -5.8120 0.15416E-05 -5.8120 0.10000E+01 0.0000 81 NaF,aq 0.40562E-07 -7.3919 0.40562E-07 -7.3919 0.10000E+01 0.0000 82 NaOH,aq 0.59932E-04 -4.2223 0.59932E-04 -4.2223 0.10000E+01 0.0000 84 OH- 0.58276E-02 -2.2345 0.48333E-02 -2.3158 0.82938E+00 -0.0812 89 HPO3-2 0.27708E-16 -16.5574 0.14073E-16 -16.8516 0.50790E+00 -0.2942 92 H3PO4,aq 0.23230E-17 -17.6340 0.23230E-17 -17.6340 0.10000E+01 0.0000 93 H2PO4- 0.61619E-10 -10.2103 0.51255E-10 -10.2903 0.83181E+00 -0.0800 94 PO4-3 0.68234E-09 -9.1660 0.15864E-09 -9.7996 0.23249E+00 -0.6336 98 HP2O7-3 0.15574E-17 -17.8076 0.34407E-18 -18.4633 0.22093E+00 -0.6557 99 P2O7-4 0.96569E-17 -17.0152 0.68762E-18 -18.1627 0.71205E-01 -1.1475 100 H2S,aq 0.20132E-06 -6.6961 0.20051E-06 -6.6979 0.99601E+00 -0.0017 101 S2-2 0.66140E-10 -10.1795 0.33593E-10 -10.4738 0.50790E+00 -0.2942 102 S3-2 0.91963E-16 -16.0364 0.46709E-16 -16.3306 0.50790E+00 -0.2942 103 S3- 0.10218E-19 -19.9906 0.84912E-20 -20.0710 0.83097E+00 -0.0804 107 SO3-2 0.32887E-11 -11.4830 0.16960E-11 -11.7706 0.51570E+00 -0.2876 108 HSO3- 0.15276E-13 -13.8160 0.12694E-13 -13.8964 0.83097E+00 -0.0804 109 HSO4- 0.92843E-11 -11.0323 0.77387E-11 -11.1113 0.83352E+00 -0.0791 111 S2O3-2 0.31152E-12 -12.5065 0.15822E-12 -12.8007 0.50790E+00 -0.2942 Charge balance for all species = -.6130E-08 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.1429389E-09 -.1891929E-01 -.1903510E+02 0.0000 2 H2O 0.1000000E+01 0.5550235E+02 0.9980874E+06 0.0000 3 Cl- 0.3357028E-03 0.3372450E-03 0.1193478E+02 6.3680 4 SO4-- 0.1319594E-03 0.1320680E-03 0.1266377E+02 15.6722 5 HCO3- 0.1031425E-02 0.2266752E-02 0.1380613E+03 6.8562 6 HS- 0.6530252E-03 0.6532820E-03 0.2156636E+02 6.6571 7 Al+++ 0.2131329E-28 0.1665659E-05 0.4486090E-01 0.4399 8 H4SiO4 0.1024625E-02 0.1281449E-01 0.1229448E+04 -2.9894 9 Ca++ 0.4234467E-07 0.2315818E-06 0.9264590E-02 12.1751 10 Mg++ 0.2253227E-10 0.9313342E-10 0.2260174E-05 8.8990 11 Fe++ 0.1148319E-12 0.1821610E-07 0.1015479E-02 6.6068 12 K+ 0.1565466E-03 0.1571763E-03 0.6134817E+01 6.0375 13 Na+ 0.2007070E-01 0.2229069E-01 0.5115338E+03 8.1445 14 Mn++ 0.4503540E-10 0.2506245E-08 0.1374396E-03 9.2007 15 F- 0.1253105E-04 0.1257163E-04 0.2384049E+00 4.9391 16 HPO4-- 0.4565197E-07 0.4639593E-07 0.4445000E-02 12.2113 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.1701272E-01 -.1699957E-01 -.1314240E-04 0.0000000E+00 2 H2O 0.4986932E+02 0.4987060E+02 -.1271007E-02 0.0000000E+00 3 Cl- 0.3030252E-03 0.3030252E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.1186672E-03 0.1186672E-03 0.0000000E+00 0.0000000E+00 5 HCO3- 0.2036747E-02 0.2036747E-02 0.0000000E+00 0.0000000E+00 6 HS- 0.5869943E-03 0.5869943E-03 0.0000000E+00 0.0000000E+00 7 Al+++ 0.4775352E-05 0.1496647E-05 0.3278705E-05 0.0000000E+00 8 H4SiO4 0.1215302E-01 0.1151422E-01 0.6387992E-03 0.0000000E+00 9 Ca++ 0.2080835E-06 0.2080835E-06 0.0000000E+00 0.0000000E+00 10 Mg++ 0.8368328E-10 0.8368328E-10 0.0000000E+00 0.0000000E+00 11 Fe++ 0.3259227E-07 0.1636774E-07 0.1622453E-07 0.0000000E+00 12 K+ 0.1412294E-03 0.1412278E-03 0.1622453E-08 0.0000000E+00 13 Na+ 0.2003215E-01 0.2002888E-01 0.3272215E-05 0.0000000E+00 14 Mn++ 0.2251939E-08 0.2251939E-08 0.0000000E+00 0.0000000E+00 15 F- 0.1129600E-04 0.1129600E-04 0.0000000E+00 0.0000000E+00 16 HPO4-- 0.4168819E-07 0.4168819E-07 0.0000000E+00 0.0000000E+00 Chg. balance for solid moles: 0.4235E-21 Mass of aqueous solution: 0.900155E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 0.0279900 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 0.3272E-05 -5.485 0.8580E-03 -3.066 2.220 0.3294E-03 quartz 0.6290E-03 -3.201 0.3779E-01 -1.423 97.77 0.1427E-01 stilpnomelane-Fe 0.3245E-08 -8.489 0.3498E-05 -5.456 0.9051E-02 0.1208E-05 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 quartz 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 0.038649 g Volume = 0.014601 cm3 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.0279900 moles log = -1.5530 Original solution: 1000.0103000 g Original solution / Rock added: 35727.41 (Water/Rock Ratio), log = 4.5530 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0206 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9997E+00 0.9859 0.1006E+01 0.1020E+01 CO2,gas 0.2282E-04 1.0071 0.2346E-04 0.2329E-04 CH4,gas 0.9596E-05 1.0125 0.9916E-05 0.9794E-05 H2,gas 0.2498E-03 1.0005 0.2551E-03 0.2549E-03 H2S,gas 0.5422E-05 0.9960 0.5512E-05 0.5534E-05 S2,gas 0.1717E-22 1.0000 0.1753E-22 0.1753E-22 CO,gas 0.1563E-11 1.0000 0.1595E-11 0.1595E-11 SO3,gas 0.3556E-39 1.0000 0.3629E-39 0.3629E-39 SO2,gas 0.3529E-20 1.0000 0.3602E-20 0.3602E-20 HF,gas 0.2046E-13 1.0000 0.2088E-13 0.2088E-13 HCl,gas 0.1056E-16 1.0000 0.1078E-16 0.1078E-16 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 17 albite -0.38 -0.38 0.00 0.000 -0.13080E-10 150 quartz -2.99 -2.99 0.00 0.000 0.00000E+00 167 stilpnomelane-Fe 13.02 13.02 0.00 0.000 -0.27298E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -12.99 -6.33 -2.110 0.10806E+05 -4.630 3 CH4,gas 4.54 -2.16 -6.70 -1.676 0.11445E+05 -5.004 4 H2,gas 8.00 2.71 -5.29 -3.024 0.90364E+04 -3.593 5 H2S,gas -6.23 -13.19 -6.96 -3.479 0.11880E+05 -5.259 6 S2,gas -7.34 -31.79 -24.46 -3.762 0.41757E+05 -22.756 7 CO,gas 3.21 -10.28 -13.50 -4.153 0.23045E+05 -11.797 8 SO3,gas 17.12 -24.02 -41.14 -10.285 0.70244E+05 -39.440 9 SO2,gas 0.83 -21.31 -22.14 -5.905 0.37808E+05 -20.443 10 HF,gas 0.47 -14.91 -15.38 -7.690 0.26260E+05 -13.680 11 HCl,gas 5.19 -13.48 -18.67 -9.333 0.31872E+05 -16.967 12 acmite 7.71 7.42 -0.29 -0.030 0.49685E+03 16 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 20 spessartine 24.46 19.51 -4.94 -0.247 0.84416E+04 21 analcite 3.32 2.61 -0.72 -0.080 0.12231E+04 23 andradite 39.01 38.06 -0.95 -0.049 0.16145E+04 24 grossular 32.73 28.44 -4.29 -0.215 0.73329E+04 27 annite 20.12 17.33 -2.79 -0.155 0.47706E+04 28 phlogopite 27.06 24.21 -2.86 -0.159 0.48807E+04 33 apatite-OH -18.15 -21.56 -3.41 -0.262 0.58172E+04 34 apatite-F -34.30 -36.47 -2.17 -0.180 0.36971E+04 38 aragonite 0.97 -0.81 -1.78 -0.593 0.30396E+04 39 brucite 12.57 8.90 -3.67 -0.734 0.62656E+04 40 calcite 0.81 -0.81 -1.63 -0.542 0.27754E+04 41 carnegieite-low 9.02 5.60 -3.43 -0.490 0.58537E+04 42 carnegieite-high 10.09 5.60 -4.50 -0.643 0.76807E+04 43 carpholite-Mg 8.58 3.80 -4.78 -0.319 0.81654E+04 45 celadonite 5.34 3.42 -1.92 -0.113 0.32834E+04 46 celadonite-Fe 3.88 1.13 -2.75 -0.162 0.46957E+04 47 chrysotile 23.89 20.72 -3.17 -0.265 0.54199E+04 49 clinochlore 39.07 36.41 -2.66 -0.083 0.45469E+04 50 daphnite 28.97 24.95 -4.02 -0.126 0.68638E+04 54 chloritoid-Fe 9.17 4.50 -4.68 -0.312 0.79850E+04 55 chloritoid-Mn 11.40 7.09 -4.31 -0.287 0.73593E+04 57 coesite -2.38 -2.99 -0.61 -0.204 0.10473E+04 64 cristobalite -2.56 -2.99 -0.43 -0.143 0.73267E+03 66 cymrite-K 1.69 -2.49 -4.18 -0.348 0.71309E+04 68 diaspore 2.87 0.44 -2.43 -0.406 0.41557E+04 69 diamond -3.10 -7.57 -4.47 -1.278 0.76349E+04 70 diopside 16.18 15.10 -1.09 -0.109 0.18544E+04 71 hedenbergite 14.21 12.80 -1.41 -0.141 0.23994E+04 78 epidote 24.67 21.51 -3.16 -0.153 0.53873E+04 80 epidote-Fe 29.84 26.33 -3.51 -0.182 0.59981E+04 81 fayalite 14.05 10.22 -3.82 -0.546 0.65253E+04 82 ferrosilite 11.15 7.23 -3.91 -0.391 0.66843E+04 86 gibbsite 4.08 0.44 -3.64 -0.520 0.62142E+04 87 glaucophane 22.97 19.95 -3.02 -0.082 0.51640E+04 88 glaucophane-Fe 17.28 13.07 -4.20 -0.114 0.71749E+04 89 graphite -3.55 -7.57 -4.03 -1.151 0.68771E+04 90 greenalite 16.14 13.84 -2.30 -0.192 0.39238E+04 93 hematite 12.57 10.51 -2.06 -0.250 0.35175E+04 94 heulandite -5.83 -7.87 -2.04 -0.093 0.34899E+04 98 jadeite 4.22 2.61 -1.61 -0.161 0.27485E+04 100 kalsilite 7.58 3.49 -4.10 -0.585 0.69937E+04 101 kaolinite -1.33 -5.10 -3.77 -0.342 0.64309E+04 104 laumontite 2.88 1.10 -1.79 -0.119 0.30500E+04 105 lawsonite 9.62 7.08 -2.54 -0.169 0.43370E+04 106 leucite 4.12 0.50 -3.62 -0.362 0.61816E+04 108 lizardite 23.24 20.72 -2.53 -0.210 0.43125E+04 109 magnesite 0.69 -4.09 -4.78 -1.593 0.81623E+04 110 magnetite 20.09 17.11 -2.97 -0.243 0.50789E+04 111 minnesotaite 10.39 7.86 -2.53 -0.149 0.43122E+04 115 manganosite 14.06 9.20 -4.86 -1.214 0.82940E+04 119 microcline -2.49 -2.49 0.00 0.000 0.75539E+01 123 muscovite 2.58 -1.61 -4.19 -0.247 0.71604E+04 124 paragonite 4.24 0.50 -3.74 -0.220 0.63920E+04 125 nepheline 8.34 5.60 -2.74 -0.392 0.46861E+04 137 phlogopite-Na 29.65 26.31 -3.33 -0.185 0.56920E+04 139 prehnite 19.37 16.26 -3.11 -0.183 0.53105E+04 140 prehnite-Fe 22.50 21.07 -1.42 -0.086 0.24297E+04 145 pyrite -21.25 -22.48 -1.23 -0.289 0.20994E+04 146 pyrrhotite -4.26 -6.58 -2.32 -0.774 0.39627E+04 147 pyrrhotiteFe0.875 -6.02 -7.74 -1.73 -0.635 0.29467E+04 148 pyroxmangite 7.40 6.21 -1.19 -0.237 0.20275E+04 149 pyrophyllite -6.18 -11.08 -4.90 -0.306 0.83703E+04 154 rhodochrosite -0.98 -3.79 -2.81 -0.937 0.48011E+04 155 rhodonite 7.45 6.21 -1.23 -0.247 0.21078E+04 156 sanidine -1.28 -2.49 -1.22 -0.093 0.20753E+04 158 siderite -2.61 -6.38 -3.77 -1.258 0.64438E+04 166 stilbite -7.52 -7.87 -0.35 -0.017 0.59605E+03 168 stilpnomelane-Mg 27.44 24.48 -2.96 -0.088 0.50597E+04 174 talc 16.49 14.74 -1.75 -0.103 0.29911E+04 177 tephroite 18.09 15.41 -2.67 -0.382 0.45656E+04 181 tridymite -2.63 -2.99 -0.36 -0.121 0.61998E+03 182 tremolite 47.87 44.93 -2.94 -0.079 0.50189E+04 183 ferroactinolite 38.45 33.47 -4.98 -0.135 0.85095E+04 184 troilite-low -4.41 -6.58 -2.17 -0.723 0.37055E+04 190 wairakite 3.95 1.10 -2.85 -0.168 0.48719E+04 191 walstromite 11.51 9.19 -2.32 -0.465 0.39674E+04 192 wollastonite 10.46 9.19 -1.28 -0.255 0.21778E+04 193 pseudo-wollastonite 11.00 9.19 -1.81 -0.363 0.30976E+04 195 akaganeite 7.75 5.25 -2.50 -0.541 0.42713E+04 202 chalcedony -2.80 -2.99 -0.19 -0.062 0.31930E+03 204 montmorillonite-Ca -2.29 -6.28 -3.99 -0.247 0.68074E+04 205 montmorillonite-K -2.24 -6.29 -4.06 -0.248 0.69278E+04 206 montmorillonite-Mg -2.48 -6.82 -4.34 -0.268 0.74074E+04 207 montmorillonite-Na -2.04 -5.60 -3.56 -0.218 0.60802E+04 208 nontronite-Ca 3.21 1.69 -1.53 -0.099 0.26049E+04 209 nontronite-H 2.53 -0.32 -2.85 -0.191 0.48708E+04 210 nontronite-K 3.34 1.67 -1.67 -0.107 0.28486E+04 211 nontronite-Mg 3.07 1.15 -1.93 -0.125 0.32890E+04 212 nontronite-Na 3.52 2.37 -1.15 -0.074 0.19669E+04 228 tobermorite 9.82 7.15 -2.67 -0.729 0.45600E+04 234 alabandite -0.98 -3.99 -3.01 -1.003 0.51384E+04 237 boehmite 4.41 0.44 -3.97 -0.661 0.67726E+04 239 ferrous-oxide 9.81 6.61 -3.20 -0.801 0.54721E+04 245 silica-amorphous -2.09 -2.99 -0.90 -0.299 0.15335E+04 247 an20ab80 2.02 1.11 -0.91 -0.070 0.15532E+04 248 an25ab75 2.65 1.48 -1.16 -0.090 0.19885E+04 249 an30ab70 3.28 1.85 -1.43 -0.110 0.24334E+04 250 tr.625ac.25prg.125 45.16 42.88 -2.28 -0.061 0.38967E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 0.0010000 MOLES Current total amount of reactant added: 0.0279900 MOLES New total amount of reactant added: 0.0289900 MOLES Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.5508E-08 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 7 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 0.0289900 Water: Moles liquid = 0.4988E+02 kg liquid = 0.8985E+00 Moles total = 0.4987E+02 kg total = 0.8984E+00 Activity = 1.0000 Stoichiometric ionic strength = .1319745E-01 Osmotic coef. = 0.9362 True ionic strength = .2165684E-01 Chg. balance for total moles = -.5508E-08 Max. difference allowed = 0.3089E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.14430E-09 -9.8407 0.12066E-09 -9.9184 0.83615E+00 -0.0777 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.34223E-03 -3.4657 0.28433E-03 -3.5462 0.83081E+00 -0.0805 4 SO4-- 0.13726E-03 -3.8624 0.69821E-04 -4.1560 0.50866E+00 -0.2936 5 HCO3- 0.10731E-02 -2.9694 0.89292E-03 -3.0492 0.83210E+00 -0.0798 6 HS- 0.67473E-03 -3.1709 0.56066E-03 -3.2513 0.83094E+00 -0.0804 7 Al+++ 0.22144E-28 -28.6548 0.48783E-29 -29.3117 0.22030E+00 -0.6570 8 H4SiO4 0.10246E-02 -2.9894 0.10246E-02 -2.9894 0.10000E+01 0.0000 9 Ca++ 0.41475E-07 -7.3822 0.20932E-07 -7.6792 0.50468E+00 -0.2970 10 Mg++ 0.22483E-10 -10.6482 0.11291E-10 -10.9473 0.50223E+00 -0.2991 11 Fe++ 0.11679E-12 -12.9326 0.58724E-13 -13.2312 0.50281E+00 -0.2986 12 K+ 0.15654E-03 -3.8054 0.13029E-03 -3.8851 0.83231E+00 -0.0797 13 Na+ 0.20089E-01 -1.6970 0.16687E-01 -1.7776 0.83065E+00 -0.0806 14 Mn++ 0.45802E-10 -10.3391 0.23050E-10 -10.6373 0.50326E+00 -0.2982 15 F- 0.12975E-04 -4.8869 0.10756E-04 -4.9684 0.82899E+00 -0.0814 16 HPO4-- 0.45656E-07 -7.3405 0.23227E-07 -7.6340 0.50874E+00 -0.2935 18 HSiO3- 0.95442E-02 -2.0203 0.79294E-02 -2.1008 0.83081E+00 -0.0805 19 Ca(HSiO3)+ 0.45405E-08 -8.3429 0.37799E-08 -8.4225 0.83250E+00 -0.0796 20 Mg(HSiO3)+ 0.30482E-11 -11.5160 0.25376E-11 -11.5956 0.83250E+00 -0.0796 21 NaHSiO3,aq 0.21401E-02 -2.6696 0.21401E-02 -2.6696 0.10000E+01 0.0000 22 AlO+ 0.54759E-16 -16.2615 0.45587E-16 -16.3412 0.83250E+00 -0.0796 24 HAlO2,aq 0.75243E-10 -10.1235 0.75243E-10 -10.1235 0.10000E+01 0.0000 25 AlO2- 0.16647E-05 -5.7787 0.13804E-05 -5.8600 0.82922E+00 -0.0813 26 CH4,aq 0.69930E-08 -8.1553 0.69650E-08 -8.1571 0.99599E+00 -0.0017 27 C2H6,aq 0.43022E-19 -19.3663 0.42849E-19 -19.3681 0.99599E+00 -0.0017 31 CO,aq 0.11193E-14 -14.9511 0.11193E-14 -14.9511 0.10000E+01 0.0000 32 CO2,aq 0.23114E-06 -6.6361 0.23021E-06 -6.6379 0.99599E+00 -0.0017 33 CO3-2 0.12737E-02 -2.8949 0.64640E-03 -3.1895 0.50751E+00 -0.2946 34 CaCO3,aq 0.16966E-06 -6.7704 0.16966E-06 -6.7704 0.10000E+01 0.0000 35 Ca(HCO3)+ 0.57309E-09 -9.2418 0.47710E-09 -9.3214 0.83250E+00 -0.0796 36 CaCl+ 0.11569E-10 -10.9367 0.96315E-11 -11.0163 0.83250E+00 -0.0796 37 CaCl2,aq 0.65061E-15 -15.1867 0.65061E-15 -15.1867 0.10000E+01 0.0000 38 CaF+ 0.39484E-11 -11.4036 0.32871E-11 -11.4832 0.83250E+00 -0.0796 39 CaOH+ 0.14852E-07 -7.8282 0.12364E-07 -7.9078 0.83250E+00 -0.0796 40 CaSO4,aq 0.46409E-09 -9.3334 0.46409E-09 -9.3334 0.10000E+01 0.0000 41 HCl,aq 0.62865E-14 -14.2016 0.62865E-14 -14.2016 0.10000E+01 0.0000 45 HF,aq 0.88841E-11 -11.0514 0.88841E-11 -11.0514 0.10000E+01 0.0000 46 HF2- 0.38832E-16 -16.4108 0.32262E-16 -16.4913 0.83081E+00 -0.0805 48 FeCl+ 0.31746E-16 -16.4983 0.26428E-16 -16.5779 0.83250E+00 -0.0796 51 FeF+ 0.38771E-16 -16.4115 0.32277E-16 -16.4911 0.83250E+00 -0.0796 53 FeO,aq 0.15677E-09 -9.8047 0.15677E-09 -9.8047 0.10000E+01 0.0000 54 FeOH+ 0.19030E-10 -10.7206 0.15843E-10 -10.8002 0.83250E+00 -0.0796 55 HFeO2- 0.16364E-07 -7.7861 0.13595E-07 -7.8666 0.83081E+00 -0.0805 56 FeO+ 0.10318E-15 -15.9864 0.85894E-16 -16.0660 0.83250E+00 -0.0796 58 FeO2- 0.14531E-08 -8.8377 0.12073E-08 -8.9182 0.83081E+00 -0.0805 59 HFeO2,aq 0.18527E-10 -10.7322 0.18527E-10 -10.7322 0.10000E+01 0.0000 60 H2,aq 0.19432E-06 -6.7115 0.19354E-06 -6.7132 0.99599E+00 -0.0017 61 KCl,aq 0.67142E-09 -9.1730 0.67142E-09 -9.1730 0.10000E+01 0.0000 62 KHSO4,aq 0.31034E-17 -17.5082 0.31034E-17 -17.5082 0.10000E+01 0.0000 63 KOH,aq 0.46116E-06 -6.3362 0.46116E-06 -6.3362 0.10000E+01 0.0000 64 KSO4- 0.16991E-06 -6.7698 0.14116E-06 -6.8503 0.83081E+00 -0.0805 65 MgCO3,aq 0.22940E-10 -10.6394 0.22940E-10 -10.6394 0.10000E+01 0.0000 66 Mg(HCO3)+ 0.31589E-12 -12.5005 0.26298E-12 -12.5801 0.83250E+00 -0.0796 67 MgCl+ 0.56564E-14 -14.2475 0.47090E-14 -14.3271 0.83250E+00 -0.0796 68 MgF+ 0.78898E-14 -14.1029 0.65683E-14 -14.1825 0.83250E+00 -0.0796 69 MgOH+ 0.44332E-10 -10.3533 0.36906E-10 -10.4329 0.83250E+00 -0.0796 71 MnF+ 0.50161E-14 -14.2996 0.41759E-14 -14.3793 0.83250E+00 -0.0796 72 MnO,aq 0.16397E-08 -8.7852 0.16397E-08 -8.7852 0.10000E+01 0.0000 73 MnOH+ 0.69390E-09 -9.1587 0.57768E-09 -9.2383 0.83250E+00 -0.0796 74 MnO2-2 0.73651E-11 -11.1328 0.37379E-11 -11.4274 0.50751E+00 -0.2946 75 HMnO2- 0.11893E-09 -9.9247 0.98807E-10 -10.0052 0.83081E+00 -0.0805 78 MnCl+ 0.48478E-13 -13.3145 0.40358E-13 -13.3941 0.83250E+00 -0.0796 79 MnSO4,aq 0.46461E-12 -12.3329 0.46461E-12 -12.3329 0.10000E+01 0.0000 80 NaCl,aq 0.15724E-05 -5.8034 0.15724E-05 -5.8034 0.10000E+01 0.0000 81 NaF,aq 0.42020E-07 -7.3765 0.42020E-07 -7.3765 0.10000E+01 0.0000 82 NaOH,aq 0.59421E-04 -4.2261 0.59421E-04 -4.2261 0.10000E+01 0.0000 84 OH- 0.57748E-02 -2.2385 0.47886E-02 -2.3198 0.82922E+00 -0.0813 89 HPO3-2 0.27604E-16 -16.5590 0.14009E-16 -16.8536 0.50751E+00 -0.2946 92 H3PO4,aq 0.23649E-17 -17.6262 0.23649E-17 -17.6262 0.10000E+01 0.0000 93 H2PO4- 0.62164E-10 -10.2065 0.51698E-10 -10.2865 0.83165E+00 -0.0801 94 PO4-3 0.67669E-09 -9.1696 0.15706E-09 -9.8039 0.23210E+00 -0.6343 98 HP2O7-3 0.15726E-17 -17.8034 0.34682E-18 -18.4599 0.22054E+00 -0.6565 99 P2O7-4 0.96735E-17 -17.0144 0.68668E-18 -18.1632 0.70986E-01 -1.1488 100 H2S,aq 0.20992E-06 -6.6780 0.20907E-06 -6.6797 0.99599E+00 -0.0017 101 S2-2 0.70911E-10 -10.1493 0.35988E-10 -10.4438 0.50751E+00 -0.2946 102 S3-2 0.10320E-15 -15.9863 0.52377E-16 -16.2809 0.50751E+00 -0.2946 103 S3- 0.11590E-19 -19.9359 0.96291E-20 -20.0164 0.83081E+00 -0.0805 107 SO3-2 0.34077E-11 -11.4675 0.17560E-11 -11.7555 0.51532E+00 -0.2879 108 HSO3- 0.15968E-13 -13.7968 0.13266E-13 -13.8773 0.83081E+00 -0.0805 109 HSO4- 0.97421E-11 -11.0113 0.81187E-11 -11.0905 0.83336E+00 -0.0792 111 S2O3-2 0.33788E-12 -12.4712 0.17148E-12 -12.7658 0.50751E+00 -0.2946 Charge balance for all species = -.6129E-08 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.1442998E-09 -.1879909E-01 -.1891422E+02 0.0000 2 H2O 0.1000000E+01 0.5550240E+02 0.9980910E+06 0.0000 3 Cl- 0.3422316E-03 0.3438047E-03 0.1216695E+02 6.3723 4 SO4-- 0.1372645E-03 0.1373795E-03 0.1317312E+02 15.6809 5 HCO3- 0.1073089E-02 0.2347171E-02 0.1429598E+03 6.8693 6 HS- 0.6747335E-03 0.6749989E-03 0.2228335E+02 6.6671 7 Al+++ 0.2214369E-28 0.1664789E-05 0.4483758E-01 0.4436 8 H4SiO4 0.1024625E-02 0.1270884E-01 0.1219315E+04 -2.9894 9 Ca++ 0.4147536E-07 0.2315774E-06 0.9264437E-02 12.1577 10 Mg++ 0.2248257E-10 0.9313162E-10 0.2260137E-05 8.8896 11 Fe++ 0.1167900E-12 0.1801125E-07 0.1004062E-02 6.6057 12 K+ 0.1565415E-03 0.1571732E-03 0.6134715E+01 6.0334 13 Na+ 0.2008917E-01 0.2229026E-01 0.5115253E+03 8.1408 14 Mn++ 0.4580165E-10 0.2506196E-08 0.1374374E-03 9.1996 15 F- 0.1297452E-04 0.1301655E-04 0.2468429E+00 4.9501 16 HPO4-- 0.4565618E-07 0.4639503E-07 0.4444927E-02 12.2029 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.1690504E-01 -.1689190E-01 -.1314573E-04 0.0000000E+00 2 H2O 0.4987014E+02 0.4987160E+02 -.1460424E-02 0.0000000E+00 3 Cl- 0.3089252E-03 0.3089252E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.1234422E-03 0.1234422E-03 0.0000000E+00 0.0000000E+00 5 HCO3- 0.2109047E-02 0.2109047E-02 0.0000000E+00 0.0000000E+00 6 HS- 0.6065193E-03 0.6065193E-03 0.0000000E+00 0.0000000E+00 7 Al+++ 0.4775352E-05 0.1495894E-05 0.3279458E-05 0.0000000E+00 8 H4SiO4 0.1215302E-01 0.1141951E-01 0.7335085E-03 0.0000000E+00 9 Ca++ 0.2080835E-06 0.2080835E-06 0.0000000E+00 0.0000000E+00 10 Mg++ 0.8368328E-10 0.8368328E-10 0.0000000E+00 0.0000000E+00 11 Fe++ 0.3259227E-07 0.1618399E-07 0.1640828E-07 0.0000000E+00 12 K+ 0.1412294E-03 0.1412278E-03 0.1640828E-08 0.0000000E+00 13 Na+ 0.2003215E-01 0.2002888E-01 0.3272895E-05 0.0000000E+00 14 Mn++ 0.2251939E-08 0.2251939E-08 0.0000000E+00 0.0000000E+00 15 F- 0.1169600E-04 0.1169600E-04 0.0000000E+00 0.0000000E+00 16 HPO4-- 0.4168819E-07 0.4168819E-07 0.0000000E+00 0.0000000E+00 Chg. balance for solid moles: 0.4235E-21 Mass of aqueous solution: 0.900170E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 0.0289900 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 0.3273E-05 -5.485 0.8582E-03 -3.066 1.936 0.3295E-03 quartz 0.7237E-03 -3.140 0.4348E-01 -1.362 98.06 0.1642E-01 stilpnomelane-Fe 0.3282E-08 -8.484 0.3538E-05 -5.451 0.7978E-02 0.1222E-05 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 quartz 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 0.044339 g Volume = 0.016750 cm3 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.0289900 moles log = -1.5378 Original solution: 1000.0103000 g Original solution / Rock added: 34495.01 (Water/Rock Ratio), log = 4.5378 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0206 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9997E+00 0.9859 0.1006E+01 0.1020E+01 CO2,gas 0.2396E-04 1.0071 0.2463E-04 0.2446E-04 CH4,gas 0.9921E-05 1.0125 0.1025E-04 0.1013E-04 H2,gas 0.2488E-03 1.0005 0.2541E-03 0.2540E-03 H2S,gas 0.5654E-05 0.9960 0.5747E-05 0.5770E-05 S2,gas 0.1882E-22 1.0000 0.1920E-22 0.1920E-22 CO,gas 0.1634E-11 1.0000 0.1668E-11 0.1668E-11 SO3,gas 0.3766E-39 1.0000 0.3843E-39 0.3843E-39 SO2,gas 0.3723E-20 1.0000 0.3799E-20 0.3799E-20 HF,gas 0.2137E-13 1.0000 0.2181E-13 0.2181E-13 HCl,gas 0.1087E-16 1.0000 0.1109E-16 0.1109E-16 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 17 albite -0.38 -0.38 0.00 0.000 -0.13080E-10 150 quartz -2.99 -2.99 0.00 0.000 0.00000E+00 167 stilpnomelane-Fe 13.02 13.02 0.00 0.000 0.21232E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -12.97 -6.31 -2.103 0.10770E+05 -4.609 3 CH4,gas 4.54 -2.14 -6.69 -1.672 0.11420E+05 -4.989 4 H2,gas 8.00 2.71 -5.29 -3.025 0.90393E+04 -3.595 5 H2S,gas -6.23 -13.17 -6.94 -3.470 0.11849E+05 -5.241 6 S2,gas -7.34 -31.75 -24.42 -3.756 0.41689E+05 -22.717 7 CO,gas 3.21 -10.26 -13.48 -4.147 0.23011E+05 -11.778 8 SO3,gas 17.12 -23.99 -41.11 -10.279 0.70201E+05 -39.415 9 SO2,gas 0.83 -21.29 -22.12 -5.898 0.37768E+05 -20.420 10 HF,gas 0.47 -14.89 -15.36 -7.680 0.26227E+05 -13.661 11 HCl,gas 5.19 -13.46 -18.65 -9.327 0.31851E+05 -16.955 12 acmite 7.71 7.41 -0.29 -0.031 0.50361E+03 16 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 20 spessartine 24.46 19.52 -4.94 -0.247 0.84344E+04 21 analcite 3.32 2.61 -0.72 -0.080 0.12231E+04 23 andradite 39.01 38.01 -1.00 -0.052 0.17046E+04 24 grossular 32.73 28.39 -4.34 -0.217 0.74094E+04 27 annite 20.12 17.33 -2.80 -0.155 0.47768E+04 28 phlogopite 27.06 24.18 -2.89 -0.160 0.49295E+04 33 apatite-OH -18.15 -21.62 -3.47 -0.267 0.59261E+04 34 apatite-F -34.30 -36.51 -2.21 -0.184 0.37735E+04 38 aragonite 0.97 -0.81 -1.78 -0.592 0.30332E+04 39 brucite 12.57 8.89 -3.68 -0.736 0.62817E+04 40 calcite 0.81 -0.81 -1.62 -0.541 0.27690E+04 41 carnegieite-low 9.02 5.60 -3.43 -0.490 0.58537E+04 42 carnegieite-high 10.09 5.60 -4.50 -0.643 0.76807E+04 43 carpholite-Mg 8.58 3.80 -4.78 -0.319 0.81687E+04 45 celadonite 5.34 3.41 -1.93 -0.114 0.33001E+04 46 celadonite-Fe 3.88 1.12 -2.75 -0.162 0.46982E+04 47 chrysotile 23.89 20.69 -3.20 -0.267 0.54679E+04 49 clinochlore 39.07 36.37 -2.70 -0.084 0.46142E+04 50 daphnite 28.97 24.95 -4.02 -0.126 0.68602E+04 54 chloritoid-Fe 9.17 4.50 -4.67 -0.311 0.79741E+04 55 chloritoid-Mn 11.40 7.10 -4.30 -0.287 0.73485E+04 57 coesite -2.38 -2.99 -0.61 -0.204 0.10473E+04 64 cristobalite -2.56 -2.99 -0.43 -0.143 0.73267E+03 66 cymrite-K 1.69 -2.49 -4.18 -0.348 0.71316E+04 68 diaspore 2.87 0.44 -2.43 -0.405 0.41493E+04 69 diamond -3.10 -7.56 -4.45 -1.272 0.76045E+04 70 diopside 16.18 15.07 -1.11 -0.111 0.19002E+04 71 hedenbergite 14.21 12.78 -1.42 -0.142 0.24310E+04 78 epidote 24.67 21.49 -3.18 -0.154 0.54345E+04 80 epidote-Fe 29.84 26.30 -3.54 -0.184 0.60521E+04 81 fayalite 14.05 10.22 -3.82 -0.546 0.65289E+04 82 ferrosilite 11.15 7.23 -3.92 -0.392 0.66880E+04 86 gibbsite 4.08 0.44 -3.64 -0.519 0.62079E+04 87 glaucophane 22.97 19.92 -3.05 -0.082 0.52120E+04 88 glaucophane-Fe 17.28 13.07 -4.21 -0.114 0.71804E+04 89 graphite -3.55 -7.56 -4.01 -1.146 0.68468E+04 90 greenalite 16.14 13.84 -2.30 -0.192 0.39293E+04 93 hematite 12.57 10.51 -2.06 -0.250 0.35183E+04 94 heulandite -5.83 -7.88 -2.05 -0.093 0.35069E+04 98 jadeite 4.22 2.61 -1.61 -0.161 0.27485E+04 100 kalsilite 7.58 3.49 -4.10 -0.585 0.69944E+04 101 kaolinite -1.33 -5.09 -3.76 -0.342 0.64182E+04 104 laumontite 2.88 1.09 -1.80 -0.120 0.30670E+04 105 lawsonite 9.62 7.07 -2.55 -0.170 0.43541E+04 106 leucite 4.12 0.50 -3.62 -0.362 0.61823E+04 108 lizardite 23.24 20.69 -2.55 -0.213 0.43605E+04 109 magnesite 0.69 -4.08 -4.77 -1.590 0.81422E+04 110 magnetite 20.09 17.11 -2.98 -0.243 0.50815E+04 111 minnesotaite 10.39 7.86 -2.53 -0.149 0.43177E+04 115 manganosite 14.06 9.20 -4.86 -1.215 0.82958E+04 119 microcline -2.49 -2.49 0.00 0.000 0.82567E+01 123 muscovite 2.58 -1.60 -4.19 -0.246 0.71484E+04 124 paragonite 4.24 0.50 -3.74 -0.220 0.63792E+04 125 nepheline 8.34 5.60 -2.74 -0.392 0.46861E+04 137 phlogopite-Na 29.65 26.29 -3.36 -0.187 0.57400E+04 139 prehnite 19.37 16.23 -3.14 -0.185 0.53573E+04 140 prehnite-Fe 22.50 21.04 -1.45 -0.087 0.24832E+04 145 pyrite -21.25 -22.44 -1.19 -0.281 0.20364E+04 146 pyrrhotite -4.26 -6.56 -2.30 -0.768 0.39335E+04 147 pyrrhotiteFe0.875 -6.02 -7.73 -1.71 -0.628 0.29169E+04 148 pyroxmangite 7.40 6.21 -1.19 -0.238 0.20294E+04 149 pyrophyllite -6.18 -11.07 -4.89 -0.306 0.83576E+04 154 rhodochrosite -0.98 -3.77 -2.79 -0.931 0.47668E+04 155 rhodonite 7.45 6.21 -1.24 -0.247 0.21097E+04 156 sanidine -1.28 -2.49 -1.22 -0.094 0.20760E+04 158 siderite -2.61 -6.36 -3.75 -1.251 0.64095E+04 166 stilbite -7.52 -7.88 -0.36 -0.017 0.61309E+03 168 stilpnomelane-Mg 27.44 24.44 -3.00 -0.090 0.51305E+04 174 talc 16.49 14.71 -1.78 -0.105 0.30391E+04 177 tephroite 18.09 15.41 -2.68 -0.382 0.45694E+04 181 tridymite -2.63 -2.99 -0.36 -0.121 0.61998E+03 182 tremolite 47.87 44.85 -3.02 -0.082 0.51585E+04 184 troilite-low -4.41 -6.56 -2.15 -0.718 0.36763E+04 190 wairakite 3.95 1.09 -2.86 -0.168 0.48890E+04 191 walstromite 11.51 9.17 -2.34 -0.468 0.39971E+04 192 wollastonite 10.46 9.17 -1.29 -0.259 0.22076E+04 193 pseudo-wollastonite 11.00 9.17 -1.83 -0.366 0.31274E+04 195 akaganeite 7.75 5.25 -2.50 -0.541 0.42717E+04 202 chalcedony -2.80 -2.99 -0.19 -0.062 0.31930E+03 204 montmorillonite-Ca -2.29 -6.28 -3.99 -0.247 0.68070E+04 205 montmorillonite-K -2.24 -6.29 -4.06 -0.248 0.69248E+04 206 montmorillonite-Mg -2.48 -6.82 -4.34 -0.268 0.74047E+04 207 montmorillonite-Na -2.04 -5.60 -3.56 -0.218 0.60770E+04 208 nontronite-Ca 3.21 1.69 -1.53 -0.099 0.26086E+04 209 nontronite-H 2.53 -0.32 -2.85 -0.191 0.48696E+04 210 nontronite-K 3.34 1.67 -1.67 -0.107 0.28496E+04 211 nontronite-Mg 3.07 1.15 -1.93 -0.125 0.32904E+04 212 nontronite-Na 3.52 2.37 -1.15 -0.074 0.19677E+04 228 tobermorite 9.82 7.14 -2.69 -0.733 0.45848E+04 234 alabandite -0.98 -3.97 -2.99 -0.997 0.51093E+04 237 boehmite 4.41 0.44 -3.96 -0.660 0.67662E+04 239 ferrous-oxide 9.81 6.61 -3.21 -0.801 0.54739E+04 245 silica-amorphous -2.09 -2.99 -0.90 -0.299 0.15335E+04 247 an20ab80 2.02 1.11 -0.91 -0.070 0.15566E+04 248 an25ab75 2.65 1.48 -1.17 -0.090 0.19928E+04 249 an30ab70 3.28 1.85 -1.43 -0.110 0.24385E+04 250 tr.625ac.25prg.125 45.16 42.81 -2.35 -0.063 0.40150E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 0.0010000 MOLES Current total amount of reactant added: 0.0289900 MOLES New total amount of reactant added: 0.0299900 MOLES Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.5508E-08 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 7 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 0.0299900 Water: Moles liquid = 0.4988E+02 kg liquid = 0.8986E+00 Moles total = 0.4987E+02 kg total = 0.8984E+00 Activity = 1.0000 Stoichiometric ionic strength = .1326241E-01 Osmotic coef. = 0.9358 True ionic strength = .2171893E-01 Chg. balance for total moles = -.5508E-08 Max. difference allowed = 0.3148E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.14568E-09 -9.8366 0.12179E-09 -9.9144 0.83600E+00 -0.0778 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.34876E-03 -3.4575 0.28970E-03 -3.5381 0.83065E+00 -0.0806 4 SO4-- 0.14257E-03 -3.8460 0.72464E-04 -4.1399 0.50827E+00 -0.2939 5 HCO3- 0.11151E-02 -2.9527 0.92773E-03 -3.0326 0.83194E+00 -0.0799 6 HS- 0.69644E-03 -3.1571 0.57859E-03 -3.2376 0.83078E+00 -0.0805 7 Al+++ 0.23011E-28 -28.6381 0.50606E-29 -29.2958 0.21992E+00 -0.6577 8 H4SiO4 0.10246E-02 -2.9894 0.10246E-02 -2.9894 0.10000E+01 0.0000 9 Ca++ 0.40652E-07 -7.3909 0.20500E-07 -7.6882 0.50429E+00 -0.2973 10 Mg++ 0.22435E-10 -10.6491 0.11258E-10 -10.9485 0.50183E+00 -0.2994 11 Fe++ 0.11879E-12 -12.9252 0.59683E-13 -13.2241 0.50242E+00 -0.2989 12 K+ 0.15654E-03 -3.8054 0.13026E-03 -3.8852 0.83215E+00 -0.0798 13 Na+ 0.20108E-01 -1.6966 0.16699E-01 -1.7773 0.83048E+00 -0.0807 14 Mn++ 0.46584E-10 -10.3318 0.23425E-10 -10.6303 0.50286E+00 -0.2986 15 F- 0.13418E-04 -4.8723 0.11121E-04 -4.9538 0.82883E+00 -0.0815 16 HPO4-- 0.45660E-07 -7.3405 0.23211E-07 -7.6343 0.50835E+00 -0.2938 18 HSiO3- 0.94572E-02 -2.0242 0.78556E-02 -2.1048 0.83065E+00 -0.0806 19 Ca(HSiO3)+ 0.44063E-08 -8.3559 0.36675E-08 -8.4356 0.83234E+00 -0.0797 20 Mg(HSiO3)+ 0.30115E-11 -11.5212 0.25066E-11 -11.6009 0.83234E+00 -0.0797 21 NaHSiO3,aq 0.21217E-02 -2.6733 0.21217E-02 -2.6733 0.10000E+01 0.0000 22 AlO+ 0.55763E-16 -16.2537 0.46414E-16 -16.3334 0.83234E+00 -0.0797 24 HAlO2,aq 0.75895E-10 -10.1198 0.75895E-10 -10.1198 0.10000E+01 0.0000 25 AlO2- 0.16638E-05 -5.7789 0.13794E-05 -5.8603 0.82905E+00 -0.0814 26 CH4,aq 0.72246E-08 -8.1412 0.71955E-08 -8.1429 0.99597E+00 -0.0018 27 C2H6,aq 0.46091E-19 -19.3364 0.45905E-19 -19.3381 0.99597E+00 -0.0018 31 CO,aq 0.11694E-14 -14.9320 0.11694E-14 -14.9320 0.10000E+01 0.0000 32 CO2,aq 0.24241E-06 -6.6155 0.24143E-06 -6.6172 0.99597E+00 -0.0018 33 CO3-2 0.13120E-02 -2.8821 0.66536E-03 -3.1769 0.50712E+00 -0.2949 34 CaCO3,aq 0.17103E-06 -6.7669 0.17103E-06 -6.7669 0.10000E+01 0.0000 35 Ca(HCO3)+ 0.58327E-09 -9.2341 0.48548E-09 -9.3138 0.83234E+00 -0.0797 36 CaCl+ 0.11547E-10 -10.9375 0.96110E-11 -11.0172 0.83234E+00 -0.0797 37 CaCl2,aq 0.66149E-15 -15.1795 0.66149E-15 -15.1795 0.10000E+01 0.0000 38 CaF+ 0.39991E-11 -11.3980 0.33287E-11 -11.4777 0.83234E+00 -0.0797 39 CaOH+ 0.14413E-07 -7.8412 0.11996E-07 -7.9209 0.83234E+00 -0.0797 40 CaSO4,aq 0.47173E-09 -9.3263 0.47173E-09 -9.3263 0.10000E+01 0.0000 41 HCl,aq 0.64653E-14 -14.1894 0.64653E-14 -14.1894 0.10000E+01 0.0000 45 HF,aq 0.92722E-11 -11.0328 0.92722E-11 -11.0328 0.10000E+01 0.0000 46 HF2- 0.41913E-16 -16.3776 0.34815E-16 -16.4582 0.83065E+00 -0.0806 48 FeCl+ 0.32880E-16 -16.4831 0.27367E-16 -16.5628 0.83234E+00 -0.0797 51 FeF+ 0.40751E-16 -16.3899 0.33919E-16 -16.4696 0.83234E+00 -0.0797 53 FeO,aq 0.15638E-09 -9.8058 0.15638E-09 -9.8058 0.10000E+01 0.0000 54 FeOH+ 0.19165E-10 -10.7175 0.15952E-10 -10.7972 0.83234E+00 -0.0797 55 HFeO2- 0.16174E-07 -7.7912 0.13435E-07 -7.8718 0.83065E+00 -0.0806 56 FeO+ 0.10410E-15 -15.9825 0.86648E-16 -16.0622 0.83234E+00 -0.0797 58 FeO2- 0.14390E-08 -8.8419 0.11953E-08 -8.9225 0.83065E+00 -0.0806 59 HFeO2,aq 0.18515E-10 -10.7325 0.18515E-10 -10.7325 0.10000E+01 0.0000 60 H2,aq 0.19360E-06 -6.7131 0.19282E-06 -6.7149 0.99597E+00 -0.0018 61 KCl,aq 0.68394E-09 -9.1650 0.68394E-09 -9.1650 0.10000E+01 0.0000 62 KHSO4,aq 0.32504E-17 -17.4881 0.32504E-17 -17.4881 0.10000E+01 0.0000 63 KOH,aq 0.45676E-06 -6.3403 0.45676E-06 -6.3403 0.10000E+01 0.0000 64 KSO4- 0.17634E-06 -6.7537 0.14648E-06 -6.8342 0.83065E+00 -0.0806 65 MgCO3,aq 0.23543E-10 -10.6281 0.23543E-10 -10.6281 0.10000E+01 0.0000 66 Mg(HCO3)+ 0.32731E-12 -12.4850 0.27243E-12 -12.5647 0.83234E+00 -0.0797 67 MgCl+ 0.57474E-14 -14.2405 0.47838E-14 -14.3202 0.83234E+00 -0.0797 68 MgF+ 0.81356E-14 -14.0896 0.67716E-14 -14.1693 0.83234E+00 -0.0797 69 MgOH+ 0.43799E-10 -10.3585 0.36456E-10 -10.4382 0.83234E+00 -0.0797 71 MnF+ 0.52719E-14 -14.2780 0.43880E-14 -14.3577 0.83234E+00 -0.0797 72 MnO,aq 0.16355E-08 -8.7864 0.16355E-08 -8.7864 0.10000E+01 0.0000 73 MnOH+ 0.69877E-09 -9.1557 0.58161E-09 -9.2354 0.83234E+00 -0.0797 74 MnO2-2 0.72157E-11 -11.1417 0.36592E-11 -11.4366 0.50712E+00 -0.2949 75 HMnO2- 0.11754E-09 -9.9298 0.97637E-10 -10.0104 0.83065E+00 -0.0806 78 MnCl+ 0.50207E-13 -13.2992 0.41789E-13 -13.3789 0.83234E+00 -0.0797 79 MnSO4,aq 0.49005E-12 -12.3098 0.49005E-12 -12.3098 0.10000E+01 0.0000 80 NaCl,aq 0.16032E-05 -5.7950 0.16032E-05 -5.7950 0.10000E+01 0.0000 81 NaF,aq 0.43479E-07 -7.3617 0.43479E-07 -7.3617 0.10000E+01 0.0000 82 NaOH,aq 0.58910E-04 -4.2298 0.58910E-04 -4.2298 0.10000E+01 0.0000 84 OH- 0.57222E-02 -2.2424 0.47440E-02 -2.3239 0.82905E+00 -0.0814 89 HPO3-2 0.27503E-16 -16.5606 0.13947E-16 -16.8555 0.50712E+00 -0.2949 92 H3PO4,aq 0.24080E-17 -17.6183 0.24080E-17 -17.6183 0.10000E+01 0.0000 93 H2PO4- 0.62718E-10 -10.2026 0.52149E-10 -10.2828 0.83149E+00 -0.0801 94 PO4-3 0.67104E-09 -9.1733 0.15550E-09 -9.8083 0.23172E+00 -0.6350 98 HP2O7-3 0.15880E-17 -17.7992 0.34961E-18 -18.4564 0.22016E+00 -0.6573 99 P2O7-4 0.96900E-17 -17.0137 0.68576E-18 -18.1638 0.70770E-01 -1.1501 100 H2S,aq 0.21867E-06 -6.6602 0.21779E-06 -6.6620 0.99597E+00 -0.0018 101 S2-2 0.75861E-10 -10.1200 0.38471E-10 -10.4149 0.50712E+00 -0.2949 102 S3-2 0.11544E-15 -15.9376 0.58542E-16 -16.2325 0.50712E+00 -0.2949 103 S3- 0.13103E-19 -19.8826 0.10884E-19 -19.9632 0.83065E+00 -0.0806 107 SO3-2 0.35260E-11 -11.4527 0.18157E-11 -11.7410 0.51494E+00 -0.2882 108 HSO3- 0.16668E-13 -13.7781 0.13846E-13 -13.8587 0.83065E+00 -0.0806 109 HSO4- 0.10208E-10 -10.9911 0.85052E-11 -11.0703 0.83321E+00 -0.0792 111 S2O3-2 0.36556E-12 -12.4370 0.18538E-12 -12.7319 0.50712E+00 -0.2949 Charge balance for all species = -.6129E-08 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.1456818E-09 -.1867890E-01 -.1879334E+02 0.0000 2 H2O 0.1000000E+01 0.5550246E+02 0.9980947E+06 0.0000 3 Cl- 0.3487602E-03 0.3503641E-03 0.1239911E+02 6.3763 4 SO4-- 0.1425695E-03 0.1426909E-03 0.1368246E+02 15.6889 5 HCO3- 0.1115142E-02 0.2427587E-02 0.1478581E+03 6.8818 6 HS- 0.6964407E-03 0.6967150E-03 0.2300031E+02 6.6768 7 Al+++ 0.2301142E-28 0.1663918E-05 0.4481423E-01 0.4474 8 H4SiO4 0.1024625E-02 0.1260345E-01 0.1209207E+04 -2.9894 9 Ca++ 0.4065207E-07 0.2315729E-06 0.9264283E-02 12.1405 10 Mg++ 0.2243467E-10 0.9312983E-10 0.2260099E-05 8.8802 11 Fe++ 0.1187924E-12 0.1780730E-07 0.9926951E-03 6.6046 12 K+ 0.1565364E-03 0.1571702E-03 0.6134612E+01 6.0292 13 Na+ 0.2010760E-01 0.2228983E-01 0.5115168E+03 8.1371 14 Mn++ 0.4658389E-10 0.2506148E-08 0.1374351E-03 9.1985 15 F- 0.1341796E-04 0.1346145E-04 0.2552806E+00 4.9605 16 HPO4-- 0.4566039E-07 0.4639414E-07 0.4444853E-02 12.1945 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.1679737E-01 -.1678422E-01 -.1314905E-04 0.0000000E+00 2 H2O 0.4987096E+02 0.4987261E+02 -.1649382E-02 0.0000000E+00 3 Cl- 0.3148252E-03 0.3148252E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.1282172E-03 0.1282172E-03 0.0000000E+00 0.0000000E+00 5 HCO3- 0.2181347E-02 0.2181347E-02 0.0000000E+00 0.0000000E+00 6 HS- 0.6260443E-03 0.6260443E-03 0.0000000E+00 0.0000000E+00 7 Al+++ 0.4775352E-05 0.1495140E-05 0.3280212E-05 0.0000000E+00 8 H4SiO4 0.1215302E-01 0.1132503E-01 0.8279888E-03 0.0000000E+00 9 Ca++ 0.2080835E-06 0.2080835E-06 0.0000000E+00 0.0000000E+00 10 Mg++ 0.8368328E-10 0.8368328E-10 0.0000000E+00 0.0000000E+00 11 Fe++ 0.3259227E-07 0.1600103E-07 0.1659124E-07 0.0000000E+00 12 K+ 0.1412294E-03 0.1412277E-03 0.1659124E-08 0.0000000E+00 13 Na+ 0.2003215E-01 0.2002888E-01 0.3273576E-05 0.0000000E+00 14 Mn++ 0.2251939E-08 0.2251939E-08 0.0000000E+00 0.0000000E+00 15 F- 0.1209600E-04 0.1209600E-04 0.0000000E+00 0.0000000E+00 16 HPO4-- 0.4168819E-07 0.4168819E-07 0.0000000E+00 0.0000000E+00 Chg. balance for solid moles: 0.4235E-21 Mass of aqueous solution: 0.900185E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 0.0299900 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 0.3274E-05 -5.485 0.8584E-03 -3.066 1.716 0.3295E-03 quartz 0.8181E-03 -3.087 0.4915E-01 -1.308 98.28 0.1856E-01 stilpnomelane-Fe 0.3318E-08 -8.479 0.3577E-05 -5.446 0.7152E-02 0.1236E-05 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 quartz 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 0.050016 g Volume = 0.018893 cm3 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.0299900 moles log = -1.5230 Original solution: 1000.0103000 g Original solution / Rock added: 33344.79 (Water/Rock Ratio), log = 4.5230 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0206 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9997E+00 0.9859 0.1006E+01 0.1020E+01 CO2,gas 0.2513E-04 1.0071 0.2583E-04 0.2565E-04 CH4,gas 0.1025E-04 1.0125 0.1059E-04 0.1046E-04 H2,gas 0.2479E-03 1.0005 0.2531E-03 0.2530E-03 H2S,gas 0.5889E-05 0.9960 0.5987E-05 0.6011E-05 S2,gas 0.2057E-22 1.0000 0.2099E-22 0.2099E-22 CO,gas 0.1707E-11 1.0000 0.1743E-11 0.1743E-11 SO3,gas 0.3982E-39 1.0000 0.4064E-39 0.4064E-39 SO2,gas 0.3922E-20 1.0000 0.4003E-20 0.4003E-20 HF,gas 0.2231E-13 1.0000 0.2277E-13 0.2277E-13 HCl,gas 0.1118E-16 1.0000 0.1141E-16 0.1141E-16 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 17 albite -0.38 -0.38 0.00 0.000 -0.94784E-12 150 quartz -2.99 -2.99 0.00 0.000 0.00000E+00 167 stilpnomelane-Fe 13.02 13.02 0.00 0.000 0.21232E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -12.95 -6.29 -2.096 0.10735E+05 -4.588 3 CH4,gas 4.54 -2.13 -6.67 -1.669 0.11396E+05 -4.975 4 H2,gas 8.00 2.70 -5.30 -3.026 0.90421E+04 -3.597 5 H2S,gas -6.23 -13.15 -6.92 -3.461 0.11819E+05 -5.223 6 S2,gas -7.34 -31.71 -24.38 -3.750 0.41623E+05 -22.678 7 CO,gas 3.21 -10.24 -13.46 -4.141 0.22979E+05 -11.759 8 SO3,gas 17.12 -23.97 -41.09 -10.273 0.70160E+05 -39.391 9 SO2,gas 0.83 -21.26 -22.10 -5.892 0.37729E+05 -20.398 10 HF,gas 0.47 -14.87 -15.34 -7.671 0.26195E+05 -13.643 11 HCl,gas 5.19 -13.45 -18.64 -9.321 0.31830E+05 -16.943 12 acmite 7.71 7.41 -0.30 -0.031 0.51046E+03 16 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 20 spessartine 24.46 19.52 -4.94 -0.247 0.84273E+04 21 analcite 3.32 2.61 -0.72 -0.080 0.12231E+04 23 andradite 39.01 37.96 -1.05 -0.055 0.17935E+04 24 grossular 32.73 28.35 -4.38 -0.219 0.74846E+04 27 annite 20.12 17.32 -2.80 -0.156 0.47831E+04 28 phlogopite 27.06 24.15 -2.92 -0.162 0.49783E+04 33 apatite-OH -18.15 -21.69 -3.53 -0.272 0.60326E+04 34 apatite-F -34.30 -36.55 -2.25 -0.188 0.38483E+04 38 aragonite 0.97 -0.81 -1.77 -0.591 0.30273E+04 39 brucite 12.57 8.88 -3.69 -0.738 0.62977E+04 40 calcite 0.81 -0.81 -1.62 -0.539 0.27630E+04 41 carnegieite-low 9.02 5.60 -3.43 -0.490 0.58537E+04 42 carnegieite-high 10.09 5.60 -4.50 -0.643 0.76807E+04 43 carpholite-Mg 8.58 3.80 -4.79 -0.319 0.81719E+04 45 celadonite 5.34 3.40 -1.94 -0.114 0.33168E+04 46 celadonite-Fe 3.88 1.12 -2.75 -0.162 0.47008E+04 47 chrysotile 23.89 20.66 -3.23 -0.269 0.55160E+04 49 clinochlore 39.07 36.33 -2.74 -0.086 0.46816E+04 50 daphnite 28.97 24.95 -4.02 -0.125 0.68567E+04 54 chloritoid-Fe 9.17 4.51 -4.66 -0.311 0.79632E+04 55 chloritoid-Mn 11.40 7.10 -4.30 -0.286 0.73376E+04 57 coesite -2.38 -2.99 -0.61 -0.204 0.10473E+04 64 cristobalite -2.56 -2.99 -0.43 -0.143 0.73267E+03 66 cymrite-K 1.69 -2.49 -4.18 -0.348 0.71323E+04 68 diaspore 2.87 0.45 -2.43 -0.404 0.41429E+04 69 diamond -3.10 -7.54 -4.44 -1.268 0.75748E+04 70 diopside 16.18 15.04 -1.14 -0.114 0.19456E+04 71 hedenbergite 14.21 12.77 -1.44 -0.144 0.24622E+04 78 epidote 24.67 21.46 -3.21 -0.156 0.54808E+04 80 epidote-Fe 29.84 26.27 -3.58 -0.186 0.61052E+04 81 fayalite 14.05 10.22 -3.83 -0.547 0.65326E+04 82 ferrosilite 11.15 7.23 -3.92 -0.392 0.66917E+04 86 gibbsite 4.08 0.45 -3.63 -0.519 0.62015E+04 87 glaucophane 22.97 19.89 -3.08 -0.083 0.52601E+04 88 glaucophane-Fe 17.28 13.07 -4.21 -0.114 0.71860E+04 89 graphite -3.55 -7.54 -3.99 -1.141 0.68170E+04 90 greenalite 16.14 13.84 -2.30 -0.192 0.39349E+04 93 hematite 12.57 10.51 -2.06 -0.250 0.35193E+04 94 heulandite -5.83 -7.89 -2.06 -0.094 0.35234E+04 98 jadeite 4.22 2.61 -1.61 -0.161 0.27485E+04 100 kalsilite 7.58 3.49 -4.10 -0.585 0.69951E+04 101 kaolinite -1.33 -5.08 -3.75 -0.341 0.64054E+04 104 laumontite 2.88 1.08 -1.81 -0.120 0.30835E+04 105 lawsonite 9.62 7.06 -2.56 -0.171 0.43706E+04 106 leucite 4.12 0.50 -3.62 -0.362 0.61830E+04 108 lizardite 23.24 20.66 -2.58 -0.215 0.44086E+04 109 magnesite 0.69 -4.07 -4.76 -1.586 0.81230E+04 110 magnetite 20.09 17.11 -2.98 -0.243 0.50843E+04 111 minnesotaite 10.39 7.86 -2.53 -0.149 0.43233E+04 115 manganosite 14.06 9.20 -4.86 -1.215 0.82977E+04 119 microcline -2.49 -2.49 -0.01 0.000 0.89577E+01 123 muscovite 2.58 -1.60 -4.18 -0.246 0.71363E+04 124 paragonite 4.24 0.51 -3.73 -0.219 0.63664E+04 125 nepheline 8.34 5.60 -2.74 -0.392 0.46861E+04 137 phlogopite-Na 29.65 26.26 -3.39 -0.188 0.57881E+04 139 prehnite 19.37 16.21 -3.16 -0.186 0.54031E+04 140 prehnite-Fe 22.50 21.01 -1.49 -0.089 0.25359E+04 145 pyrite -21.25 -22.40 -1.16 -0.272 0.19749E+04 146 pyrrhotite -4.26 -6.55 -2.29 -0.762 0.39051E+04 147 pyrrhotiteFe0.875 -6.02 -7.71 -1.69 -0.622 0.28879E+04 148 pyroxmangite 7.40 6.21 -1.19 -0.238 0.20313E+04 149 pyrophyllite -6.18 -11.06 -4.89 -0.305 0.83448E+04 154 rhodochrosite -0.98 -3.75 -2.77 -0.924 0.47334E+04 155 rhodonite 7.45 6.21 -1.24 -0.247 0.21116E+04 156 sanidine -1.28 -2.49 -1.22 -0.094 0.20767E+04 158 siderite -2.61 -6.34 -3.73 -1.245 0.63760E+04 166 stilbite -7.52 -7.89 -0.37 -0.018 0.62961E+03 168 stilpnomelane-Mg 27.44 24.40 -3.05 -0.091 0.52015E+04 174 talc 16.49 14.68 -1.81 -0.106 0.30872E+04 177 tephroite 18.09 15.41 -2.68 -0.383 0.45732E+04 181 tridymite -2.63 -2.99 -0.36 -0.121 0.61998E+03 182 tremolite 47.87 44.77 -3.10 -0.084 0.52973E+04 184 troilite-low -4.41 -6.55 -2.14 -0.712 0.36479E+04 190 wairakite 3.95 1.08 -2.87 -0.169 0.49055E+04 191 walstromite 11.51 9.15 -2.36 -0.472 0.40264E+04 192 wollastonite 10.46 9.15 -1.31 -0.262 0.22369E+04 193 pseudo-wollastonite 11.00 9.15 -1.85 -0.370 0.31567E+04 195 akaganeite 7.75 5.25 -2.50 -0.541 0.42722E+04 202 chalcedony -2.80 -2.99 -0.19 -0.062 0.31930E+03 204 montmorillonite-Ca -2.29 -6.28 -3.99 -0.247 0.68064E+04 205 montmorillonite-K -2.24 -6.29 -4.05 -0.248 0.69218E+04 206 montmorillonite-Mg -2.48 -6.81 -4.34 -0.268 0.74020E+04 207 montmorillonite-Na -2.04 -5.59 -3.56 -0.218 0.60737E+04 208 nontronite-Ca 3.21 1.68 -1.53 -0.099 0.26122E+04 209 nontronite-H 2.53 -0.32 -2.85 -0.191 0.48684E+04 210 nontronite-K 3.34 1.67 -1.67 -0.107 0.28507E+04 211 nontronite-Mg 3.07 1.15 -1.93 -0.125 0.32918E+04 212 nontronite-Na 3.52 2.37 -1.15 -0.074 0.19687E+04 228 tobermorite 9.82 7.12 -2.70 -0.737 0.46092E+04 234 alabandite -0.98 -3.95 -2.98 -0.992 0.50809E+04 237 boehmite 4.41 0.45 -3.96 -0.660 0.67598E+04 239 ferrous-oxide 9.81 6.60 -3.21 -0.802 0.54758E+04 245 silica-amorphous -2.09 -2.99 -0.90 -0.299 0.15335E+04 247 an20ab80 2.02 1.10 -0.91 -0.070 0.15599E+04 248 an25ab75 2.65 1.48 -1.17 -0.090 0.19969E+04 249 an30ab70 3.28 1.85 -1.43 -0.110 0.24435E+04 250 tr.625ac.25prg.125 45.16 42.74 -2.42 -0.065 0.41324E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 0.0010000 MOLES Current total amount of reactant added: 0.0299900 MOLES New total amount of reactant added: 0.0309900 MOLES Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.5508E-08 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 7 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 0.0309900 Water: Moles liquid = 0.4988E+02 kg liquid = 0.8986E+00 Moles total = 0.4987E+02 kg total = 0.8985E+00 Activity = 1.0000 Stoichiometric ionic strength = .1332737E-01 Osmotic coef. = 0.9355 True ionic strength = .2178058E-01 Chg. balance for total moles = -.5508E-08 Max. difference allowed = 0.3207E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.14709E-09 -9.8324 0.12294E-09 -9.9103 0.83586E+00 -0.0779 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.35529E-03 -3.4494 0.29506E-03 -3.5301 0.83049E+00 -0.0807 4 SO4-- 0.14787E-03 -3.8301 0.75103E-04 -4.1243 0.50789E+00 -0.2942 5 HCO3- 0.11576E-02 -2.9364 0.96286E-03 -3.0164 0.83179E+00 -0.0800 6 HS- 0.71815E-03 -3.1438 0.59651E-03 -3.2244 0.83062E+00 -0.0806 7 Al+++ 0.23918E-28 -28.6213 0.52509E-29 -29.2798 0.21953E+00 -0.6585 8 H4SiO4 0.10246E-02 -2.9894 0.10246E-02 -2.9894 0.10000E+01 0.0000 9 Ca++ 0.39871E-07 -7.3993 0.20091E-07 -7.6970 0.50390E+00 -0.2977 10 Mg++ 0.22389E-10 -10.6500 0.11226E-10 -10.9498 0.50144E+00 -0.2998 11 Fe++ 0.12084E-12 -12.9178 0.60665E-13 -13.2171 0.50202E+00 -0.2993 12 K+ 0.15653E-03 -3.8054 0.13023E-03 -3.8853 0.83200E+00 -0.0799 13 Na+ 0.20126E-01 -1.6962 0.16711E-01 -1.7770 0.83032E+00 -0.0808 14 Mn++ 0.47383E-10 -10.3244 0.23808E-10 -10.6233 0.50247E+00 -0.2989 15 F- 0.13861E-04 -4.8582 0.11486E-04 -4.9398 0.82866E+00 -0.0816 16 HPO4-- 0.45665E-07 -7.3404 0.23196E-07 -7.6346 0.50796E+00 -0.2942 18 HSiO3- 0.93704E-02 -2.0282 0.77820E-02 -2.1089 0.83049E+00 -0.0807 19 Ca(HSiO3)+ 0.42787E-08 -8.3687 0.35607E-08 -8.4485 0.83219E+00 -0.0798 20 Mg(HSiO3)+ 0.29754E-11 -11.5265 0.24761E-11 -11.6062 0.83219E+00 -0.0798 21 NaHSiO3,aq 0.21033E-02 -2.6771 0.21033E-02 -2.6771 0.10000E+01 0.0000 22 AlO+ 0.56792E-16 -16.2457 0.47262E-16 -16.3255 0.83219E+00 -0.0798 24 HAlO2,aq 0.76557E-10 -10.1160 0.76557E-10 -10.1160 0.10000E+01 0.0000 25 AlO2- 0.16630E-05 -5.7791 0.13784E-05 -5.8606 0.82889E+00 -0.0815 26 CH4,aq 0.74589E-08 -8.1273 0.74287E-08 -8.1291 0.99595E+00 -0.0018 27 C2H6,aq 0.49308E-19 -19.3071 0.49108E-19 -19.3088 0.99595E+00 -0.0018 31 CO,aq 0.12207E-14 -14.9134 0.12207E-14 -14.9134 0.10000E+01 0.0000 32 CO2,aq 0.25397E-06 -6.5952 0.25294E-06 -6.5970 0.99595E+00 -0.0018 33 CO3-2 0.13500E-02 -2.8697 0.68408E-03 -3.1649 0.50673E+00 -0.2952 34 CaCO3,aq 0.17233E-06 -6.7636 0.17233E-06 -6.7636 0.10000E+01 0.0000 35 Ca(HCO3)+ 0.59338E-09 -9.2267 0.49380E-09 -9.3064 0.83219E+00 -0.0798 36 CaCl+ 0.11528E-10 -10.9382 0.95936E-11 -11.0180 0.83219E+00 -0.0798 37 CaCl2,aq 0.67252E-15 -15.1723 0.67252E-15 -15.1723 0.10000E+01 0.0000 38 CaF+ 0.40488E-11 -11.3927 0.33693E-11 -11.4725 0.83219E+00 -0.0798 39 CaOH+ 0.13995E-07 -7.8540 0.11647E-07 -7.9338 0.83219E+00 -0.0798 40 CaSO4,aq 0.47915E-09 -9.3195 0.47915E-09 -9.3195 0.10000E+01 0.0000 41 HCl,aq 0.66474E-14 -14.1774 0.66474E-14 -14.1774 0.10000E+01 0.0000 45 HF,aq 0.96673E-11 -11.0147 0.96673E-11 -11.0147 0.10000E+01 0.0000 46 HF2- 0.45143E-16 -16.3454 0.37491E-16 -16.4261 0.83049E+00 -0.0807 48 FeCl+ 0.34046E-16 -16.4679 0.28332E-16 -16.5477 0.83219E+00 -0.0798 51 FeF+ 0.42789E-16 -16.3687 0.35609E-16 -16.4484 0.83219E+00 -0.0798 53 FeO,aq 0.15599E-09 -9.8069 0.15599E-09 -9.8069 0.10000E+01 0.0000 54 FeOH+ 0.19301E-10 -10.7144 0.16062E-10 -10.7942 0.83219E+00 -0.0798 55 HFeO2- 0.15985E-07 -7.7963 0.13276E-07 -7.8769 0.83049E+00 -0.0807 56 FeO+ 0.10503E-15 -15.9787 0.87408E-16 -16.0584 0.83219E+00 -0.0798 58 FeO2- 0.14248E-08 -8.8462 0.11833E-08 -8.9269 0.83049E+00 -0.0807 59 HFeO2,aq 0.18503E-10 -10.7328 0.18503E-10 -10.7328 0.10000E+01 0.0000 60 H2,aq 0.19289E-06 -6.7147 0.19211E-06 -6.7165 0.99595E+00 -0.0018 61 KCl,aq 0.69646E-09 -9.1571 0.69646E-09 -9.1571 0.10000E+01 0.0000 62 KHSO4,aq 0.33999E-17 -17.4685 0.33999E-17 -17.4685 0.10000E+01 0.0000 63 KOH,aq 0.45238E-06 -6.3445 0.45238E-06 -6.3445 0.10000E+01 0.0000 64 KSO4- 0.18276E-06 -6.7381 0.15178E-06 -6.8188 0.83049E+00 -0.0807 65 MgCO3,aq 0.24137E-10 -10.6173 0.24137E-10 -10.6173 0.10000E+01 0.0000 66 Mg(HCO3)+ 0.33880E-12 -12.4701 0.28194E-12 -12.5498 0.83219E+00 -0.0798 67 MgCl+ 0.58384E-14 -14.2337 0.48586E-14 -14.3135 0.83219E+00 -0.0798 68 MgF+ 0.83805E-14 -14.0767 0.69741E-14 -14.1565 0.83219E+00 -0.0798 69 MgOH+ 0.43274E-10 -10.3638 0.36012E-10 -10.4436 0.83219E+00 -0.0798 71 MnF+ 0.55351E-14 -14.2569 0.46062E-14 -14.3367 0.83219E+00 -0.0798 72 MnO,aq 0.16312E-08 -8.7875 0.16312E-08 -8.7875 0.10000E+01 0.0000 73 MnOH+ 0.70367E-09 -9.1526 0.58559E-09 -9.2324 0.83219E+00 -0.0798 74 MnO2-2 0.70682E-11 -11.1507 0.35817E-11 -11.4459 0.50673E+00 -0.2952 75 HMnO2- 0.11616E-09 -9.9349 0.96472E-10 -10.0156 0.83049E+00 -0.0807 78 MnCl+ 0.51982E-13 -13.2841 0.43259E-13 -13.3639 0.83219E+00 -0.0798 79 MnSO4,aq 0.51620E-12 -12.2872 0.51620E-12 -12.2872 0.10000E+01 0.0000 80 NaCl,aq 0.16341E-05 -5.7867 0.16341E-05 -5.7867 0.10000E+01 0.0000 81 NaF,aq 0.44939E-07 -7.3474 0.44939E-07 -7.3474 0.10000E+01 0.0000 82 NaOH,aq 0.58401E-04 -4.2336 0.58401E-04 -4.2336 0.10000E+01 0.0000 84 OH- 0.56697E-02 -2.2464 0.46996E-02 -2.3279 0.82889E+00 -0.0815 89 HPO3-2 0.27405E-16 -16.5622 0.13887E-16 -16.8574 0.50673E+00 -0.2952 92 H3PO4,aq 0.24521E-17 -17.6105 0.24521E-17 -17.6105 0.10000E+01 0.0000 93 H2PO4- 0.63281E-10 -10.1987 0.52607E-10 -10.2790 0.83133E+00 -0.0802 94 PO4-3 0.66539E-09 -9.1769 0.15394E-09 -9.8127 0.23135E+00 -0.6357 98 HP2O7-3 0.16036E-17 -17.7949 0.35244E-18 -18.4529 0.21978E+00 -0.6580 99 P2O7-4 0.97064E-17 -17.0129 0.68485E-18 -18.1644 0.70557E-01 -1.1515 100 H2S,aq 0.22757E-06 -6.6429 0.22665E-06 -6.6446 0.99595E+00 -0.0018 101 S2-2 0.80990E-10 -10.0916 0.41041E-10 -10.3868 0.50673E+00 -0.2952 102 S3-2 0.12874E-15 -15.8903 0.65235E-16 -16.1855 0.50673E+00 -0.2952 103 S3- 0.14769E-19 -19.8306 0.12266E-19 -19.9113 0.83049E+00 -0.0807 107 SO3-2 0.36437E-11 -11.4385 0.18749E-11 -11.7270 0.51456E+00 -0.2886 108 HSO3- 0.17378E-13 -13.7600 0.14432E-13 -13.8407 0.83049E+00 -0.0807 109 HSO4- 0.10682E-10 -10.9714 0.88983E-11 -11.0507 0.83305E+00 -0.0793 111 S2O3-2 0.39460E-12 -12.4038 0.19996E-12 -12.6991 0.50673E+00 -0.2952 Charge balance for all species = -.6129E-08 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.1470854E-09 -.1855871E-01 -.1867246E+02 0.0000 2 H2O 0.1000000E+01 0.5550251E+02 0.9980983E+06 0.0000 3 Cl- 0.3552884E-03 0.3569232E-03 0.1263127E+02 6.3802 4 SO4-- 0.1478743E-03 0.1480021E-03 0.1419178E+02 15.6963 5 HCO3- 0.1157587E-02 0.2508001E-02 0.1527563E+03 6.8939 6 HS- 0.7181470E-03 0.7184302E-03 0.2371725E+02 6.6859 7 Al+++ 0.2391840E-28 0.1663045E-05 0.4479085E-01 0.4511 8 H4SiO4 0.1024625E-02 0.1249832E-01 0.1199124E+04 -2.9894 9 Ca++ 0.3987147E-07 0.2315684E-06 0.9264130E-02 12.1236 10 Mg++ 0.2238855E-10 0.9312803E-10 0.2260062E-05 8.8708 11 Fe++ 0.1208401E-12 0.1760425E-07 0.9813784E-03 6.6035 12 K+ 0.1565313E-03 0.1571671E-03 0.6134510E+01 6.0250 13 Na+ 0.2012601E-01 0.2228940E-01 0.5115083E+03 8.1333 14 Mn++ 0.4738252E-10 0.2506100E-08 0.1374328E-03 9.1973 15 F- 0.1386138E-04 0.1390634E-04 0.2637180E+00 4.9705 16 HPO4-- 0.4566458E-07 0.4639325E-07 0.4444779E-02 12.1860 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.1668969E-01 -.1667654E-01 -.1315239E-04 0.0000000E+00 2 H2O 0.4987178E+02 0.4987362E+02 -.1837877E-02 0.0000000E+00 3 Cl- 0.3207252E-03 0.3207252E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.1329922E-03 0.1329922E-03 0.0000000E+00 0.0000000E+00 5 HCO3- 0.2253647E-02 0.2253647E-02 0.0000000E+00 0.0000000E+00 6 HS- 0.6455693E-03 0.6455693E-03 0.0000000E+00 0.0000000E+00 7 Al+++ 0.4775352E-05 0.1494384E-05 0.3280968E-05 0.0000000E+00 8 H4SiO4 0.1215302E-01 0.1123078E-01 0.9222372E-03 0.0000000E+00 9 Ca++ 0.2080835E-06 0.2080835E-06 0.0000000E+00 0.0000000E+00 10 Mg++ 0.8368328E-10 0.8368328E-10 0.0000000E+00 0.0000000E+00 11 Fe++ 0.3259227E-07 0.1581888E-07 0.1677339E-07 0.0000000E+00 12 K+ 0.1412294E-03 0.1412277E-03 0.1677339E-08 0.0000000E+00 13 Na+ 0.2003215E-01 0.2002888E-01 0.3274258E-05 0.0000000E+00 14 Mn++ 0.2251939E-08 0.2251939E-08 0.0000000E+00 0.0000000E+00 15 F- 0.1249600E-04 0.1249600E-04 0.0000000E+00 0.0000000E+00 16 HPO4-- 0.4168819E-07 0.4168819E-07 0.0000000E+00 0.0000000E+00 Chg. balance for solid moles: 0.1271E-20 Mass of aqueous solution: 0.900200E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 0.0309900 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 0.3274E-05 -5.485 0.8586E-03 -3.066 1.542 0.3296E-03 quartz 0.9124E-03 -3.040 0.5482E-01 -1.261 98.45 0.2070E-01 stilpnomelane-Fe 0.3355E-08 -8.474 0.3616E-05 -5.442 0.6495E-02 0.1249E-05 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 quartz 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 0.055678 g Volume = 0.021032 cm3 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.0309900 moles log = -1.5088 Original solution: 1000.0103000 g Original solution / Rock added: 32268.81 (Water/Rock Ratio), log = 4.5088 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0206 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9997E+00 0.9859 0.1006E+01 0.1020E+01 CO2,gas 0.2633E-04 1.0071 0.2706E-04 0.2687E-04 CH4,gas 0.1058E-04 1.0125 0.1093E-04 0.1080E-04 H2,gas 0.2470E-03 1.0005 0.2522E-03 0.2521E-03 H2S,gas 0.6129E-05 0.9960 0.6231E-05 0.6255E-05 S2,gas 0.2244E-22 1.0000 0.2291E-22 0.2291E-22 CO,gas 0.1782E-11 1.0000 0.1819E-11 0.1819E-11 SO3,gas 0.4206E-39 1.0000 0.4292E-39 0.4292E-39 SO2,gas 0.4127E-20 1.0000 0.4212E-20 0.4212E-20 HF,gas 0.2326E-13 1.0000 0.2374E-13 0.2374E-13 HCl,gas 0.1149E-16 1.0000 0.1173E-16 0.1173E-16 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 17 albite -0.38 -0.38 0.00 0.000 -0.94784E-12 150 quartz -2.99 -2.99 0.00 0.000 0.00000E+00 167 stilpnomelane-Fe 13.02 13.02 0.00 0.000 0.69761E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -12.93 -6.27 -2.089 0.10700E+05 -4.568 3 CH4,gas 4.54 -2.12 -6.66 -1.665 0.11372E+05 -4.961 4 H2,gas 8.00 2.70 -5.30 -3.027 0.90448E+04 -3.598 5 H2S,gas -6.23 -13.13 -6.90 -3.452 0.11789E+05 -5.205 6 S2,gas -7.34 -31.67 -24.34 -3.744 0.41558E+05 -22.640 7 CO,gas 3.21 -10.22 -13.44 -4.135 0.22947E+05 -11.740 8 SO3,gas 17.12 -23.94 -41.07 -10.267 0.70120E+05 -39.367 9 SO2,gas 0.83 -21.24 -22.07 -5.887 0.37692E+05 -20.376 10 HF,gas 0.47 -14.85 -15.32 -7.662 0.26165E+05 -13.625 11 HCl,gas 5.19 -13.44 -18.63 -9.315 0.31810E+05 -16.931 12 acmite 7.71 7.41 -0.30 -0.031 0.51741E+03 16 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 20 spessartine 24.46 19.53 -4.93 -0.247 0.84202E+04 21 analcite 3.32 2.61 -0.72 -0.080 0.12231E+04 23 andradite 39.01 37.91 -1.10 -0.057 0.18812E+04 24 grossular 32.73 28.30 -4.43 -0.221 0.75584E+04 26 ankerite -2.14 -7.13 -4.99 -0.832 0.85224E+04 27 annite 20.12 17.32 -2.80 -0.156 0.47894E+04 28 phlogopite 27.06 24.12 -2.94 -0.164 0.50272E+04 33 apatite-OH -18.15 -21.75 -3.59 -0.276 0.61367E+04 34 apatite-F -34.30 -36.60 -2.30 -0.191 0.39215E+04 38 aragonite 0.97 -0.80 -1.77 -0.590 0.30216E+04 39 brucite 12.57 8.87 -3.70 -0.740 0.63138E+04 40 calcite 0.81 -0.80 -1.61 -0.538 0.27574E+04 41 carnegieite-low 9.02 5.60 -3.43 -0.490 0.58537E+04 42 carnegieite-high 10.09 5.60 -4.50 -0.643 0.76807E+04 43 carpholite-Mg 8.58 3.79 -4.79 -0.319 0.81751E+04 45 celadonite 5.34 3.39 -1.95 -0.115 0.33336E+04 46 celadonite-Fe 3.88 1.12 -2.75 -0.162 0.47034E+04 47 chrysotile 23.89 20.63 -3.26 -0.272 0.55642E+04 49 clinochlore 39.07 36.29 -2.78 -0.087 0.47491E+04 50 daphnite 28.97 24.95 -4.01 -0.125 0.68531E+04 54 chloritoid-Fe 9.17 4.52 -4.66 -0.310 0.79521E+04 55 chloritoid-Mn 11.40 7.11 -4.29 -0.286 0.73266E+04 57 coesite -2.38 -2.99 -0.61 -0.204 0.10473E+04 64 cristobalite -2.56 -2.99 -0.43 -0.143 0.73267E+03 66 cymrite-K 1.69 -2.49 -4.18 -0.348 0.71330E+04 68 diaspore 2.87 0.45 -2.42 -0.404 0.41365E+04 69 diamond -3.10 -7.52 -4.42 -1.263 0.75457E+04 70 diopside 16.18 15.02 -1.17 -0.117 0.19905E+04 71 hedenbergite 14.21 12.75 -1.46 -0.146 0.24929E+04 78 epidote 24.67 21.43 -3.24 -0.157 0.55262E+04 80 epidote-Fe 29.84 26.23 -3.61 -0.187 0.61576E+04 81 fayalite 14.05 10.22 -3.83 -0.547 0.65364E+04 82 ferrosilite 11.15 7.23 -3.92 -0.392 0.66954E+04 86 gibbsite 4.08 0.45 -3.63 -0.518 0.61950E+04 87 glaucophane 22.97 19.87 -3.11 -0.084 0.53083E+04 88 glaucophane-Fe 17.28 13.06 -4.21 -0.114 0.71916E+04 89 graphite -3.55 -7.52 -3.98 -1.136 0.67879E+04 90 greenalite 16.14 13.83 -2.31 -0.192 0.39405E+04 93 hematite 12.57 10.50 -2.06 -0.250 0.35203E+04 94 heulandite -5.83 -7.90 -2.07 -0.094 0.35395E+04 98 jadeite 4.22 2.61 -1.61 -0.161 0.27485E+04 100 kalsilite 7.58 3.49 -4.10 -0.585 0.69958E+04 101 kaolinite -1.33 -5.08 -3.74 -0.340 0.63925E+04 104 laumontite 2.88 1.07 -1.82 -0.121 0.30995E+04 105 lawsonite 9.62 7.05 -2.57 -0.171 0.43866E+04 106 leucite 4.12 0.50 -3.62 -0.362 0.61837E+04 108 lizardite 23.24 20.63 -2.61 -0.218 0.44568E+04 109 magnesite 0.69 -4.06 -4.75 -1.582 0.81045E+04 110 magnetite 20.09 17.11 -2.98 -0.243 0.50872E+04 111 minnesotaite 10.39 7.85 -2.54 -0.149 0.43289E+04 115 manganosite 14.06 9.20 -4.86 -1.215 0.82997E+04 119 microcline -2.49 -2.49 -0.01 0.000 0.96569E+01 123 muscovite 2.58 -1.59 -4.17 -0.245 0.71241E+04 124 paragonite 4.24 0.52 -3.72 -0.219 0.63536E+04 125 nepheline 8.34 5.60 -2.74 -0.392 0.46861E+04 137 phlogopite-Na 29.65 26.23 -3.42 -0.190 0.58363E+04 139 prehnite 19.37 16.18 -3.19 -0.188 0.54481E+04 140 prehnite-Fe 22.50 20.98 -1.52 -0.091 0.25878E+04 145 pyrite -21.25 -22.37 -1.12 -0.264 0.19149E+04 146 pyrrhotite -4.26 -6.53 -2.27 -0.757 0.38774E+04 147 pyrrhotiteFe0.875 -6.02 -7.69 -1.67 -0.616 0.28596E+04 148 pyroxmangite 7.40 6.21 -1.19 -0.238 0.20332E+04 149 pyrophyllite -6.18 -11.06 -4.88 -0.305 0.83319E+04 154 rhodochrosite -0.98 -3.73 -2.75 -0.918 0.47008E+04 155 rhodonite 7.45 6.21 -1.24 -0.248 0.21135E+04 156 sanidine -1.28 -2.49 -1.22 -0.094 0.20774E+04 158 siderite -2.61 -6.32 -3.72 -1.238 0.63434E+04 166 stilbite -7.52 -7.90 -0.38 -0.018 0.64563E+03 168 stilpnomelane-Mg 27.44 24.35 -3.09 -0.092 0.52725E+04 174 talc 16.49 14.65 -1.84 -0.108 0.31354E+04 177 tephroite 18.09 15.41 -2.68 -0.383 0.45770E+04 181 tridymite -2.63 -2.99 -0.36 -0.121 0.61998E+03 182 tremolite 47.87 44.69 -3.18 -0.086 0.54354E+04 184 troilite-low -4.41 -6.53 -2.12 -0.707 0.36202E+04 190 wairakite 3.95 1.07 -2.88 -0.170 0.49215E+04 191 walstromite 11.51 9.13 -2.38 -0.475 0.40553E+04 192 wollastonite 10.46 9.13 -1.33 -0.265 0.22658E+04 193 pseudo-wollastonite 11.00 9.13 -1.87 -0.373 0.31856E+04 195 akaganeite 7.75 5.25 -2.50 -0.541 0.42727E+04 202 chalcedony -2.80 -2.99 -0.19 -0.062 0.31930E+03 204 montmorillonite-Ca -2.29 -6.28 -3.99 -0.247 0.68057E+04 205 montmorillonite-K -2.24 -6.29 -4.05 -0.248 0.69187E+04 206 montmorillonite-Mg -2.48 -6.81 -4.33 -0.268 0.73992E+04 207 montmorillonite-Na -2.04 -5.59 -3.56 -0.218 0.60704E+04 208 nontronite-Ca 3.21 1.68 -1.53 -0.099 0.26158E+04 209 nontronite-H 2.53 -0.32 -2.85 -0.191 0.48672E+04 210 nontronite-K 3.34 1.67 -1.67 -0.107 0.28520E+04 211 nontronite-Mg 3.07 1.15 -1.93 -0.125 0.32933E+04 212 nontronite-Na 3.52 2.37 -1.15 -0.074 0.19697E+04 228 tobermorite 9.82 7.11 -2.71 -0.740 0.46333E+04 234 alabandite -0.98 -3.94 -2.96 -0.986 0.50532E+04 237 boehmite 4.41 0.45 -3.96 -0.659 0.67534E+04 239 ferrous-oxide 9.81 6.60 -3.21 -0.802 0.54777E+04 245 silica-amorphous -2.09 -2.99 -0.90 -0.299 0.15335E+04 247 an20ab80 2.02 1.10 -0.92 -0.070 0.15631E+04 248 an25ab75 2.65 1.47 -1.17 -0.090 0.20009E+04 249 an30ab70 3.28 1.85 -1.43 -0.110 0.24483E+04 250 tr.625ac.25prg.125 45.16 42.68 -2.49 -0.067 0.42492E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 0.0010000 MOLES Current total amount of reactant added: 0.0309900 MOLES New total amount of reactant added: 0.0319900 MOLES Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.5508E-08 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 7 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 0.0319900 Water: Moles liquid = 0.4988E+02 kg liquid = 0.8986E+00 Moles total = 0.4987E+02 kg total = 0.8985E+00 Activity = 1.0000 Stoichiometric ionic strength = .1339233E-01 Osmotic coef. = 0.9352 True ionic strength = .2184180E-01 Chg. balance for total moles = -.5508E-08 Max. difference allowed = 0.3266E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.14851E-09 -9.8282 0.12411E-09 -9.9062 0.83571E+00 -0.0779 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.36182E-03 -3.4415 0.30043E-03 -3.5223 0.83033E+00 -0.0807 4 SO4-- 0.15318E-03 -3.8148 0.77739E-04 -4.1094 0.50751E+00 -0.2946 5 HCO3- 0.12004E-02 -2.9207 0.99831E-03 -3.0007 0.83163E+00 -0.0801 6 HS- 0.73985E-03 -3.1309 0.61442E-03 -3.2115 0.83046E+00 -0.0807 7 Al+++ 0.24867E-28 -28.6044 0.54497E-29 -29.2636 0.21916E+00 -0.6592 8 H4SiO4 0.10246E-02 -2.9894 0.10246E-02 -2.9894 0.10000E+01 0.0000 9 Ca++ 0.39131E-07 -7.4075 0.19703E-07 -7.7055 0.50351E+00 -0.2980 10 Mg++ 0.22344E-10 -10.6508 0.11195E-10 -10.9510 0.50105E+00 -0.3001 11 Fe++ 0.12293E-12 -12.9103 0.61668E-13 -13.2099 0.50163E+00 -0.2996 12 K+ 0.15653E-03 -3.8054 0.13020E-03 -3.8854 0.83184E+00 -0.0800 13 Na+ 0.20144E-01 -1.6958 0.16723E-01 -1.7767 0.83017E+00 -0.0808 14 Mn++ 0.48198E-10 -10.3170 0.24199E-10 -10.6162 0.50208E+00 -0.2992 15 F- 0.14305E-04 -4.8445 0.11852E-04 -4.9262 0.82850E+00 -0.0817 16 HPO4-- 0.45669E-07 -7.3404 0.23181E-07 -7.6349 0.50758E+00 -0.2945 18 HSiO3- 0.92838E-02 -2.0323 0.77087E-02 -2.1130 0.83033E+00 -0.0807 19 Ca(HSiO3)+ 0.41572E-08 -8.3812 0.34589E-08 -8.4611 0.83203E+00 -0.0799 20 Mg(HSiO3)+ 0.29398E-11 -11.5317 0.24460E-11 -11.6115 0.83203E+00 -0.0799 21 NaHSiO3,aq 0.20850E-02 -2.6809 0.20850E-02 -2.6809 0.10000E+01 0.0000 22 AlO+ 0.57847E-16 -16.2377 0.48131E-16 -16.3176 0.83203E+00 -0.0799 24 HAlO2,aq 0.77230E-10 -10.1122 0.77230E-10 -10.1122 0.10000E+01 0.0000 25 AlO2- 0.16621E-05 -5.7793 0.13774E-05 -5.8609 0.82873E+00 -0.0816 26 CH4,aq 0.76958E-08 -8.1137 0.76644E-08 -8.1155 0.99593E+00 -0.0018 27 C2H6,aq 0.52678E-19 -19.2784 0.52463E-19 -19.2801 0.99593E+00 -0.0018 31 CO,aq 0.12731E-14 -14.8951 0.12731E-14 -14.8951 0.10000E+01 0.0000 32 CO2,aq 0.26583E-06 -6.5754 0.26475E-06 -6.5772 0.99593E+00 -0.0018 33 CO3-2 0.13875E-02 -2.8578 0.70258E-03 -3.1533 0.50635E+00 -0.2955 34 CaCO3,aq 0.17357E-06 -6.7605 0.17357E-06 -6.7605 0.10000E+01 0.0000 35 Ca(HCO3)+ 0.60344E-09 -9.2194 0.50208E-09 -9.2992 0.83203E+00 -0.0799 36 CaCl+ 0.11513E-10 -10.9388 0.95792E-11 -11.0187 0.83203E+00 -0.0799 37 CaCl2,aq 0.68371E-15 -15.1651 0.68371E-15 -15.1651 0.10000E+01 0.0000 38 CaF+ 0.40975E-11 -11.3875 0.34092E-11 -11.4673 0.83203E+00 -0.0799 39 CaOH+ 0.13598E-07 -7.8665 0.11314E-07 -7.9464 0.83203E+00 -0.0799 40 CaSO4,aq 0.48638E-09 -9.3130 0.48638E-09 -9.3130 0.10000E+01 0.0000 41 HCl,aq 0.68326E-14 -14.1654 0.68326E-14 -14.1654 0.10000E+01 0.0000 45 HF,aq 0.10069E-10 -10.9970 0.10069E-10 -10.9970 0.10000E+01 0.0000 46 HF2- 0.48525E-16 -16.3140 0.40292E-16 -16.3948 0.83033E+00 -0.0807 48 FeCl+ 0.35245E-16 -16.4529 0.29325E-16 -16.5328 0.83203E+00 -0.0799 51 FeF+ 0.44888E-16 -16.3479 0.37348E-16 -16.4277 0.83203E+00 -0.0799 53 FeO,aq 0.15560E-09 -9.8080 0.15560E-09 -9.8080 0.10000E+01 0.0000 54 FeOH+ 0.19439E-10 -10.7113 0.16174E-10 -10.7912 0.83203E+00 -0.0799 55 HFeO2- 0.15798E-07 -7.8014 0.13117E-07 -7.8822 0.83033E+00 -0.0807 56 FeO+ 0.10598E-15 -15.9748 0.88175E-16 -16.0547 0.83203E+00 -0.0799 58 FeO2- 0.14106E-08 -8.8506 0.11713E-08 -8.9313 0.83033E+00 -0.0807 59 HFeO2,aq 0.18489E-10 -10.7331 0.18489E-10 -10.7331 0.10000E+01 0.0000 60 H2,aq 0.19220E-06 -6.7162 0.19142E-06 -6.7180 0.99593E+00 -0.0018 61 KCl,aq 0.70896E-09 -9.1494 0.70896E-09 -9.1494 0.10000E+01 0.0000 62 KHSO4,aq 0.35519E-17 -17.4495 0.35519E-17 -17.4495 0.10000E+01 0.0000 63 KOH,aq 0.44802E-06 -6.3487 0.44802E-06 -6.3487 0.10000E+01 0.0000 64 KSO4- 0.18916E-06 -6.7232 0.15707E-06 -6.8039 0.83033E+00 -0.0807 65 MgCO3,aq 0.24722E-10 -10.6069 0.24722E-10 -10.6069 0.10000E+01 0.0000 66 Mg(HCO3)+ 0.35037E-12 -12.4555 0.29152E-12 -12.5353 0.83203E+00 -0.0799 67 MgCl+ 0.59292E-14 -14.2270 0.49333E-14 -14.3069 0.83203E+00 -0.0799 68 MgF+ 0.86246E-14 -14.0643 0.71760E-14 -14.1441 0.83203E+00 -0.0799 69 MgOH+ 0.42756E-10 -10.3690 0.35574E-10 -10.4489 0.83203E+00 -0.0799 71 MnF+ 0.58059E-14 -14.2361 0.48307E-14 -14.3160 0.83203E+00 -0.0799 72 MnO,aq 0.16269E-08 -8.7886 0.16269E-08 -8.7886 0.10000E+01 0.0000 73 MnOH+ 0.70862E-09 -9.1496 0.58959E-09 -9.2294 0.83203E+00 -0.0799 74 MnO2-2 0.69224E-11 -11.1597 0.35052E-11 -11.4553 0.50635E+00 -0.2955 75 HMnO2- 0.11479E-09 -9.9401 0.95309E-10 -10.0209 0.83033E+00 -0.0807 78 MnCl+ 0.53807E-13 -13.2692 0.44769E-13 -13.3490 0.83203E+00 -0.0799 79 MnSO4,aq 0.54309E-12 -12.2651 0.54309E-12 -12.2651 0.10000E+01 0.0000 80 NaCl,aq 0.16650E-05 -5.7786 0.16650E-05 -5.7786 0.10000E+01 0.0000 81 NaF,aq 0.46401E-07 -7.3335 0.46401E-07 -7.3335 0.10000E+01 0.0000 82 NaOH,aq 0.57892E-04 -4.2374 0.57892E-04 -4.2374 0.10000E+01 0.0000 84 OH- 0.56174E-02 -2.2505 0.46553E-02 -2.3321 0.82873E+00 -0.0816 89 HPO3-2 0.27309E-16 -16.5637 0.13828E-16 -16.8592 0.50635E+00 -0.2955 92 H3PO4,aq 0.24973E-17 -17.6025 0.24973E-17 -17.6025 0.10000E+01 0.0000 93 H2PO4- 0.63853E-10 -10.1948 0.53073E-10 -10.2751 0.83117E+00 -0.0803 94 PO4-3 0.65974E-09 -9.1806 0.15239E-09 -9.8171 0.23098E+00 -0.6364 98 HP2O7-3 0.16196E-17 -17.7906 0.35533E-18 -18.4494 0.21940E+00 -0.6588 99 P2O7-4 0.97227E-17 -17.0122 0.68395E-18 -18.1650 0.70346E-01 -1.1528 100 H2S,aq 0.23664E-06 -6.6259 0.23568E-06 -6.6277 0.99593E+00 -0.0018 101 S2-2 0.86302E-10 -10.0640 0.43699E-10 -10.3595 0.50635E+00 -0.2955 102 S3-2 0.14316E-15 -15.8442 0.72487E-16 -16.1397 0.50635E+00 -0.2955 103 S3- 0.16600E-19 -19.7799 0.13784E-19 -19.8606 0.83033E+00 -0.0807 107 SO3-2 0.37607E-11 -11.4247 0.19337E-11 -11.7136 0.51419E+00 -0.2889 108 HSO3- 0.18098E-13 -13.7424 0.15027E-13 -13.8231 0.83033E+00 -0.0807 109 HSO4- 0.11164E-10 -10.9522 0.92983E-11 -11.0316 0.83290E+00 -0.0794 111 S2O3-2 0.42504E-12 -12.3716 0.21522E-12 -12.6671 0.50635E+00 -0.2955 Charge balance for all species = -.6129E-08 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.1485111E-09 -.1843852E-01 -.1855159E+02 0.0000 2 H2O 0.1000000E+01 0.5550256E+02 0.9981019E+06 0.0000 3 Cl- 0.3618164E-03 0.3634821E-03 0.1286342E+02 6.3839 4 SO4-- 0.1531789E-03 0.1533131E-03 0.1470108E+02 15.7030 5 HCO3- 0.1200428E-02 0.2588411E-02 0.1576543E+03 6.9055 6 HS- 0.7398523E-03 0.7401446E-03 0.2443416E+02 6.6947 7 Al+++ 0.2486665E-28 0.1662171E-05 0.4476744E-01 0.4549 8 H4SiO4 0.1024625E-02 0.1239346E-01 0.1189066E+04 -2.9894 9 Ca++ 0.3913053E-07 0.2315640E-06 0.9263976E-02 12.1069 10 Mg++ 0.2234419E-10 0.9312624E-10 0.2260024E-05 8.8614 11 Fe++ 0.1229346E-12 0.1740212E-07 0.9701130E-03 6.6024 12 K+ 0.1565262E-03 0.1571641E-03 0.6134407E+01 6.0208 13 Na+ 0.2014437E-01 0.2228897E-01 0.5114998E+03 8.1295 14 Mn++ 0.4819795E-10 0.2506052E-08 0.1374305E-03 9.1962 15 F- 0.1430479E-04 0.1435121E-04 0.2721552E+00 4.9800 16 HPO4-- 0.4566876E-07 0.4639235E-07 0.4444705E-02 12.1775 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.1658202E-01 -.1656886E-01 -.1315572E-04 0.0000000E+00 2 H2O 0.4987260E+02 0.4987462E+02 -.2025903E-02 0.0000000E+00 3 Cl- 0.3266252E-03 0.3266252E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.1377672E-03 0.1377672E-03 0.0000000E+00 0.0000000E+00 5 HCO3- 0.2325947E-02 0.2325947E-02 0.0000000E+00 0.0000000E+00 6 HS- 0.6650943E-03 0.6650943E-03 0.0000000E+00 0.0000000E+00 7 Al+++ 0.4775352E-05 0.1493628E-05 0.3281724E-05 0.0000000E+00 8 H4SiO4 0.1215302E-01 0.1113677E-01 0.1016251E-02 0.0000000E+00 9 Ca++ 0.2080835E-06 0.2080835E-06 0.0000000E+00 0.0000000E+00 10 Mg++ 0.8368328E-10 0.8368328E-10 0.0000000E+00 0.0000000E+00 11 Fe++ 0.3259227E-07 0.1563755E-07 0.1695472E-07 0.0000000E+00 12 K+ 0.1412294E-03 0.1412277E-03 0.1695472E-08 0.0000000E+00 13 Na+ 0.2003215E-01 0.2002888E-01 0.3274942E-05 0.0000000E+00 14 Mn++ 0.2251939E-08 0.2251939E-08 0.0000000E+00 0.0000000E+00 15 F- 0.1289600E-04 0.1289600E-04 0.0000000E+00 0.0000000E+00 16 HPO4-- 0.4168819E-07 0.4168819E-07 0.0000000E+00 0.0000000E+00 Chg. balance for solid moles: -.4235E-21 Mass of aqueous solution: 0.900215E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 0.0319900 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 0.3275E-05 -5.485 0.8588E-03 -3.066 1.400 0.3297E-03 quartz 0.1006E-02 -2.997 0.6046E-01 -1.218 98.59 0.2283E-01 stilpnomelane-Fe 0.3391E-08 -8.470 0.3655E-05 -5.437 0.5961E-02 0.1263E-05 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 quartz 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 0.061327 g Volume = 0.023165 cm3 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.0319900 moles log = -1.4950 Original solution: 1000.0103000 g Original solution / Rock added: 31260.09 (Water/Rock Ratio), log = 4.4950 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0206 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9997E+00 0.9859 0.1006E+01 0.1020E+01 CO2,gas 0.2756E-04 1.0071 0.2833E-04 0.2813E-04 CH4,gas 0.1092E-04 1.0125 0.1128E-04 0.1114E-04 H2,gas 0.2461E-03 1.0005 0.2513E-03 0.2512E-03 H2S,gas 0.6373E-05 0.9960 0.6479E-05 0.6504E-05 S2,gas 0.2444E-22 1.0000 0.2495E-22 0.2495E-22 CO,gas 0.1859E-11 1.0000 0.1897E-11 0.1897E-11 SO3,gas 0.4436E-39 1.0000 0.4528E-39 0.4528E-39 SO2,gas 0.4337E-20 1.0000 0.4427E-20 0.4427E-20 HF,gas 0.2423E-13 1.0000 0.2472E-13 0.2472E-13 HCl,gas 0.1181E-16 1.0000 0.1206E-16 0.1206E-16 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 17 albite -0.38 -0.38 0.00 0.000 -0.94784E-12 150 quartz -2.99 -2.99 0.00 0.000 0.00000E+00 167 stilpnomelane-Fe 13.02 13.02 0.00 0.000 0.21232E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -12.91 -6.25 -2.082 0.10666E+05 -4.548 3 CH4,gas 4.54 -2.10 -6.65 -1.662 0.11349E+05 -4.948 4 H2,gas 8.00 2.70 -5.30 -3.028 0.90475E+04 -3.600 5 H2S,gas -6.23 -13.12 -6.89 -3.444 0.11760E+05 -5.189 6 S2,gas -7.34 -31.64 -24.30 -3.739 0.41495E+05 -22.603 7 CO,gas 3.21 -10.21 -13.42 -4.129 0.22916E+05 -11.722 8 SO3,gas 17.12 -23.92 -41.04 -10.261 0.70080E+05 -39.344 9 SO2,gas 0.83 -21.22 -22.05 -5.881 0.37655E+05 -20.354 10 HF,gas 0.47 -14.83 -15.31 -7.653 0.26134E+05 -13.607 11 HCl,gas 5.19 -13.43 -18.62 -9.309 0.31789E+05 -16.919 12 acmite 7.71 7.40 -0.31 -0.032 0.52444E+03 16 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 20 spessartine 24.46 19.53 -4.93 -0.246 0.84131E+04 21 analcite 3.32 2.61 -0.72 -0.080 0.12231E+04 23 andradite 39.01 37.86 -1.15 -0.060 0.19678E+04 24 grossular 32.73 28.26 -4.47 -0.223 0.76310E+04 26 ankerite -2.14 -7.10 -4.97 -0.828 0.84852E+04 27 annite 20.12 17.31 -2.81 -0.156 0.47957E+04 28 phlogopite 27.06 24.09 -2.97 -0.165 0.50761E+04 33 apatite-OH -18.15 -21.81 -3.65 -0.281 0.62387E+04 34 apatite-F -34.30 -36.64 -2.34 -0.195 0.39932E+04 38 aragonite 0.97 -0.80 -1.77 -0.589 0.30163E+04 39 brucite 12.57 8.86 -3.71 -0.741 0.63299E+04 40 calcite 0.81 -0.80 -1.61 -0.537 0.27521E+04 41 carnegieite-low 9.02 5.60 -3.43 -0.490 0.58537E+04 42 carnegieite-high 10.09 5.60 -4.50 -0.643 0.76807E+04 43 carpholite-Mg 8.58 3.79 -4.79 -0.319 0.81782E+04 45 celadonite 5.34 3.38 -1.96 -0.115 0.33504E+04 46 celadonite-Fe 3.88 1.12 -2.76 -0.162 0.47059E+04 47 chrysotile 23.89 20.61 -3.29 -0.274 0.56125E+04 49 clinochlore 39.07 36.25 -2.82 -0.088 0.48166E+04 50 daphnite 28.97 24.95 -4.01 -0.125 0.68495E+04 54 chloritoid-Fe 9.17 4.52 -4.65 -0.310 0.79410E+04 55 chloritoid-Mn 11.40 7.12 -4.28 -0.286 0.73156E+04 57 coesite -2.38 -2.99 -0.61 -0.204 0.10473E+04 64 cristobalite -2.56 -2.99 -0.43 -0.143 0.73267E+03 66 cymrite-K 1.69 -2.49 -4.18 -0.348 0.71337E+04 68 diaspore 2.87 0.45 -2.42 -0.403 0.41300E+04 69 diamond -3.10 -7.50 -4.40 -1.258 0.75172E+04 70 diopside 16.18 14.99 -1.19 -0.119 0.20352E+04 71 hedenbergite 14.21 12.73 -1.48 -0.148 0.25233E+04 78 epidote 24.67 21.41 -3.26 -0.158 0.55708E+04 80 epidote-Fe 29.84 26.20 -3.64 -0.189 0.62092E+04 81 fayalite 14.05 10.22 -3.83 -0.547 0.65401E+04 82 ferrosilite 11.15 7.23 -3.92 -0.392 0.66992E+04 86 gibbsite 4.08 0.45 -3.62 -0.518 0.61885E+04 87 glaucophane 22.97 19.84 -3.14 -0.085 0.53566E+04 88 glaucophane-Fe 17.28 13.06 -4.22 -0.114 0.71972E+04 89 graphite -3.55 -7.50 -3.96 -1.131 0.67594E+04 90 greenalite 16.14 13.83 -2.31 -0.193 0.39461E+04 93 hematite 12.57 10.50 -2.06 -0.250 0.35213E+04 94 heulandite -5.83 -7.91 -2.08 -0.095 0.35550E+04 98 jadeite 4.22 2.61 -1.61 -0.161 0.27485E+04 100 kalsilite 7.58 3.49 -4.10 -0.585 0.69965E+04 101 kaolinite -1.33 -5.07 -3.74 -0.340 0.63795E+04 104 laumontite 2.88 1.06 -1.82 -0.122 0.31151E+04 105 lawsonite 9.62 7.04 -2.58 -0.172 0.44022E+04 106 leucite 4.12 0.50 -3.62 -0.362 0.61844E+04 108 lizardite 23.24 20.61 -2.64 -0.220 0.45051E+04 109 magnesite 0.69 -4.05 -4.74 -1.579 0.80868E+04 110 magnetite 20.09 17.11 -2.98 -0.243 0.50901E+04 111 minnesotaite 10.39 7.85 -2.54 -0.149 0.43345E+04 115 manganosite 14.06 9.20 -4.86 -1.215 0.83016E+04 119 microcline -2.49 -2.49 -0.01 0.000 0.10354E+02 123 muscovite 2.58 -1.58 -4.17 -0.245 0.71118E+04 124 paragonite 4.24 0.53 -3.71 -0.218 0.63406E+04 125 nepheline 8.34 5.60 -2.74 -0.392 0.46861E+04 137 phlogopite-Na 29.65 26.20 -3.45 -0.191 0.58846E+04 139 prehnite 19.37 16.16 -3.22 -0.189 0.54921E+04 140 prehnite-Fe 22.50 20.95 -1.55 -0.093 0.26389E+04 145 pyrite -21.25 -22.33 -1.09 -0.256 0.18562E+04 146 pyrrhotite -4.26 -6.52 -2.25 -0.752 0.38503E+04 147 pyrrhotiteFe0.875 -6.02 -7.68 -1.66 -0.610 0.28320E+04 148 pyroxmangite 7.40 6.21 -1.19 -0.238 0.20352E+04 149 pyrophyllite -6.18 -11.05 -4.87 -0.305 0.83189E+04 154 rhodochrosite -0.98 -3.71 -2.73 -0.911 0.46690E+04 155 rhodonite 7.45 6.21 -1.24 -0.248 0.21155E+04 156 sanidine -1.28 -2.49 -1.22 -0.094 0.20781E+04 158 siderite -2.61 -6.30 -3.70 -1.232 0.63114E+04 166 stilbite -7.52 -7.91 -0.39 -0.018 0.66118E+03 168 stilpnomelane-Mg 27.44 24.31 -3.13 -0.093 0.53436E+04 174 talc 16.49 14.63 -1.86 -0.110 0.31837E+04 177 tephroite 18.09 15.40 -2.68 -0.383 0.45809E+04 181 tridymite -2.63 -2.99 -0.36 -0.121 0.61998E+03 182 tremolite 47.87 44.61 -3.26 -0.088 0.55729E+04 184 troilite-low -4.41 -6.52 -2.10 -0.701 0.35931E+04 190 wairakite 3.95 1.06 -2.89 -0.170 0.49371E+04 191 walstromite 11.51 9.12 -2.39 -0.478 0.40839E+04 192 wollastonite 10.46 9.12 -1.34 -0.269 0.22943E+04 193 pseudo-wollastonite 11.00 9.12 -1.88 -0.376 0.32141E+04 195 akaganeite 7.75 5.25 -2.50 -0.541 0.42732E+04 202 chalcedony -2.80 -2.99 -0.19 -0.062 0.31930E+03 204 montmorillonite-Ca -2.29 -6.28 -3.99 -0.247 0.68049E+04 205 montmorillonite-K -2.24 -6.29 -4.05 -0.248 0.69155E+04 206 montmorillonite-Mg -2.48 -6.81 -4.33 -0.268 0.73963E+04 207 montmorillonite-Na -2.04 -5.59 -3.55 -0.218 0.60670E+04 208 nontronite-Ca 3.21 1.68 -1.53 -0.100 0.26195E+04 209 nontronite-H 2.53 -0.32 -2.85 -0.191 0.48662E+04 210 nontronite-K 3.34 1.67 -1.67 -0.107 0.28533E+04 211 nontronite-Mg 3.07 1.14 -1.93 -0.125 0.32949E+04 212 nontronite-Na 3.52 2.37 -1.15 -0.074 0.19708E+04 228 tobermorite 9.82 7.10 -2.73 -0.744 0.46570E+04 234 alabandite -0.98 -3.92 -2.94 -0.981 0.50263E+04 237 boehmite 4.41 0.45 -3.95 -0.659 0.67469E+04 239 ferrous-oxide 9.81 6.60 -3.21 -0.802 0.54795E+04 245 silica-amorphous -2.09 -2.99 -0.90 -0.299 0.15335E+04 247 an20ab80 2.02 1.10 -0.92 -0.071 0.15663E+04 248 an25ab75 2.65 1.47 -1.17 -0.090 0.20048E+04 249 an30ab70 3.28 1.84 -1.44 -0.111 0.24529E+04 250 tr.625ac.25prg.125 45.16 42.61 -2.56 -0.069 0.43653E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 0.0010000 MOLES Current total amount of reactant added: 0.0319900 MOLES New total amount of reactant added: 0.0329900 MOLES Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.5508E-08 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 7 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 0.0329900 Water: Moles liquid = 0.4988E+02 kg liquid = 0.8986E+00 Moles total = 0.4987E+02 kg total = 0.8985E+00 Activity = 1.0000 Stoichiometric ionic strength = .1345729E-01 Osmotic coef. = 0.9349 True ionic strength = .2190258E-01 Chg. balance for total moles = -.5508E-08 Max. difference allowed = 0.3325E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.14996E-09 -9.8240 0.12530E-09 -9.9020 0.83556E+00 -0.0780 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.36834E-03 -3.4337 0.30579E-03 -3.5146 0.83017E+00 -0.0808 4 SO4-- 0.15848E-03 -3.8000 0.80371E-04 -4.0949 0.50713E+00 -0.2949 5 HCO3- 0.12437E-02 -2.9053 0.10341E-02 -2.9854 0.83148E+00 -0.0802 6 HS- 0.76156E-03 -3.1183 0.63232E-03 -3.1991 0.83030E+00 -0.0808 7 Al+++ 0.25858E-28 -28.5874 0.56573E-29 -29.2474 0.21878E+00 -0.6600 8 H4SiO4 0.10246E-02 -2.9894 0.10246E-02 -2.9894 0.10000E+01 0.0000 9 Ca++ 0.38427E-07 -7.4154 0.19334E-07 -7.7137 0.50313E+00 -0.2983 10 Mg++ 0.22302E-10 -10.6517 0.11166E-10 -10.9521 0.50066E+00 -0.3005 11 Fe++ 0.12508E-12 -12.9028 0.62695E-13 -13.2028 0.50125E+00 -0.2999 12 K+ 0.15652E-03 -3.8054 0.13018E-03 -3.8855 0.83169E+00 -0.0800 13 Na+ 0.20163E-01 -1.6955 0.16735E-01 -1.7764 0.83001E+00 -0.0809 14 Mn++ 0.49031E-10 -10.3095 0.24598E-10 -10.6091 0.50169E+00 -0.2996 15 F- 0.14748E-04 -4.8313 0.12217E-04 -4.9131 0.82834E+00 -0.0818 16 HPO4-- 0.45673E-07 -7.3403 0.23166E-07 -7.6352 0.50721E+00 -0.2948 18 HSiO3- 0.91975E-02 -2.0363 0.76355E-02 -2.1172 0.83017E+00 -0.0808 19 Ca(HSiO3)+ 0.40414E-08 -8.3935 0.33619E-08 -8.4734 0.83188E+00 -0.0799 20 Mg(HSiO3)+ 0.29047E-11 -11.5369 0.24163E-11 -11.6168 0.83188E+00 -0.0799 21 NaHSiO3,aq 0.20667E-02 -2.6847 0.20667E-02 -2.6847 0.10000E+01 0.0000 22 AlO+ 0.58929E-16 -16.2297 0.49021E-16 -16.3096 0.83188E+00 -0.0799 24 HAlO2,aq 0.77913E-10 -10.1084 0.77913E-10 -10.1084 0.10000E+01 0.0000 25 AlO2- 0.16612E-05 -5.7796 0.13764E-05 -5.8612 0.82857E+00 -0.0817 26 CH4,aq 0.79353E-08 -8.1004 0.79028E-08 -8.1022 0.99591E+00 -0.0018 27 C2H6,aq 0.56205E-19 -19.2502 0.55975E-19 -19.2520 0.99591E+00 -0.0018 31 CO,aq 0.13266E-14 -14.8772 0.13266E-14 -14.8772 0.10000E+01 0.0000 32 CO2,aq 0.27800E-06 -6.5560 0.27686E-06 -6.5577 0.99591E+00 -0.0018 33 CO3-2 0.14247E-02 -2.8463 0.72085E-03 -3.1422 0.50597E+00 -0.2959 34 CaCO3,aq 0.17475E-06 -6.7576 0.17475E-06 -6.7576 0.10000E+01 0.0000 35 Ca(HCO3)+ 0.61347E-09 -9.2122 0.51033E-09 -9.2922 0.83188E+00 -0.0799 36 CaCl+ 0.11501E-10 -10.9393 0.95674E-11 -11.0192 0.83188E+00 -0.0799 37 CaCl2,aq 0.69507E-15 -15.1580 0.69507E-15 -15.1580 0.10000E+01 0.0000 38 CaF+ 0.41453E-11 -11.3824 0.34484E-11 -11.4624 0.83188E+00 -0.0799 39 CaOH+ 0.13219E-07 -7.8788 0.10997E-07 -7.9587 0.83188E+00 -0.0799 40 CaSO4,aq 0.49342E-09 -9.3068 0.49342E-09 -9.3068 0.10000E+01 0.0000 41 HCl,aq 0.70211E-14 -14.1536 0.70211E-14 -14.1536 0.10000E+01 0.0000 45 HF,aq 0.10479E-10 -10.9797 0.10479E-10 -10.9797 0.10000E+01 0.0000 46 HF2- 0.52063E-16 -16.2835 0.43221E-16 -16.3643 0.83017E+00 -0.0808 48 FeCl+ 0.36478E-16 -16.4380 0.30345E-16 -16.5179 0.83188E+00 -0.0799 51 FeF+ 0.47049E-16 -16.3274 0.39139E-16 -16.4074 0.83188E+00 -0.0799 53 FeO,aq 0.15520E-09 -9.8091 0.15520E-09 -9.8091 0.10000E+01 0.0000 54 FeOH+ 0.19579E-10 -10.7082 0.16287E-10 -10.7882 0.83188E+00 -0.0799 55 HFeO2- 0.15611E-07 -7.8066 0.12960E-07 -7.8874 0.83017E+00 -0.0808 56 FeO+ 0.10693E-15 -15.9709 0.88949E-16 -16.0509 0.83188E+00 -0.0799 58 FeO2- 0.13964E-08 -8.8550 0.11593E-08 -8.9358 0.83017E+00 -0.0808 59 HFeO2,aq 0.18475E-10 -10.7334 0.18475E-10 -10.7334 0.10000E+01 0.0000 60 H2,aq 0.19153E-06 -6.7178 0.19075E-06 -6.7195 0.99591E+00 -0.0018 61 KCl,aq 0.72146E-09 -9.1418 0.72146E-09 -9.1418 0.10000E+01 0.0000 62 KHSO4,aq 0.37065E-17 -17.4310 0.37065E-17 -17.4310 0.10000E+01 0.0000 63 KOH,aq 0.44368E-06 -6.3529 0.44368E-06 -6.3529 0.10000E+01 0.0000 64 KSO4- 0.19556E-06 -6.7087 0.16235E-06 -6.7895 0.83017E+00 -0.0808 65 MgCO3,aq 0.25297E-10 -10.5969 0.25297E-10 -10.5969 0.10000E+01 0.0000 66 Mg(HCO3)+ 0.36202E-12 -12.4413 0.30115E-12 -12.5212 0.83188E+00 -0.0799 67 MgCl+ 0.60200E-14 -14.2204 0.50079E-14 -14.3003 0.83188E+00 -0.0799 68 MgF+ 0.88681E-14 -14.0522 0.73772E-14 -14.1321 0.83188E+00 -0.0799 69 MgOH+ 0.42245E-10 -10.3742 0.35142E-10 -10.4542 0.83188E+00 -0.0799 71 MnF+ 0.60846E-14 -14.2158 0.50616E-14 -14.2957 0.83188E+00 -0.0799 72 MnO,aq 0.16225E-08 -8.7898 0.16225E-08 -8.7898 0.10000E+01 0.0000 73 MnOH+ 0.71361E-09 -9.1465 0.59364E-09 -9.2265 0.83188E+00 -0.0799 74 MnO2-2 0.67785E-11 -11.1689 0.34298E-11 -11.4647 0.50597E+00 -0.2959 75 HMnO2- 0.11341E-09 -9.9453 0.94151E-10 -10.0262 0.83017E+00 -0.0808 78 MnCl+ 0.55681E-13 -13.2543 0.46319E-13 -13.3342 0.83188E+00 -0.0799 79 MnSO4,aq 0.57075E-12 -12.2436 0.57075E-12 -12.2436 0.10000E+01 0.0000 80 NaCl,aq 0.16959E-05 -5.7706 0.16959E-05 -5.7706 0.10000E+01 0.0000 81 NaF,aq 0.47864E-07 -7.3200 0.47864E-07 -7.3200 0.10000E+01 0.0000 82 NaOH,aq 0.57384E-04 -4.2412 0.57384E-04 -4.2412 0.10000E+01 0.0000 84 OH- 0.55652E-02 -2.2545 0.46111E-02 -2.3362 0.82857E+00 -0.0817 89 HPO3-2 0.27215E-16 -16.5652 0.13770E-16 -16.8611 0.50597E+00 -0.2959 92 H3PO4,aq 0.25437E-17 -17.5945 0.25437E-17 -17.5945 0.10000E+01 0.0000 93 H2PO4- 0.64434E-10 -10.1909 0.53546E-10 -10.2713 0.83102E+00 -0.0804 94 PO4-3 0.65410E-09 -9.1844 0.15084E-09 -9.8215 0.23061E+00 -0.6371 98 HP2O7-3 0.16357E-17 -17.7863 0.35826E-18 -18.4458 0.21902E+00 -0.6595 99 P2O7-4 0.97389E-17 -17.0115 0.68306E-18 -18.1655 0.70137E-01 -1.1541 100 H2S,aq 0.24588E-06 -6.6093 0.24487E-06 -6.6111 0.99591E+00 -0.0018 101 S2-2 0.91797E-10 -10.0372 0.46447E-10 -10.3330 0.50597E+00 -0.2959 102 S3-2 0.15877E-15 -15.7992 0.80332E-16 -16.0951 0.50597E+00 -0.2959 103 S3- 0.18609E-19 -19.7303 0.15449E-19 -19.8111 0.83017E+00 -0.0808 107 SO3-2 0.38772E-11 -11.4115 0.19922E-11 -11.7007 0.51383E+00 -0.2892 108 HSO3- 0.18827E-13 -13.7252 0.15629E-13 -13.8061 0.83017E+00 -0.0808 109 HSO4- 0.11654E-10 -10.9335 0.97052E-11 -11.0130 0.83275E+00 -0.0795 111 S2O3-2 0.45691E-12 -12.3402 0.23118E-12 -12.6360 0.50597E+00 -0.2959 Charge balance for all species = -.6129E-08 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.1499593E-09 -.1831834E-01 -.1843072E+02 0.0000 2 H2O 0.1000000E+01 0.5550261E+02 0.9981054E+06 0.0000 3 Cl- 0.3683441E-03 0.3700408E-03 0.1309556E+02 6.3875 4 SO4-- 0.1584834E-03 0.1586238E-03 0.1521037E+02 15.7092 5 HCO3- 0.1243671E-02 0.2668818E-02 0.1625521E+03 6.9166 6 HS- 0.7615565E-03 0.7618582E-03 0.2515105E+02 6.7030 7 Al+++ 0.2585828E-28 0.1661297E-05 0.4474400E-01 0.4588 8 H4SiO4 0.1024625E-02 0.1228887E-01 0.1179034E+04 -2.9894 9 Ca++ 0.3842655E-07 0.2315595E-06 0.9263822E-02 12.0904 10 Mg++ 0.2230158E-10 0.9312445E-10 0.2259987E-05 8.8520 11 Fe++ 0.1250772E-12 0.1720093E-07 0.9588998E-03 6.6013 12 K+ 0.1565211E-03 0.1571610E-03 0.6134304E+01 6.0166 13 Na+ 0.2016271E-01 0.2228854E-01 0.5114913E+03 8.1257 14 Mn++ 0.4903059E-10 0.2506003E-08 0.1374282E-03 9.1950 15 F- 0.1474818E-04 0.1479606E-04 0.2805921E+00 4.9890 16 HPO4-- 0.4567293E-07 0.4639146E-07 0.4444632E-02 12.1689 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.1647434E-01 -.1646118E-01 -.1315906E-04 0.0000000E+00 2 H2O 0.4987342E+02 0.4987563E+02 -.2213455E-02 0.0000000E+00 3 Cl- 0.3325252E-03 0.3325252E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.1425422E-03 0.1425422E-03 0.0000000E+00 0.0000000E+00 5 HCO3- 0.2398247E-02 0.2398247E-02 0.0000000E+00 0.0000000E+00 6 HS- 0.6846193E-03 0.6846193E-03 0.0000000E+00 0.0000000E+00 7 Al+++ 0.4775352E-05 0.1492871E-05 0.3282481E-05 0.0000000E+00 8 H4SiO4 0.1215302E-01 0.1104299E-01 0.1110028E-02 0.0000000E+00 9 Ca++ 0.2080835E-06 0.2080835E-06 0.0000000E+00 0.0000000E+00 10 Mg++ 0.8368328E-10 0.8368328E-10 0.0000000E+00 0.0000000E+00 11 Fe++ 0.3259227E-07 0.1545706E-07 0.1713521E-07 0.0000000E+00 12 K+ 0.1412294E-03 0.1412277E-03 0.1713521E-08 0.0000000E+00 13 Na+ 0.2003215E-01 0.2002887E-01 0.3275627E-05 0.0000000E+00 14 Mn++ 0.2251939E-08 0.2251939E-08 0.0000000E+00 0.0000000E+00 15 F- 0.1329600E-04 0.1329600E-04 0.0000000E+00 0.0000000E+00 16 HPO4-- 0.4168819E-07 0.4168819E-07 0.0000000E+00 0.0000000E+00 Chg. balance for solid moles: 0.1694E-20 Mass of aqueous solution: 0.900230E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 0.0329900 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 0.3276E-05 -5.485 0.8589E-03 -3.066 1.283 0.3297E-03 quartz 0.1100E-02 -2.959 0.6610E-01 -1.180 98.71 0.2496E-01 stilpnomelane-Fe 0.3427E-08 -8.465 0.3694E-05 -5.432 0.5517E-02 0.1276E-05 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 quartz 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 0.066961 g Volume = 0.025293 cm3 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.0329900 moles log = -1.4816 Original solution: 1000.0103000 g Original solution / Rock added: 30312.53 (Water/Rock Ratio), log = 4.4816 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0206 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9997E+00 0.9859 0.1006E+01 0.1020E+01 CO2,gas 0.2882E-04 1.0071 0.2962E-04 0.2941E-04 CH4,gas 0.1126E-04 1.0125 0.1163E-04 0.1149E-04 H2,gas 0.2452E-03 1.0005 0.2504E-03 0.2503E-03 H2S,gas 0.6622E-05 0.9960 0.6731E-05 0.6758E-05 S2,gas 0.2657E-22 1.0000 0.2712E-22 0.2712E-22 CO,gas 0.1937E-11 1.0000 0.1977E-11 0.1977E-11 SO3,gas 0.4675E-39 1.0000 0.4771E-39 0.4771E-39 SO2,gas 0.4555E-20 1.0000 0.4648E-20 0.4648E-20 HF,gas 0.2521E-13 1.0000 0.2573E-13 0.2573E-13 HCl,gas 0.1214E-16 1.0000 0.1239E-16 0.1239E-16 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 17 albite -0.38 -0.38 0.00 0.000 0.11184E-10 150 quartz -2.99 -2.99 0.00 0.000 0.00000E+00 167 stilpnomelane-Fe 13.02 13.02 0.00 0.000 -0.27298E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -12.89 -6.23 -2.076 0.10633E+05 -4.528 3 CH4,gas 4.54 -2.09 -6.63 -1.658 0.11326E+05 -4.934 4 H2,gas 8.00 2.70 -5.30 -3.029 0.90501E+04 -3.601 5 H2S,gas -6.23 -13.10 -6.87 -3.435 0.11732E+05 -5.172 6 S2,gas -7.34 -31.60 -24.27 -3.733 0.41433E+05 -22.567 7 CO,gas 3.21 -10.19 -13.40 -4.124 0.22885E+05 -11.704 8 SO3,gas 17.12 -23.90 -41.02 -10.255 0.70041E+05 -39.321 9 SO2,gas 0.83 -21.20 -22.03 -5.875 0.37618E+05 -20.333 10 HF,gas 0.47 -14.82 -15.29 -7.644 0.26105E+05 -13.590 11 HCl,gas 5.19 -13.42 -18.61 -9.303 0.31769E+05 -16.907 12 acmite 7.71 7.40 -0.31 -0.032 0.53155E+03 16 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 20 spessartine 24.46 19.53 -4.92 -0.246 0.84061E+04 21 analcite 3.32 2.61 -0.72 -0.080 0.12231E+04 23 andradite 39.01 37.81 -1.20 -0.062 0.20535E+04 24 grossular 32.73 28.22 -4.51 -0.226 0.77024E+04 26 ankerite -2.14 -7.08 -4.95 -0.825 0.84489E+04 27 annite 20.12 17.31 -2.81 -0.156 0.48021E+04 28 phlogopite 27.06 24.06 -3.00 -0.167 0.51252E+04 33 apatite-OH -18.15 -21.87 -3.71 -0.286 0.63385E+04 34 apatite-F -34.30 -36.68 -2.38 -0.198 0.40635E+04 38 aragonite 0.97 -0.80 -1.76 -0.588 0.30113E+04 39 brucite 12.57 8.85 -3.72 -0.743 0.63460E+04 40 calcite 0.81 -0.80 -1.61 -0.536 0.27471E+04 41 carnegieite-low 9.02 5.60 -3.43 -0.490 0.58537E+04 42 carnegieite-high 10.09 5.60 -4.50 -0.643 0.76807E+04 43 carpholite-Mg 8.58 3.79 -4.79 -0.319 0.81813E+04 45 celadonite 5.34 3.37 -1.97 -0.116 0.33672E+04 46 celadonite-Fe 3.88 1.12 -2.76 -0.162 0.47085E+04 47 chrysotile 23.89 20.58 -3.32 -0.276 0.56608E+04 49 clinochlore 39.07 36.21 -2.86 -0.089 0.48841E+04 50 daphnite 28.97 24.96 -4.01 -0.125 0.68459E+04 54 chloritoid-Fe 9.17 4.53 -4.64 -0.310 0.79299E+04 55 chloritoid-Mn 11.40 7.12 -4.28 -0.285 0.73045E+04 57 coesite -2.38 -2.99 -0.61 -0.204 0.10473E+04 64 cristobalite -2.56 -2.99 -0.43 -0.143 0.73267E+03 66 cymrite-K 1.69 -2.49 -4.18 -0.348 0.71344E+04 68 diaspore 2.87 0.46 -2.41 -0.402 0.41234E+04 69 diamond -3.10 -7.49 -4.39 -1.253 0.74893E+04 70 diopside 16.18 14.96 -1.22 -0.122 0.20794E+04 71 hedenbergite 14.21 12.71 -1.50 -0.150 0.25534E+04 78 epidote 24.67 21.38 -3.29 -0.159 0.56147E+04 80 epidote-Fe 29.84 26.17 -3.67 -0.190 0.62602E+04 81 fayalite 14.05 10.21 -3.83 -0.548 0.65439E+04 82 ferrosilite 11.15 7.22 -3.93 -0.393 0.67030E+04 86 gibbsite 4.08 0.46 -3.62 -0.517 0.61820E+04 87 glaucophane 22.97 19.81 -3.17 -0.086 0.54050E+04 88 glaucophane-Fe 17.28 13.06 -4.22 -0.114 0.72029E+04 89 graphite -3.55 -7.49 -3.94 -1.126 0.67315E+04 90 greenalite 16.14 13.83 -2.31 -0.193 0.39518E+04 93 hematite 12.57 10.50 -2.06 -0.250 0.35225E+04 94 heulandite -5.83 -7.92 -2.09 -0.095 0.35701E+04 98 jadeite 4.22 2.61 -1.61 -0.161 0.27485E+04 100 kalsilite 7.58 3.49 -4.10 -0.585 0.69972E+04 101 kaolinite -1.33 -5.06 -3.73 -0.339 0.63665E+04 104 laumontite 2.88 1.05 -1.83 -0.122 0.31302E+04 105 lawsonite 9.62 7.03 -2.59 -0.172 0.44173E+04 106 leucite 4.12 0.50 -3.62 -0.362 0.61851E+04 108 lizardite 23.24 20.58 -2.67 -0.222 0.45535E+04 109 magnesite 0.69 -4.04 -4.73 -1.575 0.80697E+04 110 magnetite 20.09 17.10 -2.98 -0.244 0.50932E+04 111 minnesotaite 10.39 7.85 -2.54 -0.150 0.43402E+04 115 manganosite 14.06 9.20 -4.86 -1.216 0.83036E+04 119 microcline -2.49 -2.49 -0.01 0.000 0.11050E+02 123 muscovite 2.58 -1.58 -4.16 -0.245 0.70995E+04 124 paragonite 4.24 0.53 -3.71 -0.218 0.63275E+04 125 nepheline 8.34 5.60 -2.74 -0.392 0.46861E+04 137 phlogopite-Na 29.65 26.17 -3.47 -0.193 0.59330E+04 139 prehnite 19.37 16.13 -3.24 -0.191 0.55354E+04 140 prehnite-Fe 22.50 20.92 -1.58 -0.095 0.26893E+04 145 pyrite -21.25 -22.30 -1.05 -0.248 0.17987E+04 146 pyrrhotite -4.26 -6.50 -2.24 -0.746 0.38238E+04 147 pyrrhotiteFe0.875 -6.02 -7.66 -1.64 -0.604 0.28049E+04 148 pyroxmangite 7.40 6.21 -1.19 -0.239 0.20372E+04 149 pyrophyllite -6.18 -11.04 -4.86 -0.304 0.83059E+04 154 rhodochrosite -0.98 -3.69 -2.72 -0.905 0.46378E+04 155 rhodonite 7.45 6.21 -1.24 -0.248 0.21175E+04 156 sanidine -1.28 -2.49 -1.22 -0.094 0.20788E+04 158 siderite -2.61 -6.29 -3.68 -1.226 0.62801E+04 166 stilbite -7.52 -7.92 -0.40 -0.019 0.67628E+03 168 stilpnomelane-Mg 27.44 24.27 -3.17 -0.095 0.54147E+04 174 talc 16.49 14.60 -1.89 -0.111 0.32320E+04 177 tephroite 18.09 15.40 -2.69 -0.384 0.45849E+04 181 tridymite -2.63 -2.99 -0.36 -0.121 0.61998E+03 182 tremolite 47.87 44.53 -3.34 -0.090 0.57099E+04 184 troilite-low -4.41 -6.50 -2.09 -0.696 0.35666E+04 190 wairakite 3.95 1.05 -2.90 -0.171 0.49521E+04 191 walstromite 11.51 9.10 -2.41 -0.482 0.41120E+04 192 wollastonite 10.46 9.10 -1.36 -0.272 0.23225E+04 193 pseudo-wollastonite 11.00 9.10 -1.90 -0.380 0.32423E+04 195 akaganeite 7.75 5.25 -2.50 -0.541 0.42738E+04 202 chalcedony -2.80 -2.99 -0.19 -0.062 0.31930E+03 204 montmorillonite-Ca -2.29 -6.28 -3.98 -0.247 0.68040E+04 205 montmorillonite-K -2.24 -6.28 -4.05 -0.248 0.69123E+04 206 montmorillonite-Mg -2.48 -6.81 -4.33 -0.268 0.73934E+04 207 montmorillonite-Na -2.04 -5.59 -3.55 -0.217 0.60636E+04 208 nontronite-Ca 3.21 1.68 -1.54 -0.100 0.26231E+04 209 nontronite-H 2.53 -0.32 -2.85 -0.191 0.48652E+04 210 nontronite-K 3.34 1.67 -1.67 -0.107 0.28547E+04 211 nontronite-Mg 3.07 1.14 -1.93 -0.125 0.32966E+04 212 nontronite-Na 3.52 2.36 -1.15 -0.074 0.19719E+04 228 tobermorite 9.82 7.08 -2.74 -0.748 0.46805E+04 234 alabandite -0.98 -3.91 -2.93 -0.976 0.49999E+04 237 boehmite 4.41 0.46 -3.95 -0.658 0.67404E+04 239 ferrous-oxide 9.81 6.60 -3.21 -0.803 0.54814E+04 245 silica-amorphous -2.09 -2.99 -0.90 -0.299 0.15335E+04 247 an20ab80 2.02 1.10 -0.92 -0.071 0.15693E+04 248 an25ab75 2.65 1.47 -1.18 -0.090 0.20086E+04 249 an30ab70 3.28 1.84 -1.44 -0.111 0.24575E+04 250 tr.625ac.25prg.125 45.16 42.54 -2.62 -0.071 0.44808E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 0.0010000 MOLES Current total amount of reactant added: 0.0329900 MOLES New total amount of reactant added: 0.0339900 MOLES Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.5508E-08 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 7 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 0.0339900 Water: Moles liquid = 0.4988E+02 kg liquid = 0.8986E+00 Moles total = 0.4987E+02 kg total = 0.8985E+00 Activity = 1.0000 Stoichiometric ionic strength = .1352225E-01 Osmotic coef. = 0.9347 True ionic strength = .2196291E-01 Chg. balance for total moles = -.5508E-08 Max. difference allowed = 0.3384E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.15143E-09 -9.8198 0.12651E-09 -9.8979 0.83542E+00 -0.0781 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.37487E-03 -3.4261 0.31115E-03 -3.5070 0.83002E+00 -0.0809 4 SO4-- 0.16379E-03 -3.7857 0.83000E-04 -4.0809 0.50675E+00 -0.2952 5 HCO3- 0.12873E-02 -2.8903 0.10702E-02 -2.9705 0.83132E+00 -0.0802 6 HS- 0.78326E-03 -3.1061 0.65022E-03 -3.1869 0.83015E+00 -0.0808 7 Al+++ 0.26896E-28 -28.5703 0.58743E-29 -29.2310 0.21841E+00 -0.6607 8 H4SiO4 0.10246E-02 -2.9894 0.10246E-02 -2.9894 0.10000E+01 0.0000 9 Ca++ 0.37757E-07 -7.4230 0.18982E-07 -7.7216 0.50275E+00 -0.2986 10 Mg++ 0.22261E-10 -10.6525 0.11137E-10 -10.9533 0.50028E+00 -0.3008 11 Fe++ 0.12727E-12 -12.8953 0.63745E-13 -13.1956 0.50087E+00 -0.3003 12 K+ 0.15652E-03 -3.8054 0.13015E-03 -3.8856 0.83153E+00 -0.0801 13 Na+ 0.20181E-01 -1.6951 0.16747E-01 -1.7761 0.82985E+00 -0.0810 14 Mn++ 0.49881E-10 -10.3021 0.25006E-10 -10.6020 0.50131E+00 -0.2999 15 F- 0.15192E-04 -4.8184 0.12581E-04 -4.9003 0.82818E+00 -0.0819 16 HPO4-- 0.45677E-07 -7.3403 0.23151E-07 -7.6354 0.50683E+00 -0.2951 18 HSiO3- 0.91115E-02 -2.0404 0.75627E-02 -2.1213 0.83002E+00 -0.0809 19 Ca(HSiO3)+ 0.39308E-08 -8.4055 0.32693E-08 -8.4855 0.83173E+00 -0.0800 20 Mg(HSiO3)+ 0.28700E-11 -11.5421 0.23870E-11 -11.6221 0.83173E+00 -0.0800 21 NaHSiO3,aq 0.20485E-02 -2.6886 0.20485E-02 -2.6886 0.10000E+01 0.0000 22 AlO+ 0.60038E-16 -16.2216 0.49935E-16 -16.3016 0.83173E+00 -0.0800 24 HAlO2,aq 0.78607E-10 -10.1045 0.78607E-10 -10.1045 0.10000E+01 0.0000 25 AlO2- 0.16603E-05 -5.7798 0.13754E-05 -5.8616 0.82841E+00 -0.0818 26 CH4,aq 0.81774E-08 -8.0874 0.81438E-08 -8.0892 0.99589E+00 -0.0018 27 C2H6,aq 0.59893E-19 -19.2226 0.59647E-19 -19.2244 0.99589E+00 -0.0018 31 CO,aq 0.13814E-14 -14.8597 0.13814E-14 -14.8597 0.10000E+01 0.0000 32 CO2,aq 0.29048E-06 -6.5369 0.28929E-06 -6.5387 0.99589E+00 -0.0018 33 CO3-2 0.14614E-02 -2.8352 0.73890E-03 -3.1314 0.50560E+00 -0.2962 34 CaCO3,aq 0.17587E-06 -6.7548 0.17587E-06 -6.7548 0.10000E+01 0.0000 35 Ca(HCO3)+ 0.62346E-09 -9.2052 0.51855E-09 -9.2852 0.83173E+00 -0.0800 36 CaCl+ 0.11492E-10 -10.9396 0.95583E-11 -11.0196 0.83173E+00 -0.0800 37 CaCl2,aq 0.70658E-15 -15.1508 0.70658E-15 -15.1508 0.10000E+01 0.0000 38 CaF+ 0.41923E-11 -11.3775 0.34869E-11 -11.4576 0.83173E+00 -0.0800 39 CaOH+ 0.12858E-07 -7.8908 0.10694E-07 -7.9709 0.83173E+00 -0.0800 40 CaSO4,aq 0.50031E-09 -9.3008 0.50031E-09 -9.3008 0.10000E+01 0.0000 41 HCl,aq 0.72131E-14 -14.1419 0.72131E-14 -14.1419 0.10000E+01 0.0000 45 HF,aq 0.10896E-10 -10.9627 0.10896E-10 -10.9627 0.10000E+01 0.0000 46 HF2- 0.55762E-16 -16.2537 0.46283E-16 -16.3346 0.83002E+00 -0.0809 48 FeCl+ 0.37746E-16 -16.4231 0.31394E-16 -16.5031 0.83173E+00 -0.0800 51 FeF+ 0.49275E-16 -16.3074 0.40983E-16 -16.3874 0.83173E+00 -0.0800 53 FeO,aq 0.15480E-09 -9.8102 0.15480E-09 -9.8102 0.10000E+01 0.0000 54 FeOH+ 0.19720E-10 -10.7051 0.16402E-10 -10.7851 0.83173E+00 -0.0800 55 HFeO2- 0.15425E-07 -7.8118 0.12803E-07 -7.8927 0.83002E+00 -0.0809 56 FeO+ 0.10789E-15 -15.9670 0.89731E-16 -16.0471 0.83173E+00 -0.0800 58 FeO2- 0.13822E-08 -8.8594 0.11473E-08 -8.9403 0.83002E+00 -0.0809 59 HFeO2,aq 0.18459E-10 -10.7338 0.18459E-10 -10.7338 0.10000E+01 0.0000 60 H2,aq 0.19087E-06 -6.7193 0.19009E-06 -6.7211 0.99589E+00 -0.0018 61 KCl,aq 0.73395E-09 -9.1343 0.73395E-09 -9.1343 0.10000E+01 0.0000 62 KHSO4,aq 0.38638E-17 -17.4130 0.38638E-17 -17.4130 0.10000E+01 0.0000 63 KOH,aq 0.43935E-06 -6.3572 0.43935E-06 -6.3572 0.10000E+01 0.0000 64 KSO4- 0.20195E-06 -6.6947 0.16763E-06 -6.7757 0.83002E+00 -0.0809 65 MgCO3,aq 0.25863E-10 -10.5873 0.25863E-10 -10.5873 0.10000E+01 0.0000 66 Mg(HCO3)+ 0.37375E-12 -12.4274 0.31086E-12 -12.5074 0.83173E+00 -0.0800 67 MgCl+ 0.61108E-14 -14.2139 0.50825E-14 -14.2939 0.83173E+00 -0.0800 68 MgF+ 0.91109E-14 -14.0404 0.75777E-14 -14.1205 0.83173E+00 -0.0800 69 MgOH+ 0.41740E-10 -10.3794 0.34717E-10 -10.4595 0.83173E+00 -0.0800 71 MnF+ 0.63713E-14 -14.1958 0.52991E-14 -14.2758 0.83173E+00 -0.0800 72 MnO,aq 0.16181E-08 -8.7910 0.16181E-08 -8.7910 0.10000E+01 0.0000 73 MnOH+ 0.71864E-09 -9.1435 0.59771E-09 -9.2235 0.83173E+00 -0.0800 74 MnO2-2 0.66364E-11 -11.1781 0.33554E-11 -11.4743 0.50560E+00 -0.2962 75 HMnO2- 0.11204E-09 -9.9506 0.92997E-10 -10.0315 0.83002E+00 -0.0809 78 MnCl+ 0.57606E-13 -13.2395 0.47912E-13 -13.3196 0.83173E+00 -0.0800 79 MnSO4,aq 0.59918E-12 -12.2224 0.59918E-12 -12.2224 0.10000E+01 0.0000 80 NaCl,aq 0.17269E-05 -5.7627 0.17269E-05 -5.7627 0.10000E+01 0.0000 81 NaF,aq 0.49329E-07 -7.3069 0.49329E-07 -7.3069 0.10000E+01 0.0000 82 NaOH,aq 0.56877E-04 -4.2451 0.56877E-04 -4.2451 0.10000E+01 0.0000 84 OH- 0.55131E-02 -2.2586 0.45671E-02 -2.3404 0.82841E+00 -0.0818 89 HPO3-2 0.27124E-16 -16.5666 0.13714E-16 -16.8628 0.50560E+00 -0.2962 92 H3PO4,aq 0.25913E-17 -17.5865 0.25913E-17 -17.5865 0.10000E+01 0.0000 93 H2PO4- 0.65025E-10 -10.1869 0.54027E-10 -10.2674 0.83086E+00 -0.0805 94 PO4-3 0.64846E-09 -9.1881 0.14931E-09 -9.8259 0.23025E+00 -0.6378 98 HP2O7-3 0.16521E-17 -17.7820 0.36125E-18 -18.4422 0.21866E+00 -0.6602 99 P2O7-4 0.97550E-17 -17.0108 0.68218E-18 -18.1661 0.69931E-01 -1.1553 100 H2S,aq 0.25528E-06 -6.5930 0.25423E-06 -6.5948 0.99589E+00 -0.0018 101 S2-2 0.97476E-10 -10.0111 0.49284E-10 -10.3073 0.50560E+00 -0.2962 102 S3-2 0.17564E-15 -15.7554 0.88803E-16 -16.0516 0.50560E+00 -0.2962 103 S3- 0.20810E-19 -19.6817 0.17272E-19 -19.7626 0.83002E+00 -0.0809 107 SO3-2 0.39930E-11 -11.3987 0.20502E-11 -11.6882 0.51346E+00 -0.2895 108 HSO3- 0.19566E-13 -13.7085 0.16240E-13 -13.7894 0.83002E+00 -0.0809 109 HSO4- 0.12154E-10 -10.9153 0.10119E-10 -10.9949 0.83260E+00 -0.0796 111 S2O3-2 0.49025E-12 -12.3096 0.24787E-12 -12.6058 0.50560E+00 -0.2962 Charge balance for all species = -.6129E-08 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.1514306E-09 -.1819816E-01 -.1830985E+02 0.0000 2 H2O 0.1000000E+01 0.5550266E+02 0.9981090E+06 0.0000 3 Cl- 0.3748715E-03 0.3765992E-03 0.1332769E+02 6.3909 4 SO4-- 0.1637876E-03 0.1639344E-03 0.1571964E+02 15.7148 5 HCO3- 0.1287320E-02 0.2749222E-02 0.1674498E+03 6.9273 6 HS- 0.7832598E-03 0.7835709E-03 0.2586791E+02 6.7109 7 Al+++ 0.2689556E-28 0.1660421E-05 0.4472053E-01 0.4626 8 H4SiO4 0.1024625E-02 0.1218454E-01 0.1169028E+04 -2.9894 9 Ca++ 0.3775704E-07 0.2315551E-06 0.9263668E-02 12.0741 10 Mg++ 0.2226070E-10 0.9312266E-10 0.2259949E-05 8.8425 11 Fe++ 0.1272692E-12 0.1700069E-07 0.9477394E-03 6.6002 12 K+ 0.1565160E-03 0.1571580E-03 0.6134202E+01 6.0123 13 Na+ 0.2018100E-01 0.2228811E-01 0.5114828E+03 8.1218 14 Mn++ 0.4988086E-10 0.2505955E-08 0.1374260E-03 9.1938 15 F- 0.1519155E-04 0.1524089E-04 0.2890287E+00 4.9976 16 HPO4-- 0.4567708E-07 0.4639057E-07 0.4444558E-02 12.1603 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.1636667E-01 -.1635350E-01 -.1316239E-04 0.0000000E+00 2 H2O 0.4987424E+02 0.4987664E+02 -.2400527E-02 0.0000000E+00 3 Cl- 0.3384252E-03 0.3384252E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.1473172E-03 0.1473172E-03 0.0000000E+00 0.0000000E+00 5 HCO3- 0.2470547E-02 0.2470547E-02 0.0000000E+00 0.0000000E+00 6 HS- 0.7041443E-03 0.7041443E-03 0.0000000E+00 0.0000000E+00 7 Al+++ 0.4775352E-05 0.1492112E-05 0.3283240E-05 0.0000000E+00 8 H4SiO4 0.1215302E-01 0.1094946E-01 0.1203565E-02 0.0000000E+00 9 Ca++ 0.2080835E-06 0.2080835E-06 0.0000000E+00 0.0000000E+00 10 Mg++ 0.8368328E-10 0.8368328E-10 0.0000000E+00 0.0000000E+00 11 Fe++ 0.3259227E-07 0.1527741E-07 0.1731486E-07 0.0000000E+00 12 K+ 0.1412294E-03 0.1412277E-03 0.1731486E-08 0.0000000E+00 13 Na+ 0.2003215E-01 0.2002887E-01 0.3276314E-05 0.0000000E+00 14 Mn++ 0.2251939E-08 0.2251939E-08 0.0000000E+00 0.0000000E+00 15 F- 0.1369600E-04 0.1369600E-04 0.0000000E+00 0.0000000E+00 16 HPO4-- 0.4168819E-07 0.4168819E-07 0.0000000E+00 0.0000000E+00 Chg. balance for solid moles: -.4235E-21 Mass of aqueous solution: 0.900245E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 0.0339900 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 0.3276E-05 -5.485 0.8591E-03 -3.066 1.184 0.3298E-03 quartz 0.1194E-02 -2.923 0.7172E-01 -1.144 98.81 0.2708E-01 stilpnomelane-Fe 0.3463E-08 -8.461 0.3733E-05 -5.428 0.5143E-02 0.1289E-05 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 quartz 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 0.072581 g Volume = 0.027415 cm3 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.0339900 moles log = -1.4686 Original solution: 1000.0103000 g Original solution / Rock added: 29420.72 (Water/Rock Ratio), log = 4.4687 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0206 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9997E+00 0.9859 0.1006E+01 0.1020E+01 CO2,gas 0.3011E-04 1.0071 0.3095E-04 0.3073E-04 CH4,gas 0.1160E-04 1.0125 0.1199E-04 0.1184E-04 H2,gas 0.2444E-03 1.0005 0.2496E-03 0.2494E-03 H2S,gas 0.6875E-05 0.9960 0.6989E-05 0.7016E-05 S2,gas 0.2884E-22 1.0000 0.2944E-22 0.2944E-22 CO,gas 0.2017E-11 1.0000 0.2059E-11 0.2059E-11 SO3,gas 0.4921E-39 1.0000 0.5023E-39 0.5023E-39 SO2,gas 0.4778E-20 1.0000 0.4876E-20 0.4876E-20 HF,gas 0.2621E-13 1.0000 0.2675E-13 0.2675E-13 HCl,gas 0.1247E-16 1.0000 0.1273E-16 0.1273E-16 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 17 albite -0.38 -0.38 0.00 0.000 -0.13080E-10 150 quartz -2.99 -2.99 0.00 0.000 0.00000E+00 167 stilpnomelane-Fe 13.02 13.02 0.00 0.000 -0.27298E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -12.87 -6.21 -2.069 0.10601E+05 -4.509 3 CH4,gas 4.54 -2.08 -6.62 -1.655 0.11304E+05 -4.921 4 H2,gas 8.00 2.70 -5.30 -3.030 0.90527E+04 -3.603 5 H2S,gas -6.23 -13.08 -6.85 -3.427 0.11704E+05 -5.156 6 S2,gas -7.34 -31.57 -24.23 -3.728 0.41372E+05 -22.531 7 CO,gas 3.21 -10.17 -13.39 -4.119 0.22855E+05 -11.686 8 SO3,gas 17.12 -23.88 -41.00 -10.250 0.70003E+05 -39.299 9 SO2,gas 0.83 -21.18 -22.01 -5.870 0.37583E+05 -20.312 10 HF,gas 0.47 -14.80 -15.27 -7.636 0.26076E+05 -13.573 11 HCl,gas 5.19 -13.40 -18.59 -9.297 0.31749E+05 -16.895 12 acmite 7.71 7.39 -0.32 -0.033 0.53875E+03 16 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 20 spessartine 24.46 19.54 -4.92 -0.246 0.83990E+04 21 analcite 3.32 2.61 -0.72 -0.080 0.12231E+04 23 andradite 39.01 37.76 -1.25 -0.065 0.21382E+04 24 grossular 32.73 28.18 -4.55 -0.228 0.77727E+04 26 ankerite -2.14 -7.06 -4.93 -0.821 0.84135E+04 27 annite 20.12 17.31 -2.82 -0.156 0.48085E+04 28 phlogopite 27.06 24.03 -3.03 -0.168 0.51743E+04 33 apatite-OH -18.15 -21.92 -3.77 -0.290 0.64364E+04 34 apatite-F -34.30 -36.72 -2.42 -0.202 0.41324E+04 38 aragonite 0.97 -0.79 -1.76 -0.587 0.30066E+04 39 brucite 12.57 8.84 -3.73 -0.745 0.63621E+04 40 calcite 0.81 -0.79 -1.61 -0.535 0.27423E+04 41 carnegieite-low 9.02 5.60 -3.43 -0.490 0.58537E+04 42 carnegieite-high 10.09 5.60 -4.50 -0.643 0.76807E+04 43 carpholite-Mg 8.58 3.79 -4.79 -0.320 0.81843E+04 45 celadonite 5.34 3.36 -1.98 -0.117 0.33840E+04 46 celadonite-Fe 3.88 1.12 -2.76 -0.162 0.47111E+04 47 chrysotile 23.89 20.55 -3.34 -0.279 0.57093E+04 49 clinochlore 39.07 36.17 -2.90 -0.091 0.49517E+04 50 daphnite 28.97 24.96 -4.01 -0.125 0.68423E+04 54 chloritoid-Fe 9.17 4.54 -4.64 -0.309 0.79186E+04 55 chloritoid-Mn 11.40 7.13 -4.27 -0.285 0.72934E+04 57 coesite -2.38 -2.99 -0.61 -0.204 0.10473E+04 64 cristobalite -2.56 -2.99 -0.43 -0.143 0.73267E+03 66 cymrite-K 1.69 -2.49 -4.18 -0.348 0.71351E+04 68 diaspore 2.87 0.46 -2.41 -0.402 0.41169E+04 69 diamond -3.10 -7.47 -4.37 -1.249 0.74618E+04 70 diopside 16.18 14.94 -1.24 -0.124 0.21234E+04 71 hedenbergite 14.21 12.70 -1.51 -0.151 0.25831E+04 78 epidote 24.67 21.36 -3.31 -0.161 0.56578E+04 80 epidote-Fe 29.84 26.14 -3.70 -0.192 0.63105E+04 81 fayalite 14.05 10.21 -3.83 -0.548 0.65477E+04 82 ferrosilite 11.15 7.22 -3.93 -0.393 0.67068E+04 86 gibbsite 4.08 0.46 -3.62 -0.517 0.61754E+04 87 glaucophane 22.97 19.78 -3.19 -0.086 0.54534E+04 88 glaucophane-Fe 17.28 13.05 -4.22 -0.114 0.72086E+04 89 graphite -3.55 -7.47 -3.93 -1.122 0.67041E+04 90 greenalite 16.14 13.82 -2.32 -0.193 0.39575E+04 93 hematite 12.57 10.50 -2.06 -0.250 0.35237E+04 94 heulandite -5.83 -7.93 -2.10 -0.095 0.35848E+04 98 jadeite 4.22 2.61 -1.61 -0.161 0.27485E+04 100 kalsilite 7.58 3.49 -4.10 -0.585 0.69979E+04 101 kaolinite -1.33 -5.05 -3.72 -0.338 0.63533E+04 104 laumontite 2.88 1.04 -1.84 -0.123 0.31448E+04 105 lawsonite 9.62 7.02 -2.60 -0.173 0.44319E+04 106 leucite 4.12 0.50 -3.62 -0.362 0.61858E+04 108 lizardite 23.24 20.55 -2.70 -0.225 0.46019E+04 109 magnesite 0.69 -4.03 -4.72 -1.572 0.80533E+04 110 magnetite 20.09 17.10 -2.98 -0.244 0.50963E+04 111 minnesotaite 10.39 7.84 -2.55 -0.150 0.43459E+04 115 manganosite 14.06 9.19 -4.86 -1.216 0.83057E+04 119 microcline -2.49 -2.49 -0.01 -0.001 0.11743E+02 123 muscovite 2.58 -1.57 -4.15 -0.244 0.70870E+04 124 paragonite 4.24 0.54 -3.70 -0.218 0.63144E+04 125 nepheline 8.34 5.60 -2.74 -0.392 0.46861E+04 137 phlogopite-Na 29.65 26.14 -3.50 -0.195 0.59814E+04 139 prehnite 19.37 16.11 -3.27 -0.192 0.55779E+04 140 prehnite-Fe 22.50 20.89 -1.60 -0.096 0.27389E+04 145 pyrite -21.25 -22.27 -1.02 -0.240 0.17424E+04 146 pyrrhotite -4.26 -6.48 -2.22 -0.741 0.37979E+04 147 pyrrhotiteFe0.875 -6.02 -7.64 -1.63 -0.598 0.27785E+04 148 pyroxmangite 7.40 6.20 -1.19 -0.239 0.20392E+04 149 pyrophyllite -6.18 -11.03 -4.86 -0.304 0.82927E+04 154 rhodochrosite -0.98 -3.67 -2.70 -0.899 0.46073E+04 155 rhodonite 7.45 6.20 -1.24 -0.248 0.21195E+04 156 sanidine -1.28 -2.49 -1.22 -0.094 0.20795E+04 158 siderite -2.61 -6.27 -3.66 -1.220 0.62495E+04 166 stilbite -7.52 -7.93 -0.40 -0.019 0.69093E+03 168 stilpnomelane-Mg 27.44 24.23 -3.21 -0.096 0.54860E+04 174 talc 16.49 14.57 -1.92 -0.113 0.32805E+04 177 tephroite 18.09 15.40 -2.69 -0.384 0.45890E+04 181 tridymite -2.63 -2.99 -0.36 -0.121 0.61998E+03 182 tremolite 47.87 44.45 -3.42 -0.093 0.58462E+04 184 troilite-low -4.41 -6.48 -2.07 -0.691 0.35407E+04 190 wairakite 3.95 1.04 -2.91 -0.171 0.49668E+04 191 walstromite 11.51 9.08 -2.42 -0.485 0.41398E+04 192 wollastonite 10.46 9.08 -1.38 -0.275 0.23503E+04 193 pseudo-wollastonite 11.00 9.08 -1.92 -0.383 0.32701E+04 195 akaganeite 7.75 5.25 -2.50 -0.541 0.42744E+04 202 chalcedony -2.80 -2.99 -0.19 -0.062 0.31930E+03 204 montmorillonite-Ca -2.29 -6.27 -3.98 -0.246 0.68029E+04 205 montmorillonite-K -2.24 -6.28 -4.05 -0.248 0.69091E+04 206 montmorillonite-Mg -2.48 -6.81 -4.33 -0.268 0.73904E+04 207 montmorillonite-Na -2.04 -5.59 -3.55 -0.217 0.60601E+04 208 nontronite-Ca 3.21 1.68 -1.54 -0.100 0.26268E+04 209 nontronite-H 2.53 -0.32 -2.85 -0.191 0.48643E+04 210 nontronite-K 3.34 1.67 -1.67 -0.107 0.28562E+04 211 nontronite-Mg 3.07 1.14 -1.93 -0.125 0.32983E+04 212 nontronite-Na 3.52 2.36 -1.16 -0.074 0.19732E+04 228 tobermorite 9.82 7.07 -2.75 -0.752 0.47037E+04 234 alabandite -0.98 -3.89 -2.91 -0.971 0.49741E+04 237 boehmite 4.41 0.46 -3.94 -0.657 0.67338E+04 239 ferrous-oxide 9.81 6.60 -3.21 -0.803 0.54833E+04 245 silica-amorphous -2.09 -2.99 -0.90 -0.299 0.15335E+04 247 an20ab80 2.02 1.10 -0.92 -0.071 0.15722E+04 248 an25ab75 2.65 1.47 -1.18 -0.091 0.20122E+04 249 an30ab70 3.28 1.84 -1.44 -0.111 0.24619E+04 250 tr.625ac.25prg.125 45.16 42.47 -2.69 -0.072 0.45957E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 0.0010000 MOLES Current total amount of reactant added: 0.0339900 MOLES New total amount of reactant added: 0.0349900 MOLES Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.5508E-08 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 7 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 0.0349900 Water: Moles liquid = 0.4988E+02 kg liquid = 0.8987E+00 Moles total = 0.4988E+02 kg total = 0.8985E+00 Activity = 1.0000 Stoichiometric ionic strength = .1358720E-01 Osmotic coef. = 0.9344 True ionic strength = .2202280E-01 Chg. balance for total moles = -.5508E-08 Max. difference allowed = 0.3443E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.15293E-09 -9.8155 0.12773E-09 -9.8937 0.83527E+00 -0.0782 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.38140E-03 -3.4186 0.31651E-03 -3.4996 0.82986E+00 -0.0810 4 SO4-- 0.16909E-03 -3.7719 0.85625E-04 -4.0674 0.50639E+00 -0.2955 5 HCO3- 0.13314E-02 -2.8757 0.11066E-02 -2.9560 0.83117E+00 -0.0803 6 HS- 0.80496E-03 -3.0942 0.66811E-03 -3.1751 0.82999E+00 -0.0809 7 Al+++ 0.27981E-28 -28.5531 0.61011E-29 -29.2146 0.21805E+00 -0.6614 8 H4SiO4 0.10246E-02 -2.9894 0.10246E-02 -2.9894 0.10000E+01 0.0000 9 Ca++ 0.37120E-07 -7.4304 0.18648E-07 -7.7294 0.50238E+00 -0.2990 10 Mg++ 0.22222E-10 -10.6532 0.11109E-10 -10.9543 0.49990E+00 -0.3011 11 Fe++ 0.12951E-12 -12.8877 0.64819E-13 -13.1883 0.50049E+00 -0.3006 12 K+ 0.15651E-03 -3.8055 0.13012E-03 -3.8857 0.83138E+00 -0.0802 13 Na+ 0.20199E-01 -1.6947 0.16759E-01 -1.7757 0.82970E+00 -0.0811 14 Mn++ 0.50749E-10 -10.2946 0.25422E-10 -10.5948 0.50094E+00 -0.3002 15 F- 0.15635E-04 -4.8059 0.12946E-04 -4.8879 0.82802E+00 -0.0820 16 HPO4-- 0.45681E-07 -7.3403 0.23136E-07 -7.6357 0.50646E+00 -0.2955 18 HSiO3- 0.90256E-02 -2.0445 0.74900E-02 -2.1255 0.82986E+00 -0.0810 19 Ca(HSiO3)+ 0.38252E-08 -8.4173 0.31809E-08 -8.4974 0.83157E+00 -0.0801 20 Mg(HSiO3)+ 0.28358E-11 -11.5473 0.23582E-11 -11.6274 0.83157E+00 -0.0801 21 NaHSiO3,aq 0.20302E-02 -2.6925 0.20302E-02 -2.6925 0.10000E+01 0.0000 22 AlO+ 0.61175E-16 -16.2134 0.50871E-16 -16.2935 0.83157E+00 -0.0801 24 HAlO2,aq 0.79312E-10 -10.1007 0.79312E-10 -10.1007 0.10000E+01 0.0000 25 AlO2- 0.16595E-05 -5.7800 0.13745E-05 -5.8619 0.82825E+00 -0.0818 26 CH4,aq 0.84222E-08 -8.0746 0.83874E-08 -8.0764 0.99587E+00 -0.0018 27 C2H6,aq 0.63748E-19 -19.1955 0.63485E-19 -19.1973 0.99587E+00 -0.0018 31 CO,aq 0.14373E-14 -14.8424 0.14373E-14 -14.8424 0.10000E+01 0.0000 32 CO2,aq 0.30329E-06 -6.5181 0.30203E-06 -6.5199 0.99587E+00 -0.0018 33 CO3-2 0.14978E-02 -2.8246 0.75671E-03 -3.1211 0.50523E+00 -0.2965 34 CaCO3,aq 0.17694E-06 -6.7522 0.17694E-06 -6.7522 0.10000E+01 0.0000 35 Ca(HCO3)+ 0.63344E-09 -9.1983 0.52675E-09 -9.2784 0.83157E+00 -0.0801 36 CaCl+ 0.11486E-10 -10.9398 0.95517E-11 -11.0199 0.83157E+00 -0.0801 37 CaCl2,aq 0.71825E-15 -15.1437 0.71825E-15 -15.1437 0.10000E+01 0.0000 38 CaF+ 0.42386E-11 -11.3728 0.35247E-11 -11.4529 0.83157E+00 -0.0801 39 CaOH+ 0.12512E-07 -7.9027 0.10405E-07 -7.9828 0.83157E+00 -0.0801 40 CaSO4,aq 0.50704E-09 -9.2950 0.50704E-09 -9.2950 0.10000E+01 0.0000 41 HCl,aq 0.74084E-14 -14.1303 0.74084E-14 -14.1303 0.10000E+01 0.0000 45 HF,aq 0.11320E-10 -10.9461 0.11320E-10 -10.9461 0.10000E+01 0.0000 46 HF2- 0.59625E-16 -16.2246 0.49481E-16 -16.3056 0.82986E+00 -0.0810 48 FeCl+ 0.39050E-16 -16.4084 0.32473E-16 -16.4885 0.83157E+00 -0.0801 51 FeF+ 0.51568E-16 -16.2876 0.42882E-16 -16.3677 0.83157E+00 -0.0801 53 FeO,aq 0.15440E-09 -9.8113 0.15440E-09 -9.8113 0.10000E+01 0.0000 54 FeOH+ 0.19864E-10 -10.7019 0.16518E-10 -10.7820 0.83157E+00 -0.0801 55 HFeO2- 0.15241E-07 -7.8170 0.12648E-07 -7.8980 0.82986E+00 -0.0810 56 FeO+ 0.10886E-15 -15.9631 0.90522E-16 -16.0432 0.83157E+00 -0.0801 58 FeO2- 0.13680E-08 -8.8639 0.11352E-08 -8.9449 0.82986E+00 -0.0810 59 HFeO2,aq 0.18443E-10 -10.7342 0.18443E-10 -10.7342 0.10000E+01 0.0000 60 H2,aq 0.19022E-06 -6.7207 0.18944E-06 -6.7225 0.99587E+00 -0.0018 61 KCl,aq 0.74643E-09 -9.1270 0.74643E-09 -9.1270 0.10000E+01 0.0000 62 KHSO4,aq 0.40238E-17 -17.3954 0.40238E-17 -17.3954 0.10000E+01 0.0000 63 KOH,aq 0.43503E-06 -6.3615 0.43503E-06 -6.3615 0.10000E+01 0.0000 64 KSO4- 0.20834E-06 -6.6812 0.17289E-06 -6.7622 0.82986E+00 -0.0810 65 MgCO3,aq 0.26419E-10 -10.5781 0.26419E-10 -10.5781 0.10000E+01 0.0000 66 Mg(HCO3)+ 0.38557E-12 -12.4139 0.32063E-12 -12.4940 0.83157E+00 -0.0801 67 MgCl+ 0.62015E-14 -14.2075 0.51570E-14 -14.2876 0.83157E+00 -0.0801 68 MgF+ 0.93531E-14 -14.0290 0.77778E-14 -14.1091 0.83157E+00 -0.0801 69 MgOH+ 0.41243E-10 -10.3846 0.34297E-10 -10.4647 0.83157E+00 -0.0801 71 MnF+ 0.66663E-14 -14.1761 0.55435E-14 -14.2562 0.83157E+00 -0.0801 72 MnO,aq 0.16136E-08 -8.7922 0.16136E-08 -8.7922 0.10000E+01 0.0000 73 MnOH+ 0.72372E-09 -9.1404 0.60182E-09 -9.2205 0.83157E+00 -0.0801 74 MnO2-2 0.64962E-11 -11.1873 0.32820E-11 -11.4839 0.50523E+00 -0.2965 75 HMnO2- 0.11068E-09 -9.9559 0.91847E-10 -10.0369 0.82986E+00 -0.0810 78 MnCl+ 0.59584E-13 -13.2249 0.49549E-13 -13.3050 0.83157E+00 -0.0801 79 MnSO4,aq 0.62842E-12 -12.2018 0.62842E-12 -12.2018 0.10000E+01 0.0000 80 NaCl,aq 0.17579E-05 -5.7550 0.17579E-05 -5.7550 0.10000E+01 0.0000 81 NaF,aq 0.50796E-07 -7.2942 0.50796E-07 -7.2942 0.10000E+01 0.0000 82 NaOH,aq 0.56372E-04 -4.2489 0.56372E-04 -4.2489 0.10000E+01 0.0000 84 OH- 0.54612E-02 -2.2627 0.45232E-02 -2.3445 0.82825E+00 -0.0818 89 HPO3-2 0.27034E-16 -16.5681 0.13658E-16 -16.8646 0.50523E+00 -0.2965 92 H3PO4,aq 0.26401E-17 -17.5784 0.26401E-17 -17.5784 0.10000E+01 0.0000 93 H2PO4- 0.65626E-10 -10.1829 0.54516E-10 -10.2635 0.83071E+00 -0.0806 94 PO4-3 0.64283E-09 -9.1919 0.14778E-09 -9.8304 0.22989E+00 -0.6385 98 HP2O7-3 0.16688E-17 -17.7776 0.36429E-18 -18.4386 0.21829E+00 -0.6610 99 P2O7-4 0.97709E-17 -17.0101 0.68131E-18 -18.1667 0.69728E-01 -1.1566 100 H2S,aq 0.26485E-06 -6.5770 0.26376E-06 -6.5788 0.99587E+00 -0.0018 101 S2-2 0.10334E-09 -9.9857 0.52211E-10 -10.2822 0.50523E+00 -0.2965 102 S3-2 0.19385E-15 -15.7125 0.97938E-16 -16.0090 0.50523E+00 -0.2965 103 S3- 0.23217E-19 -19.6342 0.19267E-19 -19.7152 0.82986E+00 -0.0810 107 SO3-2 0.41081E-11 -11.3864 0.21079E-11 -11.6762 0.51310E+00 -0.2898 108 HSO3- 0.20315E-13 -13.6922 0.16858E-13 -13.7732 0.82986E+00 -0.0810 109 HSO4- 0.12662E-10 -10.8975 0.10540E-10 -10.9771 0.83245E+00 -0.0796 111 S2O3-2 0.52510E-12 -12.2798 0.26529E-12 -12.5763 0.50523E+00 -0.2965 Charge balance for all species = -.6129E-08 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.1529254E-09 -.1807799E-01 -.1818899E+02 0.0000 2 H2O 0.1000000E+01 0.5550272E+02 0.9981125E+06 0.0000 3 Cl- 0.3813987E-03 0.3831573E-03 0.1355982E+02 6.3941 4 SO4-- 0.1690917E-03 0.1692448E-03 0.1622889E+02 15.7200 5 HCO3- 0.1331378E-02 0.2829623E-02 0.1723473E+03 6.9377 6 HS- 0.8049620E-03 0.8052829E-03 0.2658475E+02 6.7185 7 Al+++ 0.2798087E-28 0.1659544E-05 0.4469703E-01 0.4665 8 H4SiO4 0.1024625E-02 0.1208049E-01 0.1159048E+04 -2.9894 9 Ca++ 0.3711974E-07 0.2315506E-06 0.9263514E-02 12.0580 10 Mg++ 0.2222153E-10 0.9312087E-10 0.2259912E-05 8.8330 11 Fe++ 0.1295121E-12 0.1680141E-07 0.9366325E-03 6.5991 12 K+ 0.1565108E-03 0.1571549E-03 0.6134099E+01 6.0080 13 Na+ 0.2019926E-01 0.2228768E-01 0.5114742E+03 8.1179 14 Mn++ 0.5074921E-10 0.2505907E-08 0.1374237E-03 9.1926 15 F- 0.1563490E-04 0.1568571E-04 0.2974650E+00 5.0058 16 HPO4-- 0.4568122E-07 0.4638968E-07 0.4444484E-02 12.1517 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.1625899E-01 -.1624583E-01 -.1316573E-04 0.0000000E+00 2 H2O 0.4987505E+02 0.4987764E+02 -.2587114E-02 0.0000000E+00 3 Cl- 0.3443252E-03 0.3443252E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.1520922E-03 0.1520922E-03 0.0000000E+00 0.0000000E+00 5 HCO3- 0.2542847E-02 0.2542847E-02 0.0000000E+00 0.0000000E+00 6 HS- 0.7236693E-03 0.7236693E-03 0.0000000E+00 0.0000000E+00 7 Al+++ 0.4775352E-05 0.1491353E-05 0.3283999E-05 0.0000000E+00 8 H4SiO4 0.1215302E-01 0.1085616E-01 0.1296859E-02 0.0000000E+00 9 Ca++ 0.2080835E-06 0.2080835E-06 0.0000000E+00 0.0000000E+00 10 Mg++ 0.8368328E-10 0.8368328E-10 0.0000000E+00 0.0000000E+00 11 Fe++ 0.3259227E-07 0.1509862E-07 0.1749365E-07 0.0000000E+00 12 K+ 0.1412294E-03 0.1412277E-03 0.1749365E-08 0.0000000E+00 13 Na+ 0.2003215E-01 0.2002887E-01 0.3277001E-05 0.0000000E+00 14 Mn++ 0.2251939E-08 0.2251939E-08 0.0000000E+00 0.0000000E+00 15 F- 0.1409600E-04 0.1409600E-04 0.0000000E+00 0.0000000E+00 16 HPO4-- 0.4168819E-07 0.4168819E-07 0.0000000E+00 0.0000000E+00 Chg. balance for solid moles: 0.0000E+00 Mass of aqueous solution: 0.900260E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 0.0349900 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 0.3277E-05 -5.485 0.8593E-03 -3.066 1.099 0.3299E-03 quartz 0.1287E-02 -2.890 0.7732E-01 -1.112 98.90 0.2920E-01 stilpnomelane-Fe 0.3499E-08 -8.456 0.3772E-05 -5.423 0.4824E-02 0.1303E-05 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 quartz 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 0.078186 g Volume = 0.029532 cm3 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.0349900 moles log = -1.4561 Original solution: 1000.0103000 g Original solution / Rock added: 28579.89 (Water/Rock Ratio), log = 4.4561 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0206 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9997E+00 0.9859 0.1006E+01 0.1020E+01 CO2,gas 0.3144E-04 1.0071 0.3231E-04 0.3209E-04 CH4,gas 0.1195E-04 1.0125 0.1235E-04 0.1219E-04 H2,gas 0.2436E-03 1.0005 0.2487E-03 0.2486E-03 H2S,gas 0.7132E-05 0.9960 0.7250E-05 0.7279E-05 S2,gas 0.3126E-22 1.0000 0.3190E-22 0.3190E-22 CO,gas 0.2099E-11 1.0000 0.2142E-11 0.2142E-11 SO3,gas 0.5176E-39 1.0000 0.5282E-39 0.5282E-39 SO2,gas 0.5008E-20 1.0000 0.5111E-20 0.5111E-20 HF,gas 0.2723E-13 1.0000 0.2780E-13 0.2780E-13 HCl,gas 0.1281E-16 1.0000 0.1307E-16 0.1307E-16 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 17 albite -0.38 -0.38 0.00 0.000 -0.94784E-12 150 quartz -2.99 -2.99 0.00 0.000 0.00000E+00 167 stilpnomelane-Fe 13.02 13.02 0.00 0.000 0.21232E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -12.85 -6.19 -2.063 0.10569E+05 -4.491 3 CH4,gas 4.54 -2.06 -6.61 -1.652 0.11282E+05 -4.908 4 H2,gas 8.00 2.70 -5.30 -3.030 0.90552E+04 -3.604 5 H2S,gas -6.23 -13.07 -6.84 -3.419 0.11677E+05 -5.140 6 S2,gas -7.34 -31.53 -24.20 -3.722 0.41313E+05 -22.496 7 CO,gas 3.21 -10.15 -13.37 -4.113 0.22826E+05 -11.669 8 SO3,gas 17.12 -23.85 -40.98 -10.244 0.69966E+05 -39.277 9 SO2,gas 0.83 -21.16 -21.99 -5.864 0.37548E+05 -20.291 10 HF,gas 0.47 -14.78 -15.25 -7.627 0.26047E+05 -13.556 11 HCl,gas 5.19 -13.39 -18.58 -9.291 0.31729E+05 -16.884 12 acmite 7.71 7.39 -0.32 -0.033 0.54603E+03 16 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 20 spessartine 24.46 19.54 -4.91 -0.246 0.83920E+04 21 analcite 3.32 2.61 -0.72 -0.080 0.12231E+04 23 andradite 39.01 37.71 -1.30 -0.068 0.22219E+04 24 grossular 32.73 28.14 -4.59 -0.230 0.78419E+04 26 ankerite -2.14 -7.04 -4.91 -0.818 0.83789E+04 27 annite 20.12 17.30 -2.82 -0.157 0.48149E+04 28 phlogopite 27.06 24.01 -3.06 -0.170 0.52236E+04 33 apatite-OH -18.15 -21.98 -3.83 -0.294 0.65323E+04 34 apatite-F -34.30 -36.76 -2.46 -0.205 0.42000E+04 38 aragonite 0.97 -0.79 -1.76 -0.586 0.30021E+04 39 brucite 12.57 8.83 -3.74 -0.747 0.63783E+04 40 calcite 0.81 -0.79 -1.60 -0.534 0.27379E+04 41 carnegieite-low 9.02 5.60 -3.43 -0.490 0.58537E+04 42 carnegieite-high 10.09 5.60 -4.50 -0.643 0.76807E+04 43 carpholite-Mg 8.58 3.79 -4.79 -0.320 0.81872E+04 45 celadonite 5.34 3.35 -1.99 -0.117 0.34009E+04 46 celadonite-Fe 3.88 1.12 -2.76 -0.162 0.47137E+04 47 chrysotile 23.89 20.52 -3.37 -0.281 0.57578E+04 49 clinochlore 39.07 36.13 -2.94 -0.092 0.50193E+04 50 daphnite 28.97 24.96 -4.01 -0.125 0.68386E+04 54 chloritoid-Fe 9.17 4.54 -4.63 -0.309 0.79073E+04 55 chloritoid-Mn 11.40 7.14 -4.26 -0.284 0.72823E+04 57 coesite -2.38 -2.99 -0.61 -0.204 0.10473E+04 64 cristobalite -2.56 -2.99 -0.43 -0.143 0.73267E+03 66 cymrite-K 1.69 -2.49 -4.18 -0.348 0.71358E+04 68 diaspore 2.87 0.47 -2.41 -0.401 0.41102E+04 69 diamond -3.10 -7.46 -4.35 -1.244 0.74349E+04 70 diopside 16.18 14.91 -1.27 -0.127 0.21671E+04 71 hedenbergite 14.21 12.68 -1.53 -0.153 0.26125E+04 78 epidote 24.67 21.33 -3.34 -0.162 0.57002E+04 80 epidote-Fe 29.84 26.12 -3.72 -0.194 0.63601E+04 81 fayalite 14.05 10.21 -3.84 -0.548 0.65515E+04 82 ferrosilite 11.15 7.22 -3.93 -0.393 0.67106E+04 86 gibbsite 4.08 0.47 -3.61 -0.516 0.61688E+04 87 glaucophane 22.97 19.75 -3.22 -0.087 0.55020E+04 88 glaucophane-Fe 17.28 13.05 -4.23 -0.114 0.72143E+04 89 graphite -3.55 -7.46 -3.91 -1.117 0.66772E+04 90 greenalite 16.14 13.82 -2.32 -0.193 0.39632E+04 93 hematite 12.57 10.50 -2.06 -0.250 0.35251E+04 94 heulandite -5.83 -7.94 -2.11 -0.096 0.35990E+04 98 jadeite 4.22 2.61 -1.61 -0.161 0.27485E+04 100 kalsilite 7.58 3.49 -4.10 -0.586 0.69986E+04 101 kaolinite -1.33 -5.05 -3.71 -0.338 0.63401E+04 104 laumontite 2.88 1.03 -1.85 -0.123 0.31591E+04 105 lawsonite 9.62 7.01 -2.60 -0.174 0.44462E+04 106 leucite 4.12 0.50 -3.62 -0.362 0.61865E+04 108 lizardite 23.24 20.52 -2.72 -0.227 0.46505E+04 109 magnesite 0.69 -4.02 -4.71 -1.569 0.80375E+04 110 magnetite 20.09 17.10 -2.99 -0.244 0.50996E+04 111 minnesotaite 10.39 7.84 -2.55 -0.150 0.43516E+04 115 manganosite 14.06 9.19 -4.87 -1.216 0.83077E+04 119 microcline -2.49 -2.49 -0.01 -0.001 0.12435E+02 123 muscovite 2.58 -1.56 -4.14 -0.244 0.70744E+04 124 paragonite 4.24 0.55 -3.69 -0.217 0.63011E+04 125 nepheline 8.34 5.60 -2.74 -0.392 0.46861E+04 137 phlogopite-Na 29.65 26.12 -3.53 -0.196 0.60300E+04 139 prehnite 19.37 16.08 -3.29 -0.194 0.56196E+04 140 prehnite-Fe 22.50 20.87 -1.63 -0.098 0.27880E+04 145 pyrite -21.25 -22.24 -0.99 -0.233 0.16872E+04 146 pyrrhotite -4.26 -6.47 -2.21 -0.736 0.37725E+04 147 pyrrhotiteFe0.875 -6.02 -7.63 -1.61 -0.593 0.27525E+04 148 pyroxmangite 7.40 6.20 -1.20 -0.239 0.20413E+04 149 pyrophyllite -6.18 -11.02 -4.85 -0.303 0.82795E+04 154 rhodochrosite -0.98 -3.66 -2.68 -0.894 0.45774E+04 155 rhodonite 7.45 6.20 -1.24 -0.249 0.21216E+04 156 sanidine -1.28 -2.49 -1.22 -0.094 0.20802E+04 158 siderite -2.61 -6.25 -3.64 -1.214 0.62194E+04 166 stilbite -7.52 -7.94 -0.41 -0.020 0.70518E+03 168 stilpnomelane-Mg 27.44 24.19 -3.25 -0.097 0.55573E+04 174 talc 16.49 14.54 -1.95 -0.115 0.33290E+04 177 tephroite 18.09 15.40 -2.69 -0.384 0.45932E+04 181 tridymite -2.63 -2.99 -0.36 -0.121 0.61998E+03 182 tremolite 47.87 44.37 -3.50 -0.095 0.59821E+04 184 troilite-low -4.41 -6.47 -2.06 -0.686 0.35154E+04 190 wairakite 3.95 1.03 -2.92 -0.172 0.49810E+04 191 walstromite 11.51 9.07 -2.44 -0.488 0.41673E+04 192 wollastonite 10.46 9.07 -1.39 -0.279 0.23778E+04 193 pseudo-wollastonite 11.00 9.07 -1.93 -0.386 0.32976E+04 195 akaganeite 7.75 5.25 -2.50 -0.541 0.42751E+04 202 chalcedony -2.80 -2.99 -0.19 -0.062 0.31930E+03 204 montmorillonite-Ca -2.29 -6.27 -3.98 -0.246 0.68017E+04 205 montmorillonite-K -2.24 -6.28 -4.04 -0.248 0.69057E+04 206 montmorillonite-Mg -2.48 -6.81 -4.33 -0.268 0.73873E+04 207 montmorillonite-Na -2.04 -5.58 -3.55 -0.217 0.60565E+04 208 nontronite-Ca 3.21 1.67 -1.54 -0.100 0.26305E+04 209 nontronite-H 2.53 -0.32 -2.85 -0.191 0.48634E+04 210 nontronite-K 3.34 1.67 -1.67 -0.107 0.28577E+04 211 nontronite-Mg 3.07 1.14 -1.93 -0.125 0.33001E+04 212 nontronite-Na 3.52 2.36 -1.16 -0.074 0.19745E+04 228 tobermorite 9.82 7.05 -2.77 -0.755 0.47266E+04 234 alabandite -0.98 -3.88 -2.90 -0.966 0.49489E+04 237 boehmite 4.41 0.47 -3.94 -0.657 0.67272E+04 239 ferrous-oxide 9.81 6.60 -3.21 -0.803 0.54852E+04 245 silica-amorphous -2.09 -2.99 -0.90 -0.299 0.15335E+04 247 an20ab80 2.02 1.10 -0.92 -0.071 0.15751E+04 248 an25ab75 2.65 1.47 -1.18 -0.091 0.20158E+04 249 an30ab70 3.28 1.83 -1.44 -0.111 0.24661E+04 250 tr.625ac.25prg.125 45.16 42.41 -2.76 -0.074 0.47101E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 0.0010000 MOLES Current total amount of reactant added: 0.0349900 MOLES New total amount of reactant added: 0.0359900 MOLES Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.5508E-08 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 7 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 0.0359900 Water: Moles liquid = 0.4988E+02 kg liquid = 0.8987E+00 Moles total = 0.4988E+02 kg total = 0.8985E+00 Activity = 1.0000 Stoichiometric ionic strength = .1365215E-01 Osmotic coef. = 0.9341 True ionic strength = .2208223E-01 Chg. balance for total moles = -.5508E-08 Max. difference allowed = 0.3502E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.15444E-09 -9.8112 0.12898E-09 -9.8895 0.83513E+00 -0.0782 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.38793E-03 -3.4113 0.32187E-03 -3.4923 0.82971E+00 -0.0811 4 SO4-- 0.17440E-03 -3.7585 0.88247E-04 -4.0543 0.50602E+00 -0.2958 5 HCO3- 0.13759E-02 -2.8614 0.11434E-02 -2.9418 0.83102E+00 -0.0804 6 HS- 0.82666E-03 -3.0827 0.68600E-03 -3.1637 0.82984E+00 -0.0810 7 Al+++ 0.29117E-28 -28.5359 0.63383E-29 -29.1980 0.21769E+00 -0.6622 8 H4SiO4 0.10246E-02 -2.9894 0.10246E-02 -2.9894 0.10000E+01 0.0000 9 Ca++ 0.36513E-07 -7.4376 0.18329E-07 -7.7369 0.50200E+00 -0.2993 10 Mg++ 0.22184E-10 -10.6540 0.11081E-10 -10.9554 0.49952E+00 -0.3014 11 Fe++ 0.13181E-12 -12.8801 0.65919E-13 -13.1810 0.50011E+00 -0.3009 12 K+ 0.15651E-03 -3.8055 0.13009E-03 -3.8857 0.83123E+00 -0.0803 13 Na+ 0.20217E-01 -1.6943 0.16771E-01 -1.7754 0.82954E+00 -0.0812 14 Mn++ 0.51636E-10 -10.2870 0.25847E-10 -10.5876 0.50056E+00 -0.3005 15 F- 0.16078E-04 -4.7938 0.13311E-04 -4.8758 0.82787E+00 -0.0820 16 HPO4-- 0.45685E-07 -7.3402 0.23121E-07 -7.6360 0.50610E+00 -0.2958 18 HSiO3- 0.89400E-02 -2.0487 0.74176E-02 -2.1297 0.82971E+00 -0.0811 19 Ca(HSiO3)+ 0.37242E-08 -8.4290 0.30964E-08 -8.5091 0.83143E+00 -0.0802 20 Mg(HSiO3)+ 0.28020E-11 -11.5525 0.23297E-11 -11.6327 0.83143E+00 -0.0802 21 NaHSiO3,aq 0.20121E-02 -2.6964 0.20121E-02 -2.6964 0.10000E+01 0.0000 22 AlO+ 0.62341E-16 -16.2052 0.51832E-16 -16.2854 0.83143E+00 -0.0802 24 HAlO2,aq 0.80029E-10 -10.0968 0.80029E-10 -10.0968 0.10000E+01 0.0000 25 AlO2- 0.16586E-05 -5.7803 0.13735E-05 -5.8622 0.82810E+00 -0.0819 26 CH4,aq 0.86696E-08 -8.0620 0.86337E-08 -8.0638 0.99585E+00 -0.0018 27 C2H6,aq 0.67775E-19 -19.1689 0.67494E-19 -19.1707 0.99585E+00 -0.0018 31 CO,aq 0.14945E-14 -14.8255 0.14945E-14 -14.8255 0.10000E+01 0.0000 32 CO2,aq 0.31643E-06 -6.4997 0.31511E-06 -6.5015 0.99585E+00 -0.0018 33 CO3-2 0.15337E-02 -2.8143 0.77429E-03 -3.1111 0.50486E+00 -0.2968 34 CaCO3,aq 0.17795E-06 -6.7497 0.17795E-06 -6.7497 0.10000E+01 0.0000 35 Ca(HCO3)+ 0.64342E-09 -9.1915 0.53495E-09 -9.2717 0.83143E+00 -0.0802 36 CaCl+ 0.11483E-10 -10.9399 0.95474E-11 -11.0201 0.83143E+00 -0.0802 37 CaCl2,aq 0.73008E-15 -15.1366 0.73008E-15 -15.1366 0.10000E+01 0.0000 38 CaF+ 0.42843E-11 -11.3681 0.35621E-11 -11.4483 0.83143E+00 -0.0802 39 CaOH+ 0.12182E-07 -7.9143 0.10128E-07 -7.9945 0.83143E+00 -0.0802 40 CaSO4,aq 0.51364E-09 -9.2893 0.51364E-09 -9.2893 0.10000E+01 0.0000 41 HCl,aq 0.76074E-14 -14.1188 0.76074E-14 -14.1188 0.10000E+01 0.0000 45 HF,aq 0.11753E-10 -10.9299 0.11753E-10 -10.9299 0.10000E+01 0.0000 46 HF2- 0.63658E-16 -16.1961 0.52818E-16 -16.2772 0.82971E+00 -0.0811 48 FeCl+ 0.40392E-16 -16.3937 0.33583E-16 -16.4739 0.83143E+00 -0.0802 51 FeF+ 0.53929E-16 -16.2682 0.44838E-16 -16.3484 0.83143E+00 -0.0802 53 FeO,aq 0.15400E-09 -9.8125 0.15400E-09 -9.8125 0.10000E+01 0.0000 54 FeOH+ 0.20009E-10 -10.6988 0.16636E-10 -10.7790 0.83143E+00 -0.0802 55 HFeO2- 0.15057E-07 -7.8223 0.12493E-07 -7.9033 0.82971E+00 -0.0811 56 FeO+ 0.10984E-15 -15.9593 0.91321E-16 -16.0394 0.83143E+00 -0.0802 58 FeO2- 0.13538E-08 -8.8685 0.11232E-08 -8.9495 0.82971E+00 -0.0811 59 HFeO2,aq 0.18426E-10 -10.7346 0.18426E-10 -10.7346 0.10000E+01 0.0000 60 H2,aq 0.18959E-06 -6.7222 0.18880E-06 -6.7240 0.99585E+00 -0.0018 61 KCl,aq 0.75890E-09 -9.1198 0.75890E-09 -9.1198 0.10000E+01 0.0000 62 KHSO4,aq 0.41866E-17 -17.3781 0.41866E-17 -17.3781 0.10000E+01 0.0000 63 KOH,aq 0.43074E-06 -6.3658 0.43074E-06 -6.3658 0.10000E+01 0.0000 64 KSO4- 0.21471E-06 -6.6681 0.17815E-06 -6.7492 0.82971E+00 -0.0811 65 MgCO3,aq 0.26967E-10 -10.5692 0.26967E-10 -10.5692 0.10000E+01 0.0000 66 Mg(HCO3)+ 0.39748E-12 -12.4007 0.33047E-12 -12.4809 0.83143E+00 -0.0802 67 MgCl+ 0.62922E-14 -14.2012 0.52315E-14 -14.2814 0.83143E+00 -0.0802 68 MgF+ 0.95948E-14 -14.0180 0.79774E-14 -14.0981 0.83143E+00 -0.0802 69 MgOH+ 0.40752E-10 -10.3898 0.33882E-10 -10.4700 0.83143E+00 -0.0802 71 MnF+ 0.69698E-14 -14.1568 0.57949E-14 -14.2370 0.83143E+00 -0.0802 72 MnO,aq 0.16090E-08 -8.7934 0.16090E-08 -8.7934 0.10000E+01 0.0000 73 MnOH+ 0.72883E-09 -9.1374 0.60597E-09 -9.2175 0.83143E+00 -0.0802 74 MnO2-2 0.63577E-11 -11.1967 0.32098E-11 -11.4935 0.50486E+00 -0.2968 75 HMnO2- 0.10932E-09 -9.9613 0.90700E-10 -10.0424 0.82971E+00 -0.0811 78 MnCl+ 0.61617E-13 -13.2103 0.51230E-13 -13.2905 0.83143E+00 -0.0802 79 MnSO4,aq 0.65849E-12 -12.1815 0.65849E-12 -12.1815 0.10000E+01 0.0000 80 NaCl,aq 0.17889E-05 -5.7474 0.17889E-05 -5.7474 0.10000E+01 0.0000 81 NaF,aq 0.52264E-07 -7.2818 0.52264E-07 -7.2818 0.10000E+01 0.0000 82 NaOH,aq 0.55867E-04 -4.2528 0.55867E-04 -4.2528 0.10000E+01 0.0000 84 OH- 0.54094E-02 -2.2668 0.44795E-02 -2.3488 0.82810E+00 -0.0819 89 HPO3-2 0.26946E-16 -16.5695 0.13604E-16 -16.8663 0.50486E+00 -0.2968 92 H3PO4,aq 0.26902E-17 -17.5702 0.26902E-17 -17.5702 0.10000E+01 0.0000 93 H2PO4- 0.66237E-10 -10.1789 0.55013E-10 -10.2595 0.83056E+00 -0.0806 94 PO4-3 0.63720E-09 -9.1957 0.14626E-09 -9.8349 0.22953E+00 -0.6392 98 HP2O7-3 0.16858E-17 -17.7732 0.36738E-18 -18.4349 0.21793E+00 -0.6617 99 P2O7-4 0.97868E-17 -17.0094 0.68045E-18 -18.1672 0.69527E-01 -1.1578 100 H2S,aq 0.27460E-06 -6.5613 0.27346E-06 -6.5631 0.99585E+00 -0.0018 101 S2-2 0.10940E-09 -9.9610 0.55230E-10 -10.2578 0.50486E+00 -0.2968 102 S3-2 0.21347E-15 -15.6707 0.10777E-15 -15.9675 0.50486E+00 -0.2968 103 S3- 0.25846E-19 -19.5876 0.21445E-19 -19.6687 0.82971E+00 -0.0811 107 SO3-2 0.42226E-11 -11.3744 0.21651E-11 -11.6645 0.51274E+00 -0.2901 108 HSO3- 0.21074E-13 -13.6763 0.17485E-13 -13.7573 0.82971E+00 -0.0811 109 HSO4- 0.13179E-10 -10.8801 0.10969E-10 -10.9598 0.83230E+00 -0.0797 111 S2O3-2 0.56150E-12 -12.2507 0.28348E-12 -12.5475 0.50486E+00 -0.2968 Charge balance for all species = -.6129E-08 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.1544442E-09 -.1795782E-01 -.1806813E+02 0.0000 2 H2O 0.1000000E+01 0.5550277E+02 0.9981159E+06 0.0000 3 Cl- 0.3879255E-03 0.3897152E-03 0.1379194E+02 6.3971 4 SO4-- 0.1743955E-03 0.1745549E-03 0.1673812E+02 15.7247 5 HCO3- 0.1375852E-02 0.2910021E-02 0.1772447E+03 6.9477 6 HS- 0.8266633E-03 0.8269939E-03 0.2730157E+02 6.7258 7 Al+++ 0.2911672E-28 0.1658666E-05 0.4467350E-01 0.4704 8 H4SiO4 0.1024625E-02 0.1197672E-01 0.1149094E+04 -2.9894 9 Ca++ 0.3651260E-07 0.2315462E-06 0.9263359E-02 12.0421 10 Mg++ 0.2218406E-10 0.9311908E-10 0.2259874E-05 8.8235 11 Fe++ 0.1318073E-12 0.1660310E-07 0.9255798E-03 6.5980 12 K+ 0.1565057E-03 0.1571519E-03 0.6133996E+01 6.0037 13 Na+ 0.2021749E-01 0.2228725E-01 0.5114657E+03 8.1140 14 Mn++ 0.5163609E-10 0.2505859E-08 0.1374214E-03 9.1914 15 F- 0.1607823E-04 0.1613051E-04 0.3059010E+00 5.0137 16 HPO4-- 0.4568535E-07 0.4638879E-07 0.4444410E-02 12.1430 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.1615132E-01 -.1613815E-01 -.1316908E-04 0.0000000E+00 2 H2O 0.4987587E+02 0.4987865E+02 -.2773210E-02 0.0000000E+00 3 Cl- 0.3502252E-03 0.3502252E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.1568672E-03 0.1568672E-03 0.0000000E+00 0.0000000E+00 5 HCO3- 0.2615147E-02 0.2615147E-02 0.0000000E+00 0.0000000E+00 6 HS- 0.7431943E-03 0.7431943E-03 0.0000000E+00 0.0000000E+00 7 Al+++ 0.4775352E-05 0.1490593E-05 0.3284759E-05 0.0000000E+00 8 H4SiO4 0.1215302E-01 0.1076311E-01 0.1389908E-02 0.0000000E+00 9 Ca++ 0.2080835E-06 0.2080835E-06 0.0000000E+00 0.0000000E+00 10 Mg++ 0.8368328E-10 0.8368328E-10 0.0000000E+00 0.0000000E+00 11 Fe++ 0.3259227E-07 0.1492070E-07 0.1767157E-07 0.0000000E+00 12 K+ 0.1412294E-03 0.1412276E-03 0.1767157E-08 0.0000000E+00 13 Na+ 0.2003215E-01 0.2002887E-01 0.3277690E-05 0.0000000E+00 14 Mn++ 0.2251939E-08 0.2251939E-08 0.0000000E+00 0.0000000E+00 15 F- 0.1449600E-04 0.1449600E-04 0.0000000E+00 0.0000000E+00 16 HPO4-- 0.4168819E-07 0.4168819E-07 0.0000000E+00 0.0000000E+00 Chg. balance for solid moles: 0.4235E-21 Mass of aqueous solution: 0.900275E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 0.0359900 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 0.3278E-05 -5.484 0.8595E-03 -3.066 1.026 0.3299E-03 quartz 0.1380E-02 -2.860 0.8291E-01 -1.081 98.97 0.3131E-01 stilpnomelane-Fe 0.3534E-08 -8.452 0.3810E-05 -5.419 0.4548E-02 0.1316E-05 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 quartz 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 0.083777 g Volume = 0.031643 cm3 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.0359900 moles log = -1.4438 Original solution: 1000.0103000 g Original solution / Rock added: 27785.78 (Water/Rock Ratio), log = 4.4438 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0206 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9997E+00 0.9859 0.1006E+01 0.1020E+01 CO2,gas 0.3280E-04 1.0071 0.3371E-04 0.3348E-04 CH4,gas 0.1230E-04 1.0125 0.1271E-04 0.1255E-04 H2,gas 0.2427E-03 1.0005 0.2479E-03 0.2477E-03 H2S,gas 0.7395E-05 0.9960 0.7517E-05 0.7547E-05 S2,gas 0.3383E-22 1.0000 0.3452E-22 0.3452E-22 CO,gas 0.2182E-11 1.0000 0.2227E-11 0.2227E-11 SO3,gas 0.5439E-39 1.0000 0.5551E-39 0.5551E-39 SO2,gas 0.5245E-20 1.0000 0.5353E-20 0.5353E-20 HF,gas 0.2827E-13 1.0000 0.2886E-13 0.2886E-13 HCl,gas 0.1315E-16 1.0000 0.1342E-16 0.1342E-16 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 17 albite -0.38 -0.38 0.00 0.000 -0.94784E-12 150 quartz -2.99 -2.99 0.00 0.000 0.00000E+00 167 stilpnomelane-Fe 13.02 13.02 0.00 0.000 -0.27298E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -12.83 -6.17 -2.057 0.10537E+05 -4.472 3 CH4,gas 4.54 -2.05 -6.59 -1.649 0.11261E+05 -4.896 4 H2,gas 8.00 2.70 -5.30 -3.031 0.90577E+04 -3.606 5 H2S,gas -6.23 -13.05 -6.82 -3.411 0.11650E+05 -5.124 6 S2,gas -7.34 -31.50 -24.16 -3.717 0.41254E+05 -22.462 7 CO,gas 3.21 -10.14 -13.35 -4.108 0.22797E+05 -11.652 8 SO3,gas 17.12 -23.83 -40.95 -10.239 0.69929E+05 -39.256 9 SO2,gas 0.83 -21.14 -21.97 -5.859 0.37514E+05 -20.271 10 HF,gas 0.47 -14.77 -15.24 -7.619 0.26020E+05 -13.540 11 HCl,gas 5.19 -13.38 -18.57 -9.286 0.31710E+05 -16.872 12 acmite 7.71 7.39 -0.32 -0.034 0.55338E+03 16 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 20 spessartine 24.46 19.55 -4.91 -0.246 0.83850E+04 21 analcite 3.32 2.61 -0.72 -0.080 0.12231E+04 23 andradite 39.01 37.66 -1.35 -0.070 0.23049E+04 24 grossular 32.73 28.10 -4.63 -0.232 0.79101E+04 26 ankerite -2.14 -7.02 -4.89 -0.815 0.83452E+04 27 annite 20.12 17.30 -2.82 -0.157 0.48214E+04 28 phlogopite 27.06 23.98 -3.09 -0.172 0.52729E+04 33 apatite-OH -18.15 -22.03 -3.88 -0.299 0.66264E+04 34 apatite-F -34.30 -36.80 -2.50 -0.208 0.42663E+04 38 aragonite 0.97 -0.79 -1.76 -0.585 0.29978E+04 39 brucite 12.57 8.82 -3.75 -0.749 0.63945E+04 40 calcite 0.81 -0.79 -1.60 -0.534 0.27336E+04 41 carnegieite-low 9.02 5.60 -3.43 -0.490 0.58537E+04 42 carnegieite-high 10.09 5.60 -4.50 -0.643 0.76807E+04 43 carpholite-Mg 8.58 3.79 -4.80 -0.320 0.81901E+04 45 celadonite 5.34 3.34 -2.00 -0.118 0.34178E+04 46 celadonite-Fe 3.88 1.11 -2.76 -0.162 0.47163E+04 47 chrysotile 23.89 20.49 -3.40 -0.283 0.58065E+04 49 clinochlore 39.07 36.09 -2.98 -0.093 0.50871E+04 50 daphnite 28.97 24.96 -4.00 -0.125 0.68349E+04 54 chloritoid-Fe 9.17 4.55 -4.62 -0.308 0.78959E+04 55 chloritoid-Mn 11.40 7.14 -4.26 -0.284 0.72710E+04 57 coesite -2.38 -2.99 -0.61 -0.204 0.10473E+04 64 cristobalite -2.56 -2.99 -0.43 -0.143 0.73267E+03 66 cymrite-K 1.69 -2.49 -4.18 -0.348 0.71365E+04 68 diaspore 2.87 0.47 -2.40 -0.401 0.41036E+04 69 diamond -3.10 -7.44 -4.34 -1.240 0.74085E+04 70 diopside 16.18 14.89 -1.29 -0.129 0.22105E+04 71 hedenbergite 14.21 12.66 -1.55 -0.155 0.26416E+04 78 epidote 24.67 21.31 -3.36 -0.163 0.57419E+04 80 epidote-Fe 29.84 26.09 -3.75 -0.195 0.64092E+04 81 fayalite 14.05 10.21 -3.84 -0.548 0.65554E+04 82 ferrosilite 11.15 7.22 -3.93 -0.393 0.67145E+04 86 gibbsite 4.08 0.47 -3.61 -0.516 0.61621E+04 87 glaucophane 22.97 19.72 -3.25 -0.088 0.55506E+04 88 glaucophane-Fe 17.28 13.05 -4.23 -0.114 0.72201E+04 89 graphite -3.55 -7.44 -3.90 -1.113 0.66507E+04 90 greenalite 16.14 13.82 -2.32 -0.194 0.39690E+04 93 hematite 12.57 10.50 -2.07 -0.250 0.35264E+04 94 heulandite -5.83 -7.94 -2.12 -0.096 0.36129E+04 98 jadeite 4.22 2.61 -1.61 -0.161 0.27485E+04 100 kalsilite 7.58 3.48 -4.10 -0.586 0.69993E+04 101 kaolinite -1.33 -5.04 -3.71 -0.337 0.63267E+04 104 laumontite 2.88 1.03 -1.86 -0.124 0.31729E+04 105 lawsonite 9.62 7.00 -2.61 -0.174 0.44600E+04 106 leucite 4.12 0.50 -3.62 -0.362 0.61872E+04 108 lizardite 23.24 20.49 -2.75 -0.229 0.46991E+04 109 magnesite 0.69 -4.01 -4.70 -1.566 0.80223E+04 110 magnetite 20.09 17.10 -2.99 -0.244 0.51029E+04 111 minnesotaite 10.39 7.84 -2.55 -0.150 0.43574E+04 115 manganosite 14.06 9.19 -4.87 -1.217 0.83098E+04 119 microcline -2.49 -2.49 -0.01 -0.001 0.13125E+02 123 muscovite 2.58 -1.55 -4.14 -0.243 0.70618E+04 124 paragonite 4.24 0.56 -3.68 -0.217 0.62878E+04 125 nepheline 8.34 5.60 -2.74 -0.392 0.46861E+04 137 phlogopite-Na 29.65 26.09 -3.56 -0.198 0.60786E+04 139 prehnite 19.37 16.06 -3.32 -0.195 0.56606E+04 140 prehnite-Fe 22.50 20.84 -1.66 -0.100 0.28363E+04 145 pyrite -21.25 -22.20 -0.96 -0.225 0.16331E+04 146 pyrrhotite -4.26 -6.46 -2.19 -0.732 0.37477E+04 147 pyrrhotiteFe0.875 -6.02 -7.61 -1.60 -0.587 0.27271E+04 148 pyroxmangite 7.40 6.20 -1.20 -0.239 0.20434E+04 149 pyrophyllite -6.18 -11.02 -4.84 -0.303 0.82661E+04 154 rhodochrosite -0.98 -3.64 -2.66 -0.888 0.45480E+04 155 rhodonite 7.45 6.20 -1.24 -0.249 0.21237E+04 156 sanidine -1.28 -2.49 -1.22 -0.094 0.20809E+04 158 siderite -2.61 -6.23 -3.63 -1.208 0.61899E+04 166 stilbite -7.52 -7.94 -0.42 -0.020 0.71902E+03 168 stilpnomelane-Mg 27.44 24.14 -3.30 -0.098 0.56287E+04 174 talc 16.49 14.51 -1.98 -0.116 0.33777E+04 177 tephroite 18.09 15.39 -2.69 -0.385 0.45974E+04 181 tridymite -2.63 -2.99 -0.36 -0.121 0.61998E+03 182 tremolite 47.87 44.29 -3.58 -0.097 0.61175E+04 184 troilite-low -4.41 -6.46 -2.04 -0.681 0.34905E+04 190 wairakite 3.95 1.03 -2.93 -0.172 0.49949E+04 191 walstromite 11.51 9.05 -2.46 -0.491 0.41945E+04 192 wollastonite 10.46 9.05 -1.41 -0.282 0.24049E+04 193 pseudo-wollastonite 11.00 9.05 -1.95 -0.389 0.33248E+04 195 akaganeite 7.75 5.25 -2.50 -0.541 0.42757E+04 202 chalcedony -2.80 -2.99 -0.19 -0.062 0.31930E+03 204 montmorillonite-Ca -2.29 -6.27 -3.98 -0.246 0.68004E+04 205 montmorillonite-K -2.24 -6.28 -4.04 -0.248 0.69024E+04 206 montmorillonite-Mg -2.48 -6.80 -4.32 -0.268 0.73842E+04 207 montmorillonite-Na -2.04 -5.58 -3.54 -0.217 0.60529E+04 208 nontronite-Ca 3.21 1.67 -1.54 -0.100 0.26341E+04 209 nontronite-H 2.53 -0.32 -2.85 -0.191 0.48625E+04 210 nontronite-K 3.34 1.67 -1.67 -0.107 0.28593E+04 211 nontronite-Mg 3.07 1.14 -1.93 -0.125 0.33020E+04 212 nontronite-Na 3.52 2.36 -1.16 -0.074 0.19758E+04 228 tobermorite 9.82 7.04 -2.78 -0.759 0.47492E+04 234 alabandite -0.98 -3.86 -2.88 -0.961 0.49242E+04 237 boehmite 4.41 0.47 -3.94 -0.656 0.67205E+04 239 ferrous-oxide 9.81 6.60 -3.21 -0.803 0.54872E+04 245 silica-amorphous -2.09 -2.99 -0.90 -0.299 0.15335E+04 247 an20ab80 2.02 1.09 -0.92 -0.071 0.15778E+04 248 an25ab75 2.65 1.46 -1.18 -0.091 0.20192E+04 249 an30ab70 3.28 1.83 -1.45 -0.111 0.24703E+04 250 tr.625ac.25prg.125 45.16 42.34 -2.83 -0.076 0.48240E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 0.0010000 MOLES Current total amount of reactant added: 0.0359900 MOLES New total amount of reactant added: 0.0369900 MOLES Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.5508E-08 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 7 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 0.0369900 Water: Moles liquid = 0.4988E+02 kg liquid = 0.8987E+00 Moles total = 0.4988E+02 kg total = 0.8985E+00 Activity = 1.0000 Stoichiometric ionic strength = .1371709E-01 Osmotic coef. = 0.9339 True ionic strength = .2214120E-01 Chg. balance for total moles = -.5508E-08 Max. difference allowed = 0.3561E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.15599E-09 -9.8069 0.13025E-09 -9.8852 0.83499E+00 -0.0783 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.39445E-03 -3.4040 0.32722E-03 -3.4852 0.82956E+00 -0.0812 4 SO4-- 0.17970E-03 -3.7455 0.90866E-04 -4.0416 0.50566E+00 -0.2961 5 HCO3- 0.14207E-02 -2.8475 0.11805E-02 -2.9279 0.83087E+00 -0.0805 6 HS- 0.84836E-03 -3.0714 0.70388E-03 -3.1525 0.82969E+00 -0.0811 7 Al+++ 0.30306E-28 -28.5185 0.65863E-29 -29.1814 0.21733E+00 -0.6629 8 H4SiO4 0.10246E-02 -2.9894 0.10246E-02 -2.9894 0.10000E+01 0.0000 9 Ca++ 0.35934E-07 -7.4445 0.18026E-07 -7.7441 0.50164E+00 -0.2996 10 Mg++ 0.22148E-10 -10.6547 0.11055E-10 -10.9564 0.49915E+00 -0.3018 11 Fe++ 0.13416E-12 -12.8724 0.67044E-13 -13.1736 0.49974E+00 -0.3013 12 K+ 0.15650E-03 -3.8055 0.13007E-03 -3.8858 0.83108E+00 -0.0804 13 Na+ 0.20236E-01 -1.6939 0.16783E-01 -1.7751 0.82939E+00 -0.0812 14 Mn++ 0.52542E-10 -10.2795 0.26281E-10 -10.5804 0.50019E+00 -0.3009 15 F- 0.16522E-04 -4.7819 0.13675E-04 -4.8641 0.82771E+00 -0.0821 16 HPO4-- 0.45689E-07 -7.3402 0.23107E-07 -7.6363 0.50573E+00 -0.2961 18 HSiO3- 0.88547E-02 -2.0528 0.73455E-02 -2.1340 0.82956E+00 -0.0812 19 Ca(HSiO3)+ 0.36274E-08 -8.4404 0.30154E-08 -8.5207 0.83128E+00 -0.0803 20 Mg(HSiO3)+ 0.27687E-11 -11.5577 0.23016E-11 -11.6380 0.83128E+00 -0.0803 21 NaHSiO3,aq 0.19939E-02 -2.7003 0.19939E-02 -2.7003 0.10000E+01 0.0000 22 AlO+ 0.63538E-16 -16.1970 0.52817E-16 -16.2772 0.83128E+00 -0.0803 24 HAlO2,aq 0.80757E-10 -10.0928 0.80757E-10 -10.0928 0.10000E+01 0.0000 25 AlO2- 0.16577E-05 -5.7805 0.13725E-05 -5.8625 0.82794E+00 -0.0820 26 CH4,aq 0.89197E-08 -8.0497 0.88825E-08 -8.0515 0.99583E+00 -0.0018 27 C2H6,aq 0.71979E-19 -19.1428 0.71679E-19 -19.1446 0.99583E+00 -0.0018 31 CO,aq 0.15530E-14 -14.8088 0.15530E-14 -14.8088 0.10000E+01 0.0000 32 CO2,aq 0.32991E-06 -6.4816 0.32853E-06 -6.4834 0.99583E+00 -0.0018 33 CO3-2 0.15692E-02 -2.8043 0.79163E-03 -3.1015 0.50450E+00 -0.2971 34 CaCO3,aq 0.17893E-06 -6.7473 0.17893E-06 -6.7473 0.10000E+01 0.0000 35 Ca(HCO3)+ 0.65340E-09 -9.1848 0.54316E-09 -9.2651 0.83128E+00 -0.0803 36 CaCl+ 0.11483E-10 -10.9400 0.95454E-11 -11.0202 0.83128E+00 -0.0803 37 CaCl2,aq 0.74207E-15 -15.1296 0.74207E-15 -15.1296 0.10000E+01 0.0000 38 CaF+ 0.43294E-11 -11.3636 0.35990E-11 -11.4438 0.83128E+00 -0.0803 39 CaOH+ 0.11865E-07 -7.9257 0.98633E-08 -8.0060 0.83128E+00 -0.0803 40 CaSO4,aq 0.52012E-09 -9.2839 0.52012E-09 -9.2839 0.10000E+01 0.0000 41 HCl,aq 0.78099E-14 -14.1074 0.78099E-14 -14.1074 0.10000E+01 0.0000 45 HF,aq 0.12193E-10 -10.9139 0.12193E-10 -10.9139 0.10000E+01 0.0000 46 HF2- 0.67864E-16 -16.1684 0.56297E-16 -16.2495 0.82956E+00 -0.0812 48 FeCl+ 0.41773E-16 -16.3791 0.34725E-16 -16.4594 0.83128E+00 -0.0803 51 FeF+ 0.56361E-16 -16.2490 0.46852E-16 -16.3293 0.83128E+00 -0.0803 53 FeO,aq 0.15360E-09 -9.8136 0.15360E-09 -9.8136 0.10000E+01 0.0000 54 FeOH+ 0.20156E-10 -10.6956 0.16755E-10 -10.7758 0.83128E+00 -0.0803 55 HFeO2- 0.14874E-07 -7.8276 0.12339E-07 -7.9087 0.82956E+00 -0.0812 56 FeO+ 0.11083E-15 -15.9553 0.92129E-16 -16.0356 0.83128E+00 -0.0803 58 FeO2- 0.13395E-08 -8.8730 0.11112E-08 -8.9542 0.82956E+00 -0.0812 59 HFeO2,aq 0.18408E-10 -10.7350 0.18408E-10 -10.7350 0.10000E+01 0.0000 60 H2,aq 0.18896E-06 -6.7236 0.18818E-06 -6.7254 0.99583E+00 -0.0018 61 KCl,aq 0.77137E-09 -9.1127 0.77137E-09 -9.1127 0.10000E+01 0.0000 62 KHSO4,aq 0.43523E-17 -17.3613 0.43523E-17 -17.3613 0.10000E+01 0.0000 63 KOH,aq 0.42646E-06 -6.3701 0.42646E-06 -6.3701 0.10000E+01 0.0000 64 KSO4- 0.22107E-06 -6.6555 0.18339E-06 -6.7366 0.82956E+00 -0.0812 65 MgCO3,aq 0.27507E-10 -10.5606 0.27507E-10 -10.5606 0.10000E+01 0.0000 66 Mg(HCO3)+ 0.40948E-12 -12.3878 0.34039E-12 -12.4680 0.83128E+00 -0.0803 67 MgCl+ 0.63830E-14 -14.1950 0.53060E-14 -14.2752 0.83128E+00 -0.0803 68 MgF+ 0.98361E-14 -14.0072 0.81765E-14 -14.0874 0.83128E+00 -0.0803 69 MgOH+ 0.40268E-10 -10.3950 0.33474E-10 -10.4753 0.83128E+00 -0.0803 71 MnF+ 0.72822E-14 -14.1377 0.60535E-14 -14.2180 0.83128E+00 -0.0803 72 MnO,aq 0.16043E-08 -8.7947 0.16043E-08 -8.7947 0.10000E+01 0.0000 73 MnOH+ 0.73399E-09 -9.1343 0.61015E-09 -9.2146 0.83128E+00 -0.0803 74 MnO2-2 0.62211E-11 -11.2061 0.31385E-11 -11.5033 0.50450E+00 -0.2971 75 HMnO2- 0.10796E-09 -9.9667 0.89558E-10 -10.0479 0.82956E+00 -0.0812 78 MnCl+ 0.63705E-13 -13.1958 0.52957E-13 -13.2761 0.83128E+00 -0.0803 79 MnSO4,aq 0.68942E-12 -12.1615 0.68942E-12 -12.1615 0.10000E+01 0.0000 80 NaCl,aq 0.18200E-05 -5.7399 0.18200E-05 -5.7399 0.10000E+01 0.0000 81 NaF,aq 0.53733E-07 -7.2698 0.53733E-07 -7.2698 0.10000E+01 0.0000 82 NaOH,aq 0.55363E-04 -4.2568 0.55363E-04 -4.2568 0.10000E+01 0.0000 84 OH- 0.53578E-02 -2.2710 0.44360E-02 -2.3530 0.82794E+00 -0.0820 89 HPO3-2 0.26859E-16 -16.5709 0.13550E-16 -16.8681 0.50450E+00 -0.2971 92 H3PO4,aq 0.27416E-17 -17.5620 0.27416E-17 -17.5620 0.10000E+01 0.0000 93 H2PO4- 0.66857E-10 -10.1749 0.55519E-10 -10.2556 0.83041E+00 -0.0807 94 PO4-3 0.63158E-09 -9.1996 0.14474E-09 -9.8394 0.22918E+00 -0.6398 98 HP2O7-3 0.17030E-17 -17.7688 0.37052E-18 -18.4312 0.21757E+00 -0.6624 99 P2O7-4 0.98025E-17 -17.0087 0.67960E-18 -18.1677 0.69329E-01 -1.1591 100 H2S,aq 0.28453E-06 -6.5459 0.28334E-06 -6.5477 0.99583E+00 -0.0018 101 S2-2 0.11564E-09 -9.9369 0.58340E-10 -10.2340 0.50450E+00 -0.2971 102 S3-2 0.23459E-15 -15.6297 0.11835E-15 -15.9268 0.50450E+00 -0.2971 103 S3- 0.28714E-19 -19.5419 0.23820E-19 -19.6231 0.82956E+00 -0.0812 107 SO3-2 0.43365E-11 -11.3629 0.22220E-11 -11.6533 0.51239E+00 -0.2904 108 HSO3- 0.21844E-13 -13.6607 0.18121E-13 -13.7418 0.82956E+00 -0.0812 109 HSO4- 0.13706E-10 -10.8631 0.11406E-10 -10.9429 0.83216E+00 -0.0798 111 S2O3-2 0.59949E-12 -12.2222 0.30244E-12 -12.5194 0.50450E+00 -0.2971 Charge balance for all species = -.6128E-08 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.1559875E-09 -.1783766E-01 -.1794727E+02 0.0000 2 H2O 0.1000000E+01 0.5550282E+02 0.9981194E+06 0.0000 3 Cl- 0.3944521E-03 0.3962729E-03 0.1402404E+02 6.4001 4 SO4-- 0.1796992E-03 0.1798649E-03 0.1724734E+02 15.7289 5 HCO3- 0.1420745E-02 0.2990416E-02 0.1821419E+03 6.9573 6 HS- 0.8483635E-03 0.8487042E-03 0.2801836E+02 6.7327 7 Al+++ 0.3030579E-28 0.1657787E-05 0.4464994E-01 0.4743 8 H4SiO4 0.1024625E-02 0.1187323E-01 0.1139168E+04 -2.9894 9 Ca++ 0.3593374E-07 0.2315417E-06 0.9263205E-02 12.0263 10 Mg++ 0.2214828E-10 0.9311729E-10 0.2259836E-05 8.8140 11 Fe++ 0.1341564E-12 0.1640578E-07 0.9145818E-03 6.5968 12 K+ 0.1565006E-03 0.1571489E-03 0.6133893E+01 5.9994 13 Na+ 0.2023567E-01 0.2228682E-01 0.5114572E+03 8.1101 14 Mn++ 0.5254196E-10 0.2505811E-08 0.1374191E-03 9.1901 15 F- 0.1652155E-04 0.1657530E-04 0.3143367E+00 5.0212 16 HPO4-- 0.4568946E-07 0.4638790E-07 0.4444336E-02 12.1342 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.1604364E-01 -.1603047E-01 -.1317242E-04 0.0000000E+00 2 H2O 0.4987669E+02 0.4987965E+02 -.2958809E-02 0.0000000E+00 3 Cl- 0.3561252E-03 0.3561252E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.1616422E-03 0.1616422E-03 0.0000000E+00 0.0000000E+00 5 HCO3- 0.2687447E-02 0.2687447E-02 0.0000000E+00 0.0000000E+00 6 HS- 0.7627193E-03 0.7627193E-03 0.0000000E+00 0.0000000E+00 7 Al+++ 0.4775352E-05 0.1489832E-05 0.3285520E-05 0.0000000E+00 8 H4SiO4 0.1215302E-01 0.1067031E-01 0.1482709E-02 0.0000000E+00 9 Ca++ 0.2080835E-06 0.2080835E-06 0.0000000E+00 0.0000000E+00 10 Mg++ 0.8368328E-10 0.8368328E-10 0.0000000E+00 0.0000000E+00 11 Fe++ 0.3259227E-07 0.1474365E-07 0.1784862E-07 0.0000000E+00 12 K+ 0.1412294E-03 0.1412276E-03 0.1784862E-08 0.0000000E+00 13 Na+ 0.2003215E-01 0.2002887E-01 0.3278381E-05 0.0000000E+00 14 Mn++ 0.2251939E-08 0.2251939E-08 0.0000000E+00 0.0000000E+00 15 F- 0.1489600E-04 0.1489600E-04 0.0000000E+00 0.0000000E+00 16 HPO4-- 0.4168819E-07 0.4168819E-07 0.0000000E+00 0.0000000E+00 Chg. balance for solid moles: -.8470E-21 Mass of aqueous solution: 0.900290E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 0.0369900 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 0.3278E-05 -5.484 0.8597E-03 -3.066 0.9621 0.3300E-03 quartz 0.1473E-02 -2.832 0.8849E-01 -1.053 99.03 0.3342E-01 stilpnomelane-Fe 0.3570E-08 -8.447 0.3848E-05 -5.415 0.4307E-02 0.1329E-05 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 quartz 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 0.089352 g Volume = 0.033748 cm3 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.0369900 moles log = -1.4319 Original solution: 1000.0103000 g Original solution / Rock added: 27034.61 (Water/Rock Ratio), log = 4.4319 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0206 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9997E+00 0.9859 0.1006E+01 0.1020E+01 CO2,gas 0.3420E-04 1.0071 0.3515E-04 0.3490E-04 CH4,gas 0.1265E-04 1.0125 0.1307E-04 0.1291E-04 H2,gas 0.2419E-03 1.0005 0.2471E-03 0.2469E-03 H2S,gas 0.7662E-05 0.9960 0.7789E-05 0.7820E-05 S2,gas 0.3656E-22 1.0000 0.3731E-22 0.3731E-22 CO,gas 0.2268E-11 1.0000 0.2314E-11 0.2314E-11 SO3,gas 0.5711E-39 1.0000 0.5828E-39 0.5828E-39 SO2,gas 0.5489E-20 1.0000 0.5602E-20 0.5602E-20 HF,gas 0.2933E-13 1.0000 0.2994E-13 0.2994E-13 HCl,gas 0.1350E-16 1.0000 0.1378E-16 0.1378E-16 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 17 albite -0.38 -0.38 0.00 0.000 -0.13080E-10 150 quartz -2.99 -2.99 0.00 0.000 0.00000E+00 167 stilpnomelane-Fe 13.02 13.02 0.00 0.000 0.21232E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -12.81 -6.15 -2.051 0.10506E+05 -4.454 3 CH4,gas 4.54 -2.04 -6.58 -1.646 0.11240E+05 -4.884 4 H2,gas 8.00 2.69 -5.31 -3.032 0.90602E+04 -3.607 5 H2S,gas -6.23 -13.04 -6.81 -3.404 0.11624E+05 -5.109 6 S2,gas -7.34 -31.46 -24.13 -3.712 0.41196E+05 -22.428 7 CO,gas 3.21 -10.12 -13.33 -4.103 0.22768E+05 -11.636 8 SO3,gas 17.12 -23.81 -40.93 -10.233 0.69893E+05 -39.234 9 SO2,gas 0.83 -21.12 -21.95 -5.853 0.37480E+05 -20.252 10 HF,gas 0.47 -14.75 -15.22 -7.611 0.25992E+05 -13.524 11 HCl,gas 5.19 -13.37 -18.56 -9.280 0.31690E+05 -16.861 12 acmite 7.71 7.38 -0.33 -0.034 0.56082E+03 16 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 20 spessartine 24.46 19.55 -4.91 -0.245 0.83780E+04 21 analcite 3.32 2.61 -0.72 -0.080 0.12231E+04 23 andradite 39.01 37.61 -1.40 -0.073 0.23870E+04 24 grossular 32.73 28.06 -4.67 -0.234 0.79774E+04 26 ankerite -2.14 -7.00 -4.87 -0.811 0.83122E+04 27 annite 20.12 17.30 -2.83 -0.157 0.48279E+04 28 phlogopite 27.06 23.95 -3.12 -0.173 0.53223E+04 33 apatite-OH -18.15 -22.09 -3.93 -0.303 0.67188E+04 34 apatite-F -34.30 -36.84 -2.54 -0.211 0.43314E+04 38 aragonite 0.97 -0.79 -1.75 -0.584 0.29938E+04 39 brucite 12.57 8.81 -3.75 -0.751 0.64108E+04 40 calcite 0.81 -0.79 -1.60 -0.533 0.27296E+04 41 carnegieite-low 9.02 5.60 -3.43 -0.490 0.58537E+04 42 carnegieite-high 10.09 5.60 -4.50 -0.643 0.76807E+04 43 carpholite-Mg 8.58 3.78 -4.80 -0.320 0.81929E+04 45 celadonite 5.34 3.33 -2.01 -0.118 0.34347E+04 46 celadonite-Fe 3.88 1.11 -2.76 -0.163 0.47190E+04 47 chrysotile 23.89 20.46 -3.43 -0.286 0.58552E+04 49 clinochlore 39.07 36.05 -3.02 -0.094 0.51549E+04 50 daphnite 28.97 24.96 -4.00 -0.125 0.68312E+04 54 chloritoid-Fe 9.17 4.56 -4.62 -0.308 0.78844E+04 55 chloritoid-Mn 11.40 7.15 -4.25 -0.283 0.72597E+04 57 coesite -2.38 -2.99 -0.61 -0.204 0.10473E+04 64 cristobalite -2.56 -2.99 -0.43 -0.143 0.73267E+03 66 cymrite-K 1.69 -2.49 -4.18 -0.348 0.71372E+04 68 diaspore 2.87 0.47 -2.40 -0.400 0.40969E+04 69 diamond -3.10 -7.43 -4.32 -1.235 0.73825E+04 70 diopside 16.18 14.86 -1.32 -0.132 0.22536E+04 71 hedenbergite 14.21 12.64 -1.56 -0.156 0.26705E+04 78 epidote 24.67 21.28 -3.39 -0.164 0.57829E+04 80 epidote-Fe 29.84 26.06 -3.78 -0.196 0.64577E+04 81 fayalite 14.05 10.20 -3.84 -0.549 0.65593E+04 82 ferrosilite 11.15 7.21 -3.93 -0.393 0.67184E+04 86 gibbsite 4.08 0.47 -3.60 -0.515 0.61554E+04 87 glaucophane 22.97 19.70 -3.28 -0.089 0.55993E+04 88 glaucophane-Fe 17.28 13.04 -4.23 -0.114 0.72260E+04 89 graphite -3.55 -7.43 -3.88 -1.109 0.66247E+04 90 greenalite 16.14 13.81 -2.33 -0.194 0.39749E+04 93 hematite 12.57 10.50 -2.07 -0.250 0.35279E+04 94 heulandite -5.83 -7.95 -2.12 -0.097 0.36263E+04 98 jadeite 4.22 2.61 -1.61 -0.161 0.27485E+04 100 kalsilite 7.58 3.48 -4.10 -0.586 0.70000E+04 101 kaolinite -1.33 -5.03 -3.70 -0.336 0.63133E+04 104 laumontite 2.88 1.02 -1.87 -0.124 0.31864E+04 105 lawsonite 9.62 7.00 -2.62 -0.175 0.44735E+04 106 leucite 4.12 0.49 -3.62 -0.362 0.61879E+04 108 lizardite 23.24 20.46 -2.78 -0.232 0.47478E+04 109 magnesite 0.69 -4.00 -4.69 -1.563 0.80076E+04 110 magnetite 20.09 17.10 -2.99 -0.244 0.51062E+04 111 minnesotaite 10.39 7.83 -2.56 -0.150 0.43633E+04 115 manganosite 14.06 9.19 -4.87 -1.217 0.83120E+04 119 microcline -2.49 -2.49 -0.01 -0.001 0.13813E+02 123 muscovite 2.58 -1.55 -4.13 -0.243 0.70491E+04 124 paragonite 4.24 0.56 -3.67 -0.216 0.62743E+04 125 nepheline 8.34 5.60 -2.74 -0.392 0.46861E+04 137 phlogopite-Na 29.65 26.06 -3.59 -0.199 0.61273E+04 139 prehnite 19.37 16.03 -3.34 -0.196 0.57010E+04 140 prehnite-Fe 22.50 20.81 -1.69 -0.102 0.28841E+04 145 pyrite -21.25 -22.17 -0.93 -0.218 0.15799E+04 146 pyrrhotite -4.26 -6.44 -2.18 -0.727 0.37233E+04 147 pyrrhotiteFe0.875 -6.02 -7.60 -1.58 -0.582 0.27022E+04 148 pyroxmangite 7.40 6.20 -1.20 -0.240 0.20456E+04 149 pyrophyllite -6.18 -11.01 -4.83 -0.302 0.82527E+04 154 rhodochrosite -0.98 -3.62 -2.65 -0.882 0.45193E+04 155 rhodonite 7.45 6.20 -1.25 -0.249 0.21258E+04 156 sanidine -1.28 -2.49 -1.22 -0.094 0.20816E+04 158 siderite -2.61 -6.22 -3.61 -1.203 0.61609E+04 166 stilbite -7.52 -7.95 -0.43 -0.020 0.73248E+03 168 stilpnomelane-Mg 27.44 24.10 -3.34 -0.100 0.57002E+04 174 talc 16.49 14.48 -2.01 -0.118 0.34264E+04 177 tephroite 18.09 15.39 -2.70 -0.385 0.46017E+04 181 tridymite -2.63 -2.99 -0.36 -0.121 0.61998E+03 182 tremolite 47.87 44.21 -3.66 -0.099 0.62525E+04 184 troilite-low -4.41 -6.44 -2.03 -0.677 0.34661E+04 190 wairakite 3.95 1.02 -2.93 -0.173 0.50083E+04 191 walstromite 11.51 9.04 -2.47 -0.494 0.42214E+04 192 wollastonite 10.46 9.04 -1.42 -0.285 0.24318E+04 193 pseudo-wollastonite 11.00 9.04 -1.96 -0.393 0.33517E+04 195 akaganeite 7.75 5.25 -2.50 -0.542 0.42765E+04 202 chalcedony -2.80 -2.99 -0.19 -0.062 0.31930E+03 204 montmorillonite-Ca -2.29 -6.27 -3.98 -0.246 0.67990E+04 205 montmorillonite-K -2.24 -6.28 -4.04 -0.247 0.68990E+04 206 montmorillonite-Mg -2.48 -6.80 -4.32 -0.267 0.73810E+04 207 montmorillonite-Na -2.04 -5.58 -3.54 -0.217 0.60493E+04 208 nontronite-Ca 3.21 1.67 -1.54 -0.100 0.26378E+04 209 nontronite-H 2.53 -0.31 -2.85 -0.191 0.48618E+04 210 nontronite-K 3.34 1.67 -1.68 -0.108 0.28609E+04 211 nontronite-Mg 3.07 1.14 -1.93 -0.126 0.33039E+04 212 nontronite-Na 3.52 2.36 -1.16 -0.074 0.19773E+04 228 tobermorite 9.82 7.03 -2.79 -0.762 0.47716E+04 234 alabandite -0.98 -3.85 -2.87 -0.957 0.49000E+04 237 boehmite 4.41 0.47 -3.93 -0.655 0.67138E+04 239 ferrous-oxide 9.81 6.60 -3.21 -0.804 0.54891E+04 245 silica-amorphous -2.09 -2.99 -0.90 -0.299 0.15335E+04 247 an20ab80 2.02 1.09 -0.93 -0.071 0.15805E+04 248 an25ab75 2.65 1.46 -1.18 -0.091 0.20226E+04 249 an30ab70 3.28 1.83 -1.45 -0.111 0.24743E+04 250 tr.625ac.25prg.125 45.16 42.27 -2.89 -0.078 0.49374E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 0.0010000 MOLES Current total amount of reactant added: 0.0369900 MOLES New total amount of reactant added: 0.0379900 MOLES Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.5508E-08 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 7 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 0.0379900 Water: Moles liquid = 0.4989E+02 kg liquid = 0.8987E+00 Moles total = 0.4988E+02 kg total = 0.8986E+00 Activity = 1.0000 Stoichiometric ionic strength = .1378204E-01 Osmotic coef. = 0.9336 True ionic strength = .2219970E-01 Chg. balance for total moles = -.5508E-08 Max. difference allowed = 0.3620E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.15756E-09 -9.8026 0.13154E-09 -9.8810 0.83485E+00 -0.0784 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.40098E-03 -3.3969 0.33258E-03 -3.4781 0.82941E+00 -0.0812 4 SO4-- 0.18500E-03 -3.7328 0.93482E-04 -4.0293 0.50530E+00 -0.2965 5 HCO3- 0.14661E-02 -2.8338 0.12179E-02 -2.9144 0.83073E+00 -0.0805 6 HS- 0.87006E-03 -3.0604 0.72175E-03 -3.1416 0.82954E+00 -0.0812 7 Al+++ 0.31551E-28 -28.5010 0.68457E-29 -29.1646 0.21697E+00 -0.6636 8 H4SiO4 0.10246E-02 -2.9894 0.10246E-02 -2.9894 0.10000E+01 0.0000 9 Ca++ 0.35381E-07 -7.4512 0.17736E-07 -7.7512 0.50127E+00 -0.2999 10 Mg++ 0.22114E-10 -10.6553 0.11030E-10 -10.9574 0.49879E+00 -0.3021 11 Fe++ 0.13656E-12 -12.8647 0.68196E-13 -13.1662 0.49938E+00 -0.3016 12 K+ 0.15650E-03 -3.8055 0.13004E-03 -3.8859 0.83094E+00 -0.0804 13 Na+ 0.20254E-01 -1.6935 0.16795E-01 -1.7748 0.82924E+00 -0.0813 14 Mn++ 0.53467E-10 -10.2719 0.26724E-10 -10.5731 0.49983E+00 -0.3012 15 F- 0.16965E-04 -4.7705 0.14039E-04 -4.8527 0.82756E+00 -0.0822 16 HPO4-- 0.45694E-07 -7.3401 0.23092E-07 -7.6365 0.50538E+00 -0.2964 18 HSiO3- 0.87696E-02 -2.0570 0.72736E-02 -2.1383 0.82941E+00 -0.0812 19 Ca(HSiO3)+ 0.35348E-08 -8.4516 0.29379E-08 -8.5320 0.83113E+00 -0.0803 20 Mg(HSiO3)+ 0.27359E-11 -11.5629 0.22739E-11 -11.6432 0.83113E+00 -0.0803 21 NaHSiO3,aq 0.19758E-02 -2.7043 0.19758E-02 -2.7043 0.10000E+01 0.0000 22 AlO+ 0.64765E-16 -16.1887 0.53828E-16 -16.2690 0.83113E+00 -0.0803 24 HAlO2,aq 0.81497E-10 -10.0889 0.81497E-10 -10.0889 0.10000E+01 0.0000 25 AlO2- 0.16568E-05 -5.7807 0.13715E-05 -5.8628 0.82779E+00 -0.0821 26 CH4,aq 0.91724E-08 -8.0375 0.91340E-08 -8.0393 0.99581E+00 -0.0018 27 C2H6,aq 0.76364E-19 -19.1171 0.76045E-19 -19.1189 0.99581E+00 -0.0018 31 CO,aq 0.16128E-14 -14.7924 0.16128E-14 -14.7924 0.10000E+01 0.0000 32 CO2,aq 0.34374E-06 -6.4638 0.34230E-06 -6.4656 0.99581E+00 -0.0018 33 CO3-2 0.16042E-02 -2.7947 0.80874E-03 -3.0922 0.50414E+00 -0.2975 34 CaCO3,aq 0.17985E-06 -6.7451 0.17985E-06 -6.7451 0.10000E+01 0.0000 35 Ca(HCO3)+ 0.66340E-09 -9.1782 0.55137E-09 -9.2586 0.83113E+00 -0.0803 36 CaCl+ 0.11485E-10 -10.9399 0.95456E-11 -11.0202 0.83113E+00 -0.0803 37 CaCl2,aq 0.75422E-15 -15.1225 0.75422E-15 -15.1225 0.10000E+01 0.0000 38 CaF+ 0.43741E-11 -11.3591 0.36354E-11 -11.4394 0.83113E+00 -0.0803 39 CaOH+ 0.11562E-07 -7.9370 0.96097E-08 -8.0173 0.83113E+00 -0.0803 40 CaSO4,aq 0.52648E-09 -9.2786 0.52648E-09 -9.2786 0.10000E+01 0.0000 41 HCl,aq 0.80162E-14 -14.0960 0.80162E-14 -14.0960 0.10000E+01 0.0000 45 HF,aq 0.12642E-10 -10.8982 0.12642E-10 -10.8982 0.10000E+01 0.0000 46 HF2- 0.72248E-16 -16.1412 0.59923E-16 -16.2224 0.82941E+00 -0.0812 48 FeCl+ 0.43193E-16 -16.3646 0.35899E-16 -16.4449 0.83113E+00 -0.0803 51 FeF+ 0.58867E-16 -16.2301 0.48926E-16 -16.3105 0.83113E+00 -0.0803 53 FeO,aq 0.15319E-09 -9.8148 0.15319E-09 -9.8148 0.10000E+01 0.0000 54 FeOH+ 0.20305E-10 -10.6924 0.16876E-10 -10.7727 0.83113E+00 -0.0803 55 HFeO2- 0.14692E-07 -7.8329 0.12186E-07 -7.9141 0.82941E+00 -0.0812 56 FeO+ 0.11183E-15 -15.9514 0.92947E-16 -16.0318 0.83113E+00 -0.0803 58 FeO2- 0.13253E-08 -8.8777 0.10993E-08 -8.9589 0.82941E+00 -0.0812 59 HFeO2,aq 0.18390E-10 -10.7354 0.18390E-10 -10.7354 0.10000E+01 0.0000 60 H2,aq 0.18835E-06 -6.7250 0.18756E-06 -6.7269 0.99581E+00 -0.0018 61 KCl,aq 0.78383E-09 -9.1058 0.78383E-09 -9.1058 0.10000E+01 0.0000 62 KHSO4,aq 0.45209E-17 -17.3448 0.45209E-17 -17.3448 0.10000E+01 0.0000 63 KOH,aq 0.42219E-06 -6.3745 0.42219E-06 -6.3745 0.10000E+01 0.0000 64 KSO4- 0.22743E-06 -6.6431 0.18863E-06 -6.7244 0.82941E+00 -0.0812 65 MgCO3,aq 0.28037E-10 -10.5523 0.28037E-10 -10.5523 0.10000E+01 0.0000 66 Mg(HCO3)+ 0.42158E-12 -12.3751 0.35039E-12 -12.4554 0.83113E+00 -0.0803 67 MgCl+ 0.64738E-14 -14.1888 0.53806E-14 -14.2692 0.83113E+00 -0.0803 68 MgF+ 0.10077E-13 -13.9967 0.83752E-14 -14.0770 0.83113E+00 -0.0803 69 MgOH+ 0.39790E-10 -10.4002 0.33071E-10 -10.4806 0.83113E+00 -0.0803 71 MnF+ 0.76037E-14 -14.1190 0.63196E-14 -14.1993 0.83113E+00 -0.0803 72 MnO,aq 0.15996E-08 -8.7960 0.15996E-08 -8.7960 0.10000E+01 0.0000 73 MnOH+ 0.73920E-09 -9.1312 0.61437E-09 -9.2116 0.83113E+00 -0.0803 74 MnO2-2 0.60863E-11 -11.2156 0.30683E-11 -11.5131 0.50414E+00 -0.2975 75 HMnO2- 0.10661E-09 -9.9722 0.88420E-10 -10.0534 0.82941E+00 -0.0812 78 MnCl+ 0.65851E-13 -13.1814 0.54731E-13 -13.2618 0.83113E+00 -0.0803 79 MnSO4,aq 0.72122E-12 -12.1419 0.72122E-12 -12.1419 0.10000E+01 0.0000 80 NaCl,aq 0.18511E-05 -5.7326 0.18511E-05 -5.7326 0.10000E+01 0.0000 81 NaF,aq 0.55204E-07 -7.2580 0.55204E-07 -7.2580 0.10000E+01 0.0000 82 NaOH,aq 0.54860E-04 -4.2607 0.54860E-04 -4.2607 0.10000E+01 0.0000 84 OH- 0.53063E-02 -2.2752 0.43925E-02 -2.3573 0.82779E+00 -0.0821 89 HPO3-2 0.26773E-16 -16.5723 0.13497E-16 -16.8697 0.50414E+00 -0.2975 92 H3PO4,aq 0.27943E-17 -17.5537 0.27943E-17 -17.5537 0.10000E+01 0.0000 93 H2PO4- 0.67489E-10 -10.1708 0.56033E-10 -10.2516 0.83026E+00 -0.0808 94 PO4-3 0.62596E-09 -9.2035 0.14324E-09 -9.8439 0.22883E+00 -0.6405 98 HP2O7-3 0.17205E-17 -17.7644 0.37372E-18 -18.4275 0.21722E+00 -0.6631 99 P2O7-4 0.98181E-17 -17.0080 0.67876E-18 -18.1683 0.69133E-01 -1.1603 100 H2S,aq 0.29465E-06 -6.5307 0.29341E-06 -6.5325 0.99581E+00 -0.0018 101 S2-2 0.12207E-09 -9.9134 0.61542E-10 -10.2108 0.50414E+00 -0.2975 102 S3-2 0.25729E-15 -15.5896 0.12971E-15 -15.8870 0.50414E+00 -0.2975 103 S3- 0.31838E-19 -19.4971 0.26407E-19 -19.5783 0.82941E+00 -0.0812 107 SO3-2 0.44497E-11 -11.3517 0.22784E-11 -11.6424 0.51204E+00 -0.2907 108 HSO3- 0.22624E-13 -13.6454 0.18765E-13 -13.7267 0.82941E+00 -0.0812 109 HSO4- 0.14243E-10 -10.8464 0.11850E-10 -10.9263 0.83201E+00 -0.0799 111 S2O3-2 0.63911E-12 -12.1944 0.32220E-12 -12.4919 0.50414E+00 -0.2975 Charge balance for all species = -.6128E-08 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.1575560E-09 -.1771750E-01 -.1782642E+02 0.0000 2 H2O 0.1000000E+01 0.5550287E+02 0.9981228E+06 0.0000 3 Cl- 0.4009783E-03 0.4028303E-03 0.1425615E+02 6.4028 4 SO4-- 0.1850027E-03 0.1851746E-03 0.1775654E+02 15.7326 5 HCO3- 0.1466062E-02 0.3070807E-02 0.1870389E+03 6.9666 6 HS- 0.8700627E-03 0.8704136E-03 0.2873513E+02 6.7393 7 Al+++ 0.3155091E-28 0.1656908E-05 0.4462635E-01 0.4783 8 H4SiO4 0.1024625E-02 0.1177002E-01 0.1129268E+04 -2.9894 9 Ca++ 0.3538144E-07 0.2315373E-06 0.9263050E-02 12.0108 10 Mg++ 0.2211418E-10 0.9311550E-10 0.2259798E-05 8.8045 11 Fe++ 0.1365610E-12 0.1620945E-07 0.9036392E-03 6.5957 12 K+ 0.1564954E-03 0.1571458E-03 0.6133790E+01 5.9950 13 Na+ 0.2025382E-01 0.2228639E-01 0.5114486E+03 8.1061 14 Mn++ 0.5346730E-10 0.2505763E-08 0.1374168E-03 9.1888 15 F- 0.1696484E-04 0.1702006E-04 0.3227722E+00 5.0283 16 HPO4-- 0.4569356E-07 0.4638700E-07 0.4444261E-02 12.1254 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.1593597E-01 -.1592279E-01 -.1317577E-04 0.0000000E+00 2 H2O 0.4987751E+02 0.4988065E+02 -.3143907E-02 0.0000000E+00 3 Cl- 0.3620252E-03 0.3620252E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.1664172E-03 0.1664172E-03 0.0000000E+00 0.0000000E+00 5 HCO3- 0.2759747E-02 0.2759747E-02 0.0000000E+00 0.0000000E+00 6 HS- 0.7822443E-03 0.7822443E-03 0.0000000E+00 0.0000000E+00 7 Al+++ 0.4775352E-05 0.1489070E-05 0.3286282E-05 0.0000000E+00 8 H4SiO4 0.1215302E-01 0.1057776E-01 0.1575259E-02 0.0000000E+00 9 Ca++ 0.2080835E-06 0.2080835E-06 0.0000000E+00 0.0000000E+00 10 Mg++ 0.8368328E-10 0.8368328E-10 0.0000000E+00 0.0000000E+00 11 Fe++ 0.3259227E-07 0.1456749E-07 0.1802478E-07 0.0000000E+00 12 K+ 0.1412294E-03 0.1412276E-03 0.1802478E-08 0.0000000E+00 13 Na+ 0.2003215E-01 0.2002887E-01 0.3279073E-05 0.0000000E+00 14 Mn++ 0.2251939E-08 0.2251939E-08 0.0000000E+00 0.0000000E+00 15 F- 0.1529600E-04 0.1529600E-04 0.0000000E+00 0.0000000E+00 16 HPO4-- 0.4168819E-07 0.4168819E-07 0.0000000E+00 0.0000000E+00 Chg. balance for solid moles: 0.0000E+00 Mass of aqueous solution: 0.900305E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 0.0379900 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 0.3279E-05 -5.484 0.8598E-03 -3.066 0.9059 0.3301E-03 quartz 0.1565E-02 -2.805 0.9405E-01 -1.027 99.09 0.3552E-01 stilpnomelane-Fe 0.3605E-08 -8.443 0.3886E-05 -5.410 0.4094E-02 0.1342E-05 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 quartz 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 0.094913 g Volume = 0.035848 cm3 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.0379900 moles log = -1.4203 Original solution: 1000.0103000 g Original solution / Rock added: 26322.99 (Water/Rock Ratio), log = 4.4203 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0206 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9997E+00 0.9859 0.1006E+01 0.1020E+01 CO2,gas 0.3563E-04 1.0071 0.3662E-04 0.3636E-04 CH4,gas 0.1301E-04 1.0125 0.1344E-04 0.1328E-04 H2,gas 0.2411E-03 1.0005 0.2462E-03 0.2461E-03 H2S,gas 0.7934E-05 0.9960 0.8066E-05 0.8098E-05 S2,gas 0.3946E-22 1.0000 0.4027E-22 0.4027E-22 CO,gas 0.2355E-11 1.0000 0.2403E-11 0.2403E-11 SO3,gas 0.5992E-39 1.0000 0.6115E-39 0.6115E-39 SO2,gas 0.5740E-20 1.0000 0.5859E-20 0.5859E-20 HF,gas 0.3041E-13 1.0000 0.3104E-13 0.3104E-13 HCl,gas 0.1386E-16 1.0000 0.1414E-16 0.1414E-16 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 17 albite -0.38 -0.38 0.00 0.000 -0.13080E-10 150 quartz -2.99 -2.99 0.00 0.000 0.00000E+00 167 stilpnomelane-Fe 13.02 13.02 0.00 0.000 0.69761E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -12.80 -6.14 -2.045 0.10476E+05 -4.436 3 CH4,gas 4.54 -2.03 -6.57 -1.643 0.11219E+05 -4.871 4 H2,gas 8.00 2.69 -5.31 -3.033 0.90626E+04 -3.609 5 H2S,gas -6.23 -13.02 -6.79 -3.396 0.11598E+05 -5.093 6 S2,gas -7.34 -31.43 -24.09 -3.707 0.41140E+05 -22.395 7 CO,gas 3.21 -10.10 -13.32 -4.098 0.22740E+05 -11.619 8 SO3,gas 17.12 -23.79 -40.91 -10.228 0.69857E+05 -39.214 9 SO2,gas 0.83 -21.10 -21.93 -5.848 0.37447E+05 -20.232 10 HF,gas 0.47 -14.73 -15.21 -7.604 0.25966E+05 -13.508 11 HCl,gas 5.19 -13.36 -18.55 -9.274 0.31671E+05 -16.849 12 acmite 7.71 7.38 -0.33 -0.035 0.56832E+03 16 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 20 spessartine 24.46 19.55 -4.90 -0.245 0.83710E+04 21 analcite 3.32 2.61 -0.72 -0.080 0.12231E+04 23 andradite 39.01 37.56 -1.45 -0.075 0.24683E+04 24 grossular 32.73 28.02 -4.71 -0.236 0.80437E+04 26 ankerite -2.14 -6.98 -4.85 -0.808 0.82798E+04 27 annite 20.12 17.29 -2.83 -0.157 0.48345E+04 28 phlogopite 27.06 23.92 -3.15 -0.175 0.53718E+04 33 apatite-OH -18.15 -22.14 -3.99 -0.307 0.68095E+04 34 apatite-F -34.30 -36.88 -2.57 -0.215 0.43953E+04 38 aragonite 0.97 -0.78 -1.75 -0.584 0.29900E+04 39 brucite 12.57 8.80 -3.76 -0.753 0.64270E+04 40 calcite 0.81 -0.78 -1.60 -0.532 0.27257E+04 41 carnegieite-low 9.02 5.60 -3.43 -0.490 0.58537E+04 42 carnegieite-high 10.09 5.60 -4.50 -0.643 0.76807E+04 43 carpholite-Mg 8.58 3.78 -4.80 -0.320 0.81957E+04 45 celadonite 5.34 3.32 -2.02 -0.119 0.34517E+04 46 celadonite-Fe 3.88 1.11 -2.77 -0.163 0.47216E+04 47 chrysotile 23.89 20.43 -3.46 -0.288 0.59040E+04 49 clinochlore 39.07 36.01 -3.06 -0.096 0.52227E+04 50 daphnite 28.97 24.97 -4.00 -0.125 0.68275E+04 54 chloritoid-Fe 9.17 4.56 -4.61 -0.307 0.78728E+04 55 chloritoid-Mn 11.40 7.16 -4.25 -0.283 0.72484E+04 57 coesite -2.38 -2.99 -0.61 -0.204 0.10473E+04 64 cristobalite -2.56 -2.99 -0.43 -0.143 0.73267E+03 66 cymrite-K 1.69 -2.49 -4.18 -0.348 0.71379E+04 68 diaspore 2.87 0.48 -2.40 -0.399 0.40901E+04 69 diamond -3.10 -7.41 -4.31 -1.231 0.73569E+04 70 diopside 16.18 14.84 -1.34 -0.134 0.22965E+04 71 hedenbergite 14.21 12.63 -1.58 -0.158 0.26990E+04 78 epidote 24.67 21.26 -3.41 -0.165 0.58234E+04 80 epidote-Fe 29.84 26.03 -3.81 -0.198 0.65056E+04 81 fayalite 14.05 10.20 -3.84 -0.549 0.65632E+04 82 ferrosilite 11.15 7.21 -3.94 -0.394 0.67223E+04 86 gibbsite 4.08 0.48 -3.60 -0.514 0.61486E+04 87 glaucophane 22.97 19.67 -3.31 -0.089 0.56482E+04 88 glaucophane-Fe 17.28 13.04 -4.24 -0.114 0.72319E+04 89 graphite -3.55 -7.41 -3.86 -1.104 0.65991E+04 90 greenalite 16.14 13.81 -2.33 -0.194 0.39807E+04 93 hematite 12.57 10.50 -2.07 -0.251 0.35293E+04 94 heulandite -5.83 -7.96 -2.13 -0.097 0.36394E+04 98 jadeite 4.22 2.61 -1.61 -0.161 0.27485E+04 100 kalsilite 7.58 3.48 -4.10 -0.586 0.70007E+04 101 kaolinite -1.33 -5.02 -3.69 -0.335 0.62997E+04 104 laumontite 2.88 1.01 -1.87 -0.125 0.31995E+04 105 lawsonite 9.62 6.99 -2.63 -0.175 0.44865E+04 106 leucite 4.12 0.49 -3.62 -0.362 0.61886E+04 108 lizardite 23.24 20.43 -2.81 -0.234 0.47967E+04 109 magnesite 0.69 -3.99 -4.68 -1.560 0.79934E+04 110 magnetite 20.09 17.09 -2.99 -0.244 0.51097E+04 111 minnesotaite 10.39 7.83 -2.56 -0.151 0.43691E+04 115 manganosite 14.06 9.19 -4.87 -1.217 0.83142E+04 119 microcline -2.49 -2.49 -0.01 -0.001 0.14499E+02 123 muscovite 2.58 -1.54 -4.12 -0.242 0.70362E+04 124 paragonite 4.24 0.57 -3.67 -0.216 0.62608E+04 125 nepheline 8.34 5.60 -2.74 -0.392 0.46861E+04 137 phlogopite-Na 29.65 26.03 -3.62 -0.201 0.61762E+04 139 prehnite 19.37 16.01 -3.36 -0.198 0.57407E+04 140 prehnite-Fe 22.50 20.78 -1.72 -0.103 0.29313E+04 145 pyrite -21.25 -22.14 -0.89 -0.211 0.15277E+04 146 pyrrhotite -4.26 -6.43 -2.17 -0.722 0.36994E+04 147 pyrrhotiteFe0.875 -6.02 -7.59 -1.57 -0.577 0.26777E+04 148 pyroxmangite 7.40 6.20 -1.20 -0.240 0.20478E+04 149 pyrophyllite -6.18 -11.00 -4.83 -0.302 0.82392E+04 154 rhodochrosite -0.98 -3.61 -2.63 -0.877 0.44910E+04 155 rhodonite 7.45 6.20 -1.25 -0.249 0.21280E+04 156 sanidine -1.28 -2.49 -1.22 -0.094 0.20822E+04 158 siderite -2.61 -6.20 -3.59 -1.197 0.61324E+04 166 stilbite -7.52 -7.96 -0.44 -0.021 0.74556E+03 168 stilpnomelane-Mg 27.44 24.06 -3.38 -0.101 0.57718E+04 174 talc 16.49 14.46 -2.04 -0.120 0.34752E+04 177 tephroite 18.09 15.39 -2.70 -0.385 0.46061E+04 181 tridymite -2.63 -2.99 -0.36 -0.121 0.61998E+03 182 tremolite 47.87 44.13 -3.74 -0.101 0.63872E+04 184 troilite-low -4.41 -6.43 -2.02 -0.672 0.34422E+04 190 wairakite 3.95 1.01 -2.94 -0.173 0.50214E+04 191 walstromite 11.51 9.02 -2.49 -0.498 0.42480E+04 192 wollastonite 10.46 9.02 -1.44 -0.288 0.24585E+04 193 pseudo-wollastonite 11.00 9.02 -1.98 -0.396 0.33783E+04 195 akaganeite 7.75 5.25 -2.50 -0.542 0.42772E+04 202 chalcedony -2.80 -2.99 -0.19 -0.062 0.31930E+03 204 montmorillonite-Ca -2.29 -6.27 -3.98 -0.246 0.67975E+04 205 montmorillonite-K -2.24 -6.28 -4.04 -0.247 0.68955E+04 206 montmorillonite-Mg -2.48 -6.80 -4.32 -0.267 0.73778E+04 207 montmorillonite-Na -2.04 -5.58 -3.54 -0.217 0.60456E+04 208 nontronite-Ca 3.21 1.67 -1.55 -0.100 0.26414E+04 209 nontronite-H 2.53 -0.31 -2.85 -0.191 0.48610E+04 210 nontronite-K 3.34 1.66 -1.68 -0.108 0.28627E+04 211 nontronite-Mg 3.07 1.14 -1.94 -0.126 0.33058E+04 212 nontronite-Na 3.52 2.36 -1.16 -0.074 0.19787E+04 228 tobermorite 9.82 7.02 -2.81 -0.766 0.47938E+04 234 alabandite -0.98 -3.83 -2.86 -0.952 0.48763E+04 237 boehmite 4.41 0.48 -3.93 -0.655 0.67070E+04 239 ferrous-oxide 9.81 6.60 -3.22 -0.804 0.54911E+04 245 silica-amorphous -2.09 -2.99 -0.90 -0.299 0.15335E+04 247 an20ab80 2.02 1.09 -0.93 -0.071 0.15831E+04 248 an25ab75 2.65 1.46 -1.19 -0.091 0.20259E+04 249 an30ab70 3.28 1.83 -1.45 -0.112 0.24782E+04 250 tr.625ac.25prg.125 45.16 42.21 -2.96 -0.080 0.50504E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 0.0010000 MOLES Current total amount of reactant added: 0.0379900 MOLES New total amount of reactant added: 0.0389900 MOLES Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.5508E-08 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 7 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 0.0389900 Water: Moles liquid = 0.4989E+02 kg liquid = 0.8987E+00 Moles total = 0.4988E+02 kg total = 0.8986E+00 Activity = 1.0000 Stoichiometric ionic strength = .1384698E-01 Osmotic coef. = 0.9334 True ionic strength = .2225774E-01 Chg. balance for total moles = -.5508E-08 Max. difference allowed = 0.3679E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.15915E-09 -9.7982 0.13284E-09 -9.8767 0.83471E+00 -0.0785 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.40750E-03 -3.3899 0.33793E-03 -3.4712 0.82926E+00 -0.0813 4 SO4-- 0.19031E-03 -3.7205 0.96094E-04 -4.0173 0.50494E+00 -0.2968 5 HCO3- 0.15118E-02 -2.8205 0.12557E-02 -2.9011 0.83058E+00 -0.0806 6 HS- 0.89176E-03 -3.0498 0.73962E-03 -3.1310 0.82939E+00 -0.0812 7 Al+++ 0.32855E-28 -28.4834 0.71172E-29 -29.1477 0.21663E+00 -0.6643 8 H4SiO4 0.10246E-02 -2.9894 0.10246E-02 -2.9894 0.10000E+01 0.0000 9 Ca++ 0.34854E-07 -7.4577 0.17459E-07 -7.7580 0.50091E+00 -0.3002 10 Mg++ 0.22082E-10 -10.6560 0.11006E-10 -10.9584 0.49842E+00 -0.3024 11 Fe++ 0.13902E-12 -12.8569 0.69374E-13 -13.1588 0.49902E+00 -0.3019 12 K+ 0.15649E-03 -3.8055 0.13001E-03 -3.8860 0.83079E+00 -0.0805 13 Na+ 0.20272E-01 -1.6931 0.16807E-01 -1.7745 0.82909E+00 -0.0814 14 Mn++ 0.54413E-10 -10.2643 0.27177E-10 -10.5658 0.49947E+00 -0.3015 15 F- 0.17408E-04 -4.7592 0.14404E-04 -4.8415 0.82741E+00 -0.0823 16 HPO4-- 0.45698E-07 -7.3401 0.23078E-07 -7.6368 0.50502E+00 -0.2967 18 HSiO3- 0.86847E-02 -2.0612 0.72019E-02 -2.1426 0.82926E+00 -0.0813 19 Ca(HSiO3)+ 0.34459E-08 -8.4627 0.28635E-08 -8.5431 0.83099E+00 -0.0804 20 Mg(HSiO3)+ 0.27035E-11 -11.5681 0.22465E-11 -11.6485 0.83099E+00 -0.0804 21 NaHSiO3,aq 0.19577E-02 -2.7082 0.19577E-02 -2.7082 0.10000E+01 0.0000 22 AlO+ 0.66025E-16 -16.1803 0.54866E-16 -16.2607 0.83099E+00 -0.0804 24 HAlO2,aq 0.82250E-10 -10.0849 0.82250E-10 -10.0849 0.10000E+01 0.0000 25 AlO2- 0.16559E-05 -5.7810 0.13705E-05 -5.8631 0.82764E+00 -0.0822 26 CH4,aq 0.94278E-08 -8.0256 0.93882E-08 -8.0274 0.99579E+00 -0.0018 27 C2H6,aq 0.80937E-19 -19.0919 0.80597E-19 -19.0937 0.99579E+00 -0.0018 31 CO,aq 0.16739E-14 -14.7763 0.16739E-14 -14.7763 0.10000E+01 0.0000 32 CO2,aq 0.35794E-06 -6.4462 0.35643E-06 -6.4480 0.99579E+00 -0.0018 33 CO3-2 0.16388E-02 -2.7855 0.82562E-03 -3.0832 0.50378E+00 -0.2978 34 CaCO3,aq 0.18074E-06 -6.7429 0.18074E-06 -6.7429 0.10000E+01 0.0000 35 Ca(HCO3)+ 0.67342E-09 -9.1717 0.55960E-09 -9.2521 0.83099E+00 -0.0804 36 CaCl+ 0.11490E-10 -10.9397 0.95478E-11 -11.0201 0.83099E+00 -0.0804 37 CaCl2,aq 0.76654E-15 -15.1155 0.76654E-15 -15.1155 0.10000E+01 0.0000 38 CaF+ 0.44182E-11 -11.3548 0.36715E-11 -11.4352 0.83099E+00 -0.0804 39 CaOH+ 0.11272E-07 -7.9480 0.93665E-08 -8.0284 0.83099E+00 -0.0804 40 CaSO4,aq 0.53274E-09 -9.2735 0.53274E-09 -9.2735 0.10000E+01 0.0000 41 HCl,aq 0.82262E-14 -14.0848 0.82262E-14 -14.0848 0.10000E+01 0.0000 45 HF,aq 0.13099E-10 -10.8828 0.13099E-10 -10.8828 0.10000E+01 0.0000 46 HF2- 0.76816E-16 -16.1146 0.63700E-16 -16.1959 0.82926E+00 -0.0813 48 FeCl+ 0.44654E-16 -16.3501 0.37107E-16 -16.4305 0.83099E+00 -0.0804 51 FeF+ 0.61449E-16 -16.2115 0.51063E-16 -16.2919 0.83099E+00 -0.0804 53 FeO,aq 0.15278E-09 -9.8159 0.15278E-09 -9.8159 0.10000E+01 0.0000 54 FeOH+ 0.20456E-10 -10.6892 0.16999E-10 -10.7696 0.83099E+00 -0.0804 55 HFeO2- 0.14511E-07 -7.8383 0.12034E-07 -7.9196 0.82926E+00 -0.0813 56 FeO+ 0.11285E-15 -15.9475 0.93774E-16 -16.0279 0.83099E+00 -0.0804 58 FeO2- 0.13112E-08 -8.8823 0.10873E-08 -8.9637 0.82926E+00 -0.0813 59 HFeO2,aq 0.18371E-10 -10.7359 0.18371E-10 -10.7359 0.10000E+01 0.0000 60 H2,aq 0.18774E-06 -6.7264 0.18695E-06 -6.7283 0.99579E+00 -0.0018 61 KCl,aq 0.79627E-09 -9.0989 0.79627E-09 -9.0989 0.10000E+01 0.0000 62 KHSO4,aq 0.46925E-17 -17.3286 0.46925E-17 -17.3286 0.10000E+01 0.0000 63 KOH,aq 0.41795E-06 -6.3789 0.41795E-06 -6.3789 0.10000E+01 0.0000 64 KSO4- 0.23378E-06 -6.6312 0.19387E-06 -6.7125 0.82926E+00 -0.0813 65 MgCO3,aq 0.28559E-10 -10.5443 0.28559E-10 -10.5443 0.10000E+01 0.0000 66 Mg(HCO3)+ 0.43378E-12 -12.3627 0.36047E-12 -12.4431 0.83099E+00 -0.0804 67 MgCl+ 0.65647E-14 -14.1828 0.54552E-14 -14.2632 0.83099E+00 -0.0804 68 MgF+ 0.10317E-13 -13.9864 0.85737E-14 -14.0668 0.83099E+00 -0.0804 69 MgOH+ 0.39319E-10 -10.4054 0.32673E-10 -10.4858 0.83099E+00 -0.0804 71 MnF+ 0.79345E-14 -14.1005 0.65934E-14 -14.1809 0.83099E+00 -0.0804 72 MnO,aq 0.15948E-08 -8.7973 0.15948E-08 -8.7973 0.10000E+01 0.0000 73 MnOH+ 0.74444E-09 -9.1282 0.61862E-09 -9.2086 0.83099E+00 -0.0804 74 MnO2-2 0.59532E-11 -11.2252 0.29991E-11 -11.5230 0.50378E+00 -0.2978 75 HMnO2- 0.10526E-09 -9.9777 0.87287E-10 -10.0591 0.82926E+00 -0.0813 78 MnCl+ 0.68057E-13 -13.1671 0.56554E-13 -13.2475 0.83099E+00 -0.0804 79 MnSO4,aq 0.75394E-12 -12.1227 0.75394E-12 -12.1227 0.10000E+01 0.0000 80 NaCl,aq 0.18823E-05 -5.7253 0.18823E-05 -5.7253 0.10000E+01 0.0000 81 NaF,aq 0.56677E-07 -7.2466 0.56677E-07 -7.2466 0.10000E+01 0.0000 82 NaOH,aq 0.54359E-04 -4.2647 0.54359E-04 -4.2647 0.10000E+01 0.0000 84 OH- 0.52550E-02 -2.2794 0.43492E-02 -2.3616 0.82764E+00 -0.0822 89 HPO3-2 0.26689E-16 -16.5737 0.13445E-16 -16.8714 0.50378E+00 -0.2978 92 H3PO4,aq 0.28485E-17 -17.5454 0.28485E-17 -17.5454 0.10000E+01 0.0000 93 H2PO4- 0.68131E-10 -10.1667 0.56556E-10 -10.2475 0.83012E+00 -0.0809 94 PO4-3 0.62034E-09 -9.2074 0.14174E-09 -9.8485 0.22849E+00 -0.6411 98 HP2O7-3 0.17383E-17 -17.7599 0.37698E-18 -18.4237 0.21687E+00 -0.6638 99 P2O7-4 0.98336E-17 -17.0073 0.67793E-18 -18.1688 0.68939E-01 -1.1615 100 H2S,aq 0.30495E-06 -6.5158 0.30367E-06 -6.5176 0.99579E+00 -0.0018 101 S2-2 0.12870E-09 -9.8904 0.64837E-10 -10.1882 0.50378E+00 -0.2978 102 S3-2 0.28165E-15 -15.5503 0.14189E-15 -15.8481 0.50378E+00 -0.2978 103 S3- 0.35239E-19 -19.4530 0.29222E-19 -19.5343 0.82926E+00 -0.0813 107 SO3-2 0.45623E-11 -11.3408 0.23345E-11 -11.6318 0.51170E+00 -0.2910 108 HSO3- 0.23416E-13 -13.6305 0.19418E-13 -13.7118 0.82926E+00 -0.0813 109 HSO4- 0.14789E-10 -10.8301 0.12302E-10 -10.9100 0.83187E+00 -0.0799 111 S2O3-2 0.68041E-12 -12.1672 0.34278E-12 -12.4650 0.50378E+00 -0.2978 Charge balance for all species = -.6128E-08 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.1591501E-09 -.1759735E-01 -.1770558E+02 0.0000 2 H2O 0.1000000E+01 0.5550292E+02 0.9981262E+06 0.0000 3 Cl- 0.4075044E-03 0.4093874E-03 0.1448824E+02 6.4055 4 SO4-- 0.1903060E-03 0.1904842E-03 0.1826572E+02 15.7360 5 HCO3- 0.1511808E-02 0.3151196E-02 0.1919357E+03 6.9755 6 HS- 0.8917609E-03 0.8921222E-03 0.2945187E+02 6.7457 7 Al+++ 0.3285507E-28 0.1656027E-05 0.4460274E-01 0.4823 8 H4SiO4 0.1024625E-02 0.1166709E-01 0.1119396E+04 -2.9894 9 Ca++ 0.3485412E-07 0.2315328E-06 0.9262895E-02 11.9953 10 Mg++ 0.2208174E-10 0.9311371E-10 0.2259761E-05 8.7949 11 Fe++ 0.1390226E-12 0.1601412E-07 0.8927524E-03 6.5945 12 K+ 0.1564903E-03 0.1571428E-03 0.6133686E+01 5.9906 13 Na+ 0.2027193E-01 0.2228596E-01 0.5114400E+03 8.1022 14 Mn++ 0.5441260E-10 0.2505714E-08 0.1374145E-03 9.1875 15 F- 0.1740812E-04 0.1746481E-04 0.3312073E+00 5.0351 16 HPO4-- 0.4569764E-07 0.4638611E-07 0.4444187E-02 12.1165 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.1582829E-01 -.1581511E-01 -.1317912E-04 0.0000000E+00 2 H2O 0.4987833E+02 0.4988166E+02 -.3328497E-02 0.0000000E+00 3 Cl- 0.3679252E-03 0.3679252E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.1711922E-03 0.1711922E-03 0.0000000E+00 0.0000000E+00 5 HCO3- 0.2832047E-02 0.2832047E-02 0.0000000E+00 0.0000000E+00 6 HS- 0.8017693E-03 0.8017693E-03 0.0000000E+00 0.0000000E+00 7 Al+++ 0.4775352E-05 0.1488306E-05 0.3287046E-05 0.0000000E+00 8 H4SiO4 0.1215302E-01 0.1048547E-01 0.1667555E-02 0.0000000E+00 9 Ca++ 0.2080835E-06 0.2080835E-06 0.0000000E+00 0.0000000E+00 10 Mg++ 0.8368328E-10 0.8368328E-10 0.0000000E+00 0.0000000E+00 11 Fe++ 0.3259227E-07 0.1439223E-07 0.1820004E-07 0.0000000E+00 12 K+ 0.1412294E-03 0.1412276E-03 0.1820004E-08 0.0000000E+00 13 Na+ 0.2003215E-01 0.2002887E-01 0.3279766E-05 0.0000000E+00 14 Mn++ 0.2251939E-08 0.2251939E-08 0.0000000E+00 0.0000000E+00 15 F- 0.1569600E-04 0.1569600E-04 0.0000000E+00 0.0000000E+00 16 HPO4-- 0.4168819E-07 0.4168819E-07 0.0000000E+00 0.0000000E+00 Chg. balance for solid moles: -.4235E-21 Mass of aqueous solution: 0.900320E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 0.0389900 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 0.3280E-05 -5.484 0.8600E-03 -3.065 0.8561 0.3301E-03 quartz 0.1658E-02 -2.780 0.9959E-01 -1.002 99.14 0.3761E-01 stilpnomelane-Fe 0.3640E-08 -8.439 0.3924E-05 -5.406 0.3906E-02 0.1355E-05 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 quartz 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 0.100458 g Volume = 0.037942 cm3 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.0389900 moles log = -1.4090 Original solution: 1000.0103000 g Original solution / Rock added: 25647.87 (Water/Rock Ratio), log = 4.4091 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0206 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9997E+00 0.9859 0.1006E+01 0.1020E+01 CO2,gas 0.3710E-04 1.0071 0.3813E-04 0.3787E-04 CH4,gas 0.1337E-04 1.0125 0.1382E-04 0.1365E-04 H2,gas 0.2404E-03 1.0005 0.2454E-03 0.2453E-03 H2S,gas 0.8212E-05 0.9960 0.8348E-05 0.8381E-05 S2,gas 0.4254E-22 1.0000 0.4342E-22 0.4342E-22 CO,gas 0.2444E-11 1.0000 0.2494E-11 0.2494E-11 SO3,gas 0.6283E-39 1.0000 0.6412E-39 0.6412E-39 SO2,gas 0.5999E-20 1.0000 0.6123E-20 0.6123E-20 HF,gas 0.3151E-13 1.0000 0.3216E-13 0.3216E-13 HCl,gas 0.1422E-16 1.0000 0.1452E-16 0.1452E-16 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 17 albite -0.38 -0.38 0.00 0.000 -0.13080E-10 150 quartz -2.99 -2.99 0.00 0.000 0.00000E+00 167 stilpnomelane-Fe 13.02 13.02 0.00 0.000 0.21232E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -12.78 -6.12 -2.039 0.10446E+05 -4.419 3 CH4,gas 4.54 -2.01 -6.56 -1.640 0.11198E+05 -4.860 4 H2,gas 8.00 2.69 -5.31 -3.034 0.90650E+04 -3.610 5 H2S,gas -6.23 -13.01 -6.78 -3.389 0.11572E+05 -5.078 6 S2,gas -7.34 -31.40 -24.06 -3.702 0.41084E+05 -22.362 7 CO,gas 3.21 -10.09 -13.30 -4.093 0.22713E+05 -11.603 8 SO3,gas 17.12 -23.77 -40.89 -10.223 0.69822E+05 -39.193 9 SO2,gas 0.83 -21.08 -21.91 -5.843 0.37414E+05 -20.213 10 HF,gas 0.47 -14.72 -15.19 -7.596 0.25939E+05 -13.493 11 HCl,gas 5.19 -13.35 -18.54 -9.269 0.31652E+05 -16.838 12 acmite 7.71 7.37 -0.34 -0.035 0.57590E+03 16 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 20 spessartine 24.46 19.56 -4.90 -0.245 0.83641E+04 21 analcite 3.32 2.61 -0.72 -0.080 0.12231E+04 23 andradite 39.01 37.52 -1.49 -0.078 0.25489E+04 24 grossular 32.73 27.98 -4.75 -0.237 0.81091E+04 26 ankerite -2.14 -6.97 -4.83 -0.805 0.82482E+04 27 annite 20.12 17.29 -2.84 -0.158 0.48411E+04 28 phlogopite 27.06 23.89 -3.18 -0.176 0.54215E+04 33 apatite-OH -18.15 -22.19 -4.04 -0.311 0.68985E+04 34 apatite-F -34.30 -36.91 -2.61 -0.218 0.44580E+04 38 aragonite 0.97 -0.78 -1.75 -0.583 0.29863E+04 39 brucite 12.57 8.79 -3.77 -0.755 0.64434E+04 40 calcite 0.81 -0.78 -1.59 -0.531 0.27221E+04 41 carnegieite-low 9.02 5.60 -3.43 -0.490 0.58537E+04 42 carnegieite-high 10.09 5.60 -4.50 -0.643 0.76807E+04 43 carpholite-Mg 8.58 3.78 -4.80 -0.320 0.81983E+04 45 celadonite 5.34 3.31 -2.03 -0.119 0.34687E+04 46 celadonite-Fe 3.88 1.11 -2.77 -0.163 0.47243E+04 47 chrysotile 23.89 20.41 -3.49 -0.291 0.59530E+04 49 clinochlore 39.07 35.97 -3.10 -0.097 0.52907E+04 50 daphnite 28.97 24.97 -4.00 -0.125 0.68238E+04 54 chloritoid-Fe 9.17 4.57 -4.60 -0.307 0.78612E+04 55 chloritoid-Mn 11.40 7.16 -4.24 -0.283 0.72370E+04 57 coesite -2.38 -2.99 -0.61 -0.204 0.10473E+04 64 cristobalite -2.56 -2.99 -0.43 -0.143 0.73267E+03 66 cymrite-K 1.69 -2.50 -4.18 -0.348 0.71386E+04 68 diaspore 2.87 0.48 -2.39 -0.399 0.40833E+04 69 diamond -3.10 -7.40 -4.29 -1.227 0.73317E+04 70 diopside 16.18 14.81 -1.37 -0.137 0.23392E+04 71 hedenbergite 14.21 12.61 -1.60 -0.160 0.27274E+04 78 epidote 24.67 21.24 -3.43 -0.166 0.58632E+04 80 epidote-Fe 29.84 26.00 -3.84 -0.199 0.65531E+04 81 fayalite 14.05 10.20 -3.85 -0.549 0.65672E+04 82 ferrosilite 11.15 7.21 -3.94 -0.394 0.67262E+04 86 gibbsite 4.08 0.48 -3.60 -0.514 0.61418E+04 87 glaucophane 22.97 19.64 -3.34 -0.090 0.56971E+04 88 glaucophane-Fe 17.28 13.04 -4.24 -0.115 0.72378E+04 89 graphite -3.55 -7.40 -3.85 -1.100 0.65740E+04 90 greenalite 16.14 13.80 -2.33 -0.195 0.39867E+04 93 hematite 12.57 10.50 -2.07 -0.251 0.35309E+04 94 heulandite -5.83 -7.97 -2.14 -0.097 0.36521E+04 98 jadeite 4.22 2.61 -1.61 -0.161 0.27485E+04 100 kalsilite 7.58 3.48 -4.10 -0.586 0.70014E+04 101 kaolinite -1.33 -5.01 -3.68 -0.335 0.62861E+04 104 laumontite 2.88 1.00 -1.88 -0.125 0.32122E+04 105 lawsonite 9.62 6.98 -2.64 -0.176 0.44993E+04 106 leucite 4.12 0.49 -3.62 -0.362 0.61893E+04 108 lizardite 23.24 20.41 -2.84 -0.236 0.48456E+04 109 magnesite 0.69 -3.98 -4.67 -1.558 0.79798E+04 110 magnetite 20.09 17.09 -2.99 -0.244 0.51132E+04 111 minnesotaite 10.39 7.83 -2.56 -0.151 0.43751E+04 115 manganosite 14.06 9.19 -4.87 -1.218 0.83164E+04 119 microcline -2.49 -2.50 -0.01 -0.001 0.15183E+02 123 muscovite 2.58 -1.53 -4.11 -0.242 0.70233E+04 124 paragonite 4.24 0.58 -3.66 -0.215 0.62472E+04 125 nepheline 8.34 5.60 -2.74 -0.392 0.46861E+04 137 phlogopite-Na 29.65 26.00 -3.65 -0.203 0.62251E+04 139 prehnite 19.37 15.99 -3.38 -0.199 0.57797E+04 140 prehnite-Fe 22.50 20.75 -1.74 -0.105 0.29780E+04 145 pyrite -21.25 -22.11 -0.86 -0.203 0.14763E+04 146 pyrrhotite -4.26 -6.41 -2.15 -0.718 0.36759E+04 147 pyrrhotiteFe0.875 -6.02 -7.57 -1.55 -0.572 0.26537E+04 148 pyroxmangite 7.40 6.20 -1.20 -0.240 0.20500E+04 149 pyrophyllite -6.18 -10.99 -4.82 -0.301 0.82255E+04 154 rhodochrosite -0.98 -3.59 -2.61 -0.871 0.44632E+04 155 rhodonite 7.45 6.20 -1.25 -0.250 0.21302E+04 156 sanidine -1.28 -2.50 -1.22 -0.094 0.20829E+04 158 siderite -2.61 -6.18 -3.58 -1.192 0.61044E+04 166 stilbite -7.52 -7.97 -0.44 -0.021 0.75829E+03 168 stilpnomelane-Mg 27.44 24.02 -3.42 -0.102 0.58434E+04 174 talc 16.49 14.43 -2.06 -0.121 0.35242E+04 177 tephroite 18.09 15.39 -2.70 -0.386 0.46105E+04 181 tridymite -2.63 -2.99 -0.36 -0.121 0.61998E+03 182 tremolite 47.87 44.05 -3.82 -0.103 0.65214E+04 184 troilite-low -4.41 -6.41 -2.00 -0.667 0.34187E+04 190 wairakite 3.95 1.00 -2.95 -0.173 0.50342E+04 191 walstromite 11.51 9.01 -2.50 -0.501 0.42744E+04 192 wollastonite 10.46 9.01 -1.46 -0.291 0.24848E+04 193 pseudo-wollastonite 11.00 9.01 -1.99 -0.399 0.34046E+04 195 akaganeite 7.75 5.25 -2.51 -0.542 0.42780E+04 202 chalcedony -2.80 -2.99 -0.19 -0.062 0.31930E+03 204 montmorillonite-Ca -2.29 -6.27 -3.98 -0.246 0.67958E+04 205 montmorillonite-K -2.24 -6.27 -4.04 -0.247 0.68920E+04 206 montmorillonite-Mg -2.48 -6.80 -4.32 -0.267 0.73745E+04 207 montmorillonite-Na -2.04 -5.58 -3.54 -0.217 0.60419E+04 208 nontronite-Ca 3.21 1.67 -1.55 -0.100 0.26450E+04 209 nontronite-H 2.53 -0.31 -2.85 -0.191 0.48603E+04 210 nontronite-K 3.34 1.66 -1.68 -0.108 0.28644E+04 211 nontronite-Mg 3.07 1.14 -1.94 -0.126 0.33078E+04 212 nontronite-Na 3.52 2.36 -1.16 -0.074 0.19803E+04 228 tobermorite 9.82 7.00 -2.82 -0.770 0.48157E+04 234 alabandite -0.98 -3.82 -2.84 -0.947 0.48531E+04 237 boehmite 4.41 0.48 -3.92 -0.654 0.67002E+04 239 ferrous-oxide 9.81 6.59 -3.22 -0.804 0.54931E+04 245 silica-amorphous -2.09 -2.99 -0.90 -0.299 0.15335E+04 247 an20ab80 2.02 1.09 -0.93 -0.071 0.15857E+04 248 an25ab75 2.65 1.46 -1.19 -0.091 0.20291E+04 249 an30ab70 3.28 1.83 -1.45 -0.112 0.24821E+04 250 tr.625ac.25prg.125 45.16 42.14 -3.02 -0.081 0.51630E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 0.0010000 MOLES Current total amount of reactant added: 0.0389900 MOLES New total amount of reactant added: 0.0399900 MOLES Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.5508E-08 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 7 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 0.0399900 Water: Moles liquid = 0.4989E+02 kg liquid = 0.8987E+00 Moles total = 0.4988E+02 kg total = 0.8986E+00 Activity = 1.0000 Stoichiometric ionic strength = .1391192E-01 Osmotic coef. = 0.9331 True ionic strength = .2231529E-01 Chg. balance for total moles = -.5508E-08 Max. difference allowed = 0.3738E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.16077E-09 -9.7938 0.13418E-09 -9.8723 0.83458E+00 -0.0785 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.41403E-03 -3.3830 0.34328E-03 -3.4644 0.82912E+00 -0.0814 4 SO4-- 0.19561E-03 -3.7086 0.98703E-04 -4.0057 0.50459E+00 -0.2971 5 HCO3- 0.15580E-02 -2.8074 0.12938E-02 -2.8881 0.83044E+00 -0.0807 6 HS- 0.91346E-03 -3.0393 0.75748E-03 -3.1206 0.82925E+00 -0.0813 7 Al+++ 0.34221E-28 -28.4657 0.74014E-29 -29.1307 0.21628E+00 -0.6650 8 H4SiO4 0.10246E-02 -2.9894 0.10246E-02 -2.9894 0.10000E+01 0.0000 9 Ca++ 0.34350E-07 -7.4641 0.17194E-07 -7.7646 0.50056E+00 -0.3005 10 Mg++ 0.22051E-10 -10.6566 0.10983E-10 -10.9593 0.49806E+00 -0.3027 11 Fe++ 0.14154E-12 -12.8491 0.70581E-13 -13.1513 0.49866E+00 -0.3022 12 K+ 0.15649E-03 -3.8055 0.12998E-03 -3.8861 0.83065E+00 -0.0806 13 Na+ 0.20290E-01 -1.6927 0.16819E-01 -1.7742 0.82895E+00 -0.0815 14 Mn++ 0.55378E-10 -10.2567 0.27640E-10 -10.5585 0.49911E+00 -0.3018 15 F- 0.17851E-04 -4.7483 0.14768E-04 -4.8307 0.82726E+00 -0.0824 16 HPO4-- 0.45702E-07 -7.3401 0.23064E-07 -7.6371 0.50467E+00 -0.2970 18 HSiO3- 0.86001E-02 -2.0655 0.71305E-02 -2.1469 0.82912E+00 -0.0814 19 Ca(HSiO3)+ 0.33606E-08 -8.4736 0.27921E-08 -8.5541 0.83084E+00 -0.0805 20 Mg(HSiO3)+ 0.26715E-11 -11.5733 0.22196E-11 -11.6537 0.83084E+00 -0.0805 21 NaHSiO3,aq 0.19397E-02 -2.7123 0.19397E-02 -2.7123 0.10000E+01 0.0000 22 AlO+ 0.67318E-16 -16.1719 0.55930E-16 -16.2524 0.83084E+00 -0.0805 24 HAlO2,aq 0.83014E-10 -10.0808 0.83014E-10 -10.0808 0.10000E+01 0.0000 25 AlO2- 0.16551E-05 -5.7812 0.13695E-05 -5.8634 0.82749E+00 -0.0822 26 CH4,aq 0.96859E-08 -8.0139 0.96450E-08 -8.0157 0.99577E+00 -0.0018 27 C2H6,aq 0.85704E-19 -19.0670 0.85341E-19 -19.0688 0.99577E+00 -0.0018 31 CO,aq 0.17364E-14 -14.7603 0.17364E-14 -14.7603 0.10000E+01 0.0000 32 CO2,aq 0.37251E-06 -6.4289 0.37094E-06 -6.4307 0.99577E+00 -0.0018 33 CO3-2 0.16730E-02 -2.7765 0.84225E-03 -3.0746 0.50343E+00 -0.2981 34 CaCO3,aq 0.18159E-06 -6.7409 0.18159E-06 -6.7409 0.10000E+01 0.0000 35 Ca(HCO3)+ 0.68347E-09 -9.1653 0.56785E-09 -9.2458 0.83084E+00 -0.0805 36 CaCl+ 0.11497E-10 -10.9394 0.95520E-11 -11.0199 0.83084E+00 -0.0805 37 CaCl2,aq 0.77902E-15 -15.1085 0.77902E-15 -15.1085 0.10000E+01 0.0000 38 CaF+ 0.44620E-11 -11.3505 0.37073E-11 -11.4309 0.83084E+00 -0.0805 39 CaOH+ 0.10992E-07 -7.9589 0.91330E-08 -8.0394 0.83084E+00 -0.0805 40 CaSO4,aq 0.53892E-09 -9.2685 0.53892E-09 -9.2685 0.10000E+01 0.0000 41 HCl,aq 0.84402E-14 -14.0736 0.84402E-14 -14.0736 0.10000E+01 0.0000 45 HF,aq 0.13564E-10 -10.8676 0.13564E-10 -10.8676 0.10000E+01 0.0000 46 HF2- 0.81571E-16 -16.0885 0.67632E-16 -16.1698 0.82912E+00 -0.0814 48 FeCl+ 0.46159E-16 -16.3357 0.38351E-16 -16.4162 0.83084E+00 -0.0805 51 FeF+ 0.64109E-16 -16.1931 0.53265E-16 -16.2736 0.83084E+00 -0.0805 53 FeO,aq 0.15237E-09 -9.8171 0.15237E-09 -9.8171 0.10000E+01 0.0000 54 FeOH+ 0.20609E-10 -10.6859 0.17123E-10 -10.7664 0.83084E+00 -0.0805 55 HFeO2- 0.14331E-07 -7.8437 0.11882E-07 -7.9251 0.82912E+00 -0.0814 56 FeO+ 0.11387E-15 -15.9436 0.94612E-16 -16.0241 0.83084E+00 -0.0805 58 FeO2- 0.12970E-08 -8.8871 0.10754E-08 -8.9684 0.82912E+00 -0.0814 59 HFeO2,aq 0.18351E-10 -10.7363 0.18351E-10 -10.7363 0.10000E+01 0.0000 60 H2,aq 0.18714E-06 -6.7278 0.18635E-06 -6.7297 0.99577E+00 -0.0018 61 KCl,aq 0.80872E-09 -9.0922 0.80872E-09 -9.0922 0.10000E+01 0.0000 62 KHSO4,aq 0.48672E-17 -17.3127 0.48672E-17 -17.3127 0.10000E+01 0.0000 63 KOH,aq 0.41372E-06 -6.3833 0.41372E-06 -6.3833 0.10000E+01 0.0000 64 KSO4- 0.24012E-06 -6.6196 0.19909E-06 -6.7010 0.82912E+00 -0.0814 65 MgCO3,aq 0.29073E-10 -10.5365 0.29073E-10 -10.5365 0.10000E+01 0.0000 66 Mg(HCO3)+ 0.44609E-12 -12.3506 0.37063E-12 -12.4311 0.83084E+00 -0.0805 67 MgCl+ 0.66557E-14 -14.1768 0.55299E-14 -14.2573 0.83084E+00 -0.0805 68 MgF+ 0.10558E-13 -13.9764 0.87718E-14 -14.0569 0.83084E+00 -0.0805 69 MgOH+ 0.38853E-10 -10.4106 0.32281E-10 -10.4911 0.83084E+00 -0.0805 71 MnF+ 0.82749E-14 -14.0822 0.68752E-14 -14.1627 0.83084E+00 -0.0805 72 MnO,aq 0.15899E-08 -8.7986 0.15899E-08 -8.7986 0.10000E+01 0.0000 73 MnOH+ 0.74974E-09 -9.1251 0.62291E-09 -9.2056 0.83084E+00 -0.0805 74 MnO2-2 0.58220E-11 -11.2349 0.29310E-11 -11.5330 0.50343E+00 -0.2981 75 HMnO2- 0.10391E-09 -9.9833 0.86158E-10 -10.0647 0.82912E+00 -0.0814 78 MnCl+ 0.70323E-13 -13.1529 0.58427E-13 -13.2334 0.83084E+00 -0.0805 79 MnSO4,aq 0.78759E-12 -12.1037 0.78759E-12 -12.1037 0.10000E+01 0.0000 80 NaCl,aq 0.19134E-05 -5.7182 0.19134E-05 -5.7182 0.10000E+01 0.0000 81 NaF,aq 0.58151E-07 -7.2354 0.58151E-07 -7.2354 0.10000E+01 0.0000 82 NaOH,aq 0.53858E-04 -4.2687 0.53858E-04 -4.2687 0.10000E+01 0.0000 84 OH- 0.52038E-02 -2.2837 0.43061E-02 -2.3659 0.82749E+00 -0.0822 89 HPO3-2 0.26606E-16 -16.5750 0.13394E-16 -16.8731 0.50343E+00 -0.2981 92 H3PO4,aq 0.29041E-17 -17.5370 0.29041E-17 -17.5370 0.10000E+01 0.0000 93 H2PO4- 0.68783E-10 -10.1625 0.57088E-10 -10.2435 0.82997E+00 -0.0809 94 PO4-3 0.61473E-09 -9.2113 0.14025E-09 -9.8531 0.22815E+00 -0.6418 98 HP2O7-3 0.17563E-17 -17.7554 0.38029E-18 -18.4199 0.21652E+00 -0.6645 99 P2O7-4 0.98490E-17 -17.0066 0.67711E-18 -18.1693 0.68749E-01 -1.1627 100 H2S,aq 0.31545E-06 -6.5011 0.31412E-06 -6.5029 0.99577E+00 -0.0018 101 S2-2 0.13552E-09 -9.8680 0.68226E-10 -10.1660 0.50343E+00 -0.2981 102 S3-2 0.30777E-15 -15.5118 0.15494E-15 -15.8098 0.50343E+00 -0.2981 103 S3- 0.38935E-19 -19.4097 0.32282E-19 -19.4910 0.82912E+00 -0.0814 107 SO3-2 0.46742E-11 -11.3303 0.23902E-11 -11.6216 0.51135E+00 -0.2913 108 HSO3- 0.24219E-13 -13.6159 0.20080E-13 -13.6972 0.82912E+00 -0.0814 109 HSO4- 0.15345E-10 -10.8140 0.12763E-10 -10.8940 0.83173E+00 -0.0800 111 S2O3-2 0.72344E-12 -12.1406 0.36420E-12 -12.4387 0.50343E+00 -0.2981 112 HS2O3- 0.10538E-19 -19.9772 0.87375E-20 -20.0586 0.82912E+00 -0.0814 Charge balance for all species = -.6128E-08 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.1607704E-09 -.1747720E-01 -.1758473E+02 0.0000 2 H2O 0.1000000E+01 0.5550297E+02 0.9981296E+06 0.0000 3 Cl- 0.4140301E-03 0.4159443E-03 0.1472032E+02 6.4080 4 SO4-- 0.1956091E-03 0.1957935E-03 0.1877489E+02 15.7390 5 HCO3- 0.1557987E-02 0.3231582E-02 0.1968324E+03 6.9842 6 HS- 0.9134580E-03 0.9138300E-03 0.3016859E+02 6.7517 7 Al+++ 0.3422144E-28 0.1655145E-05 0.4457910E-01 0.4863 8 H4SiO4 0.1024625E-02 0.1156446E-01 0.1109552E+04 -2.9894 9 Ca++ 0.3435032E-07 0.2315284E-06 0.9262740E-02 11.9800 10 Mg++ 0.2205096E-10 0.9311193E-10 0.2259723E-05 8.7854 11 Fe++ 0.1415431E-12 0.1581981E-07 0.8819221E-03 6.5933 12 K+ 0.1564851E-03 0.1571398E-03 0.6133583E+01 5.9862 13 Na+ 0.2029000E-01 0.2228553E-01 0.5114315E+03 8.0981 14 Mn++ 0.5537835E-10 0.2505666E-08 0.1374122E-03 9.1862 15 F- 0.1785138E-04 0.1790955E-04 0.3396422E+00 5.0416 16 HPO4-- 0.4570171E-07 0.4638522E-07 0.4444113E-02 12.1076 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.1572062E-01 -.1570743E-01 -.1318247E-04 0.0000000E+00 2 H2O 0.4987915E+02 0.4988266E+02 -.3512574E-02 0.0000000E+00 3 Cl- 0.3738252E-03 0.3738252E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.1759672E-03 0.1759672E-03 0.0000000E+00 0.0000000E+00 5 HCO3- 0.2904347E-02 0.2904347E-02 0.0000000E+00 0.0000000E+00 6 HS- 0.8212943E-03 0.8212943E-03 0.0000000E+00 0.0000000E+00 7 Al+++ 0.4775352E-05 0.1487543E-05 0.3287809E-05 0.0000000E+00 8 H4SiO4 0.1215302E-01 0.1039343E-01 0.1759594E-02 0.0000000E+00 9 Ca++ 0.2080835E-06 0.2080835E-06 0.0000000E+00 0.0000000E+00 10 Mg++ 0.8368328E-10 0.8368328E-10 0.0000000E+00 0.0000000E+00 11 Fe++ 0.3259227E-07 0.1421787E-07 0.1837440E-07 0.0000000E+00 12 K+ 0.1412294E-03 0.1412276E-03 0.1837440E-08 0.0000000E+00 13 Na+ 0.2003215E-01 0.2002887E-01 0.3280460E-05 0.0000000E+00 14 Mn++ 0.2251939E-08 0.2251939E-08 0.0000000E+00 0.0000000E+00 15 F- 0.1609600E-04 0.1609600E-04 0.0000000E+00 0.0000000E+00 16 HPO4-- 0.4168819E-07 0.4168819E-07 0.0000000E+00 0.0000000E+00 Chg. balance for solid moles: -.8470E-21 Mass of aqueous solution: 0.900335E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 0.0399900 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 0.3280E-05 -5.484 0.8602E-03 -3.065 0.8116 0.3302E-03 quartz 0.1750E-02 -2.757 0.1051 -0.978 99.18 0.3970E-01 stilpnomelane-Fe 0.3675E-08 -8.435 0.3961E-05 -5.402 0.3738E-02 0.1368E-05 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 quartz 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 0.105988 g Volume = 0.040031 cm3 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.0399900 moles log = -1.3980 Original solution: 1000.0103000 g Original solution / Rock added: 25006.51 (Water/Rock Ratio), log = 4.3981 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0206 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9997E+00 0.9859 0.1006E+01 0.1020E+01 CO2,gas 0.3861E-04 1.0071 0.3969E-04 0.3941E-04 CH4,gas 0.1374E-04 1.0125 0.1420E-04 0.1402E-04 H2,gas 0.2396E-03 1.0005 0.2447E-03 0.2445E-03 H2S,gas 0.8494E-05 0.9960 0.8635E-05 0.8669E-05 S2,gas 0.4581E-22 1.0000 0.4676E-22 0.4676E-22 CO,gas 0.2535E-11 1.0000 0.2588E-11 0.2588E-11 SO3,gas 0.6583E-39 1.0000 0.6719E-39 0.6719E-39 SO2,gas 0.6266E-20 1.0000 0.6395E-20 0.6395E-20 HF,gas 0.3263E-13 1.0000 0.3331E-13 0.3331E-13 HCl,gas 0.1459E-16 1.0000 0.1489E-16 0.1489E-16 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 17 albite -0.38 -0.38 0.00 0.000 -0.94784E-12 150 quartz -2.99 -2.99 0.00 0.000 0.00000E+00 167 stilpnomelane-Fe 13.02 13.02 0.00 0.000 0.21232E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -12.76 -6.10 -2.033 0.10416E+05 -4.401 3 CH4,gas 4.54 -2.00 -6.55 -1.637 0.11178E+05 -4.848 4 H2,gas 8.00 2.69 -5.31 -3.035 0.90674E+04 -3.611 5 H2S,gas -6.23 -12.99 -6.76 -3.381 0.11547E+05 -5.064 6 S2,gas -7.34 -31.36 -24.03 -3.697 0.41029E+05 -22.330 7 CO,gas 3.21 -10.07 -13.29 -4.088 0.22686E+05 -11.587 8 SO3,gas 17.12 -23.75 -40.87 -10.218 0.69787E+05 -39.173 9 SO2,gas 0.83 -21.06 -21.89 -5.838 0.37382E+05 -20.194 10 HF,gas 0.47 -14.70 -15.18 -7.588 0.25913E+05 -13.477 11 HCl,gas 5.19 -13.34 -18.53 -9.263 0.31633E+05 -16.827 12 acmite 7.71 7.37 -0.34 -0.036 0.58356E+03 16 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 20 spessartine 24.46 19.56 -4.89 -0.245 0.83572E+04 21 analcite 3.32 2.61 -0.72 -0.080 0.12231E+04 23 andradite 39.01 37.47 -1.54 -0.080 0.26288E+04 24 grossular 32.73 27.94 -4.79 -0.239 0.81737E+04 26 ankerite -2.14 -6.95 -4.81 -0.802 0.82171E+04 27 annite 20.12 17.28 -2.84 -0.158 0.48478E+04 28 phlogopite 27.06 23.86 -3.20 -0.178 0.54712E+04 33 apatite-OH -18.15 -22.24 -4.09 -0.315 0.69861E+04 34 apatite-F -34.30 -36.95 -2.65 -0.221 0.45196E+04 38 aragonite 0.97 -0.78 -1.75 -0.582 0.29828E+04 39 brucite 12.57 8.79 -3.78 -0.757 0.64597E+04 40 calcite 0.81 -0.78 -1.59 -0.531 0.27186E+04 41 carnegieite-low 9.02 5.60 -3.43 -0.490 0.58537E+04 42 carnegieite-high 10.09 5.60 -4.50 -0.643 0.76807E+04 43 carpholite-Mg 8.58 3.78 -4.80 -0.320 0.82010E+04 45 celadonite 5.34 3.30 -2.04 -0.120 0.34857E+04 46 celadonite-Fe 3.88 1.11 -2.77 -0.163 0.47270E+04 47 chrysotile 23.89 20.38 -3.52 -0.293 0.60020E+04 49 clinochlore 39.07 35.93 -3.14 -0.098 0.53587E+04 50 daphnite 28.97 24.97 -3.99 -0.125 0.68200E+04 54 chloritoid-Fe 9.17 4.58 -4.60 -0.306 0.78494E+04 55 chloritoid-Mn 11.40 7.17 -4.23 -0.282 0.72255E+04 57 coesite -2.38 -2.99 -0.61 -0.204 0.10473E+04 64 cristobalite -2.56 -2.99 -0.43 -0.143 0.73267E+03 66 cymrite-K 1.69 -2.50 -4.18 -0.348 0.71392E+04 68 diaspore 2.87 0.49 -2.39 -0.398 0.40764E+04 69 diamond -3.10 -7.38 -4.28 -1.223 0.73069E+04 70 diopside 16.18 14.79 -1.39 -0.139 0.23816E+04 71 hedenbergite 14.21 12.59 -1.61 -0.161 0.27555E+04 78 epidote 24.67 21.21 -3.46 -0.168 0.59025E+04 80 epidote-Fe 29.84 25.98 -3.87 -0.201 0.66000E+04 81 fayalite 14.05 10.20 -3.85 -0.550 0.65712E+04 82 ferrosilite 11.15 7.21 -3.94 -0.394 0.67302E+04 86 gibbsite 4.08 0.49 -3.59 -0.513 0.61350E+04 87 glaucophane 22.97 19.61 -3.37 -0.091 0.57462E+04 88 glaucophane-Fe 17.28 13.03 -4.24 -0.115 0.72438E+04 89 graphite -3.55 -7.38 -3.84 -1.096 0.65492E+04 90 greenalite 16.14 13.80 -2.34 -0.195 0.39926E+04 93 hematite 12.57 10.50 -2.07 -0.251 0.35325E+04 94 heulandite -5.83 -7.97 -2.15 -0.098 0.36645E+04 98 jadeite 4.22 2.61 -1.61 -0.161 0.27485E+04 100 kalsilite 7.58 3.48 -4.10 -0.586 0.70020E+04 101 kaolinite -1.33 -5.01 -3.67 -0.334 0.62724E+04 104 laumontite 2.88 0.99 -1.89 -0.126 0.32246E+04 105 lawsonite 9.62 6.97 -2.64 -0.176 0.45117E+04 106 leucite 4.12 0.49 -3.63 -0.363 0.61900E+04 108 lizardite 23.24 20.38 -2.87 -0.239 0.48947E+04 109 magnesite 0.69 -3.98 -4.67 -1.555 0.79665E+04 110 magnetite 20.09 17.09 -3.00 -0.245 0.51168E+04 111 minnesotaite 10.39 7.82 -2.57 -0.151 0.43810E+04 115 manganosite 14.06 9.19 -4.87 -1.218 0.83187E+04 119 microcline -2.49 -2.50 -0.01 -0.001 0.15865E+02 123 muscovite 2.58 -1.52 -4.11 -0.242 0.70102E+04 124 paragonite 4.24 0.59 -3.65 -0.215 0.62335E+04 125 nepheline 8.34 5.60 -2.74 -0.392 0.46861E+04 137 phlogopite-Na 29.65 25.97 -3.67 -0.204 0.62742E+04 139 prehnite 19.37 15.96 -3.41 -0.200 0.58182E+04 140 prehnite-Fe 22.50 20.73 -1.77 -0.107 0.30241E+04 145 pyrite -21.25 -22.08 -0.83 -0.196 0.14257E+04 146 pyrrhotite -4.26 -6.40 -2.14 -0.713 0.36528E+04 147 pyrrhotiteFe0.875 -6.02 -7.56 -1.54 -0.566 0.26300E+04 148 pyroxmangite 7.40 6.20 -1.20 -0.240 0.20523E+04 149 pyrophyllite -6.18 -10.99 -4.81 -0.301 0.82118E+04 154 rhodochrosite -0.98 -3.57 -2.60 -0.866 0.44359E+04 155 rhodonite 7.45 6.20 -1.25 -0.250 0.21325E+04 156 sanidine -1.28 -2.50 -1.22 -0.094 0.20836E+04 158 siderite -2.61 -6.17 -3.56 -1.186 0.60768E+04 166 stilbite -7.52 -7.97 -0.45 -0.021 0.77067E+03 168 stilpnomelane-Mg 27.44 23.98 -3.46 -0.103 0.59152E+04 174 talc 16.49 14.40 -2.09 -0.123 0.35732E+04 177 tephroite 18.09 15.38 -2.70 -0.386 0.46150E+04 181 tridymite -2.63 -2.99 -0.36 -0.121 0.61998E+03 182 tremolite 47.87 43.97 -3.90 -0.105 0.66554E+04 184 troilite-low -4.41 -6.40 -1.99 -0.663 0.33956E+04 190 wairakite 3.95 0.99 -2.96 -0.174 0.50465E+04 191 walstromite 11.51 8.99 -2.52 -0.504 0.43005E+04 192 wollastonite 10.46 8.99 -1.47 -0.294 0.25109E+04 193 pseudo-wollastonite 11.00 8.99 -2.01 -0.402 0.34307E+04 195 akaganeite 7.75 5.25 -2.51 -0.542 0.42788E+04 202 chalcedony -2.80 -2.99 -0.19 -0.062 0.31930E+03 204 montmorillonite-Ca -2.29 -6.27 -3.98 -0.246 0.67941E+04 205 montmorillonite-K -2.24 -6.27 -4.03 -0.247 0.68884E+04 206 montmorillonite-Mg -2.48 -6.80 -4.32 -0.267 0.73711E+04 207 montmorillonite-Na -2.04 -5.57 -3.54 -0.217 0.60381E+04 208 nontronite-Ca 3.21 1.66 -1.55 -0.101 0.26487E+04 209 nontronite-H 2.53 -0.31 -2.85 -0.191 0.48596E+04 210 nontronite-K 3.34 1.66 -1.68 -0.108 0.28662E+04 211 nontronite-Mg 3.07 1.14 -1.94 -0.126 0.33098E+04 212 nontronite-Na 3.52 2.36 -1.16 -0.074 0.19819E+04 228 tobermorite 9.82 6.99 -2.83 -0.773 0.48375E+04 234 alabandite -0.98 -3.81 -2.83 -0.943 0.48303E+04 237 boehmite 4.41 0.49 -3.92 -0.653 0.66933E+04 239 ferrous-oxide 9.81 6.59 -3.22 -0.805 0.54950E+04 245 silica-amorphous -2.09 -2.99 -0.90 -0.299 0.15335E+04 247 an20ab80 2.02 1.09 -0.93 -0.072 0.15882E+04 248 an25ab75 2.65 1.46 -1.19 -0.092 0.20322E+04 249 an30ab70 3.28 1.82 -1.46 -0.112 0.24858E+04 250 tr.625ac.25prg.125 45.16 42.08 -3.09 -0.083 0.52752E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 0.0010000 MOLES Current total amount of reactant added: 0.0399900 MOLES New total amount of reactant added: 0.0409900 MOLES Mixing fraction reached given limit of 0.4000E-01 TOTMIX = 0.4099E-01 Execution stopped.