File SKIP_SPECIES.TXT lists species and minerals omitted from the calculations due to given T, P, option switches, or suppression in CHIMRUN, or are suppressed in the SOLTHERM database. It also lists minerals for which density is not specified in SOLTHERM. This is an extended P(to 5 kB), T(to 600 C) run (CON_FLAG = 1). methanol,aq is suppressed in SOLTHERM data file. methanol,aq is suppressed in SOLTHERM data file. CuCl4-3 is suppressed in SOLTHERM data file. H2BO3- is suppressed in SOLTHERM data file. UO2CO3,aq is suppressed in SOLTHERM data file. UO2SO4,aq is suppressed in SOLTHERM data file. UO2Cl2,aq is suppressed in SOLTHERM data file. UO2F2,aq is suppressed in SOLTHERM data file. PO4-3 is suppressed in SOLTHERM data file. H2PO4- is suppressed in SOLTHERM data file. H3PO4 is suppressed in SOLTHERM data file. O2,gas is suppressed in THIS RUN. O2,gas is suppressed in THIS RUN. amesite is suppressed in SOLTHERM data file. antigorite is suppressed in SOLTHERM data file. goethite is suppressed in THIS RUN. goethite is suppressed in THIS RUN. riebeckite is suppressed in THIS RUN. riebeckite is suppressed in THIS RUN. sapphirine-Fe(221) is suppressed in SOLTHERM data file. sapphirine(221) is suppressed in SOLTHERM data file. talc-prl is suppressed in SOLTHERM data file. PrO1.833(s) is suppressed in SOLTHERM data file. niter-NH4 is suppressed in SOLTHERM data file. FMQ_HS-1 is suppressed in THIS RUN. kf-ab-equil is suppressed in THIS RUN. ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Species No. Charge Tot.moles Trial molality Gamma Mixing solution H+ 1 1. -0.15721E-01 0.16077E-09 0.8346 0.00000000E+00 H2O 2 0. 0.49879E+02 0.10000E+01 1.0000 0.00000000E+00 Cl- 3 -1. 0.37383E-03 0.41403E-03 0.8291 0.00000000E+00 SO4-- 4 -2. 0.17597E-03 0.19561E-03 0.5046 0.00000000E+00 HCO3- 5 -1. 0.29043E-02 0.15580E-02 0.8304 0.00000000E+00 HS- 6 -1. 0.82129E-03 0.91346E-03 0.8292 0.00000000E+00 Al+++ 7 3. 0.47754E-05 0.34221E-28 0.2163 0.00000000E+00 H4SiO4 8 0. 0.12153E-01 0.10246E-02 1.0000 0.00000000E+00 Ca++ 9 2. 0.20808E-06 0.34350E-07 0.5006 0.00000000E+00 Mg++ 10 2. 0.83683E-10 0.22051E-10 0.4981 0.00000000E+00 Fe++ 11 2. 0.32592E-07 0.14154E-12 0.4987 0.00000000E+00 K+ 12 1. 0.14123E-03 0.15649E-03 0.8306 0.00000000E+00 Na+ 13 1. 0.20032E-01 0.20290E-01 0.8289 0.00000000E+00 Mn++ 14 2. 0.22519E-08 0.55378E-10 0.4991 0.00000000E+00 F- 15 -1. 0.16096E-04 0.17851E-04 0.8273 0.00000000E+00 HPO4-- 16 -2. 0.41688E-07 0.45702E-07 0.5047 0.00000000E+00 Chg. balance for total moles = -.5508E-08 Max. difference allowed = 0.3738E-07 The following parameters were given: ERPC = 0.1000E-11 pH = 0.0000 PFLUID = 50.0000 SLIM = 0.800000E-01 TEMP = 100.0000 SINC = 0.2000E-02 TEMPC = 0.0000 TOTMIX = 0.399900E-01 ENTH = 0.0000 SENTH = 0.0000 DENTH = 0.0000 TOTWAT = 90.0000 SOLMIN = 0.0000E+00 RM = 0.0000 AQGRM = 1000.0103 SUPRNT = 0.1000E-19 VBOX-1 = 400.9996 RHOFRS = 0.0000 RHOROC = 2.5000 The following options were selected: CONFLG = 1 C = 3 IFRAC = 0 IPUNCH = 2 NLOOP = 400 ISTEP = 2 LIMSOL = 1 LOOC = 0 IENTH = 0 ITREF = 0 IDEAL = 0 IPSAT = 1 INCREM = 0 INCP = 0 MINSOL = 3 NEUT = 0 AWAT = 0 CHGF = 0 Of the derived species, only those with molality > 0.10E-19 will appear in the output Species No. Charge Log K(diss) Species No. Charge Log K(diss) SiF6-2 17 -2. -24.5019 Mn+3 70 3. 19.1453 HSiO3- 18 -1. 9.0298 MnF+ 71 1. -1.2264 Ca(HSiO3)+ 19 1. 7.6723 MnO,aq 72 0. 17.9848 Mg(HSiO3)+ 20 1. 7.5773 MnOH+ 73 1. 8.5194 NaHSiO3,aq 21 0. 7.8210 MnO2-2 74 -2. 40.4638 AlO+ 22 1. 6.8663 HMnO2- 75 -1. 29.1232 AlOH+2 23 2. 3.1691 MnO4- 76 -1. 83.3111 HAlO2,aq 24 0. 10.5671 MnO4-2 77 -2. 81.3005 AlO2- 25 -1. 16.2221 MnCl+ 78 1. -0.7894 CH4,aq 26 0. 6.0126 MnSO4,aq 79 0. -2.4604 C2H6,aq 27 0. 12.3733 NaCl,aq 80 0. 0.4796 C3H8,aq 28 0. 17.3707 NaF,aq 81 0. 0.6306 C4H10,aq 29 0. 22.3757 NaOH,aq 82 0. 12.3669 ethanol,aq 30 0. 15.3258 O2,aq 83 0. 53.5502 CO,aq 31 0. 4.6892 OH- 84 -1. 12.2382 CO2,aq 32 0. -6.3298 HO2- 85 -1. 50.8010 CO3-2 33 -2. 10.0588 H2O2,aq 86 0. 40.0166 CaCO3,aq 34 0. 5.9605 H3PO2,aq 87 0. 24.3066 Ca(HCO3)+ 35 1. -1.4070 H2PO2- 88 -1. 26.5366 CaCl+ 36 1. -0.2091 HPO3-2 89 -2. 11.9254 CaCl2,aq 37 0. 0.4151 H3PO3,aq 90 0. 3.5792 CaF+ 38 1. -1.1644 H2PO3- 91 -1. 5.6232 CaOH+ 39 1. 10.1471 H3PO4,aq 92 0. -9.8447 CaSO4,aq 40 0. -2.5018 H2PO4- 93 -1. -7.2659 HCl,aq 41 0. 0.7370 PO4-3 94 -3. 12.0884 HClO,aq 42 0. 32.4260 H4P2O7,aq 95 0. -17.8095 ClO- 43 -1. 39.6530 H3P2O7- 96 -1. -15.9156 HClO2,aq 44 0. 70.1812 H2P2O7-2 97 -2. -13.4262 HF,aq 45 0. -3.8354 HP2O7-3 98 -3. -6.7266 HF2- 46 -1. -3.3639 P2O7-4 99 -4. 2.8952 Fe+3 47 3. 8.3809 H2S,aq 100 0. -6.4900 FeCl+ 48 1. -0.1994 S2-2 101 -2. 1.2355 FeCl2,aq 49 0. 4.3001 S3-2 102 -2. -8.8031 FeCl+2 50 2. 6.5269 S3- 103 -1. -16.3389 FeF+ 51 1. -1.7084 S4-2 104 -2. -18.6615 FeF+2 52 2. 1.4309 S5-2 105 -2. -28.3439 FeO,aq 53 0. 16.4104 SO2,aq 106 0. -0.2309 FeOH+ 54 1. 7.4874 SO3-2 107 -2. 10.3052 HFeO2- 55 -1. 24.3908 HSO3- 108 -1. 2.5086 FeO+ 56 1. 11.4004 HSO4- 109 -1. -2.9839 FeOH+2 57 2. 9.1194 HSO5- 110 -1. 38.8366 FeO2- 58 -1. 24.0895 S2O3-2 111 -2. -4.5600 HFeO2,aq 59 0. 15.9850 HS2O3- 112 -1. -6.8123 H2,aq 60 0. 9.4190 H2S2O3,aq 113 0. -8.0173 KCl,aq 61 0. 1.7417 S2O4-2 114 -2. 10.5541 KHSO4,aq 62 0. -0.4514 HS2O4- 115 -1. 7.6551 KOH,aq 63 0. 12.3695 H2S2O4,aq 116 0. 6.6259 KSO4- 64 -1. -1.1908 S2O5-2 117 -2. 10.0741 MgCO3,aq 65 0. 6.5614 S2O6-2 118 -2. 11.5521 Mg(HCO3)+ 66 1. -1.4164 S2O8-2 119 -2. 42.0620 MgCl+ 67 1. -0.1664 S3O6-2 120 -2. 3.7866 MgF+ 68 1. -1.7331 S4O6-2 121 -2. -17.8657 MgOH+ 69 1. 9.4041 S5O6-2 122 -2. -14.1333 For mixed gases (JSOLS=6), log K(hydrol) = log (K*P) Log K Trial Log K Trial Mineral No. hydrol Moles Mineral No. hydrol Moles H2O,gas 1 1.696 0.0000E+00 osumilite(1) 126 21.717 0.0000E+00 CO2,gas 2 -6.660 0.0000E+00 osumilite(2) 127 20.667 0.0000E+00 CH4,gas 3 4.544 0.0000E+00 osumilite-Fe 128 14.390 0.0000E+00 H2,gas 4 8.000 0.0000E+00 pargasite 129 65.092 0.0000E+00 H2S,gas 5 -6.230 0.0000E+00 periclase 130 16.138 0.0000E+00 S2,gas 6 -7.335 0.0000E+00 periclase-Fe 131 11.627 0.0000E+00 CO,gas 7 3.215 0.0000E+00 perovskite-Al 132 12.344 0.0000E+00 SO3,gas 8 17.121 0.0000E+00 perovskite-Ca 133 23.807 0.0000E+00 SO2,gas 9 0.832 0.0000E+00 perovskite-Fe 134 21.143 0.0000E+00 HF,gas 10 0.473 0.0000E+00 perovskite-Mg 135 23.119 0.0000E+00 HCl,gas 11 5.189 0.0000E+00 phase_A 136 80.189 0.0000E+00 acmite 12 7.710 0.0000E+00 phlogopite-Na 137 29.647 0.0000E+00 akermanite 13 36.442 0.0000E+00 piemontite(ordered) 138 33.776 0.0000E+00 akimotoite 14 16.591 0.0000E+00 prehnite 139 19.372 0.0000E+00 akimotoite-Fe 15 13.067 0.0000E+00 prehnite-Fe 140 22.498 0.0000E+00 albite-high 16 0.693 0.0000E+00 pumpellyite-Fe 141 46.269 0.0000E+00 albite 17 -0.384 0.3280E-05 pumpellyite-Mg 142 48.995 0.0000E+00 almandine 18 24.442 0.0000E+00 px-Mg-tschermaks 143 19.616 0.0000E+00 pyrope 19 37.248 0.0000E+00 px-Ca-tschermaks 144 18.610 0.0000E+00 spessartine 20 24.457 0.0000E+00 pyrite 145 -21.247 0.0000E+00 analcite 21 3.322 0.0000E+00 pyrrhotite 146 -4.260 0.0000E+00 andalusite 22 5.002 0.0000E+00 pyrrhotiteFe0.875 147 -6.017 0.0000E+00 andradite 23 39.009 0.0000E+00 pyroxmangite 148 7.399 0.0000E+00 grossular 24 32.731 0.0000E+00 pyrophyllite 149 -6.176 0.0000E+00 anhydrite 25 -5.317 0.0000E+00 quartz 150 -2.989 0.1750E-02 ankerite 26 -2.135 0.0000E+00 rankinite 151 40.713 0.0000E+00 annite 27 20.123 0.0000E+00 ringwoodite-Fe 152 15.456 0.0000E+00 phlogopite 28 27.065 0.0000E+00 ringwoodite-Mg 153 27.575 0.0000E+00 biotite-Mn 29 32.960 0.0000E+00 rhodochrosite 154 -0.976 0.0000E+00 anorthite 30 12.710 0.0000E+00 rhodonite 155 7.446 0.0000E+00 anthophyllite 31 51.852 0.0000E+00 sanidine 156 -1.275 0.0000E+00 anthophyllite-Fe 32 29.306 0.0000E+00 sapphirine(351) 157 78.899 0.0000E+00 apatite-OH 33 -18.153 0.0000E+00 siderite 158 -2.608 0.0000E+00 apatite-F 34 -34.301 0.0000E+00 sillimanite 159 5.262 0.0000E+00 apatite-OH-zs 35 -12.736 0.0000E+00 sodalite 160 49.976 0.0000E+00 apatite-F-zs 36 -27.774 0.0000E+00 spinel 161 20.870 0.0000E+00 apatite-Cl-zs 37 -16.674 0.0000E+00 spurrite 162 59.482 0.0000E+00 aragonite 38 0.967 0.0000E+00 staurolite-Fe 163 73.598 0.0000E+00 brucite 39 12.569 0.0000E+00 staurolite-Mg 164 89.802 0.0000E+00 calcite 40 0.812 0.0000E+00 staurolite-Mn 165 83.909 0.0000E+00 carnegieite-low 41 9.023 0.0000E+00 stilbite 166 -7.522 0.0000E+00 carnegieite-high 42 10.093 0.0000E+00 stilpnomelane-Fe 167 13.017 0.3675E-08 carpholite-Mg 43 8.582 0.0000E+00 stilpnomelane-Mg 168 27.441 0.0000E+00 carpholite-Fe 44 6.713 0.0000E+00 stishovite 169 2.720 0.0000E+00 celadonite 45 5.342 0.0000E+00 sudoite-Fe 170 18.296 0.0000E+00 celadonite-Fe 46 3.877 0.0000E+00 sudoite 171 21.077 0.0000E+00 chrysotile 47 23.892 0.0000E+00 sulfur 172 -9.152 0.0000E+00 chondrodite 48 56.475 0.0000E+00 sylvite 173 1.338 0.0000E+00 clinochlore 49 39.070 0.0000E+00 talc 174 16.491 0.0000E+00 daphnite 50 28.965 0.0000E+00 talc-Fe 175 13.448 0.0000E+00 chlorite-Mn 51 46.869 0.0000E+00 talc-tschermaks 176 19.091 0.0000E+00 chlorite-Al-free 52 47.173 0.0000E+00 tephroite 177 18.086 0.0000E+00 chloritoid-Mg 53 13.198 0.0000E+00 tilleyite 178 41.377 0.0000E+00 chloritoid-Fe 54 9.174 0.0000E+00 titanite-CaSi 179 15.479 0.0000E+00 chloritoid-Mn 55 11.401 0.0000E+00 topaz-H 180 4.618 0.0000E+00 clinohumite 56 97.128 0.0000E+00 tridymite 181 -2.626 0.0000E+00 coesite 57 -2.376 0.0000E+00 tremolite 182 47.869 0.0000E+00 cordierite-H 58 23.715 0.0000E+00 ferroactinolite 183 38.452 0.0000E+00 cordierite 59 24.049 0.0000E+00 troilite-low 184 -4.411 0.0000E+00 cordierite-Fe 60 20.450 0.0000E+00 tschermakite 185 48.210 0.0000E+00 cordierite-Mn 61 25.066 0.0000E+00 vesuvianite 186 223.471 0.0000E+00 corundum 62 8.383 0.0000E+00 wadeite-Si 187 20.216 0.0000E+00 corundum-MgSi 63 18.891 0.0000E+00 wadsleyite-Fe 188 15.680 0.0000E+00 cristobalite 64 -2.560 0.0000E+00 wadsleyite-Mg 189 25.850 0.0000E+00 cummingtonite 65 52.099 0.0000E+00 wairakite 190 3.950 0.0000E+00 cymrite-K 66 1.685 0.0000E+00 walstromite 191 11.509 0.0000E+00 deerite 67 95.671 0.0000E+00 wollastonite 192 10.461 0.0000E+00 diaspore 68 2.874 0.0000E+00 pseudo-wollastonite 193 11.000 0.0000E+00 diamond 69 -3.102 0.0000E+00 zoisite 194 22.849 0.0000E+00 diopside 70 16.181 0.0000E+00 akaganeite 195 7.755 0.0000E+00 hedenbergite 71 14.208 0.0000E+00 beidellite-Ca 196 -1.646 0.0000E+00 dolomite,ordered 72 0.546 0.0000E+00 beidellite-H 197 -2.326 0.0000E+00 eastonite 73 28.489 0.0000E+00 beidellite-K 198 -1.520 0.0000E+00 enstatite 74 17.265 0.0000E+00 beidellite-Mg 199 -1.790 0.0000E+00 clinoenstatite-HiP 75 18.354 0.0000E+00 beidellite-Na 200 -1.342 0.0000E+00 clinoenstatite 76 17.166 0.0000E+00 calcium 201 84.026 0.0000E+00 protoenstatite 77 17.824 0.0000E+00 chalcedony 202 -2.802 0.0000E+00 epidote 78 24.670 0.0000E+00 dawsonite 203 1.682 0.0000E+00 clinozoisite 79 22.806 0.0000E+00 montmorillonite-Ca 204 -2.291 0.0000E+00 epidote-Fe 80 29.841 0.0000E+00 montmorillonite-K 205 -2.237 0.0000E+00 fayalite 81 14.046 0.0000E+00 montmorillonite-Mg 206 -2.480 0.0000E+00 ferrosilite 82 11.149 0.0000E+00 montmorillonite-Na 207 -2.038 0.0000E+00 forsterite 83 21.016 0.0000E+00 nontronite-Ca 208 3.215 0.0000E+00 gedrite 84 50.522 0.0000E+00 nontronite-H 209 2.533 0.0000E+00 gehlenite 85 36.628 0.0000E+00 nontronite-K 210 3.341 0.0000E+00 gibbsite 86 4.079 0.0000E+00 nontronite-Mg 211 3.075 0.0000E+00 glaucophane 87 22.975 0.0000E+00 nontronite-Na 212 3.520 0.0000E+00 glaucophane-Fe 88 17.276 0.0000E+00 sepiolite 213 24.118 0.0000E+00 graphite 89 -3.546 0.0000E+00 topaz 214 -16.546 0.0000E+00 greenalite 90 16.140 0.0000E+00 alite 215 57.999 0.0000E+00 grunerite 91 31.215 0.0000E+00 belite 216 30.433 0.0000E+00 halite 92 1.575 0.0000E+00 ettringite 217 43.232 0.0000E+00 hematite 93 12.566 0.0000E+00 gypsum 218 -4.955 0.0000E+00 heulandite 94 -5.827 0.0000E+00 hemicarboaluminate 219 70.954 0.0000E+00 hercynite 95 17.279 0.0000E+00 hydrogarnet 220 60.662 0.0000E+00 hollandite 96 25.673 0.0000E+00 hydrogarnet-Si 221 50.586 0.0000E+00 iron 97 19.086 0.0000E+00 jennite 222 24.367 0.0000E+00 jadeite 98 4.215 0.0000E+00 monosulfoaluminate 223 53.400 0.0000E+00 julgoldite 99 70.427 0.0000E+00 monocarboaluminate 224 61.898 0.0000E+00 kalsilite 100 7.584 0.0000E+00 portlandite 225 18.272 0.0000E+00 kaolinite 101 -1.333 0.0000E+00 stratlingite 226 36.502 0.0000E+00 kyanite 102 4.876 0.0000E+00 tricarboaluminate 227 70.370 0.0000E+00 larnite-bredigite 103 30.686 0.0000E+00 tobermorite 228 9.823 0.0000E+00 laumontite 104 2.883 0.0000E+00 C4AH13 229 81.816 0.0000E+00 lawsonite 105 9.616 0.0000E+00 C2AH8 230 45.203 0.0000E+00 leucite 106 4.119 0.0000E+00 C3A 231 86.953 0.0000E+00 lime 107 25.998 0.0000E+00 C4AF 232 117.416 0.0000E+00 lizardite 108 23.244 0.0000E+00 CAH10 233 28.335 0.0000E+00 magnesite 109 0.691 0.0000E+00 alabandite 234 -0.978 0.0000E+00 magnetite 110 20.087 0.0000E+00 alunite 235 -10.435 0.0000E+00 minnesotaite 111 10.388 0.0000E+00 artinite 236 15.121 0.0000E+00 minnesotaite-Mg 112 20.602 0.0000E+00 boehmite 237 4.406 0.0000E+00 magnesioferrite 113 26.212 0.0000E+00 dolomite,disordered 238 1.247 0.0000E+00 majorite 114 53.251 0.0000E+00 ferrous-oxide 239 9.812 0.0000E+00 manganosite 115 14.058 0.0000E+00 fluorite 240 -9.931 0.0000E+00 margarite 116 17.324 0.0000E+00 huntite 241 3.770 0.0000E+00 meionite 117 44.874 0.0000E+00 hydromagnesite 242 19.995 0.0000E+00 merwinite 118 55.930 0.0000E+00 nesquehonite 243 4.723 0.0000E+00 microcline 119 -2.486 0.0000E+00 potassium-oxide 244 69.038 0.0000E+00 monticellite 120 24.339 0.0000E+00 silica-amorphous 245 -2.091 0.0000E+00 mullite-Al 121 363.148 0.0000E+00 sodium-oxide 246 55.169 0.0000E+00 mullite-Si 122 7.264 0.0000E+00 an20ab80 247 2.018 0.0000E+00 muscovite 123 2.582 0.0000E+00 an25ab75 248 2.646 0.0000E+00 paragonite 124 4.239 0.0000E+00 an30ab70 249 3.279 0.0000E+00 nepheline 125 8.339 0.0000E+00 tr.625ac.25prg.125 250 45.165 0.0000E+00 Initial composition of reactant (mole%): H2O 88.87 HCl 0.5900 CO2 7.070 CO 0.1600 H2 1.540 S2 0.8000E-01 SO2 1.150 HF 0.4000E-01 H2S 1.120 0.000 Sum of wt% of reactants: 100.6200 Reactant consumed: 0.0399900 moles log = -1.3980 Original solution: 1000.0103000 g Original solution / Rock added: 25006.51 (Water/Rock Ratio), log = 4.3981 The following minerals and/or gases with identical index are in solid solution: H2O,gas 6 CO2,gas 6 CH4,gas 6 H2,gas 6 H2S,gas 6 S2,gas 6 CO,gas 6 SO3,gas 6 SO2,gas 6 HF,gas 6 HCl,gas 6 almandine 16 pyrope 16 spessartine 16 andradite 8 grossular 8 annite 15 phlogopite 15 biotite-Mn 15 clinochlore 1 daphnite 1 chlorite-Mn 1 diopside 5 hedenbergite 5 epidote 3 clinozoisite 3 iron 9 magnetite 14 talc 7 talc-Fe 7 tremolite 2 ferroactinolite 2 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 10 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 0.0399900 Water: Moles liquid = 0.4989E+02 kg liquid = 0.8987E+00 Moles total = 0.4988E+02 kg total = 0.8986E+00 Activity = 1.0000 Stoichiometric ionic strength = .1391192E-01 Osmotic coef. = 0.9331 True ionic strength = .2231529E-01 Chg. balance for total moles = -.5508E-08 Max. difference allowed = 0.3738E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.16077E-09 -9.7938 0.13418E-09 -9.8723 0.83458E+00 -0.0785 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.41403E-03 -3.3830 0.34328E-03 -3.4644 0.82912E+00 -0.0814 4 SO4-- 0.19561E-03 -3.7086 0.98703E-04 -4.0057 0.50459E+00 -0.2971 5 HCO3- 0.15580E-02 -2.8074 0.12938E-02 -2.8881 0.83044E+00 -0.0807 6 HS- 0.91346E-03 -3.0393 0.75748E-03 -3.1206 0.82925E+00 -0.0813 7 Al+++ 0.34221E-28 -28.4657 0.74014E-29 -29.1307 0.21628E+00 -0.6650 8 H4SiO4 0.10246E-02 -2.9894 0.10246E-02 -2.9894 0.10000E+01 0.0000 9 Ca++ 0.34350E-07 -7.4641 0.17194E-07 -7.7646 0.50056E+00 -0.3005 10 Mg++ 0.22051E-10 -10.6566 0.10983E-10 -10.9593 0.49806E+00 -0.3027 11 Fe++ 0.14154E-12 -12.8491 0.70581E-13 -13.1513 0.49866E+00 -0.3022 12 K+ 0.15649E-03 -3.8055 0.12998E-03 -3.8861 0.83065E+00 -0.0806 13 Na+ 0.20290E-01 -1.6927 0.16819E-01 -1.7742 0.82895E+00 -0.0815 14 Mn++ 0.55378E-10 -10.2567 0.27640E-10 -10.5585 0.49911E+00 -0.3018 15 F- 0.17851E-04 -4.7483 0.14768E-04 -4.8307 0.82726E+00 -0.0824 16 HPO4-- 0.45702E-07 -7.3401 0.23064E-07 -7.6371 0.50467E+00 -0.2970 18 HSiO3- 0.86001E-02 -2.0655 0.71305E-02 -2.1469 0.82912E+00 -0.0814 19 Ca(HSiO3)+ 0.33606E-08 -8.4736 0.27921E-08 -8.5541 0.83084E+00 -0.0805 20 Mg(HSiO3)+ 0.26715E-11 -11.5733 0.22196E-11 -11.6537 0.83084E+00 -0.0805 21 NaHSiO3,aq 0.19397E-02 -2.7123 0.19397E-02 -2.7123 0.10000E+01 0.0000 22 AlO+ 0.67318E-16 -16.1719 0.55930E-16 -16.2524 0.83084E+00 -0.0805 24 HAlO2,aq 0.83014E-10 -10.0808 0.83014E-10 -10.0808 0.10000E+01 0.0000 25 AlO2- 0.16551E-05 -5.7812 0.13695E-05 -5.8634 0.82749E+00 -0.0822 26 CH4,aq 0.96859E-08 -8.0139 0.96450E-08 -8.0157 0.99577E+00 -0.0018 27 C2H6,aq 0.85704E-19 -19.0670 0.85341E-19 -19.0688 0.99577E+00 -0.0018 31 CO,aq 0.17364E-14 -14.7603 0.17364E-14 -14.7603 0.10000E+01 0.0000 32 CO2,aq 0.37251E-06 -6.4289 0.37094E-06 -6.4307 0.99577E+00 -0.0018 33 CO3-2 0.16730E-02 -2.7765 0.84225E-03 -3.0746 0.50343E+00 -0.2981 34 CaCO3,aq 0.18159E-06 -6.7409 0.18159E-06 -6.7409 0.10000E+01 0.0000 35 Ca(HCO3)+ 0.68347E-09 -9.1653 0.56785E-09 -9.2458 0.83084E+00 -0.0805 36 CaCl+ 0.11497E-10 -10.9394 0.95520E-11 -11.0199 0.83084E+00 -0.0805 37 CaCl2,aq 0.77902E-15 -15.1085 0.77902E-15 -15.1085 0.10000E+01 0.0000 38 CaF+ 0.44620E-11 -11.3505 0.37073E-11 -11.4309 0.83084E+00 -0.0805 39 CaOH+ 0.10992E-07 -7.9589 0.91330E-08 -8.0394 0.83084E+00 -0.0805 40 CaSO4,aq 0.53892E-09 -9.2685 0.53892E-09 -9.2685 0.10000E+01 0.0000 41 HCl,aq 0.84402E-14 -14.0736 0.84402E-14 -14.0736 0.10000E+01 0.0000 45 HF,aq 0.13564E-10 -10.8676 0.13564E-10 -10.8676 0.10000E+01 0.0000 46 HF2- 0.81571E-16 -16.0885 0.67632E-16 -16.1698 0.82912E+00 -0.0814 48 FeCl+ 0.46159E-16 -16.3357 0.38351E-16 -16.4162 0.83084E+00 -0.0805 51 FeF+ 0.64109E-16 -16.1931 0.53265E-16 -16.2736 0.83084E+00 -0.0805 53 FeO,aq 0.15237E-09 -9.8171 0.15237E-09 -9.8171 0.10000E+01 0.0000 54 FeOH+ 0.20609E-10 -10.6859 0.17123E-10 -10.7664 0.83084E+00 -0.0805 55 HFeO2- 0.14331E-07 -7.8437 0.11882E-07 -7.9251 0.82912E+00 -0.0814 56 FeO+ 0.11387E-15 -15.9436 0.94612E-16 -16.0241 0.83084E+00 -0.0805 58 FeO2- 0.12970E-08 -8.8871 0.10754E-08 -8.9684 0.82912E+00 -0.0814 59 HFeO2,aq 0.18351E-10 -10.7363 0.18351E-10 -10.7363 0.10000E+01 0.0000 60 H2,aq 0.18714E-06 -6.7278 0.18635E-06 -6.7297 0.99577E+00 -0.0018 61 KCl,aq 0.80872E-09 -9.0922 0.80872E-09 -9.0922 0.10000E+01 0.0000 62 KHSO4,aq 0.48672E-17 -17.3127 0.48672E-17 -17.3127 0.10000E+01 0.0000 63 KOH,aq 0.41372E-06 -6.3833 0.41372E-06 -6.3833 0.10000E+01 0.0000 64 KSO4- 0.24012E-06 -6.6196 0.19909E-06 -6.7010 0.82912E+00 -0.0814 65 MgCO3,aq 0.29073E-10 -10.5365 0.29073E-10 -10.5365 0.10000E+01 0.0000 66 Mg(HCO3)+ 0.44609E-12 -12.3506 0.37063E-12 -12.4311 0.83084E+00 -0.0805 67 MgCl+ 0.66557E-14 -14.1768 0.55299E-14 -14.2573 0.83084E+00 -0.0805 68 MgF+ 0.10558E-13 -13.9764 0.87718E-14 -14.0569 0.83084E+00 -0.0805 69 MgOH+ 0.38853E-10 -10.4106 0.32281E-10 -10.4911 0.83084E+00 -0.0805 71 MnF+ 0.82749E-14 -14.0822 0.68752E-14 -14.1627 0.83084E+00 -0.0805 72 MnO,aq 0.15899E-08 -8.7986 0.15899E-08 -8.7986 0.10000E+01 0.0000 73 MnOH+ 0.74974E-09 -9.1251 0.62291E-09 -9.2056 0.83084E+00 -0.0805 74 MnO2-2 0.58220E-11 -11.2349 0.29310E-11 -11.5330 0.50343E+00 -0.2981 75 HMnO2- 0.10391E-09 -9.9833 0.86158E-10 -10.0647 0.82912E+00 -0.0814 78 MnCl+ 0.70323E-13 -13.1529 0.58427E-13 -13.2334 0.83084E+00 -0.0805 79 MnSO4,aq 0.78759E-12 -12.1037 0.78759E-12 -12.1037 0.10000E+01 0.0000 80 NaCl,aq 0.19134E-05 -5.7182 0.19134E-05 -5.7182 0.10000E+01 0.0000 81 NaF,aq 0.58151E-07 -7.2354 0.58151E-07 -7.2354 0.10000E+01 0.0000 82 NaOH,aq 0.53858E-04 -4.2687 0.53858E-04 -4.2687 0.10000E+01 0.0000 84 OH- 0.52038E-02 -2.2837 0.43061E-02 -2.3659 0.82749E+00 -0.0822 89 HPO3-2 0.26606E-16 -16.5750 0.13394E-16 -16.8731 0.50343E+00 -0.2981 92 H3PO4,aq 0.29041E-17 -17.5370 0.29041E-17 -17.5370 0.10000E+01 0.0000 93 H2PO4- 0.68783E-10 -10.1625 0.57088E-10 -10.2435 0.82997E+00 -0.0809 94 PO4-3 0.61473E-09 -9.2113 0.14025E-09 -9.8531 0.22815E+00 -0.6418 98 HP2O7-3 0.17563E-17 -17.7554 0.38029E-18 -18.4199 0.21652E+00 -0.6645 99 P2O7-4 0.98490E-17 -17.0066 0.67711E-18 -18.1693 0.68749E-01 -1.1627 100 H2S,aq 0.31545E-06 -6.5011 0.31412E-06 -6.5029 0.99577E+00 -0.0018 101 S2-2 0.13552E-09 -9.8680 0.68226E-10 -10.1660 0.50343E+00 -0.2981 102 S3-2 0.30777E-15 -15.5118 0.15494E-15 -15.8098 0.50343E+00 -0.2981 103 S3- 0.38935E-19 -19.4097 0.32282E-19 -19.4910 0.82912E+00 -0.0814 107 SO3-2 0.46742E-11 -11.3303 0.23902E-11 -11.6216 0.51135E+00 -0.2913 108 HSO3- 0.24219E-13 -13.6159 0.20080E-13 -13.6972 0.82912E+00 -0.0814 109 HSO4- 0.15345E-10 -10.8140 0.12763E-10 -10.8940 0.83173E+00 -0.0800 111 S2O3-2 0.72344E-12 -12.1406 0.36420E-12 -12.4387 0.50343E+00 -0.2981 112 HS2O3- 0.10538E-19 -19.9772 0.87375E-20 -20.0586 0.82912E+00 -0.0814 Charge balance for all species = -.6128E-08 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.1607704E-09 -.1747720E-01 -.1758473E+02 0.0000 2 H2O 0.1000000E+01 0.5550297E+02 0.9981296E+06 0.0000 3 Cl- 0.4140301E-03 0.4159443E-03 0.1472032E+02 6.4080 4 SO4-- 0.1956091E-03 0.1957935E-03 0.1877489E+02 15.7390 5 HCO3- 0.1557987E-02 0.3231582E-02 0.1968324E+03 6.9842 6 HS- 0.9134580E-03 0.9138300E-03 0.3016859E+02 6.7517 7 Al+++ 0.3422144E-28 0.1655145E-05 0.4457910E-01 0.4863 8 H4SiO4 0.1024625E-02 0.1156446E-01 0.1109552E+04 -2.9894 9 Ca++ 0.3435032E-07 0.2315284E-06 0.9262740E-02 11.9800 10 Mg++ 0.2205096E-10 0.9311193E-10 0.2259723E-05 8.7854 11 Fe++ 0.1415431E-12 0.1581981E-07 0.8819221E-03 6.5933 12 K+ 0.1564851E-03 0.1571398E-03 0.6133583E+01 5.9862 13 Na+ 0.2029000E-01 0.2228553E-01 0.5114315E+03 8.0981 14 Mn++ 0.5537835E-10 0.2505666E-08 0.1374122E-03 9.1862 15 F- 0.1785138E-04 0.1790955E-04 0.3396422E+00 5.0416 16 HPO4-- 0.4570171E-07 0.4638522E-07 0.4444113E-02 12.1076 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.1572062E-01 -.1570743E-01 -.1318247E-04 0.0000000E+00 2 H2O 0.4987915E+02 0.4988266E+02 -.3512574E-02 0.0000000E+00 3 Cl- 0.3738252E-03 0.3738252E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.1759672E-03 0.1759672E-03 0.0000000E+00 0.0000000E+00 5 HCO3- 0.2904347E-02 0.2904347E-02 0.0000000E+00 0.0000000E+00 6 HS- 0.8212943E-03 0.8212943E-03 0.0000000E+00 0.0000000E+00 7 Al+++ 0.4775352E-05 0.1487543E-05 0.3287809E-05 0.0000000E+00 8 H4SiO4 0.1215302E-01 0.1039343E-01 0.1759594E-02 0.0000000E+00 9 Ca++ 0.2080835E-06 0.2080835E-06 0.0000000E+00 0.0000000E+00 10 Mg++ 0.8368328E-10 0.8368328E-10 0.0000000E+00 0.0000000E+00 11 Fe++ 0.3259227E-07 0.1421787E-07 0.1837440E-07 0.0000000E+00 12 K+ 0.1412294E-03 0.1412276E-03 0.1837440E-08 0.0000000E+00 13 Na+ 0.2003215E-01 0.2002887E-01 0.3280460E-05 0.0000000E+00 14 Mn++ 0.2251939E-08 0.2251939E-08 0.0000000E+00 0.0000000E+00 15 F- 0.1609600E-04 0.1609600E-04 0.0000000E+00 0.0000000E+00 16 HPO4-- 0.4168819E-07 0.4168819E-07 0.0000000E+00 0.0000000E+00 Chg. balance for solid moles: 0.8470E-21 Mass of aqueous solution: 0.900335E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 0.0399900 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 0.3280E-05 -5.484 0.8602E-03 -3.065 0.8116 0.3302E-03 quartz 0.1750E-02 -2.757 0.1051 -0.978 99.18 0.3970E-01 stilpnomelane-Fe 0.3675E-08 -8.435 0.3961E-05 -5.402 0.3738E-02 0.1368E-05 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 quartz 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 0.105988 g Volume = 0.040031 cm3 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.0399900 moles log = -1.3980 Original solution: 1000.0103000 g Original solution / Rock added: 25006.51 (Water/Rock Ratio), log = 4.3981 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0206 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9997E+00 0.9859 0.1006E+01 0.1020E+01 CO2,gas 0.3861E-04 1.0071 0.3969E-04 0.3941E-04 CH4,gas 0.1374E-04 1.0125 0.1420E-04 0.1402E-04 H2,gas 0.2396E-03 1.0005 0.2447E-03 0.2445E-03 H2S,gas 0.8494E-05 0.9960 0.8635E-05 0.8669E-05 S2,gas 0.4581E-22 1.0000 0.4676E-22 0.4676E-22 CO,gas 0.2535E-11 1.0000 0.2588E-11 0.2588E-11 SO3,gas 0.6583E-39 1.0000 0.6719E-39 0.6719E-39 SO2,gas 0.6266E-20 1.0000 0.6395E-20 0.6395E-20 HF,gas 0.3263E-13 1.0000 0.3331E-13 0.3331E-13 HCl,gas 0.1459E-16 1.0000 0.1489E-16 0.1489E-16 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 17 albite -0.38 -0.38 0.00 0.000 -0.94784E-12 150 quartz -2.99 -2.99 0.00 0.000 0.00000E+00 167 stilpnomelane-Fe 13.02 13.02 0.00 0.000 -0.27298E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -12.76 -6.10 -2.033 0.10416E+05 -4.401 3 CH4,gas 4.54 -2.00 -6.55 -1.637 0.11178E+05 -4.848 4 H2,gas 8.00 2.69 -5.31 -3.035 0.90674E+04 -3.611 5 H2S,gas -6.23 -12.99 -6.76 -3.381 0.11547E+05 -5.064 6 S2,gas -7.34 -31.36 -24.03 -3.697 0.41029E+05 -22.330 7 CO,gas 3.21 -10.07 -13.29 -4.088 0.22686E+05 -11.587 8 SO3,gas 17.12 -23.75 -40.87 -10.218 0.69787E+05 -39.173 9 SO2,gas 0.83 -21.06 -21.89 -5.838 0.37382E+05 -20.194 10 HF,gas 0.47 -14.70 -15.18 -7.588 0.25913E+05 -13.477 11 HCl,gas 5.19 -13.34 -18.53 -9.263 0.31633E+05 -16.827 12 acmite 7.71 7.37 -0.34 -0.036 0.58356E+03 16 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 20 spessartine 24.46 19.56 -4.89 -0.245 0.83572E+04 21 analcite 3.32 2.61 -0.72 -0.080 0.12231E+04 23 andradite 39.01 37.47 -1.54 -0.080 0.26288E+04 24 grossular 32.73 27.94 -4.79 -0.239 0.81737E+04 26 ankerite -2.14 -6.95 -4.81 -0.802 0.82171E+04 27 annite 20.12 17.28 -2.84 -0.158 0.48478E+04 28 phlogopite 27.06 23.86 -3.20 -0.178 0.54712E+04 33 apatite-OH -18.15 -22.24 -4.09 -0.315 0.69861E+04 34 apatite-F -34.30 -36.95 -2.65 -0.221 0.45196E+04 38 aragonite 0.97 -0.78 -1.75 -0.582 0.29828E+04 39 brucite 12.57 8.79 -3.78 -0.757 0.64597E+04 40 calcite 0.81 -0.78 -1.59 -0.531 0.27186E+04 41 carnegieite-low 9.02 5.60 -3.43 -0.490 0.58537E+04 42 carnegieite-high 10.09 5.60 -4.50 -0.643 0.76807E+04 43 carpholite-Mg 8.58 3.78 -4.80 -0.320 0.82010E+04 45 celadonite 5.34 3.30 -2.04 -0.120 0.34857E+04 46 celadonite-Fe 3.88 1.11 -2.77 -0.163 0.47270E+04 47 chrysotile 23.89 20.38 -3.52 -0.293 0.60020E+04 49 clinochlore 39.07 35.93 -3.14 -0.098 0.53587E+04 50 daphnite 28.97 24.97 -3.99 -0.125 0.68200E+04 54 chloritoid-Fe 9.17 4.58 -4.60 -0.306 0.78494E+04 55 chloritoid-Mn 11.40 7.17 -4.23 -0.282 0.72255E+04 57 coesite -2.38 -2.99 -0.61 -0.204 0.10473E+04 64 cristobalite -2.56 -2.99 -0.43 -0.143 0.73267E+03 66 cymrite-K 1.69 -2.50 -4.18 -0.348 0.71392E+04 68 diaspore 2.87 0.49 -2.39 -0.398 0.40764E+04 69 diamond -3.10 -7.38 -4.28 -1.223 0.73069E+04 70 diopside 16.18 14.79 -1.39 -0.139 0.23816E+04 71 hedenbergite 14.21 12.59 -1.61 -0.161 0.27555E+04 78 epidote 24.67 21.21 -3.46 -0.168 0.59025E+04 80 epidote-Fe 29.84 25.98 -3.87 -0.201 0.66000E+04 81 fayalite 14.05 10.20 -3.85 -0.550 0.65712E+04 82 ferrosilite 11.15 7.21 -3.94 -0.394 0.67302E+04 86 gibbsite 4.08 0.49 -3.59 -0.513 0.61350E+04 87 glaucophane 22.97 19.61 -3.37 -0.091 0.57462E+04 88 glaucophane-Fe 17.28 13.03 -4.24 -0.115 0.72438E+04 89 graphite -3.55 -7.38 -3.84 -1.096 0.65492E+04 90 greenalite 16.14 13.80 -2.34 -0.195 0.39926E+04 93 hematite 12.57 10.50 -2.07 -0.251 0.35325E+04 94 heulandite -5.83 -7.97 -2.15 -0.098 0.36645E+04 98 jadeite 4.22 2.61 -1.61 -0.161 0.27485E+04 100 kalsilite 7.58 3.48 -4.10 -0.586 0.70020E+04 101 kaolinite -1.33 -5.01 -3.67 -0.334 0.62724E+04 104 laumontite 2.88 0.99 -1.89 -0.126 0.32246E+04 105 lawsonite 9.62 6.97 -2.64 -0.176 0.45117E+04 106 leucite 4.12 0.49 -3.63 -0.363 0.61900E+04 108 lizardite 23.24 20.38 -2.87 -0.239 0.48947E+04 109 magnesite 0.69 -3.98 -4.67 -1.555 0.79665E+04 110 magnetite 20.09 17.09 -3.00 -0.245 0.51168E+04 111 minnesotaite 10.39 7.82 -2.57 -0.151 0.43810E+04 115 manganosite 14.06 9.19 -4.87 -1.218 0.83187E+04 119 microcline -2.49 -2.50 -0.01 -0.001 0.15865E+02 123 muscovite 2.58 -1.52 -4.11 -0.242 0.70102E+04 124 paragonite 4.24 0.59 -3.65 -0.215 0.62335E+04 125 nepheline 8.34 5.60 -2.74 -0.392 0.46861E+04 137 phlogopite-Na 29.65 25.97 -3.67 -0.204 0.62742E+04 139 prehnite 19.37 15.96 -3.41 -0.200 0.58182E+04 140 prehnite-Fe 22.50 20.73 -1.77 -0.107 0.30241E+04 145 pyrite -21.25 -22.08 -0.83 -0.196 0.14257E+04 146 pyrrhotite -4.26 -6.40 -2.14 -0.713 0.36528E+04 147 pyrrhotiteFe0.875 -6.02 -7.56 -1.54 -0.566 0.26300E+04 148 pyroxmangite 7.40 6.20 -1.20 -0.240 0.20523E+04 149 pyrophyllite -6.18 -10.99 -4.81 -0.301 0.82118E+04 154 rhodochrosite -0.98 -3.57 -2.60 -0.866 0.44359E+04 155 rhodonite 7.45 6.20 -1.25 -0.250 0.21325E+04 156 sanidine -1.28 -2.50 -1.22 -0.094 0.20836E+04 158 siderite -2.61 -6.17 -3.56 -1.186 0.60768E+04 166 stilbite -7.52 -7.97 -0.45 -0.021 0.77067E+03 168 stilpnomelane-Mg 27.44 23.98 -3.46 -0.103 0.59152E+04 174 talc 16.49 14.40 -2.09 -0.123 0.35732E+04 177 tephroite 18.09 15.38 -2.70 -0.386 0.46150E+04 181 tridymite -2.63 -2.99 -0.36 -0.121 0.61998E+03 182 tremolite 47.87 43.97 -3.90 -0.105 0.66554E+04 184 troilite-low -4.41 -6.40 -1.99 -0.663 0.33956E+04 190 wairakite 3.95 0.99 -2.96 -0.174 0.50465E+04 191 walstromite 11.51 8.99 -2.52 -0.504 0.43005E+04 192 wollastonite 10.46 8.99 -1.47 -0.294 0.25109E+04 193 pseudo-wollastonite 11.00 8.99 -2.01 -0.402 0.34307E+04 195 akaganeite 7.75 5.25 -2.51 -0.542 0.42788E+04 202 chalcedony -2.80 -2.99 -0.19 -0.062 0.31930E+03 204 montmorillonite-Ca -2.29 -6.27 -3.98 -0.246 0.67941E+04 205 montmorillonite-K -2.24 -6.27 -4.03 -0.247 0.68884E+04 206 montmorillonite-Mg -2.48 -6.80 -4.32 -0.267 0.73711E+04 207 montmorillonite-Na -2.04 -5.57 -3.54 -0.217 0.60381E+04 208 nontronite-Ca 3.21 1.66 -1.55 -0.101 0.26487E+04 209 nontronite-H 2.53 -0.31 -2.85 -0.191 0.48596E+04 210 nontronite-K 3.34 1.66 -1.68 -0.108 0.28662E+04 211 nontronite-Mg 3.07 1.14 -1.94 -0.126 0.33098E+04 212 nontronite-Na 3.52 2.36 -1.16 -0.074 0.19819E+04 228 tobermorite 9.82 6.99 -2.83 -0.773 0.48375E+04 234 alabandite -0.98 -3.81 -2.83 -0.943 0.48303E+04 237 boehmite 4.41 0.49 -3.92 -0.653 0.66933E+04 239 ferrous-oxide 9.81 6.59 -3.22 -0.805 0.54950E+04 245 silica-amorphous -2.09 -2.99 -0.90 -0.299 0.15335E+04 247 an20ab80 2.02 1.09 -0.93 -0.072 0.15882E+04 248 an25ab75 2.65 1.46 -1.19 -0.092 0.20322E+04 249 an30ab70 3.28 1.82 -1.46 -0.112 0.24858E+04 250 tr.625ac.25prg.125 45.16 42.08 -3.09 -0.083 0.52752E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 0.0020000 MOLES Current total amount of reactant added: 0.0399900 MOLES New total amount of reactant added: 0.0419900 MOLES Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.5508E-08 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 7 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 0.0419900 Water: Moles liquid = 0.4989E+02 kg liquid = 0.8988E+00 Moles total = 0.4988E+02 kg total = 0.8986E+00 Activity = 1.0000 Stoichiometric ionic strength = .1404179E-01 Osmotic coef. = 0.9326 True ionic strength = .2242896E-01 Chg. balance for total moles = -.5508E-08 Max. difference allowed = 0.3856E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.16409E-09 -9.7849 0.13690E-09 -9.8636 0.83431E+00 -0.0787 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.42708E-03 -3.3695 0.35398E-03 -3.4510 0.82883E+00 -0.0815 4 SO4-- 0.20621E-03 -3.6857 0.10391E-03 -3.9833 0.50390E+00 -0.2977 5 HCO3- 0.16517E-02 -2.7821 0.13711E-02 -2.8629 0.83015E+00 -0.0808 6 HS- 0.95685E-03 -3.0192 0.79319E-03 -3.1006 0.82896E+00 -0.0815 7 Al+++ 0.37154E-28 -28.4300 0.80105E-29 -29.0963 0.21560E+00 -0.6663 8 H4SiO4 0.10246E-02 -2.9894 0.10246E-02 -2.9894 0.10000E+01 0.0000 9 Ca++ 0.33408E-07 -7.4761 0.16699E-07 -7.7773 0.49985E+00 -0.3012 10 Mg++ 0.21994E-10 -10.6577 0.10939E-10 -10.9610 0.49736E+00 -0.3033 11 Fe++ 0.14677E-12 -12.8334 0.73083E-13 -13.1362 0.49795E+00 -0.3028 12 K+ 0.15647E-03 -3.8056 0.12993E-03 -3.8863 0.83037E+00 -0.0807 13 Na+ 0.20326E-01 -1.6919 0.16843E-01 -1.7736 0.82866E+00 -0.0816 14 Mn++ 0.57373E-10 -10.2413 0.28595E-10 -10.5437 0.49840E+00 -0.3024 15 F- 0.18738E-04 -4.7273 0.15496E-04 -4.8098 0.82696E+00 -0.0825 16 HPO4-- 0.45710E-07 -7.3400 0.23037E-07 -7.6376 0.50398E+00 -0.2976 18 HSiO3- 0.84317E-02 -2.0741 0.69884E-02 -2.1556 0.82883E+00 -0.0815 19 Ca(HSiO3)+ 0.31999E-08 -8.4949 0.26577E-08 -8.5755 0.83056E+00 -0.0806 20 Mg(HSiO3)+ 0.26087E-11 -11.5836 0.21667E-11 -11.6642 0.83056E+00 -0.0806 21 NaHSiO3,aq 0.19038E-02 -2.7204 0.19038E-02 -2.7204 0.10000E+01 0.0000 22 AlO+ 0.70007E-16 -16.1549 0.58145E-16 -16.2355 0.83056E+00 -0.0806 24 HAlO2,aq 0.84581E-10 -10.0727 0.84581E-10 -10.0727 0.10000E+01 0.0000 25 AlO2- 0.16533E-05 -5.7816 0.13676E-05 -5.8640 0.82719E+00 -0.0824 26 CH4,aq 0.10210E-07 -7.9910 0.10167E-07 -7.9928 0.99574E+00 -0.0019 27 C2H6,aq 0.95838E-19 -19.0185 0.95429E-19 -19.0203 0.99574E+00 -0.0019 31 CO,aq 0.18657E-14 -14.7292 0.18657E-14 -14.7292 0.10000E+01 0.0000 32 CO2,aq 0.40281E-06 -6.3949 0.40110E-06 -6.3968 0.99574E+00 -0.0019 33 CO3-2 0.17401E-02 -2.7594 0.87480E-03 -3.0581 0.50274E+00 -0.2987 34 CaCO3,aq 0.18317E-06 -6.7371 0.18317E-06 -6.7371 0.10000E+01 0.0000 35 Ca(HCO3)+ 0.70370E-09 -9.1526 0.58446E-09 -9.2332 0.83056E+00 -0.0806 36 CaCl+ 0.11518E-10 -10.9386 0.95660E-11 -11.0193 0.83056E+00 -0.0806 37 CaCl2,aq 0.80448E-15 -15.0945 0.80448E-15 -15.0945 0.10000E+01 0.0000 38 CaF+ 0.45487E-11 -11.3421 0.37780E-11 -11.4227 0.83056E+00 -0.0806 39 CaOH+ 0.10467E-07 -7.9802 0.86933E-08 -8.0608 0.83056E+00 -0.0806 40 CaSO4,aq 0.55102E-09 -9.2588 0.55102E-09 -9.2588 0.10000E+01 0.0000 41 HCl,aq 0.88802E-14 -14.0516 0.88802E-14 -14.0516 0.10000E+01 0.0000 45 HF,aq 0.14522E-10 -10.8380 0.14522E-10 -10.8380 0.10000E+01 0.0000 46 HF2- 0.91668E-16 -16.0378 0.75977E-16 -16.1193 0.82883E+00 -0.0815 48 FeCl+ 0.49301E-16 -16.3071 0.40947E-16 -16.3878 0.83056E+00 -0.0806 51 FeF+ 0.69677E-16 -16.1569 0.57871E-16 -16.2375 0.83056E+00 -0.0806 53 FeO,aq 0.15155E-09 -9.8194 0.15155E-09 -9.8194 0.10000E+01 0.0000 54 FeOH+ 0.20922E-10 -10.6794 0.17377E-10 -10.7600 0.83056E+00 -0.0806 55 HFeO2- 0.13975E-07 -7.8547 0.11583E-07 -7.9362 0.82883E+00 -0.0815 56 FeO+ 0.11597E-15 -15.9357 0.96320E-16 -16.0163 0.83056E+00 -0.0806 58 FeO2- 0.12687E-08 -8.8966 0.10516E-08 -8.9782 0.82883E+00 -0.0815 59 HFeO2,aq 0.18310E-10 -10.7373 0.18310E-10 -10.7373 0.10000E+01 0.0000 60 H2,aq 0.18596E-06 -6.7306 0.18516E-06 -6.7324 0.99574E+00 -0.0019 61 KCl,aq 0.83358E-09 -9.0791 0.83358E-09 -9.0791 0.10000E+01 0.0000 62 KHSO4,aq 0.52261E-17 -17.2818 0.52261E-17 -17.2818 0.10000E+01 0.0000 63 KOH,aq 0.40531E-06 -6.3922 0.40531E-06 -6.3922 0.10000E+01 0.0000 64 KSO4- 0.25278E-06 -6.5973 0.20951E-06 -6.6788 0.82883E+00 -0.0815 65 MgCO3,aq 0.30076E-10 -10.5218 0.30076E-10 -10.5218 0.10000E+01 0.0000 66 Mg(HCO3)+ 0.47102E-12 -12.3270 0.39121E-12 -12.4076 0.83056E+00 -0.0806 67 MgCl+ 0.68381E-14 -14.1651 0.56795E-14 -14.2457 0.83056E+00 -0.0806 68 MgF+ 0.11038E-13 -13.9571 0.91674E-14 -14.0378 0.83056E+00 -0.0806 69 MgOH+ 0.37940E-10 -10.4209 0.31511E-10 -10.5015 0.83056E+00 -0.0806 71 MnF+ 0.89859E-14 -14.0464 0.74633E-14 -14.1271 0.83056E+00 -0.0806 72 MnO,aq 0.15800E-08 -8.8013 0.15800E-08 -8.8013 0.10000E+01 0.0000 73 MnOH+ 0.76045E-09 -9.1189 0.63160E-09 -9.1996 0.83056E+00 -0.0806 74 MnO2-2 0.55650E-11 -11.2545 0.27977E-11 -11.5532 0.50274E+00 -0.2987 75 HMnO2- 0.10124E-09 -9.9946 0.83912E-10 -10.0762 0.82883E+00 -0.0815 78 MnCl+ 0.75046E-13 -13.1247 0.62330E-13 -13.2053 0.83056E+00 -0.0806 79 MnSO4,aq 0.85781E-12 -12.0666 0.85781E-12 -12.0666 0.10000E+01 0.0000 80 NaCl,aq 0.19759E-05 -5.7042 0.19759E-05 -5.7042 0.10000E+01 0.0000 81 NaF,aq 0.61104E-07 -7.2139 0.61104E-07 -7.2139 0.10000E+01 0.0000 82 NaOH,aq 0.52860E-04 -4.2769 0.52860E-04 -4.2769 0.10000E+01 0.0000 84 OH- 0.51020E-02 -2.2923 0.42203E-02 -2.3747 0.82719E+00 -0.0824 89 HPO3-2 0.26442E-16 -16.5777 0.13293E-16 -16.8764 0.50274E+00 -0.2987 92 H3PO4,aq 0.30198E-17 -17.5200 0.30198E-17 -17.5200 0.10000E+01 0.0000 93 H2PO4- 0.70122E-10 -10.1541 0.58180E-10 -10.2352 0.82969E+00 -0.0811 94 PO4-3 0.60353E-09 -9.2193 0.13729E-09 -9.8624 0.22748E+00 -0.6431 98 HP2O7-3 0.17934E-17 -17.7463 0.38710E-18 -18.4122 0.21585E+00 -0.6659 99 P2O7-4 0.98794E-17 -17.0053 0.67549E-18 -18.1704 0.68374E-01 -1.1651 100 H2S,aq 0.33705E-06 -6.4723 0.33561E-06 -6.4742 0.99574E+00 -0.0019 101 S2-2 0.14976E-09 -9.8246 0.75288E-10 -10.1233 0.50274E+00 -0.2987 102 S3-2 0.36570E-15 -15.4369 0.18385E-15 -15.7355 0.50274E+00 -0.2987 103 S3- 0.47305E-19 -19.3251 0.39208E-19 -19.4066 0.82883E+00 -0.0815 107 SO3-2 0.48961E-11 -11.3102 0.25003E-11 -11.6020 0.51068E+00 -0.2918 108 HSO3- 0.25859E-13 -13.5874 0.21432E-13 -13.6689 0.82883E+00 -0.0815 109 HSO4- 0.16489E-10 -10.7828 0.13710E-10 -10.8630 0.83145E+00 -0.0802 111 S2O3-2 0.81486E-12 -12.0889 0.40966E-12 -12.3876 0.50274E+00 -0.2987 112 HS2O3- 0.12099E-19 -19.9173 0.10028E-19 -19.9988 0.82883E+00 -0.0815 Charge balance for all species = -.6128E-08 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.1640921E-09 -.1723692E-01 -.1734306E+02 0.0000 2 H2O 0.1000000E+01 0.5550307E+02 0.9981362E+06 0.0000 3 Cl- 0.4270807E-03 0.4290574E-03 0.1518447E+02 6.4126 4 SO4-- 0.2062148E-03 0.2064116E-03 0.1979316E+02 15.7438 5 HCO3- 0.1651664E-02 0.3392344E-02 0.2066253E+03 7.0007 6 HS- 0.9568493E-03 0.9572431E-03 0.3160196E+02 6.7630 7 Al+++ 0.3715449E-28 0.1653378E-05 0.4453174E-01 0.4944 8 H4SiO4 0.1024625E-02 0.1136007E-01 0.1089947E+04 -2.9894 9 Ca++ 0.3340807E-07 0.2315195E-06 0.9262430E-02 11.9499 10 Mg++ 0.2199434E-10 0.9310836E-10 0.2259647E-05 8.7662 11 Fe++ 0.1467674E-12 0.1543426E-07 0.8604325E-03 6.5910 12 K+ 0.1564748E-03 0.1571337E-03 0.6133376E+01 5.9773 13 Na+ 0.2032602E-01 0.2228468E-01 0.5114143E+03 8.0900 14 Mn++ 0.5737334E-10 0.2505570E-08 0.1374076E-03 9.1835 15 F- 0.1873784E-04 0.1879896E-04 0.3565111E+00 5.0538 16 HPO4-- 0.4570979E-07 0.4638345E-07 0.4443964E-02 12.0896 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.1550527E-01 -.1549208E-01 -.1318918E-04 0.0000000E+00 2 H2O 0.4988079E+02 0.4988467E+02 -.3879165E-02 0.0000000E+00 3 Cl- 0.3856252E-03 0.3856252E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.1855172E-03 0.1855172E-03 0.0000000E+00 0.0000000E+00 5 HCO3- 0.3048947E-02 0.3048947E-02 0.0000000E+00 0.0000000E+00 6 HS- 0.8603443E-03 0.8603443E-03 0.0000000E+00 0.0000000E+00 7 Al+++ 0.4775352E-05 0.1486012E-05 0.3289340E-05 0.0000000E+00 8 H4SiO4 0.1215302E-01 0.1021013E-01 0.1942891E-02 0.0000000E+00 9 Ca++ 0.2080835E-06 0.2080835E-06 0.0000000E+00 0.0000000E+00 10 Mg++ 0.8368328E-10 0.8368328E-10 0.0000000E+00 0.0000000E+00 11 Fe++ 0.3259227E-07 0.1387189E-07 0.1872038E-07 0.0000000E+00 12 K+ 0.1412294E-03 0.1412275E-03 0.1872038E-08 0.0000000E+00 13 Na+ 0.2003215E-01 0.2002887E-01 0.3281852E-05 0.0000000E+00 14 Mn++ 0.2251939E-08 0.2251939E-08 0.0000000E+00 0.0000000E+00 15 F- 0.1689600E-04 0.1689600E-04 0.0000000E+00 0.0000000E+00 16 HPO4-- 0.4168819E-07 0.4168819E-07 0.0000000E+00 0.0000000E+00 Chg. balance for solid moles: 0.1271E-20 Mass of aqueous solution: 0.900365E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 0.0419900 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 0.3282E-05 -5.484 0.8606E-03 -3.065 0.7355 0.3304E-03 quartz 0.1933E-02 -2.714 0.1161 -0.935 99.26 0.4386E-01 stilpnomelane-Fe 0.3744E-08 -8.427 0.4036E-05 -5.394 0.3450E-02 0.1394E-05 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 quartz 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 0.117000 g Volume = 0.044190 cm3 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.0419900 moles log = -1.3769 Original solution: 1000.0103000 g Original solution / Rock added: 23815.44 (Water/Rock Ratio), log = 4.3769 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0206 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9997E+00 0.9859 0.1006E+01 0.1020E+01 CO2,gas 0.4175E-04 1.0071 0.4291E-04 0.4261E-04 CH4,gas 0.1448E-04 1.0125 0.1496E-04 0.1478E-04 H2,gas 0.2381E-03 1.0005 0.2431E-03 0.2430E-03 H2S,gas 0.9075E-05 0.9960 0.9226E-05 0.9262E-05 S2,gas 0.5297E-22 1.0000 0.5406E-22 0.5406E-22 CO,gas 0.2724E-11 1.0000 0.2780E-11 0.2780E-11 SO3,gas 0.7215E-39 1.0000 0.7364E-39 0.7364E-39 SO2,gas 0.6824E-20 1.0000 0.6965E-20 0.6965E-20 HF,gas 0.3494E-13 1.0000 0.3566E-13 0.3566E-13 HCl,gas 0.1535E-16 1.0000 0.1567E-16 0.1567E-16 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 17 albite -0.38 -0.38 0.00 0.000 0.11184E-10 150 quartz -2.99 -2.99 0.00 0.000 0.00000E+00 167 stilpnomelane-Fe 13.02 13.02 0.00 0.000 -0.27298E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -12.73 -6.07 -2.022 0.10358E+05 -4.367 3 CH4,gas 4.54 -1.98 -6.52 -1.631 0.11139E+05 -4.825 4 H2,gas 8.00 2.69 -5.31 -3.036 0.90721E+04 -3.614 5 H2S,gas -6.23 -12.96 -6.73 -3.367 0.11498E+05 -5.035 6 S2,gas -7.34 -31.30 -23.97 -3.687 0.40921E+05 -22.267 7 CO,gas 3.21 -10.04 -13.25 -4.078 0.22632E+05 -11.556 8 SO3,gas 17.12 -23.71 -40.83 -10.208 0.69719E+05 -39.133 9 SO2,gas 0.83 -21.02 -21.86 -5.828 0.37319E+05 -20.157 10 HF,gas 0.47 -14.67 -15.15 -7.573 0.25863E+05 -13.448 11 HCl,gas 5.19 -13.31 -18.50 -9.252 0.31595E+05 -16.805 12 acmite 7.71 7.36 -0.35 -0.036 0.59909E+03 16 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 20 spessartine 24.46 19.57 -4.89 -0.244 0.83434E+04 21 analcite 3.32 2.61 -0.72 -0.080 0.12231E+04 23 andradite 39.01 37.38 -1.63 -0.085 0.27867E+04 24 grossular 32.73 27.87 -4.86 -0.243 0.83005E+04 26 ankerite -2.14 -6.91 -4.78 -0.796 0.81567E+04 27 annite 20.12 17.28 -2.85 -0.158 0.48612E+04 28 phlogopite 27.06 23.80 -3.26 -0.181 0.55710E+04 33 apatite-OH -18.15 -22.34 -4.19 -0.322 0.71567E+04 34 apatite-F -34.30 -37.02 -2.72 -0.226 0.46397E+04 38 aragonite 0.97 -0.78 -1.74 -0.581 0.29764E+04 39 brucite 12.57 8.77 -3.80 -0.760 0.64925E+04 40 calcite 0.81 -0.78 -1.59 -0.529 0.27122E+04 41 carnegieite-low 9.02 5.60 -3.43 -0.490 0.58537E+04 42 carnegieite-high 10.09 5.60 -4.50 -0.643 0.76807E+04 43 carpholite-Mg 8.58 3.78 -4.81 -0.320 0.82060E+04 45 celadonite 5.34 3.28 -2.06 -0.121 0.35199E+04 46 celadonite-Fe 3.88 1.10 -2.77 -0.163 0.47323E+04 47 chrysotile 23.89 20.32 -3.57 -0.298 0.61005E+04 49 clinochlore 39.07 35.85 -3.22 -0.101 0.54950E+04 50 daphnite 28.97 24.98 -3.99 -0.125 0.68124E+04 54 chloritoid-Fe 9.17 4.59 -4.58 -0.306 0.78257E+04 55 chloritoid-Mn 11.40 7.18 -4.22 -0.281 0.72025E+04 57 coesite -2.38 -2.99 -0.61 -0.204 0.10473E+04 64 cristobalite -2.56 -2.99 -0.43 -0.143 0.73267E+03 66 cymrite-K 1.69 -2.50 -4.18 -0.348 0.71406E+04 68 diaspore 2.87 0.49 -2.38 -0.397 0.40625E+04 69 diamond -3.10 -7.35 -4.25 -1.215 0.72584E+04 70 diopside 16.18 14.74 -1.44 -0.144 0.24659E+04 71 hedenbergite 14.21 12.56 -1.65 -0.165 0.28110E+04 78 epidote 24.67 21.17 -3.50 -0.170 0.59795E+04 80 epidote-Fe 29.84 25.92 -3.92 -0.204 0.66925E+04 81 fayalite 14.05 10.19 -3.85 -0.550 0.65792E+04 82 ferrosilite 11.15 7.20 -3.95 -0.395 0.67383E+04 86 gibbsite 4.08 0.49 -3.58 -0.512 0.61211E+04 87 glaucophane 22.97 19.55 -3.42 -0.093 0.58446E+04 88 glaucophane-Fe 17.28 13.03 -4.25 -0.115 0.72558E+04 89 graphite -3.55 -7.35 -3.81 -1.088 0.65007E+04 90 greenalite 16.14 13.79 -2.35 -0.195 0.40047E+04 93 hematite 12.57 10.50 -2.07 -0.251 0.35358E+04 94 heulandite -5.83 -7.99 -2.16 -0.098 0.36883E+04 98 jadeite 4.22 2.61 -1.61 -0.161 0.27485E+04 100 kalsilite 7.58 3.48 -4.10 -0.586 0.70034E+04 101 kaolinite -1.33 -4.99 -3.66 -0.332 0.62447E+04 104 laumontite 2.88 0.98 -1.90 -0.127 0.32484E+04 105 lawsonite 9.62 6.96 -2.66 -0.177 0.45354E+04 106 leucite 4.12 0.49 -3.63 -0.363 0.61913E+04 108 lizardite 23.24 20.32 -2.92 -0.244 0.49931E+04 109 magnesite 0.69 -3.96 -4.65 -1.550 0.79414E+04 110 magnetite 20.09 17.09 -3.00 -0.245 0.51241E+04 111 minnesotaite 10.39 7.82 -2.57 -0.151 0.43931E+04 115 manganosite 14.06 9.18 -4.87 -1.219 0.83233E+04 119 microcline -2.49 -2.50 -0.01 -0.001 0.17223E+02 123 muscovite 2.58 -1.51 -4.09 -0.241 0.69838E+04 124 paragonite 4.24 0.60 -3.63 -0.214 0.62057E+04 125 nepheline 8.34 5.60 -2.74 -0.392 0.46861E+04 137 phlogopite-Na 29.65 25.91 -3.73 -0.207 0.63726E+04 139 prehnite 19.37 15.92 -3.45 -0.203 0.58935E+04 140 prehnite-Fe 22.50 20.67 -1.82 -0.110 0.31149E+04 145 pyrite -21.25 -22.02 -0.78 -0.183 0.13268E+04 146 pyrrhotite -4.26 -6.37 -2.11 -0.704 0.36077E+04 147 pyrrhotiteFe0.875 -6.02 -7.53 -1.51 -0.557 0.25839E+04 148 pyroxmangite 7.40 6.19 -1.20 -0.241 0.20569E+04 149 pyrophyllite -6.18 -10.97 -4.79 -0.300 0.81841E+04 154 rhodochrosite -0.98 -3.54 -2.57 -0.856 0.43826E+04 155 rhodonite 7.45 6.19 -1.25 -0.250 0.21372E+04 156 sanidine -1.28 -2.50 -1.22 -0.094 0.20850E+04 158 siderite -2.61 -6.14 -3.53 -1.176 0.60229E+04 166 stilbite -7.52 -7.99 -0.47 -0.022 0.79445E+03 168 stilpnomelane-Mg 27.44 23.89 -3.55 -0.106 0.60592E+04 174 talc 16.49 14.34 -2.15 -0.126 0.36717E+04 177 tephroite 18.09 15.38 -2.71 -0.387 0.46243E+04 181 tridymite -2.63 -2.99 -0.36 -0.121 0.61998E+03 182 tremolite 47.87 43.82 -4.05 -0.110 0.69225E+04 184 troilite-low -4.41 -6.37 -1.96 -0.654 0.33505E+04 190 wairakite 3.95 0.98 -2.97 -0.175 0.50703E+04 191 walstromite 11.51 8.96 -2.55 -0.510 0.43520E+04 192 wollastonite 10.46 8.96 -1.50 -0.300 0.25624E+04 193 pseudo-wollastonite 11.00 8.96 -2.04 -0.408 0.34823E+04 195 akaganeite 7.75 5.25 -2.51 -0.542 0.42804E+04 202 chalcedony -2.80 -2.99 -0.19 -0.062 0.31930E+03 204 montmorillonite-Ca -2.29 -6.27 -3.98 -0.246 0.67902E+04 205 montmorillonite-K -2.24 -6.27 -4.03 -0.247 0.68811E+04 206 montmorillonite-Mg -2.48 -6.79 -4.31 -0.267 0.73642E+04 207 montmorillonite-Na -2.04 -5.57 -3.53 -0.216 0.60303E+04 208 nontronite-Ca 3.21 1.66 -1.56 -0.101 0.26559E+04 209 nontronite-H 2.53 -0.31 -2.85 -0.191 0.48584E+04 210 nontronite-K 3.34 1.66 -1.68 -0.108 0.28700E+04 211 nontronite-Mg 3.07 1.13 -1.94 -0.126 0.33140E+04 212 nontronite-Na 3.52 2.36 -1.16 -0.075 0.19852E+04 228 tobermorite 9.82 6.96 -2.86 -0.780 0.48804E+04 234 alabandite -0.98 -3.78 -2.80 -0.934 0.47858E+04 237 boehmite 4.41 0.49 -3.91 -0.652 0.66795E+04 239 ferrous-oxide 9.81 6.59 -3.22 -0.805 0.54991E+04 245 silica-amorphous -2.09 -2.99 -0.90 -0.299 0.15335E+04 247 an20ab80 2.02 1.08 -0.93 -0.072 0.15929E+04 248 an25ab75 2.65 1.45 -1.19 -0.092 0.20381E+04 249 an30ab70 3.28 1.82 -1.46 -0.112 0.24929E+04 250 tr.625ac.25prg.125 45.16 41.94 -3.22 -0.087 0.54988E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 0.0020000 MOLES Current total amount of reactant added: 0.0419900 MOLES New total amount of reactant added: 0.0439900 MOLES Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.5508E-08 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 7 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 0.0439900 Water: Moles liquid = 0.4989E+02 kg liquid = 0.8988E+00 Moles total = 0.4988E+02 kg total = 0.8986E+00 Activity = 1.0000 Stoichiometric ionic strength = .1417165E-01 Osmotic coef. = 0.9322 True ionic strength = .2254065E-01 Chg. balance for total moles = -.5508E-08 Max. difference allowed = 0.3974E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.16753E-09 -9.7759 0.13972E-09 -9.8547 0.83404E+00 -0.0788 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.44013E-03 -3.3564 0.36467E-03 -3.4381 0.82854E+00 -0.0817 4 SO4-- 0.21682E-03 -3.6639 0.10911E-03 -3.9621 0.50323E+00 -0.2982 5 HCO3- 0.17471E-02 -2.7577 0.14499E-02 -2.8387 0.82987E+00 -0.0810 6 HS- 0.10002E-02 -2.9999 0.82887E-03 -3.0815 0.82868E+00 -0.0816 7 Al+++ 0.40379E-28 -28.3938 0.86791E-29 -29.0615 0.21494E+00 -0.6677 8 H4SiO4 0.10246E-02 -2.9894 0.10246E-02 -2.9894 0.10000E+01 0.0000 9 Ca++ 0.32545E-07 -7.4875 0.16246E-07 -7.7893 0.49917E+00 -0.3018 10 Mg++ 0.21944E-10 -10.6587 0.10899E-10 -10.9626 0.49666E+00 -0.3039 11 Fe++ 0.15225E-12 -12.8174 0.75707E-13 -13.1209 0.49726E+00 -0.3034 12 K+ 0.15646E-03 -3.8056 0.12988E-03 -3.8865 0.83009E+00 -0.0809 13 Na+ 0.20362E-01 -1.6912 0.16867E-01 -1.7730 0.82838E+00 -0.0818 14 Mn++ 0.59457E-10 -10.2258 0.29592E-10 -10.5288 0.49771E+00 -0.3030 15 F- 0.19624E-04 -4.7072 0.16223E-04 -4.7899 0.82668E+00 -0.0827 16 HPO4-- 0.45718E-07 -7.3399 0.23010E-07 -7.6381 0.50331E+00 -0.2982 18 HSiO3- 0.82643E-02 -2.0828 0.68473E-02 -2.1645 0.82854E+00 -0.0817 19 Ca(HSiO3)+ 0.30512E-08 -8.5155 0.25333E-08 -8.5963 0.83028E+00 -0.0808 20 Mg(HSiO3)+ 0.25475E-11 -11.5939 0.21151E-11 -11.6747 0.83028E+00 -0.0808 21 NaHSiO3,aq 0.18680E-02 -2.7286 0.18680E-02 -2.7286 0.10000E+01 0.0000 22 AlO+ 0.72842E-16 -16.1376 0.60480E-16 -16.2184 0.83028E+00 -0.0808 24 HAlO2,aq 0.86202E-10 -10.0645 0.86202E-10 -10.0645 0.10000E+01 0.0000 25 AlO2- 0.16515E-05 -5.7821 0.13657E-05 -5.8647 0.82691E+00 -0.0825 26 CH4,aq 0.10745E-07 -7.9688 0.10699E-07 -7.9706 0.99570E+00 -0.0019 27 C2H6,aq 0.10682E-18 -18.9714 0.10636E-18 -18.9732 0.99570E+00 -0.0019 31 CO,aq 0.20009E-14 -14.6988 0.20009E-14 -14.6988 0.10000E+01 0.0000 32 CO2,aq 0.43475E-06 -6.3618 0.43288E-06 -6.3636 0.99570E+00 -0.0019 33 CO3-2 0.18053E-02 -2.7434 0.90638E-03 -3.0427 0.50206E+00 -0.2992 34 CaCO3,aq 0.18463E-06 -6.7337 0.18463E-06 -6.7337 0.10000E+01 0.0000 35 Ca(HCO3)+ 0.72415E-09 -9.1402 0.60125E-09 -9.2209 0.83028E+00 -0.0808 36 CaCl+ 0.11547E-10 -10.9375 0.95873E-11 -11.0183 0.83028E+00 -0.0808 37 CaCl2,aq 0.83061E-15 -15.0806 0.83061E-15 -15.0806 0.10000E+01 0.0000 38 CaF+ 0.46344E-11 -11.3340 0.38479E-11 -11.4148 0.83028E+00 -0.0808 39 CaOH+ 0.99802E-08 -8.0009 0.82864E-08 -8.0816 0.83028E+00 -0.0808 40 CaSO4,aq 0.56287E-09 -9.2496 0.56287E-09 -9.2496 0.10000E+01 0.0000 41 HCl,aq 0.93369E-14 -14.0298 0.93369E-14 -14.0298 0.10000E+01 0.0000 45 HF,aq 0.15517E-10 -10.8092 0.15517E-10 -10.8092 0.10000E+01 0.0000 46 HF2- 0.10258E-15 -15.9889 0.84992E-16 -16.0706 0.82854E+00 -0.0817 48 FeCl+ 0.52631E-16 -16.2788 0.43699E-16 -16.3595 0.83028E+00 -0.0808 51 FeF+ 0.75592E-16 -16.1215 0.62763E-16 -16.2023 0.83028E+00 -0.0808 53 FeO,aq 0.15072E-09 -9.8218 0.15072E-09 -9.8218 0.10000E+01 0.0000 54 FeOH+ 0.21243E-10 -10.6728 0.17637E-10 -10.7536 0.83028E+00 -0.0808 55 HFeO2- 0.13622E-07 -7.8658 0.11286E-07 -7.9474 0.82854E+00 -0.0817 56 FeO+ 0.11812E-15 -15.9277 0.98072E-16 -16.0085 0.83028E+00 -0.0808 58 FeO2- 0.12406E-08 -8.9064 0.10279E-08 -8.9880 0.82854E+00 -0.0817 59 HFeO2,aq 0.18267E-10 -10.7383 0.18267E-10 -10.7383 0.10000E+01 0.0000 60 H2,aq 0.18480E-06 -6.7333 0.18400E-06 -6.7352 0.99570E+00 -0.0019 61 KCl,aq 0.85841E-09 -9.0663 0.85841E-09 -9.0663 0.10000E+01 0.0000 62 KHSO4,aq 0.55983E-17 -17.2519 0.55983E-17 -17.2519 0.10000E+01 0.0000 63 KOH,aq 0.39697E-06 -6.4012 0.39697E-06 -6.4012 0.10000E+01 0.0000 64 KSO4- 0.26541E-06 -6.5761 0.21990E-06 -6.6578 0.82854E+00 -0.0817 65 MgCO3,aq 0.31048E-10 -10.5080 0.31048E-10 -10.5080 0.10000E+01 0.0000 66 Mg(HCO3)+ 0.49642E-12 -12.3041 0.41217E-12 -12.3849 0.83028E+00 -0.0808 67 MgCl+ 0.70212E-14 -14.1536 0.58296E-14 -14.2344 0.83028E+00 -0.0808 68 MgF+ 0.11517E-13 -13.9387 0.95626E-14 -14.0194 0.83028E+00 -0.0808 69 MgOH+ 0.37050E-10 -10.4312 0.30762E-10 -10.5120 0.83028E+00 -0.0808 71 MnF+ 0.97390E-14 -14.0115 0.80862E-14 -14.0923 0.83028E+00 -0.0808 72 MnO,aq 0.15698E-08 -8.8042 0.15698E-08 -8.8042 0.10000E+01 0.0000 73 MnOH+ 0.77134E-09 -9.1128 0.64043E-09 -9.1935 0.83028E+00 -0.0808 74 MnO2-2 0.53150E-11 -11.2745 0.26685E-11 -11.5737 0.50206E+00 -0.2992 75 HMnO2- 0.98588E-10 -10.0062 0.81685E-10 -10.0879 0.82854E+00 -0.0817 78 MnCl+ 0.80036E-13 -13.0967 0.66453E-13 -13.1775 0.83028E+00 -0.0808 79 MnSO4,aq 0.93213E-12 -12.0305 0.93213E-12 -12.0305 0.10000E+01 0.0000 80 NaCl,aq 0.20384E-05 -5.6907 0.20384E-05 -5.6907 0.10000E+01 0.0000 81 NaF,aq 0.64063E-07 -7.1934 0.64063E-07 -7.1934 0.10000E+01 0.0000 82 NaOH,aq 0.51867E-04 -4.2851 0.51867E-04 -4.2851 0.10000E+01 0.0000 84 OH- 0.50007E-02 -2.3010 0.41351E-02 -2.3835 0.82691E+00 -0.0825 89 HPO3-2 0.26280E-16 -16.5804 0.13194E-16 -16.8796 0.50206E+00 -0.2992 92 H3PO4,aq 0.31418E-17 -17.5028 0.31418E-17 -17.5028 0.10000E+01 0.0000 93 H2PO4- 0.71508E-10 -10.1456 0.59309E-10 -10.2269 0.82941E+00 -0.0812 94 PO4-3 0.59236E-09 -9.2274 0.13436E-09 -9.8717 0.22683E+00 -0.6443 98 HP2O7-3 0.18317E-17 -17.7371 0.39416E-18 -18.4043 0.21518E+00 -0.6672 99 P2O7-4 0.99093E-17 -17.0040 0.67392E-18 -18.1714 0.68009E-01 -1.1674 100 H2S,aq 0.35948E-06 -6.4443 0.35794E-06 -6.4462 0.99570E+00 -0.0019 101 S2-2 0.16479E-09 -9.7831 0.82734E-10 -10.0823 0.50206E+00 -0.2992 102 S3-2 0.43189E-15 -15.3646 0.21683E-15 -15.6639 0.50206E+00 -0.2992 103 S3- 0.57141E-19 -19.2431 0.47344E-19 -19.3247 0.82854E+00 -0.0817 107 SO3-2 0.51153E-11 -11.2911 0.26089E-11 -11.5835 0.51002E+00 -0.2924 108 HSO3- 0.27547E-13 -13.5599 0.22824E-13 -13.6416 0.82854E+00 -0.0817 109 HSO4- 0.17676E-10 -10.7526 0.14692E-10 -10.8329 0.83117E+00 -0.0803 111 S2O3-2 0.91377E-12 -12.0392 0.45876E-12 -12.3384 0.50206E+00 -0.2992 112 HS2O3- 0.13833E-19 -19.8591 0.11461E-19 -19.9408 0.82854E+00 -0.0817 Charge balance for all species = -.6128E-08 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.1675260E-09 -.1699666E-01 -.1710139E+02 0.0000 2 H2O 0.1000000E+01 0.5550317E+02 0.9981428E+06 0.0000 3 Cl- 0.4401301E-03 0.4421694E-03 0.1564858E+02 6.4166 4 SO4-- 0.2168196E-03 0.2170289E-03 0.2081137E+02 15.7473 5 HCO3- 0.1747131E-02 0.3553094E-02 0.2164174E+03 7.0161 6 HS- 0.1000236E-02 0.1000653E-02 0.3303522E+02 6.7732 7 Al+++ 0.4037950E-28 0.1651608E-05 0.4448427E-01 0.5027 8 H4SiO4 0.1024625E-02 0.1115689E-01 0.1070457E+04 -2.9894 9 Ca++ 0.3254519E-07 0.2315107E-06 0.9262119E-02 11.9202 10 Mg++ 0.2194425E-10 0.9310479E-10 0.2259571E-05 8.7468 11 Fe++ 0.1522488E-12 0.1505286E-07 0.8391743E-03 6.5886 12 K+ 0.1564644E-03 0.1571276E-03 0.6133169E+01 5.9683 13 Na+ 0.2036187E-01 0.2228382E-01 0.5113971E+03 8.0818 14 Mn++ 0.5945658E-10 0.2505474E-08 0.1374030E-03 9.1806 15 F- 0.1962423E-04 0.1968831E-04 0.3733788E+00 5.0649 16 HPO4-- 0.4571780E-07 0.4638167E-07 0.4443815E-02 12.0714 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.1528992E-01 -.1527672E-01 -.1319590E-04 0.0000000E+00 2 H2O 0.4988242E+02 0.4988667E+02 -.4243633E-02 0.0000000E+00 3 Cl- 0.3974252E-03 0.3974252E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.1950672E-03 0.1950672E-03 0.0000000E+00 0.0000000E+00 5 HCO3- 0.3193547E-02 0.3193547E-02 0.0000000E+00 0.0000000E+00 6 HS- 0.8993943E-03 0.8993943E-03 0.0000000E+00 0.0000000E+00 7 Al+++ 0.4775352E-05 0.1484478E-05 0.3290874E-05 0.0000000E+00 8 H4SiO4 0.1215302E-01 0.1002789E-01 0.2125128E-02 0.0000000E+00 9 Ca++ 0.2080835E-06 0.2080835E-06 0.0000000E+00 0.0000000E+00 10 Mg++ 0.8368328E-10 0.8368328E-10 0.0000000E+00 0.0000000E+00 11 Fe++ 0.3259227E-07 0.1352962E-07 0.1906265E-07 0.0000000E+00 12 K+ 0.1412294E-03 0.1412275E-03 0.1906265E-08 0.0000000E+00 13 Na+ 0.2003215E-01 0.2002887E-01 0.3283249E-05 0.0000000E+00 14 Mn++ 0.2251939E-08 0.2251939E-08 0.0000000E+00 0.0000000E+00 15 F- 0.1769600E-04 0.1769600E-04 0.0000000E+00 0.0000000E+00 16 HPO4-- 0.4168819E-07 0.4168819E-07 0.0000000E+00 0.0000000E+00 Chg. balance for solid moles: -.4235E-21 Mass of aqueous solution: 0.900396E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 0.0439900 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 0.3283E-05 -5.484 0.8609E-03 -3.065 0.6729 0.3305E-03 quartz 0.2115E-02 -2.675 0.1271 -0.896 99.32 0.4799E-01 stilpnomelane-Fe 0.3813E-08 -8.419 0.4110E-05 -5.386 0.3212E-02 0.1420E-05 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 quartz 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 0.127949 g Volume = 0.048324 cm3 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.0439900 moles log = -1.3566 Original solution: 1000.0103000 g Original solution / Rock added: 22732.67 (Water/Rock Ratio), log = 4.3567 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0206 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9997E+00 0.9859 0.1006E+01 0.1020E+01 CO2,gas 0.4506E-04 1.0071 0.4631E-04 0.4599E-04 CH4,gas 0.1524E-04 1.0125 0.1575E-04 0.1555E-04 H2,gas 0.2366E-03 1.0005 0.2416E-03 0.2414E-03 H2S,gas 0.9679E-05 0.9960 0.9839E-05 0.9879E-05 S2,gas 0.6101E-22 1.0000 0.6227E-22 0.6227E-22 CO,gas 0.2921E-11 1.0000 0.2982E-11 0.2982E-11 SO3,gas 0.7891E-39 1.0000 0.8054E-39 0.8054E-39 SO2,gas 0.7417E-20 1.0000 0.7570E-20 0.7570E-20 HF,gas 0.3733E-13 1.0000 0.3810E-13 0.3810E-13 HCl,gas 0.1614E-16 1.0000 0.1648E-16 0.1648E-16 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 17 albite -0.38 -0.38 0.00 0.000 0.11184E-10 150 quartz -2.99 -2.99 0.00 0.000 0.00000E+00 167 stilpnomelane-Fe 13.02 13.02 0.00 0.000 0.21232E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -12.69 -6.03 -2.011 0.10302E+05 -4.334 3 CH4,gas 4.54 -1.96 -6.50 -1.625 0.11102E+05 -4.803 4 H2,gas 8.00 2.68 -5.32 -3.038 0.90768E+04 -3.617 5 H2S,gas -6.23 -12.94 -6.71 -3.353 0.11450E+05 -5.007 6 S2,gas -7.34 -31.24 -23.90 -3.678 0.40817E+05 -22.206 7 CO,gas 3.21 -10.01 -13.22 -4.069 0.22580E+05 -11.526 8 SO3,gas 17.12 -23.67 -40.79 -10.198 0.69653E+05 -39.094 9 SO2,gas 0.83 -20.99 -21.82 -5.819 0.37257E+05 -20.121 10 HF,gas 0.47 -14.64 -15.12 -7.559 0.25814E+05 -13.419 11 HCl,gas 5.19 -13.29 -18.48 -9.241 0.31558E+05 -16.783 12 acmite 7.71 7.35 -0.36 -0.037 0.61491E+03 16 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 20 spessartine 24.46 19.58 -4.88 -0.244 0.83297E+04 21 analcite 3.32 2.61 -0.72 -0.080 0.12231E+04 23 andradite 39.01 37.29 -1.72 -0.090 0.29422E+04 24 grossular 32.73 27.80 -4.93 -0.247 0.84244E+04 26 ankerite -2.14 -6.88 -4.74 -0.790 0.80984E+04 27 annite 20.12 17.27 -2.85 -0.159 0.48748E+04 28 phlogopite 27.06 23.74 -3.32 -0.185 0.56713E+04 33 apatite-OH -18.15 -22.44 -4.29 -0.330 0.73219E+04 34 apatite-F -34.30 -37.09 -2.79 -0.232 0.47558E+04 38 aragonite 0.97 -0.77 -1.74 -0.580 0.29705E+04 39 brucite 12.57 8.75 -3.82 -0.764 0.65255E+04 40 calcite 0.81 -0.77 -1.58 -0.528 0.27063E+04 41 carnegieite-low 9.02 5.60 -3.43 -0.490 0.58537E+04 42 carnegieite-high 10.09 5.60 -4.50 -0.643 0.76807E+04 43 carpholite-Mg 8.58 3.77 -4.81 -0.321 0.82109E+04 45 celadonite 5.34 3.26 -2.08 -0.122 0.35542E+04 46 celadonite-Fe 3.88 1.10 -2.77 -0.163 0.47378E+04 47 chrysotile 23.89 20.26 -3.63 -0.303 0.61994E+04 49 clinochlore 39.07 35.77 -3.30 -0.103 0.56317E+04 50 daphnite 28.97 24.98 -3.99 -0.125 0.68047E+04 54 chloritoid-Fe 9.17 4.60 -4.57 -0.305 0.78017E+04 55 chloritoid-Mn 11.40 7.20 -4.20 -0.280 0.71791E+04 57 coesite -2.38 -2.99 -0.61 -0.204 0.10473E+04 64 cristobalite -2.56 -2.99 -0.43 -0.143 0.73267E+03 66 cymrite-K 1.69 -2.50 -4.18 -0.349 0.71420E+04 68 diaspore 2.87 0.50 -2.37 -0.395 0.40485E+04 69 diamond -3.10 -7.33 -4.22 -1.207 0.72112E+04 70 diopside 16.18 14.69 -1.49 -0.149 0.25496E+04 71 hedenbergite 14.21 12.53 -1.68 -0.168 0.28657E+04 78 epidote 24.67 21.12 -3.55 -0.172 0.60544E+04 80 epidote-Fe 29.84 25.87 -3.97 -0.206 0.67833E+04 81 fayalite 14.05 10.19 -3.86 -0.551 0.65874E+04 82 ferrosilite 11.15 7.20 -3.95 -0.395 0.67464E+04 86 gibbsite 4.08 0.50 -3.58 -0.511 0.61070E+04 87 glaucophane 22.97 19.49 -3.48 -0.094 0.59435E+04 88 glaucophane-Fe 17.28 13.02 -4.26 -0.115 0.72681E+04 89 graphite -3.55 -7.33 -3.78 -1.080 0.64535E+04 90 greenalite 16.14 13.79 -2.35 -0.196 0.40170E+04 93 hematite 12.57 10.49 -2.07 -0.251 0.35393E+04 94 heulandite -5.83 -8.00 -2.17 -0.099 0.37108E+04 98 jadeite 4.22 2.61 -1.61 -0.161 0.27485E+04 100 kalsilite 7.58 3.48 -4.10 -0.586 0.70048E+04 101 kaolinite -1.33 -4.97 -3.64 -0.331 0.62165E+04 104 laumontite 2.88 0.97 -1.92 -0.128 0.32709E+04 105 lawsonite 9.62 6.95 -2.67 -0.178 0.45580E+04 106 leucite 4.12 0.49 -3.63 -0.363 0.61927E+04 108 lizardite 23.24 20.26 -2.98 -0.249 0.50920E+04 109 magnesite 0.69 -3.95 -4.64 -1.546 0.79178E+04 110 magnetite 20.09 17.08 -3.01 -0.245 0.51317E+04 111 minnesotaite 10.39 7.81 -2.58 -0.152 0.44054E+04 115 manganosite 14.06 9.18 -4.88 -1.219 0.83282E+04 119 microcline -2.49 -2.50 -0.01 -0.001 0.18573E+02 123 muscovite 2.58 -1.49 -4.07 -0.240 0.69571E+04 124 paragonite 4.24 0.62 -3.62 -0.213 0.61776E+04 125 nepheline 8.34 5.60 -2.74 -0.392 0.46861E+04 137 phlogopite-Na 29.65 25.86 -3.79 -0.211 0.64715E+04 139 prehnite 19.37 15.88 -3.49 -0.206 0.59667E+04 140 prehnite-Fe 22.50 20.62 -1.88 -0.113 0.32040E+04 145 pyrite -21.25 -21.97 -0.72 -0.170 0.12307E+04 146 pyrrhotite -4.26 -6.35 -2.09 -0.696 0.35640E+04 147 pyrrhotiteFe0.875 -6.02 -7.50 -1.49 -0.547 0.25391E+04 148 pyroxmangite 7.40 6.19 -1.21 -0.241 0.20617E+04 149 pyrophyllite -6.18 -10.95 -4.78 -0.299 0.81559E+04 154 rhodochrosite -0.98 -3.51 -2.54 -0.845 0.43309E+04 155 rhodonite 7.45 6.19 -1.25 -0.251 0.21420E+04 156 sanidine -1.28 -2.50 -1.22 -0.094 0.20863E+04 158 siderite -2.61 -6.10 -3.50 -1.166 0.59704E+04 166 stilbite -7.52 -8.00 -0.48 -0.023 0.81698E+03 168 stilpnomelane-Mg 27.44 23.81 -3.63 -0.108 0.62036E+04 174 talc 16.49 14.28 -2.21 -0.130 0.37706E+04 177 tephroite 18.09 15.37 -2.71 -0.388 0.46340E+04 181 tridymite -2.63 -2.99 -0.36 -0.121 0.61998E+03 182 tremolite 47.87 43.66 -4.21 -0.114 0.71887E+04 184 troilite-low -4.41 -6.35 -1.94 -0.646 0.33069E+04 190 wairakite 3.95 0.97 -2.98 -0.175 0.50928E+04 191 walstromite 11.51 8.93 -2.58 -0.516 0.44027E+04 192 wollastonite 10.46 8.93 -1.53 -0.306 0.26131E+04 193 pseudo-wollastonite 11.00 8.93 -2.07 -0.414 0.35329E+04 195 akaganeite 7.75 5.25 -2.51 -0.542 0.42822E+04 202 chalcedony -2.80 -2.99 -0.19 -0.062 0.31930E+03 204 montmorillonite-Ca -2.29 -6.27 -3.97 -0.246 0.67860E+04 205 montmorillonite-K -2.24 -6.26 -4.03 -0.247 0.68736E+04 206 montmorillonite-Mg -2.48 -6.79 -4.31 -0.267 0.73570E+04 207 montmorillonite-Na -2.04 -5.56 -3.53 -0.216 0.60223E+04 208 nontronite-Ca 3.21 1.65 -1.56 -0.101 0.26631E+04 209 nontronite-H 2.53 -0.31 -2.84 -0.191 0.48572E+04 210 nontronite-K 3.34 1.66 -1.68 -0.108 0.28740E+04 211 nontronite-Mg 3.07 1.13 -1.94 -0.126 0.33183E+04 212 nontronite-Na 3.52 2.35 -1.16 -0.075 0.19887E+04 228 tobermorite 9.82 6.94 -2.88 -0.787 0.49226E+04 234 alabandite -0.98 -3.76 -2.78 -0.926 0.47429E+04 237 boehmite 4.41 0.50 -3.90 -0.651 0.66654E+04 239 ferrous-oxide 9.81 6.59 -3.22 -0.806 0.55032E+04 245 silica-amorphous -2.09 -2.99 -0.90 -0.299 0.15335E+04 247 an20ab80 2.02 1.08 -0.94 -0.072 0.15974E+04 248 an25ab75 2.65 1.45 -1.20 -0.092 0.20437E+04 249 an30ab70 3.28 1.82 -1.46 -0.113 0.24997E+04 250 tr.625ac.25prg.125 45.16 41.81 -3.35 -0.090 0.57212E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 0.0020000 MOLES Current total amount of reactant added: 0.0439900 MOLES New total amount of reactant added: 0.0459900 MOLES Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.5508E-08 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 7 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 0.0459900 Water: Moles liquid = 0.4989E+02 kg liquid = 0.8988E+00 Moles total = 0.4988E+02 kg total = 0.8987E+00 Activity = 1.0000 Stoichiometric ionic strength = .1430151E-01 Osmotic coef. = 0.9318 True ionic strength = .2265033E-01 Chg. balance for total moles = -.5508E-08 Max. difference allowed = 0.4092E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.17108E-09 -9.7668 0.14264E-09 -9.8458 0.83379E+00 -0.0789 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.45318E-03 -3.3437 0.37535E-03 -3.4256 0.82827E+00 -0.0818 4 SO4-- 0.22742E-03 -3.6432 0.11430E-03 -3.9420 0.50257E+00 -0.2988 5 HCO3- 0.18444E-02 -2.7341 0.15301E-02 -2.8153 0.82960E+00 -0.0811 6 HS- 0.10436E-02 -2.9815 0.86454E-03 -3.0632 0.82840E+00 -0.0818 7 Al+++ 0.43930E-28 -28.3572 0.94138E-29 -29.0262 0.21429E+00 -0.6690 8 H4SiO4 0.10246E-02 -2.9894 0.10246E-02 -2.9894 0.10000E+01 0.0000 9 Ca++ 0.31754E-07 -7.4982 0.15829E-07 -7.8005 0.49850E+00 -0.3023 10 Mg++ 0.21901E-10 -10.6595 0.10862E-10 -10.9641 0.49599E+00 -0.3045 11 Fe++ 0.15800E-12 -12.8013 0.78462E-13 -13.1053 0.49659E+00 -0.3040 12 K+ 0.15645E-03 -3.8056 0.12983E-03 -3.8866 0.82982E+00 -0.0810 13 Na+ 0.20398E-01 -1.6904 0.16891E-01 -1.7723 0.82810E+00 -0.0819 14 Mn++ 0.61633E-10 -10.2102 0.30634E-10 -10.5138 0.49704E+00 -0.3036 15 F- 0.20511E-04 -4.6880 0.16950E-04 -4.7708 0.82639E+00 -0.0828 16 HPO4-- 0.45726E-07 -7.3398 0.22984E-07 -7.6386 0.50265E+00 -0.2987 18 HSiO3- 0.80979E-02 -2.0916 0.67073E-02 -2.1735 0.82827E+00 -0.0818 19 Ca(HSiO3)+ 0.29131E-08 -8.5356 0.24179E-08 -8.6166 0.83001E+00 -0.0809 20 Mg(HSiO3)+ 0.24878E-11 -11.6042 0.20649E-11 -11.6851 0.83001E+00 -0.0809 21 NaHSiO3,aq 0.18324E-02 -2.7370 0.18324E-02 -2.7370 0.10000E+01 0.0000 22 AlO+ 0.75834E-16 -16.1201 0.62943E-16 -16.2011 0.83001E+00 -0.0809 24 HAlO2,aq 0.87877E-10 -10.0561 0.87877E-10 -10.0561 0.10000E+01 0.0000 25 AlO2- 0.16497E-05 -5.7826 0.13637E-05 -5.8653 0.82662E+00 -0.0827 26 CH4,aq 0.11292E-07 -7.9472 0.11243E-07 -7.9491 0.99566E+00 -0.0019 27 C2H6,aq 0.11869E-18 -18.9256 0.11817E-18 -18.9275 0.99566E+00 -0.0019 31 CO,aq 0.21423E-14 -14.6691 0.21423E-14 -14.6691 0.10000E+01 0.0000 32 CO2,aq 0.46841E-06 -6.3294 0.46637E-06 -6.3313 0.99566E+00 -0.0019 33 CO3-2 0.18687E-02 -2.7285 0.93698E-03 -3.0283 0.50139E+00 -0.2998 34 CaCO3,aq 0.18597E-06 -6.7306 0.18597E-06 -6.7306 0.10000E+01 0.0000 35 Ca(HCO3)+ 0.74488E-09 -9.1279 0.61826E-09 -9.2088 0.83001E+00 -0.0809 36 CaCl+ 0.11584E-10 -10.9361 0.96152E-11 -11.0170 0.83001E+00 -0.0809 37 CaCl2,aq 0.85745E-15 -15.0668 0.85745E-15 -15.0668 0.10000E+01 0.0000 38 CaF+ 0.47195E-11 -11.3261 0.39172E-11 -11.4070 0.83001E+00 -0.0809 39 CaOH+ 0.95286E-08 -8.0210 0.79089E-08 -8.1019 0.83001E+00 -0.0809 40 CaSO4,aq 0.57451E-09 -9.2407 0.57451E-09 -9.2407 0.10000E+01 0.0000 41 HCl,aq 0.98112E-14 -14.0083 0.98112E-14 -14.0083 0.10000E+01 0.0000 45 HF,aq 0.16551E-10 -10.7812 0.16551E-10 -10.7812 0.10000E+01 0.0000 46 HF2- 0.11436E-15 -15.9417 0.94717E-16 -16.0236 0.82827E+00 -0.0818 48 FeCl+ 0.56163E-16 -16.2505 0.46616E-16 -16.3315 0.83001E+00 -0.0809 51 FeF+ 0.81879E-16 -16.0868 0.67961E-16 -16.1677 0.83001E+00 -0.0809 53 FeO,aq 0.14988E-09 -9.8243 0.14988E-09 -9.8243 0.10000E+01 0.0000 54 FeOH+ 0.21572E-10 -10.6661 0.17905E-10 -10.7470 0.83001E+00 -0.0809 55 HFeO2- 0.13273E-07 -7.8770 0.10994E-07 -7.9589 0.82827E+00 -0.0818 56 FeO+ 0.12033E-15 -15.9196 0.99873E-16 -16.0006 0.83001E+00 -0.0809 58 FeO2- 0.12126E-08 -8.9163 0.10044E-08 -8.9981 0.82827E+00 -0.0818 59 HFeO2,aq 0.18222E-10 -10.7394 0.18222E-10 -10.7394 0.10000E+01 0.0000 60 H2,aq 0.18365E-06 -6.7360 0.18286E-06 -6.7379 0.99566E+00 -0.0019 61 KCl,aq 0.88322E-09 -9.0539 0.88322E-09 -9.0539 0.10000E+01 0.0000 62 KHSO4,aq 0.59845E-17 -17.2230 0.59845E-17 -17.2230 0.10000E+01 0.0000 63 KOH,aq 0.38869E-06 -6.4104 0.38869E-06 -6.4104 0.10000E+01 0.0000 64 KSO4- 0.27801E-06 -6.5559 0.23026E-06 -6.6378 0.82827E+00 -0.0818 65 MgCO3,aq 0.31989E-10 -10.4950 0.31989E-10 -10.4950 0.10000E+01 0.0000 66 Mg(HCO3)+ 0.52231E-12 -12.2821 0.43353E-12 -12.3630 0.83001E+00 -0.0809 67 MgCl+ 0.72051E-14 -14.1424 0.59803E-14 -14.2233 0.83001E+00 -0.0809 68 MgF+ 0.11997E-13 -13.9209 0.99576E-14 -14.0018 0.83001E+00 -0.0809 69 MgOH+ 0.36183E-10 -10.4415 0.30032E-10 -10.5224 0.83001E+00 -0.0809 71 MnF+ 0.10537E-13 -13.9773 0.87458E-14 -14.0582 0.83001E+00 -0.0809 72 MnO,aq 0.15592E-08 -8.8071 0.15592E-08 -8.8071 0.10000E+01 0.0000 73 MnOH+ 0.78241E-09 -9.1066 0.64941E-09 -9.1875 0.83001E+00 -0.0809 74 MnO2-2 0.50722E-11 -11.2948 0.25432E-11 -11.5946 0.50139E+00 -0.2998 75 HMnO2- 0.95955E-10 -10.0179 0.79476E-10 -10.0998 0.82827E+00 -0.0818 78 MnCl+ 0.85309E-13 -13.0690 0.70807E-13 -13.1499 0.83001E+00 -0.0809 79 MnSO4,aq 0.10108E-11 -11.9953 0.10108E-11 -11.9953 0.10000E+01 0.0000 80 NaCl,aq 0.21011E-05 -5.6775 0.21011E-05 -5.6775 0.10000E+01 0.0000 81 NaF,aq 0.67028E-07 -7.1737 0.67028E-07 -7.1737 0.10000E+01 0.0000 82 NaOH,aq 0.50878E-04 -4.2935 0.50878E-04 -4.2935 0.10000E+01 0.0000 84 OH- 0.49001E-02 -2.3098 0.40505E-02 -2.3925 0.82662E+00 -0.0827 89 HPO3-2 0.26122E-16 -16.5830 0.13097E-16 -16.8828 0.50139E+00 -0.2998 92 H3PO4,aq 0.32707E-17 -17.4854 0.32707E-17 -17.4854 0.10000E+01 0.0000 93 H2PO4- 0.72942E-10 -10.1370 0.60479E-10 -10.2184 0.82913E+00 -0.0814 94 PO4-3 0.58121E-09 -9.2357 0.13147E-09 -9.8812 0.22619E+00 -0.6455 98 HP2O7-3 0.18713E-17 -17.7278 0.40148E-18 -18.3963 0.21454E+00 -0.6685 99 P2O7-4 0.99387E-17 -17.0027 0.67239E-18 -18.1724 0.67654E-01 -1.1697 100 H2S,aq 0.38279E-06 -6.4170 0.38113E-06 -6.4189 0.99566E+00 -0.0019 101 S2-2 0.18064E-09 -9.7432 0.90571E-10 -10.0430 0.50139E+00 -0.2998 102 S3-2 0.50725E-15 -15.2948 0.25433E-15 -15.5946 0.50139E+00 -0.2998 103 S3- 0.68661E-19 -19.1633 0.56870E-19 -19.2451 0.82827E+00 -0.0818 107 SO3-2 0.53318E-11 -11.2731 0.27159E-11 -11.5661 0.50938E+00 -0.2930 108 HSO3- 0.29285E-13 -13.5333 0.24256E-13 -13.6152 0.82827E+00 -0.0818 109 HSO4- 0.18909E-10 -10.7233 0.15712E-10 -10.8038 0.83091E+00 -0.0804 111 S2O3-2 0.10206E-11 -11.9912 0.51171E-12 -12.2910 0.50139E+00 -0.2998 112 HS2O3- 0.15757E-19 -19.8025 0.13051E-19 -19.8844 0.82827E+00 -0.0818 Charge balance for all species = -.6127E-08 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.1710772E-09 -.1675641E-01 -.1685975E+02 0.0000 2 H2O 0.1000000E+01 0.5550327E+02 0.9981492E+06 0.0000 3 Cl- 0.4531785E-03 0.4552805E-03 0.1611267E+02 6.4202 4 SO4-- 0.2274238E-03 0.2276454E-03 0.2182951E+02 15.7495 5 HCO3- 0.1844427E-02 0.3713831E-02 0.2262090E+03 7.0305 6 HS- 0.1043619E-02 0.1044059E-02 0.3446839E+02 6.7825 7 Al+++ 0.4392962E-28 0.1649835E-05 0.4443671E-01 0.5110 8 H4SiO4 0.1024625E-02 0.1095492E-01 0.1051084E+04 -2.9894 9 Ca++ 0.3175357E-07 0.2315018E-06 0.9261807E-02 11.8910 10 Mg++ 0.2190063E-10 0.9310123E-10 0.2259495E-05 8.7274 11 Fe++ 0.1580030E-12 0.1467568E-07 0.8181510E-03 6.5862 12 K+ 0.1564540E-03 0.1571216E-03 0.6132961E+01 5.9591 13 Na+ 0.2039756E-01 0.2228297E-01 0.5113798E+03 8.0734 14 Mn++ 0.6163266E-10 0.2505378E-08 0.1373984E-03 9.1777 15 F- 0.2051054E-04 0.2057759E-04 0.3902454E+00 5.0749 16 HPO4-- 0.4572574E-07 0.4637989E-07 0.4443665E-02 12.0529 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.1507457E-01 -.1506136E-01 -.1320263E-04 0.0000000E+00 2 H2O 0.4988406E+02 0.4988867E+02 -.4605934E-02 0.0000000E+00 3 Cl- 0.4092252E-03 0.4092252E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.2046172E-03 0.2046172E-03 0.0000000E+00 0.0000000E+00 5 HCO3- 0.3338147E-02 0.3338147E-02 0.0000000E+00 0.0000000E+00 6 HS- 0.9384443E-03 0.9384443E-03 0.0000000E+00 0.0000000E+00 7 Al+++ 0.4775352E-05 0.1482941E-05 0.3292411E-05 0.0000000E+00 8 H4SiO4 0.1215302E-01 0.9846740E-02 0.2306280E-02 0.0000000E+00 9 Ca++ 0.2080835E-06 0.2080835E-06 0.0000000E+00 0.0000000E+00 10 Mg++ 0.8368328E-10 0.8368328E-10 0.0000000E+00 0.0000000E+00 11 Fe++ 0.3259227E-07 0.1319112E-07 0.1940115E-07 0.0000000E+00 12 K+ 0.1412294E-03 0.1412275E-03 0.1940115E-08 0.0000000E+00 13 Na+ 0.2003215E-01 0.2002887E-01 0.3284651E-05 0.0000000E+00 14 Mn++ 0.2251939E-08 0.2251939E-08 0.0000000E+00 0.0000000E+00 15 F- 0.1849600E-04 0.1849600E-04 0.0000000E+00 0.0000000E+00 16 HPO4-- 0.4168819E-07 0.4168819E-07 0.0000000E+00 0.0000000E+00 Chg. balance for solid moles: 0.8470E-21 Mass of aqueous solution: 0.900426E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 0.0459900 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 0.3285E-05 -5.484 0.8613E-03 -3.065 0.6204 0.3306E-03 quartz 0.2296E-02 -2.639 0.1380 -0.860 99.38 0.5210E-01 stilpnomelane-Fe 0.3880E-08 -8.411 0.4183E-05 -5.379 0.3013E-02 0.1445E-05 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 quartz 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 0.138833 g Volume = 0.052435 cm3 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.0459900 moles log = -1.3373 Original solution: 1000.0103000 g Original solution / Rock added: 21744.08 (Water/Rock Ratio), log = 4.3373 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0206 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9997E+00 0.9859 0.1006E+01 0.1020E+01 CO2,gas 0.4854E-04 1.0071 0.4990E-04 0.4955E-04 CH4,gas 0.1601E-04 1.0125 0.1655E-04 0.1634E-04 H2,gas 0.2351E-03 1.0005 0.2401E-03 0.2399E-03 H2S,gas 0.1031E-04 0.9960 0.1048E-04 0.1052E-04 S2,gas 0.7005E-22 1.0000 0.7149E-22 0.7149E-22 CO,gas 0.3128E-11 1.0000 0.3192E-11 0.3192E-11 SO3,gas 0.8615E-39 1.0000 0.8793E-39 0.8793E-39 SO2,gas 0.8047E-20 1.0000 0.8212E-20 0.8212E-20 HF,gas 0.3982E-13 1.0000 0.4064E-13 0.4064E-13 HCl,gas 0.1696E-16 1.0000 0.1731E-16 0.1731E-16 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 17 albite -0.38 -0.38 0.00 0.000 0.11184E-10 150 quartz -2.99 -2.99 0.00 0.000 0.00000E+00 167 stilpnomelane-Fe 13.02 13.02 0.00 0.000 -0.27298E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -12.66 -6.00 -2.000 0.10246E+05 -4.302 3 CH4,gas 4.54 -1.94 -6.48 -1.620 0.11065E+05 -4.781 4 H2,gas 8.00 2.68 -5.32 -3.039 0.90814E+04 -3.620 5 H2S,gas -6.23 -12.91 -6.68 -3.339 0.11404E+05 -4.980 6 S2,gas -7.34 -31.18 -23.84 -3.668 0.40714E+05 -22.146 7 CO,gas 3.21 -9.98 -13.19 -4.060 0.22530E+05 -11.496 8 SO3,gas 17.12 -23.63 -40.75 -10.189 0.69588E+05 -39.056 9 SO2,gas 0.83 -20.95 -21.78 -5.809 0.37196E+05 -20.086 10 HF,gas 0.47 -14.62 -15.09 -7.545 0.25766E+05 -13.391 11 HCl,gas 5.19 -13.27 -18.46 -9.230 0.31521E+05 -16.762 12 acmite 7.71 7.34 -0.37 -0.038 0.63102E+03 16 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 20 spessartine 24.46 19.59 -4.87 -0.244 0.83162E+04 21 analcite 3.32 2.61 -0.72 -0.080 0.12231E+04 23 andradite 39.01 37.20 -1.81 -0.094 0.30956E+04 26 ankerite -2.14 -6.84 -4.71 -0.785 0.80419E+04 27 annite 20.12 17.26 -2.86 -0.159 0.48886E+04 28 phlogopite 27.06 23.68 -3.38 -0.188 0.57720E+04 33 apatite-OH -18.15 -22.54 -4.38 -0.337 0.74820E+04 34 apatite-F -34.30 -37.15 -2.85 -0.238 0.48681E+04 38 aragonite 0.97 -0.77 -1.74 -0.579 0.29652E+04 39 brucite 12.57 8.73 -3.84 -0.768 0.65586E+04 40 calcite 0.81 -0.77 -1.58 -0.527 0.27009E+04 41 carnegieite-low 9.02 5.60 -3.43 -0.490 0.58537E+04 42 carnegieite-high 10.09 5.60 -4.50 -0.643 0.76807E+04 43 carpholite-Mg 8.58 3.77 -4.81 -0.321 0.82155E+04 45 celadonite 5.34 3.24 -2.10 -0.124 0.35887E+04 46 celadonite-Fe 3.88 1.10 -2.78 -0.163 0.47433E+04 47 chrysotile 23.89 20.20 -3.69 -0.307 0.62988E+04 49 clinochlore 39.07 35.69 -3.38 -0.106 0.57689E+04 50 daphnite 28.97 24.98 -3.98 -0.124 0.67969E+04 54 chloritoid-Fe 9.17 4.62 -4.55 -0.304 0.77773E+04 55 chloritoid-Mn 11.40 7.21 -4.19 -0.279 0.71556E+04 57 coesite -2.38 -2.99 -0.61 -0.204 0.10473E+04 64 cristobalite -2.56 -2.99 -0.43 -0.143 0.73267E+03 66 cymrite-K 1.69 -2.50 -4.18 -0.349 0.71433E+04 68 diaspore 2.87 0.51 -2.36 -0.394 0.40342E+04 69 diamond -3.10 -7.30 -4.20 -1.199 0.71652E+04 70 diopside 16.18 14.64 -1.54 -0.154 0.26326E+04 71 hedenbergite 14.21 12.50 -1.71 -0.171 0.29198E+04 78 epidote 24.67 21.08 -3.59 -0.174 0.61275E+04 80 epidote-Fe 29.84 25.82 -4.02 -0.209 0.68725E+04 81 fayalite 14.05 10.18 -3.86 -0.552 0.65957E+04 82 ferrosilite 11.15 7.19 -3.96 -0.396 0.67547E+04 86 gibbsite 4.08 0.51 -3.57 -0.510 0.60927E+04 87 glaucophane 22.97 19.44 -3.54 -0.096 0.60429E+04 88 glaucophane-Fe 17.28 13.01 -4.26 -0.115 0.72805E+04 89 graphite -3.55 -7.30 -3.75 -1.072 0.64075E+04 90 greenalite 16.14 13.78 -2.36 -0.197 0.40294E+04 93 hematite 12.57 10.49 -2.07 -0.252 0.35430E+04 94 heulandite -5.83 -8.01 -2.19 -0.099 0.37322E+04 98 jadeite 4.22 2.61 -1.61 -0.161 0.27485E+04 100 kalsilite 7.58 3.48 -4.10 -0.586 0.70061E+04 101 kaolinite -1.33 -4.96 -3.62 -0.329 0.61880E+04 104 laumontite 2.88 0.96 -1.93 -0.129 0.32922E+04 105 lawsonite 9.62 6.93 -2.68 -0.179 0.45793E+04 106 leucite 4.12 0.49 -3.63 -0.363 0.61940E+04 108 lizardite 23.24 20.20 -3.04 -0.253 0.51914E+04 109 magnesite 0.69 -3.93 -4.62 -1.541 0.78957E+04 110 magnetite 20.09 17.08 -3.01 -0.246 0.51395E+04 111 minnesotaite 10.39 7.80 -2.59 -0.152 0.44178E+04 115 manganosite 14.06 9.18 -4.88 -1.220 0.83332E+04 119 microcline -2.49 -2.50 -0.01 -0.001 0.19915E+02 123 muscovite 2.58 -1.48 -4.06 -0.239 0.69298E+04 124 paragonite 4.24 0.64 -3.60 -0.212 0.61490E+04 125 nepheline 8.34 5.60 -2.74 -0.392 0.46861E+04 137 phlogopite-Na 29.65 25.80 -3.85 -0.214 0.65709E+04 139 prehnite 19.37 15.84 -3.54 -0.208 0.60380E+04 140 prehnite-Fe 22.50 20.57 -1.93 -0.116 0.32913E+04 145 pyrite -21.25 -21.91 -0.67 -0.157 0.11371E+04 146 pyrrhotite -4.26 -6.32 -2.06 -0.687 0.35216E+04 147 pyrrhotiteFe0.875 -6.02 -7.48 -1.46 -0.538 0.24956E+04 148 pyroxmangite 7.40 6.19 -1.21 -0.242 0.20667E+04 149 pyrophyllite -6.18 -10.94 -4.76 -0.297 0.81274E+04 154 rhodochrosite -0.98 -3.48 -2.51 -0.836 0.42806E+04 155 rhodonite 7.45 6.19 -1.26 -0.251 0.21470E+04 156 sanidine -1.28 -2.50 -1.22 -0.094 0.20877E+04 158 siderite -2.61 -6.07 -3.47 -1.156 0.59193E+04 166 stilbite -7.52 -8.01 -0.49 -0.023 0.83833E+03 168 stilpnomelane-Mg 27.44 23.72 -3.72 -0.111 0.63485E+04 174 talc 16.49 14.22 -2.27 -0.133 0.38700E+04 177 tephroite 18.09 15.37 -2.72 -0.389 0.46440E+04 181 tridymite -2.63 -2.99 -0.36 -0.121 0.61998E+03 182 tremolite 47.87 43.50 -4.37 -0.118 0.74542E+04 184 troilite-low -4.41 -6.32 -1.91 -0.637 0.32644E+04 190 wairakite 3.95 0.96 -3.00 -0.176 0.51142E+04 191 walstromite 11.51 8.90 -2.61 -0.522 0.44526E+04 192 wollastonite 10.46 8.90 -1.56 -0.312 0.26630E+04 193 pseudo-wollastonite 11.00 8.90 -2.10 -0.420 0.35828E+04 195 akaganeite 7.75 5.25 -2.51 -0.542 0.42840E+04 202 chalcedony -2.80 -2.99 -0.19 -0.062 0.31930E+03 204 montmorillonite-Ca -2.29 -6.26 -3.97 -0.246 0.67813E+04 205 montmorillonite-K -2.24 -6.26 -4.02 -0.246 0.68658E+04 206 montmorillonite-Mg -2.48 -6.78 -4.30 -0.266 0.73496E+04 207 montmorillonite-Na -2.04 -5.56 -3.52 -0.216 0.60141E+04 208 nontronite-Ca 3.21 1.65 -1.56 -0.101 0.26703E+04 209 nontronite-H 2.53 -0.31 -2.84 -0.191 0.48562E+04 210 nontronite-K 3.34 1.66 -1.69 -0.108 0.28781E+04 211 nontronite-Mg 3.07 1.13 -1.95 -0.126 0.33227E+04 212 nontronite-Na 3.52 2.35 -1.17 -0.075 0.19924E+04 228 tobermorite 9.82 6.92 -2.91 -0.793 0.49642E+04 234 alabandite -0.98 -3.73 -2.75 -0.918 0.47013E+04 237 boehmite 4.41 0.51 -3.90 -0.649 0.66511E+04 239 ferrous-oxide 9.81 6.59 -3.23 -0.806 0.55073E+04 245 silica-amorphous -2.09 -2.99 -0.90 -0.299 0.15335E+04 247 an20ab80 2.02 1.08 -0.94 -0.072 0.16017E+04 248 an25ab75 2.65 1.45 -1.20 -0.092 0.20491E+04 249 an30ab70 3.28 1.81 -1.47 -0.113 0.25061E+04 250 tr.625ac.25prg.125 45.16 41.68 -3.48 -0.094 0.59428E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 0.0020000 MOLES Current total amount of reactant added: 0.0459900 MOLES New total amount of reactant added: 0.0479900 MOLES Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.5508E-08 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 7 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 0.0479900 Water: Moles liquid = 0.4990E+02 kg liquid = 0.8989E+00 Moles total = 0.4989E+02 kg total = 0.8987E+00 Activity = 1.0000 Stoichiometric ionic strength = .1443135E-01 Osmotic coef. = 0.9314 True ionic strength = .2275796E-01 Chg. balance for total moles = -.5508E-08 Max. difference allowed = 0.4210E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.17475E-09 -9.7576 0.14566E-09 -9.8367 0.83353E+00 -0.0791 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.46623E-03 -3.3314 0.38603E-03 -3.4134 0.82800E+00 -0.0820 4 SO4-- 0.23803E-03 -3.6234 0.11947E-03 -3.9227 0.50192E+00 -0.2994 5 HCO3- 0.19436E-02 -2.7114 0.16119E-02 -2.7927 0.82934E+00 -0.0813 6 HS- 0.10870E-02 -2.9638 0.90018E-03 -3.0457 0.82813E+00 -0.0819 7 Al+++ 0.47842E-28 -28.3202 0.10222E-28 -28.9905 0.21366E+00 -0.6703 8 H4SiO4 0.10246E-02 -2.9894 0.10246E-02 -2.9894 0.10000E+01 0.0000 9 Ca++ 0.31026E-07 -7.5083 0.15446E-07 -7.8112 0.49785E+00 -0.3029 10 Mg++ 0.21863E-10 -10.6603 0.10830E-10 -10.9654 0.49533E+00 -0.3051 11 Fe++ 0.16405E-12 -12.7850 0.81356E-13 -13.0896 0.49593E+00 -0.3046 12 K+ 0.15644E-03 -3.8056 0.12978E-03 -3.8868 0.82955E+00 -0.0812 13 Na+ 0.20433E-01 -1.6897 0.16915E-01 -1.7717 0.82783E+00 -0.0821 14 Mn++ 0.63906E-10 -10.1945 0.31722E-10 -10.4986 0.49638E+00 -0.3042 15 F- 0.21397E-04 -4.6697 0.17676E-04 -4.7526 0.82612E+00 -0.0830 16 HPO4-- 0.45734E-07 -7.3398 0.22958E-07 -7.6391 0.50200E+00 -0.2993 18 HSiO3- 0.79327E-02 -2.1006 0.65682E-02 -2.1826 0.82800E+00 -0.0820 19 Ca(HSiO3)+ 0.27846E-08 -8.5552 0.23105E-08 -8.6363 0.82975E+00 -0.0811 20 Mg(HSiO3)+ 0.24297E-11 -11.6145 0.20160E-11 -11.6955 0.82975E+00 -0.0811 21 NaHSiO3,aq 0.17969E-02 -2.7455 0.17969E-02 -2.7455 0.10000E+01 0.0000 22 AlO+ 0.78992E-16 -16.1024 0.65543E-16 -16.1835 0.82975E+00 -0.0811 24 HAlO2,aq 0.89611E-10 -10.0476 0.89611E-10 -10.0476 0.10000E+01 0.0000 25 AlO2- 0.16480E-05 -5.7831 0.13618E-05 -5.8659 0.82635E+00 -0.0828 26 CH4,aq 0.11849E-07 -7.9263 0.11797E-07 -7.9282 0.99562E+00 -0.0019 27 C2H6,aq 0.13151E-18 -18.8810 0.13093E-18 -18.8830 0.99562E+00 -0.0019 31 CO,aq 0.22902E-14 -14.6401 0.22902E-14 -14.6401 0.10000E+01 0.0000 32 CO2,aq 0.50390E-06 -6.2977 0.50169E-06 -6.2996 0.99562E+00 -0.0019 33 CO3-2 0.19303E-02 -2.7144 0.96657E-03 -3.0148 0.50075E+00 -0.3004 34 CaCO3,aq 0.18721E-06 -6.7277 0.18721E-06 -6.7277 0.10000E+01 0.0000 35 Ca(HCO3)+ 0.76594E-09 -9.1158 0.63554E-09 -9.1969 0.82975E+00 -0.0811 36 CaCl+ 0.11630E-10 -10.9344 0.96497E-11 -11.0155 0.82975E+00 -0.0811 37 CaCl2,aq 0.88500E-15 -15.0531 0.88500E-15 -15.0531 0.10000E+01 0.0000 38 CaF+ 0.48042E-11 -11.3184 0.39863E-11 -11.3994 0.82975E+00 -0.0811 39 CaOH+ 0.91083E-08 -8.0406 0.75576E-08 -8.1216 0.82975E+00 -0.0811 40 CaSO4,aq 0.58600E-09 -9.2321 0.58600E-09 -9.2321 0.10000E+01 0.0000 41 HCl,aq 0.10304E-13 -13.9870 0.10304E-13 -13.9870 0.10000E+01 0.0000 45 HF,aq 0.17626E-10 -10.7538 0.17626E-10 -10.7538 0.10000E+01 0.0000 46 HF2- 0.12704E-15 -15.8961 0.10519E-15 -15.9780 0.82800E+00 -0.0820 48 FeCl+ 0.59910E-16 -16.2225 0.49710E-16 -16.3036 0.82975E+00 -0.0811 51 FeF+ 0.88566E-16 -16.0527 0.73487E-16 -16.1338 0.82975E+00 -0.0811 53 FeO,aq 0.14903E-09 -9.8267 0.14903E-09 -9.8267 0.10000E+01 0.0000 54 FeOH+ 0.21911E-10 -10.6593 0.18181E-10 -10.7404 0.82975E+00 -0.0811 55 HFeO2- 0.12929E-07 -7.8884 0.10705E-07 -7.9704 0.82800E+00 -0.0820 56 FeO+ 0.12260E-15 -15.9115 0.10172E-15 -15.9926 0.82975E+00 -0.0811 58 FeO2- 0.11848E-08 -8.9263 0.98105E-09 -9.0083 0.82800E+00 -0.0820 59 HFeO2,aq 0.18175E-10 -10.7405 0.18175E-10 -10.7405 0.10000E+01 0.0000 60 H2,aq 0.18252E-06 -6.7387 0.18172E-06 -6.7406 0.99562E+00 -0.0019 61 KCl,aq 0.90800E-09 -9.0419 0.90800E-09 -9.0419 0.10000E+01 0.0000 62 KHSO4,aq 0.63855E-17 -17.1948 0.63855E-17 -17.1948 0.10000E+01 0.0000 63 KOH,aq 0.38049E-06 -6.4197 0.38049E-06 -6.4197 0.10000E+01 0.0000 64 KSO4- 0.29058E-06 -6.5367 0.24060E-06 -6.6187 0.82800E+00 -0.0820 65 MgCO3,aq 0.32899E-10 -10.4828 0.32899E-10 -10.4828 0.10000E+01 0.0000 66 Mg(HCO3)+ 0.54873E-12 -12.2606 0.45531E-12 -12.3417 0.82975E+00 -0.0811 67 MgCl+ 0.73900E-14 -14.1314 0.61319E-14 -14.2124 0.82975E+00 -0.0811 68 MgF+ 0.12477E-13 -13.9039 0.10353E-13 -13.9849 0.82975E+00 -0.0811 69 MgOH+ 0.35337E-10 -10.4518 0.29321E-10 -10.5328 0.82975E+00 -0.0811 71 MnF+ 0.11383E-13 -13.9438 0.94447E-14 -14.0248 0.82975E+00 -0.0811 72 MnO,aq 0.15483E-08 -8.8101 0.15483E-08 -8.8101 0.10000E+01 0.0000 73 MnOH+ 0.79366E-09 -9.1004 0.65854E-09 -9.1814 0.82975E+00 -0.0811 74 MnO2-2 0.48365E-11 -11.3155 0.24219E-11 -11.6159 0.50075E+00 -0.3004 75 HMnO2- 0.93342E-10 -10.0299 0.77287E-10 -10.1119 0.82800E+00 -0.0820 78 MnCl+ 0.90881E-13 -13.0415 0.75409E-13 -13.1226 0.82975E+00 -0.0811 79 MnSO4,aq 0.10941E-11 -11.9609 0.10941E-11 -11.9609 0.10000E+01 0.0000 80 NaCl,aq 0.21640E-05 -5.6647 0.21640E-05 -5.6647 0.10000E+01 0.0000 81 NaF,aq 0.70000E-07 -7.1549 0.70000E-07 -7.1549 0.10000E+01 0.0000 82 NaOH,aq 0.49893E-04 -4.3020 0.49893E-04 -4.3020 0.10000E+01 0.0000 84 OH- 0.48001E-02 -2.3187 0.39666E-02 -2.4016 0.82635E+00 -0.0828 89 HPO3-2 0.25965E-16 -16.5856 0.13002E-16 -16.8860 0.50075E+00 -0.3004 92 H3PO4,aq 0.34068E-17 -17.4676 0.34068E-17 -17.4676 0.10000E+01 0.0000 93 H2PO4- 0.74428E-10 -10.1283 0.61691E-10 -10.2098 0.82887E+00 -0.0815 94 PO4-3 0.57010E-09 -9.2441 0.12860E-09 -9.8908 0.22557E+00 -0.6467 98 HP2O7-3 0.19123E-17 -17.7184 0.40906E-18 -18.3882 0.21391E+00 -0.6698 99 P2O7-4 0.99675E-17 -17.0014 0.67090E-18 -18.1733 0.67309E-01 -1.1719 100 H2S,aq 0.40703E-06 -6.3904 0.40525E-06 -6.3923 0.99562E+00 -0.0019 101 S2-2 0.19731E-09 -9.7048 0.98804E-10 -10.0052 0.50075E+00 -0.3004 102 S3-2 0.59281E-15 -15.2271 0.29685E-15 -15.5275 0.50075E+00 -0.3004 103 S3- 0.82115E-19 -19.0856 0.67991E-19 -19.1675 0.82800E+00 -0.0820 107 SO3-2 0.55456E-11 -11.2561 0.28213E-11 -11.5495 0.50875E+00 -0.2935 108 HSO3- 0.31076E-13 -13.5076 0.25731E-13 -13.5895 0.82800E+00 -0.0820 109 HSO4- 0.20190E-10 -10.6949 0.16771E-10 -10.7754 0.83065E+00 -0.0806 111 S2O3-2 0.11358E-11 -11.9447 0.56873E-12 -12.2451 0.50075E+00 -0.3004 112 HS2O3- 0.17889E-19 -19.7474 0.14812E-19 -19.8294 0.82800E+00 -0.0820 Charge balance for all species = -.6127E-08 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.1747513E-09 -.1651619E-01 -.1661812E+02 0.0000 2 H2O 0.1000000E+01 0.5550337E+02 0.9981555E+06 0.0000 3 Cl- 0.4662257E-03 0.4683906E-03 0.1657672E+02 6.4233 4 SO4-- 0.2380271E-03 0.2382610E-03 0.2284758E+02 15.7506 5 HCO3- 0.1943591E-02 0.3874557E-02 0.2359998E+03 7.0440 6 HS- 0.1086998E-02 0.1087463E-02 0.3590146E+02 6.7910 7 Al+++ 0.4784225E-28 0.1648058E-05 0.4438905E-01 0.5195 8 H4SiO4 0.1024625E-02 0.1075420E-01 0.1031831E+04 -2.9894 9 Ca++ 0.3102626E-07 0.2314929E-06 0.9261495E-02 11.8621 10 Mg++ 0.2186347E-10 0.9309767E-10 0.2259419E-05 8.7079 11 Fe++ 0.1640472E-12 0.1430278E-07 0.7973658E-03 6.5837 12 K+ 0.1564436E-03 0.1571155E-03 0.6132752E+01 5.9499 13 Na+ 0.2043307E-01 0.2228212E-01 0.5113626E+03 8.0649 14 Mn++ 0.6390641E-10 0.2505283E-08 0.1373937E-03 9.1747 15 F- 0.2139678E-04 0.2146680E-04 0.4071108E+00 5.0840 16 HPO4-- 0.4573360E-07 0.4637812E-07 0.4443515E-02 12.0343 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.1485922E-01 -.1484601E-01 -.1320936E-04 0.0000000E+00 2 H2O 0.4988570E+02 0.4989066E+02 -.4966019E-02 0.0000000E+00 3 Cl- 0.4210252E-03 0.4210252E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.2141672E-03 0.2141672E-03 0.0000000E+00 0.0000000E+00 5 HCO3- 0.3482747E-02 0.3482747E-02 0.0000000E+00 0.0000000E+00 6 HS- 0.9774943E-03 0.9774943E-03 0.0000000E+00 0.0000000E+00 7 Al+++ 0.4775352E-05 0.1481400E-05 0.3293952E-05 0.0000000E+00 8 H4SiO4 0.1215302E-01 0.9666696E-02 0.2486324E-02 0.0000000E+00 9 Ca++ 0.2080835E-06 0.2080835E-06 0.0000000E+00 0.0000000E+00 10 Mg++ 0.8368328E-10 0.8368328E-10 0.0000000E+00 0.0000000E+00 11 Fe++ 0.3259227E-07 0.1285643E-07 0.1973584E-07 0.0000000E+00 12 K+ 0.1412294E-03 0.1412274E-03 0.1973584E-08 0.0000000E+00 13 Na+ 0.2003215E-01 0.2002886E-01 0.3286058E-05 0.0000000E+00 14 Mn++ 0.2251939E-08 0.2251939E-08 0.0000000E+00 0.0000000E+00 15 F- 0.1929600E-04 0.1929600E-04 0.0000000E+00 0.0000000E+00 16 HPO4-- 0.4168819E-07 0.4168819E-07 0.0000000E+00 0.0000000E+00 Chg. balance for solid moles: 0.4235E-21 Mass of aqueous solution: 0.900456E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 0.0479900 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 0.3286E-05 -5.483 0.8617E-03 -3.065 0.5758 0.3308E-03 quartz 0.2476E-02 -2.606 0.1488 -0.827 99.42 0.5619E-01 stilpnomelane-Fe 0.3947E-08 -8.404 0.4255E-05 -5.371 0.2843E-02 0.1470E-05 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 quartz 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 0.149650 g Volume = 0.056520 cm3 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.0479900 moles log = -1.3188 Original solution: 1000.0103000 g Original solution / Rock added: 20837.89 (Water/Rock Ratio), log = 4.3189 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0206 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9997E+00 0.9859 0.1006E+01 0.1020E+01 CO2,gas 0.5222E-04 1.0071 0.5368E-04 0.5330E-04 CH4,gas 0.1680E-04 1.0125 0.1737E-04 0.1715E-04 H2,gas 0.2336E-03 1.0005 0.2386E-03 0.2385E-03 H2S,gas 0.1096E-04 0.9960 0.1114E-04 0.1118E-04 S2,gas 0.8018E-22 1.0000 0.8183E-22 0.8183E-22 CO,gas 0.3344E-11 1.0000 0.3413E-11 0.3413E-11 SO3,gas 0.9391E-39 1.0000 0.9584E-39 0.9584E-39 SO2,gas 0.8717E-20 1.0000 0.8896E-20 0.8896E-20 HF,gas 0.4240E-13 1.0000 0.4328E-13 0.4328E-13 HCl,gas 0.1781E-16 1.0000 0.1818E-16 0.1818E-16 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 17 albite -0.38 -0.38 0.00 0.000 -0.94784E-12 150 quartz -2.99 -2.99 0.00 0.000 0.00000E+00 167 stilpnomelane-Fe 13.02 13.02 0.00 0.000 0.21232E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -12.63 -5.97 -1.990 0.10192E+05 -4.270 3 CH4,gas 4.54 -1.92 -6.46 -1.615 0.11029E+05 -4.760 4 H2,gas 8.00 2.68 -5.32 -3.041 0.90860E+04 -3.622 5 H2S,gas -6.23 -12.88 -6.65 -3.326 0.11358E+05 -4.953 6 S2,gas -7.34 -31.12 -23.79 -3.659 0.40614E+05 -22.087 7 CO,gas 3.21 -9.95 -13.17 -4.051 0.22480E+05 -11.467 8 SO3,gas 17.12 -23.60 -40.72 -10.179 0.69524E+05 -39.018 9 SO2,gas 0.83 -20.92 -21.75 -5.800 0.37137E+05 -20.051 10 HF,gas 0.47 -14.59 -15.06 -7.531 0.25719E+05 -13.364 11 HCl,gas 5.19 -13.25 -18.44 -9.220 0.31485E+05 -16.740 12 acmite 7.71 7.33 -0.38 -0.039 0.64742E+03 16 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 20 spessartine 24.46 19.59 -4.86 -0.243 0.83028E+04 21 analcite 3.32 2.61 -0.72 -0.080 0.12231E+04 23 andradite 39.01 37.11 -1.90 -0.099 0.32471E+04 26 ankerite -2.14 -6.81 -4.68 -0.780 0.79871E+04 27 annite 20.12 17.25 -2.87 -0.160 0.49026E+04 28 phlogopite 27.06 23.62 -3.44 -0.191 0.58733E+04 33 apatite-OH -18.15 -22.63 -4.47 -0.344 0.76374E+04 34 apatite-F -34.30 -37.22 -2.91 -0.243 0.49768E+04 38 aragonite 0.97 -0.77 -1.73 -0.578 0.29603E+04 39 brucite 12.57 8.71 -3.86 -0.772 0.65919E+04 40 calcite 0.81 -0.77 -1.58 -0.526 0.26960E+04 41 carnegieite-low 9.02 5.60 -3.43 -0.490 0.58537E+04 42 carnegieite-high 10.09 5.60 -4.50 -0.643 0.76807E+04 43 carpholite-Mg 8.58 3.77 -4.81 -0.321 0.82198E+04 45 celadonite 5.34 3.22 -2.12 -0.125 0.36233E+04 46 celadonite-Fe 3.88 1.10 -2.78 -0.164 0.47488E+04 47 chrysotile 23.89 20.14 -3.75 -0.312 0.63987E+04 49 clinochlore 39.07 35.61 -3.46 -0.108 0.59065E+04 50 daphnite 28.97 24.99 -3.98 -0.124 0.67890E+04 54 chloritoid-Fe 9.17 4.63 -4.54 -0.303 0.77525E+04 55 chloritoid-Mn 11.40 7.22 -4.18 -0.278 0.71318E+04 57 coesite -2.38 -2.99 -0.61 -0.204 0.10473E+04 64 cristobalite -2.56 -2.99 -0.43 -0.143 0.73267E+03 66 cymrite-K 1.69 -2.50 -4.18 -0.349 0.71446E+04 68 diaspore 2.87 0.52 -2.35 -0.392 0.40197E+04 69 diamond -3.10 -7.27 -4.17 -1.191 0.71203E+04 70 diopside 16.18 14.59 -1.59 -0.159 0.27152E+04 71 hedenbergite 14.21 12.47 -1.74 -0.174 0.29732E+04 78 epidote 24.67 21.04 -3.63 -0.176 0.61989E+04 80 epidote-Fe 29.84 25.76 -4.08 -0.212 0.69603E+04 81 fayalite 14.05 10.18 -3.87 -0.553 0.66041E+04 82 ferrosilite 11.15 7.19 -3.96 -0.396 0.67632E+04 86 gibbsite 4.08 0.52 -3.56 -0.509 0.60783E+04 87 glaucophane 22.97 19.38 -3.60 -0.097 0.61429E+04 88 glaucophane-Fe 17.28 13.00 -4.27 -0.115 0.72932E+04 89 graphite -3.55 -7.27 -3.73 -1.065 0.63625E+04 90 greenalite 16.14 13.77 -2.37 -0.197 0.40421E+04 93 hematite 12.57 10.49 -2.08 -0.252 0.35468E+04 94 heulandite -5.83 -8.02 -2.20 -0.100 0.37524E+04 98 jadeite 4.22 2.61 -1.61 -0.161 0.27485E+04 100 kalsilite 7.58 3.48 -4.10 -0.586 0.70074E+04 101 kaolinite -1.33 -4.94 -3.61 -0.328 0.61590E+04 104 laumontite 2.88 0.94 -1.94 -0.129 0.33125E+04 105 lawsonite 9.62 6.92 -2.69 -0.180 0.45996E+04 106 leucite 4.12 0.49 -3.63 -0.363 0.61953E+04 108 lizardite 23.24 20.14 -3.10 -0.258 0.52914E+04 109 magnesite 0.69 -3.92 -4.61 -1.537 0.78749E+04 110 magnetite 20.09 17.07 -3.01 -0.246 0.51476E+04 111 minnesotaite 10.39 7.79 -2.59 -0.153 0.44305E+04 115 manganosite 14.06 9.17 -4.88 -1.221 0.83383E+04 119 microcline -2.49 -2.50 -0.01 -0.001 0.21248E+02 123 muscovite 2.58 -1.46 -4.04 -0.238 0.69022E+04 124 paragonite 4.24 0.66 -3.58 -0.211 0.61201E+04 125 nepheline 8.34 5.60 -2.74 -0.392 0.46861E+04 137 phlogopite-Na 29.65 25.74 -3.91 -0.217 0.66709E+04 139 prehnite 19.37 15.79 -3.58 -0.210 0.61075E+04 140 prehnite-Fe 22.50 20.52 -1.98 -0.119 0.33772E+04 145 pyrite -21.25 -21.86 -0.61 -0.144 0.10457E+04 146 pyrrhotite -4.26 -6.30 -2.04 -0.679 0.34804E+04 147 pyrrhotiteFe0.875 -6.02 -7.45 -1.44 -0.528 0.24532E+04 148 pyroxmangite 7.40 6.19 -1.21 -0.243 0.20719E+04 149 pyrophyllite -6.18 -10.92 -4.74 -0.296 0.80984E+04 154 rhodochrosite -0.98 -3.45 -2.48 -0.826 0.42317E+04 155 rhodonite 7.45 6.19 -1.26 -0.252 0.21522E+04 156 sanidine -1.28 -2.50 -1.22 -0.094 0.20890E+04 158 siderite -2.61 -6.05 -3.44 -1.146 0.58694E+04 166 stilbite -7.52 -8.02 -0.50 -0.024 0.85858E+03 168 stilpnomelane-Mg 27.44 23.64 -3.80 -0.114 0.64941E+04 174 talc 16.49 14.17 -2.33 -0.137 0.39699E+04 177 tephroite 18.09 15.36 -2.73 -0.389 0.46544E+04 181 tridymite -2.63 -2.99 -0.36 -0.121 0.61998E+03 182 tremolite 47.87 43.35 -4.52 -0.122 0.77192E+04 184 troilite-low -4.41 -6.30 -1.89 -0.629 0.32232E+04 190 wairakite 3.95 0.94 -3.01 -0.177 0.51345E+04 191 walstromite 11.51 8.87 -2.64 -0.527 0.45018E+04 192 wollastonite 10.46 8.87 -1.59 -0.318 0.27122E+04 193 pseudo-wollastonite 11.00 8.87 -2.13 -0.425 0.36321E+04 195 akaganeite 7.75 5.24 -2.51 -0.543 0.42859E+04 202 chalcedony -2.80 -2.99 -0.19 -0.062 0.31930E+03 204 montmorillonite-Ca -2.29 -6.26 -3.97 -0.246 0.67762E+04 205 montmorillonite-K -2.24 -6.25 -4.02 -0.246 0.68578E+04 206 montmorillonite-Mg -2.48 -6.78 -4.30 -0.266 0.73419E+04 207 montmorillonite-Na -2.04 -5.56 -3.52 -0.215 0.60057E+04 208 nontronite-Ca 3.21 1.65 -1.57 -0.102 0.26775E+04 209 nontronite-H 2.53 -0.31 -2.84 -0.191 0.48552E+04 210 nontronite-K 3.34 1.65 -1.69 -0.108 0.28823E+04 211 nontronite-Mg 3.07 1.13 -1.95 -0.126 0.33272E+04 212 nontronite-Na 3.52 2.35 -1.17 -0.075 0.19962E+04 228 tobermorite 9.82 6.89 -2.93 -0.800 0.50052E+04 234 alabandite -0.98 -3.71 -2.73 -0.910 0.46610E+04 237 boehmite 4.41 0.52 -3.89 -0.648 0.66366E+04 239 ferrous-oxide 9.81 6.58 -3.23 -0.807 0.55115E+04 245 silica-amorphous -2.09 -2.99 -0.90 -0.299 0.15335E+04 247 an20ab80 2.02 1.08 -0.94 -0.072 0.16057E+04 248 an25ab75 2.65 1.44 -1.20 -0.093 0.20541E+04 249 an30ab70 3.28 1.81 -1.47 -0.113 0.25122E+04 250 tr.625ac.25prg.125 45.16 41.55 -3.61 -0.097 0.61636E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 0.0020000 MOLES Current total amount of reactant added: 0.0479900 MOLES New total amount of reactant added: 0.0499900 MOLES Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.5508E-08 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 7 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 0.0499900 Water: Moles liquid = 0.4990E+02 kg liquid = 0.8989E+00 Moles total = 0.4989E+02 kg total = 0.8987E+00 Activity = 1.0000 Stoichiometric ionic strength = .1456118E-01 Osmotic coef. = 0.9310 True ionic strength = .2286349E-01 Chg. balance for total moles = -.5508E-08 Max. difference allowed = 0.4328E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.17855E-09 -9.7482 0.14879E-09 -9.8274 0.83329E+00 -0.0792 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.47927E-03 -3.3194 0.39671E-03 -3.4015 0.82773E+00 -0.0821 4 SO4-- 0.24863E-03 -3.6044 0.12464E-03 -3.9044 0.50130E+00 -0.2999 5 HCO3- 0.20447E-02 -2.6894 0.16952E-02 -2.7708 0.82908E+00 -0.0814 6 HS- 0.11304E-02 -2.9468 0.93580E-03 -3.0288 0.82787E+00 -0.0820 7 Al+++ 0.52160E-28 -28.2827 0.11112E-28 -28.9542 0.21305E+00 -0.6715 8 H4SiO4 0.10246E-02 -2.9894 0.10246E-02 -2.9894 0.10000E+01 0.0000 9 Ca++ 0.30357E-07 -7.5177 0.15094E-07 -7.8212 0.49721E+00 -0.3035 10 Mg++ 0.21833E-10 -10.6609 0.10800E-10 -10.9666 0.49468E+00 -0.3057 11 Fe++ 0.17040E-12 -12.7685 0.84396E-13 -13.0737 0.49528E+00 -0.3051 12 K+ 0.15643E-03 -3.8057 0.12973E-03 -3.8870 0.82929E+00 -0.0813 13 Na+ 0.20468E-01 -1.6889 0.16939E-01 -1.7711 0.82756E+00 -0.0822 14 Mn++ 0.66283E-10 -10.1786 0.32859E-10 -10.4833 0.49574E+00 -0.3047 15 F- 0.22283E-04 -4.6520 0.18402E-04 -4.7351 0.82585E+00 -0.0831 16 HPO4-- 0.45741E-07 -7.3397 0.22934E-07 -7.6395 0.50137E+00 -0.2998 18 HSiO3- 0.77685E-02 -2.1097 0.64302E-02 -2.1918 0.82773E+00 -0.0821 19 Ca(HSiO3)+ 0.26647E-08 -8.5744 0.22104E-08 -8.6555 0.82949E+00 -0.0812 20 Mg(HSiO3)+ 0.23729E-11 -11.6247 0.19683E-11 -11.7059 0.82949E+00 -0.0812 21 NaHSiO3,aq 0.17616E-02 -2.7541 0.17616E-02 -2.7541 0.10000E+01 0.0000 22 AlO+ 0.82328E-16 -16.0845 0.68290E-16 -16.1656 0.82949E+00 -0.0812 24 HAlO2,aq 0.91405E-10 -10.0390 0.91405E-10 -10.0390 0.10000E+01 0.0000 25 AlO2- 0.16462E-05 -5.7835 0.13599E-05 -5.8665 0.82608E+00 -0.0830 26 CH4,aq 0.12418E-07 -7.9059 0.12363E-07 -7.9079 0.99558E+00 -0.0019 27 C2H6,aq 0.14533E-18 -18.8376 0.14469E-18 -18.8396 0.99558E+00 -0.0019 31 CO,aq 0.24451E-14 -14.6117 0.24451E-14 -14.6117 0.10000E+01 0.0000 32 CO2,aq 0.54133E-06 -6.2665 0.53894E-06 -6.2685 0.99558E+00 -0.0019 33 CO3-2 0.19899E-02 -2.7012 0.99516E-03 -3.0021 0.50012E+00 -0.3009 34 CaCO3,aq 0.18834E-06 -6.7250 0.18834E-06 -6.7250 0.10000E+01 0.0000 35 Ca(HCO3)+ 0.78738E-09 -9.1038 0.65313E-09 -9.1850 0.82949E+00 -0.0812 36 CaCl+ 0.11682E-10 -10.9325 0.96902E-11 -11.0137 0.82949E+00 -0.0812 37 CaCl2,aq 0.91330E-15 -15.0394 0.91330E-15 -15.0394 0.10000E+01 0.0000 38 CaF+ 0.48889E-11 -11.3108 0.40553E-11 -11.3920 0.82949E+00 -0.0812 39 CaOH+ 0.87162E-08 -8.0597 0.72300E-08 -8.1409 0.82949E+00 -0.0812 40 CaSO4,aq 0.59738E-09 -9.2237 0.59738E-09 -9.2237 0.10000E+01 0.0000 41 HCl,aq 0.10816E-13 -13.9659 0.10816E-13 -13.9659 0.10000E+01 0.0000 45 HF,aq 0.18744E-10 -10.7271 0.18744E-10 -10.7271 0.10000E+01 0.0000 46 HF2- 0.14069E-15 -15.8517 0.11646E-15 -15.9338 0.82773E+00 -0.0821 48 FeCl+ 0.63888E-16 -16.1946 0.52995E-16 -16.2758 0.82949E+00 -0.0812 51 FeF+ 0.95680E-16 -16.0192 0.79365E-16 -16.1004 0.82949E+00 -0.0812 53 FeO,aq 0.14817E-09 -9.8292 0.14817E-09 -9.8292 0.10000E+01 0.0000 54 FeOH+ 0.22259E-10 -10.6525 0.18464E-10 -10.7337 0.82949E+00 -0.0812 55 HFeO2- 0.12588E-07 -7.9000 0.10420E-07 -7.9821 0.82773E+00 -0.0821 56 FeO+ 0.12493E-15 -15.9033 0.10363E-15 -15.9845 0.82949E+00 -0.0812 58 FeO2- 0.11572E-08 -8.9366 0.95787E-09 -9.0187 0.82773E+00 -0.0821 59 HFeO2,aq 0.18126E-10 -10.7417 0.18126E-10 -10.7417 0.10000E+01 0.0000 60 H2,aq 0.18140E-06 -6.7414 0.18060E-06 -6.7433 0.99558E+00 -0.0019 61 KCl,aq 0.93276E-09 -9.0302 0.93276E-09 -9.0302 0.10000E+01 0.0000 62 KHSO4,aq 0.68019E-17 -17.1674 0.68019E-17 -17.1674 0.10000E+01 0.0000 63 KOH,aq 0.37236E-06 -6.4290 0.37236E-06 -6.4290 0.10000E+01 0.0000 64 KSO4- 0.30312E-06 -6.5184 0.25090E-06 -6.6005 0.82773E+00 -0.0821 65 MgCO3,aq 0.33781E-10 -10.4713 0.33781E-10 -10.4713 0.10000E+01 0.0000 66 Mg(HCO3)+ 0.57570E-12 -12.2398 0.47754E-12 -12.3210 0.82949E+00 -0.0812 67 MgCl+ 0.75762E-14 -14.1205 0.62844E-14 -14.2017 0.82949E+00 -0.0812 68 MgF+ 0.12959E-13 -13.8874 0.10749E-13 -13.9686 0.82949E+00 -0.0812 69 MgOH+ 0.34511E-10 -10.4620 0.28627E-10 -10.5432 0.82949E+00 -0.0812 71 MnF+ 0.12279E-13 -13.9108 0.10185E-13 -13.9920 0.82949E+00 -0.0812 72 MnO,aq 0.15372E-08 -8.8133 0.15372E-08 -8.8133 0.10000E+01 0.0000 73 MnOH+ 0.80509E-09 -9.0942 0.66782E-09 -9.1753 0.82949E+00 -0.0812 74 MnO2-2 0.46078E-11 -11.3365 0.23044E-11 -11.6374 0.50012E+00 -0.3009 75 HMnO2- 0.90750E-10 -10.0422 0.75117E-10 -10.1243 0.82773E+00 -0.0821 78 MnCl+ 0.96773E-13 -13.0142 0.80272E-13 -13.0954 0.82949E+00 -0.0812 79 MnSO4,aq 0.11823E-11 -11.9273 0.11823E-11 -11.9273 0.10000E+01 0.0000 80 NaCl,aq 0.22270E-05 -5.6523 0.22270E-05 -5.6523 0.10000E+01 0.0000 81 NaF,aq 0.72978E-07 -7.1368 0.72978E-07 -7.1368 0.10000E+01 0.0000 82 NaOH,aq 0.48914E-04 -4.3106 0.48914E-04 -4.3106 0.10000E+01 0.0000 84 OH- 0.47008E-02 -2.3278 0.38832E-02 -2.4108 0.82608E+00 -0.0830 89 HPO3-2 0.25809E-16 -16.5882 0.12907E-16 -16.8892 0.50012E+00 -0.3009 92 H3PO4,aq 0.35508E-17 -17.4497 0.35508E-17 -17.4497 0.10000E+01 0.0000 93 H2PO4- 0.75966E-10 -10.1194 0.62946E-10 -10.2010 0.82860E+00 -0.0817 94 PO4-3 0.55901E-09 -9.2526 0.12576E-09 -9.9005 0.22497E+00 -0.6479 98 HP2O7-3 0.19547E-17 -17.7089 0.41694E-18 -18.3799 0.21330E+00 -0.6710 99 P2O7-4 0.99959E-17 -17.0002 0.66945E-18 -18.1743 0.66973E-01 -1.1741 100 H2S,aq 0.43223E-06 -6.3643 0.43032E-06 -6.3662 0.99558E+00 -0.0019 101 S2-2 0.21483E-09 -9.6679 0.10744E-09 -9.9688 0.50012E+00 -0.3009 102 S3-2 0.68963E-15 -15.1614 0.34490E-15 -15.4623 0.50012E+00 -0.3009 103 S3- 0.97787E-19 -19.0097 0.80942E-19 -19.0918 0.82773E+00 -0.0821 107 SO3-2 0.57566E-11 -11.2398 0.29251E-11 -11.5339 0.50814E+00 -0.2940 108 HSO3- 0.32922E-13 -13.4825 0.27250E-13 -13.5646 0.82773E+00 -0.0821 109 HSO4- 0.21522E-10 -10.6671 0.17871E-10 -10.7478 0.83039E+00 -0.0807 111 S2O3-2 0.12598E-11 -11.8997 0.63003E-12 -12.2006 0.50012E+00 -0.3009 112 HS2O3- 0.20249E-19 -19.6936 0.16761E-19 -19.7757 0.82773E+00 -0.0821 Charge balance for all species = -.6127E-08 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.1785539E-09 -.1627598E-01 -.1637650E+02 0.0000 2 H2O 0.1000000E+01 0.5550347E+02 0.9981617E+06 0.0000 3 Cl- 0.4792718E-03 0.4814997E-03 0.1704073E+02 6.4259 4 SO4-- 0.2486297E-03 0.2488759E-03 0.2386558E+02 15.7505 5 HCO3- 0.2044660E-02 0.4035270E-02 0.2457900E+03 7.0567 6 HS- 0.1130372E-02 0.1130863E-02 0.3733443E+02 6.7986 7 Al+++ 0.5215959E-28 0.1646278E-05 0.4434130E-01 0.5281 8 H4SiO4 0.1024625E-02 0.1055476E-01 0.1012699E+04 -2.9894 9 Ca++ 0.3035723E-07 0.2314841E-06 0.9261182E-02 11.8337 10 Mg++ 0.2183273E-10 0.9309411E-10 0.2259343E-05 8.6883 11 Fe++ 0.1703997E-12 0.1393421E-07 0.7768221E-03 6.5812 12 K+ 0.1564331E-03 0.1571095E-03 0.6132544E+01 5.9405 13 Na+ 0.2046840E-01 0.2228126E-01 0.5113452E+03 8.0563 14 Mn++ 0.6628296E-10 0.2505187E-08 0.1373891E-03 9.1715 15 F- 0.2228295E-04 0.2235595E-04 0.4239750E+00 5.0923 16 HPO4-- 0.4574137E-07 0.4637635E-07 0.4443365E-02 12.0153 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.1464387E-01 -.1463065E-01 -.1321610E-04 0.0000000E+00 2 H2O 0.4988734E+02 0.4989266E+02 -.5323841E-02 0.0000000E+00 3 Cl- 0.4328252E-03 0.4328252E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.2237172E-03 0.2237172E-03 0.0000000E+00 0.0000000E+00 5 HCO3- 0.3627347E-02 0.3627347E-02 0.0000000E+00 0.0000000E+00 6 HS- 0.1016544E-02 0.1016544E-02 0.0000000E+00 0.0000000E+00 7 Al+++ 0.4775352E-05 0.1479856E-05 0.3295496E-05 0.0000000E+00 8 H4SiO4 0.1215302E-01 0.9487783E-02 0.2665237E-02 0.0000000E+00 9 Ca++ 0.2080835E-06 0.2080835E-06 0.0000000E+00 0.0000000E+00 10 Mg++ 0.8368328E-10 0.8368328E-10 0.0000000E+00 0.0000000E+00 11 Fe++ 0.3259227E-07 0.1252561E-07 0.2006666E-07 0.0000000E+00 12 K+ 0.1412294E-03 0.1412274E-03 0.2006666E-08 0.0000000E+00 13 Na+ 0.2003215E-01 0.2002886E-01 0.3287469E-05 0.0000000E+00 14 Mn++ 0.2251939E-08 0.2251939E-08 0.0000000E+00 0.0000000E+00 15 F- 0.2009600E-04 0.2009600E-04 0.0000000E+00 0.0000000E+00 16 HPO4-- 0.4168819E-07 0.4168819E-07 0.0000000E+00 0.0000000E+00 Chg. balance for solid moles: -.8470E-21 Mass of aqueous solution: 0.900487E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 0.0499900 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 0.3287E-05 -5.483 0.8620E-03 -3.064 0.5374 0.3309E-03 quartz 0.2655E-02 -2.576 0.1595 -0.797 99.46 0.6025E-01 stilpnomelane-Fe 0.4013E-08 -8.396 0.4326E-05 -5.364 0.2697E-02 0.1494E-05 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 quartz 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 0.160399 g Volume = 0.060579 cm3 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.0499900 moles log = -1.3011 Original solution: 1000.0103000 g Original solution / Rock added: 20004.21 (Water/Rock Ratio), log = 4.3011 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0206 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9997E+00 0.9859 0.1006E+01 0.1020E+01 CO2,gas 0.5610E-04 1.0071 0.5766E-04 0.5725E-04 CH4,gas 0.1761E-04 1.0125 0.1820E-04 0.1797E-04 H2,gas 0.2322E-03 1.0005 0.2371E-03 0.2370E-03 H2S,gas 0.1164E-04 0.9960 0.1183E-04 0.1188E-04 S2,gas 0.9154E-22 1.0000 0.9342E-22 0.9342E-22 CO,gas 0.3570E-11 1.0000 0.3644E-11 0.3644E-11 SO3,gas 0.1022E-38 1.0000 0.1043E-38 0.1043E-38 SO2,gas 0.9429E-20 1.0000 0.9624E-20 0.9624E-20 HF,gas 0.4509E-13 1.0000 0.4602E-13 0.4602E-13 HCl,gas 0.1870E-16 1.0000 0.1909E-16 0.1909E-16 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 17 albite -0.38 -0.38 0.00 0.000 -0.13080E-10 150 quartz -2.99 -2.99 0.00 0.000 0.00000E+00 167 stilpnomelane-Fe 13.02 13.02 0.00 0.000 0.21232E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -12.60 -5.94 -1.979 0.10139E+05 -4.239 3 CH4,gas 4.54 -1.90 -6.44 -1.610 0.10994E+05 -4.740 4 H2,gas 8.00 2.68 -5.32 -3.042 0.90906E+04 -3.625 5 H2S,gas -6.23 -12.86 -6.63 -3.313 0.11314E+05 -4.927 6 S2,gas -7.34 -31.06 -23.73 -3.651 0.40516E+05 -22.030 7 CO,gas 3.21 -9.92 -13.14 -4.042 0.22432E+05 -11.438 8 SO3,gas 17.12 -23.56 -40.68 -10.170 0.69461E+05 -38.982 9 SO2,gas 0.83 -20.88 -21.72 -5.791 0.37079E+05 -20.017 10 HF,gas 0.47 -14.56 -15.04 -7.518 0.25674E+05 -13.337 11 HCl,gas 5.19 -13.23 -18.42 -9.209 0.31449E+05 -16.719 12 acmite 7.71 7.32 -0.39 -0.040 0.66410E+03 16 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 20 spessartine 24.46 19.60 -4.85 -0.243 0.82895E+04 21 analcite 3.32 2.61 -0.72 -0.080 0.12231E+04 23 andradite 39.01 37.02 -1.99 -0.103 0.33968E+04 26 ankerite -2.14 -6.78 -4.65 -0.774 0.79338E+04 27 annite 20.12 17.24 -2.88 -0.160 0.49167E+04 28 phlogopite 27.06 23.57 -3.50 -0.194 0.59751E+04 33 apatite-OH -18.15 -22.71 -4.56 -0.351 0.77884E+04 34 apatite-F -34.30 -37.28 -2.98 -0.248 0.50822E+04 38 aragonite 0.97 -0.76 -1.73 -0.577 0.29558E+04 39 brucite 12.57 8.69 -3.88 -0.776 0.66254E+04 40 calcite 0.81 -0.76 -1.58 -0.525 0.26915E+04 41 carnegieite-low 9.02 5.60 -3.43 -0.490 0.58537E+04 42 carnegieite-high 10.09 5.60 -4.50 -0.643 0.76807E+04 43 carpholite-Mg 8.58 3.77 -4.82 -0.321 0.82239E+04 45 celadonite 5.34 3.20 -2.14 -0.126 0.36582E+04 46 celadonite-Fe 3.88 1.09 -2.78 -0.164 0.47544E+04 47 chrysotile 23.89 20.09 -3.81 -0.317 0.64992E+04 49 clinochlore 39.07 35.53 -3.54 -0.111 0.60445E+04 50 daphnite 28.97 24.99 -3.97 -0.124 0.67809E+04 54 chloritoid-Fe 9.17 4.65 -4.53 -0.302 0.77274E+04 55 chloritoid-Mn 11.40 7.24 -4.16 -0.278 0.71078E+04 57 coesite -2.38 -2.99 -0.61 -0.204 0.10473E+04 64 cristobalite -2.56 -2.99 -0.43 -0.143 0.73267E+03 66 cymrite-K 1.69 -2.50 -4.19 -0.349 0.71460E+04 68 diaspore 2.87 0.53 -2.35 -0.391 0.40050E+04 69 diamond -3.10 -7.25 -4.14 -1.184 0.70764E+04 70 diopside 16.18 14.54 -1.64 -0.164 0.27973E+04 71 hedenbergite 14.21 12.44 -1.77 -0.177 0.30261E+04 78 epidote 24.67 21.00 -3.67 -0.178 0.62687E+04 80 epidote-Fe 29.84 25.71 -4.13 -0.214 0.70467E+04 81 fayalite 14.05 10.17 -3.87 -0.553 0.66127E+04 82 ferrosilite 11.15 7.18 -3.97 -0.397 0.67717E+04 86 gibbsite 4.08 0.53 -3.55 -0.507 0.60636E+04 87 glaucophane 22.97 19.32 -3.66 -0.099 0.62434E+04 88 glaucophane-Fe 17.28 13.00 -4.28 -0.116 0.73060E+04 89 graphite -3.55 -7.25 -3.70 -1.057 0.63186E+04 90 greenalite 16.14 13.76 -2.37 -0.198 0.40549E+04 93 hematite 12.57 10.49 -2.08 -0.252 0.35507E+04 94 heulandite -5.83 -8.04 -2.21 -0.100 0.37716E+04 98 jadeite 4.22 2.61 -1.61 -0.161 0.27485E+04 100 kalsilite 7.58 3.48 -4.10 -0.586 0.70088E+04 101 kaolinite -1.33 -4.92 -3.59 -0.326 0.61296E+04 104 laumontite 2.88 0.93 -1.95 -0.130 0.33317E+04 105 lawsonite 9.62 6.91 -2.71 -0.180 0.46188E+04 106 leucite 4.12 0.49 -3.63 -0.363 0.61967E+04 108 lizardite 23.24 20.09 -3.16 -0.263 0.53918E+04 109 magnesite 0.69 -3.91 -4.60 -1.534 0.78552E+04 110 magnetite 20.09 17.07 -3.02 -0.246 0.51558E+04 111 minnesotaite 10.39 7.79 -2.60 -0.153 0.44433E+04 115 manganosite 14.06 9.17 -4.89 -1.222 0.83437E+04 119 microcline -2.49 -2.50 -0.01 -0.001 0.22574E+02 123 muscovite 2.58 -1.44 -4.03 -0.237 0.68741E+04 124 paragonite 4.24 0.67 -3.57 -0.210 0.60907E+04 125 nepheline 8.34 5.60 -2.74 -0.392 0.46861E+04 137 phlogopite-Na 29.65 25.68 -3.97 -0.220 0.67713E+04 139 prehnite 19.37 15.76 -3.62 -0.213 0.61753E+04 140 prehnite-Fe 22.50 20.47 -2.03 -0.122 0.34617E+04 145 pyrite -21.25 -21.81 -0.56 -0.132 0.95639E+03 146 pyrrhotite -4.26 -6.28 -2.01 -0.672 0.34401E+04 147 pyrrhotiteFe0.875 -6.02 -7.43 -1.41 -0.520 0.24119E+04 148 pyroxmangite 7.40 6.18 -1.22 -0.243 0.20773E+04 149 pyrophyllite -6.18 -10.90 -4.73 -0.295 0.80690E+04 154 rhodochrosite -0.98 -3.43 -2.45 -0.817 0.41839E+04 155 rhodonite 7.45 6.18 -1.26 -0.253 0.21575E+04 156 sanidine -1.28 -2.50 -1.22 -0.094 0.20903E+04 158 siderite -2.61 -6.02 -3.41 -1.136 0.58206E+04 166 stilbite -7.52 -8.04 -0.51 -0.024 0.87779E+03 168 stilpnomelane-Mg 27.44 23.55 -3.89 -0.116 0.66402E+04 174 talc 16.49 14.11 -2.38 -0.140 0.40704E+04 177 tephroite 18.09 15.35 -2.73 -0.390 0.46651E+04 181 tridymite -2.63 -2.99 -0.36 -0.121 0.61998E+03 182 tremolite 47.87 43.19 -4.68 -0.126 0.79839E+04 184 troilite-low -4.41 -6.28 -1.86 -0.621 0.31829E+04 190 wairakite 3.95 0.93 -3.02 -0.178 0.51537E+04 191 walstromite 11.51 8.84 -2.66 -0.533 0.45504E+04 192 wollastonite 10.46 8.84 -1.62 -0.323 0.27608E+04 193 pseudo-wollastonite 11.00 8.84 -2.16 -0.431 0.36807E+04 195 akaganeite 7.75 5.24 -2.51 -0.543 0.42879E+04 202 chalcedony -2.80 -2.99 -0.19 -0.062 0.31930E+03 204 montmorillonite-Ca -2.29 -6.26 -3.97 -0.245 0.67708E+04 205 montmorillonite-K -2.24 -6.25 -4.01 -0.246 0.68496E+04 206 montmorillonite-Mg -2.48 -6.78 -4.30 -0.266 0.73339E+04 207 montmorillonite-Na -2.04 -5.55 -3.51 -0.215 0.59971E+04 208 nontronite-Ca 3.21 1.64 -1.57 -0.102 0.26846E+04 209 nontronite-H 2.53 -0.31 -2.84 -0.191 0.48543E+04 210 nontronite-K 3.34 1.65 -1.69 -0.109 0.28867E+04 211 nontronite-Mg 3.07 1.12 -1.95 -0.127 0.33319E+04 212 nontronite-Na 3.52 2.35 -1.17 -0.075 0.20002E+04 228 tobermorite 9.82 6.87 -2.96 -0.806 0.50456E+04 234 alabandite -0.98 -3.68 -2.71 -0.902 0.46219E+04 237 boehmite 4.41 0.53 -3.88 -0.646 0.66219E+04 239 ferrous-oxide 9.81 6.58 -3.23 -0.808 0.55158E+04 245 silica-amorphous -2.09 -2.99 -0.90 -0.299 0.15335E+04 247 an20ab80 2.02 1.08 -0.94 -0.073 0.16096E+04 248 an25ab75 2.65 1.44 -1.21 -0.093 0.20589E+04 249 an30ab70 3.28 1.80 -1.47 -0.113 0.25179E+04 250 tr.625ac.25prg.125 45.16 41.43 -3.74 -0.101 0.63839E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 0.0020000 MOLES Current total amount of reactant added: 0.0499900 MOLES New total amount of reactant added: 0.0519900 MOLES Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.5508E-08 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 7 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 0.0519900 Water: Moles liquid = 0.4990E+02 kg liquid = 0.8989E+00 Moles total = 0.4989E+02 kg total = 0.8988E+00 Activity = 1.0000 Stoichiometric ionic strength = .1469101E-01 Osmotic coef. = 0.9306 True ionic strength = .2296687E-01 Chg. balance for total moles = -.5508E-08 Max. difference allowed = 0.4446E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.18249E-09 -9.7388 0.15202E-09 -9.8181 0.83305E+00 -0.0793 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.49232E-03 -3.3078 0.40738E-03 -3.3900 0.82748E+00 -0.0822 4 SO4-- 0.25923E-03 -3.5863 0.12979E-03 -3.8867 0.50068E+00 -0.3004 5 HCO3- 0.21477E-02 -2.6680 0.17800E-02 -2.7496 0.82882E+00 -0.0815 6 HS- 0.11737E-02 -2.9304 0.97140E-03 -3.0126 0.82761E+00 -0.0822 7 Al+++ 0.56929E-28 -28.2447 0.12095E-28 -28.9174 0.21245E+00 -0.6727 8 H4SiO4 0.10246E-02 -2.9894 0.10246E-02 -2.9894 0.10000E+01 0.0000 9 Ca++ 0.29741E-07 -7.5266 0.14769E-07 -7.8306 0.49658E+00 -0.3040 10 Mg++ 0.21808E-10 -10.6614 0.10775E-10 -10.9676 0.49406E+00 -0.3062 11 Fe++ 0.17708E-12 -12.7518 0.87594E-13 -13.0575 0.49466E+00 -0.3057 12 K+ 0.15642E-03 -3.8057 0.12968E-03 -3.8871 0.82904E+00 -0.0814 13 Na+ 0.20504E-01 -1.6882 0.16963E-01 -1.7705 0.82730E+00 -0.0823 14 Mn++ 0.68768E-10 -10.1626 0.34048E-10 -10.4679 0.49511E+00 -0.3053 15 F- 0.23169E-04 -4.6351 0.19128E-04 -4.7183 0.82558E+00 -0.0832 16 HPO4-- 0.45749E-07 -7.3396 0.22909E-07 -7.6400 0.50076E+00 -0.3004 18 HSiO3- 0.76054E-02 -2.1189 0.62933E-02 -2.2011 0.82748E+00 -0.0822 19 Ca(HSiO3)+ 0.25526E-08 -8.5930 0.21167E-08 -8.6743 0.82924E+00 -0.0813 20 Mg(HSiO3)+ 0.23176E-11 -11.6350 0.19218E-11 -11.7163 0.82924E+00 -0.0813 21 NaHSiO3,aq 0.17266E-02 -2.7628 0.17266E-02 -2.7628 0.10000E+01 0.0000 22 AlO+ 0.85855E-16 -16.0662 0.71194E-16 -16.1476 0.82924E+00 -0.0813 24 HAlO2,aq 0.93263E-10 -10.0303 0.93263E-10 -10.0303 0.10000E+01 0.0000 25 AlO2- 0.16444E-05 -5.7840 0.13580E-05 -5.8671 0.82582E+00 -0.0831 26 CH4,aq 0.12999E-07 -7.8861 0.12941E-07 -7.8880 0.99554E+00 -0.0019 27 C2H6,aq 0.16022E-18 -18.7953 0.15951E-18 -18.7972 0.99554E+00 -0.0019 31 CO,aq 0.26072E-14 -14.5838 0.26072E-14 -14.5838 0.10000E+01 0.0000 32 CO2,aq 0.58082E-06 -6.2360 0.57823E-06 -6.2379 0.99554E+00 -0.0019 33 CO3-2 0.20475E-02 -2.6888 0.10227E-02 -2.9902 0.49950E+00 -0.3015 34 CaCO3,aq 0.18940E-06 -6.7226 0.18940E-06 -6.7226 0.10000E+01 0.0000 35 Ca(HCO3)+ 0.80926E-09 -9.0919 0.67107E-09 -9.1732 0.82924E+00 -0.0813 36 CaCl+ 0.11742E-10 -10.9303 0.97368E-11 -11.0116 0.82924E+00 -0.0813 37 CaCl2,aq 0.94237E-15 -15.0258 0.94237E-15 -15.0258 0.10000E+01 0.0000 38 CaF+ 0.49739E-11 -11.3033 0.41246E-11 -11.3846 0.82924E+00 -0.0813 39 CaOH+ 0.83496E-08 -8.0783 0.69238E-08 -8.1597 0.82924E+00 -0.0813 40 CaSO4,aq 0.60871E-09 -9.2156 0.60871E-09 -9.2156 0.10000E+01 0.0000 41 HCl,aq 0.11349E-13 -13.9451 0.11349E-13 -13.9451 0.10000E+01 0.0000 45 HF,aq 0.19907E-10 -10.7010 0.19907E-10 -10.7010 0.10000E+01 0.0000 46 HF2- 0.15536E-15 -15.8087 0.12856E-15 -15.8909 0.82748E+00 -0.0822 48 FeCl+ 0.68113E-16 -16.1668 0.56482E-16 -16.2481 0.82924E+00 -0.0813 51 FeF+ 0.10325E-15 -15.9861 0.85621E-16 -16.0674 0.82924E+00 -0.0813 53 FeO,aq 0.14730E-09 -9.8318 0.14730E-09 -9.8318 0.10000E+01 0.0000 54 FeOH+ 0.22618E-10 -10.6456 0.18755E-10 -10.7269 0.82924E+00 -0.0813 55 HFeO2- 0.12252E-07 -7.9118 0.10138E-07 -7.9940 0.82748E+00 -0.0822 56 FeO+ 0.12734E-15 -15.8950 0.10559E-15 -15.9764 0.82924E+00 -0.0813 58 FeO2- 0.11298E-08 -8.9470 0.93488E-09 -9.0292 0.82748E+00 -0.0822 59 HFeO2,aq 0.18076E-10 -10.7429 0.18076E-10 -10.7429 0.10000E+01 0.0000 60 H2,aq 0.18029E-06 -6.7440 0.17949E-06 -6.7460 0.99554E+00 -0.0019 61 KCl,aq 0.95749E-09 -9.0189 0.95749E-09 -9.0189 0.10000E+01 0.0000 62 KHSO4,aq 0.72347E-17 -17.1406 0.72347E-17 -17.1406 0.10000E+01 0.0000 63 KOH,aq 0.36429E-06 -6.4386 0.36429E-06 -6.4386 0.10000E+01 0.0000 64 KSO4- 0.31564E-06 -6.5008 0.26119E-06 -6.5831 0.82748E+00 -0.0822 65 MgCO3,aq 0.34634E-10 -10.4605 0.34634E-10 -10.4605 0.10000E+01 0.0000 66 Mg(HCO3)+ 0.60326E-12 -12.2195 0.50025E-12 -12.3008 0.82924E+00 -0.0813 67 MgCl+ 0.77638E-14 -14.1099 0.64381E-14 -14.1912 0.82924E+00 -0.0813 68 MgF+ 0.13442E-13 -13.8715 0.11146E-13 -13.9529 0.82924E+00 -0.0813 69 MgOH+ 0.33706E-10 -10.4723 0.27951E-10 -10.5536 0.82924E+00 -0.0813 71 MnF+ 0.13229E-13 -13.8785 0.10970E-13 -13.9598 0.82924E+00 -0.0813 72 MnO,aq 0.15257E-08 -8.8165 0.15257E-08 -8.8165 0.10000E+01 0.0000 73 MnOH+ 0.81670E-09 -9.0879 0.67724E-09 -9.1693 0.82924E+00 -0.0813 74 MnO2-2 0.43860E-11 -11.3579 0.21908E-11 -11.6594 0.49950E+00 -0.3015 75 HMnO2- 0.88181E-10 -10.0546 0.72967E-10 -10.1369 0.82748E+00 -0.0822 78 MnCl+ 0.10300E-12 -12.9872 0.85413E-13 -13.0685 0.82924E+00 -0.0813 79 MnSO4,aq 0.12758E-11 -11.8942 0.12758E-11 -11.8942 0.10000E+01 0.0000 80 NaCl,aq 0.22901E-05 -5.6402 0.22901E-05 -5.6402 0.10000E+01 0.0000 81 NaF,aq 0.75962E-07 -7.1194 0.75962E-07 -7.1194 0.10000E+01 0.0000 82 NaOH,aq 0.47940E-04 -4.3193 0.47940E-04 -4.3193 0.10000E+01 0.0000 84 OH- 0.46022E-02 -2.3370 0.38005E-02 -2.4202 0.82582E+00 -0.0831 89 HPO3-2 0.25655E-16 -16.5908 0.12814E-16 -16.8923 0.49950E+00 -0.3015 92 H3PO4,aq 0.37031E-17 -17.4314 0.37031E-17 -17.4314 0.10000E+01 0.0000 93 H2PO4- 0.77561E-10 -10.1104 0.64248E-10 -10.1921 0.82835E+00 -0.0818 94 PO4-3 0.54797E-09 -9.2612 0.12295E-09 -9.9103 0.22438E+00 -0.6490 98 HP2O7-3 0.19987E-17 -17.6993 0.42511E-18 -18.3715 0.21270E+00 -0.6722 99 P2O7-4 0.10024E-16 -16.9990 0.66804E-18 -18.1752 0.66646E-01 -1.1762 100 H2S,aq 0.45846E-06 -6.3387 0.45641E-06 -6.3406 0.99554E+00 -0.0019 101 S2-2 0.23321E-09 -9.6322 0.11649E-09 -9.9337 0.49950E+00 -0.3015 102 S3-2 0.79895E-15 -15.0975 0.39907E-15 -15.3989 0.49950E+00 -0.3015 103 S3- 0.11600E-18 -18.9355 0.95990E-19 -19.0178 0.82748E+00 -0.0822 107 SO3-2 0.59648E-11 -11.2244 0.30274E-11 -11.5189 0.50754E+00 -0.2945 108 HSO3- 0.34824E-13 -13.4581 0.28816E-13 -13.5404 0.82748E+00 -0.0822 109 HSO4- 0.22907E-10 -10.6400 0.19016E-10 -10.7209 0.83014E+00 -0.0808 111 S2O3-2 0.13931E-11 -11.8560 0.69587E-12 -12.1575 0.49950E+00 -0.3015 112 HS2O3- 0.22859E-19 -19.6409 0.18915E-19 -19.7232 0.82748E+00 -0.0822 Charge balance for all species = -.6127E-08 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.1824913E-09 -.1603579E-01 -.1613490E+02 0.0000 2 H2O 0.1000000E+01 0.5550357E+02 0.9981677E+06 0.0000 3 Cl- 0.4923168E-03 0.4946078E-03 0.1750472E+02 6.4281 4 SO4-- 0.2592316E-03 0.2594900E-03 0.2488350E+02 15.7494 5 HCO3- 0.2147675E-02 0.4195971E-02 0.2555794E+03 7.0685 6 HS- 0.1173742E-02 0.1174259E-02 0.3876730E+02 6.8055 7 Al+++ 0.5692940E-28 0.1644494E-05 0.4429345E-01 0.5369 8 H4SiO4 0.1024625E-02 0.1035661E-01 0.9936922E+03 -2.9894 9 Ca++ 0.2974128E-07 0.2314753E-06 0.9260869E-02 11.8055 10 Mg++ 0.2180840E-10 0.9309056E-10 0.2259266E-05 8.6686 11 Fe++ 0.1770803E-12 0.1357004E-07 0.7565228E-03 6.5787 12 K+ 0.1564226E-03 0.1571035E-03 0.6132335E+01 5.9310 13 Na+ 0.2050355E-01 0.2228041E-01 0.5113279E+03 8.0476 14 Mn++ 0.6876775E-10 0.2505091E-08 0.1373844E-03 9.1683 15 F- 0.2316904E-04 0.2324503E-04 0.4408381E+00 5.0998 16 HPO4-- 0.4574905E-07 0.4637458E-07 0.4443215E-02 11.9962 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.1442852E-01 -.1441529E-01 -.1322284E-04 0.0000000E+00 2 H2O 0.4988897E+02 0.4989465E+02 -.5679352E-02 0.0000000E+00 3 Cl- 0.4446252E-03 0.4446252E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.2332672E-03 0.2332672E-03 0.0000000E+00 0.0000000E+00 5 HCO3- 0.3771947E-02 0.3771947E-02 0.0000000E+00 0.0000000E+00 6 HS- 0.1055594E-02 0.1055594E-02 0.0000000E+00 0.0000000E+00 7 Al+++ 0.4775352E-05 0.1478310E-05 0.3297042E-05 0.0000000E+00 8 H4SiO4 0.1215302E-01 0.9310025E-02 0.2842995E-02 0.0000000E+00 9 Ca++ 0.2080835E-06 0.2080835E-06 0.0000000E+00 0.0000000E+00 10 Mg++ 0.8368328E-10 0.8368328E-10 0.0000000E+00 0.0000000E+00 11 Fe++ 0.3259227E-07 0.1219872E-07 0.2039355E-07 0.0000000E+00 12 K+ 0.1412294E-03 0.1412274E-03 0.2039355E-08 0.0000000E+00 13 Na+ 0.2003215E-01 0.2002886E-01 0.3288885E-05 0.0000000E+00 14 Mn++ 0.2251939E-08 0.2251939E-08 0.0000000E+00 0.0000000E+00 15 F- 0.2089600E-04 0.2089600E-04 0.0000000E+00 0.0000000E+00 16 HPO4-- 0.4168819E-07 0.4168819E-07 0.0000000E+00 0.0000000E+00 Chg. balance for solid moles: -.8470E-21 Mass of aqueous solution: 0.900517E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 0.0519900 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 0.3289E-05 -5.483 0.8624E-03 -3.064 0.5041 0.3311E-03 quartz 0.2833E-02 -2.548 0.1702 -0.769 99.49 0.6428E-01 stilpnomelane-Fe 0.4079E-08 -8.389 0.4397E-05 -5.357 0.2570E-02 0.1519E-05 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 quartz 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 0.171079 g Volume = 0.064612 cm3 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.0519900 moles log = -1.2841 Original solution: 1000.0103000 g Original solution / Rock added: 19234.67 (Water/Rock Ratio), log = 4.2841 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0206 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9997E+00 0.9859 0.1006E+01 0.1020E+01 CO2,gas 0.6019E-04 1.0071 0.6186E-04 0.6143E-04 CH4,gas 0.1843E-04 1.0125 0.1905E-04 0.1881E-04 H2,gas 0.2308E-03 1.0005 0.2357E-03 0.2355E-03 H2S,gas 0.1234E-04 0.9960 0.1255E-04 0.1260E-04 S2,gas 0.1043E-21 1.0000 0.1064E-21 0.1064E-21 CO,gas 0.3807E-11 1.0000 0.3885E-11 0.3885E-11 SO3,gas 0.1111E-38 1.0000 0.1134E-38 0.1134E-38 SO2,gas 0.1019E-19 1.0000 0.1040E-19 0.1040E-19 HF,gas 0.4789E-13 1.0000 0.4888E-13 0.4888E-13 HCl,gas 0.1962E-16 1.0000 0.2003E-16 0.2003E-16 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 17 albite -0.38 -0.38 0.00 0.000 -0.13080E-10 150 quartz -2.99 -2.99 0.00 0.000 0.00000E+00 167 stilpnomelane-Fe 13.02 13.02 0.00 0.000 -0.27298E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -12.57 -5.91 -1.969 0.10087E+05 -4.209 3 CH4,gas 4.54 -1.88 -6.42 -1.605 0.10960E+05 -4.720 4 H2,gas 8.00 2.67 -5.33 -3.044 0.90952E+04 -3.628 5 H2S,gas -6.23 -12.83 -6.60 -3.300 0.11270E+05 -4.901 6 S2,gas -7.34 -31.01 -23.67 -3.642 0.40419E+05 -21.973 7 CO,gas 3.21 -9.89 -13.11 -4.034 0.22384E+05 -11.411 8 SO3,gas 17.12 -23.52 -40.64 -10.161 0.69399E+05 -38.945 9 SO2,gas 0.83 -20.85 -21.68 -5.782 0.37021E+05 -19.983 10 HF,gas 0.47 -14.54 -15.01 -7.505 0.25629E+05 -13.311 11 HCl,gas 5.19 -13.21 -18.40 -9.199 0.31413E+05 -16.698 12 acmite 7.71 7.31 -0.40 -0.041 0.68108E+03 16 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 20 spessartine 24.46 19.61 -4.85 -0.242 0.82763E+04 21 analcite 3.32 2.61 -0.72 -0.080 0.12231E+04 23 andradite 39.01 36.93 -2.08 -0.108 0.35451E+04 26 ankerite -2.14 -6.75 -4.62 -0.769 0.78818E+04 27 annite 20.12 17.24 -2.89 -0.160 0.49311E+04 28 phlogopite 27.06 23.51 -3.56 -0.198 0.60775E+04 33 apatite-OH -18.15 -22.80 -4.65 -0.357 0.79352E+04 34 apatite-F -34.30 -37.34 -3.04 -0.253 0.51844E+04 38 aragonite 0.97 -0.76 -1.73 -0.576 0.29516E+04 39 brucite 12.57 8.67 -3.90 -0.780 0.66591E+04 40 calcite 0.81 -0.76 -1.57 -0.525 0.26874E+04 41 carnegieite-low 9.02 5.60 -3.43 -0.490 0.58537E+04 42 carnegieite-high 10.09 5.60 -4.50 -0.643 0.76807E+04 43 carpholite-Mg 8.58 3.76 -4.82 -0.321 0.82278E+04 45 celadonite 5.34 3.18 -2.16 -0.127 0.36932E+04 46 celadonite-Fe 3.88 1.09 -2.79 -0.164 0.47601E+04 47 chrysotile 23.89 20.03 -3.87 -0.322 0.66003E+04 49 clinochlore 39.07 35.45 -3.62 -0.113 0.61832E+04 50 daphnite 28.97 25.00 -3.97 -0.124 0.67728E+04 54 chloritoid-Fe 9.17 4.66 -4.51 -0.301 0.77019E+04 55 chloritoid-Mn 11.40 7.25 -4.15 -0.277 0.70835E+04 57 coesite -2.38 -2.99 -0.61 -0.204 0.10473E+04 64 cristobalite -2.56 -2.99 -0.43 -0.143 0.73267E+03 66 cymrite-K 1.69 -2.50 -4.19 -0.349 0.71473E+04 68 diaspore 2.87 0.54 -2.34 -0.389 0.39901E+04 69 diamond -3.10 -7.22 -4.12 -1.177 0.70333E+04 70 diopside 16.18 14.50 -1.69 -0.169 0.28790E+04 71 hedenbergite 14.21 12.41 -1.80 -0.180 0.30785E+04 78 epidote 24.67 20.96 -3.71 -0.180 0.63370E+04 80 epidote-Fe 29.84 25.66 -4.18 -0.217 0.71320E+04 81 fayalite 14.05 10.17 -3.88 -0.554 0.66213E+04 82 ferrosilite 11.15 7.18 -3.97 -0.397 0.67804E+04 86 gibbsite 4.08 0.54 -3.54 -0.506 0.60486E+04 87 glaucophane 22.97 19.26 -3.72 -0.100 0.63444E+04 88 glaucophane-Fe 17.28 12.99 -4.29 -0.116 0.73190E+04 89 graphite -3.55 -7.22 -3.68 -1.050 0.62756E+04 90 greenalite 16.14 13.76 -2.38 -0.199 0.40679E+04 93 hematite 12.57 10.48 -2.08 -0.252 0.35549E+04 94 heulandite -5.83 -8.05 -2.22 -0.101 0.37898E+04 98 jadeite 4.22 2.61 -1.61 -0.161 0.27485E+04 100 kalsilite 7.58 3.48 -4.11 -0.587 0.70101E+04 101 kaolinite -1.33 -4.91 -3.57 -0.325 0.60998E+04 104 laumontite 2.88 0.92 -1.96 -0.131 0.33499E+04 105 lawsonite 9.62 6.90 -2.72 -0.181 0.46370E+04 106 leucite 4.12 0.49 -3.63 -0.363 0.61980E+04 108 lizardite 23.24 20.03 -3.22 -0.268 0.54929E+04 109 magnesite 0.69 -3.90 -4.59 -1.530 0.78368E+04 110 magnetite 20.09 17.06 -3.02 -0.247 0.51642E+04 111 minnesotaite 10.39 7.78 -2.61 -0.154 0.44563E+04 115 manganosite 14.06 9.17 -4.89 -1.222 0.83493E+04 119 microcline -2.49 -2.50 -0.01 -0.001 0.23890E+02 123 muscovite 2.58 -1.43 -4.01 -0.236 0.68456E+04 124 paragonite 4.24 0.69 -3.55 -0.209 0.60608E+04 125 nepheline 8.34 5.60 -2.74 -0.392 0.46861E+04 137 phlogopite-Na 29.65 25.62 -4.02 -0.224 0.68724E+04 139 prehnite 19.37 15.72 -3.66 -0.215 0.62415E+04 140 prehnite-Fe 22.50 20.42 -2.08 -0.125 0.35449E+04 145 pyrite -21.25 -21.76 -0.51 -0.120 0.86885E+03 146 pyrrhotite -4.26 -6.25 -1.99 -0.664 0.34008E+04 147 pyrrhotiteFe0.875 -6.02 -7.41 -1.39 -0.511 0.23715E+04 148 pyroxmangite 7.40 6.18 -1.22 -0.244 0.20829E+04 149 pyrophyllite -6.18 -10.88 -4.71 -0.294 0.80392E+04 154 rhodochrosite -0.98 -3.40 -2.42 -0.808 0.41373E+04 155 rhodonite 7.45 6.18 -1.27 -0.253 0.21631E+04 156 sanidine -1.28 -2.50 -1.22 -0.094 0.20916E+04 158 siderite -2.61 -5.99 -3.38 -1.127 0.57727E+04 166 stilbite -7.52 -8.05 -0.52 -0.025 0.89600E+03 168 stilpnomelane-Mg 27.44 23.47 -3.97 -0.119 0.67869E+04 174 talc 16.49 14.05 -2.44 -0.144 0.41715E+04 177 tephroite 18.09 15.35 -2.74 -0.391 0.46762E+04 181 tridymite -2.63 -2.99 -0.36 -0.121 0.61998E+03 182 tremolite 47.87 43.04 -4.83 -0.131 0.82485E+04 184 troilite-low -4.41 -6.25 -1.84 -0.614 0.31436E+04 190 wairakite 3.95 0.92 -3.03 -0.178 0.51719E+04 191 walstromite 11.51 8.82 -2.69 -0.539 0.45985E+04 192 wollastonite 10.46 8.82 -1.65 -0.329 0.28089E+04 193 pseudo-wollastonite 11.00 8.82 -2.18 -0.437 0.37287E+04 195 akaganeite 7.75 5.24 -2.51 -0.543 0.42900E+04 202 chalcedony -2.80 -2.99 -0.19 -0.062 0.31930E+03 204 montmorillonite-Ca -2.29 -6.25 -3.96 -0.245 0.67649E+04 205 montmorillonite-K -2.24 -6.24 -4.01 -0.245 0.68412E+04 206 montmorillonite-Mg -2.48 -6.77 -4.29 -0.265 0.73257E+04 207 montmorillonite-Na -2.04 -5.54 -3.51 -0.215 0.59882E+04 208 nontronite-Ca 3.21 1.64 -1.58 -0.102 0.26917E+04 209 nontronite-H 2.53 -0.31 -2.84 -0.191 0.48535E+04 210 nontronite-K 3.34 1.65 -1.69 -0.109 0.28913E+04 211 nontronite-Mg 3.07 1.12 -1.95 -0.127 0.33366E+04 212 nontronite-Na 3.52 2.35 -1.17 -0.075 0.20043E+04 228 tobermorite 9.82 6.84 -2.98 -0.813 0.50857E+04 234 alabandite -0.98 -3.66 -2.68 -0.895 0.45838E+04 237 boehmite 4.41 0.54 -3.87 -0.645 0.66070E+04 239 ferrous-oxide 9.81 6.58 -3.23 -0.808 0.55201E+04 245 silica-amorphous -2.09 -2.99 -0.90 -0.299 0.15335E+04 247 an20ab80 2.02 1.07 -0.94 -0.073 0.16132E+04 248 an25ab75 2.65 1.44 -1.21 -0.093 0.20635E+04 249 an30ab70 3.28 1.80 -1.48 -0.114 0.25234E+04 250 tr.625ac.25prg.125 45.16 41.30 -3.87 -0.104 0.66039E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 0.0020000 MOLES Current total amount of reactant added: 0.0519900 MOLES New total amount of reactant added: 0.0539900 MOLES Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.5508E-08 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 7 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 0.0539900 Water: Moles liquid = 0.4990E+02 kg liquid = 0.8990E+00 Moles total = 0.4989E+02 kg total = 0.8988E+00 Activity = 1.0000 Stoichiometric ionic strength = .1482082E-01 Osmotic coef. = 0.9302 True ionic strength = .2306806E-01 Chg. balance for total moles = -.5508E-08 Max. difference allowed = 0.4564E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.18657E-09 -9.7292 0.15538E-09 -9.8086 0.83281E+00 -0.0795 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.50536E-03 -3.2964 0.41805E-03 -3.3788 0.82722E+00 -0.0824 4 SO4-- 0.26983E-03 -3.5689 0.13494E-03 -3.8699 0.50008E+00 -0.3010 5 HCO3- 0.22527E-02 -2.6473 0.18665E-02 -2.7290 0.82858E+00 -0.0817 6 HS- 0.12171E-02 -2.9147 0.10070E-02 -2.9970 0.82736E+00 -0.0823 7 Al+++ 0.62206E-28 -28.2062 0.13179E-28 -28.8801 0.21187E+00 -0.6739 8 H4SiO4 0.10246E-02 -2.9894 0.10246E-02 -2.9894 0.10000E+01 0.0000 9 Ca++ 0.29174E-07 -7.5350 0.14470E-07 -7.8395 0.49598E+00 -0.3045 10 Mg++ 0.21790E-10 -10.6617 0.10752E-10 -10.9685 0.49344E+00 -0.3068 11 Fe++ 0.18411E-12 -12.7349 0.90959E-13 -13.0412 0.49405E+00 -0.3062 12 K+ 0.15641E-03 -3.8057 0.12963E-03 -3.8873 0.82879E+00 -0.0816 13 Na+ 0.20539E-01 -1.6874 0.16986E-01 -1.7699 0.82705E+00 -0.0825 14 Mn++ 0.71367E-10 -10.1465 0.35291E-10 -10.4523 0.49450E+00 -0.3058 15 F- 0.24055E-04 -4.6188 0.19853E-04 -4.7022 0.82533E+00 -0.0834 16 HPO4-- 0.45757E-07 -7.3395 0.22886E-07 -7.6404 0.50016E+00 -0.3009 18 HSiO3- 0.74435E-02 -2.1282 0.61575E-02 -2.2106 0.82722E+00 -0.0824 19 Ca(HSiO3)+ 0.24476E-08 -8.6113 0.20290E-08 -8.6927 0.82899E+00 -0.0814 20 Mg(HSiO3)+ 0.22636E-11 -11.6452 0.18765E-11 -11.7267 0.82899E+00 -0.0814 21 NaHSiO3,aq 0.16917E-02 -2.7717 0.16917E-02 -2.7717 0.10000E+01 0.0000 22 AlO+ 0.89586E-16 -16.0478 0.74266E-16 -16.1292 0.82899E+00 -0.0814 24 HAlO2,aq 0.95187E-10 -10.0214 0.95187E-10 -10.0214 0.10000E+01 0.0000 25 AlO2- 0.16426E-05 -5.7845 0.13561E-05 -5.8677 0.82556E+00 -0.0833 26 CH4,aq 0.13591E-07 -7.8667 0.13530E-07 -7.8687 0.99550E+00 -0.0020 27 C2H6,aq 0.17624E-18 -18.7539 0.17544E-18 -18.7559 0.99550E+00 -0.0020 31 CO,aq 0.27770E-14 -14.5564 0.27770E-14 -14.5564 0.10000E+01 0.0000 32 CO2,aq 0.62249E-06 -6.2059 0.61969E-06 -6.2078 0.99550E+00 -0.0020 33 CO3-2 0.21032E-02 -2.6771 0.10493E-02 -2.9791 0.49890E+00 -0.3020 34 CaCO3,aq 0.19037E-06 -6.7204 0.19037E-06 -6.7204 0.10000E+01 0.0000 35 Ca(HCO3)+ 0.83161E-09 -9.0801 0.68940E-09 -9.1615 0.82899E+00 -0.0814 36 CaCl+ 0.11808E-10 -10.9278 0.97891E-11 -11.0093 0.82899E+00 -0.0814 37 CaCl2,aq 0.97224E-15 -15.0122 0.97224E-15 -15.0122 0.10000E+01 0.0000 38 CaF+ 0.50593E-11 -11.2959 0.41941E-11 -11.3774 0.82899E+00 -0.0814 39 CaOH+ 0.80061E-08 -8.0966 0.66370E-08 -8.1780 0.82899E+00 -0.0814 40 CaSO4,aq 0.62001E-09 -9.2076 0.62001E-09 -9.2076 0.10000E+01 0.0000 41 HCl,aq 0.11903E-13 -13.9244 0.11903E-13 -13.9244 0.10000E+01 0.0000 45 HF,aq 0.21117E-10 -10.6754 0.21117E-10 -10.6754 0.10000E+01 0.0000 46 HF2- 0.17111E-15 -15.7667 0.14155E-15 -15.8491 0.82722E+00 -0.0824 48 FeCl+ 0.72603E-16 -16.1390 0.60187E-16 -16.2205 0.82899E+00 -0.0814 51 FeF+ 0.11132E-15 -15.9534 0.92281E-16 -16.0349 0.82899E+00 -0.0814 53 FeO,aq 0.14643E-09 -9.8344 0.14643E-09 -9.8344 0.10000E+01 0.0000 54 FeOH+ 0.22986E-10 -10.6385 0.19056E-10 -10.7200 0.82899E+00 -0.0814 55 HFeO2- 0.11920E-07 -7.9237 0.98606E-08 -8.0061 0.82722E+00 -0.0824 56 FeO+ 0.12981E-15 -15.8867 0.10761E-15 -15.9681 0.82899E+00 -0.0814 58 FeO2- 0.11026E-08 -8.9576 0.91209E-09 -9.0400 0.82722E+00 -0.0824 59 HFeO2,aq 0.18024E-10 -10.7441 0.18024E-10 -10.7441 0.10000E+01 0.0000 60 H2,aq 0.17919E-06 -6.7467 0.17838E-06 -6.7486 0.99550E+00 -0.0020 61 KCl,aq 0.98220E-09 -9.0078 0.98220E-09 -9.0078 0.10000E+01 0.0000 62 KHSO4,aq 0.76847E-17 -17.1144 0.76847E-17 -17.1144 0.10000E+01 0.0000 63 KOH,aq 0.35630E-06 -6.4482 0.35630E-06 -6.4482 0.10000E+01 0.0000 64 KSO4- 0.32814E-06 -6.4839 0.27144E-06 -6.5663 0.82722E+00 -0.0824 65 MgCO3,aq 0.35459E-10 -10.4503 0.35459E-10 -10.4503 0.10000E+01 0.0000 66 Mg(HCO3)+ 0.63145E-12 -12.1997 0.52347E-12 -12.2811 0.82899E+00 -0.0814 67 MgCl+ 0.79531E-14 -14.0995 0.65930E-14 -14.1809 0.82899E+00 -0.0814 68 MgF+ 0.13927E-13 -13.8562 0.11545E-13 -13.9376 0.82899E+00 -0.0814 69 MgOH+ 0.32921E-10 -10.4825 0.27291E-10 -10.5640 0.82899E+00 -0.0814 71 MnF+ 0.14236E-13 -13.8466 0.11801E-13 -13.9281 0.82899E+00 -0.0814 72 MnO,aq 0.15138E-08 -8.8199 0.15138E-08 -8.8199 0.10000E+01 0.0000 73 MnOH+ 0.82849E-09 -9.0817 0.68681E-09 -9.1632 0.82899E+00 -0.0814 74 MnO2-2 0.41712E-11 -11.3797 0.20810E-11 -11.6817 0.49890E+00 -0.3020 75 HMnO2- 0.85634E-10 -10.0674 0.70839E-10 -10.1497 0.82722E+00 -0.0824 78 MnCl+ 0.10959E-12 -12.9602 0.90850E-13 -13.0417 0.82899E+00 -0.0814 79 MnSO4,aq 0.13748E-11 -11.8618 0.13748E-11 -11.8618 0.10000E+01 0.0000 80 NaCl,aq 0.23533E-05 -5.6283 0.23533E-05 -5.6283 0.10000E+01 0.0000 81 NaF,aq 0.78953E-07 -7.1026 0.78953E-07 -7.1026 0.10000E+01 0.0000 82 NaOH,aq 0.46970E-04 -4.3282 0.46970E-04 -4.3282 0.10000E+01 0.0000 84 OH- 0.45042E-02 -2.3464 0.37185E-02 -2.4296 0.82556E+00 -0.0833 89 HPO3-2 0.25501E-16 -16.5934 0.12722E-16 -16.8954 0.49890E+00 -0.3020 92 H3PO4,aq 0.38643E-17 -17.4129 0.38643E-17 -17.4129 0.10000E+01 0.0000 93 H2PO4- 0.79215E-10 -10.1012 0.65598E-10 -10.1831 0.82810E+00 -0.0819 94 PO4-3 0.53696E-09 -9.2701 0.12017E-09 -9.9202 0.22380E+00 -0.6501 98 HP2O7-3 0.20441E-17 -17.6895 0.43360E-18 -18.3629 0.21212E+00 -0.6734 99 P2O7-4 0.10051E-16 -16.9978 0.66666E-18 -18.1761 0.66329E-01 -1.1783 100 H2S,aq 0.48575E-06 -6.3136 0.48357E-06 -6.3155 0.99550E+00 -0.0020 101 S2-2 0.25247E-09 -9.5978 0.12596E-09 -9.8998 0.49890E+00 -0.3020 102 S3-2 0.92207E-15 -15.0352 0.46002E-15 -15.3372 0.49890E+00 -0.3020 103 S3- 0.13713E-18 -18.8629 0.11344E-18 -18.9452 0.82722E+00 -0.0824 107 SO3-2 0.61702E-11 -11.2097 0.31280E-11 -11.5047 0.50696E+00 -0.2950 108 HSO3- 0.36787E-13 -13.4343 0.30431E-13 -13.5167 0.82722E+00 -0.0824 109 HSO4- 0.24347E-10 -10.6135 0.20206E-10 -10.6945 0.82990E+00 -0.0810 111 S2O3-2 0.15364E-11 -11.8135 0.76651E-12 -12.1155 0.49890E+00 -0.3020 112 HS2O3- 0.25743E-19 -19.5893 0.21295E-19 -19.6717 0.82722E+00 -0.0824 Charge balance for all species = -.6126E-08 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.1865699E-09 -.1579562E-01 -.1589331E+02 0.0000 2 H2O 0.1000000E+01 0.5550367E+02 0.9981737E+06 0.0000 3 Cl- 0.5053607E-03 0.5077150E-03 0.1796867E+02 6.4298 4 SO4-- 0.2698326E-03 0.2701032E-03 0.2590136E+02 15.7474 5 HCO3- 0.2252675E-02 0.4356660E-02 0.2653682E+03 7.0796 6 HS- 0.1217108E-02 0.1217653E-02 0.4020007E+02 6.8116 7 Al+++ 0.6220577E-28 0.1642708E-05 0.4424552E-01 0.5457 8 H4SiO4 0.1024625E-02 0.1015980E-01 0.9748123E+03 -2.9894 9 Ca++ 0.2917387E-07 0.2314664E-06 0.9260554E-02 11.7777 10 Mg++ 0.2179049E-10 0.9308701E-10 0.2259190E-05 8.6487 11 Fe++ 0.1841102E-12 0.1321030E-07 0.7364707E-03 6.5761 12 K+ 0.1564120E-03 0.1570974E-03 0.6132125E+01 5.9213 13 Na+ 0.2053851E-01 0.2227956E-01 0.5113105E+03 8.0387 14 Mn++ 0.7136651E-10 0.2504996E-08 0.1373798E-03 9.1649 15 F- 0.2405506E-04 0.2413404E-04 0.4576999E+00 5.1064 16 HPO4-- 0.4575664E-07 0.4637281E-07 0.4443064E-02 11.9768 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.1421317E-01 -.1419994E-01 -.1322959E-04 0.0000000E+00 2 H2O 0.4989061E+02 0.4989664E+02 -.6032505E-02 0.0000000E+00 3 Cl- 0.4564252E-03 0.4564252E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.2428172E-03 0.2428172E-03 0.0000000E+00 0.0000000E+00 5 HCO3- 0.3916547E-02 0.3916547E-02 0.0000000E+00 0.0000000E+00 6 HS- 0.1094644E-02 0.1094644E-02 0.0000000E+00 0.0000000E+00 7 Al+++ 0.4775352E-05 0.1476760E-05 0.3298592E-05 0.0000000E+00 8 H4SiO4 0.1215302E-01 0.9133447E-02 0.3019573E-02 0.0000000E+00 9 Ca++ 0.2080835E-06 0.2080835E-06 0.0000000E+00 0.0000000E+00 10 Mg++ 0.8368328E-10 0.8368328E-10 0.0000000E+00 0.0000000E+00 11 Fe++ 0.3259227E-07 0.1187579E-07 0.2071648E-07 0.0000000E+00 12 K+ 0.1412294E-03 0.1412273E-03 0.2071648E-08 0.0000000E+00 13 Na+ 0.2003215E-01 0.2002886E-01 0.3290305E-05 0.0000000E+00 14 Mn++ 0.2251939E-08 0.2251939E-08 0.0000000E+00 0.0000000E+00 15 F- 0.2169600E-04 0.2169600E-04 0.0000000E+00 0.0000000E+00 16 HPO4-- 0.4168819E-07 0.4168819E-07 0.0000000E+00 0.0000000E+00 Chg. balance for solid moles: 0.8470E-21 Mass of aqueous solution: 0.900548E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 0.0539900 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 0.3290E-05 -5.483 0.8628E-03 -3.064 0.4749 0.3312E-03 quartz 0.3010E-02 -2.521 0.1808 -0.743 99.52 0.6829E-01 stilpnomelane-Fe 0.4143E-08 -8.383 0.4466E-05 -5.350 0.2458E-02 0.1543E-05 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 quartz 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 0.181688 g Volume = 0.068619 cm3 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.0539900 moles log = -1.2677 Original solution: 1000.0103000 g Original solution / Rock added: 18522.14 (Water/Rock Ratio), log = 4.2677 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0206 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9997E+00 0.9859 0.1006E+01 0.1020E+01 CO2,gas 0.6450E-04 1.0071 0.6630E-04 0.6583E-04 CH4,gas 0.1927E-04 1.0125 0.1992E-04 0.1967E-04 H2,gas 0.2293E-03 1.0005 0.2342E-03 0.2341E-03 H2S,gas 0.1308E-04 0.9960 0.1329E-04 0.1335E-04 S2,gas 0.1185E-21 1.0000 0.1209E-21 0.1209E-21 CO,gas 0.4055E-11 1.0000 0.4138E-11 0.4138E-11 SO3,gas 0.1207E-38 1.0000 0.1232E-38 0.1232E-38 SO2,gas 0.1100E-19 1.0000 0.1122E-19 0.1122E-19 HF,gas 0.5080E-13 1.0000 0.5185E-13 0.5185E-13 HCl,gas 0.2058E-16 1.0000 0.2100E-16 0.2100E-16 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 17 albite -0.38 -0.38 0.00 0.000 0.11184E-10 150 quartz -2.99 -2.99 0.00 0.000 0.00000E+00 167 stilpnomelane-Fe 13.02 13.02 0.00 0.000 0.21232E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -12.54 -5.88 -1.959 0.10036E+05 -4.178 3 CH4,gas 4.54 -1.86 -6.40 -1.600 0.10927E+05 -4.701 4 H2,gas 8.00 2.67 -5.33 -3.045 0.90998E+04 -3.630 5 H2S,gas -6.23 -12.81 -6.58 -3.288 0.11227E+05 -4.876 6 S2,gas -7.34 -30.95 -23.62 -3.633 0.40324E+05 -21.917 7 CO,gas 3.21 -9.87 -13.08 -4.025 0.22337E+05 -11.383 8 SO3,gas 17.12 -23.49 -40.61 -10.152 0.69338E+05 -38.909 9 SO2,gas 0.83 -20.82 -21.65 -5.773 0.36965E+05 -19.950 10 HF,gas 0.47 -14.51 -14.98 -7.492 0.25585E+05 -13.285 11 HCl,gas 5.19 -13.19 -18.38 -9.188 0.31378E+05 -16.678 12 acmite 7.71 7.30 -0.41 -0.042 0.69834E+03 16 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 20 spessartine 24.46 19.62 -4.84 -0.242 0.82634E+04 21 analcite 3.32 2.61 -0.72 -0.080 0.12231E+04 23 andradite 39.01 36.85 -2.16 -0.112 0.36920E+04 26 ankerite -2.14 -6.72 -4.59 -0.764 0.78310E+04 27 annite 20.12 17.23 -2.90 -0.161 0.49456E+04 28 phlogopite 27.06 23.44 -3.62 -0.201 0.61805E+04 33 apatite-OH -18.15 -22.88 -4.73 -0.364 0.80782E+04 34 apatite-F -34.30 -37.40 -3.09 -0.258 0.52836E+04 38 aragonite 0.97 -0.76 -1.73 -0.575 0.29478E+04 39 brucite 12.57 8.65 -3.92 -0.784 0.66930E+04 40 calcite 0.81 -0.76 -1.57 -0.524 0.26836E+04 41 carnegieite-low 9.02 5.60 -3.43 -0.490 0.58537E+04 42 carnegieite-high 10.09 5.60 -4.50 -0.643 0.76807E+04 43 carpholite-Mg 8.58 3.76 -4.82 -0.321 0.82314E+04 45 celadonite 5.34 3.16 -2.18 -0.128 0.37284E+04 46 celadonite-Fe 3.88 1.09 -2.79 -0.164 0.47658E+04 47 chrysotile 23.89 19.97 -3.93 -0.327 0.67020E+04 49 clinochlore 39.07 35.37 -3.70 -0.116 0.63223E+04 50 daphnite 28.97 25.00 -3.96 -0.124 0.67646E+04 54 chloritoid-Fe 9.17 4.68 -4.50 -0.300 0.76760E+04 55 chloritoid-Mn 11.40 7.27 -4.13 -0.276 0.70590E+04 57 coesite -2.38 -2.99 -0.61 -0.204 0.10473E+04 64 cristobalite -2.56 -2.99 -0.43 -0.143 0.73267E+03 66 cymrite-K 1.69 -2.50 -4.19 -0.349 0.71486E+04 68 diaspore 2.87 0.55 -2.33 -0.388 0.39749E+04 69 diamond -3.10 -7.20 -4.09 -1.170 0.69911E+04 70 diopside 16.18 14.45 -1.73 -0.173 0.29605E+04 71 hedenbergite 14.21 12.37 -1.83 -0.183 0.31305E+04 78 epidote 24.67 20.92 -3.75 -0.182 0.64039E+04 80 epidote-Fe 29.84 25.61 -4.23 -0.220 0.72162E+04 81 fayalite 14.05 10.16 -3.88 -0.555 0.66302E+04 82 ferrosilite 11.15 7.17 -3.98 -0.398 0.67892E+04 86 gibbsite 4.08 0.55 -3.53 -0.505 0.60335E+04 87 glaucophane 22.97 19.20 -3.78 -0.102 0.64461E+04 88 glaucophane-Fe 17.28 12.98 -4.29 -0.116 0.73323E+04 89 graphite -3.55 -7.20 -3.65 -1.043 0.62334E+04 90 greenalite 16.14 13.75 -2.39 -0.199 0.40812E+04 93 hematite 12.57 10.48 -2.08 -0.253 0.35591E+04 94 heulandite -5.83 -8.06 -2.23 -0.101 0.38071E+04 98 jadeite 4.22 2.61 -1.61 -0.161 0.27485E+04 100 kalsilite 7.58 3.48 -4.11 -0.587 0.70114E+04 101 kaolinite -1.33 -4.89 -3.55 -0.323 0.60695E+04 104 laumontite 2.88 0.91 -1.97 -0.131 0.33672E+04 105 lawsonite 9.62 6.89 -2.73 -0.182 0.46543E+04 106 leucite 4.12 0.49 -3.63 -0.363 0.61993E+04 108 lizardite 23.24 19.97 -3.28 -0.273 0.55946E+04 109 magnesite 0.69 -3.89 -4.58 -1.526 0.78193E+04 110 magnetite 20.09 17.06 -3.03 -0.247 0.51729E+04 111 minnesotaite 10.39 7.77 -2.62 -0.154 0.44696E+04 115 manganosite 14.06 9.16 -4.89 -1.223 0.83551E+04 119 microcline -2.49 -2.50 -0.01 -0.001 0.25198E+02 123 muscovite 2.58 -1.41 -3.99 -0.235 0.68166E+04 124 paragonite 4.24 0.71 -3.53 -0.208 0.60305E+04 125 nepheline 8.34 5.60 -2.74 -0.392 0.46861E+04 137 phlogopite-Na 29.65 25.56 -4.08 -0.227 0.69741E+04 139 prehnite 19.37 15.68 -3.69 -0.217 0.63063E+04 140 prehnite-Fe 22.50 20.37 -2.12 -0.128 0.36270E+04 145 pyrite -21.25 -21.71 -0.46 -0.108 0.78296E+03 146 pyrrhotite -4.26 -6.23 -1.97 -0.656 0.33624E+04 147 pyrrhotiteFe0.875 -6.02 -7.38 -1.37 -0.502 0.23319E+04 148 pyroxmangite 7.40 6.18 -1.22 -0.245 0.20886E+04 149 pyrophyllite -6.18 -10.87 -4.69 -0.293 0.80089E+04 154 rhodochrosite -0.98 -3.37 -2.40 -0.799 0.40917E+04 155 rhodonite 7.45 6.18 -1.27 -0.254 0.21689E+04 156 sanidine -1.28 -2.50 -1.23 -0.094 0.20929E+04 158 siderite -2.61 -5.96 -3.35 -1.118 0.57258E+04 166 stilbite -7.52 -8.06 -0.53 -0.025 0.91327E+03 168 stilpnomelane-Mg 27.44 23.38 -4.06 -0.121 0.69343E+04 174 talc 16.49 13.99 -2.50 -0.147 0.42732E+04 177 tephroite 18.09 15.34 -2.75 -0.392 0.46878E+04 181 tridymite -2.63 -2.99 -0.36 -0.121 0.61998E+03 182 tremolite 47.87 42.88 -4.99 -0.135 0.85130E+04 184 troilite-low -4.41 -6.23 -1.82 -0.606 0.31052E+04 190 wairakite 3.95 0.91 -3.04 -0.179 0.51891E+04 191 walstromite 11.51 8.79 -2.72 -0.544 0.46460E+04 192 wollastonite 10.46 8.79 -1.67 -0.335 0.28564E+04 193 pseudo-wollastonite 11.00 8.79 -2.21 -0.442 0.37763E+04 195 akaganeite 7.75 5.24 -2.51 -0.544 0.42921E+04 202 chalcedony -2.80 -2.99 -0.19 -0.062 0.31930E+03 204 montmorillonite-Ca -2.29 -6.25 -3.96 -0.245 0.67586E+04 205 montmorillonite-K -2.24 -6.24 -4.00 -0.245 0.68325E+04 206 montmorillonite-Mg -2.48 -6.77 -4.29 -0.265 0.73172E+04 207 montmorillonite-Na -2.04 -5.54 -3.50 -0.214 0.59791E+04 208 nontronite-Ca 3.21 1.63 -1.58 -0.103 0.26988E+04 209 nontronite-H 2.53 -0.31 -2.84 -0.190 0.48528E+04 210 nontronite-K 3.34 1.64 -1.70 -0.109 0.28959E+04 211 nontronite-Mg 3.07 1.12 -1.96 -0.127 0.33415E+04 212 nontronite-Na 3.52 2.34 -1.18 -0.076 0.20085E+04 228 tobermorite 9.82 6.82 -3.00 -0.819 0.51253E+04 234 alabandite -0.98 -3.64 -2.66 -0.888 0.45467E+04 237 boehmite 4.41 0.55 -3.86 -0.643 0.65919E+04 239 ferrous-oxide 9.81 6.58 -3.24 -0.809 0.55246E+04 245 silica-amorphous -2.09 -2.99 -0.90 -0.299 0.15335E+04 247 an20ab80 2.02 1.07 -0.95 -0.073 0.16167E+04 248 an25ab75 2.65 1.43 -1.21 -0.093 0.20678E+04 249 an30ab70 3.28 1.80 -1.48 -0.114 0.25286E+04 250 tr.625ac.25prg.125 45.16 41.17 -4.00 -0.108 0.68236E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 0.0020000 MOLES Current total amount of reactant added: 0.0539900 MOLES New total amount of reactant added: 0.0559900 MOLES Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.5508E-08 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 7 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 0.0559900 Water: Moles liquid = 0.4990E+02 kg liquid = 0.8990E+00 Moles total = 0.4989E+02 kg total = 0.8988E+00 Activity = 1.0000 Stoichiometric ionic strength = .1495062E-01 Osmotic coef. = 0.9298 True ionic strength = .2316702E-01 Chg. balance for total moles = -.5508E-08 Max. difference allowed = 0.4682E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.19080E-09 -9.7194 0.15885E-09 -9.7990 0.83259E+00 -0.0796 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.51840E-03 -3.2853 0.42871E-03 -3.3678 0.82698E+00 -0.0825 4 SO4-- 0.28043E-03 -3.5522 0.14008E-03 -3.8536 0.49950E+00 -0.3015 5 HCO3- 0.23597E-02 -2.6271 0.19546E-02 -2.7089 0.82834E+00 -0.0818 6 HS- 0.12605E-02 -2.8995 0.10426E-02 -2.9819 0.82712E+00 -0.0824 7 Al+++ 0.68050E-28 -28.1672 0.14379E-28 -28.8423 0.21130E+00 -0.6751 8 H4SiO4 0.10246E-02 -2.9894 0.10246E-02 -2.9894 0.10000E+01 0.0000 9 Ca++ 0.28651E-07 -7.5429 0.14193E-07 -7.8479 0.49539E+00 -0.3051 10 Mg++ 0.21779E-10 -10.6620 0.10734E-10 -10.9693 0.49285E+00 -0.3073 11 Fe++ 0.19151E-12 -12.7178 0.94502E-13 -13.0246 0.49345E+00 -0.3068 12 K+ 0.15640E-03 -3.8058 0.12959E-03 -3.8874 0.82855E+00 -0.0817 13 Na+ 0.20573E-01 -1.6867 0.17010E-01 -1.7693 0.82681E+00 -0.0826 14 Mn++ 0.74085E-10 -10.1303 0.36591E-10 -10.4366 0.49391E+00 -0.3064 15 F- 0.24941E-04 -4.6031 0.20578E-04 -4.6866 0.82508E+00 -0.0835 16 HPO4-- 0.45764E-07 -7.3395 0.22863E-07 -7.6409 0.49958E+00 -0.3014 18 HSiO3- 0.72828E-02 -2.1377 0.60227E-02 -2.2202 0.82698E+00 -0.0825 19 Ca(HSiO3)+ 0.23490E-08 -8.6291 0.19468E-08 -8.7107 0.82875E+00 -0.0816 20 Mg(HSiO3)+ 0.22108E-11 -11.6554 0.18322E-11 -11.7370 0.82875E+00 -0.0816 21 NaHSiO3,aq 0.16569E-02 -2.7807 0.16569E-02 -2.7807 0.10000E+01 0.0000 22 AlO+ 0.93537E-16 -16.0290 0.77519E-16 -16.1106 0.82875E+00 -0.0816 24 HAlO2,aq 0.97181E-10 -10.0124 0.97181E-10 -10.0124 0.10000E+01 0.0000 25 AlO2- 0.16408E-05 -5.7849 0.13542E-05 -5.8683 0.82531E+00 -0.0834 26 CH4,aq 0.14196E-07 -7.8478 0.14131E-07 -7.8498 0.99547E+00 -0.0020 27 C2H6,aq 0.19345E-18 -18.7134 0.19257E-18 -18.7154 0.99547E+00 -0.0020 31 CO,aq 0.29547E-14 -14.5295 0.29547E-14 -14.5295 0.10000E+01 0.0000 32 CO2,aq 0.66649E-06 -6.1762 0.66347E-06 -6.1782 0.99547E+00 -0.0020 33 CO3-2 0.21568E-02 -2.6662 0.10747E-02 -2.9687 0.49831E+00 -0.3025 34 CaCO3,aq 0.19127E-06 -6.7184 0.19127E-06 -6.7184 0.10000E+01 0.0000 35 Ca(HCO3)+ 0.85449E-09 -9.0683 0.70816E-09 -9.1499 0.82875E+00 -0.0816 36 CaCl+ 0.11882E-10 -10.9251 0.98471E-11 -11.0067 0.82875E+00 -0.0816 37 CaCl2,aq 0.10029E-14 -14.9987 0.10029E-14 -14.9987 0.10000E+01 0.0000 38 CaF+ 0.51454E-11 -11.2886 0.42643E-11 -11.3702 0.82875E+00 -0.0816 39 CaOH+ 0.76836E-08 -8.1144 0.63678E-08 -8.1960 0.82875E+00 -0.0816 40 CaSO4,aq 0.63133E-09 -9.1997 0.63133E-09 -9.1997 0.10000E+01 0.0000 41 HCl,aq 0.12479E-13 -13.9038 0.12479E-13 -13.9038 0.10000E+01 0.0000 45 HF,aq 0.22378E-10 -10.6502 0.22378E-10 -10.6502 0.10000E+01 0.0000 46 HF2- 0.18801E-15 -15.7258 0.15548E-15 -15.8083 0.82698E+00 -0.0825 48 FeCl+ 0.77377E-16 -16.1114 0.64127E-16 -16.1930 0.82875E+00 -0.0816 51 FeF+ 0.11991E-15 -15.9211 0.99376E-16 -16.0027 0.82875E+00 -0.0816 53 FeO,aq 0.14555E-09 -9.8370 0.14555E-09 -9.8370 0.10000E+01 0.0000 54 FeOH+ 0.23366E-10 -10.6314 0.19364E-10 -10.7130 0.82875E+00 -0.0816 55 HFeO2- 0.11592E-07 -7.9358 0.95867E-08 -8.0183 0.82698E+00 -0.0825 56 FeO+ 0.13237E-15 -15.8782 0.10970E-15 -15.9598 0.82875E+00 -0.0816 58 FeO2- 0.10756E-08 -8.9683 0.88950E-09 -9.0509 0.82698E+00 -0.0825 59 HFeO2,aq 0.17971E-10 -10.7454 0.17971E-10 -10.7454 0.10000E+01 0.0000 60 H2,aq 0.17809E-06 -6.7494 0.17728E-06 -6.7513 0.99547E+00 -0.0020 61 KCl,aq 0.10069E-08 -8.9970 0.10069E-08 -8.9970 0.10000E+01 0.0000 62 KHSO4,aq 0.81529E-17 -17.0887 0.81529E-17 -17.0887 0.10000E+01 0.0000 63 KOH,aq 0.34837E-06 -6.4580 0.34837E-06 -6.4580 0.10000E+01 0.0000 64 KSO4- 0.34061E-06 -6.4677 0.28168E-06 -6.5502 0.82698E+00 -0.0825 65 MgCO3,aq 0.36257E-10 -10.4406 0.36257E-10 -10.4406 0.10000E+01 0.0000 66 Mg(HCO3)+ 0.66030E-12 -12.1803 0.54723E-12 -12.2618 0.82875E+00 -0.0816 67 MgCl+ 0.81441E-14 -14.0892 0.67494E-14 -14.1707 0.82875E+00 -0.0816 68 MgF+ 0.14414E-13 -13.8412 0.11946E-13 -13.9228 0.82875E+00 -0.0816 69 MgOH+ 0.32154E-10 -10.4928 0.26647E-10 -10.5743 0.82875E+00 -0.0816 71 MnF+ 0.15304E-13 -13.8152 0.12683E-13 -13.8968 0.82875E+00 -0.0816 72 MnO,aq 0.15017E-08 -8.8234 0.15017E-08 -8.8234 0.10000E+01 0.0000 73 MnOH+ 0.84047E-09 -9.0755 0.69654E-09 -9.1571 0.82875E+00 -0.0816 74 MnO2-2 0.39631E-11 -11.4020 0.19749E-11 -11.7045 0.49831E+00 -0.3025 75 HMnO2- 0.83111E-10 -10.0803 0.68731E-10 -10.1628 0.82698E+00 -0.0825 78 MnCl+ 0.11656E-12 -12.9334 0.96600E-13 -13.0150 0.82875E+00 -0.0816 79 MnSO4,aq 0.14797E-11 -11.8298 0.14797E-11 -11.8298 0.10000E+01 0.0000 80 NaCl,aq 0.24167E-05 -5.6168 0.24167E-05 -5.6168 0.10000E+01 0.0000 81 NaF,aq 0.81950E-07 -7.0865 0.81950E-07 -7.0865 0.10000E+01 0.0000 82 NaOH,aq 0.46007E-04 -4.3372 0.46007E-04 -4.3372 0.10000E+01 0.0000 84 OH- 0.44070E-02 -2.3559 0.36371E-02 -2.4392 0.82531E+00 -0.0834 89 HPO3-2 0.25348E-16 -16.5961 0.12631E-16 -16.8986 0.49831E+00 -0.3025 92 H3PO4,aq 0.40351E-17 -17.3941 0.40351E-17 -17.3941 0.10000E+01 0.0000 93 H2PO4- 0.80930E-10 -10.0919 0.66998E-10 -10.1739 0.82786E+00 -0.0820 94 PO4-3 0.52599E-09 -9.2790 0.11743E-09 -9.9302 0.22325E+00 -0.6512 98 HP2O7-3 0.20913E-17 -17.6796 0.44241E-18 -18.3542 0.21155E+00 -0.6746 99 P2O7-4 0.10077E-16 -16.9966 0.66533E-18 -18.1770 0.66021E-01 -1.1803 100 H2S,aq 0.51418E-06 -6.2889 0.51185E-06 -6.2909 0.99547E+00 -0.0020 101 S2-2 0.27262E-09 -9.5644 0.13585E-09 -9.8669 0.49831E+00 -0.3025 102 S3-2 0.10604E-14 -14.9745 0.52844E-15 -15.2770 0.49831E+00 -0.3025 103 S3- 0.16160E-18 -18.7916 0.13364E-18 -18.8741 0.82698E+00 -0.0825 107 SO3-2 0.63727E-11 -11.1957 0.32271E-11 -11.4912 0.50639E+00 -0.2955 108 HSO3- 0.38813E-13 -13.4110 0.32097E-13 -13.4935 0.82698E+00 -0.0825 109 HSO4- 0.25847E-10 -10.5876 0.21444E-10 -10.6687 0.82966E+00 -0.0811 111 S2O3-2 0.16902E-11 -11.7721 0.84223E-12 -12.0746 0.49831E+00 -0.3025 112 HS2O3- 0.28927E-19 -19.5387 0.23922E-19 -19.6212 0.82698E+00 -0.0825 Charge balance for all species = -.6126E-08 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.1907967E-09 -.1555547E-01 -.1565174E+02 0.0000 2 H2O 0.1000000E+01 0.5550377E+02 0.9981795E+06 0.0000 3 Cl- 0.5184034E-03 0.5208211E-03 0.1843259E+02 6.4312 4 SO4-- 0.2804329E-03 0.2807157E-03 0.2691914E+02 15.7444 5 HCO3- 0.2359700E-02 0.4517337E-02 0.2751563E+03 7.0901 6 HS- 0.1260469E-02 0.1261043E-02 0.4163273E+02 6.8171 7 Al+++ 0.6805006E-28 0.1640919E-05 0.4419751E-01 0.5547 8 H4SiO4 0.1024625E-02 0.9964337E-02 0.9560620E+03 -2.9894 9 Ca++ 0.2865105E-07 0.2314576E-06 0.9260239E-02 11.7501 10 Mg++ 0.2177902E-10 0.9308346E-10 0.2259113E-05 8.6287 11 Fe++ 0.1915123E-12 0.1285506E-07 0.7166688E-03 6.5734 12 K+ 0.1564014E-03 0.1570914E-03 0.6131915E+01 5.9116 13 Na+ 0.2057327E-01 0.2227871E-01 0.5112931E+03 8.0297 14 Mn++ 0.7408534E-10 0.2504900E-08 0.1373751E-03 9.1614 15 F- 0.2494101E-04 0.2502299E-04 0.4745606E+00 5.1124 16 HPO4-- 0.4576412E-07 0.4637104E-07 0.4442913E-02 11.9571 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.1399782E-01 -.1398458E-01 -.1323634E-04 0.0000000E+00 2 H2O 0.4989225E+02 0.4989863E+02 -.6383251E-02 0.0000000E+00 3 Cl- 0.4682252E-03 0.4682252E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.2523672E-03 0.2523672E-03 0.0000000E+00 0.0000000E+00 5 HCO3- 0.4061147E-02 0.4061147E-02 0.0000000E+00 0.0000000E+00 6 HS- 0.1133694E-02 0.1133694E-02 0.0000000E+00 0.0000000E+00 7 Al+++ 0.4775352E-05 0.1475208E-05 0.3300144E-05 0.0000000E+00 8 H4SiO4 0.1215302E-01 0.8958072E-02 0.3194948E-02 0.0000000E+00 9 Ca++ 0.2080835E-06 0.2080835E-06 0.0000000E+00 0.0000000E+00 10 Mg++ 0.8368328E-10 0.8368328E-10 0.0000000E+00 0.0000000E+00 11 Fe++ 0.3259227E-07 0.1155687E-07 0.2103540E-07 0.0000000E+00 12 K+ 0.1412294E-03 0.1412273E-03 0.2103540E-08 0.0000000E+00 13 Na+ 0.2003215E-01 0.2002886E-01 0.3291730E-05 0.0000000E+00 14 Mn++ 0.2251939E-08 0.2251939E-08 0.0000000E+00 0.0000000E+00 15 F- 0.2249600E-04 0.2249600E-04 0.0000000E+00 0.0000000E+00 16 HPO4-- 0.4168819E-07 0.4168819E-07 0.0000000E+00 0.0000000E+00 Chg. balance for solid moles: 0.0000E+00 Mass of aqueous solution: 0.900578E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 0.0559900 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 0.3292E-05 -5.483 0.8632E-03 -3.064 0.4490 0.3313E-03 quartz 0.3185E-02 -2.497 0.1914 -0.718 99.55 0.7226E-01 stilpnomelane-Fe 0.4207E-08 -8.376 0.4535E-05 -5.343 0.2359E-02 0.1567E-05 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 quartz 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 0.192225 g Volume = 0.072598 cm3 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.0559900 moles log = -1.2519 Original solution: 1000.0103000 g Original solution / Rock added: 17860.52 (Water/Rock Ratio), log = 4.2519 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0206 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9997E+00 0.9859 0.1006E+01 0.1020E+01 CO2,gas 0.6906E-04 1.0071 0.7098E-04 0.7048E-04 CH4,gas 0.2013E-04 1.0125 0.2080E-04 0.2054E-04 H2,gas 0.2279E-03 1.0005 0.2328E-03 0.2326E-03 H2S,gas 0.1384E-04 0.9960 0.1407E-04 0.1413E-04 S2,gas 0.1344E-21 1.0000 0.1372E-21 0.1372E-21 CO,gas 0.4314E-11 1.0000 0.4403E-11 0.4403E-11 SO3,gas 0.1310E-38 1.0000 0.1337E-38 0.1337E-38 SO2,gas 0.1186E-19 1.0000 0.1210E-19 0.1210E-19 HF,gas 0.5384E-13 1.0000 0.5495E-13 0.5495E-13 HCl,gas 0.2158E-16 1.0000 0.2202E-16 0.2202E-16 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 17 albite -0.38 -0.38 0.00 0.000 -0.94784E-12 150 quartz -2.99 -2.99 0.00 0.000 0.00000E+00 167 stilpnomelane-Fe 13.02 13.02 0.00 0.000 0.21232E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -12.51 -5.85 -1.949 0.99850E+04 -4.149 3 CH4,gas 4.54 -1.84 -6.38 -1.595 0.10895E+05 -4.682 4 H2,gas 8.00 2.67 -5.33 -3.047 0.91044E+04 -3.633 5 H2S,gas -6.23 -12.78 -6.55 -3.275 0.11185E+05 -4.852 6 S2,gas -7.34 -30.90 -23.56 -3.625 0.40231E+05 -21.863 7 CO,gas 3.21 -9.84 -13.06 -4.017 0.22291E+05 -11.356 8 SO3,gas 17.12 -23.45 -40.57 -10.143 0.69277E+05 -38.874 9 SO2,gas 0.83 -20.78 -21.62 -5.764 0.36909E+05 -19.917 10 HF,gas 0.47 -14.49 -14.96 -7.480 0.25542E+05 -13.260 11 HCl,gas 5.19 -13.17 -18.36 -9.178 0.31343E+05 -16.657 12 acmite 7.71 7.29 -0.42 -0.044 0.71590E+03 16 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 20 spessartine 24.46 19.63 -4.83 -0.242 0.82506E+04 21 analcite 3.32 2.61 -0.72 -0.080 0.12231E+04 23 andradite 39.01 36.76 -2.25 -0.117 0.38377E+04 26 ankerite -2.14 -6.69 -4.56 -0.760 0.77814E+04 27 annite 20.12 17.22 -2.91 -0.161 0.49604E+04 28 phlogopite 27.06 23.38 -3.68 -0.204 0.62841E+04 33 apatite-OH -18.15 -22.97 -4.81 -0.370 0.82175E+04 34 apatite-F -34.30 -37.45 -3.15 -0.263 0.53799E+04 38 aragonite 0.97 -0.76 -1.72 -0.575 0.29443E+04 39 brucite 12.57 8.63 -3.94 -0.788 0.67271E+04 40 calcite 0.81 -0.76 -1.57 -0.523 0.26801E+04 41 carnegieite-low 9.02 5.60 -3.43 -0.490 0.58537E+04 42 carnegieite-high 10.09 5.60 -4.50 -0.643 0.76807E+04 43 carpholite-Mg 8.58 3.76 -4.82 -0.322 0.82347E+04 45 celadonite 5.34 3.14 -2.20 -0.130 0.37638E+04 46 celadonite-Fe 3.88 1.08 -2.79 -0.164 0.47716E+04 47 chrysotile 23.89 19.91 -3.99 -0.332 0.68043E+04 49 clinochlore 39.07 35.28 -3.78 -0.118 0.64621E+04 50 daphnite 28.97 25.01 -3.96 -0.124 0.67563E+04 54 chloritoid-Fe 9.17 4.69 -4.48 -0.299 0.76497E+04 55 chloritoid-Mn 11.40 7.28 -4.12 -0.275 0.70342E+04 57 coesite -2.38 -2.99 -0.61 -0.204 0.10473E+04 64 cristobalite -2.56 -2.99 -0.43 -0.143 0.73267E+03 66 cymrite-K 1.69 -2.50 -4.19 -0.349 0.71499E+04 68 diaspore 2.87 0.55 -2.32 -0.386 0.39596E+04 69 diamond -3.10 -7.17 -4.07 -1.163 0.69497E+04 70 diopside 16.18 14.40 -1.78 -0.178 0.30417E+04 71 hedenbergite 14.21 12.34 -1.86 -0.186 0.31821E+04 78 epidote 24.67 20.88 -3.79 -0.184 0.64696E+04 80 epidote-Fe 29.84 25.57 -4.28 -0.222 0.72995E+04 81 fayalite 14.05 10.16 -3.89 -0.555 0.66391E+04 82 ferrosilite 11.15 7.17 -3.98 -0.398 0.67982E+04 86 gibbsite 4.08 0.55 -3.52 -0.504 0.60181E+04 87 glaucophane 22.97 19.14 -3.84 -0.104 0.65484E+04 88 glaucophane-Fe 17.28 12.97 -4.30 -0.116 0.73457E+04 89 graphite -3.55 -7.17 -3.63 -1.036 0.61920E+04 90 greenalite 16.14 13.74 -2.40 -0.200 0.40946E+04 93 hematite 12.57 10.48 -2.09 -0.253 0.35635E+04 94 heulandite -5.83 -8.07 -2.24 -0.102 0.38235E+04 98 jadeite 4.22 2.61 -1.61 -0.161 0.27485E+04 100 kalsilite 7.58 3.48 -4.11 -0.587 0.70127E+04 101 kaolinite -1.33 -4.87 -3.54 -0.322 0.60387E+04 104 laumontite 2.88 0.90 -1.98 -0.132 0.33835E+04 105 lawsonite 9.62 6.88 -2.74 -0.182 0.46706E+04 106 leucite 4.12 0.49 -3.63 -0.363 0.62006E+04 108 lizardite 23.24 19.91 -3.34 -0.278 0.56969E+04 109 magnesite 0.69 -3.88 -4.57 -1.523 0.78028E+04 110 magnetite 20.09 17.05 -3.03 -0.248 0.51818E+04 111 minnesotaite 10.39 7.76 -2.63 -0.154 0.44830E+04 115 manganosite 14.06 9.16 -4.90 -1.224 0.83610E+04 119 microcline -2.49 -2.50 -0.02 -0.001 0.26497E+02 123 muscovite 2.58 -1.39 -3.97 -0.234 0.67872E+04 124 paragonite 4.24 0.73 -3.51 -0.207 0.59998E+04 125 nepheline 8.34 5.60 -2.74 -0.392 0.46861E+04 137 phlogopite-Na 29.65 25.50 -4.14 -0.230 0.70764E+04 139 prehnite 19.37 15.64 -3.73 -0.219 0.63698E+04 140 prehnite-Fe 22.50 20.33 -2.17 -0.131 0.37081E+04 145 pyrite -21.25 -21.66 -0.41 -0.096 0.69855E+03 146 pyrrhotite -4.26 -6.21 -1.95 -0.649 0.33247E+04 147 pyrrhotiteFe0.875 -6.02 -7.36 -1.34 -0.494 0.22931E+04 148 pyroxmangite 7.40 6.17 -1.23 -0.245 0.20946E+04 149 pyrophyllite -6.18 -10.85 -4.67 -0.292 0.79781E+04 154 rhodochrosite -0.98 -3.35 -2.37 -0.790 0.40471E+04 155 rhodonite 7.45 6.17 -1.27 -0.255 0.21749E+04 156 sanidine -1.28 -2.50 -1.23 -0.094 0.20942E+04 158 siderite -2.61 -5.93 -3.33 -1.109 0.56797E+04 166 stilbite -7.52 -8.07 -0.54 -0.026 0.92963E+03 168 stilpnomelane-Mg 27.44 23.29 -4.15 -0.124 0.70824E+04 174 talc 16.49 13.93 -2.56 -0.151 0.43755E+04 177 tephroite 18.09 15.33 -2.75 -0.393 0.46998E+04 181 tridymite -2.63 -2.99 -0.36 -0.121 0.61998E+03 184 troilite-low -4.41 -6.21 -1.80 -0.599 0.30675E+04 190 wairakite 3.95 0.90 -3.05 -0.179 0.52055E+04 191 walstromite 11.51 8.76 -2.75 -0.550 0.46931E+04 192 wollastonite 10.46 8.76 -1.70 -0.340 0.29036E+04 193 pseudo-wollastonite 11.00 8.76 -2.24 -0.448 0.38234E+04 195 akaganeite 7.75 5.24 -2.51 -0.544 0.42943E+04 202 chalcedony -2.80 -2.99 -0.19 -0.062 0.31930E+03 204 montmorillonite-Ca -2.29 -6.25 -3.95 -0.245 0.67520E+04 205 montmorillonite-K -2.24 -6.23 -4.00 -0.245 0.68236E+04 206 montmorillonite-Mg -2.48 -6.76 -4.28 -0.265 0.73084E+04 207 montmorillonite-Na -2.04 -5.53 -3.50 -0.214 0.59698E+04 208 nontronite-Ca 3.21 1.63 -1.58 -0.103 0.27059E+04 209 nontronite-H 2.53 -0.31 -2.84 -0.190 0.48521E+04 210 nontronite-K 3.34 1.64 -1.70 -0.109 0.29007E+04 211 nontronite-Mg 3.07 1.11 -1.96 -0.127 0.33464E+04 212 nontronite-Na 3.52 2.34 -1.18 -0.076 0.20129E+04 228 tobermorite 9.82 6.80 -3.02 -0.825 0.51645E+04 234 alabandite -0.98 -3.62 -2.64 -0.881 0.45105E+04 237 boehmite 4.41 0.55 -3.85 -0.642 0.65765E+04 239 ferrous-oxide 9.81 6.57 -3.24 -0.810 0.55290E+04 245 silica-amorphous -2.09 -2.99 -0.90 -0.299 0.15335E+04 247 an20ab80 2.02 1.07 -0.95 -0.073 0.16199E+04 248 an25ab75 2.65 1.43 -1.21 -0.093 0.20719E+04 249 an30ab70 3.28 1.80 -1.48 -0.114 0.25335E+04 250 tr.625ac.25prg.125 45.16 41.04 -4.12 -0.111 0.70432E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 0.0020000 MOLES Current total amount of reactant added: 0.0559900 MOLES New total amount of reactant added: 0.0579900 MOLES Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.5508E-08 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 7 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 0.0579900 Water: Moles liquid = 0.4990E+02 kg liquid = 0.8990E+00 Moles total = 0.4989E+02 kg total = 0.8989E+00 Activity = 1.0000 Stoichiometric ionic strength = .1508042E-01 Osmotic coef. = 0.9295 True ionic strength = .2326369E-01 Chg. balance for total moles = -.5508E-08 Max. difference allowed = 0.4800E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.19518E-09 -9.7096 0.16246E-09 -9.7893 0.83236E+00 -0.0797 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.53145E-03 -3.2745 0.43937E-03 -3.3572 0.82674E+00 -0.0826 4 SO4-- 0.29103E-03 -3.5361 0.14521E-03 -3.8380 0.49894E+00 -0.3020 5 HCO3- 0.24688E-02 -2.6075 0.20444E-02 -2.6894 0.82810E+00 -0.0819 6 HS- 0.13038E-02 -2.8848 0.10781E-02 -2.9673 0.82688E+00 -0.0826 7 Al+++ 0.74532E-28 -28.1277 0.15708E-28 -28.8039 0.21075E+00 -0.6762 8 H4SiO4 0.10246E-02 -2.9894 0.10246E-02 -2.9894 0.10000E+01 0.0000 9 Ca++ 0.28169E-07 -7.5502 0.13938E-07 -7.8558 0.49481E+00 -0.3056 10 Mg++ 0.21774E-10 -10.6621 0.10719E-10 -10.9699 0.49227E+00 -0.3078 11 Fe++ 0.19931E-12 -12.7005 0.98235E-13 -13.0077 0.49287E+00 -0.3073 12 K+ 0.15639E-03 -3.8058 0.12954E-03 -3.8876 0.82832E+00 -0.0818 13 Na+ 0.20608E-01 -1.6860 0.17034E-01 -1.7687 0.82657E+00 -0.0827 14 Mn++ 0.76931E-10 -10.1139 0.37952E-10 -10.4208 0.49333E+00 -0.3069 15 F- 0.25827E-04 -4.5879 0.21303E-04 -4.6716 0.82483E+00 -0.0836 16 HPO4-- 0.45771E-07 -7.3394 0.22841E-07 -7.6413 0.49902E+00 -0.3019 18 HSiO3- 0.71232E-02 -2.1473 0.58891E-02 -2.2300 0.82674E+00 -0.0826 19 Ca(HSiO3)+ 0.22563E-08 -8.6466 0.18694E-08 -8.7283 0.82852E+00 -0.0817 20 Mg(HSiO3)+ 0.21593E-11 -11.6657 0.17890E-11 -11.7474 0.82852E+00 -0.0817 21 NaHSiO3,aq 0.16224E-02 -2.7898 0.16224E-02 -2.7898 0.10000E+01 0.0000 22 AlO+ 0.97722E-16 -16.0100 0.80965E-16 -16.0917 0.82852E+00 -0.0817 24 HAlO2,aq 0.99249E-10 -10.0033 0.99249E-10 -10.0033 0.10000E+01 0.0000 25 AlO2- 0.16390E-05 -5.7854 0.13523E-05 -5.8689 0.82507E+00 -0.0835 26 CH4,aq 0.14812E-07 -7.8294 0.14745E-07 -7.8314 0.99543E+00 -0.0020 27 C2H6,aq 0.21192E-18 -18.6738 0.21095E-18 -18.6758 0.99543E+00 -0.0020 31 CO,aq 0.31410E-14 -14.5029 0.31410E-14 -14.5029 0.10000E+01 0.0000 32 CO2,aq 0.71295E-06 -6.1469 0.70969E-06 -6.1489 0.99543E+00 -0.0020 33 CO3-2 0.22083E-02 -2.6559 0.10992E-02 -2.9589 0.49775E+00 -0.3030 34 CaCO3,aq 0.19211E-06 -6.7165 0.19211E-06 -6.7165 0.10000E+01 0.0000 35 Ca(HCO3)+ 0.87794E-09 -9.0565 0.72739E-09 -9.1382 0.82852E+00 -0.0817 36 CaCl+ 0.11962E-10 -10.9222 0.99107E-11 -11.0039 0.82852E+00 -0.0817 37 CaCl2,aq 0.10345E-14 -14.9853 0.10345E-14 -14.9853 0.10000E+01 0.0000 38 CaF+ 0.52325E-11 -11.2813 0.43352E-11 -11.3630 0.82852E+00 -0.0817 39 CaOH+ 0.73802E-08 -8.1319 0.61147E-08 -8.2136 0.82852E+00 -0.0817 40 CaSO4,aq 0.64270E-09 -9.1920 0.64270E-09 -9.1920 0.10000E+01 0.0000 41 HCl,aq 0.13080E-13 -13.8834 0.13080E-13 -13.8834 0.10000E+01 0.0000 45 HF,aq 0.23692E-10 -10.6254 0.23692E-10 -10.6254 0.10000E+01 0.0000 46 HF2- 0.20611E-15 -15.6859 0.17040E-15 -15.7685 0.82674E+00 -0.0826 48 FeCl+ 0.82457E-16 -16.0838 0.68317E-16 -16.1655 0.82852E+00 -0.0817 51 FeF+ 0.12907E-15 -15.8892 0.10694E-15 -15.9709 0.82852E+00 -0.0817 53 FeO,aq 0.14466E-09 -9.8397 0.14466E-09 -9.8397 0.10000E+01 0.0000 54 FeOH+ 0.23756E-10 -10.6242 0.19683E-10 -10.7059 0.82852E+00 -0.0817 55 HFeO2- 0.11269E-07 -7.9481 0.93165E-08 -8.0307 0.82674E+00 -0.0826 56 FeO+ 0.13500E-15 -15.8697 0.11185E-15 -15.9514 0.82852E+00 -0.0817 58 FeO2- 0.10489E-08 -8.9793 0.86713E-09 -9.0619 0.82674E+00 -0.0826 59 HFeO2,aq 0.17917E-10 -10.7467 0.17917E-10 -10.7467 0.10000E+01 0.0000 60 H2,aq 0.17699E-06 -6.7520 0.17618E-06 -6.7540 0.99543E+00 -0.0020 61 KCl,aq 0.10316E-08 -8.9865 0.10316E-08 -8.9865 0.10000E+01 0.0000 62 KHSO4,aq 0.86402E-17 -17.0635 0.86402E-17 -17.0635 0.10000E+01 0.0000 63 KOH,aq 0.34052E-06 -6.4679 0.34052E-06 -6.4679 0.10000E+01 0.0000 64 KSO4- 0.35306E-06 -6.4522 0.29189E-06 -6.5348 0.82674E+00 -0.0826 65 MgCO3,aq 0.37029E-10 -10.4315 0.37029E-10 -10.4315 0.10000E+01 0.0000 66 Mg(HCO3)+ 0.68986E-12 -12.1612 0.57156E-12 -12.2429 0.82852E+00 -0.0817 67 MgCl+ 0.83372E-14 -14.0790 0.69075E-14 -14.1607 0.82852E+00 -0.0817 68 MgF+ 0.14905E-13 -13.8267 0.12349E-13 -13.9084 0.82852E+00 -0.0817 69 MgOH+ 0.31405E-10 -10.5030 0.26019E-10 -10.5847 0.82852E+00 -0.0817 71 MnF+ 0.16436E-13 -13.7842 0.13618E-13 -13.8659 0.82852E+00 -0.0817 72 MnO,aq 0.14891E-08 -8.8271 0.14891E-08 -8.8271 0.10000E+01 0.0000 73 MnOH+ 0.85262E-09 -9.0692 0.70641E-09 -9.1509 0.82852E+00 -0.0817 74 MnO2-2 0.37619E-11 -11.4246 0.18725E-11 -11.7276 0.49775E+00 -0.3030 75 HMnO2- 0.80613E-10 -10.0936 0.66646E-10 -10.1762 0.82674E+00 -0.0826 78 MnCl+ 0.12394E-12 -12.9068 0.10268E-12 -12.9885 0.82852E+00 -0.0817 79 MnSO4,aq 0.15910E-11 -11.7983 0.15910E-11 -11.7983 0.10000E+01 0.0000 80 NaCl,aq 0.24802E-05 -5.6055 0.24802E-05 -5.6055 0.10000E+01 0.0000 81 NaF,aq 0.84954E-07 -7.0708 0.84954E-07 -7.0708 0.10000E+01 0.0000 82 NaOH,aq 0.45048E-04 -4.3463 0.45048E-04 -4.3463 0.10000E+01 0.0000 84 OH- 0.43104E-02 -2.3655 0.35564E-02 -2.4490 0.82507E+00 -0.0835 89 HPO3-2 0.25195E-16 -16.5987 0.12541E-16 -16.9017 0.49775E+00 -0.3030 92 H3PO4,aq 0.42162E-17 -17.3751 0.42162E-17 -17.3751 0.10000E+01 0.0000 93 H2PO4- 0.82710E-10 -10.0824 0.68452E-10 -10.1646 0.82762E+00 -0.0822 94 PO4-3 0.51507E-09 -9.2881 0.11471E-09 -9.9404 0.22270E+00 -0.6523 98 HP2O7-3 0.21401E-17 -17.6696 0.45157E-18 -18.3453 0.21100E+00 -0.6757 99 P2O7-4 0.10104E-16 -16.9955 0.66404E-18 -18.1778 0.65723E-01 -1.1823 100 H2S,aq 0.54380E-06 -6.2646 0.54132E-06 -6.2665 0.99543E+00 -0.0020 101 S2-2 0.29368E-09 -9.5321 0.14618E-09 -9.8351 0.49775E+00 -0.3030 102 S3-2 0.12157E-14 -14.9152 0.60510E-15 -15.2182 0.49775E+00 -0.3030 103 S3- 0.18989E-18 -18.7215 0.15699E-18 -18.8041 0.82674E+00 -0.0826 107 SO3-2 0.65722E-11 -11.1823 0.33245E-11 -11.4783 0.50584E+00 -0.2960 108 HSO3- 0.40904E-13 -13.3882 0.33817E-13 -13.4709 0.82674E+00 -0.0826 109 HSO4- 0.27410E-10 -10.5621 0.22734E-10 -10.6433 0.82943E+00 -0.0812 111 S2O3-2 0.18550E-11 -11.7316 0.92333E-12 -12.0346 0.49775E+00 -0.3030 112 HS2O3- 0.32442E-19 -19.4889 0.26821E-19 -19.5715 0.82674E+00 -0.0826 Charge balance for all species = -.6126E-08 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.1951791E-09 -.1531534E-01 -.1541018E+02 0.0000 2 H2O 0.1000000E+01 0.5550386E+02 0.9981852E+06 0.0000 3 Cl- 0.5314450E-03 0.5339263E-03 0.1889647E+02 6.4321 4 SO4-- 0.2910325E-03 0.2913274E-03 0.2793686E+02 15.7405 5 HCO3- 0.2468789E-02 0.4678002E-02 0.2849437E+03 7.0998 6 HS- 0.1303826E-02 0.1304430E-02 0.4306530E+02 6.8219 7 Al+++ 0.7453198E-28 0.1639127E-05 0.4414942E-01 0.5639 8 H4SiO4 0.1024625E-02 0.9770256E-02 0.9374439E+03 -2.9894 9 Ca++ 0.2816936E-07 0.2314488E-06 0.9259923E-02 11.7227 10 Mg++ 0.2177402E-10 0.9307992E-10 0.2259036E-05 8.6086 11 Fe++ 0.1993114E-12 0.1250435E-07 0.6971196E-03 6.5708 12 K+ 0.1563908E-03 0.1570854E-03 0.6131705E+01 5.9017 13 Na+ 0.2060783E-01 0.2227786E-01 0.5112756E+03 8.0206 14 Mn++ 0.7693070E-10 0.2504805E-08 0.1373704E-03 9.1577 15 F- 0.2582688E-04 0.2591186E-04 0.4914201E+00 5.1177 16 HPO4-- 0.4577150E-07 0.4636928E-07 0.4442761E-02 11.9372 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.1378247E-01 -.1376922E-01 -.1324309E-04 0.0000000E+00 2 H2O 0.4989389E+02 0.4990062E+02 -.6731542E-02 0.0000000E+00 3 Cl- 0.4800252E-03 0.4800252E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.2619172E-03 0.2619172E-03 0.0000000E+00 0.0000000E+00 5 HCO3- 0.4205747E-02 0.4205747E-02 0.0000000E+00 0.0000000E+00 6 HS- 0.1172744E-02 0.1172744E-02 0.0000000E+00 0.0000000E+00 7 Al+++ 0.4775352E-05 0.1473653E-05 0.3301699E-05 0.0000000E+00 8 H4SiO4 0.1215302E-01 0.8783925E-02 0.3369095E-02 0.0000000E+00 9 Ca++ 0.2080835E-06 0.2080835E-06 0.0000000E+00 0.0000000E+00 10 Mg++ 0.8368328E-10 0.8368328E-10 0.0000000E+00 0.0000000E+00 11 Fe++ 0.3259227E-07 0.1124200E-07 0.2135027E-07 0.0000000E+00 12 K+ 0.1412294E-03 0.1412273E-03 0.2135027E-08 0.0000000E+00 13 Na+ 0.2003215E-01 0.2002886E-01 0.3293159E-05 0.0000000E+00 14 Mn++ 0.2251939E-08 0.2251939E-08 0.0000000E+00 0.0000000E+00 15 F- 0.2329600E-04 0.2329600E-04 0.0000000E+00 0.0000000E+00 16 HPO4-- 0.4168819E-07 0.4168819E-07 0.0000000E+00 0.0000000E+00 Chg. balance for solid moles: -.8470E-21 Mass of aqueous solution: 0.900609E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 0.0579900 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 0.3293E-05 -5.482 0.8635E-03 -3.064 0.4260 0.3315E-03 quartz 0.3359E-02 -2.474 0.2018 -0.695 99.57 0.7622E-01 stilpnomelane-Fe 0.4270E-08 -8.370 0.4603E-05 -5.337 0.2271E-02 0.1590E-05 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 quartz 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 0.202688 g Volume = 0.076549 cm3 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.0579900 moles log = -1.2366 Original solution: 1000.0103000 g Original solution / Rock added: 17244.53 (Water/Rock Ratio), log = 4.2367 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0206 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9997E+00 0.9859 0.1006E+01 0.1020E+01 CO2,gas 0.7387E-04 1.0071 0.7593E-04 0.7539E-04 CH4,gas 0.2100E-04 1.0125 0.2170E-04 0.2143E-04 H2,gas 0.2265E-03 1.0005 0.2313E-03 0.2312E-03 H2S,gas 0.1464E-04 0.9960 0.1488E-04 0.1494E-04 S2,gas 0.1522E-21 1.0000 0.1553E-21 0.1553E-21 CO,gas 0.4586E-11 1.0000 0.4681E-11 0.4681E-11 SO3,gas 0.1420E-38 1.0000 0.1449E-38 0.1449E-38 SO2,gas 0.1278E-19 1.0000 0.1304E-19 0.1304E-19 HF,gas 0.5700E-13 1.0000 0.5817E-13 0.5817E-13 HCl,gas 0.2261E-16 1.0000 0.2308E-16 0.2308E-16 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 17 albite -0.38 -0.38 0.00 0.000 0.11184E-10 150 quartz -2.99 -2.99 0.00 0.000 0.00000E+00 167 stilpnomelane-Fe 13.02 13.02 0.00 0.000 -0.75827E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -12.48 -5.82 -1.940 0.99350E+04 -4.120 3 CH4,gas 4.54 -1.82 -6.36 -1.591 0.10864E+05 -4.663 4 H2,gas 8.00 2.66 -5.33 -3.048 0.91090E+04 -3.636 5 H2S,gas -6.23 -12.76 -6.53 -3.263 0.11144E+05 -4.827 6 S2,gas -7.34 -30.84 -23.51 -3.617 0.40139E+05 -21.809 7 CO,gas 3.21 -9.81 -13.03 -4.009 0.22246E+05 -11.330 8 SO3,gas 17.12 -23.42 -40.54 -10.134 0.69217E+05 -38.839 9 SO2,gas 0.83 -20.75 -21.58 -5.756 0.36854E+05 -19.885 10 HF,gas 0.47 -14.46 -14.93 -7.467 0.25500E+05 -13.235 11 HCl,gas 5.19 -13.15 -18.34 -9.168 0.31308E+05 -16.637 12 acmite 7.71 7.28 -0.43 -0.045 0.73376E+03 16 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 20 spessartine 24.46 19.63 -4.82 -0.241 0.82380E+04 21 analcite 3.32 2.61 -0.72 -0.080 0.12231E+04 23 andradite 39.01 36.68 -2.33 -0.121 0.39824E+04 26 ankerite -2.14 -6.66 -4.53 -0.755 0.77328E+04 27 annite 20.12 17.21 -2.91 -0.162 0.49753E+04 28 phlogopite 27.06 23.32 -3.74 -0.208 0.63884E+04 33 apatite-OH -18.15 -23.05 -4.89 -0.376 0.83535E+04 34 apatite-F -34.30 -37.51 -3.21 -0.267 0.54735E+04 38 aragonite 0.97 -0.76 -1.72 -0.574 0.29411E+04 39 brucite 12.57 8.61 -3.96 -0.792 0.67615E+04 40 calcite 0.81 -0.76 -1.57 -0.523 0.26769E+04 41 carnegieite-low 9.02 5.60 -3.43 -0.490 0.58537E+04 42 carnegieite-high 10.09 5.60 -4.50 -0.643 0.76807E+04 43 carpholite-Mg 8.58 3.76 -4.82 -0.322 0.82378E+04 44 carpholite-Fe 6.71 1.72 -4.99 -0.333 0.85254E+04 45 celadonite 5.34 3.12 -2.23 -0.131 0.37994E+04 46 celadonite-Fe 3.88 1.08 -2.80 -0.165 0.47774E+04 47 chrysotile 23.89 19.85 -4.05 -0.337 0.69073E+04 49 clinochlore 39.07 35.20 -3.87 -0.121 0.66025E+04 50 daphnite 28.97 25.01 -3.95 -0.123 0.67478E+04 54 chloritoid-Fe 9.17 4.71 -4.46 -0.298 0.76231E+04 55 chloritoid-Mn 11.40 7.30 -4.11 -0.274 0.70092E+04 57 coesite -2.38 -2.99 -0.61 -0.204 0.10473E+04 64 cristobalite -2.56 -2.99 -0.43 -0.143 0.73267E+03 66 cymrite-K 1.69 -2.50 -4.19 -0.349 0.71512E+04 68 diaspore 2.87 0.56 -2.31 -0.385 0.39440E+04 69 diamond -3.10 -7.15 -4.05 -1.156 0.69090E+04 70 diopside 16.18 14.35 -1.83 -0.183 0.31227E+04 71 hedenbergite 14.21 12.31 -1.89 -0.189 0.32334E+04 78 epidote 24.67 20.84 -3.83 -0.186 0.65341E+04 80 epidote-Fe 29.84 25.52 -4.32 -0.225 0.73818E+04 81 fayalite 14.05 10.15 -3.89 -0.556 0.66482E+04 82 ferrosilite 11.15 7.16 -3.99 -0.399 0.68073E+04 86 gibbsite 4.08 0.56 -3.52 -0.502 0.60025E+04 87 glaucophane 22.97 19.08 -3.90 -0.105 0.66514E+04 88 glaucophane-Fe 17.28 12.97 -4.31 -0.116 0.73594E+04 89 graphite -3.55 -7.15 -3.60 -1.029 0.61513E+04 90 greenalite 16.14 13.73 -2.41 -0.201 0.41083E+04 93 hematite 12.57 10.48 -2.09 -0.253 0.35680E+04 94 heulandite -5.83 -8.08 -2.25 -0.102 0.38390E+04 98 jadeite 4.22 2.61 -1.61 -0.161 0.27485E+04 100 kalsilite 7.58 3.48 -4.11 -0.587 0.70140E+04 101 kaolinite -1.33 -4.85 -3.52 -0.320 0.60075E+04 104 laumontite 2.88 0.89 -1.99 -0.133 0.33990E+04 105 lawsonite 9.62 6.87 -2.74 -0.183 0.46861E+04 106 leucite 4.12 0.49 -3.63 -0.363 0.62019E+04 108 lizardite 23.24 19.85 -3.40 -0.283 0.57999E+04 109 magnesite 0.69 -3.87 -4.56 -1.520 0.77872E+04 110 magnetite 20.09 17.05 -3.04 -0.248 0.51908E+04 111 minnesotaite 10.39 7.75 -2.63 -0.155 0.44967E+04 115 manganosite 14.06 9.16 -4.90 -1.225 0.83672E+04 119 microcline -2.49 -2.50 -0.02 -0.001 0.27787E+02 123 muscovite 2.58 -1.38 -3.96 -0.233 0.67572E+04 124 paragonite 4.24 0.74 -3.50 -0.206 0.59686E+04 125 nepheline 8.34 5.60 -2.74 -0.392 0.46861E+04 137 phlogopite-Na 29.65 25.44 -4.20 -0.234 0.71794E+04 139 prehnite 19.37 15.60 -3.77 -0.222 0.64320E+04 140 prehnite-Fe 22.50 20.28 -2.22 -0.133 0.37881E+04 145 pyrite -21.25 -21.61 -0.36 -0.085 0.61548E+03 146 pyrrhotite -4.26 -6.19 -1.93 -0.642 0.32877E+04 147 pyrrhotiteFe0.875 -6.02 -7.34 -1.32 -0.486 0.22550E+04 148 pyroxmangite 7.40 6.17 -1.23 -0.246 0.21008E+04 149 pyrophyllite -6.18 -10.83 -4.65 -0.291 0.79469E+04 154 rhodochrosite -0.98 -3.32 -2.34 -0.782 0.40034E+04 155 rhodonite 7.45 6.17 -1.28 -0.255 0.21811E+04 156 sanidine -1.28 -2.50 -1.23 -0.094 0.20955E+04 158 siderite -2.61 -5.91 -3.30 -1.100 0.56343E+04 166 stilbite -7.52 -8.08 -0.55 -0.026 0.94512E+03 168 stilpnomelane-Mg 27.44 23.21 -4.24 -0.126 0.72313E+04 174 talc 16.49 13.87 -2.62 -0.154 0.44785E+04 177 tephroite 18.09 15.33 -2.76 -0.394 0.47122E+04 181 tridymite -2.63 -2.99 -0.36 -0.121 0.61998E+03 184 troilite-low -4.41 -6.19 -1.77 -0.592 0.30305E+04 190 wairakite 3.95 0.89 -3.06 -0.180 0.52210E+04 191 walstromite 11.51 8.73 -2.78 -0.555 0.47398E+04 192 wollastonite 10.46 8.73 -1.73 -0.346 0.29503E+04 193 pseudo-wollastonite 11.00 8.73 -2.27 -0.453 0.38701E+04 195 akaganeite 7.75 5.24 -2.52 -0.544 0.42965E+04 202 chalcedony -2.80 -2.99 -0.19 -0.062 0.31930E+03 204 montmorillonite-Ca -2.29 -6.24 -3.95 -0.244 0.67449E+04 205 montmorillonite-K -2.24 -6.23 -3.99 -0.244 0.68144E+04 206 montmorillonite-Mg -2.48 -6.75 -4.27 -0.264 0.72993E+04 207 montmorillonite-Na -2.04 -5.53 -3.49 -0.214 0.59602E+04 208 nontronite-Ca 3.21 1.63 -1.59 -0.103 0.27130E+04 209 nontronite-H 2.53 -0.31 -2.84 -0.190 0.48514E+04 210 nontronite-K 3.34 1.64 -1.70 -0.109 0.29057E+04 211 nontronite-Mg 3.07 1.11 -1.96 -0.127 0.33514E+04 212 nontronite-Na 3.52 2.34 -1.18 -0.076 0.20174E+04 228 tobermorite 9.82 6.78 -3.05 -0.832 0.52035E+04 234 alabandite -0.98 -3.60 -2.62 -0.874 0.44752E+04 237 boehmite 4.41 0.56 -3.84 -0.640 0.65609E+04 239 ferrous-oxide 9.81 6.57 -3.24 -0.810 0.55336E+04 245 silica-amorphous -2.09 -2.99 -0.90 -0.299 0.15335E+04 247 an20ab80 2.02 1.07 -0.95 -0.073 0.16230E+04 248 an25ab75 2.65 1.43 -1.22 -0.094 0.20758E+04 249 an30ab70 3.28 1.79 -1.49 -0.114 0.25381E+04 250 tr.625ac.25prg.125 45.16 40.91 -4.25 -0.115 0.72629E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 0.0020000 MOLES Current total amount of reactant added: 0.0579900 MOLES New total amount of reactant added: 0.0599900 MOLES Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.5508E-08 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 7 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 0.0599900 Water: Moles liquid = 0.4991E+02 kg liquid = 0.8991E+00 Moles total = 0.4990E+02 kg total = 0.8989E+00 Activity = 1.0000 Stoichiometric ionic strength = .1521020E-01 Osmotic coef. = 0.9291 True ionic strength = .2335804E-01 Chg. balance for total moles = -.5508E-08 Max. difference allowed = 0.4918E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.19972E-09 -9.6996 0.16620E-09 -9.7794 0.83215E+00 -0.0798 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.54449E-03 -3.2640 0.45002E-03 -3.3468 0.82651E+00 -0.0828 4 SO4-- 0.30163E-03 -3.5205 0.15033E-03 -3.8230 0.49838E+00 -0.3024 5 HCO3- 0.25800E-02 -2.5884 0.21359E-02 -2.6704 0.82787E+00 -0.0820 6 HS- 0.13472E-02 -2.8706 0.11136E-02 -2.9533 0.82665E+00 -0.0827 7 Al+++ 0.81731E-28 -28.0876 0.17181E-28 -28.7649 0.21022E+00 -0.6773 8 H4SiO4 0.10246E-02 -2.9894 0.10246E-02 -2.9894 0.10000E+01 0.0000 9 Ca++ 0.27726E-07 -7.5571 0.13703E-07 -7.8632 0.49425E+00 -0.3061 10 Mg++ 0.21776E-10 -10.6620 0.10707E-10 -10.9703 0.49170E+00 -0.3083 11 Fe++ 0.20753E-12 -12.6829 0.10217E-12 -12.9907 0.49231E+00 -0.3078 12 K+ 0.15638E-03 -3.8058 0.12950E-03 -3.8877 0.82809E+00 -0.0819 13 Na+ 0.20642E-01 -1.6852 0.17057E-01 -1.7681 0.82633E+00 -0.0828 14 Mn++ 0.79909E-10 -10.0974 0.39377E-10 -10.4048 0.49277E+00 -0.3074 15 F- 0.26713E-04 -4.5733 0.22027E-04 -4.6570 0.82459E+00 -0.0838 16 HPO4-- 0.45779E-07 -7.3393 0.22819E-07 -7.6417 0.49846E+00 -0.3024 18 HSiO3- 0.69649E-02 -2.1571 0.57565E-02 -2.2398 0.82651E+00 -0.0828 19 Ca(HSiO3)+ 0.21689E-08 -8.6638 0.17965E-08 -8.7456 0.82829E+00 -0.0818 20 Mg(HSiO3)+ 0.21090E-11 -11.6759 0.17469E-11 -11.7577 0.82829E+00 -0.0818 21 NaHSiO3,aq 0.15881E-02 -2.7991 0.15881E-02 -2.7991 0.10000E+01 0.0000 22 AlO+ 0.10216E-15 -15.9907 0.84619E-16 -16.0725 0.82829E+00 -0.0818 24 HAlO2,aq 0.10139E-09 -9.9940 0.10139E-09 -9.9940 0.10000E+01 0.0000 25 AlO2- 0.16372E-05 -5.7859 0.13504E-05 -5.8695 0.82483E+00 -0.0836 26 CH4,aq 0.15441E-07 -7.8113 0.15370E-07 -7.8133 0.99539E+00 -0.0020 27 C2H6,aq 0.23173E-18 -18.6350 0.23066E-18 -18.6370 0.99539E+00 -0.0020 31 CO,aq 0.33362E-14 -14.4767 0.33362E-14 -14.4767 0.10000E+01 0.0000 32 CO2,aq 0.76204E-06 -6.1180 0.75852E-06 -6.1200 0.99539E+00 -0.0020 33 CO3-2 0.22577E-02 -2.6463 0.11225E-02 -2.9498 0.49719E+00 -0.3035 34 CaCO3,aq 0.19288E-06 -6.7147 0.19288E-06 -6.7147 0.10000E+01 0.0000 35 Ca(HCO3)+ 0.90201E-09 -9.0448 0.74713E-09 -9.1266 0.82829E+00 -0.0818 36 CaCl+ 0.12049E-10 -10.9191 0.99799E-11 -11.0009 0.82829E+00 -0.0818 37 CaCl2,aq 0.10670E-14 -14.9718 0.10670E-14 -14.9718 0.10000E+01 0.0000 38 CaF+ 0.53206E-11 -11.2740 0.44070E-11 -11.3559 0.82829E+00 -0.0818 39 CaOH+ 0.70945E-08 -8.1491 0.58763E-08 -8.2309 0.82829E+00 -0.0818 40 CaSO4,aq 0.65415E-09 -9.1843 0.65415E-09 -9.1843 0.10000E+01 0.0000 41 HCl,aq 0.13706E-13 -13.8631 0.13706E-13 -13.8631 0.10000E+01 0.0000 45 HF,aq 0.25062E-10 -10.6010 0.25062E-10 -10.6010 0.10000E+01 0.0000 46 HF2- 0.22550E-15 -15.6468 0.18638E-15 -15.7296 0.82651E+00 -0.0828 48 FeCl+ 0.87864E-16 -16.0562 0.72777E-16 -16.1380 0.82829E+00 -0.0818 51 FeF+ 0.13885E-15 -15.8575 0.11501E-15 -15.9393 0.82829E+00 -0.0818 53 FeO,aq 0.14376E-09 -9.8424 0.14376E-09 -9.8424 0.10000E+01 0.0000 54 FeOH+ 0.24159E-10 -10.6169 0.20011E-10 -10.6987 0.82829E+00 -0.0818 55 HFeO2- 0.10950E-07 -7.9606 0.90502E-08 -8.0433 0.82651E+00 -0.0828 56 FeO+ 0.13771E-15 -15.8610 0.11407E-15 -15.9428 0.82829E+00 -0.0818 58 FeO2- 0.10223E-08 -8.9904 0.84498E-09 -9.0732 0.82651E+00 -0.0828 59 HFeO2,aq 0.17861E-10 -10.7481 0.17861E-10 -10.7481 0.10000E+01 0.0000 60 H2,aq 0.17590E-06 -6.7547 0.17509E-06 -6.7567 0.99539E+00 -0.0020 61 KCl,aq 0.10562E-08 -8.9762 0.10562E-08 -8.9762 0.10000E+01 0.0000 62 KHSO4,aq 0.91478E-17 -17.0387 0.91478E-17 -17.0387 0.10000E+01 0.0000 63 KOH,aq 0.33275E-06 -6.4779 0.33275E-06 -6.4779 0.10000E+01 0.0000 64 KSO4- 0.36549E-06 -6.4371 0.30208E-06 -6.5199 0.82651E+00 -0.0828 65 MgCO3,aq 0.37775E-10 -10.4228 0.37775E-10 -10.4228 0.10000E+01 0.0000 66 Mg(HCO3)+ 0.72015E-12 -12.1426 0.59649E-12 -12.2244 0.82829E+00 -0.0818 67 MgCl+ 0.85325E-14 -14.0689 0.70674E-14 -14.1507 0.82829E+00 -0.0818 68 MgF+ 0.15400E-13 -13.8125 0.12755E-13 -13.8943 0.82829E+00 -0.0818 69 MgOH+ 0.30673E-10 -10.5132 0.25406E-10 -10.5951 0.82829E+00 -0.0818 71 MnF+ 0.17638E-13 -13.7535 0.14609E-13 -13.8354 0.82829E+00 -0.0818 72 MnO,aq 0.14763E-08 -8.8308 0.14763E-08 -8.8308 0.10000E+01 0.0000 73 MnOH+ 0.86495E-09 -9.0630 0.71643E-09 -9.1448 0.82829E+00 -0.0818 74 MnO2-2 0.35674E-11 -11.4476 0.17737E-11 -11.7511 0.49719E+00 -0.3035 75 HMnO2- 0.78140E-10 -10.1071 0.64583E-10 -10.1899 0.82651E+00 -0.0828 78 MnCl+ 0.13174E-12 -12.8803 0.10912E-12 -12.9621 0.82829E+00 -0.0818 79 MnSO4,aq 0.17089E-11 -11.7673 0.17089E-11 -11.7673 0.10000E+01 0.0000 80 NaCl,aq 0.25439E-05 -5.5945 0.25439E-05 -5.5945 0.10000E+01 0.0000 81 NaF,aq 0.87964E-07 -7.0557 0.87964E-07 -7.0557 0.10000E+01 0.0000 82 NaOH,aq 0.44095E-04 -4.3556 0.44095E-04 -4.3556 0.10000E+01 0.0000 84 OH- 0.42146E-02 -2.3752 0.34764E-02 -2.4589 0.82483E+00 -0.0836 89 HPO3-2 0.25042E-16 -16.6013 0.12451E-16 -16.9048 0.49719E+00 -0.3035 92 H3PO4,aq 0.44084E-17 -17.3557 0.44084E-17 -17.3557 0.10000E+01 0.0000 93 H2PO4- 0.84557E-10 -10.0728 0.69962E-10 -10.1551 0.82739E+00 -0.0823 94 PO4-3 0.50419E-09 -9.2974 0.11202E-09 -9.9507 0.22218E+00 -0.6533 98 HP2O7-3 0.21908E-17 -17.6594 0.46110E-18 -18.3362 0.21047E+00 -0.6768 99 P2O7-4 0.10129E-16 -16.9944 0.66278E-18 -18.1786 0.65434E-01 -1.1842 100 H2S,aq 0.57468E-06 -6.2406 0.57203E-06 -6.2426 0.99539E+00 -0.0020 101 S2-2 0.31568E-09 -9.5008 0.15695E-09 -9.8042 0.49719E+00 -0.3035 102 S3-2 0.13895E-14 -14.8571 0.69086E-15 -15.1606 0.49719E+00 -0.3035 103 S3- 0.22255E-18 -18.6526 0.18394E-18 -18.7353 0.82651E+00 -0.0828 107 SO3-2 0.67689E-11 -11.1695 0.34203E-11 -11.4659 0.50530E+00 -0.2964 108 HSO3- 0.43064E-13 -13.3659 0.35593E-13 -13.4486 0.82651E+00 -0.0828 109 HSO4- 0.29038E-10 -10.5370 0.24078E-10 -10.6184 0.82921E+00 -0.0813 111 S2O3-2 0.20317E-11 -11.6921 0.10101E-11 -11.9956 0.49719E+00 -0.3035 112 HS2O3- 0.36320E-19 -19.4399 0.30018E-19 -19.5226 0.82651E+00 -0.0828 Charge balance for all species = -.6126E-08 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.1997247E-09 -.1507523E-01 -.1516864E+02 0.0000 2 H2O 0.1000000E+01 0.5550396E+02 0.9981907E+06 0.0000 3 Cl- 0.5444856E-03 0.5470305E-03 0.1936032E+02 6.4326 4 SO4-- 0.3016313E-03 0.3019383E-03 0.2895450E+02 15.7358 5 HCO3- 0.2579982E-02 0.4838655E-02 0.2947305E+03 7.1089 6 HS- 0.1347179E-02 0.1347813E-02 0.4449777E+02 6.8261 7 Al+++ 0.8173089E-28 0.1637332E-05 0.4410125E-01 0.5732 8 H4SiO4 0.1024625E-02 0.9577582E-02 0.9189607E+03 -2.9894 9 Ca++ 0.2772575E-07 0.2314400E-06 0.9259607E-02 11.6956 10 Mg++ 0.2177553E-10 0.9307638E-10 0.2258958E-05 8.5884 11 Fe++ 0.2075342E-12 0.1215822E-07 0.6778257E-03 6.5681 12 K+ 0.1563801E-03 0.1570794E-03 0.6131494E+01 5.8916 13 Na+ 0.2064218E-01 0.2227701E-01 0.5112581E+03 8.0113 14 Mn++ 0.7990943E-10 0.2504710E-08 0.1373657E-03 9.1540 15 F- 0.2671268E-04 0.2680068E-04 0.5082784E+00 5.1223 16 HPO4-- 0.4577877E-07 0.4636752E-07 0.4442609E-02 11.9170 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.1356712E-01 -.1355387E-01 -.1324985E-04 0.0000000E+00 2 H2O 0.4989552E+02 0.4990260E+02 -.7077328E-02 0.0000000E+00 3 Cl- 0.4918252E-03 0.4918252E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.2714672E-03 0.2714672E-03 0.0000000E+00 0.0000000E+00 5 HCO3- 0.4350347E-02 0.4350347E-02 0.0000000E+00 0.0000000E+00 6 HS- 0.1211794E-02 0.1211794E-02 0.0000000E+00 0.0000000E+00 7 Al+++ 0.4775352E-05 0.1472095E-05 0.3303257E-05 0.0000000E+00 8 H4SiO4 0.1215302E-01 0.8611030E-02 0.3541990E-02 0.0000000E+00 9 Ca++ 0.2080835E-06 0.2080835E-06 0.0000000E+00 0.0000000E+00 10 Mg++ 0.8368328E-10 0.8368328E-10 0.0000000E+00 0.0000000E+00 11 Fe++ 0.3259227E-07 0.1093124E-07 0.2166103E-07 0.0000000E+00 12 K+ 0.1412294E-03 0.1412272E-03 0.2166103E-08 0.0000000E+00 13 Na+ 0.2003215E-01 0.2002886E-01 0.3294592E-05 0.0000000E+00 14 Mn++ 0.2251939E-08 0.2251939E-08 0.0000000E+00 0.0000000E+00 15 F- 0.2409600E-04 0.2409600E-04 0.0000000E+00 0.0000000E+00 16 HPO4-- 0.4168819E-07 0.4168819E-07 0.0000000E+00 0.0000000E+00 Chg. balance for solid moles: 0.4235E-21 Mass of aqueous solution: 0.900640E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 0.0599900 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 0.3295E-05 -5.482 0.8639E-03 -3.064 0.4054 0.3316E-03 quartz 0.3532E-02 -2.452 0.2122 -0.673 99.59 0.8014E-01 stilpnomelane-Fe 0.4332E-08 -8.363 0.4670E-05 -5.331 0.2192E-02 0.1613E-05 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 quartz 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 0.213075 g Volume = 0.080472 cm3 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.0599900 moles log = -1.2219 Original solution: 1000.0103000 g Original solution / Rock added: 16669.62 (Water/Rock Ratio), log = 4.2219 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0206 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9997E+00 0.9859 0.1006E+01 0.1020E+01 CO2,gas 0.7895E-04 1.0071 0.8115E-04 0.8058E-04 CH4,gas 0.2189E-04 1.0125 0.2262E-04 0.2234E-04 H2,gas 0.2251E-03 1.0005 0.2299E-03 0.2297E-03 H2S,gas 0.1547E-04 0.9960 0.1572E-04 0.1579E-04 S2,gas 0.1721E-21 1.0000 0.1757E-21 0.1757E-21 CO,gas 0.4871E-11 1.0000 0.4972E-11 0.4972E-11 SO3,gas 0.1538E-38 1.0000 0.1570E-38 0.1570E-38 SO2,gas 0.1376E-19 1.0000 0.1404E-19 0.1404E-19 HF,gas 0.6029E-13 1.0000 0.6153E-13 0.6153E-13 HCl,gas 0.2369E-16 1.0000 0.2418E-16 0.2418E-16 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 17 albite -0.38 -0.38 0.00 0.000 0.11184E-10 150 quartz -2.99 -2.99 0.00 0.000 0.00000E+00 167 stilpnomelane-Fe 13.02 13.02 0.00 0.000 -0.27298E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -12.45 -5.79 -1.930 0.98857E+04 -4.091 3 CH4,gas 4.54 -1.80 -6.34 -1.586 0.10833E+05 -4.645 4 H2,gas 8.00 2.66 -5.34 -3.050 0.91136E+04 -3.639 5 H2S,gas -6.23 -12.73 -6.50 -3.251 0.11103E+05 -4.803 6 S2,gas -7.34 -30.79 -23.45 -3.608 0.40048E+05 -21.755 7 CO,gas 3.21 -9.79 -13.00 -4.001 0.22201E+05 -11.304 8 SO3,gas 17.12 -23.38 -40.50 -10.126 0.69158E+05 -38.804 9 SO2,gas 0.83 -20.72 -21.55 -5.747 0.36799E+05 -19.853 10 HF,gas 0.47 -14.44 -14.91 -7.455 0.25458E+05 -13.211 11 HCl,gas 5.19 -13.13 -18.32 -9.158 0.31273E+05 -16.616 12 acmite 7.71 7.27 -0.44 -0.046 0.75193E+03 16 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 20 spessartine 24.46 19.64 -4.82 -0.241 0.82256E+04 21 analcite 3.32 2.61 -0.72 -0.080 0.12231E+04 23 andradite 39.01 36.59 -2.42 -0.126 0.41261E+04 26 ankerite -2.14 -6.64 -4.50 -0.750 0.76851E+04 27 annite 20.12 17.20 -2.92 -0.162 0.49905E+04 28 phlogopite 27.06 23.26 -3.80 -0.211 0.64933E+04 33 apatite-OH -18.15 -23.12 -4.97 -0.382 0.84861E+04 34 apatite-F -34.30 -37.56 -3.26 -0.272 0.55645E+04 38 aragonite 0.97 -0.75 -1.72 -0.574 0.29381E+04 39 brucite 12.57 8.59 -3.98 -0.796 0.67960E+04 40 calcite 0.81 -0.75 -1.57 -0.522 0.26739E+04 41 carnegieite-low 9.02 5.60 -3.43 -0.490 0.58537E+04 42 carnegieite-high 10.09 5.60 -4.50 -0.643 0.76807E+04 43 carpholite-Mg 8.58 3.76 -4.83 -0.322 0.82407E+04 44 carpholite-Fe 6.71 1.74 -4.98 -0.332 0.84983E+04 45 celadonite 5.34 3.10 -2.25 -0.132 0.38352E+04 46 celadonite-Fe 3.88 1.08 -2.80 -0.165 0.47833E+04 47 chrysotile 23.89 19.79 -4.11 -0.342 0.70110E+04 49 clinochlore 39.07 35.12 -3.95 -0.123 0.67436E+04 50 daphnite 28.97 25.02 -3.95 -0.123 0.67392E+04 54 chloritoid-Fe 9.17 4.72 -4.45 -0.297 0.75960E+04 55 chloritoid-Mn 11.40 7.31 -4.09 -0.273 0.69839E+04 57 coesite -2.38 -2.99 -0.61 -0.204 0.10473E+04 64 cristobalite -2.56 -2.99 -0.43 -0.143 0.73267E+03 66 cymrite-K 1.69 -2.50 -4.19 -0.349 0.71525E+04 68 diaspore 2.87 0.57 -2.30 -0.383 0.39281E+04 69 diamond -3.10 -7.13 -4.02 -1.149 0.68689E+04 70 diopside 16.18 14.31 -1.88 -0.188 0.32037E+04 71 hedenbergite 14.21 12.28 -1.92 -0.192 0.32844E+04 78 epidote 24.67 20.81 -3.86 -0.187 0.65974E+04 80 epidote-Fe 29.84 25.47 -4.37 -0.227 0.74633E+04 81 fayalite 14.05 10.15 -3.90 -0.557 0.66575E+04 82 ferrosilite 11.15 7.16 -3.99 -0.399 0.68166E+04 86 gibbsite 4.08 0.57 -3.51 -0.501 0.59867E+04 87 glaucophane 22.97 19.02 -3.96 -0.107 0.67551E+04 88 glaucophane-Fe 17.28 12.96 -4.32 -0.117 0.73733E+04 89 graphite -3.55 -7.13 -3.58 -1.023 0.61112E+04 90 greenalite 16.14 13.73 -2.41 -0.201 0.41222E+04 93 hematite 12.57 10.47 -2.09 -0.254 0.35726E+04 94 heulandite -5.83 -8.08 -2.26 -0.103 0.38536E+04 98 jadeite 4.22 2.61 -1.61 -0.161 0.27485E+04 100 kalsilite 7.58 3.48 -4.11 -0.587 0.70152E+04 101 kaolinite -1.33 -4.83 -3.50 -0.318 0.59758E+04 104 laumontite 2.88 0.88 -2.00 -0.133 0.34137E+04 105 lawsonite 9.62 6.86 -2.75 -0.184 0.47008E+04 106 leucite 4.12 0.49 -3.63 -0.363 0.62032E+04 108 lizardite 23.24 19.79 -3.46 -0.288 0.59036E+04 109 magnesite 0.69 -3.86 -4.55 -1.517 0.77724E+04 110 magnetite 20.09 17.04 -3.05 -0.249 0.52001E+04 111 minnesotaite 10.39 7.75 -2.64 -0.155 0.45106E+04 115 manganosite 14.06 9.15 -4.90 -1.226 0.83737E+04 119 microcline -2.49 -2.50 -0.02 -0.001 0.29068E+02 123 muscovite 2.58 -1.36 -3.94 -0.232 0.67268E+04 124 paragonite 4.24 0.76 -3.48 -0.205 0.59368E+04 125 nepheline 8.34 5.60 -2.74 -0.392 0.46861E+04 137 phlogopite-Na 29.65 25.38 -4.27 -0.237 0.72831E+04 139 prehnite 19.37 15.57 -3.80 -0.224 0.64931E+04 140 prehnite-Fe 22.50 20.23 -2.26 -0.136 0.38673E+04 145 pyrite -21.25 -21.56 -0.31 -0.074 0.53362E+03 146 pyrrhotite -4.26 -6.16 -1.90 -0.635 0.32514E+04 147 pyrrhotiteFe0.875 -6.02 -7.32 -1.30 -0.478 0.22176E+04 148 pyroxmangite 7.40 6.16 -1.23 -0.247 0.21073E+04 149 pyrophyllite -6.18 -10.81 -4.64 -0.290 0.79152E+04 154 rhodochrosite -0.98 -3.30 -2.32 -0.773 0.39605E+04 155 rhodonite 7.45 6.16 -1.28 -0.256 0.21875E+04 156 sanidine -1.28 -2.50 -1.23 -0.094 0.20968E+04 158 siderite -2.61 -5.88 -3.27 -1.091 0.55895E+04 166 stilbite -7.52 -8.08 -0.56 -0.027 0.95979E+03 168 stilpnomelane-Mg 27.44 23.12 -4.32 -0.129 0.73809E+04 174 talc 16.49 13.81 -2.68 -0.158 0.45822E+04 177 tephroite 18.09 15.32 -2.77 -0.395 0.47250E+04 181 tridymite -2.63 -2.99 -0.36 -0.121 0.61998E+03 184 troilite-low -4.41 -6.16 -1.75 -0.585 0.29942E+04 190 wairakite 3.95 0.88 -3.07 -0.180 0.52357E+04 191 walstromite 11.51 8.71 -2.80 -0.561 0.47862E+04 192 wollastonite 10.46 8.71 -1.76 -0.351 0.29966E+04 193 pseudo-wollastonite 11.00 8.71 -2.29 -0.459 0.39165E+04 195 akaganeite 7.75 5.24 -2.52 -0.544 0.42988E+04 202 chalcedony -2.80 -2.99 -0.19 -0.062 0.31930E+03 204 montmorillonite-Ca -2.29 -6.24 -3.95 -0.244 0.67375E+04 205 montmorillonite-K -2.24 -6.22 -3.99 -0.244 0.68050E+04 206 montmorillonite-Mg -2.48 -6.75 -4.27 -0.264 0.72899E+04 207 montmorillonite-Na -2.04 -5.52 -3.48 -0.213 0.59503E+04 208 nontronite-Ca 3.21 1.62 -1.59 -0.103 0.27200E+04 209 nontronite-H 2.53 -0.31 -2.84 -0.190 0.48508E+04 210 nontronite-K 3.34 1.64 -1.70 -0.109 0.29107E+04 211 nontronite-Mg 3.07 1.11 -1.97 -0.128 0.33565E+04 212 nontronite-Na 3.52 2.34 -1.18 -0.076 0.20220E+04 228 tobermorite 9.82 6.75 -3.07 -0.838 0.52421E+04 234 alabandite -0.98 -3.58 -2.60 -0.867 0.44408E+04 237 boehmite 4.41 0.57 -3.83 -0.639 0.65450E+04 239 ferrous-oxide 9.81 6.57 -3.24 -0.811 0.55382E+04 245 silica-amorphous -2.09 -2.99 -0.90 -0.299 0.15335E+04 247 an20ab80 2.02 1.07 -0.95 -0.073 0.16260E+04 248 an25ab75 2.65 1.43 -1.22 -0.094 0.20794E+04 249 an30ab70 3.28 1.79 -1.49 -0.115 0.25425E+04 250 tr.625ac.25prg.125 45.16 40.78 -4.38 -0.118 0.74827E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 0.0020000 MOLES Current total amount of reactant added: 0.0599900 MOLES New total amount of reactant added: 0.0619900 MOLES Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.5508E-08 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 7 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 0.0619900 Water: Moles liquid = 0.4991E+02 kg liquid = 0.8991E+00 Moles total = 0.4990E+02 kg total = 0.8989E+00 Activity = 1.0000 Stoichiometric ionic strength = .1533998E-01 Osmotic coef. = 0.9288 True ionic strength = .2345002E-01 Chg. balance for total moles = -.5508E-08 Max. difference allowed = 0.5036E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.20444E-09 -9.6894 0.17008E-09 -9.7693 0.83194E+00 -0.0799 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.55752E-03 -3.2537 0.46067E-03 -3.3366 0.82628E+00 -0.0829 4 SO4-- 0.31223E-03 -3.5055 0.15544E-03 -3.8084 0.49785E+00 -0.3029 5 HCO3- 0.26933E-02 -2.5697 0.22291E-02 -2.6519 0.82765E+00 -0.0822 6 HS- 0.13905E-02 -2.8568 0.11492E-02 -2.9396 0.82642E+00 -0.0828 7 Al+++ 0.89737E-28 -28.0470 0.18818E-28 -28.7254 0.20970E+00 -0.6784 8 H4SiO4 0.10246E-02 -2.9894 0.10246E-02 -2.9894 0.10000E+01 0.0000 9 Ca++ 0.27318E-07 -7.5636 0.13487E-07 -7.8701 0.49371E+00 -0.3065 10 Mg++ 0.21784E-10 -10.6619 0.10699E-10 -10.9707 0.49115E+00 -0.3088 11 Fe++ 0.21621E-12 -12.6651 0.10632E-12 -12.9734 0.49176E+00 -0.3082 12 K+ 0.15637E-03 -3.8058 0.12945E-03 -3.8879 0.82787E+00 -0.0820 13 Na+ 0.20676E-01 -1.6845 0.17081E-01 -1.7675 0.82611E+00 -0.0830 14 Mn++ 0.83029E-10 -10.0808 0.40869E-10 -10.3886 0.49222E+00 -0.3078 15 F- 0.27598E-04 -4.5591 0.22751E-04 -4.6430 0.82436E+00 -0.0839 16 HPO4-- 0.45786E-07 -7.3393 0.22798E-07 -7.6421 0.49793E+00 -0.3028 18 HSiO3- 0.68077E-02 -2.1670 0.56251E-02 -2.2499 0.82628E+00 -0.0829 19 Ca(HSiO3)+ 0.20865E-08 -8.6806 0.17277E-08 -8.7625 0.82807E+00 -0.0819 20 Mg(HSiO3)+ 0.20599E-11 -11.6862 0.17057E-11 -11.7681 0.82807E+00 -0.0819 21 NaHSiO3,aq 0.15540E-02 -2.8086 0.15540E-02 -2.8086 0.10000E+01 0.0000 22 AlO+ 0.10687E-15 -15.9711 0.88496E-16 -16.0531 0.82807E+00 -0.0819 24 HAlO2,aq 0.10362E-09 -9.9846 0.10362E-09 -9.9846 0.10000E+01 0.0000 25 AlO2- 0.16354E-05 -5.7864 0.13486E-05 -5.8701 0.82460E+00 -0.0838 26 CH4,aq 0.16083E-07 -7.7936 0.16008E-07 -7.7957 0.99535E+00 -0.0020 27 C2H6,aq 0.25296E-18 -18.5969 0.25178E-18 -18.5990 0.99535E+00 -0.0020 31 CO,aq 0.35408E-14 -14.4509 0.35408E-14 -14.4509 0.10000E+01 0.0000 32 CO2,aq 0.81391E-06 -6.0894 0.81012E-06 -6.0914 0.99535E+00 -0.0020 33 CO3-2 0.23050E-02 -2.6373 0.11448E-02 -2.9413 0.49666E+00 -0.3039 34 CaCO3,aq 0.19359E-06 -6.7131 0.19359E-06 -6.7131 0.10000E+01 0.0000 35 Ca(HCO3)+ 0.92675E-09 -9.0330 0.76741E-09 -9.1150 0.82807E+00 -0.0819 36 CaCl+ 0.12142E-10 -10.9157 0.10055E-10 -10.9976 0.82807E+00 -0.0819 37 CaCl2,aq 0.11004E-14 -14.9584 0.11004E-14 -14.9584 0.10000E+01 0.0000 38 CaF+ 0.54101E-11 -11.2668 0.44799E-11 -11.3487 0.82807E+00 -0.0819 39 CaOH+ 0.68248E-08 -8.1659 0.56514E-08 -8.2478 0.82807E+00 -0.0819 40 CaSO4,aq 0.66572E-09 -9.1767 0.66572E-09 -9.1767 0.10000E+01 0.0000 41 HCl,aq 0.14358E-13 -13.8429 0.14358E-13 -13.8429 0.10000E+01 0.0000 45 HF,aq 0.26490E-10 -10.5769 0.26490E-10 -10.5769 0.10000E+01 0.0000 46 HF2- 0.24626E-15 -15.6086 0.20348E-15 -15.6915 0.82628E+00 -0.0829 48 FeCl+ 0.93625E-16 -16.0286 0.77528E-16 -16.1105 0.82807E+00 -0.0819 51 FeF+ 0.14928E-15 -15.8260 0.12361E-15 -15.9079 0.82807E+00 -0.0819 53 FeO,aq 0.14285E-09 -9.8451 0.14285E-09 -9.8451 0.10000E+01 0.0000 54 FeOH+ 0.24573E-10 -10.6095 0.20349E-10 -10.6915 0.82807E+00 -0.0819 55 HFeO2- 0.10635E-07 -7.9733 0.87877E-08 -8.0561 0.82628E+00 -0.0829 56 FeO+ 0.14052E-15 -15.8523 0.11636E-15 -15.9342 0.82807E+00 -0.0819 58 FeO2- 0.99609E-09 -9.0017 0.82305E-09 -9.0846 0.82628E+00 -0.0829 59 HFeO2,aq 0.17804E-10 -10.7495 0.17804E-10 -10.7495 0.10000E+01 0.0000 60 H2,aq 0.17480E-06 -6.7575 0.17399E-06 -6.7595 0.99535E+00 -0.0020 61 KCl,aq 0.10809E-08 -8.9662 0.10809E-08 -8.9662 0.10000E+01 0.0000 62 KHSO4,aq 0.96768E-17 -17.0143 0.96768E-17 -17.0143 0.10000E+01 0.0000 63 KOH,aq 0.32504E-06 -6.4881 0.32504E-06 -6.4881 0.10000E+01 0.0000 64 KSO4- 0.37790E-06 -6.4226 0.31226E-06 -6.5055 0.82628E+00 -0.0829 65 MgCO3,aq 0.38495E-10 -10.4146 0.38495E-10 -10.4146 0.10000E+01 0.0000 66 Mg(HCO3)+ 0.75122E-12 -12.1242 0.62207E-12 -12.2062 0.82807E+00 -0.0819 67 MgCl+ 0.87303E-14 -14.0590 0.72293E-14 -14.1409 0.82807E+00 -0.0819 68 MgF+ 0.15898E-13 -13.7987 0.13165E-13 -13.8806 0.82807E+00 -0.0819 69 MgOH+ 0.29959E-10 -10.5235 0.24808E-10 -10.6054 0.82807E+00 -0.0819 71 MnF+ 0.18913E-13 -13.7232 0.15661E-13 -13.8052 0.82807E+00 -0.0819 72 MnO,aq 0.14631E-08 -8.8347 0.14631E-08 -8.8347 0.10000E+01 0.0000 73 MnOH+ 0.87746E-09 -9.0568 0.72660E-09 -9.1387 0.82807E+00 -0.0819 74 MnO2-2 0.33795E-11 -11.4711 0.16785E-11 -11.7751 0.49666E+00 -0.3039 75 HMnO2- 0.75693E-10 -10.1209 0.62544E-10 -10.2038 0.82628E+00 -0.0829 78 MnCl+ 0.14001E-12 -12.8538 0.11594E-12 -12.9358 0.82807E+00 -0.0819 79 MnSO4,aq 0.18340E-11 -11.7366 0.18340E-11 -11.7366 0.10000E+01 0.0000 80 NaCl,aq 0.26077E-05 -5.5837 0.26077E-05 -5.5837 0.10000E+01 0.0000 81 NaF,aq 0.90980E-07 -7.0411 0.90980E-07 -7.0411 0.10000E+01 0.0000 82 NaOH,aq 0.43148E-04 -4.3650 0.43148E-04 -4.3650 0.10000E+01 0.0000 84 OH- 0.41196E-02 -2.3851 0.33970E-02 -2.4689 0.82460E+00 -0.0838 89 HPO3-2 0.24889E-16 -16.6040 0.12361E-16 -16.9079 0.49666E+00 -0.3039 92 H3PO4,aq 0.46126E-17 -17.3361 0.46126E-17 -17.3361 0.10000E+01 0.0000 93 H2PO4- 0.86477E-10 -10.0631 0.71531E-10 -10.1455 0.82717E+00 -0.0824 94 PO4-3 0.49336E-09 -9.3068 0.10936E-09 -9.9611 0.22167E+00 -0.6543 98 HP2O7-3 0.22434E-17 -17.6491 0.47100E-18 -18.3270 0.20995E+00 -0.6779 99 P2O7-4 0.10154E-16 -16.9934 0.66157E-18 -18.1794 0.65154E-01 -1.1861 100 H2S,aq 0.60689E-06 -6.2169 0.60407E-06 -6.2189 0.99535E+00 -0.0020 101 S2-2 0.33862E-09 -9.4703 0.16818E-09 -9.7742 0.49666E+00 -0.3039 102 S3-2 0.15839E-14 -14.8003 0.78666E-15 -15.1042 0.49666E+00 -0.3039 103 S3- 0.26022E-18 -18.5847 0.21502E-18 -18.6675 0.82628E+00 -0.0829 107 SO3-2 0.69625E-11 -11.1572 0.35145E-11 -11.4541 0.50478E+00 -0.2969 108 HSO3- 0.45296E-13 -13.3439 0.37427E-13 -13.4268 0.82628E+00 -0.0829 109 HSO4- 0.30735E-10 -10.5124 0.25479E-10 -10.5938 0.82899E+00 -0.0815 111 S2O3-2 0.22209E-11 -11.6535 0.11030E-11 -11.9574 0.49666E+00 -0.3039 112 HS2O3- 0.40596E-19 -19.3915 0.33544E-19 -19.4744 0.82628E+00 -0.0829 Charge balance for all species = -.6126E-08 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.2044419E-09 -.1483514E-01 -.1492712E+02 0.0000 2 H2O 0.1000000E+01 0.5550405E+02 0.9981961E+06 0.0000 3 Cl- 0.5575250E-03 0.5601338E-03 0.1982414E+02 6.4327 4 SO4-- 0.3122293E-03 0.3125483E-03 0.2997207E+02 15.7303 5 HCO3- 0.2693318E-02 0.4999296E-02 0.3045165E+03 7.1175 6 HS- 0.1390526E-02 0.1391194E-02 0.4593013E+02 6.8297 7 Al+++ 0.8973726E-28 0.1635535E-05 0.4405301E-01 0.5826 8 H4SiO4 0.1024625E-02 0.9386343E-02 0.9006148E+03 -2.9894 9 Ca++ 0.2731756E-07 0.2314312E-06 0.9259289E-02 11.6686 10 Mg++ 0.2178360E-10 0.9307285E-10 0.2258881E-05 8.5680 11 Fe++ 0.2162096E-12 0.1181673E-07 0.6587896E-03 6.5653 12 K+ 0.1563694E-03 0.1570734E-03 0.6131282E+01 5.8815 13 Na+ 0.2067633E-01 0.2227616E-01 0.5112405E+03 8.0018 14 Mn++ 0.8302880E-10 0.2504615E-08 0.1373610E-03 9.1501 15 F- 0.2759841E-04 0.2768942E-04 0.5251356E+00 5.1263 16 HPO4-- 0.4578591E-07 0.4636576E-07 0.4442457E-02 11.8966 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.1335177E-01 -.1333851E-01 -.1325661E-04 0.0000000E+00 2 H2O 0.4989716E+02 0.4990458E+02 -.7420562E-02 0.0000000E+00 3 Cl- 0.5036252E-03 0.5036252E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.2810172E-03 0.2810172E-03 0.0000000E+00 0.0000000E+00 5 HCO3- 0.4494947E-02 0.4494947E-02 0.0000000E+00 0.0000000E+00 6 HS- 0.1250844E-02 0.1250844E-02 0.0000000E+00 0.0000000E+00 7 Al+++ 0.4775352E-05 0.1470535E-05 0.3304817E-05 0.0000000E+00 8 H4SiO4 0.1215302E-01 0.8439411E-02 0.3713609E-02 0.0000000E+00 9 Ca++ 0.2080835E-06 0.2080835E-06 0.0000000E+00 0.0000000E+00 10 Mg++ 0.8368328E-10 0.8368328E-10 0.0000000E+00 0.0000000E+00 11 Fe++ 0.3259227E-07 0.1062461E-07 0.2196766E-07 0.0000000E+00 12 K+ 0.1412294E-03 0.1412272E-03 0.2196766E-08 0.0000000E+00 13 Na+ 0.2003215E-01 0.2002885E-01 0.3296029E-05 0.0000000E+00 14 Mn++ 0.2251939E-08 0.2251939E-08 0.0000000E+00 0.0000000E+00 15 F- 0.2489600E-04 0.2489600E-04 0.0000000E+00 0.0000000E+00 16 HPO4-- 0.4168819E-07 0.4168819E-07 0.0000000E+00 0.0000000E+00 Chg. balance for solid moles: -.8470E-21 Mass of aqueous solution: 0.900671E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 0.0619900 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 0.3296E-05 -5.482 0.8643E-03 -3.063 0.3869 0.3318E-03 quartz 0.3704E-02 -2.431 0.2225 -0.653 99.61 0.8403E-01 stilpnomelane-Fe 0.4394E-08 -8.357 0.4736E-05 -5.325 0.2120E-02 0.1636E-05 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 quartz 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 0.223386 g Volume = 0.084366 cm3 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.0619900 moles log = -1.2077 Original solution: 1000.0103000 g Original solution / Rock added: 16131.80 (Water/Rock Ratio), log = 4.2077 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0207 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9997E+00 0.9859 0.1006E+01 0.1020E+01 CO2,gas 0.8432E-04 1.0071 0.8667E-04 0.8606E-04 CH4,gas 0.2280E-04 1.0125 0.2356E-04 0.2327E-04 H2,gas 0.2237E-03 1.0005 0.2284E-03 0.2283E-03 H2S,gas 0.1633E-04 0.9960 0.1661E-04 0.1667E-04 S2,gas 0.1943E-21 1.0000 0.1984E-21 0.1984E-21 CO,gas 0.5170E-11 1.0000 0.5277E-11 0.5277E-11 SO3,gas 0.1666E-38 1.0000 0.1700E-38 0.1700E-38 SO2,gas 0.1480E-19 1.0000 0.1511E-19 0.1511E-19 HF,gas 0.6373E-13 1.0000 0.6504E-13 0.6504E-13 HCl,gas 0.2482E-16 1.0000 0.2533E-16 0.2533E-16 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 17 albite -0.38 -0.38 0.00 0.000 -0.94784E-12 150 quartz -2.99 -2.99 0.00 0.000 0.00000E+00 167 stilpnomelane-Fe 13.02 13.02 0.00 0.000 -0.27298E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -12.42 -5.76 -1.920 0.98369E+04 -4.062 3 CH4,gas 4.54 -1.78 -6.33 -1.582 0.10803E+05 -4.628 4 H2,gas 8.00 2.66 -5.34 -3.052 0.91183E+04 -3.641 5 H2S,gas -6.23 -12.71 -6.48 -3.239 0.11062E+05 -4.780 6 S2,gas -7.34 -30.74 -23.40 -3.600 0.39957E+05 -21.703 7 CO,gas 3.21 -9.76 -12.98 -3.993 0.22157E+05 -11.278 8 SO3,gas 17.12 -23.35 -40.47 -10.117 0.69099E+05 -38.769 9 SO2,gas 0.83 -20.69 -21.52 -5.739 0.36744E+05 -19.821 10 HF,gas 0.47 -14.41 -14.89 -7.443 0.25417E+05 -13.187 11 HCl,gas 5.19 -13.11 -18.30 -9.148 0.31239E+05 -16.596 12 acmite 7.71 7.26 -0.45 -0.047 0.77040E+03 16 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 20 spessartine 24.46 19.65 -4.81 -0.241 0.82134E+04 21 analcite 3.32 2.61 -0.72 -0.080 0.12231E+04 23 andradite 39.01 36.51 -2.50 -0.130 0.42690E+04 26 ankerite -2.14 -6.61 -4.47 -0.746 0.76383E+04 27 annite 20.12 17.19 -2.93 -0.163 0.50059E+04 28 phlogopite 27.06 23.20 -3.86 -0.215 0.65990E+04 34 apatite-F -34.30 -37.61 -3.31 -0.276 0.56530E+04 38 aragonite 0.97 -0.75 -1.72 -0.573 0.29354E+04 39 brucite 12.57 8.57 -4.00 -0.800 0.68308E+04 40 calcite 0.81 -0.75 -1.56 -0.521 0.26712E+04 41 carnegieite-low 9.02 5.60 -3.43 -0.490 0.58537E+04 42 carnegieite-high 10.09 5.60 -4.50 -0.643 0.76807E+04 43 carpholite-Mg 8.58 3.75 -4.83 -0.322 0.82433E+04 44 carpholite-Fe 6.71 1.75 -4.96 -0.331 0.84708E+04 45 celadonite 5.34 3.07 -2.27 -0.133 0.38713E+04 46 celadonite-Fe 3.88 1.07 -2.80 -0.165 0.47893E+04 47 chrysotile 23.89 19.73 -4.17 -0.347 0.71154E+04 49 clinochlore 39.07 35.04 -4.03 -0.126 0.68854E+04 50 daphnite 28.97 25.02 -3.94 -0.123 0.67306E+04 54 chloritoid-Fe 9.17 4.74 -4.43 -0.296 0.75685E+04 55 chloritoid-Mn 11.40 7.33 -4.08 -0.272 0.69584E+04 57 coesite -2.38 -2.99 -0.61 -0.204 0.10473E+04 64 cristobalite -2.56 -2.99 -0.43 -0.143 0.73267E+03 66 cymrite-K 1.69 -2.50 -4.19 -0.349 0.71537E+04 68 diaspore 2.87 0.58 -2.29 -0.382 0.39120E+04 69 diamond -3.10 -7.10 -4.00 -1.143 0.68295E+04 70 diopside 16.18 14.26 -1.92 -0.192 0.32845E+04 71 hedenbergite 14.21 12.26 -1.95 -0.195 0.33351E+04 78 epidote 24.67 20.77 -3.90 -0.189 0.66597E+04 80 epidote-Fe 29.84 25.42 -4.42 -0.230 0.75440E+04 81 fayalite 14.05 10.14 -3.90 -0.558 0.66669E+04 82 ferrosilite 11.15 7.15 -4.00 -0.400 0.68260E+04 86 gibbsite 4.08 0.58 -3.50 -0.500 0.59706E+04 87 glaucophane 22.97 18.96 -4.02 -0.109 0.68595E+04 88 glaucophane-Fe 17.28 12.95 -4.33 -0.117 0.73874E+04 89 graphite -3.55 -7.10 -3.56 -1.016 0.60717E+04 90 greenalite 16.14 13.72 -2.42 -0.202 0.41363E+04 93 hematite 12.57 10.47 -2.10 -0.254 0.35773E+04 94 heulandite -5.83 -8.09 -2.27 -0.103 0.38675E+04 98 jadeite 4.22 2.61 -1.61 -0.161 0.27485E+04 100 kalsilite 7.58 3.47 -4.11 -0.587 0.70165E+04 101 kaolinite -1.33 -4.81 -3.48 -0.316 0.59436E+04 104 laumontite 2.88 0.88 -2.01 -0.134 0.34276E+04 105 lawsonite 9.62 6.85 -2.76 -0.184 0.47146E+04 106 leucite 4.12 0.49 -3.63 -0.363 0.62044E+04 108 lizardite 23.24 19.73 -3.52 -0.293 0.60080E+04 109 magnesite 0.69 -3.85 -4.54 -1.515 0.77584E+04 110 magnetite 20.09 17.04 -3.05 -0.249 0.52095E+04 111 minnesotaite 10.39 7.74 -2.65 -0.156 0.45247E+04 115 manganosite 14.06 9.15 -4.91 -1.227 0.83804E+04 119 microcline -2.49 -2.50 -0.02 -0.001 0.30340E+02 123 muscovite 2.58 -1.34 -3.92 -0.231 0.66959E+04 124 paragonite 4.24 0.78 -3.46 -0.203 0.59046E+04 125 nepheline 8.34 5.60 -2.74 -0.392 0.46861E+04 137 phlogopite-Na 29.65 25.32 -4.33 -0.240 0.73875E+04 139 prehnite 19.37 15.53 -3.84 -0.226 0.65530E+04 140 prehnite-Fe 22.50 20.19 -2.31 -0.139 0.39457E+04 145 pyrite -21.25 -21.51 -0.27 -0.062 0.45285E+03 146 pyrrhotite -4.26 -6.14 -1.88 -0.628 0.32157E+04 147 pyrrhotiteFe0.875 -6.02 -7.29 -1.28 -0.470 0.21807E+04 148 pyroxmangite 7.40 6.16 -1.24 -0.248 0.21139E+04 149 pyrophyllite -6.18 -10.79 -4.62 -0.289 0.78830E+04 154 rhodochrosite -0.98 -3.27 -2.29 -0.765 0.39183E+04 155 rhodonite 7.45 6.16 -1.29 -0.257 0.21942E+04 156 sanidine -1.28 -2.50 -1.23 -0.095 0.20981E+04 158 siderite -2.61 -5.86 -3.25 -1.083 0.55454E+04 166 stilbite -7.52 -8.09 -0.57 -0.027 0.97364E+03 168 stilpnomelane-Mg 27.44 23.03 -4.41 -0.132 0.75314E+04 174 talc 16.49 13.75 -2.74 -0.161 0.46866E+04 177 tephroite 18.09 15.31 -2.78 -0.396 0.47384E+04 181 tridymite -2.63 -2.99 -0.36 -0.121 0.61998E+03 184 troilite-low -4.41 -6.14 -1.73 -0.578 0.29585E+04 190 wairakite 3.95 0.88 -3.07 -0.181 0.52495E+04 191 walstromite 11.51 8.68 -2.83 -0.566 0.48323E+04 192 wollastonite 10.46 8.68 -1.78 -0.356 0.30427E+04 193 pseudo-wollastonite 11.00 8.68 -2.32 -0.464 0.39625E+04 195 akaganeite 7.75 5.24 -2.52 -0.545 0.43012E+04 202 chalcedony -2.80 -2.99 -0.19 -0.062 0.31930E+03 204 montmorillonite-Ca -2.29 -6.23 -3.94 -0.244 0.67297E+04 205 montmorillonite-K -2.24 -6.22 -3.98 -0.244 0.67953E+04 206 montmorillonite-Mg -2.48 -6.74 -4.26 -0.264 0.72803E+04 207 montmorillonite-Na -2.04 -5.52 -3.48 -0.213 0.59402E+04 208 nontronite-Ca 3.21 1.62 -1.60 -0.104 0.27270E+04 209 nontronite-H 2.53 -0.31 -2.84 -0.190 0.48502E+04 210 nontronite-K 3.34 1.63 -1.71 -0.110 0.29159E+04 211 nontronite-Mg 3.07 1.11 -1.97 -0.128 0.33616E+04 212 nontronite-Na 3.52 2.33 -1.19 -0.076 0.20267E+04 228 tobermorite 9.82 6.73 -3.09 -0.844 0.52804E+04 234 alabandite -0.98 -3.56 -2.58 -0.860 0.44070E+04 237 boehmite 4.41 0.58 -3.82 -0.637 0.65289E+04 239 ferrous-oxide 9.81 6.57 -3.25 -0.812 0.55429E+04 245 silica-amorphous -2.09 -2.99 -0.90 -0.299 0.15335E+04 247 an20ab80 2.02 1.06 -0.95 -0.073 0.16287E+04 248 an25ab75 2.65 1.43 -1.22 -0.094 0.20829E+04 249 an30ab70 3.28 1.79 -1.49 -0.115 0.25467E+04 250 tr.625ac.25prg.125 45.16 40.65 -4.51 -0.122 0.77028E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 0.0020000 MOLES Current total amount of reactant added: 0.0619900 MOLES New total amount of reactant added: 0.0639900 MOLES Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.5508E-08 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 7 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 0.0639900 Water: Moles liquid = 0.4991E+02 kg liquid = 0.8992E+00 Moles total = 0.4990E+02 kg total = 0.8989E+00 Activity = 1.0000 Stoichiometric ionic strength = .1546974E-01 Osmotic coef. = 0.9284 True ionic strength = .2353959E-01 Chg. balance for total moles = -.5508E-08 Max. difference allowed = 0.5154E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.20934E-09 -9.6791 0.17411E-09 -9.7592 0.83173E+00 -0.0800 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.57056E-03 -3.2437 0.47132E-03 -3.3267 0.82606E+00 -0.0830 4 SO4-- 0.32283E-03 -3.4910 0.16055E-03 -3.7944 0.49733E+00 -0.3034 5 HCO3- 0.28088E-02 -2.5515 0.23241E-02 -2.6337 0.82744E+00 -0.0823 6 HS- 0.14339E-02 -2.8435 0.11847E-02 -2.9264 0.82620E+00 -0.0829 7 Al+++ 0.98654E-28 -28.0059 0.20638E-28 -28.6853 0.20920E+00 -0.6794 8 H4SiO4 0.10246E-02 -2.9894 0.10246E-02 -2.9894 0.10000E+01 0.0000 9 Ca++ 0.26942E-07 -7.5696 0.13287E-07 -7.8766 0.49318E+00 -0.3070 10 Mg++ 0.21798E-10 -10.6616 0.10695E-10 -10.9708 0.49062E+00 -0.3093 11 Fe++ 0.22537E-12 -12.6471 0.11071E-12 -12.9558 0.49123E+00 -0.3087 12 K+ 0.15636E-03 -3.8059 0.12941E-03 -3.8880 0.82765E+00 -0.0822 13 Na+ 0.20710E-01 -1.6838 0.17104E-01 -1.7669 0.82589E+00 -0.0831 14 Mn++ 0.86297E-10 -10.0640 0.42431E-10 -10.3723 0.49169E+00 -0.3083 15 F- 0.28484E-04 -4.5454 0.23475E-04 -4.6294 0.82414E+00 -0.0840 16 HPO4-- 0.45793E-07 -7.3392 0.22778E-07 -7.6425 0.49741E+00 -0.3033 18 HSiO3- 0.66518E-02 -2.1771 0.54949E-02 -2.2600 0.82606E+00 -0.0830 19 Ca(HSiO3)+ 0.20085E-08 -8.6971 0.16628E-08 -8.7792 0.82786E+00 -0.0820 20 Mg(HSiO3)+ 0.20119E-11 -11.6964 0.16656E-11 -11.7784 0.82786E+00 -0.0820 21 NaHSiO3,aq 0.15201E-02 -2.8181 0.15201E-02 -2.8181 0.10000E+01 0.0000 22 AlO+ 0.11187E-15 -15.9513 0.92614E-16 -16.0333 0.82786E+00 -0.0820 24 HAlO2,aq 0.10593E-09 -9.9750 0.10593E-09 -9.9750 0.10000E+01 0.0000 25 AlO2- 0.16336E-05 -5.7868 0.13467E-05 -5.8707 0.82438E+00 -0.0839 26 CH4,aq 0.16737E-07 -7.7763 0.16658E-07 -7.7784 0.99531E+00 -0.0020 27 C2H6,aq 0.27569E-18 -18.5596 0.27439E-18 -18.5616 0.99531E+00 -0.0020 31 CO,aq 0.37554E-14 -14.4253 0.37554E-14 -14.4253 0.10000E+01 0.0000 32 CO2,aq 0.86875E-06 -6.0611 0.86468E-06 -6.0631 0.99531E+00 -0.0020 33 CO3-2 0.23500E-02 -2.6289 0.11659E-02 -2.9333 0.49613E+00 -0.3044 34 CaCO3,aq 0.19425E-06 -6.7116 0.19425E-06 -6.7116 0.10000E+01 0.0000 35 Ca(HCO3)+ 0.95221E-09 -9.0213 0.78829E-09 -9.1033 0.82786E+00 -0.0820 36 CaCl+ 0.12242E-10 -10.9121 0.10135E-10 -10.9942 0.82786E+00 -0.0820 37 CaCl2,aq 0.11349E-14 -14.9451 0.11349E-14 -14.9451 0.10000E+01 0.0000 38 CaF+ 0.55011E-11 -11.2596 0.45541E-11 -11.3416 0.82786E+00 -0.0820 39 CaOH+ 0.65699E-08 -8.1824 0.54389E-08 -8.2645 0.82786E+00 -0.0820 40 CaSO4,aq 0.67743E-09 -9.1691 0.67743E-09 -9.1691 0.10000E+01 0.0000 41 HCl,aq 0.15038E-13 -13.8228 0.15038E-13 -13.8228 0.10000E+01 0.0000 45 HF,aq 0.27981E-10 -10.5531 0.27981E-10 -10.5531 0.10000E+01 0.0000 46 HF2- 0.26846E-15 -15.5711 0.22177E-15 -15.6541 0.82606E+00 -0.0830 48 FeCl+ 0.99765E-16 -16.0010 0.82591E-16 -16.0831 0.82786E+00 -0.0820 51 FeF+ 0.16042E-15 -15.7947 0.13281E-15 -15.8768 0.82786E+00 -0.0820 53 FeO,aq 0.14193E-09 -9.8479 0.14193E-09 -9.8479 0.10000E+01 0.0000 54 FeOH+ 0.25001E-10 -10.6020 0.20697E-10 -10.6841 0.82786E+00 -0.0820 55 HFeO2- 0.10325E-07 -7.9861 0.85290E-08 -8.0691 0.82606E+00 -0.0830 56 FeO+ 0.14342E-15 -15.8434 0.11873E-15 -15.9254 0.82786E+00 -0.0820 58 FeO2- 0.97010E-09 -9.0132 0.80136E-09 -9.0962 0.82606E+00 -0.0830 59 HFeO2,aq 0.17746E-10 -10.7509 0.17746E-10 -10.7509 0.10000E+01 0.0000 60 H2,aq 0.17370E-06 -6.7602 0.17289E-06 -6.7622 0.99531E+00 -0.0020 61 KCl,aq 0.11055E-08 -8.9565 0.11055E-08 -8.9565 0.10000E+01 0.0000 62 KHSO4,aq 0.10228E-16 -16.9902 0.10228E-16 -16.9902 0.10000E+01 0.0000 63 KOH,aq 0.31741E-06 -6.4984 0.31741E-06 -6.4984 0.10000E+01 0.0000 64 KSO4- 0.39030E-06 -6.4086 0.32241E-06 -6.4916 0.82606E+00 -0.0830 65 MgCO3,aq 0.39190E-10 -10.4068 0.39190E-10 -10.4068 0.10000E+01 0.0000 66 Mg(HCO3)+ 0.78312E-12 -12.1062 0.64831E-12 -12.1882 0.82786E+00 -0.0820 67 MgCl+ 0.89307E-14 -14.0491 0.73934E-14 -14.1312 0.82786E+00 -0.0820 68 MgF+ 0.16401E-13 -13.7851 0.13578E-13 -13.8672 0.82786E+00 -0.0820 69 MgOH+ 0.29261E-10 -10.5337 0.24224E-10 -10.6158 0.82786E+00 -0.0820 71 MnF+ 0.20266E-13 -13.6932 0.16777E-13 -13.7753 0.82786E+00 -0.0820 72 MnO,aq 0.14495E-08 -8.8388 0.14495E-08 -8.8388 0.10000E+01 0.0000 73 MnOH+ 0.89015E-09 -9.0505 0.73691E-09 -9.1326 0.82786E+00 -0.0820 74 MnO2-2 0.31982E-11 -11.4951 0.15868E-11 -11.7995 0.49613E+00 -0.3044 75 HMnO2- 0.73273E-10 -10.1351 0.60528E-10 -10.2180 0.82606E+00 -0.0830 78 MnCl+ 0.14876E-12 -12.8275 0.12315E-12 -12.9096 0.82786E+00 -0.0820 79 MnSO4,aq 0.19667E-11 -11.7063 0.19667E-11 -11.7063 0.10000E+01 0.0000 80 NaCl,aq 0.26716E-05 -5.5732 0.26716E-05 -5.5732 0.10000E+01 0.0000 81 NaF,aq 0.94003E-07 -7.0269 0.94003E-07 -7.0269 0.10000E+01 0.0000 82 NaOH,aq 0.42207E-04 -4.3746 0.42207E-04 -4.3746 0.10000E+01 0.0000 84 OH- 0.40253E-02 -2.3952 0.33184E-02 -2.4791 0.82438E+00 -0.0839 89 HPO3-2 0.24736E-16 -16.6067 0.12272E-16 -16.9111 0.49613E+00 -0.3044 92 H3PO4,aq 0.48296E-17 -17.3161 0.48296E-17 -17.3161 0.10000E+01 0.0000 93 H2PO4- 0.88471E-10 -10.0532 0.73161E-10 -10.1357 0.82695E+00 -0.0825 94 PO4-3 0.48259E-09 -9.3164 0.10674E-09 -9.9717 0.22118E+00 -0.6553 98 HP2O7-3 0.22980E-17 -17.6387 0.48131E-18 -18.3176 0.20945E+00 -0.6789 99 P2O7-4 0.10178E-16 -16.9923 0.66039E-18 -18.1802 0.64884E-01 -1.1879 100 H2S,aq 0.64050E-06 -6.1935 0.63750E-06 -6.1955 0.99531E+00 -0.0020 101 S2-2 0.36254E-09 -9.4406 0.17987E-09 -9.7450 0.49613E+00 -0.3044 102 S3-2 0.18010E-14 -14.7445 0.89354E-15 -15.0489 0.49613E+00 -0.3044 103 S3- 0.30362E-18 -18.5177 0.25081E-18 -18.6007 0.82606E+00 -0.0830 107 SO3-2 0.71530E-11 -11.1455 0.36071E-11 -11.4428 0.50428E+00 -0.2973 108 HSO3- 0.47604E-13 -13.3224 0.39324E-13 -13.4053 0.82606E+00 -0.0830 109 HSO4- 0.32506E-10 -10.4880 0.26940E-10 -10.5696 0.82878E+00 -0.0816 111 S2O3-2 0.24233E-11 -11.6156 0.12023E-11 -11.9200 0.49613E+00 -0.3044 112 HS2O3- 0.45311E-19 -19.3438 0.37430E-19 -19.4268 0.82606E+00 -0.0830 Charge balance for all species = -.6125E-08 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.2093397E-09 -.1459506E-01 -.1468561E+02 0.0000 2 H2O 0.1000000E+01 0.5550415E+02 0.9982014E+06 0.0000 3 Cl- 0.5705633E-03 0.5732360E-03 0.2028793E+02 6.4325 4 SO4-- 0.3228265E-03 0.3231576E-03 0.3098956E+02 15.7239 5 HCO3- 0.2808838E-02 0.5159925E-02 0.3143018E+03 7.1254 6 HS- 0.1433869E-02 0.1434571E-02 0.4736239E+02 6.8328 7 Al+++ 0.9865440E-28 0.1633735E-05 0.4400469E-01 0.5922 8 H4SiO4 0.1024625E-02 0.9196566E-02 0.8824089E+03 -2.9894 9 Ca++ 0.2694243E-07 0.2314224E-06 0.9258971E-02 11.6418 10 Mg++ 0.2179831E-10 0.9306932E-10 0.2258803E-05 8.5475 11 Fe++ 0.2253690E-12 0.1147990E-07 0.6400137E-03 6.5625 12 K+ 0.1563586E-03 0.1570674E-03 0.6131070E+01 5.8711 13 Na+ 0.2071025E-01 0.2227532E-01 0.5112229E+03 7.9923 14 Mn++ 0.8629651E-10 0.2504520E-08 0.1373563E-03 9.1460 15 F- 0.2848406E-04 0.2857810E-04 0.5419915E+00 5.1298 16 HPO4-- 0.4579294E-07 0.4636400E-07 0.4442304E-02 11.8758 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.1313642E-01 -.1312315E-01 -.1326337E-04 0.0000000E+00 2 H2O 0.4989880E+02 0.4990656E+02 -.7761195E-02 0.0000000E+00 3 Cl- 0.5154252E-03 0.5154252E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.2905672E-03 0.2905672E-03 0.0000000E+00 0.0000000E+00 5 HCO3- 0.4639547E-02 0.4639547E-02 0.0000000E+00 0.0000000E+00 6 HS- 0.1289894E-02 0.1289894E-02 0.0000000E+00 0.0000000E+00 7 Al+++ 0.4775352E-05 0.1468973E-05 0.3306379E-05 0.0000000E+00 8 H4SiO4 0.1215302E-01 0.8269093E-02 0.3883927E-02 0.0000000E+00 9 Ca++ 0.2080835E-06 0.2080835E-06 0.0000000E+00 0.0000000E+00 10 Mg++ 0.8368328E-10 0.8368328E-10 0.0000000E+00 0.0000000E+00 11 Fe++ 0.3259227E-07 0.1032215E-07 0.2227012E-07 0.0000000E+00 12 K+ 0.1412294E-03 0.1412272E-03 0.2227012E-08 0.0000000E+00 13 Na+ 0.2003215E-01 0.2002885E-01 0.3297471E-05 0.0000000E+00 14 Mn++ 0.2251939E-08 0.2251939E-08 0.0000000E+00 0.0000000E+00 15 F- 0.2569600E-04 0.2569600E-04 0.0000000E+00 0.0000000E+00 16 HPO4-- 0.4168819E-07 0.4168819E-07 0.0000000E+00 0.0000000E+00 Chg. balance for solid moles: -.1271E-20 Mass of aqueous solution: 0.900702E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 0.0639900 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 0.3297E-05 -5.482 0.8647E-03 -3.063 0.3701 0.3319E-03 quartz 0.3874E-02 -2.412 0.2327 -0.633 99.63 0.8790E-01 stilpnomelane-Fe 0.4454E-08 -8.351 0.4801E-05 -5.319 0.2055E-02 0.1659E-05 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 quartz 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 0.233619 g Volume = 0.088230 cm3 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.0639900 moles log = -1.1939 Original solution: 1000.0103000 g Original solution / Rock added: 15627.60 (Water/Rock Ratio), log = 4.1939 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0207 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9996E+00 0.9859 0.1006E+01 0.1020E+01 CO2,gas 0.9000E-04 1.0071 0.9251E-04 0.9186E-04 CH4,gas 0.2373E-04 1.0125 0.2452E-04 0.2422E-04 H2,gas 0.2223E-03 1.0005 0.2270E-03 0.2269E-03 H2S,gas 0.1724E-04 0.9960 0.1752E-04 0.1759E-04 S2,gas 0.2192E-21 1.0000 0.2237E-21 0.2237E-21 CO,gas 0.5483E-11 1.0000 0.5596E-11 0.5596E-11 SO3,gas 0.1803E-38 1.0000 0.1840E-38 0.1840E-38 SO2,gas 0.1592E-19 1.0000 0.1625E-19 0.1625E-19 HF,gas 0.6731E-13 1.0000 0.6870E-13 0.6870E-13 HCl,gas 0.2600E-16 1.0000 0.2653E-16 0.2653E-16 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 17 albite -0.38 -0.38 0.00 0.000 0.11184E-10 150 quartz -2.99 -2.99 0.00 0.000 0.00000E+00 167 stilpnomelane-Fe 13.02 13.02 0.00 0.000 0.21232E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -12.39 -5.73 -1.911 0.97886E+04 -4.034 3 CH4,gas 4.54 -1.77 -6.31 -1.577 0.10773E+05 -4.610 4 H2,gas 8.00 2.66 -5.34 -3.053 0.91230E+04 -3.644 5 H2S,gas -6.23 -12.69 -6.46 -3.228 0.11022E+05 -4.756 6 S2,gas -7.34 -30.68 -23.35 -3.592 0.39868E+05 -21.650 7 CO,gas 3.21 -9.74 -12.95 -3.985 0.22114E+05 -11.252 8 SO3,gas 17.12 -23.31 -40.43 -10.109 0.69040E+05 -38.735 9 SO2,gas 0.83 -20.66 -21.49 -5.730 0.36690E+05 -19.789 10 HF,gas 0.47 -14.39 -14.86 -7.431 0.25376E+05 -13.163 11 HCl,gas 5.19 -13.09 -18.28 -9.138 0.31204E+05 -16.576 12 acmite 7.71 7.25 -0.46 -0.048 0.78919E+03 16 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 20 spessartine 24.46 19.65 -4.80 -0.240 0.82014E+04 21 analcite 3.32 2.61 -0.72 -0.080 0.12231E+04 23 andradite 39.01 36.43 -2.58 -0.134 0.44113E+04 26 ankerite -2.14 -6.58 -4.45 -0.741 0.75922E+04 27 annite 20.12 17.18 -2.94 -0.163 0.50215E+04 28 phlogopite 27.06 23.14 -3.93 -0.218 0.67054E+04 34 apatite-F -34.30 -37.66 -3.36 -0.280 0.57391E+04 38 aragonite 0.97 -0.75 -1.72 -0.573 0.29328E+04 39 brucite 12.57 8.55 -4.02 -0.804 0.68659E+04 40 calcite 0.81 -0.75 -1.56 -0.521 0.26686E+04 41 carnegieite-low 9.02 5.60 -3.43 -0.490 0.58537E+04 42 carnegieite-high 10.09 5.60 -4.50 -0.643 0.76807E+04 43 carpholite-Mg 8.58 3.75 -4.83 -0.322 0.82456E+04 44 carpholite-Fe 6.71 1.77 -4.94 -0.330 0.84429E+04 45 celadonite 5.34 3.05 -2.29 -0.135 0.39076E+04 46 celadonite-Fe 3.88 1.07 -2.81 -0.165 0.47954E+04 47 chrysotile 23.89 19.66 -4.23 -0.352 0.72205E+04 49 clinochlore 39.07 34.95 -4.12 -0.129 0.70279E+04 50 daphnite 28.97 25.03 -3.94 -0.123 0.67217E+04 54 chloritoid-Fe 9.17 4.76 -4.42 -0.294 0.75406E+04 55 chloritoid-Mn 11.40 7.34 -4.06 -0.271 0.69326E+04 57 coesite -2.38 -2.99 -0.61 -0.204 0.10473E+04 64 cristobalite -2.56 -2.99 -0.43 -0.143 0.73267E+03 66 cymrite-K 1.69 -2.51 -4.19 -0.349 0.71550E+04 68 diaspore 2.87 0.59 -2.28 -0.380 0.38957E+04 69 diamond -3.10 -7.08 -3.98 -1.136 0.67905E+04 70 diopside 16.18 14.21 -1.97 -0.197 0.33654E+04 71 hedenbergite 14.21 12.23 -1.98 -0.198 0.33857E+04 78 epidote 24.67 20.73 -3.94 -0.191 0.67210E+04 80 epidote-Fe 29.84 25.38 -4.47 -0.232 0.76241E+04 81 fayalite 14.05 10.14 -3.91 -0.559 0.66765E+04 82 ferrosilite 11.15 7.15 -4.00 -0.400 0.68355E+04 86 gibbsite 4.08 0.59 -3.49 -0.498 0.59542E+04 87 glaucophane 22.97 18.90 -4.08 -0.110 0.69646E+04 88 glaucophane-Fe 17.28 12.94 -4.33 -0.117 0.74017E+04 89 graphite -3.55 -7.08 -3.53 -1.009 0.60328E+04 90 greenalite 16.14 13.71 -2.43 -0.203 0.41506E+04 93 hematite 12.57 10.47 -2.10 -0.254 0.35822E+04 94 heulandite -5.83 -8.10 -2.27 -0.103 0.38806E+04 98 jadeite 4.22 2.61 -1.61 -0.161 0.27485E+04 100 kalsilite 7.58 3.47 -4.11 -0.587 0.70178E+04 101 kaolinite -1.33 -4.79 -3.46 -0.315 0.59109E+04 104 laumontite 2.88 0.87 -2.02 -0.134 0.34406E+04 105 lawsonite 9.62 6.85 -2.77 -0.185 0.47277E+04 106 leucite 4.12 0.48 -3.63 -0.363 0.62057E+04 108 lizardite 23.24 19.66 -3.58 -0.298 0.61131E+04 109 magnesite 0.69 -3.85 -4.54 -1.512 0.77451E+04 110 magnetite 20.09 17.03 -3.06 -0.250 0.52191E+04 111 minnesotaite 10.39 7.73 -2.66 -0.156 0.45390E+04 115 manganosite 14.06 9.15 -4.91 -1.228 0.83873E+04 119 microcline -2.49 -2.51 -0.02 -0.001 0.31602E+02 123 muscovite 2.58 -1.32 -3.90 -0.230 0.66644E+04 124 paragonite 4.24 0.80 -3.44 -0.202 0.58719E+04 125 nepheline 8.34 5.60 -2.74 -0.392 0.46861E+04 137 phlogopite-Na 29.65 25.26 -4.39 -0.244 0.74926E+04 139 prehnite 19.37 15.50 -3.87 -0.228 0.66119E+04 140 prehnite-Fe 22.50 20.14 -2.36 -0.142 0.40234E+04 145 pyrite -21.25 -21.47 -0.22 -0.051 0.37305E+03 146 pyrrhotite -4.26 -6.12 -1.86 -0.621 0.31806E+04 147 pyrrhotiteFe0.875 -6.02 -7.27 -1.26 -0.462 0.21444E+04 148 pyroxmangite 7.40 6.16 -1.24 -0.248 0.21208E+04 149 pyrophyllite -6.18 -10.77 -4.60 -0.287 0.78503E+04 154 rhodochrosite -0.98 -3.25 -2.27 -0.757 0.38769E+04 155 rhodonite 7.45 6.16 -1.29 -0.258 0.22011E+04 156 sanidine -1.28 -2.51 -1.23 -0.095 0.20994E+04 158 siderite -2.61 -5.83 -3.22 -1.074 0.55019E+04 166 stilbite -7.52 -8.10 -0.58 -0.028 0.98673E+03 168 stilpnomelane-Mg 27.44 22.94 -4.50 -0.134 0.76828E+04 174 talc 16.49 13.68 -2.81 -0.165 0.47917E+04 177 tephroite 18.09 15.30 -2.78 -0.398 0.47522E+04 181 tridymite -2.63 -2.99 -0.36 -0.121 0.61998E+03 184 troilite-low -4.41 -6.12 -1.71 -0.571 0.29234E+04 190 wairakite 3.95 0.87 -3.08 -0.181 0.52626E+04 191 walstromite 11.51 8.65 -2.86 -0.571 0.48781E+04 192 wollastonite 10.46 8.65 -1.81 -0.362 0.30885E+04 193 pseudo-wollastonite 11.00 8.65 -2.35 -0.470 0.40083E+04 195 akaganeite 7.75 5.23 -2.52 -0.545 0.43036E+04 202 chalcedony -2.80 -2.99 -0.19 -0.062 0.31930E+03 204 montmorillonite-Ca -2.29 -6.23 -3.94 -0.244 0.67215E+04 205 montmorillonite-K -2.24 -6.21 -3.97 -0.243 0.67854E+04 206 montmorillonite-Mg -2.48 -6.74 -4.26 -0.263 0.72703E+04 207 montmorillonite-Na -2.04 -5.51 -3.47 -0.213 0.59299E+04 208 nontronite-Ca 3.21 1.61 -1.60 -0.104 0.27340E+04 209 nontronite-H 2.53 -0.31 -2.84 -0.190 0.48497E+04 210 nontronite-K 3.34 1.63 -1.71 -0.110 0.29211E+04 211 nontronite-Mg 3.07 1.10 -1.97 -0.128 0.33669E+04 212 nontronite-Na 3.52 2.33 -1.19 -0.076 0.20316E+04 228 tobermorite 9.82 6.71 -3.11 -0.850 0.53186E+04 234 alabandite -0.98 -3.54 -2.56 -0.854 0.43740E+04 237 boehmite 4.41 0.59 -3.81 -0.636 0.65126E+04 239 ferrous-oxide 9.81 6.56 -3.25 -0.812 0.55477E+04 245 silica-amorphous -2.09 -2.99 -0.90 -0.299 0.15335E+04 247 an20ab80 2.02 1.06 -0.96 -0.073 0.16314E+04 248 an25ab75 2.65 1.42 -1.22 -0.094 0.20862E+04 249 an30ab70 3.28 1.79 -1.49 -0.115 0.25506E+04 250 tr.625ac.25prg.125 45.16 40.52 -4.64 -0.125 0.79234E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 0.0020000 MOLES Current total amount of reactant added: 0.0639900 MOLES New total amount of reactant added: 0.0659900 MOLES Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.5508E-08 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 7 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 0.0659900 Water: Moles liquid = 0.4991E+02 kg liquid = 0.8992E+00 Moles total = 0.4990E+02 kg total = 0.8990E+00 Activity = 1.0000 Stoichiometric ionic strength = .1559950E-01 Osmotic coef. = 0.9281 True ionic strength = .2362669E-01 Chg. balance for total moles = -.5508E-08 Max. difference allowed = 0.5272E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.21443E-09 -9.6687 0.17830E-09 -9.7488 0.83154E+00 -0.0801 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.58360E-03 -3.2339 0.48197E-03 -3.3170 0.82585E+00 -0.0831 4 SO4-- 0.33342E-03 -3.4770 0.16565E-03 -3.7808 0.49683E+00 -0.3038 5 HCO3- 0.29266E-02 -2.5336 0.24209E-02 -2.6160 0.82723E+00 -0.0824 6 HS- 0.14772E-02 -2.8306 0.12202E-02 -2.9136 0.82599E+00 -0.0830 7 Al+++ 0.10860E-27 -27.9642 0.22666E-28 -28.6446 0.20871E+00 -0.6805 8 H4SiO4 0.10246E-02 -2.9894 0.10246E-02 -2.9894 0.10000E+01 0.0000 9 Ca++ 0.26598E-07 -7.5751 0.13104E-07 -7.8826 0.49267E+00 -0.3074 10 Mg++ 0.21820E-10 -10.6612 0.10694E-10 -10.9709 0.49011E+00 -0.3097 11 Fe++ 0.23505E-12 -12.6288 0.11534E-12 -12.9380 0.49072E+00 -0.3092 12 K+ 0.15635E-03 -3.8059 0.12937E-03 -3.8882 0.82745E+00 -0.0823 13 Na+ 0.20744E-01 -1.6831 0.17128E-01 -1.7663 0.82567E+00 -0.0832 14 Mn++ 0.89721E-10 -10.0471 0.44069E-10 -10.3559 0.49118E+00 -0.3088 15 F- 0.29370E-04 -4.5321 0.24198E-04 -4.6162 0.82392E+00 -0.0841 16 HPO4-- 0.45800E-07 -7.3391 0.22758E-07 -7.6429 0.49691E+00 -0.3037 18 HSiO3- 0.64972E-02 -2.1873 0.53658E-02 -2.2704 0.82585E+00 -0.0831 19 Ca(HSiO3)+ 0.19348E-08 -8.7134 0.16013E-08 -8.7955 0.82765E+00 -0.0822 20 Mg(HSiO3)+ 0.19650E-11 -11.7066 0.16263E-11 -11.7888 0.82765E+00 -0.0822 21 NaHSiO3,aq 0.14864E-02 -2.8279 0.14864E-02 -2.8279 0.10000E+01 0.0000 22 AlO+ 0.11719E-15 -15.9311 0.96992E-16 -16.0133 0.82765E+00 -0.0822 24 HAlO2,aq 0.10833E-09 -9.9653 0.10833E-09 -9.9653 0.10000E+01 0.0000 25 AlO2- 0.16318E-05 -5.7873 0.13449E-05 -5.8713 0.82416E+00 -0.0840 26 CH4,aq 0.17404E-07 -7.7594 0.17322E-07 -7.7614 0.99527E+00 -0.0021 27 C2H6,aq 0.30000E-18 -18.5229 0.29858E-18 -18.5249 0.99527E+00 -0.0021 31 CO,aq 0.39805E-14 -14.4001 0.39805E-14 -14.4001 0.10000E+01 0.0000 32 CO2,aq 0.92674E-06 -6.0330 0.92236E-06 -6.0351 0.99527E+00 -0.0021 33 CO3-2 0.23928E-02 -2.6211 0.11860E-02 -2.9259 0.49563E+00 -0.3048 34 CaCO3,aq 0.19487E-06 -6.7103 0.19487E-06 -6.7103 0.10000E+01 0.0000 35 Ca(HCO3)+ 0.97844E-09 -9.0095 0.80980E-09 -9.0916 0.82765E+00 -0.0822 36 CaCl+ 0.12349E-10 -10.9084 0.10221E-10 -10.9905 0.82765E+00 -0.0822 37 CaCl2,aq 0.11703E-14 -14.9317 0.11703E-14 -14.9317 0.10000E+01 0.0000 38 CaF+ 0.55938E-11 -11.2523 0.46297E-11 -11.3344 0.82765E+00 -0.0822 39 CaOH+ 0.63286E-08 -8.1987 0.52378E-08 -8.2808 0.82765E+00 -0.0822 40 CaSO4,aq 0.68932E-09 -9.1616 0.68932E-09 -9.1616 0.10000E+01 0.0000 41 HCl,aq 0.15748E-13 -13.8028 0.15748E-13 -13.8028 0.10000E+01 0.0000 45 HF,aq 0.29537E-10 -10.5296 0.29537E-10 -10.5296 0.10000E+01 0.0000 46 HF2- 0.29220E-15 -15.5343 0.24131E-15 -15.6174 0.82585E+00 -0.0831 48 FeCl+ 0.10631E-15 -15.9734 0.87991E-16 -16.0556 0.82765E+00 -0.0822 51 FeF+ 0.17233E-15 -15.7636 0.14263E-15 -15.8458 0.82765E+00 -0.0822 53 FeO,aq 0.14100E-09 -9.8508 0.14100E-09 -9.8508 0.10000E+01 0.0000 54 FeOH+ 0.25442E-10 -10.5945 0.21057E-10 -10.6766 0.82765E+00 -0.0822 55 HFeO2- 0.10019E-07 -7.9992 0.82743E-08 -8.0823 0.82585E+00 -0.0831 56 FeO+ 0.14641E-15 -15.8344 0.12118E-15 -15.9166 0.82765E+00 -0.0822 58 FeO2- 0.94437E-09 -9.0249 0.77991E-09 -9.1080 0.82585E+00 -0.0831 59 HFeO2,aq 0.17686E-10 -10.7524 0.17686E-10 -10.7524 0.10000E+01 0.0000 60 H2,aq 0.17261E-06 -6.7629 0.17179E-06 -6.7650 0.99527E+00 -0.0021 61 KCl,aq 0.11301E-08 -8.9469 0.11301E-08 -8.9469 0.10000E+01 0.0000 62 KHSO4,aq 0.10804E-16 -16.9664 0.10804E-16 -16.9664 0.10000E+01 0.0000 63 KOH,aq 0.30985E-06 -6.5088 0.30985E-06 -6.5088 0.10000E+01 0.0000 64 KSO4- 0.40268E-06 -6.3950 0.33255E-06 -6.4781 0.82585E+00 -0.0831 65 MgCO3,aq 0.39861E-10 -10.3995 0.39861E-10 -10.3995 0.10000E+01 0.0000 66 Mg(HCO3)+ 0.81589E-12 -12.0884 0.67527E-12 -12.1705 0.82765E+00 -0.0822 67 MgCl+ 0.91341E-14 -14.0393 0.75598E-14 -14.1215 0.82765E+00 -0.0822 68 MgF+ 0.16910E-13 -13.7719 0.13995E-13 -13.8540 0.82765E+00 -0.0822 69 MgOH+ 0.28578E-10 -10.5440 0.23653E-10 -10.6261 0.82765E+00 -0.0822 71 MnF+ 0.21702E-13 -13.6635 0.17962E-13 -13.7456 0.82765E+00 -0.0822 72 MnO,aq 0.14355E-08 -8.8430 0.14355E-08 -8.8430 0.10000E+01 0.0000 73 MnOH+ 0.90301E-09 -9.0443 0.74737E-09 -9.1265 0.82765E+00 -0.0822 74 MnO2-2 0.30234E-11 -11.5195 0.14985E-11 -11.8243 0.49563E+00 -0.3048 75 HMnO2- 0.70880E-10 -10.1495 0.58536E-10 -10.2326 0.82585E+00 -0.0831 78 MnCl+ 0.15803E-12 -12.8013 0.13079E-12 -12.8834 0.82765E+00 -0.0822 79 MnSO4,aq 0.21075E-11 -11.6762 0.21075E-11 -11.6762 0.10000E+01 0.0000 80 NaCl,aq 0.27357E-05 -5.5629 0.27357E-05 -5.5629 0.10000E+01 0.0000 81 NaF,aq 0.97033E-07 -7.0131 0.97033E-07 -7.0131 0.10000E+01 0.0000 82 NaOH,aq 0.41272E-04 -4.3843 0.41272E-04 -4.3843 0.10000E+01 0.0000 84 OH- 0.39317E-02 -2.4054 0.32404E-02 -2.4894 0.82416E+00 -0.0840 89 HPO3-2 0.24582E-16 -16.6094 0.12184E-16 -16.9142 0.49563E+00 -0.3048 92 H3PO4,aq 0.50604E-17 -17.2958 0.50604E-17 -17.2958 0.10000E+01 0.0000 93 H2PO4- 0.90545E-10 -10.0431 0.74857E-10 -10.1258 0.82674E+00 -0.0826 94 PO4-3 0.47186E-09 -9.3262 0.10414E-09 -9.9824 0.22070E+00 -0.6562 98 HP2O7-3 0.23547E-17 -17.6281 0.49205E-18 -18.3080 0.20896E+00 -0.6799 99 P2O7-4 0.10202E-16 -16.9913 0.65926E-18 -18.1809 0.64622E-01 -1.1896 100 H2S,aq 0.67558E-06 -6.1703 0.67239E-06 -6.1724 0.99527E+00 -0.0021 101 S2-2 0.38744E-09 -9.4118 0.19203E-09 -9.7166 0.49563E+00 -0.3048 102 S3-2 0.20431E-14 -14.6897 0.10126E-14 -14.9946 0.49563E+00 -0.3048 103 S3- 0.35358E-18 -18.4515 0.29200E-18 -18.5346 0.82585E+00 -0.0831 107 SO3-2 0.73405E-11 -11.1343 0.36981E-11 -11.4320 0.50379E+00 -0.2978 108 HSO3- 0.49991E-13 -13.3011 0.41285E-13 -13.3842 0.82585E+00 -0.0831 109 HSO4- 0.34354E-10 -10.4640 0.28465E-10 -10.5457 0.82857E+00 -0.0817 111 S2O3-2 0.26399E-11 -11.5784 0.13084E-11 -11.8833 0.49563E+00 -0.3048 112 HS2O3- 0.50510E-19 -19.2966 0.41714E-19 -19.3797 0.82585E+00 -0.0831 Charge balance for all species = -.6125E-08 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.2144272E-09 -.1435501E-01 -.1444411E+02 0.0000 2 H2O 0.1000000E+01 0.5550424E+02 0.9982065E+06 0.0000 3 Cl- 0.5836004E-03 0.5863373E-03 0.2075168E+02 6.4319 4 SO4-- 0.3334230E-03 0.3337661E-03 0.3200699E+02 15.7169 5 HCO3- 0.2926581E-02 0.5320542E-02 0.3240865E+03 7.1328 6 HS- 0.1477208E-02 0.1477945E-02 0.4879455E+02 6.8353 7 Al+++ 0.1086005E-27 0.1631934E-05 0.4395631E-01 0.6019 8 H4SiO4 0.1024625E-02 0.9008276E-02 0.8643455E+03 -2.9894 9 Ca++ 0.2659830E-07 0.2314137E-06 0.9258652E-02 11.6151 10 Mg++ 0.2181974E-10 0.9306579E-10 0.2258726E-05 8.5268 11 Fe++ 0.2350463E-12 0.1114779E-07 0.6215002E-03 6.5597 12 K+ 0.1563478E-03 0.1570614E-03 0.6130858E+01 5.8607 13 Na+ 0.2074396E-01 0.2227447E-01 0.5112053E+03 7.9825 14 Mn++ 0.8972073E-10 0.2504425E-08 0.1373515E-03 9.1418 15 F- 0.2936964E-04 0.2946671E-04 0.5588462E+00 5.1326 16 HPO4-- 0.4579983E-07 0.4636224E-07 0.4442151E-02 11.8548 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.1292107E-01 -.1290780E-01 -.1327014E-04 0.0000000E+00 2 H2O 0.4990043E+02 0.4990853E+02 -.8099179E-02 0.0000000E+00 3 Cl- 0.5272252E-03 0.5272252E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.3001172E-03 0.3001172E-03 0.0000000E+00 0.0000000E+00 5 HCO3- 0.4784147E-02 0.4784147E-02 0.0000000E+00 0.0000000E+00 6 HS- 0.1328944E-02 0.1328944E-02 0.0000000E+00 0.0000000E+00 7 Al+++ 0.4775352E-05 0.1467409E-05 0.3307943E-05 0.0000000E+00 8 H4SiO4 0.1215302E-01 0.8100099E-02 0.4052921E-02 0.0000000E+00 9 Ca++ 0.2080835E-06 0.2080835E-06 0.0000000E+00 0.0000000E+00 10 Mg++ 0.8368328E-10 0.8368328E-10 0.0000000E+00 0.0000000E+00 11 Fe++ 0.3259227E-07 0.1002391E-07 0.2256836E-07 0.0000000E+00 12 K+ 0.1412294E-03 0.1412271E-03 0.2256836E-08 0.0000000E+00 13 Na+ 0.2003215E-01 0.2002885E-01 0.3298916E-05 0.0000000E+00 14 Mn++ 0.2251939E-08 0.2251939E-08 0.0000000E+00 0.0000000E+00 15 F- 0.2649600E-04 0.2649600E-04 0.0000000E+00 0.0000000E+00 16 HPO4-- 0.4168819E-07 0.4168819E-07 0.0000000E+00 0.0000000E+00 Chg. balance for solid moles: -.4235E-21 Mass of aqueous solution: 0.900733E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 0.0659900 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 0.3299E-05 -5.482 0.8650E-03 -3.063 0.3549 0.3321E-03 quartz 0.4043E-02 -2.393 0.2429 -0.615 99.64 0.9173E-01 stilpnomelane-Fe 0.4514E-08 -8.345 0.4866E-05 -5.313 0.1996E-02 0.1681E-05 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 quartz 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 0.243773 g Volume = 0.092064 cm3 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.0659900 moles log = -1.1805 Original solution: 1000.0103000 g Original solution / Rock added: 15153.97 (Water/Rock Ratio), log = 4.1805 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0207 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9996E+00 0.9859 0.1006E+01 0.1020E+01 CO2,gas 0.9600E-04 1.0071 0.9868E-04 0.9799E-04 CH4,gas 0.2467E-04 1.0125 0.2550E-04 0.2518E-04 H2,gas 0.2209E-03 1.0005 0.2255E-03 0.2254E-03 H2S,gas 0.1818E-04 0.9960 0.1848E-04 0.1856E-04 S2,gas 0.2470E-21 1.0000 0.2521E-21 0.2521E-21 CO,gas 0.5812E-11 1.0000 0.5932E-11 0.5932E-11 SO3,gas 0.1951E-38 1.0000 0.1991E-38 0.1991E-38 SO2,gas 0.1712E-19 1.0000 0.1747E-19 0.1747E-19 HF,gas 0.7105E-13 1.0000 0.7252E-13 0.7252E-13 HCl,gas 0.2722E-16 1.0000 0.2779E-16 0.2779E-16 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 17 albite -0.38 -0.38 0.00 0.000 0.11184E-10 150 quartz -2.99 -2.99 0.00 0.000 0.00000E+00 167 stilpnomelane-Fe 13.02 13.02 0.00 0.000 0.21232E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -12.36 -5.70 -1.902 0.97407E+04 -4.006 3 CH4,gas 4.54 -1.75 -6.29 -1.573 0.10744E+05 -4.594 4 H2,gas 8.00 2.65 -5.35 -3.055 0.91277E+04 -3.647 5 H2S,gas -6.23 -12.66 -6.43 -3.216 0.10983E+05 -4.733 6 S2,gas -7.34 -30.63 -23.30 -3.584 0.39780E+05 -21.598 7 CO,gas 3.21 -9.71 -12.93 -3.977 0.22070E+05 -11.227 8 SO3,gas 17.12 -23.28 -40.40 -10.100 0.68982E+05 -38.701 9 SO2,gas 0.83 -20.62 -21.46 -5.722 0.36637E+05 -19.758 10 HF,gas 0.47 -14.37 -14.84 -7.419 0.25336E+05 -13.140 11 HCl,gas 5.19 -13.07 -18.26 -9.128 0.31170E+05 -16.556 12 acmite 7.71 7.24 -0.47 -0.049 0.80829E+03 16 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 20 spessartine 24.46 19.66 -4.80 -0.240 0.81897E+04 21 analcite 3.32 2.61 -0.72 -0.080 0.12231E+04 23 andradite 39.01 36.34 -2.67 -0.139 0.45529E+04 26 ankerite -2.14 -6.55 -4.42 -0.737 0.75468E+04 27 annite 20.12 17.17 -2.95 -0.164 0.50373E+04 28 phlogopite 27.06 23.07 -3.99 -0.222 0.68126E+04 34 apatite-F -34.30 -37.71 -3.41 -0.284 0.58229E+04 38 aragonite 0.97 -0.75 -1.72 -0.572 0.29305E+04 39 brucite 12.57 8.53 -4.04 -0.808 0.69012E+04 40 calcite 0.81 -0.75 -1.56 -0.521 0.26663E+04 41 carnegieite-low 9.02 5.60 -3.43 -0.490 0.58537E+04 42 carnegieite-high 10.09 5.60 -4.50 -0.643 0.76807E+04 43 carpholite-Mg 8.58 3.75 -4.83 -0.322 0.82477E+04 44 carpholite-Fe 6.71 1.78 -4.93 -0.329 0.84145E+04 45 celadonite 5.34 3.03 -2.31 -0.136 0.39442E+04 46 celadonite-Fe 3.88 1.06 -2.81 -0.165 0.48015E+04 47 chrysotile 23.89 19.60 -4.29 -0.358 0.73264E+04 49 clinochlore 39.07 34.87 -4.20 -0.131 0.71713E+04 50 daphnite 28.97 25.03 -3.93 -0.123 0.67128E+04 54 chloritoid-Fe 9.17 4.77 -4.40 -0.293 0.75122E+04 55 chloritoid-Mn 11.40 7.36 -4.04 -0.270 0.69066E+04 57 coesite -2.38 -2.99 -0.61 -0.204 0.10473E+04 64 cristobalite -2.56 -2.99 -0.43 -0.143 0.73267E+03 66 cymrite-K 1.69 -2.51 -4.19 -0.349 0.71562E+04 68 diaspore 2.87 0.60 -2.27 -0.379 0.38790E+04 69 diamond -3.10 -7.06 -3.95 -1.130 0.67521E+04 70 diopside 16.18 14.16 -2.02 -0.202 0.34462E+04 71 hedenbergite 14.21 12.20 -2.01 -0.201 0.34361E+04 78 epidote 24.67 20.70 -3.97 -0.193 0.67814E+04 80 epidote-Fe 29.84 25.33 -4.51 -0.234 0.77036E+04 81 fayalite 14.05 10.13 -3.92 -0.559 0.66862E+04 82 ferrosilite 11.15 7.14 -4.01 -0.401 0.68453E+04 86 gibbsite 4.08 0.60 -3.48 -0.497 0.59376E+04 87 glaucophane 22.97 18.83 -4.14 -0.112 0.70706E+04 88 glaucophane-Fe 17.28 12.93 -4.34 -0.117 0.74163E+04 89 graphite -3.55 -7.06 -3.51 -1.003 0.59943E+04 90 greenalite 16.14 13.70 -2.44 -0.203 0.41652E+04 93 hematite 12.57 10.47 -2.10 -0.255 0.35872E+04 94 heulandite -5.83 -8.11 -2.28 -0.104 0.38929E+04 98 jadeite 4.22 2.61 -1.61 -0.161 0.27485E+04 100 kalsilite 7.58 3.47 -4.11 -0.587 0.70190E+04 101 kaolinite -1.33 -4.78 -3.44 -0.313 0.58776E+04 104 laumontite 2.88 0.86 -2.02 -0.135 0.34530E+04 105 lawsonite 9.62 6.84 -2.78 -0.185 0.47400E+04 106 leucite 4.12 0.48 -3.64 -0.364 0.62069E+04 108 lizardite 23.24 19.60 -3.64 -0.304 0.62191E+04 109 magnesite 0.69 -3.84 -4.53 -1.510 0.77325E+04 110 magnetite 20.09 17.02 -3.06 -0.250 0.52290E+04 111 minnesotaite 10.39 7.72 -2.67 -0.157 0.45536E+04 115 manganosite 14.06 9.14 -4.92 -1.229 0.83945E+04 119 microcline -2.49 -2.51 -0.02 -0.001 0.32854E+02 123 muscovite 2.58 -1.30 -3.88 -0.228 0.66325E+04 124 paragonite 4.24 0.82 -3.42 -0.201 0.58387E+04 125 nepheline 8.34 5.60 -2.74 -0.392 0.46861E+04 137 phlogopite-Na 29.65 25.20 -4.45 -0.247 0.75986E+04 139 prehnite 19.37 15.47 -3.91 -0.230 0.66698E+04 140 prehnite-Fe 22.50 20.10 -2.40 -0.144 0.41004E+04 145 pyrite -21.25 -21.42 -0.17 -0.041 0.29414E+03 146 pyrrhotite -4.26 -6.10 -1.84 -0.614 0.31459E+04 147 pyrrhotiteFe0.875 -6.02 -7.25 -1.23 -0.454 0.21085E+04 148 pyroxmangite 7.40 6.15 -1.25 -0.249 0.21280E+04 149 pyrophyllite -6.18 -10.75 -4.58 -0.286 0.78171E+04 154 rhodochrosite -0.98 -3.22 -2.25 -0.749 0.38362E+04 155 rhodonite 7.45 6.15 -1.29 -0.259 0.22083E+04 156 sanidine -1.28 -2.51 -1.23 -0.095 0.21006E+04 158 siderite -2.61 -5.81 -3.20 -1.066 0.54589E+04 166 stilbite -7.52 -8.11 -0.59 -0.028 0.99906E+03 168 stilpnomelane-Mg 27.44 22.85 -4.59 -0.137 0.78350E+04 174 talc 16.49 13.62 -2.87 -0.169 0.48976E+04 177 tephroite 18.09 15.29 -2.79 -0.399 0.47666E+04 181 tridymite -2.63 -2.99 -0.36 -0.121 0.61998E+03 184 troilite-low -4.41 -6.10 -1.69 -0.564 0.28887E+04 190 wairakite 3.95 0.86 -3.09 -0.182 0.52749E+04 191 walstromite 11.51 8.63 -2.88 -0.577 0.49236E+04 192 wollastonite 10.46 8.63 -1.84 -0.367 0.31341E+04 193 pseudo-wollastonite 11.00 8.63 -2.37 -0.475 0.40539E+04 195 akaganeite 7.75 5.23 -2.52 -0.545 0.43061E+04 202 chalcedony -2.80 -2.99 -0.19 -0.062 0.31930E+03 204 montmorillonite-Ca -2.29 -6.22 -3.93 -0.243 0.67129E+04 205 montmorillonite-K -2.24 -6.20 -3.97 -0.243 0.67752E+04 206 montmorillonite-Mg -2.48 -6.73 -4.25 -0.263 0.72600E+04 207 montmorillonite-Na -2.04 -5.50 -3.47 -0.212 0.59193E+04 208 nontronite-Ca 3.21 1.61 -1.61 -0.104 0.27411E+04 209 nontronite-H 2.53 -0.31 -2.84 -0.190 0.48492E+04 210 nontronite-K 3.34 1.63 -1.71 -0.110 0.29265E+04 211 nontronite-Mg 3.07 1.10 -1.97 -0.128 0.33722E+04 212 nontronite-Na 3.52 2.33 -1.19 -0.077 0.20366E+04 228 tobermorite 9.82 6.69 -3.14 -0.856 0.53565E+04 234 alabandite -0.98 -3.52 -2.54 -0.848 0.43417E+04 237 boehmite 4.41 0.60 -3.80 -0.634 0.64960E+04 239 ferrous-oxide 9.81 6.56 -3.25 -0.813 0.55526E+04 245 silica-amorphous -2.09 -2.99 -0.90 -0.299 0.15335E+04 247 an20ab80 2.02 1.06 -0.96 -0.074 0.16338E+04 248 an25ab75 2.65 1.42 -1.22 -0.094 0.20893E+04 249 an30ab70 3.28 1.78 -1.50 -0.115 0.25543E+04 250 tr.625ac.25prg.125 45.16 40.39 -4.77 -0.128 0.81444E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 0.0020000 MOLES Current total amount of reactant added: 0.0659900 MOLES New total amount of reactant added: 0.0679900 MOLES Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.5508E-08 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 7 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 0.0679900 Water: Moles liquid = 0.4991E+02 kg liquid = 0.8992E+00 Moles total = 0.4990E+02 kg total = 0.8990E+00 Activity = 1.0000 Stoichiometric ionic strength = .1572924E-01 Osmotic coef. = 0.9278 True ionic strength = .2371129E-01 Chg. balance for total moles = -.5508E-08 Max. difference allowed = 0.5390E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.21971E-09 -9.6581 0.18266E-09 -9.7384 0.83134E+00 -0.0802 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.59664E-03 -3.2243 0.49261E-03 -3.3075 0.82565E+00 -0.0832 4 SO4-- 0.34402E-03 -3.4634 0.17075E-03 -3.7676 0.49634E+00 -0.3042 5 HCO3- 0.30466E-02 -2.5162 0.25196E-02 -2.5987 0.82702E+00 -0.0825 6 HS- 0.15205E-02 -2.8180 0.12556E-02 -2.9011 0.82578E+00 -0.0831 7 Al+++ 0.11971E-27 -27.9219 0.24929E-28 -28.6033 0.20824E+00 -0.6814 8 H4SiO4 0.10246E-02 -2.9894 0.10246E-02 -2.9894 0.10000E+01 0.0000 9 Ca++ 0.26283E-07 -7.5803 0.12936E-07 -7.8882 0.49218E+00 -0.3079 10 Mg++ 0.21848E-10 -10.6606 0.10697E-10 -10.9707 0.48961E+00 -0.3102 11 Fe++ 0.24528E-12 -12.6103 0.12024E-12 -12.9200 0.49022E+00 -0.3096 12 K+ 0.15634E-03 -3.8059 0.12933E-03 -3.8883 0.82724E+00 -0.0824 13 Na+ 0.20777E-01 -1.6824 0.17151E-01 -1.7657 0.82547E+00 -0.0833 14 Mn++ 0.93310E-10 -10.0301 0.45786E-10 -10.3393 0.49068E+00 -0.3092 15 F- 0.30255E-04 -4.5192 0.24922E-04 -4.6034 0.82371E+00 -0.0842 16 HPO4-- 0.45807E-07 -7.3391 0.22739E-07 -7.6432 0.49642E+00 -0.3041 18 HSiO3- 0.63439E-02 -2.1976 0.52378E-02 -2.2808 0.82565E+00 -0.0832 19 Ca(HSiO3)+ 0.18649E-08 -8.7294 0.15431E-08 -8.8116 0.82745E+00 -0.0823 20 Mg(HSiO3)+ 0.19191E-11 -11.7169 0.15880E-11 -11.7992 0.82745E+00 -0.0823 21 NaHSiO3,aq 0.14530E-02 -2.8377 0.14530E-02 -2.8377 0.10000E+01 0.0000 22 AlO+ 0.12285E-15 -15.9106 0.10165E-15 -15.9929 0.82745E+00 -0.0823 24 HAlO2,aq 0.11082E-09 -9.9554 0.11082E-09 -9.9554 0.10000E+01 0.0000 25 AlO2- 0.16300E-05 -5.7878 0.13431E-05 -5.8719 0.82395E+00 -0.0841 26 CH4,aq 0.18084E-07 -7.7427 0.17998E-07 -7.7448 0.99524E+00 -0.0021 27 C2H6,aq 0.32599E-18 -18.4868 0.32444E-18 -18.4889 0.99524E+00 -0.0021 31 CO,aq 0.42166E-14 -14.3750 0.42166E-14 -14.3750 0.10000E+01 0.0000 32 CO2,aq 0.98810E-06 -6.0052 0.98340E-06 -6.0073 0.99524E+00 -0.0021 33 CO3-2 0.24334E-02 -2.6138 0.12049E-02 -2.9191 0.49514E+00 -0.3053 34 CaCO3,aq 0.19543E-06 -6.7090 0.19543E-06 -6.7090 0.10000E+01 0.0000 35 Ca(HCO3)+ 0.10055E-08 -8.9976 0.83199E-09 -9.0799 0.82745E+00 -0.0823 36 CaCl+ 0.12463E-10 -10.9044 0.10313E-10 -10.9866 0.82745E+00 -0.0823 37 CaCl2,aq 0.12069E-14 -14.9183 0.12069E-14 -14.9183 0.10000E+01 0.0000 38 CaF+ 0.56884E-11 -11.2450 0.47069E-11 -11.3273 0.82745E+00 -0.0823 39 CaOH+ 0.60999E-08 -8.2147 0.50474E-08 -8.2969 0.82745E+00 -0.0823 40 CaSO4,aq 0.70141E-09 -9.1540 0.70141E-09 -9.1540 0.10000E+01 0.0000 41 HCl,aq 0.16488E-13 -13.7828 0.16488E-13 -13.7828 0.10000E+01 0.0000 45 HF,aq 0.31163E-10 -10.5064 0.31163E-10 -10.5064 0.10000E+01 0.0000 46 HF2- 0.31758E-15 -15.4982 0.26221E-15 -15.5814 0.82565E+00 -0.0832 48 FeCl+ 0.11330E-15 -15.9458 0.93754E-16 -16.0280 0.82745E+00 -0.0823 51 FeF+ 0.18506E-15 -15.7327 0.15313E-15 -15.8149 0.82745E+00 -0.0823 53 FeO,aq 0.14007E-09 -9.8537 0.14007E-09 -9.8537 0.10000E+01 0.0000 54 FeOH+ 0.25896E-10 -10.5868 0.21428E-10 -10.6690 0.82745E+00 -0.0823 55 HFeO2- 0.97177E-08 -8.0124 0.80234E-08 -8.0956 0.82565E+00 -0.0832 56 FeO+ 0.14951E-15 -15.8253 0.12371E-15 -15.9076 0.82745E+00 -0.0823 58 FeO2- 0.91892E-09 -9.0367 0.75870E-09 -9.1199 0.82565E+00 -0.0832 59 HFeO2,aq 0.17626E-10 -10.7539 0.17626E-10 -10.7539 0.10000E+01 0.0000 60 H2,aq 0.17150E-06 -6.7657 0.17069E-06 -6.7678 0.99524E+00 -0.0021 61 KCl,aq 0.11547E-08 -8.9375 0.11547E-08 -8.9375 0.10000E+01 0.0000 62 KHSO4,aq 0.11405E-16 -16.9429 0.11405E-16 -16.9429 0.10000E+01 0.0000 63 KOH,aq 0.30237E-06 -6.5195 0.30237E-06 -6.5195 0.10000E+01 0.0000 64 KSO4- 0.41504E-06 -6.3819 0.34267E-06 -6.4651 0.82565E+00 -0.0832 65 MgCO3,aq 0.40507E-10 -10.3925 0.40507E-10 -10.3925 0.10000E+01 0.0000 66 Mg(HCO3)+ 0.84958E-12 -12.0708 0.70299E-12 -12.1531 0.82745E+00 -0.0823 67 MgCl+ 0.93407E-14 -14.0296 0.77289E-14 -14.1119 0.82745E+00 -0.0823 68 MgF+ 0.17424E-13 -13.7588 0.14418E-13 -13.8411 0.82745E+00 -0.0823 69 MgOH+ 0.27911E-10 -10.5542 0.23095E-10 -10.6365 0.82745E+00 -0.0823 71 MnF+ 0.23227E-13 -13.6340 0.19219E-13 -13.7163 0.82745E+00 -0.0823 72 MnO,aq 0.14212E-08 -8.8474 0.14212E-08 -8.8474 0.10000E+01 0.0000 73 MnOH+ 0.91604E-09 -9.0381 0.75798E-09 -9.1203 0.82745E+00 -0.0823 74 MnO2-2 0.28550E-11 -11.5444 0.14136E-11 -11.8497 0.49514E+00 -0.3053 75 HMnO2- 0.68516E-10 -10.1642 0.56570E-10 -10.2474 0.82565E+00 -0.0832 78 MnCl+ 0.16785E-12 -12.7751 0.13889E-12 -12.8573 0.82745E+00 -0.0823 79 MnSO4,aq 0.22570E-11 -11.6465 0.22570E-11 -11.6465 0.10000E+01 0.0000 80 NaCl,aq 0.28000E-05 -5.5528 0.28000E-05 -5.5528 0.10000E+01 0.0000 81 NaF,aq 0.10007E-06 -6.9997 0.10007E-06 -6.9997 0.10000E+01 0.0000 82 NaOH,aq 0.40343E-04 -4.3942 0.40343E-04 -4.3942 0.10000E+01 0.0000 84 OH- 0.38390E-02 -2.4158 0.31631E-02 -2.4999 0.82395E+00 -0.0841 89 HPO3-2 0.24428E-16 -16.6121 0.12095E-16 -16.9174 0.49514E+00 -0.3053 92 H3PO4,aq 0.53062E-17 -17.2752 0.53062E-17 -17.2752 0.10000E+01 0.0000 93 H2PO4- 0.92702E-10 -10.0329 0.76622E-10 -10.1156 0.82654E+00 -0.0827 94 PO4-3 0.46120E-09 -9.3361 0.10157E-09 -9.9932 0.22023E+00 -0.6571 98 HP2O7-3 0.24136E-17 -17.6173 0.50323E-18 -18.2982 0.20850E+00 -0.6809 99 P2O7-4 0.10225E-16 -16.9904 0.65816E-18 -18.1817 0.64370E-01 -1.1913 100 H2S,aq 0.71224E-06 -6.1474 0.70884E-06 -6.1494 0.99524E+00 -0.0021 101 S2-2 0.41336E-09 -9.3837 0.20467E-09 -9.6889 0.49514E+00 -0.3053 102 S3-2 0.23128E-14 -14.6359 0.11452E-14 -14.9411 0.49514E+00 -0.3053 103 S3- 0.41105E-18 -18.3861 0.33938E-18 -18.4693 0.82565E+00 -0.0832 107 SO3-2 0.75249E-11 -11.1235 0.37874E-11 -11.4217 0.50331E+00 -0.2982 108 HSO3- 0.52462E-13 -13.2802 0.43315E-13 -13.3634 0.82565E+00 -0.0832 109 HSO4- 0.36285E-10 -10.4403 0.30057E-10 -10.5220 0.82837E+00 -0.0818 111 S2O3-2 0.28715E-11 -11.5419 0.14218E-11 -11.8472 0.49514E+00 -0.3053 112 HS2O3- 0.56241E-19 -19.2499 0.46435E-19 -19.3332 0.82565E+00 -0.0832 Charge balance for all species = -.6125E-08 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.2197148E-09 -.1411497E-01 -.1420263E+02 0.0000 2 H2O 0.1000000E+01 0.5550434E+02 0.9982115E+06 0.0000 3 Cl- 0.5966365E-03 0.5994376E-03 0.2121540E+02 6.4309 4 SO4-- 0.3440188E-03 0.3443738E-03 0.3302434E+02 15.7091 5 HCO3- 0.3046586E-02 0.5481147E-02 0.3338704E+03 7.1397 6 HS- 0.1520541E-02 0.1521315E-02 0.5022661E+02 6.8372 7 Al+++ 0.1197112E-27 0.1630130E-05 0.4390787E-01 0.6118 8 H4SiO4 0.1024625E-02 0.8821502E-02 0.8464273E+03 -2.9894 9 Ca++ 0.2628335E-07 0.2314049E-06 0.9258332E-02 11.5885 10 Mg++ 0.2184799E-10 0.9306227E-10 0.2258648E-05 8.5060 11 Fe++ 0.2452782E-12 0.1082042E-07 0.6032513E-03 6.5568 12 K+ 0.1563369E-03 0.1570555E-03 0.6130645E+01 5.8501 13 Na+ 0.2077743E-01 0.2227363E-01 0.5111876E+03 7.9727 14 Mn++ 0.9331016E-10 0.2504330E-08 0.1373468E-03 9.1375 15 F- 0.3025515E-04 0.3035526E-04 0.5756997E+00 5.1349 16 HPO4-- 0.4580659E-07 0.4636048E-07 0.4441998E-02 11.8335 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.1270572E-01 -.1269244E-01 -.1327691E-04 0.0000000E+00 2 H2O 0.4990207E+02 0.4991051E+02 -.8434464E-02 0.0000000E+00 3 Cl- 0.5390252E-03 0.5390252E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.3096672E-03 0.3096672E-03 0.0000000E+00 0.0000000E+00 5 HCO3- 0.4928747E-02 0.4928747E-02 0.0000000E+00 0.0000000E+00 6 HS- 0.1367994E-02 0.1367994E-02 0.0000000E+00 0.0000000E+00 7 Al+++ 0.4775352E-05 0.1465842E-05 0.3309510E-05 0.0000000E+00 8 H4SiO4 0.1215302E-01 0.7932454E-02 0.4220566E-02 0.0000000E+00 9 Ca++ 0.2080835E-06 0.2080835E-06 0.0000000E+00 0.0000000E+00 10 Mg++ 0.8368328E-10 0.8368328E-10 0.0000000E+00 0.0000000E+00 11 Fe++ 0.3259227E-07 0.9729921E-08 0.2286235E-07 0.0000000E+00 12 K+ 0.1412294E-03 0.1412271E-03 0.2286235E-08 0.0000000E+00 13 Na+ 0.2003215E-01 0.2002885E-01 0.3300365E-05 0.0000000E+00 14 Mn++ 0.2251939E-08 0.2251939E-08 0.0000000E+00 0.0000000E+00 15 F- 0.2729600E-04 0.2729600E-04 0.0000000E+00 0.0000000E+00 16 HPO4-- 0.4168819E-07 0.4168819E-07 0.0000000E+00 0.0000000E+00 Chg. balance for solid moles: 0.1694E-20 Mass of aqueous solution: 0.900764E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 0.0679900 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 0.3300E-05 -5.481 0.8654E-03 -3.063 0.3409 0.3322E-03 quartz 0.4211E-02 -2.376 0.2530 -0.597 99.66 0.9553E-01 stilpnomelane-Fe 0.4572E-08 -8.340 0.4929E-05 -5.307 0.1942E-02 0.1703E-05 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 quartz 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 0.253845 g Volume = 0.095868 cm3 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.0679900 moles log = -1.1676 Original solution: 1000.0103000 g Original solution / Rock added: 14708.20 (Water/Rock Ratio), log = 4.1676 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0207 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9996E+00 0.9859 0.1006E+01 0.1020E+01 CO2,gas 0.1024E-03 1.0071 0.1052E-03 0.1045E-03 CH4,gas 0.2563E-04 1.0125 0.2649E-04 0.2616E-04 H2,gas 0.2194E-03 1.0005 0.2241E-03 0.2240E-03 H2S,gas 0.1917E-04 0.9960 0.1949E-04 0.1956E-04 S2,gas 0.2781E-21 1.0000 0.2838E-21 0.2838E-21 CO,gas 0.6156E-11 1.0000 0.6284E-11 0.6284E-11 SO3,gas 0.2110E-38 1.0000 0.2154E-38 0.2154E-38 SO2,gas 0.1840E-19 1.0000 0.1878E-19 0.1878E-19 HF,gas 0.7497E-13 1.0000 0.7651E-13 0.7651E-13 HCl,gas 0.2850E-16 1.0000 0.2909E-16 0.2909E-16 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 17 albite -0.38 -0.38 0.00 0.000 -0.13080E-10 150 quartz -2.99 -2.99 0.00 0.000 0.00000E+00 167 stilpnomelane-Fe 13.02 13.02 0.00 0.000 0.21232E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -12.34 -5.68 -1.892 0.96932E+04 -3.978 3 CH4,gas 4.54 -1.73 -6.28 -1.569 0.10716E+05 -4.577 4 H2,gas 8.00 2.65 -5.35 -3.056 0.91325E+04 -3.650 5 H2S,gas -6.23 -12.64 -6.41 -3.205 0.10944E+05 -4.710 6 S2,gas -7.34 -30.58 -23.25 -3.576 0.39692E+05 -21.547 7 CO,gas 3.21 -9.69 -12.90 -3.969 0.22028E+05 -11.202 8 SO3,gas 17.12 -23.24 -40.37 -10.091 0.68923E+05 -38.667 9 SO2,gas 0.83 -20.59 -21.43 -5.713 0.36583E+05 -19.726 10 HF,gas 0.47 -14.34 -14.82 -7.408 0.25297E+05 -13.116 11 HCl,gas 5.19 -13.05 -18.24 -9.118 0.31136E+05 -16.536 12 acmite 7.71 7.22 -0.48 -0.050 0.82773E+03 16 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 20 spessartine 24.46 19.67 -4.79 -0.239 0.81783E+04 21 analcite 3.32 2.61 -0.72 -0.080 0.12231E+04 23 andradite 39.01 36.26 -2.75 -0.143 0.46941E+04 26 ankerite -2.14 -6.53 -4.39 -0.732 0.75021E+04 27 annite 20.12 17.16 -2.96 -0.164 0.50533E+04 28 phlogopite 27.06 23.01 -4.05 -0.225 0.69206E+04 34 apatite-F -34.30 -37.76 -3.46 -0.288 0.59045E+04 38 aragonite 0.97 -0.75 -1.72 -0.572 0.29284E+04 39 brucite 12.57 8.51 -4.06 -0.813 0.69368E+04 40 calcite 0.81 -0.75 -1.56 -0.520 0.26641E+04 41 carnegieite-low 9.02 5.60 -3.43 -0.490 0.58537E+04 42 carnegieite-high 10.09 5.60 -4.50 -0.643 0.76807E+04 43 carpholite-Mg 8.58 3.75 -4.83 -0.322 0.82495E+04 44 carpholite-Fe 6.71 1.80 -4.91 -0.327 0.83857E+04 45 celadonite 5.34 3.01 -2.33 -0.137 0.39810E+04 46 celadonite-Fe 3.88 1.06 -2.82 -0.166 0.48076E+04 47 chrysotile 23.89 19.54 -4.35 -0.363 0.74332E+04 49 clinochlore 39.07 34.79 -4.28 -0.134 0.73154E+04 50 daphnite 28.97 25.04 -3.93 -0.123 0.67038E+04 54 chloritoid-Fe 9.17 4.79 -4.38 -0.292 0.74834E+04 55 chloritoid-Mn 11.40 7.37 -4.03 -0.269 0.68802E+04 57 coesite -2.38 -2.99 -0.61 -0.204 0.10473E+04 64 cristobalite -2.56 -2.99 -0.43 -0.143 0.73267E+03 66 cymrite-K 1.69 -2.51 -4.19 -0.349 0.71575E+04 68 diaspore 2.87 0.61 -2.26 -0.377 0.38622E+04 69 diamond -3.10 -7.03 -3.93 -1.123 0.67141E+04 70 diopside 16.18 14.12 -2.07 -0.207 0.35272E+04 71 hedenbergite 14.21 12.17 -2.04 -0.204 0.34864E+04 78 epidote 24.67 20.66 -4.01 -0.194 0.68409E+04 80 epidote-Fe 29.84 25.28 -4.56 -0.237 0.77826E+04 81 fayalite 14.05 10.12 -3.92 -0.560 0.66961E+04 82 ferrosilite 11.15 7.13 -4.01 -0.401 0.68551E+04 86 gibbsite 4.08 0.61 -3.47 -0.495 0.59207E+04 87 glaucophane 22.97 18.77 -4.20 -0.114 0.71773E+04 88 glaucophane-Fe 17.28 12.92 -4.35 -0.118 0.74311E+04 89 graphite -3.55 -7.03 -3.49 -0.997 0.59564E+04 90 greenalite 16.14 13.69 -2.45 -0.204 0.41800E+04 93 hematite 12.57 10.46 -2.10 -0.255 0.35923E+04 94 heulandite -5.83 -8.11 -2.29 -0.104 0.39045E+04 98 jadeite 4.22 2.61 -1.61 -0.161 0.27485E+04 100 kalsilite 7.58 3.47 -4.11 -0.587 0.70203E+04 101 kaolinite -1.33 -4.76 -3.42 -0.311 0.58439E+04 104 laumontite 2.88 0.85 -2.03 -0.135 0.34646E+04 105 lawsonite 9.62 6.83 -2.78 -0.186 0.47516E+04 106 leucite 4.12 0.48 -3.64 -0.364 0.62082E+04 108 lizardite 23.24 19.54 -3.70 -0.309 0.63258E+04 109 magnesite 0.69 -3.83 -4.52 -1.507 0.77206E+04 110 magnetite 20.09 17.02 -3.07 -0.250 0.52390E+04 111 minnesotaite 10.39 7.71 -2.68 -0.157 0.45684E+04 115 manganosite 14.06 9.14 -4.92 -1.230 0.84019E+04 119 microcline -2.49 -2.51 -0.02 -0.002 0.34097E+02 123 muscovite 2.58 -1.28 -3.87 -0.227 0.65999E+04 124 paragonite 4.24 0.84 -3.40 -0.200 0.58049E+04 125 nepheline 8.34 5.60 -2.74 -0.392 0.46861E+04 137 phlogopite-Na 29.65 25.13 -4.51 -0.251 0.77053E+04 139 prehnite 19.37 15.43 -3.94 -0.232 0.67267E+04 140 prehnite-Fe 22.50 20.05 -2.45 -0.147 0.41768E+04 145 pyrite -21.25 -21.37 -0.13 -0.030 0.21600E+03 146 pyrrhotite -4.26 -6.08 -1.82 -0.607 0.31117E+04 147 pyrrhotiteFe0.875 -6.02 -7.23 -1.21 -0.447 0.20731E+04 148 pyroxmangite 7.40 6.15 -1.25 -0.250 0.21355E+04 149 pyrophyllite -6.18 -10.73 -4.56 -0.285 0.77833E+04 154 rhodochrosite -0.98 -3.20 -2.22 -0.741 0.37962E+04 155 rhodonite 7.45 6.15 -1.30 -0.260 0.22157E+04 156 sanidine -1.28 -2.51 -1.23 -0.095 0.21018E+04 158 siderite -2.61 -5.78 -3.17 -1.057 0.54163E+04 166 stilbite -7.52 -8.11 -0.59 -0.028 0.10107E+04 168 stilpnomelane-Mg 27.44 22.76 -4.68 -0.140 0.79882E+04 174 talc 16.49 13.56 -2.93 -0.172 0.50044E+04 177 tephroite 18.09 15.29 -2.80 -0.400 0.47815E+04 181 tridymite -2.63 -2.99 -0.36 -0.121 0.61998E+03 184 troilite-low -4.41 -6.08 -1.67 -0.557 0.28545E+04 190 wairakite 3.95 0.85 -3.10 -0.182 0.52865E+04 191 walstromite 11.51 8.60 -2.91 -0.582 0.49690E+04 192 wollastonite 10.46 8.60 -1.86 -0.372 0.31794E+04 193 pseudo-wollastonite 11.00 8.60 -2.40 -0.480 0.40992E+04 195 akaganeite 7.75 5.23 -2.52 -0.546 0.43087E+04 202 chalcedony -2.80 -2.99 -0.19 -0.062 0.31930E+03 204 montmorillonite-Ca -2.29 -6.22 -3.93 -0.243 0.67040E+04 205 montmorillonite-K -2.24 -6.20 -3.96 -0.243 0.67647E+04 206 montmorillonite-Mg -2.48 -6.73 -4.25 -0.263 0.72495E+04 207 montmorillonite-Na -2.04 -5.50 -3.46 -0.212 0.59084E+04 208 nontronite-Ca 3.21 1.61 -1.61 -0.104 0.27481E+04 209 nontronite-H 2.53 -0.31 -2.84 -0.190 0.48487E+04 210 nontronite-K 3.34 1.62 -1.72 -0.110 0.29321E+04 211 nontronite-Mg 3.07 1.10 -1.98 -0.128 0.33776E+04 212 nontronite-Na 3.52 2.32 -1.20 -0.077 0.20417E+04 228 tobermorite 9.82 6.66 -3.16 -0.862 0.53943E+04 234 alabandite -0.98 -3.50 -2.52 -0.841 0.43100E+04 237 boehmite 4.41 0.61 -3.79 -0.632 0.64791E+04 239 ferrous-oxide 9.81 6.56 -3.25 -0.814 0.55575E+04 245 silica-amorphous -2.09 -2.99 -0.90 -0.299 0.15335E+04 247 an20ab80 2.02 1.06 -0.96 -0.074 0.16361E+04 248 an25ab75 2.65 1.42 -1.23 -0.094 0.20922E+04 249 an30ab70 3.28 1.78 -1.50 -0.115 0.25578E+04 250 tr.625ac.25prg.125 45.16 40.27 -4.90 -0.132 0.83661E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 0.0020000 MOLES Current total amount of reactant added: 0.0679900 MOLES New total amount of reactant added: 0.0699900 MOLES Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.5508E-08 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 8 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 0.0699900 Water: Moles liquid = 0.4992E+02 kg liquid = 0.8993E+00 Moles total = 0.4990E+02 kg total = 0.8990E+00 Activity = 1.0000 Stoichiometric ionic strength = .1585898E-01 Osmotic coef. = 0.9275 True ionic strength = .2379333E-01 Chg. balance for total moles = -.5508E-08 Max. difference allowed = 0.5508E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.22521E-09 -9.6474 0.18719E-09 -9.7277 0.83116E+00 -0.0803 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.60967E-03 -3.2149 0.50325E-03 -3.2982 0.82545E+00 -0.0833 4 SO4-- 0.35461E-03 -3.4502 0.17584E-03 -3.7549 0.49587E+00 -0.3046 5 HCO3- 0.31689E-02 -2.4991 0.26201E-02 -2.5817 0.82683E+00 -0.0826 6 HS- 0.15639E-02 -2.8058 0.12911E-02 -2.8890 0.82558E+00 -0.0832 7 Al+++ 0.13214E-27 -27.8790 0.27458E-28 -28.5613 0.20779E+00 -0.6824 8 H4SiO4 0.10246E-02 -2.9894 0.10246E-02 -2.9894 0.10000E+01 0.0000 9 Ca++ 0.25996E-07 -7.5851 0.12782E-07 -7.8934 0.49170E+00 -0.3083 10 Mg++ 0.21883E-10 -10.6599 0.10704E-10 -10.9705 0.48913E+00 -0.3106 11 Fe++ 0.25610E-12 -12.5916 0.12542E-12 -12.9016 0.48974E+00 -0.3100 12 K+ 0.15633E-03 -3.8060 0.12929E-03 -3.8884 0.82705E+00 -0.0825 13 Na+ 0.20811E-01 -1.6817 0.17174E-01 -1.7651 0.82527E+00 -0.0834 14 Mn++ 0.97074E-10 -10.0129 0.47586E-10 -10.3225 0.49020E+00 -0.3096 15 F- 0.31141E-04 -4.5067 0.25645E-04 -4.5910 0.82351E+00 -0.0843 16 HPO4-- 0.45813E-07 -7.3390 0.22721E-07 -7.6436 0.49595E+00 -0.3046 18 HSiO3- 0.61919E-02 -2.2082 0.51111E-02 -2.2915 0.82545E+00 -0.0833 19 Ca(HSiO3)+ 0.17985E-08 -8.7451 0.14878E-08 -8.8274 0.82725E+00 -0.0824 20 Mg(HSiO3)+ 0.18743E-11 -11.7272 0.15505E-11 -11.8095 0.82725E+00 -0.0824 21 NaHSiO3,aq 0.14197E-02 -2.8478 0.14197E-02 -2.8478 0.10000E+01 0.0000 22 AlO+ 0.12887E-15 -15.8899 0.10661E-15 -15.9722 0.82725E+00 -0.0824 24 HAlO2,aq 0.11342E-09 -9.9453 0.11342E-09 -9.9453 0.10000E+01 0.0000 25 AlO2- 0.16282E-05 -5.7883 0.13412E-05 -5.8725 0.82375E+00 -0.0842 26 CH4,aq 0.18778E-07 -7.7264 0.18687E-07 -7.7285 0.99520E+00 -0.0021 27 C2H6,aq 0.35375E-18 -18.4513 0.35205E-18 -18.4534 0.99520E+00 -0.0021 31 CO,aq 0.44644E-14 -14.3502 0.44644E-14 -14.3502 0.10000E+01 0.0000 32 CO2,aq 0.10530E-05 -5.9776 0.10480E-05 -5.9796 0.99520E+00 -0.0021 33 CO3-2 0.24716E-02 -2.6070 0.12226E-02 -2.9127 0.49467E+00 -0.3057 34 CaCO3,aq 0.19595E-06 -6.7078 0.19595E-06 -6.7078 0.10000E+01 0.0000 35 Ca(HCO3)+ 0.10334E-08 -8.9857 0.85489E-09 -9.0681 0.82725E+00 -0.0824 36 CaCl+ 0.12584E-10 -10.9002 0.10410E-10 -10.9825 0.82725E+00 -0.0824 37 CaCl2,aq 0.12446E-14 -14.9050 0.12446E-14 -14.9050 0.10000E+01 0.0000 38 CaF+ 0.57852E-11 -11.2377 0.47858E-11 -11.3200 0.82725E+00 -0.0824 39 CaOH+ 0.58829E-08 -8.2304 0.48667E-08 -8.3128 0.82725E+00 -0.0824 40 CaSO4,aq 0.71373E-09 -9.1465 0.71373E-09 -9.1465 0.10000E+01 0.0000 41 HCl,aq 0.17262E-13 -13.7629 0.17262E-13 -13.7629 0.10000E+01 0.0000 45 HF,aq 0.32862E-10 -10.4833 0.32862E-10 -10.4833 0.10000E+01 0.0000 46 HF2- 0.34469E-15 -15.4626 0.28452E-15 -15.5459 0.82545E+00 -0.0833 48 FeCl+ 0.12077E-15 -15.9180 0.99908E-16 -16.0004 0.82725E+00 -0.0824 51 FeF+ 0.19869E-15 -15.7018 0.16437E-15 -15.7842 0.82725E+00 -0.0824 53 FeO,aq 0.13912E-09 -9.8566 0.13912E-09 -9.8566 0.10000E+01 0.0000 54 FeOH+ 0.26365E-10 -10.5790 0.21811E-10 -10.6613 0.82725E+00 -0.0824 55 HFeO2- 0.94208E-08 -8.0259 0.77764E-08 -8.1092 0.82545E+00 -0.0833 56 FeO+ 0.15271E-15 -15.8161 0.12633E-15 -15.8985 0.82725E+00 -0.0824 58 FeO2- 0.89375E-09 -9.0488 0.73774E-09 -9.1321 0.82545E+00 -0.0833 59 HFeO2,aq 0.17564E-10 -10.7554 0.17564E-10 -10.7554 0.10000E+01 0.0000 60 H2,aq 0.17040E-06 -6.7685 0.16958E-06 -6.7706 0.99520E+00 -0.0021 61 KCl,aq 0.11793E-08 -8.9284 0.11793E-08 -8.9284 0.10000E+01 0.0000 62 KHSO4,aq 0.12032E-16 -16.9197 0.12032E-16 -16.9197 0.10000E+01 0.0000 63 KOH,aq 0.29497E-06 -6.5302 0.29497E-06 -6.5302 0.10000E+01 0.0000 64 KSO4- 0.42739E-06 -6.3692 0.35279E-06 -6.4525 0.82545E+00 -0.0833 65 MgCO3,aq 0.41130E-10 -10.3858 0.41130E-10 -10.3858 0.10000E+01 0.0000 66 Mg(HCO3)+ 0.88424E-12 -12.0534 0.73149E-12 -12.1358 0.82725E+00 -0.0824 67 MgCl+ 0.95507E-14 -14.0200 0.79008E-14 -14.1023 0.82725E+00 -0.0824 68 MgF+ 0.17945E-13 -13.7461 0.14845E-13 -13.8284 0.82725E+00 -0.0824 69 MgOH+ 0.27260E-10 -10.5645 0.22551E-10 -10.6468 0.82725E+00 -0.0824 71 MnF+ 0.24847E-13 -13.6047 0.20555E-13 -13.6871 0.82725E+00 -0.0824 72 MnO,aq 0.14064E-08 -8.8519 0.14064E-08 -8.8519 0.10000E+01 0.0000 73 MnOH+ 0.92924E-09 -9.0319 0.76872E-09 -9.1142 0.82725E+00 -0.0824 74 MnO2-2 0.26929E-11 -11.5698 0.13321E-11 -11.8755 0.49467E+00 -0.3057 75 HMnO2- 0.66181E-10 -10.1793 0.54629E-10 -10.2626 0.82545E+00 -0.0833 78 MnCl+ 0.17826E-12 -12.7489 0.14747E-12 -12.8313 0.82725E+00 -0.0824 79 MnSO4,aq 0.24157E-11 -11.6170 0.24157E-11 -11.6170 0.10000E+01 0.0000 80 NaCl,aq 0.28643E-05 -5.5430 0.28643E-05 -5.5430 0.10000E+01 0.0000 81 NaF,aq 0.10311E-06 -6.9867 0.10311E-06 -6.9867 0.10000E+01 0.0000 82 NaOH,aq 0.39420E-04 -4.4043 0.39420E-04 -4.4043 0.10000E+01 0.0000 84 OH- 0.37470E-02 -2.4263 0.30866E-02 -2.5105 0.82375E+00 -0.0842 89 HPO3-2 0.24274E-16 -16.6149 0.12007E-16 -16.9206 0.49467E+00 -0.3057 92 H3PO4,aq 0.55681E-17 -17.2543 0.55681E-17 -17.2543 0.10000E+01 0.0000 93 H2PO4- 0.94947E-10 -10.0225 0.78459E-10 -10.1054 0.82634E+00 -0.0828 94 PO4-3 0.45059E-09 -9.3462 0.99034E-10 -10.0042 0.21979E+00 -0.6580 98 HP2O7-3 0.24749E-17 -17.6065 0.51488E-18 -18.2883 0.20804E+00 -0.6818 99 P2O7-4 0.10247E-16 -16.9894 0.65710E-18 -18.1824 0.64127E-01 -1.1930 100 H2S,aq 0.75054E-06 -6.1246 0.74694E-06 -6.1267 0.99520E+00 -0.0021 101 S2-2 0.44032E-09 -9.3562 0.21781E-09 -9.6619 0.49467E+00 -0.3057 102 S3-2 0.26130E-14 -14.5829 0.12925E-14 -14.8886 0.49467E+00 -0.3057 103 S3- 0.47712E-18 -18.3214 0.39384E-18 -18.4047 0.82545E+00 -0.0833 104 S4-2 0.10243E-19 -19.9896 0.50668E-20 -20.2953 0.49467E+00 -0.3057 107 SO3-2 0.77060E-11 -11.1132 0.38750E-11 -11.4117 0.50285E+00 -0.2986 108 HSO3- 0.55020E-13 -13.2595 0.45416E-13 -13.3428 0.82545E+00 -0.0833 109 HSO4- 0.38303E-10 -10.4168 0.31721E-10 -10.4986 0.82818E+00 -0.0819 111 S2O3-2 0.31190E-11 -11.5060 0.15429E-11 -11.8117 0.49467E+00 -0.3057 112 HS2O3- 0.62559E-19 -19.2037 0.51639E-19 -19.2870 0.82545E+00 -0.0833 Charge balance for all species = -.6125E-08 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.2252129E-09 -.1387495E-01 -.1396117E+02 0.0000 2 H2O 0.1000000E+01 0.5550443E+02 0.9982163E+06 0.0000 3 Cl- 0.6096715E-03 0.6125370E-03 0.2167908E+02 6.4295 4 SO4-- 0.3546137E-03 0.3549807E-03 0.3404161E+02 15.7006 5 HCO3- 0.3168892E-02 0.5641740E-02 0.3436536E+03 7.1460 6 HS- 0.1563870E-02 0.1564683E-02 0.5165856E+02 6.8387 7 Al+++ 0.1321419E-27 0.1628324E-05 0.4385936E-01 0.6218 8 H4SiO4 0.1024625E-02 0.8636268E-02 0.8286567E+03 -2.9894 9 Ca++ 0.2599596E-07 0.2313962E-06 0.9258012E-02 11.5621 10 Mg++ 0.2188318E-10 0.9305875E-10 0.2258569E-05 8.4850 11 Fe++ 0.2561047E-12 0.1049785E-07 0.5852691E-03 6.5538 12 K+ 0.1563259E-03 0.1570495E-03 0.6130431E+01 5.8393 13 Na+ 0.2081067E-01 0.2227278E-01 0.5111698E+03 7.9626 14 Mn++ 0.9707401E-10 0.2504235E-08 0.1373420E-03 9.1329 15 F- 0.3114059E-04 0.3124374E-04 0.5925519E+00 5.1367 16 HPO4-- 0.4581320E-07 0.4635873E-07 0.4441844E-02 11.8119 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.1249037E-01 -.1247708E-01 -.1328367E-04 0.0000000E+00 2 H2O 0.4990371E+02 0.4991248E+02 -.8767004E-02 0.0000000E+00 3 Cl- 0.5508252E-03 0.5508252E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.3192172E-03 0.3192172E-03 0.0000000E+00 0.0000000E+00 5 HCO3- 0.5073347E-02 0.5073347E-02 0.0000000E+00 0.0000000E+00 6 HS- 0.1407044E-02 0.1407044E-02 0.0000000E+00 0.0000000E+00 7 Al+++ 0.4775352E-05 0.1464273E-05 0.3311079E-05 0.0000000E+00 8 H4SiO4 0.1215302E-01 0.7766183E-02 0.4386837E-02 0.0000000E+00 9 Ca++ 0.2080835E-06 0.2080835E-06 0.0000000E+00 0.0000000E+00 10 Mg++ 0.8368328E-10 0.8368328E-10 0.0000000E+00 0.0000000E+00 11 Fe++ 0.3259227E-07 0.9440210E-08 0.2315206E-07 0.0000000E+00 12 K+ 0.1412294E-03 0.1412271E-03 0.2315206E-08 0.0000000E+00 13 Na+ 0.2003215E-01 0.2002885E-01 0.3301818E-05 0.0000000E+00 14 Mn++ 0.2251939E-08 0.2251939E-08 0.0000000E+00 0.0000000E+00 15 F- 0.2809600E-04 0.2809600E-04 0.0000000E+00 0.0000000E+00 16 HPO4-- 0.4168819E-07 0.4168819E-07 0.0000000E+00 0.0000000E+00 Chg. balance for solid moles: 0.8470E-21 Mass of aqueous solution: 0.900795E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 0.0699900 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 0.3302E-05 -5.481 0.8658E-03 -3.063 0.3282 0.3324E-03 quartz 0.4377E-02 -2.359 0.2630 -0.580 99.67 0.9931E-01 stilpnomelane-Fe 0.4630E-08 -8.334 0.4992E-05 -5.302 0.1892E-02 0.1724E-05 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 quartz 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 0.263835 g Volume = 0.099641 cm3 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.0699900 moles log = -1.1550 Original solution: 1000.0103000 g Original solution / Rock added: 14287.90 (Water/Rock Ratio), log = 4.1550 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0207 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9996E+00 0.9859 0.1006E+01 0.1020E+01 CO2,gas 0.1091E-03 1.0071 0.1121E-03 0.1113E-03 CH4,gas 0.2662E-04 1.0125 0.2751E-04 0.2717E-04 H2,gas 0.2180E-03 1.0005 0.2226E-03 0.2225E-03 H2S,gas 0.2020E-04 0.9960 0.2053E-04 0.2061E-04 S2,gas 0.3128E-21 1.0000 0.3193E-21 0.3193E-21 CO,gas 0.6518E-11 1.0000 0.6653E-11 0.6653E-11 SO3,gas 0.2282E-38 1.0000 0.2330E-38 0.2330E-38 SO2,gas 0.1977E-19 1.0000 0.2018E-19 0.2018E-19 HF,gas 0.7905E-13 1.0000 0.8069E-13 0.8069E-13 HCl,gas 0.2984E-16 1.0000 0.3046E-16 0.3046E-16 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 17 albite -0.38 -0.38 0.00 0.000 -0.13080E-10 150 quartz -2.99 -2.99 0.00 0.000 0.00000E+00 167 stilpnomelane-Fe 13.02 13.02 0.00 0.000 0.21232E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -12.31 -5.65 -1.883 0.96460E+04 -3.950 3 CH4,gas 4.54 -1.72 -6.26 -1.565 0.10688E+05 -4.561 4 H2,gas 8.00 2.65 -5.35 -3.058 0.91373E+04 -3.652 5 H2S,gas -6.23 -12.62 -6.39 -3.193 0.10905E+05 -4.688 6 S2,gas -7.34 -30.53 -23.19 -3.568 0.39605E+05 -21.496 7 CO,gas 3.21 -9.66 -12.88 -3.962 0.21985E+05 -11.177 8 SO3,gas 17.12 -23.21 -40.33 -10.083 0.68865E+05 -38.633 9 SO2,gas 0.83 -20.56 -21.39 -5.705 0.36530E+05 -19.695 10 HF,gas 0.47 -14.32 -14.79 -7.396 0.25257E+05 -13.093 11 HCl,gas 5.19 -13.03 -18.22 -9.108 0.31102E+05 -16.516 12 acmite 7.71 7.21 -0.50 -0.052 0.84750E+03 16 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 20 spessartine 24.46 19.67 -4.78 -0.239 0.81672E+04 21 analcite 3.32 2.61 -0.72 -0.080 0.12231E+04 23 andradite 39.01 36.18 -2.83 -0.147 0.48349E+04 26 ankerite -2.14 -6.50 -4.37 -0.728 0.74580E+04 27 annite 20.12 17.15 -2.97 -0.165 0.50697E+04 28 phlogopite 27.06 22.95 -4.12 -0.229 0.70294E+04 34 apatite-F -34.30 -37.81 -3.50 -0.292 0.59839E+04 38 aragonite 0.97 -0.75 -1.71 -0.571 0.29264E+04 39 brucite 12.57 8.48 -4.08 -0.817 0.69726E+04 40 calcite 0.81 -0.75 -1.56 -0.520 0.26622E+04 41 carnegieite-low 9.02 5.60 -3.43 -0.490 0.58537E+04 42 carnegieite-high 10.09 5.60 -4.50 -0.643 0.76807E+04 43 carpholite-Mg 8.58 3.75 -4.83 -0.322 0.82510E+04 44 carpholite-Fe 6.71 1.82 -4.89 -0.326 0.83564E+04 45 celadonite 5.34 2.99 -2.35 -0.138 0.40181E+04 46 celadonite-Fe 3.88 1.06 -2.82 -0.166 0.48139E+04 47 chrysotile 23.89 19.48 -4.42 -0.368 0.75408E+04 49 clinochlore 39.07 34.70 -4.37 -0.137 0.74604E+04 50 daphnite 28.97 25.04 -3.92 -0.123 0.66946E+04 54 chloritoid-Fe 9.17 4.81 -4.37 -0.291 0.74541E+04 55 chloritoid-Mn 11.40 7.39 -4.01 -0.268 0.68537E+04 57 coesite -2.38 -2.99 -0.61 -0.204 0.10473E+04 64 cristobalite -2.56 -2.99 -0.43 -0.143 0.73267E+03 66 cymrite-K 1.69 -2.51 -4.19 -0.349 0.71587E+04 68 diaspore 2.87 0.62 -2.25 -0.375 0.38450E+04 69 diamond -3.10 -7.01 -3.91 -1.117 0.66766E+04 70 diopside 16.18 14.07 -2.11 -0.211 0.36082E+04 71 hedenbergite 14.21 12.14 -2.07 -0.207 0.35366E+04 78 epidote 24.67 20.63 -4.04 -0.196 0.68996E+04 80 epidote-Fe 29.84 25.24 -4.60 -0.239 0.78610E+04 81 fayalite 14.05 10.12 -3.93 -0.561 0.67061E+04 82 ferrosilite 11.15 7.13 -4.02 -0.402 0.68652E+04 86 gibbsite 4.08 0.62 -3.46 -0.494 0.59035E+04 87 glaucophane 22.97 18.71 -4.27 -0.115 0.72849E+04 88 glaucophane-Fe 17.28 12.91 -4.36 -0.118 0.74462E+04 89 graphite -3.55 -7.01 -3.47 -0.990 0.59189E+04 90 greenalite 16.14 13.68 -2.46 -0.205 0.41951E+04 93 hematite 12.57 10.46 -2.11 -0.255 0.35975E+04 94 heulandite -5.83 -8.12 -2.29 -0.104 0.39154E+04 98 jadeite 4.22 2.61 -1.61 -0.161 0.27485E+04 100 kalsilite 7.58 3.47 -4.11 -0.587 0.70215E+04 101 kaolinite -1.33 -4.74 -3.40 -0.309 0.58096E+04 104 laumontite 2.88 0.85 -2.04 -0.136 0.34754E+04 105 lawsonite 9.62 6.83 -2.79 -0.186 0.47625E+04 106 leucite 4.12 0.48 -3.64 -0.364 0.62094E+04 108 lizardite 23.24 19.48 -3.77 -0.314 0.64334E+04 109 magnesite 0.69 -3.82 -4.52 -1.505 0.77093E+04 110 magnetite 20.09 17.01 -3.07 -0.251 0.52493E+04 111 minnesotaite 10.39 7.70 -2.68 -0.158 0.45835E+04 115 manganosite 14.06 9.13 -4.93 -1.231 0.84096E+04 119 microcline -2.49 -2.51 -0.02 -0.002 0.35330E+02 123 muscovite 2.58 -1.26 -3.85 -0.226 0.65669E+04 124 paragonite 4.24 0.86 -3.38 -0.199 0.57706E+04 125 nepheline 8.34 5.60 -2.74 -0.392 0.46861E+04 137 phlogopite-Na 29.65 25.07 -4.58 -0.254 0.78129E+04 139 prehnite 19.37 15.40 -3.97 -0.234 0.67828E+04 140 prehnite-Fe 22.50 20.01 -2.49 -0.150 0.42526E+04 145 pyrite -21.25 -21.33 -0.08 -0.019 0.13856E+03 146 pyrrhotite -4.26 -6.06 -1.80 -0.601 0.30779E+04 147 pyrrhotiteFe0.875 -6.02 -7.21 -1.19 -0.439 0.20381E+04 148 pyroxmangite 7.40 6.14 -1.26 -0.251 0.21432E+04 149 pyrophyllite -6.18 -10.71 -4.54 -0.284 0.77490E+04 154 rhodochrosite -0.98 -3.18 -2.20 -0.733 0.37567E+04 155 rhodonite 7.45 6.14 -1.30 -0.260 0.22235E+04 156 sanidine -1.28 -2.51 -1.23 -0.095 0.21031E+04 158 siderite -2.61 -5.76 -3.15 -1.049 0.53741E+04 166 stilbite -7.52 -8.12 -0.60 -0.028 0.10215E+04 168 stilpnomelane-Mg 27.44 22.67 -4.77 -0.142 0.81424E+04 174 talc 16.49 13.50 -2.99 -0.176 0.51120E+04 177 tephroite 18.09 15.28 -2.81 -0.401 0.47969E+04 181 tridymite -2.63 -2.99 -0.36 -0.121 0.61998E+03 184 troilite-low -4.41 -6.06 -1.65 -0.551 0.28207E+04 190 wairakite 3.95 0.85 -3.10 -0.182 0.52974E+04 191 walstromite 11.51 8.57 -2.94 -0.587 0.50142E+04 192 wollastonite 10.46 8.57 -1.89 -0.378 0.32246E+04 193 pseudo-wollastonite 11.00 8.57 -2.43 -0.485 0.41444E+04 195 akaganeite 7.75 5.23 -2.52 -0.546 0.43113E+04 202 chalcedony -2.80 -2.99 -0.19 -0.062 0.31930E+03 204 montmorillonite-Ca -2.29 -6.21 -3.92 -0.243 0.66946E+04 205 montmorillonite-K -2.24 -6.19 -3.96 -0.242 0.67540E+04 206 montmorillonite-Mg -2.48 -6.72 -4.24 -0.262 0.72386E+04 207 montmorillonite-Na -2.04 -5.49 -3.45 -0.211 0.58972E+04 208 nontronite-Ca 3.21 1.60 -1.61 -0.105 0.27551E+04 209 nontronite-H 2.53 -0.31 -2.84 -0.190 0.48483E+04 210 nontronite-K 3.34 1.62 -1.72 -0.110 0.29377E+04 211 nontronite-Mg 3.07 1.09 -1.98 -0.129 0.33831E+04 212 nontronite-Na 3.52 2.32 -1.20 -0.077 0.20469E+04 228 tobermorite 9.82 6.64 -3.18 -0.868 0.54320E+04 234 alabandite -0.98 -3.48 -2.51 -0.835 0.42789E+04 237 boehmite 4.41 0.62 -3.78 -0.631 0.64619E+04 239 ferrous-oxide 9.81 6.55 -3.26 -0.814 0.55625E+04 245 silica-amorphous -2.09 -2.99 -0.90 -0.299 0.15335E+04 247 an20ab80 2.02 1.06 -0.96 -0.074 0.16383E+04 248 an25ab75 2.65 1.42 -1.23 -0.094 0.20949E+04 249 an30ab70 3.28 1.78 -1.50 -0.115 0.25610E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 0.0020000 MOLES Current total amount of reactant added: 0.0699900 MOLES New total amount of reactant added: 0.0719900 MOLES Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.5508E-08 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 8 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 0.0719900 Water: Moles liquid = 0.4992E+02 kg liquid = 0.8993E+00 Moles total = 0.4991E+02 kg total = 0.8991E+00 Activity = 1.0000 Stoichiometric ionic strength = .1598871E-01 Osmotic coef. = 0.9271 True ionic strength = .2387278E-01 Chg. balance for total moles = -.5508E-08 Max. difference allowed = 0.5626E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.23093E-09 -9.6365 0.19190E-09 -9.7169 0.83098E+00 -0.0804 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.62271E-03 -3.2057 0.51389E-03 -3.2891 0.82525E+00 -0.0834 4 SO4-- 0.36521E-03 -3.4375 0.18093E-03 -3.7425 0.49542E+00 -0.3050 5 HCO3- 0.32935E-02 -2.4823 0.27226E-02 -2.5650 0.82664E+00 -0.0827 6 HS- 0.16072E-02 -2.7939 0.13266E-02 -2.8773 0.82539E+00 -0.0833 7 Al+++ 0.14607E-27 -27.8354 0.30288E-28 -28.5187 0.20735E+00 -0.6833 8 H4SiO4 0.10246E-02 -2.9894 0.10246E-02 -2.9894 0.10000E+01 0.0000 9 Ca++ 0.25735E-07 -7.5895 0.12642E-07 -7.8982 0.49124E+00 -0.3087 10 Mg++ 0.21925E-10 -10.6591 0.10714E-10 -10.9700 0.48866E+00 -0.3110 11 Fe++ 0.26757E-12 -12.5726 0.13091E-12 -12.8830 0.48927E+00 -0.3104 12 K+ 0.15631E-03 -3.8060 0.12925E-03 -3.8886 0.82686E+00 -0.0826 13 Na+ 0.20844E-01 -1.6810 0.17198E-01 -1.7645 0.82508E+00 -0.0835 14 Mn++ 0.10102E-09 -9.9956 0.49474E-10 -10.3056 0.48974E+00 -0.3100 15 F- 0.32026E-04 -4.4945 0.26367E-04 -4.5789 0.82331E+00 -0.0844 16 HPO4-- 0.45820E-07 -7.3389 0.22704E-07 -7.6439 0.49550E+00 -0.3050 18 HSiO3- 0.60413E-02 -2.2189 0.49856E-02 -2.3023 0.82525E+00 -0.0834 19 Ca(HSiO3)+ 0.17355E-08 -8.7606 0.14354E-08 -8.8430 0.82706E+00 -0.0825 20 Mg(HSiO3)+ 0.18305E-11 -11.7374 0.15139E-11 -11.8199 0.82706E+00 -0.0825 21 NaHSiO3,aq 0.13867E-02 -2.8580 0.13867E-02 -2.8580 0.10000E+01 0.0000 22 AlO+ 0.13529E-15 -15.8687 0.11189E-15 -15.9512 0.82706E+00 -0.0825 24 HAlO2,aq 0.11612E-09 -9.9351 0.11612E-09 -9.9351 0.10000E+01 0.0000 25 AlO2- 0.16264E-05 -5.7888 0.13394E-05 -5.8731 0.82355E+00 -0.0843 26 CH4,aq 0.19485E-07 -7.7103 0.19390E-07 -7.7124 0.99516E+00 -0.0021 27 C2H6,aq 0.38339E-18 -18.4164 0.38154E-18 -18.4185 0.99516E+00 -0.0021 31 CO,aq 0.47246E-14 -14.3256 0.47246E-14 -14.3256 0.10000E+01 0.0000 32 CO2,aq 0.11218E-05 -5.9501 0.11164E-05 -5.9522 0.99516E+00 -0.0021 33 CO3-2 0.25074E-02 -2.6008 0.12392E-02 -2.9069 0.49421E+00 -0.3061 34 CaCO3,aq 0.19643E-06 -6.7068 0.19643E-06 -6.7068 0.10000E+01 0.0000 35 Ca(HCO3)+ 0.10623E-08 -8.9738 0.87856E-09 -9.0562 0.82706E+00 -0.0825 36 CaCl+ 0.12712E-10 -10.8958 0.10513E-10 -10.9783 0.82706E+00 -0.0825 37 CaCl2,aq 0.12836E-14 -14.8916 0.12836E-14 -14.8916 0.10000E+01 0.0000 38 CaF+ 0.58843E-11 -11.2303 0.48667E-11 -11.3128 0.82706E+00 -0.0825 39 CaOH+ 0.56767E-08 -8.2459 0.46950E-08 -8.3284 0.82706E+00 -0.0825 40 CaSO4,aq 0.72632E-09 -9.1389 0.72632E-09 -9.1389 0.10000E+01 0.0000 41 HCl,aq 0.18071E-13 -13.7430 0.18071E-13 -13.7430 0.10000E+01 0.0000 45 HF,aq 0.34639E-10 -10.4604 0.34639E-10 -10.4604 0.10000E+01 0.0000 46 HF2- 0.37366E-15 -15.4275 0.30836E-15 -15.5109 0.82525E+00 -0.0834 48 FeCl+ 0.12875E-15 -15.8902 0.10649E-15 -15.9727 0.82706E+00 -0.0825 51 FeF+ 0.21328E-15 -15.6710 0.17640E-15 -15.7535 0.82706E+00 -0.0825 53 FeO,aq 0.13817E-09 -9.8596 0.13817E-09 -9.8596 0.10000E+01 0.0000 54 FeOH+ 0.26850E-10 -10.5711 0.22206E-10 -10.6535 0.82706E+00 -0.0825 55 HFeO2- 0.91284E-08 -8.0396 0.75333E-08 -8.1230 0.82525E+00 -0.0834 56 FeO+ 0.15603E-15 -15.8068 0.12905E-15 -15.8893 0.82706E+00 -0.0825 58 FeO2- 0.86886E-09 -9.0610 0.71703E-09 -9.1445 0.82525E+00 -0.0834 59 HFeO2,aq 0.17501E-10 -10.7569 0.17501E-10 -10.7569 0.10000E+01 0.0000 60 H2,aq 0.16929E-06 -6.7714 0.16847E-06 -6.7735 0.99516E+00 -0.0021 61 KCl,aq 0.12038E-08 -8.9194 0.12038E-08 -8.9194 0.10000E+01 0.0000 62 KHSO4,aq 0.12688E-16 -16.8966 0.12688E-16 -16.8966 0.10000E+01 0.0000 63 KOH,aq 0.28763E-06 -6.5412 0.28763E-06 -6.5412 0.10000E+01 0.0000 64 KSO4- 0.43972E-06 -6.3568 0.36288E-06 -6.4402 0.82525E+00 -0.0834 65 MgCO3,aq 0.41729E-10 -10.3796 0.41729E-10 -10.3796 0.10000E+01 0.0000 66 Mg(HCO3)+ 0.91992E-12 -12.0363 0.76083E-12 -12.1187 0.82706E+00 -0.0825 67 MgCl+ 0.97643E-14 -14.0104 0.80757E-14 -14.0928 0.82706E+00 -0.0825 68 MgF+ 0.18473E-13 -13.7335 0.15279E-13 -13.8159 0.82706E+00 -0.0825 69 MgOH+ 0.26622E-10 -10.5748 0.22018E-10 -10.6572 0.82706E+00 -0.0825 71 MnF+ 0.26567E-13 -13.5757 0.21973E-13 -13.6581 0.82706E+00 -0.0825 72 MnO,aq 0.13913E-08 -8.8566 0.13913E-08 -8.8566 0.10000E+01 0.0000 73 MnOH+ 0.94261E-09 -9.0257 0.77960E-09 -9.1081 0.82706E+00 -0.0825 74 MnO2-2 0.25370E-11 -11.5957 0.12538E-11 -11.9018 0.49421E+00 -0.3061 75 HMnO2- 0.63876E-10 -10.1947 0.52714E-10 -10.2781 0.82525E+00 -0.0834 78 MnCl+ 0.18930E-12 -12.7229 0.15656E-12 -12.8053 0.82706E+00 -0.0825 79 MnSO4,aq 0.25842E-11 -11.5877 0.25842E-11 -11.5877 0.10000E+01 0.0000 80 NaCl,aq 0.29288E-05 -5.5333 0.29288E-05 -5.5333 0.10000E+01 0.0000 81 NaF,aq 0.10616E-06 -6.9740 0.10616E-06 -6.9740 0.10000E+01 0.0000 82 NaOH,aq 0.38504E-04 -4.4145 0.38504E-04 -4.4145 0.10000E+01 0.0000 84 OH- 0.36559E-02 -2.4370 0.30108E-02 -2.5213 0.82355E+00 -0.0843 89 HPO3-2 0.24118E-16 -16.6177 0.11919E-16 -16.9237 0.49421E+00 -0.3061 92 H3PO4,aq 0.58475E-17 -17.2330 0.58475E-17 -17.2330 0.10000E+01 0.0000 93 H2PO4- 0.97285E-10 -10.0120 0.80372E-10 -10.0949 0.82615E+00 -0.0829 94 PO4-3 0.44004E-09 -9.3565 0.96527E-10 -10.0154 0.21936E+00 -0.6588 98 HP2O7-3 0.25386E-17 -17.5954 0.52702E-18 -18.2782 0.20761E+00 -0.6828 99 P2O7-4 0.10269E-16 -16.9885 0.65609E-18 -18.1830 0.63893E-01 -1.1945 100 H2S,aq 0.79060E-06 -6.1020 0.78678E-06 -6.1041 0.99516E+00 -0.0021 101 S2-2 0.46834E-09 -9.3294 0.23146E-09 -9.6355 0.49421E+00 -0.3061 102 S3-2 0.29467E-14 -14.5307 0.14563E-14 -14.8367 0.49421E+00 -0.3061 103 S3- 0.55305E-18 -18.2572 0.45641E-18 -18.3406 0.82525E+00 -0.0834 104 S4-2 0.12248E-19 -19.9120 0.60529E-20 -20.2180 0.49421E+00 -0.3061 107 SO3-2 0.78840E-11 -11.1033 0.39610E-11 -11.4022 0.50241E+00 -0.2989 108 HSO3- 0.57671E-13 -13.2390 0.47593E-13 -13.3225 0.82525E+00 -0.0834 109 HSO4- 0.40412E-10 -10.3935 0.33461E-10 -10.4755 0.82799E+00 -0.0820 111 S2O3-2 0.33835E-11 -11.4706 0.16722E-11 -11.7767 0.49421E+00 -0.3061 112 HS2O3- 0.69526E-19 -19.1579 0.57376E-19 -19.2413 0.82525E+00 -0.0834 Charge balance for all species = -.6124E-08 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.2309333E-09 -.1363496E-01 -.1371972E+02 0.0000 2 H2O 0.1000000E+01 0.5550452E+02 0.9982210E+06 0.0000 3 Cl- 0.6227053E-03 0.6256354E-03 0.2214273E+02 6.4278 4 SO4-- 0.3652079E-03 0.3655869E-03 0.3505882E+02 15.6914 5 HCO3- 0.3293538E-02 0.5802321E-02 0.3534361E+03 7.1519 6 HS- 0.1607194E-02 0.1608047E-02 0.5309041E+02 6.8397 7 Al+++ 0.1460717E-27 0.1626516E-05 0.4381080E-01 0.6320 8 H4SiO4 0.1024625E-02 0.8452602E-02 0.8110363E+03 -2.9894 9 Ca++ 0.2573473E-07 0.2313874E-06 0.9257690E-02 11.5357 10 Mg++ 0.2192542E-10 0.9305523E-10 0.2258491E-05 8.4638 11 Fe++ 0.2675694E-12 0.1018009E-07 0.5675555E-03 6.5508 12 K+ 0.1563150E-03 0.1570435E-03 0.6130217E+01 5.8284 13 Na+ 0.2084368E-01 0.2227194E-01 0.5111521E+03 7.9524 14 Mn++ 0.1010221E-09 0.2504141E-08 0.1373373E-03 9.1282 15 F- 0.3202595E-04 0.3213215E-04 0.6094030E+00 5.1380 16 HPO4-- 0.4581965E-07 0.4635698E-07 0.4441690E-02 11.7899 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.1227502E-01 -.1226173E-01 -.1329044E-04 0.0000000E+00 2 H2O 0.4990535E+02 0.4991444E+02 -.9096749E-02 0.0000000E+00 3 Cl- 0.5626252E-03 0.5626252E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.3287672E-03 0.3287672E-03 0.0000000E+00 0.0000000E+00 5 HCO3- 0.5217947E-02 0.5217947E-02 0.0000000E+00 0.0000000E+00 6 HS- 0.1446094E-02 0.1446094E-02 0.0000000E+00 0.0000000E+00 7 Al+++ 0.4775352E-05 0.1462703E-05 0.3312649E-05 0.0000000E+00 8 H4SiO4 0.1215302E-01 0.7601308E-02 0.4551712E-02 0.0000000E+00 9 Ca++ 0.2080835E-06 0.2080835E-06 0.0000000E+00 0.0000000E+00 10 Mg++ 0.8368328E-10 0.8368328E-10 0.0000000E+00 0.0000000E+00 11 Fe++ 0.3259227E-07 0.9154814E-08 0.2343746E-07 0.0000000E+00 12 K+ 0.1412294E-03 0.1412271E-03 0.2343746E-08 0.0000000E+00 13 Na+ 0.2003215E-01 0.2002885E-01 0.3303274E-05 0.0000000E+00 14 Mn++ 0.2251939E-08 0.2251939E-08 0.0000000E+00 0.0000000E+00 15 F- 0.2889600E-04 0.2889600E-04 0.0000000E+00 0.0000000E+00 16 HPO4-- 0.4168819E-07 0.4168819E-07 0.0000000E+00 0.0000000E+00 Chg. balance for solid moles: -.8470E-21 Mass of aqueous solution: 0.900826E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 0.0719900 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 0.3303E-05 -5.481 0.8662E-03 -3.062 0.3164 0.3325E-03 quartz 0.4542E-02 -2.343 0.2729 -0.564 99.68 0.1030 stilpnomelane-Fe 0.4687E-08 -8.329 0.5053E-05 -5.296 0.1846E-02 0.1745E-05 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 quartz 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 0.273740 g Volume = 0.103382 cm3 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.0719900 moles log = -1.1427 Original solution: 1000.0103000 g Original solution / Rock added: 13890.96 (Water/Rock Ratio), log = 4.1427 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0207 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9996E+00 0.9859 0.1006E+01 0.1020E+01 CO2,gas 0.1162E-03 1.0071 0.1194E-03 0.1186E-03 CH4,gas 0.2762E-04 1.0125 0.2854E-04 0.2819E-04 H2,gas 0.2166E-03 1.0005 0.2212E-03 0.2211E-03 H2S,gas 0.2127E-04 0.9960 0.2163E-04 0.2171E-04 S2,gas 0.3516E-21 1.0000 0.3589E-21 0.3589E-21 CO,gas 0.6898E-11 1.0000 0.7041E-11 0.7041E-11 SO3,gas 0.2468E-38 1.0000 0.2519E-38 0.2519E-38 SO2,gas 0.2124E-19 1.0000 0.2168E-19 0.2168E-19 HF,gas 0.8333E-13 1.0000 0.8505E-13 0.8505E-13 HCl,gas 0.3124E-16 1.0000 0.3189E-16 0.3189E-16 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 17 albite -0.38 -0.38 0.00 0.000 0.11184E-10 150 quartz -2.99 -2.99 0.00 0.000 0.00000E+00 167 stilpnomelane-Fe 13.02 13.02 0.00 0.000 0.21232E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -12.28 -5.62 -1.874 0.95991E+04 -3.923 3 CH4,gas 4.54 -1.70 -6.24 -1.561 0.10661E+05 -4.545 4 H2,gas 8.00 2.65 -5.35 -3.060 0.91422E+04 -3.655 5 H2S,gas -6.23 -12.59 -6.36 -3.182 0.10866E+05 -4.665 6 S2,gas -7.34 -30.48 -23.14 -3.561 0.39518E+05 -21.445 7 CO,gas 3.21 -9.64 -12.85 -3.954 0.21943E+05 -11.152 8 SO3,gas 17.12 -23.18 -40.30 -10.074 0.68807E+05 -38.599 9 SO2,gas 0.83 -20.53 -21.36 -5.697 0.36477E+05 -19.664 10 HF,gas 0.47 -14.30 -14.77 -7.385 0.25218E+05 -13.070 11 HCl,gas 5.19 -13.01 -18.20 -9.098 0.31068E+05 -16.496 12 acmite 7.71 7.20 -0.51 -0.053 0.86761E+03 16 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 20 spessartine 24.46 19.68 -4.78 -0.239 0.81564E+04 21 analcite 3.32 2.61 -0.72 -0.080 0.12231E+04 23 andradite 39.01 36.09 -2.91 -0.151 0.49755E+04 26 ankerite -2.14 -6.48 -4.34 -0.724 0.74144E+04 27 annite 20.12 17.14 -2.98 -0.165 0.50862E+04 28 phlogopite 27.06 22.88 -4.18 -0.232 0.71391E+04 34 apatite-F -34.30 -37.85 -3.55 -0.296 0.60613E+04 38 aragonite 0.97 -0.75 -1.71 -0.571 0.29246E+04 39 brucite 12.57 8.46 -4.10 -0.821 0.70088E+04 40 calcite 0.81 -0.75 -1.56 -0.519 0.26603E+04 41 carnegieite-low 9.02 5.60 -3.43 -0.490 0.58537E+04 42 carnegieite-high 10.09 5.60 -4.50 -0.643 0.76807E+04 43 carpholite-Mg 8.58 3.75 -4.83 -0.322 0.82523E+04 44 carpholite-Fe 6.71 1.84 -4.88 -0.325 0.83266E+04 45 celadonite 5.34 2.97 -2.38 -0.140 0.40555E+04 46 celadonite-Fe 3.88 1.05 -2.82 -0.166 0.48202E+04 47 chrysotile 23.89 19.41 -4.48 -0.373 0.76492E+04 49 clinochlore 39.07 34.61 -4.45 -0.139 0.76063E+04 50 daphnite 28.97 25.05 -3.92 -0.122 0.66852E+04 54 chloritoid-Fe 9.17 4.83 -4.35 -0.290 0.74243E+04 55 chloritoid-Mn 11.40 7.40 -4.00 -0.267 0.68268E+04 57 coesite -2.38 -2.99 -0.61 -0.204 0.10473E+04 64 cristobalite -2.56 -2.99 -0.43 -0.143 0.73267E+03 66 cymrite-K 1.69 -2.51 -4.19 -0.349 0.71599E+04 68 diaspore 2.87 0.63 -2.24 -0.374 0.38276E+04 69 diamond -3.10 -6.99 -3.89 -1.111 0.66395E+04 70 diopside 16.18 14.02 -2.16 -0.216 0.36895E+04 71 hedenbergite 14.21 12.11 -2.10 -0.210 0.35868E+04 78 epidote 24.67 20.60 -4.07 -0.198 0.69575E+04 80 epidote-Fe 29.84 25.19 -4.65 -0.242 0.79391E+04 81 fayalite 14.05 10.11 -3.93 -0.562 0.67163E+04 82 ferrosilite 11.15 7.12 -4.03 -0.403 0.68754E+04 86 gibbsite 4.08 0.63 -3.45 -0.492 0.58861E+04 87 glaucophane 22.97 18.64 -4.33 -0.117 0.73934E+04 88 glaucophane-Fe 17.28 12.91 -4.37 -0.118 0.74615E+04 89 graphite -3.55 -6.99 -3.44 -0.984 0.58817E+04 90 greenalite 16.14 13.67 -2.47 -0.205 0.42104E+04 93 hematite 12.57 10.46 -2.11 -0.256 0.36028E+04 94 heulandite -5.83 -8.13 -2.30 -0.105 0.39256E+04 98 jadeite 4.22 2.61 -1.61 -0.161 0.27485E+04 100 kalsilite 7.58 3.47 -4.11 -0.588 0.70227E+04 101 kaolinite -1.33 -4.71 -3.38 -0.307 0.57747E+04 104 laumontite 2.88 0.84 -2.04 -0.136 0.34856E+04 105 lawsonite 9.62 6.82 -2.80 -0.186 0.47727E+04 106 leucite 4.12 0.48 -3.64 -0.364 0.62106E+04 108 lizardite 23.24 19.41 -3.83 -0.319 0.65419E+04 109 magnesite 0.69 -3.82 -4.51 -1.503 0.76986E+04 110 magnetite 20.09 17.01 -3.08 -0.251 0.52597E+04 111 minnesotaite 10.39 7.69 -2.69 -0.158 0.45988E+04 115 manganosite 14.06 9.13 -4.93 -1.232 0.84176E+04 119 microcline -2.49 -2.51 -0.02 -0.002 0.36553E+02 123 muscovite 2.58 -1.24 -3.83 -0.225 0.65332E+04 124 paragonite 4.24 0.88 -3.36 -0.198 0.57358E+04 125 nepheline 8.34 5.60 -2.74 -0.392 0.46861E+04 137 phlogopite-Na 29.65 25.01 -4.64 -0.258 0.79214E+04 139 prehnite 19.37 15.37 -4.00 -0.236 0.68380E+04 140 prehnite-Fe 22.50 19.96 -2.53 -0.152 0.43280E+04 145 pyrite -21.25 -21.28 -0.04 -0.009 0.61735E+02 146 pyrrhotite -4.26 -6.04 -1.78 -0.594 0.30445E+04 147 pyrrhotiteFe0.875 -6.02 -7.19 -1.17 -0.432 0.20034E+04 148 pyroxmangite 7.40 6.14 -1.26 -0.252 0.21512E+04 149 pyrophyllite -6.18 -10.69 -4.52 -0.282 0.77141E+04 154 rhodochrosite -0.98 -3.15 -2.18 -0.726 0.37178E+04 155 rhodonite 7.45 6.14 -1.31 -0.261 0.22315E+04 156 sanidine -1.28 -2.51 -1.23 -0.095 0.21043E+04 158 siderite -2.61 -5.73 -3.12 -1.041 0.53324E+04 166 stilbite -7.52 -8.13 -0.60 -0.029 0.10317E+04 168 stilpnomelane-Mg 27.44 22.58 -4.86 -0.145 0.82976E+04 174 talc 16.49 13.43 -3.06 -0.180 0.52204E+04 177 tephroite 18.09 15.27 -2.82 -0.403 0.48130E+04 181 tridymite -2.63 -2.99 -0.36 -0.121 0.61998E+03 184 troilite-low -4.41 -6.04 -1.63 -0.544 0.27873E+04 190 wairakite 3.95 0.84 -3.11 -0.183 0.53076E+04 191 walstromite 11.51 8.55 -2.96 -0.593 0.50592E+04 192 wollastonite 10.46 8.55 -1.91 -0.383 0.32697E+04 193 pseudo-wollastonite 11.00 8.55 -2.45 -0.491 0.41895E+04 195 akaganeite 7.75 5.23 -2.53 -0.546 0.43140E+04 202 chalcedony -2.80 -2.99 -0.19 -0.062 0.31930E+03 204 montmorillonite-Ca -2.29 -6.21 -3.92 -0.242 0.66849E+04 205 montmorillonite-K -2.24 -6.19 -3.95 -0.242 0.67430E+04 206 montmorillonite-Mg -2.48 -6.71 -4.23 -0.262 0.72273E+04 207 montmorillonite-Na -2.04 -5.48 -3.45 -0.211 0.58858E+04 208 nontronite-Ca 3.21 1.60 -1.62 -0.105 0.27621E+04 209 nontronite-H 2.53 -0.31 -2.84 -0.190 0.48479E+04 210 nontronite-K 3.34 1.62 -1.72 -0.111 0.29434E+04 211 nontronite-Mg 3.07 1.09 -1.98 -0.129 0.33887E+04 212 nontronite-Na 3.52 2.32 -1.20 -0.077 0.20523E+04 228 tobermorite 9.82 6.62 -3.20 -0.874 0.54695E+04 234 alabandite -0.98 -3.47 -2.49 -0.829 0.42484E+04 237 boehmite 4.41 0.63 -3.77 -0.629 0.64445E+04 239 ferrous-oxide 9.81 6.55 -3.26 -0.815 0.55676E+04 245 silica-amorphous -2.09 -2.99 -0.90 -0.299 0.15335E+04 247 an20ab80 2.02 1.06 -0.96 -0.074 0.16404E+04 248 an25ab75 2.65 1.42 -1.23 -0.094 0.20974E+04 249 an30ab70 3.28 1.78 -1.50 -0.116 0.25641E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 0.0020000 MOLES Current total amount of reactant added: 0.0719900 MOLES New total amount of reactant added: 0.0739900 MOLES Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.5508E-08 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 8 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 0.0739900 Water: Moles liquid = 0.4992E+02 kg liquid = 0.8993E+00 Moles total = 0.4991E+02 kg total = 0.8991E+00 Activity = 1.0000 Stoichiometric ionic strength = .1611843E-01 Osmotic coef. = 0.9268 True ionic strength = .2394959E-01 Chg. balance for total moles = -.5508E-08 Max. difference allowed = 0.5744E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.23689E-09 -9.6255 0.19681E-09 -9.7060 0.83081E+00 -0.0805 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.63574E-03 -3.1967 0.52453E-03 -3.2802 0.82507E+00 -0.0835 4 SO4-- 0.37580E-03 -3.4250 0.18601E-03 -3.7305 0.49498E+00 -0.3054 5 HCO3- 0.34206E-02 -2.4659 0.28269E-02 -2.5487 0.82646E+00 -0.0828 6 HS- 0.16505E-02 -2.7824 0.13620E-02 -2.8658 0.82521E+00 -0.0834 7 Al+++ 0.16171E-27 -27.7913 0.33462E-28 -28.4754 0.20693E+00 -0.6842 8 H4SiO4 0.10246E-02 -2.9894 0.10246E-02 -2.9894 0.10000E+01 0.0000 9 Ca++ 0.25498E-07 -7.5935 0.12514E-07 -7.9026 0.49079E+00 -0.3091 10 Mg++ 0.21975E-10 -10.6581 0.10728E-10 -10.9695 0.48821E+00 -0.3114 11 Fe++ 0.27972E-12 -12.5533 0.13673E-12 -12.8641 0.48883E+00 -0.3108 12 K+ 0.15630E-03 -3.8060 0.12921E-03 -3.8887 0.82668E+00 -0.0827 13 Na+ 0.20876E-01 -1.6803 0.17221E-01 -1.7639 0.82489E+00 -0.0836 14 Mn++ 0.10516E-09 -9.9781 0.51456E-10 -10.2886 0.48929E+00 -0.3104 15 F- 0.32911E-04 -4.4827 0.27090E-04 -4.5672 0.82312E+00 -0.0845 16 HPO4-- 0.45826E-07 -7.3389 0.22687E-07 -7.6442 0.49506E+00 -0.3053 18 HSiO3- 0.58919E-02 -2.2297 0.48613E-02 -2.3133 0.82507E+00 -0.0835 19 Ca(HSiO3)+ 0.16755E-08 -8.7758 0.13855E-08 -8.8584 0.82688E+00 -0.0826 20 Mg(HSiO3)+ 0.17876E-11 -11.7477 0.14781E-11 -11.8303 0.82688E+00 -0.0826 21 NaHSiO3,aq 0.13540E-02 -2.8684 0.13540E-02 -2.8684 0.10000E+01 0.0000 22 AlO+ 0.14214E-15 -15.8473 0.11753E-15 -15.9299 0.82688E+00 -0.0826 24 HAlO2,aq 0.11893E-09 -9.9247 0.11893E-09 -9.9247 0.10000E+01 0.0000 25 AlO2- 0.16246E-05 -5.7893 0.13376E-05 -5.8737 0.82336E+00 -0.0844 26 CH4,aq 0.20205E-07 -7.6945 0.20107E-07 -7.6967 0.99512E+00 -0.0021 27 C2H6,aq 0.41501E-18 -18.3819 0.41299E-18 -18.3841 0.99512E+00 -0.0021 31 CO,aq 0.49978E-14 -14.3012 0.49978E-14 -14.3012 0.10000E+01 0.0000 32 CO2,aq 0.11947E-05 -5.9228 0.11888E-05 -5.9249 0.99512E+00 -0.0021 33 CO3-2 0.25409E-02 -2.5950 0.12546E-02 -2.9015 0.49377E+00 -0.3065 34 CaCO3,aq 0.19687E-06 -6.7058 0.19687E-06 -6.7058 0.10000E+01 0.0000 35 Ca(HCO3)+ 0.10921E-08 -8.9617 0.90305E-09 -9.0443 0.82688E+00 -0.0826 36 CaCl+ 0.12847E-10 -10.8912 0.10623E-10 -10.9738 0.82688E+00 -0.0826 37 CaCl2,aq 0.13238E-14 -14.8782 0.13238E-14 -14.8782 0.10000E+01 0.0000 38 CaF+ 0.59859E-11 -11.2229 0.49497E-11 -11.3054 0.82688E+00 -0.0826 39 CaOH+ 0.54806E-08 -8.2612 0.45318E-08 -8.3437 0.82688E+00 -0.0826 40 CaSO4,aq 0.73921E-09 -9.1312 0.73921E-09 -9.1312 0.10000E+01 0.0000 41 HCl,aq 0.18917E-13 -13.7232 0.18917E-13 -13.7232 0.10000E+01 0.0000 45 HF,aq 0.36498E-10 -10.4377 0.36498E-10 -10.4377 0.10000E+01 0.0000 46 HF2- 0.40460E-15 -15.3930 0.33382E-15 -15.4765 0.82507E+00 -0.0835 48 FeCl+ 0.13729E-15 -15.8624 0.11352E-15 -15.9449 0.82688E+00 -0.0826 51 FeF+ 0.22892E-15 -15.6403 0.18929E-15 -15.7229 0.82688E+00 -0.0826 53 FeO,aq 0.13720E-09 -9.8626 0.13720E-09 -9.8626 0.10000E+01 0.0000 54 FeOH+ 0.27350E-10 -10.5630 0.22615E-10 -10.6456 0.82688E+00 -0.0826 55 HFeO2- 0.88407E-08 -8.0535 0.72941E-08 -8.1370 0.82507E+00 -0.0835 56 FeO+ 0.15947E-15 -15.7973 0.13186E-15 -15.8799 0.82688E+00 -0.0826 58 FeO2- 0.84427E-09 -9.0735 0.69658E-09 -9.1570 0.82507E+00 -0.0835 59 HFeO2,aq 0.17436E-10 -10.7585 0.17436E-10 -10.7585 0.10000E+01 0.0000 60 H2,aq 0.16817E-06 -6.7742 0.16735E-06 -6.7764 0.99512E+00 -0.0021 61 KCl,aq 0.12284E-08 -8.9107 0.12284E-08 -8.9107 0.10000E+01 0.0000 62 KHSO4,aq 0.13375E-16 -16.8737 0.13375E-16 -16.8737 0.10000E+01 0.0000 63 KOH,aq 0.28038E-06 -6.5523 0.28038E-06 -6.5523 0.10000E+01 0.0000 64 KSO4- 0.45205E-06 -6.3448 0.37297E-06 -6.4283 0.82507E+00 -0.0835 65 MgCO3,aq 0.42305E-10 -10.3736 0.42305E-10 -10.3736 0.10000E+01 0.0000 66 Mg(HCO3)+ 0.95667E-12 -12.0192 0.79106E-12 -12.1018 0.82688E+00 -0.0826 67 MgCl+ 0.99819E-14 -14.0008 0.82539E-14 -14.0833 0.82688E+00 -0.0826 68 MgF+ 0.19009E-13 -13.7210 0.15718E-13 -13.8036 0.82688E+00 -0.0826 69 MgOH+ 0.25999E-10 -10.5850 0.21498E-10 -10.6676 0.82688E+00 -0.0826 71 MnF+ 0.28395E-13 -13.5468 0.23479E-13 -13.6293 0.82688E+00 -0.0826 72 MnO,aq 0.13758E-08 -8.8615 0.13758E-08 -8.8615 0.10000E+01 0.0000 73 MnOH+ 0.95613E-09 -9.0195 0.79061E-09 -9.1020 0.82688E+00 -0.0826 74 MnO2-2 0.23873E-11 -11.6221 0.11788E-11 -11.9286 0.49377E+00 -0.3065 75 HMnO2- 0.61602E-10 -10.2104 0.50826E-10 -10.2939 0.82507E+00 -0.0835 78 MnCl+ 0.20100E-12 -12.6968 0.16620E-12 -12.7794 0.82688E+00 -0.0826 79 MnSO4,aq 0.27633E-11 -11.5586 0.27633E-11 -11.5586 0.10000E+01 0.0000 80 NaCl,aq 0.29935E-05 -5.5238 0.29935E-05 -5.5238 0.10000E+01 0.0000 81 NaF,aq 0.10922E-06 -6.9617 0.10922E-06 -6.9617 0.10000E+01 0.0000 82 NaOH,aq 0.37594E-04 -4.4249 0.37594E-04 -4.4249 0.10000E+01 0.0000 84 OH- 0.35655E-02 -2.4479 0.29357E-02 -2.5323 0.82336E+00 -0.0844 89 HPO3-2 0.23962E-16 -16.6205 0.11832E-16 -16.9270 0.49377E+00 -0.3065 92 H3PO4,aq 0.61458E-17 -17.2114 0.61458E-17 -17.2114 0.10000E+01 0.0000 93 H2PO4- 0.99720E-10 -10.0012 0.82366E-10 -10.0843 0.82597E+00 -0.0830 94 PO4-3 0.42956E-09 -9.3670 0.94050E-10 -10.0266 0.21894E+00 -0.6597 98 HP2O7-3 0.26049E-17 -17.5842 0.53969E-18 -18.2679 0.20719E+00 -0.6836 99 P2O7-4 0.10289E-16 -16.9876 0.65511E-18 -18.1837 0.63668E-01 -1.1961 100 H2S,aq 0.83252E-06 -6.0796 0.82846E-06 -6.0817 0.99512E+00 -0.0021 101 S2-2 0.49744E-09 -9.3033 0.24562E-09 -9.6097 0.49377E+00 -0.3065 102 S3-2 0.33176E-14 -14.4792 0.16382E-14 -14.7856 0.49377E+00 -0.3065 103 S3- 0.64029E-18 -18.1936 0.52828E-18 -18.2771 0.82507E+00 -0.0835 104 S4-2 0.14616E-19 -19.8352 0.72172E-20 -20.1416 0.49377E+00 -0.3065 107 SO3-2 0.80586E-11 -11.0937 0.40453E-11 -11.3930 0.50198E+00 -0.2993 108 HSO3- 0.60418E-13 -13.2188 0.49849E-13 -13.3023 0.82507E+00 -0.0835 109 HSO4- 0.42619E-10 -10.3704 0.35281E-10 -10.4525 0.82781E+00 -0.0821 111 S2O3-2 0.36661E-11 -11.4358 0.18102E-11 -11.7423 0.49377E+00 -0.3065 112 HS2O3- 0.77208E-19 -19.1123 0.63702E-19 -19.1958 0.82507E+00 -0.0835 Charge balance for all species = -.6124E-08 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.2368880E-09 -.1339498E-01 -.1347829E+02 0.0000 2 H2O 0.1000000E+01 0.5550461E+02 0.9982255E+06 0.0000 3 Cl- 0.6357381E-03 0.6387328E-03 0.2260634E+02 6.4257 4 SO4-- 0.3758014E-03 0.3761922E-03 0.3607595E+02 15.6815 5 HCO3- 0.3420562E-02 0.5962891E-02 0.3632179E+03 7.1573 6 HS- 0.1650512E-02 0.1651408E-02 0.5452215E+02 6.8401 7 Al+++ 0.1617071E-27 0.1624706E-05 0.4376218E-01 0.6424 8 H4SiO4 0.1024625E-02 0.8270530E-02 0.7935686E+03 -2.9894 9 Ca++ 0.2549842E-07 0.2313787E-06 0.9257368E-02 11.5093 10 Mg++ 0.2197486E-10 0.9305172E-10 0.2258412E-05 8.4424 11 Fe++ 0.2797196E-12 0.9867191E-08 0.5501125E-03 6.5478 12 K+ 0.1563039E-03 0.1570376E-03 0.6130002E+01 5.8173 13 Na+ 0.2087644E-01 0.2227110E-01 0.5111342E+03 7.9420 14 Mn++ 0.1051648E-09 0.2504046E-08 0.1373325E-03 9.1234 15 F- 0.3291124E-04 0.3302050E-04 0.6262528E+00 5.1388 16 HPO4-- 0.4582595E-07 0.4635523E-07 0.4441535E-02 11.7677 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.1205967E-01 -.1204637E-01 -.1329721E-04 0.0000000E+00 2 H2O 0.4990698E+02 0.4991641E+02 -.9423654E-02 0.0000000E+00 3 Cl- 0.5744252E-03 0.5744252E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.3383172E-03 0.3383172E-03 0.0000000E+00 0.0000000E+00 5 HCO3- 0.5362547E-02 0.5362547E-02 0.0000000E+00 0.0000000E+00 6 HS- 0.1485144E-02 0.1485144E-02 0.0000000E+00 0.0000000E+00 7 Al+++ 0.4775352E-05 0.1461130E-05 0.3314222E-05 0.0000000E+00 8 H4SiO4 0.1215302E-01 0.7437854E-02 0.4715166E-02 0.0000000E+00 9 Ca++ 0.2080835E-06 0.2080835E-06 0.0000000E+00 0.0000000E+00 10 Mg++ 0.8368328E-10 0.8368328E-10 0.0000000E+00 0.0000000E+00 11 Fe++ 0.3259227E-07 0.8873763E-08 0.2371851E-07 0.0000000E+00 12 K+ 0.1412294E-03 0.1412270E-03 0.2371851E-08 0.0000000E+00 13 Na+ 0.2003215E-01 0.2002885E-01 0.3304734E-05 0.0000000E+00 14 Mn++ 0.2251939E-08 0.2251939E-08 0.0000000E+00 0.0000000E+00 15 F- 0.2969600E-04 0.2969600E-04 0.0000000E+00 0.0000000E+00 16 HPO4-- 0.4168819E-07 0.4168819E-07 0.0000000E+00 0.0000000E+00 Chg. balance for solid moles: -.1271E-20 Mass of aqueous solution: 0.900858E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 0.0739900 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 0.3305E-05 -5.481 0.8666E-03 -3.062 0.3056 0.3327E-03 quartz 0.4705E-02 -2.327 0.2827 -0.549 99.69 0.1068 stilpnomelane-Fe 0.4744E-08 -8.324 0.5114E-05 -5.291 0.1803E-02 0.1766E-05 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 quartz 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 0.283561 g Volume = 0.107090 cm3 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.0739900 moles log = -1.1308 Original solution: 1000.0103000 g Original solution / Rock added: 13515.48 (Water/Rock Ratio), log = 4.1308 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0207 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9996E+00 0.9859 0.1006E+01 0.1020E+01 CO2,gas 0.1237E-03 1.0071 0.1272E-03 0.1263E-03 CH4,gas 0.2864E-04 1.0125 0.2960E-04 0.2923E-04 H2,gas 0.2151E-03 1.0005 0.2197E-03 0.2196E-03 H2S,gas 0.2240E-04 0.9960 0.2277E-04 0.2286E-04 S2,gas 0.3951E-21 1.0000 0.4033E-21 0.4033E-21 CO,gas 0.7297E-11 1.0000 0.7448E-11 0.7448E-11 SO3,gas 0.2669E-38 1.0000 0.2724E-38 0.2724E-38 SO2,gas 0.2281E-19 1.0000 0.2329E-19 0.2329E-19 HF,gas 0.8780E-13 1.0000 0.8962E-13 0.8962E-13 HCl,gas 0.3270E-16 1.0000 0.3338E-16 0.3338E-16 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 17 albite -0.38 -0.38 0.00 0.000 -0.94784E-12 150 quartz -2.99 -2.99 0.00 0.000 0.00000E+00 167 stilpnomelane-Fe 13.02 13.02 0.00 0.000 0.21232E-10 145 pyrite -21.25 -21.24 0.01 0.002 -0.14558E+02 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -12.25 -5.59 -1.865 0.95525E+04 -3.896 3 CH4,gas 4.54 -1.68 -6.23 -1.557 0.10634E+05 -4.529 4 H2,gas 8.00 2.64 -5.36 -3.061 0.91471E+04 -3.658 5 H2S,gas -6.23 -12.57 -6.34 -3.171 0.10828E+05 -4.643 6 S2,gas -7.34 -30.43 -23.09 -3.553 0.39431E+05 -21.394 7 CO,gas 3.21 -9.61 -12.83 -3.947 0.21902E+05 -11.128 8 SO3,gas 17.12 -23.14 -40.26 -10.066 0.68749E+05 -38.565 9 SO2,gas 0.83 -20.50 -21.33 -5.688 0.36424E+05 -19.633 10 HF,gas 0.47 -14.27 -14.75 -7.373 0.25179E+05 -13.048 11 HCl,gas 5.19 -12.99 -18.18 -9.088 0.31034E+05 -16.477 12 acmite 7.71 7.19 -0.52 -0.054 0.88807E+03 16 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 20 spessartine 24.46 19.69 -4.77 -0.239 0.81459E+04 21 analcite 3.32 2.61 -0.72 -0.080 0.12231E+04 23 andradite 39.01 36.01 -3.00 -0.156 0.51158E+04 26 ankerite -2.14 -6.45 -4.32 -0.720 0.73713E+04 27 annite 20.12 17.13 -2.99 -0.166 0.51030E+04 28 phlogopite 27.06 22.82 -4.25 -0.236 0.72497E+04 34 apatite-F -34.30 -37.89 -3.59 -0.299 0.61366E+04 38 aragonite 0.97 -0.75 -1.71 -0.571 0.29229E+04 39 brucite 12.57 8.44 -4.13 -0.825 0.70452E+04 40 calcite 0.81 -0.75 -1.56 -0.519 0.26587E+04 41 carnegieite-low 9.02 5.60 -3.43 -0.490 0.58537E+04 42 carnegieite-high 10.09 5.60 -4.50 -0.643 0.76807E+04 43 carpholite-Mg 8.58 3.75 -4.83 -0.322 0.82533E+04 44 carpholite-Fe 6.71 1.85 -4.86 -0.324 0.82964E+04 45 celadonite 5.34 2.94 -2.40 -0.141 0.40932E+04 46 celadonite-Fe 3.88 1.05 -2.83 -0.166 0.48266E+04 47 chrysotile 23.89 19.35 -4.54 -0.379 0.77586E+04 49 clinochlore 39.07 34.53 -4.54 -0.142 0.77532E+04 50 daphnite 28.97 25.06 -3.91 -0.122 0.66758E+04 54 chloritoid-Fe 9.17 4.84 -4.33 -0.289 0.73941E+04 55 chloritoid-Mn 11.40 7.42 -3.98 -0.265 0.67997E+04 57 coesite -2.38 -2.99 -0.61 -0.204 0.10473E+04 64 cristobalite -2.56 -2.99 -0.43 -0.143 0.73267E+03 66 cymrite-K 1.69 -2.51 -4.19 -0.350 0.71611E+04 68 diaspore 2.87 0.64 -2.23 -0.372 0.38098E+04 69 diamond -3.10 -6.97 -3.87 -1.105 0.66027E+04 70 diopside 16.18 13.97 -2.21 -0.221 0.37709E+04 71 hedenbergite 14.21 12.08 -2.13 -0.213 0.36370E+04 78 epidote 24.67 20.56 -4.11 -0.199 0.70147E+04 80 epidote-Fe 29.84 25.15 -4.70 -0.244 0.80167E+04 81 fayalite 14.05 10.11 -3.94 -0.563 0.67267E+04 82 ferrosilite 11.15 7.12 -4.03 -0.403 0.68858E+04 86 gibbsite 4.08 0.64 -3.44 -0.491 0.58684E+04 87 glaucophane 22.97 18.58 -4.39 -0.119 0.75027E+04 88 glaucophane-Fe 17.28 12.90 -4.38 -0.118 0.74771E+04 89 graphite -3.55 -6.97 -3.42 -0.978 0.58450E+04 90 greenalite 16.14 13.66 -2.47 -0.206 0.42260E+04 93 hematite 12.57 10.45 -2.11 -0.256 0.36083E+04 94 heulandite -5.83 -8.13 -2.30 -0.105 0.39351E+04 98 jadeite 4.22 2.61 -1.61 -0.161 0.27485E+04 100 kalsilite 7.58 3.47 -4.11 -0.588 0.70239E+04 101 kaolinite -1.33 -4.69 -3.36 -0.306 0.57392E+04 104 laumontite 2.88 0.84 -2.05 -0.136 0.34951E+04 105 lawsonite 9.62 6.82 -2.80 -0.187 0.47822E+04 106 leucite 4.12 0.48 -3.64 -0.364 0.62119E+04 108 lizardite 23.24 19.35 -3.90 -0.325 0.66512E+04 109 magnesite 0.69 -3.81 -4.50 -1.501 0.76884E+04 110 magnetite 20.09 17.00 -3.09 -0.252 0.52704E+04 111 minnesotaite 10.39 7.69 -2.70 -0.159 0.46144E+04 115 manganosite 14.06 9.12 -4.93 -1.234 0.84260E+04 119 microcline -2.49 -2.51 -0.02 -0.002 0.37766E+02 123 muscovite 2.58 -1.22 -3.81 -0.224 0.64990E+04 124 paragonite 4.24 0.90 -3.34 -0.196 0.57003E+04 125 nepheline 8.34 5.60 -2.74 -0.392 0.46861E+04 137 phlogopite-Na 29.65 24.94 -4.70 -0.261 0.80307E+04 139 prehnite 19.37 15.34 -4.04 -0.237 0.68925E+04 140 prehnite-Fe 22.50 19.92 -2.58 -0.155 0.44029E+04 146 pyrrhotite -4.26 -6.02 -1.76 -0.588 0.30114E+04 147 pyrrhotiteFe0.875 -6.02 -7.17 -1.15 -0.424 0.19691E+04 148 pyroxmangite 7.40 6.13 -1.26 -0.253 0.21595E+04 149 pyrophyllite -6.18 -10.67 -4.50 -0.281 0.76786E+04 154 rhodochrosite -0.98 -3.13 -2.15 -0.718 0.36795E+04 155 rhodonite 7.45 6.13 -1.31 -0.262 0.22398E+04 156 sanidine -1.28 -2.51 -1.23 -0.095 0.21055E+04 158 siderite -2.61 -5.71 -3.10 -1.033 0.52909E+04 166 stilbite -7.52 -8.13 -0.61 -0.029 0.10412E+04 168 stilpnomelane-Mg 27.44 22.49 -4.95 -0.148 0.84540E+04 174 talc 16.49 13.37 -3.12 -0.184 0.53298E+04 177 tephroite 18.09 15.26 -2.83 -0.404 0.48296E+04 181 tridymite -2.63 -2.99 -0.36 -0.121 0.61998E+03 184 troilite-low -4.41 -6.02 -1.61 -0.538 0.27542E+04 190 wairakite 3.95 0.84 -3.11 -0.183 0.53171E+04 191 walstromite 11.51 8.52 -2.99 -0.598 0.51042E+04 192 wollastonite 10.46 8.52 -1.94 -0.388 0.33146E+04 193 pseudo-wollastonite 11.00 8.52 -2.48 -0.496 0.42345E+04 195 akaganeite 7.75 5.23 -2.53 -0.547 0.43167E+04 202 chalcedony -2.80 -2.99 -0.19 -0.062 0.31930E+03 204 montmorillonite-Ca -2.29 -6.20 -3.91 -0.242 0.66747E+04 205 montmorillonite-K -2.24 -6.18 -3.94 -0.241 0.67316E+04 206 montmorillonite-Mg -2.48 -6.71 -4.23 -0.261 0.72158E+04 207 montmorillonite-Na -2.04 -5.48 -3.44 -0.211 0.58741E+04 208 nontronite-Ca 3.21 1.59 -1.62 -0.105 0.27692E+04 209 nontronite-H 2.53 -0.31 -2.84 -0.190 0.48475E+04 210 nontronite-K 3.34 1.61 -1.73 -0.111 0.29493E+04 211 nontronite-Mg 3.07 1.09 -1.99 -0.129 0.33943E+04 212 nontronite-Na 3.52 2.31 -1.21 -0.077 0.20577E+04 228 tobermorite 9.82 6.60 -3.23 -0.880 0.55070E+04 234 alabandite -0.98 -3.45 -2.47 -0.824 0.42184E+04 237 boehmite 4.41 0.64 -3.76 -0.627 0.64267E+04 239 ferrous-oxide 9.81 6.55 -3.26 -0.816 0.55728E+04 245 silica-amorphous -2.09 -2.99 -0.90 -0.299 0.15335E+04 247 an20ab80 2.02 1.06 -0.96 -0.074 0.16423E+04 248 an25ab75 2.65 1.42 -1.23 -0.095 0.20998E+04 249 an30ab70 3.28 1.78 -1.50 -0.116 0.25669E+04 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 7 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 0.0739900 Water: Moles liquid = 0.4992E+02 kg liquid = 0.8993E+00 Moles total = 0.4991E+02 kg total = 0.8991E+00 Activity = 1.0000 Stoichiometric ionic strength = .1610604E-01 Osmotic coef. = 0.9269 True ionic strength = .2394546E-01 Chg. balance for total moles = -.5508E-08 Max. difference allowed = 0.5744E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.23657E-09 -9.6260 0.19655E-09 -9.7065 0.83082E+00 -0.0805 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.63574E-03 -3.1967 0.52453E-03 -3.2802 0.82508E+00 -0.0835 4 SO4-- 0.37377E-03 -3.4274 0.18502E-03 -3.7328 0.49500E+00 -0.3054 5 HCO3- 0.34187E-02 -2.4661 0.28254E-02 -2.5489 0.82647E+00 -0.0828 6 HS- 0.16363E-02 -2.7861 0.13503E-02 -2.8696 0.82522E+00 -0.0834 7 Al+++ 0.16087E-27 -27.7935 0.33293E-28 -28.4776 0.20695E+00 -0.6841 8 H4SiO4 0.10246E-02 -2.9894 0.10246E-02 -2.9894 0.10000E+01 0.0000 9 Ca++ 0.25480E-07 -7.5938 0.12506E-07 -7.9029 0.49082E+00 -0.3091 10 Mg++ 0.21958E-10 -10.6584 0.10721E-10 -10.9698 0.48824E+00 -0.3114 11 Fe++ 0.27891E-12 -12.5545 0.13634E-12 -12.8654 0.48885E+00 -0.3108 12 K+ 0.15711E-03 -3.8038 0.12988E-03 -3.8864 0.82669E+00 -0.0827 13 Na+ 0.20872E-01 -1.6804 0.17217E-01 -1.7640 0.82490E+00 -0.0836 14 Mn++ 0.10494E-09 -9.9790 0.51351E-10 -10.2895 0.48932E+00 -0.3104 15 F- 0.32911E-04 -4.4827 0.27090E-04 -4.5672 0.82313E+00 -0.0845 16 HPO4-- 0.45826E-07 -7.3389 0.22688E-07 -7.6442 0.49508E+00 -0.3053 18 HSiO3- 0.58997E-02 -2.2292 0.48677E-02 -2.3127 0.82508E+00 -0.0835 19 Ca(HSiO3)+ 0.16766E-08 -8.7756 0.13863E-08 -8.8581 0.82689E+00 -0.0826 20 Mg(HSiO3)+ 0.17887E-11 -11.7475 0.14790E-11 -11.8300 0.82689E+00 -0.0826 21 NaHSiO3,aq 0.13555E-02 -2.8679 0.13555E-02 -2.8679 0.10000E+01 0.0000 22 AlO+ 0.14179E-15 -15.8484 0.11724E-15 -15.9309 0.82689E+00 -0.0826 24 HAlO2,aq 0.11880E-09 -9.9252 0.11880E-09 -9.9252 0.10000E+01 0.0000 25 AlO2- 0.16249E-05 -5.7892 0.13379E-05 -5.8736 0.82337E+00 -0.0844 26 CH4,aq 0.20129E-07 -7.6962 0.20031E-07 -7.6983 0.99512E+00 -0.0021 27 C2H6,aq 0.41207E-18 -18.3850 0.41006E-18 -18.3872 0.99512E+00 -0.0021 31 CO,aq 0.49861E-14 -14.3022 0.49861E-14 -14.3022 0.10000E+01 0.0000 32 CO2,aq 0.11924E-05 -5.9236 0.11866E-05 -5.9257 0.99512E+00 -0.0021 33 CO3-2 0.25428E-02 -2.5947 0.12556E-02 -2.9011 0.49380E+00 -0.3065 34 CaCO3,aq 0.19689E-06 -6.7058 0.19689E-06 -6.7058 0.10000E+01 0.0000 35 Ca(HCO3)+ 0.10908E-08 -8.9623 0.90195E-09 -9.0448 0.82689E+00 -0.0826 36 CaCl+ 0.12838E-10 -10.8915 0.10616E-10 -10.9740 0.82689E+00 -0.0826 37 CaCl2,aq 0.13229E-14 -14.8785 0.13229E-14 -14.8785 0.10000E+01 0.0000 38 CaF+ 0.59818E-11 -11.2232 0.49463E-11 -11.3057 0.82689E+00 -0.0826 39 CaOH+ 0.54840E-08 -8.2609 0.45347E-08 -8.3435 0.82689E+00 -0.0826 40 CaSO4,aq 0.73474E-09 -9.1339 0.73474E-09 -9.1339 0.10000E+01 0.0000 41 HCl,aq 0.18892E-13 -13.7237 0.18892E-13 -13.7237 0.10000E+01 0.0000 45 HF,aq 0.36450E-10 -10.4383 0.36450E-10 -10.4383 0.10000E+01 0.0000 46 HF2- 0.40407E-15 -15.3935 0.33339E-15 -15.4771 0.82508E+00 -0.0835 48 FeCl+ 0.13690E-15 -15.8636 0.11320E-15 -15.9462 0.82689E+00 -0.0826 51 FeF+ 0.22826E-15 -15.6416 0.18875E-15 -15.7241 0.82689E+00 -0.0826 53 FeO,aq 0.13717E-09 -9.8627 0.13717E-09 -9.8627 0.10000E+01 0.0000 54 FeOH+ 0.27308E-10 -10.5637 0.22581E-10 -10.6463 0.82689E+00 -0.0826 55 HFeO2- 0.88504E-08 -8.0530 0.73023E-08 -8.1365 0.82508E+00 -0.0835 56 FeO+ 0.15926E-15 -15.7979 0.13169E-15 -15.8805 0.82689E+00 -0.0826 58 FeO2- 0.84541E-09 -9.0729 0.69753E-09 -9.1564 0.82508E+00 -0.0835 59 HFeO2,aq 0.17437E-10 -10.7585 0.17437E-10 -10.7585 0.10000E+01 0.0000 60 H2,aq 0.16809E-06 -6.7745 0.16727E-06 -6.7766 0.99512E+00 -0.0021 61 KCl,aq 0.12348E-08 -8.9084 0.12348E-08 -8.9084 0.10000E+01 0.0000 62 KHSO4,aq 0.13354E-16 -16.8744 0.13354E-16 -16.8744 0.10000E+01 0.0000 63 KOH,aq 0.28221E-06 -6.5494 0.28221E-06 -6.5494 0.10000E+01 0.0000 64 KSO4- 0.45196E-06 -6.3449 0.37290E-06 -6.4284 0.82508E+00 -0.0835 65 MgCO3,aq 0.42307E-10 -10.3736 0.42307E-10 -10.3736 0.10000E+01 0.0000 66 Mg(HCO3)+ 0.95545E-12 -12.0198 0.79005E-12 -12.1023 0.82689E+00 -0.0826 67 MgCl+ 0.99746E-14 -14.0011 0.82479E-14 -14.0837 0.82689E+00 -0.0826 68 MgF+ 0.18995E-13 -13.7214 0.15707E-13 -13.8039 0.82689E+00 -0.0826 69 MgOH+ 0.26014E-10 -10.5848 0.21511E-10 -10.6673 0.82689E+00 -0.0826 71 MnF+ 0.28337E-13 -13.5477 0.23431E-13 -13.6302 0.82689E+00 -0.0826 72 MnO,aq 0.13766E-08 -8.8612 0.13766E-08 -8.8612 0.10000E+01 0.0000 73 MnOH+ 0.95542E-09 -9.0198 0.79003E-09 -9.1024 0.82689E+00 -0.0826 74 MnO2-2 0.23949E-11 -11.6207 0.11826E-11 -11.9272 0.49380E+00 -0.3065 75 HMnO2- 0.61720E-10 -10.2096 0.50923E-10 -10.2931 0.82508E+00 -0.0835 78 MnCl+ 0.20059E-12 -12.6977 0.16587E-12 -12.7802 0.82689E+00 -0.0826 79 MnSO4,aq 0.27428E-11 -11.5618 0.27428E-11 -11.5618 0.10000E+01 0.0000 80 NaCl,aq 0.29929E-05 -5.5239 0.29929E-05 -5.5239 0.10000E+01 0.0000 81 NaF,aq 0.10920E-06 -6.9618 0.10920E-06 -6.9618 0.10000E+01 0.0000 82 NaOH,aq 0.37636E-04 -4.4244 0.37636E-04 -4.4244 0.10000E+01 0.0000 84 OH- 0.35702E-02 -2.4473 0.29396E-02 -2.5317 0.82337E+00 -0.0844 89 HPO3-2 0.23950E-16 -16.6207 0.11826E-16 -16.9271 0.49380E+00 -0.3065 92 H3PO4,aq 0.61298E-17 -17.2126 0.61298E-17 -17.2126 0.10000E+01 0.0000 93 H2PO4- 0.99591E-10 -10.0018 0.82260E-10 -10.0848 0.82598E+00 -0.0830 94 PO4-3 0.43010E-09 -9.3664 0.94178E-10 -10.0260 0.21897E+00 -0.6596 98 HP2O7-3 0.26013E-17 -17.5848 0.53902E-18 -18.2684 0.20721E+00 -0.6836 99 P2O7-4 0.10288E-16 -16.9877 0.65516E-18 -18.1837 0.63680E-01 -1.1960 100 H2S,aq 0.82427E-06 -6.0839 0.82025E-06 -6.0861 0.99512E+00 -0.0021 101 S2-2 0.48914E-09 -9.3106 0.24153E-09 -9.6170 0.49380E+00 -0.3065 102 S3-2 0.32315E-14 -14.4906 0.15957E-14 -14.7970 0.49380E+00 -0.3065 103 S3- 0.62302E-18 -18.2055 0.51404E-18 -18.2890 0.82508E+00 -0.0835 104 S4-2 0.14103E-19 -19.8507 0.69640E-20 -20.1571 0.49380E+00 -0.3065 107 SO3-2 0.80112E-11 -11.0963 0.40217E-11 -11.3956 0.50201E+00 -0.2993 108 HSO3- 0.59985E-13 -13.2220 0.49492E-13 -13.3055 0.82508E+00 -0.0835 109 HSO4- 0.42334E-10 -10.3733 0.35045E-10 -10.4554 0.82782E+00 -0.0821 111 S2O3-2 0.36102E-11 -11.4425 0.17827E-11 -11.7489 0.49380E+00 -0.3065 112 HS2O3- 0.75933E-19 -19.1196 0.62650E-19 -19.2031 0.82508E+00 -0.0835 Charge balance for all species = -.6124E-08 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.2365721E-09 -.1341081E-01 -.1349422E+02 0.0000 2 H2O 0.1000000E+01 0.5550461E+02 0.9982254E+06 0.0000 3 Cl- 0.6357386E-03 0.6387327E-03 0.2260634E+02 6.4263 4 SO4-- 0.3737709E-03 0.3741618E-03 0.3588123E+02 15.6803 5 HCO3- 0.3418686E-02 0.5962889E-02 0.3632178E+03 7.1576 6 HS- 0.1636308E-02 0.1637195E-02 0.5405290E+02 6.8370 7 Al+++ 0.1608709E-27 0.1625038E-05 0.4377114E-01 0.6419 8 H4SiO4 0.1024625E-02 0.8279757E-02 0.7944538E+03 -2.9894 9 Ca++ 0.2547972E-07 0.2313787E-06 0.9257366E-02 11.5102 10 Mg++ 0.2195769E-10 0.9305171E-10 0.2258412E-05 8.4433 11 Fe++ 0.2789086E-12 0.9878009E-08 0.5507156E-03 6.5477 12 K+ 0.1571143E-03 0.1578497E-03 0.6161703E+01 5.8201 13 Na+ 0.2087164E-01 0.2226785E-01 0.5110595E+03 7.9425 14 Mn++ 0.1049444E-09 0.2504046E-08 0.1373325E-03 9.1236 15 F- 0.3291126E-04 0.3302050E-04 0.6262526E+00 5.1393 16 HPO4-- 0.4582553E-07 0.4635522E-07 0.4441534E-02 11.7688 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.1205967E-01 -.1206061E-01 0.9464599E-06 0.0000000E+00 2 H2O 0.4990698E+02 0.4991641E+02 -.9429698E-02 0.0000000E+00 3 Cl- 0.5744252E-03 0.5744252E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.3383172E-03 0.3364912E-03 0.1825956E-05 0.0000000E+00 5 HCO3- 0.5362547E-02 0.5362547E-02 0.0000000E+00 0.0000000E+00 6 HS- 0.1485144E-02 0.1472363E-02 0.1278169E-04 0.0000000E+00 7 Al+++ 0.4775352E-05 0.1461430E-05 0.3313922E-05 0.0000000E+00 8 H4SiO4 0.1215302E-01 0.7446153E-02 0.4706867E-02 0.0000000E+00 9 Ca++ 0.2080835E-06 0.2080835E-06 0.0000000E+00 0.0000000E+00 10 Mg++ 0.8368328E-10 0.8368328E-10 0.0000000E+00 0.0000000E+00 11 Fe++ 0.3259227E-07 0.8883494E-08 0.2370878E-07 0.0000000E+00 12 K+ 0.1412294E-03 0.1419574E-03 -.7280113E-06 0.0000000E+00 13 Na+ 0.2003215E-01 0.2002592E-01 0.6225967E-05 0.0000000E+00 14 Mn++ 0.2251939E-08 0.2251939E-08 0.0000000E+00 0.0000000E+00 15 F- 0.2969600E-04 0.2969600E-04 0.0000000E+00 0.0000000E+00 16 HPO4-- 0.4168819E-07 0.4168819E-07 0.0000000E+00 0.0000000E+00 Chg. balance for solid moles: -.8470E-21 Mass of aqueous solution: 0.900858E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 0.0739900 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 0.6226E-05 -5.206 0.1633E-02 -2.787 0.5763 0.6267E-03 quartz 0.4700E-02 -2.328 0.2824 -0.549 99.67 0.1066 stilpnomelane-Fe -.1456E-05 1.000 -.1570E-02 1.000 -.5540 -.5422E-03 pyrite 0.7304E-05 -5.136 0.8763E-03 -3.057 0.3093 0.1748E-03 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 quartz 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 pyrite 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 0.283306 g Volume = 0.106893 cm3 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.0739900 moles log = -1.1308 Original solution: 1000.0103000 g Original solution / Rock added: 13515.48 (Water/Rock Ratio), log = 4.1308 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0207 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9996E+00 0.9859 0.1006E+01 0.1020E+01 CO2,gas 0.1235E-03 1.0071 0.1270E-03 0.1261E-03 CH4,gas 0.2853E-04 1.0125 0.2948E-04 0.2912E-04 H2,gas 0.2150E-03 1.0005 0.2196E-03 0.2195E-03 H2S,gas 0.2218E-04 0.9960 0.2255E-04 0.2264E-04 S2,gas 0.3877E-21 1.0000 0.3957E-21 0.3957E-21 CO,gas 0.7280E-11 1.0000 0.7430E-11 0.7430E-11 SO3,gas 0.2648E-38 1.0000 0.2702E-38 0.2702E-38 SO2,gas 0.2262E-19 1.0000 0.2309E-19 0.2309E-19 HF,gas 0.8768E-13 1.0000 0.8950E-13 0.8950E-13 HCl,gas 0.3266E-16 1.0000 0.3334E-16 0.3334E-16 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 17 albite -0.38 -0.38 0.00 0.000 -0.94784E-12 145 pyrite -21.25 -21.25 0.00 0.000 0.60662E-11 150 quartz -2.99 -2.99 0.00 0.000 0.00000E+00 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -12.26 -5.60 -1.865 0.95539E+04 -3.896 3 CH4,gas 4.54 -1.69 -6.23 -1.557 0.10637E+05 -4.530 4 H2,gas 8.00 2.64 -5.36 -3.061 0.91475E+04 -3.658 5 H2S,gas -6.23 -12.58 -6.35 -3.173 0.10835E+05 -4.647 6 S2,gas -7.34 -30.44 -23.10 -3.554 0.39445E+05 -21.403 7 CO,gas 3.21 -9.61 -12.83 -3.947 0.21903E+05 -11.129 8 SO3,gas 17.12 -23.15 -40.27 -10.067 0.68755E+05 -38.568 9 SO2,gas 0.83 -20.50 -21.34 -5.689 0.36430E+05 -19.637 10 HF,gas 0.47 -14.27 -14.75 -7.374 0.25180E+05 -13.048 11 HCl,gas 5.19 -12.99 -18.18 -9.088 0.31035E+05 -16.477 12 acmite 7.71 7.19 -0.52 -0.054 0.88722E+03 16 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 20 spessartine 24.46 19.69 -4.77 -0.239 0.81462E+04 21 analcite 3.32 2.61 -0.72 -0.080 0.12231E+04 23 andradite 39.01 36.02 -2.99 -0.156 0.51114E+04 26 ankerite -2.14 -6.45 -4.32 -0.720 0.73728E+04 27 annite 20.12 17.14 -2.99 -0.166 0.50995E+04 28 phlogopite 27.06 22.82 -4.24 -0.236 0.72414E+04 34 apatite-F -34.30 -37.89 -3.59 -0.299 0.61361E+04 38 aragonite 0.97 -0.75 -1.71 -0.571 0.29228E+04 39 brucite 12.57 8.44 -4.13 -0.825 0.70438E+04 40 calcite 0.81 -0.75 -1.56 -0.519 0.26586E+04 41 carnegieite-low 9.02 5.60 -3.43 -0.490 0.58537E+04 42 carnegieite-high 10.09 5.60 -4.50 -0.643 0.76807E+04 43 carpholite-Mg 8.58 3.75 -4.83 -0.322 0.82536E+04 44 carpholite-Fe 6.71 1.85 -4.86 -0.324 0.82982E+04 45 celadonite 5.34 2.95 -2.39 -0.141 0.40877E+04 46 celadonite-Fe 3.88 1.05 -2.82 -0.166 0.48228E+04 47 chrysotile 23.89 19.35 -4.54 -0.378 0.77544E+04 49 clinochlore 39.07 34.53 -4.54 -0.142 0.77477E+04 50 daphnite 28.97 25.05 -3.91 -0.122 0.66782E+04 54 chloritoid-Fe 9.17 4.84 -4.33 -0.289 0.73958E+04 55 chloritoid-Mn 11.40 7.42 -3.98 -0.266 0.68009E+04 57 coesite -2.38 -2.99 -0.61 -0.204 0.10473E+04 64 cristobalite -2.56 -2.99 -0.43 -0.143 0.73267E+03 66 cymrite-K 1.69 -2.51 -4.19 -0.349 0.71571E+04 68 diaspore 2.87 0.64 -2.23 -0.372 0.38106E+04 69 diamond -3.10 -6.97 -3.87 -1.105 0.66048E+04 70 diopside 16.18 13.97 -2.21 -0.221 0.37680E+04 71 hedenbergite 14.21 12.08 -2.13 -0.213 0.36357E+04 78 epidote 24.67 20.56 -4.11 -0.199 0.70134E+04 80 epidote-Fe 29.84 25.15 -4.69 -0.244 0.80146E+04 81 fayalite 14.05 10.11 -3.94 -0.563 0.67270E+04 82 ferrosilite 11.15 7.12 -4.03 -0.403 0.68861E+04 86 gibbsite 4.08 0.64 -3.44 -0.491 0.58692E+04 87 glaucophane 22.97 18.58 -4.39 -0.119 0.74985E+04 88 glaucophane-Fe 17.28 12.90 -4.38 -0.118 0.74776E+04 89 graphite -3.55 -6.97 -3.42 -0.978 0.58471E+04 90 greenalite 16.14 13.66 -2.48 -0.206 0.42265E+04 93 hematite 12.57 10.45 -2.11 -0.256 0.36083E+04 94 heulandite -5.83 -8.13 -2.30 -0.105 0.39353E+04 98 jadeite 4.22 2.61 -1.61 -0.161 0.27485E+04 100 kalsilite 7.58 3.47 -4.11 -0.587 0.70199E+04 101 kaolinite -1.33 -4.69 -3.36 -0.306 0.57409E+04 104 laumontite 2.88 0.84 -2.05 -0.136 0.34953E+04 105 lawsonite 9.62 6.82 -2.80 -0.187 0.47824E+04 106 leucite 4.12 0.48 -3.64 -0.364 0.62078E+04 108 lizardite 23.24 19.35 -3.89 -0.324 0.66470E+04 109 magnesite 0.69 -3.81 -4.50 -1.501 0.76884E+04 110 magnetite 20.09 17.00 -3.09 -0.252 0.52705E+04 111 minnesotaite 10.39 7.69 -2.70 -0.159 0.46149E+04 115 manganosite 14.06 9.12 -4.93 -1.234 0.84255E+04 119 microcline -2.49 -2.51 -0.02 -0.002 0.33762E+02 123 muscovite 2.58 -1.22 -3.80 -0.224 0.64966E+04 124 paragonite 4.24 0.90 -3.34 -0.196 0.57019E+04 125 nepheline 8.34 5.60 -2.74 -0.392 0.46861E+04 137 phlogopite-Na 29.65 24.95 -4.70 -0.261 0.80265E+04 139 prehnite 19.37 15.34 -4.04 -0.237 0.68912E+04 140 prehnite-Fe 22.50 19.92 -2.58 -0.155 0.44008E+04 146 pyrrhotite -4.26 -6.03 -1.77 -0.589 0.30189E+04 147 pyrrhotiteFe0.875 -6.02 -7.17 -1.16 -0.426 0.19765E+04 148 pyroxmangite 7.40 6.13 -1.26 -0.253 0.21591E+04 149 pyrophyllite -6.18 -10.67 -4.50 -0.281 0.76803E+04 154 rhodochrosite -0.98 -3.13 -2.16 -0.719 0.36805E+04 155 rhodonite 7.45 6.13 -1.31 -0.262 0.22394E+04 156 sanidine -1.28 -2.51 -1.23 -0.095 0.21015E+04 158 siderite -2.61 -5.71 -3.10 -1.033 0.52925E+04 166 stilbite -7.52 -8.13 -0.61 -0.029 0.10414E+04 167 stilpnomelane-Fe 13.02 13.02 0.00 0.000 -0.27298E-10 168 stilpnomelane-Mg 27.44 22.49 -4.95 -0.148 0.84461E+04 174 talc 16.49 13.37 -3.12 -0.183 0.53256E+04 177 tephroite 18.09 15.26 -2.83 -0.404 0.48287E+04 181 tridymite -2.63 -2.99 -0.36 -0.121 0.61998E+03 184 troilite-low -4.41 -6.03 -1.62 -0.539 0.27617E+04 190 wairakite 3.95 0.84 -3.11 -0.183 0.53173E+04 191 walstromite 11.51 8.52 -2.99 -0.598 0.51028E+04 192 wollastonite 10.46 8.52 -1.94 -0.388 0.33132E+04 193 pseudo-wollastonite 11.00 8.52 -2.48 -0.496 0.42330E+04 195 akaganeite 7.75 5.23 -2.53 -0.547 0.43167E+04 202 chalcedony -2.80 -2.99 -0.19 -0.062 0.31930E+03 204 montmorillonite-Ca -2.29 -6.20 -3.91 -0.242 0.66754E+04 205 montmorillonite-K -2.24 -6.18 -3.94 -0.241 0.67310E+04 206 montmorillonite-Mg -2.48 -6.71 -4.23 -0.261 0.72164E+04 207 montmorillonite-Na -2.04 -5.48 -3.44 -0.211 0.58747E+04 208 nontronite-Ca 3.21 1.59 -1.62 -0.105 0.27691E+04 209 nontronite-H 2.53 -0.31 -2.84 -0.190 0.48477E+04 210 nontronite-K 3.34 1.61 -1.73 -0.111 0.29479E+04 211 nontronite-Mg 3.07 1.09 -1.99 -0.129 0.33943E+04 212 nontronite-Na 3.52 2.31 -1.21 -0.077 0.20577E+04 228 tobermorite 9.82 6.60 -3.22 -0.880 0.55058E+04 234 alabandite -0.98 -3.45 -2.47 -0.825 0.42253E+04 237 boehmite 4.41 0.64 -3.76 -0.627 0.64276E+04 239 ferrous-oxide 9.81 6.55 -3.26 -0.816 0.55730E+04 245 silica-amorphous -2.09 -2.99 -0.90 -0.299 0.15335E+04 247 an20ab80 2.02 1.06 -0.96 -0.074 0.16423E+04 248 an25ab75 2.65 1.42 -1.23 -0.095 0.20998E+04 249 an30ab70 3.28 1.78 -1.50 -0.116 0.25670E+04 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 7 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 0.0739900 Water: Moles liquid = 0.4992E+02 kg liquid = 0.8993E+00 Moles total = 0.4991E+02 kg total = 0.8991E+00 Activity = 1.0000 Stoichiometric ionic strength = .1611839E-01 Osmotic coef. = 0.9268 True ionic strength = .2394958E-01 Chg. balance for total moles = -.5508E-08 Max. difference allowed = 0.5744E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.23689E-09 -9.6255 0.19681E-09 -9.7060 0.83081E+00 -0.0805 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.63574E-03 -3.1967 0.52453E-03 -3.2802 0.82507E+00 -0.0835 4 SO4-- 0.37579E-03 -3.4250 0.18601E-03 -3.7305 0.49498E+00 -0.3054 5 HCO3- 0.34206E-02 -2.4659 0.28269E-02 -2.5487 0.82646E+00 -0.0828 6 HS- 0.16505E-02 -2.7824 0.13620E-02 -2.8658 0.82521E+00 -0.0834 7 Al+++ 0.16170E-27 -27.7913 0.33462E-28 -28.4755 0.20693E+00 -0.6842 8 H4SiO4 0.10246E-02 -2.9894 0.10246E-02 -2.9894 0.10000E+01 0.0000 9 Ca++ 0.25498E-07 -7.5935 0.12514E-07 -7.9026 0.49079E+00 -0.3091 10 Mg++ 0.21975E-10 -10.6581 0.10728E-10 -10.9695 0.48821E+00 -0.3114 11 Fe++ 0.27430E-12 -12.5618 0.13408E-12 -12.8726 0.48883E+00 -0.3108 12 K+ 0.15631E-03 -3.8060 0.12922E-03 -3.8887 0.82668E+00 -0.0827 13 Na+ 0.20876E-01 -1.6803 0.17221E-01 -1.7639 0.82489E+00 -0.0836 14 Mn++ 0.10516E-09 -9.9781 0.51456E-10 -10.2886 0.48929E+00 -0.3104 15 F- 0.32911E-04 -4.4827 0.27090E-04 -4.5672 0.82312E+00 -0.0845 16 HPO4-- 0.45826E-07 -7.3389 0.22687E-07 -7.6442 0.49506E+00 -0.3053 18 HSiO3- 0.58920E-02 -2.2297 0.48613E-02 -2.3132 0.82507E+00 -0.0835 19 Ca(HSiO3)+ 0.16755E-08 -8.7758 0.13855E-08 -8.8584 0.82688E+00 -0.0826 20 Mg(HSiO3)+ 0.17876E-11 -11.7477 0.14782E-11 -11.8303 0.82688E+00 -0.0826 21 NaHSiO3,aq 0.13540E-02 -2.8684 0.13540E-02 -2.8684 0.10000E+01 0.0000 22 AlO+ 0.14213E-15 -15.8473 0.11753E-15 -15.9299 0.82688E+00 -0.0826 24 HAlO2,aq 0.11893E-09 -9.9247 0.11893E-09 -9.9247 0.10000E+01 0.0000 25 AlO2- 0.16246E-05 -5.7893 0.13376E-05 -5.8737 0.82336E+00 -0.0844 26 CH4,aq 0.20205E-07 -7.6945 0.20107E-07 -7.6967 0.99512E+00 -0.0021 27 C2H6,aq 0.41500E-18 -18.3819 0.41298E-18 -18.3841 0.99512E+00 -0.0021 31 CO,aq 0.49978E-14 -14.3012 0.49978E-14 -14.3012 0.10000E+01 0.0000 32 CO2,aq 0.11946E-05 -5.9228 0.11888E-05 -5.9249 0.99512E+00 -0.0021 33 CO3-2 0.25409E-02 -2.5950 0.12546E-02 -2.9015 0.49377E+00 -0.3065 34 CaCO3,aq 0.19687E-06 -6.7058 0.19687E-06 -6.7058 0.10000E+01 0.0000 35 Ca(HCO3)+ 0.10921E-08 -8.9617 0.90305E-09 -9.0443 0.82688E+00 -0.0826 36 CaCl+ 0.12847E-10 -10.8912 0.10623E-10 -10.9738 0.82688E+00 -0.0826 37 CaCl2,aq 0.13238E-14 -14.8782 0.13238E-14 -14.8782 0.10000E+01 0.0000 38 CaF+ 0.59859E-11 -11.2229 0.49496E-11 -11.3054 0.82688E+00 -0.0826 39 CaOH+ 0.54806E-08 -8.2612 0.45318E-08 -8.3437 0.82688E+00 -0.0826 40 CaSO4,aq 0.73919E-09 -9.1312 0.73919E-09 -9.1312 0.10000E+01 0.0000 41 HCl,aq 0.18917E-13 -13.7232 0.18917E-13 -13.7232 0.10000E+01 0.0000 45 HF,aq 0.36498E-10 -10.4377 0.36498E-10 -10.4377 0.10000E+01 0.0000 46 HF2- 0.40460E-15 -15.3930 0.33382E-15 -15.4765 0.82507E+00 -0.0835 48 FeCl+ 0.13463E-15 -15.8709 0.11132E-15 -15.9534 0.82688E+00 -0.0826 51 FeF+ 0.22448E-15 -15.6488 0.18562E-15 -15.7314 0.82688E+00 -0.0826 53 FeO,aq 0.13454E-09 -9.8711 0.13454E-09 -9.8711 0.10000E+01 0.0000 54 FeOH+ 0.26820E-10 -10.5715 0.22177E-10 -10.6541 0.82688E+00 -0.0826 55 HFeO2- 0.86694E-08 -8.0620 0.71528E-08 -8.1455 0.82507E+00 -0.0835 56 FeO+ 0.15637E-15 -15.8058 0.12930E-15 -15.8884 0.82688E+00 -0.0826 58 FeO2- 0.82791E-09 -9.0820 0.68309E-09 -9.1655 0.82507E+00 -0.0835 59 HFeO2,aq 0.17098E-10 -10.7670 0.17098E-10 -10.7670 0.10000E+01 0.0000 60 H2,aq 0.16817E-06 -6.7742 0.16735E-06 -6.7764 0.99512E+00 -0.0021 61 KCl,aq 0.12284E-08 -8.9107 0.12284E-08 -8.9107 0.10000E+01 0.0000 62 KHSO4,aq 0.13375E-16 -16.8737 0.13375E-16 -16.8737 0.10000E+01 0.0000 63 KOH,aq 0.28039E-06 -6.5522 0.28039E-06 -6.5522 0.10000E+01 0.0000 64 KSO4- 0.45205E-06 -6.3448 0.37297E-06 -6.4283 0.82507E+00 -0.0835 65 MgCO3,aq 0.42305E-10 -10.3736 0.42305E-10 -10.3736 0.10000E+01 0.0000 66 Mg(HCO3)+ 0.95667E-12 -12.0192 0.79105E-12 -12.1018 0.82688E+00 -0.0826 67 MgCl+ 0.99819E-14 -14.0008 0.82539E-14 -14.0833 0.82688E+00 -0.0826 68 MgF+ 0.19009E-13 -13.7210 0.15718E-13 -13.8036 0.82688E+00 -0.0826 69 MgOH+ 0.25999E-10 -10.5850 0.21498E-10 -10.6676 0.82688E+00 -0.0826 71 MnF+ 0.28395E-13 -13.5468 0.23479E-13 -13.6293 0.82688E+00 -0.0826 72 MnO,aq 0.13758E-08 -8.8615 0.13758E-08 -8.8615 0.10000E+01 0.0000 73 MnOH+ 0.95613E-09 -9.0195 0.79061E-09 -9.1020 0.82688E+00 -0.0826 74 MnO2-2 0.23873E-11 -11.6221 0.11788E-11 -11.9286 0.49377E+00 -0.3065 75 HMnO2- 0.61602E-10 -10.2104 0.50826E-10 -10.2939 0.82507E+00 -0.0835 78 MnCl+ 0.20100E-12 -12.6968 0.16620E-12 -12.7794 0.82688E+00 -0.0826 79 MnSO4,aq 0.27632E-11 -11.5586 0.27632E-11 -11.5586 0.10000E+01 0.0000 80 NaCl,aq 0.29935E-05 -5.5238 0.29935E-05 -5.5238 0.10000E+01 0.0000 81 NaF,aq 0.10922E-06 -6.9617 0.10922E-06 -6.9617 0.10000E+01 0.0000 82 NaOH,aq 0.37594E-04 -4.4249 0.37594E-04 -4.4249 0.10000E+01 0.0000 84 OH- 0.35655E-02 -2.4479 0.29357E-02 -2.5323 0.82336E+00 -0.0844 89 HPO3-2 0.23962E-16 -16.6205 0.11832E-16 -16.9270 0.49377E+00 -0.3065 92 H3PO4,aq 0.61458E-17 -17.2114 0.61458E-17 -17.2114 0.10000E+01 0.0000 93 H2PO4- 0.99720E-10 -10.0012 0.82365E-10 -10.0843 0.82597E+00 -0.0830 94 PO4-3 0.42956E-09 -9.3670 0.94051E-10 -10.0266 0.21894E+00 -0.6597 98 HP2O7-3 0.26049E-17 -17.5842 0.53969E-18 -18.2679 0.20719E+00 -0.6836 99 P2O7-4 0.10289E-16 -16.9876 0.65511E-18 -18.1837 0.63668E-01 -1.1961 100 H2S,aq 0.83249E-06 -6.0796 0.82843E-06 -6.0817 0.99512E+00 -0.0021 101 S2-2 0.49741E-09 -9.3033 0.24561E-09 -9.6098 0.49377E+00 -0.3065 102 S3-2 0.33173E-14 -14.4792 0.16380E-14 -14.7857 0.49377E+00 -0.3065 103 S3- 0.64023E-18 -18.1937 0.52823E-18 -18.2772 0.82507E+00 -0.0835 104 S4-2 0.14615E-19 -19.8352 0.72163E-20 -20.1417 0.49377E+00 -0.3065 107 SO3-2 0.80585E-11 -11.0937 0.40452E-11 -11.3931 0.50198E+00 -0.2993 108 HSO3- 0.60416E-13 -13.2188 0.49848E-13 -13.3024 0.82507E+00 -0.0835 109 HSO4- 0.42618E-10 -10.3704 0.35280E-10 -10.4525 0.82781E+00 -0.0821 111 S2O3-2 0.36660E-11 -11.4358 0.18102E-11 -11.7423 0.49377E+00 -0.3065 112 HS2O3- 0.77204E-19 -19.1124 0.63699E-19 -19.1959 0.82507E+00 -0.0835 Charge balance for all species = -.6124E-08 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.2368870E-09 -.1339503E-01 -.1347834E+02 0.0000 2 H2O 0.1000000E+01 0.5550461E+02 0.9982255E+06 0.0000 3 Cl- 0.6357381E-03 0.6387328E-03 0.2260634E+02 6.4257 4 SO4-- 0.3757947E-03 0.3761856E-03 0.3607531E+02 15.6815 5 HCO3- 0.3420556E-02 0.5962891E-02 0.3632179E+03 7.1573 6 HS- 0.1650466E-02 0.1651361E-02 0.5452061E+02 6.8401 7 Al+++ 0.1617043E-27 0.1624707E-05 0.4376221E-01 0.6424 8 H4SiO4 0.1024625E-02 0.8270561E-02 0.7935715E+03 -2.9894 9 Ca++ 0.2549836E-07 0.2313787E-06 0.9257368E-02 11.5093 10 Mg++ 0.2197481E-10 0.9305172E-10 0.2258412E-05 8.4425 11 Fe++ 0.2742966E-12 0.9676018E-08 0.5394543E-03 6.5393 12 K+ 0.1563065E-03 0.1570402E-03 0.6130105E+01 5.8173 13 Na+ 0.2087642E-01 0.2227109E-01 0.5111340E+03 7.9420 14 Mn++ 0.1051641E-09 0.2504046E-08 0.1373325E-03 9.1234 15 F- 0.3291124E-04 0.3302050E-04 0.6262528E+00 5.1388 16 HPO4-- 0.4582595E-07 0.4635523E-07 0.4441535E-02 11.7677 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.1205967E-01 -.1204642E-01 -.1325091E-04 0.0000000E+00 2 H2O 0.4990698E+02 0.4991641E+02 -.9423674E-02 0.0000000E+00 3 Cl- 0.5744252E-03 0.5744252E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.3383172E-03 0.3383112E-03 0.5972608E-08 0.0000000E+00 5 HCO3- 0.5362547E-02 0.5362547E-02 0.0000000E+00 0.0000000E+00 6 HS- 0.1485144E-02 0.1485102E-02 0.4180826E-07 0.0000000E+00 7 Al+++ 0.4775352E-05 0.1461131E-05 0.3314221E-05 0.0000000E+00 8 H4SiO4 0.1215302E-01 0.7437881E-02 0.4715139E-02 0.0000000E+00 9 Ca++ 0.2080835E-06 0.2080835E-06 0.0000000E+00 0.0000000E+00 10 Mg++ 0.8368328E-10 0.8368328E-10 0.0000000E+00 0.0000000E+00 11 Fe++ 0.3259227E-07 0.8701837E-08 0.2389043E-07 0.0000000E+00 12 K+ 0.1412294E-03 0.1412294E-03 0.0000000E+00 0.0000000E+00 13 Na+ 0.2003215E-01 0.2002884E-01 0.3314221E-05 0.0000000E+00 14 Mn++ 0.2251939E-08 0.2251939E-08 0.0000000E+00 0.0000000E+00 15 F- 0.2969600E-04 0.2969600E-04 0.0000000E+00 0.0000000E+00 16 HPO4-- 0.4168819E-07 0.4168819E-07 0.0000000E+00 0.0000000E+00 Chg. balance for solid moles: -.1271E-20 Mass of aqueous solution: 0.900858E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 0.0739900 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 0.3314E-05 -5.480 0.8691E-03 -3.061 0.3065 0.3336E-03 pyrite 0.2389E-07 -7.622 0.2866E-05 -5.543 0.1011E-02 0.5719E-06 quartz 0.4705E-02 -2.327 0.2827 -0.549 99.69 0.1068 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 pyrite 0.1000E+01 0.1000E+01 1.0000 0.000 quartz 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 0.283560 g Volume = 0.107090 cm3 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.0739900 moles log = -1.1308 Original solution: 1000.0103000 g Original solution / Rock added: 13515.48 (Water/Rock Ratio), log = 4.1308 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0207 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9996E+00 0.9859 0.1006E+01 0.1020E+01 CO2,gas 0.1237E-03 1.0071 0.1272E-03 0.1263E-03 CH4,gas 0.2864E-04 1.0125 0.2960E-04 0.2923E-04 H2,gas 0.2151E-03 1.0005 0.2197E-03 0.2196E-03 H2S,gas 0.2240E-04 0.9960 0.2277E-04 0.2286E-04 S2,gas 0.3951E-21 1.0000 0.4033E-21 0.4033E-21 CO,gas 0.7297E-11 1.0000 0.7448E-11 0.7448E-11 SO3,gas 0.2669E-38 1.0000 0.2724E-38 0.2724E-38 SO2,gas 0.2281E-19 1.0000 0.2329E-19 0.2329E-19 HF,gas 0.8780E-13 1.0000 0.8962E-13 0.8962E-13 HCl,gas 0.3270E-16 1.0000 0.3338E-16 0.3338E-16 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 17 albite -0.38 -0.38 0.00 0.000 -0.94784E-12 145 pyrite -21.25 -21.25 0.00 0.000 0.00000E+00 150 quartz -2.99 -2.99 0.00 0.000 0.00000E+00 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -12.25 -5.59 -1.865 0.95525E+04 -3.896 3 CH4,gas 4.54 -1.68 -6.23 -1.557 0.10634E+05 -4.529 4 H2,gas 8.00 2.64 -5.36 -3.061 0.91471E+04 -3.658 5 H2S,gas -6.23 -12.57 -6.34 -3.171 0.10828E+05 -4.643 6 S2,gas -7.34 -30.43 -23.09 -3.553 0.39431E+05 -21.394 7 CO,gas 3.21 -9.61 -12.83 -3.947 0.21902E+05 -11.128 8 SO3,gas 17.12 -23.14 -40.26 -10.066 0.68749E+05 -38.565 9 SO2,gas 0.83 -20.50 -21.33 -5.689 0.36424E+05 -19.633 10 HF,gas 0.47 -14.27 -14.75 -7.373 0.25179E+05 -13.048 11 HCl,gas 5.19 -12.99 -18.18 -9.088 0.31034E+05 -16.477 12 acmite 7.71 7.18 -0.53 -0.055 0.90257E+03 16 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 20 spessartine 24.46 19.69 -4.77 -0.239 0.81459E+04 21 analcite 3.32 2.61 -0.72 -0.080 0.12231E+04 23 andradite 39.01 36.00 -3.01 -0.157 0.51448E+04 26 ankerite -2.14 -6.46 -4.33 -0.721 0.73858E+04 27 annite 20.12 17.11 -3.01 -0.167 0.51465E+04 28 phlogopite 27.06 22.82 -4.25 -0.236 0.72497E+04 34 apatite-F -34.30 -37.89 -3.59 -0.299 0.61366E+04 38 aragonite 0.97 -0.75 -1.71 -0.571 0.29229E+04 39 brucite 12.57 8.44 -4.13 -0.825 0.70452E+04 40 calcite 0.81 -0.75 -1.56 -0.519 0.26587E+04 41 carnegieite-low 9.02 5.60 -3.43 -0.490 0.58537E+04 42 carnegieite-high 10.09 5.60 -4.50 -0.643 0.76807E+04 43 carpholite-Mg 8.58 3.75 -4.83 -0.322 0.82533E+04 44 carpholite-Fe 6.71 1.85 -4.87 -0.324 0.83109E+04 45 celadonite 5.34 2.94 -2.40 -0.141 0.40931E+04 46 celadonite-Fe 3.88 1.04 -2.84 -0.167 0.48411E+04 47 chrysotile 23.89 19.35 -4.54 -0.379 0.77586E+04 49 clinochlore 39.07 34.53 -4.54 -0.142 0.77531E+04 50 daphnite 28.97 25.01 -3.95 -0.124 0.67483E+04 54 chloritoid-Fe 9.17 4.83 -4.34 -0.289 0.74086E+04 55 chloritoid-Mn 11.40 7.42 -3.98 -0.265 0.67997E+04 57 coesite -2.38 -2.99 -0.61 -0.204 0.10473E+04 64 cristobalite -2.56 -2.99 -0.43 -0.143 0.73267E+03 66 cymrite-K 1.69 -2.51 -4.19 -0.349 0.71611E+04 68 diaspore 2.87 0.64 -2.23 -0.372 0.38098E+04 69 diamond -3.10 -6.97 -3.87 -1.105 0.66027E+04 70 diopside 16.18 13.97 -2.21 -0.221 0.37709E+04 71 hedenbergite 14.21 12.07 -2.14 -0.214 0.36515E+04 78 epidote 24.67 20.55 -4.12 -0.200 0.70292E+04 80 epidote-Fe 29.84 25.13 -4.71 -0.245 0.80458E+04 81 fayalite 14.05 10.09 -3.96 -0.565 0.67558E+04 82 ferrosilite 11.15 7.10 -4.05 -0.405 0.69148E+04 86 gibbsite 4.08 0.64 -3.44 -0.491 0.58684E+04 87 glaucophane 22.97 18.58 -4.39 -0.119 0.75027E+04 88 glaucophane-Fe 17.28 12.87 -4.40 -0.119 0.75206E+04 89 graphite -3.55 -6.97 -3.42 -0.978 0.58450E+04 90 greenalite 16.14 13.64 -2.50 -0.208 0.42695E+04 93 hematite 12.57 10.44 -2.13 -0.258 0.36373E+04 94 heulandite -5.83 -8.13 -2.30 -0.105 0.39351E+04 98 jadeite 4.22 2.61 -1.61 -0.161 0.27485E+04 100 kalsilite 7.58 3.47 -4.11 -0.588 0.70239E+04 101 kaolinite -1.33 -4.69 -3.36 -0.306 0.57392E+04 104 laumontite 2.88 0.84 -2.05 -0.136 0.34951E+04 105 lawsonite 9.62 6.82 -2.80 -0.187 0.47822E+04 106 leucite 4.12 0.48 -3.64 -0.364 0.62118E+04 108 lizardite 23.24 19.35 -3.90 -0.325 0.66512E+04 109 magnesite 0.69 -3.81 -4.50 -1.501 0.76884E+04 110 magnetite 20.09 16.98 -3.11 -0.254 0.53139E+04 111 minnesotaite 10.39 7.66 -2.73 -0.160 0.46579E+04 115 manganosite 14.06 9.12 -4.93 -1.234 0.84260E+04 119 microcline -2.49 -2.51 -0.02 -0.002 0.37753E+02 123 muscovite 2.58 -1.22 -3.81 -0.224 0.64990E+04 124 paragonite 4.24 0.90 -3.34 -0.196 0.57003E+04 125 nepheline 8.34 5.60 -2.74 -0.392 0.46861E+04 137 phlogopite-Na 29.65 24.94 -4.70 -0.261 0.80307E+04 139 prehnite 19.37 15.34 -4.04 -0.237 0.68925E+04 140 prehnite-Fe 22.50 19.91 -2.59 -0.156 0.44174E+04 146 pyrrhotite -4.26 -6.03 -1.77 -0.591 0.30259E+04 147 pyrrhotiteFe0.875 -6.02 -7.18 -1.16 -0.427 0.19818E+04 148 pyroxmangite 7.40 6.13 -1.26 -0.253 0.21595E+04 149 pyrophyllite -6.18 -10.67 -4.50 -0.281 0.76787E+04 154 rhodochrosite -0.98 -3.13 -2.15 -0.718 0.36795E+04 155 rhodonite 7.45 6.13 -1.31 -0.262 0.22398E+04 156 sanidine -1.28 -2.51 -1.23 -0.095 0.21055E+04 158 siderite -2.61 -5.72 -3.11 -1.036 0.53055E+04 166 stilbite -7.52 -8.13 -0.61 -0.029 0.10412E+04 167 stilpnomelane-Fe 13.02 12.97 -0.04 -0.001 0.72554E+02 168 stilpnomelane-Mg 27.44 22.49 -4.95 -0.148 0.84539E+04 174 talc 16.49 13.37 -3.12 -0.184 0.53298E+04 177 tephroite 18.09 15.26 -2.83 -0.404 0.48296E+04 181 tridymite -2.63 -2.99 -0.36 -0.121 0.61998E+03 184 troilite-low -4.41 -6.03 -1.62 -0.541 0.27687E+04 190 wairakite 3.95 0.84 -3.11 -0.183 0.53171E+04 191 walstromite 11.51 8.52 -2.99 -0.598 0.51042E+04 192 wollastonite 10.46 8.52 -1.94 -0.388 0.33146E+04 193 pseudo-wollastonite 11.00 8.52 -2.48 -0.496 0.42345E+04 195 akaganeite 7.75 5.22 -2.54 -0.548 0.43312E+04 202 chalcedony -2.80 -2.99 -0.19 -0.062 0.31930E+03 204 montmorillonite-Ca -2.29 -6.20 -3.91 -0.242 0.66747E+04 205 montmorillonite-K -2.24 -6.18 -3.94 -0.241 0.67316E+04 206 montmorillonite-Mg -2.48 -6.71 -4.23 -0.261 0.72158E+04 207 montmorillonite-Na -2.04 -5.48 -3.44 -0.211 0.58741E+04 208 nontronite-Ca 3.21 1.58 -1.64 -0.106 0.27982E+04 209 nontronite-H 2.53 -0.32 -2.86 -0.191 0.48765E+04 210 nontronite-K 3.34 1.60 -1.74 -0.112 0.29783E+04 211 nontronite-Mg 3.07 1.07 -2.00 -0.130 0.34233E+04 212 nontronite-Na 3.52 2.30 -1.22 -0.078 0.20867E+04 228 tobermorite 9.82 6.60 -3.23 -0.880 0.55070E+04 234 alabandite -0.98 -3.45 -2.47 -0.824 0.42184E+04 237 boehmite 4.41 0.64 -3.76 -0.627 0.64268E+04 239 ferrous-oxide 9.81 6.54 -3.27 -0.818 0.55873E+04 245 silica-amorphous -2.09 -2.99 -0.90 -0.299 0.15335E+04 247 an20ab80 2.02 1.06 -0.96 -0.074 0.16423E+04 248 an25ab75 2.65 1.42 -1.23 -0.095 0.20998E+04 249 an30ab70 3.28 1.78 -1.50 -0.116 0.25669E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 0.0020000 MOLES Current total amount of reactant added: 0.0739900 MOLES New total amount of reactant added: 0.0759900 MOLES Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.5508E-08 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 8 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 0.0759900 Water: Moles liquid = 0.4992E+02 kg liquid = 0.8994E+00 Moles total = 0.4991E+02 kg total = 0.8991E+00 Activity = 1.0000 Stoichiometric ionic strength = .1624809E-01 Osmotic coef. = 0.9265 True ionic strength = .2402371E-01 Chg. balance for total moles = -.5508E-08 Max. difference allowed = 0.5862E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.24309E-09 -9.6142 0.20192E-09 -9.6948 0.83064E+00 -0.0806 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.64877E-03 -3.1879 0.53516E-03 -3.2715 0.82489E+00 -0.0836 4 SO4-- 0.38639E-03 -3.4130 0.19109E-03 -3.7188 0.49456E+00 -0.3058 5 HCO3- 0.35500E-02 -2.4498 0.29333E-02 -2.5326 0.82628E+00 -0.0829 6 HS- 0.16938E-02 -2.7711 0.13974E-02 -2.8547 0.82503E+00 -0.0835 7 Al+++ 0.17928E-27 -27.7465 0.37027E-28 -28.4315 0.20653E+00 -0.6850 8 H4SiO4 0.10246E-02 -2.9894 0.10246E-02 -2.9894 0.10000E+01 0.0000 9 Ca++ 0.25286E-07 -7.5971 0.12399E-07 -7.9066 0.49037E+00 -0.3095 10 Mg++ 0.22032E-10 -10.6570 0.10747E-10 -10.9687 0.48778E+00 -0.3118 11 Fe++ 0.25904E-12 -12.5866 0.12652E-12 -12.8979 0.48840E+00 -0.3112 12 K+ 0.15630E-03 -3.8061 0.12918E-03 -3.8888 0.82650E+00 -0.0828 13 Na+ 0.20909E-01 -1.6797 0.17244E-01 -1.7634 0.82471E+00 -0.0837 14 Mn++ 0.10951E-09 -9.9605 0.53537E-10 -10.2713 0.48886E+00 -0.3108 15 F- 0.33796E-04 -4.4711 0.27812E-04 -4.5558 0.82294E+00 -0.0846 16 HPO4-- 0.45832E-07 -7.3388 0.22670E-07 -7.6445 0.49464E+00 -0.3057 18 HSiO3- 0.57440E-02 -2.2408 0.47382E-02 -2.3244 0.82489E+00 -0.0836 19 Ca(HSiO3)+ 0.16184E-08 -8.7909 0.13380E-08 -8.8736 0.82671E+00 -0.0826 20 Mg(HSiO3)+ 0.17457E-11 -11.7580 0.14432E-11 -11.8407 0.82671E+00 -0.0826 21 NaHSiO3,aq 0.13215E-02 -2.8789 0.13215E-02 -2.8789 0.10000E+01 0.0000 22 AlO+ 0.14945E-15 -15.8255 0.12355E-15 -15.9082 0.82671E+00 -0.0826 24 HAlO2,aq 0.12185E-09 -9.9142 0.12185E-09 -9.9142 0.10000E+01 0.0000 25 AlO2- 0.16228E-05 -5.7897 0.13358E-05 -5.8742 0.82318E+00 -0.0845 26 CH4,aq 0.20940E-07 -7.6790 0.20837E-07 -7.6812 0.99508E+00 -0.0021 27 C2H6,aq 0.44872E-18 -18.3480 0.44651E-18 -18.3502 0.99508E+00 -0.0021 31 CO,aq 0.52849E-14 -14.2770 0.52849E-14 -14.2770 0.10000E+01 0.0000 32 CO2,aq 0.12718E-05 -5.8956 0.12656E-05 -5.8977 0.99508E+00 -0.0021 33 CO3-2 0.25720E-02 -2.5897 0.12689E-02 -2.8966 0.49335E+00 -0.3068 34 CaCO3,aq 0.19728E-06 -6.7049 0.19728E-06 -6.7049 0.10000E+01 0.0000 35 Ca(HCO3)+ 0.11230E-08 -8.9496 0.92840E-09 -9.0323 0.82671E+00 -0.0826 36 CaCl+ 0.12990E-10 -10.8864 0.10739E-10 -10.9691 0.82671E+00 -0.0826 37 CaCl2,aq 0.13653E-14 -14.8648 0.13653E-14 -14.8648 0.10000E+01 0.0000 38 CaF+ 0.60903E-11 -11.2154 0.50349E-11 -11.2980 0.82671E+00 -0.0826 39 CaOH+ 0.52938E-08 -8.2762 0.43765E-08 -8.3589 0.82671E+00 -0.0826 40 CaSO4,aq 0.75240E-09 -9.1236 0.75240E-09 -9.1236 0.10000E+01 0.0000 41 HCl,aq 0.19802E-13 -13.7033 0.19802E-13 -13.7033 0.10000E+01 0.0000 45 HF,aq 0.38445E-10 -10.4152 0.38445E-10 -10.4152 0.10000E+01 0.0000 46 HF2- 0.43764E-15 -15.3589 0.36100E-15 -15.4425 0.82489E+00 -0.0836 48 FeCl+ 0.12963E-15 -15.8873 0.10717E-15 -15.9699 0.82671E+00 -0.0826 51 FeF+ 0.21750E-15 -15.6625 0.17981E-15 -15.7452 0.82671E+00 -0.0826 53 FeO,aq 0.12060E-09 -9.9187 0.12060E-09 -9.9187 0.10000E+01 0.0000 54 FeOH+ 0.24670E-10 -10.6078 0.20395E-10 -10.6905 0.82671E+00 -0.0826 55 HFeO2- 0.75759E-08 -8.1206 0.62493E-08 -8.2042 0.82489E+00 -0.0836 56 FeO+ 0.14433E-15 -15.8407 0.11932E-15 -15.9233 0.82671E+00 -0.0826 58 FeO2- 0.72593E-09 -9.1391 0.59881E-09 -9.2227 0.82489E+00 -0.0836 59 HFeO2,aq 0.15378E-10 -10.8131 0.15378E-10 -10.8131 0.10000E+01 0.0000 60 H2,aq 0.16705E-06 -6.7771 0.16623E-06 -6.7793 0.99508E+00 -0.0021 61 KCl,aq 0.12530E-08 -8.9021 0.12530E-08 -8.9021 0.10000E+01 0.0000 62 KHSO4,aq 0.14093E-16 -16.8510 0.14093E-16 -16.8510 0.10000E+01 0.0000 63 KOH,aq 0.27321E-06 -6.5635 0.27321E-06 -6.5635 0.10000E+01 0.0000 64 KSO4- 0.46437E-06 -6.3331 0.38305E-06 -6.4167 0.82489E+00 -0.0836 65 MgCO3,aq 0.42858E-10 -10.3680 0.42858E-10 -10.3680 0.10000E+01 0.0000 66 Mg(HCO3)+ 0.99456E-12 -12.0024 0.82221E-12 -12.0850 0.82671E+00 -0.0826 67 MgCl+ 0.10204E-13 -13.9912 0.84355E-14 -14.0739 0.82671E+00 -0.0826 68 MgF+ 0.19553E-13 -13.7088 0.16165E-13 -13.7914 0.82671E+00 -0.0826 69 MgOH+ 0.25389E-10 -10.5954 0.20989E-10 -10.6780 0.82671E+00 -0.0826 71 MnF+ 0.30337E-13 -13.5180 0.25080E-13 -13.6007 0.82671E+00 -0.0826 72 MnO,aq 0.13598E-08 -8.8665 0.13598E-08 -8.8665 0.10000E+01 0.0000 73 MnOH+ 0.96981E-09 -9.0133 0.80175E-09 -9.0960 0.82671E+00 -0.0826 74 MnO2-2 0.22436E-11 -11.6491 0.11069E-11 -11.9559 0.49335E+00 -0.3068 75 HMnO2- 0.59360E-10 -10.2265 0.48965E-10 -10.3101 0.82489E+00 -0.0836 78 MnCl+ 0.21341E-12 -12.6708 0.17643E-12 -12.7534 0.82671E+00 -0.0826 79 MnSO4,aq 0.29534E-11 -11.5297 0.29534E-11 -11.5297 0.10000E+01 0.0000 80 NaCl,aq 0.30583E-05 -5.5145 0.30583E-05 -5.5145 0.10000E+01 0.0000 81 NaF,aq 0.11228E-06 -6.9497 0.11228E-06 -6.9497 0.10000E+01 0.0000 82 NaOH,aq 0.36692E-04 -4.4354 0.36692E-04 -4.4354 0.10000E+01 0.0000 84 OH- 0.34760E-02 -2.4589 0.28614E-02 -2.5434 0.82318E+00 -0.0845 89 HPO3-2 0.23804E-16 -16.6233 0.11744E-16 -16.9302 0.49335E+00 -0.3068 92 H3PO4,aq 0.64646E-17 -17.1895 0.64646E-17 -17.1895 0.10000E+01 0.0000 93 H2PO4- 0.10226E-09 -9.9903 0.84444E-10 -10.0734 0.82579E+00 -0.0831 94 PO4-3 0.41915E-09 -9.3776 0.91604E-10 -10.0381 0.21855E+00 -0.6605 98 HP2O7-3 0.26739E-17 -17.5729 0.55292E-18 -18.2573 0.20678E+00 -0.6845 99 P2O7-4 0.10310E-16 -16.9868 0.65417E-18 -18.1843 0.63453E-01 -1.1976 100 H2S,aq 0.87638E-06 -6.0573 0.87207E-06 -6.0594 0.99508E+00 -0.0021 101 S2-2 0.52762E-09 -9.2777 0.26030E-09 -9.5845 0.49335E+00 -0.3068 102 S3-2 0.37292E-14 -14.4284 0.18398E-14 -14.7352 0.49335E+00 -0.3068 103 S3- 0.74042E-18 -18.1305 0.61076E-18 -18.2141 0.82489E+00 -0.0836 104 S4-2 0.17411E-19 -19.7592 0.85897E-20 -20.0660 0.49335E+00 -0.3068 107 SO3-2 0.82298E-11 -11.0846 0.41279E-11 -11.3843 0.50157E+00 -0.2997 108 HSO3- 0.63266E-13 -13.1988 0.52187E-13 -13.2824 0.82489E+00 -0.0836 109 HSO4- 0.44929E-10 -10.3475 0.37185E-10 -10.4296 0.82764E+00 -0.0822 111 S2O3-2 0.39679E-11 -11.4014 0.19575E-11 -11.7083 0.49335E+00 -0.3068 112 HS2O3- 0.85678E-19 -19.0671 0.70675E-19 -19.1507 0.82489E+00 -0.0836 Charge balance for all species = -.6124E-08 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.2430892E-09 -.1315507E-01 -.1323692E+02 0.0000 2 H2O 0.1000000E+01 0.5550470E+02 0.9982299E+06 0.0000 3 Cl- 0.6487697E-03 0.6518293E-03 0.2306992E+02 6.4233 4 SO4-- 0.3863871E-03 0.3867898E-03 0.3709234E+02 15.6709 5 HCO3- 0.3549995E-02 0.6123448E-02 0.3729990E+03 7.1622 6 HS- 0.1693777E-02 0.1694717E-02 0.5595218E+02 6.8401 7 Al+++ 0.1792832E-27 0.1622895E-05 0.4371354E-01 0.6530 8 H4SiO4 0.1024625E-02 0.8090110E-02 0.7762591E+03 -2.9894 9 Ca++ 0.2528589E-07 0.2313700E-06 0.9257045E-02 11.4830 10 Mg++ 0.2203161E-10 0.9304822E-10 0.2258333E-05 8.4209 11 Fe++ 0.2590420E-12 0.8462764E-08 0.4718146E-03 6.4918 12 K+ 0.1562955E-03 0.1570343E-03 0.6129891E+01 5.8060 13 Na+ 0.2090893E-01 0.2227025E-01 0.5111161E+03 7.9315 14 Mn++ 0.1095125E-09 0.2503952E-08 0.1373277E-03 9.1183 15 F- 0.3379646E-04 0.3390879E-04 0.6431014E+00 5.1391 16 HPO4-- 0.4583208E-07 0.4635349E-07 0.4441380E-02 11.7451 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.1184432E-01 -.1183106E-01 -.1325693E-04 0.0000000E+00 2 H2O 0.4990862E+02 0.4991837E+02 -.9747689E-02 0.0000000E+00 3 Cl- 0.5862252E-03 0.5862252E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.3478672E-03 0.3478609E-03 0.6245312E-08 0.0000000E+00 5 HCO3- 0.5507147E-02 0.5507147E-02 0.0000000E+00 0.0000000E+00 6 HS- 0.1524194E-02 0.1524151E-02 0.4371719E-07 0.0000000E+00 7 Al+++ 0.4775352E-05 0.1459557E-05 0.3315795E-05 0.0000000E+00 8 H4SiO4 0.1215302E-01 0.7275872E-02 0.4877148E-02 0.0000000E+00 9 Ca++ 0.2080835E-06 0.2080835E-06 0.0000000E+00 0.0000000E+00 10 Mg++ 0.8368328E-10 0.8368328E-10 0.0000000E+00 0.0000000E+00 11 Fe++ 0.3259227E-07 0.7611020E-08 0.2498125E-07 0.0000000E+00 12 K+ 0.1412294E-03 0.1412294E-03 0.0000000E+00 0.0000000E+00 13 Na+ 0.2003215E-01 0.2002883E-01 0.3315795E-05 0.0000000E+00 14 Mn++ 0.2251939E-08 0.2251939E-08 0.0000000E+00 0.0000000E+00 15 F- 0.3049600E-04 0.3049600E-04 0.0000000E+00 0.0000000E+00 16 HPO4-- 0.4168819E-07 0.4168819E-07 0.0000000E+00 0.0000000E+00 Chg. balance for solid moles: 0.0000E+00 Mass of aqueous solution: 0.900889E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 0.0759900 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 0.3316E-05 -5.479 0.8695E-03 -3.061 0.2964 0.3338E-03 pyrite 0.2498E-07 -7.602 0.2997E-05 -5.523 0.1022E-02 0.5980E-06 quartz 0.4867E-02 -2.313 0.2924 -0.534 99.70 0.1104 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 pyrite 0.1000E+01 0.1000E+01 1.0000 0.000 quartz 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 0.293294 g Volume = 0.110765 cm3 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.0759900 moles log = -1.1192 Original solution: 1000.0103000 g Original solution / Rock added: 13159.76 (Water/Rock Ratio), log = 4.1192 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0207 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9996E+00 0.9859 0.1006E+01 0.1020E+01 CO2,gas 0.1317E-03 1.0071 0.1354E-03 0.1345E-03 CH4,gas 0.2968E-04 1.0125 0.3067E-04 0.3029E-04 H2,gas 0.2137E-03 1.0005 0.2182E-03 0.2181E-03 H2S,gas 0.2358E-04 0.9960 0.2397E-04 0.2407E-04 S2,gas 0.4437E-21 1.0000 0.4529E-21 0.4529E-21 CO,gas 0.7716E-11 1.0000 0.7875E-11 0.7875E-11 SO3,gas 0.2886E-38 1.0000 0.2946E-38 0.2946E-38 SO2,gas 0.2450E-19 1.0000 0.2501E-19 0.2501E-19 HF,gas 0.9248E-13 1.0000 0.9440E-13 0.9440E-13 HCl,gas 0.3423E-16 1.0000 0.3494E-16 0.3494E-16 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 17 albite -0.38 -0.38 0.00 0.000 -0.94784E-12 145 pyrite -21.25 -21.25 0.00 0.000 0.00000E+00 150 quartz -2.99 -2.99 0.00 0.000 0.00000E+00 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -12.23 -5.57 -1.856 0.95061E+04 -3.868 3 CH4,gas 4.54 -1.67 -6.21 -1.553 0.10607E+05 -4.513 4 H2,gas 8.00 2.64 -5.36 -3.063 0.91521E+04 -3.661 5 H2S,gas -6.23 -12.55 -6.32 -3.160 0.10790E+05 -4.620 6 S2,gas -7.34 -30.38 -23.04 -3.545 0.39345E+05 -21.344 7 CO,gas 3.21 -9.59 -12.80 -3.939 0.21860E+05 -11.104 8 SO3,gas 17.12 -23.11 -40.23 -10.057 0.68691E+05 -38.531 9 SO2,gas 0.83 -20.47 -21.30 -5.680 0.36371E+05 -19.602 10 HF,gas 0.47 -14.25 -14.72 -7.362 0.25141E+05 -13.025 11 HCl,gas 5.19 -12.97 -18.16 -9.078 0.31000E+05 -16.457 12 acmite 7.71 7.12 -0.59 -0.061 0.99922E+03 16 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 20 spessartine 24.46 19.69 -4.76 -0.238 0.81358E+04 21 analcite 3.32 2.61 -0.72 -0.080 0.12231E+04 23 andradite 39.01 35.82 -3.18 -0.165 0.54367E+04 26 ankerite -2.14 -6.48 -4.35 -0.724 0.74190E+04 27 annite 20.12 16.97 -3.16 -0.175 0.53911E+04 28 phlogopite 27.06 22.75 -4.31 -0.240 0.73612E+04 34 apatite-F -34.30 -37.94 -3.64 -0.303 0.62100E+04 38 aragonite 0.97 -0.74 -1.71 -0.570 0.29214E+04 39 brucite 12.57 8.42 -4.15 -0.830 0.70820E+04 40 calcite 0.81 -0.74 -1.56 -0.519 0.26572E+04 41 carnegieite-low 9.02 5.60 -3.43 -0.490 0.58537E+04 42 carnegieite-high 10.09 5.60 -4.50 -0.643 0.76807E+04 43 carpholite-Mg 8.58 3.75 -4.83 -0.322 0.82541E+04 44 carpholite-Fe 6.71 1.82 -4.89 -0.326 0.83560E+04 45 celadonite 5.34 2.92 -2.42 -0.142 0.41311E+04 46 celadonite-Fe 3.88 0.99 -2.88 -0.170 0.49235E+04 47 chrysotile 23.89 19.28 -4.61 -0.384 0.78689E+04 49 clinochlore 39.07 34.44 -4.63 -0.145 0.79010E+04 50 daphnite 28.97 24.80 -4.17 -0.130 0.71179E+04 54 chloritoid-Fe 9.17 4.81 -4.37 -0.291 0.74536E+04 55 chloritoid-Mn 11.40 7.43 -3.97 -0.264 0.67723E+04 57 coesite -2.38 -2.99 -0.61 -0.204 0.10473E+04 64 cristobalite -2.56 -2.99 -0.43 -0.143 0.73267E+03 66 cymrite-K 1.69 -2.51 -4.19 -0.350 0.71623E+04 68 diaspore 2.87 0.65 -2.22 -0.370 0.37918E+04 69 diamond -3.10 -6.95 -3.85 -1.099 0.65663E+04 70 diopside 16.18 13.93 -2.26 -0.226 0.38525E+04 71 hedenbergite 14.21 12.00 -2.21 -0.221 0.37775E+04 78 epidote 24.67 20.48 -4.19 -0.203 0.71616E+04 80 epidote-Fe 29.84 24.99 -4.85 -0.252 0.82748E+04 81 fayalite 14.05 9.99 -4.05 -0.579 0.69180E+04 82 ferrosilite 11.15 7.00 -4.14 -0.414 0.70771E+04 86 gibbsite 4.08 0.65 -3.43 -0.489 0.58504E+04 87 glaucophane 22.97 18.52 -4.46 -0.121 0.76131E+04 88 glaucophane-Fe 17.28 12.73 -4.55 -0.123 0.77640E+04 89 graphite -3.55 -6.95 -3.40 -0.972 0.58085E+04 90 greenalite 16.14 13.50 -2.64 -0.220 0.45129E+04 93 hematite 12.57 10.34 -2.22 -0.269 0.37946E+04 94 heulandite -5.83 -8.14 -2.31 -0.105 0.39439E+04 98 jadeite 4.22 2.61 -1.61 -0.161 0.27485E+04 100 kalsilite 7.58 3.47 -4.11 -0.588 0.70251E+04 101 kaolinite -1.33 -4.67 -3.34 -0.304 0.57032E+04 104 laumontite 2.88 0.83 -2.05 -0.137 0.35040E+04 105 lawsonite 9.62 6.81 -2.81 -0.187 0.47911E+04 106 leucite 4.12 0.48 -3.64 -0.364 0.62130E+04 108 lizardite 23.24 19.28 -3.96 -0.330 0.67615E+04 109 magnesite 0.69 -3.81 -4.50 -1.499 0.76788E+04 110 magnetite 20.09 16.84 -3.25 -0.265 0.55523E+04 111 minnesotaite 10.39 7.52 -2.87 -0.169 0.49013E+04 115 manganosite 14.06 9.12 -4.94 -1.235 0.84346E+04 119 microcline -2.49 -2.51 -0.02 -0.002 0.38956E+02 123 muscovite 2.58 -1.20 -3.79 -0.223 0.64641E+04 124 paragonite 4.24 0.92 -3.32 -0.195 0.56643E+04 125 nepheline 8.34 5.60 -2.74 -0.392 0.46861E+04 137 phlogopite-Na 29.65 24.88 -4.77 -0.265 0.81411E+04 139 prehnite 19.37 15.30 -4.07 -0.239 0.69462E+04 140 prehnite-Fe 22.50 19.82 -2.68 -0.161 0.45678E+04 146 pyrrhotite -4.26 -6.06 -1.80 -0.599 0.30690E+04 147 pyrrhotiteFe0.875 -6.02 -7.20 -1.18 -0.434 0.20141E+04 148 pyroxmangite 7.40 6.13 -1.27 -0.254 0.21682E+04 149 pyrophyllite -6.18 -10.65 -4.48 -0.280 0.76426E+04 154 rhodochrosite -0.98 -3.11 -2.13 -0.711 0.36418E+04 155 rhodonite 7.45 6.13 -1.32 -0.263 0.22484E+04 156 sanidine -1.28 -2.51 -1.23 -0.095 0.21067E+04 158 siderite -2.61 -5.74 -3.13 -1.043 0.53402E+04 166 stilbite -7.52 -8.14 -0.61 -0.029 0.10501E+04 167 stilpnomelane-Fe 13.02 12.75 -0.26 -0.008 0.45171E+03 174 talc 16.49 13.30 -3.19 -0.187 0.54401E+04 177 tephroite 18.09 15.25 -2.84 -0.406 0.48469E+04 181 tridymite -2.63 -2.99 -0.36 -0.121 0.61998E+03 184 troilite-low -4.41 -6.06 -1.65 -0.549 0.28118E+04 190 wairakite 3.95 0.83 -3.12 -0.183 0.53259E+04 191 walstromite 11.51 8.49 -3.02 -0.603 0.51491E+04 192 wollastonite 10.46 8.49 -1.97 -0.394 0.33595E+04 193 pseudo-wollastonite 11.00 8.49 -2.51 -0.501 0.42794E+04 195 akaganeite 7.75 5.17 -2.58 -0.558 0.44098E+04 202 chalcedony -2.80 -2.99 -0.19 -0.062 0.31930E+03 204 montmorillonite-Ca -2.29 -6.19 -3.90 -0.241 0.66642E+04 205 montmorillonite-K -2.24 -6.17 -3.94 -0.241 0.67200E+04 206 montmorillonite-Mg -2.48 -6.70 -4.22 -0.261 0.72039E+04 207 montmorillonite-Na -2.04 -5.47 -3.43 -0.210 0.58621E+04 208 nontronite-Ca 3.21 1.48 -1.73 -0.112 0.29569E+04 209 nontronite-H 2.53 -0.41 -2.94 -0.197 0.50278E+04 210 nontronite-K 3.34 1.50 -1.84 -0.118 0.31360E+04 211 nontronite-Mg 3.07 0.98 -2.10 -0.136 0.35807E+04 212 nontronite-Na 3.52 2.21 -1.31 -0.084 0.22440E+04 228 tobermorite 9.82 6.58 -3.25 -0.886 0.55444E+04 234 alabandite -0.98 -3.43 -2.45 -0.818 0.41890E+04 237 boehmite 4.41 0.65 -3.75 -0.626 0.64087E+04 239 ferrous-oxide 9.81 6.49 -3.32 -0.830 0.56685E+04 245 silica-amorphous -2.09 -2.99 -0.90 -0.299 0.15335E+04 247 an20ab80 2.02 1.05 -0.96 -0.074 0.16440E+04 248 an25ab75 2.65 1.41 -1.23 -0.095 0.21020E+04 249 an30ab70 3.28 1.77 -1.50 -0.116 0.25696E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 0.0020000 MOLES Current total amount of reactant added: 0.0759900 MOLES New total amount of reactant added: 0.0779900 MOLES Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.5508E-08 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 8 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 0.0779900 Water: Moles liquid = 0.4992E+02 kg liquid = 0.8994E+00 Moles total = 0.4991E+02 kg total = 0.8992E+00 Activity = 1.0000 Stoichiometric ionic strength = .1637779E-01 Osmotic coef. = 0.9262 True ionic strength = .2409511E-01 Chg. balance for total moles = -.5508E-08 Max. difference allowed = 0.5980E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.24955E-09 -9.6028 0.20725E-09 -9.6835 0.83048E+00 -0.0807 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.66180E-03 -3.1793 0.54580E-03 -3.2630 0.82472E+00 -0.0837 4 SO4-- 0.39698E-03 -3.4012 0.19617E-03 -3.7074 0.49416E+00 -0.3061 5 HCO3- 0.36819E-02 -2.4339 0.30417E-02 -2.5169 0.82611E+00 -0.0830 6 HS- 0.17371E-02 -2.7602 0.14328E-02 -2.8438 0.82486E+00 -0.0836 7 Al+++ 0.19908E-27 -27.7010 0.41039E-28 -28.3868 0.20614E+00 -0.6858 8 H4SiO4 0.10246E-02 -2.9894 0.10246E-02 -2.9894 0.10000E+01 0.0000 9 Ca++ 0.25096E-07 -7.6004 0.12296E-07 -7.9102 0.48995E+00 -0.3098 10 Mg++ 0.22096E-10 -10.6557 0.10769E-10 -10.9678 0.48737E+00 -0.3121 11 Fe++ 0.24492E-12 -12.6110 0.11952E-12 -12.9226 0.48798E+00 -0.3116 12 K+ 0.15628E-03 -3.8061 0.12914E-03 -3.8889 0.82633E+00 -0.0828 13 Na+ 0.20941E-01 -1.6790 0.17267E-01 -1.7628 0.82454E+00 -0.0838 14 Mn++ 0.11408E-09 -9.9428 0.55722E-10 -10.2540 0.48845E+00 -0.3112 15 F- 0.34682E-04 -4.4599 0.28535E-04 -4.5446 0.82276E+00 -0.0847 16 HPO4-- 0.45838E-07 -7.3388 0.22655E-07 -7.6448 0.49424E+00 -0.3061 18 HSiO3- 0.55975E-02 -2.2520 0.46163E-02 -2.3357 0.82472E+00 -0.0837 19 Ca(HSiO3)+ 0.15640E-08 -8.8058 0.12927E-08 -8.8885 0.82654E+00 -0.0827 20 Mg(HSiO3)+ 0.17047E-11 -11.7684 0.14090E-11 -11.8511 0.82654E+00 -0.0827 21 NaHSiO3,aq 0.12892E-02 -2.8897 0.12892E-02 -2.8897 0.10000E+01 0.0000 22 AlO+ 0.15726E-15 -15.8034 0.12998E-15 -15.8861 0.82654E+00 -0.0827 24 HAlO2,aq 0.12490E-09 -9.9034 0.12490E-09 -9.9034 0.10000E+01 0.0000 25 AlO2- 0.16210E-05 -5.7902 0.13341E-05 -5.8748 0.82300E+00 -0.0846 26 CH4,aq 0.21688E-07 -7.6638 0.21581E-07 -7.6659 0.99504E+00 -0.0022 27 C2H6,aq 0.48465E-18 -18.3146 0.48224E-18 -18.3167 0.99504E+00 -0.0022 31 CO,aq 0.55866E-14 -14.2529 0.55866E-14 -14.2529 0.10000E+01 0.0000 32 CO2,aq 0.13537E-05 -5.8685 0.13470E-05 -5.8706 0.99504E+00 -0.0022 33 CO3-2 0.26005E-02 -2.5849 0.12819E-02 -2.8921 0.49294E+00 -0.3072 34 CaCO3,aq 0.19764E-06 -6.7041 0.19764E-06 -6.7041 0.10000E+01 0.0000 35 Ca(HCO3)+ 0.11550E-08 -8.9374 0.95468E-09 -9.0201 0.82654E+00 -0.0827 36 CaCl+ 0.13140E-10 -10.8814 0.10861E-10 -10.9641 0.82654E+00 -0.0827 37 CaCl2,aq 0.14083E-14 -14.8513 0.14083E-14 -14.8513 0.10000E+01 0.0000 38 CaF+ 0.61977E-11 -11.2078 0.51227E-11 -11.2905 0.82654E+00 -0.0827 39 CaOH+ 0.51158E-08 -8.2911 0.42284E-08 -8.3738 0.82654E+00 -0.0827 40 CaSO4,aq 0.76596E-09 -9.1158 0.76596E-09 -9.1158 0.10000E+01 0.0000 41 HCl,aq 0.20728E-13 -13.6834 0.20728E-13 -13.6834 0.10000E+01 0.0000 45 HF,aq 0.40484E-10 -10.3927 0.40484E-10 -10.3927 0.10000E+01 0.0000 46 HF2- 0.47292E-15 -15.3252 0.39003E-15 -15.4089 0.82472E+00 -0.0837 48 FeCl+ 0.12492E-15 -15.9034 0.10325E-15 -15.9861 0.82654E+00 -0.0827 51 FeF+ 0.21085E-15 -15.6760 0.17428E-15 -15.7588 0.82654E+00 -0.0827 53 FeO,aq 0.10815E-09 -9.9660 0.10815E-09 -9.9660 0.10000E+01 0.0000 54 FeOH+ 0.22711E-10 -10.6438 0.18772E-10 -10.7265 0.82654E+00 -0.0827 55 HFeO2- 0.66203E-08 -8.1791 0.54599E-08 -8.2628 0.82472E+00 -0.0837 56 FeO+ 0.13332E-15 -15.8751 0.11019E-15 -15.9578 0.82654E+00 -0.0827 58 FeO2- 0.63653E-09 -9.1962 0.52495E-09 -9.2799 0.82472E+00 -0.0837 59 HFeO2,aq 0.13837E-10 -10.8590 0.13837E-10 -10.8590 0.10000E+01 0.0000 60 H2,aq 0.16592E-06 -6.7801 0.16510E-06 -6.7822 0.99504E+00 -0.0022 61 KCl,aq 0.12775E-08 -8.8936 0.12775E-08 -8.8936 0.10000E+01 0.0000 62 KHSO4,aq 0.14845E-16 -16.8284 0.14845E-16 -16.8284 0.10000E+01 0.0000 63 KOH,aq 0.26611E-06 -6.5749 0.26611E-06 -6.5749 0.10000E+01 0.0000 64 KSO4- 0.47667E-06 -6.3218 0.39312E-06 -6.4055 0.82472E+00 -0.0837 65 MgCO3,aq 0.43388E-10 -10.3626 0.43388E-10 -10.3626 0.10000E+01 0.0000 66 Mg(HCO3)+ 0.10336E-11 -11.9856 0.85435E-12 -12.0684 0.82654E+00 -0.0827 67 MgCl+ 0.10430E-13 -13.9817 0.86210E-14 -14.0644 0.82654E+00 -0.0827 68 MgF+ 0.20107E-13 -13.6967 0.16619E-13 -13.7794 0.82654E+00 -0.0827 69 MgOH+ 0.24792E-10 -10.6057 0.20492E-10 -10.6884 0.82654E+00 -0.0827 71 MnF+ 0.32402E-13 -13.4894 0.26781E-13 -13.5722 0.82654E+00 -0.0827 72 MnO,aq 0.13435E-08 -8.8718 0.13435E-08 -8.8718 0.10000E+01 0.0000 73 MnOH+ 0.98363E-09 -9.0072 0.81301E-09 -9.0899 0.82654E+00 -0.0827 74 MnO2-2 0.21058E-11 -11.6766 0.10380E-11 -11.9838 0.49294E+00 -0.3072 75 HMnO2- 0.57150E-10 -10.2430 0.47132E-10 -10.3267 0.82472E+00 -0.0837 78 MnCl+ 0.22658E-12 -12.6448 0.18728E-12 -12.7275 0.82654E+00 -0.0827 79 MnSO4,aq 0.31557E-11 -11.5009 0.31557E-11 -11.5009 0.10000E+01 0.0000 80 NaCl,aq 0.31232E-05 -5.5054 0.31232E-05 -5.5054 0.10000E+01 0.0000 81 NaF,aq 0.11535E-06 -6.9380 0.11535E-06 -6.9380 0.10000E+01 0.0000 82 NaOH,aq 0.35796E-04 -4.4462 0.35796E-04 -4.4462 0.10000E+01 0.0000 84 OH- 0.33874E-02 -2.4701 0.27878E-02 -2.5547 0.82300E+00 -0.0846 89 HPO3-2 0.23646E-16 -16.6262 0.11656E-16 -16.9334 0.49294E+00 -0.3072 92 H3PO4,aq 0.68056E-17 -17.1671 0.68056E-17 -17.1671 0.10000E+01 0.0000 93 H2PO4- 0.10491E-09 -9.9792 0.86614E-10 -10.0624 0.82562E+00 -0.0832 94 PO4-3 0.40881E-09 -9.3885 0.89187E-10 -10.0497 0.21816E+00 -0.6612 98 HP2O7-3 0.27459E-17 -17.5613 0.56673E-18 -18.2466 0.20640E+00 -0.6853 99 P2O7-4 0.10329E-16 -16.9859 0.65327E-18 -18.1849 0.63246E-01 -1.1990 100 H2S,aq 0.92235E-06 -6.0351 0.91778E-06 -6.0373 0.99504E+00 -0.0022 101 S2-2 0.55896E-09 -9.2526 0.27554E-09 -9.5598 0.49294E+00 -0.3072 102 S3-2 0.41862E-14 -14.3782 0.20636E-14 -14.6854 0.49294E+00 -0.3072 103 S3- 0.85548E-18 -18.0678 0.70553E-18 -18.1515 0.82472E+00 -0.0837 104 S4-2 0.20710E-19 -19.6838 0.10209E-19 -19.9910 0.49294E+00 -0.3072 107 SO3-2 0.83978E-11 -11.0758 0.42088E-11 -11.3758 0.50118E+00 -0.3000 108 HSO3- 0.66222E-13 -13.1790 0.54615E-13 -13.2627 0.82472E+00 -0.0837 109 HSO4- 0.47350E-10 -10.3247 0.39181E-10 -10.4069 0.82748E+00 -0.0822 111 S2O3-2 0.42903E-11 -11.3675 0.21149E-11 -11.6747 0.49294E+00 -0.3072 112 HS2O3- 0.95027E-19 -19.0222 0.78371E-19 -19.1058 0.82472E+00 -0.0837 Charge balance for all species = -.6124E-08 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.2495532E-09 -.1291512E-01 -.1299552E+02 0.0000 2 H2O 0.1000000E+01 0.5550479E+02 0.9982341E+06 0.0000 3 Cl- 0.6618003E-03 0.6649248E-03 0.2353347E+02 6.4205 4 SO4-- 0.3969788E-03 0.3973933E-03 0.3810929E+02 15.6596 5 HCO3- 0.3681888E-02 0.6283994E-02 0.3827793E+03 7.1666 6 HS- 0.1737084E-02 0.1738070E-02 0.5738365E+02 6.8397 7 Al+++ 0.1990822E-27 0.1621082E-05 0.4366481E-01 0.6637 8 H4SiO4 0.1024625E-02 0.7911304E-02 0.7591044E+03 -2.9894 9 Ca++ 0.2509633E-07 0.2313613E-06 0.9256721E-02 11.4568 10 Mg++ 0.2209595E-10 0.9304472E-10 0.2258254E-05 8.3992 11 Fe++ 0.2449245E-12 0.7401783E-08 0.4126641E-03 6.4445 12 K+ 0.1562843E-03 0.1570284E-03 0.6129677E+01 5.7946 13 Na+ 0.2094118E-01 0.2226941E-01 0.5110982E+03 7.9207 14 Mn++ 0.1140784E-09 0.2503858E-08 0.1373229E-03 9.1130 15 F- 0.3468161E-04 0.3479700E-04 0.6599487E+00 5.1389 16 HPO4-- 0.4583803E-07 0.4635174E-07 0.4441225E-02 11.7222 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.1162897E-01 -.1161570E-01 -.1326300E-04 0.0000000E+00 2 H2O 0.4991026E+02 0.4992033E+02 -.1006877E-01 0.0000000E+00 3 Cl- 0.5980252E-03 0.5980252E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.3574172E-03 0.3574107E-03 0.6483799E-08 0.0000000E+00 5 HCO3- 0.5651747E-02 0.5651747E-02 0.0000000E+00 0.0000000E+00 6 HS- 0.1563244E-02 0.1563199E-02 0.4538660E-07 0.0000000E+00 7 Al+++ 0.4775352E-05 0.1457981E-05 0.3317371E-05 0.0000000E+00 8 H4SiO4 0.1215302E-01 0.7115330E-02 0.5037690E-02 0.0000000E+00 9 Ca++ 0.2080835E-06 0.2080835E-06 0.0000000E+00 0.0000000E+00 10 Mg++ 0.8368328E-10 0.8368328E-10 0.0000000E+00 0.0000000E+00 11 Fe++ 0.3259227E-07 0.6657073E-08 0.2593520E-07 0.0000000E+00 12 K+ 0.1412294E-03 0.1412294E-03 0.0000000E+00 0.0000000E+00 13 Na+ 0.2003215E-01 0.2002883E-01 0.3317371E-05 0.0000000E+00 14 Mn++ 0.2251939E-08 0.2251939E-08 0.0000000E+00 0.0000000E+00 15 F- 0.3129600E-04 0.3129600E-04 0.0000000E+00 0.0000000E+00 16 HPO4-- 0.4168819E-07 0.4168819E-07 0.0000000E+00 0.0000000E+00 Chg. balance for solid moles: 0.0000E+00 Mass of aqueous solution: 0.900921E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 0.0779900 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 0.3317E-05 -5.479 0.8699E-03 -3.061 0.2871 0.3339E-03 pyrite 0.2594E-07 -7.586 0.3112E-05 -5.507 0.1027E-02 0.6209E-06 quartz 0.5028E-02 -2.299 0.3021 -0.520 99.71 0.1141 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 pyrite 0.1000E+01 0.1000E+01 1.0000 0.000 quartz 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 0.302940 g Volume = 0.114408 cm3 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.0779900 moles log = -1.1080 Original solution: 1000.0103000 g Original solution / Rock added: 12822.29 (Water/Rock Ratio), log = 4.1080 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0207 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9996E+00 0.9859 0.1006E+01 0.1020E+01 CO2,gas 0.1402E-03 1.0071 0.1441E-03 0.1431E-03 CH4,gas 0.3074E-04 1.0125 0.3177E-04 0.3137E-04 H2,gas 0.2122E-03 1.0005 0.2168E-03 0.2166E-03 H2S,gas 0.2482E-04 0.9960 0.2523E-04 0.2533E-04 S2,gas 0.4982E-21 1.0000 0.5085E-21 0.5085E-21 CO,gas 0.8156E-11 1.0000 0.8325E-11 0.8325E-11 SO3,gas 0.3121E-38 1.0000 0.3186E-38 0.3186E-38 SO2,gas 0.2632E-19 1.0000 0.2687E-19 0.2687E-19 HF,gas 0.9739E-13 1.0000 0.9940E-13 0.9940E-13 HCl,gas 0.3583E-16 1.0000 0.3658E-16 0.3658E-16 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 17 albite -0.38 -0.38 0.00 0.000 -0.94784E-12 145 pyrite -21.25 -21.25 0.00 0.000 0.60662E-11 150 quartz -2.99 -2.99 0.00 0.000 0.00000E+00 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -12.20 -5.54 -1.847 0.94599E+04 -3.841 3 CH4,gas 4.54 -1.65 -6.20 -1.549 0.10581E+05 -4.498 4 H2,gas 8.00 2.64 -5.36 -3.065 0.91572E+04 -3.664 5 H2S,gas -6.23 -12.53 -6.30 -3.149 0.10752E+05 -4.598 6 S2,gas -7.34 -30.33 -22.99 -3.537 0.39259E+05 -21.294 7 CO,gas 3.21 -9.56 -12.78 -3.932 0.21819E+05 -11.080 8 SO3,gas 17.12 -23.07 -40.20 -10.049 0.68633E+05 -38.497 9 SO2,gas 0.83 -20.44 -21.27 -5.672 0.36318E+05 -19.571 10 HF,gas 0.47 -14.23 -14.70 -7.351 0.25103E+05 -13.003 11 HCl,gas 5.19 -12.95 -18.14 -9.068 0.30966E+05 -16.437 12 acmite 7.71 7.07 -0.64 -0.067 0.10958E+04 16 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 20 spessartine 24.46 19.70 -4.76 -0.238 0.81260E+04 21 analcite 3.32 2.61 -0.72 -0.080 0.12231E+04 23 andradite 39.01 35.65 -3.35 -0.174 0.57279E+04 26 ankerite -2.14 -6.50 -4.36 -0.727 0.74522E+04 27 annite 20.12 16.82 -3.30 -0.183 0.56347E+04 28 phlogopite 27.06 22.69 -4.38 -0.243 0.74737E+04 34 apatite-F -34.30 -37.98 -3.68 -0.307 0.62815E+04 38 aragonite 0.97 -0.74 -1.71 -0.570 0.29200E+04 39 brucite 12.57 8.40 -4.17 -0.834 0.71191E+04 40 calcite 0.81 -0.74 -1.56 -0.518 0.26558E+04 41 carnegieite-low 9.02 5.60 -3.43 -0.490 0.58537E+04 42 carnegieite-high 10.09 5.60 -4.50 -0.643 0.76807E+04 43 carpholite-Mg 8.58 3.75 -4.83 -0.322 0.82545E+04 44 carpholite-Fe 6.71 1.79 -4.92 -0.328 0.84001E+04 45 celadonite 5.34 2.90 -2.44 -0.144 0.41694E+04 46 celadonite-Fe 3.88 0.95 -2.93 -0.172 0.50055E+04 47 chrysotile 23.89 19.22 -4.67 -0.389 0.79802E+04 49 clinochlore 39.07 34.36 -4.71 -0.147 0.80498E+04 50 daphnite 28.97 24.58 -4.38 -0.137 0.74853E+04 54 chloritoid-Fe 9.17 4.78 -4.39 -0.293 0.74978E+04 55 chloritoid-Mn 11.40 7.45 -3.95 -0.263 0.67446E+04 57 coesite -2.38 -2.99 -0.61 -0.204 0.10473E+04 64 cristobalite -2.56 -2.99 -0.43 -0.143 0.73267E+03 66 cymrite-K 1.69 -2.51 -4.20 -0.350 0.71635E+04 68 diaspore 2.87 0.66 -2.21 -0.368 0.37735E+04 69 diamond -3.10 -6.93 -3.82 -1.093 0.65302E+04 70 diopside 16.18 13.88 -2.30 -0.230 0.39345E+04 71 hedenbergite 14.21 11.92 -2.29 -0.229 0.39031E+04 78 epidote 24.67 20.40 -4.27 -0.207 0.72929E+04 80 epidote-Fe 29.84 24.86 -4.98 -0.259 0.85027E+04 81 fayalite 14.05 9.90 -4.15 -0.592 0.70796E+04 82 ferrosilite 11.15 6.91 -4.24 -0.424 0.72387E+04 86 gibbsite 4.08 0.66 -3.42 -0.488 0.58320E+04 87 glaucophane 22.97 18.45 -4.52 -0.122 0.77244E+04 88 glaucophane-Fe 17.28 12.59 -4.69 -0.127 0.80065E+04 89 graphite -3.55 -6.93 -3.38 -0.966 0.57724E+04 90 greenalite 16.14 13.35 -2.79 -0.232 0.47553E+04 93 hematite 12.57 10.25 -2.31 -0.280 0.39512E+04 94 heulandite -5.83 -8.14 -2.31 -0.105 0.39521E+04 98 jadeite 4.22 2.61 -1.61 -0.161 0.27485E+04 100 kalsilite 7.58 3.47 -4.12 -0.588 0.70263E+04 101 kaolinite -1.33 -4.65 -3.32 -0.302 0.56665E+04 104 laumontite 2.88 0.83 -2.06 -0.137 0.35122E+04 105 lawsonite 9.62 6.81 -2.81 -0.187 0.47992E+04 106 leucite 4.12 0.48 -3.64 -0.364 0.62142E+04 108 lizardite 23.24 19.22 -4.03 -0.335 0.68729E+04 109 magnesite 0.69 -3.80 -4.49 -1.497 0.76697E+04 110 magnetite 20.09 16.70 -3.39 -0.277 0.57897E+04 111 minnesotaite 10.39 7.38 -3.01 -0.177 0.51437E+04 115 manganosite 14.06 9.11 -4.95 -1.236 0.84436E+04 119 microcline -2.49 -2.51 -0.02 -0.002 0.40148E+02 123 muscovite 2.58 -1.18 -3.77 -0.221 0.64286E+04 124 paragonite 4.24 0.94 -3.30 -0.194 0.56276E+04 125 nepheline 8.34 5.60 -2.74 -0.392 0.46861E+04 137 phlogopite-Na 29.65 24.81 -4.83 -0.269 0.82524E+04 139 prehnite 19.37 15.27 -4.10 -0.241 0.69993E+04 140 prehnite-Fe 22.50 19.74 -2.76 -0.166 0.47174E+04 146 pyrrhotite -4.26 -6.08 -1.82 -0.608 0.31119E+04 147 pyrrhotiteFe0.875 -6.02 -7.22 -1.20 -0.441 0.20463E+04 148 pyroxmangite 7.40 6.12 -1.28 -0.255 0.21772E+04 149 pyrophyllite -6.18 -10.63 -4.45 -0.278 0.76059E+04 154 rhodochrosite -0.98 -3.09 -2.11 -0.704 0.36045E+04 155 rhodonite 7.45 6.12 -1.32 -0.264 0.22574E+04 156 sanidine -1.28 -2.51 -1.23 -0.095 0.21079E+04 158 siderite -2.61 -5.76 -3.15 -1.049 0.53748E+04 166 stilbite -7.52 -8.14 -0.62 -0.030 0.10582E+04 167 stilpnomelane-Fe 13.02 12.53 -0.49 -0.014 0.82892E+03 174 talc 16.49 13.24 -3.25 -0.191 0.55514E+04 177 tephroite 18.09 15.24 -2.85 -0.407 0.48648E+04 181 tridymite -2.63 -2.99 -0.36 -0.121 0.61998E+03 184 troilite-low -4.41 -6.08 -1.67 -0.557 0.28547E+04 190 wairakite 3.95 0.83 -3.12 -0.184 0.53341E+04 191 walstromite 11.51 8.47 -3.04 -0.608 0.51939E+04 192 wollastonite 10.46 8.47 -1.99 -0.399 0.34044E+04 193 pseudo-wollastonite 11.00 8.47 -2.53 -0.507 0.43242E+04 195 akaganeite 7.75 5.13 -2.63 -0.568 0.44881E+04 202 chalcedony -2.80 -2.99 -0.19 -0.062 0.31930E+03 204 montmorillonite-Ca -2.29 -6.19 -3.90 -0.241 0.66532E+04 205 montmorillonite-K -2.24 -6.17 -3.93 -0.241 0.67081E+04 206 montmorillonite-Mg -2.48 -6.69 -4.21 -0.261 0.71916E+04 207 montmorillonite-Na -2.04 -5.46 -3.43 -0.210 0.58497E+04 208 nontronite-Ca 3.21 1.39 -1.82 -0.118 0.31148E+04 209 nontronite-H 2.53 -0.50 -3.03 -0.203 0.51784E+04 210 nontronite-K 3.34 1.41 -1.93 -0.124 0.32930E+04 211 nontronite-Mg 3.07 0.89 -2.19 -0.142 0.37373E+04 212 nontronite-Na 3.52 2.11 -1.41 -0.090 0.24006E+04 228 tobermorite 9.82 6.55 -3.27 -0.892 0.55817E+04 234 alabandite -0.98 -3.41 -2.44 -0.812 0.41601E+04 237 boehmite 4.41 0.66 -3.74 -0.624 0.63904E+04 239 ferrous-oxide 9.81 6.44 -3.37 -0.842 0.57493E+04 245 silica-amorphous -2.09 -2.99 -0.90 -0.299 0.15335E+04 247 an20ab80 2.02 1.05 -0.96 -0.074 0.16457E+04 248 an25ab75 2.65 1.41 -1.23 -0.095 0.21041E+04 249 an30ab70 3.28 1.77 -1.51 -0.116 0.25721E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 0.0020000 MOLES Current total amount of reactant added: 0.0779900 MOLES New total amount of reactant added: 0.0799900 MOLES Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.5508E-08 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 8 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 0.0799900 Water: Moles liquid = 0.4993E+02 kg liquid = 0.8994E+00 Moles total = 0.4991E+02 kg total = 0.8992E+00 Activity = 1.0000 Stoichiometric ionic strength = .1650748E-01 Osmotic coef. = 0.9260 True ionic strength = .2416375E-01 Chg. balance for total moles = -.5508E-08 Max. difference allowed = 0.6098E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.25629E-09 -9.5913 0.21281E-09 -9.6720 0.83033E+00 -0.0808 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.67483E-03 -3.1708 0.55643E-03 -3.2546 0.82455E+00 -0.0838 4 SO4-- 0.40757E-03 -3.3898 0.20124E-03 -3.6963 0.49377E+00 -0.3065 5 HCO3- 0.38163E-02 -2.4184 0.31521E-02 -2.5014 0.82595E+00 -0.0830 6 HS- 0.17804E-02 -2.7495 0.14683E-02 -2.8332 0.82469E+00 -0.0837 7 Al+++ 0.22142E-27 -27.6548 0.45562E-28 -28.3414 0.20577E+00 -0.6866 8 H4SiO4 0.10246E-02 -2.9894 0.10246E-02 -2.9894 0.10000E+01 0.0000 9 Ca++ 0.24929E-07 -7.6033 0.12204E-07 -7.9135 0.48956E+00 -0.3102 10 Mg++ 0.22168E-10 -10.6543 0.10795E-10 -10.9668 0.48697E+00 -0.3125 11 Fe++ 0.23183E-12 -12.6348 0.11304E-12 -12.9468 0.48759E+00 -0.3119 12 K+ 0.15627E-03 -3.8061 0.12911E-03 -3.8890 0.82617E+00 -0.0829 13 Na+ 0.20973E-01 -1.6783 0.17290E-01 -1.7622 0.82437E+00 -0.0839 14 Mn++ 0.11887E-09 -9.9249 0.58017E-10 -10.2364 0.48805E+00 -0.3115 15 F- 0.35567E-04 -4.4490 0.29257E-04 -4.5338 0.82260E+00 -0.0848 16 HPO4-- 0.45844E-07 -7.3387 0.22640E-07 -7.6451 0.49385E+00 -0.3064 18 HSiO3- 0.54524E-02 -2.2634 0.44958E-02 -2.3472 0.82455E+00 -0.0838 19 Ca(HSiO3)+ 0.15121E-08 -8.8204 0.12495E-08 -8.9033 0.82638E+00 -0.0828 20 Mg(HSiO3)+ 0.16645E-11 -11.7787 0.13755E-11 -11.8615 0.82638E+00 -0.0828 21 NaHSiO3,aq 0.12572E-02 -2.9006 0.12572E-02 -2.9006 0.10000E+01 0.0000 22 AlO+ 0.16562E-15 -15.7809 0.13687E-15 -15.8637 0.82638E+00 -0.0828 24 HAlO2,aq 0.12808E-09 -9.8925 0.12808E-09 -9.8925 0.10000E+01 0.0000 25 AlO2- 0.16191E-05 -5.7907 0.13323E-05 -5.8754 0.82284E+00 -0.0847 26 CH4,aq 0.22451E-07 -7.6488 0.22339E-07 -7.6509 0.99501E+00 -0.0022 27 C2H6,aq 0.52291E-18 -18.2816 0.52030E-18 -18.2837 0.99501E+00 -0.0022 31 CO,aq 0.59038E-14 -14.2289 0.59038E-14 -14.2289 0.10000E+01 0.0000 32 CO2,aq 0.14405E-05 -5.8415 0.14333E-05 -5.8437 0.99501E+00 -0.0022 33 CO3-2 0.26266E-02 -2.5806 0.12937E-02 -2.8882 0.49256E+00 -0.3075 34 CaCO3,aq 0.19798E-06 -6.7034 0.19798E-06 -6.7034 0.10000E+01 0.0000 35 Ca(HCO3)+ 0.11882E-08 -8.9251 0.98194E-09 -9.0079 0.82638E+00 -0.0828 36 CaCl+ 0.13299E-10 -10.8762 0.10990E-10 -10.9590 0.82638E+00 -0.0828 37 CaCl2,aq 0.14528E-14 -14.8378 0.14528E-14 -14.8378 0.10000E+01 0.0000 38 CaF+ 0.63083E-11 -11.2001 0.52131E-11 -11.2829 0.82638E+00 -0.0828 39 CaOH+ 0.49459E-08 -8.3058 0.40872E-08 -8.3886 0.82638E+00 -0.0828 40 CaSO4,aq 0.77990E-09 -9.1080 0.77990E-09 -9.1080 0.10000E+01 0.0000 41 HCl,aq 0.21699E-13 -13.6636 0.21699E-13 -13.6636 0.10000E+01 0.0000 45 HF,aq 0.42622E-10 -10.3704 0.42622E-10 -10.3704 0.10000E+01 0.0000 46 HF2- 0.51060E-15 -15.2919 0.42102E-15 -15.3757 0.82455E+00 -0.0838 48 FeCl+ 0.12048E-15 -15.9191 0.99558E-16 -16.0019 0.82638E+00 -0.0828 51 FeF+ 0.20451E-15 -15.6893 0.16900E-15 -15.7721 0.82638E+00 -0.0828 53 FeO,aq 0.97010E-10 -10.0132 0.97010E-10 -10.0132 0.10000E+01 0.0000 54 FeOH+ 0.20923E-10 -10.6794 0.17290E-10 -10.7622 0.82638E+00 -0.0828 55 HFeO2- 0.57846E-08 -8.2377 0.47697E-08 -8.3215 0.82455E+00 -0.0838 56 FeO+ 0.12325E-15 -15.9092 0.10185E-15 -15.9920 0.82638E+00 -0.0828 58 FeO2- 0.55809E-09 -9.2533 0.46018E-09 -9.3371 0.82455E+00 -0.0838 59 HFeO2,aq 0.12455E-10 -10.9047 0.12455E-10 -10.9047 0.10000E+01 0.0000 60 H2,aq 0.16479E-06 -6.7831 0.16397E-06 -6.7852 0.99501E+00 -0.0022 61 KCl,aq 0.13021E-08 -8.8854 0.13021E-08 -8.8854 0.10000E+01 0.0000 62 KHSO4,aq 0.15633E-16 -16.8059 0.15633E-16 -16.8059 0.10000E+01 0.0000 63 KOH,aq 0.25909E-06 -6.5865 0.25909E-06 -6.5865 0.10000E+01 0.0000 64 KSO4- 0.48897E-06 -6.3107 0.40318E-06 -6.3945 0.82455E+00 -0.0838 65 MgCO3,aq 0.43895E-10 -10.3576 0.43895E-10 -10.3576 0.10000E+01 0.0000 66 Mg(HCO3)+ 0.10740E-11 -11.9690 0.88752E-12 -12.0518 0.82638E+00 -0.0828 67 MgCl+ 0.10661E-13 -13.9722 0.88104E-14 -14.0550 0.82638E+00 -0.0828 68 MgF+ 0.20670E-13 -13.6847 0.17081E-13 -13.7675 0.82638E+00 -0.0828 69 MgOH+ 0.24208E-10 -10.6160 0.20005E-10 -10.6989 0.82638E+00 -0.0828 71 MnF+ 0.34597E-13 -13.4610 0.28590E-13 -13.5438 0.82638E+00 -0.0828 72 MnO,aq 0.13267E-08 -8.8772 0.13267E-08 -8.8772 0.10000E+01 0.0000 73 MnOH+ 0.99760E-09 -9.0010 0.82439E-09 -9.0839 0.82638E+00 -0.0828 74 MnO2-2 0.19738E-11 -11.7047 0.97223E-12 -12.0122 0.49256E+00 -0.3075 75 HMnO2- 0.54973E-10 -10.2599 0.45328E-10 -10.3436 0.82455E+00 -0.0838 78 MnCl+ 0.24056E-12 -12.6188 0.19879E-12 -12.7016 0.82638E+00 -0.0828 79 MnSO4,aq 0.33707E-11 -11.4723 0.33707E-11 -11.4723 0.10000E+01 0.0000 80 NaCl,aq 0.31883E-05 -5.4964 0.31883E-05 -5.4964 0.10000E+01 0.0000 81 NaF,aq 0.11843E-06 -6.9265 0.11843E-06 -6.9265 0.10000E+01 0.0000 82 NaOH,aq 0.34907E-04 -4.4571 0.34907E-04 -4.4571 0.10000E+01 0.0000 84 OH- 0.32996E-02 -2.4815 0.27150E-02 -2.5662 0.82284E+00 -0.0847 89 HPO3-2 0.23487E-16 -16.6292 0.11568E-16 -16.9367 0.49256E+00 -0.3075 92 H3PO4,aq 0.71709E-17 -17.1444 0.71709E-17 -17.1444 0.10000E+01 0.0000 93 H2PO4- 0.10767E-09 -9.9679 0.88878E-10 -10.0512 0.82546E+00 -0.0833 94 PO4-3 0.39853E-09 -9.3995 0.86800E-10 -10.0615 0.21780E+00 -0.6619 98 HP2O7-3 0.28209E-17 -17.5496 0.58117E-18 -18.2357 0.20602E+00 -0.6861 99 P2O7-4 0.10348E-16 -16.9851 0.65241E-18 -18.1855 0.63048E-01 -1.2003 100 H2S,aq 0.97054E-06 -6.0130 0.96570E-06 -6.0152 0.99501E+00 -0.0022 101 S2-2 0.59147E-09 -9.2281 0.29133E-09 -9.5356 0.49256E+00 -0.3075 102 S3-2 0.46932E-14 -14.3285 0.23117E-14 -14.6361 0.49256E+00 -0.3075 103 S3- 0.98763E-18 -18.0054 0.81436E-18 -18.0892 0.82455E+00 -0.0838 104 S4-2 0.24599E-19 -19.6091 0.12117E-19 -19.9166 0.49256E+00 -0.3075 107 SO3-2 0.85623E-11 -11.0674 0.42880E-11 -11.3677 0.50080E+00 -0.3003 108 HSO3- 0.69292E-13 -13.1593 0.57135E-13 -13.2431 0.82455E+00 -0.0838 109 HSO4- 0.49887E-10 -10.3020 0.41273E-10 -10.3843 0.82732E+00 -0.0823 111 S2O3-2 0.46348E-11 -11.3340 0.22829E-11 -11.6415 0.49256E+00 -0.3075 112 HS2O3- 0.10535E-18 -18.9774 0.86865E-19 -19.0612 0.82455E+00 -0.0838 Charge balance for all species = -.6123E-08 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.2562941E-09 -.1267520E-01 -.1275414E+02 0.0000 2 H2O 0.1000000E+01 0.5550488E+02 0.9982382E+06 0.0000 3 Cl- 0.6748297E-03 0.6780193E-03 0.2399698E+02 6.4174 4 SO4-- 0.4075697E-03 0.4079961E-03 0.3912617E+02 15.6477 5 HCO3- 0.3816269E-02 0.6444528E-02 0.3925590E+03 7.1706 6 HS- 0.1780385E-02 0.1781420E-02 0.5881503E+02 6.8388 7 Al+++ 0.2214217E-27 0.1619267E-05 0.4361604E-01 0.6746 8 H4SiO4 0.1024625E-02 0.7734167E-02 0.7421096E+03 -2.9894 9 Ca++ 0.2492887E-07 0.2313526E-06 0.9256396E-02 11.4305 10 Mg++ 0.2216803E-10 0.9304122E-10 0.2258175E-05 8.3773 11 Fe++ 0.2318336E-12 0.6473278E-08 0.3608990E-03 6.3973 12 K+ 0.1562731E-03 0.1570225E-03 0.6129462E+01 5.7830 13 Na+ 0.2097317E-01 0.2226857E-01 0.5110802E+03 7.9098 14 Mn++ 0.1188744E-09 0.2503764E-08 0.1373181E-03 9.1076 15 F- 0.3556668E-04 0.3568516E-04 0.6767948E+00 5.1382 16 HPO4-- 0.4584380E-07 0.4635000E-07 0.4441069E-02 11.6989 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.1141362E-01 -.1140035E-01 -.1326910E-04 0.0000000E+00 2 H2O 0.4991190E+02 0.4992228E+02 -.1038688E-01 0.0000000E+00 3 Cl- 0.6098252E-03 0.6098252E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.3669672E-03 0.3669605E-03 0.6692516E-08 0.0000000E+00 5 HCO3- 0.5796347E-02 0.5796347E-02 0.0000000E+00 0.0000000E+00 6 HS- 0.1602294E-02 0.1602247E-02 0.4684761E-07 0.0000000E+00 7 Al+++ 0.4775352E-05 0.1456404E-05 0.3318948E-05 0.0000000E+00 8 H4SiO4 0.1215302E-01 0.6956277E-02 0.5196743E-02 0.0000000E+00 9 Ca++ 0.2080835E-06 0.2080835E-06 0.0000000E+00 0.0000000E+00 10 Mg++ 0.8368328E-10 0.8368328E-10 0.0000000E+00 0.0000000E+00 11 Fe++ 0.3259227E-07 0.5822205E-08 0.2677006E-07 0.0000000E+00 12 K+ 0.1412294E-03 0.1412294E-03 0.0000000E+00 0.0000000E+00 13 Na+ 0.2003215E-01 0.2002883E-01 0.3318948E-05 0.0000000E+00 14 Mn++ 0.2251939E-08 0.2251939E-08 0.0000000E+00 0.0000000E+00 15 F- 0.3209600E-04 0.3209600E-04 0.0000000E+00 0.0000000E+00 16 HPO4-- 0.4168819E-07 0.4168819E-07 0.0000000E+00 0.0000000E+00 Chg. balance for solid moles: 0.4235E-21 Mass of aqueous solution: 0.900952E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 0.0799900 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 0.3319E-05 -5.479 0.8703E-03 -3.060 0.2785 0.3341E-03 pyrite 0.2677E-07 -7.572 0.3212E-05 -5.493 0.1028E-02 0.6408E-06 quartz 0.5187E-02 -2.285 0.3116 -0.506 99.72 0.1177 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 pyrite 0.1000E+01 0.1000E+01 1.0000 0.000 quartz 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 0.312496 g Volume = 0.118017 cm3 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.0799900 moles log = -1.0970 Original solution: 1000.0103000 g Original solution / Rock added: 12501.69 (Water/Rock Ratio), log = 4.0970 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0207 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9996E+00 0.9859 0.1006E+01 0.1020E+01 CO2,gas 0.1492E-03 1.0071 0.1533E-03 0.1523E-03 CH4,gas 0.3182E-04 1.0125 0.3288E-04 0.3247E-04 H2,gas 0.2108E-03 1.0005 0.2153E-03 0.2152E-03 H2S,gas 0.2611E-04 0.9960 0.2655E-04 0.2665E-04 S2,gas 0.5592E-21 1.0000 0.5708E-21 0.5708E-21 CO,gas 0.8619E-11 1.0000 0.8798E-11 0.8798E-11 SO3,gas 0.3376E-38 1.0000 0.3446E-38 0.3446E-38 SO2,gas 0.2827E-19 1.0000 0.2886E-19 0.2886E-19 HF,gas 0.1025E-12 1.0000 0.1047E-12 0.1047E-12 HCl,gas 0.3751E-16 1.0000 0.3829E-16 0.3829E-16 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 17 albite -0.38 -0.38 0.00 0.000 -0.94784E-12 145 pyrite -21.25 -21.25 0.00 0.000 0.00000E+00 150 quartz -2.99 -2.99 0.00 0.000 0.75827E-12 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -12.17 -5.51 -1.838 0.94138E+04 -3.814 3 CH4,gas 4.54 -1.64 -6.18 -1.546 0.10556E+05 -4.483 4 H2,gas 8.00 2.63 -5.37 -3.066 0.91623E+04 -3.667 5 H2S,gas -6.23 -12.51 -6.27 -3.137 0.10714E+05 -4.576 6 S2,gas -7.34 -30.28 -22.94 -3.530 0.39174E+05 -21.244 7 CO,gas 3.21 -9.54 -12.75 -3.924 0.21778E+05 -11.056 8 SO3,gas 17.12 -23.04 -40.16 -10.040 0.68575E+05 -38.463 9 SO2,gas 0.83 -20.41 -21.24 -5.664 0.36264E+05 -19.540 10 HF,gas 0.47 -14.21 -14.68 -7.340 0.25064E+05 -12.980 11 HCl,gas 5.19 -12.93 -18.12 -9.058 0.30932E+05 -16.417 12 acmite 7.71 7.01 -0.70 -0.073 0.11925E+04 16 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 20 spessartine 24.46 19.70 -4.75 -0.238 0.81167E+04 21 analcite 3.32 2.61 -0.72 -0.080 0.12231E+04 23 andradite 39.01 35.48 -3.52 -0.183 0.60184E+04 26 ankerite -2.14 -6.52 -4.38 -0.731 0.74855E+04 27 annite 20.12 16.68 -3.44 -0.191 0.58777E+04 28 phlogopite 27.06 22.62 -4.44 -0.247 0.75872E+04 34 apatite-F -34.30 -38.02 -3.72 -0.310 0.63511E+04 38 aragonite 0.97 -0.74 -1.71 -0.570 0.29188E+04 39 brucite 12.57 8.38 -4.19 -0.838 0.71566E+04 40 calcite 0.81 -0.74 -1.55 -0.518 0.26545E+04 41 carnegieite-low 9.02 5.60 -3.43 -0.490 0.58537E+04 42 carnegieite-high 10.09 5.60 -4.50 -0.643 0.76807E+04 43 carpholite-Mg 8.58 3.75 -4.83 -0.322 0.82547E+04 44 carpholite-Fe 6.71 1.77 -4.94 -0.330 0.84434E+04 45 celadonite 5.34 2.88 -2.46 -0.145 0.42080E+04 46 celadonite-Fe 3.88 0.90 -2.98 -0.175 0.50873E+04 47 chrysotile 23.89 19.15 -4.74 -0.395 0.80926E+04 49 clinochlore 39.07 34.27 -4.80 -0.150 0.81998E+04 50 daphnite 28.97 24.37 -4.60 -0.144 0.78510E+04 54 chloritoid-Fe 9.17 4.76 -4.42 -0.294 0.75411E+04 55 chloritoid-Mn 11.40 7.47 -3.93 -0.262 0.67166E+04 57 coesite -2.38 -2.99 -0.61 -0.204 0.10473E+04 64 cristobalite -2.56 -2.99 -0.43 -0.143 0.73267E+03 66 cymrite-K 1.69 -2.51 -4.20 -0.350 0.71647E+04 68 diaspore 2.87 0.67 -2.20 -0.367 0.37548E+04 69 diamond -3.10 -6.91 -3.80 -1.087 0.64943E+04 70 diopside 16.18 13.83 -2.35 -0.235 0.40167E+04 71 hedenbergite 14.21 11.85 -2.36 -0.236 0.40285E+04 78 epidote 24.67 20.32 -4.35 -0.211 0.74233E+04 81 fayalite 14.05 9.81 -4.24 -0.606 0.72408E+04 82 ferrosilite 11.15 6.82 -4.33 -0.433 0.73999E+04 86 gibbsite 4.08 0.67 -3.40 -0.486 0.58134E+04 87 glaucophane 22.97 18.39 -4.59 -0.124 0.78367E+04 88 glaucophane-Fe 17.28 12.45 -4.83 -0.131 0.82482E+04 89 graphite -3.55 -6.91 -3.36 -0.960 0.57366E+04 90 greenalite 16.14 13.21 -2.93 -0.244 0.49971E+04 93 hematite 12.57 10.16 -2.41 -0.292 0.41072E+04 94 heulandite -5.83 -8.15 -2.32 -0.105 0.39596E+04 98 jadeite 4.22 2.61 -1.61 -0.161 0.27485E+04 100 kalsilite 7.58 3.47 -4.12 -0.588 0.70275E+04 101 kaolinite -1.33 -4.63 -3.30 -0.300 0.56292E+04 104 laumontite 2.88 0.82 -2.06 -0.137 0.35197E+04 105 lawsonite 9.62 6.80 -2.82 -0.188 0.48068E+04 106 leucite 4.12 0.48 -3.64 -0.364 0.62154E+04 108 lizardite 23.24 19.15 -4.09 -0.341 0.69852E+04 109 magnesite 0.69 -3.80 -4.49 -1.496 0.76610E+04 110 magnetite 20.09 16.56 -3.53 -0.288 0.60264E+04 111 minnesotaite 10.39 7.23 -3.15 -0.186 0.53855E+04 115 manganosite 14.06 9.11 -4.95 -1.238 0.84529E+04 119 microcline -2.49 -2.51 -0.02 -0.002 0.41329E+02 123 muscovite 2.58 -1.16 -3.74 -0.220 0.63925E+04 124 paragonite 4.24 0.97 -3.27 -0.193 0.55903E+04 125 nepheline 8.34 5.60 -2.74 -0.392 0.46861E+04 137 phlogopite-Na 29.65 24.75 -4.90 -0.272 0.83647E+04 139 prehnite 19.37 15.24 -4.13 -0.243 0.70516E+04 140 prehnite-Fe 22.50 19.65 -2.85 -0.171 0.48665E+04 146 pyrrhotite -4.26 -6.11 -1.85 -0.616 0.31548E+04 147 pyrrhotiteFe0.875 -6.02 -7.23 -1.22 -0.448 0.20784E+04 148 pyroxmangite 7.40 6.12 -1.28 -0.256 0.21865E+04 149 pyrophyllite -6.18 -10.61 -4.43 -0.277 0.75687E+04 154 rhodochrosite -0.98 -3.07 -2.09 -0.697 0.35678E+04 155 rhodonite 7.45 6.12 -1.33 -0.266 0.22667E+04 156 sanidine -1.28 -2.51 -1.24 -0.095 0.21091E+04 158 siderite -2.61 -5.78 -3.17 -1.056 0.54093E+04 166 stilbite -7.52 -8.15 -0.62 -0.030 0.10658E+04 167 stilpnomelane-Fe 13.02 12.31 -0.71 -0.021 0.12045E+04 174 talc 16.49 13.17 -3.32 -0.195 0.56638E+04 177 tephroite 18.09 15.23 -2.86 -0.409 0.48835E+04 181 tridymite -2.63 -2.99 -0.36 -0.121 0.61998E+03 184 troilite-low -4.41 -6.11 -1.70 -0.566 0.28976E+04 190 wairakite 3.95 0.82 -3.13 -0.184 0.53416E+04 191 walstromite 11.51 8.44 -3.07 -0.614 0.52387E+04 192 wollastonite 10.46 8.44 -2.02 -0.404 0.34492E+04 193 pseudo-wollastonite 11.00 8.44 -2.56 -0.512 0.43690E+04 195 akaganeite 7.75 5.08 -2.67 -0.578 0.45662E+04 202 chalcedony -2.80 -2.99 -0.19 -0.062 0.31930E+03 204 montmorillonite-Ca -2.29 -6.18 -3.89 -0.241 0.66418E+04 205 montmorillonite-K -2.24 -6.16 -3.92 -0.240 0.66959E+04 206 montmorillonite-Mg -2.48 -6.68 -4.20 -0.260 0.71790E+04 207 montmorillonite-Na -2.04 -5.46 -3.42 -0.209 0.58371E+04 208 nontronite-Ca 3.21 1.30 -1.92 -0.124 0.32721E+04 209 nontronite-H 2.53 -0.59 -3.12 -0.209 0.53283E+04 210 nontronite-K 3.34 1.32 -2.02 -0.130 0.34494E+04 211 nontronite-Mg 3.07 0.79 -2.28 -0.148 0.38934E+04 212 nontronite-Na 3.52 2.02 -1.50 -0.096 0.25566E+04 228 tobermorite 9.82 6.53 -3.29 -0.898 0.56190E+04 234 alabandite -0.98 -3.40 -2.42 -0.807 0.41317E+04 237 boehmite 4.41 0.67 -3.73 -0.622 0.63718E+04 239 ferrous-oxide 9.81 6.40 -3.41 -0.854 0.58299E+04 245 silica-amorphous -2.09 -2.99 -0.90 -0.299 0.15335E+04 247 an20ab80 2.02 1.05 -0.96 -0.074 0.16472E+04 248 an25ab75 2.65 1.41 -1.23 -0.095 0.21059E+04 249 an30ab70 3.28 1.77 -1.51 -0.116 0.25743E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 0.0020000 MOLES Current total amount of reactant added: 0.0799900 MOLES New total amount of reactant added: 0.0819900 MOLES Mixing fraction reached given limit of 0.8000E-01 TOTMIX = 0.8199E-01 Execution stopped.